& EPA United States Control Technology EPA-450/3-89-33 Environmental Protection Center October 1989 Agency Research Triangle Park NC 27711 Powder Coatings Technology Update control * technology center ------- EPA-450/3-89-33 POWDER COATINGS TECHNOLOGY UPDATE CONTROL TECHNOLOGY CENTER SPONSORED BY: Emission Standards Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, NC 27711 Air and Energy Engineering Research Laboratory Office of Research and Development U.S. Environmental Protection Agency Research Triangle Park.NC 27711 Center for Environmental Research Information Office of Research and Development U.S. Environmental Protection Agency Cincinnati, OH 45268 October 1989 ------- EPA-45-/3-89-33 October 1989 POWDER COATINGS TECHNOLOGY UPDATE Prepared by: Charles I. Hester Rebecca L Nicholson Midwest Research Institute 401 Harrison Oaks Boulevard Gary, North Carolina 27513 EPA Contract No. 68-02-4379 Project Officer Karen P. Catlett Chemicals and Petroleum Branch Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, NC 27711 Prepared for: Control Technology Center U.S. Environmental Protection Agency Research Triangle Park, NC 27711 ------- ACKNOWLEDGEMENT This report was prepared for EPA's Control Technology Center (CTC) by Charles Hester and Rebecca Nicholson of Midwest Research Institute. The project officer was Karen Catlett of EPA's Office of Air Quality Planning and Standards (OAQPS). Also on the project team was Robert Blaszczak of OAQPS and Michael Kosusko of the Air and Energy Engineering Research Laboratory. ------- PREFACE The Powder Coating Technology Update report was funded as a project of the U. S. Environmental Protection Agency's (EPA's) Control Technology Center (CTC). The CTC was established by EPA's Office of Research and Development (ORD) and Office of A1r Quality Planning and Standards (OAQPS) to provide technical assistance to State and local air pollution control agencies. This report describes the current status of powder coating technology. It Includes discussions of the advantages, costs, perfor- mance, and end uses of powder coatings. The report 1s available to State and local agencies for their use 1n demonstrating the feasibility of powder coatings as an alternative to coatings containing volatile organic compounds (VOC's). 11 ------- TABLE OF CONTENTS Page List of Abbreviations 1v LIST OF TABLES v SECTION 1.0 INTRODUCTION 1 SECTION 2.0 BACKGROUND 3 SECTION 3.0 POWDER COATING MATERIALS 5 3.1 THERMOPLASTIC POWDERS 5 3.2 THERMOSETTING POWDERS 6 3.3 NEWLY DEVELOPED POWDERS 7 SECTION 4.0 POWDER COATING EQUIPMENT 11 4.1 PRETREATMENT 11 4.2 POWDER APPLICATION 12 4.2.1 Powder Delivery System 12 4.2.2 Electrostatic Spray Gun 12 4.2.3 Powder Spray Booths 14 4.2.4 Powder Recovery and Recycle System 14 SECTION 5.0 END USES OF POWDER COATING. 16 SECTION 6.0 ECONOMIC ADVANTAGES OF POWDER COATING VS. LIQUID COATINGS 21 6.1 ENERGY SAVINGS 21 6.2 LABOR SAVINGS 21 .6.3 GREATER OPERATING EFFICIENCY 22 '6.4 ENVIRONMENTAL BENEFITS 22 6.5 COST COMPARISON: POWDER VS. LIQUIDS 22 6.5.1 Total Capital Costs 22 6.5.2 Material Costs 25 6.5.3 Total Annual Operating Costs 25 SECTION 7.0 CONCLUSIONS 33 SECTION 8.0 REFERENCES 37 APPENDIX A. SURVEY SUMMARY: POWDER COATING EQUIPMENT SUPPLIERS... A-l APPENDIX B. SURVEY SUMMARY: POWDER COATING MANUFACTURERS B-l APPENDIX C. SURVEY SUMMARY: POWDER COATING USERS C-l 111 ------- List of Abbreviations ft » foot ft2 » square foot ft3 * cubic foot g » gram gal » gallon 1n. = Inch kg = kilogram 1b a pound i - liter m a meter m2 * square meter m3 = cubic meter m1n - minute urn » micron » 1x10" meter TGIC a trlglyddyl Isocyanurate VOC » volatile organic compound yr » year 1v ------- LIST OF TABLES Page TABLE la. TYPICAL PROPERTIES OF THERMOSETTING POWDER COATINGS (Metric Units) 8 Table 15. TYPICAL PROPERTIES OF THERMOSETTING POWDER COATINGS (English Units) 9 TABLE 2. END USES FOR EPOXY AND HYBRID POWDER COATINGS 17 TABLE 3. END USES FOR TGIC-POLYESTERS AND ALIPHATIC POLYESTER- URETHANE POWDER COATINGS 18 TABLE 4. END USES FOR AROMATIC URETHANE AND ACRYLIC POWDER COATINGS 19 TABLE 5. TOTAL CAPITAL COSTS 23 TABLE 6a. MATERIAL COSTS (Metric Units) 26 TABLE 6b. MATERIAL COSTS (English Units) 28 TABLE 7a. TOTAL ANNUAL OPERATING COSTS (Metric Units) 30 TABLE 7b. TOTAL ANNUAL OPERATING COSTS (English Units) 31 TABLE 8a. VOC REDUCTION COMPARISON (Metric Units) 34 TABLE 8b. VOC REDUCTION COMPARISON (English Units) 35 ------- 1.0 INTRODUCTION The purpose of this report 1s to provide an overview of the current status of powder coating technology. Powder coating use 1n North America 1s Increasing at a rate approaching 20 percent per year 1n terms of quantities of powder sold.1 Recent Improvements 1n the technology required to manufacture and apply powder coatings, 1n conjunction with environmental considerations, have led to this rapid growth. Many of the drawbacks previously associated with the use of dry powder coating as an Industrial finish have been virtually eliminated. As a result, there are currently about 2,000 powder coating operations 1n the United States and the number 1s Increasing rapidly.2 From an environmental standpoint, the Increased use of powder coatings as an alternative to liquid, solvent-based coatings represents a significant reduction 1n emissions of VOC's. Because powder coatings are applied as dry, finely divided particles, there are no VOC's released durfng application and only minute quantities are released during the curing process. Therefore, the use of powder coatings as a means of reducing VOC emissions from Industrial finishing operations 1s being encouraged by many air pollution control agencies. This report 1s Intended to be helpful to those agencies by providing them Information regarding the types of products being powder coated. It 1s anticipated that this will assist them 1n evaluating powder as a recommended air pollution control technology by answering questions concerning the performance, applicability, costs, and availability of powder coatings. The Information presented 1n this report 1s based on data obtained from literature searches, contacts with several State and local air pollution control agencies, and written survey questionnaires. Survey questionnaires were submitted to nine powder coating equipment suppliers, nine powder coating manufacturers, and nine powder coating users. Three of the nine equipment suppliers responded, and a summary of their responses 1s presented in Appendix A. A summary of the responses from the seven powder coating manufacturers who took part 1n the survey is presented in Appendix B. Four powder coating users responded and that summary 1s contained in Appendix C. ------- The remainder of this report is divided into five sections. The first provides a brief history of powder coatings from the 1950's through the 1980's. The next section describes the different classes of powder coatings that are currently available, including those types of powder resins that have recently been developed. The types of equipment required for a powder coating line and the types of products that are typically powder coated are discussed in Sections 4.0 and 5.0. A list of represen- tative products currently being powder coated is also included in Section 5.0. Section 6.0 discusses the economic advantages of using powder coatings and presents a cost comparison between powder and liquid coatings. Section 7.0 presents the major points discussed in this report and conclusions. ------- 2.0 BACKGROUND The technology for finishing metal products with dry powder coatings rather than with conventional liquid paints has been available in this country since the mid 1950's. By the late 50's, powder was being used to coat pipe for corrosion protection and electric motor parts for Insulation. These coatings were applied using a flu1d1zed-bed process In which heated parts were dipped Into a vat containing powder suspended In air. In this process, once the particles of powder contact and adhere to the heated metal parts, they begin to soften and flow Into a smooth, even layer. Most of the coatings applied 1n fluldlzed beds were vinyl or epoxy powders. Typical coating thicknesses ranged from 150 to 1,000 um (6 to 40 mils) and the applied coatings were functional rather than decorative.3 During the historical development of powder coating technology, there were several disadvantages or potential problems Identified. Today, most of these have been resolved or minimized. The following are some of the major Issues that were problems in the past: 1. Frequent color changes could entail extensive downtime for production lines and the ability to apply a wide range of colors could be restricted by equipment requirements and changeover times. Multiple booths are required for rapid color changes and special equipment is required to recover different colors separately (for recycle). 2. Storage and handling of powder requires special "climate" controls; powder will not remain "fluid" 1f exposed to moisture. 3. Accurate feeding of powder to the spray gun might be difficult, resulting in uneven flow. 4. Color matching and color uniformity appear to be more difficult to achieve than with liquid coatings. 5. Uniformity of coating thickness is sometimes difficult to maintain and thin films 25 to 51 um (1 to 2 mils) are sometimes difficult to achieve. 6. Cure temperatures required for some powders are so high that damage may occur to solder joints or temperature-sensitive parts of the item being coated. High cure temperatures and long cure times require high fuel usage. ------- 7. Powder coatings are especially susceptible to "Faraday cage" effects on sharp Internal corners. 8. Airflow 1n the booth and the area prior to the oven must be carefully controlled to avoid dislodging the unbaked powder. 9. Because of the extra equipment requirements (multiple booths, powder handling and recovery systems), conversion of an existing liquid line could be very expensive. Technological advances in powder coating have addressed most of these Issues. These advances are discussed in this report. The development that opened the way for powder coatings to become a major factor 1n the metal finishing industry was the Introduction of the electrostatic spray process in the early 1960's. Electrostatic spraying of powders allowed the application of relatively thin layers of coatings and allowed powders to be used on parts not suitable for dipping in a fluidized bed. Thus, powder coatings became a viable alternative for decorative as well as functional coatings. The emergence of powder coatings as an alternative to liquid decorative coatings led to the development of a variety of resin systems designed to meet the needs of the diverse user Industries. Epoxy resins were used almost exclusively during the early years of powder coatings. Polyesters, polyester/urethanes, acrylics and (most recently) polyvinylidene fluoride, have now become equally accepted resin systems, with each haying its own market share depending on the performance characteristics needed for the product. Powder coatings currently are available in virtually any color, gloss level, and texture. Recent advances in application technology also have allowed powder coatings to be used in an Increasing number of Industries. Automated finishing systems that allow rapid and frequent color changes and extremely high powder utilization efficiencies have made powder an economical coating in many high-volume industries. (Powder utilization efficiency is defined as the percentage of purchased powder that Is deposited on the work piece [Including any powder that is recovered and resprayed].) ------- 3.0 POWDER COATING MATERIALS As recently as the early 1970's, the powder coating Industry had a limited number of solid resin systems on which to base their powder formulations. Consequently, the ability of the powder coating Industry to meet the diverse needs of the finishing Industry was also limited. Because of the Increased concerns over VOC emissions, worker safety, and energy costs during the 1970's, the popularity of powder coatings grew until powder coatings represented 8 percent of coating used In the finishing Industry by 1987.* As the Interest 1n powders grew, the Industry responded with technological Improvements 1n the resins and with many new resin systems. Powder coatings are now formulated 1n a virtually limitless range of colors, glosses, and textures. The two major types of powder coatings, thermoplastics and thermosettlngs, are discussed below. 3.1 THERMOPLASTIC POWDERS A thermoplastic powder coating Is one that melts and flows when heat 1s applied, but continues to have the same chemical composition once 1t cools and solidifies. Thermoplastic powders are based on high molecular weight polymers that exhibit excellent chemical resistance, toughness, and flexibility. These resins tend to be difficult to grind to the consfstant fine particles needed for spray application, and they have a high melt viscosity. Consequently, they are used mostly 1n thicker film applications and are applied mainly by the fluldlzed bed application technique. Typical thermoplastic powder coatings Include: polyethylene powders, polypropylene powders, nylon powders, polyvlnyl chloride powders, and thermoplastic polyester powders. Polyethylene powders were the first thermoplastic powder coatings to be offered. They provide excellent chemical resistance and outstanding electrical Insulation properties. Polyethylene coatings are smooth, have a medium gloss, and good release properties that allow sticky materials to be cleaned from their surfaces. They are often used as coatings for laboratory equipment. Polypropylene powder produces a surface that 1s very Inert and 1s often used 1n applications where the powder-coated part may be exposed to chemicals. Nylon powders offer excellent abrasion, wear and Impact ------- resistance, and a low coefficient of friction. They are commonly used as mechanical coatings for sliding and rotating bearing applications 1n appliances, farm equipment, and textile machinery. Polyvlnyl chloride powders provide good durability as well as flexibility. An example of products coated with polyvinyl chloride powders 1s dishwasher racks. Thermoplastic polyesters offer good exterior durability and weather- ability. They do not usually require a primer for good adhesion to most metals and are often used for outdoor metal furniture. Thermoplastic powders are especially well suited for a thick coat capable of extreme performance requirements. Because of the Inherent thickness of these coatings, they do not generally compete In the same market as liquid paints. 3.2 THERMOSETTING POWDERS Thermosettlng powder coating's are based on lower molecular weight solid resins. These coatings melt when exposed to heat, flow Into a uniform thin layer, and chemically cross-link within themselves or with other reactive components to form a higher molecular weight reaction product. The final coating has a different chemical structure than the basic resin. These newly formed materials are heat stable and, after curing, do not soften back to the liquid phase when heated. Resins used 1n thermosettlng powders can be ground Into very fine particles necessary for spray application and for applying thin, pa1nt-Hke coatings. Because these systems can produce a surface coating that 1s comparable to, and competes with, liquid coatings, most of the technological advancements 1n recent years have been with thermosettlng powders. Thermosettlng powders are derived from three generic types of resins; epoxy, polyester, and acrylic. From these three basic resin types, five coating systems are derived. Epoxy resin-based systems are the most commonly used thermosettlng powders and are available 1n a wide range of formulations. They are used for both functional and decorative coatings. Functional properties of epoxles Include corrosion resistance and outstanding electrical Insulation. Decorative epoxles offer attractive finishes that are tough, corrosion resistant, flexible, and have high Impact strength. These lack ultraviolet resistance and therefore, are not recommended for outdoor use 1n direct sunlight because ------- of their tendency to chalk and discolor. High chemical reactivity and the use of various classes of hardeners are opening a wide range of applications for epoxles. Recent developments allow epoxles to be cured at temperatures as low as 121°C (250°F) for 20 to 30 minutes, or even shorter times at higher temperatures.5 Epoxy-polyester hybrid coatings consist of epoxy and polyester resins. These coatings are used mainly for decorative applications. They are more resistant to chalking and yellowing than epoxles but have a lower surface hardness and are less resistant to solvents. Polyester-TGIC coatings contain a polyester resin cross-linked with trlglyddyl Isocyanurate (TGIC) as a curing agent. These powders offer very good mechanical properties, Impact strength, and weather resistance. They are resistant to chalking and are often used for such outdoor applications as patio furniture, lawn mowers, and aluminum extrusions and panels for large commercial buildings. Aery11c-urethane coatings are formulated with acrylic resins crosslInked with blocked Isocyanates. They have excellent color, gloss, hardness, weatherability, and chemical resistance. They have an excellent thin film appearance but are less flexible than polyesters. Polyester-urethane coatings are formed by cross-Unking polyester hydroxyl resin with blocked Isocyanate hardeners. Polyurethanes have an outstanding thin film appearance and toughness as well as good weathering properties. Tables la and Ib provide a summary of the key physical properties of the thermosettlng powder coatings described above. 