<>EPA
             United States
             Environmental Protection
             Agency
                 Office of Mobile Source Air Pollution Control
                 Emission Control Technology Division
                 2565 Plymouth Road
                 Ann Arbor, Michigan 48105
EPA 460/3-88-006
May 1988
             Air
Intake System  Deposits
and Gasoline/Alcohol Blends

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                                 EPA 460/3-88-006
Intake System Deposits and
  Gasoline/Alcohol  Blends
                  by

            Sherrill F. Martin

        Southwest Research Institute
            6220 Culebra Road
         San Antonio, Texas 78284

          Contract No. 68-03-3353
          Work Assignment B-2

     EPA Project Officer: Craig A. Harvey


              Prepared for

   ENVIRONMENTAL PROTECTION AGENCY
  Office of Mobile Source Air Pollution Control
     Emission Control Technology Division
           2565 Plymouth Road
        Ann Arbor, Michigan 48105
               May 1988

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This report is issued by the Environmental Protection Agency to report technical
data of interest to a limited number of readers.  Copies are available free of charge
to Federal employees, current contractors and grantees, and nonprofit organizations
- in limited quantities - from the Library  Services Office, Environmental Protection
Agency, 2565 Plymouth Road, Ann Arbor,  Michigan 48105.
This report was furnished to the Environmental Protection Agency by Southwest
Research Institute, 6220 Culebra Road,  San Antonio, Texas, in fulfillment of Work
Assignment No. B-2  of Contract  68-03-3353.   The  contents of  this report  are
reproduced  herein as received from  Southwest Research Institute. The opinions,
findings, and conclusions expressed are those of the author and  not necessarily those
of the Environmental Protection Agency.  Mention of company or product names is
not to be considered as an endorsement by the Environmental Protection Agency.
                       Publication No. EPA 460/3-88-006
                                      ii

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                                 FOREWORD
     This report covers the effort under Work Assignment No. B-2 of EPA Contract
68-03-3353, performed for the Emission Control Technology Division, Environmental
Protection Agency,  2565 Plymouth Road, Ann Arbor, Michigan 48105.  The EPA
Contracting Officer  was Mr. E.  M. Hennessey, and  the Project Officer was Mr.
Craig A. Harvey.

     The Southwest Research  Institute  Project Leader was  Sherrill F. Martin.
Charles T. Hare, Project Manager,  was involved in fiscal negotiations concerning
this work assignment, and Charles M. Urban was involved in technical development
of the test  plan.  The  project  was performed  during the period September, 1986
through August, 1987 and was identified as SwRI Project 08-1193-002.
                                      111

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                                  ABSTRACT
     Six vehicles, four of them ethanol blend-fueled and two gasoline-fueled,  were
examined for intake system  deposits.  The engines were partially disassembled,
photographs  were taken,  and deposits were evaluated  by  a  professional rater.
Elemental analysis was made of the intake valve deposits.
                                      IV

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                            TABLE OF CONTENTS

                                                                        Page

FOREWORD                                                              iii

ABSTRACT                                                              iv

LIST OF FIGURES                                                        vi

LIST OF TABLES                                                         vii

I.    SUMMARY                                                         1

IL   INTRODUCTION                                                    3

IIL  TEST PLAN                                                         5
     A. Test Plan                                                        5
        1.  Task 1 - Arrange for Test Vehicles and Inspection
            Capability                                                    5
        2.  Task 2 - Inspection and Parts Replacement                       6
            a.  Task 2 A - Engines                                          6
            b.  Task 2B - Fuel Tank                                        6
        3.  Task 3 - analysis
     B. Vehicles                                                         7
     C. Blend Fuel                                                       8

IV.  DISASSEMBLY AND INSPECTION                                     9

V.   DEPOSIT RATINGS                                                 17
     A. Engine  Components                                              20
        1.  Intake Valves
        2.  Combustion Chambers
        3.  Intake Manifold Runners and Intake Ports                       18
        4.  Piston Crowns                                                19
        5.  Carburetor Bores                                             19
        6.  Miscellaneous Items                                           19
     B. Fuel Tanks                                                      20

VL  ANALYSIS OF VALVE DEPOSITS                                     21

VH.  DISCUSSION OF PROGRAM RESULTS                                23

APPENDICES
     A. Vehicle Information
     B. Rater's Reports
     C. Fuel Additive Analysis

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                              LIST OF FIGURES




Figure                                                                    gage




   1        Intake Valves, Ford Escorts                                        10




   2        Intake Valves, Plymouth Reliants                                  11




   3        Cylinder Heads, Plymouth Reliants                                 12




   4        Typical Cylinder Head, Ford Escorts                               13




   5        Intake Manifolds, Plymouth Reliants                               14




   6        Carburetor Bores, Plymouth Reliants                               15




   7        Fuel Tanks, Ford Escorts                                          16
                                     VI

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                               LIST OF TABLES






Table                                                                    Page




  1        Deposit Rating Summary                                         1




  2        Test Vehicles                                                   7




  3        Ratings of Intake Valves                                        17




  4        Ratings of Combustion Chambers                                18




  5        Ratings of Manifold Runners                                    18




  6        Ratings of Intake Ports                                         18




  7        Ratings of Piston Crowns                                       19




  8        Ratings of Carburetor Bores                                    19




  9        Ratings of Miscellaneous Items                                  20




  10       Elemental Analysis of Valve Deposits                            22
                                      VII

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                                 L SUMMARY
     Six vehicles, three Ford Escorts and three Plymouth Reliants, were borrowed
from the State of Minnesota for examination of their  intake system deposits.  Two
vehicles of each make had been operated almost exclusively on a 10% ethanol blend
available  at fleet headquarters, while  the  third  had been  fueled  with gasoline
purchased on the  road.  The average age of the vehicles was five years, and the
average odometer reading was 63,000 miles.

     The vehicles were transported to Southwest Research Institute, San Antonio,
Texas, for examination.  Cylinder heads, intake manifolds, and valves were removed.
Fuel tanks were also removed and cut open for inspection.

     Preliminary  observations showed that one  of the  blend-fueled  Reliants  had
extreme deposits  on the intake valves.  The other blend-fueled Reliant also showed
very heavy valve deposits, but not to the extreme extent  of the first.  The gasoline-
fueled Reliant  had deposits which were typical of a vehicle of its age and mileage.
One of  the blend-fueled Escorts had  heavier intake valve deposits than the other  two
Escorts.  Other components showed either the same  trend to a lesser degree or
minimal differences.  The rater's report is summarized in  Table 1.  Higher numerical
ratings  mean better condition or less severe deposits.
                    TABLE 1. DEPOSIT RATING SUMMARY
   Vehicle/Fuel       Valves

Ford Escort
 Gasoline               7.6
 Blend, avg.             6.7

Plymouth Reliant
 Gasoline               6.3
 Blend, avg.             4.2
Manifold
Runners
  8.2
  8.6
  8.0
  7.5
Intake
 Ports
  8.0
  8.3
  9.2
  7.0
EGR
Line
 8.0
 8.0
 6.0
 5.2
Carburetor
  7.3
  6.8
  7.0
  4.2
      An  elemental analysis of  the  deposits found  on  the intake  valves was
conducted.  Sulfur, iron, copper, and zinc appear  to  correlate with  type  of fuel.
Magnesium, aluminum, phosphorus, potassium, iron, and nickel showed  correlation
with vehicle make.

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                              IL INTRODUCTION
     On September 11, 1986, Work  Assignment No.  B-2,  entitled, "Intake  System
Deposits and Gasoline/Alcohol Blends," was authorized by  the EPA Contracting
Officer for contract 68-03-3353.  The objective  of  this  work assignment  was  to
determine   any  differences  in  deposit-forming   tendencies  of  gasoline   versus
gasoline/alcohol  blends, in vehicles  that have use these fuels  over an  extended
period of time in typical everyday driving.

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                                 BO.  TEST PLAN
      This section provides the test plan that  was to be followed and describes the
vehicles used in the work assignment. It also describes what is known about the fuel
used in the vehicles.

      A.   Test Plan

           The test plan  was divided into three major parts.  They are described in
the following three sub-sections.

