EPA-AA-TEB-84-04
  EFFECT OF EVAPORATIVE CANISTER REMOVAL AND REID
VAPOR PRESSURE ON HYDROCARBON EVAPORATIVE EMISSIONS
                         by

                 William M. Pidgeon
                   September 1984
             Test and Evaluation Branch
        Emission Control Technology Division
              Office of Mobile Sources
        U.S.  Environmental Protection Agency

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I.   INTRODUCTION:

At the request of  the  Technical  Support Staff of EPA's Emission
Control  Technology Division,  the  Technology  Evaluation  Branch
tested   six  vehicles   for   evaporative  emissions  with  their
evaporative  canisters   removed.   Two  of  these  six  were  also
tested with  their  canisters  installed.   The other four vehicles
were tested  with  their canisters installed  in a prior project,
but those data are also included in this report.

For this  test  effort  the  vehicles  were tested  with  two  fuels;
Indolene  HO, which  is an  unleaded  gasoline that meets EPA test
fuel  specifications,   and   an  unleaded  commercial  gasoline.
Commercial fuel specifications generally allow greater variance
in batch to batch  characteristics  than Indolene.   Also,  among
other differences,  the volatility  of  commercial gasoline  can be
significantly  higher   than   Indolene's  volatility.    Refiners
routinely  adjust   commercial  fuels'  volatility  to  accommodate
ambient  pressures and  temperatures  that  vary  with  geographic
location and seasonal changes within geographic regions.

The  Environmental  Protection  Agency  (EPA)   uses  air  quality
models to  predict the  impact  of atmospheric  pollutants  on the
Nation's air  quality.   A  prerequisite  to  accurate  air quality
predictions  is data  on  the  emission  levels  of  current  and
future pollutant  sources.    MOBILES is  the  name of  the  newest
model  used  to   predict   these  emission   rates  for  on-road
vehicles.    In-use  data  collected   through   EPA's   National
Emission Factors  programs  have  shown  that  in  some cases  it is
incorrect  to  assume   that   the   emission   rates   of  on-road
pollutant  sources  are at   or-  below  the   standards  they  were
designed  to comply  with.   MOBILE3  is therefore  designed  to
permit employing  in-use data  to reflect real-world conditions.
The emission rates  predicted  by MOBILES  are- then  utilized by
the air quality models.

The 1977 amendments  to the Clean Air  Act,  Sections 203(a)(3)(A)
and   (B) ,  make   it   illegal  for  automobile  dealers,   fleet
operators, and  repair   or  service  facilities,  to disconnect or
modify emission control systems.   However,  surveys conducted in
1978,  1979,  1981  and 1982  found  that  evaporative control system
tampering  occurrences   ranged  from  1.5% in  the  1982  survey to
2.6%  in   the  1978   survey   [1].    Thus,   the  emission  rates
predicted   by   MOBILES,   and   the   subsequent   air   quality
predictions  will   be   in  error  if   not   corrected  for  this
tampering.   Since  over   one-half   of  the   hydrocarbons  in
urbanized  areas are from automobile  emissions [1] , evaporative
control  system  tampering  can  significantly affect  air quality
and should be accounted for.

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This  test  program  was  designed  to  quantify  the  evaporative
emissions  increase  on  in-use  vehicles   that  have  had  their
evaporative canisters  disconnected.   The  data  are to be used in
EPA's MOBILES emission rates model.

Surveys have  also  found that  the  Reid Vapor  Pressures  (RVP) of
commercial  gasolines   in  some geographical  regions  are  higher
than  Indolene HO's  RVP  [2].  Emission  factors   data  indicate
that  evaporative  emissions   increase  as  RVP  increases   [3].
Since  the emission  rates  have  been  based  on vehicles  tested
with  Indolene,  the  data  must   be   corrected  to  reflect  the
real-world situation wherein  vehicles use gasolines with higher
RVPs than Indolene.

So   in   addition  to  quantifying   the   evaporative  emissions
increase  with disconnected canisters,  this project  is  also  a
follow-up to  an  EPA project  that  assessed the  effect of  RVP on
evaporative   emissions  and   resulted  in  a   report  entitled
"Effects  of  Reid   Vapor  Pressure  on  Hydrocarbon  Evaporative
Emissions" (see Reference 3).

An additional  follow-on  project  evaluated the  effect of  RVP on
evaporative  emissions  of  older  vehicles  whose  model  years
ranged from 1963 to  1975.   A  final report on  the  older  vehicles
project  is  in  preparation and  will  be   released  in  the  near
future.

This report on evaporative canister removal (tampering)  will:

     1.   Quantify  the  increase   in  evaporative  emissions  when
evaporative canisters  are removed from in-use vehicles.

     2.   Quantify  the  increase   in  evaporative  emissions  when
the  Indolene   HO  test  fuel   (RVP=9.1  psi)   is  replaced by  a
commercial  fuel  with   a  Reid  Vapor Pressure of 11.7  psi.  This
discussion will  be  limited to the change  in  emissions  when the
canisters are removed.  RVP effects with the canisters
installed are discussed  in Reference 3.

The  data  will be used in the MOBILES on-road  vehicle  emission
rates  model  to  improve  the   accuracy  of  its  predictions  and
in-turn improve the accuracy of EPA's air quality predictions.

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II.  TEST VEHICLES

The  following  table  lists  the six  vehicles that  were  tested.
The  table  also  includes  the  evaporative  HC emission  standard
and the test procedure they were certified under.

                           Emission
                           Standard    Certification
                           g/test      Test Procedure

1974 Buick Century         2*          carbon trap method
1975 Chevy Nova            2*          carbon trap method
1979 Ford Pinto            6.0         SHED
1979 Olds Cutlass          6.0         SHED
1983 Olds Custom Cruiser
   (Wagon)                  2.0*        SHED
1983 Plymouth Reliant      2.0*        SHED

Vehicle descriptions  are  provided  in Appendix B.  The two  1983
vehicles  were   set   to   manufacturers'   specifications   before
testing.  The  other  four vehicles  were  checked out, but  were
not set  to  manufacturer's specifications  unless EPA judged that
the problem would have  been  apparent to  the typical owner.   The
checklists for these four vehicles are in Appendix C.

