TECHNICAL APPENDICES
             WARD COVE
    WATER QUALITY ASSESSMENT

   JONES & STOKES ASSOCIATES, INC.
environmental planning • natural resource sciences


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  TECHNICAL APPENDICES
        WARD COVE
WATER QUALITY ASSESSMENT
    Work Assignment No. 16

   EPA Contract No. 68-02-4381

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                        TABLE OF CONTENTS
APPENDIX A

APPENDIX B
APPENDIX C

APPENDIX D
APPENDIX E

APPENDIX F
Draft Report from Kinnetic Labs, Inc.

Chemistry Analyses
   EPA Manchester Lab
   ECOVA Laboratory Analyses
   WDOE Laboratory Analyses

ADEC Field Notes and Raw Data

Bioassay Results
   ToxScan, Inc.
   EPA Manchester Lab
   Westec Services Bioassay Laboratory

Intercalibration Data

EPA Environmental Research Laboratory (Duluth) Dioxin Study

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     APPENDIX A






DRAFT REPORT FROM KLI

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                             2.0  METHODS
2.1  Short-Term Intensive Studies

2.1.1  Experimental Design

The  physical  oceanographic  studies were  designed to determine  the
flushing characteristics of Ward  Cove,  as  well  as to evaluate as far
as possible the  questions  of oxygen balance within  the  cove.   These
studies were undertaken in late August when minimum oxygen conditions
historically  occur  in the  cove.   The  August  field  studies  were
conducted during 19 August - 24 August 1988, which is a period of low
tide  range  at Ward  Cove  representing a minimum  flushing situation.
Supplemental measurements were also conducted in late September.

Salinity/temperature/depth   (STD)   profiles   were  taken  with   an
oceanographic probe system at stations within and outside the cove in
order to  establish water stratification.   Stream  flow into Ward Cove
was  determined  by  velocity  and  cross section  measurements  using
accepted  USGS  methodology  (Rantz  1982) .   Current drogues  were  used
within Ward  Cove at  the  surface  layer  and at depth  to measure  the
estuarine circulation within the cove, and also to estimate the tidal
and  wind  induced exchange  that is active  in mixing  cove waters  with
those  just outside  the  entrance.   The  above  data will then  be
interpreted in the context of a simple  estuary tidal flushing model.
The methodology used will be those of Officer (1976)  or Ditoro et al.
(1977).

The  oxygen balance of  the  cove includes oxygen inputs from the fresh
water and the effluent discharged into the cove, from  the seawater
exchange with the waters outside the cove,  from air/water exchange at
the  surface of the water,  and from phytoplankton productivity within
the  cove.  Oxygen consumption terms include the BOD  loading from the
pulp mill, the BOD loading from  the cannery,  the benthic BOD demand
including  that  of  any  waste  organic  debris, and  the  natural  BOD
demand from natural  organic material in the seawater.

Oxygen  consumption  terms  for  the  pulp  mill  effluent  and  for  the
cannery  can be  estimated  from the volume  and  BOD values measured
during the study and also  from  those reported in  their permits.
The  benthic consumption term  is important,  especially  since debris or
sludge  from previous  mill  or log storage activities  may  also be
important.   This  benthic  consumption  term is difficult to measure
directly.      In  addition to  the  laboratory measurements,  direct
measurements of benthic oxygen  demand were made by. an  in  situ chamber
placed on the bottom.   The in situ benthic chamber was used at two
stations  in the upper  Cove, and one  station in the lower  Cove to help
estimate  the benthic oxygen consumption term.

In addition to the in situ benthic chamber,  bottom  grabs were taken
as part  of the  chemistry  and  toxicity  study  elements.   Determining
the  BOD  demand in the laboratory of sediment  samples from grabs or
cores will  yield some useful information,  however the normal demand


                                 A-l

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though the  benthic interface would not be  duplicated in a disturbed
core or grab sample.

2.1.2  Field Methodology

Field work  was  carried out during a  four-day  period in late August,
and  during  a  two-day  period  in  late  September  coinciding  with
historical  minimum  oxygen concentration  conditions  in Ward  Cove.
Operations  in August  were  conducted  from  the Curlew, a U.S. Fish and
Wildlife Service vessel.  The September sampling was  conducted from a
tug boat provided by  the Ketchikan Pulp Mill.

Hydrographic  CSTD  (conductivity,  salinity, temperature,  and depth)
profiles  were performed  with  an  InterOcean  Systems 513D recording
oceanographic profiling system, equipped  with dissolved  oxygen and
transmissivity  probes.  Discrete  samples for DO  (dissolved oxygen)
determinations  were taken frequently  for calibration purposes using
General Oceanics  5-liter Niskin oceanographic sampling bottles.   All
DO samples  were run within 8 hours using the Winkler  technique, after
Strickland  and Parsons (1972).  Salinity, temperature, and pH samples
were  also be taken for calibration  purposes.   Salinity samples were
brought back to  the  laboratory and run on a laboratory salinometer
using   Copenhagen  Standard  seawater.     The  pH  and  temperature
calibration samples were run in the  field  on a  Corning 105 portable
temperature and pH meter.  In addition to the  InterOcean CSTD system,
an  Applied  Microsystems STD-12  was  utilized during  the September
sampling  to obtain  supplemental temperature, salinity, and pH profile
data at each hydrographic station.

The  grid  of  hydrographic  stations  that  were  occupied  included
sufficient  stations within the cove to characterize the water masses
and rheterogeneity of the cove as well as sufficient  stations outside
to  characterize ambient ocean  waters  in  Tongass Narrows (Figure 2-1
and  Table   2-1).     Station  positioning  was accomplished  with  a
MiniRanger  III  microwave  navigation system.  This system gives the
range between the vessel and a  series  of shore transponders set up at
known  locations.   Accuracy of  the system was checked both prior to
entering  the field  and  by  positioning the vessel  at  known points
along   the   shoreline.    Supplemental  radar  bearings  and  visual
sightings were  obtained at the calibration sites.   In addition, this
system  also allowed  for accurate tracking of  drogues and positioning
of sediment stations.

Drogues  were used  to measure  the  currents within the  cove,  and to
estimate  the exchange of water with those  in  Tongass Narrows. The
drogue  experiments were carried out using  8  by 6_ ft plastic window
shade drogues designed to  have  a drogue to  float area ratio in excess
of  100/1  to minimize any wind drift errors  (Figure 2-2).   Drogues
were  set  in pairs at each deployment site,  one in the surface  layer
and  one at 15 m.   Drogue  experiments were conducted on two  separate
days  including  intensive tracking  over one complete  tidal cycle.
Drogue  positions were determined by motoring  alongside and recording
MiniRanger  coordinates.   Some difficulties were  encountered in the
use  of  these drogues  due  to  large areas  within the  Cove occupied by

                                 A-2

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Table 2-1.  Hydrographic,  Primary  Productivity,  and BOD Station
            Coordinates.
Station
Date
Latitude
Longitude
Hydrographic Stations
1-1
1-2
1-3
2-1
2-2
2-3
2-4
2-5
3-1
3-2
3-3
3-4
3-5
4-1
4-2
4-3
5-1
5-2
5-3
5-4
5-5
5-6
50
51
Primary
P-l
P-2
P-3
P-4
P-5
P-6
9/20









8/21

9/21



8/21




8/23
8/21

Productivity
8/20
8/21
8/20
8/20
8/20
8/20
55 24' 25.5"
55 24' 25.2"
55 24' 25.1"
55 24' 25.8"
55 24' 20.2"
55 24' 19.3"
55 24' 19.0' '
55 24' 15.9"
55 24' 20.4"
55 24' 11.7"
55 24' 10.8' '
55 24' 8.1"
55 24' 6.5"
55 24' 3.2"
55 23' 58.1"
55 23' 53.6"
55 23' 53.1"
55 23' 47.6"
55 23' 45.9"
55 23' 42.9"
55 23' 38.8"
55 23' 54.3"
55 23' 50.0"
55 23' 15.0"
Stations
55 23' 15.0"
55 23' 53.0"
55 24' 8.0"
55 24' 23.0"
55 24' 26.0"
55 24' 19.0"
131 43' 6.7"
131 43' 4.9"
131 43' 3.8"
131 43' 25.6"
131 43' 25.6"
131 43' 15.6"
131 43' 11.7"
131 43' 5.9"
131 43' 41.7"
131 43' 30.1"
131 43' 30.6"
131 43' 23.3"
131 43' 22.5"
131 43' 47.0"
131 43' 42.3"
131 43' 40.5"
131 44' 28.3"
131 44' 24.0"
131 44' 18.5"
131 44' 14.2"
131 44' 8.6"
131 43' 51.7"
131 44' 35.0"
131 44' 30.0"

131 45' 40.0"
131 43' 40.0"
131 43' 34.0"
131 43' 29.0"
131 43' 3.0"
131 43' 45.0"
BOD Stations
2
3
4



55 23' 56.6"
55 24' 25.3"
55 24' 13.9"
131 43' 36.6"
131 43' 6.8"
131 43' 46.6""
                                  A-3

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                                                                - Primary
                                                                 Productivity
                                                             131°43'
                                                       'fc. '• - Hydrographic
                                                            - Primary
                                                              Productivity
                                                       0	0.1  0.1  03  0.4  O.B Kllom.l.n


                                                       0     0.1     O.I     0.3 Niul. Mil
2-1.   Hydrographic, primary productivity,  and BOD stations in Ward  Cove.
                                    A-4

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                          IDENTIFICATION  PENNANT
CONNECTING  LINE
                       TRACKING BUOY
                 10'  SPHERICAL FLOAT
                                                6-8 MIL  POLYETHYLENE
                                                           PVC  PIPE
                                                             WATER
                                                            _L E V E L
                                                        10  LB.  BALLAST
                                                        CONTAINED WITHIN
                                                        BOTTOM  PVC P1PE
  2-2.  Window-shade drogue, flotation, and marker buoy.
                                 A-5

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floating log storage.   However,  a time-integrating method of current
measurement was  desired, as  the currents within the  Cove  were very
low.   When the current  drogues  encountered areas of  log booms,  the
drogues were picked up and reset.

Stream  flow measurements  of Ward  Creek were  taken  at appropriate
gaging sites using  a Montedoro-Whitney PVM-2A portable flow velocity
meter  and  standard USGS cross-sectional  flow measurement techniques
(Rantz 1982a).   Measurements were  made above the MHHW (mean higher
high water) level  along a section of  the stream that was relatively
straight with uniform hydraulic  conditions.

Benthic oxygen demand was determined experimentally at three selected
stations,  two  being located in  the upper cove and one in the lower.
An  in  situ benthic chamber was  placed on the bottom for purposes of
these  measurements.   The chamber consisted of a 10-liter glass dome
built  into a  bottom mount,  a  Sea Bird  dissolved oxygen  probe  and
water  pump, and  a  data logger.   The bottom of the dome was sealed in
a stainless steel ring,  which extended below the bottom mount and cut
into the  sediment to a  depth of 8 cm to effect  a bottom seal.   The
dome was eguipped with a water pump which pumped water from the dome,
across the oxygen electrode  and back into  the  chamber.  A Campbell
Scientific CR10  programmable data  logger/controller  housed  in  an
Aanderaa pressure  housing was used to control the water pump and to
log the data measured by the  oxygen sensor.  Water within the chamber
was sampled  at 30 minute  intervals.   The  chamber  was  carefully
lowered to the bottom so as not to disturb the sediment and then was
buoyed off for later recovery.   The  oxygen electrode was calibrated
with  the  Winkler  method  before  the  initial  deployment  and  after
retrieval  in the laboratory-

Productivity  measurements were  made  at 5  stations  within  Ward Cove
and'l  outside in Tongass Narrows (Figure 2-1),  using the radiocarbon
technique  (Strickland and  Parsons  1972).   Water samples were taken
from 1 m and 5 m depths at Stations  PI,  P2,  P3, and P4.  At Station
P5  only  the 1 m depth was sampled due to  the shallow water column.
In  addition to these  samples, extra water was collected near the main
effluent outfall  (Station P6), at 1 m,  and at Station P4, at 1 m, and
incubated  at Station  P3.

Three  150  ml glass  bottles  were filled for  each depth.   Two of the
bottles  were clear  and the third was a  dark bottle  used  as a non-
photosynthetic  uptake blank.  Each water sample was injected with  5
microCuries of  -^C-labeled  sodium bicarbonate.   The bottles were then
suspended  from a surface mooring at  the  proper  depth from which the
water  was  collected.   Incubations were done for  5 to 7 hours.

After  incubation,  the  samples were  filtered  (in  subdued light)
through  0.45  micron  Millipore filters  and rinsed  with  filtered
seawater.   The filters were placed in scintillation vials and placed
in  a desiccator overnight.   The vials were then stored with the lids
on  until  scintillation counting  procedures were performed  at the
University of  Alaska's  laboratory  in  Fairbanks.
                                 A-6

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2.1.3  Data Analysis

Hydrographic data obtained in the field were returned for analysis to
KLI's data processing facilities in Santa Cruz, California.  Cassette
data tapes  from the  InterOcean  513D CSTD were processed on  a tape
reader  and  combined with  calibration coefficients to  produce final
engineering values for analysis.   Data from the solid state recording
Applied Microsystems STD-12 were dumped directly into computer files.
All CSTD profiles  were  then plotted to aid  in the interpretation of
the data.  QA/QC data obtained in the field were compared against the
recorded values to ascertain their accuracy.

All drogue data were plotted on plan view maps of the study area that
show deployment and  subsequent drogue positions.   An analysis of the
drogue  positions  was also performed to  determine the speed  of the
individual drogues.

Stream  velocity measurements  were combined  with the  stream cross-
section  measurements to  determine the  discharge rate according to
standard USGS  techniques  (Rantz 1982) .   This data was then  used in
combination with dissolved oxygen  data to determine the oxygen input
to  the  cove by Ward  Creek.   In addition, the stream discharge rate
was  compared  with pulp  mill's effluent discharge  rate to determine
the  percentage of  the  stream flow  that was  utilized for the pulp
mill's operations.

Data  obtained from  the in  situ benthic oxygen  demand chamber were
dumped  from the Campbell  Scientific CR10 data logger onto computer
files.    The  dissolved  oxygen data  was   plotted versus  time  to
determine the oxygen consumption rate within  the chamber.   The data
was  combined  with  the volume of the  chamber and the surface area of
the  bottom to determine  the oxygen demand  as a  function  of the
surface area of the bottom.

Primary  productivity samples were  sent to the University of Alaska's
laboratory  in Fairbanks  for the  scintillation counting  procedures.
Before  counting,  the vials  were fumed with  hydorchloric  acid vapors
for  several hours  to remove any carbonates.   10 ml of scintillation
cocktail  was   then  added  to  each  vial  and  the outside  of  the vial
wiped with  acetone.  The  activity of the 14C was determined with a
Beckman  5801  Liquid Scintillation Counter.   Rates of photosynthesis
were calculated according  to Strickland and  Parsons  (1972).

Rough estimates  were made of the magnitude  of the oxygen input into
Ward Cove  and consumption terms.  The  purpose of this effort was to
evaluate  the  possible  magnitude  of  the pulp mill  BOD  load,  as a
fraction of the total oxygen available to the  cove and  in relation to
the  other consumption  terms.   The  historical available  oxygen data
for  the late  summer periods have not shown significant  improvement
even  though  the  effluent  BOD loads  from  the  pulp mill  have been
reduced  over  recent  years.

Oxygen  inputs  from the  fresh water  discharged into  the cove were
estimated from sampling the oxygen content of  these waters, using  the


                                 A-7

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Winkler method, and combining the value with the measured flow rates.
Oxygen  measurements done  in the  cove and  just outside  on station
profiles, at the same  time as the  hydrographic CSTD casts, were used
to establish  the total  amount  of oxygen  in the cove waters  and of
those outside.   Combining  these  values with  the  exchange estimates
done above for  flushing  purposes will  yield  an estimate of the input
of dissolved oxygen brought into the cove with the outside seawater.
Phytoplankton productivity within  the cove  was measured by standard
14C  productivity  measurements and converted into an  estimate of in
situ oxygen production.   The contribution of oxygen input by air-sea
exchange were estimated  from literature values, and from wind records
from the pulp mill and the Ketchikan airport.
                                 A-8

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                             3.0  RESUI/CS
3.1  Short-Term Intensive Studies

3.1.1  Hydrography

Water  quality  sampling  was  conducted  during both  the August  and
September  sampling  efforts.    An  InterOcean  Model  513D  CSTD  was
utilized during both the August  and September efforts.   During the
September sampling  an Applied Micro Systems STD-12 was  also  used to
collect  backup  data  as  a  result  of  problems  encountered  during
August.   Due to  either  a recorder  malfunction or a  bad  data tape,
only 14  hydrographic casts were obtained during the August sampling.
During  September,  a  total  of  31 hydrographic casts were  obtained
 (refer  to Table  2-1  and Figure  2-1  for station  locations).    In
addition to  the CSTD data,  discrete water samples  were  obtained for
temperature, pH,  salinity, and dissolved oxygen.

During the August sampling  the only CSTD  data  obtained  was  from the
inner cove transects  #1 and  #2,  and  from the outer transect #5,  plus
Stations 50, 51,  and 4-3.  The inner transect near the mouth of Ward
Creek showed a  strong pycnocline  near  the surface as a result of the
fresh water runoff.   The  brackish surface layer had salinities of 5-
10  ppt  and  temperatures  of  14-15.5  °C.   DO  was  at 80-90  percent
saturation  in  the  brackish  surface  layer near the  mouth  of  Ward
Creek,  but  quickly  declined  with distance from  the  creek and  with
depth  (Figure  3-1) .  At 1-2 m  depth a minimum in DO occurred at all
of  the  inner stations.   DO  then increased from  around  3-6 m before
declining again near the  bottom.   The  trend in the DO profiles seems
to  have  been a  near surface minimum and a  bottom minimum.  The lowest
values  in  DO found  at any  of the inner  profiles was  at Station 1-1
where bottom values were  0.0 mg/L in  the titrated  samples  (Table 3-
 1).  At  the same  station ADEC found a bottom DO level of 0.3 mg/L and
the Ketchikan Pulp  Company found a bottom  DO level of 0.4 mg/L.

At  the  outer stations in August, a pycnocline existed at around 5 m
depth as a  result of both a thermocline and halocline at that depth.
Salinities  increased from 23  ppt at  the  surface to 28 ppt  at  10 m
depth  (Figure  3-2).  Similarly, temperatures decreased from 15 °C at
the surface  to 12 °C  at  10 m depth.   The DO at most of the stations
had a  similar pattern to that  found at the inner stations,  a slight
depression  was found near the  surface with moderate values  near mid
depth and lower values near the bottom.  pH at  the outer stations was
higher  than that at the  inner  stations ranging from 7.5 to 8.0 pH
units.    Refer to  Appendix  A for  plots  of  all  hydrographic  data
 obtained and to Appendix B for  data listings.

 During the September sampling, hydrographic surveys of Ward Cove were
conducted on  two consecutive days, 20  and 21  September  with most of
the same stations being covered.   Hydrographic data from stations in
the inner  cove  were  similar  to  those  found  during the August
 sampling.   Surface waters  showed a freshwater  influence  from Ward
Creek,  however the signal  was  not  as  strong as  during  the August
                                 A-9

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>
 I
       20-
       25-
       30-1
                                 X Light Tronamittance
                                  4           6
                                Dissolved Oxygen (mg/L)
                                     4             6
                                    pH (pH units)
                                        8
                      10
                                Density Excess (Sigma—t)
                             10           15          20
                                   Salinity (p.p.t)
                                15         20
                                                     25 '
                             10
                                 Temperature (Deg. C.)
                                           12
                                                                      10
                                                                      10
                                                                   25
- — — Dissolved Oxygen


 — —  % Light Transmrttance
                                                                                              5 -
                                                                                             ID-
                                                                                             15-
                                                                                             20-
                                                                                             25-
                                                                                             30-J
                                                                          % Light Transm'rttonce
                                                                           4           6
                                                                         Dissolved Oxygen (mg/L)
                                                                              4             6
                                                                             pH (pH units)
                                                                                 8
                                                                         Density Excess (Sigma—t)
                                                                       10           15
                                                                                               20
                                                               10
                                                                            Salinity (p.p.t)
                                                                         15        20
                                                                                              25
                                                                          Temperature (Deg. C.)
                                                                      10            12
                                                                                                 14
                                                                                                                                        ,PH
                                                                                                        30
                                                                                                               10
                                                                                                              10
                                                                                                            25
- — —  Dissolved Oxygen


 — — - % Light Transm'rttance
                                                                                                              16
                 Date=08/21/88  Station=1-2  Time=1645
                                                          Date=08/21/88  Station=1-1  Time=1630
     3-1.   Hydrographic profiles  at  inner  stations  during August 1988.

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Table 3-1.  Water Samples From Hydrographic Stations.
Date
August 21

























August 22



August 23











Station
1-1
1-2
2-1,2-2


2-3


2-4


2-5
3-1

3-2
3-3
3-4
3-5
4-1
4-2
4-3
5-1
5-2
5-3
5-4
5-5
3-1
3-3
3-5
4-1
5-5
1-1
1-1


1-2

2-3

3-2




Depth
(m)
1.0
1.0
0.5
5.0
9.0
0.5
5.0
13.0
0.5
5.0
10.0
1.5
0.5
Bot
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
Bot
1.0
1.0
1.0
1.0
1.0
Bot


2.0

1.0
6.0
0.5
5.0
21.0


DO
(mg/L)
5.80
5.45
4.94
7.62
7.28
6.19
7.18
6.15
7.48
7.87
7.90
7.29
-
-
-
-
-
6.19
-
-
-
-
-
-
-
—
5.40
5.78
5.12
6.42
6.72
6.51
0.0
0.0
0.0
5.80
5.30
5.31
7.66
5.10
7.75
3.25
3.14
2.76
Salinity
(PPt)
_
-
-
26.075
30.262
22.116
24.907
27.779
23.901
20.447
20.434
-
-
-
-
-
-
-
-
-
-
-
-
-
-
—
-
-
-
—
-
-
-
-
-
-
-
23.901
26.075
30.262
30.342
30.349
Temperature
(°C)
_
-
14.7
14.1
14.0
14.9
14.3
13.0
15.0
14.5
13.5
-
15.1
14.5
15.0
14.8
15.0
15.1
14.8
14.5
15.0
-
-
14.2
14.5
14.2
-
-
-
—
-
-
-
-
-
-
-
-
-
-
-
~
pH
_
-
7.10
7.73
7.71
7.15
7.71
7.85
7.28
7.57
7.83
-
6.46
7.31
7.45
7.47
7.29
7.19
7.22
7.43
7.15
7.30
7-78
7.77
7.84
7.85
-
-
-
—
-
-
-
-
-
-
-
-
-
-
-
~
                                   A-ll

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Table 3-1.  (Continued)
Date Station
Sept. 20 1-2
2-1

2-3

2-5

3-1

Sept. 21 1-3
2-1


2-3




3-1

4-2


BOD #1
BOD #2
Depth
(m)
0.5
8.0
0.5
8.0
0.5
16.0
0.5
9.0
0.5
Bot
0.5
Bot
0.5
5.0
Bot
0.5
5.0
Bot


1.0
11.0
1.0
5.0
Bot
0.5
0.5
DO
(mg/L)
6.19
5.29
5.74
2.83
5.83
4.14
5.86
4.62
5.16
2.32
5.29
4.59
5.61
4.55
6.24
5.38
5.18
2.73
2.38
3.07
5.51
0.38
5.18
6.59
4.55
5.89
4.01
Salinity
(Ppt)
28.115
23.380
29.037
21.862
29.375
22.653
28.901
23.716
23.388
21.007
27.655
22.293
25.777
27.189
22.002
25.695
29.607
29.700
29.637
22.668
29.125
23.128
26.208
31.986
-
Temperature pH
(°C)
- -
- -
- -
- -
- -
- -
- -
- -
— —
- -
- -
- -
- -
- -
- -
- -
- -
- -
- -
- -
- -
- -
- -
- -
                                 A-12

-------
       10-
       20-
 I
I—•
U)
       40-
       50-
       60-1
                                  S Light Tranamrttance
                                   4           6
                                                                        10
                                 Dissolved Oxygen (mg/L)
                                     4             6
                                     pH (pH units)
                                         8
                                                                        10
                                 Density Excess (Sigma-t)
                                           15
                                                        20
                                                                     25
                      10
                                    Salinity (p.p.t.)
                                 15        20
                                                      25
                                                                 30
                              10
                                  Temperature (Deg. C.)
                                            12
                                                          14
                                                                       16
- Temperature

• Salinity

 Sigma—t
- — — — Dissolved Oxygen

 — — —  % Light Transm'rttance
                                                                                                10-
                                                                                                20-
                                                                                              S- 30-
                                                                                              e
                                                                                                40-
                                                                                                50-
                                                                                                60-1
                                                                                            % Light Transmittanco
                                                                                             4           6
                                                                                                                                  10
                                                                                           Dissolved Oxygen (mg/L)
                                                                                                4             6
                                                                                               pH (pH units)
                                                                                                   8
                                                                                                                                                                10
                                                                                                                       10
                                                                                           Density Excess (Sigma— t)
                                                                                                     15
                                                                                                                                                 20
                                                                                                                                                             25
                                                                                                               10
                                                                                              Salinity (p.p.t)
                                                                                           15         20
                                                                                                                25
                                                                                                                           30
                                                                                        10
                                                                                            Temperature (Deg. C.)
                                                                                                      12
                                                                                                                                                  14
- Temperature

• Salinity

 Sigma-t
                                                                                                                                            , pH
- — — - Dissolved Oxygen

 •- — — % Light Transmrttance
                                                                                                                                                                16
                 Date=08/21/88  Station=5-4  Time=1225
                                                                           Date=08/21/88  Station=4-3  Time=1245
          3-2.    Hydrographic profiles  at  outer stations  during  August  1988.

-------
X Light Transmittance
0 2 4 6 8 10
Dissolved Oxygen (mg/L)
02468
pH (pH units)
678
9 10
Density Excess (Sigma— t)
5 10 15 20 25
0 -

5 -
-
> 10-
I
E X -
f 15-
O
Q
0
20-
25-
Salinity (p.p.t)
5 10 15 20
Temperature (Deg.
8 10 12
__?'"
\ /
__ / /
/ " /






— ^— — Salinity - -
25 30
C.)
14 16
" ^"^^ "" N
\\ ^
' \ -

u >*
'•\'^
'• 1 X






— — Dissolved Oxygen
— — % Liaht Transmrttance
                                                                             5 ^
                                                                           &
                                                                           a
                                                                           G
                                                                             20 H
                                                                             30-1
                                                                                                    X Ught Tron«mJttonc«
                                                                                                     4          6
                                                                                                                                      10
                                                                                                   Dinotved Oxygon (mg/L)
                                                                                                        4           6
                                                                                                       f>H (pH unrai)
                                                                                                           8
                                                                                                                                      10
                                                                                                 10
                                                                                                   Density Exc**» (Sla.mo-t)
                                                                                                             15
                                                                                                                        20
                                                                                                                                    25
                                                                                          10
                                                                                                       Sonntty (p^J.t.
                                                                                                    15        20
                                                                                                                       25
                                                                                                                                30
                                                                                                    Temperature (Deg. C.)
                                                                                                 10           12
                                                                                                                          H
                                                                                                                                      16
           • Temperature


           • Salinity


            Sigma—t
                                                                                                                    'PH
•	Disaohrad Oxygen


 — -• • X Ught Tronsmittance
        Date=09/20/88  Station=2-1   Time=1120
Date=09/20/88  Station=2-2  Time=ll38
3-3.   Hydrographic profiles at inner stations  during September 1988.

-------
  10-
  20-
o
o
—
  40-
  50-
  60-1
                            X b'ght Transmrttance
                             4            6
                           Dissolved Oxygen (mq/L)
                                4             6
           pH (pH units)
7               8
                                                                  10
                         10
                           Density Excess (Sigma-t)
                                      15
                 10
                               Salinity (p.p.L)
                            15         20
                         10
                            Temperature (Deg. C.)
                                                  20
                                                               25
                                                 25
                                                           30
                                                    14
                                                                  16
     - Temperature

     • Salinity

      Sigma—t
                                              pH
- — — Dissolved Oxygen

 — — • X Light Transmrttance
                                                                                          10-
                                                                                          20-
                                                                    a. 30-
                                                                    a
                                                                    a
                                                                    t—
                                                                    o
                                                                                          40-
                                                                                          50-
                                                                                          60 ->
                                                                                                % Light Tronsmrttance
                                                                                                 4           6
                                                                                               Dissolved Oxygen (mg/L)
                                                                                                    4            6
                                                                                                                       pH (pH units)
                                                                                                                           8
                                                                                                         10
                                                                                               Density Excess (Sigma—t)
                                                                                             10           15
                                                                                                   Salinity (p.p.L)
                                                                                               15         20
                                                                                                                 10
                                                                                                Temperature (Deg. C.)
                                                                                                          12
                                                                                                                                          20
                                                                                                                                        25
                                                                                                                                           14
- Temperature

• Salinity

• Sigma—t
                                                                                                                                      pH
                                                                                                                                     10
                                                                                                                                                         10
                                                                                                                                                       25
                                                                                                                                                   30
- — — — Dissofved Oxygen

 — — -• % Light Transmrttonce
                                                                                                                                                         16
            Date=09/21/88   Station=4-2  Time=1600
                                                                               Date=09/21/88  Station=5-1   Time=1445
   3-4.    Hydrographic profiles at  outer  stations  during September  1988.

-------
0.0
12.0     24.0     36.0     48.0     60.0
                     TIME  (hours]
                                                           72.0    84.0    96.0
3-5.  Predicted tides for Ketchikan, AK, 0000 hr 8/20/88 to 0000 hr 8/24/88.

-------
        ward  cove    8/20/88    surface  drog
                                                                      :&?**•  ^
                                                                             S = Start, of Drogue Track
                                                                             E = End of Drogue Track
                                                                            0   0.1   0.2   0.3   0.4  0.5 Kllom«t«r«

                                                                                                      0.3 Naut. Mile*
3-6.   Surface drogue trajectories on 20 August 1988,

-------
        I	1	1	1	1
        ward cove   8/20/88    15m  drogues
                                                                          S = Start of Drogue Track
                                                                          E = End of Drogue Track
                                                                         0   0.1   0.2  0.3   0.4  0.5 Kilometers

                                                                                                  0.3 Naut. Miles
3-7.  is-m drogue trajectories on 20 August 1988,

-------
sampling   (Figure   3-3).     Temperatures  however   were  much  more
isothermal than in August ranging from around 12-13 °C at the surface
to 11  °C at depth.  pH varied between 7.0 and 8.0  pH units with the
lowest values  found in either the oxygen  depleted  surface layers or
bottom layer.  DO  at the  inner stations were found to have a minimum
a short distance above the bottom.

The  outer deeper  stations  exhibited a  fairly strong  pycnocline at
around 10 m depth  dominated  mainly by the salinity signal  (Figure 3-
4) .    A  most  stations  their  was   no  real  distinct  thermocline,
temperatures decreased linearly with depth from around  13  °C at the
surface  to around  8 °C  at  the  bottom.   An  exception to  this was
station  5-1  along the north  shore  near the mouth  of the cove where
surface  temperatures of  15.38  °C were  found.   Salinity and  pH had
surface  minimums of 15.90 ppt and 7.01 pH units respectively  (Figure
3-4).  The main effluent discharge from the pulp mill is routed along
the  northern shore  of the cove by a  series of log containment booms,
discharging  near Station 5-1  resulting in higher  temperatures,  and
lower salinities and pH's.  No DO data was available for that site.
DO  at  the deeper outer stations  generally decreased with depth from
5-8  mg/L at  the surface to  1-4  mg/L at depth.    Titrated DO values,
salinities,  pH's,  and temperatures  -for various depths  and stations
are  presented  in  Table  3-1  for  both  the  August and  September
sampling.

3.1.2  Drogue Study

Drogue studies were conducted on two separate days during the August
sampling.  The  first day  was a limited effort conducted on 20 August
over a 2.5 hour period of rising tide and  light wind conditions.  The
second drogue  experiment was conducted  on 23  August over a complete
tide cycle and moderate wind conditions.

Two  pairs of  drogues were  released on 20  August on  a flood tide.
Each pair consisted of  a  surface  drogue and a  15-m  drogue.   The
drogues  were  released in  pairs to examine  how  the  deeper layers
within Ward  Cove were moving in relation to the surface waters.  The
drogues  were released beginning at  1314 hr  on 20  August with all of
the  drogues  being  picked up by 1543.   The  tide was flooding with a
low  of 5.0 ft at  1047 hr and  a high of  13.5  at  1708 hr  (NOS 1987)
 (Figure  3-5).    The  surface drogues  indicated a  counter clockwise
circulation  pattern  (Figure  3-6).    Drogue  #8 traveled parallel to
shore  towards  the  northeast  before  encountering  some log rafts near
Holies Ledge.   Drogue #7  first headed towards shore then looped back
and  started heading  towards  the south.      The  deeper  15-m depth
drogues  showed  very  little movement  (Figure 3-7).    Both  drogues
traveled in  counter clockwise  patterns at  their respective  deployment
sites.      Winds  at the  Ketchikan Airport on 20 August were  calm in
the  morning  picking  up  to  5-7  knots  from  the  southeast  in the
afternoon.   Winds  at Ward Cove  were also light,  but were from the
southwest as a result of  local  topographic steering.

The  second drogue  experiment conducted  on  23 August  was much  more
extensive than the first effort.   The  study consisted of  following


                                A-19

-------
four pairs of drogues,  surface  and 15  m depth,  over a complete tidal
cycle.  If the  drogues  encountered shore or any log rafts, they were
picked  up and  redeployed  at  a  new  location.    Drogue  pairs  were
initially deployed with  one  pair  near  the mouth  of the  cove,  two
pairs  across  from  each other along  a  transect  starting at  the
cannery,  and the  last  pair was deployed  further up  into the cove.
The upper third of the cove was not used during the drogue studies as
it was almost completed covered by log rafts.

The  drogue  pairs were  all  deployed between  0830 and 0900  hr on 23
August.   Deployments were made approximately one hour preceding the
high  tide of 11.2 ft at  0942 hr  (NOS  1987)  (Figure 3-5).  The three
surface drogues that were  deployed in  the outer  part  of  the  cove
(#4A,  #11A,  and #7A) traveled towards the mouth  of the cove  (Figure
3-8) .   The  inner  most  surface  drogue, #5, traveled  in  the opposite
direction towards the northeast  before encountering  a  log raft and
being accidently destroyed during recovery operations.     The  15-m
depth drogues  (#9A,  #8A,  #20, and  #17A) all traveled toward the inner
part  of the cove after their  initial deployments  (Figure  3-9).  Winds
were  fairly  calm at  Ward Cove on  the morning of 23 August increasing
to  5-10  knots  from  the  southwest in the  late morning.   Since the
winds were  fairly  calm after the initial  deployment,  the  drogue
movements would have been due to tidal influences.  Upon  examination,
it  seems  that  the surface  waters  had started  to  ebb prior to high
tide, while water  at depth was  still flooding.

Later in  the morning on 23 August after the wind  had picked up and
the  tide  had turned the surface  drogues were driven  mainly by wind
forcing.  Both #7A  and  #11A  were  forced into  shore near the cannery
by  the winds.   Upon  redeployment  in front  of  the  cannery  #11B
traveled  toward  the  northeast  before encountering  a  log  raft.
Drogue  #7B  was redeployed  at its original start location.   It also
traveled  towards  the  northeast along  with  surface drogues  #4B and
#11C.   Since the tide was ebbing at this time,  these  movements would
indicate  the wind  to be  the major  forcing mechanism.

The  15-m  drogues were somewhat  less dependent on the wind conditions.
Drogue  #20  closely  followed the  tidal forcing,  moving towards the
inner part  of  the cove  during flood,  then heading  back out during
ebb,  and  finally  reversing again  during the flood  at 1530 hr.   The
low  tide  in  the afternoon was 5.7  ft at  1455 hr (NOS 1987).  A couple
of the other 15-m drogues (#9B and #17B) indicated a  counter  flow at
depth to  that observed at the  surface as  a result of the wind setup
along the northern  shore of  the  cove.    Drogue #8A traveled towards
the  northeast  during  its whole deployment  before  encountering some
log  rafts at 1500  hr.   Its  initial movement probably was due to tidal
forcing with wind forcing  becoming more important during the second
half of its  trajectory.

3.1.3  Stream Discharge

The  fresh water  discharge  of Ward Creek  was  monitored  twice during
the   short-term  intensive  studies.     Discharge   measurements  were
performed on 20 and  23 August 1988.  A Montedoro-Whitney Model PVM-2A


                                 A-20

-------
                                                                           S = Start of  Drogue Track
                                                                           E = End of Drogue Track
3-8.  Surface drogue trajectories on 23 August  1988.

-------
                   3O
           ward   cove    8/23/88    15m  drogues
                                                                                  S = Start of Drogue Track
                                                                                  E = End of Drogue Track
                                                                                                                          30"
                                                                                                                         55°'
                                                                                                                          24'|
                                                                                 0   0.1   0.2   0.3   0.4   0.5 Kilometer*

                                                                                                           0.3 Naut. Miles
0.1
0.2
L
 3-9.   15-m drogue trajectories on  23  August  1988.

-------
electromagnetic flow meter  was  used to measure stream velocity along
each  cross  section.    Horizontal  distances  were  measured with  a
surveyors  tape and water  depths  were measured  with a  stadia rod.
Velocity measurements were taken every 5 ft along each cross section.
At  the  time of  the measurements  the discharge  rate was relatively
low, therefore the stream could be waded to obtain the measurements.

Ward Creek empties into upper  Ward Cove via two  channels,  with the
southern channel  carrying the majority  of  the flow.    On 20 August
the discharge  rate in  the  north and  south channels were 1.3  f t3/s
(0.8 mgd)  and  33.4 ft3/s (21.6 mgd)  respectively (Table 3-2).   Thus
the two channels had a total freshwater discharge of  34.7  ft3/s (22.4
mgd) compared  to the total  pulp  mill discharge  of  57.7 ft3/s  (37.3
mgd)  (Table 3-2).   Discharge  into Ward Cove  on 23 August was 2.6
ft3/s  (1.7 mgd)  through the  north channel,  62.7  ft3/s  (40.5 mgd)
through the south channel,   and 61.7  ft3/s  (39.9 mgd)  from the pulp
mill  (Table 3-2).   Precipitation  during the August survey was low
ranging from 0.0 to 0.08 in/day, thus  attributing to the relatively
low stream discharge rates  during this period.

Based  on  visual  observations,  the  north  channel  would  have been
impassable to  migrating salmon  at the time  of the survey.  The south
channel  however  was  of  sufficient  depth   (1-2  ft in  the deepest
channel) to allow  fish to pass upstream.  These observations extended
only 200-300 m upstream from the mouth.

Dissolved  oxygen measurements  were made from  a small  skiff at the
mouth  of   Ward Creek  in  the surface waters  below  high  tide level.
Concentrations were 8.74 mg/L on 21 August,  8.38 mg/L on 23 August,
and  7.69  mg/L on  20  September  1988.   Saturation conditions for the
water  sampled were 9.71 mg/L  at 15.4  °C  and 4.5  ppt  salinity for
August, and 9.28  mg/L at 12.0 °C and 23.5 ppt salinity for the water
sampled in September (Unesco 1973).   It is  believed that the  water
sampled was lower than the  saturation  values as  a result of partial
mixing with the  cove  waters.  Due to the turbulent  conditions in the
stream it  can  be assumed that the Ward  Creek  water was at  100 percent
saturation of 10.06 mg/L at 15.0 °C and 0.0 ppt salinity in August
and 10.75  mg/L in  September.

3.1.4  Bottom  In Situ Oxygen Demand

The in situ benthic oxygen  demand chamber was deployed at  three sites
during  the September sampling.   During the  August  sampling,  a data
logger malfunction resulted in  the loss of all data.  The sites were
located offshore of the Ward Cove  fish  processing plant  (Station BOD-
2);  near  the mouth of Ward Creek (Station  BOD-3);_and near the pulp
mill's main effluent outfall (Station BOD-4)  (refer  to Figure 2-1 and
Table  2-1  for station  locations).   Station  BOD-1  was  a QA/QC test
station  at  the  pulp mill's dock  where only  surface  readings were
obtained.

The dissolved oxygen within the  chamber was found  to  fall the most
rapidly  at Station BOD-3  near the mouth of Ward  Creek  followed  by
Station  BOD-4 near the pulp mill's effluent discharge.   The  lowest


                                  A-23

-------
Table 3-2.  Pulp Mill and Ward Creek Discharge Rates.
Discharge Location
Ketchikan Pulp Mill:
Main Effluent
Primary Effluent
Secondary Effluent
Filter Plant
Total Discharge
Ward Creek Discharqe:
20 August
(mgd)

12.3
14.3
5.3
5.4
37.3

21 August
(mgd)

14.9
12.0
5.3
5.4
37.6

22 August
(mgd)

16.5
12.9
4.9
5.4
39.7

23 August
(mgd)

18.0
11.3
5.2
5.4
39.9

  North Channel




  South Channel




  Total Flow
21.6




 0.8




22.4
40.5




 1.7




42.2
                                   A-24

-------
rate was measured offshore of the fish processing plant.  The rate of
decrease  at Station  BOD-3  was 1.0  mg/L per  hour  with DO  levels
dropping  from  3.57  mg/L to 1.08 mg/L over a  2.5 hour period (Figure
3-10) .    The rate of  DO decrease at  Station  BOD-4 was much less at
0.24 mg/L/hr,  however  the initial  CO level was  only  0.80 mg/L.   The
rate of decrease at Station BOD-2 was 0.08 mg/L/hr, dropping from 2.5
mg/L to 1.7 mg/L over a 9.5 hour period.

The volume of the in situ benthic oxygen demand chamber was 10 liters
with a bottom surface area of 730 cm2.  The above DO demand rates can
then be converted  into respiration rates per  unit  area of bottom.
The  respiration  rates  were 11.0 mg of  DO per square  meter of bottom
per  hour  (mg/m2/hr) at Station  BOD-2,  137.0 mg/m2/hr  at Station BOD-
3, and 32.4 mg/m2/hr at Station BOD-4.

3.1.5  Primary Productivity

Primary productivity  measurements  were made  at  six sites during the
August  sampling.   Five sites were  located  within Ward Cove and the
six  site was  located  on the  western  side  of  the  Tongass Narrows
(refer  to  Figure  2-1  and  Table  2-1  for  station  locations.    The
primary productivity  and  uptake rates at all  stations were quite low
(Table 3-3) .   In most cases, less than  1 mgC/m-^/hr was taken up.   The
highest measured rates were those  measured  at Station PI, outside of
Ward Cove  on the  west  side  of  Tongass  Narrows.    Even  those
measurements are relatively low (1.6 and 3.3 mgC/m3/hr at 1 m depth
and  0.1  and  0.6   mgC/m^/hr at  5 m  depth)  .    Given the  inherent
uncertainties  in the techniques for  estimating  primary productivity
paired with such low  uptake rates,  it is difficult to compare uptake
results from station to station within  Ward Cove.

The  "dark"  bottle counts  in the Ward  Cove samples are often a very
significant portion  of  total  counts  in the  "light" bottles  even
though  the  total counts are low in both bottles.  Normally, in areas
of high uptake rates by photosynthesis, the dark blank is less than 5
percent of  the fixation of radioactive  carbon measured in the "light"
bottles.    Where the  primary productivity  is relatively  low,  as in
these  samples, the dark bottle activity  can be  a very significant
portion of  the total uptake  of  radioactive carbon.

Dark bottle  uptake  of  14C-bicarbonate  may  occur  as  a  result of
bacterial activity.    In  polluted waters where huge  quantities of
bacteria   are   found,  dark  fixation,   dark  fixation  may  be  of
extraordinary  importance  (Steemann-Nielsen  1975).  It has been noted
by several  other authors  (Morris et al.  1971; Taguchi and Platt 1977;
and  Tuttle  and Jannasch 1977) that dark bottle uptakes in other study
areas  have  been  quite  high  and  have even exceeded  light bottle
uptakes.    Tuttle  and  Jannasch  (1977)  attributed  this  to  bacterial
activity.   It  has been shown that bacterial activity  can  be  inhibited
by  even  very  low  light  intensities  (Jorgensen  and  Steemann-Nielsen
1960) .    Thus   ,  if  bacterial  activity  is  inhibited  in  the light
bottles   yet   proceeds  in  the  dark  ones,   when  dark  bottles  are
subtracted  from the   light  bottles,  primary  productivity  can be
underestimated.
                                  A-25

-------
I
M
            0.0
2.0
                                            STRTIGN BGD-2
                                            STRTIGN BOD-3
                                            5TRTIGN
14.0     6.0     8.0
  TIME  (hours)
10.0
12.0
         3-10. In situ benthic oxygen demand during September 1988.

-------
Table 3-3.  Primary Productivity Rates.
Date    Station  Depth   Decays per  Total CO2     W        P.P.      Uptake
                   (m)      Minute      (meq/L)   (mgC/m3)  (mgC/m3-hr)  (mgC/m3-hr
8/20/88 PI



8/21/88 PI



8/20/88 P2



8/20/88 P3



8/20/88 P4



8/20/88 P4@P3

8/20/88 P5

8/20/88 P6@P3
r
1-L
1-D
5-L
5-D
1-L
1-D
5-L
5-D
1-L
1-D
5-L
5-D
1-L
1-D
5-L
5-D
1-L
1-D
5-L
5-D
1-L
1-D
1-L
1-D
1-L
1-D
5159.0
492.1
642.1
479.7
13412.4
399.1
2648.6
685.6
1282.0
1136.8
642.7
805.9
807.2
757.6
735.6
715.8
2086.4
1491.3
1181.4
1310.7
1469.5
1052.8
1771.0
536.3
1628.3
1413.8
1.6
1.6
2.0
2.0
1.6
1.6
2.0
2.0
1.5
1.5
1.6
1.6
1.5
1.5
1.7
1.7
1.5
1.5
1.7
1.7
1.5
1.5
1.5
1.5
1.5
1.5
1.9E+04
1.9E+04
2.4E+04
2.4E+04
1.9E+04
1.9E+04
2.4E+04
2.4E+04
1.8E+04
1.8E+04
1.9E+04
1.9E+04
1.8E+04
1.8E+04
2.0E+04
2.0E+04
1.8E+04
1.8E+04
2.0E+04
2.0E+04
1.8E+04
1.8E4-04
1.8E+04
1.8E+04
1.8E+04
1.8E+04
1.6
0.0
0.1
0.0
3.3
0.0
0.6
0.0
0.0
0.0
-0.1
0.0
0.0
0.0
0.0
0.0
0.2
0.0
0.0
0.0
0.1
0.0
0.3
0.0
0.1
0.0
1.7
0.2
0.3
0.2
3.4
0.1
0.9
0.2
0.4
0.3
0.2
0.3
0.3
0.2
0.3
0.3
0.5
0.4
0.3
0.4
0.5
0.3
0.5
0.1
0.5
0.4
 *  L = average  of 2  light bottles
   D = dark bottle

 14C-measured photosynthesis (mgC/m3-hr)  = [ (Rs  -  Rb)  x W x 1.05]/(R x N)
      where Rg  = DPM in the light bottle
            Rb  = DPM in the dark bottle
             W  = weight of carbonate carbon present in the water (12,000 x
                 Total Carbon Dioxide in mgC/m3).   Total  CO2  is calculated  fro
             sample salinity according to procudures  in Strickland and
                 Parsons (1972).
             R  — total activity of bicarbonate added to each bottle (5 uCi =
                 1.11 x 107 DPM)
             N  = incubation time in hours
                                   A-27

-------
Sediment Chemistry Station Coordinates.
Sediment Chemistry
300/2-4 8/22
301/5-1
302/5-3
303/5-5
304/4-3
305/4-2
306/4-1
307/6-1
308/6-2
309/3-1
310/3-2
311/3-3
312/3-5
312/3-5
312/2-3
313/1-2
314/1-1
315/2-2
315/2-1
316/6-JZ.5
Sediment Chemistry
50-2 9/20
50-4
50-5
40-3
40-1 '
B
A
10-1 9/21
10-0
10-0
20-1
20-1
20-1
30-1
60-1
60-1
60-1
Stations
55
55
55
55
55
55
55
55
55
55
55
55
55
55
55
55
55
55
55
55
24'
23'
23'
23'
23'
23'
24'
24'
24'
24'
24'
24'
24'
24'
24'
24'
24'
24'
24'
24'
- August
20
52
45
50
53
58
5
5
13
20
16
10
6
6
15
23
26
23
25
23
Stations -
55
55
55
55
55
55
55
55
55
55
55
55
55
55
55
55
55
23'
23'
23'
23'
24'
24'
23'
24'
24'
24'
24'
24'
24'
24'
24'
24'
24'
49
44
48
54
2
3
58
25
27
27
28
28
28
24
17
18
15
.4'
.4'
.5'
.5'
.9'
.2'
.2'
.5'
.8'
.1'
.1'
.8'
.5'
.1'
.2'
.8'
.9'
.5'
.8'
.9'
'
'
'
'
'
'
'
'
'
/
/
/
/
/
/
/
'
/
/
/
131
131
131
131
131
131
131
131
131
131
131
131
131
131
131
131
131
131
131
131
43
44
44
44
43
43
43
43
43
43
43
43
43
43
43
43
43
43
43
43
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
i
i
i
i
i
8
25
18
10
40
44
48
51
46
40
35
29
22
22
23
9
14
20
24
31
.0'
.5'
.0'
.6'
.1'
.2'
.2'
.1'
.9'
.0'
.2'
.8'
.5'
.2'
.6'
.0'
.7'
.6'
.7'
.9'
'/
'
1 '
1 '
' '
1 '
'
'
'
'
'
' '
'
' '
'
' '
'
'
r
i
September
"
.3'
.9'
.9'
.0'
.5'
.9'
.6'
.3'
.4'
.3'
.2'
.4'
.0'
.3'
.0'
.5'

/
/
/
/
/
/
/
/
/
/
/
/
'
/
/
/
131
131
131
131
131
131
131
131
131
131
131
131
131
131
131
131
131
44
44
43
43
43
43
43
43
43
43
43
43
43
43
43
43
43
r
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
19
5
48
37
50
39
31
4
13
14
17
17
17
29
40
40
47
.2'
.2'
.8'
.9'
.0'
.1'
.2'
.3'
.3'
.3'
.2'
.5'
.3'
.4'
.8'
.0'
.1'
• i
' i
• i
• i
• i
t
• t
' i
• i
• i
' r
• i
• i
' /
• i
' '
' i
                                  A-28

-------
Without a much more intensive research effort, it is hard to say what
the productivity regime is within Ward Cove.  However with all of the
observed  anoxic areas with  production of  hydrogen sulfide  and the
dark  color of  the  water as  a result  of  industrial waste  or humic
acids, it  is possible that bacterial  activity is a large contributor
to the uptake  of ^-4C-bicarbonate.  What  can be  said  about  the Ward
Cove productivity is  that it  is  quite low,  and after subtracting out
the  dark bottle uptakes,  the primary  productivity is near  zero at
most  stations.   The  productivity measured  outside of Ward  Cove, at
Station PI, is  much higher than  at the stations inside of Ward Cove.
Also the dark bottle  uptake  at Station PI  is a much smaller fraction
of the light bottle uptake than at other stations.
                                  A-29

-------
          4.0  QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES


4.1  Obj ectives

The  objective  of  the  Quality  Assurance/Quality  Control  (QA/QC)
program is to assure that the  data  collected are of high quality and
to develop documentation to provide an assurance of the data quality.

The following definitions apply:

Quality Assurance;
Comprises  planned  and  systematic  actions,  including  audits  and
corrective  actions  necessary to  provide adequate confidence  in the
results of the sampling program.

Quality Control:
Comprises those  actions that provide a means  to control and measure
the  characteristics   of  equipment  and  processes  to  established
requirements or tolerances.

4.2  Field QA/QC Program

4.2.1  Documentation

Field  data sheets  were used  to record  both  field  data  and  QA/QC
program  data.    Field  logs  for  each program task   (hydrographic
profiling,  drogue tracking,  sediment sampling, etc.)  were printed on
waterproof  paper  and  supplied  to the  field  crews  in  three-ring
binders.   Completed field  logs will be  kept on file  for any QA/QC
checks.

4.2.2  Station Locations

All  positioning  for  hydrographic  stations,  sediment  stations,  and
drogue  movement  studies  was  accomplished by utilizing  a Motorola
MiniRanger   III   microwave  positioning   system  with  shore-based
transponders.   The MiniRanger  system  was  calibrated  prior to the
survey over a standard, known  1,000 meter range.  The accuracy of the
MiniRanger  was  determined by  positioning the vessel at three known
points  along  the shoreline.   These positions were cross-checked with
radar bearings and  visual sightings at the calibration  sites.

4.2.3  Field Instrumentation and  Sampling QA/QC

Conductivity,  salinity, temperature, depth  (CSTD)  profiles,  as well
as pH,  transmissivity,  and  dissolved oxygen profiles were taken with
an  InterOcean Systems  Model 513D  recording oceanographic profiling
system.   An Applied Microsystems Model STD-12 solid state recording
CSTD  was  also  utilized  for  additional  hydrographic  profile data.
Both of these systems  were  calibrated  prior  to  shipment  as per the
instructions of the manufacturers contained  in their respective users
                                  A-30

-------
manuals, using laboratory or electronic standards.   Both probes were
also  electronically  checked  immediately  before  deployment  in  the
field.

Salinity,  temperature,  pH,  and  dissolved oxygen values  recorded by
the  CSTD  probes were  checked  against discrete  water  samples  and
measurements  taken  simultanously  with  the  profiles.    All  water
samples  were collected  with  5-liter  Niskin  sample  bottles  at  the
surface, mid, and bottom depths.

Dissolved  oxygen (DO) samples were taken  from the  Niskin bottles,
fixed immediately onboard the  boat and then titrated approximately 6-
8  hours later using the Winkler technique  (Strickland  and Parsons
1972).   When the titrated  DO values are compared  to the calibrated
InterOcean  probe values there  is  some variance  from  the optimal
sitution  (Figure 4-1).  It  is  evident from examining the CSTD profile
plots that sharp vertical  gradients exist  for dissolved oxygen,  and
every  attempt was  made to retrieve a water  sample  as close to a
comparable  probe depth as  possible.   Yet because  the Niskin bottle
retrieves  a sample  over a  range  of  0.5 m in depth it is likely that
there was variability in depth where the water sample was  collected
when  compared to the depth that the probe value was recorded.  Also,
the  reponse time of  the  InterOcean DO sensor  is  not instaneous, so
recorded  values  may  not be  located  exactly at the  recorded depth.
This  error  was  minimized  by performing  slow  upcasts  on  the  CSTD
system.     These two factors probably  account   for  most of  the
variability seen.  Another  factor is that in areas  with high
organic  load there  are  possible  interference  problems   with  the
Winkler oxygen technique  (Strickland and Parsons 1972).

The  salinity samples were  placed in glass  containers equipped with
plastic lined screw caps  and sent to the laboratory  for salinity
determinations against Copenhagen standard  seawater  using  a Beckman
laboratory   salinometer.     Results   show   that   variance  between
laboratory measured  salinity  and those salinity  values  recorded by
the  InterOcean and  Applied Microsystem CSTD  probes  was minimal and
that  both probes recorded accurate data for this parameter throughout
the  study (Figures 4-2 and  4-3).

Both  pH  and temperature  calibrations  were determined  on discrete
samples in the field and were recorded using a Corning 105 portable
pH and temperature  meter.   Comparisons between the  portable pH and
temperature meter  and the  InterOcean  CSTD  probe values  show that
variability is minimal  (Table 4-1).   During the September  sampling,
the  Applied Microsystems CSTD was used to verify the accuracy of the
InterOcean CSTD  probe.

Sampling  variability was determined  for salinity and dissolved oxygen
by analyzing triplicate samples  taken  at the bottom of Stations  3-2
and  2-3.   Results shown  in  Table  4-2 indicate  that  although  there was
some  difference  between the  three  samples  taken at the bottom depth
for  salinity and DO, it was minimal  and in the case of DO, could be
                                   A-31

-------
I
GO
              CD
              O
               •
              r-
              o
           t	, to
            CD
            £
           o ">
           O

           LJJ
           CD _
           0 °
           DC
           UJ
           h-
              CO
              O

              CM
              O

                                                                                -f
               0.0     1.0     2.0      3.0      4.0     5.0     6.0      7.0     8.0

                                       TITRRTED DO  (mg/U
            4-1.   Titrated  dissolved oxygen values versus InterOcean STD values.

-------
 i
tAJ
CO
             o
              •

             en
             CM
             CO
             0
             CD
_J 00
O~ CM
CO
   CD

   CO*
          CD
          cr
          UJ
          DC _;-
             C\J
             CM
             4-
                                                      4-
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                                                 4-
4-
                      22.0     2U.O    26.0    28.0    30.0

                              LflBGRRTGRT SflLINITY  (ppt)
                                                      32.0
            4-2.  Discrete salinity sample values versus InterOcean STD values.

-------
   O

   en


   o
   c\j
   oo


^ o
 ^- o
 a en
Z 00
r—i C\J
_J
a:
CO
CO
C\J
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 i
a

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co  'H
^ CM
O

C\J
C\J
                                          •H-
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                          -H-
         22.0    21.0     26.0    28.0    30.0
                LRBGRRTORT SflLINITT  Cppti
                                                     32.0
3^70
  4-3.  Discrete salinity sample values versus Applied
        Microsystem STD values.

-------
Table 4-1.  Temperature and pH Variability Between Discrete
            Water Sample and InterOcean 513D STD Probe Values.
Station
Water*
Sample
Probe*
Variance
Temperature
5-3
5-4
5-5
4-3

5-1
5-2
5-3
5-4
5-5
5-6
14.20
14.50
14.20
15.00

7.30
7.78
7.77
7.84
7.85
7.15
14.36
14.27
14.17
14.81
PH
7.35
7.65
7.70
7.96
7.75
7.08
-0.160
+0.230
+0.030
+0.190

-0.050
+0.130
+0.070
-0.120
+0.100
+0.070
 * These measurements were taken at the surface.
                                 A-35

-------
Table 4-2.  Sampling Variability for DO and Salinity.
Station # Sample #*
3-2 A
B
C
Mean
Std. Dev.
2-3 A
B
C
Mean
Std. Dev.
DO (mg/1)
3.25
3.14
2.76
3.05
0.257
2.73
2.38
3.07
2.73
0.345
Salinity (ppt)
30.262
30.342
30.349
30.318
0.048
29.607
29.637
29.700
29.648
0.047
 *  Three discrete samples were taken from one
   Niskin bottle at the bottom.
                                  A-36

-------
attributed to  variable amounts of organic material  contained in the
three bottles.

Variability and calibration  checks of the InterOcean 513D probe were
done by performing triplicate profiles for salinity, temperature,
pH,  and dissolved  oxygen at one  station  (Table  4-3).   The  same
calibration check was performed  for the Applied Microsystems probe
with the exception  of dissolved oxygen that is  not  measured  by that
probe  (Table  4-4).   Results show that  salinity,  temperature,  and pH
variability  for  both probes  was not a problem.     There is  some
variability between casts for dissolved oxygen on the InterOcean 513D
probe.  This could be due to a delayed response time as the probe was
profiling.

Since   the  current  drogue   experiments  involved  measurements  of
position and time, the drogue positions were determined by use of the
MiniRanger whose  calibration  and quality assurance  procedures  have
just  been discussed  above.    Time  measurements were  calibrated  by
field members  synchronzing their watches before the study.

The  stream  flow meter  was  factory  calibrated and  electronically
calibrated  just  before  use.    Stream  cross-sectional  areas  were
determined by  using a portable flow velocity meter  according to the
standard U.S.G.S. procedures  (Rantz  1982a).

The   oxygen   probe   in  the   benthic  oxygen  demand  apparatus  was
calibrated in  the laboratory prior to  field use.   The oxygen sensor
was calibrated for a  zero reading using a NaSO3 solution and was also
adjusted using an oxygen saturation  calibration to  achieve a maximum
value  for  the sensor  range.   During the latter step the sensor was
placed  into  a bath  of  saturated freshwater  at 22°C.   The  sensor
output  was then calibrated to standard values of saturated water at a
given  temperature and salinity.   In the field,  calibration  against
the Winkler method  was done at a test  station  next to the pulp mill
dock  just prior to  emplacement at the first BOD station.  The sensor
recorded  6.29  mg/L at 12.85°C  at the surface while  the titrated DO
value  at  the  surface was 5.89 mg/L  at  approximately 11.83°C.   These
DO values are  in relative agreement  given the fact that if the sensor
had  equilibrated  longer at  the surface the  recorded temperature and
DO would have  been lower and closer  still to the titrated value.  The
benthic oxygen demand appartus also  was  calibrated in the laboratory
after  use in  the  field.    A saturated  freshwater  sample taken  at
18.1°C  was  measured  with the  oxygen sensor.    The sample was  then
titrated.  The results were very close with the sensor reading 9.03
mg/L and the titrated value being 9.09 mg/L.

At each primary  productivity  station  two samples  were taken  with
clear   bottles while a  third  dark bottle  was  used  as  a  non-
phot osynthetic uptake  blank.    The  two clear  bottle  uptakes  were
averaged and  the  mean compared to the  light bottle uptakes.   In all
cases the two  light bottle uptakes were within 10 percent of the mean
except  for Station P4(lm) which was  within 20 percent.
                                 A-37

-------
Table 4-3.  InterOcean Probe Variability Check - Triplicate Casts.
Depth (m)
Cast 1
Cast 2
Cast 3
Mean
Std.
Dev-
Coeff. of
Variation
Temperature
2.4
4.1
5.5
7.0
8.4
10.1
11.5
13.0
14.4
16.0
17.4
18.2
12.49
12.37
12.11
11.86
11.48
11.10
10.77
10.58
10.41
10.32
10.27
10.32
12.47
12.34
12.09
11.82
11.47
11.06
10.76
10.55
10.40
10.30
10.30
10.30
12.47
12.33
12.14
11.90
11.46
11.04
10.74
10.55
10.39
10.30
10.27
10.30
12.48
12.35
12.11
11.86
11.47
11.07
10.76
10.56
10.40
10.31
10.28
10.31
0.012
0.021
0.025
0.040
0.010
0.031
0.015
0.017
0.010
0.012
0.017
0.012
0.093
0.169
0.208
0.337
0.087
0.276
0.142
0.164
0.096
0.112
0.168
0.112
                            Salinity
2.4
4.1
5.5
7.0
8.4
10.1
11.5
13.0
r
14.4
16.0
17.4
18.2
23.98
24.20
24.79
25.92
27.25
28.62
29.19
29.50

29.62
29.73
29.76
29.68
23.88
24.23
24.79
25.81
27.12
28.66
29.17
29.50

29.62
29.74
29.77
29.75
23.90
24.14
24.97
25.80
27.11
28.67
29.21
29.51

29.64
29.75
29.78
29.74
23.92
24.19
24.84
25.84
27.16
28.65
29.19
29.50

29.63
29.74
29.77
29.72
0.053
0.046
0.110
0.067
0.078
0.026
0.020
0.006

0.012
0.010
0.010
0.038
0.221
0.189
0.443
0.258
0.288
0.092
0.069
0.020

0.039
0.034
0.034
0.127
                                pH
2.4
4.1
5.5
7.0
8.4
10.1
11.5
13.0
14.4
16.0
17.4
18.2
7-72
7.81
7.88
7.89
7.78
7.64
7.63
7.67
7.69
7.71
7.72
7.69
7.76
7.81
7.86
7.87
7-78
7.65
7.63
7.67
7.68
7.69
7.69
7.65
7.76
7.81
7.87
7.91
7.83
7.68
7.61
7.64
7.65
7.62
7.55
7.40
7-75
7.81
7.87
7.89
7.80
7.66
7.62
7.66
7.67
7.67
7.65
7.58
0.023
0.000
0.010
0.020
0.029
0.021
0.012
0.017
0.021
0.047
0.091
0.157
0.298
0.000
0.127
0.253
0.370
0.272
0.151
0.226
0.271
0.616
1.186
2.073
                                 A-38

-------
Table 4-3.  (Continued)
Depth (m)

2.4
4.1
5.5
7.0
8.4
10.1
11.5
13.0
14.4
16.0
17.4
18.2
Cast 1

6.59
6.28
5.94
5.21
4.68
4.53
4.79
5.07
5.25
5.46
5.62
5.74
Cast 2

6.41
6.07
5.73
4.91
4.20
3.99
4.23
4.43
4.49
4.65
4.98
5.63
Cast 3
Dissolved
6.41
6.18
5.92
5.34
4.49
4.05
4.36
4.72
4.88
5.30
5.83
6.58
Mean
Oxygen
6.47
6.18
5.86
5.15
4.46
4.19
4.46
4.74
4.87
5.14
5.48
5.98
Std.
Dev.

