&EPA United States Environmental Protection Agency Office of Pesticide Programs Washington DC 20460 EPA-540/9-78-007 June 1977 Pesticide Pesticide Usage Survey of Agricultural, Governmental, and Industrial Sectors in the United States, 1974 ------- PESTICIDE- USAGE SURVEY OF AGRICULTURAL, GOVERNMENTAL, AND INDUSTRIAL SECTORS IN THE UNITED STATES, 1974 Directed by South Carolina Epidemiologic Studies Program Center Preventive Medicine Section Medical University of South Carolina Charleston, South Carolina 29401 Julian E. Keil, Dr.P.H., Principal Investigator Samuel T. Caldwell, M.A., Field Studies Coordinator C. Boyd Loadholt, Ph.D., Biometrist With the Cooperation of the Epidemiologic Studies Program Centers and Projects This study was supported by the Epidemiologic Studies Program, Technical Services Division, Office of Pesticide Programs, Environmental Protection Agency under contract number EPA 68-01-1950. The views expressed herein are those of the investigators and do not necessarily reflect the official viewpoint of the supporting agency. June 1, 1977 (An abridgement of a report made to EPA, May 31, 1976) ------- TABLE OF CONTENTS Page Acknowledgements ii List of Figures iii List of Tables iv Introduction and Background ] Methods and Procedures 5 Quality Control 6 Agriculture 6 Industry - PCO 7 Industrial Utility and Government 7 Results 8 Discussion and Recommendations 33 Recommendations 43 Uses of Data 49 Summary 49 References ..... 51 Index 52 ------- ACKNOWLEDCEMENTS The authors wish' to acknowledge the following persons who cooperated in this survey. South Carolina ESP Center S. H. Sandifer, M.D., M. T. Watson, D. L. Rlols, B. D. Brltz Colorado ESP Center E. P. Savage, Ph.D., L. Mounce Iowa ESP Center D. P. Morgan, M.D., V. B. Beat, D.V.M. California ESP Project W. F. Serat, Ph.D., D. C. Mengle Hawaii ESP Project H. W. Klemmer, Ph.D., W. Takahashi Idaho ESP Project D. Brock, Ph.D., P. Smith Michigan ESP Project A. W. Bloomer, A. D. Oudbier Mississippi ESP Project B. F. Barren tine, Ph.D., R. Arthur, Ph.D. New Jersey ESP Project R. A. Altaian, M.D., F. Marshall Texas ESP Project C. A. Nau, M.D., D. E. Foster, Ph.D. Utah ESP Project J. W. Southwick, Ph.D., D. A. Hilden, Ph.D. Washington ESP Project J. Allard, Ph.D., D. F. Nash Consultants: E. E. Moore - Kentucky Department of Human Resources W. Sitterly, Ph.D. - Clemson University J. B. Kissam, Ph.D. - Clemson University R. L. Miller, Ph.D. - Horticultural Consultant, Orlando, Florida Appreciation is also expressed to the numerous State Pesticide Coordinators, State Extension Services, state and federal agencies, industries and utilities which responded to our survey. ii ------- LIST OF-FIGURES Page 1. USA 1974 Pesticide Usage in Agriculture, Government, and Industrial Sectors 9 2. Pesticide Usage in USA by EPA Region, 1974 21 3. Estimated Pesticide Usage IN USA by Class of Compound, 197*4 23 4. Estimated Pesticide Usage in USA by Type of Compound, 1974 25 iii ------- LIST OF TABLES Page 1. Estimated Pesticide Usage for USA and EPA Regions by Type of Use, 1974 10 2. Estimated Pesticide Usage for Region I and States by Type of Use, 1974 11 3. Estimated Pesticide Usage for Region II and States by Type of Use, 1974 12 4. Estimated Pesticide Usage for Region III and States by Type of Use, 1974 13 5. Estimated Pesticide Us.age for Region IV and States by Type of Use, 1974 14 6. Estimated Pesticide Usage for Region V and States by Type of Use, 1974 15 7. Estimated Pesticide Usage for Region VI and States by Type of Use, 1974 16 8. Estimated Pesticide Usage for Region VII and States by Type of Use, 1974 17 9. Estimated Pesticide Usage for Region VIII and States by Type of Use, 1974 18 10. Estimated Pesticide Usage for Region IX and States by Type of Use, 1974 19 11. Estimated Pesticide Usage for Region X and States by Type of Use, 1974 20 12. Estimated Pesticide Usage for USA and EPA Regions by Class of Compound, 1974 24 13. Estimated Pesticide Usage in USA by EPA Region and Type of Compound, 1974 26 14. Estimated Pesticide Usage for USA by Major Crop and Class of Compound, 1974 27 15. Estimated Pesticide Usage for USA by Major Crop and Type of Compound, 1974 29 iv ------- Page 16. Estimated Pesticide Usage for USA by Government and Class of Compound, 1974 30 17. Estimated Pesticide Usage for USA by Government and Type of Compound, 1974 ...... 31 18. Estimated Pesticide Usage for USA by Elements of Industry and Class of Compound, 1974 32 19. Estimated Pesticide Usage for USA by Elements of Industry and Type of Compound, 1974 34 20. Estimates of U.S. Pesticide Usage in Agriculture, Government, and Industry by Type of Use and Generic Name, 1974 35 21. Twenty-Five Leading Pesticides as Estimated by ESP Survey, 1974 45 ------- INTRODUCTION AND BACKGROUND Parties with vested interests in the production, sales, use, and regulation of pesticides have long sought pesticide use information for competitive and enforcement reasons. Immediately apparent are four other reasons for the need for an inventory of the pesticides which are disbursed to our environment. (1) The most cogent of these is to modify the stereotyped image cf pesti- cides, per se, as being an evil biocidepesticides, which are an important factor in food and fibre production, are a conglomerate of chemical classes and varying acute and chronic toxicities. It would not be unreasonable to assume that certain of these chemicals are more harmful to the ecosystem than others. (2) From an economic viewpoint, an inventory of use would assist in the evaluation of the impact of continuance or discontinuance of certain pesticides and would provide baselines so that secular trends of use be identified. (3) From an epidemiologic viewpoint, specific use data may serve as the denominator for the Incidence of acute poisoning and other diseases. (4) Additionally, determination of usage pacterns may assist in the identification of potential areas of concern (for example, in cotton where experienced workers are employed or in vegetable crops where migrant workers are engaged). The reader is encouraged to accept the data as a beginning in the acquisition of more precise national information. The basis of the agricultural pesticide estimation process reported herein was that die leading pesticides on the seven leading crops in each state were ------- - 3 - identified and quantified by established guidelines which called for the most knowledgeable persons available to estimate their use, thus, the knowledgeable concept method used in the agricultural section of this survey. The most recent and extensive survey of pesticide usage is found in the Midwest Research Institute's "Production, Distribution, Use, and Environmental Impact of Selected Pesticides," published in 1974. This summary, which reports usage for 1972, presents data in the four elements of usage (agriculture, government, industry, and home and garden) and focuses upon 25 leading compounds. The Economic Research Services of the United States Department of Agriculture perlodocally surveys pesticide usage; the latest report published in 1974, Farmers' Use of Pesticides 