EPA-AA-TEB-80-12
    Evaluation of XRG #1  a Fuel  Additive


                   by

            Edward Anthony Earth


              February 1980
       Test and Evaluation Branch
    Emission Control Technology Division
Office of Mobile Source Air Pollution Control
       Environmental Protection Agency

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Background

The  Environmental  Protection Agency  receives  information about  many  systems
which  appear  to offer  potential  for emission  reduction or  fuel  economy im-
provement  compared  to   conventional  engines  and  vehicles.   EPA's  Emission
Control  Technology  Division is  interested in evaluating  all  such  systems
because  of  the  obvious benefits  to the Nation  from the  identification  of
systems that can reduce emissions, improve fuel economy, or both.   EPA invites
developers of  such  systems  to provide complete technical data on the system's
principle of operation,  together  with available test  data on the system.  In
those  cases  for which  review by EPA technical staff  suggests that  the data
available shows  promise, attempts  are made to schedule tests at  the EPA Motor
Vehicle Emission Laboratory  at  Ann Arbor, Michigan.   The  results  of  all such
test  projects  are set  forth in a  series of Test and Evaluation Reports,  of
which this report is one.

In  February  of  1978 the  EPA tested NRG #1,   a  fuel additive developed and
marketed by NRG International, Inc. of Clayville, New York.  Contrary to NRG's
claims, the test  results showed,  "neither a general  increase in fuel economy
nor  a decrease in  emissions associated  with  the addition  of NRG //I  to the
fuel."  (1)(Evaluation of NRG #1, A Fuel Additive, TAEB Report 77-19, February
1978).*

In response to a request from the  Federal  Trade Commission for more in-depth
information on NRG  //I  (now referred to  as "XRG #1")  (2) this new series  of
tests was performed.

The conclusions drawn from the EPA evaluation tests are necessarily of limited
applicability.   A complete  evaluation of  the  effectiveness of  an  emission
control  system  in  achieving performance  improvements on the many different
types of vehicles that are in actual use requires a much larger sample of test
vehicles  than  is economically  feasible in the  evaluation  test  projects con-
ducted by EPA.  For  promising systems it is necessary  that more extensive test
programs be carried  out.

The  conclusions  from the EPA evaluation  test  can be  considered  to be quanti-
tively valid  only  for the specific test  cars  used;  however, it is reasonable
to extrapolate the  results  from the  EPA  test  to other types of vehicles in a
directional manner,  i.e.,   to  suggest that similar  results  are  likely to  be
achieved on other types of vehicles.

Summary of Findings

There  was  no  significant change in emissions  or fuel economy through the use
of XRG #1 for  the group of vehicles tested.

For  individual vehicles,  the Citation showed a 2% fuel economy improvement on
the  FTP and 4% fuel  economy  improvement on the HFET.   There was no significant
increase  or  decrease in fuel economy for the Dart and Fairmont for either the
FTP  or HFET.

*  Numbers in  parenthesis  designate  references  at  the  end  of  this  report.

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Description

XRG //I  is  a fuel additive developed and  marketed  by XRG International, Inc.,
(formerly NRG International) of Clayville, New York.

XRG //I is recommended by the manufacturer for use "with all grades of gasoline
and diesel  fuel used  in  internal combustion engines."  It  is  mixed directly
with  fuel  in the vehicle's tank  in  a  ratio of 1:1600  (0.08  fl.  oz. additive
per gallon fuel).  The following benefits are claimed by the manufacturer when
the additive is used in an automotive gasoline engine (3):

     - Increased fuel economy of 10-25%.
     - Decreased exhaust emissions.
     - Increased engine power.
     - Decreased starting time in cold weather.
     - Decreased dieseling tendency.
     - Decreased carbon buildup inside engine.

The manufacturer  claims these  benefits occur over  a period of  time  of con-
tinued  usage.   That is, there  are some immediate benefits  from  usage of the
fuel  additive  but full benefits  are obtained only  after  several tankfuls of
the XRG #1 additive doped fuel.  In addition, to retain these benefits, XRG #1
usage must be continued.