           1.   Task 1  - Arrange for Test Vehicles and Inspection Capability

               Each of the potential candidate fleets  of vehicles listed in Table 1 of
the Appendix A "Statement of Work" (S.O.W.) will be contacted.  Contact will also
be made with other potential sources of vehicles, primarily local sources, if any such
fleets are located.  Vehicle selection (automobiles, small vans, or pickups) will be
based on the criteria  given under Task 1 in the S.O.W.  Following identification of
potentially  available  vehicles   that   apparently  meet   the  required  criteria,
verification  of their operating history will be  obtained.  It is anticipated that such
verification  will require  on-site visits to inspect the vehicles and the records.  Only
vehicles having adequate operating records as required in Tasks 1  and  2A of  the
S.O.W. will be considered for final selection.  As  required, a maximum of 40  hours
will  be expended in identifying  potentially  available  vehicles and  in  making
preliminary  provisions for performing  the Task 2  inspections.  At  that  time,  the
status will be reported verbally to the Project Officer. If conditions are such that a
Project Officer decision on continuation appears  appropriate, this decision will be
requested.

               In the  event  that all required information concerning  the  vehicles is
readily provided by the vehicle sources, it will be included in the verbal report to
the Project Officer.   As  previously stated, however, it is anticipated that  a visit will
be required to each of the sources of the tentatively selected vehicles.   Such site
visits are  not included in and will be in addition  to the previously stated 40 hours.
Visits to  each source  of vehicles  could be required,  two are assumed for planning
purposes.

               It is planned  to arrange for transport of  the vehicles  to SwRI for
inspection, but potential for on-site vehicle  inspection will be discussed  with  the
sources.   Conducting the inspections  at  SwRI  will generally be more efficient,
provide  for  better  technical  control,  and enable better  safety  precautions  when
working with the fuel tanks.   In  summary, more  reliable data will  be obtained at
lower costs.   Other than reimbursing the vehicle  supplier  for the cost of renting a
replacement vehicle,  no provisions  are included for  any compensation or  financial
incentives to the suppliers of the vehicles.

               The Project Officer will be  notified of the vehicles selected, and his
approval will be obtained prior to continuation  of the project.  If we are dealing with
fleets operated by government organizations, limited assistance by  EPA personnel
(introductions to fleet managers,  interagency  cooperation requests,  etc.) may also
be requested to find vehicles.

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              This planned  effort is based on  a total  of six vehicles, two having
operated on gasoline and four on gasoline-alcohol blends.  Depending on the actual
effort involved  in locating, obtaining, and evaluating the vehicles, the total number
of vehicles could increase or decrease from the planned number.

          2.  Task 2 - Inspection and Parts Replacement

              Information listed under Task 2A of the S.O.W. will be recorded for
each vehicle  inspected.  The information related to source and operation of the
vehicles will generally be obtained in Task 1, prior to final selection of the vehicles.
Component inspections will  be conducted by  a qualified rater in accord with  CRC
rating procedures, where applicable.   For any components or  requirements not
covered by a  procedure, an  existing  procedure considered most appropriate will be
adapted.  Tentative inspection methods for use in this work assignment are listed in
Appendix B.

              a.   Task 2 A - Engines

                   Engine components listed under  Task 2A of the  S.O.W.  will be
inspected.   These  inspections will include the  following criteria, as appropriate:
deposits, wear, cracks, surface texture and discoloration.

                   It is planned to remove the carburetor, intake  manifold, and the
cylinder head(s). In addition, it will generally be necessary to remove the EGR valve
and the intake and exhaust valves to  conduct the requested inspections.  Any valves
with  an  "unusual" amount  of deposit  build-up  or  erosion  will  be replaced, as
described under Task  2A of the  S.O.W.   Any "unusual" deposit build-up or other
characteristics apparent on other components will be photographed and/or samples
taken as appropriate and practical. Replacement of components,  other than valves
as previously described,  will be done  only when  necessary,  or  when  deemed
appropriate based  on the severity of deposits or other characteristics.

              b.   Task 2B - Fuel Tank

                  The fuel  tank  will be removed from  each vehicle and replaced
with a new fuel tank.  The procedure to be followed for inspecting the in-use  fuel
tanks will be as follows:

                  (1)   Drain fuel  tank and  remove from  vehicle (if inspection
                       preparation is not to proceed at that time, replace several
                       gallons of the drained  fuel and seal all fuel tank openings).

                  (2)   Drain, or otherwise remove, all liquid fuel from the tank.

                  (3)   Purge the tank with  nitrogen, or other  appropriate inert
                       gas,  until essentially all fuel vapors  are removed from the
                       tank.

                  (4)   While still flowing the purge gas, cut open the fuel tank.

                  (5)   Inspect the  tank  in  accord  with  the requirements  under
                       Task 2B of the S.O.W.

                  NOTE:  Steps 2 through 5 will normally be completed during an
                          8-hr work shift, and in no case  will the elapsed time
                          exceed 24 hours.

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          3.   Task 3 - Analysis

              Selected  deposit  samples will be  analyzed to  determine amount,
composition, and physical characteristics.  The number of samples and the specific
analyses will be determined in coordination with the Project Officer.  The allocation
in this  work plan is  for a reasonable  number of  analyses  on up to four samples,
assuming that a total of  six vehicles are inspected in detail.

              The data  collected under all tasks will be reviewed for any apparent
relationship between the fuel(s)/additive(s) used and  the observed condition of the
inspected components.

      B. Vehicles

          The six vehicles used  in the program were  obtained from  the  Minnesota
Department of Administration.  Basic information is  listed  in Table 2. The  blend-
fueled vehicles  were from the Capitol District of the Minnesota DOA.  They were
principally fueled at  the fleet headquarters at St. Paul.  Occasional "on-the-road"
fueling  would have occurred, which would cause a small percentage of operation on
very low ethanol content fuel.
                           TABLE 2.  TEST VEHICLES
Number

SC239
SC205
SC453

C83
C202
C232
  Make

Ford
Ford
Ford

Plymouth
Plymouth
Plymouth
 Model

Escort
Escort
Escort

Reliant
Reliant
Reliant
Year     Mileage       Fuel
1982
1981
1981

1983
1983
1982
62,000
61,000
68,000
57,000
75,000
55,000
Gasoline
Blend
Blend
Gasoline
Blend
Blend
Engine

 1.6L
 1.6L
 1.6L

 2.2L
 2.2L
 2.2L
           The gasoline-fueled vehicles were headquartered in other cities without
fleet fueling facilities.  Therefore, their  fueling history would be typical of other
vehicles operating in Minnesota, with gasoline being purchased  at  retail from  a
variety of suppliers.

          The vehicles were taken from service with an average of 63,000 miles on
the odometer.  Most, if not all,  of the vehicles were about to be  auctioned by the
fleet.  The Ford Escorts were 1981  and  1982 models, while the Plymouth Reliants
were of 1982 and 1983 vintages.

          Examination  of  the maintenance records showed  no work which  would
affect the purposes of this assignment.  One of the Ford Escorts, number SC205, had
undergone  a camshaft repair at 39,000 miles.  Because this vehicle has an overhead
cam engine, it is possible to remove the camshaft without disturbing the valves. No
fuel tanks had  been  replaced.   No specific oil consumption records were kept.
However, excessive oil use would have been reported.

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      C. Blend Fuel

          The blend  fuel supplied to the Minnesota  DOA is provided on a yearly
contract basis. Gasoline and ethanol are purchased by the contractor from different
suppliers  and blended in the tank  truck.   The target blend is 10% ethanol.   No
corrosion inhibitor or detergent  package is  added to the blend by  the  contractor.
However, analysis of the fuels indicates that an additive package was present in the
blend fuels.

      The producer of most of  the ethanol used in  the  Minnesota  Fleet blend
confirmed that a detergent package was added to the ethanol starting early in the
summer of 1986.  It had been standard practice to include a corrosion inhibitor prior
to that  time.  Therefore, the blend fueled vehicles would only have been exposed to
the additional detergent for roughly nine months prior to this study.  This would not
be expected to clean up deposits existing before that time.

The additive analysis is included  as Appendix C.  Note that the blend fuels (the  last
four listed) all indicated higher additive content than the two gasoline samples.

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                     IV. DISASSEMBLY AND INSPECTION
     In order to perform the inspections required by the test plan, the carburetor,
manifolds, cylinder head,  and EGR lines  were removed  from  each engine.  In
addition, the valves were removed from the heads to  allow inspection and rating of
the stem  side of the valve heads.   All fuel tanks were removed, drained, and cut
open for inspections.

     Figures  1  through 7  are photographs of the  major components which  were
inspected.  First shown are the  intake valves.  The R.eliants showed the widest
variation  in deposits, ranging  from normal  to extremely heavy.  Valve deposits on
the Escorts ranged from light  to  moderate.  In both  cases, the vehicles which had
been fueled on gasoline had the lightest deposits.  The carburetors, particularly in
the area under the  secondary throttle,  showed similar trends.  Other components on
the Reliants fell in line. The remaining components on the Escorts showed no  clear
correlation with the deposits on the valves and carburetors.

