U.S. DEPARTMENT OF COMMERCE
                                     National Technical Information Service
                                       PB-245  065
AIR POLLUTION  CONTROL  TECHNOLOGY  AND  COST:
SEVEN  SELECTED  RMISSION SOURCES
Industrial Gas  Cleaning  Institute
Prepared  for:

Environmental Protection Agency

De ce mber  1974

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EPA-450/3-74J060
DECEMBER 1974
    AIR POLLUTION CONTROL
    TECHNOLOGY AND COSTS*
             SEVEN SELECTED
           EMISSION SOURCES
   U.S. ENVIRONMENTAL PROTECTION AGENCY
      Office of Air and Waste Management
   Office of Air Quality Planning and Standards
   Research Triangle Park, North Carolina 27711

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                              TECHNICAL RFPORT DATA
                        (Please read f>;-tfin ti.iiiS on t/i- reverse before compiling)
   EPORT NO.
  EPA-450/3-74J060
                                                   3. RECIPIENT'S ACCESSION>NO.
 4. TITLE AND SUBTITLE
  Air Pdllution  Control Technology  and Costs
  Seven Selected Emission Sources
5. REPORT DATE
 December,  1974  ,
                                                   6. PERFORMING ORGANIZATION CODE
 7. AUTHOR(S)
8. PERFORMING ORGANIZATION REPORT NO


 47.
9. PERFORMING ORGANIZATION NAME AND ADDRESS

  Industrial Gas  Cleaning Institute
  P.O.  Box 1333                -
  Stamford, Connecticut'/O6904 . •
10. PROGRAM ELEMENT NO.
                I
11. CONTRACT/GRANT NO.


 68-02-1091
 12. SPONSORING AGENCY NAME AND ADDRESS
  Environmental Protection Agency
  Office of Air and  Waste Management
  Office of Air Quality Planning and  Standards
                         . No. Carolina  27711
                                                   13. T.YPE OF REPORT AND PERIOD COVERED
                                                    Final
14. SPONSORING AGENCY CODE
 16. ABSTRACT          •

  Under this contract,  the Industrial  Gas Cleaning  Institute collected
  and formalized data  on air pollution abatement for  seven selected
  industrial emission  sources.  These  seven sources were:
         Kraft Paper Mills, Ferroalloy Furnaces, Grain Cleaning
         Houses, Glass  Melting Furnaces,  Crushed Stone and
         Aggregate, Asphalt Saturation,  and Surface Coating
         Operation.
  For each source  area  studied, costs  of  conventionally  applied pollution
  control systems  are  presented for a  range of plant  sizes and control
  efficiencies.

17. .... i WORDS AND DOCUMENT ANALYSIS
a. ' DESCRIPTORS
Air Pollution Performance
Air P6llution Control Equipment
Cost Estimates
Cost Engineering Mechanical Collect
ors
Electrostatic Precipitators
Incinerators
Scrubbers Fahrir Filtnrs
18. DISTRIBUTION STATEMENT
kelciiso Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS
Air Pollution Control
Kraft Processes
Ferroalloy
-Crushed Stone ง Aggre
gate
Glass Furnaces
Grain Cleaning
^i IT fact* Cnatina
19. SECURITY CLASS (ThisTteportf
Unclassified
20. SECURITY CLASS (This page)
Unclassified
XXX9ฎeX'X!X#J&<*$[
- Asphalt
Saturation
21. NO. OF PAGES
EPA Form 2220-1 (9-73)

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                               ฃPA-450/3-74f060

AIR POLLUTION CONTROL TECHNOLOGY
     AND COSTS:  SEVEN SELECTED
           EMISSION SOURCES
   KRAFT MILL RECOVERY  BOILERS,
       FERROALLOY FURNACES,
    FEED AND GRAIN PROCESSING,
 GLASS MELTING FURNACES, CRUSHED
  STONE AND AGGREGATE INDUSTRY,
        ASPHALT SATURATORS,
    INDUSTRIAL SURFACE COATINGS
                    by
            Industrial Gas Cleaning Institute, Inc.
                 P.O. Box 1333
              Stamford, Connecticut 06904
               Contract No. 68-02-1091
             EPA Project Officer: Paul A. Boys
                  Prepared for

           ENVIRONMENTAL PROTECTION AGENCY
            Office of Air and Waste Management
          Office of Air Quality Planning and Standards
            Research Triangle Park, N. C. 27711

                 December 1974

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This report is issued by the Environmental Protection Agency to report technical
data of interest to a limited number of readers.  Copies are available free of
charge to Federal employees, current contractors and grantees,  and nonprofit
organizations-as supplies permit-from the Air Pollution Technical Information
Center, Environmental Protection Agency, Research Triangle Park, North
Carolina 27711; or, for  a fee, from the National Technical Information Service,
5285 Port Royal Road, Springfield, Virginia 22161.
This report was furnished to the Environmental Protection Agency by
Industrial Gas Cleaning Institute, Inc. , Stamford, Connecticut, in fulfillment
of Contract No. 68-02-1091.   The contents of this report are reproduced
herein as received from Industrial Gas Cleaning Institute,  Inc.   The
opinions, findings, and  conclusions expressed are those  of the author and
not necessarily those of the Environmental Protection Agency.  Mention of
company or product names is not to be considered as an endorsement by the
Environmental Protection Agency.
                    Publication No. EPA-450/3-74-060
                                     11

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      Contract Number 68-02-1091
         Air Pollution Control
        Technology And Costs
       In Seven Selected Areas
              including
      Kraft Mill Recovery Boilers
         Ferroalloy Furnaces
      Feed and Grain Processing
       Glass Melting Furnaces
Crushed Stone and Aggregate Industry
         Asphalt Saturators
      Industrial Surface Coatings

             Final Report

        (Completed 15 May, 1975)
                 by
 L. R. Steenberg, Coordinating Engineer
                 for
    Industrial Gas Cleaning Institute
 Box 1333, Stamford,  Connecticut 06904
             Prepared For

  The Environmental Protection Agency
     Durham, North Carolina 27701
           H a

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               INDUSTRIAL GAS CLEANING INSTITUTE, INC.

     Box 1333                              Stamford, Connecticut 06904
                                   MEMBERS
AIR CORRECTION DIVISION
  UNIVERSAL OIL PRODUCTS CO.
AMERICAN AIR FILTER COMPANY, INC.
AMERICAN STANDARD, INC.
BELCO POLLUTION CONTROL CORP.
BUFFALO FORGE COMPANY
THE CARBORUNDUM COMPANY
  POLLUTION CONTROL DIVISION
C E AIR PREHEATER
THE CBLCOTE COMPANY, INC.
CHEMICAL CONSTRUCTION CORP.
  AIR POLLUTION CONTROL COMPANY
THE DUCON COMPANY, INC.
  SUBS. OF U. S. FILTER CORP.
DUSTEX CORPORATION
  SUBS. OF AMERICAN PRECISION
   INDUSTRIES, INC.
ENVIRONEERINQ, INC.
ENVIROTECH-CORPORATION
FISHER-KLOSTERMAN, INC.
FULLER COMPANY, DRACCO PRODUCTS
GALLAGHER-KAISER CORPORATION
INDUSTRIAL CLEAN AIR, INC.
JOHNS MANVILLE
THE KIRK ft BLUM MANUFACTURING CO.
THE KOPPERS COMPANY, INC.
  ENVIRONMENTAL SYSTEMS DIVISION
MATHEY-BISHOP, INC.
MIKROPUL, DIV. OF U. S. FILTER CORP.
PEABODY ENGINEERING CORPORATION
POLLUTION CONTROL-WALTHER, MC.
PRECIPITATION ASSOCIATES OF AMERICA
RESEARCH-COTTRELL, INC.
THE TORIT CORPORATION
WESTERN PRECIPITATION DIVISION
  JOY MANUFACTURING COMPANY
WHEELABRATOR-FRYE, INC.
  AIR POLLUTION CONTROL DIVISION
ZURN AIR SYSTEMS
                         STATEMENT OF PURPOSES

     The Industrial Gas Cleaning Institute, Incorporated In 1960 In the State of New  York,
     was founded to further the Interests of manufacturers of air pollution control equipment, by

     encouraging  the  general Improvement  of  engineering  and technical standards In
     the manufacture, installation, operation, and performance of equipment

     disseminating  Information  on  air pollution;  the effect of industrial gas cleaning on
     public health; and general economic, social, scientific,  technical, and governmental
     matters affecting the  industry, together with the views of the members thereon; and

     promoting the Industry through desirable advertising and publicity.
                            ACKNOWLEDGEMENT

    The efforts of the IGCI Engineering  Standards Committee in the preparation, editing
    and reviewing of this Report are gratefully acknowledged:

                    Harry Krockta, Chairman, The Ducon Company, Inc.
                       G. L Brewer, far Correction Division, UOP
                            C. A. Gallaer, Envirotech Corp.
                       N. D. Phillips, Fuller Co., Dracco Products
                E. J. Malarkey, Whoe/abrator-Frye. Inc., Air Pollution Control Division

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                          TABLE OF CONTENTS


                                                                  Page No.

 I   Introduction  	  1

 II   Technical Data  	  1

     A.   General Description  	  1
          1. Format 	  1
          2. Selection of Applicable Equipment Types  	  2
          3. Basis for Preparing Specifications and Bid Prices  	3
          4. Presentation of Data 	  9

     B.   Process Description and Costs  	 11
          1. Kraft Pulp Mills  	 11
          2. Ferroalloy Furnaces  	 49
          3. Grain Cleaning Houses  	83
          4. Glass Melting Furnaces 	 99
          5. Crushed Stone and Aggregate Industry  	 141
          6. Asphalt Saturation  	 179
          7. Surface Coating Operations	 215

     C.   Additional Cost Data  	 246
          1. Discussion of Cost Basis  	 246
          2. Discussion of Utility  Price Levels  	 248
          3. Derived Capital Cost Indices  	249

     D.   Generalized Cost Data  	 289

III   Appendix

     A.   Specifications for Abatement Equipment  	 305
     B.   Instructions for Submitting Cost Data  	 311

     C.   City Cost Indices  	 315
     D.   Average Hourly Labor Rates by Trade 	 317

     E.   List of Standard Abbreviations 	 319

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                                                 UST OF FIGURES
                                                                                          Page No.
                  Figure 1     Process Flow Diagram — Black Liquor Recovery  	 14
                  Figure 2     Row Diagram of Conventional Recovery Furnace 	 18
                  Figure 3     Relation Between hfeS Production and Furnace Loading 	20
                  Figure 4     Black Liquor Recovery Using Oxidation — Block Flow
                                Diagram  	21
                  Figure 5     Flow Diagram of Air Contact Evaporation System 	 23
                  Figure 6     Flow Diagram of Laminaire Air Heater System 	24
                  Figure 7     Flow Diagram of Large Economizer System  	26
                  Figure 8     Capital Cost of Electrostatic Precipitators for Kraft Pulp Mill
                                Conventional Recovery Furnace (Medium Efficiency) 	35
                  Figure 9     Annual Cost of Electrostatic Precipitators for Kraft Pulp Mill
                                Conventional Recovery Furnace (Medium Efficiency) 	36
                  Figure 10   Capital Cost of Electrostatic Precipitators for Kraft Pulp Mill
                                Conventional Recovery Furnace (High Efficiency)  	 37
                  Figure 11   Annual Cost of Electrostatic Precipitators for Kraft Pulp Mill
                                Conventional Recovery Furnace (High Efficiency)  	38
                  Figure 12   Capital Cost of Electrostatic Precipitators for Kraft Pulp Mill
                                Controlled Odor Recovery Furnace (Medium Efficiency)  	43
                  Figure 13   Annual Cost of Electrostatic Precipitators for Kraft Pulp Mill
                                Controlled Odor Recovery Furnace (Medium Efficiency)  	45
                  Figure 14   Capital Cost of Electrostatic Precipitators for Kraft Pulp Mill
                                Controlled Odor Recovery Furnace (High Efficiency)  	46
                  Figure 15   Annual Cost of Electrostatic Precipitators for Kraft Pulp Mill
                                Controlled Odor Recovery Furnace (High Efficiency)  	47
                  Figure 16   Electric Furnace for Ferroalloy Production  	 51
                  Figure 17   Sealed Furnace for  Producing Ferroalloys  	55
                  Figure 18   Covered Furnace for Producing Ferroalloys  	 56
                  Figure 19   Capital Cost of Fabric Filters for Ferrosilicon Furnaces  	66
                  Figure 20   Annual Cost of Fabric Filters for Ferrosilicon Furnaces  	68
                  Figure 21    Capital Cost of Fabric Filters for Silicon Metal Furnace
                                (Dilution Cooling)   	 72
                  Figure 22   Annual Cost of Fabric Filters for Silicon Metal Furnace
                                (Dilution Cooling)   	74
                  Figure 23   Capital Cost of Fabric Filters for Silicon Metal Furnace
                                (Evaporative Cooling)  	 78
                  Figure 24   Annual Cost of Fabric Filters for Silicon Metal Furnace
                                (Evaporative Cooling)  	80
                  Figure 25   Flow Diagram for Grain Cleaning House  	 85
                  Figure 26   Capital Cost of Fabric Filters for Grain Cleaning House 	95
                  Figure 27   Annual Cost of Fabric Filters for Grain Cleaning House	97
iv

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                           LIST OF FIGURES (cent.)

                                                                      Page No.

Figure 28    Flow Diagram for Soda-Lime Glass Manufacture   	 106
Figure 29    Process Flow Diagram of a Batch Plant   	 107
Figure 30    Log-Probability Distribution of Particle Sizes Present
              in Glass Furnace Effluent   	 112
Figure 31    Natural Gas for Bridgewall-Type Regenerative Furnace   	 117
Figure 32    Capital Cost of Electrostatic Precipitators for
              Glass-Melting Furnace 	 125
Figure 33    Annual Cost of Electrostatic Precipitators for
              Glass-Melting Furnace 	 127
Figure 34    Capital Cost of Wet Scrubbers for Glass-Melting Furnace	131
Figure 35    Annual Cost of Wet Scrubbers for Glass-Melting Furnace	 133
Figure 36    Capital Cost of Fabric Filters for Glass-Melting Furnace   	 137
Figure 37    Annual Cost of Fabric Filters for Glass-Melting Furnace   	 139
Figure 38    Simplified Flow Diagram of a Typical Rock Gravel Plant  	 143
Figure 39    Capital Cost of Wet Scrubbers for Secondary and
              Tertiary Rock Crushers (Medium Efficiency) 	 154
Figure 40    Annual Cost of Wet Scrubbers for Secondary and
              Tertiary Rock Crushers (Medium Efficiency) 	 155
Figure 41    Capital Cost of Wet Scrubbers for Secondary and
              Tertiary Rock Crushers (High Efficiency)	 156
Figure 42    Annual Cost of Wet Scrubbers for Secondary and
              Tertiary Rock Crushers (High Efficiency)  	 157
Figure 43    Capital Cost of Wet Scrubbers for Crushed Stone and
              Aggregate Conveyor Transfer Points (Medium
              Efficiency) 	 162
Figure 44    Annual Cost of Wet Scrubbers for Crushed Stone and
              Aggregate Conveyor Transfer Points (Medium
              Efficiency) 	 163
Figure 45    Capital Cost of Wet Scrubbers for Crushed Stone and
              Aggregate Conveyor Transfer Points (High Efficiency)	 164
Figure 46    Annual Cost of Wet Scrubbers for Crushed Stone and
              Aggregate Conveyor Transfer Points (High Efficiency)  	 165
Figure 47    Capital Cost of Fabric Filters for Secondary and Tertiary
              Rock Crushers  	 169
Figure 48    Annual Cost of Fabric Filters for Secondary and Tertiary
              Rock Crushers  	 171
Figure 49    Capital Cost of Fabric Filters for Crushed Stone  and
              Aggregate Conveyor Transfer Points  	 175

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                                             UST OF RQURES (cent)

                                                                                       Page No.

                  Figure 50   Annual Cost of Fabric Filters for Crushed Stone and
                                Aggregate Conveyor Transfer Points	177
                  Figure 51    Schematic Flow Diagram of Asphalt Saturation Process  	  181
                  Figure 52   Capital Cost of Wet Scrubbers for Asphalt Saturator  	191
                  Figure 53   Annual Cost of Wet Scrubbers for Asphalt Saturator  	  193
                  Rgure 54   Capital Cost of Thermal Incinerators (With Heat Exchange)
                                for Asphalt Saturator (High Efficiency)  	  198
                  Figure 55   Annual Cost of Thermal Incinerators (With Heat Exchange)
                                for Asphalt Saturator (High Efficiency)  	200
                  Figure 56   Capital Cost of High Energy Air Filters for Asphalt
                                Saturator	204
                  Rgure 57   Annual Cost of High Energy Air Rlters for Asphalt
                                Saturator 	206
                  Figure 58   Capital Cost of Thermal Incinerators for Asphalt Blow Still
                                (With Heat Exchange)  	211
                  Figure 59   Annual Cost of Thermal Incinerators for Asphalt Blow Still
                                (With Heat Exchange)  	213
                  Figure 60   Water Wash Spray Booth 	222
                  Figure 61    Down-Draft Water Wash Spray Booth  	223
                  Figure 62   Schematic of Carbon Adsorption and Desorption Units  	229
                  Figure 63   Flow Diagram of Thermal Incineration System  	233
                  Figure 64   Annual Cost for Carbon Adsorption for Surface Coating
                                Operations	235
                  Rgure 65   Annual Cost for Catalytic Incineration (Without Heat
                                Exchange) for Surface Coating Operations  	236
                  Rgure 66    Annual Cost for Catalytic Incinerators (Without Heat
                                Exchange) for Surface Coating Operations  	237
                  Figure 67    Annual Cost for Thermal Incineration (Without Heat
                                Exchange) for Surface Coating Operations	238
                  Figure 68    Annual Cost for Thermal Incineration (With Heat Exchange)
                                for Surface Coating Operations  	239
                  Rgure 69    Annual Cost for Carbon Adsorption for Surface Coating
                                Operations  	240
                  Figure 70    Annual Cost for Catalytic Incineration (Without Heat
                                Exchange) for Surface Coating Operations 	241
                  Figure 71    Annual Cost for Catalytic  Incineration (With  Heat Exchange)
                                for Surface Coating Operations  	242
                  Rgure 72    Annual Cost for Thermal Incineration (Without Heat
                                Exchange) for Surface Coating Operations 	243
                  Rgure 73    Annual Cost for Thermal Incineration (With Heat Exchange)
                                for Surface Coating Operations  	244
vt

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                            LIST OF FIGURES (cont.)

                                                                        Page No.

Figure 74   Capital Cost of Wet Scrubbers Only  	 293
Figure 75   Total Installed Cost of Scrubbing Systems  	294
Figure 76   Direct Operating Cost of Wet Scrubbers  	 295
Figure 77   Capital Costs of Fabric Filters  	296
Figure 78   Installed Costs of Fabric Filters 	 297
Figure 79   Direct Operating Costs of Fabric Filters 	 298
Figure 80   Capital Costs of Thermal Incinerators  	299
Figure 81   Installed Cost of Thermal Incinerators with Heat Exchange  — 300
Figure 82   Direct Operating Cost of Thermal Incinerators
              with Heat Exchange 	 301
Figure 83   Capital Cost of Electrostatic Precipitators  	302
Rgure 84   Installed Cost of Electrostatic Precipitators  	303
Figure 85   Direct Operating Cost of Electrostatic Precipitators 	304
                                                                                           vii

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                                                   LIST OF TABLES
                                                                                           Page No.
                   Table 1     Abatement Equipment Types Selected for the Seven
                                 Process Areas 	4
                   Table 2     Process Weight Table for Medium Efficiency for Paniculate
                                 Collection Cases Only 	 6
                   Table 3     Collection Efficiencies Selected for the Seven Process Areas  — 7
                   Table 4     Odorous Chemicals Emitted from Kraft Pulp Mills  	 17
                   Table 5     Electrostatic Precipitator Process Description for Conventional
                                 Kraft Pulp Mill Recovery Furnace Specification  	30
                   Table 6     Electrostatic Precipitator Operating Conditions for
                                 Conventional Kraft Pulp Mill Recovery Furnace
                                 Specification 	32
                   Table. 7     Estimated Capital Cost Data (Cost in Dollars) for Electrostatic
                                 Precipitators for Kraft  Pulp Mill Conventional Recovery
                                 Furnace 	 33
                   Table 8     Annual Operating Cost Data (Cost in $/Year) for Electrostatic
                                 Precipitators for Kraft  Pulp Mill Conventional Recovery
                                 Furnace 	 34
                   Table 9     Electrostatic Precipitator Process Description for Kraft Pulp
                                 Mill Controlled Odor Recovery Furnace Specification  	39
                   Table 10    Electrostatic Precipitator Operating Conditions for Kraft Pulp
                                 Mill Controlled Odor Recovery Furnace Specification  	41
                   Table 11    Estimated Capital Cost Data (Cost in Dollars) for Electrostatic
                                 Precipitators for Kraft  Pulp Mill Controlled Odor Recovery
                                 Furnace 	42
                   Table 12    Annual Operating Cost Data (Cost in $/Year) for Electrostatic
                                 Precipitators for Kraft  Pulp Mill Controlled Odor Recovery
                                 Furnace 	 43
                   Table 13    Compositions of Typical Ferroalloys  	 50
                   Table 14    Basic Overall Reactions for Ferroalloy Production  	 53
                   Table 15    Distribution of  Domestic  Ferroalloy Furnaces 	 54
                   Table 16    Weight Balance for Production of 45% Ferrosilicon  	 58
                   Table 17    Comparison of Gas Flows from Open and Closed Hood 50 MW
                                 Submerged Arc Furnaces Making 50% Ferrosilicon  	59
                   Table 18    Properties of Paniculate Emissions from  Ferroalloy Furnaces  ... 60
                   Table 19    Fabric Filter Process Description for Ferrosilicon Furnace
                                 Specification 	 63
                   Table 20    Fabric Filter Operating Conditions for Ferrosilicon Furnace
                                 Specification 	64
viii

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                            LIST OF TABLES (cont.)


                                                                       Page No.

Table 21     Estimated Capital Cost Data (Cost in Dollars) for Fabric Filters
              for Ferrosilicon Furnace  	 65
Table 22     Annual Operating Cost Data (Cost in $/Year) for Fabric Filters
              for Ferrosilicon Furnace  	 67
Table 23     Fabric Filter Process Description for Silicon Metal Furnace
              Specification 	 69
Table 24     Fabric Filter Operating Conditions for Silicon Metal  Furnace
              Specification 	 70
Table 25     Estimated Capital Cost Data (Cost in Dollars) for Fabric Filters
              for Silicon Metal Furnace (Dilution Cooling)  	 71
Table 26     Annual Operating Cost Data (Cost in $/Year) for Fabric Filters
              for Silicon Metal Furnace (Dilution Cooling)  	 73
Table 27     Fabric Filter Process Description for Silicon Metal Furnace
              Specification 	75
Table 28     Fabric Filter Operating Conditions for Silicon Metal  Furnace
              Specification	 76
Table 29     Estimated Capital Cost Data (Cost in Dollars) for Fabric Filters
              for Silicon Metal Furnace (Evaporative Cooling)  	 77
Table 30     Annual Operating Cost Data (Cost in $/Year) for Fabric Filters
              for Silicon Metal Furnace (Evaporative Cooling)  	 79
Table 31     Annual Grain Production Statistics  	84
Table 32     Contaminants Generated During Grain Cleaning 	88
Table 33     Properties of Dust Emitted from Grain Cleaning Operations  	89
Table 34     Relative Advantages and Disadvantages of Cyclones
              and Fabric Filters   	 90
Table 35     Fabric Filter Process Description for Grain Cleaning House
              Specification 	92
Table 36     Fabric Filter Operating Conditions for Grain Cleaning  House
              Specification 	 93
Table 37     Estimated Capital Cost Data (Cost in Dollars) for Fabric Filters
              for Grain Cleaning House  	94
Table 38     Annual Operating Cost Data (Cost in $/Year) for Fabric Filters
              for Grain Cleaning House  	96
Table 39     Approximate Compositions of Commercial Glasses  	  100
Table 40     Useful Range of Glass Viscosities   	  103
                                                                                           ix

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                            LIST OF TABLES (cent)
                                                                      Page No.

Table 41     Glassmaking Materials	  104
Table 42     Estimated National Emissions, 1971, Glass Furnaces  	  109
Table 43     Source Test Data for Glass-Melting Furnaces  	  110
Table 44     Size Distribution of Paniculate Emissions (Micromerograph
              Analyses)  	  111
Table 45     Flue Conditions from the Manufacture of Glass 	  113
Table 46     Emissions from the Manufacture of Glass  	  114
Table 47     Chemical Composition of Paniculate Emissions
              (Quantitative Analyses)  	  115
Table 48     Chemical Composition of Gaseous Emissions from Gas
              Fired Regenerative  Furnaces 	  118
Table 49     Electrostatic Precipitator Process Description for
              Glass-Melting Furnace Specification  ...	  122
Table 50     Electrostatic Precipitator Operating Conditions for
              Glass-Melting Furnace Specification  —	  123
Table 51     Estimated Capital Cost Data (Cost in Dollars) for Electrostatic
              Predpitators for Glass-Melting Furnace  	  124
Table 52     Annual Operating Cost Data (Cost in Dollars) for Electrostatic
              Predpitators for Glass-Melting Furnace  	  126
Table 53     Wet Scrubber Process Description for Glass-Melting
              Furnace Specification  	  128
Table 54     Wet Scrubber Operating Conditions for Glass-Melting
              Furnace Specification	  129
Table 55     Estimated Capital Cost (Cost in Dollars) for Wet Scrubbers
              for Glass-Melting Furnace	  130
Table 56     Annual Operating Cost Data (Cost in Dollars) for Wet
              Scrubbers for Glass-Melting Furnace  	  132
Table 57     Fabric Filter Process Description for Glass-Melting Furnace
              Specification  	.;;	  134
Table 58     Fabric Filter Operating Conditions for Glass-Melting
              Furnace Specification	  135
Table 59     Estimated Capital Cost Data (Cost in Dollars) for Fabric
              Filters for Glass-Melting Furnace	  136
Table 60    Annual Operating Cost Data (Cost in Dollars) for Fabric
              Filters for Glass-Melting Furnace  .. —	  138
Table 61     Rock and Mineral Production Unit Operations  	  146

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                            LIST OF TABLES (cont.)


                                                                      Page No.

Table 62    Wet Scrubber Process Description for Secondary and
              Tertiary Rock Crusher Specification  	 150
Table 63    Wet Scrubber Operating Conditions for Secondary and
              Tertiary Rock Crusher Specification  	 151
Table 64    Estimated Capital Cost Data (Cost in Dollars) for Wet
              Scrubbers for Secondary and Tertiary Rock Crushers  	 152
Table 65    Annual Operating Cost Data (Cost in Dollars) for Wet
              Scrubbers for Secondary and Tertiary Rock Crushers  	 153
Table 66    Wet Scrubber Process Description for Crushed Stone and
              Aggregate Conveyor Transfer Points Specification  	 158
Table 67    Wet Scrubber Operating Conditions for Crushed Stone and
              Aggregate Conveyor Transfer Points Specification  	 159
Table 68    Estimated Capital Cost Data (Cost in Dollars) for Wet
              Scrubbers for Crushed Stone and Aggregate Conveyor
              Transfer Points  	 160
Table 69    Annual Operating Cost Data (Cost in Dollars) for Wet
              Scrubbers for Crushed Stone and Aggregate Conveyor
              Transfer Points  	 161
Table 70    Fabric Filter Process Description for Secondary and
              Tertiary Rock Crusher Specification  	 166
Table 71    Fabric Filter Operating Conditions for Secondary and
              Tertiary Rock Crusher Specification  	 167
Table 72    Estimated Capital Cost Data (Cost in Dollars) for Fabric
              Filters for Secondary and Tertiary Rock Crushers 	 168
Table 73    Annual Operating Cost Data (Cost in Dollars) for Fabric
              Filters for Secondary and Tertiary Rock Crushers 	 170
Table 74    Fabric Filter Process Description for Crushed Stone and
              Aggregate Conveyor Transfer Points Specification  	 172
Table 75    Fabric Filter Operating Conditions for Crushed Stone and
              Aggregate Conveyor Transfer Points Specification  	 173
Table 76    Estimated Capital Cost Data (Cost in Dollars) for Fabric
              Filters for Crushed Stone and Aggregate Conveyor
              Transfer Points  	 174
Table 77    Annual Operating Cost Data (Cost in Dollars) for Fabric Filters
              for Crushed Stone and Aggregate Conveyor Transfer
              Points   	 176
Table 78    Number of Establishments and Value of Shipments of
              Asphalt Saturated Products  	 180
                                                                                         xi

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                                              LIST OF TABLES (cont.)


                                                                                        Page No.

                  Table 79    Wet Scrubber Process Description for Asphalt Saturator
                                Specification   	  188
                  Table 80    Wet Scrubber Operating Conditions for Asphalt Saturator
                                Specification   	  189
                  Table 81    Estimated Capital Cost Data (Cost in Dollars) for Wet
                                Scrubbers for Asphalt Saturator  	  190
                  Table 82    Annual Operating Cost Data (Cost in Dollars) for Wet
                                Scrubbers for Asphalt Saturator  	  192
                  Table 83    Thermal Incinerator (With Heat Exchange) Process
                                Description for Asphalt Saturator Specification  	  194
                  Table 84    Thermal Incinerator (With Heat Exchange) Operating
                                Conditions for Asphalt Saturator Specification  	  196
                  Table 85    Estimated Capital Cost Data (Cost in Dollars) for Thermal
                                Incinerators (With Heat Exchange) for Asphalt Saturator  	  197
                  Table 86    Annual Operating Cost Data (Cost in Dollars) for Thermal
                                Incinerators (With Heat Exchange) for Asphalt Saturator  	  199
                  Table 87    High Energy Air Filter Process Description for Asphalt
                                Saturator Specification 	201
                  Table 88    High Energy Air Filter Operating Conditions for Asphalt
                                Saturator Specification 	  202
                  Table 89    Estimated Capital Cost Data (Cost in Dollars) for H.E.A.F.
                                for Asphalt Saturator  	  203
                  Table 90    Annual Operating Cost Data (Cost in Dollars) for H.E.A.F.
                                for Asphalt Saturator  	  205
                  Table 91    Thermal Incinerator Process Description for Asphalt Blow
                                Still Specification (With Heat Exchange)   	207
                  Table 92    Thermal Incinerator (With Heat Exchange)  Operating
                                Conditions for Asphalt Blow Still Specification   	209
                  Table 93    Estimated Capital Cost Data (Cost in Dollars) for Thermal
                                Incinerators (With Heat Exchange) for Asphalt Blow Still  	210
                  Table 94    Annual Operating Cost Data (Cost in Dollars) for Thermal
                                Incinerators (With Heat Exchange) for Asphalt Blow Still  	212
                  Table 95    Examples of Surface-Coating Formulas on an As-Purchased
                                Basis	217
                  Table 96    Threshold Limit Values of Typical Paint Solvents  	219
                  Table 97    Substitution of Exempt Solvent   	 227
                  Table 98    Sizes for Solvent Recovery Systems Using Activated
                                Carbon  	 231
xii

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                           LIST OF TABLES (cont.)
                                                                    Page No.

Table 99    Units of Plant Size for Each Process Area 	 252
Table 100   Derived Cost Indices for Kraft Mill Recovery Furnaces  	 255
Table 101   Derived Cost Indices for Kraft Mill Controlled Odor Furnaces ... 256
Table 102   Derived Cost Indices for Ferrosilicon Furnace 	257
Table 103   Derived Cost Indices for Silicon Metal Furnace
              (Dilution Cooling)   	 258
Table 104   Derived Cost Indices for Silicon Metal Furnace
              (Evaporative Cooling)  	 259
Table 105   Derived Cost Indices for Grain Cleaning House 	 260
Table 106   Derived Cost Indices for Glass-Melting Furnace
              (Electrostatic Precipitation) 	 261
Table 107   Derived Cost Indices for Glass-Melting Furnace
              (Wet Scrubbing)  	 262
Table 108   Derived Cost Indices for Glass-Melting Furnace
              (Fabric Filtration)	 263
Table 109   Derived Cost Indices for Secondary and Tertiary Rock Crusher
              (Wet Scrubbing)  	 264
Table 110   Derived Cost Indices for Crushed Stone and  Aggregate
              Conveyor Transfer Points (Wet Scrubbing)  	 265
Table 111   Derived Cost Indices for Secondary and Tertiary Rock
              Crusher (Fabric Filtration) 	 266
Table 112   Derived Cost Indices for Crushed Stone and  Aggregate
              Conveyor Transfer Points (Fabric Filtration) 	 267
Table 113   Derived Cost Indices for Asphalt Saturator (Wet Scrubbing) — 268
Table 114   Derived Cost Indices for Asphalt Saturator
              (Thermal Incineration) 	 269
Table 115   Derived Cost Indices for Asphalt Saturator (Glass Fiber
              Mat Filtration)   	 270
Table 116   Derived Cost Indices for Asphalt Blow Still 	 271
Table 117   Derived Cost per SCFM for Kraft Mill Recovery Furnaces 	273
Table 118   Derived Cost per SCFM for Kraft Mill Controlled
              Odor Furnaces  	 274
Table 119   Derived Cost per SCFM for Ferrosilicon Furnaces  	 275
Table 120   Derived Cost per SCFM for Silicon Metal  Furnaces  	 276
Table 121   Derived Cost per SCFM for Grain Cleaning Houses 	 277
Table 122   Derived Cost per SCFM for Glass-Melting Furnaces
              (Electrostatic Precipitation) 	 278
                                                                                        XIII

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                                           UST OF TABLES (cent.)


                                                                                   Page No.

                 Table 123   Derived Cost per SCFM for Glass-Melting Furnaces
                               (Wet Scrubbing)   	279
                 Table 124   Derived Cost per SCFM for Glass-Melting Furnaces
                               (Fabric Filtration)  	280
                 Table 125   Derived Cost per SCFM for Secondary and Tertiary Rock
                               Crusher (Wet Scrubbing)  	281
                 Table 126   Derived Cost per SCFM for Crushed Stone and Aggregate
                               Conveyor Transfer Points (Wet Scrubbing) 	282
                 Table 127   Derived Cost per SCFM for Secondary and Tertiary Rock
                               Crusher (Fabric Filtration)  	 283
                 Table 128   Derived Cost per SCFM for Crushed Stone and Aggregate
                               Conveyor Transfer Points (Fabric Filtration) 	:	284
                 Table 129   Derived Cost per SCFM for Asphalt Saturator
                               (Wet Scrubbing)   	285
                 Table 130   Derived Cost per SCFM for Asphalt Saturator
                               (Thermal Incineration)  	286
                 Table 131   Derived Cost per SCFM for Asphalt Saturator (Glass Fiber
                               Mat Filtration)  	 287
                 Table 132   Derived Cost per SCFM for Asphalt Blow Still 	 288
                 Table 133   Plotting Symbol Key 	 290
xiv

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                          LIST OF APPENDICES
Appendix A    Specifications for Abatement Equipment
Appendix B    Instructions for Submitting Cost Data
Appendix C    City Cost Indices
Appendix 0    Average Hourly Labor Rates by Trade
Appendix E    List of Standard Abbreviations
                                                                                     xv

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I.    INTRODUCTION

     The Industrial Gas Cleaning Institute (IGCI) is an association of manufacturers
     of gas cleaning equipment, used primarily for the abatement of air pollution.
     Under this contract, the IGCI is collecting and formalizing data on air pollution
     control in seven industrial areas selected by the EPA. These areas are:

          1. Kraft Mill Recovery Boilers
          2. Ferroalloy Furnaces                       Phase I
          3. Feed and Grain Cleaning Houses
          4. Glass-Melting Furnaces            _
          5. Crushed Stone and Aggregate Plants"
          6. Asphalt Saturation  Plants
          7. Industrial Surface Coating Operations^,

     This  final report contains all of the technical information assembled for both
     the three process areas of Phase I and the four process areas of Phase II.
     The  technical  material  consists of a narrative description of each  of  the
     process  areas tabulated above, specifications for  air pollution  abatement
     equipment for each, and  a summary of  capital and operating costs  for
     equipment obtained from the  IGCI  member companies in response  to  the
     specifications.  The  following section  summarizes all  of the technical data
     assembled.
II.    TECHNICAL DATA

     This  section contains  all  of the data collected as  a part of this program.
     This  includes  information on  process  descriptions, air pollution  control
     requirements, specifications, and capital and operating costs for abatement
     equipment used in these industries. Narrative material was generated by the
     combined  efforts of Air Resources, Inc.  personnel acting  as  editors  and
     coordinators for the  program, and  the most qualified personnel of the IGCI
     member companies  active in each field. The cost data, however, is  entirely
     the product of companies  judged most qualified. In addition to IGCI member
     companies, some non-members participated by supplying cost information.
     These companies prepared cost estimates independently of one another. Air
     Resources, Inc. consolidated the data and edited it with regard to format only.
                       A.  GENERAL DESCRIPTION

     1.   Format

         This study includes seven industrial areas, divided into two groups, each of

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     which were covered by  a separate earlier phase report. In this  final
     report, the two phases are combined and summarized.

     There are  seven  sections in this  report,  each  covering one of the
     industrial areas. For each area, the following format is used:

          1.    Description of the Process
               a.  Manufacturing or Production Aspects
               b.  Air Pollution Control Equipment
          2.    Specifications and Costs
               a.  Electrostatic Precipitators
                  (1) Specifications
                  (2) Capital  Costs
                  (3) Operating Costs
               b.  Wet Scrubbers
               c.  Fabric Filters
               d.  Others
          3.    Summary Comments

     This material will not be  presented in outline form, nor will  each item
     necessarily be included for each process area.

2.    Selection of Applicable Equipment Types

     Emissions from the industries studied under this  contract fall into two
     broad classes: paniculate matter,  and hydrocarbons. Five of the seven
     study areas, including all of those in Phase I, are concerned primarily
     with emissions of particulate matter. These five include:

       Kraft Mill Recovery Boilers (Conventional and Controlled Odor Types)
       Ferroalloy Furnaces
       Feed and Grain Cleaning Houses
       Glass Melting Furnaces
       Crushed Stone and Aggregate Rants
     Odor problems in  kraft mills  are  normally dealt with through process
     modification. One common modification for odor control is the "controlled
     odor" type of recovery boiler.  While the  kraft mill  recovery boiler study
     investigates control of particulate emissions from both  kinds  of boilers,
     the study does not cover odor abatement techniques or performances,
     per se. It includes the controlled odor type boiler only because it represents
     a common  boiler type,  currently in  use,  requiring particulate emission
     control.

     The other two study areas are concerned primarily with hydrocarbon

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     emissions:

          Asphalt Saturation Plants
          Industrial Surface Coating Operations

     All of the conventional pollution  abatement devices will be included in
     this seven industry study, as indicated below:

          Control of Paniculate Matter        Control of Hydrocarbons

          Electrostatic Precipitators           Incinerators
          Fabric Filters                      Adsorption Units
          Wet Scrubbers                    Absorption Units

     In general, a given process is amenable to control by more than one
     type of device. The Engineering  Standards Committee of the IGCI has
     been responsible for selecting the types which will be considered in this
     program. In many areas, the EPA is conducting simultaneous programs
     in which industrial  surveys, source testing, and other programs may
     furnish additional insight into the  equipment types predominating in well-
     controlled installations. This information was incorporated into the judg-
     ments  reached  by  the Engineering Standards  Committee through a
     series of technical exchange meetings with the EPA.

     Selections of equipment types to be studied were made during several
     Engineering Standards  Committee meetings  and technical exchange
     meetings. Present  at all  of the  technical  exchange meetings  were
     representatives of the following groups:

               EPA        Economics Analysis Branch
               EPA        Industry Studies Branch
               IGCI        Technical Director
               IGCI        Engineering Standards Committee
               ARI         Project Coordinator

     The end results of this selection process are presented in Table 1.

3.    Basis for Preparing Specifications and Bid Prices

     The degree of reduction of emissions required in  a given application will
     influence  the  cost  significantly  for wet  scrubbers and  electrostatic
     precipitators. The costs of fabric  filters, mechanical collectors,  and
     incinerators are, on the other hand, relatively insensitive to the efficiency
     level specified.  In all  cases, the cost  is directly  related to size or gas
     handling capacity required.

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                                 TABLE 1

               ABATEMENT EQUIPMENT TYPES SELECTED
                    FOR THE SEVEN PROCESS AREAS
Process Area

Kraft Mill
  Recovery Boilers

Ferroalloy Furnaces

Feed and Grain
  Processing

Glass-Melting Furnace
Crushed Stone and
  Aggregate Plant
Emission Source

Conventional Boiler
Controlled Odor Boiler

Open Furnace

Cleaning House
Soda-Lime Glass-Melting
  Furnace
Equipment Type

Electrostatic Precipitator
Electrostatic Precipitator

Fabric Fitter

Fabric Filter
Electrostatic Precipitator
Wet Scrubber
Fabric Filter
Secondary and Tertiary   Wet Scrubber
  Rock Crushers         Fabric Filter

Conveyor Transfer Points  Wet Scrubber
                        Fabric Filter
Asphalt Saturation Plant   Asphalt Saturator
Industrial Surface
  Coating Operations
                        Asphalt Blow Still
                        Wet Scrubber (absorber)
                        Thermal Incinerator
                        High Energy Air Fitter
                        Thermal Incinerator
Spray Coating Chambers  Carbon Adsorption
                        Thermal Incinerator
                        Catalytic Incinerator

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In order to make a meaningful comparison of capital and operating costs,
it is necessary to specify the performance level, or degree of reduction
of emissions required. Two levels of performance were specified for most
types of equipment so that costs could be related  to  the  degree of
emission reduction as well as to gas handling capacity. The two perform-
ance  levels are called  "medium efficiency" and "high efficiency."  For
each  of the  seven  process areas, numerical  collection efficiencies
were specified for each performance level during the technical exchange
meetings  with  EPA. In  those cases where fabric filters were applied,
only one performance level was specified, the "high efficiency" level.

The efficiencies were chosen on the basis of the following criteria:

     High Efficiency   — A sufficiently low grain loading  to expect  a
                         clear stack.

     Medium Efficiency — The process weight table  published  in  the
                         Federal  Register  April 7,  1971,   or other
                         process  operating  emission  factors  re-
                         lated  to the  specific industry under study.

The process weight table used is presented in Table 2. Table 3 lists the
collection efficiencies specified for each case.

Several simplifications were made in the preparation of the specifications
which have some bearing on the results which are reported here. These
should be kept in mind when using the prices, operating costs, etc. The
form of the specification for equipment may have an influence over the
price quoted.  Overly-restrictive specifications may add 5% to 10% to
the equipment price, without a corresponding increase in value received
by the purchaser.  In each of the cases presented in this report, prices
are based on a specification which covers most of  the conditions of
purchase  in  an equitable  way.  Instead of writing each specification
independently,  the participants  agreed  upon the general terms and
conditions to be specified, and these conditions were made identical for
each specification.  The final specification in each case was made by
inserting one section of descriptive material and one section of operating
conditions pertaining to the specific application into the standard format.
To avoid unnecessary repetition, a sample of the complete specification
for one of the applications is included  as  Appendix A to this  report.
Only the pages pertinent to specific applications are contained in the
body of the report.

Prices were requested in such a way as to indicate three bases:

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                      TABLE 2

  PROCESS WEIGHT TABLE FOR MEDIUM EFFICIENCY
FOR PARTICULATE MATTER COLLECTION CASES ONLY*

   Process Weight                           Rate of
   Rate (Ib/hr)                        Emission (Ib/hr)

     100  	 0.551
     200  	 0.877
     400  	 1.40
     600  	 1.85
     800	 2.22
    1,000  	 2.58
    1,500  	 3.38
    2,000  	 4.10
    2.500  	 4.76
    3,000  	 5.38
    3,500	 5.96
    4,000	 6.52
    5,000	 7.58
    6,000	 8.56
    7,000  	 9.49
    8,000  	10.44
    9,000  	..11.2
   12,000  	13.6
   16,000  	16.5
   18,000  	17.9
   20,000  ...:	19.2
   30,000  	25.2
   40,000  	30.5
   50,000  	35.4
   60,000 or more 	40.0
  •Federal Register April 7, 1971

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                                                TABLE 3
                   COLLECTION EFRCIENCIES SELECTED FOR SEVEN PROCESS AREAS
Emission Source

Kraft Mill
  Recovery Boilers
Emission Type
Paniculate Matter
Equipment Type
Medium Efficiency   High Efficiency
Ferroalloy Furnaces     Particulate Matter

Feed & Grain          Particulate Matter
  Processing

Glass-Melting Furnace  Particulate Matter
Crushed Stone and
Aggregate Industry
  Secondary and Ter-   Particulate Matter
  tiary Rock Crushers
  Conveyor Transfer
  Points

Asphalt Saturator
Asphalt Blow Still
Particulate Matter
Hydrocarbons
Hydrocarbons
(1) Only one efficiency specified
(2) Process Weight Table
(3) ADT = Air dried ton of pulp
Electrostatic Precipitator
Fabric Fitter
Fabric Fitter
Electrostatic Precipitator
Wet Scrubber
Fabric Filter
Wet Scrubber
Fabric Filter
Wet Scrubber
Fabric Filter
Wet Scrubber (absorber)
Thermal Incinerator
High Energy Air Filter
1.7lb/ADT(3)
(0.035 gr/DSCF)
(D
(1)
(1)
(1)
(D
(2)
(D
0.04 gr/ACF
(D
(D
98%
(1)
0.02 gr/DSCF
(1.0lb/ADT)
0.01 gr/ACF
0.01 gr/ACF
0.01 gr/ACF
0.01 gr/ACF
0.01 gr/ACF
0.01 gr/ACF
0.01 gr/ACF
0.01 gr/ACF
0.01 gr/ACF
8 Ib/hr
99%
98%
Thermal Incinerator
    (1)
99%

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      1.    Air pollution control device. This includes only the flange-to-
           flange precipitator, fabric filter, scrubber, etc.
      2.    Air pollution control auxiliary equipment. This includes major
           items such as fans, pumps, etc.
      3.    Complete turnkey installation.  This includes the  design, all
           labor  and  materials,  equipment  fabrication,  erection,  and
           startup.