0.104
0.105
0.116
0.221
0.242
0.296
0.293
0.320
0.380
0.429
0.443
0.520
Coeff. of
Variation

1.606
1.701
1.977
4.279
5.424
7.064
6.571
6.761
7-798
8.352
8.084
8.685
                                  A-39

-------
Table 4-4.  Applied Microsystems Probe Variability Check -
            Triplicate Casts.
Depth (m)

1.7
3.7
5.4
7.2
8.9
10.7
12.4
14.3
16.7
17.9
19.2

1.7
3.7
5.4
7.2
8.9
10.7
12.4
14.3
16.7
17.9
19.2

1.7
3.7
5.4
7.2
8.9
10.7
12.4
14.3
16.7
17.9
19.2
Cast 1

13.313
12.524
12.408
11.976
11.681
11.300
10.954
10.626
10.379
10.317
10.253

22.550
23.898
24.322
25.692
26.789
28.299
28.930
29.360
29.603
29.653
29.712

7.39
7.39
7.64
7.89
8.02
7.89
7.77
7.64
7.64
7.64
7.77
Cast 2

12.942
12.715
12.396
12.011
11.675
11.342
10.894
10.598
10.354
10.285
10.277

23.375
23.613
24.241
25.671
26.604
28.287
28.977
29.393
29.565
29.607
29.737

7.39
7.39
7.64
7.77
7.89
7.89
7.77
7.64
7.64
7.64
7.64
Cast 3 Mean
Temperature
13.124
12.496
12.376
12.154
11.788
11.218
10.923
10.613
10.386
10.290
10.260
Salinity
23.117
23.964
24.356
24.938
26.663
28.589
28.742
29.377
29.594
29.672
29.699
PH
7.39
7.52
7.64
7.77
7.89
7.89
7.77
7.64
7.64
7.64
7.64

13.126
12.578
12.393
12.047
11.715
11.287
10.924
10.612
10.373
10.297
10.247

23.014
23.825
24.306
25.434
26.685
28.392
28.883
29.377
29.587
29.644
29.716

7.39
7.43
7.64
7.81
7.93
7.89
7.77
7.64
7.64
7.64
7.68
Std.
Dev.

0.186
0.119
0.016
0.094
0.064
0.063
0.030
0.014
0.017
0.017
0.017

0.422
0.187
0.059
0.429
0.095
0.171
0.124
0.017
0.020
0.033
0.019

0.000
0.075
0.000
0.069
0.075
0.000
0.000
0.000
0.000
0.000
0.075
Coeff. of
Variation

1.413
0.948
0.130
0.783
0.543
0.559
0.275
0.132
0.162
0.167
0.170

1.834
0.783
0.243
1.688
0.354
0.602
0.431
0.056
0.067
0.113
0.065

0.000
1.010
0.000
0.887
0.946
0.000
0.000
0.000
0.000
0.000
0.977
                                  A-40

-------
                        8.0  LITERATURE CITED


Ditoro, D.M.,  R.V.  Thomann,  D.J. O'Connor, and J.L.  Mancini.   1977.
     Marine Modeling, Vol. 6.   P- 969-1020 In:   The sea:   Ideas and
     observation on progress in the progress in the study of the seas
     (E.G. Goldberg,  I.N.  McCave, J.J. O'Brian,  J.H.  Steele,  Eds.).
     John Wiley & Sons,  New York.

Officer,  C.B.    1976.     Physical  oceanography  of  estuaries  and
     associated coastal waters.  John Wiley & Sons, New York.

Rantz,  S.E.   1982a.   Measurement and  computation  of streamflow,
     Volume  1.   Measurement of stage  and  discharge.   U.S.G.S.  Water
     Supply Paper 2175.   Washington D.C.

Rantz,  S.E.     1982b.    Measurement  and  computation  of  streamflow,
     Volume  2.   Computation  of  discharge.   U.S.G.S. Water  Supply
     Paper 2175.  Washington D.C.

Strickland, J.D.H., and T.R. Parsons.  1972.  A Practical handbook of
     seawater  analysis.   Fish. Res. Bd. Can. Bulletin  167.  311 p.

Steemann-Nielsen,  E.    1975.   Marine  photosynthesis:  with special
     emphasis   on  the  ecological  aspects.   Elsevier  Oceanography
     Series,  13.  Elsevier Sci.  Publ.  Co., Amsterdam.
                                  A-41

-------
Sta
Date
Time
Depth   Temp   Sal   Sig-T   Trans
                                                             DO
PH
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-2
1-2
1-2
1-2
1-2
1-2
1-2
1-2
1-2
1-2
1-2
1-2
r
1-2
1-2
1-2
1-2
1-2
1-2
1-2
1-3
1-3
1-3
1-3
1-3
1-3
1-3
1-3
2-5
2-5
2-5
2-5
2-5
2-5
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88

8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
1630
1630
1630
1630
1630
1630
1630
1630
1630
1630
1630
1630
1630
1630
1630
1630
1630
1630
1645
1645
1645
1645
1645
1645
1645
1645
1645
1645
1645
1645

1645
1645
1645
1645
1645
1645
1645
1700
1700
1700
1700
1700
1700
1700
1700
1715
1715
1715
1715
1715
1715
0.2
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
0.2
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5

6.0
6.5
7.0
7.5
8.0
8.5
9.0
0.2
0.5
1.0
1.5
2.0
2.5
3.0
3.5
0.0
0.2
1.0
1.5
1.9
2.5
14.87
14.90
14.86
14.55
14.52
14.39
14.16
13.96
13.34
13.17
13.00
12.87
12.79
12.64
12.38
12.08
11.94
11.85
14.88
15.01
14.73
14.39
14.27
14.36
13.83
13.67
13.41
12.94
12.88
12.63

12.53
12.57
12.46
12.14
12.04
11.96
11.96
14.81
15.02
14.75
14.40
14.32
14.34
14.22
13.98
12.16
15.02
15.20
14.31
14.46
14.33
13.35
22.94
23.35
23.77
23.78
23.99
24.23
24.61
25.58
25.83
26.10
26.23
26.42
26.63
27.28
27.61
27.88
28.09
5. 61
23.08
23.53
23.84
23 .84
23.95
24.76
24.91
25.64
26.09
26.31
26.49

26.70
26.71
26.97
27.59
27.73
27.87
28.01
17.20
23.06
23.70
23.78
23.83
23.94
24.09
24.41
27.44
19.11
22.37
23.79
23.79
23.82
9.44
16.77
17.09
17.47
17.48
17.67
17.90
18.23
19.09
19.31
19.55
19.67
19.83
20.02
20.57
20.88
21.11
21.29
3 . 50
16.85
17.25
17.55
17.58
17-64
18.36
18.51
19.12
19.55
19.73
19.92

20.08
20.10
20.32
20.85
20.98
21.10
21.21
12.39
16.83
17.38
17.51
17.56
17_. 64
17.78
18.07
20.73
13.81
16.27
17.53
17.50
17.55
7.16
6.64
6.91
7.51
7.61
7.39
7.68
7.84
8.26
8.27
8.38
8.42
8.33
8.34
8.07
6.07
4.61
5.13
7.99
6.61
6.85
7.84
7.84
7.75
7.76
7.88
8.25
8.41
8.27
8.33

8.28
8.28
8.08
5.50
4 .39
4.52
5.06
7.23
6.87
6.96
7.67
7.91
7.76
7.64
7.80
8.80
7.12
6.65
8.13
8.11
8.06
6.41
5.12
4.95
5.33
5.64
5.54
5.50
5.50
5.65
5.55
5.46
5.52
5.19
5.06
4.51
2.73
0.68
0.25
8.74
6.25
5.48
6.11
6.58
6.54
5.84
5.77
5.59
5.54
5.47
5.17

4.92
4.64
4.25
2.66
1.05
0.58
0.25
8.21
5.57
5.10
5.69
6.34
6.39
6.00
5.75
5.86
5.36
4.84
7.41
7.22
7.43
7.24
7.12
7.14
7.32
7.46
7.44
7.46
7.52
7.69
7.67
7.71
7.72
7.65
7.64
7.55
7.35
7.27
7.16
7.67
7.11
7.24
7.64
7.74
7.55
7.57
7.60
7.63
7.72
7.66
7.64

7.61
7.59
7.49
7.48
7.31
7.21
7.53
7.39
7.06
7.27
7.61
7.73
7.56
7.58
7.50
7.78
7.33
7.02
7.84
7.82
7.86
                               A-42

-------
Sta
Date
Time   Depth   Temp   Sal   Sig-T   Trans
DO
pH
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
5-1
5-1
5-1
5-1 ,
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
1715
1715
1715
1715
1715
1715
1715
1715
1715
1715
1715
1715
1715
1245
1245
1245
1245
1245
1245
1245
1245
1245
1245
1245
1245
1145
1145
1145
1145
1145
1145
1145
1145
1145
1145
1145
1145
1145
1145
1145
1200
1200
1200
1200
1200
1200
1200
1200
1200
1200
1200
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
0.5
0.8
1.4
5.4
9.2
11.3
14.7
16.0
20.2
25.5
28.1
30.6
0.4
2.4
3.7
3.9
5.9
6.6
9.0
10.2
11.3
12.4
14. 6
16.6
18.8
21.0
22.4
0.5
1.2
2.0
3.5
5.5
7.4
11.1
13.0
16.9
18.9
21.9
14.35
14.22
14.04
13.28
13.03
12.70
12.76
12.47
12.46
12.35
12.25
12.17
12.20
14.81
14.75
14.80
13.32
12.28
11.65
10.96
10.78
10.32
9.65
9.43
9.35
14.45
14.35
13.98
13.87
13.27
12.98
12.39
12.00
11.77
11.57
11.28
11.03
10.67
10.35
10. 14
14.31
14.32
14.32
14.33
13.36
12.55
11.72
11.48
10.89
10.61
10.18
23.83
24.24
24.43
25.73
25.97
26.41
26.72
26.97
27.08
27.06
27.40
27.38
27.35
23.67
23.76
23.72
26.13
27.60
28.32
29.11
29.27
29.77
30.34
30.53
30.61
23.73
24.08
24.85
24.92
26.17
26.48
27.39
27.85
28.18
28.44
28.80
29. 12
29.50
29.81
28.32
24.20
24.20
24.17
24.18
26.03
27.37
28.25
28.55
29.26
29.57
29.91
17.55
17.89
18.07
19.21
19.44
19.84
20.07
20.32
20.40
20.41
20.69
20.69
20.66
17.34
17.42
17.38
19.51
20.84
21.50
22.23
22.39
22.85
23.40
23.58
23.66
17.46
17.75
18.41
18.48
19.55
19.85
20.65
21.08
21.37
21.61
21.94
22.23
22.58
22.88
21.75
17.85
17_.84
17.82
17.83
19.43
20.61
21.44
21.71
22.36
22.65
22.98
8.11
7.80
7.58
8.36
8.69
8.52
8.64
8.82
8.79
8.77
8.76
8.79
8.82
7.33
7.18
7.28
8.00
8.95
8.89
8.71
8.54
8.65
8.78
8.77
8.77
7.10
7.46
7.92
8.05
8.42
8.45
8.61
8.61
8.65
8.57
8.47
8.48
8.58
8.41
8.30
7.67
7.63
7.61
7.72
8.57
8.75
8.75
8.74
8.73
8.71
8.71
7.28
6.42
5.96
5.82
5.70
5.88
6.06
6.17
6.22
6.13
6.05
6.01
5.99
7.57
7.44
7.34
7.07
7.26
7.37
7.31
7.25
7.04
6.79
6.64
6.34
7.59
7.48
7.33
7.32
7.32
7.42
7.50
7.58
7.61
7.58
7.44
7.19
6.87
6.64
6.40
8.38
8.26
8.20
8.14
8.07
8.14
8.01
7.77
7.52
7.46
7.23
7.80
7.52
7.52
7.66
7.73
7.76
7.79
7.79
7.83
7.82
7.78
7.77
7.79
7.37
7.41
7.39
7.67
7.76
7.76
7.72
7.74
7.72
7.69
7.69
7.68
7.29
7.33
7.42
7.52
7.61
7.53
7.55
7.55
7.61
7.52
7.47
7.49
7.51
7.50
7.45
7.63
7.63
7.63
7.63
7.72
7.75
7.63
7.66
7.69
7.66
7.60
                                A-43

-------
Sta
Date
Time   Depth   Temp   Sal   Sig-T   Trans
DO
                                                                   pH
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3 ,
5-3
5-3
5-3
5-3
5-3
5-3
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
o ""* 2* J_ ~~ o o
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
1200
1200
1200
1200
1200
1200
1200
1200
1200
1200
1200
1200
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1210
1225
1225
1225
1225
1225
1225
1225
1225
1225
1225
1225
1225
1225
1225
1225
1225
25.7
27.6
29.6
31.4
36.2
41.0
43.0
45.0
46.9
48.8
50.7
52.4
0.5
0.8
2.0
3.6
4.9
6.4
7.8
9.2
10.5
12.7
15.3
17.7
19.9
23.9
25.7
29.5
31.4
35.0
37.7
41.2
43.0
46.5
49.8
53.5
0.4
1.5
1.8
3.3
4.0
5.4
6.9
8.5
10.0
12.2
14.3
16.3
18.4
20.7
22.3
24.5
9.59
9.38
9.26
8.99
8.49
8.04
7.92
7.77
7.58
7.46
7.40
7.37
14.36
14.36
14.36
14.19
13.65
13. 14
12.57
12 .36
11.87
11.34
11.23
10.73
10.42
9.94
9.69
9.22
9.02
8.63
8.28
7-99
7 .88
7.61
7.44
7.34
14.27
14.26
14.26
14.15
13.93
13.36
12.96
12.66
12.14
11.58
11.26
10.83
10.55
10.31
10.09
9.81
30.38
30.57
30.68
30.89
31.22
31.62
31.70
31.83
31.98
32.10
32.16
32.16
24.11
24.12
24.14
24.68
25.57
26.58
27.30
27.60
28.03
28.71
28.98
29.40
29.75
30.11
30.29
30.69
30.86
31.11
31.40
31.65
31.74
31.96
32.12
32.22
23.87
24.10
24.15
24.58
25.31
26.08
26.90
27.40
27.88
28.61
28.94
29.33
29.61
29.84
30.01
30.26
23.44
23.62
23.73
23.93
24.26
24.64
24.72
24.85
24.99
25.10
25.16
25.16
17 .77
17.77
17.79
18.24
19.02
19.89
20.55
20.82
21.24
21.86
22.09
22.50
22.82
23.18
23.36
23.74
23.90
24.16
24.44
24.67
24.76
24.97
25.12
25.19
17.60
17.78
17.82
18.17
18.77
19.47
20.17
20.61
21.08
21.74
22.05
22.43
22.69
22.91
23.08
23.31
8.72
8.70
8.67
8.65
8.66
8.54
8.57
8.57
8.55
8.49
8.49
1.30
7.78
7.80
7.75
8.15
8.58
8.86
8.90
8.90
8.76
8.84
8.90
8.88
8.72
8.87
8.87
8.85
8.80
8.82
8.82
8.81
8.81
8.75
8.65
8.71
8.34
8.33
8.32
8.31
8.45
8.75
8.93
8.97
8.70
8.99
8.98
8.97
8.93
8.89
8.94
8.94
6.71
6.70
6.71
6.67
6.19
5.87
5.71
5.53
5.38
5.26
5.14
4.98
7.79
7.77
7.74
7.69
7.71
7.72
7.76
7.78
7.75
6.85
6.43
6.25
6.40
6.20
6.15
6.39
6.40
5.99
5.67
5.57
5.43
5.26
5.11
4.90
8.65
8.56
8.48
8.24
8.18
8.15
8.11
8.08
8.10
7.98
7.70
7.63
7.58
7.40
7.19
6.95
7.65
7.69
7.61
7.56
7.62
7.55
7.57
7.56
7.57
7.53
7.60
7.37
7.67
7.69
7.72
7.69
7.70
7.80
7.75
7.78
7.76
7.64
7.74
7.74
7.68
7.70
7.73
7.68
7.61
7.58
7.68
7.57
7.66
7.67
7.62
7.55
8.00
8.01
7.95
7.91
7.85
7.90
7.95
7.98
7.93
7.95
7.98
7.97
7.92
7.87
7.89
7.90
                               A-44

-------
Sta
Date
Time
Depth   Temp   Sal   Sig-T
Trans
DO
                                                                   pH
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-4
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5 ,
5-5
50
50
50
50
50
50
50
50
50
50
51
51
51
51
51
51
51
51
51
51
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
1225
1225
1225
1225
1225
1225
1225
1225
1225
1225
1225
1225
1235
1235
1235
1235
1235
1235
1235
1235
1235
1235
1235
1235
1235
1235
1235
1235
1235
1235
1235
1125
1125
1125
1125
1125
1125
1125
1125
1125
1125
1110
1110
1110
1110
1110
1110
1110
1110
1110
1110
26.0
32.9
33.6
35.2
37.4
39.5
42.5
44.7
46.9
49.1
51.9
52.4
0.4
1.1
2.5
3.4
10.7
12.4
14.2
16.8
19.4
22.0
25.4
27.0
29.6
32.1
35.4
38.7
42.1
45.2
48.7
0.3
1.1
1.2
2.5
2.6
3.0
4.4
5.5
6.4
7.0
0.3
0.9
1.5
2.3
3.2
5.7
7.4
9.0
11.5
13.9
9.61
8.89
8.74
8.55
8.33
8.15
7.85
7.79
7.54
7.40
7.36
7.33
14.17
14.13
14.18
14.14
12.10
11.73
11.36
10.78
10.41
10.12
9.67
9.38
9.16
8.89
8.42
8.23
7.88
7.74
7.38
14.46
14.37
14.30
14.18
14.01
13.95
13.80
13.47
13.25
12.91
14. 18
14.18
13.71
13.41
13.16
12.52
12.28
12.06
11.41
10.88
30.42
30.96
31.08
31.22
31.39
31.54
31.78
31.89
32.05
32.18
32.20
32.23
24.12
24.24
24.20
24.51
28.00
28.52
28.82
29.34
29.71
29.99
30.35
30.57
30.76
30.96
31.30
31.47
31.75
31.87
32.18
24.04
24.17
24.24
24.59
24.72
24.80
25.22
25.92
26.36
26.72
23.88
23.89
24.21
24.72
25.64
27.13
27.62
28.12
28.56
29.21
23.47
24.00
24.12
24.26
24.42
24.56
24.80
24.89
25.05
25.17
25.19
25.22
17.81
17.91
17.87
18.12
21.18
21.64
21.94
22.44
22.79
23.05
23.41
23.62
23.81
24.00
24.34
24.50
24.77
24.88
25. 17
17.69
17.81
17.88
18.17
18.30
18.37
18.72
19.32
19.70
20.04
17.62
17.63
17.97
18.41
19.17
20.43
20.85
21.28
21.73
22.32
8.93
8.89
8.90
8.91
8.90
8.89
8.87
8.85
8.74
8.81
8.80
1.56
8.30
8.40
8.50
8.60
9.01
9.06
9. 04
9.03
9.01
9.00
8.98
8.97
8.92
8.90
8.90
8.90
8.89
8.89
8.15
7.59
7.65
7.80
8.00
7.98
8.07
8.47
8.49
8.56
8.58
8.45
8.20
8.13
8.05
8.39
8.67
8.68
8.69
8.68
8.69
6.92
6.54
6.42
6.23
6.01
5.93
5.74
5.58
5.42
5.28
5.11
4.88
8.48
8.24
8.15
8.10
7.86
7.76
7.73
7.76
7.64
7.46
7.20
7.13
7.00
6.71
6.27
6.03
5.83
5.53
5.04
8.32
8.25
8.21
8.16
8.16
8.16
8.13
8.15
8.20
8.25
7.96
7.50
7.09
7.06
7.01
6.86
6.74
6.65
6.59
6.52
7-95
7.80
7.85
7.90
7.87
7.91
7.86
7.88
7.86
7.89
7.85
7.72
7.78
7.65
7.59
7.60
7.68
7.61
7.63
7.67
7.64
7.61
7.58
7.58
7.56
7.48
7.49
7.50
7.39
7.45
7.48
7.65
7.68
7.70
7.74
7.77
7.79
7.84
7.87
7.88
7.88
7.95
7.96
7.95
7.97
7.99
7.99
7.98
7.97
7.93
7.91
                               A-45

-------
Sta
Date
Time
Depth   Temp   Sal   Sig-T   Trans
DO
                                                                   pH
51
51
51
51
51
51
51
51
1-2
1-2
1-2
1-2
2-3
2-3
2-3
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-2
1-2
1-2 '
1-2
1-2
1-2
1-2
1-2
1-2
1-2
1-3
1-3
1-3
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-1
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-21-88
8-23-88
8-23-88
8-23-88
8-23-88
8-23-88
8-23-88
8-23-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
1110
1110
1110
1110
1110
1110
1110
1110
1430
1430
1430
1430
1042
1042
1042
1009
1009
1009
1009
1009
1009
1009
1009
1009
1039
1039
1039
1039
1039
1039
1039
1039
1039
1039
1103
1103
1103
1120
1120
1120
1120
1120
1120
1120
1120
1120
1120
18.7
23.4
25.9
30.5
34.9
36.7
38.5
41.1
0.2
1.0
2.0
3.0
0.2
1.0
6.0
0.2
0.5
1.0
2.0
3.0
4.0
5.0
6.0
7.0
0.2
0.5
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
0.2
0.5
1.0
0.2
0.5
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
10.31
9.69
9.44
9.10
8.44
8.23
7.99
7.84
15.40
15.35
14.50
13.44
14.29
14.10
13.04
11.86
11.83
11.72
11.58
11.40
11.31
11.24
11.25
11.23
11.76
11.66
11.67
11.39
11.23
11.20
11.25
11.20
11.20
11.15
11.77
11.68
11.57
11.34
11.73
11.66
11.35
11.25
11.20
11.06
10.99
10.84
10.66
29.79
30.36
30.56
30.83
31.36
31.53
31.70
31.79
4.70
23.32
24.20
25.62
23.25
23.78
26.56
21.50
23.52
24.18
25.20
25.53
25.78
26.19
26.25
26.54
23.26
23.70
24.01
25.81
26.34
26.70
26.88
26.96
26.65
26.58
15.42
24.08
24.00
23.18
23.75
23.76
25.63
26.35
26.75
27.18
27.31
27.64
27.67
22.87
23.41
23.61
23.87
24.38
24.55
24.71
24.80
2.72
16.97
17.81
19.10
17.12
17.56
19.90
16.20
17.77
18.29
19.10
19.39
19.60
19.93
19.97
20.20
17.58
17.93
18.17
19.61
20.04
20.33
20.46
20.53
20.29
20.24
11.53
18.22
18.18
17.58
17-. 96
17.98
19.48
20.05
20.37
20.72
20.83
21.11
21.17
8.66
8.63
8.61
8.53
8.52
8.49
8.44
8.40
8.91
7.61
8.24
8.40
7.50
7.66
8.68
7.65
8.59
8.88
9.12
9.03
8.91
8.95
8.87
9.17
8.58
8.59
5.53
9.17
9.00
8.78
8.68
8.73
9.22
9. 14
8.09
8.49
8.91
7.57
8.07
8.27
8.45
7.90
8.91
8.90
8.67
8.28
8.65
6.35
6.19
6.12
5.97
6.05
6.15
6.29
6.43
8.38
5.26
4.61
5.09
6.63
5.50
6.22
5.94
6.05
6.26
6.44
5.97
5.27
4.97
4.99
5.61
6.47
6.12
6.13
6.08
5.42
4.43
3.92
4.23
5.16
5.71
5.91
5.61
6.01
7.19
5.52
5.23
4.27
3.20
3.34
3.28
2.37
1.79
1.67
7.88
7.84
7.82
7.79
7.74
7.73
7.71
7.70
7.33
7.21
7.34
7.66
6.78
7.20
7.73

.
.
*
.
,
.
.
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.
.
B
.
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«




i



                               A-46

-------
Sta
Date
Time
Depth   Temp   Sal   Sig-T   Trans
                                                             DO
                                                           PH
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-3
2-3
2-3
2-3
2-3
2-3
2-3
2-3
2-3
2-3
2-3 '
2-3
2-3
2-3
2-3
2-3
2-3
2-3
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
1138
1138
1138
1138
1138
1138
1138
1138
1138
1138
1138
1138
1138
1138
1138
1138
1138
1138
1138
1202
1202
1202
1202
1202
1202
1202
1202
1202
1202
1202
1202
1202
1202
1202
1202
1202
1202
1226
1226
1226
1226
1226
1226
1226
1226
1226
1226
1226
1226
1226
1226
1226
0.0
0.2
0.5
1.0
1.0
2.0
2.0
3.0
3.0
4.0
4.0
5.0
5.0
6.0
6.0
7.0
7.0
8.0
9.0
0.0
0.2
0.5
1.0
1.0
2.0
2.0
3.0
3.0
4.0
4.0
5.0
5.0
6.0
6.0
7.0
8.0
9.0
0.0
0.2
0.5
1.0
1.0
2.0
2.0
3.0
3.0
4.0
4.0
5.0
5.0
6.0
7.0
10.32
12.18
11.75
11.41
10.28
11.29
10.18
11.19
10.06
11.09
10.02
10.96
9.89
10.93
9.73
10.67
9.71
10.57
10.53
10.52
11.88
11.71
11.56
10.33
11.35
10.12
11.28
9.97
11. 19
9.85
10.99
9.81
10.93
9.75
10.77
10.72
10.50
10.60
11.94
11.78
11.53
10.34
11.36
10.19
11.29
10.01
11.21
9.85
11.05
9.77
10.91
10.83
27.62
22.02
23.38
24.80
27.73
26.20
27.75
26.57
28.00
27.13
27.86
27.33
27.69
27.45
27.86
27.72
27.80
27.54
27.61
27.55
21.70
22.97
24.54
27.55
25.61
27.76
26.37
27.72
26.88
27.75
27.03
27.76
27.35
27.72
27.44
27.50
27.58
27.73
21.48
23.41
24.48
27.54
25.34
27.82
26.38
27.89
26.67
28.23
27.21
27.81
27.54
27.46
21.18
16.55
17.67
18.82
21.27
19.93
21.31
20.23
21.52
20.68
21.42
20.85
21.30
20.95
21.46
21.20
21.42
21.08
21.14
21.10
16.35
17.36
18.60
21.13
19.46
21.32
20.06
21.32
20.47
21.36
20.62
21.37
20.87
21.35
20.97
21.03
21.12
21.22
16.18
17.69
18.56
21.12
19.25
21.36
20.06
21.44
20.30
21.73
20.75
21.42
21.03
20.98
8.98
7.73
8.20
8.86
8.90
9.20
8.92
9.24
9.18
9.20
9.39
9.36
9.15
9.46
9.20
9.43
8.94
9.33
9.26
9.33
8.08
8.17
8.74
9.34
9.01
9.26
9.29
9.34
9.28
9.90
9.46
9.43
9.26
9.43
9.36
9.43
9.32
9.20
8.09
8.12
8.76
9.11
9.09
9.24
9.28
9.25
9.52
9.44
9.39
9.26
9.28
9.38
2.49
7.41
6.47
6.10
2.54
6.16
2.50
4.85
2.81
4.63
3.22
4.91
3.63
5.17
3.87
3.68
4.15
3.30
2.65
3.08
5.92
5.85
5.89
2.40
5.93
2.54
6.11
3.29
5.42
3.64
5.51
3.91
4.14
4.14
4.02
4.76
3.71
4.34
5.71
5.59
5.71
2.45
5.85
2.48
5.49
3.35
6.40
4.45
6.46
4.62
5.49
4.44
                               A-47

-------
Sta
Date
Time   Depth   Temp   Sal   Sig-T   Trans
                                                             DO
PH
2-4
2-4
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3 r
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-5
3-5
3-5
3-5
3-5
3-5
3-5
3-5
3-5
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
1226
1226
1249
1249
1249
1249
1249
1249
1249
1249
1249
1249
1249
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1343
1354
1354
1354
1354
1354
1354
1354
1354
1354
8.0
9.0
0.2
0.5
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
1.0
2.2
2.7
4.1
4.9
6.3
7.0
7.8
9.1
9.9
11.2
12.0
12.8
14.2
15.3
16.0
17.8
19.1
20.2
22.0
23.3
25.1
27.1
29.0
30.9
32.8
34.8
36.0
38.0
1.7
2.3
2.9
3.5
4.1
4.7
5.9
7.0
8.3
10.
10.
12.
12.
11.
11.
11.
11.
11.
10.
10.
10.
10.
12.
13 .
13.
12.
12.
11.
11.
11.
11.
11.
10.
10.
10.
10.
10.
10.
10.
10.
9.
9.
9.
9.
9.
9.
9.
9.
8.
8.
8.
13.
12.
12.
11.
11.
11.
11.
11.
11.
76
60
54
18
64
47
31
38
00
94
84
78
63
71
73
15
47
42
49
36
27
13
01
92
84
80
68
57
49
23
09
98
92
80
63
43
33
19
03
90
85
66
90
82
00
68
60
55
44
29
05
27
27
20
22
23
25
25
26
27
27
27
27
27
11
23
24
24
25
27
28
28
28
28
29
29
29
29
29
29
29
29
29
29
30
30
30
30
30
30
30
30
31
22
24
25
26
27
27
27
28
28
.56
.41
.05
.87
.84
.83
.91
.39
.29
.55
.35
.56
.44
.61
.42
.31
.75
.57
.87
.29
.47
.69
.84
.00
.08
.12
.32
.43
.50
.70
.82
.89
.95
.06
.21
.37
.47
.60
.74
.83
.87
.04
.74
.14
.68
.93
.19
.41
.98
.27
.67
21.
20.
14.
17.
18.
19.
19-
20.
20.
21.
20.
21.
20.
8.
17.
18.
18.
19.
21.
21.
21.
21.
22.
22.
22.
22.
22.
22.
22.
22.
22.
23.
23.
23.
23.
23.
23.
23.
23.
23.
23.
24.
16.
18.
19.
20.
20.
20.
21.
21.
21.
07 9.34
98 9.39
98 7.48
21 8.10
04 9.67
61 9.17
70 8.93
06 9.32
82 9.37
03 9.34
89 9.19
06 9.10
99 8.85
42
34
13
59
24
17
52
67
87
01
14
22
26
43
54
61
81
92
00
05
15
30
46
55
68
81
90
94
10
78
05
39
41
63
80
27
52
87
4.90
4.86
5.96
5.89
6.07
6.21
5.98
5.93
6.03
6.00
5.37
4.65
3.93

^
,
.
.
.
.
m
.
.
.
.
.
m
.
,
B
.
^
,
^
.
.
.
p
,
,
w
•

*
.
.
.
*
B
w
,
m
•

*
^
B
9
m
m
^
m
.
•
7.77
7.26
7.26
7.39
7.39
7.77
7.77
7.77
7.89
7.89
8.02
8.02
8.02
7.89
7.77
7.77
7.77
7.89
7.89
7.89
7.89
7.77
7.77
7.77
7.64
7.52
7.52
7.52
7.39
7.77
7.64
7.77
7.89
7.89
8.02
8.02
8.02
8.02
                                A-48

-------
Sta     Date     Time   Depth   Temp   Sal   Sig-T   Trans   DO    pH
3-5
3-5
3-5
3-5
3-5
3-5
3-5
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2 '
4-2
4-2
4-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
1354
1354
1354
1354
1354
1354
1354
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1454
1553
1553
1553
1553
1553
1553
1553
1553
1553
1553
1553
1553
1553
1553
1553
1553
1553
1553
1553
9.5
10.7
12.0
13.4
14.5
15.7
16.9
1.1
2.4
4.1
5.3
7.2
8.4
10.3
11.6
13.0
14.3
16.2
17.3
19.2
20.2
23.7
26.3
29.3
32.4
34.3
35.6
37.0
39.5
42.7
45.9
47.3
48.5
0.8
1.1
1.5
2.0
3.5
5.0
6.5
7.8
9.1
10.5
12.4
14.4
16.0
18.3
20.7
22.4
24.8
26.8
28.8
11.03
10.86
10.73
10.67
10.51
10.37
10.23
12.66
12.03
11.47
11.30
11.01
10.97
10.88
10.80
10.54
10.49
10.21
10.05
9.95
9.86
9.58
9.41
9.22
8.95
8.84
8.75
8.64
8.46
8.27
8.14
8.09
8.03
12.83
12.83
12.80
12.78
12.28
11.92
11.69
11.52
11.35
11.08
10.87
10.68
10.52
10.19
9.99
9.83
9.65
9.53
9.32
28.77
29.03
29.19
29.30
29.45
29.56
29.65
24.21
25.31
27.40
28.14
28.73
28.83
29.05
29.18
29.34
29.42
29.67
29.83
29.90
29.96
30.23
30.37
30.53
30.78
30.87
30.94
31.03
31.19
31.36
31.47
31.51
31.52
23.55
23.55
23.58
23.60
25.14
26.28
27.32
28.25
28.60
28.98
29.23
29.39
29.49
29.79
29.96
30.09
30.26
30.36
30.51
21.95
22.18
22.33
22.43
22.57
22.67
22.77
18.14
19.10
20.81
21.42
21.92
22.01
22.20
22.31
22.47
22.55
22.79
22.93
23 .00
23.07
23.32
23.46
23.61
23.85
23.93
24.00
24.09
24.24
24.40
24.51
24.54
24.56
17.62
17.62
17.65
17.67
18.94
19.88
20.72
21.47
21.77
22-- 11
22. 34
22.50
22.60
22.89
23.05
23.18
23.34
23.44
23.59
m
.
.
.
.
.
•
.
.
.
.
»
.
.
,
^
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
•
7.60
7.64
7.69
7.74
8.83
9.19
9.34
9.48
9.47
9.49
9.47
9.47
9.49
9.48
9.48
9.47
9.36
9.34
9.43
8.02
. 7.89
7.89
7.89
7.77
7.77
. 7.89
. 7.89
. 8.02
. 8.02
. 8.02
. 8.02
8.02
. 8.02
7.89
7.89
7.77
7.89
7.89
7.89
. 7.77
7.77
. 7.64
. 7.64
. 7.64
. 7.64
. 7.64
. 7.52
7.39
. 7.26
. 7.14
7.01
. 7.26
. 7.88
7.88
. 7.89
. 7.90
7.98
8.02
. 8.01
8.02
. 8.01
8.00
. 8.01
8.00
. 7.99
. 7.98
. 7.95
. 7.94
7.90
. 7.83
. 7.83
                               A-49

-------
Sta
Date
Time   Depth   Temp   Sal   Sig-T   Trans
                                                             DO
pH
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
5-2
Dock
Dock
Dock
Dock
Dock
Dock
Dock
Dock
Dock
Dock
Dock
Dock
Dock
Dock
Dock
Dock
Dock
1-1 '
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-1
1-2
1-2
1-2
1-2
1-2
1-2
1-2
1-2
1-2
1-3
1-3
1-3
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-20-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
1553
1553
1553
1553
1553
1553
1553
1553
1553
1553
1553
0930
0930
0930
0930
0930
0930
0930
0930
0930
0930
0930
0930
0930
0930
0930
0930
0930
1835
1835
1835
1835
1835
1835
1835
1835
1835
1835
1840
1840
1840
1840
1840
1840
1840
1840
1840
1848
1848
1848
31.1
33.4
35.4
37.7
39.9
42.5
44.5
46.2
47.0
49.7
51.7
0.9
1.0
1.7
2.0
2.6
3.5
4.1
4.7
5.3
6.2
6.8
7.4
8.0
8.6
9.8
10.7
11.0
0.4
1.0
1.8
2.6
3.4
4.2
5.0
6.0
7.0
8.0
0.4
0.9
1.4
3.9
4.7
5.5
6.5
7.5
8.5
0.5
1.0
1.6
9.04
8.74
8.37
8.15
7.93
7.79
7.66
7.60
7.57
7.49
7.46
11.78
11.88
12.04
11.97
11.78
11.65
11.62
11.57
11.51
11.44
11.40
11.32
11.29
11.16
11.05
10.97
10.97
13.28
13.13
12.69
12.39
12.32
12.27
12.12
11.65
11.37
11.38
13.59
13.52
13.32
12.36
12.25
11.91
11.40
11.34
11.37
13.76
13.71
13.45
30.74
31.02
31.29
31.48
31.67
31.80
31.91
31.97
32.00
32.06
32.09
23.57
23.55
24.99
25.18
26.34
26.99
27.29
27.57
27.83
28.07
28.25
28.39
28.45
28.67
28.82
28.92
28.92
18.61
22.69
23.09
23.98
24.37
24.57
24.75
25.74
28.19
28.21
20.50
22.68
22.91
24.21
24.46
25.28
28.16
28.28
28.24
21.76
22.89
23.04
23.81
24.08
24.34
24.52
24.70
24.82
24.92
24.98
25.01
25.06
25.09
17.80
17.76
18.85
19.01
19.94
20.47
20.70
20.93
21.14
21.33
21.48
21.60
21.65
21.85
21.98
22.08
22.08
13.74
16.90
17.29
18.03
18.34
18.50
18.67
19.51
21.45
21.47
15.14
16.83
17.04
18.21
18.42
19.11
21.42
21.53
21.49
16.08
16.95
17.12
9.44
9.45
9.43
9.42
9.36
9.33
9.33
9.35
9.35
9.30
9.27

•
*
9
•
.
•
•
•
.
.
.
.
^
•
•
•
7.34
7.52
7.55
8.22
8.30
8.33
8.36
9.00
9.39
7.78
7.09
6.92
6.86
8.21
8.20
8.28
9.37
9.31
6.36
7.05
6.50
6.26
•
*
•
•
•
•
•
•
m
•
•
*
•
•
B
•
.
•
•
•
•
.
.
.
*
•
.
•
5.44
5.46
5.48
5.41
5.38
5.36
5.48
5.77
6.12
6.76
5.05
5.01
4.95
4.74
4.76
4.84
5.00
5.26
5.93
6.07
6.23
6.41
7.84
7.83
7.81
7.79
7.77
7.74
7.74
7.75
7.75
7.76
7.76
7.39
7.39
7.39
7.39
7.39
7.52
7.52
7.52
7.52
7.52
7.39
7.39
7.39
7.39
7.26
7.26
7.26
7.54
7.56
7.63
7.68
7.70
7.71
7.75
7.78
7.75
7.71
7.44
7.47
7.51
8.15
7.69
7.75
7.77
7.74
7.67
7.24
7.26
7.28
                               A-50

-------
Sta
Date
Time   Depth   Temp   Sal   Sig-T   Trans
                                                             DO
pH
1-3
1-3
1-3
1-3
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2
2-2 -
2-2
2-2
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
2-3a
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
1848
1848
1848
1848
1805
1805
1805
1805
1805
1805
1805
1805
1805
1805
1805
1805
1805
1820
1820
1820
1820
1820
1820
1820
1820
1820
1820
1820
1820
1820
1820
1743
1743
1743
1743
1743
1743
1743
1743
1743
1743
1743
1743
1743
1743
1743
1743
1743
1743
2.0
2.4
2.8
3.1
0.2
0.6
• 1.0
1.6
2.2
3.0
3.8
4.6
5.4
6.2
7.1
7.9
8.5
0.2
0.7
1.2
1.8
2.4
3.0
3.5
4.0
4.6
5.2
5.9
6.5
7.1
7.6
1.7
2.4
3.0
3.7
4.8
6.0
7.2
7.8
8.9
10.1
11.3
12.4
13.2
14.3
15.0
16.1
17.3
18.6
13.23
13.10
13.07
13.13
13.23
12.92
12.68
12.43
12.39
12.34
12.31
12.17
12.08
12.00
11.86
11.67
11.68
12.94
12.74
12.70
12.50
12.42
12.42
12.42
12.41
12.36
12.27
12.13
12.09
12.03
12.00
13.31
13.37
13.31
12.52
12.41
12.27
11.98
11.91
11.68
11.45
11.19
10.95
10.85
10.63
10.58
10.43
10.35
10.28
23.16
23.28
23.20
23.14
21.07
22.30
22.91
23.35
23.77
24.03
24.34
24.65
25.04
25.37
25.94
26.85
27.17
20.66
22.53
23.10
23.44
23.98
23.98
24.06
24.10
24.29
24.53
24.94
25.14
25.28
25.55
22.55
22.48
23.10
23.90
24.13
24.74
25.69
25.89
26.79
27.92
28.52
28.93
29.09
29.36
29.41
29.55
29.63
29.69
17.25
17.36
17.31
17.25 '
15.64
16.64
17.15
17.53
17.86
18.07
18.32
18.58
18.90
19.17
19.63
20.36
20.61
15.38
16.85
17.30
17.59
18.02
18.02
18.08
18.12
18.27
18.47
18.81
18.97
19.09
19.30
16.74
16.67
17.17
17.92
18.12
18.62
19.40
19.57
20.30
21.22
21.73
22.09
22.23
22.48
22.52
22.66
22.73
22.79
7.00
7.47
7.61
6.47
7.34
7.45
7.62
7.37
8.09
8.08
8.01
8.27
8.35
8.46
8.12
8.58
8.09
7.48
7.68
7.74
7.67
8.00
8.08
8.11
8.03
8.06
7.97
8.21
8.14
8.09
8.04
•
•
.
*
•
•
.
•
.
,
.
•
.
•
•
.
•
,
6.50
6.62
6.73
6.89
5.02
5.07
5.10
5.14
5.13
5.06
4.97
4.93
4.82
4.84
5.00
5.35
5.68
5.44
5.46
5.46
5.48
5.47
5.42
5.34
5.26
5.16
5.17
5.27
5.39
5.60
5.86
•
.
•
•
.
.
•
.
•
B
•
•
•
•
a
•
•
m
7.29
7.29
7.28
7.26
7.63
7.67
7.71
7.75
7.78
7.80
7.83
7.88
7.97
8.02
8.14
8.07
8.17
7.57
7.59
7.61
7.65
7.66
7.67
7.67
7.68
7.68
7.68
7.67
7.66
7.64
7.63
7.39
7.39
7.39
7.39
7.64
7.64
7.89
7.89
8.02
7.89
7.89
7.77
7.64
7.64
7.64
7.64
7.64
7.64
                               A-51

-------
Sta
Date
Time   Depth   Temp   Sal   Sig-T   Trans
DO
                                                                   pH
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3b
2-3c
2-3c
2-3C
2-3C
2-3c
2-3C
2-3c
2-3c
2-3c
2-3C
2-3c
2-3o
2-3c
2-3c
2-3C
2-3C
2-3C
2-3d
2-3d
2-3d
2 -3d
2-3d
2-3d
2-3d
2-3d
2-3d
2-3d
2-3d
2-3d
2-3d
2-3d
2-3d
2-3d
2-3d
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
1749
1749
1749
1749
1749
1749
1749
1749
1749
1749
1749
1749
1749
1749
1749
1749
1749
1749
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1745
1745
1745
1745
1745
1745
1745
1745
1745
1745
1745
1745
1745
1745
1745
1745
1745
1.3
1.8
2.4
3.0
4.1
5.3
5.9
7.3
8.6
9.9
11.2
12.4
13.0
14.3
15.0
16.4
17.5
18.0
1.7
2.2
2.8
3.5
4.7
5.9
7.0
8.2
8.9
10.3
11.6
12.9
14.0
15.3
16.5
17.7
18.3
0.3
1.0
1.7
2.4
3.4
4.4
5.3
6.3
7.2
8.2
9.1
10.1
11.1
12.1
13.0
14.0
15.0
13.27
12.94
12.75
12.73
12.54
12.40
12.26
12.01
11.77
11.47
11.21
10.89
10.77
10.60
10.51
10.39
10.33
10.29
13.12
12.85
12.62
12.50
12.39
12.34
12.15
11.92
11.79
11.38
11.09
10.79
10.61
10.48
10.39
10.29
10.28
13.25
12.76
12.49
12.49
12.41
12.37
12.17
11.93
11.81
11.54
11.24
11.10
10.84
10.68
10.58
10.46
10.38
23.02
23.38
23.54
23.59
23.94
24.24
24.71
25.67
26.60
27.92
28.57
28.98
28.96
29.39
29.47
29.59
29.61
29.61
23.12
23.63
23.79
23.96
24.23
24.44
24.94
25.92
26.66
28.22
28.78
28.87
29.38
29.50
29.59
29.67
29.68
22.19
22.84
23.87
23.98
24.07
24.30
24.63
25.61
26.07
27.03
28.24
28.62
29.04
29.35
29.50
29.60
29.68
17.11
17.44
17.61
17.64
17.95
18.21
18.59
19.38
20.14
21.21
21.77
22.13
22.14
22.51
22.58
22.70
22.72
22.73
17.21
17.65
17.82
17.98
18.20
18.37
18.79
19.58
20.19
21.46
21.94
22.07
22.49
22.61
22.70
22.77
22.78
16.50
17.08
17.92
18.01
18.09
18.28
18.57
19-. 36
19.74
20.53
21.51
21.83
22.20
22.47
22.60
22.70
22.77
*
*
•
7.36
7.27
8.00
7.90
7.88
8.17
7.77
8.62
8.95
9.17
9.47
9.41
9.40
9.40
9.40
9.45
9.43
*
a
•
5.11
5.16
5.09
5.00
4.84
4.64
4.44
4.03
3.50
3.14
3.00
2.94
3.11
3.34
3.48
3.61
3.73
7.39
7.39
7.39
7.39
7.52
7.64
7.64
7.77
7.89
7.89
7.77
7.77
7.64
7.64
7.64
7.64
7.64
7.64
7.39
7.39
7.39
7.52
7.64
7.64
7.77
7.89
7.89
7.89
7.77
7.64
7.64
7.64
7.64
7.64
7.64
7.54
7.61
7.69
7.72
7.77
7.82
7.86
7.89
7.88
7.81
7.71
7.64
7.63
7.64
7.67
7.69
7.69
                                A-52

-------
Sta
Date
Time   Depth   Temp   Sal   Sig-T
Trans
DO
                                                                   PH
2-3d
2-3d
2-3d
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3e
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-3f
2-4
2-4
2-4
2-4
2-4
2-4
2-4
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
1745
1745
1745
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1750
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1730
1730
1730
1730
1730
1730
1730
16.0
17.0
17.4
0.3
1.8
2.0
2.6
3.4
4.4
5.2
6.2
7.2
8.2
9.1
10.1
11.1
12.1
13.1
14.1
15.0
15.9
17.0
17.8
0.1
0.6
1.1
1.9
2.7
3.5
4.3
5.3
6.2
7.0
8.0
9.0
10.0
11.0
12.0
12.9
13.9
14.9
15.9
16.9
17.6
0.3
0.8
1.0
1.6
2.2
3.0
3.8
10.32
10.28
10.27
13.29
12.52
12.50
12.47
12.38
12.32
12.16
11.98
11.78
11.55
11.27
11.06
10.82
10.66
10.55
10.45
10.36
10.31
10.28
10.30
13.22
12.95
12.68
12.48
12.47
12.40
12.32
12.18
11.98
11.90
11.56
11.29
11.04
10.81
10.65
10.57
10.46
10.35
10.31
10.28
10.29
13.50
13.35
13.26
12.72
12.43
12.33
12.25
29-73
29.75
29.76
21.21
23.54
23.67
23.92
24.11
24.37
24.72
25.45
25.86
26.96
27.81
28.66
29.07
29.29
29.50
29.61
29.67
29.74
29.77
29.77
21.88
22.53
23.06
23.74
23.96
24.11
24.18
24.89
25.41
25.80
26.55
27.92
28.67
29.11
29.37
29.50
29.58
29.69
29.74
29.77
29.77
14.36
21.93
22.73
23.45
23.79
24.15
24.46
22.82
22.84
22.85
15.74
17.67
17.77
17.97
18.13
18.34
18.64
19.23
19.58
20.47
21.17
21.87
22.23
22.42
22.60
22.71
22. 77
22.83
22.86
22.85
16.27
16.81
17.27
17.83
18.00
18.12
18.19
18.76
19.20
19.51
20.15
21.26
21.88
22.26
22.49
22.60
22.68
22.78
22.83
2-2.86
22.86
10.44
16.28
16.91
17.56
17.87
18.17
18.42
9.36
8.85
8.97
7.49
8.09
8.13
8.03
7.99
7.90
8.04
8.82
8.93
9.22
9.47
9.47
9.51
9.52
9.46
9.51
9.52
9.07
8.94
7.26
•
•
•
•
•
.
•
.
»
*
•
.
•
^
•
•
•
•
.
•
•
7.05
6.61
6.29
7.55
8.13
8.23
8.09
3.87
3.99
4.03
4.95
4.94
4.91
4.77
4.60
4.40
4.21
3.78
3.18
2.67
2.47
2.40
2.57
2.76
2.84
2.88
2.95
3.06
3.25
3.64
4.93
4.95
4.95
4.89
4.79
4.67
4.55
4.37
4.15
3.75
3.10
2.64
2.46
2.66
2.94
3.10
3.23
3.41
3.64
4.02
4.37
5.35
5.43
5.45
5.42
5.38
5.34
5.31
7.71
7.72
7.72
7.58
7.73
7.74
7.78
7.80
7.82
7.86
7.88
7.87
7.79
7.71
7.65
7.63
7.64
7.67
7.68
7.68
7.69
7.69
7.68
7.60
7.63
7.68
7.74
7.77
7.80
7.82
7.86
7.89
7.91
7.87
7.78
7.68
7.61
7.62
7.63
7.65
7.64
7.62
7.59
7.53
7.64
7.58
7.61
7.73
7.79
7.81
7.83
                               A-53

-------
Sta
Date
Time   Depth   Temp   Sal   Sig-T   Trans
DO
                                                                   pH
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-4
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
2-5
3-1
3-1
3-1
3-1
3-1 ,
3-1
3-1
3-1
3-1
3-1
3-1
3-1
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
1730
1730
1730
1730
1730
1730
1730
1730
1730
1730
1730
1730
1720
1720
1720
1720
1720
1720
1720
1720
1720
1720
1720
1720
1630
1630
1630
1630
1630
1630
1630
1630
1630
1630
1630
1630
1700
1700
1700
1700
1700
1700
1700
1700
1700
1700
1700
1700
1700
1700
1700
4.6
5.4
8.1
9.0
9.8
10.8
12.0
13.0
14.0
15.0
16.0
17.1
0.4
0.9
1.5
2.1
2.9
3.9
4.9
5.9
6.9
7.9
8.9
9.9
0.3
0.8
1.2
1.6
2.2
3.0
4.0
5.0
6.0
6.8
8.1
9.0
0.2
0.8
1.2
1.8
2.4
3.4
4.5
5.7
6.9
7.7
8.9
11.0
12.8
14.8
16.8
12.16
12.09
11.51
11.29
11.04
10.78
10.63
10.45
10.34
10.29
10.27
10.27
13.66
13.13
13.05
12.64
12.37
12.24
12.17
12.04
11.79
11.60
11.44
11.39
13.66
12.93
12.62
12.61
12.59
12.39
12.17
11.97
11.67
11.56
11.40
11.36
13.46
13.43
13.34
12.83
12.48
12.42
12.22
12.03
11.69
11.56
11.32
10.84
10.59
10.40
10.24
24.81
24.98
27.08
28.26
28.62
29.11
29.39
29.61
29.70
29.75
29.77
29.78
16.42
22.98
23.16
23.42
24.06
24.44
24.85
24.95
25.64
27.11
27.68
28.16
21.44
22.10
23.29
23.90
24.15
24.45
24.93
25.46
26.23
27.34
28.15
28.28
23.12
23.16
23.23
23.55
23.87
24.15
24.83
25.73
27.06
27.51
28.38
29.15
29.48
29.61
29.75
18.71
18.85
20.57
21.52
21.84
22.26
22.51
22.71
22.79
22.84
22.86
22.87
12.00
17.13
17.28
17.55
18.09
18.41
18.73
18.83
19.41
20.58
21.04
21.42
15.85
16.49
17.46
17.93
18.12
18.39
18.80
19.24
19.89
20.76
21.42
21.52
17.18
17.21
17.28
17.62
17.93
18-. 15
18.71
19.44
20.52
20.89
21.61
22.28
22.58
22.71
22.85
8.50
8.56
9.32
9.48
9.49
9.43
9.43
9.46
9.48
9.48
9.44
9.35
7.30
7.44
7.52
7.49
8.02
8.41
8.52
8.47
9.00
9.38
9.29
9.37
6.86
7.58
7.86
7.74
7.08
7.42
8.13
8.88
8.89
8.56
6.89
0.10
6.62
6.62
6.61
6.61
7.93
7.94
8.15
8.38
9.41
9.42
9.58
9.62
9.60
9.63
9.59
5.23
5.11
3.82
3.92
3.97
4.18
4.54
4.74
4.83
4.91
5.09
5.42
5.97
6.06
6.12
6.21
6.15
6.13
6.16
6.19
6.14
6.20
6.44
6.86
4.54
4.52
4.44
4.38
4.31
4.04
3.62
2.99
2.60
2.66
3.16
3.59
5.57
5.61
5.66
5.73
5.61
5.52
5.46
5.04
4.39
4.07
3.72
3.79
4.34
4.65
4.51
7.87
7.90
7.91
7.81
7.74
7.72
7.73
7.77
7. 78
7.77
7.76
7.75
7.58
7.55
7.61
7.69
7.83
7.87
7.89
7.94
7.96
7.91
7.87
7.85
7.45
7.58
7.61
7.62
7.63
7.71
7.78
7.79
7.68
7.52
7.48
7.36
7.48
7.53
7.57
7.66
7.78
7.78
7.87
7.96
7.96
7.90
7.82
7.75
7.74
7.82
7.82
                                A-54

-------
Sta
Date
Time   Depth   Temp   Sal   Sig-T   Trans
DO
PH
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-3
3-5
3-5
3-5
3-5
3-5
3-5
3-5
3-5
3-5
3-5
3-5
3-5
4-1
4-1
4-1
4-1
4-1
4-1
4-1
4-1 r
4-1
4-1
4-1
4-1
4-1
4-1
4-1
4-1
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-2
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
1700
1700
1700
1700
1700
1700
1700
1700
1700
1710
1710
1710
1710
1710
1710
1710
1710
1710
1710
1710
1710
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1600
1600
1600
1600
1600
1600
1600
1600
1600
1600
1600
1600
1600
1600
18.8
20.8
22.8
24.9
26.2
27.9
29.8
31.8
33.2
0.3
0.6
1.0
1.4
2.0
2.8
3.6
4.6
5.6
6.3
7.4
8.3
1.2
1.9
2.5
3.7
4.4
5.0
6.3
8.2
10.1
12.4
14.0
16.2
17.6
19.3
21.5
22.7
0.4
1.7
2.2
3.8
5.9
6.6
8.7
9.0
11.7
17.5
20.4
22.9
25.8
29.1
10.16
10.09
9.93
9.51
9.31
9.15
9.01
8.75
8.45
12.93
12.76
12.65
12.57
12.51
12.46
12.38
12.13
11.86
11.76
11.64
11.54
13.10
13.12
12.96
12.46
12.30
12.31
12.01
11.51
11.01
10.32
10.00
8.29
9.30
9.35
9.49
9.67
13.28
13.03
12.40
12.06
11.65
11.38
11.32
10.85
10.58
10.07
9.88
9.56
9.21
9.04
29.84
29.89
30.03
30.38
30.57
30.72
30.86
31.02
31.31
22.81
23.06
23.43
23.47
23.67
23.82
23.89
24.29
25.79
26.23
26.61
27.29
23.20
23.40
23.59
23.99
24.33
24.74
25.71
27.76
28.88
29.64
29.92
31.35
30.48
30.43
30.31
30.18
23.25
23.55
24.09
25.34
26.81
27.91
28.30
28.96
29.44
29.91
30.10
30.36
30.65
30.81
22.93
22.98
23.12
23.46
23.63
23.78
23.91
24.07
24.34
17.03
17.25
17.56
17.60
17.77
17.89
17.96
18.31
19.51
19.87
20. 18
20.73
17.28
17.44
17.61
18.01
18.29
18.61
19.41
21.08
22.04
22.74
23.02
24.40
23.56
23.52
23.40
23.27
17.31
17.58
18.11
19.13
20.34
21.23
21.54
22.14
22.55
23.00
23.18
23.43
23.71
23.86
9.55
9.63
9.55
9.51
9.30
9.42
9.16
8.80
8.17
7.53
7.58
7.77
7.92
8.04
8.13
8.22
8.37
8.87
9.21
9.41
0.73

.
.
.
,
.
•
.
.
*
.
.
.
.
.
•
6.84
7.38
7.61
8.29
9.42
9.43
9.66
9.64
9.67
9.60
9.27
9.53
9.63
9.53
4.63
4.19
3.87
2.63
1.94
1.33
0.83
0.63
1.20
*
.
.
.
.
.
.
,
.
.
.
•
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
•
5.00
4.84
4.59
4.32
4.04
3.79
3.61
3.52
3.40
2.99
2.68
2.04
1.43
0.99
7.82
7.84
7.80
7.71
7.59
7.59
7.44
7.38
7.34
7.69
7.73
7.77
7.80
7.83
7.86
7.90
7.97
7.99
7.97
7.94
7.87
7.52
7.52
7.52
7.77
7.89
7.89
8.02
8.02
8.02
7.89
7.77
7.39
7.64
7.64
7.77
7.77
7.66
7.75
7.89
7.96
7.99
7.93
7.91
7.84
7.83
7.75
7.75
7.79
7.67
7.58
                                A-55

-------
Sta
Date
Time   Depth   Temp   Sal   Sig-T
Trans
                                                             DO
                                                           PH
4-2
4-2
4-2
4-2
4-2
4-2
4-2
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3 '
4-3
4-3
4-3
4-3
4-3
4-3
4-3
4-3
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-1
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
1600
1600
1600
1600
1600
1600
1600
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1550
1445
1445
1445
1445
1445
1445
1445
1445
1445
1445
1445
1445
1445
1445
31.6
33.5
36.3
38.0
40.0
42.8
44.6
0.3
0.6
0.8
1.2
1.8
2.8
3.8
5.0
6.3
7.7
9.1
10.9
12.9
14.9
16.8
18.8
20.8
22.8
24.8
26.9
28.9
30.8
32.8
34.8
36.8
38.8
40.9
42.6
43.8
45.0
46.2
1.0
1.6
2.1
2.7
3.3
4.4
5.6
6.8
8.0
9.1
10.2
11.5
12.6
13.7
8.72
8.42
8.13
7.98
7.87
7.73
7.72
13.50
13.40
13.38
13.34
13.10
12.29
12.02
11.84
11.61
11.43
11.20
10.78
10.56
10.30
10.14
10.03
9.89
9.67
9.38
9.21
9.02
8.88
8.52
8.36
8.13
8.02
7.84
7.71
7.68
7.65
7.57
15.38
13.23
12.97
12.96
12.92
12.08
12.05
11.78
11.59
11.55
11.46
11.29
10.99
10.79
31.09
31.34
31.57
31.68
31.58
31.70
31.80
23.03
23.12
23.16
23.23
23.46
24.37
25.72
26.28
27.35
28.07
28.57
29.18
29.45
29.68
29.81
29.93
30.06
30.22
30.46
30.61
30.80
30.94
31.22
31.37
31.55
31.64
31.78
31.90
31.91
31.94
31.99
15.90
20.27
22.00
22.05
22.35
24.48
25.37
26.35
27.18
27.46
27.82
28.42
28.90
29.12
24.13
24.37
24.59
24.70
24.61
24.73
24.83
17.10
17.19
17.22
17.28"
17.50
18.34
19.43
19.89
20.76
21.35
21.77
22.32
22.56
22.78
22.91
23.02
23.15
23.31
23.54
23.68
23.86
23.99
24.26
24.40
24.58
24.66
24.80
24.91
24.92
24.95
25.00
11.26
15.00
16.38
16.42
16-. 66
18.45
19.14
19.95
20.62
20.84
21.14
21.64
22.06
22.26
9.37
9.20
8.56
9.27
9.32
7.19
0.15
6.73
6.74
6.78
6.79
7.04
8.20
8.83
9.44
9.49
9.66
9.67
9.63
9.74
9.76
9.77
9.77
9.58
9.72
9.74
9.65
9.68
9.51
9.42
9.48
9.54
9.33
9.06
8.41
8.21
7.82
8.36
.
.
.
.
.
.
.
.
.
.
.
.
.
.
1.03
1.55
1.71
1.45
1.09
0.77
0.26
6.27
6.30
6.32
6.38
6.51
6.61
6.52
6.05
5.87
5.47
5.11
5.16
5.58
5.15
4.64
4.22
3.92
3.94
3.18
2.78
1.93
1.43
1.76
2.06
2.21
2.54
2.59
2.78
2.88
2.95
3.17
.
.
.
*
.
.
.
*
.
.
,
.
*
.
7.48
7.45
7.59
7.59
7.56
7.30
6.39
7.59
7.62
7.64
7.68
7.76
7.91
8.03
8.12
8.00
8.02
7.93
7.84
7.91
7.97
7.90
7.87
7.72
7.81
7 .IB
7.70
7.65
7.54
7.50
7.53
7.62
7.59
7.61
7.63
7.64
7.66
7.64
7.01
7.26
7.52
7.64
7.64
8.02
7.89
7.89
7.89
7.77
7.77
7.77
7.64
7.77
                               A-56

-------
Sta
Date
Time   Depth   Temp   Sal   Sig-T   Trans
DO
                                                                   PH
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-1
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3
5-3 '
5-3
5-3
5-3
5-3
5-3
5-3
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
5-5
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
1445
1445
1445
1445
1445
1445
1445
1445
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1510
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
15.0
16.2
17.3
18.6
19.8
21.6
23.2
25.6
0.3
0.7
1.5
2.5
4.1
5.1
6.0
8.1
10.5
11.4
13.4
15.4
17.6
19. 6
21.7
23.6
25.6
27.6
29.7
31.7
35.3
37.3
39.2
41.2
43.7
45.7
47.8
49.0
1.3
2.5
3.8
5.5
7.3
8.5
10.3
12.8
14.7
16.0
17.2
19.1
20.3
23.4
25.2
28.3
10.73
10.60
10.41
10.33
10.25
10.00
9.92
9.68
12.52
12.46
12.35
12.23
12.07
11.71
11.57
11.31
11.02
10.89
10.72
10.38
10.24
9.89
9.81
9.69
9.43
9.19
8.95
8.67
8.20
8.05
7.78
7.65
7.57
7.52
7.50
7.51
13.25
12.44
12.20
12.14
11.53
11.41
11.09
10.93
10.73
10.52
10.41
10.24
10.07
9.79
9.67
9.34
29.22
29.34
29.52
29.59
29.38
29.89
29.96
30.16
23.75
23.75
23.83
23.97
25.38
26.61
27.42
28.60
29.00
29.19
29.34
29.65
29.82
30.07
30.15
30.12
30.24
30.57
30.67
30.95
31.06
31.19
31.34
31.50
31.70
31.80
31.87
31.92
23.24
23.80
24.06
25.08
27.76
28.30
28.83
29.06
29.24
29.42
29.52
29.66
29.81
30.04
30.13
30.40
22.35
22.47
22.64
22.71
22.55
22.99
23.06
23.25
17.83
17.84
17.92
18.05
19.16
20.17
20.82
21.78
22.14
22.31
22.45
22.75
22.90
23.15
23.23
23.22
23.33
23.65
23.75
24.09
24.12
24.24
24.38
24.54
24.74
24.82
24.89
24.94
17.29
17.86
18.10
18.90
21.08
21.52
21.99
22.19
22.37
22.54
22.64
22.78
22.91
23.14
23.23
23.49
.
.
,
,
.
.
w
•
8.08
8.03
8.10
8.14
8.29
9.31
9.46
9.51
9.50
9.52
9.53
9.53
9.52
9.51
9.49
9.53
9.51
9.50
9.48
9.44
9.41
9.38
9.30
9.28
9.21
9.16
8.93
8.72