2 in 1971. This survey presents the agricultural element of usage and derives estimates through expansion of use patterns found in a sample survey of farmers. The Agricultural Stabilization and Conservation Service, also part of the USDA, has published on an annual basis since 1953 The Pesticide Review, This publication makes available data concerning the trends, production, and trade of pesticides but provides scant information on specific compounds. The latest publication in this series is The Pesticide Review 1974, published in September 1975, and provides sales and trade data for 1973 and some data for 1974. There have also been a limited number of statewide surveys by local agricultural extension 4 5 personnel; Kansas, 1974 and Arizona, 1974. Pennsylvania surveyed its agricultural pesticide usage for 1973, but as with Kansas and Arizona, these were special studies and not performed on an annual basis. The Epidemiologic Studies Program of the Environmental Protection Agency (EPA) have published information on a limited number of compounds since 1967, ------- - 4 - but these data are representative of small geographic areas. The state of California has made the greatest contribution of pesticide usage monitoring since the institution of a mandatory usage reporting system in 1970. Annual reports are published by the first quarter of the following o year. The Pesticide Use Report by Commodity 1974 and the Pesticide Use 9 Report 1974, prepared by the California Department of Food and Agriculture, provides complete usage information for agriculture, government, and industry. Although some usage data on the state level are available as indicated, local or urban pesticide usage data are more elusive. This point was reported by the Consad Research Corporation in their report to the Environmental Protection Agency, "A Study of the National Scope of Urban Pesticide Runoff," published November 1974. The authors stated that after ". . .a comprehensive literature search, including computerized data bases . . . ; and a survey of state agricultural extension services, little hard data on urban pesticide usage were obtained." The preceding paragraphs have presented current published research efforts toward pesticide usage estimates. Private market research agencies, in recent years and today, carry out usage surveys for pesticide manufacturers; but since their reporting is on a confidential basis, the data are unavailable to concerned government agencies and the public. Reports of this type may contain valuable and timely information since the reports are frequent and usually generated within a year of pesticide application. The need for definitive and timely pesticide usage reports is quite clear and was recently expressed by the Executive Committee of the National Academy of Sciences in Volume I of their Contemporary Pest Control Practices and Prospects, 1975. This publication recommended the collaboration of the USDA and EPA in a joint effort to improve methodologies ------- - 5 - and frequency of pesticide usage surveys and that these surveys should include non-agricultural use. METHODS AND PROCEDURES A distinct survey method was used for each component of pesticide usage, i.e., agriculture, industry, and government. The agricultural survey protocol called for pesticide usage estimates to be made by each state's Pesticide Coordinator, vho vas thought to be the most knowledge- able contact for his respective state. When contacted, the coordinator was asked to estimate usage on his state's seven leading crops taking into consideration number of applications per chemical per crop, acreage treated, and application rate. Forty-four^ state Pesticide Coordinators or Chemical Specialists cooperated with the survey. Additionally, agricul- tural usage estimates for three states were derived from state regulatory agency data. In two states, estimates were made by survey personnel and in one state, estimates were made by a consulting firm. Industrial pesticide usage was considered by public utilities and pest control operations. Public utilities, which included railroads, electric, gas, telephone, and water companies, were surveyed in all states and in each instance, response rates exceeded 852. The survey of pest control firms required individualized techniques and a. variety of approaches because of the diversity of operations. National, regional, and local pest control concerns, as well as national distributors of pest control chemicals, were contacted. Estimates from these sources reflect a consolidation of all source data and were carefully audited to eliminate double reporting. ------- - 6 - The survey of governmental usage included state divisions of public health, transportation, park and forest operations and all federal agencies. Of all state agencies contacted, only two failed to respond. Thirty-four state health departments, 47 state highway departments, and 46 park and forest agencies reported pesticide usage for 1974. Federal respondents included military installations; the Department of Agricul- ture's Soil Conservation, Animal and Plant Health Inspection, and National Forest Services; Corps of Engineers; the Postal Service; and the Depart- ment of the Interior. Quality Control Twenty-nine pesticides were chosen for validation; ten by random selection and the remainder because of their current toxicological importance and widespread use. Manufacturers cooperated by supplying, in confidence, their own estimates of use for 23 of them. The mean ratio of survey estimates to manufacturer estimates was .83, with 95Z confidence limits of .69 - .98. Agriculture Quality control of agricultural data encompassed four procedures: (1) checking estimator's acreage base for all crops against reported acreage of USDA's Statistical Reporting Service, (2) having crop specialists review the consistency of reported use with current practices in six randomly selected states and 22 crops, (3) mechanical verification of submitted data with computer output, and (4) auditing the reliability of data from six randomly pre-survey selected states and four chemicals ------- - 7 - per state. These quality control procedures suggested minimum variances: (1) Of 196 acreage comparisons, 1% were in error and required a change in estimates. (2) Of 20 crops reviewed, one required a change in estimate. (3) The mechanical audit found no coding, keypunching, or retrieval errors. (4) The reliability (reproducibility) of the estimation process was 83%. There were two variances - one of a 5.4% and one of an 3.6% magnitude. One of these variances was attribut- able to improper labeling and would extrapolate to an overall estimate error of about 1%. Industry - PCO A preliminary validation of PCO data was made using extrapolations of usage and market data from a national pest control firm. These findings are presented in the "Discussion" section. Industrial Utility and Government Upon completion of survey activities, each surveyor was contacted for an audit to verify that all appropriate utilities and government agencies were surveyed. Additionally, a stratified