71-24
     Exhaust Emissions from a Passenger Car
With Gasoline Treated With Bycosin Fuel Additive
                   April 1971
               Leonard D.  Verrelli
     Division of Emission Control Technology
     Mobile Source Pollution Control Program
          Air Pollution Control Office
         ENVIRONMENTAL PROTECTION AGNECY

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Vehicle Tested
In order to evaluate the effects of the additive Bycosin a
1962 Chevrolet Impala was selected.  There is extensive data
on this vehicle and it has a record of good repeatability.
This vehicle is equipped with a 283 cubic inch V8 engine
and automatic transmission.  The additive was mixed with
Indolene 30 fuel as specified by the manufacturer.

Tests Conducted
The following four tests were performed on the vehicle:
    1.  Standard 1970 Federal test procedure for exhaust
        emissions  (Table 1).
    2.  Closed, constant volume sampling technique using
        nine repeats of the 7-mode 1970 Federal emissions
        test cycle (Table 2).
    3.  Standard 1972 Federal test procedure using the LA-4-
        S3 driving cycle with constant volume sampling
        (Table 3).
    4.  Steady State Test procedure, using the continuous
        sampling technique (Table 4).
For the 1970 Federal test procedure, oxides of nitrogen
were analyzed using a continuous non-dispersive infrared
technique.  For the constant volume sampling tests oxides of
nitrogen were measured using both the wet chemical modified
Saltzman technique and the electrochemical "NOX Box".  Carbon
monoxide was measured using non-dispersive infrared and hydro-
carbons were determined using a flame ionization detector.

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                          - 2 -

Emission Results

In Table 1 comparisons are made between two identical tests

using the 1970 Federal test procedure.  Minor increases

were noted in hydrocarbons and carbon monoxide emissions

but oxides of nitrogen showed a minor decrease in emissions.


Table 2 constant volume tests shows the same type of emission

results.

 X
The 1972 Federal test procedure reported in Table 3 shows

a specific improvement in hydrocarbons, carbon monoxide and

oxides of nitrogen.


During steady state conditions shown in Table 4 hydrocarbons

and carbon monoxide data consistently showed a significant

reduction, oxides of nitrogen increased considerably at

all speeds.  A 1963 Chevrolet Impala with automatic

transmission was used for this test only.


Conclusions

Data from tests utilizing a cyclic driving pattern differed

considerably from that of steady state operation.  The

steady state operation showed a significant increase, the

exact opposite was found when the cyclic driving patterns

were driven.


These data proved to be inconclusive in that no consistant

repeatable data was obtained.

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                          - 3 -



To be able to obtain consistent data complex programs have



to be developed to provide a confidence factor in any



improvements found.  Unless extensive testing is accomplished



it is impossible to say conclusively what the effects of



Bycosin would be on emissions for the total car population.



The results of this test do not justify such a program by



this Agency.

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                              TABLE 1

                    1970 Federal Test Procedure

                                     HC gpm     CO gpm      NOx

Baseline (Indolene 30)                7.25       71.66       4.14

Bycosin (Indolene 30 plus additive)   7.79       72.20       3.62

Percent Reduction from Baseline      -6.93%      -0.88%     12.6%
                                   (Increase)  (Increase)
                              TABLE 2

                 9 Cycle Constant Volume Sampling

                                     HC gpm      CO gpm      NOX gpm

Baseline (Indolene 30)                10.58       89.31       4.35

Bycosin (Indolene 30 plus additive)   10.92       92.98       4.26

Percent Reduction from Baseline       -3ill%      -3.94%      2.06%
                                     (Increase)   (Increase)
                              TABLE 3

                    1972 Federal Test Procedure

                                     HC gpm      CO gpm      NOX gpm

Baseline  (Indolene 30)                 9.5       112.3        4.15

Bycosin  (Indolene 30 plus additive)    8.33      101.19       3.81

Percent Reduction from Baseline       12,32%       9.89%      8.19%
gpm indicates calculated mass in grams per mile

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                               TABLE 4

                            Steady State
State
10 MPH


20 MPH


30 MPH
C


40 MPH


50 MPH


Baseline
HC
CO
NO
HC
CO
NO
HC

CO
NO
HC
CO
NO
HC
CO
NO
254.1
2.2
118.1
276.7
1.9
242.1
354.5

2.0
517.6
411.5
4.1
601.8
370.7
4.1
846.9
314.6
2.3
104.4
299.9
1.7
206.6
382.9

2.21
381.5
376.6
3.1
724.2
371.3
4.2
829.3
Addi tive
230.3
1.3
158.1
254.1
1.2
327.2
327.9

1.4
612.9
* 391.9
3.8
665.2
356.4
3.6
985.5
260.9
1.4
136.2
270.0
1.1
265.7
368.2

1.6
619.7
388.2
2.6
924.2
354.5
3.4
1003.3
% Reduct
13.6%
39.6%
-24.4%
9.1%
36.0%
-22.9%
5.6%

28.6%
-27.0%
1.0%
11.1%
-16.6%
4.2%
16.6%
-15.7%
HC and NO given in ppm (parts per million)
CO given in %

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