WATER POLLUTION CONTROL RESEARCH SERIES 12060—03/68 Aerated Lagoon Treatment of Food Processing Wastes ENVIRONMENTAL, PROTECTION AGENCY • WATER QUALITY OFFICE ------- WATER POLLUTION CONTROL RESEARCH SERIES The Water Pollution Control Research Series describes the results and progress in the control and abatement of pollu- tion of our Nation's waters. They provide a central source of information on the research, development, and demon- stration activities of the Water Quality Office, Environ- mental Protection Agency, through inhouse research and grants and contracts with Federal, State, and local agencies, re- search institutions, and industrial organizations. Inquiries pertaining to the Water Pollution Control Research. Reports should be directed to the Head, Project Reports System, Office of Research and Development, Water Quality Office, Environmental Protection Agency, Washington, D.C. 20242. ------- AERATED LAGOON TREATMENT OF FOOD PROCESSING WASTES Prepared by Kenneth A. Dostal Pacific Northwest Water Laboratory 200 Southwest 35th Street Corvallis, Oregon 97330 for the WATER QUALITY OFFICE ENVIRONMENTAL PROTECTION AGENCY Project #12060 03/68 March 1968 For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C., 20402 - Price 55 cents ------- 11 TABLE OF CONTENTS Chapter Page INTRODUCTION 1 Problem 1 Purpose 2 Authority 2 SUMMARY 3 THE KELLEY-FARQUHAR & COMPANY PLANT AND WASTE TREATMENT FACILITIES 5 Processing Plant 5 Waste Treatment Plant 6 Description 6 Operation 7 STUDY OF TREATMENT OPERATIONS 9 Data Collection Methods 9 Study Results 10 EVALUATION OF TREATMENT OPERATIONS 17 BIBLIOGRAPHY 27 APPENDIX 29 ------- iii LIST OF FIGURES Figure 1 Industrial Waste Treatment Facilities, Ferndale, Washington 2 Variation in Water Use With Time ..... 32 3 Quiescent Sedimentation Tests ...... 33 ------- IV LIST OF TABLES Table Page 1 Foods Processed and Water Used 34 2 Temperature and pH Data, July 13, 1967 35 3 Temperature and pH Data, July 20, 1967 36 4 Temperature and pH Data, July 27, 1967 37 5 Temperature and pH Data, August 3, 1967 .... 38 6 Temperature and pH Data, August 10, 1967 .... 40 7 Temperature and pH Data, August 17, 1967 .... 41 8 Lagoon Temperature Data 42 9 Lagoon Dissolved Oxygen Data 43 10 Solids Data 45 11 Inorganic Nutrient Data 46 12 Organic Carbon, pH and Alkalinity Data 47 13 BOD and COD Data 48 14 Average Percent Reductions 49 ------- ABBREVIATIONS BOD 5-day, 20°C biochemical oxygen demand, mg/1 COD chemical oxygen demand, mg/1 SS suspended solids, mg/1 TS total solids, mg/1 VSS volatile suspended solids, mg/1 TVS total volatile solids, mg/1 Temp. temperature, °C NH3-N ammonia nitrogen, mg/1 as N T.K.-N total Kjeldahl nitrogen, mg/1 as N T. P04 total phosphate, mg/1 as P04 0. PO^ ortho phosphate, mg/1 as P04 Alk. total alkalinity, mg/1 as CaC03 TOC total organic carbon, mg/1 DOC dissolved organic carbon, mg/1 D.O. dissolved oxygen, mg/1 SVI sludge volume index ------- vl ACKNOWLEDGMENTS The assistance and cooperation of Kelley-Farquhar & Co. and the State of Washington Water Pollution Control Commission are appreciated. ------- INTRODUCTION Problem The food-processing industry is the second largest industrial source of waterborne organic wastes in the Pacific Northwest. Wastes from the processing of foods are usually large in volume and of high oxygen-consuming pollutional strength. Adequate secondary treatment of these wastes by conventional processes is complicated by the seasonal nature of most of the food- processing plants and the large capital expenditures for waste treatment facilities which may be used for only a few months each year. Recently, several other industries have constructed waste treatment plants consisting of small, deep ponds with oxygen supplemented by mechanical surface aerators. Process efficiency can be varied over a wide range by control of nutrient feeds, oxygen addition, aeration basin detention time, and solids recycle. The pulp and paper industry estimates construction and operational costs of aerated lagoons at 60 and 40 percent, respec- tively, of those for activated sludge treatment in the 90 percent BOD removal range. Land requirements are reported to be about 5 to 10 percent of that used by conventional stabilization basins loaded at 50 pounds of BOD per acre per day. ------- 2 Although two food-processing plants, both in the State of Washington, have recently installed aerated lagoon facilities, there is a scarcity of good, reliable operational data. There is a very distinct need for this information so that the design of new facilities can be adequately assessed by State regulatory agencies prior to construction. Purpose The purpose of this study was to gather good operational data on a full-scale aerated lagoon which is used to treat food- processing wastes. Authority Following discussions between personnel of the Federal Water Pollution Control Administration (FWPCA) and representatives of the various State regulatory agencies concerned with water pol- lution in the Pacific Northwest, a study was initiated on treat- ment of food-processing wastes by aerated lagoons. This study was of specific interest to the State of Washington Water Pollution Control Commission as evidenced by the letter shown