 In order to maintain a consistent approach to quoting in each area, the
 specifications were written around the air pollution control device. The
 process description was, however, made general enough to allow the
 bidders to quote on the auxiliary equipment, such as fans, pumps, solids
 handling devices, etc., and to quote on an approximate installation cost.
 A complete set of instructions for quoting is given in Appendix B.

 Labor costs vary from one location to another, and it was not possible
 to establish the complex pattern of variations in turnkey prices which
 occur as a function of local variations in hourly rates, productivity, and
 availability of construction tradesmen. In  order to provide a consistent
 basis for the  preparation of price quotations, the cost indices given in
 Appendix C were used. These figures do not take productivity differences
 into account and may understate the variations in cost from one  city
 to another.

 The participating companies were instructed  to estimate the  installation
 costs  as though erection or installation  of the system would  be in
 Milwaukee, Wisconsin or another  city  relatively  convenient  to  the
 participant's point of shipment with a labor index near 100. Readers are
 cautioned to take local labor rates and productivity into account when
 making first  estimates of air pollution control system installed costs
 based on the data in this report. Appendix D shows the  tabulated
 hourly rates for various construction trades (based on national averages)
 which may be useful for this purpose.

 Considerable emphasis was placed on the estimation of operating costs.
 Manufacturers submitting costs for equipment were asked to estimate
 the operating costs  in terms of utility requirements, maintenance and
 repair labor,  and operating labor. These were  requested in terms of
 quantity required, rather than cost. This was done because the operating
 costs will be analyzed in terms of standard utility and labor rates.

Air pollution control  costs for the Industrial  Surface Coatings section
of this report  were  not obtained  in the same fashion as  costs for the

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     other  three study areas. Equipment specifications were  not prepared
     nor were specific bids solicited. Instead, the three firms selected as
     "most  expert  reviewers" reviewed generalized  economics  for  the
     common types of abatement systems used for control in this industry.
     These generalized economics are presented as part of the  narrative
     portion of the report.

4.    Presentation of Data

     Estimates of both capital  cost and annual operating cost are presented
     for each type of abatement equipment  applied to each  of the seven
     industries covered under  the program. In general, the capital cost data
     are presented  in one table,  which shows the averaged details of  the
     bids submitted for each  application, followed by a graph. The graph
     shows the capital cost for the abatement device, the total equipment
     cost, and the turnkey system cost correlated with plant size.

     Operating costs are  also presented in similar fashion. A table shows
     averaged annual  estimates  of  labor, maintenance, and utilities, and
     an estimate of the annualized capital charge, computed as a percentage
     of  total system capital cost.  Graphs  present direct  annual cost and
     total annual cost correlated with plant size.

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B.   PROCESS DESCRIPTION AND COSTS

1.   KRAFT PULP MILLS

     Paper has evolved from early man's use of bark, ivory, papyrus, and parchment
in an effort to  record activities and events. In the early nineteenth century, paper
production methods employed rags as the primary raw material. Improving levels
of communication created a rapidly increasing demand for paper leading to increased
production and a  subsequent scarcity of  rags. Inventors, however, responded to
this scarcity by developing  production methods which  utilized wood. The second
half of the nineteenth century saw development of first mechanical, and then chemical
methods for pulping wood.

     Since the turn of the century, wood has  become the most important source of
fiber for paper  pulps. Sulfate, or kraft, pulping is one of two main chemical processes
used to convert wood to papermaking fibers. Sulfite pulping, similar in many process
details to the kraft method,  also employs  chemical means but produces pulp with
lower physical  strength and opacity. Other processes in use are mechanical pulping,
where logs are reduced to fiber by physical grinding,  and "chemi-mechanical"
pulping which  combines both chemical and mechanical methods of  defibration.
The  soda process, which is  similar in many respects to the sulfite  and sulfate
process accounts for only a small percentage of the pulp produced.

     The kraft process,  introduced to the United States in  1908, is aptly named
because kraft is the German word for strong and the  kraft product is characterized
by superior physical strength.  In 1966, more than 63%  of the total U.S. production
of pulp was made by the kraft process. The  majority of new chemical  pulp manu-
facturing facilities  built since then, or currently in the design stage, also use the
kraft process.
                      KRAFT PROCESS DESCRIPTION

     In  kraft or sulfate pulping, separation of fibers is accomplished by chemical
treatment to dissolve the lignin which bonds wood fibers together. The chemical
reactions responsible for this  defibration involve hydrolysis of lignins in the wood
to alcohols and acids. This hydrolysis also produces mercaptans and sulfides which
are responsible for the familiar odor around sulfate-pulp mills. This reaction takes
place in the digesters. The chemicals used  in kraft milling are too expensive to
discard. Consequently, much of the pulping  process  is devoted to recovery  and
reuse of these chemicals.

     It is possible to produce relatively pure cellulose fiber by the kraft process,
since almost fifty  percent of the log is extracted. Papers from this pulp have high
                         Preceding page blank

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                 physical strength, bulk, and opacity; low unbleached brightness; and relatively poor
                 sheet formation properties. Both bleached and unbleached sulfate pulps are used
                 as packaging papers, container board, and a variety of printing and bond papers.
                 The kraft process consists of the following steps.

                      1.    Logs are debarked. The bark is often used as a fuel in the bark power
                           boiler along with either coal, gas, or oil. Bark power boilers, as an emission
                           source,  have been studied  in  depth  under a separate EPA contract,
                           No. 68-02-0301, entitled "Air Pollution Control Technology and Costs in
                           Nine Selected Areas". In some areas the bark is prepared for a garden
                           mulch. However, with the increasing cost of other fuels, it must be con-
                           sidered as a potential source of energy.

                      2.    The  debarked logs  are conveyed to chippers  which are large rotating
                           discs holding four or more long heavy knives. The chipper reduces the
                           wood to small chips. The chips are screened for size to separate those
                           of  the desired size from those that  are too large  and from sawdust.
                           Oversize chips are sent through crushers to reduce them to the proper
                           size. Proper sized chips are send to a chip bin or silo where they may be
                           joined by chips that have arrived by  rail or truck  from  lumber, veneer,
                           and ply-wood mills.

                      3.    From the chip bin the wood  chips are fed to the digester. Two types of
                           digesters in wide use today are the continuous digester and batch digester.
                           There are also a few rotary  digesters still in use.  Continuous digesters
                           are tall towers that  are fed  chips and cooking  liquor at the top,  while
                           pulp, along with spent cooking liquor, are continuously withdrawn to the
                           blow tank. Batch digesters consist of a  series of vertical vessels. The
                           individual vessels are charged with chips, and  cooking  liquor is added.
                           The vessel is closed up and pressurized with  live steam. The cooking
                           time  will vary from 2 to 5 hours at a temperature of about 350ฐF and a
                           pressure of 100 to 125 psig. The cooking liquor is composed primarily
                           of a 12.5% solution of sodium sulf ide and  caustic soda. It is often referred
                           to as white liquor because of its color.

                      4.    When the operator determines that the cook is finished, he will reduce
                           the pressure to 80 psig by opening the blow valve on the bottom of the
                           vessel and  allowing the pulp, along with the spent  liquor, to be blown
                           to the blow tank. Blow tanks are vented to an accumulator.

                      5.    The pulp is separated from the cooking liquor by filtration and washing.

                      6.    The spent liquor (black  liquor), now containing about  15% solids,  is
                           transferred to the weak black liquor storage tank prior to the recovery of
12

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          its chemical constituents for reuse in the digester.

     7.   The washed pulp passes to the screen room where slivers of uncooked
          wood, and knots which failed to disintegrate, are separated from the pulp.
          Knots removed in this step are sent to waste, but screenings are refined
          and returned to the process.

     8.   If the pulp is to be bleached (by an agent which oxidizes and destroys
          dyes which were formed from tannins present in the wood and intensified
          by sulfides in the cooking liquor), it is done at this time.

     9.   After the pulp is bleached  or prepared as desired and thickened, it is
          sent to storage.

     10.  If the end product is pulp, "lapping"  is performed on an  endless felt
          belt which carries pulp sheets through a series of squeeze and hot press
          rolls. The resulting "laps", which contain approximately 40%  air-dry fiber,
          are subject to pressures up to 3000 psig. This pressure, exerted by
          hydraulic presses, raises the air-dry fiber content to between 50 to 60%.
          If the pulp is to be made directly  into  paper, the pulp from storage will
          go through refining before it goes  to the wet end of the paper machine.

     The recovery and reuse of chemicals from the weak black liquor makes kraft
pulping economically feasible. The recovery  system,  in general, and the recovery
furnace, in particular, are the primary subjects of this narrative.

     The weak black liquor removed from the pulp in  the washer (Step 5) contains
about 96% of the alkali originally charged to the digester. Alkali  is present as sodium
sulfate, salt, silica,  and trace quantities of other inorganic compounds.

     The recovery system portion of the process  is shown schematically on Figure
1. It consists of the following steps.

     11.  The weak black liquor is pumped from storage to the multiple-effect
          evaporators. These evaporators use  steam to concentrate the  liquor
          to about 50% solids.  There is no direct contact between the steam and
          black liquor in these evaporators.

     12.  At this point, the liquor is concentrated to a solids content of at least 63%;
          necessary for it to ignite and sustain combustion when sprayed into the
          recovery furnace. This concentrated black liquor is termed "strong black
          liquor". Several alternative schemes are used for the concentration step.
          These are discussed in detail in the section entitled "Nature of the Gaseous
          Discharge".
                                                                                           13

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                                                      /WWWV—i
                                     STRONG BLACK
                                    LIQUOR STORAGE
   AIR
PREHEATER
             STEAM TO
              PLANT
                                                           GAS CLEANING
                                                             DEVICE
           WEAK BLACK LIQUOR
                                                   W
                                                  RECOVERY
                                                  FURNACE
        RECOVERED LIQUOR
                               MULTIPLE EFFECT
                                EVAPORATOR
          Figure  I.      Process  flow  diagram-block  liquor  recovery
14

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     13.  Strong black liquor is burned in the recovery furnace. Heat generated by
          the combustion of organic constituents is used to generate steam in a
          recovery boiler. This steam is returned to the  plant and can be used
          directly in the process or to generate electricity.

     14.  The solid smelt removed from the recovery furnace is dissolved in water
          to form green liquor. This liquor is subjected to  a causticizing treatment
          with slaked lime, to convert sodium carbonate to sodium hydroxide.

     15.  Following Step  14, the causticized liquor, referred to as "white  liquor",
          is conveyed to a settling tank. Calcium carbonate sludge settles out in the
          tank and the white liquor is further clarified by filters. The clarified liquor
          is now ready for  reuse as cooking liquor in the digester.  The calcium
          carbonate sludge is burned in a lime kiln where carbon dioxide is liberated
          yielding calcium oxide or lime. This lime is reused in the causticizing of
          green liquor as in Step 14. The subject of these lime kilns as an emission
          source is covered in depth in a separate report entitled,  "Air Pollution
          Control Technology and Costs in Seven Selected Areas". This report was
          prepared under EPA Contract No. 68-02-0289.

     It is obvious from the preceding process description and flow diagram that the
recovery system is an important part of the whole process. The recovery steps
regenerate 95% of the chemicals used in  addition to producing  10,000 Ib steam2
per ton of pulp produced. It is estimated2 that in 1960, the pulp industry in the United
States internally generated about 60% of the 30 billion Kw-hr of electrical energy
that it consumed that year.
                         THE RECOVERY FURNACE

     In the recovery furnace, combustion of black liquor is effected by spraying the
atomized liquid onto the furnace walls. Spray nozzles are located on one furnace
wall  and oscillate (and/or rotate) automatically such that the sheet spray covers
the remaining walls. The extent and frequency of oscillation  is manually adjustable
over a wide range  in order to compensate for changes in  solids content of the
liquor. The adjustability permits optimization of the operation in terms of recovering
cooking chemicals, disposing of organic sulfur compounds, satisfying process steam
demand, and minimizing the quantity of objectionable emissions. In the lower portion
of the  furnace, called the reduction zone, inorganic sodium sulfate and sodium
carbonate are reduced. These settle out in a smelt  on the furnace grate. Organic
sulfur compounds are oxidized in the upper, or oxidizing,  zone.
                                                                                           15

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                      Varying  firing rates  and steam  demand affects the nature and quantity of
                 pollutants emitted. An inadequate supply of primary or secondary air results in
                 incomplete combustion giving rise to higher emission rates for carbon monoxide
                 and other unburned hydrocarbons. Gaseous, malodorous components of the flue gas
                 are hydrogen sulfide, mercaptans (particularly methyl mercaptan), dimethyl sulfide,
                 dimethyl disulfide, and other organic sulfides and disulfides.

                      The odor problem in the vicinity of kraft pulp mills is aggravated by the fact
                 that olfactory responses to gases mentioned in the preceding paragraph occur at
                 extremely low concentrations. Hydrogen sulfide, for example, characterized by the
                 smell of rotten eggs, has  an odor threshold value in the parts per billion range. By
                 contrast,  the odor threshold for ammonia is over 50 parts per million. Table 4 lists
                 ranges of odor threshold values for some of these gases along with their character-
                 istic odor3.
                                   NATURE OF THE GASEOUS DISCHARGE

                      The nature of the gas discharged from the black liquor recovery system strongly
                 depends upon which of several alternative flow schemes is used. The conventional
                 scheme is the one shown in Figure 2. The black liquor is concentrated from 15%
                 to about 50% dissolved solids in a series  of multiple effect evaporators. It is
                 then pumped from storage through the wet bottom of the precipitator, if used,
                 where  the  salt cake collected by  the  precipitator is deposited  and  dissolved
                 into the liquor. From this point, it goes to the chemical ash tank where it receives
                 the salt cake that accumulates  in the hoppers  under the boiler section of the
                 recovery boiler. From the  chemical  ash tank the  liquor goes to a direct contact
                 evaporator. This evaporator may be either a cyclone or cascade type. In either case,
                 the liquor is in direct contact with the flue gases from the boiler. The flue gases
                 enter the evaporator at about 550ฐF, leave  at  about 300ฐF, and pick up enough
                 water from the liquor to concentrate it to 63%+ solids. From the evaporator, the
                 liquor goes to the salt cake mix tank where make-up salt cake is added as required
                 before it goes to the burner nozzles in the recovery furnace.

                      The conventional system has two sources of odor emission: the furnace and the
                 direct contact evaporator. If the furnace is operated properly at its design rating,
                 with sufficient combustion air, it should not be  a significant source of odor6. The
                 tendency, however,  is to run  these furnaces well above capacity. Under these
                 conditions, emissions of odorous gases occur at a much higher rate, as illustrated
                 in Figure 31.

                     Odorous emissions occur at  the direct  contact evaporator due to chemical
                 reactions between  components of the black liquor and the furnace flue gases.
16

-------
                              TABLE 4s
       ODOROUS CHEMICALS EMITTED FROM KRAFT PULP MILLS
Gaseous Compound


Sulfur Dioxide


Hydrogen Sulfide


Methyl Mercaptan


Dimethyl Sulfide
Odor Threshold Range
   ppm by Volume    Characteristic Odor
     1.0 to 5.0       Sharp, pungent


  0.0009 to 0.0085    Rotten eggs


  0.0006 to 0.040     Rotten cabbage


  0.0001 to 0.0036    Vegetable sulfide
                                                                               17

-------
               I
                  ELEC.
                 PRECIP.
           50V.
           BLACK

           LIQUOR
           5TORAGI
i
        FROM
        MULTIPLE
        EVAPORATORS
                                                        n  a  a
                                                      LIQUOR BURNERS
        Figure  2.    Flow  diagram  of  conventional  recovery  furnace.
18

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                       Na2 S + 2H2O -* 2NaOH + H2S

                    Na2S + CO2  4- H2O -ป Na2C03 + H2S

  Exhaust gases from recovery boilers using direct contact evaporators have been
  reported to contain 70 to 1,500  ppm of H2S9 and constitute the principal source
  of odor from recovery boilers not  using oxidized black liquor8.

       As well as  concentrating  the black  liquor,  the direct  contact  evaporator
  performs  an  efficient  job as a  SO2  scrubber, and a  limited and rather  less
  efficient job as a particle  collector. Paniculate  loadings from recovery boilers
  having direct contact  evaporators, not using venturi scrubbers, will range from
  1.5  gr/ACF  to 3.0 gr/ACF. Exit  flue gas  temperatures will range  from  270ฐF
  to 350ฐF.

     Several alternative approaches to the conventional flow scheme have been
tried in order to reduce  the emissions of odorous gases. Each of these schemes
has been aimed at  impeding the mechanisms by which odorous gases are formed
in the direct contact evaporator.

     Three different process schemes have been put forward to alter the chemistry
in the evaporator. The  first of these is to precede the evaporator step with  an
oxidation step.

     Oxidation
     The oxidation  reaction converts Na2S to Na2S2Oa and, as a result, Na2S is
not available for hydrolysis or reaction with CO2, and H2S is therefore not formed.
Black liquor oxidization to the extent of 99% and higher is commercially feasible3.

     The weak or strong black liquor, or both, may be oxidized. However, reverse
reactions yielding Na2S  are possible and can impede overall effectiveness. Where
a low cost  source  of O2 is available, weak  liquor oxidation can be  done very
efficiently and with a minimum of capital equipment.  Since  foaming of the oxidized
black  liquor in the recovery furnace  is  a  problem with weak liquor,  strong
liquor oxidation is used more often.

     A block flow diagram of this process is presented in Figure 4.


     ACE System

     Another process which  alters the chemistry in  the evaporator  uses  an air
contact evaporator and is called the ACE system. A regenerative air heater replaces
the direct contact evaporator on the flue gas end of the boiler.  The heated combustion
air from the  air heater is then used to evaporate the water, and thus concentrate
                                                                                          19

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    1000  r
      JOO
  s:
  CL
  Q-
         0
i jju re  3 .
       FURNACE  LOADING

Re 1.'it ion between  IbS production  ;mcl  furnace

-------
                                       TO  ATMOSPHERE
BLACK
LIQUOR
1*




1ULTIPLE
^—






OXIDATION

I


EFFECT
EVAPORATORS















ซ—












DIRECT
CONTACT
EVAPORATOR
COMBUSTION AIR
-ป






BLACK
LIQUOR
RECOVERY
FURNACE

















SMELT



Figure 4.     Black liquor recovery using oxidation, block flow diagram.

-------
                  the liquor for firing into the furnace, in a cascade type contact evaporator before
                  the air is directed to the wind boxes of the furnace. Since the COz in the flue gases
                  does not come in  direct contact with the Na2S in the liquor, no H2S is formed.
                  This process,  however, does not prevent the production of hfeS by the hydrolysis
                  route. A flow diagram is shown in Figure 5.

                      Since the flue gases from  the boiler also pass through the  small passages
                  of the air heater, there is a tendency for these passages to plug, and they  must
                  be kept clean by soot blowing and periodic washing.

                      During at least part of the washing period, the air heater must  be isolated from
                  the system by means of gates, to prevent water carry-over. These boilers have two
                  air heaters so that it is possible for the boiler to remain in service while one heater
                  is being washed.

                      Controlling the combustion of liquor presents some problems with this system,
                  due to the high moisture content of the combustion  air, which results from the
                  evaporation of water from  the liquor in  the air cascade evaporator. The level of
                  SOa emission is generally higher than with the conventional system.

                      This system does not require black liquor oxidation to control H2S emission,
                  nor does it require a black liquor concentrator following the multiple effect evaporators.

                      The particulate loadings from  this type of recovery  boiler system will range
                  from 2.5 gr/ACF to 4.5 gr/ACF. The salt cake collected in the precipitator appears
                  to be more sticky  than that found in other systems.  Exit flue gas temperature
                  will range from 325ฐF to 400ฐF.

                      LAH System

                      The Laminaire air heater (LAH) type of boiler arrangement is similar to the
                  ACE system since  it utilizes regenerative air  heaters.  However, it does not have
                  an air contact evaporator. A flow diagram is shown in Figure 6. With the exception
                 of the  furnace, which is designed  to burn black liquor, the boiler arrangement
                 is very much like most utility boilers. Means are provided for washing one of the
                 two air heaters while the boiler remains in service.

                      Since a contact evaporator is not  used, the liquor  from the multiple effect
                  evaporators must be further concentrated to about 63% solids in a steam concen-
                  trator, before it can be fired in the furnace.

                      Paniculate loading will range from 3.0 to 4.5 gr/ACF. Flue gas temperatures
                  generally will range from 350ฐF to 400ฐF. Flue gas volumes, as with the ACE system,
                 will average higher than with other  systems due to the leakage in the air heater.
                  Seals must be maintained in order to keep this leakage at a minimum.
22

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   BLACK
   LIQUOR
   STORAGE
                       65% BLACK.IQUOR
FROM
MULTIPLE
EVAPORATORS
Figure 5.      Flow diagram of air contact evaporation system.
                                                                          23

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             50%
           BLACK
           LIQUOR
          STORAGE
ฃ8    63%  BLACK  LIQUOR


k.
•v:
>-
LiJ
>
DISSOLVING
TANK
         FROM  MULTIPLE
           EVAPORATORS
                                                           TO
                                                          CAUSTICIZER
Figure  6.    Flow diagram of Laminaire air heater  system.

-------
     Large Economizer

     The large economizer boiler arrangement does not utilize a contact evaporator
and therefore the liquor must  be concentrated before firing, as with the LAH
arrangement. This has been achieved by designing the multiple effect evaporators
to produce 60 to 63% solids content product and recovering available furnace heat
from the flue gases with a large economizer.  A flow diagram of this arrangement
is shown in Figure 7. The size and  configuration of the economizer will depend
upon the desired feed water temperature and flue gas temperature requirement.

     Since there is  a tendency for  the economizer  to  plug, soot-blower  steam
requirements are considerable and account for the higher than expected water vapor
in the flue gas along with  its volume. Paniculate loading  will range from 3.0 to as
high as 6.0 gr/ACF, with exhaust temperatures from 350ฐF to 450ฐF. Grain loading,
as well as temperature, tend to  cycle with the cleanliness in the economizer. As
the economizer  becomes dirty,  the  exit gas  temperature will go up. The grain
loading in the flue gas will sharply increase when the blower cycle begins.
                 NATURE OF THE PARTICULATE EMISSION

     Particulate emissions from  a kraft recovery furnace are characterized by a
high sodium  content. A small percentage of these particles may be as large as
10 microns in diameter but, generally, they will be smaller than 1 micron.
                  t
     Most of the salt cake fired into the furnace with the black liquor is reduced to
sodium sulfide  and is  removed from the furnace as smelt. A portion of the salt
cake volatilizes and passes through the boiler where it condenses on cooler surfaces
or in cooler gases. Particulates formed in this manner are extremely small in size,
generally below one micron.

     The control of air to the furnace is very important. Excess air in the reduction
zone will oxidize carbon directly to carbon dioxide,  destroying its ability to reduce
salt cake to sodium sulfide. If excess air is reduced, the concentration of sodium
carbonate in  the carry-over will increase. The  condition  of the smelt bed and its
temperature will also have an  effect on the paniculate matter as well as the gases
emitted.

     Some of the salt  cake will collect  in the generating tube, superheater tube,
and economizer tube sections of the boiler. This is removed by automatic soot
blowers and  in some cases  lancing.  Much of this is reentrained in  the  gas
stream  and  leaves the boiler with the flue gases.  The remainder is collected
in  hoppers under the economizer and returned to the chemical ash tank where it
is  put back into the black liquor. Since the bulk density  of  the salt  cake leaving
                                                                                           25

-------
       Q
              ELEC--
           PREaPITATOR
          50%
        BLACK LIQUOR
        STORAGE
                                                             DISSOLVING
                                                                TANK
        FROM  MULTIPLE
        EVAPORATORS
                                                                TO
                                                              CAUSTICIZER
        Figure  7.    Flow diagram of  large economizer  system.
26

-------
the boiler is well below 10 Ibs/cu/ft, it is very easily reentrained.

     The quantities of  participates emitted,  including  sodium  sulfate,  sodium
carbonate, and unburned carbon will be in the range of 90 to 275 pounds per air
dried ton (ADT) of pulp produced  by the plant. A nominal  average emission rate
of 150  lb/(ADT)2.4 is used  for estimating  purposes. This  loss of chemical is
not only an economic problem to the plant (sodium sulfate  lost must be replaced
in the process) but is also an  air  pollution nuisance.
                  POLLUTION CONTROL CONSIDERATIONS

     Early methods of reducing participate emission consisted of filters, using wetted
wood chips and cyclone type mechanical collectors.  Later, these  were replaced
with electrostatic precipitators and wet scrubbers, both capable of  90% collecting
efficiency. Precipitators were capable of still  higher efficiency, but the increased
efficiency  above 90% could not be economically justified. At this  efficiency, and
assuming the uncontrolled plant would emit 150 Ib of  salt cake per (ADT) of pulp
produced, there would be a net reclamation of  135 Ib of salt cake. Using a delivered
cost of salt cake of $0.015/lb, the reclaimed chemicals produce a savings of over
$2.00 per (ADT).

     Scrubbers are  no  longer  employed as  a primary collector.  The scrubbers
used were high energy venturi types using black liquor as the  scrubbing media
which provided a means of  heat recovery.  The black  liquor was concentrated  by
evaporation as it cooled  the flue gas to about 180ฐF. The black liquor,  used  as
scrubbing media, however, was in direct contact with  the flue gases and became
another source for odor pick-up. Foaming is also a problem.

     Scrubbing is effective in the removal of both paniculate and gaseous emissions,
particularly SO2 where black liquor is used.  The overall thermal  efficiency of a
furnace equipped with a venturi-evaporative scrubber  is considerably higher than
a comparable furnace employing an electrostatic precipitator since the final discharge
gas  temperature is 120ฐF lower in the  former  case.  In order to obtain the 90%
collecting  efficiency, the pressure  drop across the venturi has to be maintained at
about 40 in.wc.

      Low energy  water scrubbers are being currently used following some precipita-
  tors to collect agglomerates which have been re-entrained. These agglomerates are
  large particles, or flakes of  salt cake, which are relatively flat, presenting a high sail
  area for re-entrainment after initial collection.  The emission of these re-entrained
  particles is known as "snowing". In some cases, where the scrubber is not actually
  provided as part  of a new emission control system, provisions are made for future
  addition of these  scrubbers.
                                                                                            27

-------
                      Today, precipitators are the sole device being purchased for the control of
                 participate emission from recovery boiler gases. Recently installed units and those
                 currently contemplated are all designed at efficiencies ranging from 99.5% to 99.9%.
                 Boilers without contact  evaporators  generally  have a  slightly higher inlet dust
                 loading and, therefore, the precipitator should be designed for a higher efficiency in
                 order to yield the same residual. All of the precipitators have steel shells and are
                 well insulated. In some instances, auxiliary heat is supplied between the insulation
                 and the shell. Each unit is designed with  many bus sections and always has two or
                 more chambers. Electronic automatic controls maintain the operating level, so little
                 or no attention is required of the plant operators.

                      Although there  are  now  no  commercial  kraft  installations  employing
                 fabric filters, the economics of this abatement method are becoming more attractive.
                 There is ongoing pilot plant  work on kraft mill fabric filters and it is expected that a
                 prototype will be built soon.
                                        SPECIFICATIONS AND COSTS

                     Equipment specifications were written for electrostatic precipitators applied to
                both conventional and controlled odor  (large economizer) type recovery boilers.
                Each specification requested costs for both medium and high efficiency performance
                precipitators applied to a small (500 ADT/day of pulp) and a large (1,500 ADT/day
                pulp) recovery boiler. Medium efficiency was specified at a residual of 1.7 Ib. of
                emission/ADT.* High efficiency was specified at 0.02 gr/DSCF. These specifications
                are shown in Tables 5, 6, 9, 10, 11, and 12.

                     Two sets of specifications were written for the controlled odor boiler cases:
                one specifying a roof location for the precipitator, the other specifying a ground
                location. Some of the bidders reported no difference in capital cost between the two
                systems. Other bidders reported differences as summarized below.

                                                Additional Cost for Ground Location
                               Boiler Size            Dollars       % of Total Capital Cost

                                 Small              $21OM                11
                                 Large              $640 M                14
               *While the paper  industry and old pollution control codes  quantify emissions in
               terms of Ibs/ADT, equipment manufacturers use gr/ACF.
28

-------
     As can be seen, the costs are greater for the ground locations. The ground
locations cost the same amount more than the roof locations for both the medium
and  high  efficiency  precipitators since the increased cost is due  solely to the
additional structural steal and ductwork required for the ground location.

     Cost data are presented for the conventional boiler in Tables 7 and 8 and in
Figures 8,  9,  10, and 11. Cost  data are presented for the controlled odor boiler
(ground location) in Tables 9 and 10 and in Figures 12, 13, 14, and 15. Average
drift velocities used to size the precipitators are summarized below.

                                                        Drift Velocity
                                                    cm/sec       ft/sec

                         Conventional Boilers         7 to 8    0.23 to 0.26
                         Controlled Odor Boiler     5.51 to 6.5  0.18 to 0.21

     The lower drift velocities in the controlled odor precipitators are due to lower particle
     density and size from the controlled odor boilers. The specifications for both types of
     boilers required that provision be made for a low energy "anti-snow" scrubber to be
     installed potentially at a later date. One precipitator bidder was asked to supply the
     cost of the scrubber that would be installed, should it be required. Those installed
     scrubber costs are estimated to be:

          Small Plant (Med. and High Eff.) —  $146,000
          Large Plant (Med. and High Eff.) — $498,750
                                                                                            29

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                                                       TABLE 5

                                ELECTROSTATIC PRECIPITATOR PROCESS DESCRIPTION

                      FOR CONVENTIONAL KRAFT PULP MILL RECOVERY FURNACE SPECIFICATION
                   A wet bottom electrostatic precipltator Is to remove solids from the effluent gas from a
                   new, conventional recovery furnace.

                   The system shall be quoted complete including all of the following:

                   1. Inlet ductwork and inlet plenum.

                   2. Wet bottom electrostatic precipitator and liquor handling equipment.

                   3. Outlet ductwork and 100 foot stack.

                   4. Dampers,  slide gates and pressure control system.  The draft fan will be considered
                     part of the boiler and will be supplied by others.

                   5. Other necessary auxiliary equipment.

                   6. Electrical installation work including only low voltage wiring.

                   The precipitator is to continually reduce the solids content of the flue gas to  the levels
                   specified.

                   1. Inlet Ductwork and Inlet Plenum
                     The outlet ductwork of the boiler will be extended through the roof by the boiler manu-
                     facturer and be available for connection to the inlet plenum of the  precipitator. The
                     inlet plenum will be specified.

                   2. Precipitator
                     The precipitator shall be a  wet bottom, single stage, plate type unit with a minimum
                     of two fields in the direction of gas flow for the intermediate efficiency case  and three
                     fields for the high efficiency case. Inlet face velocity shall not exceed 5 FPS and 4 FPS,
                     respectively.

                     The precipitator shall be divided into two gas-tight chambers. Dampers or similar flow
                     balancing  devices shall be furnished for each chamber. Each chamber will have slide
                     gates at inlet and outlet,  so that one chamber may  be isolated for repairs while the
                     other chamber remains operative.  A heated pressurized penthouse design should be
                     employed. Shell heating is not required.

                     The precipitator will be located on the roof of the recovery boiler building.

                     The wet bottom shall be capable of holding a minimum depth of one foot of black
                     liquor. Agitators will cover a minimum of 50% of the bottom area and will continuously
                     mix deposited salt cake into the black liquor. One black liquor feed connection, one
30

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   overflow connection, one emergency overflow, three inch Instrument flanged connection,
   and one drain connection  will be provided. Black liquor handling  to and from the
   precipitator will be supplied by others. The black liquor coming to the preclpitator wet
   bottom will normally contain ซs67 wt% solid.

   Electrical power at 460v,  3  phase,  60 cycle; and 110v, 1 phase, 60 cycle is available
   in sufficient quantity at the site. Automatic voltage controls shall be provided for each
   field. A safety interlock system shall be provided  so  that no access to  high voltage
   equipment is possible without first de-energizing all fields.

   Equipment shall be provided for continuous removal of the solids recovered in the liquor.
   Storage equipment will have a capacity sufficient for 24 hours of continuous operation,
   and will be supplied by the purchaser.

3. Outlet Ductwork and Stack
   The cleaned gases will be conveyed to the atmosphere by the outlet ductwork  and
   stack, located on the roof. The outlet  ductwork will be  the equivalent of  150 linear
   feet and will have provisions for the addition of a wet scrubber at a later time.

4. Fans, Dampers, and Pressure Control System
   A tan of sufficient size to overcome the pressure drop of the precipitator system, including
   possible future secondary wet scrubber, will be supplied by the boiler manufacturer.
   Appropriate dampers shall be placed so as  to control the flow of gas as described in
   Section  #2.

The material of construction of all parts of the system shall be mild steel.

A model study for the precipitator gas  distribution system will not be required.
                                                                                                    31

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                                                      TABLE 6

                                ELECTROSTATIC PRECIPITATOR OPERATING CONDITIONS
                                        FOR CONVENTIONAL KRAFT PULP MILL
                                         RECOVERY FURNACE SPECIFICATION
                    Plant Capacity, ADTIday

                    Precipitator Inlet Conditions
                        Gas Rate, ACFM
                        Temperature, ฐF
                        Gas Rate, SCFM
                        Moisture Content, vol%
                        Gas Rate, DSCFM

                    Inlet Loading
                       grIACF
                       grIDSCF
                       Iblhr

                    Precipitator Outlet Conditions
                       Gas Rate, ACFM
                       Temperature, ฐF
                       Gas Rate, SCFM
                       Moisture Content, vo/%
                       Gas Rate, DSCFM

                    Residual, Med. Eff. Case
                       grIACF
                       gr/DSCF
                       Iblhr

                    Collection Efficiency, %

                    Residual, High Eff. Case
                       grIACF
                       grIDSCF
                       Iblhr

                    Collection Efficiency, %
265,300
    350
173,600
     30
121,500
      2.0
      4.4
  4,549
265,300
    350
173,600
     30
121,500
      0.016
       .035
    36

    99.2
     0.009
     0.02
    20.8

    99.6
 795,900
    350
 520,800
     30
 364,500
      2.0
      4.4
 13,647
795,900
    350
520.800
     30
364,500
      0.016
       .035
    109

     99.2
     0.009
     0.02
    62.4

    99.6
32

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                    TABLE 7

   ESTIMATED CAPITAL COST DATA (COST IN DOLLARS)
FOR ELECTROSTATIC PRECIPITATORS FOR KRAFT PULP MILL
         CONVENTIONAL RECOVERY FURNACE


Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
( 1 } Gas Cleaning Device Cost
(2) Auxiliaries Cost "1
(a) Fan(s)
(b) Pump(s)
(c) Damper(s) I
(d) Conditioning,/
Equipment
(e) Dust Disposal
Equipment
J
(3) Installation Cost "N
(a) Engineering
(b) Foundations
& Support
Ductwork
Stack
Electrical
Piping >
Insulation
Painting
Supervision
Startup
Performance Test
Other
(4) Total Cost
Medium Efficiency
Small

265,300
350
173,600
30

2.0
4,549

265,300
350
173,600
30
.016
36
99.2
469,367
55,973 '








677,390












1,202,730
Large

795,900
350
520,800
30

2.0
13,647

795,900
350
520,800
30
.016
109
99.2
1,097,288
112,350








1,316,453












2,526,092
High Efficiency
Small

265,300
350
173,600
30

2.0
2,549

265,300
350
173,600
30
.009
20.8
99.6
534,121
73,334








729,157












1,336,613
Large

795,900
350
520,800
30

2.0
13,647

795,900
350
520,800
30
.009
62.4
99.6
1,372,041
133,744








1,539,262












3,045,047
                                                              33

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                    TABLE 8

    ANNUAL OPERATING COST DATA (COST IN S/YEAR)
FOR ELECTROSTATIC PRECIPITATORS FOR KRAFT PULP MILL
         CONVENTIONAL RECOVERY FURNACE
Operating Cost Item
Operating Factor, Hr/Year-8600
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost

$6/mh
$8/mh
$6/mh



$0.011 kwh




16% of Cap

Medium Efficiency
Small

3,240
1,440
4,680
1,920
67
1,987
9,200
9,200

42,100


42,100
57,967
192,437
250,404
Large

3,240
1,440
4,680
2,580
100
2,680
14,825
14,825

113,400


113,400
135,585
404,175
539,760
High Efficiency
Small

3,240
1,440
4,680
1,920
67
1,987
9,200
9,200

45,800


45,800
61,667
213,858
275,525
Large

3,240
1,440
4,680
2,580
100
2,680
14,825
14,825
i
i
123,700


123,700
145,885
487,208
-633,093

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                              FIGURE 8


             CAPITAL COST OF ELECTROSTATIC PRECIPITATORS

            FOR KRAFT MILL CONVENTIONAL RECOVERY FURNACE

                          (MEDIUM EFFICIENCY)
    6


    5


    A
                                                 TURNKEY SYSTEM

   I06
    9
    8

fc"   I
8   6
                                                 COLLECTOR PLUS AUXILIARIES

                                                 COLLECTOR ONLY
    I05
      I05
   3    4   5   6  7 8 9 ICT

CLEANED GAS FLOW, ACFM
                                                                             35

-------
                                     FIGURE 9

                     ANNUAL COST OF ELECTROSTATIC PRECIPITATORS
                 FOR KRAFT PULP MILL CONVENTIONAL RECOVERY FURNACE
                                 (MEDIUM EFFICIENCY)
      \
      te
      o
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CLEANED GAS FLOW, ACFM
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-------
                          FIGURE 10
6

5

4
          CAPITAL COST ฉF ELECTROSTATIC PRECIPITATORS
          KRAFT PULP MILL CONVENTIONAL RECOVERY FURNACE
                       (HIGH EFFICIENCY)
                                              TURNKEY SYSTEM
2
                                    X
                                             COLLECTOR PLUS AUXILIARIES
                                             COLLECTOR ONLY
8
7
 5

 4

 3
          S*'
I05
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2      3   4   5   6789 I06

    CLEANED GAS  FLOW, ACFM
                                                                       37

-------
                                      FIGURE 11
                      ANNUAL COST OF ELECTROSTATIC PRECIPITATORS
                  FOR KRAFT PULP MILL CONVENTIONAL RECOVERY FURNACE
                                   (HIGH EFFICIENCY)
6
5
4
3
2
-I I05
Q 9
" 8
Is 7
8 6
5
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CLEANED GAS FLOW, ACFM
38

-------
                                    TABLE 9

             ELECTROSTATIC PRECIPITATOR PROCESS DESCRIPTION

 FOR KRAFT PULP MILL CONTROLLED ODOR RECOVERY FURNACE SPECIFICATION
A dry bottom electrostatic precipitator is to remove solids from the effluent flue gas from
a controlled odor recovery furnace.

The system shall be quoted complete including all of the following:

1.  Inlet ductwork and inlet plenum.

2.  Dry bottom electrostatic precipitator.

3.  Outlet ductwork and 100 foot stack.

4.  Dampers,  slide  gates  and pressure  control system. The draft fan will be considered
   part of the boiler and will be supplied by others.

5.  Other necessary auxiliary equipment.

6.  Electrical installation work including only low voltage wiring.

The precipitator is to  continually reduce the solids content of the flue gas to the levels
specified.

1.  Inlet Ductwork and Inlet Plenum
   The outlet ductwork of the boiler will be extended through the roof by the boiler manu-
   facturer and be available for connection  to the inlet plenum of the precipitator.  The
   inlet plenum  will be specified.

2.  Precipitator

   The precipitator shall be a  wet bottom, single stage, plate type unit  with a minimum
   of two fields  in the direction of gas flow for the intermediate efficiency case and three
   fields for the high efficiency case. Inlet face velocity shall not exceed 4Vi FPS and 4 FPS,
   respectively.

   The precipitator shall be divided into two gas-tight chambers. Dampers or similar flow
   balancing  devices shall be furnished for each  chamber. Each chamber will have slide
   gates  at inlet and  outlet, so that one chamber may be isolated for repairs while the
   other chamber remains operative. A heated pressurized penthouse design should be
   employed. Shell heating is not required.

   The precipitator will be located at ground level adjacent to the recovery boiler building.

   Electrical power at 460v, 3 phase, 60 cycle; and 110v,  1 phase, 60 cycle is available
   in sufficient quantity at the site. Automatic voltage controls  shall be provided for each
   field.  A safety system shall be provided so that no  access  to high voltage equipment
   is possible without first de-energizing all fields.
                                                                                                  39

-------
                    Equipment shall be provided for continuous removal of the solids recovered in the liquor.
                    Storage equipment will have a capacity sufficient for 24 hours of continuous operation,
                    and will be supplied by the purchaser.

                  3. Outlet Ductwork and Stack
                    The cleaned gases will  be conveyed to the atmosphere by the outlet ductwork and a
                    stack located on  the  ground. The ductwork shall be the equivalent of 300 linear feet
                    and will have provision for attachment of a secondary wet scrubber.

                  4. Fans, Dampers, and Pressure Control System
                    A fan of sufficient size  to overcome the pressure drop of the precipitator system, including
                    possible future secondary  wet scrubber, will be supplied by the boiler manufacturer.
                    Appropriate dampers shall be placed so as to control the  flow of gas as described in
                    Section  #2.

                  The material of construction of all parts of the system shall be mild steel.

                  A model study for the precipitator gas distribution system will not be required.
40

-------
                                 TABLE 10

            ELECTROSTATIC PRECIPITATOR OPERATING CONDITIONS
                 FOR   KRAFT PULP MILL  CONTROLLED ODOR
                     RECOVERY FURNACE SPECIFICATION
Plant Capacity, ADT/day

Precipitator Inlet Conditions
    Gas Rate, ACFM
    Temperature, ฐF
    Gas Rate, SCFM
    Moisture Content, vol%
    Gas Rate, DSCFM

Inlet Loading
    gr/ACF
    gr/DSCF
    Ib/hr

Precipitator Outlet Conditions
    Gas Rate, ACFM
    Temperature, ฐF
    Gas Rate, SCFM
    Moisture Content, vol%
    Gas Rate, DSCFM

Residual, Med. EH.  Case
    gr/ACF
    gr/DSCF
    Ib/hr

Collection Efficiency, %

Residual, High EH. Case
    gr/ACF
    gr/DSCF
    Ib/hr

Collection Efficiency, %
260,200
    425
155,800
     22
121,500
      4.0
      8.6
  8,920
260,200
   425
155,800
     22
121,500
      0.016
      0.080
    36

    99.6
     0.009
     0.02
    20.8

    99.8
                   Large

                   1,500
780,600
    425
467,400
     22
364,500
      4.0
      8.6
 26,760
780,600
    425
467,400
     22
364,500
      0.016
     0.080
    107

     99.6
     0.009
     0.02
    62.4

    99.8
                                                                                       41

-------
                                     TABLE 11

                     ESTIMATED CAPITAL COST DATA (COST IN DOLLARS)
                  FOR ELECTROSTATIC PRECIPITATORS FOR KRAFT PULP MILL
                         CONTROLLED ODOR RECOVERY FURNACE


Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
(1) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering
(b) Foundations
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup
Performance Test
Other
(4) Total Cost
Medium Efficiency
Small

260,000
425
155,800
22

4.0
8,920

260,200
425
155,800
22

.016
36
99.6
588,726
94,065


39,106




863,120













1,545,911
Large

780,600
425
467,400
22

4.0
26,760

780,600
425
467,400
22

.016
107
99.6
1,374,257
213,764


103,717




1,936,340













3,524,361
High Efficiency
Small

260,200
425
155,800
22

4.0
8,920

260,200
425
155,800
22

.009
20.8
99.8
704,551
98,909


39,106




943,358













1,746,818
Large

780,600
425
467,400
22

4.0
26,760

780,600
425
467,400
22

.009
62.4
99.8
1,713,660
227,347


103,717




2,172,809













4,113,816
42

-------
                    TABLE 12

    ANNUAL OPERATING COST DATA (COST IN $/YEAR)
FOR ELECTROSTATIC PRECIPITATORS FOR KRAFT PULP MILL
       CONTROLLED ODOR RECOVERY FURNACE
Operating Cost Item
Operating Factor, Hr/Year-8600
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost

$6/mh
$8/mh

$6/mh





$0.011/kwh






16% of Cap

Medium Efficiency
Small

3,240
1,440
4,680

1,920
67
1,987
9,400
9,400

45,800




45,800
61,867
247,346
309,213
Large

3,240
1,440
4,680

2,580
100
2,680
12,350
12,350

125,600




125,600
145,310
563,898
709,208
High Efficiency
Small

3,240
1,440
4,680

1,920
67
1,987
9,500
9,500

46,400




46,400
62,567
279,491
342,058
Large

3,240
1,440
4,680

2,580
100
2,680
13,250
13,250

127,900




127,900
148,510
658,211
806,721

-------
                                     FIGURE 12

                     CAPITAL COST OF ELECTROSTATIC PRECIPITATORS
                FOR KRAFT PULP MILL CONTROLLED ODOR RECOVERY FURNACE
                                (MEDIUM EFRCIENCY)
D
5
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44

-------
     ANNUAL COST OF ELECTROSTATIC PRECIPITATORS
FOB KRAFT PULP MILL CONTROLLED ODOR RECOVERY FURNACE
                (MEDIUM EFFICIENCY)
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                                                                45

-------
                                     RGURE14

                     CAPITAL COST OF ELECTROSTATIC PRECIPITATORS
                FOR KRAFT PULP MILL CONTROLLED ODOR RECOVERY FURNACE
                                  (HIGH EFFICIENCY)
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-------
                     FIGURE 15

     ANNUAL COST OF ELECTROSTATIC PRECIPITATORS
FOR KRAFT PULP MILL CONTROLLED ODOR RECOVERY FURNACE
                 (HIGH EFFICIENCY)
D
5
4
3
2
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                                                               47

-------
                                               REFERENCES
                 1.    Stem, Arthur C., Air Pollution, Volume III, Sources of Air Pollution and Their
                      Control, 2nd Edition, Academic Press, New York, 1968.

