CONDUCTED BY EPA, REGION III
  AIR QUALI1Y MONITORING BRANCH
SURVEILU\NCE & ANALYSIS DIVISION
   APPENDICES A THROUGH I

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B

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    APPENDIX B



METEOROLOGICAL DATA

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                                                   90    180- -270   360-
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IPO

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   APPENDIX C



TEST PROCEDURES

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                     METHODS   OF
                     AIR  SAM
                              /nfersoc/e/y Comm/Vfee
  American Conference of Governmental  Industrial Hygienists
                           American Chemical Society
                 American Industrial  Hygiene Association
               Association of Official  Analytical Chemists
                      Air Pollution  Control Association
                     American Public Health Association
                     American Public Works Association
                    American Society of Civil Engineers
               American Society of Mechanical Engineers
              American Society for Testing and Materials
                                      Published by
AMERICAN PUBLIC'HEALTH ASSOCIATION
1015 Eighteenth Street, N.W., Washington,  D.C. • 1972

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INTERSOCIETY  COMMITTEE

                                 112
TENTATIVE  METHOD OF  ANALYSIS FOR  FORMALDEHYDE
CONTENT OF THE ATMOSPHERE  (MBTH—
COLORIMETRIC  METHOD—APPLICATIONS
TO  OTHER ALDEHYDES)
43502-02-70T
1. Principle of Method
  1.1 The aldehydes in ambient air are
collected in a 0.05 per cent aqueous 3-
methyl-2-benzothiazolone hydrazone hy-
drochloride (MBTH) solution.  The re-
sulting azine is then oxidized by a ferric
chloride-sulfamic acid solution  to form
a blue cationic dye in acid media, which
can be measured at 628 nm (1,2,3).
  1.2 The  mechanism  of the present
procedure as applied to formaldehyde in-
cludes the following steps: reaction of
the aldehyde with 3-methyl-2-benzothia-
zolone hydrazone, A, to form the azine,
B; oxidation of A to a reactive cation,
C; and formation of the blue cation. D
       Me
        I
S   ^ \
     I     C = N-NH_
X.--^.
            ©
                                    2. Range and Sensitivity

                                      2.1 From 0.03  /xg/ml-0.7 /tg/ml  of
                                    formaldehyde can be measured in  the
                                    color developed solution 112 ml).   A
                                    concentration of 0.03 ppm of aldehyde
                                    I as formaldehyde I can be determined in
                                    a 25 1 air sample based on an aliquot of
                                    10 ml from 35 ml  of absorbing solution
                                    and a difference of 0.05 absorbance unit
                                    from the blank.

                                    3. Interferences

                                      3.1 The following classes  of com-
                                    pounds react wilh MHTFT to produce col-
                                    ored  products.   These  are  aromatic
                                    amines, imino heterocyclics. carhazoles.
                                    azo dyes, stilhenes. Srhiff bases, the ali-
                                CH70
          T
—•[    7     xC = N -N=CH2
                                                      Me
                                                       N
                                                          C = N -
                               Me
                                I
                              ,-N.
                                                      Me
                        ^'-> r     .                   /    /-^^
                        ! L,' i     C = N = N = CH = N - N = C     j''|
                               s-'                   ~*s-   ^
                                                                   199
                          c-a

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 phatic aldehyde 2,4-d'mitrophenyl hydra-
 zones, and compounds containing  the
 p-hydroxy styryl group.  Most of these
 compounds are not gaseous or water sol-
 uble and. consequently, should not inter-
 fere with the analysis  of  water soluble
 aliphatic  aldehydes in  the  atmosphere
"(3).

 4.  Precision and  Accuracy
   The method was checked  for repro-
 ducibility by having three different ana-
 lysts in three different  laboratories ana-
 lyze  standard   formaldehyde  samples.
 The results  listed in  Table  1 agreed
 within ±5 per cent.

 5. Apparatus
   5.1 Absorbers—I All  glass  samplers
 with coarse fritted tube inlet.  Figure 1
 shows an acceptable absorber.)
   5.2 Air metering  device—Either  a
 limiting orifice of approximately 0.5 1pm
 capacity or a wet test meter can be used.
 If a limiting orifice is  used, regular and
 frequent calibration is  required.
   5.3 Air pump—A pump  capable of
 drawing at least 0.5 I of air/min for 24
 hr  through  the  sampling  train  is  re-
 quired.
   5.4 Spectrophotometer—An   instru-
 ment capable of  measuring  accurately
 the developed color at  the narrow ab-
 sorption  band of 628 nm.

 6.  Reagents
   6.1 Purity of chemicals—All reagents
 must be  analytical reagent grade.
   6.2 3-Methyl-2-benzothiazolone hydra-
 zone,  hydrochloride absorbing  solution
 ({>.(>:>  per  cent)—Dissolve  0.5  g  of
 MBTH in distilled water and dilute to 1
 liter.  This colorless solution is filtered
 by gravity, if slightly turbid, and is sta-
 ble  for at least 1 week after which it be-
 comes pale yellow.  Stability may be in-
 creased by storing in a dark bottle jn the
 cold.
   6.3 Oxidizing  reagent -Dissolve  1.6
 g of sulfainic acid and 1.0 g of ferric
 Table 1. Comparison  of Formaldehyde
    Results  from  Three Laboratories
   (Analysis of Standard Formaldehyde
               Samples)

                      Absorbance
 Micrograms/ml    Labors-  Labora-  Labora-
 Formaldehyde    tory 1    tory 2   tory 3
0.05
0.10
0.30
0.50
0.70
0.078
0.151
0.430
0.720
0.990
0.077
0.156
0.457
0.700
1.04
0.082
0.146
0.445
0.728
1.02
chloride in distilled water and dilute to
100 ml.
   6.4  formaldehyde standard solution
"A" (1 me/ml)—Dilute  2.7  ml of 37
per cent formalin solution to 1 liter with
distilled water. This solution  must be
standardized as described in  "Calibra-
tion'' section.  This solution is stable for
at least a 3-month period.
   6.5  Formaldehyde standard solution
"B" (10 pg. ml.)—Dilute  I ml of stand-
ard  solution "A" to 100  ml with  0.05
per cent MBTH solution.  Make up fresh
daily.
   6.6  Iodine 0.1  .V  (approximate)—
Dissolve 25 g of  potassium  iodide  in
about  25  ml of water, add  12.7 g of
iodine and dilute to 1 liter.
   6.7  Iodine 0.01 .V—Dilute 100 ml of
the  0.1  N  iodine  solution  to 1  liter.
Standardize  against sodium thiosulfate.
   6.8  Starch solution 1 per cent—Make
a paste of  1 g  of soluble starch in 2 ml
of water and slowly add the paste to 100
ml of  boiling water.  Cool, add several
nils of chloroform as a preservative, and
store  in a stoppered  bottle.   Discard
when a mold growth is noticeable.
   6.9  Sodium carbonate buffer solution
—Dissolve  80  g of  anhydrous sodium
carbonate  in about  500  ml of water.
Slowly add 20 ml of glacial acetic  acid
and dilute to 1  liter.
   6.10 Sodium bisulfite 1 percent—Dis-
solve I <' of sodium  bisulfite in 100 ml
 200

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                                                                 FORMALDEHYDE
                              APPROX. 140mm
GAS WASHING
BOTTLE 10 ml
and 20 ml.
12/b
                                                            12/5
                                                     3mm O.D.
                                                     22mm 0.0.
                                                            SIDE ARM CONNECTIONS
                                                            MUST BE SAME HEIGHT
                                                            ON RESPECTIVE BOTTLES
                                                     19mm O.D.
                                                     20ml - LENGTH
                              Figure 1—Absorber.
                                                                              201

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of ualtr.   It  i> best lo  prepare a fresh
solution weekly.
7. Procedure
  7.1  'tir   xd/nplinii — Draw   measured
volumes <>f ihe \apor laden air at a rate
of O.o Ipiii  for 21  lir  through 35 ml  of
MBT1I  absorbing solution  contained  in
ihe absorber.   A shorter sampling  time
can be used providing enough formalde-
hyde is collected to be above the lower
limit of sensitivity  of  the  method.
  The  average collection  efficiency  of
formaldehyde in air has been determined
to be 84 per cent when air was sampled
at a rate of 0.5 Ipm over a 24-hr period
in 35  ml of collecting reagent  (3)  in
an  absorber  equipped with  an  extra
coarse (EC) fritted tube  inlet.  Absorp-
tion efficiency may be improved by using
a coarse (C) frit although data are lack-
ing on (his  likelihood.


