EPA-450/3-77-008e
October 1976
PRELIMINARY SCORING
OF SELECTED ORGANIC
AIR POLLUTANTS
APPENDIX IV -
CHEMISTRY, PRODUCTION,
AND TOXICITY
OF CHEMICALS
O THROUGH Z
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Air and Waste Management
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711
-------
EPA-450/3-77-008e
PRELIMINARY SCORING
OF SELECTED ORGANIC AIR POLLUTANTS
APPENDIX IV -
CHEMISTRY, PRODUCTION,
AND TOXICITY
OF CHEMICALS
O THROUGH Z
by
J. Dorigan, B. Fuller and R. Duffy
The Mitre Corporation
Metrek Division
Westgate Research Park
McLean, Virginia 22101
Contract No. 68-02-1495
Project No. 077L
EPA Project Officer: David R. Patrick
Prepared for
ENVIRONMENTAL PROTECTION AGENCY
Office of Air and Waste Management
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711
October 1976
-------
PREFACE
A program is being developed by the Emission Standards and
Engineering Division of the U.S. Environmental Protection Agency to
determine the extent and environmental effects of atmospheric industrial
emissions of synthetic organic chemicals. As part of the initial effort,
EPA requested that the MITRE Corporation, METREK Division, devise a
system for identifying those chemicals that may be released to the
atmosphere from chemical manufacturing plants and whose health effects
have been documented. To address this need, three general categories of
information for each compound to be evaluated were deemed directly
relevant:
(1) the quantity of the compound produced;
(2) the potential for atmospheric release from chemical manu-
facturing plants, and
(3) the toxicological effects of the compounds.
The results of this study are presented in the accompanying report
"Preliminary Scoring of Organic Air Pollutants."
The following dossiers were prepared for each of the 637 compounds
under consideration in an attempt to collate the pertinent data for
subsequent evaluation.
-------
TABLE OF CONTENTS
Octyl alcohol AIV-2
Octyl decyl phthalate AIV-4
Octylphenol AIV-6
Oxalic acid AIV-8
Paraldehyde AIV-10
Paraquat AIV-12
PCNB AIV-14
PCP AIV-16
Pentaerythritol AIV-18
Pentane AIV-20
Pentylene AIV-22
Perchloroethylene AIV-24
Perchloromethyl mercaptan AIV-26
o-Phenetidine AIV-28
p-Phenetidine AIV-30
Phenol AIV-32
Phenothiazine AIV-34
o-Phenylenediamine AIV-36
p-PHenylenediamine AIV-38
Phenylhydrazine AIV-40
Phosgene AIV-42
Phthalic anhydride AIV-44
Phthalimide AIV-46
Phthalonitrile AIV-48
Picloram AIV-50
g-Picoline AIV-52
a,g-Pinene AIV-54
Piperazine AIV-56
Piperonyl butoxide AIV-58
Planavin AIV-60
Polacrylamide AIV-62
Polybutenes AIV-64
Polychlorinated biphenyl AIV-66
Polyethylene and co-polymers AIV-68
Polyethylene glycols AIV-70
Polyethylene glycol chloride AIV-72
Polyethylene terephthalate AIV-74
Polypropylene AIV-76
Polypropylene glycol AIV-78
Polystyrene . AIV-80
Polystyrene, thermoplastic resins AIV-82
Polytetrafluoroethylene AIV-84
Polyvinyl alcohol AIV-86
Polyvinyl chloride AIV-88
iii
-------
TABLE OF CONTENTS (Continued)
Princep AIV-90
Propachlor AIV-92
Propane AIV-94
Propanil AIV-96
Propargyl alcohol AIV-98 :
Propazine AIV-100
Propiolactone AIV-102
Propionaldehyde AIV-104
Propionic acid AIV-106
Propyl acetate AIV-108
Propyl alcohol AIV-110
Propylamine AIV-112
Propyl chloride AIV-114
Propylene AIV-116
Propylene chlorohydrin AIV-118
Propylene glycol ~ AIV-120
Propyleneimine AIV-122
Propylene oxide AIV-124
Pyridine AIV-126
Randox AIV-128
Resorcinol AIV-130
Ronnel AIV-132
Ruelene AIV-134
Salicylic acid AIV-136
Silvex AIV-138
Sodium acetate AIV-140
Sodium benzoate AIV-142
Sodium carboxymethylcellulose AIV-144
Sodium chloroacetate AIV-146
Sodium formate AIV-148
Sodium phenate AIV-150
Sorbic acid AIV-152
Sorbitol AIV-154
Styrene monomer AIV-156
Succinic acid AIV-158
Succinonitrile AIV-160
Sulfanilic acid AIV-162
Sulfolane AIV-164
Sulfosuccinic, bis (2-ethylhexyl) ester, sodium salt AIV-166
Sutan AIV-168
TEA AIV-170
TCA AIV-172
Terephthalic acid AIV-174
Termik '"" AIV-176
l,l,l:,2-Tetrachloro-2,2-difluoroethane AIV-178
iv
-------
TABLE OF CONTENTS (Continued)
I,1,2,2-Tetrachloro-l,2-difluoroethane
Tetrachloronaphthalene
Tetrachlorophthalic anhydride
Tetraethyl lead
Tetrahydrofuran
Tetrahydronaphthalene
Tetrahydrophthalic anhydride
Tetramethylethylenediamine
Tetrainethyl lead
Tetramethyl succinonitrile
Tetranitromethane
Tetrapropylene
Tetryl
Thiuram
o-Tolidine
Toluene
Toluene-2,4-diamine
Toluene diisocyanate
Toluenesulfonamide
o-Toluenesulfonic acid
p-Toluenesulfonic acid
Toluenesulfonyl chloride
m-Toluidine
o-Toluidine
p-Toluidine
Toxaphene
Tributyl phosphate
Trichloroaniline
Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
Trichlorofluoromethane
Trichloroisocyanuric acid
Trichloronaphthalene
Trichlorophenoxyacetic acid
Trichloropropane
Trichlorotrifluoroethane
Tricresyl phosphate
Tridecylbenzenesulfonic acid, sodium salt
Triethanolamine
AIV-180
AIV-182
AIV-184
AIV-186
AIV-188
AIV-190
AIV-192
AIV-194
AIV-196
AIV-198
AIV-200
AIV-202
AIV-204
AIV-206
AIV-208
AIV-210
AIV-212
AIV-214
AIV-216
AIV-218
AIV-220
AIV-222
AIV-224
AIV-226
AIV-228
AIV-230
AIV-232
AIV-234
AIV-236
AIV-238
AIV-240
AIV-242
AIV-244
AIV-246
AIV-248
AIV-250
AIV-252
AIV-254
AIV-256
AIV-258
AIV-260
-------
TABLE OF CONTENTS (Concluded)
Triethylamine AIV-262
Triethylene glycol AIV-264
Triethylene glycol, dimethyl ether AIV-266
Triethylene glycol, monomethyl ether AIV-268
Trifluralin AIV-270
Triisobutylene AIV-272
Trimethylamine AIV-274
Trimethylpentanediol AIV-276
Trinitrotoluene AIV-278
Trithion AIV-280
Urea AIV-282
Vernam AIV-284
Vinyl acetate AIV-286
Vinyl chloride AIV-288
Vinylidene chloride AIV-290
Vinyltoluene AIV-292
Warfarin AIV-294
m-Xylene AIV-296
o-Xylene AIV-298
p-Xylene AIV-300
Xylenesulfonic acid, sodium salt AIV-302
2,6-Xylenol AIV-304
3,5-Xylenol AIV-306
Zinc stearate AIV-308
Chemical Name Index AIV-310
VI
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APPENDIX IV
CHEMISTRY, PRODUCTION AND TOXICITY OF SELECTED
SYNTHETIC ORGANIC CHEMICALS
AIV-1
-------
Octyl alcohol
CHEMICAL NAME
CAS Number: 1341-41-9
Chemical Name: Isooctyl alcohol
Synonyms: 2-Ethylhexyl alcohol
2-Ethyl-14iexanol
Molecular
Formula: C8H180
Structure: CH2 - CH2 - CH2 - CH2 - CH - CH2OH
CH,,
I
CH,
Chemical Properties
Molecular Weight: 130.23
Vapor Pressure: 0.2 mm at 20°C
Boiling Point: 18S°C
Density: 0.8328 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Liquid
Vapor Density: 4.49
Melting Point: -76°C
Solubility: Insoluble (H2O)
Environmental Persistence
BOD: 37% of theoretical
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-moderate
AIV-2
-------
Octyl alcohol
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr): 15.8
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LD50 1480mg/kg rat oral
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-3
-------
CHEMICAL NAME
CAS Number: 119-07-3
Chemical Name: Phthalic acid, decyl octyl ester
Synonyms: n-Octyl-n-decyl phthalate
Decyl octyl ester of phthalic acid
Molecular
Formula:
Structure:
0-C10H21
Chemical Properties
Molecular Weight: 418.6
Vapor Pressure: Negligible at 25°C
Boiling Point: 239°C at 4 mm
Density: 0.980 at 20°C/20°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Liquid
Vapor Density:
Melting Point: -40°C
Solubility:
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-slight
AIV-4
-------
Octyl decyl phthalate
PRODUCTION DATA
Annual U.S.
Production: 200xl06lbs. Consumption: 200x10 Ibs.
Fraction of Fraction of Pro-
Dispersion: 1-° duction Lost: °-015
Release Rate (million Ibs/yr): 203.0
TOXIC ITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-5
-------
Octylphenol
CAS Number: 27193-28-8
Chemical Name: Octylphenol
Synonyms: Diisobutylphenol
Molecular
Formula: Ci4H22O
Structure:
CHEMICAL NAME
CH,
1 *
C-CH,
J^ J
CH3
OH
Chemical Properties
Molecular Weight: 206.36
Vapor Pressure:
Boiling Point: 280 to 283°C
Density: °-941 at 24°C/4°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Solid
Vapor Density:
Melting Point:
Solubility: Insoluble (H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-slight
Disaster hazard—dangerous—toxic fumes-phenol
AIV-6
-------
Octylphenol
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDLo 25 mg/kg mouse intraperitoneal
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-7
-------
Oxalic acid
CHEMICAL NAME
CAS Number: 144-62-7
Chemical Name: Oxalic acid
Synonyms: Ethanedioic acid
Molecular
Formula: C2H204
Structure:
C - C
HO
O
OH
Chemical Properties
Molecular Weight: 90.04
Vapor Pressure:
Boiling Point: 150°C (sublimes)
Density: 1.653 (hydrate)
Octanol/Water Parti-
tion Coefficient: -0.78
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: 187°C (anhydrous)
Solubility: Soluble (H2O)
AIV-8
-------
Oxalic acid
PRODUCTION DATA
Annual U.S.
Production: 18 x 106 ibs. (1974 estimate) Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost: 0.015
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDL0 700 mg/kg human oral
lOOOmg/kg j dog oral
Non-lethal Acute Effects:
Conosion of mouth, esophagus and stomach
Kidney and liver damage
Irritation of eyes and upper respiratory tract
Corneal damage
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 1 mg/m3
Carcinoganicity:
Mutagenicity:
Teratogenicity: TLV: 1 mg/m3
Other Chronic Effects:
Skin irritation
AIV-9
-------
Paraldehyde
CHEMICAL NAME
CAS Number: 123-63-7
Chemical Name: 2,4,6-Trimethyl-s-trioxane
Synonyms: Paraldehyde
Paia-acetaldehyde
Molecular
Formula: C6H12O3
CH3
O O
Structure: I I
H3C O CH3
Chemical Properties
Molecular Weight: 132.18 Physical State: Liquid
Vapor Pressure: 25.3 mm at 20°C Vapor Density: 4.55
Boiling Point: 124.5°C Melting Point: 12.6°C
Density: 0.9943 at 20°C/4°C Solubility: Slightly soluble (H2O)
Octanol/Water Parti-
tion Coefficient: 0.95
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials ,
Safety Hazard: Fire-dangerous
Explosion-slight
AIV-10
-------
Paraldehyde
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 3500mg/kg dog oral
Non-lethal Acute Effects:
Irritation of eyes and mucous membranes
Dermatitis
Psychotrophic effects
TDLo 14 mg/kg human oral
14 mg/kg human intravenous
71 mg/kg human intramuscular
14 mg/kg human rectal
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Neoplasm
TDj_,0 12gm/kgfora week mouse skin
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-11
-------
Paraquat
CHEMICAL NAME
CAS Number: 1910-42-5
Chemical Name: l,l'-Dimethyl-4,4'-bipyridium dichloride
Synonyms: Paraquat
l,r-Dimethyl-4,4'-dipyiidium salt
Molecular
Formula:
C12H14N2-2C1
Structure:
a(-> CH(+)_
- CH(3+)Cl<->
Chemical Properties
Molecular Weight: 257.18
Vapor Pressure: non-volatile
Boiling Point: Decomposes
Density: 1.24 to 1.26 at 20°C/20°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Susceptible to ultraviolet decomposition
Physical State: Solid
Vapor Density:
Melting Point:
Solubility: Infinite
Safety Hazard:
AIV-12
-------
Paraquat
PRODUCTION DATA
Annual U.S.
Production: (O, through 1976) Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDso 57 mg/kg rat oral
80 mg/kg rat oral
50 mg/kg monkey oral
22 mg/kg guinea pig oral
LDi,0 236 mg/kg man oral
Non-lethal Acute Effects:
Lung injury
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
TDLo: 6500 fig/kg (6 days) pregnant rat intraperitoneal
Other Chronic Effects:
AIV-13
-------
PCNB
CHEMICAL NAME
CAS Number: 82-68-8
Chemical Name: Pentachloronitiobenzene
Synonyms: PCNB
Quintozene terrachlor
Tritison
Molecular
Formula: C6C15NO2
Chemical Properties
Molecular Weight: 295.32 Physical State: Solid
Vapor Pressure: Vapor Density:
Boiling Point: 328°C (some decomposition) Melting Point: 144°C
Density: 1.718 at 25°C/4°C Solubility: Practically insoluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard: Disaster hazard-dangerous-toxic fumes-NOX and chlorides
AIV-14
-------
PCNB
PRODUCTION DATA
Annual U.S.
Production: 3 x 106 Ibs.
Fraction of
Dispersion: Estimated as 1.0
Release Rate (million Ibs/yr): 3.0
Consumption:
Fraction of Pro-
duction Lost 0.01
Acute Toxicity
LDSO
TOXICITY DATA
Dosage
1650 mg/kg
1650 mg/kg
Animal
rat
mammal
Route
oral
unreported
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Neoplastic effects:
TD,
Lo
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
135 gm/kg (77 weeks) mouse
576 mg/kg (12 weeks) mouse
TLV:
oral
skin
AIV-15
-------
PCP
CHEMICAL NAME
CAS Number: 87-86-5
Chemical Name: Pentachlorophenol
Synonyms: PCP (and salts)
Molecular
Formula: C6HC15O
Chemical Properties
Molecular Weight: 266.32 Physical State: Solid
Vapor Pressure: 40 mm at 211.2°C Vapor Density:
Boiling Point: 310°C (decomposes) at 759 mm Melting Point: 174°C
Density: 1.978 at 22°C/4°C Solubility: Slightly soluble
Octanol/Water Parti-
tion Coefficient: 5.01
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard: Disaster hazard-dangerous-toxic fumes-chlorides
AIV-16
-------
PCP
PRODUCTION DATA
Annual U.S.
Production: 46.0 x 106 Ibs. (1969 capacity) Consumption: 50.0 x 106 Ibs. (197S)
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
Fraction of Pro-
duction Lost: 0.015
TOXICITY DATA
Acute Toxicity
LDSO
TDLO
27 mg/kg
105 mg/kg
56 mg/kg
100 mg/kg
29 mg/kg
Animal
rat
rat
rat
rat
human
Route
oral
skin
intraperitoneal
subcutaneous
oral
Non-lethal Acute Effects:
Irritation of skin, eyes, and mucous membranes
Nausea and vomiting
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 500 /jg/m3
Carcinogenicity:
May be associated with cancer
Mutagenicity:
Mutagen in laboratory
Teratogenicity:
Other Chronic Effects:
TLV: 500Mg/m3
AIV-17
-------
Pentaerythritol
CHEMICAL NAME
CAS Number: 115-77-5
Chemical Name: 2,2-bis(Hydroxymethyl)-l,3-propanediol
Synonyms: Pentek PE 200
Pentek
Penetek
Tetramethylol
Molecular
Formula:
Pentaerythrite
Monopentaerythritol
Tetrahydroxymethylmethane
CH2OH
Structure: HO - CH, - C - CH,OH
2 ! 2
CH2OH
Chemical Properties
Molecular Weight: 136.1
Vapor Pressure:
Boiling Point: 276°C at 30 mm (sublimes)
Density: 1.399 at 25°C/4°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Solid
Vapor Density:
Melting Point: 262°C
Solubility: Soluble (H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-moderate
AIV-18
-------
Pentaerythritol
PRODUCTION DATA
Annual U.S.
Production: 100.4 x 106lbs. (1975) Consumption: 89 x 106 Ibs. (1975)
Fraction of Fraction of Pro-
Dispersion: duction Lost: 0.015
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-19
-------
Pentane
CAS Number: 109-66-0
Chemical Name: Pentane
Synonyms: Amylhydride
Molecular
Formula: C5Hi2
Structure: CH3CH2CH2CH2CH3
CHEMICAL NAME
Chemical Properties
Molecular Weight: 72.15
Vapor Pressure: 400 mm at 18.5°C
Boiling Point: 36.1°C
Density: 0.626 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Liquid
Vapor Density: 2.48
Melting Point: -129.72°C
Solubility: Slightly soluble (0.03 gm/100 ml H2O)
Safety Hazard: Fire-very dangerous
Explosion - severe
AIV-20
-------
Pentane
PRODUCTION DATA
Annual U.S.
Production: 478 x 106 Ibs. (1964) (all pentanes) Consumption:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
Fraction of Pro-
duction Lost: 0.015
Acute Toxicity
TOXICITY DATA
Dosage Animal
Route
Non-lethal Acute Effects:
Narcotic in high concentrations
CNS effects
TCLO 1 30,000 ppm
Irritation of eyes and respiratory tract
human
inhalation
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 1000 ppm
Carcinogenicity: Carcinogen
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV: 1000 ppm
AIV-21
-------
Pentylene
CHEMICAL NAME
CAS Number: 513-3S-9
Chemical Name: 2-Methyl-2-butene
Synonyms: Amylenes (mixed)
Trimethylethylene
3-Methyl-2-butene
Molecular
Formula: CSH10
CH3
Structure: CH3 - C = CH - CH3
Chemical Properties
Molecular Weight: 70.14 Physical State: Liquid
Vapor Pressure: Vapor Density:
Boiling Point: 38.57°C at 760 mm Melting Point: -133.77°C
Density: 0.6623 at 20°C/4°C Solubility: Insoluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-dangerous
AIV-22
-------
Pentylene
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
Moderate effects from ingestion or inhalation
AIV-23
-------
Perchloroethylene
CHEMICAL NAME
CAS Number: 127-18-4
Chemical Name: Tettachloroethylene
Synonyms: Perchloroethylene
Ethylene tetrachloiide
Molecular
Formula: C2C14
Carbondichloride
Tetrachloioethene
Structure:
Chemical Properties
Molecular Weight: 165.82
Vapor Pressure: 18.47 mm at 25°C
Boiling Point: 121.20°C at 760mm
Density: 1.6227 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Activity: RO2ti^ = 220 years
031^4 = 11 years
OH: t% = 8 days
Photochemical Degradation: Not photoreactive
Safety Hazard: Disaster hazard-dangerous-toxic fumes-chlorides
Physical State: Liquid
Vapor Density: 5.83
Melting Point: -19°C
Solubility: Insoluble (H2O)
AIV-24
-------
Perchloroethylene
PRODUCTION DATA
Annual U.S.
Production: 673.7 x 106 Ibs. (1975)
Fraction of
Dispersion: 0.89
Release Rate (million Ibs/yr): 688.0
Consumption: 515 to 575 x 106 Ibs. (1975 estimate)
Fraction of Pro-
duction Lost: 0.015
Acute Toxicity
TOXICITY DATA
Dosage Animal
2200 mg/kg rabbit
5000 mg/kg rabbit
4000 mg/kg cat
85 mg/kg dog
4000 mg/kg dog
4000 ppm (4 hours) rat
Route
subcutaneous
oral
oral
intravenous
oral
inhalation
Non-lethal Acute Effects:
TCLO 600 ppm (10 min) man-inhalation—central nervous systems effects
280 ppm (2 hours) man-inhalation—eye irritant
230 ppm human-inhalation-systemic effects
Local irritant; lachrymation; irritation of nose and throat; vomiting, nausea; drowsiness;
attitude of irresponsibility; anesthetic; headache; dermatitis; irritation of gastrointestinal tract
following ingestion.
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 100 ppm
continuous 200 ppm
peak 300 ppm for 5 minutes in 3 hours
Carcinogenicity:
Not carcinogenic according to Dow Chemical Co.
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
fLV:
AIV-25
-------
Perchloromethyl mercaptan
CHEMICAL NAME
CAS Number: 75-70-7
Chemical Name: Trichloromethanetniol
Synonyms: Perchloromethyl mercaptan
Molecular
Formula:
CHCljS
Structure:
Cl
1
Cl — C — SH
1_
Cl
Chemical Properties
Molecular Weight: 151.43
Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Trichloromethyl mercaptan
Physical State:
Vapor Density:
Melting Point:
Solubility:
Liquid
Safety Hazard:
Disaster hazard-dangerous-toxic fumes-chlorides
AIV-26
-------
Perchloromethyl mercaptan
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
TOXICITY DATA
Acute Toxicity
LDSO
Dosage
83 mg/kg
483 ppm (10 minutes)
58 ppm (10 minutes)
58 ppm (15 minutes)
Non-lethal Acute Effects:
Eye
TCLo 45 ppm
Irritation of respiratory tract
Animal
rat
human
mouse
cat
human
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 800 mg/m3
Carcinogenicity:
Mutagenicity:
TCLO
Teratogenicity:
Other Chronic Effects:
15 mg/m (68 weeks) rat
TLV:
Route
oral
inhalation
inhalation
inhalation
inhalation
inhalation
AIV-27
-------
o-Phenetidine
CHEMICAL NAME
CAS Number: 94-70-2
Chemical Name: o-Phenetidme
Synonyms: 2-Aminophenetole
2-Ethoxyaniline
Molecular
Formula: C8H,,NO
Structure:
Chemical Properties
Molecular Weight: 137.2
Vapor Pressure: 1 mm at 67°C
Boiling Point: 232.5°C at 760 mm
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Liquid
Vapor Density:
Melting Point: -20° C
Solubility: Slightly (H2O)
Safety Hazard: Disaster hazard-dangerous-toxic fumes-NOx
AIV-28
-------
o-Phenetidine
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Sublethal acute effects:
Highly toxic
Palpitation
Dyspnea
Cyanosis
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity: Recognized carcinogen
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-29
-------
p-Phenetidine
CHEMICAL NAME
CAS Number: 156-434
Chemical Name: p-Phenetidine
Synonyms: 4-Ethoxybenzenamine
4-Aminophenetole
4-Ethoxyaniline
Molecular
Formula: C8HnNO
Structure:
^
OCH2CH3
Chemical Properties
Molecular Weight: 137-2
Vapor Pressure: <10mmat 25°C
Boiling Point: 253 to 255°C
Density: 1-0652 at 16°C/4°C
Octanol/Water Parti-
tion Coefficient:
Physical State: L»quid
Vapor Density: 4-73
Melting Point: 2to4°C
Solubility: Slightly soluble (H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard: Disaster hazard-dangerous-toxic fumes-NOX
AIV-30
-------
p-Phenetidine
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity: Recognized carcinogen
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-31
-------
Phenol
CHEMICAL NAME
CAS Number: 108-95-2
Chemical Name: Phenol
Synonyms: Carbolic acid
Phenic acid
Phenylic acid
Molecular
Formula: C6H6O
Oxybenzene
Phenyl hydroxide
Hydroxy benzene
Structure:
Chemical Properties
Molecular Weight: 94.11
Vapor Pressure: 0.530 mm at 25°C
1 mm at 40°C
Boiling Point: 181.9°C at 760mm
Density: 1.05 76 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD: 96% of theoretical after 20 days at 20° C
Total theoretical oxygen demand = 2.4 gm/gm
Atmospheric Reactivity:
Activity: reacts with oxidizing materials
RO2tvi = 5 mos. j
O3 tvi = 9.6 hours
OHtfc=nday~
Is rapidly biodegiaded to catechol, CHj, CHa and -keto-adipate
Safety Hazard: Fire-moderate
Disaster hazard-dangerous-toxic fumes
Physical State: Solid
Vapor Density: 3.24
Melting Point: 42.5to43°C
Solubility: Soluble (86.6 gm/1 H2O)
Infinitely soluble in hot H
AIV-32
-------
Phenol
PRODUCTION DATA
Annual US
Production: 2,399 x 106 Ibs. (1974)
Fraction of
Dispersion:
Release Rate (million Ibs/yr): 47.0
TOXICITY
Acute Toxicity Dosage
LDSO • 414 mg/kg
669 mg/kg
250 mg/kg
344 mg/kg
300 mg/kg
LDLo 140 mg/kg
650 mg/kg
80 mg/kg
50 mg/kg
420 mg/kg
2000 mg/kg
620 mg/kg
620 mg/kg
180 mg/kg
300 mg/kg
450 mg/kg
290 mg/kg
Non-lethal Acute Effects:
Gastrointestinal 14 mg/kg ,
Liver and kidney damage
Convulsions
Estrous cycle disturbances
Decreased brain cortex activity
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity: TD^ 4000 mg/kg (20 weeks)
Mutagenicity:
Teratogenicity:
Other Chronic Effects: Nausea and vomiting
Paralysis
Consumption:
Fraction of Pro-
duction Lost:
DATA
Animal
rat
rat
rat
mouse
mouse
human
rat
cat
cat
rabbit
rabbit
rabbit
rabbit
rabbit
guinea pig
guinea pig
frog
human
mouse
TLV: Sppm
2,300 x 106 Ibs. (1974 estimate)
0.015
Route
oral .
skin
intraperitoneal
subcutaneous
oral
oral
subcutaneous
subcutaneous
intravenous
oral
skin
intraperitoneal
subcutaneous
intravenous
intraperitoneal
subcutaneous
parenteral
oral
skin
AIV-33
-------
Phenothiazine
CHEMICAL NAME
CAS Number: 92-84-2
Chemical Name: Phenothiazine
Synonyms: Thiodiphenylamine
Dibenzo-l,4-thiazine
Molecular
Formula: C12H9NS(tiicyclic)
H
I
.N
(f ~V
Structure:
Chemical Properties
Molecular Weight: 199.3
Vapor Pressure:
Boiling Point: 371°C at 760 mm
Density:
Octanol/Water Parti-
tion Coefficient: 4.15
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: 185.5 to 185.9 C
Solubility: Slightly (H2O)
AIV-34
-------
Phenothiazine
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
Acute Toxicity
LDso
TOXICITY DATA
Dosage Animal
5 gm/kg rat
Non-lethal Acute Effects:
Hemolytic anemia
Toxic degeneration of liver
Skin irritation and photosensitization
TDLo 425 mg/kg (5 days)
child
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 5 mg/m3
Carcinogsnicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV: Smg/nV*
Route
oral
oral
AIV-35
-------
o-Phenylenediamine
CHEMICAL NAME
CAS Number: 95-54-5
Chemical Name: o-Phenylenediamine
Synonyms: o-Diaminobenzene
1,2-Diamobenzene
Molecular
Formula: C6H8N2
Structure:
NH,,
NH.,
Chemical Properties
Molecular Weight: 108.1
Vapor Pressure: Negligible
Boiling Point: 257°C at 760 mm
Density:
Octanol/Water Parti-
tion Coefficient: 0.37
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard: Fire-slight
Physical State: Solid
Vapor Density:
Melting Point: 102 to 103°C
Solubility: Soluble (hot H2O)
AIV-36
-------
o-Phenylenediamine
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICiTY DATA
Acute Toxicity Dosage Animal Route
LDLo 600 mg/kg rat subcutaneous
600 mg/kg mouse subcutaneous
Non-lethal Acute Effects:
Skin and eye irritant
Liver damage
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV: 100/ag/m3 (skin)
Other Chronic Effects:
AIV-37
-------
p-Phenylenediamine
CHEMICAL NAME
CAS Number: 106-50-3
Chemical Name: p-Phenylenediamine
Synonyms: 1 ,4-Diaminobenzene
Ursol D
Molecular
Formula: C6H8N2
NH2
Structure:
V;
NH
2
Chemical Properties
Molecular Weight: 108.16 Physical State: Solid
Vapor Pressure: lmmat98.8°C Vapor Density: 3.72
Boiling Point: 267°C Melting Point: 140°C
Density: 1.0696 at 58° C/4°C Solubility: Slightly soluble (H2O)
,„., n . Soluble (hot H0O)
Octanol/Water Parti- 1
tion Coefficient: -0.26
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard: Disaster hazard-dangerous toxic fumes
AIV-38
-------
p-Phenylenediamine
Annual U.S.