     Five of the  fuel  tanks looked like new inside.  The  sixth, from one of the
blend-fueled Escorts, was free  of corrosion, but had a dull gray film inside.

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                SC 239
                SC 205
                SC453
FIGURE 1. INTAKE VALVES, FORD ESCORTS
                  10

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JLJLXJL
       C83
       C202
       C232
FIGURE 2. INTAKE VALVES, PLYMOUTH RELIANTS
        11

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FIGURE 3.  CYLINDER HEADS, PLYMOUTH RELIANTS
                      12

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FIGURE 4. TYPICAL CYLINDER HEAD, FORD ESCORTS
                        13

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               SC232 CLOSE UP
FIGURE 5. INTAKE MANIFOLDS, PLYMOUTH RELIANTS
                     14

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                       C83
                       CZ02
                       C232
FIGURE 6. CARBURETOR BORES, PLYMOUTH RELIANTS
                         15

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FIGURE 7.  FUEL TANKS, FORD ESCORTS

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                             V.  DEPOSIT RATINGS
      This section discusses the report of the rater on his examination of the engine
components (Tables 3 through 9).  These ratings involve subjective comparisons  of
the components to photographs and charts in  the CRC Manual.  Ratings are on a
scale of 0  to  10, with 10 being the highest quality (best condition)  rating.   Quality
control is maintained by regular attendance of the rater at CRC rating symposiums.

      A.   Engine Components

           1.    Intake Valves

                Within  each vehicle make grouping, the lightest deposits occurred
on the gasoline-fueled vehicle. In addition to being heavier, the valve deposits were
quite variable in the blend-fueled vehicles.  For instance, among the Escorts, vehicle
C239 (gasoline)  and vehicle C453 (blend) had almost identical valve deposit ratings,
but vehicle C205 (blend) was  significantly worse.  For the  Reliants, vehicle  C202
(blend)  had deposits  which  were intermediate between those  of vehicle  C83
(gasoline) and  C232 (blend).

                It is inconceivable that the deposits on the intake valves in vehicle
C232 had no effect on performance.  The fleet manager confirmed, that  one vehicle
had difficulty climbing  the ramps onto the vehicle carrier, and we suspect that  it
was C232.
                   TABLE 3.  RATINGS OF INTAKE VALVES
                                	Cylinder
      Vehicle        Fuel         123
      SC239        Gasoline      7.6      7.6     7.6      7.6
      SC205        Blend         5.7      5.5     7.0      6.0
      SC453        Blend         7.4      7.6     7.1      7.4

      C83          Gasoline      5.7      6.9     6.8      5.7
      C202         Blend         5.8      5.8     4.8      5.1
      C232         Blend         3.5      3.5     2.0      3.5
          2.  Combustion Chambers

              All  of  the  Escort  cylinder  heads were visually  similar  in the
combustion chamber areas, therefore only one photograph  is shown.  The ratings
confirm this similarity.  The Reliant heads displayed slight visual differences, but
the rater's report indicates minimal practical differences.  Note that in the head
from  vehicle C232, some deposits can be  seen caked in the area behind the intake
valve, which is not part of the combustion chamber.
                                       17

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             TABLE 4.  RATINGS OF COMBUSTION CHAMBERS
                                         Cylinder
     Vehicle

     SC239
     SC205
     SC453

     C83
     C202
     C232
Fuel
Gasoline
Blend
Blend
Gasoline
Blend
Blend
Intake Manifold
1
9.0
8.9
8.5
8.5
8.3
8.0
Runners
2
8.8
8.9
8.3
8.1
8.2
7.9
and Intake
3
8.4
8.2
8.8
8.1
8.1
7.8
Ports
4
8.6
7.9
8.7
8.2
8.0
7-9

                                               7.9
         3.

             With the exception of Reliant C232, the intake manifold runners and
intake  ports  showed no correlation  with  fuel  or  vehicle.   Vehicle C232  rated
comparatively low, in line with the valve ratings.
               TABLE 5. RATINGS OF MANIFOLD RUNNERS
     Vehicle

     SC239
     SC205
     SC453

     C83
     C202
     C232
Cylinder
Fuel
Gasoline
Blend
Blend
Gasoline
Blend
Blend
1
8.4
8.0
9.0
8.0
9.0
7.4
2
8.4
8.0
9.1
8.0
9.1
6.2
3
8.0
8.0
9.1
8.0
8.9
5.5
4
8.0
8.0
9.2
8.0
8.6
5.6
                 TABLE 6. RATINGS OF INTAKE PORTS
     Vehicle

     SC239
     SC205
     SC453

     C83
     C202
     C232
  Fuel
                                        Cylinder
Gasoline
Blend
Blend

Gasoline
Blend
Blend
1
8.0
8.2
9.4
9.2
7.9
6.5
2
8.0
8.2
8.4
9.0
8.6
4.6
3
8.0
7-9
7.8
9.0
8.2
3.5
4
8.0
8.0
8.5
9.4
8.8
7.9
8.0
8.
8.
9.2
8.4
5.6
                                    18

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          4.  Piston Crowns

              Piston crowns showed very little variation from vehicle to vehicle.
Vehicle C232 again deviated on the low rating side compared to the others.


                  TABLE 7. RATINGS OF PISTON CROWNS


                                	Cylinder	
      Vehicle        Fuel
      SC239        Gasoline      7.8      8.2     8.2      8.5
      SC205        Blend         8.0      8.3     8.0      7.9
      SC453        Blend         8.0      8.4     8.5      8.0

      C83          Gasoline      8.3      8.5     8.5      8.0
      C202         Blend         8.2      8.2     8.1      8.1
      C232         Blend         7.8      7-9     8.0      7.5
           5.   Carburetor Bores

                The rater  was asked to evaluate  only the area of the carburetor
bores below the throttle plate.  All were  fairly  normal except  for  C232.  The
extremely low rating of the C232 carburetor requires some explanation.  From the
photograph, Fig. 6,  there appears  to be very heavy deposits  in the bores  of the
spacer below  the throttle body. This material is actually a rubber-like  lining which
was present in this  1982 Reliant, but not in either of the others, which were  both
1983 models.  The rater treated this liner material as a deposit.
                TABLE 8.  RATINGS OF CARBURETOR BORES
                                               Barrel
                     Vehicle       Fuel        1      \
                     SC239      Gasoline     7.5    7.1
                     SC205      Blend        6.2    6.4
                     SC453      Blend        7.2    7.4

                     C83        Gasoline     7.5    6.5
                     C202       Blend        7.5    5.4
                     C232       Blend        3.1    0.8
          6.   Miscellaneous Items

              For the Escorts,  the intake manifold inlet, EGR port, and EGR line
showed no trends with respect  to  fuel.  In the Reliants, C232 again showed the
heaviest deposits, while the other blend-fueled Reliant had heavier deposits than the
gasoline-fueled vehicle in the EGR port and line.
                                      19

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              TABLE 9.  RATINGS OF MISCELLANEOUS ITEMS
             Vehicle

             SC239
             SCZ05
             SC453

             C83
             C202
             C232
  Fuel
Gasoline
Blend
Blend

Gasoline
Blend
Blend
 Intake
Manifold
  Inlet

  8.9
  8.5
  9.2

  9.5
  9.5
  7.7
EGR
Line

 8.0
 8.0
 8.0

 6.0
 5.5
 5.0
     B.  Fuel Tanks

         The  rater's  reports on  the  fuel tanks (see Appendix B) confirmed the
evidence of the photographs.  All were in good to very good condition, with one of
the Escort blend-fueled tanks (SC453) having a gray  film in the bottom half.
                                     20

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                      VL  ANALYSIS OF VALVE DEPOSITS
     One "average" looking intake valve was selected from each of four engines.
These  engines included two of each vehicle and two of each fueling history.   An
elemental analysis was made of deposit samples removed from each of  these four
valves  (Table  10).   Elements  other than  hydrogen,  carbon,  and  nitrogen  were
determined by the X-ray fluorescence method.