  7.2 Analysis.

     7.2.1 Transfer  the samples from the
sampling bottles to  50  nil graduates, di-
lute lo  35 ml  with distilled  water and
allow to stand  for 1 hr.
     7.2.2 Pipet  a  10  ml  aliquot  of
the sampling solution  into  a  glass stop-
pered test tube.  A  blank containing  10
ml  of MBTH solution  must also  be run.
If the aldehyde  content  of the  aliquot
exceeds  the limits of  the  method, a
smaller aliquot diluted to 10 ml with
MBTH  solution is used.
     7.2.3 Add 2 ml of oxidizing solution
and mix thoroughly.
  7.2.4 After  standing for at least  12
min. read at 628 run on a suitable spec-
lr
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                                                                   FORMALDEHYDE
  8.9 Preparation  of standard curve.

     8.9.1. Pipet 0,  0.5,  1.0,  3.0, 5.0,
and  7.0 ml  of standard  formaldehyde
solution "B"  into  100  ml  volumetric
flasks.  Dilute to  volume  with 0.05 per
cent MBTH  solution.   These  solutions
contain 0, 0.05. 0.1. 0.3,  0.5, and 0.7
/tg of  formaldehyde/nil.
     8.9.2. After final dilution let stand
for 1-hour.
     8.9.3. Transfer  10 ml of each  solu-
tion to a glass stoppered test  tube and
add  2 ml of  oxidizing reagent and mix.
     8.9.4. After 12 min read the absorb-
ance at 628  nm in  a suitable spectro-
photometer using  1  cm cells.
     8.9.5. Plot absorbance against mi-
crograms of  formaldehyde/ml of  solu-
tion.

9. Calculation
  9.1 The concentration   of total  ali-
phatic  aldehyde (as  formaldehyde)  in
the sampled  atmosphere may be calcu-
lated by  using the following equation:
  PPM fVol ^ _ C X 35 X 24.4n
  f mi vol.)-• VxMW  x£
      E=correction factor for sampling
          efficiency (0.84 may be used if
          absorber  contains an EC  frit)
      V=liters of  air sampled.
      C=/tg/ml  of   formaldehyde  in
          sampling solution.  (Since each
          sample  is  diluted to 35 ml,
          this figure must be multiplied
          by  35  to   give  total  micro-
          grams in sampling solution.)
  M.W.=molecular weight  of formalde-
          hyde (30.03).
  24.45=ml of formaldehyde gas in one
          millimole  at  760  Torr and
          25 C.

10.  Effect of Storage
   10.1 The time study of the reaction of
microgram quantities of formaldehyde
with 0.05 per cent MBTH shows that the
reaction is complete in approximately 45
min: therefor*1, a reaction lime of I hr
is selected  for this procedure. Formalde-
hyde is  fairly stable in  0.05  per cent
MBTH  since  only  approximately  .5 per
cent of  the  formaldehyde is  lost  after
standing in the VIMTII for 13 day?.  The
samples are. therefore, stable enough for
later analsis
11.  References

1. Sawickl.  E.: T. R.  Hoiivrr: T.  »'.  Slangy:  a"'l
  V(". F.lbcrt.  Thr .|.\lrilivl-2.Bi-nniihia»iluiii- IK. Iran. m-
  Te»t. Anal. Chem. 33 .-93. 1961.
2. Hauler. T. R..  anil  R. I.. Cummin.*.  Inrrro.ins tin-
  Senailivity  of 3-Mohrl-Z-Benzalhiaiolone Hydruone
  Ten for  Analytil of  Aliphatic  Aldehydes  in  Air.
  Anal. Chirm. 37*79. 1964.
3. Hau«er. Thomai R.  Determination  at Aliphatic Al-
  dehyde*:  3>Methv|.2'Benzothiazolone Hydratone  Hy-
  drochloridr I MBTH) Mrlhml. Srlrclnl  Methodi for
  the Measurement of Air  Polliilanft. Public Hrnlili
  Service Publication  ,Vn. MO-AIMl.  Pan- F 1.  19*3.
            ADDENDUM

    Applications  to Other  Aldehydes

  Acetaldehyde and propionic aldehyde
both yield a blue dye after reaction with
3-methyl-2-benzothiazolone  hydrazone
hydrochloride and a ferric chloride-sul-
famic acid solution.  It has been found
that as the length of chain increases, the
sensitivity decreases.   Therefore  when
measuring total  aldehydes as  formalde-
hyde this method would -jive low results
if any aldehyde other than formaldehyde
is present.
  From  0.05  /ig/ml-1.0 n§/m\  of  both
acetaldehyde  and propionic  aldehyde
can be measured  in the color developed
solution  (12 mil.  For the lower con-
centrations the method  has  poor repro-
ducibility.  However,  at higher  concen-
trations  (0.30 /xg/ml and  above) repro-
ducibility was very good.  These  data
are summarized  in Tables A and B.
  Acetaldehyde  (Eastman Kodak Com-
pany, Cat. No. 468) and propionic  alde-
hyde  (Eastman  Kodak Company, Cat.
No. 653) were considered  to be primary
standards when  preparing solutions  of
known concentration.   Exactly  1.28 ml
of acetaldehvtle was diluted to 1 1 with
                                                                               203
                                         c-c.

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                              Table A. Arelaldvhvde

u^, ml
0.05
0.10
0.30
0.50
0.70
1. 00


Mg.'ml
0.05
0.10
0.30
0.50
0.70
I.(H)
Number of
Samples
29
29
29
2')
29
15

Number of
Samples
29
29
29
2'J
29
!.->
Average
Absorbanre
0.063
0.125
0.339
0.519
0.685
0.900
Table R. I'ropinnie
Average
Absorbance
0.046
0.082
0.243
0.399
0.538
0.732

Range
0.050-0.074
0.106-0.144
0.316-0.355
0.49.^0.538
0.660 0.710
0.890 0.910
Aldehyde

KaajiP
0.032-0.057
0.063-0.095
0.225-0.250
0.380-0.422
0.515-0.568
0.710 0.750
% Variance
From Avft.
±20
±15
± 7
± 4
± 3
± 1

'"< Variance
From Avg.
±27
±20
± 5
± 5
± 5
± 2
distilled  water and  then 1  nil of  this
solution  was  diluted  to 100  ml  with
MBTH solution giving a final concentra-
tion  of  10 pg/mi.   Exactly  1.24 ml of
propionic aldehyde  was diluted  to  1 1
with distilled  water and then  1 ml of
this solution was diluted to  100 ml with
MBTH solution giving a final concentra-
tion  of 10 pg/ml. The strong standard
solutions have a 2 month shelf life.  The
dilute standard  solutions must be pre-
pared fresh daily.
  A  series of  34 ambient  air samples
were collected in 35 nil  of MBTH solu-
tion contained in each of two absorbers
in series.  The sampling time was 24 hr
and the sampling rate was 1 liter 'minute.
Collection  efficiencies varied  from  69
per cent to 100 per cent with  the average
for the 34 samples being 82 per cent

                         Subcommittee 4

                  R. C. SMITH. Chairman
                            R. J. BRYAN
                           M. FELDSTEIN
                             B. LEVADIE
                           F. A. MILLER
                         E.  R. STEPHENS
                           N. G. WHITE
204
                                 C-l

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                                                             PHENOLIC COMPOUNDS
and  the  ahsorbanre  mensural  directly
at 510 nin.

