ADDENDUM REPORT AND DETERMINATION OF
CHLOROPHENOLICS, SPECIAL ANALYTICAL
SERVICES CONTRACT 1047, EPISODE 1886
Analytical Technologies Inc.,
Prepared for W. A. Telliard, Industrial Technology Division
(WH-552)
U.S. EPA
401 M St. SW
Washington, DC 20450
May 1991
-------
•ection 1: Sample Numbers and Dates of Receipt
Table 1: Sample Numbers and Dates of Receipt
Episode
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
1886
—Sample Identifications-
EPA ATI
Date
Received Analysis
19355
19356
19357
19358
19359
19360
19361
19362
19364
19365
19366
19367
19368
19369
19370
19371
19372
19373
19375
19376
19377
19378
19379
19380
19381
19382
19383
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
90-05-
,90-05-
90-05-
90-05-
90-05-
•031-
•031-
031
031-
•031-
•031-
•031-
031-
•033-
•033-
•033-
033-
033-
033-
•033-
033-
•033-
•033-
037-
037-
037-
037-
037-
037-
037-
•037-
037-
•01A
•01A
02A
02A
•03A
06A
•07A
08A
•01A
•02A
03A
04A
05A
06A
•07A
08A
09A
•10A
01A
•02A
03A
04A
•05A
06A
07A
08A
09A
05/17/90
05/17/90
05/17/90
05/17/90
05/17/90
05/17/90
05/17/90
05/17/90
05/18/90
05/18/90
05/18/90
05/18/90
05/18/90
05/18/90
05/18/90
05/18/90
05/18/90
05/18/90
05/19/90
05/19/90
05/19/90
05/19/90
05/19/90
05/19/90
05/19/90
05/19/90
05/19/90
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Chlorophenolics
Section 2: Narrative
2.1 SAS Information
SAS solicitation No. 1047 was received on May 7, 1990.
The response to bid was sent via fax on May 9, 1990. Award was
made via fax on May 10, 1990 by Susan B. Grove for Viar & Co.
Copies of page one of the SAS, the bid response, and the award
notification are given in Appendix A. The contract letter was
mailed on June 15, 1990 per Susan B. Grove.
2.2 Sample Logistics
Samples were received in three shipments on the dates shown
in Table 1. All samples were received cool and intact. Traffic
Reports and ATI Workorders for these samples are given in
Appendix B.
page -3-
-------
2.3 Reference standard
Standards for chlorophenols were obtained from Ultra Chemical
Co. Standards for the remaining chlorophenolics were obtained
from Helix Biotech. Standards for all chlorophenolics specified
in NCASI Method CP-85.01 (including those blacked out in the SAS)
were available except for 3,6-Dichlorocatechol. Standards were
obtained for the following chlorophenolics not specified in the
NCASI method but available from Helix Biotech:
4-Chlorocatechol
3,5-Dichlorocatechol
5-Chloroguaiacol
6-Chloroguaiacol
3,4,5-Trichloroguaiacol
3,4,6-Trichloroguaiacol
2,6-Dichlorosyringealdehyde
The GC systems were calibrated with all standards available,
including the above.
Technical data on chlorophenolic standards is presented in
Appendix C.
2.4 Derivitization/extraction/concentration of chlorophenolics
The derivitization/extraction/concentration processes were
straightforward with good recoveries of the analytes and
surrogate from reagent water in the precision and recovery tests.
Laboratory chronicles are presented in Appendix D.
Because standards are not available in derivitized form,
there is always a concern that complete derivitization did not
occur. However, calibration data showed a single, distinct peak
for each compound, thus indicating complete derivitization.
2.5 Analysis by Gas Chromatography (GC)
Sample extracts were analyzed using a 30 meter DB-1 column
and a 30 meter DB-608 column. The NCASI method specifies a 15
meter DB-1 column and no confirmatory column. The 30 meter
column improved the separation of the analytes, and the
confirmatory column permitted rigorous identification.
Columns and conditions:
DB-1
30 meter x 0.53 mm i.d., methyl silicone with 1.5 micron
film thickness
DB-608
30 meter x 0.53 mm i.d., 35 percent phenyl, 65 percent
methyl silicone with 0.83 micron film thickness
Injector temperatures: 200 ° C
Temperature program: 140 ° C for 1 minute, 140-190 ° C at
2 ' C per minute, 190-220 ° C at 10 ° C per minute, 220-280
° C at 20 ° C per minute, 280 ° C for 2 minutes.
Detectors: Electrolytic conductivity in halogen mode
Carrier gas and flow rates: Helium @ 8 mL/min.
Sample size: 3 uL injected with dual auto-injectors.
page -4-
-------
2.6 Identification
Analytes were identified by comparing retention times on the
two columns with retention time windows derived from calibration
data and by comparing the concentration determined on each
column/detector system. For all samples in which an analyte was
detected, the retention times were within their respective
windows on both columns and the concentrations were within a
factor of two. If these conditions were not met, the analyte was
considered not identified. Supporting quality control data for
these identifications is given in Section 3 of this report.
2.7 Quantitation
Concentrations in sample extracts were determined by
applying the average calibration factor (response divided by
amount) from a multi-point calibration, per the following
equation:
Ce = CF x response
where C is the concentration of the sample extract, CF is the
calibration factor from the calibration, and the response is the
peak height or peak area in the analysis of the sample. The
calibration factors are listed in the Section 4, and the
responses are tabulated in Section 3 of this report.
Cs Cc (ua/mLl x V (mL)
Vs (L)
where Cs is the concentration in the sample. The sample volumes
and the extract volumes are given in Section 3 of this report
and in the Laboratory Chronicles in Appendix D.
2.8 Supporting Quality Control Data
These data are summarized in Section 4. Data are presented
for:
Initial Calibration
Retention Time Windows
Calibration Verification
Initial Precision and Recovery
Ongoing Precision and Recovery
Analysis of a Blank
2.9 Supporting Raw Data
Supporting raw data including chromatograms and quantitation
lists are presented in Appendix E.
3.0 Telephone Logs
Telephone logs and faxes are contained in Appendix F-
Section 3: Results and Detection Limits
Table 2: Results obtained for Chlorophenolics
page -5-
-------
Section 4: Supporting Quality Assurance/Quality Control Data
Table 3: Quantitation of chlorophenolics
Table 4: Identification of chlorophenolics
Table 5: Initial precision and recovery for chlorophenolics
Table 6: On-going precision and recovery for chlorophenolics
Table 7: Surrogate recoveries and compounds detected in blanks
for chlorophenolics
Table 8: Matrix spike recoveries for chlorophenolics
Table 9: Run chronology for chlorophenolics
Table 10: Calibration for chlorophenolics
Table 11: Calibration verification for chlorophenolics
CERTIFICATION
Analytical Technologies Inc. certifies that the analyses reported
herein are true, complete, and correct within the limitations of
the methods employed.
ry^/ErTJa
Operations Manager
/
Dale R Rushneck
Laboratory Manager and Quality
Assurance
page -6-
-------
IL TECHNOLOGIES INC. SAS 1047
Results Obtained for Chlorinated Phenolics. Concentration
D
.orophenol
.orophenol
orophenol
uaiacol
chlorophenol
oroguaiacol
orocatechol
anillin
orocatechol
chloroguaiacol
orovanillin
ingaldehyde
chlorocatechol
syringol
orosyringaldehyde
henol
orophenol
chlorophenol
uaiacol
chlorophenol
col
etrachlorophenol
chloroguaiacol
orocatechol
chloroguaiacol
rophenol
roguaiacol
rocatechol
Blank
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
19355 19356
< 0.3
( 0.3 <
< 0.3 <
< 0.
< 0.
3.
< 0.
< 0.
< 2.
0.
< 0.
1.
< 0.
< 0.
< 1.
( 0.
< 0.
( 0.
< 0.
0.
< 0.
< 0.
< 0.
< 1.
1.
< 0.
( 0.
< 0.
,5 (
,1 (
0 <
5
5 <
5 <
1 <
5 <
0 (
3 <
3 «
3 <
3 " '
1 <
3 <
5 <
5
5 <
3 <
5' <
0
1 <
1 '•
1 <
3
5.7
2.5
2.5
5.0
1.0
2.5
53
5.0.
25
1.0
5.0
5.0
2.5
2.5
13
2.5
1.0
2.5
5.0
24
5.0
1 C
6 . J
5.0
46
2.5
1.0
1.0
57
D
19357
< 2.5
< 2.5
< 2.5
< 5.0
< 1.0
61
< 5.0
< 5.0
< 25
5.3
< 5.0
( 5.0
< 2.5
36
29
'. 2.5
< 1.0
27
< 5.0
18
< 5.0
11
10
< 10
125
< 1.0
3.1
' 2.5
s in ug/L.
PA Sauple
19358
< 0.3
< 0.3
( 0.3
< 0/5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< h3
' 0.3
< 0.1
•' 5.3
( 0.5
' 0.3
( 0.5
•• 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
• 0.3
Nunbers
19359
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
( 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
'. 0.3
< 0.1
( 0.3
( 0.5
< 0.3
< 0.5
< 0.3
< 0.5
( 1.0
< 0.3
< 0.1
< 0.1
< 0.3
19360
< 0.3
< 0.3
< 0.3
< 0.5
0.1
2.9
( 0.5
1.4
( 2.5
< 0.1
< 0.5
< 0.5
< 0.3
1.3
2.1
'. 0.3
'. 0.1
1.4
< 0.5
2.2
< 0.5
< 0.3
< 0.5
!.0
6.0
< 0.1
• 0.1
0.3
19361
< 0.
< 0.
< 0.
< 0.
0.
2.
4.
( 0.
1.
< 0.
< 0.
0.
< 0.
1.
1.
< c.
< 0.
0
6 •
< 0.
2.
< 0.
( 0.
< 0.
6.
4.
i ,
< 0.
< 0.
3
3
3
5
1
9
5
5
4
1
5 ,
8
0
J
1
4
i
i
•>
j
5
•*T
t
5
3
5
0
6
6
1
3
19362
< 0.3
< 0.3
< 0.3
< 0.5
( 0.1
1.2
1.8
1.8
1.1
( 0.1
< 0.5
< 0.5
< 0.3
0.4
1.1
< 0.3
0.1
0.3
< 0.5
1.1
< 0.5
< 0.3
1.5
2.5
1.1
< 0.1
< 0.1
0.3
-------
TECHNOLOGIES INC. SiS 1047
[Results Obtained
!
'Dichlorophenol
•Dichlorophenol
•Dichlorophenol
Chloroguaiacol
'richlorophenol
Chloroguaiacol
chlorocatechol
Chlorovanillin
chlorocatechol
Chloroguaiacol
.chlorovanillin
isyringaldehyde
chlorocatechol
chlorosyringol
irosyringaldehyd
4-Chloro?henoi
Dichlorophenol
richlorophenol
Chloroguaiacol
richlorophenol
4,5-Guaiacol
trachlcrophenol
Chloroguaiacol
chlorocatechol
Chloroguaiacol
tachlorophenol
:hloroguaiacol
:hlorocatechol
for Chlorinated Phenolics. Concentrati
D
19364
0.4
< 0.3
< 0.3
( 0.5
< 0.1
11
< 0.5
0.5
( 2.5
0.5
< 0.5
2.0
< 0.3
< 0.3
( 1.3
< 0.3
< 0.1
1.1
< 0.5
0.6
< 0.5
( 0.3
( 0.5
< 1.0
1.3
< 0.1
< 0.1
< 0.3
19365
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
5.8
( 0.5
< 0.5
< 2.5
0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
0.6
< 0.5
0.4
< 0.5
< 0.3
< 0.5
< 1.0
O.B
< 0.1
< 0.1
< 0.3
19366
13
< 2.5
( 2.5
< 5.0
< 1.0
< 2.5
67
15
< 25
2.4
< 5.0
< 5.0
< 2.5
< 2.5
12
( 2.5
( 1.0
( 2.5
< 5.0
26
( 5.0
< 2.5
( 5.0
61
< 2.5
< 1.0
< 1.0
20
L
19367
< 2.5
< 2.5
< 2.5
7.2
( 1.0
65
< 5.0
( 5.0
7.0
5.6
< 5.0
< 5.0
< 2.5
45
46
< 2.5
3.7
23
< 5.0
28
< 5.0
17
16
< 10
144
< 1.0
8.2
< 2.5
ons in ug/l
PA Saople 1
19368
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
( 0.5
< 0.5
< 0.3
( 0.3
< 1.3"
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
( 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
L. (Continued)
NUUUCL 3
19369
< 0.3
< 0.3
< 0.3
( 0.5
0.1
2.9
< 0.5
1.4
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
1.3
2.1
< 0.3
< 0.1
1.4
t 0.5
2.2
< 0.5
< 0.3
< 0.5
< 1.0
6.0
< 0.1
< 0.1
< 0.3
19370
< 0.5
< 0.5
( 0.5
< 1.0
( 0.2
< 0.5
< 1.0
4.9
( 5.0
< 0.2
< 1.0
< 1.0
7.2
4.1
4.0
0.5
< 0.2
2.0
< 1.0
3.8
< 1.0
•: 0.5
< 1.0
< 2.0
9.7
5.2
3.5
< 0.5
19371
< 0.5
< 0.5
< 0.5
( 1.0
0.3
4.4
5.2
1.8
( 5.0
0.7
< 1.0
< 1.0
< 0.5
< 0.5
2.8
< 0.5
0.7
3.3
< 1.0
4.9
< 1.0
< 0.5
1.3
8.4
8.9
2.4
< 0.2
( 0.5
19372
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
1.4
1.4
3.0
1.4
< 0.1
4 0.5
< 0.5
< 0.3
< 0.3
1.3
< 0.3
0.2
0.6
< 0.5
1.4
< 0.5
1.1
.0.8
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
-------
ft, TECHNOLOGIES IHC. SAS 1047
Results Obtained
-Dichlorophenol
-Dichlorophenol
-Dichlorophenol
-Chloroguaiacol
Trichlorophenol
ichloroguaiacol
ichlorocatechol
-Chlorovanillin
ichlorocatechol
ichloroguaiacol
ichlorovanillin
osyringaldehyde
ichlorocatechol
ichlorosyringol
orosyringaldehyd
4-Chlorophenol
-Dichlorophenol
rrichlorophenol
-Chloroguaiacol
Prichlorophenol
4,5-Guaiacol
>trachlorophenol
ichloroguaiacol
ichlorocatechol
ichloroguaiacol
tachlorophenol
ichloroguaiacol
ichlorocatechol
for Chlorinated Phenolics. Concentrati
0
19373
< 0.3
< 0.3
< 0.3
( 0.5
< 0.1
1.9
1.9
3.0
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
0.9
2.2
< 0.3
0.2
0.6
< 0.5
1.6
< 0.5
< 0.3
0.5
< 1.0
< 0.3
< 0.1
< 0.1
0.5
19375
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
( 2.5
< 0.1
( 0.5
< 0.5
( 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
( 1.0
( 0.3
< 0.1
( 0.1
( 0.3
19376
< 0.3
< 0.3
< 0.3
1.4
< 0.1
( 0.3
0.8
< 0.5
0.9
0.8
1.7
< 0.5
0.6
0.2
< 1.3
- ' 0.3
' 0.1
< 0.3
< 0.5
1.4
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
0.4
0.9
< 0.3
&
19377
< 2.5
< 2.5
< 2.5
8.9
< 1.0
< 2.5
98
< 5.0
< 25
< 1.0
< 5.0
( 5.0
( 2.5
< 2.5
< 13
3.2
< 1.9
< 2.5
( 5.0
41
' 5.0
' 2.5
( 5.0
77
< 2.5
< 1.0
' 1.0
26
ons in ug/
PA Sanple
19378
< 2.5
< 2.5
< 2.5
< 5.0
< 1.0
64
( 5.0
< 5.0
< 25
11
< 5.0
( 5.0
< 2.5
39
14"
< 2.5
5.0
27
( 5.0
29
< 5.0
< 2.5
13
< 10
125
'. 1.0
< 1.0
' 2.5
L. (Continued)
NuDoers
19379
< 0.3
1.2
< 0.3
< 0.5
< 0.1
< 0.3
( 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
( 0.3
< 0.3
( 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
( 0.5
< 0.3
< 0.5
< 1.0
< 0.3
' 0.1
< 0.1
< 0.3
19380
< 0.3
< 0.3
( 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
( 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< C.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
; 0.3
' 0.1
< 0.1
< 0.3
19381
< 0.5
( 0.5
( 0.5
2.0
< 0.2
< 0.5
3.8
2.3
2.3
< 0.2
7.6,
< 1.0
< 0.5
( 0.5
< 2.5
' 0.5
< 0.2
1.1
< 1.0
3.9
< 1.0
( 0.5
< 1.0
< 2.0
< 0.5
< 0.2
< 0.2
' 0.5
19382
< 0.5
( 0.5
< 0.5
< 1.0
0.9
7.9
11.3
1.8
3.2
1.8
< 1.0
< 1.0
< 0.5
3.9
4.3
1.0
1.1
4.7
< 1.0 .
6.6
< 1.0
< 0.5
< 1.0
12.6
13.0
< 0.2
< 0.2
( 0.5
19383
< 0.3
< 0.3
< 0.3
( 0.5
< 0.1
6.8
7.1
7.1
< 2.5
< 0.1
< 0.5
5.8
< 0.3
2.7
5.9
3.3
0.9
1.9
< 0.5
4.3
' 0.5
2.6
• 0.5
15.5
• 0.3
3.2
0.1
' 0.3
-------
PBEAL TECHNOLOGIES INC.
(PWUFKAHONS
SAS 1047
Blank ATI No. 90-05-031-00
Sample Volume (Vs) = 100 mL
: Extract Volume (Ve) = 5 mL
COMPOUND
MIX A
c&lorophenol
c&lorophenol
cnlorophenol
oiguaiacol
Trichlorophenol
ciloroguaiacol
ellorocatecnol
rivanillin
ellorocatechol
wichloroguaiacol
cllorovanillin
sfringaldehyde
rrichlorocatechol
ajosyringol
cjilorosyringaldehyde
MIX B
raphenol
±lorophenol
IMdilorophenol
cigguaiacol
ftichlorophenol
dfecol
S^Tetrachlorophenol
^.chloroguaiacol
iorocatechol
chloroguaiacol
rophenol
roguaiacol
rocatechol
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
.DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05-
2.12E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
4"
chlorophenol DB-608 43885 9.41E-05 4.13
0.1
dpration factors from average of 4-point calibration. CF = Cone (ug/mL)/peak area
; = CF * A
«e/Dil factor (X) is the amount the extract is concentrated or diluted
; = (Ce * Ve * x * 1000)/Vs
21
-------
TECHNOLOGIES INC.
SAS 1047
QUANTIFICATIONS
3. 19355
Sample Volime (Vs)
Extract Volume (Ve)
ATI No.
90-05-031-01
100 mL
5 mL
(IMPOUND
MIX A
jhlorophenol
lilorophenol
lilorophenol
pguaiacol
llchlorophenol
filoroguaiacol
nlorocatechol
fcvanillin
JLLorocatechol
pchloroguaiacol
lilorovanillin
irringaldehyde
llchlorocatechol
rosyringol
llorosyringaldehyde
MIX B
iphenol
lorophenol
ichlorophenol
guaiacol
ichlorophenol
acol
Tetrachlorophenol
Richloroguaiacol
|lorocatecnol
tichloroguaiacol
lorophenol
loroguaiacol
lorocatechol
*
i
lichlorophenol
Quant.
Colurm
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak CaliJ)
Area Factor
(A) (CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
5676 1.05E-04
1.20E-04
76 2.80E-04
1.13E-04
282 8.49E-05
1.18E-04
560 3.54E-04
8.37E-05
472 7.95E-05-
2.12E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
958 1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
2159 1.02E-04
5.86E-05
7.31E-05
8.26E-05
29352 9.41E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
0.60
< 0.10
< 0.10
< 0.50
0.02
< 0.10
0.20
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
0.10
< 0.10
< 0.05
< 0.10
< 0.20
0.22
< 0.02
< 0.02
< 0.05
2.76
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
3.0
< 0.5
< 0.5
< 2.5
0.1
< 0.5
1.0
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
0.5
< 0.5
< 0.3
< 0.5
< 1.0
1.1
< 0.1
< 0.1
< 0.3
14
-------
TECHNOLOGIES INC.
SAS 1047
QOMmFICATIONS
19356
Sample Volume (Vs)
Extract Volume (Ve)
ATI No.
90-05-031-02
100 mL
5 mL
COMPOUND
MIX A
lorophenol
lorophenol
lorophenol
guaiacol
idilorophenol
loroguaiacol
lorocatechol
vanillin
lorocatechol
ichloroguaiacol
lorovanillin
ringaldehyde
ichlorocatechol
osyringol
lorosyringaldehyde
MIX B
phenol
lorophenol
idilorophenol
juaiacol
Lchlorophenol
icol
Petrachlorophenol
Ldiloroguaiacol
Lorocatechol
ichloroguaiacol
irophenol
iroguaiacol
irocatechol
ehlorophenol
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calih
Area Factor
(A) (CF) (1)
1489 7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
8915 1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
290 1.43E-04
l.OOE-04
2.02E-04
1.68E-04
4806 1.01E-04
8.49E-05
1.24E-04
1.24E-04
5415 1.70E-04
1.02E-04
5.86E-05
7.31E-05
13917 8.26E-05
4729 9.41E-05
Cone, in
Extract
Ce (ug/mL) (2)
0.11
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
1.07
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
0.49
< 0.10
< 0.05
< 0.10
0.92
< 0.05
< 0.02
< 0.02
1.15
0.44
Conc/Dil
Factor
(X) (3)
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Sample
Cone.
Cs (ug/L) (4)
5.7
< 2.5
< 2.5
< 5.0
< 1.0
< 2.5
53
< 5.0
< 25
< 1.0
< 5.0
< 5.0
< 2.5
< 2.5
< 13
< 2.5
< 1.0
< 2.5
< 5.0
24
< 5.0
< 2.5
< 5.0
46
< 2.5
< 1.0
< 1.0
57
22
-------
DC.
SAS 1047
QUSNTIFICaTIONS
19357
ATI No.
90-05-031-03
Sample Volume (Vs) =
fectract Volume (Ve) =
COMPOUND
MIX A
chlorophenol
cHlorophenol
ettlorophenol
riguaiacol
mlchlorophenol
Jloroguaiacol
CTlorocatechol
iSvanillin
dalorocatechol
Tlichloroguaiacol
ellorovanillin
sfringaldehyde
Tiichlorocatechol
olosyringol
Aorosyringaldehyde
1 MIX B
Ahenol
dtlorophenol
tteLchlorophenol
njguaiacol
l&chlorophenol
ajacol
^Tetrachlorophenol
Wchloroguaiacol
dBLorocatechol
lAchloroguaiacol
hSprophenol
f|proguaiacol
Wbrocatechol
100 mL
5 mL
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
11599
1251
9065
2730
2681
3604
1700
1626
24601
840
Calib
Factor
(CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05-
2.12E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
1.22
< 0.10
< 0.10
< 0.50
0.11
< 0.10
< 0.10
< 0.05
0.72
0.58
< 0.05
< 0.02
0.54
< 0.10
0.36
< 0.10
0.21
0.20
< 0.20
2.51
< 0.02
0.06
< 0.05
Conc/Dil
Factor
(X) (3)
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Sample
Cone.
Cs (ug/L) (4)
< 3
< 3
< 3
< 5
< 1
61
< 5
< 5
< 25
5
< 5
< 5
< 3
36
29
< 3
< 1
27
< 5
18
< 5
11
10
< 10
125
< 1
3
< 3
ntchlorophenol
DB-608
4829 9.41E-05
0.45
1.0
23
-------
H^L TECHNOLOGIES INC.
SAS 1047
QGAmFKATIGNS
19358
Sample Volune (Vs)
Detract Volume (Ve)
ATI No.
90-05-031-04
100 DfiL
5 mL
COMPOUND
fflXA
orophenol
orophenol
orophenol
uaiacol
chlorophenol
oroguaiacol
orocatechol
anillin
orocatechol
chloroguaiacol
orovanillin
ingaldehyde
chlorocatechol
syringol
orosyringaldehyde
MIX B
henol
orophenol
chlorophenol
uaiacol
chlorophenol
col
etrachlorophenol
chloroguaiacol
orocatechol
qichloroguaiacol
.( rophenol
( roguaiacol
(rocatechol
Quant.
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-OS
2.12E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
Conc/Dil
Factor
(X) (3)
0.1
6.1
0.1
0.1
0.1
0.1"
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
^chlorophenol
DB-608
33139 9.41E-05
3.12
0.1
16
-------
CHj TECHNOLOGIES INC.
