United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park NC 27711
EPA-450/4-80-022
August 1980
Air
Philadelphia Oxidant
Enhancement Study:
Hydrocarbon Analysis
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EPA-450/4-80-022
Philadelphia Oxidant Enhancement
Study: Hydrocarbon Analysis
by
H. Westberg and P. Sweany
Chemical Engineering Department
Washington State University
Pullman, Washington 99164
Contract No. 68-02-3339
Prepared for
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Air, Noise, and Radiation
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711
August 1980
-------
DISCLAIMER
This report has been reviewed by Washington State University and EPA
and approved for publication. Approval does not signify that the contents
necessarily reflect the views and policies of the Environmental Protection
Agency, nor does mention of trade names or commercial products constitute
endorsement or recommendation for use.
n
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ABSTRACT
An extensive hydrocarbon monitoring program, including ground level
and aerial sampling, was conducted in the Philadelphia area during July
and August of 1978. Individual hydrocarbon identities and concentrations
were determined in approximatley 150 samples. One-hour integrated samples
were collected each day during the 0600-0700 and 0800-0900 EOT time periods
at two Philadelphia locations. Airborne sampling was performed by an EPA-
Las Vegas Helicopter. The hydrocarbon data will be utilized to improve
current knowledge concerning photochemical processes which lead to peak
ozone and N02 concentrations in the Northeastern United States.
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CONTENTS
Page
ABSTRACT ................ » . . . iii
FIGURES v
TABLES vi
ACKNOWLEDGEMENTS vii
Introduction 1
Experimental Procedures 2
Results 8
REFERENCES 20
APPENDICIES 21
A. Individual hydrocarbon concentrations in 0600-0700 Franklin
Institute samples 21
i
B. Individual hydrocarbon concentrations in 0800-0900 Franklin
Institute samples 41
C. Individual hydrocarbon concentrations in 0600-0700 Industrial
site samples N • • C3
D. Individual hydrocarbon concentrations in 0800-0900 Industrial
site samples 86
E. Individual hydrocarbon concentrations in afternoon (1400-1500)
integrated samples 109
F. Individual hydrocarbon concentrations in roving samples collected
in the Philadelphia area 115
G. Individual hydrocarbon concentrations in helicopter samples
collected by EPA-LV 130
H. Individual hydrocarbon concentrations in samples collected for
intercomparison purposed 166
IV
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FIGURES
Number Page
1 Map of Philadelphia area 3
2 Map of Eastern Pennsylvania 4
3 Total ion chromatogram from ambient air sample 9
4 FID chromatogram for sample collected between 0600-0700 on
July 27, at Franklin Institute site . 10
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TABLES
Number Page
1
2
3
4
5
6
7
8
9
Results of Collaborative Gas Analysis Cross Reference
Service Non-methane Hydrocarbon (C^io) by GC Analysis . . .
Hydrocarbon Concentrations in 0800-0900 Granklin Institute
Sample on 7/26/79
Non-methane Hydrocarbon Concentrations (ppbC) Obtained by
Percentage Olefins, Aromatics and Paraffins in Surface
Average Concentration (ppbC) of Selected Hydrocarbons at
Average Concentration (ppbC) of Selected Hydrocarbons at
Summary of Non-methane Hydrocarbon Concentrations (ppbC) in
Comparison of Concentration Data Obtained from an Individual
7
/
11
1 O
lo
1 A
14
1 C
lb
ID
i -7
I/
1Q
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ACKNOWLEDGEMENT
We wish to thank the Environmental Protection Agency - Office of Air
Quality, Planning and Standards for providing financial support for this
field program. Special thanks go to Hal Richter for his help and guidance
with technical aspects of the study. We are indebted to Jim Friend and
Allan Smith of Drexel University for providing laboratory space for our
gas chromatographs. The use of City of Philadelphia air monitoring stations
is greatfully acknowledged. Other members of the Washington State University
research group who participated in this study include Mike Holdren and Scott
Robinson.
vn
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INTRODUCTION
EPA is currently attempting to assist various states with control re-
quirements needed to attain the ambient air quality standard for ozone.
Part of this effort involves assessing the utility of various air quality
simulaiton models for designing ozone control strategies. To test the
usefulness of the modeling approach, an attempt is being made to verify a
model in several urban areas which typlify different photochemical and
meteorological regimes. During the summer of 1979 a comprehensive data
gathering program was conducted in the Philadelphia area. Several research
organizations aided in this effort to acquire sufficient air quality,
meteorological and emissions data for applying the SAI Photochemical model.
The ambient measurements will also serve as validation points for evaluating
the model's predictive capabilities.
Since hydrocarbons are one of the important precursors for oxidant for-
mation, they play an integral part in any modeling effort. The SAI model
requires that hydrocarbons be grouped together according to carbon bond type.
Thus paraffins, olefins and aromatics are treated as separate input para-
meters in the model. Acquisition of this type of hydrocarbon information was
the primary goal of our study in the Philadelphia region during the summer of
1979. Results from this hydrocarbon measurement program are described in this
report.
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EXPERIMENTAL PROCEDURES
Approximatley 150 samples for detailed hydrocarbon analysis were collected
in the Philadelphia area during the period from July 15 to August 15, 1979.
Samples were collected at two ground level monitoring sites and aloft in a
helicopter. All analyses were completed within 24 hours of when the sample was
collected.
SAMPLING SITES AND PROCEDURES
Our base of operations in the Philadelphia area was located at Drexel
University. Analytical instrumentation was set up in laboratory space provided
by the chemistry department. Four samples for detailed hydrocarbon analysis
were collected each day at two City of Philadelphia air monitoring stations.
One-hour integrated samples were obtained at each site between the hours of
0600-0700 and 0800-0900 EOT. Air was transferred from the station's sample
manifold into a 20L.Teflon bag by means of a Komhyr Teflon pump (Science Pump
Corp.). Both the pumps and the bags were shown to be free of contamination.
In addition to the four integrated samples, two grab samples were collected
in stainless steel canisters at various locations in the Philadelphia area
on most days. The canisters were filled to a positive pressure with a battery
operated Metal Bellows pump.
Figures 1 and 2 show the location of the study sites. The routine collec-
tion stations were located at the Franklin Institute near downtown Phila-
delphia and in a more industrialized area just south of the approach to the
Walt Whitman Bridge. The roving sites depicted in Figure 1 represent typical
grab sample collection points.
On days when the EPA-Las Vegas helicopter was able to fly, four airborne
samples were acquired by pressurizing stainless steel canisters with a Metal
Bellows pump.
2.
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PHILADELPHIA AREA
Roving site
Scale
mi.
Figure 1. Map of Philadelphia Area.
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©
-L. Pipersville, PA
+ Pottstown, PA
, Pottstown
VORTAC
Yardley
VORTAC
-|- Willow Grove NAS
Wilmington Airport
V ' I
New Castle +&j_ New Castle, DE
VORTAC
Chesapeake & Delaware Car\a\_
Summit Field
o
Woodstown
_ VORTAC
McGuire
VORTAC
Robbinsville
VORTAC
-f- Medford, NJ
¥
-f Seabrook, NJ
©•
+ Hammonton, NJ
Millvilie
VORTAC
LEGEND:
1 Spiral Site
^ .VORTAC -
A- Airport
j_ Landmarks
NAUTICAL VIILES 10| | |
STATUTE MILES 10| [
I I I I I
| |
|
0 10| 20 1 JO
0 10] 20 1 30)
Figure 2. Map of New Jersey and Southeastern Pennsylvania
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SPIRAL SITE DESCRIPTIONS
SITE NUMBER
LOCATION
10
11
12
SUMMIT FIELD
MODENA
MEDFORD
TRENTON/
ROBBINSVILLE
LAKEHURST
CENTER CITY
BUCKS FIELD
Four Mile
(McGuire AFB)
PIPERSVILLE
WILLOW GROVE
YARROW FIELD
HAMMONTON
1 nautical mile (nrni) south of the
Chesapeake & Delaware Canal in Delaware.
Elevation 71 ft, 39°31'17" N, . 75°43.'15" W.
Altor power substation, 3 nmi northeast of
the Modena VORTAC, near West Chester, PA.
Elevation 200 ft, 39°5S'OS" N, 75°39'59" W.
Medford Field (the Flying "W" Ranch), 2 nrai
north of Medford, NJ. Elevation 50 ft,
39°56'05" N, 74°48'27"W.
Trenton/Robbinsville Airfield, 2 nmi east
of Trenton, NJ, beside the NJ turnpike.
Elevation 119 ft, 40°12'56" N, 74°36'25" W.
North of Lakehurst, NJ approximately 4 nmi.
(This site was never used.) Elevation
103 39°58'45" N, 74°24'30"W.
Penn's Landing, Philadelphia, PA. Elevation
10 ft, 39°56'45" N, 75°08'11" W.
Palatine, NJ, 4 nmi east of Seabrook, NJ.
Elevation 100 ft, 39°32'10" N. 75°11'12" W.
Four Mile, NJ. A New Jersey mental hospi-
tal located on the 310° radial, 9 nmi from
the Coyle VORTAC. Elevation 100 ft,
39°53'12" N, 74°35'00" W.
Pleasant Valley Park, PA. A ravine 3nmi
east-northeast of Pipersville, PA and 2 nmi
northeast of Point Pleasant, PA. Elevation
150 ft, 40°26'15" N, 75°04'46" W.
Naval Air Station (NAS) Willow Grove, PA.
Elevation 36 ft, 40°11'51" N, 75°08'47" W.
Yarrow Field, Schwenksville, PA. (Some-
times referred to as PERKIOMEN.) Eleva-
tion 310 ft, 40°15'00" N, 75°25'00" W.
Hammonton Field, Hammonton, N'J. Elevation
69 ft, 39°41'16" N, 74°44'42" W.
4A
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GC PROCEDURES
Gas chromatographic analyses were performed with two Perking Elmer 900
chromatographs equipped with subambient temperature programming capabilities.
The normal carrier gas flow system was modified to include a freeze-out trap
for concentrating organics in ambient air.(l) The column used to separate
light hydrocarbons (C2-Cs) was a packed capillary (20' x 1/16") containing
Durapak n-Octane/Porasil C. When operated with a carrier gas (He) flow of
5 ml/min and temperature programmed from -60° to 80°C at 24°/min, this col-
umn provided excellent resolution of the light hydrocarbon fraction.
A SE-30 glass capillary column (J & W Scientific) was used to separate
hydrocarbons in the GS to CIQ molecular weight range. Helium was used as
the carrier gas with column flow maintained at 1 ml/min. Optimum results
were obtained by temperature programming from -50° to 80°C at 4°/min.
Air from the sample container was drawn through the cryogenic trap into
an evacuated cylinder. The sample volume was monitored by measuring the
pressure change in the evacuated cylinder. Normally, 500 ml of air was
passed throught the freeze out trap which was maintained at -186°C (liquid
oxygen). The trap itself consisted of a 1/8" x 6" stainless steel tube
packed with 60-80 mesh glass beads. This trap was attached to the gas
chromatograph via a mini-volume gas sampling valve (Carle Inst.).
Output from the gas chromatographs was channeled directly into a
Hewlett Packard 3352 data system. This is a computer based system which
provides individual hydrocarbon identification and quantisation information
immediately following each gc run.
A Hewlett Packard 5930A Mass Spectrometer coupled with a Hewlett Packard
5700 Gas Chromatograph was employed in our home laboratory for gc-ms analysis.
The mass spectrometer is a standard quadrupole instrument which has been
modified by the addition of a second 4-inch diffusion pump. The glass cap-
illary columns we use for hydrocarbon analyses require a low carrier gas flow
rate (<5 ml/min.). This, coupled with the extra pumping capacity, permits
the total gc column effluent to be passed directly into the mass specto-
meter. Thus, the mass spectrometer serves exactly the same function as the
flame ionization detector and a chromatogram resulting from the flame detec-
tor will be nearly identical to that recorded by minitoring the total ion
current in the mass spectrometer. This makes it relatively easy to verify
peak assignments. Samples collected and analyzed in the field using the
flame ionization detector are shipped to our mass spec laboratory where they
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are analyzed using the same chromatographic conditions as in the field.
Hydrocarbon identities reported in this study are based on retention time
comparisons with standards plus mass spectral fragmentation patterns.
CALIBRATION
Calibration of the Perkin Elmer gas chromatographs was achieved by
measuring instrument response to known concentrations of hexane in air..
Three different hexane sources were used to prepare standards in the ppbC
range. In the field, a .209 ppbC neo-hexane standard was run each day in
order to insure instrument stability and response reproducivility.
We have participated in several hydrocarbon intercomparison checks
with other research groups during the past few years. In all cases our
results have been in good agreement. Table 1 shows data obtained by
Scott Environmental Technology, Inc. during their cross reference studies.
TABLE 1. Results of collaborative Gas Analysis Cross Reference Service
Non-methane Hydrocarbon (C^Hin) by GC Analysis (2).
Company Analysis
(ppb)
EPA (ESRL-RTP) .269
Scott Env. Tech. .202
Washington State Univ. .249
As can be seen, our analysis results were intermediate between the other
two groups and very close to the mean (.240 ppm).
During the 1979 field program in Pennsylvania, several samples were inter-
changed between our group and the EPA (RTP-ESRL) field laboratory which was
located east of New York City on Long Island. Table 2 lists data obtained
from two ambient air sample canisters that were exchanged.
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TABLE 2. Hydrocarbon Intercomparisons Between WSU and EPA-RTP.
Sample
Canister #1
Canister #2
Sample
Canister #1
Canister #2
Identified
NMHC (ppmC)
.520
.483
Identified
NMHC (ppmC)
.488
.465
Species
0
18
14
Species
0
14
12
WSU
Breakdown (%)
A P
22
23
EPA
56
58
Breakdown (%)
A P
32
29
49
54
Both the total quantity of hydrocarbons identified and the species breakdown
data are in fairly good agreement.
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RESULTS
Individual hydrocarbon information was obtained from approximately
150 samples collected in the Philadelphia area. As" indfca't'ed previously,
sampels were routinely obtained between 0600-0700 and 0800-0900 EOT at two
fixed surface sites. Other samples were collected in the Philadelphia area
at various ground level locations and aloft from an instrumented helicopter.
As pointed out in the Experimental Section, individual hydrocarbon
identities were established through a comparison of retention times and mass
spectral fragmentation patterns. Using these procedures we were able to
identify about 75 hydrocarbon species. This generally corresponds to at
least 80% of the individual hydrocarbon total. Light hydrocarbon identities
were easily established on a retention basis. Figure 3 shows a total ion
chromatogram obtained from an ambient sample. The peaks which represent
hydrocarbon compounds in the 05-012 molecular weight range were assigned
primarily on the basis of fragmentation patterns.
Once a hydrocarbon pattern has been established using the gc-ms technique,
it can easily be extrapolated to the large number of field samples since we
employ exactly the same column and gas chromatographic conditions in both the
field analysis (flame ionization detector) and laboratory analysis (mass spec
detector). For example, Figure 4 shows a chomatogram typical of those
obtained in the field. The pattern provided by toluene, ethyl benzene, p & m-
xylene and o-xylene (peaks 46,55,56 and 58) is readily distinguishable in both
chromatograms. There are other commanly encountered patterns in the lower
molecular weight ranges as well. Using these marker peaks, the low concen-
trations peaks recorded in a field chromatogram can usually be identified.
The results of this procedure are exemplified in Table 3, which lists
individual hydrocarbon concentrations in a sample collected at Franklin
Institute on the morning of July 26. As indicated near the bottom of the
table, the total of all identified hydrocarbons was 709 ppbC. The small
unidentified peaks in the" chromatogram amounted to an additional 109 ppbC.
Therefore, a total of 818 ppbC was recorded in this sample 87% of which was
assignable to specific hydrocarbons.
All of the ethylene data reported for the FVnak'lih 'Institute and Indus-
trial sites are questionable. Consequently, we have flagged ethylene con-
centration as shown in Table 3 and have not included these data in the sum-
mations. Neither of the City of Philadelphia monitoring stations had ethylene
8
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TOTAL ION CHROMATOGRAM
INCREASING TIME AND TEMPERATURE
1. 2 - Methyl - 1 - butene 37.
2 - Methyl butane 38.
Halocarbon 39.
1 - Pentene 40.
3 - Methyl - 1 - butene 41.
n - Pentane 42.
7. Isoprene 43.
8. Carbon disulfide 44.
9. t - 2 - Pentene 45.
10. c - 2 - Pentene 46.
11. 2 - Methyl - 2 - butene 47.
12. 2.2 - Ulmethylbutane 48.
1). Cyclopentene 49.
14. /"Cyclopentane
V.4 - Hethyl - 1 - pentene 50.
II. 2.3 - Otmethylbutane 51.
16. (2 Hethylpentane 52.
Vt 4 - Hethyl - 2 - pentene 53.
17. c 4 - Hethyl - 2 - pentene 54.
It. 3 Methylpenten* 55.
19. n. Hethyl -. 1 - pentene 56.
VI Hexene
20. n Hexane 57.
21. t 2 - Hexene 58.
22. (2 - Hethyl - 2 - pentene 59.
\t-3- Hethyl - 2 - pentene 60.
23. c - 2 - Hexene 61.
24. Methylcyclopentane 62.
25. c • 3 - Methyl - 2 - pentene 63.
26. 2.2.3 - Trlmethylbutane 64.
27. 1.1,1 - Trlchloroethane 65.
2B. 2.4 - Dimethylpentane 66.
29. Benzene 67.
30. 1 - Methylcyclopentene 68.
31. Cyclohexane 69.
32. 2 - Methylhexane 70.
33. 2.3 - Dlmethylpantane 71.
14. 3 - Methylhexane 72.
35. D1a»thylcyc1opentane
M. Dlaethylcyclopentane
Dine thy 1 cyclopentane
2.2.3 - TrlMthylpenUn*
n - Heptane
Hethylcyclohexane
Trlmethylcyclopentane
EthylCyclopentane
2.5 - Olmethylhexane
2,4 - Olnethylhexane
2.3,4 - Trlmethy 1 pentant
Toluene
2.3 - Olmethylhexane
2 - Methyl heptane
n - Ethylhexane
\3 - Methyl heptane
C - 9 Alkene
DlMthyl cyclohexane
n - Octane
Ethylcyclohexane
C - 9 Alkane
Ethylbenzene
p - Xylene
\n - Xylene
Serene
o - Xylene
n - Nonane
1 - Propylbenzene
n - Propylbenzene
3 - Ethyl toluene
2 - Ethyl toluene
1 - Ethyl toluene
1,3.5 - Trlmethylbenzene
1.2.4 - TrlmethylbenztM
1,2.3 - Trlnethylbenzene
Methyls tyrene
1,3 - 01 ethyl benzene
1.4 - Olethylbeniene
C - 10 Subst'd. benzene
C - 10 Subst'd. benzene
Figure 3. Total ion chromatogram from ambient air sample.
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Ill
CO
o
a.
«o
UJ
a:
Unk
INCREASING TIME AND TEMPERATURE
Figure 4. FID chromatogram for sample collected between 0600-.0700 on
July 27 at the Franklin Institute site.
10
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TABLE 3. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
7/26/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
13.5
(40.5)
12.8
138.
9.8
.0
.3
45.
86.
5.3
5.3
11.3
62.3
34.5
6.0
3.0
4.5
20.3
12.8
1.5
16.5
1.5
0.8
8.3
4.5
15.0
6.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methy!pentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
6.8
9.0
5.3
6.0
6.0
2.3
1.5
30.0
1.5
5.3
3.0
3.8
2.3
8.3
21.0
3.0
9.0
4.5
5.3
4.5
9.0
4.5
9.8
4.5
9.8
2.3
2.3
2.3
1.5
2,3-Dimethy! pentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye 1ohexane
2 ;4-D1methyl hexane
2,3,4-Trimethylpentane
Toluene
2,3-Dimethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Trimethyl benzene
1,2,3-Tr1methylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefin
i Aromatic
z Paraffin
Acetylene
ppbC %
46
137
513
13
709
6
19
72
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species ,
ppbC
109
818
--- Less than 0.5 ppbC
11
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combustors attached to the exhaust lines from their chemiluminescent ozone
monitors. At the Industrial monitoring site the exhaust and sample inlet
lines were fairly close together and as a result ethylene contamination
problems were greatest there. An average ethylene/acetyfene ratio of 1.3
was calculated from roving and aircraft samples that were not tainted with
ethylene. The corresponding ratios at the Franklin Institute and Industrial
sites were 9.0 and 39.5, respectively. Hence, average ethylene concentrations
determined at the two ground monitoring stations exceeded the true value by
factors of about 7 and 30.
Appendicies A-H contain a tabulation of hydrocarbon data for all samples
collected in the Philadelphia area during the summer 1979 intensive sampling
period. Information similar to that contained in Table 3 is provided for
each site on all sampling days. In order to summarize hydrocarbon data con-
tained in the Appendices, a series of tables have been prepared which illus-
trate notable features.
Table 4 lists the nonmethane hydrocarbon totals measured at the two
primary ground sites. Concentrations varied between about 0.2 and 1.7
ppmC with highest levels generally recorded at the Franklin Institute site.
Average concentrations in the 0600-0700 and 0800-0900 samples at the In-
dustrial site were nearly identical (604 vs 592 ppbC) while at Franklin
Institue the 0800-0900 samples averaged 20% higher than those collected
during the earlier period (836 vs 642 ppbC). For the most part, hydrocarbon
concentrations trends were similar at the two sites.
A listing of the hydrocarbon compositional breakdown at the two
Philadelphia sites is provided in Table 5. Olefins generally comprised
less than 10% of the total, aromatics about 25% and paraffins between 60
and 70%. As can be seen in Table 5, the average olefinic, aromatic and
paraffinic content at the two sites was nearly identical.
Tables 6 and 7 give average concentrations for the most abundant hy-
drocarbons. Standard deviations included in these two tables indicate that
individual hydrocarbon concentrations varied considerably from day to day.
In most cases the standard deviation is about the same as the mean. Table
7 also lists average individual hydrocarbon concentration measured in four
one-hour integrated samples collected during the afternoon hours at the
Industrial site. Afternoon levels were generally about a factor of two
lower than those recorded during the morning hours.
12
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Hydrocarbon data obtained from samples collected aloft are contained
in Appendix F. Since we know little about conditions under which these
samples were collected, it is difficult to provide much meaningful infor-
mation. However, it does appear 'possible to categorize the airborne hydro-
carbon data into three groups as shown in Table 8. Concentrations in samples
collected above the early morning surface inversion averaged 45 ppbC. This
compares to 233 ppbC for samples collected below the surface inversion.
These measurements were made in the early morning hours at a point upwind
of Philadelphia shortly after breakup of the morning inversion averaged 361
ppbC. Thus average hydrocarbon concentrations measured in airborne samples
were considerably below those measured at ground level.
A secondary goal of this research program was to compare ambient hydrocar-
bon levels as determined by summing individual species with non-methane hydro-
carbon data obtained from a total hydrocarbon analysis. The number of inter-
comparison samples was small and therefore a quantitative relationship between
the two methods was not established; however, as illustrated in Table 9, the
results from the two analysis techniques were in fairly good agreement for
samples collected during the morning hours on 8/17/79. However, there is a
big difference between the Beckman data dn individual hydrocarbon summation
in samples obtained during the afternoon at the Lamberton, NJ site. It appears
that the Lamberton bags which were returned to the field laboratory for de-
tailed hydrocarbon analysis were contaminated by gasoline fumes.
In summary, the primary objective of this research program was to obtain
ambient hydrocarbon data in the Philadelphia area that could be used in a
photochemical modeling effort. This goal was achieved by monitoring hydro-
carbon levels and identifying individual species in samples collected between
July 15 and August 15, 1979.
13
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Table 4. Nonmethane Hydrocarbon Concentrations (ppbC) obtained by Summing
the Individual Species j=
Date
7/17
18
19
20
23
24
25
26
27
30
31
8/1
2
3
4
5
6
7
8
9
19
14
15
16
AVE.
Frankling Institute
0600-0700 0800-0900
670
411
575
1219
377
1732
910
980
214
268
483
764
266
407
899
205
227
__-
—
—
930
1023
284
—
642
1051
639
756
831
975
1401
885
818
405
622
794
1206
546
1160
996
246
614
949
—
—
Ill
1409
476
—
836
Industrial
0600-0700 0800-0900
1511.
520
448
575
575
1710
493
1139
• ---
361
424
345
226
539
307
290
550
272
878
418
744
367
588
—
604
809
'629
558
_-_
1048
1047
988
572
666
383
511
975
278
700
532
255
691
369
507
452
308
419
316
—
592
Ethylene not included
14
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Table 5. Percentage Olefins, Aromatics and Paraffins in Surface Samples
Collected at Philadelphia.
Date
Franklin Institute
0600-0700 0800-0900
0 A P 0 A P
Industrial
0600-0700 0800-0900
0 A P 0 A P
7/17
18
19
20
23
24
25
26
27
30
31
8/1
2
3
4
5
6
7
8
9
10
14
15
16
12
2
2
8
5
2
17
5
2
1
2
6
4
3
3
5
3
—
--
--
6
4
4
—
28
27
26
11
31
6
16
11
32
31
35
17
23
24
45
26
29
--
--
--
14
34
40
—
60
69
71
30
63
91
66
84
65
67
59
76
69
72
52
66
67
—
--
--
80
63
54
—
6
14
6
5
7
6
6
6
5
3
5
5
6
5
5
2
9
6
--
__
5
6
7
--
20
28
30
30
23
14
19
19
26
30
27
15
25
24
26
29
25
32
--
_-
16
27
31
—
72
54
61
51
67
80
74
72
65
64
65
79
67
68
68
67
67
60
--
--
77
66
59
--
5
6
5
4
9
9
7
8
--
2
7
8
2
5
6
3
7
4
5
5
3
18
5
--
13
26
32
34
27
20
25
36
--
35
32
18
31
23
19
27
21
27
10
31
49
12
20
--
79
68
60
61
61
71
66
55
--
60
58
72
65
69
73
68
71
66
84
61
48
69
73
--
4
9
9
—
7
8
4
10
4
5
5
10
5
5
15
2
8
5
6
7
9
7
4
--
24
24
24
__
20
21
15
31
50
32
30
14
28
26
16
30
23
27
15
24
25
14
21
--
69
63
63
_-
73
69
81
58
43
59
62
75
65
66
67
63
65
66
77
66
66
78
72
—
AVE.
5 25 69
6 25 67
6 26 66
7 24 67
15
-------
Table 6. Average Concentration (ppbC) of Selected Hydrocarbons at the Franklin
Institute Site
Franklin
0600-0700
N=20
Ethane
Acetylene
Propane
Propene
i -Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
i -Pentane
n-Pentane
Cyclopentane
2 , 3-Di methyl butane
2 -Methyl pentane
3-Methyl pentane
n-Hexane
Methyl cycl opentane
Benzene
2, 3-Dimethyl pentane
3-Methyl hexane
n -Heptane
Methyl cycl ohexane
Toluene
2-Methyl heptane
3-Ethyl hexane
n-Octane
Ethyl benzene
p & m-Xylene
o-Xylene
o-Ethyl toluene
1 , 2, 4-Trimethyl benzene
14.5 ±
5.5 ±
51.0 ±
11.0 ±
38.0 ±
82.5 ±
3.0 ±
3.0 ±
2. 5 ±
51.0 ±
31.0 ±
3.0 ±
4.0 *
15.0 ±
10.5 *
16.0 *
6. 5 ±
8.0 ±
6.0 *
8.0 ±
6.0 *
12. 5 ±
28. 0±
3.5*
3.0±
3.5*
7.0±
21. 0±
8. 5±
6.0 ±
9.0±
9.0
3.5
63.0
12.5
50.0
112.0
4.0
3.5
3.5
48.0
23.5
2.0
2.0
9.0
5.5
10.0
4.0
6.5
3.5
6.0
3.0
16.0
10.0
2.5
1.5
1.5
6.0
20.0
6.0
3.0
4.5
Frankl i n
0800-0900
N=21
15.5
13.5
62. 0
12.0
34.0
74.0
4.0
5.0
4.5
67.0
39.5
3.5
6.0
25.0
16.0
23.0
10.0
17.0
9.5
11.0
8.5
8.0
40.0
6.0
4.5
4.5
9.5
28.5
11.0
12.0
10.5
±8.5
±6.5
±67.5
± 5.0
± 22.5
±46.5
±2.5
±3.0
±3.0
±30.0
±13.5
± 1.0
±2.0
±8.0
±5.5
±10.0
±4.0
±5.0
±3.5
± 4.0
±2.5
±3.5
±13.5
±2.5
±2.0
±1.5
±3.0
±11.0
±3.5
±3.0
±5.5
16
-------
Table 7. Average Concentration (ppbC) of Selected Hydrocarbons at the
Industrial site.
Ethane
Acetyl ene
Propane
Propene
i -Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
i-Pentane
n-Pentane
Cyclopentane
2, 3-Dimethyl butane
2-Methyl pentane
3-Methyl pentane
n-Hexane
Methyl cycl opentane
Benzene
2, 3-Dimethyl pentane
3-Methyl hexane
n-Heptane
Methyl cycl ohexane
Tol uene
2-Methyl heptane
3-Ethyl hexane
n-Octane
Ethyl benzene
p & m-Xylene
o-Xylene
o-Ethyl toluene
1 , 2, 4-Tri methyl benzene
Industrial
0600-0700
N=22
13.0 ± 7.0
7.5 ±5.5
28.0 ± 19.0
14.0 ± 13.0
19.5 ± 15.0
47.0 ± 30.5
2. 5 ± 2.5
3.0 ± 3.0
2.0 ± 3.0
41.5 ± 30.5
26.5 ± 13.5
2.5 ± 2.5
4. 5 ± 4.0
18.5 ± 20.5
12.5 ± 13.5
17.0 ± 11.5
8.0 ± 10.0
27.5 ± 45.0
9. 5 ± 11.5
12.0 ± 16.5
8.0 ± 8.5
19.5 ± 49.5
32.5 ± 23.5
4.0 ± 3.5
3.0 ± 3.0
3.5 ± 3.5
5.0 ± 2.0
13.0 ± 5.0
6.5 ± 3.5
7.5 ± 4.5
9.0 ± 5.5
Industrial
0800-0900
N=24
14.5 ± 10.0
10.5 ± 5.0
36.0 ± 32.5
14.5 ± 12.0
22.5 ± 14.0
52.0 ± 35.0
3.0 ± 2.5
4.0 ± 6.0
2.5 ± 2.5
41.5 ± 22.5
25.0 ±9.5
2.5 ± 1.0
4.5 ± 3.0
14.5 ± 9.0
10.5 ±6.0
15.5 ± 8.0
6.5 ± 4.5
15.5 ± 10.0
6.5 ± 3.5
8.0 ± 4.5
6.0 ± 3.0
8.5 ± 10.0
28.5 ± 13.0
3.5 ± 1.5
3.0 ± 1.0
3.5 ± 2.0
5.0 ± 2.0
13.5 ± 5.5
6.5 ± 2.0
7.5 ± 6.0
10.0 ±6.0
Industrial
1400-1500
N=4
12.0 ±4.5
5.0 ± 1.0
18.5 ±9.0
5.5 ±1.0
12.5 ±2.0
34.5 ± 11.0
1.5 ±2.0
3.0 ±2.5
.5 ± 1.0
23.5 ± 6.0
19.5 ±6.0
1.5 ±0.5
2.0 ±0.5
8.0 ±1.0
5.5 ±1.0
9.0 ± 1.5
3.0 ±0.5
7.5 ± 1.0
3.0 ±0.5
3.5 ±0.5
3.0 ±0.5
3.5 ±1.5
14.5 ±2.0
2.5 ±0.5
1.5 ±0.5
2.0 ±0.5
3.0 ± 1.0
7.5 ±3.0
4.0 ±1.5
4.6 ±1.5
9.0 ±5.5
17
-------
Table 8. Summary of Nonmethane Hydrocarbon Concentration (ppbC) in Samples
Collected with the EPA-LV Helicopter
Date
7/23
7/5
8/4
8/5
8/6
8/7
8/10
8/14
8/15
8/16
AVE.