Production: 48 x 106 Ibs.
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost: 0.01S
Acute Toxicity
TOXICITY DATA
Animal
100 mg/kg rat
50 mg/kg . rat
170 mg/kg rat
100 mg/kg dog
17 mg/kg dog
100 mg/kg cat
100 mg/kg rabbit
200 mg/kg rabbit
17 mg/kg mammal
Route
oral
intraperitoneal
subcutaneous
subcutaneous
intravenous
oral
oral
subcutaneous
intravenous
Non-lethal Acute Effects:
Severe skin and eye irritant
Liver damage
Asthma
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 100 Mg/m3 (skin)
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-39
-------
Phenylhydrazine
CHEMICAL NAME
CAS Number: 100-63-0
Chemical Name: Phenylhydrazine
Synonyms: Hydiazinobenzene
Molecular
Formula: C6H8N2
H
I
N-NH2
f ir
Structure:
Chemical Properties
Molecular Weight: 108.14
Vapor Pressure: 1 mm at 71.8°C
Boiling Point: 243.5°C at 760 mm
Density: 1.0978 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient: 1.25
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density: 3.7
Melting Point: 19.35°C
Solubility: Very slightly soluble (H2O)
Soluble in hot fO
AIV-40
-------
Phenylhydrazine
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
TOXICITY DATA
Acute Toxicity
LDSO
LDLo
Dosage
188 mg/kg
80 mg/kg
80 mg/kg
40 mg/kg
175 mg/kg
170 mg/kg
200 mg/kg
120 mg/kg
80 mg/kg
300 mg/kg
Animal
rat
rabbit
guinea pig
rat
mouse
mouse
dog
dog
rabbit
frog
Route
oral
oral
oral
subcutaneous
oral
subcutaneous
oral
intravenous
subcutaneous
unknown
Non-lethal Acute Effects: •
Hemolysis of red blood cells
Gastrointestinal disturbances
Dermatitis
Nausea and vomiting
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 5 ppm (skin)
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV: 5 ppm
Other Chronic Effects: Damage to kidney and liver
Dermatitis
AIV-41
-------
Phosgene
CAS Number: 75-44-5
Chemical Name: Phosgene
Synonyms: Caibonoxychloiide
Carbonylchloride
CG
Molecular
Formula: CC12O
CHEMICAL NAME
Structure:
O
Cl
Cl
Chemical Properties
Molecular Weight: 98.92
Vapor Pressure: 1428 mm at 25°C
Boiling Point: 7.56°C at 760 mm
Density: 1.392 at 19°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Physical State: Gas or volatile liquid
Vapor Density: 3.4
Melting Point: -118°C
Solubility: Decomposes in H2O
Safety Hazard: Disaster hazard—highly dangerous-toxic fumes
AIV-42
-------
Phosgene
PRODUCTION DATA
Annual U.S.
Production: 728.2 x 106lbs. (1973)
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
Consumption: 1,066 x 10b ibs. (1973)
Fraction of Pro-
duction Lost: 0.015
Acute f oxicity
LCSO
Irritant
Non-lethal Acute Effects:
Corneal opacity
Nausea
TOXICITY DATA
Animal
75 ppm (30 months) rat
110 ppm (30 months) mouse
1087 ppm (1 month) monkey
1482 ppm (1 month) cat
3211 ppm (1 month) rabbit
141 ppm (30 months) guinea pig
79 ppm (30 months) dog
31 mg/m (20 months) guinea pig
25 ppm (30 months) human
Route
inhalation
inhalation
inhalation
inhalation
inhalation
inhalation
inhalation
inhalation
inhalation
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects: Pulmonary edema
TLV: 0.1 ppm
AIV-43
-------
Phthalic anhydride
CHEMICAL NAME
CAS Number: 85-44-9
Chemical Name: Phthalic anhydride
Synonyms: Phalandione
Molecular
Formula: C8H4O3
-o
Structure: \ /
O
Chemical Properties
Molecular Weight: 148.12 Physical State: Solid
Vapor Pressure: 1 mm at 96.5°C Vapor Density: 5.10
Boiling Point: 295.1°C Melting Point: 131.61°C
Density: 1.527 at 4°C Solubility: Soluble slightly (hot H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: (Common air contaminant)
Reacts with oxidizing materials
Safety Hazard: Explosion-moderate
AIV-44
-------
Phthalic anhydride
PRODUCTION DATA
Annual U.S.
Production:
933 x 10" Ibs.
(703.7 x 10° Ibs. in 1975)
0
Release Rate (million Ibs/yr): 14.0
Fraction of
Dispersion:
Consumption: 933.7 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.015
TOXICITYDATA
Acute Toxicity
LDSO
Dosage
4020 mg/kg
800 mg/kg
100 mg/kg
Animal
rat
guinea pig
rat
Route
oral
oral
oral
Non-lethal Acute Effects:
Conjunctivitis
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 2 ppm
Carcinogsnicity:
Mutagenicity:
Teratogenicity: fLV: 2 ppm
Other Chronic Effects: Emphysema and asthma
AIV-45
-------
Phthalimide
CHEMICAL NAME
CAS Number: 8541-6
Chemical Name: lH-Isoindole-l,3(2H)-dione
Synonyms: Phthalimide
1,3-Isoindoledione
Phthalic acid, imide
Molecular Benzoimide
Formula: C8HSNO2
Structure:
Chemical Properties
Molecular Weight: 147.14
Vapor Pressure: < 10 mm at 25°C
Boiling Point: 238°C (sublimes)
Density:
Octanol/Water Parti-
tion Coefficient: 1-69
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard: Disaster hazard-slight-toxic fumes
Physical State: Solid
Vapor Density:
Melting Point: 238°C
Solubility: Slightly soluble (H2O)
AIV-46
-------
Phthalimide
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-47
-------
Phthalonitrile
CHEMICAL NAME
CAS Number: 91-15-6
Chemical Name: Phthalonitrile
Synonyms: o-Dicyanobenzene
1,2-Benzene dicaibonitiile
Molecular
Formula: CgH4N2
Structure:
Chemical Properties
Molecular Weight: 128.14
Vapor Pressure:
Boiling Point: 187°C (sublimes)
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard: Disaster hazard-dangerous-cyanides
Physical State: Solid
Vapor Density: 4.42
Melting Point: 141°C
Solubility: Slightly soluble (H2O)
AIV-48
-------
Phthalonitrile
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LD50 1860mg/kg rat oral
62 mg/kg rat intraperitoneal
65 mg/kg mouse oral
35 mg/kg mouse intraperitoneal
46 mg/kg mouse subcutaneous
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-49
-------
Picloram
CHEMICAL NAME
CAS Number: 1918-02-1
Chemical Name: 4-Amino-3,5,6-trichloropicolinic acid
Synonyms: Picloram
Molecular
Formula:
C6H3C13N202
NH-,
Cl
Structure:
Cl
Cl ^ C - OH
II
o
Chemical Properties
Molecular Weight: 214.46
Vapor Pressure: 6.16 x 10 mm at 35°c
Boiling Point: 215°C (decomposes)
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Photo decomposition
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: 209.5to210°C
(decomposes at 215 C)
Solubility: Soluble (H2O) (430 ppm at 25°C)
AIV-50
-------
Picloram
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 3750mg/kg rat oral
1500 mg/kg mouse oral
2000 mg/kg rabbit oral
2000 mg/kg mammal unknown
Low toxicity to humans
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 10 mg/m3
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-51
-------
B-Picoline
CHEMICAL NAME
CAS Number: 108-99-6
Chemical Name: 3-Picoline
Synonyms: 0-Kcoline
3-Methylpyridine
Molecular
Formula: C6H7N
Structure:
CH,
Chemical Properties
Molecular Weight: 93.12
Vapor Pressure: 10.46 mm at 25°C
Boiling Point: 144.1°C at 760 mm
Density: 0.9566 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Physical State: Liquid
Vapor Density: 3.71
Melting Point: -18.3°C
Solubility: Infinite (H2O)
Safety Hazard:
Fire-moderate
Disaster hazard-dangerous-toxic fumes-NOx
AIV-52
-------
B-Picoline
PRODUCTION DATA
Annual U.S.
Production: >60 x 106 Ibs. (1976) Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost: 0.015
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-53
-------
a, B-Pinene
CHEMICAL NAME
CAS Number: a': 80-56-8
ft: 5947-71-7
rilom. ,, Wa_0. a: 2,6,6-Trimethylbicyclo (3.1.1)ihept-2-ene
Chemical Name: a -,",_. , ,,. , ,,,,,, ,
p : 2,6,6-Tnmethylbicyclo (3.1.1) hept-1-ene
Synonyms: a: 2-Pinene
Molecular
Formula:
C,0H
10"16
: 3-Pinene
Nopinene
Pseudopinene
Structure:
Chemical Properties
Molecular Weight: 136.24
Physical State: Liquid
Vapor Pressure: 1 mm at 37.3 C (unspecified isomer) Vapor Density: 4.7 (unspecified isomer)
Melting Point: a: -55°C
„ .,. „ . a: 156.1 Cat 760mm
Bo.lmgPomt: p: 164 to 166°C at 760mm
Density: a '• 0.8582 at 20 C/4 C
/3": 0.8654 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Solubility: Insoluble (H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-moderate
AIV-54
-------
a, B-Pinene
PRODUCTION DATA
Annual U.S.
Production: 120.7 x 106 Ibs. (1968) Consumption:
(isomer not specified)
Fraction of Fraction of Pro-
Dispersion: duction Lost: 0.015
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Non-lethal Acute Effects:
Irritant to skin and mucous membranes
Nephritis
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-55
-------
Piperazine
CHEMICAL NAME
CAS Number: 110-85-0
Chemical Name: Piperazine
Synonyms: Hexahydropyrazine
Dimethylenediamine
Molecular
Formula: C4Hj0N2
H
Structure:
Chemical Properties
Molecular Weight: 86.14
Vapor Pressure:
Boiling Point: 146 C at 760 mm
Density: 1.1
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard: Disaster hazard-dangerous-toxic fumes-NOx
Physical State: Solid
Vapor Density: 3.0
Melting Point: To6°C
Solubility: Very soluble (H2O)
AIV-56
-------
Piperazine
PRODUCTION DATA
Annual U.S.
Production: 4.6 x 10° ibs. (1968)
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
Consumption:
Fraction of Pro-
duction Lost: 0.015
Acute Toxicity
LDSO
Non-lethal Acute Effects:
Irritant to skin
Blurred vision
TOXICITY DATA
Dosage
1100mg/kg
Animal
mouse
Route
subcutaneous
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-57
-------
Piperonyl butoxide
CHEMICAL NAME
CAS Number: 51-03-6
Chemical Name: o-[2-(2-Butoxyethoxy) ethoxy] -4,5-(methylenedioxy)-2-propyltoluene
Synonyms: Piperonyl butoxide
Butylcarbityl (6-propylpiperonyl) ether
Butacide
Molecular
Formula: C19H3oOs
Structure:
CH2CH3
Chemical Properties
Molecular Weight: 338.4
Vapor Pressure:
Boiling Point: 180°C at 1 mm
Density: 1.04 to 1.07 at 20°C/20°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Liquid
Vapor Density:
Melting Point:
Solubility: Insoluble (
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard: Fire-slight
AIV-58
-------
Piperonyl butoxide
PRODUCTION DATA
Annual U.S.
Production: 1.0xl06lbs.
Fraction of
Dispersion: Estimated at 1.0
Release Rate (million Ibs/yr): 1.0
Consumption:
Fraction of Pro-
duction Lost: 0.015
TOXICITY DATA
Acute Toxicity
LDso
11500mg/kg
380'0 mg/kg
7500 mg/kg
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Animal
rat
mouse
rabbit
TLV:
Route
oral
oral
oral
AIV-59
-------
Planavin
CHEMICAL NAME
CAS Number: 4726-14-1
Chemical Name: 4-(Methyl sulfonyl)-2,6-dinitio-N,N-dipiopylaniline
Synonyms: Planavin
Molecular
Formula:
6 ,N02
Structure: CH3 ~
=\ , CH,CH,CH,
O
NO
Chemical Properties
Molecular Weight: 345.41
Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Solid or liquid
Vapor Density:
Melting Point: 151 to 152°C
Solubility:
Safety Hazard:
AIV-60
-------
Annual U.S.
Production:
Fraction of
Dispersion:
2.0
Estimated as 1.0
Release Rate (million Ibs/yr): 2.0
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost: 0.015
Planavin
Acute Toxicity
LDso
2000 mg/kg
2000 mg/kg
TOXICITY DATA
Animal
rat
mammal
Route
oral
unieported
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-61
-------
Polyacrylamide
CHEMICAL NAME
CAS Number: 9005-05-8
Chemical Name: 2-Propenamide,homopolymer
Synonyms: Polyacrylamide
Acrylainide, polymers
Molecular
Formula: (C3H5NO)n
O
__.... - — .-_
Structure: (CH2 = CH - C - NH2)n
Chemical Properties
Molecular Weight: (71.08)n
Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point:
Solubility: Soluble (H26)
AIV-62
-------
Polyacrylamide
PRODUCTION DATA
Annual U.S.
Production: 12.8 x 106 ibs. Consumption: 12.8 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 1.0 duction Lost: 0.03
Release Rate (million Ibs/yr): 13.2
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogsnicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-63
-------
Polybutenes
CHEMICAL NAME
CAS Number: 9003-29-6
Chemical Name: Butene, homopolymers
Synonyms: Polybutenes
Butene polymers
Molecular
Formula: (C4H8)n
Structure: Any of several thermoplastic isotactic polymers of isobutane of varying molecular
weight; also polymers of butene-1 and butene-2.
Chemical Properties
Molecular Weight: <3000 Physical State: Liquid
Vapor Pressure: Negligible at 25°C Vapor Density:
Boiling Point: Melting Point: -50 to -38°C
Density: 0.83 to 0.89 Solubility: Insoluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
AIV-64
-------
Polybutenes
PRODUCTION DATA
Annual U.S.
Production: 335.0 x 106 lbs.(M.W. <3000) Consumption: 335.0 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 0.98 duction Lost: 0.01S
Release Rate (million Ibs/yr): 333.3
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects: .
AIV-65
-------
Polychlorihated biphenyl
CHEMICAL NAME
CAS Number: (a) 11097-69-1 (b) 11096-82-5
Chemical Name: (a) Aroclor 1254 (b) Atoclor 1260
Synonyms: (a) PCB 1254 Cb) PCB1260
Chlorinated biphenyls Kanechloi
Polychlorinated biphenyls
Molecular
Formula: (exact composition unknown or undetermined)
Structure:
X = Q or H
Chemical Properties (Aroclor 1254)
Molecular Weight:
Vapor Pressure: <1 mm at 25°C
Boiling Point: 365 to 390°C
Density: 1-495 to 1.505 at 65°C/15.5°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Activity towards OH:
Physical State: Liquid-solid
Vapor Density:
Melting Point:
Solubility: Slight (H2O)
= 26 days
Safety Hazard:
Disaster hazard-dangerous-toxic fumes
AIV-66
-------
Polychlorinated biphenyl
Annual U.S.
Production:
Fraction of
Dispersion:
5.495 x 106 Ibs.
1.0
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
0.01
Release Rate (million Ibs/yr): 30.3
Acute Toxicity
Non-lethal Acute Effects:
Liver damage
TOXICITY DATA
Animal
Chronic Toxicity
U.S. Occupational Standard: Aroclor 1254 - 0.5 mg/m3
Aroclor 1242 -1.0 mg/m3
Carcinogenicity:
"KanedubTSOO"
Neoplasm
Lo
Carcinogenicity
KanechloF400
Neoplasm
17gm/kg(49weeks)
2Tgrn7kg732~weeks)
7500mg/kgTlTyears)
Skin effects
PLO
Kanechlor 300"
Neoplasm
TD,
ILo
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
28 mg/kg
18gm/kg(52weeics)
rat
mouse"
human
rat
Route
oral
oral
oral
oral
oral
AIV-67
-------
Polyethylene and co-polymers
CHEMICAL NAME
CAS Number: 9002-88-4
Chemical Name: Ethylene, polymers
Synonyms: Polyethylene
Molecular
Formula: (C2H4)n
H H -i
I I
Structure: —J-C - C
I I
H
H
(chain is linear)
Chemical Properties
Molecular Weight: (28.05)n
Vapor Pressure: Negligible mm at 25°C
Boiling Point: 85 to 110°C
Density: 0.92 average
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 85 to 110°C
Solubility: Insoluble (H2O)
Safety Hazard:
AIV-68
-------
Polyethylene and co-polymers
PRODUCTION DATA
Annual U.S.
Production: 2295.9 x 106 Ibs. Consumption: 2010.8 xlO6 Ibs.
1975: High density polymers-2,289 x 106 Ibs.
Fraction of Low density polymers-4,725 x 106 Ibs.
Dispersion: 1.0 Fraction of Pro-
Release Rate (million Ibs/yr): 2079.7 duction Lost . 0.03
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Neoplasm
TDLo 2120 mg/kg rat implant
330 mg/kg mouse implant
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-69
-------
Polyethylene glycol
CHEMICAL NAME
CAS Number: 25322-68-3
Chemical Name: Polyethylene glycols
Synonyms: Polyoxyethylene Polyglycol ether
Polyglycol
Ethylene oxide polymer
Molecular
Formula: (C2H40)nH2O
Structure: H (OCH2CH2)nOH
Chemical Properties
Molecular Weight: 200 to 6000 Physical State: Liquid
Vapor Pressure: Negligible to 25°C Vapor Density:
Boiling Point: Melting Point: 4 to 10°C
Density: 1.110 to 1.140 at 20°C Solubility: Infinite (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD: 5% of theoretical after 10 days at 20°C with acclimated culture
Total theoretical oxygen demand =1.7 (gm/gm)
Atmospheric Reactivity:
Safety Hazard:
Fire-moderate
AI.V-70
-------
Polyethylene glycol
PRODUCTION DATA
Annual U.S.
Production: 52.4 x 106 Ibs. Consumption: 44.4 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 0.70 auction Lost: 0.015
Release Rate (million Ibs/yr): 31.8
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
420 mg/kg (1 year) mouse intravaginal
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-71
-------
Polyethylene glycol chloride
CHEMICAL NAME
CAS Number: (Not listed in 9th Chemical Index)
Chemical Name:
Synonyms: Poly(ethylene glycoi) chloride
Molecular
Formula: (C2H9O)nHCl
Structure: C1(CH2 - CH2 -O)nH
Chemical Properties
Molecular Weight: 100 to 600 Physical State: Liquid
Vapor Pressure: (low) Vapor Density: 4.31
Boiling Point: Melting Point: -90°C to 20°C (sets)
Density: 1.18 to 1.14at20°C/20°C Solubility: Miscible (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard: Disaster hazard-dangerous-toxic fumes-chlorides
AIV-72
-------
Polyethylene glycol chloride
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 1070mg/kg rat oral
Chronic Toxicity
U.S. Occupational Standard:
Carcinoganicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-73
-------
Polyethylene terephthalate
CHEMICAL NAME
CAS Number: 25038-59-9
Chemical Name: Poly(oxy-l ,2-ethanediyloxycarbonyl-l ,4-phenylenecarbonyl)
Synonyms:
Molecular
Formula:
Structure:
Polyethylene terephthalate
Polyester resin
Poly(oxyethyleneoxyterephthaloyl)
(C,oH804)n
O
O - CH, - CH-, - O - C
O
Chemical Properties
Molecular Weight: (192.17)n
Vapor Pressure:
Boiling Point: Decomposes
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: 265°C
Solubility: Insoluble (H2O)
AIV-74
-------
Polyethylene terephthalate
PRODUCTION DATA
Annual U.S.
Production: 2500 x 106 Ibs.
Fraction of
Dispersion: 1-0
Release Rate (million Ibs/yr): 2487.5
Consumption: 2450 x 10 Ibs.
Fraction of Pro-
duction Lost: 0.015
Acute Toxicity
TOXICITY DATA
Animal
Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinoganicity:
Neoplasm
TDLo
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
50 mg/kg
rat
TLV:
implant
AIV-75
-------
Polypropylene
CHEMICAL NAME
CAS Number: 9003-07-0
Chemical Name: 1-Propene, homopolymer
Synonyms: Polypropylene
Propene, polymers
Molecular
Formula:
(C3H6)n
Structure:
CH,
CH2-C
H
Chemical Properties
Molecular Weight: >40,000 (42.09)n
Vapor Pressure: Negligible at 25°C
Boiling Point:
Density: 0.90
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: 167°C (isotactic)
Solubility: Insoluble (H2O)
AIV-76
-------
Polypropylene
PRODUCTION DATA
Annual U.S.
Production: 2,162 x 10 Ibs. (1973) Consumption: 1,924 x 106lbs. (1973)
Fraction of Fraction of Pro-
Dispersion: 1-0 duction Lost: 0.03
Release Rate (million Ibs/yr): 1563.2
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-77
-------
Polypropylene glycol
CHEMICAL NAME
CAS Number: 25322-69-4
Chemical Name: a-Hydro-O-hydroxypoly [oxy (methyl-l,2-ethanediyl)]
Synonyms: Polypropylene glycols
Poly (propylene oxide)
Polyglycol
Molecular
Formula:
Structure: HO(C3H6O)nH
Chemical Properties
Molecular Weight: (76.11-monomer)400 to 2000 Physical State: Liquid
Vapor Pressure: Vapor Density:
Boiling Point: 189°C (monomer) Melting Point: Does not crystalize
Density: 1.002 to 1.007 Solubility: Infinite (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard: Fire-slight
AIV-78
-------
Polypropylene glycol
PRODUCTION DATA
Annual U.S.
Production: 359.2 x 106 Ibs. Consumption: 302.2 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 0.07 duction Lost: 0.015
Release Rate (million Ibs/yr): 26.6
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 419 mg/kg rat oral
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenlcity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-79
-------
Polystyrene
CHEMICAL NAME
CAS Number: 9003-53-6
Chemical Name: Ethynlbenzene, homopolymei
Synonyms: Styrene, polymers
Polystyrene, straight (thermoplastic resins)
Phenylethylene
Molecular
Formula: (CgHg)n
Vinylbenzene
CHCH,
Structure:
n = 500-2000
Chemical Properties (monomer)
Molecular Weight: 104.16
Vapor Pressure: Negligible
Boiling Point: 145.2°C at 760 mm
Density: 0.9060 at 20°C/4°C
Octanbl/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: -30.63
Solubility: Insoluble (H2O)
AIV-80
-------
Polystyrene
PRODUCTION DATA
Annual U.S.
Production: 3,322 x 106 Ibs. (1973) • Consumption: 3,005 x 10blbs. (1973)
(2,641 x 106lbs., 1975)
Fraction of Fraction of Pro-
Dispersion: 1-0 duction Lost: 0.03
Release Rate (million Ibs/yr): 1471
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcihogenicity:
Neoplasm
TDLo 19mg/kg rat implant
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-81
-------
Polystyrene, thermoplastic resins
CHEMICAL NAME
CAS Number: (Chemical mixture)
Chemical Name:
Synonyms: Polystyrene, rubber modified (thermoplastic resins)
Styrene, polymers
Molecular
Formula: (C8H8)n
Structure: . Mixture of polystyrene and polybutadiene
Chemical Properties
Molecular Weight:
Vapor Pressure:
Boiling Point:
Density: 1.01 to 1.07
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point:
Solubility: Insoluble (H,O)
AIV-82
-------
Polystyrene, thermoplastic resins
PRODUCTION DATA
Annual U.S.
Production: 1647 x 106 ibs. Consumption: 1678 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 1-0 duction Lost: 0.03
Release Rate (million Ibs/yr): 1,727.4
TOXICITY DATA
AcuteToxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity: j Reports of leukemia at rubber plants
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-83
-------
Polytetrafluoroethylene
CHEMICAL NAME
CAS Number: 116-14-3
Chemical Name: Tetrafluoroethene
Synonyms: Teflon
TFE
Perfluoroethylene
Molecular
Formula: C2F4
•: frO--
Structure:
F F'n
Chemical Properties (Monomer)
Molecular Weight: 100.02 Physical State: Gas
Vapor Pressure: Vapor Density:
Boiling Point: -76.3°C at 760 mm Melting Point: -142.5°C
Density: 1.519 at 76.3°C Solubility: Insoluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Resistant to oxidation, moisture, ozone and U.V. radiation
Safety Hazard:
Disaster hazard—dangerous-toxic fumes—fluorides
AIV-84
-------
Polytetrafluoroethylene
PRODUCTION DATA
Annual U.S.
Production: 13.2 x 106 Ibs.
Fraction of
Dispersion:
1-0
Consumption: 14.6xl06lbs.
Fraction of Pro-
duction Lost: 0.03
Release Rate (million Ibs/yr): 15.0
Acute Toxicity
TOXICITY DATA
Dosage Animal
Non-lethal Acute Effects:
Dust can cause "polymer fume fever"
Chronic Toxicity
U.S. Occupational Standard:
Carcinogsnicity:
Neoplasm
TDLo 80mg/kg
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Route
rat
TLV:
implant
AIV-85
-------
Polyvinyl alcohol
CHEMICAL NAME
CAS Number: 9002-89-5
Chemical Name: Ethanol, homopolymer
Synonyms:
Polyvinyl alcohol
PVA
Vinyl alcohol, polymers
Molecular
Formula:
Structure: -+- CH2CH OH-+-
Chemical Properties
Molecular Weight: 25,000 to 300,000
Vapor Pressure:
Boiling Point: >200°C (decomposes)
Density: 1.329
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard:
Fire-slight
Explosion-slight
Physical State: Solid
Vapor Density:
Melting Point:
Solubility: Solubility in H2O increases
with increasing molecular
weight.