SAS 1047
OJJANTIFICATIONS
|9359
Sanple Volune (Vs)
Eftract Volume (Ve)
ATI No.
90-05-031-05
100 mL
5 mL
COMPOUND
MIX A
Mfcrophenol
hjtrophenol
ttforophenol
oghaiacol
pftMorophenol
yproguaiacol
ISxocatechol
amnillin
dM>rocatechol
OT±loroguaiacol
[Jprovanillin
ratngaldehyde
ilfoilorocatechol
rlbyringol
S^rosyringaldehyde
MIX B
Aenol
il>rophenol
Ahlorophenol
xliaiacol
^phlorophenol
Lapol
•Tfetrachlorophenol
aiiloroguaiacol
m>rocatechol
:ipiloroguaiacol
Lwophenol
iifx>guaiacol
.orocatechol
Quant.
Golunn
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05-
2.12E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cfflic. in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
'. 0.02
< 0.02
< 0.05
Conc/Dil
Factor
00 (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Gone.
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
•iichlorophenol
DB-608
33507 9.41E-05
3.15
0.1
16
-------
TECHNOLOGIES INC.
SAS 1047
QUALIFICATIONS
ATI No.
le Volume (Vs)
ract Volume (Ve)
90-05-031-06
100 mL
5 mL
COMPOUND
MIX A
lifcrophenol
hprophenol
Krophenol
OMiaiacol
raMorophenol
raproguaiacol
rorocatechol
Jpnillin
hlfcrocatechol
abhloroguaiacol
tttrovanillin
mngaldehyde
drhlorocatechol
KByringol
l^prosyringaldehyde
MIX B
Dljienol
hfl>rophenol
ijcnlorophenol
Dgjbiacol
ijpilorophenol
iieol
-mrachlorophenol
i^hloroguaiacol
ajjlrocatechol
npiloroguaiacol
LOTophenol
®oguaiacol
llfocatechol
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
325
5435
1005
3270
1983
1400
4417
11711
Calib
Factor
(CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05-
2.12E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
0.02
0.57
< 0.10
0.28
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
0.26
0.42
< 0.05
< 0.02
0.28
< 0.10
0.45
< 0.10
< 0.05
< 0.10
< 0.20
1.19
< 0.02
< 0.02
< 0.05
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1"
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
0.1
2.9
< 0.5
1.4
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
1.3
2.1
< 0.3
< 0.1
1.4
< 0.5
2.2
< 0.5
< 0.3
< 0.5
< 1.0
6.0
< 0.1
< 0.1
< 0.3
riehlorophenol
DB-608
27246 9.41E-05
2.56
0.1
13
-------
lALiTOCHNOl/DGIES DC.
SAS 1047
QUAOTIFKATIQNS
$361
ATI No.
90-05-031-07
J
!!
1
1
1
1
1
I
I
I
1
1
il
*
IA
I
id
1
id
taple Volute (Vs) -
tract Volune (Ve) =
OCMPOUND
MIX A
rophenol
rophenol
rophenol
aiaool
alorophenol
roguaiacol
cocatediol
iiillin
cocatediol
dloroguaiacol
rovanillin
tigaldehyde
ilorocatechol
fringol
rosyringaldehyde
MIXB
3K)1
rophenol
ilorophenol
dacol
ilorophenol
)1
:rachlorophenol
iloroguaiacol
Itfrocatechol
idiloroguaiacol
4
OK
°f
)phenol
jguaiacol
)catechol
100 mL
5 mL
Peak
Quant. Area
Golum (A)
W-l
HB-1
W-l
V&-I
IB-1
IB-1
W-l
DB-1
Iffl-1
I»-l
Iffl-1
IB-1
DB-1
Iffl-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
445
5482
7549
289
2456
450
2754
1277
2243
5400
7093
9078
5539
Calii
Factor
(CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05.
7.95E-05
2.12E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Gene, in
Extract
Ce (ug/tnL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
0.03
0.58
0.91
0.10
0.28
< 0.02
< 0.10
0.16
< 0.05
0.22
0.27
< 0.05
< 0.02
0.45
< 0.10
0.55
< 0.10
0.05
•: 0.10
1.21
0.93
0.32
< 0.02
< 0.05
Conc/Dil
Factor
00 (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Saople
Gone.
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
0.1
2.9
4.5
< 0.5
1.4
< 0.1
< 0.5
0.8
< 0.3
1.1
1.4
< 0.3
< 0.1
2.3
< 0.5
2.7
< 0.5
< 0.3
< 0.5
6.0
4.6
1.6
< 0.1
< 0.3
tilorophenol
DB-608
23287 9.41E-05
0.1
11
-------
INC.
SAS 1047
QUMmriCATICNS
$362
Simple Volune (Vs)
E#ract Volume (Ve)
ATI Mb.
90-05-031-08
100 mL
5 mL
OCMPCUND
MIX A
GJUphenol
iDrophenol
J&ophenol
iglaiacol
;Milorophenol
fflroguaiacol
tfflrocatechol
flfrniillin
dlrocatechol
oailoroguaiacol
ilmxivanillin
rangaldehyde
iqhlorocatechol
t^ringol
ilorosyringaldehyde
MIX B
jLnol
liftxiphenol
•fflilorophenol
fflraiacol
•Milorophenol
aaDl
TSarachlorophenol
ijliloroguaiacol
iMtxatechol
"Miloroguaiaool
^phaiol
<«3guaiaool
orpcatechol
i^ilorophenol
Quant.
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
569
2987
3680
1610
2486
1461
1401
184
334
2207
2342
2997
2183
823
20492
Calib
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61£-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
9.41E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
0.24
0.35
0.36
0.23
< 0.02
< 0.10
< 0.10
< 0.05
0.09
0.23
< 0.05
0.02
0.07
< 0.10
0.22
< 0.10
< 0.05
0.29
0.51
0.22
< 0.02
< 0.02
0.07
1.93
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
1.2
1.8
1.8
1.1
< 0.1
< 0.5
< 0.5
< 0.3
0.4
1.1
< 0.3
0.1
0.3
< 0.5
1.1
< 0.5
< 0.3
1.5
2.5
1.1
< 0.1
< 0.1
0.3
10
-------
^^TECHNOLOGIES INC.
SAS 1047
QUANTIFICATIONS
Blank
ATI No.
90-05-033-00
Staple Volume (Vs) =
E|fSract Volume (Ve) =
COMPOUND
MIX A
liophenol
tlfophenol
lorophenol
jtjiiiacol
i&Lorophenol
LOfoguaiacol
jjmocatechol
ranillin
Loibcatechol
Lciloroguaiacol
Lotovanillin
Mgaldehyde
iHlorocatechol
staingol
Lofcsyringaldehyde
f MIX B
flBtnol
Lojpphenol
Mlorophenol
It&Lacol
.eflorophenol
ff
Vilrachlorophenol
.cILoroguaiacol
OTicatechol
.cmoroguaiacol
tlmtoenol
(fjpuaiacol
illfcatechol
*
100 mL
5 mL
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calih
Area Factor
(A) (CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05-
2.12E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
jlorophenol
DB-608
49569 9.41E-05
4.66
0.1
23
-------
INC.
m
QOMiriFICATICNS
SAS 1047
ATI No.
le Volvme (Vs)
Volume (Ve)
90-06-033-01
100 mL
5 mL
JOOMPOUND
J rax A
njaphenol
ijbphenol
ophenol
iacol
Lorophenol
oguaiaool
ocatechol
illin
acatechol
Loroguaiacol
ovanillin
jaldehyde
Lorocatechol
fringol
iosyringaldehyde
MIX B
-^
ijophenol
torophenol
paool
fLorophenol
*1
tjrachlorophenol
boroguaiacol
jpcatechol
lloroguaiacol
aphenol
Iguaiacol
ieatechol
Qiant.
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
1366
352
27412
464
1558
1695
1129
1286
2581
Calib
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
0.08
< 0.05
< 0.05
< 0.10
< 0.02
2.18
< 0.10
0.10
< 0.50
0.10
< 0.10
0.40
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
0.23
< 0.10
0.13
< 0.10
< 0.05
< 0.10
< 0.20
0.26
< 0.02
< 0.02
< 0.05
Conc/Dil
Factor
00 (3)
0.1
0.1'
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (4)
0.4
< 0.3
< 0.3
< 0.5
< 0.1
10.9
< 0.5
0.5
< 2.5
0.5
< 0.5
2.0
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
1.1
< 0.5
0.6
< 0.5
< 0.3
< 0.5
'• 1.0
1.3
< 0.1
< 0.1
< 0.3
.orophenol
DB-608
38993 9.41E-05
3.67
0.1
18
-------
TECHNOLOGIES INC.
SAS 1047
Lf65
ATT No.
90-05-033-02
Sample Volume (Vs) =
^ract Volume (Ve) =
4
IOOMPOUND
i
irocatechol
Iloroguaiacol
Sovanillin
•galdehyde
llorocatechol
iringol
Sosyringaldehyde
1 MIX B
Inol
lophenol
ilorophenol
aiacol
ilorophenol
|l
Irachlorophenol
Iloroguaiacol
locatechol
iLoroguaiacol
•phenol
iguaiacol
|catechol
Ilorophenol
100 mL
5 mL
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
14528
210
442
393
633
735
501
1536
166
41477
Calil)
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04"
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
9.41E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
1.15
< 0.10
< 0.10
< 0.50
0.03
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
0.13
< 0.10
0.07
< 0.10
< 0.05
< 0.10
< 0.20
0.16
< 0.02
< 0.02
< 0.05
3.90
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
5.8
< 0.5
< 0.5
< 2.5
0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
0.6
< 0.5
0.4
< 0.5
< 0.3
< 0.5
< 1.0
0.8
< 0.1
< 0.1
< 0.3
20
-------
INC.
SAS 1047
QUANTIFICATIONS
ATI No.
90-05-033-03
iople Volume (Vs) =
ract Volume (Ve) =
IMPOUND
MIX A
jphenol
jphenol
jphenol
Lacol
Lorophenol
xfuaiacol
xatechol
Lllin
)catechol
Loroguaiacol
jvanillin
jaldehyde
Lorocatechol
ringol
)syringaldehyde
NIX B
K>1
>phenol
.orophenol
.acol
.orophenol
•achlorophenol
.oroguaiacol
icatechol
.oroguaiacol
ihenol
(uaiacol
atechol
.orophenol
100 mL
5 mL
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
3519
11231
1100
565
1118
5111
7181
4813
6024
cn-ih
Factor
(CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
9.41E-05
Cone, in
Extract
Ce (ug/mL) (2)
0.27
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
1.35
0.31
< 0.50
0.05
< 0.10
< 0.10
< 0.05
< 0.05
0.24
< 0.05
< 0.02
< 0.05
< 0.10
0.52
< 0.10
< 0.05
< 0.10
1.22
< 0.05
< 0.02
< 0.02
0.40
0.57
Conc/Dil
Factor
00 (3)
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Sample
Cone.
Cs (ug/L) (4)
13
< 3
< 3
< 5
< 1
< 3
67
15
< 25
2
< 5
< 5
< 3
< 3
12
< 3
< 1
< 3
< 5
26
< 5
< 3
< 5
61
< 3
< 1
< 1
20
28
-------
INC.
SAS 1047
QUANTIFICATIONS
ATI No.
pie Volute (Vs)
act Volune (Ve)
90-05-033-04
100 QiL
5 mL
JOMPOUND
MIX A
)phenol
>phenol
tphenol
acol
.orophenol
iguaiacol
xatechol
Lllin
xatechol
Loroguaiacol
wanillin
jaldehyde
.orocatechol
ringol
syringaldehyde
rax B
K.1
jphenol
.orophenol
acol
Lorophenol
jguaiacol
•achlorophenol
Loroguaiacol
xratechol
.oroguaiacol
rfienol
juaiacol
atechol
Quant.
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
693
12409
1242
1325
11332
4302
735
2257
5636
2731
2502
28289
2252
Calib
Factor
(CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-O4
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/oiL) (2)
< 0.05
< 0.05
< 0.05
0.14
< 0.02
1.30
< 0.10
< 0.10
0.14
0.11
< 0.10
< 0.10
< 0.05
0.90
0.91
< 0.05
0.07
0.46
< 0.10
0.57
< 0.10
0.34
0.31
< 0.20
2.89
< 0.02
0.16
< 0.05
Conc/Dil
Factor
(X) (3)
1.0
1.0
1.0
1.0
i.o-
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Sample
Cone.
Cs (ug/L) (4)
< 3
< 3
< 3
7
< 1
65
< 5
< 5
7
6
< 5
< 5
< 3
45
46
< 3
4
23
< 5
28
< 5
17
16
< 10
144
< 1
8
< 3
.orophenol
DB-608
6373 9.41E-05
0.60
1.0
30
-------
3IES INC.
SAS 1047
CpmFTCATICNS
ties
ATI No.
90-05-033-05
fiple Volume (Vs) =
Iract Volume (Ve) =
t
pCMPOUND
f MIX A
jphenol
jphenol
jphenol
Lacol
Lorophenol
jguaiacol
jcatechol
jillin
ocatechol
loroguaiacol
Dvanillin
galdehyde
lorocatechol
ringol
Dsyringaldehyde
MIX B
nol
ophenol
Lorophenol
iacol
Lorophenol
L
rachlorophenol
Loroguaiacol
Dcatechol
Loroguaiacol
dienol
juaiaeol
atecnol
100 mL
5 mL
Quant.
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05"
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
224 1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Gone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
Oonc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Gone
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
lorophenol
DB-608
48060 9.41E-05
4.52
0.1
23
-------
UES INC.
SAS 1047
QUANTIFICATIONS
369
ATI No.
90-05-033-06
Imple Volume (Vs) =
tract Volume (Ve) =
\ COMPOUND
i MIX A
Bophenol
bophenol
bophenol
jiacol
ilorophenol
noguaiacol
rocatechol
lillin
rocatechol
iloroguaiacol
x»vanillin
igaldehyde
ilorocatechol
fringol
rosyringaldehyde
MK B
;nol
xiphenol
ilorophenol
liacol
ilorophenol
>1
:rachlorophenol
iloroguaiacol
racatechol
iloroguaiacol
iphenol
iguaiacol
icatechol
100 mL
5 mL
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
Conc/Dil
Factor
(X) (3)
0.1
0.1-
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
ilorophenol
DB-608
22386 9.41E-05
2.11
0.1
11
-------
TSLJINULJJUJ.
3IES INC.
QUAMTJICATIONS
SAS 1047
ATI No.
90-05-033-07
|le Volume (Vs) =
act Volume (Ve) =
i
IMPOUND
OX A
shenol
shenol
ihenol
icol
>rophenol
juaiacol
atechol
lin
atechol
iroguaiacol
^anillin
ildehyde
>rocatechol
ngol
ivringaldehyde
IK B
.1
henol
rophenol
col
rophenol
chlorophenol
roguaiacol
atechol
roguaiacol
enol
aiacol
techol
100 mL
= 5 mL
Peak Calib
Quant. Area Factor
Column (A) (CF) (1)
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2208 2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
10888 6.64E-05
6717 6.12E-05
- 2456 1.61E-04
347 1.43E-04
l.OOE-04
980 2.02E-04
1.68E-04
3794 1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
9550 1.02E-04
8909 5.86E-05
4765 7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
0.49
< 0.50
< 0.02
< 0.10
< 0.10
0.72
0.41
0.40
0.05
< 0.02
0.20
< 0.10
0.38
< 0.10
< 0.05
< 0.10
< 0.20
0.97
0.52
0.35
< 0.05
Conc/Dil
Factor
(X) (3)
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
Sample
Cone.
Cs (ug/L) (4)
< 0.5
< 0.5
< 0.5
< 1.0
< 0.2
< 0.5
< 1.0
4.9
< 5.0
< 0.2
< 1.0
< 1.0
7.2
4.1
4.0
0.5
< 0.2
2.0
< 1.0
3.8
< 1.0
< 0.5
1.0
< 2.0
9.7
5.2
3.5
0.5
rophenol
DB-608
22292 9.41E-05
2.10
0.2
21
-------
IES INC.
QUANTIFICATIONS
SAS 1047
ATI No.
90-05-033-08
le Volume (Vs) =
ct Volume (Ve) =
t
3MPOUND
fK A
r
henol
henol
henol
icol
irophenol
luaiacol
atechol
Jin
atechol
(roguaiacol
anillin
ildehyde
irocatechol
.ngol
yringaldehyde
[EXB
il
Jienol
irophenol
icol
rophenol
chlorophenol
roguaiacol
atechol
roguaiacol
enol
aiacol
techol
100 mL
5 mL
Quant.
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
370
559
5563
5414
795
1054
1731
700
1620
4823
1058
4926
8771
4016
Calib
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
0.03
0.44
0.52
0.18
< 0.50
0.07
< 0.10
< 0.10
< 0.05
< 0.05
0.28
< 0.05
0.07
0.33
< 0.10
0.49
< 0.10
< 0.05
0.13
0.84
0.89
0.24
< 0.02
< 0.05
Conc/Dil
Factor
(X) (3)
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
Sample
Cone.
Cs (ug/L) (4)
< 0.5
< 0.5
< 0.5
< 1.0
0.3
4.4
5.2
1.8
< 5.0
0.7
< 1.0
< 1.0
< 0.5
< 0.5
2.8
< 0.5
0.7
3.3
< 1.0
4.9
< 1.0
< 0.5
1.3
8.4
8.9
2.4
< 0.2
< 0.5
rophenol
DB-608
22366 9.41E-05
2.10
0.2
21
-------
INC.
QUWmriCATIONS
SAS 1047
ATI No.
90-05-033-09
|le Volume (Vs) =
let Volume (Ve) =
IMPOUND
nx A
r
jtoenol
ihenol
ihenol
icol
>rophenol
fuaiacol
^atechol
Llin
jatechol
)roguaiacol
fanillin
ildehyde
>rocatechol
jigol
lyringaldehyde
DK B
,1
ihenol
irophenol
icol
•rophenol
ichlorophenol
iroguaiacol
atechol
ffoguaiacol
lenol
laiacol
itechol
100 mL
5 mL
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
3504
2850
2745
3053
1557
359
576
2746
1787
1330
Calil)
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Gone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
0.28
0.27
0.61
0.28
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
0.25
< 0.05
0.04
0.12
< 0.10
0.28
< 0.10
0.22
0.16
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (4)
. < 0.3
< 0.3
< 0.3
< 0.5
< 0.1
1.4
1.4
3.0
1.4
< 0.1
< 0.5
< 0.5
< 0.3
0.3
1.3
< 0.3
0.2
0.6
< 0.5
1.4
< 0.5
1.1
0.8
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
irophenol
DB-608
36106 9.41E-05
3.40
0.1
17
-------
me.
QUANITFICATIGNS
SAS 1047
ATI No.
90-05-033-10
e Volume (Vs) =
t Volume (Ve) =
POUND
X A
jnol
aiol
jnol
jl
jphenol
iiacol
;echol
in
jtechol
^guaiacol
[lillin
^ehyde
bcatechol
gol
pingaldehyde
K B
3K>1
ophenol
Dl
jphenol
ilorophenol
>guaiacol
:echol
>guaiacol
10!
Lacol
ichol
jphenol
100 mL
= 5 mL
Peak
Quant. Area
Column (A)
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
711
268
4740
3876
2733
-
2878
2747
403
549
3088
832
1164
28856
CalUj
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
9.41E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
0.38
0.37
0.61
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
0.18
0.44
< 0.05
0.04
0.11
< 0.10
0.31
< 0.10
< 0.05
0.10
< 0.20
< 0.05
< 0.02
< 0.02
0.10
2.72
Conc/Dil
Factor
«) (3)
0.1
0.1
0.1
0.1
0.1
0.1 "
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Saople
Cone.
Cs (ug/L) (4)
< 0.3
< 0.3
•< 0.3
< 0.5
< 0.1
1.9
1.9
3.0
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
0.9
2.2
< 0.3
0.2
0.6
< 0.5
1.6
'- 0.5
0.3
0.5
1.0
0.3
< 0.1
< 0.1
0.5
14
-------
OES INC.
SAS 1047
ATI No.
90-05-037-00
lie Volime (Vs) =
fct Volune (Ve) =
t
•
IMPOUND
QXA
ihenol
ihenol
ihenol
icol
irophenol
fuaiacol
atechol
Llin
atechol
>roguaiacol
ranillin
LLdehyde
irocatechol
ngol
Yringaldehyde
OX B
1
ihenol
rophenol
col
rophenol
chlorophenol
roguaiacol
atechol
roguaiacol
enol
aiacol
techol
100 odj
5 mL
Quant.
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05 .
2.12E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Gone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
Conc/Dil
Factor
00 (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sanple
Gene.
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
(rophenol
DB-608
38397 9.41E-05
3.61
0.1
18
-------
iCHNOUDGIES INC.
SAS 1047
QUALIFICATIONS
ATI No.
90-05-037-01
^Le Volume (Vs) =
jrct Volume (Ve) =
IMPOUND
HX A
»henol
>henol
ihenol
icol
irophenol
[uaiacol
atechol
lin
atechol
(roguaiacol
anillin
ildehyde
irocatechol
ngol
yringaldehyde
IK B
1
henol
rophenol
col
irophenol
chlorophenol
'roguaiacol
atechol
roguaiacol
enol
aiacol
techol
rophenol
100 mL
5 mL
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calil)
Area Factor
(A) (CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
55048 9.41E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
'. 0.25
< 0.05
'• 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
5.18
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
'. 0.3
< 0.3
'• 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
'- 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
'. 0.3
26
-------
INC.
SAS 1047
QUANTIFICATIONS
ATI No.
90-05-037-02
pe Volune (Vs) =
act Volune (Ve) =
1
WPOUND
EX A
ihenol
ihenol
ihenol
tool
>rophenol
juaiacol
atechol
Llin
atechol
)roguaiaool
ranillin
aldehyde
jrocatechol
ingol
^ringalddiyde
OX B
>1
ftenol
>rophenol
icol
>rophenol
Lchlorophenol
>roguaiacol
atechol
iroguaiacol
lenol
laiacol
itechol
>rophenol
100 mL
- 5 mL
Peak
Quant. Area
Colum (A)
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
363
1723
1717
1908
2304
3573
1919
572
209
2827
1430
2495
71068
Calib
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-O4
5.86E-05
7.31E-05
8.26E-05
9.41E-05
Cane, in
Extract
Oe (ug/mL) (2)
< 0.05
< 0.05
< 0.05
0.29
< 0.02
< 0.05
0.17
< 0.10
0.17
0.15
0.34
< 0.10
0.13
0.04
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
0.29
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
0.08
0.18
< 0.05
6.69
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Gone.
Cs (ug/L) (4)
< 0.3
< 0.3
< , 0.3
1.4
< 0.1
< 0.3
0.8
< 0.5
0.9
0.8
1.7
< 0.5
0.6
0.2
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
1.4
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
0.4
0.9
< 0.3
33
-------
IHNDLOGIES me.
SAS 1047
QIISNTIFICATICNS
ATI No.
90-05-037-03
kle Volune CVs) •
let Volume (Ve) ••
F
IMPOUND
b A
henol
henol
henol
col
rophenol
uaiacol
atechol
lin
atechol
roguaiacol
anillin
Idehyde
rocatechol
ngol
yringaldehyde
K B
1
henol
rophenol
col
rophenol
uaiacol
dhlorophenol
roguaiacol
itechol
roguaiacol
snol
aiacol
techol
rophenol
100 mL
= 5 mL
Peak Calib
Quant. Area Factor
Column (A) (CF) (1)
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
7.62E-05
8.63E-05
536 8.97E-05
853 2.08E-04
6.40E-05
1.05E-04
16407 1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05.
2.12E-04
441 1.43E-04
l.OOE-04
2.02E-04
1.68E-04
8102 1.01E-04
8.49E-05
1.24E-04
1.24E-04
9107 1.70E-04
1.02E-04
5.86E-05
7.31E-05
6254 8.26E-05
7782 9.41E-05
Cane, in
Extract
Oe (ug/mL) (2)
< 0.05
< 0.05
< 0.05
0.18
< 0.02
< 0.05
1.97
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
0.06
< 0.02
< 0.05
< 0.10
0.82
< 0.10
< 0.05
< 0.10
1.55
< 0.05
< 0.02
< 0.02
0.52
0.73
Gonc/Dil
Factor
(X) (3)
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Sample
Cone.
Cs (ug/L) (4)
< 3
< 3
< 3
9
< 1
< 3
98
< 5
< 25
< 1
< 5
< 5
< 3
< 3
< 13
3
< 1
< 3
< 5
41
< 5
< 3
< 5
77
< 3
<. 1
( 1
26
37
-------
EHNOHXnES INC.