     The ratio of hydrogen to carbon  was highest  in the engine  with the extreme
deposits, indicating the presence of more organic material.   Nitrogen, magnesium,
aluminum, phosphorus, potassium,  iron,  and nickel appear  to correlate more with the
make of vehicle  than with  fuel type.   Sulfur, iron, copper, and zinc show some
correlation with fuel type.  The difference between  100% and the  total shown would
be mostly oxygen.
                                       21

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                                  TABLE 10.  ELEMENTAL ANALYSIS OF VALVE DEPOSITS
Vehicle
Escort
SC239
SC205
Reliant
C83
C232
Fuel

Gasoline
Blend

Gasoline
Blend
H

4.2*
4.5

4.9
6.5
C

53.4*
63.8

62.1
65.4
N

0.95*
1.80

3.19
3.47
Mg

1.7
2.6

2.9
4.2
Al

0.12
0.10

0.04
0.04
Si

0.19
0.13

0.10
0.16
P

1.8
2.0

5.4
3.5
S

5.7
4.6

5.8
4.4
YL

0.57
0.29

0.08
0.12
Ca Cr

1.2
0.9 0.04

0.9 --
1.5
Fe

1.0
0.51

0.24
0.21
Cu

0.30
0.13

0.22
0.10
Ni Zn

0.08 2.4
0.04 2.0

— 4.5
— 2.7
Pb

1.2
0.5

0.50
0.71
Total

74.8
84.0

90.9
93.0
All values percent by mass.
* Marginal sample quantity.

-------
                   VIL DISCUSSION OF PROGRAM RESULTS
     On the basis of a limited sampling from one fleet of vehicles, there is evidence
that vehicles being  operated on ethanol-gasoline blends can develop heavier deposits
in the  intake system  than those operated on generally-available gasolines.   The
reason for these heavier deposits is not clear from  the present study.  The ethanol
producer began adding a detergent package shortly before these vehicles were pulled
from service. This would not have been expected to clean up pre-existing deposits.
The effect on deposits is mainly limited to the  intake system, because the effect
observable in the  combustion chambers  was minimal.   There was no corrosion
evident in the fuel tanks of any of the vehicles examined.
                                      23

-------
     APPENDICES









A. VEHICLE INFORMATION




B. RATER'S REPORTS




C. FUEL ADDITIVE ANALYSIS

-------
     APPENDIX A




VEHICLE INFORMATION

-------
           VEHICLE INFORMATION
Fleet ID No.




Make and Model




Model Year




Odometer Reading




V.I.N.




Engine Size & Cylinders




Engine Family




Transmission Type




Carburetor No.




Emission Controls




Fuel
SCZ39




Ford Escort




1982




62194




2FABPO62XCX240987




1.6Lx4




Label Missing




Automatic




E2EEL1A 2E17




EGR/PMP/OXD/3WY




Gasoline
                     A-2

-------
           VEHICLE INFORMATION
Fleet ID No.




Make and Model




Model Year




Odometer Reading




V.I.N.




Engine Size & Cylinders




Engine Family




Transmission Type




Carburetor No.




Emission Controls




Fuel
SC205




Ford Escort Wagon




1981




61307




1FABPO82BW276552




1.6Lx4




1.6AP




Automatic




E1EE NA 1F2




EGR/PMP/OXD/3WY




10%  Ethanol Blend
                     A-3

-------
           VEHICLE INFORMATION
Fleet ID No.




Make and Model




Model Year




Odometer Reading




V.I.N.




Engine Size & Cylinders




Engine Family




Transmission Type




Carburetor No.




Emission Controls




Fuel
SC453




Ford Escort Wagon




1981




68185




1FABPO820BW275464




1.6Lx4




1.6 AP




Automatic




E1EE  NA 1F1




EGR/PMP/OXD/3WY




10% Ethanol Blend
                     A-4

-------
           VEHICLE INFORMATION
Fleet ID No.




Make and Model




Model Year




Odometer Reading




V.I.N.




Engine Size & Cylinders




Engine Family




Transmission Type




Carburetor No.




Emission Controls




Fuel
C83




Plymouth Reliant




1983




57470




1P3BP26CXDF195447




2.2Lx4




Label Missing




Automatic




40010-2 42807086 0263




EGR/PMP/ODX/3CL




Gasoline
                     A-5

-------
           VEHICLE INFORMATION
Fleet ID No.




Make and Model




Model Year




Odometer Reading




V.I.N.




Engine Size & Cylinders




Engine Family




Transmission Type




Carburetor No.




Emission Controls




Fuel
C202




Plymouth Reliant




1983




74626




1P3BP26C6DF195423




2.2Lx4




DCR2.2V2HAC3 DCRKA




Automatic




40010-2 4287086 0203




EGR/PMP/ODX/3CL




10% Ethanol Blend
                    A-6

-------
           VEHICLE INFORMATION
Fleet ID No.




Make and Model




Model Year




Odometer Reading




V.I.N.




Engine Size & Cylinders




Engine Family




Transmission Type




Carburetor No.




Emission Controls




Fuel
C232




Plymouth Reliant




1982




54927




1P3BP26B3CF218590




2.2Lx4




CCR2.2V2HNLX CCRKA




Automatic




R9019 4227293 1042




EGR/PMP/OXD/3 CL




10% Ethanol Blend
                     A-7

-------
  APPENDIX B



RATER'S REPORTS

-------
                      INDUCTION SYSTEM RATING SHEET
 TEST NO.:  SC-239              DATE:  05-26-87              RATER:   G.  TSCHIRHART

                           COMBUSTION CHAMBERS

No. 1



Area
50%
30%
20%
Rate
9.5
9.0
8.0
Merit
4.75
2.70
1.60
No. 2 Area
20%
50%
30%
Rate
9.5
9.0
8.0
Merit
1.90
4.50
2.40
 Total	9.05        Total	8.80
No. 3



Area
10%
20%
70%
Rate
9.5
9.0
8.0
Merit
0.95
1.80
5.60
No . 4 Area
30%
20%
50%
Rate
9.5
9.0
8.0
Merit
2.85
1.80
4.00
Total	8.35        Total	8.65


                          Comments;  Avg. 8.71
                                 VALVES
                              INTAKE VALVES

No._           Rate           No.           Rate           No.           Rate

_i_           7.6             2            7.6             3            7.6

 4            7.6

                         Comments:   Avg.  7.60


                             EXHAUST VALVES

No-           Rate           No.           Rate           No.          Rate
 1_           8.0             2            7.8             3           7.9

 4            7.8

                         Comments:   Avg. 7.90
                                     B-2

-------
                      INDUCTION SYSTEM RATING SHEET
TEST NO.:  SC-239
                    DATE:  05-26-87
                                   RATER:   G. TSCHIRHART
                             MANIFOLD RUNNERS

No. 1
Total. ..

Area
40%
60%

Rate
9.0
8.0

Merit
3.60
4.80
...8.40

No. 2 Area
40%
60%
Total 	

Rate
9.0
8.0
•
Merit
3.60
4.80
...8.40
No. 3
Area
Rate
Merit
No. 4
Area
Rate
Merit
           100%
          8.0
          8.00
                      100%
                     8.0
                    8.00
Total	8.00
                               Total	8.00
                            Comments:   8.20
                           HEAD PORTS - INTAKE
No. 1
Area
Rate
Merit
No. 2
Area
Rate
Merit
           100%
          8.0
          8.00
                      95%
                       5%
                     8.0
                     7.5
                    7.60
                    0.38
Total	8.00
                               Total	7.98
No. 3
Area
Rate
Merit
No. 4
                                Area
                                                    Rate
                    Merit
           95%
            5%
          8.0
          7.5
          7.60
          0.38
                      100%
                     8.0
                    8.00
Total	7.98
                                Total	8.00
                          Comments:    Avg.  7.99
                                   B-3

-------
TEST NO.  SC-239
INTAKE MANIFOLD;  8.9 Carbon Rating

EGR PORT INTO INTAKE SYSTEM;  7.5 Carbon Rating

EGR LINE;  8.0 Carbon Rating

PISTON CROWN;  1 - 7.8
               2 - 8.2
               3 - 8.2
               4 - 8.5
            Avg.  8.18
CYLINDER BORE;  1
                2
                3
                4 -
        Good condition, no apparent distress.
        Good condition, no apparent distress.
        Good condition, no apparent distress.
        Good condition, no apparent distress.
FUEL TANK:
Fuel tank is in very good condition.  No signs of rust or varnish.
Trace amount of foreign material in bottom of tank.

