EPA-AA-TEB-84-04 EFFECT OF EVAPORATIVE CANISTER REMOVAL AND REID VAPOR PRESSURE ON HYDROCARBON EVAPORATIVE EMISSIONS by William M. Pidgeon September 1984 Test and Evaluation Branch Emission Control Technology Division Office of Mobile Sources U.S. Environmental Protection Agency ------- I. INTRODUCTION: At the request of the Technical Support Staff of EPA's Emission Control Technology Division, the Technology Evaluation Branch tested six vehicles for evaporative emissions with their evaporative canisters removed. Two of these six were also tested with their canisters installed. The other four vehicles were tested with their canisters installed in a prior project, but those data are also included in this report. For this test effort the vehicles were tested with two fuels; Indolene HO, which is an unleaded gasoline that meets EPA test fuel specifications, and an unleaded commercial gasoline. Commercial fuel specifications generally allow greater variance in batch to batch characteristics than Indolene. Also, among other differences, the volatility of commercial gasoline can be significantly higher than Indolene's volatility. Refiners routinely adjust commercial fuels' volatility to accommodate ambient pressures and temperatures that vary with geographic location and seasonal changes within geographic regions. The Environmental Protection Agency (EPA) uses air quality models to predict the impact of atmospheric pollutants on the Nation's air quality. A prerequisite to accurate air quality predictions is data on the emission levels of current and future pollutant sources. MOBILES is the name of the newest model used to predict these emission rates for on-road vehicles. In-use data collected through EPA's National Emission Factors programs have shown that in some cases it is incorrect to assume that the emission rates of on-road pollutant sources are at or- below the standards they were designed to comply with. MOBILE3 is therefore designed to permit employing in-use data to reflect real-world conditions. The emission rates predicted by MOBILES are- then utilized by the air quality models. The 1977 amendments to the Clean Air Act, Sections 203(a)(3)(A) and (B) , make it illegal for automobile dealers, fleet operators, and repair or service facilities, to disconnect or modify emission control systems. However, surveys conducted in 1978, 1979, 1981 and 1982 found that evaporative control system tampering occurrences ranged from 1.5% in the 1982 survey to 2.6% in the 1978 survey [1]. Thus, the emission rates predicted by MOBILES, and the subsequent air quality predictions will be in error if not corrected for this tampering. Since over one-half of the hydrocarbons in urbanized areas are from automobile emissions [1] , evaporative control system tampering can significantly affect air quality and should be accounted for. ------- This test program was designed to quantify the evaporative emissions increase on in-use vehicles that have had their evaporative canisters disconnected. The data are to be used in EPA's MOBILES emission rates model. Surveys have also found that the Reid Vapor Pressures (RVP) of commercial gasolines in some geographical regions are higher than Indolene HO's RVP [2]. Emission factors data indicate that evaporative emissions increase as RVP increases [3]. Since the emission rates have been based on vehicles tested with Indolene, the data must be corrected to reflect the real-world situation wherein vehicles use gasolines with higher RVPs than Indolene. So in addition to quantifying the evaporative emissions increase with disconnected canisters, this project is also a follow-up to an EPA project that assessed the effect of RVP on evaporative emissions and resulted in a report entitled "Effects of Reid Vapor Pressure on Hydrocarbon Evaporative Emissions" (see Reference 3). An additional follow-on project evaluated the effect of RVP on evaporative emissions of older vehicles whose model years ranged from 1963 to 1975. A final report on the older vehicles project is in preparation and will be released in the near future. This report on evaporative canister removal (tampering) will: 1. Quantify the increase in evaporative emissions when evaporative canisters are removed from in-use vehicles. 