NMHC above NMHC below
surface inversion surface inversion
in early morning in early morning
117
29 144
— —
58 447
160
37
99
299
— —
21
45 233
NMHC in mixed layer
over Phil ade-T ph i a
during late morning
___
504
382
331
430
332
305
203
875
702
450
473
138
46
56
184
361
18
-------
Table 9. Comparison of Concentration Data Obtained From an Individual and
Total Hydrocarbon Analysis.
Summation of
Individual Hydrocarbons Beckman 6800
Site Date - Time (ppbC) (ppbC)
Lumberton, NJ
8/17 - 1300 1.121
8/17 - 1400 .544
Downingtown, PA
8/17 - 0800 .143 .1
8/17 - 0900 .146 .1
8/17 - 1000 .261 .1
19
-------
REFERENCES
1. Westberg, H.H., R.A. Rasmussen and M.W. Holdren. Gas Chromatographic
Analysis of Ambient Air for Light Hydrocarbons Using a Chemically Bonded
Stationare Phase. Analytical Chemistry, 46(12): 1852, 1974
2. Atmospheric Air Monitoring Cross Reference Service, Scott Environmental
Technology, Inc., Report No. 2, October, 1979
-------
APPENDIX A
Individual Hydrocarbon Concentrations in 0600-0700
Franklin Institute Samples
21
-------
'TABLE Al. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
7/17/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
6.0
(196.)
11.5
17.0
8.0
17.0
41.5
12.5
10.0
4.5
44.0
32.5
2.5
4.5
20.0
13.5
6.0
23.5
8.0
2.0
12.0
6.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
7.5 2,3-Dimethylpentane
8.0 3-Methylhexane
5.0 2,2,3-Trlmethylpentane
6.0 n-Heptane
5.0 Methylcyclohexane
2.5 2,4-Dimethylhexane
1.0 2,3,4-Trlmethylpentane
50.0 Toluene
2.0 2,3-Dimethylhexane
4.5 2-Methyl heptane
3.0 3-Ethylhexane
3.5 n-Octane
2.0 Ethylcyclohexane
7.0 Ethyl benzene
18.0 pa m-Xylene
3.0 Styrene
8.0 o-Xylene
5.5 n-Nonane
1.0 i-Propylbenzene
n-Propylbenzene
3.5 p-Ethyl toluene
3.0 m-Ethyltoluene
8.0 o-Ethyltoluene
8.5 1,3,5-Trimethylbenzene
10.0 1,2,4-Trimethylbenzene
3.0 1,2,3-Trimethylbenzene
1.5 Methylstyrene
1,3-Diethyl benzene
1,4-Diethyl benzene
Total Identified
Hydrocarbons
z Olefin
£ Aromatic
i Paraffin
Acetylene
ppbC %
46
132
288
12
478
10
28
60
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
190
670
22
-------
TABLE A2. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
7/18/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.0
(93.5)
8.5
19.0
5.6
14.0
37.5
26.5
17.5
2.0
3.5
12.0
7.0
11.0
5.0
3.5
8.0
5.5
Ettiane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-Dtmethylpentane
Benzene
Cyclohexane
4.5 2,3-Dimethylpentane
5.0 3-Methylhexane
3.8 2,2,3-Trimethylpentane
4.0 n-Heptane
4.5 Methyl cyclohexane
2.0 2,4-Dlmethylhexane
2,3,4-Tr1methylpentane
17.5 Toluene
1.5 2,3-Dimethylhexane
2.5 2-Methyl heptane
3.0 3-Ethylhexane
4.0 n-Octane
Ethylcyclohexane
6.0 Ethyl benzene
16.0 p 4 m-Xylene
2-° Styrene
6 • 0 o-Xyl ene
3.0 n-Nonane
1-Propylbenzene
n-Propylbenzene
5.0 p-Ethyl toluene
m-Ethyltoluene
5.5 o-Ethyltoluene
7-° 1,3,5-Trlmethylbenzene
4-5 1,2,4-Trlmethy1 benzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-D1ethyl benzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
i Olefln
I Aromatic
z Paraffin
Acetylene
ppbC %
7
81
209
9
305
2
27
69
3
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species ;
ppbC
106
441
23
-------
TABLE A3. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
7/19/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.0
(8.0)
8.0
10.5
5.0
12.0
22.5
24.5
14.5
2.0
3.5
13.0
8.0
11.5
5.5
6.0
10.5
14.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methyl pentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
16 0 2,3-Dimethylpentane
26 o 3-Methylhexane
10 o 2,2,3-Trimethylpentane
lO.'o n-Heptane
70.0 Methylcyclohexane
85 2,4-Dimethylhexane
l'o 2,3,4-Trimethylpentane
38 io Toluene
2.5 2,3-Dimethylhexane
5 .'5 2-Methylheptane
4^0 3-Ethylhexane
2.5 n-Octane
Ethylcyclohexane
6.5 Ethyl benzene
18.0 P * m-Xylene
2.5 Styrene
7.0 o-Xylene
3.5 n-Nonane
1.5 i-Propylbenzene
4.5 n-Propylbenzene
3.5 p-Ethyltoluene
3.5 m-Ethyltoluene
6.5 o-Ethyltoluene
4.5 1,3,5-Tr1methylbenzene
8.5 1,2,4-Trimethylbenzene
2.5 1,2,3-Trimethylbenzene
Methyl styrene
1.5 1,3-Diethylbenzene
2.0 1,4-DIethyl benzene
Total Identified
Hydrocarbons
i Olefin
E Aromatic
z Paraffin
Acetylene
ppbC ^
*i 2
26
71
119
326
8
460
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species :
ppbC
115
575
24
-------
TABLE A4. HYDROCARBON CONCENTRATIONS IN: 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
7/20/79
ppbC
Hydrocarbon
ppbG
Hydrocarbon-
3.5
(2.5)
8.5
71.5
34.5
130
240
12.0
9.0
11.0
159
68
1.0
6.0
7.5
30.5
19.0
27.5
1.5
1.0
13.5
7.0
13.0
10.0
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
CycTopentane
2,3-tflmethylbutane
2-Methylpentane
c-4-MethyT-2-pentene
S-MethyTpentane'
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyelohexane
10.5
14.0
9.5
11.0
21.0
4.0
.5
,5
1.
38.
2.5
3.5
4.5
5.0
2.0
8.0
21.0
3.0
8.0
4.0
2.0
2.5
3.5
4.0
8.5
6.0
7.5
2.5
1.5
2,3-D>1 methyl pentane
3-Methylhexane
2,2,3-Trimethyl pentane:
n-Heptane
Me thyleye1ohexane
2,4»-B1methyThexane
2,3,4~Tr1methyipenta
-------
TABLE A5. HYDROCARBON CONCENTRATIONS.IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
7/23/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.5
(49.5)
4.5
24.0
5.5
12.5
26.0
2.0
2.0
2.0
23.0
14.0
1.5
3.0
11.5
8.0
14.0
6.0
3.0
7.5
5.5
Ethane
Ethylene
Acetylene
Propane
Propene
•{-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
4,0 2,3-Dimethylpentane
4.5 3-Methylhexane
3^5 2,2,3-Trimethylpentane
3.5 n-Heptane
3.5 Methylcyclohexane
1.5 2,4-Dimethylhexane
2,3,4-Trlmethylpentane
22.5 Toluene
1.0 2,3-Dimethylhexane
2.5 2-Methylheptane
1.5 3-Ethylhexane
2.0 n-Octane
Ethylcyclohexane
5.5 Ethyl benzene
14.5 p 4 m-Xylene
2.0 Styrene
5.5 o-Xylene
5.5 n-Nonane
1.5 i-Propylbenzene
4.5 n-Propylbenzene
3.0 p-Ethyltoluene
3.0 m-Ethyltoluene
7.0 o-Ethyltoluene
3.5 1,3,5-Trlmethylbenzene
12.0 1,2,4-Trimethylbenzene
2.5 1,2,3-Trlmethylbenzene
1.0 Methyl styrene
1.0 1,3-DIethyl benzene
1.0 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefln
i Aromatic
i Paraffin
Acetylene
ppbC
14
94
193
5
307
5
31
63
2
Total Unidentified
Hydrocarbons
Total NMHC by
sunning individual
species j
ppbC
70
377
-------
TABLE A6. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
7/24/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
30.5
(20.0)
250
16.0
199
472
2.
7.
.0
.0
6.5
177
100
6.0
1.0
7.0
7.5
35.5
22.0
31.0
1.5
1.0
14.5
4.5
13.5
11.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyctopentene
Cyclopentane
2,3-Dfmethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-MethyTpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
10.5
15'0
6 ."5
12.0
24 1 o
3 ' 5
1*0
28 '. 0
2^0
5 ' 0
4. '5
6.5
2.5
5.5
15.0
3 . 0
7 . 5
5.0
1.5
3.5
3.0
2.5
6.0
2.5
5
5
5
.0
2, 3-D i methyl pentane
3-Methylhexane
2,2,3-Trlmethylpentane
n -Heptane
Methyl eye 1 ohexane
2,4 -01 methyl hexa ne*
2,3,4-Trlmethylpentane
1.0
2,3-Dlmethylhexane
2 -Methyl heptane
3-Ethylhexane
n-Octane
Ethyl cyclohexane
Ethyl benzene
P * m-Xylene
Sty rene
o-Xyl ene
n-Nonane
1 -Propyl benzene
n-Propyl benzene
p-Ethyl toluene
m-Ethyl toluene
o-Ethyl to! uene
1, 3, 5-Trtmethyl benzene
1, 2, 4-Trimethyl benzene
1, 2, 3-Trimethyl benzene
Methyl sty rene
1,3-01 ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
i Paraffin
Acetylene
ppbC
38
104
1462
1604
2
6
91
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species ,
ppbC
128
1732
27
-------
TABLE A7. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
7/25/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
20.0
(58.0)
8.5
62.0
51.5
40.0
121
3.5
2.5
3.0
71.5
36.0
3.5
5.0
6.5
25.0
17.0
26.0
1.5
1.0
12.0
5.0
20.0
9.5
Ethane
Ethyl ene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
9.5
13.5
11.5
9.0
27.0
5.0
3.0
36.0
3.0
8.5
5.0
5.0
2.5
7.0
21.5
3.5
9.0
3.5
9.0
4.5
1.5
4.5
9.0
4.0
9.0
1.5
2.0
i.5
1.5
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methylcyclohexane
2,4-D1methy1hexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Trimethyl benzene
1,2,3-Trlmethylbenzene
Methylstyrene
1,3-01ethylbenzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
E Paraffin
Acetylene
ppbC
131
125
514
9
778
17
16
66
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
PPbC
132
910
28
-------
TABLE A8. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
7/26/79
ppbC
24.5
(33.0)
4.5
135.
15.5
92.5
19 2-.
5.5
5.5
7.5
—
109.
51.5
4.5
—
—
5.0
6.0
23.0
—
13.5
—
18.5
—
—
9.0
4.0
10.0
6.0
Hydrocarbon
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
i -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i -Pentane
n -Pentane
1-Pentene
t-2'-Pentene
c-2'-Pentene
Cyclopentene
Cycl'Opentane
2',,3-Dimethy/l butane
2--Methy/l pentane
c-4-Methy^l -2'-pentene
3-Me thy/I pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2 ,4-Dime thy! pentane
Benzene
Cyclohexane
ppbC Hydrocarbon
6.0 2, 3-Oimethyl pentane
8.0 3-Methyl hexane
8.0 2, 2,3-Trimethyl pentane
7.5 n -Heptane
8.0 Me thy 1 eye 1 ohexa ne
2.5 2 , 4-0 i methyl hexane
2.0 2 ,3 ,4-Trimethyl pentane
26.5 Toluene
2.0 2, 3-Dimethyl hexane
3.5 2 -Methyl heptane
3.5 3-Ethyl hexane
5.0 n -Octane
2.0 Ethyl cyclohexane
6-0 Ethyl benzene
15.0 pi m-Xylene
2 . 5 Styrene
6.0 o-Xylene
5.0 n-Nonane
2.0 j -Propyl benzene
— n-Propyl benzene
3 . 5 p- Ethyl tol uene
1 • 5 m-Ethyl toluene
6 . 0 o-Ethyltol uene
2.5 1, 3, 5-Tr imethy 1 benzene
9.0 1,2, 4-Tr imethy 1 benze ne
1.5 l ,2 ,3-Trimethyl benzene
1 • 0 Methyl styrene
1.5 i , 3-D1 ethyl benzene
1.5 i ,4-Di ethyl benzene
Total Identified
Hydrocarbons
z Olefin
i Aromatic
z Paraffin
Acetylene
ppbC %
41 5
94 11
752 84
5 1
892-
ppbC
Total Unidentified 88
Hydrocarbons
Total NMHC by 980
summing individual
species i
-------
TABLE A9. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
7/27/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
7.5
(26.0)
3.0
8.0
2.0
5.5
12.0
12.0
10.0
1.0
1.5
6.0
4.0
7.5
2.5
2.0
4.5
4.5
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-Dimethylpentane
Benzene
Cyclohexane
3.0 2,3-Dimethylpentane
4.0 3-Methylhexane
2.5 2,2,3-Trimethylpentane
3.0 n-Heptane
11.0 Methyl eyelohexane
1.5 2,4-Dimethylhexane
2,3,4-Trlmethylpentane
26.0 Toluene
1.5 2,3-Dimethylhexane
1.5 2-Methylheptane
2.5 3-Etnylhexane
2.5 n-Octane
Ethyl eyelohexane
3.5 Ethyl benzene
9.0 p & m-Xylene
1.5 Styrene
3.5 o-Xylene
2.0 n-Nonane
i-Propylbenzene
n-Propylbenzene
2.5 p-Ethyl toluene
1.0 m-Ethyltoluene
3.0 o-Ethyltoluene
1,3,5-Trimethylbenzene
4.0 1,2,4-Trlmethylbenzene
1,2,3-Trfmethylbenzene
Methylstyrene
1,3-Diethylbenzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefin
i Aromatic
r Paraffin
Acetylene
ppbC
3
58
119
3
TS4"
2
32
65
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
30
214
30
-------
TABLE A10. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
7/30/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.5
(9.5)
7.0
7.5
3.0
8.5'
20.5
20.0
13.0
1.5
2.0
8.5
6.0
9.0
3.5
3.5
6.0
5.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-MethyTpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
3.5 2,3-Dimethylpentane
4 ".5 3-Methylhexane
3.'5 2,2,3-Trimethylpentane
3.0 n-Heptane
8.0 Methyl eye1ohexane
2.0 2,4-Dlmethylhexane
2,3,4-Trlmethylpentane
21.0 Toluene
1.0 2,3-Dimethylhexane
3.0 2-Methylheptane
2.0 3-Ethylhexane
1.5 n-Octane
Ethyleye1ohexane
4.5 Ethyl benzene
13.0 p & m-Xylene
1.0 Styrene
4.5 o-Xylene
2.0 n-Nonane
i-Propylbenzene
2.5 n-Propylbenzene
2.5 p-Ethyltoluene
2.0 m-Ethyltoluene
5.5 o-Ethyltoluene
1.5 1,3,5-Trimethyl benzene
5.0 1,2,4-Trimethylbenzene
1.5 1,2,3-Trimethylbenzene
Methyls tyrene
1,3-Diethyl benzene
1,4-Diethyl benzene
Total Identified
Hydrocarbons
z Olefin
£ Aromatic
i Paraffin
Acetylene
ppbC %
3
70
151 •
__3
227
1
31
67
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species .
ppbC
39
268
-------
TABLE All. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
7/31/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
19.0
(65.0)
12.5
34.0
6.0
13.5
32.0
27.0
19.5
2.0
2.5
10.0
6.5
10.0
4.5
4.5
23.0
6.5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
4.0 2,3-Dimethylpentane
7.5 3-Methylhexane
4.0 2,2,3-Trimethylpentane
5.0 n-Heptane
5.5 Methylcyclohexane
2.5 2,4-Dimethylhexane
2,3,4-Trlmethylpentane
39.5 Toluene
1.0 2,3-Dimethylhexane
1.5 2-Methyl heptane
2.0 3-Ethylhexane
2.5 n-Octane
Ethylcyclohexane
8-0 Ethyl benzene
25.5 p 4 m-Xylene
2.5 Styrene
8.5 o-Xylene
3.0 n-Nonane
6.5 1-Propy1 benzene
2.5 n-Propylbenzene
2.5 p-Ethyltoluene
2.5 m-Ethyltoluene
6.0 o-Ethyltoluene
3.0 1,3,5-Trlmethylbenzene
8.0 1,2,4-Trimethylbenzene
1.5 1,2,3-Trimethylbenzene
1,0 Methylstyrene
1.5 1,3-Diethyl benzene
1.0 1,4-01ethyl benzene
Total Identified
Hydrocarbons
i Olefin
i Aromatic
z Paraffin
Acetylene
ppbC ^
9
139
231
13
392
2
35
59
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species !
ppbC
91
483
32
-------
TABLE A12. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
8/1/79
ppbC
Hydrocarbon
Total Identified
Hydrocarbons
z Olefin
i Aromatic
z Paraffin
Acetylene
ppbC %
40
115
507
5
666
6
17
76
1
ppbC
Hydrocarbon
21.5
(457.)
5.0
76.5
13.5
57.5
110.
6.5
8.5
6.0
—
64.0
34.5
5.5
—
—
—
3.0
4.5
16.5
—
11.5
—
15.5
0.5
1.5
7.5
3.5
11.0
7.0
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1 -Butane
n-Butane
1 -Butene
1-Butene
t-2-Butene
c-2-Butene
1 -Pentane
n-Pentane
1 -Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cycl opentane
2, 3-D1methyl butane
2-Methyl pentane
c-4-Methyl -2-pentene
3-Methyl pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye 1 opentane
2, 4-Dimethyl pentane
Benzene
Cyclohexane
6.5
8.5
5.5
5.5
21.5
3.5
1.0
33.0
1.5
2.5
3.5
3.5
—
6.0
18.5
2.0
6.0
4.5
7.0
3.5
6.0
—
6.0
3.5
11.5
1.0
1.0
1.5
1.0
2 ,3-Dimethyl pentane
3-Methylhexane
2 ,2 ,3-Trimethyl pentane
n-Heptane
Methyl eye lohexane
2 , 4-Dimethyl hexane
2,3,4-Trlmethylpentane
Toluene
2, 3-Dime thy 1 hexane
2-Methyl heptane
3-Ethyl hexane
n -Octane
Ethyl eye lohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xyl ene
n-Nonane
i-Propyl benzene
n-Propyl benzene
p- Ethyl toluene
m-Ethyl tol uene
o-Ethyl tol uene
1 ,3 ,5-Trimethyl benzene
1,2,4-Trimethylbenzene
1, 2, 3-Trimethyl benzene
Methyl styrene
1 ,3-D1 ethyl benzene
1 ,4-01 ethyl benzene
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species. !
ppbC
98
764
33
-------
TABLE A13. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
8/2/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
10.5
(70.0)
8.5
9.0
15.0
31.5
23.0
15.0
4.0
2.0
6.5
4.5
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
3.5 2,3-Dimethylpentane
4.5 3-Methylhexane
2.0 2,2,3-Trimethyl pentane
4.0 n-Heptane
5.0 Methylcyclohexane
2.0 2,4-Dimethylhexane
2,3,4-Trimethylpentane
15.0 Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
1.5 n-Octane
Ethylcyclohexane
3.5 Ethyl benzene
8.5 pi m-Xylene
Styrene
3.0 o-Xylene
1-5 n-Nonane
i-Propylbenzene
1-5 n-Propylbenzene
2-0 p-Ethyltoluene
1-5 m-Ethyltoluene
o-Ethyltoluene
3-5 1,3,5-Trimethylbenzene
5.0 1,2,4-Trimethylbenzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-Diethyl benzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
£ Paraffin
Acetylene
ppbC j>
9
50
151
9
218
4
23
69
4
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species ;
ppbC
48
266
34
-------
TABLE A14. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
8/3/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
13.0
(67.0)
7.0
23.0
6.5
16.0
34.0
—
—
—
32.0
40.0
—
—
—
—
2.0
2.5
11.5
—
7.5
—
15.5
—
—
4.5
3.0
10.0
5.0
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
i -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1 -Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2, 3 -Dimethyl butane
2-Methylpentane
c-4-Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye 1 open tane
2 ,4-Dimethyl pentane
Benzene
Cyclohexane
4.5
5.0
3.5
4.0
3.5
2.5
—
27.5
2.0
4.0
5.5
4.0
2.0
5.0
12.0
2.0
6.0
2.0
—
1.5
2.5
2.5
6.0
.1.0
5.0
1.5
1.0
1.5
1.5
2 ,3-Dimethyl pentane
3-Methyl hexane
2,2 ,3-Trime thyl pentane
n -Hep tane
Methyl eye 1 ohexane
2 ,4 -Dime thyl hexane
2 ,3 ,4-Tr1methyl pentane
Toluene
2, 3-Dlme thyl hexane
2-Me thyl heptane
3-Ethyl hexane
n -Octane
Ethyl eye 1 ohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propyl benzene
n-Propyl benzene
p-Ethyl toluene
m-Ethyl tol uene
o-Ethyl toluene
1, 3, 5-Trlme thyl benzene
1, 2, 4-Trime thyl benzene
1,2,3-Trimethylbenzene
Me thyl styrene
1, 3 -Di ethyl benzene
1 ,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefin
i Aromatic
i Paraffin
Acetylene
ppbC
10
83
251
7
351
3
24
72
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species- ;
ppbC
55
407
35
-------
TABLE A15. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
8/4/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
15.0
(54.0)
25.5
3.8
22.5
18.8
39.8
35.3
2.3
4.5
17.3
12.0
16.5
6.8
3.0
12.8
6.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
6.8
7.5
6.0
6.0
6.8
3.0
33.0
8.3
5.3
4.5
2.3
15.8
59.3
5.3
.3
,5
14.
10.
3.0
12.8
5.3
6.8
14.3
12.8
23.3
9.0
9.0
20.3
9.0
2,3-D1methylpentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methylcyclohexane
2,4-Dimethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-D1ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefin
i Aromatic
i Paraffin
Acetylene
ppbC %
18
252
292
562"
3
45
52
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species :
ppbC
337
899
-------
TABLE A16. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
8/5/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
11.5 Ethane
(37.0) Ethyl ene
4.0 Acetylene
10.0 Propane
7.0 Propene
1.5.5 f -Butane
15.5 n-Butane
— 1-Butene
1-Butene
t-2-Butene
c-2-Butene
16.5 f-Pentane
17.0 n-Pentane
— 1-Pentene
— t-2-Pentene
c-2-Pentene
— Cyclopentene
1 - 0 Cyclopentane
2.0 2,3-Dimethylbutane
5.5 2-Methy1pentane
— c-4-Methyl-2-pentene
3.0 3-Methylpentane
1-Hexene
5.5 n-Hexane
— t-2-Hexene
— c-2-Hexene
2.0 Me thy 1 eye 1 opentane
1.0 2,4-Dimethylpentane
4.5 Benzene
2.5 Cyclohexane
2.0
2.0
3.5
2.0
2.0
1.0
13.5
1.0
2.0
2.0
2.0
3.0
10.0
1.0
3.5
1.5
1.0
1.5
1.5
3.0
2.0
4.0
1.0
2.0
1.5
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methyl-cyclohexane
2,4-Dime thy!hexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & ra-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethylto!uene
1,3,5-Trlmethylbenzene
1,2,4-Trfmethyl benzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-D1ethyl benzene
1,4-Di ethyl benzene
Total Identified
Hydrocarbons
r Olefin
E Aromatic
r Paraffin
Acetylene
ppbG
10
51
129
4
194
5
26
66
2
Total Unidentified.
Hydrocarbons
Total NMHC by
summing individual
species (
PRbC
11
205
37
-------
TABLE A17. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
8/6/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
10.5
( 52.5 )
2.0
10.0
3.0
7.0
17.0
16.0
.14.0
1.0
2.0
7.0
4.0
8.5
3.0
1.0
5.5
5.0
Ethane
Ethyl ene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-Dimethylpentane
Benzene
Cyclohexane
2.5 2,3-Dimethylpentane
3.0 3-Methylhexane
3.0 2,2,3-Trimethylpentane
2.5 n-Heptane
2.5 Methyl cyclohexane
1.5 2,4-D1methylhexane
2,3,4-Trlmethylpentane
14.0 Toluene
1.0 2,3-Dimethylhexane
3.5 2-Methyl heptane
2.5 3-Ethylhexane
2.5 n-Octane
Ethylcyclohexane
4.0 Ethyl benzene
11.5 p & m-Xylene
1.0 Styrene
3.5 o-Xylene
1.5 n-Nonane
1-Propylbenzene
1.5 n-Propylbenzene
3.0 p-Ethyl toluene
m-Ethyltoluene
3.5 o-Ethyltoluene
2.5 1,3,5-Tr1methylbenzene
4.5 1,2,4-Tr1methylbenzene
1.5 1,2,3-Trlmethylbenzene
1.0 Methylstyrene
2.5 1,3-01ethyl benzene
0.5 1,4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
£ Paraffin
Acetylene
ppbC
5
58
132
2
197
3
29
67
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species :
ppbC
30
227
38
-------
TABLE A18. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
8/10/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
39.0
(37.5)
4.5
101.
21.8
63.8
121.
3.0
4.5
4.5
78.8
51.8
3.8
4.5
5.3
22.5
15.0
39.8
11.3
3.8
12.0
7.5
Ethane
Ethylene
Acetylene
Propane
Propene
1- -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-.2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dtmethylpentane
Benzene
Cyclohexane
6.8
8.3
6.0
9.0
9.8
1.5
0.8
21.8
1.5
3.0
3.8
5.3
3.0
5.3
12.0
3.0
6.8
6.0
4.5
3.8
2.3
3.0
6.0
5.3
12.0
3.0
4.5
6.8
3.0
2,3-Dimethyl pentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methyl cyclotiexane
2,4-Dtraethy*! hexane
2,3,4-TrtmethyTpentane
Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethyl eyelohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
ra-Ethyltoluene
o-Ethyltoluene
1,3,5-Trimethy1 benzene
1,2,4-Trimethylbenzene
1,2,3-Tr1methylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
i Paraffin
Acetylene
ppbC
45
108
629
_5
786
6
14
80
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species ;
ppbC
144
930
39
-------
TABLE AT9. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
8/14/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
18.8
(40.5)
138.
6.8
35.3
73.5
6.0
6.8
3.0
53.3
25.5
2.3
3.8
16.5
11.3
16.5
7.5
6.8
12.8
6.0
Ethane
Ethyl ene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
3.0
7.5
6.0
6.0
6.8
2.3
1.5
38.3
2.3
3.8
5.3
6.8
2.3
28.5
90.0
5.3
27.8
2.3
0.8
6.0
10.5
3.0
4.5
15.8
14.3
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Tr1methyl pentane
n-Heptane
Methylcyclohexane
2,4-Dimethylhexane
2,3,4-Tr1methylpentane
Toluene
2,3-Dimethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Tr1methylbenzene
1,2,4-Trimethylbenzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
i Paraffin
Acetylene
ppbC ^
27
252
471
751
4
34
63
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species .
ppbC
272
1023
40
-------
TABLE A20. HYDROCARBON CONCENTRATIONS IN 0600-0700 FRANKLIN INSTITUTE SAMPLE ON
8/15/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
6.8
(26.3)
3.0
5.3
1.5
4.5
12.0
11.3
9.0
0.8
3.8
2.3
3.8
1.5
1.5
3.0
3.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
1.5 2,3-Dimethy!pentane
1.5 3-Methylhexane
2.3 2,2,3-Trimethylpentane
1^5 n-Heptane
2.3 Methyl eye1ohexane ,
2,4-Dimethylhexane
2,3,4-Trimethylpentane
9.8 Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
1.5 n-Octane
Ethyl eye1ohexane
3.8 Ethyl benzene
12.0 p & m-Xylene
0.8 Styrene
4.5 o-Xylene
2.3 n-Nonane
i-Propylbenzene
n-Propylbenzene
1.5 p-Ethyltoluene
1.5 m-Ethyltoluene
3.8 o-Ethyltoluene
9.0 i,3,5-Trimethylbenzene
6.8 1,2,4-Trimethy1 benzene
1.5 1,2,3-Trimethylbenzene
Methylstyrene
1,3-Diethyl benzene
1,4-Diethyl benzene
Total Identified
Hydrocarbons
£ Olefin
z Aromatic
i Paraffin
Acetylene
ppbC
6
57
76
3
T4T
4
40
54
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species :
ppbC
143
284
-------
APPENDIX B
Individual Hydrocarbon Concentrations in 0800-0900
Franklin Institute Samples
42
-------
TABLE Bl . HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
7/17/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
11.3
(192.)
17.3
21.0
12.8
48.0
152.
6.0
1.5
6.0
9.0
129.