                 2.    Steam, Its Generation  and Use, 37th  Edition, The Babcock  and Wilcox
                      Company, New York, 1963.

                 3.    Hendrickson, E. R., J. E. Robertson and J. B. Koogler, Control of Atmospheric
                      Emissions  in the Wood Pulping Industry, Final Report. Contract No. CPA
                      22-69-18, March 15, 1970.

                 4.    Shreve, Norris R., The Chemical Process Industries. Chapter 33, McGraw-Hill,
                      New York,  1956.

                 5.    An  Economic Comparison of  Precipitators  and Bag Filters for Particulate
                      Emission  Control  on  Kraft  Recovery Furnaces.  Atmospheric  Quality
                      Improvement Tech. Bulletin No.  57, National Council of the Paper Industry
                      for Air and Stream Improvement, New York, Jan. 31, 1972.

                 6.    Field Operations and Enforcement Manual for Air Pollution Control,  Vol. Ill,
                      Inspection Procedures for Specific Industries, U.  S. Environmental Protection
                      Agency, OAP, August 1972.

                 7.    Scrubber Handbook, Vol. 1, Prepared for Control Systems Div., Office of Air
                      Programs,  Environmental  Protection  Agency,  Contract  No.  CPA-70-95,
                      August 1972.

                 8.    Canovali, L. L, and Suda,  S.,  "Case History of Selection and Installation of
                      a Kraft Recovery Odor-Reduction System," TAPPI, Vol.  53, No.  8, August
                      1970. pp. 1488-1493.

                 9.    Gommi. J.  V., "Reduced-Odor  Recovery Units,"  TAPPI. Vol. 55, No. 7,  July
                      1972, pp. 1094-1096.
48

-------
 2.    FERROALLOY FURNACES

      Ferroalloy is the term given to alloys of iron and non-ferrous metals such as
 silicon, chromium, and phosphorus.  Ferroalloys are primarily used as alloying
 agents and deoxidants in the production of stainless steel, carbon steel and cast iron.
 In the United States, most ferroalloys are produced in either blast or electric furnaces.
 Blast furnaces have a  lower operating cost but are limited to the production of
 ferroalloys with high carbon and low nonferrous metal content. Typical ferroalloys
 produced in blast furnaces  are  Spiegeleisen, ferromanganese, ferrosilicon, ferro-
 chrome, and ferrophosphorus. Electric furnaces have higher operating costs but
 are required for the production of low carbon, high nonferrous metal content alloys.
 For example, ferrosilicon from a blast furnace is limited  to 17% silicon. Its carbon
 content would be approximately 1.5%. Electric furnaces can produce ferrosilicon of
 over  85% silicon and less than 0.15% carbon. Typical ferroalloy compositions are
 listed in Table 13.

      Since  more than 80%  of the domestic production of ferroalloys is performed
 in electric furnaces1 the  remainder of the narrative will deal with  this type of furnace.

      Most electric furnaces used in the ferroalloy industry are of the submerged arc
 type. They differ from the standard electric furnace used in steelmaking in that the
 majority of the electrical energy is used to promote a chemical  reaction. There are
 generally three or six carbon electrodes. The electrodes are submerged into the
 melt half way between  the  hearth and the slag at  the top.  Figure 16 shows  a
 typical submerged arc furnace. Energy requirements are high. Depending on the
 type of ferroalloy  being produced, energy  requirements2 can vary from  1  to  6
 kwh/lb. Furnace sizes range3 from a few hundred to 50,000 kw.

     Most  ferroalloys such  as ferromanganese, high carbon ferrochrome,  and
 ferrosilicon  are produced  via  a one-step process  in a submerged  arc  electric
 furnace.4i s<6 Other ferroalloys require further treatment after  being tapped  from
the furnace. For example, molten high carbon ferrochrome is treated with oxygen
to produce  medium carbon  ferrochrome.6  Low  carbon  ferrochrome is produced
via a multiple  step process.6 This process incorporates a slag furnace, an  alloy
furnace, a ladle, and two reaction vessels.

     In the submerged arc  electric furnace, raw materials are continuously fed
 into  the  top of  the furnace. The  raw materials consist of iron and nonferrous
 metal ores,  reducing agents and fluxes. Typical reducing agents are coke,  coal,
 coke fines, wood chips,  and ferrosilicon alloys. At high temperatures, up to 2000ฐC,
 a reduction  reaction occurs  between  the metal  oxides and the reducing agents.
 The  products of the reaction are molten alloy and carbon monoxide.  The molten
                                                                                          49

-------
Ul
o
                                                             TABLE 13



                                              COMPOSITIONS OF TYPICAL FERROALLOYS
                 ALLOY TYPE




                 Ferromanganese (Std.)


                 Ferromanganese (L.C.)


                 Ferrosilicon


                 Ferrochromium (H.C.)


                 Ferrochromium (L.C.)


                 Ferrovanadium


                 Silicomanganese


                 Ferrotitanium


                 Spiegeleisen


                 Silvery Iron
wt.%
C Mn
7.5* 80
0.1-0.75 83
0.15*
6
0.03-2.0
3.5*
65
4
6.5* 17
1.5*
P
0.35*
0.35
0.05*


0.25*


0.25*
0.15*
S
0.05*
0.05
0.04*


0.40*


0.05*
0.06*
Si V Cr
1.25*
1.25
50
3* 73
1.5* 73
13* 35
20
2.5
1.0-4.0
17
Ti Al





1.5*

20 1.5


                  'Maximum

-------
                                PLAN
                      •*•"•*•* '•*.*'• •>ป"ซ*ซ'Vปi'.ซ''•••'ป.
                      ^  •"• • *• •• .*••••?.•:.• ''-1'
                                         *
                            SECTION
         (oS  ELECTRODES.             (f)  FLEXIBLE CONNECTORS.
         (b)  ELECTRODE HOLDERS       (g)  CABLES TO COUNTERBALANCES.
         U)  CAJIBON HEARTH          (h)  TAP HOLE
         (d)  CHARGE                 ( j)  PLATFORM
         (•)  BUSBARS                (Z)  CAR
Figure 16..Electric furnace  for  ferroalloy  production
                                                                              51

-------
                 alloy  settles to the hearth. Here, it is  tapped at one to  five hour intervals. The
                 carbon monoxide is the major gaseous emission from the melt. The basic overall
                 reactions are listed in Table  14. The nonreduced constituents of the metal ores,
                 known as slag, remain  at the top of the melt. The  slag is  either discarded or is
                 further processed.

                      Submerged arc furnaces can further be classified as open or closed according
                 to the method of  fume capture. Open hood furnaces allow the burning of carbon
                 monoxide over the melt. This  type of capture offers the advantage of easy access
                 to the furnace for stoking and addition of raw material. Its  chief disadvantage is
                 the production of  large volumes of gases. Closed hood furnaces collect  only the
                 fumes emitted directly from the melt. Their chief advantages are a low rate of gas
                 flow into the subsequent pollution  abatement equipment,  and the potential  for
                 carbon monoxide  recovery. The major disadvantages are the inaccessability of the
                 furnace for stoking, the problems involved in creating a good  seal, and the  disposal
                 of carbon monoxide from the abatement equipment. The  numbers of closed and
                 open hood furnaces in the U.S.A. are listed in Table 152.

                      Figures 17 and 18 show two types of closed hood furnaces. The completely
                ' sealed furnace has been used in Europe, Canada, and Japan.* Here, a mechanical
                 seal is used around the electrode to prevent escape of gases. In this type of design
                 all the off-gases  are  collected. There  is  no leakage into  the room. The major
                 problems are reliability of the mechanical  seal and maintenance of sufficient mix
                 height in the raw material additions ports (mix spouts) to preserve the seal.

                     The covered furnace is  more common in the United States. Raw materials
                 are fed around the electrodes thus creating the seal. This type of hood is reasonably
                 simple. From 65% to 98% of the gaseous emissions  are  captured. The major
                 disadvantage results from the gases which are not  captured. Gases leak  from
                 around the electrodes and burn. The flames create further pollution and maintenance
                 problems.

                     Control of emissions from  open hood submerged arc electric ferroalloy furnaces7
                by fabric filters  and wet scrubbers was dealt  with under a prior  EPA contract,
                No. 68-02-0301. In this narrative, additional cases of control of open hood emissions
                by fabric filters will be considered.
                 'There is one such unit in the United States, as well.
52

-------
                          TABLE 14


   BASIC OVERALL REACTIONS FOR FERROALLOY PRODUCTION



   Ore          Reducing    Electrical     Molten       Furnace
Constituents        Agents      Energy       Alloy          Gas


   Cr203     +     3C          -*         2Cr     +     3CO


   MnO     +      C          -ป         Mn           CO


   Si02      +     2C          -*         Si            2CO


   Fe203     +     2C          -ป         2Fe           3CO


   AI203


   CaO


   Mg02                                 Slag


   Si02
                                                                        53

-------
                                             TABLE 15






                          DISTRIBUTION OF DOMESTIC FERROALLOY FURNACES






                        Furnace Type           Number in Use          % of Total




                 Submerged Arc - Open Hood        100-150              71-76




                 Submerged Arc - Closed Hood       30-35               21-18




                 Open Arc                         12                  8-6
54

-------
     ELECTRODE
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TAP _.
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FURNACE
GAS OFFTAKE
/
&


Figure  17.   Sealed  furnace  for  producing
             ferroalloys.
                                                         55

-------
                        ELECTRODES
RAW MAT
FEED ARO
ELECTROC
COVER^
TAP .-
HOLEC
'L
UND
)ES v
m
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                                           GAS OFFTAKE
          Figure 18.  Covered  furnace for producing
                      ferroalloys.
56

-------
                  NATURE OF THE GASEOUS DISCHARGE

     Carbon monoxide is the major by-product of ferroalloy production. The weight
of CO emitted from the melt can exceed the weight of alloy produced. For example,
Table 16 shows a weight balance for production of 45% ferrosilicon. The amount
of carbon monoxide emitted is 2.12 tons for every 2 tons of ferroalloy produced8.

     The amount of gaseous emissions from closed and  open furnaces is  quite
different. The volume can be as much as 50 times greater with the open hood. For
example, Table 17 shows a comparison  of open and closed furnaces for the pro-
duction of 50% ferrosilicon. In this example, the difference in  gas flow rate was
a factor of 26.

     Only two and one-half volumes of air are needed to  convert one volume of
carbon monoxide to carbon dioxide. The remainder of the excess air used with
the open hood design is required for adequate ventilation  around the  hood to
prevent leakage of fumes into the room.

     Other components of the gaseous  discharge include hydrogen  and volatile
hydrocarbon. The volatile hydrocarbon comes from the  electrodes and from oil on
the surface of the steel shavings.
                NATURE OF THE PARTICULATE EMISSIONS

     Operation  of ferroalloy furnaces produces  particulate emissions at three
principal points:

     1. The top of the furnace, carried out with the reaction gases.
     2. The furnace tapholes.  Since most furnaces are tapped cyclically rather
       than continuously, the source is active only about 15% of the time.
     3. The ladle after tapping, which is also a non-continuous source of particulates.

     The particulates emitted are small in size and are composed of the oxides of
the metals being produced and used in the process. Examples are given in Table
18. Attention should be drawn to the submicron size of  the particles. Particles of
this size  are difficult to collect and usually require  high  expenditures  of energy.
Agglomeration of the particles can make the effective particle size to the collector
much larger than  that indicated  in the Table. Grain  loadings have been reported
in  the range of 5  to 30 gr/SCF  for the closed hood system and 0.1 to 2  gr/SCF
for the open hood system9.
                                                                                         57

-------
                                             TABLE 16

                     WEIGHT BALANCE FOR PRODUCTION OF 45% FERROSIUCON


                                 Production Rate Basis: 2 Ton/Hr of Alloy

                         Input, ton/hr                            Output, ton/hr*

               Quartzite                   2.02         Ferrosilicon                 2.00
               Coke                      1.18         Slag                      0.06
               Steel Shavings              1.15         Gas                       2.33
               Electrode Mass              0.04                                  	
                                          4.39                                   4.39
                'Averaged over operating cycle
58

-------
                      TABLE 17

 COMPARISON OF GAS FLOWS FROM OPEN AND CLOSED HOOD
50 MW SUBMERGED ARC FURNACES MAKING 50% FERROSILICON
                              Closed Hood           Open Hood

      Flow, ACFM                  20,000              310,000

      Temperature, ฐF                1,100                 460

      Flow, SCFM                   6,600              175,000
                                                                      59

-------
                                             TABLE 18
               PROPERTIES OF PARTICIPATE EMISSIONS FROM FERROALLOY FURNACES
           Alloy Type

           Furnace Hood Type

           Particle Size, /*
             Maximum
             Range of Most Particles

           Chemical Analysis, Wt. %*
             Si02
             FeO
             MgO
             CaO
             MnO
             AI203
             Cr203
             LOI"
50% Fe Si    Si Mn
            Fe Mn    H.C. Fe Cr
  Open
   0.75
  63-88
Covered
Open
Covered
0.75
0.2-0.4
15.63
6.75
1.12

31.35
5.55

0.75
0.05-0.4
25.48
5.96
1.03
2.24
33.60


1.0
0.1-0.4
20.96
10.92
15.41

2.84
7.12
29.27
             23.25
             8.38
             "Standard metal  oxides analysis  —  compounds not necessarily found in the
             chemical forms listed.

            "Loss in weight on ignition.
60

-------
                  POLLUTION CONTROL CONSIDERATIONS

     As previously mentioned,  the size of the particles emitted from a ferroalloy
furnace is very small. There are five types  of pollution control equipment which
could be employed to control this emission. They are:
     1.   Dynamic scrubber
     2.   Venturi scrubber
     3.   Ceramic tube filter
     4.   Electrostatic precipitator
     5.   Fabric filter

     The dynamic scrubber  has been successfully employed to collect particulate
matter from ferroalloy furnaces. Collection efficiencies  of greater than 98% for
participates and 79% for organics have been reported.9 The major problems are
a design capacity limitation  of  4000 ACFM  (2000 ACFM is standard size sold)
per unit, high power usage, high clean water consumption, and  disposal of the
liquid discharge.

     The venfuri  scrubber has  also been used to clean gaseous  emissions  from
ferroalloy furnaces. Collection efficiencies of greater than 98% have been reported
with open hood furnaces.9 High pressure drops are required for successful operation.
However, power and water consumption are  less than with the dynamic scrubber.

     Ceramic  tube  filters  have  been  used  in  Germany on calcium  carbide
electric  furnaces. This filter operates at 600ฐC which is above the combustion
temperature of the hydrocarbons in the gas stream. The capital cost is high.

     Electrostatic precipitators have not been widely used to control ferroalloy furnace
emissions in this country although they have  been used to some extent in  Europe.
The principal problems are poor resistivity and high capital cost.

     Fabric filters are widely  used as control devices for emissions from open hood
ferroalloy furnaces. High collection efficiencies are obtainable but the unit must be
installed so as to avoid the operating problems which are inherent in the application
of fabric filters to furnace gases. Furnace gases must be cooled prior to entering
the  fabric filter in order  to avoid damaging the bags which  have low design limit
temperatures.  Provision  must be made to  minimize the condensation of hydro-
carbon on the bags which could lead to blinding. Provision must also be made to
capture  sparks and  burning particles  before they can enter the fabric filter and
burn holes in the bags.
                                                                                         61

-------
                                          SPECIFICATIONS AND COSTS

                       Abatement specifications for fabric  filters were written for both small and
                   large sized operations for three types of ferroalloy furnace installations: ferrosilicon
                   furnaces with air dilution coolers, silicon  metal furnaces with air dilution coolers,
                   and silicon metal furnaces with evaporative coolers.

                       Estimates of capital costs and annual operating costs made by the bidders
                   for each system were averaged and presented in the cost tables and  graphs.
                   Reverse air or shaker type collectors with an  average air to cloth ratio of about
                   2:1 were used in each of the cases.  One of the three bidders specified a CaCOa
                   pre-coat required for all three systems and showed the pre-coat cost in his annual
                   operating cost estimate. This fact is footnoted  on the operating cost tables but is
                   not included in the averaged cost data presented.

                       Specifications for fabric filter systems for ferroalloy furnaces are shown in
                   Tables  19 and 20.  Cost data are presented in Tables 21  and 22 and Figures 19
                   and 20. This system uses an air dilution cooler preceding the fabric filter.

                       The specifications for fabric  filter systems for silicon metal furnaces using air
                   dilution coolers are shown  in Tables 23 and 24. Cost data are  presented in
                   Tables 25 and 26 and Figures 21  and 22.

                       The  specifications for fabric filter systems for silicon  metal  furnaces using
                   evaporative coolers are shown  in Tables 27  and 28. Cost data are presented
                   in Tables 29 and 30 and Figures 23 and 24.

                       The same sized silicon metal furnaces were specified for both the air dilution
                   and evaporative cooled systems. This allows  a comparison of the differences in
                   costs of the two alternative cooling methods.
62

-------
                                    TABLE 19

                      FABRIC FILTER PROCESS DESCRIPTION
                   FOR FERROSILICON FURNACE SPECIFICATION


A fabric filter is to remove particulates from the effluent  fume from a new ferrosilicon
furnace installation.  The fabric filter is to be preceded by an air dilution cooler. The furnace
is of the submerged arc type.  It is charged with raw material continuously and is tapped
intermittently on a two-hour cycle. The furnace is located inside the building and the air
pollution control system is  located on the outside.  The ductwork from the furnace hood
to the beginning of the air  pollution control system is 200 ft. long and consists of 100 ft.
of vertical and 100 ft. of horizontal duct.

The abatement system shall include the following:

1. Hoods for the capture of gaseous and particulate contaminants from the tap hole and
   ladle. The capture hood for the top of the furnace will be supplied by others.

2. All of the ductwork, connecting hoods, and abatement equipment.

3. Fans sized  with  at least 20% excess  capacity on volume and 10% excess capacity
   on static pressure. The location of the fans shall be on the inlet side of the abatement system.

4. A  mechanical collector upstream of the fabric filter and fan to  help protect the bags
   from large burning particles.

5. Compartmented  design  of  the fabric  filter to permit shutdown  of each  section for
   maintenance.

6. Sufficient capacity for operation with one compartment out of service for cleaning.

7. Bags with a temperature rating of =s500ฐF.

8. A high temperature by-pass around the fabric filter for use during operational upsets.

9. Dust hoppers and conveyors.

10.  Dust storage bins with 24-hour capacity.
                                                                                                   63

-------
                                                      TABLE 20

                                         FABRIC FILTER OPERATING CONDITIONS

                                      FOR FERROSILICON FURNACE SPECIFICATION
                     Alloy Type

                     Furnace Type
                     Furnace Size, mw
                     Product Rate, tonlhr
                     Process Weight, tonlhr

                     Gas to Collector
75% FeSi

  Open
    25
      2.84
     12.78
                         Temperature, ฐF
                         SCFM
                         Moisture Content, vo/%
                         So//ds Loading
                            grIACF
                            Iblhr
75% FeSi

  Open
    40
      4.55
    20.48
750,500
400
462,500
2.0
0.40
2,600
1,200,800
400
740,000
2.0
0.40
4,160
                     Gas from Collector
                        ACFM
                         Temperature,  ฐF
                        SCFM
                        Moisture Content, vo/%
                        So//ds Loading
                            gr/ACF
                            Iblhr
                        Collection Efficiency, %
750,500
400
462,500
2.0
1,200,800
400
740,000
2.0
      0.01
    64
    97.S2
      0.01
    103
     97.52
                     'Includes 60,000 ACFM @ 150"F from taphole hood.
                     Performance will exceed stated  efficiency. The stated efficiency represents an outlet
                     loading of 0.01 grIACF for guarantee purposes.
64

-------
                 TABLE 21

ESTIMATED CAPITAL COST DATA (COST IN DOLLARS)
 FOR FABRIC FILTERS FOR FERROSILICON FURNACE


Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
(1) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering
(b) Foundations
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup
Performance Test
Other
(4) Total Cost
Medium Efficiency
Small









































Large









































High Efficiency
Small

750,500
400
462,500
2.0

.40
2,600

750,500
400
462,500
2.0

.01
64
97.5
1,258,833
409,567







1,226,433













2,894,833
Large

1,200,800
400
740,000
2.0

.40
4,160

1,200,800
400
740,000
2.0

.01
103
97.5
1,957,350
624,647







1,901,700













4,483,697
                                                         65

-------
                                   FIGURE 19

                          CAPITAL COST OF FABRIC FILTERS
                            FOR FERROSILICON FURNACES
D
5
4
3
2
-j I06
O 9
8
8 6
5
4
3
2
I05









































































'
A












#
0











,

'











^
y
r












/COLLECTOR
COLLECTOR
X











PLUS AUXIt
ONLY













JARIES










K)5
                                3   4   5   6 7 8 9 I06

                             CLEANED GAS FLOW, ACFM
66

-------
                                           TABLE 22

                           ANNUAL OPERATING COST DATA (COST IN S/YEAR)
                          FOR FABRIC FILTERS FOR FERROSILICON FURNACE
Operating Cost Item
Operating Factor, Hr/Year-8600
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify*
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost

$6/mh
$8/mh
$6/mh

$0.011/kwh
$0.25
16% of Cat
Medium Efficiency
Small






Large






High Efficiency
Small

11,874
520
12,394
9,438
2,167
11,605
89,560
89,560
208,700
875
209,575
323,134
463,173
786,307
Large

13,188
648
13,836
13,656
3,250
16,906
143,361
143,361
334,400
1,190
335,590
509,693
717,392
1,227,085
One bidder recommended the use of a  CaCOa precoat at  a cost of $20/ton.

-------
                               COST, DOLLARS
             ro
                        (*>
                                                                         O>
o
r

C1  co
m
o  .&.

O

ฃ  ซ
>
o 
-------
                                    TABLE 23

                      FABRIC FILTER PROCESS DESCRIPTION
                   FOR SILICON METAL FURNACE SPECIFICATION


 A fabric filter is to remove particulates from the effluent fume from a new silicon metal
 furnace installation. The fabric filter is to be preceded by an air dilution cooler. The furnace
 is of the submerged arc type. It is charged with raw material continuously and is tapped
 intermittently on a two-hour cycle.  The furnace is located inside the building and the air
 pollution control system is located on the outside.  The ductwork from the furnace hood
 to the beginning of the air pollution control system is 200 ft. long and consists of WO ft.
 of vertical and 100 ft. of horizontal duct.

 The abatement system shall include the following:

 1. Hoods for the capture of gaseous and paniculate contaminants from the  tap hole  and
   ladle. The capture hood for the top of the furnace will be supplied by others.

 2. All of the ductwork,  connecting hoods, and abatement equipment.

 3. Fans sized with at least 20% excess  capacity on  volume  and  10% excess capacity
   on static pressure. The location of the fans shall be on the inlet side of the abatement system.

 4. A mechanical collector upstream of the fabric filter and fan to  help protect  the bags
   from large burning particles.

 5. Compartmented design  of the fabric  filter to  permit  shutdown  of each section for
   maintenance.

 6. Sufficient capacity for operation with one compartment out of service for cleaning.

 7. Bags with a temperature rating of =s500ฐF.

 8. A high temperature  by-pass around the fabric filter for use during operational upsets.

 9. Dust hoppers and conveyors.

10. Dust storage bins with 24-hour capacity.
                                                                                                  69

-------
                                                      TABLE 24

                                         FABRIC FILTER OPERATING CONDITIONS
                                      FOR SILICON METAL FURNACE SPECIFICATION
                     Alloy Type

                     Furnace Type
                     Furnace Size, mw
                     Product Rate, tonlhr
                     Process Weight, tonlhr

                     Gas to Collector
                        ACFM1
                         Temperature, ฐF
                        SCFM
                        Moisture Content, vo'%
                        So//ds Loading
                            gr/ACF
                            Iblhr

                     Gas from Collector
                        ACFM
                        Temperature. ฐF
                        SCFM
                        Moisture Content, vol%
                        Solids Loading
                            grIACF
                            Iblhr
                        Collection Efficiency, %
 Silicon

   Open
     15
      1.07
      5.24
450,300
    400
277,500
      2.0

      0.56
  2,160
450.300
    400
277,500
      2.0

      0.01
     39
     98.2*
 Silicon

   Open
     25
      1.79
      8.77
750,500
    400
462,500
      2.0

      0.56
  3,600
750,500
    400
462,500
      2.0

      0.01
     64
     98.2*
                     Includes 60,000 ACFM @ 150ฐF from taphole hood.
                     Performance  will exceed stated efficiency. The stated efficiency represents an outlet
                      loading of 0.01 grIACF for guarantee purposes.
70

-------
                 TABLE 25

ESTIMATED CAPITAL COST DATA (COST IN DOLLARS)
FOR FABRIC FILTERS FOR SILICON METAL FURNACE
             (DILUTION COOLING)


Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
( 1 ) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering
(b) Foundations
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup
Performance Test
Other
(4) Total Cost
Medium Efficiency
Small








































Large








































High Efficiency
Small

450,000
400
277,500
2.0

.56
2,160

450,000
400
277,500
2.0

.01
39
98.2
765,100
263,733






768,873













1,797,706
Large

750,500
400
462,500
2.0

.56
3.600

750,500
400
464,500
2.0

.01
64
98.2
1,258,633
415,200






1,231,800













2.905.633
                                                            71

-------
                                   FIGURE 21

                          CAPITAL COST OF FABRIC FILTERS
                            FOR SILICON METAL FURNACE
                               (DILUTION COOLING)
O
5
4
3
2
2 io6
o 9
8
^ 7
8 6
5
4
3
2
IO5
*

































^X
^
x
/








X
jrf
X3

y
r








^/

y
/^
























0
.
0








,


^

^











^

'










- TURNKEY SYSTEM

COLLECTOR PLUS
COLLECTOR ONL1












AUXIUARIE
1












5










                                3   4   5   6 7  8 9 IO6

                             CLEANED GAS FLOW, ACFM
72

-------
                                            TABLE m

                             ANNUAL OPERATING COST DATA (COST IN $/YEAR)
                            FOR FABRIC FILTERS FOR SILICON METAL FURNACE
                                        (DILUTION COOLING)
Operating Cost Item
Operating Factor, Hr/Year -8600
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify*
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost

$6/mh
$8/mh
$6/mh

$0.011/kwh
$0.25 M/gal
16% of Cap
Medium Efficiency
Small






Large






High Efficiency
Small

7,068
312
7,380
6,408
1,383
7,791
54,363
54,363
114,100
728
114,828
184,362
287,633
471,995
Large

11,874
520
12,394
9,486
2,167
11,653
87,947
87,947
215,800
A
875
215,675
325,669
464,901
790,570
*0ne bidder  recommended the  use of a CaCOs  precoat at a  cost of $20/ton.

-------
                                    FIGURE 22

                           ANNUAL COST OF FABRIC FILTERS
                            FOR SILICON METAL FURNACE
                                (DILUTION COOLING)
D
5
4
3
2
3 i<*
5 9
S 8
ฃ 7
8-6
5
4
3
2
io5






































A
/

/









A
X


/








J
/


/









/



/












^








/




/







/




/







TOTAL ANNUAL CO





TOTAL DIRECT CO$







ST





JT

















             I05
   3   4  5   6 7  8 9 106

CLEANED GAS FLOW, ACFM
74

-------
                                     TABLE 27

                       FABRIC FILTER PROCESS DESCRIPTION

                   FOR SILICON METAL FURNACE SPECIFICATION


 A fabric filter is to remove particulates from the effluent fume from a new silicon metal
 furnace installation. The fabric filter is to be preceded by an evaporative cooler. The furnace
 is of the submerged arc type. It is charged with raw material continuously and is tapped
 intermittently on a two-hour cycle. The furnace is located inside the building and the air
 pollution control system is located on the outside. The ductwork from the furnace hood
 to the beginning of the air pollution  control system is 200 ft. long and consists of 100 ft.
 of vertical and 100 ft. of horizontal duct.

 The abatement system shall include the following:

 1. Hoods for the capture of gaseous and paniculate contaminants from the tap hole and
    ladle. The capture hood for the top of the furnace will be supplied by others.

 2. All of the ductwork, connecting hoods, and abatement,equipment.

 3. Fans sized  with  at least 20% excess  capacity on volume and 10%  excess capacity
    on static pressure. The location of the fans shall be on the inlet side of the abatement system.

 4. A mechanical collector upstream of the fabric filter and fan to help protect the bags
    from large burning particles.

 5. An evaporative cooler to lower the temperature of the inlet gas to 400ฐF.

 6. Compartmented  design  of  the fabric  filter to permit  shutdown of each section for
    maintenance.

 7. Sufficient capacity for operation with one compartment out of service for cleaning.

 8. Bags with a temperature rating of ^500ฐF.

' 9. A high temperature by-pass around the fabric filter for use during operational upsets.

10. Dust  hoppers and conveyors.

11. Dust  storage bins with 24-hour capacity.
                                                                                                 75

-------
                                                       TABLE 28

                                         FABRIC FILTER OPERATING CONDITIONS

                                      FOR SILICON METAL FURNACE SPECIFICATION
                     Alloy Type

                     Furnace Type
                     Furnace Size, mw
                     Product Rate, tonlhr
                     Process Weight, tonlhr

                     Gas fo Gas Cooler
                         ACFM*
                         Temperature,  ฐF
                         Moisture Content, vol%

                     Gas to Collector
                         ACFM1
                         Temperature,  ฐF
                         SCFM
                         Moisture Content, vol%
                         Solids Loading
                            gr/ACF
                            Iblhr

                     Gas from Collector
                         ACFM
                         Temperature, ฐF
                         SCFM
                         Moisture Content, vol%
                         Solids Loading
                            gr/ACF
                            Iblhr
                         Collection Efficiency, %
 Silicon

   Open
     15
      1.07
      5.24
261,700
  1,100
      2.0
176,900
   400
109,000
     18.5

      0.01
     15
     99.3*
 Silicon

   Open
     25
      1.79
      8.77
436,200
  1,100
      2.0
176,900
400
109.000
18.5
1.42
2,160
294,900
400
181,700
18.5
1.42
3,600
294,900
    400
181,700
     18.5

      0.01
     25
     99.32
                     includes 60,000 ACFM @ 150ฐF from taphole hood.
                     Performance will exceed stated efficiency.  The  stated efficiency represents an outlet
                     loading of 0.01 gr/ACF for guarantee purposes.
76

-------
                 TABLE 29

ESTIMATED CAPITAL COST DATA (COST IN DOLLARS)
FOR FABRIC FILTERS FOR SILICON METAL FURNACE
           (EVAPORATIVE COOLING)


Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
(1) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering
(b) Foundations
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup
Performance Test
Other
(4) Total Cost
Medium Efficiency
Small








































Large








































High Efficiency
Small

261,700
1,100
88,900
2.0

.96
2,160

176,900
400
109,000
18.5

.01
15
99.3
326,802
203,399






394,023













924,224
Large

436,200
1,100
148,200
2.0

.96
3,600

294,900
400
181,700
18.5

.01.
25
99.3
528,163
306,217






605,170













1,439,550
                                                           77

-------
                                    FIGURE 23
                           CAPITAL COST OF FABRIC FILTERS
                             FOR SILICON METAL FURNACE
                               (EVAPORATIVE COOLING)
D
5
4
3
2
5 itf
d 9
S 8
* i
8 6
5
4
3
2
I05





Of
s^
s^
'
0X
,S
' /
/





X

a
s
S
Q
f
'






'
S^
r

y
f








/
X


s










COI

_C
-------
                TABLE 30

 ANNUAL OPERATING COST DATA (COST IN $/YEAR)
FOR FABRIC FILTERS FOR SILICON METAL FURNACE
          (EVAPORATIVE COOLING)
Operating Cost Item
Operating Factor, Hr/Year-8600
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost

$6/mh
$8/mh

$6/mh


$0.011/kwh
$0.25 M/gal
$0.05 M/gal


16% of Cap

Medium Efficiency
Small











Large











High Efficiency
Small

5,580
307
5,887

4,743
1,198
5,941
26,281
26,281
60,600
417
1,457
68,302
106,411
147,876
254,287
Large

6,606
332
6,938

6,846
1,857
8,703
40,370
40,370
100,400
583
2,209
112,030
168,041
230,328
398 , 369

-------
                                 FIGURE 24

                        ANNUAL COST OF FABRIC FILTERS
                         FOR SILICON METAL FURNACES
                            (EVAPORATIVE COOLING)
D
5
4
3
2
3 io6
d 9
2 8
te" I
8 6
5
4
3
2
IO5
1C












X
of











X
r
/










/

^
/













































TOTAL ANNUAL COST


TOT



ALDII



IEC



C<



81

























































D5 2 3456789 IO6 2 34
                            CLEANED GAS FLOW, ACFM
so

-------
                               REFERENCES
1.   Annual Statistical Report  1972, American  Iron  and Steel Institute, 1973,
     Washington, D.C., p. 48.

2.   Person, R. A.,  "Emission Control  of  Ferroalloy  Furnaces",  Fourth  Annual
     North Eastern Regional Antipollution Conference, 1971.

3.   Bocey, John L, Ferrous Process Metallurgy, John Wiley & Sons, Inc., NYC,
     1954, pp. 149-153, 278, 351-355.

4.   Rex  T. Hooper, "The  Production of Ferromanganese", Journal of  Metals,
     May, 1968.

5.   Schofield,  M., "Industrial Silicon and Ferrosilicon", Metallurgia,  July, 1967.

6.   Sully, A. H., and Brandes, E. A., Metallurgy of the Rare Metals — Chromium,
     Plenum Press, 1954, NYC, pp. 19-25.

7.   Air  Pollution Control  Technology  and  Costs  in  Nine  Selected Areas,
     Industrial Gas Cleaning Institute, Inc., 1972,  pp. 349-396.

8.   Elyutun, V. P., et al.,  Production of Ferroalloys, Electrometallurgy, Moscow,
     1957, pp. 23-69, 108-137, 158-221.

9.   Person, R. A., "Control of Emissions from  Ferroalloy Furnace Processing",
     Journal of Metals, April, 1971.

10.  Ferrari, Renzo,  "Experiences  in Developing an  Effective  Pollution  Control
     System for a Submerged Arc Ferroalloy Furnace Operation", Journal of Metals,
     April,  1968.
                                                                                          81

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3.   GRAIN CLEANING HOUSES

     For centuries, grain has been an important food source for both man and
animals. This importance is still apparent today, with world-wide  annual grain
production now in  excess of 1.3 billion metric tons, nearly 300 million metric tons
of which are grown in North America. Table 31 shows a breakdown of this production
by grain type.1 Two factors which  account for the  wide use of grain  as a food
source are ease of growing,  and storage stability.

     Milling of grain into flour and other products is an important industry throughout
the world. Originally, milling was done in  the home. Millstones were  highly valued
household articles,  being passed on from generation to generation. Gradually, custom
milling came  into  existence,  and it has  developed  into the large complex grain
milling industry of today.

     The milling process involves many steps, of which the following are among the
more important. Grain is  received at the  mill, given a  cursory cleaning to remove
large objects  such as sticks, rocks, pieces of  metal, and cloth, and is  then sent
to storage. As needed, it  is withdrawn, and given a much more thorough cleaning,
including removing small stones, sticks,  bits of  metal, foreign seeds, chaff, and
dirt.  The grain is then "tempered" by the addition of the right amount of moisture
to enhance milling properties.  Sometimes, heat is also added, in which case the
process is called "conditioning". The  grain is  then  ground  into finished  product
and conveyed to storage where it awaits distribution.

     Because the quality of the finished product is dependent largely upon the cleanli-
ness of the grain, grain cleaning is an important step in the milling process. However,
the cleaning of grain generates by-products which could result in environmental
problems.  This report will focus on  the grain cleaning process and  will include a
discussion of  the process,  by-products, pollution control  equipment, and related
capital and operating costs.
                          PROCESS DESCRIPTION

     Figure 25 shows  a typical layout configuration for a grain cleaning house2.
Grain is withdrawn from a storage bin as needed, usually on a continuous basis,
and conveyed to the grain cleaning  house.  Several methods of conveyance  are
used, with screw, belt,  bucket, and pneumatic conveyors being the most popular.
These methods are used throughout the mill. The grain is weighed and sent to a
separation device, such as an oscillating  inclined sieve which is called a scalper.
Here, dirt, dust,  small pebbles and sticks, and other small objects are separated
from the grain.  During  scalping,  the grain  passes over sets of air jets, called
                         Preceding  page blank
                                                                                           83

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                                               TABLE 31

                                      ANNUAL GRAIN PRODUCTION
                                              STATISTICS1
             REGION
              Year

             All Cereals, mmt(*)

             Wheat, mmt

             Rice, mmt

             Maize, mmt

             Barley, mmt
        WORLD

 1969    1970     1971

1195.6    1203.5   1305.7

 315.6    316.7    340.2

 294.9    305.8    508.9

 264.8    259.7    307.9

 137.1    138.5    152.1
   NORTH AMERICA
1969     1970     1971

239.8     215.4    275.6
 58.4
  4.1
46.5      58.5
 3.8
3.8
118.3     107.0    143.6
 17.5
18.0      24.5
            •Millions of metric tons
84

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         CLEANED
         GRAIN TO
         MILLING
         PROCESS
                      WEIGHING
     JET

OSCILLATING INCLINED
        SIEVE

     (SCALPER)
                                                 WATER
                                                   i
                                                                  ,   ASPIRATOR  N
                                                                  (ONE OF SEVERAL)
_pi^r_a	|
1BEESWING ~~  WATER
A              i*ซ
                                                          .
                                                        J
                                ROTATING
                                DISC
                                PLATE
                                (ONE OF
                                 MANY)
                                                         DISC
                                                         SEPARATOR
                                      WASTE
                           AIR
                          EXCESS WATER
                           CENTRIFUGE
         FINAL WASH
SCOURER
PREWASH
         Figure 25. Flow  diagram for Grain Cleaning  House
00
en

-------
                  aspirators, located in the scalper. These aspirators dislodge very light objects of
                  large surface area, i.e., wheat chaff, without disturbing the grain. These scalpers
                  are similar to those used at grain elevators and terminals where the grain is first
                  brought  by farmers, but have a smaller screen  size. Scalpers at elevators and
                  terminals are used solely for removal of large objects from the grain such as rocks,
                  large sticks, pieces of iron, rags, and so on. This process could be classified as
                  grain cleaning, but will  not be the principal process studied here.  Instead,  this
                  report will focus on the grain cleaning process used just prior to grain milling.

                      Next, ferrous metal pieces still remaining in the grain are removed by magnets.
                  This metal could cause serious damage to mill rolls  if it were not removed. The
                  grain is  then conveyed through one or more aspirating devices. Like those used
                  in the initial scalping step, these devices utilize air jets to remove dust particles,
                  dirt, and chaff. Since no aspirator is 100% efficient, several are used to assure as
                  complete a separation as possible.

                      The grain then goes  to a disc separator. The main feature of  this machine
                  is its unique set of rotating discs. Each disc contains many specially designed
                  grooves  or  pockets which trap and lift away foreign seeds, such as weed seeds,
                  while allowing the grain to pass  unhindered.  Different plates are  used to trap
                  different  kinds of  seeds. The  discs are  positioned at right angles to the flow of
                  grain and the machine is designed so that  grain may be withdrawn  at any point.

                      From  here, the grain  passes on to a scourer.  This machine  removes  dirt
                  from the surface of the wheat by  friction. Designs vary, but usually the wheat is
                  pushed against a hard emery surface by paddles, the severity of the operation
                  being controlled by the clearance between the paddles and  the emery surface.
                  Scouring is often preceded by a light pre-wash to help toughen the grain and prevent
                  it from being broken during the scouring process. Dirt  and pieces of the  outer
                  coating of the wheat bran called beeswing generated during the scouring process
                  are removed by air aspiration in the same way as outlined above.

                      The last cleaning operation performed on the grain is a water wash. The water
                  removes any dirt still remaining on the grain and acts as a final separating device
                  for any stones or bits of metal which may have remained throughout the cleaning
                  process.  Again, designs vary,  but  usually the grain is conveyed through a trough
                  of water. The dirt is floated away,  and the  metal and small stones  sink.  Excess
                  water is  removed from the grain by centrifugal action and the wheat is sent to
                  the mill for grinding.
                                   NATURE OF THE PARTICULATE EMISSION

                      The discharge from a grain cleaning house consists of dust and other particles
86

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developed during the cleaning process or carried in as dockage, as shown in Table
32. Dockage is defined as that material in the grain which is of no use and must
be removed. This includes chaff,  dirt, sticks, stones, cloth, paper, insect  debris,
foreign seeds, and so on. Any of these materials, if fine enough, will yield air-borne
dust upon agitation  of the grain. Since the  cleaning process, by its very  nature,
agitates the  grain vigorously, much dust is released in the process. Table 33 lists
some of the  properties of the dust emitted during the cleaning process. The quantity
of dust generated depends, of course, upon the size of the operation and upon
such  factors as grain type, quality, and the amount of dockage present. As is
to be expected, different pieces of  equipment in the cleaning process emit different
concentrations of dust. However, usual practice is to duct the individual dust sources
to a common dust collector. Based on emission test measurements in about 600
grain cleaning operations, average emission estimates from various kinds of grain
cleaning equipment  have been made. These emissions,  measured as dust  load to
the control device,  range from a  high of 9.9  gr/SCF from the  scourer in an air
volume of 2350 ACFM to a low of 1.45 gr/SCF from the wheat cleaning separator
in an air volume of 8,000 ACFM. Other pieces of equipment tested were  the scalper
and the wheat cleaning aspirator  which  had dust loads of 3.2  and 2.32 gr/SCF
in an average of 2,950 ACFM  and  5,000 ACFM, respectively.

     In addition to the common dust collector operation, some pieces of equipment,
such as the aspirator, operate on a closed system basis. The  same  air  is used
repeatedly, cleaned  and recirculated, and never escapes to the atmosphere8.  This
report will focus on equipment which is not of the closed  system type.
                 POLLUTION CONTROL CONSIDERATIONS

     The two types of pollution control equipment most commonly used in conjunction
with grain cleaning operations are fabric filters and cyclones.

     As mentioned above, common practice is to provide a dust collection system
common to many pieces of equipment. Therefore, the cleaning house may be served
by  a single appropriately sized  fabric filter or  bank of cyclones. To  keep dust
emissions to a  minimum, machines are usually closed to the atmosphere  and
under negative  pressure  so  that  dust generated in the cleaning process is kept
within the machine and carried by the ductwork to the collection system.

     Both cyclones and fabric filters are in wide use in the feed and grain industry.
Table 34 shows a comparison of these two  types of control devices. Where com-
pliance with  relevant  codes can be achieved with cyclones, economics will dictate
their use. However, cyclones have limited efficiency capability and cannot achieve
compliance in all cases. Where cyclones cannot be  used, fabric filters are the most
common control device  employed. Fabric filter  efficiencies  are, in most cases,
                                                                                         87

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                                              TABLE 32
                         CONTAMINANTS GENERATED DURING GRAIN CLEANING
                                       Operation




                                       Inclined Sieve




                                       Aspirator




                                       Disc Separator




                                       Scourer




                                       Conveyors
Type of Contaminant Generated




Dust, dirt, chaff




Dust, dirt, chaff




Foreign seeds, dust




Dirt, beeswing




Dust
88

-------
                               TABLE 33

                 PROPERTIES OF DUST EMITTED FROM
                    GRAIN CLEANING OPERATIONS
Particle Size



Dust Concentration

Specific Gravity


Temperature

Moisture Content of Dust
Ranges3 from V to 1000/z
Larger particles such as chaff and insect debris
may also be present

Ranges4 from about 1 to 10 gr/SCF

1.8 for both  the primary cyclone and secondary
fabric  filter catch

Ambient

Moisture content of the air due to ambient relative
humidity
                                                                                   89

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                                                  TABLE 34

                              RELATIVE ADVANTAGES AND DISADVANTAGES OF
                                      CYCLONES AND FABRIC FILTERS
                   Unit

                   Fabric Filters
         Advantages
       Disadvantages
1.  High single unit efficiency.    1. High  maintenance  cost,
                              i.e., bag replacement.