AIV-86
-------
Polyvinyl alcohol
PRODUCTION DATA
Annual U.S.
Production: 100 to 141 x 106 ibs. (1974) Consumption: 141.1 x 106 Ibs. (1975)
Fraction of
Dispersion: 1.0
Release Rate (million Ibs/yr): 104.0
Fraction of Pro-
duction Lost: 0.03
Acute f oxicity
TOXICITY DATA
Dosage Animal
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
TDLo
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
2500 mg/kg
rat
TLV:
Route
subcutaneous
AIV-87
-------
Polyvinyl chloride
CHEMICAL NAME
CAS Number: 9002-86-2
Chemical Name: Chloroethylene, polymers
Synonyms: Polyvinyl chloride
PVC
Molecular
Formula: (C2H3Cl)n
. H H
Structure: 4- C — C
\ H a
Chemical Properties
Molecular Weight: 60,000 Physical State: Solid
Vapor Pressure: Negligible at 25°C Vapor Density:
Boiling Point: Decomposes Melting Point:
Density: 1.406 Solubility: Insoluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Photochemical degradation: Biodegradable, photodegradable
Unreactive to RO2,03
Hydrolysis is slow (rates unknown)
Safety Hazard:
Disaster hazard-dangerous-toxic fumes
AIV-88
-------
Polyvinyl chloride
PRODUCTION DATA
Annual U.S.
Production:
Fraction of
Dispersion:
4,562 x 10°lbs. (1973)
1.0
Consumption:
Fraction of Pro-
duction Lost:
4,586 x 10° Ibs. (1973)
(3,615 x!06lbs. in 1975)
0.03
Release Rate (million Ibs/yr): 4385.7
Acute Toxicity
Non-lethal Acute Effects:
Dermatitis
TOXICITY DATA
Dosage Animal
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity: Carcinogen (sarcomas, granulomas)
Neoplasm:
TDLo
Mutagenicity:
Teratogenicity:
Positive
Other Chronic Effects:
100 mg/kg
rat
rat
TLV:
Route
implant
intraperitoneal
AIV-89
-------
Princep
CHEMICAL NAME
CAS Number: 122-34-9
Chemical Name: 2-Chloro4,6-bis(ethylamino)-s-triazine
Synonyms: 2-Chloro-4,6-bis(dimethy Iamino)-s-triazine
Molecular
Formula: C7Hi2ClNs
Cl
Structure:
CH3-CH2-N N N-CH2-CH3
H H
Chemical Properties
Molecular Weight: 221.75
Vapor Pressure: 6.1 x 10"9 mm at 20°C
Boiling Point:
Density: 1.0956
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Decomposed by ultraviolet irradiation
Physical State: Liquid
Vapor Density:
Melting Point: 225 to 227°C
Solubility: 5 ppm H2O at 20°C
Safety Hazard:
Disaster hazard-dangerous—chlorides
AIV-90
-------
Princep
PRODUCTION DATA
Annual U.S.
Production: 5 x 10 Ibs. Consumption:
Fraction of Fraction of Pro-
Dispersion: Estimated as 1.0 duction Lost: 0.015
Release Rate (million Ibs/yr): 5.0
TOXIC!TY DATA
Acute Toxicity Dosage Animal Route
LD5o 5000mg/kg rat oral
No toxicity in man reported
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-91
-------
Propachlor
CHEMICAL NAME
CAS Number: 1918-16-7
Chemical Name: 2-Chloro-N-
-------
Propachlor
PRODUCTION DATA
Annual U.S.
Production: 23xl06lbs. Consumption: 23 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: Estimated as 1.0 duction Lost: 0.01
Release Rate (million Ibs/yr): 23.2
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 1200 mg/kg rat oral
380 mg/kg rabbit skin
800 mg/kg mammal unreported
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
Skin and eye irritant
AIV-93
-------
Propane
CAS Number: 74-986
Chemical Name: Propane
Synonyms: Dimethyl methane
Molecular
Formula:
CHEMICAL NAME
Structure: CH3 - CH2 - CH3
Chemical Properties
Molecular Weight: 44.09
Vapor Pressure: 7095 mm at 25°C
Boiling Point: -42.07°C at 760 mm
Density: 0.5852 at -44.5°C/4°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Gas
Vapor Density: 1.56
Melting Point: -189.9°C
Solubility: H9gm/l(H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts vigorously with oxidizing materials
Safety Hazard:
Fire-highly dangerous
Explosion—severe
AIV-94
-------
Propane
PRODUCTION DATA
Annual U.S.
Production: 9608.3 x 106 Ibs. Consumption: 9608.3 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 0 auction Lost: 0.01
Release Rate (million Ibs/yr): 96.1
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Non-lethal Acute Effects:
Paralysis by inhalation of concentrated gas
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 1000 ppm
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV: 1000 ppm
Other Chronic Effects:
AIV-95
-------
Propanil
CHEMICAL NAME
CAS Number: 709-98-8
Chemical Name: N-(3,4-Dichlorophenyl)propanamide
Synonyms: Propanil
3,4-Dichloiopropionanilide
Molecular
Formula:
C9H9C12NO
Cl
V^
o
/ NK
Structure: Cl -? V N - C -
\ — / I
H
CH2 - CH3
Chemical Properties
Molecular Weight: 218.09
Vapor Pressure:
Boiling Point: 91 to 95°C (technical)
Density: 1.25at25°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Physical State: Solid (pure compound)
Liquid (technical compound)
Vapor Density:
Melting Point: 85 to 89°C (pure)
Solubility: 0.05%inH2O
Safety Hazard:
Disaster hazard-dangerous-chlorides
AIV-96
-------
Annual U.S.
Production:
Fraction of
Dispersion:
6.0 x 10° Ibs.
Estimated as 1.0
Release Rate (million Ibs/yr): 6.0
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
0.015
Propanil
Acute Toxicity
LDSO
TOXICITY DATA
Dosage
1500 mg/kg
560 mg/kg
1300 rag/kg
1217 mg/kg
500 mg/kg
Animal
rat
rat
rat
dog
rabbit
Route
oral
oral
oral
oral
umeported
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-97
-------
Propargyi alcohol
CHEMICAL NAME
CAS Number: 107-19-7
Chemical Name: 2 Propyn-1-ol
Synonyms: Propiolic alcohol
Molecular
Formula: C3H4O
Structure: HC = C - CH2OH
Chemical Properties
Molecular Weight: 56.07
Vapor Pressure:
Boiling Point: 113.6°C at 760mm
Density: 0.9715 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Volatile liquid
Vapor Density:
Melting Point: -48°C
Solubility: Soluble (H2O)
ATV-98
-------
Propargyl alcohol
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 0.07 mg/kg rat oral
LCLo I 2000 mg/kg mouse inhalation
Non-lethal Acute Effects:
CNS depressant
Irritant to skin and mucous membranes
Chronic Toxicity
U.S. Occupational Standard: (air) 1 ppm (skin)
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-99
-------
Propazine
CHEMICAL NAME
CAS Number: 139-10-2
Chemical Name: 2-Chloro-4,6-bis(isopropylamino)-s-triazine
Synonyms: Propazine
Molecular
Formula: C9H16C1NS
Cl
Structure:
CH,
I I
CH3H
CH,
H-C-N N N-C-H
I I
H CH,
Chemical Properties
Molecular Weight: 229.74
Vapor Pressure: 2.9 x 10"8 mm at 20°C
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 212 to 214°C
Solubility: Slightly soluble
(8.6 ppm H2O)
Safety Hazard:
AIV-100
-------
Propazine
PRODUCTION DATA
Annual U.S.
Production: 4.0 x 106 Ibs. Consumption:
Fraction of Fraction of Pro-
Dispersion: Estimated as 1.0 duction Lost: 0.015
Release Rate (million Ibs/yr): 4.0
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSo 485 mg/kg rat oral
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Neoplasm
TDLo 22 gm/kg (82 weeks) rat oral
750 mg/kg (15 weeks) rat subcutaneous
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-101
-------
Propiolactone
CHEMICAL NAME
CAS Number: 57.57.8
Chemical Name: 2-Oxetanone
Synonyms: 0-Propiolactone 3-Hydroxypropionic acid, lactone
Hydraacrylic acid 0 lactone
Propanolide
Molecular
Formula: C3H4O2
-Q
Structure:
Chemical Properties
Molecular Weight: 72.06 Physical State: Liquid
Vapor Pressure: Vapor Density:
Boiling Point: 162°C (decomposes) Melting Point: -33.4°C
Density: 1.1460at'20°C/5°C Solubility: Decomposes (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-moderate
AIV-102
-------
Propiolactone
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
Acute Toxicity
LD50
TOXICITY DATA
Dosage Animal
345 mg/kg mouse
Route
intravenous
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Carcinogen
TDLO
Neoplastic effects:
TDLo
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
12,865 mg/kg (62 weeks) hamster
56,400 mg/kg (141 weeks) guinea pigs
3500 mg/kg (70 weeks) rat
20 mg/kg (34 weeks) rat
180 mg/kg (30 weeks) rat
8100 mg/kg (27 weeks) mouse
69 mg/kg (43 weeks) mouse
40 mg/kg mouse
tLV:
skin
skin
oral
subcutaneous
in tra trachea!
skin
subcutaneous
intravenous
AIV-103
-------
Propionaldehyde
CHEMICAL NAME
CAS Number: 123-38-6
Chemical Name: Propionaldehyde
Synonyms: Propyl aldehyde Propanal
Piopylic aldehyde Propionic aldehyde
Molecular
Formula: C3H6O
O
II
Structure: CH3 - CH2 - C - H
Chemical Properties
Molecular Weight: 58.08 Physical State: Liquid
Vapor Pressure: 10mmat25°C Vapor Density: 2.0
Boiling Point: 48.8°C Melting Point: -81°C
Density: 0.8058 at 20°C/4°C Solubility: Soluble (H2O)
Octanol/Water Parti-
tion Coefficient: 0.38
Environmental Persistence
BOD: 95% of theoretical
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire—dangerous
AIV-104
-------
Propionaldehyde
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
TOXICITY DATA
Acute Toxicity
LDso
TC
Lo
Dosage
820 mg/kg
680 mg/kg
800 mg/kg
800 mg/kg
3400 mg/kg
8000 ppm (4 hours)
Non-lethal Acute Effects:
Local irritant to respiratory tract
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Animal
rat
mouse
rat
mouse
rabbit
rat
Route
subcutaneous
subcutaneous
oral
oral
skin
inhalation
TLV:
AIV-105
-------
Propionic acid
CHEMICAL NAME
CAS Number: 79-094
Chemical Name: Propionic acid
Synonyms: Methylacetic acid
Propanoic acid
Molecular
Formula: C3H6O2
Structure:
CH3 - CH2 - C - OH
Chemical Properties
Molecular Weight: 74.09
Vapor Pressure: 4.49 at 25°C
Boiling Point: 141°C at 760 mm
Density: 0.992
Octanoi/Water Parti-
tion Coefficient: 0.52
Environmental Persistence
BOD: 56% of theoretical
Atmospheric Reactivity:
Safety Hazard: Fire -moderate
Physical State: Liquid
Vapor Density: 2.56
Melting Point: -20.8°C
Solubility: Infinite (H2O)
AIV-106
-------
Propionic acid
PRODUCTION DATA
Annual U.S.
Production: 60.4 x 106 Ibs. (1973) Consumption: 60.4 x 106 Ibs. (1973)
(65 x 106 Ibs., 1975)
Fraction of Fraction of Pro-
Dispersion: duction Lost: 0.015
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 1510mg/kg rat oral
1370mg/kg mouse oral
625 mg/kg mouse intravenous
1900 mg/kg rabbit oral
500 mg/kg rabbit . skin
Non-lethal Acute Effects:
Local irritant to eyes, skin, and mucous membranes
Chronic Toxicity
U.S. Occupational Standard:
Carcinogen icity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-107
-------
Propyl acetate
CHEMICAL NAME
CAS Number: 109-604
Chemical Name: Acetic acid, propyl ester
Synonyms: n-Propyl acetate
Propyl ester of acetic acid
Molecular
Formula: CSH10O2
O
y
Structure: CH3 - C - O - CH2 - CH2 - CH3
Chemical Properties >
Molecular Weight: 102.13 Physical State: Liquid
Vapor Pressure: 40 mm at 28.8°C, Vapor Density: 3.52
Boiling Point: T6l.6°C at 760mm Melting Point: -95°C
Density: 0.8898 at 20°C/4°C Solubility: Slightly (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD: 72% of theoretical after 20 days at 20°C
Total theoretical oxygen demand = 2.04 gm/gm
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-dangerous
Explosion-moderate
AIV-108
-------
Propyl acetate
PRODUCTION DATA
Annual U.S.
Production: 32.4 x 106 Ibs.
Fraction of
Dispersion: 0.75
Release Rate (million Ibs/yr): 24.8
Consumption: 32.4 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.015
Acute Toxicity
LD50
LCLo
Non-lethal Acute Effects:
Conjunctivitis
Irritation of skin
TOXICITY DATA
Animal
6630mg/kg rabbit
8000 ppm (4 hours) rat
Route
oral
inhalation
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 200 ppm
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV: 200 ppm
AIV-109
-------
Propyl alcohol
CHEMICAL NAME
CAS Number: 71-23-8
Chemical Name' Propyl alcohol
Synonyms: Ethyl carbinol
Propan-1-ol
1-Propanol
Molecular
Formula: C3H8O
Structure: CH3 - CH2 - CH2 - OH
Chemical Properties
Molecular Weight: 60.11 Physical State: Liquid
Vapor Pressure: 19.8 mm at 25°C Vapor Density: 2.07
Boiling Point: 97°Cat760mm Melting Point: -126.5°C
Density: 0.8035 at 20°C/4°C Solubility: Infinite (H2O)
Octanol/Water Parti-
tion Coefficient: 0.74
Environmental Persistence
BOD: 85% of theoretical after 20 days at 20° C
Total theoretical oxygen demand = 2.40 gm/gm
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-dangerous
. Explosion-moderate
AIV-110
-------
Propyl alcohol
PRODUCTION DATA
Annual U.S.
Production: 83.1 x 106 Ibs.
Fraction of
Dispersion: 0-75
Release Rate (million Ibs/yr): 63.6
Consumption: 83.1 x 106 Ibs.
Fraction of Pro-
duction Lost:
0.015
TOXICITY DATA
Acute Toxicity
LDSO
LCLO
Non-lethal Acute Effects:
Conjunctivitis
Vomiting
Anemia
Dosage
1.9g/kg
1870 mg/kg
3230 mg/kg
5700 mg/kg
140 mg/kg
3500 mg/kg
5 mg/kg .
4000 ppm (4 hours)
Animal
rats
rats
mouse
woman
mouse
rabbit
mammal
rat
Route
oral
oral
subcutaneous
oral
oral
oral
subcutaneous
inhalation
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 200 ppm
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV: 200 ppm
AIV-111
-------
Propylamine
CHEMICAL NAME
CAS Number: 107-10-8
Chemical Name: Propylamine
Synonyms: 1-Aminopropane
Molecular
Formula: C3H9N
Structure:
CH3 - CH2 - CH2 - NH2
Chemical Properties
Molecular Weight: 59.11
Vapor Pressure: 248 mm at 20°C
Boiling Point: 47.8°C at 760 mm
Density: 0.7173 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Fire-dangerous
Physical State: Liquid
Vapor Density:
Melting Point: -83.0°C
Solubility: Soluble (H2O)
AIV-112
-------
Propylamine
PRODUCTION DATA
Annual U.S.
Production: 0.2 x 10° ibs. (1969) Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost: 0.015
Release Rate (million Ibs/yr):
TOXICITYDATA
Acute Toxicity Dosage Animal Route
LDSO 560mg/kg rabbit skin
LDLo 570mg/kg rat oral.
LC50 . 2310 ppm (4 hours) rat inhalation
Non-lethal Acute Effects:
Irritant
Skin sensitizer
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagehicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-113
-------
Propyl chloride
CHEMICAL NAME
CAS Number: 540-54-5
Chemical Name: 1-Chloropiopane
Synonyms: n-Propylchloride
Molecular
Formula: C3H7C1
Structure: CH3 - CH2 - CH2 - Cl
Chemical Properties
Molecular Weight: 78.54 Physical State: Liquid
Vapor Pressure: 348.8 mm at 25°C Vapor Density: 2.71
Boiling Point: 46.6°C at 760 mm Melting Point: -122.8°C
Density: 0.8909 at 20°C/4°C Solubility: Slightly (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-dangerous
Explosion—moderate
AIV-114
-------
Propyl chloride
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Non-lethal Acute Effects:
Irritant to mucous membranes
Narcotic at high concentrations
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronig Effects:
AIV-115
-------
Propylene
CHEMICAL NAME
CAS Number: 115-07-1
Chemical Name: Propene
Synonyms: Propylene
Methylethylene
Molecular
Formula:
Structure:
CH3 - CH = CH2
Chemical Properties
Molecular Weight: 42.09
Vapor Pressure: 8582 mm at 25°C
Boiling Point: -47.4°C at 760 mm
Density: 0.5139 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Gas
Vapor Density: 1-46
Melting Point: -185.2°C
Solubility: Slightly (0.78 gm/1 H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire—dangerous
Explosion - moderate
AIV-116
-------
Propylene
PRODUCTION DATA
Annual U.S. q
Production: 22 to 24 x 10* Ibs. (1974) Consumption: 22 to 24 x 1
-------
Propylene chlorohydrin
CHEMICAL NAME
CAS Number: 78-89-7
Chemical Name: 2-Chloro-l-propanol
Synonyms: Propylene chlorohydrin
2-Chloropropyl alcohol
Molecular
Formula: C3H7C1O
H
I
Structure: CH2 - C - CH3
OH Cl
Chemical Properties
Molecular Weight: 94.54 Physical State: Liquid
Vapor Pressure: 4.9 mm at 20°C Vapor Density: 3.26
Boiling Point: 133tol34°cf Melting Point:
Density: 1.1128 at 20°C/20°C Solubility: Soluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-moderate
Disaster hazard-dangerous-toxic fumes-chlorides
AIV-118
-------
Propylene chlorohydrin
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: ductiori Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LD50 220 mg/kg rat oral
480mg/kg rabbit skin
720 mg/kg guinea pig oral
LCLo 500 mg/kg rat inhalation
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-119
-------
Propylene glycol
CHEMICAL NAME
CAS Number: 57-55-6
Chemical Name: l ,2-Propanediol
Synonyms: Propyleneglycol
1,2-Dihydroxy propane
Molecular
Formula: C3H8O2
OH
I
Structure: HO - CH, - C •- CH,
1
H
Chemical Properties
Molecular Weight: 76.11 Physical State: Liquid
Vapor Pressure: 1 mm at 45.5°C Vapor Density: 2.62
Boiling Point: 187.3°C Melting Point:
Density: 1.0361 at 20°C/4°C Solubility: Infinite (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD: 79% of theoretical after 20 days at 20°C
Total theoretical oxygen demand = 1.68 gm/gm
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-moderate
AIV-120
-------
Propylene glycol
PRODUCTION DATA
Annual U.S.
Production: 562.6 x 106 Ibs.
Fraction of
Dispersion: 0.32
Release Rate (million Ibs/yr): 154.0
Consumption: 454.8 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.015
TOXICITY DATA
Acute Toxicity
LD50
Dosage
945 mg/kg
283 mg/kg
195 mg/kg
890 mg/kg
471 mg/kg
285 mg/kg
322 mg/kg
220 mg/kg
821 mg/kg
322 mg/kg
Non-lethal Acute Effects:
Local irritant
Allergen
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Animal
rat
rat
rat
mouse
mouse
mouse
mouse
rabbit
hamster
hamster
Route
oral
intraperitoneal
intravenous
oral
intraperitoneal
subcutaneous
intravenous
intravenous
oral
intraperitoneal
TLV:
AIV-121
-------
Propyleneimine
CHEMICAL NAME
CAS Number: 75-55-8
Chemical Name: 2-Methylaziridine
Synonyms: Propyleneimine
1,2-Propyleneimine
Molecular
Formula: CaH7N
H
J
N
/_\
Structure: H,C - C - CH,
*• I J
Chemical Properties
Molecular Weight: 58.10 Physical State: Liquid
Vapor Pressure: Vapor Density: 2.0
Boiling Point: 66 to 67°C Melting Point:
Density: 0.81 at 25°C/25°C Solubility: Soluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-moderate
Disaster hazard-dangerous-toxic fumes-NOx
AIV-122
-------
Propyleneimine
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LD50 19 mg/kg rat oral
43 mg/kg guinea pig skin
LCLo 500 ppm (4 hours) rat inhalation
500 ppm (1 hour) guinea pig inhalation
Chronic Toxicity
U.S. Occupational Standard: (aii) TWA 2 ppm (skinj
Carcinogenicity: Carcinogen
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-123
-------
Propylene oxide
CHEMICAL NAME
CAS Number: 75-56-9
Chemical Name: Propene oxide
Synonyms: Propylene oxide
Methyl oxiiane 1
Molecular
Formula: C3H6O
O
1,2-Epoxy propane
Structure: CH2 - CH- CH3
Chemical Properties
Molecular Weight: 58.08
Vapor Pressure: 596 mm at 25°C
Boiling Point: 33.9°C at 760 mm
Density: 0.8394 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD: 12% of theoretical after 10 days at 20°C
Total theoretical oxygen demand = 2.2 gm/gm
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-highly dangerous
Explosion-highly dangerous
Physical State: Liquid
Vapor Density: 2.0
Melting Point: -104.4°C
Solubility: Soluble (650 gm/1 H2O)
AIV-124
-------
Propylene oxide
PRODUCTION DATA
Annual U.S.
Production:
Fraction of
Dispersion:
1640xl06lbs.
0.01
Consumption: 1620 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.015
Release Rate (million Ibs/yr): 40.8
TOXICITY DATA
Acute Toxicity
LD50
LC50
LCLo
930 mg/kg
1500 mg/kg
690 mg/kg
1740 ppm (4 hours)
4000 ppm (4 hours)
2005 ppm (4 houis)
Animal
rat
rabbit
guinea pig
mouse
rat
dog
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 100 ppm
Carcinogenicity: Experimentation carcinogen
Mutagenicity:
Teratogenicity:
TLV:
Other Chronic Effects:
Moderately severe effects from inhalation and ingestion
Route
oral
skin
oral
.inhalation
inhalation
inhalation
AIV-125
-------
Pyridine
CAS Number: 110-86-1
Chemical Name: Pyridine
Synonyms: Azine
Azabenzene
Molecular
Formula: C5HSN
CHEMICAL NAME
Structure:
Chemical Properties
Molecular Weight: 79.10
Vapor Pressure: 20.3 mm at 25°C
Boiling Point: 115.3°C
Density: 0.982 at 20°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Liquid
Vapor Density: 2.73
Melting Point: -42.0°C
Solubility: Infinite (H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-dangerous
Explosion-severe
Disaster hazard-dangerous-toxic fumes-cyanides
AIV-126
-------
Pyridine
PRODUCTION DATA
Annual U.S.
Production:
Fraction of
Dispersion:
>60 x 10' Ibs. (1976 capacity)
Consumption:
Fraction of Pro-
duction Lost: 0.015
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity
LD50
LCSO
LDLo
Dosage
891 mg/kg
1000 mg/kg
1121 mg/kg
4000 ppm (4 hours)
1200 mg/kg
870 mg/kg
4000 mg/kg
Animal
iat
rat
rabbit
rat
mouse
guinea pig
guinea pig
Route
oral
subcutaneous
skin
inhalation
intraperitoneal
intraperitoneal
oral
Non-lethal Acute Effects:
Local irritant
CNS depressant
Kidney and liver damage
Gastrointestinal upset
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 5 ppm
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV: 5 ppm
AIV-127
-------
Randox
CHEMICAL NAME
CAS Number: 93-71-0
Chemical Name: N,N-Diallyl-2-chloroacetamide
Synonyms: 2-Chloro-N,N-diallyl acetamide
Molecular
Formula: C8H12C1NO
O F5
2 - CH = CH2
Structure: Cl - CH2 - C - N
CH2 - CH = CH2
Chemical Properties
Molecular Weight: 173.7
Vapor Pressure: <20 mm at 25°C
Boiling Point: 74°C at 0.3 mm
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Liquid
Vapor Density:
Melting Point:
Solubility: Slightly (H2O)
Safety Hazard:
Disaster hazard-dangerous-chlorides
AIV-128
-------
Randox
PRODUCTION DATA
Annual U.S. 6
Production: 10 x 10 lbs- Consumption:
Fraction of Fraction of Pro-
Dispersion: Estimated as 1.0 duction Lost:
Release Rate (million Ibs/yr): 10.0
TOXICITYDATA
Acute Toxicity Dosage Animal Route
LDSO . 700mg/kg rat oral
360 mg/kg rat skin
700 mg/kg mammal umeported
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: , TLV:
Other Chronic Effects: Irritant to skin and eyes
AIV-129
-------
Resorcinol
CHEMICAL NAME
CAS Number: 108-46-3
Chemical Name: Resorcinol
Synonyms: 1,3-Benzendiol
Resorcin
Dihydroxybenzene
Molecular
Formula: C6H6O2
Structure:
OH
Chemical Properties
Molecular Weight: 110.12
Vapor Pressure: 1 mm at 108.4°C
Boiling Point: 276.5°C at 760 mm
Density: 1.285 at 15°C
Octanol/Water Parti-
tion Coefficient: 0.80
Physical State: Solid
Vapor Density: 3.79
Melting Point: 110.7°C
Solubility: Soluble (H2O)
Environmental Persistence
BOD: 61 % of theoretical
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-slight
AIV-130
-------
Resorcinol
PRODUCTION DATA
Annual U.S.
Production: 35 x 106 Ibs. (1976 capacity) Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost: 0.015
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity . Dosage Animal Route
LDSO 301 mg/kg rat oral
340 mg/kg mouse subcutaneous
LDLo 270 mg/kg frog parenteral
Non-lethal Acute Effects:
Dermatitis
Eye irritant
Methemoglobinemia
Convulsions
Tachycardia
Jaundice
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-131
-------
Ronnel
CHEMICAL NAME
CAS Number: 299-84-3
Chemical Name: Phosphorothioic acid, O,0-dimethyl-O-(2,4,5-trichlorophenyl)ester
Synonyms: Ronnel
Fenchlorphos
O,O-Dimethyl-O-(2,4,5-tiichlotophenyl) phosphorothioate
Molecular
Formula:
Structure:
Chemical Properties
Molecular Weight: 321.6
Vapor Pressure: 8 x 10 3 mm at 25°C
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 41°C
Solubility:
Safety Hazard:
AIV-132
-------
Ronnel
Annual U.S.
Production: 2.0 x 106 Ibs.
