EPA-AA-TSS-PA-84-4

                 Technical Report
          Size Specific Total Particulate
        Emission Factors for Mobile Sources
                        By

                Robert  I. Bruetsch


                     June 1984
                      NOTICE

Technical Reports do not  necessarily  represent  final EPA
decisions or  positions.   They are  intended to  present
technical  analysis  of   issues   using   data  which  are
currently available.  The purpose in  the  release  of such
reports  is  to  facilitate  the  exchange  of  technical
information  and  to  inform   the  public  of  technical
developments which  may form  the  basis  for  a  final  EPA
decision, position or regulatory action.

              Technical Support Staff
        Emission  Control Technology  Division
   Office of Mobile Source Air Pollution Control
         Office of Air, Noise and  Radiation
       U. S. Environmental Protection Agency

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                             -2-

                      Table of Contents

                                                          Page

List of Tables                                              3

List of Figures                                             5

1.0    Introduction                                         6

2.0    Projecting Size Specific Total
         Particulate Emission Factors                       9

       2.1   Lead Emission Factors                         14

       2.2   Misfueling and Fuel Switching                 18

       2.3   Particle Size Distribution                    20

       2.4   Control System Fractions                      21

       2.5   Organic, Sulfate, Heavy-Duty Truck
               and Motorcycle Emission Factors             23

             2.5.1 Organic Emission Factor Components      23
             2.5.2 Sulfate Emission Factor Components      23
             2.5.3 Diesel Emission Factors                 27
             2.5.4 Heavy-Duty Truck Emission
                     Factor Components            .         28
             2.5.5 Motorcycle Emission Factors             32

       2.6   Brake and Tire Wear Particulate Emission
               Factor Components                           33

3.0    Example Calculation of Automobile
         Particulate Emissions Less than 10 Microns        57

4.0    References                                          66

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                             -3-

                         List  of Tables

Number   	Title	     Page

   1     Emission Factors of Motor Vehicle Engine
           Total Particulate Emissions                     35,36

   2     Lead Content of Gasoline        ,                   37

   3     Fraction of Light-Duty Vehicle Model Year
           Sales Equipped with Different Emission
           Control Systems  (Low-Altitude Non-California)    38

   4     Fleet Sales Fractions:  Light-Duty Vehicles        39

   5     Travel Weighting Factor Calculation:  Light-
           Duty Vehicles                        -            40

   6     City/Highway Combined  On-Road Fuel Economy         41

   7     Fuel Economy Correction Factors at Various
           Speeds, Cs                                       42

   8     Fraction of Light-Duty Truck I Model Year
           Sales Equipped with  Different Emission
           Control Systems  (Low-Altitude Non-California)    43

   9     Fleet Sales Fractions:  Light-Duty Trucks I        44

  10     Travel Weighting Factor Calculation:  Light-
           Duty Trucks I                                    45

  11     Fraction of Model  Year Sales of Light-Duty
           Trucks II by  Emission Control Systems            46

  12     Fleet Sales Fractions:  Light-Duty Trucks II       47

  13     Travel Weighting Factor Calculation:  Light-
           Duty Trucks II                                   48

  14     Fleet Sales Fractions:  Heavy-Duty Gasoline-
. .          Powered Trucks I and II                       ... 49

  15     Travel Weighting Factor Calculation:  Heavy-
           Duty Trucks I and Heavy-Duty Gasoline Trucks
           II                                               50

  16     Travel Weighting Factor Calculation:  Heavy-
           Duty Diesel Trucks II                            51

  17     Travel Weighting Factor Calculation:
           Motorcycles                                      52

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                             -4-

                   List of Tables (cont'd)

Number   	Title	    Page

  18     Rates of Misfueling (r^) for Different
           Vehicle Classes (Simplified Rates)               53

  18a    Rates of Misfueling (r^) for Different
           Vehicle Ages and Classes (Exact Rates)           54

  19     Average Data on Particle Size Distribution      55,56

  20     Example Calculations:  Light-Duty Vehicle
           Particulate Emission Rate Under 10 Microns
           for the Year 1985                                61

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                             -5-




                       List of Figures




Number   Title	     Page




  1      Leaded Gasoline Particulate Size Distribution      62




  2      Unleaded Gasoline Particulate Size Distribution    63




  3      Diesel Particulate Size Distribution               64




  4      Brake Wear Particulate Size Distribution           65

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                             -6-

1.0  INTRODUCTION

The  following   material   was   developed  to   predict   total
particulate emission  factors of on-road vehicles,  trucks  and
motorcycles,  both  gasoline  and  diesel  fueled,  at  various
vehicle  speeds   for  particles   in  the  respirable   size  range
(less  than  10  microns).   Particulate  emissions   from  these
vehicles may also be  determined at other size  intervals  less
than 10 microns  (e.g., less than 7.5, 5, or 2.5 microns).

User  inputs  to the  equations  developed  for   this  emission
factor determination  include area  travel  fractions  by vehicle
class,  vehicle  miles traveled,  vehicle speed,  particle  size
limits of interest and calendar year.

This report is  arranged to present  total  particulate emission
factor  equations,  as  the  sum  of  individual  masses of  lead
salt,  organic  and  sulfate  components for  leaded and unleaded
gasoline   fueled  vehicles  and   compositely   (i.e.,   total
particulate mass) for diesel fueled vehicles  and motorcycles,
and  tire and  brake  wear  particulate.   These  equations  are
subsequently accompanied by  tabulated  emission  factors  which
may  be  inserted  into the  appropriate particulate component
equations.   Fleet  sales  fractions  and travel  fractions  by
model  year   are  included  for  each  vehicle   class.    The
fractions  within each vehicle  class  that  are  equipped  with
different   emission  control   systems   are   also   provided.
Cumulative  distributions   of  particle  size  for.   leaded  and
unleaded   gasoline   and   diesel   fuel   are   presented   both
graphically  and  tabularly.   Also,  for  the   benefit  of  the
user,  an example  calculation   of  particulate emissions  from
light-duty vehicles is provided.

The  procedure  herein  can  be  used  to  project  automotive
particulate  emissions  by  those  agencies  developing  State

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                             -7-

Implementation  Plans  for  particulate  matter  or  by  other
interested parties  within or outside  the  EPA concerned  with
size  specific  particulate   emission   factor  projections  for
mobile sources.

This document was prepared by the  Office of  Mobile Sources in
response to a request from the  Office  of Air Quality Planning
and  Standards.   It has  been designed  to  be  consistent  with
the  methodology developed in the  April 15,   1983  EPA report,
Supplementary   Guidelines  for   Lead   Implementation  Plans—
Updated  Projections  for Motor Vehicle  Lead  Emissions,  by
Penny M. Carey,  and uses this  methodology for the projection
of  the  lead  component  of  total   particulate emissions  for
vehicles  using  leaded   and  unleaded  gasoline   (1)*.    In
addition to the  lead document,  from which  the methodology for
the  projection  of  area  lead emission  factors is  used,  this
report  uses  three  other  sources  of  particulate  emission
factor estimates.   Emission  factors for organics,  sulfates on
the  Federal  Test   Procedure   (FTP)   cycle,  and  heavy-duty
gasoline  trucks  came  from  the  Draft  Study of  Particulate
Emissions from  Motor Vehicles  (for Section  214 of  the Clean
Air  Act), by  the Environmental  Sciences  Research Laboratory,
Office  of  Research and Development,  U.S.   EPA,  July  1983
(10).  Sulfates on the  Sulfate Emission Test  (SET)  cycle and
motorcycle  emission  factors came from  the  March  1981  EPA
report,  Compilation  of  Air   Pollutant  Emission  Factors:
Highway  Mobile  Sources, EPA-460-3-81-005   (2).   Light-  and
heavy-duty diesel  particulate  emission factors are referenced
from  the Draft Diesel  Particulate  Study,   Emission  Control
Technology Division, Office  of Mobile  Sources,  Office of Air
and   Radiation,  U.S.    EPA,   October  1983   (4).   Emission
* Numbers in parentheses  represent  references  which are given
at the end of this report in Section 4.0.

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                             -8-

factor estimate  updating  is an  ongoing  process and,  in  many
cases,  these  values  are  based  on  testing  of  only  a  few
vehicles.

Further revisions will be  made  to this document as  needed  as
new   information  becomes   available.   In  particular,   new
information on  fleet  characteristics  and on the  incidence  of
fuel  switching  has  recently been prepared in connection  with
the preparation  of  MOBILES, the  latest  computer program  for
calcu-
lation  of  motor  vehicle  emissions  of  hydrocarbons,  carbon
monoxide,   and  oxides  of  nitrogen.   This  document  will  be
revised  to  reflect  this  new  information  as  promptly  as
possible.   In  the meantime,  the calculations  described  here
will give acceptable results.

This  document  may also have  to be revised  in  the  future  to
reflect  changes  in  the   use   of  unleaded  fuel.    EPA  is
currently considering banning  the use of leaded  fuel because
of the health hazards  associated with lead and to  discourage
the practice  of misfueling which deteriorates  the  efficiency
of vehicle  emission control  systems.  Since EPA  has not  at
this  time  proposed  these  regulations,  this   report  assumes
that  use of leaded  gasoline will continue with only  the  lead
phasedown in effect restricting the lead level to  1 g/gallon
in leaded gasoline.

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                             -9-

2.0    PROJECTING  SIZE SPECIFIC  TOTAL  PARTICULATE  EMISSION
       FACTORS

The purpose of  this  report is  to provide a  methodology  with
which  to  project  areawide total  particulate emissions  from
mobile  sources   in   a  given  calendar   year.    Particulate
emissions  can consist  of lead  salts,  organics  and  sulfate
emissions.  The  relative   amounts  vary for different  vehicle
types,  emission  control  strategies  and  vehicle  operating
modes.  Analysis  of  lead  particulate  indicates  that most  of
the exhausted lead appears as  PbClBr.   Therefore  estimates  of
the mass of lead particulate will be  considerably larger  than
those  predicted  by   the   lead  document.   Organic  emissions
include both  soluble  organics  and elemental  carbon and  are
important  contributors to total  particulate emissions  from
all  vehicles  especially  diesels.   Sulfate emissions,  mostly
from   unleaded   gasoline-fueled   vehicles   equipped   with
catalysts, are also  important  contributors  to total vehicular
particulate emissions.

Areawide particulate  emissions,  as is shown  in  Equation  1.0,
are  a  function  of   calendar  year,  average  vehicle  speed,
vehicle class travel  fractions,  the  particle  size range  of
interest and  the  vehicle  class emissions  associated with  the
calendar year and  vehicle speed.   With the exceptions  of  the
vehicle class  emission factors, all  of  the  above  parameters
are  inputs selected  by  the  user  on  an areawide  basis  to
obtain  the  desired   output  of   mobile   source   particulate
emissions from the area of interest.

Equation 1.0
     EF
Pm,n,s
EF
  brakes
                                                  EF
                                                    tires

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where:
                             -10-
EF
 ' pm,n,s
size   specific   all-vehicle   class   total
particulate emission  factor  on January  1  of
calendar year n at vehicle speed s (g/mile);
                 vehicle  class  designator   1  =  light-duty
                 vehicles  (LDV),   2  =  light-duty  trucks  I
                 (LDT1), 3 = light-duty trucks  II  (LDT2),  4 =
                 heavy-duty  trucks  I  (HDT1),  5  =  heavy-duty
                 trucks II (HDT2), 6 = motorcycles (MC);

                 vehicle  speed;  avg.  Federal  Test  Procedure
                 (FTP)  = 19.6,  avg.  Sulfate  Emissions  Test
                 (SET) = 34.8  (miles/hr);  (Note:   The FTP and
                 SET   are   driving   cycles   used    for   the
                 determination of emission factors.)

                 area  travel fraction of  vehicle class  i  in
                 calendar year n;
EF.
exhaust   particulate   emission
vehicle  class   i   in   calendar
vehicle speed s  (g/mile).
factor  for
year  n  at
EF.
  brakes
airborne  brake   wear   particulate  emission
factor  component  = 0.0128  grams/mile.   This
emission  factor  component  is  assumed  to  be
the  same for  all  vehicle classes,  vehicle
speeds  and  calendar years  (all i,  s,  and  n)
due to  lack of separate  information for each
i,  s, and n;

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                             -11-
EF..     =        airborne  tire   wear  particulate   emission
  tires
                 factor  component  =  0.002  grams/mile.   This
                 emission  factor  component  is  assumed  to  be
                 the  same  for  all  vehicle  classes,  vehicle
                 speeds and  calendar  years  (all i,  s,  and  n)
                 due to lack of  separate  information for each
                 i, s and n;

M-.      =        fraction  of airborne  particles  less  than  a
 hi
                 user  specified  size cutoff (0.1-10  urn) that
                 are attributable  to  vehicle brake wear, from
                 Table 19 or Figure 4.

The vehicle  classes for which  emission factor estimates  may
be  obtained   include:   1)   light-duty  vehicles  (passenger
cars),  2)   light-duty  trucks   I   (0-6000  Ibs.   GVWR),   3)
light-duty  trucks   II  (6001-8500  Ibs.  GVWR),  4)  heavy-duty
trucks  I   (8501-14000  Ibs.  GVWR),  5)  heavy-duty  trucks  II
(greater than 14001 Ibs. GVWR),  and 6) motorcycles.

The exhaust  emission  factors  for  each vehicle  class  for  a
given  calendar year  (EF.     )   are  broken down   into  compo-
                         i, n, s
nent emission  factors  in Equation  1.1.   The  components repre-
sent  the  masses of  lead  salt,  organic and  sulfate emissions
from  both leaded  and  unleaded  gasoline  fueled  vehicles  and
total particulate  mass from  diesel vehicles—all  of which are
multiplied by  the  fraction of total  vehicles of a given model
year designed  for  use  on these  three fuel types.   The  sum  of
these  components  for  each model  year  is  also multiplied  by
the fraction of the  vehicle  class  travel  attributable to that
model  year  (m.  .)  in  the  calendar  year of   interest.   For
               1» J
example,   the   component    (EF.  .       )    represents   the
                                 i, j , K , n, LI
emissions  in grams per mile  of  lead  salts  (k=l)  from vehicle
class  i  emitted from  model  year  j  vehicles  that are  on  the
road  in  calendar  year n and are  designed  for  use  on  leaded

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                             -12-

fuel.  These  emission components must  be summed  up  over the
twenty model years  prior  to the calendar year  of  interest to
include  all  the  contributing  fractions of  emissions  from
vehicles on the road.