2.  With the right filter fabric,    2. High first cost.
   efficiencies  remain  high
   for small particles.
                   Cyclones
1.  Low first cost.
1.  Single  unit efficiencies
   tow especially for small
   particles,  requiring cas-
   cading.
                                   2. Low maintenance  cost.
90

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more than adequate to achieve compliance with all applicable codes.
                       SPECIFICATIONS AND COSTS

     Specifications  have been written for fabric filter systems to collect the dust
emitted from the operations of  both a  small  and a large grain cleaning  house
processing wheat. The fabric filter is specified  to treat a single air exhaust stream
which has been ducted from the hoods of the  following grain cleaning operations:

          1.  Scalping
          2.  Aspiration
          3.  Disc  separation
          4.  Scouring

     Equipment specifications are shown in Tables 35 and 36 and cost data for the
systems are shown in  Tables 37 and 38 and Figures 26  and 27. The  bidders
specified different but standard fabric filter materials and  average  air to cloth
ratios of about 10/1  for both small and large sized operations, respectively.

     To minimize the explosion hazard associated with grain cleaning operations,
a  number  of fabric filter  safety features were considered.  Explosion vents are
standard on all grain house fabric filters and are included in the gas cleaning device
cost.  While spark proof fan wheels are sometimes used to minimize explosion
danger, they are not normally required since they are on the clean air side of the
fabric filter. Consequently, this feature was not  included in the bids.
                                                                                          91

-------
                                                      TABLE 35

                                        FABRIC FILTER PROCESS DESCRIPTION

                                     FOR GRAIN CLEANING HOUSE SPECIFICATION
                   A fabric, filter system is to treat the dust emitted from the grain cleaning operations in a
                   grain cleaning house. These cleaning operations include the following:

                        1. Scalping

                        2. Aspiration

                        3. Disc Separation

                        4. Scouring

                   The  hoods from all of these operations are to be ducted together to provide a single
                   common air exhaust stream which will be treated by the fabric filter.

                   The  vendor is to furnish a pulse-type fabric filter unit, hoppers equipped with rotary air
                   locks, required  booster fan, and all controls. The vendor is also  to supply the required
                   hoods and ductwork in accordance with the information shown below:

                   A.  Small (227 bulhr) plant.

Operation
Scalping
Aspiration
Disc Separation
Scouring
Ventilation Rate
ACFM
4,000
6,000
2,000
3,000
Hood Area
ft*
16
24
8
12
Duct Velocity
fpm
3,500
3,500
3,500
3,500
                                                      15,000
 60
                   B.  Large (758 bulhr) plant.
Ventilation Rate
Operation
Scalping
Aspiration
Disc Separation
Scouring
ACFM
12,000
18,000
6,000
9,000
Hood Area
ft2
48
72
24
35
Duct Velocity
fpm
3,500
3,500
3,500
3,500
                                                       45,000
180
                   All common ductwork will be designed for a velocity of 3,500 fpm.
92

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                                 TABLE 36
                    FABRIC FILTER OPERATING CONDITIONS
                 FOR GRAIN CLEANING HOUSE SPECIFICATION
Cleaning House Capacity, bu/hr
Cleaning House Process Weight, Ib/hr
Adjacent Flour Mill Capacity, cwt/day

Inlet Gas to Fabric Filter
    ACFM
    Temperature,  ฐF
    SCFM
    Solids Loading
       gr/ACF
       Ib/hr
Outlet Gas from Fabric Filter
    ACFM
    Temperature,  ฐF
    SCFM
    Solids Loading
       gr/ACF
       Ib/hr
    Collection Efficiency
 Small
  227
12,500
 2,400
    0.01
    1.29
   99.6
 Large
   758
41,700
 9,000
15,000
75
14,900
3.02
388
15,000
75
14,900
45,000
75
44,600
3.32
1,281
45,000
75
44,600
    0.01
    3.86
   99.7
                                                                                        93

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                                     TABLE 37

                    ESTIMATED CAPITAL COST DATA (COST IN DOLLARS)
                     FOR FABRIC FILTERS FOR GRAIN CLEANING HOUSE


Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
(1) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering
(b) Foundations
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup
Performance Test
Other
(4) Total Cost
Medium Efficiency
Small









































Large









































High Efficiency
Small
15,000
75
14,900



3.02
388
15,000
75
14,900



.01
1.29
99.6
12,364

4,537




1,821

28,825













47,547
Large
45,000
75
44,600



3.32
1,281
45,000
75
44,600



.01
3.86
99.7
29,493

12,910




3,212

62,030













107,645
94

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                             FIGURE 26

                   CAPITAL COST OF FABRIC FILTERS
                     FOR GRAIN CLEANING HOUSE
    6

    5

    A
    10*
    8
V'
    4
                                        TURNKEY SYSTEM
COLLECTOR PLUS AUXILIARIES
                                          COLLECTOR ONLY
    10
                          3   A  5   6  7 8 9 I05

                       CLEANED GAS  FLOW, ACFM
                                                                          95

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                TABLE 38

   ANNUAL OPERATING COST (COST IN S/YEAR)
FOR FABRIC FILTERS FOR GRAIN CLEANING HOUSE
Operating Cost Item
Operating Factor, Hr/Year -4000
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost


$6/mh
$8/mh


$6/mh





$0.011/kwh






16% of Cap

Medium Efficiency
Small




















Large




















High Efficiency
Small


None


1,068
125
1,193
775
775

1,142




1,142
3,110
7,608
10,718
Large


None


1,410
150
1,560
1,575
1,575

2,876




2,876
6,011
17,223
23,234

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                         FIGURE 27

               ANNUAL COST OF FABRIC FILTERS
                 FOR GRAIN CLEANING HOUSE
 6

 5

 A
                                    TOTAL ANNUAL COST
10*
 9
 8
 7
 6
to
8
                                        TOTAL DIRECT COST
IOJ
  10*
                          3   A   5  6  7 8 9 I05

                       CLEANED GAS  FLOW, ACFM
                                                                       97

-------
                                                REFERENCES
                 1.   Monthly Bulletin of Agricultural Economics and Statistics. Food and Agriculture
                      Organization of the United Nations - Rome, Vol. 20, Dec., 1971, p. 16.

                 2.   Matz, Samuel A., Cereal Technology, AVI Publishing Co., Westport, Connecti-
                      cut, 1970, pp. 5-6.

                 3.   Environmental Controls for Feed Manufacturing & Grain Handling. American
                      Feed Manufacturers Association, Chicago, III. 1972, p. 7.

                 4.   Engineering and Cost  Study of  Emission Control in the Grain and  Feed
                      Industry. EPA Contract 68-02-0213, 1973, pp. 3-45.

                 5.   Air  Pollution Engineering Manual.  U. S.  Department of  Health, Education
                      and  Welfare, Public Services Publication No. 999-AP-40, Cincinnati,  Ohio,
                      1967, p. 356.

                 6.    Stern, Arthur C.,  Air Pollution.  Vol. Ill,  Second  Edition,  Academic Press,
                      New York, 1968, p. 277.

                 7.    Engineering and Cost Study of Emissions Control in the Grain and  Feed
                      Industry, EPA Contract 68-02-0213, 1973, pp. 3-130.

                 8.    Lockwood,  Joseph,  Flour  Milling, Henry  Simon  Ltd.,  Stockport Cheshire,
                      England, 1960, p. 148.
98

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4.   GLASS-MELTING FURNACES

     Glass is an inorganic  product of fusion  which has been  cooled  to a  rigid
condition without crystallizing. Commercial glasses  are  produced from inorganic
oxides, of  which silica,  or  sand,  is usually an important constituent.  Glass is
made  by heating a mixture of dry materials to about 2800ฐF  in  a  refractory
container.  The  heating  is  continued  until a viscous, homogeneous  liquid is
formed. By varying the proportions of the raw materials, glasses can be produced
with physical  and chemical properties which vary over wide ranges.

     Glasses are mixtures rather than compounds of various oxides. The common
oxides in glass  are  classified as formers, stabilizers and fluxes. Only a limited
number of chemical compounds are capable  of forming the three-dimensional
random  atomic  structure characteristic  of  glass.   The common glass formers
are  the  oxides  of silicon (SiOz),  boron (8203), and phosphorous (PaOs).  The
melting point  and working  temperature  of  the mixture are  lowered by adding
fluxes, which  decrease  the  viscosity of  the  mixture. Stabilizers  are  added to
improve chemical durability and/or to prevent crystallization.

     About 700  different  types of glasses are  produced commercially each year.
Of these glasses, a small  number are  produced in great volume because  they
have good all-around  usefulness. These glasses,  which comprise  the  bulk of
commercial production, are  commonly  classified in  the  following  chemical types
of silicate glass:

     1. soda-lime glass
     2. lead glass
     3. borosilicate glass
     4. 96 percent silica  glass
     5. 99.8 percent silica glass, i.e., fused quartz or fused silica.1

     The composition  ranges of these commercial  types are given in  Table 39.
Soda-lime glass  presently  constitutes  about 90 percent of the total production
of commercial glass.3

     Non-silicate  glass forming systems are  used  to a much lesser extent.
For  example, phosphate glasses  are  used  as   high temperature  lubricants;
iron  glasses  are used in heat-absorbing applications;  and borate glasses  are
used in sodium vapor lamps.

     Other types of silicate glasses, such as colored, opal, and optical, are usually
made  from the  five basic  types  of silicate glass  listed  in  Table 39. Colored
glasses are generally  made by adding  traces of  metallic oxides to the  batch,
plus proper  heat treatment of the finished   glass.  Opal  glasses, which  are
                                                                                        99

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                                          TABLE 39

                      APPROXIMATE COMPOSITIONS OF COMMERCIAL GLASSES1
                           Soda-lime     Lead    Borosilicate  96% Silica  99.8% Silica
                                                 Wt%	    Wt%      Wt%
Si02
Na2O
K2O
CaO
PbO
B2O3
AI2O3
MgO
ป W I /W
70-75
12-18
0-1
5-14
—
—
0.5-2.5
0-4
w • ป /w
53-68
5-10
1-10
0-6
15-40
—
0-2
—
73-82 96 99.8
3-10
0.4-1
0-1
0-10
5-20 3
2-3
—
100

-------
translucent silicas of various colors, capable of refracting light and then reflecting
it in a play of colors, are usually made by  adding  fluorides or phosphates to
the batch.  Optical glasses are made in  a variety of compositions. In general,
the chemical composition of other types of glasses  does not vary significantly
from that of the five basic types.

     Over 5,000,000 tons of glass sand are used in the United States each year
in order  to produce  all  of  these various glasses. To flux  this silica requires
over 1,500,000 tons  of  soda ash,  113,000 tons of  salt cake  (impure  sodium
sulfate, 90 to 99%), and 875,000 tons of limestone or equivalent lime.5

     Sand  for glass  manufacture should be almost  pure quartz.  The location
of glass factories  is frequently determined by the location of glass-sand deposits.
Soda, NazO, is supplied mainly by  dense  soda ash, NazCOa. Other sources
are sodium bicarbonate, sodium sulfate, and sodium nitrate. The primary sources
of lime, CaO, are limestone and burnt lime from dolomite.

     The  chemical reactions  involved in making glass may  be  summarized
as follows:5

                   NazCOs  + aSiO2  -ป Na2O • aSiOz + CO2                 (1)
                   CaCOs  + bSiOz  -ป CaO • bSiOz + COz                 (2)
                     +  cSiOz + C -> NazO • cSiOz + SOz + CO            (3)
The last reaction may take place as in equations (4) or (5), and (6):

                       Na2SO4 + C -ป NazSOa + CO                     (4)
                      2Na2SO4 + C -ป 2Na2SO3 + COz                    (5)
                   NazSOa + cSiOz -ป NazO • cSiOz + SOz                 (6)

     The  ratios NazO/SiOz   and CaO/SiOz  need  not  be  1  to  1  molecular
ratios. In ordinary window glass the molecular ratios are approximately:

            2 mots NazO/5 mols SiOz and 1 mole CaO/5 moles SiOz

Other glasses vary widely.5
PROCESS DESCRIPTION

     There are two basic steps in the manufacture of glass. They are:

     1.  The melting of sand and stabilizing oxides to form molten glass
     2.  The fabrication of this molten glass into useful articles

     In  the  first  step,  sand  and  other  raw  materials  are  procured and
                                                                                       101

-------
                 stored  in  sufficient quantities  to  permit  continuity  of operation.  These
                 materials  are  accurately  weighed  in  correct  proportions to  yield  glass  of
                 the desired composition. Then they are thoroughly mixed  and  fed into the
                 melting  furnace.  In the  melter the raw  materials are  heated  to  a  higher
                 temperature until chemical reactions  which liberate carbon dioxide,  water, and
                 other  gases are completed,  and the bubbles thus  formed are eliminated. The
                 glass  is cooled,  before leaving the melting unit,  to  bring  its viscosity  to a
                 value that is suitable for the particular  forming operation to be used. Table 40
                 presents the useful  range of glass  viscosities with regard to its use in  a particular
                 manufacturing operation.

                      Fabrication of  the  molten glass  may involve such  operations as  pressing,
                 blowing, rolling  or  drawing.  After  the  glass  is formed  to  a  particular
                 shape,  the  article   passes  through  an  annealing oven to  reduce  internal
                 stress.
                      Secondary, or  finishing, operations such as  grinding,  polishing, cutting
                 and  chemical  treatment are  frequently performed  on  the  fabricated articles.
                 In  most instances, such operations  are separated from the primary fabrication
                 operations and sometimes occur in a plant of an entirely different organization.

                      The factors involved in the selection of sand, and other materials as well,
                 are purity, cost, and  grain size. The  principal ingredients used for manufacturing
                 soda-lime  glass are  sand,  soda ash, and limestone. Other materials  frequently
                 used  in  glass  production  are  borax,  boric  acid,  litharge,  potash,  fluorspar,
                 zinc oxide, and barium carbonate. Table 41  lists several of the raw  constituents
                 of glass and their glassmaking equivalents.

                      Most  glass  is  melted  by a  continuous   process in  tanks  made of
                 refractory  blocks  and  heated from above by   the  flames of  burning  fuel.
                 Batch or  day  tanks are  used  for  small  amounts of  glass,  having  special
                 composition and properties. The batch  type units reach  sizes of  a  few tons
                 in holding  capacity, while continuous tanks range  from less than a ton to  1500
                 tons capacity, with outputs up to several hundred tons of glass per day.

                     Continuous  tanks for  melting  glass  are  generally rectangular in
                 shape  and  are divided  into  two  compartments  by  a permanent wall or
                 by  floating  refractory  baffles.  The batch  of well-mixed  raw  materials is
                 introduced  into the   larger compartment  known  as  the melting  end.   The
                 other  compartment,  known as  the  working  or  refining end,  is  where  the
                 glass is cooled and distributed for use.

                     In  the melting  end  of  the  tank,  the  batch  is heated  until  the
102

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                    TABLE 40

     USEFUL RANGE OF GLASS VISCOSITIES1


      Operation                           Viscosity. Poises


Melting                                         102

At Automatic Feeder                          103 -10"

For hand gathering                              103-2

Gather when placed in paste mold                 ~\Q*'5

Ware removed from paste mold                    107

Annealing                                   1013 -1013-5

At maximum service temperature              1014-6 -1015-5
  (Temperature at which glass is substantially rigid)
                                                                         103

-------
                                        TABLE 41
                                GLASSMAKING MATERIALS1
Raw Material
Sand
Soda Ash
Limestone
Dolomite

Feldspar


Borax

Boric Acid
Litharge
Potash
Fluorspar
Zinc Oxide
Barium Carbonate
Chemical
Composition
SiO2
Na2CO3
CaCOa
CaCOa-MgCOa

K2(Na2)O-AI2O3-6SiO2


Na2B4O7-1OH2O

B2O3-H2O
PbO
K2CO3-1.5H2O
CaF2
ZnO
BaCO3
Glassmaking
Oxide
SiO2
Na2O
CaO
CaO
MgO
AI203
K2(Na2)O
Si02
Na2O
B203
B2O3
PbO
KizO
CaF2
ZnO
BaO
Percent
Oxide
100.0
58.5
56.0
30.4
21.8
18.0
13.0
68.0
16.3
36.5
56.3
100.0
57.0
100.0
100.0
77.7
104

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fluxes melt  and  dissolve  the sand and other  ingredients.  Carbon  dioxide
and water, as  well  as air trapped in  the interstices  of the batch, produce
many  bubbles  so  that when  first  melted,  the  glass  is  a  foamy  mass.
Most  of  these  bubbles  are  eliminated  at the  high  temperature  of the
melting  end. Convection  currents, which  arise in  the glass  through the
heating of  the  flames  and cooling by  side  walls  and cold batch, help  to
make  the melt  homogeneous by  a stirring  action. The molten glass from
the  melting  end  passes  through  a  hole,  or throat,  in  the wall,  or  under
the  floating  refractory  baffles.  This  serves  to  skim off  foam  or  scum
on the surface of the molten glass.

     In the  refining  end of the  tank, the  glass  is  cooled  until its  viscosity
has increased to the proper  value for  fabrication. In mechanized operations,
the glass  flows from  the refining  end to the forming equipment in  refractory
channels termed "forehearths." The final cooling  takes place in the forehearths,
the construction of which vary depending upon the kind  of forming machine  to
be supplied. A  flow  diagram for  soda-lime glass manufacture is  presented  in
Figure 28.

     Systems for batch mixing and conveying of  materials for making  soda-lime
glass normally use commercial equipment of standard design. This  equipment
is  generally  separate  from  the  glass-melting furnace and  is  commonly
referred  to as  a  "batch  plant."  A  flow  diagram  of  a  typical batch  plant
is shown  in  Figure  29. Major raw materials  and cullet  (broken  scrap  glass)
are  conveyed  to the  elevated  storage  bins  from   railroad  hopper  cars  or
hopper trucks  by  a  combination  of screw conveyors,  belt  conveyors,  and
bucket elevators.  Minor  ingredients are  usually  delivered in  cardboard
drums and transferred  by  hand  to small bins.  The  ingredients for a given
batch  are dropped  from  the storage   bins  into  weigh  hoppers  and then
released  into the  mixer.  Cullet  is  ground and then  mixed  with  the other
ingredients in the  mixer.  These  materials  are  blended  for  3 to 5 minutes
and then  transferred  to  a  charge  bin  located  near  the  melting  furnace.
The blended  material is fed  into the furnace feeders  through  rotary  valves
located at the bottom of the charge bin.

     Glass-melting  furnaces  for  soda-lime glass  are  generally direct-fired,
continuous,  regenerative  furnaces.  They  usually range in capacity from  50
to 300 tons  of glass  per  day.  The most  common  capacity  found  in  the
United  States  is 100  tons  per  day.3  Regenerative  firing  systems consist
of dual chambers filled with  brick  checkerwork. Combustion  air is  preheated
in one chamber, while  the  products of combustion  from  the  melter  pass
through  and  heat  the  opposite  chamber.  By  reversing  the  flow  of air
and  combustion  products,  the functions  of each  chamber are  interchanged.
This occurs every 15 to 20 minutes  in order to maximize heat conservation.
                                                                                        105

-------
o
O>
                SILICA  SAND
                Si02ป99%
            TO YIELD  SILICA,
            Si Oo .SANDSTONES
           (IN PA..W. VA..ILL.,
            MO.) ARE  CRUSHED,
            WASHED,  SCREENED
            TO  APPROX. 20-100
            MESH
            Fe2 03 
-------
       GULLET
        SFfET
 MAONETC
[SEPARATOR
       CRUSHER
RAW MATERIALS
RECEIVING
 HOPPER
         CONVEYOR
                         STORAGE BINS
                       MAJOR RAW MATERIALS
                                          MINOR
                                         MGREDIENT
                                          STORAGE
                                                        \.
                                                            Y
                                                              I

                                                           BATCH
                                                           STORAGE
                                                           BW|

                                                              I
                                                            FURNACE
                                                             FEEDER
                                                                  GLASS
                                                                 MELTING
                                                                 FURNACE
                               FIGURE 29
               PROCESS FLOW DIAGRAM OF A BATCH PLANT3
                                                                                 107

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                  In order to prevent air induction and a subsequent loss in combustion efficiency,
                  continuous furnaces  are  usually operated slightly  above atmospheric pressure.
                  Furnace draft is produced by induced-draft fans, natural-draft stacks,  or ejectors.
                  NATURE OF THE GASEOUS DISCHARGE

                  Melting Furnaces

                       The major source of air contaminants from a glass plant is the glass-melting
                  furnace. An  estimate of national pollutant emissions  from  glass furnaces based
                  upon production in  1971  is presented in Table 42. During the melting process,
                  carbon dioxide bubbles form  and propel particulates  from the melting batch.
                  These  particulates  are entrained  by  the  fast-moving  stream of  flames and
                  combustion  gases.  Once  swept from  the  melter,  they are either  collected  in
                  the checkerwork and gas passages or exhausted to the atmosphere. Paniculate
                  emissions are  also  formed due to the condensation  of certain  components
                  which were volatized in the glass melt.

                       Many source tests of glass furnaces in Los Angeles County were studied to
                  determine the  major variables  which influence stack emissions,  and this data is
                  summarized  in Table 43.  Paniculate samples  were  obtained from the catch of a
                  pilot fabric filter which vented part of the effluent from  a large soda-lime container
                  furnace,3 and  panicle  size distributions  of two  typical  samples are shown  in
                  Table 44. Additional panicle size  distributions from a  separate  study of two
                  side-port, regenerative, gas-fired furnaces are presented in Figure 30. Flue gas
                  conditions and compositions during  sampling for these additional tests are shown
                  in Tables 45  and 46.

                      The chemical  compositions of five  separate paniculate samples, four from
                  a pilot fabric filter, and one from the stack  of a soda-lime regenerative furnace,
                  are presented  in Table 47. These samples  were found to be composed mostly
                  of alkali sulfates although alkalies are reported as oxides.

                      Opacity of  stack  and paniculate  emissions did not correlate very  well,
                  based on the source test data presented in Table 43. However, some generalizations
                  on opacity can  be made.

                      1.   Opacity increased directly with paniculate loading
                      2.   Furnaces burning U. S. Grade  5 fuel  oil usually  have plumes exceeding
                          40% opacity.
                      3.   While burning natural gas or U. S. Grade 3 fuel oil, however, the plumes
                          from these same furnaces are only 15 to 30 percent white opacity.
108

-------
                 TABLE 42




ESTIMATED NATIONAL EMISSIONS, 1971 (TONS)




            GLASS FURNACES4









         Sulfur Oxides           1,675




         Nitrogen Oxides         1,125




         Carbon Monoxide        2,350




         Fluorides                275




         Paniculate Matter        26,250
                                                                  109

-------
                                              TABLE 43
                          SOURCE TEST DATA FOR GLASS-MELTING FURNACES*


Test No.

C-339b
C-339
C-382-1
C-382-2
C-536
C383
Pri-Lab
Pri Lab
PriLab
Pri Lab
PriLab
Pri Lab
Pri Lab
C-101
C-120
C-577
C-278-1
C-278-2
C-653
C-244-1
C-244-2
C-420-1
C-420-2
C-743
C-471

Type
of
Furnace*
EP
EP
EP
EP
EP
EP
EP
EP
EP
EP
EP
EP
EP
EP
EP
SP
SP
SP
SP
SP
SP
SP
SP
SP
SP

Type
of
Fuel"
0-300
G
G
G
0-200
G
G
G
G
G
G
0-300
G
G
G
0-300
G
0-300
G
G
G
G
G
G
G
Xi
(paniculate
emissions),
Ib/hr
7.00
3.00
4.60
6.40
4.70
8.40
3.86
4.76
4.26
6.84
4.62
3.96
7.16
9.54
9.90
12.70
3.97
8.44
8.90
6.30
3.00
6.30
6.60
10.20
6.70
X2
(process wt ratio),
Ib/hr ft2
of Metier Area
16.7
13.8
16.5
18.2
17.5
17.9
10.9
14.6
17.1
17.4
18.5
14.6
20.2
15.2
14.2
24.2
18.3
18.5
22.0
7.5
5.4
10.7
13.2
26.2
11.6
X3,
X4
Maximum
wt fraction (checker volume), Opacity
of cullet in
Charge*"
0.300
0.300
0.300
0.300
0.199
0.300
0.094
0.094
0.157
0.094
0.365
0.269
0.175
0.300
0.320
0.134
0.361
0.360
0.131
0.182
0.100
0.100
0.100
0.047
0.276
ftW
of Melter
5.40
5.40
5.40
5.40
5.40
6.50
8.00
8.00
8.00
8.00
9.00
9.00
9.00
5.00
5.00
6.90
6.93
6.93
8.74
7.60
7.60
7.60
7.60
8.25
5.60
of Stack
Emissions, %
50
10
10
10
10
20
25
25
25
25
—
45
20
20
20
35
20
20
40
25
25
10
5
25
30
     *EP = end port, regenerative furnace; SP = side port, regenerative furnace.
    "G = natural gas; 0-200 = U.S. Grade 3 fuel oil; 0-300 = U.S. Grade 5 fuel oil.
    "Constants: Sulfate content of charge 0.18 to 0.34 wt %.  Fines (-325 mesh) content of charge 0.2 to 0.3 wt%.
110

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                 TABLE 44
SIZE DISTRIBUTION OF PARTICULATE EMISSIONS3
          (Mlcromerograph Analyses)
Furnace 1
Diameter (D),
M
36.60
22.0
18.30
16.50
14.60
12.80
12.20
11.60
11.00
10.40
9.80
9.20
8.50
7.30
6.10
4.88
3.66
3.05
2.44
1.83
1.52
1.22
— Flint Glass
% (by wt)
Less Than D
100
99.5
98.6
97.7
94.0
84.6
80.7
76.6
72.7
67.7
• 62.4
58.3
51.8
43.1
34.4
28.0
21.3
18.6
14.9
11.0
8.3
4.1
Furnace 2 -
Diameter (D),
M
17.40
15.70
14.00
12.20
11.60
11.00
10.50
9.90
9.30
8.80
8.10
7.00
5.80
4.65
3.49
2.91
2.33
1.74
1.45
1.16


- Amber Glass
% (by wt)
Less Than D
100
99.8
99.4
96.8
92.5
89.5
87.2
83.4
78.7
75.0
73.4
60.3
47.6
35.6
25.4
20.5
16.4
10.9
8.9
5.3


                                                                111

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              O2      12    ฃป    IO   2O 3O     SO     7O  SO    9O  95   9S 99    99.ฉ
            PERCENT  BY  NUMBER  EQUAL.  TO  OR  L.ETSS THAN  INDICATED   SIZE
FIGURE 30.  Log .-probability  distribution  of  particle  sizes present in  glass   furnace   effluent.^2)

-------
                              TABLE 45

                          FLUE CONDITIONS
                      THE MANUFACTURE OF GLASS2
                                           Flint           Amber
                                           Glass           Glass
                                          Furnace         Furnace

Flue diameter, ft                                56
Average gas velocity, ft/sec                      16             33
Average gas temperature, ฐ F                   619          1,143
Static pressure, in. H2O                        - 0.44          - 0.98
Gas volume, scfm                           8,250         16,800
                                                                               113

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                                                TABLE 46

                                               EMISSIONS
                                  FROM THE MANUFACTURE OF GLASS2
                                                              Flint           Amber
                                    Emissions                Glass          Glass
                                                            Furnace         Furnace

                  Solids, gr/scf                                  0.029           0.041
                  Solids, Ib/hr                                  2.1              5.4
                  Sulfur trioxide, ppm*                          17              15
                  Sulfur dioxide, ppm                          250             315
                  Fluorine, ppm                                 2.2             1.9
                  Nitrogen oxides, ppm                         340             640
                  Carbon monoxide, ppm                       375             40
                  *ppm by volume for all gaseous pollutants.
114

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                                    TABLE 47

               CHEMICAL COMPOSITION OF PARTICIPATE EMISSIONS
                              (Quantitative Analyses)

                         Metallic Ions Reported as Oxides3
       Sample Source
Baghouse   Baghouse   Baghouse  Baghouse   Millipore*
  Catch       Catch      Catch      Catch      Filter
Test
Type of Glass
Components
Silica (SiOz)
Calcium oxide (CaO)
Sulfuric Anhydride (SOa)
Borix Anhydride (6203)
Arsenic Oxide (AszOa)
Chloride (Cl)
Lead Oxide (PbO)
K2O + Na2O
ALzOa
Fluoride
FezOa
MgO
ZnO
Unknown metallic oxide (RzOa)
Loss on ignition
No. 1
Amber,
wt%
0.03
1.70
46.92
3.67
7.71
0.01
0.39
29.47






10.10
No. 2
Flint,
wt%
0.3
2.3
25.1
1.3



28.1
3.5
8.6




30.8
No. 3
Amber,
wt%
0.1
0.8
46.7




26.1


0.1

0.5

25.7
No. 4
Flint,
wt%
4.1
19.2
30.5




36.5
0.2

0.6
1.4


7.5
No. 5
Flint,
wt%
3.3

39.4




39.2





6.5
11.6
"Stack test of baghouse exhaust
                                                                                     115

-------
                      4.  The plumes from furnaces with ejector draft systems will have lower
                         opacities than furnaces with natural-draft stacks or induced-draft fans.3

                      Exhaust volumes from  glass-melting  furnaces can be  computed from
                 the fuel  requirements  on the basis  of combustion with 40  percent  excess
                 combustion  air. Figure 31  presents the fuel requirements for bridgewall-type,
                 regenerative furnaces fired  with  natural  gas.  The   information  presented
                 is  based  on  furnaces  constructed  before 1955,  which  generally  require
                 more fuel  per  ton of  glass  than  do  furnaces  constructed  since  1955.
                 Forty  percent excess combustion  air is  chosen  as   representing  average
                 combustion  conditions.  The  fuel  requirements  of container  furnaces  at
                 maximum  pull rates  should be  estimated by using a melter rating parameter
                 of  4  square  feet  of melter  surface  area  per  daily ton of glass. For
                 estimating the fuel  requirements of  non-bridgewall  furnaces  supplying  glass
                 for  sheet,  rod,  and  tube  manufacture,  a melter  rating  parameter  of  8
                 should be  used.

                      Exhaust volumes from  furnaces  with ejector  systems  are usually  30
                 to  40 percent greater  than  exhaust volumes from  furnaces with natural-draft
                 stacks or  induced-draft fan  systems.  This  is  due to the  ejector air,
                 which is mixed in the ejector with the furnace effluent.

                      The  temperature of  exhaust gases  from  furnaces  with  natural-draft
                 stacks or induced-draft  fan  systems usually  ranges   from  600 to  1,200ฐF
                 depending  upon many   variables,  including  furnace  age.  Exhaust  gas
                 temperatures from furnaces with  ejector systems  are lower, varying  from 400
                 to 600ฐF.

                      The  exhaust gases  from large,  regenerative,  gas-fired furnaces  melting
                 three  kinds  of soda-lime  glass  were   analyzed. The results of   the chemical
                 analyses of the gaseous components produced are presented in Table 48.3
                 POLLUTION CONTROL CONSIDERATIONS

                     With  regard  to  paniculate emissions, it appears that  most uncontrolled
                 glass-melting  furnace  emissions are  in,  or  very  close to,  compliance  with
                 federal regulations.  However,  when  burning U.  S.  Grade  5 fuel oil,  they
                 usually have plumes  exceeding  40  percent opacity. While  burning  natural
                 gas or  U.  S.  Grade 3  fuel  oil,  the  plumes from these  same furnaces
                 are only 15 to 30 percent opacity.

                     In general,  opacity is directly related to the amount of small sized paniculate
                 matter. There are many  process  variables  that  affect the  emissions from
116

-------
 3D



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 09
 2
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 m
               NATURAL    GAS    CONSUMED.


                                          OF   GLASS
       O


       3D
       m
5     2
3)
m
o
m

m
3D


I
m
•n

3D


I
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<2
0)
                                                                                                                             117

-------
                                               TABLE 48

                             CHEMICAL COMPOSITION OF GASEOUS EMISSIONS
                               FROM GAS-FIRED, REGENERATIVE FURNACES1
                          Gaseous Components

                  Nitrogen, vol %
                  Oxygen, vol %
                  Water vapor, vol %
                  Carbon dioxide, vol %
                  Carbon monoxide, vol %
                  Sulfur dioxide (862), ppm
                  Sulfur trioxide (SOa), ppm
                  Nitrogen oxides (NO, NOz), ppm
                  Organic acids, ppm
                  Aldehydes, ppm
 Flint
Glass

 71.9
  9.3
 12.4
  6.4
  0
  0
  0
 724
 NA*
 NA
Amber
Glass

 81.8
 10.2
  7.7
  8.0
 0.007
 61
 12
 137
 50
  7
Georgia
 Green
 72.5
  8.0
 12.1
  7.4
  0
 14
 15
  NA
  NA
  NA
                  *NA = not available.
118

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glass-melting  furnaces.  If these  variables are  changed  as  described  below,
they will tend to decrease participate emissions:

     1.  Decrease  the  total  sulfate  (SOซ)  content  of  the  batch  charge.
     2.  Decrease the quantity of <325-mesh fines in the batch charge.
     3.  Increase  the cullet content of the batch charge.
     4.  Decrease  the  amount  of  fuel  required  to  melt  a ton  of glass.
         (This  variable  is  largely  influenced  by  the  mechanical design  of
         the furnace, in particular, the checker design.)
     5.  Improve the combustion efficiency.
     6.  Improve  regenerator  efficiency  by  performing  furnace  reversals
         in  relation  to checker  temperatures  instead  of at  fixed  periods
         of  15 to  20  minutes. This would serve to maximize the conservation
         of heat, and thereby minimize fuel consumption.

     There  has   been  little  work  done  with  regard  to  the application  of
pollution  control  systems  to  glass-melting  furnace  emissions.   Fabric
filters,  electrostatic precipitators, and high  energy Venturi  scrubbers have been
tested  to a limited degree.

Electrostatic Precipitators

     Electrostatic  precipitators are suitable for collection of fine  particles such
as those emitted from  glass furnaces. Costs, however, tend to be high for small
gas  volumes  compared to  other  types  of  collectors.  Electrostatic  precipitators
can  become more economically competitive  if several  small melting  furnaces
in one plant  are  manifolded together  to  produce a relatively  large  exhaust
gas volume.
Wet Scrubbers

     Low energy, wet, centrifugal  scrubbers have  been  applied to controlling
emissions  from  glass-melting  furnaces.  The  collection  efficiency for  these
devices  was  only  about  50 percent.3  Experimental work is currently  being
done  with  high  energy venturi  scrubbers.  This  type of scrubber can  provide
high collection efficiency when operated at a high pressure drop.

     The main disadvantages of the Venturi scrubber include the  high operating
cost due to  the  high  pressure  drop  across the throat  section and the cost of
removal and safe disposal of slurries and sludges from the system.
                                                                                          119

-------
                   Fabric Filters

                        Fabric  filters  have  an  inherently  high collection  efficiency,  provide  for
                   dry product recovery and are relatively simple in their construction and operation.

                       Disadvantages of fabric  filters  include  a temperature  limitation  of 550ฐF
                  and high  bag  replacement costs.  Gas inlet temperatures  to the filter  must
                  be controlled above the  dew  point temperature, to prevent  the  formation  of
                  a  mud which will  blind the filter,  and below the temperature limitation of the
                  bag material.  Also, at  temperatures below the dew point there  is rapid chemical
                  attack  of the fabric material.

                       With  the  pilot   bag  filters  tested  to   date,  the  furnace  effluent
                  has been  cooled  below  the  maximum  safe operating  temperature for the
                  particular fabric under consideration. The  methods used to cool  the furnace
                  effluent  have  included: air  dilution,  radiation  cooling  columns,  air to  gas
                  heat exchangers,   and  evaporative  coolers.  The  most  trouble free  method,
                  but one  which requires the largest fabric filter, is air dilution. Heat exchangers
                  and radiation  ductwork  are  subject to  rapid  fouling  from dust  in  the
                  effluent.  Evaporative  coolers,  if  not  properly   designed  and  installed,  can
                  also pose problems with temperature control  and condensation.

                   SPECIFICATIONS AND COSTS

                       Abatement specifications  were written for  electrostatic  precipitators, wet
                   scrubbers, and  fabric  filters to remove  particulates from the exhaust gas of both
                   a small  and a  large sode-lime, glass-melting  furnace. Since opacity rather than
                   weight rate of particulate matter is the problem requiring control, only one efficiency
                   level was specified for each type of equipment. That level was chosen to correspond
                   to an expected clear stack,  although a guarantee of the result could not be specified.

                       Estimates  of  capital cost and annual  operating costs made by the bidders
                   for each system  were averaged  and  presented  in the cost tables and graphs
                   which  follow this section.

                       Specifications  for electrostatic  precipitators  for glass-melting  furnaces  are
                   shown in Tables 49 and 50.  Cost data are presented in  Tables 51 and 52 and
                   Figures  32 and 33. Annual operating cost data was supplied by only one of the
                   two bidders.

                       Bidders  for these  systems submitted the collector plate  areas  in  addition
                   to their  cost data. The areas were averaged and are  tabulated  below  along
120

-------
with calculated drift velocities:

        Plant Size              Plate Area ft2      Calculated Drift Velocity, fps
          Small                    6400                   0.14
          Large                   15100                   0.14

     Specifications for wet scrubbers are shown in Tables 53 and 54.  Average
cost data are presented in Tables 55 and  56 and Figures 34 and 35. Bidders
for these  systems submitted scrubber pressure drops and L/G ratios in addition
to their cost data. Average values are tabulated below:

        Plant Size         Scrubber AP, in.  w.c.  Scrubber L/G^gprn/lOOO ACFM

          Small                    63                        8
          Large                    65                        7

     Specifications  for  fabric  filter systems for  glass-melting furnaces  are
shown in  Tables 57 and 58. Cost data are presented in Tables  59 and 60  and
Figures 36 and 37.

     Combination  shaker,  reverse  air  type  fabric  filters  with   an air-to-cloth
ratio of about 1Va/1  were  used for  both  the  small  and the large glass melting
furnace. One  of the two bidders specified  a  precoat additive upstream of the
filter unit.  This fact is footnoted on the operating cost table, but is  not  included
in the averaged cost data presented.  It should be noted the  bidders differed
greatly on the cost of many items. The  relative difference between highest  and
lowest was a factor of about two.
                                                                                         121

-------
                                                        TABLE 49


                                  ELECTROSTATIC PRECIPITATOR PROCESS DESCRIPTION

                                      FOR GLASS-MELTING FURNACE SPECIFICATION


                          A single electrostatic precipitator Is to remove paniculate matter from the exhaust gas
                    of a soda-lime, glass-melting furnace.  The furnace is natural gas fired with No. 2 fuel oil
                    standby.

                          The exhaust gas is to be brought from the furnace exhaust ports to a location 30 feet
                    outside of the furnace  enclosure by means of a fan. The precipitator will be at ground
                    level In an area beyond the ductwork which  is free of space  limitations. The fan will
                    follow the precipitator.  The abatement system shall continuously reduce the furnace
                    outlet loading to the levels specified and shall include the following:

                    1.    Precipitator with a minimum of three independent electrical fields in the direction of
                          gas How.

                    2.    Fans sized with at least 20% excess capacity when operating at the design pressure
                          drop and 90% of the maximum recommended operating speed.

                    3.    A safety interlock system which prevents access to the precipitator internals unless
                          the electrical circuitry is disconnected or grounded.

                    4.    Automatic voltage control.

                    5.    Dust hoppers and conveyors.

                    6.    Rapping system which is adjustable in terms of both intensity and rapping period.

                    7.    Dust storage with 24-hour capacity.

                    8.    Necessary flow controls and dampers.

                    9.    A model study for precipitator gas distribution.

                    10.   Materials of construction will be ASTM A242 or approved equal.
122

-------
                                 TABLE 50


            ELECTROSTATIC PRECIPITATOR OPERATING CONDITIONS

                 FOR GLASS-MELTING FURNACE SPECIFICATION


                                              Small            Large

Glass Output, ton/day                              100              300

Inlet Gas
    Flow, ACFM                               25,000           60,000
    Temp., ฐF*                                    725              725
    Flow.SCFM                               11,200           26,800
    % Moisture (vol)                                12               12

Inlet Loading
    Avg. Particle Size, p                             0.25              0.25
    Solids Rate, Ib/hr                               16.9              40.5
    Solids Loading, gr/DSCF                          .2                .2

Gas Composition, ppm
    F                                             2.2               1.9
    Cl                                             4.9               4.1
    NO,                                         340              640
    CO                                          375               40

Outlet Gas
    Outlet .Solids Loading
       gr/ACF                                     0.01              0.01
       gr/DSCF                                    .025              .025
    Outlet Solids Rate, Ib/hr                          2.11              5.05
    Efficiency, wt %                                88               88


'Can cycle up to 850ฐF during normal operation.
                                                                                        123

-------
                                       TABLE 51

                              ESTIMATED CAPITAL COST DATA
                                   (COSTS IN DOLLARS)
                            FOR ELECTROSTATIC PRECIPITATORS
                               FOR GLASS-MELTING FURNACE


Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
( 1 ) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
Model Study
(3) Installation Cost
(a) Engineering
(b) Foundations
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup
Performance Test
Other
(4) Total Cost
Medium Efficiency
Small








































Large








































High Efficiency
Small

25,000
725
11,200
12

.08
16.9

25,000
725
11,200
12

.01
2.14
88
94,312

4,800

1,309


3,530
5,066
249,796













358,813
Large

60,000
725
26,800
12

.08
40.5

60,000
725
26,800
12

.01
5.14
88
152,285

6,700

3,067


4,120
8,280
339,321









i

,

513,773
124

-------
                                  FIGURE 32
                 CAPITAL COST OF ELECTROSTATIC PRECIPITATORS
                             GLASS-MELTING FURNACE
    6

    5

    A
to
o:
-|   105
    9
    8


8   I
U
    4
    I04
      10*
                     TURNKEY COST
                                             COLLECTOR PLUS AUXILIARIES

                                              I  I  I
                                             COLLECTOR COST ONLY
   3    4   5   6  7  8 9 I05

CLEANED GAS  FLOW, ACFM
                                                                                125

-------
           TABLE 52

  ANNUAL OPERATING COST DATA
       (COSTS IN S/YEAR)
FOR ELECTROSTATIC PRECIPITATORS
   FOR GLASS-MELTING FURNACE
Operating Cost Item
Operating Factor, Hr/Year 8,600
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost



$6/hr





$0.011/kwh




16% of Cap
-
Medium Efficiency
Small
















Large
















High Efficiency
Small



240
75
315
550
550

6,467


6,467
7,332
57,410
64,742
Large



240
125
365
550
550

11,146


11,146
12,061
82,204
94,265

-------
                              FIGURE 33

               ANNUAL COST OF ELECTROSTATIC PRECIPITATORS
                       FOR GLASS-MELTING FURNACE
I05
9
8
7
6
5
4
3
2
I04
9
8
7
6
5
4
3
2
1 ft






























Of^
S^














_4*
X








^






j>
X








^
^*
_. ._




>









r






r









TOTAL A
1






TC















TA















.D










raNUAL COST

. . .




IRECT COST










































te
o
u
tf
                         3456789 I05

                      CLEANED GAS  FLOW, ACFM
                                                                      127

-------
                                                       TABLE 53


                                         WET SCRUBBER PROCESS DESCRIPTION

                                     FOR GLASS-MELTING FURNACE SPECIFICATION
                         A wet scrubber is to remove paniculate matter from the exhaust gas of a glass-melting
                    furnace. The furnace is fired with No. 5 fuel oil using 40 percent excess combustion air.

                         The exhaust gas is to be brought from the furnace exhaust ports to a fan located
                    30 feet outside of the furnace enclosure. The scrubber will be located before the fan
                    in  an area free of space  limitation.  Fresh make-up water is available and  is to be
                    added to the recirculation tank. The scrubber is to operate so as to continuously reduce
                    the furnace outlet loading to the levels specified.

                         The scrubbing system should include the following:

                    1.    Venturi scrubber with a cyclonic entrapment separator constructed of carbon steel
                         lined  with FRP or rubber with a  precooler constructed  of Incoloy or brick lined
                         carbon steel.  The scrubber internals should be either Incoloy or fiberglass reinforced
                         polyester.

                    2.    Recirculation tank and pumps.

                    3.    Fifty-foot stack following scrubber.

                    4.    Slurry settler, which will handle a  portion of the recirculation pump discharge and
                         be capable of producing a reasonably thickened underflow product.

                    5.    Fans sized with at least 20% excess capacity when operating at the design pressure
                         drop and 90% of the maximum recommended operating speed.

