EVALUATION OF A GM 1976 PROTOTYPE
     VEHICLE - A CATALYTIC EXHAUST
            MANIFOLD SYSTEM
               June 1972
           Henry L. Gompf
     Test and Evaluation Branch
Environmental Protection Agency

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 Background

     As part  of  the Office  of Air Programs continuing  effort  to
 keep abreast  of  potential 1975-76 control technology,  a  test
 sequence was  conducted  on a General Motors prototype utilizing
•a  catalytic exhaust manifold system concept.  Data compiled at
 General Motors Corporation  on the test 'vehicle  indicated low
 mileage average  emission data as follows:
                                       i
                 Hydrocarbon .25 grams per mile
                 Carbon Monoxide 2.4 grams per mile
                 Oxides of  Nitrogen .34 grams per mile

 Due to the consistent success displayed by' 'this system in
 meeting the required 1976 emission level in the General  Motors
 laboratory, an evaluation program was initiated by EPA.  At
 the time of the  evaluation  in the Ann Arbor laboratory,  GM
 had not yet subjected this  candidate system to durability
 evaluation.

 System Description

     The prototype system under evaluation was supplied  to EPA
 installed on  a 1972 Chevrolet Belair equipped with an  automatic
 transmission  and a 350  cubic inch displacement California engine
 Beyond necessary engine modifications, the vehicle was equipped
 with four major  emission controls.
     1.  A uuick heat intake manifold ,&&£, was incorporated to
     assist  in cold start fuel evaporation.  Exhaust from both
     exhaust manifolds was piped transversely through a single
     plane hot plate in the intake manifold resulting in dual
     cross flow for warm-up.

     2.  A Grace noble metal catalyst was employed for oxidation
     of hydrocarbon and carbon monoxide.  The catalyst had a
     monolith structure.

     3.  A Gulf noble metal catalyst was employed for reduction
     of oxides of nitrogen.  This catalyst had a .monolith .structure


     4.  An  air pump and associated valving was used to supply
     air for exhaust port oxidation and oxidizing air to the
     Grace catalyst bed.

     The sequence of operation during EPA's evaluation was
 largely manual.  For cold start purposes the choke was manually
 released within three seconds of vehicle start-up.  Initially

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air injection was directed manually to the exhaust ports during
catalyst bed warm-up.  After reaching necessary catalyst temp-
erature (approximately 60 seconds) the major portion of the air
injection was manually diverted to the oxidizing catalyst for
the duration of the testing cycle.  Simultaneously the exhaust
to the EFE manifold was shut-off.  The manual controls utilized
could feasibly be replaced with temperature actuated valves after
further optimization studies.

     Both catalyst beds were neatly packaged together at the
rear of each exhaust manifold.  Special note should be made of
the fact that this system does not employ any exhaust gas
recirculation for the control of oxides of nitrogen other than
that obtained from valve overlap with the 1972 California
camshaft.

     A schematic view of the overall engine system is presented
in Figure 1  of this report.  Figure 2 schematically shows
typical valving and a cross section of the catalyst beds. (Note
that this figure shows pellatized beds whereas the one tested
was monolithic in structure) .

Test Procedure

     The GM prototype system was tested three times from a cold
start using the 1975 Federal emission test procedure.  Full
details of this procedure are found in the July 2, 1971, Federal
T3^rr-ic?-f1'£iT»  ir/"\1iTm£a "Z. f\  Mi iTr»V\^»-v- TOO  T5oT»4- TT
     All three tests were conducted using the General Motors
recommended dynamometer inertia loading of 5000 pounds.  Test
fuel was Indolene Clear (an available lead free standard fuel) .

     In addition, one hot start 1972 split-bag procedure was
conducted at an inertia weight of 4000 pounds to indicate,
if possible, major effects of vehicle size on emissions with
this type of system.

