EPA-AA-SDSB-84-3

                   Technical  Report
              Corrections  for  Variations
               in Test Fuel Properties
                          By

                    G.  D.  Thompson
                        NOTICE

Technical Reports  do not  necessarily represent  final  EPA
decisions  or  positions.    They  are   intended  to  present
technical   analysis   of   issues   using   data  which  are
currently available.   The purpose  in the  release  of such
reports  is   to   facilitate  the   exchange  of  technical
information   and   to   inform   the  public   of  technical
developments  which   may  form  the  basis  for  a  final  EPA
decision, position or regulatory action.

       Standards Development  and Support Branch
         Emission  Control  Technology Division
               Office of Mobile  Sources
             Office of Air and Radiation
        U.  S. Environmental Protection Agency

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I.   Introduction

     General Motors  Corporation has recently  asserted that the
test fuel used at the  EPA/MVEL  has  varied in energy density and
carbon content  since 1975.[1]  General Motors has subsequently
requested  that  a  CAFE  correction  be  granted  to account  for
these variations in fuel properties.

     GM  has submitted  data  demonstrating  that  the  test  fuel
used by GM has varied  since  1975.   Since  EPA and GM obtain fuel
from the same sources  it  is  probable  that the EPA test fuel has
also  varied in  a similar  fashion.   If  so,  this is  a  change
which would  systematically affect the measured  fuel  economy of
test  vehicles  and  hence  corporate  average  fuel  economies
(CAFE).   This   change   is  similar  to previous  test  procedure
changes for which CAFE corrections have been proposed.[2]

     The  report  develops  a  simple   correction  based  on  the
energy  content  per  unit  carbon  of  the  fuel.   The   correction
proposed by  GM  is also discussed, as  is  the problem of limited
available data on the test fuels.

II.  The Correction for Test Fuel Properties

     The  EPA exhaust   emission  and  fuel  economy measurements
determine  the  quantity  of  carbon  combusted  by the  vehicle
during the  test.  The  carbon balance  equation then computes the
volume  of  fuel  which  must have  been   burned  to   yield  the
measured  amount  of   carbon.    The  coefficients  of  the  EPA
equation are  currently  fixed  numerical  values  which  in effect
define a reference test fuel.

     If  the  carbon content  of  the fuel  varies in time,  as GM
has asserted, then the  present  carbon balance equation will not
give  the  true  volume  of  the  test  fuel  consumed.    It  will,
however, continue to  give the  correct quantity of the original
reference  fuel  which  would  have to  be   consumed to  give  the
measured   carbon.    Therefore   the   carbon   balance   equation
automatically adjusts  the  fuel  economy calculation for whatever
fuel is used back to a volume of the reference fuel.

     While the carbon balance equation automatically adjusts

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                              -2-
the  fuel  economy  calculation  for the  carbon  content  of  the
fuel,  it  does not  consider  how the  engine is  affected  by the
fuel.  For long term  variations  in the fuel properties, such as
those  which  appear  to have  occurred  at the  EPA/MVEL,  the fuel
delivery  to   the  engine  will  be  adjusted to  account  for  the
energy content.  This will occur automatically with some closed
loop  fuel  control   systems  and  manually through  calibration
adjustments  in  other instances.   This will be  required either
to  maintain  vehicle driveability  or  to maintain  acceptable HC
and CO emissions.

Ultimately the  energy content is  the most important  aspect of
the  fuel  to  the  engine.   If the energy  content of  the fuel
decreases the engine must burn  more  fuel to provide  the same
amount of work  output.   Therefore, fuel economy corrections for
changes in fuel properties should  be  formulated  in terms of the
energy  content  per  unit   carbon  of  the  fuel.   Since  the
variations  in  the   fuel  properties   have been  small,   it  is
reasonable to state that  the  fuel consumption  is proportional
to the energy content per unit carbon of the fuel.  That is:
          = COM
               fc
                                             (1)
Where:
     COMr =
       Er =
the quantity of the  reference  fuel  which would
be consumed

the measured consumption of test fuel

the  energy  content  per   unit  carbon  of  the
actual fuel

the  energy  content  per   unit  carbon  of  the
reference fuel
     Equation 1 simply  states  that the quantity of carbon which
is burned  is proportional  to  the  energy content  of  the fuel.
If the  actual  fuel  has  more  energy  per  unit carbon  than  the
reference  fuel,  say  10  percent  more,  then  10  percent  more
carbon of  the  reference carbon fuel would have  to be burned to
provide the  necessary  energy for  the  fuel  economy or emissions
test.