SAS 1047
QUAWTIFICATICNS
ATI No.
90-05-037-04
ijle Volune (Vs)
Volroe (Ve)
r
100 mL
5 mL
MPOUND
l
K A
lenol
lenol
lenol
col
rophenol
laiacol
atechol
lin
ktechol
roguaiacol
anillin
Idehyde
rocatechol
ngol
yringaldehyde
IX B
1
henol
rophenol
col
bophenol
laiacol
iilorophenol
poguaiacol
itechol
roguaiacol
snol
dacol
:echol
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
12113
2549
9909
1298
995
2698
5738
2136
24506
Calib
Factor
(CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05.
2.12E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
1.27
< 0.10
< 0.10
< 0.50
0.22
< 0.10
< 0.10
< 0.05
0.79
0.28
< 0.05
0.10
0.54
< 0.10
0.58
< 0.10
< 0.05
0.26
< 0.20
2.50
< 0.02
( 0.02
< 0.05
Gone/Oil
Factor
(X) (3)
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Sample
Gone.
Cs (ug/L) (4)
< 3
< 3
< 3
< 5
< 1
64
< 5
< 5
< 25
11
< 5
< 5
< 3
39
14
< 3
5
27
< 5
29
< 5
< 3
13
< 10
125
< l
< 1
< 3
x>phenol
DB-608
6784 9.41E-05
0.64
1.0
32
-------
TECHNOLOGIES INC.
SAS 1047
QUANTIFICATIONS
19379
ATT No.
90-05-037-05
Sample Volume (Vs) =
Extract Volume (Ve) =
COMPOUND
MIX A
ilorophenol
ilorophenol
ilorophenol
guaiacol
ichlorophenol
iloroguaiacol
ilorocatechol
vanillin
lorocatechol
ichloroguaiacol
lorovanillin
ringaldehyde
ichlorocatechol
osyringol
lorosyringaldehyde
MIX B
phenol
lorophenol
ichlorophenol
guaiacol
ichlorophenol
acol
Tetrachlorophenol
ichloroguaiacol
lorocatechol
ichloroguaiacol
orophenol
oroguaiacol
orocatecnol
100 mL
5 mL
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
6.02E-05
3577 6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
0.25
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (4)
< 0.3
1.2
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
ichlorophenol
DB-608
99712 9.41E-05
9.38
0.1
47
-------
3CHNOLOGIES INC.
SAS 1047
QUANTIFICATIONS
10
ATI Nb.
90-05-037-06
>le Volume (Vs) =
ict Volume (Ve) =
MPOJND
nx A
henol
henol
henol
icol
•rophenol
[uaiacol
atechol
lin
atechol
•roguaiacol
anillin
Idehyde
irocatechol
ngol
yringaldehyde
IX B
1
henol
rophenol
col
rophenol
chlorophenol
roguaiacol
atechol
roguaiacol
enol
aiacol
techol
100 mL
5 mL
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04"
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
o.i
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
'• 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
<• i.o
< 0.3
< 0.1
< 0.1
< 0.3
rophenol
DB-608
20999 9.41E-05
1.98
0.1
10
-------
INC.
SAS 1047
QUANTIFICATIONS
81
|le Volume (Vs)
jkct Volume (Ve)
ATI No.
90-05-037-07
100 raL
5 mL
H".
tax A
phenol
phenol
phenol
acol
arophenol
juaiacol
satechol
llin
satechol
aroguaiacol
iranillin
aldehyde
jrocatechol
Lngol
syringaldehyde
EX B
31
Aenol
>rophenol
JCOl
tfophenol
ichlorophenol
iroguaiacol
atechol
>roguaiacol
lenol
laiacol
Jtechol
Quant.
Golum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
732
1230
3960
1023
2464
8081
542
3886
Calib
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Gone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
0.20
< 0.02
< 0.05
0.38
0.23
0.23
< 0.02
0.76
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
0.11
< 0.10
0.39
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
Conc/Dil
Factor
(X) (3)
0.2
0.2
0.2 ,
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
Sanple
Cone.
Cs (ug/L) (4)
< 0.5
< 0.5
< 0.5
2.0
< 0.2
< 0.5
3.8
2.3
2.3
< 0.2
7.6
< 1.0
< 0.5
< 0.5
< 2.5
< 0.5
< 0.2
1.1
< 1.0
3.9
< 1.0
< 0.5
< 1.0
< 2.0
< 0.5
< 0.2
< 0.2
< 0.5
xophenol
DB-608
29650 9.41E-05
2.79
0.2
28
-------
JCHNOirXJIES INC.
SAS 1047
QUWCTTFICAnCNS
ATI No.
90-05-037-08
le Volume (Vs) =
ct Volume (Ve) =
MPOUND
IX A
henol
henol
tienol
col
rophenol
uaiacol
atechol
lin
atechol
roguaiacol
anillin
Idehvde
rocatechol
ngol
vringaldehyde
IXB
I
tienol
rophenol
»1
rophenol
dilorophenol
roguaiacol
Jtechol
roguaiacol
aiol
riacol
techol
100 mL
5 mL
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
1731
9985
11720
797
3538
2674
.
6339
2687
692
1134
2339
6515
7389
12747
Calib
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.2ZE-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
0.09
0.79
1.13
0.18
0.32
0.18
< 0.10
< 0.10
< 0.05
0.39
0.43
0.10
0.11
0.47
< 0.10
0.66
< 0.10
< 0.05
< 0.10
1.26
1.30
< 0.02
< 0.02
< 0.05
Conc/Dil
Factor
(X) (3)
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
Sample
Cone.
Cs (ug/L) (4)
< 0.5
< 0.5
' < 0.5
< 1.0
0.9
7.9
11.3
1.8
3.2
1.8
< 1.0
< 1.0
< 0.5
3.9
4.3
1.0
1.1
4.7
< 1.0
6.6
< 1.0
< 0.5
< 1.0
12.6
13.0
< 0.2
< 0.2
< 0.5
rophenol
DB-608
28385 9.41E-05
2.67
o.:
27
-------
IBS INC.
SAS 1047
QUANTIFICATIONS
ATI No.
90-05-037-09
lie Volume (Vs) =
fct Volume (Ve) =
i
POUND
IX A
henol
henol
henol
bol
irophenol
juaiacol
atechol
lin
Wechol
Iroguaiacol
anillin
Idehyde
rocatechol
ngol
yringaldehyde
DC B
1
henol
rophenol
col
rophenol
chlorophenol
roguaiacol
atechol
roguaiacol
enol
aiacol
techol
100 mL
5 mL
Peak
Quant. Area
Column (A)
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
17134
14661
6356
4925
8674
7300
1788
1880
8465
4221
12312
11048
Calib
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04"
6.64E-05
6.12E-05
1.61E-04
1.43E-04
l.OOE-04
2.02E-04
1.68E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
1.36
1.41
1.41
< 0.50
< 0.02
< 0.10
1.16
< 0.05
0.53
1.18
< 0.05
0.18
0.38
< 0.10
0.85
< 0.10
0.52
< 0.10
2.09
< 0.05
0.65
< 0.02
< 0.05
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) (4)
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
6.8
7.1
7.1
< 2.5
< 0.1
< 0.5
5.8
< 0.3
2.7
5.9
< 0.3
0.9
1.9
< 0.5
4.3
0.5
2.6
<• 0.5
10.5
< 0.3
3.2
0.1
0.3
rophenol
DB-608
79870 9.41E-05
7.52
0.1
38
-------
INC.
SAS 1047
IDENTIFICATIONS
ATI No. 90-05-031-00
IMPOUND
px A
i
ftienol
Sienol
Jhenol
icol
>rophenol
Fuaiacol
atechol
Llin
atechol
ffoguaiacol
'anillin
ildehyde
irocatechol
ngol
ivringaldehyde
DK B
1
henol
col
rophenol
rophenol
chlorophenol
roguaiacol
atechol
roguaiacol
enol
aiacol
techol
UD-I cojiiim u»-ouo coium
Quant. Observed Observed
Colunn Ret. Time Window Ret. Time Window
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1 '
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6,73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
rophenol
DB-608 11.88
11.59 to 12.04
10.56
10.30 to 10.75
-------
TECHNOICGIES INC.
SAS 1047
IDEOTIFICanONS
9355
ATI No. 90-05-031-01
ODMPOUND
MIX A
irophenol
•rophenol
irophenol
laiacol
ihlorophenol
iroguaiaool
jrocatechol
millin
jrocatechol
Woroguaiaool
)rovanillin
ingaldehyde
:hlorocatechol
iyringol
irosyringaldehyde
MIX B
enol
>rophenol
aiacol
ihlorophenol
'hlorophenol
nl
'trachlorophenol
'hloroguaiacol
'rocatechol
'hloroguaiacol
ophenol
oguaiacol
ocatechol
Quant.
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
UD^J. UU1U1IU1
(Swerved
Ret. Time Window
5.34
6.10
7.02
7.41
9.15
10.93 10.86
13.45
14.46 14.12
14.89
17.27 16.89
19.41
20.32 . 19.93
21.00
23.12 22.71
26.22
3.88
5.80
7.25
8.10
9.94 9.74
12.51
13.99
14.56
16.02
18.37 18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
"21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
UO-QVO CTJlLBIil
Observed
Ret. Time Window
5.26
4.84
6.30
8.03
9.02
11.86 11.54
13.79
16.72 16.49
16.47
16.72 16.46
21.60
23.82 23.22
22.43
23.82 23.22
28.16
3.41
5.22
8.09
7.18
8.85 8.70
13.09
13.50
14.13
16.33
20.04 19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
' 6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
hlorophenol
DB-608 11.82
11.59 to 12.04
10.56
10.30 to 10.75
-------
\L TECHNOLOGIES INC.
SAS 1047
IDEOTIFKATIONS
19356
ATI No. 90-05-031-02
COMPOUND
MIX A
Lorophenol
[orophenol
Lorophenol
juaiacol
ichlorophenol
[oroguaiacol
Lorocatechol
vanillin
Lorocatechol
ichloroguaiacol
lorovanillin
ingaldehyde
:Chlorocatechol
Jsyringol
lorosyringaldehyde
MIX B
ihenol
.orophenol
fuaiacol
chlorophenol
chlorophenol
icol
'etrachlorophenol
chloroguaiacol
orocatechol
chloroguaiacol
'rophenol
'roguaiacol
'rocatechol
Ouant.
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
UB-i cojuim
Observed
Ret. Time Window
5.53 5.34
6.10
7.02
7.41
9.15
10.86
13.74 13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.89 3.88
5.80
7.25
8.10
9.90 9.74
12.51
13.99
14.56
16.23 16.02
18.08
21.16
22.21
26.20 26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
uo-ouo coium
Observed
Ret. Time Window
5.53 5.26
4.84
6.30
8.03
9.02
11.54
14.14 13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.50 3.41
5.22
8.09
7.18
8.83 8.70
13.09
13.50
14.13
16.58 16.33
19.74
19.97
21.82
27.04 26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
. 8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
chlorophenol
DB-608 11.77
11.59 to 12.04
10.53
10.30 to 10.75
-------
L TECHNOLOGIES INC.
SAS 1047
IDENTIFICATIONS
19357
ATI No. 90-05-031-03
COMPOUND
MIX A
)rophenol
:>rophenol
Drophenol
jaiacol
:hlorophenol
)roguaiacol
)rocatechol
uiillin
)rocatechol
Moroguaiacol
)rovanillin
ingaldehyde
:hlorocatechol
syringol
)rosyringaldehyde
MK B
lenol
>rophenol
taiacol
Worophenol
tolorophenol
nl
itrachlorophenol
ftloroguaiacol
•rocatechol
tloroguaiacol
^phenol
'oguaiacol
watechol
Quant. Observed
Column Ret. Time
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1 10.90
DB-1
DB-1
DB-1
DB-1 17.25
DB-1
DB-1
DB-1
DB-1 23.07
DB-1 26.61
DB-608
DB-608
DB-608
DB-608 8.26
DB-608 9.92
DB-608
DB-608 14.42
DB-608 14.79
DB-608
DB-608 18.32
DB-608
DB-608 22.40
DB-608
— unri LUiuim
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
Observed
Ret. Time
11.84
16.65
23.60
28.57
7.36
8.84
13.74
14.38
20.02
22.02
-tnr-wo uuiuiii
Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
Worophenol
DB-608 11.78
11.59 to 12.04
10.53
10.30 to 10.75
-------
3tt, TECHNOLOGIES INC.
SAS 1047
IDENTIFICATIONS
19358
ATI No. 90-05-031-04
COMPOUND
rax A
ilorophenol
dorophenol
ilorophenol
iguaiacol
ichlorophenol
iloroguaiacol
ilorocatechol
wanillin
ilorocatechol
ichloroguaiacol
ilorovanillin
ringaldehyde
ichlorocatechol
tsyringol
lorosyringaldehyde
MIX B
phenol
ilorophenol
guaiacol
ichlorophenol
ichlorophenol
acol
Tetrachlorophenol
ichloroguaiacol
lorocatechol
ichloroguaiacol
orophenol
oroguaiacol
orocatechol
UB^I coium-^ UD-OUO coium
Quant. Observed Observed
Golum Ret. Time Window Ret. Time Window
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
ichlorophenol
DB-608 11.85
11.59 to 12.04
10.59
10.30 to 10.75
-------
-TKHOJDGIES INC.
SAS 1047
IDENTIFICATIONS
19359
ATI No. 90-05-031-05
OCMPOJND
MIX A
lorophenol
lorophenol
Lorophenol
guaiacol
Lchlorophenol
loroguaiacol
Lorocatechol
vanillin
Lorocatechol
Lchloroguaiacol
Lorovanillin
ringaldehyde
ichlorocatechol
asyringol
Lorosyringaldehyde
MIX B
ihenol
.orophenol
luaiacol
chlorophenol
chlorophenol
I(X>1
'etrachlorophenol
chloroguaiacol
orocatechol
chloroguaiacol
'rophenol
'roguaiacol
rocatechol
UO-L coium IJU-OUB coium
Quant. Observed Observed
Coium Ret. Time Window Ret. Time Window
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to'
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
chlorophenol
DB-608 11.83
11.59 to 12.04
10.56
10.30 to 10.75
-------
, TBCHNOUDGIES INC.
SAS 1047
IDENTIFICATIONS
19360
ATI No. 90-05-031-06
COMPOUND
KK A
iilorophenol
(ilorophenol
ilorophenol
oguaiacol
richlorophenol
hloroguaiacol
ilorocatechol
Dvanillin
ilorocatechol
Ichloroguaiacol
ilorovanillin
Tingaldehyde
ichlorocatechol
tisyruigol
ilorosvringaldehyde
MIX B
Jphenol
ilorophenol
oguaiacol
richlorophenol
"ichlorophenol
lacol
-Tet rachlorophenol
"ichloroguaiacol
ilorocatechol
ichloroguaiacol
orophenol
oroguaiacol
[orocatechol
Quant. Observed
Colum Ret. Time
DB-1
DB-1
DB-1
DB-1
DB-1 9.50
DB-1 10.97
DB-1
DB-1 14.50
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1 23.14
DB-1 26.70
DB-608
DB-608
DB-608
DB-608 8.32
DB-608 9.97
DB-608
DB-608
DB-608
DB-608
DB-608 18.42
DB-608
DB-608
DB-608
— uBr-i coium
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
. 21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
UDT-OUO coium
Observed
Ret. Time Window
5.26
4.84
6.30
8.03
9.50 9.02
11.88 11.54
13.79
16.71 16.49
16.47
16.46
21.60
23.22
22.43
23.66 23.22
28.58 28.16
3.41
5.22
8.09
7.38 7.18
8.86 8.70
13.09
13.50
14.13
16.33
20.05 19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
.8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
"ichlorophenol
DB-608 11.83
11.59 to 12.04
10.57
10.30 to 10.75
-------
TECHNOLOGIES INC.
SAS 1047
IDENTIFICATIONS
L9361
ATI No. 90-05-031-07
GCMPOUND
MIX A
>rophenol
>rophenol
>rophenol
laiacol
:hlorophenol
>roguaiacol
jrocatechol
millin
jFocatechol
Moroguaiacol
jrovanillin
;ngaldehyde
rhlorocatechol
iyringol
>rosyringaldehyde
MIX B
lenol
>rophenol
aiacol
:hlorophenol
:hlorophenol
»1
'trachlorophenol
Moroguaiacol
•rocatechol
Moroguaiacol
•ophenol
"oguaiacol
"ocatechol
Quant.
Colunn
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Observed
Ret. Time
9.53
10.97
13.82
14.49
15.28
20.37
23.15
26.82
8.32
9.98
16.32
18.39
21.42
— vo~i coium
Window
5.34
6.10
7.02
7.41
9.15
10.96
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
°^ 21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
Observed
Ret. Time
9.20
11.87
14.18
16.84
16.84
23.66
23.66
28.58
7.38
8.86
16.62
20.05
20.32
•I/DT-OUO ooium
Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
. to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
D.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
'Worophenol
DB-608 11.84
11.59 to 12.04
10.56
10.30 to 10.75
-------
ICAL TECHNOLOGIES INC.
SAS 1047
IDENnFICATIONS
. 19362
ATI No. 90-05-031-08
COMPOUND
MIX A
Morophenol
Morophenol
•hlorophenol
xxjuaiacol
tichlorophenol
:hloroguaiacol
'hlorocatechol
wanillin
'hlorocatechol
Vichloroguaiacol
hlorovanillin
yringaldehyde
tichlorocatechol
'rosyringol
h lorosyringaldehyde
MIX B
ophenol
hlorophenol
oguaiacol
richlorophenol
richlorophenol
iacol
-Tet rachlorophenol
richloroguaiacol
hlorocatechol
richloroguaiacol
lorophenol
loroguaiacol
lorocatechol
Quant.
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Observed
Ret. Time
5.53
10.85
13.71
14.38
14.93
.
23.01
26.72
5.89
8.22
9.88
14.93
16.20
18.27
26.34
UD-JL UUJ.UII1
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
Observed
Ret. Tine
5.39
11.88
14.18
16.64
16.64
23.67
28.59
5.39
7.38
8.86
14.18
16.64
20.05
27.18
I/LTTA/O UUJ.LUI1
Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
richlorophenol
DB-608
11.59 to 12.04
10.57
10.30 to 10.75
-------
TBCHNOLDGIES INC.
SAS 1047
IDENTIFICATIONS
Blank 1
ATI No. 90-05-033-00
COMPOUND
rax A
dorophenol
dorophenol
dorophenol
iguaiacol
ichlorophenol
iloroguaiaool
ilorocatechol
vanillin
lorocatechol
ichloroguaiaool
lorovanillin
ringaldehyde
ichlorocatechol
osyrlngol
lorosyruigaldehyde
UK B
phenol
lorophenol
guaiacol
ichlorophenol
ichlorophenol
acol
retrachlorophenol
ichloroguaiaool
lorocatechol
ichloroguaiacol
Mophenol
oroguaiaool
ttocatechol
• "-L/U' 1 UUlCliai - UD-DUO UJ1UUII
Quant. Observed Observed
Colum Ret. Time Window Ret. Time Window
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
5.26
4.84
6.30
8.03
9.02
11.54
D.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
D.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24:01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
ichlorophenol
DB-608 11.84
11.59 to 12.04
10.57
10.3C to 10.75
-------
TECHNDLDGIES INC.
SAS 1047
IDENTIFICATIONS
19364
ATI Mo. 90-05-033-01
COMPOUND
MH A
iilorophenol
hlorophenol
hlorophenol
oguaiacol
•richlorophenol
hloroguaiacol
hlorocatechol
wanillin
hlorocatechol
ttchloroguaiacol
tilorovanillin
yringaldehyde
tichlorocatechol
rosyringol
hlorosyringaldehyde
MIX B
ophenol
'hlorophenol
oguaiacol
'richlorophenol
ftchlorophenol
iacol
"Tetracnlorophenol
tichloroguaiacol
hlorocatechol
tichloroguaiacol
lorophenol
loroguaiacol
lorocatechol
Quant. Observed
Colum Ret. Time
DB-1 5.48
DB-1 6.19
DB-1
DB-1
DB-1
DB-1 10.85
DB-1
DB-1 14.38
DB-1
DB-1 17.20
DB-1
DB-1 20.25
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608 8.22
DB-608 9.89
DB-608
DB-608
DB-608
DB-608
DB-608 18.29
DB-608
DB-608
DB-608
UttrL COllim
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
uijr-ouo coium
Observed
Ret. Time Window
5.42 5.26
5.10 4.84
6.30
8.03
9.02
11.88 11.54
13.79
16.76 16.49
16.47
16.76 16.46
21.60
23.66 23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.38 7.18
8.87 8.70
13.09
13.50
14.13
16.33
20.05 19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
•8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
richlorophenol
DB-608 11.73
11.59 to 12.04
10.57
10.30 to 10.75
-------
TECHNOLOGIES INC.
SAS 1047
iDEwnnavnoNS
,. 19365
ATI No. 90-05-033-02
COMPOUND
MIX A
dilorophenol
dilorophenol
±lorophenol
roguaiacol
Irichlorophenol
Moroguaiacol
Alorocatechol
rovanillin
iilorocatechol
Pridiloroguaiacol
ilorovanillin
syringaldehyde
Mchlorocatechol
irosyringol
Morosyringaldehyde
MIX B
^phenol
Morophenol
'oguaiacol
ttchlorophenol
ttchlorophenol
iacol
-Tetrachlorophenol
tichloroguaiacol
hlorocatechol
ttchloroguaiacol
lorophenol
loroguaiaool
lorocatechol
ttchlorophenol
Quant. Observed
Column Ret. Time
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1 10.84
DB-1
DB-1 14.38
DB-1
DB-1 17.18
DB-1
DB-1
DB-1
DB-1 23.01
DB-1
DB-608
DB-608
DB-608
DB-608 8.22
DB-608 9.87
DB-608
DB-608
DB-608
DB-608 16.38
DB-608 18.27
DB-608
DB-608
DB-608 26.18
DB-608 11.72
UO~i UJJ-lIIHl
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
11.59
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
12.04
1JD-OUO UU1UII1
Observed
Ret. Time Window
5.26
4.84
6.30
8.03
9.02
11.88 11.54
13.79
16.72 16.49
16.47
16.72 16.46
21.60
23.22
22.43
23.85 23.22
28.16
3.41
5.22
8.09
7.39 7.18
8.87 8.70
13.09
13.50
14.13
16.72 16.33
20.06 19.74
19.97
21.82
22.04 26.73
10.57 10.30
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
10.75
-------
flCAL TECHNOLOGIES INC.
SAS 1047
10. 19366
ATT No. 90-05-033-03
OMPOUND
MIX A
Morophenol
Morophenol
Morophenol
xxjuaiacol
tichlorophenol
Moroguaiacol
hlorocatechol
•ovanijlin
hlorocatediol
tichloroguaiacol
hlorovanillin
yringaldehyde
tichlorocatechol
rosyringol
hlorosyringaldehyde
MIX B
ophenol
hlorophenol
oguaiacol
Hchlorophenol
ttchlorophenol
iacol
"'fetrachlorophenol
ttchloroguaiacol
hlorocatechol
rtchloroguaiacol
lorophenol
loroguaiacol
lorocatechol
Quant, Observed
Colum Ret. Time
DB-1 5.55
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1 13.76
DB-1 14.43
DB-1
DB-1 17.25
DB-1
DB-1
DB-1
DB-1
DB-1 26.77
DB-608
DB-608
DB-608
DB-608
DB-608 9.91
DB-608
DB-608
DB-608
DB-608 16.25
DB-608
DB-608
DB-608
DB-608 26.22
— U&-L ccuum
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
-21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
UD-WO ooium
Observed
Ret. Time Window
5.53 5.26
4.84
6.30
8.03
9.02
11.54
14.14 D.79
16.84 16.49
16.47
16.84 16.46
21.60
23.22
22.43
23.22
28.57 28.16
3.41
5.22
8.09
7.18
8.83 8.70
13.09
13.50
14.13
16.59 16.33
19.74
19.97
21.82
27.04 26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
' 6.73
8.48
9.53
12.D
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
fichlorophenol
DB-608 11.78
11.59 to 12.04
10.53
10.30 to 10.75
-------
TECHNOLOGIES INC.