9.80 Sludge Rating
9.80 Varnish Rating
                                   B-4

-------
     CARBURETOR MAKE.
. BBLS.
      USE SEPARATE SHEET FOR:  PRIMARY BBLS.
                  Appendix C
 RECOMMENDED CARBURETOR RATING FORM
_ DATE  05-26-87 TEST #  SC-239   RATERG.  Tschirhart
	  SECONDARYBBLS	
DEPOSIT DESCRIPTION
Clean (no visible deposits)
* 10.0 to 9.0
Light discoloration
* 9.0 to 6.0
Definite (dark) discoloration
*6.0to< .001 "thick
Deposit < .015" > .001" thick
Deposit > .015" thick

(1)
Linkage Barrel
% Area x
(2)
Left
Side

1007o



100%
(1)
Right
Side

100%



100%
Depth
Factor

10.0
7.5
5.0
2.5
0
Total
Deposit
Number
Deposit
No.
Left
Side

7.50


0
7.50
Right
Side

7.50


0
7.50
Non-Linkage Barrel
% Area x
Left
Side

95%
5%


1 00%
Right
Side

70%
30%


100%
Depth
Factor

10.0
7.5
5.0
2.5
0
Total
Deposit
Number
Deposit
No.
Left
Side

7.12
0.25

0
7.37
Right
Side

5.25
1.50

0
6.75
M
I
Ul
     % OF TOTAL AREA BELOW THROTTLE PLATE AVAILABLE FOR DEPOSIT (CRC Test Sleeves (3): 40% Left; 60% Right)
                                % Left Side = 100 x Left Depth   =	%;  % Right Side = 100 x Right Depth  =      %
                                                 Left + Right                             Left + Right
     FOR 2/4 BBL CARBURETORS: AVG RIGHT DEPOSIT NO. = 0.5 x (RIGHT LINKAGE BARREL + RIGHT NON-LINKAGE BARREL) = 7.12
                               AVG LEFT DEPOSIT NO.  = 0.5 x (LEFT LINKAGE BARREL + LEFT NON-LINKAGE BARREL) =  7 '.43
     CARBURETOR MERIT RATING = (Avg. Left Dep. No. x % Available Area) + (Avg. Right Dep. No. x % Available Area)
     Carburetor Merit Rating = (           x           ) + (           x            ) = (                     ) + (
     NOTES
     1.  The right side of the carburetor/sleeve is the one with idle fuel ports, transfer slot, and vac. ports.
        The linkage barrel is the barrel adjacent to the carburetor linkages.
     .2.  The left side of the carburetor/sleeve has no holes.
     3.  The CRC Carburetor Cleanliness Test Aluminum sleeve is considered to have 40% Left Side Available Area, 60% Right Side Available Area.
        *CRC Varnish Rating Scale

-------
                      INDUCTION SYSTEM RATING SHEET
TEST NO.:  SC-205              DATE:  05-26-87             RATER:  G.  TSCHIRHART
                           COMBUSTION CHAMBERS
No. 1

Area
20%
60%
20%
Rate
9.5
9.0
8.0
Merit
1.90
5.40
1.60
No. 2 Area
20%
60%
20%
Rate
9.5
9.0
8.0
Merit
1.90
5.40
1.60
Total	8.90        Total	8.90


No. 3	Area	Rate	Merit	 No. 4	Area	Rate	Merit

           30%       9.0       2.70                   80%       8.0       6.40
           60%       8.0       4.80                   20%       7.5       1.50
           10%       7.5       0.75

Total	8.25        Total	7.90

                          Comment s;  Avg.  8.49
                                 VALVES
                              INTAKE VALVES

No.           Rate           No.           Rate           No.           Rate

 1            5.7             2            5.5             3            7.0

 4            6.0

                          Comments:    Avg.  6.0
                             EXHAUST VALVES

No.           Rate           No.            Rate           No.          Rate

 1            7.5             2            7.5              3           7.5

 4            7.5

                          Comments:    Avg.  7.5
                                   B-6

-------
                      INDUCTION SYSTEM RATING SHEET


TEST NO.:  SC-205              DATE:   05-26-87          RATER:    G.  TSCHIRHART


                             MANIFOLD RUNNERS


No. 1	Area	Rate	Merit	No.  2	Area	Rate	Merit

           1007o      8.0       8.00                   1007=      8.0        8.00


Total	8.00        Total	8.00



No. 3      Area      Rate      Merit       No.  4       Area      Rate       Merit

           1007.,      8.0       8.00                   1007=      8.0        8.00


Total	8.00        Total	8.00


                          Comments:  Avg.  8.00


                           HEAD PORTS  - INTAKE



No. 1      Area      Rate      Merit       No.  2       Area      Rate     Merit

           207o       9.0       1.80                   207o        9.0      1.80
           807o       8.0       6.40                   807=        8.0      6.40


Total	8.20        Total	8.20
No. 3



Total . . .
Area
907o
57=
57=

Rate
8.0
7.5
7.0

Merit
7.20
0.38
0.35
...7.93
No. 4 Area
957»
57=

Total 	 ,
Rate
8.0
7.5


Merit
7.60
0.38

...7.98
                           Comments:    Avg.  8.08
                                     B-7

-------
TEST NO.  SC-205
INTAKE MANIFOLD;  8.5 Carbon Rating

EGR PORT INTO INTAKE SYSTEM;  7.0 Carbon Rating

EGR LINE;  8.0 Carbon Rating

PISTON CROWN;  1 - 8.0
               2 - 8.3
               3 - 8.0
               4 - 7.9
            Avg.  8.05
CYLINDER BORE;  1 - Good condition,  no apparent distress.
                2 - Good condition,  no apparent distress.
                3 - Good condition,  no apparent distress.
                4 - Good condition,  no apparent distress.

FUEL TANK;  Fuel tank is in very good condition.   No signs of rust or varnish.
            Trace amount of foreign  material in bottom of tank.

            9.80 Sludge Rating
            9.80 Varnish Rating
                                    B-8

-------
    CARBURETOR MAKE.
BBLS.
    USE SEPARATE SHEET FOR:  PRIMARY BBLS.
                  Appendix C
 RECOMMENDED CARBURETOR RATING FORM
_ DATE  05-26-87  JEST #  SC-205  RATER G.  Tschirhart
	  SECONDARY BBLS.	
DEPOSIT DESCRIPTION
Clean (no visible deposits)
* 10.0 to 9.0
Light discoloration
* 9.0 to 6.0
Definite (dark) discoloration
* 6.0 to < .001 "thick
Deposit < .015" > .001 "thick
Deposit > .01 5" thick

(1)
Linkage Barrel
% Area x
(2)
Left
Side


100%


100%
0)
Right
Side

95%
5%


100%
Depth
Factor

10.0
7.5
5.0
2.5
0
Total
Deposit
Number
Deposit
No.
Left
Side


5.00

0
5.00
Right
Side

7.12
.25

0
7.37
Non-Linkage Barrel
%Area x
Left
Side

60%
40%


100%
Right
Side

50%
50%


100%
Depth
Factor

10.0
7.5
5.0
2.5
0
Total
Deposit
Number
Deposit
No.
Left
Side

4.50
2.00

0
6.50
Right
Side

3.75
2.50

0
6.25
to
I
    % OF TOTAL AREA BELOW THROTTLE PLATE AVAILABLE FOR DEPOSIT (CRC Test Sleeves (3): 40% Left; 60% Right)
                               % Left Side = 100 x Left Depth   =	%;  % Right Side = 100 x Right Depth   =     %
                                                Left + Right                             Left + Right
    FOR 2/4 BBL CARBURETORS: AVG RIGHT DEPOSIT NO.  = 0.5 x (RIGHT LINKAGE BARREL + RIGHT NON-LINKAGE BARREL) = 6.81
                              AVG LEFT DEPOSIT NO.   = 0.5 x (LEFT LINKAGE BARREL + LEFT NON-LINKAGE BARREL) = 5.75
    CARBURETOR MERIT RATING = (Avg. Left Dep. No. x % Available Area) + (Avg. Right Dep. No. x % Available Area)
    Carburetor Merit Rating = (           x           ) + (           x            ) = (                      ) + (
    NOTES
    1.  The right side of the carburetor/sleeve is the one with idle fuel ports, transfer slot, and vac. ports.
       The linkage barrel is the barrel adjacent to the carburetor linkages.
    2.  The left side of the carburetor/sleeve has no holes.
    3.  The CRC Carburetor Cleanliness Test Aluminum sleeve is considered to have 40% Left Side Available Area, 60% Right Side Available Area.
                                              v
       *CRC Varnish Rating Scale

-------
                      INDUCTION SYSTEM RATING SHEET
TEST NO.:  SC-453              DATE:  05-26-87             RATER:  G.  TSCHIRHART

                           COMBUSTION CHAMBERS

No. 1



Area
10%
30%
60%
Rate
9.5
9.0
8.0
Merit
0.95
2.75
4.80
No. 2 Area
30%
70%

Rate
9.0
8.0

Merit
2.70
5.60

Total	8.50        Total	8.30
No. 3

Area
80%
20%
Rate
9.0
8.0
Merit
7.20
1.60
No. 4 Area
10%
50%
40%
Rate
9.5
9.0
8.0
Merit
0.95
4.50
3.20
Total	8.80        Total	8.65


                         Comments;  Avg. 8.56
                                 VALVES
                              INTAKE VALVES

No.           Rate           No.            Rate           No.            Rate

 1            7.4             2            7.6              3            7.1

 4            7.4

                          Comments:    Avg.  7.4
                             EXHAUST VALVES

              Rate           No.            Rate           No.           Rate

              7.5              2             7.5              3           7.5

              7.5

                          Comments:   Avg. 7.5
                                        B-10

-------
INDUCTION SYSTEM RATING SHEET
TEST NO.