2. Quantify the increase in evaporative emissions when the Indolene HO test fuel (RVP=9.1 psi) is replaced by a commercial fuel with a Reid Vapor Pressure of 11.7 psi. This discussion will be limited to the change in emissions when the canisters are removed. RVP effects with the canisters installed are discussed in Reference 3. The data will be used in the MOBILES on-road vehicle emission rates model to improve the accuracy of its predictions and in-turn improve the accuracy of EPA's air quality predictions. ------- II. TEST VEHICLES The following table lists the six vehicles that were tested. The table also includes the evaporative HC emission standard and the test procedure they were certified under. Emission Standard Certification g/test Test Procedure 1974 Buick Century 2* carbon trap method 1975 Chevy Nova 2* carbon trap method 1979 Ford Pinto 6.0 SHED 1979 Olds Cutlass 6.0 SHED 1983 Olds Custom Cruiser (Wagon) 2.0* SHED 1983 Plymouth Reliant 2.0* SHED Vehicle descriptions are provided in Appendix B. The two 1983 vehicles were set to manufacturers' specifications before testing. The other four vehicles were checked out, but were not set to manufacturer's specifications unless EPA judged that the problem would have been apparent to the typical owner. The checklists for these four vehicles are in Appendix C. The 6.0 g/test standard of the two 1979 vehicles is numerically less stringent than 2 g/test standard of the 1974 and 1975 vehicles. However, the certification test procedure was changed from the carbon trap method to the Sealed Housing for Evaporative Determination (SHED) method for the 1978 model year vehicles. This test procedure change effectively made the 6.0 g/test standard more stringent than the 2 g/test standard. A significant evaporative control system difference between the 2 g/test vehicles and the other four vehicles is the method of carburetor float bowl venting. The 2 g/test vehicles have their float bowls vented through the air cleaners. The float bowls are vented through the carbon canisters of the other four vehicles. Note the difference in significant digits between the 2 g/test standard and the 2.0 g/test standard. Subsequent discussions refer to the vehicles by the standards they are certified under and could cause confusion if the reader incorrectly assumes they are the same standard. The test procedures are also different. ------- III. TEST PLAN The basic Federal Test Procedure (FTP) with the SHED procedure was used for exhaust and evaporative emission testing of the six vehicles. Although exhaust emission tests were run and the results are available, they will not be discussed in this document. The FTP requires that the vehicles be preconditioned with the Urban Dynamometer Driving Schedule (UDDS) which is more commonly referred to as the LA-4 driving cycle. The LA-4 was used to precondition four of the vehicles with their canisters installed. These vehicles were previously tested to support the project documented in Reference 3. They are the 1979 Ford Pinto, 1979 Olds Cutlass, 1983 Olds Wagon, and the 1983 Plymouth Reliant. The LA-4 duration is 1372 seconds (22.9 minutes) and nominally 7.45 miles. All six vehicles listed in Section II of this report were tested with their canisters removed to support the project documented in this report. They were not preconditioned with the LA-4. The LA-4 cycle was abbreviated to its first 630 seconds (4.04 miles) and is referred to as Cycle B. All six vehicles were preconditioned with Cycle B in the "canister-removed" configuration. Cycle B was also used for the 1974 Buick Century and the 1975 Chevy Nova with their canisters installed, as well as with their canisters removed. With their canisters installed, each vehicle was tested a minimum of four times; two tests with Indolene HO and two tests with unleaded commercial fuel. The test sequences are listed in Appendix A. Because of high variability, the Ford Pinto received 3 tests with Indolene and the 1979 Olds Cutlass received 3 tests with commercial fuel. The canisters were then removed from the vehicles to minimize the test variability which might occur with an incompletely purged canister still in the car. The hoses to the canister were left open. Each car received two tests with its canister removed, one with Indolene HO and one with commercial unleaded gasoline. ------- IV. TEST RESULTS 1. Effect of Canister Removal on Emissions a. General Results Table 1 lists the evaporative test result averages for each vehicle. The individual test results are presented in Appendix D. Table 2 summarizes the mean change in emissions after the canisters were removed, and lists the coefficients of variation (COV). Table 3 stratifies the vehicles into three categories based on the emission standard and test procedure they were certified under. It lists the average evaporative emissions for each category with the canisters removed. MOBILES uses discrete inputs for diurnal and hot soak emissions rather than total evaporative emissions, so Tables 2, 3 and 4, and the