SAS 1047
. 19367
ATI No. 90-05-033-04
COMPOUND
MIX A
chlorophenol
dilorophenol
Morophenol
roguaiacol
rrichlorophenol
±loroguaiaool
:hlorocatechol
tovanillin
Morocatechol
fcidiloroguaiacol
ihlorovanillin
syringaldehyde
IWchlorocatechol
>rosyringol
iilorosyringaldehyde
MIX B
^phenol
ttorophenol
xjguaiacol
Wchlorophenol
Wchlorophenol
Woroguaiacol
'-Tetrachlorophenol
ttchloroguaiacol
hlorocatechol
ttchloroguaiacol
iorophenol
ioroguaiacol
iorocatechol
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Observed
Ret. Time
7.62
10.90
14.97
17.25
.
23.07
26.62
5.92
8.26
9.93
14.43
14.80
18.33
22.40
-unrL coium
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
LttJ-wo column
Observed
Ret. Time Window
8.26
11.85
16.67
23.62
28.57
5.37
7.36
8.84
13.75
14.38
20.02
22.02
5.26
4.84
6.30
8.03
9.02
11.54
• 13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
- 6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
ttchlorophenol
DB-608 11.79
11.59 to 12.04
10.54
10.30 to 10.75
-------
1CAL TECHNOLOGIES DC.
SAS 1047
IDENTIFICATIONS
, 19368
ATI No. 90-05-033-05
ODMPOUND
MIX A
dilorophenol
chlorophenol
chloropbenol
roguaiacol
rrichlorophenol
diloroguaiacxil
chlorocatechol
rovanillin
chlorocatechol
rrichloroguaiacol
dilorovanillin
syringaldehyde
Ittchlorocatechol
JtDsyringol
Alorosyringaldehyde
MIXB
rophenol
ftlorophenol
Doguaiaool
Tichlorophenol
Ittchlorophenol
aaool
'-TetracMorophenol
Wchloroguaiaool
*lorocatechol
frichloroguaiacol
florophenol
iloroguaiaool
florocatechol
Quant. Observed
Colum Ret. Time
DB-1
IB-1
DB-i
DB-I
DB-I
DB-l
DB-I
DB-l
DB-I
DB-I
DB-l
DB-l
DB-l
DB-l
DB-l
DB-608
DB-608
DB-608
DB-608
DB-608 9.88
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
— ittj-i ccuum
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
UD-WB coium
Observed
Ret. Time Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.93 8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
36.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
'Hchlorophenol
DB-608 11.73
11.59 to 12.04
10.61
10.30 to 10.75
-------
TECHNOLDGIES INC.
SAS 1047
IDENTIFICATIONS
19369
ATI No. 90-05-033-06
COMPOUND
HEX A
:hlorophenol
dilorophenol
±lorophenol
roguaiacol
rrichlorophenol
diloroguaiacol
iilorocatechol
ravanillin
Morocatechol
rrichloroguaiacol
ilorovanillin
syringaldehyde
rrichlorocatechol
irosyringol
:hlorosyrlngaldehyde
MIX B
rophenol
-hlorophenol
sguaiacol
Wchlorophenol
Wchlorophenol
Jiacol
>-Tet rachlorophenol
frichloroguaiacol
;hlorocatechol
Wchloroguaiacol
dorophenol
tioroguaiacol
rtorocatechol
VO-i CO1UHK1 UB-OUO CO1WI1
Quant. Observed Observed
Goliann Ret. Time Window Ret. Time Window
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
oo 71;
L*j-l * 1 -J
26.65
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
,to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
Mchlorophenol
DB-608 11.72
11.59 to 12.04
10.57
10.30 to 10.75
-------
TECHNOLOGIES INC.
SAS 1047
n)ENTIFICATIONS
,. 19370
ATI No. 90-05-033-07
COMPOUND
MIX A
chlorophenol
dilorophenol
dilorophenol
roguaiacol
rrichlorophenol
±loroguaiacol
Morocatechol
novanillin
Morocatechol
Prichloroguaiacol
iilorovanillin
syringaldehyde
Frichlorocatechol
)rosyringol
:hlorosyringaldehyde
MIX B
tiphenol
:hlorophenol
tiguaiacol
nchlorophenol
Vichlorophenol
dacol
>-Tet rachlorophenol
"richloroguaiacol
hlorocatechol
tichloroguaiacol
ilorophenol
iloroguaiacol
ilorocatechol
Quant . Observed
Colum Ret. Time
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1 14.36
DB-1
DB-1
DB-1
DB-1
DB-1 21.27
DB-1 22.99
DB-1 26.55
DB-608 3.89
DB-608
DB-608 7.38
DB-608
DB-608 9.86
DB-608
DB-608
DB-608
DB-608
DB-608 18.26
DB-608 21.27
DB-608 22.28
DB-608
LHJ-l CU1UIII11
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to.
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
UD-OUO coium
Observed
Ret. Time Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.69 16.49
16.47
16.46
21.60
23.22
22.87 22.43
23.67 23.22
28.56 28.16
3.42 3.41
C. OT
J f Ui*
7.38 8.09
7.18
8.88 8.70
13.09
13.50
14.13
16.33
20.07 19.74
20.32 19.97
22.05 21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
Wchlorophenol
DB-608 11.72
11.59 to 12.04
10.57
10.30 to i:.75
-------
TBCHNOUDGIES INC.
SAS 1047
IDEOTIFICATICNS
19371
ATI No. 90-05-033-08
COMPOUND
rax A
:hlorophenol
rhlorophenol
iilorophenol
roguaiacol
Prichlorophenol
:hloroguaiacol
Morocatechol
rovanillin
rhlorocatechol
rrichloroguaiacol
rhlorovanillin
jyringaldehyde
ftlchlorocatechol
)rosyringol
tolorosyringaldehyde
POX B
^phenol
:hlorophenol
x)guaiacol
"richlorophenol
Wchlorophenol
uacol
'-Tetrachlorophenol
"fichloroguaiacol
Morocatechol
ttchloroguaiacol
iorophenol
'loroguaiacol
ilorocatechol
Ouant.
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Observed
Ret. Time
6.38
9.43
10.85
13.71
14.38
17.18
26.57
5.92
8.22
9.87
14.93
16.18
18.26
21.27
— UO-L coium
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
Observed
Ret. Time
5.09
9.20
11.89
14.19
16.84
16.84
28.60
5.41
7.39
8.88
14.43
16.64
20.06
20.33
-UB^-OUO coiunm
Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
Wchlorophenol
DB-608 11.73
11.59 to 12.04
10.57
10.30 to 10.75
-------
1(JL TECHNOLOGIES INC.
SAS 1047
LUtwriMCATICNS
i. 19372
ATI No. 90-05-033-09
OCMPOUND
MIX A
chlorophenol
chlorophenol
dilorophenol
roguaiacol
Tridilorophenol
chloroguaiacx)!
dilorocatediol
rovanillin
chlorocatechol
Trichloroguaiaool
chlorovanillin
syringaldehyde
rrichlorocatechol
orosyringol
*lorosyringaldehyde
MIX B
rophenol
ftlorophenol
roguaiacol
Wchlorophenol
Wchlorophenol
Jiacol
»-Tetrachlorophenol
Wchloroguaiacol
Worocatechol
tochloroguaiacol
tiorophenol
tioroguaiacol
tiorocatechol
Quant. Observed
Colum Ret. Tijne
DB-1
DB-1
DB-1
DB-i
DB-1
DB-1 10.84
DB-1 13.71
DB-1 14.36
DB-1 14.93
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1 26.54
DB-608
DB-608 5.90
DB-608
DB-608 8.20
DB-608 9.87
DB-608
DB-608 14.36
DB-608 14.93
DB-608
DB-608
DB-608
DB-608
DB-608
— iffl-i column
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
UBr-oiRJ COllim
Observed
Ret. Time Window
5.26
4.84
6.30
8.03
9.02
11.89 11.54
14.19 13.79
16.67 16.49
16.67 16.47
16.46
21.60
23.22
22.43
23.22
28.61 28.16
3.41
5.39 5.22
8.09
7.38 7.18
8.88 8.70
13.09
13.79 13.50
14.40 14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
D.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
fiichlorophenol
DB-608 11.72
11.59 to 12.04
10.58
10.30 to 10.75
-------
TECHNOLOGIES INC.
SAS 1047
IDENnFICATIONS
,. 19373
ATI No. 90-05-033-10
COMPOUND
MIX A
ichlorophenol
ichlorophenol
.chlorophenol
iroguaiacol
Trichlorophenol
.chloroguaiacol
chlorocatechol
irovanillin
chlorocatechol
Trichloroguaiacol
chlorovanillin
syringaldehyde
Trichlorocatechol
orosyringol
chlorosyringaldehyde
MIX B
rophenol
chlorophenol
roguaiacol
Wchlorophenol
Mchlorophenol
aiacol
6-Tetrachlorophenol
M. chloroguaiacol
Alorocatechol
M chloroguaiacol
ilorophenol
iloroguaiacol
ilorocatechol
Quant.
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Observed
Ret. Time
5.53
6.42
10.86
13.72
14.38
fc
23.
26.
5.
8.
9.
14.
26.
02
57
91
22
88
93
34
— UD-I coimn
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
Observed
Ret. Time
5
5
11
14
16
23
28
5
7
8
14
.38
.08
.88
.20
.68
.69
.61
.38
.39
.88
.41
27.19
-UB-OUB column
Window
5.26
4.84
6.30
8".03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
Mchlorophenol
DB-608 11.74
11.59 to 12.04
10.58
10.30 to 10.75
-------
TECHNOLOGIES INC.
SAS 1047
IDENTIFICATIONS
to. Blank 1
ATI No. 90-05-037-00
OCMPOUND
MIX A.
lichlorophenol
lichlorophenol
lichlorophenol
oroguaiacx)!
-Triciilorophenol
ichloroguaiacol
ichlorocatechol
orovanillin
idilorocatechol
-Trichloroguaiacol
ichlorovanillin
osyringaldehyde
-Trichlorocatechol
lorosyringol
ichlorosyringaldehyde
MIX B
orophenol
ichlorophenol
orcguaiacol
•Trichlorophenol
•Trichlorophenol
uaiacol
• 6-Tet rachlorophenol
•Trichloroguaiacol
ichlorocatechol
•Trichloroguaiacol
^hlorophenol
^oroguaiacol
ilorocatechol
U&-L column ua-wo column
Quant, Observed Observed
Colurai Ret. Time Window Ret. Time Window
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1 .
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20,17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
Trichlorophenol
DB-608 11.82
11.59 to 12.04
10.56
10.30 to 10.75
-------
TECHNOLOGIES INC.
SAS 1047
UDENTIFICATICNS
,. 19375
ATT No. 90-05-037-01
COMPOUND
MIX A
chlorophenol
chlorophenol
chlorophenol
iroguaiacol
Trichlorophenol
chloroguaiacol
chlorocatechol
rovanillin
chlorocatechol
Trichloroguaiacol
chlorovanillin
syringaldehyde
Trichlorocatechol
orosyringol
chlorosyringaldehyde
MIX B
tophenol
chlorophenol
roguaiacol
Wchlorophenol
frichlorophenol
iiacol
Htetracnlorophenol
Mchloroguaiacol
Alorocatechol
tochloroguaiacol
tiorophenol
tioroguaiacol
tiorocatechol
UO-L coiunn IJB-OUB coium
Quant. Observed Observed
Colum Ret. Time Window Ret. Time Window
DB-1
DB-1
IB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1 .
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
" 20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
frichlorophenol
DB-608 11.72
11.59 to 12.04
10.59
10.30 to 10.75
-------
TECHNOLOGIES INC.
SAS 1047
IDENTIFICATIONS
i. 19376
ATI No. 90-05-037-02
COMPOUND
MIX A
ichlorophenol
ichlorophenol
ichlorophenol
jroguaiacol
•Trichlorophenol
ichloroguaiacol
ichlorocatechol
Jiwanillin
ichlorocatechol
•Trichloroguaiacol
.chlorovanillin
isyringaldehyde
•Trichlorocatechol
iorosyringol
chlorosyringaldehyde
MIX B
irophenol
chlorophenol
itoguaiacol
Trichlorophenol
Mchlorophenol
laiacol
Hfetrachlorophenol
Trichloroguaiacol
chlorocatecnol
Trichloroguaiacol
fclorophenol
Woroguaiacol
hlorocatecnol
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Observed
Ret. Time
6.22
7.41
13.72
14.95
17.22
19.73
21.32
23.02
8.21
9.88
21.32
22.30
UD-l UUJ.UHII
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
Observed
Ret. Time
5.18
8.40
13.%
16.%
16.%
21.95
22.72
23.65
7.26
9.01
20.26
21.95
•tttJTWO UJJ.U1I1
Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
'Mchlorophenol
DB-608 11.74
11.59 to 12.04
10.72
10.30 to 10.75
-------
TECHNOLOGIES INC.
SAS 1047
IDENTIFICATIONS
j. 19377
ATI No. 90-06-037-03
OCMPOUND
MIX A
Lchlorophenol
ichlorophenol
Lchlorophenol
sroguaiacol
-Trichlorophenol
idiloroguaiacol
Lchlorocatechol
)rovanillin
Lchlorocatechol
•Trichloroguaiacol
Lchlorovanillin
Byringaldehyde
-Mchlorocatechol
lorosyringol
u^lorosyringaldehyde
MIX B
>rophenol
Khlorophenol
>roguaiacol
•Trichlorophenol
;Trichlorophenol
'chloroguaiacol
6-Tetrachlorophenol
•Trichloroguaiacol
'*lorocatechol
•Mchloroguaiacol
Worophenol
Aloroguaiaool
^orocatechol
Quant. Observed
Colum Ret. Time
DB-i
DB-I
DB-1 7.41
DB-1 7.62
DB-I
DB-1
DB-1 D.79
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608 3.91
DB-608
DB-«08
DB-608
DB-608 9.93
DB-608
DB-608
DB-608
DB-608 16.27
DB-608
DB-608
DB-608
DB-608 36.26
— ittj-i coium
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to-
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
UD-OUO comn
Observed
Ret. Time tfiodov
5.26
4.84
6.52 6.30
8.28 8.03
9.02
11.54
14.16 13.79
16.49
16.47
16.46
21.60
23.22
•n «"3
— ~--S-J
23.22
28.lt
3.51 3.41
5.21
8.09
7. IS
8.85 8.7<:
13.09
13.50
" * " ~
16.61 lf.35
* * ~! f
^.*, '"5
19.57
21-S:
27,07 at~:-
to
to
to
to
to
to
to
to
to
to
to
to
to
to
"-f-i
ID
tc
to
k^_
L-C-
-^
--
--
r_-
r--.
to
i.4.1
tc
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24-01
2S.99
" -.—
5 .-5?
: r-
*- li_
r.~~
13-55
13.95
- r ~~
15. SI
2E'.2t
•**• ^"
11. 3t
r.x
DB-608 11.81
11.59 to 12.04
10.54
-------
TECHNOLOGIES INC.
SAS 1047
IDENTIFICATIONS
No. 19378
ATT No. 90-05-037-04
COMPOUND
I
| MIX A
I
Dichlorophenol
Dichlorophenol
jHchlorophenol
loroguaiacol
[-Trichlorophenol
ttchloroguaiacol
Jidilorocatechol
[orovanillin
fccftlorocatechol
i-Trichloroguaiacol
ttchlorovanillin
posyringaldehyde
i-Trichlorocatechol
ilotosyringol
Kchlorosyringaldehyde
MIX B
orophenol
Hdilorophenol
t-Mchlorophenol
OFoguaiacol
hTrichlorophenol
Kchloroguaiacol
• 6-Tetrachlorophenol
^Trichloroguaiacol
icftlorocatechol
"Trichloroguaiacol
dilorophenol
^loroguaiacol
*lorocatechol
Quant. Observed
Colunm Ret. Time
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1 10.93
DB-1
DB-1
DB-1
DB-1 17.28
DB-1
DB-1
DB-1
DB-1 ' 23.13
DB-1 26.65
DB-608
DB-608 5.93
DB-608 8.28
DB-608
DB-608 9.95
DB-608
DB-608
DB-608 14.83
DB-608
DB-608 18.37
DB-608
DB-608
DB-608
— uo-i coium
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
UBr-OUB CO1UH1
Observed
Ret. Time Window
5.26
4.84
6.30
8.03
9.02
11.86 11.54
13.79
16.49
16.47
16.68 16.46
21.60
23.22
22.43
23.64 23.22
28.57 28.16
3.41
5.39 5.22
7.37 8.09
7.18
8.85 8.70
13.09
13.50
14.41 14.13
16.33
20.03 19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
•Trichlorophenol
DB-608 11.82
11.59 to 12.04
10.54
10.30 to 10.75
-------
flfflL TECHNOLOGIES INC.
SflS 1047
IDEWITFICATICNS
,. 19379
ATI No. 90-05-037-05
COMPOUND
MIX A
chlorophenol
ehlorophenol
chlorophenol
iraguaiacx»l
Trichlorophenol
chloroguaiac»l
chlorocatechol
irovanillin
chlorocatechol
Trichloroguaiacol
chlorovanillin
eyringaldehyde
Trichlorocatechol
orosyringol
chlorosyringaldehyde
MKB
rophenol
chlorophenol
roguaiacol
ftichlorophenol
Trichlorophenol
aiacol
^Tetrachlorophenol
Mchloroguaiacol
*lorocatechol
Trichloroguaiacol
tiorophenol
tioroguaiacol
foorocatechol
Quant. Observed
Golum Ret. Time
DB-1
DB-1 6.25
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
VETL UUJ.UUB1
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
umjvro UJ.LIUII
Observed
Ret. Time Window
5.26
4.98 4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
Tfichlorophenol
DB-608 11.79
11.59 to 12.04
10.73
10.30 to 10.75
-------
1CAL TECHNOLOGIES INC.
SAS 1047
1. 19380
ATI No. 90-05-037-06
•
COMPOUND
MIX A
ichlorophenol
ichlorophenol
ichlorophenol
Hxxfuaiacol
Trichlorophenol
:chloroguaiacol
Lchlorocatechol
jrovanillin
ichlorocatechol
-Trichloroguaiacx)!
Lchlorovanillin
Kyringaldehyde
•Trichlorocatechol
orosyringol
ichlorosyringaldehyde
MIX B
>rophenol
ichlorophenol
Jroguaiaool
•Trichlorophenol
•Trichlorophenol
aiacol
•6-Tetrachlorophenol
;Trichloroguaiac»l
Khlorocatechol
•Trichloroguaiacwl
*lorophenol
•frloroguaiacol
sflorocatechol
im-i CUJ.UDH IHJ-OUO ixuiuii
Quant. Observed Observed
Colurn Ret. Time Window Ret. Tine Window
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1 .
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
.20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
~Ttidaorophenol
DB-608 11.73
11.59 to 12.04
10.65
10.30 to 10.75
-------
TECHNOLOGIES INC.
SAS 1047
IDENTIFICATIONS
b. 19381
ATI No. 90-05-037-07
COMPOUND
MIX A
ichlorophenol
ichlorophenol
Dichlorophenol
loroguaiacol
6-Trichlorophenol
Dichlonoguaiacol
lichlorocatechol
orovanillin
ichlorocatechol
i-Trichloroguaiacol
ichlorovanillin
osyringaldehyde
-Mchlorocatechol
ilorosyringol
ichlorosyringaldehyde
MIX B
lorophenol
Kichlorophenol
|°roguaiacol
^ichlorophenol
hTTichlorophenol
feacol
S-Tet rachlorophenol
^Mchloroguaiaool
^hlorocatechol
hTTichloroguaiacol
lorophenol
*loroguaiacol
^lorocatechol
Quant. Observed
Column Ret. Time
DB-1 5.51
DB-1
DB-1
DB-1 7.53
DB-1
DB-1
DB-1 13.69
DB-1 14.36
DB-1 15.16
DB-1
DB-1 19.70
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608 8.20
DB-608 9.87
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
— ua-L coiunn
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
uij-ouB coium
Observed
Ret. Tine Window
5.59 5.26
4.84
6.30
8.33 8.03
9.02
11.54
11.95 13.79
14.26 16.49
16.74 16.47
16.46
21.83 21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.43 7.18
8.93 8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
'^ichlorophenol
DB-608 11.73
11.59 to 12.04
10.63
10.30 to 10.75
-------
TECHNOLOGIES INC.
SAS 1047
IDENTIFICATIONS
b. 19382
ATI No. 90-05-037-08
COMPOUND
MIX A
[flichlorophenol
rDichlorophenol
-Dichlorophenol
toroguaiacol
Jb-Mchlorophenol
iichloroguaiacol
tichlorocatechol
lorovanillin
tichlorocatechol
,5-Trichloroguaiacol
•Dichlorovanillin
irosyringaldehyde
5-Trichlorocatechol
iilorosyringol
•fichlorosyringaldehyde
MIX B
lorophenol
fiichlorophenol
loroguaiacol
6 Trichlorophenol
5 MchloEOBhenol
Guaiacol ' "
4 6-Tetraehlorophenol
^Trichloroguaiac»l
Kichloroeatechol
{~Tnchloroguaiacol
achlorophenol
8chloroguaiacol
a*lorocatechol
Quant. Observed
Colum Ret. Time
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1 *
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
9.42
10.87
13.72
14.38
15.17
17.18
23.02
26.73
3.92
5.90
8.22
9.88
16.21
21.30
UOri CO1UUI1
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
Observed
Ret. Time
9.25
11.94
14.25
16.94
16.94
16.94
23.74
28.67
3.52
5.42
7.42
8.91
16.70
20.14
UD-OUO coium
Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.D
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
ichlorophenol
DB-608 11.75
11.59 to 12.04
10.63
10.30 to 10.75
-------
TECHNOLOGIES INC.
SAS 1047
HKNTIFICATIONS
o. 19383
ATI No. 90-05-037-09
COMPOUND
MIX A
lichlorophenol
lichlorophenol
lichlorophenol
oroguaiacol
-Trichlorophenol
.diloroguaiacol
ichlorocatechol
orovanillin
ichlorocatechol
-Trichloroguaiacol
lichlorovanillin
osyringaldehyde
-Trichlorocatechol
ilorosyringol
lichlorosyringaldehyde
MIX B
orophenol
ichlorophenol
oioguaiacol
-Trichlorophenol
-Trichlorophenol
uaiacol
' 6-Tet rachlorophenol
-Trichloroguaiacol
ichlorocatechol
"Trichloroguaiacol
chlorophenol
*loroguaiacol
*lorocatechol
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Observed
Ret. Time
10.87
13.73
14.38
20.26
23.03
26.58
5.92
8.22
9.89
14.38
16.22
21.31
— ua-L comm
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
7.25
8.10
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
7.57
8.43
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
Observed
Ret. Time
11.93
14.25
16.72
23.73
23.73
28.67
5.42
7.42
8.91
13.65
16.72
20.14
-OB-DUO coium
Window
5.26
.4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
8.09
7.18
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
8.41
7.52
9.07
13.53
13.%
14.61
16.82
20.26
20.53
22.36
27.30
•Trichlorophenol
DB-608 11.76
11.59 to 12.04
10.63
10.30 to 10.75
-------
Technologies, Inc.
e 5 Initial Precision and Recovery
OCMPOUND
MIX A
Dichlorophenol
Dichlorophenol
Dichlorophenol
loroguaiacol
Hrichlorophenol
Dichloroguaiacol
6-Trichlorophenol
Dichlorocatechol
ilorovaniLLin
Dichlorocatechol
5-Trichloroguaiacol
Dichlorovanillin
rosyringaldehyde
5-Trichlorocatechol
hlorosyringol
Dichlorosyringaldehyde
MIX B
Lorophenol
)ichlorophenol
Loroguaiacol
i-Trichlorophenol
>-Mchlorophenol
Httdilorophenol
1, 6-Tetrachlorophenol
^Trichloroguaiacol
ttchloroguaiacol
ttchlorocatechol
HtLchloroguaiacol
'chlorophenol
ichloroguaiacol
'chlorocatechol
Quant.
Column -
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-l
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
Cone.
Expected
100
100
100
200
40
100
100
100
200
200
40
200
200
100
100
500
100
40
200
100
100
100
100
100
100
200
40
20
40
100
Cone.
Found
Rep 1
Concen
92
97
98
193
40
106
102
100
1%
200
38
1%
201
100
98
486
92
38
185
99
95
92
94
97
104
187
39
19
37
97
Cone.
Found
Rep 2
tration in
94
110
109
215
44
115
111
112
220
223
44
236
238
109
108
581
87
36
184
97
95
93
100
99
108
195
38
20
38
104
Cone.
Found
Rep 3
«._ /T
ug/Lf
110
105
108
218
45
112
106
107
207
218
43
211
209
104
107
502
%
42
204
105
106
105
104
106
116
199
41
20
41
103
Cone.
Found Mean
Rep 4 Cone.