.
,
.
.
.
.
.
.
.
.
.
.
.
•
.
.
.
^
.
m
.
.
•
7.88
7.84
7.67
7.46
7.39
7.26
7.08
6.80
6.64
6.55
6.33
6.21
5.92
5.79
5.66
5.31
4.87
4.39
3.92
3.78
3.85
3.73
3.78
3.87
4.03
4.10
4.17
4.24

.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
7.77
7.64
7.64
7.64
7.64
7.64
7.64
7.52
8.03
8.06
8.11
8.13
8.09
8.12
8.12
8.07
8.05
8.05
8.03
8.01
8.00
7.97
7.96
7.96
7.91
7.89
7.82
7.78
7.79
7.77
7.75
7.76
7.76
7.77
7.77
7.77
7.39
7.77
8.02
8.02
8.02
8.02
8.02
8.02
8.02
7.89
7.89
7.89
7.89
7.89
7.89
7.77
                                A-57

-------
Sta     Date     Time   Depth   Temp   Sal   Sig-T    Trans    DO     pH


                                                                .   7.77
                                                                .   7.64
                                                                .   7.64
                                                                .   7.64
                                                                .   7.64
                                                                .   7.52
                                                                .   7.52
5-5
5-5
5-5
5-5
5-5
5-5
5-5
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
9-21-88
1526
1526
1526
1526
1526
1526
1526
31
33
35
37
39
42
44
.4
.9
.2
.2
.7
.8
.7
8
8
8
8
7
7
7
.94
.50
.43
.16
.95
.67
.58
30
31
31
31
31
31
31
.77
.15
.21
.43
.60
.84
.92
23
24
24
24
24
24
24
.84
.21
.26
.48
.64
.87
.94
                                 A-58

-------
                                % Light Transmittance
                                 4             6
                                 8
                             10
                              Dissolved Oxygen (mg/L)
                                    4               6
                                       8
                                   pH (pH units)
                                        8
                                              10
                              Density Excess (Sigma—t)
                            10             15             20
                                           25
                   10
       Salinity (p.p.t.)
   15          20
          25
30
             8
    Temperature (Deg. C.)
10              12
              14
       16
   5 -
  ID-
  15-
Q

Q
  20-
  25-
   30 J
  Temperature


 • Salinity


  Sigma—t
                                             — — —  Dissolved Oxygen
_ _ _ _ %_ Light Transmittance
              Date=08/21/88  Station=1-1  Time=1630
                                    A-59

-------
                               £ U'qht Transmittance
                                4            6
                              8
                  10
     Salinity (p.p.t)
  15          20
         25
                            10
0
6

Dissolved Oxygen (mg/L)
246
pH (pH units)
7 8
Density Excess (Sigma— t)
5 10 15

9
20
8
10
25
30
                               Temperature (Deg. C.)
                           10             12
                            14
                            16
   5 -
   10-
£

-t~>

a
a
o
  20-
   25-
  30
Temperature


Salinity


Sigma—t
       PH
                                            — — — Dissolved Oxygen
— — — % Light Transmittance
             Date=08/21/88   Station=1-2  Time-1645
                                 A-60

-------
     0
    % Light Transmittance
     4             6
              8
       10
                               Dissolved Oxygen (mg/L)
                                    4               6
                                       8
                                   pH (pH units)
                                        8
                                              10
                              Density Excess (Sigma—t)
                            10             15
                             20
                         25
                   10
       Salinity (p.p.t.)
   15          20
         25
30
  0
             8
    Temperature (Deg. C.)
10              If
             14
       16
   5 -
  10-
£-15-
a
a
  20-
  25-
  30-1
  Temperature



  Salinity



  Sigma—t
                                             — — — - Dissolved Oxygen
— — — % -Light Transmittance
              Date-08/21/88  Station=1-3  Time=1700
                                     A-61

-------
  5 -
  10-
                            X Light Transmtttanco
                             4            6
                            8

                          10
Dissolved Oxygen (mg/L)
246
pH (pH units)
• 789
Density Excess (Sigma— t)
5 10 15 20
Salinity (p.p.t)
5 10 15 20 25
Temperature (Deg. C.)
8 10 12 14
«:::::. 	 ••"*"**—•!:
8
10
25
30
16
^
o
Q

fc
  20-
  25-
   30
Temperature     i «•«•!••• 11  pH
 Salinity


• Sigma-t
                                         — — — - Dissolved Oxygen
- — — — X Light Transm'rttance
             Date=08/21/88  Station=2-5  Time=1715
                                A-62

-------
     0
    % Light Transmittance
     4             6
              8
                  10
      Salinity (p.p.t.)
   15         20
        25
30
       10
0
6

Dissolved Oxygen (mg/L)
246
pH (pH units)
7 8
Density Excess (Sigma— t)
5 10 15

9
20
8
10
25
            8
    Temperature (Dcg. C.)
10             12
            14
       16
  10-
  20-
g-30
a
a
o
  40-
  50-
  60 -J
  Temperature

  Salinity

  Sigma—t
— — - Dissolved Oxygen

— —  — %-Light Transmittance
             Date=08/21/88   Station=4-3  Time-1245
                                   A-63

-------
                                % Light Transmittance
                                 4             6
                                 8
                            10
     0
   Dissolved Oxygen (mg/L)
        4               6
                    8
                                    pH (pH units)
                                        8
                                               10
                               Density Excess (Sigma—t)
                            10             15
                             20
                         25
                   10
       Salinity (p.p.t.)
   15          20
        25
30
   0
             8
    Temperature (Deg. C.)
10              12
            14
       16
  10-
  20-
a
a
$5
  40-
  50-
   60 -J
  Temperature

 • Salinity

  Sigma—t
                                                      pH
— —   Dissolved Oxygen

— — — % tight Transmittance
              Date=08/21/88   Station=5-1   Time=1 145
                                      A-64

-------
                               % Light Transmittonce
                                4             6
                                8
                                                                       10
     0
   Dissolved Oxygen (mg/L)
        4              6
                                                               8
                                   pH (pH units)
                                       8
                                              10
                              Density Excess (Sigma—t)
                           10             15             20
                                           25
                   10
       Salinity (p.p.O
   15          20
                                                   25
30
            8
    Temperature (Deg. C.)
10             12
                                                       14
       16
  10-
  20-
a
a
  40-
  50-
60-"
                             Temperature

                             Salinity

                             Sigma—t
                         PH
                — — —   Dissolved Oxygen

                _ _ _ _ % Light Transmittance
             Date-08/21/88  Station=5-2  Time-1200
                                   A-65

-------
     0
    % Light Transmittance
     4             6
             8
       10
                              Dissolved Oxygen (mg/L)
                                   4               6
                                      8
                                   pH (pH units)
                                       8
                                              10
                              Density Excess (Sigma—t)
                           10             15
                            20
                        25
                   10
       Salinity (p.p.t.)
   15          20
       25
30
            8
    Temperature (Deg. C.)
10             12
           14
       16
  10-
  20-
a
a
o
  40-
  50-
  60 -1
  Temperature

  Salinity

  Sigma—t
— — Dissolved Oxygen

— —  %_ Light Transmittance
              Date=08/21/88   Station=5-3  Time-1210
                                    A-66

-------
     0
    % Light Transmittance
     4             6
               8
       10
     0
   Dissolved Oxygen (mg/L)
        4               6
                     8
                                    pH (pH units)
                                         8
                                               10
                               Density Excess (Sigma—t)
                            10             15
                             20
                          25
                   10
       Salinity (p.p.t.)
   15          20
         25
30
   0
             8
    Temperature (Deg. C.)
10              12
             14
       16
  10-
  20-
£

-*-•

Q
Q
   40-
   50-
   60 -I
  Temperature

  Salinity

  Sigma—t
 — — — Dissolved Oxygen

— — —  %- Light Transmittance
              Date-08/21/88   Station=5-4  Time-1225
                                      A-67

-------
                                % Light Transmittance
                                 4              6
                                 8
                     10
     0
   Dissolved Oxygen (mg/L)
        4               6
              8
                                    pH (pH units)
                                         8
                                               10
                               Density Excess (Sigma—t)
                            10             15
                             20
                  25
                   10
       Salinity (p.p.L)
   15          20
  25
30
   0
             8
    Temperature (Deg. C.)
10              12
      14
       16
  10-
  20-
a
a
o
  40-
  50-
   60 -I
  Temperature

 • Salinity

  Sigma—t
Dissolved Oxygen

%_ Light Transmittance
              Date=08/21/88   Station=5-5
                                     A-68

-------
     0
                              % Light Transmittance
                               4             6
                                                           8
                                            10
                               Dissolved Oxygen (mg/L)
                                     46
                                                                  8
                                    pH (pH units)
                                         8
                                                                         10
                               Density Excess (Sigma— t)
                             10              15
                                                        20
                                                                      25
                    10
    Salinity (p.p.t.)
15          20
                                                      25
                                                                  30
   0
             8
                              Temperature (Deq. C.)
                          10              1.
                                                          14
                                            16
   5 -
   10-
£

-+-•

a
a
15-
   20-
25-
30 -J
                               Temperature


                               Salinity


                              • Sigma—t
                                                    Dissolved Oxygen
                                            — —  — •%- Light Transmittance
                Date=08/21/88  Station=50   Time=1125
                                     A-69

-------
                               % Light Transmittance
                                4            6
                                8
                  10
       Salinity (p.p.t.)
   15          20
        25
30
                           10
0
6

Dissolved Oxygen (mg/L)
246
pH (pH units)
789
Density Excess (Sigma— t)
5 10 15 20
8
10
25
            8
    Temperature (Deg. C.)
10             12
            14
       16
  10-
  20-
8-3CH
o
  40-
  50-
  60 J
  Temperature
  Salinity
  Sigma—t
                                                   PH
— — - Dissolved Oxygen
— —  — % Light Transmittance
              Date=08/21/88  Station=51  7ime=1110
                                    A-70

-------
                               % Light Transmittance
                                4             6
                                8
                             10
     0
   Dissolved Oxygen (mg/L)
        4              6
                                   pH (pH units)
                                       8
                                              10
                              Density Excess (Sigma—t)
                            10             15
                            20
                          25
                   10
       Salinity (p.p.t.)
   15          20
          25
30
             8
    Temperature (Deg. C.)
10             12
              14
       16
   5 -
  ID-
Q

Q

O
  20-
  25-
  30 -I
  Temperature


  Salinity


  Sigma—t
                                            — — — - Dissolved Oxygen
- — —  —%- Light Transmittance
              Date=08/23/88   Station=1-2   Time=1430
                                    A-71

-------
                                % Light Transmittance
     0             2             4             6             8             10

                               Dissolved Oxygen (mg/L)
     02468

                                   pH (pH units)
     6                 7                8                 9                10

                               Density Excess (Sigma—t)
              5             10             15            20             25

                                   Salinity (p.p.t.)
        5           10          15          20          25           30

                                Temperature (Deg. C.)
             8              10              12             14              16
   5 -
  10-
g-15
a
a   '
o
  20-
  25 -                	Temperature     	•••••• pH


                      ————— Salinity         — — —   Dissolved Oxygen


  30—'                	Sigma—t        — —  — - %- Light Transmittance





              Date=08/23/88   Station=2-3   Time-1042
                                     A-72

-------
     0
    % Light Transmittance
     4             6
               8
       10
     0
   Dissolved Oxygen (mg/L)
        4               6
                                   pH (pH units)
                                        8
                                               10
                               Density Excess (Sigma—t)
                            10             15
                             20
                          25
                   10
       Salinity (p.p.L)
   15          20
          25
30
  0
             8
    Temperature (Deg. C.)
10              12
              14
       16
   5 -
  10-
g-15
a
  20-
  25-
  30-•
  Temperature


  Salinity


  Sigma—t
        pH
                                              — — —  Dissolved Oxygen
— — —  %-Ljght Transmittance
              Date=09/20/88  Station=Dock  Time=0930
                                      A-73

-------
                                 % Light Transmittance
                                  4              6
                                  8
                    10
     0
   Dissolved Oxygen (mg/L)
        4               6
            8
                                    pH (pH units)
                                         8
                                                10
                                Density Excess (Sigma—t)
                             10             15
                              20
                 25
                    10
       Salinity (p.p.t)
   15           20
25
30
   0
             8
    Temperature (Deg. C.)
10              12
    14
        16
   5 -
  ID-
S'15
a
a
  20-
  25-
   30-1
  Temperature     ........... pH


  Salinity          —  — — Dissolved Oxygen


  Sigma—t         — —  — • %-Light Transmittance
               Date=09/20/88   Station-1 -1   Time-1009
                                      A-74

-------
     0
    % Light Transmittance
     4             6
      8
       10
     0
   Dissolved Oxygen (mg/L)
        4               6
                                   pH (pH units)
                                        8
                                               10
                               Density Excess (Sigma—t)
                            10             15
                             20
                25
                   10
       Salinity (p.p.t.)
   15          20
25
30
             8
    Temperature (Deq. C.)
10              12
    14
       16
   5 -
   10-
£

-«-•

o
Q
   20-
                                     \
   25-
   30-1
  Temperature      	• • • • •  pH


 • Salinity           —  — —  Dissolved Oxygen


  Sigma—t        — — —   %- Light Transmittance
              Date=09/20/88   Station=1-2   Time=1039
                                     A-75

-------
                                % Light Transmittance
                                  4              6
                                                            8
                10
                             Dissolved Oxygen (mg/L)
                                  4               6
                                                                    8
                                    pH (pH units)
                                         8
                                                                          10
                             Density Excess (Sigma—t)
                          10             15             20
                                                                         25
                   10
    Salinity (p.p.L)
15          20
                                                      25
        30
             8
                              Temperature (Deg. C.)
                          10              12
14
                                            16
   5 -
  10-
S-15H
Q
  20-
25-
30-1
                               Temperature      • • • •	  pH


                              . Salinity          - — —  — Dissolved Oxygen


                               Sigma—t        • —  — —  % -Light Transmittance
              Date=09/20/88  Station-1 -3  Time-1103
                                      A-76

-------
     0
    % Light Transmittance
     4             6
               8
       10
                               Dissolved Oxygen (mg/L)
                                    4               6
                                       8
                                    pH (pH units)
                                        8
                                               10
                               Density Excess (Sigma—t)
                            10             15
                             20
                          25
                   10
       Salinity (p.p.t.)
   15          20
          25
30
  0
             8
    Temperature (Dcg. C.)
10              12
              14
       16
   5 -
  10-
8-15H
Q
Q

O
  20-
  25-
  30 J
  Temperature


 • Salinity


  Sigma-t
        PH
                                               — —  — Dissolved Oxygen
— — —  7
-------
                               X Light Trarwmlttance
                                4              6
                                                         8
                            10
                             Dissolved Oxygen (mg/L)
                                   4              6
                                                                8
    6
                               pH (pH units)
                                    8
           9
       10
                           10
                           Density Excess (Sigma—t)
                                       1 w
           20
    25
                  10
                               Salinity Tp.p.
                            15          20
         25
30
            8
                         10
                               Temperature
                                       (Deg. C.)
             14
       16
  10
                                                                     I
                                                                     \
f
o
a
15
   20-
   25-
   30
                            Temperature


                           • Salinity


                            Sigma—t
        pH
                                             — — — Dissolved Oxygen
— — — • % Light Transmittance
                Date=09/20/88   Station-2-2  Time=ll38
                                     A-78

-------
                              X Ught Transmlttance
                               4             6
                             8
                                             10
                             Dissolved Oxygen (mg/L)
                                  4              6
                                    8
    6
     pH (pH units)
         8
                            9
                                          10
                             Density Excess (Sigma—t)
                          10            15            20
                                        25
10
15
                                 Salinity (p.p.
               p.L)
               20
                        25
                                                                 30
            8
    Temperature (Dog. C.)
10             12
                            14
                                          16
  10
o
a
  15
  20-
   25-
   30
     J
 Temperature


> Salinity


 Sigma—t
                                            - — — — Dissolved Oxygen
                  — — —  X Light Transmittance
              Date=09/20/88   Station-2-3  Time-1202
                                    A-79

-------
                            % Light Tranamfttanca
                             4             8
                                8
                               10
                           Dissolved Oxygon (mg/L)
                                 4               6
                                      8
                                pH (pH units)
                                    8
                             9
                               10
                         10
                           Density Excess
              (Sigma-t)
                            20
                            25
10
15
                               Salinity (p.p.
p.L)
20
                           25
                                                               30
          8
10
                             Temperature
              (Deg. C.)
                14
                                           16
5 -
10
  -
20-
25-
 30
                                                                   I

                                                                   I
  Temperature


  • Salinity


  Sigma—t
           pH
                                          -  — — — Dissolved Oxygen
    — — — % Light Transm'rttance
            Date=09/20/88   Station=2-4   Time-1226
                                 A-80

-------
     0
    % Light Transmittance
     4             6
               8
       10
     0
  Dissolved Oxygen (mg/L)
        4              6
                     8
                                   pH (pH units)
                                        8
                                              10
                              Density Excess (Sigma—t)
                            10             15            20
                                           25
                   10
       Salinity (p.p.t)
   15          20
          25
30
  0
             8
    Temperature (Deq. C.)
10             12
             14
       16
   5 -
  10-
S-15H
a
  20-
  25-
  30-1
  Temperature



 i Salinity



  Sigma—t
                                             — — —  Dissolved Oxygen
— — —  7
-------
     0
    % Light Transmittance
     4             6
             8
       10
                               Dissolved Oxygen (mg/L)
                                    4               6
                                       8
                                   pH (pH units)
                                        8
                                              10
                              Density Excess (Sigma—t)
                            10            15
                             20
                        25
                   10
       Salinity (p.p.L)
   15          20
       25
30
             8
    Temperature (Deg. C.)
10             12
           14
       16
  10-
  20-
S-30-i
a
  40-
  50-
   60-1
  Temperature

 • Salinity

  Sigma-t
— —  Dissolved Oxygen

— —  % bight Transmittance
              Date=09/20/88  Station-3-3  Time= 1343
                                    A-82

-------
     0
    % Light Transmittance
     4             6
      8
       10
     0
   Dissolved Oxygen (mg/L)
        4               6
                                   pH (pH units)
                                        8
                                               10
                              Density Excess (Sigma—t)
                            10             15
                             20
                25
                   10
       Salinity (p.p.t.)
   15          20
25
30
             8
    Temperature (Deq. C.)
10              12
    14
       16
   5 -
  10-
g-15-
a
a
  20-
  25-
   30-1
  Temperature     •••.••••••  pH


  Salinity          — — — - Dissolved Oxygen


  Sigma—t        - — — — %_Light Transmittance
              Date=09/20/88  Station=3-5  Time-1354
                                     A-83

-------
                               % Light Transmittance
                                4             6
                                8
                           10
     0
  Dissolved Oxygen (mg/L)
        4              6
                                  pH (pH units)
                                       8
                                             10
                              Density Excess (Sigma—t)
                           10             15
                            20
                        25
                   10
       Salinity (p.p.t.)
   15          20
        25
30
  0
            8
    Temperature (Deg. C.)
10             12
            14
       16
  10-
  20-
S-30H
Q
Q   '
  40-
  50-
  60-1
  Temperature

  Salinity

  Sigma—t
                                                    pH
 — — - Dissolved Oxygen

— — — % -Light Transmittance
              Date=09/20/88   Station=4-2  Time-1454
                                    A-84

-------
                              % Light Transmittance
                               4            6
                               8
                           10
0
6

Dissolved Oxygen (mg/L)
246
pH (pH units)
7 8
Density Excess (Sigma— t)
5 10 15

g
20
8
10
25
                  10
       Salinity (p.p.t)
   15         20
         25
30
            8
    Temperature (Deg. C.)
10             12
             14
       16
  10-
  20-J
a
a
o
  40-
  50-
  60-
  Temperature

  Salinity

  Sigma—t
— — — Dissolved Oxygen

— — — % Light Transmittance
             Date=09/20/88  Station=5-2  Time=1553
                                 A-85

-------
     0
    % Light Transmittance
     4              6
                 8
        10
     0
   Dissolved Oxygen (mg/L)
        4               6
                       8
                                    pH (pH units)
                                         8
                                                10
                               Density Excess (Sigma—t)
                             10             15
                              20
                           25
                    10
       Salinity (p.p.L)
   15           20
           25
30
             8
    Temperature (Deg. C.)
10              If
               14
        16
   5 -
                                                                      _. rf
  10-
g-15
Q

Q

O
  20-
  25-
   30-"
  Temperature


 • Salinity


  Sigma—t
                                               — —  —  Dissolved Oxygen
— — — - %- Light Transmittance
               Date=09/21 /88   Station^ 1-1   Time= 1835
                                      A-86

-------
     0
    % Light Transmittance
     4             6
      8
       10
                              Dissolved Oxygen (mg/L)
                                    4              6
                                       8
                                   pH (pH units)
                                        8
                                              10
                              Density Excess (Sigma—t)
                            10            15
                             20
                25
                   10
       Salinity (p.p.t.)
   15          20
25
30
  0
             8
    Temperature (Deg. C.)
10             12
    14
       16
   5 -
  10-
8-15-
a
a   '
o
  20-
  25-
  30 -J
  Temperature      •	 pH


 • Salinity          — — — Dissolved Oxygen


 • Sigma—t        —  — — • % -Light Transmittance
              Date=09/21/88  Station-1-2  Time=1840
                                     A-87

-------
                                % Light Transmittance
     0             2             4             6             8            10
0
6

Dissolved Oxygen (mg/L)
246
pH (pH units)
789
Density Excess (Sigma— t)
5 10 15 20
8
10
25
                                   Salinity (p.p.t.)
                   10          15          20          25          30

                                Temperature (Deg. C.)
             8              10              12              14              16
   5 -
  10-
8-15-
a
a   '
o
  20-
  25-
  30 J
Temperature     •••••••••• pH
                              Salinity          — — — — Dissolved Oxygen
Sigma—t        • — — —  %- Light Transmittance
              Date=09/21/88  Station-1-3  Time-1848
                                     A-88

-------
     0
    % Light Transmittance
     4             6
                             8
               10
     0
   Dissolved Oxygen (mg/L)
        4               6
                                    8
                                    pH (pH units)
                                        8
                                               10
                               Density Excess (Sigma—t)
                            10             15             20
                                            25
                   10
       Salinity (p.p.L)
   15          20
                        25
        30
   0
             8
10
Temperature (Deg. C.)
            12
14
16
   5 -
  10-
8-15H
a
a
o
  20-
  25-
  Temperature


 • Salinity


  Sigma—t
                                              — —  —  Dissolved Oxygen
                                             — — —  - %-Light Transmittance
              Date=09/21 /88   Station=2-1   Time= 1805
                                    A-89

-------
     0
    % Light Transmittance
     4            6
                            8
                  10
      Salinity (p.p.t.)
   15          20
                       25
               10
0
6

Dissolved Oxygen (mg/L)
246
pH (pH units)
7 8
Density Excess (Sigma— t)
5 10 15

9
20
8
10
25
        30
            8
10
Temperature (Deg. C.)
           12
14
16
  5 -
  10-
8-15-1
a
a
o
  20-
  25-
  30 -I
  Temperature


 • Salinity


  Sigma—t
             	 pH


              — — — Dissolved Oxygen


             —  — —  %- Light Transmittance
              Date=09/21/88  Station-2-2   Time-1820
                                   A-90

-------
     0
    % Light Transmittance
     4             6
                8
       10
     0
  Dissolved Oxygen (mg/L)
        4               6
                                    pH (pH units)
                                        8
                                               10
                               Density Excess (Sigma—t)
                            10             15             20
                                            25
                   10
       Salinity (p.p.t.)
   15          20
           25
30
  0
             8
    Temperature (Deg. C.)
10              1.
               14
       16
   5 -
  10-
g-15
a
Q
  20-
  25-
   30-J
  Temperature


  Salinity


  Sigma—t
                                             — — —  Dissolved Oxygen
- — — — %- Light Transmittance
              Date=09/21 /88  Station=2-3a   Time= 1743
                                     A-91

-------
     0
    % Light Transmittance
     4             6
                                          10
                              Dissolved Oxygen (mg/L)
                                   4              6
                                   pH (pH units)
                                       8
                                              10
                              Density Excess (Sigma—t)
                            10             15
                             20
                                       25
                   10
       Salinity (p.p.t.)
   15          20
                       25
        30
             8
10
Temperature (Deg. C.)
            12
14
16
   5 -
  10-
a
a
fc
  20-
  25-
  30 -J
  Temperature


  Salinity


  Sigma—t
                      PH
                                              — — — Dissolved Oxygen
              — — —  %~ Light Transmittance
             Date=09/21/88  Station-2-3b   Time-1749
                                    A-92

-------
     0
                            % Light Transmittance
                              4             6
      8
                   10
                               Salinity (p.p.t)
                            15         20
25
       10
0
6

Dissolved Oxygen (mg/L)
246
pH (pH units)
789
Density Excess (Sigma— t)
5 10 15 20
8
10
25
30
   0
             8
                             Temperature (Deg. C.)
                         10             12
    14
       16
   5 -
  ID-
£

-t-»

0
Q
15-
   20-
   25-
   30-1
                           Temperature      •••••	  pH
                              Salinity         — — —  Dissolved Oxygen
                           Sigma—t        - —  — — %-Light Transmittance
             Date=09/21 /88  Station=2-3c   Time=1750
                                    A-93

-------
     0
                              % Light Transmittance
                               4             6
               8
       10
                               Dissolved Oxygen (mg/L)
                                     4              6
                                    pH (pH units)
                                         8
                                                                         10
                               Density Excess (Sigma—t)
                            10             15
                                                       20
                         25
                   10
                                 Salinity (p.p.t.)
                             15          20
         25
30
   0
             8
                              Temperature (Deq. C.)
                          10              12
             14
       16
   5 -
   ID-
^E

•+-•

Q
Q

fc
15-
   20-
   25-
   30 -I
                            Temperature


                            Salinity


                            Sigma—t
                                             -  — — — Dissolved Oxygen
— — — % -Light Transmittance
              Date=09/21 /88  Station=2-3d   Time= 1745
                                    A-94

-------
     0
    % Light Transmittance
     4             6
                8
       10
     0
   Dissolved Oxygen (mg/L)
        4               6
                      8
                                   pH (pH units)
                                        8
                                               10
                               Density Excess (Sigma—t)
                            10             15             20
                                            25
                   10
       Salinity (p.p.t.)
   15          20
          25
30
             8
    Temperature (Deg. C.)
10              12
              14
       16
   5 -
  10-
8-15
a
Q
  20-
  25-
  30 -I
  Temperature


 ' Salinity


  Sigma—t
                                              —  — —  Dissolved Oxygen
— — —  %-LJght Transmittance
              Date-09/21 /88   Station-2-3e  Time=1750
                                    A-95

-------
  5 -
  10-
8-15-
a
a
o
  20-
  25-
  30 -J
                             % Light Transmittance
                              4            6
Temperature


Salinity


Sigma—t
                                         10
Dissolved Oxygen (mg/L)
) 2 4 6
pH (pH units)
5789
Density Excess (Sigma— t)
5 10 15 20
Salinity (p.p.t.)
5 10 15 20 25
Temperature (Deg. C.)
8 10 12 14
8
10
25
30
16
                                          — — —  Dissolved Oxygen
— — —  • %-Light Transmittance
            Date=09/21/88  Station=2-3f  Time-1755
                                  A-96

-------
                                 % Light Transmittance
                                  4             6
                                 8
                                            10
     0
   Dissolved Oxygen (mg/L)
        4               6
                                    8
                                    pH (pH units)
                                         8
                                                10
                               Density Excess (Sigma—t)
                             10              15
                             20
                                        25
                   10
       Salinity (p.p.t)
   15          20
                        25
        30
             8
10
Temperature (Deq. C.)
            12
14
16
   5 -
  10-
a
a
  20-
  25-
  30-"
  Temperature


  Salinity



  Sigma—t
                                             —  — — - Dissolved Oxygen
              — — — % Light Transmittance
              Date=09/21/88   Station=2-4
                                    A-97

-------
                               % Light Transmittcmce
                                 4             6
                                                          8
                                                                       10
     0
                            Dissolved Oxygen (mg/L)
                                 4              6
                                   pH (pH units)
                                        8
                                                                       10
                              Density Excess (Sigma—t)
                            10             15
                                                      20
                                                                    25
                   10
                                Salinity (p.p.t.)
                            15          20
                                                    25
30
   0
             8
                             Temperature (Deg. C.)
                         10              12
                                                        14
       16
   5 -
   10-
£

-*-•

Q
a
  20-
25-
30 -J
                              Temperature


                              Salinity


                              Sigma—t
                                             — — Dissolved Oxygen
                                           — — — % tight Transmittance
              Date=09/21/88  Station-2-5   Time-1720
                                    A-98

-------
     0
    % Light Transmittance
     4             6
      8
       10
     0
   Dissolved Oxygen (mg/L)
        4               6
                                    pH (pH units)
                                         8
                                               10
                               Density Excess (Sigma—t)
                            10             15             20
                                            25
                    10
       Salinity (p.p.L)
   15          20
25
30
   0
             8
    Temperature (Deg. C.)
10              12
    14
       16
   5 -
  10-
8-15
a
a
fc
  20-
  25-
   30-1
  Temperature     ••••••••••• pH


 ' Salinity          — — —  Dissolved Oxygen


 • Sigma—t        — — — - % Light Transmittance
              Date=09/21 /88  Station=3-1   Time= 1630
                                      A-99

-------
     0
    % Light Transmittance
     4             6
              8
       10
     0
  Dissolved Oxygen (mg/L)
        4              6
                    8
                                   pH (pH units)
                                       8
                                              10
                              Density Excess (Sigma—t)
                           10             15
                            20
                        25
                   10
       Salinity (p.p.t.)
   15          20
        25
30
             8
    Temperature (Deq. C.)
10             12
            14
       16
  10-
  20-
g-30
a
a   -
o
  40-
  50-
  60-J
  Temperature

  Salinity

  Sigma—t
                                                     pH
— —  Dissolved Oxygen

— — - % light Transmittance
              Date=09/21/88   Station=3-3  Time=1700
                                   A-100

-------
     0
                             % Light Transmittance
                              4             6
                                                         8
                                           10
  0
                              Dissolved Oxygen (mg/L)
                                   46
                                   pH (pH units)
                                       8
                                                                       10
                              Density Excess (Sigma— t)
                           10             15
                                                      20
                                                                    25
                   10
   Salinity (p.p.t.)
15          20
                                                    25
                                                                30
            8
                         10
                             Temperature (Deg. C.)
                                        12
                           14
16
  5 -
  10-
8-15'
D

Q

O
  20-
25-
30 -•
                             Temperature


                             Salinity


                             Sigma—t
                                          —  — —  Dissolved Oxygen
                                          — — — - %-Light Transmittance
              Date=09/21/88   Station-3-5  Time=1710
                                   A-101

-------
     0
    % Light Transmittance
     4             6
               8
       10
                               Dissolved Oxygen (mg/L)
                                     4               6
                                        8
                                    pH (pH units)
                                         8
                                                10
                               Density Excess (Sigma—t)
                             10              15
                              20
                          25
                    10
       Salinity (p.p.t.)
   15          20
         25
30
             8
    Temperature (Deg. C.)
10              12
             14
        16
  10-
  20-
J,

•*-•

Q
Q

O
   40-
   50-
   60 J
  Temperature

  Salinity

  Sigma—t
                                                       pH
 — — — Dissolved Oxygen

— — —  % -Light Transmittance
               Date=09/21 /88  Station=4-1   Time-1620
                                      A-102

-------
  0
  % Light Transmittance
   4             6
              8
       10
  0
 Dissolved Oxygen (mg/L)
      4               6
                    8
                                pH (pH units)
                                     8
                                            10
                            Density Excess (Sigma—t)
                         10             15             20
                                         25
                10
     Salinity (p.p.L)
 15          20
        25
30
                             Temperature (Deg. C.)
                         10              12
60 -1
Temperature

Salinity

Sigma—t
                             14
                           16
 — —  Dissolved Oxygen

_ —  .%_ Light Transmittance
           Date=09/21/88  Station-4-2  Time-1600
                                 A-103

-------
                               % Light Transmittance
                                4             6
                                8
                           10
     0
  Dissolved Oxygen (mg/L)
        4              6
                    8
                                  pH (pH units)
                                       8
                                              10
                              Density Excess (Sigma—t)
                           10             15
                            20
                        25
                   10
       Salinity (p.p.L)
   15          20
        25
30
  0
            8
    Temperature (Deg. C.)
10             12
            14
       16
  10-
  20-
g-30
a
Q
  40-
  50-
  60-1
  Temperature

  Salinity

  Sigma—t
	 pH

 — — Dissolved Oxygen

 — — • % Light Transmittance
              Date=09/21/88   Station=4-3  Time=1550
                                    A-104

-------
     0
    % Light Transmittance
     4             6
               8
       10
                               Dissolved Oxygen (mg/L)
                                    4               6
                                        8
                                    pH (pH units)
                                        8
                                               10
                               Density Excess (Sigma—t)
                            10             15             20
                                            25
                   10
       Salinity (p.p.L)
   15          20
         25
30
             8
    Temperature (Deg. C.)
10              12
             14
        16
  10-
  20-
g-30
a
a
o
  40-
  50-
  60-1
  Temperature

 • Salinity

 • Sigma—t
 — — — Dissolved Oxygen

_ _ _ %-Light Transmittance
              Date=09/21 /88   Station=5-1   Time= 1445
                                    A-105

-------
     0
    % Light Transmittance
     4             6
              8
       10
     0
   Dissolved Oxygen (mg/L)
        4              6
                    8
                                   pH (pH units)
                                       8
                                              10
                              Density Excess (Sigma—t)
                           10             15             20
                                           25
                   10
       Salinity (p.p.t.)
   15          20
        25
30
            8
    Temperature (Deg. C.)
10             12
            14
       16
  10-
  20-
a

£
o
  40-
  50-
  60 -J
  Temperature

  Salinity

  Sigma—t
                                                    pH
— — - Dissolved Oxygen

— —  — % Light Transmittance
             Date=09/21/88  Station-5-3   Time=1510
                                 A-106

-------
     0
    % Light Transmittance
     4             6
            8
                  10
      Salinity (p.p.t.)
   15         20
       25
       10
0
6

Dissolved Oxygen (mg/L)
246
pH (pH units)
7 8
Density Excess (Sigma— t)
5 10 15

9
20
8
10
25
30
            8
    Temperature (Deg. C.)
10             12
           14
       16
  10-
  20-
£

-*-•

a
a
  40-
  50-
   60 -1
  Temperature

  Salinity

  Sigma—t
— — Dissolved Oxygen

— —  %_Light Transmittance
             Date=09/21/88   Station-5-5  Time=1526
                                  A-107

-------
    APPENDIX B






CHEMISTRY ANALYSES

-------
EPA MANCHESTER LAB

-------
                       List of Result Qualifiers  for Non-numeric results
Definition:
  A result qualifier indicates  the reason  the analysis did not produce a numerical result.
Qualifier

   FPS
Full name

Failed Preliminary Screening
   NSQ
Not Sufficient Quantity
   LAC
   FAC
Laboratoy Accident
Field Accident
   ISP
   NAI
   NAR
   CAN
   FQC
Improper Sample Preservation
Not Analyzed Due To Interference
No Analysis Result
Cancelled
Failed Quality Control
   BOL
Below Detection Limit
Definition

A preliminary screening of the
sample for the subject parameter
was conducted.
The result of the screening
indicated that it would not be
useful to determine the con-
centration of the parameter.

There-was not a sufficient
quantity of the sample to con-
duct an analysis to determine
the concentration of the subject
parameter-

There was an accident in the
laboratory that either destroyed
the sample or rendered it not
suitable for analysis.

There was an accident in the field
that either destroyed the sample or
rendered it not suitable for
analysis.

Due to improper preservation of the
sample it was rendered not suitable
for analysis.

Because of uncontrollable inter-
ference the analysis for the
subject parameter was not conducted.

There is no analysis result.
The reason is unspecified.

The analysis of this parameter
was cancelled and not performed.

The analysis result is unusable
because Quality Control limits were
exceeded when the analysis was
conducted.

Compound was analyzed, but found
below detection limits.
                                        B-l

-------
> a mp .
09:41:50




   Project: WTR-081A  AK.PULP  CORP./ KETCHIKAN PULP CO.




Laboratory: EPA, Manchester




 Sample  No: 88 350000             Description: MAIN OUTFALL  (001)




                                    Begin Date: 88/0»/21 07:00
                                                  Officer: DGB
                                                                        Account:  AFEB3A
                                                   Source: Industrial Effluent
| Gen Inorg/Phys-Speci
i
pH LAB
Sulf ide
| Solids -
1
Solids
| Demand —
1
BOD
COD
T-Org-C
| Metals -
1
Arsenic
Silver
Me rcury
| Metals -
I
Cadmium
Ch r omium
Coppe r
Lead
Nickel
Z inc

Meter
Total
Specified

T— Suspen
Specified

5 Day
Hi Level
Total
Specified

As-To ta 1
Ag-Total
Hg-Total
ICP Scan

Cd-Total
Cr-Tota'l
Cu — To t a 1
Pb-Total
Ni-Total
Zn-To t a 1
Water-Total
Result Units
2.80 * Std Unt£
.39 * mg/1
Wate r-Total
Result Units
45. * mg/1
Wate r-Total
Result Units
86. * mg/1
556. * mg/1
184. * mg/1
Water-Total
Result Units
1U ug/1
0 . 2U ug/1
< 0 . 0 8U ug/1
Water-Total
Result Units
5U ug/1
10U ug/1
7 * ug/1
SOU ug/1
10U ug/1
7 * ug/1
               (Sample Complete]

-------
     09:41:50                                  	,.._,._-.,	........

        Project:  WTR-081A  AK.PULP  CORP./ KETCHIKAN  PULP  CO.

     Laboratory:  EPA,  Manchester

      Sample No:  88  350009            Description: MAIN OUTFALL 001

                                        Begin Date: 88/08/24  07:00

                                          End Date: 88/08/25  07:00

     +	^	+
     |  Gen Ino rg/Phy s-Stgec i     Water-Total    |
     I               ''   ,"         Result   units  |
     +	%	+
     pH  LAB    Meter'            3.45  *  Std Unts
     Sulfide   Total             10.5  *  mg/1

     +	+
     |  Solids - Specified       Water-Total    |
     I                            Result   Units  |
     +	+
     Solids    T-Suspen           172  *  mg/1

     +	1-
     |  Demand - Specified       Water-Total    |
     I                            Result   Units  j
     -I	1-
     BOD        5  Day             111.  *  mg/1
     COD        Hi  Level          614.  *  mg/1
tfl    T-Org-c   Total             186.  *  mg/1
 I
W    +	+
     |  Metals - Specified       Water-Total    |
     |                            Result   Units  j

     Arsenic   As-Total              1U   ug/1
     Silver    Ag-Total          '0.2  *  ug/1
     Mercury   Hg-Total          3.91  *  ug/1

     +	+
     |  Metals - ICP  Scan         Water-Total    |
     |                            Result   Units  j
     +	+
     Cadmium   Cd-Total  '            5U   ug/1
     Chromium  Cr-Total             10U   ug/1
     Copper    Cu-Total              8  *  ug/1
     Lead      Pb-Total             SOU   ug/1
     Nickel    Ni-Total             22  *  ug/1
     Zinc      Zn-Total              9  *  ug/1
Officer: DGB
                      Account:  AFEB3A
 Source:  Industrial Effluent
   Comp :
                          F req :
                                                              (Sample Complete)

-------
13-JAN-8 9
09:41:50                                  Sample/Project Analysis Results

   Project:  WTR-081A  AK.PULP  CORP./ KETCHIKAN  PULP CO.

Laboratory:  EPA,  Manchester

 Sample No:  88  350004            Description: MAIN  OUTFALL (001)

                                   Begin Date: 88/08/22  07:32
                                                                Officer -.  DGB
                                                                                     Account:  AFEB3A
|  Organics —  General
 OiltGrea  Tot-GrFr
                                                                 Source:  Industrial  Effluent
----------------- H
 Water-Total     |
 Result  Units   j
                               5.1  *  mg/1
                                                         (Sample Complete)

-------
        Project:  WTR-081A  AK.PULP  CORP./ KETCHIKAN  PULP CO.


    Laboratory:  EPA, Manchester


     Sample  No:  88  350013             Description:  MAIN OUTFALL 001


                                           Begin Date:  88/08/^25  07:45
                                                                                                          Officer:  DGB
                                                                                                                                   Account: AFEB3A
                                                                       Source:  Industrial  Effluent
      Organics  — General
     Oil&Grea   Tot-GrFr
Water-Total
Result  Un its
                                     16.8  * mg/1
(U
 I
tn
                                                                    (Sample  Complete)

-------
09:41:50                                  	




   Project: WTR-081A  AK.PULP  CORP./ KETCHIKAN  PULP CO.




Laboratory: EPA, Manchester




 Sample  No: 88 350001            Description: PRIMARY TREAT. EFF.  (002)





                                   Begin Date: 88/08^21 07:00
Officer:  DGB
                      Account: AFEB3A
 Source:  Industrial  Effluent
| Gen Ino
1

Sulf ids
| Solids
1
Solids
| Demand
i
BOD
COD
T-Org-C
tfl H 	 	 -
1 | Metals
<* 1
Arsenic
S i 1 ve r
Me rcury
| Metals
1
Cadmium
Chromium
Coppe r
Lead
Nickel
Zinc
| Metals
| Matrix
Cadmium
Ch romium
Coppe r
Lead
Nickel
rg/Phys-Speci

Total
- Spec i f i ed
T-Suspen
- Specified
5 Day
Hi Level
Total
— Speci f ied
As-Total
Ag-Total
Hg-Total
- ICP Scan
Cd-Total
Cr-Total
Cu-Total
Pb-Total
Ni-Total
Zn-Total
- ICP Scan
Spike ttl
Cd-Tot a 1
Cr-Total
Cu-Total
Pb-Total
Ni-Total
	 •(• + 	
Water-Total | | Metals - ICP Scan
Result Units | | *** Continued

3.4 * mg/1 Zinc Zn-Total
Water-Total | | Metals - ICP Scan
Result Units | | Matrix Spike #2
85. * mg/1 Cadmium Cd-Total
Chromium Cr-Total
Water-Total | Lead Pb-Total
Result Units | Nickel Ni-Total
186. * mg/1
1012. * mg/1
314. * mg/1
Water-Total |
Result Units |
1U ug/1
0.2U ug/1
< 0 . 08U ug/1
Water-Total |
Result Units |
5U ug/1
10U ug/1
11 * ug/1
SOU ug/1
15 * ug/1
17 * ug/1
Water-Total |
Result Units |
70 % Recov
93 % Recov
90 % Recov
96 % Recov
92 % Recov
Wate r-To t al |
|

106 % Recov
_1_
Water-Total |
Result Units \
64 % Recov
95 % Recov
97 % Recov
96 % Recov







                                                          (Sample Complete)

-------
 03:41:50                                    Sample/Project  Anaxybxa  f^<3*>**j.~




    Project:  WTR-081A  AK.PULP  CORP./  KETCHIKAN  PULP CO.




Laboratory:  EPA, Manchester




 Sample  No:  88  350010             Description:  PRIMARY TREATMENT EFF  002




                                     Begin  Date:  88/08./24 07:00




                                       End  Date:  88/08/25 07:00
Officer:  DGB
                       Account:  AFEB3A
 Source:  Industrial  Effluent
| Gen Ino rg/Phy s-Spec i
1
pH LAB
Sulf ide
] Solids
1
Solids
| Demand
1
BOD
COD
T-Org-C
| Metals
1
Arsenic
Silver
Me r cu ry
| Metals
1
C a dm i u m
Ch romium
Coppe r
Lead
Nickel
Z inc
| Metals
| Matrix
Cadmium
Chromium
Coppe r
Lead
Nickel
Meter
Total
- Specified
T-Suspen
- Speci f i ed
5 Day
Hi Level
Total
- Specified
As-Total
Ag-Total
Hg-Tota 1
- ICP Scan
Cd-Total
Cr-Total
Cu-Total
Pb-Total
Ni-Total
Zn — To t a 1
- ICP Scan
Spike ftl
Cd-Total
Cr-Total
Cu— Tot al
Pb-Total
Ni-Total
	 1- ^ 	
Water-Total | | Metals - ICP Scan
Result Units j | »** Continu

2 . 6 * rag/1 Zinc Zn-Total
Water -Total | | Metals - ICP Scan
Result Units | | Matrix Spike ft 2
85 * mg/1 Cadmium Cd-Total
Chromium Cr-Total
Water-Total | Lead Pb-Total
Result Units | Nickel Ni-Total
205. * mg/1
928. * mg/1
301. * mg/1
Water-Total |
Result Un.it s j
1U ug/1
0 . 2U ug/1
0.25 * ug/1
Water-Total |
Result Units |
5U ug/1
10U ug/1
10 * ug/1
SOU ug/1
18 * ug/1
34 * ug/1
Water-Total |
Result Units |
66 % Recov
96 % Recov
95 * Recov
98 % Recov
104 % Recov
Water-Total |
ed *** I
Result Units |
105 % Recov
Water-Total |
Result Units |
61 % Recov
97 % Recov
94 % Recov
96 % Recov
97 % Recov
105 % Recov
    Comp :
                           Freq :
                                                             (Sample Complete)

-------
      09:41:50                                   a a my i »,»....,	

         Project:  WTR-081A  AK.PULP CORP./ KETCHIKAN PULP CO.


      Laboratory:  EPA, Manchester


       Sample No:  88  350005            Description:  PRIMARY TREAT. EFF.  (002)


                                         Bagin Data:  88/08/22 07:59
                                                                                           Officer:  DGB
                                                                                                                  Account: Arc.oj.rv
                                                                                             Source: Industrial  Effluent
I  organics -  General

I

 Oil&Grea  Tot-GrFr
                                   Water-Total     |
                                   Result  Units   |
                                     9.4 * mg/1
CO
 I
00
                                                                (Sample Complete)

-------
09:41:50                                  Sample/Project  Analysis  Ke

   Project:  WTR-081A  AK.PULP  CORP./ KETCHIKAN PULP CO.

Laboratory:  EPA,  Manchester

 Sample No:  88  350014            Description:  PRIMARY TREAT  EFF  002

                                   Begin  Date:  88/08/25 08:05
                                                               Officer :  DGB
                                                                                    Account:  AFEB3A
                                                                Source:  Industrial  Effluent
  Organics - General
 OiliGrea  Tot-GrFr
Water-Total     |
Result  Units   j

  8.4 * mg/1
                                                         (Sample Complete)

-------
 09:41:50



   Project: WTR-031A   AK.PULP  CORP./ KETCHIKAN PULP CO.



Laboratory: EPA, Manchester



 Sample No: 88 350002            Description:  SEC.  TREAT.  EFF.  (002)



                                  Begin  Date:  88/08/21  07:00
                                                   •
                                                                                      Officer: DGB
                                                                                                           Account:  AFEB3A
                                                                                       Source: Industrial  Effluent
Gen Inorg/Phys-Speci
                           Water-Total     |

                           Result  Units   |
pH LAB
Sulf ide
| Solids -
1
Solids
| Demand -
1
BOD
COD
T-Org-C
| Metals -
1
Arsenic
Silver
Me rcury
| Metals -
1
Cadmium
Ch r omium
Coppe r
Lead
Nickel
Zinc
Meter
Total
Specified
T— Suspen
Speci f ied
5 Day
Hi Level
Total
Spec i f ied
As-Total
Ag-Total
Hg-Total
ICP Scan
Cd-Total
Cr-Total
Cu-Total1
Pb-Total
Ni-Total
Zn-Total
7.23 * Std Unts
4.0 * mg/1
Water-Total
Result Units
460. * mg/1
Water-Total
Result Units
143. * rog/1
3095. * mg/1
1003. * rag/1
Wate r-Total
Re suit Unit s
1U ug/1
0.2U ug/1
<0 . 08U ug/1
Wate r-Total
Re suit Uni t s
5U ug/1
33 * ug/1
3 * ug/1
SOU ug/1
13 * ug/1
68 * ug/1
1
1

1
1

1
1

1
1

                                                       (Sample  Complete)

-------
 I
I—'
0 9 : 4 1 ; 5 0
Project
Laboratory
Sample No



: WTR-081A AK .
: EPA, Manchest
: 88 350011


| Gen Inorg/Phys-Speci
1
pH LAB
Sulf ide
| Solids -
1
Solids
| Demand -
1
BOD
COD
T-Org-C
| Metals -
1
Ar s enic
Sil ve r
Me r cury
| Metals -
1
Cadmium
Ch r omi urn
Coppe r
Lead
Nickel
Zinc

Meter
Total
Specified

T— Suspen
Speci f i ed

5 Day
Hi Level
Total
Spec i f ied

As-Total
Ag-Total
Hg-Total
ICP Scan

Cd-Total
Cr-Total
Cu— Total
Pb-Total
Ni-Total
Zn-To t a 1
Sam
PULP CORP./ KETCHI
e r
Des cription
Begin Date
End Date
Water-Total |
Result Units |
7.46 * Std Unts
5.0 * mg/1
Water-Total |
Result Units |
440 * mg/1
Water-Total |
Result Units |
265. * mg/1
3666 . * mg/1
1274 . * mg/1
Water-Total |
Result Uni ts |
1U ug/1
0 . 2U ug/1
< 0 . 08U ug/1
Water-Total |
Result Units |
5U ug/1
35 * ug/1
4 * ug/1
SOU ug/1
19 * ug/1
58 * ug/1
                                                       Sample/project. *\i.
                                                             SEC.  TREAT.EFF 002


                                                             88/08/24  07:00


                                                             88/08/25  07:00
                                                                                                                Officer:  DOB
                                                                                                                                         Account: AFEB3A
                                                                                                                 Source:  Industrial Effluent
Comp:
                          Freq :
                                                                        (Sample  Complete)

-------
       Project:  WTR-081A  AK.PULP  CORP./ KETCHIKAN PULP CO.

   Laboratory:  EPA,  Manchester

    Sample  No:  88  350006            Description:  SEC.  TREAT.  EFF (002;

                                     Begin  Date:  88/08/22 07:42
                                                                                             Officer:  DOB
                                                                                                                  Account:  AFEB3A
                                                               Source:  Industrial Effluent
   |  Organics  -  General
    OiliGrea   Tot-GrFr
Wate r-Total
Result  Units
                                 9.8  * mg/1
I
h-•
                                                           (Sample Complete)

-------
   09:41:50                                  Sample/Project  Anao.ysit


      Project:  WTR-081A  AK.PULP  CORP./ KETCHIKAN PULP  CO.


   Laboratory:  EPA,  Manchester



    Sample No:  88  350015            Description: SEC TREAT  EFF  002



                                      Begin Date: 88/08/-25 07:50
                                                               Officer: DGB
                                                                                     Account:  AFEB3A
                                                                Source: Industrial Effluent
   |  Organics - General

   I
   -I	
Water-Total     |

Result   Units   j
    OiltGrea  Tot-GrFr
                                14.1  *  rag/1
to
 i
i—
U)
                                                            (Sample Complete)

-------
bd
i
     09:41:50                                   s a mp 4. e/ r r o 3 e c L. «naJ.i, = J.J

        Project: WTR-081A  AK.PULP  CORP./ KETCHIKAN PULP CO.

    Laboratory: EPA,  Manchester

     Sample  No: 88 350003             Description:  FILTER PLANT  (003)

                                        Begin Date:  88/0 V 21 07:00

    +	+
    |  Gen  Inorg/Phys-Speci     Water-Total     |
    I                             Result   Units   |

     pH LAB     Meter             4.47  *  Std Unts

    +	+
    |  Solids  - Specified       Water-Total     |
    |                             Result   Units   j
    +	1-
     Solids     T—Suspen           4.5  *  mg/1

    +	+
    |  Demand  — Specified       Water-Total     |
    |                             Result   Units   |
    +	+
     BOD        5 Day              3.2  *  mg/1
Officer:  DGB
                       Account: AFEB3A
 Source:  Industrial  Effluent
                                                              (Sample  Complete)

-------
    1 J — -J AW — o y
    09:41:50                                   Sample/Project Ana±ysj

       Project:  WTR-081A   AK.PULP CORP./ KETCHIKAN  PULP CO.


   Laboratory:  EPA,  Manchester


     Sample  No:  88  350012            Description:  FILTER PLANT  003


                                        Begin Date:  88/08/25 08:20



   |  Gen  Ino rg/Phy s— Spec i      Water-Total    |
   |                              Result   Units  |
                                                                 Office r:  DGB
                                                                                        Account:  AFEB3A
                                                                  Source:  Industrial Effluent
    pH  LAB    Meter
    | Solids - Specified

    I
   H	
    Solids     T—Suspen
    |  Demand — Specified
    I
    I	
    BOD        5  Day
                                  4.28  *  Std Unts
Water-Total     |
Result   Units   |
  3.6  *  mg/1
Water-Total
Result   Units
  1.5  *  mg/1
W
 I
h->
Ul
                                                               (Sample Complete;

-------
 I
h-'
en
     09:41:50                                 sa jnp j. e/ x i u j «, *. <.

        Project: WTR-081A   AK.PULP CORP./ KETCHIKAN PULP  CO.

      Blank  ID: PB100
                                                                                          Officer:  DGB
                                                                                                                Account:  AFEB3A
I  Metals — ICP  Scan
I  Blank ttl
                                Water-Total    |
                                Result   Units  j
     Cadmium
     Chromium
     Copper
     Lead
     Nickel
     Zinc
Cd-Total
Cr-Total
Cu-Tota1
Pb-Total
Ni-Total
Zn-Total
                                5U  ug/1
                               10U  ug/1
                                2U  ug/1
                               SOU  ug/1
                               10U  ug/1
                                4U  ug/1
                                                             (Sample Complete)

-------
     09:41:50                                  Sample/Project;

        Project: WTR-081A  AK.PULP CORP./  KETCHIKAN PULP CO.

       Blank ID: PB101
                                                               Officer: DOB
                                                                                     Account:  AFEB3A
     |  Metals - ICP Scan
     I  Blank *2
Water-Total
Result   Units
Cadmium
Ch romium
Coppe r
Lead
Nickel
Zinc
Cd-Total
Cr-Total
Cu-To t a 1
Pb-Total
Ni-Total
Zn-Total
5U
10U
2U
SOU
10U
7 *
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
to
I
                                                              (Sample Complete)

-------
      09:41:50                                     s amp a. e/ r i ~ j = - _



         Project:  WTR-081A   AK.PULP  CORP./  KETCHIKAN PULP  CO.



       Blank ID:  PB102
                                                                    Officer: DGB
                                                                                            Account: AFEB3A
       Metals -  ICP Scan

       Blank #1
Water-Total

Result  Units
Cadmium
Chromium
Coppe r
Lead
Nickel
Zinc
Cd-Total
Cr-Total
Cu-Total
Pb-Total
Ni-Total
Zn-Total
5U
10U
2U
SOU
10U
4U
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
w
 I
f—•
oo
                                                                   (Sample  Complete;

-------
   Project: WTR-081A  AK.PULP CORP./ KETCHIKAN PULP CO.

  Blank ID: PB103
                                                                                       Officer: DGB
                                                                                                            Account: AFEB3A
I  Metals  - ICP Scan
I  Blank  #2
Water-Total    |
Result  Units  j

    5U  ug/1
   10U  ug/1
    2U  ug/1
   SOU  ug/1
   10U  ug/1
    4U  ug/1
 Cadmium
 Chromium
 Coppe r
 Lead
 Nickel
 Zinc
Cd-Total
Cr-Total
Cu-Total
Pb-Total
Ni-Total
Zn-Total
                                                       (Sample Complete!

-------
tt
 i
    09:41:50

       Project: WTR-081B   KETCHIKAN  PULP  CO./ KETCHIKAN,  AK.                                Officer: DWK

    Laboratory: EPA, Manchester

     Sample No: 88 350314            Description:  WARDCOVESTA1-1,MINRANGER3-1444,4-504       Source:

                                      Begin  Date:  88/08/22 18:05

                                        Comment:  1-1/2  GAL CTR RECVD BRKN,3-8OZ.RECVD UNBROKEN
                                                                                  Account:  AFEB3A
                                                                      Bottom Sediment  or  Deposit
    |  Gen  Inorg/Phys-Speci
     Cadmium   Cd-Sedmt
     Chromium  Cr-Sedmt
     Copper    Cu-Sedmt
     Lead      Pb-Sedmt
     Nickel    Ni-Sedmt
     Zinc      Zn-Sedmt
    |  Organics — General,
    I

     OiliGrea  Sed-GrFr
Sediment
Result  Units
Sulf ide
| Demand
1
BOD-5
| Metals
1
Arsenic
S i 1 ve r
Me rcury
| Metals
1
Sedmt
- Specified
Sedmt
- Specified
As-Sedmt
Ag— Sedmt
Hg-Sedmt
- ICP Scan
10300 . * mg/kg-wt
Sediment |
Result Units |
14500. * mg/kg-dr
Sediment |
Result Units |
7.6 * mg/kg-dr
0.05 * mg/kg-dr
0.02 * mg/kg-wt
Sediment |
Result Units |
   .5U  mg/kg-dr
 70.3 *  mg/kg-dr
 39.4 *  mg/kg-dr
 13.4 *  mg/kg-dr
 39.1 *  mg/kg-dr
  206 *  mg/kg-dr
Sediment
Result  Units
8520. * mg/kg-dr
                                                           (Sample Complete)

-------
 1 J —JAW — o y
 09:41:50                                  Sample/Project Analysis  Kesuj-ts

   Project:  WTR-081B  KETCHIKAN  PULP  CO./ KETCHIKAN, AK .

Laboratory:  EPA,  Manchester
                                                              Officer:  DWK
                                                                                    Account: AFEB3A
 Sample No:  88  350313
 Cadmium   Cd-Sedmt
 Chromium  Cr-Sedmt
 Copper    Cu-Sedmt
'Lead      Pb-Sedmt
 Nickel    Ni-Sedmt
 Z inc      Zn-Sedmt
  Organics -  General
                                 Description:  WARDCOVESTA1 - 2 , MI NIRANGER 3 -1 4 0 6 , 4 - 3 9 5

                                  Begin  Date:  88/OV22 17:40

                                      Comment:  1-80Z RCVD BRKN  1 - 8O ZUBN , 1 - 1/2 UNUSABLE
                                                                                            Source:  Bottom Sediment  or  Deposit
| Gen Inorg/Phys— Speci
i
Sulf ide
| Demand
1
BOD-5
I Metals
1
Arsenic
S i 1 ve r
Me rcury
| Metals
1
Sedmt
- Specified
Sedmt
- Specified
As-Sedmt
Ag— Sedmt
Hg-Sedmt
- ICP Scan
Sediment |
Result Units |
2240. * mg/kg-wt
Sediment |
Result Units j
3260. * mg/kg-dr
Sediment |
Result Units j
3.3 * mg/kg-dr
0 . 02U mg/kg-dr
0.01 * mg/kg-wt
Sediment |
Result Units |
	 	 i.
   .5U  mg/kg-dr
  106 * mg/kg-dr
 12.0 * mg/kg-dr
  5.OU  mg/kg-dr
 53.6 * mg/kg-dr
 86.1 * mg/kg-dr
Sediment
Result  Units
 Oil&Grea   Sed-GrFr
 500 .  * mg/kg-dr
                                                        ( Sajnpl e  Complete )

-------
w
 I
M
NJ
      09:41:50                                     Sample/Project An a j. y s i a ci.vs> <**.,.=


          Project:  WTR-081B  KETCHIKAN PULP  CO./ KETCHIKAN,  AK.


      Laboratory:  EPA, Manchester


                                           Description: WARDCOVE  STA.2-1,MINRANGER3-1348,4-543


                                            Begin  Date: 88/0 8y 22  18:40


                                               Comment: 1-1/2GAL  RECVD  BRKN,3-8OZ.RCVD  UNBROKEN
                                                                                                  Officer: DWK
                                                                                                                          Account: AFEB3A
Sample No:  88 350315
                                                                                                    Source:  Bottom  Sediment or  Deposit
      |  Gen  Inorg/Phys-Speci

      I
      H	

       Sulfide    Sedmt
        Demand  — Specified
                              Sediment
                              Res ult   Uni ts
                                    17200.  *  mg/kg-wt
                              Sediment

                              Result   Units
BOD-5
| Metal s -
1
Arsenic
Silver
Me rcu ry
| Metals -
1
Cadmium
Ch r omium
Coppe r
Lead
Nickel
Z inc
| Organics
1
Sedmt
Spec i f i ed

As— Sedmt
Ag— Sedmt
Hg-Sedmt
ICP Scan

Cd-Sedmt
Cr-Sedrat
Cu— Sedmt
Pb-Sedmt
Ni-Sedmt
Zn— Sedmt
— G eTi a r 3 1

17300. * mg/kg-dr
Sediment |
Result Units |
5.7 * mg/kg-dr
0.02 * mg/kg-dr
0.02 * mg/kg-wt
Sediment |
Result Units |
. 5U mg/kg-dr
42.9 * mg/kg-dr
47.1 * mg/kg-dr
18 7 * mg/kg-dr
45.1 * mg/kg-dr
139 * mg/kg-dr
Sediment |
Result Units j
	 	 \-
       OiltGrea  Sed-GrFr
                             14990.  * mg/kg-dr
                                                                    ( Sample  Complete)

-------
       Project: WTR-081B  KETCHIKAN PULP CO./  KETCHIKAN,  AK.


    Laboratory: EPA,  Manchester


    Sample  No:  88  350312           Description: WARDCOVESTA2-3,MINIRANGER3-1052,4-303


                                     Bagin Date: 88/08/22  17:38
                                                        -»

                                        Comment: 1-8OZ. CTR RECV'D  UNBROKEN
                                                                                            Officer: DWK
                                                                                                                 Account: AFEB3A
                                                              Source: Bottom Sediment  or  Deposit
   I  Gen Inorg/Phys-Speci      Sediment        |
   I                            Result  Units   |
    Sulfide   Sedmt
   |  Demand - Specified
   I
    BOD-5     Sedmt
   |  Organics -  General
   I
   H	
    Oil&Grea  Sed-GrFr
                              14800 .  * mg/kg-wt
Sediment        |
Result  Units   |
                              19600 .  * mg/kg-dr

                             	+
Sediment
Result  Units
                              16390. * mg/kg-dr
 I
NJ
U)
                                                           (Sample  Complete)

-------
      13-JAN-8 9
      09:41:50
 I
NJ
EPA  Region A  i^au  .-i=i*«^«	
  Sample/Project  Analysis  Results
          Project:  WTR-081B  KETCHIKAN  PULP  CO./ KETCHIKAN,  AK.