following discussion do not include total emissions. Canister removal caused larger increases in commercial fuel diurnal and hot soak emissions than for Indolene emissions. Diurnal emissions (Table 2) increased an average of 15.24 g/test with Indolene and 21.73 g/test with commercial fuel. Hot soak emissions respectively increased 8.26 and 9.81 g/test when the canisters were removed. Note that this discussion concerns the average change in emissions rather than the total mass, which was also higher with commercial fuel. The high COVs (27% to 74%) in Table 2 indicate that evaporative emission sensitivity to canister disablement varies widely from vehicle to vehicle. Diurnal emissions increased more with commercial fuel than with Indolene on all six vehicles (Table 1) . Hot soak emissions also increased more with commercial fuel than with Indolene, on four of the six vehicles. The 1974 Buick Century and the 1975 Chevrolet Nova had larger increases in hot soak emissions with Indolene. Their increases were 5.18 g/test for the Buick and 9.95 g/test for the Nova. These hot soak Indolene increases were in-line with the other four vehicles whose increases ranged between 4.67 g/test for the 1983 Olds Wagon and 10.82 g/test for the 1979 Olds Cutlass. The Buick actually showed an insignificant decrease in commercial fuel hot soak emissions (0.05 g/test) when the canister was removed and the Nova increased only 3.33 grams. The other four vehicles had an average increase in hot soak emissions of 13.89 g/test with commercial fuel. ------- b. Buick and Nova Hot Soak Results The small changes in commercial fuel hot soak emissions as a result of canister disablement on the Buick and the Nova appear questionable. In comparison, the other four vehicles' hot soak emissions increased significantly. However, the Buick and Nova commercial fuel emission changes appear logical when the evaporative control systems of the vehicles are considered. The Buick and Nova are the only vehicles whose carburetor float bowls are not vented through their canisters. Therefore, removing their canisters should not affect the evaporative emissions from their carburetors. The Exxon Research and Engineering Company found that "Hydrocarbon vapors escaping from the air cleaner during the hot soak are by far the largest contributor to evaporative losses. One half of the hydrocarbon loss is by this route with vapors escaping from the air cleaner snorkel." [4] This finding was based on SHED testing of twenty 1973 to 1975 vehicles. Thus, the small increase in hot soak emissions that occurred after canister removal is not surprising since most of the float bowl hydrocarbons escape from the air cleaner. The other four vehicles' float bowls are vented through their canisters, so removing their canisters can be expected to result in a significant increase in evaporative HC emissions. While these factors may explain why commercial fuel hot soak emissions did not increase on the Buick and Nova, they throw the Indolene hot soak emissions into question. Why did Indolene hot soak emissions increase with canister removal if their canisters are not used to control float bowl emissions? The Exxon report stated that the second and third largest evaporative emission contributors were respectively carburetor leaks and canister overflow. Carburetor leaks should not be pertinent since the same carburetors were used with both fuels, but canister overflow may provide the solution to the riddle. The Exxon report said that overflow from the canister "is the third largest source of evaporative emissions with 10% occurring during the diurnal cycle and an additional 10% during the hot soak. This indicates insufficient working capacity in the canister of five of the twenty cars in the group." [4] ------- The Exxon vehicles were tested with Indolene HO which has an RVP specification that holds the RVP range to between 8.7 and 9.2 psi. The commercial fuel used in this project had an RVP of 11.7 psi. The high volatility of this fuel may have led to canister overloading during the diurnal test. How would canister overloading provide an explanation for the increase in hot soak Indolene emissions with no change in hot soak commercial fuel emissions? The explanation relies on four assumptions. First assume that the Indolene diurnal tests did not overload the canisters, but they were overloaded on the commercial fuel diurnal tests. Or, assume that the FTP driving cycle previous to the Indolene hot soak test sufficiently purged the canisters, but did not sufficiently purge the canisters when commercial fuel was used. Second, assume that evaporative emissions escaped from