c/EPA
                       UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
                   OFFICE OF CRIMINAL ENFORCEMENT, FORENSICS, AND TRAINING
                                    ENVIRONMENTAL CRIME
                           Technical Investigation-Evidentiary/Forensic Analysis

                           The following NEIC employees contributed to this paper.

                                         Earl W. Beam, MA
                                       Dorothy E. Biggs, MLS
                                        Willis Collins, Jr., BS
                                       Margo R. Dusenbury, BS
                                       Phoebe P. MacLeish, BA
                                      Konrad E. Nottingham, BS
                                          Don J. Smith, BS
                                       Jennifer A. Suggs, MS
                                   Library assistance provided by:
                                                            . :^V-

                                 Gitanjali Passfield, Contractor (Vistronix)
                                 Nancy B. Greer, Contractor (Vistronix)
                                          Prepared for:
                                     f
                               13th International Forensic Science Symposium
                            Author to whom correspondence should be addressed:
                                         Jennifer A. Suggs
                                            EPA-NEIC
                                    Bldg. 53, Denver Federal Center
                                         Denver, CO 80225
                         NATIONAL ENFORCEMENT INVESTIGATIONS CENTER
                                       Diana A. Love, Director
                                         Denver, Colorado
                                               NIIG

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    UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
OITICE OF CRIMINAL ENFORCEMENT, FORENSICS, AND TRAINING
                  ENVIRONMENTAL CRIME
        Technical Investigation-Evidentiary/Forensic Analysis

        The following NEIC employees contributed to this paper.

                       Earl W. Beam, MA
                      Dorothy E. Biggs, MLS
                      Willis Collins, Jr., BS
                     Margo R. Dusenbury, BS
                     Phoebe P. MacLeish, BA
                    Konrad E. Nottingham, BS
                        Don J. Smith, BS
                      Jennifer A. Suggs, MS
                  Library assistance provided by:

               Gitanjali Passfield, Contractor (Vistronix)
               Nancy B. Greer, Contractor (Vistronix)
                         Prepared for:

             13th International Forensic Science Symposium
         Author to whom correspondence should be addressed:
                        Jennifer A. Suggs
                          EPA-NEIC
                  Bldg. 53, Denver Federal Center
                        Denver, CO 80225
      NATIONAL ENFORCEMENT INVESTIGATIONS CENTER
                     Diana A. Love, Director
                        Denver, Colorado

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                             CONTENTS

LIST OF ACRONYMS	3
INTRODUCTION	5

ENVIRONMENTAL CRIME SCENE EXAMINATION	7
     INTRODUCTION	7
     PLANNING	8
     GATHERING INFORMATION	10
     GATHERING EVIDENCE	13
          Field Techniques and Equipment	14
          Sampling	17
          Electronic Evidence	20

LABORATORY ANALYSIS OF ENVIRONMENTAL SAMPLES	22
     METHODS AND METHOD SELECTION	.	22
          Hazardous and Solid Wastes	23
          Water and Wastewater	23
          Air	24
          Additional	24
     INSTRUMENTATION AND TECHNIQUES	25

EVIDENCE PRESENTATION	31
     LINK ANALYSIS	31
     ENVIRONMENTAL SCIENCE AND THE COURTROOM	32

SELECTED TOPICS	35
     LABORATORY FRAUD	35
     CHEMICAL FINGERPRINTING	37
     ACCREDITATION OF ENVIRONMENTAL FORENSIC LABS	 38

CONCLUSIONS	40
REFERENCES	41

APPENDIX	58
     TERMINOLOGY AND PUBLICATIONS	58
     SUPPLEMENTAL INTERNET SITES	..58
     TABLE - DOWNLOADABLE USEPA METHODS ONLINE	62

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                              LIST OF ACRONYMS

AA - Atomic Absorption
A2LA - American Association for Laboratory Accreditation
AAAS - American Association for the Advancement of Science
ACS - American Chemical Society
AES - Atomic Emission Spectroscopy
AMTIC - Ambient Monitoring Technology Information Center
APHA - American Public Health Association
ASCLD/LAB - American Society of Crime Laboratory Directors/Laboratory Accreditation Board
ASE - Accelerated Slolvent Extraction
ASTM - American Society for Testing and Materials
AWWA - American Water Works Association
CA - Chemical Abstracts
CAA - Clean Air Act
CAS - Chemical Abstracts Service
CASE - Court Appointed Scientific Experts
CE - Capillary Electrophoresis
CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act
CERCLIS - Comprehensive Environmental Response, Compensation, and Liability Information
System
CFR - Code of Federal Regulations
CID - Criminal Investigation Division
CLU-EN - Hazardous Waste Clean-Up Information (Internet site)
CWA - Clean Water Act
DSMS - Direct Sampling Mass Spectrometry
EMC - Emissions Measurement Center
ETV - Environmental Technology Verification Program
FATE - Field Analytic Technologies Encyclopedia
FFDCA - Federal Food, Drug, and Cosmetic Act
FIFRA - Federal Insecticide, Fungicide and Rodenticide Act
FPXRF - Field-Portable X-Ray Fluorescence
FQPA - Food Qualiry Protection Act
GC - Gas Chromatography
GC-MS - Gas Chromatography with Mass Spectrometry
GC-AED - Gas Chromatography with Atomic Emission Detection
GC-FTIR - Gas Chromatography with Fourier Transform Infrared Spectrometry
GIS - Geographic Information Systems
GPO - Government Printing Office
HPLC - High Performance Liquid Chromatography
1C - Ion Chromatography
ICP - Inductively Coupled Plasma
ICP-AES - Inductively Coupled Plasma with Atomic Emission Spectrometry

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ICP-MS - Inductively Coupled Plasma with Mass Spectrometry
ICP-OES - Inductively Coupled Plasma with Optical Emission Spectrometry
IMS - Ion Mobility Spectrometry
IR - Infrared
LC-MS - Liquid Chromatography with Mass Spectrometry
MAE - Microwave Assisted Extraction
MS - Mass Spectrometry
NEIC - National Enforcement Investigations Center
NELAC - National Environmental Laboratory Accrediting Conference
NELAP - National Environmental Laboratory Accreditation Program
NFSTC - National Forensic Science Technology Center
NTIS - National Technical Information Service
NVLAP - National Voluntary Laboratory Accreditation Program
OCEFT - Office of Criminal Enforcement, Forensics and Training
OIG - Office of Inspector General
PFE - Pressurized Fluid Extraction
PLE - Pressurized Liquid Extraction
PLM - Polarized Light Microscopy
PPE - Personal Protective Equipment
QA - Quality Assurince
QC - Quality Control
RCRA - Resource Conservation and Recovery Act
RCRAInfo - Resource Conservation and Recovery Act Information System
SEC - Securities and Exchange Commission
SFE - Supercritical Fluid Extraction
SPE - Solid Phase Extraction
SPME - Solid Phase Microextraction
SW-^6 - Test Methods  for Solid Waste
TIO - Technology Innovation Office
TSCA - Toxic Substances Control Act
TTN - Technology Transfer Network
UMEA - Ultramicroelectrode Arrays
UNEP - United Nations Environment Programme
US - United States
USEPA - United States Environmental Protection Agency
UV - Ultraviolet
VOC - Volatile Organic  Compound
XRF - X-Ray Fluorescence
XRS - X-Ray Spectroscopy

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                                   INTRODUCTION

       This report is a compilation of information and advances in scientific and technical methods
as applied to environmental crime investigations. Included are sections on information gathering and
planning prior to a forensic investigation, evidence gathering techniques and field methods, tools of
the investigation (computer forensics, link analysis), laboratory methods and instrumentation, and
examples of laboratory fraud encountered.  The planning section is a guide for the topics presented in
this paper and  it outlines the  thought process and flow  of events in an environmental crime
investigation.
       Literature  of particular  interest  or with  foundational  reviews  regarding  methods,
instrumentation, or techniques have been included in the search for current methods and upcoming
trends in this field. This arena of environmental crime is expansive and lists of additional resources
(both print and electronic) have been provided in the appendix to aid the researcher who may require
more information than the text of this paper provides.  A list of acronyms  used in this paper is
included after the table of contents.
       Within this paper some commercial products, firms, or trade names may be mentioned. The
mention of such does not constitute an endorsement or recommendation of those specific products or
companies by the United States Environmental Protection Agency (USEPA) or the USEPA National
Enforcement  Investigations Center (NEIC).  Names of this type mentioned within  the text  are
intended solely  as an aid to the reader within the context of the topic.  Many of the Internet sites
given  in this  paper do not have any connection  with USEPA and, therefore, are  not under any
editorial control by USEPA.
       The United States federal laws, and the methods approved for use by the USEPA, provide the
frame of reference for the points of view expressed in this paper.  This perspective and many of the
issues and legal considerations that are dealt with  in the United  States are presented to aid in
understanding the concerns relevant to environmental enforcement in the US.  Each nation has their
own sovereignty with regard to environmental regulations and environmental crimes. The methods
used and types of environmental pollution  control approaches will differ from nation to nation and
the viewpoints presented in this paper are not intended as a standard for all to follow.
       The purpose;  of this paper is  to share general  information on  the  enforcement of
environmental laws  within the  law enforcement community.  It does not  set any  absolute
requirements  under  any legal system nor does  it  create any rights, substantive or procedural,
enforceable at law by any party to  litigation. In addition to literature references, this paper includes
much practical information developed by NEIC over several years of helping develop environmental
criminal cases.  This information is presented for its value to  potential users of this paper. This
information may or nay not apply in any specific case. It should always be understood that there are
many ways of approaching any  environmental problem.
       Common environmental crimes in the US include illegal disposal  of  hazardous  waste,
unpermitted discharges to sewer  systems  or surface water, discharge of oil by vessels to  waters
within US jurisdiction, the misapplication  of pesticides, the illegal importation of ozone-depleting
substances, data falsification, and  laboratory fraud. Federal, state, and sometimes local statutes and
regulations are in place to protect the water, air, land, and human health. From a Federal perspective,
these include the Resource Conservation and Recovery Act (RCRA) for hazardous wastes, the Toxic

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Substances Control Act (TSCA) for toxic substances, the Clean Air Act (CAA), the Clean Water Act
(CWA), the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA)
for abandoned waste sites, and the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA) for
pesticides. Each of these laws contains some standard methods for sampling and analyses to prove
environmental crimes.1>2 The Code of Federal Regulations (CFR) contains the specific requirements
of the laws. 3'4  Within the USEPA, the Criminal Investigation Division  (CID) of the Office of
Criminal Enforcement, Forensics  and  Training  (OCEFT) is tasked with the responsibility to
investigate criminal offenses.5
       Criminal offenses are more serious in nature than civil violations in the United States. To
successfully prosecute an environmental  criminal case, the government has to prove, beyond a
reasonable doubt, that a corporation or person knowingly  violated  an environmental statute
containing criminal sanctions. The same analytical objectives of providing good quality data and
accurate measurements prevail in both civil and criminal cases; the only distinction between the two
are legal.

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                 ENVIRONMENTAL CRIME SCENE EXAMINATION

INTRODUCTION

       "In the fields of observation chance favors only the prepared mind." 6
                           - Louis Pasteur
                            Inaugural lecture, University of Lille,
                            December?, 1854

       Proving environmental cases can be difficult due to both technical and legal complexities;
penalties vary depending upon the statute and technical issues require ever-increasing knowledge
from the investigative team.
       The criminal prosecution of environmental crimes in the US is in its infancy. While a few
scattered efforts at environmental crime prosecution  occurred during the 1970s, the US federal
government prosecution of environmental crimes substantially increased in the 1980s. Around that
time, environmental laws were being developed or were being enhanced from misdemeanor criminal
penalties (any crime punishable by less than 1 year in jail) to felony (any crime punishable by more
than 1  year in jail) provisions.  The following  are  some challenges  that must be met by  the
investigative team.
•      Scientific and technological advances throughout the years have improved our understanding
       of complex issues involved in environmental crimes, such as chemical fate and transport. As
       a result, the effective use of the increasingly sophisticated information sources and evidence
       collection tools that are becoming available for intelligence gathering, surveillance, field
       screening and measurements, laboratory analysis, and modeling pollutant behavior in  the
       environment is required.
•      All the  scientific tools and technological capabilities, along with the resources required to
       investigate an environmental case, need to be  singularly focused to prove the allegations.
       Scientific anc, technical conclusions then need to be presented cogently so a jury can clearly
       understand that the defendant committed the crime.
•      One familiar vactic used by defense attorneys is  to confuse the jury with the complexity of the
       evidence.  The more complex the science, the more difficult it  is to explain  to a jury.
       Although the evidence exists to prove the case, the defense has a responsibility in the  US
       legal system to represent the client to the best of his/her ability. Defense counsel will often
       try to convince a jury that a crime was not committed willfully and knowingly because the
       defendant could not have comprehended what  was  expected.
•      Another challenge can  be convincing  a  prosecuting attorney  of the importance of an
       environmental case when he or she has competing, high  visibility cases involving murder,
       drugs, and olher high profile crimes.  "Environmental crime is real crime; improperly
       disposed pollutants poison community water  supplies, contaminate fisheries, and injure
       human beings." 7
       To overcome these challenges, environmental cases must be legally and technically sound,
and presented in a straightforward manner. Documenting and illustrating to the court the impact to
human health and  the environment is also important.

