-------
Eastern Research Group, Inc.
MODIFIED METHOD 5 DATA SHEET
Run r$
Page 1 of 2-
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
U. *• "Sxtcc
9/t*/?7
ft, ^*c\c.i
- ->.o
Z-9.0^
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (eF)
Minimum Sample Volume (ft3)
Initial Leak Check •«£ \* '• Vu
Final Leak Check ,eo'tgv*<< *
;M8
4« V.OVG
ri^f}
o.OoTl
&.0b*2-
Meter Box Number
Meter delta H @ V -~>0<
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A-3-3
> <3. *?•»•*
O.99C
O . *Z \ O
7S
?>
9. C
n*
, »* « *
A^.-»k-'-*A'V
Diagram or Duct
Schematic of Traverse Point Layout
Read and record all data every 5> minutes
Traverse
Point
Number
Sampling
Time
(min)
O
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps),
in.H20)
Stack
Ts
(•F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
(•F)
Filter
Temp.
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
(•F)
Pump
Vacuum
(in.Hg)
I. -71
I. -7 \
61
43
Go
Go
fco
Z.oo
t.0
6'
-So
T-T.0.0
\ .<
t ,
7.0
•1-2-%- O
\.
\.
86
I0\o
•96
t , L'i
.O?
99
•170
G'i.
•I
70
•L -7 I
C.-2,
66
•J.
U.I
05-
So
LTo
.5-
1.-V6
Gr
93
.12-
I. v-v
C
4 1
I UD
. o
G7
%&
G 'i
". 9
fte
1 .t
_efi_
• x
\\
^5
^<
no
. 17
• LI
_27_
VI
JJ>_
t9lO
3.1-7,5-10
ifel
Gt
KS'x
''-V.I
G
Comments:
-------
Planl
Date
Location T>
Sample Type
"T. 0 ,
Run Number
Operator
Page "^of "2-
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps),
in.H20)
Stack
Ts
Orifice Pressure
Differential
(delta H. in H2O)
Desired
Actual
Probe
Temp.
CF)
Filter
Temp.
Adsorbent
Trap
Temp.
CF)
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in.Hg)
ft-
190 .
\.
M4
66
\ 'Jo
>v O
7. -to
94
8-V-
C'J
VO
fi
io oo
Qfe
l.oS
2.60
,\o
.9S
65
1 S'O
I O
C.G
. I O
\ (.0
. ! 0
.*; v
7-33
u s:
C,o
to-
64-
l.VA
7.-II
4:
. to
81
fffl
\99
.. 1 O
.75
1-OO
89
C.-L
7-40?
\
2.3'i
5'
710
10
C. l
90
l.x-%
Col
di
89
t.33
/.JC,
60
7.1
1 7
6 1
85
• IT
1.4
(. C'i-
43
£?
>. (iz
ZT8
t
17
I-
i.fc'J-
Comments:
-------
tERG
Eastern Research Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
PA
9-5- 3.-^^*
-X Hi~f.T /W8/2.'*i<\L. Cj % i & ( "£-£/?
ft/?
3
Ai-A.
A c tiort^ //^is-CJL I roL-^tsMt
1
Impinger
Number
1
2
3
4
5
6
7
Impinger
Solution
M-\
h°
/J>0
M 7
$.1*.
*
Amount of
Solution
(9)
tOOfnt
lOO^H
Impinger Tip
Configuration
Impinger Weight -Li • *
''''' Final
?(g)
5553
(<£%!}
sic$
%1.1
m/
Initial
(g) »
H^5.3>
G.I0.3L
5?O.X
45*20
75} £
Total Weight Gain (g)
Weight
Gain
(g>
L'd
L/^
, i
5.7
4/).1
* /
f- D > .(*
-------
Facility:
Date:
Location:
Run Number:
Sample Type:
US Intec
09/22/97
T.O. Outlet
1
M23
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
3ercent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)
240.0
30.18
.30.18
0.00
408.71
962.11
145.560
1.18
95.27
139.90
1.9
19.0
79.1
0.9840
0.310
0.84
0.574
137.775
3.902
4.57
0.954
29.06
28.56
1917.92
584.58
12814.26
362.90
7495.50
212.27
97.63
N/A
0.00
0.00
0.00
0.00
-------
Plant
Date
Sampling Location
Sample Type
Run Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intial Leak Check
US Intec
09/22/97
T.O. Outlet
M23
1
MKO
84
30.18
0
.012@15"
Probe Length & Type
Nozzle ID (in)
Meter Box Number
Meter Delta H@
Dry Gas Meter Factor (Yd)
K Factor
Probe Heater Setting
Heater Box Setting
Pilot Constant
Final Leak Check
4' glass
A-38
0.31
1.828
0.984
5.98
250
0.84
.011@5"
Height of Location (ft)
Moisture Collected (g)
C02 Percent
02 Percent
N2 Percent
Parbculate Catch (g)
Stack Geometry (R or C)?
Stack Diameter (in)
Stack Width (If Rectangle)
0
139.9
1.8
19
79.1
35
US Intec
09/22/97
M23
Sampling
Traverse Time
Point (min)
Location
A-12
11
10
9
8
7
6
5
4
3
2
1
B-12
11
10
9
8
7
6
5
4
3
2
1
Q
10
20
30
40
50
60
70
80
90
100
110
120
10
20
30
40
50
60
70
80
90
100
110
120
Clock
Time
(24 hr)
1450
1500
1510
1520
1530
1540
1550
1600
1610
1620
1630
1640
1650
1725
1735
1745
1755
1805
1815
1825
1835
1845
1855
1905
1915
1925
Dry Gas Orifice
Meter Velocity Pressure
Reading Head Diff
Vm (ff) (f P) @H)
(in H20) (in H20)
523 575 • • •
528.64
535.36
541.43
546.63
551.84
557.43
564.72
570.05
575.94
583.05
589.46
596.24
596.345
602.55
607.48
615.57
621.45
628.62
633.43
639.25
645.15
651.45
657.63
663.23
669.24
0.2
0.19
0.18
0.15
0.15
0.17
0.2
0.2
0.22
0.24
0.24
0.22
0.23
0.21
0.21
0.19
0.17
0.17
0.18
0.19
0.18
0.2
0.21
0.24
1.19
1.13
1.07
0.89
0.89
1.01
1.19
1.19
1.31
1.43
1.43
1.43
1.37
1.25
1.25
.13
.01
.01
.07
.13
.01
.19
.25
.43
Stack Dry Gas Meter Impinger
Temp Temperature Exit Pump
Ts Tm in Tm out Temp Vacuum
(F) (F) (F) (F) (inH20)
413
413
410
413
408
407
406
411
405
403
401
404
409
409
412
410
407
407
415
408
411
407
412
408
87
94
95
98
104
106
105
102
102
99
93
94
97
104
101
101
101
101
101
100
99
97
98
97
87
88
88
89
94
97
98
96
95
98
90
91
91
92
92
91
90
91
91
90
90
89
89
90
61
62
54
59
57
58
60
66
61
61
61
61
59
58
63
65
64
65
64
65
65
65
65
64
2
3
4
4
4
4
4
4
4.5
4.5
4.5
4.5
4
4
4
4
4
4
4
4
4
4
4
4
END
Average
Meter
Temp
A-12
11
10
9
8
7
6
5
4
3
2
1
B-12
11
10
9
8
7
6
5
4
3
2
1
87.0
91.0
91.5
935
99.0
101.5
101.5
99.0
985
98.5
91.5
325
94.D
98.0
96.5
96.0
95.5
96.0
96.0
95.0
94.5
93.0
93.5
935
END
95.27083
-------
Eastern Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant
Date
Operator tfXAf/b.
Sampling Location
Sample Type
Run Number
Static Piessure (±) (in. H2QL
Barometric Pressure (in. H2O)
(j£ £V^£|
f.7,1 *ft
faffaf'
M.ktf
filc/rth }
/
n , & <^_
1,0 '///5
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check 0 o
Final Leak Check 0'(>/0
1-*? £•>
£/ s-kl'
* f6?
I l^af/S'
af ** "
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A"-J$8
/.fi'fe
fa (~3 /* jf
V / £t f~
£^ft
ft &
£~r&
7-7$
^ ^
. / ... . 0~ /
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page of
Traverse
Point
Number
i
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps),
in.H20)
Stack
Ts
(•F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
m
Filter
Temp.
(°F)
t.
Adsorbent
Trap
Temp.
(•F)
• <• .
Dry Gas Meter
Inlet Outlet
(Tm In) (Tm out)
1
Impinger
Exit
Temp.
(•F)
Pump
Vacuum
(in.Hg)
—
Comments:
-------
tERG
Eostem Reseorcn Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
m
<>* L
)i>t>.^L
Impinger Tip
Configuration
ttkz?
W££
h£f
*>6S
** 6$
Impinger Weig
Final
(g)
Initial
(g)
43S5"
SHI.']
G>o^
HVS
!n^.\
Total Weight Gain (g)
ht
Weight
Gain ;
(i) *
5^05
5V?,1
\qs i}^ | "• t-
GO'S.0!
nni
%1H
1 9 ^
-, D
H \^
-------
Facility:
Date:
Location:
Run Number:
Samole Tvoe:
US Intec
09/23/97
T.O. Outlet
2
M23
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)
240.0
29.92
29.92
0.00
403.42
962.11
147.570
1.15
90.42
160.10
1.9
19.0
79.1
0.9840
0.310
0.84
0.582
139.707
3.9.56
5.13
0.949
29.06
28.50
1900.37
579.23
12697.03
359.58
7364.83
208.57
100.75
N/A
0.00
0.00
0.00
0.00
-------
Plant
Date
Sampling Location
Sample Type
Run Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intial Leak Check
US Intec
09/23/97
M23
Traverse
Point
Location
A-12
11
10
9
8
7
6
6
4
3
2
1
B-12
11
10
9
8
7
6
5
4
3
2
1
Sampling
Time
(min)
0
10
20
30
40
50
60
70
80
90
100
110
120
10
20
30
40
50
60
70
80
' 90
100
110
120
US Intec
09/23/97
T.O. Outlet
M23
2
MKO
84
29.92
0
.017@10"
Dry Gas
Clock
Time
(24 hr)
1015
1025
1035
1045
1055
1105
1115
1125
1135
1145
1155
1205
1215
1240
1250
1300
1310
1320
1330
1340
1350
1400
1410
1420
1430
1440
Meter
Reading
Vmfft3)
669.24 -
677.42
683.22
690.03
695.95
703.65
709.84
715
720.75
726.28
732.26
738.83
744.79
744.86
749.99
755.75
761.73
767.55
773.13
779.33
784.48
790.53
797.04
803.15
810.1
816.88
Velocity
Head
(IP)
(in H2O)
0.2
0.21
0.25
0.23
0.23
0.2
0.17
0.16
0.16
0.18
0.2
0.22
0.16
0.17
0.17
0.16
0.15
0.17
0.17
0.18
0.2
0.24
0.25
0.21
Probe Length & Type 4' glass
Nozzle ID (in) 0.31
Meter Box Number A-38
Meter Delta H@ 1.828
Dry Gas Meter Factor (Yd) 0.984
K Factor 5.98
Probe Heater Setting 250
Heater Box Setting
Pitot Constant 0.84
Final Leak Check .008@1 0"
Orifice
Pressure
Diff
SH>
(in H2O)
.19
.25
.47
.37
.37
.15
.01
0.95
0.95
1.07
1.19
1.31
0.95
1.01
1.01
0.95
0.88
1.01
.01
.07
.19
.43
.49
1.25
Stack
Temp
Ts
(F)
393
399
405
408
407
406
409
406
408
397
404
404
389
395
398
400
401
400
406
407
409
409
412
410
Dry Gas Meter
Temperature
Tm in Tm out
(F)
86
95
95
99
99
99
100
99
100
94
95
96
88
90
96
92
93
93
95
94
95
97
96
97
(F)
84
83
83
86
86
87
88
91
92
87
85
86
84
83
84
83
84
S4
84
86
86
86
87
88
Impinger
Exit
Temp
(F)
60
61
62
58
56
57
57
58
60
62
63
62
66
64
62
63
56
57
59
63
65
66
67
67
Height of Lc
Moisture Cc
C02 Percer
O2 Percent
N2 Percent
Paniculate (
Stack Georr
Stack DiarrH
Stack Width
Pump
Vacuum
(in H2O)
1
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
0
160.1
1.9
19
79.1
35
END
END
Average
Meter
Temp
(F)
A-12
11
10
9
8
7
6
5
4
3
2
1
B-12
11
10
9
8
7
6
5
4
3
2
1
85.0
89.0
89.0
92.5
92.5
93.0
94.0
95.0
96.0
90.5
90.0
91.0
86.0
86.5
90.0
87.5
88.5
86.5
89.5
90.0
90.5
91.5
91.5
92.5
90.41667
-------
Eastern Research Group, Inc.
MODIFIED METHOD 6 DATA SHEET
Run
Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
MfO
f^
Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
7 &f~(
-------
Page of
Plant •
Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
;
Sampling
Time
(min)
Clock
Time
(24hr)
^
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
CF)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
(°F)
Filter
Temp,
(°F)
\
•
Adsorbent
Trap
Temp.
CF)
DryGa
Inlet
(Tm In)
s Meter
Outlet
(Tm out)
Impinger
Exit
Temp.
(°F)
Pump
Vacuum
(in.Hg)
Comments:
-------
feERG
Eastern Research Group, Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
PPi
06>TL£T lEH££/VrlL ^X/Al^c^
£s /F
sC
M.A,
M -e T Ji.n //\CA)^ l~TOLU?t
1
Impinger
Number
1
2
3
4
5
6
7
Impinger
; Solution
MT
l^V
i^o
M-J
^.fc,
*
Amount of
Solution
(g)
(OOnJL
;DC«JL
Impinger Tip
Configuration
KC?
M u5
M^S
MUS
MtS
Imptnger Weight ' j> ^
Final
(9)
5S3.3
SWS
5%%.O
Wss
•^i.x
Initial
(g)
y^tc
""
5-^^.3,
ffS^.3
*mo
9iS.T
Total Weight Gain (g)
Weight,
Gainfl
(g) -i?
!!\.3
•2.
, ^
: n
! I
3.^
^.0
/^.'
-------
Facility: US Intec
Date: 09/23/97
Location: T.O. Outlet
Run Number: 3
Samole Type: M23
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.92
Absolute Stack Pressure (in Hg) 29.92
Stack Static Pressure (in H2O) 0.00
Average Stack Temperature (°F) 401.42
Stack Area (sq in) 962.11
Actual Meter Volume (cu ft) 144.216
Average Meter Pressure (in H2O) 1.15
Average Meter Temperature (°F) 90.54
Moisture Collected (g) 141.70
Carbon Dioxide Concentration (%V) 1.9
Oxygen Concentration (%V) 19.0
Nitrogen Concentration (%V) 79.1
Dry Gas Meter Factor 0.9840
Nozzle Diameter (in) 0.310
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.569
Standard Metered Volume (dscf) 136.496
Standard Metered Volume (dscm) 3.866
Stack Moisture (%V) 4:67
Mole Fraction Dry Stack Gas 0.953
Dry Molecular Weight 29.06
Wet Molecular Weight 28.55
Stack Gas Velocity (fpm) 1895.97
Stack Gas Velocity (mpm) 577.89
Volumetric Flow Rate (acfm) 12667.61
Volumetric Flow Rate (acmm) 358.75
Volumetric Flow Rate (dscfm) 7400.53
Volumetric Flow Rate (dscmm) 209.58
3ercent Isokinetic 97.96
Percent Excess Air N/A
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0 00
-------
Plant
Date
Sampling Location
Sample Type
Run Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intel Leak Check
US Intec
09/23/97
M23
Sampling
Traverse
Point
Location
A-1
2
3
4
5
6
7
8
9
10
11
12
B-1
2
3
4
5
6
7
8
9
10
11
12
Time
(min)
10
20
30
40
50
60
70
80
90
100
110
120
10
20
30
40
50
60
70
80
90
100
110
120
US Intec
09/23/97
T.O. Outlet
M23
3
MKO
78
29.92
0
0.014@10"
Dry Gas
Clock Meter
Time
(24 hr)
171ft
1 r I v
1720
1730
1740
1750
1760
1800
1810
1820
1830
1840
1850
1900
1940
1950
2000
2010
2020
2030
2040
2050
2100
2110
2120
2130
2140
Reading
Vm(fP)
04Q C4R
O I !7.O*»3
825.69
832.25
838.63
845.62
852.14
858.88
864.89
870.43
875.92
882.17
888.62
895.055
895.095
900.34
905.69
911.43
916.26
922.02
927.93
933.02
939.46
945.63
951.83
958.02
963.901
Velocity
Head
if)
(in H2O)
0.17
0.24
0.25
0.24
0.23
0.23
0.19
0.15
0.17
0.19
0.22
0.22
0.14
0.14
0.16
0.17
0.15
0.17
0.16
0.17
0.19
0.22
0.24
0.24
Probe Length & Type 4' glass
Nozzle ID (in) 0.31
Meter Box Number A-38
Meter Delta H@ 1.828
Dry Gas Meter Factor (Yd) 0.984
K Factor 5.98
Probe Heater Setting 250
Heater Box Setting
Pilot Constant 0.84
Final Leak Check 0.009@9"
Orifice
Pressure Stack Dry Gas Meter
DifT
fH)
(in H2O)
1.01
1.43
1.49
1.43
1.37
1.37
1.13
0.89
1.01
1.13
1.31
1.31
0.83
0.83
0.95
1.01
0.89
1.01
0.95
1.01
1.13
1.31
1.43
1.43
Temp
Ts
(F)
376
399
402
401
401
402
405
406
408
407
406
403
392
397
399
397
398
398
404
405
407
409
405
407
Temperature
Tmin
(F)
80
90
91
94
95
96
100
100
100
101
101
101
88
93
95
95
95
95
95
94
95
96
96
97
Tmout
(F)
79
81
82
84
85
86
87
89
89
89
90
91
87
85
86
86
85
86
86
86
85
86
86
87
Impinger
Exit
Temp
(F)
64
58
59
64
59
60
62
62
62
64
64
63
63
64
67
64
63
64
65
62
62
63
64
65
Height of Lc
Moisture Co
CO2 Percer
O2 Percent
N2 Percent
Paniculate (
Stack Georr
Stack Diami
Stack Width
Pump
Vacuum
(in H20)
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
0
141.7
1.9
19
79.1
END
END
Average
Meter
Temp
(F)
A-1
2
3
4
5
6
7
8
9
10
11
12
B-1
2
3
4
5
6
7
8
9
10
11
12
79.5
85.5
86.5
89.0
90.0
91.0
93.5
94.5
94.5
95.0
95.5
96.0
87.5
89.0
90.5
90.5
90.0
90.5
90.5
90.0
90.0
91.0
91.0
92.0
90.54167
-------
Eastern Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Schematic of Traverse Point Layout
Read and record all data every /£? mlnutec
— ' / ? ^
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),ft3
Velocity
Head
((delta Ps),
in.H20)
Stack
Ts
CF)
Orifice Pressure
Differential
(delta H. in.H2O)
Desired Actual
Probe
Temp.
CF)
Filter
Temp.
Adsorbent
Trap
Temp.
(•F)
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
CF)
Pump
Vacuum
(in.Hg)
Comments
-------
of
Plant
Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
*
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
CF)
Orifice (
Diffe
(delta H
Desired
3ressure
rential
in.H2O)
Actual
Probe
Temp.
CF)
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
CF)
DryGa
Inlet
(Tm in)
s Meter
Outlet
{Tm out)
\
Impinger
Exit
Temp.
CF)
Pump
Vacuum
(in.Hg)
Comments:
-------
tERG
Eastern Research Group, inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plants •••• ' :x/:::x 1
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
PA
ntt-~\UcT7 T/-/€/2W\i £y/Gi9£&
£& p\/
-------
Facility: US Intec
Date: 09/22/97
Location: T.O. Inlet
Run Number: 1
Samole Tvoe: MSA
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.98
Absolute Stack Pressure (in Hg) 29.47
Stack Static Pressure (in H2O) -7.00
Average Stack Temperature (°F) 88.08
Stack Area (sq in) 962.11
Actual Meter Volume (cu ft) 162.722
Average Meter Pressure (in H2O) 1.49
Average Meter Temperature (°F) 95.28
Moisture Collected (g) 93.90
Carbon Dioxide Concentration (%V) 0.0
Oxygen Concentration (%V) 20.9
Nitrogen Concentration (%V) 79.1
Dry Gas Meter Factor 0.9840
Nozzle Diameter (in) 0.315
Pilot Constant 0.84
Average Sampling Rate (dscfm) 0.638
Standard Metered Volume (dscf) 153.199
Standard Metered Volume (dscm) 4.339
Stack Moisture (%V) 2.81
Mole Fraction Dry Stack Gas 0.972
Dry Molecular Weight 28.84
Wet Molecular Weight 28.53
Stack Gas Velocity (fpm) 1302.50
Stack Gas Velocity (mpm) 397.00
Volumetric Flow Rate (acfm) 8702.43
Volumetric Flow Rate (acmm) 246.45
Volumetric Flow Rate (dscfm) 8024.07
Volumetric Flow Rate (dscmm) 227.24
Dercent Isokinetic 98.21
Percent Excess Air N/A
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) QQQ
-------
Plant
Date
Sampling Location
, Sample Type
Run Number
'Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intial Leak Check
US Intec
09/22/97
MSA
Sampling
Traverse
Point
Location
B-1
1
1
1
2
2
2
2
3
3
3
3
4
4
4
4
5
5
5
5
6
6
6
6
A-6
6
6
6
5
5
5
5
4
4
4
4
3
3
3
3
2
2
2
2
1
1
1
1
Time
(min)
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
• 110
115
120
120
125
130
135
140
145
150
155
160
165
170
175
180
185
190
195
200
205
210
215
220
225
230
235
240
US Intec
09/22/97
T.O. Inlet
MSA
1
MWH/BJ
85
29.98
-7
.016@15"
Dry Gas
Clock
Time
(24 hr)
1450
1455
1500
1505
1510
1515
1520
1525
1530
1535
1540
1545
1550
1555
1600
1605
1610
1615
1620
1625
1630
1635
1640
1645
1650
1725
1730
1735
1740
1745
1750
1755
1800
1805
1810
1815
1820
1825
1830
1835
1840
1845
1850
1855
1900
1905
1910
1915
1920
1925
Meter
Reading
Vm(fP)
11.5UZ -
14.800
18.000
21.000
24.000
27.000
29.600
32.600
35.700
37.400
39.100
40.600
43.000
46.000
48.700
52.500
57.100
61.400
63.400
67.400
70.600
74.200
78.700
82.000
85.671
85.712
89.600
94.200
97.700
101.900
106.000
109.500
113.500
118.100
121.500
124.600
127.900
130.800
134.300
137.3
139.4
142.2
144.8
148.2
151.6
155.8
159.8
164.2
168.2
174.265
Velocity
Head
fP)
(in H2O)
0.11
0.12
0.11
0.12
0.1
0.1
0.1
0.1
0.03
0.03
0.03
0.03
0.14
0.14
0.16
0.14
0.19
0.16
0.16
0.15
0.18
0.17
0.17
0.19
0.2
0.2
0.19
0.19
0.18
0.19
0.19
0.19
0.16
0.16
0.16
0.16
0.07
0.09
0.09
0.07
0.12
0.12
0.14
0.12
0.3
0.3
0.3
0.3
Probe Length & Type 4' Boro
Nozzle ID (in) 0.315
Meter Box Number A-40
Meter Delta H@ 1.791
Dry Gas Meter Factor (Yd) 0.984
K Factor 10.13
Probe Heater Setting 108
Heater Box Setting
Pilot Constant 0.84
Final Leak Check
Orifice
Pressure
Diff
<£H)
(in H2O)
1.11
1.22
1.11
1.22
1.01
1.01
1.01
1.01
0.3
0.3
0.3
0.3
1.42
1.42
1.62
1.42
1.92
1.62
1.62
1.52
1.82
1.72
1.72
1.92
2.03
2.03
1.92
1.92
1.82
1.92
1.92
1.92
1.62
1.62
1.62
1.62
0.071
0.91
0.91
0.71
1.22
1.22
1.42
1.22
3.04
3.04
3.04
3.04
Stack
Temp
Ts
(F)
92
91
92
93
89
90
92
93
93
94
93
93
93
93
92
92
89
80
80
82
84
84
86
88
90
90
89
86
85
85
86
87
87
87
88
88
88
88
88
88
87
87
87
87
83
83
83
83
Dry Gas Meter
Temperature
Tm in Tm out
(F)
97
104
105
105
105
105
105
105
103
102
102
102
105
106
107
107
107
102
102
102
102
102
102
102
95
98
100
100
100
100
99
99
99
99
99
99
98
98
100
100
101
101
101
101
103
102
102
102
(F)
87
88
89
90
91
90
91
92
92
92
93
93
93
93
93
94
94
95
94
93
92
92
91
91
87
87
87
87
87
86
86
85
85
85
85
85
85
85
85
85
85
86
86
86
86
87
87
87
Impinger
Exit
Temp
(F)
69
59
60
60
62
63
63
62
63
65
66
66
65
63
63
64
63
61
61
61
62
63
63
65
72
60
62
66
.68
65
64
65
66
66
67
68
68
68
67
63
62
62
61
61
62
62
65
64
Height of Lc
Moisture Co
C02 Percer
O2 Percent
N2 Percent
Paniculate (
Stack Georr
Stack Diami
Stack Width
Pump
Vacuum
On H20)
1
1
1
1
1
1
1
1
0.5
0.5
0.5
0.5
2
2
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
3
3
3
3
3
3
3
3
3
3
3
3
2
• 2
2
2
2
2
2
2
5
5
5
5
0
93.9
0
20.9
79.1
35
END
END
Average
Meter
Temp
(F)
B-1
1
1
1
2
2
2
2
3
3
3
3
4
4
4
4
5
5
5
5
6
6
6
6
0
A-6
6
6
6
5
5
5
5
4
4
4
4
3
3
3
3
2
2
2
2
1
1
1
1
92.0
96.0
97.0
97.5
98.0
97.5
98.0
98.5
97.5
97.0
97.5
97.5
99.0
99.5
100.0
100.5
100.5
98.5
98.0
97.5
97.0
97.0
96.5
96.5
91.0
92.5
93.5
93.5
93.5
93.0
92.5
92.0
92.0
92.0
92.0
92.0
91.5
91.5
92.5
92.5
93.0
93.5
93.5
93.5
94.5
94.5
94.5
94.5
95.28125
-------
E««t*m fVeieinch Group, Inc.
A
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant U. *. XV^cf
Date ? /X.T-/ 11
Operator
Sampling Location T.o. irsA*^
Sample Type JA 5 V\
Run Number 1
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O) |o)S
/V\ |^l- gfj
If^A
|
*^ II J 1 -V
2-»<,'' . *" ^ ;-^
\ — LL y- - -^
0 A
, ^ \-
10'°|%C)L- 6.C 0«- 71 1 7" ^T. Diagram of Duct
Schematic of Traverse Point Layout ^^^ v[«..u^ o
Read and record all data every -S minutes
Comments:
-------
Page 1* of T^
Plant
Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(•F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
CF)
._ i^^^
Temp.
Temp.
_C±L
Dry Gas Meter
Inlet
(Tm In)
Outlet
(Tm out)
Impinger
Exit
Temp.
CF?
Pump
Vacuum
(in-Hg)
W&
no
3^
. 30
203
"72,
60
•3-0
IH*
tol-
( 0 0
1 O
33:
/oe>
jq
7 GO
3-0
13-5
J&-
/o
•s-o
>(e>o
((V- i
•9Z-
ss
SO
. /o
Li-Z
/oS
^
/^Q
66
AtoL
/O
8rS
•s.o
!
I'VS
: 20
SS
«o
1.0
3
0 ,
(40
/of-
/O6
i^.
loo
HI,
/QO
f 2.
III.
*
2.D
l/o
A
r-'iT-
its
/o/
2 -0
S
/.
-------
fcERG
Eastern Research Group, inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant •• >: y:0::H«:- ^:
Date i
Sampling Location
Sample Type ,
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number -**
XAD Number
M
flttfa
J»lek ~TltoJ( />2i?/y^
3&
1
M-fl
r^
Q^tfOtfl -C^ ^ ''
AJ$
Impinger
Number ;
1
2
3
4
5
6
7
• vtrripinger
Solution
Jkc
•^rr
/l^
\
x ,/°\T
// >,
-W^'
$/?.
Amount of
Solution
(g)
J»D*L
K- L
/ V L/ J-i I_3
Impinger Tip
Configuration
h63
6$
fr,6S
fr&S
i Impinger Weig ht
Final
(g)
( CVCL70^\
V^-S.i'UA/ J
C.SH'3
ie^^fc' )
GiS,^
50 1 >
^,0
Initial
(g)
5S(^.O
G^'l^
+^.(o
II K i j r\
q-4 M Ji
-t I ' U V
^S0.3
Total Weight Gain (g)
Weight
Gain
(g)
4?.^>
!.?
r4 *
•C& ^
>h.
^.^
** I
-------
Facility:
Date:
Location:
Run Number:
Samole Tvoe:
US Intec
09/23/97
T.O. Inlet
2
MSA
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)
240.0
29.92
29.41
-7.00
84.73
962.11
150.965
1.28
89.49
109.80
0.0
20.9
79.1
0.9840
0.310
0.84
0.598
143.442
4.062
3.48
0.965
28.84
28.46
1201.82
366.32
8029.80
227.40
7382.71
209.08
103.20
N/A
0.00
0.00
0.00
000
-------
Plant
Date
Sampling Location
Sample Type
Run Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intial Leak Check
US Intec
09/23/97
MSA
Sampling
Traverse
Point
Location
B-1
1
1
1
2
2
2
2
3
3
3
3
4
4
4
4
5
5
5
5
6
6
6
6
A-6
6
6
6
5
5
S
5
4
4
4
4
3
3
3
3
2
2
2
2
1
1
1
1
Time
(min)
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
. 105
110
115
120
120
125
130
135
140
145
150
155
160
165
170
175
180
185
190
195
200
205
210
215
220
225
230
235
240
US Intec Probe Length & Type 4' glass
09/23/97 Nozzle ID (in) 0.31
T.O. Inlet Meter Box Number A-40
MSA Meter Delta H@ 1.791
2 Dry Gas Meter Factor (Yd) 0.984
MWH K Factor 10.13
80 rain Probe Heater Setting 108
29.92 Heater Box Setting
-7 Pilot Constant 0.84
0.01 @1 0" Final Leak Check
Dry Gas Orifice
Clock
Time
(24 hr)
1015
1020
1025
1030
1035
1040
1045
1050
1055
1100
1105
1110
1115
1120
1125
1130
1135
1140
1145
1150
1155
1200
1205
1210
1215
1240
1245
1250
1255
1300
1305
1310
1315
1320
1325
1330
1335
1340
1345
1350
1355
1400
1405
1410
1415
1420
1425
1430
1435
1440
Meter
Reading
Vm(fP)
176.209 •
179.600
182.600
186.100
189.200
192.200
194.900
197.700
200.500
202.400
203.700
205.300
207.200
211.600
212.600
216.700
219.400
223.600
226.800
230.400
234.400
237.300
241.400
244.900
248.555
248.762
252.600
256.800
260.400
264.800
268.400
270.900
275.400
279.100
282.800
286.500
290.800
294.800
296.700
298.1
300
302.4
305.3
308
310.9
315.4
318.4
320.6
323.8
327.381
Velocity
Head
(IP)
(in H2O)
0.14
0.14
0.13
0.11
0.1
0.09
0.09
0.09
0.03
0.03
0.03
0.03
0.12
0.13
0.16
0.13
0.16
0.16
0.14
0.16
0.16
0.16
0.16
0.16
0.19
0.18
0.18
0.16
0.18
0.18
0.2
0.19
0.16
0.16
0.16
0.18
0.03
0.03
0.05
0.05
0.12
0.1
0.09
0.1
0.15
0.15
0.12
0.14
Pressure
Diff
dH)
(in H2O)
1.42
1.42
1.32
1.11
1.01
0.91
0.91
0.91
0.3
0.3
0.3
0.3
1.22
1.32
1.62
1.32
1.62
1.62
1.42
1.62
1.62
1.62
1.62
1.62
1.92
1.82
1.82
1.62
1.82
1.82
2.02
1.92
1.62
1.62
1.62
1.82
0.3
0.3
0.5
0.5
1.22
1.01
0.91
1.01
1.52
1.52
1.21
1.42
Stack
Temp
Ts
(F)
83
82
85
87
85
84
86
85
88
89
89
90
92
90
87
85
83
80
79
80
81
81
83
83
83
82
81
82
81
82
83
84
86
87
86
86
86
86
87
86
87
87
88
88
83
84
83
82
Dry Gas Meter
Temperature
Tm in Tm out
(F)
93
97
98
99
100
100
100
100
97
97
97
97
102
101
100
99
98
96
94
94
94
94
95
95
93
98
98
99
99
99
100
100
100
99
99
100
96
94
95
95
98
99
99
99
100
100
100
100
(F)
82
83
83
84
85
87
85
86
86
86
86
87
87
87
87
87
87
85
85
85
84
84
83
84
82
82
83
84
84
84
84
84
84
85
85
84
85
84
84
84
84
84
85
85
85
85
85
85
Height of Lo
Moisture Co
CO2 Percen
O2 Percent
N2 Percent
Paitculate C
Stack Geom
Stack DiamE
Stack Width
Impinger
Exit
Temp
(F)
63
56
55
58
61
63
64
65
67
66
65
64
61
58
58
57
58
58
58
58
58
58
58
58
70
53
53
55
56
56
56
55
56
56
56
56
58
60
61
59
59
57
57
59
58
58
59
59
Pump
Vacuum
(in H20)
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1
1
1
1
1.5
1.5
2
2
2
2
2
2
2
2
2
2
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
0.5
0.5
0.5
0.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
2
0
109.8
0
20.9
79.1
35
END
END
Average
Meter
Temp
(F)
B-1
1
1
1
2
2
2
2
3
3
3
3
4
4
4
4
5
5
5
5
6
6
6
6
0
A-6
6
6
6
5
5
5
5
4
4
4
4
3
3
3
3
2
2
2
2
1
1
1
1
87.5
90.0
90.5
91.5
92.5
93.5
92.5
/93.0
•'91.5
91.5
\91.5
92.0
94.5
.'94.0
93.5
93.0
! 92.5
V^O.5
89)5
8,9.5
£9.0
/89.0
.' 89.0
i 89.5
1 2.5
.-'90.0
/ 90.5
/ 91.5
/ 91.5
'V 91.5
X>-v92.0
92.0
/92.0
/92.0
/ 92-0
V. 92.0
? 90.5
/ 89.0
' 89.5
89.5
91.0
S. 91.5
/ 92.0
/ 92.0
\ 92.5
\ 92.5
/ 92.5
/ 92.5
'.48958
-------
Eaitrm Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant
Date
*-v .
Sampling Location
Sample Type
Run Number
Static Pressure (i) (in. H2O)
Barometric Pressure (in. H2O)
V<>3
&\ I \. iL
* fl *Or1
(rVJc
fl\£
2,
-?•(
•23.C-
A/T&C.
?/9>
- fJ0
/f
3 *
M-
XAD Trap Number
Filter Heater Setting (°F)
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
fjjft
(OS
(I t *• -j.
i O"^T*^
/O
\ S'i
i CO
\.S'
109
V ox
voo
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••30
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41-
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3
II
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lot
VC,
(-0
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Go
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til
/ot,
97-
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1-37.
t 0
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20
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so
I-ML.
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IEL
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.62.
//O
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/0
C v(
JIl
IIC,
&-
2.^0
IZo
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1 (
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joG
1^
10
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page of
Traverse
Point
Number
Sampling
Time
(mini
Clock
Time
24hr)
£
Gas
Meter
Reading
Vm),ft3
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(•F)
Orifice Pressure
Differentia!
(delta H, in.H2O)
Desired
Actual
Probe
Temp.
Filter
Temp.
CF)
CF)
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
PF)
Pump
Vacuum
(In.Ha)
no
-1 . C,
t •
firl.
10
2-S
/:*.', So
I.Sl-
4*3-
I O o
25
I HO
li '. 00
dfc
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VI.
.
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/OO
f -q
no
/oo
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i.GT.
1(0
/O 0
. /C,
no
sc.
2. S
,/fe
/oo
.
tS
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no
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s
S*
. f
•30
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a
(DO
(10
G/
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/V.'OO
05
SO
• 50
yo/
(/o
59
20$
1-2.1.
5
fi'./o
. (0
1.01
HO
7-2.0
/ V.' £0
. (0
H t
/s
2.2 C
1,52.
lot
Ml
too
/•r
2.50
J oO
fog
/oo
fcS"
LIZ
. iZ:
I a\
zvo
-£Q_3_
^J2L
Comments:
-------
tERG
Eastern Research Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
P^
q ~2L3-(?rf
T/VL£T ~TH££NM &*\ f\\^E^
5"A
^
.
-rce
illy,'1! Li'9/X77 /'-'j 7"'/
/M/A
Impinger
Number
1
2
3
4
5
B
7
Impinger
Solution
H*0
^0
MT
<>.&.
Amount of
Solution
(9)
ICOnfi
lOOrtL
Impinger Tip
Configuration
Mu-5
ts
Mb*>
Mb5
Impinger Weight
Final
(9)
(.S10
57Y.1
Mi3£;
7>l.(p
Initial
: (g)
sw.z
522-3
^^.H
73^5
Total Weight Gain (g)
Weight
Gain
(g)
:'- 6 • <*
!J? . (£>
"~~r \o
j;. /
.//? ^ 3
-------
Facility: US Intec
Date: 09/23/97
Location: T.O. Inlet
Run Number: 3
Samole Tvoe: M5A - PM
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.89
Absolute Stack Pressure (in Hg) 29.38
Stack Static Pressure (in H2O) -7.00
Average Stack Temperature (°F) 85.00
Stack Area (sq in) 962.11
Actual Meter Volume (cu ft) 149.725
Average Meter Pressure (in H2O) 1.24
Average Meter Temperature (°F) 87.89
Moisture Collected (g) 103.90
Carbon Dioxide Concentration (%V) 0.0
Oxygen Concentration (%V) 20.9
Nitrogen Concentration (%V) 79.1
Dry Gas Meter Factor 0.9840
Nozzle Diameter (in) 0.310
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.594
Standard Metered Volume (dscf) 142.485
Standard Metered Volume (dscm) 4.035
Stack Moisture (%V) 3.32
Mole Fraction Dry Stack Gas 0.967
Dry Molecular Weight 28.84
Wet Molecular Weight 28.48
Stack Gas Velocity (fpm) 1183.08
Stack Gas Velocity (mpm) 360.60
Volumetric Flow Rate (acfm) 7904.57
Volumetric Flow Rate (acmm) 223.86
Volumetric Flow Rate (dscfm) 7268.54
Volumetric Flow Rate (dscmm) 205.85
Dercent Isokinetic 104.12
Percent Excess Air N/A
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) p QQ
-------
Plant
Date
Sampling Location
Sample Type
Run Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intial Leak Check
US Intec
09/23/97
MSA - PM
Sampling
Traverse
Point
Location
B-1
1
1
1
2
2
2
2
3
3
3
3
4
4
4
4
5
5
5
5
6
6
6
6
A-6
6
6
6
5
5
5
5
4
4
4
4
3
3
3
3
2
2
2
2
1
1
1
1
Time
(min)
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
120
125
130
135
140
145
150
155
160
165
170
175
180
185
190
195
200
205
210
215
220
225
230
235
240
US Intec Probe Length & Type 4' glass
09/23/97 Nozzle ID (in) 0.31
T.O. Inlet Meter Box Number A-40
MSA - PM Meter Delta H@ 1 .791
3 Dry Gas Meter Factor (Yd) 0.984
MWH K Factor 10.13
75 rain Probe Heater Setting 108
29.89 Heater Box Setting
-7 Pitot Constant 0.84
0.001@10" Final Leak Check .002@10"
Dry Gas Orifice
Clock
Time
(24 hr)
1710
1715
1720
1725
1730
1735
1740
1745
1750
1755
1800
1805
1810
1815
1820
1825
1830
1835
1840
1845
1850
1855
1900
1905
1910
1940
1945
1950
1955
2000
2005
2010
2015
2020
2025
2030
2035
2040
2045
2050
2055
2100
2105
2110
2115
2120
2125
2130
2135
2140
Meter
Reading
Vm(fP)
327 687
330.6
333.6
337
340.4
342.8
346
348.3
351.2
352.6
353.8
355.3
357.1
359.7
363.4
365.9
369.2
373.7
376.4
380.3
384.2
388.2
392.2
395.7
400.234
400.259
404.3
408.3
412.2
416
419.3
423.3
427.1
431
434.6
437.7
441.1
445
446.5
448.9
450.7
453.1
455.5
458.3
462.3
464.9
468.2
470.8
473.9
477.437
Velocity
Head
(fP)
(in H2O)
0.11
0.11
0.11
0.11
0.1
0.09
0.09
0.09
0.02
0.02
0.02
0.02
0.11
0.11
0.11
0.11
0.16
0.18
0.17
0.18
0.2
0.2
0.19
0.19
0.2
0.19
0.19
0.18
0.18
0.17
0.18
0.18
0.14
0.14
0.14
0.14
0.05
0.05
0.05
0.05
0.1
0.1
0.1
0.11
0.11
0.12
0.12
0.12
Pressure
Diff
(P)
(in H20)
.11
.11
.11
.11
.01
0.91
0.91
0.91
0.2
0.2
0.2
0.2
1.11
1.11
1.11
1.11
1.62
1.82
1.72
1.82
2.02
2.02
1.92
1.92
2.02
1.92
1.92
1.82
1.82
1.72
1.82
1.82
1.42
1.42
1.42
1.42
0.51
0.51
0.51
0.51
1.01
1.01
1.01
1.11
1.11
1.21
1.21
1.21
Stack
Temp
Ts
-------
Eastern Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run 3
Page 1 of Z-
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
<;& ivicc.
<\ («/«!*-
WVfc$l-l
»rJX4.r T.O.
z b w\
•O 0"
IH.&q
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type :
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
-
/ofc
/'•Wr-
/oS
.00 1@0"
.OOiQp'
Meter Box Number
Meter delta H @
DGM FactorJY)
Nozzle Type & ID (in.) CrU&&
Ambient Temperature (°F) (Ifr/tO
Assumed Moisture (% H2O)
K-Factor
A-
-------
Plant
Date
Location
Sample Type
~T,0.
Run Number
Operator
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
24hr)
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps),
in.H20)
Stack
Ts
(CF)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp
(T)
Filter
Temp.
Adsorbent
Dry Gas Meter
Inlet
(Tm In)
Outlet
(Tm out)
Impinger
Exit
Temp.
CF)
Pump
Vacuum
(in.Hg)
20
2,0'L
Ml-
/oi
&Z.
it*
(.<**-
1-92.
U I
wife-O
3 S
&.
. f-frZ-
(•Sri.
HO
±
t/13-3
no
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I-SCL,
/oo
10
SS
00
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S
/.
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//
3-0
3
l.-vz
(0(9
±3:
lo S
IQl
Ul
o.SI
loV
no
o
201 £0
0-S'i
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Ho
J'O
no
6S
/•o
200
lo
ro?
III
/•o
10
o»
-QI
10*=?
roT
Tog
GZ.
0
2tO
if-'/o
£
VI
t -Qi
fZ.
2--0
462
o(
10
z.o
l. II
(•
fc
8Z
it
2,0
5
ULL
111
2,0
££0-
2.//30
10j
12.
82.
an
1.
H3
ilL
2.0
51
1.2-1
12.
JJJL
£±-
A3
.12.
1. 2.1
-UlL.
Comments:
-------
tERG
Eastern Researcn Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
PA.
q-v3-r?
iTi?RkfvL Dx/r\i^ef^ /A/L/ET
TA
3
At A
TT^
#9/1??- // £>
MuB
.MbS
tmpinger Weight : , ;;K^-
Final
(a)
t^.o
(,&%
504. b
^6,^
Initial
(g)
5%..l
5^-1
H%.^
200.1
Total Weight Gain (g)
Weight
Gain
(g)
f\$
IZ.L
^7
•^ • i
j^
^ ,^-
; A x -7
j -j • '
-------
Facility:
Date:
Location:
Run Number:
Samole Tvoe:
US Intec
09/22/97
T.O. Outlet
1
MSA
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)
240.0
30.18
30.18
0.00
400.54
962.11
151.686
1.14
88.29
151.60
1.9
19.0
79.1
0.9990
0.310
0.84
0.615
147.623
4.181
4!62
0.954
29.06
28.55
1920.73
585.44
12833.07
363.43
7573.84
214.49
103.52
N/A
0.00
0.00
0.00
0.00
-------
Plant
fnpling Location
nple Type
pun Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Jntial Leak Check
US Intec
09/22/97
MSA
Sampling
Traverse
Point
Location
B-1
2
3
4
5
6
7
8
9
10
11
12
A-1
2
3
4
5
6
7
8
9
10
11
12
Time
(min)
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
• 210
220
230
240
250
US Intec
09/22/97
T.O. Outlet
MSA
1
MKO
84
30.18
0
.007@15"
Dry Gas
Clock
Time
(24 hr)
14CA
l*rOW
1500
1510
1520
1530
1540
1550
1600
1610
1620
1630
1640
1650
1725
1735
1745
1755
1805
1815
1825
1835
1845
1855
1905
1915
1925
Meter
Reading
Vm(fP)
489 300
494.770
501.040
506.270
511.850
517.620
523.750
529.120
534.850
540.630
547.130
553.630
560.580
561.884
568.350
573.430
587.550
589.670
595.430
603.170
608.530
615.040
621.350
628.630
635.340
642.290
Velocity
Head
§P)
(in H20)
0.15
0.17
0.15
0.18
0.15
0.16
0.18
0.17
0.16
0.2
0.22
0.25
0.24
0.24
0.23
0.22
0.21
0.22
0.19
0.21
0.23
0.21
0.25
0.22
Probe Length & Type 4' glass
Nozzle ID (in) 0.31
Meter Box Number A-37
Meter Delta H@ 1.735
Dry Gas Meter Factor (Yd) 0.999
K Factor 5.68
Probe Heater Setting 1 60
Heater Box Setting
Pilot Constant 0.84
Final Leak Check .020@3"
Orifice
Pressure
Ditf
®H>
(in H20)
0.85
0.96
0.85
1.02
0.86
0.91
1.02
0.96
0.96
1.13
1.24
1.42
1.36
1.36
1.3
1.24
1.19
1.24
1.07
1.19
1.3
1.24
1.42
1.24
Stack
Temp
Ts
(F)
404
400
400
400
405
402
402
399
404
404
407
409
399
398
397
397
395
397
404
399
399
396
397
399
Dry Gas Meter
Temperature
Tm in Tm out
(F)
82
90
91
93
95
97
97
96
97
91
94
95
96
96
94
93
94
93
94
94
94
95
93
94
(F)
82
83
83
85
87
88
87
86
86
80
80
81
84
83
81
81
81
82
82
82
81
82
81
82
Impinger
Exit
Temp
(F)
63
62
59
60
53
52
54
56
56
59
61
61
46
47
55
57
58
61
62
61
62
63
57
58
Height of Lc
Moisture Cc
CO2 Percer
O2 Percent
N2 Percent
Particulate (
Stack Georr
Stack Diami
Stack Width
Pump
Vacuum
(in H2O)
1
1
1
1
1
1
1
1
1
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
0
151.6
1.9
19
79.1
35
-END
Average
Meter
Temp
(F)
A-1
2
3
4
5
6
7
8
9
10
11
12
0
A-1
2
3
4
5
6
7
8
9
10
11
12
82.0
86.5
87.0
89.0
91.0
92.5
92.0
91.0
91.5
85.5
87.0
88.0
90.0
89.5
87.5
87.0
87.5
87.5
88.0
88.0
87.5
88.5
87.0
88.0
END
88.29167
-------
Eastern Heieaixh Group. INC.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant
Date
Operator
Sampling Location ffdj
Sample Type
Run Number
Static Pressure (t) (in. H2O)
Barometric Pressure (in. H2O)
*/,£ fjyA £
?'*&-% 7
flfa
tA/KAA>/£>f
ffl
/
d-0&
16. fa
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check 0> <•
Final Leak Check 6sffi(>
(to£/R
ti*f
67 «!^"/$'
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in )
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
^'/7
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f $/£>
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£J/C?'Z^3 & /L s&^h Diagram of Duct
Schematic of Traverse "Point Layout
Read and record all data every /(? minutes
&}ffiAL
ft
Traverse
Point
Number
Sampling
Time
(min)
Clock
. Time
(24hr)
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(•F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desjrjed Actual
Probe
Temp.
(•F)
Filter
Temp.
Adnnrhanf
/ ncuui k/i^i 11
Jiap
Zeotp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
(•F)
Pump
Vacuum
(in.Hg)
, O
to
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£,/
/ n
m-
52
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page of
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),tt3)
Velocity
Head
({delta Ps),
in.H2O)
i
Stack
Ts
(°F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
(°F)
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
CF)
DryGa
Inlet
(Tm in)
s Meter
Outlet
(Tm out)
Impinger
Exit
Temp.
(T)
Pump
Vacuum
(in.Hg)
Comments:
-------
Eastern Research Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant,,, •„ :••.•:•:-,— :•-•;
Date . m . . •>. ••
Sampling Location
Sample Type t
Run Number ;
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number — >
XAD Number
;/4
QlnftQ
/> J&/ "Ttn^ ^>^^
^A
1
toft
T^E
\^^l * ^*i 1 cl* ^^ I
yl / J_ L
Impinger
Number
1
2
3
4
5
6
7
(mpinger
Solution
^f
&
£VT
^^
$-
701^
Total Weight Gain (g)
Weight
Gain
^l'(g)-- ;
^Ifc.r
fcaM
4 54; .2
?^/4,0
^1.^
-------
Facility: US Intec
Date: 09/23/97
Location: T.O. Outlet
Run Number: 2
Sample Type: MSA
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.92
Absolute Stack Pressure (in Hg) 29.92
Stack Static Pressure (in H2O) 0.00
Average Stack Temperature (°F) 401.88
Stack Area (sq in) 962.11
Actual Meter Volume (cu ft) 147.917
Average Meter Pressure (in H20) 1.07
Average Meter Temperature (°F) 85.54
Moisture Collected (g) 155.10
Carbon Dioxide Concentration (%V) 1.9
Oxygen Concentration (%V) 19.0
Nitrogen Concentration (%V) 79.1
Dry Gas Meter Factor 0.9830
Nozzle Diameter (in) 0.310
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.588
Standard Metered Volume (dscf) 141.111
Standard Metered Volume (dscm) 3.996
Stack Moisture (%V) 4!93
Mole Fraction Dry Stack Gas 0.951
Dry Molecular Weight 29.06
Wet Molecular Weight 28.52
Stack Gas Velocity (fpm) 1878.02
Stack Gas Velocity (mpm) 572.42
Volumetric Flow Rate (acfm) 12547.68
Volumetric Flow Rate (acmm) 355.35
Volumetric Flow Rate (dscfm) 7306.53
Volumetric Flow Rate (dscmm) 206.92
Percent Isokinetic 102.58
Percent Excess Air N/A
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0 00
-------
Plant
Date
Sampling Location
Sample Type
Run Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intial Leak Check
US Intec
09/23/97
MSA
Traverse
Point
Location
B-12
11
10
9
8
7
6
5
4
3
2
1
A-12
11
10
9
8
7
6
5
4
3
2
1
Sampling
Time
(min)
10
20
30
40
50
60
70
80
90
100
110
120
10
20
30
40
50
60
70
80
90
100
110
120
US Intec
09/23/97
T.O. Outlet
MSA
2
MKO
84
29.92
0
0.01 0@10"
Dry Gas
Clock
Time
(24 hr)
1015
1U IO
1025
1035
1045
1055
1105
1115
1125
1135
1145
1155
1205
1215
1240
1250
1300
1310
1320
1330
1340
1350
1400
1410
1420
1430
1440
Meter
Reading
Vmfft3}
644743
651.73
657.95
664.4
670.73
677.03
681.35
687.53
692.75
698.94
703.84
710.14
714.83
714.89
721.35
726.89
733.94
739.85
745.53
751.13
758.43
765.23
773.02
779.05
785.92
792.72
Velocity
Head
<|P)
(in H2O)
0.23
0.22
0.2
0.18
0.16
0.16
0.17
0.15
0.15
0.15
0.16
0.14
0.22
0.2
0.17
0.16
0.17
0.18
0.23
0.23
0.24
0.23
0.24
0.21
Probe Length & Type 4' glass
Nozzle ID (in) 0.31
Meter Box Number A-37
Meter Delta H@ 1.839
Dry Gas Meter Factor (Yd) 0.983
K Factor 5.68
Probe Heater Setting 125
Heater Box Setting
Pilot Constant 0.84
Final Leak Check 0.006@1 0"
Orifice
Pressure
Diff
<|H)
(in H2O)
1.3
1.13
1.13
1.02
0.9
0.9
0.96
0.85
0.85
0.85
0.9
0.78
1.24
1.13
0.96
0.9
0.96
1.02
1.3
1.3
1.38
1.3
1.38
1.19
Stack
Temp
Ts
(F)
409
412
410
417
411
406
404
397
399
381
389
385
396
402
408
405
404
403
401
403
403
400
399
401
Dry Gas Meter
Temperature
Tm in Tm out
(F)
86
93
94
94
95
96
95
94
95
87
88
89
85
86
88
89
90
91
92
92
92
93
93
93
(F)
79
82
83
82
82
83
83
82
83
78
78
79
77
77
77
78
78
78
78
79
79
80
80
81
Height of Lc
Moisture Cc
CO2 Percer
02 Percent
N2 Percent
Paniculate (
Stack Georr
Stack Diarrx
Stack Width
Impinger
Exit
Temp
(F)
58
61
61
48
48
50
48
49
50
50
50
50
50
49
52
51
52
52
51
52
53
54
53
56
Pump
Vacuum
(in H2O)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
155.1
1.9
19
79.1
35
END
Average
Meter
Temp
(F)
A-1
2
3
4
5
6
7
8
9
10
11
12
0
A-12
11
10
9
8
7
6
5
4
3
2
1
82.5
87.5
88.5
88.0
88.5
89.5
89.S
88.0
89.0
82.5
83.0
84.0
81.0
81.5
82.5
83.5
84.0
84.5
B5.S
85.5
85.5
86.5
86.5
B7.6
END
8554157
-------
Eastern Research Group, Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
J?
XAD Trap Number
Filter Heater Setting (°F) / to / £
Probe Length & Type
frobe Heater Setting ("F)
Minimum Sample Volume (ft3)
Meter Box Number
eter delta H i
PGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
7
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page of
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(°F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
CF)
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
CF)
Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)
Impinger
Exit
Temp.
CF)
Pump
Vacuum
(in.Hg)
Comments:
-------
Eastern Research Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses ;
Sample Identification
Filter Number
XAD Number
Pk
9-2.3-cl'?>
OUTLET TtfficLMfti ^oias
£~*f\
^ (ij
Q.
MA.
TCEL
^K KA,
09/19'V' ~im ^ ''
A//ft
Impinger
Number
1
2
3
4
5
6
7
Impinger
Solution
ti^O
H,0
MT
s.fc.
•
Amount of
Solution
(9)
lOOnd
loOwQ-
Impinger Tip
Configuration
/^S
bS
M(^3
.MuS
Impinger Weight
Final
(a)
GSO.H
ts(,.4
H^,g
u^.i
Initial
(3)
^92,?-
tN.S
4?5.r
^1.3
Total Weight Gain (g)
Weight
Gain
(9)
10!, "1
^<
, • \
***• . \
a 1.9
!
-------
Facility: US Intec
Date: 09/23/97
Location: T.O. Outlet
Run Number: 3
Sample Type: MSA
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.92
Absolute Stack Pressure (in Hg) 29.92
Stack Static Pressure (in H2O) 0.00
Average Stack Temperature (°F) 401.63
Stack Area (sq in) 962.11
Actual Meter Volume (cu ft) 144.935
Average Meter Pressure (in H2O) 1.05
Average Meter Temperature (°F) 83.73
Moisture Collected (g) 145.10
Carbon Dioxide Concentration (%V) 1.9
Oxygen Concentration (%V) 19.0
Nitrogen Concentration (%V) 79.1
Dry Gas Meter Factor 0.9830
Nozzle Diameter (in) 0.310
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.578
Standard Metered Volume (dscf) 138.740
Standard Metered Volume (dscm) 3.929
Stack Moisture (%V) 4.70
Mole Fraction Dry Stack Gas 0.953
Dry Molecular Weight 29.06
Wet Molecular Weight 28.54
Stack Gas Velocity (fpm) 1860.44
Stack Gas Velocity (mpm) 567.06
Volumetric Flow Rate (acfm) 12430.24
Volumetric Flow Rate (acmm) 352.02
Volumetric Flow Rate (dscfm) 7257.58
Volumetric Flow Rate (dscmm) 205.53
Percent Isokinetic 101.53
Percent Excess Air N/A
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0 00
-------
Plant
Date
Sampling Location
Sample Type
Run Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intial Leak Check
US Intec
09/23/97
MSA
Traverse
Point
Location
B-12
11
10
9
8
7
6
5
4
3
2
1
A-12
11
10
9
8
7
6
5
4
3
2
1
Sampling
Time
(min)
10
20
30
40
50
60
70
80
90
100
110
120
10
20
30
40
50
60
70
80
90
100
110
120
US Intec
09/23/97
T.O. Outlet
MSA
3
MKO
78
29.92
0
.006@9"
Dry Gas
Clock
Time
(24 hr)
1710
1720
1730
1740
1750
1800
1810
1820
1830
1840
1850
1900
1910
1940
1950
2000
2010
2020
2030
2040
2050
2100
2110
2120
2130
2140
Meter
Reading
Vm(fP)
792 839
800.49
805.62
812.42
818.27
824.55
829.48
835.45
841.23
846.35
851.77
857.49
863.25
863.28
869.66
875.86
881.35
887.2
893.03
899.04
905.45
911.9
918.63
925.43
932.26
937.804
Probe Length & Type 4' glass
Nozzle ID (in) 0.31
Meter Box Number A-37
Meter Delta H@ 1.839
Dry Gas Meter Factor (Yd) 0.983
K Factor 5.68
Probe Heater Setting 125
Heater Box Setting
Pitot Constant 0.84
Final Leak Check 0.007@7"
Orifice
Velocity
Head
0?)
(in H20)
0.23
0.2
0.21
0.17
0.16
0.16
0.18
0.15
0.16
0.15
0.15
0.16
0.2
0.2
0.17
0.17
0.16
0.18
0.21
0.21
0.23
0.23
0.21
0.21
Pressure
Diff
iH)
(in H20)
1.3
1.13
1.19
0.96
0.9
0.9
1.02
0.85
0.9
0.85
0.85
0.9
1.13
1.13
0.96
0.96
0.9
1.02
1.19
1.19
1.3
1.3
1.18
1.19
Stack
Temp
Ts
(F)
405
408
407
406
401
402
399
399
399
397
398
395
408
406
406
404
402
399
398
399
399
400
401
401
Dry Gas Meter
Temperature
Tm in Tm out
(F)
78
90
92
92
91
92
92
91
92
92
92
93
80
88
89
89
88
88
89
90
91
91
91
92
(F)
77
79
79
79
79
79
79
76
79
79
79
80
78
77
72
77
77
77
77
77
77
77
78
78
Height of Lc
Moisture Cc
CO2 Percer
O2 Percent
N2 Percent
Paniculate (
Stack Geon
Stack Diarrn
Stack Width
Impinger
Exit
Temp
(F)
54
57
60
64
60
60
57
57
58
58
58
60
567
55
58
60
61
60
60
60
60
60
61
62
Pump
Vacuum
(in H2O)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
145.1
1.9
19
79.1
35
END
END
Average
Meter
Temp
(F)
A-1
2
3
4
5
6
7
8
9
10
11
12
0
A-12
11
10
9
8
7
6
5
4
3
2
1
77.5
84.5
85.5
85.5
85.0
85.5
85.5
83.5
85.5
85.5
85.5
86.5
79.0
82.5
80.5
83.0
82.5
82.5
83.0
83.5
84.0
84.0
84.5
85.0
83.72917
-------
Eastern Research Croup, Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant
Date
Operator
Sampling Location QCrffc
Sample Type
Run Number
Static Pressure (±) (in. H20)
Barometric Pressure (in. H2O)
(//t^iJfs-ffC.
'%•-'£?*'}'?
Mt0 .
&t>$J!*^
4°-/7
•J
£ • 0 &
£-f xf-Z— '
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check 0 ^fa
Final Leak Check /) , Q£
/to "£"
ty' ' e/q-Vf
/ e,$"^
>(,*? /^7*f& Diagram of Duct
Schematic of Traverse Point Layout
C.O£, "/ '
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page of
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),f»3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(°F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
(°F)
Filter
Temp.
(°F)
Adsorbent
Trap
Temp.
(°F)
DryGa
Inlet
(Tm in)
s Meter
Outlet
(Tm out)
•
Impinger
Exit
Temp.
CF)
Pump
Vacuum
(in.Hg)
Comments:
-------
Eastern Research Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impihger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
3A-
9-33-^
TTtefcKKu COUfti^E^: Ch"a£T
U.H
Initial
(9)
A6.(o
0315
fSfc.1^
^?.s
Total Weight Gain (g)
Weight
Gain
^:i::i:(g> - =
^./
^-<
^ 6
^-^
1^,'
-------
Facility:
Date:
Location:
Run Number:
Samole Tvoe:
US Intec
09/23/97
APR Stack
1
MSA
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)
60.0
29.92
29.92
0.01
99.33
706.86
45.916
1.83
87.46
31.40
1.9
19.0
79.1
0.9840
0.246
0.84
0.730
43.772
1.240
3.27
0.967
29.06
28.70
2427.53
739.91
11916.12
337.46
10880.48
308.14
99.72
N/A
0.00
0.00
0.00
0.00
-------
Plant
Date
Sampling Location
Sample Type
Run Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intel Leak Check
USIntec
09/23/97
MSA
Traverse
Point
Location
Y-1
2
3
4
5
6
X-1
2
3
4
5
6
Sampling
Time
(min)
0
5
10
15
20
25
30
30
35
40
45
50
55
60
US Intec |
ogtfsrar
APP Stack
MSA
1
Jackson
80
29.92
0.01
.008@15"
Dry Gas
Clock
Time
(24 hr)
1325
1330
1335
1340
1345
1350
1355
1401
1406
1411
1416
1421
1426
1431
Meter
Reading
Vm(fP)
477623
480.6
484.6
488.7
491.9
495.4
498.853
498.895
502.8
506.8
510.7
515.1
519.8
523.581
I" Probe Length & Type 41 glass
Nozzle ID (in) 0.246
Meter Box Number A-40
Meter Delta H@ 1.791
Dry Gas Meter Factor (Yd) 0.984
K Factor 3.71
Probe Heater Setting 1 08
Heater Box Setting
Pitot Constant 0.84
Final Leak Check .005@1 5"
Orifice
Velocity
Head
<£P)
(in H2O)
0.34
0.48
0.57
0.34
0.39
0.41
0.47
0.52
0.56
0.65
0.67
0.52
Pressure
Diff
UN
(in H20)
1.26
1.78
2.12
1.26
1.44
1.52
1.75
1.93
2.08
2.41
2.49
1.93
Stack
Temp
Ts
(F)
97
97
98
102
100
100
96
98
99
100
102
103
Dry Gas Meter
Temperature
Tm in Tm out
(F)
89
94
95
96
95
95
89
94
95
95
95
95
(F)
80
80
80
81
81
81
81
81
81
82
82
82
Height of Lc
Moisture Co
C02 Pereer
O2 Percent
N2 Percent
Paniculate (
Stack Georr
Stack Diami
Stack Width
Impinger
Exit
Temp
(F)
66
62
60
62
62
60
59
58
59
61
63
65
Pump
Vacuum
(in H20)
1
1
1
1
1
1
1
1
1
1.5
1.5
1
1.9
T9
79.1
30
Y-1
2
3
4
5
6
X-1
2
3
4
5
6
Average
Meter
Temp
84.5
87.Q
87.5
83.5
88.0
68.0
85.0
87.5
88.0
88.5
88.5
88.5
END
END
87.45*33
-------
Eastern Research Croup. Inc.
METHOD 5 DATA SHEET
0
Run —
Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
U.£.;jyW.«
f>/1-*t /9T
"SaeV&o.^
/VfP&WJK
1* S" A
I
•v- .01
"l.«3.9j_
sXAD Trap Number
Filter Heater SettingJT)
Probe Length & Type CV»o«-*» /)
Probe Heater Setting (°F)
Minimum Sample Volumejft3)
Initial Leak Check <2. vT '• VW.
Final Leak Check C \.") Diagram or Duct
Schematic of Traverse Point Layout
Read and record all data every.
Traverse
Point
Number
Y- 1
i
1
<5
^
9
Q
Sampling
Time
(min)
o
C
10
IS
^0
tr
10
*>o'
tt
4o
^C
5«
CS
60
Clock
'Time
(24hr)
\ Z-L*Z
tl -v-
VS3F
I 3-Vo
^*»5'
tico
v?rr
IAO)
lAOt
. t-^\\
\4-\fc
' \*"L\
'. 14 at
', »^1l
Gas
Meter
Reading
((Vm).tt3)
-V7.U-3
^9o.«
^«A.6
•^88. 1
^«5V .9
^fS-4-
4?e.65^
^9a.B«9«i
5o-v.«a
S0fc,fc
5(0. -7
«;ic.i
^\«».fi
513.!Tft|
Velocity
Head
((delta Ps),
in.H2O)
,2.4-
.^4
- ^7
-M
,•*«»
.-41
.4-7
-1
<5"7
98
v 07.
voo
loo
9t
*>«
9c,
\ r»o
\o'2-
»o'i
Orifice F
Differ
(delta H,
Desired
I.V6
l.-»«
i.ll
1.1.6
l.^
V.«i
l.-JS'
l.9'l
•2-.O<2,
•2.^»
l. -4*
V.93
'ressure
ential
in.H2O)
Actual
\.-uC,
\.-»8
i. \i-
V.2.G
l-»4-
V-S2-
I. "IS
V.^-3
-L.09
t.^«
^.-v9
\ .^3
Probe
Temp.
CF)
to3
104
io-5
IO2-
105
I 0-7
I 0^
10*7
\o'i
L O1
Vo6
\0fi
Filter
Temp.
CF)
^^
VOI
lo^
V V2>
\\6
1 tfl
VU
\ 1-7
V\¥S
\ 1S
Uft
V\9
W
Temp.
CF)
95
9C
'SS
•94.
^^
9tf
98
V OO
\0>
vo \
HS'2.
103
DryGa
Inlet
(Tm in)
«?
94-
*55
96
«y<..
>^
^^
^4-
95
95
99
vs
s Meter
Outlet
(Tm out)
«(7
©0
feo
Q\
ei
«1
&v
9»
8\
ftl
^l
©^
Impinger
Exit
Temp.
CF)
tc
(••2.
to
fol-
6 Z
SO
^
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page of
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(•F)
Orifice Pressure
Differential
(delta H, in,H2O)
Desired Actual
Probe
Temp.
(°F)
Fitter
Temp.
(°F)
Adsorbent
Trap
Temp.
(•F)
Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)
Impinger
Exit
Temp.
CF)
Pump
Vacuum
(in.Hg)
Comments:
-------
tERG
Eastern Research Group, Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant I- 1 Pftf
Date ., ^-A^/-^
Sampling Location C^Pfi^. ft <^ \/
Impinger Weight
Rnal
(g)
S'iM.O
5%.X
4^n
7^,1
Initial
(9)
5E1.(c
5sa.H
tftS.S
KsS
Total Weight Gain (g)
Weight
Gatn
(g)
9.f
^-2
3.1
11.4
3LH
-------
Facility: US Intec
Date: 09/24/97
Location: APR Stack
Run Number: 2
Samole Tvoe: MSA
Total Sampling Time (min) 60.0
Corrected Barometric Pressure (in Hg) 29.83
Absolute Stack Pressure (in Hg) .29.83
Stack Static Pressure (in H2O) 0.01
Average Stack Temperature (°F) 100.67
Stack Area (sq in) 706.86
Actual Meter Volume (cu ft) 46.831
Average Meter Pressure (in H2O) 1.91
Average Meter Temperature (°F) 88.75
Moisture Collected (g) 32.80
Carbon Dioxide Concentration (%V) 1.9
Oxygen Concentration (%V) 19.0
Nitrogen Concentration (%V) 79.1
Dry Gas Meter Factor 0.9840
Nozzle Diameter (in) 0.246
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.740
Standard Metered Volume (dscf) 44.409
Standard Metered Volume (dscm) 1.258
Stack Moisture (%V) 3^37
Mole Fraction Dry Stack Gas 0.966
Dry Molecular Weight 29.06
Wet Molecular Weight 28.69
Stack Gas Velocity (fpm) 2485.69
Stack Gas Velocity (mpm) 757.64
Volumetric Flow Rate (acfm) 12201.62
Volumetric Flow Rate (acmm) 345.55
Volumetric Flow Rate (dscfm) 11070.51
Volumetric Flow Rate (dscmm) 313.52
Percent Isokinetic 99.43
Percent Excess Air N/A
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Plant
Date
Sampling Location
Sample Type
Run Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intel Leak Check
US Intec
09/24/97
MSA
Traverse
Point
Location _
X-1
2
3
4
5
6
Y-1
2
3
4
5
6
Sampling
Time
(min)
o
5
10
15
20
25
30
30
35
40
45
50
55
60
US Intec
09/24/97
APP Stack
MSA
2
Jackson
80
29.83
0.01
.012@15"
Dry Gas
Clock
Time
(24 hr)
1*510
19 IU
1515
1520
1525
1530
1535
1540
1550
1555
1600
1605
1610
1615
1620
Meter
Reading
Vm(fP)
59388
9£«J.OO "
527.7
531.7
535.7
540.1
544.5
548.893
549.04
553.1
556.7
561
564.2
567.6
570.858
Velocity
Head
tfP)
(in H20)
0.49
0.54
0.58
0.61
0.65
0.63
0.49
0.55
0.57
0.35
0.39
0.32
Probe Length & Type 4' glass
Nozzle ID On) 0.246
Meter Box Number A-40
Meter Delta H@ 1.791
Dry Gas Meter Factor (Yd) 0.984
K Factor 3.71
Probe Heater Setting 1 08
Heater Box Setting
Pilot Constant 0.84
Final Leak Check .014@15"
Orifice
Pressure
Diff
dH)
(in H2O)
1.82
2.01
2.15
2.27
2.41
2.34
1.82
2.04
2.12
1.3
1.45
1.19
Stack
Temp
Ts
(F)
99
99
102
101
102
103
99
98
99
103
102
101
Dry Gas Meter
Temperature
Tm in Tm out
(F) C
91
96
97
98
100
99
92
96
95
93
94
S4
F)
80
81
81
82
83
84
83
83
83
82
82
81
Height of Lo
Moisture Co
CO2 Percen
O2 Percent
N2 Percent
Particulate C
Stack Geom
Stack Diame
Stack Width
Impinger
Exit
Temp
(F)
66
58
60
62
65
60
62
57
58
59
60
60
Pump
Vacuum
On H2O)
1.5
1.5
2
2
2
2
1.5
1.5
2
1
1
1
0
32.8
1.9
19
79.1
30
X-1
2
3
4
5
6
Y-1
2
3
4
5
6
Average
Meter
Temp
(F)
85.5
88.5
89.0
90.0
91.5
91.5
87.5
89.5
89.0
87.5
88.0
87.5
END
END
88.75
-------
Eastern Reseirch Group. Inc.
.MODIFIED METHOD S^ATA SHEET
Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
iA - fc. tT^V«.e
9 / "L •* /9T
"3*CX«,V:*1>H
Af pJ-ta*VL.
f*\ 5* A
-1
••*• . 01
'•>•?. X 3
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type ( v>0 **}
Probe Heater Setting ("F)
Minimum Sample Volume (ft3)
Initial Leak Check <& v «•'• VL&
Final Leak Check fi. i^" *• VV«»
(J,|iv
\ofl
^'
vog
o.o 10.
o.o i^V
Meter Box Number
Meter delta H@
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
k-^o
1.19*
o.^tJ-4
o.z.^6
Bo
"^
S .'^ i
•^
i
o
jL
, 5 *• <»•*»
rlnl)
"* } I SK oj.) Diagram of Duel
Schematic of Traverse Point Layout
Read and record all data every Si> minute*
Traverse
Point
Number
Y_ - i
I
*
•+•
G£
e
V - t
/
•/
i
• *
Z
(,
Sampling
Time
(min)
O
£
\ 0
v S
"2.0
'L<1
lo
1,0
H
<*a
-»C
rt.'
??>
C^)'
* Clock
$ft
VS»«5»«*
\y«s-
»5iO
V$"VR
\C 30
vr^r
\ J"4o
'• '£^-?
X 1^5*0
> »svr
xi(.oo
„ v-(*««;
0 vfe \ o
X ibiy
HrWK
Gas
Meter
Reading
((Vm).tt3)
S13.B«o
^Z-».1
Sli -i
5^e-7
5^0. V
C«5
\0^
\,01_
lo-L
102.
103
DryGa
Inlet
(Tm In)
^\
9£
•^7
^^
V Oo
9-=?
91.
0)6
9 <:
93
y-t
^4
s Meter
Outlet
(Tm out)
go
e\
at
0Z_
83
a^
8 '3
s^
«3T
fi2-
D^L.
^ I
Impinger
Exit
Temp.
(°F)
Gi
Cfl
6£>
(, -^
6S
&A
«"X
^'7
«;«
^9
CO
Go
Pump
Vacuum
(in.Hg)
V.T
\.c:
^.
•2.
7.
Z
1.5
v.?i
7.
\
1
\
Comments:
-------
Page of_
Plant
Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(°F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
(°F)
Filter
Temp.
(°F)
Adsorbent
Trap
Temp.
(8F)
Dry Gas Meter
Inlet Outlet
(Tm In) (Tm out)
Impinger
Exit
Temp.
(°F)
Pump
Vacuum
(in.Hg)
Comments:
-------
fcERG
Eastern Research Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
P.r\
I-HH-^
Ai^P V/£MT &O-LCT
^A
2L
N.f\
~rr 1-
09)5X99-35" V'1
Impinger
Number
1
2
3
4
5
6
7
Impinger
Solution
M
M
kT
S.G,
-*
Amount of
Solution
(g)
IMnt
w*&
Impinger Tip
Configuration
^ifp>
^fi>
k(,b
M^&
.
tmpinger Weight
Final
(g)
51S,&
GcSS
H^I.Q
ms
Initial
(a)
585", i
Coa.o
*f^8.^
m.5"
Total Weight Gain (g)
Weight
Gain
(g)
1* .1
(s *
O^. C7
/o J
— 9
_^ > • •-
-------
Facility: US Intec
Date: 09/24/97
Location: APR Stack
Run Number: 3
Sample Type: MSA
Total Sampling Time (min) 60.0
Corrected Barometric Pressure (in Hg) 29.83
Absolute Stack Pressure (in Hg) .29.83
Stack Static Pressure (in H2O) 0.01
Average Stack Temperature (°F) 95.50
Stack Area (sq in) 706.86
Actual Meter Volume (cu ft) 46.969
Average Meter Pressure (in H20) 1.91
Average Meter Temperature (°F) 86.13
Moisture Collected (g) 28.00
Carbon Dioxide Concentration (%V) 1.9
Oxygen Concentration (%V) 19.0
Nitrogen Concentration (%V) 79.1
Dry Gas Meter Factor 0.9840
Nozzle Diameter (in) 0.246
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.746
Standard Metered Volume (dscf) 44.754
Standard Metered Volume (dscm) 1.267
Stack Moisture (%V) 2^87
Mole Fraction Dry Stack Gas 0.971
Dry Molecular Weight 29.06
Wet Molecular Weight 28.75
Stack Gas Velocity (fpm) 2478.44
Stack Gas Velocity (mpm) 755.43
Volumetric Flow Rate (acfm) 12165.99
Volumetric Flow Rate (acmm) 344.54
Volumetric Flow Rate (dscfm) 11198.54
Volumetric Flow Rate (dscmm) 317.14
Dercent Isokinetic 99.06
Percent Excess Air N/A
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
_flant
Date
Sampling Location
fsampleType
iRun Number
^Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intial Leak Check
US Intec
09/24/97
MSA
Traverse
Point
Location
Y-1
2
3
4
5
6
X-1
2
3
4
5
6
Sampling
Time
(min)
0
5
10
15
20
25
30
30
35
40
45
50
55
60
US Intec
09/24/97
APP Stack
MSA
3
Jackson
78
29.83
0.01
.011@15"
Dry Gas
Clock
Time
(24 hr)
1632
1637
1642
1647
1652
1657
1702
1705
1710
1715
1720
1725
1730
1735
Meter
Reading
Vm(fP)
571 133
574.6
578.9
582.7
586.3
590.2
593.707
593.81
597.1
601
605.3
609.3
613.6
618.205
Probe Length & Type 4' glass
Nozzle ID (in) 0.246
Meter Box Number A-40
Meter Delta H@ 1.791
Dry Gas Meter Factor (Yd) 0.984
K Factor 3.71
Probe Heater Setting 1 08
Heater Box Setting
Prtot Constant 0.84
Final Leak Check .005@15"
Orifice
Velocity
Head
IP)
(in H20)
0.42
0.53
0.58
0.42
0.46
0.44
0.37
0.51
0.57
0.64
0.66
0.58
Pressure
Diff
(|H)
(in H20)
1.56
1.97
2.15
1.56
1.71
1.63
1.37
1.89
2.12
2.38
2.45
2.15
Stack
Temp
Ts
(F)
93
93
94
99
99
98
93
94
95
95
99
94
Dry Gas Meter
Temperature
Tm in Tm out
(F)
89
92
92
91
90
91
90
92
94
94
95
93
(F)
79
80
80
80
80
80
80
80
81
81
81
82
Height of Lo
Moisture Co
CO2 Percen
O2 Percent
N2 Percent
Particulate C
Stack Geom
Stack Diame
Stack Width
Impinger
Exit
Temp
(F)
58
56
58
61
62
62
65
64
64
64
65
65
Pump
Vacuum
(in H2O)
1
1
105
1
1
1
1
1
1
1.5
1.5
1.5
0
28
1.9
19
79.1
30
Y-1
2
3
4
5
6
X-1
2
3
4
5
6
Average
Meter
Temp
(F)
84.0
86.0
86.0
85.5
85.0
85.5
85.0
86.0
87.5
87.5
88.0
87.5
END
END
86.125
-------
Eaitem Research Group, Inc.
A
MODIFIED METHOD 5 DATA SHEET
Run ^
Page 1 of \
i
Rant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (t) (in. H2O)
Barometric Pressure (in. H2O)
U.S. ^u-Vec
**/ /«r?
Ay*f SV^
vM CA
•a,
•V O. o \
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type C. V>«x-cO
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check © \S*» vU
Final Leak Check <» 1 S"" Ufi.
AJ .A,.
v oft
-*'
loft
0.011
0 .DOS
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A-^b
1 .T»}
G.<>&\
O.Z^t
•78
3
3^1
-5
7
A
I^'-^Z^V)
y 1 ' ~
^Joy t-ift
i
d (cc\ ov.) Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data everv > minute* r*
Traverse
Point
Number
Y- I
1
3
•V
i-
G
% " '
1.
1,
4
s
G
Sampling
Time
(min)
O
<^
vo
\c
2.0
-2.5
^0
'iO
35"
^Q
<*S
So
5 f
GO
Clock
Time
(24hr)^
I *>VL
\fc^'7
IjU^i.
tt4T
1651
Vb5T'7
Mo^
^Toe
n 10
v-i ir
n o-o
n tr
I7?o
v-ii$*
uas
Meter
Reading
((Vm).ft3)
T-^4. ^"^'4
«??-% &
<;-)«'.«?
S-81,7
«r«6.?
S9 o . L
^9 ^. -7 0-7
•^
s^'J.svo
3*? "7 \
6o\.o
£,o^.^
Co*?. 3
6 U.8
616. 2-05
veiocny
Head
((delta Ps).
in.H2O)
,4^.
.0
.Sfi
.-11.
.-«
^"*
.'il
.C|
.5T
.C4
.£4
,5-fl
Stack
Ts
CF)
9-J
9^^
9"V
qg
•^^
9«
^5^
9^
95'
«r5'
•99
^4
urmce h
Differ
(delta H,
Desired
»,S6
\ .9-7
•2..15-
i.SL
v.n j
i.e.?
\.1~l
v.e^
T-.IV
2.-2S
t.-^r
2..\T
•ressure
ential
in.H2O)
Actual
i.^^:
i.S-7
i.\5
use
l.T i
H.3
in
U89
T..\7_
•r.^e
•LAS'
l,N9
Probe
Temp.
(T)
95
97
Tie
?e
voo
u>t
103
ioi
loc;
tot,
te^
164
Filter
Temp.
CF)
lo-t
t OC
V.OT
(oe
L0^3
Ll 0
\\1-
Ii1_
U*
vv-v
V\6
^7
^USUIITchl
•trap
Temp.
CF)
^5
98
95
95"
96
9C
95"
9tf
«51
=37
98
^9
uryua
Inlet
(Tm In)
99
9X
7"C
9!
^0
9 »
?0
91
•7-V
9^
?5
^ ^
s Meier
Outlet
(Tm out)
79
80
<3o
90
«0
60
to
O
ei
8)
et
&^
impinger
Exit
Temp.
CF)
se
^
s«,
6<
V.Z,
fa'Z.
£5
64
64
t*\
6S^
65T
Pump
Vacuum
(in.Hg)
^
f
1.5
1
\
\
1
I
1
\-5
1.5
hV
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page.
of
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(°F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
(°F)
Filter
Temp.
(°F)
.
Adsorbent
Trap
Temp.
CF)
DryGa
Inlet
(Tm in)
s Meter
Outlet
(Tm out)
.
Impinger
Exit
Temp.
(°F)
;'
Pump
Vacuum
(in.Hg)
Comments:
-------
Eastern Research Group, inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
A.Y.
cy-S-H -*?'•?*
ApP> \ffcrtT 60Tl£T
.4TA"
^
M. Pv.
/^^ ( ^9 V ^ / ^ *f //r
Impinger
Number '
1
2
3
4
5
6
7
Impinger
Solution
H^O
1^0
k.x
^(v.