the fuel tank vent hoses during the hot soak test. The vent hoses were left open when the canisters were removed. Third, assume that the installed canisters were overloaded (first assumption) during the commercial fuel diurnal tests. Therefore, they would have been ineffective in controlling fuel tank emissions during the hot soak test. Fourth, assume that the canisters were not overloaded during the Indolene diurnal tests. Therefore, they would have been effective in controlling fuel tank emissions during the hot soak test. If these assumptions are correct, removing the canister should have caused an increase in Indolene hot soak emissions since an effective control device was removed. Conversely, commercial fuel hot soak emissions should not have increased when the canister was removed since it was ineffective before it was removed. This explanation is offered as a theory; it has not been experimentally verified. Although the commercial fuel hot soak emissions for the Buick and Nova hardly changed after the canisters 'were removed, their mass emissions were roughly two times greater than the emissions of the other vehicles with their canisters removed. This fact bolsters the theory that the canisters were overloaded during the commercial fuel diurnal test. This also suggests that parameters other than the canisters are responsible for the lower emissions of the four newer vehicles. One difference is the carburetor bowl volumes which range between 45 and 65 cubic centimeters (cc) on the newer vehicles compared to 76 cc on both the Buick and the Nova. ------- c. Vehicle to Vehicle Variations As previously stated, the COVs in Table 2 show that the effect of canister disablement varied significantly from vehicle to vehicle. Table 1 shows the range of increase in diurnal emissions was 9.84 g/test for the 1983 Reliant to 19.44 g/test for the 1979 Cutlass with Indolene. The range of increase in diurnal emissions with commercial fuel was 14.80 g/test for the 1979 Pinto to 28.37 g/test for the 1979 Cutlass. Canister removal allowed hot soak emissions with Indolene to increase from 4.67 g/test for the Olds Wagon to 10.82 g/test on the 1979 Cutlass. Hot soak emissions with commercial gasoline increased from no significant change on the 1974 Buick to 19.04 g/test on the 1983 Reliant. These ranges represent vehicle averages rather than single test extremes. d. Comparative Results of Vehicles Certified Under Different Evaporative Emission Standards The data in Table 3 list the average emissions for three vehicle categories - the three evaporative emission standards the vehicles were certified under. The data indicate that the average emissions for vehicles certified under the 2 g/test standard, on average, had higher evaporative emissions than their four counterparts that were certified under more stringent standards. Comparing the vehicles certified to the 2.0 g/test standard with the vehicles certified to the 6.0 g/test standard show that there is less than a 1.0 g/test difference in the average diurnal emissions of each group. The 2.0 g/test vehicles had lower average hot soak emissions on the tests run with Indolene, but their hot soak emissions were higher than the 6.0 g/test vehicles on the tests run with commercial fuel. In summary, the "canister-removed" data conclusively show that the vehicles certified under the 2 g/test standard have significantly higher emissions than the other vehicles. But there are not significant group differences between the vehicles certified to the 6.0 g/test standard and vehicles certified to the 2.0 g/test standard. 2. Effect of Fuel Volatility on Evaporative Emissions This section discusses the change in evaporative emissions when Indolene HO with an RVP of 9.1 pounds per square inch (psi) was ------- 10 replaced with commercial fuel having an RVP of 11.7 psi. This discussion will be limited to the effect of fuel volatility on evaporative emissions with the canister removed since Reference 3 discusses the canister installed configuration. Table 1 lists the ratios for Indolene fuel evaporative emissions versus commercial fuel emissions. Commercial fuel evaporative emissions with the canisters removed were greater than Indolene emissions in all cases. The diurnal ratio is defined as the diurnal evaporative emissions with commercial fuel divided by the diurnal emissions with Indolene. The hot soak ratio is calculated in the same manner. Table 4 lists the mean diurnal and hot soak ratios. The six vehicle mean diurnal ratio is 1.7 (Table 4) and the mean hot soak ratio is 1.6. However, the hot soak ratios segregate into two groups. The first group, which includes