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PLANNING

       Understanding what crime has been allegedly committed and who was involved is the first
step. Organizing and planning a case using a team approach is critical, as is communication between
team members.  Often, multiple government agencies are involved with a case, which makes
communication more of a challenge. Each team member must have a clear objective and take care to
do a thorough job on his/her own piece of the investigation, but interaction with other members of
the team is also needed to ensure continuity.
       In the United States, a lead criminal investigator, commonly referred to as the "case agent," is
usually in  charge of the overall process of investigating an environmental crime.  The case agent
develops an understanding of allegations of criminal activities, and consults with various witnesses,
peers, and experts to decide what evidence is needed to ultimately prove the case. A recent book by
Drielak titled Environmental Crime: Evidence Gathering and Investigative Techniques describes on-
site environmental crime investigations. The author covers the issues related to search warrants and
techniques used to gather evidence. Many photos from real environmental crime scenes are included
to illustrate the topics in the book.8
       A typical  cai.e requires knowledge of many fields within science, technology, and law.  The
case agent may need a team with a mix of knowledge of engineering (chemical processes and
technology, field techniques and instrumentation), chemistry (laboratory sample analysis, chemical
reactions and processes) and law (environmental regulations). The appropriate team members and
experts will depend on the type of case being pursued and the personnel resources available.  The
case may require assistance from individuals skilled  in gathering background information, seizing
computer data, or detecting laboratory fraud.
       Experts, either internal or outside  the enforcement organization, can be especially valuable
when they understand and communicate the interplay between legal requirements, science and
technology, and the crime allegedly committed. Experts should not only understand their own field,
but should be able  to explain their opinions clearly and openly to other team members, to the
prosecuting attorney, and ultimately to the jury without bias or condescension.
       During the investigative process, a decision is often required regarding the need to conduct
one or more searches for evidence.  In the US, evidence must be gathered in accordance with the
Federal Rules of Criminal Procedure and other federal guidelines designed to protect the individual's
constitutional rights. 9  Methods used to obtain evidence  of a crime include  the use of consent
searches, search warrants, and grand jury subpoenas.  Sampling that is done on a consensual basis is
not recommended because consent can be revoked at any time.  If a search warrant is necessary, the
agent will need to articulate what probable cause exists that a crime has been committed and that the
location requested for the search contains the evidence of the crime.  The case agent may articulate
probable cause through evidence  gathered from a variety of sources including witness interviews,
surveillance of suspects, use  of informants, as well as sampling of suspected discharges from the
targeted facility.  The agent will need to anticipate who will be physically present, what samples will
be collected, and what documents will  be seized.   Samples may be collected during criminal
investigations to  establish probable cause for a search warrant, provide evidence, or both.
       Execution ol' search warrants can require extensive planning.   Ongoing communication
regarding goals, problems, and objectives, including face-to-face meetings enable the team to work

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collaboratively to plan the field objectives, and to make the best use of the limited time available on-
site. Generally, wairants are required to be executed during the hours of 6 a.m. to 10 p.m., unless a
special situation is involved, such as a chemical release that can only be sampled as the release is
occurring.
       If releases of regulated pollutants to air, water or land are suspected, and sample evidence is
to be collected, a fisld team leader should be identified. The field team leader is responsible to
ensure that conditions are safe for workers, that the proper evidentiary samples are collected, and that
field activities and observations of on-site conditions are documented. Any field measurements must
be performed according to accepted procedures, and, as always, must be documented.
       Safety of the  field  team should always  take precedence over evidence collection.  Safety
considerations while conducting a search can include hostile individuals, chemical exposure and/or
chemical incompatibility hazards, working under unpleasant and/or toxic conditions, collecting
samples or searching in high places  (for example, on top of tanks), and working around heavy
equipment or industrial machinery, or working in confined spaces.
       Manufacturing processes often need to be evaluated in detail to understand how chemicals
are produced and what wastes are generated.  Industrial waste treatment and management systems
often need to be evaluated in detail.- For example, waste tanks and associated piping may need to be
identified to see  if there is  a connection to a sewer where an alleged release occurred.
       The field tezim leader should maintain contact with the laboratory personnel to discuss
sampling activities, to ensure that appropriate analytical techniques are available for use, and to
ensure that  resources are available to complete  the analyses within  applicable holding times
(established time limitations for sample analysis).  Multiple  laboratories may be involved, for
example when both hazardous waste and radionuclides are contaminants of concern.  Laboratory
personnel should be :.nvolved as early as possible in the planning process. The analytical chemist(s)
should be familiar with the types of samples being collected, the purpose of each sample in proving
the case, and the appropriate analytical methods to be used to prove the allegations.
       Documentation of the analysis may include laboratory notebooks, bench sheets, instrument
printouts, instrumenl  calibration, and confirmatory analysis by alternate methods. Expert opinions
may be required regzirding chemical compounds and the fate and transport of contaminants.
       Evidence preservation is a critical step in prosecuting any case, and environmental cases are
no exception. As pait of the Federal Rules of Evidence, it is the burden of the government to prove
that any evidence presented in court is authentic.  Challenges may be made to every step of the
investigative process in an attempt to show that evidence was improperly handled. This includes
sampling, transportalion, physical and chemical analysis and sample storage. If care is not taken to
properly preserve evidence and maintain chain of custody in every step of the investigative process,
the evidence may be inadmissible at trial.
       Testimony typically occurs long after the technical work is complete, and many details will
need to be recalled. The investigative file should contain records of interviews, photographs, video
recordings, sketches, field project plans, laboratory quality assurance project plans, correspondence,
field notes, chain-of-custody records, calibration records, laboratory bench sheets, reports, and other
pertinent records.  The case agent should maintain contact with the team  members  involved in
evidence collection. The team members should be kept informed about the progress of the case so
they can provide input to conclusions about the evidence they collected and any limitations on its

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use.  In advance of i:he trial, each person should be contacted about potential testimony so they can
prepare.
       Two regional  offices within  the  USEPA have  prepared  manuals  on environmental
investigations. These are available through the regional Internet sites. Region 4 (offices located in
Atlanta, Georgia) h.is prepared the "Environmental Investigations: Standard Operating Procedures
and Quality Assurance Manual." It contains information about different types of investigations,
forms and recordke eping,  sampling design, quality assurance (QA), and procedures for various
sampling media, and an extensive listing of field procedures.I0 Region 10 (offices located in Seattle,
Washington) has prepared an online manual, "Conducting Environmental Compliance Inspections."
There are four main sections to select from: Inspection, Safety, Legal Considerations, and Evidence.
There is also a Photo Gallery section that includes pictures taken from  site inspections.  An
alphabetized index of the topics from the manual is also provided for the reader. "

GATHERING INFORMATION

       Background  information  for an environmental crime investigation  is available from an
extensive and expanding wealth of sources and in many formats.  In the information age, a forensic
investigator can answer the basic questions of "Who?," "What?," "Where?," "How?," "When?," and
even "Why?" through research in print  and computerized sources.
       "Using On-line Searches in Investigations," is a seminal article exploring the online research
tools available for fact-finding and discusses the pros and cons of commercial database research
versus Internet resources.  l2   Other  publications  outlining research resources  include The
Investigator's Little Black Book which covers topics on experts, organizations, and publications from
"Accident Reconstruction" to "Zip Code Information." 13 Sources  of Information for Criminal
Investigators, prepared by Anacapa Sciences to support their courses  in investigation methods and
criminal analysis, is a valuable compilation for information resources.l4 General sources like these
point to specific sources for background information.
       The following sources answer the questions of "Who?," to find out about the corporation or
individual(s) suspected of criminal activities, and "Where?," to locate possible crime scenes and to
link together the properties owned by the suspect(s).
•      Dun and Biadstreet Services provides business histories, operations, public filings and
       credit ratings, with an international scope. The service also provides access to information on
       more than 5i< million global companies. 15
*      EDGAR, the Electronic Data Gathering, Analysis, and Retrieval system, performs automated
       collection, validation, indexing, acceptance, and forwarding of submissions by companies
       and others who are required by law to file forms with the US Securities and Exchange
       Commission (SEC). 16'18
•      Directory ol: Corporate Affiliations is a business information source offering corporate
       linkage coverage, making it a trusted guide to corporate families in the US and worldwide.l9
•      Autotrack and CDB Infotek, database services available from ChoicePoint Company, are
       US  nationwide providers of organized online public record data and other information
       services that are used to  detect fraudulent activity, locate people and assets, and  verify
       information ;md identities.20
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*      m/oUSA is regarded as a comprehensive and accurate source of business and residential
       information covering nearly 12 million US businesses, 1.1 million Canadian businesses, 125
       million US households, and 12 million Canadian households. The company  provides
       information in a wide range of formats ranging from CD-ROM and Internet access to the
       more traditional printed materials. 2I
       Additional information about the crime scene can be obtained using Geographic Information
Systems  (GIS).   These  systems are a powerful tool in assembling and evaluating  multiple
information sources with respect to a particular site. Maps can be prepared depicting many layers of
data such as buildings, surface water bodies, soil types, utilities and sewers, and other  pertinent
features.   The  maps provide  a graphical representation of site conditions,  the surrounding
environment, and potential receptors (such as a sensitive ecosystem or a school building). 22~25
       "How?," as in how a particular chemical product or by-product was produced, might be the
next question for the investigator.   Based on  known facility and business descriptions,  other
resources can be tapped to learn about the processes, raw materials, and waste streams that may be
on a site.
•      Kirk-Othmer Encyclopedia of Chemical Technology is a library of information for the
       chemical industry. The latest version of this 27-volume encyclopedia is now complete and
       includes CAS registry numbers and in-depth information on regulations, patents, and
       licensing.  Articles primarily focus on chemical substances or industrial processes.26
•      Ullmann's Encyclopedia of Industrial Chemistry is another massive source of information
       on chemical industries. This encyclopedia has a 40-volume print set that covers the basics of
       theoretical principles and fundamentals of chemical  engineering along  with  practical
       knowledge of unit operations and plant construction with specific company examples. A
       newer electronic edition is also available.27
•      The USEPA's Office of Water has published a series titled "Development Document for
       Final Effluent Limitations  Guidelines and Standards" for many industries. Included in
       this series are the Landfills Point Source Category, the Alkaline Coal Mining Subcategory,
       the Metal Products and the Machinery Point Source category among others. Diagrams and
       descriptions of industrial processes are provided in the series. 28~30 These documents are
       distributed through the National Technical Information Service (NTIS).  Further details about
       NTIS are provided in the appendix.
•      The USEPA',5 Office of Compliance has developed a series of profiles or Sector Notebooks
       containing  information  on  selected major industries.   Each  notebook includes  a
       comprehensi ve environmental profile, industrial process information, pollution prevention
       techniques, pollutant release data, regulatory requirements, contact names, compliance and
       enforcement history and bibliographic references.31
       Before beginning the on-site investigation, the investigator should explore "What?" chemicals
might be found at the site and the potential risks posed by those chemicals. Many resources can
provide this information. Recent articles point to sources of toxicological information. 32~35 Some
sources are available on the Internet at no cost.
•      The Global information Network on Chemicals (GINC), is a world-wide information
       network for the safe use of chemicals. From this homepage you can explore useful
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       information sources provided by both international organizations and national institutions
       collaborating for safe control of chemicals.36
•      The MSDS search Internet site is a good starting point for locating manufacturers' material
       safety data sheets (MSDS).  MSDS provide detailed information about the hazards of a
       particular chemical and references to further information about that chemical. An added
       feature includes links to translation services that provide MSDS in many languages. 37
•      Also available on the Internet, but for a fee, is the Chemical Abstracts Service (CAS). CAS
       is the producer of the world's largest and  most comprehensive databases of chemical
       information.  The principal databases, Chemical Abstracts (CA) and  REGISTRY, now
       include about 16 million document records  and more than 30 million  substance records,
       respectively. CAS also produces databases of chemical reactions, commercially available
       chemicals, listed regulated chemicals, and compounds claimed in patents. 8
       An overview of forensic techniques for answering the question of "When?" is presented in a
recent  article by  Morrison. 39  The  techniques for age-dating include corrosion models for
underground  storage  tanks,  commercial availability  of  a chemical,  stable isotope analysis,
degradation models, biomarkers, and contaminant transport models.
•      The Integral ed Model Evaluation System (MES) is an interactive system for selecting fate
       models (air, surface water, groundwater and multimedia) most appropriate to the needs of an
       exposure assessor.  It includes information on over 100 models that address items such as the
       input requirements, level of detail, required user expertise, applications, and validation.  It is
       distributed on  a CD-ROM that includes many of the fate models themselves and their
               40-4' >
       manuals.    "
•      The Environmental Fate Data Base (EFDB) was developed under the sponsorship of the
       USEPA to allow rapid access to all available  fate data on a given chemical and to provide a
       data source for constructing structure-activity correlations for degradability and transport of
       chemicals in the environment.  The EFDB  is a tremendous aid in identifying persistent
       chemical  classes as well  as the physical or chemical properties that may correlate to
       particular behavior in the environment.  The EFDB is composed of several interrelated
       files-DATALOG, CHEMFATE, BIOLOG, and BIODEG.  These databases share a CAS
       number file containing over 20,000  chemicals with preferred name and formula and a
       bibliographic file containing full references on over 35,000 cited articles. 43
       "Why?" is a more difficult question to research, but the motivation behind an environmental
crime may be indicated in financial information sources  and by reviewing the suspect's compliance
history.
•      The Financial Crimes Enforcement Network (FinCEN) of the US Department of Treasury
       supports law enforcement investigative efforts and fosters interagency and global cooperation
       against domestic and international financial crimes.  FinCEN is a network linked between
       law enforcement, financial, and regulatory communities. FinCEN strives to work with its
       domestic and international partners to maximize the information sharing network and find
       new ways to prevent and detect financial crime.  **
•      The USEPA created the Envirofacts Warehouse to provide the public with direct access to
       the wealth of information contained in its databases. The Envirofacts  Warehouse allows
       searching on a company or facility name to retrieve environmental information from across
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       USEPA databases (such as the Toxic Release Inventory, RCRAInfo, and CERCLIS). A
       USEPA-internal version of Envirofacts allows retrieval of compliance data as well.45
       Although not  a comprehensive  listing,  this overview  of information  sources for
environmental crime enforcement would be incomplete without the following references to these
important information systems.
•      LEXIS/NEXIS  and Westlaw are two commercial, computerized legal research systems
       which provide access to case decisions and other public records. These records show the
       legal histories of companies and individuals as well as the statutory and regulatory issues.
       Most easily accessed online, these systems also produce traditional print products.  NEXIS
       provides many full-text newspapers, journals, financial reports and news wires from around
       the world. 4647
•      DIALOG is potent information retrieval service providing access to more than 600 databases
       spanning business, science, and technology, many providing full-text online. 48
•      UNEP-Infolerra is an international environmental referral and research network made up of
       177 countries coordinated by the United Nations Environment Programme (UNEP) in
       Nairobi, Kenya.  The US National Focal Point for UNEP-Infoterra is located at the USEPA
       Headquarter;; Library and is managed by the Office of Environmental Information.  The
       services offered by UNEP-Infoterra/USA to requests for environmental information from the
       international  community include document delivery, database searching, bibliographic
       products, purchasing information, and referrals to experts. 49
•      INTERPOL, the International Criminal Police Organization, has an Environmental Crimes
       Committee to combat environmental crime.  Member nations fill out "Eco Messages" on
       international environmental crimes  for INTERPOL.  These messages are compiled in a
       database, analyzed, and circulated to other member nations for the purpose of coordinating
       international law enforcement in the fight against environmental crime.50

GATHERING EVIDENCE

       Evidence  gathered at a crime  site typically  involves  interviews,  visual observations,
measurements, sampling, and seizure of paper documents and records and electronic data.  The
following  sections describe  techniques  and  sources  of  information  with respect  to field
measurements, sampling, and retrieving electronic data. Interviewing techniques will not be covered
in detail.
       Field work is always a challenge, and regardless of the amount of advance preparation, the
unexpected can happen. The team should be able to anticipate and  plan for many potential issues
and problems commonly encountered during the execution  of a search warrant.  Environmental
crime search warrants often entail unique challenges such as chemical exposure risks and safety
issues. Heavy equipment may be needed, unknown chemicals may be present; large quantities of
waste may be involved; and the terrain, temperature, or weather may make sampling more difficult.
To minimize the impact of the unexpected, a well thought out and detailed plan should be developed
and discussed by the team. The  plan should be detailed in writing to the extent possible, based on
available information, and should evolve as new information becomes  available.
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Field Techniques sind Equipment