8. Standardization  of Phenol  Solu-
tion
   8.1  Stock standard  phenol solution—
prepare a 0.1 per cent solution of phenol
in distilled water.   Into a 500 ml iodine
flask  transfer  50 ml  of stock  standard
and add 100 ml of  distilled water.   Add
exactly 10 ml  of bromide-bromate solu-
tion.   Add carefully  0.5 ml  of concen-
trated hydrochloric acid.  Swirl the flask
gently, making certain that the stopper
is seated.  If.  at this  point, the color of
bromine  does  not  persist, continue to
add exactly 10 ml portions of bromide
bromate solution until  the reddish-brown
bromine color does persist.  If the stock
solution  is made  up  to  cunlain   1000
nig of phenol I, 4-10  ml portions of
bromide  hrnmale  solution will be  re-
quired.   With the stopper  in position
let the reaction flask sit  for 10 minutes.
Add quickly one p  of  potassium iodide.
Prepare a  blank  in   exactly  the  same
manner, using 10  ml of  bromide bro-
mate   solution   and  distilled  water.
Titrate  both  blank  and  sample  with
0.025 ,V sodium thiosulfate. using starch
as indicator.   Calculate  the  concentra-
tion of phenol solution as follows:
   Milligrams   of   phenol  per liter=
[(AX B)—C] X  7.835
A=ml of 0.025 .V thiosulfate used for
    blank.
R=ml of bromide-bromate solution used
    for sample, divided  by 10.
C=ml of 0.025 .V thiosulfate used for
    sample.  The factor. 7.835. is  based
    on the use of  an exactly  0.025 .V
    thiosulfate solution in the  titration.
   !>.2  Primary  standard  phenol  solu-
tion—Dilute the stock standard so  that
1  ml  is equal  to  10 /xg of phenol.
   8.3  Working  standard—Dilute  the
primary  standard  1:10  with  distilled
water.   This solution contains one  ft£.
of phenol in 1 ml.
9.  Calculation

  (J.l  Working  standards  are  used  to
prepare  a concentration  vs absorbance
curve  from  which  the  concentration  of
phenol in samples  is determined.   One
/ig  of  phenol  I  of  air  is equal to 0.26
ppm and one ppm  is equal to 3.84 /ig/1
at 25 C  and standard pressure.


10. Effects  of Storage

  10.1 The  addition of 5 ml  of copper
sulfate solution  to  the  alkaline  solution
of  phenols  will  serve  to  stabilize the
sample.
  10.2 Cautions.
     10.2.1 Equipment  which  has  been
lubricated with  stopcock grease should
not be used.
     10.2.2 Temperature  variations  will
affect  the blank.
     10.2.3 Filtration of the chloroform
extract before reading  it in the spectro-
photometer  will remove  possible  tur-
bidity  due to  presence  of water disper-
sion.
     10.2.4 The  chloroform  extract  of
the dye  will fade on standing.
     10.2.5 It   is   advisable  to  work
quickly  when serial readings are made.


11. References

1. Emenna, E.  I.  The  Condensation of Arninnanti-
  pyrine:  A  New  Teat  (or Phrnolir Compound!.  J.
  Organic Cheat.. 8:417. 1943.
2. F.ttinerr, M. D.; C. C. Ru.-hhoft;  .mil R. J. I.iihk..
  Srnftilive  4>Aminnantipyrine  Nfethod  for  Phennlir
  C.MRi|i.>iinil».  Anal.  Client. --1:1783  1788.  I9SI.
.1. Jurtili*. M. II. Tlir Analytical Chrmiiilry of Inriilitrtal
  INiiaont.  Hazardt  and  Solvents.   Intrr«rienr<» Pub*
  lisliera. 2nd Edition, (pp TO",).
I Mnhler.  K. F.  and T..  N. jamb.   Drl-rmin.itmn ••(
  IMinnnlir.Typ** Compnuitdfl in Watrr and Industrial
  \Va«lr Water-.  \n.il.  C.lii-ni.  ;0:|.1M-nrt. 10".
".. Smih. K.  G.. J. D. MwiKwen; and R.  K. Barmx.
  Sampling and -\niil\.'>9.

                          Suhconiiiiittee I
                     R. G. SMITH, Chairman
                             R.  J. BRYA>
                             M. FELDSTEI^
                               I!. LEVADIE
                             V.  \. MILI.EK
                          E. R. TKHUKN-
                             N. C. \Vnirt
                                                                                  223

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pare according  to classical laboratory
method.

7. Procedure

  7.1 Air Sampling—P articulates. Draw
a 24-hr air sample at a measured flow
rate  through a Hash-fired fiberglass filter
using u  high  volume sampler.1
  7.2 Air Sampling.   Sapors  and I'ar-
ticulates.   Wet method—Draw  a 30 min
sample  lor larger if desired)  of air
through a 0.1 N solution of sodium hy-
droxide in distilled water,  at a standard
impinger flow rale of  one ftY">inule.   If
only vapor phenolics are  required, use
a membrane filter in  the sampling train
to remove particulates.
  7.3 Analysis— (CAUTION—do  not
u.ti' stopcock grease in any apparatus I.
  7.4 Filter samples—Extract  the filter
or any desired portion of it in  a Soxhlet
extractor  by reflux ing with benzene for
3 hours.   Transfer the benzene extract
to  a  separatory  funnel,  filtering   it
through a close (Whatman 42 or equiva-
lent)  paper.  Extract 3 times with  10
ml  portions of  1.0  /V  NaOH.  Treat
according  to Section  7.6 Determination
of Phenols.

  7.5 Samples collected in 0.1  N NaOH.

     7.5.1  Air samples.   Proceed   to
Section 7.6 Determination of  Phenols.
     7.5.2  Exhaust gases or  process
effluents.  Use the whole sample. Add
1 ml of 10 per cent copper sulfale solu-
tion.  Acidify, using  methyl orange  as
indicator  and  10 per  cent phosphoric
acid solution. Transfer to an  all glass
distillation apparatus and distill, collect-
ing 90 ml  of the distillate. Cool the dis-
tillation flask and  add 10 ml of distilled
water.   Continue the distillation  until
exactly 100 ml of distillate has^ liern col-
  1 Proper  method.-,  for calibrating tin-  high
volume sampler  or  other  sampling devices
should-be provided by the manual supplied by
ih«  manufacturer
lecleil.  Acidify  with  0.5  ml of 10  per
cent phosphoric  acid  solution, add  1.0
ml of 10 per rent copper sulfate solution
and transfer to a  separatory funnel. Add
30 g  of  reagent  grade sodium chloride
and extract  with  3-10 ml portions,  of
chloroform.  Discard the aqueous phase.
Shake the chloroform  extract with 2 -15
nd  portions  of O.I N NaOH.  Discard
the chloroform phase.   Meat the alkali
extracts until the traces  of chloroform
have  been  removed, dilute the alkaline
extract to 100 ml volume with distilled
water  and  treat   according to Section
7.6.2.

  7.6  Determination  of Phenols.

    7.6.1 Adjust the  alkaline extracts
to volume of  100 ml.  either by aliquot-
ing or diluting to volume with distilled
water.  Add 1 ml of 10 per cent copper
.sulfate solution.   Acidify  with  10 per
cent  phosphoric  acid  solution  using
methyl orange indicator.   Distill  from
an all glass  distillation apparatus until
90 ml have been collected.  Add  10 ml
of distilled  water to the cooled distilla-
tion flask and continue the distillation
until a total volume of 100 ml of distil-
late have been collected.
    7.6.2 Take a 50  ml  aliquot  of  the
distillate.    Prepare standards  contain-
ing 0.5,  1.0.  5.0. 10.0 and 20.0  Mg  of
phenol.  Adjust  the volumes of sample
and standards to 100 ml  with distilled
water. Add 2 ml of ammonium chloride
solution.  Using  a pH meter  adjust  to
pH 10.0 ±: 0.2. with  concentrated  am-
monium  hydroxide.   Add 1  ml of  4-
aminoantipyrine solution and mix.  Add
L ml of potassium ferricyanide solution.
transfer to a separatory funnel and wait
3  minutes.   Extract  with 3-5 ml por-
tions   of  chloroform  and  discard  the
aqueous  phase.   Make  up  the  chloro-
form  extract  to  a known  volume with
chloroform.  Using a blank as reference.
record the absorbance at 460  nm.  For
higher  concentrations of phenol   the
chloroform  extraction  mav he omillfd
222

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                                                          PHENOLIC  COMPOUNDS
 2.  Range  and  Sensitivity

   2.1  One  cubic  meter of air contain-
 ing 1.3 ppb of phenol  will produce suf-
 ficient sample to give a coupling product
 absorbance of approximately  0.2 units
 in a 20 mm cuvet when measured  at 460
 nm wavelength  in a speotrophotomeler.

 3.  Interferences
   3.1  Any  color,  other  than  that due
 to the reagents used, interferes with  the
 method.  Turbidity, sulfur compounds
 and certain metallic ions interfere (4).
 However,   the   distillation  procedure
 described by Smith eliminates these  in-
 terferences.