the 1979 Pinto and the 1979 Cutlass, had a mean hot soak ratio of 1.3. The second, which includes the 1974 Buick, 1975 Nova, 1983 Olds Wagon and the 1983 Plymouth Reliant, had a mean hot soak ratio of 1.8. The mean diurnal ratio is 1.6 for the first group and 1.7 for the second group, but they do not obviously separate into two distinct groups as the hot soak ratios do. V. SUMMARY OF RESULTS 1. Canister removal caused larger increases in commercial fuel evaporative emissions than for Indolene emissions. Removal caused an average increase in diurnal emissions of 15.2 g/test with Indolene for the six vehicles. On commercial fuel, the mean increase was 21.7 g/test. Mean hot soak emissions increased 8.3 g/test on Indolene and 9.8 g/test on commercial gasoline. 2. The range of increase in diurnal emissions was 9.8 g/test for the 1983 Reliant to 19.4 g/test for the 1979 Cutlass with Indolene. The range of increase in diurnal emissions with commercial fuel was 14.8 g/test for the 1979 Pinto to 28.4 g/test for the 1979 Cutlass. Canister removal allowed hot soak emissions with Indolene to increase from 4.7 g/test for the 1983 Olds Wagon to 10.8 g/test on the 1979 Cutlass. Hot soak emissions with commercial gasoline increased from no change on the 1974 Buick to 19.0 g/test on the 1983 Reliant. These ranges are for vehicle averages rather than single test extremes. 3. The increases in evaporative emissions upon removal of the canisters varied widely from vehicle to vehicle. ------- 11 4. Canister removal did not make a significant difference in the hot soak emissions of the 1974 Buick and the 1975 Nova when fueled with commercial gasoline. 5. With their canisters removed, the 1974 Buick Century and the 1975 Chevy Nova, which were certified to the 2 g/test standard, had higher diurnal and hot soak emissions (two vehicle averages) on Indolene and commercial fuels than the group average emissions of the other four vehicles which were certified to the more stringent 6.0 g/test* and 2.0 g/test standards. 6. The average diurnal ratio** was 1.7 for the six vehicles. 7. The average hot soak ratio** for the six vehicles was 1.6. However, the hot soak ratios segregate into two groups. The first group, which includes the 1979 Pinto and the 1979 Cutlass, had a mean hot soak ratio of 1.3. The second, which includes the 1974 Buick, 1975 Nova, 1983 Olds Wagon and the 1983 Plymouth Reliant, had a mean hot soak ratio of 1.8. 8. The average diurnal ratio is 1.6 for the first group and 1.7 for the second group; they do not obviously segregate into two distinct groups as do the hot soak ratios. * Although 6.0 g/test is numerically less stringent than 2 g/test, the test procedure change from the Carbon Trap method to the SHED method resulted the 6.0 g/test standard being a more stringent than the 2 g/test standard. ** The ratio is calculated by dividing commercial fuel emissions by Indolene emissions for tests performed with the canisters removed. ------- 12 References 1. "Motor Vehicle Tampering Survey - 1982," United States Environmental Protection Agency, Office of Enforcement and Legal Counsel, EPA-330/1-81-001. 2. Analysis of MVMA National Fuel Volatility Data, Memo from Craig A. Harvey, Technical Support Staff to Charles L. Gray, Jr., Emission Control Technology Division, October 7, 1983. 3. "Effects of Reid Vapor Pressure on Hydrocarbon Evaporative Emissions," Edward Anthony Earth, Environmental Protection Agency, EPA-AA-TEB-84-3. 4. Investigation and Assessment of Light-Duty Vehicle Evaporative Emission Sources and Control - Contract #68 - 03 - 2172, U.S. EPA - Exxon Research and Engineering Company, P.J. Clarke, October 1975. ------- Table 1 Mean Evaporative Emissions with Indolene and Commercial Fuels Vehicle Canister Diurnal Ind. Comm. Ratio* Hot Soak Ind. Comm. Ratio* Ind. Total Comm. Ratio* 1974 Buick Century** Installed 1974 Buick Century** Removed Change 1975 Chevy Nova** Installed 1975 Chevy Nova** Removed Change 1979 Ford 1979 Ford Change ,1979 Olds 1979 Olds Change 1983 Olds 1983 Olds Pinto*** Installed Pinto** Removed Cutlass*** Installed Cutlass** Removed Wagon*** Installed Wagon** Removed Change 1983 Plymouth Reliant*** Installed 1983 Plymouth Reliant** Removed Change HC (g/test) 5.50 17. 22.46 36. 16.96 2.58 19.33 16.75 0.23 10.25 10.02 1.89 21.33 19.44 0.72 19.12 18.40 1.13 10.97 9.84 19. 10. 34. 24. 0. 15. 14. 7. 35. 28. 4. 32. 27. 2. 18. 15. 24 59 35 20 31 11 36 16 80 16 53 37 99 98 99 76 52 76 3.1 1.6 4.0 1.8 1.6 1.5 3.8 1.7 6.9 1.7 2.4 1.7 HC (g/test) 10.74 27.37 2.5 15.92 27.32 1.7 5.18 10.00 19.95 9.95 0.68 9.73 9.05 1.78 12.60 10.82 2.74 7.41 4.67 1.34 11.22 9.88 -0. 31. 34. 3. 0. 12. 