46.5
3.8
0.8
4.5
9.0
33.8
21.8
26.3
2.3
2.3
13.5
7.5
24.0
8.3
Ethane
Ethylene
Acetyl ene
Propane
Propene
i-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1 opentane
2,4-D1methylpentane
Benzene
Cyclohexane
13.5 2,3-D1methylpentane
15.0 3-Methylhexane
13.5 2,2,3-Trimethylpentane
9.8 n-Heptane
9.0 Methylcyclohexane
4.5 2,4-D1methylhexane
2.3 2,3,4-Trlmethylpentane
47.3 Toluene
2.3 2,3-Dimethylhexane
6.8 2-Methyl heptane
4.5 3-Ethylhexane
4.5 n-Octane
1.5 Ethylcyclohexane
9.8 Ethyl benzene
26.3 p & m-Xylene
3.8 Styrene
13.5 o-Xylene
6.0 n-Nonane
2.3 i-Propylbenzene
6.8 n-Propylbenzene
6.0 p-Ethyltoluene
5.3 m-Ethyltoluene
12.0 o-Ethyltoluene
4.5 l,3,5-Trlmethylbenzene
10.5 1,2,4-Trimethylbenzene
1,2,3-Trimethylbenzene^
5.3 Methylstyrene ^
3.0 1,3-Diethylbenzene
3.0 1,4-Diethyl benzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
z Paraffin
Acetylene
ppbC
54
174
625
17
871
6
20
72
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
180
1051
43
-------
TABLE B2. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
7/18/79
ppbC
12.0
(187.)
23.0
17.5
14.5
18.0
45.0
3.5
8.0
7.5
47.0
28.5
___
—
—
—
3.0
4.5
19.5
—
11.5
3.0
16.0
—
—
8.0
2.5
16.5
7.0
Hydrocarbon
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
i -Butane
n-Butane
1-Butene
i -Butene
t-2-Butene
c-2-Butene
i -Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyelopentane
2, 3-D1methyl butane
2-Methyl pentane
c-4-Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2 ,4-Dimethyl pentane
Benzene
Cyclohexane
ppbC Hydrocarbon
8.5 2, 3-Dimethyl pentane
9.0 3-Methyl hexane
6.0 2,2,3-Trimethylpentane
7.0 n-Heptane
6.0 Methyl cyclohexane
2.5 2 , 4-D i raethy 1 hexane?
1.5 2,3,4-Trimethylpentane
36.0 Toluene
1.5 2, 3-Dimethyl hexane
5.0 2-Methylheptane
3.5 3-Ethyl hexane
3.5 n -Octane
1.0 Ethyl cyclohexane
9.5 Ethyl benzene
27.5 p 4 m-Xylene
3.0 Styrene
10.5 o-Xylene
3.5 n-Nonane
1.5 i-Propyl benzene
3.5 n-Propylbenzene
5.0 p-Ethyl toluene
4.5 m-Ethyl toluene
12.5 o-Ethyl tol uene
6-0 1,3,5-Trimethylbenzene
3.5 1, 2, 4-Trimethyl benzene
— 1,2,3-Trimethylbenzene
2 . 5 Methyl s tyrene
1.5 1, 3 -Di ethyl benzene
1.5 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefin
x Aromatic
E Paraffin
Acetylene
ppbC %
70 14
140 28
270 54
23 5
503'
ppbC
Total Unidentified 136
Hydrocarbons
Total NMHG by 639
summing individual
species i
-------
TABLE B3. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
7/19/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
10.0
(69.0)
20.0
15.0
9.0
18.5
49.0
3.0
7.0
6.0
54.5
31.5
4.0
7.0
27.0
16.0
4.0
21.5
10.5
6.0
20.0
10.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
14.0 2,3-Dimethylpentane
16.5 3-Methylhexane
10.0 2,2,3-Tn'methylpentane
12.0 n-Heptane
18.0 Methylcyclohexane
4.0 2,4-Dimethylhexane
2,3,4-TMmethylpentane
57.5 Toluene
2.5 2,3-Dlmethylhexane
7.0 2-Methyl heptane
5.0 3-Ethylhexane
4.5 n-Octane
Ethylcyclohexane
10.5 Ethyl benzene
30.0 p & m-Xylene
4.0 Styrene
12.5 o-Xylene
4.5 n-Nonane
3.0 1-Propylbenzene
6.0 n-Propylbenzene
6.5 p-Ethyltoluene
5.5 m-Ethyltoluene
14.0 o-Ethyltoluene
3.5 1,3,5-Tr1methylbenzene
8.0 1,2,4-Trimethylbenzene
2.0 1,2,3-Trtmethylbenzene
3.0 Methylstyrene
2.5 l,3-D1ethylbenzene
1.5 1,4-01ethyl benzene
Total Identified
Hydrocarbons
E Olefin
L Aromatic
i Paraffin
Acetylene
ppbC
36
188
378
20
623
6
30
61
3
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species
ppbC
133
756
45
-------
TABLE B4. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
ppbC
Hydrocarbon
ppbC
Hydrocarbon
12.5
(solo)
17,
37.
10.
24.0
54.5
3.0
2.5
4.5
53.0
34.0
2.0
0.5
5.0
7.0
31.5
21.0
28.5
1.5
1.0
13.0
8.0
24.5
9.5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
12.5 2,3-Dimethylpentane
15.0 3-Methylhexane
8.5 2,2,3-Trimethylpentane
11.5 n-Heptane
9.5 Methyl cyclbhexane
4.0 2,4-D1methy!hexane
2.0 2,3,4-Trtmethylpentane
61.0 Toluene
3.0 2,3-Dimethylhexane
9.0 2-Methylheptane
6.0 3-Ethylhexane
6.0 n-Octane
2.0 Ethylcyclohexane
12.0 Ethylbenzene
35.0 p 4 m-Xylene
4.5 Styrene
14.0 o-Xylene
4.5 n-Nonane
6.5 i-propy!benzene
4.5 n-Propylbenzene
13.5 p-Ethyltoluene
5.0 m-Ethyltoluene
14.5 o-Ethyltoluene
5.0 1,3,5-Trimethylbenzene
9.0 1,2,4-Trimethy!benzene
1.5 1,2,3-Trimethylbenzene
2-5 Methylstyrene
1-5 1,3-Diethyl benzene
1.0 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefin
£ Aromatic
z Paraffin
Acetylene
ppbC
32
209
433
18
692
5
30
51
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species
PPbC
139
831
-------
TABLE B5. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
7/23/79
ppbC
11.3
(73.5 )
13.5
27.8
14.3
27.8
75.0
4.5
5.3
6.8
—
82.5
43.5
3.0
31.5
19.5
0.8
5.3
9.0
36.0
0.8
23.3
1.5
30.8
1.5
1.5
15.0
6.8
21.0
7.5
Hydrocarbon
Ethane
Ethyl ene
Acetylene
Propane
Propene
1 -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2 ,3-D1methyl butane
2-Methyl pentane
c-4-Methyl -2-pentene
3-Methyl pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye 1 opentane
2 ,4-Dimethyl pentane
Benzene
Cyclohexane
ppbC Hydrocarbon
13.5 2, 3-D1me thy! pentane
15.8 3-Methyl hexane
9.8 2,2,3-Trimethylpentane
10.5 n-Heptane
9.3 Methyl cyclohexane
4.5 2, 4-Dimethyl hexane
2.3 2,3,4-Trlmethylpentane
43.5 Toluene
2.3 2, 3-D1methyl hexane
7.5 2-Methyl heptane
5.3 3-Ethyl hexane
4.5 n-Octane
2.3 Ethyl cyclohexane
9-8 Ethyl benzene
29.3 p 4 m-Xylene
4 . 5 Sty rene
12.8 o-Xylene
6.8 n-Nonane
2.3 1-Propyl benzene
4.5 n-Propyl benzene
8.3 p-Ethyl toluene
6.0 m-Ethyl toluene
15.0 o-Ethyl toluene
4.5 1, 3, 5-Trlmethyl benzene
14.3 1, 2, 4-Trlmethyl benzene
3.0 1, 2, 3-Tr1methyl benzene
3.8 Methyl sty rene
3.0 1,3-Dlethyl benzene
2.3 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
r Olefin
T. Aromatic
i Paraffin
Acetylene
ppbC %
55 7
177 23
518 62
14 2
ppbC
Total Unidentified 211
Hydrocarbons
Total NMHC by 975
summing individual
cnA/»4Ae
774
47
-------
TABLE B6. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
7/24/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
36.0
(64.0)
9.0
152.
21.8
96.8
203.
6.8
6.8
8.3
3.8
113.
69.0
4.5
5.3
8.3
35.0
0.8
24.0
0.8
39.8
0.8
1.5
17.3
5.3
21.0
10.5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thy! eye 1 opentane
2,4-Dimethylpentane
Benzene
Cyclohexane
12.0 2,3-Dimethylpentane
15.8 3-Methylhexane
7.5 2,2,3-Trimethylpentane
12.0 n-Heptane
15.0 Methyl eyeliohexane
3.8 2,4-Dimethylhexane
2.3 2,3,4-Trlmethylpentane
42.0 Toluene
2.3 2,3-Dimethylhexane
5.3 2-Methy!heptane
6.0 3-Ethylhexane
6.8 n-Octane
3.8 Ethylcyclohexane
9.8 Ethyl benzene
26.3 p & m-Xylene
4.5 Styrene
12.0 o-Xylene
6.0 n-Nonane
3.0 i-Propylbenzene
2.3 n-Propylbenzene
6.0 p-Ethyl toluene
4.5 m-Ethyltoluene
11.3 o-Ethyltoluene
2.3 i,3,5-Trlmethylbenzene
10.5 1,2,4-Trimethylbenzene
2.3 1,2,3-Trimethylbenzene
3.0 Methylstyrene
2.3 1,3-Dlethylbenzene
1.5 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
E Olefin
z Aromatic
i Paraffin
Acetylene
ppbC ji
6.3
157
915
9
1144
6
14
80
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species :
ppbC
193
1337
48
-------
TABLE B7. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
7/25/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
19.5
(59.3)
7.5
128.
12.8
44.3
90.0
5.3
5.3
7.5
71.3
36.8
4.5
3.8
6.0
24.8
0.8
18.0
3.0
28.
1.
0.8
11.3
4.5
18.8
7.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
,3
.5
,5
.3
8.
10.
7.5
7.5
8.3
3.0
1.
41.
1.5
6.8
3.8
4.5
2.3
8.3
24.0
3.0
9.8
3.8
1.5
4.5
5.3
3.8
10.5
3.0
9.0
2.3
2.3
2.3
2.3
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Tn'methylpentane
n-Heptane
Methyl eye1ohexane
2,4-Dimethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methyl heptane
3-Ethy!hexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-D1ethyl benzene
1.4-D1ethyl benzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
E Paraffin
Acetylene
ppbC j!
47
147
567
8
768
6
19
74
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
PPbC
117
885
-------
TABLE B8. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
7/26/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
13.5
(40.5)
12.8
138.
9.8
45.0
86.3
5.3
5.3
11.3
62.3
34.5
6.0
3.0
4.5
20.3
12.8
1.5
16.5
1.5
0.8
8.3
4.5
15.0
6.0
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
i-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methy1pentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
6.8
9.0
5.3
6.0
6.0
2.3
1.5
30.0
1.5
5.3
3.0
3.8
2.3
8.3
21.0
3.0
9.0
4.5
5.3
4.5
9.0
4.5
9.8
4.5
9.8
2.3
2.3
2.3
1.5
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trimethyl pentane
n-Heptane
Methyl eye 1ohexane
2,4-D fmethy1hexa ne
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propy!benzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Tr1methy!benzene
1,2,4-Trimethylbenzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-Di ethyl benzene
Total Identified
Hydrocarbons
i Olefin
I Aromatic
z Paraffin
Acetylene
ppbC %
46
137
513
13
709"
6
19
72
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species ,
PPbC
109
818
50
-------
TABLE B9. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
7/27/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
7.5
(44.3)
12.0
9.0
6.8
11.3
30.8
2.3
2.3
3.0
35.3
22.5
1.5
2.3
3.8
15.8
10.5
14.3
6.0
3.8
13.5
6.8
Ethane
Ethylene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
6.8 2,3-Dimethylpentane
8.3 3-Methylhexane
5.3 2,2,3-Trlmethylpentane
6.0 n-Heptane
8.3 Methyl cyclohexane
2.3 2,4-Dimethylhexane
2,3,4-Tr1methylpentane
27.8 Toluene
1.5 2,3-Dimethylhexane
3.8 2-Methyl heptane
3.8 3-Ethylhexane
3.0 n-Octane
0.8 Ethylcyclohexane
6.0 Ethyl benzene
18.0 pi m-Xylene
2.3 Styrene
7.5 o-Xylene
2.3 n-Nonane
1-Propylbenzene
2.3 n-Propylbenzene
6.8 p-Ethyl toluene
2.5 m-Ethyltoluene
8.3 o-Ethyltoluene
1.5 1,3,5-Trlmethylbenzene
6.0 1,2,4-Trlmethylbenzene
1,2,3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefin
£ Aromatic
£ Paraffin
Acetylene
ppbC %
19
94
232
12
356
5
26
65
3
Total Unidentified
Hydrocarbons
Total NMHC by
sunning individual
species :
PpbC
49
405
51
-------
TABLE BIO. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
7/30/79
ppbC
Hydrocarbon
ppbC
Hydroearborr
9.5
(63.5)
18.5
18-. 5
9.0
18,. 0
48.5
52.0
33.5
3.5
4.5
22.5
14.5
19.5
8.5
2.5
15.0
7.5
Ethane
Ethylene
A'cetylene
Propane
Propene
1-Butane
n--Butane
T-Butene
1-Butene
t-2-Butene
o-Z-Eutene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2;-Pentene
Cyelopentene
C'yelopentane
2,.3-DrtinethyTbutane
2:-Methyl pentane
c-4-Methy1-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
MethylI cyclopentane
2,4-Dlmethyi pentane
Benzene
Cyclohexane
9.0
10.0
7.5
8.5
5.5
3.5
39.0
2.0
6.5
4.5
4.0
9,0
25.0
3.5
11.0
4.0
2.5
8.0
6.0
5.5
13.4
3.0
8.0
1.5
3.5
2.5
1.5
2,3-Dimethylpentane
3-Methylhexane
2,2% 3-Tr i me thylipentane
n-Hep/tane
Me thy Teyc T'ohexane
2,4-D1methyl*hexane
2 ,,3!, 4'-Tr line thy 1 pentane
Tolsuene
2,3-Dimethyl hexane.
2-Methy/nheptane
3-Ethy/Thexane
n-Octane
E t hyl^cye 1 o hexa ne
Ethylbenzene
p & m^Xylene
Styrene
o-XyTene
n-Nonane
1-PropyTbenzene
n-Propylbenzene
p-Ethyl toluene
m-EthyltoTuene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Trimethyl benzene
1,2,3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefln
i Aromatic
i Paraffin
Acetyl ene
ppbC
16
152
328
3
514
3
30
64
1
Total Unidentified
Hydrocarbons
Total' NMHC by
summing individual
s-peote* ;
ppbC
108
622
52
-------
TABLE BIT. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
7/31/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
15.0
(61.5)
17.0
44.0
12.0
26.0
65.0
7.0
7.5
3.5
62.0
40.0
4.0
5.5
24.5
16.0
21.0
1.5
1.0
9.5
6.5
21.0
9.0
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
11.0 2,3-Dimethyl pentane
17.0 3-Methylhexane
7.0 2,2,3-Trimethylpentane
— n-Heptane
10.0 Methylcyclohexane
4.0 2,4-Dimethylhexane
7.0 2,3,4-Trlmethylpentane
61.0 Toluene
2.5 2,3-Dimethyl hexane
6.5 2-Methylheptane
4.5 3-Ethylhexane
4.0 n-Octane
I-5 Ethylcyclohexane
11.0 Ethyl benzene
33.0 p 4 m-Xylene
4.0 Styrene
13.0 o-Xylene
4.5 n-Nonane
4.0 i-Propylbenzene
4.0 n-Propylbenzene
11.5 p-Ethyltoluene
m-Ethyltoluene
14.5 o-Ethyltoluene
4.0 1,3,5-Trlmethylbenzene
8.5 1,2,4-Trimethylbenzene
2.0 1,2,3-Trimethyl benzene
Methylstyrene
1,3-Diethylbenzene
1,4-DIethyl benzene
Total Identified
Hydrocarbons
z Olefin
i Aromatic
i Paraffin
Acetylene
ppbC
35
178
428
17
658
5
27
65
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
136
794
53
-------
TABLE B12. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
8/1/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
36.5
(77.0)
9.0
219.
24.5
80.0
144.
8.5
10.5
5.5
93.5
54.5
0.5
4.5
7.5
32.0
23.0
31.5
2.0
1.0
14.0
5.8
1.7.5
8.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pejitene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethyl butane
2-Methy1pentane
c-4-Methyl-2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
10.5 2,3-Dimethylpentane
12.5 3-Methylhexane
7.0 2,2,3-Trimethylpentane
9.5 n-Heptane
10.5 Methylcyclohexane
4.0 2,4-D1methylhexane
1.5 2,3,4-Trimethylpentane
43.5 Toluene
2.5 2,3-Dimethylhexane
4.0 2-Methylheptane
5.0 3-Ethylhexane
6.0 n-Octane
2.5 Ethylcyclohexane
9.0 Ethyl benzene
26.5 p 4 m-Xylene
4.0 Styrene
10.5 o-Xylene
4.5 n-Nonane
2.5 i-Propylbenzene
4.5 n-Propylbenzene
5.0 p-Ethyl toluene
4.5 m-Ethyltoluene
11.5 o-Ethyltoluene
3.5 1,3,5-Trlmethylbenzene
9.0 1,2,4-Trlroethylbenzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-DIethyl benzene
— 1,4-DIethyl benzene
Total Identified
Hydrocarbons
z 01efin
z Aromatic
z Paraffin
Acetylene
ppbC %
57
152
829
9
1047
5
15
79
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species ,
ppbC
159
1206
54
-------
TABLE Bl3.- HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
8/2/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
11.0
(63.5 )
7.5
23.0
9.5
20.
44.
3.5
4.0
2.5
.5
.5
43.5
32.0
2.5
3.5
16.0
10.0
13.5
6.0
2.5
10.0
5.6
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D-imethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
5,5 2,3-Dimethylpentane
6.0 3-Methylhexane
4.5 2,2,3-Trimethylpentane
5.5 n-Heptane
4.0 Methylcyclohexane
2.5 2,4-Dimethylhexane
2,3,4-Trlmethylpentane
23.0 Toluene
1.0 2,3-Dimethylhexane
2.0 2-Methylheptane
2.5 3-Ethylhexane
3.0 n-Octane
1.5 Ethylcyclohexane
5.5 Ethyl benzene
14.0 p 4 m-Xylene
3.0 Styrene
7.0 o-Xylene
6.0 n-Nonane
1.5 i-Propylbenzene
4.5 n-Propylbenzene
2.5 p-Ethyltoluene
2.5 m-Ethyltoluene
8.5 o-Ethyltoluene
3.0 1,3,5-Trimethylbenzene
13.5 1,2,4-Trimethylbenzene
4.0 1,2,3-Tr1methylbenzene
3.0 Methylstyrene
2.5 1,3-01ethyl benzene
1.5 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefln
z Aromatic
i Paraffin
Acetylene
ppbC j>
25
104
276
8
413
6
25
67
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species :
ppbC
133
546
-------
TABLE B14. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
8/3/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
16.0
(118.)
27.0
27.5
14.0
35.0
90.5
5.0
6.0
2.5
86.5
67.5
3.0
5.0
7.5
32.5
22.0
29.0
2.0
1.0
13.5
10.5
22.0
9.5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
13.5 2,3-Dimethylpentane
15.0 3-Methylhexane
85 2,2,3-Trimethylpentane
n| 5 n-Heptane
9,0 Methyl eye1ohexane
5!5 2,4-Dimethylhexane
2|o 2,3,4-Trimethylpentane
56.0 Toluene
3.5 2,3-Dimethylhexane
1410 2-Methyl heptane
lols 3-Ethylhexane
7.5 n-Octane
3.0 Ethyl eye1ohexane
11.5 Ethyl benzene
34.0 p A m-Xylene
5.5 Styrene
15.5 o-Xylene
5.0 n-Nonane
2.0 i-Propylbenzene
5.5 n-Propylbenzene
8.0 p-Ethyltoluene
7.0 m-Ethyltoluene
17.5 o-Ethyltoluene
4.0 1,3,5-Trimethylbenzene
11.0 1,2,4-Trimethylbenzene
2.5 1,2,3-Trimethylbenzene
4.0 Methylstyrene
2.0 l,3-D1ethylbenzene
1.0 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefin
E Aromatic
i. Paraffin
Acetylene
ppbC
42
200
560
27
829
5
24
68
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
specfes i
PPbC
331
1160
56
-------
TABLE B15. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
8/4/79
ppbC
Hydrocarbon
Total Identified
Hydrocarbons
I Olefin
£ Aromatic
£ Paraffin
Acetylene
ppbC ji
37
209
536
13
794
5
26
68
2
ppbC
Hydrocarbon
14.0
( 56.0 )
13.0
23.5
7.5
45.0
129.
5.0
7.5
5.5
— — —
97.5
52.5
—
—
—
—
4.5
7.5
28.0
—
18.0
—
23.5
—
—
10.0
6.0
18.5
8.5
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
i -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2 ,3-Dimethyl butane
2-Methylpentane
c-4-Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2 ,4-D1methyl pentane
Benzene
Cyclohexane
10.0
10.5
9.0
8.5
7.0
4.0
2.0
43.0
2.5
7.5
5.5
4.5
1.5
14.5
53.5
4.5
14.0
7.0
2.0
6.0
11.0
___
12.0
9.0
16.0
3.5
6.5
—
5.5
2, 3-Dimethyl pentane
3-Methyl hexane
2,2,3-Trimethylpentane
n-Heptane
Methyl cyclohexane
2 ,4-Dimethyl hexane
2,3,4-Trimethylpentane
To! uene
2, 3-Dimethyl hexane
2 -Methyl heptane
3-Ethyl hexane
n-Octane
Ethyl cyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xyl ene
n-Nonane
i-Propyl benzene
n-Propyl benzene
p-Ethyl toluene
m-Ethyl tol uene
o-Ethyl toluene
1, 3, 5-Trimethyl benzene
1 ,2 ,4-Trimethyl benzene
1 , 2 ,3-Trimethyl benzene
Methyl styrene
1,3-Diethyl benzene
1 ,4-D1 ethyl benzene
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species •.
ppbC
202
996
57
-------
TABLE B16. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN'INSTITUTE SAMPLE ON
8/5/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
10.5
(44.5)
4.5
13.0
3.0
8.0
17.5
16.0
20.0
1.0
2.0
7.0
4.0
7.5
2.5
2.5
5.5
4.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
2.5 2,3-Dimethylpentane
3.0 3-Methylhexane
2.5 2,2,3-Trimethylpentane
2.5 n-Heptane
2.5 Methyl eye 1 ohexa/ie
1.5 2,4-Dimethylhexane
2,3,4-Trlmethylpentane
16.0 Toluene
1.0 2,3-Dimethylhexane
2.0 2-Methyl heptane
3.0 3-Ethylhexane
2.. 5 n-Octane
1.0 Ethyl eye1ohexane
4.0 Ethyl benzene
11.5 pa ro-Xylene
1 - 5 Styrene
4.0 o-Xylene
1-5 n-Nonane
i-Propylbenzene
2.0 n-Propylbenzene
2.0 p-Ethyltoluene
2.0 m-Ethy 1toluene
4.0 o-Ethyltoluene
2.0 1,3,5-Trimethylbenzene
4.5 1,2,4-Trimethy!benzene
1.0 1,2,3-Trimethylbenzene
1.0 Methylstyrene
1.0 1,3-01ethyl benzene
1.0 1,4-01ethyl benzene
Total Identified
Hydrocarbons
i Olefin
z Aromatic
z Paraffin
Acetylene
ppbC %
4
61
140
5
"209"
2
29
67
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
-species ,
ppbC
37
246
58
-------
TABLE B17. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
8/6/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
12.0
(79.0)
26.5
12.0
15.5
47.0
4.5
7.0
1.5
58.5
38.5
6.5
3.5
5.5.
23.5
16.0
21.0
1.5
2.0
9.0
4.0
15.5
7.0
Ethane
Ethylene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
2.
7.
9.0
10.0
6.5
8.5
6.0
3.5
1.5
34.0
.0
.0
5.0
5.0
1.5
8.5
24.0
3.0
9.5
3.0
1.0
3.5
5.0
4.5
12.0
2.0
6.5
1.5
3.0
2.0
1.5
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Tr1methylpentane
n-Heptane
Methyl eye 1ohexane
2,4-D1methylhexane
2,3,4-Tr1methyl pentane
Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Tr1methylbenzene
1,2,3-Trfmethyl benzene
Methylstyrene
l,3-D1ethylbenzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefin
£ Aromatic
z Paraffin
Acetylene
ppbC %
46
132
354
532
9
25
67
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
82
614
59
-------
TABLE B18. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
8/7/79
ppbC
10.0
(70.5)
18.5
16.0
12.5
30.5
76.5
6.0
7.0
4.0
—
76.0
42.5
—
—
—
—
4.0
6.0
28.0
—
17.5
—
19.5
1.0
2.0
10.5
8.0
17.0
7.5
Hydrocarbon
Ethane
Ethylene
Acetyl ene
Propane
Propene
1 -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cycl opentane
2 ,3-Dlmethyl butane
2-Me thy! pentane
c-4-Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cycl opentane
2 ,4-Dimethyl pentane
Benzene
Cyclohexane
ppbC Hydrocarbon
10.5 2, 3 -Dime thy! pentane
12.0 3-Methyl hexane
7^0 2,2,3-Trlmethylpentane
9.5 n-Heptane
9.0 Methyl cyclohexane a
3.0 2, 4-Dimethyl hexane r.
1.5 2, 3,4-Tr1methyl pentane
44.0 Toluene
2.5 2, 3-D1methyl hexane
8.5 2-Methyl heptane
6.5 3-€thyl hexane
6.5 n-Octane
2.0 Ethyl cyclohexane
14.0 Ethyl benzene
51.0 p 4 m-Xylene
5.0 Styrene
15.5 o-Xylene
9.0 n-Nonane
3.0 1-Propyl benzene
6.5 n-Propyl benzene
6.5 p-Ethyl toluene
7 . 0 m-Ethyl to! uene
15.0 o-Ethyl toluene
10.0 1, 3, 5-Trlmethyl benzene
21.5 1, 2, 4-Trlmethyl benzene
4.0 1,2,3-Trimethylbenzene
6 . 5 Methyl styrene
15.5 1,3-D1 ethyl benzene
6.0 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefin
Z Aromatic
i Paraffin
Acetylene
ppbC %
44 6
236 32
439 60
19 3
737
ppbC
Total Unidentified 212
Hydrocarbons
Total NMHC by 949
summing individual
.species •
-------
TABLE B19. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
8/10/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
15.0 Ethane
(48.8) Ethyl ene
9.0 Acetylene
146. Propane
9.8 Propene
41.3 1-Butane
81.0 n-Butane
3.0 1-Butene
5.3 1-Butene
6.0 t-2-Butene
c-2-Butene
60.0 1-Pentane
34.5 n-Pentane
3.8 1-Pentene
t-2-Pentene
— c-2-Pentene
0.8 Cyclopentene
3-0 Cyclopentane
4.5 2,3-D1methyl butane
19.5 2-Methylpentane
— c-4-Methyl-2-pentene
12.0 3-Methylpentane
1 •5 1-Hexene
15.8 n-Hexane
0.8 t-2-Hexene
1.5 c-2-Hexene
7.5 Methyl cyclopentane
4.5 2,4-Dimethylpentane
12.8 Benzene
6.8 Cyclohexane
6.8
7.5
6.0
6.8
5.3
3.0
1.5
24.0
1.5
5.3
3.0
3.8
1.5
6.0
18.0
3.0
7.5
5.3
1.5
3.0
3.0
3.8
7.
6.
12.
1.5
3.0
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Tr1methylpentane
n-Heptane
Methyl eye1ohexane
2,4-Dimethylhexane
2,3,4-Tr1methylpentane
Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trimethyl benzene
1,2,4-Trimethylbenzene
1,2,3-Trimethy!benzene
Methylstyrene
1,3-Diethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
£ Paraffin
Acetylene
ppbC
25
107
509
9
660
5
16
77
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species .
ppbC
117
777
61
-------
TABLE B20. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
8/14/79
ppbC
31.5
(59.3)
15.0
186.
19.5
51.8
103.
3.0
5.3
7.5
3.8
85.5
48.0
6.0
2.3
—
—
4.5
6.8
33.0
—
22.5
—
50.3
1.5
0.8
15.8
8.3
21.0
8.3
_ _ . _ _._ _
Hydrocarbon
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1 -Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
1 -Pentane
n-Pentane
1 -Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2 ,3-D1methyl butane
2 -Methyl pentane
c-4-Methyl -2-pentene
3-Methylpentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye 1 open tane
2 ,4-Diraethyl pentane
Benzene
Cycl ohexane
ppbC Hydrocarbon
11.3 2, 3-Dimethyl pentane
12.8 3-Methyl hexane
8.3 2,2,3-Trimethylpentane
10.5 n-Heptane
10.5 Methyl oycl ohexane
3.0 2, 4-Dimethyl hexane
2.3 2,3,4-Trlmethylpentane
52.5 Toluene
2.3 2, 3-Dimethyl hexane
4.5 2-Methyl heptane
5.3 3-Ethyl hexane
7.5 n-Octane
3.8 Ethyl eye 1 ohexane
16.5 Ethyl benzene
48.0 p 4 m-Xylene
5.3 Styrene
18.8 o-Xylene
10.5 n-Nonane
2.3 1-Propyl benzene
8.3 n-Propyl benzene
12.8 p-Ethyl toluene
3.8 m-Ethyl tol uene
15.0 o-Ethyl tol uene
31.5 1, 3, 5-Tr1methyl benzene
26.3 1, 2, 4-Trimethyl benzene
5.3 1, 2, 3-Trimethyl benzene
13.5 Methyl styrene
20.3 1,3-01 ethyl benzene
12.8 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefin
£ Aromatic
z Paraffin
Acetylene
ppbC %
64 6
295 27
738 66
15 1
ppbC
Total Unidentified 298
Hydrocarbons
Total NMHC by 1409
summing individual
^flpci-es'
mi
6-2
-------
TABLE B21. HYDROCARBON CONCENTRATIONS IN 0800-0900 FRANKLIN INSTITUTE SAMPLE ON
8/15/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
7.5
(34
8.3
11.3
6.8
11.3
29.3
5)
29.3
20.3
2.3
4.5
1.5
2.3
11.3
6.8
9.0
4.5
2.3
7.5
3.8
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methyl pentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye1opentane
2,4-Dtmethylpentane
Benzene
Cyclohexane
3.8 2,3-Dimethyl pentane
4.5 3-Methylhexane
4.5 2,2,3-Trimethylpentane
3.8 n-Heptane
3.8 Methyl eye 1ohexane
1.5 2,4-Dimethylhexane
2,3,4-Trlmethylpentane
18.0 Toluene
0.8 2,3-Dimethylhexane
3.0 2-Methylheptane
2.3 3-Ethylhexane
2.3 n-Octane
Ethyl eye1ohexane
6.8 Ethyl benzene
23.3 p & m-Xylene
2.3 Styrene
7.5 o-Xylene
3.0 n-Nonane
i-Propylbenzene
3.0 n-Propylbenzene
6.0 p-Ethyltoluene
1.5 m-Ethyltoluene
9.8 o-Ethyltoluene
17.3 i.3,5-Trlmethylbenzene
7.5 1,2,4-Trimethylbenzene
12.8 1,2,3-Tr1methylbenzene
7.5 Methylstyrene
1,3-01ethyl benzene
1,4-D1ethylbenzene
Total Identified
Hydrocarbons
£ Olefin
E Aromatic
i Paraffin
Acetylene
ppbC %
23
98
184
8
312
7
31
59
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species
ppbC
164
476
63
-------
APPENDIX C
Individual Hydrocarbon Concentrations in 0600-0700
Industrial Site Samples
64
-------
TABLE Cl . HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 7/17/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
14.3
(404.)