Fraction of
Dispersion: Estimated as 1.0
Release Rate (million Ibs/yr): 2.0
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
0.015
Acute Toxicity
LDSO
TOXICITY DATA
Dosage
1760 mg/kg
1000 mg/kg
906 mg/kg
2000 mg/kg
2823 mg/kg
118 mg/kg
80 mg/kg
400 mg/kg
Non-lethal Acute Effects:
Edema of lungs
Convulsions
Heart attack
Vomiting
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 10 mg/m3
Carcinogenicity:
Animal
rat
rabbit
rat
rat
rat
mouse
wild bird
mammal
Route
oral
skin
oral
skin
intiaperitoneal
intraperitoneal
oral
unre ported
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV: ISmg/m3
AIV-133
-------
Ruelene
CHEMICAL NAME
CAS Number: 299-86-5
Chemical Name: Methyl phosphoramidic acid, 4-tert-butyl-2-chlorophenyl methyl ester
Synonyms: Ruelene
4-t-Butyl-2-chlorophenyl-O-methyl methyl phosphoroamidate
Molecular
Formula: C12H19aNO3P
OCH
_
O - P
NH - CH3
Chemical Properties
Molecular Weight: 291.74
Vapor Pressure:
Boiling Point:
Density: T6
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 61.8°C
Solubility: 0.5 gm/100mlH2Oat25 C
Safety Hazard:
AIV-134
-------
Ruelene
Annual U.S.
Production: 2.0 x 106 Ibs.
Fraction of
Dispersion: Estimated as 1.0
Release Rate (million Ibs/yr): 2.0
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
0.015
Acute Toxicity
LD50
TOXICITY DATA
. 770 mg/kg
460 mg/kg
770 mg/kg
400 mg/kg
1000 mg/kg
218 mg/kg
100 mg/kg
Animal
rat
rat
'rat
rabbit
guinea pig
chicken
wild bird
Route
oral
oral
unreported
oral.
oral
oral
oral
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 5 mg/m3
Carcinogehicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Moderate irritant to eyes
Emesis
TLV:
AIV-135
-------
Salicylic acid
CHEMICAL NAME
CAS Number: 69-72-7
Chemical Name: Salicylic acid
Synonyms: o-Hydroxybenzoic acid
Molecular
Formula: C7H6O3
OH
COOH
Structure:
Chemical Properties
Molecular Weight: 138.13
Vapor Pressure: 1 mm at 113.7°C
Boiling Point: 211°C at 20 mm (sublimes)
Density: 1.443 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient: 2.32
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density: 4.8
Melting Point: 158 to 161°C
Solubility: Slightly (H2O)
Very soluble (hot H2O)
Safety Hazard:
Fire-slight
Explosion-slight
AIV-136
-------
Salicylic acid
PRODUCTION DATA
Annual U.S.
Production:
Fraction of
Dispersion:
35.0 x 106 Ibs. (acetosalicate)
1.0
Consumption: 35.2 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.03
Release Rate (million Ibs/yr): 35.9
TOXICITY DATA
Acute Toxicity
LD50
891 mg/kg
520 mg/kg
700 mg/kg
450 mg/kg
991 mg/kg
300 mg/kg
1300 mg/kg
900 mg/kg
850 mg/kg
500 mg/kg
Non-lethal Acute Effects:
Nausea
Rapid pulse
Skin eruptions
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Animal
rat
mouse
rat
dog
dog
dog
rabbit
guinea pig
guinea pig
frog
Route
oral
subcutaneous
subcutaneous
oral
intraperitoneal
subcutaneous
oral
intraperitoneal
subcutaneous
subcutaneous
TLV:
AIV-137
-------
Silvex
CHEMICAL NAME
CAS Number: 93-72-1
Chemical Name: 2-(2,4>S-Trichlor-phenoxy)propionic acid
Synonyms: 2,4,5-TCPPA
Molecular
Formula: C9h7Cl3O3
Cl
Structure: Cl
Cl
__
OH
Chemical Properties
Molecular Weight: 269.5
Vapor Pressure:
Boiling Point:
Density: l7640~
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 180.4 to 181.6°C
Solubility: Slightly (140 ppm H2O at 25 C)
Safety Hazard:
Disaster hazard—dangerous-chlorides
AIV-138
-------
Silvex
PRODUCTION DATA
Annual U.S.
Production: 3 x 106 Ibs. Consumption:
Fraction of Fraction of Pro- _
Dispersion: Estimated as 1.0 duction Lost: 0.015
Release Rate (million Ibs/yr): 3.0
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSo 375-1200 mg/kg rat oral
650 mg/kg rat oral
650 mg/kg mammal oral
650 mg/kg mammal unreported
Low toxicity to man
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-139
-------
Sodium acetate
CHEMICAL NAME
CAS Number: 127-09-3
Chemical Name: Acetic acid, sodium salt
Synonyms:
Molecular
Formula: C2H3O2 * Na
O
Structure: CH3 - C
Chemical Properties
Molecular Weight: 83.06
Vapor Pressure:
Boiling Point:
Density: 1.528
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD: 45% of theoretical
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: 324°C
Solubility: Soluble (H2O)
AIV-140
-------
Sodium acetate
PRODUCTION DATA
Annual U.S.
Production: 16.5 x 106 ibs. (1968) Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost: 0.015
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 3530mg/kg rat oral
8000 mg/kg mouse subcutaneous
335 mg/kg mouse intravenous
LDLo 3000 mg/kg dog intravenous
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-141
-------
Sodium benzoate
CHEMICAL NAME
CAS Number: 532-32-1
Chemical Name: Benzole acid, sodium salt
Synonyms: Benzoate of soda
Molecular
Formula: C7HSO2 -Na
Structure:
O
Chemical Properties
Molecular Weight: 144.1
Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point:
Solubility: Soluble (H2O)
AIV-142
-------
Sodium benzoate
PRODUCTION DATA
Annual U.S.
Production: ca. 6x10 Ibs. (1975) Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost: 0.015
Release Rate (million Ibs/yr):
TOXICITYDATA
Acute Toxicity Dosage Animal Route
LDSO 4100 mg/kg rat oral
2000mg/kg rabbit oral
LDLo 2000 mg/kg rabbit . subcutaneous
1400 mg/kg guinea pig intiapeiitoneal
100 mg/kg frog subcutaneous
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-143
-------
Sodium carboxymethylcellulose
CHEMICAL NAME
CAS Number: 9004-324
Chemical Name: Cellulose, caiboxymethyl ether, sodium salt
Synonyms: Sodium carboxymethylcellulose Cellulose gum
CMC CM cellulose
Sodium cellulose glycolate
Molecular
Formula: (Exact composition unknown or undetermined)
Structure: A synthetic cellulose gum containing 0.4 to 1.5 sodium carboxymethyl group
(-CH2COO Na) per glucose unit of the cellulose
Chemical Properties
Molecular Weight: ca. 21,000 to 500,000 Physical State: Solid
Vapor Pressure: < 0.6 mm at 25°C Vapor Density:
Boiling Point: Decomposes Melting Point:
Density: Solubility: Soluble (H26)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
AIV-144
-------
Sodium carboxymethylcellulose
PRODUCTION DATA
Annual U.S.
Production: 69.0 x 106 Ibs. Consumption: 69.0 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 1-0 duction Lost: 0.03
Release Rate (million Ibs/yr): 71.0
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Neoplasm:
TDLo 8600 mg/kg (19 weeks) rat . subcutaneous
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-145
-------
Sodium chloroacetate
CHEMICAL NAME
CAS Number: 3926-62-3
Chemical Name: Chloroacetic acid, sodium salt
Synonyms:
Molecular
Formula: C2H2ClO2-Na
O
n
Structure: C1CH2 _ c _ o(-)Na<+>
Chemical Properties
Molecular Weight: 116.49 Physical State: Solid
Vapor Pressure: Vapor Density:
Boiling Point: 200°C (decomposes) Melting Point:
Density: Solubility: Soluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
AIV-146
-------
Sodium chloroacetate
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 76 mg/kg rat oral
165 mg/kg mouse oral
109 mg/kg mouse intravenous
80 mg/kg guinea pig oral
LDLo 100 mg/kg mammal oral
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-147
-------
Sodium formate
CHEMICAL NAME
CAS Number: 141-53-7
Chemical Name: Formic acid, sodium salt
Synonyms:
Molecular
Formula: CHO2' Na
O
Structure: HC
Na
<+>
Chemical Properties
Molecular Weight: 68.01
Vapor Pressure:
Boiling Point: 253°C (decomposes)
Density: l.92at20°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD: 42% of theoretical
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 253°C
Solubility: Soluble (440 gm/1 H2O)
Safety Hazard:
Fire-slight
AIV-148
-------
Sodium formate
PRODUCTION DATA
Annual U.S.
Production:
Fraction of
Dispersion:
32.0 x 106 Ibs.
0.70
Consumption: 32.0 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.015
Release Rate (million Ibs/yr): 22.9
TOXICITY DATA
Acute Toxicity
LD
Lo
Dosage
807 mg/kg
2500 mg/kg
4000 mg/kg
3000 mg/kg
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Animal
mouse
mouse
dog
dog
TLV:
Route
intravenous
unreported
oral
intravenous
AIV-149
-------
Sodium phenate
CHEMICAL NAME
CAS Number: 139-02-6
Chemical Name: Phenol, sodium salt
Synonyms:
Molecular
Formula:
Sodium phenolate
Sodium carbolate
Sodium phenylate
C6H5NaO
Structure:
Chemical Properties
Molecular Weight: 116.0
Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Physical State: Solid
Vapor Density:
Melting Point:
Solubility: Soluble (H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Decomposed by CO2 of the air
Safety Hazard:
AIV-150
-------
Sodium phenate
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
Acute toxicity
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TOXICITY DATA
Animal
TLV:
Route
AIV-151
-------
Sorbic acid
CHEMICAL NAME
CAS Number: 11044-1
Chemical Name: Sorbic acid
Synonyms: 2.4-Hexadienoicacid
1,3-Pentadiene-l-carboxylic acid
2-Propenylacrylic acid
Molecular
Formula: C6H8O2
O
H
Structure:
CH3
\
\
c = c
OH
C = C
_/ \_
H H
(trans-trans)
Chemical Properties -(tian&.tians)
Molecular Weight: 112.12
Vapor Pressure: <0.01 mm at 20°C
Boiling Point: 228°C (decomposes)
Density: 1.204 at 19°C/4°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Solid
Vapor Density: 3.87
Melting Point: 134.5°C
Solubility: Soluble (2.5 gm/1 H2O)
Environmental Persistence
BOD: 70% of theoretical after 10 days at 20°C
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire—slight
AIV-152
-------
Sorbic acid
PRODUCTION DATA
Annual U.S.
Production:
40 x 10 Ibs.
Fraction of
Dispersion: 0-^0
Release Rate (million Ibs/yr): 20.6
Consumption: 40 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.015
TOXICITY DATA
Acute Toxicity
LDLo
LDSO
Dosage
5000 mg/kg
7400 mg/kg
Animal
human
rat
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
TDLo
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
2600 mg/kg (65 weeks) (rat
TLV:
Route
unreported
oral
subcutaneous
AIV-153
-------
Sorbitol
CHEMICAL NAME
CAS Number: 50-704
Chemical Name: D-Glucitol
Synonyms: Hexahydric alcohol
Sotbol
Molecular
Formula: C6H14O6
OH H OH OH
I I I I
Structure: HO - CH2 -C-C-C-C- CH2 - OH
i r i i
H OH H H
Chemical Properties
Molecular Weight: 182.18
Vapor Pressure: Negligible
. Boiling Point: 295°C at 3.5 mm
Density: 1.489 at 200C/40C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: 110 to 112°C (anhydrous)
Solubility: Very soluble (2350 gm/1
AIV-154
-------
Sorbitol
PRODUCTION DATA
Annual U.S.
Production: 84.1 x 106 Ibs. (1968)
Fraction of
Dispersion:
Release Rate (million Ibs/yr): 52.2
Consumption:
Fraction of Pro-
duction Lost: 0.015
Acute Toxicity
TOXICITY DATA
Dosage Animal
Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mgtagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-155
-------
Styrene monomer
CHEMICAL NAME
CAS Number: 100-42-5
Chemical Name: Styrene
Synonyms: Phenylethylene
Vinyl benzene
Molecular
Formula: C8H8
Cinnamine
Structure: 4 /}- CH = CH2
Chemical Properties
Molecular Weight: 104.14
Vapor Pressure: 6.05 mm at 25°C
Boiling Point: 146°C at 760 mm
Density: 0.9045 at 25°C/25°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD: 87% of theoretical after 20 days at 20° C
Total theoretical oxygen demand = 3.1 gm/gm
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-moderate
Disaster hazard—dangerous—toxic fumes
Physical State: Liquid
Vapor Density:
Melting Point: -30.63°C
Solubility: Insoluble (H2O)
AIV-156
-------
Styrene monomer
PRODUCTION DATA
Annual U.S.
Production: 4394.0 x 106 Ibs. (1975)
Fraction of
Dispersion: °
Release Rate (million Ibs/yr): 89.1
Consumption: 4394.0 x 106 Ibs.
Fraction of Pro-
duction Lost: °-015
TOXICITY DATA
Acute Toxicity
LDSO
Dosage
5000 mg/kg
216 mg/kg
10,000 ppm (30 months)
5,000 ppm
10,000 ppm
Animal
rat
mouse
human
rat
mouse
12 gm/m^ (14 hours) guinea pig
Route
oral
oral
inhalation
inhalation
inhalation
inhalation
Non-lethal Acute Effects:
Irritant
TCLO 600 ppm human inhalation
Central nervous system
TCL0 376 ppm human inhalation
Glandular
TCLO 20 mg/m3 woman inhalation
Lachrymation and violent itching of the eyes
Weakness ~
Stupor
Incoordination
Tremors
Unconsciousness
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 100 ppm
Ceiling concentration 200 ppm
Peak concentration 600 ppm/5 minutes/ 3 hours
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
, TLV: 100 ppm
AIV-157
-------
Succinic acid
CHEMICAL NAME
CAS Number: 110-15-6
Chemical Name: Succinic acid
Synonyms: Ethylene succinic acid Butanedioic acid
Ethylene dicarboxylic acid
Molecular
Formula: C4H6O4
o
I.
H,C - C
Structure:
H2C-C
' 0
H2C - C - OH
I
H2C - C - OH
Chemical Properties
Molecular Weight: 118.09 Physical State: Solid
Vapor Pressure: Vapor Density:
Boiling Point: 235°C (decomposes) Melting Point: 188°C
Density: 1.564 at 15°C/4°C Solubility: Slightly (H2O)
Very soluble (hot H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-slight
AIV-158
-------
Succinic acid
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
TOXICITY DATA
Acute Toxicity
Dosage
2000 mg/kg
Animal
frog
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
Route
subcutaneous
AIV-159
-------
Succinonitrile
CHEMICAL NAME
CAS Number: 110-61-2
Chemical Name: Succinonitrile
Synonyms: Butanedinitrile
Ethylenedicyanide
Molecular
Formula: C4H4N2
Structure:
H2C-C = N
I
H2C-C =
Chemical Properties
Molecular Weight: S0.09
Vapor Pressure: 2 mm at 100°C
Boiling Point: 267°C at 760 mm
Density: 1.022 at 20°C
Octanol/Water Parti-
tion Coefficient: 0-35
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Physical State: Solid
Vapor Density: 270°C
Melting Point: 57 to 57.5°C
Solubility: Very soluble (H2O)
Safety Hazard:
Disaster hazard-dangerous-toxic fumes of cyanides
AIV-160
-------
Succinonitrile
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LD50 100 mg/kg rat intiaperitoneal
LDLo 150 mg/kg dog unreported
36 mg/kg rabbit unreported
2200 mg/kg . pigeon unreported
1000 mg/kg frog subcutaneous
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-161
-------
Sulfanilic acid
CHEMICAL NAME
CAS Number: 88-21-1
Chemical Name: o-Aminobenzenesulfonic acid
Synonyms: Sulfanilic acid
Orthanilic acid
Molecular
Formula:
C6H7N03S-HiO
NH-.
Structure:
SO3H-H2O
Chemical Properties
Molecular Weight: 191.2
Vapor Pressure:
Boiling Point:
Density: 1.485 at 25°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 288°C (decomposes)
Solubility: Slightly (hot H2O)
Safety Hazard:
Disaster hazard-dangerous-toxic fumes-NOx and SOX
AIV-162
-------
Sulfanilic acid
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
Acute Toxicity
Non-lethal Acute Effects:
Slight irritation
Low toxicity
TOXICITY DATA
Dosage Animal
Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-163
-------
Sulfolane
CHEMICAL NAME
CAS Number: 126-334
Chemical Name: Tetrahydrothiophene-l,l-dioxide
Synonyms: Sulfolane
Cyclocyclic tetramethylene sulfone
Cyclo tetiamethylene sulfone
Molecular
Formula: C4HgO2S
Tetramethylene sulfone.
Structure:
Chemical Properties
Molecular Weight: 120.18
Vapor Pressure: 0.01 mm at 20°C
Boiling Point: 285°C
Density: 1.261 at 30°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Reacts slowly with ROj and 63
Activity toward OH: t^ = 2 days
Safety Hazard:
Physical State: Liquid
Vapor Density:
Melting Point: 27°C
Solubility: Infinite (H2O)
AIV-164
-------
Sulfolane
Annual U.S.
Production: 35.0 x 106 Ibs.
Fraction of
Dispersion: Estimated as 1.0
Release Rate (million Ibs/yr): 35.5
PRODUCTION DATA
Consumption: 35.0 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.015
Acute Toxicity
LDSO
TOXICITY DATA
1540 mg/kg
1900 mg/kg
3180 mg/kg
Animal
rat
mouse
rabbit
Route
oral
oral
skin
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-165
-------
Sulfosuccinic, bis(2-ethylhexyl) ester, sodium salt
CHEMICAL NAME
CAS Number: 577-11-7
Chemical Name: Sulfobutanedioic acid,l,4-bis(2-ethylhexyl)ester, sodium salt
Synonyms:
Molecular
Formula: C20H37O7S-Na
C2H5
O
o
• II
C2H5
I ii • ii I
Structure: CH3 - (CH2)3 - CH - CH2 - O - C - CH2 - CH - C - O - CH2 - CH - (CH2)3 - CH3
I
SO3--Na+
Chemical Properties
Molecular Weight: 445.64
Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State:
Vapor Density:
Melting Point:
Solubility:
AIV-166
-------
Sulfosuccinic, bis(2-ethylhexyl) ester, sodium salt
PRODUCTION DATA
Annual U.S.
Production: 12.4 x 106 Ibs.
Fraction of
Dispersion: 1.0
Release Rate (million Ibs/yr): 12.8
Consumption: 12.4 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.03
TOXICITY DATA
Acute Toxicity
LD50
Dosage
1900 mg/kg
4800 mg/kg
60 mg/kg
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Animal
rat
mouse
mouse
TLV:
Route
oral
oral
intravenous
AIV-167
-------
Sutan
CHEMICAL NAME
CAS Number: 2008-41-5
Chemical Name: Bis(2-methylpropyl)carbamothioic acid, S-ethyl ester
Synonyms: S-Ethyldiisobutylthiocarbamate
Molecular
Formula: CuH23NOS
CH3
I
O CH2 - CH - CH3
n /
Structure: CH3CH2S - C - N
CH2 - CH - CH3
CHq
Chemical Properties
Molecular Weight: 217.41
Vapor Pressure: 13 x 10"3 mm at 25°C
Boiling Point:
Density: 0.9402 at 25°C/25°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Liquid
Vapor Density:
Melting Point:
Solubility: 45 ppm H2O at 22°C
Safety Hazard:
AIV-168
-------
Sutan
PRODUCTION DATA
Annual U.S.
Production: 6.0 x 10 Ibs. Consumption:
Fraction of Fraction of Pro-
Dispersion: Estimated as 1.0 duction Lost: 0.015
Release Rate (million Ibs/yr): 6.0
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LD5o 5366 mg/kg rat oral
4000mg/kg rat oral
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-169
-------
TBA
CHEMICAL NAME
CAS Number: 50-31-7
Chemical Name: 2,3,6-Ttichlotobenzoic acid
Synonyms: 2,3,6-TCB
2,3,6-TBA
Molecular
Formula:
Structure:
Cl
Chemical Properties
Molecular Weight: 225.46
Vapor Pressure: Negligible
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Physical State: Solid
Vapor Density:
Melting Point: 124 to 125°C (pure compound)
87 to 99°C (commercial mixture)
Solubility: Slightly soluble (0.84 gm/100 ml H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Relatively stable to ultraviolet decomposition
Safety Hazard:
AIV-170
-------
TBA
Annual U.S.
Production:
Fraction of
Dispersion:
2.0 x 10° Ibs.
PRODUCTION DATA
Consumption:
Estimated as 1.0
Release Rate (million Ibs/yr): 2.0
Fraction of Pro-
duction Lost: 0.015
Acute Toxicity
LDSO
TOXICITY DATA
Dosage
1644 mg/kg
650 mg/kg
1000 mg/kg
615 mg/kg
1500 mg/kg
812 mg/kg
1218 mg/kg
700 mg/kg
Animal
rat
rat
rat
mouse
mouse
rabbit
guinea pig
mammal
Route
oral
oral
intraperitoneal
oral
subcutaneous
oral
oral
unreported
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-171
-------
TCA
CHEMICAL NAME
CAS Number: 76-03-9
Chemical Name: Trichloroacetic acid
Synonyms: TCA
Molecular
Formula: C2HC13O2
Cl O
I ii
Structure: Cl - C - C - OH
I
Cl
Chemical Properties
Molecular Weight: 163.38
Vapor Pressure: 5 mm at 77°C
Boiling Point: 197.55°Cat760mm
Density: 1.62 at 25°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 55to58°C
Solubility: Very soluble (H2O)
Safety Hazard:
AIV-172
-------
TCA
Annual U.S.
Production:
Fraction of
Dispersion:
1.0xl06lbs.
Estimated as 1
Release Rate (million Ibs/yr): 1-0
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost: 0.015
Acute Toxicity
LD50
LDLo
TOXICITY DATA
Animal
3320 mg/kg
500 mg/kg
rat
mouse
Route
oial
intraperitoneal
Non-lethal Acute Effects:
May cause skin bums upon prolonged contact
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Irritant to nose and throat
TLV:
AIV-173
-------
Terephthalic acid
CHEMICAL NAME
CAS Number: 100-21-0
Chemical Name: Teiephthalic acid
Synonyms: p-Phthalic acid
TPA
Benzene-p-dicar boxy lie acid
Molecular
Formula: C8H6O4
Structure:
O
OH
Chemical Properties
Molecular Weight: 166.14
Vapor Pressure: Negligible
Boiling Point: Sublimes
Density: 1.51
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: >300° sublimes without melting
Solubility: Insoluble (H2O)
AIV-174
-------
Terephthalic acid
PRODUCTION DATA
Annual U.S.
Production: 4644.1 x 106 Ibs. (1975)
Fraction of
Dispersion: 0
Release Rate (million Ibs/yr): 28.9
Consumption: 4644 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.015
TOXICITY DATA
Acute Toxicity
LDSO
LD10
1430 mg/kg
767 mg/kg
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Animal
mouse
dog
Route
intraperitoneal
intravenous
TLV:
AIV-175
-------
Termik
CHEMICAL NAME
CAS Number: 116-06-3
Chemical Name: 2-Methyl-2(methylthio)propionaldehyde-O-(methyl-caibamoyl)oxime
Synonyms: Termik
Aldicaib
Molecular
Formula:
C7H14N202S
CH,
Structure: CH3-S-C-CH = N-O-C
CH,
O
Chemical Properties
Molecular Weight: 190.1
Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
\
N-CH3
H
Physical State:
Vapor Density:
Melting Point:
Solubility:
Solid
100°C
Safety Hazard:
AIV-176
-------
Termik
Annual U.S.
Production:
Fraction of
Dispersion:
2.0 x 10" Ibs.
Estimated as 1.0
Release Rate (million Ibs/yr): 2.0
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
0.015
Acute Toxicity
LDSO
TOXICITY DATA
Dosage
0.93 mg/kg
5 mg/kg
1 mg/kg
2500 //g/kg
930
300
1400 mg/kg
4440 Mg/kg
666 Mg/kg
Animal
rat
rabbit
rat
rat
rat
mouse
rabbit
duck
rat
Route
oral
skin
oral
skin
unreported
oral
skin
oral
subcutaneous
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-177
-------
1,1,1, 2-Tetrachloro-2, 2-difluoroethane
CHEMICAL NAME
CAS Number: 76-12-0
Chemical Name: l,l,2,2-Tetiachloro-l,2-difluoroethane
Synonyms: Tetrachlotodifluoroethane
Molecular
Formula:
Structure:
a a
i i
F-C-C-F
I .1
a a
Physical State: Liquid
Vapor Density: 7.03
Melting Point: 25°C
Solubility: Insoluble (H2O)
Chemical Properties
Molecular Weight: 203.83
Vapor Pressure: 52.53 mm at 25°C
Boiling Point: 93°C at 760 mm
Density: 1.6447 at 25°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Stable in lower atmosphere
Safety Hazard:
Disaster hazard—dangerous—toxic fumes of chlorides and fluorides
AIV-178
-------
1, 1, 1, 2-Tetrachioro-2, 2-difluoroethane
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LCSO 10,000 ppm (7 hours) rat inhalation
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-179
-------
, 2, 2-Tetrachloro-l, 2-difluoroethane
CHEMICAL NAME
CAS Number: 76-12-0
Chemical Name: 1,1,2,2-Tetrachloro-l, 2-difluoroethane
Synonyms: 1 ,2-Difluoro-l ,1 ,2 ,2-tetrachloroethane Freon 112
sym-Tetrachloiodifluoroethane Genetronll2
F-112
Molecular
Formula:
Structure:
Cl Cl
I I
F-C-C-F
I I
Cl Cl
Chemical Properties
Molecular Weight: 208.83
Vapor Pressure:
Boiling Point: 93°C at 760 mm
Density: 1.6447 at 25°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Stable in lower atmosphere
Physical State: Solid or liquid
Vapor Density:
Melting Point: 25°C
Solubility: Insoluble (H2O)
Safety Hazard:
AIV-180
-------
1, 1, 2, 2-Tetrachloro-l, 2-difluoroethane
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: dilution Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chropic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-181
-------
Tetrachloronaphthalene
CHEMICAL NAME
CAS Number: 605-36-7
Chemical Name: l,2,3,4-Tetrachloro-l,2,3,4-tetrahydronaphthalene
Synonyms:
Molecular
Formula: C10H8CU
Structure:
Cl
a
a
Solid
Physical State:
Vapor Density:
Melting Point: 182°C
Solubility:
Chemical Properties
Molecular Weight: 269.99
• Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Disaster hazard-dangerous; when heated to decomposition produces toxic fumes
AIV-182
-------
Tetrachloronaphthalene
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
Acute Toxicity
Non-lethal Acute Effects:
Systemic effects
TCLo
TOXICITY DATA
Dosage Animal
3mg/m3
human
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 2 mg/m3 (skin)
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
Route
inhalation
AIV-183
-------
Tetrachlorophthalic anhydride
CHEMICAL NAME
CAS Number: 117-08-8
Chemical Name: Tetrachlorophthalic anhydride,
Synonyms:
Molecular
Formula: C8C14O3
Structure:
•a
a
Chemical Properties
Molecular Weight: 285.90
Vapor Pressure:
Boiling Point: 371°C (sublimes)
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: 255 to 256.5°C
Solubility: Slightly (decomposes in hot H2O)
AIV-184
-------
Tetrachlorophthalic anhydride
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: fLV:
Other Chronic Effects:
AIV-185
-------
Tetraethyl lead
CHEMICAL NAME
CAS Number: 78-00-2
Chemical Name: Tetraethylplumbane
Synonyms: Tetraethyl lead
TEL
Molecular
Formula: C8H20Pb
CH2 - CH3
Structure: CH3 - CH2 - Pb - CH2 - CH3
CH2
CH2
Chemical Properties
Molecular Weight: 323.44
Vapor Pressure: 1 mm at 28.4°C
Boiling Point: 200°C (decomposes)
Density: 1.659 at 11°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
WithO3: tw= 2-3 days
With RC>2: slow to react in water
With OH :tv4= 2-3 days
Safety Hazard:
Fire-moderate
Physical State: Liquid
Vapor Density:
Melting Point: -136.8°C
Solubility: Insoluble (2 x 10^g/l H2O)
AIV-186
-------
Tetraethyl lead
PRODUCTION DATA
Annual U.S.