3.3 NEWLY DEVELOPED POWDERS In addition to the coating types discussed above, new developments are occurring 1n the area of enamel powders. Conventional porcelain enamel, the glassy coating traditionally found on metal surfaces such as bathtubs and washing machines, 1s a vitreous Inorganic coating bonded to metal by fusion. The porcelain enameling process Involves the re-fusing of powdered glass on the metal surface. The powdered glass 1s formed by melting oxide components and then quenching to form enamel frits. The frits can be converted to wet sprayable suspensions or to dry enamel powders through ball-milling. The resultant enamel coating 1s heat stable to over 450°C (842°F), color fast, and scratch resistant.7 Enamel ------- 00 TABLE la. TYPICAL PROPERITES OF THERMOSETTING POWDER COATINGS6 (Metric Units) Properties App 1 1 cat 1 on th 1 ckness Cure cycle (metal temperatures )b Outdoor weather ab II Ity Penc 1 1 hardness Direct Impact resistance, cm-kgc Adhesion Chemical resistance Epoxy 25-510 Jim* 232'C-3 mln 121*C-30 mln Poor HB-5H 92-184 Excel lent Excel lent Epoxy /polyester hybrid 25-250 ym 232'C-3 min 163*C- 25 mln Poor HB-2H 92-184 Excellent Very good T6IC polyester 25-250 |im 204 'C-7 mln 154*C-20 mln Excellent HB-2H 92-184 Excellent Good Polyester urethane 25-89 vim 204*C-7 mln 177*C-17 mln Very good HB-3H 92-184 Excellent Good Acrylic urethane 25-89 )im 204*C-7 mln 182*C-25 mln Very good H-3H 23-69 Excellent Very good ^Thickness of up to 3,800 urn can be applied via multiple coats In a fluldlzed bed. Time and temperature can be reduced, by utilizing accelerated curing mechanisms, while maintaining the same general properties. cTested at a coating thickness of 51 ym. ------- TABLE Ib. TYPICAL PROPERITES OF THERMOSETTING POWDER COATINGS6 (English Units) Properties Application thickness Cure cycle (natal temperatures)'* Outdoor weatherabl 1 Ity Pencil hardness Direct Impact resistance, ln-lbc Adhesion Chemical resistance Epoxy 1-20 alls8 450*F-3 aln 250*F-30 m\n Poor HB-5H 80-160 | Excellent Excellent, E poxy /polyester hybrid 1-10 alls 450'F-3 aln 325 *F- 25 ain Poor HB-2H 60-160 Excellent Very good T6IC polyester 1-10 alls 400'F-7 Bin 310*F-20 aln Excellent HB-2H 80-160 Excel lent Good Polyester urethane 1-3.5 mils 400*F-7 «ln 350*F-17 aln Very good HB-3H 80-160 Eiccellent Good Acrylic urethane 1-3.5 alls 400* F-7 ain 360*F-25 aln Very good H-3H 20-60 Excel lent Very good "Thickness of up to 150 alls can be applied via aultlple coats In a fluldlzed bed. "Time and temperature can be reduced, by utilizing accelerated curing mechanisms, while maintaining the same general properties. Tested at a coating thickness of 2.0 nil. ------- powders, a potential replacement for porcelain, are presently available 1n a limited range of colors and are relatively expensive to manufacture. Continued development 1s expected to make these coatings more competitive. Polyv1nyl1dene fluoride coatings have recently become available 1n powder form.8 These fluoropolymer powder coatings have been available in Europe for about 2 years and are now sold 1n the United States. Because of their high resistance to weathering, Industrial pollution, and corrosion, they are used for exterior aluminum extrusions and panels for architectural purposes. Advancements 1n powder coating formulations are occurring at a rapid pace. Powders are being developed to compete with almost every market that has traditionally been held by liquid coatings. Architectural coatings (based on fluoropolymers), heat resistant coatings, metallic and textured coatings, low-temperature-cure powders, transparent and clear powders, and powders that can be used to color plastic parts by Introducing the powder Into the mold used for compression-molded plastic are 1n production use at this time. Most of these developments have occurred during the last 4 to 6 years and most powder coating manufacturers believe that the potential of powder coatings 1s only beginning to be realized. 10 ------- 4.0 POWDER COATING EQUIPMENT The process of applying powder coatings to the surface of a product 1s, In general terms, Identical to the traditional painting line used to apply liquid coatings. For powder coating or traditional painting, parts to be coated must first go through a pretreatment operation to ensure that the surface to be coated is clean and free of grease, dust, rust, etc. In many cases, the parts are also subjected to treatments such as pickling, phosphating, or chromatlzing to Improve the adhesion of the surface coating. After pretreatment, the parts enter the spray booth where the coating 1s applied with spray guns which are available in a wide variety of designs. When the coating has been applied, parts enter the curing oven to dry (in the case of traditional painting) and cure the coating. The following sections present information about the types of equipment that are available for each step in the process outlined above. There are numerous manufacturers of powder coating equipment competing in today's market, and each has various products that are capable of performing the same basic task. The discussions presented here will be generic, in that manufacturers' brand names will not be used, and will focus on the spray application of powder to a metal substrate. (The curing ovens used with powder coating systems are similar to those used for liquid coating lines, and therefore, are not discussed here.) 4.1 PRETREATMENT Although the substrate pretreatment process is critical to achieving an acceptable powder coated product, it is not a requirement that ts unique to powders. All industrial surface coatings require a substrate that 1s clean and dry. There 1s a wide range of pretreatment requirements for powder coating as well as for liquid coating. The pretreatment process steps required are a function of the characteristics of the coating and the substrate and the end use of the product being coated. The pretreatment process is normally carried out in a series of dip tanks containing degreasing solvents, alkali cleaners, and rinses. Parts that are not easily dipped because of their size or shape may be cleaned with pressurized and/or heated sprays. An additional step that is used in many powder coating lines is a phosphating application that adds to the 11 ------- corrosion protection provided by the coating system and improves the adhesion of the coating to the substrate. When the parts have passed through all of the pretreatment steps, they are normally dried in a low temperature dry-off oven. After drying, the parts are ready to be sprayed with the powder coatings. 4.2 POWDER APPLICATION The powder coating application process makes use of four basic types of equipment: the powder delivery system, the electrostatic spray gun system, the spray booth and overspray exhaust air system, and the powder recovery system. 4.2.1 Powder Delivery System Powder 1s -supplied to the spray gun by the powder delivery system. This system consists of a powder storage container or feed hopper, a pumping device that transports a stream of powder into hoses or feed tubes. A compressed air supply is often used as a "pump" because 1t aids 1n separating the powder into individual particles .for easier transport. The powder delivery system is usually capable of supplying powder to one or several guns, often many feet from the powder supply. Delivery systems are available in many different sizes depending on the application, number of guns to be supplied, and volume of powder to be sprayed in a given time period. Recent improvements in powder delivery systems, coupled with better powder chemistries that reduce clumping of the powder, have made possible the delivery of a very consistent flow of particles to the spray gun. Agitating or fluidizing the powder in the feed hopper also helps prevent clogging or clumping of the powder prior to its entry into the transport lines. 4.2.2 Electrostatic Spray Guns Electrostatic powder spray guns function to shape and direct the flow of powder; control the pattern size, shape and density of the powder as it is released from the gun; Impart the electrostatic charge to the powder being sprayed; and control the deposition rate and location of powder on the target. All spray guns can be classified as either manual (hand-held) or automatic (mounted on a mechanical control arm). Both manual and automatic guns are manufactured by many different companies, with about 8 to 10 of these companies supplying the majority of these guns. Although 12 ------- the basic principles of operation of most guns are the same, there 1s an almost limitless variety 1n the style, size, and shape of spray guns. The type of gun chosen for a given coating line can, thus, be matched to the performance characteristics needed for the products being coated. Traditionally, the electrostatic charge was Imparted to the powder particles by a charging electrode located at the front of the spray gun. These "corona charging" guns generate a high-voltage, low-amperage electrostatic field between the electrode and the product being coated. The charge on the electrode 1s usually negative and can be controlled by the operator. Powder particles', passing through the Ionized electrostatic field at the tip of the electrode become charged and are thus directed by the electrostatic field. The particles follow the field lines and air currents to the target workpiece and are deposited on the grounded surface of the workpiece. One drawback to the use of this type of gun Is the difficulty of coating Irregularly shaped parts that have recessed areas or cavities (that may be affected by Faraday cages) Into which the electrostatic field cannot reach. Because the powder particles are directed by the presence of the field, Insufficient powder may be deposited on surfaces outside the reach of the field. A relatively recent Innovation 1n electrostatic spray guns 1s the "trlbo" electric gun. The powder particles 1n a tribo electric gun receive an electrostatic charge as a result of friction which occurs when powder particles contact a solid insulator or conductor inside the delivery hose and gun. The resulting charge 1s accomplished through the exchange of Ions, or electrons, between the powder and the material used for construction of the supply hose and gun barrel. Because there is no actual electrostatic field, the charged particles of powder migrate toward the grounded workpiece and are free to deposit 1n an even layer over the entire surface of the workpiece. With the elimination of an electrostatic field, the Farraday cage effect can be prevented. Other improvements that have been made to spray guns involve variations in the spray patterns to improve the coating transfer efficiency. Nozzles that resist clogging have been introduced. Spray guns with variable spray patterns are also available to allow the use of one gun on multiple parts of different configurations." Innovations in 13 ------- spray gun design have resulted 1n versatile and efficient guns with Increased ease of operation. Manual coating 1s characterized by simple operation of both the equipment and controls. After a short period of training, personnel are capable of meeting the requirements for quality and uniformity of coating. 4.2.3 Powder Spray Booths The primary function of the powder spray booth 1s to contain the spraying operation so that oversprayed powder cannot migrate Into other work station areas. Several criteria must be met in selecting the appropriate spray booth for a given coating line. The entrance and exit openings must be properly sized to allow clearance of the largest product part. The airflows through the booth must be sufficient to channel all overspray to the collection device, but not so forceful that it disrupts the powder deposition and retention on the part. If one booth 1s to be used for multiple colors, the booth interior should be free of narrow crevices, seams, and Irregular surfaces that would be difficult to clean. This 1s especially Important 1f collected overspray 1s to be recycled. Airflow rates for powder spray booths are considerably lower than those for booths used for spraying solvent-based paint. The OSHA requires a minimum of 2.8 m3/m1n (100 ft3/m1n) of air movement through the booth in a system using solvent paint. During the cooler months, an air makeup differential of 8° to 14°C (15° to 25°F) is required to replace solvent-laden air that is exhausted through the booth. With powder 9 coating, there is no makeup requirement for spray booth air movement. Also, because there is no solvent loading of the air exhausted from a powder coating booth, the air can be recirculated within the plant. 4.2.4 Powder Recovery and Recycle System In most manufacturers' designs, the powder recovery and recycle systems are an integral part of the spray booth. The fact that oversprayed powders can be collected and reused has led equipment manufacturers to develop systems designed especially to accommodate powder recovery. Traditional spray booths for liquid coatings have either dry or wet filter systems to remove overspray from the exhaust air stream. The collected paint is of no value and 1s therefore discarded. In this situation, color changes are accomplished b'y simply changing the spray gun 14 ------- from one paint delivery system to one filled with the next color to be applied. The resulting collected overspray 1s a combination of all the colors applied between filter replacements or booth cleanings. For collected oversprayed powder to be of greatest value, It should be free of cross-contamination between colors. When a pellet of the wrong color adheres to the part being powder coated, 1t will not blend in with the color being used. There are numerous systems now available that are designed to accomplish this segregation of colors and still allow several colors to be applied 1n the same booth. Most of these systems make use of a moveable dry filter panel or a cartridge filter that can be dedicated to one color and can be removed easily when another color Is needed. Color changes can then be accomplished by disconnecting the powder delivery system and purging the lines, cleaning the booth with compressed air or a rubber squeegee, exchanging the filter used for the previous color with the filter for the next color, and connecting the powder delivery system for the new color. Equipment manufacturers have made significant design Improvements 1n spray booths that allow color changes to be made with a minimal downtime and allow the recovery of a high percentage of the overspray. As with spray guns, there are a large number of spray booth and powder recovery designs from which to choose, depending on the exact requirements of a given finishing system. 15 ------- 5.0 END USES OF POWDER COATINGS As can be seen 1n Tables 2 through 4, the 11st of products that are being coated with powder coatings 1s extensive. There are certain market sectors where powder coatings have shown particularly strong growth rates. For example, powder coatings are being used extensively to produce linings on the Inside of oil drilling pipe where severe pressures, high temperatures, and corrosive materials allow only a few types of coatings to be effective. The automotive Industry 1s Increasing Its use of powder coatings for economic, quality, and ecological reasons. Powder 1s being used for the exterior body Intermediate coat known as a "primer-surfacer", as well as for finishing of underhood components. Parts that require extra protection as well as a decorative finish are Increasingly being powder coated. Wheels, bumpers, shock absorbers, mirror frames, oil filters, engine blocks, battery trays and coll springs are some of the many automotive products being powder coated. Clear powder coatings, as an alternative to solvent-borne clear coats, for use over automotive exterior basecoats, are being evaluated.. The appliance Industry 1s the largest single market sector for thermosettlng powders accounting for about 30 percent of powder sales.12 As porcelain-replacement powders become further developed, the appliance market will continue to grow. Current uses Include range housings, freezer cabinets, dryer drums, and washer tops and Hds. Outdoor furniture, farm Implements, and lawn and garden equipment are also major markets for powder coatings. The general metal finishing Industry accounts for over 40 percent of thermoset powder sales.12 (The general metal finishing Industry 1s defined here as Including all metal finishing Industries except for the automotive, appliance, and architectural finishing Industries.) Potential large market areas for powders are the aluminum extrusion and architectural products markets. The recent advances 1n polyester-TGIC and fluoropolymer powders have enabled powder coatings to compete with liquid architectural coatings 1n durability, weatherablHty, and resistance to fading. Some of these coatings have been 1n use In Europe since 1976 and are now being Introduced Into this country. IS ------- TABLE 2. END USES FOR EPCXY AND HYBRID POWDER COATINGS 10 Hardware and consumer goods Bunk beds Kitchen blenders Kitchen mixers Crock pots Desk lamps Pens Vacuum cleaners Speaker frames Barbecue gri11s Microphones Glass containers Thumb tacks Water heaters Faucets .Tape player doors Space heaters Can openers Gas meters Curtain hardware Floor polishers Cigarette Iighters Mine racks Closet hardware Chair frames and bases Safe deposit boxes Archery bows Steel toys Wire baskets Bed frames Fishing reels Book ends Waste baskets Christmas tree stands Notebook spiral wires Lawn and garden edgers/tools Luggage frames Desk accessories EIectronIc/eIectr i caI Electrical motor stators Electric motor rotors Switch boxes Electric boxes Thresholds Transformers Electric meters Electric connectors Electronic instrument housing Electronic instrument cabinets Computer room floor systems Automot i ve Steering wheels Air conditioning components Interior trim parts Engine blocks Oil filters Shock absorbers Motor windings Motor housings Motor mounts Coil springs Valve covers Brake shoe frames Intake manifolds Truck light housings Truck seat frames Seat bases Seat belt latches Seat belt mounts Auto jacks Jack stands Functional and specified Internal and external pipe Gas riser pipe Reinforcing bar for concrete Cable for prestressed concrete Rebar saddles Structural steel Conduit Military projectiles Military tent hardware General industrial Medical