27.8
32.3
15.8
28.5
60.8
6.8
3.0
9.0
56.3
35.3
2.3
5.3
21.0
14.5
12.0
22.5
2.3
11.3
11.3
17.3
33.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thy! cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
45.0 2,3-Dimethylpentane
78.8 3-Methylhexane
23.3 2,2,3-Trimethylpentane
24.8 n-Heptane
239. Methylcyclohexane
18.8 2,4-Dfmethylhexane
2,3,4-Trimethylpentane
62.3 Toluene
7.5 2,3-Dimethylhexane
12.0 2-Methylheptane
9.0 3-Ethylhexane
3.8 n-Octane
2.3 Ethylcyclohexane
8.3 Ethyl benzene
15.8 p & m-Xylene
1.5 Styrene
3.8 o-Xylene
5.3 n-Nonane
5.3 i-Propylbenzene
3.0 n-Propylbenzene
3.8 p-Ethyltoluene
4.5 m-Ethyltoluene
6.8 o-Ethyltoluene
8.3 1,3,5-Trlmethylbenzene
8.3 1,2,4-Trimethyl benzene
1,2,3-Trfmethyl benzene
— Methylstyrene
— 1,3-Diethylbenzene
— 1,4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefin
E Aromatic
i Paraffin
Acetylene
ppbC
54
139
817
28
1034
5
13
79
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species ;
ppbC
477
1511
65
-------
TABLE C2 . HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 7/18/79
ppbC
7.0
(170. )
7.5
12.0
4.0
15.5
48.0
3.5
2.5
2.0
—
53.0
29.5
___
___
___
3.0
5.5
19.5
___
12.5
5.5
17.0
1.5
1.5
6.5
4.0
8.5
3.5
Hydrocarbon
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2, 3-D1methy1 butane
2-Methyl pentane
c-4 -Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye 1 open tane
2, 4-Dimethyl pentane
Benzene
Cyclohexane
ppbC Hydrocarbon
8.0 2, 3-Dimethyl pentane
9.5 3-Methyl hexane
8.0 2,2,3-Trimethylpentane
6.5 n-Heptane
8.5 Methyl cyclohexane
3.5 2, 4-Dimethyl hexane
2,3,4-Trimethylpentane
32.5 Toluene
2.0 2, 3-Dimethyl hexane
3.5 2-Methyl heptane
2.5 3-Ethyl hexane
2.0 n-Octane
Ethyl cyclohexane
5.0 Ethyl benzene
13.0 P & m-Xylene
2 . 5 Styrene
7.0 o-Xylene
3.5 n-Nonane
— i-Propyl benzene
— n-Propyl benzene
4.0 p-Ethyl toluene
7.0 m-Ethyl toluene
7.0 o-Ethyl toluene
4.0 1, 3, 5-Trimethyl benzene
5.5 1, 2, 4-Trimethyl benzene
3.0 1,2,3-Trimethylbenzene
1.5 Methyl styrene
1.5 1, 3 -D1 ethyl benzene
1.5 1,4-DI ethyl benzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
z Paraffin
Acetyl ene
ppbC %
25 6
108 25
293 68
8 2
ppbC
Total Unidentified 86
Hydrocarbons
Total NMHC by 520
summing individual
cnprlec ,
434
66
-------
TABLE C3 . HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 7/19/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.0
(234. )
9.0
16.0
6.0
12.0
24.5
2.0
1.0
2.5
27.0
15.5
2.0
4.5
16.0
11.0
5.0
17.0
6.5
4.5
13.0
4.0
Ethane
Ethyl ene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methyl pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
6.5 2,3-Dimethylpentane
8.5 3-Methylhexane
5.0 2,2,3-Trimethylpentane
6.0 n-Heptane
6.5 Methyl eyelohexane
2.0 2,4-Dimethylhexane
2,3,4-Trlmethylpentane
39.0 Toluene
1.5 2,3-Dimethylhexane
3.5 2-Methylheptane
2.0 3-Ethylhexane
2.5 n-Octane
Ethyl eye1ohexane
5.5 Ethyl benzene
15.5 p A m-Xylene
2.0 Styrene
7.0 o-Xylene
2.5 n-Nonane
13.5 1-Propylbenzene
4.0 n-Propylbenzene
3.0 p-Ethyl toluene
2.5 m-Ethyl toluene
6.0 o-Ethyltoluene
3.0 1,3,5-Tr1methylbenzene
5.0 1,2,4-Trimethylbenzene
1.0 1,2,3-Trlmethylbenzene
1.5 Methylstyrene
1.0 1,3-01ethyl benzene
1.0 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefln
£ Aromatic
i Paraffin
Acetylene
ppbC
18
122
227
9
"376
5
32
60
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species ;
ppbC
72
448.
67
-------
TABLE C4 . HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 7/2Q/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
21.5
(21.5)
8.0
15.0
11.0
11.0
28.5
31.5
21.0
2.0
3.5
14.0
9.5
20.0
6.5
4.0
7.5
4.5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-01methylpentane
Benzene
Cyclohexane
7.5
11.5
4.5
7.0
19.0
3.0
45.0
1.5
2.5
2.0
3.0
5.5
16.5
3.0
7.5
6.5
1.5
7.5
4.0
5.0
9.5
5.0
19.0
5.5
2.5
2.5
3.5
2,3-Dimethylpentane
3-Me thylhexane
2,2,3-Trimethylpentane
n-Heptane
Methyl eye1ohexane
2,4j-DimethyThexane<
2,3,4-Trimethylpentane
Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Tri me thylbenze ne
1,2,3-Trimethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
E Olefln
£ Aromatic
i Paraffin
Acetylene
ppbG
16
145
261
_8_
430-
4
34
61
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species. ,
ppbC
145
575
-------
TABLE C5 . HYDROCARBON CONCENTRATIONS IN 0600^0700 INDUSTRIAL SITE SAMPLE ON 7/23/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
13.5
(146.)
11.0
38.5
31.0
13.0
41.0
17.0
11.0
1.5
3.5
14.5
11.0
2.5
23.5
9.5
2.0
5.5
2.5
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
3.5 2,3-Dimethylpentane
5.0 3-Methylhexane
— 2,2,3-Trimethylpentane
4.5 n-Heptane
5.5 Methylcyclohexane
1.0 2,4-Dimethylhexane
--- 2,3,4-Trlmethylpentane
25.0 Toluene
1.0 2,3-D1methylhexane
1.5 2-Methyl heptane
1.5 3-Ethylhexane
2.5 n-Octane
Ethylcyclohexane
5.0 Ethyl benzene
12.5 p & m-Xylene
3.0 Styrene
5.5 o-Xyl ene
12.0 n-Nonane
2.5 i-Propylbenzene
11.0 n-Propylbenzene
3.0 p-Ethyltoluene
6.0 m-Ethyltoluene
22.5 o-Ethyltoluene
1,3,5-Trimethylbenzene
7.5 1,2,4-Tr1methylbenzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-Dlethylbenzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
r Paraffin
Acetylene
ppbC
36
105
239
11
392
9
27
61
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
183
575
69
-------
TABLE C6 . HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 7/24/79
ppbC
9.5
(82.0 )
1.0
30.0
30.0
32.5
86.0
7.5
8.0
10.5
—
149.
60.0
15.5
—
—
4.5
13.0
21.5
104.
69.0
—
61.0
16.5
22.5
49.0
18.0
105.
16.0
Hydrocarbon
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
i -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1 -Pentane
n-Pentane
1 -Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cycl opentane
2 ,3-Dimethyl butane
2-Methyl pentane
c-4-Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cycl opentane
2 ,4-Dimethyl pentane
Benzene
Cycl ohexane
ppbC Hydrocarbon
41.5 2, 3-D i methyl pentane
36.5 3-Methyl hexane
10.0 2,2,3-Trimethylpentane
37.0 n-Heptane
36.5 Methyl eye 1 oftexasne
7.0 2,4-Dimethylhtexiane
2,3,4-Trimethylpentane
80.0 Toluene
5.0 2, 3-Dimethyl hexane
13.5 2-Methyl heptane
12.5 3-Ethyl hexane
14.5 n-Octane
5 . 5 Ethyl eye 1 ohexane
8.5 Ethyl benzene
24.0 p & m-Xylene
8.0 Styrene
12.5 o-Xylene
11.0 n-Nonane
2.5 i-Propyl benzene
7.5 n-Propyl benzene
3.0 p-Ethyl toluene
8.0 m-Ethyl to! uene
8.5 o-Ethyl toluene
3.0 1, 3, 5-Trimethyl benzene
12.5 1, 2, 4-Trimethyl benzene
3.0 1, 2, 3-Trimethyl benzene
2.5 Methyl styrene
2.0 1,3-DI ethyl benzene
2.0 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefln
z Aromatic
z Paraffin
Acetyl ene
ppbC %
126 9
282 20
1009 71
1
1419
ppbC
Total Unidentified 281
Hydrocarbons
Total NMHC by 1710
summing individual
species ,
70
-------
TABLE C7. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 7/25/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
7.5
(66.0)
2.5
19.5
21.5
13.5
42.0
1.5
1.5
2.5
25.0
18.5
1.5
3.5
12.5
10.0
16.5
6.5
6.5
9.5
3.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methy1butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
5.0
7.5
4.5
14.5
2.0
28.0
1.5
3.0
2.0
2.0
3.5
12.5
1.5
5.0
4.0
1.0
3.0
2.5
6.0
2.0
9.5
2.0
1.0
1.0
1.0
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methyl eye1ohexane
2,4-Dimethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Tr1methylbenzene
1,2,4-Trimethylbenzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-Diethyl benzene
Total Identified
Hydrocarbons
£ Olefln
z Aromatic
z Paraffin
Acetylene
ppbC
29
87
232
3
"350"
7
25
66
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
77
493
71
-------
TABLE C8. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 7/26/7?
ppbC
11.3
(33.8)
3.0
45.0
6.8
15.8
30.0
4.5
4.5
6.0
60.0
27.0
4.5
16.5
12.0
1.5
4.5
8.3
37.5
2.3
23.3
3.8
21.8
6.8
3.8
19.5
5.3
99.8
6.8
Hydrocarbon
Ethane
Ethyl ene
Acetylene
Propane
Propene
1 -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1 -Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cycl open tane
2, 3-D1methyl butane
2-Me thy! pentane
c-4-Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thy! cycl opentane
2 ,4-D1methyl pentane
Benzene
Cycl ohexane
ppbC Hydrocarbon
18.8 2, 3-D 1 methyl pentane
2i.o 3-Methyl hexane
6.0 2,2,3-Trimethylpentane
15.8 n-Heptane
18.0 Methyl cycl ohexane
4.5 2, 4-Dimethyl hexane
1.5 2,3,4-Trlmethylpentane
64.5 Toluene
3.8 2, 3-Dimethyl hexane
10.5 2-Methyl heptane
4.5 3-Ethyl hexane
10.5 n-Octane
5.3 Ethyl cycl ohexane
10.5 Ethyl benzene
25.5 p & m-Xylene
11.3 Styrene
18.0 o-Xylene
20.3 n-Nonane
3.0 1-Propyl benzene
11.3 n-Propyl benzene
7.5 p-Ethyl toluene
6.8 m-Ethyl toluene
15.8 o-Ethyl toluene
7.5 1, 3, 5-Trlmethyl benzene
27.8 1, 2, 4-Trimethyl benzene
6.8 1, 2, 3-Trlmethyl benzene
6.0 Methyl styrene
4.5 1,3-Dlethylbenzene
3.8 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
£ Olefin
£ Aromatic
z Paraffin
Acetylene
ppbC %
67 8
306 36
474 55
__3
ppbC
Total Unidentified 279
Hydrocarbons
Total NMHC by 1139
summing Individual
&necie& •
860
72
-------
TABLE C9. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 7/30/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
12.0
(429.)
7.0
18.5
5.0
8.5
21.5
23.5
13.0
1.0
2.0
7.5
5.5
8.0
3.0
2.0
14.0
2.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methy1butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methyl pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
4.0
6.5
3.5
4.5
12.5
3.0
24.0
1.0
1.5
2.0
2.0
4.0
12.5
1.5
5.0
2.5
18.0
3.0
2.0
2.0
5.0
4.5
7.0
2,3-Dimethy!pentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-Dimethylhexane
2,3,4-Tr1methylpentane
Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Tr1methylbenzene
1,2,4-Trimethylbenzene
1,2,3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
z Olefin
£ Aromatic
i Paraffin
Acetylene
ppbC
7
101
173
7
288
2
35
60
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species <
ppbC
73
361
73
-------
TABLE CIO. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 7/31/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
10.5
(196)
12.5
.18.0
6.5
14.0
25.5
4.0
6.0
3.5
28.5
19.5
1.5
3.5
12.0
9.0
8.0
3.5
2.0
28.5
3.5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Olmethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methy!cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
4.0
5.0
4.0
3.5
4.0
2.5
26.5
1.0
2.0
2.5
2.5
4.0
13.5
2.5
6.5
5.5
5.0
6.0
3.0
12.5
2.5
1.0
1.5
1.0
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methyl eye1ohexane ,
2,4 -Dimethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & ro-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Trimethylbenzene
1,2,3-Trlmethylbenzene
Methylstyrene
1,3-Diethylbenzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
z Olefin
£ Aromatic
z Paraffin
Acetylene
ppbC %
23
110
200
13
343
7
32
58
4
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species t
ppbC
78
424
74
-------
TABLE Cll. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 8/1/79
ppbC
Hydrocarbon
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
z Paraffin
Acetylene
8
18
72
2
ppbC
Hydrocarbon
8.5
(798.)
4.5
31.5
21.5
18.0
57.0
1.5
—
—
—
25.0
18.5
—
—
—
—
1.0
2.0
6.5
5.0
—
8.0
—
—
2.5
1.0
5.0
1.5
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1 -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1 -Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2, 3-D1methyl butane
2-Methylpentane
c-4-Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2 ,4-D1methyl pentane
Benzene
Cyclohexane
2.0
3.0
2.5
2.0
2.0
1.0
—
11.5
—
1.0
1.0
1.5
—
2.0
6.5
1.0
3.0
2.5
—
2.5
0.5
3.0
9.0
—
5.0
—
—
—
3.5
2, 3-Dimethyl pentane
3-Methyl hexane
2,2, 3-Trlmethyl pentane
n-Heptane
Methyl eye 1 ohexane
2, 4-D1methyl hexane
2 ,3,4-Trlmethyl pentane
Tol uene
2 ,3-Dimethyl hexane
2-Methyl heptane
3-Ethyl hexane
n -Octane
Ethyl cyclohexane
Ethyl benzene
p A m-Xylene
Styrene
o-Xyl ene
n-Nonane
1-P ropy 1 benzene
n-Propyl benzene
p-Ethyl toluene
m- Ethyl tol uene
o-Ethyl toluene
1, 3, 5-Trlme thy 1 benzene
1 ,2, 4-Trimethyl benzene
1, 2, 3-Trlmethyl benzene
Methyl styrene
1 ,3-D1 ethyl benzene
1 ,4-01 ethyl benzene
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
60
345
75
-------
TABLE C12, HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 8/2/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
7.5
(90.0)
3.0
19.5
4.0
8.5
20.5
13.5
10.0
1.5
4.0
3.0
4.5
1.5
3.0
3.5
1.5
Ethane
Ethylene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methy1pentane
Benzene
Cyclohexane
2.5
4.0
2.5
8.0
2.5
12.5
1.5
1.0
1.0
2.5
9.5
3.5
2.5
1.5
1.5
1.5
1.5
4.5
3.0
8.5
1.5
2,3-Dimethyl pentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methyl eye1ohexane
2,4-Dimethylhexane
2,3,4-Trlmethyl pentane
Toluene
2,3-Dimethyl hexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethyltoluene
o-Ethylto!uene
1,3,5-Tr1methyl benzene
1,2,4-Trimethylbenzene
1,2,3-Tr1methylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
z Olefln
£ Aromatic
z Paraffin
Acetylene
ppbC
4
58
123
3
189
2
31
65
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species )
ppbC
137
226
76
-------
TABLE C13. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 8/3/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
20.5
(376.)
10.5
42.0
12.0
22.
46.
4.
3.5
1.5
.5
.5
.5
45.0
40.5
2.0
3.0
13.5
9.5
15.5
5.5
3.5
34.5
4.5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2^Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thy! cyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
5.0 2,3-Dimethylpentane
6.5 3-Methylhexane
4.0 2,2,3-Trimethylpentane
4.5 n-Heptane
6.0 Methyl cyclohexane
2.5 2,4-Dimethylhexane
2,3,4-Trlmethylpentane
22.0 Toluene
1.0 2,3-Dimethylhexane
2.0 2-Methylheptane
2.0 3-Ethylhexane
3.0 n-Octane
1.5 Ethylcyclohexane
4.5 Ethyl benzene
11.5 p & m-Xylene
2.0 Styrene
6.0 o-Xylene
2.5 n-Nonane
1.5 i-Propylbenzene
3.0 n-Propylbenzene
3.0 p-Ethyltoluene
2.5 m-Ethyltoluene
5.5 o-Ethyltoluene
2.5 1,3,5-Trimethylbenzene
7.0 1,2,4-Trimethylbenzene
2.0 1,2,3-Trimethylbenzene
1.5 Methylstyrene
0.5 1,3-01ethyl benzene
1.0 1,4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefln
i: Aromatic
£ Paraffin
Acetylene
ppbC
24
107
315
11
457
5
23
69
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species ,
ppbC
82
539
77
-------
TABLE C14. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 8/4/7$
ppbC
Hydrocarbon
ppbC
Hydrocarbon
12.5
(654.)
5.5
21.5
5.0
24.0
39.0
3.5
3.5
1.5
34.0
31.0
1.0
1.5
6.0
4.0
7.5
2.5
2.5
4.5
1.5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methy!pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye 1 opentane
2,4-Dimethylpentane
Benzene
Cyclohexane
2.5 2,3-Dimethylpentane
3.5 3-Methylhexane
2.5 2,2,3-Trimethylpentane
2.0 n-Heptane
2.0 Methylcyclohexane
1.5 2,4-Dimethylhexane
2,3,4-Trimethylpentane
13.5 Toluene
2,3-Dimethylhexane
1.0 2-Methylheptane
1.0 3-Ethylhexane
1.5 n-Octane
Ethylcyclohexane
2.5 Ethyl benzene
7.5 p & m-Xylene
1.0 Styrene
3.5 o-Xyl ene
1.5 n-Nonane
3.0 i-Propylbenzene
2.0 n-Propylbenzene
p-Ethyl toluene
2.5 m-Ethyltoluene
3.5 o-Ethyltoluene
4.0 1,3,5-Tr1methylbenzene
5.0 1,2,4-Trimethylbenzene
1,2,3-Trimethylbenzene
1.0 Methylstyrene
1.0 1,3-DIethyl benzene
0.5 1,4-Diethyl benzene
Total Identified
Hydrocarbons
E Olefin
z Aromatic
z Paraffin
Acetylene
ppbC 2,
16
54
206
6
282
6
19
73
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
25
307
78
-------
TABLE C15. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 8/5/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
14.0
(525. )
6.0
11.0
4.5
12.0
29.0
22.5
23.0
1.0
3.0
9.0
5.5
7.5
3.0
1.5
7.5
2.0
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
3.0 2,3-Dimethylpentane
4.0 3-Methylhexane
4.5 2,2,3-Trlmethylpentane
3.0 n-Heptane
5.0 Methylcyclohexane
2.0 2,4-D1methylhexane
2,3,4-Tr1methylpentane
18.0 Toluene
2,3-Dimethylhexane
2.0 2-Methylheptane
1.5 3-Ethylhexane
1.5 n-Octane
Ethylcyclohexane
3.5 Ethyl benzene
11.0 p 4 m-Xylene
1.0 Styrene
4.5 o-Xylene
2.0 n-Nonane
1.0 1-Propy!benzene
2.5 n-Propylbenzene
2.0 p-Ethyltoluene
2.0 m-Ethyltoluene
5.0 o-Ethyltoluene
2.0 1,3,5-Trlmethylbenzene
7.0 1,2,4-Trimethylbenzene
1,2,3-Trimethylbenzene
1.0 Methylstyrene
1.0 1,3-01ethyl benzene
1.0 1,4-01ethyl benzene
Total Identified
Hydrocarbons
E Olefln
£ Aromatic
£ Paraffin
Acetylene
ppbC %
8
68
173
6
255
3
27
68
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
35
290
79
-------
TABLE C16. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 8/6/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
16.5
(244. )
13.0
57.5
10.0
16.0
36.5
4.0
6.0
3.0
40.0
30.0
4.0
2.5
3.5
17.0
10.5
17.5
6.0
3.5
12.5
3.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thy! cycl opentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
6.5 2,3-Dimethylpentane
7.5 3-Methylhexane
5.0 2,2,3-Trlmethylpentane
5.5 n-Heptane
5.0 Methyl cyclohexane
2.5 2,4-Dlmethylhexane
1.0 2,3,4-Trlmethylpentane
26.5 Toluene
1.5 2,3-Dimethylhexane
4.5 2-Methylheptane
3.5 3-Ethylhexane
3.0 n-Octane
1.0 Ethyl eyelohexane
6.0 Ethyl benzene
18.0 pi m-Xylene
2.5 Sty rene
8.0 o-Xylene
3.5 n-Nonane
1-Propylbenzene
3.0 n-Propylbenzene
7.5 p-Ethyltoluene
3.0 m-Ethyltoluene
9.5 o-Ethyltoluene
2.0 1,3,5-Tr1methylbenzene
10.0 1,2,4-Trimethylbenzene
1.0 1,2,3-Trimethylbenzene
2.0 Methylstyrene
2.0 1,3-D1ethyl benzene
1.0 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefln
£ Aromatic
z Paraffin
Acetylene
ppbC
32
97
330
13
467
7
21
71
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
83
550
-------
TABLE C17. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 8/7/79
ppbC
Hydrocarbon
Total Identified
Hydrocarbons
i Olefln
z Aromatic
z Paraffin
Acetylene
ppbC
10
61
148
5
223
4
27
66
2
ppbC
Hydrocarbon
5.0
(594.)
4.5
10.5
4.0
14.5
40.0
3.0
2.0
—
—
24.5
15.0
—
—
—
—
1.0
1.5
7.5
—
5.0
—
8.0
—
—
2.5
2.0
4.5
1.5
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1 -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cycl opentene
Cyclopentane
2, 3-D1methyl butane
2-Methylpentane
c-4-Methyl -2-pentene
3-Methy 1 pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2 ,4-D1methyl pentane
Benzene
Cyclohexane
2.5
3.0
2.0
2.0
2.0
1.0
___
12.0
—
2.0
1.0
1.0
—
3.5
9.0
1.0
4.0
2.5
2.0
2.5
1.5
2.0
5.0
5.0
8.0
—
—
—
1.0
2 ,3 -Dime thy! pentane
3-Methyl hexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye lohexane
2 ,4-D1methyl hexane
2,3,4-Trlmethylpentane
To! uene
2, 3 -Dimethyl hexane
2 -Me thy! heptane
3-Ethyl hexane
n -Octane
Ethyl eye lohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propyl benzene
n-Propyl benzene
p-Ethyl toluene
m-Ethyl toluene
o-Ethyl toluene
1, 3, 5-Trlmethyl benzene
1 ,2,4-Trimethyl benzene
1, 2 ,3-Trlmethyl benzene
Methyl styrene
1,3-01 ethyl benzene
1 ,4-D1 ethyl benzene
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species :
PPbC
49
272
81
-------
TABLE CIS. -HYDROCARBON CONCENTRATIONSjIN 0600-0700 INDUSTRIAL SITE SAMPLE .ON 8/8719
ppbC
Hydrocarbon
ppbC
Hydrocarbon
37.0
(85.0)
6.0
.93.0
19.0
80.5
159.
4.5
3.5
1.5
.98.5
54.5
5.5
4.5
5.5
.26.0
16.0
24.5
11.0
3.0
16.0
-7.0
Ethane
,Ethylene
Acetylene
: Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
yt>2-Butene
c-2-Butene
t-Pentane
n-rRentane
1-Pentene
t-12-Pentene
c-2-Pentene
.Cyclopentene
.Cyclopentane
.2 ,3-Dlmethylbutane
2-Me.thyl pentane
c-4-Methyl-2~pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-01methylpentane
Benzene
Cyclohexane
9.0 2,3-Dimethy!pentane
10.5 3-Methylhexane
5.5 2,2,3-Trtmethylpentane
10.5 n-Heptane
10.5 Methylcycllohexane t
2.0 2,4rDlroethyl hexari'e •
2,3 i4-Tr1methylpentane
.121.5 Toluene
2.0 2,3rDtmethylhexane
3.5 2-Methylheptane
4.0 3-Ethylhexane
5.5 n-r Octane
1.5 Ethyl eye1ohexane
4.0 Ethyl benzene
10.5 p & m-Xylene
2.5 :Styrene
6.0 o-Xylene
3.5 n-Nonane
2.5 i-Propylbenzene
3.0 n-Propylbenzene
2.5 p-Ethyltoluene
3.0 m-Ethylto!uene
6.5 o-Ethyltoluene
1.5 1,3,5-Trimethylbenzene
6.0 1,2,4-Trimethylbenzene
1,2,3-Triraethylbenzene
1.0 Methylstyrene
1.0 1,3-Diethylbenzene
1.0 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefln
l Aromatic
.1 Paraffin
Acetylene
ppbC
38
85
688
6
817
.5
10
84
1
Total Unidentified
Hydrocarbons
Total ^NMHC by
summing Individual
sspeotes i
ppbC
61
878
-------
TABLE C19. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 8/9/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
.5
.0
9.0
(408.)
6.5
14.
7.
12.0
28.5
2.0
3.5
1.5
27.0
34.5
1.5
3.5
10.5
9.0
11.5
4.0
3.0
8.5
3.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
5.5 2,3-Dimethylpentane
5.5 3-Methylhexane
3.0 2,2,3-Trlmethylpentane
4.0 n-Heptane
3.5 Methyl cyclohexane
1.5 2,4-Dimethylhexane
2,3,4-Trlmethylpentane
26.0 Toluene
1.0 2,3-Dimethylhexane
1.5 2-Methylheptane
2.0 3-Ethylhexane
2.0 n-Octane
Ethylcyclohexane
4.0 Ethyl benzene
13.5 p & m-Xylene
2.0 Styrene
6.5 o-Xylene
3.5 n-Nonane
1.5 1-Propylbenzene
3.5 n-Propylbenzene
3.0 p-Ethyltoluene
3.0 m-Ethyltoluene
7.5 o-Ethyltoluene
7.0 1,3,5-Trlmethylbenzene
11.5 1,2,4-Trimethy!benzene
2.0 1,2.3-Trlmethylbenzene
2.5 Methylstyrene
3.0 1,3-01ethyl benzene
5.0 1,4-01ethyl benzene
Total Identified
Hydrocarbons
i Olefin
I Aromatic
i Paraffin
Acetylene
ppbC
18
105
206
7
336
5
31
61
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
82
418
-------
TABLE C20 . HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 8/107/7/9
ppbC
Hydrocarbon
ppbC
Hydrocarbon
9.8
(126.)
3.0
20.3
9.0
16.5
39.8
39.0
24.8
3.0
4.5
20.3
12.8
4.
19.
1.5
7.5
3.8
185.
12.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1 -Pe.nte.ne
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye 1 opentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
10.5
12.0
5.3
12.8
12.0
3.0
96.0
3.0
4.5
5.3
7.5
2.3
5.3
14.5
3.0
7.5
4.5
0.8
2.3
1.5
2.3
3.0
2.3
4.5
1.5
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
t Methyl eye1ohexane
2,4-Dlmethyl hexa'rte
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethyleye1ohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Trimethylbenzene
1,2,3-Trimethylbenzene
Methyl styrene
1,3-D1ethyl benzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
z Olefin
£ Aromatic
z Paraffin
Acetylene
ppbC
18
326
318
3
663
3
49
48
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species* i
ppbC
81
744
84
-------
TABLE C21. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON 8/14/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
14.3
(537.)
4.5
34.5
59.3
14.3
77.3
22.5
12.0
1.5
1.5
7.5
5.3
14.3
3.8
2.3
5.3
2.3
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1 opentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
3.0 2,3-Dimethylpentane
3.0 3-Methylhexane
2.3 2,2,3-Trimethylpentane
2.3 n-Heptane
1.5 Methylcyclohexane
1-5 2,4-Dimethylhexane
2,3,4-Trlmethylpentane
10.5 Toluene
0.8 2,3-Dimethylhexane
1.5 2-Methylheptane
1.5 3-Ethylhexane
1.5 n-Octane
Ethylcyclohexane
2.3 Ethyl benzene
6.0 p & m-Xylene
0.8 Styrene
3.0 o-Xylene
1.5 n-Nonane
i-Propylbenzene
1.5 n-Propylbenzene
3.0 p-Ethyltoluene
1.5 m-Ethyltoluene
4.5 o-Ethyltoluene
0.8 1,3,5-Tr1methylbenzene
3.8 1,2,4-Trimethylbenzene
1,2,3-Trfmethyl benzene
Methylstyrene
1,3-Diethy1 benzene
1,4-DIethyl benzene
Total Identified
Hydrocarbons
E Olefln
£ Aromatic
E Paraffin
Acetylene
ppbC
61
42
234
5
340
18
12
69
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
27
367
85
-------
TABLE C22. HYDROCARBON CONCENTRATIONS IN 0600-0700 INDUSTRIAL SITE SAMPLE ON
ppbC
Hydrocarbon
Total Identified
Hydrocarbons
i Olefin
i Aromatic
z Paraffin
Acetylene
ppbC
26
96
355
_13_
489"
.5
20
73
ppbC
Hydrocarbon
15.5
( 132.)