in the Appen- dix, page A-l. The Commission said, "...we have a very distinct need for additional performance and design information." Federal authorization for this type of study comes from the Federal Water Pollution Control Act, as amended. ------- SUMMARY This report presents the data collected and the conclusions drawn from a six-week period of sampling of an aerated lagoon used to treat wastes from the frozen pea processing plant of Kelley-Farquhar located at Ferndale, Washington. Eleven hour composite samples were collected one day per week from July 6 to August 17, 1967, of the influent to the 5.6 million gallon aerated lagoon, effluent from the lagoon and effluent from a 135,000 gallon polishing pond. Conclusions drawn from the sampling program include: 1. Water use per 1,000 pounds of peas processed averaged 3,500 gallons. Suspended solids, BOD and COD contributions to the waste stream per 1,000 pounds of peas averaged 10, 24, and 41 pounds, respectively. 2. Reductions in total BOD and COD across the aerated lagoon averaged 76 and 59 percent, respectively. Dissolved BOD was reduced by 95 percent and dissolved COD by 82 percent. 3. Inorganic nutrients were not reduced appreciably by the aerated lagoon. 4. The polishing pond readily filled with solids and ceased to function as a removal device. Suspended solids increased from 340 to 580 mg/1 across the aerated lagoon and the average reduction by the polishing pond was 10 percent. ------- 4 5. Current operation of the aerated lagoon results in foaming problems during the first week or two of operation and the growth of filamentous floe which causes a highly bulked sludge (SVI>1000). 6. When all four aerators are in operation, the reduction in organics across the complete-mixed lagoon can be predicted using available formulations. Necessary constants were obtained from this study. ------- THE KELLEY-FARQUHAR & COMPANY PLANT AND WASTE TREATMENT FACILITIES Processing Plant Kelley-Farquhar & Company owns and operates several food processing plants in western Washington and the Pacific North- west. Their plant at Ferndale, Washington, processes peas, carrots, asparagus, broccoli, strawberries, and raspberries. All of the finished products are frozen. The plant normally processes vegetables and berries which are grown on about 6,000 acres in Whatcom and Skagit Counties and disburses nearly $2,000,000 annually in payroll and payments to farmers and others. By far the strongest wastes are those derived from the processing of peas for freezing. In 1967 pea processing started July 6 and continued until August 17. For about the first week, processing was only done during the day shift. Then as the quantity of peas available for processing increased markedly, two shifts per day, six days per week, and one shift on Sunday were utilized for processing. Normally the day shift started at 8:00 a.m. and continued to about 5:30 p.m. Following clean-up the evening shift started at 7:00 p.m. and ran until 4:30 a.m. the following morning. ------- Waste Treatment Plant Description Wastes flow by gravity from the processing plant to a sump from which they are pumped to a rotary screen. Liquid effluent from the screen flows by gravity to the aerated lagoon. Screened solids are loaded on trucks and hauled away for use as a food supplement for cattle. Domestic wastes are kept separate from the processing wastes and are added to the city's sewers. Effluent from the aerated lagoon flows through a polishing pond and then to the Nooksack River. The outfall is located about six miles upstream from the mouth of the river which dis- charges into Bellingham Bay. The aerated lagoon has a surface area of 1.75 acres, an average depth of ten feet and a volume of 5.6 million gallons (mg). Side slopes of the lagoon are two horizontal to one vertical. Four 50 horsepower (hp) aerators, mounted on fixed platforms in the lagoon, have a rated aeration capacity of 12,000 pounds of oxygen per day. Effluent from the aerated lagoon flows into the north end of the polishing pond as shown on Figure 1 (Appendix, page A-2). Effluent from the 135,000- gallon pond overflows at the south end. The original design called for recirculation of settled solids from the polishing pond back to the aerated lagoon but this practice was never initiated. ------- 7 Operation The aerators are only used during the pea processing period since the quantity and strength of wastes from the other processed foods are considerably lower. For the first week or two of pea processing, less than four aerators are usually kept in operation depending upon the quantity of peas processed and the dissolved oxygen (D.O.) levels in the aerated lagoon. D.O. levels in the aerated lagoon are routinely checked twice a day by plant personnel. After the initial period of intermittent aerator operation, all four are run continuously until pea processing is terminated. Then the aerators are operated intermittently again for about another week to assure stabilization of the organic material present in the aerated lagoon. ------- STUDY OF TREATMENT OPERATIONS Data Collection Methods On July 13, 1967, and each Thursday thereafter for the period of study, a set of composite samples was taken of the