furniture Steel carts Power tools Office furniture Two-wheel hand trucks Computer frames/cabinet Copier cabinets Storage cabinets Reta iI store racks Retail store shelving Refrigerator shelving Air cleaners Lighting fixtures Folding furniture Water pumps Steel drums Scaffolding Fertilizer spreaders Wire cloth/screen Industrial mixers Alarm system bells Propane tanks Thickness gauges Grain storage systems FiI ing cabinets Lab cabinets/furniture Drawer suspension units Warehouse rack systems Lug wrenches Tool boxes and chests Air compressors Camp stoves Polished hardware Refrigerator liners Hand tools Grapevine support poles Pressure reserve tanks Friction disc binders Electrostatic spray equipment Office partitions Escalator steps 17 ------- TABLE 3. END USES FOR TGIC-POLYESTERS AND ALIPHATIC POLYESTER-URETHANE POWDER COATINGS1 Hardware consumer goods Automotive General Industrial Barbecue grills Mailboxes Screen doors Ice machines Water cans Snowblowers Antennas Microwave ovens YardHghts A1r conditioner cabinets Flash bulbs Shower curtain hardware Recreational vehicle hardware Playground equipment garden tillers Gas cans Battery cases Screen Wagons Luggage frames Pool hardware Laundry appliances Chain saws Wheels Automotive trim Truck tool boxes Instrument bulbs Windshield wipers Bumpers Roll bars Mirror brackets Outdoor patio furniture Lawn mowers Tractors Motorcycle frames Bicycle frames Highway signs Fence wire and poles Extruded aluminum doors Extruded aluminum windows Guardral1 Golf carts Building facade panels Satellite dishes Marine motors and drives Vending machines Roofing tile Irrigation pipe Refrigerator skins Propane tanks Water tanks F1re extinguishers Light poles Electric boxes Transformers Junction boxes Gas pumps Sonar equipment Parking meters 18 ------- TABLE 4. END USES FOR AROMATIC URETHANE AND ACRYLIC POWDER COATINGS11 Aromatic urethanes Acrylics Interior metal furniture Wheels Industrial racking systems Ranges Primers for light poles Garden equipment Residential aluminum window and door frames Clothes dryers Low cost outdoor furniture Automotive topcoat Store front window and door frames Office equipment 19 ------- The Powder Coating Institute estimates that powder coating use 1n North America will grow from about 57xl06 kg (125xl06 1b) 1n 1989 to about 102xl06 kg (225xlOs Ib) 1n 1993. During this period, the projected annual growth rate for selected market areas 1s; automotive—19 percent, appliance—12 percent, architectural—40 percent, and general metal finishing—21 percent.12 20 ------- 6.0 ECONOMIC ADVANTAGES OF POWDER COATINGS VS. LIQUID COATINGS When comparing powder coating systems with liquid coating systems, several significant advantages are readily apparent. There are also other, seemingly less significant advantages that, when viewed collectively, contribute substantial cost savings. This section discusses the economic advantages of powder vs. liquid coating systems in the following areas: energy savings, labor savings, greater operating efficiencies, and environmental benefits. A detailed cost comparison of powder vs. liquid coating systems also is provided at the end of this section. 6.1 ENERGY SAVINGS There are two significant advantages of powder coating which contribute to lower energy costs as compared to liquid coating. The first advantage is that the air used to exhaust the powder spray booth can be redrculated directly to the plant since the powder does not contain volatile compounds at room temperature. This eliminates the cost of heating or cooling the makeup air that occurs when air is exhausted from the plant, a particular advantage where extreme weather conditions are prevalent. The second advantage 1s the lower cost of heating the curing oven. Ovens that cure solvent-based coatings must heat and exhaust huge volumes of air to Insure that the solvent fumes do not approach the lower explosive limit. Because powder coatings have no solvent content, the airflow 1n the curing ovens is considerably lower. 6.2 LABOR SAVINGS The required operator skills and training for operation of a powder coating system are less than those needed for a liquid system and considerably less than those required for an electrocoat system. In addition, powder 1s "ready to use" when purchased and does not require labor for mixing with solvents or catalysts as is necessary with liquid coatings. Also, there are no critical operating parameters to monitor such as viscosity and pH (which are monitored in many liquid coating systems) or percent solIds, specific resistance, and binder to pigment ratio, (which all must be monitored in electrocoatlng systems). 21 ------- 6.3 GREATER OPERATING EFFICIENCY Because no drying or flash-off time 1s required, and the powder application system allows parts to be racked closer together on a conveyor, more parts can pass through the production line resulting In greater operating efficiency and lower unit costs. Despite the greater line speeds, powder coating systems generally have significantly lower reject rates than do liquid coating systems. One reason for this lower reject rate 1s that 1t 1s virtually impossible to have drips, runs, or sags when applying powder coatings. In addition, 1f a powder-coated part is found to be Improperly sprayed (prior to curing) the powder coating can •be blown off with an air gun and the bare part recoated. Another factor which contributes to a greater operating efficiency 1s the fact that oversprayed powder can be reclaimed and thus, reused. 6.4 ENVIRONMENTAL BENEFITS As regulatory agencies further limit the amount of solvent that can be emitted, many plants that use liquid coating systems are finding it necessary to purchase VOC control equipment, such as afterburners, to incinerate the emitted solvents. Another environmental problem faced by liquid coating users is the Increased difficulty and cost of disposing of hazardous waste generated by liquid coating operations. With a dry powder coating system, there 1s no liquid paint sludge to send to a disposal site. 6.5 COST COMPARISON: POWDER VS. LIQUIDS A detailed cost comparison between powder and liquid coating systems is provided below. The three types of liquid coating systems included in the comparison are: conventional solvent, water-borne, and high sol Ids. Total capital and annual operating costs are provided for each of the four coating systems. Material costs represent two-thirds or more of the total annual.operating costs, and therefore, detailed material costs are also provided. 6.5.1 Total Capital Costs Capital costs for four different coating systems (I.e., conventional solvent, water-borne, higher solids, and powder) are presented in Table 5. The two sources of these costs are a reprint from Products Finishing entitled "Powder Coating Today" (1987), and an earlier 22 ------- TABLE 5. TOTAL CAPITAL COSTS Type of coating Equipment (Ref.) installed cost, $ Conventional solvent Water-borne Higher-solids Powder Two water-wash booths (13) 150,000 One dry filter booth (14) Four automatic guns Two manual guns Two reciprocators Paint heating equipment Solvent recovery or incineration equipment Two waterwash booths (13) 110,000 One dry filter booth (14) 108,000 Four automatic electrostatic guns Two reciprocators Safety interlocks and stand-offs Two waterwash booths ' (13) 110,000 One dry filter sooth (14) 110,000 Four automatic electrostatic guns Two manual electrostatic guns Paint heating equipment Two powder spray booths (13) 120,000 Four automatic electrostatic guns (14) 190,000 One manual electrostatic gun Two reciprocators or gun movers Two powder recovery systems with automatic recycle 23 ------- publication entitled "VOC Emission Reductions and Other Benefits Achieved by Major Powder Coating Operations" (1984).13»l" Both of these sources contain Information generated by the Powder Coating Institute. The "Powder Coating Today" article 1s actually an updated version of the 1984 publication. Cost estimates cited 1n these two sources were used because they are consistent with cost estimates provided by powder coating equipment suppliers 1n response to questionnaires submitted by the Agency. The capital costs from each literature source are similar with one notable exception—the cost of the same powder coating equipment purchased 1n 1983 ($150,000) has decreased to $120,000 by 1986. (Note: costs listed 1n the two references are based on the year prior to the publication year.) In addition, the "Powder Coating'Today" article Included the cost of solvent recovery or Incineration equipment 1n the total capital cost for the conventional solvent coating system. These costs were considered reasonable based on EPA experience with paint application and control equipment. No costs were provided 1n the earlier reference for a conventional solvent coating system. The capital costs presented 1n Table 5 are based on the following assumptions: 1. The parts to be coated are formed sheet steel parts that are of average complexity; 2. Both sides of each part are automatically coated and touched up manually; 3. Two colors are used; 4. l.lxlO6 m2 (12xl06 ft2) of parts are surface coated per year; 5. Conveyor speed 1s 4.6 m/m1n (15 ft/m1n); 6. The Installation 1s new and has automatic equipment to more efficiently apply either a conventional solvent, water-borne, high solids, or powder coating; 7. A solvent recovery system or Incinerator (cost: $40,000) 1s Included 1n the system applying conventional solvent coatings to satisfy emission regulations; and 8. The same pretreatment systems and ovens can be used with each system with little or no modification. 24 ------- 6.5.2 Material Costs Materials costs for the four coating systems are presented In Tables 6a and 6b; these costs are based on six different sources of Information. Each source calculated the material costs 1n a similar manner with the higher solIds system generally having a lower material cost. Cost Information that was obtained from the powder coating surveys supported the cost Information that was found 1n the literature and presented 1n Tables 6a, 6b, 7a, and 7b. The most complete and up-to-date source of cost Information 1s the "Powder Coating Today" article (Reference Nos. 16 and 21 1n Tables 6a, 5b, 7a, and 7b). Costs obtained from other sources were Included in Tables 6a, 6b, 7a, and 7b for comparison purposes. (Note that in Table 6a and 6b, the columns for powder costs are 1n terms of kg (Ib) rather than i (gal). The material costs presented in Reference Nos. 16 and 21 are based on 1986 data and the following assumptions: 1. The conventional solvent coating 1s a 38 percent (by volume) solIds acrylic or alkyd baking enamel applied at an average thickness of 30 um (1.2 mils); 2. The water-borne coating is a 35 percent (by volume) solids acrylic latex applied at an average thickness of 30 um (1.2 mils); 3. The higher solids coating is a high-performance acrylic or polyester-type coating applied at an average thickness of 30 um (1.2 mils); and .4. The powder coating is a high-quality polyester-urethane type applied an average thickness of 30 um (1.2 mils). 6.5.3 Total Annual Operating Costs The total annual operating costs for the, four coating systems are presented in Tables 7a and 7b. These costs are based on five different sources of Information (note that reference No. 18 in Table 7 did not provide operating costs). Operating costs were not provided by those companies that responded to the powder coating surveys, and therefore, it was not possible to make a comparison between actual plant-specific operating costs and those operating costs supplied in the literature. All literature references and survey respondent information used to create Tables 7a and 7b identified powder coating as having the lowest 25 ------- TABLE 6a. MATERIAL COSTS, DOLLARS (Metric Units) Item Coating cost, $/4 Volume solids, percent Reducing agent cost, S/l Mix ratio (coating: reducing agent) Mixed coating costs, S/l Volume solids at spray v i scos i ty , percent Specific gravity • Theoretical coverage m /Z/wm (Ref.) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) Conventional solvent __ 2.70 3.15 2.30 — 3.15 __ 38 47 43 ~ 47 •»_ 0.40 ~ 0.40 — 0.40 _ 4:1 3:1 5:2 — 3:1 __ 2.26 2.48 1.77 2.38 2.48 __ 30.5 35 31 35 35 __ — — ~ — -- 305 350 310 — Water-borne — 2.90 2.90 « — 2.90 • — 35 35 ~ — 35 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A _ 2.90 2.90 — ~ 2.90 __ 35 35 — — 35 __ ~ — — — ~ 350 350 — — Higher sol ids 5.55 3.90 4.50 — — 4.50 __ 63 63 ~ — 63 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 5.55 3.90 4.50 — 3.70 4.50 54 63 63 — 55 63 __ — — ~ — — 540 630 630 — — - Powder3 5.30 4.65 5.10 4.75 4.75 5.10 -_ 98 98 98 100 100 N/A N/A N/A N/A N/A N/A. N/A N/A N/A N/A N/A N/A 5.30 4.65 5.10 -— — 5.10 98 98 98 98 100 100 __ .6 .6 .6 .5 .6 614 624 614 614 — Substitute kg for i in all calculations (continued) 26 ------- TABLE 6a. (continued) Item Dry filoi thickness, ]im° Transfer efficiency, percent0 a Actual coverage, ar/J. Appl led cost, S/m2 Annual cost to coat l.lxlO6 m2. S (Ref.) (15) (16) . (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) Conventional solvent — 30 30 30 30 30 50 60 40 50 60 •* 5.00 6.86 4.07 5.71 6.86 ^^ 0.4510 0.3606 0.4338 0.4155 0.3606 502,800 402,000 483,600 463.200 402,000 Water-borne — 30 30 — — 30 55 60 ~ — 60 __ 6.30 6.86 — _ 6.86 „ _ 0.4607 0.4220 — ~ 0.4220 513.600 470,400 320,400 — 470,400 Higher solids 30 30 30 — 30 30 80 60 70 — 80 70 14.1 12.4 14.5 ~ 14.4 14.4 0.3918 0.3154 0.3100 — 0.2562 0.3111 436,800 351.600 345,600 310,800 285,600 346,800 Powdera 30 30 30 30 30 30 95 96 97 97 98 97 19.0 19.7 19.5 19.5 21.3 19.5 0.2777 0.2357 0.2605 0.2433 0.2228 0.2605 309,600 262,800 290,400 271,200 248,400 290,400 ^Substitute kg for I in all calculations. "Coating thicknesses Mere normalized to put costs on a common basis. cTransfer efficiency is the ratio of coating that adheres to the part and the coating that is sprayed through the gun. In the case of powder coating, where powder is recovered and recycled, the term "utilization efficiency" is used. The transfer efficiencies used by the sources for this table are somewhat high. This may cause the costs of the nonpowder alternatives presented here to appear lower than they '.'actual ly would be. 27 ------- TABLE 6a. (continued) Item Dry film thickness, UOID Transfer efficiency, percent Actual coverage, ar/i Applied cost, S/ffl2 Annual cost .to coat l.lxlO6 a2, $ (Ref.) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) Conventional solvent — 30 30 30 30 30 50 60 40 50 60 _ _ 5.00 6.86 4.07 5.71 6.86 __ 0.4510 0.3606 0.4338 0.4155 0.3606 502,600 402,000 483,600 463,200 402,000 Water-borne — 30 30 — — 30 55 60 — — 60 w— 6.30 6.86 -- — 6.86 — *» 0.4607 0.4220 — — 0.4220 513,600 470,400 320,400 •— ' 470,400 Higher solids 30 30 30 — 30 30 80 60 70 — 80 70 14.1 12.4 14.5 — 14.4 14.4 0.3918 0.3154 0.3100 — 0.2562 0.3111 436,800 351,600 345,600 310,800 285,600 346,800 Powder8 30 30 30 30 30 30 95 96 97 97 98 97 19.0 19.7 19.5 19.5 21.3 19.5 0.2777 0.2357 0.2605 0.2433 0.2228 0.2605 309,600 262.800 290,400 271,200 248,400 290,400 "Substitute kg for jt in all calculations. Coating thicknesses were normalized to put costs on a common basis. cTransfer efficiency is the ratio of coating that adheres to the part and the coating that is sprayed through the gun. In the case of powder .coating, where powder is recovered and recycled, the term "utilization efficiency" is used. The transfer efficiencies used by the sources for this table are somewhat high. This may cause the costs of the nonpowder alternatives presented here to appear lower than they actually would be. Traditionally, high transfer efficiency has been of importance to a coating facility for several reasons. The value added to most products by the coating is small and the cost of the coating is usually almost negligible in comparison to labor and equipment costs. One major automobile manufacturer represented its transfer efficiency at almost twice the 30 percent that was subsequently determined by tests. Modern reciprocating systems and highly robotic!zed systems can operate poorly, as tests of state of the art equipment demonstrated in the nid-1980's. A new auto assembly line with reciprocators was found to be operating at 15 percent transfer efficiency and a second plant with a state of the art coating line was found to achieve less than 20 percent. In fact, the EPA authority on transfer efficiency has been quoted "never underestimate people's inability to recognize how low their transfer efficiency really is." 27 ------- TABLE 6b. MATERIAL COSTS, DOLLARS (English Units) (ten Coating cost, S/gal Volume solids, percent Reducing agent cost, S/gal Mix ratio (coating: reducing agent) Mixed coating costs, S/gal Volume solids at spray viscosity, percent Specific gravity Theoretical coverage ftVgal/mil (Ref.) C5) (16) (14) (17) (18) (19) (15) C6) (14) (17) (18) (19) ('5) (16) (14) (17) (18) (19) (13) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) Conventional solvent — 10.30 12.00 8.75 — 12.00 __ 38 47 43 — 47 „ 1.50 ~ 1.55 — 1.50 __ 4:1 3:1 5:2 — 3:1 « 8.54 9.38 6.69 9.00 9.38 __ 30.5 35 31 35 35 ... __ — — — — ~ 489 561 497 ~ Water-borne — 11.00 11.00 — — 11.00 __ 35 35 __ — 35 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A __ 11.00 11.00 — -- 11.00 __ 35 35 — « 35 «. — — — — — 561 561 — . Higher sol ids 21.00 14.80 17.00 — • 17.00 ^— 63 63 — — 63 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 21.00 14.80 17.00 ~ 14.00 17.00 54 63 63 -. 55 63 __ — — — — — - 866 1,010 1,011 — — Powder3 2.40 2.10 2.30 2.15 2.15 2.30 __ 98 98 98 100 100 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 2.40 2.10 2.30 — -- 2.30 98 98 98 98 100 100 __ 1.6 1.6 1.6 1.5 1.6 118 120 118 118 — 'Substitute pounds for gallons in all calculations (continued) 28 ------- TABLE 6b. (continued) Item Dry filn thickness, mils0 Conventional (Ref.) solvent (15) — (16) .2 (14) .2 (17) .2 (18) .2 (19) .2 Water-borne 1.2 1.2 1.2 Higher solids Powder8 1.2 .2 1.2 .2 1.2 .2 „„ 2 1 .2 '.2 1.2 .2 Transfer efficiency, percent0 • Actual coverage, ft^/gal Applied cost, J/ft2 Annual cost-to coat 12x10° ft2, S (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) (15) (16) (14) (17) (18) (19) 50 60 40 50 60 __ 204 280 166 233 280 __ 0.0419 0.0335 0.0403 0.0386 0.0335 __ 502,800 402,000 483,600 463,200 402,000 55 60 — — 60 __ 257 280 — — 280 _» 0.0428 0.0392 — ~ 0.0392 __ 513,600 470,400 320,400 — 470,400 80 60 70 ~ 80 70 577 505 590 ~ 588 588 0.0364 0.0293 0.0288 ~ 0.0238 0.0289 436,800 351,600 345,600 310,800 285,600 346,800 95 96 97 97 98 97 93 96 95 95 104 95 0.0258 0.0219 0.0242 0.0226 0.0207 0.0242 309,600 262,800 . 