EPA-AA-TEB-80-12 Evaluation of XRG #1 a Fuel Additive by Edward Anthony Earth February 1980 Test and Evaluation Branch Emission Control Technology Division Office of Mobile Source Air Pollution Control Environmental Protection Agency ------- Background The Environmental Protection Agency receives information about many systems which appear to offer potential for emission reduction or fuel economy im- provement compared to conventional engines and vehicles. EPA's Emission Control Technology Division is interested in evaluating all such systems because of the obvious benefits to the Nation from the identification of systems that can reduce emissions, improve fuel economy, or both. EPA invites developers of such systems to provide complete technical data on the system's principle of operation, together with available test data on the system. In those cases for which review by EPA technical staff suggests that the data available shows promise, attempts are made to schedule tests at the EPA Motor Vehicle Emission Laboratory at Ann Arbor, Michigan. The results of all such test projects are set forth in a series of Test and Evaluation Reports, of which this report is one. In February of 1978 the EPA tested NRG #1, a fuel additive developed and marketed by NRG International, Inc. of Clayville, New York. Contrary to NRG's claims, the test results showed, "neither a general increase in fuel economy nor a decrease in emissions associated with the addition of NRG //I to the fuel." (1)(Evaluation of NRG #1, A Fuel Additive, TAEB Report 77-19, February 1978).* In response to a request from the Federal Trade Commission for more in-depth information on NRG //I (now referred to as "XRG #1") (2) this new series of tests was performed. The conclusions drawn from the EPA evaluation tests are necessarily of limited applicability. A complete evaluation of the effectiveness of an emission control system in achieving performance improvements on the many different types of vehicles that are in actual use requires a much larger sample of test vehicles than is economically feasible in the evaluation test projects con- ducted by EPA. For promising systems it is necessary that more extensive test programs be carried out. The conclusions from the EPA evaluation test can be considered to be quanti- tively valid only for the specific test cars used; however, it is reasonable to extrapolate the results from the EPA test to other types of vehicles in a directional manner, i.e., to suggest that similar results are likely to be achieved on other types of vehicles. Summary of Findings There was no significant change in emissions or fuel economy through the use of XRG #1 for the group of vehicles tested. For individual vehicles, the Citation showed a 2% fuel economy improvement on the FTP and 4% fuel economy improvement on the HFET. There was no significant increase or decrease in fuel economy for the Dart and Fairmont for either the FTP or HFET. * Numbers in parenthesis designate references at the end of this report. ------- Description XRG //I is a fuel additive developed and marketed by XRG International, Inc., (formerly NRG International) of Clayville, New York. XRG //I is recommended by the manufacturer for use "with all grades of gasoline and diesel fuel used in internal combustion engines." It is mixed directly with fuel in the vehicle's tank in a ratio of 1:1600 (0.08 fl. oz. additive per gallon fuel). The following benefits are claimed by the manufacturer when the additive is used in an automotive gasoline engine (3): - Increased fuel economy of 10-25%. - Decreased exhaust emissions. - Increased engine power. - Decreased starting time in cold weather. - Decreased dieseling tendency. - Decreased carbon buildup inside engine. The manufacturer claims these benefits occur over a period of time of con- tinued usage. That is, there are some immediate benefits from usage of the fuel additive but full