11. 1. 17. 15. 4. 13. 9. 1. 20. 19. 05 53 3.2 86 1.7 33 92 1.4 18 1.3 26 66 0.9 48 1.4 82 34 1.6 79 1.9 45 62 1.2 66 1.8- 04 HC (g/test) 16.25 44.61 38.38 63.91 22.13 12.59 39.29 26.70 0.91 19.98 19.07 3.67 33.93 30.26 3.46 26.54 23.08 2.46 22.19 19.73 19.30 41.73 69.17 27.44 1.28 27.34 26.06 8.83 53.01 44.18 9.33 46.76 37.43 4.38 39.18 34.80 2.7 1.7 3.3 1.8 1.4 1.4 2.4 1.6 2.7 1.8 1.78 1.8 Number of Tests Ind. Comm. 2 1 2 1 2 1 2 1 2 1 2 1 2 1 3 1 2 1 2 1 Mean Change 15.24 21.73 8.26 9.81 23.50 31.54 * Ratio = Commercial Fuel Emissions/lndolene Emissions. ** Cycle B prep used with both fuels (Cycle B is the first 630 seconds, 4.04 miles, of the LA-4 driving schedule). *** LA-4 prep cycle used with both fuels. ------- 14 Table 2 Mean Increase In Emissions Upon Canister Removal for Six Vehicles Fuel Indolene HO Commercial Increase in Diurnal Emissions Coefficient of Variation 15.24 g/test 21.73 g/test 28% 27% Fuel Indolene HO Commercial Change in Hot Soak HC Emissions 8.26 g/test 9.81 g/test Coefficient of Variation 32% 74% Table 3 Average Evaporative Emissions of Vehicles Categorized by their Evaporative Emission Standard (Canisters Removed) Evaporative Standard 2 g/test* 6.0 g/test** 2.0 g/test*** Mean Diurnal Emissions Mean Hot Soak Emissions g/test Indolene Commercial Indolene Commercial 20.90 35.45 17.94 31.09 15.79 25.34 11.16 14.83 15.04 25.75 9.32 17.22 * 1974 Buick Century, 1975 Chevy Nova ** 1979 Ford Pinto, 1979 Olds Cutlass *** 1983 Olds Wagon, 1983 Plymouth Reliant ------- 15 Table 4 Ratios of Evaporative Emissions (Commercial/Indolene Fuel, Canisters Removed) Diurnal Ratio Hot Soak Ratio Number of Tests Vehicles Mean COV Mean COV Ind. Comm. All six 1.7 6% 1.6 16% 6 6 First Group: '79 Pinto & '79 Cutlass 1.6 9% 1.3 8% 2 2 Second Group: '74 Buick, '75 Nova, '83 Olds, & '83 Reliant 1.7 4% 1.8 4% 4 4 ------- 16 Appendix A-l Test Sequence With Canisters Installed Test vehicles for this test sequence are: 1979 Ford Pinto, 1979 Oldsmobile Cutlass, 1983 Oldsmobile Custom Cruiser, and 1983 Plymouth Reliant. 1. Check vehicle. 2. Drain and".refuel with Indolene. 3. Road preconditioning - #1 Adrian Road Route (a 125 mile road route). The standard evaporative emission test consists of Steps 4 through 10 below: 4. Drain and 40% refuel with chilled Indolene. 5. Dynamometer prep using LA-4 driving schedule. 6. Standard soak from 12 hours to 36 hours. 7. Drain and 40% refuel with chilled Indolene. 8. Diurnal evaporative emissions test (one hour soak in SHED enclosure, fuel is heated from 60°F to 84°F). 9. Test using FTP (LA-4 driving schedule with repeat of first 505 seconds). 10. Hot soak evaporative emissions test (one hour soak in SHED enclosure). 11. Repeat numbers 4 through 10 above. 12. Repeat numbers 2 through 10 above using commercial fuel so that each vehicle receives two tests with commercial fuel. NOTE: All tests were with Indolene HO for the first two tests and commercial unleaded for the next two. The Pinto's first three tests were with Indolene and the 1979 Olds Cutlass's last three tests were with commercial fuel. ------- 1.7 Appendix A-2 Test Sequence With Canisters Installed Test vehicles for this test sequence are: 1974 Buick Century, 1975 Chevrolet Nova. 1. Check vehicle. 2. Drain and refuel with Indolene. 3. Driveability check - one LA-4 driving schedule. The standard evaporative emission test consists of Steps 4 through 10 below except that the standard LA-4 was replaced by Cycle B in Step 5: 4. Drain and 40% refuel with chilled Indolene. 5. Dynamometer prep using Cycle B driving schedule. 6. Standard soak from 12 hours to 36 hours. 7. Drain and 40% refuel with chilled Indolene. 8. Diurnal evaporative emissions test (one hour soak in SHED enclosure, fuel is heated from 60°F to 84°F). 9. Test using FTP (LA-4 driving schedule with repeat of first 505 seconds). 10. Hot soak evaporative emissions test (one hour soak in SHED enclosure). 11. Repeat numbers 4 through 10 above unti-l each vehicle has completed two tests with Indolene. 12. Repeat numbers 4 through 10 above using commercial fuel so that each vehicle receives two tests with commercial fuel. NOTES: 1. All tests were with Indolene HO for the first two tests and commercial unleaded for the next two. 2. Cycle B is the- first 630 seconds, 4.04 miles, of the LA-4 driving schedule. ------- 18 Appendix A-3 Test Sequence With Canisters Removed Test vehicles for this test sequence are: 1974 Buick Century, 1975 Chevrolet Nova, 1979 Ford Pinto, 1979 Oldsmobile Cutlass, 1983 Oldsmobile Custom Cruiser, and 1983 Plymouth Reliant. 1. Remove canisters and leave hoses open 2. Check vehicle and 40% refuel with Indolene. 