134
115
117
237
48
122
118
116
232
228
46
223
226
113
114
541
98
36
181
98
103
97
97
99
110
192
37
21
39
102
107
107
108
216
44
113
109
109
214
217
43
216
218
107
107
528
93
38
188
99
100
97
99
100
110
193
39
20
39
102
% RSD
15.5
6.4
6.3
7.2
5.9
5.1
5.5
5.5
6.3
4.9
6.9
6.7
6.6
4.6
5.4
7.0
4.6
6.2
4.9
3.1
4.7
5.1
3.7
3.1
3.9
2.4
3.6
2.8
3.6
2.7
-------
flCRL TECHNOLOGIES INC.
6 On-going Precision and Recovery
Sample: 90-05-031-OPR
COMPOUND
r~~
ichlorophenol
idilorophenol
idilorophenol
Hoguaiacol
-Trichlorophenol
ichloroguaiacol
idilorocatechol
idilorocatechol
-Mchloroguaiacol
-Tridilorocatechol
lorosyringol
Quanti-
titation
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
Spike
Cone.
ug/L
25
25
25
50
13
25
25
50
13
25
25
Cone.
Found
ug/L
24
24
25
47
10
25
25
49
10
24
24
Percent
Recovery
95
96
99
95
79
99
99
97
82
98
95
SAS 1047
Sample: 90-05-033-OPR
Cone.
Found
ug/L
30
31
31
63
13
31
32
61
13
32
30
Percent
Recovery
120
126
126
126
106
125
129
122
107
128
119
CCMPOUND
Sample: 90-05-037-OPR
Quanti- Spike Cone.
titation Cone. Found Percent
Colum ug/L ug/L Recovery
ichlorophenol
chlorophenol
chlorophenol
Toguaiacol
Trichlorophenol
chloroguaiacol
chlorocatechol
chlorocatechol
Trichloroguaiacol
Trichlorocatechol
orosyringol
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
25
25
25
50
13
25
25
50
13
25
25
24
24
25
47
10
25
25
49
10
24
24
95
96
99
95
79
99
99
97
82
98
95
-------
TBCHNDLDGIES INC.
SAS 1047
7 Surrogate Recoveries
Concentration Concentration
3,4,5-WiJiloror, 3,4,5-Mchloro- >^
pie pfe^ Jj^c pfeS?- W*3
) Chemex ID Added (ug/Lj Found (ug/L)
ik
155
156
157
158
159
160
61
162
k
64
65
66
67
68
69
70
71
72
73
k
75
76
77
78
79
JO
il
!2
13
90-05-031-00
90-05-031-01
90-05-^)31-02
90-05-031-03
90-05-031-04
90-05-031-05
90-05-031-06
90-05-031-07
90-05-031-08
90-05-033-00
90-05-033-01
90-05-033-02
90-05-033-03
90-05-033-04
90-05-033-05
90-05-033-06
90-05-033-07
90-05-033-08
90-05-033-09
90-05-033-10
90-05-037-00
90-05-037-01
90-05-037-02
90-05-037-03
90-05-037-04
90-05-037-05
90-05-037-06
90-05-037-07
90-05-037-08
90-05-037-09
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25'
25
25
25
25
25
25
25
25
21
14
22
23
16
16
13
11
10
23
18
20
28
30
23
11
21
21
17
14
18
26
33
37
32
47
10
28
28
38
Percent
Recovery
83
55
90
91
62
63
51
44
39
93
73
78
113
120
90
42
84
84
68
54
72
104
134
146
128'
188
40
112
112
150
c MATSPK Blank
4.5
90
-------
ICAL TECHNOLOGIES INC.
SAS 1047
3 Matrix Spike Recoveries
COMPOUND
chlorophenol
chlorophenol
chlorophenol
roguaiacol
rrichlorophenol
chloroguaiacol
chlorocatediol
rovanillin
dilorocatechol
Iridiloroguaiacol
dilorovanillin
syringaldehyde
rrichlorocatechol
Hosyringol
dilorosyringaldehyde
COMPOUND
iilorophenol
iilorophenol
iilorophenol
roguaiacol
Prichlorophenol
:hloroguaiacol
tlorocatechol
wanillin
Worocatechol
Wchloroguaiacol
ftlorovanillin
ivringaldehyde
Wchlorocatechol
'rosyringol
Worosyringaldehyde
Quanti-
titation
Colum
DB-1
DB-1
D&-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
Quanti-
titation
Colum
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
Spike
Gone.
ug/L
50
50
50
100
20
50
50
100
100
50
100
100
50
50
250
Spike
Cone.
ug/L
50
50
50
100
20
50
50
100
100
50
100
100
50
50
250
Saople
Sanple
Cone.
ug/L
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
1.2
1.8
1.8
1.1
< 0.1
< 0.5
< 0.5
< 0.3
0.4
1.1
Sample:
Sanple
Cone.
ug/L
< 0.3
'. 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
: 90-05-031-08
Cone.
Found
ug/L
53
49
52
100
2
52
54
81
100
22
81
85
58
52
219
90-05-037-06
Cone.
Found
Percent
Recovery
107
98
104
100
10
102
105
79
99
44
81
85
117
104
87
Percent
Sample:
Sanple
Cone.
ug/L
0.4
< 0.3
< 0.3
< 0.5
< 0.1
10.9
< 0.5
0.5
< 2.5
0.5
< 0.5
2.0
< 0.3
< 0.3
< 1.3
90-05-033-01
Cone.
Found
ug/L
49
48
55
97
20
60
51
77
100
20
83
79
51
50
199
Percent
Recovery
97
%
109
97
98
98
101
77
100
40
83
77
102
101
79
ug/L Recovery
51
50
49
100
20
50
51
83
102
20
79
82
51
48
206
101
99
99
100
102
100
103
83
102
40
79
82
102
95
82
-------
TECHNODDGIES INC.
SAS 1047
9 Run Chronology
Date
Sample Received
ration std A High, curve 1 N/A
ration std A 1:2, curve 1 N/A
ration std A 1:4, curve 1 N/A
ration std A 1:20, curve 1 N/A
ration std B High, curve 1 N/A
ration std B 1:2, curve 1 N/A
ration std B 1:4, curve 1 N/A
•ation std B 1:20, curve 1 N/A
031-OPR (100: 5mL) 05-17-90
033-OPR (100: 5mL) 05-18-90
037-OPR (100:5mL) 05-19-90
031-02 (100:5mL) 05-17-90
031-03 (100: 5mL) 05-17-90
033-03 (100: 5mL) 05-18-90
•033-04 (100:5mL) 05-18-90
1:4 Calibr. Verification N/A
1:4 Calibr. Verification N/A
037-03 (100: 5mL) 05-19-90
037-04 (100: 5mL) 05-19-90
1:4 Calibr. Verification N/A
1:4 Calibr. Verification N/A
031-00 (100:0.5mL) 05-17-90
033-00 (100:0.5mL) 05-18-90
-037-00 (100:0.5mL) 05-19-90
031-01 (100:0. 5mL) 05-17-90
•031-04 (100:0.5mL) 05-17-90
-031-05 (100:0.5mL) 05-17-90
•031-06 (100:0.5mL) 05-17-90
H531-07 (100:0. 5mL) 05-17-90
1:4 Calibr. Verification N/A
1:4 Calibr. Verification N/A
ration std A High, curve 2 N/A
ration std A 1:2, curve 2 N/A
ration std A 1:4, curve 2 N/A
ration std A 1:20, curve 2 N/A
ration std B High, curve 2 N/A
ration std B 1:2, curve 2 N/A
ration std B 1:4, curve 2 N/A
ration std B 1:20, curve 2 N/A
^031-08 (100:0.5mL) 05-17-90
"033-01 (100:0.5mL) 05-18-90
•033-02 (100:0.5mL) 05-18-90
~°33-05 (100:0. 5mL) 05-18-90
•033-06 (100:0.5mL) 05-18-90
•°33-07 (100: ImL) 05-18-90
~°33-08 (100: ImL) 05-18-90
•°33-09 (100:0.5mL) 05-18-90
Date
Extracted
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-17-90
05-21-90
05-29-90
05-17-90
05-17-90
05-21-90
05-21-90
05-25-90
05-25-90
05-29-90
05-29-90
05-25-90
05-25-90
05-17-90
05-21-90
05-29-90
05-17-90
05-17-90
05-17-90
05-17-90
05-17-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-17-90
05-21-90
05-21-90
05-21-90
05-21-90
05-21-90
05-21-90
05-21-90
Colum: DB-1
Date Time
Analyzed
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-09-90
06-10-90
06-10-90
06-10-90
06-10-90
06-10-90
06-10-90
06-10-90
06-10-90
06-10-90
06-10-90
06-10-90
06-10-90
06-10-90
06-10-90
06-10-90
06-10-90
11:26
12:05
12:43
14:02
15:36
16:13
16:51
17:28
18:05
18:43
19:20
20:34
21:11
21:49
22:26
23:40
00:18
00:55
01:32
14:30
15:07
17:50
18:27
19:05
19:42
20:19
20:57
21:34
22:11
23:26
00:03
12:32
13:08
13:45
14:22
14:58
15:35
16:11
16:48
17:24
18:01
18:37
19:14
19:50
20:27
21:03
21:40
Colum: DB-608
Date Time
Analyzed
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-07-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-08-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
10:31
11:21
12:05
14:03
13:20
15:36
16:13
16:51
17:28
18:05
18:43
19:57
20:34
21:11
21:49
23:03
23:40
00:18
00:55
13:53
14:30
17:13
17:50
18:27
19:05
19:42
20:19
20:57
21:34
22:48
23:26
00:03
00:40
01:17
01:55
02:32
03:09
03:46
04:23
-------
pTICftL TECHNOLOGIES INC
2 9 Run Chronology
Date
Sample Received
1 1:4 Calibr. Verification N/A
1 1:4 Calibr. Verification N/A
5-033-10 (100:0.5mL) 05-18-90
5-037-01 (100:0.5mL) 05-19-90
5-037-02 (100:0.5mL) 05-19-90
j-037-05 (100:0. 5mL) 05-19-90
HJ37-06 1100:0. 5mL) 05-19-90
j-037-07 (100:lmL) 05-19-90
)-037-08 (100:ljnL) 05-19-90
HJ37-09 (100:0.5mL) 05-19-90
1 1:4 Calibr. Verification N/A
) 1:4 Calibr. Verification N/A
ration std A High, curve 3 N/A
ration std A 1:2, curve 3 N/A
ration std A 1:4, curve 3 N/A
ration std A 1:20, curve 3 N/A
ration std B High, curve 3 N/A
ration std B 1:2, curve 3 N/A
ration std B 1:4, curve 3 N/A
ration std B 1:20, curve 3 N/A
N/A
-031-08MS A (100:5mL) 05-17-90
-033-01MS A (100:5cnL) 05-18-90
-037-06MS A (100:5mL) 05-19-90
ration std A High, (2.5:1) N/A
ration std B High, (2.5:1) N/A
1:4 Calibr. Verification N/A
1:4 Calibr. Verification N/A
Date
Extracted
05-25-90
05-25-90
05-21-90
05-29-90
05-29-90
05-29-90
05-29-90
05-29-90
05-29-90
05-29-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
05-25-90
05-25-90
Colum:
Date
SAS 1008
DB-1
Tine
Analyzed
06-10-90
06-10-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-13-90
-06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
22:53
23:29
00:06
00:42
01:19
01:55
02:32
03:08
03:44
04:23
05:34
06:11
17:55
18:32
19:10
19:47
20:24
21:01
21:39
22:16
22:53
00:08
00:45
01:22
04:28
05:05
05:43
06:20
Colum:
Date
DB-608
Time
Analyzed
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
-06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
05:38
06:15
06:52
07:29
08:34
10:56
11:34
12:10
12:47
13:23
15:44
16:23
17:10
17:55
18:32
19:10
19:47
20:24
21:01
21:39
22:16
23:30
00:08
00:45
03:51
04:28
05:05
05:43
-------
TECHNOLOGIES INC.
10 Calibration Data Curve 1
SAS 1047
Compound
chlorophenol
idilorophenol
ichlorophenol
)roguaiacol
trichlorophenol
chloroguaiacol
chlorocatechol
rovanillin
Alorocatechol
tichloroguaiacol
Cone
(ug/mL
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04 •
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
Peak
Area
24292
12883
6431
1488
22305
11667
5938
1169
21423
11446
5660
1115
19406
10332
4822
893
12475
6519
3164
593
18857
9727
4878
920
16048
8466
4250
857
14172
7390
3593
697
33489
17711
9090
1846
8903
5094
2483
441
UO-L
Calib
Factor
8.23E-05
7.76E-05
7.77E-05
6.72E-05
8.97E-05
8.57E-05
8.42E-05
8.55E-05
9.34E-05
8.74E-05
8.83E-05
8.97E-05
2.06E-04
1.94E-04
2.07E-04
2.24E-04
6.41E-05
6.14E-05
6.32E-05
6.75E-05
1.06E-04
1.03E-04
1.03E-04
1.09E-04
1.25E-04
1.18E-04
1.18E-04
1.17E-04
2.82E-04
2.71E-04
2.78E-04
2.87E-04
1.19E-04
1.13E-04
1.10E-04
1.08E-04
8.99E-05
7.85E-05
8.05E-05
9.07E-05
Mean
Calib
Factor
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
%RSDof
Calib
Factors
7.3
2.4
2.5
5.2
3.5
2.4
2.7
2.1
3.8
6.4
-------
TECHN01CGIES INC.
SAS 1047
10 Calibration Data Curve 1 (Continued)
Compound
idilorovanillin
'osyringealdehyde
rtrichlorocatediol
lorosyringol
ichlorosyringaldehyde
trichlorophenol
rophenol
chlorophenol
raguaiacol
trichlorophenol
Cone
(ug/mL
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
10.00
5.00
2.50
0.50
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
Peak
Area
33439
16806
8360
1737
12283
5589
2639
523
23962
11983
5874
1208
24468
12845
6301
1262
45598
24045
11872
2395
19710
11170
5211
1120
13688
7282
3644
668
8258
4392
2135
337
12659
6804
3317
466
18614
10631
5250
924
l/D-J.
Calib
Factor
1.20E-04
1.19E-04
1.20E-04
1.15E-04
3.26E-04
3.58E-04
3.79E-04
8.35E-05
8.35E-05
8.51E-05
8.28E-05
8.17E-05
7.79E-05
7.94E-05
7.92E-05
2.19E-04
2.08E-04
2.11E-04
2.09E-04
r\o cno
DO DUO
1.01E-04
8.95E-05
9.60E-05
8.93E-05
1.46E-04
1.37E-04
1.37E-04
1.50E-04
9.69E-05
9.11E-05
9.37E-05
1.19E-04
1.58E-04
1.47E-04
1.51E-04
2.15E-04
2.15E-04
1.88E-04
1.90E-04
2.16E-04
Mean %RSD of
Calib Calib
Factor Factors
1.18E-04 1.6
3.54E-04 6.2
8.37E-05 1.0
7.95E-05 1.8
2.12E-04 2.1
9.41E-05 5.4
1.43E-04 3.8
l.OOE-04 10.9
1.68E-04 16.4
2.02E-04 6.5
-------
TECHNOLOGIES INC.
Calibration Data Curve I (Continued)
SAS 1047
Compound
-trichlorophenol
lichloroguaiacol
,6-tetradilorophenol
-trichloroguaiacol
idilorocatechol
t richloroguaiacol
hlorophenol
hloroguaiacol
hlorocatechol
Gone
(ug/mL
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
0.40
0.20
0.10
0.02
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
Peak
Area
19383
11110
5250
879
20597
12721
6400
1166
13748
8136
3803
1034
14167
8299
4001
908
22646
13203
6367
1037
7787
4147
1965
380
7159
3771
1643
310
10525
5669
2627
574
23243
13841
6578
1040
unrwo —
Calib
Factor
1.03E-04
9.00E-05
9.52E-05
1.14E-04
9.71E-05
7.86E-05
7.81E-05
8.58E-05
1.45E-04
1.23E-04
1.31E-04
9.67E-05
1.41E-04
1.20E-04
1.25E-04
1.10E-04
1.77E-04
1.51E-04
1.57E-04
1.93E-04
1.03E-04
9.65E-05
1.02E-04
1.05E-04
5.59E-05
5.30E-05
6.09E-05
6.45E-05
7.60E-05
7.06E-05
7.61E-05
6.97E-05
8.60E-05
7.22E-05
7.60E-05
9.62E-05
Mean %8SD of
Calil) Calib
Factor Factors
1.01E-04 8.9
8.49E-05 9.0
1.24E-04 14.3
1.24E-04 9.0
1.70E-04 9.7
1.02E-04 3.2
5.86E-05 7.6
7.31E-05 4.1
8.26E-05 U.3
-------
TECHNOLOGIES INC.
SAS 1047
10 Calibration Data Curve 2
Compound
ichlorophenol
ichlorophenol
ichlorophenol
iroguaiacol
trichlorophenol
chloroguaiacol
chlorocatechol
rwanillin
Chlorocatechol
trichloroguaiacol
Cone
(ug/mL
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
Peak
Area
354%
16587
7782
1664
32931
14876
7020
1253
29084
13430
6235
1087
30493
12783
5805
988
18471
7584
3969
708
27068
12115
5839
1319
22386
10273
4893
1030
20439
8867
4137
893
46946
22146
10677
2077
14583
6082
2995
503
l/D-J.
Calib
Factor
5.63E-05
6.03E-05
6.43E-05
6.01E-05
6.07E-05
6.72E-05
7.12E-05
7.98E-05
6.88E-05
7.45E-05
8.02E-05
9.20E-05
1.31E-04
1.56E-04
1.72E-04
2.02E-04
4.33E-05
5.27E-05
5.04E-05
5.65E-05
7.39E-05
8.25E-05
8.56E-05
7.58E-05
8.93E-05
9.73E-05
1.02E-04
9.71E-05
1.%E-04
2.26E-04
2.42E-04
2.24E-04
8.52E-05
9.03E-05
9.37E-05
9.63E-05
5.49E-05
6.58E-05
6.68E-05
7.95E-05
Mean
Calib
Factor
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
%RSDof
Calib
Factors
4.6
9.9
10.9
15.6
9.5
6.0
5.5
7.5
4.5
13.1
-------
TECHNOLOGIES INC.
SAS 1047
10 Calibration Data Curve 2 (Continued)
Compound
idilorovanillin
Dsyringealdehyde
-trichlorocatechol
lorosyringol
ichlorosyringaldehyde
•trichlorophenol
Cone
(ug/mL
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
10.00
5.00
2.50
0.50 .
2.00
1.00
0.50
0.10
Peak
Area
44048
22284
10295
2047
18235
8997
3798
738
32780
15631
6982
1453
33968
16974
8018
1548
64486
33205
14535
2997
36871
16622
8376
1512
UD~i
Calib
Factor
9.08E-05
8.98E-05
9.71E-05
9.77E-05
2.19E-04
2.22E-04
2.63E-04
6.10E-05
6.40E-05
7.16E-05
6.88E-05
5.89E-05
5.89E-05
6.24E-05
6.46E-05
1.55E-04
1.51E-04
1.72E-04
1.67E-04
5.42E-05
6.02E-05
5.97E-05
6.61E-05
Mean %RSD of
Calib Calib
Factor Factors
9.38E-05 3.8
2.35E-04 8.5
6.64E-05 6.2
6.12E-05 4.0
1.61E-04 5.4
6.01E-05 7.0
-------
TECHNOLOGIES INC.
, 10 Calibration Data Curve 3
SAS 1047
Compound
ichlorophenol
idilorophenol
ichlorophenol
iroguaiacol
trichlorophenol
diloroguaiacol
-hlorocatechol
^vanillin
iilorocatechol
richloroguaiacol
Gone
(ug/mL
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
Peak
Area
36336
17143
9602
2010
33658
16278
8545
1851
31248
15416
7779
1628
28482
137%
6884
1640
19067
8954
4770
1125
29485
13870
7488
1534
25328
12042
6208
1301
22513
10474
5510
1132
50271
24277
13139
2616
15962
7393
3959
829
vnri.
CaliJ)
Factor
5.50E-05
5.83E-05
5.21E-05
4.98E-05
5.94E-05
6.14E-05
5.85E-05
5.40E-05
6.40E-05
6.49E-05
6.43E-05
6.14E-05
1.40E-04
1.45E-04
1.45E-04
1.22E-04
4.20E-05
4.47E-05
4.19E-05
3.56E-05
6.78E-05
7.21E-05
6.68E-05
6.52E-05
7.90E-05
8.30E-05
8.05E-05
7.69E-05
1.78E-04
1.91E-04
1.81E-04
1.77E-04
7.%E-05
8.24E-05
7.61E-05
7.65E-05
5.01E-05
5.41E-05
5.05E-05
4.83E-05
Mean
Calib
Factor
5.38E-05
5.83E-05
6.36E-05
1.38E-04
4.10E-05
6.80E-05
8.08E-05
1.82E-04
7.86E-05
5.07E-05
%RSDof
Calih
Factors
6.0
4.6
2.1
6.9
8.2
3.8
2.1
3.1
3.2
4.2
-------
TECHNOLOGIES INC.
SAS 1047
10 Calibration Data Curve 3 (Continued)
CoBPpound
lidilorovanillin
osyringealdehyde
-trichlorocatechol
lorosyringol
ichlorosyringaldehyde
•trichlorophenol
>rophenol
chlorophenol
toguaiacol
trichlorophenol
Cone
(ug/mL
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
10.00
5.00
2.50
0.50
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
Peak
Area
51224
24726
13192
2698
18660
8587
4748
944
34558
16108
8647
1801
37624
18320
9755
2167
68510
32484
17633
3727
23249
11866
6598
1322
17999
9026
4797
940
10722
5471
2823
590
16907
8851
4634
977
25442
13257
6961
1481
unri
Calib
Factor
7.81E-05
8.09E-05
7.58E-05
7.41E-05
2.14E-04
2.33E-04
2.11E-04
5.79E-05
6.21E-05
5.78E-05
5.55E-05
5.32E-05
5.46E-05
5.13E-05
4.61E-05
1.46E-04
1.54E-04
1.42E-04
1.34E-04
8.60E-05
8.43E-05
7.58E-05
7.56E-05
1.11E-04
1.11E-04
1.04E-04
1.06E-04
7.46E-05
7.31E-05
7.08E-05
6.78E-05
1.18E-04
1.13E-04
1.08E-04
1.02E-04
1.57E-04
1.51E-04
1.44E-04
1.35E-04
Mean %8SD of
Calib Calib
Factor Factors
7.72E-05 3.3
2.19E-04 4.4
5.83E-05 4.1
5.13E-05 6.2 '
1.44E-04 5.0
8.04E-05 5.9
1.08E-04 2.7
7.16E-05 3.6
1.10E-04 5.4
1.47E-04 5.6
-------
TECHNOLOGIES INC.
10 Calibration Data Curve 3 (Continued)
Coopound
-tridilorophenol
ichloroguaiaool
, 6-tetrachlorophenol
-trichloroguaiacol
chlorocatechol
trichloroguaiacol
hlorophenol
iloroguaiacol
tiorocatechol
Cone
(ug/mL
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
0.40
0.20
0.10
0.02
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
Peak
Area
26665
13588
7421
1411
31544
15972
8791
1727
20231
10232
5637
1098
20768
10704
5857
1017
32891
16349
8526
1540
10466
5128
2699
485
9392
4525
2290
411
14609
7181
3811
594
30155
15017
7708
1378
I/D-WO —
Calib
Factor
7.50E-05
7.36E-05
6.74E-05
7.09E-05
6.34E-05
6.26E-05
5.69E-05
5.79E-05
9.89E-05
9.77E-05
8.87E-05
9.11E-05
9.63E-05
9.34E-05
8.54E-05
9.83E-05
1.22E-04
1.22E-04
1.17E-04
1.30E-04
7.64E-05
7.80E-05
7.41E-05
8.25E-05
4.26E-05
4.42E-05
4.37E-05
4.87E-05
5.48E-05
5.57E-05
5.25E-05
6.73E-05
6.63E-05
6.66E-05
6.49E-05
7.26E-05
Mean
Calib
Factor
. 7.17E-05
6.02E-05
9.41E-05
9.34E-05
1.23E-04
7.78E-05
4.48E-05
5.76E-05
6.76E-05
%RSDof
Calib
Factors
4.1
4.7
4.6
5.3 .
3.7
3.9
5.2
10.0
4.4
-------
"-.. ,-***
This supplement contains matrix spike/matrix spike duplicate
results and raw data not contained in the report submitted
June 15, 1990. All tables associated with this data have been
updated and are contained in this package.