 4. Precision and Accuracy
  4.1  Tn  the  range  of 0.49-1.03 ppm
 the standard deviation is 0.022 and  at
 the 95%  confidence  level  0.065.   At
 18—75  ppb the  standard  deviation  is
 3.3 and at the 95?v confidence  level 10.7
 ppb.  Accuracy is plus or minus two per
 cent (4).

 5. Apparatus
  5.1  Smchlet extractors.
  5.2  Distillation  apparatus—all glass.
  5.3  Iodine bottles—500 ml size.
  5.4  Impingers—Standard, midget  or
equipped  with  fritted absorbers  (extra
coarse porosity).
  5.5  Fiber floss filter sheets, flash fired.
  5.6 Spectrophotometer—any  spectro-
photometer  capable  of measuring the
absorbance  of the solution  complex at
460-510 nm. as required.
  5.7  High volume sampler or other air
sampling device for collection of particu-
late samples, equipped with a calibrated
gauge  or flow meter to measure air vol-
ume flow accurately.

 6. Reagents
  6.1  Purity of chemicals.  \ll reasents
should be ACS analytical grade.
   6.2  t-iiiniiiiniiilii>\riiic  .filiation—dis-
solve 2  g of 4-aminoantipyrine in dis-
tilled water and make up to 100 ml. This
solution should not be kept longer than
 I  week.
   (>.3 I'nlussium jerricyanide solution—
dissolve 8 g of analytical  reagent grade
potassium ferricyanide in distilled water
and make up to 100 ml.   Discard  when
the solution becomes  darkened.
   6.4 Ammonium  chloride  solution—
dissolve 50 g of analytical  reagent grade
salt  in  distilled water  and make up to
one liter.
   6.5 Copper sulfate  solution—prepare
a  10 per cent solution of  the pentahy-
drate.
   6.6 Sodium hydroxide sampling solu-
tion—prepare a 1 /V solution.
   6.7 Bromide 'Rromate  solution—dis-
solve 2.784 g of analytical  reagent grade
potassium  bromate  in distilled  water:
add  10  g of analytical reagent  grade
potassium  bromide  and make up  to  1
liter.
   6.8 Ammonium.  Hydroxide—Analyti-
cal reagent grade.
  6.9 Hydrochloric Acid -  Analytical re-
agent grade.
   6.10  Phosphoric  acid solution—pre-
pare a 10 per cent solution  of orthophos-
phoric acid.
  6.11  Potassium Iodide—Analytical re-
agent grade salt.
  6.12 Sodium  thiosuljate  solution—
prepare a 0.1  A solution of the salt and
-tandardi/e according to classical labora-
tory procedures.  Dilute to make an ex-
actly 0.025 V solution.
  6.13 Starch solution—dissolve one  g
of soluble  starch in 100 ml of distilled
water.   Prepare a  fresh solution  daily.
  6.H Phenol—reagent grade.
  6.15 llt'itzene—reagent grade.
  6.16 C.hlorojorm—reagent grade.
  6.17 Methyl  orange  indicator—pre-
                                                                             221

-------
INTERSOCIETY COMMITTEE

                                  116
TENTATIVE  METHOD  OF  ANALYSIS  FOR  DETERMINATION
OF  PHENOLIC COMPOUNDS  IN  THE  ATMOSPHERE
(4-AMINOANTIPYR1NE  METHOD)
I7320-OI-70T
1. Principle  of the Method
  1.1  Air is scrubbed with an alkaline
solution in  u standard  impinger.   Par-
ticulate phenolic substances are collected
by passing air  through a fiberglass Slier.
Phenolic compounds are separated from
other  compounds by  distillation  from
an acidified system.   Phenols are deter-
mined by coupling them with 4-amino-
antipyrine in an alkaline medium  con-
taining an oxidant.
  1.2  The  method is based on a reac-
tion discovered by Emerson (1).  This
procedure is essentially that  of Smith
        N
CH3 -N
         c = o
          I
CH3 -C
         C-NH2

4 iimirio-iintipyrine
                                    ft al (5).  Discussions of theory and
                                    eHiciency are given by Etlinger (2) and
                                    Mohler "(4).
                                      1.3  In the presence of a strong alka-
                                    line oxidizing  reagent this coupling re-
                                    action  will  proceed  as  shown  in  1.4
                                    below.  If the system is not sufficienlh
                                    alkaline dimerization of  4-aminoanti-
                                    pyrine to antipyrine red will take place,
                                    as in 1.5 below.   It is important, there-
                                    fore, to have a high pH when the  cou-
                                    pling reaction  is induced.
                                      1.4  Coupling reaction of 4-aminoanli-
                                    pyrine and phenol

                                             C6HS
                                               I
                                               N
      (OK  CH3-N    C-0
•-OH Tg^gT      !      I
     1B  ' CH3 -C    C-N =
                                                                    •= O
                          phenol
  1.5  Dirnerizalioii  of 4-aminoaalipy-
rine
         i
         N
 CH,-N    C = O
      !      I    i
 CH, - C  = (
                      o = c
               NH2   H^N-C
 N-CH,
 C-CHn
                 F.C/3 !   [O]
                       C8H5

                        N
                 CH3 -C  -  C
                                  HO -C
                            Antipyrine Red.
                                           N
                                           11
                                           i >
                                        -  C-CH3

                                               0
220

-------
criteria for a recommended standard.

   OCCUPATIONAL EXPOSURE
                   TO
            FIBROUS GLASS
  U.S. DEPARTMENT OF HEALTH, EDUCATION, AND WELFARE
                Public Health Service
              Center for Disease Control
               »•
       National Institute for Occupational Safety and Health
                  April 1977
             ml* by the Superintendent of Documents. U.S. Government
               Printing Office. Washington. D.C. 20402

-------
                              IX.  APPENDIX I


                   AIR SAMPLING METHOD - MEMBRANE FILTER
General Reguirements

      The  following  sampling and anlytical methods for fiber counting are

adapted from the NIOSH  membrane  filter  method  for  evaluating  airborne

asbestos fibers [90].

      (a)    Air  samples  representative of the breathing zones of workers

must be collected to characterize the exposure from each  Job  or  specific

operation in each work area.

      (b)    Samples  collected  shall be representative of the exposure of

individual workers.

      (c)    Suggested records:

             (1)    The date and time of sample collection.

             (2)    Sampling duration.

             (3)    Total sample volume.

             (4)    Location of sampling.

             (6)    Other pertinent information.
Sampling


      (a)    Samples  shall  be collected so as to be representative of the


breathing zones of  workers ^ without  interfering  with  their  freedom  of

movement.
                                  \

      (b)    Samples  shall  be  collected  to  permit determination of TWA


exposures for every job involving exposure to fibrous glass  in  sufficient



                                  119

-------
numbers to determine the variability of exposures in the work situation.



      (c)    Equipment



      The sampling train consists of a membrane filter and a vacuum pump.



             (1)    Membrane   filter:    Samples   of  fibrous  glass  are



collected in the breathing zones of the workers using  a  personal  sampler



with ••'cellulose  ester  membrane  filter.  The filter is a 0.8-jan pore size



mixed cellulose ester membrane mounted in  a  open-face  sampling  cassette



which can be attached to the worker near his or her breathing zone.



             (2)    Pump:   A battery-operated pump, complete with clip for



attachment to the worker's belt, capable of operation at 2.5  liters/minute



or less.



      (d)    Calibration



      The  personal  sampling pump should be recharged prior to calibration



and then calibrated against a bubble meter, wet test meter, spirometer,  or



similar  device  at  a  flowrate of 1.0 to 2.5 liters/minute.  The sampling



train used in the calibration (pump, hose, filter) shall be  equivalent  to



the  one  used  in  the  field.   The calibration should be performed to an



accuracy of + 5%.



      (e)    Sampling Procedure



             (1)    Sampling  is  performed  using  an  open-face  membrane



filter cassette.



             (2)    The sampler shall be operated at a flowrate between 1.5



and 2 liters/minute.



             (3)    The  temperature  and  pressure of the atmosphere being
                                  w


sampled are measured and recorded.
                                   120



                                  C-\4

-------
             (4)    One  membrane  filter  is treated in the same manner as

the sample filters with the exception that no  air  is  drawn  through  it.