13.0
18.0
11.0
22.5
55.0
3.5
5.5
2.0
53.5
37.0
—
—
—
3.0
4.0
20.5
—
13.5
21.5
—
—
9.0
3.0
12.0
5.5
Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
1 -Butene
1 -Butene
t-2-Butene
c-2-Butene
i -Pentane
n -Pentane
1 -Pentene
t-2-Pentene
c -2 -Pentene
Cyclopentene
Cycl opentane
2 ,3-Dimethyl butane
2-Metbyl pentane
c-4-Me thyl -2-pentene
3-Methyl pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye 1 opentane
2 ,4-Dimethyl pentane
Benzene
Gycl ohexane
9.5
11.0
4.5
13.0
9.0
2.5
1.0
20.5
2.0
4.0
4.5
5.5
2.0
5.0
12.0
3.5
7.5
5.0
1.5
4.0
3.5
4.5
7.0
2.5
9.0
2.0
2.0
1.5
1.0
2 ,3-Dimethyl pentane
3-Methylhexane
2,2, 3-Trimethyl pentane
n-Heptane
Me thyl eye 1 ohexane :
2 ,4-Oimethyl hexane
2 ,3,4-Trimethyl pentane
To! uene
2 ,3^Dimethyl hexane
2-Me thyl heptane
3 -Ethyl hexane
n -Octane
Ethyl eye 1 ohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xyl ene
n-Nonane
i-Propyl benzene
n-Propyl benzene
p-Ethyl tol uene
m-Ethyl tol uene
o-Ethyl tol uene
1,3, 5-Tri methyl benzene
1 ,2 ,4-Trlmethyl benzene
1,2,3-Trime thyl benzene
Methyl styrene
1 , 3-01 ethyl benzene
1 ,4-01 ethyl benzene
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species- i
ppbC
99
588
86
-------
APPENDIX D
Individual Hydrocarbon Concentrations in 0800-0900
Industrial Site Samples
87
-------
TABLE Dl. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 7/17/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
11,
(407,
17,
27.0
.5
.3
10.
29.
72.0
3.0
3.8
3.8
63.8
33.0
3.8
6.0
24.0
15.0
22.5
9.0
6.8
15.0
5.3
Ethane
Ethyl ene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methy!-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
.5
.5
.5
10.
13.
7.
7.5
6.8
3.0
49.5
2.3
5.3
3.8
3.0
6.8
18.8
3.0
9.0
4.5
1.5
4.5
4.5
3.8
6.8
3.0
8.3
2.3
0.8
0.8
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye1ohexane
2,4-D1methylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propy 1 benzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-TrImethy1 benzene
1,2,4-Trimethylbenzene
1,2,3-TrImethy1 benzene
Methylstyrene
1,3-01ethyl benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefln
£ Aromatic
E Paraffin
Acetylene
ppbC
21
133
390
17
55T
4
24
69
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
248
809
-------
TABLE D2. HYDROCARBON CONCENTRATIONS IN 080.0-0900 INDUSTRIAL SITE SAMPLE ON 7/18/79
ppbC
8.0
(255. )
17.0
17.5
10.0
26.0
32.5
6.5
5.5
2.5
—
36.5
23.5
--—
—
—
2.5
4.5
14.5
—
7.5
8.0
12.0
— — —
-— —
5.0
3.5
10.5
4.0
Hydrocarbon
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1 -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1 -Pentane
n-Pentane
1 -Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cycl opentane
2, 3-D1methyl butane
2-Methylpentane
c-4-Methyl -2-pentene
3-Methylpentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye 1 opentane
2,4-Dlmethylpentane
Benzene
Cycl ohexane
ppbC Hydrocarbon
7.5 2,3-Dlmethylpentane
10.0 3-Methylhexane
6.0 2,2,3-Trlmethylpentane
7.0 n-Heptane
16.5 Me thy! eye 1 ohexane * * ,
2.0 2,4-D1methylhexane i
2,3,4-Trfmethylpentane
30.0 Toluene
1.5 2,3-Dlmethylhexane
3.5 2-Methyl heptane
2.0 3-Ethylhexane
2.0 n-Octane
Ethyl eye 1 ohexane
5.0 Ethyl benzene
13.5 pi m-Xylene
2.0 Styrene
7.0 o-Xylene
1.0 n-Nonane
1.5 1-Propyl benzene
n-Propyl benzene
3.5 p-Ethyl tol uene
3.5 m-Ethy 1 tol uene
7.0 o-Ethyl tol uene
4.5 1, 3, 5-Tr1methyl benzene
7 . 5 1 ,2 ,4-T rime thy 1 benzene
2.0 1, 2, 3-Trl methyl benzene
1.5 Methyl styrene
1,3-Diethyl benzene
— 1 ,4-D1 ethyl benzene
Total Identified
Hydrocarbons
z Olefln
z Aromatic
z Paraffin
Acetylene
ppbC %
23 9
98 24
256 63
17 .4
ppbC
Total Unidentified 152
Hydrocarbons
Total NMHC by 629
summing individual
SDecies ,
406
-------
TABLE D3 . HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 7/19/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
10.0
(213.)
16.5
21.0
7.6
14.0
28.5
2.0
2.0
4.5
34.5
18.5
3.0
5.5
22.5
15.5
4.0
22.5
9.5
5.5
18.0
5.0
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methyl pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
8.5
12.0
6.0
8.0
10.0
4.
1
,5
,5
69.5
2.5
5.0
3.5
4.0
8.0
23.0
2.5
10.0
3.0
28.0
3.0
4.0
3.5
7.5
3.0
6.0
2.0
1.0
2,3-D1methylpentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methylcyclohexane
2,4-Dimethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methy!heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trimethyl benzene
1,2,4-Trimethylbenzene
1,2,3-Tr1methylbenzene
Methylstyrene
1,3-Diethy1 benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
i Olefln
I Aromatic
T. Paraffin
Acetylene
ppbC
23
187
284
17
406
9
24
63
4
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species •.
ppbC
119
558
9.0
-------
TABLE D4. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 7/23/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
31.5
(*)
6.0
84.0
33.8
42.0
82.5
3.0
3.8
3.0
48.8
31.5
3.8
5.3
24.0
16.5
32.3
13.5
4.5
21.8
11.3
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
10.5
17.3
6.8
12.8
52.5
5.3
36.8
3.0
5.3
5.3
7.5
6.0
15.8
5.3
8.3
13.5
3.8
9.0
5.3
4.5
4.5
23.3
6.8
6.0
4.5
3.0
2,3-Dimethyl pentane
3-Methyl he.xane
2,2,3-Trlmethylpentane
n-Heptane
- Methy!eye1ohexane
2,4-Dimethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propy1 benzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Triroethylbenzene
1,2,4-Trimethy!benzene
1,2,3-Trimethylbenzene
Methy!styrene
1,3-D1ethyl benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefin
i Aromatic
i Paraffin
Acetylene
ppbC %
55
153
571
6
786
7
20
73
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species >
ppbC
262
1048
91
-------
TABLE D5. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 7/24/79
ppbC
24.8
(167.)
10.5
66.8
26.3
42.0
80.3
4.5
4.5
5.3
—
75.5
42.0
6.0
1.5
6.0
12.8
44.3
2.3
30.0
7.5
37.5
6.0
3.0
21.8
9.8
39.0
9.0
Hydrocarbon
Ethane
Ethyl ene
Acetylene
Propane
Propene
1 -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2, 3-D1methyl butane
2-Methylpentane
c-4-Methyl -2-pentene
3-Methylpentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cycl opentane
2 ,4-D1methyl pentane
Benzene
Cyclohexane
ppbC Hydrocarbon
17.3 2, 3-D1methyl pentane
21.0 3-Methyl hexane
2.3 2,2,3-Trimethylpentane
16.5 n-Heptane
18.0 Methyl cyclohexane
3.8 2, 4-D1methyl hexane
1.5 2,3,4-Trlmethylpentane
49.5 Toluene
2.3 2, 3-D1methyl hexane
6.8 2 -Me thy! heptane
6.0 3-Ethyl hexane
8.3 n-Octane
3 . 0 Ethyl eye 1 ohexane
6.8 Ethyl benzene
18.8 p * m-Xylene
2.3 Styrene
8.3 o-Xylene
8.3 n-Nonane
3.0 1-Propyl benzene
6.8 n-Propyl benzene
4.5 p-Ethyl toluene
3.8 m-Ethy 1 to! uene
12.0 o-Ethyl toluene
3.0 1, 3, 5-Tr1methyl benzene
12.0 1, 2 ,4-Trlmethyl benzene
3.8 1, 2, 3-Trlmethyl benzene
1.5 Methyl styrene
2.3 1,3-01 ethyl benzene
1.5 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefin
E Aromatic
z: Paraffin
Acetylene
ppbC %
70 8
175 21
575 69
11 1
831
ppbC
Total Unidentified 216
Hydrocarbons
Total NMHC by 1047
summing individual
species i
92
-------
TABLE D6. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 7/25/7®
ppbC
Hydrocarbon
ppbC
Hydrocarbon
42.0
(194.)
3.8
92.3
12.8
41.3
127.
3.0
2.3
2.3
118.
31.5
6.8
2.3
12.0
23.3
18.0
2.3
24.8
1.5
0.8
11.3
8.3
12.0
4.5
Ethane
Ethylene
Acetyl ene
Propane
Propene
i-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
6.8
9.0
36.0
7.5
8.3
6.8
6.0
38.3
3.8
3.8
3.0
7.5
3.0
4.5
13.5
3.0
6.0
6.0
2.3
8.3
3.8
3.0
6.8
2.3
12.8
3.8
2.3
1.5
1.5
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methyl eye 1ohexane <
2,4-0-1 methyl hexane
2,3,4-THme thy! pentane
Toluene
2,3-Pimethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
EthylCyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethyltoluene
o-Ethyl toluene
1,3,5-Tr1methylbenzene
1,2,4-Tr1methylbenzene
1,2,3-Trimethyl benzene
Methylstyrene
1,3-01ethyl benzene
1,4-D1ethylbenzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
£ Paraffin
Acetylene
ppbC
37
120
664
4
4
15
81
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
164
988
93
-------
TABLE D7. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 7/26/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.3
(35.3)
5.3
28.5
23
9.0
38.3
2.3
3.0
5.3
30.0
17.3
2.3
3.0
10.5
6.0
3.0
11.3
4.5
3.0
11.3
3.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methyl pentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
4.5
6.8
3.0
4.5
15.0
2.3
21.8
1.5
3.0
3.8
2.3
1.5
5.3
15.3
3.0
6.0
11.3
1.5
9.0
3.8
4.5
12.8
3.0
23.3
5.3
2.3
3.0
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methylcyclohexane
2,4-Dimethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-D1methylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Tr1methylbenzene
1,2,4-Trimethylbenzene
1,2,3-Trimethyl benzene
Methylstyrene
1,3-Diethyl benzene
1,4-Diethyl benzene
Total Identified
Hydrocarbons
z Olefin
£ Aromatic
i Paraffin
Acetylene
ppbC %
40
128
235
5
408
10
31
58
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species <
ppbC
164
572
941
-------
TABLE Da HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 7/27/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.3
(266. }
12.0
12.0
7.5
12.0
27.8
2.3
2.3
3.0
29.3
22.5
1.5
3.0
12.8
9.0
12.8
5.3
3.8
9.8
3.0
Ethane
Ethylene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
5.3 2,3-Dimethylpentane
6.0 3-Methylhexane
3.8 2,2,3-Trlmethylpentane
4.5 n-Heptane
3.8 Methylcyclohexane
2.3 2,4-DtmetHy1hexane
2,3,4-Trlmethylpentane
27.0 Toluene
1.5 2,3-Dimethylhexane
4.5 2-Methylheptane
3.0 3-Ethylhexane
3.0 n-Octane
0.8 Ethyl cyclohexane
9.8 Ethyl benzene
18.0 p & m-Xylene
3.0 Styrene
7.5 o-Xylene
6.0 n-Nonane
1-PropyTbenzene
3.8 n-Propylbenzene
4.5 p-Ethyltoluene
2.3 m-Ethyl toluene
32.3 o-Ethyltoluene
78.3 1,3,5-Trtmethylbenzene
21.0 1,2,4-Trimethy!benzene
21.0 1,2,3-Trfmethyl benzene
4.5 Methy!styrene
1,3-D1ethylbenzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefin
£ Aromatic
i Paraffin
Acetylene
ppbC
18
240
206
12
476
4
50
43
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
spectes* ;
ppbC
190
666
-------
TABLE D9. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 7/30/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.5
(302.)
10.5
20.0
7.5
10.0
27.0
2.0
2.5
1.5
28.5
17.5
2.0
3.0
11.5
8.5
12.0
5.0
3.0
32.0
3.0
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-D1methy1pentane
Benzene
Cyclohexane
4.5 2,3-Dimethylpentane
5.5 3-Methylhexane
3.5 2,2,3-Tr1methylpentane
4.0 n-Heptane
4.0 Methylcyclohexane
2.0 2,4-Dlmethylhexane
2,3,4-Tr1methylpentane
21.5 Toluene
1.0 2,3-Dlmethylhexane
3.0 2-Methylheptane
2.0 3-Ethylhexane
2.0 n-Octane
Ethylcyclohexane
4.0 Ethyl benzene
12.5 p 4 m-Xylene
2•0 Styrene
6-0 6-Xylene
3-0 n-Nonane
4.5 i-Propylbenzene
2.5 n-Propylbenzene
2.5 p-Ethyl toluene
2.5 m-Ethy1 to!uene
6.0 o-Ethyltoluene
4.5 1,3,5-Trlmethylbenzene
7.5 1,2,4-Trimethylbenzene
1.0 1,2,3-Trimethylbenzene
1.5 Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
E Olefln
i Aromatic
£ Paraffin
Acetylene
ppbC
17
107
194
_11
330
5
32
59
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
PPbC
53
383
-------
TABLE .010. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 7/31/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
11.0
(396. )
13.5
24.0
8.0
18.0
38.5
2.0
4.0
2.5
35.5
23.0
3.0
5.0
18.0
14.0
13.5
5.5
4.0
36.5
4.5
Ethane
fthyl.ene
Acetylene
Propane
Propene
i-Butane
n-Birtane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
^-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dtmethylbutane
2-Methylpentane
c-4^Me thyl -2 - pen tene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thy! eye 1 opentane
2,4-D1methylpentane
Benzene
Cyclohexane
6.0 2,3-Di methylpentane
7.5 3-Methylliexane
4.0 2,2,3-Trlmethylpentane
5.0 n-Heptawe
6.5 Methyl eye1ohexane
3.5 2,4-Dtmethylhexane
2,3,4-Trlmetihyl pentane
28.0 Toluene
1.5 2,3-Dimethylhexane
2.5 2-Methyl heptane
3.0 3-Ettiylhexane
2.5 n-Octane
Ethyl eye1ohexane
5.0 Ethyl benzene
14.5 p & m-Xylewe
2.5 Styrene
7.0 o-Xyl ene
5.5 n-Nonane
1.0 i-Propyl'benzene
3.5 n-Propylbenzene
3.0 p-Ethyl tol'uene
3.0 m-Ethy 1 to!uene
7.0 o-Ethylto!uene
6.0 1,3,5-Tr1methylbenzene
12.5 1,2,4-TrImethylbenzene
2.5 1,2,3-Trimethylbenzene
1.0 Methylstyrene
1,3-Olethyl'benzene
1.0 lf4-D1ethyl benzene
Total Identified
Hydrocarbons
l Olefin
£ Aromatic
l Paraffin
Acetylene
ppbC
20
131
266
4
430
30
62
1
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species !
ppbC
81
511
-------
TABLE Oil. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 8/1/79
ppbC
Hydrocarbon
Total Identified
Hydrocarbons
E Olefin
£ Aromatic
£ Paraffin
Acetylene
ppbC
85
115
637
11
10
14
75
1
ppbC
Hydrocarbon
37.0
(684.)
11.0
140.
58.5
63.0
163.
7.5
6.5
5.0
—
62.0
38.5
3.5
—
—
—
3.0
4.5
17.5
—
13.0
—
22.0
—
—
10.0
3.5
17.0
5.0
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1 -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2, 3-D1methyl butane
2-Methylpentane
c-4-Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye 1 opentane
2 ,4-Dimethyl pentane
Benzene
Cyclohexane
6.5
8.0
5.0
7.5
9.0
2.0
—
28.0
1.5
3.0
3.5
5.0
2.0
4.5
11.0
2.5
6.5
5.0
4.5
4.0
4.0
5.0
8.0
9.0
11.5
_ ~ •»
1.0
1.5
1.0
2, 3-Dime thyl pentane
3-Methyl hexane
2 ,2 ,3-Trlmethyl pentane
n-Heptane
Methyl cyclohexane
2 ,4-D1methyl hexane
2, 3, 4-Trlme thyl pentane
Toluene
2, 3-Dime thyl hexane
2-Me thyl heptane
3-Ethyl hexane
n-Octane
Ethyl cyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xyl ene
n-Nonane
1-P ropy 1 benzene
n-Propyl benzene
p-Ethyl toluene
m-Ethyl toluene
o-Ethyl toluene
1, 3, 5-Tr1me thyl benzene
1 ,2,4-Tr1methyl benzene
1 ,2,3 -Tri me thyl benzene
Me thyl styrene
1 ,3-D1ethyl benzene
1 ,4-01 ethyl benzene
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species >
ppbC
127
975
-------
TABLED12. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 8/2/7?
ppbC
Hydrocarbon
ppbC
Hydrocarbon
7.5
(175)
6.5
12.0
9.5
11.5
21.0
14.5
8.5
1.5
4.0
3.5
5.0
2.0
26.5
4.0
1.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dlmethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
2.0 2,3-Dimethylpentane
3.0 3-Methylhexane
2.5 2,2,3-Trlmethylpentane
2.0 n-Heptane
3.5 Me thy 1 eye 1 ohexane-
2.0 2,4-Dlmethylhexane
2,3,4-Tr1methylpentane
13.5 Toluene
2,3-Dimethylhexane
1.5 2-Methylheptane
1.0 3-Ethylhexane
1.5 n-Octane
Ethylcyclohexane
3.0 Ethyl benzene
10.5 p & m-Xylene
1.5 Styrene
5.0 o-Xylene
3.0 n-Nonane
1.0 1-Propylbenzene
2.0 n-Propylbenzene
4.0 p-Ethyl toluene
m-Ethyltoluene
4.5 o-Ethyltoluene
4.0 1,3,5-Tr1methylbenzene
7.5 1,2,4-Tr1methy.l benzene
1.0 1,2,3-Tr1methylbenzene
Methylstyrene
1,3-D1ethylbenzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefin
E Aromatic
z Paraffin
Acetylene
ppbC
11
60
140
7
217
5
28
65
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species:- !
ppbC
61
278
-------
TABLE D13. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 8/3/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
21.0
(613.)
11.5
46.5
14.0
25.5
59.0
4.5
5.5
3.0
51.0
37.0
2.7
5.0
18.0
13.0
19.0
8.0
5.0
31.5
5.5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
7.5 2,3-Dimethylpentane
9.5 3-Methylhexane
5.5 2,2,3-Trimethylpentane
6.0 n-Heptane
10.5 Methyl eyelohexane
3.5 2,4-Dimethylhexane
1.0 2,3,4-Trlmethylpentane
34.5 Toluene
2.0 2,3-Dimethylhexane
3.0 2-Methyl heptane
2.5 3-Ethylhexane
4.5 n-Octane
1.5 Ethyl eyelohexane
6.0 Ethyl benzene
18.0 p 4 m-Xylene
2.0 Styrene
9.0 o-Xylene
5.0 n-Nonane
5.0 1-Propylbenzene
4.5 n-Propylbenzene
3.5 p-Ethyl toluene
3.5 m-Ethyltoluene
7.5 o-Ethyltoluene
6.5 1,3,5-Tr1methylbenzene
13.0 l,2,4-Trimethylbenzene
2.5 1,2,3-Tr1methylbenzene
1.5 Methylstyrene
1.0 1,3-01ethyl benzene
1.0 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
L Olefln
z Aromatic
£ Paraffin
Acetylene
5
26
66
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species ,
ppbC
132
700
too
-------
TABLED! 4. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 8/4/79
ppbC
16.5
(889. )
7.5
35.0
13.5
27.0
56.0
7.0
29.5
11.0
56.5
34.0
—
—
—
—
1.5
2.5
10.5
—
7.0
10.5
—
—
3.5
1.5
10.0
2.0
Hydrocarbon
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
i-Butane
n-Butane
1-Butene
i-fiutene
t-2-Butene
c-2-Butene
1 -Pentane
n-Pentane
1-Pentene
t-2-PeiJtene
c-Z-Rentene
Cyclopemtene
Cyentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cycl opentane
2, 4-Dimethyl pentane
Benzene
Cycl ohexane
ppbC
4.0
4.5
3.5
3.5
2.5
2.0
0.5
18.0
1.0
2.5
2.0
1.5
—
3.5
9.5
1.5
4.5
2.0
1.5
2.0
3.5
— - —
4.5
4.0
6.0
2.0
1.0
1.0
1.0
Hydrocarbon
2 ,3-D1me thy! pentane
3-Methylhexane
2 ,2 ,3-Trlraethyl pentane
n-Heptane
Methyl eye 1 ohexane
2,4-Dlraethylhexane
2 ,3,4-Trifl»ethyl pentane
Tol uene
2 ,3-Dimethyl hexane
2 -Methyl heptane
3-Ethylhexane
n -Octane
Ethyl eye 1 ohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylfine
n-Nonane
1-Propyl benzene
n-Propylbenzene
p-Ethyl tol uene
m-Etnyl toluene
o-Ethyl tol upne
1 ,3, 5-Trlme thy 1 benzene
1 ,2,4-Trimethyl benzene
1 ,2,3-Trlroethyl benzene
Methyl styrene
1 ,3-01 ethyl benzene
1 ,4-01 ethyl benzene
Total Identified
Hydrocarbons
£ Olefin
£ Aromatic
£ Paraffin
Acetylene
ppbC %
64 15
71 16
294 67
8 2
Total
ppbC
Unidentified 96
Hydrocarbons
Total
NMHC by 532
summing individual
sripr-tAsc
10J
-------
TABLE Dl5..HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 8/5/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
11.5
(707.)
.5
.5
10.
12.
4.5
8.5
25.5
19.5
17.0
1.0
1.5
7.0
5.0
8.5
2.5
1.0
9.0
1.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methyl pentane
c-4-Methyl-2-pentene
3-Methyl pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
3.0 2,3-Dimethylpentane
3.5 3-Methylhexane
2.5 2,2,3-Trlmethylpentane
3.0 n-Heptane
3.0 Methylcyclohexane
1.5 2,4-Dimethylhexane
2,3,4-Tr1methylpentane
20.5 Toluene
1.0 2,3-Dimethylhexane
1.0 2-Methyl heptane
1.5 3-Ethylhexane
1.5 n-Octane
Ethylcyclohexane
3.5 Ethyl benzene
11.5 p & m-Xylene
1.0 Styrene
5.0 o-Xylene
2.0 n-Nonane
1.0 i-Propylbenzene
1.5 n-Propylbenzene
2.0 p-Ethyltoluene
2.0 m-Ethyltoluene
4.0 o-Ethyltoluene
3.0 l,3,5-Trimethylbenzene
5.0 1,2,4-Trimethylbenzene
1.0 1,2,3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
i Paraffin
Acetylene
ppbC
5
68
146
11
230
2
30
63
5
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
PpbC
25
255
102
-------
TABLE D16. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 8/6/79-"
ppbC
15.5
(573.)
23.0
29.5
15.5
24.0
60.0
6.0
7.5
3.5
—
62.0
41.0
5.0
—
—
3.5
5.0
22.0
—
15.0
—
19.5
1.5
1.0
8.5
4.5
17.0
4.5
Hydrocarbon
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1 -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i -Pentane
n-Pentane
1 -Pentene
t-2-Pentene
c-2-Pentene
Cycl opentene
Cycl opentane
2, 3-Dimethyl butane
2 -Methyl pentane
c-4-Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cycl opentane
2, 4-Di methyl pentane
Benzene
Cycl ohexane
ppbC Hydrocarbon
9.5 2, 3-Dimethyl pentane
10.5 3-Methylhexane
7.0 2,2,3-Trimethylpentane
7.5 n-Heptane
8.5 Me thy! cycl ohexane
4.0 2,4-Dimethylhexane
1.5 2,3,4-Trlmethylpentane
32.5 Toluene
2.0 2,3-Dimethylhexane
6.0 2-Methyl heptane
4.5 3-Ethyl hexane
4.0 n -Octane
1 . 5 Ethyl eye 1 ohexane
7 . 0 Ethyl benzene
20.5 p 4 m-Xylene
3.5 Styrene
10.5 o-Xylene
4.5 n-Nonane
1.5 1-Propyl benzene
4.0 n-Propyl benzene
9.0 p-Ethyl toluene
4 . 0 m-Ethyl to! uene
9 . 5 o-Ethyl tol uene
2.0 1, 3, 5-Tr1methyl benzene
12.0 1, 2, 4-Tri methyl benzene
2.0 1, 2, 3 -Tri methyl benzene
2.0 Methyl styrene
1.5 1, 3 -D1 ethyl benzene
2.0 1, 4-DI ethyl benzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
z Paraffin
Acetylene
ppbC %
46 8
135 23
384 65
23 4
""""PKH
ppbC
Total Unidentified 103
Hydrocarbons
Total NMHC by 691
summing individual
species^ •.
103
-------
TABLE D191 HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 8/7/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
.5
.5
9.0
(1060.0)
5.0
18.0
5.5
18.
39.
2.5
3.0
2.0
35.5
21.0
2.0
1.5
2.5
11.5
7.5
10.0
4.0
3.5
8.0
2.5
Ethane
Ethyl ene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
MethylI eye 1 opentane
2,4-Dimethy1pentane
Benzene
Cyclohexane
4.5
5.5
3.5
4.0
3.5
2.0
0.
22.
1
.5
.5
0
3.0
2.0
2.0
4.5
13.5
2.0
6.0
2.5
5.0
2.0
5.0
2.0
7.0
1.0
1.0
1.5
1.0
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methylcyclohexane
2,4-D1methy1hexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethy1toluene
o-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
i Paraffin
Acetylene
ppbC
18
89
219
5
5
27
66
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
PPbC
39
369
104
-------
TABLE D18. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 8/8/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
17.5
(239.)
11.0
42.5
14.0
29.0
71.0
3.0
4.0
2.0
53.0
35.0
3.0
2.5
4.0
19.5
12.5
18.0
8.0
3.5
12.5
4.5
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-01methy!butane
2-Methyl pentane
c-4-Methyl-2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dtnethylpentane
Benzene
Cyclohexane
6.0
7.5
4.0
6.0
5.5
2.0
1.0
23.0
1.5
4.0
3.0
3.0
1.0
4.0
12.0
1.5
5.5
2.5
1.0
1.5
2.0
2.5
3.0
3.0
3.5
2,3-Dlmethylpentane
3-Methy]hexane
2,2,3-THmethyl pentane
n-Heptane
Me thy 1 eye i| ohexane
2,4-Dimethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dfmethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene >
p A m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Trtmethy1 benzene
1,2.3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefin
£ Aromatic
i Paraffin
Acetylene
ppbC
28
74
368
11
481
15
77
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
PPPC
26
567
185
-------
TABLE Dl9, HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 8/9/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.5
(575.)
11.0
17.0
9.5
16.5
39.5
5.5
5.0
2.5
38.0
27.5
2.0
4.0
14.5
11.0
14.0
6.0
3.5
6.5
4.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
7.0 2,3-Dimethylpentane
8.0 3-Methylhexane
5.0 2,2,3-Trlmethylpentane
5.5 n-Heptane
6.5 Methyl cyclohexane
2.5 2,4-Dimethylhexane
1.0 2,3,4-Trlmethylpentane
27.5 Toluene
1.5 2,3-Dimethylhexane
4.0 2-Methylheptane
3.0 3-Ethylhexane
3.0 n-Octane
1.0 Ethylcyclohexane
4.5 Ethyl benzene
12.5 p * m-Xylene
2.0 Styrene
7.0 o-Xylene
3.0 n-Nonane
1.0 1-Propylbenzene
2.5 n-Propylbenzene
5.5 p-Ethyltoluene
1.5 m-Ethyltoluene
6.5 o-Ethyltoluene
4.5 1,3,5-Tr1methylbenzene
9.0 1,2,4-Trimethylbenzene
2.0 1,2,3-Trlmethylbenzene
1.5 Methylstyrene
1.0 1,3-DIethyl benzene
1.0 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefin
E Aromatic
£ Paraffin
Acetylene
ppbC
26
94
257
11
"357
7
24
66
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
65
452
106
-------
TABLE D20. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 8/10/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
9.8
(258.) .
—
24.8
10.5
10.5
30.8
—
—
—
—
22.5
12.8
—
—
—
1.5
3.0
7.5
—
4.5
8.3
8.3
—
2.3
3.0
3.0
20.3
3.8
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
i -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2, 3-D1methyl butane
2-Methyl pentane
c-4-Methyl -2-pentene
3-Me thy! pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cycl opentane
2 ,4-D1methyl pentane
Benzene
Cycl ohexane
3.0
3.8
3.8
3.0
3.8
0.8
—
19.5
0.8
2.3
1.5
1.5
—
2.3
7.5
0.8
3.0
1.5
—
0.8
1.5
1.5
2.3
2.3
2.3
—
—
—
—
2, 3-Dimethyl pentane
3-Methyl hexane
2 ,2 ,3-Trimethyl pentane
n-Heptane
Methyl eye 1-ohexane /.
2, 4-Dimethyl hexane
2,3,4-Trimethylpentane
Toluene
2 , 3-Dimethyl hexane
2 -Methyl heptane
3-Ethyl hexane
n -Octane
Ethyl cycl ohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xyl ene
n-Nonane
1-Propyl benzene
n-Propyl benzene
p- Ethyl toluene
m- Ethyl toluene
o-Ethyl tol uene
1, 3, 5-Trimethyl benzene
1, 2, 4-Trimethyl benzene
1, 2, 3-Trimethyl benzene
Methyl styrene
1 ,3-DI ethyl benzene
1 ,4-D1 ethyl benzene
Total Identified
Hydrocarbons
z Olefln
i Aromatic
i Paraffin
Acetylene
ppbC %
23
63
170
"257
9
25
66
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
s.pecies ,
ppbC
51
308
107
-------
TABLE D21. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 8/14/79
ppbC
Hydrocarbon
Total Identified
Hydrocarbons
i Oleffn
z Aromatic
E Paraffin
Acetylene
ppbC
26
51
293
7
14
78
1
ppbC
Hydrocarbon
28.5
(866.)