-*
Amount of
Solution
(g)
/OO&
)££>&
Impinger Tip
Configuration
M&6
6(i
Ml^ft
Mbfc
Impinger Weight
Final
(g)
m.5
sn.it
^D.3,
7W.2
Initial
(g)
521, lo
5?3.5~
H^.l
76f.2
Total Weight Gain (g)
Weight
Gain
(g)
s? °-,
£ \
•>-/
I.G
H 0
P?.o
-------
Facility:
Date:
Location:
Run Number:
Sample Type:
US Intec
09/24/97
SBS Stack
1
MSA
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)
60.0
29.92
29.92
0.01
101.58
706.86
46.275
1.71
87.46
28.20
1.9
19.0
79.1
0.9960
0.246
0.84
0.744
44.641
1.264
2.89
0.971
29.06
28.74
2413.14
735.52
11845.47
335.46
10814.86
306.28
102.31
N/A
0.00
0.00
0.00
0.00
-------
Plant
Date
Sampling Location
Sample Type
Run Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intel Leak Check
US Intec
09/24/97
MSA
Traverse
Point
Location
X-1
2
3
4
5
6
Y-1
2
3
4
5
6
Sampling
Time
(min)
o
5
10
15
20
25
30
30
35
40
45
50
55
60
US Intec
09/24/97
SBS Stack
MSA
1
Jackson
85
29.92
0.01
.010@15"
Dry Gas
Clock
Time
(24 hr)
1435
1440
1445
1450
1455
1500
1505
1508
1513
1518
1523
1528
1533
1538
Meter
Reading
Vm(fP)
349 998
353.6
357.5
361.7
365.8
370.2
374.388
374.455
378.1
382
386.1
389.2
392.9
396.34
Probe Length & Type 4' glass
Nozzle ID (in) 0.246
Meter Box Number A-39
Meter Delta H@ 1.7
Dry Gas Meter Factor (Yd) 0.996
K Factor 3.53
Probe Heater Setting 108
Heater Box Setting
Pitot Constant 0.84
Final Leak Check 0.01 6@1 5"
Orifice
Velocity
Head
£*)
(in H2O)
0.48
0.5
0.55
0.57
0.6
0.57
0.4
0.47
0.56
0.29
0.42
0.41
Pressure
Diff
<*H)
(in H20)
1.69
1.76
1.94
2.01
2.11
2.01
1.41
1.66
1.97
1.02
1.48
1.45
Stack
Temp
Ts
(F)
99
100
102
102
103
102
103
102
103
102
100
101
Dry Gas Meter
Temperature
Tm in Tm out
(F)
83
93
93
91
91
91
91
92
93
93
92
92
(F)
83
82
83
84
84
84
84
84
84
84
84
84
Impinger
Exit
Temp
(F)
63
51
52
54
54
56
59
59
59
60
62
62
Height of Lc
Moisture Co
CO2 Percer
02 Percent
N2 Percent
Particulate (
Stack Georr
Stack Diami
Stack Width
Pump
Vacuum
(in H2O)
2
2
2
3
3
3
2
2
3
1
2
2
0
28.2
1.9
19
79.1
30
X-1
2
3
4
5
6
Y-1
2
3
4
5
6
Average
Meter
Temp
(F)
83.0
87.5
88.0
87.5
87.5
87.5
87.5
88.0
88.5
88.5
88.0
88.0
END
END
87.45833
-------
Eattem Research Croup. Inc.
MODIFIED METHOD 5ADATA SHEET
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O) •'
U f <5>ct'e.t
9 / L.-f /*» 7
5*~«.VCroi»i
SBSJWk;
^\ 5" A
1
•l-o.o |
•Z.9551
Traverse
Point
Number
X - 1
I
•^
4
*
4
Y- 1
t.
1
<
5-
£
Sampling
Time
(min)
O
q
I O
19
2.0
1 r
3.0
•jt^
40
t£
0
S»F
cc
1
* Clock
VUg
\-\ ^ro
1 -*\ ^S"
1 <1 yo
1 ^ 5*5-
I9i9c.
^ So*
% V8J?
t si i
' I STlft
lS">-J
^ S'^-g
% CVi
l$'^«
Gas
Meter
Reading
«Vm),ft3)
^L ^^ ^^ Q^3 G.
»),t>V (a
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A. -5*5
V..TOO
to .^^C,
o.i-^-C
^S
•^
?. 5"5
fell
& C**<-V w ,_) Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every 5 minutes ** x V'Vftr 1t^ \^C
Velocity
Head
((delta Ps),
in.H20)
. ^S
>GO
.5?"
-5 '7
«j6o
.5' -7
• ^\ 0
.^1
, 5£
tq
--V2.
'^ t
Stack
Ts
CF)
^ 9
I O O
I 01.
1 07.
V 0 "J>
\ 00.
I o-\
1 OT.
(01
(02.
i OO
\ o |
Orifice F
Differ
(delta H
Desired
i -6^
i. "i(>
\ .9-^-
Z.OI
1. V\
Z.. 01
1.4 «
l.CC
1 .9"?
I. OX
1 .'^'8
\. ^5'
3ressure
ential
in.H20)
Actual
i .€^9
1.-7C
\.9-V
7..0I
t. t i
^ -0 \
\ ••** 1
V .4 6
1.-TT1
Uo7-
V-*\8
\.*V?
Probe
Temp.
CF)
US
\\ 9
\V ft
\ \ A-
V JC>
\ V t,
\ 1 3
V I ft
\ l A
\ \9
\ * 5"
V \ .T
Filter
Temp.
CF)
V \*r
\\q
\ i "7
\ \ C,
1 1 "7
\ \ -j
11 #*|
TB?
I Vfl.
v \9
\ \<9
V. V1^
V 4 fe
•^fasorbefit
Temp.
CF)
v 0-7
\\ t
\\'l
\\ "*
I Vft
V V ^
I O
V V°J
\\ft
\\6
\ \ %
V \ S
DryGa
Inlet
(Tm In)
8'i
9i
92
51
•=5 i
•=> i
9 /
9'2-
«?3
*? 3
9'i-
9 i_
s Meter
Outlet
(Tm out)
83
fc'c
XV --j
13 ^
04
Q*r
•% «^
g,^
^1 /\.
Q^
^A
8^
*8 ^
Impinger
Exit
Temp.
CF)
6"*
£ t
c;-^
S^f
5*4-
*»%
*>•?
^<^
S9
Co
1. 1
G t~
Pump
Vacuum
(in.Hg)
1^
•^
-z.
•5
•^
•^
1_
•1^
•^
\
T_
^_
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page of
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
x
Gas
Meter
Reading
«Vm}.ft3}
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(•F)
Orifice Pressure
Differential
(delta H, in H2O)
Desired Actual
Probe
Temp.
(°F)
Filter
Temp.
(°F)
Adsorbent
Trap
Temp.
(°F>
Dry Gas Meter
Inlet Outlet
{Tm in) (Tm out)
Impinger
Exit
Temp.
(°F)
Pump
Vacuum
(in.Hg)
Comments:
-------
Eastern Research Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant ,
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
P. Pi
^-34-9^
•5(V^ vrtrtT O/J7L£~
£f\
1_
M.tt,
Tf.-e
o'm^-lS *f"
Impinger
Number
1
2
3
4
5
6
7
Impinger
Solution
Ht.0
I^O
Ml
5.t,
•
Amount of
Solution
(g)
IO£>*(L
I00t£i
Impinger Tip
Configuration
M^6
(?£
Mi.? ft
MbO
Impinger Weight
Final
(g)
(sisa
(36,0
H?^
xti
Initial
(g>
(cd3>
^r
G»0b.^
^fc.^
gffi-j
M,4"
Total Weight Gain (g)
Weight
Gain
(g) *.
/£-^
2,1
i.s
W
^,y
3\ " '
-------
Facility:
Date:
Location:
Run Number:
Sample Type:
US Intec
09/25/97
SBS Stack
2
MSA
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H20)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)
60.0
29.86
.29.86
0.01
93.08
706.86
50.677
1.91
77.75
21.70
1.9
19.0
79.1
0.9960
0.246
0.84
0.828
49.682
1.407
2.02
0.980
29.06
28.84
2534.15
772.41
12439.47
352.29
11612.33
328.86
106.05
N/A
0.00
0.00
0.00
0.00
-------
Plant
Date
Sampling Location
Sample Type
Run Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intial Leak Check
US Intec
09/25/97
MSA
Traverse
Point
Location
Y-1
2
3
4
5
6
X-1
2
3
4
5
6
Sampling
Time
(min)
o
5
10
15
20
25
30
30
35
40
45
50
55
60
US Intec
09/25/97
SBS Stack
MSA
2
Jackson
68
29.86
0.01
.006@15"
Dry Gas
Clock
Time
(24 hr)
922
927
932
937
942
947
952
956
1001
1006
1011
1016
1021
1026
Meter
Reading
Vm(fP)
396737
400.5
404.4
408.4
412.4
415.8
419.876
420.016
424.4
428.7
433.5
438.1
442.8
447.554
Probe Length & Type 4' glass
Nozzle ID (in) 0.246
Meter Box Number A-39
Meter Delta H@ 1.7
Dry Gas Meter Factor (Yd) 0.996
K Factor 3.53
Probe Heater Setting 1 08
Heater Box Setting
Pilot Constant 0.84
Final Leak Check ,006@1 5"
Orifice
Velocity
Head
fP)
(in H2O)
0.45
0.5
0.52
0.4
0.47
0.56
0.52
0.58
0.59
0.6
0.65
0.66
Pressure
Diff
&)
(in H20)
1.59
1.76
1.83
1.41
1.66
1.97
1.83
2.04
2.08
2.12
2.29
2.33
Stack
Temp
Ts
(F)
94
95
94
95
91
91
91
92
92
93
95
94
Dry Gas Meter
Temperature
Tm in Tm out
(F)
76
82
83
82
81
82
83
84
85
85
85
85
(F)
71
71
72
72
72
73
73
73
74
74
74
74
Height of Lc
Moisture Cc
CO2 Percer
O2 Percent
N2 Percent
Paniculate (
Stack Georr
Stack Diarrx
Stack Width
Impinger
Exit
Temp
(F)
52
49
51
52
55
56
55
56
58
60
61
61
Pump
Vacuum
(in H2O)
2
3
3
2
2
3
3
3
4
4
4
4
0
21.7
1.9
19
79.1
30
Y-1
2
3
4
5
6
X-1
2
3
4
5
6
Average
Meter
Temp
(F)
73.5
76.5
77.5
77.0
76.5
77.5
78.0
78.5
79.5
79.5
79.5
79.5
END
END
77.75
-------
Eistem Research Group, Inc.
METHOD 5 DATA SHEET
Run
Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
U.£. fcvtec
9 /^S" 797
3~«V<,ICSOV>
S8.S S1&«_V£
toSA
T-
•f. 01
*»-9. ftC
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type C loon, . )
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check 1.$"' V*v
V»-A
log
-v t
\ 08
0.006
O.OOfe
Meter Box Number
Meter delta H@
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (T)
Assumed Moisture (% H2O)
K-Factor
A-39
U"ioo
O.JVL
0/i4t
fcs
•j
3 53
*c
V
G
Tt
\
£i" CV^4>
^
^i«v c-»JO
i
* Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every 7 minute* £». Vt*V
Traverse
Point
Number
y- i
7.
%
4
1
C
Tt - i
2
1
•^
• 3-
C
Sampling
Time
(min)
G
<;
Vo
V?'
Ttf
zr
to
30
3?
4o
4C
3&
55-
to
* Clock
Time
(24hr)
091^
o«»a*7
o 9 '1 •*.
o«» 1 7
oTVt
o *» -\ T
o "><;•/
e-9^C
idol
100C
\0I )
\o I jG
I 0^)
\a-u$
Gas
Meter
Reading
((Vm).ft3)
49 C.. 137
-loo. S
-4o^. -V
toe .4
^ 1 'l-,4
4 \C. ft
-\\9 a~)&
^VLO .ut 6
-t t
.C,o
.65
.tG,
Stack
Ts
(T)
94
95
9-V
^5'
9 1
•3 »
^ \
9-L
*92-
9"i
^c,
9.^
Orifice F
Differ
(delta H.
Desired
l.S>v)
l.'7t
1.82
\ A\
1 .f>G
t.^-7
\.^'^
t.o^
'L. 0«
JL. \T-
1..-L9
2., 3 5
Vessure
ential
in.H20)
Actual
i.59
l.Tt
\,8'?
\.-v\
\.Cr.
1.^-7
v.e^
^-0-^
•L-OS
T-.l I
1.19
^--5?
Probe
Temp.
(•F)
*?tt
\ OQ
10^
* \T-
V V O
\ 0«
\.o9
\\1
i V-7
\ 1C
viG
Lit
Filter
Temp.
(•F)
^OT
V04
1 0^
lot
\o L
"7 '2.
-73
•7'i
73
14
1^
^4
"7-t
Impinger
Exit
Temp.
CF)
52.
AO
?i
5 2-
5*^
*C
55
S 6
^ V,
Go
L\
G\
Pump
Vacuum
(in.Hg)
7-
"^
3
T_
2
S
^
^
A
•4-
-V
^
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page of
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps),
in.H2O)
'
Stack
Ts
(°F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
(•F)
Fitter
Temp.
(°F)
Adsorbent
Trap
Temp.
CF)
Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)
Impinger
Exit
Temp.
CF)
Pump
Vacuum
(in.Hg)
.
Comments:
-------
tERG
Eastern Research Grcxjp. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type .
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses :«;
Sample Identification
Filter Number
XAD Number
p. K.
Q-^M-^%-
^~> (l/~5 Vl ^M^T" ^ 0~T l£~T
£^j\
/)
""^
Af A •
T££.
33 1 13 ^ - X^ V *
Impinger
Number
Impinger
Solution
Amount of
Solution
(g)
Impinger Tip
Configuration
Impinger Weight
Final
(g)
Initial
(g)
Weight
Gain
(g)
MT
J
fet.O
Total Weight Gain g)
-------
Facility: US Intec
Date: 09/25/97
Location: SBS Stack
Run Number: 3
Sample Type: MSA
Total Sampling Time (min) 60.0
Corrected Barometric Pressure (in Hg) 29.86
Absolute Stack Pressure (in Hg) 29.86
Stack Static Pressure (in H2O) 0.01
Average Stack Temperature (°F) 93.25
Stack Area (sq in) 706.86
Actual Meter Volume (cu ft) 48.024
Average Meter Pressure (in H2O) 1.84
Average Meter Temperature (°F) 81.17
Moisture Collected (g) 20.00
Carbon Dioxide Concentration (%V) 1.9
Oxygen Concentration (%V) 19.0
Nitrogen Concentration (%V) 79.1
Dry Gas Meter Factor 0.9960
Nozzle Diameter (in) 0.246
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.780
Standard Metered Volume (dscf) 46.789
Standard Metered Volume (dscm) 1.325
Stack Moisture (%V) 1.98
Mole Fraction Dry Stack Gas 0.980
Dry Molecular Weight 29.06
Wet Molecular Weight 28.85
Stack Gas Velocity (fpm) 2487.63
Stack Gas Velocity (mpm) 758.23
Volumetric Flow Rate (acfm) 12211.12
Volumetric Flow Rate (acmm) 345.82
Volumetric Flow Rate (dscfm) 11400.65
Volumetric Flow Rate (dscmm) 322.87
Percent Isokinetic 101.73
Percent Excess Air N/A
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Plant
Date
Sampling Location
Sample Type
Run Number
Operator
Ambient Temperature
Barometric Pressure
Static Pressure (Ps)
Intial Leak Check
US Intec
09/25/97
MSA
Traverse
Point
Location
X-1
2
3
4
5
6
Y-1
2
3
4
5
6
Sampling
Time
(min)
o
5
10
15
20
25
30
30
35
40
45
50
55
60
US Intec
09/25/97
SBS Stack
MSA
3
Jackson
60
29.86
0.01
.008@15"
Dry Gas
Clock
Time
(24 hr)
1040
1045
1050
1055
1100
1105
1110
1114
1119
1124
1129
1134
1139
1144
Meter
Reading
Vm(fP)
447782
451.8
455.8
460
464.3
468.7
473.198
473.309
477
480.9
484.9
488.2
492.1
495.917
Probe Length & Type 4' glass
Nozzle ID (in) 0.246
Meter Box Number A-39
Meter Delta H@ 1.7
Dry Gas Meter Factor (Yd) 0.996
K Factor 3.53
Probe Heater Setting 1 08
Heater Box Setting
Pilot Constant 0.84
Final Leak Check .007@1 5"
Orifice
Velocity
Head
(|P)
(in H2O)
0.5
0.56
0.55
0.61
0.66
0.64
0.43
0.47
0.5
0.37
0.48
0.5
Pressure
Diff
<£H)
(in H20)
1.76
1.97
1.94
2.15
2.33
2.26
1.52
1.66
1.76
1.3
1.69
1.76
Stack
Temp
Ts
(F)
92
92
91
92
94
95
94
95
96
93
94
91
Dry Gas Meter
Temperature
Tm in Tm out
(F)
81
85
85
86
87
86
80
86
86
85
87
89
(F)
74
75
75
76
77
77
77
78
79
79
79
79
Height of Lc
Moisture Cc
CO2 Percer
O2 Percent
N2 Percent
Paniculate (
Stack Georr
Stack Diami
Stack Width
Impinger
Exit
Temp
(F)
62
58
61
62
64
62
58
56
56
58
59
59
Pump
Vacuum
(in H20)
7
8
8
9
11
11
7
7
7
5
7
7
0
20
1.9
19
79.1
30
Y-1
2
3
4
5
6
X-1
2
3
4
5
6
Average
Meter
temp
(F)
77.5
80.0
80.0
81.0
82.0
81.5
78.5
82.0
82.5
82.0
83.0
84.0
END
END
81.16667
-------
Eastern Research Group, Inc.
vMODiriCD METHOD 5 DATA SHEET
A,
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
U.S *I>\te«:
9 / 1.5V*n
'3«vt,Nc*»^
3 as sw^t
^ ^A
**>
•V.o |
•2.9. <4
'3
3.S1
u, !*-«.*
T *
~f>" cii
, hi i
) Diagram of Duct
r
0
Schematic of Traverse Point Layout
Read and record all data every S minutes
Traverse
Point
Number
y- <
^ -z.
?
4
3
c
y- »
r 'I
1
1
^-
L
Sampling
Time
(min)
O
^
lo
V^
Xo
^r
\0
'Jo
:?,s
^«
-rr
7o
rs
60
Clock
Time
(24hr)
10-^0
Vto^9
t o £0
i«a cr
^ t <3 O
\ \ &F
\\ i O
( t v<^
V^ \9
VNO.-1
VVT.9
V \ '?^
v \19
V\^4
Gas
Meter
Reading
((Vm).ft3)
**-^n.78i
^?v . a
<*$•? -
I. 6t>
\ .~IL
1.1,0
V.L9
|.-lfc
3ressure
ential
in.H20)
Actual
t^-6
V.9'7
V.^'V
-/-.y
95
*>$•
*5S
96
S^t
^fi
«5^
99
99
99
DryGa
Inlet
(Tm in)
a i
85:
«£
RA
«"7
««6
^0
3£
ft<5
e^
9-7
e^
s Meter
Outlet
(Tm out)
?+
-is
'I 5
-7^.
T7
T 7
T7
7«
7 ?
09
-79-
~7^
Impinger
Exit
Temp.
CF)
<^
S8
G I
fel-
44
61
•58
5^
SC
Si)?
s?
S9
Pump
Vacuum
(in.Hg)
1
ft
ft
9
\ I
t 1
7
7
7
s:
7
"7
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page ol
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps),
in.H20)
Stack
Ts
CF)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
(°F)
Filter
Temp.
CF)
.
Adsorbent
Trap
Temp.
CF)
Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)
Impinger
Exit
Temp.
CF)
Pump
Vacuum*
(in.Hg)
Comments:
-------
fcERG
Eastern Research Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant ,
Date 3 ^:..-: «;?•:.. vV:::. ::::?':V <;
Sampling? Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
- M->
qr-35-9^
-5 /?><> \) fc/siT £>OT UHT
-Tr\
^
M.H.
^9/a^^-3H ^''
Impinger
Number
1
2
3
4
5
&
7
Impinger
Solution
H^D
1^0
M,T.
^^t
-*
Amount of
Solution
(9)
^Ot,
100^
Impfnger Tip
Configuration
- 'SK ';:;:''' ''':
M^fe
^fe
Mb6
M(?B
.rf Impinger Weight
Filial
(g)
•oOS.l
dU, $
4^1.5"
?^.o
Initial
(9)
6o3,(b
CoJT'C^
HS-S.C
^ifc.S
Total Weight Gain (g)
Weight
Gain
(g)
^, /
A V
^.^
/^-^
5o <>
-------
fcERG
~ r fmmtmn DA*ASlr/*H f^.tf*i ,f
Eastern Research Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
P. (\,
q-^3 -^*^
Ttitfe. AJ A i A v i A i ^.£A CUTLET
:rTR 5" A
^(^•^
M ,P\i
c3 ^ / d.^ 'XI M "
Impinger
Number
1
2
3
4
5
6
7
Impinger
Solution
W
/^O
A\T
^.^.
Amount of
Solution
(g)
IOD^
(60 »&.
Impinger Tip
Configuration
Impinger Weig
Final
(g)
Initial
(g)
5tfo =H
G3i,H
^fc.l
7^13
Total Weight Gain (g)
ht
Weight
Gain
(g)
-------
Eastern Research Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant ..::x;:, ..••' -,.;:,;<•• -• :.
Date ,,:•:;:;:
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
P.A.
S-&V7T
TneGMh L £ y~( ftR.eQ /A( <-£ r
5Jr\
o
Ml
5-fc?.
Amount of
Solution
(9)
iDDnd
100 ^(L
Impinger Tip
Configuration
Impinger Weight
Final
(g)
Initial
(g)
s^rsrt
fftS.'X
^.^
W.^
Total Weight Gain (g)
Weight
Gain
(g)
-------
Eosfem Research Group, Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
Pft
9-l"Vc7c?-
CctLftfei-Pwic ^UTL£\ 0> ^
rgj_
&>\ . PV. i
Impinger
Number
1
2
3
4
5
6
7
Impinger
Solution
jy\T
Uȣ
^0
Ml
^.<^.
Amount of
Solution
(g)
/fiCi^.
iooi^i
Impinger Tip
Configuration
Impinger Weig
Final
(g)
4Si.>
Initial
(g)
m.%
atf.7-
£%>.«
HSf^S
l^.O
Total Weight Gain (g)
ht
Weight
Gain
(g)
-------
lERG
Eastern Research Group. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Persort
Recovery Rinses
Sample Identification
Filter Number
XAD Number
PP\
Gf'&'Z-^*?
n
Al.f\ ,
Impinger
Number
1
2
3
4
5
6
7
Impinger
Solution
H~V
UtD
t-f^-D
MT
^.6.
»
Amount of
Solution
(9)
IDO^i
lOQSld
Impinger Tip
Configuration
Impinger Weight
Final
(g)
Initial,
(g) ii
W.I
t-IO-Cs
5?
-------
Traverse Point Location Form
Eotfem Research Group. Inc.
Plant
Date
isampling Location
"total Duct Depth (Distance A)
U.£- ±^*-a-e
9Y T-i / 9-7
T. c. ±>».UsAt
'W
Uinside Far Wall to Outside of Nipple/Port)
Nipple/Port Length (Distance B)
*t h
(Inside Near Wall to Outside End of Nipple/Port)
Stack Depth (Dist A - Dist B)
Stack Width (If rectangular)
Nearest Upstream Disturbance
Nearest Downstream Disturbance
Calculator
~?>?<%
K, A.
05.63AO Si 6 '•
ft.iiAO *7^"
S. ^^*NOv.
Sample Ports Number I.D. (in)
Information "2- & ?<> ° -f '•
,^7A
^'•^VJ «
\ ^~ f ~
V ° "^ '"• "\.
Schematic of Sampling Location
(Cross Section of Duct)
1
Traverse
Point
Number
A 6 - \
r- a
3
*\
«>
G
-
,--:v,.:::,V:V,:2--' ' --.• •
Percent Fraction
of Stack ID
<6t-4-
. * ^G
.L5fc
.-70-V
;^^
.^C^
.*
••. 3 ..
Stack
ID
(in)
1>5'
4 ': , : •
Product of Columns
2&3
(to nearest 1/8 inch)
\ V^
S '755.
I O VA
2.-VV6
a9 ^
33 y,
-, •'S---
Distance
B
(in)
^
I
•
- , ^,,:.:6- ;v-.
Traverse Point Location
from Outside of Nipple
(sum of columns 4 & 5)
s v^
^ /«
\A V^
-2.8 Va
f337/g
T»T V^
f
F
t
-------
Eastern Research Group. Inc.
PERCENT OF STACK DIAMETER FROM INSIDE WALL
TO TRAVERSE POINT
Traverse
point
number
on a
diameter a
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Number of traverse point on a diameter
24 6 8 10 12 14 16 18 20 22 24
14.6
85.4
6.7
25.0
75.0
933
4.4
14.6
29.6
70.4
85.4
95.6
3.2
10.5
19.4
323
67.7
80.6
89.5
96.8
•
2.6
8.2
14.6
22.6
34.2
65.8
77.4
85.4
91.8
97.4
2.1
6.7
11.8
17.7
25.0
35.6
64.4
75.0
823
88.2
933
97.9
1.8
5.7
9.9
14.6
20.1
26.9
36.6
63.4
73.1
79.9
85.4
90.1
943
98.2
1.6
4.9
8.5
12J
16.9
22.0
283
37.5
62.5
71.7
78.0
83.1
87.5
91.5
95.1
98.4
1.4
4.4
7.5
10.9
14.6
18.8
23.6
29.6
38.2
61.8
70.4
76.4
81.2
85.4
89.1
92.5
95.6
98.6
13
3.9
6.7
9.7
12.9
16.5
20.4
25.0
30.6
38.8
61.2
-.69.4
75.0
79.6
83.5
87.1
90.3
933
96.1
98.7
1.1
3.5
6.0
8.7
11.6
14.6
18.0
21.8
26.2
31.5
393
60.7
68.5
73.8
78.2
82.0
85.4
88.4
913
94.0
96.5
98.9
1.1
32
5.5
7.9
10.5
13.2
16.1
19.4
23.0
27.2
323
39.8
602
67.7
72.8
77.0
80.6
83.9
86.8
89.5
92.1
94.5
96.8
98.9
a Points numbered horn far side to near side of the stack.
-------
Eastern Research Group. Inc.
Preliminary Velocity Traverse Form and Cyclonic Flow Check
Plant
U > T--W
[Location
Stack ID (in)
Barometric Pressure (in Hg) |
I Ambient'Tempen^ure (°F)
Static Pressure (in H2O)
- T. 0
l°pj
erators
i-3
Checked By
Schematic of Traverse Point Layout
(Cross Section of Duct)
Traverse
Point
Number
A - )
^
•3
-^
i
7
C
B~ i
•v
I
t
r
c
-
Velocity
Head
AP. (in H2O)
.7.0
.ZO
- \O
lc
. ao
- 12
i«
»"7
. 09
. I O
1~7
.'iu3
Stack
Temperature
TS, rn
^T_
^7
•9^
9"2_
^^
9^
5?
^^
*)3
^3
^•^
20" Require Alignment Approach Sampling.
-------
. Eastern Research Group. Inc.
K-FACTOR CALCULATION FORM
Plant
Date
U.S TVS tee
°> i 1- \ I °>~l
Location/Sampling Train
Operator
Used for runs
T.O. T^-t
WUA-vv^^ /^Jtse
I
\ , -L. c^,( 3
^a^ MSA
C0 (S-type: 0.84; Std: 0.99)
Pb (barometric pressure
at location)
Dn (nozzle diameter, inches)
Bw (moisture in gas stream, fractional percent)
Pm (barometric pressure at meter, Hg) = . ^
(Average AH/ 13.6) + Pb
A H@ (pressure differential of orifice in meterbox,
HjO)
Ps (stack pressure, in. Hg) = _ //
Pb ± (stack static pressure (in. HjO) / 13.6) ~" '
Ts (average stack temperature, ° R) =
3i°F + 460 = "R
Tm (average meter temperature, ° R) =
Tamblent + 2ffF+460=_'R
Md (molecular weight of stack gas, dry, Ib/lb-mole) =
(0.44 x %CQ,) + (032 x %Q,) + (0.28 x %Ny
Ms (molecular weight of stack gas with water vapor, Ib/lb-mole) =
[M, x (1 - EU)] + [18 x BU
K= (846.720)(Dn)4(A H@)(CD)2(l-Bw)2(Md/Ms)(Ps/Pm)(Tm/Ts)
A-l-3
O,1*^
To.oV
ZK
.&
30. /6
0, 99&
Lnoo
1^.$2^
r^^
^o
1<\
2V-63-
1-fc^
A-'Vo
0,S^c
30. oV
,3/S
,0!
36. f6
o.^84
\7T5\
2q.$Z,
^5-L
^^0
i^
2*-&
I0.t3
AH = KAP
Correlation Chart
1
AH
AP
2
AH
AP
3
AH
AP
Comments:
-------
Eastern Research Group. Inc.
Preliminary Velocity Traverse Form and Cyclonic Flow Check
i Location
Stack ID (in) 1 %<• *"
liarometric Pressure (in Hg)j
Ambient Temperature (°F)
Static Pressure (in H2O)
Ooerators
/&/&?
! Checked By
Schematic of Traverse Point Layout
(Cross Section of Duct)
Traverse
Point
Number
Velocity
Head
AP, (in H2O)
Stack
Temperature
Ts, (°R
Cyclonic
Row
Angle (± °)
Traverse
Point
Number
Velocity
Head
AP. (in H2O)
Stack
Temperature
Ts,
Cyclonic
Row
Anqte (± °)
M_
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,
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* Average of Absolute Values of All Angles > 20° Require Alignment Approach Sampling.
-------
Eastern Research Group, Inc.
K-FACTOR CALCUJ^TION FORM
Plant
Date
IK ^^d
<=»/zzA?
Location/Sampling Train
Operator /r\ o /7> /-/
Used for runs
OUT^f -rttauwrfc OX !*/*.
-------
]
\
-------
Appendix B
Participate Matter Raw Data
-------
16
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-------
Appendix C
Dioxin/Furan Raw Data
-------
CASE NARRATIVE
Analysis of Samples for the Presence of
Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans by
High-Resolution Chromatography / High-Resolution Mass Spectrometry
Method 23 (6/93)
Date:
Client ID:
P.O. Number:
TLI Project Number:
October 20, 1997
Eastern Research Group
43431
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Rev. 05/08/97
Triangle Laboratories, Inc.
801 Capitola Drive P-0. Box 13485 '
Durham, NC 27713-4411 Research Triangle Park, NCU7709-3485
919-544-5729 Fax # 919-544-5491
-------
Triangle Laboratories, Inc. October 20, 1997
Case Narrative 43431
Overview
Ten M23 samples were received from Eastern Research Group at 7.0 °C in good
condition on September 29,1997 and were stored in a refrigerator at 4°C. Only the
results for nine of the samples are included in this data package. The samples and any
associated QC samples were extracted and analyzed according to procedures described in
the Triangle Laboratories' Data User's Manual (Rev. 12/92-HK-2-AH-2/93). Any
particular difficulties encountered during the sample handling by Triangle Laboratories will
be discussed in the QC Remarks section below. Results reported relate only to the items
tested.
Quality Control Samples
A laboratory method blank, identified as the TLI Blank, was prepared along with the
samples.
Quality Control Remarks
This release of this particular set of Eastern Research Group analytical data by Triangle
Laboratories was authorized by the Quality Control Chemist who has reviewed each
sample data package individually following a series of inspections/reviews. When
applicable, general deviations from acceptable QC requirements are identified below and
comments are made on the effect of these deviations upon the validity and reliability of the
results. Please consult Triangle Laboratories' Data User's Manual for further details.
Specific QC issues associated with this particular project are:
Sample Preparation Laboratory: All the field samples were processed through additional
clean-up procedures. An additional blank, identified as CleanUp BLK, was initiated at
that time.
Mass Spectrometry: None
Data Review: None
Other Comments: Any analytes found in the TLI Blank or the cleanup blank are
detected at a level equal to or less than the Target Detection Limit. This level of
contamination is acceptable as per TLI guidelines.
Sample Calculations:
-------
Triangle Laboratories, Inc. October 20,1997
Case Narrative 43431
Analyte Concentration
The amount of any analyte is calculated using the following expression.
Ao*Qp
Amt (o)=
Ap*RRF(o) *W
Where:
Amt (a) is the amount of a given analyte,
AO is the integrated current for the characteristic ions of the analyte,
Ap is the integrated current of the characteristic ions of the corresponding internal
standard,
Qp represents the amount of internal standard added to the sample before extraction,
RRF(a) is the mean analyte relative response factor from the initial calibration (ICal) and,
W is the sample weight or volume (W = 1 for M23)
The amount is expressed in nanograms (ng) or picograms (pg).
Detection Limits
The detection limit reported for a target analyte that is not detected or presents an analyte
response that is less than 2.5 times the background level is calculated by using the
following expression. The area of the analyte is replaced by the noise level measured in a
region of the chromatogram clear of genuine GC signals multiplied by an empirically
determined factor. The detection limits represent the maximum possible concentration of
a target analyte that could be present without being detected.
2 * 2.5 * (F * H) * Qp
•l-'Mo)=
Ap*RRF(0) *W
Where:
DL(0) is the estimated detection limit for a target analyte,
-------
Triangle Laboratories, Inc. October 20, 1997
Case Narrative 43431
2.5 is the minimum response required for a GC signal,
F is an empirical number that approximates the area to height ratio for a GC signal. This
number is 3.7 for both the DB-5 GC column and the DB-225 GC column,
H is the height of the noise
Ap is the integrated current of the characteristic ions of the corresponding internal
standard,
Qp represents the amount of internal standard added to the sample before extraction,
RRF(o) is the mean analyte relative response factor from the initial calibration (ICal) and,
W is the sample weight or volume
The detection limit is expressed in nanograms (ng) or picograms (pg).
Other sample calculations may be found in the Triangle Laboratories Data User's Manual.
Data Flags
In order to assist with data interpretation, data qualifier flags are used on the final reports,
as discussed in Triangle Laboratories' Method 23 Data User's Manual. Please note that all
data qualifier flags are subjective and are applied as consistently as possible. Each flag has
been reviewed by two independent Chemists and the impact of the data qualifier flag on
the quality of the data discussed above. The most commonly used flags are:
A 'B' flag is used to indicate that an analyte has been detected in the laboratory method
blank as well as in an associated field sample. The 'B' flag will be used only when the
concentration of analyte found in the sample is less than 20 times that found in the
associated blank. This flag denotes possible contribution of background laboratory
contamination to the concentration or amount of that analyte detected in the field sample.
Under Triangle Laboratories guidelines, a laboratory blank is acceptable if the tetra-
through hepta-CDD/CDF levels are all below the target detection limits (TDLS) or if the
contamination levels are less than 5% of the levels detected in the associated field samples.
If these conditions are satisfied or if the blank is unable to be reextracted, the
interpretation of the contamination levels relative to the samples should be as follows: 1)
analyte quantitations should be considered valid if the level of blank contamination is less
than five percent of the level detected in the field sample, 2) analyte quantitations should
be considered estimated if the analyte level in the sample is five to twenty times the level
of the analyte in the blank, or 3) analytes whose level in a sample is the same as or less
-------
Triangle Laboratories, Inc. October 20,1997
Case Narrative 43431
than five times the level detected in the associated blank should be considered present
likely due to laboratory contamination and not native to the sample.
An '£' flag is used to indicate that an PCDF peak has eluted at the same time as the
associated diphenyl ether (DPE) and that the DPE peak intensity is ten percent or more of
the PCDF peak intensity. Total PCDF values are flagged '£' if the total DPE contribution
to the total PCDF value is greater than ten percent. All PCDF peaks that are significantly
influenced by the presence of DPE peaks are quantitated with EMPC values, regardless of
the isotopic abundance ratio. These EMPC values are most likely overestimated due to
the DPE contribution to the peak area.
An *!' flag is used to indicate labeled standards have been interfered with on the GC
column by coeluting, interferent peaks. The interference may have caused the standard's
area to be overestimated. All quantitations relative to this standard, therefore, may be
underestimated.
A 'PR* flag is used to indicate that a GC peak is poorly resolved. This resolution problem
may be seen as two closely eluting peaks without a reasonable valley between the peak
tops, overly broad peaks, or peaks whose shapes vary greatly from a normal distribution.
The concentrations or amounts reported for such peaks are most likely overestimated.
A 'Q' flag is used to indicate the presence of QC ion instabilities caused by quantitative
interferences. Affected analytes may be overestimated or underestimated as a result of this
interference. A peak is flagged 'Q' only if it is affected by a QC ion deviation greater than
20% full scale as determined relative to the labeled standard against which it is
quantitated. Total PCDF/PCDF quantitations will be flagged 'Q' if the interferences affect
ten percent or more of the total PCDD/PCDF peak areas.
An *RO' flag is used to indicate that a labeled standard has an ion abundance ratio that is
outside of the acceptable QC limits, most likely due to a coeluting interference. This may
have caused the percent recovery of the standard to be overestimated. All quantitations
versus this standard, therefore, may be underestimated.
A 'U' flag is used to indicate that a specific (2,3,7,8-substituted) isomer cannot be
resolved from a large, coeluting interferent GC peak. The specific isomer is reported as
not detected as a valid concentration/amount cannot be determined. The calculated
detection limit, therefore, should be considered an underestimated value.
A 'V* flag is used to indicate that, although the percent recovery of a labeled standard may
be below a specific QC limit, the signal-to-noise ratio of the peak is greater than ten-to-
one. The standard is considered reliably quantifiable. All quantitations derived from the
standard are considered valid as well.
-------
Triangle Laboratories, Inc. October 20, 1997
Case Narrative 43431
By our interpretation, the analytical data in this project are valid based on the guidelines
of EPA Method 23 (6/93) and Triangle Laboratories' Method 23 Data User's Manual.
Any specific QC concerns or problems have been discussed in the QC Remarks section of
this case narrative with emphasis on their effect on the data. Should Eastern Research
Group have any questions or comments regarding this data package, please feel free to
contact our Project Scientist, Amy Boehm, at 919/544-5729 ext. 268.
For Triangle Laboratories, Inc.,
Report Preparation Quality Control
Kenneth Varley /^W - C.
Report Preparation Chemist Report Preparation Chemist
The total number of pages in the data package is : rr\(£.
-------
TRIANGLE LABORATORIES, INC.
LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL
American Association for Laboratory Accreditation. Certification pending. Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(Including
Waste Water, SoI/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX,
Volatiles, Pesticides, PCB's, BNA's, and Dioxin/Furan. Method 1613 for Drinking Water.
State of Alabama, Department of Environmental Management. Expires December 31, 1997
Laboratory I.D. # 40950. Dioxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires December 21, 1997.
Certificate number OS-00397 Dioxin in drinking water.
State of Arizona, Department of Health Services. Expires May 26, 1998. Certificate
#AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste.
State of Arkansas, Department of Pollution Control and Ecology. Expires February 18,
1998. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX.
State of California, Department of Health Services. Expires August 31, 1999. Certificate
#1922. Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and
SoI/Haz Waste. Dioxin in drinking water.
State of Connecticut, Department of Health Services. Certification pending. Registration #
PH-0117. Dioxin in drinking water.
Delaware Health and Social Services. Expires December 31, 1997. Certificate #NC 140.
Dioxin in drinking water.
Florida Department of Health and Rehabilitative Services. Expires June 30, 1998. Dioxin in
DW. Drinking Water ID HRS# 87424. Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS#
E87411.
Hawaii Department of Health. Expires March 1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .
Revised 10/15/97 RM
Printed 10/15/97 „„„ _ .. . Jungle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27309-3485
919-544-5729 Fax # 919-544-5491 ' ( —
-------
Idaho Department of Health and Welfare. Expires November 30, 1997. Dioxin in drinking
water.
State of Kansas, Department of Health and Environment. Expires January 31, 1998.
Environmental Analyses/Non potable Water and Solid and Hazardous Waste. Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste - E-1209.
Commonwealth of Kentucky, Department for Environmental Protection. Expires December
31, 1997. ID#90060. Dioxin in drinking water. '
Maryland Department of Health and Mental Hygiene. Expires September 30, 1998.
Certification #235. Drinking water by Method 1613A.
State of Michigan, Department of Public Health. Expires June 3, 1998. Drinking water by
Method 1613.
Mississippi State Department of Health. No expiration date.. Dioxin in drinking water.
Montana Department of Health and Environmental Services. Expires December 31, 1997
Dioxin in drinking water.
State of New Jersey, Department of Environmental Protection and Energy. Extended by
state. Temporary certificate until December 31, 1997. ID #67851. BNAs and Volatiles. Dioxin in
drinking water.
State of New Mexico, Environment Department. Certification pending. Dioxin in drinking
water.
New York State Department of Health. Expires April 1, 1998. ID'#11026. Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.
State of North Carolina, Department of Environment Health and Natural Resources
Expires August 31, 1999. Certificate # 37751. Dioxin in drinking water.
State of North Carolina, Department of Environment, Health, and Natural Resources,
Division of Environmental Management. Expires December 31, 1997. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.
North Dakota State Department of Health and Consolidated Laboratories. Expires
December 31, 1997. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.
Revised 10/15/97 RM
Printed 10/15/97
8
-------
Oklahoma Department of Environmental Quality. Expires August 31, 1998. Laboratory
#9612. Dioxin by 1613A, 8290 and 8280.
State of South Carolina, Department of Health and Environmental Control.October 31,
1997. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002 (other parameters). Dioxin/Furans, BNA, Volatiles, and RGBs/pesticides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid
and Hazardous Waste.
State of Tennessee. Department of Environment and Conservation. Expires February 5,
1999. ID #02992. Method 1613 Drinking water only.
U.S. Department of Agriculture Soil Permit. Expires September 30, 2001. Permit No. S-
3790. Under the authority of the Federal Plant Pest Act, permission is granted to receive
foreign soil samples for use in laboratory analysis.
U.S. Army Corps of Engineers. Expires November 30, 1997. Validated to perform methods
8280 & 8290 for Lockboume Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USAGE North Pacific Division Laboratory.
U.S. EPA Region V. Expires November 14, 1999. Dioxin in drinking water.
U.S. EPA Region VIII, for the State of Wyoming. Expires November 13, 1997. Dioxin in
drinking water.
State of Utah, Department of Health. Expires December 31, 1997 Certificate Number E-166.
Certification for the following parameters: Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by Method
1613; Metals including Mercury and Microwave Digestion.
Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30, 1998. ID # 00341. Dioxin in drinking water.
State of Washington, Department of Ecology. Expires September 11, 1998. Lab
Accreditation Number C067. Scope of Accreditation applies to water analyses for
Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile)
Organics and Purgeable (Volatile) Organics.
State of Washington, Department of Health. Expires April 30, 1998. Dioxin in drinking water.
Lab I.D. 129
State of West Virginia, Department of Health. Expires December 31, 1997 Certificate No.
9923(C). Dioxin in drinking water.
Revised 10/15/97 RM
Printed 10/15/97
-------
State of Wisconsin, Department of Natural Resources. Expires August 31, 1998.
Laboratory ID Number 999869530. Certification for the following categories of Organics:
Purgeable, Base/Neutral, Acid, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ID
999869530. Dioxin in drinking water.
PHARMACEUTICAL
Drug Enforcement Agency (DEA). Expires November 30, 1997. Registration number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.
N.C. Department of Human Resources. Expires October 31, 1997. Registration number NC-
PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.
Food & Drug Administration (FDA) Registration. Expires June 1998. ID #'s 001500
1053481. Annual registration of drug establishment. Annual registration of drug establishment.
OTHER
Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30, 1999.
ID # 34D0705123. Department of Health & Human Services, Health Care Financing
Administration.
U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.
North Carolina Radioactive Materials License. Expires April 30 1998. License No. 032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.
North Carolina General License for Radiation Protection. No. expiration date. License No.
032-875-OG. The general license applies only to radioactive material contained in devices
which have been manufactured and labeled in accordance with specific requirements.
Revised 10/15/97 RM
Printed 10/15/97
10
-------
DOCUMENT
CONTROL
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709.3485
919-544-5729 Fax * 919-544-5491 H
-------
CHAIN OF CUSTODY - US Intec
US EPA • Asphalt Plants, Port Arthur,
RELINQUISHED BY:
RELINQUISHED BY:
DATE:
DATE:
RECEIVED BY:
RECEIVED BY:
\y
y/
V
V
V
V
\l
SAMPLE ID
USI-34
USI-4
USI-38
USI-B
USI-12
USI-42
USI-16
USI-46
USI-20
USI-50
FIELD ID
USI- • M23- TIN- XAD- 1
^USI- - . M23- TOUT- XAD- 1
USI- „ - M23- TINr XAD- 2
USI- - M23- TOUT- XAD- 2
USI- - M23- TOUT- XAD- 3
USI- - M23- TIN- XAD- 3
USI- - M23- TOUT- XAD- FBI
USI- - M23- TIN- XAD- FB2
USI- - M23- TOUT- XAD- RBI
USI- - M23- TIN- XAD- RB2
SAMPLE TYPE
METHOD 23, THERMAL INLET, RUN 1
METHOD 23, THERMAL OUT, RUN 1
METHOD 23, THERMAL INLET, RUN 2
METHOD 23. THERMAL OUT, RUN 2
METHOD 23. THERMAL OUT. RUN 3
METHOD 23. THERMAL INLET, RUN 3
METHOD 23, THERMAL OUT, FB
METHOD 23, THERMAL INLET, FB2
METHOD 23, THERMAL OUT, RBI
METHOD 23, THERMAL INLET, RB2
PRESERVATIVE
XAD Trap
XAD Trap
XAD Trap
XAD Trap
XAD Trap
XAD Trap
XAD Trap
XAD Trap '
XAD Trap
XAD Trap
COMMENTS
D\*r P\AlW-fr£| S
CA*,(<>
O^ PvrJ/SLV^'S
fc"T £R(T>
Page?
-------
coc
CHAIN OF CUSTODY - US Inlec
US EPA - Asphalt Plants, Port
RELINQUISHED BY
RELINQUISHED BY:
lanls,PortArthur,TX /) A .
&fi^(JAjL
DATE:
DATE:
RECEIVED BY:
RECEIVED BY:
DATE:
V
V
V
V
V
0-
V
\,
{/
V
V
V
V
s/
\/
V
V
SAMPLE ID
USI-21
USI-3
USI-33
USI-51
USI-61
USI-71
USI-23
USI-37
- USI-53
USI-63
USI-7
USI-73
USI-11
USI-25
USI-41
USI-55
USI-65
" USI-75
USI-27
USI-15
USI-45
' USI-57
USI-67
USI-77
USI-29
USI-19
USI-49
USI-59
USI-69 _L
USI-79
FIELD ID
USI- - MSA- TOUT- F- 1
USI- - M23- TOUT- F- 1
USI- - M23- TIN- F- 1
USI- - MSA- TIN- F- 1
USI- • MSA- SBSOUT- F- 1
USI- - MSA- APPOUT- F- 1
USI- - MSA- TOUT- F- 2
USI- - M23- TIN- F- 2
USI- - MSA- TIN- F- 2
USI- - MSA- SBSOUT- F- 2
USI- - M23- TOUT- F- 2
USI- - MSA- APPOUT- F- 2
USI- - M23- TOUT- F- 3
USI- - MSA- TOUT- F- 3
USI- - M23- TIN- F- 3
USI- - MSA- TIN- F- 3
USI- - MSA- SBSOUT- F- 3
USI- . - MSA- APPOUT- F- 3
•USI- - MSA- TOUT- F- FB
USI- - M23- TOUT- F- FBI
USI- - M23- T/N- F- FB2
USI- - MSA- TIN- F- FB2
USI- - MSA- SBSOUT- F- FB3
USI- - MSA- APPOUT- F- FB4
USI- - • MSA- TOUT- F- RB
USI- - M23- TOUT- F- RBI
USI- - M23- TIN- F- RB2
USI- - MSA- - TIN- F- RB2
USI- - i MSA- SBSOUT- F- RB3
USI- - MSA- APPOUT- F- RB4
SAMPLE TYPE
METHOD 5A, THERMAL OUT, RUN 1
METHOD 23. THERMAL OUT. RUN 1
METHOD 23. THERMAL INLET, RUN 1
METHOD 5A, THERMAL INLET, RUN 1
METHOD SA. SBS VENT OUT. RUN 1
METHOD SA, APP VENT OUT, RUN 1
METHOD SA. THERMAL OUT. RUN 2
METHOD 23. THERMAL INLET. RUN 2
METHOD SA. THERMAL INLET. RUN 2
METHOD SA, SBS VENT OUT. RUN 2
METHOD 23, THERMAL OUT, RUN 2
METHOD SA, APP VENT OUT, RUN 2
METHOD 23, THERMAL OUT, RUN 3
METHOD SA, THERMAL OUT, RUN 3
METHOD 23, THERMAL INLET, RUN 3
METHOD SA, THERMAL INLET, RUN 3
METHOD SA, SBS VENT OUT, RUN 3
METHOD SA, APP VENT OUT, RUN 3
METHOD SA, THERMAL OUT, FBA_
METHOD 23, THERMAL OUT. FB4-
METHOD 23, THERMAL INLET, FB2
METHOD SA. THERMAL INLET. FB2
METHOD SA. SBS VENT OUT. FB3
METHOD SA. APP VENT OUT. FB4
METHOD SA. THERMAL OUT. RBI
METHOD 23. THERMAL OUT. RBI
METHOD 23. THERMAL INLET. RB2
METHOD SA. THERMAL INLET. RB2
METHOD SA, SBS VENT OUT, RB3
METHOD SA, APP VENT OUT, RB4
PRESERVATIVE
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coc
CHAIN OF CUSTODY - US Inlec
US EPA -Asphalt Plants. Port Arthur, TX
RELINQUISHED BY:
RELINQUISHED BY:
DATE:
DATE:
RECEIVED BY:
RECEIVED BY:
DATE:
DATE:
V
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USI-31
USI-35
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USI- - M23- TOUT- PR- 1
USI- - M23- TIN- PR- 1
USI- * - ' M23- TIN- PR- 2
USI- - M23- . TOUT- PR- 2
USI- - M23- TIN- PR- 3
USI- - M23- TOUT- PR- 3
USI. - M23- TOUT- PR- FB1
USI- - M23- TIN- PR- FB2
USI- - M23- TOUT- PR- RBI
USI- - M23- TIN- PR- RB2
SAMPLE TYPE
METHOD 23, THERMAL OUT, RUN 1
METHOD 23. THERMAL INLET. RUN 1
METHOD 23. THERMAL INLET. RUN 2
METHOD 23, THERMAL OUT, RUN 2
METHOD 23, THERMAL INLET. RUN 3
METHOD 23, THERMAL OUT. RUN 3
METHOD 23. THERMAL OUT, FBI.
METHOD 23. THERMAL INLET. FB2
METHOD 23, THERMAL OUT, RBI
METHOD 23, THERMAL INLET, RB2
PRESERVATIVE
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acelone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Ace(one Probe Rinse
COMMENTS
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-------
|| Custody Seal : Present/Intact Sample Seals t Present
|| Chain of Custody ; Present Container...! Intact
H Sample Tags : Absent
|| Sample Tag Numbers: Not Listed on Chain of Custody
|| SMO Forms : N/A
TLI Project Number 43431
Client! ERGO 2 - Eastern Research Group
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Date Received | 09/29/97 | By XA/X^W>T//
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=Form Revised 05/27/1997 -- Page 1 OF 3=
-------
=TRIANOLE LABORATORIES, INC. -- LOG IN RECORD/CHAIN OF CUSTODY**
Custody Seal : Present/Intact
Chain of Custody : Present
Sample Tags Absent
Sample Tag Numbers: Not Listed on Chain of Custody
SMO Forma i N/A
Sample Seals: Present
Container. . . : Intact
TL1 Project Number 43431
Client: ERG02 - Eastern Research Group
Book J
185 {
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Revised 05/27/1997 -- Page 2 OF 3«
-------
=TRIANGLE LABORATORIES, INC. -- LOO IN RECORD/CHAIN OF CUSTODY*
I Custody Seal : Present/Intact
|| Chain of Custody i Present
I) Sample Tags : Absent
I) Sample Tag Numbers: Not Listed on Chain of Custody
|i SMO Forms : N/A
Sample Sea 1st Present
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TLI Project Number 43431 ,
Client i ERO02 - Eastern Research Group
Date Received
| 09/29/97 | By
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=Form Revised 05/27/1997 -- Page 3 OF 3=
-------
TRIANGLE LABORATORIES, INC.
SAMPLE TRACKING AND PROJECT MANAGEMENT FORM
ADMINISTRATIVE INFORMATION
TLI Proj#: 43431- Samples: 9 TurnAround.: 21 Day(s)
Prod Code: D23061 Matrix.: M23Train Hold Time..: 30 Day(s)
DetectLim: 0.05 ng Type...: A Start Date.: 0^*^/97*l/3»
Recvd..: 09/29/97 Ship By. . . . : JL&ftt/BI "»/'*
DWL Due Dt.: 10/07/97
Analyte List.: M23/Tetra-Octa
Method : Method 23 :Tetra-Octa (Tol Combined)
Client Proj..: Asphalt Roofing Project
Client : Eastern Research Group (ERG02)
P.O. No : Collect Dt/Tm: SeeCOC
Contact : Jim McGaughey Phone : 919/461-1209
Proj . Mgr. . . . : Amy J. Boehm Fax : 919/461-1579
Sample Origin:
•SPECIAL INSTRUCTIONS / QA REQUIREMENTS
Prespike Standard: USD-C, USD-S
Prespike Amount..: 4.Ong
REPORTING REQUIREMENTS-
Reporting Format: Report Option II
See MILES for Instructions/Communications.
Completed by: DATE:
Reviewed by: / DATE: ^^<4- (PMGT0197)
18
-------
Date: 10/01/97
Time: 19:49
Sample
H crd TLI_Number.. Customer.Sample.Id
000 TLI Blank TLI M23 Blank
001 165-5-1A-D M23 THERMAL INLET RUNfll
002 185-S-2A-D M23 THERMAL INLET RUNH2
003 185-5-3A-D M23 THERMAL INLET RUNH3
004 185-5-4A-D M23 THERMAL INLET FB2
005 185-5-6A-D M23 THERMAL OUTLET RUNfll
006 185-5-7A-D M23 THERMAL OUTLET RUNK2
007 185-S-8A-D M23 THERMAL OUTLET RUN»3
008 18S-S-9A-D M23 THERMAL OUTLET FBI
009 185-S-10A-D M23 THERMAL OUTLET RBI
010 TLI LCS TLI LCS
Oil TLI LCSD TLI LCSD
*•• End of Report **•
1
RUNM1
RUNH2
RUNS 3
FB2
r RUNIII
r RUN (t 2
r RUNH3
r FBI
r RBI
F.
No
0
1
1
1
1
1
1
1
1
1
0
0
XAU
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
HHITE
WHITE
WHITE
WHITE
HHITE
TRIANGLE LABORATORIES, INC.
Wet Lab MM5/PUF Observations
Project: 43431
Filter Glass Wool PUF
. Color. . , . Color Color Odor
WHITE/GRAY
WHT/LT.BRN
WHT/LT.BRN
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
HHITE
WHITE
WHITE
WHITE
WHITE
WHITE
NONE
PETROLEUM
PETROLEUM
PETROLEUM
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
Air
Q.No.
03916
03916
03916
03916
03916
03916
03916
03916
03916
03916
Entered. By. .
ADKINS
ADKINS
ADKINS
ADKINS
ADKINS
ADKINS
ADKINS
ADKINS
ADKINS
ADKINS
ADKINS
ADKINS
.... Date .
10/01
10/01
10/01
10/01
10/01
10/01
10/01
10/01
10/01
10/01
10/01
10/01
19
19
19
19
19
19
19
19
19
19
19
PRDl'KRC v4 . 00
Page : 1
. Time. . . . S
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TRIANGLE LABORATORIES OF RTF, INC.
PROJECT COMMUNICATION TRACKING FORM
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PROJECT COMMUNICATfON TRACKING FORM
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handling -this project. Decisions, corrective actions and recommendations must also appear on this
tracking document _:_
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.-Name
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TRIANGLE LABORATORIES OF RTF, INC.
PROJECT COMMUNICATFON TRACKING FORM
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' i . £/f ft/tjV9-
I
-------
TRIANGLE LABORATORIES OF RTF, INC.
PROJECT COMMUNICATION TRACKING FORM
page _j[ot 6
TL! Project Number: 4 3LI3
Use this form to record-all exchanges of information between production units as well as personnel
handling -this project. Decisions, corrective actions and recommendations must also appear on this
• ' tracking document
K
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'
.-Name
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ERG02-Eastern Research Group
USI-19=M23 T. OUTLET RB1
Rr-c^jeot:. : 4-34-3 1
/ Observation
~%h^o £W
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1©5 — 5— 10D
ERG02-Eastern Research Group
USI-19=M23 T. OUTLET RB1
Rr-o.jjeo-t : 4-34-3 1
1 ©5—5—1 OC
ERG02— Eastern Re^parrh firnun
USI-19=M23 T. OUTLET RB1
R Y~ r~> ~i ^^ r~" "t~ - >i *a >i *a -i
1 ©5—5—1 OA
ERG02-Eastern Research Group
USI-19=M23 T. OUTLET RB1
Rr~o>.J©ot : 4-34-31
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-------
Project: 43431
TRIANGLE LABORATORIES, INC. PAGE 1 OF :
Dioxin Sanrple Preparation Tracking & Management Form
Client: Eastern Research Group (ERG02I
1 Solvent (s) /Acid (s) : /tf/W/lfi / ^n^t-lz. / Jflsl.-B^atvsi
1 Lot Numbers: 5 7¥ %& j 1 ^73*f3o / ^70 7^^
1 IS Spike: 40 Hi cone: 0.1000 ng/Ml
I SS Spike: «1 cone: . nq/ul
1 MS Spike: 0 fil cone: 0.0000 ng/Ml
I LCS Spike: 0 M! cone: 0.0000 ng/^1
| OPR Spike: 20 M! cone : _0.01 ng/Ml
Method: Method 23 :Tetra-Octa (Tol Combined) Matrix: XAT7
Extraction Date: l" / 1 /"' t^.^,^. '''
^d/
^ 1
1 /jf 1 A ^^^S— JMT 1 Chemist
1 5VO/& 1 5233T?/I 'ij'.^inH- 1 ^ ISoike ft
1 U5f \ \ v/5P »V 1 OSP-A I • » ID
| _7 / £A/^ | VLi M/f&i J / ^ /& | _/_/_! •• E>
.. it i i / ^J i Ib i A / fQ. i /«./•» XV Y P / / in^.
1 1 TLI / | GROSS | SAMPLE | f$_ . _/£" | /. | ^ CO I • | " Ta
|S#.crd| SAMPLE / CLIENT | HEIGHT | SIZE 1 &• \ nq/Ml 1 0&\ ng/«l 1 D.l ng/Ml 1 ne»/ul i " Cc
1 | ID / SAMPLE ID | Before After | g
I | TLI Blank | | |
|000 | TLI M23 Blank | ^ ~-| |
I | 185-5-1A-D 1 . 1 1
|001 | M23 THERMAL INLET RUNS1 | «— -f 1
| | 185-S-2A-D | | |
|002 | M23 THERMAL INLET RDN82 | ^___J_ — |
| | 18S-S-3A-D | | | ,
|003 1 M23 THERMAL INLET RUN#3 | ^^\ |
1 | 185-5-4A-D | | |
|004 | M23 THERMAL INLET FB2 | ^-"T |
| | 18S-S-6A-D | | |
| DOS | M23 THERMAL ODTLET RDN#1 | l___— |
| | 185-5-7A-D | | |
|006 | M23 THERMAL ODTLET RON#2 | J- |
| | 185-5-8A-D | | ^^^ \
|007 | M23 THERMAL ODTLET RDN#3 | ^^^ \
\ \ 18S-5-9A-D | l^--— |
|008 | M23 THERMAL ODTLET FBI | ^\ \
\ | 18S-S-10A-D | |^ |
|009 | M23 THERMAL ODTLET RBI | ^x-*T |
^>ir
ite
me |
>nc.
1 ml 1 10 Ml 1 / 1 0 Bl 1 'V & Ml ! Ml " Vol .
/*T£\. ^
1 f , 1 1 1 lAnyll
1 1 1 ^ , - 1 lAny
1^1 1 C K. ' ! *«
I.I 1 1 |Any 1
1 v?^1]/ I | (\ k I 1 yes
1 1 1 A • ' |Any
1^1 i Ct i i ^
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1 v/O /I 1 I L I 1 yes ,
II 1 1 1 lAny :
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no i
no |
eft|
no |
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10 !
ft|
10 i
10 h
Gross weight of sample container + sample before/after aliquot removal.
Comments:
Initials
: LA Date: &j
Initials of both SPIKER AND OBSERVER must be entered.
XXXXX • Gross Weight not provided for HATER Samples. |
REV 05/27/97 (PSTMF 7)--*
25
-------
reject: 43431
TRIANGLE LABORATORIES, INC. PAGE 2 OF 2
Dioxin Sample Preparation Tracking & Management Form
Client: Eastern Research Group (ERG02)
3lver.t(s)/Acid(s) :
Nuriers:
/
/ fl\t>4Vi6.yi ^ Method: Method 23:Tetra-Octa (Tol Combined) Matrix:
/ ^767&H Extraction Date: V / I / 1*
IS Spike: 40 pi cone: 0.1000
SS Spike: M! cone: .
MS Spike: 0 fil cone: 0.0000
tCS Spike: 0 nl cone: 0.0000 ng/fil
OPR Spike: 20 fil cone: _0.01
J.
] TLI / I GROSS | SAMPLE I II l$_ \ _H • /J" | | •
tf.crd! SAMPLE / CLIENT | WEIGHT | SIZE | O- ] net/ul \ O-O{ na/ul \ O. ' nq/ul | ng/jil
i ID / SAMPLE ID | Before After | g / ml | *f i) ill \ V£> jil \ ft) pi | nl
(Chemist
(Spike *
• ID
• Expir
• Date
" Time
" Cone.
• Vol.
TLI LCS
.HO
TLI LCS
(Any Left
^
TLI LCSD
111
TLI LCSD
lAny^Leftj^
\
(Any Left)
| yes/no i
(Any Left[
| yes/no |
(Any Left!
| yes/no |
(Any Left!
| yes/no {
|Any Left|
| yes/no |
(Any Leftf
| yes /no f
(Any Left)
| yes/no \
1
1
1
(Any Lef=l
| yes /no 1
oss weight of sample container + sample before/after aliquot removal.
tomments :
1
Initials :
Date:
— I
XXXXX - Gross Height not provided for WATER Samples. |
- REV 05/27/97 (PSTMF 7)- —
?6
"itials of both SPIKER AND OBSERVER must be entered.
-------
PAGE 1 OF :
TRIANGLE LABORATORIES, INC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
TLI Project No.: 43431
Ixt S#.crd and ,
ni Number | ]
!JL!^-M^———
Enter the procedure number below into the box at the top of each column to signify the step performed.
Initial and date each sample for each numbered procedure performed.
PROCEDURE
EXTRACTION
IPIKE AFTER EXTRACTION
'ADD TRIDECANE /f-"5£>
•OVAP 40mL
5) COMBINE
DIVIDE / LIPID DETERMINATION 20%/80*
SOLVENT EXCHANGE
Jar / Sep Funnel / Steam Dist / Cent LL / ASE / Waste Dilution]
I
TRANSFER fcSp-ilZ Y • 2.
10) ADDITIONAL CLEANUP
11) FINAL TRANSFER
5mL/20mL Other
DSP 225 / DSP 115 / DSP 215 • / DSP 267 / Other
Mod. DSP 260 / DSP 225 / DSP US / DSP 215 / DSP 267 / Other
; Comments:s
•Rev 06/24/97 (PSTMF 4)==+
27
-------
PAGE 2 OF 2
TRIANGLE LABORATORIES, INC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
TLI Project No.. 43431
I] Ext S#.crd and
I TLI Number
Enter the procedure number below into the box at the top of each column to signify the step performed.
Initial and date each sample for each numbered procedure performed.
PROCEDURE DETAILS (circle) [
EXTRACTION ONj^OFF__<§oxhle£ / Jar / Sep Funnel / Steam Dist / Cont LL / ASE / Waste Dilution I
SPIKE AFTER EXTRACTION /*///*?• /*(2/^£==
?8
-------
PAGE 1 OF 1
r— — — — — — — — — — — _ — _ — _ _ _ _ — — ___ __ — 1
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 43431
Transfer From: DWLH5 To: DMS5
Tni 1-i al s . . Dat-p> Time. . .
Released by
Accepted by
MILES . ID
43431-
43431-
43431-
43431-
43431-
43431-
43431-
43431-
43431-
43431-
43431-
43431-
-000
-001
-002
-003
-004
-005
-006
-007
-008
-009
-010
-Oil
_.?/ i-
^-
: Ml
TLI No. .
TLI Blank
185-5-1A-D
185-5-2A-D
185-5-3A-D
185-5-4A-D
185-5-6A-D
185-5-7A-D
185-5-8A-D
185-5-9A-D
185-5-10A-D
TLI LCS
TLI LCSD
•
lo/
-if/
Cust
TLI
M23
M23
M23
M23
M23
M23
M23
M23
M23
TLI
TLI
i_
Co/S7 ^:[5J_
10 /}Y JLl : ^o
Id
M23 Blank
THERMAL INLET RUN#1
THERMAL INLET RUN#2
THERMAL INLET RUN#3
THERMAL INLET FB2
THERMAL OUTLET RUN#1
THERMAL OUTLET RUN#2
THERMAL OUTLET RUN#3
THERMAL OUTLET FBI
THERMAL OUTLET RBI
LCS
LCSD
Y-F-rrnr (TJO-V i n /nn /Q4.1 --d.
Additional comments or instructions:
?9
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
Method: Method 23 :Tetra-Octa (Tol Combined) HR GC.'XSMS ANALYSIS
Required Detection Limit : 0 . 05 ng
\
r
| PROJECT: 43431 [
SAMPLZ INFORMATION RS Cone 5
1ST COLUMN 2ND COLUMN 20 /il ® 100.0 PG/^l f
| TLI / I GC/MS FILENAME [CONFIRM [CONFIRM FILENAME [USF-RS \9 3 |DSF-RSf9q ANALYSIS [
|S#.crd| SAMPLE ID / CLIENT | COLUMN: ~"TV;^*^}\ f / | | ;
008 | M23 THERMAL OUTLET FBI | | '\jf | •*=&• ' |
| 18S-S-10A-D | 2^'b~3~vty lAS'\ 1
009 j M23 THERMAL OUTLET RBI | | /J /J \ *" ' ' |
1 TLI LCS | | . | |
010 | TLI LCS | <-> —), "7y7l K/ 1 -*_ 1
J (. /<** ' ' v
| TLI LCSD | | / i _|
Oil | TLI LCSD | ^2s*7/ 7^"? 1 ^\_/ 1 ~ 1
( \\ \ I
[ . .
L..L. ! _!
, .
1 I ' . ....:
, i ,
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fill i
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1 ; 1 1
1 1 !
1 1 I
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1 ' 1 I
1 1 I
1 1 f
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1 1 1
, ' 1 ' '
I I I
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Comments : ' ^ Type : SL~ ^*"|*W? ^|
*"/*?£ 3 /&ji-s*/'f-3 T~ft^~ y**0^ "d-erfc-Te-y ff*^ ftf ez.
<**
M«=> [o/f
-------
Triangle Laboratories, Inc.
Run Log
instrument ID
Column Tye
Column ID
Plot Name
Acquisition
G/C
/*/>&•?
-------
Triangle Laboratories, Inc.
Run Log
Instrument ID
Column Type
Column ID
Plot Name
Acquisition
G/C
Signature
Date
Filename
Date*
Time-
Project #
Sampled
No.
Client Sample ID
Syr
332
Operator/Dale
Comments
66
T-y
nvti
ef
Pi it, hi
3
7Z/
t •/*/*)
I/
££r:
V-J
•f 5"
c?
r*
f6
#
Y
*
**
Transcribed from chromatographic data
Dated initials required
ConCal Due:
ConCal Due:
\\'ti\
srvrtfql/formsftiiTunlog doc (02/05/97)
Pago
-------
Triangle Laboratories, Inc.
Run Log
Instalment ID
Column Type
CglumnJD
Plot Name
In. Vol.
Acquisition
Signature
QIC
Date
Filename
Dale* | Time*
Project #
Sample*
No.
Client Sample ID
Syr
332
Operalor/Dale
Comments*
16 f.
V
5-0^76"
-^-^ -p
H
M2'i
f
TU
* Transcribed from chromatographic data
** Dated initials required
srvrl/toorms/hrrunlog.doc (02/05/97)
CO
ConCal Due:
ConCalDue:
Page:
-------
SAMPLE
DATA
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax * 919*44-5491
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 43431
Method 8290X Full Screen Analyses (DB-5)
Page 1
10/21/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
S976745
TLI M23 Blank
ng
10/01/97
10/16/97
S
XAD
S976746
M23 THERMAL INL
ET RUN#1
ng
10/01/97
10/16/97
S
M23TRAIN
S976747
M23 THERMAL INL
ET RUN#2
ng
10/01/97
10/16/97
S
M23TRAIN
S976748
M23 THERMAL INL
ET RUNS3
ng
10/01/97
10/16/97
S
M23TRAIN
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
(0.008)
(0.01)
(0.01)
(0.01)
(0.01)
(0.01)
(0.02)
(0.006)
(0.008)
(0.008)
(0.008)
(0.006)
(0.008)
(0.009)
(0.01)
(0.01)
(0.02)
(0.008)
(0.01)
(0.01)
(0.01)
(0.006)
(0.008)
(0.007)
(0.01)
(0.006)
(0.01)
(0.01)
(0.01)
(0.01)
(0.01)
0.02
(0.004)
(0.008)
(0.008)
(0.008)
(0.006)
{0.01}
(0.008)
(0.01)
(0.01)
(0.02)
(0.006)
(0.01)
(0.01)
(0.01)
(0.004)
(0.008)
{0.01}
(0.01)
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 104 104
13C12-PeCDF 234 91.9 86.2
81.
13C12-HxCDF 478 81.3
13C12-HxCDD 478 74.9
13C12-HpCDF 789 92.0
93.7
89.1
104
Other Standards Percent Recovery Summary (% Rec)
13C12-HxCDF 789 90.0 99.3
13C12-HXCDF 234 99.1 104
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 74.6 108
13C12-2378-TCDD 65.7 92.9
13 C12-PeCDF 123 72.1 78.2
13C12-PeCDD 123 71.0 74.0
(0.005)
(0.009)
(0.01)
(0.008)
(0.008)
(0.01)
(0.02)
(0.003)
(0.005)
(0.005)
(0.006)
(0.004)
(0.006)
(0.006)
(0.007)
(0.01)
(0.01)
0.01
(0.009)
(0.009)
(0.01)
(0.003)
(0.005)
(0.005)
(0.008)
98.4
85.7
.91.8
87.2
97.8
87.4
96.5
99.4
90.6
79.2
77.0
(0.005)
(0.01)
(0.01)
(0.008)
(0.009)
(0.01)
(0.02)
(0.003)
(0.006)
(0.006)
(0.006)
(0.005)
(0.006)
(0.007)
(0.008)
(0.01)
(0.01)
{0.006}
(0.01)
(0.009)
(0.01)
(0.003)
(0.006)
(0.006)
(0.009)
106
86.6
92.9
86.7
97.9
94.1
103
104
87.2
76.9
73.0
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:19,10*21/97
3D
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 43431
Method 8290X Full Screen Analyses (DB-5)
Page 2
10/21/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
S976745
TLI M23 Blank
ng
10/01/97
10/16/97
S
XAD
S976746
M23 THERMAL INL
ET RON#1
ng
10/01/97
10/16/97
S
M23TRAIN
S976747
M23 THERMAL INL
ET RUN#2
ng
10/01/97
10/16/97
S
M23TRAIN
S976748
M23 THERMAL INL
ET RUN*3
ng
10/01/97
10/16/97
S
M2 3TRAIN
Internal Standards Percent Recovery Summary (% Rec)
13C12-HxCDF 678 99.3
13C12-HxCDD 678 97.1
13C12-HpCDF 678 81.5
13C12-HpCDD 678 99.8
13C12-OCDD 93.0
105
96.1
89.2
100
88.5
97.0
91.5
84.9
97.1
93.9
104
96.1
85.5
95.0
84.3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:1910/jgl 797
-------
Data File
Sample ID
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project
Method 8290X Full Screen Analyses
S976749 S976750
43431
(DB-5)
S976757
M23 THERMAL INL M23 THERMAL OUT M23 THERMAL OUT
ET FB2 LET RDNfl LET RUN#2
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
Other Standards
37C1-TCDD
13C12 -PeCDF 234
13C12-HxCDF 478
13C12-HxCDD 478
13C12-HpCDF 789
Other Standards
13C12-HXCDF 789
13C12-HxCDF 234
ng ng
10/01/97 10/01/97
10/16/97 10/16/97
S S
M23TRAIN M23TRAIN
(0.005) 0.009
(0.007) (0.008)
(0.009) (0.01)
(0.007) (0.008)
(0.007) (0.008)
(0.01) (0.01)
(0.01) {0.07}
(0.003) (0.004)
(0.005) (0.005)
(0.005) (0.005)
(0.005) (0.006)
(0.004) (0.004)
(0.005) 0.01
(0.006) (0.006)
(0.007) (0.007)
(0.009) (0.01)
(0.01) (0.01)
(0.005) 0.009
(0.007) (0.008)
(0.008) (0.008)
(0.01) (0.01)
(0.003) {0.009}
(0.005) (0.005)
(0.005) 0.01
(0.008) (0.008)
Percent Recovery Summary (% Rec)
97.4 95.2
89.3 94.4
80.2 79.3
80.7 77-. 6
94.7 90.5
Percent Recovery Summary (% Rec)
82.9 79.9
92.9 86.8
ng
10/01/97
10/16/97
S
M23TRAIN
(0.009)
(0.01)
(0.01)
(0.01)
(0.01)
0.02
(0.02)
(0.006)
(0.009)
(0.009)
(0.008)
(0.006)
(0.008)
(0.01)
(0.01)
(0.02)
(0.02)
(0.009)
(0.01)
(0.01)
0.05
(0.006)
(0.009)
(0.008)
(0.01)
98.0
91.7
78.9
70.5
92.5
85.1
93.9
Page 3
10/21/97
S976758
M23 THERMAL OUT
LET RUN#3
ng
10/01/97
10/16/97
S
M23TRAIN
(0.01)
(0.02)
(0.02)
(0.02)
(0.02)
(0.02)
{0.03}
(0.009)
(0.01)
(0.01)
(0.01)
(0.01)
(0.01)
(0.01)
(0.02)
(0.02)
(0.02)
(0.01)
(0.02)
(0.02)
(0.02)
(0.009)
(0.01)
(0.01)
(0.02)
97.3
96.2
75.5
72.6
90.0
60.4
69.3
Internal Standards Percent Recovery Summary (% Rec)
13C12 -2378-TCDF
13C12-2378-TCDD
13C12-PeCDF 123
13C12-PeCDD 123
81.7 78.1
75.3 74.2
76.4 70.4
78.4 72.1
87.8
81.7
81.5
82.3
58.1
53.0
49.7
50.7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:^9^/21/97
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 43431
Method 829OX Full Screen Analyses (DB-5)
Page 4
10/21/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
S976749
M23 THERMAL
ET FB2
ng
10/01/97
10/16/97
S
M23TRAIN
INL
S976750
M23 THERMAL OUT
LET RUNfl
ng
10/01/97
10/16/97
S
M23TRAIN
S976757
M23 THERMAL OUT
LET RUNf2
ng
10/01/97
10/16/97
S
M23TRAIN
S976758
M23 THERMAL OUT
LET RUN#3
ng
10/01/97
10/16/97
S
M23TRAIN
Internal Standards Percent Recovery Summary (% Rec)
13C12-HXCDF 678 97.7 94.1 101
13C12-HXCDD 678 89.2 88.3 103
13012-HpCDF 678 75.4 76.7 75.2
13C12-HpCDD 678 90.1 88.5 94.5
13C12-OCDD 90.7 95.1 95.8
76.7
74.0
57.0
66.6
70.2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:19 10/21/97
Ul 38
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 43431
Method 8290X Full Screen Analyses (DB-5)
Page 5
10/21/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
S976759
M23 THERMAL OUT
LET FBI
ng
10/01/97
10/16/97
S
M23TRAIN
S976760
M23 THERMAL OUT
LET RBI
ng
10/01/97
10/16/97
S
M23TRAIN
S976761
Cleanup Blk
ng
10/01/97
10/17/97
S
XAD
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
(0.009)
(0.01)
(0.01)
(0.01)
(0.01)
(0.01)
{0.01}
(0.006)
(0.009)
(0.009)'
(0.008)
(0.006)
(0.008)
(0.008)
(0.01)
(0.01)
(0.01)
0.01
(0.01)
(0.01)
(0.01)
(0.006)
(0.009)
(0.007)
(0.01)
(0.006)
(0.009)
(0.009)
(0.007)
(0.008)
(0.01)
(0.02)
(0.004)
(0.006)
(0.006)
(0.006)
(0.004)
(0.005)
(0.006)
(0.008)
(0.01)
(0.01)
(0.006)
(0.009)
(0.008)
(0.01)
(0.004)
(0.006)
(0.005)
(0.01)
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 97.9 95.7
13C12-PeCDF 234 95.0 96.9
76.4 77.7
71.9 74.5
86.2 93.2
13C12-HXCDF 478
13C12-HxCDD 478
13C12-HpCDF 789
Other Standards Percent Recovery Summary (% Rec)
13C12-HxCDF 789 65.5 58.7
13C12-HxCDF 234 72.6 65.6
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 58.7 55.8
13C12-2378-TCDD 54.4 52.8
13C12-PeCDF 123 54.9 50.4
13C12-PeCDD 123 56.8 55.0
(0.002)
(0.003)
(0.004)
(0.003)
(0.003)
(0.004)
(0.007)
(0.001)
(0.002)
(0.002)
(0.002)
(0.002)
{0.006}
(0.003)
(0.003)
(0.004)
(0.005)
(0.002)
(0.003)
(0.003)
(0.004)
(0.001)
(0.002)
{0.006}
(0.003)
78.6
81.5
71.1
70.0
66.1
62.0
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:19 10^1/97
O o
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 43431
Method 8290X Full Screen Analyses (DB-5)
Page 6
10/21/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
S976759
M23 THERMAL OUT
LET FBI
ng
10/01/97
10/16/97
S
M23TRAIN
S976760
M23 THERMAL OUT
LET RBI
ng
10/01/97
10/16/97
S
M23TRAIN
S976761
Cleanup Blk
ng
10/01/97
10/17/97
S
XAD
Extraction Type
Internal Standards Percent Recovery Summary (% Rec)
:CDF 678
:CDD 678
'CDF 678
CDD 678
DD
78.8
76.9
60.9
73.5
77.1
68.5
67.3
49.7
63.2
60.9
80.5
77.0
73.9
75.0
72.6
13C12-OCDD
{Estimated Maximum Possible Concentration), (Detection Limit).
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:19 10121/97
-------
TLl Project: 43431
Client Sample: TLI M23 Blank
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S976745
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Asphalt Roofing Project
XAD Date Received:
TLI Blank Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst
//
10/01/97
10/16/97
n/a
S976745
BJG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976737
n/a
n/a
n/a
Afta*yt*»;>^ *
2,3,7,8-TCDD
U,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2^,7,8-TCDF
1,2,3,7,8-PeCDF
2^,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
U,3,6,7,8-HxCDF
23,4,6.7,8,HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
10,3,4,7,8,9-HpCDF
1^,3,4,6,7,8,9-OCDF
^Wato^V^'^'
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
yc ;^;CA^CHS
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Amii(i>i
ND
ND
ND
ND
ND
ND
ND
ND
^ - ;rot^ ;;t*e»pe :; ;^::4,f*
0.008
0.01
0.01
0.01
0.01
0.01
0.02
0.006
0.008
0.008
0.008
0.006
0.008
0.009
0.01
0.01
0.02
^fcarabee iftffcafec ~ " - ; "-' ">-*«
0.008
0.01
0.01
0.01
0.006
0.008
0.007
0.01
$»* «*r*$t" :;;/¥ia^
—
—
Ffe^s
—
Page 1 of2
X237 J>SR V2.0Q. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:03 10/20/97
-------
TLI Project: 43431
Client Sample: TLI M23 Blank
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S976745
Internal Standards
3C,:-i3,7,8-TCDF
13Ci2-2,3,7,8-TCDD
13Ci2-l,23,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
>3C,2-U,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
'3Ci2-l,2,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
»CL-2A7,8-TCDD
I3C,2-2,3,4,7,8-PeCDF
I3C,2-1.2,3,4,7,8-HxCDF
13Ci2- 1,2^,4,7,8-HxCDD
13C,2-l,2J,4,7,8,9-HpCDF
JMtemalB Standards (Typft A) -•-
I3C,2-l,2^,7,8,9-HxCDF
13Ci2-2,3,4,6,7,8-HxCDF
Recovery Standards r^** "~,
13C,2-1,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
'Arot (ng)
3.0
2.6
2.9
2.8
4.0
3.9
3.3
4.0
7.4
amftwfc; -
4.2
3.7
3.3
3.0
3.7
Arot (ng) v""
3.6
4.0
,?*?>£,-, .:' "
-'"'' % Recovery
74.6
65.7
72.1
71.0
99.3
97.1
81.5
99.8
93.0
s~pt$fam*jr
104
91.9
81.3
74.9
92.0
s$&% Recovery
90.0
99.1
*'*: .
QC Limits
40%-130%
40%- 130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
QC Limits
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
QCLtmtts
40%-130%
40%-130%
X' f
/ Ratio
0.74
0.82
1.42
1.41
0.49
1.26
0.42
1.00
0.87
Ralte ?,
•X
1.47
0.49
1.21
039
Ratio
0.49
0.49
Ratio,
0.82
1.18
_RT_
20:23
21:10
24:42
25:49
28:28
29:11
31:11
32:04
34:33
£'*? '
21:12
25:27
28:22
29:06
32:25
HT - ''
29:43
28:59
,«T, :
20:58
29:29
Flags
_
.
_
_,.„,-
—
Flags
—
'Flags ol
—
Flags
Data Reviewer
10/20/97
Page 2 of2
X237.PSR V2.00. LARS 6.10.0*
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:03
-------
Initial ....Date...
Data Review By:
|U/ / 1 calculated Noise Area: 0.44
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated- according to method requirements.
Page No.
10/20/97
Listing of S97674SB.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why .-RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.
ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
DC
DC
d
DC
DC
DC
DC
NL
SN
SN
SN
WH
0
NL
WL
2
0:
19:
19:
21:
22:
00
39
53
38
36
0.
RO
RO
RO
RO
RO
65-0.89
0.
2.
0.
0.
0.
95
11
61
61
62
Peaks
0:
19:
20:
20:
00
13
23
55
0.
RO
RO
0
0
1
0
0
0
.65
.48
.47
.51
.87
.00
65-0.89
0.