290,400 271,200 248,400 290,400 ^Substitute pounds for gallons in all calculations. °Coating thicknesses were normalized to put costs on a common basis. cTransfer efficiency is the ratio of coating that adheres to the part and the coating that is sprayed through the gun. in the case of powder coating, where powder is recovered and .recycled, the term "utilization efficiency" is used. °The transfer efficiencies used by the sources for this table are somewhat high. This may cause the costs of the nonpowder alternatives presented here to appear lower than they actually would be. Traditionally, high transfer efficiency has been of Importance to a . coating facility for several reasons. The value added to most products by the coating is small and the cost of the coating is usually almost negligible in comparison to labor and equipment costs. One major automobile manufacturer represented its transfer efficiency at almost twice the 30 percent -hat was subsequently determined by tests. Modern reciprocating systems and highly robotic I zed systems can operate poorly, as tests of state of the art equipment demonstrated in the mid-1980's. A new auto assembly line with reciprocators was found to be operating at 15 percent transfer efficiency and a second plant with a state of the art coating line was found to achieve less than 20 percent. In fact, the EPA authority on transfer efficiency has been quoted "never underestimate people's inability to recognize how low their transfer efficiency really is." 29 ------- TABLE 7a. TOTAL ANNUAL OPERATING COSTS, DOLLARS* (Metric Units) Item Material, S/yr Labor and cleanup, S/yr Maintenance, S/yr Energy, S/yr S 1 udge d i sposa 1 , S/h F i 1 ter rep 1 acement , $/h Amortization. 10-vr straight 1 me, S Total annual cost, $b Applied cost, $/m2 (Ref.) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21 ) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) Conventional solvent __ 502,800 402)000 483,600 402,000 — _ 141,900 132,100 118)000 _ _ 121 ,300 ^^ 24,000 18,000 14,500 — •• 30,500 29 100 23)200 „_ 14,640 __ 48,758 10,800 13)480 11,280 «_ .— — — 2,500 3,000 15,000 _— — ~ . _^ 762,960 592,000 655)280 552,220 _ — 0.6846 0.5307 0.5877 0.4952 Water-borne ,, 513,600 470 400 320,400 470,400 —— 141,900 132,100 126)200 • ^ 121,300 ^^ 24,000 18,000 18,800 ~ .« 32,514 3l)lOO 22,600 _ _ 11 ..140 — ^ 40,750 10,800 _ 1 1 ,280 ^_ — » — — _. 3,000 11,000 10,800 9,800 — — — — — 763,760 673,200 497)800 __ 617,120 ^^ 0.6846 0.6039 0.4467 0.5533 High solids 436,800 351,600 345 600 310,800 « 346,800 111,440 141,900 - 128,400 126,200 __ 121,300 1 1 ,840 "• 24)000 18,000 18,800 ~ 39,460 28,300 27,100 19,700 __ 11,200 8,460 31,500 7,100 — • ~ 11,280 1,920 — — — — — — — 3.000 11,000 11,000 10,000 — " 609,920 588 300 537,200 485)500 — 493,580 0.5468 0.5274 0.4822 0.4349 0.4424 Powder 309,600 262,800 290 400 271,200 « 290,400 85,200 82,900 75,600 72)000 _« 74,540 5,060 16)000 10,000 9,000 — — 35,800 16,400 15 700 11,400 .» 7,420 N/A 700 1,100 l)000 — 1,080 N/A — — 500 — 840 12,000 15,000 1 5 ,000 — — — 435,660 391 400 407,800 380)100 — 374,280 0.3907 0.3509 0.3660 0.3412 0.3358 ^Assumed 2,000 operating hours per year Numbers have been rounded. 30 ------- TABLE 7b. TOTAL ANNUAL OPERATING COSTS, DOLLARSa (English Units) Iten Material, S/yr Labor and cleanup, S/yr Maintenance, S/yr Energy, $/yr Sludge disposal , S/h F i 1 ter rep 1 acemen t , S/h Amortization. 10-yr straight line, S Total annual cost, Jb Applied cost, S/ft2 (Ref.) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) (20) (21) (14) (17) (18) (19) Conventional solvent __ 502,800 402 000 483,600 _.. 402,000 __ 141,900 132,100 118)000 121,300 24,000 18,000 14,500 ~ _. 30,500 29)100 23)200 ^^ 14,640 __ 48,758 10,800 13)480 11,28*0 __ _ __ 2,500 3,000 ^^ 15,000 __ „_ — 762,960 592,000 655)280 552,220 ^m 0.0636 0.0493 0.0546 0.0460 Water-borne . » 513,600 470)400 320,400 ** 470,400 »» J.41,900 132,100 126)200 121,300 24,000 18,000 18,800 ~ __ 32,514 31)100 22,600 » » 11,140 _ 40,750 10)800 — — 11,280 _ — __ __ •HW 3,000 •w 11,000 10)800 9)800 __ — 763,760 673,200 497)800 617,120 ^^ 0.0636 0.0561 0.0415 » 0.0514 High solids 436,800 351,600 345)600 310,800 •• 346,800 111,440 141,900 128,400 126)200 __ 121,300 11,840 24)000 18,000 18,800 — - 39,460 28,300 27)100 19,700 _. 1 1 ,200 8,460 31,500 7,100 — — — — 11,280 1,920 — -— -— •• 3,000 — — 11,000 11,000 10,000 — — 609,920 588)300 537,200 485)500 — 493,580 0.0508 8.0490 .0448 0.0404 — • 0.0411 Powder 309,600 262,800 290)400 271 ,200 « 290,400 85 ,200 82,900 75,600 72)000 — 74,540 5,060 16)000 10,000 9,000 — — 35,800 16,400 15 700 11,400 » 7,420 N/A 700 1,100 1,000 — 1,080 N/A — — — 500 « . 840 — — 12.000 15,000 15,000 — -- 435,660 391 )400 407,800 380)100 — 374,280 0.0363 0.0326 0.0340 0.0317 « 0.0312 ^Assumed 2,000 operating nours per year. lumbers have been rounded. 31 ------- annual operating costs. The highest operating costs were associated with the conventional solvent or water-borne coating systems. Labor, cleanup, maintenance, energy, and waste disposal costs were lowest for the powder coating system, which contributed to overall lower annual operating costs. The "Powder Coating Today" article (Reference No. 21) again provided the most complete and up-to-date Information on annual operating costs. The operating costs presented 1n that brochure are based on 1986 data and the following assumptions: 1. Labor costs $12.00 per hour and supervision costs $15.20 per hour 2. Cost of electricity = $0.076 per kWh 3. Cost of natural gas = $162 per thousand m3 ($4.60 per thousand ft3), and 4. Removal of nonhazardous paint sludge was estimated to cost $255 per 208 i (55-gal) drum. As shown 1n Tables 7a and 7b, material costs represent about 2/3 or more of the total operating costs of a coating line. The material costs for any of the four coating systems could be less than those shown 1f either the volume sol Ids and/or transfer efficiency 1s Increased and/or the film thickness lowered. For example, 1f the transfer efficiency for the higher sol Ids case (Reference 16, Tables 6a and 6b) 1s Increased from 60 to 70 percent, the annual cost to coat (material cost) will drop from $351,600 to $301,400. The annual cost to coat - [(coating thickness) (mixed coating cost)(surface area coated per year)]+[(theoretical coverage)(utilization efficiency)]. Likewise, 1f the powder coating thickness in Reference 16 (Tables 6a and 6b) were decreased from 30 to 25 ym (1.2 to 1.0 mils), the material cost would drop from $262,800 to $219,000. It should be noted that, currently* the minimum consistent powder coating film thickness 1s in the range of 25 um (1 mil). If the product to be coated requires less film thickness, the cost of applying more powder than necessary should be considered when comparing powder coating costs to costs of alternative coatings. 32 ------- 7.0 CONCLUSIONS The use of powder coatings as functional and decorative Industrial finishes 1s Increasing at a dramatic rate. At an annual rate of nearly 20 percent, powder coating 1s the fastest-growing finishing technology on the market.1 (However, the Initial sales volumes of powder coatings were much lower than those of liquid coatings 1n the same time period. There- fore, a direct comparison of growth rates 1s misleading.) Significant Improvements 1n the powder coatings, the application systems, and the powder recovery systems have made powder one of the most cost-effective finishing systems available. In addition, because powder coatings contain no solvents and usually are applied 1n dry filter booths, air and water pollution problems are eliminated 1n well-operated facilities. Energy costs attributable to heating and ventilation are significantly reduced. The use of powder coatings as an alternative to liquid, solvent-based coatings results in a significant decrease in VOC emissions. Powder coatings can be characterized as the lowest VOC-content coating among the compliance options available to Industrial finishers. Tables 8a and 8b present a VOC reduction comparison of the four coating systems. The values in this table were based on the average of the values presented in Tables 6a and 6b. As shown in Tables 8a and 8b, VOC emissions for powder coating systems are substantially lower than those for the liquid coating alternatives. Emissions are 98.4 percent lower than those shown for conventional solvent coating systems, 98.1 percent lower than those shown for higher sol Ids coating systems, and 97.7 percent lower than for water- borne systems. Most of the drawbacks to the use of powders that existed a few years ago (see Section 2.0) have been eliminated. New resin systems allow powders to meet the coating specifications for almost any product. Thin films (from less than 25 urn [1 mil] to about 76 urn [3 mils!) in a very wide range of colors, glosses, and textures can be applied at powder utilization rates of 95 percent or higher.22 Many of these coatings can be cured at temperatures of 121°C to 177°C (250°F to 350°F) 1n 15 to 30 minutes. Powder manufacturers are continuing to work toward perfecting resin and curing agent designs that will allow lower cost 33 ------- OJ TABLE 8a. VOC REDUCTION COMPARISON3 (Metric Units) Volume solids at spray viscosity, percent13 Volume VOC content, percent0 d Actual coverage, in2/* (m2/kg for powder)b e VOC emissions, metric tons/yrf Conven- tional solvent 33 67 5.71 34.5 Mater- borne 35 16 6.66 23.6 Higher solids 60 40 14.0 28.1 Powder 99 1 19.7 0.54 A 6 2 ' "Assumed 1.1x10 m of parts coated per year. ^Average of values presented In Table 6a. ^Assumed density of solvent equals 882 g/i. ^Mater-borne coating VOC content assumed to be 25 percent of the nonsollds portion. fBased on transfer efficiencies presented 1n Table 6a. TControl device assumed for conventional solvent coatings with overall efficiency of about 70 percent (based on capture efficiency of about 75 percent and destruction efficiency of about 95 percent). All other systems assumed to have no control device. ------- CO 01 TABLE 8b. VOC REDUCTION COMPARISON3 (English Units) Volume solids at spray viscosity, percent*1 Volume VOC content, percent0 d Actual coverage, ft2/g*1 (ft2/lb for powder)b e VOC emissions, tons/yrf Conven- tional solvent 33 67 233 38 Water- borne 35 16 272 26 Higher solids 60 40 570 31 Powder 99 1 96 0.6 ^Assumed 12x10 ft of parts coated per year. ^Average of values presented In Table 6b. ^Assumed density of solvent equals 7.36 Ib/gal. ^Water-borne coating VOC content assumed to be 25 percent of the nonsollds portion. *Based on transfer efficiencies presented 1n Table 6b. 'Control device assumed for conventional solvent coatings with overall efficiency of about 70 percent (based on capture efficiency of about 75 percent and destruction efficiency of about 95 percent). All other systems assumed to have no control device. ------- coatings and low-temperature cure coatings. Significant advancements are also being made In the weatherabllity of powders for use in automotive and architectural applications. Clear powder coatings are used for a wide range of applications 1n a number of markets, Including the automotive industry. Clear polyester and acrylic powders are being used to finish wheels, and resin systems are available in powder coating technology that provide the exterior durability properties required of an automotive exterior body topcoat. Recent and ongoing developments in the equipment used for powder application have significantly reduced the time and effort required for color changes. Properly designed powder systems can change colors in minutes. Currently, high-production powder systems apply more than 20 different colors, with several color changes per day.23- Coil coating technology for powder is being developed. (Coil coating is the coating of flat metal sheet or strip that comes 1n rolls or colls. The metal is coated on one or both sides on a continuous production line basis.) Vertical coating booths are enabling powder to compete more effectively in the aluminum extrusion finishing market. Advances in microprocessors, robotics, and Infrared curing technology are allowing Increased production 1n powder coating facilities. All of these advances, plus the Inherent advantages of working with powder ensure that powder coatings will have a permanent and ever-increasing share of the finishing market. 36 ------- 8.0 REFERENCES 1. Bocchl, 6. J. Powder Coatings: A World Market Overview. In: Conference Proceedings, Powder Coatings '88. Sponsored by the Powder Coating Institute. November 1-3, 1988. p. 1-3. 2. User's Guide to Powder Coating, II Ed. Dearborn, Michigan, Society of Manufacturing Engineers. 1987. p. 151. 3. Miller, E. P. and Taft, 0. 0. Fundamentals of Powder Coating. Dearborn, Michigan. Society of Manufacturing Engineers. 1974. p. 13. 4. Reference 1, p. 1-16. 5. Reference 2, p. 12. 6. The Powder Coating Institute Technical Brief No. 1. January 1986. 7. Electrostatic Powder Coating. Dow Chemical Europe. Undated brochure, p. 7. 8. Sigma Coatings, The Specialist 1n Exterior Paint Systems, Introduces Sigma PVOF, a New Generation of Powder Coatings. Sigma Coatings, Industrial Coatings Division, NL-3700 AC Zelst. Undated brochure. 9. Montenaro, 0. Economics of Powder Coating. In: Conference Proceedings, Powder Coating '88. Sponsored by The Powder Coating Institute. November 1-3, 1988. p. 9-7. * 10. G111, 0. E. Powder Coatings and Their Uses. Metal Finishing. August 1988. p. 41. 11. Reference 10, p. 42. 12. Reference 1, p. 1-17. 13. Bocchl, G. J. Powder Coating Today. Reprint from Products Finishing. 1987. p. 4. 14. Cole, G., Jr. VOC Emission Reductions and Other Benefits Achieved by Major Powder Coating Operations. The Powder Coating Institute, Greenwich, Connecticut. (Presented at the A1r Pollution Control Association Meeting. San Francisco. June 24-29, 1984). p. 13. 15. Reference 2, p. 25. 16. Reference 13, p. 5. 17. Armstrong Powder Coatings. Cost Comparison Worksheet. Armstrong Products Company. Undated brochure. 37 ------- 18. Why Powder Coat? A Practical Guide to Powder Coating. Volstatic, Inc., Florence, Kentucky. Undated brochure, p. 6. 19. Cost Analysis: Powder Coatings Versus Other Finishing Systems. GUdden Chemical Coatings. Undated literature, pp. 67-74. 20. Reference 2, pp. 27 and 28. 21. Reference 13, p. 7. 22. Reference 2, p. 3. 23. Reference 18, p. 1. 38 ------- APPENDIX A. SURVEY SUMMARY: POWDER COATING EQUIPMENT SUPPLIERS ------- APPENDIX A. SURVEY SUMMARY: POWDER COATING EQUIPMENT SUPPLIERS Three of the nine powder coating equipment suppliers surveyed responded to the survey. A brief summary of their responses is provided below. A list of the equipment suppliers who responded and a compilation of their individual responses are also attached. Types of equipment sold One of the responding companies only sells a portable powder coating unit equipped with either a manual or an automatic electrostatic spray gun. The other two respondents sell a wide range of powder coating application and recovery equipment for both electrostatic spraying and fluldlzed bed dipping. None of the three respondents sells curing ovens. Color chanqeovers The portable powder coating unit sold by one of the respondents can be color changed effectively by one operator in approximately 5 minutes. The other respondents noted that the color change time depends upon the size of the booth, the number of guns, and the type of powder collection equipment used. The color change times ranged from as little as 5 minutes for laboratory-size equipment to as long as 4 hours for a large, 10 gun unit using a filter cyclone for powder recovery. Transfer efficiencies The transfer efficiency provided by the portable powder application unit 1s estimated at 20 to 45 percent, depending on the technique and material applied. Manual spray systems may achieve transfer efficiencies of 60 to 75 percent depending upon the equipment and powder used. The respondents also cited the following factors that affect transfer efficiencies: (1) powder composition (i.e., resistivity, particle size, particle shape, moisture content, resin chemistry, flow properties), (2) efficiency of charging the powder with either internal or external electrodes, (3) shape and velocity of the atomized powder cloud exiting the discharge nozzle, (4).distance to the grounded workpiece, (5) shape, complexity, and "openness" of the parts to be coated, and (6) film thickness. In general "open" parts like large frames will have transfer efficiencies of 50 to 60 percent at a coating thickness of about 2 mils. Dense parts such as flat panels may have transfer efficiencies of 65 to 85 percent at the same coating thickness. Fluldlzed bed dipping achieves 100 percent transfer efficiency, but at higher film thicknesses and on a limited range of parts. Coating thickness Minimum coating thicknesses of about 0.6 to 0.8 mils and "typical" thicknesses of 1.2 to 2.5 mils were reported. Maximum thicknesses of 20 to 30 mils were also reported. One respondent noted that automatic application systems provide the most consistent thin films; he also noted that preheating parts greatly Increases the maximum achievable film thickness. A-l ------- New powder coating technology One respondent felt that recent equipment developments have not had a significant Impact on developing or expanding new markets, and that all of the new developments have been In the powder material technology. Another respondent noted that new fluorocarbon-based powders are expected to permit the expansion of powder coating Into the high-performance architect aluminum extrusion market, currently limited to two-coat liquid coatings. The development of equipment that allows faster color changes was also mentioned. Equipment costs The respondents provided costs for a wide range of equipment types and sizes. A portable powder system costs approximately $3,700, and laboratory models cost $14,500 and up. "Budget" prices for complete booth equipment, powder guns, and fire detection packages ranged from $55,000 to $141,000 depending on the size of the equipment. The powder applicators, delivery, and recovery equipment for an eight gun, 30 1n.x66 in. (wxh) automatic coating system may range from $90,000 to $125,000. Experience with powder coatings and Industries served The three respondents have been manufacturing and selling powder application equipment from 5 to 29 years, and have an average experience of 16 years. They service a wide variety of Industries, including metal furniture, lawn and garden tractors, automotive parts, light poles, lighting fixtures, and gas tanks, among many others. Powder versus liquid coating costs One respondent 1s not Involved 1n liquid coatings, and therefore, could not provide a cost comparison between the two coating methods. Another respondent does sell equipment to liquid coating users but did not have any comparative information available. The third respondent sells a limited amount of equipment to liquid coating users and felt that, in general, powder coating systems are comparable in capital investment to new liquid coating systems. 