The 6.0 g/test standard of  the two 1979  vehicles is numerically
less  stringent  than  2 g/test standard  of  the  1974 and  1975
vehicles.   However,   the  certification   test   procedure   was
changed  from  the carbon  trap  method to the  Sealed Housing for
Evaporative Determination  (SHED) method  for the 1978 model year
vehicles.  This  test  procedure change effectively  made  the 6.0
g/test standard more stringent than the 2 g/test standard.

A  significant  evaporative control  system  difference between the
2  g/test  vehicles  and the other four vehicles  is  the method of
carburetor  float  bowl  venting.   The  2   g/test vehicles  have
their  float  bowls  vented  through  the air  cleaners.   The float
bowls  are vented through  the carbon  canisters of the other four
vehicles.
     Note  the  difference  in  significant  digits  between  the  2
     g/test  standard  and  the  2.0 g/test  standard.   Subsequent
     discussions  refer  to  the  vehicles  by  the  standards they
     are  certified  under  and   could  cause  confusion  if  the
     reader  incorrectly  assumes  they  are  the  same  standard.
     The test procedures are also different.

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III.  TEST PLAN

The basic  Federal  Test Procedure  (FTP)  with  the SHED procedure
was used  for  exhaust  and evaporative  emission testing  of  the
six vehicles.  Although  exhaust  emission tests were run and the
results  are  available,   they  will  not  be  discussed  in  this
document.

The FTP  requires that the  vehicles  be  preconditioned  with  the
Urban  Dynamometer   Driving   Schedule   (UDDS)   which  is  more
commonly referred to as the LA-4 driving cycle.  The LA-4 was
used to precondition four of the  vehicles  with their canisters
installed.   These  vehicles  were  previously  tested  to support
the project  documented in Reference 3.  They  are  the 1979 Ford
Pinto,   1979  Olds  Cutlass,  1983  Olds  Wagon,  and  the  1983
Plymouth  Reliant.    The   LA-4  duration  is   1372 seconds  (22.9
minutes)  and nominally 7.45 miles.

All  six   vehicles  listed  in  Section   II  of  this   report  were
tested  with  their   canisters  removed  to  support   the  project
documented  in  this  report.   They were  not  preconditioned with
the  LA-4.    The  LA-4  cycle  was  abbreviated  to its first  630
seconds  (4.04  miles)  and  is referred  to as Cycle  B.   All  six
vehicles    were    preconditioned   with   Cycle   B   in   the
"canister-removed" configuration.   Cycle B was also  used  for
the  1974   Buick  Century  and  the 1975 Chevy  Nova  with  their
canisters installed,  as well as with their canisters removed.

With  their  canisters  installed,  each  vehicle was   tested  a
minimum of  four  times; two  tests with  Indolene HO and two tests
with unleaded  commercial fuel.   The  test  sequences are  listed
in  Appendix A.   Because of  high variability,  the  Ford  Pinto
received  3  tests  with   Indolene  and  the  1979  Olds  Cutlass
received 3 tests with commercial fuel.

The canisters  were then  removed from   the  vehicles  to  minimize
the  test   variability  which  might occur  with  an   incompletely
purged canister  still in  the car.  The hoses  to  the  canister
were left  open.   Each car received two tests  with   its  canister
removed,  one  with  Indolene HO and one with commercial  unleaded
gasoline.

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IV.  TEST RESULTS

     1.  Effect of Canister Removal on Emissions

         a.  General Results

Table  1  lists  the  evaporative test  result averages   for  each
vehicle.   The  individual  test  results are presented in Appendix
D.  Table  2  summarizes the  mean  change  in emissions  after  the
canisters were  removed, and  lists  the coefficients of variation
(COV).    Table  3 stratifies  the  vehicles  into  three  categories
based  on the  emission standard  and  test procedure  they  were
certified  under.   It  lists  the  average  evaporative  emissions
for  each category  with  the canisters  removed.    MOBILES  uses
discrete inputs  for  diurnal  and hot  soak emissions rather  than
total  evaporative  emissions,  so   Tables   2,  3  and  4, and  the
following discussion do not include total emissions.

Canister  removal caused  larger  increases  in  commercial  fuel
diurnal  and  hot  soak  emissions   than  for Indolene  emissions.
Diurnal  emissions  (Table  2)   increased   an  average  of  15.24
g/test  with  Indolene  and  21.73   g/test  with  commercial  fuel.
Hot soak emissions  respectively  increased  8.26 and 9.81  g/test
when  the canisters  were  removed.   Note  that  this  discussion
concerns the average  change  in emissions  rather  than  the total
mass,  which  was  also  higher  with  commercial  fuel.    The  high
COVs (27% to 74%) in  Table  2 indicate that evaporative emission
sensitivity to  canister disablement  varies widely from vehicle
to vehicle.

Diurnal emissions increased  more with commercial  fuel than with
Indolene on  all  six  vehicles  (Table  1) .   Hot  soak  emissions
also increased  more  with  commercial fuel  than with Indolene, on
four of  the  six vehicles.  The 1974  Buick  Century and the  1975
Chevrolet Nova  had  larger increases  in hot soak  emissions  with
Indolene.  Their  increases  were 5.18  g/test  for   the  Buick  and
9.95 g/test  for  the  Nova.   These  hot soak  Indolene  increases
were  in-line  with   the  other  four   vehicles  whose  increases
ranged between  4.67 g/test  for  the  1983 Olds  Wagon  and 10.82
g/test for the  1979  Olds  Cutlass.   The Buick  actually showed an
insignificant  decrease in  commercial  fuel  hot  soak  emissions
(0.05  g/test)   when  the   canister  was  removed   and  the  Nova
increased  only  3.33  grams.    The   other  four  vehicles  had  an
average  increase in  hot  soak  emissions  of  13.89 g/test  with
commercial fuel.