0.
0.
0.
33
58 •
74
66
Peaks
0
10
622
7
630
'A . TV*TY
.34
.14
.51
.78
.29
p 1 Tfrt
0.825-1.102
0
0
0
1
1
.000
.964
.975
.061
.109
0.951-1.049
0
0
265.01. 357.50 1
3.10 4.68 1
.000
.943
.000 13C12-2378-TCDF ISO
.026
TCDD
320-322
320-322
0.65-0.89
DC NL 0:00 RO 1.09
DC SN 20:36 RO 1.92
DC SN 21:11 RO 0.93
DC SN 21:22 RO 7.50
0 Peaks
0.58
0.44
0.53
0.07
0.00
0.856-1.059
0.000
0.973
1.001 2378-TCDD
1.009
AN
37C1-TCDD
328 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:00
18:11
18:36
18:54
19:35
19:53
20:08
20:27
20:35
21:12
21:29
21:47
21:47
21:56
22:11
22:19
22:23
22:33
22:39
0.38
0.49
0.43
0.40
1.61
0.29
0.35
0.36
0.34
389.33
5.59
0.80
0.33
0.38
0.52
0.69
0.15
0.25
0.22
1.61
389.33
5.59
0.80
0.69
0.906-1.094
0.000
0.859
0.879
0.893
0.925
0.939
0.951
0.966
0.972
1.002 37C1-TCDD
1.015
1.029
1.029
1.036
1.048
1.054
1.057
1.065
1.070
SUR1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:0410/20/97
-------
page No. 2
10/20/97
compound/
M_Z QC.Log
J
1328
13C12-TCDD
332-334
332-334
iPeCDF
040-342
:
i
340-342
13C12-PeCDF
352-354
1
"j
S52-354
i
feCDD
356-358
4
Listing
Matched
Omit
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
Why
SN
5
NL
WL
WL
SN
6
NL
SN
SN
SN
SN
SN
SN
WH
0
NL
SN
7
NL
SN
SN
SN
SN
SN
SN
SN
. .RT.
22:53
Peaks
0:00
18:31
18:41
19:46
19:53
20:58
21:10
21:33
21:51
22:07
Peaks
0:00
22:33
23:48
24:11
24:51
25:00
25:27
26:45
Peaks
0:00
22:28
23:48
24:22
24:42
25:02
25:05
25:27
25:42
Peaks
0:00
23:53
24:32
24:42
25:00
25:23
25:40
25:48
OK
0
RO
RO
RO
RO
RO
RO
RO
1
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
of S976745B.
dbf
GC Peaks / Ratio / Ret. Time
Ratio Total.
.65-0.89
2.20
1.69
1.67
1.04
0.55
0.82
0.82
0.80
0.64
0.44
1
32-1.78
0.72
2.35
0.59
1.27
0.19
1.24
1.09
0.84
32-1.78
0.92
0.47
1.49
1.83
1.42
2.06
2.39
1.47
1.58
1,
32-1.78
1.20
0.26
1.76
2.36
0.36
0.93
0.53
0.56
Area... Area. Peak. 1 . .
0.52
398.02
0.62
0.46
0.53
1.33 0.78
3.31 1.44
633.20 285.72
443.66 200.06
13.67 6.07
2.71 1.18
0.71
,097.88
TV nn / P*ȣ*TO7 T?ol 1 AUTC
L\rlJLJ I CV^lJS s OA AOW5
0.38
0.43
0.76
0.69
0.18
0.76
0.95
0.35
0.00
0.20
0.44
16.12 9.65
2.98 2.14
517.58 303.74
5.23 4.22
1.43 1.34
461.43 274.87
4.10 2.51
008.87
0.20
0.28
0.47
0.28
0.26
0.44
0.53
0.23
Area . Peak . 2 . . Rel.RT Confound . Name . . ID.. Flags
1.081
0.906-1.094
0.000
0.875
0.883
0.75 0.934
2.63 0.939
347.48 0.991 13C12-1234-TCDD RSI
243.60 1.000 13C12-2378-TCDD IS1
7.60 1.018
1.83 1.032
1.045
0.907-1.080
0.000
0.913
0.964
0.979
1.006
1.012
1.030 23478-PeCDF AN
1.083
0.838-1.162
0.000
0.910
6.47 0.964
1.17 0.987
213.84 1.000 13C12-PeCDF 123 IS2
2.05 1.013
0.56 1.016
186.56 1.030 13C12-PeCDF 234 SUR2
1.59 1.040
0.921-1.026
0.000
0.925
0.950
0.957
0.968
0.983
0.994
0.999
riangle Laboratories, Inc.® Analytical Services Division
pi Capitola Drive • Durham, North Carolina 27713
ane: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:041
-------
Page No.
10/20/97
Listing of S976745B.dbf
Matched QC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Na
356-358
13C12-PeCDD
368-370
s.. ID. . Flags.
368-370
HxCDF
374-376
374-376
13C12-HXCDF
384-386
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
WH
0
ML
SN
SN
SN
SN
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
SN
26:21
26:38
Peaks
0:00
24:06
24:18
24:50
25:00
25:15
25:24
25:42
25:49
25:58
26:22
26:47
Peaks
0:00
27:20
27:23
27:42
27:45
27:50
28:21
28:31
28:37
28:40
28:46
28:50
28:58
29:06
29:19
29:29
29:33
29:37
29:48
Peaks
0:00
27:21
27:30
27:48
28:09
28:22
28:28
28:48
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
2
0
.33
.19
0
0
0
.31
.10
.00
32-1.78
1
1
1
2
2
1
1
1
1
1
0
1
.20
.22
.63
.16
.00
.25
.32
.00
.41
.44
.67
.00
05-1.43
2
1
1
2
1
1
1
4
3
0
2
1
1
2
1
0
0
0
0
.58
.33
.45
.00
.20
.94
.28
.50
.00
.76
.63
.11
.38
.00
.67
.35
.50
.50
.90
0
0
0
1
0
0
0
0
285
45
0
0
330
.20
.36
.63
.25
.18
.33
.44
.26
.41 167.18
.58 26.89
.71
.48
.99
1
1
.021
.032
0.845-1.155
0
0
0
0
0
0
0
0
118.23 1
18.69 1
1
1
.000
.934
.941
.962
.968
.978
.984
.995
.000 13C12-PCCDD 123
.006
.021
.037
IS3
PP CDP / HscC DP Po 1 1 ours
0
0
0
.27
.42
.25
0.22
0
0
1
0
0
0
0
0
1
0
0
0
0
0
0
0
.22
.36
.39
.18
.09
.29
.18
.19
.88
.27
.07
.13
.07
.22
.47
.00
43-0.59
0
0
0
1
0
0
0
0
.67
.62
.62
.57
.96
.49
.49
.26
0
2
6
0
0
361
464
0
.23
.94 . 1.20
.16 2.54
.35
.38
.75 118.69
.16 152.61
.71
0.956-1.053
0
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
.000
.960
.962
.973
.975
.978
.996 123478-HxCDF
.002
.005
.007
.011
.013
.018 234678-HXCDF
.022
.030
.036
.038
.040
.047
AN
AN
0.860-1.140
0
1.95 0
4.08 0
0
0
243.06 0
311.55 1
1
.000
.961
.966
.977
.989
.996 13C12-HXCDF 478
.000 13C12-HXCDF 678
.012
SDR:
IS4
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:0410/20/97
-------
Page No.
10/20/97
Listing of S976745B.db£
Matched GC Peaks / Ratio / Ret. Time
Confound/
M_Z QC.Log Omic Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..
ID.. flags.
384-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
8
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
NL
ML
WL
ML
VJL
SN
SN
SN
3
NL
SN
SN
SN
SN
HH
0
28:51
28:59
29:16
29:36
29:43
30:05
30:10
30:16
Peaks
0:00
27:49
27:59
28:07
28:15
28:21
28:28
28:35
28:50
29:11
29:30
29:37
29:44
Peaks
0:00
27:46
27:52
27:57
28:03
28:17
28:49
29:06
29:11
29:29
29:56
Peaks
0:00
31:14
31:26
31:46
31:57
33:00
Peaks
RO
RO
RO
RO
1
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
0.53
0.49
0.26
1.23
0.49
0.49
1.07
0.40
KVwtVl
.05-1.43
0.59
0.32
0.38
0.35
0.87
1.23
1.24
4.29
0.96
5.08
1.29
0.31
1.92
05-1.43
1.00
0.78
0.30
0.88
0.71
0.89
0.31
1.21
1.26
1.18
1.34
88-1.20
2.54
1.22
1.13
2.50
5.25
0.41
2.02 0.70
428.56 141.04
1.95 0.66
0.65
338.41 111.26
1.53
0.82
0.74
1,605.95
0.18
0.20
0.09
0.16
0.23
1.05
0.47
0.31
0.45
0.27
0.39
0.07
0.54
0.00
1.32 1.013
287. 52 1.018 13C12-HXCDF 234 ALT2
2.56 1.028
1
227.15 1
1
1
1
.040
.044 13C12-HXCUF 789
.057
.060
.063
ALT1
0.950-1.015
0
0
0
0
.000
.953
.959
.963
0.968
0.971
0.975
0.979
0.988
1.000 123678-HXCDD
1.011 123789-HxCDD
AN
AN
1.015
1.019
0.966-1.034
0.20
0.25
0.11
0.27
0.36
0.43
0.16
273.17 149.31
374.96 208.88
388.08 210.33
0.89
1.036.21
0.27
0.73
0.83
0.24
0.16
0.33
0.00
0.000
0.951
0.
0.
0.
0.
0..
123.86 0.
166.08 1.
177.75 1.
1.
955
958
961
969
987
997 13C12-HXCDD 478
000 13C12-HXCDD 678
010 13C12-HXCDD 789
026
SUR4
ISS
RS2
0.996-1.046
0.
1.
1.
1.
1.
1.
000
002 1234678-HpCDF AN
008
019
025
058
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:04 Jp/20/97
46
-------
Page No.
10/20/97
Listing of S976745B.db£
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OX Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
3
NL
SN
SN
SN
SN
SN
WH
0
NL
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:00
31:11
31:36
31:51
32:13
32:25
32:46
32:51
32:55
Peaks
0:00
31:25
31:30
31:42
31:52
32:08
32:36
Peaks
0:00
31:29
32:04
Peaks
0:00
31:12
31:17
31:54
32:06
32:16
32:35
33:12
33:18
33:26
33:34
33:46
34:11
34:15
34:24
34:53
35:14
35:29
35:38
0.
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
0.
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
37-0.51
0.
0.
3.
2.
0.
0.
0.
0.
0.
74
42
20
22
91
39
93
76
90
0
280
0
0
0
.50
.52
.14
.46
.62
198.96
0
0
0
480
Urh/*n
88-1.20
1.
4.
0.
1.
0.
1.
0.
08
00
92
88
39
97
74
0
0
0
0
0
.59
.49
.96
.44
V 1 Unf*
f / "P*-
.27
.22
.48
.33
.24
0.59
0.33
0
.00
88-1.20
1.
1.
1.
17
13
00
0
2
315
317
QV*S*T\
.S3
.15
.69
.84
n I /\»te
76-1.02
1.
1.
0.
0.
0.
1.
0.
0.
1.
0.
1.
0.
2.
1.
0.
0.
2.
0.
0.
50
42
26
60
97
29
89
97
41
65
63
86
11
55
28
30
19
98
39
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.19
.23
.13
.32
.63
.40
.36
.61
.32
.51
.15
.26
.17
.21
.17
0.40
0
0
0
.49
.79
.32
0.936-1.128
0
83.42 197.10 1
1
1
1
56.29 142.67 1
1
1
0.60 0.67 1
.000
.000 130.2-HpCDF 678 IS6
.013
.021
.033
.040 13C12-HpCDF 789 SUR5
.051
.053
.056
0.977-1.006
0
0
0
0
0
1
1
.000
.980
.982
.989
.994
.002
.017
0.969-1.031
0
1.14 1.01 0
158.12 157.57 1
.000
.982
.000 13C12-HpCDD 678 IS7
0.884-1.116
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
.000
.903
.905
.923
.929
.934
.943
.961
.964
.968
.972
.977
.989
.991
.996
.010
.020
.027
.031
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:04J«teO/97
-------
page No.
10/20/97
Listing of S976745B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.l.. Area.Peak.2.. Rel.RT Compound.Name.. ID.
Flags.
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
DC
DC
DC
DC
DC
SN 35:47
SN 35:57
0 Peaks
ML 0:00
SN 34:33
SN 34:42
SN 34 : 57
0 Peaks
NL 0:00
34:33
WH 35:01
1 Peak
RO 3 . 83
RO 0.64
0.76-1.02
0.89
0.82
RO 1 . 62
RO 0.29
0.76-1.02
0.80
0.87
0.87
0.11
0.45
0.00
0.17
0.69
0.40
0.19
0.00
0.18
374.44
2.37
374.44
173.76
1.036
1.041
0.884-1.116
0.000
1.000 OCDD AN
1.004
1.012
0.997-1.006
0.000
200.68 1.000 13C12-OCDD IS8
1.014
Column Description 'Why Code Description QC Log Desc.
M_Z -Nominal Ion Hass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report *•*
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
Tile:S976745 tl-829 Acq:16-OCT-1997 11:50:01 EI+ Voltage SIS 70S Hoiae:17S
303.9016 Fs2 BSUB(2S6,30, -3.0) PKD(9,S,S,0.05\,700.0,1.00\rTrT) Exp-.EPCOS
TRIANGLE LASS Text:TLI M23 BLANK TLH43431 HKT. TIME - 11:52
17:00 18:00 15:00 20:00 21:00
rilatS976745 tl-829 Aoq:16-OCT-1997 11:50:01 EI+ Voltage SIR 70S Noiae:183
305.8987 T:2 BSUS(256,30,-3.0) PKD(9,S,S,O.OS\,732.0,1.00\,T,T) Eip:EPOJS
TRIANGLE LASS Text.-HI M23 BLANK TLI*43431 HKT. TIME = 11:52
100
17:00 18:00 19:00 20:00 21:00
Tile:S976745 tl-829 Acq:16-OCT-1997 11:50:01 XX* Voltage SIX 70S Xoiae:76
315.9419 T:2 SSUS(2S6,30,-3.0) ,PXD(9,5,5,0.OS\,304.0,1.00\,T,T) Exp-.EPCUS
TRIANGLE LASS Text.:TLI K23 BLANK TLH43431 UKT. TIME - 11:52
22: 00
6.9E2
.O.OEO
Tine
22:00
1001
soj
60:
401
20J
A2.65E6
17:00 18:00 19:00 20:00 21:00
F±le:S97674S tl-829 Aoq:16-OCT-1997 11:50:01 EH- Voltage SIS 70S Noise:226
317.9389 T:2 SSUS(256,30,-3.0) PKD(9,S,5,0.05\,904 .0,1.00\,T,T) Ezp-.EPCUS
TRIANGLE LASS Text.-TLJ M23 BLANK TLIt43431 HKT. TIME - 11:52
A3.58E6
22: 00
ao
40:
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17:00 18:00 15:00
File:S976745 tl-829 Aoq:16-OCT-1997 11:50:01
330.9792 r:2 Ezp:EPCUS
TRIANGLE LASS Text:TLI M23 BLANK TLIt43431
100* 17:19 17:48 18:15 1814 5 19-06
80:
60:
40:
20:
20:00
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21:00
22: 00
OCT. TIME «
15:55 20:30
JX^VV-* »»*'^ «xv»~v
11:52
17:00 18:00 19:00 20:00 21:00
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375.8364 Tt2 ExptEPCUS
TRIANGLE LASS Tert-.TLI H23 BLANK TLH43431 OCT. TIME -
ion 19 10
22:00
11:52
ao:
fol
40:
20:
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18:46
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^^^
20:28
20:58
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Time
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9.6E5
O.OEO
Tine
49
-------
Tile:S97674S «1-B29 Acq:16-OCT-1997 11:50:01 EI+ Voltage SIS 70S Koi.BH-.181
319.8965 ri2 BSUB(2S6,30,-3.0) PKD(7,S,3,0.05%, 724. 0,1.00\,T,T) Elp:EPCUS
TRIANGLE LASS Text:01J H23 BLANK TLH43431 INJ. TIME " 11:52
100* . A5.62E3 A8.39E3
22:00
19,00 20:00 21:00
Tile:S976745 fl-829 Aoq:16-OCT-1997 11:50:01 EH- Voltage SIS 70S Soife:165
321.8936 F:2 BSVB(256,30r-3.0) tKD(7,S,3,0.05\,660.0r1.00\,r,T) Xrp:XTCUS
TRIANGLE LASS Text:TLI M23 BLANK TLH43431 ZWT. TIME = 11:52
22:00
19:00 20:00 21:00
rile:S976745 tl-829 Acq:16-OCT-1997 11:50:01 EI+ Voltage SIS 70S Boise:386
331.9368 T:2 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,1544.0,1.00\,r,T) Exp:EPCOS
TRIANGLE LASS Text .-HI M23 BLANK TLIf43431 ZK7. TIME =• 11:52
1003, A2.86E6
80.
40.
20.
ol
A2.00E6
22:00
19:00 20:00 21:00
r±l»:S976745 fl-829 Acq:16-OCX-1997 11:50:01 EI+ Voltaga SIS 70S Boiaa:174
333.9338 f:2 BSUB(2S6,30r-3.0) PKD<7,5,3,0.OS\,696.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Text.-HJ M23 BLANK TLH43431 IKT. TIME - 11:52
1004 A3.17X6
00:
50:
401
Oj
A2.44E6
22: 00
15:00 20:00 21:00
file:S976745 tl-829 Acq:16-OCT-1997 11:50:01 EH- Voltage SIS 70S Soiae:190
327.8847 f:2 BSOB(2S6,30,-3.0) fKD(7,S,3,0.05\,760.0,1.00\,r,T) ExpsEPCUS
TSIANGLE LABS Text: IEJ M23 BLANK XLH43431 UU. TIME • 11:52
100]
80:
40:
20:
OJ
A3.89E6
19:00 20:00 21:00
rile:S97674S fl-829 Acq:16-OCT-1997 11:50:01 EI+ Voltage SIS 70S
30.9792 r:2 Exp:EPCOS
TRIANGLE LABS T«xt.-TU M23 BLANK TLH43431 XK7. TIME
OOi
80:
601
40:
20:
ol
10:45
19 > 06
^•Ml* •^'a%»
15:55 20:13 20:30
22:00
11:52
19i00'
.20:00'
21:00
22: 00
.O.OEO
Time
7.2E5
15.8E5
'•.4.3E5
•.2.9E5
-1.4E5
O.OEO
Time
8.6E5
ls.9E5
.5.2E5
.3.4E5
.1.7E5
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Time
-8.8E5
.7.0ES
-S.3ES
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Time
.4.8E6
.3.8S6
.2.9E6
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-------
File:S976745 tl-829 Acg:16-OCT-1997 11:50:01 EH- Voltage SIX 70S NOiae:114
339.8597 F:2 BSUB(256,30,-3 .0) PKD(7,5,3,O.OS\,4S6.0,1.00\,r,X) ExpsEPCUS
TRIANGLE LABS Text: TIT M23 BLANK TLIt43431 1ST. TIME - 11:52
ion
80:
60:
40:
20:
)
o:
A5.85E3
A4.19E3 ^ 61E3 A5.79E3 1 1 A2.84E3
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rile:S976745 tl-829 Acg:16-OCT-1997 11:50:01 EI+ Voltage SIX 70S Noise: 160
341.8567 T:2 BSVB(256,30,-3.0) PXD( 7,5,3,0. 05%,540. 0,1. 00\,T,T) ExpiEPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLIf43431 HKT. TIME - 11:52
1001
80:
50:
I
40:
20:
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A7.93E3
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a* ^1-7 *2'80E3 A7.83E3 Ifl A3. 7213
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T±le:S976745 tl-829 Aoqsl6-OCT-1997 11:50:01 EI+ Voltage SIX 70S Noiae:59
351.9000 T:2 BSU3(256r30,-3.0) PKD(7,5,3,0.05\,236.0,1.00\fT,T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLIt43431 UfJ. TIME - 11:52
1001
so:
60:
40:
20:
0:
A3.042J5 A2.75E6
ft
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23:00 ' ' ' ' 24:00 25:00 25:00 271-00 Tiae
rile.-SS75745 tl-829 Aeq:16-OCT-1997 11:50:01 EI+ Voltage SIS 70S Soiee:63
353.8970 T:2 BSUB(256,30,-3.0) PKD(7 ,5,3,0 .OS\, 252. 0,1. 00\,T,T) ExpsEPCUS
TRIANGLE LABS TextsTLI M23 BLANK TLIf 43431 XK7. TIME - 11:52
1001
•
so:
60:
40:
20:
0:
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I A1.87E6
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23:00 24:00 25:00 ' ' ' '25:00 27:00 Time
Pile :SS 76745 tl-829 Acg:16-OCT-1997 11:50:01 EI+ Voltage SIS 70S
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLIt43431 UKT. TIKE - 11:52
1001
80j
60:
40:
20:
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22:5523:11 23:3023:47 . 24:34^24:57 25:25 25:57 .26^22 26:41
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riletS976745 tl-629 Acg:16-OCT-1997 11:50:01 EI+ Voltage SIX 70S
409.7974 T:2 Exp:EPCUS
TRIANGLE LABS Text: II J H23 BLANK TLH43431 OCT. TIME - 11:52
1001
ao:
40:
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0j
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-------
?Ue:s976745 #1-929 Acq:l6-ocT-l997 ll:SOsOl $1+ voltage siA 70s Noiae:62
355.8546 n2 BSUB(256,30,-3.0) PKD(7,5,3,0. OS\,24a.O,1.00\,T,T) EzpsSPCDS
TRIANGLE LASS TextsTLI M23 BLANK TLH43431 UKT. TIKE - 12:52
1001
24:00 25:00 26:00
rilotS976745 fl-829 Aog>16-OCT-1997 HtSOtOl EI+ Voltage SIX 70S BoiaetSO
357.8516 f:2 BSUB(2S6,30,-3.0) PKD(7,5,3,O.OS\,200.0,1.00\,r,T) Etp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLH43431 XK7. TIME = 11:52
1001 A5.96E3
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401
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A2.99E3
A1.131
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A3.22E3
24s 00 2StOO 26:00
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367.8949 T:2 BSUB(256,30,-3.0) PKD(7r5,3,0.05\t232.0,1.00\rT,T) EipsEPCUS
TRIANGLE LABS Toxf.TLI M23 BLANK TLH43431 OCT. TIME - 11:52
1004 AJ..67E6
80.
60.
40.
20.
24i00 25:00 26:00
Tile:S976745 tl-829 Acqil6-OCT-1997 11:50:01 Eli--Voltage SIS 70S Xoiaes49
369.8919 T:2 3SOB(256r30, -3.0) PXD(7,5,3,0.05\,196.0,1.00\,TeT) EzpsEPCUS
TRIANGLE LABS TextsTLI H23 BLANK TLIt43431 OCT. TIME - 11:52
1001
80.
60.
40:
20.
A1.18S6
24:00 25:00 26:00
rile:S976745 tl-829 Acqtl6-OCT-1997 11:50:01 Et+ Voltage SIX 70S
330.9792 Fi2 Exp:EPCUS
TRIANGLE LABS TmxtiXLI H23 BLANK TLIf43431 UU. TIKE - 11152
1003
80.
60.
40.
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24:10 24,21 24,34
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file: 59 76745
373.8208 T:3
#1-475 Acq:16-OCT-1997 11:
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392.9760 T:3
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TSIANGLE LABS TtactiTLI M23
1001
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50:
40:
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1 27:32 28:00
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Text:TLI M23
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-------
\*ile:sS7l,745 tl-475 AcS976745 tl-475 Acq:16-OCT-1997 11:50:01 £1+ Voltage SIS 70S Koi**:83
391.8127 r-.3 3SOB(256,30,-3.0) fXD(7,S,3,0.05\r332.0,1.00\,r,T) Exp:EPCOS
TSIAHSLE LASS Text:TLI M23 BLANK XLH43431 UTJ. TIME -
1004 A4.35E3
29:36 29:48
27:48 28:00 28-12 28:24 28:36 28:48 29:00 29:12 29:24
Tilo:S97674S il-475 Acq:16-OCT-1997 11:50:01 EI+ Voltage SIS 70S Boise-.55
401.8558 T:3 BSttB<256,30,-3.0) PKD(7,5,3,0.05\,220.0,1.00\,T,T) EzpsEPCUS
TRIANGLE LABS Text:TLI M23 BLAUK TLH43431 HKT. TIME - 11:52
29:36 29:48
1001
80.
eo:
40.
20.
A2.09E6
A2.10E6
6.6ES
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27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
Tile:S976745 il-475 A&x:16-OCT-1997 11:50:01 EI+ Voltage SIS 70S Kbi»e:56
403.8529 Fs3 BSVB(2S6,30,-3.0) PXD(7,5,3,0.OS\,224.0,1.00\,r,T) Exp:EPCUS
TSIAOGLE LABS Toxt.-TLI M23 BLANK TLH43431 XK7. TIME - 11:52
1001 A1.78E6
O.OEO
Tin.
80.
60.
40.
20.
A1.66E6
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27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12
rilo:S976745 fl-475 Acq:16-OCT-1997 11:50:01 EH- Voltage SIX 70S
92.9760 Ts3 Elp:XPCUS
TRIANGLE LABS Teit:TLI H23 BLANK TLH43431 XK7. TIME
004 28s 07 28:29 28 : 52
80.
60.
40.
20.
0.
29:24 29:36 29:48
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11:52
29:41 29:51
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O.OEO
: 36 29:48
-------
File:S97674S #1-397 Acq:16-OCT-1997 11:50:01 EI+ Voltage SIS 70S Soiae:163
407.7816 T:4 BSUB(256,30,-3.0) PXD( 7,5,J, 0.05%, £52.0,1.00\,T, T) Exp:EPCUS
TRIANGLE LABS Text:2X1 H23 BLANK XLH43431 I1TJ. TIME » 11:52
1003,
31:12 31:24 31:36 31:48 32:00 32:12 32:24
ril«:S976745 #1-397 Aoq:16-OCT-1997 lit 50 -.01 EH- Voltage SIS 70S Holme: 67
409.7789 T:4 BSV3(256,30, -3.0) PXD(7,5,3,O.OS\,268.Q,1.00\,T,T) ExpsEPCUS
TRIANGLE LABS Teit-.TLI H23 BLAXZ TLI#43431 UKT. TIME - 11:52
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
T±le:S97674S #1-397 Aeq:16-OCT-1997 11:50:01 ZT-f Voltage SIS 70S Bo±ae:128
417.8253 F:4 BSVB(256,30,-3.0) tXD(7,5,3,0.05\,S12.0,1.00\,T,T) Exp-.EPOJS
TSIASGLE LASS Tert-.TLI H23 BUUDT XLI#43431 UKT. TIME - 11:52
1001 A8.3.4E5
80J
32:36
32:48
1004
80:
o:
A5.94E3
A3.92E3
A788.00
32:48
50:
401
201
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A5.63ES
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
r±le:S97674S #1-397 Acq:16-OCT-1997 11:50:01 XI+ Voltage SIS 70S Noiae:176
419.8220 f:4 BSVS(256,30,-3.0) PXD(7,5,3, 0.05%, 704. 0,1. 00\,T,T) Exp:EPCUS
TSIASGLE LABS Tert.-ZCJ H23 BLAJOC TLI#43431 XXT. TIME - 11:52
1001 A1.97E6
32:48
80:
60l
40.
20:
A1.43E6
31:36 31:48 32:00 32:12
-OCT-1997 11:50:01 EH- Voltage SIS 70S
31:12 31:24
r±lesS976745 #1-397
430.9729 T:4 ExptEPCUS
TBIABGLE LABS Text:2ZJ M23 BLAKK tLX#43431
10« 3lA09 31:24 31:35. 31*44 31^58
•\^
so:
sol
40:
20.
32:24
32:36
32:48
XK7. TIME - 11:52
32:07 32 fj.4 32:27 32:35
31:12 31:24 31:36 31:48 32:00 32:12 32:24
rile:S976745 #1-397 Acq:16-OCT-1997 11:50:01 EI+ Voltage SIS 70S
479.7165 rt4 ExptEPCUS
TSIASGLE LABS T*xt:TLI M23 BLAHK TLI#43431 UKT. TIME - 11:52
1004
32:36
32:48
31:12
31:24
31:36
31:48
32:00
32:12
32:24
32:36
33*48
3.7E3
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7.3E2
O.OEO
Time
2.3ES
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Tiae
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Time
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55
-------
yile:sS7674S 91-397 Acq:16-ocx-15S7 11:50:01'EI+ Voltage Sis 76s Hoiae,73
423.77S6 F:4 BSOB{256,30,-3.0} PXD(7,S,3,O.OS\,2B8.0,1.00\,r,T) Exp-.EPCVS
TSIASGLE LASS Texf.TLI H23 BLANK TLH43431 JKT. TIME - 11 :S2
100$
A4.36E3
80.
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30
riletS97674S f 1-397 Acq:16-OCT-1997 11:50101 XX+ Voltage SIS 70S No Laos 66
425.7737 Ts4 BSUB(2S6,3Q,-3.0) PXD(7,5,3,O.OS\,264 .Q,1.00\,T,T) ExpsEPCUS
TRIANGLE LABS Tcxt.-TLJ H23 BLANK TLH43431 HKT. TIME - 11:52
10°* "-*0*3 A2.88E3
32..
0.0EO
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32 36 I:
Kle:S97674S tl-397 AcgslS-OCS-1997 11:50:01 JET* Voltage SIX 70S Ooiae:171
435.8169 T:4 BSUB(2S6,30, -3.0) PKD(7,5,3,0.05\,6B4.0,1.00\,r,T) Exp:EPCUS
TSIANGLE LABS Text.-HI H23 BLANK TLH43431 ISJ. TIME - 11:52
1 SOS al. 5_8E6 „ 3. 4E5
so:
50:
40:
20:
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
rile:S97674S tl-397 Acqsl6-OCT-1997 11:50:01 ZX+ Voltage SIS 70S Noiae:143
37.8140 Fs4 BSUB(2S6,30,-3.0) PKD(7,5r3,0.05*,572.0,1.00*rT,T) Exp:EPCOS
TSIASSLE LABS TextsXLI M23 BLAST TLH43431 HOT. TIME " 11:52
1004 A1.5J3E6
801
eo:
40.
20:
o:
'.2.8E5
-2.1ES
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32:24 32:30 32 36 Time
r3.6E5
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31:24 31:30 31:36 31:42 31i48 31:54 32:00 33:06 32:12 32:18 32:24 32:30
Til*13976745 tl-397 Acqil6-OCX-1997 11:50:01 KH- Vblfc«g» SIS 70S
30.9729 T:4 BzptEPCOS
IA2KLE LASS TartsTLI M23 BLAJUC TLXt43431 UU. TIME - 11:52
32
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36 Tim*
80.
60.
40:
20:
0:
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31>24 31i30 3l't36 31:42 31:48 31:54 32,00 33:06 32:12
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J2.-2< J2s0 J2 36 Time
-------
Tile:S976745 #1-397 Acq:16-OCI-1997 11:50:01 EI+ Voltage SIR 70S Noise -.74
441.7428 T:4 SSUS(2S6,30, -3.0) PKD(7,5,3,O.OS\,296.0,1.00\,TrT) Exp:EPCUS
TRIANGLE LASS Text-.TLI M23 BLANK TLH43431 INJ. TIME - 11:52
100J
901
801
701
601
SOI
401
301
201
101
31
Tile
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901
801
701
601
501
401
301
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101
31
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1001
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801
701
601
501
401
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901
801
701
601
501
401
304
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00 32:00 33:00 34:00 35:00
-.39767 4 5 tl-397 Acq: 16-OCT-1997 11:50:01 EI+ Voltage SIR 70S Noiac:48
7399 T:4 SSU3(256,30,-3.0) PXD(7, 5, 3, 0.051,192. 0,1. 00*,T,T) Ezp:EPCUS
NGLE LASS Teit:TLI M23 BLANK TLH43431 INJ. TIME - 11:52
A7.S1E3 M.04S3 ^ 6SE3 A6.27E3
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Time
1 . 8E6
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11.4E6
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11.1E6
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Li . ass
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Time
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Li.irJ
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Time
57
-------
\File-.S976745 rl-367 Acq:16-ocT-19S7 11:50:01 21+ Voltage sis 70s Noise-.42
457.7377 T:4 BSUB(256,30,-3.0) PXD(7,5,3,0.051,168.0,1.00\,r,T) SzpsEPCUS
TRIANGLE LABS Text: 1X1 H23 BLANK XLIt43431 IJKT. TIME - 11:52
1004 A3.37E3
34:30 34:36 34:43 34:48 34:54 35:00
r±le:S976745 #1-357 Acqil6-OCT-1997 11:50:01 EI+ Voltage SIS 70S Noise:46
459.7348 Ti4 BSUB(256,30,-3.0) PKD(7,5,3,0.051,184.0,1.00\,r,T) Ezp:EPCOS
TRIANGLE LABS Text: EM H23 BLANK TLIt43431 OKT. TIME - 11:52
1004 .. ,,„, A3.Q6E3
35.
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80.
60.
40.
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A3. 76.
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34:30 34:36 34:42 34:48 34:54 35:00
KlasS976745 tl-397 Acq:16-OCT-1997 11:50:01 SI+ Voltage SIS 70S B6iae:43
469.7779 f:4 BSUB(2S6,30,-3.0) rKD(7,S,3,0.05\,168.0,1.00\rTrT) E*p:EPCUS
TRIANGLE LABS Tert.-CTJ M23 BLANK XLH43431 X2K7. TIME - 11:52
1004 A1.Z4E6
35.
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06 Tine
2.4E5
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.9.6E4
'.4.8E4
34:30 34:36 34:42 34-48 34:54
File:S976745 tl-397 Ac
-------
Channel I 338,3782 Pesktoc
Height 1,8? volts 3pm 286 pp
Sustsa file
Oka file
Resolution
Group nuafcsr
icniistlon a
witching
hi, MSSSS
fl 293
B 384
C 386
0 316
E 318
F 328
G 322
H 323
I 331
!ieK
ras
k
>CCi
222.3825,
j 331
,< 332
I 334
I 348
H 342
0 352
P 354
0 356
R 358
Ref, KSS 416,3768
Height ,34 volts Spa
EP01S
fl'-S376741
o
El*
VOLfflGE
416,3768
T 379
U 376
V 418
Peak top
288 ppa
59
-------
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: M23 THERMAL INLET RUN#I Analysis File: S976746
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Asphalt Roofing Project
M23TRAIN Date Received:
185-5-1A-D Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor
Blank Hie:
Analyst
09/29/97
10/01/97
10/16/97
n/a
S976745
BJG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976737
n/a
n/a
n/a
Artafytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
U,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
23,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
U,3,7,8,9-HxCDF
U,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
U,3,4,6,7,8,9-OCDF
Totals "^
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
-Am^*0V;
ND
ND
ND
ND
ND
ND
0.02
ND
ND
ND
ND
ND
EMPC
ND
ND
ND
ND
•* "• /.%"" ' v j * \S5fi1
•• v ••••^Aintf-^ii^'^.^
ND
ND
ND
ND
ND
ND
EMPC
ND
&- ^^ ' m?v< •
0.006
0.01
0.01
0.01
0.01
0.01
0.004
0.008
0.008
0.008
0.006
0.01
0.008
0.01
0.01
0.02
fforbp DL EMPC
0.006
0.01
0.01
0.01
0.004
0.008
0.01
0.01
* ' Ratio FTT Flags
1.01 34:36
—
- ," ,;/<&; ffegs
—
Page 1 of2
X2J7_PSR Ti(XX LARS «.10.04
Triangle Laboratories, Inc.®
301 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:0410/20/97
-------
TLI Project:
Client Sample:
43431 Method 23 PCDD/PCDF Analysis (a)
M23 THERMAL INLET RUN#i Analysis File: S976746
Internal Standards "- Amt« (ng) .. v-"" ^V|5t"Recswwy
13C,2-2,3,7,8-TCDF
13C,2-Z3,7,8-TCDD
13C12-l,2J,7,8-PeCDF
l3C,2-l,2,3,7,8-PeCDD
13C12-l,2,3,6,7,8-HxCDF
13Ci2-l,2,3,6,7,8-HxCDD
13CI2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13C12-1,2,3,4,6,7,8,9-OCDD
^mraaaiiM^^iifi&A&rTv ^-^i* '^ i.
•t*m rogaw^iaHvatfls y yp0j|| , ff&
^CL-^J.S-TCDD
13C,2-2,3,4,7,8-PeCDF
I3Ci2-l,2,3,4,7,8-HxCDF
13C12-lA3,4,7,8-HxCDD
13Ci2-l,2,3,4,7,8,9-HpCDF
"•^ s-f '^V-x^'^vC ff i •• •- -. ^.^ ^ •>., ^^^\^i ''*
104
86.2
93.7
89.1
104
f^l^ec^r
99.3
104
^7^i'\^fe
v-QCl^nfe;
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
^^orn^r
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
<3C Limits
40%-130%
40%-130%
•• ' * f ' ' '
rt, /^f-^&fy, ''$',.
"*»L
0.76
0.80
1.53
1.56
0.50
1.26
0.42
1.00
0.87
:; - Balte
1.49
0.48
1.23
0.44
y
0.47
0.48
-;' 'M»
0.81
122
RT / Flags
20:23
21:12
24:43
25:50
28:29
29:12
31:12
32:04
34:35
JTT Flags
;-, >.
21:14
25:28
28:23
29:07
32:26
^ UT -fFtegs
29:43
28:59
W&&-", Flags
20:59
29:30
Data Reviewer.
Page 2 of2
10/20/97
X237.PSRT2.OaLAKS6.IO.CM
Triangle Laboratories, Inc.s
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:04 1OGfl/97
-------
Initial
..Date..
Data Review By:
Calculated Noise Area: 0.67
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
page No.
10/20/97
Listing of S976746B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
D
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
D
D
320-322
37C1-TCDD
328
DC
d
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
NL
SN
SN
0
NL
WH
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
0:00
19:55
22:13
Peaks
0:00
19:30
19:52
20:23
20:52
22:38
Peaks
0:00
18:18
18:51
19:07
19:16
19:40
19:52
20:06
20:12
20:24
20:36
20:48
21:13
21:47
22:13
Peaks
0.
RO
RO
0.
RO
RO
65-0.89
0
1
.84
.25
0.53
0
1
1
0
.70
.88
.10
.00
65-0.89
0.48
0.52
0.73
0.76 1
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.59
0.64
1
65-0.89
1.
0.
2.
0.
1.
1.
1.
2.
3.
4.
0.
1.
0.
1.
0.
54
82
87
22
83
55
18
61
75
62
76
76
98
14
98
0
2
6
.296
6
8
,311
.37
.05 0.89
.80 2.88
.86 560.71
.11 2.66
.85
.82
0.825-1.102
0
0
1
.000
.977
.090
0.951-1.049
0
1.70 0
3.92 0
736.15 1
4.52 1
1
.000
.957
.975
.000 13C12-2378-TCDF ISO
.024
.110
0.23
1.98
0.55
0.51
0.21
0.39
0.80
0.41
0.21
0.51
0.60
0.
2.
0.
0.
0.
44
60
37
97
00
0.856-1.059
0.000
0.863
0.889
0.902
0.909
0.928
0.937
0.948
0.953
0.962
0.972
0.
1.
1.
1.
981
001 2378-TCDD AN
028
048
0.906-1.094
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
0:00
19:20
19:39
21:14
21:32
21:57
21:59
22:14
0.
0.
3.
784.
1.
14
55
60 3.60
67 784.67
82 1.82
0.45
0.
0.
47
67
0.
0.
0.
1.
1.
1.
1.
1.
000
912
927
002 37C1-TCDD SUR1
016
035
037
049
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:04 10/20/97
62
-------
Page No.
10/20/97
Listing of S976746B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2. . Rel.RT Compound.Name. . ID.. Flags.
DC
328
13C12-TCDD
332-334 DC
DC
DC
DC
332-334
PeCDF
340-342 DC
DC
DC
DC
DC
DC
DC
DC
DC
D d
DC
DC
DC
DC
340-342
SN
4
ML
SN
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
22:41
22:56
Peaks
0:00
19:54
20:14
20:34
20:59
21:12
21:34
22:26
Peaks
0:00
22:38
22:54
23:04
23:14
23:32
23:40
23:59
24:36
24:44
25:04
25:12
26:08
26:30
Peaks
0.
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
0
791
.42 1.42
.46
.51
65-0.89
4.
1.
0.
1.
0.
0.
0.
1.
42
16
72
82
81
80
91
50
1
*!«.»«. .
32-1.78
1.00
0.
0.
0.
0.
0.
0.
0.
2.
1.
3.
0.
0.
1.
07
30
31
56
31
63
33
52
03
29
19
91
52
0
4
1
0
907
898
15
0
,826
.21
.60 3 . 01
.31
.90
.42 406.43
.59 400.72
.49 7.98
.57
.10
1.
1.
070
082
0.906-1.094
0.
2.60 0.
0.
0.
500.99 0.
497.87 1.
8.75 1.
1.
000
939
954
970
990 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
017
058
TCDD / PftCDP Follows ••»•
0
0
0
0
0
0
0
0
0
1
0
0
0
1
0
.16
.07
.10
.18
.15
.08
.33
.16
.74
.66
.36
.10
.48
.56
.00
0.907-1.080
0.000
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
916
927
933
940
952
958
970
995
001 12378-PeCDF AN
014
020
057
072
13C12-PeCDF
352-354
1.32-1.78
DC NL 0:00 RO 1.11
DC SN 22:29 1.54
2.44
53
50
DC SN
352-354
22:29
24:20 RO
24:43
25:01
25:28
25:54 RO
26:08 RO
26:29 RO
6 Peaks
1.
1.
1.49
2.11
0.98
2.05
0.16
0.89
3.06
803.75
5.53
672.24
1.63
1.43
2.35
1,488.36
• 2.93
486.46
3.32
402.01
0.87
1.89
0.838-1.162
0.000
0.910
1.20 0.984
317.29 1.000 13C12-P6CDF 123 IS2
2.21 1.012
270.23 1.030 13C12-PCCDF 234 SOR2
1.048
1.057
0.89
0.92
1.071
Above: PeCDF / PeCDD Follows
PeCDD
356-358
1.32-1.78
DC NL 0:00 RO 1.00
DC SN 24:12 RO 0.54
DC SN 24:25 RO 2.06
0.15
0.48
0.46
0.921-1.026
0.000
0.937
0.945
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtoia Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:04 10/20/97
63
-------
page No.
10/20/97
Listing of S976746B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.
Flags.
356-358
13C12-PeCDD
368-370
368-370
HXCDF
374-376
374-376
13C12-HXCDF
384-386
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
WH
0
ML
SN
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
1
NL
SN
SN
SN
24:34
24:41
24:52
25:08
25:31
25:52
26:21
26:43
Peaks
0:00
25:12
25:50
25:59
26:22
26:37
Peaks
0:00
27:14
27:24
27:32
27:42
28:01
28:05
28:23
28:30
28:43
28:44
28:59
29:12
29:18
29:21
29:34
29:43
29:55
29:59
30:11
30:22
Peak
0:00
27:17
27:22
27:31
28:23
28:29
RO
RO
RO
RO
RO
RO
RO
1
RO
RO
2
1
0
0
4
1
1
0
.38
.23
.10
.37
.57
.20
.59
.59
0
0
0
0
0
0
0
0
0
.20
.53
.08
.12
.54
.69
.44
.72
.00
.32-1.78
1
2
1
.10
.03
.56
1.50
1.58
RO
1.
RO
RO
RO
RO
RO
RO
0.63
KW*>*M .
.05-1.43
0,
1,
.92
.80
2.25
0.77
1.73
7.
.00
1.40
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
1.47
1.
27
2.00
2.50
0.96
1.
0.
91
75
1.04
0.
1.
0.
0.
0.
0.
69
24
81
21
51
70
0
0
426
44
.18
.74
.17 259.70
.09 26.48
1.03
0.72
0
0
0
0
0
1
1
1
.951
.955
.963
.973
.988
.001 12378-PeCDD
.020
.034
AN
0.845-1.155
0
0
166.47 1
.000
.975
.000 13C12-PeCDD 123
IS3
17.61 1.006
1
.021
1.030
470.26
PeCDD / HxCDF Follows ~~
0.40
0.
.34
0.18
0.61
0.34
0.07
0.12
1.30
1.34
0.27
0.22
2.
0.
0.
0.
0.
1.
0.
0.
0.
0.
2.
96 1.64
52
33
51
49
90
52
23
42
47
96
43-0.59
0.
1.
0.
0.
0.
0.
67
16
67
37
48
50
0.
54
0.29
0.
1.
649.
722.
74
21
15 211.44
34 239.85
0.956-1.053
0.000
0.956
0.
.962
0.967
0.972
0.984
0.
0.
.986
.996 123478-HxCDF
1.001 123678-HxCDF
AN
AN
1.008
1.009
1.70 1.
018 234678-HXCDF
AN
1.025
1.
1.
1.
1.
1.
1.
1.
1.
029
030
038
043 123789-HxCDF
050
053
060
066
AN
0.860-1.140
0.
0.
0.
0.
437.71 0.
482.49 1.
000
958
961
966
996 13C12-HXCDF 478
000 13C12-HXCDF 678
S0R3
IS4
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:04 10/20/97
-------
Page NO.
10/20/97
Listing of S976746B.db£
Hatched GC Peaks / Ratio / Ret. Tine
Compound/
M_Z QC.Log Omit Why ..RT. OK'Ratio Total.Area... Area.Peak.1.. Area.Peak. 2.. Rel.RT Compound.Name.. ID.. Flags.
384-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
7
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0
NL
SN
SN
4
28:47
28:59
29:12
29:19
29:25
29:28
29:33
29:43
29:59
30:10
Peaks
0:00
27:54
27:55
28:28
28:37
28:40
28:50
28:56
29:00
29:08
29:13
29:31
29:44
29:51
Peaks
0:00
28:35
29:07
29:12
29:30
29:42
29:56
Peaks
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
0
0
0
0
.31
.48
.74
.54
0.37
0
.36
0.93
0
1
0
.47
.10
.33
»!*...
2
666
2
1
0
0
0
550
1
0
2.595
~. . Uu*»n
05-1.43
1
0
0
1
0
1
0
2
1
0
2
1
1
.45
.44
.27
.47
.37
.17
.95
.00
.52
.95
.23
.21
.78
4.25
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
.69 0.91
.16 216.73
.91 1.42
.22
.98
.71
.60
.62 177.03
.74 1.27
.86
.61
.25
.38
.20
.72
.13
.13
.34
.22
.69
.63
.78
.15
.60
.09
.00
05-1.43
0
1
1
1
1
0
1
.46
.28
.23
.26
.22
.50
.19
-- ah™
0
2
474
546
571
1
1
1.595
rm>-' tttCD
.20
.67 1 . 50
.01 261.15
.84 304.41
.84 314.63
.41
.29
.36-
n 1 Hrx-nTJ Poll own — -
2.92 1.011
449.43 1.018 13C12-HXCDF 234
1.93 1.025
1.029
1
1
1
373.59 1
1.15 1
1
.033
.035
.037
.043 13C12-HXCDF 789
.053
.059
ALT2
ALT1
0.950-1.015
0
0
0
0
0
0
0
0
.000
.955
.956
.975
.980
.982
.987
.991
0.993
0
1
1
1
1
.998 123478-HxCDD
.001 123678-HxCDD
.011 123789-HxCDD
.018
.022
AH
AN
AN
0.966-1.034
0
1.17 0
212.86 0
242.43 1
257.21 1
1
1
.000
.979
.997 13C12-HXCDD 478
.000 13C12-HXCDD 678
.010 13C12-HXCDD 789
.017
.025
SOR4
IS5
RS2
HpCDF
408-410
408-410
13C12-HpCDF
418-420
0.88-1.20
DC NL 0:00 RO 1.59 2.12
DC SN 31:14 RO 2.53 0.96
0 Peaks 0.00
0.37-0.51
DC NL 0:00 RO 0.74 1.58
31:12 0.42 452.62
DC SN 31:34 RO 0.32 0.72
134.49
0.996-1.046
0.000
1.001 1234678-HpCDF
AN
0.936-1.128
0.000
318.13 1.000 13C12-HPCDF 678 IS6
1.012
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive* Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:04 10/20/97
-------
page No.
10/20/97
Listing of S976746B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why .-RT. OX Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
418-420
DC SN 32:07 RO 0.62
32:26 0.44
DC SN 32:53 0.50
DC SN 32:57 RO 0.28
2 Peaks
Above:
1.47
361.64
2.22
0.92
814.26
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
•
442-444
OCDD
458-460
MK
458-460
13C12-OCDD
470-472
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
WH
0
NL
SN
SN
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
1
NL
WH
0:00
32:05
32:26
Peaks
0:00
32
32
:04
:29
32:36
0
RO
RO
RO
0
RO
RO
RO
.88-1.20
5.20
1.43
4.67
.88-1.20
1.49
1
0
0.
.00
.60
.50
Peak
0:
31:
31:
00
12
23
0.
RO
RO
RO
31:44
31:
31:
32:
32:
32:
32:
32:
33:
33:
33:
34:
35:
51
57
06
10
17
35
44
02
25
43
46
00
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.31
1.51
0.37
0.00
1.45
466
0
0
466
Urs^n
.76-1.02
1.
0.
2.
,63
,38
,00
0.85
1.18
0.
1.
0.
0.
1.
0.
1.
1.
11.
0.
1.
26
10
09
88
24
81
25
14
17
36
18
Peaks
0.
0:00
34:
34:
36
48
0
0
0
0
0
0
0
0
0
.63
.57
.71
.63
n /
*/ /
.30
.45
.34
.37
.32
.15
.55
.06
.60
0.70
0.29
0.30
0.40
0.11
1.04
0.64
0.00
76-1.02
0.
1.
0.
83
01
92
Peak
0:
34:
35:
00
35
08
0.
RO
0.22
1.
.63
0.48
1.63
76-1.02
1.
0.
0.
00
87
73
0.18
525.17
1.00
1.029
111.09 250.55 1.040 13C12-HpCDF 789 SOTS
1.054
1.056
0.977-1.006
0.000
1.001 1234678-HpCDD
1.011
AN
233.85
0.969-1.031
0.000
232.78 1.000 13C12-HpCDD 678 IS7
1.013
1.017
CDF Follows
0 . 82
245.01
0.884-1.116
0.000
0.902
0.907
0.918
0.921
0.924
0.928
0.930
0.933
0.942
0.947
0.955
0.966
0.975
1.005
1.012
0.884-1.116
0.000
0.81 1.000 OCDD
1.006
0.997-1.006
0.000
280.16 1.000 13C12-OCDD
1.016
AN
IS8
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:0410/2
-------
Page No.
10/20/97
Listing of S976746B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
470-472
1 Peak
525.17
Column Description 'Why* Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (muss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
•* End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
ttle:S976746 #1-829 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIX 70S Noioe:160
303.9016 F:2 BSUB(256,30, -3.0) PXD(9,5,5,0.05\,640.0,1.00*,f,T) ExpsEPCUS
TRIANGLE LABS Teit:H23 THERMAL ISLET RORfl TLH43431 IJKT. TIKE = 12:32
IOCS,
A1.33E4
A1.72E4 I A1.32E4
17:00 18:00 19:00 20:00 21:00
rile:S976746 #1-829 Ac
-------
file :SS 75745 #1-029 Acq: 16-OCT-1997 12:29:20 EI+ Voltage SIS 70S Noise: 10 J.
319.8965 F:
2 BSUS(2S6,30,-3.0) PXD(7,S, 3,0. 05\,404. 0,1.00\,T,T) ExpsEPCOS
TRIANGLE LASS Text:M23 TBESMAL ISLET SOKfl HI f 43431 1KT. TIME * 12:32
1003
so:
60:
40:.
20:.
o-
A.
Au
Al. 5E4 7.8E3
A2.59E3 A1.44E4
A8.87E3 . *4 f1E3^l \A4.42E3 I | A2.3SE3 AS.39E3
jUA^AwvHwl' wc^\ wW\ rVL/ jw*tj*Lj<^j^
.6.2E3
.4 . 7E3
.3.1E3
.1 . 6E3
0. OEO
' 19:00 ' ' ' 20:00 ' 21:00 22:00 Tlae
Tile:S976746 fl-829 Acq: 16-OCT-1997 12:29:20 EH- Voltage SIS 70S Noise: 63
321.8936 T:
2 3SUB(256,30,-3.0) PXD(7,S,3,O.OS\,2S2.0,1.00\,T,T) Exp:EPCOS
TS I ANGLE LABS Taxt.:H23 THERMAL ISLET SOSfl TUH3431 UKT. TIME - 12s 32
100^
80:
60:
40:
'.
20'
oj
A1.47E4 4.SE3
LT.*>(' I--1)?'*"'' 8TC
.[A3.62E3 '[ '- .&n' /'//l/fl j A3.22E3 A4.16E3
n
IK
/v
A4 51E3 fl 1 1
A4 67E3 11 * J J.-&J i ill 111
"l |L i 1 i_ A3.38E3 A3.20El'l A1.52E3 \ J. fl
1 fl ( ^\, «^_^ ||| "A2mf%trf!3 1 • I ^» *> A^W 1 1 ll 1 1 II _ — Jlfl - /I t
k4Myw" vJ uv^flr^w ^.ul/^LvJUJirLA^/iM/
.3.6E3
.2.7E3
.1 . 8E3
9 . OE2
O.OEO
1.9:00 20:00 21:00 22:00 ' Tiae
File:S976746 fl-829 Acq -.16 -OCT- 1997 12:29:20 EH- Voltage SIS 70S Soise:266
331.9368 r:2 SSUB(2S6,30,-3.0) •PXD(7,S,3,O.OS\,1064.0,1.00\rr,T) ExpsEPCOS
TRIANGLE LASS TarttM23 THERMAL ISLET SUSfl TLH43431 IKT. TIME - 12*32
1004
80:
50J
40:
20:
o:
A4.06E6 _1.1£5
I A4 . 01E6
\
J U
\^
.8.8E5
'-.6.6ES
.4.4E5
.2.2ES
O.OEO
19:00 20:00 21:00 22:00 Tiae
Tile:S976746 fl-829 Acq:16-OCT-1997 12:29:20 EH- Voltage SIS 70S Ooiae:61
333.9338 T:2 BSUB(2S6,30,-3.0) PED(7 ,5,3,0. OS\,244. 0,1. 00\,F,T) ExptEPCOS
TSIAKSLE LASS T*xttM23 THERMAL ISLET StOTtl XLIf 43431 ZK7. TIME - 12:32
100^
80:
60:
40:
20:
oj
A5.0^EfsgE6 1.3E6
i \
I \i V
.1.1E6
.S.1ES
'•.S.4ES
.2.7ES
O.OEO
19:00 20:00 21:00 22:00 ' ' ' ' Tiae
rile:S976746 fl-829 Acq: 16 -OCT- 1997 12:29:20 El* Voltage SIS 70S Noise: 69
327.8847 F:2 BSUB(2S6,30,-3.0) PXD(7,5,3,O.OS\,276.0,1.00\,T,T) ExpsEPCUS
TRIANGLE LASS Text:M23 THERMAL ISLET RUSfl XLH43431 HXT. TIME - 12:32
100J
80J
60:
401
201
o-
A7.
1
15E6 -1.9E6
^_
.1.SE6
.1.1E6
.7.6E5
.3 . 8E5
O.OEO
' 19:00 20:00 21:00 22:00 Tiae
File:S976746 fl-829 Acq:16-OCT-1997 12:29:20 EH- Voltage SIS 70S
330.9792 T:2 Kxp:EPOJS
TRIANGLE LABS Taxt:M23 THERMAL ISLET XOSfl TLH43431 IJKT. TIME - 12:32
1003
80:
50:
40:
20:
oj
Sr^-^
laA4°~J*iS£j:9ii9 19j2L19s54J^12 x-v/Sv^^^AvC^^x-^^
*\r\/f*^^~r —~*^* ~***\Httf ^\ f**t — " \f** ^*~^
.4.2E6
-3.4E6
-2.SE6
_1 . 7E6
-8.4E5
O.OEO
19:00 20:00 21:00 22:00 ' ' ' Tiae
-------
leile:S976746 il-829 Acq:16-OCT-1997 12:29:20 EH- Voltage SIX 70S So±ae:50
339.8597 T:2 BSU3(256,30,-3.0) PKD(7,5,3,0.05\,200.0,1.00\,T,1) Ezp:EPCUS
TRIANGLE LABS Text:M23 THERMAL INLET SONtl TLH43431 INJ. TIKE - 12:32
1004 A2.87E3
23:00 24:00 25:00 25:00
File:S976746 fl-829 Acq:16-OCT-1997 12:29:20 EH- Voltage SIS 70S Noise-.52
341.8567 F:2 BSO3(256,30, -3.0) PXD(7,5,3,0.05\,208.0r1.00\rT,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL ISLET RUNfl TLH43431 XK7. TIME - 12:32
1004. A9.81X3
•.O.OEO
•00 Tim
23:00 24:00 25:00 26:00
r±le:S976746 tl-829 Acq:16-OCT-1997 12:29:20 ZH- Voltage SIX 70S Soiae:SO
351.9000 T:2 BSO3(256,30,-3.0) PKD(7,S,3,O.OS\r200.0,1.00\rTtT) Exp:£PCUS
TSIANSLZ LABS Text.iH23 THERMAL ISLET RtOftl XLH43431 IKT. TIMS - 12:32
1001 A4.86X6
27:(
80-
601
40l
201
A4.02E6
23:00 24:00 25:00 26:00
filesS976746 fl-829 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIS 70S Koine:44
353.8970 T:2 BSO3(256,30,-3.0) PKD(7,5r3rO.OS\t176.0,1.00\rr,T) Xzp:XPCUS
TRIANSLE LABS Text:M23 THERMAL ISLET ZVIH1 XLH43431 ZW. TIME - 12:32
1004 A3.17E6
00:
so:
40l
201
A2.70E6
A
I V.
23:00 24:00 25:00 26:00
F±le:S976746 H-829 Acq:16-QCT-1997 12:29:20 H+ Voltage SIR 70S
30.9792 F:2 Exp:EPCUS
TRIANGLE LABS ToxtiM23 THERMAL ISLET ROStl XLH43431 ZNT. TIME - 12:32
22:55 23:29 23:48 24:09 24:30 25:02 25:23 25:48
00:
so:
40.
20-
o:
23:00 24:00 25:00 26:00
File:S976746 f 1-829 Acq:16-OCT-1997 12:29:20 EH- Voltage SIS 70S
09.7974 F:2 ExpsZPCUS
TRUOTSLE LABS TfXt:M23 THERMAL ISLET SOSfl TLIf43431 ZKT. TIME • 12:32
00^
00:
60:
40:
20:
o:
23
17
25:28
25,47
26:41
23:00
24:00
25:00
20:00
1.6E6
.1.3E6
.9.3X5
-6.6ES
-3.3E5
27:
O.OEO
00 Tim,
_1. OE6
.8.3E5
-6.2ES
'.4.2ES
-.2.1E5
27:
O.OEO
00 Time
-4.4E6
.3.5E6
.2. see
.1.8E6
-8.8E5
O.OEO
27:00 Tine
.3.6E3
.2.7E3
.1. 8E3
"-9.1Z2
_ .O.OEO
7:00 Time
70
-------
flJ.e:S976746 11-829 Acq:lt>-OCT-1997 12:29:20 EH- Voltage SIS 70S Noise:45
355.8546 T:2 BSUB(256,30,-3.0) PKH(7,S,3,0.05\,180.0,1.00\,T,T) Ezp:EPCUS
TRIANGLE LASS Text:M23 THERMAL INLET SOStl TLIt43431 INJ. TIME = 12:32
1003, A9.65E3
80.
24:00 25:00 26:00
rileiS976746 tl-829 Acg:16-OCX-1997 12:29t20 EH- Voltage SIS 70S Koiae:44
357.8516 T:2 BSO3(256r30,-3.0) PXD(7,5,3,0.05\,176.0,1.00\,T,T) Exp:EPCDS
TRIANGLE LASS Teit:M23 THERMAL ISLET BUNtl TLH43431 TKJ. TIME - 12:32
1004
80.
24:00 25:00 26:00
r±le:S976746 tl-829 Acq:16-OCT-1997 12:29:20 EH- Voltage SIX 70S Soi.ae-.53
367.8949 Ti2 aSUB(256,30,-3.0) PXD(7,5,3,0.05\,212.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LASS Text:M23 THERMAL ISLET SUlTtl TLH43431 XK7. TIME * 12:32
100% A2.60E6
so:
60:
40.
20.
.2.65ES
24:00 25:00 26:00
Kle:S976746 tl-829 Acg:16-OCT-1997 12:29:20 EI+ Voltage SIS 70S Soiee-.SO
369.8919 f:2 SSUS(256,30r-3.0) PKD(7,5,3,0.05\r200.0,1.00\,T,T) Exp:EPO7S
TRIASGLE LASS Text:M23 THERMAL ISLET SOSfl XLH43431 UKT. TIME ' 12:32
ion
80.
60.
40.
20.
Al.66E6
.76ES
24:00 25:00 26:00
r±l«:S976746 tl-829 Aoqtl6-OCT-1997 12:29,20 ZH- Voltage SIS 70S
330.9792 ti2 ExptEPCUS
TRIANGLE LASS Text:M23 THERMAL ISLET SVStl TLH43431 BET. TIME - 12:32
40.
20.
0.
26:38
r8.srs
.6.9E5
.5.2E5
-3.4E5
1.7E5
O.OEO
24:00
25:00
26:00
5.1E5
4.1E5
.3.0E5
2.0ES
.1. OES
.O.OEO
Tine
4.4E6
3.5E6
2.6E6
.1. 8E6
8.8E5
0. OEO
Time
•n
-------
file:S976746 tl-47S Acq:16-OCT-1997 12:29s20 EI+ Voltage SIS 70S Jfoite:108
373.8208 T-.3 SSUS(256,30,-3.0) PXD(7,S,3, 0. OS\,432.0,1.00\,T,T) ExpsEPCOS
TRIANGLE LASS Tert:H2J TBZSMAL INLET SVNtl TLH43431 2X7. TIME = 12:32
100*
27:24 27:36 27:48 28,00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
Tile:S976746 #1-475 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIS 70S Soiae-.122
375,8178 T:3 BSUB(2S6,30,-3.0) PKD(7,5,3,0.051,488.0,1.00\,f,T) Exp:EPCUS
TRIANGLE LASS Text:M23 TSESMAL ISLET KUfftl TLIt43431 UV. TIME - 12:32
ion AI. 70x4
O.OEO
Tim
A4.37E3
A819.19H A1.39E
27:24 27:36 27:48 28tOO 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
rile:S976746 tl-475 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIS 70S Ooiae:119
383.8639 Tt3 SSOB(2S6,30,-3.0) tXD(7,5,3,0 .OS\,476.0,1.OQ\,T,T) ExpsETCOS
TRIANGLE LASS Text:M23 TSESMAL ISLET SVStl TLIt43431 XK7. TIME - 12:32
100* A2.40E6 ^^
601
40:.
201
oj
A1.77E6
Tim
a.iss
.6.5E5
.4.8E5
.3.2ES
.1. 6ES
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
Tile:S976746 tl-475 Acq:16-OCT-1997 12:29:20 EI+ Voltag* SIS 70S Xoiae:178
85.8610 T:3 SSUS(256,30,-3.0) fXD(7,5,3,0.05%, 712.0,1.00\,T,T) ExpsEPCOS
TRIANGLE LASS Taxt:M33 TBEKHAL ISLET BONtl TLIf43431 HKT. TIME - 12:32
1003 A4.82E6 A4.49E6
O.OEO
Tim.
SOI
601
401
201
ol
A3.74E6
1. 6E6
.1. 3E6
.9. 7ES
.6.4ES
-3.2ES
I V.
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
rile:S976746 tl-475 Aoq:16-OCT-1997 12:29:20 Eli- Voltage SIS 70S
92.9760 T-.3 ExptEPCUS
TRIANGLE LASS Text:M23 THERMAL ISLET SOStl TLIf43431 UU. TIME - 12:32
OOi
sol
601
401
201
OJ
O.OEO
Tia<
.1.9E6
.1.4E6
19.3ES
.4.7ES
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
ile:S976746 tl-475 Aoy:16-OCX-1997 12:29:20 EI+ Voltage SIS 70S
45.7555 T:3 Erp:EPCOS
•IASSLE LASS T*XtsM33 TSESfOL ISLET SUN41 TLIf43431 JXT. TIME - 12:32
27 52
O.OEO
Time
27'i24' 27\36 27\48' i«»0o' 28:12' 28:24' 28-36' 28:48' 29:00' 29till' 29:24 29'-. 36 29:48 30:00 30:12
-------
fiJ.e:SS76746 #1-475 Acg:J.6-OCT-J.S97 12:23:20 EI+ Voltage SIS 70S Wbj.se.-7fl
385.8155 F:3 BSVB(256,30,-3.0) PXD(7,S,3,O.OS\r312.Qtl.QO\tT,T) Exp:EPCDS
TRIANGLE LASS Tert:K2J THERMAL ISLET RUNtl TLIH3431 INJ. TIME * 12:32
1001 A7.78E3
4.0E3
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
Tile-.3976746 tl-475 Acq:16-OCT-1997 12:29:20 EH- Voltage SIS 70S Noiae:57
391.8127 Ti3 SSUB(2S6,30f-3.0) PXD(7,S,3,0.05\,22S.O,1.00\,r,T) ExpsEPCUS
TRIANGLE LASS Tezt:M23 THERMAL ISLET EDNtl TLIt43431 HU. HUE ' 12:32
1001
29:36 29:48
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
Tile:S976746 tl-475 Acg:16-OCT-1997 12:29:20 EI+ Voltage SIR 70S Noiae:54
401.SSS8 T:3 BSDS(2S6, 30,-3.0} PXD(7,5,3,O.OS\,216.0,1.00\,T,T) Efp:EPCUS
TRIANGLE LASS Text:M23 THERMAL ISLET RUNtl TLIf43431 ZK7. TIME - 12:32
•1001 ., „„..„ A3.15E6
29:36 29:48
80.
60.
40.
20.
A3.04E6
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
File:S976746 tl-475 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIR 70S Noise-.119
403.8529 T:3 BSUS(256,30, -3.0) PXD(7,5,3,O.OS\,476.0,1.00\rT,T) SxpsEPCOS
TRIANGLE LASS Teit:M23 THERMAL ISLET RUNtl TLII43431 UKT. TIME - 12:32
1001
80.
eo:
40.
20.
A2.57E6
A2.42E6
29:24 29:36 29:48
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12
rile:S976746 tl-475 Aoq:16-OCT-1997 12:29:20 EI+ Voltage SIX 70S
392.9760 r:3 Elp:EPCUS
TRIANGLE LASS Teit:M23 THERMAL ISLET RUSH TLH43431 XK7. TIME - 12:32
28:09 28sl7 28:26 . 2J-.41 ,..e?«L57. . . 39,26 29:3829:47
80.
60.
40.
20.
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
.1.1E6
.a. ass
.6.6ES
.4.4ES
.2.2E5
.O.OEO
Time
.9.3ES
7.3E5
.S.SE5
3.7ES
1. 8E5
O.OEO
Time
2.3E6
1.9E6
.1.4E6
9.3E5
.4.7E5
O.OEO
Time
73
-------
riletS976746 #1-397 Acq:16-OCT-1997 12:29,20 EI+ Volt*ye SIX 70S Soi.ao-.B26
407.7818 T:4 BSOB(256,30, -3.0) PXD(7,5,3, 0.05%,3304.0,1. 00\,T,T) EzpsEPCUS
TRIANGLE LABS Tezt:H23 THERMAL INLET RCNtl TLU43431 ISJ. TIME - 12:32
1001 .
31:24 31:36 31:48 32:00 32:12 32:24
Tile:S976746 tl-397 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIX 70S Soiee:521
409.7789 T:4 BSUB(256,30,-3.0) PKD(7,5,3, 0. 05\,2084.0,1.00\,r,T) Exp:EPCUS
TXIASGLE LABS Tezt:M23 THERMAL ISLET XUStl TLH43431 ISJ. HUE - 12:32
100*
32:36
32:48
31:12 31:24 31:36 31:48 32:00 32:12 32:24
rile:S976746 tl-397 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIB 70S Soiae:404
417.8253 F:4 BSOB(256,30,-3.0) PKD(7,S,3,0.05\,1616.0,1.00\rr,T) SxpiSPOJS
TBIANGLE LABS Text:M23 THESMAL ISLET BOlTtl TLH43431 I2KT. TIME - 12:32
100$ A1.3.4E6
32:36
32:48
00:
so;
40.
20:
A1.11E6
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
Tile:S976746 tl-397 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIR 70S Noise: 550
419.8220 F:4 BSUB(256,30,-3.0) PXD(7r5,3,0.05\,2200.0,l.OO\,r,T) Exp:EPCOS
TRIANGLE LABS Teit:M23 THERMAL ISLET SUNfl TLH43431 INT. TIME - 12:32
A3.J.8E6
80: / \ A2.51E6
60:
40:
20:
32:48
31:12 31:24 31:36 31:48 32:00 32:12 32:24
•ile:S976746 tl-397 AtX[:16-OCT-1997 12:29:20 EH- Voltage SIR 70S
U0.9729 r:4 Erp:EPCUS
TRIANGLE LABS Teit:M23 THERMAL ISLET RVStl TLIt43431 INT. TIME - 1.
1004^ 31:11 31:35 31:48 31:54 32^07^ 32^16 32:26
80:
60:
40:
20:
o:
32:36
32:48
32:24
31:12 31:24 31:36 31:48 32:00 32:12
r±la:S976746 tl-397 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIR 70S
79.7165 f:4 Elp-.EPCOS
TRIANGLE LABS Tezt:M23 THERMAL ISLET ROlTfl TLH43431 TKT. TIME - 12:32
001
32:36
32:48
31:12
31:24
31:36
31:48
32:00
32s 12
32:24
32:36
32:48
-.O.OEO
Til
3.6X5
.2.9X5
.2.2X5
.1.4X5
-.7.2X4
.0.0X0
5. 0X5
-.7.2X5
.5.4X5
.3.6X5
.1.8E5
O.OEO
Time
-1.7X6
-.1.4X6
.1. 0X6
.7.0X5
.3.5X5
0.0X0
74
-------
F3.J.e:SS76746 #1-397 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIR 70S «6iae:391
423.7766 T:4 BSUB(256,30, -3.0) PKD(7,S,3,O.OS\,1S64.0,1.00\,T,T) EzpiEPCUS
TRIANGLE LASS Text:M23 THERMAL ISLET SCJfH TLIf 43431 ISJ. TIME - 12:32
100\ A1.06E4
31s24 31:30 31:36 31:42 31:48 31s54 32:00 32s06 32:12 32:18
rile:S976746 fl-397 Aoy:16-OCT-1997 12:29:20 EI+ Voltage SIS 703 Boi»e:76
425.7737 T:4 BSUS(256,30,-3.0) PKD(7,5,3,0.OS\,304.0,1.00\,T,T) ExpsEPCUS
TRIANGLE LASS Text:M23 THERMAL ISLET RUNtl TLIf 43431 XK7. TIKE - 12:32
ion
32:24 32:30 32
.O.OEO
36 Time
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
KlesS976746 fl-397 Acq:16-OCT-1997 12:29:20 EH- Voltage SIS 70S Soiae:531
435.8169 f:4 BSUB(256,30, -3.0) PXD(7,Sr3,O.OS\,2124.0,1.00\,r,T) ExptSPCOS
TRIANGLE LASS Text:H23 THERMAL ISLET SUNtl TLIt43431 IW. TIME - 12s 32
1004 A2.34E6
80.
60.
40.
20.
32:24 32:30 32.
6.3ES
.5.0E5
'.3.8E5
'.2.5E5
'.1.3ES
O.OEO
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32 36 Time
rile:S976746 tl-397 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIS 70S Bbi*f:354
437.8140 T:4 SSUS(256,30,-3.0) PXD(7,5,3,0.051,1416.0,1.00\,r,T) SzpsEPCUS
TRIANGLE LASS Text:K23 THERMAL ISLET StOffl TLIf43431 TJSKT. TIME * 12:32
1003
00:
60:
40:
20:
. A2.33E6
6.3E5
.5.0ES
.3.8E5
.2.5ES
.1.3ES
O.OEO
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32 36 Time
Flle*S976746 fl-397 Aoq:16-OCT-1997 12:29:20 EH- Voltage SIS 70S
430.9729 F:4 ExptEPCUS
TRIANGLE LABS Toxt.tM23 THERMAL ISLET RUSH XLH43431 HKT. TIME - 12:32
50:
40:
201
0:
32:26
1. 7E6
.1.4E6
.1.0E6
.7.0E5
.3. SES
O.OEO
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32 36 Time
CU
-------
rile,S976f4i #1-397 AC(7,5,3, O.OS%,524.0,1. 00\,T,T) ExpsEPCDS
TRIANGLE LABS Text:M23 TBEBOL ISLET SDJH1 TLH43431 UfJ. TIME ' 12:32
100$
90.
ao.
701
60.
501
40.
301
201
101
A1.38E4
. A3.61E3
-A- A. .jiAA-A-nA—«^—Ar\-^
A3.23X3
A4.71E3
A9.25E3
A7.86E3
31 00 32:00 33:00 34:00 35:00
rile:S976746 « 1-397 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIS 70S Ho3.ae-.62
443.7399 f:4 BSVS(2S6,30,-3.0) PXD(7, 5,3,0 .OS\, 328.0,1. 00\rf, T) Eip:EPCUS
TRIANGLE LABS Text:K23 THESfSAL ISLET SUNtl TLIf 43431 J7TJ. TIME ' 12:32
2.6E4
L2.4E4
•-2.1E4
':!. BE4
Ll - 6E4
''.!.'3E4
.1.1E4
.7.9E3
.S.3E3
'•-2.6E3
O.OEO
Time
90.
801
701
601
501
401
301
201
101
A5.47E3
}.17E3
A1.3SE4
A2.86X31 ^
^A^AwL^
I.70E3 *3•OSE3
A4.46E3
A5
.04E3 11 A3.36E3 A4.34E3
AjWniyi JrmJk^M^lm M
^^^^****"^*~~^^*^mj****ri*""^mr**^*'i^~*^**
1.9E4
1. 7E4
l. 5E4
l.3E4
31 00 32:00 33:00 34:00 35:00
File:S976746 91-39? Acg:16-OCX-1997 12:29:20 EH- Voltage SIX 70S
430.9729 Ti4 Ezp:EPCUS
TRIANGLE LABS Text:M23 THEMHAL ISLET RUNil TLH43431 XK7. TIME - 12:32
ioo\ 31:54 32:16 32:47 33:12 33^35 ( 34:11 34:30 34.:5235!11
901
.9.5E3
.7.SE3
.S.7E3
.3.8E3
.1.9E3
.O.OEO
Time
31 00 32:00 33:00 34:00
rile:S976746 «l-397 Acq: 16-OCT-1997 12:29:20 EI+ Voltage SIS 70S
"13.6775 r:4 ExpsSPCOS
TRIANGLE LABS Tmxt:H23 XaOHAZ THLET SUKH TLH43431 HKT. TIME
100\
35:00
12:32
31 00
32:00
33:00
34:00
35:00
-------
files5976746 #1-397 AcqsJ.6-OCT-J.9S7 12:2S:20 EI+ Voltage SIX 70S Noiae:4S
457.7377 F:4 BSUB(256,30,-3.0) PXD(7,5,3, 0.05%, 196.0,1.00\,r,T) £xp:EPCUS
TRIANGLE LABS Taxt:M23 THERMAL ISLET RUNil TLI»43431 TJK7. TIME - 12:32
1003, A2.16E3
34:30 34:36 34,42 34:48 34:54 35:00
File:S976746 #1-397 Acq:16-Od-1997 12:29:20 EI+ Voltage SIR 70S Noiae:58
459.7348 t:4 BSUB(256,30,-3.0) PXD(7,S,3,0.05\r232.0,1.00\,T,T) ExptEPCOS
TSIASSLE LABS Text:M23 THERMAL ISLET RUNtl TLIf 43431 UU. TIME - 12:32
1003,
34,30 34,36 34t42 34', 48 34,54
Tile,2976746 H-397 Aexj:16-OCT-1997 12:29:20 EH- Voltaye SIS 70S Hois*,47
469.7779 f:4 BSVB(256,30,-3.0) PXD( 7,5,3, 0.05\,1B8. 0,1.00%, r,T) Exp:EPCOS
TBIANGLE LABS Toxt:H23 THESMAL ISLET SONtl TLH43431 1X7. HUE - 12:32
1003, A2
80J
601
40:
20:
A1.24E4
35
.3.0E3
-2.2E3
-1.5E3
-7.4E2
.O.OEO
06 Time
35,00
35 06
3.7ES
.3. OE5
.2.2E5
.l.SES
.7.5E4
34:30 34:36 34:42 34:48 34:54 35:00
TilesS976746 fl-397 Acq:16-OCX-1997 12:29:20 EI+ Voltage SIS 70S Boise:46
471.7750 T-.4 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,ia4.0,1.00\,T,T) Elp-.EPCUS
TSIASGLE LABS Teit:K23 THERMAL ISLET StOTfl TLIf43431 HKT. TIME - 12:32
35
O.OEO
06 Time
34:30 34:36 34:42 34,48 34:54 35,00
Tile:S976746 §1-397 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIS 70S
430.9729 T:4 ExptEPCUS
TXUOKLE LABS T*rt:M23 THEStfAL ISLET KU1H1 TLH43431 HKT. TIME ' 12:32
35
100*
aol
60.
401
20'.
0.
34:52
34:56
34:30
34:36
34:42
34:48
34:54
35:00
35
r4.4ES
.3.5ES
.2.6ES
'.1. 8E5
.8.8E4
.O.OEO
06 Tiat
1. 8E6
.1. 4E6
.1.1E6
.7.0E5
'.3. SE5
.O.OEO
06 Time
77
-------
ChanneL I 38,3752 Pesk top
Height l,S7voU- Spsn £88 ppii
Systet file nase
file nau
Kesditi.cn
isnizxion ace
Snitching
Ref, aasss 2SE.S
K 332
I 334
H 348
H 342
0 352
P 354
8 356
R 358
EPCUS
fl--S376741
2
£!•
VDLlil
416.3768
S ^8
T 378
U 376
V 418
lass 418,3769 Peak top
Height .34 volts Span ^8pp«
78
-------
TLI#43431
File:S976746 #1-397 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS
Sample Text:M23 THERMAL, INLET RUN#1
100&
90 J
80 J
70J
60 J
501
40 j
30J
20J
10J
OJ
INJ. TIME = 12:32 File Text:M23 THERMAL I»
_4.4E3
.3. 9E3
L3.4E3
_2.9E3
_2.4E3
L1.9E3
_1.5E3
_9.7E2
_4.8E2
35:00
35:12
33:36 33:48 34:00 34:12 34:24 34:36 34:48.
File:S976746 #1-397 Acq:16-OCT-1997 12:29:20 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:M23 THERMAL INLET RUN#1 TLI#43431 INJ. TIME « 12:32 File Text:M23
100%
90 J
80 J
70 J
60 J
50 J
40J
30 J
20 J
10J
OJ
33:36
33:48
34:00
34 112
34:24
34:36
—i—i—i—i—i—i—i—i—i—r
34:48 35:00
1 1 ' '
35:12
O.OEO
Time
THERMAL I»
_4.5E3
_4.1E3
_3.6E3
-3.2E3
_2.7E3
_2.3E3
_1.8E3
-1.4E3
_9.1E2
E.4.5E2
LO.OEO
Time
-------
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: M23 THERMAL INLET RUN#2 Analysis File: S976747
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Asphalt Roofing Project
M23TRAIN Date Received:
185-5-2A-D Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/01/97
10/16/97
n/a
S976745
BJG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976737
n/a
n/a
n/a
lAnaiyiei;/, "^'*' &&:&&: *t' '».,-' "S«»C ;^^^io^;i«" ^^fegs
2,3,7,8-TCDD
U,3J,8-PeCDD
1,2,3,4,7,8-HxCDD
U,3,6,7,8-HxCDD
U,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
23,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
U3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1^3,7,8,9-HxCDF
U,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1Z3,4,6,7,8,9-OCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.005
0.009
0.01
0.008
0.008
0.01
0.02
0.003
0.005
0.005
0.006 ,
0.004
0.006
0.006
0.007
0.01
0.01
^«ab ^'",;:^8|J^ .W^^sJ' ^fturober VL ^IEHPC~ \ ^f^^^;:^; }lfe*gs ;
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
0.01
ND
ND
ND
ND
ND
ND
ND
1
0.009
0.009
0.01
0.003
0.005
0.005
0.008
Page 1 of2
XZJ7J>SR rZOO. LARS 6.10M
Triangle Laboratories, Inc.®
801 Caprtola Drive * Durham, North CaroTma 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:13 10/21/97
80
-------
TLI Project:
Client Sample:
43431 Method 23 PCDD/PCDF Analysis (a)
M23 THERMAL INLET RUN#2 Analysis File: S976747
&itematStandards_ i „ _ Amfc:to/.r.....\...%.Ftecovery\ QCLImital^^Ratla!!!^ 8T.
13C12-2,3,7,8-TCDF
13Ci2-2,3,7,8-TCDD
l3C,2-12,3,7,8-PeCDF
I3Cl2-lA3,7,8-PeCDD
I3C,2-l,2,3,6t7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
l3C12-123,4,6,7,8-HpCDF
13Ci2-U3,4,6,7,8-HpCDD
13C12-1A3,4,6,7,8,9-OCDD
Surrogate Standards (Type A) ::".,Ar
37Clt-2,3,7,8-TCDD
13C12-2,3,4,7,8-PeCDF
l3C12-l,2,3,4,7,8-HxCDF
13C,2-l,2,3,4,7,8-HxCDD
13C,2-l,2,3,4,7,8,9-HpCDF
Jteaat»StaiKfa«Js"CT^A> \'^
13Ci2-l,2^,7,8,9-HxCDF
I3C,2-2,3,4,6,7,8-HxCDF
.f^^^Bda^^V^.^
13C,2-1,2^,4-TCDD
13C,2-l,2,3J,8,9-HxCDD
^ —-..—
4.0
3.6
32
3.1
3.9
3.7
3.4
35
7.5
'^p^- 5*
3.9
3.4
3.7
3J
3.9
^^W^'':S
3^
3.9
J^RV^
99.4
90.6
79.2
77.0
97.0
91.5
84.9
97.1
93.9
|;v; % Racoverj
98.4
85.7
91.8
87.2
97.8
lpP^s» ™**5«?'i'®'i
87.4
96.5
^: ' ^i**
•
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
ft^S&"*» '
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
40%-130%
40%-130%
$$£z: ,
0.76
0.82
1.51
1.49
0.49
122
0.40
1.01
0.85
1.47
0.48
125
0.43
iRafioV^:
0.49
0.49
;Ratk>
0.82
122
20:23
21:11
24:42
25:50
28:29
29:12
31:13
32:04
34:35
1 *rr,
21:12
25:27
28:22
29:07
32:25
£"£«&*
29:43
28:59
,/ iif/
20:58
29:29
Flags
—
-\ &*&
—
,.+ Flags
—
* f
Data Reviewer.