aerated lagoon influent, lagoon effluent, and polishing pond effluent. Each set of samples was composited across the day shift, including clean-up, from 8:00 a.m. to 7:00 p.m. The samples were collected hourly on July 13 and composited accord- ing to flow. On July 20 and following Thursdays all samples were composited with time. The primary reason for the change in method of compositing is shown on Figure 2. Hourly varia- tions in water use were less than 10 percent from the average for July 13. All but one of the 30-minute periods of water use during a previous trip to the plant, August 17, 1966, showed deviations from the average use of less than ten percent. All samples were kept on ice during collection and were transported to the Laboratory in Corvallis on ice immediately after collection. Analyses were started on the morning follow- ing the day of collection. All analyses were performed accord- ing to Standard Methods^) with the following exceptions: nitrate nitrogen, (-*) Kjeldahl nitrogen,' ' total and ortho phosphate,^ ' and total organic carbon and dissolved organic carbon. ' In addition to the regular BOD and COD analyses sane ------- 10 of the samples were centrifuged and these two analyses were repeated on the centrates. The samples were centrifuged at about 3,000 revolutions per minute for fifteen minutes. Grab samples were also taken from the aerated lagoon and the polishing pond effluents for onsite pH and temperature measurements and for quiescent sedimentation tests. Grab samples of the aerated lagoon and polishing pond effluents were also taken and returned to Corvallis for examination of the numbers and kinds of biological organisms. Some dissolved oxygen readings were taken with a D.O. probe at various depths and locations in the aerated lagoon. The probe was calibrated by Winkler^- ' D.O. measurements onsite prior to use in the lagoon. The sampling stations shown in Figure 1 were about midway between the aerators and the bank. Previous sampling' ' had shown that the lagoon was completely mixed when all four aerators were used and these sampling locations would give representative D.O. concentrations. Study Results The quantities of peas and raspberries processed, the amount of water used and the number of aerators in operation for each of the days that samples were taken are shown in Table 1. From 96,000 to 180,000 pounds of peas were processed during the 8:00 a.m. to 5:30 p.m. shift. The quantity of raspberries processed varied from 0 to 21,000 pounds during the day shift. ------- 11 Water use was relatively constant and independent of quantity of food processed, varying from 456,000 to 563,000 gallons during the 8:00 a.m. to 7:00 p.m. period. On July 13, only three of the four aerators were in operation, the southeast one was off, and the following week, two were in operation, both the southeast and northwest ones were turned off. All four aerators were placed in operation on July 26 and continued in operation until after the end of pea processing. The pH and temperature data collected onsite in the grab samples of the lagoon influent, lagoon effluent, and polishing pond effluent are shown in Tables 2 through 7 in the Appendix. .Overall, the temperature range in the lagoon influent was from 17°C to 29.5° with a pH range from 6.7 to 8.2. The lagoon effluent had a temperature range of 19.5 to 23°C and a pH range of 6.6 to 8.1. Temperature and pH readings on the effluent from the polishing pond were nearly identical to those of the effluent from the aerated lagoon. For the six days of sampling the temperature drop across the lagoon averaged 0°C with daily averages ranging from a drop of 2°C to a temperature increase of 2°C. The air temperature was not followed as closely, but it generally ranged from 18 to 23°C. The aerated lagoon acted as a buffer zone, evening out the pH and temperature fluctuations that occurred in the influent stream. Table 8 presents temperature measurements that were taken in the aerated lagoon at the sampling points shown on Figure 1. ------- 12 Even though less than four aerators were in operation on July 13 and 20, the temperature data indicate fairly good mixing at least in the upper layer of the lagoon. On August 3 there appeared to be good mixing throughout the lagoon, evidenced by the temperatures taken at 11:00 a.m. and 3:00 p.m. Dissolved oxygen data collected with the probe are shown in Table 9. On July 13, the dissolved oxygen content near the southeast aerator, the one not running, was 0.3 to 2.1 mg/1 lower than at the other three sampling points. There was a range in oxygen content from 0.6 to 1.2 mg/1 in the morning and from 1.0 to 2.4 mg/1 in the afternoon at the other three stations both of which were probably due to the southeast aerator. Both the southeast and the northwest aerators were off on July 20. Near the surface the oxygen content was lower near these two aerators (stations 1 and 3) than it was at sta- tions 2 and 4. At the five foot depth, the oxygen content was low, about 0.2 mg/1, and rather uniform at all four stations. With all four aerators running on July 27 and August 3, the oxygen content ranged from 1.6 to 5.9 mg/1 in the lagoon. Although the values at the 8-foot depth were less