Revised result tables, sample data sheets, and calibration
factor tables are also contained in this report. Due to a
miscalculation in the calibration factor tables, the result
summary tables and sample quantitation reports are outdated
and should be disregarded and replaced with those enclosed.
-------
lnL TECHNOLOGIES INC.
Results Obtained for Chlorinated Phenolics. Concentrations in ug/L.
SAS 1047
lorophenol
lorophenol
lorophenol
guaiacol
ich lorophenol
.oroguaiacol
lorocatechol
vanillin
lorocatechol
ichlorogaaiacol
lorovanillin
ringaldehyde
ichlorocatechol
osyrirtgol
lorosyr i nga Idehyde
phenol
lorophenol
ch lorophenol
juaiacol
ch lorophenol
oroguaiacol
etrach lorophenol
chl oroguaiacol
orocatechol
chl oroguaiacol
rophenol
roguaiacol
rocatechol
Blank
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
' 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
19355
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
3.0
< 0.5
< 0.5
< 2.5
0.1
< 0.5
1.0
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
0.5
< 0.5
< 0.3
< 0.5
< 1.0
1.1
< 0.1
< 0.1
< 0.3
19356
6
< 3
< 3
< 5
< 1
< 3
53
< 5
< 25
< 1
< 5
< 5
< 3
3
< 13
< 3
< 1
< 3
< 5
24
< 5
< 3
< 5
46
< 3
< 1
< 1
57
19357
< 3
< 3
< 3
< 5
< 1
61
< 5
< 5
< 25
5
< 5
< 5
< 3
36
29
< 3
< 1
14
< 5
18
< 5
11
10
< 10
125
< 1
3
< 3
-tPA samp i
19358
< 0.3
< 0.3
< 0.3
< 0.5
< -0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
e Nurroer!
19359
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
« 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
i
19360
< 0.3
< 0.3
' 0.3
< 0.5
0.1
2.9
< 0.5
1.4
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
1.3
2.1
< 0.3
< 0.1
0.7
< 0.5
2.2
< 0.5
< 0.3
< 0.5
< 1.0
6.0
< 0.1
< 0.1
< 0.3
19361
< 0.3
< 0.3
< 0.3
< 0.5
0.1
2.9
4.5
< 0.5
1.4
' 0.1
< 0.5
0.8
< 0.3
1.1
1.4
< 0.3
< 0.1
1.1
< 0.5
2.7
< 0.5
< 0.3
< 0.5
6.0
4.6
1.6
< 0.1
< 0.3
19362
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
1.2
1.8
1.8
1.1
< 0.1
< 0.5
< 0.5
< 0.3
0.4
1.1
< 0.3
0.1
< 0.3
< 0.5
1.1
< 0.5
< 0.3
1.5
2.5
1.1
< 0.1
' 0.1
0.3
Blank
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
-------
TECHNOLOGIES INC.
SAS 1047
Results Obtained for Chlorinated Phenolics.
id
jilorophenol
jilorophenol
dlorophenol
oguaiacol
richlorophenol
hloroguaiacol
hlorocatechol
ovanillin
hlorocatechol
rich loroguaiacol
ilorovanillin
^ringaldehyde
-ichlorocatechol
•osyringol
ilorosyringaldehyd
iphenol
ilorophenol
•ichlorophenol
iguaiacol
'ichlorophenol
loroguaiacol
Tetrachlorophenol
ich loroguaiacol
lorocatechol
ich loroguaiacol
orophenol
oroguaiacol
orocatechol
19364
0.4
< 0.3
< 0.3
< 0.5
< 0.1
10.9
< 0.5
0.5
< 2.5
0.5
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
0.6
< 0.5
0.6
< 0.5
< 0.3
< 0.5
< 1.0
1.3
< 0.1
< 0.1
< 0.3
19365
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
5.8
< 0.5
< 0.5
< 2.5
0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
0.3
< 0.5
0.4
< 0.5
' 0.3
< 0.5
< 1.0
0.8
< 0.1
< 0.1
< 0.3
19366
13
< 3
< 3
< 5
< 1
< 3
67
15
< 25
2
< 5
< 5
< 3
< 3
12
< 3
< 1
< 3
< 5
26
< 5
< 3
< 5
61
< 3
< 1
< 1
20
I
19367
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
•PA Sample
19368
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0,5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0,1
< 0.1
< 0.3
Numbers- -
19369
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
' 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
19370
< 0.5
< 0.5
< 0.5
< 1.0
< 0.2
< 0.5
< 1.0
4.9
< 5.0
< 0.2
< 1.0
< 1.0
7.2
4.1
4.0
0.5
< 0.2
1.0
< 1.0
3.8
< 1.0
< 0.5
< 1.0
< 2.0
9.7
5.2
3.5
< 0.5
19371
< 0.5
< 0.5
< 0.5
< 1.0
0.3
4.4
5.2
1.8
< 5.0
0.7
< 1.0
< 1.0
< 0.5
< 0.5
2.8
< 0.5
0.7
1.6
< 1.0
4.9
< 1.0
< 0.5
1.3
8.4
8.9
2.4
< 0.2
< 0.5
19372
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
1.4
1.4
3.0
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
0.6
1.3
< 0.3
0.2
0.3
< 0.5
1.4
< 0.5
1.1
0.8
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
19373
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
1.9
1.9
3.0
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
0.9
2.2
< 0.3
0.2
0.3
< 0.5
1.6
< 0.5
0.9
0.5
< 1.0
< 0.3
< 0.1
< 0.1
0.5
-------
|L TECHNOLOGIES INC.
Results Obtained for Chlorinated Phenolics. Concentrations in ug/L. (Continued)
SAS 1047
orophenol
orophenol
orophenol
uaiacol
chlorophenol
oroguaiacol
orocatechol
anil I in
orocatechol
chl oroguaiacol
orovanillin
ingaldehyde
chlorocatechol
syringol
orosyringaldehyd
henol
orophenol
chlorophenol
uaiacol
chlorophenol
oroguaiacol
etrach I orophenol
chl oroguaiacol
orocatechol
chl oroguaiacol
rophenol
roguaiacol
rocatechol
Blank
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
19375
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3 "
19376
< 0.3
< 0.3
< 0.3
1.4
< 0.1
< 0.3
0.8
< 0.5
0.9
0.8
1.7
< 0.5
0.6
< 0.3
< 1.3
'. 0.3
< 0.1
< 0.3
< 0.5
1.4
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
0.4
0.9
< 0.3
EPj
19377
< 3
< 3
< 3
9
< 1
< 3
98
< 5
< 25
< 1
< 5
< 5
< 3
3
< 13
3
< 1
< 3
< 5
41
< 5
< 3
< 5
77
< 3
< 1
< 1
26
i sample Nun
19378
< 3
< 3
< 3
< 5
< 1
64
< 5
< 5
< 25
11
< 5
< 5
< 3
39
14
< 3
5
14
< 5
29
< 5
< 3
13
< 10
125
< 1
< 1
< 3
Kjers
19379
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
.< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0..3
< 0.1
< 0.1
< 0.3
19380
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
' 0.1
< 0.3
' 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
19381
< 0.5
< 0.5
< 0.5
2.0
< 0.2
< 0.5
3.8
2.3
2.3
< 0.2
7.6
< 1.0
< 0.5
< 0.5
< 2.5
< 0.5
< 0.2
0.5
< 1.0
3.9
< 1.0
' 0.5
< 1.0
< 2.0
< 0.5
< 0.2
' 0.2
< 0.5
19382
< 0.5
< 0.5
< 0.5
< 1.0
0.9
7.9
11.3
1.8
3.2
1.8
< 1.0
< 1.0
< 0.5
3.9
4.3
1.0
1.1
2.4
< 1.0
6.6
< 1.0
< 0.5
< 1.0
12.6
13.0
< 0.2
< 0.2
< 0.5
19383
< 0.3
< 0.3
< 0.3
' 0.5
< 0.1
6.8
7.1
7.1
< 2.5
< 0.1
< 0.5
5.8
< 0.3
2.7
5.9
< 0.3
0.9
0.9
< 0.5
4.3
< 0.5
2.6
< 0.5
10.5
< 0.3
3.2
< 0.1
< 0.3
-------
ANALYTICAL TECHNOLOGIES INC.
EPA No. Blank
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2.3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani 1 1 in
Ch lorosyri nga Idehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
TABLE 3 and TABLE 4: QUANTIFI
ATI No. 90-05-031-00 Sample Volume (
Peak Calib Cone, in Conc/OU
Quant. Area Factor Extract Factor
Colum
DB-
DB-
DB-
DB-
DB-
DB-
DB-
DB-
DB-
DB-
DB-
DB-
DB-
DB-
DB-
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
(A) (CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
.0.1
'0.1
CATIONS AND IDENTIFICATIONS
Vs) • 100 ml Extract
Cone. Observed
Volu
col
mo •
8 At 104
5 ml
Observed
r
J column-"-
Cs (ug/L) (4) Ret. Time Window Rot. Tim* Window
< 0.3
c 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
e 0.3
< 0.3
< 1.3
< 0.3
c 0.1
< 0.3
< 0.5
t 0.3
< 0.5
< 0.3
< 0.5
« 1.0
< 0.3
< 0.1
< 0.1
< 0.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
S.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
43885 9.41E-05
4.13
0.1
21
11.88 11.59 to 12.04
10.56 10.30 to 10.75
Calibration factors from average of 4-point calibration. CF = Cone (ug/mL)/peak area
(2) Ce = CF
-------
ANALYTICAL TECHNOLOGIES INC.
TABLE 3 and TABLE 4: QUANTIFICATIONS AND IDENTIFICATIONS
SAS 1047
EPA No. T9355
ATI No. 90-05-031-01
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
COMPOUND
s=s=ss====s;s==================
2 , 6-D i ch I oropheno I
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani llin
Ch I orosyr i nga Idehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2, 6-D ich I orosyr i nga Idehyde
4 -Chi oropheno I
2, 4 -D ich I oropheno I
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacot
Pentachlorophenol
Tet rach I orogua i aco I
Tetrachlorocatechol
Quant .
Column
===========:
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
-------
ANALYTICAL TECHNOLOGIES INC.
TABLE 3 and TABLE 4: QUANTIFICATIONS AND IDENTIFICATIONS
SAS 1047
EPA No. 19356
ATI No. 90-05*031-02
Sample Volume (Vs) - 100 ml
Extract Volume (Ve)
5 mL
COMPOUND
2,6-D i chIorophenoI
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
ChIorosyr i ngaIdehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-ChiorophenoI
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
PentachIorophenoI
TetrachIoroguaiacoI
Tetrachlorocatechol
Quant .
Column
:====SE===
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
reaic tauD
Area Factor
-------
ANALYTICAL TECHNOLOGIES INC.
EPA No. 19366
COMPOUND
2,6-Oichtorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovamllin
Chlorosyringal dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Oichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pent ach I oropheno I
Tet rach I orogua i aco I
Tetrachlorocatechol
3,4,5-Trichlorophenol
TABLE 3 and TABLE 4: QUANTIFICATIONS AND
ATI No. 90-05-033-03 Sample Volume (Vs) = 100
Peak Calib Cone, in Cone /Oil Sample
Quant. Area Factor Extract Factor Cone.
Column (A)
-------
ANALYTICAL TECHNOLOGIES INC.
EPA No. 1*9358
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani 1 1 in
Ch 1 orosyri nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tet rach I orogua i aco I
Tetrachlorocatechol
3,4,5-Trichlorophenol
TABLE 3 and TABLE 4: QUANTIFICATIONS AND ID
ATI No. 90-05-031-04 Sample Volume (Vs) = 100 ml
Peak Calib Cone, in Cone/Oil Sample
Quant. Area Factor Extract Factor Cone.
Column (A) (1) Ce (ug/mL) (2) (X) (3) Cs (ug/L) (4)
DB-
DB-
DB-
DB-
DB-
DB-
DB-
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
33139 9.41E-05
< -0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
<• 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< o;os
« 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
3.12
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
t 0.5
< 0.5
< 2.5
< 0.1
< 0.5
'< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
c 0.5
< 0.3
< ' 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
16
ENTIFICATIONS
Extract
_|\Q_ 1
Observed
Ret. Time u
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
11.85 11.59
Volur
col
indo
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
ne (Ve) =
rf
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
12.04
SAS 1047
5 ml
Observed
Ret. Time V
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
10.59 10.30
t
column
ffndow
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
10.75
-------
ANALYTICAL TECHNOLOGIES INC.
EPA No. {9359
TABLE 3 and TABLE 4: QUANTIFICATIONS AND ID
ATI No. 90-05-031-05 Sample Volume (Vs) * 100 ml
Peak Calib Cone, in Cone/Oil Sample
Quant. Area Factor Extract Factor Cone.
COMPOUND Column (A) (CF) (1) Ce (ug/mL) (2) (X) (3) Cs (ug/L) (4)
2,6-Oichlorophenol DB-1 7.62E-05 < 0.05 0.1 < 0.3
3,5-Dichlorophenol
3,4-Oichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichtoroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3 , 4-D i ch lorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani 1 1 in
Chi orosyr i nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4 , 5 - D i ch I orogua i aco I
2,3,4,6-Tetrachlorophenol
3,4,6- Trichloroguaiacol
4, 5-0 ich lorocatechol
4,5,6-Trichloroguaiacol
Pentach I oropheno I
Tetrach 1 orogua i acol
Tetrach I orocatechol
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
. DB-
08-
DB-
08-
DB-
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1 .43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
c 0.02
< 0.02
< 0.05
0.1 «
0.1 <
0.1 <
0.1 <
0.1 <
0.1- <
0.1 <
0.1 <
0.1 <
0.1 .<
0.1 <
0.1 <
0.1 <
0.1 <
0.1 e
0.1 <
0.1 <
0.1 <
0.1 < .
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.3
0.3
0.5
0.1
0.3
0.5
0.5
2.5
0.1
0.5
0.5
0.3
0.3
1.3
0.3
0.1
0.3
0.5
0.3
0.5
0.3
0.5
1.0
0.3
0.1
0.1
0.3
ENTIFICATIONS
Extract \
Observed
/olu
col
no (Vo) -
SAS 104'
5 ml
Observed
Ret. Time Window Ret.
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
r
column----
Time Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
33507 9.41E-05
3.15
0.1
16
11.83 11.59 to 12.04
10.56 10.30 to 10.75
-------
ANALYTICAL TECHNOLOGIES INC.
TABLE 3 and TABLE 4: QUANTIFICATIONS AND IDENTIFICATIONS
SAS 1047
EPA No. T9360
ATI No. 90-05-031-06
Sample Volume (Vs) = 100 ml
Extract Volume (Ve)
5 ml
Quant .
i-ean V.BIID
Area Factor
COMPOUND Column (A) (CF) (1)
2,6-Dichlorophenol DB-1 7.62E-05
3,5-Dichlorophenol
3,4-Dlchlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3 ,4-0 i ch lorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
Chlorosyringaldehyde
3,4,5-THchlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Oichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pent ach I oropheno I
Tet rach I orogua i aco I
Tet rach I oroca techo I
DB-1
DB-1
DB-1
D8-1
DB-1
DB-1
DB-1
DB-
08-
DB-
08-
08-
08-
08-
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
08-608
DB-608
08-608
8.63E-05
8.97E-05
2.08E-04
325 6.40E-05
5435 LOSE -04
1.20E-04
1005 2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
3270 7.95E-05
1983 2.12E-04
1.43E-04
1.00E-04
1400 1.01E-04
3.35E-04
4417 1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
11711 1.02E-04
5.86E-05
7.31E-05
8.26E-05
Lone . i n
Extract
Ce (ug/mL) (2)
< -0.05
< 0.05
< 0.05
< 0.10
0.02
0.57
< 0.10
0.28
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
0.26
0.42
< 0.05
< 0.02
0.14
< 0.10
0.45
< 0.10
< 0.05
< 0.10
< 0.20
1.19
< 0.02
< 0.02
< 0.05
uonc/ui i
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.
0.
0.
0.
0.
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
sample
Cone.
- uo- 1
Observed
column--- •
no- ouo column- •••
Observed
Cs (ug/L) (4) Ret. Time Window Ret. Time Window
< 0.3 5.34 to 5.68 5.26 to 5.61
< 0.3
c 0.3
< 0.5
0.1
2.9
< 0.5
1.4
< 2.5
< 0.1
< 0.5
'< 0.5
< 0.3
1.3
2.1
< 0.3
< 0.1
0.7
< 0.5
2.2
<' 0.5
< 0.3
< 0.5
< 1.0
6.0
< 0.1
< 0.1
< 0.3
6.10
7.02
7.41
9.50 9.15
10.97 10.86
13.45
14.50 14.12
14.89
16.89
19.41
19.93
21.00
23.14 22.71
26.70 26.22
3.88
5.80
8.32 8.10
7.25
9.97 9.74
12.51
13.99
14.56
16.02
18.42 18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
4.84
6.30
8.03
9.50 9.02
11.88 11.54
13.79
16.71 16.49
16.47
16.46
21.60
23.22
22.43
23.66 23.22
28.58 28.16
3.41
5.22
7.38 7.18
8.09
8.86 8.70
13.09
13.50
14.13
16.33
20.05 19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-THchlorophenol
DB-608
27246 9.41E-05
2.56
0.1
13
11.83 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA Wo. 1V361
ATI No. 90-05-031-07
Sample Volume (Vs) - 100 ml
Extract Volume (Ve) =
5 mL
redK uai i u
Quant. Area Factor
COMPOUND Column (A) (CF) (1)
2,6-Oichlorophenol DB-1 7.62E-05
3,5-Dichlorophenol DB-1 8.63E-OS
3,4-Dichlorophenol DB-1 8.97E-05
5 - Ch I orogua i aco I
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-DichLorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani Uin
Ch I orosyr i nga Idehyde
3,4,5-Trichlorocatechol
T r i ch t orosyr i ngo I
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4 - Ch I orogua i aco I
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrach I orocatechol
3,4,5-Trichtorophenol
DB-1
DB-1
DB-1
DB-1
DB-1
DB-
DB-
DB-
D8-
DB-
DB-
DB-1
DB-608
OB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
445
5482
7549
289
2456
450
2754
1277
2243
5400
7093
9078
5539
23287
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
9.41E-05
lone . i n
Extract
Ce (ug/mL) (2)
< 0
< 0
< 0
< 0
0
0
0
< 0
0
< 0
< 0
0
< 0
0
0
< 0
< 0
0
< 0
0
< 0
< 0
< 0
1
0
0
< 0
< 0
2
.05
.05
.05
.10
.03
.58
.91 '
.10
.28
.02
.10
.16
.05
.22
.27
.05
.02
.23
.10
.55
.10
.05
.10
.21
.93
.32
.02
.05
.19
Lonu/ui i
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.
0.
0.
0.
0.
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
aainpie .... uo- i coiunwi
Cone. Observed
Cs (ug/L) (4) Ret. Time Window
< 0.3
< 0.3
< 0.3
< 0.5
0.1
2.9
4.5
< 0.5
1.4
< 0.1
< 0.5
0.8
< 0.3
1.1
1.4
< 0.3
< 0.1
1.1
< 0.5
2.7
< 0.5
< 0.3
< 0.5
6.0
4.6
1.6.
< 0.1
< 0.3
11
9.53
10.97
13.82
14.49
15.28
20.37
23.15
26.82
8.32
9.97
18.42
11.83
5.34
6.10
7.02
7.41
9.15
10.66
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
11.59
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
12.04
-UD-OUO tUlUIII
Observed
Ret. Time Window
9.20
11.87
14.18
16.84
16.84
23.66
23.66
28.58
7.38
8.86
20.05
10.57
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
10.30
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
to 10.75
-------
EPA.No. 19362
ATI No. 90-05-031-08
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
COMPOUND
===========================
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichtorophenol
5 -Chi orogua iacot
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovani llin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
Ch 1 orosyr i nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyn'ngol
2,6-Dfchlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4 , 5 -D i ch I orogua i aco I
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5'Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrach I orogua iacol
Tetrachlorocatechol
3,4,5-TMchlorophenol
Quant .
Column
============
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
D8-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
=========
569
2987
3680
1610
2486
1461
1401
184
334
2207
2342
2997
2183
823
20492
Calib
Factor
(CF) (1)
:==========£
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
9.41E-05
Cone . i n
Extract
Ce (ug/mL) (2)
==================
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
0.24
0.35 '
0.36
0.23
< 0.02
< 0.10
< 0.10
< 0.05
0.09
0.23
< 0.05
0.02
< 0.05
< 0.10
0.22
< 0.10
< 0.05
0.29
0.51
0.22
< 0.02
< 0.02
0.07
1.93
Conc/Oi I
Factor
(X) (3)
==========:
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
-OB-1 column-
Sample
Cone. Observed
Cs (ug/L) (4) Ret. Time Window
-DB-608 column
Observed
Ret. Time
Window
0.3
0.3
0.3
0.5
0.1
1.2
1.8
1.8
1.1
0.1
0.5
0.5
0.3
0.4
1.1
0.3
0.1
0.3
0.5
1.1
0.5
0.3
1.5
2.5
1.1
0.1
0.1
0.3
10
5.53
10.85
13.71
14.38
14.93
23.01
26.72
5.89
8.22
9.88
14.93
16.20
18.27
26.34
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
5.39
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
to 22.75
to 26.65
to
to
to
to
to
to
to
to
to
to
to
11.88
14.18
16.64
16.64
23.67
28.59
5.39
7.38
8.86
14.18
16.64
20.05
27.18
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
11.72 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA No. Blank
ATI No. 90-05-033-00
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
Quant.
reaK lauo
Area Factor
Column (A) (CF) (1)
DB-1 7.62E-05
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
8
8
2
6
1
1
2
1
8
1
3
8
.63E-05
.97E-05
.08E-04
.40E-05
.05E-04
.20E-04
.80E-04
.13E-04
.49E-05
.18E-04
.54E-04
.37E-05
7.95E-05
2
1
1
1
3
1
8
1
1
1
1
5
7
8
.12E-04
.43E-04
.OOE-04
.01E-04
.35E-04
.01E-04
.49E-05
.24E-04
.24E-04
.70E-04
.02E-04
.86E-05
.31E-05
.26E-05
Lone . i n
Extract
i.onc/ui i
Factor
sample ........... -uo- t column--- -
Conc. Observed
Ce (ug/mL) (2) (X) (3) Cs (ug/L) (4) Ret. Time Window
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
« 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
< 0.3
< 0.3
< 0.3
< 0.5
e 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1 .
< 0.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
UB-OUO column
Observed
Ret. Time Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to.
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49.
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
49569 9.41E-05
4.66
0.1
23
11.84 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA No. 19364
ATI No. 90-05-033-01
Sample Volune (Vs) = 100 mL
Extract Volune (Ve) =
5 mL
COMPOUND
2,6-Dichlorophenol
3 ,5-01 chlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2, 3, 6-TH chlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocetechol
6-Chlorovani llin
3,4-Dlchlorocatechol
3,4,5-THchloroguaiacol
5,6-Dichlorovani Uin
Ch I orosy r i nga I dehyde
3,4,5-THchlorocatechol
THchlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-D)chlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2 , 4 , 5 - T r i ch I orophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3 , 4 , 6- T r i ch I orogua i aco I
4,5-Dlchlorocetechol
4,5,6-THchloroguaiacol
Pantachlorophanol
Tctrachloroguaiacol
Tatrachlorocetochot
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
OB -608
DB-608
08-608
DB-608
DB-608
DB-608
DB-608
reaK Lai ID
Area Factor
Lone, in
Extract
LOOC/UI i
Factor
sample un- i coium
Cone. Observed
(A) (CF) (1) Ce (ug/mL) (2) (X) (3) Cs (ug/L) (4) Ret. Time Window
1366 6.02E-05
352 6.97E-05
7
1
5
27412 7
9
464 2
9
1558 6
9
1695 2
6
6
1
1
1
1129 1
3
1286 1
8
1
1
1
2581 1
5
7
8
.89E-05
.66E-04
.07E-05
.95E-05
.63E-05
.22E-04
.14E-05
.67E-05
.38E-05
.35E-04
.64E-05
.12E-05
.61E-04
.43E-04
.OOE-04
.01E-04
.35E-04
.01E-04
.49E-05
.24E-04
.24E-04
.70E-04
.026-04
.86E-05
.31E-05
.26E-05
0.08
< 0.05
< 0.05
< 0.10
< 0.02
2.18
< 0.10
0.10
< 0.50
0.10
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
0.11
< 0.10
0.13
< 0.10
< 0.05
< 0.10
< 0.20
0.26
< 0.02
< 0.02
< 0.05
0.1 0.4 5.48
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
< 0.
