-------
ANALYTICAL TECHNOLOGIES INC.
EPA No. 1*9358
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani 1 1 in
Ch 1 orosyri nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tet rach I orogua i aco I
Tetrachlorocatechol
3,4,5-Trichlorophenol
TABLE 3 and TABLE 4: QUANTIFICATIONS AND ID
ATI No. 90-05-031-04 Sample Volume (Vs) = 100 ml
Peak Calib Cone, in Cone/Oil Sample
Quant. Area Factor Extract Factor Cone.
Column (A) (1) Ce (ug/mL) (2) (X) (3) Cs (ug/L) (4)
DB-
DB-
DB-
DB-
DB-
DB-
DB-
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
33139 9.41E-05
< -0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
<• 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< o;os
« 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
3.12
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
t 0.5
< 0.5
< 2.5
< 0.1
< 0.5
'< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
c 0.5
< 0.3
< ' 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
16
ENTIFICATIONS
Extract
_|\Q_ 1
Observed
Ret. Time u
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
11.85 11.59
Volur
col
indo
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
ne (Ve) =
rf
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
12.04
SAS 1047
5 ml
Observed
Ret. Time V
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
10.59 10.30
t
column
ffndow
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
10.75
-------
ANALYTICAL TECHNOLOGIES INC.
EPA No. {9359
TABLE 3 and TABLE 4: QUANTIFICATIONS AND ID
ATI No. 90-05-031-05 Sample Volume (Vs) * 100 ml
Peak Calib Cone, in Cone/Oil Sample
Quant. Area Factor Extract Factor Cone.
COMPOUND Column (A) (CF) (1) Ce (ug/mL) (2) (X) (3) Cs (ug/L) (4)
2,6-Oichlorophenol DB-1 7.62E-05 < 0.05 0.1 < 0.3
3,5-Dichlorophenol
3,4-Oichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichtoroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3 , 4-D i ch lorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani 1 1 in
Chi orosyr i nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4 , 5 - D i ch I orogua i aco I
2,3,4,6-Tetrachlorophenol
3,4,6- Trichloroguaiacol
4, 5-0 ich lorocatechol
4,5,6-Trichloroguaiacol
Pentach I oropheno I
Tetrach 1 orogua i acol
Tetrach I orocatechol
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
. DB-
08-
DB-
08-
DB-
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1 .43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
c 0.02
< 0.02
< 0.05
0.1 «
0.1 <
0.1 <
0.1 <
0.1 <
0.1- <
0.1 <
0.1 <
0.1 <
0.1 .<
0.1 <
0.1 <
0.1 <
0.1 <
0.1 e
0.1 <
0.1 <
0.1 <
0.1 < .
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.3
0.3
0.5
0.1
0.3
0.5
0.5
2.5
0.1
0.5
0.5
0.3
0.3
1.3
0.3
0.1
0.3
0.5
0.3
0.5
0.3
0.5
1.0
0.3
0.1
0.1
0.3
ENTIFICATIONS
Extract \
Observed
/olu
col
no (Vo) -
SAS 104'
5 ml
Observed
Ret. Time Window Ret.
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
r
column----
Time Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
33507 9.41E-05
3.15
0.1
16
11.83 11.59 to 12.04
10.56 10.30 to 10.75
-------
ANALYTICAL TECHNOLOGIES INC.
TABLE 3 and TABLE 4: QUANTIFICATIONS AND IDENTIFICATIONS
SAS 1047
EPA No. T9360
ATI No. 90-05-031-06
Sample Volume (Vs) = 100 ml
Extract Volume (Ve)
5 ml
Quant .
i-ean V.BIID
Area Factor
COMPOUND Column (A) (CF) (1)
2,6-Dichlorophenol DB-1 7.62E-05
3,5-Dichlorophenol
3,4-Dlchlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3 ,4-0 i ch lorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
Chlorosyringaldehyde
3,4,5-THchlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Oichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pent ach I oropheno I
Tet rach I orogua i aco I
Tet rach I oroca techo I
DB-1
DB-1
DB-1
D8-1
DB-1
DB-1
DB-1
DB-
08-
DB-
08-
08-
08-
08-
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
08-608
DB-608
08-608
8.63E-05
8.97E-05
2.08E-04
325 6.40E-05
5435 LOSE -04
1.20E-04
1005 2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
3270 7.95E-05
1983 2.12E-04
1.43E-04
1.00E-04
1400 1.01E-04
3.35E-04
4417 1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
11711 1.02E-04
5.86E-05
7.31E-05
8.26E-05
Lone . i n
Extract
Ce (ug/mL) (2)
< -0.05
< 0.05
< 0.05
< 0.10
0.02
0.57
< 0.10
0.28
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
0.26
0.42
< 0.05
< 0.02
0.14
< 0.10
0.45
< 0.10
< 0.05
< 0.10
< 0.20
1.19
< 0.02
< 0.02
< 0.05
uonc/ui i
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.
0.
0.
0.
0.
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
sample
Cone.
- uo- 1
Observed
column--- •
no- ouo column- •••
Observed
Cs (ug/L) (4) Ret. Time Window Ret. Time Window
< 0.3 5.34 to 5.68 5.26 to 5.61
< 0.3
c 0.3
< 0.5
0.1
2.9
< 0.5
1.4
< 2.5
< 0.1
< 0.5
'< 0.5
< 0.3
1.3
2.1
< 0.3
< 0.1
0.7
< 0.5
2.2
<' 0.5
< 0.3
< 0.5
< 1.0
6.0
< 0.1
< 0.1
< 0.3
6.10
7.02
7.41
9.50 9.15
10.97 10.86
13.45
14.50 14.12
14.89
16.89
19.41
19.93
21.00
23.14 22.71
26.70 26.22
3.88
5.80
8.32 8.10
7.25
9.97 9.74
12.51
13.99
14.56
16.02
18.42 18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
4.84
6.30
8.03
9.50 9.02
11.88 11.54
13.79
16.71 16.49
16.47
16.46
21.60
23.22
22.43
23.66 23.22
28.58 28.16
3.41
5.22
7.38 7.18
8.09
8.86 8.70
13.09
13.50
14.13
16.33
20.05 19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-THchlorophenol
DB-608
27246 9.41E-05
2.56
0.1
13
11.83 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA Wo. 1V361
ATI No. 90-05-031-07
Sample Volume (Vs) - 100 ml
Extract Volume (Ve) =
5 mL
redK uai i u
Quant. Area Factor
COMPOUND Column (A) (CF) (1)
2,6-Oichlorophenol DB-1 7.62E-05
3,5-Dichlorophenol DB-1 8.63E-OS
3,4-Dichlorophenol DB-1 8.97E-05
5 - Ch I orogua i aco I
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-DichLorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani Uin
Ch I orosyr i nga Idehyde
3,4,5-Trichlorocatechol
T r i ch t orosyr i ngo I
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4 - Ch I orogua i aco I
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrach I orocatechol
3,4,5-Trichtorophenol
DB-1
DB-1
DB-1
DB-1
DB-1
DB-
DB-
DB-
D8-
DB-
DB-
DB-1
DB-608
OB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
445
5482
7549
289
2456
450
2754
1277
2243
5400
7093
9078
5539
23287
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
9.41E-05
lone . i n
Extract
Ce (ug/mL) (2)
< 0
< 0
< 0
< 0
0
0
0
< 0
0
< 0
< 0
0
< 0
0
0
< 0
< 0
0
< 0
0
< 0
< 0
< 0
1
0
0
< 0
< 0
2
.05
.05
.05
.10
.03
.58
.91 '
.10
.28
.02
.10
.16
.05
.22
.27
.05
.02
.23
.10
.55
.10
.05
.10
.21
.93
.32
.02
.05
.19
Lonu/ui i
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.
0.
0.
0.
0.
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
aainpie .... uo- i coiunwi
Cone. Observed
Cs (ug/L) (4) Ret. Time Window
< 0.3
< 0.3
< 0.3
< 0.5
0.1
2.9
4.5
< 0.5
1.4
< 0.1
< 0.5
0.8
< 0.3
1.1
1.4
< 0.3
< 0.1
1.1
< 0.5
2.7
< 0.5
< 0.3
< 0.5
6.0
4.6
1.6.
< 0.1
< 0.3
11
9.53
10.97
13.82
14.49
15.28
20.37
23.15
26.82
8.32
9.97
18.42
11.83
5.34
6.10
7.02
7.41
9.15
10.66
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
11.59
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
12.04
-UD-OUO tUlUIII
Observed
Ret. Time Window
9.20
11.87
14.18
16.84
16.84
23.66
23.66
28.58
7.38
8.86
20.05
10.57
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
10.30
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
to 10.75
-------
EPA.No. 19362
ATI No. 90-05-031-08
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
COMPOUND
===========================
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichtorophenol
5 -Chi orogua iacot
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovani llin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
Ch 1 orosyr i nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyn'ngol
2,6-Dfchlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4 , 5 -D i ch I orogua i aco I
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5'Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrach I orogua iacol
Tetrachlorocatechol
3,4,5-TMchlorophenol
Quant .