The  travel  fractions for  the  six vehicle classes from model
years n to n-19 are  provided in Tables  5, 10,  13,  15, 16, and
17.   These  tables  are  entitled  "Travel  Weighting  Factor
Calculation"  and there  is  one  for  each of the  six vehicle
classes.  (Table  15,  however, should be  used for all vehicles
in  the  heavy-duty  truck  I  category  and all  gasoline  heavy-
duty  trucks  II.   Table 16  should  be  used for  all diesels in
the heavy-duty truck II  category only.   For  an explanation of
how  to  compute   emissions  from heavy-duty  trucks  II,  see
Section 2.5.4 on  p. 23.)  The  fraction  of  vehicles from each
class  and  model  year  of   vehicles  designed  to   use  leaded
gasoline    (F, .  .),   unleaded   gasoline   (FNTT   .  .),   and
             J-i , 1 , J                              JN.LJ, 1 , J
diesel  fuel  (F  .  .) are  contained in  Tables 4,   9,  12, and
               LJ , 1 , J
14.   These  tables  are  entitled  "Fleet   Sales   Fractions".
Separate  tables   are  provided  for   light-duty vehicles  and
light-duty  trucks I  and  II.   Table  14  contains  fleet  sales
fractions of  gasoline fueled  versus  diesel  heavy-duty trucks
I and II.  Gasoline-fueled heavy-duty trucks I are assumed to
use  leaded gasoline prior to  1987 and  unleaded gasoline from
1987  on.   Gasoline-fueled heavy-duty truck  II and motorcycle
fleet  sales  are   assumed  to  consist  entirely  of  leaded
gasoline vehicles  for all model  years.
Equation 1.1
            n
EFi „ = =   Y!   C(EF< -i v  „ T + EF.  . .  T + EF.  .  .   T)(F_  .  .)
inc     71    Lvi-iV  r.T±JJ-i-ilr  T^^^-i-iV  T'^^T-i
l,n,S     ^J        l,J/K1,n,Li     l,J,K_,JLi     l,3,K0,Li   Li>l»
          j=n-19
                                          2
     (EFi,j,k1,n,NL + EFi,j,k2,NL  + EFi,j,k3,NL)(FNL,i,j}

     (EF     )(F   .  .)]m.  .

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                             -13-

where:


j          =     model year  j = n-19, n-18,...,n-2,n-1,n;

L          =     vehicles designed for use on leaded fuel;

NL         =     vehicles designed for use on unleaded fuel;

k          =     component   of   total   particulate  emission
                 factor  (k,  =  lead,  k~  =  organic,  k.,  =
                 sulfate) expressed  individually for gasoline
                 vehicles and trucks  (except  motorcycles) and
                 cumulatively for  diesel vehicles  and trucks
                 and motorcycles;

FL .  .      =     fraction   of   the  vehicle   class  i  fleet
                 designed for use  on  leaded gasoline in model
                 year j;

FXT,  .  .    =     fraction   of   the  vehicle   class  i  fleet
 NL,i,j
                 designed  for  use  on  unleaded gasoline  in
                 model year  j;

Fn .        =     fraction   of   the  vehicle   class  i  fleet
 Ut 1 / J
                 designed  for  use on  diesel  fuel in  model
                 year j ;

m. ."       =     travel fraction for  vehicle  class  i in model
 1» J
                 year j.

Component emission factors  are  derived  for  each vehicle class
over different model  years  at average  speeds  of 19.6  mph
(cyclic  driving  comparable  to  average  speed of the  Federal

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                             -14-

Test Procedure)  and  34.8 mph  (cruising  conditions comparable
to the average speed of  the  Sulfate Emissions Test) beginning
with   Equation   1.1.1   and   ending  'with   Equation  1.1.47.
Emission  factors  for speeds  between 19.6 and  34.8 should be
interpolated linearly.

2.1    Lead Emission Factors

Lead emission factors are  calculated in  the same manner as in
the recent report  entitled,  Supplementary Guidelines for Lead
Implementation  Plans--Updated  Projections  for  Motor Vehicle
Lead   Emissions,   hereinafter   referred  to   as   the   "lead
document"  (1).   These lead  emission estimates are multiplied
by  a  factor  of  1.557 to account  for  the halogens,  typically
bromine  and  chlorine, which .combine with  lead  to form  total
lead  salt particulate  emissions.   This factor  was obtained
from a report by  the Ethyl  Corporation  entitled  Composition,
Size,  and Control of Automotive Exhaust Particulates,  and is
the ratio of PbClBr mass  to Pb mass based  on FTP results of
16  test  vehicles  (24).
For i =  1,2,3   j  = n-19,...,1974   k=l   C   =  from  Table  7  a   =  0.75
                                        s                 s

Equation  1.1.1
     EFi  -i k  n T  =  CPbT  n(0.929)(MT)+
        11 J / K. , n, LI      LI, n          LI

                                            (aWl1^?}
                     TV\_     / ^  A *» "I \ / »•     \ T  \ ^^  / V ^ • «J «^ / /
                     PbXTT  _ (0.071) (MXTT „-)]   s/v
where:
                                            (E   .  . )(C )
                                             c,i,3    s'
                  fraction  of  lead  burned  that  is  exhausted;
                  for  non-catalyst   vehicles   use   a   =   0.75
                                                     S
                  (i.e.,  75%);  for  catalyst   vehicles  use  a
                  =  0.30  (i.e.  30%);

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                             -15-

C          =     speed-dependent   fuel   economy   correction
 s
                 factor  based  on  steady  cruise  or  cyclic
                 driving;     available     from     Table     7
                 (nondimensional);
Pb.TT       =     lead   content   of   unleaded   gasoline   in
  NL,n                                           ^
                 calendar year n  from Table 2 (g/gal);
    n
PbT  n      =     average  lead  content of  leaded gasoline  in
                 calendar year n from Table 2 (g/gal);

           =     city/highway  combined  on-road  fuel  economy
                 for model  year  j  and  vehicle  class  i  from
                 Table 6  (miles/gallon);

M          =     fraction  of  particles   less   than  a  user
                 specified  size  cutoff  (0.1-10  urn)  that  are
                 emitted  from  vehicles  that  are fueled  with
                 leaded gasoline, from Table 19 or Figure 1;

^NL C      =     fraction  of  particles   less   than  a  user
                 specified  size  cutoff  (0.1-10  urn)  that  are
                 emitted  from   catalyst   vehicles   that   are
                 fueled with unleaded  gasoline,  from Table 19
                 or Figure 2;

MNL NC     =     fraction  of  particles   less   than  a  user
                 specified  size  cutoff  (0.1-10  urn) .that  are
                 emitted  from  non-catalyst vehicles  that  are
                 fueled with unleaded  gasoline,  from Table 19
                 or Figure 2.

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                             -16-

For i = 1,2,3  j = 1975,. ..,n  k=l  C  = from Table 7 a  = 0.75
               -*                     O                 *3

Equation 1,1*2
     EPifjfkrn,L
                                     '    (£„ .  ,)(C'
                                            c, i, 3   s
For i = 1,2,3  j = 1975,...,n  k=l  GS = from Table 7 ag = 0.30

Equation 1.1.3
     EPi, j.k^n.NL
where:
r.         =     misfueling  rate  for  vehicle  class  i  from
                 Table 18.
The   calculation   of   area   lead   particulate   emissions
necessitates  the determination  of the  percentage  of  burned
lead  exhausted  (a  ) .   A  value  for  a   of  0.75   (i.e.,  75
      .             S      .               S            *     '  .
percent of  the lead burned  is  exhausted)  should be used for
non-catalyst -equipped,  gasoline-powered  vehicles.    The  0.75
value  is  based on  tests  which  measured  exhaust  emissions
under  cyclic driving  conditions  and  found that  17%  of  the
lead  is  retained by  the  engine   (in  the  oil  and   combustion
chamber) and  8% is  retained by the muffler  and exhaust pipes
(33).  For  gasoline-powered vehicles  with  catalysts a value
of 0.30  for  a  should be  used.   The  0.30 value  accounts for
              S

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                            -17-

lead retention  by the  catalyst  (approximately  45% based  on
some  tests  run  by  GM  (41)  on  pelleted  catalyst-equipped
vehicles), the  oil,  the combustion  chamber and  the rest  of
the  exhaust  system  (approximately  25%).   The  appropriate
values  for  a   have  been  included  above  the  appropriate
              s
equations for convenience.

Combined  city/highway  fuel  economy   (E  .   .)  is yet  another
                                       c /11 D
factor  affecting  area  lead   particulate  emissions.    Fuel
economy versus model year  is provided for  each  vehicle  class
(except motorcycles)  in  Table  6.   Fuel  economy  of gasoline-
fueled heavy-duty  trucks was  assumed to  equal 5.0  mpg  in all
model years  in the lead document  since this is the  value used
in MOBILE2.  Values for heavy-duty and future  model year fuel
economy  for  other vehicle  classes  were  updated  for  this
report since newer information is now available.   The  heavy-
duty fuel  economy values  in  this report  are  expected  to  be
changed  in  a  future  version   to  make them  consistent  with
MOBILES.   The  values  in  Table  6  are closer  to the  MOBILES
values than  was the 5.0 mpg figure used in MOBILE2.

Lead particulate  emissions can be determined  at  any speed  by
using  Equations   1.1.1,   1.1.2   and  1.1.3   (for  light-duty
vehicles  and  trucks)  and  1.1.18,  1.1.19, and 1.1.20  (for
heavy-duty  trucks) and  the  appropriate  value  of   the  speed
dependent  fuel   economy   correction  factor   (C  )   for  the
                                                  S
vehicle  speed  of  interest.   Values  of C   at  various  speeds
                                 •        S
are  provided in  Table  7.    It should be  noted  that  average
vehicle  speed  and  C   can  be determined for  an  area  by
either  of two  approaches.  One  approach  is  to base   C   on
                                                          S
the  average  vehicle  speed  for  the area of concern.   The
average area vehicle speed should  be a weighted average based
on  average  speeds and  VMT   data   for  the   various  roadway
classifications, such as limited access (greater than  5 mph) ,
suburban  roads  (35 mph)  and urban  streets (25  mph or  less).
The other  approach, which  is considered more  accurate,  is  to

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                             -18-
determine C   and area emissions  separately for each  roadway
           s
classification (and average speed).

Area  lead  particulate emissions are  also dependent upon  the
lead  content  of gasoline  in a given calendar year.   Values
for   the   lead  content  of   leaded  (Pb_  )  and   unleaded
                                          L, n
gasoline  (Pb,TT  )   are  contained   in Table  2.   Values  for
             NL,n
future  years  will  be  updated  as   new  information  becomes
available.
Emission  factors  for organic  sulfates  and diesels  have  been
derived and are listed  in  Table  1 for speeds  of 19.6 and 34.8
mph.   However,  if  emission  estimates  for these  particulate
components are  desired  at other  speeds,  linear interpolation
of  emission  factors  is possible  and appropriate.   In  fact,
some  of the  emission  factor.s  in  Table  1  (particularly  for
organic  and  diesel particulate  masses)  can be  used at  "all"
vehicle speeds.

2.2     Misfueling and Fuel Switching

EPA  has observed that  misfueling rates  (i.e.,  percentage of
vehicles  designed  for  use  on   unleaded   gasoline   that  use
leaded   gasoline)   are   dependent  on   vehicle  mileage  and
increase   with   vehicle   mileage   accumulation.    Strictly
speaking,  this  dependence on  mileage should be  reflected in
the  calculation  of particulate  emissions,  with  each  model
year   receiving   its  own  misfueling  rate.    However,   this
further  complicates an  already complex  calculation.  To give
the  user  a  choice',  this report  offers both  the  option of
using  a single  average  misfueling rate  for all  model years of
a  given vehicle  class   and  exact  misfueling  rates  for each
vehicle  class  by vehicle  age.   The  single average  rates are
determined  for  the  weighted average mileage accumulated for
each  vehicle  class  and  are  listed  in Table 18  for  inspection
and  maintenance  (I/M)  and non-I/M  areas.   In other  words, in
the   calculation  of  emission   factors   from  1975   on,  the

-------
                             -19-

misfueling  rate  (r.)  depends  only  on which  vehicle  class
(i) is being  considered  and  whether the area of  interest  has
an  I/M   program.   As   a   result,   misfueling  rates   and
particulate  emissions  will  be  slightly overestimated,  with
the degree  of overestimation declining  with  later  evaluation
years  and  essentially disappearing in  1995.   For users  who
desire more  accuracy,  Table  18a gives  exact  misfueling rates
for different vehicle ages and classes affected by misfueling.

The use of  leaded gasoline on vehicles  designed  for  unleaded
fuel  results  in  lead  salt  emissions.   Since  most  of  these
vehicles have catalysts,  the  lead  results in  poisoning  of  the
catalyst so that  organic particulate  emissions  can be assumed
to  increase  to the  levels  found with  non-catalyst  vehicles.
Also,   catalyst  poisoning should result  in  no  sulfur  dioxide
oxidation to  sulfates.   Sulfate levels  are  therefore  assumed
to be the same as those from non-catalyst vehicles.