2 Attachments A-2 ------- Attachment 1 LIST OF RESPONDENTS: POWDER COATING EQUIPMENT VENDORS Mr. Frank A. Robinson, Jr. Director of Marketing The OeVllblss Company Post Office Box 913 Toledo, Ohio 43692-0913 (419) 470-2129 Mr. Donald -S. Tyler President Volstatic, Inc. 7960 Kentucky Drive Florence, Kentucky 41042 (606) 371-2557 Mr. William Diaz National Sales Manager Finishing Systems Services, Inc. 140 Joey Drive Elk Grove Village, Illinois 60007 (312) 640-0111 A-3 ------- Attachment 2 SURVEY RESPONSES: POWDER COATING EQUIPMENT SUPPLIERS 1. Company name and address; contact name, title, and telephone number. (See attachment). 2. List the types of equipment that you sell for each step in the powder coating process (powder storage and handling, substrate pretreatment, powder delivery, application, recovery, and powder curing). DeVUblss; DeVilblss sells a portable powder coating application unit that may be equipped with either an automatic or a manual electrostatic spray gun. Finishing Systems; The equipment that Finishing Systems Services, Inc. (FSSI) fabricates is marketed under the RECLAIM" trademark. The following equipment 1s manufactured by FSSI for the powder coating Industry: Powder handling and conditioning equipment • virgin powder drum unloader • powder sieving and conditioning equipment • powder transfer retrofit for existing cyclone equipment RECLAIM" powder application equipment complete manual spray gun outfits with supply hopper laboratory and QC station manual spray gun outfits manual spray gun outfits for mounting on the powder booth complete automatic/manual powder spray systems for retrofitting existing liquid spray lines or adding provisions for powder complete automatic/manual powder spray systems for new lines ultra-violet fire detection system for automatic powder lines custom design powder application equipment for special products electric and pneumatic automatic gun movers and reciprocators RECLAIM" brand powder recovery and recycling systems Cartridge filter design powder recovery booth models: laboratory and QC station cartridge powder collection booth for spraying small samples or testing various powders chain on edge conveyor type cartridge booths for coating small parts on rotating fixtures which travel through a slot at the bottom of the booth floor. Models with single color and roll- away color change collectors manual station single color format booths with airflow capacities of 3,000 to 6,000 ftVmin color change design manual and automatic powder booths with multiple spray stations. Standard and custom models with airflow capacities of 3,000 to 20,000 ft /min A-4 ------- • special design cartridge style booths with cyclones for multiple color capability within the same recovery system • custom design booths for special oversize products • custom powder management systems for fluid-bed dipping systems • custom design dust collection booths for nondecoratlve coatings, fire extinguisher chemicals, and rubber Industry Volstatic: Volstatic manufactures electrostatic powder coating application and recovery apparatus, Including: a. Manual spray application apparatus for production use b. Manual spray application apparatus for laboratory or field test use c. Automatic spray apparatus, single gun through multi-gun configurations, typically 2 to 12 guns per booth d. Electrostatic generators, single and multi-gun configurations e. Spray booths for manual application f. Spray booths for automatic application (or combination manual/ automatic configuration) g. Powder recovery and reclaim systems: cartridge type, cyclone separators, combinations h. Fluid beds 1. Ancillary equipment: powder transfer pumps, vibrating drum tables, de1on1z1ng generators/fans; powder clean-down apparatus Vol static occasionally sells powder curing equipment when supplied with other powder application equipment 3. Please provide Information on powder application and recovery equipment relative to color changeovers (typical time required for color changeover and maximum number of colors that can be applied per booth or system). DeVilbiss; Their powder system can be color changed effectively by one operator 1n approximately 5 minutes. Finishing Systems; Powder collection equipment 1s available in three • distinct formats: cartridge filter booth which FSSI specializes in, moving filter belt booth, and the conventional cyclone booth. The simplest and most efficient of these is the cartridge booth since all the recycled powder stays within the unit. This compact booth design has no moving parts other than the fan. The collector, the housing which has the dedicated color filters, is very easy to change. The filters within the collector are also easily changed when a low volume color which does not have a dedicated collector is to be recycled. The moving filter belt booth requires the changing of the belt for powder change and has extensive auxllHary equipment for screening and recycling the powder. The idea behind the cartridge design powder recovery booth is that each recycled color has a dedicated collector with filters for that specific color. If a powder user has a multitude of colors with no A-5 ------- appreciable volume In any of these various colors, a cartridge booth - 1s not the proper choice of equipment. MutHple color recovery requires a booth which uses an Inline cyclone to separate each color. Naturally, the efficiency of the cyclone will vary greatly, and anywhere from 5 to 25 percent of the recycled powder will bypass the cyclone into the final filter and thus, will not be recovered. Further scrap powder 1s generated when the cyclone, ductwork and collection hoppers on the cyclone system are not properly cleaned during the color change. The following are some general color change times for various types of equipment and airflow size in cubic feet per minute. Approximate time in minutes for color change by two operators Cartridge Filter Equipment model format filter belt Cyclone 1,500 ftj/min for lab or QC 5 to 10 NA 15 to 20 3,000 ft,/m1n (2) manual 10 to 20 30 to 60 30 to 60 4,500 ft,/min (2) man, (4) auto 20 to 30 45 to 90 60 to 120 9,000 ftVmin (2) manual 25 to 35 60 to 120 90 to 150 12,000 ftVmin (2) man, (8) auto 40 to 60 120 to 240 120 to 240 Vqlstatic; Powder color change time Is dependent primarily on the size of the booth and the number of guns. Typically, a steel- construction booth and a complement of eight guns may be cleaned in about 30 minutes. Volstatlc's new, patented ColorSPEEDER permits that operation to be completed in less than 5 minutes, including its reclaim system. Even faster changes may be achieved by duplicating the spray booths in a "roll on/roll off" configuration but this requires additional capital investment. Employing cyclone separators between the spray booth and final filter sections of the reclaim system permits unlimited numbers of colors to be applied without duplication of reclaim system sections, (e.g., filter modules) and they achieve quite high recovery efficiencies of usable powder overspray (e.g., 95 to 97 percent). 4. Describe, and provide data 1f possible, the ranges of transfer efficiencies that are expected for each type of application equipment sold. DeVUbiss; They do not have experimental data showing transfer efficiencies for this equipment, but expect it to be in the range of 20 to 45 percent depending on the technique and material being applied. Finishing Systems: Transfer efficiency in powder application equipment 1s dependent on many factors. The most Influential factor 1s the composition of the powder; its resistivity, particle size, particle shape, moisture content, resin chemistry and flow A-6 ------- properties. Other factors are gun dependent such as the efficiency of charging the powder with either Internal or external electrodes, shape of the atomized powder cloud, velocity of the powder cloud exiting the discharge nozzle, and distance to the grounded workplace. Transfer efficiency also varies with the various types of charging methods: negative corona, positive corona and trlbo charge. The RECLAIM" Ultra-100 brand of equipment has higher high voltage and current levels at the tip of the gun electrode than other competitive brands. The higher current allows more powder to be charged at a specific high voltage level. FSSI has an Installation where four Ultra-100 guns are performing the same job as six of another manufacture on the same product. FSSI at this time does not have an Interest 1n producing any type of friction tr1bo-charging application equipment. Volstatic; Transfer efficiency 1s dependent on not only the application equipment, but the shape, complexity and "openness" of the parts to be coated. In addition, Hne speed, film thickness and powder chemistry play a major role. Volstatic equipment 1s generally regarded to achieve the highest direct transfer 1n the industry and the following are typical examples with epoxy or polyester powder at average film thicknesses of 1.5 mils + 0.5 mils: a. "Open" parts like large frames, etc: 50 to 60 percent TE b. "Average" line density, e.g., dense wire goods, tubular furniture, lighting fixtures, boxes and cabinetry, etc.: 55 to 80 percent TE c. "Dense" parts or Hne loading, e.g., flat panels: 65 to 85 percent TE In some special-purpose equipment, transfer efficiencies in excess of 90 percent can be achieved, but 100 percent in a spray apparatus is not achieved. (Fluid bed dipping achieves 100 percent transfer efficiency, but at higher film weights on a limited range of parts.) Proper flxturing for dense Hne loading is critical to achieve good transfer efficiency in any spray system. Manual spray systems typically achieve 60 to 75 percent in Volstatic systems. 5. Please provide Information on minimum and maximum coating thickness that can be achieved with each type of application equipment sold. Devnbiss; They believe that coating thickness is largely a function of the powder material itself, and they do not have experimental data in this area. Finishing Systems: The coating thickness 1s very powder dependent. The coating can be applied very thin, 0.6 to 0.8 mils but the hiding capability and the appearance of the coating may not be acceptable, A-7 ------- or may not offer the protection required. The thicker coatings are easier to achieve, but again it depends on the thickness at which the coating will start rejecting additional material and also the overall particle size. Nominal coating thicknesses are generally 1n the range of 1.2 to 2.5 mils on selected surfaces. In areas where manual touch-up is done to an automatically painted part or on surfaces very close to the nozzle of a gun the coating can be 4.0 to 5.0 mils thick. Volstatic: Volstatic has provided large-scale, automatic combination 1 manual /automatic production systems achieving 0.8 to 1.2 mils average film thickness. Some systems are capable of achieving greater than 10 mils single-pass coatings on nonpreheated parts. Preheating parts greatly Increases the maximum film thickness from this range. Thicknesses of 20 to 30 mils are certainly possible. Usually, automatic application systems provide the most consistent thin-film averages, with an additional 0.25 to 0.5 mil typical with manual coating. Without production monitoring, however, manual operators have been known to add a mil or more of unnecessary film weight. 6. Please provide as much information as possible on the types of spray booths (from Item 2) used for powder coating lines (dimensions, airflows, filter types, etc.). DeVllbiss; They are not presently manufacturing spray booths for use 1n powder coating systems. Finishing Systems; FSSI exclusively fabricates cartridge filter type powder booths. The airflow in all the RECLAIM1" powder booths 1s full height of the spray cavity whenever possible and horizontal towards the collector which 1s located at the end of the booth (single extended) or 1n the center between the manual and automatic spray stations (double extended). In cases where the booth is not extended 1t would have a single spray station directly 1n front of the collector as is the design of the laboratory booth. The capacity 1s figured by the sum of all the spray and product openings at an airflow velocity of 100 to 120 feet per minute. Volstatic; Volstatic provided examples of spray booth configurations along with reclaim systems. Product maximum dimensions are not truly limited by the booth; ovens and pretreatment systems provide the practical limits for economic feasibility. The majority of Volstatic euqipment (approximately 95 percent) falls 1n the range of 24"w x 30"h to 72 in. wide maximum width and 312 1n. maximum height, (product opening). The filters are typically nonstatlc cartridge-type 1n combination with two elements of monitoring safety filters afterward. Cyclone separators are often used prior to the filter to maximize filter life, improve efficiency and to allow an unlimited number of colors to be used without filter set duplication. A-8 ------- In some special equipment, (e.g., the Volstatic Freedomcoater) air flows are unusual and aid 1n the coating performance considerably. 7. List typical sizes and operating parameters for powder curing ovens (from Item 2) sold by your company. DeVUblss; They do not presently manufacture or sell powder curing ovens. Finishing Systems; FSSI does not fabricate powder cure ovens. Volstatic: Volstatlc normally works with oven manufacturers for the supply of these products. The product openings match or exceed the booth product openings (see question 6) and the lengths may vary from 6 feet to several hundred feet 1n conveyor1zed systems. Powders typically cure between 325"F and 400°F with cure times between 5 minutes and 20 minutes. Infra-red radiation curing accelerates these times to as little as a few seconds 1n some cases and may permit curing powder on the outside of temperature-sensitive devices whose Internal gaskets, seals or components could not tolerate temperatures above, say, 250°F. Some degree of Infra-red curing is common on massive objects, like Iron or steel castings. 8. Describe recent Improvements 1n powder coating technology that may result 1n expanded or new market areas. DeVUblss; Answer unknown. Finishing Systems; Recent equipment developments have not had significant Impact on developing or expanding new markets. All the development has been in the powder material technology. Volstatlc; The development of the ColorSPEEDER permits a true 5-minute color change without duplicate coating booths, filter modules or spray guns. This saves capital investment, floor space and permits economical "short runs" in production without wasting overspray powder. The Freedomcoater permits high production runs of parts arranged on an Intergral conveyor without the need for flxturing. Automatic masking of one side of the part is a feature of this finishing technique. / New fluorocarbon-based powders will permit the expansion of powder coating into the high-performance architect aluminum extrusion market previously limited to 2-coat liquid coatings. 