     Fuel  economy  is  proportional   to  the  inverse  of  fuel
consumption.  Therefore equation  1 may alternately be expressed
as:

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                              -3-
     MPGr=MPGmET                                           (2)
                  a

Where:

     MPGr = the fuel economy using the reference fuel

     MPGm = the measured carbon balance fuel economy

     The  energy  content per  unit carbon  of  the fuel  is  not a
normally  measured  parameter  but it can be calculated from mass
specific  heating  value  of   the  fuel and the  carbon  weight
fraction.  That is:

     E = L/C                                                  (3)

Where:

     E =   the energy content per unit carbon of the  fuel

     L =   the mass specific lower heating value of the fuel

     C =   the carbon weight fraction of the fuel

Using equation 3 in equation 2:
                 L /C

     MPGr ' MPGm ITTcr
                 L  C
     MPG  = MPG  _f _
               m L  C
                                                              (4)
     The  first  technical  report  for  fuel  economy corrections
demonstrated  that  if each  measured fuel  economy was corrected
by  a  constant  proportion  then  the  corporate  average  fuel
economy  (CAFE)  would be  modified  by  the  same proportion. [ 1]
Therefore:
     CAFE1  = CAFE  -=-   -                                      (5)
                   JL  C
                    a  r

Where :

     CAFE1  =     the CAFE corrected to the 1975 fuel conditions

     CAFE  =     the measured CAFE

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                              -4-
Subtracting the measured value from each side of equation 5:


                         Lr Ca
     CAFE  - CAFE = CAFE ^- ^ - CAFE                         (6)
                         LJ  C.
                          a  r

or
        ACAFE = / r-^ -^- - 1 I CAFE
Where:

      4 CAFE = the required CAFE correction or CAFE adjustment

     The  numerical  values  for  the CAFE  corrections,  or CAFE
adjustments, are presented later in Section V.

Ill . The General Motors Approach

     The  correction  proposed by GM  is a more  complex two step
approach. [2]   First,  the carbon  balance measured  fuel economy
is  corrected  to  a  true  volumetric fuel  economy based  on the
carbon content of the  test  fuel.   Then an empirical sensitivity
coefficient is used  to  adjust  this volumetric fuel economy to a
fuel economy of the 1975 model year fuel.

     The  correction  to  the  volumetric  fuel  economy of the test
fuel is:

                 CV
Where :

     MPG^ =      the true volumetric fuel economy of the test

     MPGm =      the measured carbon balance fuel economy

      CVa =      the carbon volume fraction of the test fuel

     CV,.,}-, =      the  carbon  volume  fraction  assumed  in  the
                 carbon balance equation

     In order to  correct  the  present volumetric fuel economy to
the  fuel  economy which would  have occurred with  1975  fuel the
GM approach  assumes  that  the correction  is  proportional  to the
change  in  the  volumetric  heating  values  of  the  fuel.   A
dimensionless sensitivity coefficient is defined as:

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                              -5-
         MPG.  - MPG
                       LV.  - LV
Where :

        R =

     MPGr =

      LVt =
      LVr =
                 the sensitivity coefficient

                 the fuel economy with the 1975 fuel

                 the lower volumetric heating  value  of  the  test
                 fuel

                 the  lower  volumetric  heating  value  of  the
                 reference fuel
     Solving equation 8 for the reference fuel economy gives:
     MPGr = MPGfc

                                                             (9)
     Using equation 7  for  the  test  fuel economy gives the total
correction as:
                 CV
     MPGr '
     Equation  10  uses  the  volumetric heating  values  and  the
volumetric  carbon   fraction  of  the  fuel.    Both  of  these
parameters  are,  however,  usually  measured and  reported on  a
mass  specific basis.   The  conversion  from  mass   specific  to
volume  specific  for  either  of  these  parameters is,  using  the
carbon fraction as an example:
     CV = (C)(S)(MH20)
                                                             (11)
Where :
        S =      the specific gravity of the fuel

     MH20 =      the mass of a unit of water

     Using equation 11  and  the  similar equation for the heating
value  of  the  fuel  in  equation 10  gives  the  final correction
equation by the GM method:

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                              -6-
                 - S(mH O)
     MPG  = MPG  -- - rV-m    L S  (mH 0)
        r      m C ,S ,  (mH_O)  nr t t   2       -,    ..
                  cb CD   2    R|r — = — ,     \  -  1J  + 1
                                 L S  (itiH-O)



                  C S             1
                   a a
          = MPG    " "       L S

               m CcbScb    (R JLj^- -  1)  +  1

                             LrSr


Rearranging terms results  in:


                  C S            L S

          = MPG    a a            rr
                          R/L q - Lq  \  +  L  q
               m CcbScb   R(LtSt ~ LrSr)  +  LrSr
                  C S L S   r	1	