Column
============
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
D8-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
=========
569
2987
3680
1610
2486
1461
1401
184
334
2207
2342
2997
2183
823
20492
Calib
Factor
(CF) (1)
:==========£
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
9.41E-05
Cone . i n
Extract
Ce (ug/mL) (2)
==================
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
0.24
0.35 '
0.36
0.23
< 0.02
< 0.10
< 0.10
< 0.05
0.09
0.23
< 0.05
0.02
< 0.05
< 0.10
0.22
< 0.10
< 0.05
0.29
0.51
0.22
< 0.02
< 0.02
0.07
1.93
Conc/Oi I
Factor
(X) (3)
==========:
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
-OB-1 column-
Sample
Cone. Observed
Cs (ug/L) (4) Ret. Time Window
-DB-608 column
Observed
Ret. Time
Window
0.3
0.3
0.3
0.5
0.1
1.2
1.8
1.8
1.1
0.1
0.5
0.5
0.3
0.4
1.1
0.3
0.1
0.3
0.5
1.1
0.5
0.3
1.5
2.5
1.1
0.1
0.1
0.3
10
5.53
10.85
13.71
14.38
14.93
23.01
26.72
5.89
8.22
9.88
14.93
16.20
18.27
26.34
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
5.39
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
to 22.75
to 26.65
to
to
to
to
to
to
to
to
to
to
to
11.88
14.18
16.64
16.64
23.67
28.59
5.39
7.38
8.86
14.18
16.64
20.05
27.18
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
11.72 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA No. Blank
ATI No. 90-05-033-00
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
Quant.
reaK lauo
Area Factor
Column (A) (CF) (1)
DB-1 7.62E-05
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
8
8
2
6
1
1
2
1
8
1
3
8
.63E-05
.97E-05
.08E-04
.40E-05
.05E-04
.20E-04
.80E-04
.13E-04
.49E-05
.18E-04
.54E-04
.37E-05
7.95E-05
2
1
1
1
3
1
8
1
1
1
1
5
7
8
.12E-04
.43E-04
.OOE-04
.01E-04
.35E-04
.01E-04
.49E-05
.24E-04
.24E-04
.70E-04
.02E-04
.86E-05
.31E-05
.26E-05
Lone . i n
Extract
i.onc/ui i
Factor
sample ........... -uo- t column--- -
Conc. Observed
Ce (ug/mL) (2) (X) (3) Cs (ug/L) (4) Ret. Time Window
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
« 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
< 0.3
< 0.3
< 0.3
< 0.5
e 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1 .
< 0.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
UB-OUO column
Observed
Ret. Time Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to.
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49.
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
49569 9.41E-05
4.66
0.1
23
11.84 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA No. 19364
ATI No. 90-05-033-01
Sample Volune (Vs) = 100 mL
Extract Volune (Ve) =
5 mL
COMPOUND
2,6-Dichlorophenol
3 ,5-01 chlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2, 3, 6-TH chlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocetechol
6-Chlorovani llin
3,4-Dlchlorocatechol
3,4,5-THchloroguaiacol
5,6-Dichlorovani Uin
Ch I orosy r i nga I dehyde
3,4,5-THchlorocatechol
THchlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-D)chlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2 , 4 , 5 - T r i ch I orophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3 , 4 , 6- T r i ch I orogua i aco I
4,5-Dlchlorocetechol
4,5,6-THchloroguaiacol
Pantachlorophanol
Tctrachloroguaiacol
Tatrachlorocetochot
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
OB -608
DB-608
08-608
DB-608
DB-608
DB-608
DB-608
reaK Lai ID
Area Factor
Lone, in
Extract
LOOC/UI i
Factor
sample un- i coium
Cone. Observed
(A) (CF) (1) Ce (ug/mL) (2) (X) (3) Cs (ug/L) (4) Ret. Time Window
1366 6.02E-05
352 6.97E-05
7
1
5
27412 7
9
464 2
9
1558 6
9
1695 2
6
6
1
1
1
1129 1
3
1286 1
8
1
1
1
2581 1
5
7
8
.89E-05
.66E-04
.07E-05
.95E-05
.63E-05
.22E-04
.14E-05
.67E-05
.38E-05
.35E-04
.64E-05
.12E-05
.61E-04
.43E-04
.OOE-04
.01E-04
.35E-04
.01E-04
.49E-05
.24E-04
.24E-04
.70E-04
.026-04
.86E-05
.31E-05
.26E-05
0.08
< 0.05
< 0.05
< 0.10
< 0.02
2.18
< 0.10
0.10
< 0.50
0.10
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
0.11
< 0.10
0.13
< 0.10
< 0.05
< 0.10
< 0.20
0.26
< 0.02
< 0.02
< 0.05
0.1 0.4 5.48
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
< 0.
< 0.
< 0.
< 0.
10.
< 0.
0.
< 2.
0.
< 0.
< 0.
< 0.
< 0.
< 1.
< 0.
< 0.
3 6.19
3
5
1
9 10.85
5
5 14.38
5
5 17.20
5
5 20.25
3
3
3
3
1
0.6 8.82
c 0.5
0.6 9.89
< 0.
5
< 0.3
< 0.5
< 1.0
1.3 18.29
< 0.1
< 0.1
< 0.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to 5.68
to 6.49
to 7.45
to 7.86
to 9.66
to 11.44
to 14.14
to 14.79
to 15.59
to 17.62
to 20.17
to 20.71
to 21.76
to 23.49
to 27.05
to 4.06
to 6.07
to 8.43
to 7.57
to 10.11
to 12.95
to 14.45
to 15.04
to 16.50
to 18.60
to 21.72
to 22.75
to 26.65
UB-OUO
Observed
cuiuwi----
Ret. Time Window
5.42 5.26
5.10 4.84
6.30
8.03
9.02
11.88 11.54
13.79
16.76 16.49
16.47
16.76 16.46
21.60
23.66 23.22
22.43
23.22
28.16
3.41
5.22
7.38 7.18
8.09
8.87 8.70
13.09
13.50
14.13
16.33
20.05 19.74
19.97
21.82
26.73
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
J,4,5-Irlchtorophanol
DB-608
38993 9.4U-05
3.67
0.1
18
11.73 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA'No. 19365
ATI No. 90-05-033-02
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
D8-608
DB-608
DB-608
DB-608
DB-608
DB-608
reaK laiio lone, in
Area Factor Extract
(A)
-------
EPA.No. 19366
ATI No. 90-05-033-03
Sample Volume (Vs) = 100 ml
Extract Volume (Ve)
5 ml
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovenillin
3,4-D1chlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani11 in
ChIorosyr i ngaIdehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trfchlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
PentachIorophenoI
Tetrachlorogualacol
Tatrachlorocatechol
3,4,5-Trichlorophenol
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-
DB-
08-
DB-
DB-
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
OB -60S
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
3519
11231
1100
565
1118
5111
7181
4813
6024
Calib
Factor
(CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
9.41E-05
tone . i n
Extract
Ce (ug/mL) (2)
0.27
< 0.05
< 0.05
< 0.10
< 0
< 0
1
0
< 0
0
< 0
< 0
< 0
< 0
0
< 0
< 0
< 0
< 0
0
< 0
< 0
< 0
1
< 0
< 0
< 0
0
0
.02
.05
.35 '
.31
.50
.05
.10
.10
.05
.05
.24
.05
.02
.05
.10
.52
.10
.05
.10
.22
.05
.02
.02.
.40
.57
Lonc/ui i
Factor
(X) (3)
1.0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
sample
Cone . Observed
uo- i
column- •-•
Cs (ug/L) (4) Ret. Time Window
13 5.55
< 3
< 3
< 5
< 1
< 3
67 13.76
15 14.43
< 25
2 17.25
< 5
< 5
< 3
< 3
12 26.77
< 3
< 1
< 3
< 5
26 9.91
< 5
< 3
< 5
61 16.25
< 3
< 1 .
< 1
20 26.22
28 11.78
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
11.59
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
12.04
Observed
Ret. Time Window
'"2S- — — SB3 — S3SSSSSSS3;:"" «•"••••"•«"
5.53 5.26 to
4.
6.
8.
84
30
03
9.02
11.
14.14 13.
16.84 16.
16.
16.84 16.
21.
23.
22.
23.
28.57 28.