5.3
69.0
24.8
27.8
51.8
—
—
30.0
18.8
—
—
—
1.5
2.3
9.0
—
6.0
—
9.0
—
—
4.5
3.8
7.5
2.3
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2 ,3-D1methyl butane
2-Methylpentane
c-4-Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye 1 open tane
2 ,4-D1methyl pentane
Benzene
Cyclohexane
3.8
4.5
3.8
3.8
3.0
1.5
___
13.5
0.8
1.5
1.5
2.3
1.5
3.0
6.0
1.5
3.8
2.3
1.5
1.5
1.5
2.3
3.8
1.5
5.3
—
—
—
—
2 ,3-D1methyl pentane
3-Methyl hexane
2, 2, 3-Tr1me thyl pentane
n-Heptane
Methyl eye 1 ohexane
2, 4 -Dime thyl hexane
2, 3, 4-Tr1me thyl pentane
Toluene
2, 3-D1me thyl hexane
2 -Me thyl heptane
3-Ethyl hexane
n -Octane
Ethyl cyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xyl ene
n-Nonane
1-Propyl benzene
n-Propyl benzene
p-Ethyl toluene
m-Ethyl tol uene
o-Ethyl toluene
1,3, 5-Tr Imethyl benzene
1, 2, 4-Trlme thyl benzene
1, 2, 3-Tr Imethyl benzene
Me thyl styrene
1 ,3-D1 ethyl benzene
1,4-01 ethyl benzene
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species •.
ppbC
44
419
108
-------
TABLE D22. HYDROCARBON CONCENTRATIONS IN 0800-0900 INDUSTRIAL SITE SAMPLE ON 8/15/7'S
ppbC
Hydrocarbon
ppbC
Hydrocarbon
10.0
(272. )
11.5
16.0
9.5
12.5
30.5
28.5
20.0
2.0
2.5
11.0
7.0
10.0
4.5
2.5
9.5
3.0
Ethane
Ethyl ene
Acetyl ene
Propane
Propane
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
5.0 2,3-D1methylpentane
5.5 3-Methylhexane
3.5 2,2,3-Trimethylpentane
5.0 n-Heptane
4.5 Methylcyclohexane i
1.5 2,4-Dimethylhexane
2,3 ,'4-Tr1methyl pentane
18.0 Toluene
1.0 2,3-Dimethyl hexane
3.5 2-Methylheptane
2.5 3-Ethylhexane
3.0 n-Octane
1.0 Ethyl eye1ohexane
3.5 Ethyl benzene
12.0 p & m-Xylene
1.5 Styrene
5.0 o-Xylene
1•5 n-Nonane
1-Propylbenzene
2.0 n-Propylbenzene
2.0 p-Ethyl toluene
2.5 m-Ethyltoluene
4.5 o-Ethy!toluene
2.5 1,3,5-Trlmethy1 benzene
2.5 1,2,4-Trimethylbenzene
1,2,3-Tr1roethylbenzene
Methylstyrene
1,3-D1ethyl benzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
l Oleftn
i Aromatic
l Paraffin
Acetylene
ppbC
n
64
216
12
302
4
21
72
4
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species .
ppbC
14
316
109
-------
APPENDIX E
Individual Hydrocarbon Concentrations in Afternoon (1400-1500)
Integrated Samples
-------
TABLE El . HYDROCARBON CONCENTRATIONS IN 1400-1500 INDUSTRIAL SITE SAMPLE ON 8/2/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
9.0
(75.5 )
5.5
15.0
5.5
11.5
32.5
2.0
3.0
2.0
31.5
28.0
1.5
1.5
8.0
5.5
7.0
3.5
2.0
7.5
2.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methyl pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dlmethy1pentane
Benzene
Cyclohexane
3.5 2,3-Dimethylpentane
4.0 3-Methylhexane
3.5 2,2,3-Trlmethylpentane
2.5 n-Heptane
5.0 Methylcyclohexane
1.5 2,4-D1methylhexane
2,3,4-Trlmethylpentane
15.0 Toluene
2,3-D1methylhexane
2.0 2-Methyl heptane
1.5 3-Ethylhexane
1.5 n-Octane
Ethylcyclohexane
2.5 Ethyl benzene
9.0 p X ro-Xylene
1.5 Styrene
4 0 o-Xylene
4.5 n-Nonane
1-Propylbenzene
2.5 n-Propylbenzene
2.0 p-Ethyltoluene
2.0 m-Ethyltoluene
5.0 o-Ethyltoluene
4.0 1,3,5-Trlmethy1 benzene
15.5 1,2,4-Tr1methylbenzene
2.0 1,2,3-Trlmethylbenzene
1.0 Methylstyrene
1.0 1,3-01ethyl benzene
1.0 1,4-01ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
i Paraffin
Acetylene
ppbC %_
15
75
187
6
283
5
27
66
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
61
344
111
-------
TABLE E2 . HYDROCARBON CONCENTRATIONS IN 1400-1500 INDUSTRIAL SITE SAMPLE ON 8/8/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
7.0
(55.5 )
3.5
9.0
6.0
12.5
32.5
4.5
5.5
21.5
17.0
1.5
2.0
9.5
6.5
10.0
3.0
1.5
7.5
2.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyelopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dlmethy1pentane
Benzene
Cyclohexane
3.5 2,3-D tmeithy 1 pentane
4.0 3-Methylhexane:
3.0 2,2,,3-Trlmethylpentane
3.5 n-Hepfane
3.5 Methyl eyeloffexane
1.5 2,4-Dlmethylhexane
2,3,4'-Tr1methyl pentane
15.5 Toluene
1.0 2,3-D1methylhexane
3.0 2-Methyl heptane
2.0 3-Ethylhexane
2.0 n-Octane
Ethyl cyclohexane
3.5 Ethyl benzene
10.5 p i ra-Xylene
2.0 Styrene
5.5 o-Xylene
2.5 n-Nonane
1-Propylbenzene
2.5 n-Propylbenzene
4.5 p-Ethyltoluene
m-Ethyltoluene
5.5 o-Ethy!toluene
2.0 1.3,5-Trlwethylbenzene
9.0 1,2,4-Tr1methylbenzene
1.0 1,2,3-Trtmethy 1benzene
1.5 Methylstyrene
1.5 1,3-01ethyl benzene
1.5 1,4-01ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
i Paraffin
Acetylene
ppbC *
20
69
165
4
257
8
27
64
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing in-dividual
species i
PPbC
49
306
112
-------
TABLE E3. HYDROCARBON CONCENTRATIONS IN 1400-1500 INDUSTRIAL SITE SAMPLE ON 8/10/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
16.5
(64.5)
6.0
30.8
6.0
15.8
49.8
24.0
19.5
1.5
3.0
8.3
6.0
10.5
3.0
3.8
8.3
2.3
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-01methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
3.0 2,3-Dimethylpentane
3.8 3-Methylhexane
3.8 2,2,3-Trlmethylpentane
3.8 n-Heptane
3.0 Methyl cyclohexane
1.5 2,4-Dlmethylhexane
2,3,4-Trlmethylpentane
15.0 Toluene
0.8 2,3-Olmethylhexane
2.3 2-Methylheptane
1.5 3-Ethylhexane
2.3 n-Octane
Ethylcyclohexane
3.8 Ethyl benzene
10.5 p 4 m-Xylene
1.5 Styrene
4.5 o-Xyl ene
3.0 n-Nonane
1.5 1-Propylbenzene
3.0 n-Propylbenzene
2.3 p-Ethyltoluene
3.0 m-Ethyltoluene
5.3 o-Ethyltoluene
2.3 1,3,5-Trlnethylbenzene
9.8 1.2,4-Tr1methyl benzene
0.8 1,2,3-Trlmethyl benzene
1.5 Methylstyrene
1.5 1,3-01ethyl benzene
1.5 1,4-01ethyl benzene
Total Identified
Hydrocarbons
i Olefln
i Aromatic
i Paraffin
Acetylene
ppbC
9.
75
232
__.6
322
3
23
72
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
68
390
113
-------
TABLE E4 . HYDROCARBON CONCENTRATIONS IN 1400-1500 INDUSTRIAL SITE SAMPLE ON 8/14/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
15.0
( 98.5 )
4.5
19.5
4.0
11.0
23.5
17.0
14.0
1.0
1.5
6.5
4.0
9.0
2.5
2.0
6.0
2.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methyl pentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
2.0 2,3-Dimethylpentane
2.5 3-Methylhexane
1.5 2,2,3-Trlmethylpentane
2.5 n-Heptane
2.0 Methylcyclohexane
1.0 2,4-Dlmethylhexahe
2,3,4-Tr1methylpentane
11.5 Toluene
2,3-Dimethylhexane
2.0 2-Methylheptane
1.0 3-Ethylhexane
1.5 n-Octane
Ethylcyclohexane
2.0 Ethyl benzene
6.5 p A ro-Xylene
Styrene
2.5 o-Xylene
1.5 n-Nonane
1-Propylbenzene
1.0 n-Propylbenzene
1.0 p-Ethyl toluene
1.5 m-Ethyltoluene
2.5 o-Ethy1toluene
1.5 1,3,5-Tr1methylbenzene
2.0 1,2,4-Tr1methylbenzene
1,2.3-Trlmethyl benzene
Methyl styrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefln
I Aromatic
£ Paraffin
Acetylene
ppbC ^
4
37
146
5
193
2
19
76
3
Total Unidentified.
Hydrocarbons
Total NMHC by
.summing individual
species i
ppbC
10
203
114
-------
TABLE E5 . HYDROCARBON CONCENTRATIONS IN 1400-1500 FRANKLIN INSTITUTE SAMPLE ON
8/2/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.5
(60.5)
7.0
14.0
5.5
18.0
36.5
30.5
26.5
1.5
2.9
9.5
5.5
10.0
3.5
5.0
6.0
5.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
3.0
3.5
3.0
4.0
5.5
2.0
0.5
26.0
3.5
22.0
16.0
10.0
3.0
6.0
13.5
4.0
6.5
4.0
1.0
2.0
2.5
2.0
4.0
2.5
6.0
1.0
2,3-Dimethyl pentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methylcyclohexane
2,4-Dimethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethyl hexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
tn-Ethyl tol uene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Trimethy1 benzene
1,2,3-Trimethylbenzene
Methy!styrene
1,3-DIethyl benzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
£ Olefln
i Aromatic
E Paraffin
Acetylene
ppbC %
10
79
257
7
352
3
22
73
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species
ppbC
70
422
115
-------
APPENDIX F
Individual Hydrocarbon Concentrations in Roving Samples
Collected in Philadelphia Area
-------
TABLE Fl . HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED AT 0730 ON 7/18/79
NEAR DOWNINGTOWN PENNSYLVANIA
ppbC
Hydrocarbon
ppbC
Hydrocarbon
32.5
( 254.)
8.0
95.5
30.5
63.0
133.
5.0
4.0
3.0
71.5
38.0
2.5
3.5
4.0
16.5
12.0
1.5
16.0
7.5
3.0
11.0
4.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-D1methy1pentane
Benzene
Cyclohexane
9.0
12.0
6.0
9.5
7.0
2.0
1.5
25.0
1.5
3.0
5.0
7.0
5.0
10.0
2.5
11.0
3.5
6.5
14.0
5.5
3.5
2.0
5.5
2.0
4.0
2,3-Dimethyl pentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-Dimethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-D1methyl hexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-THmethyl benzene
1,2,3-Trlmethyl benzene
Methylstyrene
1,3-01ethyl benzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
z Olefln
£ Aromatic
i Paraffin
Acetylene
ppbC
53
101
568
8
730.
7
14
78
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
PPbC
180
910
117
-------
TABLE F2 . HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED AT 1140 ON
7/25/79 IN WEST PHILADELPHIA
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.0
6.0
6.0
23.5
6.0
26.5
155
6.5
5.0
11.5
145
80.0
12.5
2..0
6.5
8.5
32.0
3.0
23.
14.
21.
3.5
1.5
15.5
5.4
20.0
5.0
.5
.5
.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Me thy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thy1 eye1opentane
2,4-Dlmethy1pentane
Benzene
Cyclohexane
14.0
15.5
10.
11.
.5
,5
8.5
5.0
3.0
.5
.0
76.
3.
10.0
8.5
7.5
17.5
51.5
7.0
9.0
17.0
11.0
30.5
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trlroethyl pentane
n-Heptane
Methy! eye 1ohexane j
2,4-Dtmethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p A m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Tr1methylbenzene
1,2,4-Tr1methylbenzene
1,2,3-Trtraethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
£ Olefln
£ Aromatic
£ Paraffin
Acetylene
ppbC
74
284
676
6
1040
%
7
27
65
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing 1ndiv idual
species i
PPbC
230
1270
118
-------
TABLE F3 . HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED AT 1015 ON 8/2/79
IN NE PHILADELPHIA
ppbC
Hydrocarbon
ppbC
Hydrocarbon
5.5
10.0
5.5
12.0
5.0
11.0
29.0
27.0
16.5
1.5
2.0
9.0
3.0
8.5
3.0
1.5
5.0
1.5
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyleye1opentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
3.0
4.5
.4.0
2.5
2.0
1.5
12.5
1.0
1.0
1.5
1.0
3.5
9.5
1.0
4.0
1.5
2.0
1.5
4.5
1.0
2.0
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Tr1roethylpentane
n-Heptane
Methylcyclohexane
2,4-Olmethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-Olmethyl hexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xyl ene
n-Nonane
1-Propy 1 benzene
n-Propylbenzene
p-Ethyltoluene
m-Ethy1toluene
o-Ethyltoluene
1,3,5-Trimethylbenzene
1,2.4-Tr1methylbenzene
1,2.3-Tr1n»ethyl benzene
Methylstyrene
1,3-D1ethylbenzene
l,4-D1ethylbenzene
Total Identified
Hydrocarbons
i: Olefln
z Aromatic
z: Paraffin
Acetylene
ppbC ^
16
47
152
6
221
7
21
69
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
PPbC
48
269
119
-------
TABLE F-4 . HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED ON 8/2/79 IN
SW PHILADELPHIA
ppbC
Hydrocarbon
Total Identified
Hydrocarbons
E Olefln
z Aromatic
£ Paraffin
Acetylene
ppbC ^
14
16
134
3
167
9
10
80
1
ppbC
Hydrocarbon
9.5
2.0
2.5
21.0
12.5
8.5
38.0
—
—
—
17.0
11.0
—
—
—
—
1.0
1.0
4.5
—
2.5
—
5.5
__ _
2.0
_ _ _
2.0
1.0
Ethane
Ethyl ene
Acetylene
Propane
Propene
1 -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1 -Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2, 3-D1methyl butane
2-Methy 1 pentane
c-4 -Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cycl opentane
2, 4-D1methyl pentane
Benzene
Cyclohexane
1.5
1.5
2.0
1.5
1.0
1.5
—
5.0
—
1.0
0.5
—
—
1.5
3.0
—
1.5
— — —
1r-
.5
— — —
1.5
— — —
1.5
_ _ —
_ _ —
_ _ _
_ _ _
2 ,3-Dimethyl pentane
3-Methyl hexane
2 , 2. 3-TH methyl pentane
n-Heptane ;
Methyl eye 1 ohexane
2 ,4-D1methyl hexane
2 ,3,4-Tr1methyl pentane
Toluene
2, 3-D i methyl hexane
2 -Methyl heptane
3-Ethyl hexane
n-Octane
Ethyl cycl ohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xyl ene
n-Nonane
1-Propyl benzene
n-Propyl benzene
p-Ethyl toluene
m- Ethyl tol uene
o-Ethyl toluene
1, 3, 5 -Tr1 methyl benzene
1 ,2,4-Tr1methyl benzene
1 , 2, 3-Trlmethyl benzene
Methyl styrene
1,3-01 ethyl benzene
1 ,4-01 ethyl benzene
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
11
178
120
-------
TABLE F5 . HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED AT 1200 ON 8/4/79
AT FLAT,ROCK PARK; NW PHILADELPHIA
ppbC
Hydrocarbon
ppbC
Hydrocarbon
7.0
.8.0
9.0
16.5
3.0
11.5
29.5
25.5
15.5
1.0
1.5
7.5
4.5
9.0
2.5
2.0
5.5
1.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dlmethylbutane
2-Methylpentane
c-4-Methy!-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye 1 open tane
2,4-D1methylpentane
Benzene
Cyclohexane
3.0
3.0
3.0
2.5
1.5
1.0
13.5
0.5
1.5
2.5
1.0
2.0
4.5
2.5
.0
.0
1.0
2.0
1.0
1.0
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Tr1methylpentane
n-Heptane
Methyl eye1ohexane
2.4-01methylhexane
2,3,4-TMmethyl pentane
Toluene
2,3-D1methylhexane
2-Me thylheptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p & ra-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Tr1methylbenzene
1,2,3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
I Olefln
l Aromatic
£ Paraffin
Acetylene
ppbC
11
36
154
9
210
5
17
74
4
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
12
222
121
-------
TABLE F6 . HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED AT 1355 ON
8/4/79 IN NW PHILADELPHIA
ppbC
Hydrocarbon
ppbC
Hydrocarbon
5.5
2.0
5.0
9.0
3.5
4.5
11.0
8.0
6.0
2.5
1.0
1.0
5.5
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye 1 opentane
2,4-Diroethylpentane
Benzene
Cyclohexane
2,3-01methylpentane
3-Methylhexane
2,2,3-Trlraet'hyl pentane
n-Heptane
Methyl eyelohexane
2,4-Dimethylhexane
2,3,4-Trlmethylpentane
4.0 Toluene
2,3-Dimethyl hexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethyl eyelohexane
Ethyl benzene
p A m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-PropyTbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trlrnethyl benzene
1-5 i,2,4-TMmethyl benzene
1,2,3-Trinethylbenzene
Methy Is^yrene
1,3-01ethyl benzene
1.4-01ethyl benzene
Total Identified
Hydrocarbons
£ Olefin
£ Aromatic
£ Paraffin
Acetylene
ppbC %_
5
11
49
5
8
15
70
7
Total Unidentified
Hydrocarbons
Total NMHC by
summing, 1 ndl v, 1 dual.
species i
ppbC
. 49
119
70
122
-------
TABLE F7 . HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED AT 0700 ON 8/5/79
NEAR DOWNINGTOWN, PENNSYLVANIA
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.5
2.5
5.0
11.5
2.5
7.0
15.5
15.0
9.0
0.5
1.0
5.5
3.0
5.0
1.5
3.0
1.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methyl pentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
1.5
1.5
2.0
1.0
1.0
6.0
1.0
0.5
1.5
3.5
1.5
1.0
2.0
2.5
2.0
2.5
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-Dlmethylhexane
2,3,4-Tr line thy 1 pentane
Toluene
2,3-Dlmethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p A m-Xylene
Styrene
o-Xyl ene
n-Nonane
i-Propy1 benzene
n-Propy1 benzene
p-Ethyl toluene
m-Ethyltoluene
o-Ethyltoluene
1,3.5-Trlmethylbenzene
1,2,4-Trlraethylbenzene
1,2.3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1.4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefln
1 Aromatic
£ Paraffin
Acetylene
ppbC
5
24
93
5
128
4
19
73
4
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
PPbC
21
149
123
-------
TABLE F8 , HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED ON 8/6/79
IN NW PHILADELPHIA
ppbC
Hydrocarbon
ppbC
Hydrocarbon
8.0
2.5
3.0
7.5
5.5
11.5
10.5
7.0
0.5
4.0
2.0
4.5
1.0
2.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Peritene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-01methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye1opentane
2,4-Dimethylpentane
Benzene
Cyclohexane
1.0
1.5
2.0
1.5
1.0
1.0
7.0
1.0
1.0
2.5
1.5
1.0
1.0
1.0
2,3-Dimethyl,pentane
3-Methylhexane
2 i/l, 3-Tttraethyl pentane
n-Heptane
Me thylcyc1ohexane
2,4-Dimethylhexane
2,3,4-Tr1methylpentane
Toluene
2,3-D1methylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p A m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluehe
1,3,5-Tri me thylbenzene
1,2,4-Tr1raethylbenzene
1,2,3-Tri me thylbenzene
Methylstyrene
1.3-Dtethyl benzene
1,4-DIethyl benzene
Total Identified
Hydrocarbons
£ Olefln
I Aromatic
E Paraffin
Acetylene
ppbC ^
2
17
71
3
3
18
76
3
94
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
8
102
124
-------
TABLE F9 . HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED 1305 ON
8/7/79 AT FLAT ROCK PARK; NW PHILADELPHIA
BpbC
Hydrocarbon
ppbC
Hydrocarbon
4.0
2.5
4.0
4.5
6.5
12.5
13.5
6.5
0.5
1.0
4.0
2.0
4.5
1.0
2.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methy 1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
1.5 2,3-Dimethylpentane
1^5 3-Methylhexane
4*0 2,2,3-Trlmethylpentane
1." 5 n-Heptane
Methyl eye 1ohexane
2,4-Dlmethylhexane
2,3,4-Trlroethylpentane
6.5 Toluene
2,3-Dlroethylhexane
1.0 2-Methyl heptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
1.0 Ethyl benzene
2.0 p A ra-Xylene
Styrene
1.5 o-Xyl ene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
n-Ethy1toluene
o-Ethyltoluene
1,3,5-Trlnethylbenzene
1.0 1,2,4-Tr1roethylbenzene
1,2,3-Tr1«ethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
£ Olefln
I Aromatic
J: Paraffin
Acetylene
ppbC
3
14
70
4
3
16
77
4
92
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
16
108
125
-------
TABLE F10. HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED AT 1345 ON
8/7/79 AT JUNCTION OF HIGHWAYS 252 AND 202
ppbC
Hydrocarbon
ppbC
Hydrocarbon
4.5
2.5
1.5
4.5
2.0
7.0
22.5
19.0
10.0
0.5
1.0
4.0
2.5
5.0
1.0
1.0
2.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2.3-D1«ethy1butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-01•ethylpentane
Benzene
Cyclohexane
1.0
1.5
2.0
1.0
7.5
1.5
2.0
1.0
1.5
0.5
1.0
1.0
2,3-D1methy 1 pentane
3-Methylhexane
2,2,3-Tr1methylpentane
n-Heptane
MethylQyctohexane •
2,4-D1methylhexane
2.3.4-Trlmethylpentane
Toluene
2,3-Dlnethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethyl eyelohexane
Ethyl benzene
p A m-Xylene
Styrene
o-Xyl ene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
••Ethyl toluene
o-Ethyltoluene
1.3.5-Tr1«ethylbenzene
1.2.4
-------
TABLE Fll. HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED ON 8/10/79
NEAR WEST CHESTER PENNSYLVANIA
ppbC
Hydrocarbon
ppbC
Hydrocarbon
6.8
5.3
18.0
3.0
57.0
149
6.8
12.0
6.0
125
62.3
14.3
5.3
1.5
7.5
9.8
45.8
3.8
30.0
2.3
30.8
3.8
1.5
24.0
5.3
11.3
8.3
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Hethyl pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye1opentane
2,4-D1raethylpentane
Benzene
Cyclohexane
16.5 2,3-D1methylpentane
18.8 3-Methylhexane
6.0 2,2,3-THmethylpentane
12.8 n-Heptane
13.5 Methyl cyclohexane
3.0 2,4-Dimethylhexane
2.3 2,3,4-Trlmethylpentane
24.0 Toluene
3.0 2,3-Dimethylhexane
8.3 2-Methylheptane
6.0 3-Ethylhexane
3.8 n-Octane
1-5 Ethyl cyclohexane
6.0 Ethyl benzene
15.0 p 4 m-Xylene
3.0 Styrene
7.5 o-Xylene
•8 n-Nonane
1-Propylbenzene
n-Propylbenzene
3.0 p-Ethyl toluene
1 • 5 m-Ethyltoluene
1.5 o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Tr1methy1benzene
1,2,3-Trlmethylbenzene
— Methylstyrene
1,3-01ethyl benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
£ Paraffin
Acetylene
ppbC ^
69
70
675
814
8
9
83
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species i
ppbC
93
907
127
-------
TABLE F12. HYDROCARBON .CONCENTRATIONS IN SURFACE SAMPLE COLLECTED ON 8/14/79
NEAR WEST CHESTER PENNSYLVANIA
ppbC
Hydrocarbon
ppbC
Hydrocarbon
9.8
18.0
15.8
15.8
7.5
7.5
23.3
27.8
14.3
1.5
2.3
9.0
5.3
7.5
3.8
1.5
6.8
2.3
Ethane
Ethylene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thy!eye1opentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
3,0 2,3-Dimethylpentane
3^8 3-Methylhexaf
l."5 2,4~D1methyl(hexane
2,3,4-Trtroethylpentane
13.5 Toluene
.8 2,3-Dlmethylhexane
1.5 2-Methyl heptane
1.5 3-Ethylhexane
1.5 n-Octane
Ethyl eye1ohexane
3.0 Ethyl benzene
7.5 p A ra-Xylene
.8 Styrene
3.0 o-Xylene
n-Nonane
1-Propylbenzene
.8 n-Propylbenzene
2.3 p-Ethyl toluene
1.5 B-Ethy1 toluene
5.3 o-Ethyltoluene
1.5 1,3,5-Tr1methyl benzene
1.5 1,2,4-Tr1nethylbenzene
1,2,3-Tr1methylbenzene
Methyl styrene
l,3-D1ethylbenzene
1,4-DIethyl benzene
Total Identified
Hydrocarbons
E Olefln
£ Aromatic
£ Paraffin
Acetylene
ppbC %
26
47
155
16
244
11
19
64
6
Total Unidentified.
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
32
276
128
-------
TABLE FT 3 . HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED AT 0950 ON
8/16/79 AT FLAT ROCK PARK; NW PHILADELPHIA
ppbC
Hydrocarbon
ppbC
Hydrocarbon
3.5
2.0
13.5
11.
12.
16.0
8.0
.5
.5
5.0
3.0
1.5
1.0
1.5
1.0
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye1opentane
2,4-D1methy1pentane
Benzene
Cyclohexane
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trf methylpentane
n-Heptane
Methylcyclohexane
2,4-Olmethylhexane
2,3,4-Tr1methylpentane
3.5 Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
1-0 Ethyl benzene
2.0 p A m-Xylene
Styrene
1.0 o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
ra-Ethyl toluene
0.5 o-Ethyltoluene
1,3,5-Trlmethyl benzene
1-0 1,2,4-Tr1methylbenzene
1,2,3-Trlmethyl benzene
Methyl styrene
1,3-01ethyl benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
z: Olefln
I Aromatic
i Paraffin
'Acetylene
ppbC %
16
11
58
15
Total Unidentified
Hydrocarbons
Total NMHC by
sumnlng Individual
species i
ppbC
5
94
129
-------
TABLE F14. HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED AT 1150 ON
8/16/79 IN SE PHILADELPHIA
ppbC
Hydrocarbon
ppbC
Hydrocarbon
3.5
2.0
2.5
2.5
6.0
5.5
3.0
2.0
1.0
2.0
2.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methy 1pentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
5.5
1.0
1.5
1.0
2.0
2,3-Dimethyl pentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methylcyclohexane
2,4-D1methy1hexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethyl eye 1ohexane
Ethyl benzene
p & ra-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethy1toluene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Tr1methylbenzene
1,2.3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
L Olefln
I Aromatic
£ Paraffin
Acetylene
ppbC j>
2.0
13.0
28.0
43
4
30
66
Total Unidentified
Hydrocarbons
Total NMHC by
suimring individual
species i
ppbC
8
51
130
-------
APPENDIX G
Individual Hydrocarbon Concentrations in Helicopter Samples
fnllprtpH hv FPA-I V
Collected by EPA-LV
131
-------
HYDROCARBON GRAB SAMPLE LIST
DATE
23 July
23 July
25 July
25 July
4 Aug
TIME
(EOT)
79
79
79
79
79
13
13
15
16
07
07
10
11
11
11
:06:
:08:
:58:
:01:
:37:
:40:
:57:
:01:
:22:
:27:
33
58
37
58
32
09
50
05
37
10
SITE
6
6
6 .
6
2
2
6
6
6
6
ALTITUDE
METERS (MSL)
456
24
456
27
456
122
456
46
456
24
FLIGHT
PATTERN
SW
sw
SW
sw
w
w
w
w
w
w
REMARKS AND
FLIGHT PATTERNS
Second flight of day. (FOD)
3rd FOD
1st FOD -
••
Second sample
was taken directly over
a sewage treatment plant.
2nd FOD
2nd FOD - No 1st FOD due
to inclement weather.
456 meter sample was
taken within what appeared
to be a plume.
5 Aug
6 Aug
6 Aug
7 Aug
7 Aug
10 Aug
10 Aug
79
79
79
79
79
79
79
09
09
07
07
10
11
07
07
10
10
07
10
10
;42:
:46:
:06:
:10:
:57:
:02:
:06:
:08:
:36:
:39:
:21:
:38:
:42:
33
30
20
00
52
04
00
00
19
30
30
49
39
6
6
9
9
6
6
9
9
6
6
2
6
6
456
24
456
67
486
18
456
45
456
30
456
486
18
w
w
NW
NW
NW
NW
XV
NW
NW,
NW '
W
W
W
1st FOD
1st FOD
2nd FOD
1st FOD
•.
2nd FOD
1st FOD -
ground fog,
not descend
take 2nd
2nd FOD
.
(
... ' • - '
Due to heavy
aircraft could
low enough to
grab sample.
131A
-------
TIM!
DATE (EOT) SITE METERS (MSL) PATTERN REMARKS AND FLIGHT PATTERNS
14 Aug 79 07:20:40
07:23:35
"14 Aug -79.
15 Aug 79
•10:46:5-9
10:50:01
07:36:14
07:39:54
15 Aug 79 11:01:11
11:04:30
16 Aug 79 06:51:30
06:53:55
16 Aug 79 10:27:00
10:29:14
2
2
6
/
6
11
11
6
6
11
11
6
6
462
116
456
30
456
106
456
30
456
152
456
24
W 1st FOD
W
W
W
NW
NW
NW
NW
NW
NW
NW
NW
2nd FOD
1st FOD
2nd FOD
1st FOD
2nd FOD
- This cannister
is a blank; it was never
filled with a sample
because mechanical prob-
lems with helicopter
prevented completion
of flight. Submitted
at the request of the
technical coordinator.
