71-24 Exhaust Emissions from a Passenger Car With Gasoline Treated With Bycosin Fuel Additive April 1971 Leonard D. Verrelli Division of Emission Control Technology Mobile Source Pollution Control Program Air Pollution Control Office ENVIRONMENTAL PROTECTION AGNECY ------- Vehicle Tested In order to evaluate the effects of the additive Bycosin a 1962 Chevrolet Impala was selected. There is extensive data on this vehicle and it has a record of good repeatability. This vehicle is equipped with a 283 cubic inch V8 engine and automatic transmission. The additive was mixed with Indolene 30 fuel as specified by the manufacturer. Tests Conducted The following four tests were performed on the vehicle: 1. Standard 1970 Federal test procedure for exhaust emissions (Table 1). 2. Closed, constant volume sampling technique using nine repeats of the 7-mode 1970 Federal emissions test cycle (Table 2). 3. Standard 1972 Federal test procedure using the LA-4- S3 driving cycle with constant volume sampling (Table 3). 4. Steady State Test procedure, using the continuous sampling technique (Table 4). For the 1970 Federal test procedure, oxides of nitrogen were analyzed using a continuous non-dispersive infrared technique. For the constant volume sampling tests oxides of nitrogen were measured using both the wet chemical modified Saltzman technique and the electrochemical "NOX Box". Carbon monoxide was measured using non-dispersive infrared and hydro- carbons were determined using a flame ionization detector. ------- - 2 - Emission Results In Table 1 comparisons are made between two identical tests using the 1970 Federal test procedure. Minor increases were noted in hydrocarbons and carbon monoxide emissions but oxides of nitrogen showed a minor decrease in emissions. Table 2 constant volume tests shows the same type of emission results. X The 1972 Federal test procedure reported in Table 3 shows a specific improvement in hydrocarbons, carbon monoxide and oxides of nitrogen. During steady state conditions shown in Table 4 hydrocarbons and carbon monoxide data consistently showed a significant reduction, oxides of nitrogen increased considerably at all speeds. A 1963 Chevrolet Impala with automatic transmission was used for this test only. Conclusions Data from tests utilizing a cyclic driving pattern differed considerably from that of steady state operation. The steady state operation showed a significant increase, the exact opposite was found when the cyclic driving patterns were driven. These data proved to be inconclusive in that no consistant repeatable data was obtained. ------- - 3 - To be able to obtain consistent data complex programs have to be developed to provide a confidence factor in any improvements found. Unless extensive testing is accomplished it is impossible to say conclusively what the effects of Bycosin would be on emissions for the total car population. The results of this test do not justify such a program by this Agency. ------- TABLE 1 1970 Federal Test Procedure HC gpm CO gpm NOx Baseline (Indolene 30) 7.25 71.66 4.14 Bycosin (Indolene 30 plus additive) 7.79 72.20 3.62 Percent Reduction from Baseline -6.93% -0.88% 12.6% (Increase) (Increase) TABLE 2 9 Cycle Constant Volume Sampling HC gpm CO gpm NOX gpm Baseline (Indolene 30) 10.58 89.31 4.35 Bycosin (Indolene 30 plus additive) 10.92 92.98 4.26 Percent Reduction from Baseline -3ill% -3.94% 2.06% (Increase) (Increase) TABLE 3 1972 Federal Test Procedure HC gpm CO gpm NOX gpm Baseline (Indolene 30) 9.5 112.3 4.15 Bycosin (Indolene 30 plus additive) 8.33 101.19 3.81 Percent Reduction from Baseline 12,32% 9.89% 8.19% gpm indicates calculated mass in grams per mile ------- TABLE 4 Steady State State 10 MPH 20 MPH 30 MPH C 40 MPH 50 MPH Baseline HC CO NO HC CO NO HC CO NO HC CO NO HC CO NO 254.1 2.2 118.1 276.7 1.9 242.1 354.5 2.0 517.6 411.5 4.1 601.8 370.7 4.1 846.9 314.6 2.3 104.4 299.9 1.7 206.6 382.9 2.21 381.5 376.6 3.1 724.2 371.3 4.2 829.3 Addi tive 230.3 1.3 158.1 254.1 1.2 327.2 327.9 1.4 612.9 * 391.9 3.8 665.2 356.4 3.6 985.5 260.9 1.4 136.2 270.0 1.1 265.7 368.2 1.6 619.7 388.2 2.6 924.2 354.5 3.4 1003.3 % Reduct 13.6% 39.6% -24.4% 9.1% 36.0% -22.9% 5.6% 28.6% -27.0% 1.0% 11.1% -16.6% 4.2% 16.6% -15.7% HC and NO given in ppm (parts per million) CO given in % ------- |