vvEPA
             United States
             Environmental Protection
             Agency
                   Office of Water
                   WH-550
Radionuclides in  Drinking Water
             National Primary Drinking Water Regulations
             for Radionuclides

             Proposed Rule
            June 1991
            Office of Ground Water and Drinking Water
            U.S. Environmental Protection Agency
            Washington, DC
                                                 Printed on Recycled Paper
                                             Printed on Recycled Paper

-------
                             SUMMARY
 These regulations will:
    Propose Maximum Contaminant Level Goals (MCLGs) and Maximum
    Contaminant Levels (MCLs) for four radionuclide contaminants and two categories
    of radionuclides.

    -  The four radionuclide contaminants are: radium-226, radium-228,  radon-222,
        and uranium.

    -  The two categories of radionuclides are adjusted gross alpha emitters, and beta
        and photon emitters.

        •  The category of adjusted gross alpha emitters regulates alpha emitters and
           is gross alpha measurement less uranium and less radium-226.

        •  The category of beta and photon emitters  regulates total beta and photon
           emitters (mostly man-made).

When this proposed rulemaking is final:

•  These rules will establish

    —  Four revised radionuclide standards; and
    —  Two new radionuclide standards (radon and uranium) for a total of six.


These proposed rules also include additional provisions for:

•  Monitoring, analytic methods and laboratory requirements;

•  Best Available  Technologies (BATs) for compliance with the MCLs and for the
    purpose of issuing variances:

    —   aeration                      -  ion exchange
    —   reverse osmosis               —  coagulation/filtration
    —   anion exchange

•  Mandatory health effects language to be used by systems when notifying the public
    of violations;

•  State reporting, recordkeeping and primacy requirements; and

•  Unregulated contaminant monitoring for lead-210, the first long-lived progeny of
    radon-222.
                                          Radionuclides in Drinking Water Fact Sheet—1

-------
 EPA is seeking comment from the public in this proposed rulemaking on:

 •  A number of alternative MCLs for radon, uranium, and radium; and

 •  A variety of technical and policy issues.
Key Datesr 1
June 1991
^September 1991
September 1991
(approximate)
April 1993
(22 months after
proposal)
October 1994
(18 months after
promulgation)
January 1996
Standards for 4 radionuclide contaminants and
2 categories of radionuclides proposed
Public hearingsjm Washington, D,C. andiGhicagoy 1L
Close of public comment period
(90 days after Federal Reeister publication)
Standards for 4 radionuclide contaminants and
2 categories of radionuclides promulgated
• Standards for 4 radionuclide contaminants and
2 categories of radionuclides effective
• State adoption complete
First monitoring compliance period begins |
                     Regulatory  Impact
As proposed, these regulations, when implemented, will reduce the exposure of
20 million consumers to the regulated contaminants and result in  avoidance of an
estimated 83 cancer cases per year.

•  This includes:

    -   Avoidance of an estimated 80 cancer cases per year due to reduced radon
        exposure of an estimated 17 million customers of public water systems served
        by ground-water sources;

    —   Avoidance of an estimated 3 cancer cases per year due to radium; and

    —   Reduced exposure of approximately 875,000 people to kidney toxicity risk.

•  Regulation of radon  is expected to result in the most violations, increased cost to
    public water systems, and provide  the greatest health benefits.
2—Radionuclides in Drinking Water Fact Sheet

-------
i
5
I
5
X > * * •• '
National
Costs of Proposed Radionuclide MCLs
'
!,' - '•.
Proposed MCL**
Systems Affected
Treatment Cost
Total Capital ($M)
Annual 6&M ($M)
Total Annual Cost ($M)
Monitoring ($K/Yr)*****
State Implementation
Initial ($M)
Annual ($M)
Annual Household Cost
by System Size
Very Small (25-500)
Small (501-3,300)
Medium (3,301-10,000)
Large (over 10,000)
, Rn-222
300
26,000

1,600
70
180
5,000
•• • .

'•
120
30
6
5
Rft-226
20
70

190
20
30
3



630
150
90
60
Ba-22e
20
40

40
3
6
r
860
	 	 MA
	 	 	 .. MA

650
150
90
60
Uranium
20***
1,500

350
30
60
3


580
180
80
40
AGA*
15
130

230
20
40
640



770
340
200
140
Beta
Emitters
4****
0

0
0
0
250



0
0
0
0
TOTAL

28,000

2,400
140
310
6,800
15-28
10-19

               • Adjusted Grata Alpha.
              "UCLs an expressed In pCI/L unless otherwise noted.
              ***UCL tor Uranium It expressed In \ig/L.
              ***MCL tor Beta Emitters Is expressed In mllllrems effective dose equivalent per year (mrem ede/yr).
                'Cross Alpha Is used as a screen tor Radlum-226 and uranium.