random sample of five states was selected along with two government and four utility respondents' reports (randomly selected) from each state. The procedure was to contact at least one respondent from government and two from industry from each state to obtain verification of their originally submitted data. Those respondents who could locate the data in their files responded identically ------- - 8 - to their suKiicted estimates. However, of seventeen agencies contacted, five responded. RESULTS Nine hundred and three million pounds of all type pesticides were reported used by the survey methods employed in this study of pesticide usage in the United States in 1974. Almost 94% of the total was in agriculture with about 3%% in government and 2*$% in industry (Figure 1). The greatest use of pesticides occurred in the EPA Regions IV and VI, which encompass the Southeast and mid-south states. Low use areas were in the Northeast EPA Regions I and II. These nationwide use figures by EPA region and sector are shown in Table 1. Tables 2-11 present similar data for each EPA region and indivi- dual state and shows that the greatest usage of all type pesticides occurred in California, 90 million pounds; Texas, 89; Iowa, 59; Illinois, 49; Florida, 47; Mississippi, 42; and Arkansas, 41. Those states having the lowest amounts in all sectors were Alaska, New Hampshire, Rhode Island, Vermont, Nevada, and Utah; each area having reported less than one million pounds. Agricultural applications generally were responsible for the > high or low rankings. Governmental use was greatest in Florida and Texas and lowest in Alaska and New Hampshire. The greatest industrial uses of pesticides were in the Southeastern states and lowest in the mid and west northern tier of states. Figure 2 displays proportional usage in agriculture, government, and industry for each region. As may be seen from the tabular data, the proportion attrituable to industry may be ------- Figure 1 USA 1974 PESTICIPE USAGE IN AGRICULTURE, GOVERNMENT, AND INDUSTRIAL SECTORS ------- Table 1 ESTIMATED PESTICIDE USAGE1 FOR U.S.A. AND EPA REGIONS BY TYPE OF USE, ]974 EPA REGION I II III IV V VI VII VIII IX X U.S. Total in million pounds o Totals reported Agriculture 6.1 12.7 19.5 213.8 140.1 159.1 127.5 37.9 104.5 26.0 847.2 of active ingredient Government .7 1.8 1.4 14.1 2.1 5.8 .8 .9 2.5 2.7 32.8 7 Industry ' 1.1 1.6 2.8 9.4 2.1 1.7 1.2 .7 2.2 .4 23.2 Total 7.9 16.1 23.7 237.3 144.3 166.6 129.5 39.5 109.2 29.1 903.2 I o> i ------- Table 2 ESTIMATED PESTICIDE USAGE1 FOR REGION I AND STATES BY TYPE OF USE, 1974 REGION I Connecticut Maine Massachusetts New Hampshire Rhode Island Vermont TOTAL Agriculture 1,111 2,669 1,455 167 328 331 6,061 Government 13 491 80 8 82 14 688 2 Industry 315 47 568 30 71 40 1,071 Total 1,435 3,207 2,103 205 481 385 7,820 In thousand pounds active Ingredient ^Reported ------- Table 3 ESTIMATED PESTICIDE USAGE1 FOR REGION II AND STATES BY TYPE OF USE, 1974 Agriculture Government REGION II New Jersey 2,435 870 New York 10,288 940 TOTAL 12,723 1,810 2 Industry Total 678 3,983 896 12,124 1,574 16,107 In thousand pounds active ingredient 2Reported ------- Table 4 ESTIMATED PESTICIDE USAGE FOR REGION III AND STATES BY TYPE OF USE, 1974 Agriculture Government Industry Total REGION m Delaware Maryland Pennsylvania Virginia West Virginia TOTAL 1,158 3,022 7,589 6,800 899 19,468 77 352 302 668 26 1,425 108 871 866 741 247 2,833 1,343 4,245 8,757 8,209 1,172 23,726 in thousand pounds active ingredient ------- Table 5 ESTIMATED PESTICIDE USAGE FOR REGION IV AND STATES BY TYPE OF USE, 1974 REGION IV Alabama Florida Georgia Kentucky Mississippi North Carolina South Carolina Tennessee TOTAL Agriculture 18,742 34,216 31,427 9,002 40,650 35,097 27,944 16,708 213,786 Government 179 11,236 110 239 477 632 673 540 14,086 Industry 885 2,018 1,634 642 494 1,421 1,618 666 9,378 Total 19,806 47,470 33,171 9,883 41,621 37,150 30,235 17,914 237,250 in thousand pounds active Ingredient ------- Table 6 ESTIMATED PESTICIDE USAGE ' FOR REGION V AND STATES BY TYPE OF USE, 1974 Agriculture Government Industry Total REGION V Illinois Indiana Michigan Minnesota Ohio Wisconsin TOTAL 48,537 24,315 16,581 25,750 13,936 10,991 140,110 241 446 698 314 261 149 2,109 617 547 462 46 348 112 2,132 49,395 25,308 17,741 26,110 14,545 11,252 144,351 in thousand pounds active ingredient ------- Table 7 ESTIMATED PESTICIDE USAGE FOR REGION VI AND STATES BY TYPE OF USE, 1974 Agriculture Government Industry Total REGION VI Arkansas Louisiana New Mexico Oklahoma Texas TOTAL 39,687 25,250 2,429 7,260 84,488 159,114 1,045 336 375 125 3,896 5,777 349 365 45 293 650 1,702 41,081 25,951 2,849 7,678 89,034 166,593 In thousand pounds active Ingredient ------- Table 8 ESTIMATED PESTICIDE USAGE FOR REGION VII AND STATES BY TYPE OF USE, 1974 Agriculture Government REGION VII Iowa 58,393 211 Kansas 21,569 204 Missouri 19,161 155 Nebraska 28,355 222 TOTAL 127,478 792 Industry 120 217 693 151 1,181 Total 58,724 21,990 20,009 28,728 129,451 In thousand pounds active Ingredient ------- Table 9 ESTIMATED PESTICIDE USAGE FOR REGION VIII AND STATES BY TYPE OF USE, 1974 Agriculture Government Industry Total REGION VII Colorado Montana North Dakota South Dakota Utah Wyoming TOTAL 12,171 2,566 7,986 9,144 564 5,429 37,860 280 53 83 105 280 133 934 116 9 107 139 51 252 674 12,567 2,628 8,176 9,388 895 5,814 39,468 In thousand pounds active ingredient H oo ------- Table 10 ESTIMATED PESTICIDE USAGE FOR REGION IX AND STATES BY TYPE OF USE, 1974 REGION IX Arizona California Hawaii Nevada TOTAL Agriculture Government 11,194 236 86,031 1,914 6,747 346 498 36 104,470 2,532 Industry 222 1,626 339 53 2,240 Total 11,652 89,571 7,432 587 109(242 In thousand pounds active Ingredient ------- Table U ESTIMATED PESTICIDE USAGE FOR REGION X AND STATES BY TYPE OF USE, 1974 Agriculture Government Industry . Total REGION X Alaska Idaho Oregon Washington TOTAL 11 12 60 83 7,758 609 7 8,374 7,167 735 74 7,976 11,072 1,305 294 12,671 26,008 2,661 435 29,104 In thousand pounds active Ingredient to o ------- Figure 2 PESTICIDE USAGE IN U.S.A. BY EPA REGION. 