This filter serves as a blank.

             (5)    Immediately  after  sampling,  personal  filter samples

should be sealed in individual plastic filter holders  for  shipment.   The

filters shall not be loaded to the point where portions of the sample might

be dislodged from the collecting filter during handling.

      (f)    Optimum Sampling Times

      A requirement for a minimum count of 100 fibers or 20 fields has been

determined to be the optimum choice to achieve low variability of the fiber

count  (as  approximated  by  a  Poisson distribution) and reduced counting

times.  In other words, the optimum fiber density on the filter should be 1

to 5 fibers/microscope counting field.  To estimate optimum sampling times,

the approximate field area of the counting scope and the pump flowrate must

be known in advance.

      The  following  equation  is  used  to calculate the range of optimum

sampling times which can then be plotted on log-log paper:

          Minutes -   (FB/FL)(ECA/MFA)
                          (FR)(AC)


where:     FB/FL  - 1 to 5 fibers/field

           EGA    » Effective collecting area of filter in square

                    millimeters (855 square mm for 37-mm filter)

           MFA    - Microscope field area in mm (generally 0.003

                    to 0.006 square mm)

           FR     - Pump flowrate in cc/minute
                                    121
                               C-Vf

-------
AC     - Air concentration of fibers in fibers/cc




         (NOTE:   If  air  concentrations are expressed




                 in  fibers/cu m they must be changed




                 to  fibers/cc for this equation.)
                        122




                          C-M,

-------
                              X.  APPENDIX II

                      ANALYTICAL METHOD - FIBER COUNT
Principle of the Method,
      (a)    Environmental  dust  samples  are  collected  by  drawing  air
through a membrane filter by means of a battery-powered  personal  sampling
pump.
      (b)    The  filter  is transformed from an opaque solid membrane to a
transparent, optically homogeneous gel.
      (c)    The  fibers are sized and counted by phase-contrast microscopy
at 400-450X magnification.
Range and Sensitivity
      (a)    This method has been successfully applied at concentrations of
10,000 to 20,000,000 fibers/cu m (0.01 to 20 fibers/cc) for  fibers  longer
than  5  ^m.   Large deviations from the specified conditions of the method
may result in filters with either too few or  too  many  fibers.   Too  few
fibers will yield air concentration estimates of low statistical precision.
      (b)    A  sensitivity  of 10,000 fibers/cu m (0.01 fiber/cc) has been
reported [JM Dement, written communication, 1975] based on a 4-hour  sample
at 2 liters/minute air flow.
Interferences
      All particulates, such as asbestos or mineral wool, with a length-to-
width ratio of 3 to 1 or greater, and length greater than 10 jan should,  in

                                    123
                                C-\i

-------
the absence of other information, be considered as glass fibers and counted




as such.  Asbestos interference can be  eliminated  using  phase  contrast,




polarized light microscopy.
Advantages of the Method



      (3) ••   The fiber count method allows for repeated counts, and storage



for counting at a later time.  The method consumes only part of the filter,




thereby  allowing  for  at  least  one replicate sample analysis at a later



time.



      (b)    Fiber   counts   are   assumed   to  be  more  toxicologically



significant than fiber weight for fibers less than 3.5 ym in diameter.



      (c)    Fiber size determinations may be performed.
Disadvantages of the Method



      (a)    The fiber count method is slow and tedious.



      (b)    Variation  in  counts  may  be  significant  between different



observers.




      (c)    The  sensitivity  of  the  method is dependent on the sampling



time and flowrate.  The sensitivity and useful range of this method has not



been  determined  specifically for fibrous glass but is based on the method



recommended for asbestos.
Apparatus




      (a)    Optical Equipment




             (1)    Microscope  body  with  binocular  head,  10X Huygenian
                                   124
                                    C-ft

-------
eyepieces, and Koehler illumination.




             (2)    Porton reticle.



             (3)    Mechanical  stage,  and  stage  micrometer with 0.01-mm




subdivisions.



             (4)    Abbe or Zernike condenser fitted with phase ring with  a.




numerical aperture equal to or greater than the numerical aperture  of   the




objective.




             (5)    A phase-ring centering telescope or Bertrand lens and  a




green filter if recommended by the microscope manufacturer.




             (6)    Fiber mounting equipment




                    (A)    Microscope slides, and cover slips, usually 0.17




mm thick.




                    (B)    Scalpel,  tweezers,  lens tissues, and glass  rod




or spatula for mounting procedures.




      (b)    Wheaton Balsam Bottle.
Reagents




      (a)    Dimethyl phthalate.




      (b)    Diethyl oxalate.
Analysis of Samples




      (a)    Calibration and Standardization




             (1)    Porton Reticle and the Counting Field




             The  fiber  count procedure consists of comparing  fiber  length




with calibrated circles, and counting all fibers > 10 /an in length within a






                                   125

-------
given  counting  field.    A  Porton  reticle is used for this purpose.  The



Porton reticle is a glass plate inscribed with  a  series  of  circles  and



rectangles.    The  square  on  the  left,  divided  into six rectangles, is



defined as the counting field.



             (2)    Placement in Eyepiece



             Place  the  Porton  reticle  inside  one  Huygenian  eyepiece,



resting it on the field-limiting diaphragm.  Keep the reticle clean,  since



dirt  on  the reticle will be in focus and will complicate the counting and



sizing process.



             (3)    Stage Micrometer



             The  Porton  reticle  cannot be used for counting until it has
                                                 •*•*


been properly calibrated with a stage micrometer.   Most  stage  micrometer



scales are approximately 2 mm long, divided into units of 10 /tan.



             (4)    Microscope Adjustment



             When  adjusting  the  microscope,  follow  the  manufacturer's



instructions while observing the following guidelines.



                    (A)    The  light  source  image  must  be in focus and



centered on the condenser iris or annular diaphragm.



                    (B)    The object for examination must be in focus.



                    (C)    The  illuminator  field  iris  must be in focus,



centered on the sample, and opened only to the point  where  the  field  of



view is illuminated.



                    (D)    The  phase  rings   (annular diaphragm and phase-



shifting elements) must be concerttric.



             (5)    Porton Reticle Calibration Procedure
                                   126



                                    COO

-------
             Each  eyepiece-objective-reticle combination on the microscope




must be calibrated.  Should any  of  the  three  be  changed  (disassembly,




replacement,  zoom  adjustment,  etc) the combination must be recalibrated.




Calibration may change if the  interpupillary  distance  is  changed.   For




proper calibration, the following procedure should be followed closely.




      Using  a  10X objective, place the stage micrometer on the mechanical




stage and focus and center the image.  Change to the 40-45X  objective  and




adjust  the  first scale division to coincide with the left boundary of the




Forton rectangle.  Count the number of divisions between the left and right




boundaries  of  the  long  horizontal  dimension  of the largest rectangle,




estimating any portion of the final division.  This measurement  represents




200  L  units  and the measurement is then divided by 200 to find "L."  The




large rectangle is 100 L units long on the short vertical  dimension.   The




calculated  "L"  is inserted into the formula D - L(2N)l/2 where "N" is the




circle number (indicated on the reticle) and "D" is  the  circle  diameter.




Since the circle diameters vary logarithmically, every other circle doubles




in diameter.  For example, number three is twice  the  diameter  of  number




one;  number  four  is twice the counting field area consisting of the left




six smaller rectangles can be calculated from the relation 10,000  L.   The




reticle  calibration is now completed for this specific objective-eyepiece-



recticle combination.




      (b)    Preparation of Mounting Solution




      An  important  part  of-the sample evaluation is the mounting process




which involves a special mounting  medium  of  prescribed  viscosity.   The




proper  viscosity  is important to expedite filter clearing and to minimize




particle migration.  Once the sample has been mounted, an elapsed  time  of






                                     127

-------
approximately  15  minutes  is  needed  before  the  sample  is  ready   for



evaluation.



      Combine  the dimethyl phthalate and diethyl oxalate in a 1 to  1 ratio



by volume and pour the solution into a Wheaton  balsam  bottle.   Add  0.05



gram  of  new  membrane  filter/ml  of  solution  to  reach  the  necessary



viscosity.  The-mixture must  be  stirred  periodically  until  the  filter



material  is  dissolved  and  a  homogeneous mixture is formed.  The normal



shelf life of the mounting solution is about 6 months.   Approximately   300



samples can be prepared from 20 ml of mounting solution.