No. 1
Total. . .

No. 3




No. 1
Tnl-fll

No. 3
Total 	
: SC-453 DATE: 05-26-87
MANIFOLD RUNNERS

Area Rate Merit No. 2
100% 9.0 9.00
	 9 . 00 Total 	

Area Rate Merit No. 4
30% 9.5 2.85
70% 9.0 6.30
	 9 . 15 Total 	
Comments: 9.12
HEAD PORTS - INTAKE

Area Rate Merit No. 2
1007o 9.4 9.40
	 9.40 Total 	

Area Rate Merit No. 4
807=, 8.0 6.40
107o 7.5 0.75
107o 6.5 0.65
	 7 . 80 Total . .
RATER: G.


Area Rate
307c 9.5
707o 9 . 0

Area Rate
407, 9 . 5
607o 9 . 0



Area Rate
5070 9.0
4070 8 . 0
107= 7 . 0

Area Rate
107o 9.5
507o 9.0
307o 8 . 0
10% 7 . 0
TSCHIRHART


Merit
2.85
6.30
9 15

Merit
3.80
5.40
. ..9.20



Merit
4.50
3.20
0.70
...8.40

Merit
0.95
4.50
2.40
0.70
...8.55
   Comments:   Avg. 8.54
              B-ll

-------
TEST NO.  SC-453
INTAKE MANIFOLD:  9.2 Carbon Rating

EGR PORT INTO INTAKE SYSTEM;  7.8 Carbon Rating

EGR LINE;  8.0 Carbon Rating

PISTON CROWN;  1 - 8.0
               2 - 8.4
               3 - 8.5
               4 - 8.0
            Avg.  8.22
CYLINDER BORE;  1
                2
                3
                4
Good condition, no apparent distress,
Good condition, no apparent distress,
Good condition, no apparent distress,
Good condition, no apparent distress,
FUEL TANK;  Fuel tank has trace amount of foreign material in bottom of tank.
            Tank is in good condition.  Bottom of tank has film like substance
            that is in the 4.5 range on the CRC Varnish rating scale.

            Top of tank    - 9.8 Sludge
            Bottom of tank - 9.8 Sludge
                                    B-12

-------
       *Non linkage throttle plate has  light  rust existence.


                                                              Appendix C
CARBURETOR MAKE
. BBLS.
USE SEPARATE SHEET FOR:  PRIMARY BBLS.
 RECOMMENDED CARBURETOR RATING FORM

_ DATE  05-26-87 JEST #  SC-453   RATER G.  Tschirhart-

	  SECONDARY BBLS	
DEPOSIT DESCRIPTION
Clean (no visible deposits)
* 10.0 to 9.0
Light discoloration
* 9.0 to 6.0
Definite (dark) discoloration
*6.0 to < .001 "thick
Deposit < .015" > .001 "thick
Deposit > .015" thick

(1)
Linkage Barrel
% Area x
(2)
Left
Side

100%



100%
(1)
Right
Side

80%
20%


100%
Depth
Factor

10.0
7.5
5.0
2.5
0
Total
Deposit
Number
Deposit
No.
Left
Side

7.50


0
7.50
Right
Side

6.00
1.00

0
7.00
Non-Linkage Barrel
% Area x
Left
Side

90%
10%


100%
Right
Side

100%



100%
Depth
Factor

10.0
7.5
5.0
2.5
0
Total
Deposit
Number
_ Deposit
No.
Left
Side

6.75
0.50

0
7.25
Right
Side .

7.50


0
7.50
% OF TOTAL AREA BELOW THROTTLE PLATE AVAILABLE FOR DEPOSIT (CRC Test Sleeves (3): 40% Left; 60% Right)

                           % Left Side = 100 x Left Depth  =	%;  % Right Side = 100 x Right Depth   =      %
                                            Left + Right                             Left + Right

FOR 2/4 BBL CARBURETORS: AVG RIGHT DEPOSIT NO. = 0.5 x (RIGHT LINKAGE BARREL + RIGHT NON-LINKAGE BARREL) = 7 . 25

                         AVG LEFT DEPOSIT NO.  = 0.5 x (LEFT LINKAGE BARREL + LEFT NON-LINKAGE BARREL) = 7 '.38

CARBURETOR MERIT RATING = (Avg. Left Dep. No. x % Available Area) + (Avg. Right Dep. No. x % Available Area)


Carburetor Merit Rating = (           x           ) + (           x           )=(                     ) + (

NOTES
1.  The right side of the carburetor/sleeve is the one with idle fuel ports, transfer slot, and vac. ports.
   The linkage barrel is the barrel adjacent to the carburetor linkages.

2.  The left side of the carburetor/sleeve has no holes.
3.  The CRC Carburetor Cleanliness Test Aluminum sleeve is considered to have 40% Left Side Available Area, 60% Right Side Available Area.

   *CRC Varnish Rating Scale

-------
INDUCTION SYSTEM RATING SHEET
TEST NO.: C-83 DATE: 05-25-87
COMBUSTION CHAMBERS

No. 1 Area Rate Merit No. 2
50% 9.0 4.50
50% 8.0 4.00
Total 	 8.50 Total. . .

No. 3 Area Rate Merit No. 4
107o 9.0 0.90
90% 8.0 7.20
Total 	 8.10 Total . . .
Comments: Avg. 8.22
VALVES
INTAKE VALVES
No. Rate No. Rate
1 5.7 2 6.9
4 5.7
Comment s : Avg . 6.3
EXHAUST VALVES
No. Rate No. Rate
1 7.5 2 7.5
4 7.5
RATER: G. TSCHIRHART


Area Rate Merit
10% 9.0 0.90
90% 8.0 7.20
	 8.10

Area Rate Merit
20% 9.0 1.80
80% 8.0 6.40
	 . 8 20



No. Rate
3 6.8



No. Rate
3 7.5

    Comments:    Avg.  7.5
             8-14

-------
                      INDUCTION SYSTEM RATING SHEET
TEST NO.:   C-83
                    DATE:  05-25-87
                                   RATER:   G. TSCHIRHART
                             MANIFOLD RUNNERS
No. 1
Area
Rate
Merit
No. 2
Area
                                                               Rate
                                                              Merit
           100%
          8.0
          8.00
                      100%
                     8.0
                    8.00
Total	8.00
                               Total	8.00
No. 3
Area
Rate
Merit
No. 4
Area
Rate
Merit
           100%
          8.0
          8.00
                      100%
                     8.0
                    8.00
Total	8.00
                               Total	8.00
                            Comments:   8.00
HEAD PORTS -

No. 1
T0f-.jl

No. 3
Total 	

Area
80%
20%

Area
70%
20%
10%

Rate
9.5
8.0

Rate
9.5
8.0
7.0

Merit
7.60
1.60
. . .9.20

Merit
6.65
1.60
0.70
...8.95
INTAKE

No. 2 Area Rate
70% 9.5
30% 8.0
Total 	

No. 4 Area Rate
80% 9 . 5
20% 9 . 0
Total 	

Merit
6.65
2.40
... 9 . 05

Merit
7.60
1.80
...9.40
                         Comments:   Avg. 9.15
                                   B-15

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TEST NO.   C-83
INTAKE MANIFOLD;  9.5 Carbon Rating

EGS PORT INTO INTAKE SYSTEM;  8.0 Carbon Rating

EGR LINE;  6.0 Carbon Rating

PISTON CROWN;  1 - 8.3
               2 - 8.5
               3 - 8.5
               4 - 8.0
            Avg.  8.32

CYLINDER BORE:  1 - Good condition,  no apparent distress.
                2 - Good condition,  no apparent distress.
                3 - Good condition,  no apparent distress.
                4 - Good condition,  no apparent distress.