9. For each type of equipment listed under Item 2, provide costs, or cost factors, that can be used to generate "typical" costs for a complete powder coating line. DeVilblss; A BFA portable powder system sells to an end-user for approximately $3,700.00. A-9 ------- Finishing Systems; Typical costs are not easy to supply since the powder booth equipment is usually custom fabricated. The following are budget prices for complete booth equipment, powder gun and UV fire detection packages in the various airflow and product opening sizes. Configuration Product openings Single extended Double extended ft /min Man Auto Cost, $ Man Auto Cost, $ Opening: 2'wx4'h 2'wxS'h 3'wx6'h 4'wx6'h 3'wx6'h Lab model 3«x3' 4'xS1 4,500 6,000 9,000 12,000 15,000 1,600 3,000 2 1 2 1 2 1 2 1 2 1 1 1 0 4 0 6 0 6 0 8 0 12 0 0 29,200 45,500 40,100 64,100 42,540 70,600 49,500 85,300 56,500 112,300 13,000 14,500 2 2 2 2 2 2 2 2 2 2 — — 4 6 4 8 8 10 8 12 14 16 — — 54,900 64,600 66,000 84,600 89,500 100,500 94,800 114,800 131,900 140,900 — — Volstatic: The following costs refer to equipment listed in question 2.: a. From under $4,000 b. From under $3,500 c. Typically, around $15,000 per gun for the whole system, including booth, guns generator, reclaim system. This number varies a lot depending on the particular system and degree of automation. d. From under $5,000 per gun e. Very dependent on size: from under $10,000 for a self-contained 48 1n.x48 in. face booth with integral reclaim system f. Very dependent on size—see item "c" above g. See item "c" above h. From $500 to more than $5,000 depending on size, degree of contents and degree of integral equipment, e.g., venturi pumps 1. From under $100 and up depending on the individual pieces As a very general guide, not for purpose of ordering, the powder applicators, delivery, and recovery equipment, including architectural interlock safety equipment for an 8-gun, 30"wx66"h automatic coating system may range from $90,000 to $125,000. It is essential to consult with equipment manufacturers, ideally more than one, to obtain usable cost estimates for finishing lines. A-10 ------- 10. In what Industries 1s your equipment most often used (provide a 11st of major customers, If possible). DeVUblss; Most of their more recent powder systems have been used 1n powder coating job shops and the appliance Industry. Finishing Systems; FSSI is Involved mainly 1n the Industrial decorative coating market. The various products being coated with the RECLAIM" powder equipment are as follows: lawn and garden tractors snow blowers patio furniture office furniture pallet racking display shelving wire displays restaurant chairs and tables lighting fixtures propane and oxygen tanks garden posts battery chargers boat trailers rubber membrane roofing radiators and coolers stove burner liners navy missile housings truck air conditioners RV after-market equipment farm fans and coolers radiator fans switching gear enclosures oil coolers truck bumpers hardware TV satellite dishes air conditioner housings light poles school furniture basketball poles and hoops security lighting aluminum car wheels aluminum extrusions shop welders boat winches and hardware pole transformer housings floor sweepers and vacuums parking meters automotive hardware restaurant shelving range hoods fence fabric communications equipment multitude of Job shops Volstatlc; In general, any product which 1s painted with an organic paint and which can be transported into a cure oven and which will withstand powder cure temperatures (see question 7) can and probably should be powder coated. This Includes most products made of metal • and many of other materials. 11. How long has your company sold powder coating equipment? DeVUbissi OeVllblss Company has been manufacturing and selling powder application equipment in excess, of 15 years. Finishing Systems; FSSI has been manufacturing and selling powder recycling and application equipment since March of 1984. Volstatic; Volstatlc has manufactured and sold powder coating application equipment since I960, over 29 years. 12. Do you also sell coating equipment to liquid coating users? If so, please provide information on the cost differences between the types of equipment sold for liquid and powder coatings. A-ll ------- DeVllbiss; OeV11b1ss Company sells a substantial amount of equipment to liquid coatings users. However, since they engage in very little powder application equipment business they do not gather or maintain comparative Information. Finishing Systems; FSSI is not Involved in the liquid coatings market at this time. Volstatic; Volstatlc sells a limited range of generators for private label liquid applications, including the NOT (nondestructive testing) Industry. In general, productive powder coating systems are comparable in capital investment to new liquid coating systems for a given application. A-12 ------- APPENDIX B. SURVEY SUMMARY: POWDER COATING MANUFACTURERS ------- APPENDIX B. SURVEY SUMMARY: POWDER COATING MANUFACTURERS Seven of the nine powder coating manufactures surveyed responded to the survey. A brief summary of their responses 1s provided below. A list of the powder coating manufacturers who responded and a compilation of .their individual responses are also attached. Types of powder coatings manufactured All of the respondents manufacture a variety of thermosettlng powders (e.g., polyester, urethane, epoxy, acrylic, hybrid, etc.). One manufacturer also produced the following thermoplastic powders: vinyl, nylon, and thermoplastic polyester. Color availability All of the respondents stated that virtually any color can be matched with powder coatings. The only limitation they cited was that certain metallic effects are hard to duplicate. One manufacturer explained that, although metallic-effect powder coatings are attractive and often accepted as replacements for liquid paint, it 1s very difficult to match the metallic effects displayed by liquid paint at various viewing angles of the coated part. Pretreatment steps The respondents stated that the substrate pretreatments w111 vary depending upon the substrate and the performance requirements. The pretreatment step most often suggested by the respondents was a three to seven stage Iron phosphate pretreatment. Five to nine stage zinc phosphate and chrome phosphate pretreatments were also listed. Powder storage and handling The majority of the powder coating manufacturers recommended that powders be s.tored at temperatures below 80°F and for a maximum of 6 months. Minimum coating thickness The respondents reported minimum film thicknesses ranging from about 0.5 to 1 mil. Typical film thicknesses ranged from about 1.5 to 3 mil for thermosettlng powders and from 4 to 12 mil for thermoplastic powders. Curing times and temperatures Curing temperatures ranged from a low of 250°F to a high of 475°F for thermosettlng powders, and ranged from 400 to 600°F for thermoplastic powders. Curing times ranged from 10 to 30 minutes, depending upon the curing temperature (I.e., at higher temperatures, the curing times were shorter). B-l ------- Powder coating costs Prices varied depending upon the specific formulation, the quantity ordered, the color, and the gloss level. One powder coating manufacturer stated that bright, sharp, clean colors are 20 to 100 percent more expensive than earthtones, pale shades, whites, and blacks. The price of thernrosettlng powders ranged from $1.75 to $12.00 per pound, depending upon the quantity ordered. The cost of thermoplastic powders was somewhat higher at $4.00 to $14.00 per pound, with the exception of vinyl powders which ranged 1n price from $1.50 to $6.00 per pound. One respondent stated that the "Industry average" cost of powder coatings 1s about $2.49 per pound. Minimum orders Standard or "stock" powders can be purchased from the majority of the powder coating manufacturers 1n quantities as small as 50 Ib. Nonstock powders that are custom-manufactured for specific customers usually have minimum orders from 1,500 to 5,000 Ib. One manufacturer stated that, for all of their powders, the minimum order Is 200 pounds. End users The powder coating manufacturers supply a variety of markets Including major home appliances, metal furniture, automotive, lighting, lawn and garden equipment, piping, etc. Recent trends 1n the use of powder coatings Respondents reported a 20 to 25 percent growth 1n powder sales each year for the past 5 years. One respondent stated that a significant number of conversions from liquid to powder have occurred because of regulations pertaining to the disposal of hazardous wastes. Other reported trends are Increased user sophistication (I.e., 95 percent or greater material utilization efficiencies), consistent thin films, and long-term testing prior to the use of powder. Recent developments . The following developments 1n powder coating technology were reported by the respondents: • high transfer efficiency powder application equipment • capability to apply thinner, more uniform films • more economical powder reclaim systems, facilitating more rapid color change • new powders replacing porcelain in the appliance and bathroom Industries continue to be developed • development of new thermosettlng fluorocarbon powders for use 1n architectural Industry • powder coatings now available for cure as low as 250°F 8-2 ------- powder and application equipment 1s available for coating coil or blank stock powder coatings now exist for coating a variety of plastics, both 1n mold and out of mold metallic look powders which approach chrome appearance are recently available less batch-to-batch variation with powders powders now have better weathering systems for exterior exposure 2 Attachments B-3 ------- Attachment 1 LIST OF RESPONDENTS: POWDER COATING MANUFACTURERS Mr. G. E. Bond Director EVTECH 9103 Forsyth Park Drive Charlotte, North Carolina 28241 (704) 588-2112 Mr. Ron F. Parrel! General Manager The GUdden Company Powder Coatings Operations 3926 Glenwood Drive Charlotte, North Carolina 28208 (704) 399-4221 Mr. Steven Klefer Market Manager Morton Thlokol, Inc. Power Coatings Group Post Office Box 15240/No. 5 Commerce Drive Reading, Pennsylvania 19612 (215) 775-6600 Mr. Douglas Bach Manager of Marketing and Operations The O'Brien Corporation Power Coatings Division 5300 Sunrise Street Houston, Texas 77021 (713) 641-0661 Mr. Trevor Mason General Manager Spraylat Corporation 3465 South La denega Boulevard Los Angeles, California 90016 (213) 559-2335 Mr. John K1sh Customer Service Coordinator FERRO Corporation Power Coatings Division Post Office Box 6550 Cleveland, Ohio 44101 (216) 641-8580 B-4 ------- Mr. BUI O'Dell Operations Manager Lilly Powder Coatings, Inc. 1136 Fayette North Kansas CHy, Missouri 64116 (816) 421-7400 B-5 ------- Attachment 2 SURVEY RESPONSES: POWDER COATING MANUFACTURERS 1. Company name and address; contact name, title, and telephone number. (See Attachment 1) 2. Types of powder coatings manufactured (vinyl, acrylic, polyester, hybrids, etc.) EVTECH; Polyester, urethane, epoxy/polyester, epoxy, acrylic. Glldden; Epoxy, epoxy/polyester hybrid, polyester urethane, polyester, acrylic, (all thermosettlng materials). Morton Thlokol: We currently manufacture thermoplastic and thermoset organic powder coatings as follows: Thermoplastic: vinyl, nylon, thermoplastic polyester. Thermoset: epoxy-all types, hybrid, urethane polyester, TGIC polyester, acrylic. O'Brien Corp.; Epoxy, epoxy-polyester hybrid, urethane-polyester, and TGIC-polyester. No thermoplastic types are produced. Spray!at; "Secura" epoxy, "Secura" hybrid, "Secura" polyester TGIC, "Secura" polyurethane. All available 1n various gloss levels, textures, structures and nonmetallic, metal lies. FERRO Corp.; Epoxy, polyester, hybrid, and acrylic. Lilly; Thermoset powder coatings 1n the epoxy, hybrid, TGIC polyester, and polyurethane chemistries. 3. Describe limitations on color availability. EVTECH: Colors formulated to meet customer requirements. GUdden; There are virtually no limitations on color availability. It should be noted that wh'lle attractive metallic effects can be achieved, metallic particles win generally not orient (flop) the same as they will 1n low viscosity liquids. It 1s difficult to match the exact metallic "flop" 1n different systems. This 1s not only a powder problem but a problem between various viscosities or solids levels in liquids. This is often mentioned as a powder limitation. Morton Thlokol; Virtually any color can be matched 1n any coating type. We have 95 stock colors. O'Brien Corp.; Virtually any color can be produced 1n solid colors. Clear coatings and pigmented transparent colors are also available. The one area in which we are limited by current technology 1s that of metallic-effect coatings. Metallic-effect powder coatings can be produced which are very attractive, and, in B-6 ------- many cases, enjoy very favorable reception as replacements for liquid paint. However, It 1s extremely difficult to match the metallic effect displayed by liquid paint at various viewing angles of the coated part. Usually, this difference 1s not objectionable 1f the powder coated part 1s not placed 1n close proximity to a part coated with liquid paint, or does not require touch-up with liquid paint. However, for applications such as automotive topcoat, powder metalHcs are not yet direct replacements for liquids. Spray3at; Most colors are available with only a few exceptions. Special finishes have some limitations when considering resin. FERRO Corp.; The only restrictions on color is the use of pigmentation that has been chosen as a high risk safety hazard (ex. free-floating metals). Lilly; Generally, any color available in liquid Industrial finishes 1s also available in powder coatings. There are some limitations in matching liquid coatings in metallic formulations. 4. Describe the substrate pretreatment steps that are recommended or required. EVTECH; Three stage iron phosphate or five stage zinc phosphate depending on product requirements. Slldden; Substrate pretreatments vary significantly based on substrate and performance requirements. These will be the same requirements as for liquids, however. Morton Thiokol; All powder coatings require a clean, dry substrate. Further pretreatment 1s dictated by coating performance requirements; I.e., to achieve long-term corrosion resistance five stage or longer iron or zinc phosphating is typically used. A. Thermoset Powders 1. Ferrous substrates a. 3-7 stage iron phosphate with a chrome or nonchrome final rinse. b. Cleaning followed by shot blasting. c. 5-9 stage zinc phosphate. 2. Nonferrous substrates a. 3-7 stage iron phosphate with special additives b. Chromates c. Chrome phosphates d. 5-9 stage zinc phosphate (for galvanized primarily). B-7 ------- B. Thermoplastic powders 1. As above. 2. Nylon and vinyl may require a primer depending on requirements. O'Brien Corp.: Minimum recommended pretreatment is usually 3-stage iron phosphate. For applications which require a high degree of corrosion protection, 5 or 7-stage iron or zinc phosphate is recommended. In applications which are strictly decorative and used in a mild environment such as the interior of a home, vapor degreasing, alkaline cleaning, or solvent washing may be adequate. Spray!at; Thorough cleaning and degreasing. When higher specifications have to be met, a chromate or phosphate coating should be applied to the substrate. FERRO Corp.; Generally, a good quality powder finishing system should have a minimum of 5 stages; however, there are some coaters using 3 stage systems for their quality requirements. A 7-stage operation will be used if physical requirements, such as resistance to salt spray, are extremely demanding. Example of a typical 5 stage (zinc or iron phosphate): cleaner/rlnse/phosphate/rlnse/sealer. Lilly; A clean metal substrate 1s required before electrostatic application. For products exposed to Interior environments, a three- stage pretreatment 1s generally required (washer/phosphate, clear water rinse, and another rinse or sealer). For products exposed to an exterior environment, a five-stage process 1s recommended. This consists of a power wash, a rinse, an Iron or zinc phosphate, a clear water rinse, and a seal. 5. Describe any powder storage and handling procedures that are recommended. EVTECH; Storage conditions should not exceed 80°F for prolonged periods of time. Glidden; Our standard recommendation for powder storage is that the product be stored at 80°F maximum. The time depends upon the specific formulation but in no case is less than 6 months with our commercial products. While the 80°F is a good general recommendation, it is not mandatory. We have some Inventory areas as do some of our customers where there is no warehouse temperature control. Just as many liquid paints should not be stored In extremes In temperature, discretion should be used in storing powder. There are two fundamental mechanisms where powder can be unstable: (1) chemical reaction, and (2) physical melting (sintering/blocking). 8-8 ------- The first 1s dependent upon the chemistry of the particular formulation. More reactive systems can advance with heat. Many formulations will be extremely stable, however. While 1t 1s very difficult to generalize In this area, 1t would be our estimate that 75 percent of product sold have good stability in this area. The second 1s applicable to all solid plastic materials. Depending upon the melting point of the formulation, the particles will begin to stick together under some conditions of elevated heat. Again, it 1s extremely difficult to give quantitative absolutes. Because of the excellent Insulating properties of a container of powder, a package stored at an elevated temperature could take weeks and even months for that temperature to reach all areas of the powder. Powder 1s routinely shipped across the country and through the desert in standard trucks without deleterious effects. Morton TMokol: Typical powder coatings require ambient storage (80"F at 50 percent relative humidity is Ideal). Some special fast cure materials require cold storage. O'Brien Corp.; We recommend storage in a cool enviroment (75° or less) for a period of 6 months, although many applicators routinely store powder for longer periods without experiencing any difficulties. Spray!at; Dry storage, 6 months recommended maximum, stored at not more than 77°F. Particular attention should be paid to storage where adverse climatic conditions are possible. FERRO Corp.: Power storage and handling procedures; a. Climate controlled room for storage of powder coatings; b. Proper rotation of stock; c. Protection clothing and proper respirator; and d. Carefully read all M.S.D.S. information supplied with the . product. :;•:• Lilly; Lilly recommends that powder be stored at less than 80°F. Powder coatings have a shelf Hfe of 6 months from date of shipment, 1f properly stored. 