Discretionary  fuel  switching  (i.e.,  percentage  of  vehicles
designed  for  use   on   leaded   gasoline that   use   unleaded
gasoline) is  assumed to  equal 7.1% of  the  leaded  fleet prior
to  1974 and 27.5%  in 1975  and later years and only applies to
the lead  salt component  of  light-duty  vehicle  and  light-duty
truck  I   and   II  emissions.    Misfueling and  fuel  switching
rates  for all heavy-duty trucks  II  (over 14000  Ibs.  GVWR)  and
motorcycles  are  assumed  to   be  zero.   The  misfueling  rates
employed  here  were  used  in the  December   1983  EPA  report,
Anti-Tampering  and  Anti-Misfueling Programs  to Reduce  In-Use
Emissions  from  Motor  Vehicles,   EPA-AA-TSS-83-10  (3).   The
discretionary  fuel   switching  were obtained  from Energy  and
Environmental  Analysis,    Inc.,  Assessment   of_  Current  and
Projected Future  Trends  in Light-Duty Vehicle Fuel  Switching,
June 1982 (8).

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                            -20-

2.3    Particle Size Distribution

Distributions  of  particle  size   are   different   for  leaded
gasoline, unleaded gasoline and diesel  fueled  vehicles as  well
as brake and tire wear particles.   They are  also  different for
various conditions  of  vehicle  driving  cycle  (speed)  and  load.
For the  purposes of this  report,  however,   typical  or average
conditions  are  presented  to  facilitate  the  determination  of
vehicle particulate emissions versus particle size.

Particle  size  distributions  for  leaded,  unleaded  and  diesel
fueled  vehicles  and  brake  wear  particles   are  contained  in
Table 19 and also in  Figures 1, 2,  3,  and 4 (no  distributions
are  available   for  tire   wear  particulate).   Typically,   the
average  diameter of  particles  emitted  from vehicles  fueled
with  leaded gasoline  are  the  largest,  particles  emitted  from
vehicles  fueled with  unleaded gasoline  are  somewhat smaller
and particles  emitted  from diesel  fueled vehicles  are smaller
yet.   Some of  the data   for  the  size  distribution of  lead
particles  are   conflicting (e.g.,  Moran  et  al.,   1971  which
shows  a  larger  fraction  of the  lead  in smaller  size  ranges
than  the  other  leaded gasoline references.)   Thus,  these  data
are less certain  than those for unleaded  and diesel particles.
References  for  those  reports  used  in  the determination  of
particle  size   distributions  of  leaded,  unleaded   and  diesel
fueled vehicle  emissions  and brake wear emissions  are  listed
in Table 19.

Values   for ML,  MNL c,   MNL NC/   MD,  and  M_   should  be
expressed  as dimensionless fractions of total particulate  by
weight emitted  below a given  size cutoff.  Values  may be  read
directly from Table 19 for the data points  listed  therein,  or
may be  read off  the  graphs of continuous cumulative particle
size distributions  in Figures  1,  2, 3,  and  4 for  interpolated
size cutoffs (e.g.,  6.5 urn, 2.5 urn).

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                            -21-

2.4    Control System Fractions

Organic  and  sulfate  emissions  of  gasoline-fueled  vehicles
depend  on  the  type  of  vehicle  emission  control  system  in
addition to the vehicle  model year.  The fraction  of  vehicles
with  different  emission  control  systems   to  which  different
emission  factors   are  applied  are  handled similarly  to  the
fleet sales fractions for leaded, unleaded  and  diesel  vehicles
versus  model  year.   The main difference  is  that these  are
fractions of  the  total  number of vehicles designed  for  use  of
unleaded  fuel and  not  the  total  number of  vehicles in  each
vehicle class.  These fractions are  listed  in Tables 3,  8,  and
ll  for  light-duty  vehicles,  light-duty  trucks  I  and  II,
respectively.   These  are  the vehicle  classes  that  have  a
relatively wide range of control technology,  and as a result,
have a  wide range of emission factor estimates.  It should  be
noted that  since  1975  a small number of non-catalyst  equipped
vehicles  have been  certified  for  use  on  unleaded gasoline.
These vehicles constitute a  very  small  percentage of the total
non-catalyst  fleet.   However, unlike the lead  document,  these
are  considered  in this  report and  have been given  their  own
control system fraction category (Fi,j/NL/NOCAT)•

The  light-duty   vehicle  and  truck  emission  control  system
fractions were obtained  from the "sales-weighted"  EPA emission
factor  in-use vehicle test  data  base.   This data base contains
gasoline-fueled  vehicle  mixes approximating  the  sales  mixes
for  the  1975 through   1982  model  years.   All  vehicles  and
trucks  prior  to 1975 models  are  assumed to  be designed for use
on   leaded  fuel   (i.e.,  no  diesel  or  catalyst   vehicles).
Emission  control   system fractions  for  1983  and  later  model
years  are  determined  from  recent  projections  by   Energy  and
Environmental Analysis,  Inc.  in  a  report  entitled, Forecasts
Oj£  Emission Control Technology  1982-1990  (40).  For  1987  and
later,  light-duty trucks  I  and II  which are assumed to convert
largely to  three-way catalyst technology to  meet  the proposed
1987 standards.

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                             -22-

Air injection fractions were  obtained  for  light-duty vehicles
and  trucks   from  the  Anti-Tampering  and   Anti-Misfueling
Programs  to  Reduce  In-Use  Emissions  from  Motor  Vehicles
(EPA/AA/83-10) report  and  include all types of  air injection
(e.g.,   pulse-air)  in  addition   to   conventional  air  pump
control systems (3).

Data  for  1975  through  1978  light-duty  truck   I  technology
fractions  were  obtained by combining EPA fuel  economy  data
base sales  figures  by  engine displacement and model  type and
Federal  Certification  Test Results for  these  years  from the
Federal Register, Vol.  40,  No.  48, March  11,  1975 (11);  Vol.
41, No.  46, March  8,  1976  (12);  Vol.  42,  No.   110,  June 8,
1977 (13);  and  Vol. 43, No. 181,  Sept.  18,  1978  (14).   The
certification data provided  emission  control systems by model
type and engine  displacement which  were  matched with  fuel
economy sales fractions.

Heavy-duty  vehicles are   either   leaded   gasoline  or  diesel
fueled  (Table  14)  vehicles through  1986.   In  1987,  more
stringent  standards have been promulgated.  Therefore,  it is
assumed, for  the  purposes  of this  report, that  all  1987 and
later  gasoline  fueled trucks  in  the  heavy-duty  trucks  I
category  (less  than  14,001  Ibs.)  will  be   equipped  with
oxidation  catalysts and air  injection  and will  use  unleaded
gasoline.   All  1987 and later  gasoline-fueled trucks  in the
heavy-duty  truck  II category (greater  than 14,000  Ibs.)  are
assumed  in this  report to  still  use  leaded gasoline.   It
should be noted that other  EPA publications  may  use different
definitions of HDTI and HDTII.

The  effect of  discretionary fuel  switching  has  not  been
incorporated  in heavy-duty vehicle emission factor equations
due to the  lack of  data on  the  current  fuel purchase behavior
of owners of heavy-duty vehicles.   Also, as  new  estimates for

-------
                             -23-

heavy-duty fuel  economy  and new emission  standards  scenarios
become available, these equations will be revised accordingly.

Motorcycle  fractions  are  based on  2-stroke versus  4-stroke
emission   factor  estimates.    Before   1978,   most   on-road
motorcycle travel  was done  by  2-stroke vehicles  (53.4%)  and
slightly less  (46.6%) by 4-stroke  vehicles  according  to sales
figures  in the  1983  Motorcycle Statistical  Annual  published
by the Motorcycle  Industry Council,  Inc  (15).   In  1978,  more
stringent  control  of motorcycle  emissions caused nearly  all
motorcycle manufacturers  to build  4-stroke vehicles  for  on-
road  usage.   Therefore,  it is  assumed that all  motorcycles
from  1978  on  are 4-stroke vehicles  since  nearly all  2-stroke
mileage is accumulated off-road.

2.5    Organic,   Sulfate,    Diesel,   Heavy-Duty  Truck   and
       Motorcycle Emission Factors

Emission   factors    for   organics,    sulfates   and   diesel
particulates  for different  model  years, control systems,  fuel
types and  vehicle  speeds are  listed in Table  1.   This' table
also  refers the  user  to the proper  equation(s)  to  which  each
emission  factor  should be  applied.   All emission  factors  in
Table  1  are   expressed  in  grams  per   mile.    The  following
equations  should  be  used   for  the  calculation of  organic,
sulfate,  diesel,  heavy-duty  truck  and motorcycle  emission
factor components.
                   i
2.5.1  Organic Emission Factor Components

For i = 1,2,3    j = ri-19,...,1969   k=2

Equation 1.1.4
     EF.  .       = 0.193 MT (g/mile)
            _

-------
                             -24-




For i = 1,2,3    j =  1970,...,1974   k=2





Equati on 1.1.5
     EF.  . .   ,     0.068 MT  (g/mile)
       1 » J , K_ , Li            J-i
For i = 1,2,3    j  =  1975,...,n   k=2   TCi = from Table  18





Equation 1.1.6
     EF.  .        =  0.030 MT  (g/mile)

       i» D » Ko '
Equation 1.1.7



     EFi,j,k0,NL
where:





F.  .  _.,._       =     fraction of  the  unleaded vehicle  class  i
 n  "i  [^ A rp
 J. , J , \~t\ i

                    fleet  equipped with  a  catalyst  in  model


                    year j;





*"i  -i  MT Mor-AT-  =     fraction of  the  unleaded vehicle  class  i
 1 / J / JN .LJ g IN vJv^f\ X

                    fleet without a catalyst  in model year j.





2.5.2  Sulfate Emission Factor Components





For i = 1,2,3    j  = n-19,...,n   k=3   s = 19.6





Equation 1.1.8
     EF           =  0.002 M  (g/mile)
       1 » J / K-3 » •"            -I-1

-------
                             -25-
For i = 1,2,3   j = n-19,...,n   k=3   s = 34.8
Equat ion 1.1.9
     EF. .  ,   _  = 0.001 M_ (g/mile)
       i,u,k_,L           L
For i = 1,2,3   j = 1975,...,n   k=3   s = 19.6
Equation 1.1.10
EFi,j,k3,NL
'i)[(Fi,j,CAT/NOAIR}(°-005)(MNL,C)+(Fi,j,CAT/AIR)
where:
 i,j,CAT/NOAIR
  fraction  of  the  unleaded vehicle  class  i
  fleet  equipped with a catalyst  but no  air
  pump   in   model  year   j;   this   includes
  oxidation    catalyst    (F..         )     and
 three-way  catalyst
 with no air pump;
                                            (F..^  j/OXCAT)
                                          i f j , 3WCAT
                                                    ^  vehicles
Fi,j,CAT/AIR
 fraction  of  the. unleaded vehicle  class . i
 fleet  equipped with a catalyst  and an  air
 pump   in   model  year   j;   this   includes
 oxidation   catalyst  (F. ^ . ^ OXCAT/AIR)   and
 three-way     plus    oxidation     catalyst
 (Fi, j,3WCAT/OXCAT)   -vehicles    with    air
 pumps .

-------
                            -26-
For i = 1,2,3  j = 1975,. ..,n  k =3  s = 34.8  ri = from Table 18
Equation 1.1.11
EF          = (
  i,j,k3,NL
where :
Fi,j,OXCAT
fraction of the unleaded  vehicle  class  i
equipped with  an  oxidation  catalyst  but
no air pump in model year j.
 i,j,3WCAT
fraction of the  unleaded  vehicle  class i
equipped  with a three-way  catalyst  in
model  year  j.    (Note:   These  vehicles
are  sometimes equipped  with  air  pumps
that   are   usually   only  used   during
vehicle    start-up.     Therefore,    the
vehicle  category as  a  whole  is  assumed
to  emit sulfates  at  the same  rate  as
non-air    pump-equipped   vehicles    for
emission factor consideration.)
 i,j,OXCAT/AIR
fraction of the  unleaded  vehicle  class i
equipped with  an oxidation  catalyst  and
an air pump in model year j.
Fi,j,3WCAT/OXCAT
fraction of the  unleaded  vehicle  class i
equipped  with both  an oxidation and  a
three-way catalyst in model year j.

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                             -27-



2.5.3  Diesel Emission Factors (Light-Duty)





For i = 1   j = n-19,...,1980





Equation 1.1.12





     EF.     = 0.700 M  (g/mile)
       i / j , JJ          JJ



Mn     =   fraction  of  particles  less  than a  user specified


           size  cutoff  (0.1-10  urn)  that  are  emitted  from


           vehicles  that  are  fueled with  diesel  fuel,  from


           Table 19 or Figure 3 ;
For i = 1   j = 1981,...,1986




Equation 1.1.13
     EF.  • n = 0.320 Mn (g/mile)
       i, j , u          u
For i = 1   j = 1987, . .. ,n




Equation 1.1.14
     EF..  .   = 0.200 M_ (g/mile)
       i» J , L)      .    D   .
For i = 2,3   j = n-19,...,1980





Equation 1.1.15





     EF      = 0.800 Mn (g/mile)
       i i j i U          U

-------
                             -28-

For i = 2,3   j = 1981,...,1986

Equation 1.1.16

     EF. .  n = 0.280 Mn (g/mile)
       1 , J , U          LJ
For i = 2,3   j = 1987,...,n

Equation 1.1.17

     EF. .    = 0.260 M  (g/mile)


2.5.4  Heavy-Duty Truck Emission Factor Components

In this report, heavy-duty  trucks  are  divided  into two groups;
those less  than or  equal to 14,000 Ibs. GVW are  classified as
heavy-duty  trucks  I (i=4)  and  those  greater  than  14,000 Ibs.
GVW are classified  as  heavy-duty  trucks  II (i=5).  Calculation
of heavy-duty  truck I  emissions   is accomplished by  the same
procedure as light-duty emissions  by use of  Equation 1.1 (page
7)  and  the appropriate  emission  factor  component  equations
discussed   on   the   following  pages.    Heavy-duty   truck   II
emissions are  calculated  by a  slightly different procedure to
distinguish  between heavy-duty  truck  II  gasoline  and  diesel
mileage accumulation rates  and  vehicle age distribution, which
together determine  •travel  fraction by  vehicle  age.   Because
gasoline and diesel vehicles  in  the  HDT  II weight  class  are
characterized by different  travel fractions by vehicle  age,  a
single  travel  fraction  itu  .  does   not  exist,   and  it   is
necessary to keep the two vehicle types disaggregated.