Production:
Fraction of
Dispersion: 1 -0
353.0 x 106 Ibs. (1973)
Consumption: 280.4 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.015
Release Rate (million Ibs/yr): 14.6
TOXICITY DATA
Acute Toxicity
LD50
Dosage
15 mg/kg
17 mg/kg
10 mg/kg
31 mg/kg
86 mg/kg
500 mg/kg
23 mg/kg
990 mg/kg
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
TDLo 86 mg/kg (21 days)
Mutagenicity: No information
Teratogenicity: Positive-rat-oral
Other Chronic Effects:
Metabolic disturbances
Nervous system disorders
Inhibition of DNA synthesis
Decreased ACHase activity
Animal
rat
rat
rat
rat
mouse
dog
rabbit
guinea pig
Route
parenteral
oral
intraperitoneal
intravenous
subcutaneous
skin
intravenous
skin
mouse
subcutaneous
TLV: 0.0117mg/m3
AIV-187
-------
Tetrahydrofuran
CHEMICAL NAME
CAS Number: 109-99-9
Chemical Name: Tetrahydrofuran
Synonyms: Cyclotetramethylene oxide
1,4 Epoxy-butone
Hydrofuron
Molecular
Formula: C4H8O
Butane a,£-oxide
Butylene oxide
Diethylene oxide
Oxacyclopentane
Tetramethylene oxide
Oxolane
Furanidine
Structure:
Chemical Properties
Molecular Weight: 72.10
Vapor Pressure: 143 mm at 20°C
Boiling Point: 67°C
Density: 0.8892 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Forms peroxides readily
Safety Hazard:
Fire—dangerous
Explosion-moderate
Physical State: Liquid
Vapor Density: 2.5
Melting Point: -65° C
Solubility: Soluble (H2O)
AIV-188
-------
Tetrahydrofuran
PRODUCTION DATA
Annual U.S.
Production: 59.0xl06lbs. Consumption: 59.0xl06lbs.
(90 x 106 Ibs., 1975 estimate)
Fraction of Fraction of Pro-
Dispersion: °-70 duction Lost: 0-015
Release Rate (million Ibs/yr): 42.2
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDLo 3000mg/kg rat oral
500 ing/kg rat intraperitoneal
Non-lethal Acute Effects:
Narcotic
Irritant to eyes, skin and respiratory tract
Chronic Toxicity
U.S. Occupational Standard: (air) TWA200ppm
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV: 200 ppm
Other Chronic Effects:
AIV-189
-------
Tetrahydronaphthalene
CHEMICAL NAME
CAS Number: 119-64-2
Chemical Name: 1,2,3,4-Tetrahydronaphthalene
Synonyms: tetralin
Molecular
Formula: C10H12
Structure:
Chemical Properties
Molecular Weight: 132.21 Physical State: Liquid
Vapor Pressure: l mm at 38.0°C Vapor Density: 4.55
Boiling Point: 207.57°Cat 760 mm Melting Point: -35.79°C
Density: 0.9702 at 20°C/4°C Solubility: Insoluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Fire—moderate
AIV-190
-------
Tetrahydronaphthalene
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of . Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 2860 mg/kg rat oral
LDio 275 ppm (8 hours guinea pig inhalation
for 17 days)
Non-lethal Acute Effects:
Local irritant
Narcotic in high concentrations
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
Cataracts and kidney injury
AIV-191
-------
Tetrahydrophthalic anhydride
CHEMICAL NAME
CAS Number: 85-43-8
Chemical Name: 4-Cyclohexene-l,2-dicarboxylie acid
Synonyms: Tetrahydrophthallic anhydride
Molecular
Formula: C8H8O3
O
Structure:
O
Chemical Properties
Molecular Weight: 152.14
Vapor Pressure: <0.01 mm at 20°C
Boiling Point: 195°Cat50mm
Density: 1.375 at 25°C/20°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density: 5.25
Melting Point:
Solubility: Insoluble (H2O)
AIV-192
-------
Tetrahydrophthalic anhydride
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
500 mg/kg mouse intraperitoneal
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-193
-------
Tetramethylethylenediamine
CHEMICAL NAME
CAS Number: 110-18-9
Chemical Name: N,N ,N ',N '-Tetramethylethylenediamine
Synonyms: N ,N,N',N'-Tetramethyl-l ,2-diaminoethane
Molecular
Formula: C6Hi6N2
CH,
CH3- N
N - CH,
Structure:
c = c
Chemical Properties
Molecular Weight: 116.24
Vapor Pressure:
Boiling Point: 121 to 122°C
Density: 0.7765 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Liquid
Vapor Density:
Melting Point: -55.1°C
Solubility: Soluble (H2O)
AIV-194
-------
Tetramethylethylenediamine
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDLo 1580 mg/kg rat oral .
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-195
-------
Tetramethyl lead
CHEMICAL NAME
CAS Number: 75-74-1
Chemical Name: Tetramethyl plumbane
Synonyms: Tetramethyl lead
Lead tetramethyl '
TML
Molecular
Formula:
CH,
I
Structure: CH3 - Pb - CH3
CH3
Chemical Properties
Molecular Weight: 267.33 Physical State: Liquid
Vapor Pressure: 6.0 mm at 10°C Vapor Density: 9.2
Boiling Point: liO°CatlOmm Melting Point: 27.5°C
Density: 1.995 Solubility: Insoluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts vigorously with oxidizing materials
Safety Hazard:
Fire-dangerous
Explosion-moderate
AIV-196
-------
Tetramethyl lead
PRODUCTION DATA
Annual U.S.
Production: 972.5 x 106 Ibs. Consumption: 900 x 106 Ibs.
(organo lead compounds) (oigano lead compounds)
Fraction of Fraction of Pro-
Dispersion: 1-0 duction Lost: 0.015
Release Rate (million Ibs/yr): 14.6 (tetramethyl lead)
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 109mg/kg rat . oral
.105 mg/kg rat parenteral
LDLo 73 mg/kg rat intraperitoneal
90 mg/kg rabbit intravenous
Can be fatal if swallowed
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 90 Mg/m3 (skin)
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV: 90jig/m3
Other Chronic Effects:
AIV-197
-------
Tetramethyl succinonitrile
CHEMICAL NAME
CAS Number: 3333-52-6
Chemical Name: Tetramethyl succinonitrile
Synonyms: TSN
Molecular
Formula: C8H12N2
Structure:
C=N
CH3-C-CH3
I
CH3 - C - CH3
Chemical Properties
Molecular Weight: 136.20
Vapor Pressure:
Boiling Point:
Density: 1.070
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: 170.5 to 171.5°C
Solubility:
AIV-198
-------
Tetramethyl succinonitrile
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
60 ppm rat inhalation
Chronic Toxicity
U.S. Occupational Standard: (aii) TWA 3 mg/m3 (skin)
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-199
-------
Tetranitromethane
CHEMICAL NAME
CAS Number: 509-14-8
Chemical Name: Tetranitromethane
Synonyms:
Molecular
Formula: CN4Og
NO2
Structure: O2N - c - NO2
NO2
Chemical Properties
Molecular Weight: 196.03 Physical State: Liquid
Vapor Pressure: 1 mm at 22.7°C Vapor Density:
Boiling Point: 126°C Melting Point: 14.2°C
Density: 1.6380 at 20°C/4°C Solubility: Insoluble (H2O)
Octanol/Water Parti-
tion Coefficient: •
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-dangerous
Explosion-severe
Disaster hazard-severe-toxic fumes-NOx
AIV-200
-------
Tetranitrom ethane
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
TOXICITY DATA
Acute Toxicity
LCLo
LDLo
Dosage
33 ppm (6 hours)
500 rag/kg
Animal
rat
mammal
Route
inhalation
inhalation
Non-lethal Acute Effects:
Irritant to eyes and respiratory passages
. Pulmonary edema
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 1 ppm
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Liver damage
Kidney damage
TLV: 1ppm
AIV-201
-------
Tetrapropylene
CHEMICAL NAME
CAS Number: 112-114
Chemical Name: 1-Dodecene
Synonyms: a-Dodecylene
Molecular
Formula: ci2H24
Structure: CH3(CH2)9CH = CH2
Chemical Properties
Molecular Weight: 168.33
Vapor Pressure:
Boiling Point: 213.4°C at 760mm
Density: 0.7584 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Liquid
Vapor Density:
Melting Point: -35.23°C
Solubility: Insoluble (H2O)
AIV-202
-------
Tetrapropylene
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
Acute Toxicity
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TOXICITY DATA
Animal
Route
TLV:
AIV-203
-------
Tetryl
CHEMICAL NAME
CAS Number: 47945-8
Chemical Name: N-Methyl-N,2,4,6- tetranitroaniline
Synonyms: Tetryl
Tetralite
Trinitrophenylmethylnitramine
Molecular
Formula: C7H5NSO8
Nitramine
Structure:
NO-,
CH,
NO2 3
Chemical Properties
Molecular Weight: 287.15
Vapor Pressure:
Boiling Point: Explodes at 187°C
Density: 1.57atl9°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: !31tol32°C
Solubility: Insoluble (H2O)
Safety Hazard:
Fire-dangerous
Explosion-severe
AIV-204
-------
Tetryl
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: ' duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 500 mg/kg dog subcutaneous
LDLo 5000 mg/kg dog subcutaneous
Non-lethal Acute Effects:
Dermatitis
Conjunctivitis
Nausea and vomiting
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 1.5 mg/m3 (skin)
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV: 1.5 mg/m3 (skin)
Other Chronic Effects:
Anemia
Gastrointestinal conditions
AIV-205
-------
Thiuram
CHEMICAL NAME
CAS Number: 137-26-8
Chemical Name: Bis(dimethyl thiocaibamoyl)disulflde
Synonyms: Tetramethyl thiuramdisulfide
Disulfutam
TTD
Molecular
Formula: C6H12N2S4
CH,
CH,
Structure:
CH
\ II II /
N-C-S-S-C-N
3 '
CH,
Chemical Properties
Molecular Weight: 240.44
Vapor Pressure: Negligible
Boiling Point: 129°Cat20mm
Density: 1.30 at 20° C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Disaster hazard-dangerous-NOx and SOX
Thiouram
Physical State: Solid
Vapor Density:
Melting Point: 155 to 156°C
Solubility: Insoluble (H2O)
AIV-206
-------
Thiuram
PRODUCTION DATA
Annual U.S.
Production:
Fraction of
Dispersion:
15.7 x 10° Ibs. (1972)
Consumption:
Fraction of Pro-
duction Lost: 0.015
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity
LD50
Dosage
560 mg/kg
1350mg/kg
210 mg/kg
780 mg/kg
200 mg/kg
230 mg/kg
Non-lethal Acute Effects:
Liver and.kidney injury
Brain damage
Irritation of eyes, nose and throat
Animal
lat
mouse •'
rabbit
mammal
mouse
cat
Route
oral
oral
oral
unknown
intraperitoneal
oral
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 5 mg/m3
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV: 5 mg/m3 (air)
TDLo 250 mg/kg (6-17 days of pregnancy) mouse oral
250 mg/kg (8 days of pregnancy) hamster oral
Other Chronic Effects:
AIV-207
-------
o-Tolidine
CHEMICAL NAME
CAS Number: 119-93-7
Chemical Name: 3,3'-Dimethylbenzidine
Synonyms: oTolidine
3,3'-Dimethyldiphenyl-4,4'-diamine
Molecular
Formula:
Chemical Properties
Molecular Weight: 212.30
Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 131 to 132°C
Solubility: Slightly (H2O)
Safety Hazard:
AIV-208
-------
o-Tolidine
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LD50 404 mg/kg rat oral
LDLo • 125 mg/kg rat intraperitoneal
125 mg/kg mouse intraperitoneal
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Recognized carcinogen
TD 2250 mg/kg (30 days) rat oral
2880 mg/kg (34 weeks) rat subcutaneous
4480 mg/kg (1 year) rat . implant
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-209
-------
Toluene
CAS Number: 108-88-3
Chemical Name: Toluene
Synonyms: Methyl benzene
Phenyl methane
Toluol
Molecular
Formula: C7H8
Structure:
CHEMICAL NAME
Chemical Properties
Molecular Weight: 92.15
Vapor Pressure: 28.4 mm at 25°C
Boiling Point: 110.6°C at 760 mm
Density: 0-8669 at 20°C/4°C
. Octanol/Water Parti-
tion Coefficient: 2.80
Environmental Persistence
BOD: 86% of theoretical after 20 days at 20°C
Total theoretical oxygen demand = 3.13 gm/gm
Atmospheric Reactivity:
Reacts with oxidizing materials
Unreactive to O3 and RO2 (Tw = 103 - 106 days)
Reactive toward OH
No photochemical degradation
Safety Hazard:
Fire—dangerous
Explosion—moderate
Disaster hazard-moderate-toxic fumes
Physical State: Liquid
Vapor Density: 3.14
Melting Point: -95°C
Solubility: Insoluble (H2O)
AIV-210
-------
Toluene
PRODUCTION DATA
Annual U.S.
Production: 6,937.9 x 10° Ibs. (1974)
Fraction of
Dispersion: 0.15
Release Rate (million Ibs/yr): 1074.2
Consumption: 5,420 x 10° Ibs. (1975)
Fraction of Pro-
duction Lost: 0.01
TOXICITY DATA
Acute Toxicity
LDSO
LC5o
LDLo
Dosage Animal
5400 mg/kg rat
1640mg/kg rat
5 300 ppm mouse
800 mg/kg rat
5 000 mg/kg rat
4000 ppm (4 hours) rat
Route
oral
inttaperitoneal
inhalation
intra peritoneal
subcutaneous
inhalation
Non-lethal Acute Effects:
Central nervous system
TCLo 200 ppm
Psycho trophic
TCLo 100 ppm
human
inhalation
inhalation
Chronic Toxicity
U.S. Occupational Standard: (air) NIOSH Recommended Standard:
TWA 200 ppm
Ceiling 300 ppm
Peak concentration 500 ppm/10 minutes
Carcinogenicity:
(Suspected) 100% solution mouse
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Blood abnormalties
Bone marrow chromosome damage
Metabolic effects
Enzymatic effects
Increased liver microsomal enzymes
dermal
TLV:
Odor perception: 40 ppm
AIV-211
-------
Toiiiene-2, 4-diamine
CHEMICAL NAME
CAS Number: 95-80-7
Chemical Name: Toluene-2, 4-diamine
Synonyms: Tolylene diamine
2,4-Diaminotoluene
Molecular
Formula:
NH,
Structure:
CH,
Chemical Properties
Molecular Weight: 122.17
Vapor Pressure: 1 mm at 106.5°C
Boiling Point: 292°C
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Disaster hazard-moderate-toxic fumes
Physical State: Solid
Vapor Density:
Melting Point: 99°C
Solubility: Very soluble (hot H2O)
.AIV-212
-------
Toluene-2, 4-diamine
PRODUCTION DATA
Annual U.S.
Production: 63 x 106 Ibs. Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDLo 500 mg/kg rat oral
50 mg/kg rat unreported
200 mg/kg dog subcutaneous
350 mg/kg dog unreported
400 mg/kg rabbit unreported
200 mg/kg guinea pig unreported
Non-lethal Acute Effects:
Liver damage
Skin irritation
Anemia
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Neoplasm:
TDLo 280 mg/kg (35 weeks) rat subcutaneous
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects;
AIV-213
-------
Toluene diisocyanate
CHEMICAL NAME
CAS Number: 91-08-7
Chemical Name: Isocyanic acid, 2-methyl-m-phenylene ester
Synonyms: Isocyanic acid, methyl phenylene estei
TDI
2,4-Toluene diisocyanate
Molecular
Formula: C9H6N2O2
N = C = O
Structure: O = C = N-^- \- CH3
Chemical Properties
Molecular Weight: 174.16 Physical State: Liquid
Vapor Pressure: <0.01 mm at 20°C Vapor Density: 6.0
Boiling Point: 238.3°C Melting Point: 19.5to21.5°C
Density: 1.22 at 20°C/4°C Solubility: Reacts with H2O producing CO2
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Reacts slowly with 63 and RO2
TVJ, OH = 3 days
Hydrolyzes in H2O(pH 7.0) t^ = 0.5 seconds
Safety Hazard:
Disaster hazard-dangerous-toxic fumes
AIV-214
-------
Toluene diisocyanate
Annual U.S.
Production: 420 x 106 Ibs.
Fraction of
Dispersion:
Release Rate (million Ibs/yr): 6.3
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost: 0.015
TOXICITY DATA
Acute Toxicity
LCSO
14 ppm (4 hours)
10 ppm (4 hours)
13 ppm (4 houts)
Animal
rat
mouse
guinea pig
Non-lethal Acute Effects:
Irritant
TCLo 0.5 ppm human
• Pulmonary edema
Allergies produced severe dermatitis and bronchial spasms
Route
inhalation
inhalation
inhalation
inhalation
Chronic Toxicity
U.S. Occupational Standard: (air) Ceiling-140 Mg/m3
NIOSH recommends: (air) TWA 5 ppb
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Liver disease
TLV: 0.02 ppm-below level of odor perception
AIV-215
-------
Toluenesulfonamide
CHEMICAL NAME
CAS Number: 70-55-3
Chemical Name: p-Toluene sulfonylamide
Synonyms: p -Toluene sulfonamide
4-Toluenesulfonic acid, amide
Molecular
Formula: C7H9NO2S
O
II
Structure: H,N - S
ii
O
Chemical Properties
Molecular Weight: 171.22
Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence .
BOD:
Atmospheric Reactivity:
Safety Hazard:
CH,
Physical State: Solid
Vapor Density:
Melting Point: 138.5 to 139°C
Solubility: Slightly (H2O)
AIV-216
-------
Toluenesulfonamide
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITYDATA
Acute Toxicity Dosage Animal Route
LD50 75 mg/kg wild bird oral
250 mg/kg mouse intrapeiitoneal
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-217
-------
o-Toluenesulf onic acid
CHEMICAL NAME
CAS Number: 88-20-0
Chemical Name: o-Toluenesulfonic acid
Synonyms: o-Toluenesulfonate
2-Toluenesulfonic acid
Molecular
Formula:
Structure: . < />- CH3
OH
Chemical Properties
Molecular Weight: 172.21
Vapor Pressure:
Boiling Point: 128. 8° Cat 25 mm
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: 67.5°C
Solubility: Very soluble (H2O)
AIV-218
-------
o-Toluenesulfonic acid
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
Acute Toxicity
TOXICITY DATA
Dosage Animal
Non-lethal Acute Effects:
High irritant
Moderate systemic toxicity •
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
Route
AIV-219
-------
p-foluenesulfonic acid
CHEMICAL NAME
CAS Number: 104-15-4
Chemical Name: p-Toluenesulfonic acid
Synonyms: p -Toluene sulfonate
Molecular
Formula: C7H8O3S
Structure:
HO-i
Chemical Properties
Molecular Weight: 172.21
Vapor Pressure:
Boiling Point: 140°Cat 20mm
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: 104 to 105°C
Solubility: Very soluble (H2O)
AIV-220
-------
p-Toluenesulfonic acid
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LD50 400 mg/kg rat oral
Non-lethal Acute Effects:
High irritant
Moderate systemic toxicity
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-221
-------
Toluenesulfonyl chloride
CHEMICAL NAME
CAS Number: 98-59-9
Chemical Name: p-Toluenesulfonyl chloride
Synonyms:
Molecular
Formula: C7H7C1O2S
O
II
Structure: Cl - S -\\ //
I, \\ //
O
CH,
Chemical Properties
Molecular Weight: 190.65
Vapor Pressure:
Boiling Point: 145 to 146°C at 15 mm
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 71°C
Solubility: Insoluble (H2O)
Safety Hazard:
AIV-222
-------
Toluenesulfonyl chloride
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
Acute Toxicity
TOXICITY DATA
Dosage Animal
Non-lethal Acute Effects:
Severe irritant
Moderate systemic toxicity
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
Route
AIV-223
-------
m-Toluidine
CHEMICAL NAME
CAS Number: 108-44-1
Chemical Name: m-Toluidine
Synonyms: m-Methyl aniline
3-Aminotoluene
3-Amino-l-methylbenzene
Molecular
Formula: C7H9N
NH2
Structure: d \- CH3
Chemical Properties
Molecular Weight: 107.16 Physical State: Liquid
Vapor Pressure: 1 mm at 41°C Vapor Density: 3.90
Boiling Point: 200.23°C at 760 mm Melting Point: -14.7°C
Density: 0.9984 at 20°C/4°C Solubility: Slightly (H2O)
Octanol/Water Parti-
tion Coefficient: 1.60
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Disaster hazard-dangerous-toxic fumes
AIV-224
-------
m-Toluidine
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 974 mg/kg rat oral
150 mg/kg mouse intiaperitoneal
Non-lethal Acute Effects:
Local irritant
Allergies
Headache
Irritation
Difficulty in breathing
Psychic disturbances
Marked irritation of the kidneys and bladder
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Neoplasm:
TDLo 6600 Mg/kg (19 weeks) rat oral
Mutageniciry:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-225
-------
o-Toluidine
CHEMICAL NAME
CAS Number: 95-53-4
Chemical Name: o-Toluidine
Synonyms: o-Methyl aniline
2-Methyl aniline
2-Amino toluene
Molecular
Formula: C7H9N
NH,
Structure:
Chemical Properties
Molecular Weight: 107.16
Vapor Pressure: 1 mm at 44°C
Boiling Point: 200.23°C at 760 mm
Density: 0.9984 at 20°C/40C
Octanol/Water Parti-
tion Coefficient: !-61
Physical State: Liquid
Vapor Density: 3.69
Melting Point: -23.7°C (unstable)
-14.7°C (stable)
Solubility: Slightly (H2O)
Environmental Persistence
BOD: 45% of theoretical
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-moderate
Disaster hazard-dangerous-toxic fumes
AIV-226
-------
o-Toluidine
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage . Animal Route
LD50 900mg/kg rat oral
150 mg/kg mouse intraperitoneal
3250 mg/kg rabbit skin
LDLo 300 mg/kg cat oral
5 mg/kg frog oral
Non-lethal Acute Effects:
Difficulty in breathing
Headache
Marked irritation of kidneys and bladder
Psychic disturbance
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 5 ppm (skin)"
Carcinogenicity:
Neoplasm TDLo 8200 mg/kg (24 weeks) rat oral
Mutagenicity:
Teratogenicity: TLV: 5 ppmTskin)
Other Chronic Effects:
AIV-227
-------
p-Toluidine
CHEMICAL NAME
CAS Number: 106-49-0
Chemical Name: p-Toluidine
Synonyms: p-Methyl aniline
4-Amino toluene
Molecular
Formula: C7H9N
Structure: H2N -<(
Chemical Properties
Molecular Weight: 107.16
Vapor Pressure: 1 mm at 42°C
Boiling Point: 200.55°C at 760 mm
Density: 0.9619 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Solid
Vapor Density: 3.90
Melting Point: 43.7°C
Solubility: Slightly (H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-moderate
Disaster hazard-dangerous-toxic fumes
AIV-228
-------
p-Toluidine
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LD50 50 mg/kg mouse intraperitoneal
42 mg/kg wild bird oral
LDLo 100 mg/kg mammal oral
Non-lethal Acute Effects:
Difficulty in breathing
Kidney damage
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity: Recognized carcinogen
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-229
-------
Toxaphene
CHEMICAL NAME
CAS Number: 8001-35-2
Chemical Name: Toxaphene
Synonyms: Chlorinated camphene
Stiobane
Atttox
Molecular
Formula: C10H8C18
Structure:
Chemical Properties
Molecular Weight: 413.84
Vapor Pressure: 0.2 to 0.4 mm at 25°C
Boiling Point: Decomposes
Density: 1.66 at 20°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Geniphene
Physical State: Solid
Vapor Density:
Melting Point: 65 to 90°C
Solubility: 3 ppm at 25°C (H2O)
Safety Hazard:
Disaster hazard-dangerous-toxic fumes-chlorides
AIV-230
-------
Toxaphene
PRODUCTION DATA
Annual U.S.
Production: 48 x 106 Ibs.
Fraction of
Dispersion: 1-0
Release Rate (million Ibs/yr): 50.5
Consumption: 48 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.01
Acute Toxicity
LDLo
TOXICITY DATA
Animal
60 mg/kg rat
780 mg/kg rat
1025 mg/kg rabbit
71 mg/kg duck
40 mg/kg human
2000 mg/m (2 hours) mouse
180 mg/kg mouse
50 mg/kg dog
780 mg/kg rabbit
Non-lethal Acute Effects:
Nausea and vomiting
Muscle cramps
Irritation of respiratory tract
Chronic Toxicity
U.S. Occupational Standard: 7 ppm for food residues
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
Route
oral
skin
skin
oral
oral
inhalation
interperitoneal
oral
oral
AIV-231
-------
Tributyl phosphate
CHEMICAL NAME
CAS Number: 126-73-8
Chemical Name: Phosphoric acid, tributyl ester
Synonyms: • Tributyl phosphate
Molecular
Formula:
O
II
Structure: CH3 - CH2 - CH2 - O - P - O - CH2 - CH2 - CH2 - CH3
O - CH2 - CH2 - CH2 - CHj
Chemical Properties
Molecular Weight: 266.32 Physical State: Liquid
Vapor Pressure: 20 mm at 20°C ' Vapor Density: 9.20
Boiling Point: 289°C Melting Point:
Density: 0.9727 at 25°C/4°C Solubility: Soluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Disaster hazard-dangerous phosphates
AIV-232
-------
Tributyl phosphate
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
TOXICITY DATA
Acute Toxicity
LD50
LDLo
Non-lethal Acute Effects:
Stimulation of CNS
3000 mg/kg
63 mg/kg
Animal
rat
mouse
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 5 ppm
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:5 ppm
Route
oral
intra peritoneal
AIV-233
-------
Trichloroaniline
CHEMICAL NAME
CAS Number: 634-93-5
Chemical Name: 2,4,6-Trichloioaniline
Synonyms: Trichloroaniline
sym-Trichloroaniline
Molecular
Formula: C6H4C13N
Cl
Structure:
Cl
\ /
NH,,
Cl
Chemical Properties
Molecular Weight: 196.46
Vapor Pressure: 1 mm at 134°C
Boiling Point: 262°C at 746 mm
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Solid
Vapor Density:
Melting Point: 78.5°C
Solubility: Insoluble (H2O)
AIV-234
-------
Trichloroaniline
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
teratogenicity: TLV:
Other Chronic Effects:
AIV-235
-------
Trichlorobenzene
CHEMICAL NAME
CAS Number: 120-82-1
Chemical Name: 1,2,4-Trichlorobenzene
Synonyms:
Molecular
Formula: C6H3a3
Structure:
Chemical Properties
Molecular Weight: 181.45
Vapor Pressure: l mm at 40°C
Boiling Point: 213.5°C at 760 mm
Density: 1.4542 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Liquid
Vapor Density: 6.26
Melting Point: 16.95°C
Solubility: Insoluble (H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-slight
Disaster hazard—dangerous toxic fumes-chlorides
AIV-236
-------
Trichlorobenzene
PRODUCTION DATA
Annual U.S.