      (c)    Sample Mounting



      Cleanliness  is  important.   The  working area must be kept clean to



prevent sample contamination and erroneous  counts.   The  following  steps



should be followed when mounting a sample.



             (1)    Clean the slides and cover slips with lens tissue.   Lay



the slide down on a clean surface with the frosted  end  up.   It  is  good



practice to rest one edge of the cover slip on the slide and the other edge



on  the  working  surface.   By  doing  this,  you   keep   from   becoming



contaminated.



             (2)    Wipe  all the mounting tools clean with lens tissue  and



place them on a clean surface (such  as  lens  tissue).   When  mounting a



series  of  filters, wipe the scalpel clean before cutting a sector of each



sample [see (5) below].



             (3)    Apply a small drop of mounting solution onto the center



of the slide with a glass rod.  It may be necessary to adjust the  quantity
                                 *. .,
                                  t'

of  solution used or the size of the wedge.  The correct amount will result



in the solution extending only slightly beyond the filter boundary.  If  the





                                  128

-------
quantity is greater than this, adverse particle migration may occur.


             (4)    With  a spatula or a supplemental glass rod, spread the



mounting media into a triangular shape.  The size of this  triangle  should


coincide with the dimension of the filter wedge.


             (5)    Separate  the  middle  and bottom sections of the field



monitor case to expose the fragile filter.  Cut a triangular wedge from the


center  to  the  edge of the filter using a scalpel.  The size of the wedge


should approximate one-eighth of the filter surface.  The filter should  be



handled gently so that no material will be lost.


      Grasp  the filter wedge with tweezers on the outer area of the filter


which was clamped between the monitor case  sections.   Do  not  touch  the
                                           «

filter  with  fingers.   Place  the  wedge, fiber-bearing side up, upon the


mounting medium.



             (7)    Lift  the  cover  slip  with the tweezers and carefully


place it on the filter wedge.  Once this contact  has  been  made,  do_  not



reposition the cover slip.


             (8)    Label the slide with the sample number and current date


before proceeding to the next filter.


             (9)    The  sample  should  become  transparent after about 15


minutes.  If the filter appears cloudy, it may be necessary to  press  very


lightly on the cover slip.  This is rarely necessary, however.



             (10)   Examine  the  slide  within  3  days.  The sample mounts


should be discarded after 3 -days  if  it  has  not  been  counted  because


crystals  which  appear  similar  to  glass fibers may begin to grow at the


mounting media/air interfaces; they seldom  present  any  problems  if  the



slide  is  examined within 3 days.  In any case, do not perform counting or




                                    129

-------
sizing around the edges of the filter.




      (d)    Counting and Sizing—Finding and Inspecting Counting Fields




      Place  the  slide  on the mechanical stage and position the center of




the wedge under the objective lens and focus upon the sample.   Nearly  all




of the particulates (particles and fibers) will be found in the upper 10-15




im of the filter surface.  When counting and sizing, continued use  of  the




fine  focus  control  is  required to insure that nothing is missed.  Start




counting from one end of the wedge and progress along a  straight  line  to




the  other end (count in either direction from circumference to wedge tip).




Haphazard fields  are  selected  without  looking  into  the  eyepieces  by




slightly  advancing  the  slide  in one direction with the mechanical stage




control.




      (e)    Achieving Comparable Results




             (1)    Size  only  those  fibers  with a length-to-width ratio




equal to or greater than 3:1.




             (2)    Count only fibers greater than 10 ion in length.  (Be as




accurate as possible in accepting or rejecting fibers near this length).




             (3)    Count  up  to  100 fields if necessary to yield a total




count of at least 100 fibers.  Count at least 20 fields even if  more  than




100 fibers are counted.




             (4)    Select  the  field  of view without looking through the




microscope's eyepieces  to  minimize  unconsciously  selecting  "heavy"  or




"light" areas.



             (5)    The  fields  are^ selected along the entire length of a




radial line running between the outside perimeter and the tip of the wedge.
                                    130

-------
             (6)    When   an  agglomerate   (mass  of  material)  covers  a

significant portion of the field of view (approximately  1/6  or  greater),

reject  the  field  and  select another.  (Do not include this field in the

number of fields counted.)  Record the agglomerated field even though it is

not included in the count.

             (7)    Bundles  of fibers are counted as one fiber unless both

ends of a fiber crossing another can be clearly resolved.

             (8)    For  fibers  that  cross either one or two sides of the

counting field, the following procedure is used to obtain a  representative

count.  First, arbitrarily select: a) the left and bottom sides, and b) the

upper and lower left corners and vertical direction as "decision aids."
             i
      Then  count any fiber greater than 10 micrometers in length, but only

if the fiber:

      a.     lies entirely within the counting area, or

      b.     crosses the left or bottom sides, or

      c.     crosses the upper or lower left corners, or

      d.     crosses both the top and bottom sides.

      Reject and do not count all other fibers.
Calculations of Airborne Concentrations

      Glass  fiber  airborne  concentration  may  be  calculated  from  the

following formula:
                                 (F-B)(W)
                            C -
where:

      C  «   Airborne fiber concentrations in fibers >10 jan/cu m.

-------
F  -   Average fiber count in fibers >10 jum/field.



B  «   Average fiber count of blank(s) or control filter(s) in



       fibers >10 ^m/field.  (It is subtracted to eliminate the




       error or background contamination.)



W  -   855 square mm for 37-mm diameter filters (the portion  of



       the membrane filter which is exposed when mounted in



       the field monitor case, ie, the effective filter area).




A  »   The area of the counting field of a calibrated reticle



       expressed in square mm/field.



V  »   Total air volume collected through filter expressed in



       milliliters.
                             132

-------
fri

-------
                    APPENDIX D
OPERATION OF SAMPLING TRAIN-DATA SUMMARY FROM FIELD LOG BOOK

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-------

-------
        APPENDIX E
HASTINGS MASS FLOW METER DATA

-------
               HAST3NGS-RAYDIST

               A  TELEDYNE  COMPANY
                                                           Specification Sheet 505 C
HAMPTON. VIRGINIA 23361
            HASTINGS  MASS  FLOWMETER
                  LF  SERIES - NON  LINEAR
        FOR LOW FLOW  RATE MEASUREMENTS  OF  AIR AND GASES
                  RANGES: 0-20 to 0-20,000 STD  CC/MINUTE
  MAJOR  FEATURES
    MEASURES EXTREMELY LOW FLOW RATES
   READABILITY TO
                     OF RANGE.
  ^ACCURATE AND STABLE WITHIN 2% FROM 0.1
    psia TO 250 psia

  •  NO  CORRECTION  NECESSARY  OVER  WIDE
    RANGES OF TEMPERATURE AND PRESSURE

  •  RUGGED,  VERSATILE, TROUBLE-FREE TRANS-
    DUCER
  LONG LIFE

  The Hastings LF Mass Flowmeter features a thermal
  technique wherein the flow transducer sensing ele-
  ment is completely external to the flow stream and
  has no moving parts to wear out. It is safe for toxic
 .and hazardous gases. Gas flow contacts only monel
  family alloys, solder and brass.  Models with all
  monel family alloys are available for measuring flow
  rates of highly corrosive gases.
 RUGGED- EASY TO INSTALL -
 REL1ABLE

     I
 The  LF meter  circuitry  is 100%  solid  state for
 maximUm  reliability  and stability. Transducer can
 withstand extreme vacuum, pressure and flow rates
 withoutXdamage.  No special  tools or techniques£
_needed-j. _ . ---------- _ -- .
                                         ..\
HASTINGS FLOWMETER



                   TRANSDUCER

HIGH STABILITY  AND ACCURACY

With the Hastings LF Mass Flowmeter pressure and
temperature need  not be  measured to determine
mass as with volume flowmeters. No ambient tem-
perature correction is required from 32"F to 110°F.
No gas pressure correction  is required from 0.1 psia
to 250 psia or gas temperatures up to 200°F. Ac-
curacy is within 2% over this range.
Measurement repeatability  is within 1%. Standard
factory calibration is for air. Curves for other usual
gases are available. Once  installed and in use the
instrument needs  no recalibration. Pressure drop
through the flow tube is nominal for most  ranges.