Gasoline fueled heavy-duty  trucks  II  are  assumed to  use only
leaded  fuel for all model  years  (i.e.,  FMT   .   =  0 for  all
                                             'i 3 i j

-------
                             -29-
j).  Therefore,  equation 1.1  for  heavy-duty  trucks  II  (i=5)
is used as modified below.

Equation 1.1 (for i=5)
EF5,n,s =   S   t(EF5/jf     L + EF5/j/     + EP5f jf k  L)
          j=n-19                   .
  (F    ,)(m,r ,) + (EF      )(F    i)U5D  J3
    L,5,j   =>G,3       b , ] , L)   U,D,J    DU, j
where:
FT c  . = fraction of the heavy-duty truck  II fleet  designed
 ij i -> » 3
         for use on leaded gasoline in  model year  j, from
         Table 14.
Fn ,.  . = fraction of the heavy-duty  truck  II  fleet  designed
 \J i D , J
         for use on diesel  fuel  in model year j,  from  Table  14.

m5G  . =    travel   fraction  for  gasoline   fueled  heavy-duty
           trucks  II  in  model  year j,  from Table  15  (Note:
           mr:p  -; = m/i  -;as explained  in  Table  15);
            -)Vj i j    *» / j

nun  . =    travel  fraction  for diesel  fueled heavy-duty  trucks
 DL), J
           II in model year j , from  Table  16.

The  emission  factor  component  equations  for  both heavy-duty
trucks I  and  II are  listed below in  equations 1.1.18 through
For i = 4,5   j = n-19,...,1986   k  =  1   a   =  0.75
                                           s

Equation 1.1.18

     vv               (*  )(pbr   ) (1.557)  ,M .
     kr •   • i,    T      s    L,n          (M)
       i,3»k,,n,L    	—	   L
                           c, i, j

-------
                             -30-




For i = 4  j = 1987,..., n  k = 1  a  = 0.30  r  = from Table 18
                                               "
Equation 1.1.19
                      U-r4)(as)(PbNL>n)(1.557)  (
        :,j,k,,n,NL    	5	   NL,C

                               c,4, j


                   +  (r4)(as)(PbL/n)(1.557)



                              Ec,4,j
For i = 5   j = 1987,...,n   k  =  1    a  = 0.75
                                       s
Equation 1.1.20
                      (a  )(Pb    )(1.557)
       t-  . .     T =    s    L,n	  (MT
       D , j , K  , n, LJ    	=	   i

            1             c,5,j
For i = 4,5   j = n-19,...,1986   k =  2




Equation 1.1.21
     EF.        = 0.370 MT  (g/mile)

       1»D'^/
For i = 4   j = 1987,	,n   k = 2   r4 =  from Table  18



                                                             r-


Equation 1.1.22






     EF4,j,k ,NL = d-r4)(0.054)(MNLfC)+(r4)(0.370)(ML)  (g/mile)

-------
                             -31-



For i = 5   j = 1987,...,n   k = 2




Equation 1.1.23
     EF_  . ,   _ = 0.370 MT  (g/mile)
       5 , ] , K9 ,Li          J-.
For i = 4,5   j = n-19,...,1986   k  =  3




Equation 1.1.24




     EF^^  . k  L = 0.006  ML (g/mile)
For i = 4   j = 1987,..., n   k  =  3    r.  =  from  Table  18




Equation 1.1.25
     EF4,j,k  ,NL =  d-r4)(0.048)(MNLjC)+(r4)(0.006)(ML)  (g/mile)
For i = 5   j = 1987,.. .,n   k  =  3




Equation 1.1.26
     EF.  .      = 0.006 MT  (g/mile)
       3 / J , K^ , J-i          J-i

-------
                             -32-




For i = 4   j = n-19,...,1982






Equation 1.1.27
     EF4,j,D = 1-423 MD
For i = 4   j = 1983,..., n






Equation 1.1.28
     EF4,j,D = 1-188 MD
For i = 5  j = n-19,...,n






Equation 1.1.29






     EF5jj>D = 1.954 MD (g/mile)






2.5.5      Motorcycle Emission Factors






For i = 6  j = n-19, ... ,1977






Equation 1.1.30






     EF6,j,L = r(0.466).(0.046) + (0.534)(0.330)](ML)





             = 0.198 M_ (g/mile)

-------
                             -33-

For i = 6  j = 1978,...,n

Equation 1.1.31
     EF,_  . T = 0.046 MT (g/mile)
       D , ] , J-i          L,
2.6    Brake   and   Tire  Wear   Particulate   Emission  Factor
       Components

Additional  sources  of  motor  vehicle  particulate  emissions
include  brake  and  tire  wear  emission components.   Limited
testing  has  been performed  to  estimate the  contributions of
brake and tire  wear emissions to the total light-duty vehicle
particulate  emission  rate.   No  data  exist  on  the  rate at
which  light-duty trucks, heavy-duty  vehicles,  or motorcycles
emit brake and  tire wear emissions.   The  user should be aware
that brake and tire  wear particulates  are  emitted from these
vehicle  classes  at   different  rates   than  the  light-duty
vehicle  rate,  but  since  no  data  exists,  the  light-duty
vehicle  rate  is used  to estimate  their contribution to total
particulate emission rates.

Brake  wear  emissions   from  light-duty  vehicles  have  been
measured in  a  recent  study and have  been  found  to consist of
significant   quantities  of  particulate   in   the   airborne
particle size  range.   Airborne  particulate emission  rates for
.brake"  wear    particles  as   measured  on  braking   cycles
representative  of  urban driving  averaged  0.0128 grams  per
mile  for light-duty  gasoline  vehicles (42).   Particle  size
distribution  for brake wear  particulate  (MB) is  included in
this reference  and is  summarized in Table  19.    The  rate of
0.0128  g/mile  times the  appropriate fraction of M_,  for  the
                                                    o
particle  size  cutoff   of  interest  should be   added  to  any
calculation of particulate emissions  less  than  10 microns for
all  classes   of vehicles.    In  the  example  calculation  in

-------
                             -34-

Section  3.0 of  this  report,   for  example,  M_  =  0.98,  the
                                               D
brake  wear  particulate   emission  rate  is  therefore  0.0125
g/mile and  the  total light-duty vehicle particulate  emission
rate   is    0.0731   g/mile.    In   this  particular   example,
therefore,  brake wear  emissions account for 17% of  the total
particulate emission rate.

Tire wear  particulate  is  generally larger  in  size  than brake
wear particulate and therefore  consists of  fewer  particles in
the  airborne size  range.  Emission  rates  for airborne  tire
wear particulate  for  light-duty  vehicles  has been  estimated
at  0.002  g/mile   (43,44).    This  rate  should  be  added  to
calculations  of  particulate  emissions less  than  10  microns
for all classes of  vehicles.  The  addition  of 0.002 g/mile in
the  example   calculation  in  Section  3.0   indicates  that
airborne  tire  wear particulate accounts  for  about 3%  of the
total light-duty particulate emission rate.

No  data  on airborne particle size distribution  are available
for  analyses  of   tire wear particulate   emission  rates  at
smaller  particle   size   cutoffs   (i.e.,   2.5   microns   or  7
microns).   The  user  should  either  interpolate between  zero
and  10 microns to  determine the appropriate emission rate for
the  distribution  of  tire  wear particles  below  the  desired
size cutoff (e.g.,  at  7  microns tire  wear  emissions  =  0.0014
g/mile  and  at  2.5 microns tire  wear  emissions  =  0.0005
g/mile)  or simply  neglect  tire wear particulate since it is
likely to be negligible in  these smaller particle size  ranges.

Another  source  of  particulate  emissions  for which  emission
factors  could be  developed  is reentrained  particulate  from
particles   that . have  been  deposited  on  road  surfaces  or
possibly   road  material   itself.    While   information  is
available  on these reentrained particulates  (46,   47),  they
are  not  considered to be directly emitted by mobile  sources
and therefore are not  included  in this report.

-------
         Table 1
Emission Factors of Motor
Vehicle Engine Total Particulate Emissions
Applicable Participate Cbntrol
MDdel Year(s) Component System
Light-Duty
Pre-1970
1970-1974
1975+
1975+
1975+
1975+
All
1975+
Pre-1975
1975+
1975+
1975+
1975+
1975+
1975+
1975+
1975+
1975+
1975+
Light-Duty
Pre-1981
1981-1986
1987+
Pre-1981
1981-1986
1987+
Heavy-Duty
Pre-1987
1987+
Type of
FXiel Used
Vehicle
Speed
(MPH)
Emission
Factor
(grama/mile)
Emission
Equation Factor Source
Used In Reference No.
Gasoline Vehicles and Trucks:
Organic
Organic
Organic
Organic
Organic
Organic
Sulfate
Sulfate
Sulfate
Sulfate
Sulfate
Sulfate
Sulfate
Sulfate
Sulfate
Sulfate
Sulfate
Sulfate
Sulfate
Diesel Vehicles
All LDDV
All LDDV
All LDDV
All LDDT
All LDDT
All LDDT
Gasoline Trucks:
Organic
Organic
NOCAT
NOCAT
NOCAT
CAT
CAT
NOCAT
NOCAT
CAT
NOCAT
CAT/NOAIR(f)
CAT/AIR(g)
NOCAT
NOCAT
NOCAT
OXCAT/NOAIR
3WCAT
OXCAT/AIR
3WCAT/QXCAT
CAT
and Trucks:

—
_
_
_
-

NOCAT
CAT/AIR
Leaded
Leaded
Leaded
Unleaded
Leaded
Uhleaded
Leaded
Leaded
Leaded
Unleaded
Unleaded
Unleaded
Leaded
Unleaded
Unleaded
Unleaded
Unleaded
Unleaded
Leaded

Diesel
Diesel
Diesel
Diesel
Diesel
Diesel

Leaded
Unleaded
All
All
All
All
All
All
19.6
19.6
34.8
19.6
19.6
19.6
34.8
34.8
34.8
34.8
34.8
34.8
34.8

All
All
All
All
All
All

All
All
0.193
0.068
0.030
0.017
0.068
0.030
0.002
0.002
0.001
0.005
0.016
0.002
0.001
0.001
0.005
0.001
0.020
0.025
0.001

0.700
0.320
0.200
0.800
0.280
0.260

0.370
0.054
1.1.4
1.1.5
1.1.6,7
1.1.7
1.1.7
1.1.7
1.1.8,10
1.1.8,10
1.1.9
1.1.10
1.1.10
1.1.10
1.1.9
1.1.11
1.1.11
1.1.11
1.1.11
1.1.11
1.1.11

1.1.12
1.1.13
1.1.14
1.1.15
1.1.16
1.1.17

1.1.21,23
1.1.22
10
10
10(a)
10(b)
10(c)
10(a)(h)
10
10 (d)
2
10
10
10(e)
2
2
2
2
2
2
2(d)

4
4(i)
4
4
4
4

10
10
                                                                         Ul
                                                                         I

-------
                                            Table 1  (cont'd)
                                        Bnission Factors of Mator
                               Vehicle Efrgine Total Participate Emissions
Applicable
ttxJel Year(s)
Pre-1987
1987+
Participate
Component
Sulfate
Sulfate
Control
System
NOCAT
CAT/AIR
"type of
Fuel Used
Leaded
Unleaded
Vehicle
Speed
(MPH)
All
All
Emission
Factor
(grains /mile)
0.006
0.048
Equation
Used In
1.1.24,26
1.1.25
Bnission
Factor Source
Reference No.
10
10
Heavy-duty Diesel Trucks;
Pre-1983
1983+

All
Motorcycles;

All
All
All HDDT1
All HDDT1

All HDDT2
4-Stroke
2-Stroke
Diesel
Diesel

Diesel
Leaded
Leaded
All
All

All
All
All
1.423
1.188

1.954
0.046
0.330
1.1.27
1.1.28

1.1.29
1.1.30,31
1.1.30
10
10

10
 2
 2
                                                                                                                 o\
                                                                                                                  I
(a)Ratio 1.5/3.4 of 1970-74 organic value.
(b)  Combined value of organic from catalyst/no air and catalyst/air vehicles.
(c)  Same as 1970-74 no catalyst leaded organic value.
(d)  Misfueled vehicles.
(e)  Same as no catalyst leaded value.
(f)  Includes oxidation catalyst vehicles and three-way catalyst vehicles without air pumps.
(g)  Includes oxidation catalyst vehicles and three-way plus oxidation catalyst vehicles with air pumps.
(h)  Value should actually be higher for the light-duty truck II class (much like the 1970-74 organic
     value) but no data exist.
(i)  The average LDCV emission factor for  1981  through  1986 is 0.320 g/mile.  "Hiis  emission factor was
     obtained by  averaging the  factor of  0.270 g/mile  for 1981  through 1984  (appropriate for a 1.5
     g/mile  NOx standard)  and  0.420 g/mile  for  1985  and  1986  (appropriate  for a 1.0  g/mile  NQx
     standard).  Both factors are used in reference 4.

-------
                             -37-

                           Table 2

                   Lead  Content  of  Gasoline

                       Leaded Gasoline*      Unleaded Gasoline
Year                       (g/gal)               (g/gal)	

1974                        1.79
1975                        1.82                  0.014
1976                        2.02                  0.014
1977                        2.03                  0.014
1978                        1.94                  0.014
1979                        1.85                  0.014
1980                        1.38                  0.014
1981                        1.15                  0.014
1982                        1.24                  0.014
1983                        1.14                  0.014
1984                        1.1                   0.014
1985                        1.1                   0.014
1986                        1.1                   0.014
1987                        1.1                   0.014
1988                        1.1                   0.014
1989                        1.1                   0.014
1990                        1.1                   0.014
"1974-1982:Lead content based upon data  submitted  to EPA on
historical sales data for leaded  gasoline  and  data indicating
the  actual  pooled  average  lead  content.   The  value  for
unleaded gasoline is based on recent MVMA fuel surveys.