6. Are your powder coatings compatible with all typical application devices? Discuss any known exceptions. EVTECH; Compatible with all powder coating application equipment. Glidden; Our powder coatings are compatible with all powder coating application concepts. Of course, these materials cannot be sprayed through liquid guns. Applicable powder equipment must be employed. Morton Thiokol; Morton powder coatings are used 1n all known types of powder application equipment. B-9 ------- O'Brien Corp.: Our coatings are designed to apply through electrostatic spray guns, trlboelectric guns, electrostatic fluldlzed beds, or conventional fluldlzed beds. On occasion, formulations or process conditions may require alterations to yield acceptable performance on specific types of equipment, and such alterations are generally successful. Spray!at; Electrostatic, hand or automatic spray. Most products can be formulated for use in fluldlzed bed. FERRO Corp.; VEDOC powder coatings are typically compatible with all application equipment. However, particle size distribution and/or a post-additive may be required to Insure peak performance. Lilly; Generally, powder coatings are applied by the electrostatic application method. Another way of applying powder coatings 1s electrostatic fluid bed. 7. What 1s the minimum coating thickness that can be obtained with your powder coatings? What 1s the "typical" coating thickness? EVTECH; Minimum thickness 0.7 mil to 1.0 mil depending on specific color. Typical coating thickness 1.5 mils. Glidden; Film thicknesses requirements vary significantly. We have ongoing commercial operations applying powder in thickness ranging from 0.7 mils to 1.3 mils. Other applications in the electrical Industry average 15 mils. The ability to maintain consistent and low film thicknesses depends significantly on application line design and control. While liquids experience rejects through "runs and sags" when thickness 1s too high, powder is more forgiving. Operators tend to apply powders heavier to take advantage of this flexibility. Morton Thiokol; We have thermoset powder coatings that can be applied as thin is 0.5 mils. Typical thermoset film thickness range 1s 1.5 to 3.0 mil. Often thickness can be controlled to ±0.2 mil. Thermoplastics are usually applied 4 to 12 mils thick. O'Brien Corp.; In "real world" conditions, it is unusual to find coatings applied consistently under 1 mil. In a laboratory situation, coating thickness of under 1 mil may be obtained with acceptable appearance, but it 1s very difficult to maintain this film thickness on a large-scale application line. My opinion on "typical film thickness" is that it is in the 2 to 3 mil range for most applicators. Spray!at; Coating thickness of 1 mil is possible but a thickness of 2 ±0.5 mils is typical. B-10 ------- FERRO Corp.; Based on applications, coating thickness specifications are maintained at ranges of 0.8 to 1.0 mils; custom coaters environment ranges from 2 to 3 mils. Lilly; The minimum coating thickness currently being applied by customers of Lilly is 0.8 to 1 mil. The typical coating thickness is approximately 1.8 to 2.2 mils. 8. Please provide Information on the range ("low," "typical," "high") of curing times and temperatures that are required for the types of powder coatings Identified in Item 2. EVTECH; Low: 30 min. at 275'F (epoxy) Typical: 20 nrin. at 375°F (all others) High: 5 m1n. at 400°F (epoxy) 10 m1n. at 400°F (all others) Glidden: Minimum cure requirements can range from 250°F and 30 minutes to 375"F and 30 minutes. Morton Thiokol; Low Typical High Epoxy 250°F 350° to 400°F 475°F Hybrid 275" to 300°F 350° to 400°F 450°F Urethane polyester 350°F 390° to 400°F 425°F TGIC polyester 300°F 350° to 400°F 475°F Acrylic 275°F 350° to 400°F 450°F Nylon 475° to 600°F Vinyl 400° to 600°F Thermoplastic polyester 400° to 600°F O'Brien Corp.; Cure schedule. Epoxy, hybrid, polyester Urethane Low 275°-350°F/8-20 min 350e-400°F/8-20 min High 350°-425°F/8-20 m1n 375°-425°F/8-15 min Spray!at; Low cure products are available v/1th curing schedule of 3308F, 10 minutes peak metal temperature. Standard cure is 365'F, 10 minutes peak metal temperature. Polyurethane and other low gloss products have a cure of 400°F, 10 minutes peak metal temperature. By Increasing the curing times a lower cure temperature can be achieved. 8-11 ------- FERRO Corp.; Cure schedule: Epoxy Polyester Hybrid Acrylic Typical 3758F/15 min 375°F/15 min 375°F/15 min 3759F/20 min Low 300°F/15 min 360°F/30 min 325°F/30 min 360°F/30 min High 425°F/10 min 425°F/15 min 4258F/10 min 4259F/15 min Lilly; The typical thermoset powder coating cures at 400°F for 10 minutes (or an equivalent bake based on time and temperature). However, coatings can be formulated to cure at temperatures of 275° to 300°F for approximately 20 to 30 minutes, contingent upon substrate thickness. 9. Please provide Information on the price range for each type of powder coating identified 1n Item 2. EVTECH; Prices vary depending on specific formulation from $2.50 to SS.OO/lb. GUdden; Again, price can vary significantly within any generic type based on formulation specifics. The following generalities can be made: Type Cost, $/1b Epoxy 2.40 Polyester/epoxy hybrid 2.20 Polyester urethane 2.35 Polyester 2.65 Acrylic 3.00 Price is only one piece of the economic equation, however. Please refer to attached discussion on economics for further information. Price for pound of our products can range from $1.75/1b to over $10.00/1b with the average being in the $2.50/lb area. Morton Thiokol; Price Is very dependent on color with bright, sharp, clean colors being 20 to 100 percent more expensive than earthtones, pale shades, whites and blacks. Quantity also plays a role in cost. Epoxy Less than $2.00/1b to $12.00 Ib Hybrid Less than $2.00/lb to $12.00 Ib Polyesters Less than $2.00/lb to $12.00 Ib Acrylics Less than $3.00/lb to $12.00 Ib Vinyls $1.50/lb to $6.00 Ib Nylon $4.00/lb to $14.00/lb Thermoplastic polyester $4.00/lb to $14.00/lb O'Brien Corp.; It is very difficult to Identify prices only by chemistry due to the differences in pigments and additives required for each formulation. For the purpose of this survey, they assumed B-12 ------- white, high gloss coatings with a specific gravity of 1.6 to 1.54 produced 1n quantities of 21,000 pounds at a time. (Prices listed were considered confidential.) Spray1 at: Supply prices depend on quantity ordered, type of resin system, gloss level and finish required. FERRO Corp.; Information on pricing by chemical class is proprietary, but the Industry average is $2.49/15. Lilly; The average selling price for powder coatings varies according to specific gravity and color. A pastel color in a hybrid chemistry would sell for approxlmatly $2.30 [per pound] based on a 4,000 pound production. 10. What Is the minimum order (quantity) of each type of powder coating that can be purchased by your customers (excluding samples or trial orders)? EVTECH; 5,000 pound minimum order for shipment over a 6 month period for nonstock products; 55 pounds for stock or standard products. Glidden; Their general position 1s that they do not pursue single orders of powder less than 1,000 Ib in size. Most of their products are custom manufactured for a specific customer. While their company does not engage in a stock color program, many other U.S. powder coating suppliers do with quantities as low as 50 Ib being commercially available. Morton TMokol; Stock materials are available in 55 Ib quantities. Nonstock thermoset powders are available in 1,500 Ib quantities. They have "small lots" capability. This means that any coating type can be manufactured in 100 to 1,500 Ib quantities. O'Brien Corp.; For products produced to a specific customer requirement, 1,500 pound minimum. For existing products in stock, 50 pounds. Spray!at; Minimum orders are for 200 pounds of individual products. FERRO Corp.; Minimum order quantity 1s dependent on overall customer volume but, a typical minimum is 2,000 Ib per color and/or chemistry. Lilly; Minimum orders are 50 pounds for stock products and 2,000 pounds for a custom color match and manufacturing. 11. Please provide as much information as you can on the end users of your powder coatings (I.e., 11st of major customers; major market areas - automotive, large appliance, metal furniture, etc.; new market areas). B-13 ------- EVTECH; Automotive, appliances, metal furniture, lawn and garden equipment. GUdden: We market our material Into several markets which we have segmented as: Major home appliance: Washing machine tops and Hds, spinner baskets, cabinets. Dryer drums and cabinets. Refrigerator shelves, liners, and cabinets. Air conditioner cabinets. Hot water heaters, etc. Automotive: Primer surfacer, anti-chip, trim parts (door handles, etc.), under-the-hood parts (cannlsters, oil filters, air cleaners, etc.), wheels—aluminum and steel. Architectural: Aluminum extrusions, building panels. General Industrial: Electrical, lighting fixtures, office furniture, lawn and garden, and fixtures. Morton Thlokol; They, supply all powder coating markets Including: Furniture—all coating types Automotive—all coating types Appliance—epoxy, hybrid, polyester, acrylic Lawn and garden—all coating types Lighting—all coating types Electronic—all coating types Pipe and rebar—epoxles New market areas Include in mold coating of SMC, coil coating, and blank coating. On request, they can supply Individual customer contacts 1n any market area. O'Brien Corp.: O'Brien 1s strongest 1n the general Industrial finishing market, Including both custom coaters (job shops) and original equipment manufacturers. We do not actively pursue the major appliance market. We do have a presence in the automotive market (OEM and after-market), as well as the metal furniture and office equipment market. Spray!at: Decorative and functional coatings for a wide range of manufacturers and custom coaters. FERRO Corp.: Major market areas: automotive, appliance, and lighting. New potentials: functional, architectural, and plastics. Lilly; Primary market thrust 1s 1n the general metals finishing market. Major customers include manufacturers of small appliances, fabricated wire goods, electrical meters, and audio-visual aids. B-14 ------- 12. Discuss current or recent trends 1n the use of powder coatings. Compare sales of powder coatings 1n 1988 vs. 3 years ago and 5 years ago (for your company and nationwide, 1f known), also compare by major market areas. EVTECH: Powder coatings have grown 1n excess of 20 percent per year 1n volume for the last 4 years 1n the United States. GUdden; Since 1983 powder has been growing at a 20 to 25 percent annual compounded growth rate. Our growth has paralleled the Industry 1n this time period. Morton Thlokol: Total powder coating sales in the USA should exceed 120 million pounds for 1989. This 1s nearly double the figure for 5 years ago. The Powder Coating Institute can provide somewhat accurate yearly totals. The automotive and appliance markets currently use a total of approximately 30 million pounds of powder annually. The annual, metal furniture market usage approaches 20 million pounds. Growth 1n these . markets, as well as those listed 1n No. 11, comes from converting liquid coaters to powder. This growth Is expected to be 15 to 20 percent a year through 1995. As the powder market grows, a significant overall trend 1s Increased user sophistication; I.e., 95 percent or greater material utilization efficiencies, SPC, Incoming QC, consistent thin films, long-term testing prior to use of powder. O'Brien Corp.: Business has Increased over the last few years. Spray!at: Operation not started until July 1987. Therefore, no previous history. FERRO Corp.; Growth has averaged 15 percent per year for the last 5 years. Major market areas have seen a growth rate of 15 to . 18 percent per year over the last 5 years. Lilly; Lilly has been manufacturing powder coatings for the last 2% years. During the past 5 years, a growth rate of approximately 20 percent has been realized in the powder coating industry. A significant number of conversions from liquid to powder have occurred 1n the last year because of Federal and State environmental regulations pertaining to the disposal of hazardous wastes. Most manufacturers converting to powder have a payback period or return on investment of approximately 2 years. B-15 ------- 13. Discuss recent developments in powder coating technology that may result 1n expanded or new market areas. EVTECH; 1. High transfer efficiency powder application equipment 2. Capability to apply thinner, more uniform films 3. More economical powder reclaim systems facilitating more rapid color change Glidden: Several new developments are taking place. One is the use of powder as a "blanks" coating. New materials replacing porcelain in the appliance and bathroom Industries continue to be developed. We are in the early stages of Introduction of a thermosetting fluorocarbon powder. This product 1s aimed at the architectural . Industry which currently uses liquid fluorocarbons because of their excellent durability and UV resistance. We anticipate these products to be equal to or superior to these liquids and see significant market acceptance. Morton Thiokol: • Powder coatings are now available for cure as low as 250°F. • Powder and application equipment 1s available for coating coil or blank stock. • Powder coatings now exist for coating a variety of plastics, both in mold and out of mold. • Metallic look powder coatings which approach chrome appearance are recently available. Also metallic powder coatings can now match most liquid appearances. Generally any organic liquid coating performance can now be equalled by organic powder coatings. O'Brien Corp.; Developments in powder coating technology have tended to be more evolutionary than revolutionary in recent years. Advances have been made in the areas of more consistent products with less batch-to-batch variation, tighter controls on raw material streams, better weathering systems for exterior exposure, materials with better application properties, and materials which may be applied at lower film thicknesses. Progress has also been made in offering a wider range of metallic-effect coatings, and lower bake temperatures for heat-sensitive substrates such as plastics. The ultimate effect of all this is to move the use of powder coatings from an art to a science, thus establishing powder coating as a viable finishing technology which is applicable to a broad segment of the industrial finishing industry. This has been a significant factor contributing to the rapid growth of the powder coatings market in recent years, and should continue in the near term. B-16 ------- Spray1at; No major changes 1n recent years. FERRO Corp.; The development of power coatings for plastics may be the next new market area. Lilly: New markets are opening dally because of Improvements in the application equipment and powder coatings. Lilly 1s now able to develop powder coatings that can be applied at an average dry film thickness of 1.2 mils and achieve complete opacity. The Industry is working on the Improvement of metallic formulations, low cure powders and different generic types that should open new markets 1n the next few years. 14. Do you also sell liquid coatings? If so, can you provide the names of customers that are using liquid coatings to coat Identical products to those being powder coated by other customers? EVTECH; No. GUdden: Yes, we are a major supplier of liquid coatings. Many of our customers use powder and liquid for similar applications. One example would be in the major home appliance segment when some manufactures use powder for the coating of cabinet enclosures and others use liquid. Morton Thlokol; Morton's Powder Coatings Group also markets liquid primers and touch-up paints for powder coatings. A sister company, Bee Chemical, markets liquid coatings. We service similar markets, often together. O'Brien Corp.; O'Brien sells coatings for trade sales (house paints, etc.) and automotive reflnish coatings, but no liquid coatings which could compete directly with powder coatings. Spray!at: Yes, in applications where powder cannot be used I.e., plastics and rubbers. FERRO Corp.: No, Ferro Corp. does not sell liquid paint. Lilly; The parent company, Lilly Industrial Coatings, manufacturers liquid coatings. B-17 ------- APPENDIX C. SURVEY SUMMARY: POWDER COATING USERS ------- APPENDIX C. SURVEY SUMMARY: POWDER COATING USERS Four of the nine powder coating users surveyed responded to the survey. A brief summary of their responses is provided below. A 11st of the powder coating users who responded and a compilation of their Individual responses are also attached. Powder coating experience The number of years each respondent had used powder coatings ranged from 9 to 17 years, with an average experience of about 12 years. Types of items powder coated Two of the four companies only coat products that they manufacture themselves. A third company only coats Items manufactured by other companies, and the fourth company does both. The types of items coated by the four respondents included laboratory casework, medical examination tables, pumps, valves, plumbing fixtures, chemical processing equipment, computer equipment, food processing equipment, window frames, playground equipment, electrical equipment, and aerospace parts. Similar or identical liquid-coated products Two of the respondents also use liquid coatings to coat products that are identical or similar to products that they powder coat. They both preferred powder coatings for the following reasons: (1) thickness control 1s better, (2) finish control 1s better, (3) coverage is better and there are fewer parts rejected for areas not covered, (4) cleanup 1s very simple and easy with powder; there are no chemicals required to cleanup with powder, (5) powder-coated parts are more durable and can withstand strong cleaning agents and, (6) powders are easier to handle and apply. One of the respondents commented that, although it was more costly for him to use powder coatings, the powder coating was necessary to fulfill product requirements. The other respondent stated that his company would prefer to powder coat all of their items, but it was not cost effective for them to change all of their engineering prints and documentation at this time. ' Color avail ability, changeover time, and powder "ecTarnation The number of different colors of powder coatings applied at each facility ranged from 3 to 40. The company that only used three colors required about 20 minutes to change colors and usually changed colors about once a day. The same company was also able to recover 95 percent of their powder overspray (the overspray 1s collected in a filter and run through a