Page 2 of2
10/21/97
X237J>SR vZOO. LARS 6.10.04
Triangle Laboratories, Inc.*
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:13 10/21/97
Ot- 81
-------
Data Review By:
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
0.60
Page No.
10/21/97
Listing of S976747B.dbf
Hatched GC Peaks / Ratio / Ret. Tine
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..
ID.. Flags.
TCDF
304-306
D
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
320-322
37C1-TCDD
328
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
WH
0
NL
WL
WL
WH
WH
WH
3
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
0:00
20:25
20:36
22:49
Peaks
0:00
17:02
19:11
19:55
20:23
20:52
21:36
22:17
22:38
Peaks
0:00
18:17
18:31
18:43
19:03
19:17
19:20
19:58
20:54
21:09
21:30
21:41
21:46
21:51
Peak
0.
RO
RO
RO
0.
RO
RO
RO
,65-0.89
0
0
1
2
.97
.65
.02
.96
1
4
.27
.08
0.90
0
0
.48
.00
65-0.89
0
.94
0.47
0.51
0.76
0.76
RO
0,
.81
0.93
0.83
0.85
1
1
3
.27
.84
.52
7.42 3.21
1,453.10 626.09
10.09 4.53
2.05
1.54
7.84
0.825-1.102
0
1
.000
.002 2378-TCDF AN
1.011
1.119
0.951-1.049
0.000
0.836
0.941
4.21 0.977
827.01 1.000 13C12-2378-TCDF ISO
S.56 1.024
1.060
1.093
1.
110
1,470.61
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
3.
0.
2.
2.
86
78
09
19
49
94
28
81
54
50
43
73
53
41
1.06
3.08 1.35
0.41
0.41
1.
0.
0.
0.
0.
1.
0.
0.
0.
0.
3.
10
87
57
65
60
43
12
97
30
30
08
0.856-1.059
0.
1.73 0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
000
863
874
884
899
910
913
943
987
998
015
024
028
031
0.906-1.094
DC
DC
NL
SN
0:00
19:28
19:38
19:55
21:12
0.
0.
3.
1.
888.
58
52
46 3.46
33 1.33
10 888.10
0.
0.
0.
0.
1.
000
919
927
940
001 37C1-TCDD STJR1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:1410/21/97
82
-------
Page No.
10/21/97
Listing of S976747B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..
ID.. Flags.
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
D
340-342
13C12-PeCDF
352-354
352-354
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
SN
SN
13
NL
SN
SN
SN
SN
5
ML
SN
SN
SN
SN
SN
SN
SN
SN
0
ML
SN
6
21:28
21:32
21:38
21:40
21:45
21:50
21:51
22:03
22:08
22:27
22:39
22:49
Peaks
0:00
19:52
20:12
20:29
20:58
21:11
21:32
21:43
21:53
21:59
Peaks
0:00
22:59
23:20
23:26
24:10
25:05
25:30
26:01
26:12
Peaks
0:00
23:48
24:21
24:42
25:00
25:27
26:15
26:26
Peaks
0.
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
1.46 1.46
1.24 1.24
1.56 1.56
0.74 0.74
0.75 0.75
0.31
0.33
1.01 1.01
1.50 1.50
0.72 0.72
1.50 1.50
1.02 1.02
904.39
65-0.89
1.
1.
1.
0.
0.
0.
0.
4.
0.
72
27
89.
47
82
82
84
39
42
1.93
»w_
32-1.78
0.
0.
1.
0.
1.
4.
1.
0.
0.
90
57
81
29
26
76
28
34
75
0.83
6.60 4.75
1.40 1.49
1.08
1,108.94 498.15
1,070.60 482.73
19.14 8.74
0.90
0.64
0.76
2,206.68
0.59
0.43
0.41
0.12
1.45
0.43
2.30
0.33
0.72
0.00
32-1.78
1.
1.
1.
1.
1.
1.
0.
1.
15
33
20
51
73
47
82
49
0.25
5.27 3.01
5.10 3.10
994.76 598.72
7.93 5.02
826.93 491.62
0.38
3.71 2.22
1,843.70
0.
3.73
0.79
610.79
587.87
10.40
0.
0.
2.26
2.58
396.04
2.91
335.31
1.49
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
013
017
021
023
027
031
031
041
045
060
069
077
906-1.094
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
000
938
954
967
990 13C12-1234-TCDD
000 13C12-2378-TCDD
017
025
033
038
RSI
IS1
907-1.080
0.
0.
0.
0.
0.
1.
1.
1.
1.
000
930
945
949
978
016
032 23478-PeCDF
053
061
AN
838-1.162
0.
0.
0.
1.
1.
1.
1.
1.
000
964
986
000 13C12-PeCDF 123
012
030 13C12 -PeCDF 234
063
070
IS2
SOR2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:1
'21/97
-------
Page No.
10.21/97
Listing of S976747B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z..-. OC.Log Omit Why ..RT. OK Ratio Total. Area... Area. Peak. l. . Area. Peak. 2. . Rel.RT Confound. Name.. ID.. Flags.
PeCDD
356-358
356-358
13C12-P6CDD
368-370
368-370
HXCDF
374-376
D
D
D
374-376
13C12-HXCDF
384-386
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
d
d
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
0
ML
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
0
NL
SN
SN
SN
SN
0:00
24:33
25:01
25:16
26:23
Peaks
0:00
25:50
25:58
26:22
Peaks
0:00
27:31
27:33
27:50
28:00
28:13
28:23
28:30
28:35
29:00
29:15
29:18
29:27
29:35
29:45
29:51
30:08
30:14
30:20
Peaks
0:00
27:29
27:53
28:22
28:29
28:42
28:59
29:24
29:28
29:33
1
RO
RO
RO
RO
RO
1
RO
RO
1,
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
Aoove:
.32-1.78
1.00
1.10
1.08
1.91
1.20
.32-1.78
0.85
1.49
1.39
0.83
.05-1.43
1.25
0.66
0.85
1.51
0.73
0.33
0.89
1.05
2.27
1.38
0.47
1.25
1.10
1.17
2.00
1.26
0.98
0.93
0.55
43-0.59
0.85
0.36
0.40
0.48
0.49
0.68
0.49
0.58
0.32
0.54
yeti;* / re^uu toj.j.ows --•
0.16
0.36
0.69
0.28
0.39
0.00
0.18
542.03 324.42
52.19 30.31
0.95
594.22
0.90
0.98
0.40
0.87
0.52
0.33
1.77
1.56
0.34
3.50
0.42
0.54
0.21
0.39
0.54
0.43
0.98
0.45
0.38
0.00
0.89
2.96 1.00
0.68
756.25 245.09
858.62 283.92
1.99 0.90
790.45 259.72
1.17
1.04
0.94
0.921-1.026
0.000
0.950
0.968
0.978
1.021
0.845-1.155
0.000
217.61 1.000 13C12-PBCDD 123
21.88 1.005
1.021
0.956-1.053
0.000
0.966
0.967
0.977
0.983
0.991
0.996 123478-HxCDF
1.001 123678-HXCDF
1.004
1.018 234678-HxCDF
1.027
1.029
1.034
1.039
1.044 123789-HXCDF
1.048
1.058
1.061
1.065
0.860-1.140
0.000
2.76 0.965
0.979
511.16 0.996 13C12-HXCDF 478
574.70 1.000 13C12-HXCDF 678
1.32 1.008
530.73 1.018 13C12-HXCDF 234
1.032
1.035
1.037
IS3
AN
AN
AN
AN
SUR3
IS4
ALT2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:1410/21/97
-------
Page No.
10/21/97
Listing of S976747B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
H_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
384-386
HXCDD
390-392
D
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
13C12-HpCra?
418-420
DC
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
6
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
0
NL
SN
SN
SN
SN
6
NL
SN
WH
WH
0
NL
29:43
29:59
30:07
Peaks
0:00
27:48
27:58
28:02
28:06
28:13
28:22
28:35
28:43
28:58
29:13
29:20
29:24
29:37
29:41
29:50
29:55
Peaks
0:00
28:35
28:40
28:52
29:07
29:12
29:29
29:42
29:47
29:53
29:58
Peaks
0:00
32:18
32:51
32:56
Peaks
0:00
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
0.
RO
0
0
0
.49
.77
.70
05-1.43
0
1
0
0
1
1
0
1
0
0
0
0
1
0
0
0
0
.43
.48
.46
.38
.06
.03
.67
.36
.70
.93
.76
.74
.00
.23
.82
.47
.73
622
1
.62 205.72
.24
1.51
416.90 1
1
1
.043 13C12-HXCDF 789 ALT1
.053
.057
3,032.89
0
0
0
0
0
0
1
1
0
0
1
0
0
0
0
0
0
0
.40
.47
.49
.11
.35
.60
.82
.58
.29
.74
.08
.42
.31
.33
.83
.45
.20
.00
05-1.43
0
1
0
2
1
1
1
1
1
1
0
.71
.34
.59
.29
.25
.22
.22
.36
.54
.87
.59
0
3
0
0
567
669
734
4
1
0
0
1.982
HXCD
.43
.62 2.07
.36
.85
.86 314.98
.21 367.76
.97 403.39
.98 2.87
.88 1.29
.69
.40
.52 .
Dl Wrrf^PTP Prtl 1 rmfTT ——
88-1.20
1
1
0
1
.57
.89
.70
.04
1
0
1
1
0
.84
.94
.90
.37
.00
37-0.51
0
.77
1
.84
0.950-1.015
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
.000
.952
.958
.960
.962
.966
.971
.979
.983
.992
.001 123678-HXCDD AN
.005
.007
.014
.017
.022
.025
0.966-1.034
0
1.55 0
0
0
252.88 0
301.45 1
331.58 1
2.11 1
0.84 1
1
1
.000
.979
.982
.989
.997 13C12-HXCDD 478 SDR4
.000 13C12-HXCDD 678 IS5
.010 13C12-HXCDD 789 RS2
.017
.020
.023
.026
0.996-1.046
0
1
1
1
.000
.035
.052
.055
0.936-1.128
0
.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:14 10/21/97
85
-------
Page No.
10/21/97
Listing of S976747B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
394.83 1.000 13C12-HpCDF 678 IS6
1.18 1.007
1.014
1.026
292.60 1.038 13C12-HpCDF 789 SUR5
1.32 1.047
N
418-420
HpCDD
424-426
D
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
D
442-444
OCDD
458-460
D
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
d
DC
SN
SN
4
NL
SN
SN
WH
0
NL
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
0
NL
1
31:13
31:26
31:40
32:01
32:25
32:41
Peaks
0:00
31:28
32:04
32:20
Peaks
0:00
32:04
32:21
32:39
Peaks
0:00
32:11
32:23
32:33
34:40
35:05
35:37
35:43
Peaks
0:00
34:36
Peaks
0:00
34:35
Peak
RO
RO
RO
RO
0
RO
RO
RO
0
RO
RO
RO
0.
RO
RO
RO
RO
RO
0.
0.
RO
0.40
1.15
0.31
0.34
0.43
0.65
.88-1.20
1.34
1.12
1.23
0.27
.88-1.20
1.33
1.01
1.80
0.42
76-1.02
0.76
0.06
1.17
0.52
0.85
2.96
0.38
1.00
76-1.02
0.95
0.89
76-1.02
1.32
0.85
553.32
1.70
1.28
1.70
417.30
1.90
974.22
1.02
1.21
2.45
0.67
0.00
1.49
581.86
2.98
0.69
584.84
1.20
0.21
0.98
0.96
1.96
1.06
0.42
0.50
0.00
0.72
4.39
0.00
0.36
716.19
716.19
158.49
1.36
124.70
0.86
•
292.53
2.63
329.99
0.977-1.006
0.000
0.981
1.000 1234678-HpCDD
1.008
AN
0.969-1.031
0.000
289.33 1.000 13C12-HpCDD 678 IS7
1.46 1.009
1.018
Follows
.884-1.116
0.000
0.931
0.936
0.941
1.002 OCDF
1.014
1.030
AN
1.033
0.884-1.116
0.000
1.000 OCDD
0.997-1.006
0.000
386.20 1.000 13C12-OCDD
AN
IS8
Triangle Laboratories, Inc.® Analytical Services Division
801 CapKola Drive • Durham, North Carolina 27713
Phone; (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:1410/21/97
-------
Page No.
10/21/97
Listing of S976747B.dbf
Matched GC Peaks / Ratio / Set, Time
Compound/
M_Z.... Qc.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name. . ID.. Flags.
Column Description "Why* Code Description QC Log Desc.
M_Z -Nominal ion Hass(es)
. .RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
•* End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
Tile:S976747 #1-829 Acq:16-OCT-1997 13:08:39 Eli- Voltage SIS 70S Noise:352
303.9016 T:2 BSUB(256, 30, -3.0) PKD(9,S,5, 0. OS\,1408. 0,1. 00\,T,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL INLET SUJH2 TLI*43431 INJ. TIME - 13:11
1001
17:00 18:00 15:00 20:00 21:00
File:S976747 #1-829 Acq:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S No±ee:361
305.8987 T:2 BSUB(2S6,30,-3.0) PJO)(9,5,S,0.05\,1444.0,1.00\,T,T) Exp:£PCUS
TRIANGLE LABS Teit:H23 THERMAL ISLET SVN#2 TLI#43431 INJ. TIME - 13:11
1004
aol
60-,
22:00
40:
20:
17:00 18:00 15:00 20:00 21:00
riletS976747 #1-829 Acq:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S Koiae.-338
31S.9419 F:2 BSUB(256r30,-3.0) PlO>(9,5,S,0.05\,1352.0,1.00\,r,T) Exp-.EPCnS
TRIANGLE LABS Text:M23 THERMAL INLET £077*2 TLH43431 IKT. TIME - 13:11
1001
80:
40:
20:
22:00
0:
17:00 18:00 15:00 20:00 21:00
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317.9389 T:2 BSOS(256,30,-3.0) PXD(9,5,S,O.OS\,1440.0,1.00\,r,T) Efp:EPCOS
TRIANGLE LABS Teit:M23 THERMAL ISLET SVS#2 TLI#43431 X2K7. TIME - 13:11
100J
80:
40:
20j
22:00
0:
2l00
17.- 00 18:00 15:00 20:00
rile:S976747 #1-829 Acq:16-OCT-1997 13:08:39 EI+ Voltage SIR 70S
330.9792 T:2 Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL ISLET 5027*2 TLIt43431 ZKJ. TIME
100$ ._ _. ,-,_>« 10.AK IS,2O 19,4430:0520:26 20:52
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17:00 18:00 19:00 20:00
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TRIANGLE LABS Text:M23 THERMAL ISLET SO1T#2 TLH43431 HKT. TIME -
1001
22:00
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SO.
60.
40:
20:
0:
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.3.1S6
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Tiae
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.2.9E3
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lime
88
-------
File:S976747 #1-829 Acq:16-OCT-1997 13:08:39 EH- Voltage SIR
705 Noise -.24 5
319.8965 r:2 SSUS(2S6,30,-3.0) rXD(7,S,3,O.OS\,980 .0,1.00\,F,T) Exp:EPCUS
TRIANGLE LABS Teit:M23 THERMAL ISLET SUN* 2 TLIf43431 ISJ. TIME - 13:11
100S
•
80J
•
601
401
201
01
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^7.2E3
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331.9368 7:2 BSUS(256, 30, -3 .0) fKD(7 ,5,3,0 .OS\, 1616 .0,1. 00\,T,T) ExptEPCUS
TRIANGLE LASS Tej[t:M23 THERMAL ISLET RVN#2 TLH43431 ISJ. TIME = 13:11
1001
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70S Noise, 23 3
333.9338 Fs2 BSUB(256,30,-3.0) 9X0(7,5,3, 0.05%,932. 0,1. QO\,r,T) ExpiEPCOS
TRIANGLE LABS Text:M23 imtunr. TTCET SDN#2 TLIt43431 ISJ. TIME - 13:11
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file:S976747 #1-829 Acq:16-OCT-1997 13:08:39 E1+ Voltage SIR
70S Noise -.289
327.8847 F:2 BSUB(256,30,-3.0) fXD( 7,5,3, O.OS\,11S6. 0,1. 00\,F,T) Exp:EPCUS
TRIANGLE LABS Text:M23 T*VWfflr INLET RVN«2 TLH43431 ISJ. TIME • 13:11
1003
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401
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330.9792 T:2 Exp:EPCOS
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TRIANGLE LABS Te*t:M23 TBBOOL ISLET SUN#2 TLI#43431 UTJ. TIME - 13:11
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39
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Tile:S976747 tl-829 Acq:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S Noiae:182
339.8597 f:2 BSVS(2S6,30,-3.0) PKD(7,5,3,0.05\,728.0,1.00\,r,T) Exp.-EPCUS
TRIASSLE LABS Text:M23 THERMAL ISLET RU1H2 TLIf43431 HTJ. TIME = 13:11
100S.
A1.29E4 A4.15E3 A1.40E4
26: 00
23:00 24:00 25:00
Tile:S976747 tl-829 Acg:16-OCT-1997 13:08:39 EI+ Voltage SIR 70S Woiee:198
341.8567 T:2 BSUB(256,30,-3.0) PXD(7,S,3,O.OS\r792.0,1.00\rffT) Exp:EPCUS
TRIANGLE LASS Text:M23 THERMAL ISLET RUSt2 TLIt43431 £K7. TIME - 13:11
A1.19E4
23:00 24:00 25:00 26:00
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351.9000 r:2 BSVB(256,30,-3.0) PXD(7,5,3r0.05\r296.0,1.00\,r,T) Exp:EPCOS
TRIANGLE LASS Text:M23 THERMAL ISLET RUSt2 TLIt43431 IKT. TIME - 13:11
1004 AS 99E6
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TRIANGLE LASS Toxt:M23 THERMAL ISLET RVBt2 TLH43431 ZK7. TIME ' 13:11
1001
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sol
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File:S976747 tl-829 Acq: 16-OCT-1997 13:08:39 EI+ Voltage SIR 70S
330.9792 T:2 ExpsXPCOS
TRIASSLE LASS T«OCt:M23 THERMAL ISLET RWH2 TLIt43431 XK7. TIME - 13:11
22:40 23:19 23:37 34:15 24:35 24:5725:12. 25:35
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TSIANGLZ LASS Text:M23 THERMAL ISLET KOH2 TLH43431 INJ. TIME
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TRIANGLE LABS Text:M23 THERMAL ISLET SOmt2 TU»43431 ISJ.
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369.8919 T:2 BSUB(2S6,30,-3.0) PXD(7,S,3,O.OS\,268.0,1.00\,r,T)
TSTAIKU: LABS T«rt.-JC2J THERMAL ISLET f DM2 TLIt43431 ISJ.
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TSIASSLE LABS Teit:M23 •mwmar. rSLET SOS12 TLH43431 ISJ.
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91
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File:S976747 tl-475 Acq:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S Soiae:248
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TSIASSLE LASS Text.-K.2J THERMAL ISLET SUSt2 TLH43431 IKJ. TIME - 13:11
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File:S976747 tl-47S Acq:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S Soiae:199
375.8178 T:3 BSUB(256,30, -3. 0) PXD(7,5,3, 0.05%, 796. 0,1.00\,F, T) Exp-.EPCUS
TSIASSLE LASS Te*t:M33 THERMAL ISLET SOSf2 TLH43431 1X7. TIME - 13:11
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383.8639 T-.3 BSUB(256,30, -3.0) PXD(7,S,3,0.05\,996.0,l.QO\rF,T) Erp:EPCUS
TSIASSLS LASS Text:H23 THERMAL ISLET SU1H2 TLH43431 JK7. TIKE - 13:11
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00:
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27:24 27:36 27:48 28:00 28:12 28:24 38:36 38:48 39:00 39:12 39:34 29:36 39:48 30:00 30:12
File:3976747 tl-475 Acg:16-OCT-1997 13:08:39 EH- Voltage SIS 70S So±ae:293
385.8610 F:3 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,1172.0,1.00\,FrT) Exp:EPCUS
TSIASSLE LASS Text:M23 THERMAL ISLET SOSt2 TLH43431 XKJ. TIME - 13:11
1004 A5.75E6 A5.31E6 ^1.9E6
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File:S976747 tl-475 Acq:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S
392.9760 F:3 Eip-.EPCOS
TSIASSLE LABS Taxt:M23 THERMAL ISLET SUSt2 TLH43431 XK7. TIME - 1J.-11
27:25 37:3937:5028,00 28il6 28:39 28j58 29:20 29:47 30:13 ^2. OE6
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40:
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Tile:S976747 tl-475 Acq:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S
45.7555 T:3 ExptEPCUS
TSIASGLE LASS T
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tlIa:S976747 #1-475 Acq:lb-OCT-1997 13:08:39 El+ VoltageSIM 70S Noise:!OS
389.8156 F:3 3SUB(2S6,30, -3. 0) PKD(7,5,3,0.051,136.0,1.00\,P,T) SxpiEPCUS
TRIANGLE LABS Text:M23 THERMAL ISLET XWH2 TLIH3431 2X7. TIME - 13:11
10 OS,
so:
27:48 28sOO 28:12 38:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
Til*:S976747 tl-47S Acq:16-OCT-1997 13:08:39 XX+ Voltage SIX 70S Boiae:2S7
391.8127 T-.3 BSUB(256,30,-3.0) PKD(7,5,3,0.051,1028.0,1.00\,f,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL INLET SUJH2 TLIM3431 OCT. TIME - 13:11
100*
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
rile:S976747 fl-475 Acq:16-OCT-1997 13:08:39 ZI+ Voltage SIX 70S Noiae:120
401.8558 T:3 BSUB(256,30, -3.0) PXD(7,5,3,0.05\,480.0,1.00\,T,T) Exp-.EPCVS
TRIANGLE LABS Text;M23 THERMAL ISLET RVSil TLIt43431 HU. TIME " 13:11
1004 A4.Q3E6
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80.
60.
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29:36 29:48
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
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403.8529 T:3 BSUS(256,30,-3.0) PXD(7,5,3,O.OS\,676.0,1.00\,T,T) Exp-.EPCUS
TSIAKSLE LABS Text.iM23 THERMAL ISLET SU1H2 XLH43431 OCT. TIME * 13:11
29:36 29:48
100!
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60.
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27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
TH0SS976747 41-475 AojslS-OCT-J.997 13:08:39 EH- Voltage SIX 70S
392.9760 T:3 ElptEPCDS
TSIASSLE LABS Tert:M23 THERMAL ISLET RUHt2 XLIt43431 OCT. TIME - 13:11
O.OEO
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29:48
Time
uu 93
-------
r±le:S976747 #1-397 Acg:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S Soi.Be-.706
407.7818 Ts4 BSOS(2S6,30,-3.0) PKD(7,Sr3fO.OS\r2824.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LASS Text:H23 TSESMAL ISLET SW ^-^-
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tile:S976747 tl-3S7 Acq:lS-odf-l9$7 13:08:39 JgJ1* Voltage sSs 70S Noiae:333
423.7766 F:4 BSUS(256,30, -3.0) PXD(7,S,3t0.05\,1332.0r1.00\rTfT) ExpsEPCUS
TRIANGLE LASS Text:M23 THERMAL ISLET SVS*2 TLIf 43431 IKT. TIME - 13! 11
1004 A1.47E4
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Tile:S976747 tl-397 Aaj:16-OCT-1997 13:08:39 EI+ Voltage SIR 70S Noiae:250
425.7737 T:4 SSUS(256,30,-3.0) PKD(7,5,3,0.05\,1000.0,1.00\,T,T) Ezp:EPCUS
TRIANGLE LASS TeJCt:M23 THERMAL ISLET SUNt2 TLH43431 HKT. TIME - 1J.-11
1001 A1.26E4
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31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
Tile:S976747 tl-397 Acq:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S Soiae:486
435.8169 T:4 BSUS(256,30, -3.0) PB>(7,5,3,0,OS\,1944.0,1.00\,r,T) Exp:EPCVS
TRIANGLE LASS Text:M23 THERMAL ISLET RVNt2 TLH43431 IKT. TIME - 13:11
A2.93E6
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rile:S976747 tl-397 Acq:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S Soiae:363
437.8140 F:4 SSO3(256, 30, -3.0) PKD(7, 5,3, 0.051,1452.0,1.00\,f,T) Exp:EPCDS
TRIANGLE LASS Text:M23 THERMAL INLET StOTf2 TLI943431 IKT. TIME - 13:11
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ril»tS976747 tl-397 Aoqtl6-OCT-1997 13:08:39 EH- Voltmgm SIS 70S
430.9729 T:4 ZxpsttCOS
TRIANGLE LASS TeXt:M23 THERMAL ISLET SOSt2 TLII43431 1ST. TIME - 13:11
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31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32 36 Time
95
-------
file:S976747 91-397 Acq:16-OCT-1997 13:OBs39 EI+ Voltage SIS 70S Xoiae:261
441.7428 f:4 SSU3(2S6,30,-3.0) PXD(7, 5,3,0. 05\,1044. 0,1. 00*,F,T) Exp:EPCUS
TXIAKGLE LASS Tezt:M23 THERMAL ISLET BOStS TLI*43431 XW. TIME - 13 ill
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File:S976747 tl-397 Acg:16-OCT~1997 13t08:39 EI+ Voltage SIX 70S Oo±ae:339
443.7399 ts4 BSUB(256, 30, -3. 0) PXD(7,S,3,O.OS\,13S6.0,1.00\,r,T) £xp:EPCOS
TRIANGLE LASS Tart.-M2J THERMAL ISLET SUNf2 TLIf43431 HKT. TIKE ** 13:11
10 0\
90.
70-
60.
50J
40.
35:00
101
Al.60E4
AS.57E3
AJ..OSZ4 I I A8.90E3
31 00 32:00 33:00 34:00
r±le:S976747 tl-397 Acq:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S
430.9729 Ts4 Exp-.EPCUS
TSIANGLE LASS Text.iM23 THEBMAL ISLET SUNtl TLII43431 HTJ. TIME '
35:00
31:00 32:00 33:00 34:00
rilo:S976747 tl-397 Acqsl6-OCT-1997 13:03:39 EI+ Voltage SIX 70S
13.6775 Fi4 ExptSPCOS
TRIANGLE LASS Text:M23 THERMAL ISLET XVSi2 TLX943431 XKT. TIME
OC
35:00
13:11-
31 00
32s 00
33100
34i 00
35:00
2.0E4
ll. 8E4
11. 6E4
'-.1.4E4
'.1.2E4
19.8E3
.7.8E3
.5.9E3
.3.9E3
2.0E3
O.OEO
Time
O.OEO
Time
96
-------
F3.le:S976717 #1-397 Acq:16-OCT-lS97 13:08:39 EI+ Voltage SIR 70S Noife:174
457.7377 F:4 BSUB(256,30, -3. 0) ?KD(7,5,3, 0. 05%, 696.0,1.00\,T, T; ExpsEPCOS
TRIANGLE LABS Teit:M23 TBESMAL INLET SUN*2 TLIf 43431 INJ. TIME - 13:11
1003, A2.07E4
34,30 34:36 34:42 34:48 34:54
ril»:S976747 H-397 Acg: 16-OCT-1997 13:08:39 EI+ Voltage SIS 70S Noi*e:184
459,7348 Ts4 BSUB(256,30,-3.0) PXD(7,5,3, 0.05%, 736.0,1.00\,r,T) ExpsEPCUS
TSIANGLE LASS Text:M23 THERMAL INLET BONf2 TLH43431 HKT. TIME - 13:11
1003k A2.32E4
35:00
35 06
_3.5E3
34:30 34:36 34:42 34:48 34:54
r±le:S976747 tl-397 Aeq:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S Soioe:126
469.7779 T:4 BSUB(2S6,30,-3.0) PXD(7,5,3,0.05\,504.0,1.00\,r,T) ExpiEPCDS
TRIANGLE LABS Text:H23 TSEKMAL INLET SUNi2 TLI*43431 INJ. TIME - 13:11
1004 A3.JOE6
so:
60.
40.
201
35:00
O.OEO
35 06 Time
4.5E5
'.3.6ES
.2.7E5
'.1. 8E5
.9.0E4
34:30 34:36 34:42 34:48 34:54 35:00
r±le:S976747 fl-397 Aoq:16-OCT-1997 13:08:39 EI+ Voltage SIS 70S Xoiae:96
471.7750 T:4 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,384.0,1.00\,r,T) ExpsEPCOS
TRIANGLE LABS Tezt.-M2J THERMAL INLET BVNf2 TLI»43431 IKJ. TIME - 13:11
1003, A3.$6E6
O.OEO
35 06 T±ae
r5.4E5
.4.3ES
'.3.3ES
.2.2E5
.1.1E5
34:30 34:36 34:42 34:48 34:54
r±le:S976747 tl-397 Acc[sl6-OCT-1997 13:08:39 EI+ Voltage SIS 70S
430.9729 fs4 Elp:EPCUS
TRIANGLE LABS Tezt:M23 THERMAL INLET BUNK TLH43431 TKT. TIME -
35:00
35
O.OEO
06 Time
1003
80.
60.
40.
20.
0.
34:31
34:30
34:36
34:42
34:48
34-54
35:00
11.2E6
.9.3E5
.6.2ES
.3.1E5
O.OEO
35 06 Time
97
-------
ChanraL I 339,3792 Peak top
Height 1,87 volts Span £$ppii
Systsa file r»ss€
Data flLs naie
Resolution
Grcwnuiber
Ret, aassss 892,3825
fl 293
6 384
C 386
0 316
E 318
F 328
322
H 328
J 331
K 332
I 348
N 342
0 352
P 354
9 356
R 358
E?cys
H-.S37S741
2
Eh
VOL1HGE
418,3768
I 378
U 376
V 418
Ref, iass 416,3768 Pe^< top
Height ,34^lts Span 289 ppt
9S
-------
File:S976748 #1-397 Acq:16-OCT-1997 13:48:03 EH- Voltage
70S~
457.7377 F:4 Exp:EPCUS
Sample Text:M23 THERMAL INLET RUN#3
100%
90 j
TLI#43431 INJ. TIME = 13:50 File Text:M23
34:27 34 55
THERMAL I»
_4.7E3
34:48 -35:00 35:12
35:24 35:36
33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
File:S976748 #1-397 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:M23 THERMAL INLET RUN#3 TLI#43431 INJ. TIME = 13:50 File Text:M23
34:37
THERMAL I»
_5.3E3
" ' i i i i i i [ i i i i i i i i • i i I i i i
33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35
j-r-r
:36
.O.OEO
Time
-------
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: M23 THERMAL INLET RUN#S Analysis File: S976748
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Asphalt Roofing Project
M23TRAIN Date Received:
185-5-3A-D Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor
Blank File:
Analyst:
09/29/97
10/01/97
10/16/97
n/a
S976745
BJG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976737
n/a
n/a
n/a
Anafytes •\'%?>4%> "/.. *
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
23,7,8-TCDF
1,2,3,7,8-PeCDF
23,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
U,3,7,8,9-HxCDF
U3,4,6,7,8-HpCDF
U3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
j^^&^ij&£
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Arnt. (ng)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
j^v *f4>Amt:^B^^
EMPC
ND
ND
ND
ND
ND
ND
ND
& , *''";$&*$*„ >"£l$*C -ft^t» ' RT Ffegs -
0.005
0.01
0.01
0.008
0.009
0.01
0.02
0.003
0.006
0.006
0.006
0.005
0.006
0.007
0.008
0.01
0:01
pfeaia&ar ;£^."iiBiU*crt'V , ""' ' """ . "f^lags
<%f -.-$•? s ^' v% •>•«£... -.-. "•"• \*-t *. f f * s
0.006
0.01
0.009
0.01
0.003
0.006
0.006
0.009
Page 1 of2
X2J7J>SR rZOO. LARS 6.10.M
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:14 10/21/97
100
-------
v? >"
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: M23 THERMAL INLET RUN#3 Analysis File: S976748
tut ^tMfS1 ,j ...r &&*** ""v^""*?
?ltelt^l.^^:~arc^xvO;v -^ <
13C,r2,3,7,8-TCDF
I3C,2-2,3,7,8-TCDD
13C12-l,2,3,7,8-PeCDF
13C12-l,23,7,8-PeCDD
l3C12-lA3,6,7,8-HxCDF
13C12-lA3,6,7,8-HxCDD
l3C,2-l,23,4,6,7,8-HpCDF
13Cirl,23A6,7,8-HpCDD
°Cu-lA3A6;7^-OCDD
^faaL {ngHSI
4.2
3.5
3.1
2.9
4.2
3.8
3.4
3.8
6.7
PWJRWOVBT
104
87.2
76.9
73.0
104
96.1
85.5
95.0
84.3
r"flteiiagg£
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
Ratio
0.77
0.80
1.54
1.47
0.49
1.19
0.42
0.98
0.87
wHTOMtfMv f J v.
20:23
21:10
24:42
25:49
28:28
29:11
31:12
32:04
34:34
Rags
&fi*fc
"CL-^J.S-TCDD
13dr2,3,4,7,8-PeCDF
l3C12-lA3,4,7,8-HxCDF
13CI2-1^3,4,7,8-HxCDD
13CI2-1^3,4,7,8,9-HpCDF
4J2
3.5
3.7
3.5
3.9
106
86.6
92.9
86.7
97.9
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
1.48
0.49
0.43
21:12
25:27
28:22
29:07
32:25
QC Limits
13C12-l,23,7,8,9-HxCDF
3.8
4.1
94.1
103
40%-130%
40%-130%
0.49
0.49
29:43
28:59
13C12-1,23,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
0.82
120
20:58
29:29
Data Reviewer.
J
Page 2 of2
10/21/97
X237 J>SR vZOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:1410/21/97
101
-------
Daca Review By:
Initial ....Date...
|C- (0,2^ 4 L
Calculated Noise Area:
0.56
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/21/97
Listing of S976748B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name.. ID.. Flags.
TCDF
304-306
D
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
320-322
37C1-TCDD
328
328
DC
d
DC
DC
DC
DC
DC
DC
. DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
0
NL
SN
WH
3
NL
SN
SN
SN
SN
SN
WH
WH
1
NL
WL
SN
SN
8
0:00
20:23
20:33
Peaks
0:00
19:53
20:23
20:52
21:10
22:39
Peaks
0:00
18:18
18:55
20:32
21:12
21:21
21:48
22:26
22:43
Peak
0:00
19:04
19:15
19:37
21:12
21:31
21:39
21:43
21:52
22:03
22:07
22:38
Peaks
0.
RO
RO
RO
0.
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
0.
,93
0.59
2.03
1
2
0
0
.22
.51
.67
.00
65-0.89
0.
0.
0.
0.
0.
0.
91
76
77 1
42
50
59
1
*!*,»_ .
1
9
,444
5
2
4
.459
nv*m
65-0.89
1.
1.
0.
0.
0.
0.
1.
1.
0.
05
02
26
75
54
09
03
16
24
.22
.43 4.07
.44 628.47
.75 2.50
.07
.74
.62
0.71
1.79 1.03
0.41
1.38
1.93
0.11
0.69
0.57
0.51
0.825-1.102
0.000
1.000 2373-TCDF AN
1.008
0.951-1.049
0.000
5.36 0.975
815.97 1.000 13C12-2378-TCDF ISO
5.89 1.024
1.038
1.111
0.856-1.059
0.000
1.01 0.865
0.894
0.970
1.002 2378-TCDD AN
1.009
1.030
1.060
1.073
1.79
0.57
0.42
1.
6.
870.
2.
1.
1.
0.
1.
0.
1.
886.
32 1.32
26 6.26
80 870.80
78 2.78
72 1.72
84 1.84
90
00 1.00
49
05 1.05
77
0.906-1.094
0.000
0.901
0.909
0.927
1.002 37C1-TCDD SDR1
1.017
1.023
1.026
1.033
1.042
1.045
1.069
riangle Laboratories, Inc.® Analytical Services Division
V Capftola Drive • Durham, North Carolina 27713
'hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:14 10/21/97
102
-------
Page Mo.
10/21/97
Listing of S976748B.dbf
Matched GC Peaks / Ratio / Rec. Tin
Compound/
M_Z OC.Log Omit Why ..RT. OK Ratio Total. Area...
Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-TCDD
332-334
332-334
PeCDF
340-342
340-342
13C12-PeCDF
352-354
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
SN
4
ML
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
0:
19:
19:
20:
21:
21:
22:
00
04
52
58
10
32
13
0.
RO
RO
RO
RO
65-0.89
1
0
1
0
0
0
0
Peaks
0:
22:
22:
23:
23:
23:
23:
24:
24:
25:
25:
26:
26:
26:
00
24
34
21
34
44
47
06
21
07
21
12
22
27
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.69
.48
.54
.82 1
.80
.92
.69
2
32-1.78
0
2
2
1
2
0
0
1
2
0
0
3
0
0
.94
.29
.57
.50
.33
.55
.29
.31
.11
.46
.49
.35
.44
.55
Peaks
0:
22:
23:
24:
24:
25:
00
36
48
20
42
01
1.
RO
RO
RO
25:27
352-354
PeCDD
356-358
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
6
NL
SN
SN
SN
SN
SN
SN
HH
26:
26:
27
48
RO
0
1
5
,053
978
18
1
.80
.38
.12 4.44
.05 474.47
.81 435.20
.04 9.37
.82
0.906-1.094
0
0
2.89 0
578.58 0
543.61 1
10.19 1
1
.000
.901
.939
.991 13C12-1234-TCDD RSI
.000 13C12-2378-TCDD IS1
.017
.050
,055.02
TCDD / PftCDF Follows — — —
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.26
.71
.36
.50
.54
.20
.26
.84
.46
.31
.71
.51
.13
.49
.00
32-1.78
0
2
1
1
1
1
1
1
1
Peaks
0:
23:
23:
00
54
59
24:44
25:
25:
26:
26:
04
20
08
42
1.
RO
RO
RO
RO
RO
RO
.91
.18
.05
.33
.54
.65
.48
.39
.97
1
32-1.78
1
0
0
2
2
2
1
1
.50
.13
.32
.77
.67
.57
.06
.69
0
1
3
5
917
7
770
3
0
.707
.16
.15
.80 2.31
.31 3.03
.01 555.93
.09 4.41
.63 459.48
.47 2.02
.92
.31
0.907-1.080
0
0
0
0
0
0
0
0
0
1
1
1
.000
.907
.914
.945
.954
.961
.963
.976
.986
.017
.026
.061
1.067
1
.071
0.838-1.162
0
0
2.20 0
2.28 0
361.08 1
2.68 1
311.15 1
1.45 1
1
.000
.915
.964
.985
.000 13C12-PeCDP 123 IS2
.013
.030 13C12-PeCDF 234 SUR2
.071
.085
0
0
.25
.12
0.23
0
0
0
0
0
.77
.23
.54
.56
.43
0.921-1.026
0
0
0
0
0
.000
.926
.929
.958
.971
0.981
1
1
.012
.034
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:14 10/21/97
103
-------
page No. 3 Listing of S976748B.dbf
10/21/97 Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why . .RT. OK Ratio Total. Area. .. Area. Peak. 1. . Area. Peak. 2. . Rel.RT Compound. Name. .
356-358 0 Peaks 0.00
13C12-PeCDD
368-370
368-370
HXCDF
374-376
D
374-376
13C12-HXCDF
384-386
384-386
HXCDD
390-392
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
2
NL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
HH
0
NL
SN
SN
SN
SN
6
NL
SN
SN
0:00
24:51
25:49
25:58
26:43
Peaks
0:00
27:11
27:16
27:21
27:25
27:40
27:55
27:57
28:18
28:29
29:01
29:06
29:19
29:25
29:37
29:45
30:19
Peaks
0:00
27:31
28:22
28:28
28:39
28:48
28:59
29:12
29:23
29:28
29:43
Peaks
0:00
27:47
28:28
1
RO
RO
RO
1
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
.32-1.78
1.20
2.00
1.47
1.43
0.71
.05-1.43
0.80
0.49
6.80
9. 25
3.38
0.22
1.00
1.52
0.76
0.98
1.20
0.12
1.25
1.17
0.18
0.86
0.47
43-0.59
1.34
0.39
0.49
0.49
0.47
0.22
0.49
0.98
0.32
0.14
0.49
05-1.43
0.65
0.34
3.00
ID. . Flags
0.845-1.155
0.20
0.59
487.99 290.42
49.15 28.91
0.41
537.14
0.63
0.31
0.11
0.09
0.18
0.20
0.36
0.47
0.56
0.70
2.07
0.09
0.36
0.26
0.13
0.76
0.27
0.00
0
0
197 . 57 1
20.24 1
.000
.963
.000 13C12-PeCDD 123
.006
IS3
1.035
0.956-1.053
0.000
0.955
0.958
0.961
0.963
0.972
0.981
0.982
0.994
1.
1.
1.
1.
1.
1.
1.
1.
001 123678-HxCDF
019 234678-HxCDF
022
030
033
040
045 123789-HxCDF
065
AN
AN
AN
0.860-1.140
0.62
1.51
682.36 224.82
765.57 252.41
3.59 1.15
1.30
704.67 230.60
2.57 1.67
1.04
0.80
558.78 183.30
2,717.54
0.40
0.20
0.43
0.
0.
457.54 0.
513.16 1.
2.44 1.
1.
474.07 1.
1.70 1.
1.
1.
375.48 1.
000
967
996 13C12-HXCDF 478
000 13C12-HXCDF 678
006
012
018 13C12-HXCDF 234
026
032
035
044 13C12-HXCDF 789
SUR3
IS4
ALT2
ALT1
0.950-1.015
0.
0.
0.
000
952
975
Triangle Laboratories, Inc.® Analytical Services Division
301 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:1410/21/97
104
-------
Page No. 4
10/21/97
Compound/
M_Z.... QC.Log Omit Why
Listing of S976748B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK .Ratio Total.Area— Area.Peak. 1.. Area.Peak.2.. Rel.RT Confound.Name.. ID.. Flags.
390-392
13C12-HXCD0
402-404
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12 -HpCDD
436-438
436-438
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SK
SN
SN
SN
SN
SK
WH
0
NL
ML
WL
SN
SN
SN
SN
5
NL
0
NL
SN
2
NL
0
NL
SN
SN
SN
2
28:37
28:44
29:01
29:07
29:24
29:27
29:56
Peaks
0:00
28:05
28:10
28:18
28:35
28:43
28:58
29:07
29:11
29:29
29:47
29:58
Peaks
0:00
Peaks
0:00
31:12
32:25
32:55
Peaks
0:00
Peaks
0:00
31:30
32:04
32:19
32:29
32:32
Peaks
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
0.
RO
0.
RO
0.
RO
0.
RO
RO
RO
RO
0.91
0.59
1.10
2.68
0.85
0.15
0.81
05-1.43
0.62
5.00
0.80
0.62
0.74
1.58
1.14
1.27
1.19
1.20
1.19
0.34
88-1.20
1.34
37-0.51
0.60
0.42
0.43
0.49
88-1.20
1.54
88-1.20
1.05
2.89
0.98
O.SS
2.17
0.60
0.38
0.23
0.86
0.49
0.63
0.11
0.54
0.00
0.33
0.11
0.36
0.23
1.82 1.01
0.43
0.60
493.71 276.06
585.42 317.79
612.50 333.95
2.26 1.23
0.85
1,695.71
1.94
0.00
1.64
464.61 137.92
350.66 105.24
2.12
815.27
0.71
0.00
1.33
0.73
474.35 235.34
1.88 0.96
0.59
0.67
476.23
0.981
0.985
0.994
0.998 123478-HxCDD
1.007
1.009 123789-HxCDD
1.026
0.966-1.034
0.000
0.962
0.965
0.970
1.37 0.979
0.984
0.993
217.65 0.998 13C12-HXCDD 478
267.63 1.000 13C12-HXCDD 678
278.55 1.010 13C12-HXCDD 789
1.03 1.021
1.027
0.996-1.046
0.000
0.936-1.128
0.000
326.69 1.000 13C12-HpCDF 678
245.42 1.039 13C12-HpCDF 789
1.055
0.977-1.006
0.000
0.969-1.031
0.000
0.982
239.01 1.000 13C12 -HpCDD 678
1.75 1.008
1.013
1.015
AN
AN
SDR4
IS5
RS2
ZS6
SOR5
IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:1410/21/97
u 105
-------
page No.
10/21/97
Listing of S976748B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
OCDF
442-444
1442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
0:
31:
31:
32:
32:
32:
32:
33:
33:
33:
33:
33:
34:
34:
34:
34:
35:
35:
35:
00
41
54
12
22
49
54
04
17
26
34
51
08
21
28
43
12
32
43
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
76-1.02
0.
1.
1.
3.
0.
1.
0.
0.
0.
2.
0.
3.
1.
1.
1.
0.
0.
0.
0.
51
05
02
40
70
22
96
25
76
17
34
63
17
88
58
66
87
31
61
Peak
Above: IfeCDD / Octa-CDD and CDF Follows
0.884-1.116
0.42 0.000
1.42 0.917
1.23 0.923
0.28 0.932
1.02 0.936
1.12 0.949
0.53 0.952
0.38 0.957
1.64 0.963
0.57 0.967
0.47 0.971
0.45 0.979
0.55 0.987
0.96 0.994
0.72 0.997
1.49 1.004
2.02 0.94 1.08 1.018
0.47 1.028
0.91 1.033
2.02
OCDD
458-460
458-460
0.76-1.02
DC ML 0:00 RO 1.08
d SN 34:36 RO 1.06
DC SN 34:56 RO 1.22
0 Peaks
0.45
3.78
1.46
0.00
0.884-1.116
0.000
1.001 OCDD
1.011
AN
13C12-OCDD
470-472
470-472
0.76-1.02
DC NL 0:00 RO 0.67 0.47
34:34 0.87 S3S.75
DC WH 34:58 RO 0.33 1.68
DC WH 35:06 RO 0.70 1.61
1 Peak 535.75
249.54
0.997-1.006
0.000
286.21 1.000 13C12-OCDD
1.012
1.015
IS8
Column Description "Why* Code Description QC Log Desc.
H_Z -Nominal Ion Mass(es)
! . .RT. -Retention Time (nzn:ss)
Rat.i -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel. RT-Relative Retention Time
End of Report ***
HL-Below Retention Time Window
HH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
File:S976748 #1-829 Acq:16-OCT-1997 13:48:03 EH- Voltage SIR 70S Hoiae:318
303.9016 F:2 SSUB(2S6,30,-3.0) PXD(9,5,5,O.OS\,1272.0,1.00\,rrT) Exp-.EPCOS
TRIANGLE LABS TeXt:M23 THERMAL ISLET SOS#3 TLI#43431 INJ. TIME ' 13:50
1001
sol
17:00 10i00 15:00 20:00 21:00
rile:S976748 #1-829 Aeg:16-OCT-1997 13:48:03 EH- Voltage SIS 70S Noise:343
305.8987 T:2 BSU3(2S6,30,-3.0) Pa>(9,5,5,O.OS\,1372.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS Te*t:M23 THERMAL INLET KWT#3 TLI#43431 INJ". TIME - 13: SO
1004
17:00 18:00 15:00 20:00 21-00
rile:S976748 #1-829 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIS 70S Noise-.316
315.9419 Ti2 BSUB(2S6,30, -3. 0) .PXD(9,S,S, 0. OS\,1264.0,1. 00\,T,T) ExpiEPCUS
TRIANGLE LABS Taxt:M23 THESMAL INLET RUN43 TLH43431 INJ. TIME - 13:50
1004 A6.28E6
60
401
201
22:00
22: 00
17:00 18:00 19:00 20:00 21:00
Tile:S976748 #1-829 Acq:lS-OCT-1997 13:48:03 EI+ Voltage SIS 70S Noise:343
317.9389 T:2 BSVB(256,30,-3.0) PXD(9,Sf5r0.05\,1372.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THESMAL ISLET XOJT*3 TLH43431 HKT. TIME « 13:50
100A AB.16E6
SOJ
sol
20
0.
22:00
17:00 18:00 19:00 20:00 21:00
r±le:S976748 #1-839 Aojtl6-OCT-1997 13:48:03 E?+ Voltage SIS 70S
330.9792 Ts2 SxpsSPCUS
TRIANGLE LABS Te*tsM23 THESMAL ISLET SUN#3 TLH43431 IJKT. TIME • 13:50
100J
80J
60:
401
201
17:05
17s40l7:59
18:30 18s54
19:38 201OS20126 ^0:52 21:14
22: 00
21:58
17:00 18:00 19:00 20:00 21:00
r±l«:S976748 #1-829 Acg:16-OCT-1997 13:48:03 EI+ Voltage SIS 70S
375.8364 Ts2 ExptSPCUS
TSIAWSLE LASS Teft:M23 THTKHAT. ISLET SVK#3 TLIt43431 OKT. TIME '
1004
19:35
so:
601
13:50
40:
201
17:07 17:35
18:09
17:00
17:55
18:00
18:58
8.-<2
19:00
22:00
21:54
22:37
20:00
21s 00
22:00
rl. 5E6
.1.2E6
.9.0E5
.6.0E5
.3. OE5
O.OEO
Time
.1.9E6
.1. 5E6
.1.1E6
.7.6E5
.3.8E5
.O.OEO
Time
.3. 4E6
,2. 7E6
.2.0E6
.1. 4E6
6.8E5
O.OEO
Time
4.9E3
3.9E3
.2.9E3
2.0E3
.9. 8E2
.O.OEO
Time
107
-------
rile:S976748 fl-829 Acq:16-OCT-1997 lJ.-4fl.-Oj EI+ Voltage SIX 70S Koiae:208
319.8965 T:2 BSOB(256,30,-3.0) PKD(7,5,3, 0. OS\,832.0,1.00\fr,T) Exp:EPCUS
TRIANGLE LASS Text:M23 THERMAL ISLET XUS43 TLI943431 IJKT. TIME = 13:50
10 OS, A1.60E4
22:00
19:00 20:00 21:00
Tile-.5976746 #1-829 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIS 70S Noiao:198
321.8936 T:2 3SOB(256,30t-3.0) PXD(7rSr3,O.QS\,792.0r1.00\tT,T) Ezp.-JEPCOS
TRIANGLE LABS Text:H23 THERMAL INLET SOJft3 TLIf43431 HUT. TIKE - 13:50
1003, A1.55E4
22:00
19:00 20:00 21:00
fi!e:S976748 tl-829 Acq:16-Od-1997 13:48:03 EH- Voltage SIX 70S Boi*e:378
331.9368 T:2 3SUB(256,30f-3.0) PXD(7,5,3,0.05\,1512.0,1.00\rT,T) Eip:EPCUS
TSIAKSLE LASS Text:«2J THERMAL ISLET SUXt3 TLIf43431 JK7. TIKE - 13:50
100*
60:
40:
20:
22:00
19:00 20:00 21:00
Tile:S976748 #1-829 Acq:16-OCX-1997 13:48:03 EI+ Voltage SIS 70S Koioe:225
333.9338. t:2 BSUB(2S6,30,-3.0) PKD(7,5,3,0.051,900.0,1.00%,r,T) Ezp:EPCDS
TRIANGLE LASS Taxt:M23 THERMAL ISLET XWT#3 XLI#43431 UKT. TIKE - 13:50
1001
80:
60:
40:
20:
o:
19s 00 20:00 21:00 22:00
r±J.e:S976748 tl-829 Actj:16-OCT-1997 13:48:03 EI+ Voltage SIS 70S Soiae:28S
27.8847 T:2 SSUS(256,30,-3.0) PXD(7,St3t0.05\,1140.0r1.00\,T,X) Elp:EPCUS
TRIANGLE LABS Te*t:M23 THERMAL ISLET XUS*3 TLH43431 TNJ. TIME - 13:50
004 ^8. 1E6
sol
60:
40:
20:
o:
19:00 20:00 21:00 22:00
HmtS976748 #1-829 Aoq:16-OCt-1997 13:48:03 EI+ VoZtage SIX 70S
30.9792 T:2 SxptSPCUS
TRIANGLE LABS Text:M23 THERMAL ISLET RWT#3 TLH43431 HC7. TIME - 13:50
18:54 19:38 20:05 20:26 20:5221:09^ 21:4121j 58
A^X^L. ^
80:
60:
40:
20:
0:
1.3E6
:l. OE6
.7.SE5
.5.0E5
-2.SE5
O.OEO
Tia.
22:37
19:00
20:00
21:00
22:00
.1.SE6
.1.2E6
.9.1ES
.6.0E5
.3. OE5
.O.OEO
Tim.
.2.2E6
.1. 8E6
.1.3E6
.8.8ES
.4.4E5
.O.OEO
Tims
.3.4E6
.2.7S6
2.0ES
1. 4E6
S.3E5
O.OEO
Time
108
-------
fi.le:S976748 #1-829 Acq:16-OCT-1997 13:48:03 EH- Voltage SIR 70S Sdiae:80
339.8597 T:2 SSUS(256,30, -3.0) PO>(7,S,3,0.05%,320.0,1.00\,T,T) Exp:£PCUS
TRIANGLE LABS Text:M23 THERMAL ISLET RV1H3 TLI*43431 ZK7. TIME - 13:50
1004
26:00
I1 M I ' ' !•*—•"I""* I'M
23:00 24:00 25:00
T±le:S976748 tl-829 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIS 70S Noiae:87
341.8567 T:2 BSUB(256r30, -3.0) PXD(7,5,3,0.05\,348.0,i.OO\,T,T) Exp:EPCUS
TRIANGLE LASS Text:M23 THERMAL ISLET ROB*3 TLI443431 JK7. TIKE ' 13:50
1001
23 .-00 24:00 25:00 26:00
Tile:S976748 tl-829 Acg:16-OCT-1997 13:48:03 EX+ Voltage SIR 70S Soiae:49
351.9000 1:2 BSUB(256r30,-3.0) •VXD(TfS,3,\ ^ 33,44 24:18 24:54 25J5S
'1J(JU^^J[J(J^J^
3StlS
26:41
33:00
24:00
25:00
26:00
27:00 Tine
4.9X3
'•.3.9E3
i. 3. OE3
-.2.0E3
.9.9X2
LO.OEO
27:00 Tine
-------
lfile:S97674B il-829 Acq:16-dCf-lS97 13:48:03 £1+ Voltage SIX 70S Noise:76
355.8546 Tt3 BSUS(2S6,30, -3. 0) PKD(7,5,3, 0. 05\,304.0,1.00\,T,T) Erp:EPCUS
TRIANGLE LASS Text:M23 THERMAL INLET RUN*3 TLI*43431 ISJ. TIME - 13:50
1004 AS. SE3
AB.30E3
A7.48E3
A2.45E.
J. 7E3
'.3.0E3
'.2.2E3
'.1.SE3
.7.4E2
24:00 25:00 26:00
Tile:S976748 il-829 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIR 70S Koiaes48
357.8516 F:2 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,192.0,1.00\,T,T) XxpsEPCOS
TRIANGLE LASS Text:M23 THERMAL ISLET XUNf3 TLIt43431 UKT. TIKE - 13:50
A4 .61E3
O.OEO
• Tim
24:00 35:00 26:00
rile:S976748 tl-829 Acq:16-OCT-1997 13:48:03 EX+ Voltagre SIX 70S No±ae:60
367.8949 F:2 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,240.0,1.00\,r,T) ZxpsXPCDS
TRIANGLE LABS Text.-JtZJ THERMAL ISLET RUlf#3 TLHH3431 UKT. TIKE - 13:50
1004 A2.9.0E6
80.
60.
40.
20.
9.4E5
'.7.5E5
5.6E5
3.8ES '
1.9E5
2.89E5
24:00 25:00 26:00
rile:S976748 tl-829 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIS 70S SOiae:48
369.8919 F:2 SSUS(256,30, -3.0) PXD(7,5,3,0.05\,192.0r1.00\,r,T) E3Cp:EPCUS
TRIANGLE LASS T&rt:M23 THERMAL ISLET SUNt3 TLIf43431 UCJ. TIKE " 13:50
lOOi, A1.98E6
80.
60.
40.
20.
O.OEO
Time
.6.4ES
.S.2E5
3.9E5
2.6E5
-1.3E5
02E5
24:00 25:00 26:00
rile:S976748 tl-829 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIS 70S
30.9792 T:2 ExptEPCOS
TRIANGLE LABS ToXt:M23 THERMAL ISLET RDNt3 TLI943431 HKT. TIKE -
O.OEO
Time
13:50
001
80.
60.
40:
20.
0.
24:06
24:25
24:59
25:20
25:5126:02 26:15 26:27 26:40
..3.6E6
.2.9S6
.2.1E6
-1.4E6
^7.2X5
24:00
25:00
26:00
O.OEO
Time
-------
File:S976748 #1-475 Acq:16-OCT-1997 13s48:03 EI+ Voltage SIX 70S Nod.ee-.174
373.8208 T:3 BSUB(256,30,-3.0) PXD(7,5,3,0.051,696.0,1.00\,F,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL INLET ROS#3 TLI#43431 XK7. TIME - 13:50
1003
aol
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
ttle:S976748 #1-475 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIR 70S Noiaet221
375.8178 Ft3 BSUB(256,30,-3.0) PTD(7,S,3, 0.05%, 884.0,1.00\,T,T) Ezp:EPCOS
TRIANGLE LABS Teit:M23 THERMAL ISLET RUNt3
1003
sol
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29
r±le:S976748 tl-475 Acg:16-OQT-1997 13:48:03 EI+ Voltage SIX 70S Noise:273
383.8639 rt3 BSVB(256,30,-3.0) fXD(7,5,3,0.OS\,1092.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS Tert:M23 THERMAL ISLET RVS#3 TLH43431 JK7. TIME - 13:
100J
BOl
60-.
401
20.
A2.52E6
A2.31E6
A
-.36 29:48 30:00 30:12
SO
A1.83E6
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29-48 30:00 30:12
riletS976748 #1-475 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIX 70S Noises207
385.8610 T:3 BSD3(256,30f-3.0) PKD(7,5,3,0.051,828.0,1.00\,r,T) Sxp:EPCUS
TRIANGLE LABS Text:M23 THERMAL ISLET RCN#3 TLI#43431 HKT. TUB - 13:50
100J
aol
60l
401
20:
A5.13E6
A4.74E6
I
7SE6
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29-24 29:36 29:48 30:00 30:12
rile:S976748 tl-475 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIR 70S
392.9760 Tt3 ExptEPCOS
TRIANGLE LABS Taxt:M23 THERMAL ISLET RUS#3 TLI#43431 UKT. TIME - 13:50
1003127:27 27:393T.49 38.02 28:16 28^31^ 28:46 _^ _29:08 29:1929:29
80:
60:
40:
aol
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 SOsOO 30:12
File:S976748 #1-475 Acq:16-OCT-1997 13:48:03 EH- Voltage SIX 70S
445.7555 T:3 ExpsEPCUS
TRIANGLE LABS Xext:M23 THERMAL ISLET XUS#3 TLH43431 XXKT. TIME - 13:50
1001
80.
60.
40.
2
0.
27>28
27:50
27:40
28:14
LiJrMl^^
29:47
30:09
30,041
29:48 30:00 30:12
OEO
Time
3E5
7E5
OE5
3E5
7E5
OEO
Time
.7E6
.3E6
.OE6
.7ES
.3E5
.OEO
Time
.8E6
.4E6
.1E6
.2E5
,6E5
.OEO
Time
SE3
2E3
9X3
6E3
3E3
OEO
Tiae
111
-------
rile:S976?4a tl-475 Acg:lS-ocT-lSS7 13:46,03 EI+ Voltage SIR 70s Koiae-.lOB
389.8156 r:3 BSUB(2S6,30,-3.0) PXD(7,5,3,O.OS\,432.0,1.00*,r,T) ExpiEPOJS
TRIANGLE LASS Text:M23 TBERMAL INLET RO1T*3 TLH43431 IJU. TIME * 13:50
1004
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
T±le:S976748 tl-475 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIX 70S So±ae:170
391.8127 F:3 BSV3(256,30,-3.0) PKD(7rS,3,O.OS\,680.0,1.00\,r,T) Exp:EPCOS
TRIANGLE LASS Text:M23 THERMAL ISLET £027*3 TLIt43431 HKT. TIME * 13:50
1001 A6.68E3
A7.35E3
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
r±le:S976748 41-475 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIR 70S Hoiac-.BS
401.8558 T:3 SSUS(256,30, -3.0) PXD(7,5,3, 0.05%,352.0,1. 00\,r,T) Exp:EPCOS
XRIAOSLE LASS Text:M23 TBESMAL ISLET RUN13 TLH43431 JK7. TIME - 13:50
1003
80.
60.
40.
20.
A3.18E6
A3.34E6
1.1E6
.8.6E5
.6.5E5
4.3E5
-2.2ES
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
rile:S976748 41-475 Aegsl6-OCT-1997 13:48:03 EI+ Voltage SIR 70S Hoi*e:143
403.8529 Ti3 SSO3(256,30r-3.0) PKD(7,St3fO.OS\r572.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LASS TextiM23 THERMAL ISLET RUNf3 TLH43431 INT. TIME - 13:50
O.OEO
Time
1001
80.
60.
40.
20.
A2.68E6
A2.79E6
27:48 '28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
Til*:S976748 tl-475 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIR 70S
92.9760 Ts3 ErptEPCUS
TRIANGLE LASS Teit:M23 TBERMAL ISLET RUS*3 TLIf 43431 UKT. TIME - 13:50
^
80.
60.
40.
20:
0.
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
.9.3E5
.7.4ES
.5.6ES
.3. 7X5
.1.9E5
.O.OEO
Time
.1. 8E6
1.4E6
1.126
7.2ES
3.6ES
O.OEO
Tiae
-------
•ile:S976748 01-397 Acq:16-OCT-1997 1J.-48.-OJ EH- Voltage SIS 70S Noise:633
407.7818 T:4 BSUB(2S6,30t-3.0) PXD(7,5,3,0.05\,2S32. 0,1.00%,*, T) Erp.-EPCCTS
TSIASGLE LASS Toxt:M23 THERMAL INLET StOT#3 TLIt43431 UtJ. TIKE ' 13:50
1003
80J
31:12 31:24 31:36 31:48 32:00 32:12 32:24
Tile:S976748 #1-397 Acg:16-OCT-1997 13:48:03 EH- Voltage SIS 70S Noise:473
409.7789 F:4 BSVB(256,30,-3.0) PXD(7,5,3,0.051,1892.0,1.00\,T,T) Erp.-EPCOS
TRIANGLE LABS Tcit:M23 THERMAL ISLET SOS#3 TLI#43431 ISCT. TIME ' 13:50
1009
80:
32:36
32:48
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File:S976748 #1-397 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIS 70S Noiee:338
417.8253 T:4 BSUB(256,30f-3.0) PKD(7,5r3,0.OS\,1352.0,1.00\,T,T) ExptEPCUS
TRIANGLE LABS Text:H23 T3ESMAL ISLET SUN«3 TLH43431 IJKT. TIME - 13:50
100% A1.38E6
32:36
32:48
80J
50J
401
20:
A1.05E6
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
file:3976748 H-397 Acg:16-OCT-1997 13:48:03 SH- Voltage SIS 70S Xoiae:569
419.8220 r-.4 BSOB(2S6,30,-3.0) PXD(7,5,3,O.OS\,2276.0,1.00\rT,T) Exp-.EPCUS
TRIANGLE LABS Text:M23 TBESMAL ISLET SVN#3 TLH43431 UKT. TIME * 13:50
100\ A3.27E6
32:48
80:
sol
40:
20:
A2.45E6
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
Tile-.3976748 #1-397 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIS 70S
430.9729 T:4 Elp-.EPCUS
TRIANGLE LABS Teit:M23 THERMAL ISLET SUN93 TLH43431 HKT. TIME ' 13:50
31:35
n ^—^ \T^v/^VX/^^-^_^,
80:
60:
40:
20:
32:48
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48
rile:S976748 #1-397 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIS 70S
479.7165 T:4 ExptSPCOS
TRIANGLE LABS T*Xt:M23 THERMAL ISLET SOS#3 TLI#43431 TK7. TIME - 13:50
31:12
31:24
31s 36
31:48
32 s 00
32:12
32:24
32:36
32:48
-4.1E5
.3.3E5
.2.4E5
.1. 6E5
.8.1S4
O.OEO
Tiae
.7.7E5
.5.8ES
.3.8E5
.1.9E5
O.OEO
Time
.1E6
.8.2E5
.5.5ES
.2. 7E5
O.OEO
Time
J1?
-------
11-337 Acq:l6-M9-l99/ 13:4B,d3 £t+ voltage six 784 *>iae:272
423.7766 T:4 SSUB(256,30, -3.0) rXD(7,5,3f0.05\,1088.0t1.00\,r,T) ExpsSfCDS
TXIANGLS LASS Text:M23 THERMAL INLET XOHi3 TLH43431 IJKT. TIME - 13:50
1001 A1.43E4
00:
31:34 31:30 31:36 31:42 31s48 31:54 32:00 32:06 32:12 32-18
ril»:S976748 tl-397 Aoqtl6-OCT-1997 13:48,03 SI+ Voltage SIX 70S Boimoil76
425.7737 T-.4 BSOB(2S6,30, -3.0) PXD(7,S,.3,0.05%, 704.0,1.00\,r,T) Exp-.EPCUS
XBIANGLE LASS Tert:M23 TSEJUOL ISLET SWft3 TLH43431 UKT. TIME - 13:50
lOOi,
0.0SO
32:24 32-30 32:36 Tim<
..2.5E3
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
Tile:S976748 tl-397 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIX 70S Hoiae:341
435.8169 f:4 BSUB(2S6,30,-3.0) 110(7,5,3,0.051,1364.0,1.00\,T,T) Exp:EPCOS
TXIAKSLE LABS T*xt:M23 WCTMT. ISLET XONt3 TLH43431 ISJ. TIME - 13:50
A2.35E6
32:24 32:30 32
.O.OEO
36 Time
80.
60.
40:
20.
-6.SES
'.5.2E5
.3.9ES
'.2.6E5
'.1.3ES
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
rile:S976748 tl-397 Acqt 16-OCS-1997 13:48:03 EH- Voltage SIX 70S Boiae:323
437.8140 T:4 BSUB(256,30,-3.0) tXD(7,Sr3,0.05\,1292iO,1.00\,T,T) ExptffCUS
TXIJOKLE LABS Tazt:M23 T3ESMU, OUT XdTt3 TLIt43431 UKT. TIME - 13:50
1001 A2.39E6
80.
60.
40.
20.
32:24 32:30 32.
.O.OEO
36 Time
6.8E5
-S.4E5
.4.1E5
.2.7X5
-1.4E5
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30
r±l»:3976748 tl-397 Acq: 16-OO-1997 13:48:03 SH- Voltago SIX 70S
30.9729 T:4 EzpiEPCUS
TXIAtKLE LABS Taxt:M23
-------
rile:S976748 #1-397 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIX 70S Koine: 102
441.7428 F:4 BSUB(256,30r-3.0) PXD(7r5f3rO.OS\,408.0r1.00\rT,T) Exp-.XPCOS
TRIANGLE LABS Text:M23 THERMAL ISLET XOtT#3 TLI#43431 IJKT. TIME * 13:50
1003
901
801
701
601
sol
401
301
201
101
o'-
31
A9.59E3
, A7.94E3 A5.0SE3 A7.21X3 ^'l**4 A3 .44E3J, ^'ff3. ff A4.33E3
*'>^-Mll(L«»Jw^rYy^(u>r/Vv/A^v^V *JWAyi/tw*A^\j^ -f-(''njA}\Wk*fWYb*l\ttAAAst/w^^^ Myv
00 ' ' '32sOO 33:00 3<:00 ' '35-00
2.7E4
.2.4E4
.2.1E4
.1 . 9E4
.1 . 6E4
.1.354
.1.1X4
.8.1E3
.5 . 4X3
.2.7X3
.O.OEO
Time
K1»,S976748 #1-397 Aog:16-OCT-1997 13,48,03 EI+ Volts ye SIR 70S Bt>iaa:195
443.7399 T:4 SSUB(256,30,-3.0) PXD(7,5,3,0.05\r780.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL TTTT.BT XUS#3 XLI#43431 IKT. TIME - 13:50
1001
901
801
701
sol
501
401
301
201
101
0-
31
A6.99E3 A 'l E|
t 1 ii 1 AS. 37X3 A9.29E3 I A4.40E3 1 ij ij *l |A7'nTl
^J\J^kM^^
00 32:00 ' ' 33:00 ' 34:00 35:00
-2.0E4
.1 . 8E4
.1 . 6E4
.1.4E4
.1.2X4
.9.8E3
.7.8X3
.S.9E3
.3.9E3
.2.0X3
Time
Tile:S976748 #1-397 Acq-.16-QCS-l.997 13:40:03 Z3> Voltage SIR 70S
430.9729 f,4 ExptEPCUS
TRIAVSLE LABS Tert:M23 THERMAL ISLET XWT#3 TLI#43431 ZKT. TIME - 13:50
1003
901
801
701
601
501
401
301
201
101
0-
31
31-10 31:54 ._ _, ._ 33l23 33:50 34:18 34:55
[V^$^^
vi<«|if iy vv* j 'I'vir yffi f
00 32«00 33:00 34,-Ofl' ' '35:00
-1.4X6
.1.2X6
.1 . 1X6
.9.7X5
.8.3X5
.6.9X5
.5.6X5
.4.2X5
.2. 8E5
.1 . 4X5
O.OEO
Time
Tile:S97674B #1-397 Acq:16-OCT-1997 13,48:03 ZI+ Voltage SIX 70S
513.6775 T:4 Ezp:EPCVS
TSIAHSLE LABS TKTt:M23 THERMAL ISLET RUS#3 TLI#43431 XJKT. TIME - 13:50
1001
901
801
701
601
sol
461
301
201
101
o-
31
I 35:04
31-24
31:41 33,05 *' 34:27 1 35:22 3S*,46
.33:44 - 1 ill
32*51 i I 1 1 1 i inf54 111
76.0E3
.5.4X3
.4.8X3
.4.2X3
.3.6X3
.3.0X3
>
11 1 il 1 1 A JP**?fM 1 I flJiliii il M 11 ill jyill i III I \3-4E3
J M II I 1 ill Jl Tl lilftLniill fi mllunll flfii HI'07 n 11^11 /nllM I'lLI li1'813
^yivwi/yiMip^i^^ Uwv' v PiflyiJipiiKAJ w^, w"ri ii/pi p\i\^i 'i»y'V'^i.i.2r3
00 32:00 33,00 34,00 35,00
':6.0E2
•O.OEO
T±me
115
-------
nj.e:sy/o/iu tj.-jy/ Acg:J.t>-ocT-j.yy7 13:48:03 EI+ Voltage SIB 70S Noise:129
457.7377 f:4 BSUS(256,30f-3.0) ?XD(7,5,3,0.05\,516.0 ,1.00\,r,T) ExpiEPCUS
TRIANGLE LASS Text:M23 THERMAL INLET XUlTi3 TLIt43431 INJ. TIME " 13:50
100$ . A9.47E3
34:30 34:36 34:43 34:46 34:54
FilesS97674S #1-397 Acq, 16-OCT-1997 13:48:03 EH- Voltage 3IS 70S So±ae:118
459.7348 T:4 BSU3(256,30r-3.0) PXD(7,5,3,0.05\,472.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LASS Tezt:M23 TRESMAL ISLET SVSt3 TLH43431 HK7. TIME - 13:50
1001 A2.QOE4
35:00
O.OEO
35.06 Tiae
34:30 34:36 34:42 34:48 34:54 35:00
File:S97674B tl-397 Acg:16-OCT-1997 13:48:03 EH- Voltage SIR 70S Soiae-.lOa
469.7779 T:4 SSUS(256,30,-3.0) PKD(7,5,3,0.05\,432.0,1.00\,r,T) Ezp:EPCUS
TBIASGLE LASS Text:H23 THERMAL ISLET SOT*? TLH43431 BET. TIME - 13:50
lOOt, A2.5JE6
80.
60.
40:
20J
o:
O.OEO
35.06 Time
3.1ES
.2.5E5
-1.9E5
'.1.2E5
'.6.2E4
34:30 34:36 34:42 34:48 34:54 35:00
rile:S97674B 41-397 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIS 70S Koioe:163
471.7750 T:4 BSVB(256,30,-3.0) PXD(7,5,3,O.OS\,652.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS Tezt:M23 THERMAL ISLET StOfi3 TLH43431 HTJ. TIME • 13:50
L0.0S0
1001
801
eo:
40:
20'.
A3.
35.06 Time
3.4X5
.2. 7E5
.2. OSS
-1.4ES
'.6.8E4
34s30 34: 36 34:42 34:48 34:54
•ile:S976748 tl-397 Acxj:16-OCT-1997 13:48,03 EH- Voltage SIR 70S
30.9729 Ti4 Exp:EPCUS
TRIANGLE LABS Teit.:M23 THERMAL ISLET ROS13 TLH43431 ISJ. TIME '
00*
80.
60.
40.
20:
0.
35:00
35.06
.O.OEO
Tia
-1.4X6
'-1.1E6
.8.3S5
.5.5X5
.2.8X5
34:30
34:36
34:42
34:48
34:54
35:00
35.06
0.0X0
Time
<6
-------
ChsnneL I 330,3732 Pesk top
Height 1,87 volts Span 286 pp
Systa file naae
Data fiienau
Resolution
Group nmbsr
1 lonizxlon x&.
Suitching
ft 233
B 384
C 386
D 316
E 318
F 329
G 322
H 328
I 331
EFGJS
VdlfiGE
22.3325, 416,3768
j 331 S 368
K 332 T 37*
L 334 U 376
H 348 V 410
N 342
0 352
P 354
9 356
R 358
Ref, tass 416,9768 Peak top
Height ,34 volts Span 88 pn
117
-------
CO
File:S976747 #1-829 Acq:16-OCT-1997 13:08:39 EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text:M23 THERMAL INLET RUN#2 TLI#43431 INJ. TIME =
21T14 '
13:11 File Text:M23 THERMAL I»
4.1E3
22:00
SIR 70S
20:00 21100
File:S976747 #1-829 Acq: 16-OCT-1997 13:08:39 EI+ Voltage
321.8936 F:2 Exp:EPCUS
Sample Text:M23 THERMAL INLET RUN#2 TLI#43431 INJ. TIME =
100*
Time
13:11 File Text:M23 THERMAL I»
22:50 _4.5E3
2000
21:00
22:00
.O.OEO
Time
-------
•X-WfcNv s -, •• •• X*;-^. •**•' *•*• "• s. w. •*•.•.•. "• f *\ -. \ •. s f
TLI Project:
Client Sample:
43431
M23 THERMAL INLET FB2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S976749
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Asphalt Roofing Project
M23TRAIN Date Received:
185-5-4A-D Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/01/97
10/16/97
n/a
S976745
BJG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976737
n/a
n/a
n/a
Anafytes --; '-" ""
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
U,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2^,7,8-TCDF
1,2,3,7,8-PeCDF
2^,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
U,3,6,7,8-HxCDF
2J,4,6,7,8-HxCDF
!Z3.7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totate ' -' '<^|
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
5 *gr* "^Kstoap |
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
•%;.? .
ND
ND
ND
ND
ND
ND
ND
ND
^^^•0£.vx.'.*- -' ' £|yfpC:: " tfitfe&vs^r J|^tJ{yj* %-*A •• ^ff,'' FfeOS
0.005
0.007
0.009
0.007
0.007
0.01
0.01
0.003
0.005
0.005
0.005
0.004
0.005
0.006
0.007
0.009
0.01
^^nillor-' sfJI JtMISP^'"* '* *' ^^>^^^.'^^^Z ~ £tftrra -•
0.005
0.007
0.008
0.01
0.003
0.005
0.005
0.008
Page 1 of2
XZ37_PSR V2.00. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Caiofina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:1410/21/97
119
-------
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: M23 THERMAL INLET FB2 Analysis File: S976749
jntemalStaBF
13C12-2,3,4,6,7,8-HxCDF
^^^Bcb«te.v^ ^//v;
I3C12-1,2^,4-TCDD
l3Cirl,2,3,7,8,9-HxCDD
Jfc*MW.^ ^
3.3
3.0
3.1
3.1
3.9
3.6
3.0
3.6
7.3
J|ML^^ .^
3.9
3.6
32
32
3.8
^nLCn^ ;-^"%
3.3
3.7
^V5fe£
iRecoven
81.7
75.3
76.4
78.4
97.7
89.2
75.4
90.1
90.7
tRacavary
97.4
89.3
80.2
80.7
94.7
Recovery
82.9
92.9
- ,
1 QC Limits
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
- QC Limits
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
QCLsnits
40%-130%
40%-130%
\ -vV '
_;iw»
0.77
0.83
1.46
1.48
0.48
1.22
0.42
1.03
0.87
Ratio
1.49
0.51
122
0.44
* ^RafK>- -
0.49
0.49
Ratio
0.85
122
8T_ ;.Rgp_.
20:22
21:10
24:41
25:49
28:28
29:11
31:11
32:04
34:34
ffT Flags
21:11
25:27
28:22
29:06
32:25
-~8TV~ Ffegs
29:43
28:59
ST JFiagsJ j
20:56
29:29
Data Reviewer
Page 2 of2
10/21/97
X237 JBR rZOO. LARS 6.ICUW
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:14 10/21/97
150
-------
Initial
---- Date...
Data Review By:
Calculated Noise Area:
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
0.38
Page No.
10/21/97
Listing of S976749B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
320-322
37C1-TCDD
328
DC
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
NL
SN
SN
WH
0
NL
WL
WH
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
0
19
22
22
:00
:05
:16
:44
0.
RO
RO
65-0.89
1.
2.
0.
0.
08
19
72
79
Peaks
0
19
19
19
20
20
22
:00
:11
:31
:56
:22
:S1
:16
0.
RO
RO
RO
RO
0
0
1
0
0
.
.
.
.
67
28
03
75
00
65-0.89
1.
0.
0%
0.
0.
0.
1.
22
83
52
55
77
72
16
Peaks
0
19
19
19
19
19
20
20
20
21
21
22
22
:00
:12
:24
:38
:48
:50
:04
:15
:21
:34
:46
:02
:06
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
*^.«.**IL .
65-0.89
1.
2.
1.
0.
3.
0.
3.
2.
0.
0.
0.
1.
0.
47
07
12
89
78
79
00
86
57
06
13
13
57
Peaks
1
17
03
34
2.16 0.94
6
924
8
0
941
.
•
46 2.81
18 401.00
77 3.66
90
57
0.825-1.102
0.
0.
1.
1.
000
937
093
116
0.951-1.049
0.
0.
1.81 0.
5.08 0.
523.18 1.
5.11 1.
1.
000
942
958
979
000 13C12-2378-TCDF ISO
024
093
TCDP / TCDD Follows — — — —
0
0
0
1
0
0
0
0
•
.
.
.
.
.
.
60
97
44
02
32
93
42
64
1.15
0
0
.
.
07
14
0.67
0
0
•
37
00
0.856-1.059
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
000
907
917
928
935
937
948
957
961
019
028
041
044
0.906-1.094
DC
DC
DC
NL
WL
WL
0:00
18
18
19
19
:26
:56
:37
:54
0.20
0.51
20:54
21
21
:11
:30
0
4
0
0
565
4
.
.
.
.
.
23
43 4.43
60 0.60
53 0.53
36 565.36
13 4.13
0.
0.
0.
0.
0.
0.
1.
1.
000
871
894
927
940
987
001 37C1-TCDD SOR2
016
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:15 10/21/97
121
-------
page No.
10/21/97
Listing of S976749B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..
ID.. Flags.
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
340-342
13C12-PeCDF
352-354
352-354
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
10
NL
WL
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0
NL
SN
SN
6
21:41
21:46
21:53
21:58
22:41
22:47
Peaks
0:00
18:48
20:39
20:56
21:10
21:32
21:47
22:17
Peaks
0:00
22:33
23:07
23:33
23:40
23:48
24:04
24:21
24:33
25:22
25:56
26:08
26:17
26:24
26:43
26:48
Peaks
0:00
22:27
23:48
24:19
24:41
25:00
25:27
26:22
26:30
Peaks
0.
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
.65-0.89
2.75
0.53
0.90
0.85
0.83
0.86
0.55
1.67
_ A VM*
32-1.78
1.09
0.50
0.11
1.75
3.54
1.32
0.57
1.17
1.07
1.00
1.06
1.82
1.53
1.55
1.36
0.96
32-1.78
0.91
0.77
1.86
1.27
1.46
0.97
1.49
1.50
1.22
1.34 1.34
1.06 1.06
0.65 0.65
1.17 1.17
0.56 0.56
0.26
579.83
1
1
1
1
1
1
.024
.028
.034
.038
.072
.076
0.906-1.094
0.21
0.67
0.85
858.00 393.68
688.56 312.52
16.38 7.58
2.23 0.97
0.48
1.565.17
0.20
0.46
0.10
0.44
0.33
0.44
0.21
0.44
0.25
0.12
0.30
0.28
0.86
0.28
0.26
0.41
0.00
0.000
0.883
0.976
464.32 0.989 13C12-1234-TCDD RSI
376.04 1.000 13C12-2378-TCDD IS1
8.80 1.
017
1.76 1.029
1.
053
0.907-1.080
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
000
914
937
954
959
964
975
986
995
028
051
059
065
070
082
086
0.838-1.162
0.16
0.49
19.07 13.88
4.98 3.03
742.24 440.86
6.73 4.09
642.91 384.39
0.45
1.76 1.07
1,417.69
0.
0.
7.48 0.
2.38 0.
301.38 1.
4.21 1.
258.52 1.
1.
0.88 1.
000
910
964
985
000 13C12-PeCDF 123 IS2
013
031 13C12-FBCDF 234 SUR2
068
074
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:15 10/21/97
-------
Page No.
10/21/97
Listing of S976749B.dbf
Matched GC PeaXs / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
PeCDD
356-358
356-358
13C12-PeCDD
368-370
368-370
HxCDF
374-376
D
374-376
13C12-HXCDF
384-386
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
HH
0
NL
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0
NL
0:
23:
24:
24:
25:
25:
26:
26:
26:
00
55
21
40
13
28
11
21
41
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
32-1.78
1.
0.
0.
0.
1.
6.
0.
3.
0.
11
50
49
66
25
11
86
92
69
Peaks
0:
24:
24:
24:
25:
25:
25:
25:
00
11
43
49
02
16
49
57
1.
RO
RO
RO
RO
RO
RO
0
0
0
0
0
0
0
0
0
0
.16
.58
.31
.38
.25
.23
.30
.31
.67
.00
32-1.78
1.
2.
1.
3~.
1.
0.
1.
1.