MODELS FOR TUNGSTEN
HEXAFLUORIDE

Three of the  models are especially constructed and
calibrated  for directly  reading the  mass  flow of
tungsten hexafluoride gas. They are also useful for
rhenium hexafluoride and similar corrosive gases.
Transducer  construction of  all monel alloys and
"teflon"  seals.  Slightly  larger  transducer (3"
diameter".)
    Model: ALF-100W—0-100 seem
  	ALE. 3QQW—Q-3QQ seem. ..

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                        *
                      HASTMOS F-SOMCS TRANSDUCE*
                                                      CHARACTERISTICS
OPERATING PRINCIPLES

The  Hastings  LF Mass  Flowmeter consists of an
electrically  heated tube  and  an  arrangement  of
thermocouples to measure the differential cooling
caused by a gas  passing through the tube. Thermo-
electric  elements generate d-c voltage proportional
to the rate of mass flow of  gas through the tube.
  > fragile sensing elements project into the stream.
   is design depends  only on the mass flow and
specific  heat of the particular gas and is, therefore,
practically  insensitive  to pressure  changes in tem-
perature, thermal conductivity and viscosity.
   APPLICATIONS

   Hastings LF Mass Flowmeters have wide applications
   in the measurement of leak rates and flow rates of
   gases  in the manufacture of tubes, lamps, neon
   signs,  semiconductors, fuel cells, valves and capil-
   laries. They are  also used for leak testing flanges
   and  valves in cryogenic gas  lines, missile  fueling
   lines and for gas flow metering or for mixing gases
   in atomic research, magnetohydrodynamics  (MHO)
   research, and in  mass spectrometer type leak detec-
   tors. Write  details of your particular application and
   requirements for recommendations by our Engineer-
   ing Department.
                                                      POWER:


                                                      INDICATOR:


                                                      TRANSDUCER:
                                                      CABLES:
                             115 volt a-c (105 to 125 V a-c)
                             50-400 cycles, 15 watts

                             Dimensions: 7W X 5%" X
                             Weight: 6 Ibs.

                             Operating pressures: .1 psia
                             to 250 psia.
                             Gas flow temperatures: Up
                             to 200" F.
                             Ambient temperatures:
                             From 32° F to 110°F.
                             Sensitivity: 0.5% Full Scale.
                             Response Time: Approximately
                             5 seconds for most models:
                             Weight: 20 oz.

                             8-foot power and transducer
                             cables included  with instrument.
                                                      SELECTION  CHART
Range
Std. CC/Min
0-20
0-50
0-100
0-300
o.iooo
0-5000
0-10.000
0-20,000
Model
LF-20
LF-50
LF-100
LF-300
LF-1K
LF-5K
LF-10K
LF-20K
Transducers
(see Notes)
F-20
F-50
F-100
F-300
F-1K
F-5K
F-10K
F-20K
Pressure Dr
@ Full Sea
Inches Hz<
7O
12
1
3
1
1
1
1
               Standard C.C. Per Minute
       TYPICAL DIAL FACE SHOWN ACTUAL SIZE
          NOTES:

            Transducers are available in  standard  brass
          "monel" construction. Monel type denotes all mat
          rials in contact with the gas are monel family alloy
          Transducers are rated to 250 psi.

            All  models  include switch and binding  posts f
          connection  to  high  impedance potentiometer  ty;
          recorder. Output signal is approximately 0-2.4 mil
          volts dc.                                    :

            Also available as a complete flow recorder util
          ing G. E.  #520 recorder, direct reading scale ar
          0-100 linear chart paper.

            For linear type flowmeters and higher flow  rat
          to 200 scfm, see Hastings; Linear Mass. Flowmeter
          Specification Sheet 508-A.
WTELEDYNE
      MASTINGS-RAYDIST
      HAMPTON, VIRGINIA 23661. U.S.A.
      PRINTED IN U.SJV.
E-7. SPECIFICATION SHEET 0505C
                                                                                  PHONE (804) 72:
                                                                                     TWX: 710-88:
                                                                                       COPYRIGH1

-------

-------
        APPENDIX F
ROTOMETER CALIBRATION DATA

-------
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                 J4,
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                            •- 2.00
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-------
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-------

-------
            APPENDIX G
LIST OF SAMPLES AND TEST RESULTS

-------
                                                                  APPENDIX G
                                                         LIST OF SAMPLES AND TEST RESULTS
   CODE                        DESCRIPTION
FG-D-A       Fibrous Glass sites A & D - downwind
FG-D-D       Monitors moved during sampling
P-D-A        Phenol sites A ft D - downwind
P-D-D        Monitors moved during sampling
F-O-A        Formaldehyde sites A * 0 - downwind
F-D-D        Monitor moved during sampling
FG-U-B       Fibrous Glass site B - upwind
P-U-B        Phenol site G - upwind
F-U-B        Formaldehyde site B - upwind

FG-D-D       Fibrous Glass site D - downwind
P-D-D        Phenol site D - downwind
F-D-D        Formaldehyde site D - downwind
F-U-G        Fibrous Glass site B - upwind
P-U-B        Phenol site B - upwind
F-U-G'        Formaldehyde site G - upwind

FG-D-E       Fibrous Glass site E - downwind
P-D-E        Phenol site E - downwind
F-D-E        Formaldehyde site E - downwind
F-D-E(prlme) Changed pump and new solution
FG-U-B       Fibrous,Glass site B - upwind
P-U-B        Phenol site B - upwind
F-U-B        Formaldehyde site B - upwind
SAMPLE TIME
                                                      (5-2)
10:00-10:49 a.m.
10:00-12:00 p.m.
10:00-10:49 a.m.
10:50-12:00 p.m.
10:00-10:49 a.m.
10:50-12:00 p.m.
10:00-12:00 p.m.
10:00-12:00 p.im
10:00-12:00 p.m.

12:10- 2:00 p.m.
12:10- 2:00 p.m.
12:10- 2:00 p.m.
12:05- 2:05 p.m.
12:05- 2:05 p.m.
12:05- 2:05 p.m.

 2:15- 4:00 p.m.
 2:15- 4:00 p.m
 2:15- 3:05 p.m
 3:20- 4:00 p.m
  :10- 4
2:10- 4:
           p.m.
           p.m.
2:10- 4:11 p.m.
 FIBERS FOR FG
uftFOR PaTlAB
 " J RESULT
                                0.8

                                7.6

                                9.2
                                     LOST
                                0.5
                                6.8

                                0.6
                                4.2
     0.6
     8.4
     3.6

     4.2
     6.8
   25°C  76*>mn
TOTAL VOLUHIT"
                                                                                         ppb
                                                        SAMPLED HJ
     .350

     .092

     .041
     .325
     .084
     .076,

     .312
     .090
     .032
     .325
     .071
     .076

     .296
     ,086-.
     .014 C
     .024J
     .315
     .074
     .069
                                                                                                                                               Cone.
                                                        9

                                                      181

                                                      110
                                                        6
                                                      223

                                                        9
                                                       55
                                                                                 308
                                                                                  57
                                                                                  98
                                                                                           2

                                                                                          151

                                                                                           29
                                                                                            1
                                                                                          173

                                                                                            2
                                                                                           45
                                                                                          251
                                                                                            14
                                                                                            80
                                                       G-l

-------
                                                             APPENDIX  G
                                                     LIST OF SAMPLES AND TEST RESULTS
CODE                   DESCRIPTION
FG-D-E       Fibrous Glass site EftF downwind
FG-D-F       monitor moved during sampling
P-D-E        Phenol site EftF downwind
P-D-F        Monitor moved during  sampling
F-D-E        Formaldehyde moved during sampling
F-D-F        Monitor moved during sampling
FG-U-B       Fibrous Glass site B - upwind
P-U-B        Phenol site B - upwind
F-U-B        Formaldehyde site B - upwind

FG-D-G       Fibrous Glass site G downwind
P-D-G        Phenol site G downwind
F-D-G        Formaldehyde site G downwind
FG-U-H       Fibrous Glass site H upwind
P-U-H        Phenol site H upwind
F-U-H        Formaldehyde site H upwind

P-D-G        Phenol site G downwind
             changed pump
F-D-G        Formaldehyde site G downwind
P-U-H        Phenol site H upwind
F-U-H        Formaldehyde site H upwind
                                                 (5-2)
        SAMPLE TIME
                          FIBERS FOR FG
      4:12
      5:00
      4:12
      5:00
      4:12
      5:00
      4:47
      4:47
      4:47
 •5:00 p.m.
 6iOO p.m.
 •5:00 p.m.
 •6:00 p.m.
 •5:00 p.m.
 •6:00 p.m.
 6:01 p.m.
-6:01 p.m.
-6:00 p.m.
(5-4) 12:15-5:00 p.m.
      12:15-2:30 a.m.
      12:15-2:30 a.m.
      12:26-5:00 a.m.
      12:26-2:26 a.m.
      12:26-2:26 a.m.