      Laboratory:  EPA,  Manchester
                                                            Officer:  DWK
                                                                                      Account:  AFEB3A
S a mp 1 e No


: 88 350309


| Gen Ino rg/Phy s-Spec i
1
Sulf ide
| Demand —
1
BOD-5
| Metals -
1
Arsenic
Silver
Me rcu ry
| Metals -
1
Cadmium
Chromium
Copper
Lead
Nickel
Zinc
| Organics
i
Oil tG r ea

Sedmt
Speci f ied

Sedmt
Specified

As-Sedmt
Ag-Sedmt
Hg-Sedmt
ICP Scan
Cd-Sedmt
Cr-Sedmt
Cu-Sedmt
Pb-Sedmt
Ni-Sedmt
Zn-Sedmt
_ 	 ( — _
- General

Sed-GrFr
Des c rip t ion
Begin Date
Comment
Sediment |
Result Units |
7370 * mg/kg-wt
Sediment |
Result Uni ts |
9600 . * mg/kg-dr
Sediment |
Result Units |
18.5 » rog/kg-dr
0.08 * mg/kg-dr
0.022 * mg/kg-wt
Sediment |
Result Units |
. 5U ng/kg-dr
40.9 * mg/kg-dr
70.6 * mg/kg-dr
49.6 * mg/kg-dr
28.2 * mg/kg-dr
160 * mg/kg-dr
Sediment |
Result Units |
18000. * mg/kg-dr
                                                              WARDCOVE  STA. 3-1 ,MINIRANGER3 -1113 ,4-628

                                                              88/08/22  16:45

                                                              1-8OZ.RCVD BRKN  2-80Z.UNBRKN 1-1/2GAL  UNUSABLE
                                                                                                                   Source:  Bottom Sediment  or Deposit
                                                                         (Sample Complete;

-------
td
 I
K)
Ul
      09:41:50                                  Sample/Project An a j. y =


        Project: WTR-081B   KETCHIKAN  PULP CO./ KETCHIKAN,  AK.


     Laboratory: EPA, Manchester
                                                                Officer: DWK
                                                                                      Account:  AFEB3A
      Sample  No:  88 350310
                                       Des cripti on:


                                        Begin  Date:


                                            Comment:
     |  Gen Inorg/Phys-Speci

     I
     H	
      Sulfide
                 Sedmt
     |  Demand -  Specified

     I
Sediment
Result  Units
                |
                                 13100. *
                                          mg/kg-wt

                                          	+
Sediment
Result  Uni t s
BOD-5
| Metals -
1
Arsenic
Silver
Me rcu ry
| Metals -
1
Cadmium
Chromium
Coppe r
Lead
Nickel
Zinc
| Organics
1
Sedrot
Specified
As— Sedmt
Ag-Sedmt
Hg-Sedmt
ICP Scan
Cd-Sedmt
Cr-Sedmt
Cu-Sedmt
Pb-Sedmt
Ni-Sedmt
Zn-Sedmt
- GenerajL

17300. * mg/kg-dr
S ediment |
Result Units j
18.6 * mg/kg-dr
0.20 * mg/kg-dr
0.032 * mg/kg-wt
Sediment |
Result Units j
5.7 * mg/kg-dr
42.7 * mg/kg-dr
66.7 * mg/kg-dr
34.1 * mg/kg-dr
34.9 * mg/kg-dr
209 * mg/kg-dr
Sediment |
Result Units |
                   WARDCOVE  STA3-2,MINIRANGER3 -1008 ,4-502


                   88/08X22  16:55


                   1-802  CNTR RECV'D BKN
                                                                                                   Source: Bottom Sediment  or Deposit
      OiliGrea   Sed-GrFr
                                 20650 .  *  mg/kg-dr
                                                               [Sample Complete I

-------
Cd
 I
NJ
CTi
      09:41:50                                 	


        Project:  WTR-081B  KETCHIKAN PULP CO./ KETCHIKAN, AK.


     Laboratory:  EPA,  Manchester


      Sample No:  88 350311            Description: WARDCOVE STA. 3 - 3 ,MINRANGER3-883 ,4 - 383


                                       Begin Date: 88/08/.22 17:05


                                          Comment: 1-8OZ. CTR RECV'D  UNBROKEN
                                                             officer:  DWK
                                                                                   Account: AFEB3A
                                                               Source:  Bottom Sediment or Deposit
       Gen  Inorg/Phys—Speci
      Sulfide    Sedmt
       Demand - Specified
      BOD-5      Sedmt
     |  Organics - General

     I
      OilsGrea  Sed— GrFr
Sediment        |
Result  Units   |
                                10200.  *  mg/kg-wt

                               	».
Sediment
Result  Units
                                11800.  *  mg/kg-dr
Sediment        |
Result  Units   |
                                11000.  * mg/kg-dr
                                                             (Sample  Coroplete)

-------
w
 I
      09:41:50                                       _, =



          Project: WTR-OS1B   KETCHIKAN PULP CO./ KETCHIKAN, AK.



      Laboratory: EPA, Manchester



      Sample No: 88  350305             Description:  WARDCOVE STA4- 2,MINIRANGER3-433, 4 - 748



                                             Begin Date:  88/08/_22 15:55



                                                 Comment:  2-80Z.  CONTAINERS  RECV'D
                                                                         Officer:  DWK
                                                                                                  Account:  AFEB3A
                                                                          Source:  Bottom Sediment or  Deposit
| Gen Ino rg/Phy s-Speci
i
Sulf ide
| Demand —
i
BOD-5
| Metals -
1
Ar s enic
Silver
Me r cury
| Metals -
1
Cadmium
Ch r omi urn
Coppe r
Lead
Nickel
Zinc
| Organics
1

Sedmt
Speci tied

Sedmt
Specified

As-sedmt
Ag-Sedmt
Hg-Sedmt
ICP Scan

Cd-Sedmt
Cr-Sedmt
Cu-Sedmt
Pb-Sedmt
Ni-Sedmt
Zn-Sedmt
— Gene ra 1

Sediment |
Result Units |
14900. * mg/kg-wt
Sediment |
Result Units |
21100. * mg/kg-dr
Sediment |
Result Units |
9.9 * mg/kg-dr
0.18 * mg/kg-dr
0.088 * mg/kg-wt
Sediment |
Result Units |
2.5 * mg/kg-dr
30.1 * mg/kg-dr
39.0 * mg/kg-dr
15.2 * mg/kg-dr
29.1 * rag/kg-dr
170 * mg/kg-dr
Sediment |
Result Units |
      Oil&Grea   Sed—GrFr
30120.  *  mg/kg-dr
                                                                      (Sample  Complete)

-------
                                                                                              Officer:  DWK
                                                                                                                    Account:  AFEB3A
 09:41:50                                 Sample/Project  Anaj.,,,.*,  .	

    Project: WTR-081B   KETCHIKAN PULP CO./ KETCHIKAN, AK.

Laboratory: EPA, Manchester

 Sample  No: 88 350301            Description: WARDCOVE STA.5-1,MINIRANGER 3-676,4-1476   Source:  Bottom Sediment  or  Deposit

                                   Begin  Date: 88/08/22 15:12

                                      Comment: 1-8OZ. CONTAINER  RECV'D UNBROKEN

+	+
|  Gen Inorg/Phys—Speci     Sediment        |
I                            Result   Units   |
+	+
 Sulfide    Sedmt           6010.  *  rag/kg-wt
    |  Demand - Specified
    I

     BOD-5      Sedmt
      Organics - General
     OiliGrea  Sed—GrFr
133
 I
ISJ
00
                            	+
                            Sediment        |
                            Result   Units   j
                              13,600. * mg/kg-dr
                            S edi men t        |
                            Result   Units   |
                               15900 .  * mg/kg-dr
                                                            ; Sample Complete i

-------
dd
 i
to
     09:41:SO
                                              samp i
                                                                                             Officer: DWK
                                                                                                                   Account: AFEB3A
        Project:  WTR-081B  KETCHIKAN PULP  CO./  KETCHIKAN,  AK .

    Laboratory:  EPA,  Manchester

     Sample No:  88  350302           Description: WARDCOVE  STA . 5- 3 , MINIRANGER3 - 5 0 1 , 4 - 1 4 5 8    Source:  Bottom  Sediment or Deposit

                                      Begin Date: 88/08/22  15:25

                                         Comment: 1-8OZ. CONTAINER  RECV'D UNBROKEN
|  Gen Ino rg/Phy s-Speci
j
     Sulfide   Sedmt
      Demand - Specified
     BOD-5
               Sedmt
    |  Organics -  General
     Oil&Grea  Sed-GrFr
                                Sediment
                                Result  Units
                                5260.  * mg/kg-wt
                            Sediment       |
                            Result  Units  |
                              10,400.  * mg/kg-dr

                             	+
                            S ediment
                            Result  Un its
                            5620.  * mg/kg-dr
                                                            (Sample  Complete)

-------
6d
 I
UJ
o
     13-JAN-89                              	

     09:41:50                                  Sample/Project Analysis  Hesuits


       Project:  WTR-081B  KETCHIKAN  PULP CO./ KETCHIKAN, AK.


    Laboratory:  EPA,  Manchester


     Sample No:  88  350303            Description:  WARDCOVE STA.5-5,MINIRANGER3-415,4-1489


                                       Begin  Date:  88/08/-E 2   :


                                          Comment:  1-80Z.  CONTAINER RECV'D  UNBROKEN
                                                              Officer:  DWK
                                                                                    Account:  AFEB3A
                                                               Source: Bottom  Sediment or Deposit
    I  Gen Inorg/Phys-Speci     Sediment        I
    |                            Result  Units   |
     Sulfide   Sedmt
    |  Demand - Specified

    I
     BOD-5     Sedmt
    |  Organics -  General
     OiliGrea   Sed-GrFr
                                4790.  * mg/kg-wt


                                	+
Sediment        I
Result  Units   j
                                7840 .  *  mg/kg-dr
Sediment        |
Result  Units   |
4080 .  * mg/kg-dr
                                                             (Sample  Complete)

-------
td
I
oo
      13-JAN-8 9

      09:41:50                                 Sample/Project  Analysis


        Project: WTR-081B   KETCHIKAN PULP CO./ KETCHIKAN, AK .


     Laboratory: EPA, Manchester
                                                              Officer:  DWK
                                                                                    Account:  AFEB3A
      Sample No: 88 350307
      Description: WARDCOVE  STA.6-1,MI MI RANGER3-649 ,4 - 775


       Begin Date: 88/08y22  16:15


          Comment: 1-1/2GAL.  CONTAINER  RECV'D BROKEN
                                                                                               Source: Bottom  Sediment  or  Deposit
     |  Gen  Inorg/Phys-Speci

     I
      Sulfide
                Sedmt
     |  Demand - Specified

     I
      OilSGrea  Sed-GrFr
Sediment

Result  Units
                 |
                                16400.  *  mg/kg-wt
 Sediment       |
 Result  Units
BOD-5
| Metals -
1
Arsenic
Silver
Me rcury
| Metals -
1
Cadmium
Ch r omium
.Coppe r
Lead
Nickel
Zinc
| Organics
1
Sedmt
Specified

As-Sedmt
Ag-Sedmt
Hg-Sedmt
ICP Scan

Cd-Sedmt
Cr-Sedmt
Cu— Sedmt
Pb-Sedmt
Ni-Sedmt
Zn— Sedmt
- General

21800. * mg/kg-dr
Sediment j
Result Units |
10.2 * mg/kg-dr
0.17 * mg/kg-dr
0.039 * mg/kg-wt
Sediment |
Result Units |
2.6 * mg/kg-dr
37.7 * mg/kg-dr
54.7 * mg/kg-dr
28.1 * mg/kg-dr
35.8 * mg/kg-dr
132 * mg/kg-dr
Sediment \
Result Units [
	 	 — 0.
20890. * mg/kg-dr
                                                             (Sample  Complete

-------
 09:41:50                       r          saLmp±B/riOJ~i.<. „„.«.,„._ 	

    Project: WTR-081B   KETCHIKAN  PULP  CO./ KETCHIKAN,  AK.

Laboratory: EPA, Manchester

 Sample  No: 88 350308             Description: WARDCOVE  STA.6-2,MINRANGER3-907,4-688

                                   Begin  Date: 88/08/22  16:28

                                      Comment: 1-8OZ. CONTAINER RECV'D  UNBROKEN


|  Gen Inorg/Phys-Speci      Sediment        |
                             Result  Units
                                                                                                 Officer: DWK
                                                                                                                       Account:  AFEB3A
                                                                                                  Source: Bottom  Sediment or  Deposit
     Sulfide   Sadmt
    |  Demand - Specified
    I
     BOD-5
               Sedmt
    |  Organics -  General
    I
    -I	
     OiliGrea  Sed-GrFr
                                13000. * mg/kg-wt
                             Sediment
                             Re suit  Unit s
                                50400. * mg/kg-dr
                             S edimen t        |
                             Result  Units   |
                                18010 .  * mg/kg-dr
00
 I
OJ
                                                              [Sample Complete]

-------
w
 I
u>
13-jAN-aa
09:41:50
Project: WTR-081B

Sample/Project Analysis noa^-t^..
KETCHIKAN PULP CO./ KETCHIKAN, AK .



Laboratory: EPA, Manchester
Sample No: 88 350316


| Gen Ino r g/Phy s-Spec i
1

Ct
-------
     09:41:50                                  	

       Project:  WTR-081B   KETCHIKAN PULP  CO./  KETCHIKAN, AK.

      Blank  ID:  PB01.04
                                                                                            Officer: DWK
                                                                                                                  Account:  AFEB3A
I  Metals -  ICP  Scan
I  Blank #1
Cd
 I
U)
                                 Sediment        |
                                 Result  Units   |
Cadmium
Chromium
Coppe r
Lead
Nickel
Zinc
Cd-Sedmt
Cr-Sedmt
Cu-Sedmt
Pb-Sedmt
Ni-Sedmt
Zn-Sedmt
. 5U
1 . OU
. 2U
5 . OU
1.3 *
. 4U
mg/kg-dr
mg/kg-dr
mg/kg-dr
mg/kg-dr
mg/kg-dr
rag/kg-dr
                                                              (Sample Complete;

-------
     13-JAN-89
     09:41:50                                  Sample/Project Analysis Result;

       Project:  WTR-081B  KETCHIKAN PULP  CO./  KETCHIKAN,  AK.


      Blank ID:  PB01.05
                                                                                         Officer:  DWK
                                                                                                               Account: AFEB3A
 I
U)
Ul
I  Metals - ICP Scan
  Blank #2
                                Sediment        |
                                Result  Units   j
Cadmium
Chromium
Coppe r
Lead
Nickel
Zinc
Cd-Sedmt
Cr-Sedmt
Cu— Sedmt
Pb-Sedmt
Ni-Sedmt
Zn-Sedrot
.5U
1 . OU
. 2U
5 . OU
1 . OU
.4U
mg/kg-dr
mg/kg-dr
mg/kg-dr
mg/kg-dr
mg/kg-dr
mg/kg-dr
                                                            (Sample Complete)

-------
 08: 01:44                                    sampu-e/frojecc j\n<±±y^i.a

    Project:  WTR-081C  KETCHIKAN PULP  CO./ KETCHIKAN, AK.

Laboratory:  EPA, Manchester

 Sample No:  88  390101             Description: 001-MAIN COMPOSITE

                                     Begin  Date: 88/09/20 07;30

+	+
|  Gen  Inorg/Phys-Speci      Water-Total     |
|                              Result   Units   |

 pH LAB    Meter             2.79  *  Std  Unts
 Sulfide    Total              1.9  *  mg/1


|  Solids  - Specified        Water-Total     |
j                              Result   Units   |

 Solids    T-Suspen           74.  *  mg/1

^	+
|  Demand  - Specified        Water-Total     |
j                              Result   Units   |

 BOD        5  Day             95.2  *  mg/1
 COD        Hi  Level          440.  *  mg/1
 T-Org-C    Total             117   *  mg/1
Officer:  DWK
                       Account:  AFEB3A
 Source:  Industrial Effluent
  I
 U)
                                                            (Sample  Complete)

-------
   u a : u -L : ^ 4


       Project:  WTR-081C   KETCHIKAN PULP  CO./ KETCHIKAN,  AK.


   Laboratory:  EPA,  Manchester


    Sample  No:  88  390100               Description:  001-MAIN GRAB


                                             Begin  Date:  88/09/20, 07:30
                                                                               Officer:  DWK
                                                                                                          Account: AFEB3A
                                                                                Source:  Industrial  Effluent
  |   Organics -  General
  I


   OiliGrea   Tot-GrFr
	^
 Water-Total      |
 Result   Units    |


    3.0  *  mg/1
W
 I
Co
                                                                        (Sample  Complete)

-------
 08:01:44                                     	f	r

    Project:  WTR-081C   KETCHIKAN PULP  CO./  KETCHIKAN, AK.

Laboratory:  EPA, Manchester

 Sample  No:  88  390104             Description:  002A-PRIMARY COMPOSITE

                                       Begin  Date:  88/09/20 08:15

-I	1-
                                                                                                       Off ice r :  DWK
                                                                                                                               Account :  AFEB3A
                                                                                                        Source: Industrial Effluent
    Gen  Inorg/Phys-Speci
  pH LAB     Metei-
  Sulfide    Total
  |  Solids  - Specified
  I
 +	
   Solids
              T-Suspen
    Demand -  Specified
   BOD
   COD
   T - O c g - C
             5  Day
             Hi  Level
             Total
W
 I
U)
00
                                Water-Total      |
                                Result   Units
                                 6.05  * Std  Unts
                                  7.0  * mg/1
                               	h
                                Water-Total      |
                                Result   Units    |

                                  70 .  *  mg/1
                                Water-Total
                                Result   Units
137.  *  mg/1
747.  *  mg/1
206.  *  mg/1
                                                                 (Sample  Complete)

-------
  08:01:44                                   s amp 1 a/P r o ] e c c  t\n « j. y a x s


     Project: WTR-081C   KETCHIKAN  PULP CO./ KETCHIKAN, AK.


  Laboratory: EPA,  Manchester


   Sample  No: 88  390103             Description: 002A-PRIMARY GRAB


                                      Begin Date: 88/09/20 08:15
                                                                  Officer:  DWK
                                                                                         Account: AFEB3A
                                                                    Source:  Industrial  Effluent
    Organics  - General
----------------- 1.

 Water-Total      |
 Result   Units   |
   OiliGrea   Tot-GrFr
                                 10.4 * rag/1
Cd
I
                                                              (Sample Completel

-------
        Project:    WTR-081C      KETCHIKAN   PULP   CO./   KETCHIKAN,    AK.




Laboratory:    EPA,   Manchester




  Sample    No:    88    390107                            Description:    002B-SECONDARY    COMPOSITE




                                                                                  Begin   Date:    88/09/20    08:00
                                                                                                                                                                                                                       Officer:    DWK
                                                                                                                                                                                                                                                                           Account:    AFEB3A
Source:    Industrial    Effluent
) Gen Inorg/Phys-Speci
i
pH LAB Meter
Sulfide Total
| Solids - Specified
1
Solids T-Suspen
| Demand - Specified
1
BOD 5 Day
COD Hi Level
T-Org-C Total
W
1
Wa te r-
Resul t
7.47
8 . 2
Water-
Result
1100 .
Water-
Result
996 .
5441.
1679 .


Total
Units

1
* Std Unts
* mg/1
Total
Units
* mg/1
Total
Units
* mg/1
* mg/1
* mg/1



1
1

1
1





                                                                                                                                      (Sample   Complete)

-------
     Project:  WTR-081C  KETCHIKAN PULP CO./  KETCHIKAN, AK.

 Laboratory:  EPA, Manchester

  Sample No:  88  390106             Description:  002B-SECONDARY  GRAB


                                        Begin  Date:  88/09/20 08:00
                                                                                                       Officer:  DWK
                                                                                                                               Account:  AFEB3A
   Organics  - General
  Oil&Grea   Tot-GirFr
                                                                       Source:  Industrial  Effluent
Water-Total     |
Result   Units   |

 30.2 *  mg/1
tt)
 I
                                                                (Sample  Complete)

-------
    Project:  WTR-08IC   KETCHIKAN PULP  CO./ KETCHIKAN,  AK.

 Laboratory:  EPA, Manchester

  Sample  No:  88  390122             Description:  STATION  A REPLICATE

                                       Begin  Date:  88/09/20  18:35
                                                                      Source: Bottom  Sediment  or Deposit
|  Gen Inorg/Phys-Speci
I
H	
 Sulfide    Sedmt
|  Demand -  Specified
I
-i	
 BOD-5      Sedmt
Sediment         |
Result  Units   |
                                 8290  *  mg/kg-wt
Sediment         |
Result  Units   |
                                8880.  *  mg/kg-dr
     I
    *>
    NJ
                                                               (Sample  Complete)

-------
 0 8 : 0 1 : 
-------
      -L U — o **i» - w ^
      08:01:44                                                      Sample/i'rojeccrtiiaj.;

           Project:   WTR-081C    KETCHIKAN   PULP  CO./  KETCHIKAN,  AK .

     Laboratory:   EPA,   Manchester

       Sample   No:   88   390114                   Description:   STATION  B

                                                             Begin   Date:   88/09/20   18:15
                                                                                                                                                 Officer:  DWK
                                                                                                                                                                                    Account:  AFEB3A
                                                                                                                                                   Source:  Bottom  Sediment  or  Deposit
|   Gen   Ino r g/Phy s-Spec i
j
       Sulfide     Sedmt
        Demand  -  Specified
 BOD-5
                        Sedmt
                                                   Sediment             |
                                                   Result    Units    j
                                                    9150   *  mg/kg-wt
                                             Sediment             |
                                             Result    Units     |
                                                 11210.   *  mg/kg-dr
dd
 I
>£>.
                                                                                                (Sample  Complete)

-------
    .LU — JALV — a ^
    03:01:44                                    Sample/Project  Analysis


       Project:  WTR-081C  KETCHIKAN PULP CO./  KETCHIKAN,  AK .


   Laboratory:  EPA, Manchester


    Sample  No:  88  390118             Description:  STATION  10-0


                                        Begin  Date:  88/09/21 09:20
                                                                                               Officer:  DWK
                                                                                                                      Account: AFEB3A
                                                                                                Source:  Bottom  Sediment  or Deposit
Gen  Ino rg/Phy s-Speci
    Sulfide   Sedmt
   |  Demand - Specified
    BOD-5
               Sedmt
     Orcranics —  General
    Oil&Grea   S e d - G r F i:
                                 Sediment         |
                                 Result  Units    |
                                 12480 * mg/kg-wt
                            Sedi ment
                            Result  Units
                                15680.  * mg/kg-dr
                                 Sediment         |
                                 Result  Units   |
                                  8510.  * mg/kg-dt
 I
*»
Ln
                                                                (Sample Complete)

-------
      Project:  WTR-081C   KETCHIKAN PULP CO./  KETCHIKAN,  AK .



  Laboratory:  EPA,  Manchester



   Sample  No:  88  390117               Description:  STATION  10-1



                                            Begin  Date:  88/09/21  08:48
                                                                                                               Officer:  DWK
                                                                                                                                          Account:  AFEB3A
                                                                                                               Source:  Bottom  Sediment  or  Deposit
  Gen Inorg/Phys-Speci
                                    Sediment

                                    Result   Units
   Sulfide     Sedmt
                                    14300  * mg/kg-wt



                                                       ^
|  Demand  -  Specified

I
                                    Sediment         |,

                                    Result   Units   |
   BOD-5
                Sedmt
                                   19300.  *  mg/kg-dr
  |  Organic*;— General
                                  Sediment         |

                                  Result   Units   |

                                            ------- +

                                  8930.  *  mg/kg-dr
   Oil&Girea   Sed-GrFi:
to
 i
*>
en
                                                                      (Sample  Complete!

-------
       Project:  WTR-081C   KETCHIKAW  PULP  CO./  KETCHIKAN,  AK.

   Laboratory:  EPA,  Manchester

    Sample  No:  88  390119               Description:  STATION  20-1  REP.

                                              Begin Date:  88/09/21  10:00
                                                                                                                   Officer:  DWK
                                                                                                                                              Account:  AFEB3A
                                                                               Source:  Bottom Sediment  or  Deposit
     Gen  Inorg/Phys-Speci
   Sulfide     Sedmt
   |  Demand  -  Specified
   I
  .j	
    BOD-5       Sedmt
     Oiroanics  - General
                 Sed-Gi'Fv
Sediment          |
Result   Units    j

13600  * mg/kg-wt
Sediment
Result   Units
                                     1"73 20 .   *  mg/kg-di-
                                      Sediment          |
                                      Result   Units    |
                                     1 4 0 4 0    *  mg/kg-dr
 1
*=•
                                                                         (Sample  Complete)

-------
 08:01:44                                     	«.--,	

    Project:  WTR-081C  KETCHIKAN  PULP  CO./ KETCHIKAN,  AK.

Laboratory:  EPA,  Manchester

 Sample  No:  88  390123              Description:  STATION  20-1 REP.

                                       Begin  Date:  88/09/2JL  10:00

H	(.
|  Gen Inorg/Phys-Speci      Sediment         |
j                               Result   Units   j
+	+
 Sulfide    Sedmt             11900  *  mg/kg-wt



|  Demand  -  Specified        Sediment         |
j                               Result   Units   |

 BOD-5      Sedmt            15310.  *  mg/kg-dr



|  Organic?  -General        Sediment         |
j                               Result   Units]

 OiliGrea   Sed-GrFi:        12920.  *  mg/kg-dr
                                                                                                       Officer:  DWK
                                                                                                                               Account:  AFEB3A
                                                                                                        Source: Bottom Sediment  or Deposit
W
 I
*^
OO
                                                                  1 Sample Complete;

-------
    Project:  WTR-081C  KETCHIKAN  PULP CO./ KETCHIKAN,  AK .

 Laboratory:  EPA,  Manchester

  Sample  No:  88  390120              Description: STATION  30-1

                                      Begin Date: 88/09/21  10:45
                                                                                                    Officer: DWK
                                                                                                                            Account! AFEB3A
                                                                                                     Source:  Bottom Sediment or  Deposit
|  Gen  Ino rg/Phy s-Speci
I
 Sulfide    Sedmt
  Demand -  Specified
 BOD-5
             Sedmt
|  Oi'ganics  - General
I
4	
 OiltGL-ea   Sed-GrFr
                               Sediment
                               Result   Units
                               16160 *  mg/kg-wt

                               	+
                               Sediment         |
                               Result   Units    j

                              20910.  * mg/kg-dr
                               Sediment         |
                               Result   Units    |
                              20670 .  *  mg/kg-dr
  W
   I
                                                               (Sample Complete)

-------
   03:01:44                                    	«• - - ,

      Project:  WTR-OS1C  KETCHIKAN  PULP CO./ KETCHIKAN,  AK.

  Laboratory:  EPA,  Manchester

   Sample No:  88 390113             Description:  STATION  40-1

                                       Begin  Date:  88/09/2Q  17:40
                                                                                               Officer:  DWK
                                                                                                                      Account:  AFEB3A
                                                                                                Source:  Bottom Sediment or  Deposit
    Gen  Inorg/Phys-Speci
   Sulfide   Sedrat
Demand  - Specified
   BOD-5
              Sedmt
                            Sediment        |
                            Result  Units   j

                            16250  *  mg/kg-wt
                                 Sedi raent        |
                                 Result  Units   j
                               21080.  * mg/kg-dr
W
 I
                                                               (Sample Complete)

-------
      Project:  WTR-081C  KETCHIKAN PULP CO./  KETCHIKAN,  AK.

   Laboratory:  EPA,  Manchester

    Sample No:  88  390112            Description: STATION  40-3

                                      Begin Date: 88/09/20  17:00
                                                                                              Officer:  DWK
                                                                                                                    Account:  AFEB3A
                                                                                             Source: Bottom  Sediment or Deposit
   |  Gen  Inorg/Phys — Speci
   Sulfide   Sedmt
|  Demand - Specified
 BOD-5
           Sedmt
                             Sediment        |
                             Result   Units   |
                                6370  *  mg/kg-wt
                               Sediment        |
                               Result   Units  |

                               7220.  *  mg/kg-di-
 I
Ul
                                                            (Sample Complete)

-------
      Project:  WTR-081C    KETCHIKAN  PULP  CO./  KETCHIKAN,   AK.


Laboratory:  EPA,   Manchester


 Sample   No:   88  390109                    Description:   STATION   50-2


                                                          Begin  Date:   88/09/20,  15:50
                                                                                                                                                         Officer:   DWK
                                                                                                                                                                                             Account:  AFEB3A
                                                                                                                                                           Source:   Bottom  Sediment   or  Deposit
     Gen  Inorg/Phys-Speci
   S u1f1de      S edmt
  |   Demand  -   Specified

  I
   BOD-5
                     Sedmt
                                               S ediment              |
                                               Result    Units     |


                                                 8020   *  mg/kg-wt
                                               S ediment              |
                                               Result    Units     |


                                               9600 .   *   rog/kg-dr
 I
Ln
                                                                                                (Sample  Complete)

-------
     Project: WTR-081C  KETCHIKAN PULP  CO./  KETCHIKAN, AK.


 Laboratory: EPA,  Manchester


  Sample  No: 88  390110            Description:  STATION 50-4


                                     Begin Date:  88/09/2Q  16:10
                                                                                               Officer:  DWK
                                                                                                                     Account: AFEB3A
                                                                  Source: Bottom Sediment  or Deposit
 I  Gen Inorg/Phys-Speci      Sediment        |
 I                             Result   Units   |

  Sulfide    Sedmt             6650  *  mg/kg-wt
 |  Demand  -  Specified
Sediment         |
Result   Units   |
  BOD-5
             Sedmt
                              7640.  *  mg/kg-dr
W
 I
<_n
U!
                                                            (Sample Complete)

-------
  08:01:44                                    s amp j. e/r i o j = >-^  «.1=J.j

     Project:  WTR-081C  KETCHIKAN  PULP CO./  KETCHIKAN,  AK .

  Laboratory:  EPA, Manchester

   Sample No:  88 390111             Description:  STATION  50-5

                                      Begin Date:  88/09/28 16:35
                                                                  Officer:  DWK
                                                                                         Account:  AFEB3A
                                                                   Source:  Bottom  Sediment or  Deposit
    Gen Inorg/Phys-Speci
  Sulfide   Sedmt
  |  Demand - Specified
  I
 -I	
  BOD-5      Sedmt
 S ediment         |
 Result   Units   j
                                7420  *  mg/kg-wt
 Sediment         |
 Result   Units   |

10000.  *  mg/kg-dr
dd
                                                             (Sample Complete)

-------
     Project:  WTR-081C   KETCHIKAN PULP  CO./  KETCHIKAN,  AK.

 Laboratory:  EPA,  Manchester

  Sample No:  88  390121              Description:  STATION  60-1


                                          Begin  Date:  88/09/21  11:20
                                                                                                              officer:  DWK
                                                                                                                                        Account: AFEB3A
Source:  Bottom  Sediment or  Deposit
1
1

1
1

1
1
Gen Inorg/Phys-Speci
Sulfide Sedmt
Demand - Specified
BOD-5 Sedmt
Organics - General
Sediment |
Result Units |
17150 * mg/kg-wt
Sediment |
Result Units |
18590. * mg/kg-dr
Sedi ment |
Result Units |
 OiltGrea   Sed-GrFr
                                 23110.  * mg/kg-dr
 I
U1
Ul
                                                                     (Sample Complete)

-------
ECOVA LABORATORY






    ANALYSES

-------
                    U.S. ENVIRONMENTAL PROTECTION AGENCY
                                    REGION 10
  S>      *.                        1200 SIXTH AVENUE
          \                   SEATTLE, WASHINGTON 98101         • "  ! ^ f^J j"^ 1 1 tyjf |%
           a                                                  ; •"''— — •'<•— •'-! '-/t±a

                                                             JU   SEP 2 i tow
                                      September 29,  1988
   REPLY TO                                                    • ... Gcet^ i:?.c-;FJi;.:S
    MEMORANDUM
    TO:  Duane Kama, Project Officer
         Ketchikan Pulp Company

   FROM:  Joyce Crosson, Team Le
         Regional Sample Control
                               U
SUBJECT:  Total Organic Carbon results from ECOVA Laboratory
         Attached are the TOC results for samples received  on  August 25,  1988
    at ECOVA Laboratory from the Ketchikan Pulp Company site.   Samples  were
    analyzed by the Solid Waste-846 Manual, method number 9060/Total  Organic
    Carbon.  Analyses were run in triplicate and the average values  of  the
    3 runs are reported.  All samples were analyzed within  the 28 day holding
    time.  I have also attached a copy of method 9060.

         Please contact me if you have any questions regarding the results.
    The second set of samples from the Ketchikan Pulp site  will  be analyzed
    and reported in the same manner-  I can be reached at 2-2111.
                                       B-56

-------
                                METHOD 9060

                           TOTAL ORGANIC CARBON
1.0  SCOPE AND APPLICATION

    1.1  Method 9060  is  used  to  determine "the  concentration  of  organic  carbon
in ground  water,   surface   and   saline   waters,   and  domestic  and  industrial
wastes.  Some restrictions  are noted  in  Sections  2.0  and  3.0.

    1.2  Method 9060  is  most applicable   to  measurement   of  organic  carbon
above  1 mg/L.


2.0  SUMMARY OF METHOD

    2.1  Organic  carbon  is  measured  using  a  carbonaceous  analyzer.  This
instrument  converts the organic  carbon in  a sample to carbon dioxide (C02)  by
either catalytic  combustion or wet chemical  oxidation.  The  C02 formed is then
either measured directly  by an infrared detector or converted to methane (CH4)
and measured  by  a  flame ionization detector.    The  amount  of C02 or CH4 in a
sample is directly proportional  to  the concentration of carbonaceous material
in the sample.

     2.2  Carbonaceous analyzers are capable of  measuring all forms of carbon
in a sample.     However,   because  of  various properties of carbon-containing
compounds in liquid samples,  the  manner  of  preliminary sample treatment as
well as the  instrument  settings  will  determine  which  forms of carbon are
actually measured.  The  forms of  carbon  that  can be measured by Method 9060
are:

      1.  Soluble, nonvolatile organic carbon:  e.g.,  natural sugars.

      2.  Soluble, volatile organic   carbon:    e.g.,  mercaptans, alkanes,  low
          molecular weight  alcohols.

      3.   Insoluble,  partially volatile  carbon:     e.g., low molecular weight
          oils.

      4.   Insoluble,   particulate carbonaceous   materials:     e.g.,  cellulose
           fibers.

      5.   Soluble  or  insoluble   carbonaceous   materials   adsorbed or entrapped
           on insoluble inorganic suspended  matter:   e.g., oily  matter adsorbed
           on silt  particles.

      2.3   Carbonate and  bicarbonate  are inorganic  forms of  carbon  and  must be
 separated  from the total organic  carbon  value.    Depending on the instrument
 manufacturer's instructions,  this separation   can  be accomplished  by either a
 simple mathematical subtraction,  or  by   removing the carbonate  and  bicarbonate
 by  converting them to C02  with degassing prior to analysis.


                                   9060  - 1
                                                          Revision       0
                                                          Date  September 1986
                                       B-57

-------
     5.4   Carbonate-bicarbonate,  stock   solution,   1,000  mg/L  carbon:  Weigh
0.3500  g  of  sodium bicarbonate  and0.4418g of sodium carbonate and transfer
both  to the  same  100-mL volumetric  flask.   Dissolve with Type II water.

     5.5   Carbonate-bicarbonate,  standard  solution:    Prep^r   a  series of
standards similar to Step 5.3.
     NOTE:  This  standard is not  required  by some instruments.

     5.6   Blank solution:  Use  the  same  Type  U water as was used to prepare
the standard solutions.


6.0  SAMPLE COLLECTION, PRESERVATION,  AND HANDLING

     6.1   All samples must be collected  using  a sampling plan that addresses
the considerations discussed in Chapter Nine of this1 manual.

     6.Z  Sampling and storage  of   samples  in  glass  bottles is preferable.
Sampling and storage in plastic  bottles such as conventional polyethylene and
cubitainers  is permissible if  it  is  established  that the containers do not
contribute contaminating organics to the samples.
     NOTE:   A brief study performed  in the EPA Laboratory indicated that Type
          II water stored in new,  1-qt  cubitainers did not show any  increase
          in organic carbon after 2 weeks' exposure.

     6.3  Because of the possibility  of  oxidation or  bacterial decomposition
 of some  components of  aqueous  samples,  the time between sample collection and
 the  start of analysis  should be minimized.   Also,  samples should be kept  cool
 (4*C)  and protected from sunlight and atmospheric oxygen.

     6.4  In instances where analysis   cannot   be   performed   within 2 hr  from
 time of  sampling,  the  sample is  acidified  (pH £ 2)  with HC1  or H2S04.


 7.0   PROCEDURE
       r
      7.1  Homogenize  the sample  in  a  blender.
      NOTE:    To   avoid  erroneously  high  results,  inorganic  carbon must  be
           accounted for.  The  preferred method   is  to measure total  carbon and
           inorganic carbon  and to   obtain  the   organic carbon by subtraction.
           If this is  not possible,  follow Steps 7.2 and 7.3 prior to analysis;
           however,  volatile organic carbon may  be lost.

      7.2  Lower the pH of the  sample  to 2.

      7.3  Purge the sample with  nitrogen  for 10 min.

      7.4  Follow  instrument  manufacturer's   instructions  for  calibration,
 procedure,  and calculations.

      7.5  For calibration of the instrument,  a  series of standards  should be
 used that encompasses the expected concentration range of the samples.


                                   9060 - 3
                                                          Revision      0	
                                                          Date  September  1986
                                       B-58

-------
                        METMOO 9O6O

                    TOTAL ORGANIC CARBON
   Start
7. 1
  Homogenlie
the tamole  In
  m b lanoer
7.2
                                            7 . *
Follow manufacturer'«
  Instructions for
    ca 1 IDratIon.
   proceoure. ana
 calculations using
caroonaceous analyzer
  Lo^er tne
  s amo 1e OH
7.3
                                               7.5
    Uce series of
    stanOoras  for
     Ca 1 IbratIon
  Purge tne
 samo)e w1tn
  n1trogen
                                               7 .6
    Quadruo1Icate
     ana lysis
                                                  Stoo
                   9060 - 5
                                           Revision       0	
                                           Date  September 1986
                            B-59

-------
   ECOVA

   ANALYTICAL

   SERVICES
                                                        I MORGAN 1C  ANALYSIS  REPORT
                                                                                                       Client  No:   801610

                                                                                                       Page 1  of 3
    Customer  #



    EAS *



    Sample  Location/

     Description



    Matrix


3d
I    Date  Received
88350301
1047-01
5- 1
Sediment
08/25/88
88350302
1047-02
5-3
Sediment
08/25/88
88350303
1047-03
5-5
Sediment
08/25/88
88350305
1047-04
4-2
Sediment
08/25/88
88350307
1047-05
6- 1
S ed i me n t
08/25/88
88350308
1047-06
6-2
Sediment
08/25/88
    Parameters



    Total  Organic Carbon     27
14
13
                              21
                              40
37
U n i 11



 X
    All  samples run in triplicate.   Average  values  are  recorded.
    Data Release Authorized:



    68/1610HIAR.047
                                              Date

-------
ECOVA
ANALYTICAL
SERVICES
                                                      INORGANIC  ANALYSIS REPORT
                                                                                                      Client  No:  801610
                                                                                                      Page  2  of 3
Cus t omer #
EAS *
Sample Location/
Description
Matrix
fl
r> Date Received
88350309
1047-07
3- 1

Sediment
08/25/88
88350310
1047-08
3-2

Sediment
08/25/88
8835031 1
1047-09
3-3

Sediment
08/25/88
88350312
1047- 10
2-3

Sediment
08/25/88
88350313
1047- 1 1
1 - 2

Sediment
08/25/88
88350314
1047- 12
1 - 1

Sediment
08/25/88
 P arameters
Total Organic Carbon      34
                                          25
28
31
                                                                                        6.3
                                              19
Units

 X
 All  samples run in triplicate.  Average values  are  recorded.
 Data  Release Authorized:

 68/161 OH I AR.04?
                                           Date

-------
ECOVA
ANALYTICAL
SERVICES
                                                                                                    Client  No:   801610
                                                                                                    Page 3  of  3
                                                     1 N 0 R GAN I C  ANALYSIS REPOR T
Cus t omer #
EAS *
S amp le Location/
Description
Matrix
Date Received
88350315
1047-13
2- 1
Sediment
08/25/88
88350316
1047- 14
"/}
Sediment
08/25/88
 Parameters


 Total  Organic  Carbon    ' 41
40
Unit!


 X
 All  samples  run in triplicate.   Average values are recorded,
 Data  Release Authorized:


 68/1610HIAR.047
                                           Date

-------
E C 0  V A
        October 19,  1988


        Ms.  Joyce Crosson
        USEPA  Region  X, ESD
        1200 Sixth Avenue
        ES/096
        Seattle,  Washington   98101

        Dear Ms.  Crosson:

        EPA-ALASKA   801610

        Enclosed are the data sheets for the samples received on September 21,
        1988, and logged as follows:
           EAS Lab No.

           1095-01
           1095-02
           1095-03
           1095-04
           1095-05
           1095-06
           1095-07
           1095-08
           1095-09
           1095-10
           1095-11
           1095-12
           1095-13
           1095-14
                          Field ID No.

                          88390109
                          88390110
                          88390111
                          88390112
                          88390113
                          88390114
                          88390115
                          88390122
                          88390117
                          88390118
                          88390119
                          88390123
                          88390120
                          88390121
      Matrix

Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
This is a partial report for total organic carbon.  The report for metals
will be sent under separate cover.

Should you have any questions or concerns regarding the enclosed reports,
please contact me at (206) 883-1900, Extension 218.
        Sin
Corporate (Mice
3820 159th Avenue
Redmond. \VA 980."
(206) 883-1900
(206) 867-2210 FA


Gulf Coasi Region
12790 Merii Drive -L
lock Box 145
Dallas, TX 75251
(21-1)40-1-7540
(214) 404-7545 FAX
                                                                                         Eastern Region
                                                                                         500 Fifth Avenue
                                                                                         Suite 935
                                                                                         New York. NY 10110
                                                                                         (212)840-1042 *
                                                                                         (212i 840-1663 FAX
        Linda Bohannon
        Manager, Quality Assurance

        69/1610PLTR.095
        Enclosures
                                            B-63

-------
    ECOVA
    ANALYTICAL
    SERV I CES
                                                         INORGANIC ANALYSIS REPORT
                                                                                                        Client  No:   801610
                                                                                                        Page  1  of  3
    Customer #

    EAS #

    Sample Location/
     Description

    Matrix

i»   Date Received
td
I
883901 09
1095 -01
Station
50-2
883901 10
1095 -02
Station
50-4
883901 1 1
1095-03
Station
50-5
883901 12
1095-04
Station
40-3
88390113
1095-05
Station
40- 1
883901 14
1095-06
Station
B
                        Soil/Sediment   Soil/Sediment   Soil/Sediment   Soil/Sediment   Soil/Sediment  Soil/Sediment

                        09/21/88        09/21/88        09/21/88        09/21/88        09/21/88       09/21/88
    Parameters
    Total Organic  Carbon
                           17
                                                                                                                       Unit:
                                              1 1
                                                             14
                                                                        18
                                                                                           34
                                                                                                      31
    All values  reported  on  a  dry  weight  basis
  '   l-:>,/ '-,
Data Release Authorized:

69/1610HIAR.095
                                     Dnte

-------
     ECOVA

     ANALYTICAL

     SERVICES
                                                          INORGANIC ANALYSIS  REPORT
                                                                                                         Client No:  801610

                                                                                                         Page 2 of 3
I
cr\
un
Customer #



EAS #



Sample Location/

 Description



Matrix



Date Received
883901 15
1095-07
Station
A (replicate)
88390122
1095-08
Station
A (replicate,)
883901 17
1095 -09
Station
10-1
883901 18
1095-10
Station
10-0
883901 19
1095- 1 1
Station
20-1 rep
88390123
1095- 12
Station
20- 1 rep
Soil/Sediment  Soil/Sediment  Soil/Sediment  Soil/Sediment  Soil/Sediment  Soil/Sediment



09/21/88       09/21/88       09/21/88       09/21/88       09/21/88       09/21/88
     Parameters
     	i



     Total  Organic Carbon      15
                                          20
                                                         1 4
                                                                            21
                                                                                           36
                                                                                                           32
                                                                                           Units



                                                                                            %
     All  values reported on a dry weight basis,
                              /.:-/••/  i'i
     	-,	              	
     Data  Release Authorized:         Date


     69/1610HIAR. 095

-------
ECOVA
ANALYTICAL
SERVICES
                                                                                                    Client  No:   801610
                                                                                                    Page  3  of  3
                                                     INORGANIC  ANALYSIS  REPORT
Cd
I
Customer #

EAS #

Sample Location/
 Description

Matrix

Date Received
                            88390120

                            1095- 13

                            Station
                            30- 1
               88390121

               1095-U

               Station
               60- 1
Soil/Sediment  Soil/Sediment

09/21/88       09/21/88
Parameters

Total Organic Carbon
                                                                                                                      Units
All values reported on a dry weight basis
        //
    Data Release Authorized:

    69/1610HIAR.095
                                Date

-------
!     I
 C 0 V  A
          »+*
          »+»
          »*»
          »+«
          »+*
      October  28,  1988
      Ms. Joyce  Crosson
      USEPA Region X,  ESD
      1200  Sixth Avenue
      ES/096
      Seattle, Washington   98101

      Dear Ms.  Crosson:

      EPA-ALASKA   801610

      Enclosed are the metals analysis data sheets for the samples received on
      September 21,  1988, and logged as follows:
          EAS Lab No.
Field ID No.
      Matrix
          1095-09
          1095-10
          1095-11
          1095-12
          1095-13
          1095-14
88390117
88390118
88390119
88390123
88390120
88390121
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
Soil/Sediment
       This completes our report as the total organic carbon data sheets were
       transmitted October 19, 1988.

       Should you have any questions or concerns regarding the enclosed reports,
       please contact me at (206)  883-1900, Extension 218.
       Sinc^fely,
        „
       Linda Bohannon
       Manager, Quality Assurance

       69/1610-LTR.095
       Enclosures
Corporate Office
3820 159th Avenue \E
Redmond. \VA 98052
(206)883-1900
(206) 867-2210 FAX
                                                         Gulf Coast Region
                                                         12790 Merit Drive f220
                                                         Lock Box 145
                                                         Dallas. TX 75251
                                                         (214) 404-7540
                                                         (214) 404-7545 FAX
                                                         Eastern Region
                                                         500 Fifth Avenue
                                                         Suite 935
                                                         New York. NY 10110
                                                         (212) 840-1042
                                                         (212) 840-1663 FAX
                                               B-67

-------
ECOVA
ANALYTICAL
SERVICES
                      ANALYTICAL DATA REPORT NARRATIVE
To:           USEPA - Joyce Crosson                  Date:      10/28/88
Project No:    801610                                 EAS Batch No:  1095


SAMPLE RECEIPT INFORMATION

No. of Samples:      6        Collected on:   09/20/88  Received on:    09/21/88
                                       and 09/21/88
Comments:    None.

DATA & DETECTION LIMIT COMMENTS/ADDITIONAL INFORMATION

The following comments pertain to the trace metal analysis of the samples designated as
1095-09,  1095-10, 1095-11, 1095-12, 1095-13, and  1095-14.

o    The samples were homogenized and  digested  according  to  the  methods provided in the
     EPA's Contract  Laboratory Program Statement of Work, No. 787, Section III, Page  D4-D7.

o    Arsenic  and  lead  were  analyzed  by Graphite  Furnace  Atomic Absorption  (GFAA)
     Spectrometry,   using  a  Perkin-Elmer  Model  3030  Zeeman  spectrophotometer.    The
     analytical technique  incorporated the L'vov platform.  The  reported results represent the
     average of a set of duplicate injections and analyses. The calibration curves consisted of
     a blank and three standards.

o    Mercury was  analyzed by  Cold  Vapor  Atomic  Absorption  Spectroscopy according to
     Method 245.5   CLP-M, ibid.   The  calibration  curve consisted  of a  blank and three
     standards.

o    Cadmium, chromium, copper, nickel, silver, and zinc were analyzed by  Atomic Emission
     Spectrometry    (AES)  using   a  Baird   Model   PS-5  Inductively   Couple   Plasma
     (ICP) spectrophotometer.   The  calibration  curve  consists  of a  blank  and  five standards.
     The reported results represent the average of four five-second integrations.

Were any Nonconformance Memos submitted for these samples? I x  I Yes   |	[No

If yes, explain:

The  matrix spike  recoveries for mercury and  silver were outside of  the established  control
limits.
Signature:      N^(\ 4* Js^JsJ^       Date

69/1610-NAR.095
                                            B-68

-------
ECOVA
ANALYTICAL
SERVICES
                          Inorganic Analysis Data Sheet
Lab Sample No: 1095-10
Sample Matrix: Sediment
Date Sample Collected: 09/21/88
Date Sample Received:  09/21/88
Analyte

Arsenic
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Silver
Zinc
(As)
(Cd)
(Cr)
(Cu)
(Pb)
(Hg)
(Ni)
(Ag)
(Zn)
   mg/Kg
Concentration

 16.6
  3.8
 25.5
 52.9
 25.1
  0.18      U
 18.3
  3.1       U
186
                                      Project No: 801610
                                      Customer Sample No: 88390118
                                      Sample Description:
                                       Station 10-0
                                     M
F
P
P
P
F
CV
P
P
P
DATA REPORT QUALIFIERS:

U -  Indicates  that analyte  was  analyzed  for  but  not  detected.   The  number is the
     minimum attainable detection limit for the sample.

METHOD QUALIFIER - M:

P -   TCP
F -   FURNACE AA
CV - Manual Cold Vapor AA
 /J6   \jf]
 _AA^,,/<>/ I 7
Data Release Authorized:

69/1610-IAD.095
                                      B-69

-------
ECOVA
ANALYTICAL
SERVICES
                          Inorganic Analysis Data Sheet
Lab Sample No: 1095-09
Sample Matrix: Sediment
Date Sample Collected: 09/21/88
Date Sample Received:  09/21/88
Analyte

Arsenic
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Silver
Zinc
(As)
(Cd)
(Cr)
(Cu)
(Pb)
(Hg)
(Ni)
(Ag)
(Zn)
   mg/Kg
Concentration

 11.8
  2.2
 16.6
 39.8
 20.4
  0.22      U
 10.0       U
  2.5       U
140
                                 Project No: 801610
                                 Customer Sample No: 88390117
                                 Sample Description:
                                  Station  10-1
                                     M
F
P
P
P
F
CV
P
P
P
 DATA REPORT QUALIFIERS:

 U -  Indicates  that  analyte was  analyzed  for  but not detected.  The  number  is  the
     minimum  attainable detection limit for the sample.

 METHOD QUALIFIER - M:

 P -  ICP
 F -  FURNACE AA
 CV - Manual Cold Vapor AA
 Data Release Authorized:

 69/1610-IAD.095
                                        B-70

-------
ECOVA
ANALYTICAL
SERVICES
                          Inorganic Analysis Data Sheet
Lab Sample No: 1095-11
Sample Matrix: Sediment
Date Sample Collected: 09/21/88
Date Sample Received:  09/21/88
Analvte

Arsenic
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Silver
Zinc
(As)
(Cd)
(Cr)
(Cu)
(Pb)
(Hg)
(Ni)
(Ag)
(Zn)
                 mg/Kg
              Concentration
 15.1
  1.6
 18.1
 53.4
 23.7
  0.29
 12.5
  3.1
163
U
U
U
U
                                       Project No: 801610
                                       Customer Sample No: 88390119
                                       Sample Description:
                                       Station  20-1 rep
                       M
F
P
P
P
F
CV
P
P
P
DATA REPORT QUALIFIERS:

U -  Indicates  that  analyte was  analyzed  for  but not detected.  The number  is  the
     minimum attainable detection limit for the sample.

METHOD QUALIFIER - M:

P-   ICP
F-   FURNACE AA
CV - Manual Cold Vapor AA
           (A
Data Release Authorized:

69/1610-IAD.095
                                       B-71

-------
ECOVA
ANALYTICAL
SERVICES
                          Inorganic Analysis Data Sheet
Lab Sample No: 1095-12
Sample Matrix: Sediment
Date Sample Collected: 09/21/88
Date Sample Received:  09/21/88
Analvte

Arsenic
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Silver
Zinc
(As)
(Cd)
(Cr)
(Cu)
(Pb)
(Hg)
(Ni)
(Ag)
(Zn)
                 mg/Kg
              Concentration
 15.4
  1.6
 15.7
 41.3
 22.8
  0.29
 12.5
  3.1
138
U
U
U
U
                                      Project No: 801610
                                      Customer Sample No: 88390123
                                      Sample Description:
                                       Station 20-1 rep
                       M
F
P
P
P
F
CV
P
P
P
DATA REPORT QUALIFIERS:

U -  Indicates  that analyte was  analyzed  for  but  not  detected.   The number is  the
     minimum  attainable detection limit for the sample.

METHOD QUALIFIER - M:

P -  ICP
F -  FURNACE AA
CV - Manual Cold Vapor AA
Data Release Authorized:

69/1610-IAD.095
                                      B-72

-------
ECOVA
ANALYTICAL
SERVICES
                          Inorganic Analysis Data Sheet
Lab Sample No: 1095-13
Sample Matrix: Sediment
Date Sample Collected: 09/21/88
Date Sample Received:  09/21/88
Analvte

Arsenic
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Silver
Zinc
(As)
(Cd)
(Cr)
(Cu)
(Pb)
(Hg)
(Ni)
(Ag)
(Zn)
   mg/Kg
Concentration

 36.0
  5.0
 26.8
110
 92.6
  0.29      U
 26.8
  3.6       U
347
                                      Project No: 801610
                                      Customer Sample No: 88390120
                                      Sample Description:
                                       Station 30-1
                                     M
F
P
P
P
F
CV
P
P
P
 DATA REPORT QUALIFIERS:

 U -  Indicates  that analyte was  analyzed  for  but  not  detected.   The  number is the
     minimum  attainable detection limit for the sample.

 METHOD QUALIFIER - M:

 P -  ICP
 F -  FURNACE AA
 CV - Manual Cold Vapor AA
 Data Release Authorized:

 69/1610-IAD.095
                                        B-73

-------
ECOVA
ANALYTICAL
SERVICES
                          Inorganic Analysis Data Sheet
Lab Sample No: 1095-14
Sample Matrix: Sediment
Date Sample Collected: 09/21/88
Date Sample Received:  09/21/88
Analvte

Arsenic
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Silver
Zinc
(As)
(Cd)
(Cr)
(Cu)
(Pb)
(Hg)
(Ni)
(Ag)
(Zn)
                 mg/Kg
              Concentration
 12.4
  1.8
 37.5
103
 84.0
  0.40
 31.3
  3.6
184
U
U
U
                                      Project No: 801610
                                      Customer Sample No: 88390121
                                      Sample Description:
                                       Station 60-1
                       M
F
P
P
P
F
CV
P
P
P
DATA REPORT QUALIFIERS:

U -  Indicates that analyte  was analyzed for but not detected.   The  number is the
     minimum attainable detection limit for the sample.

METHOD QUALIFIER - M:

P -   ICP
F -   FURNACE AA
CV - Manual Cold Vapor AA
Data Release Authorized:

69/1610-IAD.095
                                      B-74

-------
                             U.S.  EPA - CLP
             COVER PAGE  -  INORGANIC ANALYSES DATA PACKAGE
b Name: £cor^,ce^

b Code: 	        Case No.:

H No.:  181

            EPA  Sample  No.
                                        Contract:

                                        SAS No.:
SDG No.:
                                             Lab Sample ID.
                                               ioqs-o<7
                                                  s -
re ICP interelement corrections  applied?

:e ICP background corrections applied?
  If yes-were raw data generated  before
  application of background corrections?

tunents:
    Yes/No

    Yes/No

    Yes/No
Lease of the data contained in this  hardcopy data package and in the
nputer-readable data submitted on  floppy diskette has been authorized by
- Laboratory Manager or the Manager's  designee,  as verified by the
Uowing signature.
                                  Lab Manager:   	
                                          Date:

                             COVER PAGE - IN

                                   B-75
       7/87

-------
                               U.S.  EPA - CLP
                         INORGANIC ANALYSIS DATA SHEET
Lab Name: £r0u*

Lab Code: 	
                           
-------
                               U.S.  EPA - CLP
Lab Name: t£r->r>uA

Lab Code:
                         INORGANIC ANALYSIS  DATA SHEET
                                       Contract:
                                                              EPA SAMPLE NO.
                                                             I  883^o\\8
                       Case No.:
SAS No.:
                                                              SDG No.:
Matrix  (soil/water) :   so'\i

Level  (low/med) :      TYveA

% Solids:              30*1
                                                   Lab  Sample ID: \pqS-IQ

                                                   Date Received:
           Concentration Units (ug/L  or mg/kg dry weight) :
Color Before:  B\o.c\C
 Color After:

 Comments :
                               Clarity Before:

                               Clarity After:
1 1
|CAS No. | Analyte
1 1
|7429-90-5 (Aluminum
(7440-36-0 1 Antimony
|7440-38-2 | Arsenic
17440-39-3 | Barium
|7440-41-7 | Beryllium
|7440-43-9 | Cadmium
17440-70-2 | Calcium
(7440-47-3 | Chromium
17440-48-4 | Cobalt
17440-50-8 | Copper
|7439-89-6 | Iron
17439-92-1 |Lead
|7439-95-4 (Magnesium
(7439-96-5 (Manganese
(7439-97-6 (Mercury
(7440-02-0 (Nickel
(7440-09-7 [Potassium
(7782-49-2 (Selenium
[7440-22-4 (Silver
17440-23-5 | Sodium
(7440-28-0 (Thallium
(7440-62-2 (Vanadium
(7440-66-6 |Zinc
| (Cyanide
1 1
Concentration


I&.&


3.R

,25.5-

.«.
-------
                                U.S. EPA  - CLP
                         INORGANIC  ANALYSIS DATA  SHEET


Lab Name:  £>/?,.,/?  /?oJ«/-//Vn)  .5erL/



p


                                                              Texture:
                                                              Artifacts
           r^xecA^rva
                                    FORM I - IN

                                      B-78
                                                                        7/87
                                                        Rev.  IFB Amendment One

-------
                                U.S. EPA -  CLP
                         INORGANIC ANALYSIS DATA SHEET
                                                              EPA SAMPLE NO.
                                                              I
Lab Name:  £>_/•>,;,4  AnrAy-j-.wA -Sero.gg^    Contract:	  |	- - -  -     .

Lab Code:  	       Case  No.:  	     SAS No.:          SDG No.:
Matrix  (soil/water) :   ^0,l

Level  (low/med) :

% Solids:
                     Lab Sample  ID:

                     Date Received:
                                                                         -i3.
           Concentration Units  (ug/L or mg/kg dry weight) :
                                                                  /\<0
 Comments:
1
| CAS No .
1
|7429-90-5
| 7440-36-0
[7440-38-2
(74^0-39-3
|7440-41-7
| 7440-43-9
| 7440-70-2
[7440-47-3
| 7440-48-4
[7440-50-8
| 7439-89-6
(7439-92-1
|7439-95-4
[7439-96-5
[7439-97-6
(7440-02-0
|7440-09-7
|7782-49-2
[7440-22-4
[7440-23-5
(7440-28-0
[7440-62-2
[7440-66-6
1
1
1
| Analyte
1
| Aluminum
| Antimony
| Arsenic
| Barium
| Beryllium
| Cadmium
| Calcium
| Chromium
[Cobalt
| Copper
| Iron
| Lead
| Magnesium
| Manganese
| Mercury
(Nickel
| Potassium
| Selenium
(Silver
| Sodium
(Thallium
(Vanadium
| Zinc
| Cyanide
1
Concentration


IS. 4


l.o,

/5»n

MI.3

afol • H


0.2<)
12. S-"


3*\



13ft


c





U








U
I)


U






1 1
Q | M |
1 1
1 1
1 1
\F\
\ \
1 1
IP 1
1 1
IPI
1 1
IPI
1 1
IF i
i i
i i
M \GV\
IP 1

1
hJ IP

1
1
IP

1
 -olor Before:

 -olor After:
Clarity  Before:

Clarity  After:
                                                             Texture:
                                                              Artifacts:
                                   FORM I - IN

                                      B-79
                                                                        7/87
                                                         Rev. IFB Amendment One

-------
                               U.S.  EPA - CLP
                         INORGANIC ANALYSIS DATA SHEET
                                                              EPA SAMPLE NO.
                                                             I  083^0(3.0     I
Lab Name:  t,Cov<\ AnJy'-//V»f/  6eru,ce<;    Contract: 	  	

Lab Code:  	       Case  No.:  	    SAS No.:           SDG No.:
Matrix  (soil/water) :   So/ /

Level  (low/med) :      TneA

% Solids:              /-£".,2.
                                                    Lab  Sample ID:  /O9S" -

                                                    Date Received: Q^ -21-
           Concentration Units  (ug/L  or mg/kg dry weight):
 Color Before:  R \

 Color After:   V

 Comments:
                               Clarity  Before:

                               Clarity  After:
1 i
|CAS No. | Analyte
1 1
|7429-90-5 | Aluminum
|7440-36-0 | Antimony
[7440-38-2 | Arsenic
[74-40-39-3 (Barium
[7440-41-7 (Beryllium
(7440-43-9 (Cadmium
(7440-70-2 (Calcium
|7440-47-3 (Chromium
(7440-48-4 (Cobalt
(7440-50-8 (Copper
(7439-89-6 (Iron
(7439-92-1 (Lead
(7439-95-4 (Magnesium
(7439-96-5 (Manganese
17439-97-6 (Mercury
(7440-02-0 (Nickel
(7440-09-7 (Potassium
(7782-49-2 (Selenium
17440-22-4 (Silver
(7440-23-5 (Sodium
(7440-28-0 (Thallium
(7440-62-2 (Vanadium
(7440-66-6 (Zinc
| (Cyanide
1 1
Concentration


36.0


S.O

c^O.8

110

<\3.(*


0.2<]
JC,.R


3.C,



34 T


c














u



U






Q














M



KJ






M


F


P

P

-?

F


QV\
P 1


P



P.


Texture:

Artifacts
                                   FORM  I  - IN

                                     B-80
                                                                       7/87
                                                        Rev.  IFB Amendmenc One

-------
                                                              EPA SAMPLE NO
                                U.S.  EPA - CLP

                                        1
                         INORGANIC ANALYSIS  DATA SHEET

Lab Name: £CO,/A AJnaWf.rJ Seru.ce^     Contract: 		

Lab Code: 	       Case  No.:  	    SAS No.:           SDG No.:
Matrix (soil/water) :  50,1

Level  (low/med) :      meA

I Solids:              _14'3_
                                                    Lab Sample ID:

                                                    Date Received:
            Concentration Units  (ug/L or mg/kg dry weight) : TYACJ>
 Color Before:

 Color After:
 Comments:
                               Clarity Before:

                               Clarity After:
                                                                  o
1 1
|CAS No. | Analyte
1 1
|7429-90-5 | Aluminum
|7440-36-0 [Antimony
17440-38-2 (Arsenic
174-40-39-3 (Barium
17440-41-7 (Beryllium
(7440-43-9 (Cadmium
(7440-70-2 (Calcium
(7440-47-3 (Chromium
(7440-48-4 (Cobalt
(7440-50-8 (Copper
(7439-89-6 (Iron
(7439-92-1 (Lead
(7439-95-4 (Magnesium
17439-96-5 (Manganese
(7439-97-6 (Mercury
(7440-02-0 (Nickel
(7440-09-7 (Potassium
(7782-49-2 (Selenium
(7440-22-4 (Silver
17440-23-5 (Sodium
(7440-28-0 (Thallium
(7440-62-2 (Vanadium
17440-66-6 (Zinc
| (Cyanide
1 1
Concentration


I2.*/


I.R

3H-S

\03

£4.0


o.'Ao
31.3


.3.0,



Ifc^


c





u








U



0






Q














M



rJ






M


F


P

P

P

f


cv\
P I


^
P



P


Texture:
Artifacts:
                                   FORM  I  - IN

                                     B-81
                                                                       7/87
                                                        Rev.  IFB Amendment One

-------
                             U.S. EPA - CLP
                                    2A
            INITIAL AND CONTINUING CALIBRATION VERIFICATION
D Name:

3 Code:
Case No.:
       , ^  *.t    <*        .
Ltial Calibration  Source: LeQA -
  Contract:

  SAS No.:
Cone, i   us E.p [\
   UVU_V-QfV\_
utinuing Calibration Source: :£no.-*Wc
SDG No.:
                       Concentration Units: ug/L

lalyte
Luminum
itimony
rsenic
irium
irylliun
idmium
ilciun
xromiun
Jbalt
jpper
ron
jad
ignesium
mganese
ircury
.ckel
itassium
ilenium
•Iver
Kliua
lallium
madium
.nc
ranide
	
Initi<
True


370


48^

^"OCn

JS"V,2
r
GO


5". 2
H96>


509



3/OO


il Calibrr
Found


375"


H^S

5"3T

53^

102


S^.5-
^(oR

•
/i/ f
Tfeto




:

ition



loi


inv

\O(o

9R.3

10M


IO^3
q^.t)


91. (a




II
\oo II ^a
ii
ii
un II o.qn
96,. R Ii 92o
II
Ii
t|7.0 * ^-^9
:
:
.
q-i.o -. ^^9
1! ,
; •

%R<1>


IQLJ


lO^

IC4-

ICI

104


q^-o
9,5.0


tfa.q,



q^.q


                                                                       I!
                                                                        I   I
                                                                         M
                                                                        £.
                                                                        12.1

                                                                        E
                                                                        !£.
   Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115
                           FORM II  (PART 1)  - IN

                                    B-82
                                               7/87

-------
        U.S.  EPA - CLP
               2B
 CRDL STANDARD FOR AA AND ICP
ab Name: EZC.C-J

ab Code:
Case No.:
A CRDL Standard Source:

CP CRDL Standard  Source:  IE
       re;amc
Contract:

SAS No.:
SDG No.
   Concentration Units: ug/L
Analyte
Muminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
.Icium
Chromium
Cobalt
Copper
Iron
Lead
Kagnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
sodium
Thallium
/anadium
2inc
—
CRDL S
True


10

'
1.




r
lr>
1
1
O.2O









tandard fo
Found


10.