1983-1990:  Lead content  based upon requirements  for average
lead content  of leaded  gasoline.  During  the  first  half  of
1983, small refineries were  subject to a  pooled  average lead
standard.

-------
                                                          Table 3

                                            Fraction of Light-Duty Vehicle Model
Year Sales Equipped with Different
Control
System
FL,I,J
Fl,j,NL,NOCAT
Fl, j,aXCAT/NOAIR
Fl.j,OXCAT/AIR
Fl,j.3WCAT
pl. J.3WCAT/CIXCAT
FD,l.j
Fl,j.CAT
Fl,j,CAT/NOAIR
pl. CAT/AIR
Pre-
1975
1.000
o
0
0
0
o
0
0
0
0
1975
.127
.081
.597
.322
. 0
0
0
.919
.597
.322
1976
.132
.020
.637
.343
0
0
0
.980
.637
.343
1977
.157
0
.650
.350
0
0
0
1.000
.650
.350
Emission
Systems (Low-Altitude Non-California)
1978
.131
0
.650
.350
0
0
.030
1.000
.650
.350
1979
.090
0
.640
.345
.015
0
.040
1.000
.655
.345
1980
.041
0
.421
.514
.053
.012
.050
l.OOO
.474
.526
1981
0
0
.033
.099
.263
.605
.061
1.000
.296
.704
1982
0
0
0
.140
.320
.540
.047
1.000
.140
.860
1983
0
0
0
.120
.220
.660
.024
1.000
.180
.820
1984
0
0
0
0
.400
.600
.030
1.000
.240
.760
1985
0
0
0
0
.530
.470
.054
1.000
.370
.630
1986
0
0
0
0 '
.550
.450
.063
1.000
.440
.560
1987
0
0
0
0
.570
.430
.072
1.000
.520
.480
1988+
0
0
0
0
.600
.400
.082
1.000
.530
.470
Sources:  U.S. EPA Emission Factor In-Use Test Vehicle Data Dase.
          EEA Forecasts of Emission Control Technology 1983-1990.
          U.S. EPA Fuel Economy Data Dase.
          Anti-Tampering and Anti-Misfueling Programs to Reduce In-Use Emissions from Motor Vehicles.

Mote:     Model year columns don't add up to 1.000.  Only FL, 1, j and FD,1, j are fractions of all IXVs.  All other
          systems are fractions of all unleaded LDVs.

-------
                             -39-

                               Table  4

                        FLEET SALES FRACTIONS

                         Light-Duty Vehicles
Model
Years


Pre-1975
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988+

WHERE:

FNL,I,j


FL,I,J


FD,I,J
Unleaded Gasoline
 Fraction of LDV
  Fleet, FNL>lyj*


      0.000
      0.873
      0.868
      0.843
      0.839
      0.870
      0.909
      0.939
      0.953
      0.976
      0.970
      0.946
      0.937
      0.928
      0.918
Leaded Gasoline
Fraction of LDV
 Fleet, FL,I,J*


     1.000
     0.127
     0.132
     0.157
     0.131
     0.090
     0.041
     0.000
     0.000
     0.000
     0.000
     0.000
     0.000
     0.000
     0.000
Diesel Fraction of
LDV Fleet, FD>1,j*


      0.000
      0.000
      0.000
      0.000
      0.030
      0.040
      0.050
      0.061
      0.047
      0.024
      0.030
      0.054
      0.063
      0.072
      0.082
    Estimated fraction of the  LDV  fleet  which use unleaded
    gasoline in model year j;

    Estimated fraction  of the LDV  fleet which  use  leaded
    gasoline in model year j ;

    Estimated fraction  of the LDV  fleet which  use  diesel
    fuel in model year j.
*Diesel and  gasoline sales  projections  were made  by EPA  based on
data  obtained  from  Energy and  Environmental  Analysis,  Inc.,   "The
Highway Fuel Consumption  Model:   Tenth Quarterly  Report,"  November
1983.

Percentages  of gasoline  vehicles  requiring leaded  and  nonleaded
fuel  obtained  from  Energy   and  Environmental  Analysis,    Inc.
"Documentation for the New Highway  Fuel  Consumption Model", January
1982.

-------
                            -40-

                             Table 5

               TRAVEL WEIGHTING FACTOR CALCULATION*

                       Light-Duty Vehicles
              (a)
            January 1
            Fraction
Vehicle
Age
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20+
Total
Registration**
0.025
0.106
0.096
0.074
0.096
0.108
0.093
0.074
0.069
0.062
0.050
0.037
0.031
0.024
0.016
0.010
0.005
0.003
0.002
0.016
    (b)
   Annual
   Mileage
Accumulation
    Rate
                                          (a) (b)
C(a)(b)/(SUM)]

 Fraction of
LDV Travel by
Model Year,
14400
14275
13775
13250
12675
12175
11650
11075
10575
10050
9475
8975
8450
7875
7375
6850
6275
5775
5275
4750
360.0
1513.2
1322.4
980.5
1216.8
1314.9
1083.5
819.6
729.7
623.1
473.8
332.1
262.0
189.0
118.0
68.5
31.4
17.3
10.6
76.0
0.031
0.131
0.115
0.085
0.106
0.114
0.094
0.071
0.063
0.054
0.041
0.028
0.023
0.016
0.010
0.006
0.003
0.002
0.001
0.006
                                SUM:
             11542.4
Compilationof Air  Pollutant Emission Factors:   Highway Mobile
Sources, March  1981,  [EPA-460/3-81-005].   The  travel  weighting
fractions reflect a January 1 evaluation date.

**January 1 fractions of total registration differ  from those in
the cited source because  they have been normalized to  add  up to
1.000.  The  cited  source  performed on equivalent  normalization
at a later stage in its calculation.

-------
-41-
Table 6
Ci


Model Year
Pre-1970
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988+
ty/Highway

Fuel
LDV
13.9
13.9
13.2
13.1
12.9
12.6
13.9
14.9
15.6
16.7
18.5
19.6
21.8
23.3
24.6
26.0
27.4
28.8
30.2
31.6
Combined
On-Road
Fuel Economy*

(miles/gallon)
Economy,
LDT1
10.6
10.6
10.4
10.2
9.9
9.6
12.0
12.6
13.8
14.3
15.2
16.3
18.1
18.4
18.9
19.5
20.2
21.1
22.0
22.9
Ec , i , j
LDT2
7.9
7.9
7.7
7.4
7.0
6.9
8.8
9.7
9.4
9.6
9.8
11.5
13.3
13.8
14.3
14.9
15.4
16.0
16.6
17.2


HDT1 HDT2
7.6
8.0
8.0
8.0
8.4
8.7
9.1
9.2
9.4
9.2
9.7
10.2
10.7
11.3
11.5
11.8
12.0
12.4
12.7
13.1
5.5
5.1
5.0
5.0
5.0
5.0
5.0
5.1
5.1
5.2
5.1
5.1
6.0
6.3
6.5
6.7
6.9
7.1
7.3
7.5
*Fuel economies  for  model years  1980-1988  were  obtained from
Energy  and  Environmental  Analysis,  Inc.,  "The  Highway  Fuel
Consumption  Model   -   Tenth  Quarterly  Report"   (U.S.   DOE
Contract  Number  DE-AC01-80IE-11972,  Task  No.   8,  November
1983).   Fuel   economies   for  model  years   1970-1979  were
obtained from Robert Dulla, EEA.

-------
                            -42-

                           Table 7

    Fuel Economy Correction Factors at Various Speeds,  Cs
   	(Normalized to 32.7 miles/hour-cyclic driving)	

                             Cs                  Cs
     Speed (mph)        Cyclic Driving        Steady Cruise
(-FTP)
(-SET)
5
10
15
9 O, 	
25
30
32.7
0 C 	 	
40
45
50
55
60
0.323
0.553
0.692
07 an 	
0.885
0.963
1.000
	 	 i H99 — 	
1.053
1.073
1.078
1.063
1.023
0.467
0.709
0.997
	 	 1 1 C 0
1.248
1.294
1.303
	 i on^
1.288
1.256
1.210
1.159
1.104

-------
                                                          Table 8
Fraction of Light-Duty Truck I
Year Sales Equipped with Different
Control
System
FL.2,j
F2,j,NL,NCCAT
F2,j.OXCAT/NCAIR
F2.j,OXCAT/AIR
F2.j.3WCAT
F2,j,3WCAT/OXCAT
FD.2,j
P2,j,CAT
F2,j,CAT/NCAIR
F2, CAT/AIR
Pre-
1975
1.000
0
0
0
0
0
0
0
0
0
1975
.188
.123
.570
.307
0
0
0
.877
.570
.307
1976
.088
.225
.504
.271
0
0
0
.775
.504
.271
1977
.038
.083
.596
.321
0
0
0
.917
.596
.321
Model






Emission
Systems (Low-Altitude Non-California)
1978
.027
.069
.605
.325
0
0
.005
.930
.605
.325
1979
.032
.034
.561
.405
0
0
.011
.966
.561
.405
1980
.023
.027
.564
.409
0
0
.021
.973
.564
.409
1981
0
.011
.574
.415
0
0
.084
.989
.574
.415
1982
0
0
.400
.500
.100
0
.067
1.000
.500
.500
1983
0
0
.300
.500
.200
0
.061
1.000
.500
.500
1984
0
0
.150
.450
.400
0
.056
1.000
.250
.750
1985
0
0
.150
.450
.400
0
.050
1.000
.250
.750
1986
0
0
.150
.450
.400
0
.075
1.000
.250
.750
1987
0
0
0
.150
.850
0
.100
1.000
.250
.750
1988+
0
0
0
.150
.850
0
.125
1.000
.250
.750
                                                                                                                            OJ
                                                                                                                             I
Sources:  U.S. EPA Emission Factor In-Use Test Vehicle Dbta Base.
          U.S. EPA Fuel Economy Eata Base.
          U.S. EPA Federal Register:  Federal Certification Test Results 1975-78.
          Anti-Tampering and Anti-Misfueling Programs to Reduce In-Use Emissions from Motor Vehicles.
tbte:     Model year columns don't add up to 1.000.  Only FLf2,j and
          systems are fractions of all unleaded LOTls.
                                                                       ^, j are fractions of all LDTls.  All other

-------
                             -44-
                               Table  9

                        FLEET  SALES FRACTIONS

                         Light-Duty Trucks  I
Model
Years


Pre-1975
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988+

WHERE:
FL,2,j


FD,2,j
Unleaded Gasoline
Fraction of LDT1
 Fleet, FNL,2,j*

     0.000
     0.812
     0.912
     0.962
     0.968
     0.957
     0.956
     0.916
     0.933
     0.939
     0.944
     0.950
     0.925
     0.900
     0.875
 Leaded Gasoline
Fraction of LDT1
 Fleet, FL>2,j*

     1.000
     0.188
     0.088
     0.038
     0.027
     0.032
     0.023
     0.000
     0.000
     0.000
     0.000
     0.000
     0.000
     0.000
     0.000
Diesel Fraction of
LDT1 Fleet, FD>2,j*

      0.000
      0.000
      0.000
      0.000
      0.005
      0.011
      0.021
      0.084
      0.067
      0.061
      0.056
      0.050
      0.075
      0.100
      0.125
FNL,2,j   =  Estimated fraction of  the  LDT1  fleet  which use unleaded
   gasoline in model year j;

   Estimated  fraction  of the LDT1  fleet which  use  leaded
   gasoline in model year j;

   Estimated  fraction  of the LDT1  fleet which  use  diesel
   fuel in model year j.
*Diesel  and  gasoline  sales  projections  were  made  by EPA  based  on
data  obtained  from  Energy and  Environmental  Analysis,   Inc.,  "The
Highway  Fuel  Consumption Model:   Tenth Quarterly  Report,"  .November
1983.

Percentages of gasoline  vehicles requiring leaded  and unleaded fuel
obtained from Energy and  Environmental  Analysis,  Inc. "Documentation
for the New Highway Fuel Consumption Model", January 1982.

-------
Vehicle
  Age


 1
 2
 3
 4
 5
 6
 7
 8
 9
10
11
12
13
14
15
16
17
18
19
20+
                             -45-

                             Table 10

               TRAVEL WEIGHTING FACTOR CALCULATION*

                       Light-Duty  Trucks  I**
    (a)
  January 1
  Fraction
  of Total
Registration***


    0.034
    0.101
    0.091
    0.065
    0.098
    0.106
    0.081
    0.064
    0.047
    0.051
    0.049
    0.035
    0.038
    0.035
    0.028
    0.023
    0.016
    0.012
    0.011
    0.014
    (b)
   Annual
   Mileage
Accumulation
    Rate


   15600
   15200
   13625
   12175
   10925
    9925
    9200
    8450
    7875
    7375
    6900
    6500
    6125
    5800
    5425
    5150
    4925
    4625
    4400
    4400

      SUM:
 530.4
1535.2
1239.9
 791.4
1070.7
1052.1
 745.2
 540.8
     1
     1
     1
     ,5
 370,
 376,
 338,
 227 ,
 232.8
 203.0
 151.9
 118.5
  78.8
  55.5
  48.4
  61.6

9768.0
[(a)(b)/(SUM)]

 Fraction of
LDT1 Travel by
Model Year, n^j


    0.054
    0.157
    0.127
    0.081
    0.110
    0.108
    0.076
    0.055
    0.038
    0.039
    0.035
    0.023
    0.024
    0.021
    0.016
    0.012
    0.008
    0.006
    0.005
    0.006
Compilation of  Air  Pollutant Emission  Factors:   Highway Mobile
Sources,  March 1981,  [EPA-460/3-81-005].   The  travel  weighting
fractions reflect a January 1 evaluation date.

**Light-duty trucks  I have a  gross vehicle  weight  (GVW) rating
of 6000 pounds or less.

***January  1  fractions of  total  registration differ  from those
in the  cited source  because they have been normalized  to add up
to   1.000.    The   cited   source   performed   an   equivalent
normalization at a later stage in its calculation.