3. Dynamometer prep using Cycle B driving schedule. 4. Standard soak from 12 hours to 36 hours. 5. Drain and 40% refuel with chilled Indolene. 6. Diurnal evaporative emissions test (one ho.ur soak in SHED enclosure, fuel is heated from 60°F to 84°F). 7. Test using FTP (LA-4 driving schedule with repeat of first half of schedule). 8. Hot soak evaporative emissions test (one hour soak in SHED enclosure)• 9. Repeat numbers 2 through 8 above using commercial fuel. NOTE: Cycle B is the first 630 seconds, 4.04 miles, of the LA-4 driving schedule. ------- 19 Make/Model Model Year Type Vehicle ID Initial OD Engine: Type Conf ig. Disp. Fuel Metering Engine Fam. Evap. Fam. Appendix B-l Test Vehicle Description 6.0 Gram Evaporative Standard Vehicles Buick/Century 1974 Sedan 4D29H4H156612 5.9,568 Spark Ignition V-8 350 CID 2V Garb unknown unknown Chevrolet/Nova Ford Pinto Olds Cutlass Supreme 1975 Sedan 1X27L115735 7,645 Spark Ignition V-8 350 CID 2V Garb 11X43 unknown 1979 2 dr hatchback 9T11Y186165 26,750 Spark Ignition In-line 4 2.3 liters 2V Garb 2.3A1X92EGR/CAT B 1979 2 dr hardtop 3R47A9M523280 37,700 miles Spark Ignition V-6 231 CID 2V Garb 3.8L940B2 B Emission Cont, System AIR/EGR AIR/OC/EGR PAIR/OC/EGR PAIR/OC/EGR Volumes: Fuel Tank Garb Bowl Transmission Test Parameters: Inertia Wt. HP @ 50 MPH 0303R 22 gal 76 cc Automatic 3 Speed 4500 Ibs 14.0 21 gal 76 cc Automatic 3 speed 4000 Ibs 12.0 13 gal 45 cc Automatic •3 speed 2750 Ibs 9.7 18.2 gal 50 cc Automatic 3 speed 3500 Ibs 9.5 ------- 20 Appendix B-2 Test Vehicle Descriptions for .0 Gram Evaporative Standard Vehicles Make/Model Model Year Type Vehicle ID Initial OD Engine: Type Config. Disp. Fuel Metering Engine Fam. Evap. Fam. Emission Cont. System Volumes: Fuel Tank Garb Bowl Transmission Test Parameters: Inertia Wt. HP @ 50 MPH Olds Custom Cruiser 1983 Station Wagon 1G3AP35Y5DX34364 22,400 miles Spark Ignition V-8 5.0 Liters 4V Garb D3G5.0V4ARA9 3B4-3A AIR/CL-3W/OC/EGR 22 gal 65 cc Automatic 4-speed lock-up 4750 Ibs. 12.7 Plymouth Reliant 1983 Sedan 1P3BP26C9DF251538 2,500 miles Spark Ignition Transverse 4 2.2 Liters 2V Garb DCR2.2VHAC3 DCRKA AIR/CL-3W/OC/EGR 13 gal 51 cc Automatic 3 speed 2750 Ibs. 8.0 0303R ------- 21 VEHICLE CHECKLIST Year: '74 Model:CenEury Color: vnrie VIM: 4D29H4H1S6612 Technician/Mechanic: 35694 Dace: 1-25-84 Vehicle Mfr.: Buick 1. Install fuel drain 2. Thermocouple fuel cap for Bid- volume fuel ceap. when 40Z filled 3. Pressure check fuel system 4. Change engine oil and filter 5. Check differential fluid 6 Check power steering fluid 7. Check transmission fluid 8. Check brake fluid 9. Exhaust system 10. Install boot on tailpipe 11. Canister and hoses visual check 12. Brake test Ignition System 13. Points: a) dwell b) resistance c) timing spec 4° B d) advance start done ok ok ok ok 15' X X X no leaks ok X ok spec ok Srpa X 30° X 650 functions done X done X In.H20 after 5min. 14' not necessary topped off topped off topped off X topped off X X leaks done X problem needs repair actual 29.3* bad actual 4.3° @rpm 529 X no good problem 15. Battery Fuel System 16. Choke setting 17. Choke operation 13. Vaeuun break setting 19. Vacuum break operation 20 Air cleaner 21. Adjust idle mixture to specs. 22. Idle speed 23. Fast idle speed Miscellaneous 24. Manifold heat valve 25. PCV System 26. EGR Valve ok problem spec. ok X spec. ok X ok X spec. 650 spec. ok N/A ok X ok X actual ~ problem actual problem changed done actual 631 actual 1970 problem problem problem ------- 22 VeKtele Mrr.: Chevy VEHICLE CHECKLIST APPENDIX C-2 Ye*rr '75 Model; Nova Color:Yellov VIM: LX27L5LU5735 Techaiciar/tfechanlc: 35694 Date: 1-11-84 1. Install fuel drain 2. Thermocouple fuel cap for mid- volume fuel temp, when 40! filled 3. Pressure check, fuel system 4. Change engine oil and filter 5. Check differential fluid 6 Check power steering fluid 7. Check transmission fluid 8.. Check brake fluid 9. Exhaust system 10. Install boot on tailpipe 11. Canister and hoses visual check 12. Brake test Ignition System 13. Points: a) dwell b) resistance c) timing spec 6 B d) advance start 15' done X ok X ok X ok X ok no leaks X ok X ok X spec fixed ok X @rpm 600 functions done X done X In.H20 after Sain. 14 1/2 ' not necessary topped off topped off topped off topped off X leaks done X problem needs repair actual 29.3* bad actual 8° 9rpm 535 X no good 14. Plugs, Wire* and Cap- Scope Check ok '. X problem 15. Battery ok X problem_ Fuel System 16. Choke setting 17. Choke operation 18. Vacuum break setting 19. Vacuum break operation 20 Mr cleaner 21. Adjust idle mixture to specs. done 22. Idle speed 23. Fast idle speed Miscellaneous 24. Manifold .heat valve ok X problem_ 25. PCV