benefits are obtained only after several tankfuls of the XRG #1 additive doped fuel. In addition, to retain these benefits, XRG #1 usage must be continued. Test Vehicle Description The three test vehicles used in this study were: A 1980 Chevrolet Citation equipped with a 2.8 litre V-6 engine and an automatic transmission. This vehicle used EGR, an oxidation catalyst, and pulsating air injection for emission control. A 1975 Dodge Dart equipped with a 225 cubic inch inline 6-cylinder engine and an automatic transmission. This vehicle was calibrated to meet the 1975 California emission standards. This vehicle used an air pump, EGR, and an oxidation catalyst for emission control. A 1979 Ford Fairmont equipped with a 140 cubic inch inline 4-cylinder engine and automatic transmission. This vehicle used an oxidation cata- lyst for emission control. A complete description of these vehicles is given in the test vehicle description in Appendix A. Test Procedure Exhaust emission tests were conducted according to the 1977 Federal Test Procedure (FTP) described in the Federal Register of June 28, 1977, and the EPA Highway Fuel Economy Test (HFET), described in the Federal Register of September 10, 1976. The vehicles were not tested for evaporative emissions. ------- Prior to baseline testing, each vehicle was given a specification check and inspection. The ignition timing, idle speed, and fast idle speed were checked for agreement with the manufacturer's specifications given on the Vehicle Emission Control Information label affixed to the engine compartment. Each vehicle met its manufacturer's specifications and therefore no adjustments were required. The vehicles were inspected for engine vacuum leaks, proper connection of vacuum hoses, functioning PCV valve, oil and water levels, and general condi- tion of engine compartment. Each vehicle was in satisfactory condition when initially inspected. Because the manufacturer's claims for XRG #1 additive included both immediate and long term benefits (3) the test program included testing both immediately after initial additive usage and after-mileage accumulation with the additive. Each vehicle was tested in three different conditions: 1. Baseline - as received. 2. With XRG #1 (vehicle fuel tank drained, refueled with additive doped fuel and prepped before this test). 3. After 500 miles with XRG #1. At each test condition duplicate FTP and HFET tests were conducted. The accumulation of 500 miles using fuel with XRG //I consisted of sequences of 10 HFET driving cycles and one LA-4 (the basic FTP cycle) driving cycle. The relatively high average speed of the HFET (48 mph) was expected to minimize the amount of time to achieve those additive benefits that are based on vehi- cle mileage accumulation. Mileage accumulation was accomplished on a dyna- mometer. In addition, one vehicle, that was used in later test programs, received baseline tests after the 500 mile XRG #1 tests. All testing was performed using the same gasoline batch. Two barrels of the gasoline batch were doped with the XRG #1 at the manufacturer's prescribed doseage of 1600 parts gasoline to one part XRG //I. This XRG #1 doped gasoline was used for all XRG #1 tests and mileage accumulation. Discussion of Results General Data Analysis The objective of this test program was to determine if there was a significant beneficial change in vehicle emissions, fuel economy, or performance through the use of the fuel additive XRG #1. The results of these tests are summarized in Tables I and II. Results of individual tests are given in Tables V through X in Appendix B. The results of the statistical analysis and actual changes between configurations are shown in Tables III and IV. ------- 5 Table I Average Vehicle FTP Emissions grams per mile Test Condition Baseline XRG //I XRG //I @ 500 miles Baseline XRG #1 XRG #1 @ 500 miles Baseline XRG #1 XRG #1 @ 500 miles HC CO CO, NOx MPG Chevrolet