than at the 1-foot depth, there was excess oxygen available at all of the sampling points. The D.O. content of the effluent from the polishing pond was about 4 mg/1 lower than the contents of the aerated lagoon during the afternoon of August 3. This resulted ------- 13 from the gas released upon anaerobic decomposition of the sludge which had accumulated in and filled the polishing pond. Samples of the lagoon and pond effluents collected on August 3 and analyzed by the Winkler method showed an oxygen content of about 1.5 mg/1. The oxygen demand in the lagoon had in- creased over that of the previous week, but the D.O. was still in a range that would not inhibit biological activity. D.O. concentrations on August 17 were down to 0.6 mg/1 and showed good mixing of the lagoon contents, both near the surface and at a depth of 8 feet. The measured concentration was near the level which may start to cause a slowdown in biological break- down of the organics. Quiescent settling tests were run in 2-liter graduated cylinders on grab samples of the lagoon effluent taken on the last four sampling trips. Figure 2 presents a plot of sludge volume in percent versus settling time in minutes for three of these tests. The results from the settling test conducted on August 3 were very similar to those obtained on August 17 and, therefore, are not shown. These tests were also conducted on the effluent from the polishing pond, but in every case they were virtually identical to those on the aerated lagoon effluent. On the first two sampling trips, these tests were not conducted since it was impossible to discern an interface upon settling. ------- 14 For the July 27 sedimentation curve the sludge volume index (SVI) was about 120, indicative of a good settling sludge. On the other three days, August 3, 10, and 17, the SVI was in excess of 1,000 which indicates that solids removal by conventional clarification methods would be almost impossible. A possible explanation for the bulking sludge will be discussed later. Table 10 presents the results of the solids analyses on the six sets of samples. Note the increase in suspended solids on passage through the- aerated lagoon, an average from 340 to 580 mg/1. The polishing pond improved reductions very little, especially during the last three weeks when it was full of sludge. Data collected on inorganic nutrients, nitrogen, and phos- phates, is shown in Table 11. Total Kjeldahl nitrogen averaged about 48 mg/1 in the waste stream entering the lagoon and total phosphates averaged 26 mg/1. Nearly all of the orthophosphate was incorporated into biological floe upon passage through the aerated lagoon. There was about 9 mg/1 in the influent and only 0.2 mg/1 in the lagoon effluent. The pH, alkalinity, and organic carbon data are shown in Table 12. The lagoon acted as a buffering system as it evened out the pH fluctuations of the incoming waste. There was a slight increase in total alkalinity upon passage through the lagoon from 260 to 270 mg/1 as CaCC>3- ------- 15 All COD and 6005 data collected are shown in Table 13. The average BOD of the aerated lagoon influent was 820 mg/1 and the effluents from the lagoon and the polishing pond averaged 196 and 182 mg/1, respectively. BOD of the supernatant following centri- fuging averaged about 30 mg/1 for both effluents. On July 20, when only 2 aerators were in operation, the soluble BOD was over 100 mg/1. On the effluent samples from July 27 to August 17, when all 4 aerators were operating, the soluble BOD averaged about 10 mg/1. The polishing pond did not alter the COD reductions signifi- cantly as its influent averaged 580 and the effluent averaged 550 mg/1. Sphaerotilus, the filamentous bacterium commonly seen as a gray slime growth in streams, was present in all samples from the lagoon and polishing pond effluents. On July 13 and 20, the majority of the filaments were short, less than 15 microns long. The density ranged from about 350,000 per milliliter on July 13 to over 2,000,000 per milliliter on July 20. In the samples collected on July 27, the biological floe was much denser and the Sphaerotilus appeared as long intertwined filaments. This was also the case for the samples col- lected on August 3, 10, and 17. Several types of protozoans were identified along with a few green attached and planktonic algae. On July 13 and 20 all of the protozoans identified were flagellates. In the samples collected on the last four sampling days, attached ciliates, crawling ciliates, free-swimming ciliates, and rhiezopods were also found but the flagellates continued to account for more than 70 percent of the protozoans. ------- EVALUATION OF TREATMENT OPERATIONS The quantity of water used per 1,000 pounds of peas processed varied from 2,900 to 5,300 gallons and averaged 3,500 gallons. Based on the analyses of the aerated lagoon influent (after screening), the contribution of SS, BOD, and COD per 1,000 pounds of peas processed averaged 10, 24, and 41 pounds, respectively. The range for SS was from 7 to 17.5 pounds, for BOD 18.5 to 31 pounds, and for COD 33 to 48 pounds, In general, as the total quantity of peas processed per shift increased, the contributions of flow, SS, BOD, and COD per 1,000 pounds