Test Vehicle Description

The three test vehicles used in this study were:

     A  1980 Chevrolet Citation  equipped  with a  2.8 litre V-6 engine and an
     automatic  transmission.   This vehicle  used  EGR, an  oxidation catalyst,
     and pulsating air injection for emission control.

     A 1975 Dodge Dart equipped with a 225 cubic inch inline 6-cylinder engine
     and an automatic  transmission.   This vehicle was calibrated to meet the
     1975 California  emission  standards.   This vehicle used an air pump, EGR,
     and an oxidation catalyst for emission control.

     A  1979 Ford Fairmont  equipped with  a  140  cubic  inch  inline 4-cylinder
     engine  and  automatic  transmission.  This vehicle used an oxidation cata-
     lyst for emission control.

     A  complete description of  these  vehicles is  given in  the  test vehicle
     description in Appendix A.

Test Procedure

Exhaust  emission tests  were  conducted according  to the  1977  Federal  Test
Procedure  (FTP)  described  in  the Federal Register  of June  28,  1977,  and the
EPA Highway Fuel Economy  Test (HFET), described  in the  Federal Register of
September 10,  1976.   The  vehicles were not  tested  for  evaporative emissions.

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Prior  to  baseline testing,  each vehicle was given a  specification  check and
inspection.  The ignition timing, idle speed, and fast idle speed were checked
for  agreement  with  the manufacturer's  specifications  given on  the Vehicle
Emission  Control  Information label  affixed  to  the engine compartment.   Each
vehicle met  its  manufacturer's  specifications  and therefore no  adjustments
were required.

The  vehicles  were  inspected for engine vacuum leaks,  proper  connection  of
vacuum hoses, functioning  PCV valve, oil and water levels, and general condi-
tion of engine  compartment.   Each vehicle was in  satisfactory condition when
initially inspected.

Because the manufacturer's  claims for XRG #1 additive included both immediate
and  long  term benefits (3) the test program included testing both immediately
after initial additive usage and after-mileage accumulation with the additive.
Each vehicle was tested in three different conditions:

     1.   Baseline - as received.
     2.   With XRG #1  (vehicle fuel tank drained, refueled with additive doped
          fuel and prepped before this test).
     3.   After 500 miles with XRG #1.

At  each  test  condition duplicate  FTP  and  HFET  tests  were  conducted.   The
accumulation of 500  miles  using fuel with XRG //I consisted of sequences of 10
HFET driving  cycles and one LA-4  (the  basic FTP  cycle)  driving  cycle.   The
relatively high  average speed  of the HFET  (48  mph) was  expected  to minimize
the  amount of  time to achieve those additive benefits that are based on vehi-
cle  mileage  accumulation.   Mileage  accumulation was  accomplished on a dyna-
mometer.

In  addition,  one  vehicle,  that was  used   in  later   test  programs,  received
baseline  tests after the 500 mile XRG #1 tests.

All  testing was  performed  using  the  same gasoline  batch.   Two barrels of the
gasoline  batch  were doped  with the  XRG #1  at  the manufacturer's prescribed
doseage of 1600 parts  gasoline to one part XRG //I.  This XRG #1 doped gasoline
was used  for all XRG #1 tests and mileage accumulation.

Discussion of Results

General Data Analysis

The  objective of this  test program was to determine if there was a significant
beneficial change  in vehicle emissions, fuel  economy, or performance through
the  use of the fuel additive XRG  #1.

The  results  of these  tests are  summarized  in  Tables I and  II.   Results of
individual tests  are given in Tables V  through  X in Appendix B.  The results
of  the statistical  analysis  and actual  changes  between configurations are
shown  in  Tables III and IV.