\0


O.\R









r AA
*R


130








100


<^0.o


































True





10

3.Q

«TO





RO


^0



HO

CRDL Stai
Initial
Found





i4

^

>i4





&S"


li



33.

idard .
*R





•70.0

^.s.o

P.Ro





R/.^


^0.0



fip.O

for ICP
' Fina]
Found




c



















L
*R
























      FORM  II  (PART 2)  - IN

              B-83
                                                                     7/87

-------
                              U.S.  EPA - CLP
                                     3
                                  BLANKS
ab Name:
ab Code :
               Analy'-lical /
                      Case No . :
Contract:
SAS Mo.:
SDG No,
reparation Blank Matrix (soil/water) :  50,1
reparation Blank Concentration Units  (ug/L or mg/kg): "^ / K.
Vnalyte
Vluminum
Antimony
Arsenic
"\riun
jryllium
:admiua
:alcium
:hromium
:obalt
:opper
[ron
^ead
lagnesiuin
langanese
lercury
fickel
'otasslua
ieleniun
•ilver
> odium
Gallium
Vanadium
Jinc ~"
-Vanlde
— —
1
Initial
Calib. | Continuing Calibration
Blank Blank (ug/L)
(ug/L) CJ 1 C 2 C 3 C
1
1 II II
1 II II
o.l IUI o.s IUI o.s IOI o^
II -11 II
• 1 II .11
o.o IOI o.o lul o.o IUI
1 II II
^..1 lul J3.k IUI o.o IUI
1 II II
5-.0 IUI 4.<- IUI O.s IUI
1 II II
o.o IOI 0.3 IUI o.o IOI o.\
1 II 11
1 II II
o.no^ IUI 0.00-3 IOI II
J.3 IUI o.o IUI O.o IUI
1 1
1 1
o.o U o.o U o.o IUI
1 1
1 1
1 1
o.o U o.o U o.o IOI
I 1
1 1

a







U




~"






f,
1
1
Prepa- |
ration |
Blank C j


1 1
1 I
o.oo ilOl


0.0

1 1
1 1
IOI
1 1
o.o lul

0,0

O.OL

1 1
IUI
1 1
IOI
1 1
1 1

1 1
0.0 IUI


o.o

1 1
M


^1
1
£.1
p
E
_E_
0>Zl
£_l
1
1 II 1
IUI
1 1
l£_l
1 1
1 II

1 1
0.0 IOI
IT-!
1 1 1
1 II
                                FOPM  III - IN
                                    B-84
                                                                     7/87

-------
                              U.S. EPA  -  CLP
                       ICP INTERFERENCE  CHECK SAMPLE
ab Name:
ab Code:
               nrto.lvfigq
Case No:
Contract:
SAS No.:
                                                             SDG No
CP ID Number:
                                          ICS Source: JIGS
                        Concentration  Units:  ug/L
Analyte
Aluminum_
Antimony
Arsenic
Barium
Beryllium
Cadmium
/Calcium
Chromium
Cobalt
1 Copper
llron
Lead
Magnesium
1 Manganese
1 Mercury
(Nickel 	
Potassium
Selenium
1 Silver
1 sodium
1 Thallium
1 Vanadium
Zinc

True Initial Found
Sol. Sol. Sol. Sol.
A AB A AB *R
5-020001 £-oP>corl t43300O[ Hiiftooo





SO&OCC



IQkOOO

M^ftnool















909
SIC, 000
SL3

5^
o2o30od

^"C^OOO


^46


sqs



qq^





m
^.CuZOOO
5J? -

2B
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££32000
.Tifc

31
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1C3

                                FORM IV  -  IN
                                    B-85
                                                                     7/87

-------
                              U.S.  EPA - CLP
                                     5A
                           SPIKE SAMPLE RECOVERY
                                       EPA SAMPLE NO
                                                           I
ab Name: £>.oo(V

ab Code:
                                     Contract:
atrix (soil/water) :
 Case Ho.:

50 1 1
                                         SAS No.:
SD6 No.:
                                                    Level  (lov/med)
         Concentration Units (ug/L or mg/Xg dry weight):
toalyte
Huminum
mtimony
arsenic
Jarium
Jery Ilium
:adaiuB
!alciuB
airomium
:obalt
xspper
.ron
*ad
lagnesiua
(anganese
lercury
r-< «*i**o
I1CJC61
'otassium
>eleniua
Jilver
iodiua
•nallium
'anadium
inc "~
Vanide

Control
Limit
%R


n*-\2S


^ -\as"

nz-\2S

n*-\i.>

n*-\zs'


9s-- 1^5"

n^-\7.?
i
I
O5"-i2S



•l
-------
                             u.a. fiPA  ~
                                    5B
                     POST DIGEST SPIKE SAMPLE RECOVERY
                                                         EPA SAMPLE NO
                                    Contract:
Code:
                          Mo.
atrix (soil/water) :
SAS No.: 	   SDG No.:



           Level (lov/aed):
                        Concentration Units: ug/L
taalyt*
duainua
mtinony
^rs«nic
3ariua
Jeryllivun
ladaium-
:alciua
^iromiun
:obalt
:opp«r
on
^ad
[agn«siua
Iangan«s«
lercury
[iOctl
'otassixin
ieleniua
iilver
lodiuffl
'tialliua
anadiun
inc
yanld«

Control
Limit
' %R


ss-iis1








P.S--II5"




-








SpiJc^d Saapl*
Result (SSR)


;?q








.^^











t
i
c








I.


.













Sample
Result (SR)


R..3








\-V
"












c

























Spike
Adde4 (SA)


20








20













%R


lc^








«v. o













Q

























M


F








F













                            FORM V (PART 2)  - IN



                                   B-87
                                                                 7/87

-------
                             U.b.  EPA - CLP
Naae:  ECCVA

Code:
itrix (soil/water):
                                     SB
                     POST DIGEST SPIXK SAMPLE RECOVERY
                   EPA SAMPLE NO.
                                                          I
                                     Contract:
                          No.:
SAS No.:
SD6 No.:
           L«v«l  (lov/m*d):
                        Concentration Units: ug/L
uialyt*

iluBinxrm
jitiaony_
irs«nic
tariua
i«rylliuB
ladaiua-
:alciua
broaiuB
:obalt
:opp«r
on
«ad
tagntaiua
Iangan«s«
(ercury
icXtl
'otasslua
elaniua
ilver
odiua
tialliua
anadiua
inc
yanld«
	
Control
Limit
' %R



ft S--//5"








P.S"-!!^"




'








SpiXed Sajtpl«
Result (SSR)



33








Kr,













c









I
_















Saapl*
Result (SR)



H








\f»













c


























SpiXe
1 Added (SA)



20








AC













I%R



\\0








ICO













Q


























M



F








F













 mm«nts:
                            FORM V (PART 2)  - IN

                                   B-88
                           7/87

-------
                               u.s.
                                        ~ CLP
Name:

Code:
                                      5B
                      POST DIGEST SPIKE SAMPLE  RECOVERY


           cvfl Awr-WViccA      .oes     Contract:
                   EPA SAMPLE NO.
                  I
                           No.:
SAS No.:
SD6 No.:
Matrix (soil/vater):
           Level  (lov/»ed):
                         Concentration Units: ug/L
Analyt*

Xluainxm
Antiaony_
Arstnic
Barium
Beryl liun
Cadaiua-
Calciua
Chroaiui
Cobalt
Copper
on
Uad
Magn««iua
Mangan«s«
Mercury
Nickel
Potasslua
Seleniua
Silver ~
Sodiua
Thallium
Vanadium
Zinc
cyanide

Control
Limit
' %R



P^-ll-S"








fi^-lls"




-








SpiXexl Sample
Result (SSR)



•^o




_' •



30













C


























Sample
Result (SR)



fi.?








\?,
"












c


























SpiXe
Added (SA)



^70








c30













I%R



iO«








p.s; o













Q
X

























IM
"


F








£.













 omnents:
                             FORM V (PART 2) - IN

                                    B-89
                           7/87

-------
                              U.S.  EPA - CLP

                                      SB
                     POST  DIGEST SPIKE SAMPLE RECOVERY


  Name: ECO/A-  Av>r.WUt-.rA 5?povi^e.g.     Contract:  	

  Coda:
                                 EPA SAMPLE NO
                                 I
No.:
SAS No.:
SD6 No.:
atrix  (soil/water):   Soil
                          Level (lov/med) :
                        Concentration Units: ug/L
inalvte

U.uainua_
totiaony_
irsenic
Barium
ierylliuB
ladfflium-
:alcium
broaiua
:obalt
:opp«r
on
^ad
tagxMsiua
iangan«s«
lercury
icXtl
'otasaiua
el«niun
ilver
odium
nalliua
anadiua
inc ~
yanid«
_
Control
Limit
" %R



P-.













I%R



lOf.,








<75: o













Q


























IM
**


F








F













                             FORM V (PART 2) - IN

                                     B-90
                                          7/87

-------
.ob Naa*:
,ab Cod«:
                     5B
    POST  DIGEST SPIKE SAMPLE RECOVERY
*,AvV,odiua
fhalliua
Vanadium
:inc
:yanid«

Control
Limit
' %R


ftSH 15"








fiff-hi*




,






1
1
SpiX*d Sample
RMXilt (SSR)
.


39








6,4













c












.












Saapl*
RMXllt (SR)


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~












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SpiJCtt
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 Jmments:
                             FORM V (PART 2)  - IN
                                     B-91
                                                                      7/87

-------
                                     SB
                     POST  DIGEST SPIKE SAMPLE RECOVERY


dj Kame: £CCQA-  Ana\vV\on\ ^f^vur-rt     Contract:  	
                                                            EPA SAMPLE  NO.
                                                           r
  Code:
                      Case No.:
SAS No.:
SDG Ho.:
itrix (soil/vat«r):  so'/ /
                                                     L«v«l
                        Concentration Units: ug/L
oialyt*
duainua
jitiaony
irstnic
iariua
Hrylliun
ladaiuffl-
:alciua
IxroaiuB
lobalt
:opp«r
on
^ad
Eagntaiua
langancs*
lercury
:icXel
'otassiua
:eleniua
:ilver
odiuffl
'halliua
anadium"
inc
yanida

Control
Limit
- %R


&X-HS








A5T-//5T




-








Spiked Sample
Result (SSR)


,23








6>6>













c

























Sample
Result (SR)


7.0








HA
•












c

























Spike
Added (SA)


,20








2O













%K


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?ao













Q

























M


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F













 nn«nts:
                            FORM V (PART 2)  - IN

                                    B-92
                                                                     7/87

-------
Name:


Code:
                              U.S.  EPA - CLP


                                      6

                                 DUPLICATES



              JWVvWrA ,5e£viAC£S_    Contract:
                   EPA SAMPLE NO.
                      Cas« No.:
SAS Ho.:
SDG No.:
atrix  (soil/water):
 Solids for Sample:   .23,
           Leivel  (lov/med):
           •

    % Solids for  Duplicate:
          Concentration Units (ug/L or mg/fcg dry weight):
1
1
JAnalyte
1
| Aluminum
| Antimony
1 Arsenic
I Barium
| Beryllium
I Cadmium
| Calcium
| Chromium
1 Cobalt
I Copper
I Iron
I Lead
J Magnesium
J Manganese
I Mercury
(Nickel '
I Potassium
(Selenium
(Silver
(Sodium
I Thallium
(Vanadium
(Zinc
(Cyanide
I
Control
Limit


Jol7o


I. a M9/«^
'
ao°7o

20 7o

,20 7 a










3.0 7o




























Sample (S)


l\.«


3.3L

\G>.(^

39. 8

ao.-l


o.ai
10.0


5.5-



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c









.




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0
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i.
Duplicate (D)
:

lO.fT


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,

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£.1

1
£.1
1
1
1
£.1
1
1
                                 FORM VI - IN


                                     B.-93
                           7/87

-------
                              U.S.  EPA - CL?
                        LABORATORY CONTROL SAMPLE
.b Name:
b Code:
                     Case Mo.:
lid LCS Source
ueous LCS Source:  LCS foagn)
Contract:
SAS No.:
SDG No,
nalyte
Luninum
ntiaony
rstnic
iriua
irylliuB
idftiuB
ilcium
tromiuB
sbalt ~
>pper
ron
tad
vgnesiua
mganese
srcury
.cJcel^ 	
>tasslua
ileniua
.lv«r "
xiiua
iaiiiun_
madiun"
,nc ~"
'anlde
	
Aqueous (ug/L)
True Found %R











































































.
So
True Found
"


qn


M^.4
-
qq.t;

^qio

^3d


la.i
fnG.q


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187




^T^^


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9HvO

n.^oo

^05T


13. fe
^q.q


5
-------
                            U.S.  EPA -  CLP
Hame:

Code:
(WAvA-ArA .
                           ICP SERIAL DILUTIONS
                                    Contract:
                     Case No.:
                           SAS No.:
itrix  (soil/water):
 EPA SAMPLE NO.

I'	'	
I  88330*20


 SDG No.:
                                                 Level (lov/med) :
                                                          A
                       Concentration Units: ug/L
1
1
lAnalyte
1
lAluminua
| Antimony
| Arsenic
| Barium
| Beryllium
| Cadmiuji
ICalciua
| Chroaiua
1 Cobalt
|Copp«r
llron
ILMd
|Kagn«iiuB
|Kangan«s«
1 Mercury
I Nickel
| Potassium
I Selenium
I Silver
I Sodium
(Thallium
I Vanadium
IZinc
1

























Initial Sample
Resxilt (I)





1^*7

n^»s

?o2





H3.3,


in



4s\

c













_




d




_

























Serial
Dilution
Result (S)
:





0

.2£

^39,2,





0


0




-------
U.S. EPA - CLP

      10
HOLDING TIMES
Mama: EGQJ/\ j\
coda:
rtoW/-iCA( ^fr^iCes
Caca No.:
i
Contract:
_ SAS No.: S
                               SDG No.
EPA
Sample No.
SR^OU*?
PiP^q r>\ \ ft
Pto3<3OuG\
PW^ov^O
P,ft^C5p.\
P-.P,^o\a.3




.




r









Matrix
f^Cl I
So./
-S>.-/
Soil
JS,;/
5«,-/



















. Dat«
R«c«iv«d
07-2/-A6
o^-zy-feS
o9-^/ -eft
07 -^/.fifl
0
-------
                              U.S. EPA  -  CLP
                                    11
                 INSTRUMENT DETECTION LIMITS (QUARTERLY)
Lab Nama:
Lab Coda:
ICP ID Numbar:
Flam* AA ID Numbar:
Furnaca AA ID Numbar:
                     Ca«a Ho.:
                       3O3O
Contract: 	
SAS Ho.:  	
Data:     (O-2&-9P,
SD6 Ho.
laments;
Analyta
Aluminum
Antimony_
Arsanic
Barium
Bary Ilium
Cadmium 	
Calcium
ChTomitM
Cobalt ~
Coppar
Iron
Laad
Magnaaium
Manganaaa
Marcury
NicJcal
Potasafum
Salanlum
SilVtr, "
Sotflmm *
HimillTim
VaaaAium
Zinc

Wava-
langth


193 .2.








P»Z_












CRDL
(ug/L)
200
60
10
200
5
5
5000
10
50
25
100
5
5000
15
0.2
40
5000
5
10
5000
10
50
20

IDL
(ug/L)


3.0




10

A£

3.O


0.2
HO


10



£O
1
                                                        SL
                                                        £.
                                                        2
                                FORM  XI  - IH
                                    B-97
                                                                      7/87

-------
C 0  V A
          *•
          »*
          »*
      October 28, 1988
      Ms. Joyce Crosson
      USEPA Region X,  ESD
      1200 Sixth Avenue
      ES/096
      Seattle, Washington   98101

      Dear  Ms. Crosson:

      EPA-ALASKA - 801610

      Enclosed are the metals analysis data sheets for the samples received on
      September 20,  1988, and logged as follows:
         EAS Lab No.

         1093-01
         1093-02
         1093-03
Field ID No.

88390101
88390104
88390107
Matrix

Water
Water
Water
      Should you have any questions or concerns regarding the enclosed reports,
      please contact me at (206) 883-1900, Extension 218.
      Linda Bohannon
      Manager, Quality Assurance

      69/1610-LTR.093
      Enclosures
Corporate Office
3820 159th Avenue XE
Redmond, \VA 98052
(206) 883-1900
(206) 867-2210 FAX


Gulf Coast Region
12790 Merit Drive #220
Lock Box 145
Dallas. TX 75251
(214) 404-7540
(214) 404-7545 FAX


Eastern Region
500 Fifth Avenue
Suite 935
New York, NY 10110 -
(212) 840-1042
(212) 840-1663 FAX
                                             B-98

-------
ECOVA
ANALYTICAL
SERVICES
                      ANALYTICAL DATA REPORT NARRATIVE
To:           USEPA - Joyce Crosson                 Date:     10/28/88
Project No:    801610                                 EAS Batch No: 1093


SAMPLE RECEIPT INFORMATION

No. of Samples:     3         Collected on:   09/20/88  Received on:   09/20/88

Comments:    None.

DATA & DETECTION LIMIT COMMENTS/ADDITIONAL INFORMATION

o   The  samples  were digested according to the methods  provided  in the EPA's  Contract
    Laboratory Program Statement of Work, No. 787, Section III, Page D4.

o   Arsenic  and  lead  were  analyzed  by  Graphite Furnace Atomic Absorption  (GFAA)
    Spectrometry,  using  a  Perkin-Elmer Model  3030   Zeeman   spectrophotometer.    The
    analytical technique  incorporated the  L'vov platform.  The reported results represent the
    average of  a set of duplicate injections and analyses.  The calibration curves consisted of
    a blank and three standards.

o   Mercury was  analyzed by  Cold Vapor Atomic Absorption  Spectroscopy according to
    Method 245.1  CLP-M,  ibid.   The calibration  curve consisted  of a  blank  and  four
    standards.

o   Cadmium, chromium, copper,  nickel, silver, and zinc  were analyzed by Atomic  Emission
    Spectrbmetry   (AES)   using   a  Baird   Model   PS-5  Inductively   Couple   Plasma
    (ICP) spectrophotometer.  The  calibration curve consists of a blank and  five standards.
    The  reported results represent the average of four five-second integrations.

Were any  Nonconformance Memos submitted for these samples? I x I Yes   |	|No

If yes, explain:

The matrix spike  recoveries for mercury  and silver were outside  of  the  established control
limits.
^nature:     f(i^ (I.  4 LlMAjJ          Date:

69/1610-NAR.093
                                           B-99

-------
ECOVA
ANALYTICAL
SERVICES
                          Inorganic Analysis Data Sheet
Lab Sample No: 1093-01
Sample Matrix: Water
Date Sample Collected: 09/20/88
Date Sample Received:  09/20/88
Analyte

Arsenic
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Silver
Zinc
(As)
(Cd)
(Cr)
(Cu)
(Pb)
(Hg)
(Ni)
(Ag)
(Zn)
                 mg/L
              Concentration
0.010
0.005
0.010
0.025
0.010
0.0002
0.040
0.010
0.020
U
U
U
U
U
U
U
U
U
                                 Project No: 801610
                                 Customer Sample No: 88390101
                                 Sample Description:
                                 001-Main Composite
                      M
F
P
P
P
F
CV
P
P
P
 DATA REPORT QUALIFIERS:

 U -  Indicates  that  analyte was  analyzed  for  but  not  detected.
     minimum attainable detection limit for the sample.

 METHOD QUALIFIER - M:

 P -  ICP
 F -  FURNACE AA         i
 CV - Manual Cold Vapor AA
                                                The  number  is the
        UL- ^A
 Data Release Authorized:

 69/1610-IAD.093
                                       B-100

-------
ECOVA
ANALYTICAL
SERVICES
                          Inorganic Analysis Data Sheet
Lab Sample No: 1093-02
Sample Matrix: Water
Date Sample Collected: 09/20/88
Date Sample Received:  09/20/88
Analvte

Arsenic
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Silver
Zinc
(As)
(Cd)
(Cr)
(Cu)
(Pb)
(Hg)
(Ni)
(Ag)
(Zn)
                 mg/L
              Concentration
0.010
0.005
0.010
0.025
0.010
0.0002
0.040
0.010
0.029
U
U
U
U
U
U
U
U
                                      Project No: 801610
                                      Customer Sample No: 88390104
                                      Sample Description:
                                       002A-Primary Composite
                       M
F
P
P
P
F
CV
P
P
P
 DATA REPORT QUALIFIERS:

 U -  Indicates  that  analyte was  analyzed  for but not detected.  The number  is  the
     minimum attainable detection limit for the sample.

 iMETHOD QUALIFIER - Mfc

 P -  ICP
 F -  FURNACE AA
 CV - Manual Cold Vapor AA
 Data Release Authorized:

 69/1610-IAD.093
                                       B-101

-------
ECOVA
ANALYTICAL
SERVICES
                          Inorganic Analysis Data Sheet
Lab Sample No: 1093-03
Sample Matrix: Water
Date Sample Collected: 09/20/88
Date Sample Received: 09/20/88
Analyte

Arsenic
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Silver
Zinc
(As)
(Cd)
(Cr)
(Cu)
(Pb)
(Hg)
(Ni)
(Ag)
(Zn)
                 mg/L
              Concentration
0.010
0.005
0.018
0.025
0.010
0.0002
0.040
0.010
0.132
U
u

U
u
u
u
u
                                       Project No: 801610
                                       Customer Sample No: 88390107
                                       Sample Description:
                                        002B-Secondary Composite
                       M
F
P
P
P
F
CV
P
P
P
 DATA REPORT QUALIFIERS:

 U -  Indicates that  analyte was analyzed for but not  detected.   The  number is the
     minimum attainable detection limit for the sample.

 METHOD QUALIFIER - M:

 P -  ICP
 F   FURNACE AA
 CV - Manual Cold Vapor AA
    Mn-/ _ UL _ ^ J^ '* AJ_ ..
        _            _
 Data Release Authorized:

 69/1610-IAD.093
                                        B-102

-------
                              U.S. EPA - CLP



              COVER PAGE - INORGANIC ANALYSES DATA PACKAGE



ab Name: ££/>.>A ACU.OP<;          Contract:
  Code: 	        Case No.:  	    SAS No.: 	    SDG No.
             EPA Sample No.   '                Lab Sample ID.
               8839010 \                          |pq3-o\
                      on
   ICP interelement corrections applied?                       Yes/No

ire ICP background corrections  applied?                         Yes/No
   If yes-were raw data generated before
   application of background corrections?                      Yes/No

munents:
      of the data contained  in  this hardcopy data package and  in  the
»nputer-readable data submitted  on floppy diskette has been authorized  by
ie Laboratory Manager or the  Manager's designee, as verified by the
flowing signature.                                         \/
                                    Lab Manager:  	Y	
                                           Date:
                               COVER PAGE - IN                      7/87


                                   B-103

-------
                                U.S. EPA  -  CLP
                         INORGANIC  ANALYSIS DATA  SHEET
                                                               EPA SAMPLE NO.
Lab Name:

Lab Code:
/)/).-> /v/,>
                              . ;<*<»«.
                                       Contract:
                       Case No.:
                           SAS No.:
                                                               SDG No. :
Matrix  (soil/water) :

Level  (low/med) :        \r.w

% Solids:
                                    Lab  Sample ID:

                                    Date Received:
           Concentration Units  (ug/L or mg/kg dry weight) :   ~CX9 /!_
 Color Before:

 Color After:
 Comments:
I 1
|CAS No. | Analyte
1 1
[7429-90-5 [Aluminum
[7440-36-0 [Antimony
[7440-38-2 [Arsenic
[7440-39-3 [Barium
[7440-41-7 [Beryllium
(7440-43-9 [Cadmium
[7440-70-2 [Calcium
[7440-47-3 [Chromium
17440-48-4 | Cobalt
17440-50-8 [Copper
[7439-89-6 [Iron
[7439-92-1 [Lead
| 7439-95-4 [Magnesium
[7439-96-5 [Manganese
[7439-97-6 [Mercury
[7440-02-0 [Nickel
[7440-09-7 [Potassium
[7782-49-2 | Selenium
[7440-22-4 [Silver
[7440-23-5 (Sodium
[7440-28-0 [Thallium
[7440-62-2 [Vanadium
[7440-66-6 |Zinc
| (Cyanide
1 1
1 1
Concentration) C| Q
1 1
1 1
1 1
10 IUI
1 1
1 1
S.o IUI
1 1
10 IUI
1 1
3S- IUI
1 1
\o IUI
1 1
1 1
O.2. IUINI
40 IUI
1 1
1 1
lo IUI KJ
1 1
1 1
1 1
ao IUI
1 1
1 1
M


F


P

P

P

F


cv
p


P



£_

	
               Clarity Before:
               Clarity After:   Clear
                                                              Texture:
                                                              Artifacts:
                                    FORM I -  IN

                                     B-104
                                                        7/87
                                        Rev.  IFB Amendment One

-------
                               U.S. EPA - CLP
                        INORGANIC ANALYSIS DATA SHEET
                                                             EPA SAMPLE NO.
                                                            I
Lab Name:


Lab Code:
AWAvl.^.\
                                      Contract:
                                                               883c-io\oH
       Case No. :
                                           SAS  No. :
                                             SDG No.:
Matrix  (soil/water) :


Level  (low/med) :


% Solids:
                                   Lab Sample ID:


                                   Date Received:
           Concentration Units (ug/L or mg/kg dry weight):
 Color Before:


 Color After:


 Comments:
                               Clarity Before:
                                                    V

                               Clarity After:  C\eoO
1
ICAS NO.
1
(7429-90-5
|7440-36-0
j 7440-38-2
(74TIO-39-3
|7440-41-7
J7440-43-9
|7440-70-2
1 7440-47-3
[7440-48-4
|7440-50-8
| 7439-89-6
(7439-92-1
J7439-95-4
(7439-96-5
(7439-97-6
(7440-02-0
(7440-09-7
(7782-49-2
(7440-22-4
|7440-23-5
(7440-28-0
| 7440-62-2
(7440-66-6
1
1
1
| Analyte
1
| Aluminum
| Antimony
(Arsenic
| Barium
Concentration


\
C| Q
1
1
1 M
1
1 1
1 1
10 IUI
1 1
(Beryllium) | |
| Cadmium
5:0 IUI
(Calcium
1
(Chromium in IUI
I Cobalt | |
(Copper 33- IUI
(Iron | 1
ILead in IUI
| Magnesium
j Manganese
| Mercury
(Nickel
| Potassium
1 Selenium


1
IF
i
i
i P
i ^
ip

i P
i
IF

1 1
0.2 IUIM
MO 101


(Silver | \Q
[Sodium
(Thallium
[Vanadium
| Zinc
[Cyanide
1



^


1
1
Ul v4
1
ICVI
IP 1
1
1
IP

1 1
1
I
1 ^
\ P
I 1
1 1
                                            Texture:


                                            Artifacts:
                                   FORM I - IN


                                     B-105
                                                       7/87

                                        Rev. IFB Amendment One

-------
                               U.S.  EPA - CLP
Lab Name:

Lab Code:
                        INORGANIC ANALYSIS  DATA  SHEET
                                       Contract:
                                                             EPA  SAMPLE NO
                                                             I
                       Case No.:
SAS No.:
SDG No.:
Matrix  (soil/water) :  wkxVec

Level  (low/med) :       \OW

\ Solids:
                                                   Lab Sample ID:

                                                   Date Received:
           Concentration  Units (ug/L or mg/kg dry weight) :
1 1
|CAS No. | Analyte
1 1
|7429-90-5 | Aluminum
| 7440-36-0 | Antimony
|7440-38-2 | Arsenic
|74TtO-39-3 (Barium
|7440-41-7 | Beryllium
17440-43-9 (Cadmium
(7440-70-2 (Calcium
(7440-47-3 (Chromium
(7440-48-4 (Cobalt
(7440-50-8 (Copper
(7439-89-6 (Iron
(7439-92-1 (Lead
1 7439-95-4 (Magnesium
(7439-96-5 (Manganese
(7439-97-6 (Mercury
(7440-02-0 (Nickel
(7440-09-7 (Potassium
(7782-49-2 (Selenium
17440-22-4 (Silver
(7440-23-5 (Sodium
(7440-28-0 (Thallium
(7440-62-2 (Vanadium
(7440-66-6 (Zinc
1 (Cyanide
1 1
1
Concentration
.
1
in


J7.0

ifi

3.5-

10


0.2
MO


\0



133.


c


U


0



0

0


U
U


\J






Q


w











N!
i


isl






M


F


£

f>

f>

F


CVI
PI


?



9

	
 Color Before:

 Color After:

 Comments:
                               Clarity Before: rM
                               Clarity After:   ClWr
                  Texture:

                  Artifacts:
                                   FORM  I  -  IN

                                      B-106
                                                                       7/87
                                                        Rev. IFB Amendment  One

-------
                              U.S. EPA - CLP
                                    2A
            INITIAL AND CONTINUING CALIBRATION VERIFICATION
ib Kane:

ib Code:
                 aiYriCai
                                          Contract:
                     Case  No.:
                                           SAS No. :
                                -UJpc^o Cone I.
                               - icv-4 fosp/V")
utial Calibration Source:  \_^

jntinuing Calibration Source: rchoroamc
                                                     _,	SDG  No.:
                                                     jzrcP- JTCV-I (cHfei) a
                                                          »-icv-sCc
                        Concentration Units: ug/L
inalyte
                                 I                         i
            Initial Calibration |     •-.:  Continuing Calibration
           True     Found   %R(1)   True'   Found  %R(1)  | Found  %R(1)
                                                                           M
duminum_
intinony_
irsenic	
lariua
lerylliua
          3*70
Jiromium
lobalt	"
:opper	
ron
Magnesium |
ianganese j
iercury
           qc,
otassium
eleniun
ilver__
odiua
anadiua
inc    ~
yanlde
          /TO9
          3 ICC)
                   395-
                   53T
                     qq
                             IQi
                                    so
                            101
                                   IOOO
                             infe
                                    toon
                                   loon
                             IDI
                                     1.0
                                  ir>oo
                             ^/.^
                                    IOOO
                                              1.0
                                              5-0
                                                        .IL
                                                        .11
                                                     (01  II  10MO
                                                          II
                                                    	  JL
                                                     Sff.o II
     .IL
	.IL
 ion  »
                                                     qq.o lie
                                                              .0
                                                         IL
                                                     7^ . «
                                                          IU.
                                                                    loo
ICv/1
I£J

 Zl
 £_!

 Zl
)   Control  Limits: Mercury 80-120; Other Metals 90-110;  Cyanide 85-115
                            FORM II  (PART 1) - IN

                                   B-107
                                                                       7/87

-------
       U.S.  EPA - CLP
              2B
CRDL STANDARD FOR AA AND ICP
ib Name:  brow A rvf\ftVAtoo\ -^

ib Code:  	        Case No.:
                   Contract:

                   SAS No.:
                                                              SDG No,
v CRDL Standard Source:  iTn organs

:p CRDL Standard Source: Xr>oft
                .o^
  Concentration Units:  ug/L
jialyte
luminum
.ntimony
xsenic
lariUB
terylliun
^dmium •
.Iciua
hromiuB
:obalt
Copper
ron

-------
                              U.S.  EPA -  CLP

                                     3
                                  BLANKS
b Name: £c.ouflt ftnal>/hr«l  6eru,fr.s         Contract: 	

b Code: 	        Case No.:  _[	    SAS  No.:    .       SDG No,

eparation Blank  Matrix (soil/water) :  u)aVer

eparation Blank  Concentration Units (ug/L or ing/kg):  J-x<3 |i_
nalyte
luminum
ntinony
rsenic
•\riun
jry Ilium
adaiun
alcium
hromium
obalt
opper
ron
ead
1
Initial |
Calib. | Continuing Calibration
Blank | Blank (ug/L)
(ug/L) CJ 1 C 2 C 3 C
1
II II
II II
1 1
I 1
0.^ IUI 0.2. IUI 1.2 IUI O.M
II -11
-II II
1 1
• .1 1
o.o IUI o.o IUI o.o IUI
II II
q.a lui r?.q mi *.,<
ii ii
^o IUI H-a IUI M.i.
ii it
o.i IUI o.t IUI r>.i
agnesiumj | | | |
anganese
arcury
ickel
otasslum
elenium
ilver
odium
tiallium
anadium
inc
yanlde
-
II II
o.oo IUI o.o\ IUI
3.3 IUI o.o IUI o.c
II
1 1

1 i
1 1
1 1
1 1
IUI
1 1
IUI
1 1
IUI n.^
1 1
1 1
1 1
:> I\JI
1 1
1 1

1 1
1 1
1 1
o.o HJI o.o L) o.o lUl
1 1
1 1
1 1
1 1

U
"





U












',
II
1 1
Prepa- | |
' ration j |
Blank C | | M
II
1 II
1 II
0.3 .IUI 1 F 1
1 II- 1
1 II 1
o_o IUIIPI
1 II
£.« IUI 1 P 1
III 1
o.o IUI IP
III 1
5.fl IRI 1 F
III 1
1 1 1
1 1 ICV1
0.0 IUIIPI
1 II 1
1 II 1
o.o IUI 1 P 1
III 1
III 1
1 II 1
O.o IUIIPI
III 1
1 1 1
                                FORM III -  IN

                                    B-109
7/87

-------
       U.S. EPA - CLP
ICP INTERFERENCE CHECK SAMPLE
ib Name: Z-CCUA rWlyfica
O€roiCe«q Contract:
ib Code: Case No: ' SAS No.:
:P ID Number: ^FMRG PS(
o ICS Source:
SDG No.:
XGS Co3RT) u^iLV-a^^_
 Concentration Units: ug/L
1
1
1
1 Analyte
1
| Aluminum
| Antimony
1 Arsenic
| Barium
| Beryllium
1 Cadmium
, Calcium
I Chromium
1 Cobalt
1 Copper
"llron
ILead r
True
Sol. Sol.
A AB
So3ooo\ -S'oAcor









909
SD&OCdSKeOOG



iqr.ooG

1 Magnesium | qq^QOQ
1 Manganese j
1 Mercury

1 Nickel |
1 Potassium |
1 Selenium

1 Silver |
I Sodium 1
1 Thallium |
1 vanadium j
IZinc |
1 1
513

5^
o2<930od

^CQOOO


q,\6


qqs



qn^

Initial Found
Sol. sol.
A AB %R
ik2300O\ q^ftooo




m
^,02000
53 -

2B
jQiOOO

ExceeO


13.


O.O



O.O





qsft •
^liOOO
5*^4

. Co4o
\q3,oor:>

S Li^tKClvV^i


q^a.


II SO



^ftS

ft^.^
•



I0b"
[[^
M4

UO
^.1

or>
5^P,

(oM 1
IQSOOD

*VT an A voa


q^ci


irfto



IOOO
1
f&M




ice.
po
HT

\2O
^f

je\^vNoV\
J

(OH


v.q



IC3

         FORM IV - IN



             B-110
7/87

-------
                            U.S. EPA - CLP

                                   5A
                         SPIKE  SAMPLE  RECOVERY


Name:  .jETcouA- (\<\a\VTwrA Seco.oes    Contract:
                                                             EPA SAMPLE NO.
                                                            I
   Code:
Case No.:
SAS No.:
                                                          SD6 No.:
tetrix (soil/water):
                                                  Level  (lov/med)
                                                  Ir.w
          Concentration Units (ug/L or ng/kg dry weight):  -^9,
Analyte
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
dopper
~ron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
rnallium
/anadium
Zinc
Cyanide

Control
Limit
*R


n^-as*


157- \3S

7e^-\2S~

r7S"-i2^T

ns-as-



ft7S-i2S"
1
!







Spiked Sample
Result (SSR)


fio


Mi

aiq.

A&n




O.GG
4^j p)


^?l






c

"








.











,

_
1
Sample | Spike
Result (SR) C| Added (SA)
1
1 1
1 1
In IUI 20
1 1
I 1
s-.o IUI ^o
1 1
10 IUI ^00
1 1
2.5- IUI s*r>
1 J
10 IUI ' LLO
1 1
1 1
0.2 IUI 1.0
«4O IUI 5-00


10 U .
-------
                                      SB
                      POST DIGEST SPUCE SAMPLE  RECOVERY
                                                          EPA SAMPLE  NO.
                                                            I
                          \j\o e.s_
                                      Contract:
Cod«:
                           Ho.:
SAS No.:
SDG Ko.:
!atrix  (soil/water) :
                                                   L«v«l (low/m«d):
                         Concentration Units: ug/L
inalvte

Muainua
Kntinony
\rs«nic
Bariua
Beryl liua
Zadaiua
:alciua
^iromiun
:obalt
:opp«r
on
L«ad
iagn«siua
langan€s«
lercury
lidctl
Potassium
»el«niua
»ilver
>odiua
:naiiiua
Vanadium
line
^anid«

Control
Limit
' %R



fiS-ili








PS-U5T













Spiked Saapl*
RMiuIt (SSR)



^0








01













c


























Saapl*
Rasult (SR)



10








/n













c



y








u












^^
Spika
Add*4 (SA)



30








3n













I*R
'*»


/oo








/d\s-













Q
w

























(K
41


£.








F













 laments:
                             FORM V (PART 2) - ZH
                                     B-112
                                                                   7/87

-------
Naa«:
Coda:
                SB
POST DIGEST SPIKE SAMPLE RECOVERY
         les     Contract: 	
     No.:           SAS No.:
;atrix  (soil/vat«r):
                                                            EPA SAMPLE NO.
                                                           I
                                                            SDG No.:
                        Concentration Units:  ug/L
Analyt*

\luainua
\ntimony_
\rs«nic
Bariua
Beryllium
:adniua
Zalciua
^roaiui
robalt
:opp«r
on
>»ad
lagntsiua
fangan«s«
tercury
Udcel
Potass i via
>eleniua
Silver
iodiua
:naiiixm
ranadiun
line
:yanld«
	 	 =
Control
Limit
' %R



Af^-n^








fi.
-------
                              U.S. EPA ~ CLP
dp Naa«:

ab Cod«:
                                     SB
                     POST DIGEST SPIKE SAMPLE RECOVERY
                                     Contract:
                           Ho. :
SAS No.:
atrix (soil/vatar):  .u/'g-j-er
                                                            EPA SAMPLE  NO.
                                                           I
SDG Ho.:
                                                     L«v«l (lov/Md):
                        Concentration Units:  ug/L
Uialyt*
duainua
mtiBony_
urstnic
Jarium
!«ry Ilium
:adoiua-
:alciuB
Ihroaixim
:obalt
:opp«r
on
«ad
lagntsiua
langan*s«
tercury
icXel
'otassiun
elanium
ilver
odium
halliua
anadiua
inc ""
yanid*

Control
Limit
- %R


PS- US'







R«T-ILJ







u













^^
SpiJc*
Add«4 (SA)


Dn







3r>














*R


-10.0







q^.n














Q


IW






















M


!£_







E.














 aments:
                            FORM V (PART 2)  - IN

                                     B-114
                                                                     7/87

-------
                              U.S.  EPA - CLP
                                 DUPLICATES
                                                           EPA SAMPLE NO
Name:  Erouft /WAvXimV
Code:
                                     Contract:
                     Case Ho.:
SAS Ho.:
SDG Ho.:
atrix (soil/water):
 Solids for Sample:
                                                  Level (lov/med):  \OvS
                                           % Solids for Duplicate: 	
          Concentration Units (ug/L or ng/kg dry weight):
                                                            i_
1
1
JAnalyte
1
| Aluminum
| Antimony
j Arsenic
(Barium
| Beryllium
1 Cadmium
| Calcium
| Chromium
1 Cobalt
1 Copper
llron
ILead
j Magnesium
j Manganese
I Mercury
1 Nickel -
1 Potassium
j Selenium
(Silver
1 Sodium
(Thallium
I Vanadium
1 Zinc
(Cyanide
1
Control
Limit


\O "-it.


S ^L

\O **L

3S -«»)/,.

5" -*"*/<-
!
I
0.2 v4/f
MO -i/.


\O ^/c
































Sample (S) C
1
1
10 10
1
1
/r.o 10
1
10 10
I
^.D 1011
1 II
1 II


























1 1
1 1
Ql M |
I I
1 1
1 1
I£J
-1 1
1 1

1 1
IP.,1

1 Pi
1 1
1 F 1
1 1
1 1
icyi
ipi
i i
i i
ipi
i i
i i
',, i
ip i
i i
i i
                                FORM VI - IN
                                                                  7/87
                                   B-115

-------
                               U.S.  EPA - CLP
                         LABORATORY CONTROL SAMPLE
;,ab Name:  ELcou
,ab Code:
;olid LCS Source:
                     V\
                       Case Mo. :
Aqueous LCS Source: Jincrggnic
Contract:
SAS No.:
SDG No.:
Analyte
AluBinum^
Antimony
Arsenic
Bariusi
Berylllua
Cadmium
Calcium
-hromium
cobalt
Copper
Iron
Lead
Aqueous (ug/L)
True Found %R

-^



SO

ion

I5L5"


Magnesium)
Manganese
Mercury
«ickel_i 	
Potassium
selenium
Silver
j odium
mallium
Vanadium
Jinc
^anldie
. 	
'

asn


as



550







^^

/c^O

1^0





,5^0


«2.<-



3^«







106,
130
<76.o





ion

too


^.a.

Solid (mg/lcg)
True Found C Limits %R






























•




















z











































































                                 FORM VII - IN
                                      B-116
                                                                       7/87

-------
                              U.S.  EPA - CLP
Name:
Code:
                            ICP SERIAL DILUTIONS
                                     Contract:
                                                           EPA SAMPLE NO.
                     case No.:
SAS No.:
SD6 No.:
atrix (soil/water) :
                                                  Level (lov/med) :
                        Concentration Units: ug/L
1
1
(Analyte
1
| Aluminum
| Antimony
1 Arsenic
(Barium
| Beryllium
| Cadmium
1 Calcium
| Chromium
1 Cobalt
1 Copper
(Iron
ILead
| Magnesium
(Manganese
1 Mercury
1 Nickel
I Potassium
| Selenium
(Silver
(Sodium
(Thallium
j Vanadium
(Zinc
1

























Initial Sample
Result (I)





-S.O
•
10

as





MO


in



3L<\

c
•





U

0

0





0


0






























Serial
Dilution
Result (S)





£•.0

10

3
-------
                           U.S.  EPA - CLP

                                  10
                            HOLDING TIMES
Nama:
Coda:
                   C*«a Ho
Contrmct:

SAS No.:
SDG No.:
EPA
Saapla No.
.Pft^oinl
i^A3qmn4
lftft:^oir>n






















Matrix
waVer
vw<\Ver
v«JaA-e.r





•
















. Dat«
R*c«iv«d
C?q-ao-8R
W-,20-RPs
CT-50--RR






.















1

























Marcury
Pr«p
Data
/O-S-ftR
/0-S-P,R
IO-5T-PR














-







IMarcxory
Holding
TiBa
\6,
\r.
16,






















1
1

























Cyanida
Prap
Data.










.














1
Cyanide
.Holding
Ti*a









'















                               POFM X - IN
                                                                 7/87
                                  B-118

-------
                               U.S.  EPA - CLP
                                     11
                 INSTRUMENT DETECTION LIMITS (QUARTERLY)
Name:
Coda:
               Analy-f-tca.!
                      Case No.:
CP ID Number:
lam« AA ID Number:   	
urnace AA ID Number: P&3O3O
Contract:
SAS No.:
Data:
SDG No.
1
1
1
lAnalyte
1
| AluaimiM_
j Antimony_
1 Ars«nic
1 Barium
| B^rylliuji
|rii/tBlirH
| Calcium
| Chromium
1 Cobalt
1 Copper
llron
IL«ad
| Magn««ium
|Mangan*s«
1 Mercury
1 Nickel
(Potassium
[S4l«nivm
JSUTMT "
|3oe^i»_
ITtlMll"*
IVansdiom
I Zinc
1
wave-
length
(nm)


iq^.T


^5^.5-

^67.7

.^2^.R

3-9>^,T>


AS3.1
331. C,


35ft.l



513.9

Back-
ground


BZ.








P>Z_












CRDL
(ug/L)
200
60
10
200
5
5
5000
10
50
25
100
5
5000
15
0.2
40
5000
5
10
5000
10
50
20

IDL
(ug/L)


2.0


.T.O

\0

^<

5.0


O.2
MO


10



^0 i

M


E.


£_

P

P

F






£



£.1
1
 nfflents:
                                 FORM XI - IN
                                     B-119
                                                                   7/87

-------
WDOE LABORATORY






    ANALYSES

-------
     GREGOIRE

Director
                                 STATE OF WASHINGTON           ^j

                           DEPARTMENT  OF  ECOLOGY      ""V- •"--lG!l 10
              Posf Office Box 3-46  •  Manchester, Washington 98353-0346  • (206) 895-4740
                                    October  13,  1988
       TO:       Dunne Kama,
                 Environmental  Protection Agency

       FROM:     Bob Car re 11

       SUBJECT:  Ketchikan  Pulp Company.
                 Hydrocarbon  Identification
       Nine samples were received at the Manchester  Environmental Laboratory
       for hydrocarbon  identification.  The method used is  only for semi-
       qualitative determinations of mixtures  rather than individual
       components.

       Samples  350004,  350005,  350014,  390010,  and 390103 all  contained similar
       late eluting compounds with boiling points  generally higher than #2
       diesel oil  (i.e. 680°).   Samples 350004 and 390010's components  were
       attenuated with  respect  to the others mentioned.   In addition to the
       afore mentioned  components, samples 350D06, 350015 and  390106 also
       contained #2 diesl oil and a  series of  early  eluting compounds with
       estimated boiling points  from approximately 100°F to 350°F.

       Sample 350013 contained  only  what appeared  to be a lubricating oil.

       MM/cm
                                        B-120

-------
                                                           m PROGRAMS SECTION
                                                            EM  PiSiQN 10
                 WASHINGTON STATE DEPARTMENT OF ECOLOGY
          ENVIRONMENTAL INVESTIGATIONS AND LABORATORY SERVICES
                          MANCHESTER LABORATORY
TO:       Duane Kama, EPA Region 10

FROM:     Bob Carrell, Chemist

SUBJECT:  Hydrocarbon Identifications on Ketchikan Pulp/Ward
          Cove Sediment Samples
Twenty one samples, collected on August 22 and September 20 and 21,
1988, were received at the Manchester Environmental Laboratory on August
24 and September 22, 1988 for hydrocarbon identification.  All of these
samples contained a cluster of high molecular weight hydrocarbons,
approximately C2Q-C23' wni-cn was not able to be identified.  Samples
350303 and 350302 contained very little of these compounds while the
amount in the rest of the samples varied greatly.

In addition to these samples, 390121, 390120, 350308, 350307 and 350305
also contained detectable quantities of #2 diesel oil.
   Lab Number

     350301
     350302
     350303
     350305
     350307
     350308
     350309
     350310
     350311
     350312
 Ward Cove
Station I.D.

     5-1
     5-3
     5-5
     4-2
     6-1
     6-2
     3-1
     3-2
     3-3
     2-3
Lab Number

  350313
  350314
  350315
  350316
  390117
  390118
  390119
  390120
  390121
  390123
 Ward Cove
Station I.D.

    1-2
    1-1
    2-1
    10-1
    10-0
    20-1
    30-1
    60-1
    20-1
BC:mb
                                B-121

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          APPENDIX C
ADEC FIELD NOTES AND RAW DATA

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                                                   STEVE COWPER, GOVERNOR
DEPT. OF ENVIRONMENTAL CONSERVATION
  Dr.  Harvey Van Veldhuizen,  Project Manager
  Jones and Stokes Associates,  Inc.
  1808 136th PLace, N.E.
  Bellevue, Washington 98005
                                            CERTIFIED MAIL
                                        RETURN RECEIPT REQUESTED
  Dear Dr.  Van Veldhuizen:
                                            November 2, 1988
  re:  EPA Contract NO. 68-02-4381
      Ward Cove Long Term Data Summary

  Enclosed is a brief description of our sampling project, field
  observations, equipment information and an original and backup
  floppy disk containing raw data. Also, please find maps depicting
  observed drogue flow patterns and copies of the Ketchikan
  International Airport Flight Service Station's daily weather
  observations.

  The raw data collected during the long term study is on the
  enclosed floppy in an ASCII delimited file named wardcove.del.
  Commas are used as the field delimiters. The record length is 310
  entries long. The column definitions are included on a table
  which also gives the data type and the length of the characters.
  R-Base was used to create the data tables and to converted them
  into ASCII delimited format. The data has been cross checked with
  field notes to ensure accuracy. Field note narrations for all
  sampling events are included on the floppy in WordPerfect,
  version 4.2. The file name is fieldwrk. A brief introduction to
  the data, methods used for its collection, calibration
  techniques, and additional field observations are contained in a
  WordPerfect file called WCLT.

  You are welcome to phone us with questions on the data or its
  interpretation.

  Sincerely,
  Amy Kruse,
  Ecologist
Alex Viter-i,
Environmental Engineer
  cc: Duane Kama, EPA/Region 10
      Dan Bodien, EPA/Region 10
                               C-l

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 Table:  wc88
 Read Password:  No
 Modify  Password:  No

 Column  definitions
 #  Name     Type
 1  samdate DATE
 2  samtime TIME
 3  transnum TEXT
 4  sitenum TEXT
 5  sitekey TEXT
 6  botdepth REAL
            No lock(s)
 7 tide
 8 temps
 9 tempi
10 temp5
11 templO
TEXT
REAL
REAL
REAL
REAL
12 tempelse TEXT
13 sals     REAL
14 sail     REAL
15 sa!5     REAL
16 sallO    REAL
17 salelse  TEXT
18 dos      REAL
19 dol      REAL
20 do5      REAL
21 dolO     REAL
22 doelse   TEXT
23 notes    NOTE
         Length
              Key    Expression
 2 characters
 2 characters
10 characters yes

10 characters
           4 characters
           4 characters
           4 characters
 Current number of rows:
                305
                           C-2

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                         WARD COVE  1988
                     LONG TERM WATER QUALITY
                          DATA SUMMARY

                          INTRODUCTION

The Department of Environmental Conservation, Southeast Regional
Office completed a long term water quality study of Ward Cove
during the summer of 1988.  This study was conducted as part of
the joint EPA/State Ward Cove Water Quality Assessment Work
Assignment No. 68-02-4381.  Contract negotiations, study design
review and field sampling were completed by Amy Kruse and Alex
Viteri. Water quality sampling occurred during neap tides in the
months of July, August, and September. The dates for each
sampling session were: July 23-27, August 5-10, August 18-24, and
September 12-18.
                             METHODS

The long term study followed the Quality Assurance/Quality
Control program contained in the work plan prepared by Jones and
Stokes Associates Inc., dated July 6, 1988. The QA/QC was
reviewed and approved by both DEC and EPA before field work
began. This study included measurements of dissolved oxygen,
temperature, and salinity at 16 study sites. Study sites on all
transacts are numbered from North to South, low to high. Samples
were taken at four depths, surface, 1, 5, and 10 meters. We
attempted to measure hydrogen sulfide and pH but were unable to
obtain reliable results due to interference with the sampling
technique from significant amounts of rain.
  t
Dissolved oxygen and temperature measurements were taken with a
YSI model 57 dissolved oxygen meter. Salinity measurements were
taken with a YSI model 33 salinity meter. During the first two
weeks of sampling, salinity measurements were not taken at the 10
meter depth because the cable was not long enough. The salinity
value from the 5 meter depth was used again at the 10 meter
depth. Salinity measurements were taken at all depths during the
third and fourth weeks of sampling.

The salinity and dissolved oxygen meters were calibrated each
morning before sampling began. The dissolved oxygen meter was air
calibrated at ambient air temperature right before sampling
started. The DO meter was not adjusted for altitude because all
work was done at sea level. For the first two. weeks of sampling,
dissolved oxygen was measured in a glass of tap water that had
been overfilled for two minutes. A modified Winklers titration
using Hach kit OX-2P was completed on tap water also. The BOD
bottle was overfilled for two minutes and checked for excess
bubbles. The results of the Winklers Hach kit were consistently
2.0-2.5 mg/1 higher than the YSI meter readings. We consulted
with the Hach Company technical staff about this discrepancy-
They said that the PAO reagent was very sensitive to temperature
                             C-3

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changes and could have been harmed by temperature fluctuations in
transport. This would cause over titration of the endpoint. They
advised us to discontinue the measurements until new reagent
could be shipped. We took their advice. The salinity meter was
calibrated every day using a conductivity standard prepared by
the DEC laboratory of 0.7456 grams of KCL/1000 ml double
distilled water. The probe was submerged in the standard and the
measurement was recorded.

We calibrated the dissolved oxygen meter against a winkler
titration and another YSI dissolved oxygen meter model 54A on
August 3, 1988. The YSI model 57A used a hand calculated salinity
value. The model 57 has a salinity correction dial in the meter.
We used aged distilled water, stream water and seawater of 18 ppt
salinity for the calibrations. All winkler measurements were
performed on split samples. The results follow:
                          DO CALIBRATION
a. Distilled water
             MODEL 57A
temperature     22 C
salinity         0
DO              8.6

b. stream water
temperature
salinity
DO
  r
c. seawater
temperature
salinity
DO
MODEL 57A
   16 C
    0
   9.8
MODEL 57A
 16.5 C
  18 ppt
  7.5
               MODEL 57
                 22 C
                  0
                 8.7
MODEL 57
  16 C
   0
  9.8
MODEL 57
 16.5 C
  17ppt
  7.7
                 WINKLERS TITRATION
                       N/A
                        0
                     9.2, 9.2
WINKLERS TITRATION
      N/A
       0
  10.55, 10.58
WINKLERS TITRATION
       N/A
       N/A
    8.2, 8.2
The sampling procedure for all water quality measurements were as
follows; lower probe to sampling depth, measure water
temperature with DO meter, adjust temperature dial on salinity
meter, read salinity, adjust  salinity  on DO meter and read DO.
The DO probe is slowly moved  up and down while measurements are
taken to assure that there is a mixing of the, water  in contact
with the probe membrane. All  measurements were recorded when the
meter needles stopped moving.

KPC assigned a field crew for the entire study to copy every one
of our water measurements. They duplicated our transacts and
depths except for the 10 meter readings. Their gear  was not long
enough for that depth. They grabbed water samples at depth with
sample bottles and brought them to the surface to do the
                             C-4

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readings. They stated that they normally did not work at as fast
a pace as we were able to go, but tried to keep up with us. We
noted that there was agitation of the water samples while they
were measuring for salinity and oxygen values.

drogue study:
Drogues were constructed from 8 inch white styrofoam cylinders
purchased at a near by hardware store. The cylinders were cut
into eight inch wide by 2 inch deep rings. Two rings were  tied
together with fish line so that they had about one foot
separation. Bright yellow field flagging tape was wrapped around
each ring to increase visibility. A 16 inch diameter toy punch
balloon was filled with fresh water and tied onto one of the
rings with sufficient line to allow two feet separation. Please
see attached photo. The drogues appeared to follow surface
currents with minimal wind interference. Maps depicting drop off
and pick up points for the drogues are attached.

weather:
Through out the majority of the study the weather was
predominately cold, with heavy rain fall, dense overcast and
changing high winds. Attached are copies of Ketchikan
International Airport FAA Flight Service Station's daily weather
observations for the months of June, July, August, and
September. Incorporation of the weather information is mandatory
for proper water guality assessment of Ward Cove. Over the first
sampling week, heavy rainfall created a cove freshet. We believe
that water quality data collected during the freshet can be used
as base line of the cove's surface water quality.

stream flow:
Lack of proper field instrumentation made it impossible for us to
measure Ward Creek stream flows. However, visual observations
were made as time and weather allowed. Please see field notes.

transect and study sites:
A map of transect and study sites used during the study is
attached. A video tape of transect end points is also available.
Sample sites used by KPC for their discharge monitoring reports
do not directly correspond to the study sites used in the long
term study. However, many of the sites are the same. See
attached transect/study site map.

log rafts:
The number and size of log rafts stored in Ward Cove changed
significantly during the course of the study^ Through out the
first week of the study, the number and size of rafts in the cove
appeared normal. Starting the third week of the long term study,
which was coincident with EPA's intensive study, the number and
size of rafts in the cove decreased significantly. A video tape
of log rafts contained in the cove during the intensive study is
available. The number or size of log rafts in Ward Cove at during
the last two weeks of our study were less than anytime in the
last eight years  (per. comm. Alex Viteri).
                              C-5

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                         WARD COVE
                           \
- Drogue Sites (Paired)

- Additional Hydrographic
    Stations

- Existing Hydrographic
    Stations
                                                     
-------
  Vh
      rti
                          WARD  COVE
                                               3-7,
                Q /j .-
X
 *
   ^
    •^
     o
      ^
        Vlv
                     K
•
SI
                         I
                                         -  Drogue  Sites (Paired)

                                         -  Additional  Hydrographic
                                             Stations

                                         -  Existing Hydrographic
                                             Stations
                                                    •SOS
Figure  1,  Locations  of  drogue placement and hydrographic stations
          in Ward  Cove  and  Tongass Narrows,
                                 C-8

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                         WARD COVE
                                        - Drogue Sites (Paired)
                                        - Existing Hydrographic
                                            Stations
                                        - Additional Hydrographic
                                            Stations
Figure 1.  Locations of drogue placement and hydrographic stations

          in Ward Cove and Tongass Narrows,
                                 C-9

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•R*
•^
O
W
1

•
SI
/
                                        - Drogue Sites (Paired)
                                        - Additional Hydrographic
                                            Stations

                                        - Existing Hydrographic
                                            Stations
            %.
             Viv
Figure 1,  Locations of drogue placement and hydrographic stations

          in Ward Cove and Tongass Narrows,
                                c-io

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                         WARD COVE
                                        - Drogue Sites  (Paired)
                                        - Additional  Hydrographic
                                            Stations
                                        - Existing Hydrographic
                                            Stations
Figure 1,  Locations of drogue placement and hydrographic stations

          in Ward Cove and Tongass Narrows,
                                 c-n

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                         WARD COVE
               Q/i'.2£>f*i
                                        - Drogue Sites (Paired)
                                        - Additional Hydrographic
                                            Stations
                                        - Existing Hydrographic
                                            Stations
Figure 1,  Locations of drogue  placement  and  hydrographic  stations

          in Ward Cove and  Tongass  Narrows,
                                  C-12

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                                        - Drogue Sites (Paired)

                                        - Additional Hydrographic
                                            Stations

                                        - Existing Hydrographic
                                            Stations
                                                   •sea
Figure 1,  Locations of drogue placement and hydrographic stations

          in Ward Cove and Tongass Narrows,
                                 C-13

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0
 I
             GENERAL DESCRIPTION
               The YSI Model 57 Dissolved Oxygen Meter is intended for dissolved oxygen
             and temperature measurement in water and wastewater applications, but is also
             suitable for use in certain other liquids.  Dissolved  Oxygen is indicated in mg/l
             (milligrams per liter) on 0-5. 0-10 and 0-20 mg/l scales. Temperature is indicated
             in °C on a -5° to +45°C scale. The dissolved oxygen ranges are automatically
             temperature compensated for solubility of oxygen in water and permeability of
             the probe membrane, and manually salinity compensated.
              The probes use Clark-type membrane covered  polarographic  sensors with
            built  in thermistors for temperature measurement and compensation. A thin.
            permeable membrane  stretched over the sensor isolates the sensor elements
            from  the environment, but allows oxygen and certain other gases to enter. When
            a polarizing voltage is applied across the sensor, oxygen that has passed through
            the membrane reacts at the cathode, causing a  current to flow.
              The membrane passes oxygen at a rate proportional to the pressure difference
            across it. Since oxygen is rapidly consumed  at the cathode, it can be assumed
            that the oxygen pressure inside the membrane is zero. Hence, the force causing
            the oxygen  to diffuse  through the membrane is proportional to  the  absolute
            pressure of oxygen outside  the  membrane.  If the  oxygen pressure increases,
            more oxygen diffuses through the membrane and more current flows through the
            sensor. A lower pressure results in less current.
SPECIFICATIONS
  I.  Instrument
     Oxygen Measurement
     Ranges: 0-5, 0-10 and 0-20 mg/l  (0-2.5, 0-5 and 0-10 mg/l with YSI
       5776 High Sensitivity Membrane)
     Accuracy:  ±1% of full scale at calibration temperature (±0.1 mg/l on 0-10
       scale), or 0.1 mg/l (whichever is larger).
     Readability:  .025 mg/l  on 0.5  scale: .05 mg/l on 0-10 scale;  0.1 mg/l
       on 0-20 scale.

     Temperature Measurement
     Range:  -5° to f45°C
     Accuracy:  ±0.5°C  plus probe which is ±0.1 °C
     Readability: 0.25°C

     Temperature Compensation
     ±1% of D.O. reading for measurements made within ±5°C of calibration
     temperature.
     ±3% of D.O.  reading over entire range of -5 to +45°C probe temperature.

     System  Response Time
     Typical  response for temperature and D.O. readings is 90% in  10  seconds
     at a  constant temperature of 30°C with YSI  5775  Membranes.  D.O.
     response at low temperature  and low D.O. is typically 90% in 30 seconds.
     YSI 5776 High Sensitivity Membranes can be used to improve  response at
     low temperature and low D.O. concentrations. If response time under any
     operating conditions exceeds two  minutes, probe  service is indicated.
    Operating Temperature  Range
    Instrument and probe operating range is -5° to +45°C. Large ambient
    temperature changes will  result in 2% loss of accuracy unless Red Line and
    Zero are reset

    Recorder Output
    0 to 114-136 mV.  Recorder should have 50.000 ohms minimum input im-
    pedance.

    Power Supply
    The YSI Model  57 is powered by two disposable  "C" size carbon zinc
    batteries (Eveready 935C or equal) providing approximately  1000  hour
    operation.