1974 Industry Government Agriculture N) I-' I ------- - 22 - increased bezau.se agricultural or governmental usage was low or because industrial figures were actually higher than in other areas. As shown in Figure 3 and Table 12, chlorinated hydrocarbons accounted for nearly one-fourth (24%) of the use of all classes of pesti- cides , followed by carbamates and amides (18%), and organophosphates (16%). Arsenic-type materials only made up about 2% of national usage reported in this survey while 40% was attributable to other metals and miscellaneous classes of chemicals. Fifty-one percent of all chlorinated hydrocarbons were used in Regions IV and VI, as well as two-thirds of all organophosphate pesti- cides and over 90% of arsenic-bearing products. Thus, these South- eastern and mid-south regions can be characterized as having used 45%, nearly half, of all pesticides used in the U. S.; one-fourth of all carba- mates and amides; one-half of the chlorinated hydrocarbons; two-thirds of the organophosphates; and nearly all of the arsenicals. Estimated usage by type of pesticides and by EPA region is exhibited in Figure 4 and shows that herbicides dominated with 45% of usage, followed by insecticides, 30%; fungicides, 11%; and nematocides and other products having 14% of the market. Table 13 presents these data by region. The mid-western states in EPA Regions V and VII used 211 million pounds or 52% of all herbicides. The southern states, comprising Regions IV and VI, however, used 180 million pounds (66%) of insecticides, Crop utilization of pesticides, shown in Table 14, indicates that corn, cotton, fruit, soybeans, and vegetable crops used 81% (683 million pounds) of all agricultural pesticides reported by this survey. Three of these crops, corn, cotton, and soybeans, accounted for 506 million ------- Figure 3 ESTIMATED PESTICIDE' USAGE IN U.S.A. BY CLASS OF COMPOUND, 1974 Chlorinated Hydrocarbons (24%) Arsenic (2%) Organophosphates (16%) Caruamates and Amides (18%) 10 LJ ------- Table 12 ESTIMATED PESTICIDE USAGE*FOR U.S.A. AND EPA REGIONS BY CLASS OF COMPOUND, 197/i EPA Region I II III IV V VI VII VIII IX X U.S. TOTAL Chlorinated Hydrocarbons 1.4 2.9 5.2 57. A 39.3 52.6 25.6 11.9 9.6 9.0 214.9 Carbamates and Amides 2.5 4.4 6.7 34.9 49.3 10.4 44.9 5.7 3.9 3.1 165.8 Organo- Phosphates Arsenic .9 3.8 0 3.3 38.6 9.7 6.5 .1 58.1 6.3 12.6 .2 4.9 10.2 .7 6.1 145.0 17.0 Other Metals - .1 .4 .2 13.4 1.8 3.1 .1 .5 44.7 .8 65.1 Other 3.0 4.6 8.3 83.3 47.3 36.1 46.1 16.5 /tO.l 10.1 295.4 Total 7.'J 16.1 23.7 237.3 14/..3 166.6 129.5 39.5 109.2 29.1 903.2 in million pounds active ingredient; 0 » none reported; - » estimate less than .1 million pounds to i. ------- Figure 4 ESTIMATED PESTICIDE USAGE IN U.S.A. BY TYPE OF COMPOUND. 1974 Other and Combination Products (9%) V Insecticides & Acaricides (30%) l-o Ln ------- Table 13 INTIMATED PESTICIDE USAGE IN U.S.A. BY EPA REGION AND TYPE OF COMPOUND, 1974 EPA I 11 III IV V VI VII virr IX X U.S. LLn Region Neniatocides Herbicides 19 763 257 22,168 27 211 3,672 9,697 7,287 4,022 TOTAL 48,123 thousand pounds active 1,823 3,651 11,952 75,504 1J4.618 62,277 96,539 18,032 14,206 9,206 407,808 ingredient Fungicides 1,941 3,765 3,233 24,369 6,602 5,981 755 2,592 45^490 4,178 98,906 Insecticides and Acaricides 2,143 6,495 5,457 86,907 18,851 93,023 22,940 8,325 18,071 8,268 270,480 Other and Combination Products 1,894 1,433 2,827 28,302 4,253 5,101 5,545 822 24,188 3,430 77,795 Total 7,820 16,107 23,726 237,250 1.44,351 166,593 129,451 39,468 109,242 29,104 903,112 I en ------- Table U ESTIMATED PESTICIDE USAGE1 FOR U.S.A. BY MAJOR CROP AND CLASS OF COMPOUND, 1974 Chlorinated Crop Hydrocarbons Field Crops Corn Cotton Hay and Small Grain Sorghum Soybeans Sugar Beets Tobacco Misc. Field Crops (alfalfa, flax, rice, sunflower, sugar cane) Fruit and Nut Livestock and Mink Ornamental and Misc. Vegetables TOTAL 38,909 68,275 19,984 6,465 15.224 585 531 16,338 13,112 2,660 6,111 8,078 196,272 Carbamates and Amides 76.346 7,319 2.784 1.326 37.228 2.478 6,215 3,393 11,213 14 1,299 14,341 163,956 Organo- Phosphates 13,010 79,475 3,273 5,640 2,989 558 4,025 5,267 12,499 4,075 1,328 7,049 139,188 Arsenic 0 15.401 0 0 0 0 0 22 96 0 263 0 15,782 Other Metals 7 3,198 253 - 119 2,930 - 287 53,434 0 77 2.820 63,125 Other 79,140 30,308 4,020 17,509 39.034 14,546 20,763 7.059 36,712 66 2,212 17,379 268,748 Total 207,412 203,976 30,314 30,940 94,594 21,097 31,534 32,366 127,066 6,815 11,290 49,667 847,071 In thousand pounds active ingredient; 0 - none report.d; - - estimate less than .1 thousand pounds ------- - 28 - pounds or 60S of all agricultural pesticides in 1974. Viewed by class of chemical, these three crops used 62% of the chlorinated hydrocarbons, 74% of the carbamates, 68% of the organophosphates, 97% of the arsenicals, and 45% of the other pesticide classes. Table 15 allows an examination of these crops by type of pesti- cide. Sugar beets, tobacco, vegetables, and fruit and nut crops required the greatest amount (87%) of all nematocides reported in the study, while 74% (288 million pounds) of all herbicides were applied to corn, cotton, and soybeans. Fruits, nuts, and vegetables required 83% of all fungi- cides, while using only 8% of the insecticides reported. The major insecticide-using crops in 1974 were corn (34 million pounds) and cotton (145 million pounds), accounting for 70% of the total agricultural estimate. A breakdown by class of compound of governmental estimates (Table 16) shows that chlorinated hydrocarbons comprised the bulk of * usage by both federal and state or local governmental agencies. Organo- phosphate usage ranked second. Similar data for type of pesticide are given in Table 17 and indicate that herbicides and insecticides were the most frequently used of all pesticides. Overall, these tables show pesticide use by state or local governments to be several times that of federal agency use. The use estimates in Table 18 show that in the industrial sector, PCOs used more chlorinated hydrocarbons than any other type. The chlorinated hydrocarbons, in this instance, were comprised mainly of chlordane, aldrin, dieldrin, and heptachlor. Organophosphates accounted for only 8% of industrial usage, made up mostly of malathion and ------- Table 15 ESTIMATED PESTICIDE USAGE1 FOR U.S.A. BY MAJOR CROP AND TYPE OF COMPOUND, l'J74 Crop Field Crops Corn Cotton Hay and Small Grain Sorghum Soybeans Sugar Beets Tobacco Misc. Field Crops (alfalfa, flax, rice, sunflower sugar cane) Fruit and Nut Livestock and Mink Ornamental and Misc. Vegetables TOTAL Nematocldes 1,993 - 0 3,046 14,078 11,703 4 6,981 0 1,000 8,528 47,333 Herbicides 161,123 46,822 21,977 23,026 80,724 2,900 7,522 20,652 8,815 0 6,184 6,813 386,558 Fungicides 1,700 5,787 2,142 201 1,168 2,947 526 355 64,695 0 1,436 15,469 96,426 Insecticides & Acarlcides 34,282 145,311 5,943 7,540 8,662 632 2,511 7,870 20,568 6,766 2,222 12,289 254,596 Other 10,307 4,063 252 173 994 540 9,272 3,485 26,007 49 448 6,568 62,158 Total 207,412 203,976 30,314 30,940 94,594 21,097 31,534 32,366 127,066 6,815 11,290 49,667 847,071 10 in thousand pounds active ingredient; 0 = none reported; - - estimate less than .1 thousand pounds ------- Table 16- ESTIMATED PESTICIDE USAGE1 FOR U.S.A. BY GOVERNMENT AND CLASS OF COMPOUND, 1974 Government Federal State and Local U.S. TOTAL Chlorinated Hydrocarbons 1,531 6,971 8,502 Carbamates and Amides 382 619 1,001 Organo- Phosphates 1,207 2,739 3.9A6 Other . Arsenic Metal Other 55 1,505 2,668 646 71 14,415 701 1,576 17,083 Total 7,348 25,461 32,809 In thousand pounds active Ingredient o I ------- Table 17 ESTIMATED PESTICIDE USAGE FOR U.S.A. BY GOVERNMENT AND TYPE OF COMPOUND, J974 Insecticides Other and and Combination Government Nematocldes Herbicides Fungicides Acaricides Products Federal 754 1,334 1,612 2,413 1,235 State and Local 24 10,175 158 3,561 11,543 TOTAL 778 11,509 1,770 5,974 12,778 Total 7,:i/ill 25,461 32,809 in thousand pounds active ingredient I Ul ------- Table 18 ESTIMATED PESTICIDE USAGE1 FOR U.S.A. BY ELEMENTS OF INDUSTRY AND CLASS OF COMPOUND, 1974 Industry Pest Control Operations Utilities