       From a few key sites on the Internet, a wealth of knowledge regarding techniques, tools,
instrumentation,  and sampling in the field can be obtained.  The following Internet sites have
seemingly endless li.nks to this type of information.
•      USEPA's Technology Innovation Office homepage contains links to publications that can
       be viewed, downloaded, or ordered. There is a section for site characterization that includes
       information on technology and  tools and educational materials.  Links to international
       updates (conferences, newsletters, Internet sites) and to another informative site maintained
       by the TIO abbreviated CLU-IN.51
•      The Hazardous  Waste Clean-Up Information site,  also  known as CLU-IN, has
       documents, reports, videos, and software on various topics related to methods, techniques,
       and developing technologies all ready to be downloaded by the user.  Options available on
       the site  include  the  opportunity to sign  up for email  newsletters  that highlight  new
       publications and  events of interest to site assessment and site remediation professionals.
       Users  can also register for live  Internet events-online seminars with a  web-based slide
       presentation and options for accessing the audio portion of the presentation.52  One of the
       best sections of this website is the Field Analytic Technologies Encyclopedia (FATE). The
       training modules in FATE cover geophysical,  organic chemical, and inorganic chemical
       characterization techniques and data interpretation and include information about work plans
       and data quality objectives. Most of these modules are presented on-screen as a slide-show
       presentation  with notes for each  slide.   Supplemental information and  sources for
       information ;ire generously spread throughout the training program.53 The analytics listing
       in the technologies section has links to further information about the technologies listed such
       as  the  description,  theory  of operation, target analytes,  performance specifications,
       limitations, cost data, and links to vendors.54  A free seminar on systematic planning and
       innovative field measurement technologies is  available on the CLU-IN  site.  Users can
       download thu seminar (including the  speaker's notes) in one of three different formats.55
•      USEPA REACH IT (abbreviation for REmediation And CHaracterization Innovative
       Technologies) has  an  online  searchable database  of innovative  and conventional
       technologies for characterizing or treating hazardous waste sites. The search guides the user
       through questions on the contaminant group of interest, the type of media involved, and the
       technological scale desired to reach its results. Details provided on the technology includes a
       description, verification information, uses by media type,  technical support needed, and a
       cost analysis..  A vendor database  allows the user to search for providers of specific
       technologies and  gives the vendor's Internet site if available.56
•      ETV, the USEPA's Environmental Technology Verification Program, was established to
       verify the performance of new environmental technologies to help accelerate their use. On
       this site, verified  technologies are listed by media and by specific pilot programs and each
       technology ilem includes a verification statement and report.  Links to the Internet sites  of
       project partners, USEPA sites, associations and international sites are also included.57
       An easy-to-u,»e and informative guide on field sampling and analysis is located on the Federal
Remediation Technologies Roundtable Internet site.58 Two field sampling and analysis guides exist
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on the site. One guide covers field sampling and collection techniques with information on tools and
extraction methods cross-referenced with analytes, type of sample media, and technology details.
The tools and extraction methods have links to more specific details on the item such as a basic
description, limitations, and any applicable ASTM standards or USEPA methods.59 The other guide
is a matrix that cross-references sample analysis tools (techniques or instrumentation) to analytes,
sample media, susceptibility to interference, detection limits and more. Just like the other matrix, the
analysis tools listed here have links to further information.  The additional details that can be
obtained include description of the technique or instrument, the applicable uses, the turnaround time
per sample,  the cost per analysis, limitations, and any applicable  ASTM standards or USEPA
methods. 60
       Drum, et al., recently published a textbook-style handbook to detail analytical tests in the
field. The book provides an overview of environmental testing in the first section and divides tests
in  the rest of the book by the type of media.  Directions are specific to certain manufacturer test
products.  Step-by-step instructions, diagrams, and question-and-answer sections are included for
each analytes. 61
       Field Analytical Chemistry and Technology, a periodical published by John Wiley & Sons,
regularly features papers in categories of "Technology Reviews," "Application Reviews," and
"Outfield Reports."62 These reviews and reports are specifically requested by the journal editors
when  readers ask for articles on a particular subject.  The "Outfield Reports" describe  multi
disciplinary teams involved in significant field analytical projects. Some issues are dedicated to a
single topic such as the 1999 issue on Open-Path Fourier Transform Infrared Spectroscopy (Volume
3, Issue 2).
       Recent papers that  discuss developments or trends in  field work  were searched in the
literature. The papers have been categorized into the topics below.
Field Analytical Chemistry
•      Substantial review paper from 1997; topics  covered include portable instrumentation,
       sensors, mass spectrometry, gas  chromatography,  field methods and applications, and
       immunochernical techniques 63
•      Outfield report on work plans and field  analysis for hazardous waste site investigations; cost
       comparisons of traditional and dynamic field investigations;  site application examples M
•      Technology review of trends and advances in field-portable analytical instrumentation;
       outlines operational characteristics that make a "fieldable analytical instrument;" list of past,
       present, and future field analytical technologies65
Aerosol Measurement
•      Review of literature on laser-induced  plasma spectroscopy with emphasis  on analysis in
       gaseous and ;ierosol phases; technique presented as potential next-generation field portable
       instrument for characterizing metal species 66
Volatile Organic Compounds (VOCs)
•      Review of specific recent developments for the analysis of VOCs in ambient air and natural
       waters; includes applications in the field67
Petroleum Hydrocarbons in Soils
•      Technology review on direct-push fluorescence-based sensors for determining subsurface
       chemical contaminants; different systems and configurations presented 68
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Atomic Spectroscopy
•      Review with emphasis on field-portable atomic spectrometry; includes a table of selected
       applications of laser-induced breakdown spectroscopy (LIBS) with elements, matrices, and
       limits of detection 69
Biosensors
•      Technology review of biosensors and the potential for use in screening and monitoring; list
       of analytes £Jid biosensors provided 70
Field Portable X-Rziy Fluorescence (FPXRF) Spectrometry
•      Technology review of FPXRF; evolution and characteristic features of the field-portable
       XRF analyzer71
•      FPXRF analysis of environmental sample; tables with list of available instrumentation and
       vendors and a comparison of calibration methods are included 72
•      Application of FPXRF from  soil  and sediment  metals analysis  to filters  used in air
       monitoring /3
Gas Chromatography-Mass Spectrometry (GC-MS)
•      Technology review of advances in field-portable GC-MS; discussion and pictures of vehicle-
       portable and man-portable systems 74
•      Outfield report on fast on-site analysis of hazardous emissions from fires and chemical
       accidents; details on equipment, sampling and sample preparation, and applications; many
       figures of procedures and techniques are included75
•      Mini-review on fast field screening of contaminated areas; overview of analytical methods
       for mobile G€-MS systems76
•      Outfield report overviewing GC-MS uses including sections on environmental analyses by
       type of sample media77
•      Outfield report on a modular laboratory designed for travel; list and diagram of system
       components 78
Infrared (IR) analysis
•      Portable IR analyzer for low-level hydrocarbon vapors; near real-time distribution data
       included 79
Ion Chromatography (1C)
•      Schematic layout and detailed discussion on a field-portable capillary ion chromatograph80
Ion Mobility Spectrometry (IMS)
•      Technology review on capabilities and limitations of IMS for field screening uses; includes
       details  on different spectrometers,  detection  limits  for  some  pollutants  and  future
       developments81    .
Mass Spectrometry (MS)
•      Technology  review of  direct sampling  mass spectrometry (DSMS) in  analysis of
       environmental samples; discussion of instrumentation, portability, analytical methods, and
       environmental applications 82
 Ultramicroelectrode Arrays (UMEAs)
•      Review on UMEAs with emphasis  on determination of heavy metals  in environmental
       samples; table of analytes and media provided 83
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       When assisting in the execution of a search warrant, the field team needs to ensure that the
evidence collected i> authorized by that warrant.84 Each person involved in the case can ultimately
be called as a witness later. Therefore, each person should keep this eventual testimony in mind
when performing their work. When established procedures are used to collect evidence, it is often
easier to defend their scientific reliability and legal acceptability.  If field conditions necessitate
deviation from standard procedures, the reasons should be documented. Testimony typically occurs
long after field work is complete, and many details will need to be recalled. Good documentation
will make that task easier.
       Once the field work begins, the crime scene should be secured, checked carefully for safety
hazards, and documented using photography, video recordings, and extensive written notes. Prior
evaluation of manufacturing processes and waste management procedures will provide information
needed in finalizing the sampling decisions on-site. Often before sampling, a chemical "hot zone" is
established and delineated. Everyone permitted into the area should have current safety training and
the appropriate level of personal protective equipment (for example, chemical resistant suits, hard
hats, gloves, etc.).
       When possible, field measurements should be performed according to accepted procedures,
and be well documented. Field monitoring and measurement equipment should be maintained and
calibrated,  and periodically checked to ensure they are working properly.  All these  steps are
recorded (even those steps that occurred prior to entering the site).  In the US, chain of custody is
usually  required to be maintained for any item that will be introduced  in legal proceedings.
Interviews  should be recorded along with  field activities such as  sampling and environmental
measurements. Marl.dng, labeling, preservation (if appropriate) of environmental and waste samples,
shipping, and observance of any applicable quarantines (for example certain soils or vegetation
shipped across geographical boundaries) should all be a part of the permanent record of the site visit.

Sampling

       Sampling evidence can be divided into categories in many ways.  One common way is by the
contaminants released such as volatile compounds, toxic materials or "heavy metals." Another is by
the media it is released into such as  soil, air, surface water, or groundwater.  Yet another way of
categorizing waste is by the location at which it is taken such as inside a storage area, in a tank, or in
a river, either upstream or downstream from a site. The approach to  taking a sample depends upon
which combination of categories it falls into; for example, a sample may be for volatile organic
compound analysis from water taken downstream from a plant.
       Sampling equipment can be as simple as a shovel and as sophisticated as a computer
controlled robotic sampling device. Specialized sampling devices are available for many situations.
The device selected should be  appropriate to the material being sampled. Each sampling device
should be inert to the material being sampled. Devices and equipment that are used more than once
are often cleaned in advance and decontaminated between uses. Disposable sampling devices are
sometimes  the best choice. Sample  containers used should be from a known source, inert to the
material being collected, and free of any interferences to later sample analysis. A sufficient number
of sizes and types of containers should be available in the field to collect an adequate sample volume
to perform the required analysis and quality control measures. How samples will be packed, secured
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(chain of custody) as evidence, and transported to the laboratory for analysis should be considered
prior to sending field personnel out to a site.
       Sample records can include the  source of any sample containers used,  including such
information as the company name, the lot number, the types of containers (including the size, color,
and construction materials), and any tamper-proof seals used. It is often standard procedure to wear
gloves while collecting samples  and to change the gloves between each sample to avoid cross
contamination.
       Details regarding types of sample containers, preservation techniques, and holding times
suggested by the US EPA can be found with the analytical test methods. Chapters 2, 3, and 4 within
the Test Methods for Evaluating  Solid Waste (otherwise known as SW-846) each contain useful
tables for these procedures.85
       Environment Canada has two extensive guides for field personnel when site investigation or
sampling is necessary.  The Inspector's Safety Guide provides details on protective equipment,
hazardous substances, and potential hazards when inspecting  industrial sites. 86  The  industrial
hazards section includes chemical  hazards, safety precautions, emergency response actions, and other
extremely valuable information specifically targeted to each industry type listed. The Inspector's
Field  Sampling Manual offers a full guide for sampling from early planning stages (data quality
objectives, equipment and sampling plan checklists, quality assurance and quality control) to on-site
actions (sampling protocol for specific media and laboratory tests) to shipment of samples.87
       The CLU-IN Internet  site, mentioned in  field techniques section,  also includes a few
documents  on sampling in addition to field materials.  88 An American Chemical Society (ACS)
book on environmental sampling contains chapters on sample design, quality assurance and quality
control, and sampling for specific media. The methods mentioned primarily refer back to USEPA
methods.89
       Many USEPA publications and Internet sites provide guidance for planning environmental
sampling work.  Chapters 9 and 10 within SW-846 cover sampling plans and sampling methods.85
A USEPA guidance document on "Choosing a Sampling Design for Environmental Data Collection"
has been prepared and is available to the public, but it is still undergoing peer review. 90
       A useful  reference for soil sampling is the USEPA field pocket guide Description and
Sampling of Contaminated Soils.  91  The American Society for Testing Materials (ASTM) has an
extensive book of standards for environmental sampling with sampling information on a variety of
media (soil, water, waste, air, and biological).92 Standards include terminology, diagrams, material
and apparatus lists, calculations, procedures, and numerous references. Also included is a standard
on QA/QC for sampling activities. Many of these standards are referenced in USEPA's regulations.
       Samples should be collected using procedures specified in the corresponding regulations and
regulatory guidance, if possible. Quality assurance issues and the statistical significance behind the
sampling plan can be crucial to decision-making in environmental forensics and having a statistician
or another individual who understands both field and laboratory sampling issues on staffer available
for consultation is highly recommended.
       The purpose of each sample should be carefully thought out. Some US regulations require
that samples be "representative" of the waste. What  is meant by "representative" is sometimes
defined in the regulation. These definitions vary between the different regulations.  Understanding
the role of each sam pie in proving the overall case is important. A sufficient number of samples
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should be collected from the appropriate areas to ensure that meaningful scientific statements can be
made about the sampling target.  Statistical calculations may be used to determine sample size and
quantity needed.
       Many statistical references and guides for environmental sampling exist.  These cover the
quality assurance and quality control (QA/QC) aspects of sampling, sampling theories, and examples
of statistics used in environmental pollution studies. 93"98 A current USEPA guidance document on
data quality assessment provides an overview of statistical tests. "
       A simple and efficient "generic guide" to sampling survey designs has been provided by the
Energy and Environmental Division of the American Society for Quality.  In it, a logical order of
steps in a sampling plan  is presented  along with explanations of key terms, issues, and a good
summary of responsibilities for the scientific disciplines involved.  It also includes information on
quality control (QC) measures such as field blanks and equipment blanks and the purposes behind
taking the blanks. 1(XI
       The samples are often kept in a secure location under the control of the sampler, preferably in
a locked, initialed container. Samples should be kept  at temperatures appropriate for the type of
samples taken and for the analytical techniques that will be used for testing. Wastes generated during
the  sampling  should be properly disposed according to applicable regulations.  Decontamination
procedures are often followed for sampling equipment that is to be reused and to avoid spreading
contamination outside the hot zone.  Split samples are often collected to enable the defense to
conduct an independent laboratory analysis.
       Each sample container should be marked with a discrete identification number for tracking
purposes.  This can be done using numbered tags or bar codes.  The lid of the container, if any,
should be marked with the sample location as well as the  container itself.  Preservative should be
added to the samples, if appropriate (many waste samples do not require preservation).
       Samples should be shipped as soon as possible, within any applicable analytical holding
times. l01 The samples are required to be packaged for shipment according to applicable regulations,
in a manner  that  protects  the containers  from breakage  or leaking.   Samples  of waste and
contaminated environmental samples should be stored and shipped in  separate containers from
background samples to avoid cross contamination. Incompatibility of chemicals in waste samples
must also be considered to avoid chemical reactions.
       Restrictions for shipment of dangerous goods have been set by the International Air Transport
Association in their Dangerous Goods Regulations Manual. 102  Restrictions may differ between
airlines and countries for some hazardous items. Additionally, the US Department of Transportation
has Hazardous Materials Regulations (49 CFR  100-185) covering all modes of shipping hazardous
materials (ground, sea, rail, air).  103
       As samples are collected, the laboratory should  be contacted from the field. The number of
samples collected should  be discussed as well as when the samples are expected to arrive in  the
laboratory.  A specific person or persons should be identified to receive the samples in order to
maintain a planned chain of custody.
       Chain-of-custody records usually include a standard form documenting the delivery and the
receipt of each sample collected.  Personnel handling the samples are recorded from the initial
contact at the crime scene through each sample transfer until the samples are received in  the
laboratory. l04  Undur chain-of-custody procedures, samples  are to be under the control of  the
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investigation team at all times. The locations of each sample from the time of collection through the
time of analysis in the laboratory are documented. This includes times when the containers are
stored prior to shipment and after they are received by the sample custodian in the laboratory.