 II. Probe
    Cathode:  Gold
    Anode: Silver
    Membrane:  .001" FEP Teflon
                ( 0005" FEP Teflon available)
    Electrolyte Half saturated KCI
    Temperas Compensation: (See SPECIF.CATIONS, I. Instrument)
    Pressure Compensation:  Effective 1/2% of reading w.th pressures to 100
      psi (230 ft. sea water)
    Polarizing Voltage: 0.8 volts nominal
    Probe Current:  Air at 30°C =  19  microamps nominal
                  Nitrogen  at  30°C =  .15 microamps or less

III. Accessories  and Replacement Parts
    YSI 5720A — Self Stirring  BOD  Bottle Probe
    YSI 5750—  Non Stirring BOD Bottle Probe
    YSI 5739 —  Oxygen  Temperature Probe for field use. Combine with one of
                the following 4 cables for desired lead length:
                Detachable leads for use with YSI  5739:
                YSI 5740-   10       10' Cable
                YSI 5740-  25       25' Cable
                YSI 5740-  50       50' Cable
                YSI 5740-100      100' Cable
                YSI 5740-150      150' Cable
                YSI 5740-200      200' Cable
    YSI 5721 —Battery and  charger pack operates  YSI
               Submersible  Stirrers.
    YSI 5791A — Submersible "Stirrer for  field use.
    YSI 5795A — Submersible Stirrer.
    YSI  5075A — Calibration Chamber for use with field probe,
    YSI 5890 — Carrying Case.
    YSI 5775 " Membrane and KCI Kit,  Standard  —  includes 2 each 15-
               membrane packets (.001" thick  standard membranes) and  a
               30 ml bottle KCI with Kodak photo flo.
    YSI 5776 — Membrane and KCI  Kit.  High Sensitivity — includes 2 each
                1 5-membrane packets (.0005" thick membranes) and a 30 ml
               bottle KCI with Kodak photo flo.
    YSI 5680 — Probe Reconditioning Kit
                                                                                                                                             5791A and  5795A

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               FIELD NOTES FOR THE LONG TERM STUDY
  REVIEW OF NOTES IS IMPORTANT FOR PROPER DATA INTERPRETATION

NOTES FOR 7/23/88:
10:00 am  The weather is cloudy, steady rain with approximately
20 mph winds from several directions at once. Wind gusts to 35-40
mph. Yesterday was partly cloudy with only minor showers. High
tides for 7/23/88 are 9.6 at 8:24 am, 13.2 at 8:11 pm. Low tides
are 3.1 at 2:04 am and 5.4 at 1:45 pm.


NOTES FOR 7/25/88;
12:00 pm. new batteries for both DO meter and salinity meter.
Calibration of the salinity meter; temperature of water is 18 C,
salinity is 1 pp thousand, conductivity read on the X 10 scale.
Meter reading is 130 x 10. Calibration of DO meter; new membrane,
air calibrated meter, measured DO in tap water with the YSI meter
and a Hach dissolved oxygen modified field kit. Tap water
temperature is 21.5. YSI reading on 0-10 scale - 7.8. Air
temperature is 20 C. Hach kit reading on tap water was 11.0.

2:15 pm  Set the drogues out by the effluent outfall boom
approximately 30 feet from the boom. Drogue A is even with the
secondary treatment facility, drogue B is across from the
effluent pipe. Kurt Mueller and Steve Eilertson are sampling for
KPC again.
High tide is at 11:06 am low tide is at 4:14 pm.
 (Rain fall for this period is very heavy and long in duration.
Please reference FAA's daily weather charts.)

NOTES FOR 7/27/88;
  t
We  are using the District office's salinity meter. Calibration  of
salinity meter with standard; standard temperature 18 C, salinity
of  standard 0.5, conductivity on X 10 sale is 130. Calibration  of
DO meter; air temperature 21.5, meter reading is 9.3, calibrate
to  8.8. Compare DO readings of tap water with YSI meter and Hach
modified winklers test kit. Tap water temperature 17 C. YSI
reading is 10.1. Hach kit reading is 12.

Set drogues out at 10:45 am. Used same locations for A and B as
7/25 except they were approximately  40' out  from effluent log
boom because a barge was being  loaded. Its engines were running
and effecting the surface currents. Weather  is dry, some sunshine
this a.m., about two hours. Now  its  overcast. Rain decreased in
last 24 hours. Wind  is very gentle. Air temperature is 15 C.
Drogue C is dropped by mouth of  creek  in  line with telephone pole
on  transect one and the log boom by mill. Drogue B is at transect
three station one at 1:25. Drogue A  probably went  into log boom
area by north side of cove at effluent outfall. Took photos  of
stream at 2:30 pm. No fish or fishermen observed. No  rain this
pm.  High tide at 12:47 pm 13.1', low  tide at  6:10 pm 3.7'.
                             C-15

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NOTES FOR 8/5/88;
Air calibration of the DO meter to 22.5 C, meter reading is 8.2,
calibrated to TABLE I value of 8.6. Thermometer reading  for room
temperature is 23 C. Calibration of salinity meter using
conductivity standard made up by Lab. Salinity of standard is 1.5
pp thousand, conductivity on the X 10 scale is 125 micro mhos.
Recalibrated the DO meter to the outside air temperature of 19 C.
Calibrated to 9.26 from TABLE I.

4:00 pm drogue A is released by effluent outfall at site 43.
Drogue B is released in line with the secondary treatment
facility. Gas bubbles are rising in this area a lot. Weather is
high overcast without rain about 60-65 F. Wind is blowing WNW.
4:30 pm drogue A about 70' off of the log boom by effluent
outfall. Drogue B is in middle of log rafts with the diesel tank
on it.
5:00 pm released drogue C at stream mouth. Wind blowing east.
6:00 pm no wind, water is smooth as glass. Drogue C is even with
the stairs going down to the boom shack, in the middle of the
cove.
8:20 pm Drogue A in center of cove midway between transect 2 and
3 and across from the diesel tank. Drogue C is caught on the
upstream side of a log boom across from the log bundle lift
approximately 30' inside the end of the boom. Can't find B.
Air calibrated the DO meter at end of sampling, 8:30 pm. Air
temperature is 13.5 C, meter reading 7.1, calibrated to 10.4 from
TABLE I.

7:30 pm talked to Kurt Muller and Steve Eilertson. They were also
getting low DO values on bottom by stream mouth (3.3 ppm) and the
surface by the effluent outfall and boom shack. They also skipped
some sites in order to keep up with us. The water from our boat
wake is really foaming and the foam is persistent for a long
time. Kurt said that he didn't have his map with him so his
sampling locations were different from the established ones.

Low tide is 12:55 pm at 4.3', high tide is 7:32 pm at 14.3'.


NOTES FOR 8/6/88
11:40 am Kurt Muller and Suong Yu(?) are sampling for KPC. Suong
has never sampled before. High overcast with very vague shadows.
About 65 F, very calm. Smoke from mill stacks is going straight
up. Air calibration of DO meter; temperature^of air is 20 C, DO
reading on 0-10 scale is 12.0. Let machine sit for 20 minutes to
equilibrate. Calibrate to 9.07 from TABLE I. New membrane for DO
meter.

Released drogue A at outfall at 12:05 pm. Only have two drogues
today. Gas bubbles are still coming up by outfall. Seagulls  and
eagles feeding on fish on surface. Drogue C released across  from
bulkhead in line with stream mouth at 12:15. Drogue C was found
                             C-16

-------
almost against the shore at bulkhead at 12:40. Drogue A is no
where to be found at 1:15.
3:30 Drogue float spotted hanging from dead tree in the boomed
off area of the effluent discharge area. They were hanging about
3' above the water at low tide. Don't know which drouge they are-
can 't get to the site. 4:30 drogue C found aground near bulkhead
towards the road.

Surveyed Ward Creek just above where the stream enters the tide
pool area. The stream bottom substrate was predominately bedrock
with cobble, rubble and boulders on top. The average depth was 3-
4" with some 6-8" areas. The small falls area has a drop of 10-
12". Three widths were taken in a 200' span moving upstream from
the small falls area. The widths were 65', 83' and 96'.  The
stream temperature was 16 C. Three DO reading were taken across
the stream, they are 8.7,8.8 and 8.8. The stream flow has changed
dramatically since the last field trip in July. In July, after
heavy rains for several days straight, the small falls into the
tide pools had a drop of 2.5', and the stream was running bank
full. The July stream survey was done at low tide. At that time
stream flow was so fast that had a person fallen into the water
they could not have recovered in time to get to shore.
NOTES FOR 8/8/88

2:00 Air calibration of the DO meter; 15.5 C air temperature,
meter read 9.8, corrected to 9.9 mg/1 from TABLE I. New membrane
for the probe. Calibration for the salinity meter; meter reading
22 C, salinity of standard is 1.4 pp thousand, conductivity
reading is 145 micro mhos.

Weather on Sunday was very windy with lots of rain. Weather on
Monday is very similar, perhaps not as much wind and rain as
Sunday. 3:00 pm rain stopped. Wind is WSW at about 10 mph. Still
low overcast clouds.

Drogue A is released by effluent outfall 3:00 pm. Drogue B is
released by secondary treatment facility at 3:05 pm. Started
sampling at (KPC's) reference stations (50 and 51 outside Ward.
Cove) so that we could be by the stream mouth at low tide.

                               3:30 pm waves coming into Ward
Cove from Tongass Narrows 8-12" high. Dropped drogue C off at
stream mouth at 4:25 pm. Drogue A is along shore by pilings at


                              C-17

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stream mouth at 4:30 pm. Drogue B is along effluent boom heading
toward anchored barges at 4:30 pm. Drogue C is in raid-cove by
diesel tank across from grey warehouse at 5:00 pm. Drogue C was
found at the diesel shack in middle of cove. Drogue B is next to
effluent boom close to barges. Drogue A was caught under rocks by
dock next to outfall, it lost one of its floats.

NOTES FOR 8/9/88;
Weather is dryer - not much rain, moderately low hanging clouds.
Wind from SSW at 15-18 mph. Occasional (higher) gusts. Light
rain. While outside Ward Cove, at KPC's sample site 51, near
float plane ramp, currents were pushing boat out while wind was
heading in. New batteries for both salinity and DO meter, new
membrane for DO meter. Air calibrate DO meter; 16.5 C, meter
reads 11.2, calibrate to 9.75 mg/1 from Table I.

2:15 pm Drogue C is released by effluent outfall. 2:45 pm drogue
C is picked up close to dock by effluent outfall. It was about to
go under the dock face. 2:45 released drogue on line with
transect 3 perpendicular to study site two on transect two.
Drogue A from Saturday is found between the two barges along the
NW shore. Drogue A from last trip was found wrapped around a
cable inside of the effluent foam boom. 6:00 pm drogue C is
located at effluent outfall, it made a circle in last 1.5 hours.
Gas bubbles coming up by effluent outfall again, they seem more
prevalent at low tide.

Tides today; low 5:46 pm at 4.7 feet, high 12:20 pm at 12.2 feet.


NOTES FOR 8/10/88:

2/25 pm Weather is partly cloudy approximately 65  (degrees F). No
rain last night. Wind SW at 3-5 mph. Lots of brown color in the
water, even at the reference points. Our boat wake creates lots
of foam and is very persistent. Seems to be worse than yesterday.
New membrane for DO meter. Air calibrated the DO meter.

2:25 pm released drogue A at a point on transect 3, perpendicular
to transect 2, study site 2. 2:40 pm released drogue C at
transect 1 study site 1. Drogue C was found at 5:10 pm up on  a
rock behind pilings at creek mouth by sawmill floating dock.
Drogue A was found at 5:15 pm about 200 feet north of first site
on transect 2 in between two barges. It moved counter clockwise
inside log booms and along side the big dock.

I think the DO values have dropped during the 4 hour sampling
period today. May be due to the sun's warmth?

Tides today; low at  6:28 pm, high at 1:01 pm 13.0  feet.
                             C-18

-------
NOTES FOR 8/20/88: JOINT LONG TERM & INTENSIVE STUDIES UNDERWAY;

11:30 am Weather is high clouds, very scattered showers, wind is
from NE. Water is flat calm. Deploying the productivity buoys to
measure primary productivity and the mini-ranger floats. We
sampled KPC reference sites (No. 50 and 51 outside Ward Cove),
then transect 4, transect 1, transect 2, transect 3. Sampling was
conducted in this order because of boat and barge activity in the
area. The KPC crew sampled transect 3 right after transect 4,
around 2:00-2:30 pm. KPC crew is taking samples off of the stern
of their big boat, the Tongacell. The samples may be effected by
the boat propellers- increase in DO?

At the fifth site on transect 3 we noticed that the particles on
the very surface were moving towards the creek while those
approximately five inches down were moving out of the cove. The
salinity on the top one inch was 15 ppt, and five inches down was
20.5 ppt.

Air calibration of the DO meter on 0-20 scale. Meter reading was
11.0 mg/1 at 15 C. Calibrated meter to 10.07 mg/1 from Table I.
We started sampling at the reference sites and moved in toward
the stream. Tides today; low at 11:50 am 5.0 feet, high at 6:14
pm 13.2 feet.

NOTES FOR 8/21/88:

Weather is high overcast and wind has picked up on outside
reference points. Started sampling at the reference stations at
11:15 am from the Curlew with the Kinnetics crew taking identical
samples with their CTD at the same time. The KPC Tongacell is
also running their samples along with ours. We  (Amy Kruse and
Alex Viteri) started sampling from the 10 meter deep study site
to let the surface waters equilibrate as long as possible after
boat disturbance. We are sampling from the starboard bow of the
Curlew.  (Alex Viteri is locating the Curlew over established
study sites)

DO meter calibration at 16 C, meter reading 9.2 calibrate to 9.85
mg/1 from Table I. We completed sampling KPC reference sites
 (No.50 and 51 outside Ward Cove), transect 6, transect 4 and site
one on transect three. The DO meter is giving very low readings.
We had a lot of hydrogen sulfide gas bubbles at the effluent
outfall station,  site one on transect 4. We changed the membrane
and re-calibrated the DO meter at 2:40 pm. at_ 15.5 C. The meter
was reading 7.7,  calibrated to 9.9 mg/1. We re-sampled all study
sites again. We will not use the data from the  first sampling
period.

Tides today; low  12:56 pm at 6.0 feet, high 7:22 pm at  12.9  feet.
                             C-19

-------
NOTES FOR 8/22/88;

Weather was high  clouds with  some blue  patches. We  (Amy Kruse  and
Alex Viteri onboard the AFF&G skiff)  started  sampling  at  the
creek with the  Tongacell  right beside us.  Beth  Power from EVS
consultants is  aboard  the Tongacell  to  observe  their procedures.
Alex and I had  a  meeting  with several KPC  people; Hagen,  Higgins,
-Steve Eilertson,  Soung Yu and Beth Powers.  They asked  about what
the intensive study was doing. We explained it. We  talked further
about what our  results had been  so far  for water quality.  We
explained that  we had  some consistent depression of DO at the
surface and that  there were locations by the  stream that  were
very depleted of  oxygen.  Hagen asked the KPC  field  crew if their
results were similar.                           Hagen  asked to
meet with Kinnetics and Larry Larsen to discuss our studies. We
said we would pass the request along. Beth asked to be allowed to
come aboard the Curlew to assess the gear  and techniques  for
sampling. She was allowed to  come aboard and  help sample  for
awhile.

We re-air calibrated the  DO meter after the first transect
because we were worried about interference from hydrogen  sulfate
and its effects on the membrane  at the  site by  the  stream with
the really low  DO values. The DO meter  was perfectly calibrated
with the Table  I  values.  Our  readings on the  surface were very
depressed, mostly 5-6  mg/1. About 60 %  of  our DO values were
below  6 mg/1, violations  of the  Water Quality Standards.

Tides  today; low  2:32  pm  6.3  feet, high 9:31  pm 9.7 feet.
 NOTES FOR 8/23/88:

 Easterly winds,  clear skies today for most of the day.  Air
 calibrated the DO meter at 19.5 C,  meter reading 8.7  mg/1,
 calibrated to Table I value of 9.17 mg/1.

 Tides today;  low 3:58 pm 5.7 feet,  high 10:48 am 10.9 feet.
 NOTES FOR 8/24/88:

 Weather is dry and  partly cloudy-  We did not sample all of the
 study sites today because we had an early morning meeting with
 KPC,  Kinnetics and  Larry Larsen, and we had to catch an early
 afternoon plane.

 Air calibration of  the DO meter at 17 C, meter reading 9.0 mg/1
 calibrated to 9.65  mg/1 from Table I.

 Tides today;  low 5:03 pm 4.3, high 11:41 am 12.4.


                              C-20

-------
NOTES FOR 9/13/88:

Weather is low, heavy overcast skies. Winds shifting from N to SE
and increasing from 15 to 20 mph. Heavy drizzle.

Air calibrated the DO meter at 13 C. Meter reading 15.2 mg/1,
calibrate to 10.52 mg/1 from Table I.

Tides today; low 8:28 am 0.6 feet, high 2:39 pm 15.6 feet.


NOTES FOR 9/14/88;

Weather was sunny in the morning, started to cloud up about noon.
Water is calm. We (Amy Kruse and Alex Viteri) sampled some study
sites out of order because there was a lot of log raft movement
today and they were in the way. KPC crew did not sample today
because they could not use the Tongacell and did not want to use
the generator in the rain.

Air calibrated the DO meter at 15.5 C. Meter is reading 9.1 mg/1,
calibrate to 9.9 mg/1 from Table I.


NOTES FOR 9/16/88;

Weather is clear with some high clouds. Wind blowing hard 20 mph
frpm the Northwest. Scot Menzies is running the boat today for
our crew, Alex Viteri is operating the instruments.

Air calibrated the DO meter at 15 C. Meter reading 9.9 mg.l re-
calibrated to 10.07 mg/1 from Table I.


FIELD NOTES FOR 9/17/88;

Weather is partly sunny today. Yesterday was sunny with strong
Northern winds. The inner cove is calm, the outer cove has wind
driven waves. We are sampling from the Tongacell today because
our salinity meter is broken and we are using their's. It is the
same model, a YSI 33.  (Alex Viteri is guiding the Tongacell
skipper to our sample sites and Amy Kruse is operating the
instruments.)

Air calibration of the DO meter at 15.5 C. Meter reading  12.4
mg/1, re-calibrated to 9.95 mg/1 from Table I.

We did not sample the third site on transect one because  the
Tongacell can't get in there.
                             C-21

-------
12:10 pm We are noticing a lot of grey pulp in the water
throughout the cove. We suspect the pulp mill emptied their high
density tanks into the cove. Also, there are a lot of gas bubbles
coming up by study site one on transect two.

12:50 pm Study site two, transect three. We re-air calibrated the
DO probe to see if the high concentration of pulp fibers in the
water has effected the probe. Air temperature is 16.8 C, meter
reading 9.8 mg/1, Table I value is 9.7 mg/1.

Tide today; low 10:29 am at 4.6 feet, high 4:41 pm at 14.0 feet.
                             C-22

-------
TEMPERATURE              SALINITY            DISSOLVED OXYGEN
MONTH
7
7
7
7
7
7
7
7
7
7
7
7
7
7
0 7
1 7
M 7
OJ 7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
DAY YEAR HOUR MINUTE STATION DEPTH
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
25
25
25
25
27
27
27
27
27
27
27
27
27
27
27
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
11
11
12
12
12
12
12
12
12
1
1
1
1
1
11
11
10
10
2
2
2
2
10
11
11
12
12
12
11
11
11
11
12
30
45
0
10
20
30
40
45
50
0
10
15
30
40
0
15
25
45
40
40
45
55
55
5
50
0
po
25
10
30
40
45
50
21
23
24
25
31
32
33
34
35
43
42
41
55
51
13
22
11
12
11
12
13
21
11
12
24
25
31
32
13
21
22
23
42
17
48
51
90
25
90
90
0
90
0
75
0
0
0
9
35
30
27
29
0
10
31
30
0
0
38
999
999
0
39
40
999
999
TIDE (surf.)
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
outgoing
14
14. 5
15
14.5
15
14 .5
14
14
14.5
14.5
14.5
14.5
14
14
15
14
15
15
13
13
13
12.5
13.5
13.5
13.5
14
14
14.5
13.5
13.5
13
13
14
(1 m)
14
14
14.5
14
14. 5
14 .5
14
14
14
14.5
14.5
14.5
14
14
14.5
14
15
14.5
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13.5
(5 m)
13
13
14
13.5
13
14
13.5
13.5
13.5
13
13.5
13.5
13.5
13.5

14
13
13
12.5
13
13
13
13
13
13
13
12
12.5
13
12.5
12.5
12.5
12
(10 m)

12
12
12.5
13
14
13
12
12
12
12
12
13.5


12
12
12.5
12
12

12
11.5
11.5
11.5
11.5
11.5
11.5

11.5
11
11.5
11.5
(surf.)
22.5
21
22.5
23
20.5
22
23
24
24
23
23
23
22
22
22
22.5
17
22
5
8
3
9
7
1
8
16
9
20
2
19
21
5
21
(1 m)
22
23
23
23.5
23
24
23.5
24.5
24
23.5
23.5
23
23
23
23
23
23
23
9
13
8
17
23
22
23
.23.5
23
22.5
22
22.5
23
22
23
(5 m)
24
24
23
24.5
25
25
24
24.5
24
25
24
24.5
23
25.5

23
23
24
25
23
23
21
23
23
23.5
24
23
23
23
23
24
24
23.5
(surf.)
6
6.1
6
6.6
6
6
5.8
5.9
6.2
6.3
6
6.5
6.4
7.4
5.7
6
7
5.7
9.2
8.9
9.1
7.9
8.8
10.1
7.3
7.5
7.7
7
10.2
8.3
7
8.8
6.7
(1 m)
6.7
6.5
6
7.1
6
5.8
6.3
6
6.7
6.5
5.8
6.5
6.5
7.4
6.4
6.4
5.7
6.2
9
8.2
3.5
7.5
8.1
8.3
8
8
7.1
7.4
8.3
7.5
7.4
7.9
6.8
(5 m) (10 m)
4.9
6.4
7.1
7.6
6.5
6.8
7.4
7.4
7.7
7.5
7.4
7.1
7.7
8

6.2
7.8
7.2
7.7
7.6
6.7
7.6
7.5
7.9
7.8
7.5
7.2
7.3
7.5
7.1
7.2
7.9
7.5

7.8
6.4
8.1
6.8
7.7
7.6
8
8.2
8.1
7.8
7.7
8.2


7.6
1.5
3.7
4
3.5

6.7
5.7
6.4
6.7
7.2
7.6
7.5

6.2
6.5
6.9
7.8

-------
TEMPERATURE              SALINITY            DISSOLVED OXYGEN
MONTH
7
7
7
7
7
7
7
8
8
8
8
8
8
8
0 8
1 8
M s
Jx^
^ 8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
DAY YEAR HOUR MINUTE STATION DEPTH
27
27
27
27
27
27
27
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
6
6
6
6
6
6
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
12
1
1
12
12
12
12
5
5
5
5
4
4
4
4
6
6
6
7
7
7
7
7
5
6
6
6
12
12
12
1
2
1
55
5
10
20
15
10
45
25
30
35
45
25
15
45
50
25
15
10
5
15
30
40
50
50
0
45
35
25
35
50
5
0
50
43
55
51
33
34
35
41
22
21
23
24
11
36
12
13
33
34
35
41
42
43
51
50
25
26
31
32
11
13
21
22
32
33
999
999
999
999
999
38
75
41
999
89
999
21
100
999
12
999
999
29
100
999
999
999
999
999
999
33
999
27
7
999
999
999
999
TIDE (surf.)
outgoing
outgoing
outgoing
incoming
incoming
incoming
slack
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
slack
slack
outgoing
incoming
incoming
incoming
incoming
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
13.5
14
14
14
14
14
14
15
15
15
15
15.5
16
15
15.5
15
16
16
15.5
16
15.5
15
15
15
15.5
15.5
15.5
15
15
15
15
15
15
(1 m)
13
13.5
14
13
13
13.5
13
15
15
15
15
15.5
15.5
15.5
15.5
15
15
15
15.5
15.5
16
15
15
15
15
15
15.5
14.5
14
14
13.5
14
14
(5 m)
12
13
12.5
12.5
12.5
12
12
14.5
15
14
15
14
14.5
14.5

14
14.5
14
14
14.5
14
13
14
14
14.5
14
14
13

13
12.5
13
12.5
(10 m)
11.5
12
11.5
11.5
11.5
11.5
11.5
12
12.5
12
12.5

12
12

12
13.5
12
12
12
12
12
12.5
12
12
12
12
12

12
12
11.5
12
(surf.)
20
22.5
21
22
17
17
14
12.5
20
19
19.5
9
19
19
10
20
20
17.5
20
19
20
20
21
20
20
20
20
20
19
19
19
20.5
20.5
(1 m)
23
23
23
22.5
24
23.5
23
20
20
20
20
20
19
20
20
20
20
20
20
21
20
21.5
21
20
20
20
20
21
21.5
22
22
21.5
21.5
(5 m) (surf.)
24
24
24
23.5
25
24
24
21.5
20
20
20
20
21.5
20

21
21
21
21
21
21
21.5
21.5
21
20
21
21
23.5

24.5
24
25
25
7.3
7.6
7.4
7.5
7
7
7.7
5.4
5.4
5.3
5.3
6.8
6.4
5.6
6
5.2
5.3
5.2
5.5
5.2
5.6
6
6
5.6
5
5.1
5.4
5.1
5.4
5.1
5.6
5.7
6
(1 m)
7.7
7.4
7.8
7.9
7.7
7.6
7.6
5.9
5.8
5.5
5.6
6.6
6.5
6
5.5
5.4
6.3
6.3
5.7
5.7
5
7
6.3
6.8
6.5
5.1
5.9
6
5.4
6
6.5
5.4
6.4
(5 m) (10 m)
7.4
7.8
8
7.9
7.8
8
7.4
6.6
6.2
6.7
8.1
7.2
7.2
7.4

7.7
7.6
7.5
6.1
8.3
6.8
7.5
7
7.8
7
5.8
6.3
6.8

7.1
8.3
7.7
8.2
7.7
8.2
8.2
6.6
8.2
7.5
7.9
7.3
6.4
6.6
6.9

7.4
3.8

7.1
7.1
8.5
6.1
9.1
8
8.4
8
7.7
6.7
5.1
7.4
2.7

4.5
4.4
7.5
6.3

-------
TEMPERATURE              SALINITY            DISSOLVED OXYGEN
MONTH
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
0 8
tli 8
S 8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
DAY YEAR HOUR MINUTE STATION DEPTH
6
6
6
6
6
6
6
6
6
6
6
6
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
1
1
2
2
3
3
12
2
1
2
1
1
4
4
5
5
5
5
5
5
3
3
4
4
6
4
4
5
5
5
3
3
3
45
40
50
55
10
20
30
55
30
5
15
20
15
45
15
20
30
40
45
50
50
55
5
10
0
30
,55
0
5
10
20
30
40
34
35
41
43
50
51
12
42
25
31
23
24
34
22
11
12
13
14
15
16
41
31
32
33
17
35
21
23
24
25
50
51
43
999
27
999
999
999
999
9
0
40
24
999
999
100
32
28
27
6
20
17
17
999
25
999
999
8
28
32
999
53
40
999
999
999
TIDE (surf.)
outgoing
outgoing
outgoing
incoming
incoming
incoming
outgoing
incoming
outgoing
outgoing
outgoing
outgoing
outgoing
slack
incoming
incoming
incoming
incoming
incoming
incoming
outgoing
outgoing
outgoing
outgoing
incoming
outgoing
slack
incoming
incoming
incoming
outgoing
outgoing
outgoing
15.5
15.5
15.5
15
14
15
15
15
15
15.5
13 .5
15
13.5
14
13.5
13
13.5
13.5
13.5
13
14.5
14
13.5
13.5
13.5
14
13. 5
13.5
13
13.5
14
13.5
14
(1 m)
14
13
15
14.5
14
14.5
14.5
14
14
14.5
13
14
13.5
13
13
13.5
13.5
13
13
13
14
13.5
13.5
13
13
13.5
13
13
13
13.5
13
13.5
14
(5 m)
13
12.5
13
13
12
13

12
12
13
12
12.5
13
13
13
13

13
13
13
13
12.5
13
13

13
13
13
13
13
13
13
13
(10 m)
11.5
12
11.5
11.5
12
12

12
11.5
12
11.5
11.5

13






13

13
13


12.5
13
13
13
13
13
13
(surf.)
20
20.5
21
21
22.5
21.5
17.5
21
19
20
20.5
19
11
14
10
7
8
7
7
7
21
12
16
15
10
12
11.5
8.5
8
10
19.5
23.5
19
(1 m)
22
24
21.5
21.5
22.5
21.5
21
21. 5
21.5
21
22
21.5
22
22.5
24
12
22
22
23
22
22
20.5
22
21.5
23.5
21
22.5
23
21.5
22
23
23.5
21.5
(5 m) (surf.)
24.5
25
25
24
24
23

24
25
24
25
25
24
24
24
24

24
25
25
24
26
23.5
24

24.5
24
24.5
24
24
24
24
24
5.5
5.4
5
5.5
7.7
6.3
5.8
5
4.8
4.8
6.2
5.7
7
6.5
7.4
7.5
6.8
6.9
7.2
7.5
6.8
7.6
7.3
6.7
6.8
6.8
6.9
6.8
6.7
7.5
7.8
7.5
7.2
(1 m)
6.6
6.5
5.4
5.7
7.4
7
5.9
6.8
5.1
6.2
6.8
5.7
6.4
6.5
6.2
6.6
5.8
5.4
5.4
6.3
7.4
7.3
6.6
6.5
5.6
6.3
5.8
6.4
6.5
6.6
8.2
7.7
7.4
(5 m)
9
8.8
6.8
8.1
7.7
7.8

7.8
8
7
7.7
8.7
7.5
7.2
4.3
6.6

5.1
6.4
6.2
9.1
6.2
7.4
7.7

7.4
6.4
7
7
7
9.4
10
9.4
(10 m)
9.7
7.7
7.5
8.2
8.6
8.3

7.3
6.5
5.5
5.4
5.6

6.4






10.3

7.9
8.4


5.6
7.7
7.7
7.4
10.8
11.2
10.6

-------
TEMPERATURE
                         SALINITY
                                             DISSOLVED OXYGEN
MONTH
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
0 8
1 8
NJ n
Ch 8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
DAY YEAR HOUR MINUTE STATION DEPTH
8
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
10
10
10
10
10
10
10
10
10
10
10
10
10
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
3
4
4
5
3
3
3
3
3
3
3
3
3
3
4
4
5
5
4
5
3
4
3
4
4
2
3
3
3
3
3
3
2
45
30
35
5
0
10
15
25
30
35
40
45
50
55
15
40
10
20
45
30
40
10
45
35
50
55
, o
10
15
20
25
50
45
42
22
23
12
51
50
41
42
43
35
34
33
32
31
21
25
13
14
24
15
21
34
31
41
50
12
13
25
24
23
22
32
11
999
32
54
19
999
999
999
999
0
28
999
999
999
25
32
999
6
8
44
4
32
100
27
100
39
999
11
45
36
999
999
100
29
TIDE (surf.)
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
slack
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
outgoing
15
14
14
13.5
13.5
14
14.5
14
15
14
14
14
14
15
13
13.5
14
13.5
14
14
15.5
14.5
15.5
16.5
15
14
14.5
14.5
15
15
15
16
14
(1 m)
13.5
13.5
13.5
13 .5
13.5
13 . 5
14
14.5
14
14
13.5
14
13 .5
13
13
13.5
13
13
13.5

14
14
14
14.5
14
14
14
14
14
14
14
14
13.5
(5 m)
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13


13

13
13
13
13
13
13

13
13
13
13
13
13.5
(10 m)
13
12.5
12.5

12.5
12.5
12.5
13
13
13
13

12.5
13
12.5
13


12.5

13
13

13
12.5


13
13
13
13
13
12
(surf.)
11
9
9
6
24
21.5
13
13 .5
20
11
12.5
11
10.5
10.5
10
11.5
8
11
10
1
13
17
21
15
23
5
11
12
16.5
12
15
20
5.5
(1 m)
22
13
22
15
24.5
22.5
22
22.5
22.5
22. 5
23
23
22.5
23
22
23
19
19
21.5

20
21
23
22
24
22
22
17
22
22
21.5
21.5
19
(5 m) (surf. )
24.5
25
24
25
25
25
25
24.5
25
25
24.5
25
25
25
25
24


24.5

25
24
24.5
24
25
24

24
24
24
24.5
24
22
7.4
7 .8
8.2
8.7
8
8.2
7.5
7.6
7.4
7.8
7.5
7.8
8.2
7.4
7.7
7.2
7.7
7.5
7.8
9.2
7.4
6.5
6.5
6.2
7.8
8.9
8.3
7
6.4
7.2
7.5
6.6
7.2
(1 m)
8
6.8
6.4
7.5
8.2
8.4
6.8
6.6
6.8
6.7
7.4
6.5
6.9
6.6
6
6.2
6.7
7
6.4

6.7
6
6.8
6
7.8
6.4
6.4
6.6
6.2
6.8
6.9
6.5
6.8
(5 m)
9.8
6.6
6.3
6.2
8.2
8.2
7.2
7.5
7.6
7.5
7.4
7.5
7.3
6.7
6.4
6.5


6.4

6.7
7.2
7
7.3
7.7
6.8

7.4
7.2
7.3
6.4
6.8
6.4
(10 m)
10.6
5.4
7

8.4
7.9
7.8
8.1
8
6.5
7.6

7.2
5.5
4.9
6.2


6.8

5
7.5

6.5
7.4


7.4
7.4
7
5.9
6.6
0.75

-------
                                                             TEMPERATURE              SALINITY            DISSOLVED OXYGEN
 MONTH DAY YEAR HOUR MINUTE  STATION DEPTH   TIDE   (surf.)  (1 m)   (5 m)  (10 m)  (surf.)  (1 m)   (5 m)  (surf.)  (1 m)  (5 m) (10 m)
    8   10    88     4     25        43   999 outgoing   15.5     15      13     13      17     21      24     5.2    5.4    7.2    6.8
    8   10    88     4      0        33   999 outgoing     15   13.5      13     13      15     23      24     5.4    5.8    6.8      7
    8   10    88     5      0        51   100 outgoing     15   14.5      13   12.5      22     22      24       5      7    7.4    7.7
    8   10    88     4     15        35    31 outgoing     15     14      13          20.5     22      24     5.2    5.5    6.8
    8   10    88     4     25        42    91 outgoing     16     15      13     13      21   22.5      24       6    6.2    7.4    7.6
    8   20    88     1     35        42   999 incoming   15.5     15      14   12.5      23     23      25     6.5    6.6    8.4      9
    8   20    88     3     20        32   999 incoming     16   14.5    13.5   12.5      22     23      25     5.8    5.5    6.4    5.7
    8   20    88     3     45        45    33 incoming     16     15      14     13    20.5   23.5      25     4.5      6    6.2      6
    8   20    88     2     15        13     8 incoming     15     14                    23     24            6.2    4.9
    8   20    88     2     40        23    59 incoming     15     14      14     13    21.5     24      25       5      6    7.2    6.3
    8   20    88     2     50        22    35 incoming   15.5     14    13.5     13      18   23.5    24.5     5.8    5.6      7    6.3
    8   20    88     3      0        21    38 incoming     15     14      14      13      20     24      25     5.3    5.7    6.6    5.3
    8   20    88     1     30        41    80 incoming     15     15    13.5     12      23   23.5    25.5     5.8    5.6      9    8.5
    8   20    88     2     10        12    18 incoming     15     14      13           21.5     24    25.5     5.5    5.2    6.2
    8   20    88     1      0        51   999 incoming     15   14.5      14      13      24     24      25     8.2   10.2   13.2     14
O   8   20    88     2     25        25    35 incoming     15     14      14      13      22     24    24.5     6.8    5.8    7.6    7.4
 1   8   20    88     3     40        44    80 incoming   15.5     15      14    12.5      22     23      25     5.6    6.1    6.4    5.9
^   8   20    88     3     30        33   999 incoming     16   14.5      14    12.5      21   23.5      25       5    5.8    6.8    5.6
    8   20    88     2      0        11    25 incoming     15   14.5      13             22   24.5    25.5     4.8    5.1    6.6
    8   20    88     3     10        31    27 incoming   16.5   14.5      14             21   23.5      24     6.2    6.3      7
    8   20    88     2     30        24   999 incoming     15     15      14      13    22.5     23      25     5.3    5.2    7.3    7.1
    8   20    88    12     50        50    37 incoming     15     14    13.5    12.5      24   24.5    26.5     8.6    9.2   10.2   10.4
    8   20    88     1     10        43     0 incoming   15.5   14.5      13      12    22.5     24    25.5     5.8    8.4     11     11
    8   21    88    11     35        61   999 outgoing     15   14.5      13      12      23   23.5      26     4.4    5.5    6.9    6.1
    8   21    88     4     35        50   999 incoming     15   14.5    14.5    12.5      23     23      24     8.6      9   10.1    9.1
    8   21    88     4     45        51   999 incoming     14     14      14      13    23.5   23.5      25     9.7    9.8    9.7    9.4
    8   21    88    12    ,30        65   150 outgoing   14.5   14.5    13.5      12      23   23.5      26     6.6    6.4    6.3    6.3
    8   21    88    11     45        62   999 outgoing   14.5   14.5      13      12      24     24      26     6.5    6.5    6.9    7.9
    8   21    88     3     40        22   999 incoming     15     15      14    12.5    22.5   22.5      24     6.5    6.1    7.7    6.9
    8   21    88     4      0        23   999 incoming   15.5     15      14    12.5      21     23      24     6.8    6.8    7.5    8.2
    8   21    88     6     25        25    39 incoming     16   15.5      14    12.5      21     22      25       5    5.3    6.7    6.5
    8   21    88     7     15        11    36 slack        15     15      13      12      17     23      25     5.7    5.7    6.2    0.5
    8   21    88    12      5        63   999 outgoing   14.5   14.5      14      12    23.5   23.5      25     6.6    6.1    7.1      7

-------
                                                             TEMPERATURE              SALINITY             DISSOLVED OXYGEN
 MONTH DAY YEAR HOUR MINUTE  STATION  DEPTH   TIDE   (surf.)  (1 m)   (5  m)  (10  m)  (surf.)  (1  m)   (5  m)  (surf.)  (1 m)   (5 m)  (10 m)
    8   21   88    12     20        64    999 outgoing   14.5   14.5    13.5     12    23.5   23.5      26       7    6.4     6.6    6.3
    8   21   88     3      0        35     25 incoming   15.5     15    14.5          22.5     23    23.5     4.5      5       6
    8   21   88     5      0        43    999 incoming   14.5   14.5      14     13    23.5   23.5      24     8.4    9.2     8.5    8.1
    8   21   88     5     10        42    999 incoming   15.5   14.5      14     13      22   23.5      25     6.4    9.4     8.4    8.5
    8   21   88     5     45        41    999 incoming   15.5     15    13.5   12.5    22.5   22.5      25     5.7    6.4     8.3    7.1
    8   21   88     5     35        32    999 incoming     16   15.5      14   12.5      22     22      24     6.2    5.7     7.2    6.6
    8   21   88     5     20        31     30 incoming     16     15      14     13      22     23    24.5     5.7    5.7       8    5.7
    8   21   88     7     45        12     31 slack      15.5   15.5    13.5             7     20      23     8.8    5.2       6
    8   21   88     5     45        33    999 incoming   15.5     15    14.5   12.5      22   23.5      24     6.7    5.8     7.8    6.7
    8   21   88     3     20        24     40 incoming   15.5     15      14   12.5      21   22.5      24     7.1    6.6     7.9    7.5
    8   21   88     8      0        13    999 outgoing   15.5     15                  20.5     23            5.4    5.3
    8   22   88     3     45        25     34 incoming     16     15      14     13      22   24.5      26     4.3      5     6.4      7
    8   22   88     5     15        50     26 incoming     15     15      14   13.5      25     25      26     7.4    7.6     7.8    7.2
    8   22   88     4     40        35    999 incoming     17   15.5      14          21.5     24    25.5     5.1    4.6     6.3
    8   22   88     4     50        43     80 incoming     16     15      14     13      24   24.5    25.5     5.1    5.5     7.6      7
I    8   22   88     4     30        33    999 incoming     16     16      14     13      23   23.5      26     4.8    5.2     7.2    7.2
NJ   8   22   88     4     35        34    999 incoming   16.5     15      14     13    20.5     24      26     5.2    5.4     6.8    7.6
°°   8   22   88     4     10        22    999 incoming   15.5     15      14     13    22.5     24      26     4.9    4.4     6.2    6.4
    8   22   88     5     40        51    999 incoming     15     15      14     13      25   24.5      26       8    7.8     8.1    7.6
    8   22   88     5     30        71    999 incoming   14.5   14.5      14     13    25.5     26    26.5     8.2      8       8    7.8
    8   22   88     3     35        13      7 incoming     16     15                    20     24            4.5    4.3
    8   22   88     4      0        23    999 incoming     16     15      14     13      22     24      26     5.2    4.6     7.1      8
    8   22   88     3     55        24    999 incoming     16     15      14      13      22   24.5      26     5.4      5     6.6     7.4
    8   22   88     3     30        12     25 incoming   15.5     15      14             10   23.5    25.5     5.6    5.5     4.8
    8   22   88     4      5        21      0 incoming     15   14.5      14      13      23     24      26     4.6    4.3     5.8     6.2
    8   22   88     5      0        42    999 incoming     16   15.5      14      13    23.5     24      26     5.3    6.2     7.8     7.2
    8   22   88     4     20        32    999 incoming     16   15.5      14      13      24     24      26     5.5      5     6.7     7.2
    8   22   88     5    '  5        41     80 incoming   15.5     15      14      13      24   24.5    25.5     4.5      5     6.8     6.4
    8   22   88     3     20        11     23 incoming   15.5     15      13              6     24    29.5       8    5.6     4.7
    8   23   88     4     45        12     15 incoming     16     16                  22.5     25              9    6.1
    8   23   88     7     20        42    999 incoming     16     16      14    13.5      24     25      26     6.4    5.8     7.4     8.6
    8   23   88     6      5        33    999 incoming     17     16      14      13      21     25    26.5     6.6    5.2       8     7.8
    8   23   88     6      0        32     80 incoming     17     16      14      13      23     25      27     5.4      5     8.9     8.5

-------
                                                             TEMPERATURE              SALINITY             DISSOLVED OXYGEN
o
KJ
ITH DAY YEAR HOUR MINUTE STATION DEPTH
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
9
9
9
9
9
9
9
9
9
23
23
23
23
23
23
23
23
23
23
23
23
23
24
24
24
24
24
24
24
24
24
24
24
13
13
13
13
13
13
13
13
13
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
5
6
5
4
4
5
6
5
6
5
5
7
7
10
11
11
11
11
11
10
11
10
11
11
11
12
12
12
12
1
12
11
11
20
45
45
35
50
0
10
15
55
35
10
10
20
45
20
40
50
55
30
35
5
55
5
25
20
0
,30
45
45
0
40
10
35
22
34
31
11
13
25
11
23
35
21
24
43
41
71
13
23
22
21
24
50
11
51
12
25
51
31
35
23
24
25
22
71
42
33
80
15
25
6
34
27
60
31
33
999
999
80
80
12
999
39
999
39
33
31
80
31
39
999
28
32
999
999
39
37
999
999
TIDE (surf.)
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
slack
slack
outgoing
slack
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
16
17
17.5
16
16
17
16
16
16.5
16
16
16.5
16
15
16
15.5
16
16
16
15.5
16
15
16
16
12.5
14
13.5
13
13
13.5
14
12.5
13
(1 m)
15.5
16
16
16
15.5
15.5
15.5
15.5
16.5
15
16
16
16
14.5
15
15
15
15
16
14
15
14.5
15
16
12.5
13.5
13
13
13
12.5
12.5
12
12.5
(5 m)
13.5
14.5

13

14
14
13.5
14.5
13.5
13.5
14.5
14
14

13
13
13
13
13.5
13.5
14
13.5
13.5
12
12
12.5
12.5
12.5
12.5
12.5
12
12
(10 m)
12
13



12.5

12
13
12
12.5
13.5
13
13

12.5
12
12
12
12.5
12
13
12
12.5
12

12
12.5
12
12
12
12
12
(surf.)
23.5
22
22
5
24
23
7
10
24.5
23
20
24
25
25
14
24
24
24
24
25
20.5
25
21.5
23
27
17
23
22
24
22
16
27
26.5
(1 m)
24
25
24
25
25
25
25
25
24.5
24.5
25
25
24.5
26
25
26
25
24
24
25.5
25
25.5
25
23.5
27
22
27
22
25
26
27
27
27
(5 m) (surf.)
27.5
27

28.5

27
26
27
26
27
27.5
26
26
26.5

28
28
28
28
27
27.5
26.5
25
27.5
28.5
29
28
27
28
27.5
28
27
27.5
6
5.2
6
7.3
6.7
5.4
7.7
5.1
6.2
5.6
7.1
7
4.7
8.7
6.9
6.1
5.8
5.4
5.8
6.4
6.6
8.2
7.2
5.5
7.5
6.5
6. 1
5.8
5.6
7
6.5
7.9
6.7
(1 m)
4.5
6
5.5
5
5.1
6
6.3
5
5.3
5.2
6.1
6
4.5
8.7
5.4
6.2
6
5.3
5.8
6.7
7
8.2
6.1
5.7
7.4
6.1
6.5
6
5.6
5.9
6.1
7.8
7.1
(5 m) (10 m)
8.2
9.5

6.5

7.2
7.1
7.2
7.8
7.7
7.5
8.6
7.6
8.4

5.6
5.3
4.7
6
7.9
6.1
8.2
5.2
6
7.2
6.3
6.5
6.2
6.1
6.4
5.9
7.6
7.2
5.2
9.2



6.2

6.5
8.1
6.4
7
8.7
8.2
8.1

5.7
4.5
4.2
6
7.8
0.5
7.8
0.5
5.6
7.3

5.9
6.3
5.7
6.1
4.6
7.6
6.4

-------
MONTH
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
0 9
1 9
OJ
0 9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
DAY YEAR HOUR MINUTE STATION DEPTH
13
13
13
13
13
13
13
13
13
13
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
16
16
16
16
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
11
10
11
1
12
12
1
12
12
12
12
12
12
1
1
1
2
1
1
2
12
12
12
1
1
12
1
12
12
10
12
12
12
30
50
40
20
10
15
10
35
15
20
0
35
55
30
35
55
0
10
20
10
40
20
30
45
5
45
50
'10
50
17
45
2
15
43
51
41
11
32
33
13
21
12
34
50
42
41
22
23
13
12
31
21
11
35
51
43
24
32
34
25
71
33
12
43
32
33
999
999
80
35
999
999
14
40
999
999
43
80
80
40
63
14
30
39
42
34
32
999
80
43
80
80
40
999
80
22
999
80
80
TIDE (surf.)
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
12.5
13
14
13.5
14.5
14
13
14
13
13.5
13.5
15
14
14
14
14
13.5
14
13.5
13.5
14
13
14
14.5
15
14
14
13
14
12
13
14
14.5
TEMPE]
(1 m)
12.5
13
13.5
12.5
14
13
12.5
13
13
13
13
13.5
13.5
13
13.5
13
13
13
13
13
13
12.5
13.5
13.5
13
13.5
13
13
13.5
12.5
13
13
14
MATURE
(5 m)
12
12.5
12
12.5
12.5
12.5

12.5
12
12.5
12.5
12.5
12.5
13
13

13
12.5
12.5
13
12.5
12.5
12.5
12.5
12.5
13
12.5
12.5
12.5
12
12.5
12
12
(10 m)
12
12
12
12
12
12

12
12
12
12
12
12
12
12.5


12
12
12
12.5
12
12
12
12.5
12.5
12
12
12.5

12
12
12
Si
(surf.)
27
22
21
4
19
23
9
15.5
23
23
25
19.5
24
23
16
23
24
21
21.5
23
21
26
22 .5
20
18
22
22
25
22
11
24
25
24
MjINlTY
(1 m)
27
23.5
25
26
23
25
27
25
26
27
25.5
23
25
25
24.5
25
25.5
24
25
25
23
26.5
24
24
25
23
25
25
22.5
26
24
25.5
25
UJ.&
(5 m) (surf. )
27.5
23
28
27
27.5
28.5

28
27.5
28
28
24.5
27
25.5
26

26.5
27
26.5
26
23
27
26
27
27
24
27
27.5
24
28
26
28
27
6.3
8.3
5.4
8.1
6.2
5.8
8.3
6.5
6.8
5.6
8.1
6.4
6.2
7.1
8.8
9.1
8.9
6.5
6.4
7.8
7.2
7.7
7.9
7.2
7.1
7. 1
7.3
8.7
7.5
9. 6
8.1
7
6.8
it>UJjV£,U
(1 m)
6.9
6.9
4.8
5.6
5.6
5.8
5.9
5.8
5.8
6.2
7.9
7
6.3
7.1
7
8.4
7.8
6.3
6.5
7.6
7.6
7.4
7.7
7.9
6.8
7.7
7.8
8.3
7.8
7.6
8.1
7.5
6.8
uAHjr,r<
(5 m) (10 m)
6.9
7.4
6.4
5.7
6.3
6.3

5.7
5.6
6.6
7.4
7.4
6.7
7.1
7.7

7.4
6.8
6.5
7.6
7.3
7.2
7.2
7.4
7.2
7.4
7.5
7.5
7.4
6
8.5
7
6.5
6.5
7.2
5.9
0.5
6.2
6.1

4.7
0.5
6.4
6.7
7.3
6.3
6.1
6.9


6.2
6.5
5.2
7.2
7.3
7.4
7
7.2
7.2
7.1
7.6
6.5

7.5
7
6.5

-------
TEMPERATURE
MONTH
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
„ 9
? 9
W 9
H> 9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
DAY YEAR HOUR MINUTE STATION DEPTH
16
16
16
16
16
16
16
16
16
16
16
16
16
16
16
17
17
17
17
17
17
17
17
17
17
17
17
17
17
17
17
17
17
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
11
11
1
10
11
10
1
11
12
1
10
1
12
12
10
1
12
11
2
12
11
12
1
11
12
1
1
2
11
1
1
11
11
0
40
35
25
28
10
4
13
22
19
40
46
32
55
50
25
20
30
0
30
50
5
15
40
40
50
40
'15
10
5
35
20
55
23
31
71
11
22
13
41
21
34
50
25
51
35
42
24
43
31
25
71
32
23
22
35
24
33
50
41
51
11
34
42
12
21
60
24
90
32
24
3
80
32
999
999
999
999
24
999
44
999
999
999
999
999
999
999
999
999
999
999
999
999
999
999
999
999
999
TIDE (surf.)
incoming
incoming
incoming
incoming
incoming
slack-low
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
incoming
13
15
13
14.5
12.5
12.5
13 .5
13
14.5
13
12.5
13
13.5
13 .5
13
13.5
15
12.5
12.5
14
13
100
14.5
13
14.5
13
14
13
12.5
14
14 .5
13
14
(1 m)
13
13
13
14.5
12.5
12.5
13
12.5
14
13
12
13
14
13
13
13
13
13
12.5
13
13
13
14
13
13
13
13
13
13
13
13
13
13
(5 m)
12
12
12
13
12

12
12
12
12.5
12
13
12.5
12.5
12
12.5
12
12
12.5
12
12
12
12.5
12
12
12.5
12
13
12
12
12.5
12
12
(10 m)
12

12
12


12
12
12
12

12

12.5
12
12

12
12
12
12


12
12
12
12
12

12
12
11.5

SALINITY
(surf.)
22.5
24
26
17.5
25
12
25
25
23
26
13
25.5
22.5
24
14.5
24.5
22
12
25.5
24
15.5

22.5
12
23
25
24
25
6
24
23.5
7
22
(1 m)
24.5
26
26
23.5
26
25.5
25. 5
26
24.5
26
26
25.5
23
25
25
25
24.5
25
25.5
25
24
24.5
23.5
25
24.5
25
25
25
25
25
25
25.5
25
DISSOLVED OXYGEN
(5 m) (surf.)
28
28
27.5
25
28

27
27.5
27.5
26.5
28
26
27
26
27.5
26
27
27
26. 5
27.5
27
27
26.5
27
27
26
27
25
27
27
26
27
27
7.5
7.6
9.6
9.6
6.5
9.4
7
6.4
7.1
9.1
9.2
9.2
7.5
7.8
9.3
7.7
7.6
9.4
7.6
7
8.7

6.9
10.2
7.4
8.3
5.4
7.5
9.2
6.1
7.2
9.2
7
(1 m)
7.1
7.4
9.6
6.6
6.3
7.3
7.6
6.4
6.7
8.8
6.2
9.4
7.2
7.8
7.5
7.4
6.8
7
7.5
7.4
6.7
6.8
6.5
7
6.4
8.3
. 6.3
7.6
6.7
6.6
6.8
6
6.5
(5 m) (10 m)
7.3
6.5
8.4
7
6

8
5.8
6.4
8.8
7.3
9.4
7.8
8.4
7.6
8.4
7.4
7
7.2
6.6
6.3
5.5
6.7
7.4
6.5
8.1
6.1
8
5.4
6.7
8.4
4.2
6.8
5

8.4
3.8


7.3
4
6.2
7.8

8.2

8.2
6.6
7.4

5.8
7.3
4.9
5.8


6.6
6.8
6.4
6.6
7

6.4
8.9
1.5


-------
   APPENDIX D






BIOASSAY RESULTS

-------
TOXSCAN, INC.

-------
               MARINE BIOASSAY LABORATORIES

                        1234 HIGHWAY ONE
                      WATSONVILLE, CA 95076
                          (408) 724-4522
 PRELIMINARY ASSESSMENT OF THE EFFECTS OF TEMPERATURE  AND

DISSOLVED OXYGEN UPON THE TOXICITY  OF PULP MILL  EFFLUENT TO

        JUVENILE COHO SALMON  (ONCORHYNCHUS KISUTCH)
                        Prepared  for:

             JONES AND  STOKES ASSOCIATES,  INC.
                   Bellevue,  Washington
                        Prepared by:
                        TOXSCAN, INC.
            MARINE BIOASSAY LABORATORIES DIVISION
                   Watsonville, California
                       DECEMBER, 1988
                             MBL
                      A DIVISION OF TOXSCAN, INC.

                              D-l

-------
Introduction

     As part of Work Assignment  No.  12 under  EPA Contract No. 68-02-
4381 between EPA Region X and  Jones  and Stokes  Associates,  Inc.,
Kinnetic  Laboratories,  Inc.,   through   it's  affiliated  firm ToxScan,
Inc.,  has performed toxicity  studies using juvenile Coho  Salmon
(Oncorhynchus kisutch).   The studies  were  designed to  yield  preliminary
data on the relationship between  sublethal  stress  (low dissolved oxygen
and  high  temperature)  and  observed  toxicity  of  effluent  from a pulp
mill.   These salmonid  tests represent  one  portion of a multi-species
toxicity  testing program which,  together  with oceanographic and field
biology  studies,  comprised an  investigation  of  repeated  fish kills
observed in Ward Cove near Ketchikan, Alaska.
Background

     Repeated fish kills have been observed in Ward cove,  with  affected
species including adult  coho  and pink  salmon,  adult herring and
juvenile salmonids.  Most  fish kills seem  to occur during August and
September.   Ward Cove  is  the  site of a pulp mill owned by Ketchikan
Pulp  company and  a salmon  processing  facility  owned  by Ward Cove
Packing Company.   It seems possible  that  fish kills may  be related  to
the operations of these two industries.

     Historical data indicate that low levels of dissolved oxygen occur
regularly during summer within the  top and  bottom  stratified layers  of
Ward  Cove  water,  and  Kruse  and  Viteri (1988)  hypothesize  that  fish
kills may be caused by a combination of low dissolved oxygen  in concert
with  toxicants  in  the  pulp mill  effluent.   This study was designed  to
investigate  the  relationship between dissolved  oxygen,  temperature and
effluent toxicity in affecting fish mortality.
 Experimental Design

      Juvenile  coho salmon were  exposed  to a series of dissolved oxygen
 concentrations  ranging  from  the normal 8  ppm down  to  3  ppm,  to
 determine  an LC50 for  dissolved oxygen,  i.e.,  to  quantify dissolved
 oxygen levels  which  produced obvious stress  and  subsequent mortality.
 Following  identification of  a critical  dissolved  oxygen concentration,
 salmon were  exposed  to  a  concentration  series of  pulp mill effluent at
 high, intermediate,  and  low dissolved  levels  to test  the hypothesis
 that dissolved oxygen and effluent  stresses  are  additive  (or perhaps
 synergistic)  in  contributing to fish mortality.   This  series  of tests
 was  performed  at  two different  temperatures, e.g.  at  about  8°C
 (corresponding  to the  temperature of  offshore  waters)  and  again at
 about 18°C  (well within the  range of temperatures  reported in nearshore
 waters in  the  vicinity of Ward Cove).
                                    D-2

-------
Methods

     Juvenile coho  salmon (Oncorhynchus kisutch)  were purchased  from
Silverking Oceanic Farms, Inc., Santa Cruz,  California.   All  fish were
held  in laboratory tanks  for at  least  2 weeks  prior  to  testing.
Acclimation  temperature  was  12°C, and  fish were fed  commercial  trout
chow  pellets.    Less  than  2%  mortality  was  observed  during  the
acclimation  period, and  all  fish  appeared healthy and vigorous.   Size
range was  4-6  cm (0.4-0.6 g), and individuals were  randomly  withdrawn
from acclimated laboratory populations for assignment to test  tanks.

     Attempts to acclimate the juveniles to increased salinity resulted
in elevated mortality, so testing was done in freshwater.

     Test  tanks were  10-liter polycarbonate  which  had  been  cleaned
according  to protocol-prescribed  methods,  including acid  and  acetone
rinses  to  remove adsorbed inorganic and organic contaminants.   Dilution
and  control  water was  dechlorinated municipal  water,  which was  also
used as acclimation water for the fish.

     Dissolved  oxygen concentration  in test  ranks  was  controlled by
bubbling  nitrogen and air  simultaneously  into  each tank.    The  final
D.O.  depended  upon  the rate  of  addition  of  each  gas,  and  the
empirically-determined rates  were controlled by  valved precision flow-
meters  (Cole-Parmer Model J-3216).   Test temperatures were achieved in
two ways:  for  the 18°C  test, room temperature was maintained by an air
conditioner  linked to a  precision mercury thermoregulator.  A large fan
in the  test room  maintained air  circulation adequate  to  prevent
vertical  stratification.  For the 8°C test, tanks  were placed inside a
large  commercial refrigerator modified  to  hold test  temperature within
the  specified +_  1°C  limits.   Photoperiod  was 16 hours  light:8 hours
dark.   Fish  were not  fed during  testing.  One  week prior to  initiation
of testing at  8°C and 18°C, fish were slowly brought  to the appropriate
test  temperature from  their  12°C laboratory  acclimation  temperature.
Transition from acclimation to test  temperature was  done over two days,
and  fish  were  held at the test temperature  for five  days before testing
began.

      Test protocols  generally  followed the  guidelines   in EPA 600/4-
85/013,  Methods  for  Measuring  the Acute   Toxicity of  Effluents  to
Freshwater and  Marine Organisms.
 Effluent Sampling

      Grab samples of effluent  were  collected  from three  outfalls  at  the
 pulp mill,  designated  main,  primary  and  secondary,  on 20  September,
 1988.  Samples were collected  into  5  gallon collapsible  plastic carboys
 which were immediately placed in iced coolers  for air shipment  to  the
 ToxScan laboratory in Watsonville,  CA.  Samples  arrived  on  21 September
                                     D-3

-------
and were  placed  in the  laboratory  4°C cold  room where  they  remained
until testing was initiated.  Following EPA Region X instructions, the
three effluent samples  were mixed  in  the proportions  38.5% main:  45%
primary: 16.5% secondary.  The resulting effluent composite was used as
the test material for these experiments.
Results

     The dissolved  oxygen LCcQ test was performed  on 12-16 September,
and the results  are summarized in Table 1.   Control  of  D.O.  levels in
test  tanks  was reasonably  good,  but required  frequent  monitoring and
some compensatory adjustment of  gas  flow rates.  Monitoring of D.O. is
reported as  the mean  of  hourly measurements  taken each day.   pH was
measured daily.   Temperature  data  are  not  reported,  but all  were  +_
0.4°C  of  the  target  level.   The LCjQ  for dissolved oxygen  was  4.65
mg/1,  with  95% confidence  limits on those data of 4.55 mg/1 and 4.76
mg/1.

     The 18°C effluent test was  done on  26-30  September (Tables  2,  4
and 6).  The  mean dissolved oxygen  level in the low D.O. test was 4.72
mg/1,  in  the medium D.O.  test the  mean was  6.53 mg/1 and in the high
D.O.  test the mean  was  8.44 mg/1.  The LCcQ  for pulp mill effluent was
 32%  (confidence  limits 28.4 and  35.8%), in  low D.O.,  28.1%  (25.0 and
 31.6%) in medium D.O.  and 42.1%  (0,  infinity) in high D.O.

      The 8°C effluent test was  done on 3-7  October,  (Tables  3, 5 and
 7).   Mean dissolved oxygen levels  in low, medium  and  high D.O.  tests
were,  respectively,  4.92 mg/1,  6.63 mg/1 and 10.73 mg/1.   Effluent
 LC5Qs  were  35.8% (27.1 and 47.7%) in low  D.O., 35.1% (27.9 and 44.2%)
 in medium D.O.,  and 44.5% (36.7  and  49.1%) in high  D.O.
   r

      The  results   are  tabulated in  the   text  table  below,  and are
 expressed  both  in  terms  of LC50  (* effluent)  and in  toxicity  limits
 (t.u.'s), calculated by dividing 100 by the LC50 in percent  (100/LC50).


                       Pulp Mill  Effluent Toxicity

                    Low D.O.           Medium  D.O.           High  P.O.

 LCSO  - 18°C          32.0%                28.1%              42.1%
         8°C          35.8%                35.1%              44.5%

 t.u.  - 18°C          3.13                 3.56        _       2.38
         8°C          2.79                 2.85               2.25
                                     D-4

-------
Discussion

     The results of  this  very preliminary  study  suggest  the following
conclusions.

   - At each  dissolved oxygen level  tested, the  toxicity  of the pulp
     mill effluent is lower at 8°C than at  18°C.

   - At  either experimental  temperature,  the mill  effluent  is  more
     toxic at very low dissolved oxygen than at high dissolved oxygen.

   - The toxicity tests done at intermediate levels of dissolved oxygen
     show no reduction of toxicity when compared with tests  done at low
     D.O. levels.  Toxicity at  18°C,  in fact, seems slightly increased
     with a moderate increase in D.O.

     Without  replication  of toxicity  tests, no statistical  evaluation
of  these  data can  be done.   A crude  approach to quantification of the
comparison among tests can  be made by  expressing  the toxicity reduction
in  terms  of  percent  of the higher toxicity.  The calculation was done
according to  the formula:

                       higher toxicity -  lower toxicity
        % reduction =	— X 100
                                higher toxicity
      For  the  18°C  data,  toxicity at high D.O.  is 24% less  than toxicity
 at  low D.O.;  for the 8°C  data the corresponding reduction  in toxicity
 is  19.4%.

      For  the low  D.O.  data,  toxicity  is  reduced  by about  11%  at  8°
 compared  with  that  at  18°C;  for  the  medium  D.O.  data  the  toxicity
 reduction is about  20%,  and  for  the  high D.O. data  the  toxicity  is
 reduced by  about 6%  with a 10°C  temperature decrease.

      If the  intuitively worst-case situation (low D.O.,  high
 temperature)  is compared  with the best-case situation (high  D.O.,  low
 temperature), the  toxicity reduction is about 28%.