3.
5.
7.
54
79
49
47
46
60
22
43
22
16
41
22
18
8.09
8.83 8.70
13.09
13.50
14.13
16.59 16.33
19.74
19.97
21.82
27.04 26.73
10.53 10.30
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
10.75
-------
EPA.No. 19367
ATI No. 90-05-033-04
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
ChIorosyr i ngaIdehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
P63K
Quant. Area
Column (A)
DB-1
OB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
OB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-60B
DB-608
DB-608
DB-608
DB-608
DB-608
693
12409
1242
1325
11332
4302
735
2257
5636
2731
2502
28289
2252
Lai ID
Factor
(CF) (1)
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Lone . i n
Extract
Ce (ug/mL) (2)
< 0
< 0
< 0
0
< 0
1
< 0
< 0
< 0
0
< 0
< 0
< 0
0
0
< 0
0
0
< 0
0
< 0
0
0
< 0
2
< 0
0
< 0
.05
.05
.05
.14
.02
.30
.10-
.10
.50
.11
.10
.10
.05
.90 .
.91
.05
.07
.23
.10
.57
.10
.34
.31
.20
.89
.02
.16
.05
lonc/ui i
Factor
(X) (3)
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
.0
.0
.0
.0
.0
.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
a ample -• UD- i coium — -
Cone. Observed
Cs (ug/L) (4) Ret. Time Window
< 3
< 3
< 3
7
< 1
65
< 5
< 5
< 25
6
< 5
< 5
< 3
45
46
< 3
4
11
< 5
28
< 5
17
16
< 10
144
< 1
a'
< 3
5.34 to
6.10 to
7.62
10.90
14.97
17.25
23.07
26.62
5.92
8.26
9.93
14.43
14.80
18.33
22.40
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
Observed
Ret. Time Window
8.26
11.85
16.67
16.67
23.62
28.57
5.37
7.36
8.84
13.75
14.38
20.02
22.02
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
3,4,5-Trichlorophenol
DB-608
6373 9.41E-05
0.60
1.0
30
11.79 11.59 to 12.04
10.54 10.30 to 10.75
-------
EPA No. 19368
ATI No. 90-05-033-05
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
COMPOUND
2,6-Dichlorophenol
3, 5-D ichlorophenol
3, 4-D ichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4, 5-TH chloroguaiacol
5,6-Dichlorovani 1 1 in
Chlorosyringaldehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2, 4-0 ichlorophenol
2, 4, 6-Tr ichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4 , 5 , 6- T r i ch lorogua i aco I
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
3, 4, 5-Tr ichlorophenol
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
D8-608
DB-608
08-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
08-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1) Ce
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
224 1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
48060 9.41E-05
Cone . i n
Extract
(ug/ml) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05,
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
4.52
Conc/DU
Factor
(X) (3>
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L) <
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
23
Observed
-DB-1 column-
Window
-DB-608 column
Observed
Ret. Time
Window
9.88
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
8.93
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
11.73 11.59 to 12.04
10.61 10.30 to 10.75
-------
EPA No. 19369
ATI No. 90-05-033-06
Sample Volume (Vs) = 100 ml
Extract Volume (Ve)
5 mL
reaK Lai ID
Quant. Area Factor
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
(A) (CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
bone . i n
Extract
Ce (ug/mL) (2)
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< o
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
.05
.05
.05
.10
.02
.05
.10
.10
.50
.02
.10
.10
.05
.05
.25
.05
.02
.05
.10
.05
.10
.05
.10
.20
.05
.02
.02
.05
lonc/uii sample -------ua-\
Factor Cone. Observed
coiuinn---- ------uo-ouo
Observed
(X) (3) Cs (ug/L) (4) Ret. Time Window Ret.
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.1 <
0.3
0.3
0.3
0.5
0.1
0.3
0.5
0.5
2.5
0.1
0.5
0.5
0.3
0.3
1.3
0.3
0.1
0.3
0.5
0.3
0.5
0.3
0.5
1.0
0.3
0.1
0.1
0.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
column
Time Window
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
22386 9.41E-05
2.11
0.1
11
11.72 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA No. 19370
ATI No. 90-05-033-07
Sample Volume (Vs) = 100 ml
COMPOUND
====ss=ss====================
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovani Uin
3,4-Dichlorocatechol
3,4,5-trichloroguaiacol
5,6-Dichlorovanillin
Ch 1 orosyr i nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Oichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trfchlorophenol
4,5-Oichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentach I oropheno I
Tetrachloroguaiacol
Tetrachlorocatechol
Quant.
Column
= == = =========:
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak
Area
(A)
s==r=s
2208
10888
6717
2456
347
980
3794
9550
8909
4765
Calib
Factor
(CF) (1)
> — ~ — — ==s— =—==
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone . i n
Extract
Ce (ug/mL) (2)
=================
< 0.05
< 0.05
< 0.05
< O.>0
< 0.02
< 0.05
< 0.10
0.49
< 0.50
< 0.02
< 0.10
< 0.10
0.72
0.41
0.40
0.05
< 0.02
0.10
< 0.10
0.38
< 0.10
< 0.05
< 0.10
< 0.20
0.97
0.52
0.35
< 0.05
Conc/DU
Factor
(X) (3)
==========
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
Extract Volume (Ve)
-OB-1 column-
5 ml
Sample
Cone. Observed
Cs (ug/L) (4) Ret. Time Window
-DB-608 column
Observed
Ret. Time
Window
0.5
0.5
0.5
1.0
0.2
0.5
1.0
4.9
5.0
0.2
1.0
1.0
7.2
4.1
4.0
0.5
0.2
1.0
1.0
3.8
1.0
0.5
1.0
2.0
9.7
5.2
3.5
0.5
14.36
21.27
22.99
26.55
3.89
8.20
9.86
18.26
21.27
22.28
5.34
6.10
7.02
7.41
9.15
10.86.
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
16.69
22.87
23.67
28.56
3.42
7.38
8.88
20.07
20.32
22.05
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trfchlorophenol
DB-608
22292 9.41E-05
2.10
0.2
21
11.72 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA No. 19371
ATI No. 90-05-033-08
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 ml
COMPOUND
2,6-Dichlorophenol
3,5-Dlchlorophenol
3,4-Dichlorophenol
5-ChloroguaiacoL
2,3,6-Trlchlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Oichlorocatechol
3,4,5-THchloroguaiacol
5,6-Diehlorovanillin
ChIorosyr i ngaIdehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-TrichLorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
feaK Lai ID
Quant. Area Factor
Column (A) (CF) (1)
DB-1 6.02E-05
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
370
559
5563
5414
795
1054
1731
700
1620
4823
1058
4926
8771
4016
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9. 14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
ionc. in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
0.03
0.44
0.52
0.18
< 0.50
0.07
< 0.10
< 0.10
< 0.05
< 0.05
0.28
< 0.05
0.07
0.16
< 0.10
0.49
< 0.10
< 0.05
0.13
0.84
0.89
0.24
< 0.02
< 0.05
Lonc/ui i
Factor
(X) (3)
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
aampie ....... — --UB-| coiumn----
Conc . Observed
Cs (ug/D (4) Ret. Time Window
< 0.5
< 0.5
< 0.5
< 1.0
0.3
4.4
5.2
1.8
< 5.0
0.7
< 1.0
< 1.0
< 0.5
< 0.5
2.8
< 0.5
0.7
1.6
< 1.0
4.9
< 1.0
< 0.5
1.3
8.4
8.9
2.4
< 0.2
< 0.5
6.38
9.43
10.85
13.71
14.38
17.18
26.57
5.92
8.22
9.87
14.93
16.18
18.26
21.27
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
.......... uo-Ouo coium
Observed
Ret. Time Window
5.26 to 5.61
5.09
9.20
11.89
14.19
16.84
16.84
28.60
5.41
7.39
8.88
14.43
16.64
20.06
20.33
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
tp
to
to
to
to
to
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
22366 9.41E-05
2.10
0.2
21
11.73 11.59 to 12.04
10.57 10.30 to 10.75
-------
EPA No. 19372
ATI No. 90-05-033-09
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 ml
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovani U in
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani 1 1 in
Chlorosyringaldehyde
3,4,5-Trichlorocatechol
Trichlorosyrfngol
2,6-Dlchlorosyringaldehyde
4-Chlorophenol
2,4-Oichlorophenol
2,4,6-Trichlorophenol
4-Chtoroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Oichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguafacol
Tetrachlorocatechol
Quant.