Electronic Evidence

       The last 20 years has seen the proliferation of computers in work and personal environments
and  it comes as no surprise that  computer forensics plays a part in  environmental crime
investigations. As discussed by Devaney, Lee, and Topper, the new high-tech area of computer
forensics is being deployed by the USEPA Criminal Investigation Division in the investigation of
environmental crimes. I05
       The environmental protection framework established in the United States leaves open a few
areas of concern for computer forensic experts. Large portions of all compliance monitoring is done
on a self-monitoring basis. A vast amount of this data is being generated by and stored on computers
in either a laboratoiry environment  or by  computerized environmental  monitoring equipment.
Continuous emissions monitoring (CEM) systems are an example of the latter. These computerized
devices are installed in power plants to take direct measurements of gases or  paniculate matter.
After the computer converts  these  measurements to the  units  of the emissions standard, the
information can be automatically sent to the responsible regulatory agency. A similar computerized
database  and reporting system is encountered in leak detection and repair (LDAR) investigations at
refineries. These systems monitor fugitive emissions from the various valves, flanges, and pumps at
the plant.  While LDAR is primarily evaluated during civil environmental investigations, the
computer forensic analyst's job is the same in both examples-to obtain the database or data that is
generated during mcnitoring and analyze and compare the results to the reports submitted to the
regulatory agency.
       A developing  area of environmental crime investigations involves  laboratory fraud.
Laboratory fraud is the deliberate misrepresentation  of analytical results. This misrepresented data is
often submitted to government agencies for regulatory determinations. In any laboratory setting,
there can be a considerable variety of computers and computerized systems connected to laboratory
instrumentation.  These systems are capable of producing data ranging from raw data directly from
the instrument to reduced data in the form of a report for a specific analysis. For this type of
investigation, specialized knowledge of the operating systems and programs can be an invaluable aid
in determining if fraud occurred.
       The means of acquiring, securing, and analyzing computer evidence can vary.  A traditional
approach is  to train investigators in  computer forensic techniques.  But  due to the constantly
changing technology in the computing industry, it is almost impossible for an investigator, who has
many responsibilities in investigations, to keep up with the ever-changing technology.  Another
approach to this problem  is to have a team of computer specialists work as fact-gatherers (seizing
evidence) for the criminal investigator. Eoghan Casey highlights this cooperative approach between
law enforcement, attorneys, and computer professionals in a recent book.  106
       Guidance for handling electronic evidence  has been published by the US Department of
Justice. I0? Two useful handbooks, one by  Stephenson and an older one by Wilding, present the
skills needed to assist in an investigation using the basic computer forensic concepts of preserving,
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collecting, and searching for evidence. 108>109 A book by Sammes and Jenkinson emphasizes four
principles of handling computer evidence that can be used as a helpful guide in investigations. 'I0
       Additional problems areas, such as reverse engineering and internal data security issues, need
to be  addressed  by computer forensic analysts  prior to pursuing  an  environmental  crime
investigation.I05 Reverse engineering involves understanding the code for a computer program and
using that knowledge to determine if the computer system can perform properly for its designed
function. This type of study can ascertain if the results being produced and reported are reliable and
are actually the true results or if the code contains an error that may lead to false results.
       Data security issues within a company can become a serious issue when investigators try to
determine if a suspected chemical release was  accidental, a deliberate release, the action of a
disgruntled employee, or the result of a computer hacker tampering with an automated system. This
scenario can also apply to automated reporting systems that transfer data directly to a regulatory
authority.  These issues may require working with industry to find out if computer  systems are
performing accurately and effectively and to discover if an environmental incident indicates a larger
problem related to computer security issues.
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            LABORATORY ANALYSIS OF ENVIRONMENTAL SAMPLES

METHODS AND 1HETHOD SELECTION

       The programs within the USEPA have been distinguished by the types of sample matrix or
media (air, water, wiiste). These media-specific offices have issued or adopted a variety of methods,
method manuals, and analytical requirements. Some of the most frequently used include the Test
Methods for Solid Waste (referred to as SW-846), Title 40 of the Code of Federal Regulations (often
abbreviated as 40 CFR), and the American Water Works Association (AWWA) Standard Methods
for the  Examination of Water and Wastewater. These testing methods are designed specifically for
certain media, but may be used by multiple USEPA programs.
       Method validation has become an important focus for laboratories. The need for laboratories
to use fully validated analytical methods is discussed by Wood.'" The first step in reaching a "full
validation procedure;" is identifying the analytical problem, any requirements of the customer, what is
feasible for the  laboratory (analytically and  economically  possible), and any  other specific
requirements. A few  questions that could be addressed by a validation plan are listed below.
•      When is the method going to be used?  (Official controls and in-house process control
       methods ma;/ have to fulfill different criteria on precision and accuracy.)
•      What type of answer is required-qualitative or quantitative?
•      In what state is the analytes (bound or free)?
Wood provides details on requirements for method validation through collaborative trials and for
methods validated "i,n-house." m
       An early and  basic guide to QA issues in the laboratory including analytical methods is
provided by Dux.'12  Funk and co-workers provide a "4-phase model of analytical quality assurance"
in their book.  The phases take an analytical procedure  from newly formed to routine usage to
external examination. "3
       Another QA book focusing more on environmental monitoring and instrumental methods or
techniques (for example, solid phase extraction, ICP-OES  techniques, and capillary electrophoresis
are included) has been compiled by Subramanian. l14 Details about the QA and QC needed for the
analysis of airborne particles are presented by both Hopke and Biegalski in their chapters in a recent
book.115'116
       Berger, et al. compiled an impressive reference guide titled Environmental Laboratory Data
Evaluation. This loose-leaf notebook divides into sections on scientifically valid data and overviews
of many US environmental regulations.  Within these overviews, methods are broken down into
initial QC requirements and QC to be performed during the analysis. "7
       Eurachem, a network of organizations in Europe established to promote traceability and good
quality practices, has  some free, downloadable guides on quality in the laboratory. Many guides
have been translated into several languages. Included in the titles are "The Fitness and Purpose of
Analytical Methods:  A Laboratory Guide to Method Validation and Related Topics," "Quality
Assurance for Research and Development and Non-routine Analysis," and "Quantifying Uncertainty
in Analytical Measurements." "8
       Analysts should be aware of potential problems with individual methods and review this
information carefully  before choosing or modifying analytical procedures. QC procedures should be
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used by the analysts >:o evaluate if the choice of the analytical procedures and any modifications are
appropriate to satisfy the data quality needs of the intended application.85

Hazardous and Solid Wastes

       The Test Methods for Solid Waste, or SW-846, are used for environmental crimes involving
the illegal disposal of hazardous waste.  SW-846 is entirely accessible on the Internet.85 The table of
contents and chapter titles are provided for easy reference. Copies of SW-846 in print and on CD-
ROM are also available. "9 The CD-ROM version has a helpful analytes to method cross-reference
table.
       Within SW-846, there is guidance for using the  analytical methods.  Key points that are
developed within this guidance deal with the flexibility of the methods, the stringency of method-
defined parameters, and comparing results obtained from different methods.
       The flexibility of the methods  allows the analyst to make their own choice of  reagents,
supplies, and equipment with the limitation that the method performance must be appropriate for the
intended application. Data quality objectives for the analysis (or knowing just what is needed from
the analysis) address the quality control (precision, recovery, and sensitivity, for example) needed for
the analysis.
       Quality control criteria is provided throughout the methods in SW-846. Many methods in a
numerical series (for example, the 3000, 3500, or 7000 series) refer back to one key location for the
QC information on that series.  Chapter One also provides a quality control  overview for both
laboratory and field activities. Method-defined QC criteria maybe found in the specific methods. If
inconsistencies  are found between the general  QC guidance and method-specific or technique-
specific QC, the latter takes precedence.85
       SW-846 also contains procedures for "method-defined parameters," where the analytical
results are dependant on the process used to make the measurement. Examples of these are the
toxicity characteristic leaching procedure (TCLP), the flash point, and pH. These procedures tie into
regulations that specify certain limitations when classifying material as hazardous waste.  Changes
made to these methods may change the end result or cause a material to be incorrectly identified
(either hazardous or nonhazardous).
       Another cautionary note  within SW-846 concerns comparing  results from  different
procedures. Even though different methods may be designed to measure the same thing,  they may
still produce different results for a variety of reasons. Examples of these include differences in
analytes recoveries  between extraction techniques and differences between the digestion methods for
metals analysis.

Water and Wastewater

       Violations of the Clean Water Act (CWA) often involve the illegal discharge of a pollutant to
a body of water without a permit or in violation of an existing permit.
       Methods for water and wastewater used by the USEPA come from various sources.  Some
have been prepared by the USEPA Office of Water but many others have been adopted for use from
outside sources. The analytical methods prepared by USEPA encompass both organic and inorganic
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analyses and are avai lable for purchase through NTIS (see appendix for more information). 12° Other
USEPA analytical water methods are available in downloadable electronic format. m  A collection
of analytical methods, "Methods and Guidance for Analysis of Water," is available on CD-ROM. It
contains most drinking water methods published by USEPA. 122
       The two primary  sources from outside the USEPA are the American Water Works
Association (AWWA) and the American Society for Testing and Materials (ASTM). The AWWA
provides water methods in the Standard Methods for the Examination of Water and Wastewater.
This reference book is available from the American Public Health Association (APHA).123 ASTM
water methods are taken from the Annual Book of ASTM Standards. 124  An online list of non-
USEPA methods that may be used for analysis includes the source of each method, A list of sources
with the links for the analytical methods in the water section has also been provided.  125'126

Air

       In the US, environmental crimes that involve violations of the Clean Air Act (CAA) are
primarily related to the illegal removal and disposal of asbestos  and the illegal importation of
chlorofluorocarbons (CFCs). Asbestos is regulated under the Toxic Substances Control Act and the
Clean Air Act.  127
       Crimes involving asbestos can have a significant impact on people who are part of the lower
income groups in society.  Many cases deal with asbestos removal jobs performed by indigent or
immigrant workers who have not received training or personal protective equipment (PPE) to
perform the abatemsnt (removal) procedure.   In one case, Spanish-speaking immigrants were
"trained" with videos, but the videos were in the English language, not Spanish. Another  case
detailed abatement conditions so poor that deaf employees could not see each other well enough to
communicate using sign language. Workers without proper training and PPE are exposed to asbestos
fibers which can lead to lung cancer, a lung disease called "asbestosis," and mesothelioma, a cancer
of the chest and abdominal cavities.
       CFCs and other ozone-depleting chemicals have become a serious concern since the adoption
of the Montreal Protocol on Substances that Deplete the Ozone Layer of 1987. As part of the United
States' commitment I o implementing the Montreal Protocol, the Clean Air Act (CAA) was amended
by the US Congress to add provisions for the protection of the ozone layer by restricting the domestic
production and importation in the US. l28
       Methods  for detection  and determination of air pollutants are listed at the Technology
Transfer Network (TTN) Internet site through the Emissions Measurement Center (EMC) and the
Ambient Monitoring Technology Information Center (AMTIC). 129>13° A compendium that lists and
summarizes methods for the determination of toxic organic compounds in air is available online.131
The toxic organic methods are also available in  downloadable form. l32

Additional

       Pesticides are regulated under two federal statutes: FDFRA, and the Federal Food, Drug, and
Cosmetic Act (FFDCA). The Food Quality Protection Act of 1996 (FQPA) amended FIFRA and
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FFDCA to set tougher safety standards for pesticides and uniform requirements regarding foods.133
The Office of Pesticide Programs has two indexes for analytical methods for pesticides. 134'135
       The Code of Federal Regulations also contains methods for analysis and can be accessed at
two different Internet sites. 136>137  Some USEPA methods are easily available on the Internet in
downloadable form.  A table of these methods has been included in the appendix along with the
corresponding Internet site addresses.
       A nearly all-inclusive list of the USEPA methods, revised May 2000, contains the chemical
or method name cross-referenced with USEPA report numbers, location in the Code of Federal
                                                                  1 ^8
Regulations (40 CFR), and media (if an electronic version is available).    A quick reference to
USEPA methods with link connections to the methods or sources for purchase is online as well.139
       A book by Keith provides a short description of USEPA methods listed by analytes. It
includes only brief details on the sampling method for each and a much larger amount of information
regarding the analytical method. 14°
       Comparisons between different analytical methods (both organic and inorganic) and analyte
cross-reference tables are  provided in a handy book titled Guide  to Environmental Analytical
Methods. Tables with guidelines for methods on sampling, sample extraction, and cleanup are also
included. Ml
       Analytical methods used outside the US can sometimes be accessed through a nation's
environmental protection or analytical standards Internet sites. The Environment Canada Internet
site provides a search engine to locate selected environmental protection  publications including
reference methods and guidance documents. The number and title of the document, description, and
purchase price are given in the search results.142  A search by keyword or document number at the
Dutch  National Institute of Public Health and the Environment (RTVM)  Internet site will  yield
detailed abstracts of available reports and order information for the full report. 143
       Standards Australia has a flexible "power search" for documents that allows the user to search
by title, keyword, or standard number. The document number, title, and order info are provided in
the search results. 144 The Environmental Protection Authority for the state of New South Wales,
Australia, has two Internet sites that provide the list of approved methods for sampling and analysis
for water pollutants and air pollutants. 145-146  The methods are listed in tables by the  analytes of
interest.
       British Standards Online requires that Internet site users register first and then login before
beginning any document search. The expanded search feature is impressive and allows wide-ranging
search  options in order to track down documents.  Search results include the document number, title,
and purchase price. 147

INSTRUMENTATION AND TECHNIQUES

       A wide variety of instrumentation is often required for the analysis of environmental samples.
 Analytical Chemistry, a journal  published by the American Chemical Society, is  an incredibly
valuable source  of information for trends and current developments with instrumentation and
analytical techniques. This journal has  yearly review issues that  alternate between  "fundamental
reviews" (1996,  1998, and 2000) and "application reviews" (1997,  1999, and 2001). 148  In the
"fundamental reviews," techniques such as infrared spectroscopy or gas chromatography are covered.