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         b.  Buick and Nova Hot Soak Results

The  small  changes in  commercial fuel  hot  soak emissions  as a
result of  canister disablement  on  the  Buick and the Nova appear
questionable.  In comparison,  the  other four vehicles'  hot soak
emissions  increased significantly.   However,  the Buick  and Nova
commercial   fuel  emission   changes   appear  logical  when  the
evaporative  control   systems  of  the  vehicles  are  considered.
The Buick  and Nova are the  only vehicles whose carburetor float
bowls  are  not  vented  through  their  canisters.   Therefore,
removing  their  canisters  should   not   affect   the  evaporative
emissions from their  carburetors.

The Exxon Research and Engineering Company found that

     "Hydrocarbon vapors  escaping  from the air  cleaner  during
     the  hot  soak  are  by  far  the  largest  contributor  to
     evaporative  losses.   One  half  of the  hydrocarbon  loss is
     by  this route with  vapors escaping  from  the  air  cleaner
     snorkel." [4]

This finding  was based on  SHED testing of  twenty  1973  to 1975
vehicles.  Thus,  the  small  increase in hot soak emissions that
occurred after canister removal is  not surprising since most of
the  float  bowl  hydrocarbons  escape  from the  air  cleaner.   The
other  four  vehicles'  float  bowls  are vented through  their
canisters,  so  removing  their  canisters  can  be  expected  to
result in a significant increase in evaporative HC emissions.

While  these  factors   may  explain why  commercial fuel  hot  soak
emissions  did  not increase  on the  Buick  and  Nova,  they throw
the  Indolene  hot  soak   emissions  into  question.    Why  did
Indolene  hot soak emissions  increase  with  canister  removal if
their  canisters  are  not  used to control float bowl  emissions?
The  Exxon  report stated  that the  second  and third  largest
evaporative  emission  contributors were respectively  carburetor
leaks  and  canister overflow.  Carburetor  leaks should  not be
pertinent  since  the same  carburetors were used with both fuels,
but canister overflow may provide the solution  to the riddle.

The Exxon report said that overflow from the canister

     "is the third largest source of evaporative emissions
     with 10% occurring during  the diurnal cycle and an
     additional 10% during the  hot soak.  This  indicates
     insufficient working capacity in the canister of five of
     the twenty cars  in the group."  [4]

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The  Exxon  vehicles were  tested with  Indolene HO  which has an
RVP  specification  that holds  the  RVP range  to  between 8.7 and
9.2  psi.   The commercial  fuel  used in this  project  had an RVP
of 11.7 psi.   The  high volatility of  this  fuel  may have led to
canister overloading during the diurnal test.

How  would  canister overloading  provide an  explanation for the
increase in  hot  soak  Indolene  emissions with no  change in hot
soak commercial  fuel  emissions?   The explanation relies on  four
assumptions.   First  assume that the  Indolene diurnal tests did
not  overload  the  canisters,   but  they  were overloaded  on the
commercial fuel  diurnal  tests.   Or,  assume that the FTP driving
cycle  previous  to  the  Indolene  hot  soak  test  sufficiently
purged  the  canisters,  but  did  not  sufficiently  purge  the
canisters  when commercial  fuel  was used.   Second,  assume  that
evaporative  emissions  escaped  from  the  fuel  tank  vent  hoses
during  the  hot  soak  test.  The  vent hoses  were  left open  when
the  canisters  were removed.   Third,   assume  that  the  installed
canisters   were   overloaded   (first   assumption)   during  the
commercial fuel  diurnal  tests.   Therefore,  they would have  been
ineffective  in controlling fuel  tank emissions during the hot
soak   test.    Fourth,   assume  that   the   canisters  were  not
overloaded during  the Indolene diurnal  tests.   Therefore,  they
would  have been  effective in  controlling  fuel  tank  emissions
during the hot soak test.

If these assumptions  are  correct,  removing  the  canister  should
have caused  an increase in Indolene hot soak emissions  since an
effective  control  device  was removed.   Conversely,  commercial
fuel  hot   soak  emissions  should  not  have  increased  when the
canister was  removed  since  it  was  ineffective before  it was
removed.   This explanation is offered as a  theory;  it has not
been experimentally verified.

Although the  commercial fuel  hot  soak emissions  for the Buick
and  Nova hardly  changed after the canisters 'were removed, their
mass   emissions   were  roughly  two   times   greater  than  the
emissions  of  the other  vehicles with  their canisters  removed.
This   fact  bolsters   the  theory  that   the  canisters   were
overloaded  during  the  commercial  fuel diurnal  test.  This  also
suggests   that  parameters   other   than    the   canisters  are
responsible   for  the   lower   emissions  of   the   four  newer
vehicles.  One difference  is the  carburetor bowl  volumes which
range  between 45  and 65  cubic  centimeters  (cc)  on  the newer
vehicles compared to 76 cc on both the Buick  and the Nova.

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         c.   Vehicle to Vehicle Variations

As previously  stated,  the  COVs in Table 2 show  that  the effect
of canister  disablement  varied  significantly  from  vehicle  to
vehicle.   Table  1  shows   the  range  of  increase  in  diurnal
emissions was  9.84  g/test  for the 1983 Reliant  to  19.44 g/test
for the  1979  Cutlass with Indolene.  The range  of  increase  in
diurnal emissions with  commercial  fuel was  14.80 g/test for the
1979   Pinto  to  28.37  g/test   for  the 1979  Cutlass.   Canister
removal  allowed  hot  soak  emissions with  Indolene to  increase
from 4.67 g/test for  the Olds  Wagon  to 10.82 g/test  on  the 1979
Cutlass.  Hot  soak  emissions  with  commercial  gasoline increased
from no significant  change on  the  1974 Buick  to  19.04 g/test on
the  1983  Reliant.    These  ranges   represent  vehicle  averages
rather than single test extremes.

         d.   Comparative  Results  of Vehicles  Certified  Under
Different Evaporative Emission Standards

The  data  in   Table  3  list  the  average  emissions  for  three
vehicle  categories  -  the  three  evaporative emission standards
the vehicles  were  certified  under.  The data  indicate  that the
average  emissions   for  vehicles  certified  under  the  2  g/test
standard,  on   average,  had  higher  evaporative  emissions  than
their   four   counterparts  that   were   certified  under   more
stringent standards.