< 0.
< 0.
< 0.
10.
< 0.
0.
< 2.
0.
< 0.
< 0.
< 0.
< 0.
< 1.
< 0.
< 0.
3 6.19
3
5
1
9 10.85
5
5 14.38
5
5 17.20
5
5 20.25
3
3
3
3
1
0.6 8.82
c 0.5
0.6 9.89
< 0.
5
< 0.3
< 0.5
< 1.0
1.3 18.29
< 0.1
< 0.1
< 0.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to 5.68
to 6.49
to 7.45
to 7.86
to 9.66
to 11.44
to 14.14
to 14.79
to 15.59
to 17.62
to 20.17
to 20.71
to 21.76
to 23.49
to 27.05
to 4.06
to 6.07
to 8.43
to 7.57
to 10.11
to 12.95
to 14.45
to 15.04
to 16.50
to 18.60
to 21.72
to 22.75
to 26.65
UB-OUO
Observed
cuiuwi----
Ret. Time Window
5.42 5.26
5.10 4.84
6.30
8.03
9.02
11.88 11.54
13.79
16.76 16.49
16.47
16.76 16.46
21.60
23.66 23.22
22.43
23.22
28.16
3.41
5.22
7.38 7.18
8.09
8.87 8.70
13.09
13.50
14.13
16.33
20.05 19.74
19.97
21.82
26.73
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
J,4,5-Irlchtorophanol
DB-608
38993 9.4U-05
3.67
0.1
18
11.73 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA'No. 19365
ATI No. 90-05-033-02
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
D8-608
DB-608
DB-608
DB-608
DB-608
DB-608
reaK laiio lone, in
Area Factor Extract
(A)
-------
EPA.No. 19366
ATI No. 90-05-033-03
Sample Volume (Vs) = 100 ml
Extract Volume (Ve)
5 ml
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovenillin
3,4-D1chlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani11 in
ChIorosyr i ngaIdehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trfchlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
PentachIorophenoI
Tetrachlorogualacol
Tatrachlorocatechol
3,4,5-Trichlorophenol
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-
DB-
08-
DB-
DB-
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
OB -60S
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
3519
11231
1100
565
1118
5111
7181
4813
6024
Calib
Factor
(CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
9.41E-05
tone . i n
Extract
Ce (ug/mL) (2)
0.27
< 0.05
< 0.05
< 0.10
< 0
< 0
1
0
< 0
0
< 0
< 0
< 0
< 0
0
< 0
< 0
< 0
< 0
0
< 0
< 0
< 0
1
< 0
< 0
< 0
0
0
.02
.05
.35 '
.31
.50
.05
.10
.10
.05
.05
.24
.05
.02
.05
.10
.52
.10
.05
.10
.22
.05
.02
.02.
.40
.57
Lonc/ui i
Factor
(X) (3)
1.0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
sample
Cone . Observed
uo- i
column- •-•
Cs (ug/L) (4) Ret. Time Window
13 5.55
< 3
< 3
< 5
< 1
< 3
67 13.76
15 14.43
< 25
2 17.25
< 5
< 5
< 3
< 3
12 26.77
< 3
< 1
< 3
< 5
26 9.91
< 5
< 3
< 5
61 16.25
< 3
< 1 .
< 1
20 26.22
28 11.78
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
11.59
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
12.04
Observed
Ret. Time Window
'"2S- — — SB3 — S3SSSSSSS3;:"" «•"••••"•«"
5.53 5.26 to
4.
6.
8.
84
30
03
9.02
11.
14.14 13.
16.84 16.
16.
16.84 16.
21.
23.
22.
23.
28.57 28.
3.
5.
7.
54
79
49
47
46
60
22
43
22
16
41
22
18
8.09
8.83 8.70
13.09
13.50
14.13
16.59 16.33
19.74
19.97
21.82
27.04 26.73
10.53 10.30
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
10.75
-------
EPA.No. 19367
ATI No. 90-05-033-04
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
ChIorosyr i ngaIdehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
P63K
Quant. Area
Column (A)
DB-1
OB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
OB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-60B
DB-608
DB-608
DB-608
DB-608
DB-608
693
12409
1242
1325
11332
4302
735
2257
5636
2731
2502
28289
2252
Lai ID
Factor
(CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Lone . i n
Extract
Ce (ug/mL) (2)
< 0
< 0
< 0
0
< 0
1
< 0
< 0
< 0
0
< 0
< 0
< 0
0
0
< 0
0
0
< 0
0
< 0
0
0
< 0
2
< 0
0
< 0
.05
.05
.05
.14
.02
.30
.10-
.10
.50
.11
.10
.10
.05
.90 .
.91
.05
.07
.23
.10
.57
.10
.34
.31
.20
.89
.02
.16
.05
lonc/ui i
Factor
(X) (3)
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
.0
.0
.0
.0
.0
.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
a ample -• UD- i coium — -
Cone. Observed
Cs (ug/L) (4) Ret. Time Window
< 3
< 3
< 3
7
< 1
65
< 5
< 5
< 25
6
< 5
< 5
< 3
45
46
< 3
4
11
< 5
28
< 5
17
16
< 10
144
< 1
a'
< 3
5.34 to
6.10 to
7.62
10.90
14.97
17.25
23.07
26.62
5.92
8.26
9.93
14.43
14.80
18.33
22.40
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
Observed
Ret. Time Window
8.26
11.85
16.67
16.67
23.62
28.57
5.37
7.36
8.84
13.75
14.38
20.02
22.02
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
3,4,5-Trichlorophenol
DB-608
6373 9.41E-05
0.60
1.0
30
11.79 11.59 to 12.04
10.54 10.30 to 10.75
-------
EPA No. 19368
ATI No. 90-05-033-05
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
COMPOUND
2,6-Dichlorophenol
3, 5-D ichlorophenol
3, 4-D ichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4, 5-TH chloroguaiacol
5,6-Dichlorovani 1 1 in
Chlorosyringaldehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2, 4-0 ichlorophenol
2, 4, 6-Tr ichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4 , 5 , 6- T r i ch lorogua i aco I
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
3, 4, 5-Tr ichlorophenol
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
D8-608
DB-608
08-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
08-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1) Ce
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
224 1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
48060 9.41E-05
Cone . i n
Extract
(ug/ml) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05,
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
4.52
Conc/DU
Factor
(X) (3>
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) <
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
23
Observed
-DB-1 column-
Window
-DB-608 column
Observed
Ret. Time
Window
9.88
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
8.93
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
11.73 11.59 to 12.04
10.61 10.30 to 10.75
-------
EPA No. 19369
ATI No. 90-05-033-06
Sample Volume (Vs) = 100 ml
Extract Volume (Ve)
5 mL
reaK Lai ID
Quant. Area Factor
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
(A) (CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
bone . i n
Extract
Ce (ug/mL) (2)
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< o
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
.05
.05
.05
.10
.02
.05
.10
.10
.50
.02
.10
.10
.05
.05
.25
.05
.02
.05
.10
.05
.10
.05
.10
.20
.05
.02
.02
.05
lonc/uii sample -------ua-\
Factor Cone. Observed
coiuinn---- ------uo-ouo
Observed
(X) (3) Cs (ug/L) (4) Ret. Time Window Ret.
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.3
0.3
0.3
0.5
0.1
0.3
0.5
0.5
2.5
0.1
0.5
0.5
0.3
0.3
1.3
0.3
0.1
0.3
0.5
0.3
0.5
0.3
0.5
1.0
0.3
0.1
0.1
0.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
column
Time Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
22386 9.41E-05
2.11
0.1
11
11.72 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA No. 19370
ATI No. 90-05-033-07
Sample Volume (Vs) = 100 ml
COMPOUND
====ss=ss====================
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovani Uin
3,4-Dichlorocatechol
3,4,5-trichloroguaiacol
5,6-Dichlorovanillin
Ch 1 orosyr i nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Oichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trfchlorophenol
4,5-Oichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentach I oropheno I
Tetrachloroguaiacol
Tetrachlorocatechol
Quant.
Column
= == = =========:
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
s==r=s
2208
10888
6717
2456
347
980
3794
9550
8909
4765
Calib
Factor
(CF) (1)
> — ~ — — ==s— =—==
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone . i n
Extract
Ce (ug/mL) (2)
=================
< 0.05
< 0.05
< 0.05
< O.>0
< 0.02
< 0.05
< 0.10
0.49
< 0.50
< 0.02
< 0.10
< 0.10
0.72
0.41
0.40
0.05
< 0.02
0.10
< 0.10
0.38
< 0.10
< 0.05
< 0.10
< 0.20
0.97
0.52
0.35
< 0.05
Conc/DU
Factor
(X) (3)
==========
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
Extract Volume (Ve)
-OB-1 column-
5 ml
Sample
Cone. Observed
Cs (ug/L) (4) Ret. Time Window
-DB-608 column
Observed
Ret. Time
Window
0.5
0.5
0.5
1.0
0.2
0.5
1.0
4.9
5.0
0.2
1.0
1.0
7.2
4.1
4.0
0.5
0.2
1.0
1.0
3.8
1.0
0.5
1.0
2.0
9.7
5.2
3.5
0.5
14.36
21.27
22.99
26.55
3.89
8.20
9.86
18.26
21.27
22.28
5.34
6.10
7.02
7.41
9.15
10.86.
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
16.69
22.87
23.67
28.56
3.42
7.38
8.88
20.07
20.32
22.05
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trfchlorophenol
DB-608
22292 9.41E-05
2.10
0.2
21
11.72 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA No. 19371
ATI No. 90-05-033-08
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 ml
COMPOUND
2,6-Dichlorophenol
3,5-Dlchlorophenol
3,4-Dichlorophenol
5-ChloroguaiacoL
2,3,6-Trlchlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Oichlorocatechol
3,4,5-THchloroguaiacol
5,6-Diehlorovanillin
ChIorosyr i ngaIdehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-TrichLorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
feaK Lai ID
Quant. Area Factor
Column (A) (CF) (1)
DB-1 6.02E-05
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
370
559
5563
5414
795
1054
1731
700
1620
4823
1058
4926
8771
4016
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9. 14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
ionc. in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
0.03
0.44
0.52
0.18
< 0.50
0.07
< 0.10
< 0.10
< 0.05
< 0.05
0.28
< 0.05
0.07
0.16
< 0.10
0.49
< 0.10
< 0.05
0.13
0.84
0.89
0.24
< 0.02
< 0.05
Lonc/ui i
Factor
(X) (3)
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
aampie ....... — --UB-| coiumn----
Conc . Observed
Cs (ug/D (4) Ret. Time Window
< 0.5
< 0.5
< 0.5
< 1.0
0.3
4.4
5.2
1.8
< 5.0
0.7
< 1.0
< 1.0
< 0.5
< 0.5
2.8
< 0.5
0.7
1.6
< 1.0
4.9
< 1.0
< 0.5
1.3
8.4
8.9
2.4
< 0.2
< 0.5
6.38
9.43
10.85
13.71
14.38
17.18
26.57
5.92
8.22
9.87
14.93
16.18
18.26
21.27
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
.......... uo-Ouo coium
Observed
Ret. Time Window
5.26 to 5.61
5.09
9.20
11.89
14.19
16.84
16.84
28.60
5.41
7.39
8.88
14.43
16.64
20.06
20.33
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
tp
to
to
to
to
to
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
22366 9.41E-05
2.10
0.2
21
11.73 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA No. 19372
ATI No. 90-05-033-09
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 ml
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovani U in
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani 1 1 in
Chlorosyringaldehyde
3,4,5-Trichlorocatechol
Trichlorosyrfngol
2,6-Dlchlorosyringaldehyde
4-Chlorophenol
2,4-Oichlorophenol
2,4,6-Trichlorophenol
4-Chtoroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Oichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguafacol
Tetrachlorocatechol
Quant.
Column
DB-1
DB-1
OB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
D8-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Keen
Area
(A)
3504
2850
2745
3053
2096
1557
359
576
2746
1787
1330
Lai ID
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9. 14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Lone, in
Extract
Ce (ug/mL) (2)
< 0
< 0
< 0
< 0
< 0
0
0
0
< 0
< 0
< 0
< 0
< 0
0
0
< 0
0
0
< 0
0
< 0
0
0
< 0
< 0
< 0
< 0
< 0
.05
.05
.05
.10
.02
.28
.27
.61
.50
.02
.10
.10
.05
.13
.25
.05
.04
.06
.10
.28
.10
.22
.16
.20
.05
.02
.02
.05
tonc/ui i
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.
0.
0.
0.
0.
0.
0.
0.
b ample ---UB-I column- —
Cone. Observed
Cs (ug/L) (4) Ret. Time Window
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
1.4
1.4
3.0
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
0.6
1.3
< 0.3
0.2
0.3
< 0.5
1.4
< 0.5
1.1
0.8
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
10.84
13.71
14.36
14.93
23.00
26.54
5.90
8.20
9.87
14.36
14.93
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
......... .UB.OUO coiumn----
Obscrvcd
Ret. Time Window
11.89
14.19
16.67
16.67
23.69
28.61
5.39
7.38
8.88
13.79
14.40
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
3,4,5-Trichlorophenol
DB-608
36106 9.41E-05
3.40
0.1
17
11.59 to 12.04
10.30 to 10.75
-------
EPA No. 19373
ATI No. 90-05-033-10
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
mL
feaK Lai ID (.one. in uonc/uu sample --OB-I column - UD-OUO coium
Quant. Area Factor Extract Factor Cone. Observed Observed
COMPOUND Column (A) (CF) (1) Ce (ug/mL) (2) (X) (3) Cs
-------
EPA No. Blank
ATI No. 90-05-037-00
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
COMPOUND
===========================
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
Ch 1 orosy r i nga I dehyde
3,4,5-Trichtorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Oichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
3,4,5-Trichlorophenol
Quant.
Column
============
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
OB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
D8-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
====================
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
38397 9.41E-05
Cone . i n
Extract
Ce (ug/ml) (2)
sssss======s=ssss=
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
3.61
Conc/Dil
Factor
(X) (3)
Sample
Cone.
Cs (ug/L)
=======sssssssssssrssss
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
o;i
0.1
0.1
t
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
c 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
18
Observed
-OB-1 column-
Window
-08-608 column
Observed
Ret. Time
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
to 21.72
to 22.75
to 26.65
to
to
to
to
to
to
to
to
to
to
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
11.82 11.59 to 12.04
10.56 10.30 to 10.75
-------
EPA No. 19375
ATI No. 90-05-037-01
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 ml
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dlchlorophenol
5 • Ch I orogua i aco I
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3 , 5 -D i ch I orocatecho I
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
Ch 1 orosyr i nga I dehyde
3,4,5-Trichlorocatechol
Trich I orosyr ingol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguajacol
Pentachlorophenol
Tet rach I orogua i aco I
Tetrachlorocatechol
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-
DB-
DB-
DB-
DB-
DB-
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-60B
DB-608
DB-608
DB-608
DB-608'
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
Conc/Dil Sample
Factor Cone.
(X) (3) Cs (ug/L)
Observed
(4) Ret. Time
-DB-1 column-
Window
-DB-608 column
Observed
Ret. Time
Window
0.1
0.
0.
0.
0.
6.
0.
0.
0.
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.3
0.3
0.3
0.5
0.1
0.3
0.5
0.5
2.5
0.1
0,5
0.5
0.3
0.3
1.3
0.3
0.1
0.3
0.5
0.3
0.5
0.3
0.5
1.0
0.3
0.1
0.1
0.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
to 16.50
to 18.60
to 21.72
to 22.75
to 26.65
to
to
to
to
to
to
to
to
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
55048 9.41E-05
5.18
0.1
26
11.72 11.59 to 12.04
10.59 10.30 to 10.75
-------
EPA No. 19376
ATI No. 90-05-037-02
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 ml
COMPOUND
2 , 6-D i ch I oropheno I
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichlocoguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani Uin
Ch I orosyr i nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichlorosuaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentach I oropheno I
Tetrsch lorogua i acol
Tetrachlorocatechol
KeaK
Quant. Area
Column (A)
OB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
363
1723
1717
1908
2304
3573
1919
572
209
2827
1430
2495
Lai ID
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Lone . i n
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
0.29
< 0.02
< 0.05
0.17
< 0.10
0.17
0.15
0.34
< 0.10
0.13
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
0.29
< 0.10
< 0.05
< 0.10
< a. 20
< 0.05
0.08
0.18
< 0.05
Lonc/u i i
Factor
(X) (3)
0.1
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
sample UB- I column --• — - — UB-OUO column — •
Cone. Observed Observed
Cs (ug/L) (4) Ret. Time Window Ret. Time Window
< 0.3
< 0
< 0
1
< 0
< 0
0
< 0
0
0
1
< 0
0
< 0
< 1
< 0
< 0
< 0
< 0
1
< 0
< 0
< 0
< 1
< 0
0
0
< 0
.3 6.22
.3
.4 7.41
.1
.3
.8 13.72
.5
.9 14.95
.8 17.22
.7 19.73
.5
.6 21.32
.3 23.02
.3
.3
.1
.3 8.21
.5
.4 9.88
.5
.3
.5
.0
.3
.4 21.32
.9 22.30
.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49 5.18
7.45
7.86 8.40
9.66
11.44
14.14 13.96
14.79
15.59 16.96
17.62 16.96
20.17 21.95
20.71
21.76 22.72
23.49 23.62
27.05
4.06
6.07
8.43 7.26
7.57
10.11 9.01
12.95
14.45
15.04
16.50
18.60
21.72 20.26
22.75 21.95
26.65
5.26 to 5.61
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
3,4,5-Trichlorophenol
DB-608
71068 9.41E-05
6.69
0.1
33
11.73 11.59 to 12.04
10.65 10.30 to 10.75
-------
EM NO. 19377
AH No. 90-05-037-03
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 ml
COMPOUND
2,6-Dichlorophenol
3,5-Dfchlorophenol
3,4-Dfchlorophenol
5-Chloroguatacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-DichlorocatechoL
6-ChlorovanUlin
3,4-Dfchlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dlchlorovanlllfn
ChIorosyri ngaIdehyde
3,4,5-Trichlorocatechol
Trfchlorosyrlngol
2,6-Dfchlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Ofchtorocatechot
4,5,6-Trlchloroguaiacot
Pent echIoropheno t
Tatrachloroguafacol
Tetrachlorocatechol
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
OB-1
DB-1
DB-1
DB-1
OB-1
OB-1
DB-1
DB-608
DB-608
DB-608
OB-608
DB-608
DB-608
OB-608
DB-608
DB-608
DB-608
DB-608
OB-608
DB-608
rean lauo
Area Factor
(A) (CF) (1)
7,
8
536 8
853 2
6
1
16407 1
2
1
8
1
3
8
7
2
441 1
1
1
3
8102 1
8
1
1
9107 1
1
5
7
6254 8
.62E-05
.63E-05
.97E-05
.QBE -04
.40E-05
.05E-04
.20E-04
.80E-04
.13E-04
.49E-05
.18E-04
.54E-04
.37E-05
-.95E-05
.12E-04
.43E-04
.OOE-04
.01E-04
.35E-04
.01E-04
.49E-05
.24E-04
.24E-04
.70E-04
.02E-04
.86E-05
.31E-05
.26E-05
uunc . i n
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
0.18
< 0.02
< 0.05
1.97
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
0.06
< 0.02
< 0.05
< 0.10
0.82
< 0.10
< 0.05
< 0.10
1.55
< 0.05
< 0.02
< 0.02
0.52
i,onc/uii aanfiie
Factor Cone.
(X)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Observed
(3) Cs (ug/L) (4) Ret. Time
.0 <
.0 <
.0 <
.0
.0 <
.0 <
.0
.0 <
.0 <
.0 <
.0 <
.0 <
.0 <
.0 <
.0 <
.0
.0 <
.0 <
.0 <
.0
.0 <
.0 <
.0 <
.0
.0 <
.0 <
.0 <
.0
3
3
3
9
1
3
98
5
25
1
5
5
3
3
13
3
1
3
5
41
5
3
5
77
3
1
1
26
5.34
6.10
7.41 7.02
7.62 7.41
9.15
10.86
13.79 13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.91 3.88
5.80
8.10
7.25
9.93 9.74
12.51
13.99
14.56
16.27 16.02
18.08
21.16
22.21
26.26 26.08
Window
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
. 1/o-ouo cuiiam
Observed
Ret. Time Window
5.26
4.84
6.52 6.30
8.28 8.03
9.02
11.54
14.16 13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.51 3.41
5.22
7.18
8.09
8.85 8.70
13.09
13.50
14.13
16.61 16.33
19.74
19.97
21.82
27.07 26.73
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
3,4,5-Trlchlorophenol
OB-608
7782 9.41E-05
0.73
1.0
37
11.81 11.59 to 12.04
10.54 10.30 to 10.75
-------
EPA No. T9378
ATI No. 90-05-037-04
Sample Volume (Vs) = 100 ml
Extract Volume (Ve)
5 ml
COMPOUND
2 , 6-0 i ch I oropheno I
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trlchlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovani llin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani Uin
Ch I orosy r i nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4 -Chi oropheno I
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trfchlorophenol
4,5-Oichloroguaiacol
2 , 3 , 4 , 6- Tet rach I oropheno I
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-60B
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
rear. IBIID
Area Factor
(A) (CF) (1)
7
8
8
2
6
12113 1
1
2
1
2549 8
1
3
8
9909 7
1298 2
1
995 1
2698 1
3
5738 1
8
1
2136 1
1
24506 1
5
7
8
.62E-05
.63E-05
.97E-05
.08E-04
.40E-05
.05E-04
.20E-04
.80E-04
.13E-04
.49E-05
.18E-04
.54E-04
.37E-05
.95E-05
.12E-04
.43E-04
.OOE-04
.01E-04
.35E-04
.01E-04
.49E-05
.24E-04
.24E-04
.70E-04
.02E-04
.86E-05
.31E-05
.26E-05
lone, in Lunc/uii
Extract Factor
Ce (ug/mL) (2) (X) (3)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
1.27
< 0.10
< 0.10
< 0.50
0.22
< 0.10
< 0.10
< 0.05
0.79
0.28
< 0.05
0.10
0.27
< 0.10
0.58
< 0.10
< 0.05
0.26
< 0.20
2.50
< 0.02
< 0.02
< 0.05
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
aanipic uu- i coiunn
Cone. Observed
Cs (ug/L) (4) Ret. Time Window
< 3
< 3
< 3
< 5
< 1
64
< 5
< 5
< 25
11
< 5
< 5
< 3
39
14
< 3
5
14
< 5
29
< 5
< 3
13
< 10
125
< 1
e 1
< 3
5.34
6.10
7.02
7.41
9.15
10.93 10.86
13.45
14.12
14.89
17.29 16.89
19.41
19.93
21.00
23.13 22.71
26.65 26.22
3.88
5.93 5.80
8.28 8.10
7.25
9.95 9.74
12.51
13.99
14.83 14.56
16.02
18.37 18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
Observed
Ret. Time Window
5.26
4.84
6.30
8.03
9.02
11.86 11.54
13.79
16.49
16.47
16.68 16.46
21.60
23.22
22.43
23.64 23.22
28.57 28.16
3.41
5.39 5.22
7.37 7.18
8.09
8.85 8.70
13.09
13.50
14.41 14.13
16.33
20.03 19.74
19.97
21.82
26.73
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
3,4,5-Trichlorophenol
DB-608
6784 9.41E-05
0.64
1.0
32
11.82 11.59 to 12.04
10.54 10.30 to 10.75
-------
EPA No. 1?379
ATI No. 90-05-037-05
Sample Volume (Vs) = 100 ml
Extract Volume (Ve)
5 mL
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
Ch I orosy r i nga Idehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2, 6-Dichlorosyringa Idehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trlchlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenot
3,4,6-Trichtoroguaiacol
4,5-Dfchlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
3,4,5-Trichlorophenol
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
6.02E-05
3577 6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
99712 9.41E-05
Cone . i n
Extract
Ce (ug/ml) (2)
< 0.05
0.25
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
c 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
<- 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
9.38
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L)
< 0.3
1.2
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
47
Observed
-DB-1 column-
Window
-DB-608 column
Observed
Ret. Time
Window
6.25
5.34 to 5.68
6.10 to 6.49
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
4.98
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
11.79 11.59 to 12.04
10.73 10.30 to 10.75
-------
EPA No. 19380
ATI No. 90-05-037-06
Sample Volume (Vs) = 100 ml
Extract Volume (Ve)
5 tnL
neax caiio uonc. in
Quant. Area Factor Extract
Column (A) (CF) (1) Ce (ug/mL) (2)
DB-1 6.02E-05 <
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-60B
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
OB -608
6.97E-05 <
7.89E-05 <
1.66E-04 <
5.07E-05 <
7.95E-05 <
9.63E-05 <
2.22E-04 <
9.14E-05 <
6.67E-05 <
9.38E-05 <
2.35E-04 <
6.64E-05 <
6.12E-05 <
1.61E-04 <
1.43E-04 <
1.00E-04 <
1.01E-04 <
3.35E-04 <
1.01E-04 <
8.49E-05 <
1.24E-04 <
1.24E-04 <
1.70E-04 <
1.02E-04 <
5.86E-05 <
7.31E-05 <
8.26E-05 <
0.05
0.05
0.05
0.10
0.02
0.05.