11
53
17
81
30
51
48
48
Peaks
0:
27:
27:
27:
28:
28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
29:
30:
30:
00
27
37
47
22
28
34
45
48
00
10
12
24
28
55
58
07
19
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
H !»__*•_. .
05-1.43
0.
2.
9.
1.
1.
0.
0.
3.
1.
0.
1.
2.
0.
1.
0.
0.
0.
4.
80
20
67
53
17
86
70
57
27
82
56
19
27
83
60
65
72
82
Peaks
0:
27:
27:
00
23
30
0.
0
0
0
0
0
0
427
48
475
.16
.38
.35
.54
.43
.54
.05 254.78
.85 29.14
.90
0.921-1.026
0.
0.
0.
0.
0.
0.
1.
1.
1.
000
926
943
955
977
986
014
021
034
0.845-1.155
0.
0.
0.
0.
0.
0.
172.27 1.
19.71 1.
000
937
957
961
970
979
000 13C12-PBCDD 123 IS3
005
0
0
0
0
0
0
0
0
0
1
0
.36
.22
.07
.96
.78
.34
.25
.16
.50
.35
.36
0.36 •
0
0
0
0
0
0
0
.18
.27
.27
.36
.38
.25
.00
43-0.59
0.
0.
0.
58
54
49
0
3
.49
.18 1.11
8.58 2.83
0.956-1.053
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
964
970
976
996 123478-HXCDF AN
000 123678-HxCDF AN
004
010
012
019 234678-HxCDF AN
025
026
033
035
051
053
058
065
0.860-1.140
0.
2.07 0.
5.75 0.
000
962
966
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:15 10/21/97
123
-------
page No.
10/21/97
Listing of S976749B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why . .RT. OK Ratio Total. Area... Area.Peak.1. . Area.Peak.2. . Rel.RT Compound. Name.. ID.. Flags.
384-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
11
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0
NL
SN
7
NL
SN
SN
27:41
28:22
28:28
28:41
28:47
28:59
29:15
29:21
29:28
29:36
29:43
30:04
30:05
30:10
30:18
Peaks
0:00
27:48
28:17
28:22
28:28
28:39
28:42
28:59
29:21
29:31
29:43
29:54
Peaks
0:00
28:34
28:39
29:06
29:11
29:29
29:45
29:53
29:59
Peaks
0:00
31:20
31:40
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.44
0.51
0.48
0.44
0.44
0.49
1.06
0.46
0.27
1.15
0.49
0.32
0.82
0.74
0.97
&WSMTA
.05-1.43
0.58
1.75
0.71
1.31
1.15
0.42
0.12
3.45
0.13
0.52
1.46
0.46
0
480
624
6
3
549
2
1
1
0
426
.36
.11 161.66
.30 202.17
.26 1.91
.20 0.98
.51 181.77
.39 1.68
.78 0.56
.10
.41
.68 140.13
318.45
422.13
4.35
2.22
367.74
1.58
1.22
0
0
1
1
.972
.996 13C12-HXCDF 478
.000 13C12-HXCDF 678
.008
SUR3
IS4
1.011
1.018 13C12-HXCDF 234
ALT2
1.028
1.
.031
1.035
1.040
286.55
0.59
0.68
1.34 0.66
0.89
0.54
1.
1.
.044 13C12-HXCDF 789
.056
ALT1
1.057
1.060
1.064
2,107.33
. HvCDP ' UBW*V**\ «t_1 1 .«.».
0.950-1.015
0.20
0.99
0.18
0.81
0.56
0.20
0.07
0.45
0.13
0.23
0.78
0.23
0.000
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
953
969
972
975
982
983
993
006
Oil 12 37 89 -HxCDD
018
025
AN
0.00
1.
RO
RO
RO
RO
RO
0.
RO
RO
05-1.43
0.90
0.73
3.13
1.22
1.22
1.22
2.72
1.20
0.76
88-1.20
0.94
2.38
0.84
0.966-1.034
0.
2.
0.
369.
471.
530.
1.
2.
0.
34
02 1.12
36
96 203.06
07 258 . 82
79 291.99
50 1.82
49 1.36
92 0.51
1.53
166.90
212.25
238.80
0.67
1.13
0.67
0.
0.
0.
0.
1.
1.
•1.
1.
1.
000
979
982
997 13C12-HXCDD 478
000 13C12-HXCDD 678
010 13C12-HXCDD 789
019
024
027
SUR4
IS5
RS2
1,378.75
0.
0.
0.
62
16
53
0.996-1.046
0.
1.
1.
000
005
015
riangle Laboratories, Inc.® Analytical Services Division
101 Caprtola Drive • Durham. North Carolina 27713
r (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:15J
-------
Page No.
10/21/97
Listing of S976749B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.
ID.. Flags.
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
WH
WH
0
NL
SN
SN
SN
4
NL
SN
WH
WH
0
NL
SN
SN
SN
3
NL
SN
SN
SN
SN
SN
SN
SN
SN
31:47
32:01
32:08
32:16
32:25
32:44
32:48
Peaks
0:00
31:11
31:50
31:54
32:04
32:09
32:25
32:57
Peaks
0:00
32:10
32:26
32:33
Peaks
0:00
31:27
31:42
31:51
31:54
32:04
32:19
Peaks
0:00
31:43
31:56
32:22
32:29
32:36
32:43
33:01
33:15
33:22
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
0.
RO
RO
RO
0.
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
2
1
9
0
3
0
0
.06
.00
.58
.90
.13
.60
.30
0
0
0
1
0
0
0
0
.37
.82
.24
.16
.16
.75
.37
.00
37-0.51
0
0
1
1
0
1
0
1
.98
.42
.22
.31
.46
.20
.44
.41
0
355
0
1
1
0
259
0
616
.72
.22
.72
.01
.50
.65
.48
.42
.43
HpCDF /
88-1.20
0
3
3
0
.67
.78
.09
.89
0
0
0
0
0
.27
.37
.67
.85
.00
88-1.20
0
0
2
1
0
1
0
.97
.71
.08
.50
.83
.03
.58
1
2
0
0
0
389
1
394
u*»s*n
76-1.02
0
1
0
0
0
1
11
2
0
2
.71
.85
.80
.18
.69
.16
.00
.17
.34
.75
0
0
1
0
0
0
0
0
0
0
.18
.51
.51
.45
.37
.67
.98
.16
n /
u 1
.42
.77
.10
.15
.23
.83
.11
.23
.30
.08
1
1
1
1
1
1
1
.019
.027
.030
.035
.040 1234789-HpCDF AN
.050
.052
0.936-1.128
0
105.09 250.13 1
0.61 0.50 1
0.92 0.70 1
1
1
79.74 179.74 1
1
.000
.000 13C12-HpCDF 678 IS6
.021
.023
.028
.031
.040 13C12-HpCDF 789 SDKS
.057
0.977-1.006
0
1
1
1
.000
.003
.011
.015
0.969-1.031
0
1.28 1.80 0
0
0
0
197.32 192.35 1
1.01 1.74 1
.000
.981
.989
.993
.995
.000 13C12-HpCDD 678 IS7
.008
0.884-1.116
0
0
0.49 0.61 0
0
0
0
0
0
0
0
.000
.918
.924
.936
.940
.943
.946
.955
.962
.965
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:15 10/21/97
125
-------
Page No. 6 Listing of S976749B.dbf
10/21/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC SN 33:41 RO 0.44 0.59 0.974
DC SN 33:56 RO 0.66 0.53 0.982
DC SN 34:15 RO 0.06 0.04 0.991
DC SN 34:24 0.90 0.78 0.995
34:49 RO 0.49 1.21 0.57 1.17 1.007
442-444 2 Peaks 2.31
OCDD 0.76-1.02 0.884-1.116
458-460 DC NL 0:00 RO 1.11 0.17 0.000
DC SN 34:29 RO 1.78 0.43 0.998
D d SN 34:38 RO 0.47 1.81 1.002 OCDD AN
458-460 0 Peaks 0.00
13C12-OCDD 0.76-1.02 0.997-1.006
470-472 DC ML 0:00 RO 1.09 0.21 0.000
34:34 0.87 499.87 232.32 267.55 1.000 13C12-OCDD IS8
DC WH 35:04 0.98 2.61 1.014
470-472 1 Peak 499.87
Column Description "Why Code Description QC Log Desc.
H_Z -Nominal Ion Mass(es) WL-Below Retention Time Window A-Feak Added
..RT. -Retention Time (nm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
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17:00
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TRIANGLE LABS Text:M23 THERMAL ISLET FB2 TLH43431 ISJ. TIME -
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331.9368 f:2 BSUB(2S6,30r-3.0) PXD(7,5f3,O.OS\,6S6.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL ISLET TB2 TLH43431 IJTJ. TIME -
1001 A3 94E6
80:
60:
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TRIANGLE LABS Tezt:M23 THERMAL ISLET FS2 TLH43431 ISJ. TIME -
1001 A4.$4E6
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TRIANGLE LABS Tezt:M23 THERMAL ISLET FB2 TLH43431 HU. TIME -
1001
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19:00 20:00 21:00
File:S976749 tl-829 Acq:16-OCT-1997 14:27:22 EI+ Voltage SIR 70S
30.9792 T:2 Exp:XPCUS
TRIANGLE LABS TextsM23 •nrmiT. UILET TB2 XLIt43431 XKT. TIME
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128
-------
File:S976749 #1-829 Acq:16-OCT-1997 14:27:22 EI+ Voltage SIS 70S Noise: 62
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TRIANGLE LASS Text:M23 THERMAL ISLET TS2 TLH43431 ZHT. TIME - 14:30
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341.8567 T:2 SSUB(256, 30, -3. 0) fO)( 7,S,3,0.05\,228.0, 1.00\,T,T) Eip-.EPCUS
TRIANGLE LASS Text:M23 THERMAL INLET T92 TLH43431 ISJ". TIME - 14:30
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TRIANGLE LASS Teit:M23 THERMAL ISLET 192 TLH43431 1X7. TIKE - 14:30-
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TRIANGLE LASS Text:M23 THERMAL ISLET T92 TLH43431 IKJ. TIME - 14:30
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330.9792 T:2 Exp-.EPCUS
TRUUKLX LABS Tezt:M23 THERMAL ISLET TS2 TLH43431 rOT. TIME • 14:30
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409.7974 T:2 Eip:EPCUS
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100* A5.47E3
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TRIANGLE LASS Text.-AGJ THERMAL INLET TS2 TLH43431 JfKT, TIME -
100S
14:30
24:00 25:00 26:00
File:S97S749 tl-829 Acqsl6-OCT-1997 14:27:22 XH- Voltaye SIS 70S Soiae:Sl
367.8949 t:2 BSUB(2S6,30,-3.0) PKD(7,5,3,0.05\,204.0,1.00\,T,T) ErpiEPCUS
XXIASGLE LASS Text:H23 TBESMAL ISLET TX2 XLH43431 IJTJ. TIME " 14:30
10 0\ A2.5.5E6
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40.
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24:00 25:00 26:00
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TRIANGLE LASS T&Xt:M23 TBESMAL ISLET T»2 TLH43431 BKT. TIME - 14:30
1001
80.
60.
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F±le:S976749 #1-475 Acq:16-OCT-1997 14:27:22 EH- Voltage SIS 70S No±ae:99
373.8208 T:3 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,396.0r1.00\rT,T) Ezp:EPCUS
TRIANGLE LASS TextsJO.3 TBERMAL ISLET TB2 TLIt43431 INJT. TIME ' 14:30
100*
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375.8178 T:3 BSVB(256,30, -3.0) PKD(7,5,3, O.OS\,500.0,1.00\,T,T) Ezp:EPCOS
TKIAHGLE LABS Text:M23 TBESMAI. ISLET TB2 TLH43431 HKT. TIME ' 14:30
100* AS. 9X3
4.6E3
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1.BE3
L9.1E2
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Time
27,24 27,36 27:48 28*00 28,12 28,24 28,36 28,48 29,00 29,12 29,24 29,36 29,48 30,00 30,12
File,3976749 fl-475 Acq:16-OCT-1997 14:27:22 EI+ Voltage SIS 70S N6iae:91
383.8639 F:3 BSUB(256,30, -3.0) PKD(7,5,3,O.OS\,364.0r1.00\rrrT) XxptEfCOS
TRIANGLE LABS Text:M23 TBESHAL IXLET TB2 TLH43431 1ST. TIKE ' 14:30
1001 A2.02E6 A1.82E6
SOJ
50J
40l
201
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27:24 27:36 27:48 28:00 28:12 28:24 28:36 28,48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
FHe:S976749 tl-475 Aeq:16-OCT-1997 14,27,22 EI+ Voltage SIS 70S Noiaa:153
385.8610 F:3 BSOB(256,30, -3. 0) PKD(7,5,3,0.05\,612.0,1.00\,T,T) Ezp:EPCUS
TRIANGLE LABS Text:M23 THERMAL ISLET TB2 TLH43431 OKI. TIKE - 14:30
1003
eol
601
401
201
A4.22E6
A3.68E6
A2.87E6
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rile:S976749 tl-475 Acq:16-OCT-1997 14:27:22 EI+ Voltage SIS 70S
392.9760 T*3 Elp,EPCUS
TRIANGLE LABS T*xt*K23 TSERMAL ISLET TB2 TLH43431 UKT. TIKE - 14:30
20:12 28:32 20:40 29:03 29*34 29:47 30i00
00:
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40.
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Til»*S976749 tl-475 Acq:16-OCT-1997 14*27*22 EH- Voltage SIR 70S
445.7555 Ti3 ExpsXPCtTS
TRIANGLE LABS Tmit*H23 mnmnr. ISLET TB2 TLII43431 ZKT. TIME - 14,30
O.OEO
Tine
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Time
27,24 27,36 27*48 28,00 28-12 28*24 28,36 28,48 29*00 29*12 29*24 29*36 29*48 30,00 30,12
O.OEO
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131
-------
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389.8156 Ps3 BSUS(256,30, -3. 0) PKD(7,Sr3,Q.OS\,228.0r1.00\,r,T) Exp-.EPCOS
T8IAKSLE LABS Text.:H23 TBERHAL INLET TS2 TLH43431 IKT. TIME = 14:30
100$
A3.02S3
A3.22E3
27:48 29:00 28:12 28:24 29:36 28:48 29:00 29:12 29:24 29:36 29:48
rilo:S976749 fl-475 Acq:16-OCT-1997 14:27:22 SH- Voltage SIS 70S Noiae:94
391.9127 r:3 BSUS(256,30,-3.0) PXD(7,5r3,0.05\,376.0,1.00\,r,T) Ezp:EPCUS
TSIASSLE LASS TaxtiM23 TBEUfXL ISLET TB2 XLIf43431 23CT. TIHE - 14:30
1001
27:48 28-00 28,12 28,24 28,36 28:48 29:00 29:12 29:24 29:36 29:48
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401.8558 Ts3 BSUS(2S6,30, -3.0) PXD(7,5,3,O.OS\r388.0,l.aO\,r,T) Etp:EPCOS
TRIANGLE LASS Text:H23 THERMAL ISLET fS2 TLH43431 XK7. TIME - 14:30
1004 A2.9.2E6
80.
60.
40.
20:
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Tile:S976749 fl-475 At^:16-OCT-1997 14:27:22 EI+ Voltage SIS 70S Soiae:104
03.8529 P:3 SSOB(256r30,-3,0) PXD(7,5,3,0.OS\,416.0,1.00\,r,T) Sxp:ZPCOS
TXIXBSUS LABS Taxt:M33 TSERHAL ISLET TBS TLH43431 UfT. TIME - 14:30
100\ A2.39E6
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40:
20:
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27:48 28:00 28:12 28,24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
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92.9760 P:3 Eip:EPCOS
SIABSLZ LASS Text:M23 TSEStMAL ISLET TB2 TLH43431 XK7. TIHE • 14:30
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Time
132
-------
File-.3976749 tl-397 Acg:16-OCT-1997 14:27:22 EI+ Voltage SIS 70S Noiae:152
407.7818 T:4 BSOB(256f30,-3.0) PKD(7,5,3,0. OS\,608.0,1.00\,T,T) Ezp:EPCUS
TRIANGLE LABS Text:M23 THERMAL ISLET FB2 TLH43431 XX7. TIME - 14:30
100*. A1.15E4
31:12 31:24 31:36 31:48 32:00 32:12 32:24
Tile:S976749 tl-397 Acq:16-OCT-1997 14:37:22 EH- Voltage SIS 70S Soiae:159
409.7789 f>4 BSDB(2S6,30,-3.0) PKD(7,5,3, 0.05*, 636.0,1.00\,r,T) Exp-.EPCUS
TRIANGLE LASS Tezt:M23 TBEBMAL ISLET FB2 TLH43431 1ST. TIME ' 14:30
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sol
31:12 31:24 31:36 31:48 32*00 32:13 32:24 32:36
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417.8253 Ti4 BSUB(256,30,-3.V) fXD(7,S,3,0.05\,984.0r1.00\,T,T) Erp-.EPCUS
TRIANGLE LABS Text:M23 THERMAL ISLET FB2 TLH43431 UKT. TIME - 14:30
100\ A1.0JSE6
32:36
32:48
601
401
201
OJ
A6.12E3
A3.19E3
A4.11E3
A6.30E3
32:48
801
sol
401
201
01
A7.97E5
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
T±letS976749 tl-397 Acqtl6-OCT-1997 14:27:22 EH- Voltage SIS 70S Soiae:2SO
419.8220 f:4 BSUB(256r30, -3.0) fXD(7,5r3,0.05\,1000.0,1.00\,T,T) Ezp-.EPCVS
TRIANGLE LABS Tezt:M23 THERMAL ISLET T32 TLIt43431 ZK7. TIME " 14:30
A2.50E6
A1.80E6
32:48
32:24
32:36
31:12 31:24 31:36 31:48 32:00 32:12
Tile:S976749 tl-397 Aoq:16-OCT-1997 14:27:22 EH- Voltage SIS 70S
430.9729 T:4 Exp-.EPCOS
TRIANGLE LABS Text:M23 THERMAL ISLET TB2 TLIt43431 1X7. TIME - 14:30
1004 31i09 ^ 31:23 31:33 __ 31:45 31:58 . . 32sl6 32:34
801
601
401
201
32:48
32:51
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
Pil*:S976749 tl-397 Acq:16-OCX-1997 14s27:22 EI+ Voltage SIX 70S
479.7165 Ti4 Eip:EPCUS
TBIAOGLE LABS Text:M23 >nmmT. ISLET TB2 TLH43431 OCT. TIME - 14:30
32:48
1001
801
60l
401
201
31:11
31118
32:52
31:12
31134
31:36
31:48
32:00
32:12
32:24
32:36
.6.7E3
.S.4E3
.4.0E3
.2.7E3
.1. 3E3
.O.OEO
Time
.2.4E5
.1.9ES
.1.4ES
.9. 6E4
.4.8E4
.O.OEO
Time
.5.9ES
.4.8E5
.3. 6E5
2.4E5
.1.2E5
O.OEO
Tine
1.1E6
8.9ES
6.7E5
4.4ES
2.2ES
O.OEO
Time
32:48
.6.4E3
.5.1E3
.3. 8E3
.2.6E3
.1.3E3
.O.OEO
TIM
133
-------
tile:S97t>749 11-397 Acq:16-OCT-lS97 14:27:22 EI+ Voltage "SIX 70s Koiae:71
423.7766 F:4 BSUS(2S6,30,-3.0) PXD(7,S,3,O.OS\,284.0,1.00\rfrT) Exp-.EPOJS
T&IAHGLE LASS Teit:H23 TBESHAL ISLET IB2 TZJf43431 BUT. TIME - 14:30
100%
so:
60.
40.
20.
A8.5SE3
3.7E3
'.3. OSS
'.2.2E3
1.5E3
.7.5E2
31:24 31i30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
T±lmiS976749 tl-397 Aoqtl6-OCT-1997 14i27t23 XI+ Voltage SIX 70S Noi**il06
425.7737 Ft4 BSUB(2S6r30,-3.0) ?XD(7rS,3,O.OS\,424.0,1.00*,r,T) Exp:EPCUS
TXIASGLE LASS TaxtiM23 TBEXMAL ISLET TB2 TLH43431 2KT. TIKE - 14:30
1003, A7.80E3
O.OEO
32:24 32:30 32 36. Time
6.4E3
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
ttl*:SS76749 tl-397 Adj:16-OCT-1997 14:27:22 EI+ Voltage SIS 70S Hoiae:290
435.8169 rs4 BSVB(256,30,-3.0) PKD(7,$,3tO.OS\,1160.0,1.00\,r,T) Eip-.EPCUS
OLIAXGLE LABS Taxt.-JOJ TSEXMAL ISLET FB2 XLII43431 XK7. TIME - 14:30
100\ A1.97Z6
flftl
50.
40.
20.
O.OEO
32:24 32:30 32.36 Time
r4.6E5
'.3.7ES
.2.8E5
-1.8E5
.9.2E4
O.OEO
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32.36 Time
•ile:S976749 tl-397 Aeq:16-OCT-1997 14:27:22 EH- Voltage SIX 70S Soiae:298
437.8140 T:4 BSVB(256,30,-3.0) PB>(7,5,3t0.05\,1192.0,1.00\,T,T) ExpsEPCUS
TXIAWSLZ LABS Text:M23 TBESMAL ISLET fB2 TLH43431 BET. TIME - 14:30
1003, A1.92E6 _4.«T5
SOJ
6oi
401
201
0 j . ^ ^ I" 0. OEO
'.2.6E5
11. 8E5
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32.36 Time
rile:S976749 tl-397 Aoq:16-OCT-1997 14:27:22 EH- Voltage SIX 70S
30.9729 r:4 Exp:EPCUS
LABS TmztstaS THEXMAL IXLXT TB2 TLH43431 ZKT. TIME - 14:30
rl.lS6
.8.7E5
.6.5S5
.4.4E5
.2.2ES
80.
60.
to:
sol
0:
O.OEO
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:IB 32:24 32:30 32 36 Time
134
-------
file:S976749 #1-397 Ac( 7,5,3, 0.05\,552. 0,1. 00\,T,T) Exp:EPCUS
TRIANGLE LABS TeXt:M23 THERMAL ISLET FB2 TLH43431 IKJ. TIME = 14:30
1001
901
801
701
601
sol
401
301
201
101
31
A7.00E3
1
A6.15X3 A4-38£3a6*3'1OZ:3 M'2.6E3 AS.OSE3 if*'?0*3 &3.39E3 |
^A/UWW>ALttsJtA^lk^^^
1 . 9E4
.1 . 7E4
.1 . 5E4
.1 . 3E4
.1 . 1E4
.9.4E3
.7.5E3
.5.6E3
.3.8E3
.1.9E3
00 32:00 33:00 34:00 35sOO Time
file:S976749 91-397 Aeq:16-OCT-1997 14:27:22 EI+ Voltage SIR 70S
430.9729 T:4 ExptEPCUS
TRIANGLE LABS Text:M23 THERMAL ISLET TB2 TLH43431 TtXT. TIME - 14:30
1001
901
801
701
601
sol
401
301
201
101
0:
31
*j\]\}\$$^^^
1.1E6
ll . OE6
.8.9ES
L7.8E5
'•.6.7ES
'•.5.6E5
.4.5ES
.3 . 4E5
.2.2E5
.1 . 1E5
O.OEO
00 32:00 ' 33:00 34:00 ' ' 35:00 Time
rile:S976749 tl-397 Acg:16-OCT-1997 14:27:22 EI+ Voltage SIR 70S
513.6775 T:4 Exp-.EPCCS
TRIANGLE LABS Teft:M23 THERMAL ISLET FB2 TLI 943431 TtU. TIME - 14: 30
1001
;
901
801
701
601
SOI
401
301
201
101
0
31
34s58 _4.5E3
33:14 1
32:50 33s 33 \
1 1
1 111
32:24 ill 34 T 1 ll
1 II 1 1 A 33:55 1 li ft 1 11 1 tn.3.5'^7
1 Hill II I III illflllfl! Jt5iH4l l"
31; 10 32:05 II i n 1 1 a III 1 1 Rul 1 II 111 HI 111 ill IHI i 111 1
1 A 1 i 1 II A A i 1JH IlliR III n Ilil n Ulll HI 111 II InA ilUMAliN Illlllil 1
HA! IJlA/iJ yil H llilliA lilrl A/MIll ifl(rllJ''vJli 1 hiflA InM flflJoL U IfflNliinvlJI MVliiln lIlwAlL
1
.4.1E3
.3.6E3
-3.2E3
-2.7E3
.2.3E3
.1 . SE3
_ 1 . 4E3
.9.0E2
.4.5S2
O.OEO
00 ' ' ' ' 32:00 33:00 34:00 35:00 Tiae
135
-------
*±-397 Acq:16-6CT-lii9/ 14:M:M E1+ Voltage SIS 70S Hoise:52
457.7377 F:4 BSUB(256,30,-3.0) PXD(7,S,3,O.OS\,20B.0,1.00\,r,T) ExpsEPCOS
TRIANGLE LASS Text:M23 THERMAL ISLET PB2 TLH43431 ZW. TIME - 14:30
100*
34i30 34,36 34,42 34:48 34:54
TilesS976749 tl-397 Acgtl6-OCT-1997 14:27:22 EI+ Voltage SIS 70S Boise:43
459.7348 Fi4 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,172.0,1.00\,T,T) Ezp-.EPCaS
TRIANGLE LASS Text:M23 THERMAL INLET FB2 TLH43431 IKJ. TIKE =* 14:30
100* A1.79E4
35:00
34:30 34:36 34:42 34:48 34:54
f±leiS976749 tl-397 Acq:16-OCT-1997 14:27:22 EH- Voltage SIR 70S Bo±oe:60
469.7779 T:4 BSTJB(256,30,-3.0) PKD(7,5,3,0.051,240.0,1.00\,r,T) ExpsEPCUS
TRIANGLE LASS Text:M23 THERMAL ISLET TB2 TLI#43431 XKT. TIME - 14:30
1001
80.
60.
40.
20.
35:00
34:30 34:36 34:42 34:48 34:54 35:00
rile:S976749 tl-397 Aoq:16-OCT-1997 14:27:22 EH- Voltage SIR 70S Noiae:S6
71.7750 Ti4 BSUB(2S6,30,-3.0) PXD(7,5,3,O.OS\,224.0,1.00\rr,T) Exp:EPCUS
TRIANGLE LABS Teit:M23 THERMAL ISLET TB2 TLIf43431 IHJ. TIME - 14:30
A2.68E6
80.
eo:
40.
20:
34:3034:36 . 34:42 34t48 34:54 35:00
File:S976749 tl-397 Acq:16-OCT-1997 14127:22 EI+ Voltage SIR 70S
30.9729 r:4 ElptEPCUS
TRIANGLE LABS T*xt:M23 THERMAL ISLET PS2 TLH43431 HET. TIME • 14:30
1003
so:
so:
to:
20:
o:
34^57
35 06 Time
O.OEO
35.06 Tiae
3.3E5
'.2. 7E5
'.2.0ES
.1.3E5
.6.6E4
35.
.0. OEO
06 Tiae
-3.9E5
.3.1E5
'.2.3E5
•.1.5E5
.7.7E4
O.OEO
34:30
34:36
34:42
34:48
34:54
35:00
35 06 Time
-1.1E6
'.8.8X5
'.6.6E5
.4.4E5
.2.2E5
O.OEO
35.06 Tims
136
-------
j Qiamel I
ifetat 1,67
Peak too
i oan
I Syst-s file ns*e
jOata filename
1 Resolution
| Grcup raacer
\ Icnizstton
13yi':chlng
' Ref, aassss
fl 233
6 384
C 386
0 316
E 318
F 329
li *^P^
H ^8
I 331
J
K
L
0
P
Q
R
331
332
334
348
342
352
354
356
358
EPCUS
2
El*
VOLTfiGE
416,9768
8 368
T 378
U 376
V 418
Ref, iass 416,9768 Peai< top
Height ,34 volts Span 288 ppi
137
-------
File:S976748 #1-397 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS
ample Text:M23 THERMAL INLET RUN#3 TLI#43431 INJ. TIME =
34:27 34:
13:50 File Text:M23 THERMAL I»
55
33:12 33:24 33136 33:48 34iOO 34112 34i24 34136 34148
File:S976748 #1-397 Acq:16-OCT-1997 13:48:03 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:M23 THERMAL INLET RUN#3 TLI#43431 INJ. TIME =
34,37
33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48
35:00 35:12 35:24 35:36 Time
13:50 File Text:M23 THERMAL I»
5.3E3
L4.8E3
_4.3E3
35:20 1.3.7E3
_3.2E3
_2.7E3
_2.1E3
_1.6E3
Ll.1E3
L5.3E2
O.QEQ
35IOO 35!l2 35:24 35:36 Time
-------
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: M23 THERMAL OUTLET RUN#I Analysis File: S976750
Client Project
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Asphalt Roofing Project
M23TRAIN Date Received:
185-5-6A-D Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor.
Blank Hie:
Analyst
09/29/97
10/01/97
10/16/97
n/a
S976745
BJG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976737
n/a
n/a
n/a
*«*•• .;.. :-/?
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
23,7,8-TCDF
1,2,3,7,8-PeCDF
2^,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,23,6,7,8-HxCDF
2^,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
•*«rf«t«."^ '"''' N:*^
^TOfalS'^.-' y'^t^^
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
> y&& *?*?, *w
- -^x— ,- ^ **F* i|l8llili»
0.009
ND
ND
ND
ND
ND
EMPC
ND
ND
ND
ND
ND
0.01
ND
ND
ND
ND
^•-flp^ ^f^yytif ''jt^f^y^tf'^ J|[^i!t*
Wi",'Z$t$y *^x9BS$t$f&g@$g&lfal
0.009 1
ND
ND
ND
EMPC
ND
0.01 1
ND
"^Vtvs y'jS&f&yi&i •. C?t-ff^^^^ '•> "• •,•" s\
%MF%» ^ ^-X^^^ v*1 r:lHF*-tf *•
0.008
0.01
0.008
0.008
0.01
0.07
0.004
0.005
0.005
0.006
0.004
0.006
0.007
0.01
0.01
v~v •.' |^ ttiukttr*
wef^ DL cMPv - ', -,- '^,<
0.008
0.008
0.01
0.009
0.005
0.008
f * ^ ^ ^ ' % •* "^ '-.'•"•-
0.80 21:12
_llir
—
^M^^
1.31 29:00
^__
^__ ^^
—
',
-------
v'!'• "-1'/* -::'
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: M23 THERMAL OUTLET RUN#I Analysis File: S976750
Intern^ Standards "* Amt (ng) , %R«cowy
"C,2-2,3,7,8-TCDF
l3C12-2,3,7,8-TCDD
I3C12-l,2,3,7,8-PeCDF
«CirlA3.7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C12-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C12-l,2,3,4,6,7,8-HpCDD
'3CI2-1,23,4,6,7,8,9-OCDD
£pt9Q9|ft Standards (?yp» &)*^f £i
"0-2A7.8-TCDD
13Ci2-2,3,4,7,8-PeCDF
13C12-l,2,3,4,7,8-HxCDF
13CI2-l,23,4,7,8-HxCDD
I3C12-l,23,4,7,8,9-HpCDF
AJtwnate Standards ffyp» A) Ai
vi**^ /!>s* <\»
13C12-l,2,3,7,8,9-HxCDF
3Ci2-2,3,4,6,7,8-HxCDF
^wiy^and»rf^^/^y'-^
|3C12-1,23,4-TCDD
l3CI2-l,2,3,7,8,9-HxCDD
3.1
3.0
2.8
2.9
3.8
3.5
3.1
3.5
7.6
«£t»
3.8
3.8
32
3.1
3.6
ntl:(ii«
32
3.5
78.1
74.2
70.4
72.1
94.1
88.3
76.7
88.5
95.1
ff £ ff fv """ +f ^^£w j
95.2
94.4
79.3
77.6
90.5
I): '"^|;% Recos^jf *-
79.9
86.8
QC Limits - x
40%- 130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%- 130%
25%-130%
^OdfcMr- -
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
QC Limits
40%-130%
40%-130%
$$%L „- ,'„ £
Ratio
0.76
0.80
1.49
1.41
0.49
1.17
0.42
1.04
0.87
*ft«fe
1.50
0.50
126
0.42
Ratio
0.50
0.50
^teftlO'^
0.82
121
- irr Ffe^sp
20:22
21:10
24:41
25:49
28:27
29:11
31:11
32:03
34:33
flT Flags >
21:11
25:27
28:21
29:06
32:24
•<&?- Flags
29:43
28:58
^ i . ??•..... '**""
20:56
29:29
.Data Reviewer.
10/21/97
Page 2 of2
X237J>SR TZOO. LARS 6.10.04
"'angle Laboratories, Inc.®
01 Capitola Drive • Durham, North Carolina 27713
hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:15 10/21/97
i 140
-------
Initial
..Dace..
Data Review By:
Calculated Noise Area:
0.38
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/21/97
Listing of S976750B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.
ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
KKTN
320-322
37C1-TCDD
328
DC
DC
DC
NL
1
NL
WL
0
18
:
:
00
55
0.
RO
65-0.89
0
1
.87
.31
Peak
0
19
19
19
20
:
:
:
:
:
00
12
32
53
08
0.
RO
RO
RO
RO
20:22
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
HH
WH
5
SN
SN
SN
SN
SN
SN
HH
HH
HH
1
20
21
22
:
:
:
50
24
35
RO
RO
RO
1
2
2
.16
.21 1.64
.21
65-0.89
1
1
1
0
• o
0
1
2
0
Peaks
18
18
20
20
21
21
22
:
:
:
:
:
:
:
28
54
35
52
12
35
07
22:28
22
22
:
:
32
39
0.
RO
RO
RO
.08
.00
.74
.74
.60
.76
.11
.67
.52
65-0.89
0
0
0
0
0
2
0
0
.67
.82
.78
.78
.80
.94
.63
.38
0.86
RO
3
.29
Peak
0
13
2
5
1
812
7
0
1
.67
.56
.02 1.98
.89 2.50
.36 0.59
.36 350.88
.10 4.46
.53
.91
0.825-1.102
0.
1.25 0.
000
929
0.951-1.049
0.
0.
000
943
1.14 0.959
3.39 0.
0.98 0.
461.48 1.
4.01 1.
1.
1.
976
989
000 13C12-2378-TCDF ISO
023
051
109
828.73
0
0
0
0
1
0
0
0
0
0
1
.10
.31
.73
.89
.67 0.74
.30
.39
.11
.41
.12
.67
0.856-1.059
0.
0.
0.
0.
0.93 1.
1.
1.
1.
1.
1.
872
893
972
986
002 2378-TCDD AN
020
045
061
065
070
0.906-1.094
DC
DC
DC
DC
DC
NL
WL
SN
SN
SN
0
18
19
19
:
:
:
:
00
46
36
52
20:03
20
20
21
21
21
21
:
:
:
:
:
:
11
46
11
31
37
44
0
0
7
0
0
0
0
500
2
0
1
.12
.29
.76 7.76
.43
.21
.30
.50 0.5O
.94 500.94
.80 2.80
.51 0.51
.40 1.40
0.
0.
0.
0.
0.
000
887
926
939
947
0.954
0.
1.
1.
1.
1.
981
001 37C1-TCDD SUR;
017
021
027
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:15 10/21/97
-------
page No. 2
10/21/97
Compound/
M Z..-- QC.Log omit Why
Listing of S976750B.db£
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area. Peak. 1. . Area. Peak. 2. . Rel.RT Confound. Name.. ID.. Flags.
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
340-342
13C12-PeCDF
352-354
352-354
21:51
21:57
DC SN 22:11
DC SN 22:11
22:20
DC SN 22:27
22:39
DC SN 22:50
10 Peaks
0,
DC NL 0:00 RO
DC WL 18:54
19:52
20:56
21:10
21:33
21:44
22:01
22:23
7 Peaks
DC NL 0:00
DC SN 22:44
DC SN 23:47
DC SN 24:54
DC SN 25:15
DC SN 25:38
DC SN 25:54
DC SN 26:17
DC SN 26:29
DC WK 26:43
0 Peaks
DC NL 0:00
23:46
24:18
24:41
25:00
25:27
25:59
DC SN 26:12
26:29
7 Peaks
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
.65-0.89
4.20
1
1
0
0
0
0
1
1
.15
.24
.82
.80
.82
.74
.44
.90
1
0
0
0
0
0
0
0
0
516
0
0
3
789
624
.48
.72
.39
.24
.58
.27
.66
.19
.35
.18
.60
.26
.03
.36
15.17
1.64
0.85
0.90
0.48
0.72
0.58
0.66
1.032
1.037
1.048
1.048
1.055
1.061
1.070
1.079
0.906-1.094
0.000
0.893
2
356
277
6
0
0
0
.28
.20
.43
.85
.70
.69
.97
1.84
432.83
346.93
8.32
0.94
0.48
0.51
0.939
0.989 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.018
1.
.027
1.040
1.057
,435.21
m/"?\»
32-1.78
0.82
0.85
1.30
0.86
0.35
0.23
0.23
1.27
0.56
0.73
•\ /
J /
0.907-1.080
0.15
0.48
0.92
0.31
0.12
0.08
0.
0.
0.
0.
0.
18
54
46
18
00
32-1.78
I.
1.
1.
1.
0.
1.
1.
6.
1.
11
65
65
49
89
50
66
71
18
1,
0.
20.
5.
629.
5.
576.
1.
0.
2.
241.
16
98
23
47
07
36
73
54
16
00
13.
3.
376.
3.
345.
1.
1.
06
26
55
08
56
08
31
0.
0.
0.
1.
000
921
964
009
1.023
1.
1.
1.
1.
1.
038
049
065
073
082
0.838-1.162
7.92
1.97
252.92
3.45
230.80
0.65
1.11
0.
0.
0.
1.
1.
1.
000
963
984
000 13C12-PeCDF 123 IS2
013
031 13C12-PeCDP 234 SUR2
1.0S3
1.
1.
061
073
Above: PeCDF / PeCDD Follows
tangle Laboratories, Inc.® Analytical Services Division
01 Capitola Drive • Durham, North Carolina 27713
hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:15 10/21/97
141
-------
Page No.
10/21/97
Listing of S976750B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
K_2 QC.Log Omit Why
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
PeCDD
356-358
356-358
13C12-PeCDD
368-370
368-370
HXCDF
374-376
374-376
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SK
WH
0
NL
SN
SN
SN
5
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
1
0:00
24:07
24:18
24:52
25:37
26:01
26:34
Peaks
0:00
24:42
24:51
25:02
25:26
25:49
25:57
26:22
26:36
Peaks
0:00
27:23
27:31
27:50
28:15
28:22
28:28
28:36
28:40
28:43
28:52
29:00
29:08
29:15
29:23
29:34
29:51
29:56
30:06
30:13
Peak
1.
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
32-1.78
0
0
0
0
0
0
5
.89
.44
.45
.38
.39
.67
.27
0
0
0
0
0
0
0
0
.13
.20
.16
.30
.18
.16
.28
.00
32-1.78
1
1
2
2
2
1
1
2
0
.00
.25
.00
.48
.82
.41
.70
.49
.84
ft'W.HVM* ,
05-1.43
1
7
2
0
0
1
0
0
1
0
4
1
0
0
1
0
1
2
1
3
.33
.86
.05
.47
.71
.16
.75
.69
.60
.40
.00
.31
.13
.08
.00
.78
.22
.80
.62
.25
0
1
1
0
0
361
51
1
0
416
.15
.23 0.75
.35 1.06
.74
.43
.17 211.47
.25 32.27
.40 1.37
.43
.40
0.921-1.026
0
0
0
0
0
1
1
.000
.934
.941
.963
.992
.008
.029
0.845-1.155
0
0.60 0
0.53 0
0
0
149.70 1
18.98 1
0.55 1
1
.000
.957
.963
.970
.985
.000 13C12 -PeCDD 123
.005
.021
.030
IS3
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
1
.21
.16
.43
.14
.18
.93
.54
.20
.11
.07
.22
.87 1.06
.07
.02
.43
.25 '
.20
.11
.29
.18
.87
0.956-1.053
0
0
0
0
0
0
1
1
1
1
1
0.81 1
1
1
1
1
1
1
1
1
.000
.963
.967
.978
.993
.997 123478-HxCDF
.001 123678-HxCDF
.005
.008
.009
.015
.019 234678-HxCDF
.024
.028
.033
.039
.049
.052
.058
.062
AN
AN
AN
13C12-HXCDF 0.43-0.59
384-386 DC NL 0:00 RO 0.80 0.23
27:21 RO 0.70 2.73
27:30 0.46 8.44
28:21 0.50 428.54
1.26
2.64
142.09
0.860-1.140
0.000
1.81 0.961
5.80 0.967
286.45 0.996 13C12-HXCDP 478 SUR3
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:15 10/21/97
142
-------
page No.
Listing of S976750B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.BT Conpound. Name.. ID.. Flags.
N
384-386
HXCDD
390-392
390-392
13C12 -HxCDD
102-404
«02-404
HpCDF
408-410
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
9
NL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0
NL
WL
WL
SN
SN
6
NL
28:27
28:44
28:45
28:58
29:23
29:43
30:02
30:11
30:15
Peaks
0:00
27:41
27:47
28:04
28:09
28:15
28:23
28:27
28:33
28:48
28:57
29:03
29:13
29:19
29:29
29:37
29:54
30:00
Peaks
0:00
27:52
28:07
28:34
28:50
29:06
29:11
29:29
29:46
29:55
30:02
Peaks
0:00
RO
RO
RO
RO
RO
1.
0
1
0
0
0
0
0
0
0
.49
.23
.45
.50
.86
.50
.80
.30
.42
*k
-------
?age No.
10/21/97
Listing of S976750B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
1.002 1234678-HpCDF AN
1.026
1.030
1.035
1.044
1.051
0.936-1.128
0.000
238.17 1.000 13C12-HpCDF 678 IS6
1.010
0.61 1.016
1.028
165.65 1.039 13C12-HpCDF 789 SUR5
1.057
D
408-410
13C12-HpCDF
418-420
418-420
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
WH
0
NL
SN
SN
SN
3
31:14
31:59
32:08
32:16
32:34
32:47
Peaks
0:00
31:11
31:30
31:41
32:04
32:24
32:57
Peaks
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
0.73
1.43
8.60
2.08
1.24
2.14
37-0.51
1.29
0.42
1.07
0.82
0.75
0.42
0.42
1
0
0
0
0
0
0
0
338
0
0
0
235
1
574
.12
.71
.10
.49
.51
.43
.00
.50
.11
.60
.88
.75
.96
.26
.95
99.94
0.50
70.31
HpCDD
424-426
D
D
424-426
13C12-HpCDD
436-438
436-438
---- — -- — ____________ ADOVB: npv-ur / npv.
0.88-1.20
DC
d
DC
DC
d
DC
DC
NL
SN
SN
SN
SN
SN
WH
0
0:00
31:27
31:41
31:56
32:04
32:08
32:36
Peaks
0
0
0
1
RO 0
1
RO 0
.89
.96
.91
.09
.86
.03
.72
0
1
0
0
1
0
0
0
.34
.53
.61
.48
.31
.63
.26
.00
0.88-1.20
DC
DC
NL
SN
2
0:00
31:27
32:03
32:36
Peaks
0
0
1
RO 0
.90
.93
.04
.10
0
3
358
0
.57
.08
.65
.20
0.977-1.006
0
0
0
0
1
1
1
.000
.981
.989
.996
.001 1234678-HpCDD AN
.003
.017
0.969-1.031
0
1.48 1.60 0
182.76 175.89 1
1
.000
.981
.000 13C12-HpCDD 678 IS7
.017
361.73
OCDF
442-444
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
0:00
31:16
31:25
31:31
31:41
32:02
34:17
34:55
35:03
35:52
Peaks
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
76-1.02
1.10
1
0
0
0
1
0
3
0
0
.31
.60
.33
.83
.48
.40
.80
.39
.20
0
0
0
0
0
0
0
0
0
0
0
.19
.49
.25
.23
.44
.40
.36
.76
.25
.15
.00
Octa-CDD and CDF Follows
0.884-1.116
0.000
0.905
0.909
0.912
0.917
0.927
0.992
1.011
1.014
1.038
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:
1/97
-------
Page No. 6 Listing of S976750B.dbf
10/21/97 Hatched GC Peaks / Ratio / Ret. Time
Confound/
M_Z QC-Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Sel.RT Compound. Hame.. ID., nags.
OCDD 0.76-1.02 0.884-1.116
4S8-460 DC ML 0:00 RO 1.11 0.17 0.000
M 34:35 RO 0.72 4.78 2.25 3.12 1.001 OCDD AH
DC SN 34:47 RO 1.19 0.68 1.007
DC SN 35:01 RO 0.57 0.62 1.014
458-460 1 Peak 4.78
13C12-OCDD 0.76-1.02 0.997-1.006
470-472 DC ML 0:00 1.00 0.22 0.000
34:33 0.87 490.73 227.97 262.76 1.000 13C12-OCDD IS8
470-472 1 Peak 490.73
Column Description "Why" Code Description QC Log Desc.
H_Z -Nominal Ion Hass(es) WL-B«low Retention Time Window A-Peak Added
..RT. -Retention Time (muss) HH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
rile:S976750 #1-829 Acg:16-OCT-1997 15:06:42 Eli- Voltage SIS 70S Hoises271
303.9016 T:2 BSUB(256,30, -3.0) PKD(9,5,5,0.05%, 1084.0,1.00%,T,T) ExpsEPCOS
TRIANGLE LASS Text:M23 TSESMAL OULET StOftl XLI#43431 INJ. TIME - 15:09
1003,
20
.
OJ
A1.71E4
A1.64E4
4.93E3
A9.96E3
\.79\E3\
A3L10E3
17:00 18:00 15-00 20:00 21:00
ttle:S976750 tl-829 Aoq:16-OCT-1997 15:06:42 EH- Voltage SIS 70S Soiee:311
305.8987 Ft2 BSUB(2S6,30, -3.0) TXD(9,5,5,O.OS\,1244.0r1.00\,T,T) ErptEPCUS
TRIANGLE LABS Teit:M23 THERMAL OULET RONtl TLI*43431 IXJ. TIME - 15:09
1001 A1.25E4
22: 00
17:00 18:00 15:00 20:00 21:00
Tile:S976750 tl-829 Acq:16-OCT-1997 15:06:42 EH- Voltage SIS 70S Noise:204
315.9419 T-.2 BSUB(256,30,-3.0) ?ED(9 ,5,5,0.05\, 816.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL OULET Rmrtl TLH43431 INJ. TIME - 15:09
1001 A3.51E6
60-
401
20J
OJ
22:00
17:00 18:00 15:00 20:00 21:00
File:S976750 fl-829 Acq:16-OCT-1997 15:06:42 ET+ Voltage SIS 70S Noise -.189
317.9389 JT:2 BSUB(256,30,-3.0) fXD(9,5,5,0 .05\, 7S6.0,1.00\rr,T) Exp-.EPCUS
TRIANGLE LABS Tsxt:M23 THERMAL OULZT RUB*! TLIf 43431 INJ. TIME - 15:09
1001
80J
40
201
22: 00
OJ
17:00 18:00 19:00 20:00 21:00
rile:S976750 tl-829 Acg:16-OCT-1997 15:06:42 Ell- Voltage SIS 70S
330.9792 T:2 ExpsEPCUS
TRIANGLE LABS TOIt:M23 THERMAL OULET RUftl TLH43431 UKT. TIME -
1001
SOJ
40
22:00
.7.3E3
.5.BE3
.4.4E3
.2.9E3
.1 . 5E3
.O.OEO
Tiae
OJ
.8.0E5
.6.4E5
.4.8E5
.3.2E5
.1 . 6E5
.O.OEO
Tiae
.1 . 1E6
.8.4E5
.6.3E5
.4.2E5
.2.1E5
.O.OEO
Tiae
.2.8E6
2.2E6
.1 . 7E6
1.1E6
5.6E5
O.OEO
17:00 18:00 19:00 20:00 21:00 22:00
Tile-.5976750 fl-829 Aoj:16-OCT-1997 15:06:42 EH- Voltage SIS 70S
375.8364 Ti2 ExptEPCUS
TRIANGLE LABS Text:M23 THERMAL OULET RUNtl TLII43431 XK7. TIME - 15:09
1001 15,-45
B01
17100
18:00
15:00
20:00
21»00
22:00
146
-------
ttl«:S9767SO tl-829 Acq:16-OCT-1997 15t06:42 EH- Voltage SIS 70S Koiae:91
319.8965 T:2 BSUB(256,30r-3.0) PXD(7,S,3,O.OS\,364 .Q,1.00\.,r,T) EzpsSPCUS
TRIANGLE LABS Text:M23 THERMAL ODLET RONtl TLIf43431 IM7. TIME » 15:05
1001
4.0E3
.3.2E3
A5.03E3
I F
A3.32f3 fl A1I\90E3 -
^yj^WVWlMyKWW:
'.2.4E3
Ll. 6E3
8.0E2
0.0 EO
22:00
19:00 20:00 21:00
-.3976750 fl-829 Acy:16-OCT-1997 15:06:42 EI+ Voltage SIS 70S Koine-.62
321.8936 T:2 BSnB(2S6,30,-3.0) fXD(7,5,3,0.05\,248.0,1.00\,F,T) Erp:EPCOS
TRIANGLE LABS Taxt:H23 THERMAL OULZT BONH TLH43431 XK7. TIME - 15:09
100* *—/ A1.09E4
A3.34E3
A3.23.
A4.10E3
A2.31E3
A2.97E3
Al. 70S3
22:00
15:00 20:00 21:00
TiletS9767SO tl-829 Acq:16-OCT-1997 15:06:42 SX+ Voltage SIS 70S Soiae:211
331.9368 T:2 BSOB(256,30,-3.0) PKD(7,S,3,O.OS\,844.0r1.00\rTrT) Ezp:EPCUS
TRIANGLE LABS Text:M23 TSERKAL OULET RUNtl TLIf43431 2K7. TIME - 15:09
A3.56E6
A2.77E6
40:
201
22:00
19:00 20tOO 21:00
rile:S976750 fl-829 Aoqsl6-OCT-1997 15:06:42 EI+ Voltage SIX 70S Noiae:49
333.9338 f:2 BSUB(2S6, 30, -3.0) PKD( 7,5, 3,0 .05\,196.0,1.00\,T,T) Elp-.EPCUS
TRIANGLE LABS Text:M23 TSERKAL OULET RUNfl TLIt43431 UKT. TIME - 15:09
A4.33E6
80: I\A3.47E6
60:
40:
20:
o:
22:00
19:00 20:00 21:00
Tile:S976750 tl-829 Aeqtl6-Od-1997 15:06:42 EI+ Voltage SIX 70S No±ae:60
327.8847 T:2 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,240.0,1.00\rT,T) Exp-.EPCOS
TRIANGLE LABS Text:M23 TSERKAL OULET RUNfl TLI443431 LKT. TIME * 15:09
1001 A5.01E6
sol
60:
40:
20:
0.
18:51 19:13 «:J1 20:0020:17
^-W>S/VS^W^V^V>^>'X'|A^IW^>»^»-^ "^^
-------
Fila:S976750 tl-829 Acq:16-OCT-1997 15:06:42 EI+ Voltage SIR 70S Mbi«e:47
339.8597 T:2 BSUB(256, 30, -3.0) PXD(7,5,3,0.05\,188.0,1.00\,F,T) ExpiEPCUS
TRIANGLE LABS Text:M23 THERMAL OULET RtOftl TLII43431 ZK7. TIME - 15:05
1001
ao:
60:
40:
20:
0:
A4.53IT3 2.5E3
A4.64E3 A4.59E3 |
AS • 64E3 1 1
jlKr^j^
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341.8567 F:2 BSVB(2S6, 30, -3. 0) PXD(7, 5, 3,0. 051,216. 0,1.00\,F,T) Ezp-.EPCVS
TRIANGLE LABS Teit:M23 TSERMAL OULET RUHtl TLIt43431 ZK7. TIME - 15:05
1001
80:
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351.9000 T-.2 BSDB(256,30,-3.0) PKD(7,S,3,O.OS\,192.0,1.00\,F,T) Ezp
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TRIANGLE LABS Text: #23 TSESMAL 'OULET RUJTtl TLIt43431 HKT. TIME - 15:09
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353.8970 F:2 BSUS(2S6,30,-3.0) PXD(7,5,3,0.05\,172.0,1.00\,F,T) ExpsEPCUS
TRIANGLE LABS Text:Jf23 TSERMAL OOLET RtOTtl TLIt43431 OCT. TIME - 15:05
1003
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TRIANGLE LABS Text:M23 TSERMAL OULET SUlTtl TLH43431 UCT. TIME - 15:05
100J
80:
60l
401
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[22:3622£5a23:15^23^36.2j^54
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409.7974 F:2 Exp:EPCUS
TSIASELf LABS fmrttlO3 TSERMAL OULET StOTtl TLH43431 HfT. TH
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WGLE LABS Teit:M23 THERMAL OOZET RtOHfl TLH43431 HKT. TIME - 15:05
k Al . 05E4
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8516 T:2 BSUS(256,30,-3.0) PXD(7, 5, 3,0 .051,180.0,1. 00\,T,X) Exp:EPCOS
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bA2.54X3
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24\00 ' • ' ' ' 25\00 ' ' ' • • 36rOO
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8949 Ti2 BSOB(256r30,-3.0) PXD(7,5, 3,O.OS\,180.0,1.00\,T,T) Exp:EPCUS
SSLE LABS Tezt:M23 THERMAL OOLET RWftl TLIt43431 1ST. TIME - 15:09
A3. 11X6
ft
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24:00 25:00 26:00 Time
:S976750 tl-829 Acq:16-OCT-1997 15:06:42 EH- Voltage SIX 70S Soiae:43
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HC££ LASS Teit:M23 TSEXMAL OOLET XOlftl TLJt4343I 1X7. TIME - 15:09
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330.9792 T:2 XxptEPCOS
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149
-------
file.-S976750 #1-475 Acq:16-OCT-1997 15:06:42 EH- Voltage SIS 70S Koiae:62
373.8208 T:3 BSOS(2S6,30, -3.0) PKD(7,5,3,0.05\,248.0,1.00\,r,T) Eip:EPCOS
TRIANGLE LASS Text:N23 THERMAL OOLET SOSfl TLIf43431 ZK7. TIME - 15:09
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36'29:48'30:00'30:12
SS976750 #1-475 Acq:16-OCT-1997 15:06:42 2J+ Voltage SIS 70S Jfoiae:47
375.8178 r:3 BSOS(256,30, -3.0) PKD(7,5,3,0.OS\,188.0,1.00\,T,T) E*p:EPCOS
TRIANGLE LABS Tert:M23 TBEXMAL OOLET XOXfl TLH43431 ZK7. TIME - 15:09
1004
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
JTile:5976750 #1-475 Acq:16-OCT-1997 15:06:42 EI+ Voltage SIS 70S Soiae:60
383.8639 f:3 BSOB(2S6,30t-3.0) PXD(7,5,3,0.051,240.Of1.00\,f,T) Exp:EPCOS
TRIANGLE LABS Text:X23 THERMAL OOLET RUSH TLXf43431 UKT. TIKE - 15:09
ion
sol
60:
40:
20:
o3a
Al. 6C4
A3.89E3
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Time
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1003
sol
60:
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20:
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A1.85Z6
A1.60E6
Al
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
File:S9767SO #1-475 Acq:16-OCT-1997 15:06:42 EH- Voltage SIX 70S Boise:77
385.8610 F:3 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,308.0,1.00\,T,T) Exp:EPCUS
TRIAHSLE LABS Tezt:M23 THERMAL OOLET RONtl TLIf43431 ZKT. TIME - 15:09
1003
so:
60J
40:
20:
A3.
A3.21Z6
A2.57r6
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ril»:S976750 #1-475 Aoj:16-OCT-1997 15:06:42 EH- Voltage SIX 70S
392.9760 F:3 Exp-.EPCOS
TRIANGLE LABS TezttM23 THERMAL OOLET RONtl TLIf43431 ZW7. TIME • 15:09
100} 27:3327:43 28:00 28:23 28:37 28:52 29:14 29:2729:37 29:54
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Time
27:24 27:36 27>48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
ril*iS976750 f1-475 Acqtl6~OCT-1997 15:06:42 EI+ Voltage SIX 70S
445.7555 T:3 EipiEPCOS
TXIAXGLZ LASS Tort:M23 THEXHAL OOLET XOSfl TLXf43431 OCT. TIME * 15:09
lOttt
so:
60:
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28
28:20
27:49
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.1.323
27:24 27:36 27-48 28:00 28:12 28:24 28:36 28:48 29x00 29:12 29:24 29:36 29:48 30:00 30:12
Tiae
150
-------
7ile:SS7S7SO 91-475 Acq:16-6Of-lS97 15:06:42 Eli- Voltage Sis 70S Noiae:51
389.0156 T:3 SSUS(256,30,-3.0) PXD(7,5,3,0,05\,204.0,1.00\,f,T) Exp:EPCUS
TRIANGLE LASS Text:M23 THERMAL OULET XUKtl TLIf 434 31 IXJ. TIKE - 15:09
1004 A5.91E3
27-46 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
ril»tS9767SO tl-475 Acqtl6-OCX-1997 15:06:42 Eli- Voltage SIS 70S 8oiaet37
391.8127 T:3 BSUB(2S6,30,-3.0) PKD(7,5,3,0.05\,148.0,1.00\,r,T) Exp:EPCOS
TRIANGLE LASS Text:H23 THERMAL OULET SUStl TLIf43431 ZK7. TIKE - 15:09
1001 AS.77E3
^2.6X3
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
riletS976750 tl-475 Acqsl6-OCT-1997 15:06:42 EI+ Voltage SIS 70S Koiaf.53
401.8558 F:3 SSUB(2S6,30,-3.0) PXD(7,5,3,0.051,212.0,1.00\,T,T) ExpiEPCUS
TRIAXGLE LASS Tsit:H23 THERMAL OULET EUNtl TZH43431 JK7. TIME * 15:09
100* A2.72E6
29:36 29:48
80J
60.
40.
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A2.36E6
-8.0X5
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37i4B 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
Tile:S976750 tl-475 Acq:16-OCX-1997 15:06:42 EI+ Voltage SIS 70S Roiae:43
403.8529 T:3 BSU3(256,30, -3.0) PXD(7,5,3,0,05\,172.0,1.00*,T,T) Exp:EPCUS
TRIANGLE LASS Text:M23 THERMAL OULET SUJTtl TLIf43431 1ST. TIME * 15:09
1001 A2.2SE6
80.
A2.01E6
6.7X5
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37:48 28:00 28:12 28:24 28:36 28:48 29-00 29:12 29:24 29\36 29-48
IS976750 tl-475 Acq:16-OCT-1997 15:06:42 EI+ Voltage SIS 70S
9760 T:3 Exp:EPCUS
fffLE LABS TtirttM23 IW^RM^r, OULET KUtftl TLH41431 1NJ. TTME m 15-09
28:00 28sl4 28:23 28s37 28:52 29i14 29t27 29:37 29:54
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
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Time
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Time
151
-------
•lie:SS76750 tl-397 Acq:16-OCT-1997 15:06:42 EI+ Voltage SIS 70S Hoise:23B
407.7818 T:4 BSVB(256,30, -3.0) PXD(7,5,3,0.05\,952.0,1.00\,r,T) Exp-.EPCVS
TSIAOGLE LASS Text:M23 THERMAL OULET BUNtl TLH43431 XKT. TIME - 15:09
1001
aol
601
•31:1.2 31:24 31:36 31:48 32:00 32:12 32:24 32:36
Tile:S9767SO tl-397 Acq:16-OCT-1997 15:06:42 EI+ Voltage SIS 70S Ho±*e:94
409.7789 Fi4 BSOB(2S6,30,-3.0) PXD(7,5,3,0.05\,376.0,1.00\,r,T) Exp-.EPCUS
TRIANGLE LABS Text:M23 THERMAL OULET SUStl TLIf43431 OKT. TIME - 15:09
31:12 31:24 31:36 31:48 32:00 32:12 32:24
r±le:S976750 tl-397 Acq:16-OCT-1997 15t06:42 EI+ Voltage SIS 70S Boise-.225
417.8253 T:4 BSUB(2S6,30,-3.0) PKD(7,S,3,0.05\,900.0,1.00\,rrT) Ezp:EPCUS
TSIASGLE LABS Text:M23 THERMAL OULET SWTtl TLIf43431 ZK7. TIME - 15s 09
1004 AS.SSE5
40:
201
0:
A4.98E3
r!.5£4
.1.2E4
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.5.9E3
.3.0E3
32:43
O.OEO
Time
32:36
32:48
80:
601
40:
20:
A7.03E5
31tl2 31:24 31:36 31:48 32:00 32:12 32:24 32:36
r±lesS976750 tl-397 Acq:16-OCT-1997 15:06:42 EI+ Voltage SIS 70S Bo±*e:173
419.8220 Ts4 3SU3(2S6,30,-3.0) PXD(7,5,3,0.05\,692.0,1.00\,T,T) SxpiZfCOS
TSIAWSLE LABS TextiH23 TBERHAL OULET SUNfl TLIf43431 1ST. HUE ' 15:05
1004 A2.38E6
32:48
00:
60:
40:
20:
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A1.66E6
32:24
32:36
31:12 31:24 31:36 31:48 32:00 32:12
Kle:S976750 tl-397 Acq: 16-OCT-1997 15:06:42 Eli- Voltage SIS 70S
430.9729 Ts4 ExptEPCDS
TSIASSLE LABS TextsM23 THERMAL OULET RUKtl TLIt43431 UKT. TIKE *• 15:05
1004 31tl6 ^. 31:34 . 31^54 32:07 __ 32j25 32*32 32L41
80:
60:
40:
20:
32:48
32124
31:12 31:24 31:36 31:48 32tOO 32:12
rile:S976750 tl-397 Aeysl6-OCT-1997 15:06:42 EH- Voltage SIS 70S
479.7165 Tt4 ExptEPCOS
TRIANGLE LABS T*Xt:M23 THERMAL OULET SORtl TLH43431 HKT. TIME -
1004
32:36
32:48
15:09
31:12
31:24
31:36
31:48
32:00
32:12
32:24
32:36
32:48
.2.6ES
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Time
.6.8ES
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Time
.1. OE6
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.6.0ES
.4.0E5
.2. OSS
.O.OEO
Time
152
-------
tile:SS7t>7SO tl-397 Ac
-------
rile:S976750 tl-397 Acq:16-OCT-1997 15:06:42 XI+ Voltage SIS 70S SoimesSS
441.7428 F:4 BSU3(2S6,30, -3.0) tJO>( 7,5, 3,0 .QS\,220.0,1.00\,rfT) ExpsEtCUS
TRIANGLE LABS Text:M23 TBESNAL OOLXT XUHfl TLIt43431 IW. TIKE - 15:09
ion
901
aoi
701
601
501
401
301
201
101
0
31
A1.52X4
, . A3. 39X3 A3. 29X3 . II A3. 26X3
-.2.7X4
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00 32:00 ' '33*00 ' 34:00 ' ' 35:00 Time
rile:S9767SO tl-397 Acg:16-OCT-1997 15:06:42 XI+ Voltage SIS 70S Soife-.SO
443.7399 r:4 BSUB(256,30, -3.0) fXD(7,S,3r0.05\r200.0,1.00\,r,T) Ezp:EPCUS
TSIASGLX LABS Text:M23 TBXSMAL OOLXT SOSfl TLIt43431 JK7. TIME - 15:09
ion
901
aoi
701
601
501
401
301
201
101
31
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00 ' ' '32:00 ' ' 33:00' ' ' 'j<:00' ' ' 35:00 Time
rile:S976750 tl-397 Ao%: 16-OCX-1997 15:06,42 EI+ Voltage SIS 70S
430.9729 T:4 XxpsSfCOS
XSIASGLE LABS Te*t:M23 TBESMAL OVLZT SWXtl TLH43431 UK7. TIME - 15:09
1001
90J
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701
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31:16 ,,.,4 31. 54 32:25 33:06 33:4534:03 34.34 35:41
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0.0X0
31:00 ' ' 32:00 33:00 ' ' 34:00 ' ' 35: 00' Time
rile:S9767SO tl-397 Aeq:16-OCT-1997 15:06:42 EI+ Voltage SIS 70S
513.6775 T:4 Xzp:EfCUS
TMIMHSLX LABS TeXttM33 TUXItMAT. OOOT SCOTtl TLIt43431 HKT. TIME " 15:09
1001
;
90.
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701
601
501
401
301
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31
34 19
34:39
32:32
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0.0X0
00 33*00 33«00 34:00' ' ' ' ' 35:00 ' ' ' ' Time
154
-------
rfile:S97(>750 #1-397 Acq:16-6tf-19S7 15:06:42 El+ Voltage SlS 70S Noiae:50
457.7377 Tt4 SSUB(2S6,30, -3. 0) PXD(7,5,3, 0. 05\,200.0,1.00\,r,T) Ezp:EPCUS
TSIANGLE LABS Text:M23 THERMAL OtTLET SUKfl TLH43431 INJ. TIME ' 15:09
A2.64E4
34s30 34s36 34s43 34:48 34:54 35:00
f±le:S976750 fl-397 Acgtl6-OCT-1997 15:06:42 XI+ Voltage SIS 70S Soiae:45
459.7348 T:4 BSUB(256,30,-3.0) PKD(7,5,3,0.051,180.0,1.00\,T,T) Ezp:EPCUS
TRIANGLE LABS Text:M23 THERMAL OULET SOHfl TLH43431 UKT. TIME - 15:09
lOOi. A1.9SE4
35.
O.OEO
06 Tim
A3.S7E3 A2.06E3
A5.10E3
-S.7E3
.7.0E3
.5.2E3
.3.5E3
'.1 . 7E3
34:30 34:36 34:42 34:48 34:54
TLLotS976750 fl-397 Acqsl6-OCT-l997 15:06:42 XT> Voltage SIS 70S Boiae:57
469.7779 T:4 BSUB(2S6,30, -3.0) PB>(7,5,3,0.05\,228.0,1.00\,T,T) Exp:EPCOS
TRIANGLE LABS Text:H23 THERMAL ODLET SOlTfl TLH43431 JK7. TIME - 15:09
1004 A2.28E6
35:00
34:30 34:36 34:42 34:48 34:54 35:00
T±letS976750 fl-397 Acq:16-OCT-1997 15:06:42 EI+ Voltage SIS 70S Noise:53
471.7750 F:4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\r212.0,1.00\,r,T) ExptEPCUS
TRIANGLE LABS Tozt:M23 THESMAL OOLET ROlTtl XLIf43431 HKT. TIME - 15:09
35
r3 . OE5
-2.4ES
.1 . 8E5
.1.2E5
.6.0E4
.O.OEO
06 Time
lOOi,
3E6
34:30 34:36 34:42 34:48 34:54
Til*,S9767SO fl-397 Acq:16-OCT-1997 15:06:42 XX+ Voltage SIS 70S
130.9729 r:4 EzptZPCOS
TRIANGLE LABS Text:M23 THERMAL OOZET SURfl TLH43431 UKT. TIME •
J/i^L___-.__^^C _52\_^ 34sS1
so:
so.
40:
20:
o.
35:00
15:09
-3.3ES
.2.6E5
'.2.0ES
-1.3ES
-6.5E4
35.
.O.OEO
06 Time
34:30
34:36
34:42
34:48
34 > 54
35:00
35L04 r9.9ES
•*.
.7.9E5
.5.9ES
.4.0E5
.2.0ES
, o.oro
35 06 Time
155
-------
on
tod I 328,5792 Peak top
| Height l,67voU- Span 288 cpi
Systa fits na*MS"
Data rilenaie 3-83^741
Resolution
SPOUP nuaber
•aifiOE
29E.38S, 416,
J 331 ' S
I 332
I 334
D 34@
H 342
0«JM
»"X
vwC
P 354
9 3S
R 3K
T 378
U 376
V 418
, MSS 416,3780 Peak top
Height ,34Molti Span ^9ppi
156
-------
ile:S976750 #1-397 Acq:16-OCT-1997 15:06:42 El+ Voltage SIR 70S
57.7377 F:4 Exp:EPCUS
ample Text:M23 THERMAL OULET RUN#1 TLI#43431 INJ. TIME = 15:09 File Text:M23
00% A2.25E4
90J
80J
70-i
60J
50
30
20J
10
0
33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24
File:S976750 #1-397 Acq:16-OCT-1997 15:06:42 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:M23 THERMAL OULET RUN#1 TLI#43431 INJ. TIME = 15:09 File Text:M23
100% A3.12E4
90 j
80 j
70J
60J
50J
40J
30J
20J
10J
0
33:48
34:00
34 112
34:24
34 I 36
34:48
35! 00
_,——r.
35:12
35:24
THERMAL O»
_6.3E3
L5.7E3
L5.1E3
L4.4E3
L3.8E3
L3.2E3
L2.5E3
L1.9E3
L1.3E3
L6.3E2
LO.OEO
Time
THERMAL O»
_9.8E3
_8.8E3
_7.8E3
_6.8E3
_5.9E3
_4.9E3
_3.9E3
L2.9E3
L2.0E3
L9.8E2
LO.OEO
Time
-------
File:S976750 #1-829 Acq:16-OCT-1997 15:06:42 EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text:M23 THERMAL OULET RUN#1 TLI#43431 INJ. TIME =
15:09 File Text:M23 THERMAL O»
_5.OE3
20:00 21:00 22:00
File:S976750 #1-829 Acq:16-OCT-1997 15:06:42 EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS
Sample Text:M23 THERMAL OULET RUN#1 TLI#43431 INJ. TIME =
100% A9.34E3
23:00
15:09 File Text:M23 THERMAL O»
_4.5B3
20:00
21:00
22:00
23:00
.O.OEO
Time
-------
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: M23 THERMAL OUTLET RUN#2 Analysis File: S976757
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Asphalt Roofing Project
M23TRAIN Date Received:
185-5-7A-D Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/01/97
10/16/97
n/a
S976745
MS
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976754
n/a
n/a
n/a
Anafytes ,
2,3,7,8-TCDD
U,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
U3,4.6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2^,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
U3,4,6,7.8-HpCDF
1,2,3,4,7,8,9-HpCDF
1A3,4,6,7,8,9-OCDF
'%*ate'Jy^- * ;^ ' /-,
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeODF
Total HxCDF
Total HpCDF
Aftrt. {ng};:?
ND
ND
ND
ND
ND
0.02
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
r:AM&*fegi
ND
ND
ND
0.05
ND
ND
ND
ND
* T toL -, mtV ' ' 8dt»- ITT Ffe*gs'
0.009
0.01
0.01
0.01
0.01
1.00 32:07
0.02
0.006
0.009
0.009
0.008
0.006
0.008
0.01
0.01
0.02
0.02
»wi*r^0L pspfetfe'* "'::'-, - ,, *%#$!
0.009
0.01
0.01
2
0.006
0.009
0.008
0.01
Page 1 Of 2
X237.PSRviOaiARS6.10jM
Triangle Laboratories, Inc.®
pOi Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:07 10/20/97
159
-------
stern
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: M23 THERMAL OUTLET RUN#2 Analysis File: S976757
internal Standards - AmL (ng) V;3£FtaeowM?
l3C12-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C12-l,2^,7,8-PeCDF
13C,2-123,7,8-PeCDD
l3CI2-l,23,6,7,8-HxCDF
13C,2-123,6,7,8-HxCDD
I3CI2-l,2^,4,6,7,8-HpCDF
l3Ci2-12^,4,6,7,8-HpCDD
13CI2-123,4,6,7,8,9-OCDD
3.5
3.3
3.3
3.3
4.0
4.1
3.0
3.8
7.7
87.8
81.7
81.5
82.3
101
103
75.2
94.5
95.8
y QC Limits
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
Ratio
0.77
0.78
1.49
1.52
0.50
121
0.42
0.98
0.88
' ST Flags
/x •. x ? j-
20:25
21:13
24:43
25:51
28:29
29:12
31:13
32:04
34:36
;S!Srrogate^^ ;:;^p**^ove^ <3C1^; '~£trtalfof -«*-' 8T : flags
*C]4-2^,7,8-TCDD
I3C12-2,3,4,7,8-PeCDF
13C,2-l,23,4,7,8-HxCDF
I3CI2-123,4,7,8-HxCDD
I3Ci2-l,23,4,7,8,9-HpCDF
AlteirialB Staindasds(T^» ^11;. An
>•" **"' ' % % . . ^ . .
13C,rU3,7,8^-HxCDF
13Ci2-Z3,4,6,7,8-HxCDF
.I1 ' '''** gtff^ ,y V, t ^&^ ^' - *^
Recovery ^^tufitfask^-,, v^w^ -^
l3Ci2-l,23,4-TCDD
13C,2-123,7,8,9-HxCDD
3.9
3.7
32
2.8
3.7
it.(ng)
3.4
3.8
-S4^
98.0
91.7
78.9
70.5
92.5
risi^iBF
85.1
93.9
*$• ** f *'>£, v •*•• %f+A ff-
&•£$&&*£ f^* "• s? 3?' X^
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
fc «qiinirl^
?•; ^h, ..,$,.••<'&'>"
40%-130%
40%-130%
i ' ^^: :
1.50
0.49
120
0.42
^!Wto^ .
0.50
0.48
,v -
0.80
1.19
21:14
25:29
28:23
29:08
32:27
1 "8T ^tNigs '
29:44
29:00
*';RT Flags
20:59
29:30
Data Reviewer.
Page 2 of2
10/20/97
X237.PSR tZOO. LARS 6.10.0*
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:07 10/20/97
160
-------
Data Review By:
Calculated Noise Area:
0.73
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
page No.
10/20/97
Listing of S97S757B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
H Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
D
D
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
D
320-322
37C1-TCDD
328
DC
DC
d
d
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
0
NL
WL
SN
WH
WH
3
NL
SN
SN
0
NL
WL
WL
WL
ML
ML
WL
WL
0:00
16:59
20:00
20:26
Peaks
0:00
19:16
19:59
20:25
20:54
21:08
21:40
22:09
Peaks
0:00
19:22
21:03
Peaks
0:00
18:10
18:32
18:45
18:48
18:51
18:56
19:10
19:32
19:38
19:53
20:05
20:19
20:29
20:37
21:14
21:37
0.65-0.89
0.83
RO 0 . 97
RO 1.03
0.89
0.65-0.89
0.80
0.82
0.86
0.77
RO 0.55
RO 0.22
RO 0.24
RO 1.52
_ *Vv-r
0.65-0.89
0.72
RO 1.38
RO 0.57
1.17
1.08
1.61
2.86
0.00
1.19
17.56
6.52 3.01
936.79 406.84
5.82 2.53
0.92
0.53
0.99
949.13
1.03
0.51
2.00
0.00
0.60
0.56
1.35
0.98
0.51
0.46
0.56
1.50
0.81 0.81
6.50 6.50
0.82 0.82
1.24 1.24
1.50 1.50
0.89 0.89
0.94 0.94
582.26 582.26
1.29 1.29
0.826-1.103
0.000
0.832
0.980
1.001 2378-TCDF AN
0.951-1.049
0.000
0.944
3.51 0.979
529.95 1.000 13C12-2378-TCDF ISO
4/60 1.024
1.035
1.061
1.085
0.858-1.060
0.000
0.913
0.992
0.906-1.094
0.000
0.856
0.874
0.884
0.886
0.888
0.892
0.903
0.921
0.925
0.937
0.947
0.958
0.965
0.972
1.001 37C1-TCDD SDR1
1.019
riangle Laboratories, Inc.® Analytical Services Division
Capitola Drive • Durham, North Carolina 27713
y. (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:08 10/20/97
161
-------
Page No.
10/20/97
Listing of S976757B.db£
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Coopound.Name.. ID.. Flags.
328
13C12-TCDD
332-334
K
332-334
PeCDF
340-342
340-342
13C12-PeCDF
352-354
352-354
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
12
NL
WL
WL
WL
SN
SN
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
SN
SN
6
21:39
21:45
21:50
21:56
22:02
22:10
22:40
Peaks
0:00
18:31
18:56
19:05
19:16
19:25
19:44
20:04
20:59
21:13
21:36
21:44
Peaks
0:00
22:43
23:26
24:36
24:43
25:02
25:20
25:40
25:49
26:19
Peaks
0:00
23:48
24:21
24:43
25:02
25:13
25:29
25:55
26:20
26:30
26:42
Peaks
0.
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
1
0
1
0
0
0
1
601
.67 1.67
.76
.50 1.50
.47
.58
.50
.85 1.85
.27
65-0.89
2
0
1
6
0
1
6
4
0
0
0
1
.50
.80
.28
.11
.65
.13
.31
.80
.80
.78
.80
.57
1
32-1.78
0
0
1
0
2
1
1
0
1
1
.68
.20
.68
.33
.74
.60
.00
.45
.95
.68
0
1
0
0
0
1
0
0
809
704
15
1
.74
.51
.76
.34
.94
.49 0.95
.87
.78
.13 358.55
.64 308.71
.12 6.71
.06
1
1
1
1
1
1
1
.020
.025
.029
.034
.038
.045
.068
0.906-1.094
0
0
0
0
0
0.84 0
0
0
450.58 0
395.93 1
8.41 1
.000
.873
.892
.899
.908
.915
.930
.946
.989 13C12-1234-TCDD
.000 13C12-2378-TCDD
.018
RSI
IS1
1.024
,530.38
0
0
0
0
0
0
0
0
0
.35
.33
.59
.39
.79
.65
.92
.58
.56
1.10
0
.00
32-1.78
0
1
1
1
1
1
1
1
1
0
.78
.41
.21
.49
.12
.32
.50
.69
.31
.85
0.76
X
0
25
4
747
8
1
664
2
1
1
0
,452
.23
.68 15.04
.20 2.55
.56 447.80
.11 4.93
.44
.82 399.24
.02
.17
.73 1.05
.56
.10
0.908-1.080
0
0
0
0
1
1
1
1
1
1
.000
.919
.948
.995
.000 12378-PeCDF
.013
.025
.038
.045
.065
AN
0.838-1.162
0
10.64 0
2.10 0
299.76 1
4.41 1
1
265.58 1
1
1
1.23 1
^
.000
.963
.985
.000 13C12-PeCDF 123
.013
.020
.031 13C12-PeCDF 234
.049
.065
.072
.080
IS2
SUR2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive* Durham, North Carolina27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:08 10/20/97
162
-------
page No.
10/20/97
Listing of S976757B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z QC.Log Omit Why . .RT. OK Ratio Total.Area... Area. Peak. 1. . Area.Peak.2. . Rel.RT Compound. Name.. ID.. Flags.
peCDD
356-358
356-358
13C12-PeCDD
368-370
368-370
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
WH
0
NL
SN
SN
SN
SN
SN
SN
2
0:00
23:57
24:22
25:05
25:24
25:31
26:30
26:37
Peaks
0:00
23:52
24:00
24:53
25:30
25:37
25:51
26:00
26:33
Peaks
1.
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
32-1.78
2.08
3.
94
0.55
1.
0.
2.
3.
4.
57
89
03
13
85
0.31
0.46
0
1
0
1
0
0
0
.38
.31
.41
.56
.38
.33
.00
32-1.78
0.
2.
2.
0.
1.
1.
1.
1.
2.
93
47
79
53
94
70
52
26
15
0
0
0
1
0
0
422
53
0
476
.21
.48
.87
.18
.43
.73
.75
.32
.69
.07
/ PeCDD Follows
254.67
32.41
168.08
25.71
0.921-1.027
0.000
0.926
0.943
0.970
0.983
0.987
1.02S
1.030
0.845-1.155
0.000
0.923
0.928
0.963
0.986
0.991
.000 13C12-PeCDD 123 IS3
1.006
1.027
; HXCDF
1374-376
D
374-376
13C12-HXCDF
$84-386
DC
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0
NL
SN
0:00
27:59
28:09
28:23
28:30
28:41
28:44
28:48
29:02
29:12
29:17
29:22
29:26
29:34
30:00
30:05
30:10
Peaks
0:00
27:22
27:32
27:42
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
.05-1.43
2
1
1
2
1
0
1
2
0
3
1
1
4
2
4
0
2
.00
.57
.75
.10
.13
.54
.06
.14
.92
.13
.50
.14
.67
.00
.50
.37
.88
43-0.59
0.53
0
0
0
.52
.49
.47
0.27
0.31
0.27
0.69
0.81
0.25
0.33
0.16
1.68
0.36
0.27
0.30
0.20
0.07
0.22
0.13
0.18
0.00
0.49
4.01 1.37
10.39 3.42
0.66
0.957-1.054
0.000
0.982
0.988
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
996 123478-HxCDF AN
001 123678-HxCDF AN
007
009
Oil
019 234678-KxCDF AN
025
028
031
033
038
053
056
059
0.860-1.140
0.000
2.64 0.
6.97 0.
961
967
0.972
Laboratories, Inc.® Analytical Services Division
1 Capitola Drive • Durham, North Carolina 27713
tone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:08 10/20/97
163
-------
Page No. 4
10/20/97
Compound/
M_Z. . . . QC.Log Offlit Vftry
Listing of S9767S7B.dbf
Hatched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
384-386
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
10
28:11
28:23
28:29
28:44
28:53
29:00
29:17
29:25
29:32
29:44
30:05
30:15
30:21
Peaks
RO
RO
RO
RO
RO
RO
RO
0.78
0.49
O.SO
0.21
0.31
0.48
0.47
0.46
0.25
0.50
0.75
2.11
0.21
0.60
546.25 180.70
721.72 239.74
365.55
481.98
2.19
2.43 0.82
620.79 200.75
3.26 1.04
2
0
489
.68 0.85
.77
.04 162.31
2.54 1.26
0
0
.27
.21
2.68
420.04
2.22
1.83
326.73
1.68
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
989
996 13C12-HXCDF 478
000 13C12-HXCDF 678
009
014
018 13C12-HXCDF 234
028
033
037
044 13C12-HXCDF 789
056
062
066
SDR3
IS4
ALT2
ALT1
2.403.11
RxCDD
390-392
D
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
MH
0
NL
SN
6
NL
SN
SN
SN
0:00
27:52
28:02
28:08
28:16
28:23
28:28
28:38
28:46
29:00
29:09
29:14
29:31
30:00
Peaks
0:00
28:35
29:08
29:12
29:30
29:45
29:50
29:56
Peaks
0:00
31:28
31:35
31:42
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
0.
RO
RO
RO
05-1.43
0.52'
0.65
1.86
4.50
0.25
2.06
2.65
0.84
0.22
1.45
0.84
2.72
0.81
0.44
05-1.43
0.38
0.96
1.20
1.21
1.19
1.53
1.31
0.79
88-1.20
3.78
0.82
1.33
0.93
0
.20
0.
0.20
0
0
0
1
0
2
0
0
0
0
1
0
0
0
3
415
606
593
2
2
1
.16
.09
.11
.12
.45
.35
.18
.49
.83
.72
.21
.13
.00
.20
.63 2.01
.94 227.23
.75 '332.37
.17 322.79
.96 2.02
.08 1.18
.32
0.