-------
                                                          Table 11

                                               Fraction of Model Year Sale of
Light-Duty Trucks II by Emission Control Systems
System
FL,3,j
F3, j.NL.NOCAT
F3,j,OXCAT
F3, j.OXCAT/AIR
F3,j,3VKAT
F3 , j . 3WCAT/OXCAT
FD,3.j
F3,j,CAT
F3,j,CAT/NOAIR
F3, CAT/AIR
Pre-
1975
1.000
0
0
0
0
0
0
0
0
0
1975
1.000
0
0
0
0
0
0
0
0
0
1976
1.000
0
0
0
0
0
0
0
0
0
1977
1.000
0
0
0
0
0
0
0
0
0
1978
.988
0
0
0
0
0
.012
0
0
0
1979
0
.008
.496
.496
0
0
.025
.992
.496
.496
1980
0
0
.500
.500
0
0
.050
1.000
.500
.500
1981
0
0
.500
.500
0
0
.050
1.000
.500
.500
1982
0
0
.500
.500
0
0
.080
1.000
.500
.500
1983
0
0
.500
.500
0
0
.113
1.000
.500
.500
1984
0
0
.150
.450
.400
0
.147
1.000
.250
.750
1985
0
0
.150
.450
.400
0
.180
1.000
.250
.750
1986
0
0
.150
.450
.400
0
.194
1.000
.250
.750
1987
0
0
0
0
.850
0
.208
1.000
.250
.750
1988+
0
0
0
0
.850
0
.222
1.000
.250
.750
Source:.  U.S. EPA Emission Factor In-Use Itest Vehicle Data Base.
         Anti-Tampering and Anti-Misfueling Programs to Reduce In-Use Emissions from Motor Vehicles.

Note:    Model year columns don't add up to 1.000.  Only FL(3 j and ^,3, j are fractions of all LDT2s.  All other
         systems are fractions of all unleaded LDT2s.      '

-------
                             -47-

                              Table 12

                        FLEET SALES  FRACTIONS

                        Light-Duty Trucks II
          Unleaded Gasoline
Model     Fraction of LDT2
Years      Fleet, FNL,3,j*

Pre-1975       0.000
1975           0.000
1976           0.000
1977           0.000
1978           0.000
1979           0.975
1980           0.950
1981           0.950
1982           0.920
1983           0.887
1984           0.853
1985           0.820
1986           0.806
1987           0.792
1988+          0.778
                      Leaded Gasoline
                     Fraction of LDT2
                      Fleet, FL>3,j*


                          1.000
                          1.000
                          1.000
                          1.000
                          0.988
                          0.000
                          0.000
                          0.000
                          0.000
                          0.000
                          0.000
                          0.000
                          0.000
                          0.000
                          0.000
Diesel Fraction of
LPT2 Fleet, FD>3,j*


      0.000
      0.000
      0.000
      0.000
      0.012
      0.025
      0.050
      0.050
      0.080
      0.113
      0.147
      0.180
      0.194
      0.208
      0.222
WHERE:

FNL,3,j


FL,3,j


FD,3,j
=  Estimated fraction of the LDT2  fleet  which use unleaded
   gasoline in model year j ;

=  Estimated fraction  of the LDT2  fleet which use  leaded
   gasoline in model year j;

=  Estimated fraction  of the LDT2  fleet which use  diesel
   fuel in model year j.
*Diesel  and  gasoline  sales  projections  were  made  by EPA  based  on
data  obtained  from  Energy and. Environmental  Analysis,   Inc.,  "The
Highway  Fuel  Consumption Model:   Tenth Quarterly  Report,"  November
1983.

Percentages of gasoline vehicles requiring  leaded  and nonleaded fuel
obtained   from    Energy   and    Environmental    Analysis,    Inc.,
"Documentation for  the New Highway Fuel  Consumption Model",  January
1982. '

-------
                             -48-
                              Table  13

                TRAVEL WEIGHTING  FACTOR CALCULATION*

                      Light-Duty Trucks II**
              (a)
            January 1
            Fraction
Vehicle     of Total
  Age     Registration***


 1            0.098
 2            0.247
 3            0.185
 4            0.116
 5            0.068
 6            0.067
 7            0.047
 8            0.036
 9            0.027
10            0.024
11            0.020
12            0.013
13            0.012
14            0.010
15            0.006
16            0.007
17            0.005
18            0.004
19            0.004
20+           0.005
    (b)
   Annual
   Mileage
Accumulation
    Rate


   15800
   15400
   13800
   12300
   11125
   10100
    9300
    8550
    7975
    7475
    6975
    6525
    6225
    5875
    5425
    5175
    5000
    4625
    4400
    4400

      SUM:
          C(a)(b)/(SUM)]

           Fraction of
          LDT2 Travel by
 (a)(b)    Model Year, m3/


 1548.4        0.125
 3803.8        0.306
 2553.0        0.206
 1426.8        0.115
  756.5        0.061
  676.7        0.055
  437.1        0.035
  307.8        0.025
  215.3        0.017
  179.4        0.014
  139.5        0.011
   84.8        0.007
   74.7        0.006
   58.8        0.005
   32.6        0.003
   36.2        0.003
   25.0        0.002
   18.5        0.001
   17.6        0.001
   22.0        0.002

12414.5
Compilation of  Air  Pollutant Emission Factors:   Highway Mobile
Sources,  March 1981,  [EPA-460/3-81-005].   The  travel  weighting
fractions reflect a January 1 evaluation date.

**Light-duty trucks  II have  a gross vehicle  weight  (GVW) rating
of 6001 to 8500 pounds.

***January 1  fractions of total  registration differ  from  those
in the  cited  source  because they  are  normalized to  add up  to
1.000.  The  cited source  performed an equivalent  normalization
at a later stage of its calculation.

-------
                                    -49-

                                   Table  14

                            FLEET SALES FRACTIONS

                         Heavy-Duty Trucks I and II*
Model
Years
-

Pre-1977
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
                 Gasoline
                Fraction of
                HDT1 Fleet,
               . .or F..   . .
             L'4O      NL,4,]

             1.000 (LEADED)
             1.000
             1.000
             1.000
             1.000
             1.000
             0.838
             0.820
             0.803
             0.785
             0.772
             0.759 (UNLEADED)
             0.746
             0.733
             0.720
             0.716
             0.712
             0.708
             0.704
             0.700
   Diesel
Fraction of
HDT1 Fleet,

  FD.4,j

   0.000
   0.000
   0.000
   0.000
   0.000
   0.000
   0.162
   0.180
   0.197
   0.215
   0.228
   0.241
   0.254
   0.267
   0.280
   0.284
   0.288
   0.292
   0.296
   0.300
Gasoline
Fraction of
HDT2 Fleet,
p **
L,5, j
0.623
0.468
0.440
0.412
0.472
0.330
0.360
0.344
0.327
0.311
0.303
0.295
0.288
0.280
0.272
0.264
0.256
0.248
0.240
0.232
(LEADED)
n
n
it
ti
it
H
n
ii
M
II
II
II
II
11
II
II
II
II
II
   Diesel
Fraction of
HDT2 Fleet,
  FD,5,j
   0.
   0.
 .377
 .532
0.560
0.588
0.528
0.670
0.640
0.656
0.673
0.689
0.697
0.705
0.712
0.720
0.728
0.736
0.744
0.752
0.760
0.768
  *Heavy-dutytrucks  I  are  assumed  to  have  a  gross  vehicle weight  (GVW)
rating  of 8,501  to  14,000  pounds  for  this  report.   The  reason for  the
14,000 pound  cutpoint is that it  is projected that catalysts will be  used
in 1987 and  beyond  on gasoline HDTs with  a  GVW of 14,000 pounds  or  under.
Heavy-duty  trucks   II  are assumed  to have  a  gross  vehicle weight  (GVW)
rating greater than 14,000 pounds for this report.

**The estimated  fractions of the HDT1 and HDT2  model  year  fleets  which are
gasoline-powered are based on  sales  projections  by Energy and Environmental
Analysis,   Inc.,  "The  Highway  Fuel  Consumption  Model:   Tenth  Quarterly
Report,"  November  1983.  Gasoline HDTls use leaded  fuel through the  1986
model year  and  are  all  unleaded from  1987  on.   All  gasoline  HDT2s  use
leaded fuel for all model years.

-------
                             -50-

                            Table 15

              TRAVEL WEIGHTING FACTOR CALCULATION*

                      Heavy-Duty Trucks  I**
                and  Heavy-Duty  Gasoline  Trucks  II
Vehicle
  Age


 1
 2
 3
 4
 5
 6
 7
 8
 9
10
11
12
13
14
15
16
17
18
19
20+
    (a)
  January 1
  Fraction
  of Total
Registration***


    0.0
    0.131
    0.112
    0.084
    0.098
    0.101
    0.081
    0.061
    0.047
    0.050
    0.045
    0.035
    0.034
    0.030
    0.024
    0.020
    0.015
    0.011
    0.009
    0.011
    (b)
   Annual
   Mileage
Accumulation
    Rate


       0
   21000
   18900
   17200
   15500
   14100
   12600
   11300
   10300
    9400
    8600
    8000
    7300
    6700
    6300
    5900
    5500
    5200
    5000
    5000

     SUM:
    0.0
 2741.7
 2110.1
 1449.1
 1524.4
 1425.5
 1018.2
  691.7
  487.6
  473.0
  390.4
  280.6
  250.2
  200.4
.  148.8
  119.7
   81.3
   54.8
   47.0
   55.6

13550.2
[(a)(b)/(SUM)]
  Fraction of
HDT1 Travel by
  Model Year,
m4> j and m5G> j


     0.000
     0.202
     0.156
     0.107
     0.113
     0.105
     0.075
     0.051
     0.036
     0.035
     0.029
     0.021
     0.019
     0.015
     0.011
     0.009
     0.006
     0.004
     0.003
     0.004
Compilation of  Air  Pollutant Emission Factors:   Highway Mobile
Sources,  -March  1981,  [EPA-460/3-81-005].   These  are  MOBILE2
heavy-duty gasoline  travel  fractions  (for gasoline-fueled trucks
over 8,501 pounds)  which are used  in  this report for  all  HDTls
(trucks greater  than 8,501 pounds  and less than  14,000 pounds)
and all HDGT2s (gasoline-fueled  trucks  over  14,001 pounds).   The
travel weighting fractions reflect a January 1 evaluation date.

**Heavy-duty trucks I are assumed in this  report  to  have a  gross
vehicle weight  (GVW)  rating  greater than 8,501 pounds  and  less
than 14,000 pounds.

***January 1  fractions  of total  registration  differ  from  those
in the  cited source  because  they  are  normalized to  add up  to
1.000.   The  cited source performed an equivalent  normalization
in a later stage of its calculation.

-------
Vehicle
  Age

 1
 2
 3
 4
 5
 6
 7
 8
 9
 10
 11
 12
 13
 14
 15
 16
 17
 18
 19
 20+
                             -51-

                             Table 16

               TRAVEL WEIGHTING FACTOR CALCULATION*

                   Heavy-Duty Diesel  Trucks  II**
    (a)               (b)
  January 1         Annual
  Fraction          Mileage
  of Total       Accumulation
Registration***      Rate
                                                    C(a)(b)/(SUM)]
    0.0
    0.172
    0.104
    0.065
    0.120
    0.113
    0.088
    0.063
    0.051
    0.051
    0.038
    0.029
    0.031
    0.023
    0.016
    0.012
    0.009
    0.005
    0.005
    0.008
    0
70400
66900
60600
54200
47900
43700
39400
36600
34500
33100
32400
31700
31000
29600
27500
24600
20400
17600
17600

 SUM:
                        Fraction of
                       HDT2 Travel by
            (a)(b)    Model Year,
    0.0
12135,6
 6937.2
 3948.7
 6483.4
 5432.9
 3824.9
 2466.7
 1873.2
 1748.2
 1243.4
  925.6
  975.0
  727.3
  464.2
  317.6
  209.3
   94.2
   81.3
  147.6

50037.0
0.0
0.243
0.139
0.079
0.130
0.109
0.076
0.049
0.037
0.035
0.025
0.018
0.019
0.015
0.009
0.006
0.004
0.002
0.002
0.003
*Compilation  of Air  Pollutant  Emission  Factors:   Highway  Mobile
Sources,   March  1981,   [EPA-460/3-81-005].    These   are   MOBILE2
heavy-duty  diesel  travel fractions  (for diesel-fueled  trucks  over
8,501  pounds)  which  are  used  in  this  report  for  all  HDDT2s
.(diesel-f ueled  trucks  over  14,001  pounds).   The  travel  weighting
fractions reflect a January 1 evaluation date.

**Heavy-duty  trucks  II  are  assumed in  this  report  to have  a  gross
vehicle weight  (GVW) rating greater than 14,001 pounds.

***January  1  fractions  of total  registration differ  from  those  in
the cited  source because they  are  normalized to add up to  1.000.
The cited  source performed an  equivalent normalization in  a  later
stage of its calculation.

-------
                            -52-
                             Table 17

               TRAVEL WEIGHTING FACTOR CALCULATION*
              (a)
            January 1
            Fraction
Vehicle
Age
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20+
of Total
Registration**
0.0
0.167
0.159
0.134
0.142
0.131
0.080
0.051
0.028
0.010
0.098
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Motorcycles

    (b)
   Annual
   Mileage
Accumulation
    Rate


      0
   4100
   2800
   2100
   1600
   1200
    800
    600
    400
    200
    200
    200
      0
      0
      0
      0
      0
      0
      0
      0

    SUM:
                                         1924.0
[(a)(b)/(SUMj

 Fraction of
 MC Travel by
Model Year, m<
0.0
685.7
445.7
281.0
227.0
157.8
63.7
30.4
11.1
2.1
19.6
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.356
0.232
0.146
0.118
0.082
0.033
0.016
0.001
0.010
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Compilation of Air  Pollutant Emission Factors:   Highway Mobile
Sources, March  1981,  [EPA-460/3-81-005].   The  travel  weighting
fractions reflect a January 1 evaluation date.'

**January 1 fractions of total registration differ  from those in
the  cited   source  because  they  are  normalized  to  add  up  to
1.000.   The  cited  source  performed an equivalent  normalization
in a later  stage of its calculation.