Production: 10 x 10° lbs.( 1975 estimate) Consumption:
Fraction of Fraction of Pro-
Dispersion: . duction Lost: 0.015
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LD50 756 mg/kg rat oral
766 mg/kg mouse oral
LDLo 500 mg/kg mouse intrapeiitoneal
Non-lethal Acute Effects:
Local irritant
Causes loss of hair
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-237
-------
1,1, 1-Trichloroethane
CHEMICAL NAME
CAS Number: 71-55-6
Chemical Name: 1,1,1-Trichloroethane
Synonyms: a-Trichloroethane
Methyl chloroform
Molecular
Formula: C2H3Cl3
H Cl
II
Structure: H - C - C - Cl
I I
H Cl
Chemical Properties
Molecular Weight: 133.41
Vapor Pressure: 130.86 at 25°C
Boiling Point: 74.1°C at 760 mm
Density: 1.3390 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Liquid
Vapor Density: 4.55
Melting Point: -30.41°C
Solubility: Insoluble (H2O)
Safety Hazard:
Disaster hazard—dangerous-chlorides .
AIV-238
-------
1, 1, 1-Trichloroethane
PRODUCTION DATA
Annual U.S.
Production: 591 x 106 Ibs. (1974)
Fraction of
Dispersion: 0.73
Release Rate (million Ibs/yr): 284.5
Consumption: 591 x 10° Ibs.
Fraction of Pro-
duction Lost: 0.015
Acute Toxicity
LDSO
5660 mg/kg
9470 mg/kg
Non-lethal Acute Effects:
Psychotiophic effects:
TCLo 350 ppm
CNS effects:
TCLo 920 ppm
TOXICITY DATA
Animal
rabbit
guinea pig
human male
human
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
TLV: 350 ppm
Other Chronic Effects:
Reduced growth
Reversible dystrophic changes in liver, kidneys, myocardium and lungs
Narcotic effect
Route
oral
oral
inhalation
inhalation
AIV-239
-------
, 2-Trichloroethane
CHEMICAL NAME
CAS Number: 79-00-5
Chemical Name: 1,1, 2-Trichloroethane
Synonyms: Vinyl trichloride'
(3-Trichloroethane
Molecular
Formula:
Structure:
Cl Cl
i r
H-C-C-H
I I
H Cl
Chemical Properties
Molecular Weight: 133.41
Vapor Pressure: 25 mm at 25°C
Boiling Point: 113.77°Cat 760mm
Density: 1.4397 at 200C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Liquid
Vapor Density:
Melting Point: -36.5°C
Solubility: Slightly (H2O)
Safety Hazard:
Disaster hazard-dangerous-toxic fumes-chlorides
AIV-240
-------
1, 1, 2-Trichloroethane
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
Acute Toxicity
LDSO
LDLo
LCLo
Non-lethal Acute Effects:
Psychotic effects:
_JCLo_
CNS effect's
TOXICITY DATA
Dosage Animal
580 mg/kg rat
227 mg/kg mouse
750 mg/kg dbg
95 mg/kg dog
500 mg/kg rabbit
500 ppm (8 hours) rat
350 ppm man
920 ppm human
Route
oral
subcutaneous
oral
intravenous
subcutaneous
inhalation
inhalation
inhalation
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 10 ppm (skin)
Carcinogenicity:
Not carcinogenic according to Dow Chemical Co. after 12-month test
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-241
-------
Trichloroethylene
CHEMICAL NAME
CAS Number: 79-01-6
Chemical Name: Trichloroethylene
Synonyms: Ethylene trichloride
Trichloroethene
Molecular
Formula:
Cl
Structure:
C=C
Cl
Cl
Ethinyl trichloride
Acetylene trichloride
Physical State: Liquid
Vapor Density: 4.53
Melting Point: -73°C
Solubility: Slightly (H2O)
Chemical Properties
Molecular Weight: 131.39
Vapor Pressure: 77.5 mm at 25°C
Boiling Point: 87°C at 760 mm
Density: 1.4642 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Common air contaminant
Slowly oxidized by 03 and RO2; products are phosgene, HC1, CO, trichloroethylene oxide and
dichloroacetylchloride
Unreactive towards OH
Safety Hazard:
Fire-slight
Disaster hazard—dangerous—toxic fumes-chlorides
AIV-242
-------
trichloroethylene
PRODUCTION DATA
Annual U.S.
Production: 285.2 x 10° Ibs. (1975)
Fraction of
Dispersion: 0-95
Release Rate (million Ibs/yr): 429.5
Consumption: 370 to 390 x 10 Ibs. (1975 estimate)
Fraction of Pro-
duction Lost: 0.015
Acute Toxicity
LDLo
TOXICITY DATA
Dosage Animal
4920 mg/kg rat
34 mg/kg mouse
1900 mg/kg dog
857 mg/kg human
1800 mg/kg rabbit
5860 mg/kg dog
150 mg/kg dog
3000 ppm (2 hours) mouse
11,000 ppm rabbit
8000 ppm (8 hours) rat
Non-lethal Acute Effects:
CNS effects
TCLo
Conjunctivitis
Irritation of skin and respiratory tract
160 ppm (8 3 minutes) human
Route
oral
intravenous
Lntraperitoneal
oral
subcutaneous
oral
intravenous
inhalation
inhalation
inhalation
inhalation
Chronic Toxicity
(air)
U.S. Occupational Standard:
TWA 100 ppm
Ceiling 200 ppm (recommended 150 ppm)
Peak 300 ppm/5 minutes/2 hours
Carcinogenicity:
TDLo 351 gm/kg (78 weeks)
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Kidney, spleen, and liver damage
Metabolic and enzymatic effects
Hypertension .
Decreased ATP level • i •
Reduces antibody formation
mouse
oral
TLV: 100 ppm
AIV-243
-------
Trichlorofluoromethane
CHEMICAL NAME
CAS Number: 75-694
Chemical Name: Trichlorofluoromethane
Synonyms: Freon 1 1
Monofluorotrichloromethane
Molecular
Formula:
Cl
I
Structure: Cl - C - F
I
Cl
Chemical Properties
Molecular Weight: 137.38 Physical State: Liquid
Vapor Pressure: 717.5mmat25°C Vapor Density:
Boiling Point: 24.1°C Melting Point:
Density: 1.494 at 17.2°C Solubility: Slightly (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Disaster hazard-toxic fumes-chlorides and fluorides
AIV-244
-------
Trichlorofluoromethane
PRODUCTION DATA
Annual U.S.
Production: 299.6 x 10* Ibs. Consumption: 299.6 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 0.90 duction Lost: 0.015
Release Rate (million Ibs/yr): 274.l
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Non-lethal Effects:
Narcosis
Anesthesia
Cardiotoxic
Chronic Toxicity
U.S. Occupational Standard: (aii) TWA lOOOppm
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV: 1000 ppm
Other Chronic Effects:
AIV-245
-------
Trichloroisocyanuric acid
CHEMICAL NAME
CAS Number: 87-90-1
Chemical Name: l,3,5-Trichloro-s-triazine-2,4,6(lH,3H,5H)-trione
Synonyms: Trichloroisocyanuric acid
Trichlorotriozinetrione
Molecular
Formula:
Cl
I
Structure:
n
r
CI o Cl
Chemical Properties
Molecular Weight: 232.5
Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 225 to 230°C
Solubility: Soluble (12 gm/lHjO)
Safety Hazard:
Disaster hazard-dangerous Cl and CO gases
AIV-246
-------
Trichloroisocyanuric acid
PRODUCTION DATA
Annual U.S.
Production: 40 x 106 Ibs. Consumption: 40 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 1-0 duction Lost: 0.03
Release Rate (million Ibs/yr): 41.2
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 750 mg/kg rat oral
Non-lethal Acute Effects:
Irritant to skin and tissue
Chronic Toxicity
U.S. Occupational Standard:
FDA regulation for use as sanitizing agent:
100 ppm Cl~ in aqueous solution
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-247
-------
Trichloronaphthalene
CHEMICAL NAME
CAS Number: 2437-54-9
Chemical Name: 1,4,6-Trichloronaphthalene
Synonyms:
Molecular
Formula: Ci0H5Cl3
Structure:
Chemical Properties
Molecular Weight: 231.51
Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Disaster hazard-dangerous-chlorides
Physical State:
Vapor Density:
Melting Point:
Solubility:
Solid
AIV-248
-------
Trichloronaphthalene
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
Acute Toxicity
Non-lethal Acute Effects:
Systemic effects:
TCLo
TOXICITY DATA
Dosage Animal
30 mg/kg
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
human
TLV:
Route
inhalation
AIV-249
-------
Trichlorophenoxyacetic acid
CHEMICAL NAME
CAS Number: 93-76-5
Chemical Name: (2,4,5-Trichlorophenoxy)acetic acid
Synonyms: 2,4,5-Trichlorophenoxyacetic acid
2,4,5-T
Molecular
Formula: C8H5C13O3
Cl
Structure:
Cl
O - CH9 - C - OH
II
O
Chemical Properties
Molecular Weight: 255.49
Vapor Pressure: Low
Boiling Point:
Density: l.SOat 20°C/20°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard:
Disastei hazard—dangerous chlorides
Physical State: Solid
Vapor Density:
Melting Point: 157 to 158°C
Solubility: Insoluble (H2O)
AIV-250
-------
Trichlorophenoxyacetic acid
Annual U.S.
Production:
6.0 x 106 Ibs.
PRODUCTION DATA
Consumption:
Fraction of
Dispersion: Estimated as 1
Release Rate (million Ibs/yr): 6.0
Fraction of Pro-
duction Lost: 0.015
TOXICITY DATA
Acute Toxicity
LD50
Dosage
500 mg/kg
300 mg/kg
500 mg/kg
389 mg/kg
100 mg/kg
381 mg/kg
310 mg/kg
500 mg/kg
Animal
male lat
rat
rat
mouse
dog
guinea pig
chicken
mammal
Route
oral
oral
unieported
oral
oral
oral
oral
oral
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 10mg/m3
Carcinogenicity:
Mutagenicity:
Teratogenicity:
TDLo 100 mg/kg . rat (6-15 days-pregnant) oral
<150 Mg/kg mouse (6-14 days-pregnant) subcutaneous
(The teratogenicity is due in part to 2,3,7,8-TCDD (2,3,7,8-tetrachlorodibenzo-p-dioxin)
which is present as a contaminant)
Other Chronic Effects: TLV:
AIV-251
-------
Trichloropropane
CHEMICAL NAME
CAS Number: 96-184
Chemical Name: 1,2,3-Trichloropropane
Synonyms: Glyceiol trichloiohydrin
Allyl trichloride trichlorohydrin
Molecular
Formula: C3HSC13
H H H
I I I
Structure: H-C-C-C-H
I I I
Cl Cl Cl
Chemical Properties
Molecular Weight: 147.43
Vapor Pressure: 3.59 mm at 25°C
Boiling Point: 156.85°C at 760 mm
Density: 1.3889 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Liquid
Vapor Density: 5.0
Melting Point: -14.7°C
Solubility: Slightly (H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire—moderate
Disaster hazard-dangerous-toxic fumes-chlorides
AIV-252
-------
Trichloropropane
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LD50 320mg/kg rat oral
1770 mg/kg rabbit skin
LDLo 200 mg/kg dog oral
LCLo 1000 PPm (4 hours) rat inhalation
Non-lethal Acute Effects:
Local irritant
Lesions in liver, kidney and heart
Chronic Toxicity
U.S. Occupational Standard: (air) TWA SO ppm
Carcincgenicity:
Mutagenicity:
Teratogenicity: TLV: 50 ppm
Other Chronic Effects:
AIV-253
-------
Trichlorotrifluoroethane
CHEMICAL NAME
CAS Number: 76-13-1
Chemical Name: l,l,2-Trichloro-l,2,2-trifluoroethane
Synonyms: Trifluorotrichloroethane
Molecular
Formula:
Structure:
Cl Cl
I I
Cl-C-C-F
I I
F F
Chemical Properties
Molecular Weight: 187.38
Vapor Pressure: 337.72 mm at 25°C
Boiling Point: 47.7°C at 760 mm
Density: 1.5635at25°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Stable in lower atmosphere
Safety Hazard:
Fire-slight
Disaster hazard-dangerous-toxic fumes-fluorides and chlorides
Physical State: Liquid
Vapor Density: 6.47
Melting Point: -36.4°C
Solubility: Insoluble (H2O)
AIV-254
-------
Trichlorotrifluoroethane
Annual U.S.
Production:
Fraction of
Dispersion:
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
Release Rate (million Ibs/yr): 682 (1973 emissions of F-ll and F-12)
Acute Toxicity
TOXICITY DATA
Dosage Animal
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
TCLo
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
4500 ppm
human
TLV: 1000 ppm
Route
inhalation
AIV-255
-------
Tricresyl phosphate
CHEMICAL NAME
CAS Number: 78-30-8
Chemical Name: Phosphoric acid, tri-o-tolyl ester
Synonyms: o-Tolyl phosphate
Tricresyl phosphate
Molecular
Formula:
Tri-o-cresyl phosphate
Tri-o^tolyl phosphate
Tri-2-tolyl phosphate
C2,H2104P
Structure:
Chemical Properties
Molecular Weight: 368.37
Vapor Pressure: 0.29 mm at 200°C
Boiling Point: 410°C
Density: 1.1955 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Liquid
Vapor Density: 12.7
Melting Point: 11°C
Solubility: Insoluble (H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fiie-slight
Disaster hazard-dangerous POX
AIV-256
-------
Tricresyl phosphate
PRODUCTION DATA
Annual U.S.
Production: 50.2 x 106 Ibs. Consumption: 42.7 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 1-0 duction Lost: 0.015
Release Rate (million Ibs/yr): 43.5
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDLo 4680 mg/kg rat oral
500 mg/kg dog • oral
100 mg/kg rabbit oral
Non-lethal Acute Effects:
CNS effects, paralysis
Nausea and vomiting
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 0.1 mg/m3
Carcinogenicity: Negative result in 12-week rat study
Mutagenicity:
Teratogenicity: TLV: o.l mg/m3
Other Chronic Effects:
AIV-257
-------
Tridecylbenzenesulfonic acid, sodium salt
CHEMICAL NAME
CAS Number: 1435640-2
Chemical Name: p-Tridecylbenzenesulfonic acid, sodium salt
Synonyms:
Molecular
Formula:
CH3
I
(CH2)y
Structure:
CH3(CH,) CH -4 />- S
J L x \, // - (| .
O
Chemical Properties
Molecular Weight: 361.50
Vapor Pressure: Negligible at 2S°C
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
x+y = 10
Physical State:
Vapor Density:
Melting Point:
Solubility:
AIV-258
-------
Tridecylbenzenesulfonic acid, sodium salt
PRODUCTION DATA
Annual U.S.
Production: 149.9 x 106 Ibs. Consumption: 149.9 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 1-° duction Lost: °-015
Release Rate (million Ibs/yr): 152J
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-259
-------
Triethanolamine
CHEMICAL NAME
CAS Number: 102-71-6
Chemical Name: 2,2',2",-Nitrilotriethanol
Synonyms: Triethanolamine
2,2',2"-Trihydroxyethylamine
Molecular
Formula: C6H15NO3
Structure: HO - CH2 - CH2 - N - CH2 - CH2 - OH
CH,
i z
CH,
i i
OH
Chemical Properties
Molecular Weight: 149.19 Physical State: Solid-liquid
Vapor Pressure: <0.01 mm at 20°C Vapor Density: 5.14
Boiling Point: 277°C at 150mm Melting Point: 21.2°C
Density: 1.1242 at 20°C/4°C Solubility: Infinite (H2O)
Octanol/Water Parti-
tion Coefficient: -1.75
Environmental Persistence
BOD: 66% of theoretical after 10 days at 20° Cat 10mg/l
Total theoretical oxygen demand = 2.04 gm/gm
Resistance to biodegradation
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-slight
Disaster hazard-dangerous-NOx
AIV-260
-------
Triethanolamine
PRODUCTION DATA
Annual U.S.
Production: 100.7 x 106 Ibs. Consumption: 85.7 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 0.40 duction Lost: 0.015
Release Rate (million Ibs/yr): 35.8
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSo 8000mg/kg guinea pig oral
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-261
-------
Triethylamihe
CHEMICAL NAME
CAS Number: 121-44-8
Chemical Name: Trie thy lamine
Synonyms: N,N-Diethylethanamine
Molecular
Formula: C6H,5N
Structure: CH3 - CH2 - N - CH2 -
CH2
Chemical Properties
Molecular Weight: 101.19 Physical State: Liquid
Vapor Pressure: Vapor Density: 3.48
Boiling Point: 89.3°C at 760 mm Melting Point: -114.7°C
Density: 0.7275 at 20°C/4°C Solubility: Soluble (H2O)
Octanol/Water Parti-
tion Coefficient: 1.37
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-dangerous
AIV-262
-------
Triethylamine
PRODUCTION DATA
Annual U.S.
Production:
Fraction of
Dispersion:
22.8 x!06lbs. (1967)
(Includes monoethylamine)
Consumption:
Fraction of Pro-
duction Lost: °-015
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity
LD50
LCLo
Dosage
460 mg/kg
546 mg/kg
570 mg/kg
1000 ppm (4 hours)
1000 ppm (4 hours)
Non-lethal Acute Effects:
Liver and kidney damage
Irritant to skin and mucous membranes
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Animal
rat
mouse
rabbit
rat
guinea pig
Route
oral
oral
skin
inhalation
inhalation
TLV: 25 ppm
AIV-263
-------
Triethylene glycol
CHEMICAL NAME
CAS Number: 112-27-6
Chemical Name: Triethylene glycol
Synonyms: 2.2'-Ethylene dioxy diethanol glycol
Bis (hydroxyethyl) ether
Molecular
Formula:
Structure:
C6H1404
CH, - O - CH, - CH2 - OH
CH2 - O - CH2 - CH2 - OH
Chemical Properties
Molecular Weight: 150.18
Vapor Pressure: 1 mm at 114°C
Boiling Point: 278.3°C at 760 mm
Density: I.l274at 15°C/48C
Octanol/Water Parti-
tion Coefficient: -2-08
Environmental Persistence
BOD: 85% of theoretical after 20 days at 20°C
Total theoretical oxygen demand =1.6 gm/gm
Atmospheric Reactivity:
Physical State: Liquid
Vapor Density:
Melting Point: -5°C
Solubility: Infinite (H2O)
Safety Hazard:
Fire-slight
Explosion-moderate
AIV-264
-------
Triethylene glycol
PRODUCTION DATA
Annual U.S.
Production: 113xl06lbs. Consumption: 113xl06lbs.
Fraction of Fraction of Pro-
Dispenion: 0.75 duction lost: 0.015
Release Rate (million Ibs/yr): 70.8
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LD5o 9739 mg/kg ' mouse subcutaneous
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-265
-------
Triethylene glycol, dimethyl ether
CHEMICAL NAME
CAS Number: 112-49-2
Chemical Name: 2,5,8,11-Tetraoxadodecane
Synonyms: Triethyleneglycol dimethyl ether
Triglyme
1,2-Bis(2-methoxyethoxy)ethane
Molecular
Formula: C8Hi8C>4
Structure: CH3 - (OCH2CH2)3 - OCH3
Chemical Properties
Molecular Weight: 178.22
Vapor Pressure: 0.9 mm at 20°C
Boiling Point: 216°C
Density: °-9862 at 20°C/20°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Physical State: Liquid
Vapor Density:
Melting Point: -46°C
Solubility: Soluble (H2O)
Reacts with oxidizing materials
Safety Hazard:
Fire-slight
AIV-266
-------
Triethylene glycol, dimethyl ether
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
(Low toxicity)
Chronic Toxicity
U.S. Occupational Standard:
Carcinogen icity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-267
-------
Triethylene glycol, monomethyl ether
CHEMICAL NAME
CAS Number: 112-35-6
Chemical Name: 2-[2-(2-Methoxyethoxy)ethoxy]ethanol
Synonyms:
Molecular
Formula:
Triethylene glycol, monomethyl ether
Methoxytriglycol
Methoxytriethylene glycol
Structure: CH3 - (OCH2CH2)3 - OH
Chemical Properties
Molecular Weight: 164.20
Vapor Pressure: <0.01 mm at 20°C
Boiling Point: 249°C
Density: 1.0494
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Fire-slight
Physical State:
Vapor Density:
Melting Point:
Solubility: Infinite (H2O)
AIV-268
-------
Triethylene glycol, monomethyl ether
PRODUCTION DATA
Annual U.S.
Production: 31.7 x 106 Ibs. Consumption: 26.7 x 106 Ibs.
Fraction of 1.0 Fraction of Pro- 0.015
Dispersion: duction Lost:
Release Rate (million Ibs/yr): 27.2
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-269
-------
Trifluralin
CHEMICAL NAME
CAS Number: 1582-09-8
Chemical Name: a,a,a,-TTifluoro-2,6-dinitro-N, N-dipropyl-p-toluidine
Synonyms: Trifluralin
Molecular
Formula:
F ,N<>2
I
Structure: F - C
^N02 ^ "W^
Chemical Properties
Molecular Weight: 335.32 Physical State: Solid
Vapor Pressure: 1.99 x 10"4mmat29.5°C Vapor Density:
Boiling Point: 139 to 140°Cat4.2 mm Melting Point: 48.5to49°C
Density: Solubility: Insoluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Degraded by ultraviolet irradiation
Safety Hazard:
Disaster hazard-dangerous nitrates and fluorides
AIV-270
-------
Trifluralin
PRODUCTION DATA
Annual U.S.
Production: 20 x 106 Ibs. Consumption: 20 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 1.0 duction Lost: 0.01
Release Rate (million Ibs/yr): 20.2
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO >10,000 mg/kg rat oral
5 gm/kg mouse oral
5000gm/kg mouse oral
500 mg/kg rat oral
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-271
-------
Triisobutylene
CHEMICAL NAME
CAS Number: 9003-274
Chemical Name: 2-Methyl-l-propene, homopolymer
Synonyms: Triisobutylene
2-Methylpropene (trimer)
Poly(2-methylpropene)
Molecular
Formula:
C12H24
Structure: (mixture of isomers)
Chemical Properties
Molecular Weight: 168.33
Vapor Pressure: 2.08 mm at 25°C
Boiling Point: 179 to 181°C
Density: . 0.7590 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Safety Hazard:
Polyisobutylene
Physical State: Liquid
Vapor Density:
Melting Point: -76°C
Solubility: Insoluble (H2O)
AIV-272
-------
Triisobutylene
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITYDATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-273
-------
Trimethylamine
CHEMICAL NAME
CAS Number: 75-50-3
Chemical Name: Trimethylamine
Synonyms: N,N-Dimethylmethanamine
Molecular
Formula: C3H9N
CH3
I
Structure: CH3 - N - CH3
Chemical Properties
Molecular Weight: 59.11 Physical State: Gas
Vapor Pressure: 687 mm at 0°C Vapor Density: 2.0
Boiling Point: 2.87°C at 760 mm Melting Point: -117.2°C
Density: 0.6356 at 20°C/4°C Solubility: Very(H2O)
Octanol/Water Parti-
tion Coefficient: 1.45
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire—moderate
Explosion-moderate
Disaster hazard-moderate-toxic fumes
AIV-274
-------
Trim ethy la mine
PRODUCTION DATA
Annual U.S.
Production: 28.8 x 106 Ibs.
Fraction of
Dispersion: °-70
Release Rate (million Ibs/yr): 20.6
Consumption: 28.8 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.015
TOXICITY DATA
Acute Toxicity Dosage
LDSO 90 mg/kg
LDLo 75 mg/kg
1000 mg/kg
800 mg/kg
400 mg/kg
2000 mg/kg
Non-lethal Acute Effects:
Irritant to skin, respiratory organs
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Animal
mouse
mouse
mouse
rabbit
rabbit
frog
TLV:
Route
intravenous
intraperitoneal
subcutaneous
subcutaneous
intravenous
subcutaneous
AIV-275
-------
Trimethylpentanediol
CHEMICAL NAME
CAS Number: 144-19-4
Chemical Name: 2,2,4-Trimethyl-l,3-pentanediol
Synonyms: TMFD
Molecular
Formula: C8H18O2
CH,
CH,
Structure: CH, - CH - CH - C - CH9OH
II
OH CH,
Chemical Properties
Molecular Weight: 146.23
Vapor Pressure:
Boiling Point: 234°C at 737 mm
Density: 0.937 at 15°C/1S°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Solid
Vapor Density:
Melting Point: 51.8to52.2°C
Solubility: Slightly (H2O)
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts wi* oxidizing materials
Safety Hazard:
Fire-slight
AIV-276
-------
Trimethylpentanediol
PRODUCTION DATA
Annual U.S.
Production: 20 x 106 Ibs. Consumption: 20 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: °-8 duction Lost: 0.015
Release Rate (million Ibs/yr): 16-3
TOXICITY DATA
Acute Toxicity Dosage Animal Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-277
-------
Trinitrotoluene
CHEMICAL NAME
CAS Number: 118-96-7
Chemical Name: 2,4,6-Trinitiotoluene
Synonyms: Trinitrotoluene
JTNT
sym-Trinitrotoluene
Molecular
Formula:
Structure: O2N
NO,
/ACH3
NO
Chemical Properties
Molecular Weight: 227.13
Vapor Pressure:
Boiling Point: 290 to 3 10°C (explodes)
Density: 1.654
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Triton
s-Trinitrotoluene
Physical State: Solid
Vapor Density:
Melting Point: 104°C
Solubility: Insoluble (H2O)
Safety Hazard:
Explosion-moderate
Disaster hazard-highly dangerous-toxic fumes
AIV-278
-------
Trinitrotoluene
Annual U.S.
Production:
Fraction of
Dispersion:
Release Rate (million Ibs/yr):
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
TOXICITY DATA
Acute Toxicity
Dosage
700mg/kg
1850mg/kg
200 mg/kg
500mg/kg
500 mg/kg
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Animal
rat
cat
cat
rabbit
rabbit
Route
oral
oral
subcutaneous
oral
subcutaneous
TLV:
AIV-279
-------
Trithion
CHEMICAL NAME
CAS Number: 786-19-6
Chemical Name: . Phbsphoiodithioic acid, S-[ [(p-Chlorophenyl)thio] methyl] O, O-diethyl ester
Synonyms: Trithion
O.O-diethyl-S-p-chlorophenylthiomethyl phosphorodithioate
Caibophenothion
Molecular
Formula: CuHi6ao2PS3
Structure: CH3CH2O - P - s - CH2S
OCH2CH3
Chemical Properties
Molecular Weight: 260.39
Vapor Pressure: Negligible
Boiling Point: 82°at 0.01 mm
Density: 1.280 to 1.285 at 20°C/20°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State:
Vapor Density:
Melting Point:
Solubility: Insoluble (H2O)
Safety Hazard:
Disaster hazard-dangerous phosphates and chlorides
AIV-280
-------
Trithion
Annual U.S.
