71-25
Exhaust Emissions from Two Passenger Vehicles
           Equipped with "Fumcell"
                 April 1971
               Henry L. Gompf
   Division of Emission Control Technology
   Mobile Source Pollution Control Program
        Air Pollution Control Office
       ENVIRONMENTAL PROTECTION AGENCY

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                                               71-25
Exhaust Emissions from Two Passenger Vehicles
           Equipped with "Fumcell"
                 April 1971
               Henry L. Gompf
   Division of Emission Control Technology
   Mobile Source Pollution Control Program
        Air Pollution Control Office
       ENVIRONMENTAL PROTECTION AGENCY

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Device Tested



As part of a continuing evaluation of available vehicular



emission control devices, the Test and Evaluation Branch



initiated a test program to determine the emission reduction



potential of the "Fumcell".  Fumceli is a product of Energy



Sciences Incorporated of El Segundo, California.  The "Fumcell"



is a small device, tubular in shape, which is installed in



the PCV line according to the manufacturer's instructions.



The standard PCV valve is left in place.





Vehicles Utilized



Two cars from the EPA fleet were used to evaluate "Fumcell's"



effectiveness.  The device was installed in the PCV line of



a 1970 Chevrolet Impala and a 1970 Plymouth Valiant.  The



Impala is equipped with an automatic transmission and a



350 cubic inch displacement, high compression, eight cylinder



engine.  The Valiant is equipped-with an automatic transmission



and a 225 cubic inch displacement, six cylinder engine.



Indolene 30 was used for testing of the Impala while Indolene



Clear was utilized for the Valiant.  Extensive baseline



emission data were available on each of these passenger cars.





Emission Test Procedure



The following emission tests were performed (all tests were



cold start):



    Impala



      8 Baseline 1972 Federal Test Procedure  (FTP)



      3 Fumcell-equipped 1972 FTP

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                          - 2 -




    Valiant



      1 Baseline 1968 FTP with Constant Volume Sampling  (CVS)



      1 Fumcell-equipped 1968 FTP with CVS



      6 Baseline 1972 FTP



      4 Fumcell-equipped 1972 FTP






The 1968 FTP was performed in accordance with the June 4,



1968, Federal Register, Volume 33, Number 108.  The 1972 FTP



was performed in accordance with the November 10, 1970, Federal



Register, Volume 35, Number 219.  Closed cycle data in each



case were taken utilizing the constant volume sampling technique,




Bag samples were analyzed using non-dispersive infrared



analysis for carbon monoxide and carbon dioxide.  Hydrocarbons



were measured using a flame ionization detector.  Oxides of



-nitrogen were determined utilizing the Saltzman analysis--a



wet chemical technique.  Non-dispersive infrared analysis



was utilized for open cycle, continuous analysis of hydro-



carbon, carbon monoxide, carbon dioxide, and nitric oxide



in the 1968 FTP.






Additional Tests Conducted



In addition to the emission tests described in the previous



section, two other tests were employed to further evaluate



the "Fumcell".






Fuel consumption was measured during each emission test.



The test fuel tank was weighed prior to and immediately



following each emission test.

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                          - 3 -



Because the "Fumcell" depends on altering the characteristics



of the PCV system for its effectiveness, flow versus vacuum



tests were conducted.  These tests spanned two ranges to



measure the effect on PCV flow at both high and low vacuum.



Testing was performed on a standard flow bench.  Low vacuum



utilized water as a pressure measuring fluid while it was



required to use mercury for high vacuum measurements.






Emission Results



Complete emission data for the 1970 Valiant are presented



in Table 1 of this report.  Utilizing the open cycle 1968



FTP, the employment of Fumcell resulted in measured



reduction of 28 percent in hydrocarbons and 63 percent in



carbon monoxide.  Nitric oxide emissions appeared to increase



by 3 percent.  Closed cycle or CVS data obtained simultaneously



by repeating the 7-mode cycle nine times while taking a bag



sample, indicated actual mass emission reductions of 45 percent



in hydrocarbons, 53 percent in carbon monoxide, and 24 percent



in oxides of nitrogen.  Similarly, utilizing the 1972 FTP,



mass emissions from the Valiant were reduced by 28 percent



in hydrocarbons, 48 percent in carbon monoxide, and 10 percent



in oxides of nitrogen.






Emission data for the 1970 Impala are also presented in



Table 1 of this report.  Use of the 1972 FTP revealed that



hydrocarbon emissions were reduced by 22 percent, carbon



monoxide by 48 percent.  A 4 percent increase in oxides of



nitrogen were shown.

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                          _ 4 -




Fuel Consumption Results



Fuel consumption data for both the Impala and the Valiant



are presented in Table 2.  The Valiant equipped with



Fumcell showed an 8 percent reduction in fuel consumption



during the 1968 FTP evaluations and 9 percent during the



1972 FTP.  On the other hand, the Impala used 7 percent more



fuel during 1972 FTP tests when equipped with Fumcell.






PCV Flow Test Results



The effect of the "Fumcell" on flow through a PCV system is



indicated on Figures 1 and 2 of this report.  Figure 1  depicts



flow under low vacuum conditions from 0-30 inches of water



vacuum.  Although flow initially begins at about 6 inches



of water both with and without the Fumcell in place, from



6 inches to 30 inches of water the flow through the system



equipped with Fumcell is restricted up to about 40 percent



of normal flow.