FUEL TANK:  Fuel tank is in very good condition.   No signs of rust,

            Top of tank    - 9.7 Varnish,  9.9 Sludge
            Bottom of tank - 9.0 Varnish,  9.9 Sludge
                                   B-16

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      *Non  linkage throttle plate has  100% rust.
                                                              Appendix C

                                            RECOMMENDED CARBURETOR RATING FORM
CARBURETOR MAKE .
BBLS.
USE SEPARATE SHEET FOR: PRIMARY BBLS.
.DATEQ5-25-87  TEST #   C-83

	  SECONDARY BBLS.	
.RATER  G. Tschirhart
DEPOSIT DESCRIPTION
Clean (no visible deposits)
* 10.0to9.0
Light discoloration
* 9.0 to 6.0
Definite (dark) discoloration
* 6.0 to < .001 "thick
Deposit < .015" > .001 "thick
Deposit > .015" thick

(D
Linkage Barrel
% Area x
(2)
Left
Side

100%



100%
(1)
Right
Side

100Z



100%
Depth
Factor

10.0
7.5
5.0
2.5
0
Total
Deposit
Number
Deposit
No.
Left
Side

7.50


0
7.50
Right
Side

7.50


0
7.50
Non-Linkage Barrel
% Area x
Left
Side

100%



100%
Right
Side

20%
80%


100%
Depth
Factor

10.0
7.5
5.0
2.5
0
Total
Deposit
Number
Deposit
No.
Left
Side

7.50


0
7.50
Right
Side

1.50
4.00

0
5.50
% OF TOTAL AREA BELOW THROTTLE PLATE AVAILABLE FOR DEPOSIT (CRC Test Sleeves (3): 40% Left; 60% Right)

                           % Left Side = 100 x Left Depth  =	%;  % Right Side = 100 x Right Depth  =	%
                                            Left + Right                             Left + Right

FOR 2/4 BBL CARBURETORS: AVG RIGHT DEPOSIT NO. = 0.5 x (RIGHT LINKAGE BARREL + RIGHT NON-LINKAGE BARREL) = 6.50

                         AVG LEFT DEPOSIT NO. = 0.5 x (LEFT LINKAGE BARREL + LEFT NON-LINKAGE BARREL) = 7:50

CARBURETOR MERIT RATING = (Avg. Left Dep. No. x % Available Area) + (Avg. Right Dep. No. x % Available Area)


Carburetor Merit Rating = (            x           ) +  (           x           ) = (                     ) + (

NOTES
1. The right side of the carburetor/sleeve is the one with idle fuel ports, transfer slot, and vac. ports.
  The linkage barrel is the barrel adjacent to the carburetor linkages.

2. The left side of the carburetor/sleeve has no holes.
3. The CRC Carburetor Cleanliness Test Aluminum sleeve is considered to have 40%left Side Available Area, 60% Right Side Available Area.

  *CRC Varnish Rating Scale

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                      INDUCTION SYSTEM RATING SHEET
TEST NO.:   C-202              DATE:  05-26-87              RATER:   G.  TSCHIRHART

                           COMBUSTION CHAMBERS

No. 1      Area      Rate      Merit       No. 2      Area      Rate       Merit

           30Z       9.0       2.70                   20%       9.0        1.80
           707o       8.0       5.60                   807o       8.0        6.40

Total	8.30        Total	8.20
No. 3	Area	Rate	Merit	No. 4	Area	Rate	Merit

           107o       9.0       0.90                   1007»      8.0       8.00
           907o       8.0       7.20

Total	8.10        Total	8.00


                          Comment s:  Avg. 8.15
                                 VALVES
                              INTAKE VALVES

              Rate           No.           Rate           No.           Rate
 1            5.8             2            5.8             3            4.8

 4            5.1

                          Comments:    Avg. 5.4


                             EXHAUST VALVES

No.           Rate           No.           Rate           No.          Rate

 1            7.5             2            7.5             3           7.5

 4            7.5

                          Comments:   Ayg. 7.5
                                   B-18

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INDUCTION SYSTEM RATING SHEET
TEST NO.:


No. 1
Total 	

No. 3
Total 	



No. 1
Tnf-al

No. 3
Total 	
C-202


Area
507=
50%

Area
407o
60%



Area
107o
807.,
57o
5%

Area
307o
507,
107.
10%
DATE: 05-26-87
MANIFOLD RUNNERS

Rate Merit No. 2
9.5 4.75
8.5 4.25
	 9.00 Total . . .

Rate Merit No. 4
9.5 3.80
8.5 5.10
	 8 . 90 Total 	
Comments: 8.90
HEAD PORTS - INTAKE

Rate Merit No. 2
9.5 0.95
8.0 6.40
6.0 0.30
5.0 0.25
	 7.90 Total 	

Rate Merit No. 4
9.0 2.70
8.0 4.00
7.0 0.70
7.5 0.75
	 8.15 Total..
RATER: G. TSCHIRHART


Area Rate Merit
707o 9.5 6.65
3070 8.5 2.55
	 9 10

Area Rate Merit
1070 9.5 0.95
907, 8.5 7.65
	 8.60



Area Rate Merit
7070 9.0 6.30
2070 8.0 1.60
107o 7.0 0.70
	 8.60

Area Rate Merit
807o 9.0 7.20
207o 8.0 1.60
	 8.80
   Comments:   Avg. 8.36
             B-19

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TEST NO.   C-202
INTAKE MANIFOLD:  9.5 Carbon Rating

EGR PORT INTO INTAKE SYSTEM;  6.0 Carbon Rating

EGR LINE;  5,5 Carbon Rating

PISTON CROWN;  1 - 8.2
               2 - 8.2
               3 - 8.1
               4 - 8.1
            Avg.  8.15

CYLINDER BORE;  1 - Good condition,  no apparent distress.
                2 - Good condition,  no apparent distress.
                3 - Light scratch marks,  possible stuck or broken ring.
                4 - Good condition,  no apparent distress.

FUEL TANK;  Fuel tank is in very good condition.   No signs of foreign material.

            Top of tank    - 9.9 Varnish, 9.9 Sludge, 9.0 Rust Rating
            Bottom of tank - 9.9 Varnish, 9.9 Sludge
                                    B-20

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     CARBURETOR MAKE .
BBLS.
     USE SEPARATE SHEET FOR:  PRIMARY BBLS.
                   Appendix C
 RECOMMENDED CARBURETOR RATING FORM

_ DATE  05-26-87 TEST # C-202    RATER _jG	Is-C-h-irhart
	  SECONDARYBBLS	
DEPOSIT DESCRIPTION
Clean (no visible deposits)
* 10.0to9.0
Light discoloration
* 9.0 to 6.0
Definite (dark) discoloration
*6.0to< .001 "thick
Deposit < .015" > .001 "thick
Deposit > .015" thick

(1)
Linkage Barrel
% Area x
(2)
Left
Side

100%



100%
(1)
Right
Side

100%



100%
Depth
Factor

10.0
7.5
5.0
2.5
0
Total
Deposit
Number
Deposit
No.
Left
Side

7.50


0
7.50
Right
Side

7.50


0
7.50
Non-Linkage Barrel
% Area x
Left
Side

30%
70%


100%
Right
Side


100%


100%
Depth
Factor

10.0
7.5
5.0
2.5
0
Total
Deposit
Number
Deposit
No.
Left
Side

2.25
3.50

0
5.75
Right
Side


5.00

0
5.00
w
                                                                        %
     % OF TOTAL AREA BELOW THROTTLE PLATE AVAILABLE FOR DEPOSIT (CRC Test Sleeves (3): 40% Left; 60% Right)
                                % Left Side = 100 x Left Depth   = _ %;  % Right Side = 100  x Right Depth   =
                                                 Left + Right                             Left + RighT"

     FOR 2/4 BBL CARBURETORS: AVG RIGHT DEPOSIT NO.  = 0.5 x (RIGHT LINKAGE BARREL + RIGHT NON-LINKAGE BARREL) = 6.25
                              AVG LEFT DEPOSIT NO.   = 0.5 x (LEFT LINKAGE BARREL + LEFT  NON-LINKAGE BARREL) =  6.62

     CARBURETOR MERIT RATING = (Avg. Left Dep. No. x % Available Area) + (Avg. Right Dep. No. x % Available Area)

     Carburetor Merit Rating = (           x           ) + (           x            ) = (                     ) + (

     NOTES
     1. The right side of the carburetor/sleeve is the one with idle fuel ports, transfer slot, and vac. ports.
       The linkage barrel is the barrel adjacent to the carburetor linkages.
     2. The left side of the carburetor/sleeve has no holes.
     3. The CRC Carburetor Cleanliness Test Aluminum sleeve is considered to have 40%'Left Side Available Area, 60% Right Side Available Area.