decreased. Table 14 presents the average percent reduction in the various parameters analyzed on the composite samples. The polishing pond was of very little benefit as shown by the dif- ference between the reductions across the aerated lagoon and the reductions across the aerated lagoon plus the polishing pond. During the first few days of operation, the polishing pond did remove some suspended solids which also increased the organic removal somewhat, but the pond rapidly filled with solids and no further benefit was obtained. The total volatile solids were reduced about 50 percent but both the suspended solids and the volatile suspended solids increased substantially. Total phosphate and total ------- 18 nitrogen were not reduced significantly, but this was expected since the aerated lagoon was completely mixed and the polishing pond readily filled with the bulking solids. Total organic carbon, COD, and BOD were reduced by 66, 59, and 76 percent, respectively. The dissolved BOD was reduced by 96 percent for the entire period and by 98 percent for the period when four aerators were in oper- ation. Inasmuch as most of the BOD in the effluent samples was associated with the suspended solids, the overall treatment effi- ciency could have been markedly improved by a good solids removal step following the aerated lagoon. Normally this could be done rather easily, much as initially planned, by returning solids from the polishing pond back to the aerated lagoon. Once the suspended solids reach the condition where sedimentation is very slow (high SVI), good solids removal becomes almost impossible. This con- dition was present on August 3, 10, and 17- The reason or reasons why this condition is brought on were not pinpointed in this study. One possible explanation lies in the organic loading pattern. When the pea processing starts up initially, a large volume of high-strength wastes is discharged to the aerated lagoon. Al- though sufficient oxygen may be added to the lagoon, the food to micro-organism (F/M) ratio is very high since relatively little biological life is present in the lagoon. On July 20, the F/M ratio was about 0.8 pounds of BOD per day per pound of volatile suspended solids in the lagoon. Depending upon the type of waste ------- 19 being treated, F/M ratios between 0.5 and 1.0 lead to growth of filamentous organisms which in turn cause bulking sludge. During the four sampling periods which all aerators were in operation, the F/M ratio ranged from 0.22 to 0.34 and averaged 0.28. In this range the likelihood of causing filamentous growths is probably much less although the critical ratio for this specific waste was not determined from this study. The fact that less than four aerators are used during the first week or two of pea processing accentuates the load- ing problem. With only two or three aerators in operation, the aerated lagoon does not function as a complete-mixed system since most of the large biological floe will settle out in the lagoon. This, in turn, results in higher F/M ratios. The biological floe or suspended solids are also needed to absorb dissolved organics to minimize foaming problems. During the sampling on July 13 and 20, when less than four aerators were operating, two to three feet of foam covered most of the aerated lagoon. On successive sampling days when all four aerators were in operation, virtually no foam was in evidence on the lagoon. Use of four aerators markedly increased the solids in suspension which, in turn, absorbed more dissolved organics thereby eliminating the foam problem. The BOD:N:P ratio averaged 100:5.8:1.0 for the five days of sampling for which BOD's were run. A range from 100:5.1 to ------- 20 100:6.4 was observed for BOD:N ratio and the BOD:P ratio varied from 100:0.8 to 100:1.2. The most commonly quoted ratio de- picting inorganic nutrient requirements for aerobic biological treatment is 100:5:1. Assuming all of the total Kjeldahl nitro- gen and all of the total phosphate was available for biological synthesis, the average ratios observed indicate that the inorganic nutrients levels were adequate. Usually some of the organic nitrogen and the phosphates are present in a form not readily available for cell synthesis. This, coupled with the fact that the ratios on several samples were less than optimum, indicates that possibly some nutrient addition, especially phosphate, might improve the degree of treatment obtained by the facility. In a completely mixed basin, the BOD removal relationship has been shown by W.W. Eckenfelder, Jr.,^ ' to be: Sa-Se = k Se (1) Xat where: Sa = influent BOD Se = soluble BOD in effluent Xa = MLSS t = aeration time k = removal rate coefficient the solids in the basin (MLSS) and in the effluent are Xa = So + aSr (2) 1 + bt ------- 21 where: So = influent suspended solids a = yield coefficient, synthesis per unit sub- strate removed. b = cellular auto-oxidation rate, fraction per day. Total BOD in the effluent from the completely mixed basin will be: BOD = Se + c(Xa) (3) where: c = fractional BOD equivalent of suspended solids in the effluent. These three equations were used along with the results from the analyses of the samples from July 27 to August 17, the period when all four aerators were in operation, to determine values for the four constants. The values obtained were: k = 0.018 a = 0.70 b = 0.027 c = 0.24 The following tabulation shows both the calculated and measured values in mg/1 for the soluble effluent BOD (Se), effluent sus- pended solids (Xa) and total effluent BOD. ------- 22 Date 7-20-67 7-27-67 8-3-67 8-10-67 8-17-67 Soluble Calcu. 