2.09
188.71
274.38
270.38
1.32
0.90
951-1.016
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
000
954
960
963
968
972
975
981
985
993
998 123478-HxCDD
001 123678-HxCDD
Oil 123789-HxCDD
027
AN
AN
AN
966-1.034
0.
0.
0.
1.
1.
1.
1.
1.
000
979
998 13C12-KXCDD 478
000 13C12-HXCDD 678
010 13C12-HXCDD 789
019
022
025
SUR4
IS5
RS2
1,624.53
0
0
0
0
.18
.98
.49
.54
0.
996-1.047
0.
1.
1.
1.
000
008
012
015
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:08 10/20/97
164
-------
page No.
10/20/97
Listing of S976757B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Confound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Confound.Name.. ID.. Flags.
1.022
1.026
1.034
1.043
1.057
408-410
13C12-HpCDF
418-420
418-420
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
WH
0
NL
SN
3
31:54
32:02
32:16
32:34
32:59
Peaks
0:00
31:13
31:30
32:03
32:27
Peaks
RO
RO
RO
RO
RO
0.
RO
RO
RO
8.33
4.89
1.
2.
7.
96
13
00
0
0
0
0
0
0
.12
.18
.51
.49
.41
.00
37-0.51
1.
0.
1.
1.
0.
28
42
28
20
42
0
395
1
0
282
678
.56
.44
.41
.94
.05
.90
116.85
1.25
83.57
0.936-1.128
0.000
278.59 1.000 13C12-HpCDF 678 IS6
0.98 1.009
1.027
198.48 1.040 13C12-HpCDF 789 SHR5
HpCDD
424-426
DC
NL
0:
:00
0
RO
31:30
M
424-426
13C12-HpCDD
436-438
DC
DC
SN
SN
31:51
31:58
RO
RO
32:07
DC
DC
WH
2
NL
32:27
RO
ADOW: Hp>_ijr / HJH.
.88-1.20
0.
.60
0.94
1.93
0.
.41
1.00
2.43
Peaks
0:00
0.
RO
31:30
436-438
OCDF
442-444
442-444
OCDD
458-460
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
3
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
32:
32:
32:
32:
04
24
33
37
RO
RO
RO
0
3
.18
.60
0.29
0.33
2
.68
0.71
0.978-1.007
0
.000
1.74 1.86 0.982
0,
0.
.993
.997
1.34 1.34 1.002 1234678-HpCDD AN
1.
.012
6.28
.88-1.20
0.
1.
0.
1.
2.
1.
86
14
98
54
39
55
Peaks
0:
31:
33:
34:
34:
34:
35:
35:
35:
35:
00
28
40
21
38
49
10
23
30
43
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.28
4.31
456.98
3.30
0.
.67
0.59
0.969-1.031
0.
2.30 2.01 0.
226.11 230.87 1.
2.49 1.62 1.
1.
1.
000
982
000 13C12-HpCDD 678 IS7
010
015
017
464.59
u»*/Tir
\ / /•*«•*»
76-1.02
0.
0.
0.
0.
0.
1.
3.
1.
0.
1.
71
26
56
95
32
04
26
06
53
04
Peaks
0:
00
0.
RO
0.
0.
0.
0.
0.
1.
0.
1.
0.
64
19
72
43
15
06
43
17
53
0.49
0.
00
76-1.02
0.
67
0.
17
0.884-1.116
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
000
909
973
993
001
006
016
023
026
032
0.884-1.116
0.
000
Triangle Laboratories, Inc.® Analytical Services Division
l Capttola Drive • Durham, North Carolina 27713
(919) 544-5729 • Fax: (919) 544-5491
Printed: 19:08 10/20/97
IBS
-------
Page No. 6 Listing of S976757B.dbf
10/20/97 Hatched GC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
D d SN 34:36 0.95 2.60 1.000 OCDD AN
DC SN 34:48 RO 2.11 0.34 1.006
DC SN 35:00 1.00 0.48 1.012
DC SN 35:06 0.84 0.59 1.014
458-460 0 Peaks 0.00
13C12-OCDD 0.76-1.02 0.998-1.007
470-472 DC NL 0:00 1.00 0.22 0.000
34:36 0.88 589.86 276.37 313.49 1.000 13C12-OCDD IS8
470-472 1 Peak 589.86
Column Description 'Why code Description QC Log Desc.
M_Z -Nominal Ion Hass(es) WL-Below Retention Tine Window A-Feak Added
..RT. -Retention Time (nm:ss) WH-Above Retention Time Window X-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
rile>S976757 #1-8.25 Acqil6-OCT-1997 21:31:29 EH- Voltage SIX 70S Noise:264
303.9016 Ts2 BSUB(2S6,30,-3.0) PXD(9,5,5,0.05\,1056.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LASS Toxt:M23 THEKHKL OUTLET SUSt2 TLH43431 IXJ. TIME * 21:34
1001
80.
17:00 18'tOO 19:00 20!00 21:00 22:00
Tile:S9767S7 tl-829 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIS 70S Ko±Be:321
305.8987 Ts2 3SUB(256,30,-3.0) PKD(9,5,5,0.05\,12S4.0,1.00\,r,T) ExpiEPCUS
TRIANGLE LABS Text:H23 THERMAL OUTLET SUNt2 TLIt43431 ZKJ. TIME - 21:34
1004 A1.33E4
O.OEO
Time
17-00 18:00 19:00 20:00 21:00
rile:S976757 tl-829 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIS 70S Soiae:263
315.9419 T:2 BSUB(256,30,-3.0) PXD(9,5,5,0.05\,10S2.0r1.00\,r,T) ExpiEPCUS
TRIANGLE LASS Text:H23 THERMAL OUTLET RUN*2 TLI»43431 IK7. TIME = 21:34
1003t A4.07ES
80J
60.
40:
20:
22: 00
oj
17:00 10:00 15:00 20:00 21:00
Tile:S976757 tl-829 Acq:16-OCT-1997 21:31:29 EH- Voltage SIS 70S Koine:323
317.9389 T:2 BSUB(2S6,30r-3.0) PKD(9r5,S,O.OS\,1316.0,1.00\,e,T) Exp-.EFCUS
TRIANGLE'LABS Text:M23 THERMAL OUTLET RUNt2 TLIt43431 XK7. TIME ' 21:34
A5.30E6
22:00
40
Oj
17:00 18:00 19:00 20:00 21:00
Kle:S976757 tl-829 Acq:16-OCX-1997 21:31:29 EI+ Voltage SIS 70S
330.9792 T:2 Eip:EPCUS
TRIANGLE LABS Teit:M23 THERMAL OUTLET St3ttt2 TLH43431 HKT. TIME - 21:34
22:00
lOOi
80:
60:
40:
20:
0.
17:2717:4818:10 18:40 19tl3
20:00 20:23 20:45 21:07
17:00 18:00 15:00 20:00 21:00
file:S976757 tl-829 Aeq:16-OCI-1997 21:31:29 EH- Voltage SIX 70S
75.8364 Ts2 Ezp-.EPCUS
TRIANGLE LABS Text:M23 THERMAL OUTLET SOJTt2 TLIt43431 ZK7. TIME • 21:34
18:22
22:00
9.0E5
.7.2E5
'-S.4ES
.3.6E5
ll. 8E5
.O.OEO
Xiae
-1.1E6
8.8E5
6.6E5
4.4E5
2.2ES
.O.OEO
Time
.8.2E6
6.6E6
4.9E6
3.3E6
1. 6E6
O.OEO
1R7
-------
rilt>:S9767S7 #1-829 Aeq:16-OCT-1997 21:31:29 EI+ Voltage SIS 70S Hoist,: 217
319.3965 T:2 BSUB(256, 30, -3. 0) PKD(7 ,5,3,0 .OS\, 868. 0,1. 00\,T,T) ExpsEPCOS
TBIANGLE LABS Text:M23 TSESHAL OUTLET SUN*2 TLI*43431 OKT. TOtE *
1001 A9.18E3
,.j i A4.04E3
80J 1
50:
40:
1
20:
o:
i U A8.S7E3 I! i
ill AI"lfifl 1 ll i I lAJ | flU
n\ An. . . iPvln II i . In i i ii Art R- In 11. i n llPH-0-*-8?/ 1 viill
Irtj^wwl^ ft
III 111' l V I lU'll Iff 1 1
Alt ' /
//"mW
15:00 20:00 21:00 '
F±le:S9767S7 #1-825 Aeq;:15-OCT-1557 21:31:29 EH- Voltage SZH 70S Hoi**:
21.-J4
,_.J.5r.3
AJ.34W
. 1
ill 1 1 1 A3.25E3
II II i S | 111 /
/ vifl AIM u\JM WW v^l
i_j i i r — u
'
'_2.BE3
''.2.1E3
: j.4B3
.7.0E2
• o . oro
22:00 riffle
258
321.8936 T:2 BS03(256r30, -3.0) PXD(7,S,3,O.OS\,1192.0,1.00\,r,T) Ezp:EPCUS . , I,1)-*-)'
TS1ASGLE LABS Text:M23 THERMAL OUTLET SO1T«2 TLH43431 OCT. TIMS -
1001
80:
'.
50:
40:
20:
0:
A1.53E4
, A9.89E3
,A i
A4 53E3 V 111 A
21:34 ^-.'Z-Vf '
\At^ p5.5E3
i j| " i » . lA6 . 88E3A4 . 15E3 jlln III 1 llM */ 1 til 11
^"^Hu/ '! \TM | III 1 III I ' f T W W
15:00 ' ' '20:00 21:00 '
14.4E3
'.3.3E3
-2.2E3
Ll . 1EJ
F 0 . OEO
22:00 riae
File:S97S7S7 #1-825 Actj:16-OCT-1997 21:31:29 EH- Voltage SIX 70S Boise: 525
331.9368 Ts2 BSUB(2S6, 30, -3.0) PKD(7 , S,3,0 .05\, 2100 .0,1. 00\,T,T) Exp-.EPCOS
TBIANGLE LABS Text:M23 THERMAL OUTLET RUN*2 TLI043431 XKT. TIME -
100]
so:
50:
40.
20:
o:
J1J.|5£5
1JU.05£5
fi i
A
1
7 VJ v_
' 15:00 20:00 21:00 '
21:34
-5.4E5
.7.5E5
.5.5E5
. J . 8E5
.1.SE5
O.OEO
'22:00 Mae
Hie :S5 7575 7 #1-825 Acq:16-OCT-1997 21:31:29 EX+ Voltage SIX 70S Boise: 20 8
333.9338 Ti2 BSUB(256,30,-3.0) PKD(7,S, 3,0. 051,832. 0,1.00\,r,T) Exp-.EPCUS
TSIASGLE LABS Tert:M23 TBESMAL OUTLET SVJH2 TLH43431 OCT. TIME -
ion
sol
so:
40.
20:
OJ
A4 51£5
|)j|J.55£5
7 vj
v^
' 15:00 20:00 21:00 '
21:34
_i.ir«
.S.4ES
.6.3ES
.4.2ES
.2.1E5
O.OEO
'22:00 Tlae
Xile:S575757 91-829 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIX 70S Boise: 301
327.8847 T:2 BSUB(256,30, -3 . 0 ) PXD(7, 5, 3, 0.051,1204 .0,1. 00\,r,T) gxptXPCOS
TRIANGLE LABS Te*t:M23 THERMAL OUTLET SUNI2 TLH43431 TKT. TIM* »
1003
80:
50:
40J
20:
o:
AS
1
2E5
V
15:00 20:00 21:00
file:S976757 #1-825 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIS 70S
330.9792 F:2 Exp:EPCUS
TKIABSLE LABS Tert:K23 TBESMAL OUTLET SUK#2 TLIt43431 UKT. TIM* -
ion
80:
so:
40:
20:
o:
18:40 15:13 15:41 20:00 20r2J 20:45 21: 05
^^ v- ^_ ^
r
in
' 15:00 20:00 ' ' '21:00
21:34
_1 . 3E6
-1.1E6
.8.0E5
_5.4E5
_2. 7E5
O.OEO
' 22s 00 M«e
21:34
r^
_8.2E5
_5.5E6
_4.5E5
_3.3E5
_1 . 6E6
O.OEO
22: 00 Wjie
A
IBS
-------
Jile:SS76757 fl-829 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIS 70S SOiae:103
339.8597 T-.3 BSUB(2S6,30,-3.0) PKD(7,S,3rO .05\,412.0,1.00\,T,T) Exp-.EfCUS
TRIANGLE LABS Text:M23 THERMAL OUTLET RUNf2 TLH43431 INJ. TIME - 21:34
lOOi,
A3.65E3
A4.32E3
AS.S9E3 I
80:
23:00 24:00 25:00 26:00
file:S976757 H-B29 Acq:16-OCT-1997 21:31:29 EH- Voltage SIX 70S No±ae:156
341.6567 T:2 BSVB(256,30, -3. 0) PKD(7,5,3,0.051,624.0,1.00*,f,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL OUTLET RUNt2 TLIf43431 XK7. TIME = 21:34
1003,
A9.76E3
SOJ
so:
A6.16E3
A4.90E3
A4.08E3
23100 24100 25-00 26:00
rile:S976757 H-829 Aoj:16-OCT-1997 21:31:29 EI+ Voltage SIS 70S Boiae:71
351.9000 T:2 BSUB(256,30,-3.0) PXD(7,5,3r0.05\,2S4.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL OUTLET RUtTf2 TLH43431 HIT. TIKE - 21:34
1001
sol
60l
40.
201
A4.48E6
A3.99E6
t
23:00 24:00 25:00 26:00
eilesS976757 tl-829 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIS 70S Soiae:92
353.8970 T:2 3SUB(256,30,-3.0) Pn3(7,S,3,O.OS\,368.0,1.00\rT,T) Exp:£PCUS
TRIANGLE LABS Teit:M23 THERMAL OUTLET SU1H2 TLH43431 XK7. TIME - 21:34
1001
sol
60:
40:
20:
ol
A3.00E6
A2.66E6
23:00 24:00 25:00
rile:S976757 tl-829 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIS 70S
330.9792 T:2 ExptEPCUS
TRIANGLE LABS Text:M23 THERMAL OUTLET SUN«2 TLIt43431 IKJ. TIME -
1001 23:04 23:27 23:45 24:05 . 24:48 25:05 25:2*.
p^~ i_^ T.IJ- ^Ji^l~
ao:
60:
40:
20:
o.
26:00
21:34
25:5526
•IS .262.33
23sOO 24:00 25:00 26:00
rile:S976757 tl-829 Acq:16-OCT-1997 21:31:29 EH- Voltage SIS 70S
409.7974 r:2 Exp-.EPCDS
OtlAHGLE LABS Tozt.:M23 THERMAL OUTLET RU1H2 TLH43431 OCT. TIME - 21:34
24:47 25:51
22i56 I \
24:36\
,23:44
23:15
lOOi
so:
60:
40:
o:
22:39
OJsJUA
O.OEO
27:00 Tin
3.9E3
.3.1E3
.2.3E3
.1.5E3
-7.7E2
.O.OEO
27:00 Tin.
1.3E6
.1. OE6
•.7.6E5
.S.1ES
.2.SE5
.O.OEO
27:00 Tia,
8.2E5
.6.5E5
.4.9E5
-3.3ES
_ 1. 6E5
.O.OEO
27:00 Time
8.5E6
.6.8E6
.5.1E6
.3.4E6
_1. 7E6
.O.OEO
27-00 Time
25:35
26:46
26:33
26:22
5.1E3
.4.1X3
.3.1E3
.2.0S3
.1.0E3
23-00
24tOO
25:00
26:00
~27*: OQ
O.OEO
169
-------
file
355.
TRIA
1001
BO:
SOJ
40:
20:
0'
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8546 Ti2 BSUS(256,30f-3.0) PXD(7,5, 3, 0.05%, 504. 0,1. 00\,T,T) Exp:EPCOS
tTSLE LASS Teit:M33 THERMAL OUTLET ROSf2 TLIf 43431 XK7. TIME * 21:34
Al. 4E4
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8516 T:2 BSUB(2S6,30,-3.0) PKD(7,S,3,O.OS\,244 .0,1.00\,rrT) ExptEPCUS
SSZE LASS Toxt:M33 THERMAL OUTLET RUN* 2 TLIf 43431 JK7. TIME - 21:34
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:S976757 11-839 Atyj:16-OCT-1997 21:31:29 EI+ Voltage SIS 70S Boi»e:66
8949 r:2 SSVB(256,30,-3.0) PXD(7r5,3,0.05\,264.0,1.00\,F,T) Exp:EPCUS
OGLE LASS Text:M23 THERMAL OUTLET RUN*2 TLIf 43431 HKT. TIME - 21:34
A2.55E6
IW5
34:00 35:00 36:00
sS976757 f 1-839 Ac?:16-OCT-1997 31:31:39 EI+ Voltage SIS 70S HO3.Be-.71
8919 T:3 SSUS(256,30,-3.0) PXD(7rS,3,0.05\,384 .0,1.00\,T,T) Exp:EPCUS
SGLE LASS Text:M23 THERMAL OUTLET SUIH2 TLH43431 UKT. TIME - 21:34
Al . 68E6
1 $3.S7ES
1 vv
34:00 35:00 36:00
:S976757 tl-829 Aoq:16-OCT-1997 31:31:39 BI+ Voltage SIS 70S
9793 r:3 ExpiEPCUS
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170
-------
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373.8308 Ti3 BSUS(256,30,-3.0) PXD(7,5,3,0.05\,472.0,1.00\,T,T) EzpiSfCCS
TSIASGLE LASS T*zt:M23 TSESMAL OUTLET SUBf2 TLI043431 JJW. TIME - 21:34
A6.47E3
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27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
fila:S976757 #1-475 Acg:16-OCT-1997 21:31:29 EI+ Voltage SIS 70S Hoiae:62
375.8178 T:3 BSDB(256r30r-3.0) PKD(7,5,3,0. 05\r249.0,l. 00\,r,T) Exp:EPCUS
TSIASSLE LABS Text:K23 TSESMAL OUTLET SUS92 TLH43431 INJ. TIME = 21:34
1004 A6.J.1E3
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:13 29:24 29:36 29:48 30:00 30:12
rile:S9767S7 #1-475 Acqil6-Od-1997 31:31:29 EI+ Voltage SIS 70S Noiae:87
393.8639 Fs3 BSUS(256,30,-3.0} rXD(7,S,3,0.05\r348.0,1.00\,F,T) Exp:EPCUS
TSIASGLE LABS Text:H23 TBESJOO. OUTLET SUN*2 TLH43431 JK7. TIME = 21:34
1001
80:
60:
40:
20:
A2.
A2.01E6
A1.62E6
6.8E5
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.4.1E5
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Ll.4ES
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
riIe:S9767S7 il-475 Acg:16-OCT-1997 21:31:29 Eli- Voltage SIS 70S Soise:161
385.8610'r:3 BSUS(256,30, -3.0) PXD(7,5,3r0.05\,644.0,1.00\,r,T) Exp:£PCaS
TRIANGLE LASS Text:M23 TEESMAL OUTLET SUNt2 TLH43431 XK7. TIME =• 21:34
100* A4 82E6
.O.OEO
Time
80:
sol
401
20:
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A4.20E6
A3.27E6
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27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
Tile:S9767S7 il-475 Aoy:16-OCT-1997 21:31:29 EH- Voltage SIS 70S
92.9760 r:3 Eip:EPCUS
ytXASGLE LASS Teit:M23 THERMAL OUTLET SU1T42 TLI443431 rtKT. TIME - 21:34
1001
40-
20:
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Time
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48'JO:00'30:12'
K3.e;S976757 tl-475 Aoq:16-OCT-1997 21:31:29 £1+ Voltage SIS 70S
45.7555 Ti3 Ezp:EPCUS
TSIASSLE LASS Text:M23 THERMAL OUTLET SUIH2 TLH43431 UKT. TIME - 21:34
29:24
28:25
29:11
39:051
29:34 29:46
30:11
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171
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J.essy/6757 #1-475 Acq:lo-OCT-1997 21:31:29 EI+ Voltage SIS 70S Noiae:55
389.8156 T:3 BSUB(2S6,30,-3.0) PXD(7,5,3,0.OS\,220.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LASS Teit:M23 THERMAL OUTLET RONt2 TLI043431 IKT. TIME = 21:34
1001
so:
27:48 20:00 20:12 20:24 28:36 28:48 29:00 29:12 29:24 29:36
Tilo:S9767S7 #1-475 Acg-.16-Od-J.997 21:31:29 XH- Voltage SIS 70S Noiee:103
391.8127 T:3 BSUB(2S6,30, -3.0) PXD(7,S,3,O.OS\,412.0,1.00\,r,T) Ezp:EPCUS
TRIANGLE LASS Text:M23 TSKSMAT. OUTLET XONI2 TLIf 43431 JK7. TIME - 21:34
1004 A1.54X4
OEO
29:48 30:00 Time
_4.5iTJ
27:48 20>00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
file:S9767S7 U-475 Acg:16-OCT-1997 21:31:29 ET+ Voltage SIR 70S J9bx*e:57
401.0550 T:3 BSUB(2S6,30,-3.0) PXD(7r5,3,O.OS\,22B.O,1.00\,T,T) Eip-.EPCDS
TRIANGLE LABS Tert:M23 THERMAL OUXLST XtOrf2 TLIf43431 HKT. TIME - 21:34
10(» A3.32E6 A3.23E6
80.
60.
40.
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30:00 line
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403.8529 r:3 BSUB(256,30,-3.0) PXD(7,5,3,0 .051,584.0,1.00\,r,T) EzptEPCOS
TRIANGLE LABS Tert:M23 TRTSHHT. OUTLET XOH42 TLH43431 IRJ. TIME * 21:34
.O.OEO
JO: 00 Tine
1003
80.
60.
40.
20.
A2.74E6
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27:48 28:00 28:12 20:24 28:36 20:40 29:00 29:12 29:24 29:36 29:48
file:5976757 #1-475 Acq:16-OCT-1997 21:31:29 EH- Voltage SIS 70S
392.9760 F:3 Elp:EPCUS
TRIANGLE LABS T*Xt:M23 TPTPMT. OUTLET XUf92 TLI943431 UKT. TIME - 21.-J4
laOS 28:03 28:12 ^28^6 28:36 38:54 29:06 29:16 29:30 . _25f.45.
80.
60.
40.
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0.
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29:00
29:12 29:24 29:36 29:48 30:00 Tiae
172
-------
'Tile:S976757 #1-397 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIX 70S Ooiae:170
407.7818 T-.4 BSOB(256,30, -3.0) PKD(7,5,3,0.05%,680.0,1.00\,r,T) ExpsEPCUS
TRIAHSLE LABS Text:M23 THERMAL OUTLET RU1H2 TLH43431 IKT. TIME » 21:34
100S
31:13 31:34 31:36 31:48 33:00 32:13 32:24 32:36
rile:S976757 11-397 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIS 70S Soiaa:47
409.7789 T-.4 BSUB(256,30,-3.0) PKD(7,5,3,0.05%,1S8.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS ZteZt:M23 THERMAL OUTLET BUXt2 TLI943431 INJ. TIME - 21:34
1001
32:48
O.OEO
33:00 Tim
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
rile:S9767S7 #1-357 Acq: 16-OCT-1997 21:31:29 £1+ Voltage SIR 70S «oiae:248
417.8353 r:4 BSOB(2S6,30,-3.0) fI3>(7,5,3,0.05\,992.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Text.-AGJ TSESMAL OUTLET ROSt2 TLI143431 IKJ. TIME - 21:34
1001 A1.17E6
32:48
80:
601
40:
20;
0;
A8.36E5
i 'i I i ii
31:12
i i i i i i' i i i i
31:36 31:48
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32:12
33:00 Time
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31:24 31:36 31:48 32:00 32:12 32:24 32:36
rile:S976757 #1-357 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIR 70S Soiae:193
419.8220 f:4 BSU3(256,30,-3.0) tXD<7,S,3,0.05\,772.Q,l.QO\,T,T) Elp-.ZPCUS
TSIANGLE LABS Te3Ct:M23 mTRMAT. OUTLET SUHt2 XLI043431 TXT. TIME - 21:34
A2. 79E6
A1.98E6
.O.OEO
32:48
80:
60l
40:
20:
0:
7JT 00 Time
-6.7E5
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32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
•Ue:S976757 #1-357 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIR 70S
430.9729 F:4 Szp:EPCUS
TRIAS5LE LABS Tezt:M23 TSESMAL OUTLET SUH42 TLIH3431 XK7. TIME - 21:34
32:48
100]
80:
60.
40:
so:
0:
32:25 32:34 32t42 32:49
33:00 Time
-3.2E6
'-2.5E6
'•.1.9E6
11.3E6
-6.4X5
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:34
rilesS976757 #1-357 Aog:16-OCT-1997 21:31:29 EH- Voltage SIX 70S
«79.7155 r:4 Exp-.EPCOS
TXXABSLE LABS TextiM33 TSESMAL OUTLET sujus TLH43431 uu. TIME - 21:34
1001
32:48
.o.oro
33:00 Zi*<
33:00 Time
173
-------
y/o/3/ ri—jy/ Actj:±o-OCT-i9S7 21:31:29 EI+ Voltage SIS 70S noiaitfo
423.7766 T:4 BSOB(256,30,-3.0) PXD(7,5,3,0.05\,184.0,1.00\,r,T) Exp-.EfCOS
TRIANGLE LASS Tert.-JOJ THERMAL OUTLET SOHI2 TLII43431 IJKT. HUB - 21:34
100\ A7.25E3
Al. 74S4
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
rilesS976757 tl-397 Aoq:16-OCT-1997 21:31:29 KT+ Voltage SIX 70S Boiae:74
425.7737 T:4 BSUB(256,30,-3.0) PKD(7,5,3,0.051,296.0,1.00*,r,T) Exp:EPCUS
TSIASGLE LABS Teft:M23 THERMAL OUTLET RUHt2 TLH43431 OCT. TIME - 21:34
100\ A1.82E4
31,24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24
rila:S9767S7 tl-397 Aeqtl6-OCX-1997 21t31:29 EH- Voltage SIS 70S Noiae:327
435.8169 T:4 BSVB(256,30,-3.0) PKD(7,5,3,0.05\,1308.0,1.00\,r,T) Ezp:SPCUS
TSIASSLE LABS Tert:M23 •nmmr. OUTLET VOStt TLH43431 XK7. TIME - 21:34
32:24 32:30 32:36
O.OEO
Time
6.7E3
32:30 32:36
O.OEO
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80.
60.
40:
20.
-4.5E5
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31:24 31:30 31:36 31:42 31:48 31:54 32:00 32-06 32:12 32:18 32:24
rile:S976757 11-397 Acq:16-OCT-1997 21:31:29 ZH- Voltage SIS 70S Soiae:380
437.8140 Ti4 3503(256,30,-3.0) PXD(7,5,3,0.05\,1520.0,1.00\,r,T) SxptEPCUS
TSIAKGLX LABS Text:M23 THERMAL OUTLET XUSt2 TLH43431 HKT. TIME - 21:34
1009k A2.J1Z6
32:30
.O.OEO
32:36 Time
80.
60.
40.
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4.4E5
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31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:66 32:12 32:18 32:24 32:30 32:36 Time
rile:3976757 11-397 Aeq:16-OCT-1997 21:31:29 EH- Voltage SIS 70S
430.9729 ft4 ExpiEPCUS
TSIASSLE LABS Tert:M23 THERMAL OUTLET SUHt2 TLH43431 HKT. TIME - 21:34
31:3531:39 31:46 3l.ss 32:03 32^10 ^_ . 32±2S 32^34 ..3.1E6
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174
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mietS97b75l 01-399 Acq:i6-OCT-199? 21-.3i-.29 EH- Voltage SIR 70S Nbiaeil52
441.7428 Ts4 BSUS(2S6r30, -3.0) PXB(7,5,3,0.05\,608.0,1.00%,reT) EzpiEPCUS
TKI)
1003
90.
80.
70.
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10
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A7.48E3
I A2 66E3 &6-91E3 31x3 A3.43E3 A5 69E3 \A6.S6E3
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00 32:00 33:00 34:00 35:00 Tiae
rilesS976757 #1-357 Acgr:16-OCT-1997 21:31:29 Eli- Voltage SIR 70S No±ae:209
443.7399 T:4 BSUB(256,30r -3.0) PXD{7, 5, 3,0. 051,836. 0,1.00\,r,T) Elp-.EPCOS
TMIASSLE LABS Text:M23 THERMAL OUTLET SOHt2 TLH43431 XK7. TIME - 21:34
1003
90.
801
701
601
501
401
30J
201
101
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430. 9729. Tt4 XzptXPCOS
TBIASGLE LABS Text:M23 THERMAL OUTLET RUSt2 TLH43431 OKT. TIME - 21:34
1001
90.
80.
701
601
SOI
401
301
201
101
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31:17-. J5 33llo 32:49 33:2833:45 . 34J^0j^4Ai° „ 35l 01 3S'22 35,49
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00 32:00 33:00 34:00 35:00 ' ' ' Time
rile* 55 7675 7 #1-357 Acgrtl6-OCT-1997 21:31:29 EI+ Voltage SIR 70S
513.6775 T:4 XrptXfCOS
TMIABGLE LABS Teit:K23 THERMAL OUTLET RUSK TLH43431 XK7. TIME - 21:34
1003
301
801
701
601
501
401
30\
201
101
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34 26
31:14 33 58 33t3S
31:31 32:32
31:55 ,
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^31:00 33'sOO 33\00 34.-00 35^00 • • • • ^^^
175
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H.e:S976757 #1-397 Acq:lo-OCT-1997 21;31 s29 Eli- Voltage SIR 70S Noiae:J8
457.7377 Ts4 BSOB(256,30, -3.0) PKD(7,S,3, 0. 05\, 152. 0,1.00\,T,T) Elp:EPCUS
TRIANGLE LABS T0it:M23 THERMAL OUTLET RUJH2 TLH43431 1X7. TIME - 21:34
iOO\ A1.27E4
80.
60.
40.
20.
A2.40E3
34:30 34:36 34:42 34:48 34:54 35:00
rile:S9767S7 #1-397 Acq:16-OCT-1997 21:31s2S EI+ Voltage SIX 70S Koimo:62
453.7348 T:4 BSUB(2S6,30,-3.0) PXD(7,5,3,0 .QS\,248.0,1.00\,T,T) Ezp:EPCDS
TRIANGLE LASS Tert.-K2J THERMAL OUTLET RUlTf2 TLH43431 XKT. TIKE ' 21:34
A1.33E4
34t30 34:36 34:42 34:48 34:54 35:00
Tile:S976757 #1-397 Acqtl6-OCT-1997 21:31:29 EH- Voltage SIS 70S Noise-.57
469.7779 Ts4 SSUS(256,30,-3.0) PXD(7,5,3,0.OS\,223.0,1.00\,T,T) Eip-.EPCDS
TSIASGLE LASS Toxt:M23 THERMAL OUTLET SOS#2 TLH43431 UKT. TIME - 21:34
A2.73E3
r2.1E3
.1. 7E3
'.1.3E3
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'.4.2E2
35:06
O.OEO
Time
35:06
34:30 34:36 34:42 34:48 34:54 35:00
ttle:S9767S7 #1-397 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIS 70S Boiae:57
471.7750 T:4 BSVB(256,30,-3.0) ?XD(7,5,3,0.05\,228.0,1.0Q\,T,T) ExptEPCOS
TSIABGLE LASS Text:M23 THERMAL OUTLET ROR#2 TLI#43431 OCT. TIME - 21:34
100% A3.13E6
35:06
34:30 34:36 34:42 34:48 34:54 35:00
File:S976757 #1-397 Aoj:16-OCT-1997 21t31s29 EH- Voltage SIS 70S
430.9729 T:4 SxptffCUS
TRIAHGLE LABS TmrttM23 TSEXMAL OUTLET RU1H2 TLH43431 UKT. TIME ' 21:34
35:06
1001
80.
60.
40.
20.
35101
34t30
34:36
34:42
34:48
34:54
35:00
35106
.O.OEO
Time
3.2ES
2.6E5
1.9E5
.1.3E5
6.4E4
O.OEO
Time
3. 7E5
3.0E5
2.2E5
.1.5E5
7.4E4
O.OEO
Time
3.3E6
2.6E6
2.0E6
.1.3E6
6.SE5
O.OEO
Time
176
-------
Ref, lass 232,3825 Peak top
Height ,62 volts Span 288 ppi
Systei file naae EPCOT
Data file naae R:S976756
Resolution 18668
Groupnutber 2
lonization lode El*
Switching VOLIRGE
lasses 292.9885, 416,9768
fl 293 J 331 S 368
K 332 I 378
I 334 U 376
I 348 V 418
H 342
0 352
P 354
Q 353
R 358 '
Channel I 336.9732 Peak top
Height ,68 volts Span 208 ppi
177
-------
File:S976757 #1-397 Acq:16-OCT-1997 21:31:29 El-f Voltage SIR 70S
423.7766 F:4 Exp:EPCUS
Sample Text:M23 THERMAL OUTLET RUN#2 TLI#43431 INJ. TIME =
100%
21:34 File Text:M23 THERMAL O»
31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S976757 #1-397 Acq:16-OCT-1997 21:31:29 El-f Voltage SIR 70S
425.7737 F:4 Exp:EPCUS
Sample Text:M23 THERMAL OUTLET RUN#2 TLI#43431 INJ. TIME =
100%. A1.34E4
90 j
80 J
70 J
60 J
50 J
40J
30J
20 J
10J
32:48
33:00
'33:12
OJ
31:24
31:36
31:48
32:00
32:12
32:24
32:36
21:34 File Text:M23 THERMAL O»
7. 8E3
ll.OE3
L6.2E3
L5.4E3
L4.7E3
L3.9E3
L3.1E3
L2.3E3
L1.6E3
L7.8E2
LO.OEO
32:48 33:00 ' 33:12' Time
-------
File:!3976757 #1-397 Acq:16-oCT-1997 21:31:29 EI-»- Voltage Sift 70S
457.7377 F:4 ExprEPCUS
Sample Text:M23 THERMAL OUTLET RUN#2 TLI#43431
100*
A7.46E3_
INJ. TIME = 21:34 File Text:M23
THERMAL O»
_3.4E3
33136 33148 34100 34112 34i24 34i36 34i48 35iOO 35il2
File:S976757 #1-397 Acq:16-OCT-1997 21:31:29 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:M23 THERMAL OUTLET RUN#2 TLI#43431 INJ. TIME = 21:34 File Text:M23
100%
90J
80 J
70 J
60 J
50 J
40 J
30J
20 J
10J
0 . OEO
35! 36 Time
THERMAL O»
.4 . 1E3
_3.7E3
_3 . 3E3
_2 . 9E3
_2 . 5E3
L2 . 1E3
1.6E3
33136 33i48 34':00
34! 12'
34 [24' §34:36
34:48
35:00
35:12
8.2E2
U . 1E2
35i
LO.OEO
3 6 Time
-------
TLI Project:
Client Sample:
43431 Method 23 PCDD/PCDF Analysis (a)
M23 THERMAL OUTLET RUN#3 Analysis File: S976758
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Asphalt Roofing Project
M23TRAIN Date Received:
185-5-8A-D Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor
Blank Hie:
Analyst
09/29/97
10/01/97
10/16/97
n/a
S976745
MS
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976754
n/a
n/a
n/a
Anafytes-^ ^/$&$*^v&^
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
23,7,8-TCDF
1,2,3,7,8-PeCDF
23,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1^,3,4,6,7,8-HpCDF
1^,3,4.7,8,9-HpCDF
1A3,4,6,7,8,9-OCDF
!^tabi:3^ *
Total TCDD
Total PeO)D
Total HxCDD
Total HpODD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
^JSMLMt^
ND
ND
. ND
ND
ND
ND
EMPC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
AmtliigF^
ND
ND
ND
ND
ND
ND
ND
ND
^^Shisfc^1**" **vs5
0.01
0.02
0.02
0.02
0.02
0.02
0.03
0.009
0.01
0.01
0.01
0.01
0.01
0.01
0.02
0.02
0.02
0.01
0.02
0.02
0.02
0.009
0.01
0.01
0.02
VJffeliO; , 8T Flags
—
__
__^__
—
x- ,, ---..<. . -,\ ^f±Ts ;, Floss
—
Page 1 of2
X237.PSR V2.00. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:08/10/20/97
-------
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: M23 THERMAL OUTLET RUN#S Analysis File: S976758
[internal Standards
3C,2-2,3,7,8-TCDF
13Ci2-2,3,7,8-TCDD
'3C,2-l,2,3,7,8-PeCDF
I3C12-l,2,3,7,8-PeaDD
'3Ci2-l,23,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
'3C,2-l,2,3,4,6,7,8-HpCDF
'3d2-l,2,3,4,6,7,8-HpCDD
>3Ci2-l,2,3,4,6,7,8,9-OCDD
Sorw^Stebto <%*V$
"a-WJ.S-TCDD
uC,2-2,3,4,7,8-PeCDF
13Ci2-l,2,3,4,7,8-HxCDF
13C,2-l,2,3,4,7,8-HxCDD
I3C,2-l,2,3,4)7,8,9-HpCDF
AJten-iatfr Stamlai^s |typ» A) '-
13C12-l,2,3,7,8,9-HxCDF
13CI2-2,3,4,6,7,8-HxCDF
Recovery ^aoda«is^|»f'
13C12-1,23,4-TCDD
13C,rl,2,3,7,8,9-HxCDD
v Amt
-------
Data Review By:
Calculated Noise Area:
0.73
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/20/97
Listing of S976758B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.l.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCBD
320-322
320-322
37C1-TCDD
328
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
0
NL
WL
WH
WH
3
NL
SN
SN
SN
0
0:00
17:25
19:30
20:28
Peaks
0:00
19:14
19:57
20:25
21:01
22:27
22:41
Peaks
0:00
19:53
20:00
21:51
Peaks
0.65-0.89
0.84
RO 1.91
RO 6.75
RO 1.15
0.65-0.89
RO 0.55
0.67
RO 0.60
0.75
RO 0.35
0.68
0.67
0.65-0.89
RO 1 . 01
RO 0 . 37
RO 0.46
0.65
0.826-1.103
1
0
0
1
0
.05
.62
.14
.31
.00
0
0
0
1
.000
.853
.955
.002 2378-TCDF AN
0.951-1.049
1
12
4
688
2
1
4
.38
.94
.55 1.98
.83 296.06
.57 1.12
.81
.78
0
0
3.28 0
392.77 1
3.23 1
1
1
.000
.942
.977
.000 13C12-2378-TCDF ISO
.029
.100
.111
695.95
1
0
0
0
0
.54
.90
.71
.33
.00
0.858-1.060
0
0
0
1
.000
.937
.943
.030
0.906-1.094
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
ML
WL
WL
SN
SN
SN
SN
SN
SN
0:00
18:18
18:28
18:47
18:53
19:03
19:16
19:38
19:57
20:04
21:14
21:29
21:36
22:02
22:05
22:11
22: 15
0
0
1
1
0
1
.75
.63
.23
.22
.22 .
.58
0.74
3
.95 3.95
0.83
0
416
3
1
0
0
0
0
.35
.76 416.76
.12 3.12
.96 1.96
.63
.95 0.95
.36
.30
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
.000
.863
.870
.885
.890
.898
.908
.925
.940
.946
.001 37C1-TCDD S0R1
.013
.018
.038
.041
.046
.049
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
PrirTtedi19j
-------
page No.
iO/20/97
Listing of S976758B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Confound/
M z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
328
13C12-TCDD
332-334
N
332-334
PeCDF
340-342
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
5
NL
WL
SN
SN
5
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
5
NL
SN
SN
SN
SN
SN
SN
22:28
Peaks
0
0:00 RO
19:08 RO
19:56
20:16 RO
20:59
21:13
21:36
21:47 RO
21:51 RO
Peaks
1.
0:00 RO
22:38 RO
22:57 RO
23:01 RO
23:11 RO
23:18 RO
23:48 RO
24:08 RO
24:51 RO
25:18 RO
25:27 RO
25:41 RO
26:12 RO
Peaks
1.
0:00 RO
24:21 RO
24:43
25:29
25:56
26:31 RO
Peaks
1.
0:00 RO
24:36 RO
24:54 RO
25:20 RO
26:00 RO
26:11 RO
26:22
.65-0.89
1.67
3.25
0.80
3.46
0.83
0.8O
0.80
0.14
0.48
&Vt*wa
.32-1.78
0.83
1.06
0.48
0.23
0.13
0.29
0.98
1.23
1.17
0.18
0.30
1.03
0.65
32-1.78
0.59
1.08
1.45
1.43
1.S8
1.07
32-1.78
1.07
4.17
2.45
1.04
2.69
0.84
1.55
0.37
426.74
1.29
1.58
4.24 1.89
0.85
899.76 408.25
508.34 226.53
14.23 6.32
0.55
2.30 1.00
1.428.87
0.39
0.56
0.36
0.16
0.12
0.07
1.05
0.26
0.23
0.15
0.35
1.02
0.18
0.00
0.21
4.51 2.74
506.98 300.12
473.15 278.21
4.07 2.49
1.76 1.07
990.47
0.25
0.15
0.28
0.86
0.41
0.43
0.28
1.059
0.906-1.094
0.000
0.902
2.35 0.940
0.955
491.51 0.989 13C12-1234-TCDD
281.81 1.000 13C12-2378-TCDD
7.91 1.018
1.027
2.10 1.030
0.908-1.080
0.000
0.916
0.929
0.931
0.938
0.943
0.963
0.976
1.005
1.024
1.030
1.039
1.060
0.838-1.162
0.000
2.54 0.985
206.86 1.000 13C12-PeCOF 123
194.94 1.031 13C12-PBCDF 234
1.58 1.049
1.00 1.073
0.921-1.027
0.000
0.952
0.963
0.980
1.006
1.013
1.020
RSI
IS1
IS2
SOR2
Hangle Laboratories, Inc.® Analytical Services Division
P1 Caprtola Drive • Durham, North Carolina 27713
home; (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:08 10/20/97
183
-------
Page No.
10/20/97
Listing of S976758B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why .-RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
356-358
13C12-P6CDD
368-370
368-370
HXCDF
374-376
374-376
13C12-HXCDF
384-386
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SK
0
NL
SN
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
HH
WH
0
NL
SN
SN
SN
SN
SN
SN
SN
SN
26:29
Peaks
0:00
24:43
24:52
25:31
25:51
26:00
26:25
26:33
26:43
Peaks
0:00
27:33
27:39
28:24
28:30
28:37
28:43
28:46
28:56
29:01
29:12
29:27
29:31
29:48
30:11
30:23
Peaks
0:00
27:22
27:31
27:55
28:03
28:07
28:24
28:30
28:39
28:48
28:53
29:01
29:26
29:33
29:39
RO
1.
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
1
.10
0
0
.38
.00
32-1.78
1
0
1
1
1
1
0
0
0
.00
.96
.12
.30
.45
.57
.84
.63
.46
05-1.43
3
6
1
0
1
3
0
0
2
1
0
0
0
1
0
1
.40 '
.50
.18
.85
.78
.25
.18
.29
.50
.45
.80
.50
.38
.79
.29
.33
0
1
1
0
289
37
0
0
0
.23
.09
.27
.21
.73 171.46
.91 23.14
.95
.51
.31
1
.025
0.845-1.155
0
0
0
0
118.27 1
14.77 1
1
1
1
.000
.956
.962
.987
.000 13C12-PeCDD 123
.006
.022
.027
.034
I S3
327.64
0
0
.22
.22
0.24
0
0
0
0
0
0
1
0
0
0
0
0
0
0
.72
.92
.09
.07
.13
.09
.59
.14
.22
.14
.43
.13
.42
.00
43-0.59
1
0
0
0
0
0
0
0
0
1
0
0
2
0
0
.23
.51
.49
.18
.34
.44
.48
.50
.73
.09
.39
.47
.13
.46
.83
0
2
7
0
0
0
360
497
6
1
0
416
0
0
0
.33
.30
.22 2.36
.21
.44
.36
.69 117.63
.94 164.89
.34 3.07
.60 1.16
.98
.38 133.45
.59
.60
.95
0.957-1.054
0
0
.000
.967
0.970
0
1
1
1
1
1
1
1
1
1
1
1
1
.996 123478-HxCDF
.000 123678-HxCDF
. OO4
.008
.009
.015
.018 234678-HxCDF
.025
.033
.036
.046 123789-HxCDF
.059
.066
AN
AN
AN
AN
0.860-1.140
0
0
4.86 0
0
0
0
243.06 0
333.05 1
4.20 1
1.06 1
1
282.93 1
1
1
1
.000
.960
.965
.980
.984
.987
.996 13C12-HXCDF 478
.000 13C12-HXCDF 678
.005
.011
.013
.018 13C12-HXCDF 234
.033
.037
.040
SUR3
IS4
ALT2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:
IO/97
-------
page No. 4
10/20/97
Listing of S97675SB.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
,j_Z QC.Log Omit Why . .RT. OK Ratio Total.Area... Area. Peak. 1. . Area.Peak.2.. Rel.RT Confound. Name.. ID.. Flags.
384-386
HXCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
»C12-HpCDF
418-420
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
7
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
HL
SN
SN
SN
SN
SN
5
NL
SN
SN
SN
SN
SN
WH
0
NL
SN
29:45
30:01
30:17
Peaks
0:00
27:50
28:17
28:24
28:41
29:04
29:16
29:19
29:25
29:32
29:36
Peaks
0:00
27:49
28:37
28:44
28:49
28:53
29:08
29:13
29:31
29:45
29:51
30:01
Peaks
0:00
31:27
31:36
31:41
32:05
32:29
32:54
Peaks
0:00
31:14
31:38
RO
RO
1
RO
RO
RO
RO
RO
RO
RO
RO
1,
RO
RO
RO
RO
RO
RO
RO
0
0
1
.50
.41
.01
* W»«»«.
315.77 105.29
1
1
1,605
.05-1.43
0
2
1
1
1
2
1
0
1
0
0
.41
.00
.69
.45
.06
.62
.23
.85
.15
.41
.75
0
0
0
0
0
0
0
0
0
0
0
0
.87
.09
.94
.23
.11
.36
.74
.33
.47
.49
.20
.28
.40
.22
.00
.05-1.43
0
0
0.
0,
1,
0.
1.
1.
1.
0.
.57
.57
.98
.55
.00
.94
.19
.29
.19
.76
1.06
RO
0.
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
2.02
88-1.20
2.
1.
1.
0.
2.
1.
4.
06
79
33
47
69
62
71
0.29
0.22
1.86 1.03
0.33
0.29
0.27
280.32 152.19
396.69 223.12
539.03 292.63
6.20 3.43
1.48
1.84
210.48 1.044 13C12-HXCDF 789 ALT:
1
1
.053
.063
0.951-1.016
0
0
0
0
.000
.953
.968
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0.982
0
1
.995
.002
1.003
1.007
1.011 123789-HXCDD
AN
1.013
0.966-1.034
0.000
0.952
1.05 0.979
0.983
0.986
0.989
128.13 0.997 13C12-HXCDD 478
173.57 1.000 13C12-HXCDD 678
246.40 1.010 13C12-KXCDD 789
SOR4
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4.50 1.018
1.
1.
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57
92
33
33
55
29
00
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1.
0.
0.
38
42
59
0.
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42
63 80.67
70
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0.
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1.
1.
1.
1.
1.
000
007
012
014
027
040 1234789-HpCDF
053
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0.
191.96 1.
1.
000
000 13C12-HpCDF 678
013
IS6
Triangle Laboratories, Inc.® Analytical Services Division
Jtt Capitola Drive • Durham, North Carolina 27713
phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:08 10/20/97
-------
Page No.
10/20/97
Listing of S976758B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z cc.Log Omit Why ..RT. OX Ratio Total .Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
CCDF
442-444
442-444
OCDD
458-460
MKTN
458-460
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
2
NL
SN
SN
HH
WH
0
NL
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
1
31:42
32:01
32:12
32:28
32:54
Peaks
0:00
31:30
32:00
32:28
32:35
Peaks
0:00
31:30
31:38
32:06
32:38
Peaks
0:00
31:17
32:01
32:04
32:16
32:19
32:38
32:53
33:14
33:57
34:24
34:34
34:44
35:01
35:08
35:45
Peaks
0:00
34:38
Peak
RO
RO
RO
0.82
0.78
0.84
0.40
0.51
0.
0
0
189
1
.
.
.
.
88
94
73
25 54.53
33
1.015
1.025
1.031
134.72 1.039 13C12-HpCDF 789
1.053
SDR5
461.88
• * ••— •»«« / ifu^nn ^*» 1 1 m T«-I
0.
RO
RO
RO
RO
RO
0.
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
88-1.20
0
1
0
.77
.68
.18
0.54
1
.53
nt**-isc / n^n^uu JTUAAWW* —
0
0
.
.
20
82
0.14
0
0
0
.
.
-
37
39
00
88-1.20
1
1
1
1
1
.11
.87
.75
.02
.11
-*- --
0.99
1
0
292
0
294
11 III!
.
.
.
.
VI
76-1.02
0
1
0
2
0
0
0
0
0
2
1
1
0
0
9
2
.76
.27
.59
.68
.88
.16
.68
.05
.55
.10
.00
.59
.72
.35
.00
.67
0
0
0
.
.
.
94 1.78
33
73 147.85
80
67
51
96
40
0.36
0
0
0
0
0
0
0
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1
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0
0
.
.
.
,
.
.
.
.
.
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45
13
40
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51
40
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32 •
51
23
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0.978-1.007
0.000
0.981
0.997
1.011
1.015
0.969-1.031
0.000
0.95 0.981
0.985
144.88 1.000 13C12-HpCDD 678
1.017
0.884-1.116
0.000
0.904
0.925
0.926
0.932
0.934
0.943
0.950
0.960
0.981
0.994
0.999
1.003 CCDF
1.012
1.015
1.033
IS7
AN
.00
76-1.02
1
0
.00
.66
0
1
.18
.74 0.82
0.884-1.116
0.000
1.24 1.000 OCDD
AN
1.74
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:08 10/20/97
186
-------
page No- 6 Listing of S976758B.dbf
10/20/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
,^2 CC.Log Omit Why ..RT. OK Ratio Total.Area... Area. Peak. 1.. Area.Peak.2. . Rel.RT Compound. Name.. ID.. Flags.
13C12-OCDD 0.76-1.02 0.998-1.007
470-472 DC NL 0:00 0.83 0.22 0.000
34:37 0.88 392.65 183.47 209.18 1.000 13C12-OCDD IS8
470-472 1 Peak 392.65
column Description -Why Code Description QC Log Desc.
M_Z -Nominal Ion Hass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (muss) HH-Above Retention Time Window K-Peak Kept
Kat.l -Ratio of M/M+2 Ions SK-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
Tile:S976758 #1-025 Acq:16-OCT-1997 22:10:38 EI+ Voltage SIR 70S Noise-.242
303.9016 T:2 SSUS(256,30,-3.0) PKD(9,5,5,O.OS\,968.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LASS Text:M23 THERMAL OUTLET SUIT13 TLIf43431 IKJ. TIKE - 22:13
1001
17:00 10:00 19:00 20:00 21:00
File:S976758 tl-829 Acq:16-OCT-1997 22:10:38 EH- Voltage SIR 70S Soiae:287
305.8987 T:2 BSUS(2S6,30, -3.0) PXD(9,5,5,0.05\,1148.0,1.00*,T,T) Exp:EPCUS
TRIANGLE LASS Text:M23 THERMAL OUTLET RURI3 TLIt1343l IHJ. TIME * 22:13
1001
17:00 10:00 15:00 20:00 21:00
rile:S9767S8 tl-829 Acg:16-OCT-1997 22:10:38 EI+ Voltage SIR 70S Soi.ue-.299
315.9419 F:2 3SUB(2S6,30,-3.0) PXD(9,S,5r0.05\,1196.0r1.00\,T,T) Ezp:EPCUS
TRIANGLE LASS Text:M23 THERMAL OUTLET RONt3 TLIt43431 XK7. TIME - 22:13
22:00
22:00
1001
00:
ffOJ
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17:00 18:00 15:00 20:00 21:00
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317.9389 T:2 BSUB(256,30,-3.0) PXD(9,5,S,0.OS\,2180.0,1.00\,T,T) ExptEPCUS
TRIANGLE LASS Text-.H23 THERMAL OUTLET RUt»3 TLH43431 1X7. TIME - 22:13
1004 &3.93E6
SOJ
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40:
20:
22:00
17:00 18:00 19:00 20:00 21:00
rile:S976758 tl-829 Acqsl6-OCT-1997 22:10:38 EH- Voltage SIR 70S
330.9792 F:2 SxptEPCUS
TRIANGLE LASS Tezt:M23 THERMAL OUTLET RtOTt3 TLH43431 IXJ. TIME - 22:13
22: 00
1003,
80:
60:
40:
20:
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18:29 18:54
19:31
20:07
20:43
21:32
17:00 10:00 15:00 20:00 21:00
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375.8364 T:2 ExptEPCUS
TRIANGLE LASS Tert:M23 THERMAL OUTLET RUHf3 TLH43431 HET. TIME - 22:13
1001
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-------
Tile:S976758 #1-825 Adj:16-OCT-1997 22:10*38 EH- Voltage SIS 70S N6iae:440
319.8965 T:2 BSUB(2S6,30, -3.0) ?XD(7,S,3,0.05\,1760 .0,1.00\,T,T) ExpsEPCUS
TSIASSLE LASS Text:M23 TSESMAL OUTLET SU1H3 TLII43431
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TRIANGLE LABS Text:M23 TSESMAL OUTLET SUN43 TLIf 43431
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80.
60.
40.
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1
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Tile:S97675B fl-829 Acq: 16-OCT-1997 22:10:38 JET* Voltage SIS 70S Roiae:6QB
331.9368 F:2 BSUS(256,30, -3.0) PXO(7,5,3,0.05\,2432.0,1.00\
TSIASSLE LASS Text:M23 TSESMAL OUTLET SWTf3 TLXf43431
1001
80:
60:
40:
20:
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15:00
A4
1
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333.9338 T:2 BSOB(256,30,-3.0) PXD(7,5,3,0.05\,1464.0,1.00*,F,T) Exp:EPCUS
TSIASSLE LASS Teict:M23 TSESMAL OUTLET SUJfff3 TLH43431
1001
80:
60:
40:
20:
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A4..
1
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file:S976758 fl-829 Acq:16-OCT-1997 22:10:38 EH- Voltage SIS 70S KoJ.fe:376
327.8847 fs2 BSVS(256,
30, -3.0) PXD{7,S,3,0.05\,1504.0,1.00%,r,r) Exp:EPCUS
TSIASSLE LABS Text:M23 TSESMAL OUTLET SOITf3 TLIf 434 31
1001
80:
60:
40:
20:
0:
' 15:00
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OKT. TIME - 22:13
A4.17E6
20:00 2lioO 22:00
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File:S976758 fl-829 Aoj:16-OCT-1997 22:10:38 ET+ Voltage SIS 70S
330.9792 T;2 Eip-.EPCas
TRIANGLE LASS Tezt:M23 TSESMAL OUTLET SUJH3 TLH43431
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189
-------
FileSS9767SB #1-825 Acq:16-OCT-1997 22:10:38 EI+ Voltage SIR 70S *>i«e:120
339.8597 F:2 SSUS(256,30, -3.0) PXD(7,5,3, 0.05\,480.0,1.00\rT,T) XrptEPCOS
TRIANGLE LASS T«Xt:H23 THERMAL OUTLET RU1H3 TLH43431 XWJ. TIME -
100]
80J
23:00 24:00 25:00 26:00
r±le:S976758 #1-825 Acq:16-OCT-1997 22:10:38 EI+ Voltage SIS 70S Boise: 144
341.8567 T:2 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,576.0,1.00\,r,T) XzpiEPCUS
TRIANGLE LASS Tert:M23 THERMAL OUTLET RUNI3 TLH43431 HKT. TIME - 22:13
23:00 24:00 25:00 26:00
rile:S976758 tl-829 Acq:16-OCT-1997 22:10:38 EI+ Voltage SIS 70S Boise:67
351.9000 T:2 BSDB(2S6,30,-3.0) PKD(7,5,3,0.05\,268.0,1.00\,r,T) Ezp-.EPCUS
TRIANGLE LASS Text:M23 THERMAL -OUTLET RUN*3 TLH43431 XK7. TIME ' 22:13
10°* A3.QOE6 12.78E6
40:
20:
1001 A5.61E3
A5.2SE3
A5.24E3
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rile:S976758 11-829 Acq:16-OCT-1997 22:10:38 EI+ Voltage SIS 70S Boiae-.llO
353.8970 T:2 BSU3(256r30, -3.0) PKD(7,5,3,0 .OS\,440.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LASS Text:M23 THERMAL OUTLET SUJT*3 TLH43431 UKT. HUE - 22:13
IOCS A2.07E6 A1.95E6
80J
40:
20:
24>00 25t00
22:10:38 EI.+ Voltage SIS 70S
23:00
r±le:S9767S8 tl-829
330.9792 T:2 Ezp-.EPCUS
TRIANGLE LASS Text:M23 THERMAL OUTLET RUNf3 TLH43431 TKT. TIME "
22:57 23:22. 23:44 24:04 . 24:25 25:00
26:00
1003
80J
60:
40:
20:
o.
25:22 25:43
23100 24:00 25:00 26s 00
Tile:S976758 tl-829 Aeqsl6-OCT-1997 22:10:38 EI+ Voltage SIS 70S
409.7974 T:2 ExptSPCOS
TRIANGLE LASS Tert:M23 THERMAL OUTLET RUNt3 TLH43431 TJKT. TIME - 22:13
1001
23100
24:00
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190
-------
tl-BSS Acq:16-6&S-l997 23,10-36 tl+ voltage si* 70S Hoiae:74
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TRIANGLE LABS T&xt:M23 THERMAL OUTLET BDXf3 TLI443431 UKT. TIME - 22:13
1001
24100 25:00 26:00
riletS9767S8 tl-829 Acq:16-OCT-1997 22:10:38 El* VoltMga SIS 70S Koisa:70
357.8516 T:2 BSU3(256,30, -3.0) tKD(7,S,3,0.05\,280.0,1.00\,r,T) ExpsEPCOS
TRIANGLE LABS Tsit:K23 TEERMKL OUTLET SVJTt3 TLH43431 XKT. TIME - 22:13
1003k
80.
O.OEO
Time
24,00 2SsOO 26:00
rileiS976758 11-823 Acq:16-OCT-1997 22:10:38 EI+ Voltage SIX 70S Ho±ae:68
367.8949 T:2 BSUB(256,30,-3.0) PXD(7,5,3,O.OS\,272.0,1.00\,rrT) EzpiEPCOS
XSIAKSLE LABS TexttH23 THERMAL OUTLET SUfH3 TLH43431 UKT. TIME *• 22:13
1004 A1.71E6
so;
60.
40.
20.
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Time
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369.8919 T:2 BSO3(256,30f-3.0) PKD(7,5,3,0.05\,288.0,1.00\rfrT) Exp:EPCUS
SSIASSLE LABS T&zt:M23 THERMAL OUTLET BUlTtS TLH43431 IKJ. TIME - 22:13
A1.18E6
80.
60.
40:
20.
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30.9792 Ti2 XxptEPCOS
TXIASSLE LABS T*xttM23 TSESMAL OUTLET SO1H3 XLH43431 UKT. TIKE -
.O.OEO
Time
22:13
.001
80.
60.
40.
20.
0.
24:04
24:25
25:00
25:22
25:43
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24',00
25:00
26:00
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1.5E6
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Time
191
-------
File:S976758 #1-475 Acq:16-OCT-1997 22:10:38 EX+ Voltage SIS 70S Noiae:171
373.8208 F:3 BSU3(256,30,-3.0) PKDf7,5,3,0.85%,684.0,1.00%,T,T) Exp:EPCUS
TSIAKSLE LASS Text:M23 THERMAL OUTLET SUN*3 TLIf 43431 IXJ. TIME = 22:13
100$ A7.34E3
27:24 27:36 27:48 28:00 28tl2 28:24 28:36 28:46 29:00 29:12 29:24 29:36 29:48 30:00 30:12
rile:S976758 #1-475 Ac?:16-OCX-1997 22:10:38 EI+ Voltage SIS 70S So±me:50
375.8178 T:3 SSU3(2S6,30,-3.0) PXD(7,5,3,O.OS\,200.0,1.00\,T,T) ExptEPCUS
TRIANGLE LASS Text:M23 TSESMAL OUTLET SUKt3 TLH43431 OU. TIME - 22:13
100* A4.71E3 A7.08E3 ,.2.
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
rHe:S976758 #1-475 Acq:16-OCT-1997 22:10:38 EI+ Voltage SI* 70S Soi»e:136
383.8639 r:3 BSUS(256,30,-3.0) PXD(7,5f3,0.05\;S44.Q,1.00\,rrT) Exp:EPCUS
TRIANGLE LASS Text:M23 THERMAL OUTLET ROXt3 TLH43431 OU. THIS - 22:13
OEO
time
1003
so:
eo:
40:
20:
Al.65E6
A1.33E6
Al.05E6
4.
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
File:S9767S8 tl-475 Acq:16-OCT-1997 22:10:38 EI+ Voltage SIR 70S Xoiae:109
385.8610 f:3 BSOB(256,30,-3.0) PXD(7,S,3,0.05\,436.0,1.00\,rrT) Ezp-.EPCOS
TRIANGLE LASS Tezt:M23 THERMAL OUTLET RU1T«3 TLH43431 X2KT. TIME - 22:13
1001
80:
60:
40:
20:
A3.33E6
A2.83E6
A2.10E6
_9.
.7.
'-S.
.3.
_1.
0.
27:24 27:36 27:48 28:00 28il2 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
f±le:S976758 91-475 Acq:L6-OCT-1997 22:10:38 EI+ Voltage SIS 70S
392.9760 Ti3 Exp-.EPCOS
TRIANGLE LASS Teit:M23 THERMAL OUTLET RUIH3 TLH43431 TKT. TIME - 22:13
1001
[27:20 27:46J*^U£Li*J:JvJ£3&2^
-3
'-.3
'-2
Ll
.7
0
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
File:S976758 #1-475 Acq:16-OCT-1997 22:10:38 EH- Voltage SIS 70S
445.7555 T:3 ExptEPCUS
TRIANGLE LASS Toit:M23 THERMAL OUTLET RO1H3 TLH43431 ZK7. TDOT - 22:13
1001
so:
20:01
50:
40:
20:
5E5
.6E5
.7E5
.8E5
.1E4
.OEO
Tiae
.3E5
.4ES
.6E5
.7E5
.9E5
.OEO
Time
.8E6
,OE6
,3E6
.5E6
.6E5
.OEO
T±me
. :
JiAvM^jJuJUy^
27:24 27:36 27:48 28:00 20:12 20:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
192
-------
piles SUMS SB tl-475 Acs03 29:12 39-*1 . „ 29:36 29:46 39iS6 3.8E6
00^
so:
«UL
40.
20.
0.
.3.0E6
.2.3E6
.1.5E6
.7.6E5
27:48 ' '28:00 ' '28:12 ' '28:24 ' '28:36 ' '28\48 29:00 29:12 29:24 ' '29\36 '25:48' ' '30:00
O.OEO
193
-------
File:S9767S8 #1-397 Acq:16-OCT-1997 22:10:38 EI+ Voltage SIB 70S Noise-.173
407.7818 F:4 BSUB(2S6,30, -3.0) PXD(7,5,3, 0. 05%, 692. 0,1. 00\,r,T) Exp-.EPCOS
TSIAXSLE LASS T&Ct:M23 THERMAL OUTLET RON*3 TLIf 43431 JK7. TIME - 22:13
1004
80:
601
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File:S976758 *1-397 Acqtl6-OCT-1997 22:10:38 EH- Voltage SIX 70S So±ae:87
409.7789 T:4 BSUB(256,30,-3.0) PXZ>(7,5,3,0.05\,348.0,1.00\,F,T) EzpsEPCUS
TRIANGLE LABS Tezt:M23 THERMAL OUTLET SUS«3 TLH43431 HKT. TIKE - 22:13
1003! A6.91X3
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
F±le:S976758 tl-397 Aaj:16-OCT-1997 22:10:38 EI+ Voltage SIS 70S S0ise:200
417.8253 T:4 BSUB(256,30,-3.0) PXD(7r5,3,O.OS\,800.0,1.00lrF,T) Exp:EPCUS
TRIANGLE LABS Teit:M23 THERMAL OUTLET SUlTt3 TLIt43431 IM7. TIME - 22:13
A8.07E5
A5.45E5
20:
ol
A1.23E4
A4.32E3
S5E3
.74E3
-VX/V
,.9.5E3
-.7.6E3
•.5.7E3
'.3.8E3
''.1.9E3
32:48
10.OEO
33:00 Mae
32:48
.O.OEO
33:00 Time
31:12 31:24 31:36 31:48 32:00 32:12 32:24
rile:S976758 91-397 Actj:16-OCT-1997 22:10:38 EH- Voltage SIS 70S Boiae:143
419.8220 T:4 BSUB(256,30,-3.0) PXD(7,S,3,0.05\,572.0,1.00\,T,T) Elp:EPCOS
TRIANGLE LABS Teft:M23 THERMAL OUTLET RUN*3 TLIt43431 HKT. TIME - 22:13
10 OS, A1.92E6
32:36
32:48
80:
40
201
ol
A1.35E6
.O.OEO
33:00 T±me
4.3E5
13.4E5
.2.6E5
.1. 7E5
.8.6E4
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File:S976758 tl-397 Acq:16-OCT-1997 22:10:38 El-f Voltage SIS 70S
430.9729 F:4 ElptEPCUS
TRIANGLE LABS Text:M23 THERMAL OUTLET SUJTt3 TLH43431 HTj: TIME -
lOOi, 31:28 jl-42 31:55 32:1732:24
80:
SO:
20:
32:36
22:13
32:48
.O.OEO
33:00 Time
32:57,-2.8E6
'.2.2E6
.1. 7E6
•.1.1E6
.5.6E5
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File:S97675B tl-397 Acq:16-OCT-1997 22:10:38 EH- Voltage SIS 70S
479.7165 f:4 ExpiCPCUS
TSIAHGLE LABS TeXt:H23 THERMAL OUTLET RUS43 TLH43431 HKT. TIME - 22:13
ion
32:48
.O.OEO
33 : 00 Time
so:
so:
4ol
20!
31124
32s 44
31:16
31108
31:12
31124
31:36
31:48
32:00
32:12
32:24
'32:36'
32:48'
-6.2E3
.4.9E3
.3.7E3
.2.5E3
.1.2E3
.0. OEO
33:00 Time
194
-------
7Zle:sS''i>J5a #1-3S7 Acg:16-o&f-lS97 23:10:38 SX+ Voltage Sis 70S «bijc.-51
423.7766 Fs4 BSUB(256r30,-3.0) PXD(7,5,3,0. 051,204.0,1. 00\,f,T) Erp:EPCUS
TSZANGZE LABS Text:H23 TSEUfAL OUTLET SUS»3 TLH43431 ISJ. TIKE * 22:13
IOCS A6.69E3
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:19 32:24
file:S976758 tl-397 Acg:16-OCT-1997 22:10:38 EI+ Voltage SIS 70S Noise:66
425.7737 T:4 BSUB(256,30r-3.0) PKD( 7,5, 3, 0.05%, .254.0,1. 00*,T,T) Ezp:EPCOS
XSIAHSLE LABS Teit:M23 TSKOtAL OUTLET SOX*3 TLIt43431 UET. TIME > 22:13
100\ A5.94E3
O.OEO
32:30 32:36 Time
00:
50:
40:
20:
A3.27E3 A3.54E3
A2.44E3
2.4E3
.1.9E3
.1.4E3
'.9.4E2
14.7E2
O.OEO
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24
rile:S976758 tl-397 Acqtl6-OCX-1997 22:10:38 EI+ Voltage SIS 70S Boime:260
435.8169 Tt4 BSUB(256,30,-3.0) PXD(7 ,5,3,0 .05\, 1040 .0 ,1 .00\,T,T) S*p:EPCUS
XSIASSLX LABS Text.-«2J TBXOfAL OUTLET SWT43 TLH43431 1ST. TIME - 22:13
32:30 32:36
Tlae
ion
80.
60.
40.
20.
A1.48E6
-2.9ES
'.2.3E5
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24
rile:S976758 tl-397 Acc[:16-OCT-1997 22:10:38 EI+ Voltage SIS 70S Soime:233
437.8140 T:4 BSUS(256,30,-3.0) PXD(7,5,3,0.05\,932.0,1.00\,r,T) Elp-.EPCDS
XBIAHGLE LABS Text:H23 TBEBtAL OUTLET SU1H3 TLH43431 ZK7. TUfE - 22:13
A1.45E6
32:30 32:36
Time
80.
60.
40.
20.
31:34 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24
rUmtS97S758 tl-397 Acq:16-OCT-1997 22:10:38 EH- Voltage SIS 70S
'30.3729 fi4 XxptEPCOS
XIABGLE LABS Taxt.:H23 ftnefmtT. OUTLET SUKt3 TLH43431 XK7. TIME - 22:13
32:24
.O.OEO
32:30 32:36 Time
-2.7ES
.2.2S5
,1. 6E5
_1.JLE5
-S.4E4
so:
50.
10.
ao:
o:
31\24
'31:36 ' '3ii42 ' '3J.t48
'32:06 ' 32:06 ' '32:12 ' 32:18 ' '32:34 '
'32i30
-2.7E6
.2.2X6
.1.6X6
.1.1X6
15.4X5
'.0.0X0
Time
195
-------
Kle:S9767S8 #1-357 Acq:16-OCT-1997 22:10:38 Eli- Voltage SIX 70S Noj.ae:112
441.7428 F:4 BSUB(256,30,-3.0) PKD(7,5,3,O.OS\,448.0,1.
TXIAKGLE LASS Text:M23 TBESHAL OUTLET XUJH3 TLH43431
1009
901
801
701
601
501
401
301
201
101
A5.112T3 A5.11S3 A3.34E3
^AmJl AJ _. .,,/V -..AJIA-^ JUl-Jl /\nfA JV*
31 00 ' ' 32:00 ' 33:00 '
/sjt/v^/Uu^x
'
oo%,r,r; Exp-.xpcus
HOT. TIME - 22:13
r2.7«
A7.15E3 A3. 12X3
^_jAwA-»A /Wi (f^Ti^^—^-b^inn^^J^^HfuJVJ1^^
12.4X4
.2.1X4
11.9X4
11.6E4
L1.3E4
L1.1T4
La.orJ
L5.4rJ
L2.7E3
34:00 ' ' ' ' 35:00 Tiae
rile,S976758 #1-357 Aoq:16-OCT-1997 22:10,38 XI+ Voltage SIX 70S Koiae:143
443.7399 T:4 SSUS(256,30,-3.0) PXO( 7, 5,3, 0.05%, 572. 0,1.
TSIAWSLE LASS Text:M23 TSESMAL OUTLET XUS*3 TLIf43431
100]
901
801
701
601
501
401
301
201
101
AJ . OOE4
A3. 25X3 AS. 52X3
oo\,r,i) xxptxpcus
ItfJ-. TIME ' 22:13
-1.9X4
A9.86X3
A5.08E3 1 1 f j|tf «jy A2.14IT3 1 1 A3. 13X3
JL^j&VHHJ^+M^AAsviu*^^
31 00 ' ' '32:00' ' ' 33:00 '
Li.7r4
Ll.5£4
Li.4r4
J..2E4
19.7X3
.7.7X3
.5.8X3
.3.9X3
a. 9X3
34:00 35:00 Time
r±le:S976758 #1-357 Acq:16-OCT-1997 22:10:38 EX+ Voltage SIX 70S
430.9729 T:4 XxpsEPCUS
TXIANSLX LASS Tezt:M23 TSESMAL OUTLET *UMf3 TLI443431
10°\ 31:28 31,55 32,17 , . *}[£,
*°ihV^'%Ak«^ArVVAA(A/A/irvv^A/ ^^ v» v
31 ^ Iff" TT *W V » *
70J|
WJ
50J
40J
3aJ
20J
101
o- r_
JliflO 32,00 ' 33*00
33:31
.f% .U|
fwfV
UKT. TIME * 22:13
33:501 of... /*&,, 3fi ^f"? Al\.A A*, i
^ViyNr"^ vVWV\^W^VVv^' ^"T
-.2.8X6
12.5X6
.2.3X6
.2.0X6
.1.7X6
.1.4X6
.1.1X6
.8.5X5
.5.7X5
.2.8X5
0.0X0
34:00 35«00 ' Ii»e
rilm,S976758 #1-357 Acqil6-OCT-1997 22:10,38 EX+ Voltage £XB 70S
513.6775 T,4 Ezp:EPCDS
TRIANGLE LASS Tert:M23 TBESMAL OUTLET XOSt3 T.
1009
90.
801
701
sol
501
401
301
;
201
101
01
CJ#43431
33:17
31 1 39
i
1 1 i 32:06 i
1 J bli55| 32s $yt
^n^tt **i*llHl JLii 1 Jl •3^s-34 L!| Im
'^^'HJl^.^^^y^ VIV ^*y \A^ -Ji>^A|L 1^^ Al L frflij' UL f
•vrw^
31 00 32*00 33:00'
i
33-
1
i y L
J'!JUWW
1^**
JJET. TIME * 22:13
35:05
34:0ff 35:23
1 34,46 1
.4.3X3
.3.9X3
.3.5X3
.3.0X3
.2.6X3
.2.2X3
71 1 1 • '
1 1 3i'i" 1 1 i il 35l4n f1-'7"
1 L LA J«M Jk JL mJi 1^ A MlLwl1-'*3
Ivv'HJ wwv^tA/l^'V^WU/M/^ WMIIU^F
Ls.firi
L4.3r2
lfl.«K6
34:00 ' ' 35 .-00 Time
196
-------
tl-397 Acq:lS-0&-lS97 22:10:38 £1+ Voltage SIS 70s ltoiae:4S
457.7377 rs4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,180.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL OUTLET RVSt3 TLH43431 IKT. TIME = 22:13
A1.07E4 A1.89E3
34:30 34:36 34:42 34:48 34:54 35:00
r±le:S976758 tl-397 &cq:16-OCT-1997 23:10:38 EI+ Voltage SIX 70S «O±ae:47
459.7348 T:4 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,188.0,1.00\,rrT) ExpsEPOJS
TSIAHSLE LASS Text:M23 THERMAL OUTLET SUJft3 TLH43431 IKT. TIME - 22:13
1004 A1.39E4
80.
60.
40.
20.
35:06
4.SE3
'.3. 6E3
'.2.7E3
'.1. 8E3
B.9E2
34:30 34:36 34:42 34:48 34:54 35:00
rile:S9767S8 tl-397 Acq:16-OCT-1997 22:10:38 £7+ Voltage SIS 70S SOiae:S2
469.7779 T:4 BSUB(256,30,-3.0) PB)(7,5,3,0.05\,20B.O,1.00\,P,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL OUTLET STJSt3 TLH43431 HKT. TIME - 22:13
lOOi, Al.f3E6
35:06
.O.OEO
Time
34:30 34:36 34:42 34:48 34:54 35:00
Til»tS9767S8 tl-397 Acqil6-OCT-1997 22:10:38 ZX+ Voltage SIX 70S NO±ao:62
471.7750 T:4 BSUB(256f 30, -3.0) Pn>(7,5,3,O.OS\,248.6,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS Teit.:M23 THERMAL OUTLET XUNt3 XLH43431 INT. TIME = 22:13
10M A2.QSE6
35:06
.2.3E5
.1. 8E5
.1.4E5
9.2E4
4.6E4
O.OEO
Time
-2.SE5
.2.0ES
.1.5E5
.9.9X4
.4.9E4
34:30 34:36 34:42 34:48 34:54
Kle:S976758 91-397 Acq:16-OCT-1997 22:10:38 EH- Voltage SIS 70S
430.9729 F:4 Xxp:EPCUS
TRIANGLE LABS Tert:M23 THERMAL OUTLET IUB*3 TLH43431 HIT. TIME -
100* 34jjl 34:34 34i37 34:43 34:53
80.
so:
40:
20:
o:
35-00
35:06
O.OEO
Time
22:13
34-30
34:36
34:42
34:48
34:54
35:00
35:06
.2.BE6
.2.2X6
.1.7X6
.1.1S6
.5.5X5
0.0X0
Time
197
-------
Ref, lass 282.8825 Peak top
Height .62 volts Span 266 ppi
Systa file naie
Data file naie
Resolution
Groupnuiber.
lonlzatlon iode
Switching
Ref, lasses 292.9825,
R 293 J 331
B 384
C 386
D 316
E 318
F 329
6 322
K 332
L 334
II 346
H 342
0 352
P 354
8 358
I 331 R 358
EPOJS
fl'S976756
2
D*
YOGE
416.9768
S 368
T 378
0 376
V 418
Channel I 338.9792 Peak top
Height ,68 volts Span 288 ppi
1'9'S
-------
ile:S976758 Ul-829 Acq:16-OCT-1997 22:10:38 EI+ Voltage SIR 70S
31.9368 F:2 Exp:EPCUS
ample Text:M23 THERMAL OUTLET RUN«3 TLI#43431 INJ. TIME = 22:13 File Text;
00% 20j59
90 j
80 j
70J
602
50 j
40J
30j
20 j
10J
n \ r-_
M23 THERMAL O»
9.7E5
L8.7E5
_7.7E5
_6.8E5
_5.8E5
_4.8E5
_3.9E5
_2.9E5
_1.9E5
_9.7E4
21:36 21:48
22:
19:48 20:00 20:12 20:24 20:36 20:48 21:00 21:12 21:24
ile:S976758 81-829 Acq:16-OCT-1997 22:10:38 EH- Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text:M23 THERMAL OUTLET RUN#3 TLIU43431 INJ. TIME - 22:13 File Text:M23
20:34
00
O.OEO
Time
THERMAL O»
4.9E3
I ' ' ' ' ' I
19:48 20:00
20:12
I ' '
20:24
20:36 20:48 21:00
21:24
i i i—i
21:36 21:48
22:00
.O.OEO
Time
CD
-------
File:S976758 #1-397 Acq:16-OCT-1997 22:10:38 EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS
Sample Text:M23 THERMAL OUTLET RUN#3 TLI#43431 INJ. TIME =
A8.15E3
90J
80J
70 j
60J
50 j
40 J
30J
20 J
10J
OJ
22:13 File Text:M23
THERMAL O»
._3.5E3
_3 . 1E3
_2 . 8E3
_2 . 4E3
_2 . 1E3
_1.7E3
_1.4E3
T
T
T
T
' i I i i i i i I i i
34:36 34:42
T
T
34:06 34:12 34:18 34:24 34130 34i36 34142 34i48 34i54 35:00
File:S976758 #1-397 Acq:16-OCT-1997 22:10:38 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:M23 THERMAL OUTLET RUN#3 TLI#43431 INJ. TIME =
100%. A1.24E4
90 J
80J
70J
60J
50 j
40J
30J
20J
10J
• ' I I I
35:06
i — TT — i — i
35:12
_7.OE2
_3.5E2
O.OEO
n — i — r~i — i i i i i
35:18 35:24 Time
22:13 File Text:M23
OJ
i i i i ..... i i i • i i i i i • i i i i i i i i i i i i i i i i i i i i i i i • i i i i i i i i i i i
34:06 34:12 34:18 34:24 34:30 34:36 34:42 34:48 34:54 35:00
35:06 35:12
—i—i—TT—i—•—I—r-
35:18 35
THERMAL O»
5.5E3
L5.0E3
L4.4E3
L3.9E3
L3.3E3
L2.8E3
L2.2E3
L1.7E3
Ll.1E3
L5.5E2
LO.OEO
Time
134
-------
esearc
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: M23 THERMAL OUTLET FBI Analysis File: S976759
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Asphalt Roofing Project
M23TRAIN Date Received:
185-5-9 A-D Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/01/97
10/16/97
n/a
S976745
MS
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976754
n/a
n/a
n/a
**»!•* ; ,.
2,3,7,8-TCDD
U,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
U3,7,8,9-HxCDD
U3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
U,3,7,8,9-HxCDF
U,3,4,6,7,8-HpCDF
U,3,4,7,8,9-HpCDF
U,3,4,6,7,8,9-OCDF
' "'A»L"|fck
ND
ND
ND
ND
ND
ND
EMPC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
>. ^ ' Dt ' V "/' EMPC R
-y>x 's. f v f s *• ;• v s
0.009
0.01
0.01
0.01
0.01
0.01
0.01
0.006
0.009
0.009
0.008
0.006
0.008
0.008
0.01
0.01
0.01
ai» irr Flags
—
—
iwiita. r^'^v^* ,^btc(a^;^Mii^'i^ aupcyJVx \*$&&rf:^ . jFNs--
TotalTCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
0.01
ND
ND
ND
ND
ND
ND
ND
1
0.01
0.01
0.01
0.006
0.009
0.007
0.01
_^_
Page 1 Of 2
X237.PSR vioa LARS «.10.0«
gle Laboratories, lnc.»
"10'3 Drive • Durham, North Carolina 27713
: (919) 544.5729 • Fax: (919) 544-5491
Printed: 19:09 10/20/97
201
-------
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: MIS THERMAL OUTLET FBI Analysis File: S976759
Internal Standards v— ;^> AmL (ng)
•• •• :• . >.
13Ci2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
l3C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13Ci2-l,23,6,7,8-HxCDF
13C,2-lA3,6,7,8-HxCDD
13C12-l,2^,4,6,7,8-HpCDF
13C,2-l,23,4,6,7,8-HpCDD
13C,2-123,4,6,7,8,9-OCDD
SaiirogatfiSterMtedsnVpeA) ;
•• *^ .$-.-. * * ?f v
37Cl4-23,7,8-TCDD
13C12-2,3,4,7,8-PeCDF
13Cn- 1,23,4,7,8-HxCDF
13C12-l,23,4,7,8-HxCDD
I3Cl2-123,4,7,8,9-HpCDF
^^^*"^^l"SwL'" xj"^_j •'ijjSP*'** --JJ^iSXSXj.
aCu-l,23,7,8,9-HxCDF
13Ci2-2,3,4,6,7,8-HxCDF
2.3
2.2
22
2.3
3.2
3.1
2.4
2.9
62
AWtv(R^
3.9
3.8
3.1
2.9
3.4
f. Js-ys jp. -,-.•. JA >x A
M^MNf
2.6
2.9
% Recover
58.7
54.4
54.9
56.8
78.8
76.9
60.9
73.5
77.1
p^J^fia<»van
97.9
95.0
76.4
71.9
86.2
ll||l&Beco¥er!
65.5
72.6
I QC Limits 3&
> S V f V.