      2:40-3:05 a.m.
      3:05-5:00 a.m.
      2:45-5:00 a.m.
      2:31-5:00 a.m.
      2:31-5:00 a.m.
                                   ttt) FOR PtF LAB
                                     J RESULTS
                         25°C  76° run
                         TOTAL VOLUME
                                                            LI
                                                            IP
                               PBb
                       Cone
0.6

3.4

0.9
4.2
                               9.6
                               2.7

                               0.5
                               2.7
                               ND
                               0.4
                               0.5
                               NO
.301

.079

.065
.197
.043
.035

.844
.155
.076
.693
.136
.054
                              .187
                              .057
                              .157
                              .114
  8

 52

 21
120
                                                      63
                                                      36

                                                       4
                                                      50
                        0
                        7
                        3
                        0
 2

43

 5
98
        17
        29

         1
        41
        0
        6
        1
        0
                                              G-2

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                                                                  APPENDIX 6


                                                        LIST OF SAMPLES AND TEST RESULTS
CODE
FG-D-A
P-D-A
F-D-A
FG-U-B
P-U-B
F-U-B

FG-D-A
FG-D-C
F-D-A
F-D-C
F-D-A
F-D-C
FG-U-B-
P-U-B
F-U-B

FG-D-C
P-D-C
F-D-C
FG-U-B
P-U-B
F-U-B
DESCRIPTION
SAMPLE T1HE
                                         (5-1)
Fibrous Glass-site A-downwInd        6:01-8:01 p.m.
Phenol - site A- downwind            6:01-8:01 p.m.
Formaldehyde - site A - downwind     6:01-8:01 p.m.
Fibrous Glass - site B - upwind      6:01-8:01 p.m.
Phenol - site B - upwind             6:01-8:01 p.m.
Formaldehyde - site B - upwind

Fibrous Glass - sites A&C - downwind
Monitors moved during sampling
Phenol - sites ASC downwind
Monitors moved during sampling
Formaldehyde- sites AftC downwind
monitors moved during sampling
Fibrous Glass - site B - upwind
Phenol • site B - upwind
Formaldehyde - site B - upwind

Fibrous Glass - site C - downwind    10:15-12 midnight
Phenol •• site C - downwind           10:15-12 midnight
Formaldehyde - site C - downwind     10:15-12 midnight
Fibrous Glass - site B - downwind    10:32-12:02
Phenol • site B - upwind             10:32-12:02
Formaldehyde - site B - upwind       10:32-12:02
                               6:01-8:01  p.m.

                               8:16-8:56  p.m.
                               8:56-10:01 p.m.
                               8:16-8:56  p.m.
                               8:56-10:01 p.m.
                               8:16-8:56  p.m.
                               8:56-10:01 p.m.
                               8:15-10:03 p.m.
                               8:15-10:03 p.m.
                               8:15-10:03 p.m.
   FIBERS mo
ugFOR PftF LfiB
   RESULTS
                                                                0.5
                                                                2.7

                                                                0.5
25°  76°mm
                                                                                                             Tola
(5-2) a.m.
(5-2) a.m.
(5-2) a.m.
                     0.5

                     1.1

                     1.8



                     8.5
                                                                o.5
                                                                0.4
                                                                                          samp
                                                                                               -Si
                                                                 ~'i.n
                                                                ed tj3
                                                              .330
                                                              .124
                                                              .045
                                                              .357
                                                              .088
                                                              .061
                                                              .302

                                                              .104

                                                              .036
                                                              .281
                                                              .068
                                                              .055

                                                              .289
                                                              .104
                                                              .039
                                                              .221
                                                              .056
                                                              .042
                                                                                                                                Cone.
                                                   4
                                                   60

                                                   6
                                                   0
                                                   4

                                                   31

                                                   265
                                                   0
                                                   82
                                                   0

                                                   10
                                                   10
                                     1
                                   49

                                   2
                                   0
                                    1

                                   25

                                   69
                                    0
                                   21
                                   0

                                  : 2
                                   8
                                                  G-3
                                                                                   *HD - Non-detectable

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H

-------
      APPENDIX H
HEALTH EFFECTS DATA

-------
           TABLE 15.   HUMAN RESPONSES FROM EXPOSURE TO PHENOL VAPORS30
  Concentration
      (ppm)

      0.047

    0.0 - 3.3

    1.5 - 5.2
      48.0
(plus 8  ppm
 HCHO)
 Duration of
  exposure   ^

minutes

8 hrs/day

8 hrs with two
30 min breaks
              Response

Odor threshold

No ill effect.  Rise in urinary
phenol
No ill effect; 60 to 88 percent of
phenol absorbed by lungs.  Rise in
urinary excretion of phenol during
exposure with a return to pre-
exposure levels within 24 hours
5 to 10 min/hr, Marked irritation of the nose, throat
8 hr/day        and eyes.  Formaldehyde may be prima-
                ry cause.
Reference


    4
   33

   34
                                         35

-------
    TABLE 14.   HUMAN RESPONSES FROM EXPOSURE TO FORMALDEHYDE VAPORS

Concentration
(ppm)
0.01
0.05
0.4 - 0.8
Duration of
expose
5 rain
-
Occupational
Response
Eye irritation threshold
Odor threshold
Acute exposures caused eye, nose,
Reference
13
3
1
0.13 - 0.45
0.25 - 1.39
 0.9 - 1.6
  exposure
           s
Occupational
  exposure


Occupational
  exposure


Occupational
  exposure
throat irritation, and lower
respiratory tract symptoms
Burning, stinging eyes, headaches,     21
intolerable irritation of eyes,
nose and throat; one illnes

Upper respiratory tract irritations,   20
burning of eyes and nose, sneezing-
coughing, headaches

Intense irritation, itching of eyes    22
dry and sore throat, increased
thirst disturbed sleep
1.0
4.0
4.0 - 5.0
10.0
16 - 30
50 - 100
-
5 min
10 to 30 min
few minutes
Occupational
exposure
(8 hr/day)
5-10 min
Detectable by nearly all people
Severe eye irritation
Intolerable to most people;
lachrymation, discomfort, throat
irritation
Profuse lachrymation
Skin reaction
May cause serious injury; serious
bronchial inflammation
23
24
23,25
23
26
17

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                           APPENDIX  H

                        HEALTH EFFECTS DATA
1.  Schoenberg, J. B., and C. A. Mitchell.  Airway Disease Caused by Phenolic
    (Phenol .- Formaldehyde) Resin Exposure.  Arch Environ Health. 30:574-577.
    1975.

2.  Kerfoot, E., and T. Mooney.  Formaldehyde and Paraformaldehyde Study
    In- Funeral Homes.  Am Ind Hyg Assoc. J. 36:533. 1§75.

3.  Bourne, H., and S. Seferian.  Formaldehyde fn Wrinkle-Proof Apparel
    Processes - Tears for Milady.  Ind Med Surg. 28:232. 1959.

4.  Petrov, V. I.  Causes of Phenol Vapor Poisining During Coke Slaking With
    Phenol Water, in Levine BS (trans):  USSR Literature on Air Pollution
    and Related Occupational Diseases - A Survey.  Springfield, VA., U.S.
    Dept. Comm. (NTIS 63-11570) 8:219-21. 1963.

-------

-------
                     APPENDIX I
Participants In Survey
All participants are employees of the Environmental Protection
Agency, Surveillance and Analysis Division, Region III.
Robert Kramer        -   Task Manager
Theodore Erdman      -   Test Manager and Test Site Leader
David O'Brien        -   Test Site Leader
David Lorentz        -   Test Technician
Carmella Gualtieri   -   Test Technician

-------