System ok X problem 26. EGR Valve ok X problem spec. ok X spec. ok X ok X actual problem actual problem changed spec. 600 D actual 635 spec. 1600 actual 1600 ------- 23 VEHICLE CHECKLIST APPENDIX C-3 Vehicle Mfr.: Ford Techniclan/Hechaaic: 35694 . Tear: '79 Model; Pinto Color: Peach VIN: 9T11V186165 Date: 2-24-84 1. Install fuel drain 2. Theraocouple fuel cap for aid- volume fuel temp, when 40Z filled 3. Pressure check fuel system it. Change engine oil and filter 5. Check differential fluid 6 Check power steering fluid 7. Check transmission fluid 4. Check brake fluid 9. Exhaust system 10. Install boot on tailpipe 11. Canister and hoses visual check 12. Brake test Ignition System 13. Points: a) dwell b) resistance c) tlning spec 20* d) advance start done ok ok ok ok 15' X X X X no leaks X ok ok spec ok 9rpo X X X 600 dr functions done X done X In.HjO after 5min. 19' not necessary X topped off topped off topped off topped off leak* done X problem needs repair actual - — bad actual 20° 3rpra 650 dr X no good 14. Plugs, Wires and Cap- Scope Check ok X_ problem 15. Battery ok Fuel System 16. Choke setting 17. Choke operation 18. Vacuum break setting 19. Vacuua break operation 20 Air cleaner 21. Adjust idle mixture to specs. 22. lile speed ' spec. 800 23. Fast idle speed Mi seellaneous 24. Manifold heat valve ok_ 25. ?CV System ok_ 26. EGR Valve ' ok problem spec. ok X spec. ok X ok X actual problem actual problem changed done actual 808 rpo spec. 2000 actual 2027 rpm S/A problem _problem_ problem ------- 24 VEHICLE CHECKLIST APPENDIX C-4 Vehicle Mfr.: Olds Year: 79 Model: Cut lass Color :Carmel VIM; 3R47A9M523280 Technician/Mechanic: 35694 Date: 2-24-84 1. Install fuel drain 2. Thermocouple fuel cap for mid- volume fuel temp, when 40Z filled 3. Pressure check fuel system 4. Change engine oil and filter 5. Check differential fluid 6 Check power steering fluid 7. Check transmission fluid 8. Check brake fluid 9. Exhaust system 10. Install boot on tailpipe 11. Canister and hoses visual check 12. Brake test Ignition System 13. Points: a) dwell b) resistance c) timing spec 15* d) advance start 16' done ok X ok X ok X ok X no leaks ok X ok X spec N/A ok X (?rpm 600 functions done X done X In.H^O after Smin. 18' noc necessary X topped off topped off topped off topped off X leaks done X problem needs repair actual bad actual 15° 9rpm 600 X no good 14. Plugs, Wires and Cap- Scope Check ok . X problem_ 15. Battery ok X problem_ Fuel System 16. Choke setting 17. Choke operation 18. Vacuum break setting 19. Vacuum break operation 20 Air cleaner 21. Adjust idle mixture to specs. done 22. Idle speed spec. 550 23. Fast Idle speed Miscellaneous 24. Manifold heat valve ok X problem 25. PCV System ok X problem 26. ECR Valve ok X problem spec. ok spec. ok ok X X X X actual problem actual problem changed actual 550 drive spec. 2200 actual 2218 ------- Canister Fuel 1974 Buick Century Installed Indo. Installed Indo. Installed Comm. Installed Comm. Removed '. • Indo. Removed Comm. 1975 Chevrolet Nova 25 Appendix D-l Individual Test Results B B B B B B Test Number 84-2315 84-2279 84-2280 84-2281 84-2416 84-2859 Diurnal HC Hot Soak HC g/test 4.62 6.38 17.09 17.39 22.46 36.59 10.47 11.02 30.92 23.81 15.92 27.32 Installed Installed Installed Installed Removed Removed Indo. Indo. Comm . Comm. Indo. Comm. B B B B B B 84-1908 84-1909 84-2350 84-2410 84-2764 84-2765 2.49 2.67 9.23 11.17 19.33 34.31 10.89 9.12 30.662 32.40 19.95 34.86 1971 Ford Pinto Installed Installed Installed Installed Installed Removed Removed Indo. Indo. Indo. Comm* Comm. Indo. Comm. LA-4 LA-4 LA-4 LA-4 LA-4 B B 82-2399 84-0186 84-0187 84-0188 84-0377 84-0378 84-2630 0.11 0.28 0.30 0.48 0.25 10.25 15.16 0.50 0.73 0.81 0.48 0.25 9.73 12.18 1979 Oldsmobile Cutlass Installed Installed Installed Installed Installed Removed Removed Indo. Indo. Comm. Comm. Cornm. Indo. Comm. LA-4 LA-4 LA-4 LA-4 LA-4 B B 82-2397 84-0181 84-0182 84-0183 84-0184 84-2766 84-2767 1.80 1.98 2.81 12.65 6.03 21.33 35.53 1.85 1.70 1.68 1.48 1.83 12.60 17.48 ------- 26 Appendix D-2 Individual Test Results Canister Fuel 1983 Olds Wagon Installed Indo. Installed Indo. Installed Comm. Installed Comm. Removed Indo. Removed Comm. 1983 Plymouth Reliant Installed Installed Installed Installed Removed Removed Indo. Indo. Cornm. Comm. Indo. Comm. Prep '-' yc .L s LA-4 LA-4 LA-4 LA-4 B B LA-4 LA-4 LA-4 LA-4 B B Test Number 84-0862 84-0863 84-0864 84-0865 84-2439 84-2440 84-0383 84-0384 84-0387 84-0183 84-2457 84-2441 Diurnal H 0.65 0.79 2.98 7.00 19.12 32.98 1.28 .97 2.58 2.94 . 10.97 18.52 : Hot Soak HC g/test 2, 2, 4, 4, 49 98 60. 08 7.41 13.79 1.27 1.40 1.20 2.03 11.22 20.66 ------- |