0.10
0.10
0.50
0.02
0.10
0.10
0.05
0.05
0.25
0.05
0.02
0.05
0.10
0.05
0.10
0.05
0.10
0.20
0.05
0.02
0.02
0.05
Lonc/u i i
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample -uo- 1 column im-ouo uuimm
Cone. Observed Observed
Cs (ug/L) (4) Ret. Time Window Ret. Time Window
< 0.3
< 0.3
< 0
< 0
< 0
< 0
< 0
< 0
< 2
< 0
< 0
< 0
< 0
< 0
< 1
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 1
< 0
< 0
< 0
.3
.5
.1
.3
.5
.5
.5
.1
.5
.5
.3
.3
.3
.3
.1
.3
.5
.3
.5
.3
.5
.0
.3
.1
.1
< 0.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
tp
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
J,4,5-Trlchloroph«nol
DB-608
20999 9.41E-05
1.98
0.1
10
11.73 11.59 to 12.04
10.65 10.30 to 10.75
-------
ERA No. 19381
ATI No. 90-05-037-07
Sample Volume (Vs) = 100 ml
COMPOUND
2,6-Dichlorophenol
3 , 5 -D i ch I oropheno I
3 , 4 -D i ch I oropheno I
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichtorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
Chlorosyringaldehyde
3,4,5-Trichlorocatechol
T r i ch I orosyr i ngo I
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentach I oropheno I
Tetrachloroguaiacol
Tetrachlorocatechol
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
08-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
732 6.02E-05
6.97E-05
7.89E-05
1230 1.66E-04
5.07E-05
7.95E-05
3960 9.63E-05
1023 2.22E-04
2464 9.14E-05
6.67E-05
8081 9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
542 1.01E-04
3.35E-04
3886 1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in Conc/Dil Sample
Extract Factor Cone. Observed
Ce (ug/mL) (2) (X) (3) Cs (ug/L) (4) Ret. Time
Extract Volume (Ve) =
DB-1 column
Window
5 ml
-DB-608 column
Observed
Ret. Time
Window
0.05
0.05
0.05
0.20
0.02
0.05
0.38
0.23
0.23
0.02
0.76
0.10
0.05
0.05
0.25
0.05
0.02
0.05
0.10
0.39
0.10
0.05
0.10
0.20
0.05
0.02
0.02
0.05
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.5
0.5
0.5
2.0
0.2
0.5
3.8
2.3
2.3
0.2
7.6
1.0
0.5
0.5
2.5
0.5
0.2
0.5
1.0
3.9
1.0
0.5
1.0
2.0
0.5
0.2
0.2
0.5
5.51
7.53
13.69
14.26
15.16
19.70
8.20
9.87
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
5.59
8.33
11.95
14.26
16.74
21.83
7.43
8.93
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
29650 9.41E-05
2.79
0.2
28
11.73 11.59 to 12.04
10.63 10.30 to 10.75
-------
EPA No. 19382
ATI No. 90-05-037-08
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 ml
COMPOUND
2 , 6-D i ch I oropheno I
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-0 ichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanil tin
Chlorosyringaldehyde
3,4,5-THchlorocatechol
T r i ch I orosyr i ngo I
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2, 4 -Dich I oropheno I
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4, S-D ichlorocatechol
4,5,6-Trichloroguaiacol
Pent ach I oropheno I
Tet rach I orogua i aco I
Tetrachlorocatechol
Quant .
Column
OB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
08-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
reaK
Area
(A)
1731
9985
11720
797
3538
2674
6339
2687
692
1134
2339
6515
7389
12747
L3UD
Factor
-------
EPA No. 19383
ATI No. 90-05-037-09
Sample Volume (Vs) = 100 mL
Extract Volume (Ve) =
5 ml
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5 - Ch I orogua i aco I
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovani U in
3,4-Dichlorocatechol
3,4,5-Trichlorogu'aiacol
5,6-Dichlorovani llin
Ch 1 orosy r t nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentach 1 oropheno I
Tetrachloroguaiacol
Tetrachlorocatechol
Quant.
Column
DB-1
DB-1
DB-1
DB-
DB-
DB-
DB-
DB-
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
reax
Area
(A)
laiio lone, in
Factor Extract
(CF) (1) Ce (ug/mL) (2)
6.02E-05 < 0.05
6.97E-05 < 0.05
7.89E-05 < 0.05
1.66E-04 < 0.10
17134
14661
6356
4925
8674
7300
1788
1880
8465
4221
12312
11048
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
< 0
1
1
1
< 0
< 0
< 0
1
< 0
0
1
< 0
0
0
< 0
0
< 0
0
< 0
2
< 0
0
< 0
< 0
.02
.36
.41
.41
.50
.02
.10
.16
.05
.53
.18
.05
.18
.19
.10
.85
.10
.52
.10
.09
.05
.65
.02
.05
uunc/ui i
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
aampie ~"~ UD- i column uo-ouo column
Cone. Observed Observed
Cs (ug/L) (4) Ret. Time Window Ret. Time Window
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
6.8
7.1
7.1
< 2.5
< 0.1
< 0.5
5.8
< 0.3
2.7
5.9
< 0.3
0.9
0.9
< 0.5
4.3
< 0.5
2.6
< 0.5
10.5
< 0.3
3.2
< 0.1
< 0.3
10.87
13.73
14.38
26.26
23.03
26.58
5.92
8.22
9.89
14.38
16.22
21.31
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to 5.68
to 6.49
to 7.45
to 7.86
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
11.93
14.25
16.72
23.73
23.73
26.67
5.42
7.42
8.91
13.65
16.72
20.14
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
3,4,5-Trichlorophenol
DB-608
79870 9.41E-05
7.52
0.1
38
11.76 11.59 to 12.04
10.63 10.30 to 10.75
-------
NALYTICAL TECHNOLOGIES INC.
able 8 Matrix Spike Recoveries
SAS 1047
1 COMPOUND
!,6-Dichlorophenol
,5-Dichlorophenol
,4-Dichlorophenol
-Chloroquaiacol
, 3 , 6-Trichlorophenol
, 6-Dichloroguaiacol
, 5-Dichlorocatechol
-Chlorovanillin
, 4-Dichlorocatechol
, 4 , 5-Trichloroguaiacol
, 6-Dichlorovanillin
hlorosyringaldehyde
, 4 , 5-Trichlorocatechol
richlorosyringol
, 6-Dichlorosyringaldehyde
! , 6-Dichlorophenol
, 5-Dichlorophenol
, 4-Dichlorophenol
-Chloroquaiacol
, 3 , 6-Trichlorophenol
, 6-Dichloroguaiacol
, 5-Dichlorocatechol
-Chlorovanillin
, 4-Dichlorocatechol
, 4 , 5-Trichloroguaiacol
> , 6-Dichlorovanillin
hlorosyringaldehyde
, 4 , 5-Trichlorocatechol
frichlorosyringol
!, 6-DichlorosvTingaldehyde
Quanti-
titation
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1.
DB-1
DB-1
DB-l
DB-1
DB-1
DB-1
DB-1
DB-1
Spike
Cone.
ug/L
50
50
50
100
20
50
50
100
100
50
100
100
50
50
250
50
50
50
100
20
50
50
100
100
50
100
100
50
50
250
Sample
Cone.
ug/L
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
1.2
1.8
1.8
1.1
< 0.1
< 0.5
< 0.5
< 0.3
0.4
1.1
0.4
< 0.3
< 0.3
< 0.5
< o.r
10.9
< 0.5
0.5
< 2.5
0.5
< 0.5
2.0
'. 0.3
< 0.3
' 1.3
Cone.
Found
ug/L
53
49
52
100
20
52
54
81
100
22
81
85
58
52
219
49
48
55
97
20
60
51
77
100
20
83
79
51
50
199
MS
Percent
Recovery
106
98
104
100
100
102
104
79
99
44
81
85
116
103
87
VW-VJJ.-VO
Cone.
Found
ug/L
52
52
50
106
21
55
55
82
100
22
76
82
56
50
198
Sample: 90-05-033-01-
97
96
110
97
100
98
102
77
100
39
83
77
102
100
53
54
57
108
20
66
56
83
107
20
80
70
53
47
80 189
MSD
Percent
Recovery
105
105
101
106
105
111
109
82
100
45
76
82
112
100
79
107
108
114
108
102
132
112
83
107
39
80
70
106
93
75
Percent
Difference
1
6
3
6
5
6
1
1
0
1
6
4
4
4
10
9
12
4
11
2
9
9
7
7
1
4
12
3
7
5
uoiiipxc;. j\r~\jj— \j j / -\jo
,6-Dichlorophenol
,5-Dichlorophenol
,4-Dichlorophenol
-Chloroquaiacol
, 3 , 6-Trichlorophenol
, 6-Dichloroguaiacol
, 5-Dichlorocatechol
-Chlorovanillin
, 4-Dichlorocatechol
, 4 , 5-Trichloroguaiacol
, 6-Dichlorovanillin
hlorosyringaldehyde
, 4 , 5-Trichlorocatechol
richlorosyringol
, 6-DicMorosyringaldehyde
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
50
50
50
100
20
50
50
100
100
50
100
100
50
50
250
< 0.3
' 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
'. 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
51
50
49
100
20
50
51
83
102
20
79
82
51
48
206
102
100
98
100
100
100
102
83
102
40
79
82
102
%
82
49
51
48
98
19
51
49
77
96
20
78
73
48
48
195
99
101
98
95
102
98
77
39
78
73
95
78
3
1
2
2
5
2
4
8
6
2
1
12
7
0
5
-------
ALYTICAL TECHNOLOGIES INC
SAS 1047
ble 9 Run Chronology (continued)
Date
Sample Received
d A 1:4 Calibr. Verification N/A
d B 1:4 Calibr. Verification N/A
-05-033-10 (100:0.5cnL) 05-18-90
-05-037-01 (100:0.5mL) 05-19-90
KJ5-037-02 (100:0.5mL) 05-19-90
KJ5-037-05 (100:0.5mL) 05-19-90
1-05-037-06 (100:0.5mL) 05-19-90
K)5-037-07 (100: ImL) 05-19-90
KJ5-037-08 (100: ImL) 05-19-90
K55-037-09 (100:0.5mL) 05-19-90
d A 1:4 Calibr. Verification N/A
d B 1:4 Calibr. Verification N/A
libration std A High, curve 3 N/A
libration std A 1:2, curve 3 N/A
libration std A 1:4, curve 3 N/A
libration std A 1:20, curve 3 N/A
libration std B High, curve 3 N/A
libration std B 1:2, curve 3 N/A
libration std B 1:4, curve 3 N/A
libration std B 1:20, curve 3 N/A
ank N/A
-05-031-08MS A (100:5roL) 05-17-90
-05-033-OU1S A (100:5mL) 05-18-90
-05-037-06MS A (100: 5mL) 05-19-90
libration std A High (2.5:1) N/A.
libration std B High (2.5:1) N/A
3 A 1:4 Calibr. Verification N/A
I B 1:4 Calibr. Verification N/A
Libration std A High, curve 4 N/A
Libration std A 1:2, curve 4 N/A
Libration std A 1:4, curve 4 N/A
Libration std A 1:20, curve 4 N/A
Libration std B High, curve 4 N/A
Libration std B 1:2, curve 4 N/A
Libration std B 1:4, curve 4 N/A
Libration std B 1:20, curve 4 N/A
aik N/A
-05-031-08MSD A (100:5cnL) 05-17-90
•05-033-01MSD A (100: 5mL) 05-18-90
-05-037-06MSD A (100:5mL) 05-19-90
1 A 1:4 Calibr. Verification N/A
1 B 1:4 Calibr. Verification N/A
Date
Extracted
05-25-90
05-25-90
05-21-90
05-29-90
05-29-90
05-29-90
05-29-90
05-29-90
05-29-90
05-29-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
06-12-90
06-12-90
06-12-90
06-12-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
06-22-90
06-22-90
06-22-90
06-22-90
05-25-90
05-25-90
Column: DB-1
Date Time
Analyzed
06-10-90
06-10-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-25-90
06-25-90
22:53
23:29
00:06
00:42
01:19
01:55
02:32
03:08
03:44
04:23
05:34
06:11
17:55
18:32
19:10
19:47
20:24
21:01
21:39
22:16
22:53
00:08
00:45
01:22
04:28
05:05
05:43
06:20
13:36
14:13
14:51
15:28
16:05
16:42
17:20
17:57
18:34
19:49
20:26
21:03
00:09
00:46
Column: DB-608
Date Time
Analyzed
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-25-90
05:38
06:15
06:52
07:29
08:34
10:56
11:34
12:10
12:47
13:23
15:44
16:23
17:10
17:55
18:32
19:10
19:47
20:24
21:01
21:39
22:16
23:30
00:08
00:45
03:51
04:28
05:05
05:43
12:54
13:36
14:13
14:51
15:28
16:05
16:42
17:20
17:57
19:11
19:49
20:26
23:32
00:09
-------
ilytical Technologies, Inc.
SAS 1047
>le 10 Calibration Data Curve 1 (continued)
Compound
5-dichlorovanillin
.orosyringealdehyde
4 , 5-trichlorocatechol
ichlorosyringol
6-dichlorosyringaldehyde
4 , 5-trichlorophenol
chlorophenol
-
4-dichlorophenol
4,6-trichlorophenol
chloroguaiacol
Cone
(ug/mL)
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
10.00
5.00
2.50
0.50
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
Peak
Area
33439
16806
8360
1737
12283
5589
2639
523
23962
11983
5874
1208
24468
12845
6301
1262
45598
24045
11872
2395
19710
11170
5211
1120
13688
7282
3644
668
8258
4392
2135
337
18614
10631
5250
924
12659
6804
3317
466
-UB-OUO
Mean %RSD of
Calib Calib Calib
Factor Factor Factors
1.20E-04 1.18E-04
1.19E-04
1.20E-04
1.15E-04
3.26E-04 3.54E-04
3.58E-04
3.79E-04
8.35E-05 8.37E-05
8.35E-05
8.51E-05
8.28E-05
8.17E-05 7.95E-05
7.79E-05
7.94E-05
7.92E-05
2.19E-04 2.12E-04
2.08E-04
2.11E-04
2.09E-04
1.85E-04 9.41E-05
2.12E-04
2.57E-04
4.15E-04
1.46E-04 1.43E-04
1.37E-04
1.37E-04
1.50E-04
9.69E-05 l.OOE-04
9.11E-05
9.37E-05
1.19E-04
1.07E-04 1.01E-04
9.41E-05
9.52E-05
1.08E-04
3.16E-04 3.35E-04
2.94E-04
3.01E-04
4.29E-04
1.6
6.2
1.0
1.8
2.1
5.4
3.8
10.9
6.5
16.4
-------
fclytical Technologies, Inc.
SAS 1047
Die 10 Calibration Data Curve 3 (continued)
Ctampound
5-dichlorovanillin
Lorosyringealdehvde
1 , 5-trichlorocatechol
Lchlorosyringol
5-dichlorosyringaldehyde
5,5-trichlorophenol
:hlorophenol
1-dichlorophenol
1,6-trichlorophenol
Moroguaiacol
Cone
(ug/mL)
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
10.00
5.00
2.50
0.50
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
Peak
Area
51224
24726
13192
2698
18660
8587
4748
944
34558
16108
8647
1801
37624
18320
9755
2167
68510
32484
17633
3727
23249
11866
6598
1322
17999
9026
4797
940
10722
5471
2823
590
25442
13257
6961
1481
16907
8851
4634
977
UB-WO
Mean
Calib CaliJ)
Factor • Factor
7.81E-05 7.72E-05
8.09E-05
7.58E-05
7.41E-05
2.14E-04 2.19E-04
2.33E-04
2.11E-04
5.79E-05 5.83E-05
6.21E-05
5.78E-05
5.55E-05
5.32E-05 5.13E-05
5.46E-05
5.13E-05
4.61E-05
1.46E-04 1.44E-04
1.54E-04
1.42E-04
1.34E-04
8.60E-05 9.41E-05
8.43E-05
7.58E-05
7.56E-05
1.11E-04 1.08E-04
1.11E-04
1.04E-04
1.06E-04
7.46E-05 7.16E-05
7.31E-05
7.08E-05
6178E-05
7.86E-05 7.33E-05
7.54E-05
7.18E-05
6.75E-05
2.37E-04 2.21E-04
2.26E-04
2.16E-04
2.05E-04
3.3
4.4
4.1
6.2
5.0
5.4
2.7
3.6
5.6
5.4
-------
jalytical Technologies, Inc.
SAS 1047
able 10 Calibration Data Curve 4
Compound
, 6-dichlorophenol
, 5-dichlorophenol
,4-dichlorophenol
-chloroguaiacol
, 3 , 6-t richlorophenol
, 6-dichloroguaiacol
, 5-dichlorocatechol
-chlorovanillin
,4-dichlorocatechol
, 4 , 5-trichloroguaiacol
Cone
(ug/mL)
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
Peak
Area
13493
6711
3198
588
11924
5931
2818
494
11360
5574
2698
488
10391
4935
2469
380
6962
3409
1636
303
10431
5157
2449
446
9183
4310
2143
388
7788
3744
1841
320
18120
8812
4307
883
5726
2689
1479
257
1JB-1-
Mean %RSD of
Calib Calib Calib
Factor Factor Factors
1.48E-04 1.56E-04
1.49E-04
1.56E-04
1.70E-04
1.68E-04 1.79E-04
1.69E-04
1.77E-04
2.02E-04
1.76E-04 1.86E-04
1.79E-04
1.85E-04
2.05E-04
3.85E-04 4.30E-04
4.05E-04
4.05E-04
5.26E-04
1.15E-04 1.22E-04
1.17E-04
1.22E-04
1.32E-04
1.92E-04 2.04E-04
1.94E-04
2.04E-04
2.24E-04
2.18E-04 2.35E-04
2.32E-04
2.33E-04
2.58E-04
5.14E-04 5.54E-04
5.34E-04
5.43E-04
6.25E-04
2.21E-04 2.27E-04
2.27E-04
2.32E-04
2.27E-04
1.40E-04 1.45E-04
1.49E-04
1.35E-04
1.56E-04
5.6
7.8
6.0
13.0
5.4
6.3
6.1
7.6
1.8
5.5
-------
}ralytical Technologies, Inc.
SAS 1047
(able 10 Calibration Data Curve 4 (continued)
Compound
i, 6-dichlorovanillin
tilorosyringealdehyde
, 4 , 5-trichlorocatechol
richlorosyringol
, 6-dichlorosyringaldehyde
, 4 , 5-trichlorophenol
-chlorophenol
,4-dichlorophenol
, 4 , 6-trichlorophenol
-chloroguaiacol
Cone
(ug/mL)
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
10.00
5.00
2.50
0.50
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
Peak
Area
18023
8498
4211
865
6746
3107
1427
364
12702
5872
2895
571
14112
6510
3215
721
24816
11824
5737
1184
8696
4354
2245
373
5867
3075
1637
311
3468
1832
980
152
8172
4303
2285
450
5552
3011
1505
192
uo-j. —
Mean %RSD of
Calib Calib Calib
Factor Factor Factors
2.22E-04 2.31E-04
2.35E-04
2.37E-04
2.31E-04
5.93E-04 6.46E-04
6.44E-04
7.01E-04
1.57E-04 1.69E-04
1.70E-04
1.73E-04
1.75E-04
1.42E-04 1.47E-04
1.54E-04
1.56E-04
1.39E-04
4.03E-04 4.21E-04
4.23E-04
4.36E-04
4.22E-04
2.30E-04 2.38E-04
2.30E-04
2.23E-04
2.68E-04
3.41E-04 3.23E-04
3.25E-04
3.05E-04
3.22E-04
2.31E-04 2.29E-04
2.18E-04
2.04E-04
2.63E-04
2.45E-04 2.30E-04
2.32E-04
2.19E-04
2.22E-04
7.20E-04 7.73E-04
6.64E-04
6.64E-04
1.04E-03
2.6
6.8
4.0
4.9
2.8
7.5
3.9
9.5
4.4
20.3
-------
[nalytical Technologies, Inc.
SAS 1047
fable 10 Calibration Data Curve 4 (continued)
Compound
1,4, 5-trichlorophenol
1 , 5-dichloroguaiacol
! , 3 , 4 , 6-tetrachlorophenol
, 4 , 6-trichloroguaiacol
, 5-dichlorocatechol
, 5 , 6-trichloroguaiacol
entachlorophenol
etrachloroguaiacol
etrachlorocatechol
Cone
(ug/mL)
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
0.40
0.20
0.10
0.02
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
Peak
Area
8515
4490
2386
511
10439
5354
2682
594
7073
3268
1574
314
7031
3367
1651
363
10606
5399
2894
534
3500
1661
752
168
2968
1519
631
174
4441
2470
1046
196
9753
4975
2280
388
UB-bUB
Mean %RSD of
Calib Calib Calib
Factor Factor Factors
2.35E-04 2.16E-04
2.23E-04
2.10E-04
1.96E-04
1.92E-04 1.83E-04
1.87E-04
1.86E-04
1.68E-04
2.83E-04 3.06E-04
3.06E-04
3.18E-04
3.18E-04
2.84E-04 2.90E-04
2.97E-04
3.03E-04
2.75E-04
3.77E-04 3.67E-04
3.70E-04
3.46E-04
3.75E-04
2.29E-04 2.43E-04
2.41E-04
2.66E-04
2.38E-04
1.35E-04 1.35E-04
1.32E-04
1.58E-04
1.15E-04
1.80E-04 1.84E-04
1.62E-04
1.91E-04
2.04E-04
2.05E-04 2.21E-04
2.01E-04
2.19E-04
2.58E-04
6.8
4.8
4.7
3.7
3.4
5.7
11.5
8.4
10.1
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INALYTICAL TECHNOLDGIES INC.
table 11 Calibration Verification
SAS 1047
COMPOUND
. MKA
,6-Dichlorophenol
,5-Dichlorophenol
, 4-Dichlorophenol
-Chloroguaiaool
1,3, 6-Trichlorophenol
, 6-Dichloroguaiaool
, 4, 5-Triclilorophenol
, 5-Dichlorocatechol
i-Chlorovanillin
1 , 4-Dichlorocatechol
1,4, 5-Tridiloroguaiacol
> , 6-Dichlorovanillin
hlorosyringaldehyde
! , 4 , 5-Trichlorocatechol
Yichlorosyringol
i , 6-Dichlorosyringaldehyde
MKB
l-Chlorophenol
! , 4-Dichlorophenol
! , 4, 6-Trichlorophenol
1-Chloroguaiacol
1 , 4 , 5-Trichlorophenol
1 , 5-Dichloroguaiacol
! , 3 , 4 , 6-Tetrachlorophenol
5,4, 6-Trichloroguaiacol
I , 5-Dichlorocatecnol
1,5,6-Trichloroguaiacol
'entachlorophenol
Petrachloroguaiacol
Tetrachlorocatechol
Quanti-
fication —
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608 .
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
1
18
22
23
19
26
24
5
25
25
18
34
23
19
25
22
22
2
1
4
13
6
5
6
2
6
5
4
0
12
2
21
25
23
21
27
23
7
27
27
22
33
25
20
25
23
24
9
12
12
16
14
10
3
6
13
6
5
1
21
—Percent
3
9
9
10
4
10
14
15
14
12
11
19
9
10
16
8
9
14
20
20
28
24
27
19
9
9
6
0
5
4
Deviatia
4
9
18
20
24
20
14
17
15
20
15
21
16
10
12
13
8
15
13
9
11
9
17
13
18
6
6
24
25
3
5
10
16
20
19
14
15
33
16
19
13
21
16
10
5
11
7
14
10
7
7
8
9
4
7
6
10
14
16
5
6
10
16
20
19
14
15
15
16
19
13
21
16
10
5
11
7
15
25
26
36
30
26
15
21
19
20
13
14
7
7
11
12
7
8
5.
10
7
1
5
4
5
3
2
4
7
5
10
10
11
8
10
18
4
7
0
13
4
11
3
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