      These  results  tend  to  support  the hypothesis  that  the  adverse
 environmental conditions observed in Ward Cove during the summer  months
 can potentiate  the toxic effects of pulp mill effluent.
                                   D-5

-------
TABLE 1
DISSOLVED OXYGEN - 12°C
         Mean Dissolved Oxygen
Tank #   Concentration (mg/1)

  1              3.05
  2              4.20
  3              4.62

  4              5.48
  5              6.30
  6              7.24
  7              8.60
                   Number of Survivors
          0 hrs  24 hrs  48 hrs  72 hrs
96 hrs
10
10
10
10
10
10
10
0
1
8
10
10
10
10
0
1
7
10
10
10
10
0
1
7
10
10
10
10
0
0
7
9
10
10
10
                                         LC50 (D.O.) = 4.65 mg/1
                             95% confidence limits = 4.55 mg/1, 4.76 mg/1
        Tank

          1
          2
          3

          4
          5
          6
          7
        Tank

           1
           2
           3

           4
           5
           6
           7
            Dissolved Oxygen  (mg/1)
   0 hrs  24 hrs  48 hrs   72 hrs  96 hrs
3.3
4.3
4.6
5.1
6.4
7.1
8.8

0 hrs
8.4
8.4
8.4
8.3
8.3
8.4
8.4
3.8
3.5 4.1
4.7 4.7
5.8
6.5
7.0
8.5
pH value
24 hrs 48
8.3
8.3
8.3
8.4
8.3
8.4
8.3
5.5
6.2
7.4
8.6
(pH
hrs
8.3
8.2
8.3
8.3
8.2
8.3
8.3
3.9
4.5
5.6
6.3
7.3
8.7
units)
72 hrs
8.3
8.2
8.2
8.2
8.2
8.2
8-. 3
3.8
4.6
5.4
6.1
7.4
8.4

96 hrs
8.2
8.1
8.2
8.1
8.2
8.2
8.2
                                    D-6

-------
TABLE 2
       PULP MILL EFFLUENT - 18°C

Low Dissolved Oxygen (Mean = 4.72 mg/1)
Effluent Concentration (%)

           56
           32
           18

           10
           5.6
           0 (control)
                         Number of Survivors
                 0 hrs  24 hrs  48 hrs  72 hrs  96 hrs
10
10
10
10
10
10
0
101
10
10
10
10
0
82
10
10
10
10
0
72
10
10
10
10
0
52
10
10
10
10
                                               LC50 = 32%
                                  95% confidence Hmits = 28.4%, 35.8%
 Effluent Concentration  (%)

            56
            32
            18

            10
            5.6
            0 (control)
                        Dissolved Oxygen (mg/1)
                 0 hrs  24 hrs  48 hrs  72 hrs  96 hrs
4.6
4.8
4.7
4.9
4.4
4.8
4.7
4.7
4.6
4.1
4.3
4.6
_
5.2
4.9
4.9
4.8
4.1
.
4.4
5.1
5.0
4.8
4.3
_
4.8
5.0
4.8
4.8
4.8
 Effluent  Concentration (%)

            56
            32
            18

            10
            5.6
            0 (control)
                  0 hrs
 pH Value (pH units)
24 hrs  48 hrs  72 hrs   96 hrs
7.8
7.9
8.0
8.2
8.3
8.4
8.1
8.1
8.1
8.1
8.2
8.3

7.8
8.0
8.0
8.2
8.3

8.0
8.1
8.1
8.3
8.3
.
8.0
8.0
8.1
8.2
8.3
 Behavioral observations

    1.  None Swimming;  all twitching on bottom of tank
    2.  About 50% of fish swimming,  all twitching
                                    D-7

-------
TABLE 3
       PULP MILL EFFLUENT - 8°C

Low Dissolved Oxygen  (Mean = 4.92 mg/1)
Effluent Concentration (%)

           56
           32
           18

           10
           5.6
           0 (control)
                 0 hrs
 Number of Survivors
24 hrs  48 hrs  72 hrs   96 hrs
10
10
10
10
10
10
0
101'2
10
10
9
10
0

93
9
9
10
0
81
8
9
9
10
0
71
8
8
9
9
                                                LC
                                                  50
                                    =  35.1
                                   95% confidence  limits  =  27.1%, 47.7%
 Effluent  Concentration  (%)

            56
            32
            18

            10
            5.6
            0 (control)
 Effluent Concentration (%)

            56
            32
            18

            10
            5.6
            0 (control)
                         Dissolved  Oxygen  (mg/1)
                  0 hrs   24 hrs   48 hrs  72 hrs   96 hrs
4.9
4.8
5.0
4.6
5.0
4.9

0 hrs
8.2
8.4
8.6
8.5
8.6
8.7
4.7
4.6
4.8
4.9
5.1
5.0
pH Value
24 hrs 48
8.3
8.4
8.5
8.6
8.6
8.5

4.7
5.0
4.9
5.0
5.2
(pH
hrs
_
8.3
8.5
8.4
8.5
8.6

4.9
5.1
5.1
4.8
5.3
units)
72 hrs
_
8.3
8.5
8.7
8.7
8.7
_
5.0
4.9
5.1
4.9
4.8

96 hrs
_
8.4
8.4
8.6
8.6
8.7
 Behavioral observations

    1.  Activity level much reduced; slow swimming with a "rolling" motion
    2.  All twitching
    3.  2 (of 9) twitching
                                    D-l

-------
TABLE 4
        PULP MILL EFFLUENT - 18°C

Medium Dissolved Oxygen (Mean = 6.53 mg/1)
Effluent Concentration (%)

           56
           32
           18

           10
           5.6
           0 (control)
                          Number of Survivors
                  0 hrs  24 hrs  48 hrs  72 hrs  96 hrs
10
10
10
10
10
10
10
101
10
10
10
10
0
8
9
10
10
10
0
7
9
10
10
10
0
5
8
10
10
10
                                               LCcg = 28.1%
                                  95% confidence  limits = 25.0%, 31.6%
 Effluent  Concentration  (%)

            56
            32
            18

            10
            5.6
            0  (control)
 Effluent Concentration (%)

            56
            32
            18

            10
            5.6
            0 (control)
                         Dissolved  Oxygen  (mg/1)
                   0 hrs  24  hrs   48 hrs  72 hrs  96 hrs
6.2
6.3
6.4
6.4
6.3
6.2

0 hrs
7.9
7.9
8.1
8.1
8.2
8.4
7.2
6.7
6.8
6.2
6.5
6.8
pH Value
24 hrs 48
8.2
8.1
8.1
8.2
8.2
8.3
_
6.5
6.7
6.9
6.7
6.7
(pH
hrs
_
7.8
8.0
8.1
8.1
8.2
af
6.3
6.5
6.4
6.6
6.4
units)
72 hrs
_
8.0
8.0
8.1
8.2
8.2
—
6.6
6.8
6.3
6.4
6.4

96 hrs
__
8.0
8.1
8.1
8.1
8.1
 Behavioral observations
    1.  Eratic, darting swimming behavior, all twitching,
                                   D-9

-------
TABLE 5
        PULP MILL EFFLUENT - 8°C

Medium Dissolved Oxygen (Mean = 6.63 mg/1)
Effluent Concentration (%)

           56
           32
           18

           10
           5.6
           0 (control)
                          Number of Survivors
                  0 hrs  24 hrs  48 hrs  72 hrs  96 hrs
10
10
10
10
10
10
0
101
10
10
10
10
0
102
93
10
9
9
0
82
8
10
9
9
0
72
8
9
9
9
                                               LC
                                                 50
                                      35.1%
                                  95% confidence limits = 27.9%, 44.2%
 Effluent Concentration  (%)

           56
           32
           18

           10
           5.6
           0  (control)
                         Dissolved Oxygen  (mg/1)
                   0  hrs  24 hrs   48 hrs  72 hrs  96 hrs
6.7
6.8
6.9
6.8
6.8
6.7
7.2
7.1
6.9
7.0
6.9
6.6

7.0
7.0
6.5
6.9
7.0
_
6.7
6.6
6.5
7.0
6.7
_
6.9
6.9
6.7
6.8
6.0
 Effluent  Concentration (%)

            56
            32
            18

            10
            5.6
            0 (control)
                   0 hrs
 pH Value (pH units)
24 hrs  48 hrs  72 hrs   96  hrs
8.2
8.4
8.6
8.6
8.6
8.6
8.4
8.4
8.5
8.6
8.6
8.5

8.4
8.4
8.5
8.4
8.5
_
8.4
8.5
8.6
8.5
8.6
_
8.4
8.4
8.6
8.6
8.6
 Behavioral observations

    1.  Activity level very low; fish quiet
    2.  All fish twitching
    3.  2 of 9 twitching
                                    D-10

-------
TABLE 6
       PULP MILL EFFLUENT  -  18°C

High Dissolved Oxygen  (Mean  =  8.44 mg/1)
Effluent Concentration (%)

           56
           32
           18

           10
           5.6
           0 (control)
                          Number  of  Survivors
                  0  hrs   24  hrs   48  hrs   72 hrs  96 hrs
10
10
10
10
10
10
0
101
10
10
10
10
0
101
10
10
10
10
0
101
10
10
10
10
0
102
10
10
10
10
                                               LC5p = 42.1%
                                  95%  confidence  limits = 0, infinity
 Effluent Concentration (%)

           56
           32
           18

           10
           5.6
           0 (control)
                         Dissolved Oxygen (mg/1)
                  0 hrs  24 hrs  48 hrs   72  hrs   96  hrs
8.2
8.0
8.0
8.7
8.6
9.1
8.3
8.9
8.0
8.7
8.4
8.5
_
8.8
8.7
9.2
8.9
9.1
_
8.5
8.2
8.7
7.5
8.4
_
8.6
8.6
8.8
6.9
7.8
 Effluent Concentration  (%)

            56
            32
            18

            10
            5.6
            0  (control)
                  0 hrs
 pH Value (pH units)
24 hrs  48 hrs  72  hrs   96 hrs
7.9
8.0
8.0
8.2
8.2
8.4
8.1
8.1
8.0
8.2
8.1
8.3
_
8.0
8.1
8.1
8.0_
8.1
_
8.2
8.0
8.2
8.0
8.1
__
8.1
8.0
8.2
8.1
8.0
 Behavioral  observations

    1.   Slow,  rolling  swimming motion.
    2.   8  swimming as  above;  2 twitching on bottom
                                    D-ll

-------
TABLE 7
       PULP MILL EFFLUENT - 8°C

High Dissolved Oxygen  (Mean =  10.73 mg/1)
Effluent Concentration (%)

           56
           32
           18

           10
           5.6
           0 (control)
                         Number of Survivors
                 0 hrs   24 hrs  48 hrs  72 hrs  96 hrs
10
10
10
10
10
10
101
102
10
10
9
10
61
92
10
9
9
10
21
93
10
9
9
10
I1
94
10
9
9
10
                                               LC50 = 44.5%
                                  95% confidence limits = 36.7%, 49.1%
 Effluent Concentration (%)

           56
           32
           18

           10
           5.6
           0 (control)
 Effluent  Concentration  (%)

            56
            32
            18

            10
            5.6
            0  (control)
                         Dissolved Oxygen  (mg/l)
                  0 hrs   24 hrs   48 hrs  72 hrs  96 hrs
10.0
9.9
10.5
10.4
10.8
10.2

0 hrs
8.3
8.4
8.6
8.5
8.6
8.6
10.8
11.0
11.0
11.0
11.2
11.2
pH Value
24 hrs 48
8.4
8.5
8.5
8.6
8.6
8.6
10.5
10.8
10.6
10.6
10.6
10.6
(pH
hrs
8.4
8.5
8.4
8.5
8.5-
8.5
10.4
10.5
10.6
10.4
10.7
10.8
units)
72 hrs
8.4
8.5
8.5
8.6
8.6
8.6
10.8
11.0
11.2
11.2
11.2
11.3

96 hrs
8.4
8.4
8.4
8.6
8.6
8.5
 Behavioral  observations

    1.   All  twitching
    2.   All  quiet,  not  swimming
    3.   2 swimming, 7 quiet
    4.   All  quiet,  5 twitching
                                   D-12

-------
EPA MANCHESTER LAB

-------
           UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
                                  REGION 10
                          SEATTLE, WASHINGTON 98101
          M/S  Lab              November 18,  1988

MEMORANDUM

SUBJECT:   Ketchican Pulp and Paper (Ward Cove) Sediment  Toxicity Test Results


FROM:     Joseph M. Cummins, Aquatic Bi
          Laboratory Branch

TO:       Duane W.  Kama
          Water Permits and Compliance Branch


     Attached are the results of the amphipod-sediment toxicity tests conducted
in conjunction with the water quality study of Ward  Cove involving the Ketchican
Pulp and Paper Company.  Also included are measurements  of  interstitial water
salinities, gross observations of selected sediment  characteristics, and a
description of the water quality conditions characterizing  representative sediment
test preparations.

     The sediment toxicity tests were conducted  according to  the amphipod-sediment
toxicity test protocol  described in the "Puget Sound Protocols" (Tetra Tech, 1986)0
A  few modifications in the protocol were made to adapt the  test to specific
conditions of the study.  These modifications are included  in the summary of the
test method presented below.

    rFive replicates of the test and control sediments were included in the
evaluation.  Each replicate consisted of a 2-cm  layer of well-mixed sediment
overlayed with approximately 800 mL of seawater  (Salinity 28  o/oo).  Each test
preparation was randomly seeded with twenty marine amphipods  and incubated at 15°C
for ten days with aeration and continuous, fluorescent illumination.  Water quality
conditions characterizing representative sediment preparations were measured on Day
0  and Day 10 of the test.  The response parameters used  to  assess sediment toxicity
were amphipod survival, emergence, and reburial.  Sediment  that was originally
inhabited by the amphipods used for testing served as the Control.  This sediment,
together with the amphipods, was collected from  West Beach, Whidbey Island,
Washington.  A "particle size" Control was not  included  in  the evaluation because
the particle size characteristics of the test  sediments  from  Ward Cove were unknown
prior to testing.  Cadmium chloride obtained from the EPA Environmental Monitoring
and Support Laboratory, Cincinnati, Ohio was used as a reference toxicant in a
sediment-free test system.

     In summary, all of the sediments collected  from Ward Cove were acutely toxic
to the amphipod, R. abronius  (Table 1).  Amphipod survival  ranged  from a high  of
64 % in EPA Sample No. 88390120 to a low of 7  %  in EPA Sample No. 88390121.  Mean
amphipod survival for all of the Ward Cove samples tested was 43 %.   No mortalities
were observed in the Control, and amphipod response to the  reference  toxicant  was
considered acceptable  (96-h LC50 = 1.34 mg Cd/L; 95 % Confidence Limits  1.16  -
1.55 mg Cd/L).

                                     D-13

-------
     The mean survival  of 7 % was lower than the mean survival measured in any of
the sediments collected from 48 stations occupied in 1984 during a reconnaissance
survey of eight urban and baseline bays in Puget Sound  (Battelle, 1986).  However,
survival values similiar to, or lower than this have been reported by Swartz et
jil_ (1982) in Commencement Bay sediments subject to a variety of chemical
contaminants and by the National Marine Fisheries Service in sediments from
Eagle Harbor containing high concentrations of creosote  (Personal Communication,
Dr. Michael Schiewe, NMFS Laboratory, Mukilteo, WA, 1984).

     The cause of the toxicity measured in the Ward Cove sediments cannot be
determined based on the results of this limited toxicological evaluation.  All
of the water quality characteristics measured on days 0  and 10 of the test
appeared to be within acceptable limits (Table 3).  Interstitial water salinities
(26 o/oo - 31 o/oo) were also considered acceptable (Table 4).  However, the fine
particle size of the sediments, coupled with elevated sulfide levels and relatively
low sediment pH values could possibly have contributed  to one or more of the toxic
responses  observed  (Table 4).  Correlation of these toxic responses with all of
the physical and chemical data you and others have collected  in conjunction with
this  study will be  needed before more definitive cause  and effect relationships
can be  established.

      Please  let me  know if you  have  any questions.


 References:

      Swartz, R.C.,  W.A. DeBen,  K.A.  Sercu, and J.O. Lamberson.  1982. Sediment
toxicity and the distribution  of amphipods in Commencement Bay, Washington,
U.S.A.  Mar.  Pollut.  Bull.  13:359-364.

    '  Tetra Tech, Inc.  1986.  Recommended protocols  for measuring selected
 environmental  variables  in  Puget Sound. Final  Report TC-3991-04., Tetra Tech,
 Inc., Bellevue, WA.
                                     D-14

-------
Table  1.   Responses  of  the Marine Amphipod, Rhepoxynius abronius. to Sediments Collected
In Conjunction with the Ketchican Pulp
9/27 - 10/7/88.
1
10-Day
Sampling Replicate Amphipod
Station Number Emergence


West Beach
Control



88390117 **
f, X
k/ ' )


88390118 ***
(\0-d}
V.


88390119 ***
(to-f]


88390120 **
C5o-\}
^


88390121 **
f&o-n

1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
** 10-day amphipod
0
0
0
0
0
34
58
33
53
22
55
57
61
50
67
54
27
69
46
61
35
50
34
31
51
33
45
39
26
28
emergence and


x =
Sx ••



x =
Sx ••



X =
Sx



X =
Sx


X =
Sx



X -
Sx

and Paper Co. Project and Tested
Amphipod Responses
1
10-Day Amphipod Survival
1
No.


0.0
= 0.0



39.8
= 15.1



58.0
= 6.4



51.2
= 15.9


40.2
= 9.5



= 34.2
= 7.9

survival determi
| Survivors Not
of Survivors Mean % Reburying
20
20
20 x - 20.0 100.0
20 Sx = 0.0
20
11
11
11 x = 10.6 53.0
14 Sx = 2.9
6
9
10
10 x = 9.6 48.0
7 Sx = 1.8
12
11
7
9 x = 9.0 45.0
8 Sx = 1.6
10
13
14
10 x - 12.8 64.0
12 Sx - 1.9
15
1
3
0 x = 1.4 7.0
2 Sx = 1.1
1
ned to be significantly
0
0
0
0
0
1
4
1
3
1
2
3
3
2
5
3
2
5
1
1
1
0
1
2
3
0
3
-
0
0
different
_ _ \


x =
Sx =



X =
Sx =



X =
Sx =



X =
Sx =


X =
Sx



X =
Sx




0.0
= 0



2.0
= 1.4



3.0
= 1.2



2.4
= 1.7


1.4
= 1.1



0.75
= I-.5


   from control  at  alpha = 0.05 (1-sided) by Dunnett's test (EPA Version 1.1).

*** 10-day  amphipod  emergence, survival, and reburial determined to be significantly
   different  from control  at alpha = 0.05 (1-sided) by Dunnett's test (EPA Version 1.1)
                                           D-15

-------
 Table 2.   Observations of Amphipod Emergence During the Ketchican Pulp and Paper
            Amphipod-Sediment Toxicity Tests 9/27 - 10/7/88.

                                   No. of Amphipods Out of Sediment
                              (Floating, Swimming, or On Sediment Surface)
Replicate
Treatment No.
1
2
West Beach 3
Control 4
5
1
2
88390117 * 3
4
5
1
2
88390118 * 3
4
5
1
2
88390119 * 3
4
5
1
2
88390120 * 3
4
5
1
2
88390121 * 3
4
5
123
000
000
000
000
000
454
10 8 11
940
12 8 7
340
13 8 6
11 6 1
10 10 8
12 8 1
11 11 9
798
2 10 1
7 7 10
836
969
3 7 5
984
11 6 5
12 7 4
5 7 7
963
10 6 7
565
453
633
4
0
0
0
0
0
1
7
4
1
2
4
3
3
6
6
9
2
12
5
11
4
7
5
3
5
0
3
4
4
1
Days
5 6
0
0
0
0
0
2
3
3
5
0
4
9
6
2
7
2
4
3
5
6
2
4
0
1
4
2
2
5
2
3
0
0
0
0
0
1
5
6
4
3
4
6
5
6
5
3
1
3
3
5
3
4
0
0
5
2
5
2
3
5
7
0
0
0
0
0
1
1
2
4
1
2
4
5
3
5
5
1
7
3
5
5
1
0
0
3
2
3
4
1
2
8
0
0
0
0
0
3
4
2
4
4
4
5
6
4
4
3
2
7
5
4
1
3
4
2
4
2
3
2
1
2
9
0
0
0
0
0
5
3
0
3
2
7
8
3
2
3
3
3
8
4
3
1
3
1
0
3
3
2
3
1
1
10
0
0
0
0
0
7
6
3
5
3
3
4
5
6
6
5
1
5
4
2
4
7
2
2
8
4
4
3
2
2
| 10-Day
Total Treatment
Emergence Summary
0
0
0 x = 0.0
0 Sx = 0.0
0
33
58
33 x = 39.8
53 Sx = 15.1
22
55
57
61 x = 58.0
50 Sx = 6.4
67
54
27
69 x = 51.2
46 Sx = 15.9
60
35
50
34 x = 40.2
31 Sx = 9.5
51
33
45
39 x = 34.2
26 Sx = 7.9
28
* 10-day amphipod emergence determined to be significantly greater than control  at
  alpha = 0.05 (1-sided) by Dunnett's test (EPA Version 1.1).
                                         D-16

-------
Table 3.    Selected  Water  Quality  Characteristics Measured at  the  Beginning  (Day  0)
          and End  (Day  10)  of the Amphipod-Sediment Tests Conducted 9/27  -  10/7/88.
                             Day 0
DAY 10
1
Sampling DO Temperature Salinity
Station pH (mg/L) (°C) (°/°°)
West Beach
Control 7.92 7.2 15.4 28
88390117 8.11 7.4 15.3 28
88390118 8.04 7.7 15.4 28
88390119 7.82 7.0 15.4 28
88390120 7.98 7.4 15.1 28
88390121 8.19 7.0 15.3 28
1 1 1
DO Temperature Salinity
pH (mg/L) (°C) (°/°°)
7.97 7.7 15.2 28
8.07 7.4 15.1 28
8.10 7.7 15.1 28
7.91 7.7 15.3 28
8.13 8.0 15.1 28
8.21 8.1 15.1 28
                                           D-17

-------
Table 4.  Characteristics of Ward Cove Sediments Collected  In  Conjunction With the Ketchican
         Pulp and Paper Company Project and Tested  9/27  -  10/7/88.
Sampling
Station
West Beach
Control
Interstitial Water
Salinity (o/oo)
28
PH
7.21
Wet Weight (g)
Per 2 cm Sediment
Layer Tested
282
General
Observations
Fine clean sand.
88390117
30
6.99
169
88390118
29
6.98
170
Fine black sediment with
small wood fibers, slight
H?S odor, water slightly
cloudy, slight oil sheen
on surface.

Fine black sediment with
small wood pieces, strong
H2S odor, water cloudy,
slight oil sheen on surface.
88390119
26
6.92
169
 88390120
28
7.05
169
 88390121
31
6.58
170
Fine black sediment with
many small/large wood
fibers and pieces, slight
H2S odor, water clear,
slight oil sheen on surface.

Fine black sediment with
many large wood chips and
pieces, strong ^S odor,
water cloudy, slight oil
sheen on surface.

Fine black sediment with
pulp-like wood fibers,
strong H2S odor, water
clear.
                                            D-18

-------
   WESTEC SERVICES






BIOASSAY LABORATORY

-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619) 458-1644
WBLTestNo.:      88126              Sample ID:          Ward Cove - Main

Facility Name:       Ward Cove, Alaska

Facility Location:    c/oEPAX                                    _.. ,.--
                   12006thAvenue                              '., ;:; .' •-
                   Seattle, WA  98101                            fa."'

Bioassay Specifications
                                                              A "• '!• ;•> p
Effluent Type:       Final, pulp mill effluent
Test Type/Duration:  Chronic/Sperm Fertilization  1.5 hours

Test Organism;      common name:       purple sea urchin
                   scientific name:       Strongylocentrotus purpuratus

Summary of Final Results

Test Starting Date:   8/23/88             Completion Date:            8/23/88
LC50/EC50:        N/A                95% confidence intervals:     N/A
NOEC:            <4.8%             LOEC:                    4.8%

Calculation Method:  LCso/ECso:         N/A
                   NOEC/LOEC:       Dunnett's Procedure

Quality Control Summary

Control Mortality:   N/A
Temperature maintained:                  yes
Dissolved oxygen maintained above minimum for test type:        yes
All test acceptibility requirements met:       yes - control fertilization was between 60 -
                                       90%

Test Organisms Data

Organism Source:    Collected Mission Bay, San Diego, CA
Acclimation Period:   >14 days            Acclimation Mortality:       0
Organism Age at beginning of Test:         N/A
                                       D-19

-------
Test Design
Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:

Method of Preparation:
                    5
                    4
                    Sperm to egg ratio of 200:1
                    10ml
                    EPA X personnel
                    grab
                    8/22/88
                    24 hours
                    Federal Express
                    WBL seawater collected from Mission Bay at
                    Hubbs Research Center
                    filtered to 0.45(im
 Test Certification
Laboratory Manager:

Date:     I

Analyst:

Date:

                                                              any Snyder
                                                            AlanMonji
                                      D-20

-------
cone.
                            WESTEC Bioassay Laboratory
                            Echinoderm Sperm Fertilization  Bioassay Summary
               WBL Test #
                           88126
Sample ID. #  Ward Cove  Main
rep.   # eggs fertilized # eggs unfertilized  %  unfertilized  avg.  unfertilized
control



salinity
control


4.8%



9.6%



19.2%



38.5%



76.9%



a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
tf
a
b
c
d
a
b
c
d
87
86
79
90
81
88
90
85
62
72
48
72
50
57
60
37
0
2
0
0
0
0
0
0
1
0
0
0
13
1 5
21
1 0
1 9
1 2
1 0
1 5
38
28
52
28
50
43
40
62
100
98
100
1 00
1 00
100
1 00
100
99
1 00
100
1 00
13.0%
15.0%
21.0%
10.0%
19.0%
12.0%
10.0%
15.0%
38.0%
28.0%
52.0%
28.0%
50.0%
43.0%
40.0%
62.0%
100.0%
98.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
99.0%
100.0%
100.0%
100.0%
                                                                      14.8%
                                                                      14.0%
                                                                      36.5%
                                                                      48.8%
                                                                      99.5%
                                                                     100.0%
                                                                      99.8%
                                             D-21

-------
  REVISION  1.00      5/1/87
          THE DUNNETT COMPARISON  OF  EACH CONCENTRATION
 1EAN VS THE CONTROL MEAN. UP TO  SEVEN  CONCENTRATIONS               /•"•  /      ^        Tx -/
 (INCLUDING THE CONTROL) AND UP TO TEN  REPLICATES                  OChwO(&^'rl   '  *
 KAY BE USED.

 A ONE SIDED 'T' AT 95V. IS ASSUMED  IN ALL CASES.

 THE TRANSFORMATIONS WHICH MAY BE USED  ON THE DATA ARE:

 NUMBER     TRANSFORMATION
  0       NONE
  1       SQUARE ROOT(X)
  3       LOGNKX)
  5       (ARCSIN(SQ. RT(X)/(N+1)+
          ARCSIN(SQ. RT"0.5>
          NOTE    :
                     THE LIMITS OF SIN ARE +/- 1 .
  7       ALGAL ANALYSIS - NO TRANSFORMATION

 • E S U L T S   OF    SEQUENTIAL   COMPARISONS
        USING    THE    D  U N N  E T T ' S   TEST

 CALCULATED DUNNETT T  VALUES

 lONCENTRATION   CALC DUNNETT T

 2             .1989224
 3            -5.108259
 4            -7.623344
 5            -21.94471
 4            -22.40015
 7            -22.15157

 TABULATED  DUNNETT T =   2.45

 MTE: H  TABULATED  DUNNETT   T   is  greater  than  the
     CALCULATED DUNNETT  T,  THERE IS NO SIGNIFICANT
     DIFFERENCE between  that  CONCENTRATION and  the
     CONTROL.  H  the   TABULATED  DUNNETT T  is  less
     than  the  CALCULATED DUNNETT  T,   then THERE IS
     SIGNIFICANT   DIFFERENCE  between  that  CONCEN-
     TRATION  and  the  CONTROL.

For this   set  of data, the  MINIMUM SIGNIFICANT  DIFFERENCE   is   0.075.
This represents a  51 . 1.X reduction o-f the mean response  from the CONTROL.

 There is NO S I GN I F I CANT  DIFFERENCE between CONCENTRATION 2 and -CONT

=>There  IS  A SIGNIFICANT  DIFFERENCE between CONCENTRATION 3 and CONT

=>There  IS  A SIGNIFICANT  DIFFERENCE between CONCENTRATION 4 and CONT

=>There  IS  A SIGNIFICANT  DIFFERENCE between CONCENTRATION 5 and CONT

=>There  IS  A SIGNIFICANT  DIFFERENCE between CONCENTRATION 6 and CONT

=>There  IS  A SIGNIHCAiv!  DIFFERENCE between CONCENTRATION 7 and CONT

     INPUT   DATA   TABLE       D_22

-------
0.19
0.38
0.50
1.00
1.00
0.99
U.12
0.28
0.43
0.98
1.00
1.00
U.1U
0.53
0.40
1.00
1.00
1 .00
U.I 3
0.28
0.63
1 .00
1.00
1 .00
 RANSFORMED   DATA    TABLE

 NOTEiTRANSFQRMATloN NUMBER~6~WAS
     USED  FOR THIS SET OF  DATA.
0.37
0.45
0.66
0.79
1.52
1.52
0.40
0.35
0.56
0.72
1.43
1.52
0.48
0.32
0.82
0.68
1 .52
1 .52
0.32
0.40
0.56
0.92
1 .52
1 .52
  1.47    1.52     1.52     1.52

                A N 0 V  A   TABLE
surce   DF    Sum o-f Sq .     Mean Sq .     Calc F  Tab F<0.05)

'iONn     e,        c.'^o        1.129     222.017     2.570
i~L"'-   2!        O.IC^        0.005
                                            D-23

-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619)  458-1644
WBLTestNo.:      88127              Sample ID:          Ward Cove  Primary

Facility Name:       Ward Cove, Alaska

Facility Location:    c/o EPA X
                    1200 6th Avenue
                   Seattle, WA 98101                            f:>«'/ '.;_-..*
                                                                 * .- i '*•"
Bioassay Specifications                                            ;-  ;
	                                                             n ov  o;<
Effluent Type:       Final, pulp mill effluent                           . (,,....,...,
Test Type/Duration:   Chronic/Sperm Fertilization  1.5 hours                  ;''" V
                                                                       .;;.,- .-7; - :;
Test Organism;       common name:      purple sea urchin
                    scientific name:      Strongylocentrotus purpuratus

Summary of Final Results

Test Starting Date:    8/23/88            Completion Date:           8/23/88
LC50/EC50:         N/A               95% confidence intervals:    N/A
NOEC:             <4.8%             LOEC:                    4.8%

Calculation Method:   LCsQ/ECso:         N/A
                    NOEC/LOEC:       Dunnett's Procedure

Quality Control Summary

Control Mortality:    N/A
Temperature maintained:                  yes
Dissolved oxygen maintained above minimum for test type:        yes
All test acceptibility requirements met:      yes - control fertilization was between 60 -
                                       90%

Test Organisms Data

 Organism Source:    Collected Mission Bay, San Diego, CA
Acclimation Period:   >14 days           Acclimation Mortality:       0
 Organism Age at beginning of Test:        N/A
                                        D-24

-------
Test Design

Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:

Method of Preparation:
5
4
Sperm to egg ratio of 200:1
10ml
EPA X personnel
grab
8/22/88
24 hours
Federal Express
WBL seawater collected from Mission Bay at
Hubbs Research Center
filtered to 0.45|im
 Test Certification
                     Laboratory Manager:

                     Date:        \\ \\

                     Analyst:

                     Date:       ///i/^V
            iv/W" t^OC'1- n     o  J
            •'v"/(^  Bany Snyder




                    Alan Monji
                                        D-25

-------
cone.
                     WESTEC Bioassay Laboratory
                     Echinoderm Sperm Fertilization Bioassay Summary

        WBLTesttf         88127       Sample ID. #  Ward Cove   Primary

rep.   # eggs fertilized # eggs  unfertilized  %  unfertilized avg. unfertilized
control



salinity
control


4.8%



9.6%



19.2%



38.5%



76.9%



a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
dr
a
b
c
d
a
b
c
d
87
86
79
90
81
88
90
85
78
74
67
56
42
28
31
29
2
2
4
1
0
0
0
0
0
1
0
0
1 3
1 5
21
1 0
1 9
1 2
1 0
1 5
22
26
33
44
58
72
69
71
98
98
96
99
1 00
100
100
100
100
99
1 00
1 00
13.0%
15.0%
21.0%
10.0%
19.0%
12.0%
10.0%
15.0%
22.0%
26.0%
33.0%
44.0%
58.0%
72.0%
69.0%
71.0%
98.0%
98.0%
96.0%
99.0%
100.0%
100.0%
100.0%
100.0%
100.0%
99.0%
100.0%
100.0%
                                                                     14.8%
                                                                     14.0%
                                                                     31 .2%
                                                                     67.5%
                                                                     97.8%
                                                                    100.0%
                                                                     99.8%
                                             D-26

-------
     ;:CN   1.00       5/1/87
ANOVA-UITH  THE  DUNNETT COMPARISON OF EACH  CONCENTRATION
MEAN MS THE CONTROL MEAN. UP TO SEVEN  CONCENTRATIONS              ,
(INCLUDING  THE  CONTROL) AND UP TO TEN  REPLICATES              CAftAjb (7&\
MAY BE USED.                                                    ^-^

A ONE SIDED 'T' AT 95X IS ASSUMED IN ALL CASES.

THE TRANSFORMATIONS WHICH MAY BE USED  ON THE DATA ARE:

NUMBER     TRANSFORMATION
  0        NONE
  1        SQUARE ROOT(X)
  3        LOGIO(X)
  5        
          NOTE    :
                     THE LIMITS OF SIN ARE +/- 1.
  7        ALGAL ANALYSIS - NO  TRANSFORMATION

RESULTS   OF    SEQUENTIAL    COMPARISONS
        USING    THE    DUNNETT   S   TEST

 CALCULATED DUNNETT T  VALUES

CONCENTRATION   CALC  DUNNETT T

 2             .2373651
 3           -4.70918
 4           -13,53716
 5           -24.45033
 6           -26.72909
 1           -26.43247

TABULATED DUNNETT T =   2.45

NOTE:  I-f TABULATED   DUNNETT   T  is  greater  than  the
     CALCULATED  DUNNETT  T, THERE  IS NO SIGNIFICANT
     DIFFERENCE  between  that  CONCENTRATION and  the
     CONTROL.  If  the   TABULATED  DUNNETT T  is less
     than  the   CALCULATED  DUNNETT  T,  then  THERE  IS
     SIGNIFICANT   DIFFERENCE  between  that   CONCEN-
     TRATION and  the  CONTROL.

For this set o-f  data, the   MINIMUM SIGNIFICANT  DIFFERENCE    is    0.065.
This represents a  44. OX reduction  o-f the mean  response  -from  the  CONTROL.

 There is NO SIGNIFICANT  DIFFERENCE between CONCENTRATION  2  and_CONT

=>There IS  A SIGNIFI CANT  DIFFERENCE between CONCENTRATION  3  and  CONT

=>There IS  A SIGNIFICANT  DIFFERENCE between CONCENTRATION  4  and  CONT

=>There IS  A SIGNIFICANT  DIFFERENCE between CONCENTRATION  5  and  CONT

=>There IS  A SIGNIFI CANT  DIFFERENCE between  CONCENTRATION  6  and  CONT

OThere IS  A SIGNIFICANT  DIFFERENCE between  CONCENTRATION  7  and  CONT

     INPUT   DATA   TABLE        D-27

-------
u.i*
0.22
0.58
0.98
1.00
u.i^:
0.26
0.72
0.98
1.00
U . 1U
0.33
0.69
0.96
1.00
U. 13
0.44
0.71
0.99
1.00
  i.OO    0.99     1.00    1.00

 RANSFORMED   DATA   TABLE

 NOTETTRANSFORMATlON NUMBER~6~WAS
     USED  FOR THIS SET OF DATA.

  0.37    0.40    0.48    0.32
  0.45    0.35    0.32    0.40
  0.49    0.54    0.61    0.73
  0.87    1.01    0.98    1.00
   1.43    1.43    1.37    1.47
   1.52    1.52    1.52    1.52
   1.52    1.47    1.52    1.52

                 A NOVA    TABLE
Source    DF    Sum  o-f  Sq .     Mean Sq .     Calc F  Tab  F(0.05)

ttONG     6         6.504        1.084    303.408     2.570
•IITHIN    21         0.075        0.004
TOTAL    27         6.579
                                             D-28

-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619) 458-1644
WBL Test No.:      88128              Sample ID:          Ward Cove - Secondary

Facility Name:       Ward Cove, Alaska

Facility Location:    c/o EPA X                                    ...--;"    < ..
                   1200 6th Avenue                               ,  .       ,  :..
                   Seattle, WA 98101                             O/j.

Bioassav Specifications                                                   '"  '' 'J

Effluent Type:       Final, pulp mill effluent                                   '""' '*'•''
Test Type/Duration:  Chronic/Sperm Fertilization  1.5 hours                       ''

Test Organism;      common name:      purple sea urchin
                   scientific name:      Strongylocentrotus purpuratus

Summary of Final Results

Test Starting Date:    8/23/88             Completion Date:            8/23/88
LC50/EC50:        N/A               95% confidence intervals:    N/A
NOEC:             <4.8%             LOEC:                    4.8%

Calculation Method:   LCso/ECsQ:         N/A
                    NOEC/LOEC:       Dunnett's Procedure

Quality Control Summary

Control Mortality:    N/A
Temperature maintained:                  yes
Dissolved oxygen maintained above minimum for test type:        yes
All test acceptibility requirements met:      yes - control fertilization was between 60 -
                                       90%

Test Organisms Data

Organism Source:    Collected  Mission Bay, San Diego, CA
Acclimation Period:   > 14 days            Acclimation Mortality:       0
Organism Age at beginning of Test:         N/A
                                      D-29

-------
Test Design

Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:

Method of Preparation:
5
4
Sperm to egg ratio of 200:1
10ml
EPA X personnel
grab
8/22/88
24 hours
Federal Express
WBL seawater collected from Mission Bay at
Hubbs Research Center
filtered to 0.45|im
 Test Certification
                     Laboratory Manager:

                     Date:             ii 1*188
                     Analyst:

                     Date:
                    Barry Snyder



                    Alan Monji
                                        D-30

-------
cone.
                            WESTEC Bioassay Laboratory
                            Echinoderm Sperm Fertilization Bioassay Summary
               WBL Test #   88128
                                        Sample ID. #  Ward Cove  Secc
rep.   # eggs fertilized # eggs  unfertilized %  unfertilized avg. unfertilized
control



salinity
control


4.8%



9.6%



19.2%



38.5%



76.9%



a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
87
86
79
90
81
88
90
85
45
50
49
4 1
4
0
0
1 2
0
0
0
0
0
0
0
0
0
0
0
0
1 3
1 5
21
1 0
1 9
1 2
1 0
1 5
22
26
33
44
96
1 00
100
88
100
1 00
100
1 00
100
100
1 00
100
100
1 00
100
1 00
13.0%
15.0%
21.0%
10.0%
19.0%
12.0%
10.0%
15.0%
22.0%
26.0%
33.0%
44.0%
96.0%
100.0%
100.0%
88.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
                                                                     14.8%
                                                                     14.0%
                                                                     31.2%
                                                                     96.0%
                                                                    100.0%
                                                                    100.0%
                                                                    100.0%
                                             D-31

-------
                                                                    #
  REVISION  1.00      5/1/87
ANQVA-WITH THE DUNNETT COMPARISON OF  EACH  CONCENTRATION
MEAN VS THE CONTROL MEAN. UP TO SEMEN CONCENTRATIONS
(INCLUDING THE CONTROL) AND UP TO TEN REPLICATES
HAY BE USED.

A ONE SIDED 'T' AT 95X IS ASSUMED IN  ALL CASES.

THE TRANSFORMATIONS WHICH MAY BE L^^ ON THE DATA ARE:

NUMBER     TRANSFORMAT I ON
  0       NONE
  i       SQUARE ROOT(X)
  3       LOGIO(X)
  5       There IS A SIGNIFICANT  DIFFERENCE between  CONCENTRATION 3 and CONT

=>There IS A SIGNIFICANT  DIFFERENCE between  CONCENTRATION 4 and CQNT

=>There IS A SIGNIFICANT  DIFFERENCE between  CONCENTRATION 5 and CONT

=>There IS A SIGNIFICANT  DIFFERENCE between  CONCENTRATION 6 and CONT

=>There IS A SIGNIFICANT  DIFFERENCE between  CONCENTRATION 7 and CONT

     INPUT   DATA   TABLE        D-32

-------
0.1?
0.50
0.96
1.00
1.00
1.00
0.12
0.50
1.00
1 .00
1.00
1.00
0.10
0.51
1.00
1 .00
1.00
1 .00
0.15
0.5?
0.88
1 .00
1 .00
1 .00
 RANSFQRMED    DATA   TABLE
                    NUMBER6WAS
     USED   FOR THIS SET OF DATA.
  0.37    0.40     0.48    0.32
0
0
1
1
1
1
.45
.79
.37
.52
.52
.52
0
0
1
1
1
1
.35
.79
.52
.52
.52
.52
0
0
1
1
1
1
.32
.80
.52
.52
.52
.52
0
0
1
1
1
1
.40
.88
.22
.52
.52
.52
                 AN QUA   TABLE
ource   DF    Sum o-f Sq.     Mean Sq .     Calc  F  Tab FO3.05)

MONG     6        6.902       1.150     265.055     2.570
HTHIN   21        0.091       0.004
'DIAL    27        6.993
                                            D-33

-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619) 458-1644
WBLTestNo.:       88185              Sample ID:          Ward Cove - 88390101
                                                          (Main 001)
Facility Name:        Ward Cove, Alaska

Facility Location:     c/o EPA X
                    1200 6th Avenue                                   .-..-,,..-.>-
                    Seattle, WA 98101                        ^.,.:"

BioassavSpecifications                                        :; \            ,,-.,,,
	   	                                        '••'"'""   iiiiV H-^Mo'
Effluent Type:        Final, pulp mill effluent
Test Type/Duration:   Chronic/Sperm Fertilization - 1.5 hours       ,  ••• r    , '- ^

Test Organism;       common name:      purple sea urchin
                    scientific name:      Strongylocentrotus purpuratus

Summary of Final Results

Test Starting Date:    9/22/88             Completion Date:            9/22/88
LC50/EC50:         N/A                95% confidence intervals:    N/A
NOEC:              4.8%               LOEC:                    9.6%

Calculation Method:   LC50/EC50:         N/A
                    NOEC/LOEC:       Dunnett's Procedure

Quality Control Summary

Control Mortality:    N/A
Temperature maintained:                  yes
Dissolved oxygen maintained above minimum for test type:        yes
All test acceptibility requirements met:      yes - control fertilization was between 60 -
                                       90%

Test Organisms Data

Organism Source:    Collected - Mission Bay, San Diego, CA
Acclimation Period:   > 14 days            Acclimation Mortality:       0
Organism Age at beginning of Test:         N/A
                                       D-34

-------
Test Design

Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:

Method of Preparation:
5
4
Sperm to egg ratio of 200:1
10ml
EPA X personnel
composite
9/20/88
48 hours
Alaska Airlines
WBL seawater collected from Mission Bay at
Hubbs Research Center
filtered to 0.45|im
 Test Certification
                     Laboratory Manager.

                     Date:

                     Analyst:

                     Date:           n / *• fa
                    'Barry Snyder



                    Alan Monji


                      '   AA^^y
                                         D-35

-------
                           WESTEC Bioassay Laboratory
                           Echinoderm Sperm Fertilization Bioassay Summary
              WBLTest*        88185       Sample ID. #      88390101

cone.    rep.  # eggs  fertilized # eggs unfertilized % unfertilized  avg. unfertilized
control



salinity
control


4.8%



9.6%



19.2%



38.5%



76.9%



a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
cr
a
b
c
d
a
b
c
d
89
76
69
86
93
87
84
86
84
80
76
78
52
69
57
52
1 6
2 1
3 1
1 4
0
0
0
0
0
0
0
0
1 1
24
31
1 4
7
1 3
1 6
1 4
1 6
20
24
22
48
31
43
48
84
79
69
86
100
1 00
100
100
1 00
1 00
100
1 00
1 1 .0%
24.0%
31.0%
14.0%
7.0%
13.0%
16.0%
14.0%
16.0%
20.0%
24.0%
22.0%
48.0%
31.0%
43.0%
48.0%
84.0%
79.0%
69.0%
86.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
                                                                   20.0%
                                                                   12.5%
                                                                   20.5%
                                                                   42.5%
                                                                   79.5%
                                                                  100.0%
                                                                  100.0%
                                            D-36

-------
  REVISION  1.00      5/1/87
ANtWA-WITH THE DUNNETT COMPARISON  OF  EACH CONCENTRATION     ftPfiO ,n t
MEAN VS THE CONTROL MEAN. UP TO SEVEN CONCENTRATIONS        U(/J I U I
(INCLUDING THE CONTROL) AND UP TO  TEN REPLICATES
MAY BE USED.

A ONE SIDED 'T' AT 95X IS ASSUMED  IN  ALL CASES.

THE TRANSFORMATIONS WHICH MAY BE USED ON THE DATA ARE:

NUMBER     TRANSFORMATION
  0        NONE
  1        SQUARE ROOT(X)
  3        LOGIO(X)
  5        ':ARCSIN/ +
          ARCSIN(SQ. RTThere IS A SIGNIFICANT  DIFFERENCE between CONCENTRATION  4  and  CONT

=''There IS A SIGNIFICANT  DIFFERENCE between CONCENTRATION  5  and  CONT

=>There IS A SIGNIFICANT  DIFFERENCE between CONCENTRATION  6  and  CONT

=>There IS A SIGNIFI CANT  DIFFERENCE between CONCENTRATION  7  and  CONT

     INPUT   DATA   TABLE        D-37

-------
o.u
0.48
0.84
1.00
1.00
0.20
0.31
0.79
1.00
1.00
0.24
0.43
0.69
1.00
1.00
0.22
0.48
0.86
1 .00
1 .00
 RANSFORMED   DATA    TABLE

 NOTETTRANSFORMATlON NUMBER~6~WAS
     USED  FOR THIS SET OF  DATA.

   0.34    0.51    0.59    0.38
0.27
0.41
0.77
1.16
1.52
1.52
0.37
0.46
0.59
1.09
1.52
1.52
0.41
0.51
0.72
0.98
1.52
1.52
0.38
0.49
0.77
1 .19
1 .52
1.52
                 A N  0 V A   TABLE
Source   DF     Sum  o-f  Sq.     Mean Sq.    Calc  F   Tab F<0.05)

WONG     6         6.090       1.015    205.893      2.570
4ITH1N   21         0.104       0.005
TOTAL    27         6.194
                                             D-38

-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619) 458-1644
WBLTestNo.:      88186              Sample ID:          Ward Cove - 88390104
                                                          (Primary 002A)
Facility Name:       Ward Cove, Alaska

Facility Location:    c/o EPA X
                   1200 6th Avenue
                   Seattle, WA 98101                              . , \  :f :    :
                                                             '"'••">  v  •.'.'.>'.-.'••
Bioassay Specifications                                           (!

Effluent Type:       Final, pulp mill effluent                            ' ! ! w  :-'   ' H? '
Test Type/Duration:  Chronic/Sperm Fertilization - 1.5 hours

Test Organism;      common name:      purple sea urchin              : '
                   scientific name:      Strongylocentrotus purpuratus

Summary of Final Results

Test Starting Date:   9/22/88             Completion Date:            9/22/88
LC50/EC50:        N/A                95% confidence intervals:    N/A
NOEC:            4.8%               LOEC:                    9.6%
 Calculation Method:   LCso/ECsQ:         N/A
                    NOEC/LOEC:       Dunnett's Procedure

 Quality Control Summary

 Control Mortality:    N/A
 Temperature maintained:                  yes
 Dissolved oxygen maintained above minimum for test type:        yes
 All test acceptibility requirements met:      yes - control fertilization was between 60 -
                                       90%

 Test Organisms Data

 Organism Source:    Collected  Mission Bay, San Diego, CA
 Acclimation Period:   >l4days           Acclimation Mortality:       0
 Organism Age at beginning of Test:         N/A
                                       D-39

-------
Test Design
Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:

Method of Preparation:
                    5
                    4
                    Sperm to egg ratio of 200:1
                    10ml
                    EPA X personnel
                    composite
                    9/20/88
                    48 hours
                    Alaska Airlines
                    WBL seawater collected from Mission Bay at
                    Hubbs Research Center
                    filtered to 0.45}im
 Test Certification
                     i  -j   -
Laboratory Manager:   £) L-iAAw
                         • , ^'
Date:              /,/; /^

Analyst:

Date:
                                                        I
                                                        ^-
                                                             Barry Snyder



                                                             Alan Monji
                                         D-40

-------
                           WESTEC Bioassay Laboratory
                           Echinoderm Sperm Fertilization Bioassay Summary

              WBLTesttf        88186       Sample ID. #      88390104

cone.    rep.   # eggs fertilized # eggs unfertilized  %  unfertilized avg. unfertilized
control



salinity
control


4.8%



9.6%



19.2%



38.5%



76.9%



a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
89
76
69
86
93
87
84
86
57
73
86
81
52
51
42
63
3
4
9
1 6
0
0
0
0
0
0
0
0
1 1
24
31
1 4
7
13
1 6
14
43
27
1 4
1 9
48
49
58
37
97
96
9 1
84
100
100
100
1 00
1 00
100
100
1 00
1 1 .0%
24.0%
31.0%
14.0%
7.0%
13.0%
16.0%
14.0%
43.0%
27.0%
14.0%
19.0%
48.0%
49.0%
58.0%
37.0%
97.0%
96.0%
91.0%
84.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
                                                                    20.0%
                                                                    12.5%
                                                                    25.8%
                                                                    48.0%
                                                                     92.0%
                                                                    100.0%
                                                                    100.0%
                                             D-41

-------
 REVISION  1.00      5/1/87
NOYA-UITH THE DUNNETT COMPARISON OF EACH CONCENTRATION      Q Q    Q fll ftd-
1EAN VS THE CONTROL MEAN.  UP  TO SEVEN CONCENTRATIONS         U O  5 /      ^
'INCLUDING THE CONTROL) AND UP TO TEN REPLICATES               x-   /       /
IAY BE USED .                                                  zr£ k^y^O C&*

\ WE SIDED 'T' AT 95X  IS  ASSUMED IN ALL CASES.                  X  Q, (.0*4!$-

THE TRANSFORMATIONS WHICH  MAY BE USED ON THE DATA ARE:

1UM6ER     TRANSFORMATION
 0        NONE
 1        SQUARE  ROOT(X)
 3        LOGIO(X)
 5       (ARCSIN(SQ.  RT':X)/(N+i) +
          ARCSIN(SQ.  RTCXM )/(N-H)))/2
 6        ARCSIN(O<) -0.5)
          NOTE   :
                     THE LIMITS OF  SIN ARE  +/- 1.
  7        ALGAL ANALYSIS - NO TRANSFORMATION

 ESULTS   OF   SEQUENTIAL    COMPARISONS
        USING   THE    DUNNETT'S   TEST

 CALCULATED DUNNETT T VALUES

lONCENTRATION   CALC DUNNETT T

 2            1.53299
 3           -i.06286
 4           -4.830256
 5           -13.156
 4           -16.63912
 7           -16.63912

TABULATED DUNNETT T =  2.45

WTE: If  TABULATED  DUNNETT   T is  greater than the
     CALCULATED DUNNETT T. THERE IS NO SIGNIFICANT
     DIFFERENCE between  that  CONCENTRATION and the
     CONTROL. I-f  the  TABULATED  DUNNETT T is  less
     than  the  CALCULATED DUNNETT  T, then THERE IS
     SIGNIFICANT  DIFFERENCE bet^esr. that  CONCEN-
     TRATION and  the CONTROL.

For this   set o-f data,  the MINIMUM SIGNIFICANT DIFFERENCE   is    0.107.
This represents a  53.57.  reduction o-f the mean  response -from  the  CONTROL.

 There is NO SI Gf 41FI CANT  DIFFERENCE between CONCENTRATION 2  and-COT-IT
 There is NO SIGNIFICANT  DIFFERENCE between CONCENTRATION 3  and  CONT

=>There  IS  A SIGNIFICANT  DIFFERENCE between CONCENTRATION 4  and  CONT

=>There  IS  A SIGNIFICANT  DIFFERENCE between CONCENTRATION 5  and  CONT

=>There  IS  A SIGNIFICANT  DIFFERENCE between CONCENTRATION 6  and  CONT

=>There  IS  A SIGNIFICANT  DIFFERENCE between CONCENTRATION 7  and  CONT

     INPUT    DATA   TABLE       D-42

-------
U .4J
0.48
0.97
1.00
1.00
U .£.(
0.49
0.?6
1 .00
1 .00
u . 11
0.5S
0.91
1 .00
1 .00
u . i y
0.37
0.84
1 .00
1 .00
=  FORMED   DATA
                                  ABLE
NOTE:TRANSFORMATION NUMBER  6  WAS
    USED  FOR THIS SET  OF  DATA.
  0.77
  1.40
  1.52
  1.52
0.51
0.37
0 . 55
0.78
1 .37
1 .52
1 .52
0.59
0.41
0.38
0.87
1 .27
1 .52
1 .52
0.38
0.38
0.45
0.65
1.16
1 .52
1 .52
                 A N 0
        OF
WONG     6
.-ilTHIN   21
TOTAL    27
Sum o-f Sq.

    6.307
    0.172
    6.479
                        TABLE
                      Mean Sq .

                        1.051
                        0.008
                                        Calc F  Tab F(0.05)

                                       128.344     2.570
                                           D-43

-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619) 458-1644
WBLTestNo.:      88187               Sample ID:          Ward Cove - 88390107
                                                          (Secondary 002B)
Facility Name:       Ward Cove, Alaska

Facility Location:     c/o EPA X
                   1200 6th Avenue
                   Seattle, WA 98101

Bioassay Specifications                                                        ._..
                                                                         .-- - " u

Effluent Type:       Final, pulp  mill effluent                           •• "] -,' y -
Test Type/Duration:  Chronic/Sperm Fertilization - 1.5 hours              ',;(.""
                                                                   vw*   uoV
Test Organism;      common name:      purple sea urchin
                   scientific name:      Strongylocentrotus purpuratus  ..... -,~ ? •-_.;;• ',-.;> f
                                                                           1 1  • - -
Summary of Final Results

Test Starting Date:   9/22/88             Completion Date:           9/22/88
LC50/EC50:        N/A                95% confidence intervals:    N/A
NOEC:            <4.8%             LOEC:                    4.8%
 Calculation Method:   LCso/ECsQ:        N/A
                    NOEC/LOEC:       Dunnett's Procedure

 Quality Control Summary

 Control Mortality:    N/A
 Temperature maintained:                  yes
 Dissolved oxygen maintained above minimum for test type:        yes
 All test acceptibility requirements met:      yes - control fertilization was between 60 -
                                       90%

 Test Organisms Data

 Organism Source:    Collected  Mission Bay, San Diego, CA
 Acclimation Period:   > 14 days            Acclimation Mortality:       0
 Organism Age at beginning of Test:         N/A
                                      D-44

-------
Test Design

Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:

Method of Preparation:
Sperm to egg ratio of 200:1
10ml
EPA X personnel
composite
9/20/88
48 hours
Alaska Airlines
WBL seawater collected from Mission Bay at
Hubbs Research Center
filtered to 0.45jim
 Test Certification
                     Laboratory Manager:

                     Date:          ////

                     Analyst:

                     Date:          /
                    Barry Snyder



                    Alan Monji

                    ^  T
                                        D-45

-------
                           WESTEC Bioassay Laboratory
                           Echinoderm Sperm Fertilization Bioassay Summary

              WBL Test #        88187        Sample ID. #      88390107

cone.    rep.   # eggs fertilized # eggs unfertilized  % unfertilized  avg. unfertilized
control



salinity
control


4.8%



9.6%



19.2%



38.5%



76.9%



a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
a
b
c
d
89
76
69
86
93
87
84
86
61
60
42
39
28
20
1 8
36
0
0
0
1
0
0
0
0
0
0
0
0
1 1
24
31
1 4
7
1 3
1 6
1 4
39
40
58
61
72
80
82
64
100
1 00
1 00
99
1 00
100
100
100
1 00
100
100
1 00
1 1 .0%
24.0%
31.0%
14.0%
7.0%
13.0%
16.0%
14.0%
39.0%
40.0%
58.0%
61.0%
72.0%
80.0%
82.0%
64.0%
100.0%
100.0%
100.0%
99.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
                                                                    20.0%
                                                                    12.5%
                                                                    49.5%
                                                                    74.5%
                                                                    99.8%
                                                                   100.0%
                                                                   100.0%
                                            D-46

-------
                                                                     0&/0
        THE CONTROL)  AND UP TO TEN REPLICATES               ,    .
,Y BE USED.                                                  ^™
 ONE SIDED 'T-' AT 95X IS ASSL1MED  IN ALL  CASES.                $$3*?
                                                                               M/-
'HE
TRANSFORMATIONS WHICH MAY BE USED ON THE DATA ARE:
(UMBER     TRANSFORMATION                                                  ,
 0       NONE                                                /  ${.CO*IS-
 j       SQUARE  ROOKX)                                      L
 -       LOG1 OCX)
 5      (ARCSIN(SQ.  RTThere IS A SIGNIFICANT DIFFERENCE  between  CONCENTRATION 3 and CONT

 :>There IS A SIGNIFICANT DIFFERENCE  between  CONCENTRATION 4 and "CONT

 :>There IS A SIGNIFI CAT4T DIFFERENCE  between CONCENTRATION 5 and CONT

 =>There IS A SIGNIFICANT DIFFERENCE  between CONCENTRATION 6 and CONT

 =>There IS A SIGNIFICANT DIFFERENCE  between CONCENTRATION 7  and CONT

       INPUT   DATA    TABLE

                                             D-47
0.11
0.07
0.39
0.24
0.13
0.40
0.31
0.16
0.58
0.14
0.14
0.61

-------
  i.oo     i.oo     i.oo     i.oo
  1.00     1.00     1.00     1.00

RANSFORMED    DATA   TABLE

NOTETTRANSFORMATlON NUMBER~6~WAS
     USED   FOR THIS SET  OF DATA.
0.34
0.27
0.67
1.01
1.52
1.52
1.52
0.51
0.37
0.68
1 .11
1.52
! .52
1.52
0.59
0.41
0.87
1 .13
1.52
1 .52
1 .52
0.38
0.38
0.90
0.93
1 .47
r.52
1 .52
                 A N 0 I.' A   TABLE
:urce   DF    Sum o-f  Sq .     Mean Sq.     Calc F  Tab FvO.OS)

10N6     6        6.21c.       1.036     179.004     2.570
ITHIN   2:        0.122       0.006
3TAL    27        6.338
                                            D-48

-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619) 458-1644
WBLTestNo.:      88182             Sample ID:         Ward Cove - 88390105
                                                         (Primary 002A)
Facility Name:       Ward Cove, Alaska

Facility Location:     c/o EPA X
                   1200 6th Avenue
                   Seattle, WA  98101

BioassaySpecifications                                          •'•"; ;  -.;     ;,::, ;

Effluent Type:       Final, pulp mill effluent                       •-•••-   y,^--  O'Mr
Test Type/Duration:  Static acute - 96hours                               "*'-''•'  '-''' '3

Test Organism;      common name:      rainbow trout          "     ''''',
                   scientific name:      Salmo gairdneri

Summary of Final Results

Test Starting Date:   9/22/88            Completion Date:           9/26/88
LC50/EC50:        35.3% effluent      95% confidence intervals:    27.8% - 46.9%
NOEC:            N/A               LOEC:                    N/A
 Calculation Method:   LC^Q/EC^Q:         Moving Average
                    NOEC/LOEC:       N/A

 Quality Control Summary

 Control Mortality:     5 %
 Temperature maintained:                  yes
 Dissolved oxygen maintained above minimum for test type:        yes
 All test acceptibility requirements met:       yes - control mortality less than 10%

 Test Organisms Data

 Organism Source:     Thomas Fish Farm, Novato, CA
 Acclimation Period:   7 days              Acclimation Mortality:        <1.0%
 Organism Age at beginning of Test:         approx. 30 days
                                      D-49

-------
Test Design
Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:
Method of Preparation:

 Mortality Data (percent mortality)
Test Concentration
control

6.25%

12.5%

- 25.0%

50.0%

100%

rep.
a
b
a
b
a
b
a
b
a
b
a
b
%Moi
10
0
10
0
0
10
0
10
70
100
100
100
                   5
                   2
                   10
                   2 liters
                   EPA X personnel
                   grab
                   9/20/88
                   48 hours
                   Alaska Airlines
                   WBL laboratory grade freshwater
                   charcoal filtered and aerated
                                                       Avg. Mortality (%}


                                                                5

                                                                5

                                                                5

                                                                5

                                                               85

                                                              100
  Test Certification
Laboratory Manager:

Date:         ///2

Analyst:

Date:        /' A
                                                                    Snyder
                                                                   MonJi

                                          D-50

-------
                                       DATA SHEET  FOR  EFFLUENT TOXICITY TEST.
     Indullly •To.iclnl ^"Pft X    /. Jnrr.l  f'^.lf  H ft* .^ ^ p 7/0
     Add....
                                                                                                     Tlm"
     Elllucnt Stiiil Number
     NPDES fermil Nurnbci
Beginning:
Ending:    n... !l/lf- — T I m e
    Of9»ni»m
Ten Tempeiiture fling « li ° - 3.°?^
^onc.
Ot
%
A/*-"

(.•i'S'f.

li. 
\Q
Io
l«
I"
lu
K?
10




24
(O

/O
/O
/o
^
/O
&
O




48
1
1°
*\
to
10
°l
\o
*\
4
7-
—
-r




72
1
/"
1
/o
1°
1
/o
1
4
I
—
—




90
1
1 ^
1
io
10
1
Ic.
«\
^
O
-
—




Oiisolved Oiygen
(mg/l)
0
nJ.>
"M

^f

r^u

•I.*
'.-TT*

%

n





24
t2i_C
10,0
•I'p;
1C. 6
1-tf
IPi'i
•>.6
'i.fr
O.'i
1-H
i,^r
q,(r




48
IP' Ir*
(0.0
lp.4-
•||.o
ll-o
l».e
/i.o
(0,6
|C.^
/o.e
—
—




72
l°'1
|0l
|o(.
IO)
(02
(O-t
l»l
li.'O
PJ
/^
—
—




90
f.?
?.




it
<,?*>
\.1o
(fOO
ls)0
io 00
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koc
&
tfO
bCO
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6rt>
—
—




96
i^
MTJ
^'fl
vw
^05
H?=-
tfr-V
•f*
(fPT
'7^

—




[YifyX-'ruLure ( (!)
0
"j-y^o

lift

/?,[

//•<»

M,n

/?,^





24
(t-^
k?,6.
10-1
h,f
fa'^r
loM
*7>'^
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^•f
W
^•T
^ri^




48
/J-Z-
//.-?
/^.^
fl.^
/».
ti.lf
!!•*>
ll. t.
II. u

—




72
/#y
/^c
p-f
(l-l
121
HI
U4
u-i
M-o
ft.'
—
—




96
D.fi
io n
o.r,
ti
!%•
to-'
1*}
fa-l
/p,
f?if*

—




a
 i
                 r-,,i.s
                                    ^ t/ (T-'c^ / V . i

                                                                          m

-------
C.        NUMBER         NUMBER        PERCENT       BINOMIAL
          EXPOSED        DEAD          DEAD          PROB.(X)
30           20             20            100            9.536743E-05
0            20             17            85             .1288414
5            20             1             5              2.002716E-03
2.5          20             1             5              2.002716E-03
.25          20             1             5              2.002716E-03
E  BINOMIAL TEST  SHOWS THAT  25 AND  50  CAN BE
ED AS STATISCALLY SOUND CONSERVATIVE 95 PERCENT
NFIDENCE LIMITS  SINCE THE ACTUAL CONFIDENCE LEVEL
SOCIATED WITH THESE LIMITS IS  9?.86916  PERCENT.
 APPROXIMATE  LC50 FOR THIS SET OF DATA IS  37.53657

»»»RESULTS CALCULATED USING THE MOVING AVERAGE METHOD
AN         G             LC50          95 PERCENT CONFIDENCE  LIMITS
            6.572942E-02                35.2711        27.33709       46.908
»>»RESULTS CALCULATED USING THE PROBIT METHOD

ERAT10NS    G             H             GOODNtSC  CF  FIT PROBABILITY
            3.18085        10.81941      0

PROBABILITY OF 0 MEANS THAT  IT  IS LESS THAN 0.00!