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                                         5

                                      Table I

                           Average Vehicle FTP Emissions
                                  grams per mile
Test Condition
Baseline
XRG //I
XRG //I @ 500 miles
Baseline
XRG #1
XRG #1 @ 500 miles
Baseline
XRG #1
XRG #1 @ 500 miles
HC
CO
CO,
NOx
MPG
                        Chevrolet Citation - FTP
.35
.32
.33
1.93
2.03
1.86
450
449
440
1.55
1.62
1.61
19.5
19.6
20.0
                            Dodge Dart - FTP
.63
.65
.48
7.90
8.64
6.93
568
583
563
1.81
1.72
1.85
15.3
14.8
15.4
                           Ford Fairmont - FTP
.76
.71
.74
8.40
8.57
7.74
400
402
404
1.83
1.83
1.85
21.3
21.2
21.2
                                      Table II

                           Average Vehicle HFET Emissions
                                  grams per mile
Test Condition
Baseline
XRG //I
XRG #1 <§ 500 miles
Baseline
XRG #1
XRG #1 @ 500 miles
Baseline
XRG  #1
XRG  //I  @  500 miles
HC
CO
CO,
NOx
MPG
                        Chevrolet Citation - HFET
.07
.06
.07

.05
.04
.04

.15
.14
.14
.02
.00
.00
Dodge Dart -
.15
.11
.10
Ford Fairmont
.63
.68
.58
313
310
300
HFET
368
374
364
- HFET
317
320
313
                              2.58
                              2.17
                              2.41
                               2.48
                               2.52
                               2.35
                              24.1
                              23.7
                              24.4
                              27.9
                              27.6
                              28.2

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                                    Table III
                   FTP Change From Baseline Due to XRG #1 Fuel
               Expressed in % at Minimum Stated Confidence Level*
Test Condition            HC

Chevrolet Citation - FTP
XRG #1 at 500 miles      -6%***

Dodge Dart - FTP
XRG #1 at 500 miles     -24%***

Ford Fairmont - FTP
XRG #1 at 500 miles      -3%***

Combined Effect - All Vehicles
XRG 31 at 500 miles        ***
               C0_


              -4%***


             -12%***


             -8% 94% C.L.


               ***
               NOx


             4% 93% C.L.


             2%***


             1%***


              ***
                 MPG


               2% 99% C.L.


               1%***


               0%


               ***
                                    Table IV

                  HFET Change From Baseline Due to XRG //I Fuel
               Expressed in % Change at Minimum Confidence Level*
Test Condition
HC
Chevrolet Citation - HFET
XRG //I at 500 miles

Dodge Dart - HFET
XRG #1 at 500 miles
Ford Fairmont - HFET
XRG #1 at 500 miles       	

Combined Effect - All Vehicles
XRG #1 at 500 miles
CO
NOx
                           14% 99% C.L.
MPG
                            5% 99% C.L.
-7%***
-5%***
1%***
1%***
                               ***
                                               ***
* Confidence level from statistical "t" test procedure and direction of change.

C.L. - Confidence Level

**+ indicates increase; - indicate decrease.

*** indicates change not significant at 90% confidence level.  That there is no
significant change.

Note:  The confidence  level should not be confused with changes of absolute values
but are an indication  of the statistical significance of the changes in the values
given in Tables I and  II.

Note:  The confidence  level was not calculated for the initial XRG #1 tests.

Note:  Percent change  not calculated for HC and CO emissions for HFET.  See text.

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From an  initial  review of the data given  in Tables III and IV, it may appear
that use of XRG #1  did  cause some small changes in  individual vehicle emis-
sions or fuel economy.   However,  in order  to determine  whether the apparent
differences were statistically significant, a significance test, such as a "t"
test must  be performed.   This technique analyzes  the difference  due to the
subject  variable in  relation to test to test  variability to determine if the
difference  is  real  or  is due  to  testing  variability.   The resultant signi-
ficance  determinations are  stated  in terms  of the  minimum percent confidence
level that can be ascribed to the observed difference.

The "t"  test  technique allows the determination of the effect of one variable
(use of  XRG #1  additive) on a vehicle.  The "t" test is also able to indicate
how representative the effect of the variable is for a group of vehicles.  The
resultant levels of  significance are stated in  terms  of  percents.  This con-
fidence  level indicates  the probability of assigning differences to the vari-
able (use of XRG #1 additive) being analyzed.  With a test program of the size
performed,  changes  with  confidence  levels  below  90%  are not  significant.