131B
-------
TABLE 61. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1306 DURING FLIGHT OF
7/23/79 OVER SITE 6 (15001)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
6.0
1.0
13.5
5.3
9.8
15.8
1.5
1.5
15.8
7.5
3.0
3.8
2.3
3.8
1.5
4.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-D1«ethylpentane
Benzene
Cyclohexane
1.5 2,3-Dimethylpentane
3.0 3-Methylhexane
2.3 2,2.3-Trlmethylpentane
1.5 n-Heptane
1.5 Methyl cyclohexane
2,4-Dlnethylhexane
2,3,4-Trlmethylpentane
6.0 Toluene
2,3-01methylhexane
2-Methyl heptane
3-Ethylhexane
1.5 n-Octane
Ethylcyclohexane
3.0 Ethyl benzene
6.0 p A m-Xylene
Styrene
2.3 o-Xylene
0.8 n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
0.8 n-Ethy1 toluene
o-Ethyltoluene
1,3,5-Trltte thy 1 benzene
!-5 1,2,4-Tr1«ethylbenzene
1.2.3-Trlwethylbenzene
Methyl styrene
1.3-D1ethylbenzene
1.4-01 ethyl benzene
Total Identified
Hydrocarbons
£ Olefln
£ Aromatic
£ Paraffin
Acetylene
ppbC 1
8
24
95
2
129
1
6
19
74
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
14
143
132
-------
TABLE 62. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1209 DURING FLIGHT OF
7/23/79 OVER SITE 6 (901)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
3.8
4.5
1.5
6.0
2.3
4.5
8.3
1.5
0.8
9.8
3.8
0.8
2.3
1.5
3.0
0.8
1.5
3.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1reethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
0.8
1.5
0.8
0.8
3.8
1.5
1.5
0.8
0.8
3.0
5.3
2,3-01methylpentane
3-Methylhexane
2,2,3-Tr1raethyl pentane
n-Heptane
Methyl eye1ohexane
2,4-D1methylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-01methylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propy1 benzene
n-Propylbenzene
p-Ethyltoluene
•-Ethyl toluene
o-Ethyltoluene
1.3.5-Trlnethyi benzene
1.2,4-Trlmethylbenzene
1,2.3-Tr line thy 1 benzene
Methylstyrene
1.3-D1ethylbenzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
i Olefln
I Aromatic
L Paraffin
Acetylene
ppbC %
9
19
51
2
BI
11
23
63
2
Total Unidentified
Hydrocarbons
Total NMHC: by
summing Individual
species i
ppbC
36
117
133
-------
TABLE G3. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1558 DURING FLIGHT OF
7/23/79 OVER SITE 6 (15001)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
3.0
(19
2.3
5.3
1.5
4.5
10.5
9.0
3.8
5 )
1.5
3.8
2.3
4.5
1.5
5.3
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Hethylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye1opentane
2,4-Dlnethylpentane
Benzene
Cyclohexane
0.8
1.5
0.8
4.5
0.8
1.5
1.5
0.8
0.8
2,3-D1methylpentane
3-Methylhexane
2,2,3-Trlraethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-D1methylhexane
2,3,4-Tr1methylpentane
Toluene
2,3-D1raethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethyleye1ohexane
Ethyl benzene
p A m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
•-Ethyl toluene
o-Ethyltoluene
1,3,5-Trlnethylbenzene
1,2,4-Tr1methylbenzene
1.2,3-Trlnethylbenzene
Methylstyrene
1,3-DIethyl benzene
1.4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefln
L Aromatic
£ Paraffin
Acetylene
ppbC
2
15
53
2
72~
3
21
73
3
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species i
ppbC
22
94
134
-------
TABLE 64. HYDROCARBON- CONCENTRATIONS IN- SAMPtE COLLECTED. AT 1601 DURING FLIGHT OF
7/23/79 OVER SITE 6 (80')
ppbC
Hydrocarbon
ppbC
Hydrocarbon
2.3
6.0
3.0
6.0
0.8
5.3
12.0
9.0
4.5
1.5
3.0
1.5
3.0
0.8
2.3
Ethane
Ethylene
Acetylene
Propane
Properte
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Perrtene
Cyel'opentene
Cyclopentane
2,3-D1methyl butane
2-Me thy1pentane
c-4-Methyl -2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dlnethylpentane
Benzene
Cyclohexane
0.8
1.5
1.5
7.5
0.8
3..0
8.3
1.5
4.5
0.8
1.5
1.5
6.0
3.8
5.3
1.5
2.3
1.5
2,3-
3-MethyVhex-ane
2,2,3-TpfraethyVpentane
n-Heptane
Methyl eye liohexane
2,4-D1(methyThexane
2,3,4-Trfroethylpentane
Toluene
2,3-01methythexane
2-Methyl heptane
3-EthyThexane
n-Octane
Ethyl eyeTonexane
Ethyl benzene
p A m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propy1?benzene
n-Propylbenzene
p-Ethyl toluene
•-Ethyl toluene
o-Ethyltoluene
1,3,5-lrlnethylbenzene
1,2(4-Trinethy 1 benzene
1,2.3-Tr 1«ethylbenzene
Methylstyrene
1.3-D1ethylbenzene
1.4-D1ethyl benzene
lotal Identified
Hydrocarbons
I Olefln
£ Aromatic
£ Paraffin
Acetylene
ppbC
8
49
54
3
115
7
43
47
3
lotal. Unidentified
Hydrocarbons
Total NMHC by,
siuran
-------
TABLE G5. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 0737 DURING FLIGHT OF
7/25/79 (1500') OVER SITE 2
ppbC
Hydrocarbon
ppbC
Hydrocarbon
2.3
(9.0)
0.8
0.8
0.8
3.0
3.0
1.5
0.8
1.5
1.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methy 1pentane
c-4-ftethyl -2-pentene
3-Hethylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
1.5
3.0
2,3-01methylpentane
3-Methylhexane
2,2,3-Trlraethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-D1methylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-D1methy1hexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p A m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
•-Ethyltoluene
o-Ethyltoluene
1.3,5-Trlnethylbenzene
1.2,4-Tr1o»ethyl benzene
1,2,3-Tr1»ethylbenzene
Methylstyrene
1.3-D1ethyl benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefln
I Aromatic
£ Paraffin
Acetylene
ppbC %
6
14
_l_
21
29
67
4
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species i
ppbC
7
28
136
-------
TABLE G6. HYDROCARBON .CONCENTRATIONS IN SAMPLE COLLECTED AT 0740 DURING -FLIGHT OF
7/25/79 OVER SITE 2 (400')
ppbC
Hydrocarbon
ppbC
Hydrocarbon
4.5
6.8
6.0
7.5
1.5
3.8
9.8
12.8
6.0
0.8
1.5
4.5
3.0
6.0
1.5
2.3
2.3
Ethane
Ethyl ene
Acetylene
Pro.pane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-DImethyl butane
2-Methylpentane
c-4-Me thy1-2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
1.5
1.5
2.3
0.8
0.8
6.0
1.5
3.8
2.3
1.5
2.3
5.3
1.5
2,3 -D1 me t-hy 1 pentane
3-Mathylhexane
2,2,3-friaethyl pentane
n-Heptane >
Methyl oyc lohexafle
2,4-D1methylhexane
2,3,4-TrImethylpentane
Toluene
2,3-lMme'thyl hexane
2-Methyl.heptane
3-Et'hyl^hexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p A m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
»-Ethy1toluene
o-Ethyltoluene
1,3,5-TH«ethy 1 benzene
1.2,4-TrImethylbenzene
1.2,3-Trtnetnylbenzene
Methylstyrene
1,3-D1ethyl benzene
1,4-DIethyl benzene
Total Identified
Hydrocarbons
£ Olefln
£ Aromatic
I Paraffin
Acetylene
ppbC
8
25
72
6
112
*
7
22
65
5
Total Unidentified
Hydrocarbons
Total NMHC by
*sumt1 rig :indiv idual
species i
ppbC
32
144
137
-------
TABLE G7. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1037 DURING FLIGHT OF
7/25/79 (1500') OVER SITE 6
ppbC
Hydrocarbon
ppbC
Hydrocarbon
10;5
6.0
5.3
24.8
8.3
18.0
34.5
1.5
36.8
18.0
2.3
5.3
21.0
17.3
15.8
9.8
3.8
30.0
5.3
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methy 1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thy1 eye1opentane
2,4-D1»ethy1pentane
Benzene
Cyclohexane
12.0
13.5
6.0
10.5
9.8
3.0
28.5
1.5
8.3
5.3
6.0
2.3
4.5
9.8
3.0
6.0
3.8
1.5
3.0
3.0
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Tr1methylpentane
n-Heptane
Methyl eye 1ohexane
2,4-Dlmethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-01methylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p £ m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
•-Ethyltoluene
o-Ethyltoluene
1,3.5-Trlmethy 1 benzene
1.2,4-Tr1methylbenzene
1,2,3-Tr1methyl benzene
Methylstyrene
1,3-DIethyl benzene
1.4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefln
£ Aromatic
i Paraffin
Acetylene
ppbC %
19
86
305
4T5
5
21
73
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
89
504
138
-------
TABLE G8. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1101 DURING FLIGHT OF
7/25/79 (15001) OVER SITE 6
ppbC
Hydrocarbon
ppbC
Hydrocarbon
7.5
7.5
6.0
24.0
5.3
33.0
52.5
1.5
1.5
0.8
42.0
22.5
2.3
4.5
10.5
6.8
9.8
3.8
2.3
12.8
3.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2.3-Dimethyl butane
2-Methy 1pentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
4.5
5.3
4.5
4.5
4.5
2.3
15.0
3.8
2.3
3.0
2.3
5.3
1.5
3.8
2.3
2.3
2.3
2,3-Dlmethylpentane
3-Me thy!hexane
2,2,3-Trlraethylpentane
n-Heptane
Methyl eye1ohexane
2,4-D1methylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-D1raethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
•-Ethyltoluene
o-Ethyltoluene
1,3,5-Tr1»ethy1 benzene
1,2.4-Tr1methylbenzene
1,2,3-THnethylbenzene
Methylstyrene
1,3-01ethylbenzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
I Olefln
£ Aromatic
i Paraffin
Acetylene
ppbC
17
44
263
6
329
5
13
80
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
53
382
139
-------
TABLE G9. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1123 DURING FLIGHT
OF 8/4/79 OVER SITE 6 (15001)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
11.0
22.0
12.0
15.5
4.0
18.5
45.5
41.5
23.5
1.0
2.5
9.0
5.5
9.5
3.0
2.0
6.0
1.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methyl pentane
c-4-Methyl-2-pentene
3-Methyl pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-D1methy1pentane
Benzene
Cyclohexane
3.5 2,3-Dimethy! pentane
4.0 3-Methylhexane
4.0 2,2,3-Trlmethylpentane
3.0 n-Heptane
2.0 Methylcyclohexane
1.5 2,4-D1methylhexane
2,3,4-Tr1methylpentane
17.0 Toluene
0.5 2,3-Dimethylhexane
2.0 2-Methylheptane
1.5 3-Ethylhexane
1.0 n-Octane
Ethylcyclohexane
3.0 Ethyl benzene
6.0 p A m-Xylene
1.0 Styrene
3.0 o-Xylene
6.0 n-Nonane
17.5 1-Propylbenzene
1.0 n-Propylbenzene
2.5 p-Ethyl toluene
m-Ethyltoluene
2.5 o-Ethyltoluene
1-0 1,3,5-Tr1methylbenzene
1-5 1,2.4-Tr1methylbenzene
1,2,3-Trlmethyl benzene
Methylstyrene
1,3-01ethyl benzene
1.4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
£ Paraffin
Acetylene
ppbC ^
27
68
207
12
314
9
22
66
4
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species *
ppbC
17
331
140
-------
TABLE G10 • HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1127 DURING FLIGHT
OF 8/4/79 OVER SITE 6 (90')
ppbC
Hydrocarbon
ppbC
Hydrocarbon
12.5
22.0
17.5
23.0
6.0
29.5
66.5
60.0
33.0
1.5
2.5
9.0
6.0
11.5
3.0
2.5
7.0
2.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1raethylpentane
Benzene
Cyclohexane
4.0 2,3-D1methylpentane
4*5 3-Methylhexane
S'Q 2,2,3-Tr1methylpentane
3J5 n-Heptane
2~o Methyl eyelohexane
15 2,4-Dimethylhexane
.__' 2,3,4-Trlmethylpentane
19.5 Toluene
1.0 2,3-Dtmethylhexane
3.'o 2-Methyl heptane
2.o 3-Ethylhexane
1.5 n-Octane
Ethyl eyelohexane
3.5 Ethyl benzene
7.0 p 4 ro-Xylene
1.0 Styrene
3.5 o-Xylene
1.0 n-Nonane
1.5 1-Propylbenzene
1.5 n-Propy1 benzene
1.5 p-Ethyl toluene
2.0 ra-Ethy1 toluene
3.5 o-Ethyltoluene
1.0 1,3,5-Tr1methyl benzene
2.0 1,2,4-Trfmethyl benzene
1,2,3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
z Paraffin
Acetylene
PPbC %
29
53
292
18
393
7
14
74
4
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species i
ppbC
37
430
141
-------
TABLE Gil. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 0942 DURING FLIGHT
OF 8/5/79 OVER SITE 6 (15001)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
5.0
(42.5)
1.5
4.5
2.5
4.5
12.0
4.5
2.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methylcyclohexane
2,4-Dlmethylhexane
2,3,4-Trlmethylpentane
1.5 Toluene
2,3-D1methylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p A ra-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethy1 toluene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Tr1methylbenzene
1,2.3-Tr1methyl benzene
Methylstyrene
1,3-01ethyl benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
E Olefln
£ Aromatic
£ Paraffin
Acetylene
ppbC %
2
35
2
5
90
5
39
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species i
ppbC
20
59
142
-------
TABLE G12 . HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 0946 DURING FLIGHT
OF 8/5/79 OVER SITE 6 (80')
ppbC
Hydrocarbon
Total Identified
Hydrocarbons
E Oleftn
£ Aromatic
£ Paraffin
Acetyl ene
ppbC
23
73
240
15
35T
7
21
68
"4
ppbC
Hydrocarbon
15.0
10.0
15.0
18.0
6.5
22.0
48.5
1.5
2.0
1.5
—
46.5
27.0
—
—
—
—
1.0
2.5
8.5
—
5.5
—
9.0
— — —
— — —
2.5
2.0
9r-
.5
2i-\
.0
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1 -Butane
n-Butane
1 -Bu tene
1-Butene
t-2-But'ene
c-2-Butene
1 -Pentane
n-Pentane
1 -Pentene
t-2 -Pentene
c -2 -Pentene
Cyclop-entene
CycJl opentane
2 , 3-Ofmethyl butane
2-Methylpentawe
c -4 -Methyl -2-;pentene
3-Methyl«pentane
1 -Hexene
n-Hexane
t- 2 -Hexene
c -2 -Hexene
Me thy 1 eye 1 ope n tane
2 §4-D1methyl pentane
Benzene
Cycl ohexane
4.0
4.5
5,0
4.5
2.0
1.0
—
30.0
1.0
2.0
2.0
3.0
1.0
3.0
5.5
1.5
4.5
2.0
1/-\
.0
5r*
.5
4f\
.0
3r-
.5
1r~
.5
4n
.U
2 , 3 -Dime thy 1 pentane
3-Methyl;hexa^e
2 ,2 , 3-Trlme t%S pentane
n -Hep tane <
Methyl cyclotaexa-ne •<
2,4-0 tine thy 1 hexane
2,3,4 -Tr 1 me thy 1 pentane
Toluene
2 , 3-D 1me thy ! ihexa ne
2 -Methyl heptane
3-Ethylhexa
-------
TABLE G13. HYDROCARBON CONCENTRATIONS IN SAMPLE COLELCTED AT 0706 DURING FLIGHT 1
OF 8/6/79 (15001) OVER SITE 9
ppbC
Hydrocarbon
ppbC
Hydrocarbon
6.0
(34.0 )
4.5
2.0
3.5
3.0
1.5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methy1butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye1opentane
2.4-01methylpentane
Benzene
Cyclohexane
2,3-Dimethyl pentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-D1methylhexane
2,3,4-Trlmethylpentane
1.5 Toluene
2,3-D1methylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethy1toluene
o-Ethyltoluene
1,3,5-Tr1methylbenzene
1,2.4-Tr1methylbenzene
1,2.3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefin
E Aromatic
i Paraffin
Acetylene
ppbC %
2
21
9
91
23
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
PPbC
23
144
-------
TABLE G14. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 0710 DURING FLIGHT 1
OF 8/6/79 OVER SITE 9 (220')
ppbC
Hydrocarbon
ppbC
Hydrocarbon
14.0
34.0
14.0
15.5
14.0
14.5
7.0
3.0
1.5
2.5
1.0
2.0
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dfmethyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
1.0
1.0
1.5
.10
4.0
1.0
2.5
1.5
1.0
1.5
2.5
4.5
0.5
1.0
1.0
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptame
Methyl eye Tohexane
2,4-D1methyThexane
2,3,4-Trlmethylpentane
Toluene
2,3-Oiraethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethyl cyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trtmethylbenzene
1,2.4-Tr1methylbenzene
1,2.3-Trlmethyl benzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefln
I Aromatic
i Paraffin
Acetylene
ppbC _%
35
22
97
T5l
23
14
63
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
7
160
145
-------
TABLE G15. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1057 DURING FLIGHT 2
OF 8/6/79 OVER SITE 6 (16001)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
12.0
21.0
7.5
14.0
6.0
37.0
50.5
35.0
21.5
1.5
2.0
8.5
5.0
8.5
2.5
1.5
4.0
1.5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
3.0
3.0
3.0
2.5
1.5
1.0
19.5
2.5
1.5
1.5
3.0
6.0
3.0
1.0
1.0
1.5
2.0
1.5
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eyelohexane
2,4-Dimethylhexane
2,3,4-Tr1methylpentane
Toluene
2,3-D1methylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethyl eyelohexane
Ethyl benzene
p & ro-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethy1 toluene
1,3,5-Tr1methy1 benzene
1,2,4-TMmethyl benzene
1,2,3-Tr line thy 1 benzene
Methylstyrene
1,3-01ethyl benzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
z Olefln
£ Aromatic
i Paraffin
Acetylene
ppbC %
27
42
221
8
297
9
14
74
3
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
35
332
146
-------
TABLE GT6 . HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1102 DURING FLIGHT 2
OF 8/6/79 (60') OVER SITE 6
ppbC
Hydrocarbon
ppbC
Hydrocarbon
10.5
11.5
3.5
13.0
2.0
16.0
39.0
35.5
22.0
1.0
2.0
10.5
6.5
13.5
3.5
3.0
5.0
1.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c -2 -Benzene
CycU opentene
SCyd'opentane
2,3-Wmethyl butane
2-*MethyTpentane
c-4-Me-thyil -2-,pentene
3-MethylpentaTie
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thylcyc1opentane
2,4-DImethylpentane
Benzene
Cyclohexane
3.5
4.5
2.5
.3.0
1.5
1.5
21.0
1.0
3.0
2.0
2.0
3.0
7.0
1.5
3.5
1.5
1.0
1.5
1.5
2.5
1.0
2.0
2,3-Dimethyl pentane
3-Methy1*iexane
2,2,, 3-Tr?l»me*hy:l penjt,an.e
n-Heptawe
Me thy 1 cy c?l ohexatie
2,4-01methy1hexane
2,3,4-Trtme*hylp«ntane
Toluene
2,3-Dtmethylhexane
2-Methyl;he,ptane
3-Ethylhiexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p & m-Xylene
Styrene
o-JCylene
n-Nonane
1-Propylbenzene
n-Propyl'b.eazene
p-Ethyl 1^1 uene
m-Ethyl.tol uene
o-E*hy?l toluene
1,3,5 -Trftne&tiy-l benzene
1,2,4-THmet^yl benzene
1,2,3-Trf methyl benzene
Methyl sJjyrene
1,3-01 ethyl benzene
1,,4-Dtethiyl benzene
Total Identified
Hydrocarbons
j: Olefln
£ Aromatic
T. Paraffin
Ac-etyl'ene
ppbC '%
15
49
204
4
271
5
.18
75
.1
/Total OJn.1 dentlfled
Hydrocarbons
Total -NMHC by
s.unm1'nj nndiv.idual
P.pbC
27
298
-------
TABLE G17. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 0706 DURING FLIGHT 1 OF
8/7/79 (15001) OVER SITE 9
ppbC
Hydrocarbon
ppbC
Hydrocarbon
5.5
4.0
1.5
3.5
2.0
4.5
5.0
2.5
1.0
Ethane
Ethylene
Acetyl ene
Propane
Propene
t-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dimethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-D1methylpentane
Benzene
Cyclohexane
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Tr1methylpentane
n-Heptane
Methyl eyelohexane
2,4-D1methylhexane
2,3,4-Trlmethylpentane
2.0 Toluene
2,3-Dimethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethyl eyelohexane
Ethyl benzene
1.0 p A ro-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Tr1methylbenzene
1,2,3-Tr1methylbenzene
Methylstyrene
1.3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
£ Olefln
£ Aromatic
i Paraffin
Acetylene
12
9
74
5
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species .
ppbC
3
37
148
-------
TABLE 613. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 0708 DURING FLIGHT 1
OF 8/7/79 OVER SITE 9 (T5D1)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
3.5
1.5
1.5
1.5
1.5
3.5
1.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butawe
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pewtene
c-2-Pentene
CycTopentene
Cyclopentane
2,3-Dtmethyl butane
2-Methyl pentaite
c-4-Methyl -2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
2.5
1.0
2,3-Drmethyl pentane
3-Meth\yl*iex*ne
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye 1 ohexa'ne
2,4 -D1 raethy Ishexane
2,3,4-Trtmethylpentane
Toluene
2,3-Dtmethylh«xane
2-Methyl heptane
S-Ethylhexa-ne
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethylto!uene
o-Ethyltoluene
1,3,5-Tr1methy1 benzene
1,2,4-Trimethy 1 benzene
1,2,3-Tr1methylbenzene
Methylstyrene
1,3-D1ethyTbenzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
i Paraffin
Acetylene
ppbC %
2
4
13
9
19
72
Total Unidentified
Hydrocarbons
Total NMtfC by
summing Individual
species i
PPbC
7
26
149
-------
TABLE G19. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1036 DURING FLIGHT 2 OF
8/7/79 OVER SITE 6 (15001)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
11.5
31.5
7.5
14.0
4.5
14.5
34.5
31.5
17.0
1.0
1.5
6.5
4.5
11.0
2.5
1.0
6.0
2.0
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-01methylpentane
Benzene
Cyclohexane
3.5 2,3-Dimethylpentane
4.0 3-Methylhexane
3.0 2,2,3-Trlmethylpentane
3.0 n-Heptane
2.0 Methylcyclohexane
1.0 2,4-D1methylhexane
2,3,4-Trlmethylpentane
16.5 Toluene
2,3-01methyl hexane
2.0 2-Methyl heptane
3.0 3-Ethylhexane
1.5 n-Octane
Ethylcyclohexane
2.5 Ethyl benzene
5.5 p& m-Xylene
1.0 Styrene
2.5 o-Xyl ene
1.0 n-Nonane
1-Propylbenzene
1-0 n-Propylbenzene
2.5 p-Ethyltoluene
ra-Ethy1 toluene
12.5 o-Ethyltoluene
1-° 1,3,5-Tr1methyl benzene
3-0 1,2,4-Tr1methylbenzene
!-° 1,2,3-Tr1methyl benzene
Methylstyrene
1,3-01ethylbenzene
1.4-D1ethyl benzene
Total Identified
Hydrocarbons
i Olefln
I Aromatic
£ Paraffin
Acetylene
ppbC %
39
49
177
8
273
13
20
64
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species ,
ppbC
32
305
150
-------
TABLE 62Q. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1039 DURING FLIGHT
OF 8/7/79 OVER SITE 6 (TOO1)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
4.5
7.0
2.5
11.0
3.0
12.0
25.0
25.0
14.5
1.0
2.0
7.5
5.0
10.0
2.5
1.5
5.5
2.0
Ethane
Ethylene
Aeetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyleye1opentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
5.0 2,3-D tme thy 1 pentane
6.0 3-Methylhfrxane
2.5 2,2,3-THmethylpenitane
5.0 n-Heptane
3.5 Methyl eye 1ohexane 2
1.5 2,4-D1methy1hexane
2,3,4-Trtmethylpentane
16.5 Toluene
2,3-Dimethyl hexane
2.0 2-Methylheptane
1.5 3-Ethylhexane
1.0 n-Octane
Ethyleye1ohexane
3.0 Ethyl benzene
6.5 p A m-Xylene
Styrene
3.0 o-Xylene
1.0 n-Nonane
1-Propylbenzene
1-0 n-Propylbenzene
1.0 p-Ethyltoluene
1-0 ra-Ethyltoluene
2.0 o-Ethyltoluene
1.3,5-Trlmethylbenzene
2.0 1,2,4-Tr1methylbenzene
1-0 i,2,3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefln
i Aromatic
J: Paraffin
Acetylene
ppbC J.
10
42
147
3
20T
5
21
73
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
29
230
151
-------
TABLE G21 . HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 0721 DURING FLIGHT
OF 8/10/79 OVER SITE 2 (16001)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
12.0
10.0
12.0
14.0
21.5
9.0
1.5
0.5
2.0
1.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
2,3-D1methy!pentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-D1methylhexane
2,3,4-Trlmethylpentane
3.0 Toluene
2,3-Dimethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
1.0 pi ra-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
ro-Ethy1 toluene
2.0 o-Ethyltoluene
1,3,5-Trlnethylbenzene
1.5 1,2,4-Tr1methylbenzene
1,2.3-Tr1methyl benzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefin
£ Aromatic
z Paraffin
Acetyl ene
ppbC ^
9.5
82.5
92
10
90
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species i
PPbC
7
99
152
-------
TABLE G22. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED-AT 1039 DURING FLIGHT OF
8/10/79 OVER SITE 6 (16001)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
82.5
12.0
135.
26.3
81.8
119.
4.5
6.8
3.8
2.3
99.0
48.0
5.3
4.5
5.3
21.0
12.8
21.0
10.5
3.0
17.3
7.5
Ethane
Ethylene
Acetylene
Propane
Prqpene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
.Cyclqpentane
2,3-D1methyl butane
2-Methyl:pentane
c-4^Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyleye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
3.o 2,3-Dime±hylpentane
9.0 3-Methyl»h,exane
4.5 2,2,3-Tr1me*hylpentane
9.8 n-Heptane
10.5 Me thy 1 eye 1ohexane
1.5 2,4-D i methy1hexane
2,3,4-Tr1methyl;pentane
15.0 Toluene
1.5 2,3-Dimethylhexane
3.0 2-Methylheptane
3.0 3-Ethylhexane
4.5 n-Octane
3.0 Ethyl eye 1ohexane
3.0 Ethyl benzene
4.5 p & ra-Xylene
1.5 Styrene
3.0 o-Xylene
2.3 n-Nonane
2.3 1-Propylbenzene
1-5 n-Propy1 benzene
p-Ethyl toluene
m-Ethyltoluene
1.5 o-Ethyltoluene
1,3,5-Trlmethylbenzene
2.3 1,2,4-Trlmethylbenzene
1,2,3-Trlmethylbenzene
Me-thyl styrene
1,3-01 ethyl:benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefln
z Aromatic
i -Paraffin
Acetyl-ene
ppbC %^
63
53
704
819"
8
6
86
Total .Unidentified
Hydrocarbons
Total NMH.C by
summing Individual
ppbC
56
875
153
-------
TABLE G23. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1042 DURING FLIGHT OF
8/10/79 OVER SITE 6 (60')
ppbC
Hydrocarbon
ppbC
Hydrocarbon
22.5
7.5
5.3
113.0
16.5
57.8
95.3
4.5
1.5
3.0
1.5
69.0
39.8
3.8
1.5
4.5
16.5
10.5
16.5
7.5
3.0
13.5
5.3
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye1opentane
2,4-Di«ethylpentane
Benzene
Cyclohexane
5.3
6.8
4.5
6.8
7.5
2.3
.3
.5
17.
1.
2.3
4.5
3.0
3.0
3.0
6.0
1.5
3.0
4.5
3.8
1.5
1.5
1.5
2.3
0.8
3.0
2,3-D1methylpentane
3-Methylhexane
2,2,3-Trlraethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-D1methylhexane
2.3,4-Trlmethylpentane
Toluene
2,3-01methylhexane
2-Me thylheptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p A m-Xylene
Styrene
o-Xylene
n-Nonane
1-PropylI benzene
n-Propylbenzene
p-Ethyltoluene
•-Ethyl toluene
o-Ethyltoluene
1.3.5-Tr1nethylbenzene
1,2,4-Tr1roethylbenzene
1.2.3-Trlwethylbenzene
Methylstyrene
1,3-Diethylbenzene
1,4-D1ethyl benzene
Total Identified
Hydrocarbons
I Olefln
I Aromatic
i Paraffin
Acetylene
ppbC
40
57
518
5
620
6
9
84
1
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species i
PPbC
82
702
154
-------
TABLE 624. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 0720 DURING FLIGHT OF
8/14/79 OVER SITE 2 (1520')
ppbC
Hydrocarbon
ppbC
Hydrocarbon
17.3
9.8
2.3
5.3
5.3
Ethane
Ethylene
Acetylene
Propane
Propene?
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n^Pentane
1-Pentene:
t-2'-Pentene
c-2^Pentene
Cyclopentene
Cyclopentane
2v3:-D1methy;i butane
2-MethyTpentane
c-4-Methy;i-2<-pentene
3-Methy1 pentane
1-Hexene
n-Hexane
t-2^Hexene
c-2rHexene
Methyl cyc.l opentane
2,4-D1 methyl pen tane
Benzene
Cyclohexane
2, 3>D Ime thyil^entane
3-Methylhexane
2,2,3^-Tf Iroethyl pentane
n-Heptane?
Meithy 1 eyc.l ohex-ane
2,4-01methylhexane
2.3,4-T'r1 methyl pentane
Toluene
2,3-Dimethy^hexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl tol uene;
m-Ethyl toluene
o-Ethyltoluene
1,3.5^-Trlmethyl benzene
1,2,4-THmethyl benzene:
1,2,3-Trlmethyil benzene
Methylstyrene
1,3-D1ethyl benzene
1,4-Dtethyl benzene
Tota^l
Hydrocarbons
z Olefln
2 Aromatic
£ Paraffin
Acetyl-ene
ppbC ^
ppbC
1^ Untdentitfled
Hydroearbons
totasl
1inxL1iv,t-duai1.