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
f ^\&&l&fttij^
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
rT«eijtaw^
40%-130%
40%-130%
SL Ratio v
0.79
0.80
1.55
1.40
0.48
1.20
0.42
0.98
0.84
pftk
1J2
0.50
1.18
0.40
S&S&tJKti'
0.48
0.48
RT
20:25
21:13
24:43
25:51
28:29
29:13
31:13
32:05
34:36
8T
21:14
25:29
28:23
29:08
32:26
ST
29:44
29:01
Flags
—
Flags
—
'", Flags
RT
Flags
»3Ci2-l,23,4-TCDD
13C12-lA3,7,8,9-HxCDD
0.81
122
20:59
29:31
Data Reviewer.
Page 2 of2
10/20/97
X237JPSR rlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:09 10/20/97
202
-------
Data Review By:
Initial ....Date...
Yr ^j'^j
Calculated Noise Area:
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
0.49
Page No.
10/20/97
Listing of S976759B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
H_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name..
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
ID. . Flags.
320-322
37C1-TCDD
328
DC
DC
DC
DC
NL
SN
0
NL
WL
2
0:00
18:59
Peaks
0:00
19:16
19:57
20:25
Peaks
0.65-0.89
0.81 1
RO 6.31 0
0
0.65-0.89
RO 0.51 0
RO 0.63 13
RO 0.98 5
0.79 637
643
0.826-1.103
.21
.51
.00
0
0
.000
.930
0.951-1.049
.71
.91
.22 2.89
.95 281.01
.17
0
0
2.95 0
356.94 1
.000
.944
.977
.000 13C12-2378-TCDF ISO
0.65-0.89
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
1
0:00
18:46
19:00
19:05
19:20
19:24
19:32
Peak
RO 1.15 0.69
RO 4.00 0.16
RO 1.00 0.41
RO 1.42 0.46
RO 1.16 0.97
0.66 0.93
0.89 1.34 0.63
0.858-1.060
0.000
0.885
0.896
0.899
0.911
0.914
0.71 0.921
1.34
0.906-1.094
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
0:00
18:14
18:27
18:37
18:43
18:45
18:56
18:56
19:13
19:21
19:30
19:40
19:47
20:12
20:45
21:04
21:14
21:29
21:46
0.21
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
394.
6.
0.
67
43
34
29
30
08
14
27
39
26
47 3 . 47
82 0.82
38
37
46
54 394.54
33 6.33
59
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
000
859
870
877
882
884
892
892
906
912
919
927
932
952
978
993
001 37C1-TCDD SOR1
013
026
Triangle Laboratories, Inc.® Analytical Services Division
801 Capttola Drive * Durham, North Carolina 27713
phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:09 10/20/97
203
-------
Page No.
10/20/97
Listing of S976759B.dbf
Matched GC Peaks / Ratio / Rec. Tin
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.
ID.. Flags.
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
340-342
13C12-PeCDF
352-354
352-354
K
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
8
ML
SN
SN
5
ML
SN
SN
SN
SM
SN
SM
SN
SN
SN
SN
0
ML
SN
SN
SN
SN
SN
SN
5
21:56
22:02
22:16
22:24
22:29
22:37
22:43
Peaks
0:00
19:53
20:26
20:59
21:13
21:36
21:43
21:51
Peaks
0:00
22:36
24:09
24:40
25:06
25:34
25:46
25:59
26:19
26:33
26:40
Peaks
0:00
22:49
23:06
23:13
23:47
24:05
24:21
24:43
25:09
25:29
26:19
26:32
Peaks
0.
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
0
0
0
0
0
0
0
408
.84 0.84
.93 0.93
.66 0.66
.84 0.84
.39
.37
.33
.43
65-0.89
5
1
6
0
0
0
1
1
.62
.30
.96
.81
.80
.75
.68
.57
1
32-1.78
0
13
0
0
0
0
0
1
0
1
0
.87
.00
.43
.14
.65
.68
.50
.08
.42
.29
.30
0
4
0
.23
.67 3.44
.46
824.42 367.87
478
12
0
2
.04 212.36
.26 5.24
.67
.41 2.14
1.
1.
1.
1.
1.
1.
1.
034
038
049
056
060
066
071
0.906-1.094
0.
2.64 0.
0.
456.55 0.
265.68 1.
7.02 1.
1.
1.36 1.
000
937
963
989 13C12-1234-TCDD
000 13C12-2378-TCDD
018
024
030
RSI
IS1
.321.80
0.21
0
0
0
0
0
0
0
0
0
0
0
.05
.26
.20
.25
.31
.08
.64
.44
.30
.36
.00
32-1.78
1
1
1
1
1
1
1
.11
.19
.00
.05
.51
.43
.33
1.55
RO
RO
1
1
1
2
.11
.52
.62
.15
1
0
0
0
0
20
0
4
512
2
472
0
1
.012
.16
.53
.28
.35
.32 12.22
.34
.48 2.56
.87 311.37
.45 1.49
.57 285.31
.55
.38
.69
0.908-1.080
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
000
914
977
998
016
034
042
051
065
074
079
0.838-1.162
0.
0.
0.
0.
8.10 0.
0.
1.92 0.
201.50 1.
1.34 1.
187.26 1.
1.
1.
000
923
935
939
962
974
985
000 13C12 -PeCDF 123
018
031 13C12-PeCDF 234
065
073
IS2
SOR2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:09 10/20/97
-------
page No.
10/20/97
Listing of S9767S9B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak.l.. Area. Peak. 2. . Rel.RT Compound. Name.. ID.. Flags.
PeCDD
356-358
356-358
13C12 -PeCDD
368-370
368-370
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
WH
WH
0
NL
SN
SN
SN
SN
2
1
0:00
23
24
24
25
25
26
26
26
:52
:28
:52
:36
:46
:16
:37
:45
RO
RO
RO
RO
RO
RO
RO
----- ADOve: j-et-ur / m-uu roiiows
.32-1.78
1.
0.
2.
2.
1.
1.
1.
8.
0.
56
21
05
13
05
00
33
20
69
Peaks
0
24
24
25
25
25
26
:00
:07
:54
:18
:51
:59
:22
1.
RO
RO
RO
RO
RO
RO
0.23
0.12
0.
0.
0.
0.
0.
0.
0.
0.
,54
,20
69
18
28
13
44
00
32-1.78
1.
0.
2.
1.
1.
1.
0.
25
29
57
00
40
95
59
Peaks
0.
0.
0.
0.
297.
35.
0.
333.
16
12
36
41
60 173.45
80 27 . 37
72
40
0.921-1.027
0.000
0.
,923
0.946
0.962
0.
0.
1.
1.
1.
990
997
016
030
035
0.845-1.155
0.
0.
0.
0.
124.15 1.
14.0-4 1.
1.
000
933
963
979
000 13C12-PeCDD 123 IS3
005
020
HxCDF
374-376 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
374-376
13C12-HXCDF
384-386 DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
SN
0:00
27
27
28
28
28
28
28
29
29
29
29
29
:43
:50
:00
:25
:30
:47
:53
:01
:05
:15
:32
:58
1
RO
RO
RO
.05-1.43
1.86
1.58
0.29
1.20
RO
0.81
1.30
RO
RO
RO
RO
RO
1.
2.
1.
0.
2.
4.
0.
40
33
14
54
29
00
81
Peaks
0
27
27
27
27
28
28
28
28
:00
:23
:31
:41
:56
:23
:29
:43
:49
0.
RO
RO
RO
RO
RO
0.31
0.27
0.18
0.44
0.45
0.53
0.
0.
0.
0.
0.
0.
0.
0.
36
07
92
13
31
22
23
00
43-0.59
0.
0.
0.
0.
0.
0.
0.
0.
0.
38
63
48
42
31
50
48
47
15
0.
33
4.00 1.66
9.
0.
0.
385.
526.
6.
1.
43 3.06
68
38
64 127 . 92
49 170.68
41 2.06
18
0.957-1.054
0.
.000
0.973
0.977
0.983
0.
,998 123478-HxCDF
1.001 123678-HxCDF
AN
AN
1.011
1.
1.
1.
1.
1.
1.
014
019 234678-HxCDF
021
027
037
052
AN
0.860-1.140
0.
2.65 0.
6.37 0.
0.
0.
257.72 0.
000
961
966
972
981
996 13C12-HXCDF 478
355.81 1.000 13C12-HXCDF 678
4.35 1.
1.
008
012
SUR3
IS4
^tangle Laboratories, Inc.® Analytical Services Division
>01 Capitola Drive • Durham, North Carolina 27713
hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:09 10/20/97
205
-------
Page No.
10/20/97
Listing of S976759B.dbf
Hatched GC Peaks / Ratio / Rat. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OX Ratio Total. Area...
Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
384-386
HXCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
10
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
HH
0
NL
WL
6
NL
SN
SN
SN
SN
0
29:01
29:15
29:19
29:25
29:34
29:44
30:02
30:11
30:13
Peaks
0:00
27:48
27:57
28:13
28:24
28:28
28:40
28:43
28:47
28:53
29:05
29:15
29:25
29:47
29:53
30:01
Peaks
0:00
27:47
28:37
29:08
29:13
29:31
29:51
29:51
Peaks
0:00
31:40
31:53
32:07
32:28
Peaks
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
0.48
0.27
0
0
0
0
1
0
0
.75
.74
.35
.48
.72
.15
.28
. .
449
2
2
1
0
352
1
0
0
1,739
05-1.43
1
0
0
1
3
3
0
1
1
1
0
0
0
0
0
1
.50
.38
.71
.09
.70 '
.83
.95
.00
.71
.64
.14
.62
.67
.46
.89
.15
0
0
0
.20 145.34
.72 0.92
.02 1.01
.10
.98
.12 113.48
.09 1.24
.59
.50
.12
.22
.05
.27
0.23
0
0
0
0
0
0
0
0
0
0
0
0
0
.22
.27
.33
.09
.16
.31
.05
.51
.14
.31
.29
.28
.00
05-1.43
1
0
1
1
1
1
0
1
.00
.59
.11
.18
.20
.22
.58
.85
88-1.20
1
.38
0.46
0
.76
2. 52
1
.31
0
0
3
297
424
554
1
2
.16
.31
.10 1.63
.15 160.61
.56 231.28
.98 305.35
.79 0.99
.22 ' 1.83
303.86 1
3.38 1
1.34 1
1
1
238.64 1
0.72 1
1
1
0.951
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
.019 13C12-HXCDF 234
.027
.029
.033
.038
.044 13C12-HXCDF 789
.054
.060
.061
-1.016
.000
.952
.957
.966
.972
.974
.981
.983
.985
.989
.995
.001 123678-HxCDD
.007
.019
.023
.027
ALT2
ALT1
AN
0.966-1.034
0
0
1.47 0
136.54 0
193.28 1
249.63 1
1.71 1
0.99 1
.000
.951
.979
.997 13C12-HXCDD 478
.000 13C12-HXCDD 678
.010 13C12-HXCDD 789
.022
.022
SOR4
IS5
RS2
1,283.80
0
.16
0.37
0
0
0
0
.43
.43
.65
.00
0.996-1.047
0
1
1
1
1
.000
.014
.021
.029
.040 1234789-HpCDF
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capttola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:09 10/20/97
206
-------
Page No.
10/20/97
Listing of S976759B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.PeaJc.l. . Area. Peak. 2. . Rel.RT Compound. Name.. ID.
Flags.
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
3
NL
SN
SN
SN
WH
WH
0
NL
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
0:00
31:13
32:10
32:26
32:46
32:51
Peaks
0:00
31:35
31:45
32:11
32:27
32:37
Peaks
0:00
31:30
31:47
32:05
32:36
Peaks
0:00
31:32
32:00
32:26
32:43
33:02
33:20
33:38
33:49
34:02
34:10
34:18
34:36
34:55
35:05
35:11
35:20
35:36
Peaks
0
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
0.
RO
.37-0.51
0.97
0
1
0
1
0
.42
.09
.40
.63
.35
88-1.20
1.38
2.06
3.64
1.50
3.08
3.31
0.43
299.60 89.34
0.50
199.22 57.26
0.82
3.80 1.16
502 . 62
/
0.16
0.33
0.22
0.33
0.24
0.33
0.00
88-1.20
1.29
0.89
RO
0.37
0.98
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.50
— Above:
0.84
3.29 1.55
0.22
332.23 164.27
0.43
335.52
HpCDD / Octa-CDD and CDF
76-1.02
0.
0.
0.
0.
0.
1.
0.
0.
3.
0.
0.
1.
0.
0.
0.
1.
0.
0.
41
83
95
64
33
07
13
39
05
78
50
13
53
49
27
83
42
38
0.23
0.33
0.72
0.34
0.40
0.57
0.11
0.25
0.42
0.57
0.49
0.28
0.36
0.36
0.59
0.43
0.42
0.49
0.00
0.936-1.128
0.000
210.26 1
1
141.96 1
1
3.28 1
.000 13C12-HpCDF 678 IS6
.030
.039 13C12-HpCDF 789 SOR5
.050
.052
0.978-1.007
0
0
0
1
1
.000
.984
.990
.003
.011
1.017
0.969-1.031
0.000
1.74 0.982
0.991
167.96 1.000 13C12-HpCDD 678 IS7
1.016
0.884-1.116
0.000
0.911
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
925
937
946
955
963
972
977
984
987
991
000
009
014
017
021
029
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:09 10/20/97
207
-------
Page No.
10/20/97
Listing of S976759B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT compound.Name.
OCDD
458-460
458-460
0.76-1.02
DC KL 0:00 0.89
34:36 RO 0.73
DC SN 34:48 RO 0.52
DC SN 34:58 RO 3.89
DC SN 35:05 RO 1.33
1 Peak
0.17
0.79
0.28
0.17
0.23
0.79
0.37
0.884-1.116
0.000
0.51 1.000 OCDD
1.006
1.011
1.014
ID.. Flags.
AN
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 1.00 0.18
34:36 0.84 444.34
DC WH 35:11 RO 0.36 1.06
470-472 1 Peak 444.34
203.05
0.998-1.007
0.000
241.29 1.000 13C12-OCDD
1.017
IS8
Column Description.
"Why" Code Description OC Log Desc.
M_Z -Nominal Ion Mass(es)
. .RT. -Retention Time (tnn:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Boise Level
-------
File:S9767S9 tl-829 Acq:16-OCT-1997 22:50:00 EI+
Voltage SIR 70S Noiae:272
303.9016 F:2 BSUS(256,30,-3.0) PKD(9, 5, 5,0. 051,1088. 0,1.00\,F,T) Ezp:EPCOS
TRIANGLE LABS Text:M23 THERMAL OOTLET FBI TLI #43431 IJfJ". TIME * 22:52
100.
80.
60.
40.
20.
0
Al . B3E4
i A2.06E4 i
fc.1 I 1 A1-3SE4
, m iii. WJurl, Aih
MA^A^KIIW |y wwk
T iyl [ ' " 1 In 1
17:00 18:00 19:00
File:S976759 tl-829 Aeq:16-OCT-1997 22:50:00 EH-
305.8987 F:2 BSOB(256,30, -3 .0) PKD(9, 5, 5,0.051,13
A6.76E3
A4 . 15E3
1 t
y /* it M u . .i/il ui A J jj/l H-5^
JWVAlttiiM^^
3.7E3
:2.9E3
•
.2.2E3
. 7 . 4E2
O.OEO
'20:00 21:00 22:00 Tiae
Voltage SJJ? 705 Boise: 334
36.0,1.00\,F,T) Eip:EPCUS
TRIANGLE LABS Tezt:M23 THERMAL OOTLET FBI TLIt43431 IKT. TIME - 22:52
100]
80.
60.
40.
20.
0:
A1.5BE4
1
A8.93E3 A1.41E4
ii i mi i ,« tktdmfS!*! Jil u "i
*^™^ M
I'wv'rr 1 III i If II
17:00 18:00 19: 00'
|| 1 I A,5-ffl"
5r3^ ILl , *i k h A! im J kji 1 1
rJ^Wwt^^
_j
.4.5X3
.3.6X3
I-.2.7X3
Ll - 8E3
L9 . OE2
: o . oro
20-00 21:00 22:00 Time
File:S976759 tl-829 Aeg:16-OCT-1997 22:50:00 EI+ Voltage SIR 70S Boise: 154
315.9419 Fi2 BSUB(256, 30, -3.0) PKD(9,S,5,0 .05\,616.0,1.00\,F,T) Exp:EPCUS
TRIASSLE LABS Tert:M23 THERMAL OOTLET FBI TLIt43431 UKT. TIME - 22:52
1001
80:
60:
40:
20:
o:
17:00 18:00 19:0o'
A2-.81E6 -5.5.E5
1
/ V^
.4.4E5
.3.3E5
.2.2E5
.1.1X5
O.OEO
^0;00 21*00 22:00 Cue
Filc:S976759 tl-829 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIR 70S Jfci.ae.-305
317.9389 T:2 BSOB(256,30,-3.0) PXD(9rS,5r0.05\,1220.0,1.00\,F,T) XxpsXPCUS
TRIASSLE LABS Tert:H23 THERMAL OOTLET FBI TLH43431 UKT. TIME - 22:52
1001
80:
60:
40:
20:
17:00 18.-00 19:CO'
A3.S7E6 7.3B5
I
1
/ V
.5.8E5
.4.4X5
.2.9X5
-.1.5X5
O.OEO
'20:00 21:00 22.-00 Time
File:S976759 tl-829 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIR 70S
330.9792 F:2 Exp:EPCOS
TRIASGLE LABS Text:M23 THERMAL OOTLET FBI TLI t4 3431 TKJ. TIME - 22:52
1001
80:
60\
40:
20:
o"
17:07 17:45 18:25 18:58 ^19
^^^--^-l-^^*-n^r V
17:00 18:00 19:00
.46 20:36 21:24 22:01 . ^6.3E6
• ^" _ _ ._. ^, , ^» . .. _ ^d. *»fc^**.^ . *i ft^tf^^^^^x^^.^1 ^* »^^a^/V» .
.5.1E5
.3 . 0.E6
.2.5X6
.1.3X6
0.0X0
'20:00 21:00' ' ' '22:00' ' Time
ftUe: 59 76759 tl-829 Aoq:16-OCT-1997 22:50:00 EI+ Voltage SIR 70S
375.8364 F:2 XzptEPCOS
TRIANSLE LABS Text:M23 THERMAL OOTLET FBI TLH43431 1X7. TIME - 22:52
1003
80:
60'
40:
20:
oj
19
19:13
18:51
i
^Ai^lll-V^|^r-ii.i>,A??-^,r->JA/-r-Al-l.' nAP"1. '-.JlvAjUA^
17:00 18:00 19:00
44 9.3X3
20 1 19
I 1 20:54 51:23 22:16 .
.7.4E3
.5.6E3
3.7X3
1.9X3
O.OEO
20:00 21: 00' ' 22:00 Time
209
-------
Flle:S9767S9 #1-829 Acq:16-OCT-1997 22:50:00 Eli- Voltage SIS 70S Noise:227
319.8965 T:2 BSUB(256,30,-3.0) PKD(7,5,3, 0.05\,908.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Teit-.M23 THERMAL OUTLET TBI 111*43431 nu. TIME « 22:52
1001
19:00 20:00 21:00 22:00
F±le:S9767S9 tl-829 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIR 70S Boise:196
321.8936 Tt2 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,784 .0,1.00\,T,T) Ezp:EPCOS
TRIANGLE LASS Tart:M23 THERMAL OUTLET FBI TLH43431 IBJ. TIKE - 22:52
100\ A6.92E3
19:00 20:00 21:00 22:00
FiletS976759 tl-829 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIS 70S Soiae:364
331.9368 F:2 BSUB(256,30, -3.0) PJX>(7,5,3,0.05\,1456.0,1.00\,f,T) Ezp:ETCOS
TRIANGLE LABS Tart:M23 THERMAL OUTLET FBI TLH43431 JK7. TIME - 22:52
1003
aoj
40:
20:
o:
19:00 20:00 21:00 22:00
File:S9767S9 tl-829 Acq:16-OCT-1997 22:50:00 EH- Voltage SIR 70S Roiie:67
333.9338 F:2 SSUB(256,30,-3.0) PXD(7,5,3,0.05\,268.0r1.00\,F,T) Exp:EPCUS
TRIANGLE LABS Text:M23 THERMAL OUTLET FBI TLH43431 1ST. TIME - 22:52
100* A4.57E6
80:
601
40:
20:
A2.66E6
19:00 20:00 21:00 22:00
rile:S976759 tl-829 Acq:16-OCT-1997 22:50:00 EH- Voltage SIS 70S Noise:106
327.8847 T:2 SSUB(2S6,30,-3.0) PXD(7,5,3,O.OS\,424.0,1.00\,T,T) ExptEPCCS
TRIANGLE LABS Tezt:M23 THERMAL OUTLET FBI TLIt43431 23K7. TIME • 22:52
T11»:S9767S9 tl-829 Aeq:16-OCT-1997 22:50:00 EI+ Voltage SIR 70S
330.9792 T:2 ExpiEPCUS
TRIANGLE LABS Tetxt:M23 THERMAL OUTLET FBI TU#43431 HP. TIME •
22:52
9.0E5
7.2E5
5.4ES
3. 6E5
1. 8E5
.O.OEO
Time
1. 1E6
.9.0E5
•.6.7E5
.4.5E5
.2.2ES
O.OEO
Time
003
ao:
so:
40:
20:
A3.95E6
*
IV
19':00 20':00 2l'tOO 22:00
8.7E5
.7.0E5
.S.2E5
'•.3 . 5E5
.1 . 7E5
Tiae
ion
ao:
60:
40:
20:
o-
I8..25 ,e,Sa 19:46 20:18 20:3620:52 21:24 __rg2*04 ^ —HlQ^.
' 19l:00 ' 20:00 21:00 22:00
^6.3E6
•.S.1E6
-.3.8E6
:.2.5E6
.1.3E6
• 0 . OEO
TiMC
210
-------
File:S976759 tl-829 Acq:16-OCT-1997 22:50:00 £1+
339.8597 f»2 SSUS(256f30r-3
0)
TRIANGLE LASS Text:M23 TSESMAL
100.
80.
60.
!
Voltage SIS 70S Soise:66
PXBf7,5,3,0.05»,264.0,1.00%,J',r; Exp:EPCUS
OUTLET r.
Bl TLIt43431 XKT. TIME - 22:52
A6.35E3
401 i
3°M^L A.^ ^Jl
23:00 '
AS.
!1E3
InjAvLll^
' 24:00 '
A2.37E3
^SLMJ^Lm
rile:S9767S9 tl-829 Acqil6-OCT-1997 22:50:00 EI+
341.8567 r-.2 SSUS(256,30,-3.
' 25:00 '
A3 . 94E3
WlX<^!^--w^^
4.2E3
:3 . 3E3
.2.SE3
-.1 . 7E3
.8.4E2
' 0 . OEO
2ff.-00 27:00 Tine
Voltage SIS 70S Soiae:75
0) PKD(7,S,3rO.OS\,300.0t1.00\,r,T) Erp:EPCUS
TSIAHSLE LASS Ta*t:M23 TSESMAL
10K
80.
60.
Aft
< v_
20.
0
,, 7._, A830.16
* *•*"•* til • G£B
1 1 1 fl I A9OO
23:00
OUTLET rsi TLH43431 UKT. TIME - 22:52
AS.
A4.46E3
^M^li
' 24:00 '
ftiflt
32E3
A4.
A3.40E3
' 25:00 '
A3 . 32E3
01E3 I A7.36E3
-S.1E3
.4.1E3
.3 . 1E3
.2 . 1E3
.1 . OE3
' 0 . OEO
' 26\00 ' ' 27-00 Tiae
rile :S9 76759 tl-829 Acqsl6-OCT-1997 22:50:00 EI+ Voltage SIS 70S Noise: 51
351.9000 T-.2 SSUS(256,30,-3.
0) PXD(7,5,3,
TSIASSLE LASS TextsM23 TSESMAL
ion
sol
60:
40:
20:
OJ
' 23:00
O.OS\,204.0,1.00\rr,T) Exp:EPCUS
OUTLET rsi TLIt43431 HtJ. TIME - 22:52
24:00
A3.11E6 A3.
»
/ ^ '
25-00
85E6 7.9E5
L,
.6.3E5
.4.8E5
.3.2E5
.1 . 6ES
'• 0 . OEO
' 26:00 ' '27:00 Time
rilesS9767S9 tl-829 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIS 70S Soiae:47
353.8970 r:2 SSUB(256,30r-3.0) PKD(7,S,3,
TSIANSLE LASS Tert:M23 TBSSMAL
1003
aol
sol
40:
20!
ol
' 23:00
OUTLET rS
' 24:00
0.05\,188.0r1.00\,r,T) E*p:EPCUS
1 TLH43431 IKT. TIME - 22:52
A2
•92*6 Al.
|
A
f ^- '
' 25:00 '
87E6
*
1
V
.S.4ES
-4.3E5
.3.2ES
-2.2E5
-1.1E5
• 0 . OEO
' 25:00 27.-00 Time
rile:S976759 tl-829 Aeg.:16-OCT-1997 22:50:00 EI+ Voltage SIS 70S
330.9792 r:2 Exp-.EPCUS
TSIAHSLE LASS Text:K23 TSESMAL
1001
80:
60l
40:
20:
ol
OUTLET rsi TUt43431 HZ7. TIME « 22:52
22:49 23'^Lj^i52 24:18 24:43 JS£i£L^
231 00
r
24:00
' 25:00
_25H|3^^2g;0^ , 26;41 6.6E6
.5.3E6
.4.0E6
.2. 6E6
.1 . 3E6
O.OEO
26:00 ' '27:00 Tiae
rile:S976759 tl-829 Aoq:16-OCT-1997 22:50:00 ET+ Voltage SIS 70S
409.7974 r:2 SxptEPCUS
TRIMtCT.r rjims Tftrf-tr2l TOE
1001
80:
sol
40:
20:
ol
s*
23
23:15
i
22:58 M
^JW-A-J^J\Ml!l>^v-.
23:00
IV
XL
40
?D!TX£7 F3*
'. TLIt434
? i nrr T
ner m •>?•*:•}
C4.7E3
24-51
23:55 ----- as,17 t
1
(
Jt
i
A 24:1
JWAA.
24:00
3 24s29\
1 1
1 KK J 1L
-~*v'k/ul/'wJU\J
25:00
. 25:57 26:38
JLJJJ1 26 J^ I | ,
.3.8E3
.2.8E3
.1.9E3
.9.4E2
O.OEO
' 26:00 27:00 Time
211
-------
759 tl-BSS Acg,:16-o£T-l$97 22:50:00 £X+ voltage six 70S
355.8545 r-.2 BSOB(256,30,-3.0) PKD(7,5,3, 0. OS\,272. 0,1.00\,T,T) SxpsEPCUS
TRIANGLE LABS Teit:M23 TSESMAL OOTLET FBI TLH43431 JK7. TIME - 22:52
1001
80.
24:00 25:00 25:00
rile:S976759 tl-829 Acq:16-OCT-1997 22:50:00 EH- Voltage SIS 70S Boiset44
357.8516 T-.2 BSUB(256,30,-3.0) PXD( 7,5,3, 0. 05\,176.0,1.00\,r,T) Exp:EPCOS
TRIANGLE LABS T«xtiM23 TSESMAL OOTLET FBI TLH43431 HKT. TIME - 22:52
1001
Time
^2.4E3
24:00 25:00 26:00
Tile:S9767S9 fl-829 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIS 70S Boise:49
367.8949 T:2 SSUS(256,30,-3.0) PKD(7,5,3,0.OS\,196.0,1.00\,f,T) Ezp:EPCUS
TSIASSZE LASS Tezt:H23 THERMAL OUTLET TS1 TLH43431 INJ. HUE - 22:52
1003k A1.73E6
80.
60.
401
20.
.74E5
24:00 25:00 26:00
rile:S976759 tl-829 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIS 70S Boise-.40
369.8919 T:2 SSUS(256,30,-3.0) PKD(7,5,3,0.OS\,160.0,1.00\,T,T) Exp:EPCUS
XSIASSLE LABS Tezt:H23 THERMAL OUTLET FBI TLH43431 INT. TIME - 22:52
IOCS
80.
60.
40.
20.
A1.24E6
.40E5
24:00 25:00 26:00
r±le:S976759 il-829 Aeq:16-OCT-1997 22:50:00 EH- Voltage SIS 70S
330.9792 T:2 Exp:EPCUS
TKIAHSLZ LABS Teit:M23 XSESMAL OUTLET FBI TLH43431 XK7. TIME - 22:52
60.
40.
20.
24:00
25:00
26:00
,.5.2E5
-4.1E5
'.3.1ES
.2.1E5
.1. OE5
O.OEO
Time
.2.8E5
.2.1E5
,1.4E5
.7.1E4
O.OEO
Time
6.6E6
.S.3E6
.4. OE6
.2.6E6
.1.3E6
O.OEO
Time
212
-------
File:S9767S9 fl-475 Acq:16-OCT-1997 32:50:00 EI+ Voltage SIR 70S Noise:130
373.8208 r:3 BSO3(256r30, ~3. 0) fXD(7,5,3, 0.Q5\,520.0,1. 00\,F,T) Ezp:EPCDS
TRIANGLE LASS Text:M23 THERMAL OUTLET FBI TLH43431 INJ. TIME - 22:52
1003
80:
60l
Al.89E3
A4.90E3
A4.03E3
A2.44E3
A3.22X2
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
File:S976759 #1-475 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIR 70S Soiae:69
375.8178 F-.3 BSUB(256,30,-3.0) Pa>(7,S,3,O.OS\,276.0,1.00\,T,T) Erp:EPCUS
TRIANGLE LASS Te*t:M23 THERMAL OUTLET FBI TLH43431 ZW. TIME - 22:52
A3.70E3 _j
Tim
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
File:S976759 tl-475 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIR 70S Noi*e:S3
383.8639 T:3 BSUB(256,30r-3.0) PXD(7rS,3rQ.OS\,212.0,1.00\,F,T) Exp:EPCUS
TRIANGLE LABS Tert:M23 THERMAL OUTLET FBI TLH43431 ISJ. TIME ' 22:52
100}
SO:
60l
40:
Al 71E6
Al.45E6
A1.13E6
27:24 27:36 27:48 28:00 28:13 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
rile:S9767S9 fl-475 Acg:16-OCT-1997 22:50:00 EH- Voltage SIS 70S Boiae:144
385.8610 T:3 BSUB(256,30,-3.0) tXD(7,S,3,O.OS\,S76.0,1.00\rr,T) Exp-.EPCOS
TRIANGLE LABS T*Xt:M23 THERMAL OUTLET FBI TLH43431 HKT. TIME * 22:52
1003
80:
50:
4ft!
20:
A3.56X6
A3.04E6
A2.39E6
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
rila:S976759 fl-475 Aeq:16-OCT-1997 22:50:00 EH- Voltage SIR 70S
392.9760 F:3 Exp:EPCUS
TRIANGLE LASS Te*t:M23 THERMAL OUTLET FBI TLI 143431 OCT. TIME ' 22:52
iOn
80
60:
40:
ao-
0.
eil*:S976759 tl-475 Aeq:l6-OCT-1997 22:50:00 EI+ Voltage SIR 70S
45.7555 fs3 XxptEPCOS
TRIANGLE LABS TmrtiM23 THERMAL OUTLET FBI TLI443431 ZK7. TIME - 22:52
1001 29 36
ao:
27:24
37,41 27:55
27134
28:05
29,15
28:33
28:53
28:41
t:OS
29:28
29:5830,0
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 301-00 30:12
Tim
.4.8E5
.3.SE5
.2.9E5
.1.9E5
.9.6E4
.O.OEO
Tim
.1.0E6
8.2ES
.4.1E5
O.OEO
-3.3E6
\-2.7E6
.2.0E6
.1.3E6
O.OEO
Time
5.SE3
.4.6E3
.3.5E3
.2.3X3
.2S3
O.OEO
Time
213
-------
fjJ.«:S97675a tl-475 Aeq:16-dCt-l997 23:50:09 EI+ Voltage SJte Ids Jfej.ae.-7J
389.8156 T:3 BSO3(2S6r30, -3.0) PXD(7,5,3,0.051,292.0,1.00\,r,T) SxpiEPCUS
TRIANGLE LASS Text:M23 THERMAL OUTLET FBI TLH43431 IK7. TIME - 22s 52
100$ A3.6923
27:48 28-00 28:12 28:24 28-36 28,48 29:00 29:12 29:24 29:36 29:48
T±1*:S9767S9 41-475 Aeq:16-OCT-l997 22:50:00 EH- Voltage SIS 70S Noiae:52
391.8127 F:3 BSUB(2S6,30,-3.0) PXD(7,S,3,0.05\f208.0,1.00\,T,T) ElcptEPCUS
TSIASSLE LABS Text:M23 TSESMAL OUTLET FBI TLIf43431 IJTJT. TIME * 22:52
1004 A4.50E3
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
file:S976759 tl-475 Aoj:16-OCT-1997 22:50:00 EH- Voltage SIS 70S Koiae:45
401.8558 F:3 BSOB(256,30,-3.0) PXD(7,5,3,0.05\,180.0,1.00\,r,T) Eip:EfCOS
TRIASSLE LABS TfXt:H23 TEESMAL OOTLJST FBI XLH43431 IXJ. TIMS - 22s 52
1001 A3.OSES
O.OEO
30:00 Titte
_ 3. 6E3
OEO
29:36 29:48 30:00 Time
80.
SO.
40.
20.
A2.31E6
8.4ES
.6. 7ES
-S.1ES
.3.4ES
.1. 7E5
29:36 29:48
A1.93E6
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
F±le:S976759 H-47S Acq:16-OCT-1997 22:50:00 ZI+ Voltage SIS 70S Soi.oe-.47
403.8529 F:3 BSUB(2S6f30,-3.0) PKD(7,5,3,0.9S\r188.0,1.00\,F,T) Exp:EPCUS
TSIASSLE LABS Text:M23 TSESMAL OVTT.fr FBI TLH43431 HTJ. TIME = 22:52
1004 A2.50E6
80.
60.
40.
20.
OJ
27': 4 8 28:00 28:12 28:24 28:36 28-48 29:00 29:12 29:24 29:36 29:48
F±le:S976759 tl-47S Aoj:lS-OCT-1997 32:50:00 XI+ Voltage SIS 70S
392.9760 T:3 XxpiSPCUS
XSIAIKLX LABS Tert:M33 TBESMAL OUTLET FBI TLH43431 XKT. TIME • 22:52
10n 27:59 *5\£5L/-€8s'2-1 28:39 2»s47 28:57 29:17 29}26_ 29:39 29:50
80.
60.
40.
20.
.O.OEO
30:00 Time
-6.5E5
.5.2ES
.3.9ES
.2.6E5
.1. 3ES
LO.OEO
30:00 Time
3. 3E6
.2.7E6
.2.0E6
.1.3E6
'.6.6E5
27:48 ' '28160 28:12 28:24 29:36 28:48 29:00 29:12 29:24 29:36 29:48
30,
O.OEO
00 Time
214
-------
rile:S976759 01-397 Acq:16-OCT-1997 22:50:00 EH- Voltage SIX 70S Soiae:56
407.7818 Fs4 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,224.0,1. 00\,F,T) ExpsEPCUS
TRIANGLE LASS Text:M23 THERMAL OUTLET FBI TLIt43431 HK7. TIME ' 22:52
100* .
80:
A6.7BE3
A5.33E3
A3.94E3
A A . -
A1.93E3
5.2E3
'-.4.21:3
;3. 1E3
'.2.1E3
Ll. 0£J
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
rile:S976759 tl-397 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIS 70S ttoiae:39
409.7789 Ts4 BSUB(2S6,30,-3.0) PJO>(7,5,3,0.OS\f 156.0,1.00\rT,T) ExpsEPCCTS
GLE LABS Teit:M23 THERMAL OUTLET TS1 TLIf43431 HOT. TIME ' 22:52
1003
ao:
32:48
O.OEO
33:00 Tim
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
T±le:S976759 tl-397 Acg:16-OCT-1997 22:50:00 EH- Voltage SIS 70S Hoiae:144
417.8253 F:4 BSUB(256,30, -3.0) PXD(7rS,3r0.05\,S76.0r1.00\,TrT) Eip:EPCUS
TRIANGLE LABS Tert:M23 THERMAL OUTLET FBI TLH43431 JKJ. TIME - 22:52
32:48
lOOi
80.
60.
40:
20:
A8.93E5
A5.73E5
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
r±le:S976759 *1~397 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIS 70S So±ae:149
419.8220 T:4 BSOB(256,30, -3.0) PXD(7,5,3,0.05\,596.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS Text:M23 TBEXMAL OUTLET TB1 TLIt43431 ZZW. TIME - 22:52
32:48
1001
80:
60:
40:
20:
A2.10E6
A1.42E6
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
rile:S976759 tl-397 Acq:16-OCT-1997 22:50:00 EH- Voltage SIS 70S
430.9729 T:4 Exp-.EPCUS
TRIANGLE LABS Text:M23 THERMAL OUTLET FBI TLI443431 IKT. TIME - 22:52
1004 31:11 31:25 31:42 31:53 32:13 32:23 32j40
^^/^V^^S^^—\ . -^ vx-^^^V^^^A-XV-^XA-i /V*~^\ /V>~v
80:
60:
40:
20:
o.
32:48
32:36
31sl2 31:24 31:36 31:48 32:00 32:12 32:24
rU«:S9767S9 tl-397 Acq:16-OCT-1997 22:50:00 EH- Voltagu SIS 70S
479.7165 F:4 Exp:SPOTS
TRIANGLE LASS Tert:M23 -nrrnnaT. OUTLET FBI TLH43431 UU. TIME * 22:52
lorn
ao:
601
40:
20:
0:
32:48
31:24
31:10
31:16
31:12
31s 24
31:36
31:48
32:00
32:12
32:24
32:36
32:48
.O.OEO
33:00 Tia
2.1X5
.1.7ES
'-.1.3ES
.8.4E4
.4.2E4
.O.OEO
33': 00 T±m.
4.9E5
.3.9E5
.3.0ES
.2.0ES
-9.9E4
.O.OEO
33:00 Tiae
-2.4E6
'•.1.9E6
'.1.5E6
L9.7ES
'•L4.9ES
.O.OEO
33:00
6.8E3
.5.4E3
'.4.1E3
.2.7E3
ll.4E3
.O.OEO
33100 Tiae
215
-------
fjJ.e:s976759 il-397 Acq-.lS-o&f-ISS? 22:50:00 EI± Voltage six 70S Noiae:55
433.7766 T:4 BSOB(2S6,30, -3.0) PXD(7,S,3,O.OS\,220.0,1.00\,TtT) ErptEPCUS
TRIANGLE LASS Teit:M23 THERMAL OUTLET FBI TLII43431 XK7. TIME - 22:52
1001
80.
60.
40.
20.
-2.8E3
'.2.3E3
LI. 7E3
'.1. 1E3
'.S.6E2
31:24 31:30 31:36 31:42 31:48 31:54 32x00 33:06 32:12 32:18 32:24 32:30
Til«:S9767S9 il-397 Aoj:16-OCT-1997 22:50:00 EH- Voltage SIX 70S Hoi**:42
425.7737 T:4 BSOS(2S6,30,-3.0) PKD(7r5,3,O.OS\r168.0,1.00\,T,T) Exp:EPCOS
TRIANGLE LABS Text:M23 THERMAL OOTLET T31 TLH43431 1X7. TIME - 22:52
1001 A4.50E3
.O.OEO
32:36 Tine
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24
Tile:S976759 tl-397 Acq:16-OCT-1997 22:50:00 EH- Voltage SIX 70S Noiae:266
435.8169 T:4 BSOB(256,30r -3.0) PXD(7,5,3,0.05\r1064.0,1.00\,T,T) EzpiEPCUS
TRIANGLE LABS Tert:M23 THERMAL OOTLET TB1 TLH43431 JK7. TIME - 22:52
1001 A1.64E6
80.
60.
40.
20.
32:30 32:36
Time
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
filo:S976759 tl-397 Acq:16-OCT-1997 22:SOsOO EI+ Voltage SIX 705 Soiae:205
437.8140 f:4 BSUB(256,30, -3.0) PXD(7,5,3r0.05\r820.0r1.00\rTrX) ExpsEPCUS
TRIJUKLE LABS Text:M23 THERMAL OOTLET TB1 TLIt43431 IXtJ. TIME - 22:52
1001 A1.S8E6
80.
60.
40.
20.
32:24 32:30
3.1ES
'-2.5E5
'.1.9ES
.1.2E5
.6.2E4
.O.OEO
32:36 Time
-3. OES
2.4ES
1. 8E5
1.2E5
6.0E4
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32:36
TilmiS9767S9 tl-397 Acg:16-OCT-1997 22:50*00 EH- Voltage SIX 70S
430.9729 T:4 Exp:EPCOS
TSIAIKLE LASS Text:M23 THERMAL OOTLET Ftl TLH43431 OCT. TIME - 22»52
1001 31t25 _ 31:42 31^53 _ 32:07 32^13 32.-23 32:28 32:34
80.
60.
40.
20.
O.OEO
Time
'31:24 ' '3l':30 ' 31:36 31:42 31:48 31:54 32t09 32:06 32:12 32:18 32t24 32t30 32:36
1.9E6
1.4E6
9.6E5
4.8ES
O.OEO
Time
216
-------
File:S9?6?S$ ii-397 Acq:16-OCT-1997 22:50:00 EH- Voltage SIX 70S Soise
-.53
441.7428 F:4 BSU3(2S6, 30, -3.0) PXD(7,5,3,0.05\,212.0,1.00%,F,T) Exp-.EPCUS
TRIANGLE LABS Text:M23 TSESMAL OUTLET TB1 TLH43431 XKT. TIME •
ion
90.
80.
70.
60.
SO.
40.
30.
201
101
n:
22:52
AS. 71E3 i
I A3.S1E3 A2.12E3 A4.32E3 \A2.48E3 1 AS .08E3 ^ -24E3
31 00 ' ' 32.-00 ' ' 33lsOO~ ' '34:00
2.6E4
12.3E4
12.0E4
'•.1 . 8E4
'.1.SE4
.1.3E4
.1 . OE4
.7.7E3
•'•.5.1E3
.2.6X3
'• o . OEO
35:00 Ti*e
Tile:S9767S9 * 1-397 Acg:16-OCT-1997 23:50:00 EI+ Voltage SIS 70S Xoiaesl33
443.7399 1:4 BSUS(2S6, 30, -3.0) PXD( 7,5, 3, 0 .OS\,S32.0,1.00\,r,T) Exp:EPCUS
XSIANGLE LABS Toxt:M23 TSESMAL OUTLET FBI TLI*43431 JK7. TIME =
1001
901
801
701
sol
SOI
401
301
201
101
22:52
-1 • 8E4
A1.02E4
AB-13E3 A5.B2E3 g2z3 I
, H*7'fi*? *3'?1E3W2*sk* i TP^i?2?? *H'18"-"V A4.40E3 fll*4',8-2"
A_^W JMjff^jUutf^uM ^J\A^b<^L^^JULL^A_MAJV/\ Jlv_AJVA^-A_AAK/M^W 1/lAjswAAA^A^^vA^j
31.00 32:00 33:00 34:00
KleiS976759 i 1-397 Acq:16-OCT-1997 22:50:00 EH- Voltage SIS 70S
430.9729 F:4 Exp-.EPCUS
TSIASGLE LABS Text:M23 TSESMAL OUTLET FBI TLH43431 UU. TIME "
i00\ 31,11 31:53 32:13 32:40 32:59 33:39 33:5y4J^i(34i
3 1** ¥ y V "V *y VV »V " • w I »
soli ]
70J
soJ
50J
401
301
201
101
01
31 00 32: 00 ' 33\00 ' ' ' 34:00
file:S976759 tl-397 Acq:16-OCT-1997 22:50:00 EH- Voltage SIS 70S
513.6775 T:4 Exp-.EtCUS
TSIASGLE LABS Text:K23 TBZSHAL OUTLET FBI TLH43431 OKI. TIME •
1001
901
801
70J
sol
501
401
30\
201
101
01
33:03
31:35
.
31,22 31-b9 I 1 I
1 1 JjT 32:18 32:42 I 1 11
JL\JJ AjLJill^^ kl^^A^J^J^iAA^
IUWV-V UUUJLJWWUU IW^jV3^C/Uj*~V'wU LJ
31 tOO 32:00 33:00 34:00
ll . 7E4
ll.SE4
•-1.3E4
-.1.1X4
.9.2X3
.7.4X3
.5.5E3
-.3.7X3
-.1.8X3
35:00 Time
22:52
30 34:55 35:24 .
n Al A M Ai A-^'*w^
.6.1X3
.5.4X3
.4.8X3
.4.1X3
.3.4X3
.2.7X3
.2.0X3
1.4X3
6.8X2
0.0X0
'35:00 Time
217
-------
File:SS7S75S H-3S7 Acg:16-OCT-l997 22:50:00 Eli- Voltage Sis 70s «oiae:42
457.7377 F:4 BSUS(256,30, -3. 0) PXS(7,5,3,0.05\,168.0,1.00\,FrT) Exp:EPCUS
TRIANGLE IASS Text:M23 THERMAL OUTLET FBI TLIt43431 IK7. TIME - 22:52
1001
80.
50.
40.
20.
A6.32E3
A3.SOE3
A3. S4E3
A1.58E3
34:30 34:36 34:42 34:48 34:54 35:00
File:S976759 fl-397 Acq:16-OCT-1997 22:50s00 EI+ Voltage SIR 703 Hoia*:44
459.7348 F:4 BSUB(2S6,30, -3.0) PXD(7,5,3,0.051,176.0,1.00\,F,T) Exp:EPCUS
TRIANGLE LASS Text:M23 THERMAL OUTLET FBI TLH43431 IKT. TIME - 22:52
1001 AB.Q5E3
35:06
.2.6E3
.2.1E3
.1. 6E3
.1. OE3
.5.2E2
.O.OEO
Time
34:30 34:36 34:42 34:48 34:54 35:00
F±le:S976759 11-397 Aeq:16-OCT-1997 22:50:00 EH- Voltage SIX 70S Koiae:47
469.7779 T:4 BSUB(256,30,-3. 0) PXD(7,5,3,0.05\,188.0,J..OO*,T,T) Exp:EPCUS
TRIASGLE LASS Text:M23 THERMAL OUTLET FBI TLH43431 XK7. TIME - 22:52
1001 A2.Q3E6
35-06
34:30 34:36 34:42 34:48 34:54 35:00
File:S976759 fl-397 Acg:16-OCT-1997 22:50:00 EI+ Voltage SIX 70S Hoiae:44
471.7750 F:4 BSUB(2S6,30,-3.0) PKD(7,5,3,O.OS\,176.0,1.00\,F,T) Exp:EPCUS
TSIASGLE LABS Text:M23 THERMAL OUTLET FBI TLH43431 UCT. TIME * 22:52
35:06
34:30 34:36 34:42 34:48 34:54 35:00
File:S976759 tl-397 Acgil6-OCT-1997 22:50:00 EI+ Voltage 5ZE 70S
430.9729 F:4 Exp:EPCUS
TSIABSLE LABS Tart:M23 THERMAL OUTLET FBI TLH43431 HKT. TIME - 22:52
35:06
.2.9E5
2.3E5
.1. 7E5
.1.1ES
5.7E4
O.OEO
Tine
1003
80.
60.
40.
20.
0
34:30 34:36 34:42 ^^
34:30 ' ' ' 34:36 ' ' ' 34:42 34:48 34:54 !}5:00 ' 3S>06
-2.SE6
.2.0E6
.1.5E6
.9.9E5
.4.9X5
O.OEO
life
218
-------
tef, lass 292,3825 Peak top
Height .62 volts Span 288 ppi
Systei file naae
Data file naie
Resolution
lonization lode
Switching
Ref. lasses 292.
fl 293 J 331
B 384
C 386
D 316
I 318
F 328
G 322
H 3£8
I 331
K 332
L 334
II 348
N 342
0 352
P 354
8 355
R 368
EPCUS
2
0*
VOLfflGE
416.3768
S 368
T 378
U 376
V 418
Channel I 338.3792 Peak top
Height .68 volts Span 288 ppi
219
-------
Flle:S976759 #1-829 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIR 70S
INJ. TIME =
319.8965 F:2 Exp:EPCUS
Sample Text:M23 THERMAL OUTLET FBI TLI#43431
J00%
22:52 File Text:M23 THERMAL 0»
21:54
19148 20:00 20:12 20:24 20:36 20:48
File:S976759 #1-829 Acq:16-OCT-1997 22:50:00
331.9368 F:2 Exp:EPCUS
Sample Text:M23 THERMAL OUTLET FBI TLI#43431
100%,
90_
80_
70_
60_
50_
40_
30_
20_
10J
_9.4E2
_4.7E2
O.OEO
21:00 21:12 21:24
EI+ Voltage SIR 70S
22:00
Time
INJ. TIME =
20:59
21:13
19:48 20:00 20:12 20:24 20:36 20:48 21:00 21:12 21:24 21:36 21:48 22:00
22:52 File Text:M23 THERMAL O»
_9.0E5
_8.1E5
_7.2E5
_6.3E5
_5.4E5
_4.5E5
_3.6E5
_2.7E5
_1.8E5
_9.0E4
O.OEO
Time
-------
ile:S976759 #1-397 Acq:16-OCT-1997 22:50:00 EH- Voltage SIR 70S
57.7377 F:4 ExpiEPCUS
ample Text:M23 THERMAL OUTLET FBI TLI#43431 INJ. TIME =
100%. A3.73E3
22:52 File Text:M23
THERMAL O»
3.7E3
35:12
34:00 34112 34124 34:36 34148 35:00
File:S976759 f1-397 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:M23 THERMAL OUTLET FBI TLI#43431 INJ. TIME = 22:52 File Text:M23
100% A5.10E3
90 J
80 J
70J
60 J
50J
401
30J
20 J
10J
35:24
Time
0.
THERMAL O»
_3 . 6E3
_3.3E3
_2.9E3
_2 . 5E3
_2.2E3
34lob
34-.12
34:24
—i—|—r-
34:36
34148
s'slob
35ll2
35
V24
_1.5E3
L1.1E3
L7.3E2
L3 . 6E2
O.OEO
Time
-------
File:S976759 #1-397 Acq:16-OCT-1997 22:50:00 EH- Voltage SIR 70S
457.7377 F:4 Exp:EPCUS
Sample Text:M23 THERMAL OUTLET FBI TLI#43431 INJ. TIME =
100% A3.73E3
22:52 File Text:M23
THERMAL O»
^3.76:3
0
T 1 1 1 r
35:00
34100 34:12 34:24 34:36 34:48
File:S976759 #1-397 Acq:16-OCT-1997 22:50:00 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:M23 THERMAL OUTLET FBI TLI#43431 INJ. TIME = 22:52 File Text:M23
100% A5.10E3
90J
80J
70J
60J
50J
40 j
30J
20J
10J
:24
Time
OJ
THERMAL O»
3.6E3
_3.3E3
_2.9E3
L2.5E3
L2.2E3
_1.8E3
Ll.5E3
L1.1E3
L7.3E2
L3.6E2
34:00
34:12
34:24
34:36
34:48
35:00
35ll2
35
.O.OEO
•24 Time
-------
TLI Project: 43431 Method 23 PCDD/PCDF Analysis (a)
Client Sample: M23 THERMAL OUTLET RBI Analysis File: S976760
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Asphalt Roofing Project
M23TRAIN Date Received:
185-5-10A-D Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/01/97
10/16/97
n/a
S976745
MS
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976754
n/a
n/a
n/a
AftaJytes ~
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
U3,4,7,8-HxCDD
U3,6,7,8-HxCDD
U3,7,8,9-HxCDD
U3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
U3,7,8-PeCDF
23,4,7,8-PeCDF
U3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
U3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
t^afe '^ '"'.- " '^
1
Total TCDD
fTotalPeCDD
total HxCDD
fTotalHpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Anrt. (n^^
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
v xSR T2.«X LARS 6.10.04
Uboratories, Inc.®
°1 Capitola Drive • Durham, North Carolina 27713
"one: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:09
-------
TLI Project:
Client Sample:
43431
M23 THERMAL OUTLET RBI
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S976760
Irrterriaf Standards - ^V— -
13C,2-2,3,7,8-TCDF
13C,2-2,3.7,8-TCDD
13Ci2-l,2,3,7,8-PeCDF
13d2-l,2,3,7,8-PeCDD
I3C,2-l,2,3,6,7,8-HxGDF
13Cl2-l,2,3,6,7,8-HxCDD
I3C,2-l,2,3,4,6,7,8-HpCDF
13C,2-l,23A6,7,8-HpCDD
13C12-1,23,4,6,7,8,9-OCDD
Surrogate Standards (Pype 4
37CU.2,3,7,8-TCDD
13C12-2,3,4,7,8-PeCDF
13Ci2-l,2^,4J,8-HxCDF
l3Ci2-l,2^,4,7,8-HxCDD
13C,2-l,23,4,7,8,9-HpCDF
Alternate Standards fFyp* A} -V;- ^
-" ?>,!$ •••.••
13C12-1^3,4-TCDD
13CI2-l,2^J,8,9-HxCDD
u^lYtT ( R^Il vw-^ "-xs w
MtHW \K1^J •- X"- s '• 'x
2.2
2.1
2.0
22
2.7
2.7
2.0
2.5
4.9
'•"*. .^. ^ k "* '' * f& ~f<
Antu ^ng| ,^?^
3.8
3.9
3.1
3.0
3.7
*B^HS^^;?
2.3
2.6
'¥^f<.'W'^%
;%'JFterasyaa"
55.8
52.8
50.4
55.0
68.5
67.3
49.7
63.2
60.9
W5$^??!$^s
95.7
96.9
77.7
74.5
93.2
|;-i*|;Q«wv«rftr
58.7
65.6
R^^ciLteite ^
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
^ctiBfe :;f
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
gfaCLIroife^
40%-130%
40%-130%
;^;:o^vr^^.
Ratio
0.74
0.78
155
1.42
0.49
1.27
0.42
0.99
0.88
^P*1* -
1.48
0.49
1.15
0.40
^naife ;
0.51
0.49
^i»f
0.83
123
RT s Flags
20:26
21:13
24:44
25:52
28:30
29:13
31:14
32:06
34:36
f?T "^ Flags,
21:14
25:29
28:24
29:09
32:29
,- ^8fT '-f Flags
29:45
29:01
y £«*,f ***&*
20:59
29:31
Data Reviewer
Page 2 of2
10/20/97
X237J-SR T2.00, LARS 6-10.O"
Triangle Laboratories, Inc.*
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:09 10/20/97
224
-------
Initial
.Date..
Data Review By:
^ E.^2:
Calculated Noise Area:
0.36
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/20/97
Listing of S976760B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
DC
DC
DC
DC
DC
NL
0
NL
WL
WL
ML
2
0:00
Peaks
0:00
17:57
18:07
19:16
20:26
20:54
Peaks
0.65-0.89
0.79 1
0
0.65-0.89
0.81 1
RO 1.50 0
RO 1 . 08 1
0.70 18
0.74 701
0.85 4
705
0.826-1.103
.31
.00
0
.000
0.951-1.049
.25
.71
.96
.34
.47 298.16
.43 2.04
.90
0
0
0
0
403.31 1
2.39 1
.000
.878
.887
.943
.000 13C12-2378-TCDF ISO
.023
TCDD
320-322
320-322
37C1-TCDD
328
0.65-0.89
DC
DC
DC
NL
SN
SK
0
0:00
21:13
21:24
Peaks
RO 0.92 1.06
RO 0.37 0.32
RO 1.14 0.39
0.858-1.060
0.000
1.000 2378-TCDD AN
1.009
0.00
0.906-1.094
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
ML
HL
WL
WL
HL
WL
WL
WL
WL
HL
WL
SN
SN
SN
SN
SN
0:00
18:16
18:21
18:24
18:25
18:35
18:39
18:41
18:51
18:54
18:58
19:31
19:38
19:47
20:11
20:25
20:34
20:45
21:14
21:36
21:43
21:54
0.64
0.46
0.43
0.19
0.70
0.33
0.47
0.94
0.39
0.
0.
0.
4.
0.
0.
0.
0.
0.
433.
2.
1.
0.
40
95
23
06 4.06
33
44
28
27
77 0.77
18 433.18
03 2.03
11 1.11
75 0.75
0.000
0.861
0.
865
0.867
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
868
876
879
881
888
891
894
920
925
932
951
962
969
978
001 37C1-TCDD SOR1
018
024
032
Triangle Laboratories, Inc.® Analytical Services Division
to! Capitola Drive • Durham, North Carolina 27713
hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:10 10/20/97
-------
Page No.
10/20/97
Listing of S976760B.dbf
Hatched OC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
328
13C12-TCDD
332-334
N
332-334
PeCDF
340-342
340-342
13C12 -PeCDF
352-354
352-354
PeCDD
356-358
22:04
22:11
22:17
DC SN 22:26
DC SN 22:30
DC SN 22:34
22:46
10 Peaks
DC NL 0:00
DC HL 18:55
DC WL 19:
19:
20:
21:
21:
21:
22:
22:
07
30
59
13
35
53
08
20
0.
RO
RO
RO
RO
RO
RO
65-0.89
1.75
1.49
1
0
0
0
0
1
'l
0
7 Peaks
DC NL 0:
DC SN 22:
DC SN 26:
DC WH 26:
00
36
41
51
1.
RO
RO
RO
.16
.62
.83
.78
.77
.56
.34
.86
1,
1
0
0
0
0
0
0
445
1
1
1
1
954
537
10
1
1
1
507
nw*T\
.82
.69
.70
.24
.19
.23
.51
.62
.12
.19
.88
.47
.13
.06
.45
.84
.20
.10
.25
T\ 1
32-1.78
1
0
0
0
.66
.68
.07
.31
0 Peaks
DC NL 0:
DC SN 22:
DC SN 22:
23:
24:
24:
25:
DC SN 25:
25:
25:
26:
DC SN 26:
26:
DC SN 26:
00
46
55
49
21
44
02
16
29
53
13
18
30
41
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
0
0
0
0
.09
.35
.13
.15
.00
1
0
0
0
0
432
235
4
1
0
0
.82
.69
.70
.51
.64
.52
.21
.55
.62
.91
.51
0.
1.03
521.61
301.85
5.90
1.04
0.68
0.59
1.040
1.046
1.050
1.057
1.060
1.064
1.073
906-1.094
0.000
0.892
0.901
0.919
0.989 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.017
1.031
1.043
1.053
32-1.78
0
1
0
1
1
1
0
0
1
0
0
0
1
0
8 Peaks
DC NL 0:00
1.
RO
.86
.36
.59
.42
.02
.55
.70
.23
.48
.93
.92
.67
.99
.59
1,
0
0
0
28
3
544
6
0
512
2
1
0
2
0
102
I*/™**
32-1.78
1
.91
0
.31
.59
.38
.95
.54
.97
.66
.39
.36
.04
.12
.71
.45
.39
.09
V /
f I
.28
16
2
331
4
305
1
0
1
.99
.15
.34
.05
.91
.24
.68
.91
0.
0.
11.96
2.11
213.63
5.75
206.45
1.34
0.74
0.96
908-1.080
0.000
0.914
1.079
1.086
838-1.162
0.000
0.920
0.927
0.963
0.985
1.000 13C12-PeCDF 123 IS2
1.012
1.022
1.030 13C12-PeCDF 234 SOR2
1.046
1.060
1.063
1.071
1.079
0.
921-1.027
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:10 10/20/97
226
-------
page No.
10/20/97
Listing of S976760B.dbf
Matched GC Peaks / Ratio / Ret. Time
compound/
H 2 CC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Confound.Name.. ID.. Flags.
356-358
13C12-PeCDD
368-370
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
NL
SN
SN
24
24
24
24
24
25
25
26
26
:07
:15
:43
:48
:57
:49
:57
:18
:39
RO
RO
RO
RO
RO
RO
RO
RO
0
0
4
0
0
1
4
2
6
.38
.79
.25
.33
.54
.38
.25
.67
.33
Peaks
0:00
24:13
1
RO
RO
24:29
24:45
DC
SN
25:05
RO
RO
25:52
26:00
26:11
368-370
HXCDF
374-376
374-376
13C12-HXCDF
384-386
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
4
NL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
NL
26:32
RO
RO
0
0
0
0
0
0
0
0
0
0
.30
.49
.20
.12
.21
.81
.20
.31
.38
.00
.32-1.78
1
.00
0.87
1
.55
0.97
4.40
1.42
1.40
0.89
0.83
Peaks
0:00
27:14
1.
RO
RO
27:23
27:30
27:
27:
28:
28:
28:
28:
28:
28:
28:
28:
29:
29:
29:
40
45
04
13
25
30
36
43
53
56
17
22
34
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
29:35
29:
29:
29:
30:
44
51
57
07
RO
RO
RO
.05-1.43
1.83
0.
1.
0.
41
06
50
0.21
1.63
4.17
2.27
1.
0.
1.
0.
3.
0.
0.
3.
0.
1.
1.
0.
3.
2.
31
38
29
65
67
40
89
88
77
20
22
95
44
54
Peaks
0:
00
0.
0
.16
0.33
0.51
1.14 0.69
0.38
333.30 195.54
40.87 23.87
0.90 0.55
0.58
0
0
0
0
0
0
1
1
1
.932
.938
.956
.959
.965
.998
.003
.017
.030
0.845-1.155
0
.000
0.936
0
.947
0.71 0.957
0.970
137.76 1.000 13C12-PeCDD 123 IS3
17.00 1.005
0.62 1.012
1.
.026
376.21
0.27
0.13
0.35
0.09
0.05
0.18
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
13
34
60
20
32
23
07
07
14
18
18
11
40
38
20
29
00
43-0.59
0.
48
0.
37
0.957-1.054
0.
.000
0.956
0.961
0.
965
0.971
0.974
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
985
990
997 123478-HxCDF AN
000 123678-HxCDF AN
004
008
013
015
027
030
1.037
1.
1.
1.
1.
1.
038
043
047
051
057
0.860-1.140
0.
000
tangle Laboratories, Inc.® Analytical Services Division
Capitola Drive • Durham, North Carolina 27713
19) 544-5729 • Fax: (919) 544-5491
Printed: 19:10 10/20/97
227
-------
Page Mo.
10/20/97
Listing of S976760B.dbf
Hatched GC Peaks / Ratio / Ret. Tine
Compound/
H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
384-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
8
ML
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
6
27:23
27:31
27:41
27:50
27:58
28:11
28:24
28:30
28:48
29:01
29:23
29:33
29:38
29:45
29:58
30:08
30:14
30:21
Peaks
0:00
27:48
27:53
28:15
28:25
28:30
28:42
28:48
29:02
29:13
29:16
29:31
29:33
29:39
Peaks
0:00
28:22
28:30
28:37
29:09
29:13
29:31
29:53
30:02
Peaks
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
RO
RO
RO
RO
RO
0.64
0.51
0.56
2.35
2.31
1.28
0.49
0.49
0.76
0.49
0.16
0.31
1.22
0.51
1.42
0.25
0.13
1.14
.05-1.43
0.53
1.67
1.36
1.58
3.67
1.18
1.43
0.23
1.83
0.88
0.21
1.05
0.38
1.09
.05-1.43
1.00
1.09
0.50
1.47
1.15
1.27
1.23
0.65
1.01
4
10
0
0
0
0
400
537
4
476
0
1
0
370
1
0
0
0
.42 1.87
.41 3.52
.42
.26
.24
.44
.38 131.22
.44 176.06
.26 2.14
.23 157.48
.59
.15
.35
.81 124.84
.89 1.77
.92
.56
.66
2.93
6.89
269.16
361.38
2.82
318.75
245.97
1.25
0
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
.961
.965
.971
.977
.981
.989
.996 13C12-HXCDF 478
.000 13C12-HXCDF 678
.011
.018 13C12-KXCDF 234
.031
.037
.040
.044 13C12-HXCDF 789
.051
.057
.061
.065
SUR3
IS4
ALT2
ALT1
1,805.84
• KxCDF / HxCDD Follows — — —
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
316
436
651
1
1
1,409
.16
.07
.26
.27
.20
.37
.17
.13
.52
.13
.07
.39
.11
.23
.00
.18
.48
.38
.61 2.36
.13 168.83
.07 244.00
.26 359.44
.17 0.65
.48 0.82
.72
0.
0.
1.61
147.30
192.07
291.82
1.00
0.81
951-1.016
0
0
0
0
0
0
0
0
0
1
1
1
1
1
.000
.952
.954
.967
.973
.975
.982
.986
.994
.000 123678-HXCDD
.002
.010 123789-HXCDD
.011
.015
AN
AN
966-1.034
0
0
0
0
0
1
1
1
1
.000
.971
.975
.979
.998 13C12-RXCDD 478
.000 13C12-HXCDD 678
.010 13C12-BXCDD 789
.023
.028
SOR4
IS5
RS2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:10 10/20/97
228
-------
page No.
10/20/97
Listing of S976760B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why . .RT. OK Ratio ToCal.Area.. . Area.Peak.1. . Area. Peak. 2. . Rel.RT Compound. Name.. ID.. Flags.
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13012-HpCDD
436-438
436-438
OCDF
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
WH
WH
0
NL
SN
4
NL
WL
SN
WH
0
NL
3
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:00
31:36
32:07
32:12
32:32
32:44
33:03
Peaks
0:00
31:14
31:58
32:29
32:47
32:59
Peaks
0:00
31:22
31:56
32:29
Peaks
0:00
31:29
32:06
32:27
Peaks
0:00
31:54
32:06
32:22
32:55
33:34
33:58
34:26
34:36
34:39
34:55
35:22
0
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
0.
RO
RO
RO
----- ADOVB:
.88-1.20
3.20
2.19
0.30
6.80
5.91
2.48
0.69
.37-0.51
1.24
0.42
0.97
0.40
0.91
1.37
88-1.20
1.00
0.58
0.36
1.44
raa-ij
0
0
0
0
0
0
0
0
u / npi-ue follows •
.20
.33
.16
.10
.22
.43
.49
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0.996
0
1
1
1
1
1
1
-1.047
.000
.012
.028
.031
.042
.048
.058
0.936-1.128
0
287
0
206
2
.30
.22 84.80
.42
.47 58.68
.16 1.37
1.20 1.14
0
202.42 1
1
147.79 1
.000
.000 13C12 -HpCDF 678 IS6
.023
.040 13C12 -HpCDF 789 SUR5
1.50 1 . 050
0.83 1
.056
497.05
0.36
0.29
0.29
0.51
0.978-1.007
0.000
0.977
0.
,995
1.012
0.00
0.
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
88-1.20
2.62
1.05
0.99
1.69
76-1.02
1.19
1.71
0.11
0.94
1.56
0.57
2.00
4.86
1.10
1.71
0.55
1.29
0.969-1.031
0.27
4.48 2.29
335.57 166.78
2.14 1.77
342.19
0.
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168.79 1.
1.05 1.
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981
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0.884-1.116
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0.
0.
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26
06
33
64
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11
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40
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40
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0.
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0.
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1.
1.
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928
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022
Bangle Laboratories, Inc.® Analytical Services Division
01 Capftola Drive • Durham, North Carolina 27713
'"one: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:1010/20/97
229
-------
Page No.
10/20/97
Listing of S976760B.dbf
Matched GC Peaks / Ratio / Rec. Tine
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
442-444
DC SN 35:47 RO 0.51
0 Peaks
0.64
0.00
1.034
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
IX
DC
DC
DC
DC
NL
SN
SN
0
ML
WH
1
0:00
34:36
34:54
Peaks
0:00
34:36
35:08
Peak
0.
RO
RO
0.
RO
RO
76-1.02
0
1
0
.90
.83
.29
.76-1.02
1
0
1
.22
.88
.38
0.19
0.57
0.25
0.00
0.17
411.73
1.38
411.73
192.15
0.884-1.116
0.000
1.000 OCDD AN
1.009
0.998-1.007
0.000
219.58 1.000 13C12-OCDD IS8
1.015
Column Description "Why" Code Description QC Log Desc.
H_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mn:ss)
Rat.l -Ratio of M/M+2 Ions
OK -ROsRatio Outside Limits
Rel.RT-Relative Retention Time
Fnd of Report
WL-Below Retention Tin* Window
WH-Above Retention Tin* Window
SH-Below Signal to Boise Level
-------
Tile:S976760 #1-829 Acq:16-OCT-1997 23:29:19 EH- Voltage SIS 70S Koiae:290
303.9016 F:2 BSUB(256,30,-3.0) PKD(9,5,5,O.OS\,1160.0,1. 00*,T,T) Exp-.EPCUS
TRIANGLE LASS Text:M23 THERMAL OUTLET RBI TLI#43431 JK7. TIME - 23:32
100*
so:
60:
40:
20:
17:00 18:00 19:00 20:00 21:00
file:S976760 #1-829 Acq:16-OCT-1997 23:29:19 EI+ Voltage SIR 70S JToiae:363
305.8987 F:2 BSUB(2S6,30,-3.0) PXD(9,5,5,0.05\,1452.0,1.00*,r,T) Exp:EPCUS
TRIANGLE LASS TextiM23 THERMAL OUTLET RSI TLH43431 INJ'. TIME - 23:32
10K
80:
60:
22: 00
40:
20:
17:00 13:00 19:00 20:00 21:00
Tile:S976760 #1-829 Acq:16-OCT-1997 23:29:19 EH- Voltage SIS 70S Soiae:279
315.9419 Ti2 BSUS(256,30, -3.0) PIO>(9,5,5,0.05\,1116.0,1.00\,T,T) EiptEPCUS
TRIANGLE LASS TextiM23 THERMAL OUTLET RSI TUf43431 XK7. TIME - 23:32
22:00
1001
80:
60:
40:
20:
ol
A2.
17-00 10>00 15:00 20-00 21:00
rile:S976760 #1-829 Acq:16-OCT-1997 23:29:19 EH- Voltage SIR 70S Noiae:344
317.9389 T-.2 BSUB(2S6,30, -3.0) PKD(9,5,5,0.05\,1376.0,1.00*,r,T) Exp:EPCUS
TRIANGLE LABS Tezt:M23 THERMAL OUTLET RBI TLI#43431 INJ. TIME - 23:32
A4.Q3E6
22 too
80:
so:
40:
20:
o:
17:59
17:00 18:00 19:00 20:00 21:00
rile:S976760 #1-829 Acqsl6-OCT-1997 23:29:19 EI+ Voltage SIR 70S
330.9792 rs2 ElpsEPCUS
TRIANGLE LABS Text:M23 THERMAL OUTLET SSI TLH43431 INJ. TIME - 23:32
100\ 17:18
«-^w
80:
so:
40:
30:
0:
22:00
.6.5E5
.5.2E5
.3.9ES
.2.6E5
.1. 3E5
.O.OEO
Time
8.8E5
.7.0ES
.5.3E5
.3.5ES
_1. 8E5
O.OEO
Time
5.6E6
-4.5E6
.3.3E6
-2.2E6
-1.1E6
17:00 18:00 19:00 20:00
file:S976760 #1-829 Acq:16-OCT-1997 23:29:19 EI+ Voltage SIR 70S
375.8364 f:2 Ezp-.EPCUS
LABS Text:M23 THERMAL OUTLET RBI TLH43431
21:00
22: 00
O.OEO
Time
IXT. TIME -
23:32
231
-------
Tile:S976760 91-829 Acg:16-OCT-1997 23:29:19 EI+ Voltage SIS 70S Hoise:276
319.8965 F:2 BSUB(256,30, -3.0) PXD(7,5,3, 0. OS\, 1104.0,1.00\,r, T) Exp-.EPCOS
TSIAHSLE LABS Ttat:M23 THERMAL OUTLET RBI TU 94 3431 ItfJ. TIME - 23:32
1004
0 20:00 21:00 22:00
rile:S976760 91-829 Acq:16-OCT-1997 23:29:19 EI+ Voltage SIS 70S Soi.se-.300
321.8936 T-.2 BSUB(2S6,30,-3.0) PlO>(7tS,3rO.OS\,1200.0,1.00\tr,T) Sxp:EPCUS
TRIANGLE LABS Teit:M23 THERMAL OUTLET SSI TU 943431 XK7. TIME - 23:32
O.OEO
Time
*^J* _J
19100 20*00 21:00 22:00
FHeiS976760 91-829 Acgtl6-OCT-1997 23:29:19 EI+ Voltage SIS 70S No±*e:S48
331.9368 T-.2 SSVB(256,30, -3.0) ?KD(7,5,3,0.05\,2192.Q,1.00\,T,T) Exp:EPCOS
TSIAIOSLE LABS Tart:M23 THERMAL OUTLET SB1 TLH43431 IKJ. TIME - 23:32
1001 A4.33E6
SOJ
sol
40l
20-
.35S6
19:00 20s00 21:00 22:00
Til»tS976760 U-B29 AcqtlS-OCT-1997 23:39tl9 EH- Voltagv SIS 70S BO±M»i316
333.9338 T:2 BSUS(256,30, -3.0) PKD(7,5,3,O.OS\,1264.Q,1.00\,T,T) ZxpiEPCUS
TSZASSLE LASS Text:M23 THERMAL OUTLET SB1 TLH43431 XK7. TIME - 23:32
1002 A5.22E6
so
401
201
A3.02E6
19iOO 20:00 21:00 22:00
TilosS976760 91-829 Aeqtl6-OCX-1997 23:29:19 EI+ Voltage SIM 70S Koiaa:319
327.8847 T:2 BSUS(256,30,-3.0) PXJ>(7,S,3,O.OS\r1276.0,1.00\,T,T) ExpsEPOJS
TXIASSLE LABS Toit:M23 TBEXMAL OUTLET SB1 TLH43431 IXJ. TIKE * 23:32
1001 A4.33E6
80J
sol
40l
201
15:00 20:00 21:00 22:00
ril«:S976760 91-829 AojtlS-OCT-1997 23129:19 SX+ Voltage SIX 70S
330.9792 t:2 ZzptSPCUS
TSZAHGLE LABS TexttM23 TSESKAL OUTLET SSI TU443431 OCT. TIME * 23:32
1004 18,36 19.00 19:25 TO,« 20:07 . 20s48 21:23 21:44 . 22SJ.S 22:32
.1. 1E6
.8.6ES
.S.SES
.4.3E5
.2.2ES
.O.OEO
Time
.1. 3S6
.1. OE6
.7.7E5
.5.1E5
.2.6E5
.O.OEO
Time
.1 - OE6
.8.1ES
6.1ES
4.1E5
2.0ES
O.OEO
Time
18 1 36 19100 J.91^19, 45. *"""^^^ZiZZ~^-^JS?i£Z-fSi+J« •^•^J^U^^K^^f-^
' IStOO' ' ' ' 20:00 ^ 21«00 ' 22:00
F"«* • ******
.4.5E6
.3.3E6
.2.2E6
.1 . 1E6
.O.OEO
Time
232
-------
ttlesS976760 tl-829 Acq:16-OCT-1997 23:29:19 EI+ Voltage SIS 70S Noiae:339
339.8597 T-.2 BSUB(256, 30,-3.0) PXD(7,5,3,0 ,OS\,1356.0,1.00\,T,T) Exp-.EPCUS
TRIANGLE LABS Text:M23 TSERMAL OUTLET RBI TLI#43431 TK7. TIME - 23:32
.10 01
80:
60l
401
201
A2.81E3
43.34
I A891.96
4.SE3
.3.6E3
.2. 7E3
Ll. 8E3
-9.1E2
Q.OEO
23:00 24:00 25:00 26:00
rile:S976760 tl-829 Acq:16-OCT-1997 23:29:19 EI+ Voltage SIX 70S Soiae:207
341.8567 T:2 BSUB(2S6,30, -3.0) P1O)(7,5,3, 0.05%, 828.0,1.00\,T, T) Exp-.EPCUS
TRIANGLE LABS Text:M23 TSERMAL OUTLET RBI TLI#43431 IKT. TIME = 23:32
1001
aol
27:00 Tia
23:00 24:00 25:00 26:00
T±letS976760 tl-829 Acgtl6-OCT-1997 23,29:19 EI+ Voltage SIS 70S Soiaei93
351.9000 P:2 BSUB(2S6,30,-3.0) fXD(7,5,3,0.05\,372.0,1.00\,T,T) Erp-.EPCOS
TRIANGLE LASS Text:M23 THERMAL OUTLET R31 TZH43431 INJ. TIME * 23:32
1004 A3.31E6 A3.06E6
80:
COJ
40:
20:
o:
O.OEO
27:00 Time
-9.4ES
.7.6ES
.5.7ES
.3.8ES
.1.9E5
23:00 24:00 25:00 26:00
file:S976760 tl-829 Aoqsl6-OCT-1997 23:29:19 EH- Voltage SIR 70S Koine-.111
353.8970 Ti2 SSUB(256,30,-3.0) PKD(7,S,3,0.05\,444.0,1.00\,T,T) Elp-.EPCDS
TRIANGLE LABS Text:M23 TSERMAL OUTLET RBI TUf43431 HKT. TIME ' 23:32
1001
aol
201
A2.14E6
A2.
Q6E6
27:00 Tiae
6.1E5
.4.9E5
.3.6E5
-2.4ES
-1.2ES
I V_
23:00 24:00 25:00 26:00
rilesS976760 tl-829 Acq:16-OCT-1997 23:29:19 EI+ Voltage SIR 70S
330.9792 Ts2 Exp-.EPCUS
TRIANGLE LABS Text:M23 TSERMAL OUTLET R31 TLHH3431 HKT. TIME = 23:32
100* 23:09 23:42 24:14 . 24:56 25:20 25:46
v*">%^—/* • • ^
so:
40
2ol
ol
.O.OEO
27:00 Tiae
5.8E6
.4.7E6
.3.SE6
.2.3E6
-1.2E6
23:00 24:00 25:00
F±le:S976760 tl-829 Acq:16-OCX-1997 23t29sl9 XI+ Voltage SIR 70S
09.7974 T:2 Ezp-.EPCUS
TRIANGLE LABS Text:M23 TSERMAL OUTLET RBI XLIt43431 HKT. TIME
22 50
26: 00
23:32
.O.OEO
27-00 Tiae\
1001
80:
50:
401
o:
26:30
23:57
24:25
24:12
25:16
25:52
26:16
23't 08
23:25
24:49
23:
5.1E3
.4.1E3
.3.1E3
.2.0E3
.1. OE3
23:00
24:00
25:00
26:00
.0.0X0
27:00 T±mt
233
-------
FlJ.e:SS76760 #1-8.29 Acq:16-OCT-1997 23:29:19 EI+ Voltage SIS 70S Noise: 105
355.8546 T-.2 BSUB (256,30, -3. 0) PXD( 7,5, 3, 0.051,420. 0,1.00\,T, T) Exp:EPCUS
TRIANGLE LASS Text.-JGJ THERMAE OUTLET XB1 TLI#43431 XK7. TIME - 23:32
1001
241 00 25s 00 26:00
File:S976760 #1-829 Acq:16-OCT-1997 23:29:19 EH- Voltage SIS 70S Noise:57
357.8516 Ts2 BSUS(256,30,-3.0) PXD(7,5,3,0.OS\,226.0,1.00\,r,T) Elp-.EPCUS
TRIANGLE LASS Text:M23 THERMAL OUTLET SSI TLI#43431 IXJ. TIME • 23:32
1001
80.
50.
40.
20.
A9. 8E3
A4.68E3
24:00 25:00 26:00
File-.3976760 #1-829 Aoj:16-OCT-1997 23:29:19 EH- Voltage SIX 70S Koiae:50
367.8949 T:2 BSUB(2S6,30,-3.0) PKD(7,5,3,0.05\,200.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LASS T*Xt:M23 THERMAL OUTLET SSI TLH43431 HU. TIME - 23:32
1001 A1.96E6
so:
60.
40.
20.
.39E5
24:00 25:00 26:00
Tile-.5976760 #1-829 Aoq:16-OCT-1997 23:29:19 EI+ Voltage SIS 70S Xoia*:52
369.8919 T:2 BSUB(256r30, -3.0) PXD(7,S,3, 0.05\,208.0,1.00\,F,T) Exp-.EPCUS
TRIANGLE LABS Text:M23 THERMAL OUTLET SSI TLI#43431 TOT. TIME - 23:32
A1.3SE6
so:
so:
__^
^^,,^ ^ ^.^^ ^.^r^ v^nr-v ^v
24,00 ' ' ' 25tOO 26*00
rS.8E6
.4.7E6
.3.5E6
.2.3E6
.1.2E6
.O.OEO
Time
234
-------
•ile:S575750 #1-475 Aco;:16-OCT-15S7 23:25:15 EI+ Voltage SIX 70S Hoime:108
373.8208 F:3 BSUB(256,30f-3.0) Pn>(7,5,3r0.05\,432.0,1.00\,T,T) Exp:EPCUS
TRIASSLE LABS TextiM23 THERMAL OUTLET RBI TLI043431 IK7. TIMS - 23:32
1001
27:24 27-35'27:48 28:00 20:12 28:24'28.-35 28:40 25:00 25:12 25:24 25:35 25-48 30:00 30:12
rile:S976760 #1-475 Ac?:lS-OCT-1557 23:25:15 EI+ Voltage SIX 70S Xoife:61
375.8178 T:3 BSUB(2S6,30, -3. 0; PKD(7,5,3, 0.05%,244.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Text:K23 THERMAL OUTLET RBI TLH43431 OT7. TIME - 23:32
1001 A1.02E3
27:24 27:36 27:48 20:00 20:12 20:24 28:35 28:48 25:00 25:12 25:24 25:35 25:48 30:00 30:12
Tile:S976760 #1-475 Aog-:15-OCT-1557 23:25:15 EZ> Voltage SIR 70S Soiae:59
83.8639 f:3 SSOB(256r30,-3.0) PXD(7,S,3,O.OS\,236.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS T«xtiK23 THERMAL OUTLET RBI TLH43431 Utt. TIME - 23:32
1001
00:
40:
20:
O.OEO
TJJti
O.OEO
Tio,
5^5
A1.57E6
27:24 27:35 27:40 28:00 28:12 28:24 28:35 28:40 25:00 25:12 25:24 25:35 25:40 30:00 30:12
KleiS976760 #1-475 Acysl6-OCT-1997 23:29:19 EH- Voltage SIX 70S Koiae:126
85.8610 T:3 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,S04.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Text:X23 THERMAL OUTLET RBl TLH43431 HKT. TIME * 23:32
1001 A3. (
so:
sol
40:
20:
0.