EFFECT OF XRG #1

Federal Test Procedure

The  use  of  XRG //I  did  not  significantly  affect  the  HC  emissions  for the
Citation, Dart or Fairmont.

The use  of  XRG  #1  caused mixed  effects  on CO emissions.  There was no signi-
ficant change in the Citation's or Dart's CO emissions.  The Fairmont's emis-
sions decreased 8% (at the 94% confidence level).

The use  of  XRG  //I  caused mixed effects  on  NOx emissions.  The Citation's NOx
emissions increased  4% at the 93% confidence  level.   XRG #1 did not signifi-
cantly affect the NOx emissions on the Dart or Fairmont.

The use  of XRG //I did not significantly affect the fuel economy of the Dart or
Fairmont.   (The  Citation's  fuel  economy showed a  slight improvement, 2% (at
99% confidence level).

When the FTP  results were analyzed to  determine the  effects of XRG #1 on the
group of vehicles,  the analysis showed that the use of XRG //I did not signifi-
cantly affect either HC, CO and NOx emissions or fuel economy.

Highway  Fuel Economy Test

The  HC  and CO emissions  for all three vehicles were quite  low both with and
without  use of the  additive.  HC and  CO emissions are  usually very low for
most vehicles on  the HFET.  Thus, even  a  very small change such as .01 grams
per  mile could appear as  a 5% to 30% relative  change.   Therefore,  since the
results  were  low  and  similar, there was  no  significant  change in  HC  or CO
emissions caused by  the use  of XRG #1.

The use  of  XRG  //I  caused mixed  results  on NOx emissions.   The Citation's NOx
emissions   increased   14%  at  the  99%  confidence  level.   The  Dart's  and
Fairmont's NOx emissions were  not significantly affected.

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The use of XRG #1 did not significantly affect the fuel economy of the Dart or
Fairmont.  The Citation's  fuel  economy showed a slight improvement, 4% at the
99% confidence level.

The analysis  of  the  HFET  results  to  determine the effects of XRG  #1  on the
group of  vehicles  showed that the use  of  XRG #1 did not significantly affect
either HC, CO and NOx emissions or fuel economy.

Discussion of Additive Components and Their Effects

According to  the manufacturer,  XRG #1 is composed mostly of isopropol alcohol
and  toluene.   It  also  contains  a  small  amount  of ferrous  sulphate,  nitro
benzene and water (4).  An exact chemical breakdown was not given.

Toluene is a  normal component of gasoline.   Unleaded  gasoline is reported to
presently contain  10  to 15% toluene and leaded gasoline 5 to 10% toluene (5).
Premium leaded fuel is 6% toluene.  Individual gasoline fuel samples have had
up to 45% toluene.

Conclusions

Although  a few  individual  tests indicated slight improvements in emissions or
fuel economy through the use of XRG //I, several tests indicated small emission
or fuel  economy  penalties.   A significant but small improvement in fuel econ-
omy was  noted on one vehicle for the FTP and HFET.  However, for the group of
vehicles,  XRG//1  showed  no  significant effect  on vehicle  emissions  or fuel
economy.

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                               References

1.   Evaluation  of  NRG  #1,  a  Fuel Additive.   TAEB Technical Report  77-19,
     February 1978.

2.   Telephone conversation  between Mr.  F.  Peter Hutchins,  Project  Manager,
     EPA and Mr.  Brian Boshart, engineer, XRG International Inc.,  on August 8,
     1979.

3.   NRG Fuel Additive, product information brochure (Note XRG = NRG).

4.   Letter dated  September  16,  1977  from Mr. Brian  F.  Boshart,  NRG  Inter-
     national  to Mr.  Craig  Harvey,  EPA.  Subject,  NRG contents  and  previous
     test program schedule.