Column
DB-1
DB-1
OB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
D8-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Keen
Area
(A)
3504
2850
2745
3053
2096
1557
359
576
2746
1787
1330
Lai ID
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9. 14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Lone, in
Extract
Ce (ug/mL) (2)
< 0
< 0
< 0
< 0
< 0
0
0
0
< 0
< 0
< 0
< 0
< 0
0
0
< 0
0
0
< 0
0
< 0
0
0
< 0
< 0
< 0
< 0
< 0
.05
.05
.05
.10
.02
.28
.27
.61
.50
.02
.10
.10
.05
.13
.25
.05
.04
.06
.10
.28
.10
.22
.16
.20
.05
.02
.02
.05
tonc/ui i
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.
0.
0.
0.
0.
0.
0.
0.
b ample ---UB-I column- —
Cone. Observed
Cs (ug/L) (4) Ret. Time Window
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
1.4
1.4
3.0
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
0.6
1.3
< 0.3
0.2
0.3
< 0.5
1.4
< 0.5
1.1
0.8
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
10.84
13.71
14.36
14.93
23.00
26.54
5.90
8.20
9.87
14.36
14.93
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
......... .UB.OUO coiumn----
Obscrvcd
Ret. Time Window
11.89
14.19
16.67
16.67
23.69
28.61
5.39
7.38
8.88
13.79
14.40
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
3,4,5-Trichlorophenol
DB-608
36106 9.41E-05
3.40
0.1
17
11.59 to 12.04
10.30 to 10.75
-------
EPA No. 19373
ATI No. 90-05-033-10
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
mL
feaK Lai ID (.one. in uonc/uu sample --OB-I column - UD-OUO coium
Quant. Area Factor Extract Factor Cone. Observed Observed
COMPOUND Column (A) (CF) (1) Ce (ug/mL) (2) (X) (3) Cs
-------
EPA No. Blank
ATI No. 90-05-037-00
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 mL
COMPOUND
===========================
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
Ch 1 orosy r i nga I dehyde
3,4,5-Trichtorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Oichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
3,4,5-Trichlorophenol
Quant.
Column
============
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
OB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
D8-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
====================
7.62E-05
8.63E-05
8.97E-05
2.08E-04
6.40E-05
1.05E-04
1.20E-04
2.80E-04
1.13E-04
8.49E-05
1.18E-04
3.54E-04
8.37E-05
7.95E-05
2.12E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
38397 9.41E-05
Cone . i n
Extract
Ce (ug/ml) (2)
sssss======s=ssss=
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
3.61
Conc/Dil
Factor
(X) (3)
Sample
Cone.
Cs (ug/L)
=======sssssssssssrssss
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
o;i
0.1
0.1
t
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
c 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
18
Observed
-OB-1 column-
Window
-08-608 column
Observed
Ret. Time
Window
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
to 21.72
to 22.75
to 26.65
to
to
to
to
to
to
to
to
to
to
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
11.82 11.59 to 12.04
10.56 10.30 to 10.75
-------
EPA No. 19375
ATI No. 90-05-037-01
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 ml
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dlchlorophenol
5 • Ch I orogua i aco I
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3 , 5 -D i ch I orocatecho I
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
Ch 1 orosyr i nga I dehyde
3,4,5-Trichlorocatechol
Trich I orosyr ingol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguajacol
Pentachlorophenol
Tet rach I orogua i aco I
Tetrachlorocatechol
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-
DB-
DB-
DB-
DB-
DB-
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-60B
DB-608
DB-608
DB-608
DB-608'
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
Conc/Dil Sample
Factor Cone.
(X) (3) Cs (ug/L)
Observed
(4) Ret. Time
-DB-1 column-
Window
-DB-608 column
Observed
Ret. Time
Window
0.1
0.
0.
0.
0.
6.
0.
0.
0.
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.3
0.3
0.3
0.5
0.1
0.3
0.5
0.5
2.5
0.1
0,5
0.5
0.3
0.3
1.3
0.3
0.1
0.3
0.5
0.3
0.5
0.3
0.5
1.0
0.3
0.1
0.1
0.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
to 16.50
to 18.60
to 21.72
to 22.75
to 26.65
to
to
to
to
to
to
to
to
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
55048 9.41E-05
5.18
0.1
26
11.72 11.59 to 12.04
10.59 10.30 to 10.75
-------
EPA No. 19376
ATI No. 90-05-037-02
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 ml
COMPOUND
2 , 6-D i ch I oropheno I
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichlocoguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani Uin
Ch I orosyr i nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichlorosuaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentach I oropheno I
Tetrsch lorogua i acol
Tetrachlorocatechol
KeaK
Quant. Area
Column (A)
OB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
363
1723
1717
1908
2304
3573
1919
572
209
2827
1430
2495
Lai ID
Factor
(CF) (1)
6.02E-05
6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Lone . i n
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
0.29
< 0.02
< 0.05
0.17
< 0.10
0.17
0.15
0.34
< 0.10
0.13
< 0.05
< 0.25
< 0.05
< 0.02
< 0.05
< 0.10
0.29
< 0.10
< 0.05
< 0.10
< a. 20
< 0.05
0.08
0.18
< 0.05
Lonc/u i i
Factor
(X) (3)
0.1
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
sample UB- I column --• — - — UB-OUO column — •
Cone. Observed Observed
Cs (ug/L) (4) Ret. Time Window Ret. Time Window
< 0.3
< 0
< 0
1
< 0
< 0
0
< 0
0
0
1
< 0
0
< 0
< 1
< 0
< 0
< 0
< 0
1
< 0
< 0
< 0
< 1
< 0
0
0
< 0
.3 6.22
.3
.4 7.41
.1
.3
.8 13.72
.5
.9 14.95
.8 17.22
.7 19.73
.5
.6 21.32
.3 23.02
.3
.3
.1
.3 8.21
.5
.4 9.88
.5
.3
.5
.0
.3
.4 21.32
.9 22.30
.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49 5.18
7.45
7.86 8.40
9.66
11.44
14.14 13.96
14.79
15.59 16.96
17.62 16.96
20.17 21.95
20.71
21.76 22.72
23.49 23.62
27.05
4.06
6.07
8.43 7.26
7.57
10.11 9.01
12.95
14.45
15.04
16.50
18.60
21.72 20.26
22.75 21.95
26.65
5.26 to 5.61
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
3,4,5-Trichlorophenol
DB-608
71068 9.41E-05
6.69
0.1
33
11.73 11.59 to 12.04
10.65 10.30 to 10.75
-------
EM NO. 19377
AH No. 90-05-037-03
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 ml
COMPOUND
2,6-Dichlorophenol
3,5-Dfchlorophenol
3,4-Dfchlorophenol
5-Chloroguatacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-DichlorocatechoL
6-ChlorovanUlin
3,4-Dfchlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dlchlorovanlllfn
ChIorosyri ngaIdehyde
3,4,5-Trichlorocatechol
Trfchlorosyrlngol
2,6-Dfchlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Ofchtorocatechot
4,5,6-Trlchloroguaiacot
Pent echIoropheno t
Tatrachloroguafacol
Tetrachlorocatechol
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
OB-1
DB-1
DB-1
DB-1
OB-1
OB-1
DB-1
DB-608
DB-608
DB-608
OB-608
DB-608
DB-608
OB-608
DB-608
DB-608
DB-608
DB-608
OB-608
DB-608
rean lauo
Area Factor
(A) (CF) (1)
7,
8
536 8
853 2
6
1
16407 1
2
1
8
1
3
8
7
2
441 1
1
1
3
8102 1
8
1
1
9107 1
1
5
7
6254 8
.62E-05
.63E-05
.97E-05
.QBE -04
.40E-05
.05E-04
.20E-04
.80E-04
.13E-04
.49E-05
.18E-04
.54E-04
.37E-05
-.95E-05
.12E-04
.43E-04
.OOE-04
.01E-04
.35E-04
.01E-04
.49E-05
.24E-04
.24E-04
.70E-04
.02E-04
.86E-05
.31E-05
.26E-05
uunc . i n
Extract
Ce (ug/mL) (2)
< 0.05
< 0.05
< 0.05
0.18
< 0.02
< 0.05
1.97
< 0.10
< 0.50
< 0.02
< 0.10
< 0.10
< 0.05
< 0.05
< 0.25
0.06
< 0.02
< 0.05
< 0.10
0.82
< 0.10
< 0.05
< 0.10
1.55
< 0.05
< 0.02
< 0.02
0.52
i,onc/uii aanfiie
Factor Cone.