Comparing  the vehicles  certified  to  the  2.0   g/test  standard
with  the  vehicles  certified   to  the 6.0  g/test standard  show
that there  is less than a 1.0 g/test difference  in  the average
diurnal emissions  of each group.   The  2.0  g/test vehicles had
lower  average  hot  soak  emissions on  the   tests   run  with
Indolene, but  their  hot soak  emissions were higher  than the 6.0
g/test vehicles on the tests run with commercial fuel.

In summary,  the  "canister-removed"  data conclusively  show that
the  vehicles  certified  under   the 2   g/test   standard  have
significantly  higher emissions  than the  other  vehicles.   But
there   are   not   significant  group differences   between  the
vehicles  certified  to  the  6.0  g/test  standard  and  vehicles
certified to the 2.0 g/test standard.

     2.  Effect of Fuel Volatility on Evaporative Emissions

This section  discusses  the  change  in evaporative emissions when
Indolene HO with an  RVP of 9.1 pounds per square inch (psi) was

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                               10

replaced with  commercial  fuel having an RVP  of  11.7 psi.  This
discussion will  be  limited to the effect  of  fuel volatility on
evaporative emissions with  the canister  removed  since Reference
3 discusses the canister installed configuration.

Table   1   lists   the  ratios  for   Indolene   fuel  evaporative
emissions  versus commercial  fuel  emissions.   Commercial  fuel
evaporative emissions  with the  canisters  removed  were  greater
than Indolene emissions in all cases.

The  diurnal   ratio   is   defined   as  the   diurnal  evaporative
emissions with commercial  fuel divided  by  the diurnal emissions
with Indolene.   The hot  soak ratio  is  calculated  in  the  same
manner.  Table 4 lists  the mean  diurnal  and hot  soak  ratios.
The  six vehicle  mean  diurnal  ratio is 1.7  (Table 4)  and  the
mean  hot  soak  ratio  is  1.6.  However,  the hot  soak  ratios
segregate into two  groups.   The  first group,  which includes the
1979 Pinto and the  1979 Cutlass,  had a mean hot  soak  ratio of
1.3.   The  second,  which  includes  the  1974  Buick,  1975 Nova,
1983 Olds  Wagon  and the  1983 Plymouth  Reliant,  had  a  mean  hot
soak ratio of  1.8.   The mean  diurnal ratio is 1.6 for the first
group  and  1.7  for  the  second group, but  they do  not obviously
separate into two distinct groups as the hot  soak ratios do.

V.   SUMMARY OF RESULTS

     1.  Canister removal  caused  larger  increases in commercial
fuel   evaporative  emissions   than   for   Indolene   emissions.
Removal caused an average  increase in diurnal emissions of 15.2
g/test  with Indolene  for  the  six  vehicles.  On commercial fuel,
the  mean increase  was 21.7  g/test.  Mean   hot  soak  emissions
increased 8.3  g/test on Indolene  and 9.8  g/test  on commercial
gasoline.

     2.  The   range  of increase  in  diurnal  emissions  was  9.8
g/test  for the 1983  Reliant  to 19.4  g/test for the 1979 Cutlass
with Indolene.   The  range  of  increase in diurnal emissions with
commercial  fuel   was  14.8  g/test  for  the 1979  Pinto  to  28.4
g/test  for the 1979  Cutlass.   Canister  removal allowed hot soak
emissions  with  Indolene  to  increase  from  4.7  g/test  for  the
1983 Olds  Wagon  to  10.8 g/test  on the  1979  Cutlass.   Hot  soak
emissions with commercial  gasoline increased from  no  change on
the  1974 Buick   to  19.0  g/test   on  the  1983  Reliant.   These
ranges  are  for  vehicle   averages   rather   than  single  test
extremes.

     3.  The increases  in  evaporative emissions  upon removal of
the canisters varied widely from vehicle to vehicle.

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                               11

     4.  Canister removal  did  not make a significant difference
in the hot  soak emissions of  the 1974 Buick and  the  1975 Nova
when fueled with commercial gasoline.

     5.  With  their canisters  removed,  the 1974  Buick Century
and the  1975  Chevy Nova,  which  were certified to  the  2 g/test
standard,  had  higher  diurnal  and  hot  soak  emissions  (two
vehicle  averages)   on  Indolene  and commercial  fuels  than  the
group  average  emissions  of the  other  four vehicles  which were
certified  to   the  more  stringent  6.0  g/test*  and 2.0  g/test
standards.

     6.   The  average  diurnal  ratio**   was   1.7   for  the  six
vehicles.

     7.  The  average  hot soak ratio** for  the  six vehicles was
1.6.   However,  the  hot  soak  ratios segregate  into  two groups.
The  first  group, which  includes  the  1979 Pinto  and  the 1979
Cutlass,  had  a mean hot  soak  ratio of 1.3.  The  second,  which
includes the  1974  Buick,  1975 Nova,  1983 Olds  Wagon  and  the
1983 Plymouth Reliant, had a mean hot soak ratio of 1.8.

     8.  The  average  diurnal  ratio  is 1.6 for  the  first group
and 1.7  for  the second  group; they do  not  obviously  segregate
into two distinct groups as do the hot soak ratios.
*  Although  6.0  g/test  is  numerically  less  stringent  than  2
   g/test,  the  test  procedure  change  from  the  Carbon  Trap
   method  to  the SHED method  resulted  the 6.0  g/test standard
   being a more stringent than the 2 g/test standard.

** The   ratio   is   calculated   by  dividing  commercial  fuel
   emissions by  Indolene emissions for  tests  performed with the
   canisters removed.