12 12 10 10 9 BOD Meas. 140 5 11 11 8 Sus. Calcu. 800 700 890 730 720 Solids Meas . 240 650 830 800 770 Total Calcu. 205 180 225 185 180 BOD Meas . 240 140 260 190 150 A.V6 TT3.2S 7 ~ 2 7 to 8-17 10 9 760 760 190 185 Also shown are the calculated and measured values for July 20, when only two aerators were in operation. The calculated MLSS was 800 mg/1 and the observed value was 240 which accounts for the measured soluble BOD in the effluent of 140 mg/1 compared to a calculated value of 12 mg/1. It was coincidental that the cal- culated total BOD was fairly close to the measured, 205 versus 240 mg/1. For the four days when all the aerators were in oper- ation, calculated and measured values agree fairly well. Percen- tage-wise, the largest error was. in the soluble BOD but the accuracy of the test in the 10 mg/1 area is rather poor. All suspended solids results agreed within ten percent and the BODs agreed with- in 20 percent except for the July 27 values. This may be partially explained by the fact that all four aerators were not placed in operation until July 26. On the average, agreement was very good considering only one shift per week was sampled. These constants can also be used to determine the degree of suspended solids removal that would be required to obtain a speci- ------- 23 fied effluent BOD. For example, if 90 percent BOD reduction was required, the total effluent BOD would have to be about 80 mg/1. With about 10 mg/1 of soluble BOD, the effluent suspended solids would have to be reduced to: Eff SS = 80-10 = 290 mg/1 0.24 or the aerated lagoon effluent suspended solids would be reduced by 62 percent. This could readily be accomplished by many con- ventional clarification systems as long as a low SVI was maintained through proper operation of the treatment facility. The problems of foaming, possible inorganic nutrient deficiency, low suspended solids reduction and high F/M ratio which cause sludge bulking could be partially solved by the following operation of the system: Prior to startup of pea processing, all four aerators should be placed in operation, at least intermittently. The number of hours operation per day will depend upon the quantity and strength of the wastes being produced at that time. A solids recirculation pump should be installed and also started when the aerators are placed in operation. This will allow the buildup of some solids in the aerated lagoon before the pea wastes are introduced which will aid in absorbing dissolved organics and maintain the F/M ratio as low as possible. Once pea processing has started, contin- uous recycle of suspended solids from the polishing pond back to ------- 24 the aerated lagoon will reduce foaming, possibly hold the F/M ratio low enough to stop the filamentous growth, return some inor- ganic nutrients to the aerated lagoon through auto-oxidation, and increase both the suspended solids reduction and total BOD reduc- tion. There would be some increase in oxygen demand in the aerated lagoon due to the sludge recycle, but the present aerators should be able to cope with it. The main unanswered question is whether enough solids can be built up in the aerated lagoon prior to the two critical periods (start of pea processing and change from one to two shifts per day) to keep the F/M ratio low enough to eliminate the filamentous growths. If this cannot be accomplished, then the use of a holding tank before the aerated lagoon may be advisable to spread the load out during the two critical periods. Since the polishing pond was not designed specifically for solids removal, it will be difficult to return most of the settled solids to the aerated lagoon. Multiple draw-off points in the lagoon bottom will be needed either through the use of separate lines or a line with several openings. Prior to the start of pea processing, the sludge return could be pumped intermittently depending upon the quantity and quality of solids in the effluent from the aerated lagoon. The waste treatment facility is an efficient and economical method of treatment. With some modifications, both the SS and BOD reductions could be markedly improved. ------- 25 Additional studies of this type are needed to more fully assess problems associated with biological treatment of seasonal industries such as food processing. Rapidly changing hydraulic and organic loads, and inorganic nutrient concentrations cause many operational problems in waste treatment. These problems will need solutions before higher levels of treatment can be obtained. ------- 27 BIBLIOGRAPHY Unpublished information from the State of Washington Water Pollution Control Commission. 