(X)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Observed
(3) Cs (ug/L) (4) Ret. Time
.0 <
.0 <
.0 <
.0
.0 <
.0 <
.0
.0 <
.0 <
.0 <
.0 <
.0 <
.0 <
.0 <
.0 <
.0
.0 <
.0 <
.0 <
.0
.0 <
.0 <
.0 <
.0
.0 <
.0 <
.0 <
.0
3
3
3
9
1
3
98
5
25
1
5
5
3
3
13
3
1
3
5
41
5
3
5
77
3
1
1
26
5.34
6.10
7.41 7.02
7.62 7.41
9.15
10.86
13.79 13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.91 3.88
5.80
8.10
7.25
9.93 9.74
12.51
13.99
14.56
16.27 16.02
18.08
21.16
22.21
26.26 26.08
Window
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
. 1/o-ouo cuiiam
Observed
Ret. Time Window
5.26
4.84
6.52 6.30
8.28 8.03
9.02
11.54
14.16 13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.51 3.41
5.22
7.18
8.09
8.85 8.70
13.09
13.50
14.13
16.61 16.33
19.74
19.97
21.82
27.07 26.73
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
3,4,5-Trlchlorophenol
OB-608
7782 9.41E-05
0.73
1.0
37
11.81 11.59 to 12.04
10.54 10.30 to 10.75
-------
EPA No. T9378
ATI No. 90-05-037-04
Sample Volume (Vs) = 100 ml
Extract Volume (Ve)
5 ml
COMPOUND
2 , 6-0 i ch I oropheno I
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trlchlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovani llin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovani Uin
Ch I orosy r i nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4 -Chi oropheno I
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trfchlorophenol
4,5-Oichloroguaiacol
2 , 3 , 4 , 6- Tet rach I oropheno I
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-60B
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
rear. IBIID
Area Factor
(A) (CF) (1)
7
8
8
2
6
12113 1
1
2
1
2549 8
1
3
8
9909 7
1298 2
1
995 1
2698 1
3
5738 1
8
1
2136 1
1
24506 1
5
7
8
.62E-05
.63E-05
.97E-05
.08E-04
.40E-05
.05E-04
.20E-04
.80E-04
.13E-04
.49E-05
.18E-04
.54E-04
.37E-05
.95E-05
.12E-04
.43E-04
.OOE-04
.01E-04
.35E-04
.01E-04
.49E-05
.24E-04
.24E-04
.70E-04
.02E-04
.86E-05
.31E-05
.26E-05
lone, in Lunc/uii
Extract Factor
Ce (ug/mL) (2) (X) (3)
< 0.05
< 0.05
< 0.05
< 0.10
< 0.02
1.27
< 0.10
< 0.10
< 0.50
0.22
< 0.10
< 0.10
< 0.05
0.79
0.28
< 0.05
0.10
0.27
< 0.10
0.58
< 0.10
< 0.05
0.26
< 0.20
2.50
< 0.02
< 0.02
< 0.05
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
aanipic uu- i coiunn
Cone. Observed
Cs (ug/L) (4) Ret. Time Window
< 3
< 3
< 3
< 5
< 1
64
< 5
< 5
< 25
11
< 5
< 5
< 3
39
14
< 3
5
14
< 5
29
< 5
< 3
13
< 10
125
< 1
e 1
< 3
5.34
6.10
7.02
7.41
9.15
10.93 10.86
13.45
14.12
14.89
17.29 16.89
19.41
19.93
21.00
23.13 22.71
26.65 26.22
3.88
5.93 5.80
8.28 8.10
7.25
9.95 9.74
12.51
13.99
14.83 14.56
16.02
18.37 18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
Observed
Ret. Time Window
5.26
4.84
6.30
8.03
9.02
11.86 11.54
13.79
16.49
16.47
16.68 16.46
21.60
23.22
22.43
23.64 23.22
28.57 28.16
3.41
5.39 5.22
7.37 7.18
8.09
8.85 8.70
13.09
13.50
14.41 14.13
16.33
20.03 19.74
19.97
21.82
26.73
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
3,4,5-Trichlorophenol
DB-608
6784 9.41E-05
0.64
1.0
32
11.82 11.59 to 12.04
10.54 10.30 to 10.75
-------
EPA No. 1?379
ATI No. 90-05-037-05
Sample Volume (Vs) = 100 ml
Extract Volume (Ve)
5 mL
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
Ch I orosy r i nga Idehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2, 6-Dichlorosyringa Idehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trlchlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenot
3,4,6-Trichtoroguaiacol
4,5-Dfchlorocatechol
4,5,6-Trichloroguaiacol
Pentachlorophenol
Tetrachloroguaiacol
Tetrachlorocatechol
3,4,5-Trichlorophenol
Quant.
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
6.02E-05
3577 6.97E-05
7.89E-05
1.66E-04
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
99712 9.41E-05
Cone . i n
Extract
Ce (ug/ml) (2)
< 0.05
0.25
< 0.05
< 0.10
< 0.02
< 0.05
< 0.10
< 0.10
< 0.50
< 0.02
c 0.10
< 0.10
< 0.05
< 0.05
< 0.25
< 0.05
< 0.02
<- 0.05
< 0.10
< 0.05
< 0.10
< 0.05
< 0.10
< 0.20
< 0.05
< 0.02
< 0.02
< 0.05
9.38
Conc/Dil
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample
Cone.
Cs (ug/L)
< 0.3
1.2
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
< 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
< 0.3
< 0.1
< 0.3
< 0.5
< 0.3
< 0.5
< 0.3
< 0.5
< 1.0
< 0.3
< 0.1
< 0.1
< 0.3
47
Observed
-DB-1 column-
Window
-DB-608 column
Observed
Ret. Time
Window
6.25
5.34 to 5.68
6.10 to 6.49
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
4.98
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
11.79 11.59 to 12.04
10.73 10.30 to 10.75
-------
EPA No. 19380
ATI No. 90-05-037-06
Sample Volume (Vs) = 100 ml
Extract Volume (Ve)
5 tnL
neax caiio uonc. in
Quant. Area Factor Extract
Column (A) (CF) (1) Ce (ug/mL) (2)
DB-1 6.02E-05 <
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-60B
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
OB -608
6.97E-05 <
7.89E-05 <
1.66E-04 <
5.07E-05 <
7.95E-05 <
9.63E-05 <
2.22E-04 <
9.14E-05 <
6.67E-05 <
9.38E-05 <
2.35E-04 <
6.64E-05 <
6.12E-05 <
1.61E-04 <
1.43E-04 <
1.00E-04 <
1.01E-04 <
3.35E-04 <
1.01E-04 <
8.49E-05 <
1.24E-04 <
1.24E-04 <
1.70E-04 <
1.02E-04 <
5.86E-05 <
7.31E-05 <
8.26E-05 <
0.05
0.05
0.05
0.10
0.02
0.05.
0.10
0.10
0.50
0.02
0.10
0.10
0.05
0.05
0.25
0.05
0.02
0.05
0.10
0.05
0.10
0.05
0.10
0.20
0.05
0.02
0.02
0.05
Lonc/u i i
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Sample -uo- 1 column im-ouo uuimm
Cone. Observed Observed
Cs (ug/L) (4) Ret. Time Window Ret. Time Window
< 0.3
< 0.3
< 0
< 0
< 0
< 0
< 0
< 0
< 2
< 0
< 0
< 0
< 0
< 0
< 1
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 0
< 1
< 0
< 0
< 0
.3
.5
.1
.3
.5
.5
.5
.1
.5
.5
.3
.3
.3
.3
.1
.3
.5
.3
.5
.3
.5
.0
.3
.1
.1
< 0.3
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
tp
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
J,4,5-Trlchloroph«nol
DB-608
20999 9.41E-05
1.98
0.1
10
11.73 11.59 to 12.04
10.65 10.30 to 10.75
-------
ERA No. 19381
ATI No. 90-05-037-07
Sample Volume (Vs) = 100 ml
COMPOUND
2,6-Dichlorophenol
3 , 5 -D i ch I oropheno I
3 , 4 -D i ch I oropheno I
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-Dichtorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanillin
Chlorosyringaldehyde
3,4,5-Trichlorocatechol
T r i ch I orosyr i ngo I
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentach I oropheno I
Tetrachloroguaiacol
Tetrachlorocatechol
Quant .