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                               12

References

1.   "Motor  Vehicle  Tampering  Survey  -  1982,"  United  States
     Environmental Protection Agency, Office  of  Enforcement and
     Legal Counsel, EPA-330/1-81-001.

2.   Analysis of  MVMA  National Fuel Volatility Data,  Memo from
     Craig  A.  Harvey,  Technical  Support  Staff  to Charles  L.
     Gray,  Jr.,  Emission Control  Technology Division,  October
     7, 1983.

3.   "Effects of  Reid Vapor  Pressure on Hydrocarbon Evaporative
     Emissions,"  Edward  Anthony  Earth,  Environmental Protection
     Agency, EPA-AA-TEB-84-3.

4.   Investigation   and  Assessment   of   Light-Duty   Vehicle
     Evaporative  Emission Sources  and Control -  Contract  #68  -
     03  -  2172,   U.S.  EPA  -  Exxon Research  and  Engineering
     Company, P.J. Clarke, October 1975.

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                                                        Table 1
                             Mean Evaporative Emissions with Indolene and Commercial Fuels
Vehicle
Canister
  Diurnal
Ind.     Comm.
Ratio*
Hot Soak
Ind.   Comm.
Ratio*  Ind.
   Total
Comm.  Ratio*
1974 Buick Century** Installed
1974 Buick Century** Removed
Change
1975 Chevy Nova** Installed
1975 Chevy Nova** Removed
Change
1979 Ford
1979 Ford
Change
,1979 Olds
1979 Olds
Change
1983 Olds
1983 Olds
Pinto*** Installed
Pinto** Removed
Cutlass*** Installed
Cutlass** Removed
Wagon*** Installed
Wagon** Removed
Change
1983 Plymouth Reliant*** Installed
1983 Plymouth Reliant** Removed
Change

HC (g/test)
5.50 17.
22.46 36.
16.96
2.58
19.33
16.75
0.23
10.25
10.02
1.89
21.33
19.44
0.72
19.12
18.40
1.13
10.97
9.84
19.
10.
34.
24.
0.
15.
14.
7.
35.
28.
4.
32.
27.
2.
18.
15.
24
59
35
20
31
11
36
16
80
16
53
37
99
98
99
76
52
76
3.1
1.6
4.0
1.8
1.6
1.5
3.8
1.7
6.9
1.7
2.4
1.7
HC (g/test)
10.74 27.37 2.5
15.92 27.32 1.7
5.18
10.00
19.95
9.95
0.68
9.73
9.05
1.78
12.60
10.82
2.74
7.41
4.67
1.34
11.22
9.88
-0.
31.
34.
3.
0.
12.
11.
1.
17.
15.
4.
13.
9.
1.
20.
19.
05
53 3.2
86 1.7
33
92 1.4
18 1.3
26
66 0.9
48 1.4
82
34 1.6
79 1.9
45
62 1.2
66 1.8-
04
HC (g/test)
16.25 44.61
38.38 63.91
22.13
12.59
39.29
26.70
0.91
19.98
19.07
3.67
33.93
30.26
3.46
26.54
23.08
2.46
22.19
19.73
19.30
41.73
69.17
27.44
1.28
27.34
26.06
8.83
53.01
44.18
9.33
46.76
37.43
4.38
39.18
34.80
2.7
1.7
3.3
1.8
1.4
1.4
2.4
1.6
2.7
1.8
1.78
1.8
Number of Tests
Ind.   Comm.
                                                                                                          2
                                                                                                          1
                                                                                                          2
                                                                                                          1
                                                                                                          2
                                                                                                          1
                                                                                                          2
                                                                                                          1
                                                                                                                 2
                                                                                                                 1
                                                                                       2
                                                                                       1
                                                                                                                 2
                                                                                                                 1
                                                                                       3
                                                                                       1
                                                                                       2
                                                                                       1
                                                                                       2
                                                                                       1
Mean Change
           15.24   21.73
                        8.26   9.81
                              23.50  31.54
*    Ratio = Commercial Fuel Emissions/lndolene Emissions.

**   Cycle B prep used with both fuels (Cycle B is the first 630 seconds, 4.04 miles, of the LA-4 driving
     schedule).
***  LA-4 prep cycle used with both fuels.

-------
                                    14
                                 Table 2

    Mean Increase In Emissions Upon Canister Removal for Six Vehicles
Fuel

Indolene HO

Commercial
Increase in Diurnal Emissions  Coefficient of Variation
      15.24 g/test

      21.73 g/test
         28%

         27%
Fuel

Indolene HO

Commercial
Change in Hot Soak
HC Emissions

    8.26 g/test

    9.81 g/test
  Coefficient of Variation

         32%

         74%
                                 Table 3
          Average Evaporative Emissions of Vehicles Categorized
                  by their Evaporative Emission Standard
                            (Canisters Removed)
Evaporative
Standard
2 g/test*

6.0 g/test**

2.0 g/test***
  Mean Diurnal
  Emissions
Mean Hot
Soak Emissions
  	g/test	

  Indolene   Commercial      Indolene    Commercial

  20.90      35.45           17.94       31.09

  15.79      25.34           11.16       14.83

  15.04      25.75            9.32       17.22
*   1974 Buick Century, 1975 Chevy Nova

**  1979 Ford Pinto, 1979 Olds Cutlass

*** 1983 Olds Wagon, 1983 Plymouth Reliant

-------
                                   15
                                 Table 4

       Ratios of Evaporative Emissions  (Commercial/Indolene Fuel,
                           Canisters  Removed)
                         Diurnal Ratio    Hot Soak Ratio   Number of Tests
Vehicles                 Mean     COV     Mean     COV     Ind.    Comm.

