EPA-AA-TEB-81-23
     Fuel Economy and Exhaust Emissions
        of  a Methanol-Fueled  Chevette
                     by
              H. Anthony Ashby
                  May 1981
         Test and Evaluation Branch
    Emission Control Technology Division
Office of Mobile Source Air Pollution Control
     Office of  Air,  Noise,  and  Radiation
    U.S. Environmental Protection Agency

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Abstract

This report  presents  the results of  a  series of  tests  conducted over  a
period  of  several  months  on  a  1979   Chevrolet Chevette  powered   by
anhydrous  methanol.   Baseline  tests  with  gasoline were  also  conducted
about  three  months before  the  methanol test  series  began.  The car  is
part  of  an  alcohol   evaluation program  run  by  the  Bonneville Power
Administration.  These  tests  were  conducted for  EPA  in Portland, Oregon
by a test contractor,  Hamilton Test Systems.

The  exhaust  emissions  from this car were greatly affected  by  air-fuel
ratio  and  state of tune.   Driveability was  not good  during  most tests
when CO met Federal standards.   The  best  optimized adjustments gave a  10
percent better  energy efficiency on pure  methanol  than on gasoline with
approximately similar exhaust emission levels.

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Background

In 1979, the Bonneville Power Administration  (BPA)  of  the  U.S.  Department
of Energy began  a  program of evaluating  alcohols  as motor vehicle  fuels
and  gasoline  extenders.   BPA's  activity   reflected  its   interest   in
domestically produced alcohol for motor fuel  and the need  to  develop user
experience  and  information on  the subject.   With the  enactment  of  the
Energy Security Act of 1980, BPA's program became more  significant.

To  BPA  personnel,   methanol  (CH^OH)  is  particularly  attractive   as  a
motor  fuel  because it  is  cheaper than  ethanol (02^08), which is made
from food crops  such as corn,  grain,  or  sugar beets.   Methanol would  be
made from coal,  municipal wastes, and  forest wastes.

By  the summer of  1980  BPA's program was far  enough  along   that exhaust
emissions tests  were needed.   Data from  Federal exhaust  emissions  tests
would  reveal whether emission-control performance was degraded  by the  use
of alcohol-gasoline blends or conversion to straight alcohol.

Following  inquiries  from  BPA,  the  EPA  Portland  Study  Project   Office
arranged for a series of tests to  be  conducted by  its  testing contractor,
Hamilton Test Systems.   In August and  September 1980, baseline gasoline
tests  and  a series of  tests with alcohol-gasoline blends were  conducted
on a BPA owned Chevette.   After  the car was converted to  run on straight
methanol,  a series  of  tests  was  conducted  between  November  1980  and
February 1981.

Test Vehicle

The  test  vehicle  was  a  1979  Chevrolet  Chevette with  98  cubic inch
displacement  engine and  automatic transmission.   Emission  controls   on
this car include exhaust gas recirculation and oxidation catalyst.

Dynamometer  loads   for  testing  were  2500 Ibs. inertia  weight  and  9.2
actual hp at 50 mph.

For the  gasoline baseline  tests, the car  was in totally  stock  condition
with all engine operating variables at manufacturer's specifications.

Converting the engine to run on raethanol included these steps:

The idle  mixture was adjusted  and the  main  metering  jet was  enlarged.
The carburetor  float was coated with a methanol-resistant substance.   A
mixture heater below the carburetor and a  fuel preheater,  both  making  use
of  the heat  in the  engine coolant,  were employed  to aid  in methanol
vaporization.  A cold start device was  installed for providing  a spray of
gasoline  into  the  carburetor  during  cold  ambient cold  starts.    (This
manually-operated device was not used  in the emissions  tests.)

The  initial   ignition  timing  was   advanced  about   8   degrees  from
manufacturer's   specification.   Original   equipment  spark  plugs  were
replaced with ones of lower heat rating.