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
08-608
DB-608
DB-608
DB-608
DB-608
DB-608
Peak Calib
Area Factor
(A) (CF) (1)
732 6.02E-05
6.97E-05
7.89E-05
1230 1.66E-04
5.07E-05
7.95E-05
3960 9.63E-05
1023 2.22E-04
2464 9.14E-05
6.67E-05
8081 9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
542 1.01E-04
3.35E-04
3886 1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
Cone, in Conc/Dil Sample
Extract Factor Cone. Observed
Ce (ug/mL) (2) (X) (3) Cs (ug/L) (4) Ret. Time
Extract Volume (Ve) =
DB-1 column
Window
5 ml
-DB-608 column
Observed
Ret. Time
Window
0.05
0.05
0.05
0.20
0.02
0.05
0.38
0.23
0.23
0.02
0.76
0.10
0.05
0.05
0.25
0.05
0.02
0.05
0.10
0.39
0.10
0.05
0.10
0.20
0.05
0.02
0.02
0.05
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.5
0.5
0.5
2.0
0.2
0.5
3.8
2.3
2.3
0.2
7.6
1.0
0.5
0.5
2.5
0.5
0.2
0.5
1.0
3.9
1.0
0.5
1.0
2.0
0.5
0.2
0.2
0.5
5.51
7.53
13.69
14.26
15.16
19.70
8.20
9.87
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.68
6.49
7.45
7.86
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
5.59
8.33
11.95
14.26
16.74
21.83
7.43
8.93
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
5.61
5.23
6.73
8.48
9.53
12.13
14.48
17.16
17.18
17.19
22.36
24.00
23.19
24.01
28.99
3.59
5.49
7.52
8.41
9.07
13.53
13.96
14.61
16.82
20.26
20.53
22.36
27.30
3,4,5-Trichlorophenol
DB-608
29650 9.41E-05
2.79
0.2
28
11.73 11.59 to 12.04
10.63 10.30 to 10.75
-------
EPA No. 19382
ATI No. 90-05-037-08
Sample Volume (Vs) = 100 ml
Extract Volume (Ve) =
5 ml
COMPOUND
2 , 6-D i ch I oropheno I
3,5-Dichlorophenol
3,4-Dichlorophenol
5-Chloroguaiacol
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovanillin
3,4-0 ichlorocatechol
3,4,5-Trichloroguaiacol
5,6-Dichlorovanil tin
Chlorosyringaldehyde
3,4,5-THchlorocatechol
T r i ch I orosyr i ngo I
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2, 4 -Dich I oropheno I
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4, S-D ichlorocatechol
4,5,6-Trichloroguaiacol
Pent ach I oropheno I
Tet rach I orogua i aco I
Tetrachlorocatechol
Quant .
Column
OB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
08-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
reaK
Area
(A)
1731
9985
11720
797
3538
2674
6339
2687
692
1134
2339
6515
7389
12747
L3UD
Factor
-------
EPA No. 19383
ATI No. 90-05-037-09
Sample Volume (Vs) = 100 mL
Extract Volume (Ve) =
5 ml
COMPOUND
2,6-Dichlorophenol
3,5-Dichlorophenol
3,4-Dichlorophenol
5 - Ch I orogua i aco I
2,3,6-Trichlorophenol
4,6-Dichloroguaiacol
3,5-Dichlorocatechol
6-Chlorovani U in
3,4-Dichlorocatechol
3,4,5-Trichlorogu'aiacol
5,6-Dichlorovani llin
Ch 1 orosy r t nga I dehyde
3,4,5-Trichlorocatechol
Trichlorosyringol
2,6-Dichlorosyringaldehyde
4-Chlorophenol
2,4-Dichlorophenol
2,4,6-Trichlorophenol
4-Chloroguaiacol
2,4,5-Trichlorophenol
4,5-Dichloroguaiacol
2,3,4,6-Tetrachlorophenol
3,4,6-Trichloroguaiacol
4,5-Dichlorocatechol
4,5,6-Trichloroguaiacol
Pentach 1 oropheno I
Tetrachloroguaiacol
Tetrachlorocatechol
Quant.
Column
DB-1
DB-1
DB-1
DB-
DB-
DB-
DB-
DB-
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
reax
Area
(A)
laiio lone, in
Factor Extract
(CF) (1) Ce (ug/mL) (2)
6.02E-05 < 0.05
6.97E-05 < 0.05
7.89E-05 < 0.05
1.66E-04 < 0.10
17134
14661
6356
4925
8674
7300
1788
1880
8465
4221
12312
11048
5.07E-05
7.95E-05
9.63E-05
2.22E-04
9.14E-05
6.67E-05
9.38E-05
2.35E-04
6.64E-05
6.12E-05
1.61E-04
1.43E-04
1.00E-04
1.01E-04
3.35E-04
1.01E-04
8.49E-05
1.24E-04
1.24E-04
1.70E-04
1.02E-04
5.86E-05
7.31E-05
8.26E-05
< 0
1
1
1
< 0
< 0
< 0
1
< 0
0
1
< 0
0
0
< 0
0
< 0
0
< 0
2
< 0
0
< 0
< 0
.02
.36
.41
.41
.50
.02
.10
.16
.05
.53
.18
.05
.18
.19
.10
.85
.10
.52
.10
.09
.05
.65
.02
.05
uunc/ui i
Factor
(X) (3)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
aampie ~"~ UD- i column uo-ouo column
Cone. Observed Observed
Cs (ug/L) (4) Ret. Time Window Ret. Time Window
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
6.8
7.1
7.1
< 2.5
< 0.1
< 0.5
5.8
< 0.3
2.7
5.9
< 0.3
0.9
0.9
< 0.5
4.3
< 0.5
2.6
< 0.5
10.5
< 0.3
3.2
< 0.1
< 0.3
10.87
13.73
14.38
26.26
23.03
26.58
5.92
8.22
9.89
14.38
16.22
21.31
5.34
6.10
7.02
7.41
9.15
10.86
13.45
14.12
14.89
16.89
19.41
19.93
21.00
22.71
26.22
3.88
5.80
8.10
7.25
9.74
12.51
13.99
14.56
16.02
18.08
21.16
22.21
26.08
to 5.68
to 6.49
to 7.45
to 7.86
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
to
9.66
11.44
14.14
14.79
15.59
17.62
20.17
20.71
21.76
23.49
27.05
4.06
6.07
8.43
7.57
10.11
12.95
14.45
15.04
16.50
18.60
21.72
22.75
26.65
11.93
14.25
16.72
23.73
23.73
26.67
5.42
7.42
8.91
13.65
16.72
20.14
5.26
4.84
6.30
8.03
9.02
11.54
13.79
16.49
16.47
16.46
21.60
23.22
22.43
23.22
28.16
3.41
5.22
7.18
8.09
8.70
13.09
13.50
14.13
16.33
19.74
19.97
21.82
26.73
to 5.61
to 5.23
to 6.73
to 8.48
to 9.53
to 12.13
to 14.48
to 17.16
to 17.18
to 17.19
to 22.36
to 24.00
to 23.19
to 24.01
to 28.99
to 3.59
to 5.49
to 7.52
to 8.41
to 9.07
to 13.53
to 13.96
to 14.61
to 16.82
to 20.26
to 20.53
to 22.36
to 27.30
3,4,5-Trichlorophenol
DB-608
79870 9.41E-05
7.52
0.1
38
11.76 11.59 to 12.04
10.63 10.30 to 10.75
-------
NALYTICAL TECHNOLOGIES INC.
able 8 Matrix Spike Recoveries
SAS 1047
1 COMPOUND
!,6-Dichlorophenol
,5-Dichlorophenol
,4-Dichlorophenol
-Chloroquaiacol
, 3 , 6-Trichlorophenol
, 6-Dichloroguaiacol
, 5-Dichlorocatechol
-Chlorovanillin
, 4-Dichlorocatechol
, 4 , 5-Trichloroguaiacol
, 6-Dichlorovanillin
hlorosyringaldehyde
, 4 , 5-Trichlorocatechol
richlorosyringol
, 6-Dichlorosyringaldehyde
! , 6-Dichlorophenol
, 5-Dichlorophenol
, 4-Dichlorophenol
-Chloroquaiacol
, 3 , 6-Trichlorophenol
, 6-Dichloroguaiacol
, 5-Dichlorocatechol
-Chlorovanillin
, 4-Dichlorocatechol
, 4 , 5-Trichloroguaiacol
> , 6-Dichlorovanillin
hlorosyringaldehyde
, 4 , 5-Trichlorocatechol
frichlorosyringol
!, 6-DichlorosvTingaldehyde
Quanti-
titation
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1.
DB-1
DB-1
DB-l
DB-1
DB-1
DB-1
DB-1
DB-1
Spike
Cone.
ug/L
50
50
50
100
20
50
50
100
100
50
100
100
50
50
250
50
50
50
100
20
50
50
100
100
50
100
100
50
50
250
Sample
Cone.
ug/L
< 0.3
< 0.3
< 0.3
< 0.5
< 0.1
1.2
1.8
1.8
1.1
< 0.1
< 0.5
< 0.5
< 0.3
0.4
1.1
0.4
< 0.3
< 0.3
< 0.5
< o.r
10.9
< 0.5
0.5
< 2.5
0.5
< 0.5
2.0
'. 0.3
< 0.3
' 1.3
Cone.