                    6.    Necessary controls.

                    7.    Packing glands flushed with fresh water to prevent binding of the seals.
128

-------
                                 TABLE 54


                   WET SCRUBBER OPERATING CONDITIONS

                FOR GLASS-MELTING FURNACE SPECIFICATION
Glass Output, tonlday

Inlet Gas
    Flow, ACFM
    Temp., ฐF
    Flow, SCFM
    % Moisture (vol)

Inlet Loading
    Solids Rate, Ib/hr
    Solids Loading, gr/DSCF
    Avg. Particle Size, p
       SOj Loading, ppm
       SOi Loading, ppm
       Fluorine Loading, ppm
       Chlorine Loading, ppm
       Nitrogen Oxides, ppm
       Carbon Monoxide, ppm

Outlet Gas
    Flow, ACFM
    Temp., "F
    % Moisture (vol)
    Flow DSCFM

Outlet Solids Loading
    gr/ACF
    grIDSCF
    Outlet Solid Rate, Ib/hr
    Efficiency, wt %

Wet Scrubber A/>, in. w.c."
Recirculation L/G, GPMI1000 ACFM, out

"Supplied by the bidders
 Small

   100
25,000
   725
11,200
    12
15.500
   152
   26
 9,900
    0.01
    0.02
    1.33
    92

    63
    8
60,000
   725
26,800
    12
16.9
.2
.25
250
17
2.2
4.9
340
375
40.5
.2
.25
315
15
1.9
4.1
640
40
37,200
   152
    26
23,800
    0.01
    0.02
    3.19
    92

    65
    7
                                                                                        129

-------
                                      TABLE 55

                              ESTIMATED CAPITAL COST DATA
                                   (COSTS IN DOLLARS)
                                  FOR WET SCRUBBERS
                               FOR GLASS-MELTING FURNACE


Effluent Gas Flow
ACFM
ฐF
SCFM






Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM






Moisture Content. Vol. %
Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
( 1 ) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering
(b) Foundations "
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup
Performance Test
Other
(4) Total Cost




















)






Medium Efficiency
Small









































Large









































High Efficiency
Small

25,000
725
11,200
12

.08
16.9

15,500
152
13,400
26

.01
1.33
92
13,983

37,363
1,725
175
17,493

8,233


3,950





62,298






145,220
Large

60,000
725
26,800
12

.08
40.5

37,200
152
32,200
26

.01
3.19
92
22,418

70,455
2,698
250
30,493

8,828


3,950





82,518






221,610
130

-------
6


5


A
I05

 9

 8

 7

 6
                             FIGURE 34



                   CAPITAL COST OF WET SCRUBBERS

                     FOR GLASS-MELTING FURNACE
                                       TURNKEY COST
                                        COLLECTOR PLUS AUXILIARIES
fe
o
u
                                       COLLECTOR COST ONLY
                       3   4   5   6  7  8 9 10ฐ


                    CLEANED GAS  FLOW, ACFM
                                                                        131

-------
u
to
                                                    TABLE 56

                                           ANNUAL OPERATING COST DATA
                                                (COSTS IN S/YEAR)
                                               FOR WET SCRUBBERS
                                            FOR GLASS MELTING FURNACE
Operating Cost Item
Operating Factor, Hr/Year 8,600
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost


$6/hr
$8/hr


$6/hr





$0.011/kwh

$0.25/MGal
$0.05/MGal



16% of Cap

Medium Efficiency
Small





















Large





















High Efficiency
Small


6,300
1,600
7,900

1,950
750
2,700
1,250
1,250

17,683

1,506
353

19,542
31,392
23,235
54,627
Large


6,300
1,600
7,900

1,950
875
2,825
2,375
2,375

42,834

3,264
844

46,942
60.042
35,458
95,500

-------
                                FIGURE 35

                      ANNUAL COST OF WET SCRUBBERS
                        FOR GLASS-MELTING FURNACE
    6

    5

    A
_J
8
    9
    8
    7
    5

    4
                                         TOTAL ANNUAL COST
      10*
                   TOTAL

   3    4  5   6  7 8 9 I05

CLEANED GAS  FLOW, ACFM
                                                                         133

-------
                                                       TABLE 57


                                         FABRIC FILTER PROCESS DESCRIPTION

                                     FOR GLASS-MELTING FURNACE SPECIFICATION
                         A fabric filter is to remove paniculate matter from the exhaust gas of a glass-melting
                    furnace. The furnace is fired with No. 5 fuel oil using 40 percent excess combustion air.

                         The exhaust gas is to be brought from the furnace exhaust ports to a location 30 feet
                    outside of the furnace enclosure by means of a fan. The fabric  filter will be at ground
                    level in  an area beyond  the  ductwork  which  is free of space  limitations. The fan will
                    precede the fabric filter.  The abatement system shall continuously  reduce  the furnace
                    outlet loading to the levels specified and shall include the following:

                    1.    Compartmented fabric filter operating with positive pressure.

                    2.    Fan sized with at least 20% excess capacity when operating at  the design pressure
                         drop and 90% of the maximum recommended operating speed.

                    3.    A surface cooler to lower the temperature of the gas going to the fabric  filter to
                         =s425T during normal operation.

                    4.    Compartmented design of the fabric filter which permits shutdown of one  section
                         for maintenance.

                    5.    Bags with a temperature rating of ^500ฐF.

                    6.    A high temperature by-pass around the fabric filter for use during operational upsets.

                    7.    Dust hoppers and conveyors.

                    8.    Materials of construction capable of handling furnace exhaust gas containing the
                         following:

                                  Component                       Average Concentration, ppm

                                     SO2                                    250
                                     S03                                    17
                                       F                                       2.2
                                      Cl                                       4.9
                                     NO,                                    340
134

-------
                                  TABLE 58


                    FABRIC FILTER OPERATING CONDITIONS

                 FOR GLASS-MELTING FURNACE SPECIFICATION


                                               Small            Large

Glass Output, ton/day                              100              300

Gas to Surface Cooler
    Flow, ACFM                               25,000           60,000
    Temp., ฐF*                                    725              725
    Flow, SCFM                               11,200           26,800
    % Moisture (vol)                                 12               12

Gas to Collector
    Flow, ACFM                               18,700           44,750
    Temp., ฐF*                                    425              425
    Flow, SCFM                               11,200           26,800
    % Moisture (vol)                                 12               12

Inlet Loading
    Solids Rate, Iblhr                               16.9              40.5
    Solids Loading, gr/DSCF                           .2                .2
    Avg. Particle Size, /^n                            0.25              0.25

Outlet Loading
    Solids Rate, Iblhr                                1.6               3.84
    Solids Loading, grIACF                           0.01              0.01
    Solids Loading, gr/DSCF                           .019              .019
    Efficiency, wt %                                 91               91

Air to Cloth Ratio, ACFMIft2'"                          1.5               1.5
 'Can cycle up to 850ฐF during normal operation
"Supplied by the bidders
                                                                                         135

-------
                                      TABLE 59

                              ESTIMATED CAPITAL COST DATA
                                  (COSTS IN DOLLARS)
                                  FOR FABRIC FILTERS
                              FOR GLASS-MELTING FURNACE
,

Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
( 1 ) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering
(b) Foundations
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup
Performance Test
Other
(4) Total Cost
Medium Efficiency
Small









































Large









































High Efficiency
Small

25,000
725
11,200
12

.10
16.9

18,700
425
11,200
12

.01
1.6
91
78,871

7,673

8,823
21,871

3,619


17,838
10,000

8,229
2,090
7,500
500
27,375
*
7,830
1,060
3,000
57,911
264,190
Large

60,000
725
26,800
12

.10
40.5

44,750
425
26,800
12

.01
3.84
91
147,338

15,730

11,744
47,432

4,563


22,450
17,250

12,696
3,120
10,000
850
45,638
*
11,515
1,560
4,000
112,983
468,949
136
*Included in (1)  above

-------
                                 FIGURE 36


                       CAPITAL COST OF FABRIC FILTERS
                        FOR GLASS-MELTING FURNACE
    6

    5

    4
TURNKEY COST
                                            COLLECTOR PLUS AUXILIARIES
-J  I05
Q  9
*  8

te"  7
8  6
    5

    4
                                            COLLECTOR COST ONLY
    I04
                           3    4   5   6  7 8 9 I05

                        CLEANED GAS FLOW, ACFM
                                                                              137

-------
                                               TABLE 60

                                     ANNUAL OPERATING COST DATA
                                           (COSTS IN $/YEAR)
                                          FOR FABRIC FILTERS
                                      FOR GLASS-MELTING FURNACE
Operating Cost Item
Operating Factor, Hr/Year 8,600
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials ง Replacement Parts
Total

Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify *
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost


$6/hr.
$8/hr.


$6/hr.




$0.011/kwh






16% of Cap

Medium Efficiency
Small




















Large




















High Efficiency
Small


2,681
835
3,516

1,679
11,773
13,452


16,763




16,763
33,731
42,270
76,001
Large


3,984
' 922
4,906

2,674
22,108
24,782


30,739




30,739
60,427
75,032
135,459
*0ne bidder recommended  the use of a precoat at a cost of $2,000 and $4,200 for the small and large
 fabric  filters.

-------
         FIGURE 37

ANNUAL COST OF FABRIC FILTERS
 FOR GLASS-MELTING FURNACE
D
5
4
3
2
-j 10s
Q 9
ฐ 8
, • 7
r- '
(T>
8 6
5
4
3
2
I04
l(




















_x
>gr
x^


xj







x
^



x
r






X




x
x







X



^
x^








^



^
7








TO







TA







.A







4NUAL COST



TOTAL DIRECT COST
















































)4 2 3456789 I05 2 34
CLEANED GAS FLOW, ACFM
                                                   139

-------
                                               REFERENCES
                  1.  Shand,  E.  B., Glass Engineering Handbook,  McGraw-Hill Book Company,
                     Inc., New York, 1958.

                  2.  Stockham, John D., "The Composition of Glass Furnace Emissions," Journal
                     of the Air Pollution Control Association, November, 1971, pp. 713-715,

                  3.  Air Pollution  Engineering Manual,  U.  S. Dept.  of  Health, Education,  and
                     Welfare, Public Health Services  Publication No.  999-AP-40,  Cincinnati,
                     Ohio, 1967, pp. 720-738.

                  4.  "A Screening  Study to Develop  Background  Information to Determine the
                     Significance of Glass Manufacturing,"  Prepared  by  The Research  Triangle
                     Institute, RTI Project No. 41U-762-Task 3, for The Environmental Protection
                     Agency  under Contract No. 68-02-0607-Task 3, Dec., 1972.

                  5.  Shreve,   Norris R.,  The  Chemical Process  Industries, McGraw-Hill Book
                     Company, Inc., New York, 1956.
140

-------
 5.    CRUSHED STONE AND AGGREGATE INDUSTRY

      The art  of obtaining stone from the earth's  crust is  quarrying. Quarrying
 is referred to as open-pit mining when  applied to ore bearing stone,  and strip
 mining when applied to coal mining.

      Rocks that are quarried for commercial use fall into three general classifications:
 igneous, sedimentary, and metamorphic. Igneous rock  is that formed  by volcanic
 action or great heat;  sedimentary rock is that formed by the deposit of sediment;
 and metamorphic  rock is that formed from igneous or sedimentary  rock  which
 has undergone  a change in structure due to intense pressure,  heat, or chemical
 reaction.

      Two  main products of the quarrying  industries  are  dimension stone and
 crushed and  broken  stone. The term dimension  stone is applied to blocks  or
 slabs  of natural stone that are cut to definite shapes and sizes.  Crushed and
 broken stone  generally consists of irregular fragments  produced by passing the
 stone through crushers.

      In quarrying dimension stone, blocks must be removed with care  to preserve
 their  strength and  weather resistance. The principal  uses of dimension  stone
 are  exterior and interior  building construction.  Granites and marbles  are also
 used extensively for memorials ranging from headstones to elaborate mausoleums.
 Slate is used  for roofing,  stair treads, blackboards, and many other applications.
 Sandstones are  used  as building stone and for abrasive wheels.

     Although the use of stone  in fragmentary form  is a comparatively recent
 development (the  first crushing  machine was patented in 1830), the crushed
 stone  industry  has  far outstripped the  dimension stone  industry in  tonnage.
 The chief varieties of rock used are limestone, sandstone, granite, and traprock
 (which includes  diabase, basalt and gabbro).  Since the stone is used in  small
 fragments,  explosives are used for shattering.

     The first operation in preparation for blasting is to drill a series of  deep  holes
 in rows. A  churn drill  or well drill  is often  used to sink holes 6 inches or more  in
 diameter and 50 or more feet deep.2  In large quarries  40 or more holes may be
 drilled for a single blast. The size of the charge  in each hole is determined by the
 toughness of the rock. The charges may be fired in progression or simultaneously.
 A single blast may throw down 20,000 or more tons of broken stone.

     The broken stone is  loaded  by large  capacity  power shovels and then
 transported to primary crushers where it  is reduced to  an average size of about
 six  inches. The desired fines  are separated  by  scalping and  screening, and
the larger sizes  are further  reduced by smaller secondary and tertiary crushers.
                                                                                        141

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                  Crushed  stone  is  used  chiefly for road  building,  cement  manufacturing,  for
                  agricultural purposes, in metallurgical fluxes, concrete aggregate and railroad track
                  ballast. Limestone has special uses in many chemical applications.
                  PROCESS DESCRIPTION

                       Quarrying,  or  open-pit  mining,  is  a  common  method  used  to  extract
                  consolidated ore or rock deposits that are located at or near the earth's surface.
                  Open-pit mining consists of the following steps:

                       1.  Site preparation  — constructing access roads,  designating dump sites,
                           and clearing vegetation and other obstructions.
                       2.  Removal and disposal of overburden.

                       3.  Excavation and collection of the deposit.

                       4.  Transportation of the mined resource for processing.

                       The drilling  of  shotholes  and exploratory  boreholes in hard  rock  is  an
                  essential  part of  all  quarrying operations. There has been  continual progress
                  in the development of more efficient rock drills  and drilling accessories. Two
                  main  types of wet  percussive drill have emerged; the internal or  axial  water
                  feed machines, and the external or flush-head machines.  Great advances have
                  also been made  in  the development and manufacture of  various types of dust
                  extraction  and  filtration devices,  thus enabling  the  drilling to  be  performed
                  without the aid of water.

                       In hard-rock mining, special  arrangements  have  to be made  to protect
                  workers against  dust and fumes. Holes are drilled, charged,  and fired according
                  to a  prearranged program.  The actual firing  of explosives is  done  near  the
                  end of the shift when nearly all the workers are out of the  mine.

                       After blasting, various types of mechanical equipment are used for picking up
                  the spoil and loading it into cars or onto a conveyor. Scraper loaders that draw
                  the spoil  up a ramp  into cars are also used.  A further development of this
                  principle  involves  the use  of  a power shovel  in conjunction  with a  scraper
                  that is mounted  on  a train of cars  and  distributes the  spoil  throughout the
                  length of the train. Although sometimes sent to large capacity bins first, the rock
                  in  most cases is  delivered directly to the primary crusher  plant by rail, rope
                  haulage,  conveyor belt, or diesel truck. Commonly, broken stone is loaded into
                  large-haul (20 to  75-ton capacity) trucks by front-end loaders or shovels. The rock
                  is then hauled via unimproved roads to the processing plant or primary crusher
142

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truck dump. The usual  crushing plant, situated either at the mine or at the mill,
consists of jaw or gyratory crushers as the primary  stage, followed by gyratory,
cone, or impact crushers for the final stages.

     The processing consists of screening  out the usable sizes and crushing the
oversize rock into smaller usable size  ranges.  A simplified flow diagram  for a
typical plant is shown in Figure 38.  Incoming material is routed through a  primary
crusher which crushes rocks larger than six inches. The product from this  crusher
is screened for further processing. The undersize goes to a final screening plant
and the oversize to the secondary crushing  plant. The  secondary crushers are
of the gyratory, cone, or impact type. In a  few large  plants, two or three  primary
crushers are used in parallel, followed by any number  of secondary crushers which
may or may not be in parallel.

     Jaw crushers  have  two  crushing  plates (jaws),  usually  with  one pivoted,
and moving  alternately  toward  or  away from each  other.  Maximum size feed
is about 80  inches  in  diameter and usual reduction  ratios (ratio of feed size
to product size) are about  5:1 to 8:1.

     Gyratory crushers  have  an  outer  stationary  face  which   is a  vertical,
truncated conical shell  (concave)  with  the smaller  diameter at the  bottom.
The inner movable face is a similar shell (crushing head) mounted on a spindle,
with the smaller diameter at  the  top. The  movement of the spindle  causes
the  crushing  head  to  gyrate,  alternately  moving toward  and  away from all
the points  on the circumference of the concave. Maximum  size  feed is  about
80 inches and usual reduction ratios are about 5:1 to 8:1.

     A  cone crusher is a modification of the gyratory crusher, and is specially
adapted to fine crushing.  Maximum  feed  size  for cone crushers is about 17
inches.  Average  reduction ratios  are  about 6:1  to 8:1.  Feed size  is  usually
restricted to about 80% of the feed opening.

     Impact crushers such as  the  hammermill ordinarily consist  of a  frame or
housing, a  central rotating shaft on which the hammers are mounted, and  a set
of grates which are circumferentially arranged in the lower section of the housing.
Rotational kinetic energy is transmitted from  the hammers to  the rock, and the rock
is shattered into smaller fragments.  By increasing the number of these shattering
stages,  size reductions  of 20:1  may be realized in open circuit for 3 to 6 inch
diameter rock.
NATURE OF THE GASEOUS DISCHARGE

     Particulate  matter  produced during  open-pit  mining operations  is  usually
                                                                                       143

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                          OVERSIZE
 FROM PIT
   i.
3/4- IN,
GRAVEL
STORAGE
                                       PRIMARY
                                       CONE
                                       CRUSHER
I-I/2-IN.
GRAVEL
STORAGE
PEA
GRAVEL
STORAGE

SCREEN
1


SECONDARv
CONE
C"USHER
ROCK
DUST
STORAGE
                        FIGURE 38


     SIMPLIFIED FLOW DIAGRAM OF A TYPICAL ROCK GRAVEL PLANT
PINE
CRUSHED
ROCK
STORAGE
MEDIUM
CRUSHED
ROCK
STORAGF
LARGE
CRUSHED
POCK
STORAGE

-------
 convected or permeated directly to the atmosphere,  rather than being captured
 by a local exhaust ventilation system.  In other words, the  emissions are  fugitive
 in  nature. Since many  open-pit mining operations have an indefinite operating
 life, the  installation of a fixed dust collecting system  is economically impractical.
 Therefore, fugitive  dusts should be controlled at the  point of operation. Drilling,
 blasting,  rock  handling  operations,  and wind erosion are responsible for  most
 of the particulate matter emissions produced during open-pit mining.3

      Water can be  used  in  most  open-pit  mining  operations to  control the
 generated dusts. In all  cases,  the use of rotary or  percussive drills of various
 types will lead  to  the  production  of some  amounts of  fine  respirable  dust.
 The provision  of an  efficient water feed or some other method of dust  control
 is essential.  It  is also essential that  all  surfaces in the  immediate vicinity  be
 watered  down  before drilling begins. This method is only effective at temperatures
 above the freezing point of water.

      The oldest method  of combating dust  from shotfiring is to fill a stretch of
 road with a water  fog.  This  fog  assists in  precipitating  the  dust  and fumes
 produced. It  is delivered towards the  face  of  the rock to be shotfired  through
 an air-water nozzle.

      All  scraping,  loading  and conveying operations are potential  sources of
 fugitive dust  emissions.  Oust production during  scraping and loading operations
 is  best  controlled  by  thorough  and  systematic  watering  when  temperatures
 are  above the  freezing point  of water. The loose material  should be watered
 before scraping or loading begins and from time to  time  during  operations  so
 that exposure of dry rock is avoided.

      The transport  of material from one piece of equipment to another is  usually
 accomplished by bucket elevators or, more frequently, by belt conveyors. A  point
 at which  material enters or leaves a conveyor  belt is called  a conveyor  transfer
 point.

      Dust emission in the rock crushing plant usually begins  at the primary crusher
 and continues  with  the  conveyor transfer points and the  succeeding crushers.
As the rock becomes smaller in  size, dust emissions become  greater.  Dust
emissions exist at all conveyor transfer points, dumps, crushers and screens.

     The nature and the quantity of emissions depend upon the  type of rock, the
moisture content of the rock, and the kind of processing equipment that is used.
Table 61  summarizes the unit  operations encountered in most rock and  mineral
production operations. It  also lists air  pollution  control techniques  applicable to
these unit operations.
                                                                                           145

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                                                   TABLE 61

                             ROCK AND MINERAL PRODUCTION UNIT OPERATIONS'


                          OPERATION                       CONTROL TECHNIQUES*

                   A.      Mining
                          Open pit and quarry roads   Paving; periodic oiling, watering, CaCb cover,
                                                    and/or cleaning;  covering trucks to  prevent
                                                    spillage.

                          Blasting                   Controlling size of blast, using water sprays
                                                    immediately after blasting and blasting  only
                                                    when wind direction  and other meterological
                                                    conditions are such that "neighborhood dust-
                                                    ing" will not occur.  Using "blasting mats".

                          Drilling                  .  Wet  drilling  (not fully  accepted)  or  local
                                                    exhaust ventilation.

                   B.      Transportation and storage
                          Conveyor belts             Enclosure and local exhaust ventilation.

                          Elevators                  Enclosure and local exhaust ventilation.

                          Discharge chutes           Telescoping chutes or adjustable chute heads
                                                    to  permit discharge point to be  close  to
                                                    surface of pile. Spray or local exhaust ventila-
                                                    tion at discharge point.
                          Storage piles              Enclosure (silos, bins, etc.).

                   C.      Size reduction
                          Crushing & grinding         Enclosure and  local exhaust ventilation.  Wet
                                                    sprays and/or exhaust hoods at crusher  inlet
                                                    and outlet.

                   D.      Concentration, classification
                          & mixing                   Enclosures  and  local  exhaust ventilation.
                                                    Where possible employ wet sprays.


                   'Watering  is not effective in keeping  down dust at  temperatures below freezing.
146

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 POLLUTION CONTROL CONSIDERATIONS
     Dust emissions from crushed  stone  and aggregate  production operations
 originate from three main sources:

     1.  Fugitive emissions from drilling, blasting, and rock handling operations.

     2.  All  elevator and  belt  conveyor  transfer points,  all  crusher discharge
         points and all screens.
     3.  Plant roads and stockpiles.

     The  fugitive emissions should be controlled by preventing their occurrence.
 When  temperatures  are  above freezing  this is  accomplished,  as  discussed
 in the  previous  section, through the liberal use  of water  at the point at  which
 the emissions might otherwise be generated.

     The  points  that  require hooding  and ventilation  should be  enclosed  as
 completely as possible and  plant design  should incorporate  minimum material
 falls. A minimum indraft velocity of  200 fpm  should  be maintained  through
 all open areas. The  following  rules are  also a guide to the amount of ventilation
 air required.1

     1. Conveyor transfer points require  between 350 and 500 cfm per foot of
        belt width for belt speeds of less than 200 fpm and 500 to 600 cfm per ft of
        belt width for belt speeds between 200 and 400 fpm.
     2. Bucket elevators require a tight  casing  with a ventilation  rate of 100
        cfm per square foot of casing cross section.

     3. Vibrating screens require a minimum of 50 cfm per square foot of screen
        area, with no increase for multiple  decks.

     The  most commonly used  type of dust  collection device is the fabric filter.
 In large facilities that maintain continuous operation, compartmented fabric filters
capable of cleaning  themselves during  operation  are required. Smaller facilities
can  use  equipment  that must be cleaned while  shut down. Cotton sateen  or
dacron polyester bags  are  commonly  used. The dust is collected dry by the
fabric filter and can be a saleable product.

     Medium and high  energy wet scrubbers have also  been applied to control
dust emissions in this  industry.  They are  often preceded by a dry mechanical
collector. The dust is collected in the scrubber as a slurry, is not saleable, and
must be disposed of in other ways.
                                                                                        147

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                  SPECIFICATIONS AND COSTS
                       Cost data were obtained for emission control systems for two typical types
                  of sources:  rock  crushers and conveyor transfer points. Both fabric filter  and
                  high energy wet scrubber systems were studied for each type of source.
                  Rock Crushers

                       Specifications were written for fabric filters and  wet scrubbers to control
                  the combined emissions from secondary and tertiary rock crushers. Specifications
                  were written for each of two model plant sizes. In the case of wet scrubbers, two
                  collection efficiency levels were specified for each plant size.  Only one efficiency
                  level was specified for the fabric filters. Volumetric flow rates and other parameters
                  that were  representative of plants in the industry were selected on the basis of
                  information compiled by the National Crushed Stone Association.

                       The specifications for wet scrubbers are shown in Tables 62 and 63. Averaged
                  capital and  operating cost data for the systems bid  from  these specifications
                  are presented in Tables 64 and 65 and in Figures 39, 40, 41, and 42.  In addition
                  to  the cost  data, bidders reported  scrubber  pressure  drops  and  L/G ratios for
                  the systems they bid. Averaged values for these data are tabulated below.

                   Plant   Flow Rate       Collection    Scrubber AP        Scrubber L/G
                   Size     ACFM        Efficiency        in w.c.      gpm/1000 ACFM (outlet)

                                                            7                    9
                                                           17                  13

                                                            9                    9
                                                           16                  13

                       The specifications for fabric filters are shown in Tables 70 and 71. Averaged
                  capital and operating cost data for control systems bid from these specifications
                  are presented  in  Tables 72 and 73 and in  Figures 47 and 48.  In addition  to
                  cost  data, the bidders reported the air-to-cloth  ratio for their unit. These data
                  were averaged and are tabulated below:

                                                 Flow Rate           Filter Air-to-Cloth Ratio,
                         Plant Size                 ACFM                   ACFM/ft2

                           Small                   20,000                     4.5
                           Large                   70,000                     4.5
Small
Small
Large
Large
20,000
20,000
70.000
70,000
Medium
High
Medium
High
148

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Convenor Transfer Points

     Specifications were also written for fabric filters and wet scrubbers applied
to typical conveyor transfer points. A factor of 500 ACFM per linear foot of belt
width was utilized to determine  volumetric flow  rates for the transfer points  in
the model plants. Hoods from 54", 30" and 36"-wide  belt conveyors were ducted
together for  the  small  plant. The large  plant had  eight transfer points which
included four 54"  and four 36"-wide conveyor belts.  Wet scrubber specifications
for the transfer point applications are shown in Tables 66 and 67. Average capital
and  operating cost data are presented in  Tables 68 and 69  and in  Figures-43,
44, 45 and 46. In addition to cost data, bidders reported the scrubber pressure
drop and L/G ratio which pertains to their bid.  Averaged  values are tabulated
below:

    Flow Rate,        Collection       Scrubber AP         Scrubber L/G
      ACFM          Efficiency          in w.c.      qpm/1 OOP ACFM (outlet)

       5000           Medium              7                   8
       5000           High                12                   9
      15000           Medium              7                   9
      15000           High                12                   9

     The data for the high  efficiency cases indicate  that less severe conditions
are  required,  at  comparable collection efficiency,  for  conveyor transfer  point
applications than for crusher applications.

     The specifications for fabric  filters are shown in Tables 74 and 75. Averaged
capital and  operating cost  data for the  systems bid from these specifications
are presented in Tables 76 and  77 and in Figures 49 and 50. Bidders  reported
the air-to-cloth  ratios  for the fabric filters in addition  to their cost data.  Average
values are tabulated below:

        Transfer Point Flow Rate                   Air-to-Cloth Ratio
        	ACFM	                       ACFM/ft2

                 5000                                  5.0
                15000                                  5.2

These  values  average about 10% higher than the corresponding values for the
units quoted for crusher applications.
                                                                                         149

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                                                     TABLE 62


                                       WET SCRUBBER PROCESS DESCRIPTION

                           FOR SECONDARY AND TERTIARY ROCK CRUSHER SPECIFICATION
                        A scrubber is to remove the rock dust exhausted from the secondary and tertiary
                   crushers of a rock crushing plant.  Hoods will be supplied by the bidder. The exhaust
                   points will be ducted together and brought to  the  inlet of the scrubber. The amount
                   of inlet ductwork required will be 100 ft.

                        The scrubber will be located in an open area.  Fresh make-up water and sufficient
                   power are available. The scrubbing system will consist of the following:

                   1.    Venturi scrubber with a cyclonic entrainment separator.

                   2.    Recirculation tank and pumps.

                   3.    Slurry settler,  which will handle a portion of the reclrculation pump discharge and
                        be capable of producing a reasonably thickened underflow product while returning
                        water treated to minimize solids content. Slurry withdrawal should be set to maintain
                        10% (by weight) solids when operating at design capacity.

                   4.    Two filters (one standby) to dewater the slurry product, capable of producing a
                        cake with a minimum 65% (by weight) solids.

                   5.    Fan sized with at least 20% excess capacity when operating at the design pressure
                        drop and not more than 90% of the maximum recommended operating speed.

                   6.    Necessary controls.

                   7.    Carbon steel construction.
150

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                                  TABLE 63


                    WET SCRUBBER OPERATING CONDITIONS

         FOR SECONDARY AND TERTIARY ROCK CRUSHER SPECIFICATION
      Two sizes of wet scrubbers are to be quoted for each of two efficiency levels.
 Vendor's quotations should consist of four separate and independent quotations.
 Process Wt., ton/hr

 No. of Crushers Hooded Together

 Inlet Gas
    Flow, ACFM
    Temp., ฐF
    Flow, SCFM

 Solids Loading
    gr/ACF
    grIDSCF
    Iblhr
Flow, ACFM

Scrubber, AP, in. w.c.

Solids Loading
    gr/ACF
    gr/DSCF
    Iblhr

Collector Efficiency, wt %
Flow, ACFM

Scrubber, AP, in. w.c.

Solids Loading
    gr/ACF
    gr/DSCF
    Iblhr

Collector Efficiency, wt %
SmaH
300
2
20,000
80
19,600
5.25
5.70
900
Medium Efficiency
Large
1,200
2
70,000
80
68,700
6.00
6.50
3,600

20,000
     0.23
     0.25
    40

    95.6
                                 High Efficiency
20,000
     0.01
     0.011
     1.7

    99.8
70,000
     0.076
     0.076
    40

    98.9
70,000
    0.01
    0.011
    6.0

   99.8
'To be supplied by vendor as a part of his quotation. Vendor should also supply required
liquid circulation rate.
                                                                                          151

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                                     TABLE 64

                            ESTIMATED CAPITAL COST DATA
                                 (COSTS IN DOLLARS)
                                FOR WET SCRUBBERS
                     FOR SECONDARY AND TERTIARY ROCK CRUSHERS

Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %













Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
( 1 ) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost













(a) Engineering ">
(b) Foundations
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup ^
Performance Test




^






Other }
(4) Total Cost

Medium Efficiency
Small

20,000
80
19,600


5.25
900

20,000
80
19,600
2

.23
40
95.6
14,491

5,522
2,699
2,400
3,113

9,887






81,116






2,333

121,561
Large

70,000
80
68,700


6.00
2,600

70,000
80
68,700
2

.07
40
98.9
34,148

18,092
5,175
6,932
4,036

18,220






127,650






2,333

216,586
High Efficiency
Small

20,000
80
19,600


5.25
900

20,000
80
19,600
2

.01
1.7
99.8
14,156

14,253
5,598
5,200
4,016

9,887






86,807






2,333

142,250
Large

70,000
80
68,700


6.00
3,600

70,000
80
68,700
2

.01
6.0
99.8
34,556

28,290
5,924
6,932
5,084

18,220






138,566






2,333

239,905
152

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                                                  TABLE 65

                                          ANNUAL OPERATING COST DATA
                                               (COSTS IN $/YEAR)
                                              FOR WET SCRUBBERS
                                   FOR SECONDARY AND TERTIARY ROCK CRUSHERS


Operating Factor, Hr/Year 8,500
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost

•s
&6/hr. \
&8/hr. ;
./

&6/hr.





ฃ0.011/kwh

$0.25/MGal




16% of Cap

Medium Efficiency
Small


6,086
6,086

4,540
850
5,390
3,992
3,992

6,409

603


7,012
22,480
19,450
41,930
Large


7,027
7,027

5,875
1,267
7,142
5,733
5,733

31,014

2,157


33,171
53,073
34,654
87,727
High Efficiency
Small


6,086
6,086

4,540
1,150
5,690
5,367
5,367

10,911

606


11,517
28,660
22,760
51,420
Large


7,027
7,027

5,875
1,600
7,475
6,400
6,400

39,180

2,159


41,339
62,241
38,385
100,626
CJl
w

-------
                                       COST,  DOLLARS
                   ro
n
r
rn
o

O
o

2
    ro


    ro
       O) -4 00 CO O
                  in
                                                                         co   ^   en  o
\
                                                                OH
                                                                > >
                                                                a r
                                                              -3 -< ซ
                                                                                                e OH

                                                                                                3 HO

                                                                                                  n
                                                                      Tl
                                                                      5

                                                                      a
                                                                      m
                                                                      o
                                                                      
-------
                              FIGURE 40



                    ANNUAL COST OF WET SCRUBBERS

              FOR SECONDARY AND TERTIARY ROCK CRUSHER

                          (Medium Efficiency)
6


5


4
-}  I05

Q   9
2   8


ฃ   7
O   6
U
4
                                        TOTAL ANNUAL COST
                                         TOTAL DIRECT COST
  10*
                          3   4   5   6  7 8 9 I05


                       CLEANED GAS  FLOW, ACFM
                                                                       155

-------
                              FIGURE 41

                     CAPITAL COST OF WET SCRUBBERS
               FOR SECONDARY AND TERTIARY ROCK CRUSHERS
                            (High Efficiency)
    6

    5

    4
                                          TURNKEY COST
Q   9
Q   8
i-
    4

    3
                                          COLLECTOR PLUS AUXILIARIES
   I04
      10*
                    COLLECTOR COST ONLY
   3   4   5   6 7 8 9 I05

CLEANED GAS FLOW, ACFM

-------
                         FIGURE 42

               ANNUAL COST OF WET SCRUBBERS
          FOR SECONDARY AND TERTIARY ROCK CRUSHERS
                       (High Efficiency)
D



i in5
i
y y
d Q
o
L* 7
f- /
0 6
U
s



in*









,i
^

s









_x
^

X
r








_xi
X

x
^








^^
x*


X








-rf
X


X









>


^
^








•
7


f









T<













ITA



)TA









L ANNUAL COST





































10*
   3   4  5   6  7 8 9 I05

CLEANED GAS  FLOW, ACFM
                                                                  157

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                                   TABLE 66
                     WET SCRUBBER PROCESS DESCRIPTION

               FOR CRUSHED STONE AND AGGREGATE CONVEYOR
                       TRANSFER POINTS SPECIFICATION
     A scrubber is to remove the rock dust exhausted from the conveyor transfer points
In a  rock  crushing  plant.  Hoods will  be supplied by  the  bidder.  Exhaust points
will be  ducted together and  brought to the  inlet of the scrubber. The  number  of
hoods involved and  their total face  area is shown in  the operating conditions. The
inlet ductwork required will be 50 ft/hood. Duct velocity will be 3.500 ft/min.

     The scrubber will be located In an open area. Fresh make-up water and sufficient
power are available. The scrubbing system will consist of the following:

1.   Venturi scrubber with a cyclonic entrainment separator.

2.   Reclrculation tank and pumps.

3.   Slurry settler, which will handle a portion of the recirculation pump discharge, and
     be capable of producing a reasonably thickened underflow product while returning
     water treated to minimize solids content. Slurry withdrawal should be set to maintain
     10% (by weight) solids when operating at design capacity.

4.   Two filters (one standby) to dewater the slurry product, capable of producing a cake
     with a minimum 65% (by weight) solids.

5.   Fan sized with at least 20% excess capacity when operating at the design pressure
     and not more than 90% of the maximum recommended operating speed.

6.   Necessary controls.

7.   Carbon steel construction.

-------
                                  TABLE 67
                    WET SCRUBBER OPERATING CONDITIONS

               FOR CRUSHED STONE AND AGGREGATE CONVEYOR
                       TRANSFER POINTS SPECIFICATION
      Two sizes of wet scrubbers are to be quoted for each of two efficiency levels. Vendor's
 quotations should consist of four separate and independent quotations.
 No. of Hoods Ducted Together
 Total Face Area of Hoods, ft2
 Inlet Gas
    Flow, ACFM
    Temp., "F
    Flow, SCFM
 Solids Loading
    gr/ACF
    gr/DSCF
    Ib/hr
Small

    3
   71

5,000
   80
4,900
    1.0
    1.08
   42.7
     8
  234


15,000
   80
14,700
     1.0
     1.08
   128
                               Medium Efficiency
Flow, ACFM
Scrubber, AP, in. w.c.
Solids Loading
    gr/ACF
 -   gr/DSCF
    Ib/hr
Collector Efficiency, wt %
5,000
    0.04
    0.045
    1.7

   96
15,000
    0.04
    0.045
    5.1

   96
Flow, ACFM
Scrubber, AP, In. w.c.
Solids Loading
    gr/ACF
    gr/DSCF
    Ib/hr
Collector Efficiency, wt %
                                 High Efficiency
5.000
    0.01
    0.011
    0.4

  99
15,000
    0.01
    0.011
    1.3

   99
'To be  supplied by  vendor  as  a part of  his quotation.  Vendor should also  supply
required liquid circulation rate.
                                                                                            159

-------
                                     TABLE 68

                            ESTIMATED CAPITAL COST DATA
                                 (COSTS IN DOLLARS)
                                FOR WET SCRUBBERS
              FOR CRUSHED STONE AND AGGREGATE CONVEYOR TRANSFER POINTS


Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
( 1 ) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering "\
(b) Foundations
& Support
Ductwork
Stack >
Electrical
Piping
Insulation
Painting
Supervision
Startup J
Performance Test
Other "\
(4) Total Cost
Medium Efficiency
Small

5,000
80
4,900
2

1.0
42.7

5,000
80
4,900
2

.04
1.7
96
7,322

2,093
1,345
1,099
2,963

6,554






56,321






2,333

80,030
Large

15,000
80
14,700
2

1.0
128

15,000
80
14,700
2

.04
5.1
96
12,472

3,991
2,087
2,798
3,063

11,554






70,136






2,333

108,434
High Efficiency
Small

5,000
80
4,900
2

1.0
42.7

5,000
80
4,900
2

.01
.4
99
7,175

4,151
1,348
1,099
3,000

6,554






58,123






2,333

83,783
Large

15,000
80
14,700
2

1.0
128

15,000
80
14,700
2

.. .01
1.3
99
12,511

7,649
2,087
2,798
3,063

11,554






71,802






2,333

113,797
160

-------
                                                  TABLE 69

                                         ANNUAL OPERATING COST DATA
                                               (COSTS IN S/YEAR)
                                             FOR WET SCRUBBERS
                                         FOR CONVEYOR TRANSFER POINTS
Operating Cost Item
Operating Factor, Hr/Year 8.500
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost

$6/hr. ")
$8/hr. J
$6/hr.


$0.011/kwh
$0.25/MGal


16% of Cap

Medium Efficiency
Small

5,212
5,212
1,200
570
1,770
1,867
1,867
1,708
8
1,716
10,565
12,805
23,370
Large

6,121
6,121
1,200
690
1,890
2,250
2,250
5,550
24
5,574
15,835
17,349
33,184
High Efficiency
Small

5,212
5,212
1,200
670
1,870
2,225
2,225
2,464
8
2,472
11,779
13,405
25,184
Large

6,121
6,121
1,200
790
1,990
2,593
2,593
7,202
25
7,227
17,931
18,208
36,139
0>

-------
                                      FIGURE 43

                           CAPITAL COST OF WET SCRUBBERS
        FOR CONVEYOR TRANSFER POINTS FOR CRUSHED STONE AND AGGREGATE INDUSTRY
                                  (Medium Efficiency)
9
8
7
6

5

A
     <   A
     -J  ICT
         9
         8
     \-  7

     8  6
                                                         COLLECTOR PLUS AUXILIARIES
                                                             COLLECTOR COST ONLY
         IOJ
                        2      3    456789ICT

                            CLEANED GAS  FLOW, ACFM
162

-------
                                 FIGURE 44
                       ANNUAL COST OF WET SCRUBBERS
             CRUSHED STONE AND AGGREGATE CONVEYOR TRANSFER POINTS
                              (Medium Efficiency)
to
IE

-------
                                       FIGURE 45

                             CAPITAL COST OF WET SCRUBBERS
         FOR CONVEYOR TRANSFER POINTS FOR CRUSHED STONE AND AGGREGATE INDUSTRY
                                    (High Efficiency)
                                                          COLLECTOR PLUS AUXILIARIES
                                                             COLLECTOR COST ONLY
           10
2      3    4   5   6  7 8 9 ICT

    CLEANED GAS FLOW, ACFM
164

-------
                               FIGURE 46

                    ANNUAL COST OF WET SCRUBBERS
       FOR CRUSHED STONE AND AGGREGATE CONVEYOR TRANSFER POINTS
                            (High Efficiency)
o
u
    6

    5

    4
J  10'

8   I
\-   7
    6
    5

    A
      ICT
                                                         TOTAL ANNUAL COST
                  2       3   A   '•   6  7 6 9 I04

                      CLEANED (,••   FLOW, ACFM
                                                                         165

-------
                                                      TABLE 70


                                        FABRIC FILTER PROCESS DESCRIPTION

                           FOR SECONDARY AND TERTIARY ROCK CRUSHER SPECIFICATION


                        A fabric filter is to remove rock dust from  the exhaust from the ventilation hoods
                   located over the secondary and tertiary crushers of a  rock  crushing plant. Hoods will
                   be supplied by the bidder.

                        The exhaust gases will be ducted together and brought to the Inlet of the fabric
                   filter.  The  amount of Inlet ductwork  required  will be  100 ft.  The  fabric filter  will
                   be located in  an area  free from space limitations.  A fan located at the outlet of the
                   fabric filter will draw the exhaust gases through the system.

                        The fabric  filter is to be compartmented  to allow for Isolation  of an Individual
                   compartment for  cleaning  during  operation. A  single compartment  should  have a
                   maximum of 25%  of the total collecting  surface area. Each section  should also be
                   capable of isolation for maintenance  and have  provisions for personnel safety during
                   filter operation.  No more than two bags must  be removed to permit access to all
                   of the bags.  The  dust  collecting  process should be  continuous and should  Include
                   the following:

                   1.    Compartmented fabric filter operating at negative pressure.

                   2.    Maximum air-to-cloth ratio, when one compartment Is down for cleaning, of 5.0/7.

                   3.    Dacron polyester bags.

                   4.    Pulse-Jet type cleaning mechanism.

                   5.    Trough hoppers with a minimum side and valley  angle of 55ฐ.

                   6.    Screw conveyor system with a rotary air lock at its end.

                   7.    Fans sized with at least 20% excess capacity when  operating at the design pressure
                        drop and  90% of the maximum recommended operating speed.
166

-------
                                 TABLE 71


                    FABRIC FILTER OPERATING CONDITIONS

        FOR SECONDARY AND TERTIARY ROCK CRUSHER SPECIFICATION
Process Wt., tonlhr

No. of Crushers Hooded Together

Inlet Gas
    Flow, ACFM
    Temp., ฐF
    Flow, SCFM

Solids Loading
    gr/ACF
    gr/DSCF
    Ib/hr
Small
300
2
20,000
80
19,600
5.25
5.70
900
Large
1,200
2
70,000
80
68,700
6.00
6.50
3,600
                               High Efficiency

Flow, ACFM                                  20,000

Solids Loading
    gr/ACF
    gr/DSCF
    Ib/hr

Air-to-cloth Ratio'

Collector Efficiency, wt %

"To be supplied by vendor as a part of his quotation.
 0.01
 0.011
 1.7
99.8
             70,000
 0.01
 0.11
 6.0
99.8
                                                                                        167

-------
                                      TABLE 72

                             ESTIMATED CAPITAL COST DATA
                                 (COSTS IN DOLLARS)
                                 FOR FABRIC FILTERS
                      FOR SECONDARY AND TERTIARY ROCK CRUSHERS


Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %















Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
( 1 ) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering "
(b) Foundations
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup ^
Performance Test
Other •)
J
(4) Total Cost


















\
?







Medium Efficiency
Small









































Large









































High Efficiency
Small

20,000
80
19,600
2

5.25
900

20,000
80
19,600
2

.01
1.7
99.8
35,166

6,177

825
4,557

6,316








38,437




2,000

93,478
Large

70,000
80
68,700
2

6.0
3,600

70,000
80
68,700
2

0.01
6.0
99.8
106,114

24,096

1,072
8,143

15,346








112,151




2,000

268,922
168

-------
                                 FIGURE 47
                       CAPITAL COST OF FABRIC FILTERS
                 FOR SECONDARY AND TERTIARY ROCK CRUSHERS
    6
    5
    A
-j  I05
X   9
"   8
k"   I
O   6
U
    5
    4
                                            TURNKEY COST

                                   v\
                                            COLLECTOR PLUS AUXILIARIES
                                             .COLLECTOR COST ONLY
   I04
                          3    4   5   6 7  8 9 I05
                       CLEANED GAS  FLOW, ACFM
                                                                           169

-------
                TABLE 73

       ANNUAL OPERATING COST DATA
            (COSTS IN $/YEAR)
           FOR FABRIC FILTERS
FOR SECONDARY AND TERTIARY ROCK CRUSHERS
Operating Cost Item
Operating Factor, Hr/Year 8,500
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost

$8/hr
$6/hr



$0.011/kwh




16% of Cap

Medium Efficiency
Small











•

Large













High Efficiency
Small

453
453
504
133
637
2,142
2,142

6,203


6,203
9,435
14,956
24,391
Large

453
453
1,240
433
1,673
7,541
7,541

21,784


21,784
31,451
43,028
74,479

-------
                              FIGURE 48
                           COST OF FABRIC FILTERS
             FOR SECONDARY AND TERTIARY ROCK CRUSHERS
    3
    7
    6

    5

    4
9
8
7
6
4

                                        TOTAL ANNUAL COST
                                         TOTAL DIRECT COST
(/)
8
      10*
                      3456789 I05

                   CLEANFID GAS FLOW, ACFM
                                                                      171

-------
                                                      TABLE 74
                                        FABRIC FILTER PROCESS DESCRIPTION

                                  FOR CRUSHED STONE AND AGGREGATE CONVEYOR
                                          TRANSFER POINTS SPECIFICATION
                        A  fabric  filter  Is to remove rock dust from the exhaust from ventilation hoods
                   located  at conveyor transfer points In a rock crushing plant.  Hoods  will be supplied
                   by the bidder. Duct velocity will be 3.500 ftlmln.