All six                  1.7       6%     1.6      16%      6       6

First Group: '79 Pinto
& '79 Cutlass            1.6       9%     1.3       8%      2       2

Second Group: '74 Buick,
'75 Nova, '83 Olds,
& '83 Reliant            1.7       4%     1.8       4%      4       4

-------
                                   16
                               Appendix A-l

                 Test  Sequence With  Canisters  Installed

Test  vehicles  for  this   test   sequence  are:   1979  Ford  Pinto,  1979
Oldsmobile  Cutlass,  1983  Oldsmobile  Custom  Cruiser,  and  1983  Plymouth
Reliant.

    1.   Check vehicle.

    2.   Drain and".refuel with Indolene.

    3.   Road  preconditioning -  #1  Adrian  Road Route  (a 125 mile road
         route).

The  standard evaporative  emission  test  consists of  Steps 4  through  10
below:

    4.   Drain and 40% refuel  with chilled Indolene.

    5.   Dynamometer prep using LA-4 driving schedule.
    6.   Standard soak from 12 hours to 36 hours.

    7.   Drain and 40% refuel  with chilled Indolene.

    8.   Diurnal  evaporative  emissions   test   (one  hour  soak  in  SHED
         enclosure, fuel is heated from 60°F to  84°F).

    9.   Test  using  FTP (LA-4 driving schedule  with repeat  of first 505
         seconds).

    10.  Hot  soak  evaporative emissions test  (one  hour  soak  in  SHED
         enclosure).

    11.  Repeat numbers 4 through  10 above.

    12.  Repeat numbers  2  through 10  above  using  commercial  fuel so that
         each vehicle  receives two tests  with  commercial  fuel.

NOTE:   All  tests  were  with  Indolene HO for  the  first  two  tests and
commercial  unleaded  for  the next  two.   The Pinto's first three tests were
with  Indolene and  the  1979   Olds  Cutlass's  last  three tests  were with
commercial  fuel.

-------
                                    1.7


                               Appendix A-2

                  Test  Sequence With Canisters  Installed

Test  vehicles  for  this   test sequence  are:   1974  Buick Century,  1975
Chevrolet Nova.

    1.   Check vehicle.

    2.   Drain and refuel with  Indolene.

    3.   Driveability check -  one LA-4  driving schedule.

The  standard  evaporative  emission  test  consists  of  Steps 4  through  10
below except  that  the standard  LA-4  was replaced  by Cycle  B in Step 5:

    4.   Drain and 40% refuel  with  chilled Indolene.

    5.   Dynamometer prep  using Cycle  B driving schedule.

    6.   Standard  soak from 12 hours to 36 hours.

    7.   Drain and 40% refuel  with  chilled Indolene.

    8.   Diurnal   evaporative   emissions  test  (one  hour soak   in  SHED
         enclosure, fuel is heated  from 60°F to 84°F).

    9.   Test  using  FTP (LA-4  driving schedule with repeat  of first  505
         seconds).

    10.  Hot  soak  evaporative emissions  test   (one  hour  soak  in  SHED
         enclosure).

    11.  Repeat   numbers   4  through  10  above   unti-l   each  vehicle   has
         completed two tests with  Indolene.

    12.  Repeat  numbers  4  through  10  above  using commercial fuel so that
         each vehicle receives two  tests with  commercial fuel.

NOTES:   1.   All  tests  were  with  Indolene HO  for the first two tests  and
commercial unleaded for the next  two.

         2.   Cycle B  is the- first  630  seconds,  4.04 miles,  of  the LA-4
driving  schedule.

-------
                                  18
                              Appendix A-3

                  Test Sequence With Canisters Removed

Test  vehicles   for  this  test  sequence  are:  1974  Buick  Century,   1975
Chevrolet Nova, 1979 Ford Pinto, 1979 Oldsmobile Cutlass, 1983 Oldsmobile
Custom Cruiser, and 1983  Plymouth Reliant.

    1.   Remove canisters and leave hoses open

    2.   Check vehicle and 40% refuel with Indolene.

    3.   Dynamometer prep using Cycle B  driving  schedule.

    4.   Standard soak from 12 hours to  36 hours.

    5.   Drain and 40% refuel with chilled Indolene.

    6.   Diurnal  evaporative  emissions  test  (one   ho.ur  soak  in   SHED
         enclosure, fuel  is heated from  60°F to  84°F).

    7.   Test using FTP  (LA-4  driving schedule  with repeat of first  half
         of schedule).

    8.   Hot  soak  evaporative  emissions  test  (one  hour  soak  in   SHED
         enclosure)•

    9.   Repeat numbers 2 through 8 above using  commercial fuel.

NOTE:  Cycle B  is  the  first  630 seconds, 4.04 miles,  of  the LA-4  driving
schedule.

-------
                                      19
Make/Model

Model Year
Type
Vehicle ID
Initial OD

Engine:
    Type
    Conf ig.
    Disp.
    Fuel Metering
    Engine Fam.
    Evap. Fam.
                                       Appendix B-l
                                 Test Vehicle Description
                          6.0 Gram Evaporative Standard Vehicles
Buick/Century

1974
Sedan
4D29H4H156612
5.9,568
Spark Ignition
V-8
350 CID
2V Garb
unknown
unknown
Chevrolet/Nova    Ford Pinto    Olds Cutlass Supreme
1975
Sedan
1X27L115735
7,645
Spark Ignition
V-8
350 CID
2V Garb
11X43
unknown
1979
2 dr hatchback
9T11Y186165
26,750
Spark Ignition
In-line 4
2.3 liters
2V Garb
2.3A1X92EGR/CAT
B
1979
2 dr hardtop
3R47A9M523280
37,700 miles
Spark Ignition
V-6
231 CID
2V Garb
3.8L940B2
B
Emission Cont,
System
AIR/EGR
AIR/OC/EGR
PAIR/OC/EGR
PAIR/OC/EGR
Volumes:
Fuel Tank
Garb Bowl
Transmission
Test Parameters:
Inertia Wt.
HP @ 50 MPH
0303R
22 gal
76 cc
Automatic
3 Speed
4500 Ibs
14.0

21 gal
76 cc
Automatic
3 speed
4000 Ibs
12.0

13 gal
45 cc
Automatic
•3 speed
2750 Ibs
9.7

18.2 gal
50 cc
Automatic
3 speed
3500 Ibs
9.5


-------
                                  20
                              Appendix B-2
                      Test Vehicle Descriptions for
                   .0 Gram Evaporative Standard Vehicles
Make/Model

Model Year

Type

Vehicle ID

Initial OD

Engine:
    Type
    Config.
    Disp.
    Fuel Metering
    Engine Fam.
    Evap. Fam.