1. Gellman, I., "Aerated Stabilization Basin Treatment of Mill Effluents," TAPPI, 48, 106A (1965) 2. Standard Methods for the Examination of Water and Wastewater, 12th Edition, 1965, Boyd Printing Co., Inc., Albany, New York. 3. Jenkins, P. and Medsker, L. L., "Brucine Method for the Deter- mination of Nitrate in Ocean, Estuarine, and Fresh Water." Analytical Chemistry, 36, 610 (1964) 4. Anonymous, Aminco Reprint No. 104. American Instrument Co., Inc. June 1959. 5. Strickland, J. D. H. and Parsons, T. R., "A Manual of Sea Water Analysis." Bulletin No. 125, Second Ed., pg. 47, Revised Fisheries Research Board of Canada. 6. ASTM D-2579-T, Issued 1967. Published by ASTM 1916, Race St., Philadelphia, Pennsylvania. 7. Murray, H. R. and Okey, R. W., "An Analysis of Aerated Lagoon Operation for Vegetable Wastes at Ferndale, Washington." 8. Eckenfelder, W. W., Jr., "New Design Advances in Biological Treatment of Industrial Wastes," Presented at 17th Annual Oklahoma Ind. Wastes and Pollution Control Conference, November 15, 1966. ------- APPENDIX ------- STATE OF WASHINGTON POLLUTION CONTROL COMMISSION 4O9 PUBLIC HTA1-TH DUILDtNG OLYMf.A, WASHINGTON January 19. 1966 Mr. R. F. Poston, Offieer-in-Charga Federal Water Pollution Control Administration Rocn 570 Pittock Block Portland, Orecon 97205 Dear Hr. PCStonj Ws understand that a research project on aerated lagoons is being proposed for tha Federal Water Pollution Control Administration laboratory ia Corvallia. Uc heartily support research in the Northwest on lagoons of this typa bscauf-a there itt at present a scarcity of good, reliable data for facility dc.-isn, and we believe that £heoo Byatcras havo & promising future for economical tre«tracnt of largo organic wasto loads. At present there, are thrco aerated la£°cns £n Washington treating pulp alii, vegetable., end fruit process wastes,, end withia tha jpaat few taoatha wo have r©vict?ed pinna for six additional fficilitlos of this gsmaral type. Consequently, fa hive a very distinct need for additional performance and dasijrn infomntion. I* va csn ba of sssiotanco in the development or implessentatioa of such research, please call on us at your convenience. Very truly yours, a Director K.MK:JPB:cJ cc: Mr. Boydoton FWPCA - Corvallia ------- ------- +^o \ 10 I -20 5 •JULY /3, /967 A, 8-'OO AM IQ-.OO T/Mf 6--00 PM F/GURE 2. VAX i AT 10 tJ /A/ U*e ------- /oo 1 I 1 ao 60 4O JULY 27 4O 30 120 /60 2OO T/M£ - A* /A/(JT£S 240 2&0 ------- 34 Table 1 (a) FOODS PROCESSED AND WATER USED Processed - Ibs. Water Used No. of Date Peas Raspberries Gals. Aerators 7-13-67 7-20-67 7-27-67 8-3-67 8-10-67 8-17-67 159,500 128,000 145,500 180,500 175,000 96,100 0 9,100 21,200 4,700 300 0 563,000 545,000 518,000 456,000 502,000 506,000 3 2 4 4 4 4 Average: 147,400 515,000 (a) Values for 1 shift (8:00 A.M. - 7:00 P.M.) ------- 35 Table 2 TEMPERATURE AND pH DATA JULY 13, 1967 Lagoon Influent Lagoon Effluent Pond Effluent Time 0800 0930 1030 1130 1230 1330 1430 1530 1630 1730 Temp. 19 20 20 17.5 20.5 17 19 20 19.5 18 2H 7.5 7.6 7.7 7.7 7.3 7.7 7.9 7.7 7.9 7.7 Temp. 20 20 20 20 20.5 21.5 21.5 22 22 22 £H 7.4 7.2 7.4 7.4 7.3 7.3 7.6 7.5 7.6 7.5 Temp. 19.5 19.5 20 20 21.5 22 22.5 22.5 22.5 22 2S 7.2 7.3 7.4 7.4 7.4 7.3 7.6 7.4 7.4 7.6 ------- 36 Table 3 TEMPERATURE AND pH DATA JULY 20, 1967 Lagoon Influent Lagoon Effluent Pond Effluent Time 0815 0845 0915 0945 1045 1115 1145 1215 1245 1315 1345 1415 1445 1515 1615 1715 1745 1815 Temp. 21 20 18.5 18.5 19 19 20 20 21 20 19.5 19 19 18.5 21 18.5 17 17 2H 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 .5 .5 .5 .4 .3 .3 .4 .3 .3 .4 .4 .5 .4 .5 .4 .4 Temp. 21 21 21 21 21 21 21 21 21 21 21 21 21 pH 7 7 7 7 7 7 7 7 7 7 7 7 .1 .3 .2 .1 .2 .2 .2 .1 .2 .1 .1 .2 Temp. 21 20 20.5 20.5 20.5 21 21 21 21 21 21 21 21 2! 7 7 7 7 7 7 7 7 7 7 7 7 .1 .1 .2 .0 .1 .1 .1 .0 .1 .1 .0 .1 ------- 37 Table 4 TEMPERATURE AND pH DATA JULY 27, 1967 Lagoon Influent Lagoon Effluent Pond Effluent Time 0815 0915 1015 1115 1215 1315 1415 1515 1615 1715 1815 Temp. 20 20.5 20.5 20 21 18 22.5 24 22.5 23 20 £H 7.4 7.3 7.4 7.5 7.4 7.6 7.0 6.7 7.0 6.7 7.0 Temp. 19.5 20 20 20 20 20 20.5 20.5 20.5 21 21 £H 7.3 7.3 7.3 7.4 7.3 7.2 7.0 6.6 6.9 6.9 7.0 Temp. 19.5 20 20 20 20 20 20.5 20.5 21 21 21 £S 7.3 7.3 7.3 7.4 7.3 7.2 7.0 6.5 6.5 6.7 6.9 ------- 38 Table 5 TEMPERATURE AND pH DATA AUGUST 3, 1967 Lagoon Influent Lagoon Effluent Pond Effluent j>H Temp. pH 7.5 20.5 7.5 Time 0815 0830 0845 0915 0930 1015 1030 1115 1130 1215 1230 1245 1315 1345 1415 1430 1515 1530 Temp. 19.5 20 20 22 20 24.5 26 24.5 24 25 26 pH Temp 7.8 20 7.5 7.5 20.5 7.4 22 7.5 22 7.6 21.5 7.7 7.6 7.7 7.7 23 7.6 23 7.5 21 7.3 7.4 21.5 7.2 7.4 21 7.3 7.4 23 7.2 7.6 24 7.5 7.7 23 7.4 ------- Time 1545 1615 1630 1645 1730 1745 1815 1830 Tern] 26 26 22 29.! 