Under high vacuum conditions use of the Fumcell results in



the bleeding in of additional air.  As Figure 2 indicates



from 12 inches of mercury to higher vacuums flow through the



PCV system tested remained constant.  Without Fumcell this



flow was about 2 cubic feet per minute (cfm).  With Fumcell



the flow increased to 4.5 cfm, an increase of 125 percent



under idle type conditions.

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                          - 5 -



Conclusions



1.  Hydrocarbon and carbon monoxide emissions from both the



    Impala and Valiant were substantially reduced by the



    installation of the Fumcell.  This reduction was caused



    by the high vacuum leaning effect of the Fumcell.  It



    is felt that while both cars tested were running rich



    enough to tolerate this leaning effect the same effect



    could be accomplished by adjusting the carburetion on



    both cars.  A leaner running vehicle would probably



    develop adverse driveability affects with installation



    of the Fumcell.  The restriction of PCV flow at low



    vacuum (acceleration conditions) has little effect



    because the PCV flow is a much smaller proportion of



    total flow into the intake manifold.  Oxides of nitrogen



    did not react consistently to the installation of Fumcell,



    Increasing NOX emissions from the Impala indicate the



    potential result of the leaning effect.  The decrease



    in NOx emitted by the Valiant appears questionable as



    the last two baseline tests reported are both lower than



    the average Fumcell equipped NOx emissions during the



    1972 FTP.  It is felt therefore that Fumcell has little



    direct effect on NOX emissions.





2.  Fuel consumption effects ranged from a 9 percent savings



    on the Valiant to a 7 percent penalty on the Impala.  No



    conclusion as to Fumcell*s effect on fuel consumption



    can be made.

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                          - 6 -




3.   While Fumcell seems to be an effective device for leaning



    vehicular operation, it is doubtful that it is universally



    applicable to a population of vehicles with operating



    conditions ranging from very rich to very lean.

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                             Table 1



                          Emission Data






                      1970 Valiant 225 CID



  1968 FTP - 7-mode,  open cycle
Baseline
Trip Composite
Fumcell
Trip Composite
% Reduction
9 cycle - 7-mode,
Baseline
Fumcell
% Reduction
1972 FTP, LA 4-S4
Baseline
Before
Fumcell
After
Fumcell
Average Baseline
Fumcell
Average Fumcell
% Reduction

HC ppm
162.1
116.0
28%
closed cycle
HC gpm CO gpm
3.20 43.89
1.77 20.54
45% 53%
, closed cycle
HC gpm CO gpm
3.73 67.59
2.53 42.65
2.51 29.80 '
2.79 53.73
2.57 43.63
2.53 50.69
2.78
2.16
1.66
2.18
1.98
2.00
28%
gpm 48.02 gpm
27.77
26.71
19.99
27.12
gpm 25.40 gpm
48%
CO %
1.29
0.48
63%
CO 2 gpm
398.42
388.33
3%
CO2 gpm
447.39
282.41
439.79
542.93
425.62
417.88
426.00
478.11
443.99
437.29
442.69
*NO ppm
1951.1
2011.3
3% increase
Saltzman
*N02 gpm
7.44
5.65
24%
Saltzman
*N02 gpm
6.40
7.17
6.48
7.10
4.89
5.57
gpm 6.27 gpm
5.34
5.83
5.82
5.49
450.52 gpm 5.62 gpm
6% increase 10%
* corrected for temperature and humidity

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                        Table 1 (cont'd)

                     Emission Data (cont'd)
1972 FTP

Baseline
 Before
 Fumcell
 After
 Fumcell
            1970 Impala 350 CID

LA 4-S4, closed cycle
HC gpm
4.65
4.36
4.36
4.29
4.47
6.27
5.96
4.24
CO gpm
49.68
45.01
44.10
45.35
47.01
53.77
58.80
45.00
Average Baseline    4.83 gpm
                      48.60 gpm
             CO2 gpm
              610.9
              611.7
              561.3
              544.7
              605.9
              566.3
              495.5
              610.1

              575.8 gpm
            Saltzman
           *N02 gpm
              4.9
              5.3
              5.8
              4.9
              5.9
              5.0
              4.6
              5.3

              5.2 gpm
Fumcell
Average Fumcell
         3.21
         4.11
         4.05

         3.79 gpm
25.43
23.41
26.94

25.26 gpm
567.7
590.3
628.8

595.6 gpm
5.9
4.8
5.4

5.4 gpm
% Reduction
         22%
 48%
3% increase   4% increase

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                Table 2

         Fuel Consumption Data


         1970 Valiant 225 CID

9 Cycle - 7-mode

Baseline                     1.250 kg,

Fumcell                      1.150 kg,

% Savings in fuel consumption      8%


1972 FTP - LA 4-S4

Baseline                     1.455 kg.
                             1.2.10
                             1.480
                             1.280
                             1.207

                   Average   1.326 kg,


Fumcell                      1.230 kg,
                             1.178
                             1.200
                             1.195

                   Average   1.201 kg,

% Savings in fuel consumption      9%

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           Table 2 (cont'd)

    Fuel Consumption Data  (cont'd)


          1970 Impala 350 CID

1972 FTP - LA 4-S4

Baseline                     1.63 kg,
                             1.59
                             1.64
                             1.59
                             1.82
                             1.71
                             1.84

                   Average   1.69 kg.


Fumcell                      2.02 kg.
                             1.79
                             1.62

                   Average   1.81 kg,


% Penalty in fuel consumption     7%

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BEE 20x20 TO INCH

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