NCE  THE PROBABILITY  IS LESS  THAN 0.05, RESULTS  CALCULATED
iING  THE PROBIT METHOD PROBABLY  SHOULD NOT BE  USED.

.OPE  =       3.946269
i PERCENT  CONFIDENCE  LIMITS =-3.091877    AND     10.98442

i50  =        33.89604
i PERCENT  CONFIDENCE  LIMITS   =   0    AND    t  INFINITY
:i   =        8.720297
3 PERCENT  CONFIDENCE  LIMITS   =   0  AND    27.82212
                                           D-52

-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             S an Diego, CA 92121
                                (619)  458-1644
WBLTestNo.:      88183              SamplelD:          Ward Cove - 88390102
                                                          (Main 001)
Facility Name:       Ward Cove, Alaska

Facility Location:    c/o EPA X
                   1200 6th Avenue                            ,-   - ,: "' '• /; -: --.. -
                   Seattle, WA 98101                      '•'' 'Y -'.'••• :':-'.  .

Bioassav Specifications                                         '    Jl'lv/' i")

Effluent Type:       Final, pulp mill effluent                 ..  '•' >'--.\*iK •: ''/•>.;
Test Type/Duration:  Static acute - 96hours                            : .•, .'/ ^.;. ."••'.

Test Organism;      common name:      rainbow trout
                   scientific name:      Salmo gairdneri

Summary of Final Results

Test Starting Date:   9/22/88             Completion Date:           9/26/88
LC50/EC50:        3 1.9% effluent      95% confidence intervals:    not available
NOEC:            N/A                LOEC:                    N/A
 Calculation Method:   LC^Q/EC^Q:         Linear interpolation
                    NOEC/LOEC:        N/A

 Quality Control Summary

 Control Mortality:    5 %
 Temperature maintained:                   yes
 Dissolved oxygen maintained above minimum for test type:        yes
 All test acceptibility requirements met:       yes - control mortality less than 10%

 Test Organisms Data

 Organism Source:    Thomas Fish Farm, Novato, CA
 Acclimation Period:   7 days              Acclimation Mortality:        <1.0%
 Organism Age at beginning of Test:         approx. 30 days
                                       D-53

-------
Test Design
Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:
Method of Preparation:
 Mortality Data (percent mortality)

 Test Concentration    rep.
                   5
                   2
                   10
                   2 liters
                    EPA X personnel
                    grab
                    9/20/88
                    48 hours
                    Alaska Airlines
                    WBL laboratory grade freshwater
                    charcoal filtered and aerated
             % Mortality
control

6.25%

12.5%

' 25.0%

50.0%

100%

a
b
a
b
a
b
a
b
a
b
a
b
10
0
0
0
0
0
30
0
100
100
100
100
Avg. Mortality (%)


         5

         0

         0

        15

       100

       100
 Test Certification
Laboratory Manager:

Date:

Analyst:

Date:         / •
                                                             Barry Snyder
                                                             Alan Monji
                                        D-54

-------
                    DATA SHEET FOR EFFLUENT TOXICITY TEST.
Industry
Addrtss
Coniaei
To.irani -ffYlX C,J|1-£D (tOLIf "rC&y^O
Seafyls , tut/ tl.
flttb lf'<'&&*'S&si
ElMuent Serial Numb
NPOES Permit Numbi




O
1
Ui
U1
^onc.
or
%
/^•/

£-2*-

n .*r

45"

Ctt

/O£>





Test
Containei
Numbei
„{
6
ri
A
/3
ft
/2
&
4 f
B
A t
/?




., UJP>L & H&IVS
t

Number ol
Live Organisms
0
((>
to
(0
fA
(n
to
(O
to
IQ
/o
1C?
(0




24
(<)
/O
(0
10
1°
10
|0
If)
p
itf
10°
fi>*




48
f
1°
to
/o
/o
/o
3-
/o
—
—
—
—




72
q
/^
It?
l»
l«?
r<>
1
/o
—
—
—
—




36
1
11?
10
\t~,
(f\
If'
7*
/0_

—
—
—




1C. 3. (5;^: 2J
Beginning:
Ending:
Test Orgini
Test Tempe
Dissolved OiyQcn
(mg/l)
0
/o-c>

|o
11
1-i
Vt

7ft'
/7/r
7<^P
7.«?
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S '
go
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96
W
fir5*
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—
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Toul Alkalinity
|mg/l as CaCO 3 I
0
|1








,1
tti1





24









)






48
















72
















90
















O A II
•J/30 Tim« ^.'00/3.^-

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raluie Ran
9. /J0^* i ^V

>
Total Hardness
0
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/
^
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s'r?

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72
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96
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96
lo.'i
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'<5,f,
'
-------
                Tn)ui
ONC.

100
50
25
12.5
6.25
NUMBER
EXPOSED
 20
 20
 20
 20
 20
NUMBER
DEAD
 20
 20
 3
 0
 0
HE BINOMIAL TEST SHOWS THAT  25 AND  50
SED AS STATISCALLY SOUND CONSERVATIVE 95
PERCENT
DEAD
 100
 100
 15
 0
 0
CAN BE
PERCENT
BINOMIAL
PROB.CX)
 9.536743E-05
 9.536743E-05
 .1288414
 9.536743E-05
ONFIDENCE LIMITS SINCE THE ACTUAL CONFIDENCE LEVEL
iSSOCIATED WITH THESE LIMITS IS  99.87106  PERCENT.
N APPROXIMATE LC50 FOR THIS SET OF DATA IS  31.89303

IHEN THERE ARE LESS THAN TWO CONCENTRATIONS AT WHICH THE  PERCENT
•EAO IS BETWEEN 0 AND 100, NEITHER THE MOVING AVERAGE NOR THE
'ROBIT METHOD CAN GIVE ANY STATISTICALLY SOUND RESULTS.
                                            D-56

-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619) 458-1644
WBLTestNo.:      88184             Sample ID:          Ward Cove - 88390108
                                                          (Secondary 002B)
Facility Name:       Ward Cove, Alaska

Facility Location:     c/o EPA X
                   1200 6th A venue
                   Seattle, WA  98101                      	 ---•   7""V<9;,.

Bioassay Specifications                                      ;.'.'
                                                          '     ' '••''. :'•,' 0 '
Effluent Type:       Final, pulp mill effluent
Test Type/Duration:  Static acute - 96hours                   ,:  , r,:,:,.,: x ,;  .  ,. ,  -
    ^    .                              .                        fi-'i- •';' -'''  :r'
Test Organism;      common name:      rainbow trout
                   scientific name:      Salmo gairdneri

Summary of Final Results

Test Starting Date:   9/22/88            Completion Date:           9/26/88
LC50/EC50:        77.5% effluent      95% confidence intervals:    56.0%   100%
NOEC:             N/A               LOEC:                    N/A
Calculation Method:   LC50/EC5Q:         Moving Average
                    NOEC/LOEC:        N/A

Quality Control Summary

Control Mortality:     5 %
Temperature maintained:                  yes
Dissolved oxygen maintained above minimum for test type:        yes
All test acceptibility requirements met:       yes - control mortality less than 10%

Test Organisms Data

Organism Source:     Thomas Fish Farm, Novato, CA
Acclimation Period:   7 days              Acclimation Mortality:       <1.0%
Organism Age at beginning of Test:         approx. 30 days
                                     D-57

-------
Test Design
Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:
Method of Preparation:
 Mortality Data (percent mortality)

 Test Concentration
      5
      2
      10
      2 liters
      EPA X personnel
      grab
      9/20/88
      48 hours
      Alaska Airlines
      WBL laboratory grade freshwater
      charcoal filtered and aerated
% Mortality
control

6.25%

12.5%

' 25.0%

50.0%

100%

— • a -
a
b
a
b
a
b
a
b
a
b
a
b
10
0
0
10
10
0
0
0
20
30
90
40
Avg. Mortality (%)


         5

         5

         5

         0

        25

        65
 Test Certification
                     Laboratory Manager:

                     Date:             />

                     Analyst:

                     Date:        /'A
                           Barry Snyder
                           Alan Monji
                                        D-58

-------
                                     DATA SHEET FOR  EFFLUENT TOXICITY TEST.
Indulll. To.icanl
Contact	
Elllueni Serial Number
NPDES Permit Number
                                                                                     eginning:  fi«i« 7/3.3.	Time,
                                                                                     ndlng:    n.i. ci/3-L    T'Tt
                                   I til-
                                                                                          8
                                                                                          Ending

                                                                                          Ten Temperature Rings.
Ten
Container
Number
                Number ol
                Live Organisms
                 0  24
                        48
                            72   96
                                   Oi isolved Oiygen
                                   Img/l)
                                       24
                                          48
                                              72
                                                  96
                                                                  PH
                                                          24
                                                                 72
                                                                    96
Total Alkalinity
Img/l ai CaCO3 I
                                                                            24
                                                                               48
                                                                                   72
                                                                                       96
                                                                                               T
btal Hardness (Conductivity
                                                                                              24
                                                                                                  48
                                                                                                      72
                                                                                                         96
                                                                                                                 24
                                                                                                                     48
                                                                                                                         72  96
                                                                                                                                          (  (!)
                                                                                                                                   24
                                                                                                                                       48
                                                                                                                                           72  96
        JL
                 lo
                                          0.4
                                                   j£i
                                                        111
                                                                       liA
                                                                                                                        Mo
                    la-
                            11;
                                in
                                          10.
                        (0
                                      to i>
                                          (p.4-
                                                                                                                  7m
                                                                                                                              M-n
                                                                                                                                   tt/
                                                                                                                                              l.p
                    in.
                        10
                                            <£L
                                              0 0
                                                                                                                            lo
D
 I
Ol
a -sr
                1LL
                               $3-
                                          10.4-
                                                                                                             flop
                                                                                                                 SO?
                            JL
                                          /O.i
                1LL
                    Ii2.
                                     1A
                                                                                                            lot a
                                                                                                                    (0-30
                                                                                                                         We
                                                                                                                                  Hi
                    lo
                                           /0.4-
                                              10 0
                                                                                                                m&
                ID.
                                              10'!
                                                                                                                     /410
                                                                                                                              IflO
                                                                                                                                             te*
                        2.
                                                                                                                                  n_a
                                 *
                                   77
                                              10-0
                                                                 81
                                                                                                                 JisriZ^o
                                                                                                                             2200
                                                                                                                                      //.(x
                                                                                                                                   ll-
                                                                                                                                             ifij
                      M
                    JiL
                                                             B.'b
                                                                                                                 7to-asp
                                                                                                                                           [l-t
                                                                                                                                             ^i
                            j
                                                                           -
-------
             NUMBER        NUMBER        PERCENT        BINOMIAL
             EXPOSED       DEAD          DEAD           PROB.(X)
 100           20            13             65             13.1588       -?
 50            20            5              25             2.069473
 25            20            0              0              9.536743E-05
 12.5          20            1              5              2.002716E-03
 6.25          20            1              5              2.002716E-03
THE BINOMIAL TEST SHOWS THAT  50 AND  +  INFINITY  CAN BE
USED AS STATISCALLY SOUND CONSERVATIVE  95 PERCENT
CONFIDENCE LIMITS SINCE THE ACTUAL  CONFIDENCE  LEVEL
ASSOCIATED WITH THESE LIMITS IS  97.93053   PERCENT.
AN APPROXIMATE LC50 FOR THIS SET OF DATA IS  77.45697

»»»»RESULTS CALCULATED USING THE  MOVING AVERAGE METHOD
SPAN          G             LC50           95  PERCENT CONFIDENCE LIMITS
 1             .6047553      77.45697      55.9507       141.7173
>»»»RESULTS CALCULATED USING THE PROBIT  METHOD

ITERATIONS    6             H              GOODNESS OF FIT PROBABILITY
 6             1.633447      2.871438      3.488326E-02

SINCE  THE PROBABILITY  IS  LESS THAN  0.05, RESULTS CALCULATED
USING  THE PROBIT METHOD PROBABLY  SHOULD NOT BE USED.

SLOPE   =        2.091501
95 PERCENT  CONFIDENCE  LIMITS =-.5815709    AND    4.764572

LC50   =        88.99493
95 PERCENT  CONFIDENCE  LIMITS   =   28.80873  AND  +  INFINITY
LCI    =        6.868585
95 PERCENT  CONFIDENCE  LIMITS   =  0   AND   24.11993
                                             D-60

-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619) 458-1644
WBL Test No.:

Facility Name:

Facility Location:
88188

Ward Cove, Alaska

c/o EPA X
1200 6th Avenue
Seattle, WA 98101
                   Sample ID:
Bioassay Specifications

Effluent Type:        Final, pulp mill effluent
Test Type/Duration:   Chronic/Bivalve Larvae - 48 hours
Test Organism;
common name:
scientific name:
Summary of Final Results
9/22/88
N/A
<4.8%
Test Starting Date:
LC50/EC50:
NOEC:

Calculation Method:
                    NOEC/LOEC:

Quality Control Summary

Control Mortality:    24.3%
Temperature maintained:
Ward Cove - 88390101
(Main 001)
                   Pacific oyster
                   Crassostrea gigas
                   Completion Date:
                   95% confidence intervals:
                   LOEC:

                   N/A
                   Dunnett's Procedure
       9/24/88
       N/A
       4.8%
                   yes
 Dissolved oxygen maintained above minimum for test type:        yes
 All test acceptibility requirements met:       no - control mortality should be less than 20%
 Test Organisms Data

 Organism Source:    Brood stock from Brezina and Associates, Dillon Beach, CA
 Acclimation Period:   >14days           Acclimation Mortality:       0
 Organism Age at beginning of Test:        larvae less than 3 hours
                                      D-61

-------
Test Design

Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:

Method of Preparation:
5
3
25 larvae per ml
100ml
EPA X personnel
composite
9/20/88
48 hours
Alaska Airlines
WBL seawater collected from Mission Bay at
Hubbs Research Center
filtered to 0.45(im
 Test Certification
                     Laboratory Manager

                     Date:

                     Analyst:

                     Date:
                    Barry Snyder



                    Alan Monji

                           /
                                         D-62

-------
                     WESTEC Bioassay Laboratory
                     Bivalve Larvae Bioassay Summary

     WBLTesttf         88188           Sample ID. # 88390101  (Main  001)

cone.   rep.   # normal  # abnormal   total    % abnormal  avg. abnormal %  survival
                                                            1.0%    75.7%
                                                            6.0%    77.5%
                                                           32.3%    56.9%
                                                           43.0%    23.4%
                                                             0.0%      0.0%
                                                             0.0%      0.0%
                                                             0.0%      0.0%
control


salinity
control

4.8%


9.6%


19.2%


38.5%



76.9%


a
b
c
a
b
c
a
b
c
a
b
c
a
b
c
a
b
c
r
a
b
c
142
191
175
1 16
179
210
79
142
66
3
9
1 7
0
0
0
0
0
0

0
0
0
0
2
1
4
0
1 4
32
26
39
42
23
64
0
0
0
0
0
0

0
0
0
142
1 93
176
1 20
179
224
1 1 1
1 68
105
45
32
8 1
0
0
0
0
0
0

0
0
0
0.0%
2.0%
1 .0%
4.0%
0.0%
14.0%
32.0%
26.0%
39.0%
42.0%
23.0%
64.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%

0.0%
0.0%
0.0%
                                            D-63

-------
  REVISION  1.00      5/1/87
ANWA-WITH THE DUNNETT COMPARISON OF EACH CONCENTRATION       (Jj&A'ct £0*
MEAN VS THE CONTROL MEAN. UP TO  SEVEN CONCENTRATIONS
(INCLUDING THE CONTROL) AND UP TO TEN REPLICATES               M
MAY BE USED.                                                      '

A ONE SIDED 'T' AT 95X IS ASSUMED IN ALL CASES.

THE TRANSFORMATIONS WHICH MAY BE USED ON THE DATA ARE:

NUMBER     TRANSFORMATION
  Q        NONE
  1        SQUARE ROOT*0.5>
          NOTE    :
                     THE  LIMITS OF SIN ARE +/- 1.
  7        ALGAL ANALYSIS  - NO  TRANSFORMATION

RESULTS    OF    SEQUENTIAL   COMPARISONS
         USING    THE   DUNNETT' S   TEST

 CALCULATED DUNNETT T  VALUES

CONCENTRATION    CALC DUNNETT T

 2           -1.276255
 3           -5.71658
 4           -6.914319
 5           -16.14711
 6           -16.14711
 7           -16.14711

TABULATED DUNNETT T =   2.53

NOTE: H  TABULATED   DUNNETT   T  is greater  than  the
     CALCULATED DUNNETT  T, THERE  IS NO  SIGNIFI CANT
     DIFFERENCE between  that  CONCENTRATION  and the
     CONTROL. H  the   TABULATED   DUNNETT T  is  less
     than the  CALCULATED DUNNETT T,  then THERE IS
     SIGNIFICANT   DIFFERENCE between  that   CONCEN-
     TRATION and  the  CONTROL.

For this  set o-f data, the  MINIMUM  SIGNIFICANT DIFFERENCE    is   -0.010.
This represents a-96.3X reduction  o-f  the mean response -from the  CONTROL.

 There  is NO SI GN 1FI CAT-IT  DIFFERENCE  between  CONCENTRATION  2 and  CONT

~>There IS A SIGNIFICANT  DIFFERENCE  between  CONCENTRATION  3 and-CONT

=>There IS A SIGNIFI CANT  DIFFERENCE  between  CONCENTRATION  4 and  CONT

=>There IS A SIGNIFICANT  DIFFERENCE  between  CONCENTRATION  5 and  CONT

=>There IS A SIGNIFICANT  DIFFERENCE  between  CONCENTRATION  6 and  CONT

=>There IS A S1GNIFI CANT  DIFFERENCE  between  CONCENTRATION  7 and  CONT

     INPUT   DATA   TABLE
                                            D-64
   0.00    0.02    0.01

-------
   0.42    0.23    0.64
   i.OO    1.00    1.00
   1.00    1.00    1.00
   1.00    1.00    1.00

TRANSFORMED    DATA   TABLE
                      NUMBER6WAS
      USED   FOR  THIS SET OF DATA.
0.03
0.20
0.60
0.71
1.54
1.54
1.54
0.14
0.03
0.54
0.50
1 .54
1 .54
1 .54
0.10
0.38
0.67
0.93
1 .54
1 .54
1.54
                   A N 0 V A   TABLE
 Source   DF    Sum o-f Sq.     Mean Sq.    Calc  F  Tab  F(0.05)

 AMONG     6        7.430       1.238     102.990     2.850
 WITHIN   14        0.168       0.012
 TOTAL    20        7.598
                                              D-65

-------
                    BIOMONITORING REPORT FORM

                 WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619)  458-1644
WBLTestNo.:       88189              Sample ID:          Ward Cove- 88390104
                                                          (Primary 002A)
Facility Name:        Ward Cove, Alaska

Facility Location:     c/o EPA X
                    1200 6th Avenue                               ,   ...  ,,.._.
                    Seattle, WA 98101

Bioassay Specifications                                        v-'°   .  _
                                                                  W)v o:'i9g
Effluent Type:        Final, pulp mill effluent                  /Tr, ,,.,,,,
Test Type/Duration:   Chronic/Bivalve Larvae - 48 hours            ""' ' ~: ;;' • " ' • ••' ••'• •..-•
                                                                •• L;''! '"U.:'Jfv :"•
Test Organism;       common name:      Pacific oyster
                    scientific name:      Crassostrea gigas

Summary of Final Results

Test Starting Date:    9/22/88             Completion Date:           9/24/88
LC50/EC50:         N/A                95% confidence intervals:    N/A
NOEC:              <4.8%             LOEC:                    4.8%

Calculation Method:   LC5Q/EC50:         N/A
                    NOEC/LOEC:       Dunnett's Procedure

Quality Control Summary

Control Mortality:    24.3%
Temperature maintained:                  yes
Dissolved oxygen maintained above minimum for test type:       yes
All test acceptability requirements met:      no - control mortality should be less than 20%
Test Organisms Data

Organism Source:    Brood stock from Brezina and Associates, Dillon Beach, CA
Acclimation Period:   >14 days           Acclimation Mortality:       0
Organism Age at beginning of Test:        larvae less than 3 hours
                                     D-66

-------
Test Desin
Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:

Method of Preparation:
5
3
25 larvae per ml
100ml
EPA X personnel
composite
9/20/88
48 hours
Alaska Airlines
WBL seawater collected from Mission Bay at
Hubbs Research Center
filtered to 0.45(im
 Test Certification
                     Laboratory Manager:

                     Date:          y

                     Analyst:

                     Date:
                    Barry Snyder
                    Alan Monji

                    ~^   /
                                       D-67

-------
                      WESTEC Bioassay Laboratory
                      Bivalve Larvae Bioassay Summary
     WBLTest*          88189

cone.   rep.  #  normal  #  abnormal
    Sample ID. # 88390104  (Primary  002

total % abnormal  avg. abnormal % survival
control


salinity
control

4.8%


9.6%


19.2%


38.5%



76.9%


a
b
c
a
b
c
a
b
c
a
b
c
a
b
c
a
b
c
r
a
b
c
142
191
175
1 16
179
210
9 1
1 9
51
0
4
0
0
0
0
0
0
0

0
0
0
0
2
1
4
0
1 4
43
41
1 7
27
1 7
42
0
0
0
0
0
0

0
0
0
142
1 93
176
120
179
224
134
60
68
27
21
42
0
0
0
0
0
0

0
0
0
0.0%
2.0%
1 .0%
4.0%
0.0%
14.0%
43.0%
41.0%
17.0%
27.0%
17.0%
42.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%

0.0%
0.0%
0.0%
                                                             1.0%
                                                             6.0%
                                                            33.7%
                                                            28.7%
                                                             0.0%
                                                             0.0%
                                                             0.0%
                                 75.7%
                                 77.5%
                                 38.8%
                                 13.3%
                                  0.0%
                                   0.0%
                                   0.0%
                                           D-68

-------
  PEUISIQN  1 00       5/1/87
ANoOA-UITH THE  DUNNETT COMPARISON OF EACH CONCENTRATION
MEAN VS THE CONTROL  MEAN.  UP TO SEVEN CONCENTRATIONS
(INCLUDING THE  CONTROL)  AND UP TO TEN REPLICATES


A ONE  SIDED 'T' AT 95X IS  ASSUMED IN ALL CASES.

THE TRANSFORMATIONS  WHICH  MAY BE USED ON THE DATA ARE:

NUMBER    TRANSFORMATION
  0       NONE
  1       SQUARE ROOT(X)
  3       LOG10/2
  6       ARCSIN«X>"0.5>
          NOTE    :
                      THE  LIMITS OF SIN ARE +/- 1.
  7       ALGAL ANALYSIS  - NO TRANSFORMATION

RESULTS    OF    SEQUENTIAL   COMPARISONS
         USING    THE   DUNNETT'S   TEST

 CALCULATED DUNNETT  T VALUES

CONCENTRATION    CrtLC DUNNETT T

 2            -1.312028
 3            -5.969578
 4            -5.362445
 5            -16.59972
 6            -16.59972
 7            -16.59972

TABULATED DUNNETT T  =  2.53

NOTE:  H  TABULATED  DUNNETT  T  is greater  than  the
      CALCULATED DUNNETT T, THERE  IS NO  SIGNIFICANT
      DIFFERENCE between that CONCENTRATION and  the
      CONTROL. H the  TABULATED   DUNNETT T is  less
      than the  CALCULATED DUNNETT T,  then  THERE IS
      SIGNIFICANT  DIFFERENCE between  that  CONCEN-
      TRATION and the CONTROL.

For- this  set  o-f data, the  MINIMUM  SIGNIFICANT  DIFFERENCE   is  -0.008.
This represents a-80.3X  reduction  o-f  the mean  response -from the CONTROL,

 There is NO SIGNIFICANT DIFFERENCE  between CONCENTRATION 2 and CONT

=>There IS A SIGNIFICANT DIFFERENCE  between CONCENTRATION 3 and CONT

=>There IS A SIGNIFICANT DIFFERENCE  between CONCENTRATION 4 =md CONT

=>There IS A SIGNIFICANT DIFFERENCE  between CONCENTRATION 5 and COhr

       :3 A SIGNIFICANT DIFFERENCE  between CONCENTRATION 6 and CONT

=>There IS A SIGNIFICANT DIFFERENCE  between CONCENTRATION 7 and CONT

      INPUT   DATA    TABLE

-------
   0.43    0.41     0.17
   0.27    0.17     0.42
   1.00    1.00     1.00
   1.00    1.00     1.00
   1.00    1.00     1.00

TRANSFORMED   DATA    TABLE

" NOTETTRANSFORMATlON NUMBER~
-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619)  458-1644
WBLTestNo.:       88190              Sample ID:          Ward Cove - 88390107
                                                          (Secondary 002B)
Facility Name:        Ward Cove, Alaska

Facility Location:     c/o EPA X
                    1200 6th Avenue
                    Seattle, WA 98101

Bioassay Specifications

Effluent Type:        Final, pulp mill effluent
Test Type/Duration:   Chronic/Bivalve Larvae - 48 hours

Test Organism;       common name:      Pacific oyster
                    scientific name:      Crassostrea gigas

Summary of Final Results

Test Starting Date:    9/22/88            Completion Date:           9/24/88
LC50/EC50:         N/A               95% confidence intervals:    N/A
NOEC:              <4.8%             LOEC:                    4.8%

Calculation Method:   LCso/ECsQ:         N/A
                    NOEC/LOEC:       Dunnett's Procedure

Quality Control Summary

Control Mortality:    24.3%
Temperature maintained:                  yes
Dissolved oxygen maintained above minimum for test type:        yes
All test acceptibility requirements met:      no - control mortality should be less than 20%


Test Organisms Data

Organism Source:    Brood stock from Brezina and Associates, Dillon Beach, CA
Acclimation Period:   > 14 days           Acclimation Mortality:       0
Organism Age at beginning of Test:         larvae less than 3 hours
                                       D-71

-------
Test Design

Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:

Method of Preparation:
                   5
                   3
                   25 larvae per ml
                   100ml
                    EPA X personnel
                    composite
                    9/20/88
                    48 hours
                    Alaska Airlines
                    WBL seawater collected from Mission Bay at
                    Hubbs Research Center
                    filtered to 0.45p.m
 Test Certification
Laboratory Manager

Date:            /

Analyst:

Date:           /
                                                            Barry Snyder
                                                            Alan Monji
                                        D-72

-------
                      WESTEC Bioassay Laboratory
                      Bivalve Larvae Bioassay Summary

      WBLTest*          88190           Sample ID. # 88390107  (Secondary 002

cone.   rep.   # normal  # abnormal  total    % abnormal  avg. abnormal % survival
control


salinity
control

4.8%


9.6%


19.2%


38.5%


76.9%


a
b
c
a
b
c
a
b
c
a
b
c
a
b
c
a
b
c
a
b
c
142
191
175
1 16
179
210
149
73
91
0
0
0
0
0
0
0
0
0
0
0
0
0
2
1
4
0
1 4
61
43
29
0
0
0
0
0
0
0
0
0
0
0
0
142
1 93
176
1 20
179
224
210
1 16
1 20
0
0
0
0
0
0
0
0
0
0
0
0
0.0%
2.0%
1 .0%
4.0%
0.0%
14.0%
61.0%
43.0%
29.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
                                                             1.0%
                                                             6.0%
                                                            44.3%
75.7%
77.5%
66.1%
                                                             0.0%      0.0%
                                                             0.0%      0.0%
                                                             0.0%      0.0%
                                                              0.0%
 0.0%
                                            D-73

-------
  REVISION  1.00       5/1/87
 ANOVA-WITH THE DUNNETT COMPARISON OF EACH CONCENTRATION
 MEAN VS THE CONTROL MEAN. UP TO SEVEN CONCENTRATIONS
 (INCLUDING THE CONTROL) AND UP TO TEN REPLICATES
 MAY BE USED.

 A ONE SIDED 'T' AT 95X IS ASSUMED IN ALL CASES.

 THE TRANSFORMATIONS WHICH MAY BE USED ON THE DATA ARE:

 NUMBER     TRANSFORMATION
  0        NONE
  1        SQUARE ROOT(X)
  3        LOGIO(X)
  5       
           NOTE    :
                      THE LIMITS OF SIN ARE +/-  1.
  7        ALGAL ANALYSIS - NO TRANSFORMATION

RESULTS   OF    SEQUENTIAL   COMPARISONS
         USING    THE    DUNNETT' S   TEST

 CALCULATED DUNNETT T  VALUES

CONCENTRATION   CALC DUNNETT T

 2            -1.504011
 3            -8.357164
 4            -19.02868
 5            -19.02868
 6            -19.02868
 7            -19.02868

TABULATED DUNNETT T =   2.53

NOTE:  If  TABULATED  DUNNETT   T  is greater  than  the
      CALCULATED DUNNETT  T, THERE  IS NO  S1GNIF1 CANT
      DIFFERENCE between  that  CONCENTRATION and  the
      CONTROL.  If the   TABULATED   DUNNETT  T  is  less
      than the  CALCULATED DUNNETT T,  then THERE  IS
      SIGNIFICANT   DIFFERENCE  between  that   CONCEN-
      TRATION and the  CONTROL.

For  this  set of data, the  MINIMUM  SIGNIFICANT  DIFFERENCE   is  -0.002
This  represents a-16.47. reduction  o-f  the mean  response from the CONTROL

 There  is NO SIGNIF1 CANT  DIFFERENCE  between  CONCENTRATION 2 and CONT

= >There  IS A SIGNIFICANT  DIFFERENCE  between  CONCENTRATI Of4 3 and CONT

=>There  IS A SIGNIFICANT  DIFFERENCE  between  CONCENTRATION 4 and CONT

=>There  IS A SIGNIFICANT  DIFFERENCE  between  CONCENTRATION 5 and CONT

=>There  IS A SIGNIFICANT  DIFFERENCE  between  CONCENTRATION 6 and CONT

=>There  IS A SIGNIFICANT  DIFFERENCE  between  CONCENTRATION 7 and CONT

      INPUT   DATA  TABLE       D_74

-------
0.61
1.00
1.00
1.00
1.00
0.43
1.00
1.00
1.00
1.00
0.29
1.00
1.00
1.00
1 .00
TRANSFORMED    DATA   TABLE

' NOTETTRANSFORMATlON  NUMBER~
-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619) 458-1644
WBLTestNo.:       88191              Sample ID:          Ward Cove - 0118

Facility Name:        Ward Cove, Alaska

Facility Location:     c/oEPAX
                    1200 6th Avenue                      .•'-    ;:   :'-" •'•'''"...
                    Seattle,WA 98101                    ;';    ':  -   -

Bioassav Specifications                                          ^OV 0 ,'; jQp

 Test Material:        sediment                           ;    • '-:i ;•';  ,t r  :;   ,
Test Type/Duration:   Suspended Paniculate Phase, static acute - 96 hours'   •' ! •   n

Test Organism;       common name:       mysid shrimp
                    scientific name:       Acanthomysis sculpta

Summary of Final Results

Test Starting Date:    9/29/88             Completion Date:            10/3/88
LC50/EC50:         >100% elutriate      95% confidence intervals:    N/A
NOEC:              N/A                LOEC:                   N/A

Calculation Method:   LCsQ/ECso:         N/A
                    NOEC/LOEC:       N/A

Quality Control Summary

Control Mortality:    11.7%
Temperature maintained:                  yes
Dissolved oxygen maintained above minimum for test type:        yes
All test acceptibility requirements met:       yes - control mortality less than 20%

Test Organisms Data

Organism Source:    Brezina and Associates, Dillon Beach, CA
Acclimation Period:   48 hours           Acclimation Mortality:       <10.0%
Organism Age at beginning of Test:         juvenile
                                     D-76

-------
Test Design
Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:
Method of Preparation:
 Mortality Data (percent mortality)

 Test Concentration    rep.
      3
      3
      20
      2 liters
      EPA X personnel
      grab
      9/20/88
      9 days
      Alaska Airlines
      WBL laboratory grade saltwater
      filtered to 20 |im and aerated
% Mortality
control


10.0%


- 50.0%


100%


a
b
c
a
b
c
a
b
c
a
b
c
15
10
10
0
10
20
20
25
20
40
40
10
Avg. Mortality (%)



        11.7


        10.0


        21.7


        30.0
 Test Certification
                     Laboratory Manager:

                     Date:

                     Analyst:

                     Date:
     :  £)Cl>/l/u7\ 9*^^.Barry Snyder
             i->     'J
                           Alan Monji
                                       D-77

-------
                     DATA SHEET FOR EFFLUENT TOXICITY TEST.
.,  .
 Toicanl
                 c&t  oiid
                       '  v
AM,...
3 AC*. -M-f ^ /J~~
D/)in Pkdi?$t,(A
llllutM Stilal Numb
HTDtS Ptmiit Numbi
Cone.
CH
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tttflbvl


j00iQ


6~0°h


100%






Ttti
C oniainer
Numbei
a
b
c
a.
fc
c
a
b
a
^
b
c




^^ V!T &&l^l


Number of
liv t Organisms
0
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10
10
10
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/
-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619) 458-1644
WBLTestNo.:      88192             Sample ID:         Ward Cove- 0119

Facility Name:       Ward Cove, Alaska

Facility Location:    c/o EPA X
                   1200 6th Avenue
                   Seattle, WA  98101

Bioassay Specifications

 Test Material:       sediment
Test Type/Duration:  Suspended Paniculate Phase, static acute - 96 hours

Test Organism;      common name:      mysid shrimp
                   scientific name:      Acanthomysls sculpta

Summary of Final Results

Test Starting Date:   9/29/88            Completion Date:           10/3/88
LC50/EC50:        >100% elutriate     95% confidence intervals:    N/A
NOEC:             N/A               LOEC:                    N/A
 Calculation Method:   LCsQ/ECsQ:         N/A
                    NOEC/LOEC:       N/A

 Quality Control Summary

 Control Mortali ty :     11.7%
 Temperature maintained:                  yes
 Dissolved oxygen maintained above minimum for test type:        yes
 All test acceptibility requirements met:       yes - control mortality less than 20%

 Test Organisms Data

 Organism Source:     Brezina and Associates, Dillon Beach, CA
 Acclimation Period:   48 hours            Acclimation Mortality:       <10.0%
 Organism Age at beginning of Test:         juvenile
                                       D-79

-------
Test Desien
Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:
Method of Preparation:
 Mortality Data (percent mortality)
Test Concentration
control


10.0%


- 50.0%


100%


rep.
a
b
c
a
b
c
a
b
c
a
b
c
3
3
20
2 liters
EPA X personnel
grab
9/20/88
9 days
Alaska Airlines
WBL laboratory grade saltwater
filtered to 20 Jim and aerated
                                   % Mortality

                                      15
                                      10
                                      10
                                       5
                                      25
                                      10
                                       5
                                      20
                                      20
                                      15
                                      10
                                      30
              Avg. Mortality
                      11.7
                      13.3
                      15.0
                      18.3
 Test Certification
                      Laboratory Manager:

                      Date:         /

                      Analyst:

                      Date:        /' A A*
            ^<-^>£^fearry Snyder
                     Alan Monji

                     7
                                         D-80

-------
                                                                                                  Oe
          •!...«.«.
                                    DATA SHEET FOR EFFLUENT  TOXICITY  TEST.
                               CMC  Qlt
io
^o
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w
w
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^
«•«
go
B-o-
8-3




24
80
8'
f-
6'
8-i
fl-i
^
<}»
i(
8-1
80
^J




46
ao
e°
&
fri
8-i
«i
«-3
ei
8-0
Si
01
fi-o




72
?i
«•«
8/
8i
*»
8'
g.t
&/
8-0
^1
^o
g>




96
/•'I
tli
ijj
ff'l
ff:>
•^.(
2s
?-i
a. J
ia.
ST
&••{




Salinity (ppt)
0
3r


ii

H


7^


i

!

2<
3T


vf


H


^






48
3r


3^"


^


^






72
3r


^c


?>"


5^






96
3i>


36


^


3t






i
Conductivity *
0
















24
















48
















72















96
















Temperature ( C)
0
IU
rt-»
^3
/H
ii/
y^
\W
M
IV
n-s
\w
M




24
M
lW
itf
IU
/9-^
/
-------
                    BIOMONITORING REPORT FORM

                WESTEC SERVICES BIOASSAY LABORATORY
                             10477 C Roselle Street
                             San Diego, CA 92121
                                (619) 458-1644
WBLTestNo.:      88193              Sample ID:          Ward Cove - 0121

Facility Name:       Ward Cove, Alaska

Facility Location:    c/o EPA X
                   1200 6th Avenue
                   Seattle, WA  98101

Bioassay Specifications

 Test Material:       sediment
Test Type/Duration:  Suspended Paniculate Phase, static acute - 96 hours

Test Organism;      common name:      mysid shrimp
                   scientific name:      Acanthomysis sculpta

Summary of Final Results

Test Starting Date:   9/29/88            Completion Date:           10/3/88
LC50/EC50:        40.0% elutriate      95% confidence intervals:    31.5%  50.8%
NOEC:             N/A               LOEC:                    N/A

Calculation Method:  LC5Q/EC50:        Moving Average
                   NOEC/LOEC:       N/A

Quality Control Summary

Control Mortality:    11.7%
Temperature maintained:                 yes
Dissolved oxygen maintained above minimum for test type:        yes
All test acceptibility requirements met:      yes - control mortality less than 20%

Test Organisms Data

Organism Source:   Brezina and Associates, Dillon Beach, CA
Acclimation Period:  48 hours           Acclimation Mortality:       <10.0%
Organism Age at beginning of Test:        j uvenile
                                      D-82

-------
                                    DATA SHEET FOR EFFLUENT  TOXICITY  TEST.
                   .  tufr
                                                                           Beginning:  n«i«
                                                                                             Tlm«
     ClllutM Stilil Numbti

     NPOCS Ptrrall Numbti
                      U)t>Ltt
Ending:   n.i. J^/O/S T'™«

Te.i n.n •"'••-   frcbn-tttenuj
Ted Tempenlui* Ring*.
                     J.Q
Cooc.
CH
S
(JPfl/>W|


10%


S0°lo


/^°/o






Tin
Conliinei
Numbei
a.
b
C
a
j)
C
<*
1)
c
a
b
c




Number ol
live Organijmi
0
20
ZO
W
20
10
10
W>
IX)
10
10
00
Jo




24
















48









1






72
















90
17,,
7/
nf

^
^
t?-
e
9
*y
3
d




Dissolved 0»yg«n
(mg/l)
0
6-z
to
8-t
7-^
7-9
7^
(v/
t-?
6-9
7/
7-'
^




24
74
72
7-5
7l
70
7-o
7/
7.0
*•*
^>5
67
(,5




48
72
7-i
70
7f
7D
fr<
72
7-1
71.
7i
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7-1
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7-p
T.X
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7.)
?.o
?•/




pll
0
8-1
£0
fl°
81
fH
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fl°
6-1
61
61
g«
8-0




24
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6)
81
8-1
^>
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B-4
»,i
64
fts"
§4




48
80
&o
80
fi-i
8-1
01
?-^
8-1
fti
B-i
8-'
B3




72
go
9-1
?'
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fi-/
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8)
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^}




96
7-'(
?•(?
?.o
?•*
S. 1
?(•>-
*•>
83
fr''
S^
*-V
1-5^




Salinity (ppt)
0
3^


34


H


34

1
1
'
1

24
3^


54


H


^






41
^


3^


^<


V






72
3T


^


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^






96
v,


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0
















24
















48
















72
















96
















Temperature ( C)
0
IW
A-'
/W
^
/f4
»H
rt-5
IU
!<}.J
/U
rt-<"
IH




24
|H
/^
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201
70-3
201
102
ID.?
70-2.
V*
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48
^*
*;
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w
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I1.i
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72
M-'
«•;
fty
h-f
fi.o
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fry
ll-i
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96
11ft
'vTr
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IW
(V#
M-7
ti-7
Cr.7
|CT-'-
fr.t
/7-7
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o
I
oo
         •^Conductivity values  X  10~

-------
Test Design
Number of Effluent Concentration:
Number of replicates/test concentration:
Number of Organisms per replicate:
Volume of test material per chamber:

Effluent Collection

Effluent Collector:
Type of sample (eg. grab, compsite):
Collection Dates:
Maximum Holding Time:
Method of Shipping:

Dilution Water

Dilution Water Source:
Method of Preparation:
Mortality Data (percent mortality')

Test Concentration   rep.
                                        3
                                        3
                                        20
                                        2 liters
                                        EPA X personnel
                                        grab
                                        9/20/88
                                        9 days
                                        Alaska Airlines
                                        WBL laboratory grade saltwater
                                        filtered to 20 |im and aerated
                                   % Mortality
control


10.0%


- 50.0%


100%


— ' a.
a
b
c
a
b
c
a
b
c
a
b
c
15
10
10
10
20
25
40
35
60
80
85
100
Avg. Mortality



        11.7


        18.3


        45.0


        88.3
 Test Certification
                     Laboratory Manager:  /ji

                     Date:         H/1/0&

                     Analyst:

                     Date:           I'/-*  <^
                                                            -t^Barry Snyder
                                                              Alan Monji

                                                          /f JLi-~-^.  I
                                        D-84

-------
                                                                       88 W
             NUMBER        NUMBER        PERCENT       BINOMIAU        l^O^oC (
             EXPOSED       DEAD          DEAD          PROB.OO
 !00           60            53            88.33334      3.835959E-08   /H^j j
 50            60            27            45            3.785926
 10            60            11            18.33333      3.78064E-05    C1) \
THE BINOMIAL TEST SHOWS THAT   10 AND   100  CAN BE
USED AS STATISCALLY SOUND CONSERVATIVE 95 PERCENT
CONFIDENCE LIMITS SINCE THE ACTUAL CONFIDENCE LEVEL
ASSOCIATED WITH THESE LIMITS IS  99.99996  PERCENT.
AN APPROXIMATE LC50 FOR THIS SET OF DATA  IS  53.71409

»»»»RESULTS CALCULATED USING THE  MOVING  AVERAGE  METHOD
SPAN          G             LC50          95 PERCENT CONFIDENCE LIMITS
 2            5.444088E-02                39.99059       31.49181       50.81626
»>»»RESULTS CALCULATED USING THE PROBIT METHOD

ITERATIONS    G             H             GOODNESS OF  FIT  PROBABILITY
 4            30.20642      9.220016     2.393305E-03

SINCE  THE PROBABILITY  IS  LESS  THAN  0.05,  RESULTS CALCULATED
USING  THE PROBIT METHOD PROBABLY  SHOULD  NOT  BE  USED.

SLOPE   =       1.861044
95 PERCENT  CONFIDENCE  LIMITS =-8.367324    AND     12.08941

LC50   =       37.04299
95 PERCENT  CONFIDENCE  LIMITS   =   0     AND   +  INFINITY
 LCI   =       2.081832
 95 PERCENT  CONFIDENCE  LIMITS   =   0     AND   +  INFINITY
                                             D-85

-------
      APPENDIX E






INTERCALIBRATION DATA

-------
     Table  E-l.   Intercalibration Results
M
I
Station
KLI 5-1
ADEC 61
KPC 48
Station
KLI 5-2
ADEC 62
KPC 	
Station
KLI 5-3
ADEC 63
KPC 	
Station
KLI 5-4
ADEC 64
KPC 49
Depth
sfc
1 m
5 m
10 m
Depth
sfc
1 m
5 m
10 m
Depth
sfc
1 m
5 m
10 m
Depth
sfc
1 m
5 m
10 m
Temperature
KLI ADEC
14.45 15
ND 14.5
13.27 13
12.0 12
Temperature
KLI ADEC
14.31 14.5
14.32 14.5
13.36 13
11.72 12
Temperature
KLI ADEC
14.36 14.5
14.36 14.5
13.65 14
11.87 12
Temperature
KLI ADEC
14.27 14.5
14.26 14.5
13.36 13.5
12.14 12

KPC
ND
ND
ND
ND
KPC
ND
ND
ND
ND
KPC
ND
ND
ND
ND
KPC
ND
ND
ND
ND
Salinity
KLI ADEC
23.73 23
ND 23.5
26.17 26
27.85 ND
Salinity
KLI ADEC
24.2 24
24.2 24
26.03 26
28.25 ND
Salinity
KLI ADEC
24.11 23.5
24.12 23.5
25.57 25
28.03 ND
Salinity
KLI ADEC
23.87 23.5
24.10 23.5
26.08 26
27.88 ND

KPC
ND
ND
ND
ND
KPC
ND
ND
ND
ND
KPC
ND
ND
ND
ND
KPC
ND
ND
ND
ND
Dissolved Oxygen
KLI ADEC KPC
7.59 4.4 ND
ND 5.5 ND
7.32 6.9 ND
7.58 6.1 ND
Dissolved Oxygen
KLI ADEC KPC
8.38 6.5 ND
8.26 6.5 ND
8.07 6.9 ND
8.01 7.9 ND
Dissolved Oxygen
KLI ADEC KPC
7.79 6.6 ND
7.77 6.1 ND
7.71 7.1 ND
7.75 7 ND
Dissolved Oxygen
KLI ADEC KPC
8.65 7 ND
8.56 6.4 ND
8.15 6.6 ND
8.1 6.3 ND

-------
     Table  E-l,  cont.
I
NJ

Station
KLI 5-5
ADEC 65
KPC 	


Station
KLI 4-1
ADEC 41
KPC 14


Station
KLI 4-2
ADEC 42
KPC 15


Station
KLI 4-3
ADEC 43
KPC 16


Depth
sfc
1 m
5 m
10 m

Depth
sfc
1 m
5 m
10 m

Depth
sfc
1 m
5 m
10 m

Depth
sfc
1 m
5 m
10 m

KLI
14.17
14.13
ND
12.10

KLI
ND
ND
ND
ND

KLI
ND
ND
ND
ND

KLI
14.81
14.75
13.32
12.28
Temperature
ADEC
14.5
14.5
13.5
12
Temperature
ADEC
15.5
15
13.5
12.5
Temperature
ADEC
15.5
14.5
14
13
Temperature
ADEC
14.5
14.5
14
13
-
KPC
ND
ND
ND
ND

KPC
16.5
15.9
14.7
12.9

KPC
16. 1
16.1
15.2
13 .2

KPC
16.3
15.4
15
13.4
Salinity
KLI ADEC
24.12 23
24.24 23.5
ND 26
28 ND
Salinity
KLI ADEC
ND 22.5
ND 22.5
ND 25
ND ND
Salinity
KLI ADEC
ND 22
ND 23.5
ND 25
ND ND
Salinity
KLI ADEC
23.67 23.5
23.76 23.5
26.13 24
27.6 ND

KPC
ND
ND
ND
ND

KPC
24.2
25.3
27.3
29.4
Dissol
KLI
8.48
8.24
ND
7.86
Dissol
KLI
ND
ND
ND
ND
.ved
Oxycren
ADEC KPC
6.6
6.4
6.3
6.3
.ved
ADEC
5.7
6.4
8.3
7.1
Dissolved
KPC
24.4
24.3
24.2
29.1
KLI
ND
ND
ND
ND
ADEC
6.4
9.4
8.4
8.5
Dissolved
KPC
25.1
25.3
25.4
27.5
KLI
7.57
7.44
7.07
7.26
ADEC
8.4
9.2
8.5
8.1
ND
ND
ND
ND
Oxygen
KPC
5.3
5.3
7.2
4.7
Oxygen
KPC
5.4
5.4
6.4
4.6
Oxygen
KPC
7.5
7.6
6.7
4.6

-------
      Table E-l,  cont.
M
I
u>

Station
KLI 3-1
ADEC 31
KPC 9


Station
KLI 3-2
ADEC 32
KPC 10


Station
KLI 3-5
ADEC 35
KPC 13


Station
KLI 2-2
ADEC 22
KPC 5


Depth
sfc
1 m
5 m
10 m

Depth
sfc
1 m
5 m
10 m

Depth
sfc
1 m
5 m
10 m

Depth
sfc
1 m
5 m
10 m

KLI
ND
ND
ND
ND

KLI
ND
ND
ND
ND

KLI
ND
ND
ND
ND

KLI
ND
ND
ND
ND
Temperature
ADEC
16
15
14
13
Temperature
ADEC
16
15.5
14
12.5
Temperature
ADEC
15.5
15
14.5
ND
Temperature
ADEC
15
15
14
12.5
"•
KPC
16.8
16.1
14.5
13.6

KPC
16.5
16. 1
15.4
13.4

KPC
17.9
15.6
15.2
13.6

KPC
16.8
15.9
15.2
14.5

KLI
ND
ND
ND
ND

KLI
ND
ND
ND
ND

KLI
ND
ND
ND
ND

KLI
ND
ND
ND
ND
Salinity
ADEC
22
23
24.5
ND
Salinity
ADEC
22
22
24
ND
Salinity
ADEC
22.5
23
23.5
ND
Salinity
ADEC
22.5
22.5
24
ND
Dissolved
KPC
25.
25.
27.
27.
1
2
1
3
KLI
ND
ND
ND
ND
Oxygen
ADEC KPC
5.7
5.7
8
5.7
Dissolved
KPC
24.
24.
25.
29.
7
5
6
1
KLI
ND
ND
ND
ND
6.0
5.9
7
7.2
Oxygen
ADEC KPC
6.2
5.7
7.2
6.6
Dissolved
KPC
25.
25.
26.
30.
1
2
1
1
KLI
ND
ND
ND
ND
ADEC
4.5
5
6
ND
Dissolved
KPC
23.
24.
25.
27.
4
3
2
2
KLI
ND
ND
ND
ND
ADEC
6.5
6.1
7.7
6.9
5.2
5.1
6.1
5.0
Oxygen
KPC
5.7
6.0
6.5
5.4
Oxygen
KPC
5.4
5.1
6.1
4.5

-------
     Table  E-l,  cont.
M
I
Station
KLI 2-3
ADEC 23
KPC 6
Station
KLI 2-4
ADEC 24
KPC 7
Station
KLI 50
ADEC 50
KPC 50
Station
KLI 51
ADEC 51
KPC 51
Depth
sf c
1 m
5 m
7 m
Depth
sf c
1 m
5 m
8 m
Depth
sf c
1 m
5 m
7-10 m
Depth
sfc
1 m
5 m
10 m

KLI
ND
ND
ND
ND
KLI
ND
ND
ND
ND
KLI
14.46
14.37
13.47
12.91
KLI
14.18
14.18
12.52
12.06
Temperature
ADEC
15.5
15
14
12.5
Temperature
ADEC
15.5
15
14
12.5
Temperature
ADEC
15
14.5
14.5
12.5
Temperature
ADEC
14
14
14
13

KPC
16.2
16.8
15.9
15
KPC
16.3
15.6
14.5
20.1
KPC
15.6
15.4
15.2
14.7
KPC
15.4
15
14.5
12.5

KLI
ND
ND
ND
ND
KLI
ND
ND
ND
ND
KLI
24.04
24.17
25.92
26.72
KLI
23.88
23.89
27.13
28.56
Salinity
ADEC
21
23
24
ND
Salinity
ADEC
21
22.5
24
ND
Salinity
ADEC
23
23
24
ND
Salinity
ADEC
23.5
23.5
25
ND

KPC
23.1
24.4
25.7
28.3
KPC
25.6
25.1
27.2
23.3
KPC
26.1
25.2
25.4
26.1
KPC
25.2
25.1
26.1
29.2
Dissolved Oxygen
KLI ADEC KPC
ND 6.8 5.1
ND 6.8 5.0
ND 7.5 5.8
ND 8.2 5.2
Dissolved Oxygen
KLI ADEC KPC
ND 7.1 5.9
ND 6.6 6.2
ND 7.9 7.2
ND 7.5 5.0
Dissolved Oxygen
KLI ADEC KPC
8.32 8.6 7.3
8.25 9 7.4
8.15 10.1 7.4
8.25 9.1 7.3
Dissolved Oxygen
KLI ADEC KPC
7.96 9.7 7.8
7.5 9.8 7.9
6.86 9.7 7.4
6.59 9.4 5.5

-------
Table E-l, cont.
Station
KLI 2-5
ADEC 25
KPC 8
Station
KLI 1-1
ADEC 11
KPC 	
Station
KLI 1-2
ADEC 12
KPC 	
Station
KLI 1-3
ADEC 13
KPC 	
Depth
sfc
1 m
5 m
10 m
Depth
sfc
1 m
5 m
b
Depth
sfc
1 m
5 m
b
Depth
sfc
1 m
b

KLI
12.16
15.2
13.03
12.2
KLI
14.87
14.86
13
11.85
KLI
14.88
14.73
12.88
11.96
KLI
14.81
14.75
13.98
Temperature
ADEC
16
15.5
14
12.5
Temperature
ADEC
15
15
13
12
Temperature
ADEC
15.5
15.5
13.5
ND
Temperature
ADEC
15.1
15
ND

KPC
16.0
15.4
14.5
20.9
KPC
14
14
ND
13.3
KPC
14.0
14
13.2
ND
KPC
14
12
ND
Salinity
KLI ADEC
27.44 21
22.37 22
25.97 25
27.35 ND
Salinity
KLI ADEC
13.35 17
23.35 23
26.1 25
28.09 ND
Salinity
KLI ADEC
5.61 7
23.53 20
26.31 23
28.01 ND
Salinity
KLI ADEC
17.2 20.5
23.7 23
24.41 ND

KPC
24.8
25.1
27.2
22.1
KPC
8.2
25.1
ND
28.3
KPC
9.0
26.4
28.5
ND
KPC
25.2
24.4
ND
Dissolved Oxygen
KLI ADEC KPC
5.86 5 5.6
4.84 5.3 6.5
5.7 6.7 7.0
5.99 6.5 5.5
Dissolved Oxygen
KLI ADEC KPC
6.41 5.7 8.2
4.95 5.7 5.1
5.46 6.2 ND
0.25 0.5 .9
Dissolved Oxygen
KLI ADEC KPC
8.74 8.8 7.7
5.48 5.2 6.4
5.47 6 5.4
0.25 ND ND
Dissolved Oxygen
KLI ADEC KPC
8.21 5.4 6.5
5.1 5.3 5.4
5.75 ND ND

-------
Table E-2.   Intercalibration Sampling Matrix August 21, 1988
Station
50
51
5-1
5-2
5-3
5-4
5-5
4-1
4-2
4-3
3-1
3-2
3-3
3-4
3-5
2-1
2-2
2-3
2-4
2-5
1-1
1-2
1-3
KLI
11:25
11:10
11:45
12:00
12:10
12:25
12:35
-
-
12:45
-
-
-
-
-
-
-
-
-
18:25
19:15
19:45
20:00
KPC
11:25
11:10
NS
NS
NS
NS
NS
12: xx
12: xx
12:45
13: xx
13: xx
13: xx
13 :xx
15:00
15: xx
15:40
16:00
15:20
18:25
19:15
19:45
20:00
ADEC
16:35
16:45
11:35 (T,
11:45 (T,
12:05 (T,
12:20 (T,
12:30 (T,
17:45
17:10
17:00
17:20
17:35
17:45
-
15:00
-
15:40
16:00
15:20
18:25
19:15
19:45
20:00



S)
S)
S)
S)
S)
















xx    -  Exact Time not available
NS    -  No Sampling
(T,S) -  Valid data for temperature and salinity only
                                E-6

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               APPENDIX F
EPA ENVIRONMENTAL RESEARCH LABORATORY
         (DULUTH) DIOXIN STUDY

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               NDS PHASE  II:   5I04CCUMULATIVE
                         Sample "Tracking System
 EPISODE s
            3245
                                          SCC  #:
                                                        \[\\    '••'•' ; {,~:*f.c."-'-'sS?!ff"™
                                                        U Vl  , ,', p .v"-:V--10:QQ';;-
                                                                 ... %- 'J'    I" • .,-._ •-:
.•Utnx  Type:
Sa.-nple  Composite:
              W 131
            ved:   1
                                                                 ' 44V20"
                                                                 1/11/87.
fincllytic^l:
   extraction Dat?
           G C / # 5 I J
             Lie I J
             .-/eight
             %'- i c i d
    -P£  InciCction
                   2/ 2/? ?
                  ••' A T i 5 0 4 5 0
                  G 0 2 0 2 8 c C S
                  20.0?
                   4.2
Pesticide  & Industrial Chemicals
           O/ O/  0
                              .BSE lipic  on GPC:
           0.00
           0.0
           0.000
Comments :
                                   F-l

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            NDS PHASE ii:  BIOACCUMULATIVE  POLLUTANT STUDY


EPISCQc.a:   3245                 SCC  *:   DJ023624        ERL-D Loc.:    235  '

DATA  for  al0 SIGN ICICANT  PCLYCHLORIN ATEO  DI5ENZODIDXINS AND FURANS:  '
Analyte                CfiS No.:    Ion  Qatio    S/N   S&REC Det. Lim.  Amo'untCpg/g)
2,3
2,2
3,4
2,3
1 ,2
2,3
2,3
1 , -
1,2
1 ,2
1,2
2 , :.
i,:
1,2
1,2
1,2
1,2
,7,5- TCDF
,o,7- TCOF
,6,7- TCO=
,7,d- TCDD
,5,7,i- ? e C D F
,4,7,3- P e C 5 = #
,-,o,7- P '- C D F
,^,7,-i- r 3 C J _
,3, ,.6, 7- HxCDF ,=#
, 5 ,-»,?, 8 - -i x C 0 F *
, 3 , e , 7 , o - r, x L 3 =
, a , 6 , 7 , 3 - -• x C D F "#
, j , 7 , 6 , ? - - x C D .-
,5,4,7,8- nxCDD
,3,6,7,5- n x C D D
,3,7,3,9- rlxCDD
, 3 , t , 6 , 7 , 3 - h j C D F -=
51207-31-9 0.
17-.6-01-S 0.
57117-41-5 2.
5 7117-31-4 0.
0.
40311-76-4 2.
7JD4S-23-9 0.
Q _
19405-74-3
f 7 -5 3-5 5-7 0.
^7: £-2-39-4 0 .
55.C-72-39-7 0.
i7-: 71-00-- D.
32598-13-3 0.
1.
0.
0.
95
00
54
58
00
46
00
^

00
00
CO
00
00
04
00
s 5
niiWv^s-^o* o.oo
-U2
.". •
V •

,3»4,6i7»8- HoGOD
Coeiute s with 123
Indication of OPE
0..9.7,.
478 rlxCOF on D35
interfersnce at.
30
this
1.
1.
1.
1.
1.
1.
1.
** •

1.
1 .
1.
1 .
1.
1.
1.
1
1.
22.

00
00
00
00
00
00
00
77

00
00
00
00
00
00
00
00
00
,10

80
80
80
84
82
82
32
89

35
85
85
85
89-
39 .
39
75
-J-5
77

1.
0.
u.
•1.
0.
1.
0.
0.

2.
2.
1.
2.
- -:>2.
". :: "-"^ *
— n
i.
,2.
&$

2500
49
00
4900
1.1
77
08
82
00

83
84
00 .
00
00
00
00

00
00
9600
77
00
4.600
01
rS p
45
Al


00
o n :
00
0.0.,,
i.OB

ND
NO
ND
ND
ND
ND
ND
(

ND
ND
ND
ND
ND
ND
:V NO
ND
L^.*JiP


'ispmer .
        Toxicity  Equivalency ConcentrationJ
        Percent  Contribution of 23.78"TCDF»
        2378  TCDD and 12378 PeCDD to total
        T£F  value:                                 '9,9,
                                                                         0.24
                                   F-2

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 EPISODE #.
              NDS  PHASE  II:   8IOACCUMULATIVE POLLUTANT  STUDY
                       Sample Tracking System           ERL-D
3245
                                         SCC  *'
DJ023624
                                                 Loc
                                                                    235
Sampling Information:
   Sampling Office:  U.S. FISH
   State L City:   AK. JUNEAU
   Sampling Contact:  EVERETT ROBINSON-uj
   Date Sampled:    6/18/87
   Site Location:  AK  WARD COVE NEAR
   Latitude:   N 55 23'45"
   Analysis Lab:   D
   Matrix Type:  F W3  FLATHEAD
   Sample Composite:  10
                                 AND WILDLIFE SERVICE
                                 SOLE
                               Longitude:   W 131 44'20M
                               Date  Received:   11/11/87
                               Species  Code:
Analytical:
   Extraction Date:
          GC/MS ID:
            LAB ID:
            Weight:
            %Lipid
    DPE Indication
        PCDD/PCDF             Pesticide I Industrial Chemicals
         2/ 2/88                        9/21/88-
        MAT880450                      DR88868
        G020288CS                      J092188JJ
        20.03                          20.07
         4.2                            3.9
        Y          Mass  lipid on  GPC:   0.790
Comments:
                                   F-3

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tPlSODE #:   3245
SCC *:  DJ023624
                           ERf-D Loc.:
                                   235
      Target Analyte
  I»3f5- Trichlorobenzene
  1»2»4- Trichlorobenzene
  1»2»3- Trichlorobenzene
  Hexachlorobutadiene
  1,2,4,5- Tetrachlorobenzene
  1*2,3»5- Tetrachlorobenzene
  Siphenyl
  1,2,3,4- Tetrachlorobenzene
  Pentachlorobenzene
  Trifluralin
  Alpha-BHC
  Hexachlorobenzene
  Pentachloroanisole
  Gamma-BHC CLindane)
  Pentachloronitrobenzene
  Diphenyl Disulfide
  Heptachlor
  Chlorpyrifos
  I sopropalin
  Octachlorostyrene
  Heptachlor epoxide
  Qxychlordane
  Chlordane, trans
  Chlordane» cis
  Nonachlor, trans
  p,P '- DOE
  Dieldrin
  Nitrofen
  End rin
  Perthane
  Chlorbenzilate
  Nonachlor, cis
  Methoxychlor
  Dicofol  CKelthane)
  Mirex
  Total Monochlorobipheny1
  Total Diehlorobiphenyl
  Total Trichlorobiphenyl
  Total Tetrachlorofaiphsny1
  Tot.al Pentachlorobiphenyl
  total Hexachlorobiph.nyl
  TotaJL Heptachlorobiphenyl
  T o t at" Oct ach'lo rbbi pn^rfyl:
  Total Nonachlorobiphenyl
  Total Oecachlorobipheny1
  Jotal Polvchlorinated Biphenyls

  Mercury   (  AA analysis)
  CASRN
  108-70-3
  120-82-1
   87-61-6
   87-68-3
   95-94-3
  634-90-2
   92-52-4
  634-66-2
  608-93-5
 1582-09-8
  319-84-6
  118-74-1
 1825-21-4
   58-89-9
   82-68-8
  882-33-7
   76-44-8
 2921-88-2
33820-53-0
29082-74-4
 1024-57-3
26880-48-8
 5103-74-2
 5103-71-9
39765-80-5
   72-55-9
   60-57-1
 1836-75-5
   72-20-8
   72-56-0
  510-15-6
 3734-49-4
   72-43-5
  115-32-2
 2385-85-5
27323-18-8
25512-42-9
25323-68-6
26914-33-0
25429-29-2
2A60.l-.64-4
28655-71-2
           QA Flag
53742-07-7
 2051-24-3
 7439-97-6  NO
                             CONCN
                              NO
                              NO

                              NO
                              NO
                              NO
                              NO
                              NO
                              NO
                              NO

                              NO
                              NO
                              NO
                              NO
                              NO
                              NO
                              NO
                              NO
                              NO
                              NO
                              NO
                              NO
                              NO
                              NO

                              NO
                              NO
                              NO
                              NO
                              ND
                              ND
                              ND
                              ND
                              NO
Cng/g)
                             0.27
                              ND
                              NO
                            ug/g
                             7.48
                              5.29
                                    1.99
                                    5.02
                                    10.-1
                                    47.3
                                    51.3
                                    0.85
                                      129
   Iod obenzene
   lodonaphthalene
   4»4'-Diiodobiphenyl

 C ommen t s•
                                   F-4

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