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Updates to the techniques, current research, and applications are often included in each of the
reviews.  The "application reviews" cover areas of chemistry such as environmental analysis, field
analytical chemistry, and forensic science. These reviews are often subcategorized by instruments or
techniques used or the types of samples analyzed. Searches of the table of contents for several years
of Analytical Chemistry issues can be made at the journal's web site.
       Results from  a literature search of recent papers  and reviews  on topics, techniques and
instrumentation are below.  Recent Analytical  Chemistry reviews have been included  in this
grouping.
Environmental Analysis
•      Biennial  review;  developments  in  applied environmental analytical  chemistry from
       November 1998 to October 2000; subcategories of SPME applications, air, water, and soil
       sample type analyses 149
•      Biennial review; developments from November 1996 to October 1998; categorized by matrix
       (air, water, soil, biological); technology cross-reference table I5°
•      Biennial review; developments from November 1994 to October 1996; matrix subcategories
       for analysis applications; quality control and reference materials section l51
•      Trends in environmental analysis; developments  in extraction  methods, MS,  and field-
       portable instiumentation I52
Sample Preparation
•      Review; extensive tables on techniques for preparation of both solid and liquid samples l53
•      Proper subsampling from field sample to the laboratory analysis sample; reducing mass and
                       154
       segregation errors
•      Selection  of extraction technique for organic pollutants in environmental matrices; table
       summaries o:,: analytes extracted by MAE, SFE, and PFE l55
•      Review; solventless sample preparation techniques; covers extraction  with  a gas stream,
       membrane extraction, SPE, and SFE  156
•      Comparison of extraction techniques for environmental solids l57
•      Evaluation o:~ extraction recoveries for certain organometallic compounds in sediment and
       other matrices l58
Air Analysis
•      Review of research published from 1995 to 1998; air analysis by GC; table of sampling and
       injection techniques; table of stationary phases and analytes 159
•      Biennial review; methods for air pollutant analysis covering literature from January 1997 to
       December 1998; contents  divided as gases and aerosols; applications to a  variety  of
       instrumentation I6°
•      Review; analysis of organic compounds in air; massive tables of analytical methods for
       volatile organic  compounds, aldehydes and  ketones,  semivolatile  organic  pollutants,
       polycyclic aromatic hydrocarbons, halocarbons, and isocyanates and amines  161
•      Review; sorbents used to trap volatile organic compounds from air 162
•      Analysis of process gases; overview of instrumentation and techniques, sampling systems,
       calibration and traceability, and data collection and processing 163
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Water Analysis
•      Review covering developments in water analysis from 1999 to 2000 with a few significant
       2001 references; contents categorized by pollutants 164
•      Review; methods for preconcentrating organic and inorganic compounds l65
Atomic Spectrometiy
•      Annual  review; atomic  spectrometry  update on  analysis of environmental  samples;
       categorized by media (air, water, soils, geological) l66
•      Annual  review; combined atomic absorption and fluorescence with atomic  emission
       spectrometry; covers literature from 1998 and 1999; topics include sample introduction,
       instrumentation and coupled techniques 167
•      Annual review; atomic spectrometry analysis for elements in air, water, soil and geologic
       materials; includes MS, XRF, AA, ICP-MS, AES, and other instrumentation 168
•      Trace element analysis of airborne particles; overview of methods with comparison between
       GFAAS, flame AAS, ICP-AES, and ICP-MS l69
•      Biennial review; cited papers from 1998 and 1999; developments with instrumentation and
       operation 17°
•      Annual review; atomic spectrometry update on environmental analysis; topics categorized by
       sample media 171
•      Annual review; developments in atomic absorption and fluorescence spectrometry in 1997
       and 1998 m
•      Invited lecture on the future of atomic spectrometry in environmental analysis; discussions
       on sample preparation, instrumentation, detection power, speciation, and field portability;
       also includes, nearly 200 references 173
•      Biennial review; publications from 1996 and 1997 on techniques of analytical atomic
       absorption; electrothermal  atomization, flame atomic absorption  and  emission, laser
       techniques, and vapor-phase sample introduction are covered l74
Capillary Electrophoresis (CE)
•      Review; analysis of environmental samples; charts of fresh and salt water, wastewater, and
       industrial process water matrices; chart for soil, sediment, and biological samples 175
•      Review; status of CE for organic environmental pollutant determination based on papers
       published from 1997 to early 1999; excludes pesticides and inorganic pollutants from the
       review 176
•      Review; analysis of inorganic pollutants; environmental applications divided by sample
       media; analytes tables for atmospheric, aquatic, and soil samples l77
•      Review of references published mainly from  1995 to 1997; analysis  of environmental
       samples; tables of sample matrices and ions 178
•      Review; sepiiration and analysis of environmental pollutants l79
•      Biennial review; covers the period of October 1995 to October 1997; focus on significant
       developments in theory and practice  of CE;  advances in  performance optimization,
       instrumental configuration, and detection strategies I8°
•      Review; focused on methods developed since 1994 on the determination of pollutants;
       divided according  to  pollutant  type;  large  table of environmental  applications and
       corresponding references m
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•      Review; analysis of inorganic pollutants l82
•      Review; extensive table of anions, sample matrices and electrolyte system 183
Gas Chromatography (GC)
•      Biennial review; covers fundamental developments in gas chromatography published from
       1998 and 1999; topics include adsorbents, phases, theory, and new technology m
•      Biennial review; GC developments published in articles from 1996 and 1997 18S
•      Review; sample introduction techniques; GC-MS and GC-FTIR applications 186
•      Review; trace analysis of pesticides by GC; discusses  differences between detectors and
       extraction techniques 18?
•      Overview of sample introduction and sample preparation of volatile organic compounds for
       GC analysis 188
•      Automated GC  system used by the Taiwan EPA for measuring ambient VOCs 189
Gas Chromatography-Atomic Emission Detection (GC-AED)
•      Empirical formula study  of chlorofluorocarbons using GC  coupled to atomic emission
       detection I9°
Gas Chromatography-Mass Spectrometry (GC-MS)
•      Analysis of petroleum products within forensic science  review 191
High Performance Liquid Chromatography  (HPLC)
•      Biennial review; fundamental developments in column liquid chromatography equipment
       and instrumentation from  October 1997 to October 1999; instrumentation, columns, and a
       variety of detectors are covered 192
•      Biennial review; developments in equipment and instrumentation from October 1995 through.
       October 1997 193
•      Biennial review; theory and methods in liquid chromatography from October 1995 through
       October 199 7; topics include data analysis, biopolymer separations, affinity chromatography,
       ion chromatography, and preparative LC l94
•      Review of li ierature methods published from 1989 to 1996; vast chart of anions, stationary
       and mobile phases, methods 195
•      Review; determination of nitrite and nitrate in environmental samples 196
•      Review; determination of hazardous  compounds (PCBs, dioxins, etc.) using reversed-phase
       HPLC; stationary phases discussed 197
Ion Chromatography (1C)
•      Review of articles published from 1997 to 1999 with some classic references; detailed chart
       of inorganic anions, matrices, columns, detectors; environmental applications 198
•      Review; sample preparation and separation  techniques for 1C and CE; numerous figures;
       comparison of advantages and disadvantages of 1C and  CE '"
•      Elemental analysis of airborne particles; included are tables on separation methods and filter
       media200
Inductively Coupled.  Plasma (ICP)
•      Review; book selection on advances  in ICP-Atomic Emission  Spectrometry (ICP-AES) and
       ICP-Mass Spectrometry (ICP-MS); analytical  capabilities and interferences of the  two
       spectrometers; practical applications highlighting soil samples 201
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•      USEPA methods and elements list; ICP-Optical Emission Spectrometry (ICP-OES) and ICP-
       MS technique comparison 202
•      Elemental spieciation using ICP-MS interfaced to a liquid chromatograph 203
Infrared (IR) Spectrometry
•      Biennial review; articles published during 1998 and 1999; focus on 2D IR, combinatorial
       chemistry, and human health 204
•      Biennial review; covers published literature from November  1995 to October 1997 on
       aspects of IR spectroscopy relevant to chemical analysis; includes a section on environmental
       analysis 205
Liquid Chromatography-Mass Spectrometry (LC-MS)
•      Review; general overview of instrumentation; environmental applications 206
•      Review; current and future developments in pesticide trace analysis 207
•      Determination of herbicides in water; techniques and applications to herbicide analysis 208
•      Analysis of surface and waste water with atmospheric pressure chemical ionization 209
Microwave Assisted Extraction (MAE)
•      Review; extraction of environmental samples; tables  for extraction of PCBs, pesticides,
       phenols, and organometallics in environmental matrices 21°
•      Review; tabL: comparing extraction techniques; tables for extraction of persistent organic
       pollutants and pesticides 2n
•      Review; extraction of petroleum hydrocarbons from contaminated soils 212
Mass Spectrometry (MS)
•      Annual review; update on developments in instrumentation and methodology with atomic
       mass Spectrometry 213
•      Annual review;  advances  in instrumentation, methodology,  and in understanding of the
       fundamental phenomena of atomic mass Spectrometry 214
•      Annual review; developments from 1997 and 1998; trends identified in each section 215
Pressurized Fluid  Extraction (PFE) - also known  as Pressurized  Liquid Extraction (PLE) or
Accelerated Solvent Extraction (ASE)
•      Review; extraction of persistent organic pollutants;  tables of conditions found in  the
       literature with matrices of soil, sediment, sewage sludge, dust, clay, fly  ash, and biological
       tissue216
       Extraction of polycyclic aromatic hydrocarbons from soils 217
       Extraction of PCBs from environmental samples as compared to SFE
       Extraction of hydrocarbons from soils 219
218
•      Recovery of PCBs from organic matrix; comparison to Soxhlet extraction 22°
Supercritical Fluid Extraction (SFE)
•      Review; methods, instrumentation, applications including environmental221
•      Discussion of advantages, limitations of SFE 222
Solid Phase Extraction (SPE)
•      Review; environmental applications,  coupling  with capillary electrophoresis; table of
       analytes for SPE-CE 223
•      Review; method development, sorbents, coupling with liquid chromatography224
•      Review; multi-residue analysis of organic contaminants in water 22S
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•      Review; historical to present day technical developments for SPE of organic pollutants in
       water226
•      Review;  functionalized cellulose  sorbents for  preconcentration of  trace  metals  in
       environmental analysis 227
•      Review; recent developments in SPE based on polymer sorbents 228
•      Developments in SPE disks for use in environmental chemistry for analysis of trace organic
               j  '.'29
       compounds
Solid Phase Microextraction (SPME)
•      Review; extraction modes, fibers, and instrumentation interfaces 23°
•      Review; determination of organic pollutants in environmental matrices; tables of published
       applications in air and liquid samples 231
•      Review; trace element speciation; table of species, sample type, and SPME method 232
Ultra-Violet (UV) Spectrometry
•      Biennial review; developments in ultraviolet and visible absorption  spectrometry from
       January 1996 through October 1997; subject matter covered in  categories of chemistry,
       physics, and applications 233
X-Ray Spectrometry (XRS)
•      Annual review of X-ray fluorescence spectrometry; developments over the period of 1999 to
       2000; details on instrumentation and applications, including environmental234
•      Analysis  of ambient  air samples;  topics includes  method  comparison,  sampling,
       interferences, and calibration 235
•      Annual review of X-ray fluorescence; covering papers published from 1998 to 1999236
•      Biennial review of X-ray spectrometry; literature from late 1998 to October 1999 237
•      Annual review of X-ray fluorescence spectrometry; covers work published from 1997 to
       1998; topics include instrumentation and applications 238
•      Biennial review; covering advances in X-ray spectrometry from November 1995 to the fall of
       1997; contents include categories on excitation, detection, and quantitation 239
       Various extraction methods for environmental analysis are presented in a book by Dean. The
book is divided by aqueous and solid samples and covers many techniques such as SPME, SFE, and
MAE.  Theoretical considerations and methods of analysis are discussed for the techniques and a
chart comparing all the extraction techniques is at the end. 24°
       Barcelo has compiled a significant book in the "Techniques and Instrumentation in Analytical
Chemistry" series.  Chapters submitted  by various authors  fall into these key sections: Field
Sampling  Techniques  and  Sample Preparation, Quality Assurance,  Reference Materials, and
Chemometrics, Application  Areas, and Emerging Techniques. 241
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                             EVIDENCE PRESENTATION