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In  its  original form,  the methanol  conversion  included the  plugging  of
the  vacuum line to  the EGR  valve.   This  had  been  done  because of  the
erroneous assumption that  fueling with methanol  automatically  resulted  in
low NOx emissions.  After  the first set  of  tests,  the EGR  vacuum line was
unplugged.

Testing Program

The  tests  consisted  of the cold  start  1975 Federal  Test  Procedure  (FTP)
and  the Highway  Fuel Economy Test (HFET) for measuring  exhaust  emissions
and  fuel  economy.   Engine diagnostic tests were  conducted from  time  to
time to check the engine's state  of tune.   Evaporative emissions were not
measured.

Baseline  conditions  were  established  with  Indolene  HO  Unleaded  and
commercial unleaded gasolines in tests in August and September 1980.

In  November,  shortly  after  the conversion  to  methanol  was completed,  a
set  of duplicate tests were  conducted.   These were followed by additional
sets  of  duplicate  tests   after  various   repairs  and  adjustments  from
November 1980 through February 1981.

Results and Discussion

FTP composite mass emissions, FTP fuel economy,  and  HFET fuel  economy are
listed in  Table  1.   There  are also comments on the  car's  performance  on
the  FTP.   Included  are  the  "baseline"  data  using  Indolene  HO  and
commercial  unleaded   regular  gasoline   plus   five   different   sets   of
duplicate  tests  using  anhydrous  methanol.   (All fuels except  Indolene
were supplied by BPA.)

It is important  to note that in the  Federal Test  Procedure,  hydrocarbons
are"  measured  with  a  flame  ionization  detector.   The  response  of  this
instrument to methanol is  significantly  less than unity..   Therefore,  the
HC emissions listed  are estimated to  be  only 75% of  the actual  levels  of
unburned fuel emitted.

On  methanol,  the .car  was  plagued with  driveability  problems during  the
first three  minutes  of operation on  the  FTP.   These problems were  the
result  of  methanol's  high  heat  of   vaporization  and   the  resulting
difficulty in  vaporizing  methanol in a  cold engine.  The  need  to  go  to
wide-open  throttle  (WOT)  in  order to follow the FTP  speed-time schedule
reflects the lower energy content of methanol when compared to gasoline.

In  the  as-received  condition after  the conversion  to methanol,  the  NOx
emissions  were  almost three  times   as  high  as  the baseline  tests  on
gasoline.   (See  results   for tests  6  and 7.)   The party  making  the
conversion had  believed that because methanol  "burned cooler"  there  was
no need for NOx control and so plugged the EGR vacuum line.

The  plug  was  removed  for  tests 8 and  9.   This  resulted  in  reduced  NOx
emissions but also severely  degraded  driveability.   The  high  CO emissions
on test 9  led  to the  discovery that  the carburetor  float had  swollen  in
the presence of methanol and  had  stuck in a low position,  thereby causing
over-fueling.  Replacement of that float resulted in tests 10 and 11.

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The  vehicle  was  in fleet  service at  BPA during  most  of  December  and
January, during which  time mixture adjustments were  made to improve  the
cold-ambient driveability.   The  result of those  adjustments  are seen  in
tests 12  and 13, with the  CO  emissions at  over two  times  the Federal
standard, and almost three times the baseline levels.

The  final  adjustment   made in  this  series  of  tests  was  to install
different  jets  in  the carburetor.   Tests 14  and  15  showed  that  this
action produced acceptable emissions and  unimpaired  driveability on  the
FTP.

The  average  results from  the  baseline on unleaded  regular gasoline  and
the final "optimized" methanol version are as follows:

                   	Emissions	            Fuel Economy
                    HC     CO     NOx          ~TTPHFET
Gasoline           .56    13.0   1.13           24.7     30.5
Methanol           .75    15.4   1.20           13.3     16.0

The true HC emissions from methanol are probably about one gram per mile.