Found
ug/L
53
49
52
100
20
52
54
81
100
22
81
85
58
52
219
49
48
55
97
20
60
51
77
100
20
83
79
51
50
199
MS
Percent
Recovery
106
98
104
100
100
102
104
79
99
44
81
85
116
103
87
VW-VJJ.-VO
Cone.
Found
ug/L
52
52
50
106
21
55
55
82
100
22
76
82
56
50
198
Sample: 90-05-033-01-
97
96
110
97
100
98
102
77
100
39
83
77
102
100
53
54
57
108
20
66
56
83
107
20
80
70
53
47
80 189
MSD
Percent
Recovery
105
105
101
106
105
111
109
82
100
45
76
82
112
100
79
107
108
114
108
102
132
112
83
107
39
80
70
106
93
75
Percent
Difference
1
6
3
6
5
6
1
1
0
1
6
4
4
4
10
9
12
4
11
2
9
9
7
7
1
4
12
3
7
5
uoiiipxc;. j\r~\jj— \j j / -\jo
,6-Dichlorophenol
,5-Dichlorophenol
,4-Dichlorophenol
-Chloroquaiacol
, 3 , 6-Trichlorophenol
, 6-Dichloroguaiacol
, 5-Dichlorocatechol
-Chlorovanillin
, 4-Dichlorocatechol
, 4 , 5-Trichloroguaiacol
, 6-Dichlorovanillin
hlorosyringaldehyde
, 4 , 5-Trichlorocatechol
richlorosyringol
, 6-DicMorosyringaldehyde
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
50
50
50
100
20
50
50
100
100
50
100
100
50
50
250
< 0.3
' 0.3
< 0.3
< 0.5
< 0.1
< 0.3
< 0.5
'. 0.5
< 2.5
< 0.1
< 0.5
< 0.5
< 0.3
< 0.3
< 1.3
51
50
49
100
20
50
51
83
102
20
79
82
51
48
206
102
100
98
100
100
100
102
83
102
40
79
82
102
%
82
49
51
48
98
19
51
49
77
96
20
78
73
48
48
195
99
101
98
95
102
98
77
39
78
73
95
78
3
1
2
2
5
2
4
8
6
2
1
12
7
0
5
-------
ALYTICAL TECHNOLOGIES INC
SAS 1047
ble 9 Run Chronology (continued)
Date
Sample Received
d A 1:4 Calibr. Verification N/A
d B 1:4 Calibr. Verification N/A
-05-033-10 (100:0.5cnL) 05-18-90
-05-037-01 (100:0.5mL) 05-19-90
KJ5-037-02 (100:0.5mL) 05-19-90
KJ5-037-05 (100:0.5mL) 05-19-90
1-05-037-06 (100:0.5mL) 05-19-90
K)5-037-07 (100: ImL) 05-19-90
KJ5-037-08 (100: ImL) 05-19-90
K55-037-09 (100:0.5mL) 05-19-90
d A 1:4 Calibr. Verification N/A
d B 1:4 Calibr. Verification N/A
libration std A High, curve 3 N/A
libration std A 1:2, curve 3 N/A
libration std A 1:4, curve 3 N/A
libration std A 1:20, curve 3 N/A
libration std B High, curve 3 N/A
libration std B 1:2, curve 3 N/A
libration std B 1:4, curve 3 N/A
libration std B 1:20, curve 3 N/A
ank N/A
-05-031-08MS A (100:5roL) 05-17-90
-05-033-OU1S A (100:5mL) 05-18-90
-05-037-06MS A (100: 5mL) 05-19-90
libration std A High (2.5:1) N/A.
libration std B High (2.5:1) N/A
3 A 1:4 Calibr. Verification N/A
I B 1:4 Calibr. Verification N/A
Libration std A High, curve 4 N/A
Libration std A 1:2, curve 4 N/A
Libration std A 1:4, curve 4 N/A
Libration std A 1:20, curve 4 N/A
Libration std B High, curve 4 N/A
Libration std B 1:2, curve 4 N/A
Libration std B 1:4, curve 4 N/A
Libration std B 1:20, curve 4 N/A
aik N/A
-05-031-08MSD A (100:5cnL) 05-17-90
•05-033-01MSD A (100: 5mL) 05-18-90
-05-037-06MSD A (100:5mL) 05-19-90
1 A 1:4 Calibr. Verification N/A
1 B 1:4 Calibr. Verification N/A
Date
Extracted
05-25-90
05-25-90
05-21-90
05-29-90
05-29-90
05-29-90
05-29-90
05-29-90
05-29-90
05-29-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
06-12-90
06-12-90
06-12-90
06-12-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
05-25-90
06-22-90
06-22-90
06-22-90
06-22-90
05-25-90
05-25-90
Column: DB-1
Date Time
Analyzed
06-10-90
06-10-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-11-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-25-90
06-25-90
22:53
23:29
00:06
00:42
01:19
01:55
02:32
03:08
03:44
04:23
05:34
06:11
17:55
18:32
19:10
19:47
20:24
21:01
21:39
22:16
22:53
00:08
00:45
01:22
04:28
05:05
05:43
06:20
13:36
14:13
14:51
15:28
16:05
16:42
17:20
17:57
18:34
19:49
20:26
21:03
00:09
00:46
Column: DB-608
Date Time
Analyzed
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-09-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-12-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
06-13-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-24-90
06-25-90
05:38
06:15
06:52
07:29
08:34
10:56
11:34
12:10
12:47
13:23
15:44
16:23
17:10
17:55
18:32
19:10
19:47
20:24
21:01
21:39
22:16
23:30
00:08
00:45
03:51
04:28
05:05
05:43
12:54
13:36
14:13
14:51
15:28
16:05
16:42
17:20
17:57
19:11
19:49
20:26
23:32
00:09
-------
ilytical Technologies, Inc.
SAS 1047
>le 10 Calibration Data Curve 1 (continued)
Compound
5-dichlorovanillin
.orosyringealdehyde
4 , 5-trichlorocatechol
ichlorosyringol
6-dichlorosyringaldehyde
4 , 5-trichlorophenol
chlorophenol
-
4-dichlorophenol
4,6-trichlorophenol
chloroguaiacol
Cone
(ug/mL)
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
10.00
5.00
2.50
0.50
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
Peak
Area
33439
16806
8360
1737
12283
5589
2639
523
23962
11983
5874
1208
24468
12845
6301
1262
45598
24045
11872
2395
19710
11170
5211
1120
13688
7282
3644
668
8258
4392
2135
337
18614
10631
5250
924
12659
6804
3317
466
-UB-OUO
Mean %RSD of
Calib Calib Calib
Factor Factor Factors
1.20E-04 1.18E-04
1.19E-04
1.20E-04
1.15E-04
3.26E-04 3.54E-04
3.58E-04
3.79E-04
8.35E-05 8.37E-05
8.35E-05
8.51E-05
8.28E-05
8.17E-05 7.95E-05
7.79E-05
7.94E-05
7.92E-05
2.19E-04 2.12E-04
2.08E-04
2.11E-04
2.09E-04
1.85E-04 9.41E-05
2.12E-04
2.57E-04
4.15E-04
1.46E-04 1.43E-04
1.37E-04
1.37E-04
1.50E-04
9.69E-05 l.OOE-04
9.11E-05
9.37E-05
1.19E-04
1.07E-04 1.01E-04
9.41E-05
9.52E-05
1.08E-04
3.16E-04 3.35E-04
2.94E-04
3.01E-04
4.29E-04
1.6
6.2
1.0
1.8
2.1
5.4
3.8
10.9
6.5
16.4
-------
fclytical Technologies, Inc.
SAS 1047
Die 10 Calibration Data Curve 3 (continued)
Ctampound
5-dichlorovanillin
Lorosyringealdehvde
1 , 5-trichlorocatechol
Lchlorosyringol
5-dichlorosyringaldehyde
5,5-trichlorophenol
:hlorophenol
1-dichlorophenol
1,6-trichlorophenol
Moroguaiacol
Cone
(ug/mL)
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
10.00
5.00
2.50
0.50
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
Peak
Area
51224
24726
13192
2698
18660
8587
4748
944
34558
16108
8647
1801
37624
18320
9755
2167
68510
32484
17633
3727
23249
11866
6598
1322
17999
9026
4797
940
10722
5471
2823
590
25442
13257
6961
1481
16907
8851
4634
977
UB-WO
Mean
Calib CaliJ)
Factor • Factor
7.81E-05 7.72E-05
8.09E-05
7.58E-05
7.41E-05
2.14E-04 2.19E-04
2.33E-04
2.11E-04
5.79E-05 5.83E-05
6.21E-05
5.78E-05
5.55E-05
5.32E-05 5.13E-05
5.46E-05
5.13E-05
4.61E-05
1.46E-04 1.44E-04
1.54E-04
1.42E-04
1.34E-04
8.60E-05 9.41E-05
8.43E-05
7.58E-05
7.56E-05
1.11E-04 1.08E-04
1.11E-04
1.04E-04
1.06E-04
7.46E-05 7.16E-05
7.31E-05
7.08E-05
6178E-05
7.86E-05 7.33E-05
7.54E-05
7.18E-05
6.75E-05
2.37E-04 2.21E-04
2.26E-04
2.16E-04
2.05E-04
3.3
4.4
4.1
6.2
5.0
5.4
2.7
3.6
5.6
5.4
-------
jalytical Technologies, Inc.