LINK ANALYSIS

       Link analysis or criminal intelligence analysis has long been a tool of traditional criminal
investigations.  It has  also become a method used to support criminal  and civil environmental
investigations. The various charting techniques used have covered many types of analysis, including
the Traditional Link Analysis, Association Analysis, Telephone Record Analysis, Event and Activity
Flow  Analysis, Commodity Flow, Financial Analysis, Crime Pattern Analysis and Time/Event
Analysis.  Other chctrt types have also been developed to depict how an environmental crime was
committed.
       Link analysis charts have been proven to be an effective and successful tool in US trial
presentations to depict a complex set of events along with the specific information  related to the
crime. These chart); help the judge or jury understand the complex relationships which exist in
environmental crime. Environmental crimes are often complex in nature and very difficult to follow,
especially if the crime involves keeping track of the activities of many people and  the timing of
particular events, such  as when various loads of waste are transported.
       Anacapa Sciences provides training in traditional methods of link analysis using the link,
event, activity, and commodity charting methods.242  This basic method can easily involve rolls of
paper and hundreds of "Post-it Notes."  Anacapa has developed a computerized alternative to this in
the Enhanced Criminal Network Analysis (ECNA) computer program.
       A more powerful approach is  provided by i2, Inc. 243  The Analyst's Notebook software
package has two  main tools for different types of analysis,  the Link  Notebook and the Case
Notebook.
       Link  analysis  is  being  used  successfully  by NEIC to  connect complex details  of
environmental crimes.  One use was  with USEPA's reformulated gas initiative. This initiative
required that the complex relationships between  a company and employees be clearly defined and
identified. For a higli profile laboratory fraud case, NEIC developed timeline charts using i2's Case
Notebook.  After the defendant pled guilty, the timeline charts were submitted to the court for the
sentencing phase to <:how the gravity of the fraud and illustrate the length of time that the fraud had
been committed.
       Another link analysis chart developed in a case against an environmental disposal company
showed the relationship between the proposed method of waste disposal  and the actual method of
disposal.  A corresponding link chart  illustrated the telephone calls made by the defendants and
helped to successful! y prove the conspiracy. The guilty parties received stiff jail sentences and were
forced to pay $1.27 million in clean-up costs.
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ENVIRONMENTAL SCIENCE AND THE COURTROOM

       The end result of any actions performed by any forensic laboratory may be decided in a court
of law. Data and scientific opinions will be admitted into evidence if the scientific information is
relevant and reliable. The debate in the United States legal system over what scientific opinions and
data may be included into evidence is ongoing. Understanding some of the factors that may shape
the decision to accept or reject a scientist's testimony can benefit members of a forensic science
community.
       In US  federal environmental enforcement cases, if defendants  refuse to  negotiate a
settlement, the case proceeds to a trial in the federal court system.  With a trial comes the challenge
of understanding the; scientific experts and scientific opinions presented in  the case.
       As a result or a US Supreme Court case referred to in short as Daubert, federal judges were
given the responsibility of being the "gatekeeper" of scientific evidence in  the courtroom.244 The
benefit of this ruling is that it prevents so-called "junk science" from being presented and possibly
misleading a jury.  (Juries composed of US  citizens  often serve as fact-finders.)  In many
environmental cases, a federal judge will hold some type of Daubert hearing before expert testimony
will be heard.
       In a Daubert hearing, both sides must present their best case regarding the scientific work and
be prepared to defend the work as having a sound scientific footing. The opinions presented may be
based on standard methods or on a novel application to established science.  In addition  to
questioning  by lawyers, judges often delve into the basis for expert opinions in order to find  the
answers to two key questions.
•      Is the opinion relevant?
       Does the opinion presented deal with the issues in the case? Do the scientific studies or
research cited to support the opinion given have a direct relationship to the issues in the case?
•      Is the science reliable?
       Is the methodology that was used good science?  (Was the method validated?) How were all
aspects of the measuring process performed (from sampling to the laboratory analysis)? Were all the
necessary QC actions taken to ensure the reliability of the data?  Were established procedures for
each action followed in the field, in the laboratory, and in all the steps in between? (Defensibility of
field methods is no different from that of laboratory methods.)245
       Two recent environmental crime cases involving NEIC demonstrate  problems that can occur
with determining the reliability of the science involved. One case necessitated that USEPA guidance
be challenged and shown to be faulty. In another case, the company being prosecuted challenged
their own data to show that it was unreliable and could not be used against them.
       In the first case, the owner and operator of a fertilizer manufacturing company knowingly
endangered his workers by exposing them to cyanide waste. A criminal investigation began as soon
as USEPA learned cf the illegal hazardous waste disposal activities that physically crippled and
caused permanent brain damage to one of the employees. The employee had been sent into a 25,000
gallon storage tank to clean out the cyanide sludge inside without the required protective equipment
and without telling the employee that the tank contained cyanide  waste. Even though they asked
direct questions regarding cyanide exposure, rescue workers and medical personnel were not told
that the storage tank sludge contained cyanide.
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       Among other things, NEIC developed a storage tank model to demonstrate that the waste
material  in  the  storage tank  was capable of generating the toxic  gases in harmful levels.
Additionally, because USEPA guidance on hazardous waste contained a flawed analytical method
for measuring cyanide, other methods were employed to prove that the waste was hazardous.  The
Daubert challenge from the defense attacked the tank model and the waste sample collected from the
storage tank on the premise that neither were representative of the actual circumstances in 1996.
       An NEIC expert testified during the Daubert hearing, and was able to satisfy the judge that
his opinion was based on reliable data and corroborating evidence.  At trial, he presented his opinion
that the waste was hazardous and explained how the evidence (testimony of others, NEIC sample
analyses, and medical records) supported his opinion.  The defendant was sentenced to a 17-year
prison term, the longest sentence ever imposed for an environmental crime, and was ordered to pay
$6 million in restitution to the injured employee.246
       In the other case, the challenge raised by the defendant during the Daubert hearing was
directed against the expert for the prosecution, as well as the defendant's own chemist and data. A
major meat processing company and several of the company managers were charged with felony
counts of conspiracy, illegal dumping of pollutants, and filing of false reports in violation of the
federal Clean Water Act.247'248 The company's discharge monitoring reports had been falsified to
indicate compliance with the discharge permit provided to the wastewater treatment plant that treated
waste from the company's slaughterhouse operation.  Measurements taken to monitor discharges
were recorded by the company chemist in two sets  of books.  One set contained the real numbers
from testing and the other set contained the number fabricated for reporting to the USEPA.
       The methodology used to obtain the test results was not challenged in the Daubert hearing.
The company challenged their chemist's application of the method, claimed that the numbers could
be higher or lower, and argued that their own chemist used no quality control and was incompetent
and unreliable. An NEIC expert was required to examine the company's data and offered the opinion
that it was of sufficient quality to prove permit violations. The court accepted that this data could be
used in the trial.
       The  personal responsibility for quality work  from  all  members in  an environmental
investigation and the relationship between the QA procedures and the actions actually performed
now blends together to have a significant effect on actions within the courtroom.  The scientific
expert chosen to give his or her opinion on the scientific data and how it relates to the case must be
someone with the experience, education, training, or "on-the-job" experience to address the issues.
The expertise of the scientific witness is not always the focus of the strongest amount of scrutiny; it
is quite often the execution of the methods involved in the measurement process (sample collection
and handling, chain of  custody, QA/QC, etc.) that  is examined most  closely.   Therefore, all
individuals involved in any part of the investigation must produce defensible work.
       A thorough and well-referenced guidebook for legal professionals and scientists who may be
providing expert testimony is the Scientific Evidence and Experts Handbook.249 It is a compilation
of eight chapters on topics such as "Pretrial Preparation in Scientific Cases," "Finding, Hiring, and
Supporting Scientific Experts in Complex Scientific Evidence Cases," and "Scientific Evidence in
Criminal Cases," written by litigators with years of experience in the courtroom. A year 2000 update
to this handbook is also available. 25°
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       With the responsibility of being a "gatekeeper" for scientific and technical testimony in the
courtroom, district court judges must now be able to perform inquiries into technical matters and
evaluate scientific evidence.  In order to assist judges in this potentially overwhelming task, a
number of solutions have been proposed and will be tested for their usefulness and legal reliability in
the coming years.25' The Reference Manual on Scientific Evidence produced by the Federal Judicial
Center is the easiest aid to obtain. Both editions of the manual can be downloaded from the Federal
Judicial Center Internet site in whole or in separate sections. 252  Sections include discussions of
statistics, toxicology and DNA evidence among many others.
       Another aid to judges is the Court Appointed Scientific Experts (CASE) project developed by
the American Association for the Advancement of Science (AAAS). 253  Concerns that a court-
appointed expert might not be fully impartial or that such expert testimony could tip the balances in
the legal system has many trial lawyers questioning the legal viability of this project.  The Federal
Judicial Center has indicated support for the project and will evaluate the project's usefulness after 5
years. 254
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                                 SELECTED TOPICS

LABORATORY FRAUD

       Laboratory fraud is defined as the deliberate falsification of analytical or quality assurance
results, where failed method and contractual requirements are made to appear acceptable during
reporting.255  Laboratory fraud has also been defined as a deliberate mechanism, concealment, or
falsification producing detrimental reliance on analytical results.256 Laboratory fraud has historically
been detected either by reports from disgruntled employees or electronic data audits.  In both
circumstances, the laboratory has already performed fraudulent work and the damage is done.255
       In a paper presented at the USEPA 18th Annual National Conference on Managing Quality
Systems for Environmental Programs, Worthington and Brilis discuss the assumption made by many
data producers and users that analytical data are authentic when, in fact, the data are not authentic.
There are a number of terms used to describe non-authentic data. Some people use the term "data
integrity" to consider all issues.257
       Lab fraud c.ises generally are brought forward by informants, disgruntled employees, or
outside audits.255 In 1999, the Center for Strategic Environmental Enforcement (CSEE), Criminal
Investigation Division (CID), Office of Criminal Enforcement, Forensics, and Training performed an
extensive review of all USEPA CID lab fraud cases that had been investigated from 1983 through
1998.  The review identified 63 cases involving data falsification committed by a- third party
laboratory.256 Third party laboratories are labs hired by companies to do their analytical testing (as
opposed to performing tests using an in-house lab).
       The extent of lab fraud cases has grown exponentially over the last few years. In the last 2
years alone, 11 new lab fraud cases have been opened in the United States. 256 This growing area of
environmental crime is now being defined and addressed as a source of concern for enforcement
agencies.
       A literature review was conducted to examine the scope of the laboratory fraud problem. In a
lab fraud case from 1995, Eureka Laboratories, Inc. was fined $1.8 million and two chemists were
convicted of federal fraud charges related to the manipulation of lab results for federal contracts.
The convictions came after the federal government suspended Eureka from contracting because of
allegations of fraudulent practices.258
       In another case, Donald Budd, the former owner of Texas Environmental Services  of
Beaumont, Texas, was sentenced to 6 years in federal prison after misrepresenting the lab's methods.
The laboratory tested water for cities, refineries, and other companies.259
       A slightly different type of laboratory fraud case involved a consulting company located in
Portland Oregon. OnJune 14,1996, the USEPA published an account of the fraudulent reporting of
data by Robert Cyphers. 26° According to the USEPA statement, Cyphers, the former president and
owner of UST Environmental Services, plead guilty to four felony counts involving the submission
of written false statements to the government. As part of the plea agreement, he agreed to serve a
recommended 30-month term of incarceration.
       Cyphers had operated a company whose primary business was the removal of leaking
underground storage tanks and the subsequent cleanup of contaminated soil and groundwater. He
had submitted over a. thousand fictitious laboratory analysis reports regarding the extent of soil and
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groundwater contamination to the Oregon Department of Environmental Quality. These reports are
used by regulatory agencies to determine the degree of environmental contamination and cleanup
needs necessary to protect human health and the environment. Based upon the few sites that have
been re-sampled, analyses have determined that petroleum contamination still exists at the sites.
       On January 7,1998, Intertek Testing Services Environmental Services laboratory (ITS) made
a voluntary disclosure that fraudulent practices were being conducted in their laboratory located in
Richardson, Texas. 261  ITS disclosed that employees had been improperly manipulating QC data
during the time period later determined to be 1991-1997.  The manipulations included actions
summarized with terms like "shaving," "juicing," and "time traveling" in order to make data appear to
meet QC requirements.  These practices affected hundreds of projects,  thousands of clients, and
hundreds of thousands of samples.
       In another case, the  USEPA Region 5 Laboratory, also known as the USEPA Central
Regional Laboratory, was investigated for allegations of altering test results.  A  criminal
investigation regarding these allegations was conducted by the US Department of Justice.  The
USEPA alerted federal prosecutors handling pollution cases, as well as scores of suspected polluters,
that some data used in cases against polluters might be tainted. It was reported earlier that an
unpublicized, 28-month investigation of one section of the USEPA's Central Regional Laboratory
found that USEPA  supervisors, along with private contractors in the lab's organic  section, had
mishandled some time-sensitive test samples by not initiating their analyses within required holding
times.262-264
       Worthington  groups  non-authentic data  into two  types:  unintentional  and  intentional.
Unintentional errors include those made during sample collection, calculation errors, or transcription
errors. Intentional errors include the improper reuse of instrument calibration data, altering spiked
samples to  achieve the desired recovery level, and changing the date of analysis to suggest that
samples were analyzed  within holding times among many others.257
       An  internal  USEPA memorandum discusses  contributing factors for laboratory fraud.
Managers such as USEPA officials, prime contractors, and laboratory owners may rationalize or
even foster laboratory fraud when these factors exist.
•      Ineffective oversight of laboratory data
•      Shrinking market resulting in a focus on production over quality
•      "One size fits all" approach to analytical requirements
       According to the memo, lack of oversight has been identified as a problem in prior Office of
Inspector General (OIG) and USEPA efforts. The second factor, a shrinking market, is an issue that
cannot be influenced by the USEPA.  The final condition, a "one size fits all" approach occurs in
contracts that  define specific quality  assurance  (QA) and quality control (QC) requirements.
Although laboratories bidding on contracts are aware of the requirements, in specific cases they may
view them as too stringent and cut corners to save money.265
       Several publications have been written on laboratory fraud detection.  In addition to reports
by a disgruntled current or former employee, other sources of information leading to reports of lab
fraud include data reviewers and data users, auditors and inspectors, and regulators. 256
       Another indication of fraudulent data reporting is an anomalously low bid on a contract. Bids
that are 50% lower than every other bid indicate  the possibility of lab fraud according to Stephen
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Remaley, an investigator for the USEPA. Remaley describes the types of laboratory fraud as well as
methods for detection of fraudulent practices. 266
       Simmons presented guidelines being developed by the California Military Environmental
Coordination Committee for the prevention of laboratory fraud.  The techniques which are being
considered include double-blind proficiency test samples, audits, data validation, and electronic
record audits. 258
       According to Worthington, an important step in processing non-authentic data is making and
documenting decisions when the problem is first  discovered.  Also  emphasized is the timely
reporting of the potential fraud and the establishment of a reconciliation process.257 Resources that
can be used to assist in the detection of laboratory fraud and the subsequent reconciliation of data
include  laboratory employees, data users, and inspectors.256
       A USEPA Region 9 paper contains a list of laboratory fraud terminology and provides a table
containing a description of how to recognize each technique and real world examples of each type of
laboratory fraud. The table also provides suggestions for further investigation for each technique
detected. 255