       *CRC Varnish Rating Scale

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                      INDUCTION SYSTEM RATING SHEET
TEST NO.:  C-232              DATE:  05-25-87             RATER:   G.  TSCHIRHART

                           COMBUSTION CHAMBERS

No. 1      Area      Rate      Merit       No. 2      Area      Rate       Merit

           100%      8.0       8.00                   80%       8.0        6.40
                                                      20%       7.5        1.50
Total	8.00        Total	7.90
No. 3	Area	Rate	Merit	No. 4	Area	Rate	Merit

           50%       8.0       4.00                   80%       8,0       6.40
           50%       7.5       3.75                   207»       7.5       1.50
Total	7.75        Total	7.90


                          Comment s;  Avg.  7.89
                                 VALVES
                              INTAKE VALVES

No.           Rate           No.           Rate           No.           Rate

 1            3.5             2            3.5             3            2.0

 4            3.5

                          Comments:   Avg.  3.1


                             EXHAUST VALVES

No.           Rate           No.           Rate           No.          Rate

 1            7.5             2            7.5             3           7.5

 4            7.5

                          Comments:   Avg. 7.5
                                    B-22

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INDUCTION SYSTEM RATING SHEET
TEST NO.: C-232


No. 1 Area
807=
207o
Total 	

No. 3 Area
1007o



No . 1 Area
507»
507»
Tofal

No. 3 Area
507»
507c
Total 	
DATE: 05-25-87
MANIFOLD RUNNERS

Rate Merit No. 2
7.5 6.00
7.0 1.40
	 7.40 Total...

Rate Merit No. 4
5.5 5.50
	 5 . 50 Total 	
Comments: 6.18
HEAD PORTS - INTAKE

Rate Merit No. 2
8.0 4.00
5.0 2.50
	 6.50 Total...

Rate Merit No. 4
4.0 2.00
3.0 1.50
	 3 . 50 Total . .
RATER: G.


Area Rate
307o 6.5
707» 6.0

Area Rate
307» 6 . 0
707» 5.5



Area Rate
107, 8.0
307, 6.0
207= 4.0
407o 3 . 0

Area Rate
907» 8 . 0
10% 7.0
TSCHIRHART


Merit
1.95
4.20
6 15

Merit
1.80
3.85
	 5 . 65



Merit
0.80
1.80
0.80
1.20
	 4.60

Merit
7.20
0.70
	 7.90
   Comments:   Avg. 5.62
              B-23

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TEST NO.  C-232
INTAKE MANIFOLD:  7.7 Carbon Rating
EGR PORT INTO INTAKE SYSTEM;   5.0 Carbon Rating

EGR LINE;  5.0 Carbon Rating

PISTON CROWN:  1 - 7.8
               2 - 7.9
               3 - 8.0
               4-7.5
            Avg.  7.80

CYLINDER BORE:  1 - Good condition,  no apparent distress.
                2 - Good condition,  no apparent distress.
                3 - Good condition,  no apparent distress.
                4 - Good condition,  no apparent distress.

FUEL TANK;  Fuel tank is  in very good condition.   No signs  of foreign material

            Top of tank     -  9.9 Sludge,  9.9  Varnish Rating
            Bottom of tank -  9.9 Sludge,  9.9  Varnish Rating

-------
     CARBURETOR MAKE
.BBLS.
      USE SEPARATE SHEET FOR:  PRIMARY BBLS.
                  Appendix C
 RECOMMENDED CARBURETOR RATING FORM
_ DATE  05-25-87 TEST # C-232    RATER   r,.  TSr-hirhart
	  SECONDARY BBLS	
DEPOSIT DESCRIPTION
Clean (no visible deposits)
* 10.0 to 9.0
Light discoloration
* 9.0 to 6.0
Definite (dark) discoloration
* 6.0 to < .001 "thick
Deposit < .015" > .001" thick
Deposit > .01 5" thick

(D
Linkage Barrel
°/oArea x
(2)
Left
Side

15%
5%
807c

100%
(1)
Right
Side

57»
57o
907o

100%
Depth
Factor

10.0
7.5
5.0
2.5
0
Total
Deposit
Number
Deposit
No.
Left
Side

1.12
0.25
2.00
0
3.37
Right
Side

0.38
0.25
2.25
0
2.88
Non-Linkage Barrel
% Area x
Left
Side


10%

907o
100%
Right
Side


207o

807»
100%
Depth
Factor

10.0
7.5
5.0
2.5
0
Total
Deposit
Number
Deposit
No.
Left
Side


0.50

0
0.50
Right
Side


1.00

0
1.00
ra
      % OF TOTAL AREA BELOW THROTTLE PLATE AVAILABLE FOR DEPOSIT (CRC Test Sleeves (3): 40% Left; 60% Right)
                                 % Left Side = 100 x Left Depth  =	%;  % Right Side =  100 x Right Depth  =	%
                                                  Left + Right                              Left + Right
      FOR 2/4 BBL CARBURETORS: AVG RIGHT DEPOSIT NO. = 0.5 x (RIGHT LINKAGE BARREL + RIGHT NON-LINKAGE BARREL) = 1 ._94
                               AVG LEFT DEPOSIT NO.  = 0.5 x (LEFT LINKAGE BARREL + LEFT NON-LINKAGE BARREL) =  i T 94
      CARBURETOR MERIT RATING = (Avg. Left Dep. No. x % Available Area) + (Avg. Right Dep. No.  x % Available Area)
      Carburetor Merit Rating = (           x           ) + (           x           ) = (                     ) + (
      NOTES
      1. The right side of the carburetor/sleeve is the one with idle fuel ports, transfer slot, and vac. ports.
        The linkage barrel is the barrel adjacent to the carburetor linkages.
      2. The left side of the carburetor/sleeve has no holes.
      3. The CRC Carburetor Cleanliness Test Aluminum sleeve is considered to have 40% Left Side Available Area, 60% Right Side Available Area.
                                                ^
        *CRC Varnish Rating Scale

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      APPENDIX C




FUEL ADDITIVE ANALYSIS

-------
  SOUTHWEST  RESEARCH   INSTITUTE
                         INTER-DEPARTMENTAL MEMORANDUM
TO:    Sherrill Martin

FROM:   Michelle Miller

SUBJECT:  Additive  Analysis  of  samples  C-83,  SC-239,   SC-453,  SC-205
          C-202 and C-232

October 6, 1987
     The following are the results from the analysis:

                                                             Additive A*
 Sample #                Unwashed Gum (mg/50ml)                  (ppma)

 C-83                              2.2                             4.1

 SC-239                            1.5                             0.0

 SC-453                            6.3                            17.9

 SC-205                            9.8                            28.7

 C-202                            11.3                           155.6

 C-232                            13.7                            11.0

     Sample  C-202  has  normal  amount  of  additive  A  added.   In  this
 particular  test  procedure  a high  unwashed  gum content correlates  with
 the  amount  of additive  added.   With  this  in mind,  the  high  unwashed
 gum value for C-232 could mean  there is an  additive  that  was  undetected
 by our procedure.

 *Additive  A's   name   cannot   be  given  out.   This  is   confidential
 information between the sponsor  and Southwest  Research  Institute.

MM:chl
                                 C-2

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TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
•1. REPORT NO. 2.
EPA 460/3-88-006
4. TITLE AND SUBTITLE
Intake System Deposits and Gasoline/Alcohol Blend
7. AUTHOR(S)
Sherrill F. Martin
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Southwest Research Institute
Department of Emissions Research
6220 Culebra Road
Ann Arbor, Michigan 48105
12. SPONSORING AGENCY NAME AND ADDRESS
Environmental Protection Agency
2565 Plymouth Road
Ann Arbor, Michigan 48105
15. SUPPLEMENTARY NOTES
3. RECIPIENT'S ACCESSION-NO.
5. REPORT DATE
s May 1988
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-03-3353
13. TYPE OF REPORT AND PERIOD COVERED
Final (Sept. 1986 - Aug. 1987
14. SPONSORING AGENCY CODE

16. ABSTRACT
Six vehicles, four of them ethanol blend-fueled and two gasoline-fueled, were
examined for intake system deposits. The engines were partially disassembled,
photographs were taken, and deposits were evaluated by a professional rater.
Elemental analysis was made of the intake valve deposits.
i
17. KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS b.lDENTIFI
Deposits Engine Valves Gasohc
Blends Intake Systems Blend
Fuel Tanks Intake
Fuel Additives
Ehtanol
18. DISTRIBUTION STATEMENT 19. SECURI
Release Unlimited Unclas
20. SECURI
Unclas
ERS/OPEN ENDED TERMS C. COS AT I Field/Group
)1
Fuels
2 Deposits
TY CLASS (This Report) 21. NO. OF PAGES
ssified 40
TV CLASS (This page) 22. PRICE
;sif ied
EPA Form 2220-1 (9-73)

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