Other U.S. TOTAL Chlorinated Hydrocarbons 8,325 1,285 662 10,272 Carbamatea and Amides 367 53 216 636 Organo- Phosphates 1,688 29 70 1,787 Other Arsenic Metal Other 366 244 2,530 48 125 2,058 283 5 4,871 697 374 9,459 Total 13,520 3,598 6,107 23,225 in thousand pounds active ingredient 1.0 IsJ ------- - 33 - diazinon. Of all industrial use, PCO reports accounted for almost 60% of the total. This PCO figure may be underestimated and will be con- sidered further under the "Discussion" section of this report. Insecticides made up 44% of all industrial usage, shown in Table 19; the greatest portion (98%) of this reported by PCOs. Herbi- cides, which ranked second to insecticides, were mostly used by utilities and railroads (included in "Other"). Fungicides, nematocides, and other type products only made up 15% of all industrial use. Table 20 contains a listing of pesticide product estimates in agriculture, government, and industry by type of use and genetic name. This table enumerates 238 chemicals plus a consolidated "Others" item listed at the end of each type. The confidence intervals of data in this table probably would be in the magnitude of 100,000 pounds, but figures down to the thousand levels, may assist in ranking use. The top ranking 25 pesticides have been selected for Table 21 and show the leading products, quality-wise, as judged from the ESP survey estimates. These 25 chemicals account for 75% of all pesticides reported used nationally in 1974 in this study. DISCUSSION AND RECOMMENDATIONS The total pesticide usage estimate for 1974 obtained in this ES? survey, v.i.z., 903 million pounds, is in accord with other national estimates, ' ' but the estimate that almost 94% is in agriculture, 3.5% in government, and 2.5% in industry is at considerable variance with other reports. Other estimates have suggested 55% to 60% of all pesticide usage is in agriculture. ------- Table 19 ESTIMATED PESTICIDE USAGE1 FOR U.S.A. BY ELEMENTS OF INDUSTRY AND TYPE OF COMPOUND, 1974 Industry Pest Control Operations Utilities Other Nematocides Herbicides 12 1,318 0 2,429 0 5,644 Fungicides 310 145 255 Insecticides and Acaricides 10,006 52 203 Other and Combination Products 1,874 972 5 Total 13,520 3,598 6,107 TOTAL 12 9,391 710 10,261 2,851 23,225 in thousand pounds active ingredient; 0 - none reported ------- - 35 - Table 20 ESTIMATES OF U.S. PESTICIDE USAGE1 IN AGRICULTURE, GOVERNMENT AND INDUSTRY BY TYPE OF USE AND GENERIC NAME, 1974 Nernatocides DBCP Dichloropropane/ Di chlor opropene Others Total Nematocides Herbicides Acrolein Alachlor- Amitrole AMS Atrazine Avadex Benefin Bensulide Bentazone Bentranil Bromacil Bromoxynil Butyl ate Cacodylic Acid Agriculture 9,777 37,544 12 47,333 54,390 ± ± 76,244 437 1,183 479 117 11 238 614 28,500 184 Government + 767 11 773 ± 35 130 963 200 17 ± - 230 ± ± 77 Industry 12 ± ± 12 30 16 53 257 307 - ± ± - 549 j ± 30 in thousand pounds active ingredient; - = less than 1,000 pounds; ± = >_ 1,000 £ 10,000 pcands; See Appendix C for totals of Agriculture, Government & Industry ------- Table 20 (Cont'd) - 36 - Calcium Chloride Calcium Cyanamide .Carbyne CDAA CDEC Chlof lurecol Chloramben Chlorobromuron Chloropropham Chlor othaloni 1 Chloroxuron Contact Cyanazine Cycloate Cyprazine 2,4-D Dacthal Dalapon 2,4-DB Dicamba Dichlobenil Dichlorprop Dini t roamine Dini t rophenol Dinoseb Diphenamid Dipropetryn Diquat Diuron DSHA/MSMA Endothall Agriculture ^^ 147 272 51 34 - 11,828 257 877 556 421 36 7,618 1,318 48 26,662 800 2,072 924 1/139 186 - 719 - 8,579 1,264 96 ± 5,075 15,540 90 Government ^ - - - ± ± - - - - ± - - 2,269 25 469 ± 36 33 - ± 105 29 - 24 226 541 21 Industry 760 - - - + - - - - - - - ± - - 1,381 63 92 £ 73 ± ± - ± 16 ± - i 381 427 ± ------- Table 20 (Confd) -37- EPTC Erbon Evik Fatty Alcohols Fenac Fenuron FlTiometuron Fluorodifen Folex/Def Glyphosate Glyphosine Isocil Isopropalin Karbutilate Linuron Maleic Hydrazide MCPA MCPP Metribuzin Molinate Monuron Naptalam Nitralin Nitrofen Norflurazon Paraquat PGP Pebulette Phenmediph am Picloram Agriculture 6,942 - 480 3,842 321 - 5,087 231 5,132 - 76 54 250 - 12,878 1,797 2,398 ± 1,277 1,768 + 4,940 408 127 30 1,005 - 687 68 126 Government + 26 - - 12 ± ± . 19 - + + 13 101 i ± £ + 67 - i - - 29 14 172' Industry ^ ± - + ± ± 11 40 92 ± ± - 12 86 _ ± _ 20 383 _ _ n «; ------- Table 20. (Coilt.'d) - 38 - Profluralin .Prometon Proms tryn Pronamide Propachlor Prop anil Propazine Propham Pyrazon Siduron Simazine Sodium Borate Sodium Chlorate 2,4,5-T TEA TCA TC3 Terbacil Terbutryn 2,4,5-TP Trifluralin Vernolate Others Agriculture 48 6,970 1,160 143 18,931 9,929 1,556 2.43 256 102 4,931 - 7,819 996 - 1,838 396 828 553 22,983 4,708 3,238 Government 156 ± - + 31 - - 257 422 321 324 ± 3,769 - + 82 11 - 252 Indus try 68 ± - ± ± 117 979 2,312 662 16 61 ± 164 - 32 11 - 126 Total Herbicides 386,558 11,508 9,742 ------- Table 2TD (Cont'd) - 39 - Fungicides Anilazine Benomyl Captafol Captan Carboxin Chloranil Chloroneb C-3 Hydrocarbons Copper Cy c loheximi de DCNA Dichlone Dodine Du-Ter Fenaminosulf Ferbam Folpet Formaldehyde Hexachlorobenzene Maneb/Mancozeb Mercuric Chloride Metiram PCNB Phenylphenol PMA Sulfur Terrazole Thiabendazole Thiram Agriculture 360 2,467 1,898 4,813 176 3,695 755 308 4,975 - 243 34 263 376 35 769 181 '- 36 10,704 - 2,455 1,913 80 254 56,606 88 10 1,322 Government ± ± - 13 - 13 ± ± 1,548 i - - ± ± + - ± - 20 - - 37 - 19 i 73 Industry 61 47 ± 27 - 37 13 - 260 + ± - 12 98 i - 18 _ ± 36 _ » mm ------- Table 20 (Cont'd) - 40 - Agriculture Zineb Ziram Others Total Fungicides Insecticides and Acarici.des Acaraben Aldrin Azinphosmethyl Azodrin Bacillus thuringiensis Benzene Hexachloride Bidrin Bux Carbaryl Chlordane Chlordime form C-l Hydrocarbons Chlorpyrifos Ciodrin Copper Acetoarsenite Coumaphos Cresylic Acid Cruf ornate Cryolite Cyhexatin DDT DDVP Deet 1,538 51 21 96,426 2,448 11,565 6,731 1,906 220 ± 213 1,452 18,066 2,665 4,408 124 ± 255 + 617 - 310 342 269 + 416 - Government ± ± 47 1,770 _ ± ± ± - ± ± - 600 519 - 17 - 19 ± 13 - - - 468 ± - Industry 20 37 44 710 ± 833 ± - - 19 - - 280 5,420 ± - 219 - - - - - ± - 81 ± ------- Table 20 (Cont'd) - 41 - Delnav Demeton Demeton, Methyl Dialiphor Diazinon Dicofol Dieldrin Dimethoate Disulfoton DMP Dyfdnate Endosulfan Endrin EPN Ethion Famphur Fenthion Heptachlor Kepone Lead Ar senate Leptophos Lethane Lindane Malathion Methpxychlor Methyl Parathion Me th ami dophos Methidathion Mevinphos Mexacarbate Mi rex Agriculture 63 120 343 100 3,349 833 168 1,993 6,4-51 - 2,599 1,602 1,270 1,119 2,815 356 16 1,958 - 334 14 - 324 5,521 1,693 63,418 552 303 353 ± Government ^^ + - - 65 ± 29 + ± - + ± ± ± - 86 14 + + 3 ± 3,268 70 29 - 55 67 Industry + ± ± - 536 ± 86 i ± - - + ± - ± - 38 679 ± 53 - - 11 773 96 ± - - i a ------- Table 20 (Cont'd) - 42 - Naled Organotin Parathion Per thane Phorate Phos alone Phosmet Phosphamidon Phos toxin Propargite Propoxur - Pyrethrum Ronnel Rotenone Sodium Fluoride Sulfuryl Fluoride Temophos TEPt Tetrachlorvinphos Tox£phene Trichlorfon Trithion Others Total Insecticides Combination Products Agriculture 1,016 109 13,609 118 7,804 263 1,378 540 - 976 11 12 567 ± - - ± 49 