          = MPGm   %a * *  l      ITs-     LIT

               m CcbScbLtSt  R(i - JL±)  +  ^
                                    tt      tt


But  the  carbon  balance  and  the  reference  parameters  are  the

same, that is:



     Ccb = Cr                                                (14)



     scb = sr


And the test and actual parameters are the  same:



     St = Sa                                                 (15)



Therefore:




                 C  S  L  S   f _ 1 _ -,

     MPG  = MPG  T^3- ^ ^ ^  L    LS      LSJ
        r      mCSLS^   -rr^.Tr
                  r  r  a  a R - R --R  +   --
                                     a a    a  a



                 C  L    i-       L         -i                  /i>.\

          = MPG  ^^   C - ITS - ]                  U6)

               m Cr La    R + j±t  (i _ R)

                               a a


IV.  Discussion



     The correction  developed  in Section  II  of this  report  and

that  developed  by  GM  are  quite  different   in   their   basic

concepts.   Mathematically,  however,  the  results  are  related.

The relationship is most easily shown by considering equation

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                              -7-
16 in the special case where R = 1.  In this case:



     MPGr ' MPGm (T IT                                       (17>
                  r  a
Equation 17 is identical to equation 4 of the EPA approach.

     The parameter  R may be  considered as  the  efficiency  with
which   the   vehicle   engine   adapts   to  fuel   variations.
Mathematically the difference  between  the EPA and GM methods is
simply  this  efficiency value.  GM  proposes an  efficiency value
of  0.6 based  on  tests  with  multiple fuels  in  fixed vehicle
configurations.   However   the  variations   in   the  EPA   fuel
properties  have   occurred   slowly  while   the   vehicles   were
continuously tested  and  modified.   It  is  unreasonable to expect
that  a 1985  vehicle  carefully calibrated on  1984  test   fuel
would  use  the  higher  energy  per  gallon  of  this   fuel as
inefficiently as would  a 1975 vehicle  which had been calibrated
on 1975 fuel.  As  long  as the variations  are gradual it is  more
logical  to  assume  that  the  vehicles  will  adapt  to  these
variations  with  high  efficiency,  either  automatically through
closed  loop  fuel  control systems  or  through manual calibration
changes.

     A  second  area  of questionable  accuracy  with  the GM
approach occurs when the energy content  per  unit volume of the
fuel decreases.   In this case,  the efficiency  term reduces or
discounts  the  calculated  correction.   For  example,  if  the
energy  content per  unit volume  decreased  by  20  percent,  the
fuel economy  correction  would only be  about  10  percent.  It is
unlikely that  vehicles  could  tolerate  a significant decrease in
the  energy   density  of  the   fuel   without  experiencing  an
equivalent decrease  in fuel economy.

V.   Results

     The EPA  approach  and the GM  approach  both  require data on
the  lower  heating  value and  the carbon  weight  fraction of the
fuel.   Neither  of these parameters were  routinely measured by
EPA  in  the  past.   Therefore,  these  data  are not  presently
available  at  EPA  although  efforts  are  being  made  to acquire
whatever  data may  be available  from  fuel suppliers.   GM  did
submit  data  on the  density  and other  properties  of their  test
fuel.   The   GM   data   are   given  in   Table   1.    Using  the
hydrogen/carbon  ratios  submitted  by  GM,  the  carbon  weight
fraction of the fuel may be calculated by:


     C = (12.011)/(12.011 + 1.008 HC)
(18)

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                       Table 1



                Test Fuel Properties*
Calendar
Year
1979
1980
1981
1982
1983
1984
Speci fie
Gravity
0.739
0.742
0.747
0.749
0.749
0.751
API
Gravity
59.97
59.20
57.92
57.42
57.42
56.92
Aromatics
Volume %
26.5
26
26.7
29.8
31.8
31
Avg. Dist.
Temp. , °F
220
222
219
220.3
220
221
Hydrogen/
Carbon Ratio
1.85
1.86
1.81
1.80
1.79
1.77
Data Submitted by General Motors, Reference 1.

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                              -9-
Where:

        HC = the hydrogen/carbon ratio

     12.011 = the atomic weight of carbon

      1.008 = the atomic weight of hydrogen

     The  heating  values  of  the  fuels  may be  estimated  by
empirical  equations  developed  by ASTM  or a  simplier equation
from Marks'  Mechanical  Engineering  Handbook.[3,4]   The  carbon
weight  fractions,  the  specific  gravity  of  the  fuel and  the
estimated  heating  values  are  given  in  Table  2.   Both  the
heating  values   and   the  variation   in   the   heating  values
calculated by the  different  methods  are notably different.  The
variations  computed  by  the  method  of  Marks'  handbook  are  so
small  that  the  effect  from  the change  in  heating value  is
insigni ficant.