Production:
Fraction of
Dispersion:
PRODUCTION DATA
2.0 x 106 Ibs. Consumption:
Fraction of Pro-
duction Lost:
Estimated as 1.0
Release Rate (million Ibs/yr): 2.0
0.015
Acute Toxicity
LDSO
Dosage
32 mg/kg
10 mg/kg
27 mg/kg
11 mg/kg
. 218 mg/kg
27 mg/kg
1270 mg/kg
57 mg/kg
6 mg/kg
TOXICITY DATA
Animal
male rat
tat
rat
rat
mouse
mouse
rabbit
chicken
wild bird
Route
oral
oral
skin
intraperitoneal
oral
intraperitoneal
skin
oral
oral
Non-lethal Acute Effects:
Pulmonary edema
Convulsions
Chronic Toxicity
U.S. Occupational Standard: EPA farm worker reentry standard
Carcinoganicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-281
-------
Urea
CAS Number:
Chemical Name:
57-13-6
Urea
Synonyms: Carbamide
Carbonyldiamine
Molecular
Formula: CH4N2O
O
Structure: H2N - C - NH2
CHEMICAL NAME
Chemical Properties
Molecular Weight: 60.06
Vapor Pressure:
Boiling Point: (Decomposes)
Density: 1.3230at20°C/4°C
Octanol/Water Parti-
tion Coefficient: -2.96
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 13S°C
Solubility: Very soluble (H2O)
Safety Hazard:
AIV-282
-------
^^__ . Urea
PRODUCTION DATA
Annual U.S.
Production: 8,390 x 106 Ibs. (1975) Consumption: 8,420 x 106 Ib.s (1975)
Fraction of Fraction of Pro-
Dispersion: duction Lost: 0.15
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
I.DLO 3000 mg/kg dog subcutaneous
3000 mg/kg dog intravenous
3000. mg/kg rabbit subcutaneous
600 mg/kg frog subcutaneous
511 mg/kg domestic oral
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-283
-------
Vernam
CHEMICAL NAME
CAS Number: 1929-77-7
Chemical Name: Dipiopylcarbamothioic acid, S-propyl ester
Synonyms: S-Propyldipropylthiocarbamate
Molecular
Formula: Ci0H21NOS
O CH2CH2CH3
Structure: CH3CH2CH2 - S - C - N
CH2CH2'CH o
Chemical Properties
Molecular Weight: 203.38
Vapor Pressure: 10.4 x 10"3 mm at 25°C
Boiling Point: 150°Cat 30 mm
Density: 0.95 at 20°C/20°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard:
Physical State: Liquid
Vapor Density:
Melting Point:
Solubility: 90 ppm H2O at 20°C
AIV-284
-------
Vernam
Annual U.S.
Production:
Fraction of
Dispersion:
2.0 x 10" Ibs.
Estimated as 1.0
Release Rate (million Ibs/yr): 2-°
PRODUCTION DATA
Consumption:
Fraction of Pro-
duction Lost:
Acute Toxicity
LD50
TOXICITY DATA
1800mg/kg
1470 mg/kg
1780 mg/kg
Animal
iat
rat
rat
Route
oral
oral
urtrepoited
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-285
-------
Vinyl acetate
CHEMICAL NAME
CAS Number: 108-05-4
Chemical Name: Vinyl acetate
Synonyms: Acetic acid, vinyl ester
Acetic acid, ethenyl estei
Molecular
Formula: C4H6O2
O
Structure: CH3 - C - O - CH = CH2
Chemical Properties
Molecular Weight: 86.09
Vapor Pressure: 107.5 mm at 25°C
Boiling Point: 72.2 to 72.3°C at 760 mm
Density: 0.9317 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
Physical State: . Liquid (polymerizes)
Vapor Density: 3.0
Melting Point: -93.2°C
Solubility: Insoluble (H2O)
Soluble in hot H2O
BOD: 72% of theoretical after 20 days at 20 C
Total theoretical oxygen demand = 1.67 gm/gm
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire—highly dangerous
AIV-286
-------
Vinyl acetate
PRODUCTION DATA
Annual U.S.
Production: 1210.7 x 106 Ibs. Consumption: 989.4 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 0 duction Lost: 0.015
Release Rate (million Ibs/yr): 18.2
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 2920 mg/kg rat oral
2320 mg/kg rabbit skin
LDj_,0 500 mg/kg rat intraperitoneal
LCL0 4000 ppm (4 Hours) rat . inhalation
Non-lethal Acute Effects:
Skin irritant
Vapors may be narcotic
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 10 ppm
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV: TWA 10 ppm
' _ _ . Odor perception: 0.12 ppm
Other Chronic Effects:
AIV-287
-------
Vinyl chloride
CHEMICAL NAME
CAS Number: 75-014
Chemical Name: Chloroethylene
Synonyms: Vinyl chloride
Chloroethene
Molecular
Formula: C2H3C1
Structure: CH2 = C
H
Cl
Chemical Properties
Molecular Weight: 62.50
Vapor Pressure: 2660 mm at 25°C
Boiling Point: -13.4°C>at760mm
Density: 0.9195 at 15°C/4°C
Octanol/Water Parti-
tion Coefficient:
Physical State: Liquid or gas
Vapor Density: 2.15
Melting Point: -153.8°C
Solubility: Slightly (1.1 gm/lH2O)
Environmental Persistence
BOD: Total theoretical oxygen demand = 1.28 gm/gm
Atmospheric Reactivity: Reacts with oxidizing materials
Activity toward 03: t^ = <3 days
ROj: t^ = 10s days; slow oxidation in water
OH: tw = 3 days
Safety Hazard:
Fire—dangerous
Explosion-severe
Disaster hazard-very dangerous-toxic fumes
AIV-288
-------
Vinyl chloride
PRODUCTION DATA
Annual U.S.
Production:
Fraction of
Dispersion:
5088.5 x 106 Ibs.
(4,174.6 x!06lbs., 1975)
0.01
Consumption: 4467.6 x 106 Ibs.
Fraction of Pro-
duction Lost:
0.02
Release Rate (million Ibs/yr): 146.5
Acute Toxicity
LC
Non-lethal Acute Effects:
Cardiovascular
TOXICITY DATA
Dosage Animal
100,000 to 400,000 ppm mouse
dog
cat
guinea pig
Paralysis
TCLo
Skin irritation
Conjunctivitis
20 ppm
300 ppm
human
human
Route
unknown
unknown
unknown
unknown
inhalation
inhalation
Chronic Toxicity
U.S. Occupational Standard: (air) TWA 1 ppm
Ceiling 5 ppm
Carcinogenicity:
LCLo
Mutagenicity:
Positive: Ames Salmonella
Teratogenicity:
Other Chronic Effects:
Liver and kidney damage
Cardiovascular damage
Thyroid and brain degeneration
250 ppm (4 hours/
260 days)
rat
inhalation
T LV: 500 ppm or 1300 mg/m3
AIV-289
-------
Vinylidene chloride
CHEMICAL NAME
CAS Number: 75-354
Chemical Name: 1,1-Dichloroethylene
Synonyms: Vinylidene chloride
Molecular
Formula: C2H2C12
H Cl
x /
Structure: C = C
/ \
H Cl
Chemical Properties
Molecular Weight: 97.0 Physical State: Volatile liquid
Vapor Pressure: 617.14 mm at 25°C Vapor Density:
Boiling Point: 37°Cat760mm Melting Point: -122.53°C
Density: 1.213 at 20°C/4°C Solubility: Insoluble (H2O)
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity: Reacts with oxidizing materials
Activity, towards 63: t^ < 1 day
I RO2: tvi = 103 days
OH: tvi
-------
Vinylidene chloride
PRODUCTION DATA
Annual U.S.
Production: 260 x 106 Ibs.
Fraction of
Dispersion: 0
Release Rate (million Ibs/yr): 2.4
Consumption: 54 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.03
TOXICITY DATA
Acute Toxicity
LDLd
Dosage
3700 mg/kg
5750 mg/kg
225 mg/kg
10,000 ppm
Non-lethal Acute Effects:
Irritant to eyes, skin, and respiratory tract
Narcosis
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity: Suspected
Mutagenicity: Positive: Ames bacterial system
Teratogenicity:
Other Chronic Effects:
Animal
rabbit
dog
dog
rat
Route
subcutaneous
oral
intravenous
inhalation
TLV: 25 ppm (suggested)
Odor perception: 1000 ppm
AIV-291
-------
Vinyltoluene
CHEMICAL NAME
CAS Number: 622-97-9
Chemical Name: p-Methylstyrene
Synonyms: Vinyltoluene
Molecular
Formula: C9H10
Structure: CH2 = CH
CH,
Physical State: Liquid
Vapor Density: 4.08
Melting Point:
Solubility: Insoluble (H2O)
Chemical Properties
Molecular Weight: 118.2
Vapor Pressure: 1.15 mm at 20°C
Boiling Point: 170tol71°C
Density: Monomer: 0.89 at 25°C/25°C
Polymer: 1.027 at 25°C/25°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity: Reacts with oxidizing material forming formaldehyde and methylbenzaldehyde
Activity toward RC>2: tvi = 24 hours
O3: tw = 24 hours
OH: tw = 1 day
Safety Hazard:
Fire-moderate
AIV-292
-------
Vinyltoluene
PRODUCTION DATA
Annual U.S.
Production: 40 x 10 Ibs. Consumption: 40 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: O-30 duction Lost: 0-015
Release Rate (million Ibs/yr): 12.6
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO 4000mg/kg rat oral
Non-lethal Acute Effects:
Irritation
TCLO 400 ppm human inhalation
Damaged kidneys and liver
Irritant to eye, nose and throat
Chronic Toxicity
U.S. Occupational Standard: (air) Ceiling 100 ppm
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV: 1000 ppm
Other Chronic Effects:
AIV-293
-------
Warfarin
CHEMICAL NAME
CAS Number: 81-81-2
Chemical Name: 3-(a-Acetonylbenzyl)-4-hydroxycoumarin)
Synonyms: Warfarin
WARF-42
Compound 42
Molecular
Formula: C19H16O4
Structure:
Chemical Properties
Molecular Weight: 308.35
Vapor Pressure:
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 161°c
Solubility: Insoluble (H2O)
Safety Hazard:
AIV-294
-------
Warfarin
Annual U.S.
Production:
Fraction of
Dispersion:
12.0 x 10" Ibs.
PRODUCTION DATA
Consumption:
Estimated as 1.0
Release Rate (million Ibs/yr): 13.0
Fraction of Pro-
duction Lost: 0.015
TOXICITY DATA
Acute Toxicity
LD50
Dosage
58 to 323 mg/kg
3 mg/kg
186 mg/kg
165 mg/kg
200 mg/kg
200 mg/kg
800 mg/kg
100 mg/kg
182 mg/kg
420 mg/kg
Non-lethal Acute Effects:
Inhibition of prothromben formation
Capillary damage
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Animal
rat
rat
rat
mouse
dog
dog
rabbit
rabbit
guinea pig
rat
Route
oral
oral
intravenous
intravenous
oral
intravenous
oral
intravenous
oral
intrapertioneal
TLV: 0.1 mg/m3
AIV-295
-------
m-Xylene
CAS Number: 108-38-3
Chemical Name: m-Xylene
Synonyms: m-Xylol
Molecular
Formula: C8H10
CHEMICAL NAME
Structure:
CH,
Chemical Properties
Molecular Weight: 106.2
Vapor Pressure: 8.56 mm at 25°C
Boiling Point: 139°C at 760 mm
Density: 0.864 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient: 3.20
Environmental Persistence
BOD: Total theoretical oxygen demand =3.17 gm/gm
Atmospheric Reactivity: Reacts with oxidizing materials
Activity toward 03: t^ = 100 years
RO2: tw = 2200 years
OH: t\4 = 3 days
Physical State: Liquid
Vapor Density: 3.66
Melting Point: -47.4°C
Solubility: Insoluble (0.13 gm/lH2O)
Common air contaminant, reported at 0.016 to 0.61 ppm
Safety Hazard:
Fire-dangerous
Explosion-moderate
AIV-296
-------
m-Xylene
PRODUCTION DATA
Annual U.S.
Production:
Fraction of
Dispersion:
ca. 1710 x 10° Ibs. (1975)
Consumption: ca. 1710 x 106 Ibs.
(4907.1 x 10 Ibs.-mixed xylenes, 1975)
(0.13-mixedxylenes)
Release Rats (million Ibs/yr): (ca. 765-mixed xylenes)
Fraction of Pro-
duction Lost: 0.01
(4907 x 10° Ibs.-mixed xylenes)
Acute Toxicity
LDSO
LDLo
LCLo,
TOXICITY DATA
Dosage Animal
5 000 mg/kg rat
2000 mg/kg rat
5000 mg/kg rat
8000 ppm (4 hours) rat
Route
oral
intraperitoneal
subcutaneous
inhalation
Chronic Toxicity
U.S. Occupational Standard: NIOSH recommended TWA 100 ppm
Carcinogenicity: Neoplastic effects in mice after dermal application
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Anorexia
CNS disturbances
Hyperglycemia
Leucopenia
Leucocytosis
Epidermal hypertrophy.
TLV: 100 ppm
AIV-297
-------
o-Xylene
CAS Number: 95-47-6
Chemical Name: o-Xylene
Synonyms: o-Xylol
Molecular
Formula: C8H10
CHEMICAL NAME
Structure:
CH,
CH,
Chemical Properties
Molecular Weight: 106.2
Vapor Pressure: 10 mm at 32.1°C
Boiling Point: 144.4°C at 760 mm
Density: 0.880 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient: 2.77
Physical State: Liquid
Vapor Density:
Melting Point: -25°C
Solubility: Insoluble (H2O)
Environmental Persistence
BOD: Total theoretical oxygen demand = 3 J7 gm/gm
Atmospheric Reactivity: Reacts with oxidizing materials
Safety Hazard:
Fire-moderate
Explosion-slight
AIV-298
-------
o-Xylene
PRODUCTION DATA
Annual U.S.
Production: 679.7 x 10* Ibs. (1975) Consumption: 679.7 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: (0.13-mixed xylenes) duction Lost: 0.01
Release Rate (million Ibs/yr): (ca. 765-mixed xylenes)
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDLo 5000mg/kg rat oral
1500mg/kg. rat intra peritoneal
2500mg/kg mouse subcutaneous
6920 ppm mouse inhalation
Chronic Toxicity
U.S. Occupational Standard: NIOSH recommended: (aii) TWA 100 ppm
Carcinogenicity: Neoplastic effects in mice after dermal applications
Mutagenicity:
Teratogenicity: TLV: 100 ppm
Other Chronic Effects:
Leucopenia and leucocytosis
CNS disturbances
Anorexia
Hyperglycemia
Epidermal hypertrophy
AIV-299
-------
p-Xylene
CAS Number: 106-42-3
Chemical Name: p-Xylene
Synonyms: p-Xylol
Molecular
Formula: C8H10
CHEMICAL NAME
Structure:
Chemical Properties
Molecular Weight: 106.2
Vapor Pressure: 10 mm at 27.3°C
Boiling Point: 138.5°C at 760mm
Density: 0-8611 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient: 3.15
Physical State: Liquid
Vapor Density: 3.66
Melting Point: 13.2°C
Solubility: Insoluble (H2O)
Environmental Persistence
BOD: Total theoretical oxygen demand = 3.179 gm/gm
Atmospheric Reactivity: Reacts with oxidizing materials
Activity toward RO2: t^ = 2200 years
P3: **= 100 years
OH: t% = 3 days
Safety Hazard:
Fire-moderate .
Explosion-moderate
AIV-300
-------
p-Xylene
PRODUCTION DATA
Annual U.S.
Production: 2419.3 x 106 Ibs. (1975)
Fraction of
Dispersion:
0.01
Release Rate (million Ibs/yr): 39.9
Consumption: 2419.3 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.01
Acute Toxicity
LDSO
LDLo
LCLo
TOXICITY DATA
5000 mg/kg
2000 mg/kg
5000 mg/kg
3460 ppm
Animal
tat
rat
tat
mouse
Route
oral
intraperitoneal
subcutaneous
inhalation
Chronic Toxicity
U.S. Occupational Standard: NIOSH recommended: TWA 100 ppm
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
Leucopenia and leucocytosis
CNS disturbances
Anorexia
Hyperglycemia
Epidermal hypertrophy
TLV: 100ppm
AIV-301
-------
Xylenesulfonic acid, sodium salt
CHEMICAL NAME
CAS Number: 827-93-0
Chemical Name: 3,4-Xylenesulfonic acid, sodium salt
Synonyms: Sodium xylene sulfonate
Molecular
Formula: C8H10O3S-Na
Structure:
SO,<->Na<+>
CH3
CH,
Chemical Properties
Molecular Weight: 209.23
Vapor Pressure: Negligible at 25°C
Boiling Point:
Density:
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard:
Physical State:
Vapor Density:
Melting Point:
Solubility:
AIV-302
-------
Xylenesulfonic acid, sodium salt
PRODUCTION DATA
Annual U.S.
Production: 37.4 x 106 Ibs. Consumption: 37.4 x 106 Ibs.
Fraction of Fraction of Pro-
Dispersion: 1-0 duction Lost: 0.3
Release Rate (million Ibs/yr): 38.5
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSo . 500 mg/kg mouse intraperitoneal
Chronic Toxicity
U.S. Occupational Standard:
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-303
-------
2, 6-Xylenol
CHEMICAL NAME
CAS Number: 576-26-1
Chemical Name: 2,6-Dimethylphenol
Synonyms: Xylenol
Molecular
Formula: C8H10O .
OH
Structure: CH3
Chemical Properties
Molecular Weight: 122.18
Vapor Pressure:
Boiling Point: 212°C at 760mm
Density: 0.984 at 60DC/15.5°C
Octanol/Water Parti-
tion Coefficient: 2.33
E nvironmental Penistence
BOO:
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 49°C
Solubility: Soluble (H2O)
Safety Hazard:
AIV-304
-------
2, 6-Xylenol
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITY DATA
Acute Toxicity Dosage Animal Route
LDSO . 296mg/kg rat oral
980 mg/kg mouse oral
920 mg/kg mouse skin
150 mg/kg mouse intraperitoneal
700 mg/kg rabbit oral
Chronic Toxicity
U.S. Occupational Standard: (air) TWA: 100 ppm
Carcinogenicity:
Neoplastic effects:
TDLo 4000 mg/kg (120 weeks) mouse skin
Mutagenicity:
Teratogenicity: tLV:
Odor perception: 200 ppm
Other Chronic Effects:
AIV-305
-------
3, 5-Xylenol
CHEMICAL NAME
CAS Number: 1300-71-6
Chemical Name: Dimethylphenol
Synonyms: Xylenol
3,5-Xylenol
5-Hydroxy-l, 3-dimethylbenzene
Molecular
Formula: C8H10O
3,5-Dimethylphenol
l-Hydroxy-3,5-dimethylbenzene
Structure:
Chemical Properties
Molecular Weight: 122.17
Vapor Pressure: 1 mm at 62.0°C
Boiling Point: 219.5°C (sublimes)
Density: 0.9680 at 20°C/4°C
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOD: 31% of theoretical
Atmospheric Reactivity:
Physical State: Solid
Vapor Density:
Melting Point: 68°C
Solubility: Soluble (H2O)
Safety Hazard:
Fiie-slight
AIV-306
-------
3, 5-Xylenol
PRODUCTION DATA
Annual U.S.
Production: Consumption:
Fraction of Fraction of Pro-
Dispersion: duction Lost:
Release Rate (million Ibs/yr):
TOXICITYDATA
Acute Toxicity Dosage Animal Route
LD5o 1070 mg/kg mouse oral
1750 mg/kg guinea pig subcutaneous
Chronic Toxicity
U.S. Occupational Standard: (air) TWA: 100 ppm
Carcinogenicity:
Mutagenicity:
Teratogenicity: TLV:
Other Chronic Effects:
AIV-307
-------
Zinc stearate
CHEMICAL NAME
CAS Number: 557-05-1
Chemical Name: Octadecanoic acid, zinc salt
Synonyms: Stearic acid, zinc salt
Molecular
Formula: (ci8H35°2*2 °Zn
Structure: [CH3(CH2)lfi COO"] 2 Zn2
Chemical Properties
Molecular Weight: 632.30
Vapor Pressure:
Boiling Point:
Density: 1.095
Octanol/Water Parti-
tion Coefficient:
Environmental Persistence
BOO:
Atmospheric Reactivity:
Safety Hazard:
Fire-slight
Physical State: Solid
Vapor Density:
Melting Point: 130°C
Solubility: Insoluble (H2O)
AIV-308
-------
Zinc stearate
Annual U.S.
Production: 19.4 x 106 Ibs.
Fraction of
Dispersion:
1.0
PRODUCTION DATA
Consumption: 19.4 x 106 Ibs.