155'
-------
TABLE G25 . HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 0723 DURING FLIGHT
OF 8/14/79 OVER SITE 2 (380')
ppbC
Hydrocarbon
ppbC
Hydrocarbon
17.5
31.0
15.5
18.0
9.0
14.0
37.5
44.5
24.0
1.0
1.5
6.5
4.0
5.0
2.5
1.5
4.0
1.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methy!butane
2-Methyl pentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-D1methy1pentane
Benzene
Cyclohexane
2.0
2.5
2.0
2.0
1.5
1.0
9.0
1.0
2.0
5.0
2.0
1.0
2.0
2.5
1.0
1.5
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-D1methy1hexane
2,3,4-Trlmethylpentane
Toluene
2,3-Dimethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trlmethyl benzene
1,2,4-Tr1raethylbenzene
1,2,3-Tr1methylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
E Olefln
£ Aromatic
i Paraffin
Acetylene
ppbC
40
30
190
16
275"
15
11
69
6
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
24
299
156
-------
TABLE"626. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1047 DURING FLIGHT
OF 8/14/79 OVER SITE 6 (1500')
ppbC
Hydrocarbon
ppbC
Hydrocarbon
32.
13.
5.5
.5
.5
.5
58.
18.
36.
61.0
2.5
2.5
1.5
49.5
26.5
2.0
2.5
12.0
7.5
13.0
5.5
2.0
9.0
3.0
Ethane
Ethylene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dtmethyl butane
2-Me thylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thy1 eye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
2.
2.
3.5
4.0
4.0
4.5
3.5
1.0
10.5
1.0
1.5
.0
.0
1.0
2.0
4.0
2.5
1.5
1.5
1.0
1.0
1.0
1.5
2.5
2,3-D1me thy1pentane
3-Methylhexane
2,2,3-Trtmethylpentane
n-Heptane i
Me thyleye1ehexane
2,4-D1methylhexane
2,3,4-TMmethylpentane
Toluene
2,3-01methylhexane
2-He thylheptane
3-Ethylhexane
n-Octane
Ethyl eyelohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xyl ene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethyltoluene
o-Ethyltoluene
1,3.5-Trtmethylbenzene
1,2,4-Tr1methylbenzene
1,2,3-Tr1methylbenzene
Methylstyrene
1,3-01ethylbenzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefln
z Aromatic
i Paraffin
Acetylene
ppbC £
38
36
340
6
420
9
9
81
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
30
450
157
-------
TABLE G27. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1050 DURING FLIGHT OF
8/14/79 OVER SITE 6 (1001)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
22.5
12.5
8.0
45.5
12.5
29.0
56.0
2.0
2.0
1.5
46.0
25.5
2.0
2.5
10.0
6.5
14.5
4.5
2.5
8.5
2.5
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-D1roethy1pentane
Benzene
Cyclohexane
3.0
4.0
3.0
3.5
3.0
1.5
13.0
1.5
2.0
2.5
1.5
3.0
6.0
2.0
4.0
2.5
2.0
2.5
1.5
2.0
4.0
1.5
7.5
2.0
1.5
1.5
1.5
2,3-Oimethylpentane
3-Methylhexane
2,2,3-Tr1methylpentane
n-Heptane
Methyl eye 1ohexane
2,4-D1methylhexane
2,3,4-Trlmethyl pentane
Toluene
2,3-Dfmethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p 4 m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
ro-Ethyltoluene
o-Ethyltoluene
1,3,5-Tr1methy1 benzene
1,2,4-Tr1methylbenzene
1,2,3-Tr1methylbenzene
Methylstyrene
1,3-Dlethylbenzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
E Paraffin
Acetylene
ppbC ^
34
61
299
8
401
8
15
75
2
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species i
PPbC
72
473
158
-------
TABLE G28. HYDROCARBON ''CONCENTRATIONS 3N SAMPLE COLLECTED 'DURING FLIGHT OF 8/15/79
OVER SITE ai (15001)
ppbC
Hydrocarbon
ppbC
'Hydrocarb'on
6.0
4.5
1.5
3.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbu tane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thy1 eye1 opentane
2,4-D1methylpentane
Benzene
Cyclohexane
2 ,3-Olmet-hyl pfemtane
2 ,2 , 3-Tr1nfeUhyilip1esrtalie
n -Heptane
Methyl eye Ibhexane
2 ,4 -D tmethy 1 he xa ne
2 , 3 , 4-Tf Ime thy Ipentane
Tol uene
2 , 3-D 1 methyl hexa n'e
3-Ethylhex*ne
n-Octane
Ethyl eye 1'Oiiexane
Ethyl benzene
p A ro-Xylene
Styrene
o-Xyl ene
n-Nonane
1-Propyl benzene
n-Propyl benzene
p-Ethyl tol uene
m-Ethy 1 tol uene
o-Ethylt'oluene
1 .3 , 5-TH methyl benzene
1 ,2 ,4-TM methyl benzene
1 , 2 ,3-Trl methyl benzene
Methyl styrene
1 , 3-D1 ethyl benzene
1 ,4-D1 ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
i Paraffin
Acetylene
ppbC j.
15 100
15
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
specie's ,
ppbC
20
35
159
-------
TABLE G19. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 0740 DURING FLIGHT OF
8/15/79 OVER SITE 11 (3501)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
4.5
6.0
4.5
9.0
6.0
6.0
1.5
0.8
1.5
0.8
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dlmethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Hethylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dlmethylpentane
Benzene
Cyclohexane
1.5
0.8
1.5
2,3-Oimethylpentane
3-Methylhexane
2.2,3-Trlraethyl pentane
n-Heptane
Methyl cyclohexane
2,4-D1methylhexane
2,3,4-TMmethylpentane
Toluene
2,3-01methylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p i m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propy1 benzene
n-Propylbenzene
p-Ethyltoluene
•-Ethyl toluene
o-Ethyltoluene
1.3.5-Trlnethylbenzene
1,2,4-Tr1methylbenzene
1,2,3-Trlmethyl benzene
Methylstyrene
1.3-D1ethyl benzene
1,4-DIethyl benzene
Total Identified
Hydrocarbons
i Olefln
I Aromatic
i Paraffin
Acetylene
ppbC %
5
40
10
90
Total Unidentified
Hydrocarbons
Total NMHC by
sumning Individual
species ,
PPbC
9
54
160
-------
TABLE G30. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1101 DURING FLIGHT OF
8/15/79 OVER SITE 6 (15001)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
4.5
6.8
4.5
1.5
3.8
3.8
3.0
0.8
0.8
0.8
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyleye1opentane
2,4-D1methylpentane
Benzene
Cycl ohexane
2,3-DImethylpentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-D1methylhexane
2,3,4-Trlmethylpentane
3.0 Toluene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
1.5 p & m-Xylene
Styrene
o-Xylene
0.8 n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Tr1methylbenzene
1.5 1,2,4-Tr1methylbenzene
1,2,3-Trlmethylbenzene
Methyl styrene
1,3-01ethyl benzene
1.4-D1ethyl benzene
Total Identified
Hydrocarbons
z Olefln
z Aromatic
i Paraffin
Acetylene
ppbC %
1
7
23
18
18
63
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
9 "
46
161
-------
TABLE G31. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1104 DURING FLIGHT OF
8/15/79 OVER SITE 6 (1001)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
6.0
9.0
4.5
6.0
3.0
5.3
11.3
12.8
8.3
2.3
6.0
0.8
3.0
2.3
3.8
1.5
5.3
2.3
0.8
Ethane
Ethylerie
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyleye1 opentane
2,4-D1methylpentane
Benzene
Cyclohexane
1.5
2.3
1.5
1.5
0.8
0.8
11.3
0.8
1.5
4.5
2.3
0.8
1.5
0.8
2.3
1.5
2.3
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye1ohexane
2,4-01methylhexane
2,3,4-THmethyl pentane
Toluene
2,3-Oiraethylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyl toluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Tr line thyl benzene
1,2,4-Tr1methylbenzene
1,2,3-Tr1methylbenzene
Methylstyrene
1,3-Dlethylbenzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefln
£ Aromatic
E Paraffin
Acetylene
ppbC %_
12
22
86
5
125
10
18
69
4
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
5
130
162
-------
TABLE G32. HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 0651 DURING FLIGHT
OF 8/16/79 OVER SITE 11 (1500')
ppbC
Hydrocarbon
ppbC
Hydrocarbon
4.5
2.0
1.5
2.0
3.0
1.5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2.3-D1methy1butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyleye1opentane
2,4-Dimethylpentane
Benzene
Cyclohexane
1.0
1.0
2,3-Dime'thyl pentane
3 -Methylhexane
2,2,3-Trtme
-------
TABLE G33 . HYDROCARBON CONCENTRATIONS COLLECTED IN SAMPLE AT 0654 DURING FLIGHT
OF 8/16/79 OVER SITE 11 (5001)
ppbC
Hydrocarbon
ppbC
Hydrocarbon
2.5
1.5
1.5
1.0
1.5
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1 opentane
2,4-D1methylpentane
Benzene
Cyclohexane
2,3-01methy!pentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-D1methylhexane
2,3,4-Tr line thyl pentane
2.0 Toluene
2,3-Dimethyl hexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
1.0 Ethyl benzene
2.5 p A m-Xylene
Styrene
1.0 o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
3.0 o-Ethyltoluene
1,3,5-Trlmethylbenzene
6.0 1,2.4-Tr1methylbenzene
1-5 1.2.3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
£ Olefln
£ Aromatic
£ Paraffin
Acetylene
ppbC %
17
8
~25~
68
32
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
29
54
164
-------
TABLE G34 . HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1026 DURING FLIGHT
OF 8/16/79 OVER SITE '6 (1500')
ppbC
Hydrocarbon
ppbC
Hydrocarbon
3.5
2.5
2.0
2.0
2.5
6.5
6.0
4.0
2.0
1.0
2.0
1.0
Ethane"
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cycl'opentane
•2,,.3-Df methylbutane
2-Methylpentane
c-44tethyl -2-pentene
3-Methylpentatie
1-Hexehe
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
4.0
1.0
2.0
1.0
1.0
1.5
2,3-Dimethyl pent ane
3-*Methyl'hexane
2,2,3-Tr1methylpentane
n-Heptane
Methyl eye 1ohexane
2,4-Dimethylhexane
2,3,4-Tr iroe'thy 1 pentane
Toluene
2,3-Dimethylhexane
2-Me thylheptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propy!benzene
n-Propylbenzene
p-Et'hyl toluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trimethyl benzene
1,2,4-Trimethyl benzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-Diethylbenzene
1,4-Diethylbenzene
Total Identified
Hydrocarbons
z Olefin
I Aromatic
z Paraffin
-Acetylene
PpbC
3
12
29
_2
45
5
26
64
-4
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species >
ppbC
11
56
165
-------
TABLE G35 . HYDROCARBON CONCENTRATIONS IN SAMPLE COLLECTED AT 1029 DURING FLIGHT
OF 8/16/79 OVER SITE 6
ppbC
Hydrocarbon
ppbC
Hydrocarbon
4.0
2.0
4.5
1.5
6.0
21.0
17.5
10.5
1.0
1.5
4.5
3.5
6.0
2.0
1.0
2.5
1.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1 -Biitene
i-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-Dlmethylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyleye1opentane
2,4-D1methylpentane
Benzene
Cyclohexane
15 2,3-Dimethyl pentane
1*5 3-Methylhexane
1^5 2,2,3-Tr1raethylpentane
1J5 n-Heptane
Methyl eye1ohexane
2,4-D1methylhexane
2,3,4-Trlmethylpentane
9.5 Toluene
2,3-01methylhexane
2-Methylheptane
3-Ethylhexane
1.0 n-Octane
Ethylcyclohexane
2.5 Ethyl benzene
5.0 p A ro-Xylene
1.5 Styrene
3.0 o-Xylene
2.5 n-Nonane
1-Propylbenzene
2.0 n-Propylbenzene
1.0 p-Ethyl toluene
1.5 m-Ethyltoluene
2.0 o-Ethyltoluene
2.5 1,3.5-Tr1methylbenzene
8.0 1,2,4 -Tr! me thyl benzene
2.0 1,2,3-Trlmethylbenzene
Methylstyrene
1.0 1,3-01ethyl benzene
1.0 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
z Paraffin
Acetylene
ppbC %
5 4
43 30
93 66
141
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species ,
ppbC
43
184
166
-------
APPENDIX H
Individual Hydrocarbon Concentrations in Samples Collected
for Intercomparison Purposes
167
-------
TABLE HI . HYDROCARBON CONCENTRATIONS IN 14:25-15:25 LUMBERTON NEW JERSEY SITE
SAMPLE ON 8/17/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
4.0
39.0
2.5
6.0
3.0
12.0
52.0
3.5
4.5
2.0
13.5
14.5
1.0
1.0
4.5
4.0
14.0
2.0
1.5
5.0
2.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl cyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
2.0
2.5
2.0
2.5
2.5
1.0
0.5
20.0
1.0
2.0
3.0
3.0
1.0
7.5
24.0
3.0
10.0
12.0
1.5
.0
.0
5.
5.
6.5
15.0
17.0
37.0
8.0
2.0
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Trimethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-Olmethylhexane
2,3,4-Trlmethylpentane
Toluene.»
2,3-DlmSthylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-Trimethylbenzene
1,2,4-Trimethylbenzene
1,2,3-Trimethylbenzene
Methylstyrene
1,3-Diethylbenzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
z Olefin
z Aromatic
i Paraffin
Acetylene
ppbC %_
63
155
168
3
388
16
40
43
1
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species ,
ppbC
156
544
168
-------
TABLE H2. HYDROCARBON CONCENTRATIONS IN 13:25-14:25-LUMBERTON HEW JERSEY SITE
SAMPLE ON 8/17/79
ppbC
6.0
33.0
4.0
15.5
5.5
104.
239.
12.5
15.0
11.0
93.5
59.5
9.0
—
—
1.0
4.5
4.5
19.5
---
14.0
---
21.5
1.5
1.0
4.0
2.0
6.5
3.5
Hydrocarbon
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
1 -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2, 3-D1methyl butane
2-Methyl pentane
c-4-Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye 1 opentane
2 ,4-Dimethyl pentane
Benzene
Cyclohexane
ppbC Hydrocarbon
5.5 2, 3-Dimethyl pentane
6.0 3-Methyl hexane
2.0 2,2,3-Trimethylpentane
5.0 n-Heptane
3.0 Methyl cyclohexane
1.0 2, 4-Dimethyl hexane
1.0 2,3,4-THmethylpentane
23.0 Toluene
1.0 2, 3-Dimethyl hexane
3.0 2-Methyl heptane
2.0 3-Ethyl hexane
3.5 n-Octane
1.5 Ethyl cyclohexane
5.5 Ethyl benzene
13.0 p 4 m-Xylene
4.0 Styrene
8.0 o-Xylene
12.0 n-Nonane
2.0 i-Propyl benzene
9.5 n-Propyl benzene
4.5 p-Ethyl toluene
8.0 m-Ethyl tol uene
13.5 o-Ethyl tol uene
12.5 1, 3, 5-Trimethyl benzene
37.0 1, 2, 4-Trimethyl benzene
9.5 i, 2, 3-Trimethyl benzene
8.5 Me thy! styrene
4.0 1,3-Diethyl benzene
5.0 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefin
I Aromatic
z Paraffin
Acetylene
ppbC %
94 10
162 18
645 71
4
905
ppbC
Total Unidentified 216
Hydrocarbons
Total NMHC by 1121
summing individual
species :
169
-------
TABLE H3 . HYDROCARBON CONCENTRATIONS IN 0700-0800 DOWNINGTOWN PENNSYLVANIA SAMPLE
ON 8/17/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
4.0
75.5
5.5
4.0
3.5
6.0
25.5
15.0
8.5
0.5
1.5
5.0
3.5
5.5
2.0
1.5
4.0
1.0
Ethane
Ethylene
Acetyl ene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methyl pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyl eye1opentane
2,4-Dimethy1pentane
Benzene
Cyclohexane
2.0
2.0
4.0
2.0
1.0
13.0
1.0
1.0
1.5
2.5
8.5
1.0
3.5
2.5
3.
5.
2.5
2.0
.0
.0
3.0
6.0
2.0
1.0
2,3-Dimethy!pentane
3-Methylhexane
2,2,3-Trlmethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-Dtmethylhexane
2,3,4-Trlmethyl pentane
Toluene
2,3-01methylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethylcyclohexane
Ethyl benzene
p & m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
m-Ethyltoluene
o-Ethyltoluene
1,3,5-TrImethy1 benzene
1,2,4-TMmethyl benzene
1,2.3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
r Olefln
z Aromatic
£ Paraffin
Acetylene
ppbC %
81
39
118
6
244
33
16
49
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
36
280
170
-------
TABLE H4 . HYDROCARBON CONCENTRATIONS IN 0700-0800
ON 8/17/79
OnWNINGTOWN PENNSYLVANIA SAMPLE
ppbC
Hydrocarbon
ppbC
Hydrocarbon
4.0
50.0
2.0
2.5
2.0
4.0
10.0
9.5
4.5
1.0
3.0
2.0
2.5
1.0
.10
2.5
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methylcyclopentane
2,4-Dimethylpentane
Benzene
Cyclohexane
1.5 2,3-Dimethylpentane
1.5 3-Methylhexane
2.5 2,2,3-Trimethylpentane
1.0 n-Heptane
1.0 Methyl eyelohexane
2,4-D1methylhexane
2,3,4-Trlmethylpentane
7.0 Toluene
2,3-D1methylhexane
1.0 2-Methylheptane
0.5 3-Ethylhexane
n-Octane
Ethyl eyelohexane
1.5 Ethyl benzene
4.0 p & m-Xylene
Styrene
1.5 o-Xylene
1.0 n-Nonane
1-Propylbenzenfc=
1.0 n-Propylbenzene
1.0 p-Ethyl toluene
1.0 m-Ethyltoluene
2.5 o-Ethy!toluene
1.0 l,3,5-Trlmethylbenzene
1-5 1,2,4-Tr1methylbenzene
1,2,3-Trimethyl benzene
Methylstyrene
1,3-Dlethylbenzene
1,4-DIethyl benzene
Total Identified
Hydrocarbons
E Olefln
£ Aromatic
£ Paraffin
Acetylene
ppbC %_
52
25
55
2
133
39
19
41
2
Total Unidentified
Hydrocarbons
Total NMHC by
summing individual
species i
ppbC
10
143
171
-------
TABLE H5. HYDROCARBON CONCENTRATIONS IN 0800-0900
ON 8/17/79
DOWNINGTOWN PENNSYLVANIA SAMPLE
ppbC
Hydrocarbon
ppbC
Hydrocarbon
4.0
4.0
3.5
3.5
2.5
5.0
14.0
10.5
6.5
1.0
3.5
2.5
3.0
1.5
3.0
Ethane
Ethylene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
i-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methylbutane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye1opentane
2,4-Dlmethy1pentane
Benzene
Cyclohexane
1.5
1.5
1.5
1.5
7.5
1.0
3.0
8.5
1.0
4.0
2.0
1.0
.10
1.5
3.0
3.5
5.5
1.0
2,3-Dimethylpentane
3-Methylhexane
2,2,3-Tr1methylpentane
n-Heptane
Methyl eye1ohexane
2,4-Dlmethylhexane
2,3,4-Trlmethyl pentane
Toluene
2,3-D1methylhexane
2-Methylheptane
3-Ethylhexane
n-Octane
Ethyl eye1ohexane
Ethyl benzene
p 4 m-Xylene
Styrene
o-Xylene
n-Nonane
i-Propylbenzene
n-Propylbenzene
p-Ethyltoluene
ra-Ethy1toluene
o-Ethyltoluene
1,3,5-Trlmethylbenzene
1,2,4-Tr1«nethyl benzene
1,2,3-Trlmethylbenzene
Methylstyrene
1,3-01ethyl benzene
1,4-01ethyl benzene
Total Identified
Hydrocarbons
£ Olefln
£ Aromatic
E Paraffin
Acetylene
ppbC ^
7
42
49
4
102
7
42
48
3
Total Unidentified
Hydrocarbons
Total NMHC by
sunning Individual
species i
ppbC
44
146
172
-------
TABLE H6 . HYDROCARBON; CONCENTRATIONS IN 0900-1000 .DOWMIN6TOWN PENNSYLVANIA SAMPLE
Ofl 8/17/79
ppbC
Hydrocarbon
ppbC
Hydrocarbon
4.0
6.0
4.0
3.5
2.5
5.0
17.0
11.0
7.5
1.0
3.5
2.5
3.0
1.5
1.0
3.0
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-B:utene
t-Pentane
n-Pentane
1 -Pen ten e;
t-2-Pentene
c-2-Penten'e
Cycl op;en€ene
Cyel opentane
2,3:-Dimethyl butane
2-MethyTpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Methyleyclopentane
2,4-01methylpentane
Benzene
Cyclohexane
1.5 2,3-Dimethyl pentane
1.5 3 - Me thy 1 hexa ne
2.5 2,2,3-Trimethylpentane
1.5 n-Heptane
1^5 MethylcycTohexane :
2,4-Dimethylhexane
2,3,4-Trlraethyl pentane
9... 5 Tol uene
2,3-Dimethylhexane
2-Methylheptane
3-Ethylhexane
1.5 n-Octane
Ethyleyelohexane
3.0 Ethyl benzene
9.0 p & m-Xylene
1.0 Styrene
4.5 o-Xylene
4.0 n-Nonane
1-Propylbenzene
2.0 n-P ropy1 benzene
2.0 p- Ethyl' tol uene
2.5 m-Ethy 1 tol uene
6.5 o-Ethyl toluene
7.0 1,3,5-Trimelihyl benzene
13.5 1,2,4-Tri methylbenzene
1,2,3-Trimethyl benzene
Methyl styrene
1,3>Dfethyl benzene
1,4-D't e thy Tbenze ne
Total Identified;
Hydrocarbons
i OTefln
i Aromatic
i Paraffin
Acetylene
ppbC %.
1.0.
63
74
4
150
Total Unidentlfted
Hydrocarbons
Total NMHG. by
sumnri n'§ iirrdtvl dual
speerfes i
ppbC
111
261
17 3*
-------
TABLE H7 . HYDROCARBON CONCENTRATIONS IN DOWNTOWN LANCASTER SAMPLE ON 8/14/79
ppbC
27.5
48.0
14.0
12.0
18.5
25.0
68.5
6.5
9.5
3.5
—
85.5
42.5
- - —
—
— — —
1.0
5.0
9.0
35.5
2.0
23.0
1.5
24.5
2.5
1.5
17.5
8.5
26.5
5.0
Hydrocarbon
Ethane
Ethyl ene
Acetylene
Propane
Propene
1 -Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1 -Pentane
n-Pentane
1 -Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2, 3-D1methyl butane
2-Methyl pentane
c-4 -Methyl -2-pentene
3-Methyl pentane
1 -Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thyl eye 1 opentane
2, 4-D1ne thyl pentane
Benzene
Cyclohexane
ppbC Hydrocarbon
18.5 2, 3-Dime thyl pentane
19.5 3-Methyl hexane
42.0 2, 2, 3-Trlme thyl pentane
13.0 n-Heptane
10.0 Methyl cyclohexane
12.5 2, 4-D1methyl hexane
11.5 2,3,4-Trlmethylpentane
66.5 Toluene
2.0 2, 3-D1methyl hexane
16.0 2-Methyl heptane
12.0 3-Ethyl hexane
10.5 n-Octane
4.0 Ethyl cyclohexane
21.0 Ethyl benzene
80.0 p * m-Xylene
14 . 5 Styrene
41.0 o-Xylene
10.5 n-Nonane
3.5 i-Propyl benzene
9.5 n-Propyl benzene
29.0 p-Ethyl toluene
12.0 m-Ethyl toluene
27.0 o-Ethyl toluene
7-0 1, 3, 5-Trlmethyl benzene
9.0 l, 2, 4-Tr1methyl benzene
2-0 1, 2. 3 -Trl me thyl benzene
!-5 Methyl styrene
1,3 -D1 ethyl benzene
— 1,4-01 ethyl benzene
Total Identified
Hydrocarbons
£ Olefln
i Aromatic
i Paraffin
Acetylene
ppbC %
111 11
330 32
571 56
14 1
1026
ppbC
Total Unidentified 147
Hydrocarbons
Total NMHC by 1173
summing Individual
species
174
-------
TABLE H8 . HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED ON 8/14/79 IN
DOWNTOWN LANCASTER PENNSYLVANIA #1
ppbC
Hydrocarbon
ppbC
Hydrocarbon
21.5
38.
25.
11.5
22.5
39.0
44.0
5.5
6.5
2.5
45.5
25.0
8.5
1.5
3.0
12.5
12.0
12.0
1.0
1.5
6.0
2.0
16.5
4.0
Ethane
Ethylene
Acetyl ene
Propane
Propene
1-Butane
n-Butane
1-Butene
1-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentenc
t-2-Pentene
c-2-Pentene
CycTopentene
Cyclopentane
2,3-OtmethyTbutane
2-MethyT penta ne
c-4-Methyl-2-pentene
3-Methy1pentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene;
Ne thy1 eye1bpentane
2.4-D1methylpentane
Benzene
CycTohexane
7.0
8.0
6.0
6.5
4.5
2.0
1.5
29.5
2.0
3.5
5.5
5.5
2.5
7.0
19.0
3.0
10.5
3.0
8.0
4.5
4.0
7.0
2.0
2.0
1.0
1.5
1.0
2,3-Oimethyl pentane'
3-Methylhexane
2,2,3-Trtmethylpentane
n-Heptane
Methyl eye 1ohexane
2,4-Dlmethylhexane
2,3,4-Trlmethylpentane
Toluene
2,3-01methylhexane
2-Methyl heptane
3-Ethylhexane
n-Octane.
Ethyl eye 1ohexane
Ethyl benzene
p A m-Xylene
Styrene
o-Xylene
n-Nonane
1-Propy1 benzene
n-Propylbenzene
p-Ethyltoluene
m-Ethy1 toluene
o-Ethyltoluene
1,3,5-Tr1methy1 benzene
1,2,4-Trlmethylbenzene
1,2,3-Trlmethy 1 benzene
Methylstyrene
1,3-01ethyl benzene
1,4-01 ethyl benzene
Total Identified
Hydrocarbons
z Olefln
£ Aromatic
J: Paraffin
Acetylene
ppbC %.
91
HZ
293
26
520"
18
22
56
5
Total Unidentified
Hydrocarbons-
Total NMHe by
suami ng. 1 ndl v i"dua V
spec-les
PP*>C
105
625
175
-------
TABLE H9. HYDROCARBON CONCENTRATIONS IN SURFACE SAMPLE COLLECTED ON 8/14/79 IN
DOWNTOWN LANCASTER, PENNSYLVANIA #2
ppbC
Hydrocarbon
ppbC
Hydrocarbon
23.0
35.0
22.0
13.0
12.0
21.5
49.5
3.0
6.5
2.5
48.5
28.5
4.0
1.5
2.5
12.5
8.0
10.0
5.5
2.0
9.0
3.0
Ethane
Ethyl ene
Acetylene
Propane
Propene
1-Butane
n-Butane
1-Butene
i-Butene
t-2-Butene
c-2-Butene
1-Pentane
n-Pentane
1-Pentene
t-2-Pentene
c-2-Pentene
Cyclopentene
Cyclopentane
2,3-D1methyl butane
2-Methylpentane
c-4-Methyl-2-pentene
3-Methylpentane
1-Hexene
n-Hexane
t-2-Hexene
c-2-Hexene
Me thy! eye1 opentane
2,4-Dimethylpentane
Benzene
Cyclohexane
4.5 2,3-Dimethy1pentane
5.0 3-Methylhexane
3.5 2,2,3-Trlroethylpentane
4.5 n-Heptane
3.5 Methyl eyelohexane
1.5 2,4-Dimethylhexane
1.0 2,3,4-Trlmethylpentane
18.5 Toluene
1.5 2,3-Dlmethylhexane
3.0 2-Methylheptane
3.5 3-Ethylhexane
6.0 n-Octane
2.5 Ethyl eyelohexane
6.0 Ethyl benzene
15.5 P * m-Xylene
4.5 Styrene
10.0 o-Xylene
10.5 n-Nonane
1.5 i-Propy1 benzene
6.5 n-Propylbenzene
4.5 p-Ethyltoluene
6.0 m-Ethyltoluene
10.0 o-Ethyltoluene
4.5 1,3,5-Trlmethylbenzene
14.0 1,2,4-Trlmethylbenzene
2.5 1,2,3-Trimethylbenzene
2.5 Methylstyrene
1.5 1,3-01ethyl benzene
1.0 1,4-01ethyl benzene
Total Identified
Hydrocarbons
i Olefln
£ Aromatic
z Paraffin
Acetylene
ppbC %
70
111
279
22
483
14
23
58
5
Total Unidentified
Hydrocarbons
Total NMHC by
summing Individual
species i
ppbC
105
588
176
-------
TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1. REPORT NO.
EPA-450/4-80-022
2.
3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
Philadelphia Oxidant Enhancement Study:
Hydrocarbon Analysis
5. REPORT DATE
August 25. 1980
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
8. PERFORMING ORGANIZATION REPORT NO
H. Westberg and P. Sweany
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Chemical Engineering Department
Washington State University
Pullman, Washington 99164
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-02-3339
12. SPONSORING AGENCY NAME AND ADDRESS
Office of Air Quality Planning and Standards
Monitoring and Data Analysis Division
Environmental Protection Agency
Research Triangle Park, North Carolina 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
16. ABSTRACT
An extensive hydrocarbon monitoring program, including ground level and aerial
sampling, was conducted in the Philadelphia area during July and August of 1978.
Individual hydrocarbon identities and concentrations were determined in approxi-
mately 150 samples. One-hour integrated samples were collected each day during
the 0600-0700 and 0800-0900 EOT time periods at two Philadelphia locations.
Airborne sampling was performed by an EPA-Las Vegas helicopter.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS C. COSATI Field/Group
Ambient Hydrocarbon Species
Phildelphia
18. DISTRIBUTION STATEMENT
19. SECURITY CLASS (This Report)
Unclassified
21. NO. OF PAGES
188
2O. SECURITY CLASS (This page)
22. PRICE
EPA Form 2220-1 (Rev. 4-77)
PREVIOUS EDITION IS OBSOLETE
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