CHEMICAL FINGERPRINTING

       One useful  forensic  technique  used  in  environmental investigations  is  chemical
fingerprinting. Chemical fingerprinting is used to identify an unknown chemical or compound, or to
trace contaminants back to a particular origin. For example, petroleum contamination can often be
traced back to a particular refinery based on additives that are unique to that refinery or a study of
metals in areas surrounding a smelter can point back to the smelter effluent as the cause of pollution.
       Morrison reviews the use of chemical fingerprinting for petroleum hydrocarbons in recent
articles. 267'268  Some items discussed include proprietary additives, alkyl  leads, oxygenates, dyes,
isotope  analysis, and  transport models.267  Morrison also discusses the chemistry and transport of
petroleum hydrocarbons and contaminant transport modeling in a recent book. A similar overview
of chlorinated  solvents is also included.269
       Chemical fingerprinting as it relates to oils, gasoline, and diesel fuel is addressed by Bruya.
He reviews the test methods and analyses used in identifying and matching samples, and provides a
review on evaluating chemical data used in fingerprinting. Tables of production specifications with
test methods and of  petroleum compositions with  references are provided.  Metals analysis is
mentioned briefly. 27°
       Studies on the effects of lead-based gasoline to the environment and of the residual traces left
in the environment after discontinuing the use of lead-based gasoline frequently use lead isotope
analysis for source identification and age dating. The signature left by lead in gasoline is discussed
in an article by Hurst and co-workers.271
       Determining the sources of lead in the environment has been of world-wide interest. Lead
isotope ratios have been studied in sediments in Scotland by Farmer, et al. to determine geochemical
origins of lead and relative contributions from industrial and vehicle-exhaust emissions.272 Gulson
and co-workers detail a study on lead contamination that was centered in the intersection between a
rural and an urban  area in South Australia.  Natural soil lead was considered along with  orchard
sprays, power stations, smelters, and gasoline additives.  Isotopic  ratios  indicated that while the
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natural  soil lead was the major component  for soil below  30 cm,  contamination from  the
tetraethyllead additive in gasoline was determined as the major component in surface samples.273 A
study of river waters flowing into San Francisco Bay, California from 1995 to 1998 traced the lead
deposited in the drainage basin. Dunlap and colleagues saw a trend from leaded gasoline toward
isotopic concentrations similar to inputs that occurred during hydraulic gold mining in 1853.274
       Elemental ratios can also be used as a means of source identification. Monna and colleagues
used lead isotope data and elemental ratios to  study the lead isotope composition in lichens and
aerosols to determine the impact of regional volcano activity.275  Elemental association was also
used by Rauch, et al. Lead and platinum group metals in road sediments were studied using laser
ablation-inductively coupled plasma-mass spectrometry.276
       Particle analysis is another way of tracing sources of pollutants. An older article by Linton, et
al. examines the combined use of the scanning electron microscope with energy dispersive X-ray
analysis, multi-element analysis, and X-ray powder  diffraction to identify  the sources of lead-
containing particles in urban dusts. The techniques used in the lead tracing study are described and
the strengths and limitations of the techniques are summarized. 277
       Particle source identification for air quality management is discussed by Hopke. A section
covering basic principles and natural physical constraints leads into sections on source composition
for airborne particles, chemical mass balance, multivariate calibration methods and factor analysis
methods used for these studies. 278

ACCREDITATION OF ENVIRONMENTAL FORENSIC LABS

       Due to some recent and unfortunate  events, forensic laboratories have come under greater
scrutiny for analyses and operations.262-264'279-283 "Trustworthiness" arid "responsibility" have been
repeating themes as questions about the real quality behind scientific data are propagated in the
press. The need to assure the public that  a forensic lab is capable of providing  legally defensible
analyses has made accreditation the goal of many forensic laboratories at both the federal and state
levels.28'-286
       Many accrediting bodies exist and while the basic goal of assuring the reliability of data from
forensic laboratories is the same, there are variations between each that must  be evaluated by each
laboratory seeking a source for accreditation.
       In the case of NEIC, this facility  obtained accredited status for  the laboratory's asbestos
analysis program under the National Voluntary Laboratory Accreditation Program (NVLAP).287-288
Since asbestos analysis accounts for only a portion of the total analyses conducted as part of the
laboratory operations, additional accreditation in other laboratory  functions was desired.
       Accreditation of  laboratory  operations alone  was insufficient  to encompass all NEIC
activities since the functions extend beyond sample analysis. Expert reports and expert witnessing,
field investigations including sampling (single media or multimedia), facility audits, and advanced
analytical applications also needed incorporation into an accreditation standard.
       NEIC  investigated the possibility  of obtaining accreditation through the  National
Environmental  Laboratory Accreditation Program (NELAP), the American  Association  for
Laboratory Accreditation (A2LA),  and the American Society of Crime Laboratory  Directors/
Laboratory Accreditation Board (ASCLD/LAB) before reaching a viable accreditation standard
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agreement for center activities (laboratory, field, courtroom) with the National Forensic Science
Technology Center (NFSTC). 289'292-285  The NEIC accreditation standard used elements of the
ASCLD/LAB manual and met the requirements for ISO/EC Guide 25 and ANSI/ASQC E4.
       Sufficient funding to adequately meet the challenges of accreditation is a concern for forensic
laboratories. Overall resources for the day to day implementation of accreditation standards need to
be considered. A California state auditor report on forensic labs pointed out that money is needed
not just for primary elements of accreditation (such as proficiency testing and court monitoring
programs).   Money also needs  to  be  allocated for capital  equipment replacement, facility
improvements, management information systems, and forensic examiner training programs.286 Time
is another required resource. A drop in efficiency is to be expected as employee time is funneled into
the production of documentation and reports.293
       Writing an accreditation standard for a forensic laboratory and establishing a quality system
to maintain the standard is not enough to ensure that quality scientific data is being produced unless
each member of the lab takes responsibility for their part in the system.  Rosecrance suggests the
implementation of an ethics program in the laboratory.294 In this article, the author covers the kinds
of policies and actions that are needed to inform employees regarding unacceptable and fraudulent
behavior. Additionally, a detailed table of unacceptable laboratory practices and the corresponding
actions to avoid these problems is a valuable tool for manager and scientist alike.
       Two-interesting articles about the implementation of quality systems are found in the
technical program of the 19th Annual National Conference on Managing Environmental Quality
Systems.295 MacMillan tells the success story and the means of quality system implementation for a
small environmental testing laboratory. Of special note was the decision to hire a dedicated quality
staff to document and formalize components of the program. The perspective of implementing a
quality system on a state-wide level with a division of laboratories is given  by Siders. In it, the
author lists the fundamental and critical elements needed in a laboratory quality system, and the
division-wide policies, standard operating procedures and manuals used to effect the laboratory
accreditation.
       The USEPA Quality System has some guidance documents that take into consideration the
recent developments in the federal legal system regarding the admissibility of scientific evidence. A
table of these documents and the Internet site locations are provided by Brilis, et al.296 Additionally,
the authors have provided a detailed list of criteria to consider in every stage of an environmental
investigation in  order to ensure that quality is maintained and is consistent.
       A 1996 book by Giinzler provides some details on different accreditation systems world-
wide. Many authors contributed brief descriptions  of accreditation systems in different nations.
Additionally, the book contains chapters on quality assurance, traceability, and reference materials
among other things.297
       The US environmental testing industry has joined with state regulators to form the National
Environmental Laboratory Accrediting Conference (NELAC). NELAC has published a series of
standards and within the last year has accredited its first group of private laboratories.298
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                                    CONCLUSIONS

       Key points relevant to environmental forensics investigations and the corresponding aspects
are highlighted below.
•      Information systems for the environmental forensic investigator are booming with increasing
       amounts of data being added every day regarding chemicals, fate models, and financial/
       corporate connections. Two substantial encyclopedias, the Kirk-Othmer Encyclopedia of
       Chemical Technology and the Ullmann's Encyclopedia of Industrial Chemistry, provide
       details on engineering fundamentals, plant processes, and industrial chemicals.
•      Many Internet sites within the USEPA provide extensive details about environmental crime
       scene investigations. Information available for investigators in the field include references to
       standards and methods, example documentation and reports, sampling techniques, and guides
       on field measurements. Several other Internet sites include details on laboratory analysis,
       some with downloadable methods available to the user.  The environmental protection
       agencies of many countries provide search engines on their Internet sites for reference
       methods and guidance documents.
•      With the  increasing expansion of  computer  systems  and software, case  agents  for
       environmental criminal investigations face a new challenge. One recommended solution to
       the problem of electronic  evidence in an investigation is to include computer forensic
       analysts as pan of an investigative team, like engineers, geologists, or chemists. An alternate
       approach, to train the agent in  computer forensics, may be time-consuming and may be
       insufficient to stay aware of rapid changes in computer technology.
•      In  the US, laboratory fraud has  become  an  increasing part of environmental  crime
       investigations.  Conditions that can encourage laboratory fraud to occur are the ineffective
       oversight of laboratory data, a shrinking consumer market that  reinforces a focus on
       production over quality, and an approach to analytical requirements that assumes that
       QA/QC can be the same for all analyses. Fraud hotlines and techniques such as double-blind
       proficiency testing, data validation, and electronic record audits are among the suggestions
       for the prevention of laboratory  fraud.
•      Accreditation has now become a key focus of environmental forensic laboratories. Important
       considerations for achieving accredited status include planning sufficient funding to support
       the elements  of  accreditation  (such as proficiency  testing, facility improvement, and
       management information systems) and planning in sufficient time resources to develop
       documentation and support changes in the organizational and functional structure.
•      For environmental forensic organizations that include more than just a laboratory, elements
       other than the lab that are involved in the investigative process should also be considered for
       inclusion in an accreditation standard. Elements such as field sampling, evidence custody
       and preservation, and proper documentation can affect the prosecution  of a criminal case and
       should be included in the quality management provided by properly designed accreditation
       standard.
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                                   REFERENCES

INTRODUCTION

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PLANNING

6.      Bartlett's Familiar Quotations. 16th ed. Boston: Little, Brown and Company, 1992;502.
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GATHERING INFORMATION

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36.    Global Information Network on Chemicals Home Page. http://www.nihs.go.jp/GINC/
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FIELD TECHNIQUES AND EQUIPMENT

5 1 .    USEPA: Technology Innovation Office (TIO) Home Page, http://www.epa.gov/swertiol/
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52.    Hazardous Waste Clean-Up Information (CLU-IN) Home Page, http://clu-in.org/
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55.    CLU-IN, Dynamic Data Collection Strategy Using Systematic Planning and Innovative
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74.    Meuzelaar HLC, Dworzanski JP, Arnold NS, McClennen WH, Wager DJ. Advances in
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SAMPLING

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91.     Source for the "Description and Sampling of Contaminated Soils: Field Pocket Guide."
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ELECTRONIC EVIDENCE

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110.  Sammes AJ, Jenkinson BL. Forensic Computing: A Practitioner's Guide. London:
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METHODS AND METHOD SELECTION

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                                                                                   47

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129.   USEPA Emissions Measurement Center, Test Methods.
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147.   British Standards Online Home Page, http://bsonline.techindex.co.uk/ (accessed June
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INSTRUMENTATION AND TECHNIQUES

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159.   Helmig D. Air Analysis by Gas Chromatography. Journal of Chromatography A
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162.   Harper M. Sorbent Trapping of Volatile Organic Compounds from Air. Journal of
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163.   Cleaver KD. The Analysis of Process Gases: A Review. Accreditation and Quality
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164.   Richardson SD. Water Analysis. Analytical Chemistry 2001;73:2719-2734.
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167.   Hill SJ, Chenery S, Dawson JB, Evans EH, Fisher A, Price WJ, et al. Advances in
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172.   Hill SJ, Dawson JB, Price WJ, Shuttler IL, Smith CMM, Tyson JF. Atomic Spectrometry
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179.   Song L, Xu Z, Kang J, Cheng J. Analysis of Environmental Pollutants by Capillary
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185.  Eiceman GA, Hill HH Jr, Gardea-Torresdey J. Gas Chromatography. Analytical
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190.  Hardas NR, Uden PC. Empirical Formulae Studies of Chlorofluorocarbons using Gas
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203.   Donais MK. How to Interface a Liquid Chromatograph to an Inductively Coupled
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220.   Abrha Y, Raghavan D. Polychlorinated Biphenyl (PCB) recovery from Spiked Organic
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LABORATORY FRAUD

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266.  Martin G. Toxic Sleuth; S. F. Man Nails Labs that Cheat on Superfund Testing Analyses.
      San Francisco Chronicle 2000 December 23; Sect. A:24.

CHEMICAL FINGERPRINTING

267.  Morrison RD. Critical Review of Environmental Forensic Techniques: Part n.
      Environmental Forensics 2000; 1:175-195.
268.  Morrison RD. Forensic Techniques for Establishing the Origin  and Timing of
      Contaminant Release. Environmental Claims Journal 1997 Winter;9(2):105-122.
269.  Morrison RD. Environmental Forensics: Principles & Applications. Boca Raton (FL):
      CRC Press, 2000.
270.  Bruya JE. Chemical Fingerprinting. In: Sullivan PJ, Agardy FJ, Traub RK. Practical
      Environmental Forensics: Process and Case Histories. New York: John Wiley & Sons,
      2001:151-211.
271.  Hurst RW, Davis TE, Chinn BD. The Lead Fingerprints of Gasoline Contamination.
      Environmental Science & Technology 1996;30:304A-307A.
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272.   Farmer JG, Eades LJ, Mackenzie AB, Kirika A, Bailey-Watts TE. Stable Lead Isotope
       Record of Lead Pollution in Loch Lomand Sediments Since 1630 A.D. Environmental
       Science & Technology 1996:30:3080-3083.
273.   Gulson BL, Tiller KG, Mizon KJ, Merry RH. Use of Lead Isotopes in Soils to Identify the
       Source of Lead Contamination Near Adelaide, South Australia. Environmental Science &
       Technology 1981; 15:691-696.
274.   Dunlap CE, Bouse R, Flegal AR. Past Leaded Gasoline Emissions as a Nonpoint Source
       Tracer in Riparian Systems: A Study of River Inputs to San Francisco Bay.
       Environmental Science & Technology 2000;34:1211-1215.
275.   Monna F, Aiuppa A, Varrica D, Dongarra G. Pb Isotope Composition in Lichens and
       Aerosols from Eastern Sicily: Insights into the Regional Impact of Volcanos on the
       Environment. Environmental Science & Technology 1999;33:2517-2523.
276.   Rauch S, Morrison GM, Motelica-Heino M, Donard OFX, Muris M. Elemental
       Association and Fingerprinting of Traffic-Related Metals in Road Sediments.
       Environmental Science & Technology 2000;34:3119-3123.
277.   Linton RW, Natusch DPS, Solomon RL, Evans CA Jr. Physicochemical Characterization
       of Lead in Urban Dust. A Microanalytical Approach to Lead Tracing. Environmental
       Science & Technology 1980; 14:159-164.
278.   Hopke PK. An Introduction to Source Receptor Modeling. In: Landsberger S,
       Creatchman M, editors. Elemental Analysis of Airborne Particles. Amsterdam: Gordon
       and Breach, 1999;273-315.