     Table  2  demonstrates  that  a   major uncertainty   in  the
computed correction  will be  the  heating values of  the  present
and past  fuels.   Measured data would  be highly desirable since
both of  the methods of  this report have  questionable aspects.
The  AS1M  method was  developed  for  aviation   fuel,  primarily
kerosene-like jet  fuels  and  may not  be applicable to automotive
gasoline.  The method published by Marks is a much more  general
approach  for  a  wide  range  of  petroleum  products  and  its
precision  in  estimating   the   heating  values  for  different
automotive gasolines is also questionable.

     The results of Table  2,  together  with  a  CAFE  value,  are
sufficient to calculate  the correction  by  either  the Ol  or EPA
approach.   Most  manufacturers  have   CAFE1  s   near   the  CAFE
standards.  Therefore, using  the  CAFE standards is a reasonable
approach to  estimate  the typical  CAFE   correction for the fuel
change.   These   corrections,  based  on  the  CAFE  standards  are
given in Table 3.

VI.  Conclusions

     It  is appropriate  to  develop a  CAFE correction for  changes
in  test   fuel   parameters.    The  following   equation   is  the
simplest and most logical correction:

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                            Table 2

                     Test Fuel Properties
Calendar
Year
1979
1980
1981
1982
1983
1984
Specific
Gravity
0.739
0.742
0.747
0.749
0.749
0.751
Carbon
Weight
Fraction
.8656
.8650
.8681
.8688
.8694
.8707
Lower Heating Values
ASTM*
(Btu/lb)
18,517
18,515
18,481
18,434
18,407
18,412
Marks' **
(Btu/lb)
19,035
19,013
19,013
19,008
19,014
19,014
*    Calculated by the method given in Reference 3.
**   Calculated by the method of Reference 4.

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                              Table 3

                          CAFE Correction
                                     CAFE Corrections
Model
Year (1)
1980(4)
1981
1982
1983
1984
CAFE
Standard
(MPG)
20
22
24
26
27
GM Method (5)
ASTM (2)
(MPG)
0
0.022
0.201
0.307
0.362
Marks (3)
(MPG)
0
0.036
0.190
0.259
0.282
EPA Method
ASTM (2)
(MPG)
0
-0.013
0.116
0.214
0.281
Marks' (3)
(MPG)
0
0.010
0.097
0.133
0.148
(1)   All  vehicles of any model year are  assumed  to be tested in
     the  previous calendar  year.
(2)   Lower  heating value from ASTM  calculation.
(3)   Lower  heating value from Marks'  Handbook calculation.
(4)   1980 model  year  (i.e.,  1979  calendar  year  taken  as  the
     reference).
(5)   The  CAFE corrections as  calculated  by GM were based on the
     GM  CAFE's,  not  the CAFE standards.  GM' s  calculated  CAFE
     corrections   were   .0208,  .1934,   .2722  and  .3228  mpg  for
     model  years  1981 through 1984,  respectively.

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                              -12-


Where:

     Lr =    the lower heating value of the reference fuel

     La =    the lower heating value of the actual test fuel

     Ca =    the carbon weight fraction of the actual test fuel

     Cr =    the carbon weight fraction of the reference fuel


     This  correction  is based  only on  the energy  content  per
unit of carbon  of  the fuel.   Other,  more complicated correction
equations can also be developed.

     Relatively  little  actual  fuel  data  are  available.   For
example,  no  measurements  of the  heating  value of  the  1975
reference fuel are known.  The  lack  of data is  a  major cause of
uncertainty in this correction.

     Calculated corrections  for  model  year 1984,  the  year with
the greatest CAFE  correction, range  from 0.148  mpg to 0.362 mpg
depending on  the  method of  the calculation used  and  estimated
heating values of the fuel.

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                              -13-
                           References

     1.    Letter  to  R.   E.  Maxwell,  Certification  Division,
Office  of  Mobile  Sources,  U.S.  EPA,  from W.S.  Freas,  General
Motors Emission and Fuel Economy  Operators, August  15, 1984.

     2.    "CAFE   Corrections   for  Test   Procedure  Changes,"
Thompson,  Glenn D. ,   U.S.  EPA,  OAR,  CMS, ECTD,  SDSB,  October
1983.

     3.    "Standard   Methanol    for   Estimation   of   Heat  of
Combustion of Aviation Fuels," ASTM  Standard D 3338, 1979.

     4.    Marks'   Standard Handbook  for Mechanical  Engineers,
Baumeister, Avallone, Baumeister, McGraw Hill 8th Edition,  1978.

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