-------
                             -53-

                          Table 18

                   Rates of Misfueling  (r^)
                for Different Vehicle Classes*
                                      I/M       Non-I/M
Light-Duty Vehicles (i=l)             0.08        0.17

Light-Duty Trucks I (i=2)             0.16        0.32

Light-Duty Trucks II (i=3)            0.14        0.26

Heavy-Duty Trucks I (i=4)**           0.17        0.35

Heavy-Duty Trucks II (i=5)            0           0

Motorcycles (i=6)                     0           0
*  Values  in  this table  are  expressed  as  fractions of  the
total number of vehicles in  each  class.   Misfueling rates are
determined  for  the weighted  average mileage  accumulated  for
each vehicle class.

**Misfueling  rates for  Heavy-Duty  Trucks  I   (HDT1)  pertain
only to gasoline-fueled HDTls made after model year 1986.

Source:  "Anti-Tampering   and  Anti-Misfueling   Programs   to
         Reduce   In-Use   Emissions   from   Motor   Vehicles,"
         EPA-AA-TSS-83-10,  Office of Mobile  Sources,  December
         31, 1983.

-------
-54-
Table 18a
Rates of Misfueling (rj) for
Different 'Vehicle Ages and Classes*
Vehicle
Age
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20+
Light-Duty
Vehicles
Non-I/M
0.04
0.08
0.11
0.15
0.18
0.21
0.24
0.27
0.30
0.32
0.35
0.37
0.39
0.41
0.43
0.45
0.46
0.48
0.49
0.51
I/M
0.04
0.05
0.06
0.07
0.08
0.09
0.10
0.11
0.12
0.13
0.14
0.14
0.15
0.16
0.16
0.17
0.17
0.18
0.18
0.18
Light-Duty
Trucks I
Non-I/M
0.22
0.26
0.29
0.33
0.35
0.38
0.40
0.43
0.45
0.46
0.48
0.50
0.51
0.53
0.54
0.56
0.57
0.58
0.59
0.60
I/M
0.13
0.14
0.15
0.16
0.17
0.18
0.19
0.19
0.20
0.20
0.21
0.21
0.22
0.22
0.23
0.23
0.24
0.24
0.24
0.25
Light-Duty
Trucks II
Non-I/M
0.22
0.26
0.30
0.33
0.36
0.38
0.41
0.43
0.45
0.47
0.49
0.50
0.52
0.53
0.55
0.56
0.57
0.59
0.60
0.61
I/M
0.13
0.14
0.15
0.16
0.17
0.18
0.19
0.19
0.20
0.21
0.21
0.22
0.22
0.23
0.23
0.23
0.24
0.24
0.24
0.25
Heavy-Duty
Gas Vehicles I**
Non-I/M
0.18
0.23
^ 0.28
0.33
0.37
0.40
0.44
0.47
0.49
0.52
0.54
0.56
0.58
0.59
0.61
0.63
0.64
0.65
0.67
0.68
I/M
0.12
0.13
0.15
0.16
0.17
0.19
0.20
0.20
0.21
0.22
0.23
0.23
0.24
0.24
0.25
0.25
0.26
0.26
0.27
0.27
*Values  In  this  table are  expressed  as  fractions  of  the  total number  of
vehicles  in  each  class.   Misfueling  rates  are  determined  for   the  average
mileage accumulated by each vehicle class of each vehicle age group.

**Misfueling rates  for Heavy-Duty Gasoline  Vehicles  I  (HDGV1) are estimates
for  1987  and later  calendar  years.   Currently  all  HDGVls  use  leaded  fuel.
(For example,  for  the year  1990, . use  the  first three  values  in  either  the
non-I/M or  I/M  HDGV1  column.   All  HDGVls  greater  than 3  years  old  in  this
case  (i.e.,  pre-1987  vehicles)  would have  a misfueling  rate  of  zero  since
they do not require use of unleaded fuel.)

Source:   "Anti-Tampering  and   Anti-Misfueling   Programs   to  Reduce  In-Use
Emissions from  Motor Vehicles,"  EPA-AA-TSS-83-10,  Office  of Mobile  Sources,
December 31,  1983.

-------
                                  -55-

                                Table 19

               Average Data on  Particle Size Distribution

                                      Cumulative Fraction of Particulate
                                          Mass Smaller Than Diameter	
   Leaded Fuel,-ML                      0.2 urn       2 urn        10 urn
Median Particle
  Fractions, ML                           0.23        0.43        0.64

Ranges of ML Valuesa                   0.18-0.28   0.28-0.58   0.45-0.84
a95% confidence intervals on mean of data.

References:   (author  summary  of)  Ninomiya  et al.,  1970;  Moran et  al.,
1971; Cental  et al.,  1973;  Cantwell  et al.,  1972;  Boyer  and  Laitiner,
1975; Habibi et al., 1970; Hirschler and Gilbert, 1964.

                                      Cumulative Fraction of Particulate
                                          Mass Smaller Than Diameter	
   Unleaded Fuel, MNL                    0.2 urn        2 urn       10 urn
MNL,c                                  0.87        0.89        0.97

Ranges of MNL,C Valves0                0.86-0.88   0.84-0.94   0.84-1.00

MNL/NC                                 0.42        0.66        0.90

Ranges .of MNL.C Valves                 0.29-0.55   0.52-0.80   0.63-1.00
D95% confidence  intervals by  "t" statistics.

References:   (author summary  of)  Foster  et al.,  1976;  Trayser  et al.,
1976;  Foster  et al., 1974; Melton et al. ,  1973;  Habibi,  1973;  Cental et
al, 1973.

                                   Cumulative Fraction of Particulate
                      	Mass  Smaller Than Diameter	
Diesel Fuel, MQ        0.2 urn      1.0  urn     2.0 urn     2.5 urn     10 urn
MD                    0.73       0.86        0.90       0.92       1.00

Ranges of MD          0.69-0.75  0.76-0.93   0.86-0.95  0.88-0.95  0.97-1.00
  Values0
clntermediate  speed,  no load,  prechamber engine, 2D  fuel.   (Also, limited
data cited below indicate this  is appropriate for direct injection  engines.)

References:   Breslin,  et al.,  1976;  Hare,  1979;  Bykowski,  1981;  Bykowski,
1983;  McCain  and  Faulkner,   1979;  Vuk,   et  al.,   1976;  Begeman,  1979;
Carpenter and Johnson, 1979; Verrant  and  Kittelson, 1977.

-------
                                  -56-

                            Table  19  (cont'd)

                Average Data on Particle Size Distribution


                                  Cumulative Fraction of Particulate
   Brake Wear  .                       Mass Smaller Than Diameter
 Particulate, M        0.43 urn    1.1 urn     4.7 urn      7 urn      10 urn
               B
Median Particle
  Fractions, MBd         0.09       0.16       0.82       0.90       0.98

Ranges of Mg Values      Not available
QSamplesfordetermining  particle   size  distribution  were  collected  by
running  about  20  braking  cycles  weighted  to  be  representative of  urban
driving conditions.

Reference:  Cha et. al., 1983.

-------
                             -57-  .

3.0    EXAMPLE    CALCULATION   OF    AUTOMOBILE   PARTICULATE
       EMISSIONS LESS THAN 10 MICRONS

       Problem;   For  an  area  characterized  by  light-duty
vehicles  driving  under  cyclic conditions  with  an  average
speed  of  19.6  miles   per   hour,  calculate  the  particulate
emission  rate  of particles  less than  10  urn in  diameter for
the year  1985.   Assume an inspection  and  maintenance program
has been  implemented in this area.   The simplified misfueling
rates from Table 18 will be  used.

       Solution:   Use  equations  1.0,  1.1.,  1.1.1,  1.1.2,
1.1.3, 1.1.4, 1.1.5, 1.1.6,  1.1.7,  1.1.8,  1.1.10,  1.1.12, and
1.1.13.

       Particulate Matter Size Cutoff = 10 urn

     n = 1985   i = 1 = LDV   s = 19.6 mph    M0 = 0.98
                                               B
     fcl,1985 = 1'°          ri  (from Table 18) = 0.08

Equation 1.0
EFPM10,1985,19.6 = (1.0)(EF1

Equation 1.1
                 1985
EF1,1985,19.6 V  S   ^EFl,j,lclf1985fL + EPl,j,k,,L + EF1, j^,
                j=1966          1                 2            3

     X (FL,l,j} + (EF1, 3fklf1985fNL + EPl,j,k2,NL + EF1, j.kg.NL*

-------
                             -58-




PbL,1985         =     1'1  "
PbNL,1985        =     °-014
MT 1A            =     0.64;
 L,10 um
M.TT _ ..         =     0.97;
 NL,C,10 um
"NL.NCMO um     =      °-90;



M^               =      1.00;
a                 =      0.75;
 s




C                 =      0.79.
 s




Use  the  following  equations -to plug  into Equation  1.1 and  sum


over the  appropriate  model  years:





Equation  1.1.1





EF,  . .    -.QOC T  = [(1.1)(0.929)(0.64) + (0.014)(0.071)(0.90)]
   1 1 D / K-\ i -LyoD, LJ





     •   (0.751(1.557)  =      0.968                , = 1966.74
Equation  1.1.2


EF   .            = C(l.l)(0.725)(0.64) + (0.014) (0. 275) (0. 90) ]

  -L / D ' Ki '
     0  (0.75) (1.557)  _      0.760             .  •  .  _      _
        (Eo            '                        for  D  -  1975-85

          c, 1,




Equation . 1.1.3
         (Eo    .)(0.79)          o .  .
           c, 1, 3                 c, 1, 3
   T  .  v      C:  r  = C(0.014)(0.92)(0.97) + (l.l)(0.08)(0.64)
   J- » D » K- /
      °   (0.75X1.557)   m      0.102                 . _
         IE     .0.79          E  :  :           for 3 ~

-------
                             -59-
Equation 1.1.4
     EFn _. ,.  T =  (0.193) (0.64)  =  0.124  (g/mile)
                                                for  j  = 1966-69
1,j/k2'L
Equation 1.1.5
     EF,  . .   _ =  (0.068)(0.64)  =  0.044  (g/mile)
                                                for j  = 1970-74
Equation 1.1.6
     EF,  . .   T =  (0.030)(0.64)  =  0.019  (g/mile)
       J-1 3 i KO '
                                                for j = 1975-85
Equation 1.1.7
     EPl.j.k2,NL =  (0.92)(Fif jfCAT)(0.017)(0.97)+

                                    (0.068) (0.64)4-
                                                for j = 1975-85
                  =  (0.019)(FlfjfCAT)
                                                for j = 1975-85
Equation 1.1.8
     EFn  . .   _  =  (0.002)(0.64)  = 0.001 (g/mile)
       J-1 D / K., / J-<
                                                for j = 1966-85
Equation 1.1.10
EFl,j,k3,NL '  <
               (Fl,j,NL,NOCAT)(0'002)(0-90)]+(0'08)(0-002)(0-64)

               =  C(Fl,j,CAT/NOAIR)(0-004)+(Fl,j/CAT/AIR)(0-°16)


                                                for j  = 1975-85

-------
                             -60-
Equation 1.1.12
     EF, .  _ = (0.700)(1.00)
       -L , J l *->
             = 0.700 (g/mile)                  for j = 1966-80

Equation 1.1.13
     EF. .    = (0.320)(1.00)
       J-» D » ^
             = 0.320 (g/mile)                  for j = 1981-85

After  calculating  EF. ,ooc  , Q .-  in  Table  20,  substitute  in
                     .L, J.7OO, J_y.o
Equation 1.0  and  obtain the  total  LDV  particulate emission
rate:

Equation 1.0
     EF               =  (1.0)(0.0586) + 0.0125 + 0.002
       PM10,1985,19.6
                      =    0.0731  (g/mile)
Note:  This  example  is an  estimate of  particulate emissions
from light-duty vehicles  only.   Therefore,  the total emission
rate from  all vehicle  classes  for  an area  in  calendar year
1985 can be expected to be considerably higher.