Emission Cont.
 System

Volumes:
    Fuel Tank
    Garb Bowl

Transmission
Test Parameters:
    Inertia Wt.

HP @ 50 MPH
Olds Custom Cruiser

1983

Station Wagon

1G3AP35Y5DX34364

22,400 miles
Spark Ignition
V-8
5.0 Liters
4V Garb
D3G5.0V4ARA9
3B4-3A

AIR/CL-3W/OC/EGR
22 gal
65 cc

Automatic
4-speed lock-up
4750 Ibs.

12.7
Plymouth Reliant

1983

Sedan

1P3BP26C9DF251538

2,500 miles
Spark Ignition
Transverse 4
2.2 Liters
2V Garb
DCR2.2VHAC3
DCRKA

AIR/CL-3W/OC/EGR
13  gal
51 cc

Automatic
3 speed
2750 Ibs.

8.0
0303R

-------
                      21
                                     VEHICLE CHECKLIST







              	 Year: '74  Model:CenEury Color:  vnrie  VIM:  4D29H4H1S6612




Technician/Mechanic: 35694              Dace: 1-25-84
Vehicle Mfr.: Buick
1. Install fuel drain
2. Thermocouple fuel cap for Bid-
volume fuel ceap. when 40Z filled
3. Pressure check fuel system
4. Change engine oil and filter
5. Check differential fluid
6 Check power steering fluid
7. Check transmission fluid
8. Check brake fluid
9. Exhaust system
10. Install boot on tailpipe
11. Canister and hoses visual check
12. Brake test
Ignition System
13. Points: a) dwell
b) resistance
c) timing spec 4° B

d) advance
start
done
ok
ok
ok
ok
15'
X
X
X


no leaks 	
ok X
ok
spec
ok
Srpa
X
30°
X
650
functions
done X
done X
In.H20 after 5min. 14'
not necessary
topped off
topped off
topped off X
topped off X
X leaks
done X
problem
needs repair
actual 29.3*
bad
actual 4.3° @rpm 529
X no good
                                                       problem
 15.  Battery




 Fuel System




 16.  Choke setting




 17.  Choke operation




 13.  Vaeuun break setting




 19.  Vacuum break operation




 20  Air cleaner




 21.  Adjust idle mixture to specs.




 22.  Idle speed




 23.  Fast idle speed




 Miscellaneous




 24.  Manifold heat valve




 25.  PCV  System




 26. EGR  Valve
                                        ok
                                                       problem
spec.
ok X
spec.
ok X
ok X
spec. 650
spec.
ok N/A
ok X
ok X
actual ~
problem
actual
problem
changed
done
actual 631
actual 1970
problem
problem
problem

-------
                    22
VeKtele Mrr.: Chevy
          VEHICLE  CHECKLIST              APPENDIX C-2





Ye*rr '75  Model;  Nova   Color:Yellov VIM:  LX27L5LU5735
Techaiciar/tfechanlc: 35694
             Date: 1-11-84
1. Install fuel drain
2. Thermocouple fuel cap for mid-
volume fuel temp, when 40! filled
3. Pressure check, fuel system
4. Change engine oil and filter
5. Check differential fluid
6 Check power steering fluid
7. Check transmission fluid
8.. Check brake fluid
9. Exhaust system
10. Install boot on tailpipe
11. Canister and hoses visual check
12. Brake test
Ignition System
13. Points: a) dwell
b) resistance
c) timing spec 6 B
d) advance
start 15'
done X
ok X
ok X
ok X
ok
no leaks X
ok X
ok X
spec fixed
ok X
@rpm 600
functions
done X
done X
In.H20 after Sain. 14 1/2 '
not necessary
topped off
topped off
topped off
topped off X
leaks
done X
problem
needs repair
actual 29.3*
bad
actual 8° 9rpm 535
X no good
 14.  Plugs, Wire*  and  Cap-  Scope  Check  ok    '.  X	problem




 15.  Battery                            ok	X	problem_




 Fuel System




 16.  Choke setting




 17.  Choke operation




 18.  Vacuum break setting




 19.  Vacuum break operation




 20  Mr cleaner                         	




 21.  Adjust idle mixture to specs.                     done




 22.  Idle speed




 23.  Fast idle speed




 Miscellaneous




 24.  Manifold .heat valve                ok	X	problem_




 25.  PCV System                         ok	X     problem




 26.  EGR Valve                          ok	X     problem
spec.
ok X
spec.
ok X
ok X
actual
problem
actual
problem
changed
             spec.  600 D   actual 635




             spec.  1600    actual 1600

-------
                  23
                                    VEHICLE  CHECKLIST
                                          APPENDIX C-3
Vehicle Mfr.: Ford
Techniclan/Hechaaic: 35694 .
Tear: '79  Model; Pinto  Color: Peach VIN: 9T11V186165



             Date: 2-24-84
1. Install fuel drain
2. Theraocouple fuel cap for aid-
volume fuel temp, when 40Z filled
3. Pressure check fuel system
it. Change engine oil and filter
5. Check differential fluid
6 Check power steering fluid
7. Check transmission fluid
4. Check brake fluid
9. Exhaust system
10. Install boot on tailpipe
11. Canister and hoses visual check
12. Brake test
Ignition System
13.
Points: a) dwell
b) resistance
c) tlning spec 20*
d) advance
start
done
ok
ok
ok
ok
15'