5.   Telephone conversation between Mr. F. Peter Hutchins, EPA and Mr. William
     Meyer, Gulf Research and Development,  on September 4,  1979.   Subject,
     toluene in gasolines.

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                                     10
                                    Appendix A

                             TEST VEHICLE DESCRIPTION


                 Chassis model year/make - 1980 Chevrolet Citation

                            Vehicle ID - 1X117AW150868

Engine

type	V-6, 4-Cycle
bore x stroke	89 x 76 mm/3.50 x 2.99 in.
displacement 	 2800 cc/170.9 CID
compression ratio  	 8.5 to 1
maximum power at rpm	115 hp/85.8 kW
fuel metering  	 2 Venturi Carburetor
fuel requirement 	 unleaded, tested with Indolene
                                           HO unleaded

Drive Train

transmission type  	 3-speed automatic
final drive ratio	2.53

Chassis

type	4 door sedan
tire size	P185/80R13
curb weight	2905 lb/1318 kg.
inertia weight	3000 Ib.
passenger capacity 	 5

Emission Control System

basic type 	 Oxidation catalyst
                                         EGR
                                         Pulsating air injection
Vehicle Odometer Mileage
                                         6730 miles at start of test
                                           program
                                         7480 miles at end of test
                                           program

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                                      11
                        TEST VEHICLE DESCRIPTION

                Chassis model year/make - 1975 Dodge Dart
            Emission control system - Air Pump, Catalyst EGR
                      Vehicle I.D. - LH41C5B290359
Engine
type	 Inline 6, 4-cycle
bore x stroke	3.40 X 4.125 in.
displacement	 . 225 CID/3687 cc
compression- ratio	8.4:1
fuel metering  	 1 Venturi, carburetor
fuel requirement 	v 	 unleaded, tested with Indolene
                                           HO unleaded

Drive Train

transmission type  .  .  .   .,	3-speed automatic
final drive ratio	2.75

Chassis

type . .  .	4 door sedan
tire size	 D78 X 14
inertia weight	3500 Ib.
passenger capacity 	 6

Emission Control System

basic type	 air pump
                                         oxidation catalyst
                                         EGR
                                         calibrated to 1975
                                            California standards
Vehicle Odometer Mileage
                                         20635 miles at start of test
                                            program
                                         21950 miles at end of test
                                            program

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                                    12
                             TEST VEHICLE DESCRIPTION

                   Chassis model year/make - 1979 Ford Fairmont
                            Vehicle I.D.  9X92Y175689
Engine
type	Inline 4,  4-cycle
bore x stroke	3.80 X 3.10 in./96.5 X 78.7  mm.
displacement 	  140 CID/2.3 1
compression ratio  	  9.0:1
maximum power  	  92 hp/68.6 k W
fuel metering  	  2 Venturi, carburetor
fuel requirement 	  unleaded,  tested with Indolene
                                           HO unleaded

Drive Train

transmission type  	  3-speed automatic
final drive ratio	3.08

Chassis

type	4 door sedan
tire size	BR 78 X 14
curb weight	2800 lb/1270 kg
inertia weight	3000 Ib.
passenger capacity 	.5

Emission Control System

basic type 	  oxidation catalyst

Vehicle Odometer Mileage

                                         10890 miles at start of test
                                            program
                                         11525 miles at end of test
                                            program

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                                           13

                                      Table V
Test Condition

Baseline
Baseline
Baseline
Baseline

XRG (14 miles)
XRG (55 miles)

XRG (524 miles)
XRG (552 miles)
XRG (591 miles)
                         Chevrolet Citation FTP Emissions
                                  grams per mile
Test #
EC
CO
CO,
NOx
MPG
79-9919
79-9921
79-9923
79-9925
79-9927
79-9929
79-9931
79-9978
79-9980
.39
.32
.33
.34
.32
.31
.35
.32
.32
2.29
1.66
1.73
2.03
2.23
1.83
1.87
1.91
1.80
452
450
450
449
450
447
441
440
439
1.54
1.56
1.56
1.52
1.60
1.63
1.57
1.65
1.62
19.4
19.5
19.5
19.6
19.5
19.7
19.9
20.0
20.0
                                    Table VI
Test Condition