                        The exhaust gases will be ducted together and brought to the Inlet of the fabric
                   filter. The number of hoods  Involved and the total face area under all of the hoods
                   Is  shown In the table of operating  conditions.  The Inlet ductwork required will be
                   50 ftlhood.  The  fabric filter  will be  located In an  area  free from space limitations.
                   A  fan located at the  outlet  of  the fabric filter will  draw the exhaust gases through
                   the system.

                        The fabric  filter  Is to be  compartmented to allow for Isolation  of an individual
                   compartment for cleaning during operation. A single compartment should have a maximum
                   of  25%  of the total collecting surface area. Each section should also be capable  of
                   isolation  for maintenance and have provisions for personnel safety during filter operation.
                   No more than  two bags must  be removed  to permit access to aH of the  bags.  The
                   dust collecting process should be continuous and should Include the following:

                   1.    Compartmented fabric filter operating at negative  pressure.

                   2.    Maximum alr-to-doth ratio,  when one compartment Is down for cleaning, of 6.011.

                   3.    Dacron polyester bags.

                   4.    Pulse-jet type cleaning mechanism.

                   5.    Trough hoppers with a minimum side and valley angle of 55'.

                   6.    Screw conveyor system equipped with rotary air lock.

                   7.    Fans sized with at least 20% excess capacity when operating at the design pressure
                        drop and 90% of the maximum recommended operating speed.
172

-------
                                 TABLE 75
                   FABRIC FILTER OPERATING CONDITIONS

              FOR CRUSHED STONE AND AGGREGATE CONVEYOR
                      TRANSFER POINTS SPECIFICATION
                                             Small            Large

No. of Hoods Ducted Together                        3                8
Total Face Area of Hoods, ft2                        71              234
Inlet Gas
   Flow. ACFM                               5,000            15,000
   Temp., "F                                    80               80
   Flow, SCFM                               4,900            14,700

   Solids Loading
       gr/ACF                                    1.0               1.0
       gr/DSCF                                   1.08              1.08
       Ib/hr                                     42.7             128
                               High Efficiency

    Flow, ACFM                               5,000            15,000
    Solids Loading
       gr/ACF                                    0.01              0.01
       gr/DSCF                                   0.011             0.011
       Ib/hr                                      0.4               1.3

    Air-to-cloth Ratio"

    Collector Efficiency, wt %                        99               99


To be supplied by vendor as a part of his quotation.
                                                                                       173

-------
                                       TABLE 76
                              ESTIMATED CAPITAL COST DATA
                                  (COSTS IN DOLLARS)
                                  FOR FABRIC FILTERS
               FOR CRUSHED STONE AND AGGREGATE CONVEYOR TRANSFER POINTS


Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
gr/ACF
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %















Cleaned Gas Contaminant Loading
gr/ACF
Ib/hr
Cleaning Efficiency, %
( 1 ) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering ^
(b) Foundations
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup
Performance Test
Other
I ^
(4) Total Cost ,


















>





>

Medium Efficiency
Small








































Large








































High Efficiency
Small

5,000
80
4,900
2

1.0
42.7

5,000
80
4,900
2

.01
.4
99
10,290

2,041

83
2,093

1,230







12,683




2,000

30,420
Large

15,000
80
14,700
2

1.0
128

15,000
80
14,700
2

.01
1.3
99
22,297

4,772

109
3,925

3,435







25,211




2,000

61,749
174

-------
                                   FIGURE 49
                          CAPITAL COST OF FABRIC FILTERS
           FOR CRUSHED STONE AND AGGREGATE CONVEYOR TRANSFER POINTS
    6
    5
    A
.
ir
<    s
-i   I05
Q   9
(^   o
I-   7
8   6
U
    4
    3
    I04
    -^TURNKEY COST
ฃ0CC.
                                      COLLECTOR PLUS AUXILIARIES
                                                         COLLECTOR COST ONLY
      10'
2       3   45678910*
    CLEANED GAS  FLOW, ACFM
              3   4
                                                                             175

-------
                       TABLE 77
              ANNUAL OPERATING COST DATA
                    (COSTS IN S/YEAR)
                   FOR FABRIC FILTERS
FOR CRUSHED STONE AND AGGREGATE CONVEYOR TRANSFER POINTS
Operating Cost Item
Operating Factor, Hr/Year 8,500
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost


$8/hr


$6/hr





$0.011/kwh






16% of Cap

Medium Efficiency
Small




















Large




















High Efficiency
Small


453
453

304
40
344
493
493

1,911




1,911
3,201
4,867
8,068
Large


453
453

416
90
506
1,150
1,150

3,319




3,319
5,428
9,880
15,308

-------
                              FIGURE 50


                     ANNUAL COST OF FABRIC FILTERS

       FOR CRUSHED STONE AND AGGREGATE CONVEYOR TRANSFER POINTS
co
O
u
      10
   3   4   5   6 7  8 9 10*


CLEANED GAS PLOW, ACFM
2.
                                                                      177

-------
                                               REFERENCES
                  1.  Air Pollution Engineering Manual. U. S. Dept. of Health,  Education, and
                      Welfare, Public Health Services Publication No. 999-AP-40, Cincinnati, 1967.

                  2.  Guide to the Prevention and Suppression of Dust  In  Mining, Tunnelling
                      and Quarrying,  International  Labour Office, Printed by Atar S.A., Geneva
                      (Switzerland), 1965.

                  3..  Stern, Arthur C., Air Pollution. Volume III, Academic Press, Inc., New York,
                      1968.
178

-------
6.   ASPHALT SATURATION

     Roofing paper and roofing shingles are manufactured by a process known
as  asphalt  saturation.  In  this  process  a  vegetable  felt  base  is  impregnated
with petroleum derived  asphalt materials  which are  called saturants. The felt
is made from  vegetable fibers and  is often produced  in  the  same facility  as
the finished roofing materials.

     The industry producing these products  consists of firms with a wide variation
in size. The Census of Manufacturers shows 226 firms engaged in  this  industry
in  1967.1 The average firm  employed  65 people and shipped $2.65  million
of  products. The complete  distribution  of firm sizes  and  product values is
presented  in  Table 78.  Total  shipments  by  this industry in  1971 were 7.9
million tons and  this figure was  projected  to  grow at a  rate of approximately
3% per year.
PROCESS DESCRIPTION

     The asphalt saturation process involves basically the application of a controlled
amount of asphalt to both sides of a dry felt sheet. The  application  is often
carried out by spraying the felt with hot asphalt and then dipping the felt  into a
tank holding  more hot asphalt. The  dipping operation is usually totally enclosed
with a hood which is vented to the atmosphere. A schematic flow  diagram  of the
process is shown in Figure 51.
Raw Materials

     There are two main raw materials used in the production of asphalt roofing;
asphalt saturant and felt.

     Asphalt is a  petroleum  derived product.  If is produced  as the  residual
bottoms product from the vacuum distillation of crude oil. It is principally hydrocarbon
in nature,  but  also  contains oxygen, sulfur, nitrogen,  metals,  and other trace
elements chemically bonded to the hydrocarbon molecules. It is normally solid
at room temperature,  having   an  initial  boiling  point  in excess of  1000ฐF.

     Asphalt, as produced  from a crude unit in a refinery, is not viscous enough
to be  used as saturant. Viscosity is  increased by  means of a treatment  step
called  asphalt  blowing. This treatment  consists of bubbling  air  through  liquid
asphalt. Oxidation reactions occur during this treatment which lead to polymerization
of the  hydrocarbons and some reduction of the  hydrogen content. In  the roofing
                                                                                         179

-------
                                           TABLE 78

                      NUMBER OF ESTABLISHMENTS AND VALUE OF SHIPMENTS
                        OF ASPHALT SATURATED PRODUCTS BY SIZE CLASS*
                                                                     Value of
                                                      Number of      Shipments
                                                    Establishments   (million dollars)

               1 to 4 Employees                            33             5.6
               5 to 9 Employees                            22            10.2
               10 to 19 Employees                           33            29.6
               20 to 49 Employees                           46            59.0
               50 to 99 Employees                           44           132.0
               100 to 249 Employees                         42           276.0
               250 to 499 Employees                          4            31.6"
               500 to 999 Employees                          2            53.8"
                  Total                                  226           597.8
                *1967 Data
               "Estimate, based on output per employee
180

-------
                ASPHALT HEATERS
                                                                            n	
                                                                     FEED
                                                                   HOPPER.
                                                                                 SAND
                                                                                DRYER
                                                                                SCREEN
GRANULE
STORAGE
                                                                            PNEUMATIC FEED
                                                                            FROM
                                                                            TRUCK
 DRY       DRY
FELT     LOOPER
                                                                                     00
                                                                                 DRIVEN PULLEY FEEDS
                                                                                  FELT TO HOPPER
                                                                                      LOOPING RUNGS
                                                                                       DRIVEN AT CON-
                                                                                        STANT SPEED
                                                                                                 TO
                                                                                             SPROCKET
                      SATURATING TANK
                          FIGURE 51
  SCHEMATIC FLOW DIAGRAM OF ASPHALT SATURATION PROCESS3

-------
                   products industry, the air-blown asphalt is called saturant (or coating asphalt) and
                   is characterized  by its  softening point  which is  typically 100 to 140ฐF. In the
                   saturating  process, it  is handled at 400 to 500ฐF where it is fluid enough to be
                   applied to the felt in controlled thicknesses.

                        Felt is a fibrous paper product produced from vegetable matter. It is commonly
                   characterized by two  properties: weight .and  moisture content. Weight is a term
                   for the thickness of the felt. Several standard felt weights are produced for use
                   in different products. Moisture content of the felt is  an important property since
                   it affects the quality  of the  saturator product. Excessive  moisture  can cause
                   the applied asphalt to blister. Felts  are  generally  made with 5 to 10% moisture,
                   an amount which can be adequately removed during saturation.
                   Non-Coated Products

                       These products  are  commonly referred  to  as 15 and  30 pound asphalt
                   saturated  rag  felt (ASRF).  Fifteen  pound  ASRF  is  made  from organic felt,
                   36 inches wide and  with  a felt weight  of  5.6  pounds per 100 square  feet.
                   Thirty  pound  ASRF is made  from organic  felt 36 inches  wide and with  a
                   felt weight of 10.4 pounds per 100 square feet. The organic felt is commonly
                   referred  to as  27 weight and  50 weight.  The organic felt is  wound  into jumbo
                   rolls that weigh from 2,000 to 3,000 pounds, with up to  7,000  lineal feet per roll.

                       During operation  the felt is  unrolled continuously  onto a  series of rollers
                   called  a dry looper. The dry looper acts as inventory at the front of the process
                   so that  the feed  rate to the saturator  can be  held constant,  even during
                   felt roll  changes. Felt from the dry looper is pulled into the  saturator where
                   it is saturated with hot asphalt at a temperature of 450ฐF. Saturation is accomplished
                   by spraying,  dipping,  or  both. When spraying is  employed,  hot  asphalt  is
                   sprayed  onto  one side of  the felt, driving  the moisture out  the other  side.
                   When  both methods  are  employed, spraying  precedes dipping. Most  modern
                   roofing plants  are designed to use  dipping  only,  since  the  dipping  process
                   removes  a sufficient   amount  of  moisture  out  of  the felt  by boiling  during
                   submersion in the asphalt bath.

                       After  the felt is dipped, it travels  over several rolls known  as the drying-in
                   section.  This  allows the surface  saturant to  dry into  the felt  and  helps  coat
                   the sheet.

                       The felt is then conveyed to  an accumulator before it is wound into  rolls.
                   Roll lengths vary from  72 to 144 feet.  The 27w felt generally absorbs or retains
                   approximately 7.8 pounds  of saturant per  100 square feet. The  50w  felt retains
                   approximately 17.4 pounds of saturant per 100 square feet.
182

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     The process  production rate is controlled by the  linear  speed  at  which
 felt  can  be fed  to  the saturator and that speed,  in  turn,  is controlled  by
 the  properties  of  the  felt. Maximum  speeds are  lower for heavier weight felts
 than for lighter weight felts. Speeds as  high as  1,000 fpm  can be  used with
 light weight felts,  but  average speed is about 350  fpm.  If 50w felt is fed to a
 saturator at 350 fpm, the weight rate of felt feed is 6552 Ib/hr  and the production
 rate of saturated product is 17,514 Ib/hr.
 Coated and Slate Surfaced Products

     Asphalt  shingles are  generally produced using  a 55w organic felt that
 weighs 11.5 pounds per 100  square feet.  Production of asphalt shingles begins
 with the  asphalt saturation  process and  then goes  through a coating and
 surfacing  process. The coating process  is accomplished by metering a measured
 amount of  filled coating to  both  surfaces  of the  saturated  felt. The shingle
 weight  is  controlled  in  the  coating  process  by  increasing  or decreasing  the
 amount of surface coating.

     Filled  coating is made  from  two  materials, coating and filler. There  are
 two types of filler that  are  normally used; limestone and  slate.  The  majority
 of  the  roofing companies  use  50% filler  in the  coating. The filled coating is
 applied to the sheet at temperatures ranging from 360 to 410ฐF.

     After the coating  process,  the  sheet travels through  a surfacing section
 where slate granules are applied  to the top  surface  and  a parting  agent is
 applied to  the  back surface. Different  colors  of granules  are  applied  to  the
 sheet  to  get  the desired  blend or color  of shingles.  Several different parting
 agents  are available.  Talc, sand and  dolomite are the most common parting
 agents  used.  When the sheet  leaves  the  surfacing section, it travels  through
 a  cooling  section where water is  sprayed on the back  of the sheet.  Then
 the  sheet  goes into  an  accumulator  to  further  cool  the  sheet.  When  the
 sheet leaves the accumulator,  it is cut into shingles and packaged.

     The  process production rate is controlled by the capabilities of the machine,
 such as,  saturation capacity. Machine  speeds on asphalt shingle production
 range from 350 to 600 fpm.
NATURE OF THE GASEOUS DISCHARGE

     The saturator  is totally enclosed  with a  hood for  health reasons and that
hood is vented to the atmosphere. The amount of air exhausted from this hood
depends upon  the  size  of  the saturator and the  degree of enclosure  of the
                                                                                        183

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                   saturator. Typical saturators vent 20,000 to 30,000  ACFM. The  range of rates
                   extends from 10,000 to 68,000 ACFM.1 The trend in modern plant  design is down
                   since  the  cost of the  required pollution control  equipment  depends strongly
                   upon the vent flow rate. The minimum exhaust volume is set by the quantity
                   of air that will allow men to work in the saturator enclosure and that will prevent
                   the escape of fumes into the plant.

                       The gases vented from the hood contain two principal classes of pollutants;
                   hydrocarbons and sulfur oxides. The hydrocarbons  originate from the hot asphalt
                   bath. They enter  the  ventilation  stream  by  means of vaporization  from the
                   bath and mechanical agitation of the bath caused by the  felt  passing through.
                   Where spraying is used, the spray nozzles also contribute vaporized hydrocarbons.
                   The hydrocarbons are emitted in  both the  gas  phase and the liquid  phase
                   as  an aerosol. The aerosol consists  almost entirely of droplets  formed by the
                   condensation of oil vapors driven from  the asphalt saturator, with little contribution
                   from  liquid  particles  entrained  by  mechanical  agitation  of the bath or at the
                   spray nozzle. These particles are very small with most being submicron.

                       The sulfur oxides are all  in the vapor phase.  They  are  formed from the
                   sulfur  containing  compounds in the  asphalt and  originate in  the hot asphalt
                   bath or sprays.  Sulfur oxides  are emitted  at  lower rates than  hydrocarbons.
                   Typical emission factors are as follows:1

                   Hydrocarbons                        1 to 2.5 Ib/ton product
                   Sulfur Oxides                         0.05 to 0.20  Ib/ton product

                       The asphalt  blowing facilities  represent the other  major  pollution source in
                   the typical asphalt roofing  products plant. The emissions are hydrocarbon in
                   nature  and  result from  the air  blown through  the asphalt to improve  its
                   properties as a  saturant. The rate of emission is roughly 50% of the saturator.
                  POLLUTION CONTROL CONSIDERATIONS

                       The  pollution control  systems which are  applicable to  the  emissions from
                  asphalt saturators include some of those classically applied  to control of hydro-
                  carbons: incineration, and  absorption processes using chemical  oxidants.  Glass
                  fiber mat  filters,  specifically developed for use on asphalt saturators,  are also
                  commonly  used.3 Carbon adsorption is  not used because the asphaltic hydro-
                  carbons are not  easily  desorbed from the surface of the carbon. Conventional
                  devices used  for the collection of small sized particulate matter such  as high
                  energy  wet scrubbers and electrostatic precipitators  have  been  applied  to  a
                  lesser degree.
184

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 Incinerators

     Thermal incineration is  the most  positive and  direct control  method  for
 hydrocarbon emissions and  it has been widely applied  to emissions  from this
 process.  Conversions up to  99% can  be achieved  at  operating temperatures
 of  1,200  to  1,400ฐF and residence times  of 0.3  sec.  The  units  are built
 with heat recovery  when the air flow being treated  is  large enough to make
 the  economics  attractive. The  heat  recovery  scheme used  takes one  of two
 forms.

     1.   Preheat of  the incinerator inlet gas by heat exchange  with hot outlet gas.

     2.   Use of the heat in the hot outlet gas in some other part of the roofing
          products plant,  e.g., to make  steam  for  the  felt manufacturing line.

     Incineration can  be quite effective.  However, the  operating cost can  be
 high due to fuel consumption.

     Catalytic incineration units  have not been widely  applied  in this industry
 because  of rapid deactivation  of the catalysts,  caused by sulfur  and  heavy
 metals in  the asphalt.
Glass Fiber Mat Filters

     Glass  fiber mat filters  have been specifically  developed  to  control the
 emissions  from asphalt saturators.3  These filters consist of mats  made from
 glass fibers  and  bonded  together with  phenolformaldehyde  resins.  The mats
 are constructed so that they are compressible.  As air is passed through them
 they compress and effectively reduce the  size of the passages through which
 the  gas is  flowing.  This  compression  increases  the collection efficiency of
 the filter. Collection efficiencies above 90% can be achieved  at pressure drops
 of 16 to 18 in. w.c. (see Table 88) for increasing effluent velocities.3
Absorption Processes Using Chemical Oxidants

     Chemical oxidation has  been applied in  some locations to control hydro-
carbon  emissions. The oxidation  is carried out  in a  low energy wet  scrubber,
usually  of the conventional packed tower design. The circulating scrubbing liquor
is a  dilute  solution of  oxidizing  chemical such as  potassium permanganate.
These  systems can  be effective, but require  large  amounts  of  the oxidizing
chemical to achieve an  acceptable level of conversion and often produce  solid
and  liquid  waste  products  which must be disposed  of. The following sample
                                                                                         185

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reaction demonstrates these problems:

         2 KMnOa     + -(CH2)- -ป 2MnO2   + 2KOH
(aq)
(1)
                                          (s)
                                                                           + CO2
                                                                       (aq)       (g)
                       In  this example,  two  moles (316  Ibs)  of  potassium permanganate  are
                  required to oxidize one  mole (6 Ibs) of carbon and hydrogen, and the  reaction
                  produces  two  moles  (174 Ibs)  of solid  manganese dioxide waste, and one
                  mole (56 Ibs) of potassium hydroxide which must be neutralized prior to disposal.
                  SPECIFICATIONS AND COSTS

                       Specifications were written for systems to control emissions from each of
                  the two major sources in an asphalt roofing products plant: the asphalt saturator
                  and the asphalt blow still.
                  Asphalt Saturator

                      Specifications were written  for three types  of  control systems:  thermal
                  incinerators,  glass fiber  mat filters, and  absorption  using chemical oxidants.
                  In  each case, the specification requested  costs for two independent saturator
                  operations different from one another only in ventilation  rate.  The  two units
                  represent a  new,  low  ventilation  rate  design  and  an older, higher ventilation
                  rate design.  Production rate, saturant and felt  usage, and  process operating
                  conditions are assumed to be identical for the two cases.

                      Specifications for  absorption systems  using chemical  oxidants  are shown
                  in  Tables 79 and  80.  Averaged  capital and  operating costs are presented in
                  Tables 81 and 82  and in Figures 52  and 53.  The systems were bid assuming
                  that the  scrubbing liquor would  be  a dilute,  buffered  solution of potassium
                  permanganate. In this example, the costs of buffering and neutralization have not
                  been included. The consumption rates of permanganate reflected in the operating
                  costs presented in Table 82 are calculated values based upon theoretical reactions
                  equivalent to that shown at  the end of the previous  section. The costs shown
                  on this table  do not reflect field or laboratory data.

                      Incinerator specifications are  shown in Tables 83 and  84. Averaged capital
                  and operating cost data are presented in Tables 85 and 86 and in  Figures 54
                  and 55.  The specifications requested costs  at each  of two  levels of conversion;
                  98%  and 99%.  All of  the  bidders  responded with identical capital costs and
                  nearly identical operating costs for  these  two  cases. The  capital costs shown
186

-------
in Table 85 represent both conversion  levels.  The slightly different  operating
costs are reflected in Table 86 but could not be shown  in Figure 54. In addition
to cost  data, the specification requested  combustion  data from  the bidders.
The  averaged  responses to this  request are shown in the marked  places  in
Table 84.

     Glass fiber mat  filter specifications are shown in Tables 87  and 88.  These
specifications were transmitted  to the only available bidder who  supplied the
costs presented in Tables  89 and 90 and Figures 56 and  57. The specification
requested costs and  unit pressure drop at 98% (medium) collection  efficiency
and the expected pressure drop at 99% (high) collection efficiency. The pressure
drop information is presented in Table 88.
                                                                                         187

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                                                      TABLE 79


                                         SCRUBBER PROCESS DESCRIPTION

                                      FOR ASPHALT SATURATOR SPECIFICATION


                        A scrubber is to  control hydrocarbon  emissions  from  an  asphalt saturator.
                  Processing conditions and specifications are tabulated in Table 45.

                        The  scrubbing  liquor is to consist of a 3 wt % solution of potassium permanganate
                  buffered to 9.0 pH  with  borax. Materials of  construction  should be  consistent with
                  the permanganate solution. Bids should include the following Items:

                        1.  Low energy wet scrubber and mist eliminator.

                        2.  Necessary fans and motors.

                        3.  Twenty foot stack.

                        4.  Recirculating tank.

                        5.  Permanganate makeup and storage tank.

                        6.  Interconnecting ductwork for all equipment furnished.

                        7.  Appropriate control system.

                        8.  Necessary provisions for periodic cleaning of manganese dioxide residue.

                  All of the above, except the scrubber proper, should be treated as auxiliaries.

                        The  scrubber will  be located  on the  roof of the  existing facility.  A 60 ft. square
                  area  is  available for  new equipment next  to  the  asphalt  saturator vent  stack.
                  A  four inch  concrete  slab covers  the area.  All  utilities are  available  at the  site.
                  The sewer is available  and will accept water in the 4 to 10 pH range, if  it contains
                  less than 1 wt % solids content.

                        Neither the  cost of borax to be  used in buffering nor the cost of neutralization of
                  hydroxide ion prior to  discharge has been included.
188

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                                 TABLE @ฎ


                     SCRUBBER OPERATING CONDITIONS

                  FOR ASPHALT SATURATOR SPECIFICATION
           Siza

Process Conditions
    Gas Rate, ACFM
    Gas Temp., ฐF
    Gas Rate, SCFM
    Moisture Content, vol %
    Hcbn Emission Rate, Ib/hr

Gas from Scrubber
    Gas Rate, ACFM
    Gas Temp., ฐF"
    Gas Rate, SCFM
    Moisture Content, vol %'
    Gas Rate, DSCFM
    Hcbn Content, Ib/hr
    Hcbn Removal Eff.. wt %
 Small
22,600
   140
20,000
     4.0
    50
21,300
    95
20,300
     5.2
19,200
     8
    84
  Large
 52,800
    100
 50,000
      1.6
    50
50.500
     70
 50,500
     2.5
 49,200
     8
     84
"Supplied by bidder
                                                                                     189

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                                     TABLE 81

                            ESTIMATED CAPITAL COST DATA
                                (COSTS IN DOLLARS)
                                FOR WET SCRUBBERS
                              FOR ASPHALT SATURATOR


Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Cleaned Gas Contaminant Loading
Ib/hr
Cleaning Efficiency, %
( 1 ) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering
(b) Foundations -\
& Support
Ductwork
Stack I
Electrical /
Piping
Insulation
Painting J
Supervision
Startup
Performance Test
Other
(4) Total Cost
Medium Efficiency
Small







































Large







































High Efficiency
Small

22,600
140
20,000
4.0

50

21,300
95
20,300
5.2

8
84
12,787

7,670
1,418

8,120

4,661


15,000




35,000



1,000

3,000

88,656
Large

52,800
100
50,000
1.6

50

50,500
70
50,500
2.5

8
84
26,325

17,582
1,711

8,120

6,795


20,000




40,000



1,000

3,000

124,533
190

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                                 FIGURE 52

                       CAPITAL COST OF WET SCRUBBERS
                          FOR ASPHALT SATURATOR
    5

    4
J  I0:
LJ   Q

ฃ   7
8   6
    4
                                           TURNKEY COST
                                           COLLECTOR PLUS AUXILIARIES
   I04

                                           COLLECTOR COST ONLY
      10"
                          3   4   5   6  7 8 9 I05

                       CLEANED GAS  FLOW, ACFM
                                                                            191

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(O
ro
                                                  TABLE 82

                                         ANNUAL OPERATING COST DATA
                                              (COSTS IN $/YEAR)
                                             FOR WET SCRUBBERS
                                          FOR ASPHALT SATURATOR
Operating Cost Item
Operating Factor, Hr/Year 2,000
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify- Permanganate
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost


$6/hr.

$0.011/kwh
$0.25/MGal
$0.50/lb
16% of Cap
Medium Efficiency
Small






Large






High Efficiency
Small


1,200
1,200
100
100
1,746
6,000
1,276,000
1,283,746
1,285,046
14,185
1,299,231
Large


1,200
1,200
100
100
3,492
13,500
1,276,000
1,292,992
1,294,292
19,925
1,314,217

-------
           FIGURE 53

  ANNUAL COST OF WET SCRUBBERS
     FOR ASPHALT SATURATOR
b
5
A
3
2
1
d loฐ
0 9
Q
1- 7
S 6
o
5
4
3
2
in5



















\J



































































—


















•TA







—




Lt













NNUAL COST





































   3   4   5  6  7 8 9 I05

CLEANED GAS FLOW, ACFM
                                               193

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                                                       TABLE 83
                                    THERMAL INCINERATOR PROCESS DESCRIPTION

                                      FOR ASPHALT SATURATOR SPECIFICATION
                                                 (With Heat Exchange)
                        This specification  describes the requirements  of a thermal combustion system for
                   the abatement of hydrocarbon emissions from an asphalt saturator. Processing conditions
                   and specifications for small and large facilities are tabulated in Table 49.
                        The incinerator will be gas fired using natural gas available at a pressure of 1.0 psig,
                   having  a specific gravity of 0.6 and an upper heating value of 1,040 BTU/SCF. The
                   exhaust gas  from  the  saturator  will contain sufficient oxygen  to  allow firing  of  the
                   burner without the addition of a combustion air system.

                        A fan equipped with a V-belt drive will be required at the incinerator inlet.  The fan
                   will  have the capacity  to overcome  the pressure drop of  the  ductwork,  burner, and
                   heat exchanger.  The ductwork of the system  will be  sized  for a  maximum  AP  of
                   2 in. w.c. (hot).

                        The heat exchanger will be a counterflow shell and tube exchanger and be designed
                   to operate  at an incinerator outlet  temperature  of  1500ฐF.  The maximum exchanger
                   pressure  drop (shell side and tube side) will not exceed 6.0 in.  w.c.  The  contaminated
                   gas  will flow through the tube side.

                        The incinerator will be supplied with a suitable control panel. All equipment  will
                   be designed  for outdoor operation  and to meet the Factory  Insurance  Association's
                   standards.

                        The cost estimate will include the following items:
                             Incinerator
                             Burner
                             10 Ft. Stack
                             Controls
                             Control Panel
                             Structural Steel
                             Fuel Gas Piping
                             Electrical
                             Ductwork
                             Insulation
                             Fan
                             Fan Motor
                             Two-day Start-up Service
                             Heat Exchanger
                             Dampers
194

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      All Items,  with  the  exception of the Incinerator, burner, and heat exchanger,  will
be  considered  auxiliaries.  Vendors quotations should include  both price information
and the design information requested in the operating conditions section.

      The incinerator  will be located on the roof of the existing facility, and no modification
of the building  structure is required.  The duct run  from the asphalt saturator to  the
incinerator will be 80  ft. All utilities are  available  within 30  ft.  of the  control cabinet,
motor, and burner.
                                                                                                    195

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                                                     TABLE 84
                                   THERMAL INCINERATOR OPERATING CONDITIONS

                                      FOR ASPHALT SATURATOR SPECIFICATION
                                                 (With Heat Exchange)
                   Plant Size                                       Small

                   Process Conditions
                       Gas Rate, ACFM                            22,600
                       Gas Temperature, "F                            140
                       Gas Rate, SCFM                            20,000
                       Hcbn Emission Rate, Ib/hr                        50
                       Heating Value of Gas, BTU/SCF                    0.8
                       Heat of Combustion of Hcbn, BTUIIb            16,000

                   Incinerator Specifications

                       Residence Time @ Temperature, sec.                0.3
                       Inlet Tubeside Temperature, ฐF                    140
                       Incinerator Outlet Temperature,  ฐF"                678
                       Incinerator Inlet Temperature, ฐF"                  991
                       Burner AT from Fuel Gas, ฐF*                     484
                       Burner AF from Flame Combustion, ฐF"              3
                       Burner Outlet Temperature, ฐF'                  1,487
                       Unit A7 from Thermal Combustion, ฐF'              22
                       Burner Duty, mm BTU/hr'                         12.6
                       H.E. Duty mm BTU/hr'                            19.4
                       Thermal Efficiency Counterflow H.E., %             60
                       Overall Heat Transfer Coef, U'                      5.4
                       Tube Surface Area, Ft2'                        7,549
               Large
               52,800
                  100
               50,000
                  50
                   0.3
              18,000
                   0.3
                 100
                 657
                 974
                 511
                   1.5
               1,495
                  13.5
                  33.2
                  49.6
                  60
                   5.5
              18,332
                                              Case 1 - Medium Efficiency
                   Hcbn Emission Rate, Iblhr
                   Efficiency, wt %
                   1
                  98
                                               Case 2 - High Efficiency
                   Hcbn Emission rate, Iblhr
                   Efficiency, wt %
 0.5
99
 0.5
99
                   'Supplied by bidder.
                   "Assuming 10% conversion of fume in the flame
196

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              TABLE 85
     ESTIMATED CAPITAL COST DATA
         (COSTS IN DOLLARS)
TOIBEML INCINERATORS (WITH HEAT EXCHANGE)
       FOR ASPHALT SATURATOR


Effluent Gas Flow
ACFM
op
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
Ib/hr
Cleaned Gas Flow
ACFM
op
SCFM
Moisture Content, Vol. %














Cleaned Gas Contaminant Loading
Ib/hr
Cleaning Efficiency, %
( 1 ) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering
(b) Foundations ""
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup
Performance Test
Other >
(4) Total Cost


















>







Medium Efficiency
Small

22,600
140
20,000


50


678



1
98





Same As

High

Efficiency














Large

52,800
100
50,000


50


657



1
98





Same As

High

Efficiency














High Efficiency
Small

22,600
140
20,000


50


678



.5
99
120,775
9,565








5,900





88,725






224,965
Large

52,800
100
50,000


50


657



.5
99
269,850
19,845








12,600





130,435






432,730
                                                      197

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                                     FIGURE 54

               CAPITAL COST OF THERMAL INCINERATORS (WITH HEAT EXCHANGE)
                               FOR ASPHALT SATURATOR
                                   (High Efficiency)
D
5
4
3
2
1
-] I05
Q 9
* 8
t* 7
In '
0 6
U
5
4
3
2
in*



S
S
/
/











^i
/











/
r
t










jj
/
t











ef
,,/;
gx











i
/
/











FUR
cc
-C(










4K
ILL
i
3LL










•Y
EC
1
.EC








-

:OST
'OR PLUS AUXIUARI
TffeQ CrtCT OMI V













•s

























           10"
   3   4  5   6  7 8 9 I05

CLEANED GAS  FLOW, ACFM
4
198

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                                                     TABLE
                                            ANNUAL OPERATING COST
                                                  (COSTS IN $/YEAR)
                                    FOR THERMAL INCINERATORS (WITH HEAT EXCHANGE)
                                              FOR ASPHALT SATURATO.
Operating Cost Item
Operating Factor, Hr/Year 2 000
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost



$8/hr.


$6/hr.





$0.011/kwh
$0.7232/
1000 ft3




16% of Cap

Medium Efficiency
Small



1,280
1,280

240
400
640
150
150

1,243
20,144



21,387
23,457
35,994
59,451
Large



1,920-
1,920

480
1,100
1,580
350
350

2,970
53,184



56,154
60,004
69,237
129,241
High Efficiency
Small



1,280
1,280

240
400
640
150
150

1,243
20,160



21,403
23,473
35,994
59,467
Large



1,920
1,920

480
1,100
1,580
350
350

2,970
53,200



56,170
60,020
69,237
129,257
CO
CO

-------
                                       FIGURE 55

                ANNUAL COST OF THERMAL INCINERATORS (WITH HEAT EXCHANGE)
                                 FOR ASPHALT SATURATOR
                                     (High Efficiency)
         6

         5

         A
     -J  I05
     O  9
     Q  8
\-
8
O
         7
         6
                                               TOTAL ANNUAL COST

. TOTAL DIRECT COST
           10'
                          3    4   5   6789 I05

                       CLEANED GAS  FLOW, ACFM
200

-------
                                    TABLE 87


                 GMSS FIBER MAT FILTER PROCESS DESCRIPTION

                    FOR ASPHALT SATURATOR SPECIFICATION


     A glass fiber mat filter is to control hydrocarbon emissions from an asphalt saturator.
Processing conditions and specifications  are tabulated in Table 53. Bids should include
the following items:

     1.  Filter unit

     2.  Necessary fans and motors

     3.  Twenty foot stack

     4.  Interconnecting ductwork for all equipment furnished

     5.  Appropriate control system

All of the above, except the filter should be treated as auxiliaries.

     The filter will be  located  on the roof of  the existing facility.  A  60 ft. square area
is  available for new equipment next to  the asphalt  saturator vent stack.  A four Inch
concrete slab covers the area. All necessary utilities are available at the site.

     Vendor's quotation should  include  total price  information  and relevant  design
information,  including  the  expected  pressure  drop  across  the  unit at  the required
efficiency levels.   Vendor should  also specify  the   pressure  drop  which  would be
required to  achieve  99 wt   % collection efficiency,  but  need  not supply  price
information for these extra cases.
                                                                                               201

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                                                     TABLE 88


                                GMSS FIBER MAT FILTER OPERATING CONDITIONS FOR

                                         ASPHALT SATURATOR SPECIFICATION
                               Size

                   Process Conditions

                       Gas Rate, ACFM
                       Gas Temp., "F
                       Gas Rate, SCFM
                       Moisture Content, vol %
                       Hcbn Emission Rate, Ib/hr
 Small
22,600
   140
20,000
     4.0
    50
 Large
52,800
   100
50,000
     1.6
    50
                       Outlet Gas Rate, SCFM
                       Outlet Hcbn Rate, Ib/hr
                       AP Across Filter, in. w.c.'
                       Collection Efficiency, wt %
                                                Medium Efficiency Case
20,000
     1
    26
    98
50,000
     1
    26
    98
                       Outlet Gas Rate, SCFM
                       Outlet Hcbn Rate, Ib/hr
                       AP Across Filter, in. w.c.'
                       Collection Efficiency, wt %
                                                 High Efficiency Case
20,000
     0.5
 28-30
    99
50,000
     0.5
 28-30
    99
                   'Supplied by bidder.
202

-------
                TABLE 8ง
       ESTIMATED CAPITAL COST DATA
           (COSTS IN DOLLARS)
GLASS FIBER MAT FILTERS FOR ASPHALT SATURATOR


Effluent Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Effluent Contaminant Loading
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %
Cleaned Gas Contaminant Loading
Ib/hr
Cleaning Efficiency, %
( 1 ) Gas Cleaning Device Cost
.' . Fans and Startup Incl.
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering
(b) Foundations ^
& Support
Ductwork
Stack I
Electrical /
Piping 1
Insulation I
Painting J
Supervision
Startup
Performance Test
Other
(4) Total Cost
Medium Efficiency
Small

22,600
140
20,000
4.0

50

22,600
140
20,000
4.0

1
98
62,750



2,800
12,750




25,000



125,000




18,000



246,300
Large

52,800
100
50,000
1.6

50

52,800
100
50,000
1.6

1
98
108,650



6,900
25,500




40,000



155,000




18,000



354,050
High Efficiency
Small







































Large







































                                                         203

-------
                                      FIGURE 56
                        CAPITAL COST OF HIGH ENERGY AIR FILTERS
                                FOR ASPHALT SATURATOR
          6
          5
          4
                                                 TURNKEY COST
         I05
          9
          8
          5
          4
                                                 COLLECTOR PLUS AUXILIARIES
                                                 COLLECTOR COST ONLY
*ฃ
      8
                                3    4   5   6  7 8 9 I05
                             CLEANED GAS FLOW, ACFM
204

-------
ANNUAL OPERATING COST DATA
      (COSTS IN I/YEAR)
FOR GLASS FIBER MAT FILTERS
  FOR ASPHALT SATUftATO
Operating Cost Item _
I Cost
Operating Factor, Hr/Year 2,000 !
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
. Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost

$6/hr.

$6/hr.



$0.011/kwh

$0.05/MGal


16% of Cap

Medium Efficiency
Small

100
100

300
500
800
3,500
3,500
3,237

42
3,279
7,379
39,408
46,787
Large

100
100

300
500
800
7,500
7,500
7,547

168
7,715
16,115
55,648
71,763
High Efficiency
Small














Largs















-------
                                     FIGURE 57

                        ANNUAL COST OF HIGH ENERGY AIR FILTERS
                               FOR ASPHALT SATURATOR
id3
9
8
7
6
5
4
3
2
ฃ
3 'ฐ4
p 9
Q 8
ฃ e7
u
5
4
3
2
in3
























^
&



^
?S
0










,**
^

















^




X












pr
.TO!



*
)TAL!













AL<



HRE













MN
—

CT










—

JA



:os













.c


IT







—




33T




















































10
                       2      3    4   5   6  7 8 9 IO

                           CLEANED GAS  FLOW, ACFM
206

-------
                                    TABLE 91
                 THERMAL INCINERATOR PROCESS DESCRIPTION

                            FOR ASPHALT BLOW STILL
                               (With Heat Exchange)
      This specification  describes the requirements of a  thermal  combustion system
for the  abatement  of hydrocarbon emissions from  an asphalt blow  still.  Processing
conditions and specifications for small and large facilities are tabulated in Table 57.

      The Incinerator will  bo gas fired using natural  gas available at a  pressure  of
1.0 pslg, having a specific  gravity  of 0.6 and an  upper  heating  value of  1,040
BTUISCF.  The  exhaust gas  from the  blow  still  will  contain  sufficient  oxygen  to
allow firing of the burner without the addition of a combustion air system.

      A  fan equipped  with a  V-bett drive will  be required at the Incinerator Inlet.
The  fan will have  the capacity  to  overcome  the pressure drop of the ductwork,
burner,  and heat exchanger.  The ductwork of the system  will be sized for a maximum
&Pof2  in. w.c.  (hot).

      The heat  exchanger will be a  counterflow shell and tube  exchanger and be
designed to  operate  at an  outlet Incinerator temperature of  1500'F.  The maximum
exchanger pressure drop  (shell side and tube side) will not exceed  6.0  In.  w.c.
The contaminated gas will flow through the tube side.

      The Incinerator will be supplied with a suitable control panel. All equipment will
be  designed for outdoor  operation and to meet the  Factory  Insurance  Association's
standards.

      The cost estimate will include the  following Items:
          Incinerator
          Burner
           10 Ft. Stack
          Controls
          Control Panel
          Structural Steel
          Fuel Gas Piping
          Electrical
          Ductwork
          Insulation
          Fan
          Fan  Motor
          Two-day Start-up Service
          Heat Exchanger
          Dampers

     All items,  with the exception of  the incinerator, burner, and heat exchanger, will
                                                                                                207

-------
                    be  considered auxiliaries.  Vendors  quotations  should  include  both price  information
                    and the design information requested in the operating conditions section.

                         The incinerator will be located on the roof of the existing facility, and no modification
                    of  the  building structure is  required. The  duct run from the asphalt blow still to the
                    incinerator  will be 200 ft. All utilities  are available within 30 ft.  of the control  cabinet.
                    motor, and burner.
208

-------
                                   TABLE 92
                THERMAL INCINERATOR OPERATING CONDITIONS

                    FOR ASPHALT BLOW STILL SPECIFICATION
                              (With Heat Exchange)
Plant Size                                       Small             Large

Process Conditions

    Gas Rate, ACFM                            10,600             34,100
    Gas Temperature, ฐF                            210               210
    Gas Rate, SCFM                             8.400             27,000
    Hcbn Emission Rate, Ib/hr                       52               168
    Heating Value of Gas, BTU/SCF                    1.9                1.9
    Heat of Combustion of Hcbn, BTUIIb           18.000             18,000

Incinerator Specifications

    Residence Time @ Temperature, sec.               0.3                0.3
    Inlet Tubeslde Temperature, "F                   210               210
    Incinerator Outlet Temperature, ฐF'                720               723
    Incinerator Inlet Temperature, ฐF'                1,016              1,013
    Burner AT from Fuel Gas, ฐF'                     422               426
    Burner AT from Flame Combustion, ฐF"              5.5                5.5
    Burner Outlet Temperature, ฐF*                 1,468              1,468
    Unit Af from Thermal Combustion, ฐF*             56.5              56.5
    Burner Duty, mm BTU/hr'                          4.6              14.9
    H.E. Duty mm BTUIhr'                            7.7              24.7
    Thermal Efficiency Counterflow, H.E., %*"          60 (65^           60 (64.5)
    Overall Heat Transfer Coef, U"                      5.4                5.8
    Tube Surface Area, ft2'                        3,138             9,589
                             Case 1 - High Efficiency
Hcbn Emission Rate, Ib/hr
Efficiency, wt %
 0.5
99
 0.5
99
•Supplied by bidder.
"Assuming 10% conversion of fume in the flame
'"One bidder reported  higher thermal efficiency counterflow percentages  (shown In
parenthesis) than those specified.
                                                                                           209

-------
                                      TABLE 93

                              ESTIMATED CAPITAL COST DATA
                                  (COSTS IN DOLLARS)
                               FOR THERMAL INCINERATORS
                                FOR ASPHALT BLOW STILL
•
Effluent Gas Flow
ACFM
ฐF
SCFM




Moisture Content, Vol. %
Effluent Contaminant Loading
Ib/hr
Cleaned Gas Flow
ACFM
ฐF
SCFM
Moisture Content, Vol. %






Cleaned Gas Contaminant Loading
Ib/hr
Cleaning Efficiency, %
( 1 ) Gas Cleaning Device Cost
(2) Auxiliaries Cost
(a) Fan(s)
(b) Pump(s)
(c) Damper(s)
(d) Conditioning,
Equipment
(e) Dust Disposal
Equipment
(3) Installation Cost
(a) Engineering
(b) Foundations ~"
& Support
Ductwork
Stack
Electrical
Piping
Insulation
Painting
Supervision
Startup
Performance Test
Other
(4) Total Cost


















)







Medium Efficiency
Small







































Large







































High Efficiency
Small

10,600
210
8,400


52


720



.5
99
67,175
4,599








4,300





61,200






137,274
Large

34,100
210
27,000


52


720



.5
99
147,350
13,250








8, .800





95,275






264,675
210

-------
                                  FIGURE 58
                    COITAL COST OF THERMAL INCINERATORS
                           FOR ASPHALT BLOW STILL
    6
    5
    4
                                 TURNKEY COST
J   I05
O   9
    Q
    5
    4

    3
                                 COLLECTOR PLUS AUXILIARIES
                                 COLLECTOR COST ONLY
       ^
      10'
   3    4   5   6  7 8 9 I05
CLEANED GAS  FLOW, ACFM
                                                                             211

-------
to
                                                    TABLE 94

                                           ANNUAL OPERATING COST DATA
                                                 (COSTS IN $/YEAR)
                                            FOR THERMAL INCINERATORS
                                             FOR ASPHALT BLOW STILL
Operating Cost Item
Operating Factor, Hr/Year 2,000
Operating Labor (if any)
Operator
Supervisor
Total Operating Labor
Maintenance
Labor
Materials
Total Maintenance
Replacement Parts
Total Replacement Parts
Utilities
Electric Power
Fuel
Water (Process)
Water (Cooling)
Chemicals, Specify
Total Utilities
Total Direct Cost
Annualized Capital Charges
Total Annual Cost
Unit
Cost

$8/hr.
$6/hr.

$0.011/kwh
$0.7232/
1000 ft3
16% of Cap
Medium Efficiency
Small






Large






High Efficiency
Small

1,280
1,280
240
400
640
150
150
781
7,360
8,141
10,211
21,964
32,175
Large

1,280
1,280
240
600
840
200
200
2,497
23,880
26,377
28,697
42,348
71,045

-------
             FIGURE 59

ANNUAL COST OF THERMAL INCINERATORS
      FOR ASPHALT BLOW STILL
           TOTAL ANNUAL COST.
            TOTAL DIRECT COST
     3    4   5   6 7 8 9 I05

  CLEANED GAS FLOW, ACFM
                                                      213

-------
                                                 REFERENCES
                  1.    "A Screening Study  to Develop Background Information to Determine the
                       Significance  of  Asphalt Roofing Manufacture"  EPA Contract 68-02-0607,
                       Task 2, Research Triangle Institute, Dec., 1972, Research Triangle Park,
                       North Carolina.