A3.19E6
A2.46E6
27:24 27:36 27:48 28:00 28:12 20:24 28:36 20:40 25:00 25:12 25:24 25:35 25:40 30:00 30:12
rile:S976760 #1-475 Acg:16-OCT-1557 23:25:15 Eli- Voltage SIR 70S
'92.9760 t:3 ExptEPCUS
TRIANGLE LABS Teit:M23 THERMAL OUTLET RBI TLH43431 HU. TIME - 23:32
1001^ 27-27 27:42 20:04 20.: 17 28/31 28:51 25:07 25j2S .25/42 25:58
80:
«0:
40:
20:
0:
.4.2E5
.3.1E5
.2.1E5
.1. OES
.O.OEO
Time
.1. OES
8.3E5
6.3E5
4.2E5
2.1E5
O.OEO
Time
.2.9E6
.2.3E6
.1.7E6
J..2E6
5.8ES
O.OEO
27:24 27:36 27:48 28:00 28:12 20:24 20:35 20:40 25:00 25:12 25:24 25:35 25:40 30:00 30:12
*ila:S576760 #1-475 Acg:15-OCT-1557 23:25:15 EI+ Voltage SIX 70S
l*t< Tfff ^ 4 •mm ._ _ -
"*• '555 f"3 Ex&tEPGXtS
TSIANGLE LASS TeXt.-M23 TSERMAL OUTLET SB1 TLH43431 TJKT. TIME ' 23:32
iOO\ 27 46
28:35
so:
Jo:
27:30
20:14
28:50 |
MjLWk-
25:. 9
29:59
5.1X3
1.4.1*3
L3.ir3
6:
27s24 27:36 27:48'20s00 '20:12'28:24' 20:35' 20:40'25:00' 25:12' 25^24 '25:36' 25:48'30jOo'Jbiij'
.2.0Z3
LI.013
Lo.oco
Time
235
-------
J.e:sy/o/oo (7,5,3,0.05\,200.0,1.00\,r,T) ExptEPCUS
TRIANGLE LABS Tezt.:M23 THERMAL OUTLET SSI TLI143431 UKT. TIKE - 23:32
1004 A3.?9E6
O.OEO
29:36 29:48 30:00 Time
80.
60.
401
20.
A2.44E6
1. OE6
.8.1E5
'.6.0E5
.4. OE5
.2.0ES
27*48 28:00 28*12 28*24 28*36 28*48 29*00 29:12 29*24 29*36 29:48
Tile:S9767SO tl-475 Acq:16-OCT-1997 23:29*19 EI+ Voltage SIS 70S HOiae*49
403.8529 T*3 BSUB(256,30r-3.0) PXD(7,5,3,0.05\,196.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Te*t*M23 THERMAL OUTLET RBI TLH43431 INJ. TIME - 23:32
100\ A2.92E6
30:
.O.OEO
00 Time
80.
60.
40.
20.
A1.92E6
8.4E5
.6.7ES
.5.0E5
.3.3ES
.1. 7E5
O.OEO
27*48 28:00 28:12 28:24 28*36 28:48 29:00 29:12 29*24 29*36 29:48
Tile*S976760 tl-475 Acqsl6-OCT-1997 23*29*19 EI+ Voltage SIS 70S
392.9760 T*3 XxptEPCUS
TRIANGLE LABS T«Xt:K2J THERMAL OUTLET RBI TLX943431 XK7. TIME ' 23*32
60.
40.
20.
30:00 Time
-2.9E6
.2.3E6
.1. 7X6
.1.2E6
.5.8S5
27:48 28:00 28:12 28:24 28:36 28:48 29iOO 29:12 29:24 29:36 29:48
30:
O.OEO
00 Time
236
-------
Tile:S976760 11-397 Acg:16-OCT-1997 23i29:lS EH- Voltage SIX 70S Noise:161
407.7B18 T:4 BSUS(256,30,-3.0) PKD(7,5,3,0.OS%,S44.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LASS Text:M23 TSESMAL OUTLET RSI TLH43431 TK7. TIME * 23:32
1001
80.
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
rile:S976760 fl-397 Acq:16-OCT-1997 23:29:19 EI+ Voltage SIS 70S Noise-.4 9
409.7789 T:4 SSUS(256,30,-3.0) PKD(7,5,3, 0.05%, 196.0,1.00\,T,T) Erp-.EPOJS
TRIANGLE LASS Teit:M23 THERMAL OUTLET RSI TLH43431 I7K7. TIME " 23:32
1001
BO:
32:48
33:00 Tim
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
file:S976760 fl-397 Aeq:16-OCT-1997 23:29:19 EI+ Voltage SIS 70S Koiae:132
417.8253 T:4 SSUS(256,30,-3.0) PXD(7,5,3,0.051,528.0,1.00\,r,T) Exp:EPCOS
TRIANGLE LASS Teit:M23 THERMAL OUTLET RSI TLH43431 IKJ. TIME - 23:32
32:48
ion
A8.48ES
AS.87E5
.O.OEO
33:00 Time
2.3E5
ll.9E5
Ll. 4E5
•.9.3E4
•.4.6E4
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
Tile:S976760 tl-397 Aog:16-OCT-1997 23:29:19 EH- Voltaya SIS 70S Soiso:104
419.8220 T:4 BSOB(256,30,-3.0) PXD(7,5,3,0.05\,416.0,1.00\,T,T) Exp:EPCDS
TRIANGLE LASS Text:M23 THERMAL OUTLET SSI TLH43431 UKT. TIME * 23:32
A1.48E6
32:48
•.O.OEO
33:00 Time
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
file:S976760 fl-397 Acq:16-OCT-1997 23:29:19 EH- Voltage SIS 70S
430.9729 Ti4 ExptEPCUS
TRIANGLE LASS Taxt:M23 THERMAL OUTLET SSI TLIf43431 INJ. TIME « 23:32
31:44 31iS2^ 32:16 3_2s25 32*34 J2:41
80:
eo:
40:
20:
0.
5.3ES
•.4.3E5
•.3.2E5
'.2.1E5
'.LIES
32:48
32:52
33:00 Time
2.1E6
.1. 7E6
.1.3E6
.S.5E5
.4.2ES
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
tiletS976760 fl-397 Aeq:16-OCT-1997 23:29:19 EH- Voltage SIS 70S
179.7165 r:4 Eip:EPCUS
LASS Text:M23 THERMAL OUTLET RSI TLI*43431 X1K7. TIME - 23:32
ion
80:
so:
to:
30:
0:
32:48
.0.0X0
33:00 Time
31:12
31:24
31:36
31:48
32: 00
32:12
32:24
32:36'
32:48
-4.4E3
.3.5E3
'.2.6E3
-.1.7E3
-.8.7E2
'O.OEO
33:00 Time
237
-------
tl-397 Acq:16-O&F-l997 33:39:19 la1* Voltage StX 70S
423.7766 f:4 BSUB(2S6,30,-3.0) PXD(7,5,3,0.OS\,352.0,1.00\,f,T) ExpiEPCOS
TRIANGLE LASS Text:M23 THERMAL OUTLET RBI TLH43431 ItKT. TIME - 23:32
a 001
31 .-30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
K10SS976760 tl-397 Aoj:16-OCT-1997 23:29:19 tl+ Voltage SIS 70S Boi*e:91
425.7737 f:4 BSOB(2S6,30,-3.0) tO)(7,5,3,0.05\,364.0,1.00\,f,T) ExpiEPCOS
TRIANGLE LASS T«rt:M23 TtOSHKL OUTLET MSI TZH43431 HKT. TIME * 23:32
A4.15E3 A4.15E3
32:24 32:30 32:36
.O.OEO
Time
31t24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24
rile:S976760 tl-397 Aoqsl6-OCf~1997 23:29:19 EH- Voltage SIS 70S Soia*sl72
435.8169 r:4 BSDB(2S6,30,-3.0) PXD(7,5,3,0.05\,688.0,1.00\,f,T) ExptEPCOS
TRIANGLE LASS Toit.:H23 TSZSHML OUTLET SSI TLH43431 HKT. TIME - 23:32
1003
80.
60.
40.
20.
A1.67E6
O.OEO
32:30 32:36 Time
-3.2ES
12.6ES
-1.9ES
".1.3ES
-6.4E4
10.0EO
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
F±le:S976760 tl-397 Acq: 16-OCT-1997 23:29:19 EI+ Voltage SIS 70S Koi.ae-.67
437.8140 F:4 BSm(2S6,30,-3.0) PXD( 7,5, 3,0. 051,268. 0,1.00\,e,T) Ezp:EPCDS
TBIASGLX LASS Text:M23 TffCTmr, OUTLET SB1 TLIf43431 IJKT. TIME • 23:32
1004 A1.&9E6
80.
60.
40.
20.
32:24 32:30 32:36
Time
.2.5E5
'.1. 9ES
.1. 3ES
.6.3E4
O.OEO
31:24 31 1 30 31:36 31t42 31148 31:54 32:00 32:06 32112
Tilt:S976760 tl-397 Aeq:16-OCX-1997 23:29:19 ZI+ Voltage SIS 70S
430.9739 r:4 Zxp:ZPCOS
LABS T*zt:K23 f*rffM»T. OUTLET SSI TLH43431 XK7. TIME ' 23:32
32:24 32:30 32:36
lime
80.
60.
40.
30.
0.
32^34 2.1E6
.1 . 7E6
.1.3E6
.8.5E5
.4.2E5
O.OEO
'31:24 ' '31130 ' 31:36 31s42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32:36 Ziae
238
-------
Tile:S976760 #1-397 &cq:16 <-Od- 1997 23:29:13 EI+ Voltage SIX 70S KoLae:fS
441.7420 T:4 BSVB(256, 30, -3.0) PXD(7,5,3,0. 05\,384. 0,1. 00*,T,T) EzpsEPCUS
TRIANGLE LABS TextiM33 THERMAL OUTLET RBI TLH43431 Ijrjr. TIME - 33:32
90.
801
701
S0-
50-
40.
30J
301
101
A4.93E3
_ Jl .A
A3.32E3
JL-*.
A3.94E3
A3.04E3
-2.7E4
12.4E4
''.2.1E4
':!. SE4
':!. 6E4
.1.3E4
L1-IT4
.B.OE3
.S.3E3
.2.7E3
31 00 32:00 33:00 34:00 35:00
TileiS976760 §1-397 Aoqtl6-OCX-1997 23:39:19 EI+ Voltage SIS 70S Koiae:78
443.7399 *:4 BSOB(2S6,30,-3.0) PKD(7, 5,3,0. OS\,312.0,1.00\,F,T) Exp:EPCVS
TRIANGLE LABS Teit:M23 THERMAL OUTLET SB1 TLIt43431 IKT. TIKE - 23:32
o.oxo
Tim
901
80.
701
601
501
401
301
301
101
-1.9E4
11. 7E4
.1.5X4
'.1.3X4
.1.2X4
.9.6X3
.7.7X3
.5.8X3
'.3. 8E3
A3.43E3
A4.12E3
-A»»_/-j|A—A-A/Au_A_ A-
AS.87S3
fc . II ,
11.9S3
1 00 32:00 33:00 34:00
r±l*>S976760 tl-397 Aeqt 16-OCT-1997 23:29:19 EX+ Voltage SIS 70S
430.9729 T*4 ExpiEPCUS
TRIANGLE LABS Tezt:H23 ftmtn-r. OUTLET B31 TLII43431 UKT. TIME
35:00
O.OEO
Time
23:32
31 00 32JOO 33:00 34:00
Tile-.3976760 tl-397 Aoq:16-OCT-1997 23:29tl9 EH- Voltage SIX 70S
13.6775 T:4 SzptEPCOS
TSIANGLE LABS Text:M23 TBEBMAL OOXLET JZS1 TLH43431 TXJ. TIME - 23:33
00* 31 17
901
801
70J
50.
50J
40J
301
201
101
35:00
Mv.
32:04
33:10
33:40
1:46.
32138
34:12
33tOOl
33:3.
34:
34 n
3St47
33:17
31 00
32tOO
33 tOO
.O.OEO
Time
7.0X3
.6.3S3
.5.6E3
.4.9E3
.4.2E3
.3.5X3
.2.8X3
.3.1X3
.1.4X3
.7.0X2
O.OEO
34s 00
35s 00
239
-------
file:g976760 il-357 Acq:lS-ocf-1997 23-.2S-.LS U+ Voltage sis 70s tfoise:43
457.7377 T:4 BSUB(256, 30, -3. 0) PXD(7,S,3,0.05\,172.0,1.00\,r,T) ExpiEPCUS
TRIANGLE LASS Teit:M23 THERMAL OUTLET RBI TLIf43431 UKT. TIKE - 23s32
iOO\ A3.07E3
80.
60.
40.
20.
A5.47E3
34s30 34:36 34:42 34:48 34:54 35:00
T±le:S976760 tl-397 Aeg:16-OCT-1997 23:29:19 EH- Voltage SIS 70S Noiae:49
459.7348 r:4 BSUB(2S6,30,-3.0) PXD(7,5,3, 0.05\,196.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS Text:X23 THERMAL OUTLET RSI TLIf43431 INT. TIME - 23:32
100* A4.24E3
35:06
.2.2E3
.1. 7E3
.1.3E3
.B.7E2
.4.3E2
.O.OEO
Time
34:30 34:36 34:42 34:48 34:54 35:00
Tile:S976760 tl-397 Acq:16-OCX-1997 23:29:19 EH- Voltage SIR 70S Soiae:55
469.7779 T:4 SSUB(256r30, -3.0) PXD(7,5,3, 0.OS\,220.0,1.00\,T,T) ExptEPCUS
TRIASSLE LABS Text:M23 THERMAL OUTLET RBI TLH43431 HTJ". TIME - 23:32
35:06
1003
80.
60.
40.
20.
A1.92E6
34:30 34:36 34:42 34:48 34:54 35:00
rile:S976760 tl-397 Aoq:16-OCT-1997 23:29:19 XI+ Voltage SIS 70S Xbiae:45
471.7750 T:4 BSUB(256,30,-3.0) PXD(7,5,3,0.05\.180.0,1.00\,r,T) Ezp:EPCUS
TSIASGLE LABS Text:M23 THERMAL OUTLET SB1 TLH43431 IJU. TIKE - 23:32
A2.20X6
35:06
2.2E5
1.8ES
1.3ES
B.9E4
4.5E4
O.OEO
Time
34:30 34:36 34:42 34:48 34:54 35:00
rile:S976760 tl-397 Act?: 16-OCT-1997 23:29:19 EH- Voltage SIS 70S
430.9729 Tt4 SxptEPCUS
TSIABSLE LABS Taxt:H23 THERMAL OUTLET XB1 TLH43431 OCT. TIKE • 23:32
ion
80
60
40
20.
0.
35:06
.1.9E5
_1 . 4E5
^9 . 3E4
0 . OEO
Time
2.1E6
'.1 . 7E6
.1.3E6
'.8 . 5E5
.4.3ES
34:30
34:36
34:42
34:48
34:54
35:00
35:06
O.OEO
Tine
240
-------
Ref, iass 232,3825 Peak top
Height ,82 wits Span 290 ppi
Systei file nate
Data filenaie
Resolution
lonlzation nde
Pitching
Ref, lasses 232,3825,
fl 293 J 331
B 384
C 386
0 316
E 318
F 328
6 322
H 32S
K 332
L 334
I 348
H 342
0 362
P 354
fl J5R2
R 358
EKUS
fl:S976756
2
El*
VOLTflGE
416,3768
S 368
T 378
U 376
V 418
Channel I 338.37S2 Peak top
Height ,68 volts Span 288 ppi
241
-------
SI laitUtt Resea rch G ro u p
"•>"•, 0: ..O' - - .. S"i~ *^fZ
TLI Project: 43431
Client Sample: CleanUp Blk
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S976761
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Asphalt Roofing Project
XAD Date Received:
TLI Clean-Up Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
II
10/01/97
10/17/97
n/a
S976745
MS
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976754
n/a
n/a
n/a
*W"**^&£,
2^,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
!A3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
23,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1^,3,4,6,7,8,9-OCDF
^IW*i-,^ ,-,' '/^
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
^'/^Amt^ai
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
EMPC
ND
ND
ND
ND
,-.> >g£&'-j&tn£ •'ft)]
ND
ND
ND
ND
ND
ND
EMPC
ND
a ^v "at. ^ £«PC
0.002
0.003
0.004
0.003
0.003
0.004
0.007
0.001
0.002
0.002
0.002
0.002
0.006
0.003
0.003
0.004
0.005
j) ffombef ;&t &&&&-, '?
0.002
0.003
0.003
0.004
0.001
0.002
0.006
0.003
/ tiitfkiij fff % Ffegs
f f f.
—
.^^_
____
—
Page 1 of 2
X237J>SR T2JXJ. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:1610/21/97
242
-------
TLI Project:
Client Sample:
43431
CleanUp Blk
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S976761
Internal Standards.^
3C,2-2,3,7,8-TCDF
3C,2-2,3,7,8-TCDD
3CI2-l,2,3,7,8-PeCDF
3d2-l,2,3,7,8-PeCDD
3C,2-12,3,6,7,8-HxCDF
3C12-l,2,3,6,7,8-HxCDD
13Ci2-123,4,6,7,8-HpCDF
'3C,2-l,23,4,6,7,8-HpCDD
3C,2-12,3,4,6,7,8,9-OCDD
Alternate Standards (Type -
13C,2-l,2,3,7,8,9-HxCDF
13C12-2,3,4,6,7,8-HxCDF
Recovery Standards
3CI2-12,3,4-TCDD
13Ci2-12,3,7,8,9-HxCDD
<,^*n&Ms}^^
2.8
2.8
2.6
15
32
3.1
3.0
3.0
5.8
^;awt>M^V' ~
3.1
33
^' ,4^, ^^ >.
*,*!&. *3^***T?'
71.1
70.0
66.1
62.0
80.5
77.0
73.9
75.0
72.6
% Recovery
78.6
81.5
>.*.,*. ,
X QC Lfmits
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%- 130%
25%-130%
25%-130%
25%-130%
r seumifs.
40%-130%
40%-130%
_ Ratio ,
0.74
0.79
1.48
1.41
0.50
120
0.42
0.98
0.86
V ; Balle
0.50
0.50
Ratk>
0.81
120
. , , jrr,
20:24
21:12
24:43
25:51
28:29
29:13
31:13
32:05
34:35
ij 'inu;
29:44
29:00
irr
20:59
29:30
'»P
_
„ ffegs
—
-^sbgs
Data Reviewer
10/21/97
Page 2 of 2
X237.PSR T2.CXX LARS 6.10.04
^Jangle Laboratories, Inc.®
"01 Capltola Drive • Durham, North Carolina 27713
|lhone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:16 10/21/97
243
-------
Initial
---- Dace —
Data Review By:
r- i£/fA
Calculated Noise Area:
0.29
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/21/97
Listing of S976761B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
3O4-306
13C12-TCDF
316-318
316-318
TCDD
320-322
D
D
320-322
13C12-TCDD
332-334
332-334
PeCDF
34O-342
DC
DC
DC
DC
d
DC
d
DC
DC
.
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
0
KL
3
NL
SN
SN
SN
SN
SN
0
NL
5
NL
SN
SN
SN
SN
SN
SN
SN
SN
0:
17:
00
12
0.
RO
65-0.89
0
0
.78
.64
Peaks
0:
19:
20:
20:
00
56
24
55
0.
RO
RO
RO
0.89
0.83
0.00
65-0.89
0
0
0
0
Peaks
0:
18:
18:
18:
18:
18:
00
16
36
45
50
S3
0.
RO
RO
RO
RO
.61
.49
.74 1
.58
1
65-0.89
0
1
0
0
1
0
.89
.71
.24
.83
.37
.27
Peaks
0:
19:
20:
21:
21:
21:
00
54
59
12
35
58
0.
RO
RO
1.06
6.87 2.99
,636.09 698.48
10.53 4.58
,653.49
1.04
1.03
0.34
1.19
0.53
0.46
0.00
65-0.89
1
0
0
0
0
0
Peaks
0:
23:
23:
24:
24:
24:
24:
24:
00
33
52
08
17
24
33
43
24:45
1.
RO
RO
RO
RO
RO
RO
RO
RO
.75
.56
.81 1
.79 1
.73
.77
3
32-1.78
0
1
1
0
1
0
0
0
0
.63
.31
.33
.71
.18
.65
.29
.18
.38
1.13
5.40 2.35
,746.38 781.56
,303.29 573.84
27.85 11.73
1.17 0.51
,084.09
0.28
0.28
0.56
0.28
0.33
0.46
0.16
0.12
0.2t>
0.826-1.103
0.
0.
000
843
0.951-1.049
0.
6.11 0.
937.61 1.
7.95 1.
000
977
000 13C12-2378-TCDP ISO
025
0.858-1.060
0.
0.
0.
0.
0.
0.
000
862
877
884
888
891
0.906-1.094
0.
4.20 0.
964.82 0.
729.45 1.
16.12 1.
0.66 1.
000
939
990 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
018
036
0.908-1.080
0.
0.
0.
0.
0.
0.
0.
1.
1.
000
953
966
976
982
987
993
000
001 12378-PeCDP AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:16 10/21/97
244
-------
page No.
10/21/97
Listing of S976761B.dbf
Matched OC Peaks / Ratio
/ Ret. Time
Compound/
M_Z QC.Log Oniit Why . .RT. OK Ratio Total.Area... Area. Peak. 1. . Area. Peak. 2. . Rel.RT Compound. Name.. ID.. Flags.
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
D
356-358
13C12-PCCDD
368-370
368-370
DC
DC
.DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
WH
0
NL
SN
6
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
5
24:50
25:02
25:11
25:19
25:26
25:34
26:02
26:48
Peaks
0:00
24:21
24:43
25:02
25:09
25:16
25:30
26:30
Peaks
0:00
24:10
24:19
24:33
24:43
25:09
25:18
25:27
25:38
25:41
26:11
26:19
26:30
Peaks
0:00
25:51
26:00
26:11
26:19
26:38
26:48
Peaks
RO
RO
RO
RO
RO
RO
1,
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.90
0.09
0.26
1.62
0.21
1.00
0.77
1.33
.32-1.78
0.88
1.27
1.48
1.51
7.43
2.67
1.51
1.44
32-1.78
1.36
1.17
0.33
0.30
1.63
3.07
1.31
0.95
6.50
2.07
1.67
1.25
1.70
0
0
0
0
0
0
0
0
0
.26
.12
.30
.34
.16
.46
.56
.56
.00
1
1
1
1
1
1
1
1
.005
.013
.019
.024
.029
.034
.053
.084
0.838-1.162
0
4
1,307
.23
.18 2.54
.71 779.42
9.98 6.01
0.89
2.17 2.27
9.65 5.80
3.80 2.24
0.000
2.00 0.985
528.29 1.000 13C12-PeCDF 123 IS2
3.97 1.013
1.018
0.85 1.022
3.85 1.032 13C12-PeCDF 234 SDR2
1.56 1,
.072
1,337.49
' PcCDF ' ********** «— .1 i — ...—
0.26
0.56
0.13
0.13
1.34
0.36
0.35
0.30
0.05
0.
0.
0.
0.
36
32
41
54
0.921-1.027
0.000
0.935
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
941
950
956
973
979
985
992
994
013
018
025
0.00
1.
RO
RO
RO
RO
32-1.78
1.50
1.41
1.53
1.89
0.60
0.76
2.08
0.845-1.155
0.
687.
87.
2.
1.
0.
0.
778.
25
08 402.21
03 52.57
83 2.10
33 0.81
69 0.42
64
96
0.
284.87 1.
000
000 13C12-PeCDD 123 IS3
34.46 1.006
1.11 1.
1.36 1.
0.55 1.
1.
013
018
030
037
Above: PcCDD / HxCDF Follows
riangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
p|K>ne: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:16 10/21/97
-------
Page No. 3
10/21/97
Compound/
M_Z QC.Log Omit Why
Listing of S976761B.dbf
Matched GC Peaks / Ratio
/ Ret. Time
.RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
HXCDF
374-376
M
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SH
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
WH
1
NL
SN
SN
8
NL
SN
SN
SN
SN
SN
SN
SN
SN
0:00
27:17
27:22
27:29
27:39
27:43
27:49
27:58
28:12
28:18
28:23
28:32
28:37
28:49
29:01
29:11
29:17
29:49
29:54
30:02
30:10
30:13
30:23
Peak
0:00
27:32
28:29
28:51
29:00
29:21
29:25
29:27
29:31
29:44
30:10
Peaks
0:00
28:02
28:10
28:15
28:26
28:30
28:55
29:00
29:05
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
05-1.43
1.
0.
0.
3.
0.
1.
0.
2.
4.
2.
11.
4.
1.
3.
0.
0.
0.
1.
0.
0.
0.
2.
1.
80
27
71
25
90
33
50
58
00
17
00
18
56
73
81
30
44
25
80
85
86
63
03
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.22
.05
.18
.09
.34
.14
.34
.27
.16
.13
.07
.25
.20
.25
1.81 1.00
0
0
0
0
0
0
0
0
1
.13
.13
.09
.22
.52
.22
.18
.60
.81
43-0.59
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
31
28
50
24
50
29
41
27
87
SO
36
OS-1.43
0.
0.
0.
1.
0.
2.
0.
2.
2.
74
79
80
14
68
80
38
17
00
0
0
1.044
1
979
2
1
0
0
821
1
2,854
.27
.89
.92 346.78
.78 0.60
.88 324.52
.10 0.71
.21 0.41
.62
.83 1.03
.50 272.88
.84 0.62
.06
0.957-1.054
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.24 1.
000
958
961
965
971
973
977
982
990
994
996 123478-HXCDF
002 123678-HxCDF
005
012
019 234678-HxCDF
AN
AN
AN
1.025
1.
1.
1.
1.
1.
1.
1.
028
047
050
054
059
061
067
0.860-1.140
0.
0.
698.14 1.
2.54 1.
655.36 1.
2.42 1.
0.99 1.
1.
0.55 1.
548.62 1.
1.74 1.
000
967
000 13C12-HXCDF 678
013
018 13C12-HXCDF 234
030
033
034
036
044 13C12-HXCDF 789
059
IS4
ALT2
ALT1
0
0
0
0
0
0
0
.25
.27
.36
.30
.23
.45
.14
0.52
0
.20
0.951-1.016
0.
' 0.
0.
0.
0.
0.
0.
0.
0.
000
959
964
967
973
975
990
993
995
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:16 10/21/97
246
-------
page No.
10/21/97
Listing of S976761B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z ---- QC.Log Omit Why
.RT. OK Ratio Total.Area... Area.P«ak.l.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
RpCDD
424-426
«4-426
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
0
NL
5
NL
SN
SN
SN
WH
0
NL
SN
SN
4
NL
SN
SN
SN
SN
WH
WH
0
29:08
29:14
29:18
29:23
29:25
29:31
29:35
29:44
29:50
29:57
Peaks
0:00
28:36
29:13
29:30
29:51
29:54
Peaks
0:00
31:39
32:03
32:32
32:53
Peaks
0:00
31:13
31:31
31:40
32:09
32:27
32:41
Peaks
0:00
31:25
31:50
31:59
32:19
32:29
32:34
Peaks
RO
RO
RO
RO
RO
RO
RO
RO
1
RO
RO
0.
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
0.73
0.35
0.50
1.25
0.33
1.38
0.41
6.83
0.23
0.61
.05-1.43
0.48
1.19
1.20
1.20
1.12
2.21
88-1.20
2.00
2.12
0.60
0.40
0.73
37-0.51
2.00
0.42
0.93
0.83
0.25
1.02
0.63
88-1.20
1.20
0.53
26.00
1.08
0.35
0.19
0.28
0.20
0.14
0.18
0.18
0.07
0.31
0.34
0.13
0.13
0.25
0.00
0.22
2.94 1.60
825.76 450.44
1,078.51 588.49
2.10 1.11
0.87 0.86
1,910.18
0.18
0.35
0.41
0.59
0.88
0.00
0.29
707.31 208.03
2.79 1.80
1.48 0.85
0.56
0.78 0.55
0.55
712.36
VnCTStf / Hnf™Tin P«l 1 /-n*ic ___.
0.22
0.41
0.02
0.27
0.12
0.14
0.22
0.00
0.997 123478-HXCDD
1.001 123678-HxCDD
1.003
1.006
1.007
1.010 123789-HxCDD
1.013
1.018
1.021
1.025
0.966-1.034
0.000
1.34 0.979
375.32 1.000 13C12-HXCDD 678
490.02 1.010 13C12-HXCDD 789
0.99 1.022
0.39 1.023
0.996-1.047
0.000
1.014
1.027
1.042
1.053
0.936-1.128
0.000
499.28 1.000 13C12-RpCDF 678
1.94 1.010
1.03 1.014
1.030
0.54 1.040 13C12-HpCDF 789
1.047
0.978-1.007
0.000
0.979
0.992
0.997
1.007
1.012
1.015
AN
AN
AN
IS5
RS2
IS6
SDR5
tangle Laboratories, Inc.® Analytical Services Division
Capitola Drive • Durham, North Carolina 27713
: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:16 10/21/97
247
-------
Page No. 5 Listing of S976761B.dbf
10/21/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-HpCDD 0.88-1.20 0.969-1.031
436-438 DC NL 0:00 RO 1.27 1.82 0.000
32:05 0.98 659.22 326.26 332.96 1.000 13C12-HpCDD 678 IS7
436-438 1 Peak 659.22
Above: HpCDD / Octa-CDD and CDF Follows
OCDF 0.76-1.02 0.884-1.116
442-444 DC NL 0:00 RO 1.33 0.34 0.000
DC SN 31:27 RO 0.27 0.45 0.909
DC SN 32:31 RO 0.43 0.49 0.940
DC SN 32:49 RO 7.50 0.11 0.949
DC SN 33:03 RO 8.00 0.08 0.956
DC SN 33:31 RO 0.17 0.30 0.969
DC SN 33:54 RO 1.48 0.62 0.980
DC SN 34:18 RO 0.39 0.57 0.992
DC SN 34:36 RO 1.56 0.30 1.000
DC SN 34:59 RO 4.63 0.15 1.012
DC SN 35:18 RO 5.60 0.09 1.021
DC SN 35:48 RO 1.06 0.32 1.035
DC SN 36:00 RO 0.53 0.45 1.041
442-444 0 Peaks 0.00
OCDD 0.76-1.02 0.884-1.. 116
458-460 DC NL 0:00 RO 1.13 0.15 0.000
DC SN 34:42 RO 1.11 0.34 1.003
DC SN 34:50 RO 0.50 0.21 1.007
DC SN 35:05 RO 0.35 0.17 1.014
458-460 0 Peaks 0.00
13C12-OCDD 0.76-1.02 0.998-1.007
470-472 DC NL 0:00 RO 1.60 0.19 0.000
34:35 0.86 812.59 376.33 436.26 1.000 13C12-OCDD IS8
DC HH 35:02 RO 1.69 2.91 1.013
470-472 1 Peak 812.59
Column Description 'Why code Description QC Log Desc.
M_Z -Nominal Ion Hass(es) WL-Below Retention Time Window A-Peak Added
. .RT. -Retention Time (mm:ss) WH-Above Reception Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
File:S976761 #1-829 Acq:17-OCT-lS97 00:08:37 EI+ Voltage SIX 70S Xoiae:193
303.9016 T:2 BSUB(256,30f-3.0) PKD(9, 5,5, 0.05%, 772. 0,1.00\,T,T) ExpiEPCUS
TRIANGLE LASS Text:TLI CLEAN-UP SLANT TLH43431 ISJ. TIME - 00:11
1004 A1.Q2E4
17:00 18:00 19:00 20:00 21:00
r±le:S976761 fl-829 Acq:17-OCT-1997 00:08:37 EI+ Voltage SIR 70S Ooiae:251
305.8987 F:2 SSUS(256,30,-3.0) PKD(9,S,S,O.OS\,1004.0,1.00\,r,T) XzpsEPCOS
TRIAHSLX LASS Text:TLI CLEAN-OP BLANK TLH43431 ZKT. TIKE - 00:11
1001
22: 00
17:00 18:00 15:00 20:00 21:00
r±le:S976761 #1-825 Acqsl7-OCT-1997 00:08:37 XI+ Voltage SIR 70S Boise:232
315.9419 F:2 SSUS(256,30,-3.0) PKD(9,5,5,O.OS\,92a.O,1.00\,r,T) Zzp:EPCDS
TRIANGLE LASS Tezf.TLI CLEAN-UP BLANK TLH43431 2X7. HUE = 00:11
22:00
1001
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40
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17:00 18:00 19:00 20:00 21:00
rile:S976761 fl-829 Acq:17-OCT-1997 00:08:37 EI+ Voltage SIS 70S Ooiat>:376
317.9389 f:2 SSUS(256r30,-3.0) PKD(9,S,5r0.05\r1504.0,1.00\rrtS) ZxpsSPCOS
TRIANGLE LASS Tart.-TET CLXAN-UP SLANT TLH43431 HU. TZME - 00:11
1001 A9.3SE6
aol
sol
401
aol
22:00
17:00 18:00 15:00 20:00 21:00
FU*sS976761 fl-829 Acq:17-OCT-1997 00:08:37 XI+ Voltage SIR 70S
330.9792 Fs2 EzptEPCUS
TRIANGLE LASS T*Xt:XLI CLEAN-UP BLANK TLH43431 ISJ. TIKE - 00:11
1004 17:2ff 17:56 18:19 ^?-J? 19:20 19:44 20:1020:30 21:03 21:26
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Fil»tS976761 tl-829 Acq: 17-OCT-1997 00:08:37 EI+ Voltage SIR 70S
75.8364 T:2 XxptSPCUS
TRIANGLE LASS Text-.TLI CLEAN-UP BLANK TLH43431 2K7. TUtE *
1004 18:08 20:07 20:56
aol
601
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aol
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22:00
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21:18
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18:00
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1.3X6
8.7X5
4.4X5
0.0X0
Tide
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3.0X6
2. 0X6
9.9X5
0.0X0
Time
21:00
22:00
249
-------
rile:S976761 41-829 Aoq:17-OCT-1997 00:08:37 EI+ Voltage SIS 70S Noisei244
319.8965 T:2 BSUS(256,30,-3.0) WO>f7,5,3,0.051,976. 0,1. 00%,T,T) ExpsEPCOS
TSIANGLE LABS Tert.-ZZJ CLEAN-UP BLANK TLI443431 XK7. TIME - 00:11
1004
A4.S7E3
A4.91E3 \\A2.35E3
15:00 20:00 21:00 22:00
T±letS976761 tl-829 Acq:17-OCT-1997 00:08:37 EI+ Voltage SIS 70S Noise:277
321.8936 T:2 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,1108.0,1.00\,r,T) ElpsEPCUS
TSIANGLE LABS Text:TLI CLEAN-UP BLANK TLI443431 ISJ. TIME - 00:11
19:00 20:00 21:00 22:00
f±10iS976761 11-629 Acq:17-OCT-1997 00:08:37 EI+ Voltage SIS 70S Noise-.559
331.9368 f:2 BSOS(2S6,30,-3.0) fXD(7,5,3r0.05\,2236.0,1.00\,T,T) Elp:EPCUS
TSIAKSLE LABS TaxtsTLI CLXAN-Uf BLANK TLH43431 BKT. TIME " OOs 11
lOOi, A7.82E6
80:
so:
40:
20:
\AS.74E6
19:00 20:00 21:00 22:00
rilmiS976761 il-829 Aegtl7-OCT-1997 00t08t37 EI+ Voltage SIS 70S Nbi*e*319
333.9338 T:2 BSVB(256,30,-3.0) PKD(7,S,3r0.05\,1276.0,1.00\,r,T) Exp:EPCnS
TRIANGLE LABS TeJCt:TLI CLEAN-UP BLANK TLH43431 INJ. TIME - 00:11
lOOi
so:
60:
40:
20:
A9
•SE6
A7.29E6
19:00 20:00 21:00 22:00
F±le:S976761 tl-829 Acq:17-OCT-1997 00:08:37 EI+ Voltage SIS 70S Noise:342
327.8847 Ts2 BSUB(2S6,30,-3.0) PXD(7,5,3,0.05\,1368.0,1.00\rr,T) ExpsBPCUS
TRIANGLE LABS ToxtiTLI CLEAN-OP BLANK TLH43431 HKT. TIME " 00:11
19:00 20:00 21:00
T±lesS976761 tl-829 Aey:17-OCT-1997 00:08:37 EH- Voltage SIS 70S
330.9792 r:2 XxpsXPCOS
TSIANGLE LABS TexttTLI CLEAN-UP BLANK XLII43431 UKT. TIME
18:4018156 19:20 19:44 20:10 20:30 20-.4721103 21:19
1001
80:
22:00
1.9E6
1.5E6
1.1E6
7.6E5
3.8E5
O.OEO
Time
.1.9E6
.1. 4E6
.9.3ES
.4.6E5
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Tiae
60:
40:
19*00
20:00
21:00
22:00
5.0E6
-.4.0X6
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Tiff
250
-------
FilesS976761 tl-829 Ac?:17-OCT-1997 00:08:37 EI+ Voltage SIS 70S Hoiac:87
339,8597 T:3 BSVB(256,30t-3.0) PKD(7,5,3,0,05\,348.Q,1.00\,r,T) Exp:EPCUS
TRIANGLE ZASS Text .-SIX CLEAN-UP SLANT TLH43431 1X7. TIME - 00:11
1004 A1.86E3
23:00 24:00 25:00 26:00
TilesS976761 tl-829 Aeq:17-OCT-1997 00:08:37 EH- Voltage SIS 70S BOise:133
341.8567 r:2 BSDB(256,30,-3.0) PXD(7,5,3,0.051,532.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LASS Text:TLI CLEAN-OP BLANK TLH43431 ZK7. TIME - 00:11
1001
00:
23:00 24 i 00 25:00
Tile:S976761 tl-829 Act?: 17 -OCT- 19 97 00:08:37 Eli- Voltage SIS 70S Soiee:7i
351.9000 rs2 BSVB(256,30,-3.0) PKD(7rS,3rQ.OS\,284.0,1.00\,r,T) Exp:EPCOS
TRIANSLE LABS TextiTLI CLEAN-OP BLANK TLIf 43431 .XK7. TIME -
1001
aol
40.
26:00
00:11
oJ
23:00 24:00 25:00 26:00
r±le:S976761 tl-829 Acq:17-OCT-1997 00:08:37 Eli- Voltage SIX 70S Xoj.se:78
353.8970 T:2 BSUS(256f30,-3.0) PXD(7,S,3,0.05\,312.0,1.00\,r,T) ZxpsEPCDS
TRIANGLE LABS Teit:TEI CLEAN-UP BLANK TLH43431 XKJ. TIME - 00:11
100J
sol
401
20l
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AS.
8E6
23:00 24:00 25:00 26:00
Kle:S976761 tl-829 Acq:17-OCT-1997 00:08:37 EI+ Voltage SIS 70S
330.9792 T:2 SxpsEPCBS
TRIANSLE LABS Text:TLI CLEAN-OP BLANK XLIt43431 INJ. TIME - 00:11
23:0823:2423:40
1001
aol
40:
aol
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23:00 24:00 25:00 26tOO
file:S976761 tl-829 Aoq:17-OCT-1997 00:08:37 EH- Voltage SIS 70S
409.7974 f:2 ExptSPCDS
TRIANGLE LABS Telt-.TLI CLEAN-UP BLANK XLIt43431 OKT. TIME ' 00:11
24 03
23:45
'3:35
25:48
24:20
24:37
29*09
27:00 Tim
27:00 Time
2.2E6
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27:00 Time
\ . 26:33
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-------
7ile-.S97S761 V1-82S Acq-.17-oCT-l9Sy 00:08:37 £X+ Voltage 4 J* 70s Noiae:75
355.8546 T:2 BSUB(2S6,30,-3.0) PJO>(7,S,3,0 .OS\,300 .Or1.00\,F,T) Exp:EPCUS
TSIAWSLE LABS Text:TLI CLEAN-OP BLANK Til #43431 JIU. TIME -
100*
A8.28E3
801 A2.51S3
40:
20:
00:11
A3.38E3
24:00 25:00 26:00
K1»:S976761 #1-829 Acq>17-OCT-1997 00t08i37 SI+ Voltage SIS 70S Noiae:57
3S7.8S16 Ti2 BSUB(256,30, -3.0) PO>(7,St3,O.OS\t228.0r1.00\,r,3!) SzpsEfCUS
TXIANGLE LASS Text.-TTI CLEAN-OP BLAKX TLH43431 INJ. TIKE = 00:11
1001
24:00 25:00 26:00
Tile:S976761 fl-823 Acqil7-OCT-1997 00:08:37 EI+ Voltage SIS 70S Noise-.74
367.8949 F:2 BSOS(356,30,-3.0) tXD(7rSt3tO.OS\,296.0,1.00\,r,T) Exp:EPCDS
TSIMfSLS LABS Tezt:XLI CLOUT-OP BLAST XLH43431 ZK7. TIME * 00:11
1003, A4.02E6
80.
60.
40.
20.
S.26S5
24100 25:00 26:00
Tile:S97€761 91-829 Acq:17-OCX-1997 00:08:37 EI+ Voltage SIR 70S Soime:S2
369.8919 T:2 BSUB(2S6,30,-3.0) PXB(7r5,3rO.OS\,208.0r1.00\,TrT) ExptEPOJS
TXXASGLZ LABS Tert-.TLI CLXAS-UP BLABX TLH43431 UKT. TIME * 00:11
100S A2.85E6
80.
60.
40.
20.
.4SSS
24:00 25:00 26:00
rile:S976761 #1-829 Acq:17-OCT-1997 00:08:37 EI+ Voltage SIS 70S
330.9792 r>2 SxpiXfCUS
T&IABSLE LABS Tezt.:TLI CLEAN-UP BLASX Xtl#43431 XK7. TIME -
1001
00:11
80.
60.
40:
20:
0.
24 .-07 24:20 24,34 24j48
.1.6E3
.1.2E3
.7.9E2
-4.0E2
.0. OEO
Tiae
O.OEO
Tiae
.3E6
.1.0E6
.7.6E5
.5.1E5
.2.5E5
O.OEO
Time
24 tOO
25:00
26:00
.B.3E5
.6.6E5
.5.0E5
.3.3E5
.1.7ES
.O.OEO
Time
.5.2E6
.4.2E6
.3.1S6
.2.1E6
.1 - OE6
.O.OEO
Time
252
-------
File:S976761 #1-475 Acgtl7-OCT-1997 00:08:37 EH- Voltage SIS 70S Noiae:91
373.8208 F:3 BSOB(256,30, -3.0) PKD(7,S,3,0 .OS\,364.0,1. 00\,F,T) Exp:EPCOS
TXIASSLE LABS Teit:TLI CLEAS-UP BLAST TLIf43431 IKJ. TIME - OO.-ll
1001
29:48 30:00 30:12
Tim
File-.S976761 #1-475 Acgil7-OCT-1997 00:08:37 EH- Voltage SIR 70S Koiae:50
375.8178 T:3 BSUB(2S6,30,-3.0) PTD(7,5,3,O.OS\r200.0,1.00\rF,T) Exp:EPCUS
TRIANGLE LABS Text.-JTX CLEAS-UP BLAST XLIM3431 IJKT. TIME - 00:11
1001 A1.46E4
27:24 27:36 27-43 28,00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
r±lesS976761 41-475 Acg:17-OCT-1997 00:08:37 EI+ Voltage SIS 70S So3.ae-.44
383.8639 f:3 BSVS(256, 30, -3.0) PXD( 7,5,3,0.05\,176. 0,1.00\,r,T) Exp:EPCUS
TSIANSLE LASS TextiXLI CLEAS-UP BLAUX ILH43431 UKT. TIME - 00:11
1001 A3.47E6
so:
sol
40.
20:
A3.25E6
A2.73E6
Tim
1.1E6
.8.7E5
.S.6ES
-4.4ES
_2.2ES
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
TilaiS976761 41-475 Aoq*17-OCX-1997 00:08:37 EI+ Voltage SIS 70S Hoi*e:146
385.8610 T-.3 BSUB(2S6,30,-3.0) PKD(7,5,3f0.05\,584.0,1. 00\,T,T) ExpiEPCUS
TRIANGLE LABS Teit-.TLI CLEAN-UP BLAST 3KIM3431 XK7. TIME ' 00:11
O.OEO
Time
1001
sol
6ol
40:
201
ol
A6.9BE6
A6.55E6
AS.49E6
2.2E6
Ll. 8E6
.1.3E6
.8.8E5
.4 . 4ES
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
rile:S976761 #1-475 Acq:17-OCT-1997 00:98:37 EI+ Voltage SIS 70S
392.9760 T:3 ExptEPCUS
TSIASSLE LABS TextsTLI CLEAS-UP BLAST TLH43431 JK7. TIME » 00:11
1001 27.40 _ 28:11 38:24 28:41 28:57 29:15 2?;33 29:45
/v-\^/*>^v*~-
so:
so:
40:
20:
o.
O.OEO
Time
27:24' 27:36' 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24' 29\ 36' 29:48 30 :'o6' 30:12
Tila:S976761 #1-475 Acq:17-OCT-1997 00:09:37 EI+ Voltage SIR 70S
45.7555 T:3 ExpsEPCnS
TRIANGLE LABS Tsit-.TLI CLEAS-UP BLAST TLH43431 INJ. TIME - 00:11
1001
.2..7E6
.2.1E6
.1. 6E6
.1.1S6
.5.3ES
O.OEO
Time
80:
50:
40:
20:
27,33 -i3
28:51
-JJdtiAA^AAJ^^
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29\36' '29\48' 3oYoO 30tl2
253
-------
Fil*:SS76761 il-475 Aog:17-dCT-199? 00:68:37 £1+ Voltage six 70S Noiee:71
389.8156 r:3 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,284. Q,1.00\,T, T) Exp:EPCUS
TRIANGLE LABS Tezt.-XLJ CLEAN-UP SLANT TLIt43431 INJ. TIME - 00:11
A5.59E3 AS.01E3
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
ttle:S976761 tl-475 Acq:17~OCT-1997 00:08:37 EI+ Voltage SIX 705 Noiae:94
391.8127 r:3 BSUB(256,30, -3.0) PXD(7rS,3r0.05\r376.Q,1.00\,T,T) Exp:EPCOS
TRIANGLE ZASS Text tTLl CLEAN-UP SLANT TLH43431 IKT. TIME • 00:11
1001 Al. 3E3
29:36 29:48
30:00
,.3.0E3
37:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
Tile:S976761 tl-475 Acq:17-OCT-1997 00:08:37 gH- Voltage SIS 70S Noj.ee:58
401.8558 T:3 BSUB(256,30, -3.0) PXD(7,5,3,0.05\,232.0f1.00\fr,X) SxpsEPCOS
TRIANGLE LABS TeJTt-.TLI CLEAN-UP BLANK TLH43431 HKT. TIME = 00:11
IOCS A5.8.8E6
O.OEO
29:36 29': 4 8 30-00 Time
80.
60.
40.
20.
A4.50E6
_1.8E6
'.1. 4E6
.1.1E6
.7.1ES
.3.SE5
O.OEO
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
file:S976761 tl-475 Ac?: 17-OCT-1997 00:08:37 EH- Voltage SIR 70S Noiee:126
403.8529 T:3 BSUB(2S6,30, -3.0) ?XD(7,St3,O.OS\,S04.0r1.00\fr,T) ExptEPCOS
TSIANGLE LABS T«Zt:3ZJ CLEAN-UP BLANK TLH43431 HKT. TIME - 00:11
1004 A4.90E6
80.
60.
40.
20.
A3.75E6
30:00 Time
-1.5E6
.1.2E6
.9.0E5
.6.0ES
.3.0X5
.O.OEO
27:48 28:00 28:12 28:24 28:36 28:48 29:09 29:12 29:24 29:36 29:48
ril»:S976761 tl-475 Acqil7-OCT-1997 00x08.37 EH- Volt*** SIX 70S
392.9760 T:3 ExpsSPCDS
TRIANGLE LABS TeXt:TLI CLEAN-UP BLANK TLIt43431 1ST. TIME - 00:11
80.
60.
40.
20.
30:00 Tine
r2.7E6
.2.1E6
.1. 6E6
.1.1E6
.S.3E5
,0. OEO
27^48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 Time
234
-------
Tile:S976761 #1-397 Acq:17-OCT-1997 00:08:37 EH- Voltage SIX 70S itoi.Be-.91
407.7818 Pi4 BSU3(256,30,-3.0) PXD(7,5,3,0.05%, 364.0,1. 00\,f,T) Exp-.EPCUS
TRIANGLE LASS Text:TLI CLEAN-UP BLANK TLH43431 INJ. TIKE - 00:11
1001
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File:S976761 tl-397 Acq:17-QCT-1997 00:08,37 XI+ Voltage SIR 70S Noiae:43
409.7789 T:4 BSUS(2S6,30,-3.0) PXD(7,5,3,0.051,172.0,1.00\,T,T) Exp-.EPCUS
TRIANGLE LASS Text-.TLI CLEAN-OP BLANK TLH43431 INJ. TIKE =
32:36
00:11
80.
60.
40:
20:
oj
A7.52E3
A2.51E3
32:48
A6.25E3
A2.55E3
.O.OEO
33:00 T±m<
1. 8Z3
'•.1.5E3
'.1. 1E3
.7.3E2
-.3. 6E2
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
T±le:S976761 tl-397 Acq:17-OCT-1997 00:08:37 XH- Voltage SIS 70S Noiae:198
417.8253 r-.4 SSUS(256,30,-3.0) PXD(7,S,3r0.05\,792.0,1.00\,T,T) Exp-.EPCUS
TRIANGLE LASS Tezt:TLI CLEAN-UP BLANK TLH43431 ISJ. TIKE - 00:11
32:48
0. OEO
33:00 Tiae
1001
ao:
60:
40:
20:
A2.Q8E6
-5.OES
.4.OES
.3. OE5
.2.0ES
_1. OES
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
rile:S976761 tl-397 Acq:17-OCT-1997 00:08:37 XZ+ Voltage SIS 70S Noiae-.lOO
419.8220 r-.4 BSOB(256,30, -3.0) PXD(7,5,3,0.OS\,400.0,1.00\rr,T) Exp-.EPCUS
TRIANGLE LABS Text.-ZET CLEAN-UP BLANK TLH43431 INJ. TIKE = 00:11
A4.99E6
32:48
•.O.OEO
33:00 Tiae
80:
60:
40:
20:
1.2E6
.9.6E5
-7.2E5
-4.8E5
12.4ES
31:12 31:24 31:36 31:48 32:00 32:12 32:24
Tile:S976761 41-397 Aeq:17-OCT-1997 00:08:37 EH- Voltage SIR 70S
430.9729 T:4 Exp:EPCUS
TRIANGLE LABS Text:TLI CLEAN-UP BLANK TLI443431 INJ. TIKE -
i003 .31:10 318 3127 3135 31:44 32:00 32:13 32:25
N/l
so:
so:
40:
so:
oj
.O.OEO
32:36 ' '32:48 ' 33:00 Tiae
32:55 2.OES
.1. 6E6
.1.2E6
.7.9E5
.3.9E5
31:12 31:24 31:36 31:48 32:00 32:12 32:24
rila:S976761 f1-397 Acq:17-OCT-1997 00:08:37 XH- Voltage SIS 70S
479.7165 T:4 Exp:EPCUS
TSIANGLE LASS Text:TLI CLEAN-UP BLANK XLH43431 INJ. TIME -
100}
80:
60:
40:
so:
0.
32:36
32:48
.O.OEO
33:00 Tim<
-4.2E3
.3.3S3
.2.5E3
.1. 7E3
.8.3E2
31:12
31124
31:36
31:48
32: 00
32:12
32:24
32:36
32:48
.0.0X0
33:00 Time
255
-------
f3.1e:S97Byt>l 41-397 Acq:17-6Cf-lSS7 00-.OS-.37 EI+ Voltage Sis 70S Jteiae.-Sfl
423,7766 F:4 3SVB(256,30,-3.0) PXD(7,5,3,0.05\,232.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LASS Text:TLI CLOUT-OP BLAHX TLH43431 ISJ. TIME " 00:11
1001 A2.06E3
^1•4E3
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32:36
Tile:S97676l fl-397 Aeq: 17-OCX-1997 00:08:37 EI+ Voltage SIS 70S Noise-.49
425.7737 T:4 BSUB(256,30,-3.0) PXD(7,S,3,0.05\r196.0r1.00\,r,T) EzptSPCOS
TSIAlteLE LASS Text-.TLI CLEAN-UP BLANK TLIf43431 1X7. TIME - 00:11
Time
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24
Tilm:S976761 tl-397 Aexj:17-OCT-1997 00:08:37 EI+ Voltage SIS 70S Soiae:56S
435.8169 T-.4 BSUB(256,30, -3.0) PKD(7,5,3,O.OS\r2260.0,1.00\,r,T) EzpiEPCUS
TXIAHGLE LASS Text.-XLJ CLEAN-UP BLANK TLH43431 ISJ. TIKE - 00:11
1001 A3.26E6
BO:
so:
40.
20:
32:30 32:36
o:
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24
rile:S97S7Sl fl-397 Acg:17-OCT-1997 00:08:37 EI+ Voltage SIS 70S Koiae:445
437.8140 T:4 BSUS(256,30,-3.0) PXD(7,5,3,0.051,1780.0,1.00\,T,T) Exp:EPCUS
XRIAXSLE LASS Taxt.-ZLI CLEAN-OP BLANK TLH43431 OCT. TIME - 00:11
1001 A3.33X6
eo:
eo:
40:
20:
32:30 32:36
o:
.S.1E5
.3.8E5
.2.6E5
.1.3ES
.O.OEO
Time
.6.2ES
.5.0ES
.3. 7ES
.2.5E5
.1.2E5
.O.OEO
31:24 31-30 31:36 31:42 31:48 31t54 32:00 32:06 32:12 32:18 32:24 32:30 32:36
rilmtS976761 tl-397 Acg:17-OCT-1997 00:08:37 EH- Voltage SIX 70S
430.9729 T:4 Exp:EPCUS
TSIAHGLE LABS Text:TLI CLEAN-UP BLANK TLIf43431 OCT. TIKE - 00:11
31t27 31i35 31:44 32:0032:04 32tl3 32:25 32i34
eo:
40:
20:
o:
31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32:36
2.0E6
1. 6E6
1.2E6
7.9E5
3.9E5
O.OEO
Time
256
-------
tile!S976761 tl-397 Acq:17-OCT-1997 00:08:37 EI+ Voltage SIX 70S Noife:119
441.7428 r-.4 BSOB(2S6,30, -3.0) PXD(7, 5, 3,0. 05^,476. 0,1.00\,F,T) Exp:EPCUS
TRIANGLE LASS TertilZJ CLEAN-UP BLANK TLIt43431 HV. TIME ' 00:11
100.
90.
80.
70.
60.
50.
40.
30.
20.
10.
31
A4 . 78E3
r3
j^A
-2.6X4
.2.3X4
12.0X4
11 . 8X4
:1.5E4
11.3X4
.1 . 0X4
.7.7X3
':5.1E3
.2.6E3
00 32:00 ' ' ' 33.- 00 34:00 35:00 Time
Til*tS976761 tl-397 Acq:17-OCT-1997 00:08:37 EI+ Voltage SIS 70S Soime:9l
443.7399 Tt4 BSUB(256,30,-3.0) PXD( 7,5,3,0. 051,364. 0,1. 00\,T,T) Xzp:EPCOS
TRIANGLE LABS Text.-ZXZ CLEAN-UP BLANK TLH43431 XS7. TIME = 00:11
ion
901
801
701
601
sol
401
301.
201
101
0'-
31
A1.13E4
I A8.08X3
A7.94E3 II ^A2.28E3 1 1 U8l 39S3 A , 33Z3 A Al . 62X3 A1.22JT3 •
•\MAyA-^\JUI'\A>. A^^/^^l/AT\wAy*JWA/'V/u^jJyu\^u^*jLM>— /VAV l/MAAJL»Ar\sv\«rf>^AA^Y/lW_^-WLjTAA^^'
1 . 8E4
Ll . 6X4
Ll . 5X4
'.1.3X4
-.1.1X4
.9 . 1X3
.7.3X3
.5.5E3
'-.3.6X3
Ll.8S3
O.OEO
00 ' ' ' 32:00 ' ' ' 33:00 ' ' 34-00 35:00 ' Tdae
ril«:S976761 tl-397 Aeq:17-OCT-1997 00:08:37 EI+ Voltage SIB 70S
430.9729 T:4 Exp:EPCUS
TRIANGLE LABS Tejrt:TLI CLEAN-UP BLANK TLH43431 UtT. TIME - 00:11
4 JM A A 4 J* » 35 j. » i jLJ|4 A I A ^^L« * ft^ Xft * _^\^Jl ^l^^*l ft A A A * A A t- AJ^^ £* AJjx. A
|l Ify "fyryU y^ lyv fjf iry IF
^1
70j
601
501
401
301
201
101
0-
31
.2.0X6
Ll • 8X6
_1 . 6X6
.1.4X6
-1.2X6
.9.9X5
.7.9X5
.5.9X5
.3.9X5
.2.0X5
0.0X0
00 33:00' ' 33sOO 34;»0 35:00 Time
Tile -.39767 61 tl-397 Acgtl7-OCT-1997 00:08:37 EH- Voltage SZB 70S
513.6775 Tt4 XxptXTCUS
TRIANGLE LABS Tart.-HJ CLEAN-UP BLANK TLH43431 OCT. TIME - 00:11
1001
90.
801
701
601
SOI
401
301
201
101
01
34 : 49
.1
33 .-03
II
31,36 32 32 1 11
1 1 ,, _„ i 1 In
J 1 ff1 h 34sli 34:36 I 35:29 1
^wHiJlKliW
.4.3X3
.3.9X3
.3.4X3
.3.0X3
.2.6X3
.2.1X3
.1.3X3
.8.6X2
.4.3X2
. 0 . OEO
31 00 32:00 33:00 34:00 35:00 Time
-------
*3.1e:S976761 il-397 Acq:17-otl-lW> 00:08:37 EX+ Voltage sis 70s Noi.Be-.43
457.7377 T:4 BSUB(256, 30, -3. 0) PXD(7,5,3,0.05\,172.0r1.00\,T,T) Exp-.EPCUS
TRIANGLE LASS Text-.TLI CLEAN-OP BLANK TLI#43431 XK7. TIKE - 00:11
1004
34:30 34:36 34:42 34:48 34:54 35:00
rile:S976761 #1-397 Acq:17-OCT-1997 00:06:37 EI+ Voltage SIS 70S Noiset39
459.7348 T:4 BSUB(256,30, -3.0) PXD(7,5,3,O.OS\,156.0,1.00\,T,T) Ezp.-JEPCDS
TRIANGLE LASS Teit:TLI CLEAN-UP BLANK TLII43431 JK7. TIME - 00:11
1001
80.
50.
40.
20.
35:06
A2.33E3
A2.57S3
1. 4E3
11 . 1E3
.8.4E2
.5.6E2
-2.SE2
34:30 34s36 34:42 34:48 34:54 35:00
flle:S976761 tl-397 Acq:17-OCT-1997 00:08:37 SI+ Voltage SIS 70S SoiaesSO
469.7779 T:4 BSUS(256,30, -3.0) PKD(7,5,3,0.05\,320.0,1.00\,T,T) Xxp:SPCUS
TRIANGLE LABS T&rt-.TLI CLEAN-UP BLANK TLH43431 UKT. TIKE - 00:11
1001 A3.16X6
80.
60.
40.
20.
35:06
O.OEO
Time
3.9X5
.3.2E5
.2.4E5
,.1. 6ES
-7.9E4
34:30 34:36 34:42 34:48 34:54 35:00
rilesS976761 tl-397 Acq:17-OCT-1997 00:08:37 XI+ Voltage SIS 70S Noise:51
471.7750 T:4 BSUB(256,30,-3.0) PXD(7,5,3,0.OS\,204.0,1.00\,T,T) ExpsEPCUS
TRIANGLE LABS TeJCt:TLI CLEAN-UP BLANK TLIf43431 TXT. TIME - 00:11
1004 A4^J6E6
35:06
O.OEO
Time
4.3ES
.3.5E5
.2.6E5
'.1. 7E5
.8.7E4
34:30 34:36 34:42 34:48 34:54 35:00
rile:S976761 #1-397 Acgsl7-OCT-1997 00:08:37 ZZ> Voltage SIX 70S
430.9729 Ts4 Exp-.EPCUS
TRIANGLE LABS Teit:TLI CLEAN-OP BLANK TLH43431 XK7. TIKE - 00:11
1001
80.
60.
40.
20.
0.
35:06
O.OEO
Tine
34:30
34:36
34:42
34:48
34:54
35:00
35:06
-1.9E6
.1.5E6
.1.1E6
.7.6E5
.3. ass
O.OEO
Time
258
-------
Ref. lass 232,3825 Peak top
Height .62 volts Span 208 ppi
Systa file nate
Data file naae
Resolution
Isnlzatlon iode
Switching
Ref. lasses 292.9825,
fl 293 J 331
8 364
C 386
D 316
E 318
F 320
o 322
H 328
I 331
K 332
L 334
I m
N 342
0 352
P 354
R 358
EPOJS
fl:S3/S756
2
0*
VCUBGE
416,3768
S 368
T 378
U 276
V 418
Channel I 338.3732 Peak top
Height .68 volts Span 288 ppi
-------
File:S976761 #1-475 Acq:17-OCT-1997 00:08:37 EH- Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample Text:TLI CLEAN-UP BLANK TLI#43431
lOOi
90J
80 j
70 j
601
50 j
40 j
30J
20J
10J
OJ
Al.
INJ. TIME =
OOE4
00:11 File TextrTLI CLEAN-UP »
28-is'28:24'28:30 28:36'28:42'28:48'28:54'29:66 23\Q6'29:12'29:i8'29:24
_4.4E3
..3.9E3
_3.5E3
_3.0E3
_2.5E3
_2 . OE3
_1.5E3
_9.9E2
_4.9E2
O.OEO
29:30 29:36
Time
File:S976761 #1-475 Acq:17-OCT-1997 00:08:37 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text:TLI CLEAN-UP BLANK TLI#43431 INJ. TIME =
1004, A1.24E4
90J
80 J
70 j
60J
50 j
40 J
30J
20 J
10 J
00:11 File Text:TLI
I i i i i i I i i • i i I i i • i i I i i • i i I i i • i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i
28:18 28:24 28:30 28:36 28:42 28:48 28:54 29:00 29:06 29:12 29:18 29:24
29:30 29:36
CLEAN-UP »
_4.7E3
_4.3E3
_3.8E3
_3.3E3
_2.8E3
_2.4E3
_1.9E3
_1.4E3
_9.5E2
_4.7E2
O.OEO
Time
-------
CALIBRATION
DATA
Triangle Laboratories, Inc.
801 Cap/to/a Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax * 919-544-5491
-------
Date: 10/16/97
TRIANGLE LABORATORIES. INC.
Continuing Calibration far S976754
Operator
Init Calibration.
ICal Date
Analyte Summary
Name
MS
. SF56117
• 06/10/97
Instrument- . -. s
Sid. Cone
RF
Ratio
1&2
Total MCDF
Total MO3D
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
12378-PeCDF
23478-PeCDF
TOTAL PeCDF
12378-PeCDD '
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
TOTAL HXCDP
12347 8-HxCDD
123678-HxCDD
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
0.
0.
1.
0.
1.
000
000
000
000
000
000
123
123
154
154
057
107
082
281
281
994
370
998
889
063
779
045
0.
0.
0.
0.
1.
1.
80
80
78
78
52
50
RT
Lo/High
0:27
14:27
1:15
15:15
7:27
15:27
8:15
16:15
11:27
18:27
13:15
19:15
16:53
22:33
18:14
22:32
22:28
26:43
RT Rel. RT
20:28 1.0008
21:16 1.0008
24:45 1.0007
25:31 1.0317
1.51
1.
1.
57
57
1.25
1.
1.
1.
1.
26
25
23
25
1.22
1.
23
23:50
26:34
27:15
30:01
27:47
29:41
Page
25:53 1.0006
28:24 0.9971
28:30 1.0006
29:01 1.0187
29:45 1.0445
29:09 0.9977
29:13 1.0000
1
.
ICal
RF
2.087
1.625
0.687
1.326
1.082
0.933
1.251
1.251
1.191
1.191
1.111
1.115
1.113
1.256
1.256
1.215
1.574
1.247
1.105
1.285
0.953
1.133
50.00
Delta
RF
-2.
087
-1.625
-0.
-1.
-1.
-0.
-0.
-0.
-0.
-0.
-0.
-0.
-0.
0.
0.
-0.
-0.
-0.
-0.
-0.
-0.
-0.
687
326
082
933
128
128
037
037
054
008
031
025
025
221
204
249
216
222
174
088
%D
100
100
100
100
100
100
-10
-10
-3
-3
-4
-0
-2
2
2
-18
-13
-20
-19
-17
-18
-7
.0%
. 0%
.0%
.0%
.0%
.0%
.2%
.2%
.1%
.1%
.9%
.7%
.8%
.0%
.0%
.2%
.0%
.0%
.5%
.3%
.3%
.7*
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:12 10/16/97
262
-------
Dace': 10/16/97
123739-HxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-H£CDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
Other Standard
Name
37C1-TCDD
13C12-PeCDF
13C12-HXCDF
13C12-HXCDF
L3C12-HXCDF
13C12 -HxCDD
13C12-H&CDF
234
478
234
789
478
789
TRIANGLE LABORATORIES, INC.
Continuing Calibration for S976754
0.963 1.22 29:31 1.0103 1.091
0.929 1.22 1.059
1.445 1.05 31:05 31:14 1.0005 1.543
32:41
1.074 1.03 32:27 1.0395 1.184
1.260 1.04 1.363
0.959 1.04 31:21 32:05 1.0005 1.068
32:18
0.959
1.375
0.977
Sumnary
RF
0.942
0.962
0.874
0.830
0.727
0.857
0.758
1.04
0.91
0.92
Ratio
142
1.47
O.SO
0.50
0.50
1.23
0.41
30:34
38:34
30:34
38:34
RT
Lo/High
19:15
23:15
20:44
28:44
29:13
35:13
34
34
:43
:37
RT
21
25
28
29
29
29
32
:16
:30
:23
:00
:44
:08
:26
1.0043
1.0014
Rel. RT
1.0008
1.0310
0.9965
1.0181
1.0439
0.9971
1.0390
Internal Standard Summary
Name
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF
UC12-PeCDD
13C12-HXCDP
I13C12 -HxCDD
123
123
678
678
RF
1.475
1.102
1.098
0.588
1.424
1.075
Ratio
1&2
0.74
0.31
1.50
1.54
0.49
1.21
RT
Lo/Higb.
19:27
21:27
19:15
23:15
20:44
28:44
21:52
29:52
24:29
32:29
28:13
30:13
Page 2
RT
20
21
24
25
:27
:15
:44
:52
28:29
29
:13
Rel. RT
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.068
1.493
1.105
ICal
RF
0.843
0.970
0.959
0.926
0.305
0.973
0.771
ICal
RF
1.318
1.066
1.133
0.635
1.204
0.995
-0.128
-0.130
-0.098
-0.110
-0.103
-0.109
-0.109
-0.118
-0.128
Delta
RF
0.099
-0.008
-0.085
-0.096
-0.078
-0.116
-0.013
Delta
RF
0.157
0.036
-0.035
-0.047
0.220
0.080
-11.7%
-12.3%
-6.4%
-9.3%
-7.6%
-10.2%
-10
-7
-11
%D
11
-0
-8
-10
-9
-11
-1
%D
11
3
-3
-7
18
8
.2%
.9%
.5%
.7%
.8%
.9%
.4%
.7%
.9%
.7%
.9%
.4%
.1%
.5%
.3%
.1%
jangle Laboratories, Inc.® Analytical Services Division
11 Sapitola Drive • Durham. North Caroina 27713
: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:12 10/16/97
2R3
-------
Date: 10/16/97 TRIANGLE LABORATORIES, INC.
Continuing Calibration for S976754
13C12-HpCDF 678 0.894 0.44 29:13 31:13 1.0000 0.887 0.007 0.8%
35:13
31:04 32:04 1.0000 0.315 0.010 1.3%
33:04
34:29 34:34 1.0000 0.519 0.012 2.4%
34:49
13C12-HpCDD 678 0.825 1.00
13C12-OCDD 0.531 0.88
Recovery Standard Sunmary
Name RF Ratio
1&2
13C12-1234-TCBD 1.000 0.83
13C12-HXCDD 789 1.000 1.22
RT
Lo/High
ICal Delta
RT Rel. RT RF RF
%D
21:03 0.9906 1.000 0.000 0.0%
29:30 1.0097 1.000 0.000 0.0%
QC Front End Check:
1.6559
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:12 10/16/97
^ 264
-------
!Dace: 10/16/97
TRIANGLE LABORATORIES, INC.
Continuing Calibration for S976737
operator ; HLM Tistnznei
Init Calibration. : SF56117 Std.Conc
ICal Date 06/10/97
Analyte Summary
Name RF Ratio RT RT Rel. RT
It2 Lo/High
Total MCDF 0.000 0:26
14:26
Total MCDD 0.000 1:14
15:14
Total DCDF 0.000 7:26
15:26
Total DCDD 0.000 8:14
16:14
Total TriCDF 0.000 11:26
18:26
Total TriCDD 0.000 13:14
19:14
2378-TCDF 1.151 0.79 16:51 20:27 1.0008
22:31
TOTAL TCDF 1.151 0.79
2378-TCDD 1.136 0.78 18:11 21:14 1.0000
22:29
TOTAL TCDD 1.136 0.78
12378-PeCDF 1.055 1.51 22:25 24:44 1.0007
26:41
23478-PeCDF 1.058 1.55 25:30 1.0317
TOTAL PeCDF 1.056 1.53
12378-PeCDD 1.330 1.54 23:48 25:52 1.0006
26:32
TOTAL PeCDD 1.330 1.54
123478-HXCDF 0.974 1.26 27:13 28:23 0.9965
29:59
123678-HxCDF 1.379 1.25 28:29 1.0000
234678-HxOJF 0.997 1.27 29:00 1.0181
123789-HxCDF 0.883 1.27 29:44 1.0439
TOTAL HxCDF 1.058 1.26
123478-HxCDD 0.756 1.27 27:45 29:08 0.9977
29:39
123678-HxCDD 1.028 1.17 29:12 1.0000
Page 1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
ptone: (919) 544-5729 • Fax: (919) 544-5491
i • - . . t Jafe •* '
it..; S
. . . . ; 50.00
ICal Delta
RF RF %D
2.087 -2.087 100.0%
1.625 -1.625 100.0%
0.687 -0.687 100.0%
1.326 -1.326 100.0%
1.082 -1.082 100.0%
0.933 -0.933 100.0%
1.251 -0.100 -8.0%
1.251 -0.100 -8.0%
1.191 -0.055 -4.6%
1.191 -0.055 -4.6%
1.111 -0.056 -5.1%
1.115 -0.057 -5.1%
1.113 -0.057 -5.1%
1.256 0.074 5.9%
1.256 0.074 5.9%
1.215 -0.241 -19.9%
1.574 -0.195 -12.4%
1.247 -0.250 -20.0%
1.105 -0.222 -20.1%
1.285 -0.227 -17.7%
0.953 -0.197 -20.7%
1.133 -0.105 -9.2%
Printed: 06:20 10/16/97
265
-------
Date: 10/16/97
123789-KxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL KpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
TRIANGLE LABORATORIES, INC.
Continuing Calibration for S976T37
0.931 1.22 29:30 1.0103 1.
0.905 1.21 1.
1.455 1.03 31:04 31:13 1.0005 1.
32:39
1.114 1.07 32:26 1.0395 1.
1.284 1.05 1.
0.980 1.04 31:19 32:04 1.0000 1.
32:16
0.980
1.385
0.999
1.04
0.90
0.89
30:33
38:33
30:33
38:33
34:40
34:34
1.0034
1.0005
Other Standard Summary
Name
37C1-TCDD
13C12-PeCDF
13C12-HXCDF
13C12-HXCDF
13C12-HXCDF
13C12 -HxCDD
13C12-HpCDF
234
478
234
789
478
789
Internal Standard
Name
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF
13C12-PeCDD
13C12-HXCDF
13C12 -HxCDD
123
123
678
678
RF
0.920
0.918
0.838
0.810
0.693
0.833
0.778
Ratio
142
1.47
0.51
0.50
0.49
1.26
0.42
RT
Lo/High
19:14
23 : 14
' 20:43
28:43
29:12
35:12
RT
21:15
25:29
28:23
28:59
29:43
29:07
32:26
Rel. RT
1.0008
1.0310
0.9965
1.0176
1.0433
0.9971
1.0395
Stannary
RF
1.364
1.023
0.960
0.476
1.459
1.092
Ratio
1&2
0.74
0.81
1.48
1.48
0.51
1.17
RT
Lo/High
19:26
21:26
19:14
23:14
20:43
28:43
21:51
29:51
24:29
32:29
28:12
30:12
RT
20:26
21:14
24:43
25:51
28:29
29:12
Rel. RT
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.
1.
1.
091
059
543
184
363
068
068
493
105
ICal
RF
0.
0.
0.
0.
0.
0.
0.
843
970
959
926
305
973
771
ICal
RF
1.
1.
1.
0.
1.
0.
318
066
133
635
204
995
-0.160
-0.154
-0.088
-0.070
-0.079
-0.088
-0.088
-0.108
-0.106
Delta
RF
0.077
-0.052
-0.121
-0.116
-0.112
-0.140
0.007
Delta
RF
0.046
-0.043
-0.173
-0.159
0.255
0.097
-14.
-14.
-5.
-5.
-5.
-8.
-8.
-7.
-9.
%D
9.
-5.
-12.
-12.
-13.
-14.
0.
%D
3.
-4.
-15.
-25.
21.
9.
6%
5%
7%
9%
8%
2%
2%
3%
6%
1*
4%
6%
5%
9%
4%
8%
5*
0*
3%
0*
2*
8*
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carofina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 06:20 10/16/97
266
-------
pace: 10/16/97 TRIANGLE LABORATORIES, INC.
Continuing Calibration for S976737
!3C12-HpCDF 678 0.854 0.45 29:12 31:12 1.0000 0.887 -0.033 -3.7%
35:12
!3C12-HpCDD 678 0.757 1.12 31:04 32:04 1.0000 0.815 -0.058 -7.1%
13C12-OCDD
0.529 0.88
Recovery Standard Sunsnary
Name RF Ratio
142
13C12-1234-TCDD 1.000 0.83
13C12-HXCDD 789 1.000 1.20
33:04
34:26 34:33 1.0000 0.519 0.010
34:46
RT
Lo/High
ICal Delta
RT Rel. RT RF RF
2.0%
%D
21:01 0.9898 1.000 0.000 0.0%
29:30 1.0103 1.000 0.000 0.0%
QC Front End Check:
2.0140
Page
tangle Laboratories, Inc.® Analytical Services Division
ft Capitoia Drive • Dunham, North Carolina 27713
'fione: (919) 544-5729 • Fax: (919) 544-5491
Printed:0$20 10/16797
<-Oi
-------
TRIANGLI LABORATORIES. INC.
Initial Calibration Summary ror SF55Z.1"
Analysis Date. . .
Instrument ....
Analytes
Total MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
12378-PeCDF
23478 -PeCDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
TOTAL HxCDF
123478-HxCDD
123678 -HxCDD
123789-HxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12-HXCDF 478
13C12 -HxCDF 234
13C12- HxCDF 789
13C12-HXCDD 478
13C12-HpCDF 789
Internal Standards
13C12-2378-TCDF
13C12-2378-TCDD
13C12- PeCDF 123
06/10/97
3
RF
2
1
0
1
1
0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
1
1
1
1
1
1
1
1
1
1
.087
.625
.587
.326
.082
.933
.251
.251
.191
.191
.111
.115
.113
.256
.256
.215
.574
.247
.105
.285
.953
.133
.091
.059
.543
.184
.363
.068
.068
.493
.105
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
RF
0
0
0
0
0
0
0
.843
.970
.959
.926
.805
.973
.771
0
0
0
0
0
0
0
RF
1
1
1
.318
.066
.133
0
0
0
SD
.000
.000
.000
.000
.000
.000
.116
.116
.231
.231
.082
.061
.069
.113
.113
.064
.099
.069
.060
.062
.067
.070
.067
.067
.103
.100
.095
.089
.089
.131
.066
SD
.038
.030
.042
.021
.044
.027
.049
SD
.065
.020
.051
%RSD
0%
0%
0%
0%
0%
0%
9%
9%
19%
19%
7%
5%
6%
9%
9%
5%
6%
6%
5%
5*
7%
6%
6%
6%
7%
8%
7%
8%
8%
9%
6%
%RSD
5%
3%
4%
2%
5%
3%
6%
%RSD
5%
2%
5%
Page
8:
8:
10
11
13
14
19
20
24
24
25
27
28
28
29
28
28
29
30
31
31
34
34
Method
RT
15
42
:38
:09
:59
:03
:43
:36
:12
:59
:22
:55
:01
:32
:15
:41
:46
:03
:45
:57
:37
:09
:03
RT
20
24
27
28
29
28
:36
:58
:55
:32
:15
:40
31:57
RT
19:43
20:34
24:11
1
RT/LO
0:01
0:34
6:43
7:34
10:43
12:34
15:43
16:34
20:11
21:21
24:01
24:45
26:45
27:36
30:02
30:02
RT/LO
18:34
22:11
28:45
RT/LO
18:43
18:34
20:11
. M237
RT/HI
13 :
:43
14:34
14:43
15:
17:
13:
23:
24:
28:
29:
32:
32:
34:
35:
38:
38:
34
43
34
43
34
11
21
01
45
45
36
02
02
RT/HI
22:
26:
34:
34
11
45
RT/HI
20:
22:
28:
43
34
11
Ratiol Ratio2
2.931
2.327
5.965
1.609
1.025
1.064
0.799
0.799
0.772
0.772
1.552
1.470
1.509
1.526
1.526
1.247
1.260
1.243
1.246
1.249
1.265
1.251
1.233
1.249
1.034
1.080
1.053
0.993
0 . 993
0.876
0.902
Ratiol Ratio 2
1.470
0.518
0.517
0.519
1.241
0.424
Ratiol Ratio 2
0.734
0.802
1.447
N
1
1
1
1
1
1
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
N
5
5
5
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 - Fax: (919) 544-5491
Printed: 09:49 06/10/97
268
-------
TRIANGLE LABORATORIES. INC. Date: 06/10/9"
Initial Calibration Summary for SFS5117
!3Ci;-?eCDD 123 0.=35 0.082 13% 25:21 21:21 25:21 1.461 5
X3C12-HXCDF 678 1.204 0.073 6% 28:01 24.01 32:01 0.522 I
13C12-HXCDD 678 0.595 0.017 2% 28:45 27:45 29:45 1.240 5
l3C12-HpCDF 678 0.387 0.046 5% 30:45 28:45 34:45 0.429 5
!3C12-HpCDD 678 0.315 0.077 9% 31:36 30:36 32:36 1.019 5
13C12-OCDD 0.519 0.080 15% 34:02 32:02 35:02 0.866 5
Recovery Standards RF SD %RSD RT RT/LO RT/HI Ratiol Ratio2 S
13C12-1234-TCDD 1.000 0.000 0% 20:21 0.811 5
13C12-HXCDD 789 1.000 0.000 0% 29:02 1.231 5
•»• End of Report •••
Page
"rtengle Laboratories, Inc.® Analytical Services Division
plCapitola Drive • Durham, North Carolina 27713 Printed: 09:49 06/10/97
|o^je: (919) 544-5729 • Fax: (919) 544-5491
<- D O
-------
Appendix D
Summary of Process Data
-------
This Appendix Contains
U.S. Intec Inc.
CONFIDENTIAL BUSINESS INFORMATION
This page represents Page 1 of 6
for further information, please contact:
Jeff Hughes
U.S. Intec Inc.
1212Brai Drive
P.O. Box 2845
Port Arthur, TX 77643
This Information Is Contained in the
USEPA Office of Air Quality Planning
and Standards CBI Office
-------
This Appendix Contains
U.S. Intec Inc.
CONFIDENTIAL BUSINESS INFORMATION
This page represents Page 2 of 6
for further information, please contact:
Jeff Hughes
U.S. Intec Inc.
1212 Brai Drive
P.O. Box 2845
Port Arthur, TX 77643
This Information Is Contained in the
USEPA Office of Air Quality Planning
and Standards CBI Office
-------
This Appendix Contains
U.S. Intec Inc.
CONFIDENTIAL BUSINESS INFORMATION
This page represents Page 3 of 6
for further information, please contact:
Jeff Hughes
U.S. Intec Inc.
1212 Brai Drive
P.O. Box 2845
Port Arthur, TX 77643
This Information Is Contained in the
USEPA Office of Air Quality Planning
and Standards CBI Office
-------
This Appendix Contains
U.S. Intec Inc.
CONFIDENTIAL BUSINESS INFORMATION
This page represents Page 4 of 6
for further information, please contact:
Jeff Hughes
U.S. Intec Inc.
1212 Brai Drive
P.O. Box 2845
Port Arthur, TX 77643
This Information Is Contained in the
USEPA Office of Air Quality Planning
and Standards CBI Office
-------
This Appendix Contains
U.S. Intec Inc.
CONFIDENTIAL BUSINESS INFORMATION
This page represents Page 5 of 6
for further information, please contact:
Jeff Hughes
U.S. Intec Inc.
1212 Brai Drive
P.O. Box 2845
Port Arthur, TX 77643
This Information Is Contained in the
USEPA Office of Air Quality Planning
and Standards CBI Office
-------
This Appendix Contains
U.S. Intec Inc.
CONFIDENTIAL BUSINESS INFORMATION
This page represents Page 6 of 6
for further information, please contact:
Jeff Hughes
U.S. Intec Inc.
1212Brai Drive
P.O. Box 2845
Port Arthur, TX 77643
This Information Is Contained in the
USEPA Office of Air Quality Planning
and Standards CBI
-------
TECHNICAL REPORT DATA
(Please read Instructions on reverse before completing)
1. REPORT NO.
EPA- 454/R-99-026B
3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
Asphalt Roofing Eitrismom Test Report Modified Bitumen Process
Final Report
U.S.Irtec. Port Arthur Texas
5. REPORT DATE
August 1999
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
EMAD
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Research Triangle Park, NC 27711
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-7-0001
12. SPONSORING AGENCY NAME AND ADDRESS
Director
Office of Air Quality Planning and Standards
Office of Air and Radiation
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT asphalt roofing industry is among the categories of major sources for which national
emission standards for hazardous air pollutants (NESHAPS) are to be issued by November 2000
pursuant to Section 112 of the Clean Air Act. The asphalt roofing industry category includes
facilities that have the following specific processes: asphalt blowing stills: modified bitumen
production; a saturator/coater process; and fiberglass mat production.
Source tests are required to quantify and characterize the paniculate matter (PM) and
hazardous air pollutant (HAP) emissions, and the performance of a thermal oxidizer used to
control emissions associated with a modified bitumen facility.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b. IDENTIFIERS/OPEN ENDED TERMS
c. COSATI Field/Group
Hazardous Air Pollutants (NESHAP)
Method 5A, Method 23, PM
18. DISTRIBUTION STATEMENT
Release Unlimited
19. SECURITY CLASS (Report)
Unclassified
21. NO. OF PAGES
464
20. SECURITY CLASS (Page)
Unclassified
22. PRICE
-------