73 74,469 449 201 273 254,596 and Rodenticides Government 235 - 26 - ± - - - ± - 20 + + ± - - 71 - ± 56 80 - 164 5,974 Indus try ± - 26 - ± - - ± ± - 39 44 ± ± ± 314 ± - ± 148 42 - 173 9,910 Aldicarb 1,459 Arsenic Sulfide - 39 ------- Table 20 (Cont'd) - 43 - Agriculture Government Industry Butoxy Polypropylene Glycol - 54 Carbofuran 12,327 ± Carbon Bisulfide 27 Chlorophacinone - - 50 Chloropicrin 85 14 Dinocap '203 Oiphacinone - - ± DNOC 505 ± Ethoprop 2,654 Ethylene Dibromide 1,710 ± 11 Fensulfothion 1,940 - ± Lime Sulfur 1,157 ± Metam-sodium 51 ± Methomyl 4r118 Methyl Bromide 5,177 279 340 Morestan 145 Oxamyl 24 - - para-Dichlorobenzene - ± Petroleum Oil 29,053 12,203 1,841 Pindone - ± + Pine Oil - - 19 Piperonyl Butoxide ± ±44 Silica Gel - ± Sodium Arsenite 87 20 238 Strychnine 12 ± Tetrachloroethylene - ± TFN - 107 Vorlex 417 32 Warfarin - 10 23 ------- Table 20 (Cont'd) - 44 - Agriculture Government Industry Others 1,007 75 231 Total Combination Products 62,158 12,779 2,851 TOTAL ALL PESTICIDES 8.47,071 32,809 23,225 ------- Table 21 TWENTY- FITZ HAD ING PESTICIDES AS ESTIMATED BY ESP SURVEY, 1974 Rank of Use 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Pesticide Atrazine Toxaphene Methyl Parathion Sulphur Alachlor Petroleum Oil Dichloropropane/ Dichloropropene 2,4-D Butylate Trifluralin Carbaryl Propachlor DSMA/MSMA Parathion Linuron Aldrin Car bo fur an Chloramben Maneb /Mancozeb Sodium Chlorate Prop anil DBCP Malathion Dinoseb Chlordane TOTALS Lbs. A.I. (million) 76.8 74.7 63.4 56.6 54.4 43.1 38.3 30.3 28.6 22.9 18.9 18.9 16.5 13.7 12.8 12.4 12.3 11.8 10.8 10.5 9.9 9.8 9.6 8.7 8.6 674.3 % U. S. Total 8.5 8.3 7.0 6.3 6.0 4.8 4.2 3.4 3.2 2.5 2.1 2.1 1.8 1.5 1.4 1.4 1.4 1.3 1.2 1.2 1.1 1.1 1.0 .9 .9 74.6 Agriculture, government & industry usage reported in this survey. ------- - 46 - Four assignations may account for this variance: (1) The ESP study may have overestimated agriculture, (2) the ESP project may have underestimated government and industry use, (3) the ESP survey did not consider household applications, or (4) estimates from other studies may be faulty. Validation testing, however, on 61% of the total usage reported in this survey suggested an under-reporting for the aggregate of agri- culture, industry, and government. One of the national PCO concerns (not identified here in order to protect its data given in confidence) supplied pesticide usage and marketing figures for each state of its business operations. The market share data represented households treated by this concern and when com- pared to the number of households in the country, a national market share was derived. With a national market share figure and the total pounds of active ingredient pesticides used by this company in 1974, a national PCO usage figure could then be extrapolated. This extrapolated estimate came to 15,850,000 pounds active ingredient, some 2,330,000 pounds over the usage survey estimate of 13,520,000 pounds. If the pesticide usage and market share data supplied by this concern are correct and representative of tne PCO industry, then the PCO usage estimate of this survey is within 15Z of actual PCO usage. As regards industries besides PCOs, certain industrial chemicals, such as pentachlorophenol and sodium chlorate, were not entirely within the purview of the ESP survey protocol. Contacts with knowledgeable industry sources suggest that the ESP study for agriculture may have underestimated usage of sulfur and copper ------- - 47 - fay 100%. This difference in sulfur probably occurred because of consistant under-reporting by users in California and confused patterns of usage in Florida. It is possible that study consultants in this latter state over- estimated use of synthetic miticides, when indeed most citrus growers continued to use sulfur. The problem with copper may have occurred because of misunderstanding of the types of copper needed to be reported. For instance, industry's estimate may have contained nutritional uses of copper. By the same token, one leading manufacturer, whose products account for 10% of this study's total estimate, declined to react to his products' estimate except to indicate that on some of them the ESF figures were as much as three fold too high. In summary, however, the authors of this report believe that on balance, weighing under- and overestimates, the agricultural pesticide estimate reported in this survey approximates total actual usage in 1974. Governmental use figures are considered to be adequate since they were obtained from a user survey and validated, in many instances, by official reports. The data reported by this study provide potentially fertile information for epidemiologic studies. These data identify high and low usage areas which may be the starting point of mortality and morbidity studies. Additional detail about class of. chemical compound or the type of farmer which has the greatest exposure potential is a~".so available and may be examined across a gradient of use. Factors which may have biased this study arose mostly in connec- tion with inadequate training of some field investigators, apparent ineffective contacts with USDA by EPA (OPP) and contract personnel, apprehension about (if not animosity toward) motives and purposes of ae ------- - 48 - study by USDA officials and extension personnel, timing of the survey, inadequate cooperation and response from PCOs and distributors ot PCD supplies. Three of the four quality control features of this study functioned well and effected good results. The fourth method, while not entirely satisfactory, suggested a good level of reproducibility in the agricul- tural estimates. In summary, it is felt that the objectives of the survey were met. These being (1) to provide denominator data for the development of incidence of poisonings and other health effects, (2) to determine usage patterns which may assist in the identification of potential areas of concern, (3) to have available data which may assist in the evaluation of the economic impact of discontinuance of chemicals, and (4) to provide baseline data so that secular trends of usage may be identified by sub- sequent surveys. Recommendations The authors recommend that a feasibility study be undertaken jointly by the U. S. Department of Agriculture and EPA to examine esti- mation mechanisms. Such a study might consider the time and funding required for: a) a sampling program b) utilizing a panel of users, strategically located c) the "Knowledgeable Concept Method" used in this study d) a reporting of deliveries by distributors and formulators ------- - 49 - Uses of Data Finally, the readers of this report are asked to carefully consider how this pesticide usage information might be utilized. Initially, information about patterns of use and quantities applied should provide an inventory of environmental pressures. These pressures could be of an adverse nature with a direct influence on the natural environmental control system and a beneficial effect (perhaps balancing effect) via indirectly relieving disease or pestilence and synergizing food production. Thus, a