Emission Test Results

     Table 1 shows the results of the three individual cold
start tests.  As can be seen the hydrocarbon and carbon monoxide
levels were lower than those" reported by GM in their previous
testing.  The oxides of nitrogen levels measured in the EPA
evaluation were higher than GM's figures.  In the General Motor's
testing the vehicle consistently met 1976 required levels, while
the EPA testing showed that the oxides of nitrogen exceeded
allowable levels.  The vehicle did consistently meet maximum
allowable emission levels for 1975 vehicles.

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     Table 2 compares the hot start 1972 procedure emissions
of the 5000 pound test weight with the 4000 pound results.
Significant in this table is the 12% reduction in oxides of
nitrogen at the 4000 pound weight.

     Fuel consumption during the three cold start tests was
analytically calculated.  An average fuel consumption of 9.9
miles per gallon was reported during EPA tests compared to 9.4
miles per gallon reported by GM.

     While no quantitative analysis of the vehicle driveability
was made,  a report from the test driver and that from another
EPA evaluator both reported excellent driveability.

Conclusions

     Based on discussions with General Motors engineers differ-
ences between EPA emission results and those previously reported
by GM were probably due to an interceding vehicle tear-down and
build-up immediately prior to delivery to the EPA laboratory.

     While the prototype vehicle tested showed excellent potential
of meeting Federal required levels for 1975-76 a vehicle with
minimal deterioration of driveability and fuel economy, it is
impossible to assess the full potential of the system without the
input of durability mileage data.  It appears, however, that this
prototype system is an excellent candidate for extended mileage
   lu?. t ion ;
     Due to the characteristics of catalytic-based systems
parallel analyses for ammonia, aldehyde and particulate content
of the exhaust are desirable to assure 'overall compliance with
light duty motor vehicle goals.

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                            Table 1

                   1975 FTP Emission Results
       (All results in grams per mile at 5000 pounds)
   Date        HC            CO              C02          NOx
                    High Range/Low Range
*6-5-72
6-6-72
6-7-72
0.26
0.21
0.16
1.4
1.8
1.1
1.6
1.8
	
891.8
891.8
895.7
0.47
0.45
0.49
   EPA Average
               0.21      1.4       1.7       893.1        0.47

 **GM Average
               0.25      ---       2.4       ---          0.34

***GM Average
               0.20      ---       1.1       835.9        0.44
  *Note:   After the test on 6-5-72 an orifice change controlling
          secondary air was performed.   No obviously apparent
          effect «resuired.

 **GM data collected prior  to engine tear-down, rebuild, and
   subsequent delivery to EPA.

***GM data collected in one test immediately prior to delivery
   to EPA and immediately following the return of the vehicle
   to GM.

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                          Table 2

            Hot  Start  1972 FTP Emission Results
              (All  results in grams per mile)
 Test
 Inertia Weight    Date     HC_       CO          C0_2    NOx

 5000  #            6-5-72   0.11      0.5         869.6  0.31

 5000  #            6-6-72   0.13      1.'3         874.4  0.34

 5000  #           :6-7-72   0.09      0.5         877.1  0.35

 Average at
 5000  #                    0.11      0.8         873.7  0.33

 4000--#            6-7-72   0.18      0.6         800.9  0.29

 % Change  from
 5000  #                    641*      25%**       8%**   12%**
 *  increase
•*  decrease

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                                                                                                    *
AIR PUMP
         AIR CONTROL
            VALVE
IMPROVED CARBIIRETIOM
      AKD CHOKE
                                                     QUICK KEAT MAJHFOLD
                                                      DUAL CROSS FLOW'
                                                        FOR WARM-UP
                                                                      REACTOR CONTROL
                                                                      WARM-UP CONTROL    '
                                                               p?
                                                               t'.

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                                   PORT AIR
 (COORDINATED
VALVES SHOWN IN
                       MOx
                     REDUCING
                     IN CENTEJ
                      SECTION
    EXHAUST GAS FROM
    QUICK HEAT MANIFOLD
                                       CATALYTIC EXHAUST MANIFOL
HC/CO OXIDIZING
IN PERIPHERAL SECTION
                          CONVERTER AIR

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