sifter prior to reuse to insure its cleanliness and uniformity). The remaining three respondents apply 20 to 40 different colors. One of these companies is able to change colors in about 25 seconds and these changeovers are made several times an hour; however, they do not reclaim any of their powder overspray. A second company changes colors 7 to C-l ------- 10 times a day in about 15 minutes. This company also does not reclaim any powder over spray. The third company changes colors one to four times a day depending upon the volume of each color, and takes 15 to 20 minutes to change. They also have the capacity to reclaim about 35 percent of the overspray, depending upon the volume of parts being run, the particular color, the cost of the materials, and the configuration of the part being coated. Powder types and application equipment The power coating users apply a variety of different powders Including epoxy, PVC, nylon, polyester, Teflon, Ryton and Kynar. All of the respondents use electrostatic spray guns to apply their powders. One company also uses a fluldized bed; however, only nylon powders are used 1n the fluldized bed. The number of "lines" at each plant ranges from one to three lines with 1 to 4 booths per line. Both manual and automatic spray guns are used. Coating Thickness The thickness of the powder coatings applied at the responding facilities ranges from about 1.5 mils to 125 mils. However, three of the four respondents reported thicknesses of 4 mils of less. Curing requirements Required cure temperatures and times of about 350°F to 375°F and 15 to 20 minutes, respectively, were typical. One company had a maximum cure temperature and time of 750°F and 8 hours. Converting from liquid to power coatings Only one of the four respondents converted from conventional liquid coatings to powder coatings. This company switched from liquid to powder due to requirements that the coatings be resistant to strong chemicals. One result of their switch is that they are able to offer their customers fewer colors and the film thicknesses have Increased; however, because the greater film thickness covers Irregularities 1n the substrate, they tend to have fewer rejects. "New" powder coating facilities Three of the four respondents were "new" powder coating facilities (I.e., they did not convert from liquid to powder coatings). These companies selected powder coatings rather than liquid coatings for the following reasons: (1) greater durability of powder coatings when subjected to strong cleaning agents, (2) powder coatings offered a nonpolluting process, (3) powder coatings performance versus paint was Impressive, (4) powder is less labor-intensive, and (5) powder coating can be done using less expensive employees. All of the respondents reported that their powder coating system either met or exceeded their expectations. C-2 ------- Capital and operating costs The capital cost of each plant's powder coating system ranged from $150,000 to $200,000. One company estimated the cost of powder coating to be -0.058 per square foot of coated product. Limitations associated with powder coatings Two of the respondents cited the following limitations that prevent them from applying powder on other products: (1) special colors would require development by the suppliers, and therefore,-those items requiring special colors are not done as powder coating, (2) special effects such as spatter texture may pose problems; however, texture powders are available if satisfactory to customers, (3) orange peel appearance on some powder- coated Items, and (4) excessive buildup in corners of enclosures. Another respondent stated that his company would prefer to powder coat all of their Items, but that it 1s not cost effective for them to switch over at this time. 2 Attachments C-3 ------- Attachment 1 LIST OF RESPONDENTS: POWDER COATING USERS Mr. Keith M. Long Manager, Process Operations American Sterilizer International 2720 Gunter Park East Montgomery, Alabama 361104 (205) 277-6660 Mr. David T1ce Superintendent, Maintenance Hamilton Industries, Inc. 1316 18th Street Two Rivers, Wisconsin 54241 (414) 793-1121 Mr. Jeffrey S. Yahn General Manager Erie Advanced Manufacturing 3150 West 22nd Street Erie, Pennsylvania 16506 (814) 833-1711 Mr. Dale A. Gumm Owner Tuscon Spraying Technology 628 E. 20th Street, Building 0 Tucson, Arizona 85719 C-4 ------- Attachment 2 SURVEY RESPONSES: POWDER COATING USERS 1. Company name and address; contact name, title, and telephone number. (See attachment) 2. How long has your company used powder coatings? AMSCO: 12 years Hamilton Industries; -12 years, Increased use 2 years ago Erie Advanced Manufacturing; 17 years Tucson Spraying Technology; 9 years 3. List the Items that your company manufactures that are coated with powder coatings. AMSCO; Surgical light parts, surgical table parts and sterilizer control panels. Hamilton Industries; Laboratory casework, medical examination tables, Institutional Erie; They only coat Items manufactured by other companies; they are a "custom powder coater." Tucson Spraying Technology; Electrical components. 4. Oo you apply powder coatings to products manufactured by other companies? If so, please 11st the Item you coat. AMSCO; No Hamilton Industries: No Erie; Yes. Pumps, valves,-plumbing fixtures, chemical processing equipment, computer equipment, hospital equipment, food processing r equipment, window frames, playground equipment, and electrical components. Tucson Spraying Technology: Electrical components, aerospace. 5. Are there identical (or similar) products coated by your company with liquid coatings? If so, please provide a comparison of advantages and disadvantages of the two coating types (Include factors such as cost, performance, ease of application, etc.). AMSCO; Yes, some similar parts are liquid coated. Powder 1s preferred for the following reasons: (1) thickness control is better with powder, (2) finish control is better, (3) coverage 1s better and C-5 ------- there are fewer parts rejected for areas not covered, (4) cleanup is very simple and easy with powder; there are no chemicals required for cleanup with powder, (5) powder-coated parts are more durable and can withstand strong cleaning agents, and (6) powders are easier to handle and apply. Hamilton Industries: Yes, identical products in their laboratory casework line are finished with liquid coatings; advantages of powder coating are: (1) cost of powder coating is greater than cost of liquid coating, but the p.c. performance 1s better and fulfills product requirements, (2) powder coatings are easier to apply. Erie; No Tucson Spraying Technology: Powder coating is more cost effective than liquid coating; less EPA problems, less rejects with powder coatings. 6. How many different colors of powder coatings are applied? AMSCO; Three different colors applied Hamilton Industries: 22 different colors applied Erie; 20 different colors applied Tucson Spraying Technology; Approximately 40 7. If several colors are applied, how much time is required for a color changeover? How often are changeovers made? AMSCO; 20 minutes to change colors, -I color change per day Hamilton Industries; Colors are changed in -25 seconds; change overs are made several times an hour Erie; 15 to 20 minutes between changes; changes are made one to four times a day depending upon the volume of each color Tucson Spraying Technology; We can color change 1n 15 minutes. We may change colors 7 to 10 times dally. 8. How many "lines" are used to apply powder coatings? How many booths and spray guns per line? AMSCO; One line with three spray booths (one spray gun per booth) Hamilton Industries: Three lines; one Hne has four booths and five operators, another line has one long continuous booth and five operators, the third line has two booths and two operators C-6 ------- Erie: Three conveyor lines; one has four auto guns and one manual gun (two booths); another has one manual gun or a fluid bed (one booth), and the third has one manual gun (one booth). They also have four batch coating areas that each uses one manual gun. Tucson Spraying Technology; Two job shop booths. 9. What type of application equipment do you use to apply powder coatings? What types of powders do you apply? AMSCO: Powder 1s applied using Nordson Paint equipment; they use three powder coating suppliers: (1) O'Brien Corp., (2) International Paint, and (3) Morton Thlokol, Inc. Hamilton Industries; Electrostatic spray for all but a small percentage which 1s applied via fluldlzed bed; coating types are epoxy (electrostatic) and nylon (fluldlzed bed). Erie; Nordson and Volstatlc electrostatic guns; all types of powders Including; PVC, nylon, epoxy, polyester, Teflons, Ryton, Kynars, etc. Tucson Spraying Technology; Nordson Equipment, many powder suppliers—primarily Morton. 10. What coating film thickness Is routinely achieved on your powder coated products? AMSCO; -4 mils Hamilton Industries; Average -1.5 mil or greater Erie; 1 to 125 mils routinely applied Tucson Spraying Technology; 1.5 mils 11. What are the curing requirements for your powder coated products (temperature and time)? AMSCO; All coatings baked at 375°F for 15 minutes Hamilton Industries; Cure requirements, are 350°F for 18 minutes Erie; Minimum temperature of 350°F for 40 minutes and maximum temperature of 750°F for 8 hours Tucson Spraying Technology; Average 20 to 30 minutes per load 12. If your powder coating line replaced a conventional liquid coating line, please provide the following information: AMSCO: Old not replace conventional liquid coating line C-7 ------- Erie: Did not replace conventional liquid coating line A. *Why did you convert to powder coatings? Hamilton Industries; Switched due to requirements for resistance to strong chemicals in their laboratory casework line Tucson Spraying Technology: We started with powder and added liquid B. Which components of the existing liquid line could be adapted to powders? Hamilton; Conveyors and booths easily adapted Tucson Spraying Technology: None C. What additional equipment had to be added to apply powders? Hamilton; Electrostatic application equipment and hoppers Tucson Spraying Technology: All 0. Old product specifications have to be changed (colors, film thickness, etc.)? Hamilton; Color offerings reduced; film thicknesses increased Tucson Spraying Technology: Some manufacturers had to initiate a powder specification as none existed with their company E. If you operate a coating job shop, did you lose (or gain) customers as a result of changing to powders? Hamilton; N/A Tucson Spraying Technology; Gain F. Has productivity been affected? How and why? Hamilton; Fewer rejects because greater film thickness covers irregularities in the substrate Tucson Spraying Technology; Yes. Powder is less labor-intensive G. Was extensive operator training required? How did training time compare with training an employee to use liquid coatings? Hamilton; Training time was about the same for application of powder vs. liquid C-8 ------- Tucson Spraying Technology; Powder coating can be done by less expensive employees than liquid H. What unexpected problems have you encountered? How were they resolved? Hamilton: Tendency 1s to apply excessive film; this was overcome by zone spraying in conjunction with the use of smaller nozzles by certain operators Tucson Spraying Technology; Pretreatment equipment is an absolute I. What reactions have you received from customers? Hamilton; Customers prefer powder coat; specially formulated coatings are highly chemical resistant on their products Tucson Spraying Technology; They like the durability. They can get more product to market with less assembly damage J. Are you pleased with your decision to convert to powder coatings? Hamilton; Yes Tucson Spraying Technology; We did not convert to powder, we started with powder coatings—answer yes. 13. If your powder coating line is a new facility (not a converted line), please provide the following Information: Hamilton; N/A Tucson Spraying Technology: Although their powder coating line was a new facility, they responded to question 12 rather than 13 A. Why did you select powder coatings rather than liquid coatings? AMSCO; Greater durability of powder over liquid coatings; their products are subjected to some strong cleaning agents in the sterile environment and powder-coated surfaces are much more durable Erie; Selected powder coating because it offered a nonpolluting process that was competitive with paint; also, powder coatings performance vs. paint was impressive B. Did you obtain cost quotes for powder and liquid systems? (If so, please provide copies or summarize differences.) AMSCO: No response C-9 ------- Erie: No C. Has the powder system met your expectations? If not, please describe problems. AMSCO; Yes Erie; Exceeded their expectations 0. Are you pleased with the decision to use powder coatings? AMSCO; Yes, powder met expectations and is much easier to handle and apply Erie; Yes 14. Have you encountered problems with the storage, handling, distribution, or application of powders? If so, what were they and how did you resolve these problems? AMSCO; No problems. They, only order -2 weeks quantity of powder at a time Hamilton Industries; Powders of limited use, which may be stored during hot weather, and may be stored for periods longer than 6 months, may produce rough surfaces. Powders should be stored in a cool area; old powder may have to be discarded Erie; No problems Tucson Spraying Technology; No 15. Please provide information on the capital and operating costs of your powder coating system, broken out by components if possible. AMSCO; Total capital cost -$200,000; this includes booths, application equipment and two ovens. Estimated cost of the powder coating -$0.058 per square foot Hamilton Industries; Information not readily available Erie; Paid $150,000 for "used" coating Hne Tucson Spraying Technology; We have a capital equipment investment of approximately $150,000. 16. Please describe limitations associated with powder coatings that prevent you from using them on other products. (Include items such as cost, performance, and application limitations.) AMSCO; Would prefer to powder coat all items, but 1t is not cost- effective to change all of their engineering prints and documentation at this time C-10 ------- Hamilton Industries; (1) special colors would require development by the suppliers, and therefore, those items requiring special colors are not done as powder coating, (2) performance has improved, (3) special effects such as spatter texture may pose problems; however, texture powders are available, if satisfactory to customers Erie: No limitations. They powder coat parts from 1 Inch in diameter to 4 feet long and 12 inches in diameter Tucson Spraying Technology: (1) orange peel, (2) excessive build up 1n corners of enclosures, (3) color selection and availability 17. What percentage of your "overspray" 1s collected for recycle or reuse? How 1s this done? AMSCO: 95 percent of all powder overspray is collected in a filter for reuse; the powder is run through a sifter prior to reuse to insure its cleanliness and uniformity Hamilton Industries; None Erie; Depends upon: volume of parts being run-, the particular color, cost of the materials, and the configuration of the part being coated; they have the capacity to reclaim -35 percent of the overspray Tucson Spraying Technology; None 18. Are there solid waste disposal problems associated with your powder coating system? AMSCO; None. Because 95 percent of powder 1s reclaimed, there is very little waste to deal with Hamilton Industries: No Erie; None; when they have powders to dispose, they put the powder In boxes and "cure" the powder into a hardened block to prevent problems with "dust" Tucson Spraying Technology; None C-ll ------- TECHNICAL REPORT DATA Please read instruct tons on me reverse oetore camoiennei 1. REPORT NO. 12. 3. RECIPIENT'S ACCSSSION NO. 4. TITLE AND SUBTITLE Powder Coating Technology Update 5. REPORT DATE : September 1989 ,S. PERFORMING ORGANIZATION CODE I 7. AUTHOR(S) Hester, C. I., Nicholson, R. L., Cassidy, M. A. 8. PERFORMING ORGANIZATION REPORT NO. 9. PERFORMING ORGANIZATION NAME ANO ADDRESS Midwest Research Institute 401 Harrison Oaks Boulevard, Suite 350 Gary, North Carolina 27513 10. PROGRAM ELEMENT NO. ill. CONTRACT/GRANT NO. 68-02-4379 12. SPONSORING AGENCY NAME ANO ADDRESS U. S. Environmental Protection Agency Control Technology Center Research Triangle Park, N.C. 27711 13. TYPE OF REPORT ANO PERIOD COVERED Fi'nV? 14. SPONSORING AGENCY CODE IS. SUPPLEMENTARY NOTES Work Assignment Manager: Karen Catlett, Office of Air Quality Planning and Standards 16. ABSTRACT The objective of this report Is to provide an overview of the current status of powder coating technology. Because powder coatings are applied as dry, finely divided particles, there are no volatile organic compounds (VOC's) released during application, and only minute quantities are released during the curing process. Therefore, the Increased use of powder coatings, as an alternative to liquid solvent-based coatings, represents a significant reduction in emissions of VOC's. This report describes current powder coating materials and equipment, end uses, and economic advantages of the use of powder coatings. Included 1n the report are discussions of the disadvantages and potential problems Identified early in the powder coating development process. The report addresses the resolutions of many of 'these problems. This report is Intended to be of use to State and local agencies 1n their evaluation of powder coatings as an alternative to coatings containing VOC's. 7. KEY WORDS ANO DOCUMENT ANALYSIS DESCRIPTORS b.IDENTIFIERS/OPEN ENDED TERMS c. C3SATI I leld.'CrOUp Powder coating technology Powder coating end uses VOC emissions reduction Surface coating Coating systems Industrial finishes VOC's • 18. DISTRIBUTION STATEMENT i Release unlimited i 19. SECURITY CLASS /TliiSKeporti :1. NO. OF PAGES 20. SECURITY CLASS /This page I 12. PRICE SPA form JI20-1 (R»». 4-77) =H«viouS COITION is OBSOUCTC ------- |