Baseline
Baseline
Baseline (769 miles)
Baseline (1192 miles)

XRG (8 miles)
XRG (42 miles)

XRG (521 miles)
XRG (554 miles)
XRG (595 miles)
                            Dodge Dart FTP Emissions
                                 grams per mile
Test #
HC
CO
CO,
NOx
MPG
79-9778
79-9781
80-0246
80-0735
79-9782
79-9784
79-9786
79-9788
79-9986
.83
.79
.38
.50
.46
.84
.49
.47
.47
9.94
8.58
6.06
7.00
7.00
10.27
6.68
7.12
6.99
579
591
547
553
583
583
566
562
561
1.60
1.52
1.99
2.11
1.72
1.71
1.89
1.78
1.87
14.9
14.6
15.9
15.7
14.9
14.7
15.3
15.4
15.5
                                    Table VII
Test Condition

Baseline
Baseline

XRG  (5 miles)
XRG  (52 miles)

XRG  (509 miles)
XRG  (540 miles)
                           Ford Fairmont FTP Emissions
                                 grams  per mile
Test #

79-9909
79-9911

79-9913
79-9915

79-9917
79-9984
HC

.76
.76

.72
.70

.74
.74
CO

8.29
8.50

8.58
8.56

7.88
7.59
400
400

403
400

403
404
          NOx
1.83
1.82
  .83
  .83
1.91
1.79
MPG

21.3
21.3
21
21
21.2
21.2

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                                         14
                                    Table VIII
Test Condition

Baseline
Baseline
Baseline
Baseline

XRG(24 miles)
XRG (66 miles)

XRG (536 miles)
XRG (568 miles)
XRG (608 miles)
                        Chevrolet Citation HFET Emissions
                                  grams per mile
                     Test 9
HC
CO
CO,
NOx
MPG
79-9920
79-9922
79-9924
79-9926
79-9928
79-9930
79-9932
79-9979
79-9981
.07
.07
.07
.07
.06
.06
.07
.07
.07
.00
.05
.01
.01
.00
.00
.00
.00
.00
311
316
313
310
309
310
301
299
299
1.20
1.35
1.24
1.37
1.27
1.22
1.47
1.44
1.50
28.5
28.0
28.3
28.6
28.7
28.6
29.4
29.6
29.6
                                     Table IX
Test Condition

Baseline
Baseline
Baseline  (781 miles)
Baseline  (1228 miles)
XRG
XRG
(19 miles)
(53 miles)
XRG  (532 miles)
XRG  (565 miles)
XRG  (606 miles)
                             Dodge Dart HFET Emissions
                                  grams per mile
                     Test //
HC
CO
CO,
NOx
MPG
79-9779
79-9780
80-0316
80-0734
79-9783
79-9785
79-9787
79-9789
79-9987
.05
.05
.05
.06
.04
.04
.04
.05
.04
.09
.08
.19
.22
.12
.09
.06
.09
.14
379
374
356
362
376
372
364
365
364
2.02
2.01
2.79
3.48
2.07
2.27
2.40
2.34
2.48
23.4
23.7
24.9
24.5
23.6
23.8
24.4
24.3
24.4
Test Condition

Baseline
Baseline

XRG  (24 miles)
XRG  (63 miles)

XRG  (520  miles)
XRG  (551  miles)
                                      Table X

                           Ford Fairmont HFET Emissions
                                  grams per mile
                     Test #
HC
CO
CO,
NOx
MPG
79-9910
79-9912
79-9914
79-9916
79-9918
79-9985
.14
.15
.14
.14
.13
.14
.55
.70
.68
.67
.57
.59
316
317
320
319
312
314
2.50
2.45
2.44
2.61
2.31
2.39
28.0
27.8
27.6
27.7
28.3
28.1
 US. GOVERNMENT PRINTING OFFICE: 1980- 651-112/0222

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