Fuel Economy can  also be expressed  according  to the energy available  in
the fuel.  The following values were taken from SAE paper number 800891:

    Energy content, gasoline                115,400 Btu/gallon
    Energy content, methanol                 56,560 Btu/gallon

The FTP fuel economy ratings then become:

    Gasoline:      2.14 x 10~4 mile per Btu
    Methanol:      2.35 x 10~4 mile per. Btu

It  can  be said that  the  energy in  the methanol is being utilized  about
10% more efficiently  than that in  the  gasoline.   This may be attributable
to the advanced spark timing in the methanol configuration.

Conclusions
Tests 14 and 15  showed  that  a relatively simple conversion of  a  gasoline
engine  to  methanol  can  result in  acceptable  levels  of  emissions  and
relatively   unimpaired   driveability.     That   statement    is   heavily
qualified.   Few  people  making such conversions  will have the  benefit  of
Federal exhaust  emissions tests to use  as a  diagnostic tool.   Few  will
also have a customer who is concerned with exhaust emissions.

Despite  its   reputation  among  its  enthusiasts,   methanol  does   not
automatically  "burn  clean".   All emission controls  on a gasoline  engine
should  remain  in  place  and  functioning when a  methanol  conversion  is
made.  Particular care must be  taken  to  ensure that there is no  material
incompatibility  in  the  fuel  system  that  could lead  to overfueling  the
air-fuel charge.

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Test  Vehicle Condition
 No.  Repairs, Adjustments
  2
  3

  4
  5

  6

 . 7
 8
 9
10

11

12
13
14
15
      Stock
After conversion
to methanol (EGR
vacuum line
plugged, timing +8'
from mfr. spec.)

Removed plug from
EGR vacuum line
Repaired sticking

carburetor float

Adjusted A/F mixture
to improve cold-
ambient operation.

Replaced carb jet
                       Table 1
             Emissions and Fuel Economy
              1979 Chevette, 98 CID, A3

             FTP Emissions   Fuel Economy
   Fuel        (gms/mi)        (mi/gal)
              HC*  CO    NOx   FTP   HFET
Indolene HO  .47  12.0  1.22  25.1 no test

             .51  10.9  1.15  24.9  30.0
             .46  11.2  1.15  24.7  30.3

 Unleaded-   .60  12.4  1.12  24.6  30.7
 Regular  .   .51  13.5  1.14  24.7  30.3

Methanol     .58  10.0  3.18  13.6  16.1

             .53  12.8  3.21  13.6  16.9



Methanol     .81  13.8  .99   13.8  16.6

             .88  27.1  .96   13.1  16.8


Methanol     .90  12.7  1.06  13.6  17.0

             .71   9.5  1.17  13.7  17.0

Methanol     .86  35.4  2.06  12.2  14.8
             .78  33.4  2.15  12.4  15.1
Methanol     .81  15.6  1.19  13.4  16.4
             .68  15.2  1.20  13.1  15.6
Comments

Stumble  at  165  sec.  on FTP.  WOT accel.  at
170 sec.
Same
Same

Same
Same

Stall at 25 sec, Stumble at 45, 55, 165.
WOT 168-173
Same
Stall at 24 sec, Many stalls at 340.  WOT
165-175, 190-200.
Stall at  24 sec, WOT  190-200. False  starts
on FTP Bag 3.

Stall at 22 sec, Stumbled btwn. 40-165
WOT 170-175, 190-200
Same

No stalls or stumbles
Stall at 23 sec.
No stalls or stumbles
Brief stumble at 190
sec.
NOTE:  In the carbon balance fuel economy calculations,  these values were used:
      2421 gm C per gallon Indolene and Unleaded Regular
      1153 gm C per gallon Methanol
*Due to the  response  charactersties  of the FID instruments to  methanol,
only 75% of the actual levels of unburned fuel emitted.
                                                                    the  HC emissions listed are  estimated  to be

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