SAS 1047
able 10 Calibration Data Curve 4
Compound
, 6-dichlorophenol
, 5-dichlorophenol
,4-dichlorophenol
-chloroguaiacol
, 3 , 6-t richlorophenol
, 6-dichloroguaiacol
, 5-dichlorocatechol
-chlorovanillin
,4-dichlorocatechol
, 4 , 5-trichloroguaiacol
Cone
(ug/mL)
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
Peak
Area
13493
6711
3198
588
11924
5931
2818
494
11360
5574
2698
488
10391
4935
2469
380
6962
3409
1636
303
10431
5157
2449
446
9183
4310
2143
388
7788
3744
1841
320
18120
8812
4307
883
5726
2689
1479
257
1JB-1-
Mean %RSD of
Calib Calib Calib
Factor Factor Factors
1.48E-04 1.56E-04
1.49E-04
1.56E-04
1.70E-04
1.68E-04 1.79E-04
1.69E-04
1.77E-04
2.02E-04
1.76E-04 1.86E-04
1.79E-04
1.85E-04
2.05E-04
3.85E-04 4.30E-04
4.05E-04
4.05E-04
5.26E-04
1.15E-04 1.22E-04
1.17E-04
1.22E-04
1.32E-04
1.92E-04 2.04E-04
1.94E-04
2.04E-04
2.24E-04
2.18E-04 2.35E-04
2.32E-04
2.33E-04
2.58E-04
5.14E-04 5.54E-04
5.34E-04
5.43E-04
6.25E-04
2.21E-04 2.27E-04
2.27E-04
2.32E-04
2.27E-04
1.40E-04 1.45E-04
1.49E-04
1.35E-04
1.56E-04
5.6
7.8
6.0
13.0
5.4
6.3
6.1
7.6
1.8
5.5
-------
}ralytical Technologies, Inc.
SAS 1047
(able 10 Calibration Data Curve 4 (continued)
Compound
i, 6-dichlorovanillin
tilorosyringealdehyde
, 4 , 5-trichlorocatechol
richlorosyringol
, 6-dichlorosyringaldehyde
, 4 , 5-trichlorophenol
-chlorophenol
,4-dichlorophenol
, 4 , 6-trichlorophenol
-chloroguaiacol
Cone
(ug/mL)
4.00
2.00
1.00
0.20
4.00
2.00
1.00
0.20
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
10.00
5.00
2.50
0.50
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
Peak
Area
18023
8498
4211
865
6746
3107
1427
364
12702
5872
2895
571
14112
6510
3215
721
24816
11824
5737
1184
8696
4354
2245
373
5867
3075
1637
311
3468
1832
980
152
8172
4303
2285
450
5552
3011
1505
192
uo-j. —
Mean %RSD of
Calib Calib Calib
Factor Factor Factors
2.22E-04 2.31E-04
2.35E-04
2.37E-04
2.31E-04
5.93E-04 6.46E-04
6.44E-04
7.01E-04
1.57E-04 1.69E-04
1.70E-04
1.73E-04
1.75E-04
1.42E-04 1.47E-04
1.54E-04
1.56E-04
1.39E-04
4.03E-04 4.21E-04
4.23E-04
4.36E-04
4.22E-04
2.30E-04 2.38E-04
2.30E-04
2.23E-04
2.68E-04
3.41E-04 3.23E-04
3.25E-04
3.05E-04
3.22E-04
2.31E-04 2.29E-04
2.18E-04
2.04E-04
2.63E-04
2.45E-04 2.30E-04
2.32E-04
2.19E-04
2.22E-04
7.20E-04 7.73E-04
6.64E-04
6.64E-04
1.04E-03
2.6
6.8
4.0
4.9
2.8
7.5
3.9
9.5
4.4
20.3
-------
[nalytical Technologies, Inc.
SAS 1047
fable 10 Calibration Data Curve 4 (continued)
Compound
1,4, 5-trichlorophenol
1 , 5-dichloroguaiacol
! , 3 , 4 , 6-tetrachlorophenol
, 4 , 6-trichloroguaiacol
, 5-dichlorocatechol
, 5 , 6-trichloroguaiacol
entachlorophenol
etrachloroguaiacol
etrachlorocatechol
Cone
(ug/mL)
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
2.00
1.00
0.50
0.10
4.00
2.00
1.00
0.20
0.80
0.40
0.20
0.04
0.40
0.20
0.10
0.02
0.80
0.40
0.20
0.04
2.00
1.00
0.50
0.10
Peak
Area
8515
4490
2386
511
10439
5354
2682
594
7073
3268
1574
314
7031
3367
1651
363
10606
5399
2894
534
3500
1661
752
168
2968
1519
631
174
4441
2470
1046
196
9753
4975
2280
388
UB-bUB
Mean %RSD of
Calib Calib Calib
Factor Factor Factors
2.35E-04 2.16E-04
2.23E-04
2.10E-04
1.96E-04
1.92E-04 1.83E-04
1.87E-04
1.86E-04
1.68E-04
2.83E-04 3.06E-04
3.06E-04
3.18E-04
3.18E-04
2.84E-04 2.90E-04
2.97E-04
3.03E-04
2.75E-04
3.77E-04 3.67E-04
3.70E-04
3.46E-04
3.75E-04
2.29E-04 2.43E-04
2.41E-04
2.66E-04
2.38E-04
1.35E-04 1.35E-04
1.32E-04
1.58E-04
1.15E-04
1.80E-04 1.84E-04
1.62E-04
1.91E-04
2.04E-04
2.05E-04 2.21E-04
2.01E-04
2.19E-04
2.58E-04
6.8
4.8
4.7
3.7
3.4
5.7
11.5
8.4
10.1
-------
INALYTICAL TECHNOLDGIES INC.
table 11 Calibration Verification
SAS 1047
COMPOUND
. MKA
,6-Dichlorophenol
,5-Dichlorophenol
, 4-Dichlorophenol
-Chloroguaiaool
1,3, 6-Trichlorophenol
, 6-Dichloroguaiaool
, 4, 5-Triclilorophenol
, 5-Dichlorocatechol
i-Chlorovanillin
1 , 4-Dichlorocatechol
1,4, 5-Tridiloroguaiacol
> , 6-Dichlorovanillin
hlorosyringaldehyde
! , 4 , 5-Trichlorocatechol
Yichlorosyringol
i , 6-Dichlorosyringaldehyde
MKB
l-Chlorophenol
! , 4-Dichlorophenol
! , 4, 6-Trichlorophenol
1-Chloroguaiacol
1 , 4 , 5-Trichlorophenol
1 , 5-Dichloroguaiacol
! , 3 , 4 , 6-Tetrachlorophenol
5,4, 6-Trichloroguaiacol
I , 5-Dichlorocatecnol
1,5,6-Trichloroguaiacol
'entachlorophenol
Petrachloroguaiacol
Tetrachlorocatechol
Quanti-
fication —
Column
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-1
DB-608
DB-608 .
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
DB-608
1
18
22
23
19
26
24
5
25
25
18
34
23
19
25
22
22
2
1
4
13
6
5
6
2
6
5
4
0
12
2
21
25
23
21
27
23
7
27
27
22
33
25
20
25
23
24
9
12
12
16
14
10
3
6
13
6
5
1
21
—Percent
3
9
9
10
4
10
14
15
14
12
11
19
9
10
16
8
9
14
20
20
28
24
27
19
9
9
6
0
5
4
Deviatia
4
9
18
20
24
20
14
17
15
20
15
21
16
10
12
13
8
15
13
9
11
9
17
13
18
6
6
24
25
3
5
10
16
20
19
14
15
33
16
19
13
21
16
10
5
11
7
14
10
7
7
8
9
4
7
6
10
14
16
5
6
10
16
20
19
14
15
15
16
19
13
21
16
10
5
11
7
15
25
26
36
30
26
15
21
19
20
13
14
7
7
11
12
7
8
5.
10
7
1
5
4
5
3
2
4
7
5
10
10
11
8
10
18
4
7
0
13
4
11
3
-------