27 39 Table 5 (Cont.) TEMPERATURE AND pH DATA AUGUST 3, 1967 Lagoon Influent Lagoon Effluent Pond Effluent jgH Temp. j>H Temp. j>H 7.6 7.6 23 7.6 24 7.7 7.7 23 7.7 23 7.7 7.7 7.9 23 7.6 23 7.6 ------- 40 Table 6 TEMPERATURE AND pH DATA AUGUST 10, 1967 Time 0815 0915 1015 1115 1215 1315 1415 1515 1615 1715 1815 o — Temp. 19 21.5 19.5 21.5 21 21 23 22.5 24 18 21.5 £H 7.9 7.8 7.8 7.6 7.8 7.7 7.2 7.3 7.7 7.3 7.5 Temp. 20 20.5 21 21.5 22 22 22.5 22.5 22 23 22.5 £H 7.8 7.7 7.7 7.7 7.5 7.6 7.5 7.5 7.4 7.4 7.5 Temp. 20.5 21 21 21.5 22 22 22.5 22.5 22.5 23 22.5 J3H 7.9 7.6 7.7 7.7 7.4 7.4 7.5 7.5 7.5 7.4 7.5 ------- 41 Table 7 TEMPERATURE AND pH DATA AUGUST 17, 1967 Lagoon Influent Lagoon Effluent Pond Effluent Time 0815 0915 1015 1115 1215 1315 1415 1515 1615 1715 1815 Temp. 20 20 20.5 21 21 21 20.5 20.5 21 21 18 £H 8.2 7.9 7.9 7.3 7.5 7.8 7.6 7.5 7.5 7.5 7,8 Temp. 21 21 21 21.5 21.5 21.5 21.5 21.5 21.5 22 21.5 2H 8.1 8.0 7.9 7.7 7.5 7.5 7.5 7.6 7.7 7.5 7.6 Temp. 21 21 21.5 21.5 22 22 22 21.5 22 22 21 2H 7.7 7.5 7.7 7.5 7.3 7.3 7.4 7.4 7.3 7.4 7.4 ------- 42 Table 8 Date Time 7-13-67 1145 1545 7-20-67 1030 1500 1715 8-3-67 1100 1500 LAGOON TEMPERATURE DATA, °C Depth ft. 1 1 1 1 1 1 8 1 8 ill 20 22 20 20 20 19 19 22 21.5 SAMPLING STATION (2) (3) (4) 20 20 20 21.5 20.5 20.5 20.5 19.5 20 20.5 21 21.5 20 20 20.5 19.5 20 20.5 20.5 22.5 19.5 19.5 20 19.5 20 20.5 21 151 20 22 — — — — — 22 «• ------- 43 Table 9 LAGOON DISSOLVED OXYGEN DATA, mg/1 Depth SAMPLING STATION Date 7-13-67 7-20-67 7-27-67 8-3-67 8-10-67* Time 1145 1545 1030 1500 1715 1130 1530 1730 1100 1500 1000 1300 ft. 1 1 1 5 1 5 1 5 1 8 1 8 1 8 1 8 1 8 1 1 111 0.3 0.3 0.1 0.1 0.2 0.1 0.3 0.1 2.6 2.0 3.0 2.4 3.8 3.5 5.2 3.7 4.7 4.5 121 0.9 1.0 0.2 0.9 0.1 0.9 0.2 3.4 2.3 2.7 1.6 4.0 3.4 3.9 4.0 5.0 4.8 ill 0.6 1.4 0.1 0.2 0.2 0.1 0.2 0.1 3.8 3.5 3.7 2.3 3.8 3.4 4.3 4.1 5.6 5.3 (4) (5) (6) 1.2 0.3 2.4 0.3 0.6 1.1 0.3 0.7 0.3 4.6 3.8 3.8 4.9 4.8 3.7 4.4 4.8 4.4 5.2 4.8 6.3 1.8 5.9 1.7 1.3 1.7 1.4 ------- 44 Table 9 (Cont.) LAGOON DISSOLVED OXYGEN DATA, mg/1 Depth SAMPLING STATION Date Time ft. (1) (2) (3) (4) (5) (6) 1.8 1.4 0.6 0.6 0.6 1600 1100 1500 1700 1 1 8 1 8 1 8 0.7 0.6 0.6 0.6 0.6 0.6 0.7 0.7 0.6 0.6 0.7 0.7 0.6 0.6 0.6 0.6 0.6 0.6 0.7 0.7 0.7 0.7 0.7 0.7 D.O. run by Winkler^ ' method. ------- Table 10 SOLIDS DATA, mg/1 45 7-20-67 7-27-67 8-3-67 8-10-67 8-17-67 Location T.S. T.V.S. S.S. V.S.S. Lagoon Influent 2460 1610 440 270 Lagoon Effluent 1950 1220 280 220 Pond Effluent 1970 1160 150 120 Lagoon Influent 2850 1450 310 Lagoon Effluent 1940 560 240 Pond Effluent 1860 510 180 Lagoon Influent 2560 1380 250 160 Lagoon Effluent 2250 680 650 440 Pond Effluent 2000 500 440 310 Lagoon Influent 2830 1540 330 180 Lagoon Effluent 2330 680 830 550 Pond Effluent 2330 670 820 540 Lagoon Influent 3120 1350 300 110 Lagoon Effluent 2460 680 800 500 Pond Effluent 2400 650 790 520 Lagoon Influent 2760 1110 400 230 Lagoon Effluent 2330 640 770 510 Pond Effluent 2340 660 740 490 Average Overall: Lagoon Influent Lagoon Effluent Pond Effluent 7-27 to 8-17: Lagoon Influent Lagoon Effluent Pond Effluent 2760 1410 2210 740 2150 690 340 580 520 320 760 700 190 440 400 170 500 465 ------- 46 Table 11 INORGANIC NUTRIENT DATA Date Location NH-N T.K.-N 7-13-67 Lagoon Influent 4.0 49.6 Lagoon Effluent 0.7 31.9 Pond Effluent 0.4 26.6 7-20-67 Lagoon Influent 3.1 44.0 21.7 9.1 Lagoon Effluent 0.5 23.6 12.6 0.2 Pond Effluent 2.2 20.6 9.6 0.1 7-27-67 Lagoon Influent 3.6 52.1 24.5 14.0 Lagoon Effluent 1.1 44.0 22.9 0.1 Pond Effluent 4.1 32.6 18.3 0.2 8-3-67 Lagoon Influent 4.2 53.0 39.1 12.7 Lagoon Effluent 1.5 53.0 40.9 0.1 Pond Effluent 3.7 53.0 43.9 0.2 8-10-67 Lagoon Influent 3.2 48.1 20.4 4.1 Lagoon Effluent 5.9 48.1 24.3 0.3 Pond Effluent 5.6 51.6 19.5 0.1 8-17-67 Lagoon Influent 2.8 38.0 17.0 5.5 Lagoon Effluent 3.3 64.3 22.5 0.2 Pond Effluent 6.7 61.4 24.3 0.9 Average: Lagoon Influent 3.5 47.5 25.6 8.6 Lagoon Effluent 2.2 44.2 23.3 0.2 Pond Effluent 3.8 39.4 21.7 0.3 ------- 47 Table 12 ORGANIC CARBON, pH AND ALKALINITY DATA Date Location pH Alk. TOG DOC 7-13-67 Lagoon Influent 640 Lagoon Effluent 7.3 280 200 Pond Effluent 7.3 280 170 7-20-67 Lagoon Influent 7.7 250 560 Lagoon Effluent 7.1 270 160 Pond Effluent 7.1 270 190 7-27-67 Lagoon Influent 7.8 250 Lagoon Effluent 7.5 270 190 Pond Effluent 7.5 290 150 8-3-67 Lagoon Influent 7.6 260 570 Lagoon Effluent 7.5 270 230 Pond Effluent 7.5 280 200 8-10-67 Lagoon Influent 7.8 270 540 Lagoon Effluent 7.6 290 170 Pond Effluent 7.6 290 180 8-17-67 Lagoon Influent 7.0 260 400 280 Lagoon Effluent 7.2 260 160 24 Pond Effluent 7.3 300 130 23 Average: Lagoon Influent 260 540 Lagoon Effluent 270 185 Pond Effluent 285 170 ------- 48 Table 13 BOD AND COD DATA Date Location BOD Total Dissolved COD Total Dissolved 7-13-67 7-20-67 7-27-67 8-3-67 Lagoon Influent Lagoon Effluent Pond Effluent Lagoon Influent Lagoon Effluent Pond Effluent 870 240 190 Lagoon Influent 810 Lagoon Effluent 140 Pond Effluent 140 Lagoon Influent 1020 Lagoon Effluent 260 Pond Effluent 260 870 140 110 740 5 12 850 11 7 1470 510 430 1350 410 310 1540 650 490 1580 650 670 1500 160 170 8-10-67 Lagoon Influent 780 Lagoon Effluent 190 Pond Effluent 150 8-17-67 Lagoon Influent 620 Lagoon Effluent 150 Pond Effluent 170 710 11 11 550 8 16 1540 740 740 1060 540 640 1370 150 1000 120 120 Average Overall: Lagoon Influent 820 Lagoon Effluent 196 Pond Effluent 182 745 35 31 1420 580 550 1290 140 150 7-27 to 8-17: Lagoon Influent 810 Lagoon Effluent 185 Pond Effluent 180 570 9 12 1410 640 640 ------- 49 Table 14 AVERAGE PERCENT REDUCTIONS Parameter Total Solids Total Volatile Solids Suspended Solids Volatile Suspended Solids Total Phosphate Total Kjeldahl Nitrogen Total Organic Carbon Dissolved Organic Carbon COD, Total COD, Dissolved BOD, Total BOD, Dissolved Overall 7-27 to 8-17 Aerated Lagoon 20 48 -71 -132 9 7 66 91 59 82 76 95 Lagoon & Polishing Pond 22 51 -53 -110 15 17 69 92 62 89 78 96 98.4 98 ------- |