-------
                                  LIGHT-OUT* vtnicn
                                                                     ......... .
                                                                    O.IMIMI
                                                                                                moan ro> tin m»  n>»
Mission nCKM COHNMDR CALCULATION  IWUtS
                                                                                                                                ttMMf"" "CIO* <
19*5
19*4
1*81
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1*81
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1*78
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UM 11
on u
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0.011
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. 24.
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                                             0.020
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                                                    0.140
                                                    0.29*
                                                    0.474
                                                    0.655
                                                    0.6M
                                                    O.CSO
                                                    0.637
                                                    0.5*7
                 0.610
                 0.760
                 0.820
                 0.8*0
                 0.704
                 0.526
                 O.MS
                 0.150
                 0.150
                 O.J41
                 0.122
                                                                                                                 111
                                                                                                                       1.1.
                                                                                                                 121
                                                                                                                1.1.
                                                                                                                 Ill
                                                                                                                UM!  In lv»tlan 1,1.
                                   141
                                  1.1.
                                                                                                                 HI
                                                                                                                1.1.
                                                                                                                 |6|
                                                                                                                1.1.
                                                                                                                 171
                                                                                                                                tn> mimian Itctoc
                                                                                                                                                           in


                                                                                                                                                             in


                                                                                                                                                           in


                                                                                                                                                             in


                                                                                                                                                             In


                                                                                                                                                             In


                                                                                                                                                            in
                                                                 «t  U UMi In


                                                        1.1.4. 1.1.1, ml 1.1.6


                                                         1.1.7 ttet  U un4 In


                                                         1.1.8 Omt  U UMI! In


                                                        1.1.10 th«t  U iwd In


                                                         1.1.12 ml  1.1.11  that
                                                                                                                                                                                               I
                        ill
1*85
1*84
1*81
1*82
1*81

1*7*
1*78
1*77
1*7*
1*75
1*74
1*71
1*72
1*71
1*70"
IX*
1***
1M7
1*M-
10
11
U
11
14
15
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17
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1*
20*
0.0001
0.0004
0.8005
                     0.0001
                     0.0022
                     0.0017
                     0.0012
                     0.0007
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                     0.0002
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                                             121
                                          0.0001
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                                          0.0001
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                                                        C.   (MISSION MCTCW COMOKMT


                                                               111                141
                                          0.0043
0.0002
0.0002
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A.UU
0.000*
0.0024
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0.0020
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0.0011
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                                                                              0.4151
                             CUCUUtTIOMB


                                      151
                                                                                                                   1*1
0.0003
0.0017
0.001*
0.0012
0.0012
0.0011
0.0007
0.0005
0.0004
0.0004
0.0001
                                                                                                                        0.0005
                                                                                                                        0.0011
                                                                                                                        0.0004
                                                                                                                        0.0011
                                                                                                                        0.0021
                                                                                                                        0.0040
                                                                                                                        0.002*
                                                                                                                        0.0015
                                                                                                                 O.OM4
                                                                                                                                   A.U41 - 0.0586 -

-------
FIGURE 1.  LEADED GASOLINE PARTICULATE SIZE DISTRIBUTION
     o
                                                               to
                                                               I
              PARTICLE DIAMETER microns

-------
FIGURE  2. UNLEADED GASOLINE PARTJCULATE SIZE DISTRIBUTION
    100
     0
                                                                     i
                                                                     (Tl
                                                                     OJ
                                                        Legend

                                                       O Catalyst

                                                       A Noncololyst
               PARTICLE DIAMETER microns

-------
FIGURE 3. DIESEL PARTICULATE SIZE DISTRIBUTION
 a I0°
 u
 u
 I*
 U BO
 a.
 w
 W
 I-
 ui
 W
 ^1
 O
   ao
   70
   60
   50
 3
   30
   20
   10-
 u  o
                ~T
                3
T
4
nr
5
~r
7
               070

PARTICLE DIAMETER microns
~r
9
10

-------
FIGURE 4. BRAKE WEAR PARTICULATE SIZE DISTRIBUTION
   100
                                                             I
                                                             CTl
                                                             •m
                                                             I
             PARTICLE DIAMETER microns

-------
                             -66-

                       4.0  REFERENCES

1.   Carey,  Penny  M.,   Supplementary   Guidelines  for  Lead
     Implementation  Plans—Updated   Projections   for   Motor
     Vehicle  Lead  Emissions,  EPA  Report 450/2-83=Ol5"2,  OAR,
     QMS, ECTD, TSS for OAQPS, March 1983.

2.   Compliation o_f_ Air  Pollutant Emission  Factors:   Highway
     Mobile Sources, EPA  Report  460/3-81-005,  OAR, QMS, ECTD,
     TEB, March 1981.

3.   Anti-Tampering and   Anti-Misfueling Programs to  Reduce
     In-Use Emissions  From   Motor  Vehicles"  (Draft  Report  for
     Public CommentTT  EPA/AA Report  83-3,   OAR,   QMS,  ECTD,
     TSS, May 25, 1983.

4.   Diesel Particulate  Study  (Draft),   U.S.  EPA, OAR,  QMS,
     ECTD, SDSB, October 1983.

5.   Lorang, Philip A.,  White,  John T.  and  Brzezinski, David
     J. ,   In-Use Emissions of 1980  and   1981  Passenger Cars;
     Results  of_ EPA   Testing,   SAE  Paper   No.  820975,  U.S.
     Environmental Protection Agency, presented at West Coast
     International Meeting,   San Francisco, CA, August 1982.

6.   The Impact of Light-Duty Diesel Particulate Standards on
     the  Level ~ofDieselPenetrationTntheLight-Duty
     Vehicle  andLight-Duty  Truck  Markets,  Jack  Faucett
     Associates Report for EPA,  January  1983.

7.   Documentation  for   the New   Highway  Fuel   Consumption
     Model, Energy and  Environmental  Analysis,  Inc.  Report
     for EPA,  January 1982.

8.   Assessment  of Current  and  Projected  Future Trends  in
     Light-Duty    VehicleFuel-Switching,    Energy    and
     Environmental Analysis,  Inc. Report  for EPA, June 1982.

9.   The  Highway Fuel Consumption  Model -  Eighth Quarterly
     Report,  Energy  and  Environmental  Analysis,Inc.  Report
     for EPA,  July 1982.

10.  Draft Study of Particulate  Emissions from Motor Vehicles
     by  the  Environmental Sciences  Research  Laboratory(for
     Section 214 of  the  Clean Air  Act), U.S.  EPA,  Office of
     Research   and  Development,   Mobile   Source  Emissions
     Research Branch,  July 1983.

-------
                             -67-

                     References (cont'd)

11.  "Control of  Air Pollution  from New  Motor Vehicles  and
     New  Motor  Vehicle  Engines:   Federal  Certification  Test
     Results for 1975 Model Year,"  Federal  Register,  Vol.  40,
     No. 48, March 11, 1975.

12.  "Control of  Air Pollution  from New  Motor Vehicles  and
     New  Motor  Vehicle Engines:   Federal  Certification  Test
     Results for 1976 Model Year,"  Federal  Register,  Vol.  41,
     No. 46, March 8, 1976.

13.  "Control of  Air Pollution  from New  Motor Vehicles  and
     New  Motor  Vehicle   Engines:   Federal  Certfication  Test
     Results for 1977 Model Year,"  Federal  Register,  Vol.  42,
     No. 110, June 8, 1977.

14.  "Control of  Air Pollution  from New  Motor Vehicles  and
     New  Motor  Vehicle Engines:   Federal  Certification  Test
     Results for 1978 Model Year,"  Federal  Register,  Vol.  43,
     No. 181, September 18, 1978.

15.  1983 Motorcycle  Statistical Annual, Motorcycle  Industry
     Council,   Inc.,    Research   and   Statistics    Dept.,
     Governmental Relations Office, Arlington, VA,  June 1983.

16.  Hare,   Charles   T.,   Characterization   of  Gaseous   and
     Particulate  Emissions from  Light-Duty  Diesels  Operated
     on  Various Fuels,  EPA-460/3-79-008,   Southwest  Research
     Institute  Report prepared for Office  of Mobile  Sources,
     June 1979.

17.  Bykowski,  Bruce  B.,  Characterization gjE Diesel Emissions
     from  Operation  of   a_  Light-Duty  Diesel  Vehicle  on
     Alternate   Source    Diesel    Fuels,     EPA-460/3-82-OU2",
     Southwest  Research  Institute Report prepared  for Office
     of Mobile  Sources, November 1981.

18.  Bykowski,  Bruce  B.,   Petroleum  Versus  Alternate-Source
     Fuel   Effects   on   Light-Duty  Diesel   Emissions,   EPA
     460/3-83-007,   Southwest-  Research   Institute   Report
     prepared for Office of Mobile Sources,  August 1983.

19.  Bykowski,  Bruce  B. ,  Characterization of Diesel Emissions
     as  a   Function  of   Fuel  Variables,    EPA-460/3-81-015,
     Southwest  Research  Institute Report prepared  for Office
     of Mobile  Sources, April  1981.

20.  McCain,  Joseph  D.,  and  M.  Gregory Faulkner,  Assessment
     of   Diesel    Particulate   Control;     Particle   Size
     Measurements,    EPA-600/7-79-232c,    Southern    Research

-------
                             -68-

                     References (cont'd)

     Institute  report  prepared  for  Office  of  Research  and
     Development, December 1979.

21.  Begeman,   C.R.,   and   P.J.   Groblicki,  Particle   Size
     Variation  in.  Diesel Car Exhaust,  SAE Paper  No.  790421,
     presented in Detroit, MI, February 26 - March 2, 1979.

22.  Carpenter,  Kenneth,  and  John  H.  Johnson,  Analysis  of
     the   Physical  Characteristics  of   Diesel  ParticulaTe"
     Matter    Using    Transmission    Electron    Microscope
     Techniques,   SAE   Paper  No.   790815,   presented   in
     Milwaukee, WI, September 10-13, 1979.

23.  Verrant,  John A. and  David  A.  Kittelson,   Sampling  and
     Physical  Characterization of Diesel  Exhaust  Aerosols,
     SAE Paper No. 770720, presented  in Detroit,  MI, February
     1977.

24.  Ter  Haar,  G.L.,  D.L.  Lanane,  J.N.  Hu,  and M.  Brandt,
     Composition,  Size,   and  Control   o_f  Automotive  Exhaust
     Particulates, Ethyl  Corporation report  presented  atthe
     64th Annual  APCA Meeting, Atlantic  City,  NJ,  June  27  -
     July 1, 1971.

25.  Breslin,  J.A.,   A.J. Strazisar,   and  R.L.  Stein,  Size
     Distribution and Mass Output  of  Particulates From Diesel
     Engine  Exhausts,  report  preparedbyPittsburgh  Mining
     and  Safety  Research   Center,   Pittsburgh,   PA,   U.S.
     Department of the Interior, Report of Investigation 8141.

26.  Boyer,   K.W.,  and  H.A.  Laitinen,  "Automobile  Exhaust
     Particulates,"  Environ.   Sci.   Techno1.,   9_( 5):457-469,
     1975.

27.  Cantwell,  E.N.,  E.S.  Jacobs,  W.G.   Kunz,   Jr.,   V.E.
     Liberi,  Control  of  Particulate   Lead   Emissions  from
     Automobiles, SAE Paper No. 720672,  Detroit,  May 1972.

28.  Foster,  J.F.,  D.A.  Trayser,  C.W.   Melton,   and  R.I.
     Mitchell,  Chemical  and   Physical  Characterization   p_f
     Automotive Exhaust Particulate Matter  in. the Atmosphere,
     Fourth  Annual   Summary  Report   prepared   byBattelle
     Columbus  Laboratories,   Columbus,   OH,  to   Coordinating
     Research Council  (CRC-APRAC  Project No. CAPE-19-70)  and
     U.S.  Environmental   Protection   Agency  (Contract   No.
     68-01-0279), July 1974.

-------
                             -69-

                     References (cont'd)

29.  Foster, J.F., D.A. Trayser,  E.R.  Blosser,  F.A.  Creswick,
     and D.F.  Miller,  Chemical and  Physical  Characterization
     o_f  Automotive   Exhaust   Particulate   Matter   in   the
     Atmosphere,  Fifth  Annual  Summary  Report  prepared  by
     BattelleColumbus  Laboratories,   Columbus,   OH,   to
     Coordinating  Research  Council  (CRC-APRAC  Project  No.
     CAPE-19-70), March 1974.

30.  Gentel,   J.E.,    O.J.    Manary,    and   J.C.   Valenta,
     Characterization of Particulates  and  Other Non-regulated
     Emissions from Mobile Sources and  the  Effects of Exhaust
     Emissions  Control  Devices  on  these  Emissions,  report
     prepared by The Dow Chemical  Company,  Midland,  MI,  under
     Contract  No.   EHA-70-101  to  the   U.S.   Environmental
     Protection Agency, Ann Arbor, MI,  March 1973.

31.  Habibi,  K. ,  "Characterization  of  Particulate  Matter  in
     Vehicle  Exhaust,"  Environ. Sci .  Techno 1. ,  1_ ( 3 ): 223-234,
     1973.
32,
33,
34,
35
36,
Habibi,  K.,  E.S.  Jacobs,  W.G.  Kunz,  Jr.,  and  D.L.
Pastell,  Characterization  and  Control  of   Gaseous  and
     Particulate   Exhaust
                "to
                       Emission   from  Vehicles,
presented  to  the   Air
Francisco, October 1970.
	   	  	    paper
 PollutionControlAssn.,   San
Hirschler,  D.A.,  and  L.F.  Gilbert,  "Nature of  Lead in
Automobile   Exhaust   Gas,"   Arch.   Environ.   Health,
9_:297-313, 1964.

Kittelson,   D.B.,   D.F.   Dolan,    and   J.A.   Verrant,
Investigation of  a. Diesel Exhaust  Aerosol,  SAE Paper No.
780109, Detroit,  February 1978.

Melton,  C.W.,  R.  Mitchell,  D.  Trayser,  and  J.  Foster,
Chemical  and  Physical  Characterization  of  Automotive
Exhuast  Particulate  Matter  in  the  Atmosphere,  Final
Summary   Report   prepared  by   Battell~e   Columbus  Lab,
Columbus,  OH,  to  CRC  (CRC-APRAC  Proj.   No.  CAPE-19-70)
and EPA (Contract No. 68-02-0205), June 1973.

Moran,  J.B.,   O.  Manary,   R.  Fay,  and   M.  Baldwin,
Development  of  Particulate  Emission Control  Techniques
for  Spark-Ignition  Engines,   Final   Report  preparedby
Organic  Chemicals  Department,  The  Dow  Chemical  Co.,
Midland,  MI,  under Contract  EHS70-101,  EPA,  Ann  Arbor,
MI, July 1971.

-------
                             -70-

                     References (cont'd)

37.  Ninomiya, J.S., W.  Bergman,  and B.H.  Simpson, Automotive
     Particulate  Emissions,   paper  presented   to  the  Second
     Int' 1  Clean  Air  Congress  of  the  Int' 1  Union  of  Air
     Pollution Prevention Assn, Washington, DC,  December 1970.

38.  Trayser,  D.A.,  F.A.  Creswick,  E.R.   Blosser,  and  D.F.
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41.  Schneider, Eric  W. ,  "Detection  of  Leaded-Gasoline  Usage
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42.  Cha,   Soyoung,  Philip  Carter,  and  Ronald  L.  Bradow,
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43.  Cadle,  S.H.,  and  R.L.  Williams,  "Gas   and  Particle
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44. .Pierson,  . W.R.,    and    W.W. ..  Brachaczek,    "Airborne.
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45.  The  Highway  Fuel  Consumption   Model;   Tenth  Quarterly
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                             -71-

46.  Size   Specific   Particulate    Emission    Factors   for
     Industrialand  Rural  Roads,  draft  report prepared  for
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47.  Paved   Road   Particulate   Emissions--Source   Category
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     Kansas City, MO, May 7, 1984.

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