Fraction of Pro-
duction Lost: 0.03
Release Rate (million Ibs/yr): 20.0
Acute Toxicity
Non-lethal Acute Effects:
Pulmonary fibrosis
TOXICITY DATA
Dosage Animal
Route
Chronic Toxicity
U.S. Occupational Standard:
Carcinogen icity:
Mutagenicity:
Teratogenicity:
Other Chronic Effects:
TLV:
AIV-309
-------
CHEMICAL NAME INDEX
Acenaphthylene AI-2
Acetaldehyde AI-6
Acetamide AI-10
Acetanilide AI-14
Acetic acid AI-16
Acetic acid, butyl ester AI-160
Acetic acid, sec butyl ester AI-162
Acetic acid, decyl ester AII-90
Acetic acid, 1,1-dimethylethyl ester AI-164
Acetic acid, ethyl ester AII-234
Acetic acid, isobutyl ester AIII-62
Acetic acid, methyl ester AIII-148
Acetic acid, 1-methylethyl ester AIII-84
Acetic acid, pentyl ester AI-64
Acetic acid, propyl ester AIV-108
Acetic acid, sodium salt AIV-140
Acetic anhydride AI-18
Acetoacetic acid, ethyl ester AIIr-236
Acetoacetic acid, methyl ester AIII-150
Acetone AI-20
Acetonitrile AI-24
3-(a-Acetonylbenzyl)-4-hydroxycoumarin AIV-294
Acetophenone AI-26
Acetylene AI-28
Acrolein AI-34
Acrylamide AI-36
Acrylic acid AI-38
Acrylic acid, butyl ester AI-166
Acrylic acid, ethyl ester AII-238
Acrylonitrile AI-40
Adipic acid AI-42
Adipic acid, bis(2-ethylhexyl)ester AII-104
Allyl alcohol AI-48
1-Allylnaphthalene AI-54
o-Aminobenzenesulfonic acid AIV-162
p-Aminobenzoic acid AI-58
3-Amino-2,5-dichlorobenzoic acid AI-56
2-Aminoethanol AII-230
2-[(2-Aminomethyl)amino]-ethanol AI-62
4-[(4-Aminophenyl)(4-imino-2,5-cyclohexadien-l-ylidene)-
methyl]-2-methyl benzenamine AIII-112
4-Amino-3,5,6-trichloropicolinic acid AIV-52
Aniline AI-78
Anilidine hydrochloride AI-80
AIV-310
-------
CHEMICAL NAME INDEX (Continued)
o-Anisidine AI-82
p-Anisidine AI-82
Anisole AI-84
Anthranilic acid AI-86
Anthraquinone . AI-88
Aroclor 1254 and 1260 AIV-66
Benzaldehyde AI-98
Benzamide AI-100
Benzene AI-102
1,2-Benzenedicarboxylic acid,
bis (8-methylnonyl)ester AII-122
1,2-Benzenedicarboxylic acid, dioctyl ester AII-124
m-Benzene disulfonic acid AI-104
Benzene methanamine AI-130
Benzene sulfonic acid , AI-106
Benzidine AI-108
Benzil AI-110
Benzilic acid AI-112
Benzoic acid AI-114
Benzoic acid, benzyl ester AI-134
Benzoic acid, sodium salt AIV-142
Benzoin AI-116
Benzonitrile AI-118
Benzophenone AI-120
p-Benzoquinone AI-122
Benzoyl chloride AI-126
Benzyl alcohol AI-128
Biphenyl AII-182
4-Biphenyl amine AI-60
Bis-(2-butoxyethyl)ether AII-82
N,N-Bis(carboxymethyl)glycine, trisodium salt AIII-258
Bis(2-chloroethyl)ether AII-50
Bis(a,a-dimethylbenzyl)peroxide AII-68
Bis(dimethylthiocarbamoyl)disulfide AIV-206
Bis(2-ethoxyethyl) ether AII-84
2,2-Bis(hydroxymethyl)-1,3-propanediol AIV-18
Bis-(2-methylpropyl)carbamothioic acid, S-ethyl ester AIV-168
Bromobenzene AI-146
5-Bromo-3-sec-butyl-6-methyluracil AI-144
Bromomethane AII-248
Bromomethane AIII-166
2-Bromonaphthalene AI-148
1,3-Butadiene AI-150
(S)2-Butanamine AI-176
Butane AI-152
1,3-Butanediol AI-184
1-Butanethiol AI-188
AIV-311
-------
CHEMICAL NAME INDEX (Continued)
2-Butanone AIII-192
1-Butene AI-154
2-Butene AI-156
Butene, homopolymers AIV-64
2-Butoxyethanol AI-158
a-[2-(2-Butoxyethoxy)ethoxy]-4,5-(methylenedioxy)-
2-propyltoluene AIV-58
(Butoxymethyl)oxirane AI-186
Butyl alcohol AI-168
sec-Butyl alcohol AI-170
tert-Butyl alcohol AI-172
t-Butylamine AI-178
p-tert-Butylphenol AI-190
p-tert-Butyltoluene AI-192
Butyraldehyde AI-174
Butyric acid AI-194
Butyric anhydride AI-196
Butyronitrile AI-198
Calcium propionate , AI-204
Camphor AI-208
Carbamic acid, 2,3-dihydro-2,2-dimethyl-
7-benzofuranyl ester AI-216
Carbondisulfide AI-218
4,4'-Carbonimidoyl bis[N,N-dimethyl]benzenamine AI-90
Carbon tetrabromide AI-220
Carbon tetrachloride AI-222
Castor oil AI-224
Cellulose acetate AI-226
Cellulose, carboxymethyl ether, sodium salt AIV-144
Cellulose, ethyl ether AII-252
Chloroacetaldehyde AI-232
Chloroacetic acid AI-234
Chloroacetic acid, ethyl ester AII-256
Chloroacetic acid, sodium salt AIV-146
2-Chloroacetophenone AI-236
m-Chloroaniline AI-238
o-Chloroaniline AI-240
p-Chloroaniline AI-242
2-Chloro-4,6-bis(ethylamino)-s-triazine AIV-90
2-Chloro-4,6-bis(isopropylamino)-s-triazine AIV-100
o-Chlorobenzaldehyde AI-244
p-Chlorobenzaldehyde AI-246
Chlorobenzene AI-248
Chlorobenzoic acid (2,3, and 4) AI-252
o-Chlorobenzoyl chloride AI-254
o-Chlorobenzylidene malonitrile AI-256
AIV-312
-------
CHEMICAL NAME INDEX (Continued)
Page
3-Chloro-l,3-butadiene
m-Chlorocarbanilic acid, isopropyl ester
2-Chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide
Chlorodifluoroethane
Chlorodifluoromethane
l-Chloro-2,3-epoxypropane
Chloroethane
2-Chloroethanol
2-Chloro-4-ethylamino-6-isopropylamino-s-triazine
Chloroethylene
Chloroethylene, polymers
Chloroform
Chloromethane
2-Chloro-N-(1-methylethyl)-N-phenylacetamide
3-Chloro-2-methylpropene
1-Chloronaphthalene
1-Chloro-3-nitrobenzene
l-Chloro-2-nitrobenzene
l-Chloro-4-nitrobenzene
1-Chloro-l-nitropropane
1-Chloropentane
m-Chlorophenol
p-Chlorophenol
p-Chlorophenol
1-Chloropropane
2-Chloropropane
2-Chloro-l-propanol
3-Chloropropene
a-Chlorotoluene
m-Chlorotoluene
o-Chlorotoluene
p-Chlorotoluene
C.I. Solvent Yellow 2
Citric acid
Coal tar naphtha
m-Cresol
o-Cresol
p-Cresol
(E)-Crotonaldehyde
Crotonic acid
Cumene
Cyanoacetic acid
Cyanoacetic acid, ethyl ester
Cyanogen chloride
Cyclohexane
AI-282
AI-284
AI-44
AI-258
AI-260
AII-224
AII-254
AII-264
AI-262
AIV-288
AIV-88
AI-264
AIII-174
AIV-92
AIII-136
AI-266
AI-268
AI-270
AI-272
AI-274
AI-70
AI-276
AI-278
AI-280
AIV-114
AIII-90
AIV-118
AI-50
AI-136
AI-286
AI-288
AI-290
AII-138
AI-292
AIII-238
AI-296
AI-298
AI-300
AI-302
AI-304
AI-306
AI-310
AII-258
AI-312
AI-318
AIV-313
-------
CHEMICAL NAME INDEX (Continued)
Cyclohexanol
Cyclohexanone
Cyclohexene
4-Cyclohexene-l,2-dicarboxylic acid
Cyclohexylamine
1,3-Cyclopentadiene
Decahydronaphthalene
Decyl alcohol
N,N-diethy1-m-toluamide
N,N-dially1-2-chloroacetamide
3,5-Diaminobenzoic acid
Diazomethane
1,2-Dibromo-3-chloropropane
1,2-Dibromomoethane
Dibromodifluoromethane
2,6-Di-tert-butyl-p-cresol
2,4-Dichloroaniline
3,4-Dichloroaniline
o-Dichlorobenzene
p-Dichlorobenzene
3,3'-Dichlorobenzidine
Dichlorodifluoromethane
1,3-Dichloro-5,5-dimethylhydantoin
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
1,2-Dichloroethylene (Z and E)
4,4'-Dichlorobenzilic acid, ethyl ester
Dichlorofluoromethane
Dichloromethane
3,6-Dichloro-2-methoxybenzoic acid
1,5-Dichloropentane
(2,4-Dichlorophenoxy)acetic acid
2- ( 2,4-Dichlorophenoxy)ethanol,hydrogensulfate,
sodium salt
3-(3,4-Dichlorophenyl)-1,1-dimethylurea
3-(3,4-Dichlorophenyl)-1-inethoxy-l-methylurea
N-(3,4-Dichlorophenyl)propanamide
1,2-Dichloropropane
l,3-Dichloro-2-propanol
1,3-Dichloropropene
2,2-Dichloropropionic acid, sodium salt
Dichlorotetrafluoroethane
a,o-Dichlorotoluene
4,4'-Dichloro-a-(trichloromethy1)benzhydrol
Dicyclohexylamine
AI-320
AI-322
AI-324
AIV-192
AI-326
AI-328
AII-12
AII-14
AII-16
AIV-128
AII-22
AII-26
AII-8
AII-268
AII-28
AII-30
AII-34
AII-36
AII-38
AII-40
AII-42
AII-44
AII-46
AII-312
AII-270
AIV-290
AII-48
AI-250
AII-52
AIII-186
AI-94
AII-56
AII-58
AI-294
AI1-200
AIII-110
AIV-96
AII-60
AII-54
AII-62
AII-4
AII-64
AI-138
AII-66
AII-70
AIV-314
-------
CHEMICAL NAME INDEX (Continued)
Diethylacetal acetaldehyde
Diethylamine
2-(Diethylamino)ethanol
Diethyleneglycol
2,2'-Diethylenetriamine
a,a-Diethyl-4,4'-stilbenediol
1,1-Difluoroethane
1,2-Dihydro-3,6-pyridazinedione
1,2-Dihydro-2,2,4-trimethylquinoline
Diisobutylene
DiisopropyIamine
3,3'-Dimethoxybenzidine
D ime thoxyme thane
(E)-3[(Dimethoxyphosphinyl)oxy]-2-butenoic acid,
methyl ester
Dimethylacetal acetaldehyde
N,N-Dimethylacetamide
DimethyIamine
N,N-Dimethylaniline
3,3'-DimethyIbenzidine
a, ot-Dimethy Ibenzylhydroperoxide
1,1'-Dimethy1-4,4'-bipyridium dichloride
1,3-Dimethylbutyl acetate
(1,1-Dimethylethyl) benzoic acid
N,N-DimethyIformamide
1,1-Dimethylhydrazine
1,2-Dimethylhydrazine
2,6-Dimethyl-4-heptanone
N-(1,4-Dimethylpentyl)-N'phenyl-p-phenylene-diamine
2,6-Dimethylphenol
3,5-Dimethylphenol
N,N-Dimethyl-a-phenylbenzeneacetamide
0,0-Dimethylphosphorodithioic acid,
O-(p-nitrophenyl)ester
1,l-Dimethyl-3-(a,a,a-trifluoro-m-tolyl)urea
1,2-Dinitrobenzene
1,3-Dinitrobenzene
1,4-Dinitrobenzene
2,4-Dinitrobenzoic acid
Dinitrophenol
2,4-Dinitrotoluene
p-Dioxane
1,3-Dioxolane
1,3-Dioxolan-2-one
Diphenylamine
AI-4
AII-76
AII-78
AII-80
AII-102
AII-108
AII-112
AIII-120
AII-116
AII-118
AII-126
AII-132
AIII-152
AIII-224
AII-280
AII-134
AII-136
AII-140
AIV-208
AI-308
AIV-12
AII-142
AI-180
AII-146
AII-148
AII-150
AII-120
AII-152
AIV-304
AIV-306
AII-180
AIII-214
AIII-6
AII-164
AII-164
AII-164
AII-166
AII-170
AII-172
AII-176
AII-178
AII-262
AII-184
AIV-315
-------
CHEMICAL NAME INDEX (Continued)
Diphenylmethane AI-132
Dipropylcarbamothioic acid, S-propyl ester AIV-284
Dipropylene glycol AII-190
Dipropylene glycol, monomethyl ether AII-192
1,la,2,2,3,3a,4,5,5,5a,5b,6-Dodecachloro-
octahydro-l,3,4-metheno-lH-cyclobuta(Cd) pentalene AIII-226
Dodecane AII-202
1-Dodecanethiol AII-208
1-Dodecene AIV-202
Dodecyl benzene .AII-204
Dodecylbenzenesulfonic acid, sodium salt AII-206
Dodecylguanidine, monoacetate AI-330
Dodecylphenol AII-210
Ethane AII-228
Ethanethiol AII-314
Ethanol AII-240
Ethanol, homopolymers AIV-86
2-Ethoxyethanol AII-286
2-Ethoxyethanol acetate AII-288
2-(2-Ethoxyethoxy)ethanol AII-92
2-(2-Ethoxyethoxy)ethanol acetate AII-94
Ethanamine AII-242
Ethylbenzene AII-246
Ethylbenzene, homopolymer AIV-80
S-Ethyldipropylthiocarbamate AII-226
Ethylene AII-261
Ethylene bis(dithiocarbamic acid), disodium salt AIII-234
Ethylene glycol AII-272
Ethylene glycol, diacetate AII-274
Ethylenediamine AII-266
Ethylene glycol, diethyl ether AII-278
Ethylene glycol, monoacetate AII-282
Ethylene oxide " AII-304
Ethylene, polymers AIV-68
Ethyleneimine AII-302
Ethyl ether AII-306
2-Ethyl-l-hexanol AII-310
4-Ethylmorpholine AII-318
1-Ethylnaphthalene AII-320
N-Ethyl-N-nitrosourea . AIII-290
Ethylphosphonpdithioic acid,
0-ethyl-S-phenyl ester AII-218
Ferbam AIII-2
AIV-316
-------
CHEMICAL NAME INDEX (Continued)
Ferrocene
N-Fluoren-2-yl-acetamide
Formaldehyde
Formamide
Formic acid
Formic acid, ethyl ester
Formic acid, methyl ester
Formic acid, sodium salt
Furmaric acid
2-Furaldehyde
Furfuryl alcohol
D-Glucitol
L-Glutamic acid, monosodium salt
Glycerol
Glycine
Glyoxal
Guanidine
1,4,5,6,7,8,8-Heptachloro-3a,4,7,7a-tetrahydro-4,
7-methanoindene
3-Heptanone
3-Heptene (Z and E)
1,2,3,4,5,6-Hexachlorocyclohexane(gamma isomer)
1,2,3,4,10,10-Hexachloro-6,7-epoxy-l,4,4a,5,6,7,
8,8a-octahydro-l,4,5,8-dimethanonaphthalene
Hexachloroethane
1,2,3,4,10,10-Hexachloro-l,4,4a,5,8,8a-hexahydro-
1,4,5,8-dimethanonaphthalene
Hexachloronaphthalene
1,4,5,6,7,7-Hexachloro-5-norbornene-2,
3-dimethanol, cyclic sulfite
Hexahydro-2H-azepin-2-one
3-(Hexahydro-4,7-methanoindan-5-yl)-1,
1-dimethylurea
Hexamethylenetetramine
1,6-Hexanediamine
1,6-Hexanediol
2-(Hexyloxy)ethanol
2-[2-(Hexyloxy)ethoxy]ethanol
Hydrocyanic acid
a-Hydro-0-hydroxypoly[oxy(methyl-1,2-ethanediyl)
Hydroquinone
3-Hydroxybutyraldehyde
Hydroxymethyl arsine oxide
4-Hydroxy-4-methyl-2-pentanone
AIII-4
AI-12
AIII-12
AIII-14
AIII-16
AII-308
AIII-194
AIV-148
AIII-18
AIII-20
AIII-22
AIV-154
AIII-228
AIII-24
AIII-30
AIII-32
AIII-34
AIII-38
AII-250
AIII-40
AIII-108
AII-72
AIII-44
AI-46
AIII-46
AII-220
AI-210
AIII-50
AIII-52
AIII-48
AII-290
AII-96
AIII-54
AIV-78
AIII-56
AI-8
AI-202
AII-20
AIV-317
-------
CHEMICAL NAME INDEX (Continued)
2,2*-Iminodiethanol
IH-Indene
lodomethane
Isopentyl alcohol
2-(2-Isobutoxyethoxy)ethanol
Isobutyl alcohol
Isobutyraldehyde
Isobutyric acid
Isocyanic acid, methyl ester
Isocyanic acid,i2-methy 1-m-phenylene ester
Isodecyl alcohol
IH-Isoindole-l,3(2H)-dione
Isooctanol
Isooctyl alcohol
26-(Isooctylphenoxy)-3,6,9,12,15,18,21,24-
octaoxahexacosan-1-ol
Isophthalic acid
Isoprene
Isopropyl alcohol
Isopropylamine
Isopropyl ether
4,4'-Isopropylidenediphenol
o-Isopropyl phenol
p-Isopropyl phenol
Ketene
Ligninsulfohic acid, ammonium salt
Ligninsulfonic acid, calcium salt
Ligninsulfonic acid, sodium salt
Ligninsulfonic acid, ferrochrome salt
Maleic acid
Maleic anhydride
Malic acid (DL,D and L)
Melamine
Mercaptosuccinic acid, diethyl ester, S-ester with
0,0-dimethyl phosophorodithioate
Methacrylic acid
Methacrylic acid, methyl ester
Methacrylonitrile
Methane
Methane arsonic acid
Methanearsonic acid, disodium salt
Methanearsonic acid, monosodium salt
Methanesulfonic acid, ethyl ester
Methanethiol
Methanol
AII-74
AIII-58
AIII-198
AIII-60
AII-88
AIII-64
AIII-66
AIII-70
AIII-204
AIV-214
AIII-72
AIV-46
AIII-74
AIV-2
AIII-76
AIII-80
AIII-82
AIII-86
AIII-88
AIII-92
AI-142
AIII-94
AIII-96
AIII-98
AIII-100
AIII-102
AIII-106
AIII-104
AIII-116
AIII-118
AIII-122
AIII-124
AIII-114
AIII-130
AIII-208
AIII-132
AIII-138
AIII-140
AII-194
AIII-232
AII-316
AIII-206
ALII-154
AIV-318
-------
CHEMICAL NAME INDEX (Continued)
2-Methoxyethanol
2-Methoxyethanol acetate
2-(2-Methoxyethoxy)ethanol
2-(2-Methoxyethoxy)ethanol acetate
2-[-2-(2-Methoxyethoxy)ethoxy]ethanol
l-Methoxy-4-nitrobenzene
Methylamine
N-([(Methylamino)carbonyl]oxy)ethanimidothioic acid,
methyl ester
N-Methylaniline
2-Methylaziridine
a-Methylbenzenemethanol
a-Methylbenzyl alcohol
2-Methyl-2-butene
Methyl-1-n-butyl ketone
3-(1-MethyIbutyl)phenol methylcarbamate
2-Methyl-3-butyn-2-ol
Methylcarbamic acid, 1-naphthyl ester
3-Methylcholanthrene
Methylcyclohexane
Methylcyclohexanol
2-Methylcyclohexanone
2-Methyl-4,6-dinitrophenol
Methyldioxolane ,
4,4'-Methylene bis(2-chloroaniline)
4,4'-Methylenedianiline
4-Methylene-2-oxetanone
Methyl ether
Methyl ether cellulose
4-Me thy1-3-heptanone
5-Methyl-2-hexanone
Methylhydrazine
2-Methyl lactonitrile
2-Methyl-2-(methylthio)propionaldehyde-0-
methyl-carbamoyl)oxime
Methylnaphthalene
N-Methyl-N'-nitro-N-nitrosoguanidine
N-Methyl-N-nitrosourea
2-Methyl-2,4-pentanediol
Methylamyl alcohol
4-Methy1-2-pentanol, acetate
4-Methy1-2-pentanone
4-Methyl-3-penten-2-one
3-Methyl-l-pentyn-3-ol
AIII-146
AII-294
AII-98
AII-100
AIV-268
AIII-262
AIII-156
AIII-142
AIII-162
AIV-122
AIII-220
AIII-164
AIV-22
AIII-168
AI-200
AIII-170
AI-214
AIII-176
AIII-178
AIII-180
AIII-182
AII-168
AIII-190
AIII-184
AIII-188
AII-128
AII-144
AIII-172
AII-244
AIII-200
AIII-196
AI-22
AIV-176
AIII-210
AIII-212
AIII-292
AIII-216
AIII-160
AIII-158
AIII-202
AIII-128
AIII-218
AIV-319
-------
CHEMICAL NAME INDEX (Continued)
Methylphosphoramidic acid, 4-tert-butyl-2-
chlorophenylmethyl ester
1-Methylpropene
2-Methyl-l-propene
2-Methyl-l-propene, homopolymer
2-Methyl-2-propen-l-ol
2-(l-Methylpropyl)-4,6-dinitrophenol
a-Methylstyrene
p-Me thyIs tyrene
Methylsulfide
4-(Methylsulfonyl)-2,6-dinitro-N,N-dipropylaniline
Methylsulfoxide
N-methyl-N,2,4,6-tetranitroaniline
Monostearin
Morpholine
Naphthalene
1-Naphthalenesulfpnic acid
2-Naphthalenesulfonic acid
1-Naphthol
2-Naphthol
1-Naphthylamine i
2-Naphthylamine
2-[(l-Naphthalenylamino)carbonyl]benzoic acid,
monosodium salt
Nitrate cellulose
2,2?,2"-Nitrilotriethanol
p-Nitroaniline
Nitrobenzene
p-Nitrobenzoic acid
Nitroethane
Nitroglycerine
Nitromethane
o-Nitrophenol
3-Nitrophenol
p-Nitrophenol
1-Nitropropane
2-Nitropropane
N-Nitrosodiethylamine
N-Nitrosodimethylamine
m-Nitrotoluene
o-Nitrotoluene
p-Nitrotoluene
Nonene
Nonoylphenol
1,2,4,5,6,7,8,8-Octachloro--3a,4,7,7a-tetrahydro-4,
7-methanoindan
AIV-134
AI-182
AIII-68
AIV-272
AIII-134
AII-174
AIII-222
AIV-292
AII-158
AIV-60
AII-160
AIV-204
AIII-26
AIII-230
AIII-240
AIII-242
AIII-244
AIII-246
AIII-248
AIII-250
AIII-252
AIII-254
AIII-268
AIV-260
AIII-260
AIII-264
AIII-266
AIII-270
AIII-272
AIII-274
AIII-278
AIII-276
AIII-280
AIII-282
AIII-284
AIII-286
AIII-288
AIII-294
AIII-296
AIII-298
AIII-300
AIII-302
AI-230
AIV-320
-------
CHEMICAL NAME INDEX (Continued)
Octadecanoic acid, zinc salt
2-(Octyloxy)ethanol
Octylphenol
7-Oxabicyclo(2.2.1)heptane-2,3-dicarboxylic acid
Oxalic acid
Oxalic acid, diethyl ester
2-Oxetanone
1,1'-Oxybis[2-methoxyethahe]
Oxybis(chloromethane)
Pentachloronitrobenzene
Pentachlorophenol
Pentane
1-Pentanethiol
1-Pentene
Pentyl alcohol
Pentylamine
Pentyl ether
o-Phenetidine
p-Phenetidine
Phenol
Phenol, sodium salt
Phenothiazine
2-Phenoxyethanol
o-Phenylenediamine
p-Phenylenediamine
Phenyl ether
Phenylhydrazine
Phosgene
Phosphoric acid, l,2-dibromo-2,2-dichloroethyl
dimethyl ester
Phosphoric acid, (Z)dimethy1-1-methy1-3(methylamino)-
2-oxo-l-propenyl ester
Phosphoric acid, tributyl ester
Phosphoric acid, tri-o-tolyl ester
Phosphorodithioic acid, S-[[(p-chlorophenyl)thio]
methyl]-0,0-diethyl ester
Phosphorodithioic acid, 0,0-diethyl-S-[2(ethylthio)
ethyl] ester
Phosphorodithioic acid, 0,0-diethy1-0-(3,5,6-
trichloro-2-pyridinyl) ester
Phosphorodithioic acid, 0,0-dimethyl ester, S-ester
with 3-(mercaptomethyl)-1,2,3-benzotriazin-4(3H)-one
AIV-308
AII-296
AIV-6
AII-222
AIV-8
AII-322
AIV-102
AII-86
AI-140
AIV-14
AIV-16
AIV-20
AI-76
AI-72
AI-66
AI-68
AI-74
AIV-28
AIV-30
AIV-32
AIV-150
AIV-34
AII-298
AIV-38
AIV-40
AII-186
AIV-36
AIV-42
AIII-236
AI-92
AIV-232
AIV-256
AIV-280
AII-196
AII-216
AIII-36
AIV-321
-------
CHEMICAL NAME INDEX (Continued)
Phosphorodithioic acid, S-ester with 2-mercapto-N-
methylacetamide 0,0-dimethyl ester AII-130
Phosphorodithioic acid, S,S'-methylene 0,0,0',0'-
tetraethyl ester AII-232
Phosphorothioic acid, 0,0-diethyl-0-(2-isopropyl-6-
methyl-4-pyrimidyl) ester AII-24
Phosphorothioic acid, 0,0-diethyl-0-[p-(methylsulfinyl)
phenylJester AII-6
Phosphorothioic acid, 0,0-diethyl-0-(p-nitrophenol)
ester AII-324
Phosphorothioic acid, 0,0-dimethy1-0-(2,4,5-
trichlorophenyl)ester AIV-132
Phosphorotrithious acid, tributyl ester AIII-8
Phthalic acid, bis(2-ethylhexyl)ester AII-106
Phthalic acid, decyl octyl ester AIV-4
Phthalic acid, dibutyl ester AII-32
Phthalic acid, dimethyl ester AII-154
Phthalic acid, ditridecyl ester AII-198
Phthalic anhydride AIV-44
Phthalonitrile AIV-48
B-Picoline AIV-50
Piperazine AIV-56
Pivalic acid AIII-256
Polyethylene glycol chloride AIV-72
Polyethylene glycols AIV-70
Poly(oxy-1,2-ethanediyloxycarbonyl-l,
4-phenylenecarbonyl) AIV-74
Polystyrene, thermoplastic resins AIV-80
Propane AIV-94
1,2-Propanediol AIV-120
2-Propenamide, homopolymer AIV-62
Propene AIV-116
1-Propene, homopolymer AIV-76
Propene oxide AIV-124
Propionaldehyde AIV-104
Propionic acid AIV-106
2-Propoxyethanol AII-300
Propyl alcohol AIV-110
Propylamine AIV-112
Propyne AI-52
2-Propyn-l-ol AIV-98
Pyridine AIV-126
Resorcinol AIV-130
Salicylic acid AIV-136
Silicic acid, tetraethyl ester AII-326
AIV-322
-------
CHEMICAL NAME INDEX (Continued)
Sorbic acid AIV-152
Stearic acid, calcium salt AI-206
Styrene AIV-156
Succinic acid . AIV-158
Succinonitrile AIV-160
Sulfobutanedioic acid, l,4-bis(2-ethylhexyl)ester,
sodium salt ' AIV-166
Sulfuric acid, diethyl ester AII-110
Sulfuric acid, dimethyl ester AII-156
Sulfuric acid, monodbdecyl ester, compounded with
2,2',2"-nitrilotris[ethanol](l:l) AII-214
Sulfuric acid, monododecyl ester, sodium salt AII-212
Terephthalic acid AIV-174
Terephthalic acid, dimethyl ester AII-162
2,3,5,6-Tetrachloro-p-benzoquinone AI-228
1,1,2,2-Tetrabromoethane AI-30
2,3,5,6-Tetrachloro-l,4-benzenedicarboxylic acid,
dimethyl ester AII-2
1,1,1,2-Tetrachloro-2,2-difluoroethane AIV-180
l,l,2,2-Tetrachloro-l,2-difluoroethane AIV-178
1,1,2,2-Tetrachloroethane AI-32
Tetrachloroethylene AIV-24
N-(1,1,2,2-Tetrachloroethylthio)-4-cyclohexone-l,
2-dicarboximide AII-114
1,2,3,4-Tetrachloro-l,2,3,4-tetrahydronaphthlene AIV-182
Tetrachlorophthalic anhydride AIV-184
Tetraethylplumbane AIV-186
Tetrafluoroethene AIV-84
Tetrahydrofuran AIV-188
1,2,3,4-Tetrahydronaphthalene AIV-190
Tetrahydrothiophene-l,l-dioxide AIV-164
N,N,N',N'-Tetramethyl-ethylenediamine AIV-194
Tetramethylplumbane AIV-196
Tetramethyl succinonitrile AIV-198
Tetranitromethane AIV-200
2,5,8,11-Tetraoxadodecane AIV-266
Thiocarbanilide AII-188
Toluene AIV-210
Toluene-2,4-diamine AIV-212
p-Toluenesulfonylamide AIV-216
o-Toluenesulfonic acid AIV-218
p-Toluenesulfonic acid AIV-220
p-Toluenesulfonyl chloride AIV-222
m-Toluidine AIV-224
o-Toluidine AIV-226
AIV-323
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CHEMICAL NAME INDEX (Concluded)
p-Toluidine
Toxaphene
s-Triazine-2,4,6-triol
~S,S,S,-Tributyl phosphorotrithioate
Trichloroacetic acid
2,4,6-Trichloroaniline
3,5,6-Trichloro-o-anisic acid
1,2,4-Trichlorobenzene
2,3,6-Trichlorobenzoic acid
1,1,1-Trichloro-2,2-bis(p-chlorophenyl)ethane
1,1,1-Trichloro-2,2-bis(p-methoxyphenyl)ethane
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
Trichlorofluoromethahe
Trichloromethanethiol
N(Trichloromethyl)thio-4-cyclohexene-l,
2-dicarboximide
N-[(Trichloromethyl)thio]phthalimide
1,4,6-Trichloronaphthalene
(2,4,5-Trichlorophenoxy)acetic acid
2-(2,4,5-Trichlorophenoxy)propionic acid
1,2,3-Trichloropropane
a,a^a-Trichlorotoluene
2,4,6-Trichloro-s-triazine
1,3,5-Trichloro-s-triazine-2,4,6-(1H,3H,5H)-trione
1,1,2-Trichloro-l,2,2-Trifluoroethane
p-Tridecylbenzenesulfonic acid, sodium salt
Triethylamine
Triethylene glycol
a,a,a-Trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine
Trimethylamine
1,3,4-Trimethylbenzene
2,6,6-Trimethylbicyclo(3.1.l)hept-l-ene
2,6,6-Trimethylbicyclo(3.1.l)hept-2-ene
3,5,5-Trimethyl-2-cyclohexen-l-one
2,2,4-Trimethyl-l,3-pentanediol
2,4,6-Trimethyl-S-trioxane
2,4,6-Trinitrotoluene
Urea
Vinyl acetate
m-Xylene
o-Xylene
p-Xylene
3,4-Xylenesulfonic acid, sodium salt
AIV-228
AIV-230
AI-314
AII-18
AIV-172
AIV-234
AI-96
AIV-236
AIV-170
AII-10
AIII-144
AIV-240
AIV-238
AIV-242
AIV-244
AIV-26
AI-212
AIII-10
AIV-248
AIV-250
AIV-138
AIV-252
AI-124
AI-316
AIV-246
AIV-254
AIV-258
AIV-262
AIV-264
AIV-270
AIV-274
AIII-126
AIV-54
AIV-54
AIII-78
AIV-276
AIV-10
AIV-278
AIV-282
AIV-286
AIV-296
AIV-298
AIV-300
AIV-302
AIV-324
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TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1. REPORT NO.
EPA-450/3-77-OQ8e
2.
3. RECIPIENT'S ACCESSION-NO.
4. TITL
Scoring of Organic Air Pollutants:
Chemistry, Production and Toxicity of Selected
Synthetic Organic Chemicals
icals 0-Z) Appendix IV
5. REPORT DATE
October 1976
6. PERFORMING ORGANIZATION CODE
7. AUT
8. PERFORMING ORGANIZATION REPORT NO.
J. Dorigan, B. Fuller, R. Duffy
9. PERFORMING ORGANIZATION NAME AND ADDRESS
The Mitre Corporation
Metrek Division
Westgate Research Park
McLean, Virginia 22101
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-02-1495
12. SPONSORING AGENCY NAME AND ADDRESS
EPA, Office of Air Quality Planning and Standards
Strategies and Air Standards Division
Research Triangle Park, N.C. 27711
13. TYPE OF REPORT AND PERIOD COVERED
14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
16. ABSTRACT
This is the fourth of a series of four appendices to the report "Scoring
of Organic Air Pollutants." The entire appendix contains a compilation of
available data on chemical structure and properties, environmental persistence,
production, and toxicity for 637 synthetic organic chemicals.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.IDENTIFIERS/OPEN ENDED TERMS C. COSATI Field/Group
organic chemical structure
organic chemical properties
organic chemical production
organic chemical toxicity
18. DISTRIBUTION STATEMENT
19. SECURITY CLASS (ThisReport)
unclassified
21. NO. OF PAGES
331
unlimited
20. SECURITY CLASS (Thispage)
unclassified
22. PRICE
EPA Form 2220-1 (9-73)
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