                   2.   Air  Pollution  Engineering  Manual,  U.S.  Dept.  of  Health Education  and
                       Welfare, Public Health Services  Publication No. 999-AP-40, Cincinnati, Ohio,
                       1967.

                   3.   Qoldfield, J.;  Gandhi,  K.;  "Glass  Fiber Mats  to Reduce  Effluents  from
                       Industrial Processes,"  Journal  of  the  Air  Pollution  Control  Association.
                       July, 1970, Vol. 20, No. 7, pp. 466-469.
214

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 7.    SURFACE COATING OPERATIONS

      The term  "surface  coatings"  applies to  a great many  different coating
 materials,  both  organic and  inorganic, and  different  application  technologies.
 The air  pollution control problems which accompany each type of coating and
 application method are correspondingly different from one another. This discussion
 has been limited, by the scope of the  contract  under which it was prepared, to
 organic coatings and application technologies which involve solvent evaporation
 or other vapor phase organic emission.

      The basic  purpose of an organic coating is to form a film  over a  substrate
 which will  cohere to itself and  adhere to  the  surface  over which  it is applied.
 In current  times, the usefulness of  organic coatings has been  widely  extended
 from  simply a protective (weather and corrosion) function to diverse applications
 which include:
      1.  Electrical insulation
     2.  Lubricity
     3.  Temperature control
     4.  Fire retardency
     5.  Control of marine fouling
     6.  Sound  deadening

     Currently,  most  organic  coatings are  formulated  with  synthetic resins
 which can be tailored to solve a particular finishing problem. They can be applied
 to a surface by  a number of operations including dipping, spraying, flow-coating,
 and roller coating. Furthermore,  combinations of these operations, each  designed
 for a specific task, are found.
             SCIENTIFIC PRINCIPLES OF COATING FORMATION

     The  surface coating process consists of the  conversion of the solutions or
melts of film-formers to the amorphous state and  the fixation of the film as it is
formed to  a particular substrate.

     Film-formers may be classified into those which transform during the coating
operation and those which do not transform.
Formation of Non-Transforming Coatings

     The theory of the mechanism of film-forming for these materials, which include
cellulose esters, perchlorvinylic types, and many others, states that when solvent
is  evaporated from  solutions of  compounds of low molecular weight  resins,  the
                                                                                        215

-------
                   film-formers  are  converted to the  amorphous  state. The conditions  for  pure
                   solvent evaporation must  be differentiated from those  for solvent evaporation
                   from  solutions, particularly from solutions of high molecular weight compounds.
                   For lacquers, the evaporation rate may be given as:

                                          g = 2g0x      (grams/m2/min)1                     (1)

                   where go is the evaporation rate for an individual constituent  and x is the mole
                   fraction of that constituent in the original solution.

                        Empirical evidence indicates, for the majority of solvents,  the evaporation of
                   the first 90 percent can be expressed by

                                                      L = cT                                (2)

                   where L is the percent of solvent lost, c and m are constants that are characteristic
                   of the solvent, and t is the time. The remaining 10%  evaporates slowly, and
                   its  evaporation  does  not  obey  the  above  equation. Pigments have  different
                   effects on evaporation rates. Coarse-particle pigments will accelerate evaporation,
                   whereas finely dispersed pigments retard it.
                   Coatings Formed by Transformation

                        The transformation of monomers  or  linear polymers to three-dimensional
                   polymers usually takes place as a result of the following processes:

                        1.   Polycondensation  (in phenol-aldehyde resins, and for coatings dried by
                            heat).
                        2.   Polymerization or copolymerization at the sites  of unsaturated bonds,
                            either directly or through the agency of oxygen.

                   Many film-forming substances will transform  as a result of both of these processes.
                   PROCESS DESCRIPTION
                        There are several common methods by which surface coatings are applied:
                   dipping, spraying,  flow  coating, and  roller coating.  In modern industry, these
                   methods are applied to a large number of different types of coating materials,
                   such as those listed on Table 95. Some of these processes, such as  dipping
                   and flow coating, have become obsolete in some industries as newer, inorganic
                   systems are developed.
216

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                                                               TABLE 95

                                               EXAMPLES OF SURFACE-COATING FORMULAS
                                                       ON AN AS-PURCHASED BASIS
                                                                        Hydrocarbons

Type of
Surface Coating
Paint
Varnish
Enamel
Lacquer
Metal Primer
Glaze
Resin*
Sealer
Shellac
Stain
Zinc Chromate
Non-
Volatile
Portion
44
50
58
23
34
80
50
50
50
20
60


Aliphatic
56
45
10
7
33
—
—
40
—
—
—


Aromatic
—
5
30
30
33
20
—
—
—
80
40


Alcohol
—
—
2
9
—
—
—
—
50
—
—
                                                                                            Ketones
Esters
  &
Ethers
                                                                                              22
                                                                                                           10
                      "Contains 50% solvent of an unspecified type.
ro
-vl

-------
                  Paint Dip Tanks

                       In  this method of  application, an  object  is immersed  in  a simple paint
                  container and  then removed. These containers frequently have conical bottoms.
                  The  excess paint is drained  from the object back to the dip  tank, either  by
                  simply suspending  the object over the container or by using drainboards that
                  drain  back to  the dip  tank. Agitation  is necessary  in  order  to  keep the paint
                  mixture  uniform. The most common agitation  method consists of pumping paint
                  from the bottom of the tank to some point near the  tank top, but still under the
                  liquid surface.
                  Flow Coating Machines

                       Flow coating consists of flowing paints in a steady stream over objects that
                  are suspended  from a conveyor line. The  paint is  recirculated by a pump from
                  a drain basin  back to the paint nozzles.
                  Roller Coating Machines

                       Paint  roller coating  machines  usually have three or  more  power-driven
                  rollers and are quite similar to printing presses in their construction. Paint is
                  transferred from the first roll, which is partially immersed in the paint, to a second
                  roll which  is running parallel to it.  The sheet work to be coated is run between
                  the second and third roll and is coated by transfer of paint from the second roll.
                  The quantity  of paint applied  is determined by the distance between the  rolls
                  through which the sheet passes.
                  Spraying

                       In spraying operations, a  spray gun usually operated by compressed  air,
                  is used to spray the paint on the object to be painted.  In order to insure that an
                  explosive concentration  of solvent  vapor does not occur and to  protect  the
                  health of the spray  gun  operator,  a booth or enclosure ventillated  by a  fan
                  provides  a means  of  ventilating the  spray area. Table 96  shows  threshold
                  limit values of typical paint  solvents. These values are average concentrations
                  to which  workers may be safely exposed for an 8-hour day without adverse
                  effect on their health.

                      The  spray booth may  also be  equipped  to filter incoming air as well as
                  remove paniculate matter from the exhausted air.
218

-------
                               TABLE 96

                          LIMITING VALUES OF
                       TYPICAL PAINT SOLVENTS
Acetone
Amyl Acetate
Methyl Ethyl Ketone
Butyl Acetate
Cellosolve
Cellosolve Acetate
Ethyl Acetate
Ethanol
Naphtha (Petroleum)
Toluene
Xylene
Mineral Spirits
Lower Explosive
Limit (LEL)*
%
2.15
1.1
1.81
1.7
2.6
1.71
2.18
3.28
0.92 to 1.1
1.27
1.0
0.77
25%
LEL
ppm
5,400
2,750
4,525
4,250
6,500
4,275
5,450
8,200
2,300
3,175
2,500
1.925
Worker Threshold
Limit Values"
ppm
1,000
200
250
200
200
100
400
1,000
500
200
200
500
 •Adapted from:  Factory  Mutual  Engineering Division,  Handbook  of  Industrial
 Loss Prevention, McGraw Hill Book Co., Inc. NY, 1959.

"Adapted from: American Medical Association Archives of Environmental Health,
 14:186-89, 1956.
                                                                                   219

-------
                       The chief advantages of spray painting are the speed of painting and the
                  comparative ease of obtaining a relatively smooth finish; the chief disadvantage
                  is  the waste of material that can occur.  A considerable quantity of paniculate
                  matter  results from the use  of the common air atomization type spray gun. A
                  60 percent overspray of an object  is quite  common. Paniculate  matter in paint
                  spray booths is controlled  by baffle plates,  filter pads,  or  water  spray curtains.

                       The discharge from spray  booth operations  consists of paniculate  matter
                  and organic-solvent vapors. The particulate matter concentration seldom exceeds
                  0.01  grain  per  SCF of  unfiltered  exhaust. The location of the exhaust stack is
                  extremely important so that  paint spotting on neighboring property is avoided. The
                  solvent concentration in spray booth effluent varies from 100 to 200 ppm. Depending
                  on the extent of operation, the solvent emission out of the spray booth stack will
                  vary  from less  than 1 pound per day to 3,000 pounds  per day. Solvent vapors
                  will take part  in photochemical smog reactions leading to products that result
                  in eye irritation. Odors also cause local nuisances.
                  TYPES OF SPRAY BOOTHS

                  Dry Type Booths

                                            Dry Baffle Spray Booths

                      This type of booth is especially suitable for spraying small objects which are
                  manually loaded and unloaded  through the front opening.  Overspray adheres to
                  the face of baffles or is trapped  in eddies of air striking the  rear surface of baffles.
                  The auxiliary equipment would consist  of an exhaust fan  with  electric motor,
                  light fixtures and the exhaust chamber.


                                              Paint Arrester Type

                      This is similar to the  dry  baffle type except that air-borne  paint  particles
                  from exhaust air are removed by means of disposable filters. This unit is  used
                  mainly for  intermittent spray  operations;  such as, refinish shops, schools, and
                  production lines where paint consumption is moderate.


                                              Dispo Spray Booths

                      In the "dispo" type of booth, maintenance and cleaning time are reduced to a
                  minimum. The booth may be used for heavy or light production spray operations.
220

-------
The entire  back-end of the booth  is covered  with  a felt material that collects
over-spray and particles as  the  exhaust air is  drawn through it. As the filtering
media becomes loaded with  overspray and  the  differential  in  static  pressure
rises to a preset point, fresh media is rolled down by a power drive.  The usage
of filter media is directly proportional to paint load. Auxiliaries include the customary
exhaust fan, lighting, filter media, and exhaust duct components.
Water Wash Spray Booths

     These are the most widely used and most versatile type of booth. One of
the primary benefits  of  this type of booth is that when  articles being sprayed
are of convenient  size  (up  to  and including  motor  vehicle  bodies) the  booths
will permit spraying to be  conducted in  the same workshop  as other operations
of both a mechanical and finishing nature.

     The  main feature of this type of booth is a powerful scrubbing action with a
deluge of  water which  removes  paint or resin  particles from the exhaust air.
The design of the  nozzles and their spacing  provide a curtain of  coarse water
droplets that  trap the particles and carry  them into a tank for easy  removal.
Baffles, which are  positioned between the washing  area and the  exhaust fan,
are so positioned as to remove  any free water before it reaches the stack. When
the air is  discharged,  it is essentially free  of  resin  and water particles and will
contain only organic solvent vapor as a contaminant. Figure 60 shows a typical
water wash spray booth.

     Water wash sprays are available in a great variety of capacities to efficiently
remove air-borne resin particles resulting  from spraying operations. In general,
standard  duty chambers provide  sufficient washing capacity for  maintenance
painting or moderate speed conveyorized  jobs,  while heavy  duty chambers
provide extra air washing  capability for high production applications  involving
high coating rates.

     Standard air velocities of 125 and  150 feet per minute  are offered to meet
industry and  code  standards.  Generally,  125  feet per  minute  meets  most
requirements.  One  hundred and fifty feet per  minute is available for heavy-duty
application or where preferred or specified by industry  and codes.
Down-draft Spray Booths

     Figure 61 shows a down-draft water wash  spray  booth. This type of booth
is  particularly  suited for production finishing  in many industries; highly adaptable
to  all kinds of production requirements and plant layouts. The salient features
of  this device are:
                                                                                          221

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                                                   EXHAUST
                                                              SrfOTOR
                                                                   WATER
                                                                   SPRAY
                                                                 RECIRCUL.ATING
                                                                     WATER
                                          FIGURE 60
                                   WATER-WASH SPRAY BOOTH
222

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                          EXHAUST
                              t
                        FAN

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                                        'WATER
                                         SPRAY
                                        RECIRCUL.ATING
                                            WATER

                 FIGURE 61


               DOWN-DRAFT
         WATER WASH SPRAY BOOTH
                                                         223

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                        1.  The tank of water immediately below the grilled floor where spray particles
                           settle.
                        2.  The water that cascades down the  spill sheet of the chamber.  This
                           rapidly-flowing water-curtain removes more resin particles from the air.
                   This  type  of spray booth  is  available without enclosure, with semi-enclosure,
                   and  with complete enclosure where spray operators  can work all around the
                   object being sprayed.
                  The Electrostatic Coating Booth

                       The principle of  electrostatic spraying is based on  the familiar physical
                  law  that like charges repel  and unlike charges attract. Atomized paint particles
                  are given a negative charge while the product is  maintained at ground potential
                  and is positive in relation  to the negative paint particles.  If  some  of the charged
                  paint particles bounce off or miss the product, they reverse themselves back
                  to the  product because  of  the attraction due to the  electrostatic  field.  The
                  obvious  advantage of electrostatic  spraying is  a much  greater  efficiency  of
                  paint utilization by  minimizing overspray. Spray booth  and duct maintenance are
                  correspondingly reduced.
                  Other Spray Booths

                       Various other types of spray booths are available for particular operations.
                  Included in this list are:
                       1.  Auto-truck and truck-trailer booths.
                       2.  Automatic spray booths.
                       3.  Degreasing booths.
                       4.  Cleaning booths.
                       5.  Bench and leg booths.
                       6.  Ceramic spray booths.
                       7.  Traveling spray booths.
                  Detailed descriptions of these booths  are best found by referring to manufacturers'
                  literature.
224

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ORGANIC EMISSIONS FROM PROTECTIVE COATING OPERATIONS

     The emissions from  protective coating operations  consist of  participates
and volatile organic solvents. The Air  Pollution  Control District of Los Angeles
conducted  a survey in  1955, supplemented in  1957, in order to determine the
quantities, types and sources of organic compounds in the Los Angeles County
atmosphere, exclusive of motor vehicle emissions. Results indicated that protective
coating operations accounted for 55  percent of the total organic emissions. This
figure  accounted for 470,000 pounds of organic vapors being emitted daily into
the atmosphere.

     The range of average  concentration of organic vapors from protective coating
operations  has been determined  from a survey  by the Air Pollution Control
District of Los Angeles County to be 100 to 200 parts per million. These values
are  lower  than those  allowed  by  safety requirements,  based  on the  lower
explosion limit of the individual compounds. Fire prevention  regulations usually
require that organic emissions not  exceed 25% of  the  lower  explosion limit.
For  toluene, which  has wide use  in finishes,  this would  be  about 3,000 parts
per million. (See Table 96). Although the organic vapors exist at  low concentrations,
low  partial  pressures, and  low dew  points, their  presence is still significant as
far as air pollution  control  is  concerned. Any abatement method developed for
recovery of low concentrations would  probably be  applicable as well  as more
attractive economically  in  those  operations  where high  concentrations  are
encountered.

     The exhaust air rate giving rise to hydrocarbon emissions from surface coating
operations  is fixed  by insurance standards to  be  not less  than 100  feet  per
minute  per  square foot  of booth  opening.  The  usual  spray booth ventilation
rate is 100 to 150 feet per minute.

     Paniculate matter,  consisting  of fine paint  particles,  is  emitted in surface
coating operations.  Their presence is quite important, from the point of view of
controlling organic  solvent  emissions, because they interfere  with the operation
of abatement systems designed to control organic emissions. The concentration
of these particles  seldom  exceeds  0.01  grain  per SCF  of  unfiltered  exhaust.
POLLUTION CONTROL CONSIDERATIONS FROM SURFACE COATING
OPERATIONS

Paniculate Matter

     The fraction of paint that is not deposited on  an object during  the use of
the common air atomization  spray  gun  is  called overspray.  Overspray  may
                                                                                       225

-------
                be  as high  as 90  percent;  however, 60  percent is more common. Particle
                emissions from spray booth operations are controlled by baffle plates, filter pads,
                or water spray curtains. The  efficiency of baffle plates and filter  pads can  be
                as high as 90%. Water curtains are satisfactory for removing paint particulates
                with efficiencies up to 95%. A  water  circulation rate  of 10 to 38 gallons per 1,000
                cubic feet of exhaust air is customary for this use.
                Control of Organic Emissions

                     Two techniques  are available for limiting  the  emission  of organic solvents
                from surface coating operations. These include:

                     1.   Process modification

                     2.   Pollution control with or without solvent recovery
                                                                            ^
                Under "process  modification" there are  two conventional alternatives. Emissions
                can be reduced  by a factor of two or  three by switching to  electrostatic spraying,
                or the composition of the solvent system may be  altered so  as to make  it
                exempt from Rule 66.* Table 97 is an example of substitution of exempt solvent.

                     If none of  the alternatives are  possible,  then add-on pollution abatement
                equipment is required.

                     The known methods for pollution control with  solvent recovery include the
                following: condensation by cooling, condensation by  compression,  absorption and
                stripping, and adsorption.
                                         Condensation by Cooling

                     Scheflan  and  Jacobs7 indicate  that  solvent  recovery  by  refrigeration  is
                practical  only  to  mixtures where the hydrocarbon  to be recovered  is  present
                in greater amounts than 50,000  ppm. Since  the concentration of hydrocarbon
                solvent in spray booth emissions  is between 100 and 200 ppm, it is  quite clear
                that  this  method  is  not  applicable.  For  detailed  calculation  see LAAPCD
                Report #86.
                                      Condensation by Compression

                     In order to demonstrate the  applicability of this approach to spray booth
                emissions, consider toluene to  be the organic pollutant  of  interest. The partial
                pressure of toluene at 68ฐF in a surface coating operation is 0.08 mm  Hg (100
                •Rules and Regulations, County of Los Angeles Air Pollution Control District.
226

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                              TABLE 97
                 SUBSTITUTION OF EXEMPT SOLVENT
Typical Solvent Formulation
      Acetone
      Toluene
      Cellosolve Acetate
Vol. %
  25
  50
  25
Limit Under Rule 66
     Exempt
=s20% in Aggregate
     Exempt
                                         100
Exempt Solvent Formulation
     Acetone
     Benzene
     Toluene
     Paraffinic Hydrocarbon
     Cellosolve Acetate
          Limit Under Rule 66
               Exempt
               Exempt
               =s20%
               Exempt
                                                                                227

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                   ppm toluene in air at 68ฐF). Removal  of  90% of  the  toluene at 68ฐF  by
                   compression would require increasing the total pressure on the system to 12,000
                   psi. This would require a  six-stage compressor with a power requirement of
                   (assuming 75% efficiency) 72 hp/1000 ACFM. Both capital and operating costs
                   for such a system would be prohibitive for most cases.
                                                   Absorption

                        According to Ray,5 when  the  concentration of  an organic vapor  to  be
                   recovered is  low enough to be safe, then recovery by mineral oil  absorption
                   is relatively inefficient and expensive. As far as absorption with water is concerned,
                   it is known that lower molecular weight  alcohols  and ketones  have varying
                   degrees  of solubility  in  water.  However,  the  major portion  of  paint  thinners
                   and diluents  is either  mineral spirits or toluene,  and they do not  have great
                   solubility in water.

                        In general, control  of  solvent emissions  by means of absorption is  not
                   practical,  because the extremely low vapor concentration results in a high capital
                   cost  for  the  scrubbing tower, the  stripping  tower, and  the numerous  heat
                   exchangers required.
                                                   Adsorption

                       Activated carbon appears to be the adsorbant most suitable for recovering
                  the  organic  solvent vapors  emitted  from spraying operations. Since  activated
                  carbon  will  adsorb all the usual low boiling solvent vapors, it can be  used for
                  recovery of any or all low boiling solvents vaporized in surface coating operations.

                       Various  systems have  been  employed  for  carbon adsorption.  Figure 62
                  shows a schematic  layout for a  paint spray application. The  adsorption system
                  shown would require a fan or blower to remove the vapor-laden air, two drums
                  containing  a  bed of activated  carbon which  would be used  alternately  (one
                  adsorbing the other being regenerated), a condenser, and some sort of decanter.
                  Controls are  also necessary to  switch air flows  to the adsorbers and control
                  the desorption stream.

                       There is no question that  activated carbon can be  used to remove organic
                  vapors from  a gas  stream by  adsorption. The "rule-of-thumb" is  that about 1
                  Ib of carbon  is  needed  for  1  ACFM  going  through  the recovery unit. If  the
                  concentrations of the organic vapor are very  low,  this  ratio can be reduced to
                  1/4 Ib/ACFM.  Another  "rule-of-thumb" is that the carbon will adsorb 10 to 20%
                  of its own weight, at which time desorption will be necessary.
228

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           AIR
                                                 CLEAN AIR
      DO
iWNt

 SEE
         BOOTH
                                  FILTER
                                                   f  I
                                                                    STEAM
                                                  ง5
                                                   TT   T
                                           CAR]
                                                           N
                                                  ADSORBERS
                                                                                        RECOVERED

                                                                                         SOL-VENT
                                                                          SEPARATION
                                                                CONDENSER
                                                                          CONDENSATE
                                                FIGURE 62




                              SCHEMATIC OF CARBON ADSORPTION & DESORPTION UNITS
ro
ro

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                      There  are several  factors which influence the capacity  of  a carbon bed
                 for adsorption of an organic solvent:

                      1.  Temperature — the higher the temperature, the lower a bed's capacity.

                      2.  Concentration — the  higher the concentration of organic vapor in gas
                          stream, the higher the capacity.

                      3.  Solvent  boiling  point — higher solvent boiling point increases capacity.

                      4.  Contact time — other things being equal,  the longer the contact time,
                          the greater the capacity.

                      5.  Humidity — high humidity will decrease capacity.

                      The  Air  Pollution   Control  District   of   Los  Angeles  conducted
                 an extensive  pilot plant  study  of carbon  adsorption  for the removal of organic
                 solvents from  spray  booth  operations. Table 98  shows  the results  of sizing
                 several adsorbing units  with  varying capacities. The main conclusion of their
                 study was that the control of organic emissions from  protective coating operations
                 was  technically feasible using adsorption on activated carbon.

                      There  has been  a significant amount of recent process development  in
                 carbon  adsorption  systems in  order to  make them more  economical.  These
                 developments have taken two primary  forms:

                      1.  Integration of the carbon  adsorption  process with the surface coating
                          process.  For example, using paint bake oven  exhaust gas  to desorb
                          the recovered  solvent from  the carbon  bed, or using the  heat in a
                          regeneration stream to reduce fuel costs in a surface coating oven.

                      2.  Using the carbon  adsorption  process to  reduce the volume of the
                          solvent  laden  exhaust gas  to  be treated  by other pollution control
                          systems. For example, thermal incineration can be more economical when
                          applied to the  desorption  stream  from a carbon  bed rather  than the
                          untreated process exhaust  gas stream.

                      The details  of these  developments  are outside the  scope of this paper.
                 They are mentioned here to demonstrate the  increasing applicability  of carbon
                 adsorption processes to emission control in this industry.
                                                 Incineration

                 Thermal Combustion

                      Thermal incineration involves direct  burning  of the effluent in a gas-fired
230

-------
                                 TABLE 98

                SUES FOR SOLVENT RECOVERY SYSTEMS
                       USING ACTIVATED CARBON*
Spray Booth
Capacity
Adsorbing
Unit"
Carbon Bed
Diameter*"
(in.)
Total
Carbon Weight
(Ib)
Solvent
Recovered
(Ib/day)
                      (1)
      1,000           (2)
      cfm             (3)       30             f      153            13
                      (4)

                      (1)       96
      5,000           (2)       68
      cfm             (3)       68             f      755           64
                      (4)       48 (cone ht, 42") I

                      (1)      156
     10,000           (2)       96
      cfm             (3)       96             [1,510           128
                      (4)       60 (cone ht, 150")]

                      (1)      192
     20,000           (2)      156
      cfm             (3)      156             f   3,000           257
                      (4)       96 (cone ht, 192"))

                      (1)      302
     50,000           (2)      216
      cfm             (3)      216             (   7,550           642
                      (4)      144 (cone ht, 312")
"Operating conditions: solvent toluene at concentration of 150 ppm (=2.18 lb/hr/1000 cfm);
desorption with superheated steam for 2 hr. 45 min., using 13 Ib steam/lb solvent recovered;
carbon retentivity, 81/z Ib solvent/100 Ib carbon; work, one 6-hour shift per day, 5 days per week;
duct velocity, 2500 fpm; adsorber velocity, 100 fpm.

"Adsorbing units:  (1) single unit, single flat bed; pressure drop,  2.1 in. H2O
                  (2) double unit, single flat bed; pressure drop, 2.1 in. HzO
                  (3) single uhit, two flat beds; pressure drop, 10.0 in. H2O
                  (4) single unit, vertical cone bed; pressure drop, 3.1 in.

'"Carbon bed depth, 5.7 in. all units.
                                                                                             231

-------
                 incinerator. Although simple in concept and operation, there is actually a  great
                 deal of design, engineering, and  manufacturing  skill involved. The process of
                 thermal incineration  is outlined  by the flow  diagram shown in  Figure 63. The
                 solvent laden air from the spray  booth  enters the thermal system where  it is
                 preheated  to  600ฐF  to 900ฐF and then incinerated in the residence chamber
                 at 1000ฐF  to  1500ฐF. The fumes, when properly incinerated,  evolve as carbon
                 dioxide, water, and heated air.  Fuel costs can be held to a minimum through
                 the use of heat exchange and recirculation of heated air. Thermal combustion is
                 capable of achieving a high level of effectiveness for removal of organic emissions.
                 Systems can operate continuously at efficiencies of 90% to 100%.  Combustion
                 temperatures vary according to the  solvent and  its concentration.  Auto-ignition
                 data,  which  are  available for  many  organic  solvents, can serve  as a  rough
                 guide  to the  relative difficulty  of  combustion;  however, having been obtained
                 under  optimum combustion conditions,  they  are  not  a wholly adequate index.
                 Catalytic Incineration

                      An oxidation  catalyst may be  used to reduce the combustion temperature
                 required for incineration. Combustion of organic emissions in a catalytic incinerator
                 may be self-sustaining, given sufficiently high contaminant concentrations  and
                 effluent temperatures.  Suter4  indicates  that,  where heat  contents  are of the
                 ordr 10 BTU/ft3 or more,  recycling part of the  effluent  from the catalyst for
                 preheating becomes practical.

                      Emissions from surface coating operations exist at very low concentrations
                 (see Table  96) due  to limitations  imposed  by  fire  insurance  and industrial
                 health  regulations.  Because  of  this fact,  it is reasonable to suppose that  a
                 preheat burner would be necessary, and this would deter from  the attractiveness
                 of catalytic incineration.
                 GENERALIZED ECONOMICS FOR SURFACE COATING OPERATIONS

                      Figures  64 through 69 show the operating cost and total cost  (operating
                 cost plus  10%  of total  installed system cost)  for five pollution control systems
                 for  surface  coating  operations.  In  each  case,  the concentration  of solvent
                 (assumed  to  be toluene) is  100 ppm. For small systems  (500 to 1000 SCFM),
                 catalytic incineration  with heat  exchange is the most economical method. This
                 is due to the following factors:

                      1.  Credit  for solvent  recovery  is too small to make  carbon adsorption
                         attractive.
232

-------
                FJL.TE1R
      EMISSIONS
                         Bt-OWER
    HEAT
EXCHANGER
 r       r
SPRAY BOOTH
                                                       -SB*
INCINERATOR
                                    FIGURE 63
                  FLOW DIAGRAM OF THERMAL INCINERATION SYSTEM

-------
                        2.  The  fume  concentration  is  low,  making  natural  gas  requirements
                           high, which consequently, rules out thermal incineration.

                        For larger systems (greater than 1000 SCFM), carbon  adsorption is the
                   most economical  method. This  conclusion does not depend upon obtaining  any
                   credit for solvent  recovery. The economic advantage of carbon adsorption  over
                   any  incineration  method  is strictly due  to its lower  total cost as  compared
                   with the other methods.

                        Figures 70 through 73 show the operating cost and total  cost for the same
                   pollution  control  systems at a solvent  concentration  of  1000 ppm. If credit
                   for solvent recovery  is not considered a factor, then for systems up  to 10,000
                   SCFM, catalytic incineration would  be the most economical method.  However,
                   if credit for solvent recovery is considered, then carbon adsorption is the method
                   of choice for all systems at this fume concentration.
234

-------
                                FIGURE 64
                   ANNUAL COST  FOR CARBON ADSORPTION
                    FOR SURFACE COATING  OPERATIONS
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-------
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-------
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-------
                              REFERENCES
 1.  Drinberg, Gurevich, and Tikhomirov,  Technology of Non-Metallic Coating,
     Pergamon Press, N.Y.C., 1960, p. 54.

 2.  Hardison,  L.  C.,  Controlling  Combustible Emissions, Paint and  Varnish
     Production, July 1967.

 3.  Gadowski, R. P., David, M. P., Blahut, G.A., Evaluations of Emissions  and
     Control  Technologies  in The Graphic Arts Industries, Final Report,  EPA
     Contract CPA 22-69-72.

4.    Suter, H. R., "Range  of Applicability  of  Catalytic Fume Burners",  LAPCA,
     March, 1955, pp. 173-175.

5.    Ray, Arthur  B., "Recovery  of  Solvent Vapors", Chem and Met  Eng,  47,
     May 1940, pp. 329-332.

6.    Experimental  Program for the Control of  Organic Emissions from Protective
     Coating  Operation, Final Report No. 8, Air Pollution Control District of  Los
     Angeles.

7.    Schflan,  L. and Jacobs, M.  B., The Handbook of Solvents,  New York,
     Van Nostrand, 1953.
                                                                                             245

-------
                   C.   ADDITIONAL COST DATA

                        The previous section of this report dealt with the cost of air pollution control
                   systems for seven specific  processing  applications. This section deals with the
                   generalized correlation of  costs for each type of control system for all seven  of
                   the process applications discussed. The  discussion is divided into four parts:

                        1.  A discussion of  the  annual  operating  cost  basis,  including both the
                           direct and capital charge portions of this cost.

                        2.  A discussion of the effects of utility price levels on overall costs.

                        3.  Derivation of capital cost indices for each specific  process  application.

                        4.  Generalized  graphical  correlations of capital  and  operating  costs  for
                           each type of control system.


                   1.    Discussion of Cost Basis

                        As noted in the introduction to this report, the total annual cost for a particular
                   control system is the  sum of the direct  annual operating cost and an annualized
                   capital charge.

                        In the previous section of  this report the  annual direct  operating costs  for
                   air pollution  control systems in  specific processing  applications were calculated
                   using  estimates supplied by the equipment manufacturers. These estimates were
                   prepared in  terms of the  quantity of each  operating cost item  required,  rather
                   than the cost. A standard price was applied to these estimates by the coordinating
                   engineer in order to determine the equivalent cost. The standard prices used are
                   listed below:

                      Cost Item                             Units                 Price. $/Unit

                   Operating Labor
                      Operator                           man hrs                     6
                      Supervisor                          man hrs                     8
                   Maintenance
                      Materials                             *                         *
                      Labor                               man hrs                     6
                   Replacement Parts
                   Utilities
                      Electric Power                      kwh                      0.011
                      Fuel                                mm Btu                  0.80
                      Process Water                      M Gal                    0.25
                      Cooling Water                      M Gal                    0.05
                      Chemicals                           *
246

-------
     The sum of all the above items applied over a year's operation is the direct
annual operating cost of the system.

     The total annual cost of each system is calculated by  adding the annual-
ized capital  charges to the  direct annual  operating cost.  In calculating the
annualized capital charges,  the  investment cost of the system, including taxes
and interest, must be  spread out over the useful  life of the equipment. Many
methods of  annualizing investment cost  are  used. These  methods  fall  into
three major categories:

     1.   Straight line method  which applies the capital charges at a fixed  rate
         over the useful life of the control system.

     2.   Accelerated methods which apply the capital charges  at a declining
         rate over the useful life, on the theory that aging or loss in value of equipment
         occurs to a greater degree on new equipment than on old equipment.

     3.   Methods which relate capital  charges to some  measure of  equipment
         usage. These methods are seldom applied to processing equipment. The
         most common example is mileage-based depreciation of automobiles.

     Of  the two methods  applicable  to processing  equipment,  the  most
commonly  used is the  straight  line method. This  is the method used for the
data presented in this report. Reasons for its common use are:

     1.   It  is easy to understand and calculate.

     2.   It  is thought  by many  to  be the best approximation of the rate of
         obsolescence of process equipment.

     3.   It  makes alternate  control systems comparable  on an annualized  cost
         basis since the capital charges based  upon this method are constant
         from year to year.

     Once  the decision  has been made to use this method, the only critical
issue is  what value to use for the useful life of the control system. The useful
life of any control system  is, in  reality, a composite of the useful  lives of its
component parts. Some of those parts have relatively long lives, others relatively
short lives. The value  chosen for the economic evaluation of a control system
depends upon:  the  nature  of the  primary  control device,  the  differences in
expected  useful  life  of similar  equipment  from  different  manufacturers,  the
maintenance practices of the owning firm,  the  battery limits defined for the
system,  the number and kind of structures built, and the  accounting practices
of the owning firm, among others.  For these reasons, the value chosen will vary
                                                                                        247

-------
                  from firm to firm even for similar systems.

                       Taxes may also  play  a part in the determination of useful life.  Under
                  normal  circumstances, control  systems are depreciated  over their normal useful
                  lives. They may, however, be depreciated for tax  purposes at  an accelerated
                  rate. Under certain circumstances, defined by the Internal  Revenue Service, all
                  or part of the air  pollution  control equipment may be  amortized  over a sixty
                  month period. In most cases, this period  is much shorter than the normal useful
                  life.  Accelerated depreciation for  tax  purposes,  especially the  sixty  month
                  amortization, has the  effect  of decreasing effective operating cost by deferring
                  tax payments into the future. The discounted  value of the  cash  outflow caused
                  by the operation of the pollution control system is thereby reduced.

                       The  money market at the time of equipment purchase  is another important
                  variable in the  determination of capital  charges. The rate at  which  money  is
                  available  varies  widely  from firm to firm,  as well as with overall  economic
                  considerations. The cost of capital for financing by  means  other  than  borrowing
                  also varies over a wide range from firm to firm. Variations in  the cost of financing
                  can be large enough to affect the choice between alternative control systems.

                       For the purpose of presenting the annual operating  cost data in this  report,
                  it was decided to use the same  fixed percentage of total  installed  cost  as the
                  capital charge for all of the  applications  studied.  The rate  chosen  was  16%. It
                  was based upon an estimated useful equipment  life of 15 to 20  years, debt
                  capital availability at 9 to 11%, and a correction for the  tax incentives available
                  to installers of pollution  control hardware  of 5 to 7%. Although the rate chosen
                  is a good general  estimate,  it does not  purport to be  the  correct rate for any
                  specific situation. It is used only as a good  estimate to assist the cost presentations
                  in this report.
                  2.   Discussion of Utility Price Levels

                       Evaluation of, and  selection  among,  equivalent control systems should be
                  based  upon both the capital cost  and the operating cost. Part 1  of this section
                  discussed the  capital  portion of  the  total annual  operating  cost  and showed
                  that the direct operating cost is composed of the following items:

                       Operating (operator and supervisor) Labor

                       Maintenance Labor and  Materials

                       Replacement Parts

                       Utilities and Supplies
248

-------
     The utilities portion of the operating cost is a function of utility price levels.
Price levels vary due to:

     1.  Geography — The price of natural gas, for example,  is much higher
         in the New England states than in the Gulf Coast states.

     2.  Demand — The demand for low sulfur black fuel oil keeps  its price as
         much as 50 cents per barrel higher than the equivalent higher sulfur fuel.

     3.  Nature of Use — The rates for interruptible gas service are lower than
         those for continuous service, and rates for peak period use  of electrical
         service are as much as twice the rates for off-hour power consumption.

     The effect of utility cost  levels also varies within a given type of system.
Capital cost is a larger part  of the total cost  of a small unit than it is of a large
unit  of the same type. Therefore,  the utility costs are smaller relative to the
total annual operating cost, and have  less effect  on it. Also, the  operating
parameters of a system affect the  relative size of the utility costs. Scrubbers
using a high  pressure drop, for example, require  more power to push the  gas
through, than do  scrubbers  having  a low pressure drop. Therefore,  utilities will
be a larger portion of  the total cost  of high energy scrubbers than of low energy
scrubbers.
3.   Derived Capital Cost Indices

     For each of the process  applications discussed  in the previous sections of
this  report, capital costs of pollution  control equipment have been  presented
for two or three different process  sizes. This permits development  of a  mathe-
matical expression for the capital cost of  air  pollution  control systems as  a
function of process size in  each  application. The mathematical model  chosen
was  the exponential form often  used for relating cost and size of capital equipment.


     Capital Cost = K (Size)*

Where

     K and x are constants, and

     Size is the capacity of the plant to which the abatement equipment is being
     applied.

This  relationship assumes that  a log-log plot of cost and size is a straight  line for
                                                                                          249

-------
                  each application. For most types of equipment, this is a good assumption.

                       The  constants  K and x  were evaluated by computer for each abatement
                  application studied. Calculations were made for each of the three  capital  cost
                  categories presented in each application:

                       1.   Collector only

                       2.   Collector plus auxiliaries

                       3.   Turnkey system

                       The  units of the "Size"  term  in the equation for each  application are the
                  same as those  used  in  the prior  discussion of that  application. They are
                  summarized in Table 99.

                       The  results of these calculations for generating capital costs in dollars, are
                  presented in the following tables:

                  Process Area                                            Table Numbers

                  Kraft Pulp Mills
                      '— Conventional Recovery Furnace                         100
                      — Controlled Odor Recovery Furnace                      101
                  Ferroalloy Furnaces
                      — Ferrosilicon Furnace                                    102
                      — Silicon Metal Furnace                                   103
                  Grain Cleaning Houses                                        105
                  Glass-Melting Furnaces                                        106
                  Crushed Stone and Aggregate
                      — Secondary and Tertiary Rock Crusher                  109, 111
                      — Conveyor Transfer Points                             110. 112
                  Asphalt  Saturation
                      — Asphalt Saturator                                  113, 114, 115
                      — Asphalt Blow Still                                      116
                  Also shown in these tables are the ratios of turnkey system cost to collector cost,
                  total equipment cost to collector cost, and turnkey system cost to total equipment
                  cost.

                       Calculated values of the exponents for the power function can be summarized
                  by equipment type as follows:
250

-------
                                     Maximum     Minimum     Arithmetic
Equipment Type                         Value        Value       Average

Fabric Filters
    Collector Only                       .967          .569          .804
    Turnkey System                     .933          .522          .761

Glass Fiber Mat Filters
    Collector Only                        —           —           .647
    Turnkey System                      —           —           .728

Wet Scrubbers
    Collector Only                       .851          .430          .589
    Turnkey System                     .417          .276          .356

Electrostatic Precipitators
    Collector Only                       .859          .436          .730
    Turnkey System                     .780          .327          .656

Incinerators
    Collector Only                       .947          .672          .810
    Turnkey System                     .771          .562          .667

     Of the five types of systems involved, fabric filters had the highest average
exponent. This was to be expected since fabric filtering equipment tends to be additive.
That is, to increase the capacity of a fabric filter system, one can many times add
another unit. This becomes more practicable with larger air flows. Many of the fabric
filter systems were under  100,000 ACFM. Had more been in the 200,000-and-up
range, the cost-to-size relationship would have been even closer to linear.

     The  exponent  for incinerators  had an  average  value of  .667  over  the
10 - 50,000 ACFM size range. This was above the 0.4 exponent  usually assumed,
because a number of the incinerators were of relatively larger size.

     Every  incinerator, regardless  of size,  requires  an  extensive system  of
safety control devices to prevent explosions. This system is a significant part of the cost
of smaller incinerators. So  in that size range, the cost of increasing size is relatively
small.
                                                                                        251

-------
                                                TABLE 99

                             UNITS OF PLANT SIZE FOR EACH PROCESS AREA



                  Process Area                                  Plant Size Units

                  Kraft Pulp Mills                                 ADT/day  Plant Capacity
                  Ferroalloy Furnaces                            Lb/hour  Product
                  Grain Cleaning Houses                          Lb/hour  Process Weight
                  Glass-Melting Furnaces                         Ton/day  Glass Output
                  Crushed Stone and Aggregate
                      — Secondary and Tertiary Rock Crusher       Ton/hour  Process Weight
                      — Conveyor Transfer Points                 ACFM    Inlet Gas Flow
                  Asphalt Saturation                              ACFM    Process Gas Flow
252

-------
     The  average exponent derived for glass  mat fiber filters was .647. The
limited amount of data on these systems precludes drawing many conclusions, but the
cost data correlations for them could be expected to resemble those for fabric filters.

     Wet  scrubbers  had an average exponent of .589 — approximately equal to
the 0.6 usually assumed for equipment. Every one of the scrubbers had an inlet gas
f tow rate below 100,000 ACFM. In this range the basic design of scrubbers is adequate
to handle these volumes of gas and the cost starts increasing gradually with size.

     Exponents  for  electrostatic precipitators  varied from  .436  to .859,  with
an average value of .73. In most applications the gas flow was above 100,000 ACFM.
Precipitator flow rates from 300,000 to 600,000 ACFM are not unusual. A major capital
expense of precipitators is the power supply that is required. This costs nearly as much
for small precipitators as for large ones. Therefore, the cost of small precipitators does
not increase as rapidly with size as would be expected in larger designs.

     The  use of the derived  capital cost equations outside the range of the data
from which  they were calculated  is  valid  within certain limitations. Very small
equipment installations tend to have relatively high capital costs which do not correlate
well with size. Small systems cost roughly the same regardless of the treated gas
throughput. Very large systems are frequently based on different designs than their
smaller  counterparts, or  are composed of several smaller units. Consequently, the
derived  cost indices will  be inaccurate for these larger sizes.  Numerical values for
these large and small limitations depend upon both the nature of the abatement
equipment and the nature of the process to which it is applied. Generalizations of these
numerical values can be made, however, and they are presented below as guidelines.

                                  Small Limit.  ACFM     Large Limit, ACFM

     Scrubbers                           2,000               100,000
     Fabric Filters                        2,000              very large
     Precipitators                       50,000              very large
     Incinerators                        20,000                50,000

     The  basic capital cost data collected  were also used to calculate the cost
per SCFM of inlet gas for each application. Results of these calculations are presented
in the following tables:
                                                                                        253

-------
                  Process Area

                  Kraft Pulp Mills
                      — Conventional Recovery Furnace
                      — Controlled Odor Recovery Furnace

                  Ferroalloy Furnaces
                      — Ferrosilicon Furnace
                      — Silicon Metal Furnace

                  Grain Cleaning Houses

                  Glass-Melting Furnaces

                  Crushed Stone and Aggregate
                      — Secondary and Tertiary Rock Crusher
                      — Conveyor Transfer Points

                  Asphalt Saturation
                      — Asphalt Saturator
                      — Asphalt Blow Still
Table Numbers
     117
     118
     119
     120

     121

 122, 123, 124
   125. 127
   126, 128
 129. 130. 131
     132
254

-------
                                     TABLE 100




                 DERIVED COST INDICES FOR KRAFT MILL RECOVERY FURNACES
COLLECTOR TYPE
ELECTROSTATIC PRECIPITATOR
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
ELECTROSTATIC PRECIPITATOR
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
K*


3,848
4,699
18,134
_


2,570
3,583
12,723
.

X*


.773
.759
.675
_


.859
.826
.749
-

B/A


-
-
—
1.119
1.102

-
-
~
1.137
1.097
C/A


-
-
~
2.562
2.302

-
-
~
2.502
2.219
C/B


-
-
—
2.289
2.088

-
-
"
2.200
2.022
*FOR USE  IN  EQUATION:  COST  =  K*(SIZE)**X
                                                                              255

-------
                                    TABLE 101
             DERIVED COST INDICES FOR KRAFT MILL CONTROLLED ODOR FURNACES
COLLECTOR TYPE
ELECTROSTATIC PRECIPITATOR
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE


ELECTROSTATIC PRECIPITATOR
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)

SMALL
LARGE

K*


4,854
5,776
14,622
-



4,617
5,471
13,739

-
_

X*


.111
.768
.750
-



.809
.803
.780

-
_

B/A


-
-
-
1.160
1.156



_
-
-

1.140
1.133

C/A


-
-
-
2.626
2.565



_
-
-

2.479
2.401

C/B ซJ
T
'' \
*Y
-
• 4
2.264 |
2.2l9 L
i
i
^
- 7
i
T"

...,,
2.119
T
*FOR USE IN EQUATION:   COST = K*(SIZE)**X
 256

-------
                                    TABLE 102




                    DERIVED COST INDICES FOR FERROSIUCON FURNACE
COLLECTOR TYPE
FABRIC FILTER
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
FABRIC FILTER
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
K*








382
554
947
_

X*








.937
.927
.928
~

B/A








-
-
—
1.325
1.319
C/A








-
-
~
2.300
2.291
C/B








-
-
~
1.735
1.736
*FOR USE IN EQUATION:   COST = K*(SIZE)**X
                                                                              257

-------
                                     TABLE 103
            DERIVED COST INDICES FOR SIUCON METAL FURNACE (DILUTION COOLING)
COLLECTOR TYPE
FABRIC FILTERS
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE

FABRIC FILTERS
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
K*








459
728
1,403
_

X*








.967
.946
.933
.