Citation - FTP .35 .32 .33 1.93 2.03 1.86 450 449 440 1.55 1.62 1.61 19.5 19.6 20.0 Dodge Dart - FTP .63 .65 .48 7.90 8.64 6.93 568 583 563 1.81 1.72 1.85 15.3 14.8 15.4 Ford Fairmont - FTP .76 .71 .74 8.40 8.57 7.74 400 402 404 1.83 1.83 1.85 21.3 21.2 21.2 Table II Average Vehicle HFET Emissions grams per mile Test Condition Baseline XRG //I XRG #1 <§ 500 miles Baseline XRG #1 XRG #1 @ 500 miles Baseline XRG #1 XRG //I @ 500 miles HC CO CO, NOx MPG Chevrolet Citation - HFET .07 .06 .07 .05 .04 .04 .15 .14 .14 .02 .00 .00 Dodge Dart - .15 .11 .10 Ford Fairmont .63 .68 .58 313 310 300 HFET 368 374 364 - HFET 317 320 313 2.58 2.17 2.41 2.48 2.52 2.35 24.1 23.7 24.4 27.9 27.6 28.2 ------- Table III FTP Change From Baseline Due to XRG #1 Fuel Expressed in % at Minimum Stated Confidence Level* Test Condition HC Chevrolet Citation - FTP XRG #1 at 500 miles -6%*** Dodge Dart - FTP XRG #1 at 500 miles -24%*** Ford Fairmont - FTP XRG #1 at 500 miles -3%*** Combined Effect - All Vehicles XRG 31 at 500 miles *** C0_ -4%*** -12%*** -8% 94% C.L. *** NOx 4% 93% C.L. 2%*** 1%*** *** MPG 2% 99% C.L. 1%*** 0% *** Table IV HFET Change From Baseline Due to XRG //I Fuel Expressed in % Change at Minimum Confidence Level* Test Condition HC Chevrolet Citation - HFET XRG //I at 500 miles Dodge Dart - HFET XRG #1 at 500 miles Ford Fairmont - HFET XRG #1 at 500 miles Combined Effect - All Vehicles XRG #1 at 500 miles CO NOx 14% 99% C.L. MPG 5% 99% C.L. -7%*** -5%*** 1%*** 1%*** *** *** * Confidence level from statistical "t" test procedure and direction of change. C.L. - Confidence Level **+ indicates increase; - indicate decrease. *** indicates change not significant at 90% confidence level. That there is no significant change. Note: The confidence level should not be confused with changes of absolute values but are an indication of the statistical significance of the changes in the values given in Tables I and II. Note: The confidence level was not calculated for the initial XRG #1 tests. Note: Percent change not calculated for HC and CO emissions for HFET. See text. ------- From an initial review of the data given in Tables III and IV, it may appear that use of XRG #1 did cause some small changes in individual vehicle emis- sions or fuel economy. However, in order to determine whether the apparent differences were statistically significant, a significance test, such as a "t" test must be performed. This technique analyzes the difference due to the subject variable in relation to test to test variability to determine if the difference is real or is due to testing variability. The resultant signi- ficance determinations are stated in terms of the minimum percent confidence level that can be ascribed to the observed difference. The "t" test technique allows the determination of the effect of one variable (use of XRG #1 additive) on a vehicle. The "t" test is also able to indicate how representative the effect of the variable is for a group of vehicles. The resultant levels of significance are stated in terms of percents. This con- fidence level indicates the probability of assigning differences to the vari- able (use of XRG #1 additive) being analyzed. With a test program of the size performed, changes with confidence levels below 90% are not significant. EFFECT OF XRG #1 Federal Test Procedure The use of XRG //I did not significantly affect the HC emissions for the Citation, Dart or Fairmont. The use of XRG #1 caused mixed effects on CO emissions. There was no signi- ficant change in the Citation's or Dart's CO emissions. The Fairmont's emis- sions decreased 8% (at the 94% confidence level). The use of XRG //I caused mixed effects on NOx emissions. The Citation's NOx emissions increased 4% at the 93% confidence level. XRG #1 did not signifi- cantly affect the NOx emissions on the Dart or Fairmont. The use of XRG //I did not significantly affect the fuel economy of the Dart or Fairmont. (The