X
X
X
X
no leaks X
ok
ok
spec
ok
9rpo
X
X

X
600 dr
functions
done X
done X
In.HjO after 5min. 19'
not necessary X
topped off
topped off
topped off
topped off
leak*
done X
problem
needs repair
actual - —
bad
actual 20° 3rpra 650 dr
X no good
 14. Plugs, Wires and Cap- Scope Check  ok	X_
                            problem
 15. Battery                            ok




 Fuel System




 16. Choke setting




 17. Choke operation




 18. Vacuum break setting




 19. Vacuua break operation




 20 Air  cleaner




 21. Adjust idle mixture  to  specs.




 22.  lile speed                     '    spec.  800




 23.  Fast idle  speed




 Mi seellaneous




 24. Manifold heat  valve                 ok_




 25.  ?CV  System                         ok_




  26.  EGR  Valve                   '        ok
                            problem
spec.
ok X
spec.
ok X
ok X
actual
problem
actual
problem
changed
                           done
                           actual 808  rpo
              spec.  2000    actual  2027  rpm
                    S/A
 problem




_problem_




 problem

-------
                  24
                                     VEHICLE  CHECKLIST
                                                                     APPENDIX C-4
Vehicle Mfr.:  Olds
              	  	Year: 79   Model: Cut lass Color :Carmel  VIM;  3R47A9M523280



Technician/Mechanic: 35694              Date:  2-24-84
1. Install fuel drain
2. Thermocouple fuel cap for mid-
volume fuel temp, when 40Z filled
3. Pressure check fuel system
4. Change engine oil and filter
5. Check differential fluid
6 Check power steering fluid
7. Check transmission fluid
8. Check brake fluid
9. Exhaust system
10. Install boot on tailpipe
11. Canister and hoses visual check
12. Brake test
Ignition System
13. Points: a) dwell
b) resistance
c) timing spec 15*

d) advance
start 16'
done
ok X
ok X
ok X
ok X
no leaks
ok X
ok X
spec N/A
ok X
(?rpm 600
functions
done X
done X
In.H^O after Smin. 18'
noc necessary X
topped off
topped off
topped off
topped off
X leaks
done X
problem
needs repair
actual
bad
actual 15° 9rpm 600
X no good
 14.  Plugs,  Wires  and  Cap-  Scope  Check  ok  .    X	problem_




 15.  Battery                           ok	X	problem_




 Fuel System




 16.  Choke setting




 17.  Choke operation




 18.  Vacuum break  setting




 19.  Vacuum break  operation




 20  Air cleaner                         	




 21.  Adjust idle mixture to specs.                     done




 22.  Idle speed                         spec.  550




 23.  Fast Idle speed                        	      	




 Miscellaneous




 24.  Manifold heat valve                ok	X	problem




 25.  PCV System                         ok	X      problem




 26.  ECR Valve                          ok	X      problem
spec.
ok
spec.
ok
ok

X
X
X
X
actual
problem
actual
problem
changed
                                                      actual  550 drive
                                        spec.  2200     actual  2218

-------
Canister            Fuel

1974 Buick Century

    Installed       Indo.
    Installed       Indo.
    Installed       Comm.
    Installed       Comm.

    Removed     '. •   Indo.
    Removed         Comm.

1975 Chevrolet Nova
                                 25
                                   Appendix D-l
                              Individual Test Results
B
B
B
B

B
B
         Test
         Number
84-2315
84-2279
84-2280
84-2281

84-2416
84-2859
            Diurnal HC    Hot Soak HC
            	 g/test 	
 4.62
 6.38
17.09
17.39

22.46
36.59
10.47
11.02
30.92
23.81

15.92
27.32
Installed
Installed
Installed
Installed
Removed
Removed
Indo.
Indo.
Comm .
Comm.
Indo.
Comm.
B
B
B
B
B
B
84-1908
84-1909
84-2350
84-2410
84-2764
84-2765
2.49
2.67
9.23
11.17
19.33
34.31
10.89
9.12
30.662
32.40
19.95
34.86
1971 Ford Pinto
Installed
Installed
Installed
Installed
Installed
Removed
Removed
Indo.
Indo.
Indo.
Comm*
Comm.
Indo.
Comm.
LA-4
LA-4
LA-4
LA-4
LA-4
B
B
82-2399
84-0186
84-0187
84-0188
84-0377
84-0378
84-2630
0.11
0.28
0.30
0.48
0.25
10.25
15.16
0.50
0.73
0.81
0.48
0.25
9.73
12.18
1979 Oldsmobile Cutlass
Installed
Installed
Installed
Installed
Installed
Removed
Removed
Indo.
Indo.
Comm.
Comm.
Cornm.
Indo.
Comm.
LA-4
LA-4
LA-4
LA-4
LA-4
B
B
82-2397
84-0181
84-0182
84-0183
84-0184
84-2766
84-2767
1.80
1.98
2.81
12.65
6.03
21.33
35.53
1.85
1.70
1.68
1.48
1.83
12.60
17.48

-------
                                   26
                                     Appendix D-2
                                Individual Test  Results
Canister            Fuel
1983 Olds Wagon

    Installed       Indo.
    Installed       Indo.
    Installed       Comm.
    Installed       Comm.

    Removed         Indo.
    Removed         Comm.
1983 Plymouth Reliant
    Installed
    Installed
    Installed
    Installed

    Removed
    Removed
Indo.
Indo.
Cornm.
Comm.

Indo.
Comm.
Prep
'-' yc .L s
LA-4
LA-4
LA-4
LA-4
B
B
LA-4
LA-4
LA-4
LA-4
B
B
Test
Number

84-0862
84-0863
84-0864
84-0865
84-2439
84-2440
84-0383
84-0384
84-0387
84-0183
84-2457
84-2441
Diurnal H

0.65
0.79
2.98
7.00
19.12
32.98
1.28
.97
2.58
2.94 .
10.97
18.52
                                         :    Hot Soak HC
                                          g/test 	
                                               2,
                                               2,
                                               4,
                                               4,
  49
  98
  60.
  08
                                               7.41
                                              13.79
1.27
1.40
1.20
2.03

11.22
20.66

-------