beginning may be made to assess the effect of pesticides on our environmental system's equilibrium. Another application of this knowledge about pesticide practices would be to assess chronic and acute human health effects of the chemicals used and may be the most immediate and pressing of all possible uses. SUMMARY Nine hundred and three million pounds of all type pesticides were reported in this survey of the United States for 1974. Almost 942 of this was in agriculture, with 3.52 in government, and 2.52 in industry sectors. The greatest use of pesticides occurred in the Southeastern and mid-southern states. Low use areas were in the Northeastern part of the United States. Inspection of the data, following analysis of possible bias, quality control, and validation procedures, suggest a slight underesti- mation of use in the agricultural and industrial sectors. Data from this survey provide potentially fertile information for epidemiologic studies by identifying high and low pesticide use areas, ------- - 50 - by giving application patterns by class of compound, and by recognizing the type of fanner having the greatest exposure. The survey utilized gathered data from the agricultural area, utilities, federal, and state governmental agencies, and estimates from leading pest control operators. The objectives of the survey were to provide a reliable pattern of use and an inventory of the chemicals dis- bursed to the environment, to serve economic, health, and ecologic purposes. ------- - 51 - REFERENCES 1. von Ruaker, Rosenarie, et al. "Production Distribution, Use, and Environmental Impact Potential of Selected Pesticides," Contract No. EQC-311 for the EPA, 1974. 2. Farmers' Use of Pesticides in 1971, Agricultural Economic Report No. 252, Economic Research Service, U. S. Dept. of Agriculture, 1974. 3. The Pesticide Review 1974, Agricultural Stabilization and Con- servation Service, U. S. Dept. of Agriculture, 1975. 4. "Kansas Pesticide Usage Survey 1974," Cooperative Extension Service, Kansas State University/USDA, January 1976. 5. "Agricultural Use of Pesticides in Arizona," College of Agriculture, University of Arizona, 1975. 6. "A Review of Pesticide Usage in Pennsylvania Agriculture," Bureau of Community Environmental Control, Pennsylvania Dept. of Environmental Resources, Contract No. 68-02-0351 for the EPA, 1975, 7. a) Hawaii ESP Project, Annual Report No. 6, Pacific Biomedical Research Center. b) Iowa ESP Project, Annual Report, University of Iowa. c) South Carolina ESP Project, 1970 Quarterly Report, Medical University of South Carolina. d) Mississippi ESP Project, Quarterly Report So. 20 (1973), Mississippi State. 8. Pesticide Use Report by Commodity 1974, California Dept. of Agri- culture, Agricultural Chemicals and Feed, Sacramento, Cal., 1975. 9. Pesticide Use Report 1974, California Dept. of Agriculture, Agri- cultural Chemicals and Feed, Sacramento, California, 1975. 10. Kennedy, Ralph, et al. "A Study of the National Scope of Urban Pesticide Runoff," Contract No. 68-01-2225 for the EPA, p. ix, November 15, 1974. 11- Contemporary Pest Control Practices and Prospects: The Report of the Executive Committee, Vol. I. National Academy of Sciences, Washington, D. C., 1975. ------- - 52 - INDEX Page AAtack (see Thiram) 39 AAtrex (see Atrazine) 35 Abate (see Temophos) 42 Acaraben 40 Acrolein 35 Acti-dione (see Cychloheximide) 39 Aero Cyanamid (see Calcium Cyanamide) 36 Agitol (see Bacillus thuringiensis) 40 Agrosan (see PMA) 39 Agroxone (see MCPA) 37 Akar (see Acaraben) 40 Alachlor 35, 45 Alanap (see Naptalam) 37 Aldicarb 42 Aldrex (see Aldrin) 40 Aldrin 28, 40, .45 Aldrite (see Aldrin) 40 Allidochlor (see CDAA) 36 Ametrex (see Evik) 37 Ametryn (see Evik) 37 Amiben (see Chloramben) 36 Aminotriazole (see Amitrole) 35 Amitrole 35 Animate (see AMS) 35 AMS 35 Anilazine 39 Ansar (see DSMA/MSMA) 36 Aquacide (see Diguat) 36 Aqualin (see Acrolein) 35 Aquathol (see Endothall) 36 Arsenic Sulfide 42 Aspor (see Zineb) 40 ------- - 53 Page Atlas A (see Sodium Arsenite) 43 Atratol (see Sodium Chlorate) 38 Atrazine 35, 45 Avadex 35 Azinphosmethyl 40 Azodrin 40 Bacillus thuringiensis 40 Balan (see Benefin) 35 Banvel (see Dicamba) 35 Barban (see Carfayne) 36 Baron (see Erbon) 37 Basagran (see Bentazone) 35 Baygon (see Propoxur) 42 Batex (see Fenthion) 41 Benefin 35 Benlate (see Benomyl) 39 Benomyl 39 Bensulide 35 Bentazone 35 Bentranil 35 Benzene Hexachloride 40 Betanal (see Phenmedipham) 37 Betasan (see Bensulide) 35 BHC (see Benzene Hexachloride) 40 Bidrinr 40 Bioguard (see Thiabendazole) 39 Bladex (see Cyanazine) 36 Borax (see Sodium Borate) 38 Borea (see Bromacil) 35 Borolin (see Picloram) 37 Bravo (see Chlorothalonil) 35 Brimestone (see Sulfur) 39 Bromacil 35 ------- - 54 - Page Brominal (see Bromoxynil) 35 Bromofume (see Ethylene Dibromide) 43 Brom-O-Gas (see Methyl Bromide) 43 Bromoxynil 35 Buctril (see Bromoxynil) 35 Butacide (see Piperonyl Butoxide) 43 Butoxone (see 2,4-DB) 36 Butoxy Polypropylene Glycol 43 Butylate 35, 45 Butyrac (see 2,4-DB) . 36 Bux 40 Cacodylic Acid 35 Calcium Chloride 36 Calcium Cyanamide 36 Caparol (see Prometryn) 38 Captafol 39 Captan 39 Carbaryl 40, 45 Carbicron (see Bidrin) 40 Carbofuran 43, 45 Carbon Bisulfide 43 Carbon Bisulfide (see Carbon Bisulfide) 43 Carboxin 39 Carbyne 36 Casoron (see Dichlobenil) 36 CDAA 36 CDEC 36 Ceresan (see PMA) 39 Chemox P.E. (see Dinitrophenol) 36 Chloflurecol 36 Chloramben 36, 45 Chloranil 39 ------- - 33 - Page Chlordane 35, 39, 45 Chlordimeform 40 Chlorobenzilate (see Acaraben) 40 Chlorobromuron 36 Chloroneb 39 Chlorophacinone 43 Chloropicrin 43 Chloropropham 36 Chlorothalonil 36 Chloroxuron 36 Chlorpyrifos 40 C-l Hydrocarbons 40 C-3 Hydrocarbons 39 Ciodrin 40 Cobex (see Dinitroamine) 36 Contact 36 Copper 39, 46, 47 Copper Acetoarsenite 40 Co-Ral (see Coumaphos) 40 Corrosive Sublimate (see Mercuric Chloride) 39 Cotofor (see Dipropetryn) 36 Cotoran (see Fluometuron) 37 Coumaphos 40 Cresylic A'cid 40 Crotoxyphos (see Ciodrin) 40 Crufornate 40 Cryolite 40 Cyanazine 36 Cycloate 36 Cycloheximide 39 Cygon (see Dimethoate) 41 Cyhexatin 40 Cyprazine 36 Cyprex (see Dodine) 39 Cythion (see Malathion) 41 ------- - 56 - Page 2,4-D 36, 45 Dacamine (see 2,4,5-T) 38 Daconil (see Chlorothalonil) 36 Dacthal 36 Dalapon 36 Dasanit (see Fensulfothion) 43 DATC (see Avadex) 35 2,4-DB 36 DBCP 35, 45 DCNtf 39 DCPA (see Dacthal) 36 D-D (see Dichloropropane/Dichloropropene) 35 DDT 40 DDVP 40 Dechlorane (see Mirex) 41 Deet 40 Delnav 41 Delphene (see Deet) 40 Demeton 41 Demeton, Methyl 41 Demosan (see Chloroneb) 39 Detamide (see Deet) 40 Dexon (see Fenaminosulf) 39 Dialiphor 41 Diallate (see Avadex) 35 Diazinon 33, 41 Dibrom (see Naled) 42 Dibromochloropropane (see DBCP) 35 Dicamba 36 Dicarbam (see Carbaryl) 40 Dichlobenil 36 Dichlone 39 Dichloropropane/Dichloropropene 35, 45 Dichlorprop 36 ------- - 57 - Page Dicloran (see DCNA) 40 Dicofol 41 Dieldrin 28, 41 Difolatan (see Captafol) 39 Dimecron (see Phosphamidon) 42 Dime tho ate 41 Dimethyl Phthalate (see DMP) 41 Dinitramine (see Dinitroamine) 36 Dinitro (see Dinoseb) 36 Dinitroamine 36 Dinitrophenol 36 Dinocap 43 Dinoseb 36, 45 Dipel (see Bacillus thuringiensis) 40 Diphacin (see Diphacinone) 43 Diphacinone 43 Diphenamid 36 Dipropetryn 36 Diguat 36 Diguat Dibromide (see Diguat) 36 Disulfoton 41 Di-Syston (see Disulfoton) 41 Dithane (see Maneb/Mancozeb) 39 Dithane Z-78 (see Zineb) 40 Diurex (see Diuron) 36 Diuron 36 DMP - 41 DNC (see DNOC) - 43 DNOC 43 DNSB (see Dinoseb) 36 Dodine 39 Dowfume W-85 (see Ethylene Dibromide) 43 Dowicide (see Phenylphenol) 39 Dowpon (see Dalapon) 36 ------- - 58 - Page 2,4-DP (see Dichlorprop) 36 DPA (see Propanil) 38 DSMA/MSMA 36, 45 Dursban (see Chlorpyrifos) 40 Du-Ter 39 Dybar (see Fenuron) 37 Dyfonate 41 Dylox (see Trichlorfon) 42 Dymid (see Diphenamid) 36 Dyrene (see Anilazine) 39 Ectoral (see Ronnel) 42 Ektafos (see Bidrin) 40 Endosulfan 41 Endothall 36 Endrin 41 Enide (see Diphenamid) 36 EPN 41 Eptam (see EPTC) 37 EPTC 37 Erbon 37 Ethion 41 Ethoprop 43 Ethylene Dibromide 43 Ethyl Parathion (see Parathion) 42 Evik 37 Evital (see Norflurazon) 37 Famfos (see Famphur) 41 Famophos (see Famphur) 41 Famphur 41 Fatty Alcohols 37 Fenac 37 Fenaminosulf 39 ------- Page Fenchlorfos .(see Ronnel) 42 Fensulfothion 43 Fenthion 41 Fenuron 37 Ferbam 39 Fermate (see Ferbam) 39 Fernasan (see Thiram) 39 Florocid (see Sodium Fluoride) 42 Fluometuron 37 Fluorodifen 37 Folex/Def 37 Folpet 39 Fonofos (see Dyfonate) 41 Forestan (see Morestan) 43 Forlin (see Lindane) 41 Formaldehyde 39 Fumazone (see DBCF) 35 Fundal (see Chlordimeform) 40 Furadan (see Carbofuran) 43 Glyphosate 37 Glyphosine 37 Guthion (see Azinphcsmethyl) 40 HCB (see Hexachlorobenzene) 39 Heptachlor 28, 41 Hexachlorobenzene 39 Hyvar General Weed Killer (see Isocil) 37 Hyvar X (see Bromacil) 35 Hyvar XL (see Bromacil) 35 Igran (see Terbutryn) 38 Imidan (see Phosmet) 42 IPC (see Propham) 38 ------- - 60 - Page Isocil 37 Isopropalin 37 Karathane (see Dinocap) 43 Karbutilate 37 Kannex (see Diuron) 36 Keithane (see Dicofol) 41 Kepone 41 Kerb (see Pronamide) 38 Kryocide (see Cryolite) . 40 Kuron (see 2,4,5-TP) 38 Lampreelde (see TFN) 43 Lannate (see Methomyl) 43 Lasso (see Alachlor) 35 Lead Arsenate 41 Leptophos 41 Lethane 41 Lime Sulphur 43 Lindane 41 Lintox (see Lindane) 41 Linuron 37, 45 Lorox (see Linuron) 37 Lorsban (see Chlorpyrifos) 40 Maintain (see Chloflurecol) 36 Malathion 28, 41, 45 Maleic Hydrazide 37 Maloran (see Chlorobromuron) 36 Maneb/Mancozeb 39, 45 Manzate (see Maneb/Mancozeb) 39 Marlate .(see Methoxychlor) 41 MCP (see MCPA) 41 MCPA 41 ------- - 61 - Page MCPP 37 Mediben (see Oicamba) 36 Mercuric Chloride 39 Merphos (see Folex/Def) 37 Me tarn-sodium 43 Meta-Systox (see Demeton, Methyl) 41 Methamidophos 41 Methidathion 41 Me thorny1 43 Methoxone (see MCPP) 37 Methoxychlor 41 Methyl Bromide 43 Methyl Parathion 41, 45 Metiram 3 9 Metribuzin 37 Mevinphos 41 Mexacarbate 41 Milogard (see Propazine) 38 Mirex 41 Mocap (see Ethoprop) 43 Molinate 37 Monitor (see Methamidophos) 41 Monocron (see Azodrin) 40 Monuron 37 Morestan 43 MSMA (see DSMA/MSMA) 36 Naled 42 Naptalam 37 Nemagon (see DBCP) 35 NIA 1240 (see Ethion) 41 Nitrador (see DNOC) 43 Nitralin 37 Nitrofen 37 ------- 62 Page Nitrolime (see Calcium Cyanamide) 36 Norflurazon 37 Novege (see Erbon) 37 NPA (see Naptalam) 37 Nudrin (see Methomyl) 43 Off (see Deet) 40 Omite (see Propargite) 42 Ordram (see Molinate) 37 Organotin 42 Orthocide (see Captan) 39 Outfox (see Cyprazine) 36 Oxarayl 43 Paarlan (see Isopropalin) 37 Paracide (see para-Dichlorobenzene) 43 para-Dichlorobenzene 43 Paradow (see para-Dichlorobenzene) .43 Paraquat 37 Parathion 42, 45 Paris Green (see Copper Acetoarsenite) 40 PCNB 39 PCP 37, 46 PDB (see para-Dichlorobenzene) 43 PDW (see Fenuron) 37 Pebulate 37 Penite (see Sodium Arsenite) 43 Perchlorethylene (see Tetrachloroethylene) 43 Perthane 42 Petroleum Oil 43, 45 Phaltan (see Folpet) 39 Phenmedipham 37 Phenylphenol 39 Phorate 42 ------- - 63 - Page Phosalone 42 Phosdrin (see Mevinphos) 41 Phosmet 42 Phosphamidon 42 Phostoxin 42 Phosvel (see Leptophos) 41 Phygon (see Dichlone) 39 Picloram 37 Pindone 43 Pine Oil 43 Piperonyl Butoxide 43 Pival (see Pindone) 43 Planavin (see Nitralin) 37 Plictran (see Cyhexatin) 40 PMA 39 Polyram (see Metiram) 39 Pramitol (see Prometon) 38 Prefar (see Bensulide) 35 Preforan (see Fluorodifen) 37 Premalin (see Linuron) 37 Premerge (see Dinoseb) 36 Pre-San (see Bensulide) 35 Primatol P (see Propazine) 33 Primatol Q (see Prometryn) 33 Princep (see Simazine) 33 Profluralin 33 Profume (see Methyl Bromide) 43 .>* Prometon 33 Prometryn 33 Pronamide 33 Propachlor 38, 45 Propanex (see Propanil) 33 Propanil 33t 45 Propargite 42 ------- - 64 - Page Propoxur 42 Propazine 38 Propham 38 Propy2amide (see Pronamide) 38 Pyramin (see Pyrazon) 38 Pyrazon 38 Pyre thrum 42 Rabon (see Tetrachlorvinphos) 42 Radapon (see Dalapon) 36 s Ramrod (see Propachlor) 38 Randox (see CDAA) 36 Retard (see Maleic Hydrazide) 37 Ro-Neet (see Cycloate) 36 Ronnel 42 Rotenone 42 Roundup (see Glyphosate) 37 Rozol (see Chlorophacinone) 43 Ruelene (see Crufornate) 40 Ruphos (see Delnav) 41 Sancap (see Dipropetryn) 36 Sencor (see Metribuzin) 37 Sevin :(see Carbaryl) 40 Siduxrdn 38 Silica Gel 43 Silvex (see 2,4,5-TP) 38 Silvisar (see Cacodylic Acid) 35 Simazine 38 Sinbar (see Terbacil) 38 Sinox (see DNOC) 43 Sistan (see Metam-sodium) 43 Sodium Arsenite 43 Sodium Borate 38 ------- - 65 - Page Sodium Chlorate 38, 45, 46 Sodium Fluoride 42 Spectracids (see Diazinon) 41 Stabilene Fly Repellent (see Butoxy Polypropylene Glycol) 43 Strychnine 43 Sulfur 39, 45, 47 Sulfuryl Fluoride 42 Supracide (see Hethidathion) 41 Sutan (see Butylate) ' 35 Systox (see Demeton) 41 2,4,5-T 38 Tandex (see Karbutilate) 37 TBA 38 TBZ (see Thiabendazole) 39 TCA 38 TCB 38 Telvar (see Monuron) 37 Temik (see Aldicarb) 42 Temophos 42 Tenoran (see Chloroxuron) 36 TEPP 42 Terbacil 38 Terbutryn 38 Terraclor (see PCNB) 39 Terrazole 39 Tersan (see Thiram) 39 Tersan SP (see Chloroneb) 39 Tetrachloroethylene 43 Tetrachlorvinphos 42 TFN 43 Thiabendazole 39 Thixnet (see Phorate) 42 Thiodan (see Endosulfan) 41 ------- - 66 - Page Thiram 39 Thuricide (see Bacillus thuringiensis) 40 Tillam (see Pebulate) 37 Tobaz (see Thiabendazole) 39 TOK '(see Nitrofen) 37 Tolban (see Profluralin) 38 Torak (see Dialiphor) 41 Tordon (see Picloram) 37 Toxaphene 42, 45 2,4,5-TP 38 Treflan (see Trifluralin) 38 Tributon (see 2,4,5-T) 38 Trichlorfon 42 Trichlorobenzene (see TCB) 38 Tri-Clor (see Chloropicrin) 43 Tri-Fen (see Fenac) 37 Trifluralin 38, 45 Trithion 42 Truban (see Terrazole) 39 Tubotin (see Du-Ter) 39 Tupersan (see Siduron) 38 Vapam (see Metarn-sodium) 43 Vapona (see DDVP) 40 Vapotone (see TEPP) 42 Varitox (see TCA) 38 Vegadex (see CDEC) 36 Vernam (see Vernolate) 38 Vernolate 38 Vidden D (see Dichloropropane/ Dichloropropene) 35 Vikane (see Sulfuryl Fluoride) 42 Vitavax (see Carboxin) 39 ------- - 67 - Page Vondrax (see Maleic Hydrazide) 37 Vorlex 43 VPM (see Metarn-sodium) 43 Warbex (see Famphur) 41 Warfarin 43 Weedar (see 2,4,5-T) 38 Weedol (see Paraquat) 37 Zectran (see Mexacarbate) 41 Zelan (see MCPA) 37 Zineb 40 Zinosan (see Zineb) 40 Ziram 40 Zitox (see Ziram) 40 Zolone (see Phosalone) 42 Zorial (see Norflurazon) 37 *U.S.«OWWBir««W80fBCt'B7t-620-007/3710 ------- |