Citation's fuel economy showed a slight improvement, 2% (at 99% confidence level). When the FTP results were analyzed to determine the effects of XRG #1 on the group of vehicles, the analysis showed that the use of XRG //I did not signifi- cantly affect either HC, CO and NOx emissions or fuel economy. Highway Fuel Economy Test The HC and CO emissions for all three vehicles were quite low both with and without use of the additive. HC and CO emissions are usually very low for most vehicles on the HFET. Thus, even a very small change such as .01 grams per mile could appear as a 5% to 30% relative change. Therefore, since the results were low and similar, there was no significant change in HC or CO emissions caused by the use of XRG #1. The use of XRG //I caused mixed results on NOx emissions. The Citation's NOx emissions increased 14% at the 99% confidence level. The Dart's and Fairmont's NOx emissions were not significantly affected. ------- The use of XRG #1 did not significantly affect the fuel economy of the Dart or Fairmont. The Citation's fuel economy showed a slight improvement, 4% at the 99% confidence level. The analysis of the HFET results to determine the effects of XRG #1 on the group of vehicles showed that the use of XRG #1 did not significantly affect either HC, CO and NOx emissions or fuel economy. Discussion of Additive Components and Their Effects According to the manufacturer, XRG #1 is composed mostly of isopropol alcohol and toluene. It also contains a small amount of ferrous sulphate, nitro benzene and water (4). An exact chemical breakdown was not given. Toluene is a normal component of gasoline. Unleaded gasoline is reported to presently contain 10 to 15% toluene and leaded gasoline 5 to 10% toluene (5). Premium leaded fuel is 6% toluene. Individual gasoline fuel samples have had up to 45% toluene. Conclusions Although a few individual tests indicated slight improvements in emissions or fuel economy through the use of XRG //I, several tests indicated small emission or fuel economy penalties. A significant but small improvement in fuel econ- omy was noted on one vehicle for the FTP and HFET. However, for the group of vehicles, XRG//1 showed no significant effect on vehicle emissions or fuel economy. ------- References 1. Evaluation of NRG #1, a Fuel Additive. TAEB Technical Report 77-19, February 1978. 2. Telephone conversation between Mr. F. Peter Hutchins, Project Manager, EPA and Mr. Brian Boshart, engineer, XRG International Inc., on August 8, 1979. 3. NRG Fuel Additive, product information brochure (Note XRG = NRG). 4. Letter dated September 16, 1977 from Mr. Brian F. Boshart, NRG Inter- national to Mr. Craig Harvey, EPA. Subject, NRG contents and previous test program schedule. 5. Telephone conversation between Mr. F. Peter Hutchins, EPA and Mr. William Meyer, Gulf Research and Development, on September 4, 1979. Subject, toluene in gasolines. ------- 10 Appendix A TEST VEHICLE DESCRIPTION Chassis model year/make - 1980 Chevrolet Citation Vehicle ID - 1X117AW150868 Engine type V-6, 4-Cycle bore x stroke 89 x 76 mm/3.50 x 2.99 in. displacement 2800 cc/170.9 CID compression ratio 8.5 to 1 maximum power at rpm 115 hp/85.8 kW fuel metering 2 Venturi Carburetor fuel requirement unleaded, tested with Indolene HO unleaded Drive Train transmission type 3-speed automatic final drive ratio 2.53 Chassis type 4 door sedan tire size P185/80R13 curb weight 2905 lb/1318 kg. inertia weight 3000 Ib. passenger capacity 5 Emission Control System basic type Oxidation catalyst EGR Pulsating air injection Vehicle Odometer Mileage 6730 miles at start of test program 7480 miles at end of test program ------- 11 TEST VEHICLE DESCRIPTION Chassis model year/make - 1975 Dodge Dart Emission control system - Air Pump, Catalyst EGR Vehicle I.D. - LH41C5B290359 Engine type Inline 6, 4-cycle bore x stroke 3.40 X 4.125 in. displacement . 