B/A








-
1.345
1.330
C/A








.
2.350
2.309
C/B j
^
t
tat
<&

sad

ซwii
'*',
1.747
1.736 4;
*FOR USE  IN  EQUATION:  COST  = K*(SIZE)**X
 258

-------
                                     TABLE 104




           DERIVED COST INDICES FOR SILICON METAL FURNACE (EVAPORATIVE COOLING)
COLLECTOR TYPE
FABRIC FILTERS
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
FABRIC FILTERS
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
K*








255
616
1,252
_

X*








.933
.881
.861
_

B/A








-
-
-
1.622
1.580
C/A








-
-
-
2.828
2.726
C/B








-
-
-
1.743
1.725
*FOR USE  IN  EQUATION:  COST  = K*(SIZE)**X
                                                                               259

-------
                                    TABLE 105
                    DERIVED COST INDICES FOR GRAIN CLEANING HOUSE
COLLECTOR TYPE
FABRIC FILTERS
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
FABRIC FILTERS
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
K*








14
18
79
_

X*








.722
.739
.678
_

B/A








-
-
~
1.514
1.547
C/A








-
-
•
3.846
3.650
C/B ; \
UK
\
teg


tfijfi
J
i
-
^'


2.360 (|
tetfjj
*FOR USE  IN  EQUATION:  COST  =  K*(SIZE)**X
 260

-------
                                     TABLE 106
                    DERIVED COST INDICES FOR GLASS-MELTING FURNACE
COLLECTOR TYPE
ELECTROSTATIC PRECIPITATOR
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
ELECTROSTATIC PRECIPITATOR
f HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
, TURNKEY (C)
SMALL
LARGE
[
K*








12,656
15,192
79,681
_

X*








.436
.428
.327
_

B/A








-
, -
—
1.156
1.146
C/A








-
—
••
3.805
3.374
C/B








-
-
—
3.291
2.945
*FOR USE  IN  EQUATION:  COST  =  K*(SIZE)**X
                                                                              261

-------
                                     TABLE 107
                    DERIVED COST INDICES FOR GLASS-MELTING FURNACE
COLLECTOR TYPE
WET SCRUBBER
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE

WET SCRUBBER
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE

K*






1,933
8,307
24,693
-

X*






.430
.489
.385
-

B/A






_
-
5.648
6.028

C/A






_
-
10.385
9,885

C/B !J
*|
-i

1
f
[
- 1

" t
1.839 . '
1.640 I
1
*FOR USE IN  EQUATION:  COST  =  K*(SIZE)**X
 262

-------
                                     TABLE 108
                    DERIVED COST INDICES FOR GLASS-MELTING FURNACE
COLLECTOR TYPE
I FABRIC FILTER
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
FABRIC FILTER
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
K*








5,745
8,636
23,839
_

X*








.569
.573
.522
_

B/A








-
-
.
1.532
1.539
C/A








-
-
"
3.350
3.183
C/B








-
. -
.
2.186
2.068
*FOR USE  IN  EQUATION:  COST  =  K*(SIZE)**X
                                                                              263

-------
                                    TABLE 109




             DERIVED COST INDICES FOR SECONDARY AND TERTIARY ROCK CRUSHER
COLLECTOR TYPE
WET SCRUBBER
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE


WET SCRUBBER
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE

K*

426
1,301
11,292
_.
-



360
4,085
16,563
_
-

X*

.618
.592
.417
_
-



.644
.450
.377
-
-

B/A

-
-
2.630
2.536



-
-
~
3.752
2.867

C/A

-
-
8.389
6.343



-
-
~
10.049
6.942

C/B J
k^4
7
:. "f
!
3.190 T
2.501 1.
"i
1.
i
i
- 1
i
- j
2.678 1
2.422
1
*FOR USE IN EQUATION:   COST = K*(SIZE)**X
 264

-------
                                    TABLE 110

                       DERIVED COST INDICES FOR CRUSHED STONE
                      AND AGGREGATE CONVEYOR TRANSFER POINTS
COLLECTOR TYPE
WET SCRUBBERS
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
WET SCRUBBERS
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
K*


118
379
7,596
_


96
381
7,803
_

X*


.485
.474
.276
_


.506
.483
.279
.

B/A


-
-
-
2.919
2.884

-
-
-
3.251
3.170
C/A


-
-
-
10.930
8.694

-
-
—
11.677
9.096
C/B


-
-
-
3.744
3.015

-
-
~
3.592
2.869
ftFOR USE IN EQUATION:   COST = K*CSIZE)**X
                                                                             265

-------
                                    TABLE 111




             DERIVED COST INDICES FOR SECONDARY AND TERTIARY ROCK CRUSHER
COLLECTOR TYPE
FABRIC FILTERS
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE



FABRIC FILTERS
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
K*












374
647
1,209
-

X*












.797
.772
.762
-

B/A












-
-
-
1.508
1.459
C/A












-
-
-
2.658
2.534
C/B ji.
"*
,•
Wi

i
ซ

i
l
to*
"V
^
-
-
CSjririf
1.762
1.738 .
*FOR"USE IN EQUATION:   COST = K*(SIZE)**X
 266

-------
                                    TABLE 112

                       DERIVED COST INDICES FOR CRUSHED STONE
                          AND AGGREGATE TRANSFER POINTS
COLLECTOR TYPE
FABRIC FILTER
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
FABRIC FILTERS
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
K*








26
36
126
—

X*








.704
.715
.644
_

B/A








-
-
-
1.529
1.549
C/A








-
-
-
2.956
2.769
C/B








-
-
-
1.933
1.788
*FOR USE IN EQUATION:   COST = K*(SIZE)**X
                                                                             267

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                                    TABLE 113
                     DERIVED COST INDICES FOR ASPHALT SATURATOR
COLLECTOR TYPE


WET SCRUBBERS
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE


WET SCRUBBERS
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)

SMALL
LARGE

K*












2.5
48
1,600

-
_

X*












.851
.657
.400

-
_

B/A












_
-
-

2.710
2.299

C/A












_
-
-

6.933
4.731

C/B .
••
T
i



• .
T
i
T
.1

- 1




2!057 ta
1
*FOR USE IN EQUATION:   COST = K*(SIZE)**X
 268

-------
                                     TABLE 114




                  DERIVED COST INDICES FOR ASPHALT SATURATOR (WITH H.E.)
COLLECTOR TYPE
THERMAL INCINERATORS
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
THERMAL INCINERATORS
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
K*


9
10
99
_


9
10
99
_

X*


.947
.941
.771
_


.947
.941
.771
-

B/A


-
-
-
1.079
1.074

-
-
~
1.079
1.074
C/A


-
-
—
1.863
1.604

-
-
~
1.863
1.604
C/B


-
-
—
1.726
1.494

-
-
—
1.726
1.494
*FOR USE  IN  EQUATION:   COST = K*(SIZE)**X
                                                                               269

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                                     TABLE 115




                      DERIVED COST INDICES FOR ASPHALT SATURATOR
COLLECTOR TYPE
GLASS FIBER MAT FILTERS
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE


GLASS FIBER MAT FILTERS
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE

K*









96
75
3,384
—
-

X*









.647
.694
.428
_
-

B/A









-
-
-
1.248
1.298

C/A









-
-
-
3.925
3.259
•
C/B
~T


i
i
7
1



_


2.510
7
*FOR USE IN EQUATION:   COST = K*(SIZE)**X
 270

-------
                                     TABLE 116




                      DERIVED COST INDICES FOR ASPHALT BLOW STILL
COLLECTOR TYPE
THERMAL INCINERATOR
LA PROCESS WEIGHT
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
THERMAL INCINERATOR
HIGH EFFICIENCY
COLLECTOR ONLY (A)
TOTAL EQUIPMENT (B)
TURNKEY (C)
SMALL
LARGE
K*







132
121
751
_

X*







.672
.689
.562
_

B/A







-
1.068
1.090
C/A







-
2.044
1.796
C/B







-
1.913
1.648
*FOR USE  IN  EQUATION:  COST  = K*(SIZE)**X
                                                                              271

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                                 TABLE 117

             DERIVED COST PER SCFM* FOR KRAFT MILL RECOVERY FURNACES
     COLLECTOR TYPE
 SMALL
 LARGE
     ELECTROSTATIC PRECIPITATOR
     MEDIUM EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
173,600
   2.70
   3.03
   6.93
520,800
   2.11
   2.32
   4.85
     ELECTROSTATIC PRECIPITATOR
     HIGH EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
173,600
   3.08
   3.50
   7.70
520,800
   2.63
   2.89
   5.85
*BASED ON SCFM AT 70 DEC. F AT COLLECTOR  INLET  INCLUDING WATER
 VAPOR.
                         Preceding page blank
                                                                         273

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                                   TABLE 118
           DERIVED COST PER SCFM* FOR KRAFT MILL CONTROLLED ODOR FURNACES
       COLLECTOR TYPE
 SMALL
 LARGE
       ELECTROSTATIC PRECIPITATOR
       MEDIUM EFFICIENCY
         GAS FLOW RATE, SCFM*
           COLLECTOR ONLY
           TOTAL EQUIPMENT
           TURNKEY SYSTEM
155,800
   3.78
   4.38
   9.92
467,400
   2.94
   3.40
   7.54
       ELECTROSTATIC PRECIPITATOR
       HIGH EFFICIENCY
         GAS FLOW RATE,  SCFM*
           COLLECTOR ONLY
           TOTAL EQUIPMENT
           TURNKEY SYSTEM
155,800
   4.52
   5.16
  11.21
467,400
   3.67
   4.15
   8.80
  *BASED ON  SCFM AT  70  DEC.  F AT COLLECTOR INLET INCLUDING WATER
  VAPOR.
274

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                                 TABLE 119


                DERIVED COST PER SCFM' FOR FERROSILICON FURNACES
     COLLECTOR TYPE
 SMALL
 LARGE
     FABRIC FILTER
     MEDIUM EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
     FABRIC FILTER
     HIGH EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
462,500
   2.72
   3.61
   6.26
740,000
   2.65
   3.49
   6.06
*BASED ON SCFM AT 70 DEG. F AT COLLECTOR  INLET  INCLUDING  WATER
 VAPOR.
                                                                         275

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                                  TABLE 120
                 DERIVED COST PER SCFM* FOR SILICON METAL FURNACES
      COLLECTOR TYPE
 SMALL
 LARGE
      FABRIC  FILTERS
      HIGH EFFICIENCY  (DILUTION  COOLING)
        GAS FLOW  RATE,  SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
277,500
   2.76
   3.71
   6.48
462,500
   2.72
   3.62
   6.28
      FABRIC  FILTERS
      HIGH EFFICIENCY  (EVAP.  COOLING)
        GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
109,000
   3.00
   4.86
   8.48
181,700
   2.91
   4.59
   7.92
 *BASED ON SCFM AT 70 DEG. F AT COLLECTOR  INLET  INCLUDING  WATER
  VAPOR.
276

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                                 TABLE 121

                DERIVED COST PER SCFM* FOR GRAIN CLEANING HOUSES
     COLLECTOR TYPE
 SMALL
 LARGE
     FABRIC FILTER
     MEDIUM EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
     FABRIC FILTER
     HIGH EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
14,900
  0.83
  1.26
  3.19
44,600
  0.66
  1.02
  2.41
*BASED ON SCFM AT 70 DEC. F AT COLLECTOR  INLET  INCLUDING  WATER
 VAPOR.
                                                                         277

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                                  TABLE 122

                DERIVED COST PER SCFM* FOR GLASS-MELTING FURNACES
      COLLECTOR TYPE
 SMALL
 LARGE
      ELECTROSTATIC PRECIPITATOR
      MEDIUM EFFICIENCY
        GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
      ELECTROSTATIC PRECIPITATOR
      HIGH EFFICIENCY
        GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
11,200
  8.42
  9.73
 32.04
26,800
  5.68
  6.51
 19.17
 *BASED  ON SCFM AT 70 DEC.  F AT COLLECTOR INLET INCLUDING WATER
  VAPOR.
278

-------
                                 TABLE 123
                DERIVED COST PER SCFM* FOR GLASS-MELTING FURNACES
     COLLECTOR TYPE
                  SMALL
 LARGE
     WET SCRUBBER
     MEDIUM EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
     WET SCRUBBER
     HIGH EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
                 11,200
                   1.25
                   7.05
                  12.97
26,800
  0.84
  5.04
  8.27
*BASED ON SCFM AT 70 DEG.
 VAPOR.
F AT COLLECTOR INLET INCLUDING WATER
                                                                        279

-------
                                   TABLE 124

                 DERIVED COST PER SCFM* FOR GLASS-MELTING FURNACES
      COLLECTOR TYPE
 SMALL
 LARGE
      FABRIC  FILTER
      MEDIUM  EFFICIENCY
        GAS FLOW  RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
      FABRIC  FILTER
      HIGH EFFICIENCY
        GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
11,200
  7.04
 10.79
 23.59
26,800
  5.50
  8.46
 17.50
 *BASED ON SCFM AT 70 DEG. F AT COLLECTOR  INLET  INCLUDING  WATER
  VAPOR.
280

-------
                                  TABLE 125


          DERIVED COST PER SCFM* FOR SECONDARY AND TERTIARY ROCK CRUSHER
     COLLECTOR TYPE
 SMALL
 LARGE
     WET SCRUBBER
     MEDIUM EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
19,600
  0.74
  1.94
  6.20
68,700
  0.50
  1.26
  3.15
     WET SCRUBBER
     HIGH EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
19,600
  0.72
  2.71
  7.26
68,700
  0.50
  1.44
  3.49
*BASED ON SCFM AT 70 DEG. F AT COLLECTOR INLET INCLUDING WATER
 VAPOR.
                                                                      281

-------
                                  TABLE 126


                   DERIVED COST PER SCFM* FOR CRUSHED STONE AND
                      AGGREGATE CONVEYOR TRANSFER POINTS
      COLLECTOR TYPE
SMALL
 LARGE
      WET SCRUBBER
      MEDIUM EFFICIENCY
        GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
4,900
 1.49
 4.36
16.33
14,700
  0.85
  2.45
  7.38
      WET SCRUBBER
      HIGH EFFICIENCY
        GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
4,900
 1.46
 4.76
17.10
14,700
  0.85
  2.70
  7.74
 *BASED ON SCFM AT 70 DEC. F AT COLLECTOR INLET INCLUDING WATER
  VAPOR.
282

-------
                                 TABLE 127
         DERIVED COST PER SCFM* FOR SECONDARY AND TERTIARY ROCK CRUSHER
     COLLECTOR TYPE
 SMALL
 LARGE
     FABRIC FILTER
     MEDIUM EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
     FABRIC FILTER
     HIGH EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
19,600
  1.79
  2.71
  4.77
68,700
  1.54
  2.25
  3.91
ABASED ON SCFM AT 70 DEC. F AT COLLECTOR INLET INCLUDING WATER
 VAPOR.
                                                                        283

-------
                                  TABLE 128


                    DERIVED COST PER SCFM* FOR CRUSHED STONE
                    AND AGGREGATE CONVEYOR TRANSFER POINTS
      COLLECTOR TYPE
SMALL
 LARGE
      FABRIC FILTER
      MEDIUM EFFICIENCY
        GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
      FABRIC FILTER
      HIGH EFFICIENCY
        GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
4,900
 2.10
 3.21
 6.21
14,700
  1.52
  2.35
  4.20
 *BASED ON SCFM AT 70 DEG. F AT COLLECTOR  INLET  INCLUDING WATER
  VAPOR.
284

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                                 TABLE 129


                 DERIVED COST PER SCFM* FOR ASPHALT SATURATOR
     COLLECTOR TYPE
                  SMALL
 LARGE
     WET  SCRUBBER
     MEDIUM EFFICIENCY
       GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY  SYSTEM
     WET SCRUBBER
     HIGH EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
                 20,000
                   0.64
                   1.73
                   4.43
50,000
  0.53
  1.21
  2.49
*BASED ON SCFM AT 70 DEG.
 VAPOR.
F AT COLLECTOR INLET INCLUDING WATER
                                                                        285

-------
                                  TABLE 130
                  DERIVED COST PER SCFM* FOR ASPHALT SATURATOR
      COLLECTOR TYPE
  SMALL
  LARGE
      THERMAL  INCINERATOR   (W/HEAT  EX.)
      MEDIUM EFFICIENCY
        GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
20,000
  6.04
  6.52
 11.25
50,000
  5.40
  5.79
  8.65
      THERMAL  INCINERATOR   (W/HEAT  EX.)
      HIGH EFFICIENCY
        GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
 20,000
   6.04
   6.52
  11.25
50,000
  5.40
  5.79
  8.65
 *BASED ON SCFM AT 70 DEG. F AT COLLECTOR  INLET  INCLUDING WATER
  VAPOR.
286

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                                 TABLE 131


                  DERIVED COST PER SCFM* FOR ASPHALT SATURATOR
     COLLECTOR TYPE
                  SMALL
 LARGE
     GLASS FIBER MAT FILTER
     MEDIUM EFFICIENCY
       GAS FLOW RATE, SCFMft
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
     GLASS FIBER MAT  FILTER
     HIGH EFFICIENCY
       GAS FLOW RATE, SCFM*
         COLLECTOR ONLY
         TOTAL EQUIPMENT
         TURNKEY SYSTEM
                 20,000
                   3.14
                   3.92
                  12.32
50,000
  2.17
  2.82
  7.08
*BASED ON SCFM AT 70 DEG.
 VAPOR.
F AT COLLECTOR INLET INCLUDING WATER
                                                                        287

-------
                                  TABLE 132


                   DERIVED COST PER SCFM* FOR ASPHALT BLOW STILL
      COLLECTOR TYPE
SMALL
 LARGE
      THERMAL  INCINERATOR
      MEDIUM EFFICIENCY
        GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
      THERMAL  INCINERATOR
      HIGH EFFICIENCY
        GAS FLOW RATE, SCFM*
          COLLECTOR ONLY
          TOTAL EQUIPMENT
          TURNKEY SYSTEM
8,400
 8.00
 8.54
16.34
27,000
  5.46
  5.95
  9.80
 *BASED ON SCFM AT 70 DEC. F AT COLLECTOR  INLET  INCLUDING WATER
  VAPOR.
288

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D.   GENERALIZED COST DATA

     A series of correlations were made  to investigate the general relationship
of the cost of equipment to the gas flow rate for the types of control systems discussed
in this report. These correlations were made using the data presented in the previous
section of this report. The points plotted on each graphical correlation are coded so that
the process application which they represent can be identified. The same point symbol
code was used in all of the graphs and it is fully explained in Table 133.
Scrubbers

     Correlations  were  made  for  both  the  scrubber  cost and for the  total
installed cost of the scrubber system as a function of the inlet gas flow rate in ACFM.
Figure 74 shows the cost of the scrubber alone. The data falls fairly uniformly along a
single  line. This is to be  expected because all of the scrubbers that have been
considered in this section are of low to medium energy. The plotted points represent
scrubbers of  similar complexity.

     Figure  75 shows  the relation  between  the  cost for installed scrubber
systems and the inlet gas flow rate in ACFM. The majority of the data points fall along a
straight line.  As previously mentioned, all of the scrubber systems are of similar
complexity. The only exception is the asphalt saturator application that uses a low
energy scrubber with a 3 wt% solution of potassium permanganate as the scrubber
liquor.  Because of the lower operating energy which is required in this application, the
system was less expensive. The direct operating cost of the wet scrubber in this
application, however, increases because of the cost of the potassium permanganate
that is required. Direct operating costs of wet scrubbers may be found in Figure 76. This
graph starts curving up near its bottom end as the more fixed operating costs, such as
operating and maintenance labor, become a  more significant part of the total which,
therefore, increases less rapidly with  size.
Fabric Filters

     Similar  correlations were made  for fabric filters. However, as  Figure  77,
78, and 79 illustrate, due to the wide variability in the applications involved, no true
correlation exists between the different applications on a gas flow rate basis. This is
caused by the fact that the characteristics of the different particulates being collected
require a different air-to-cloth ratio for each application. For inlet gas flow rates greater
                                                                                         289

-------
                                                  TABLE 133
                                            PLOTTING SYMBOL KEY
                   Process Area                                                       Symbol

                   Kraft Pulp Mills
                       — Conventional Recovery Boilers
                       — Controlled Odor Recovery Boilers

                   Ferroalloy Furnaces
                       — Ferrosilicon Furnaces with Air Dilution Coolers
                       — Silicon Metal Furnaces with Air Dilution Coolers
                       — Silicon Metal Furnaces with Evaporative Coolers

                   Grain Cleaning Houses

                   Glass Manufacturing

                   Crushed Stone and Aggregate Industry
                       — Secondary and Tertiary Rock Crusher
                       — Crushed Stone and Aggregate Transfer

                   Asphalt Saturation
                       — Asphalt Saturator
                       — Asphalt Blowing Still
290

-------
than  100,000 ACFM, the air-to-cloth ratio approaches a constant value, and the
relationship between size and cost becomes nearly linear. This can be expected; for as
the size increases, the cost of labor and material for replacing the bags become the
major part of the operating cost. And these bag replacement costs are directly
proportional to the size of the unit. The capital costs of fabric filters are given as Figure
77, installed costs of filter systems appear in Figure 78, and direct operating costs of
fabric filter systems are presented in Figure 79. All of the costs have been correlated
with the inlet gas flow rate in ACFM. Actual costs of filters and systems for flow rates of
100,000 ACFM or less vary in this study between the dashed lines of these figures, and
single, unique correlations of cost with gas flow rate to the filter system can not be
established  in this range.
Incinerators

     There were  only  two  applications  in  this  study  for  which  incinerator
cost information was obtained. All of these units were thermal incinerators, and heat
exchangers were specified for each unit. Inlet gas flow rates were between 10,000 and
60,000 ACFM.

     The  capital  cost of  the  incinerator alone  appears in  Figure  80  as a
function of the inlet gas flow rate. In Figure 81, the installed cost correlation has been
plotted for these systems. In this range of inlet gas flow rates, the costs of installed
systems increase significantly with increasing size. Differences in operating costs for
medium  and high efficiency incineration systems were not significant for the asphalt
saturator application.
Electrostatic Precipitators

     Capital  costs  of  electrostatic  precipitator   units   are  presented
graphically as Figure 83, and installed costs of precipitator systems are given in Figure
84. A high efficiency precipitator costs about 25 to 30 percent more than a medium
efficiency unit, and a high efficiency precipitator system has a 15 to 20 percent greater
installed cost than a medium efficiency system, for an identical inlet gas flow rate. The
cost of the installed system varied from about 2 to 3.5 times that of the precipitator
alone.

     Figure  85  shows  the  direct  operating  costs of  precipitators.  The data
indicate that the cost of operating a high efficiency unit is roughly 10% more than that of
                                                                                          291

-------
                  operating a medium efficiency unit, for the applications that have been studied. Nearly
                  all of the increase is due to the increased use of electrical power.
                  Glass Fiber Mat Filters

                       Glass fiber mat  filtration was used  in  only  one application in this  report.
                  The only correlations necessary were made when the costs were presented in the
                  previous section of this report.
292

-------
                                 FIGURE 74
                            COST OF WET SCRUBBERS ONLY
•JO3
                              INLET GAS PLOW RATE, ACFM
                                               NOT REPRODUCIBLE
                                                                               293

-------
                                      FIGURE 75
                      TOTAL INSTALLED COST OF SCRUBBING SYSTEMS
                               INLET GAS FLOW RATE, ACFM
294

-------
•s
K
O.
                         DIRECT
FIGURE 76



 COST OF WET SCRUBBERS
    'to*
                                    INLET GAS FLOW RATE, ACFM
                                                                NOT REPRODUCIBLE
                                                                                      295

-------
                                          FIGURE 77
                                CAPITAL COSTS OF FABRIC FILTERS
8
I
                                   INLET GAS FLOW RATE, ACFM
   296

-------
                                            FIGURE 78
                               INSTALLED COSTS OF FABRIC FILTERS
                 H-H-
                               t-^
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10
 9
 6
 7
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                                         INLET GAS FLOW RATE, ACFM
                                                                                               297

-------
                                       FIGURE 79
                        DIRECT OPERATING COSTS OF FABRIC FILTERS
.10
                                                             10*
5 5 7 8 9 10T
                                  INLET GAS FLOW RATE, ACFM
298

-------
                                       FIGURE 80
                         CAPITAL COSTS OF THERMAL INCINERATORS
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                                   INLET GAS FLOW RATE, ACFM
                                                                NOT REPRODUCIBLE
                                                                                    299

-------
      INLET GAS FLOW RATE, ACFM




s   7   a  e  10*'                a
7   a   a  10*

-------
                                                FIGURE 82
                                                OPERATING COST

                             OF THERMAL INCINERATORS WITH HEAT EXCHANGE

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                                           INLET GAS FLOW RATE, ACFM
                                                                                                    301

-------
                                        FIGURE 83
                       CAPITAL COST OF ELECTROSTATIC PRECIPITATORS
                                   INLET GAS FLOW RATE, ACFM
302

-------
                                          FIGURE 84
                       INSTALLED COST OF ELECTROSTATIC PRECIPITATORS
107 L
                  if
 3-




2.5-
1.5-
   1!
10ฐ
                                                    x:
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                       EFFICIENCY
                   J
 3.




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                  MEDIUM EFFICIENCY '<
 11
10s H *-
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          1.5
                2    2.5   3
                                  5   6   7  8  9
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                                                        1.5
                                                              2    2.5   3
5    6   7  8  9 10*
                                   INLET GAS FLOW RATE, ACFM
                                                                                        303

-------
                                       FIGURE 85
                  DIRECT OPERATING COST OF ELECTROSTATIC PRECIPITATORS
                                  INLET GAS FLOW RATE, ACFM
304

-------
                                 APPENDIX

             A.  SPECIFICATIONS FOR ABATEMENT EQUIPMENT
I.    SCOPE
     A.   This specification covers vendor requirements for air pollution control
         equipment for the subject process. The intent of the  specification is to
         describe the service as thoroughly as possible so as to secure vendor's
         proposal for equipment which is suitable in every respect for the service
         intended. Basic information is tabulated in Sections 2 and 3. The vendor
         should specify any of the  performance characteristics which cannot be
         guaranteed without samples of process effluent.

     B.   The vendor shall submit a bid showing three separate prices as described
         below.

         1.   All  labor,  materials,  equipment, and  services to  furnish  one
              pollution abatement device together with the following:

              a.   All ladders, platforms and other accessways to provide con-
                   venient access to  all points requiring observation or main-
                   tenance.

              b.   Foundation bolts as required.

              c.   Six  (6) sets of  drawings, instructions, spare parts list, etc.,
                   pertinent to the above.

         2.   Auxiliaries including:

              a.   Fan(s)

              b.   Pump(s)

              c.   Damper(s)

              d.   Conditioning Equipment

              e.   Conveying Equipment
                                                                                        305

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                           3.   A turnkey installation of the entire system including the following
                                installation costs:

                                a.    Engineering

                                b.    Foundations and Support*

                                c.    Ductwork

                                d.    Stack

                                e.    Insulation

                                f.    Electrical

                                g.    Piping

                                h.    Painting

                                i.    Startup

                                j.    Performance Test

                                k.    Other

                      C.   For the "pollution abatement device only" quotation, the vendor shall
                           furnish the equipment FOB point of manufacture, and shall furnish as a
                           part  of this project competent supervision of the erection, which shall
                           be by others.

                      D.   Vendor shall furnish* the following drawings, etc., as a minimum:

                           1.   With his proposal:

                                a.    Plan and elevation showing general arrangement.

                                b.    Typical details of collector internals proposed.

                                c.    Data relating to projected performance with respect to pressure
                                     drop,   gas  absorption efficiency,  and paniculate  removal
                                     efficiency to operating parameters such as gas flow.

                 'This is a typical request. The member companies are NOT to furnish this material
                 under the present project.

                   'Predicated on ideal soil conditions.

306

-------
When the detailed analysis method is used to estimate operating and maintenance
labor costs, a brief statement of the assumptions made will be helpful in combining
the estimates of several member companies.

The least desirable method of estimating maintenance and operating  labor costs
involves  the use  of a fraction  of total capital  cost. Operating labor  costs  bear
little relationship to capital cost of the equipment, and it may be true that increasing
the capital cost will decrease the labor requirement (for example, where additional
instrumentation is  used to  minimize operator attention). The  use of a  fraction of
capital cost should therefore not be used as a basis for estimating operating labor
in any case.

Maintenance costs are sometimes obtained by conducting industry-wide surveys
and the  results reported in terms of total dollars for labor and  material or as a
fraction of the installed cost of the equipment. For example, a survey of maintenance
costs in the chemical process industries reported an annual expenditure of approxi-
mately 6% of total installed system cost for a wide variety of chemical  equipment.
It might  be  reasonable to  allocate  half of this cost to labor and half to spare
parts and report a labor cost of 3% of the total installed cost. This is not recommended
and should be used only when  there is no other basis available. The  use of this
system and the source of the information on which  the  estimate is based should
be clearly indicated.
                                                                                          307

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IV.  PROCESS PERFORMANCE GUARANTEE

     A.   The equipment will be guaranteed to reduce the paniculate and/or gas
          contaminant loadings as indicated in the service description.

     B.   Performance test will be  conducted  in  accordance with  I.G.C.I, test
          methods where applicable.

     C.   Testing shall be conducted at a time mutually agreeable to the customer
          and the vendor.

     D.   The cost of the performance test is to be included in vendor's turnkey
          proposal.

     E.   In the  event the equipment fails to comply with the guarantee  at the
          specified design conditions, the vendor shall make every effort to correct
          any defect expeditiously at his own expense.  Subsequent  retesting to
          obtain a satisfactory result shall be at the vendor's expense.
V.   GENERAL CONDITIONS

     A.   Materials and Workmanship

         Only new materials of the best quality shall be used in the manufacture
         of items covered by this specification. Workmanship shall be of high quality
         and performed by competent workmen.

     B.   Equipment

         Equipment not of vendor's manufacture, furnished as a part of this collector
         shall carry the manufacturer's guarantee.
         Compliance with Applicable Work Standards and Codes

         It shall be the responsibility of the vendor to design and manufacture
         the equipment specified in compliance with the specified codes.
                                                  Preceding page  blank                3o9

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     2.   Upon receipt of order:

          a.    Proposed schedule of design and delivery.

     3.   Within 60 days of order:

          a.    Complete drawings of equipment for approval  by customer.

          b.    30 days prior to shipment:

               1)    Certified drawings of equipment, six sets

               2)    Installation instructions, six sets

          c.    30 days prior to startup:

               1)    Starting and operating instructions, six sets

               2)    Maintenance instructions and recommended spare parts
                    lists, six sets

E.   The design and construction of the collector and auxiliaries shall conform
     to the general conditions given in Section  III and to good engineering
     practice.

-------
              B.  INSTRUCTIONS FOR SUBMITTING COST DATA
Two forms (two copies each) are enclosed with each  specification. They have
been designed for the purpose of reporting the cost estimate prepared for each
specification. The forms are titled:

     A.   Estimated Capital Cost Data

     B.   Annual Operating Cost Data

These'forms will also be used to exhibit, in the final report for this study, averages
of the three cost estimates for each  process and equipment type.  Because your
costs will be averaged with those of other IGCI members,  it is necessary to prepare
them in accordance with instructions given in the following paragraphs.

A.   Estimated Capital Cost Data

The  upper part of this form should already be filled out for the particular application
when you receive it. This information on operating conditions should be identical
to that in the specification and is repeated only for the convenience of those reading
the form.

You  should fill in the estimated dollar amounts  in the appropriate spaces on the
bottom half of the form. It should not be necessary to add any information other
than  the dollar amounts. If you  wish to provide a description of the equipment
proposed, please do so on one  or more separate sheets of paper,  and attach it
to the form. If  any item is not involved in the equipment you are proposing, please
indicate this by writing "none" in the space rather than  leaving it blank or using
a zero.

     1.    The "gas cleaning device" cost should be reported just  as you  would
          report a flange-to-flange equipment sale to the  IGCI. That  is, a complete
          device including  necessary auxiliaries  such as power supplies, mist
          eliminators, etc.  Do  NOT  include such items  as  fans, solids  handling
          equipment, etc., unless these are an integral part of your gas cleaning
          device.

     2.    "Auxiliaries" are those items of equipment which are frequently supplied
          with the gas cleaning device. There is a purely arbitrary distinction between
          those  items included here and those included in the "Installation"  costs.
                                                                                         311

-------
                          Do NOT  include any of the cost of erecting or installing auxiliaries in
                          this category.

                     3.    "Installation  Cost" should  include the field  labor required  to complete
                          a turnkey installation as well as all of the  material not in 1. or 2. In
                          cases where the equipment supplier ordinarily erects the equipment but
                          does not  supply labor for foundations, etc., it is necessary to include an
                          estimated cost  for these items.  General tradework,  including  rigging,
                          erection, etc., should be included in the "Other" category.

                The installation  should  be estimated for a new plant, or one in which there are no
                limitations imposed  by the arrangement of existing equipment. Installation labor
                should be  estimated on the basis that the erection  will take place in an area
                where labor rates are  near the U.S.  average, and the  distance from your plant
                is  no more than 500 miles. Milwaukee, Wisconsin is an example of a city with
                near-average labor rates.
                B.   Annual Operating Cost Data

                Some of the information will be supplied by Air  Resources, such as unit costs
                for labor and utilities, and annualized capital charges. You should fill in the usage
                figures for the complete abatement system IN THE UNITS INDICATED  BELOW.

                          Labor                        hrs/year
                          Maintenance Materials         Dollars/year
                          Replacement Parts            Dollars/year
                          Electric Power                kw-hr/year
                          Fuel                          MMBtu/year
                          Water (Process)               MM gal/year
                          Water (Cooling)               MM gal/year
                          Chemicals                    Dollars/year
                                                       (for each chemical used)

                Air Resources will average the consumption figures reported, and convert them to
                dollar values for inclusion in the final report, using standard unit prices.

                Be sure that the operating  factor, indicated on the form in hours per year, is
                used for estimating the utility and labor requirements.
                Guidelines for Operating Cost Estimates

                The estimates of labor cost involved for operating and maintaining air pollution control
312

-------
systems are less likely to be based on first-hand knowledge than are the estimates
of capital cost for the gas cleaning equipment and system installation.  In order
to make comparable and consistent estimates of these costs, some general rules
should be  used by all of the participants in the program. This section describes
the rules which should be followed in making the estimates, and for describing the
estimating  basis in the reports prepared for the EPA.

Three alternative bases may be used for estimating the labor cost for operation
and maintenance of air pollution systems:

      1.     Direct first-hand knowledge of similar systems.

      2.     Detailed analysis of incremental labor requirements.

      3.     Percentage of first cost.

These alternatives are listed in order of preference; that is, direct first-hand knowledge
of labor costs is the most desirable, and a percentage of the first cost of the system,
the least desirable basis for estimating. The member companies are requested to
indicate which of these bases was  used in  the  preparation of each labor cost
estimate.

Direct first-hand knowledge comprises detailed records of the man-hours employed
by the owner  of an air pollution  control  system for operation and/or maintenance
of the equipment.

This  information should be  sufficiently detailed to  determine  that the time was
actually spent in connection  with the operating or  maintenance function for the
abatement  system, and not simply an arbitrary allocation of operators' or mechanics'
time between a process system and the associated abatement equipment. Such data
should be  used only  if it  is available for a system similar to that  being quoted
under this contract. A system should be considered similar only if it is  used  within
the subject industry and on substantially  the same process as that being quoted.
If the process size  is significantly  different from that which  is the subject of the
quotation, the  labor costs may be scaled up or  down on the basis of  realistic
appraisals  of the difference in requirements between large and small systems.  It
is not realistic  to scale labor costs in proportion to the size of the system.

Although first-hand information is the most desirable basis for estimating maintenance
and operating  costs,  it is unlikely that  acceptable  first-hand information will be
available often to the member companies. When it is used, the member company
should indicate the source of the data; i.e., system owned and operated by member,
feedback from  customer, industry or user survey program, etc.
                                                                                          313

-------
                A detailed analysis  of probable costs is likely to  be the  best method available
                to  the  member companies for estimating  operating and  maintenance labor.  A
                satisfactory detailed  analysis need not be complex  nor time-consuming. However,
                the estimate should be made in sufficient detail that  man-hour allocations are made
                to specific functions, as opposed to blanket assumptions of total operating or total
                maintenance labor. For example, the labor required  to rebalance the fan wheel and
                replace defective belts on an annual basis is a reasonable item with regard to
                level of detail.

                When using  this method, it is important to define  clearly the assumptions made
                with regard to the circumstances of system operation. Some of these assumptions
                are indicated in a general way below:

                    1.   Operating labor.

                         a.    Will the abatement system be operated by the same crew charged
                              with  operation  of the production equipment? If yes, operator time
                              should be allocated to the new abatement system.

                         b.    Are regular logs of operation  likely  to be helpful in obtaining best
                              operation of the abatement equipment?

                         c.    Is additional supervisory time required? If  yes,  some supervisor
                              time should be allocated to the abatement system.

                         d.    Will  any  special operator skill be required which would  limit the
                              ability of production equipment operators to serve as abatement
                              system operators?

                    2.   Maintenance labor.

                         a.    Will maintenance functions be performed routinely throughout the
                              year, or at annual or semi-annual equipment maintenance shutdown
                              periods?

                         b.    Have routine  maintenance  and  inspection  procedures been
                              recommended?

                         c.    Will there be any  special requirements for labor to purchase or
                              inventory spare parts?

                    3.   Can there be any labor credit for improvements in production equipment
                         operation due to the installation of the abatement system?
314

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C. CITY COST INDICES
Average 1969 Construction Cost & Labor Indices
City
Albany, N.Y.
Albuquerque, N.M.
Amarillo, Tx.
Anchorage, Ak.
Atlanta, Ga.
Baltimore, Md.
Baton Rouge, La.
Birmingham, Al.
Boston, Ma.
Bridgeport, Ct.
Buffalo, N.Y.
Burlington, Vt.
Charlotte, N.C.
Chattanooga, Tn.
Chicago, III.
Cincinnati, Oh.
Cleveland, Oh.
Columbus, Oh.
Dallas, Tx.
Dayton, Oh.
Denver, Co.
Des Moines, la.
Detroit, Mi.
Edmonton, Cn.
El Paso, Tx.
Erie, Pa.
Evansville, In.
Grand Rapids, Mi.
Harrisburg, Pa.
Hartford, Ct.
Honolulu, Hi.
Houston, Tx.
Indianapolis, In.
Jackson, Ms.
Jacksonville, Fl.
Kansas City, Mo.
Knoxville, Tn.
Las Vegas, Nv.
Little Rock, Ar.
Los Angeles, Ca.
Louisville, Ky.
Madison, Wi.
Manchester.N.H.
Memphis, Tn.
Miami, Fl.
Index
Labor
98
86
87
131
88
90
83
79
106
104
104
86
70
81
107
108
121
106
86
100
94
93
117
80
77
98
93
103
90
104
99
92
97
73
78
94
82
115
78
113
92
95
89
83
98
Total
100
95
84
148
94
93
88
86
103
102
107
90
75
84
103
104
112
99
89
103
91
96
111
83
83
99
97
99
92
100
109
89
98
75
79
93
82
107
81
102
93
98
92
82
94
City
Milwaukee, Wi.
Minneapolis, Mn.
Mobile, Al.
Montreal, Cn.
Nashville, Tn.
Newark, N.J.
New Haven, Ct.
New Orleans, La.
New York, N.Y.
Norfolk, Va.
OklahomaCity.Ok.
Omaha, Nb.
Philadelphia, Pa.
Phoenix, Az.
Pittsburgh, Pa.
Portland, Me.
Portland, Or.
Providence, R.I.
Richmond, Va.
Rochester, N.Y.
Rockford, III.
Sacramento, Ca.
St. Louis, Mo.
Salt Lake City, Ut.
San Antonio, Tx.
San Diego, Ca.
San Francisco, Ca.
Savannah, Ga.
Scranton, Pa.
Seattle, Wa.
Shreveport, La.
South Bend, In.
Spokane, Wa.
Springfield, Ma.
Syracuse, N.Y.
Tampa, Fl.
Toledo, Oh.
Toronto, Cn.
Trenton, N.J
Tulsa, Ok.
Vancouver, Cn.
Washington, D.C.
Wichita, Ks.
Winnipeg, Cn.
Youngstown, Oh.
Index
Labor
103
99
94
77
79
122
102
89
132
73
82
90
106
101
110
82
102
98
76
110
109
117
110
93
82
111
124
72
94
104
82
99
101
99
105
81
105
84
114
85
81
98
85
62
107
Total
108
98
90
89
82
109
100
95
118
77
88
93
101
97
106
87
103
97
79
107
109
110
103
95
82
107
109
77
96
99
89
97
100
97
103
84
105
93
103
89
91
94
90
82
106
Historical Average
Year
1969
1968
1967
1966
1965
1964
1963
1962
1961
1960
1959
1958
1957
1956
1955
1954
1953
1952
1951
1950
1949
1948
1947
1946
1945
1944
1943
1942
1941
1940
1939
1938
1937
1936
1935
1934
1933
1932
1931
1930
1929
1928
1927
1926
1925
1924
Index
100
91
86
83
79
78
76
74
72
71
69
67
65
63
59
58
57
55
53
49
48
48
43
35
30
29
29
28
25
24
23
23
23
20
20
20
18
17
20
22
23
23
23
23
23
23
                                                    315

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D.  AVERAGE HOURLY LABOR RATES BY TRADE
Trade
Common Building Labor
Skilled Average
Helpers Average
Foremen (usually 35d over trade)
Bricklayers
Bricklayers Helpers
Carpenters
Cement Finishers
Electricians
Glaziers
Hoist Engineers
Lathers
Marble & Terrazzo Workers
Painters, Ordinary
Painters, Structural Steel
Paperhangers
Plasterers
Plasterers Helpers
Plumbers
Power Shovel or Crane Operator
Rodmen (Reinforcing)
Roofers, Composition
Roofers, Tile & Slate
Roofers Helpers (Composition)
Steamfitters
Sprinkler Installers
Structural Steel Workers
Tile Layers (Floor)
Tile Layers Helpers
Truck Drivers
Welders, Structural Steel
1970
$5.00
6.85
5.15
7.20
7.15
5.20
6.95
6.75
7.50
6.25
7.05
6.60
6.45
6.20
6.50
6.30
6.60
5.30
7.75
7.20
7.30
6.30
6.35
4.75
7.70
7.70
7.45
6.50
5.25
5.15
7.15
1969
$4.55
6.05
4.65
6.40
6.40
4.70
6.15
5.90
6.45
5.50
5.90
5.95
5.60
5.45
5.80
5.60
5.95
4.85
6.90
6.20
6.35
5.55
5.60
4.45
6.90
6.90
6.45
5.60
4.80
4.60
6.35
1968
$4.10
5.50
4.20
5.85
5.85
4.30
5.40
5.30
5.95
5.10
5.40
5.45
5.25
5.05
5.30
5.15
5.50
4.45
6.15
5.65
5.80
5.05
5.10
4.00
6.10
6.10
5.90
5.20
4.35
4.30
5.80
1967
$3.85
5.15
4.00
5.50
5.55
4.05
5.10
5.05
5.60
4.75
5.10
5.20
5.05
4.75
4.95
4.75
5.15
4.15
5.75
5.35
5.45
4.75
4.85
3.75
5.70
5.70
5.55
4.90
4.15
3.95
5.45
1966
$3.65
4.90
3.85
5.25
5.35
3.95
4.90
4.85
5.45
4.60
4.85
5.05
4.90
4.50
4.80
4.55 ,
5.00
4.00
5.55
5.05
5.15
4.65
4.80
3.55
5.50
5.50
5.25
4.80
4.05
3.65
5.10
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317

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E.   LIST OF STANDARD ABBREVIATIONS
feet or foot
inch or inches
ton or tons
pound or pounds
hours or hours
minute or minutes
parts per million
grain or grains
weight percent
actual cubic feet per minute
standard cubic feet per minute
dry standard cubic feet per minute
standard cubic feet
actual cubic feet
British thermal units
odor units
volume
mole
gallon
per cent
dollars
degrees Fahrenheit
pounds per square inch gauge
change of pressure (delta pressure)
water column (pressure)
change of temperature (delta temperature)
temperature
feet per minute
dry standard cubic feet
cubic feet
revolutions per minute
gallons per minute
millions (106)
atmospheres  gage (pressure)
milligrams
micrograms
international unit
hundred weight (100 pounds)
hydrocarbon
United States pharmacopoeia
                                 ft
                                 in.
                                 ton
                                 Ib
                                 hr
                                 min
                                 ppm
                                 gr
                                 wt.%
                                 ACFM
                                 SCFM
                                 DSCFM
                                 SCF
                                 ACF
                                 Btu
                                 o.u.
                                 vol
                                 mol
                                 gal
                                 %
                                 $
                                 ฐF
                                 psig
                                 A P
                                 w.c.
                                 A T
                                 Temp
                                 FPM
                                 DSCF
                                 ft3
                                 rpm
                                 gpm
                                 MM
                                 atmg
                                 m9
                                 Y9
                                 ID
                                 cwt
                                 Hcbn
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