ACCREDITATION OF ENVIRONMENTAL FORENSIC LABS

279.   Inspector General Expected to Criticize FBI Laboratory. Las Vegas Review-Journal  1997
       April 1; Sect. A:7.
280.   US House of Representatives, Subcommittee on Crime, Committee on the Judiciary. The
       Activities of the Federal Bureau of Investigation (Part I).
       http://commdocs.house.gov/committees/judiciary/ (accessed June 2001), select
       "hju50136.000" for transcript.
281.   US Department of Justice, Office of the Inspector General Special Report. The FBI
       Laboratory One Year Later: A Follow-Up to the Inspector General's April 1997 Report on
       FBI Laboratory Practices and Alleged Misconduct in Explosives-Related and Other
       Cases, http://www.usdoi.gov/oig/fbil 1 yr.htm (accessed June 2001).
282.   Kerr DM. Preserving Accountability in the FBI Laboratory [Letter to the Editor]. The
       Washington Times 1998 August 17; Sect. A; 18.
283.   CBS News, 60 Minutes U, "Under the Microscope."
       http://cbsnews.eom/now/story/0,1597,290046-412.00.shtml (accessed June 2001).
284.   US Department of Justice, Federal Bureau of Investigation (FBI) Press Room. FBI's
       Laboratory Accreditation, http://www.fbi.gov/pressrel/pressrel98/labaccr.htm (accessed
       June 2001).
285.   Enforcement Agency Earns Formal Accreditation. Environmental Laboratory Washington
       Report 2001 March 15;11.
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286.   California State Auditor/Bureau of State Audits, Summary of Report Number 97025.
       http://www.bsa.ca.gov/bsa/summaries/97025sum.html (accessed June 2001).
287.   National Voluntary Laboratory Accreditation Program (NVLAP) Home Page.
       http://ts.nist.gOV/ts/htdocs/210/214/214.htm (accessed June 2001).
288.   NVLAP Accreditation of NEIC Bulk Asbestos Analysis by PLM.
       http://ts.nist.gOv/ts/htdocs/210/214/scopes/l 017030.htm (accessed June 2001)
289.   National Environmental Laboratory Accreditation Program (NELAP) Accrediting
       Authorities. http://www.epa.gov/ttn/nelac/nelaDacc.html (accessed June 2001).
290.   American Association for Laboratory Accreditation (A2LA) Home Page.
       http://www.a21a.org/ (accessed June 2001).
291.   American Society of Crime Laboratory Directors (ASCLD) Home Page.
       http://www.ascld.org/ (accessed June 2001).
292.   National Forensic Science Technology Center (NFSTC) Home Page.
       http://www.nfstc.org/ (accessed June 2001).
293.   Office.com: ASCLD Accreditation Indispensable for Forensic Labs.
       http://www.office.eom/global/0.2724.143-18125,FF.html (accessed June 2001).
294.   Rosecrance A. On Track to Quality  in the Lab: The Role of an Ethics Program and Data
       Quality Review Procedure. Environmental Testing & Analysis 1999
       September/October;8(5):26-37.
295.   Technical Program for 19th Annual National Conference on Managing Environmental
       Quality Systems, EPA Initiatives in  Quality Management: Quality and Environmental
       Information, http://www.epa.gov/qualitv/qs-docs/19qa-papers.pdf (accessed June 2001).
296.   Brilis GM, Worthington JC, Wait AD. Quality Science in the Courtroom: U.S. EPA Data
       Quality and Peer Review Policies and Procedures Compared to the Daubert Factors.
       Environmental Forensics 2000; 1:197-203.
297.   Giinzler H. Accreditation and Quality Assurance in Analytical Chemistry. Berlin:
       Springer-Verlag, 1996.
298.   NELAC Home Page, http://www.epa.gov/ttn/nelac/ (accessed June 2001).
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                                     APPENDIX

TERMINOLOGY AND PUBLICATIONS

       Several lists of environmental and environmental forensics terms and abbreviations exist.
 Details about USEPA publication codes and sources for publications are also available to help
the investigator.
•      Morrison's book Environmental Forensics: A Glossary of Terms has a very long list of
       acronyms and abbreviations as a chapter before the section on environmental forensics
       terms.
       Morrison RD. Environmental Forensics: A Glossary of Terms. Boca Raton (FL): CRC
       Press, 1999.
•      USEPA Terminology Reference System, http://www.epa.gov/eimd/trs/production/
       (accessed June 2001).  The Terminology Reference System is a collection of
       environmental terms used by the USEPA. Terms and the definitions can be found by
       browsing or by performing a keyword search.
•      USEPA National Service Center for Environmental Publications - Understanding "EPA
       Speak." http://www.epa.gov/ncepihom/epaterm.htm (accessed June 2001).
       Understanding "EPA Speak" has a section on "Terms of the Environment" that has a
       browse option for terms and abbreviations and  acronyms.
•      NTIS Web Site Home Page, http://www.ntis.gov/ (accessed June 2001). The US
       Department of Commerce National Technical Information Service is a centralized source
       for scientific, technical and business related government publications.
•      US Government Printing Office, http://www.gpo.gov/ (accessed June 2001). The US
       GPO is another publications source for the United States federal community.
•      USEPA National Service Center for Environmental Publications - NSCEP, USEPA
       Publication Numbering System, http://www.epa.gov/ncepihom/nscep-codes.htm
       (accessed June 2001).  The codes used to refer  to USEPA reports and publications are
       deciphered at the National Service Center for Environmental Publications with the
       USEPA Publication Numbering System. A table to convert code numbers and alpha
       descriptors is provided.
•      Information Sources - USEPA Publications.
       http://www.epa.gov/epahome/publications.htm (accessed June 2001). A list of sources
       for USEPA publications is given at the USEPA Publications Internet site.  It has a link to
       an Internet site with, more information on searching for or purchasing documents.

SUPPLEMENTAL INTERNET SITES

General

•      European Union Policies - Environment, http://europa.eu.int/pol/env/index_en.htm
       (accessed June 2001).  Site contains an index to information from the European Union on
       environmental issues.
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•      Environmental Agencies of the World, http://www.worldbankgroup.org/nipr/epas.htm
       (accessed June 2001).  Lists of the agencies in most countries primarily responsible for
       environmental issues at the national level are available here.
•      NIPR: New Ideas in Pollution Regulation Home Page.
       http://www.worldbankgroup.org/nipr/ (accessed June 2001). Information for researchers,
       government officials, and citizens interested in understanding and improving control of
       industrial pollution, especially in developing countries. The site focuses on materials
       produced by the World Bank's Economics of Industrial Pollution Control Research
       Project.
•      The Regional Environmental Center for Central and Eastern Europe, http://www.rec.org/
       (accessed June 2001). This is a non-advocacy, non-profit organization that assists in
       solving environmental problems in Central and Eastern Europe (CEE).
•      Environment Canada - CEPA Environmental Registry.
       http://www.ec.gc.ca/ceparegistry/default.cfm (accessed June 2001). The CEPA
       Environmental Registry is a comprehensive source of public information relating to
       activities under the Canadian Environmental Protection Act, 1999.
•      Joint Research Centre, http://www.jrc.org/ (accessed June 2001).  Created by the
       European Commission, all eight institutes of the Joint Research Centre (JRC) are listed
       on this site. The Environment Institute (El) conducts research in support of EU policies
       for the protection of the environment and the citizen.
•      The Air Pollution Exchange - News, http://www.uea.ac.uk/~e044/apex/news.html
       (accessed June 2001).  New Directions appears in the international journal Atmospheric
       Environment as an invited or contributed column reporting on all aspects of the
       atmospheric sciences. The articles are written in a popular style, not as scientific papers,
       but are nevertheless authored by experts  in their field. A panel of members from the
       journal's editorial board reviews the articles. The columns are also featured in
       Atmospheric Environment journal.

Legal and Regulatory

•      EHS Internet Library - Foreign Governments. http://www.safetymgmt.com/Foreign.htm
       (accessed June 2001).  Links to foreign government sites and their environmental, health
       and safety regulatory information services.
•      Monash University Law Library - Subject Guides, Environmental Law.
       http://www.lib.monash.edu.au/law/oldsubiect.htm#Environ (accessed June 2001).
       Developed by the Monash University Law Library of Australia, this site includes a variety
       of links pertinent to Environmental law.  It is international in scope.

Gathering Information

•      ATSDR - HazDat Database, http://www.atsdr.cdc.gov/hazdat.html (accessed June 2001).
       HazDat, the Agency for Toxic Substances and Disease Registry's Hazardous Substance
       Release/Health Effects Database, is  the scientific and administrative database developed
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       to provide access to information on the release of hazardous substances from Superfund
       sites or from emergency events and on the effects of hazardous substances on the health
       of human populations.

Methods and Method Selection

•      USEPA Information Sources - Environmental Test Methods and Guidelines.
       http://www.epa.gov/epahome/standards.html (accessed June 2001). Environmental test
       methods and guidelines from the United States Environmental Protection Agency.
•      USEPA New England Library, http://www.epa.gov/region01/oarm/links.html (accessed
       June 2001).  More links to sources of United States Environmental Protection Agency test
       methods on the Internet.
•      SamplePrep Web at Duquesne University, http://www.sampleprep.duq.edu (accessed
       June 2001).  This Internet site on sample preparation was developed by Duquesne
       University of Pittsburgh,  Pennsylvania.  It contains information and advice regarding
       analytical sample preparation, speciated analysis, trace analysis and microwave
       chemistry.

Reference Materials

•      NIST SRM  Catalog - Welcome Page, http://ois.nist.gov/srmcatalog/ (accessed June
       2001).  This Internet site from the United States National Institute of Standards and
       Technology (NIST) provides technical and ordering information for Standard Reference
       Materials (SRMs) and Reference Materials (RMs) that are currently available through the
       NIST Standard Reference Material program.
•      NRC - Certified Reference Materials (CRMs)/Standard Reference Materials (SRMs).
       http://www.ems.nrc.ca/ems 1 .htm (accessed June 2001).  Reference materials from the
       Institute for National Measurement Standards of the National Research Council of
       Canada.
•      Reference Materials - Particle & Surface Sciences.
       http://www.pss.aus.net/products/ref mat.html (accessed June 2001).  Laboratory of the
       Government Chemist (LGC),  is a UK organization which acts as a central supply for
       Certified Reference Materials (CRMs) from  around the world. This site provides an
       Internet-based search for  CRMs.

Computer Forensics

•      United States Department of Defense, Computer Forensics Laboratory.
       http://www.dcfl.gov/ (accessed June 2001).
•      US Department of Justice, Cybercrime, http://www.usdoj.gov/criminal/cybercrime
       (accessed June 2001).
•      Computer Forensics Tool Testing Project Web Site, http://www.cftt.nist.gov/ (accessed
       June 2001).  This project is supported by the US Department of Justice's National
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       Institute of Justice (NIJ), federal, state, and local law enforcement, and the National
       Institute of Standards and Technology (NIST) to promote efficient and effective use of
       computer technology in the investigation of crimes involving computers.
•      Computer High Tech Crime and Related Sites.
       http://members.aol.com/crimeiust/hightech.html (accessed June 2001).
•      Royal Canadian Mounted Police, Computer and Telecommunication Crime.
       http://www.rcmp-grc.gc.ca/html/cpu-cri.htm (accessed June 2001).
•      American Society for Industrial Security (ASIS). http://www.asisonline.com (accessed
       June 2001).
Many companies are now providing computer forensic work. Some work for private
corporations and some are under contract to law enforcement agencies. A few of these
companies are listed below.
•      New Technologies, Inc. http://www.forensics-intl.com (accessed June 2001).
•      Computer Security Institute, http://www.gocsi.com/ (accessed June 2001).
•      Computer Forensics, Ltd. http://www.computer-forensics.com/ (accessed June 2001).
•      Computer Forensics, Inc. http://www.forensics.com (accessed June 2001).
•      Electronic Evidence Discovery, http://www.eedinc.com (accessed June 2001).
•      Ontrack Data International, http://www.ontrack.com (accessed June 2001).
•      Vogon International Data Recovery and Forensic Computing, http://www.vogon.co.uk
       (accessed June 2001).

Accreditation

•      ISO 17025 (Guide 25) Home Page, http://www.microserve.net/~iso25/ (accessed June
       2001). General requirements for the competence of calibration and testing laboratories by
       ISO/ffiC/EN 17025 (formally ISO Guide 25 & EN45001).  Site includes an international
       listing of accreditation bodies and standards organizations with links to their Internet
       sites.
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                                       Table
                  DOWNLOADABLE USEPA METHODS ONLINE
TOPIC
Environmental Analysis
Sample Preparation
Atomic Absorption (AA)
Gas Chromatography (GC)
GC-FTIR
Gas Chromatography-Mass
Spectrometry (GC-MS)
High Performance Liquid
Chromatography (HPLC)
Infrared (BR) Spectrometer
Ion Chromatography (1C)
ICP-AES
ICP-MS
Polarized Light Microscopy (PLM)
X-Ray Fluorescence (XRF)
METHODS OR INFORMATION
Choosing the correct procedure: Ch. 2*
Inorganic analytes: Ch. 3.2*
Organic analytes: Ch. 4.2*
Method 7000A, Table 1 lists detection elements;
7000 Series Methods*
Methods, analytes listed in Ch. 2, Tables 4-19*
515.3, 515.4, 556, and 556.lt
601 to 604, 606 to 6 12$
84 10 and 8430*
Methods and analytes listed in Ch. 2, Tables 20-23;*
Method 526;t 613, 624, 625, 1624, and 1625$
Methods and analytes listed in Ch. 2, Tables 24 - 3 1 ;*
Method 532;t 605 and 610$
8440*
9056 and 9057,* 300.0, 300.1, 314.0 and 317.0t
601 OB, detection elements in Table 1*
6020, detection elements in Table 1 *
EPA/600/M4-82-020§
9075*
*     USEPA: SW-846 Online. http://www.epa.gov/SW-846/main.htm (accessed June 2001).
t     Analytical Methods Developed by the Office of Ground Water and Drinking Water.
      http://www.epa.gov/safewater/methods/sourcalt.html (accessed June 2001).
t     Methods for Organic Chemical Analysis.
      http://www.epa.gov/waterscience/Tools/guide/methods.html (accessed June 2001).
§     2000 CFR Title 40, Volume 27, Chapter I, Part 763, Asbestos.
      http://www.access.gpo.gov/nara/cfr/ (accessed June 2001).
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