225 CID/3687 cc compression- ratio 8.4:1 fuel metering 1 Venturi, carburetor fuel requirement v unleaded, tested with Indolene HO unleaded Drive Train transmission type . . . ., 3-speed automatic final drive ratio 2.75 Chassis type . . . 4 door sedan tire size D78 X 14 inertia weight 3500 Ib. passenger capacity 6 Emission Control System basic type air pump oxidation catalyst EGR calibrated to 1975 California standards Vehicle Odometer Mileage 20635 miles at start of test program 21950 miles at end of test program ------- 12 TEST VEHICLE DESCRIPTION Chassis model year/make - 1979 Ford Fairmont Vehicle I.D. 9X92Y175689 Engine type Inline 4, 4-cycle bore x stroke 3.80 X 3.10 in./96.5 X 78.7 mm. displacement 140 CID/2.3 1 compression ratio 9.0:1 maximum power 92 hp/68.6 k W fuel metering 2 Venturi, carburetor fuel requirement unleaded, tested with Indolene HO unleaded Drive Train transmission type 3-speed automatic final drive ratio 3.08 Chassis type 4 door sedan tire size BR 78 X 14 curb weight 2800 lb/1270 kg inertia weight 3000 Ib. passenger capacity .5 Emission Control System basic type oxidation catalyst Vehicle Odometer Mileage 10890 miles at start of test program 11525 miles at end of test program ------- 13 Table V Test Condition Baseline Baseline Baseline Baseline XRG (14 miles) XRG (55 miles) XRG (524 miles) XRG (552 miles) XRG (591 miles) Chevrolet Citation FTP Emissions grams per mile Test # EC CO CO, NOx MPG 79-9919 79-9921 79-9923 79-9925 79-9927 79-9929 79-9931 79-9978 79-9980 .39 .32 .33 .34 .32 .31 .35 .32 .32 2.29 1.66 1.73 2.03 2.23 1.83 1.87 1.91 1.80 452 450 450 449 450 447 441 440 439 1.54 1.56 1.56 1.52 1.60 1.63 1.57 1.65 1.62 19.4 19.5 19.5 19.6 19.5 19.7 19.9 20.0 20.0 Table VI Test Condition Baseline Baseline Baseline (769 miles) Baseline (1192 miles) XRG (8 miles) XRG (42 miles) XRG (521 miles) XRG (554 miles) XRG (595 miles) Dodge Dart FTP Emissions grams per mile Test # HC CO CO, NOx MPG 79-9778 79-9781 80-0246 80-0735 79-9782 79-9784 79-9786 79-9788 79-9986 .83 .79 .38 .50 .46 .84 .49 .47 .47 9.94 8.58 6.06 7.00 7.00 10.27 6.68 7.12 6.99 579 591 547 553 583 583 566 562 561 1.60 1.52 1.99 2.11 1.72 1.71 1.89 1.78 1.87 14.9 14.6 15.9 15.7 14.9 14.7 15.3 15.4 15.5 Table VII Test Condition Baseline Baseline XRG (5 miles) XRG (52 miles) XRG (509 miles) XRG (540 miles) Ford Fairmont FTP Emissions grams per mile Test # 79-9909 79-9911 79-9913 79-9915 79-9917 79-9984 HC .76 .76 .72 .70 .74 .74 CO 8.29 8.50 8.58 8.56 7.88 7.59 400 400 403 400 403 404 NOx 1.83 1.82 .83 .83 1.91 1.79 MPG 21.3 21.3 21 21 21.2 21.2 ------- 14 Table VIII Test Condition Baseline Baseline Baseline Baseline XRG(24 miles) XRG (66 miles) XRG (536 miles) XRG (568 miles) XRG (608 miles) Chevrolet Citation HFET Emissions grams per mile Test 9 HC CO CO, NOx MPG 79-9920 79-9922 79-9924 79-9926 79-9928 79-9930 79-9932 79-9979 79-9981 .07 .07 .07 .07 .06 .06 .07 .07 .07 .00 .05 .01 .01 .00 .00 .00 .00 .00 311 316 313 310 309 310 301 299 299 1.20 1.35 1.24 1.37 1.27 1.22 1.47 1.44 1.50 28.5 28.0 28.3 28.6 28.7 28.6 29.4 29.6 29.6 Table IX Test Condition Baseline Baseline Baseline (781 miles) Baseline (1228 miles) XRG XRG (19 miles) (53 miles) XRG (532 miles) XRG (565 miles) XRG (606 miles) Dodge Dart HFET Emissions grams per mile Test // HC CO CO, NOx MPG 79-9779 79-9780 80-0316 80-0734 79-9783 79-9785 79-9787 79-9789 79-9987 .05 .05 .05 .06 .04 .04 .04 .05 .04 .09 .08 .19 .22 .12 .09 .06 .09 .14 379 374 356 362 376 372 364 365 364 2.02 2.01 2.79 3.48 2.07 2.27 2.40 2.34 2.48 23.4 23.7 24.9 24.5 23.6 23.8 24.4 24.3 24.4 Test Condition Baseline Baseline XRG (24 miles) XRG (63 miles) XRG (520 miles) XRG (551 miles) Table X Ford Fairmont HFET Emissions grams per mile Test # HC CO CO, NOx MPG 79-9910 79-9912 79-9914 79-9916 79-9918 79-9985 .14 .15 .14 .14 .13 .14 .55 .70 .68 .67 .57 .59 316 317 320 319 312 314 2.50 2.45 2.44 2.61 2.31 2.39 28.0 27.8 27.6 27.7 28.3 28.1 US. GOVERNMENT PRINTING OFFICE: 1980- 651-112/0222 ------- |