-------
 Total Costs

 •  Total costs to all public water systems will be approximately $317 million per
     year.  Approximately 75% of these costs will be borne by systems serving fewer
     than 10,000 people.'

 •  State implementation costs will be $15-28 million initially and $10-19 million in
     future years.

 Monitoring and Treatment

 •  Monitoring requirements will be standardized, with monitoring required every
     three, six, or nine years depending on the system's vulnerability  to the particular
     contaminant.

 •  Nationally,  it will cost approximately $7 million per year for systems  to monitor.

 •  Nationally,  monitoring for lead-210 will cost systems an addition $8 million
     one-time cost.

 •  Monitoring  for radionuclides will be required for approximately 80,000 systems.

     Ground Water

     -  Approximately 68,000 community and non-transient non-community public
        water systems with ground-water or mixed surface and ground-water sources
        must monitor for radon, radium-226, radium-228, uranium, and adjusted gross
        alpha emitters.  Vulnerable systems also must monitor for beta and photon
        emitters.

     Surface Water

     -  Approximately 12,000 community systems and non-transient non-community
        public water systems with surface water sources must monitor for  radium-226,
        radium-228, uranium, and adjusted gross alpha emitters.   Vulnerable systems
        also must monitor for beta and photon emitters.

•  Nationally, approximately 28,000 or 35% of affected public water systems will be
    required to provide treatment or find an alternative source of water.

    -  Treatment will cost approximately $3 to $800 per household  annually
     .  depending upon system size, degree of contamination, and other factors.

    -  It will cost systems $310 million per year to provide treatment.

    —  At State's  option, extendable exemptions based on costs may be allowed for
        systems with less than 500 service connections, as long as the level does not
        exceed unreasonable risk to health and alternative sources are not feasible.

4—Radionuclides in Drinking Water Fact Sheet

-------
                               RadionucHde National Primary Prinking Water Regulations
Oorrtnrolrwit*
O.lnWngW.tw
HonMh pfftcis
                                                         EPA Standard*
Proposed
MCWJ
Proposed
MW,1
                                                                     Current MCL
Source?
Analytic
Method
BAT
R«dlum-226
Radlum-228
                      cancer
                                          zero
                                          zero
                                   20pCI/l        5 pCI/l combined    naturally occurring   RE; RC       IE; LS; RO
                                                  with radium 228
                                   20pCI/l        5 pCI/l combined    naturally occurring   RC; LS       IE; LS; RO
                                                  with radlum-226
Radon-222 cancer , , zero , 3OOpCI/l
Uranium kidney, cancer zero 20|ig/l*
Ad|usted gross alpha cancer . zero 1SpCI/l 1SpCI/l
emitters
Gross beta and cancer ' zero 4 mrem 4 mrem/yr
photon emitters ede/yr any organ
naturally occurring LS; LC
naturally occurring RC; FL; AS
naturally occurring GA/B; GA
and man-made
man-made and
or naturally occurring
AER
C/F; AE; LS; HO*
RO

IE;RO

whole body
- radioactive cesium : . . . • . .
- radioactive Iodine .
- radioactive , .' ' • •
strontium 89.90
-UUum
-gamma and ,
photon emitters

PREC
PHEC
PREC; RC

LS
GRS


Analytic Methods Key: Best Available Technology Key:
RE Radon Emanation , ' IE
RC Radloctwmlcal LS
LS Liquid SclnUlatlon ' RO
LC Lucas Call : . AER
FL Ruoromstrle t C/F
IAS Alpha Spsctromelry AE
GA/B Gross alpha and/or bala activity
GA Gross alpha activity
PREC Precipitation
GRA Gamma Ray Speclrometry
Ion Exchange
Lime Softening
R«v«r>« Ounotl*
Aeiatlon
Coagulation/Filtration
Anlon Exchange














I






I'

 'pCI/l Is an activity measurement of radioactive decay (1 pd = 2.2 disintegrations per minute); \>g>l is a mass measuiement; mrem Is measurement ot effective
 radiation dose to organs).
 'Except as noted, BAT for Ihe purpose of Issuing variances Is the same as BAT for compliance.
 '20 (ig/l Is based on kidney toxlclty. 2O \>g/l Is the equivalent of 3O pCI/l
 'Coagulation/Filtration and Lime Softening are not BAT for small systems (those with less than 50O connections) lor the purpose ot granting variances.

-------
I
I
K
l
s
I
Summary  of

[Calendar Year1
       Minimum  Monitoring  Kreqiiuncies   for  Kadioiuiclidcs
                                                                                                  2(K)3     21XM
W Framework |il
••'f:v. • ^.  . .     K'-fv
   Divisions p!
                                     Firsl 9-ycar cycle
                                                                                                    Sec-oiiil 0-year cyck
       Monitor  for  Current MO.s
                                             ||i||p|yliiili;il
                                                                                           Itepeal  period
                                 New  Monitoring
                                  Requirements
                                 Noi Yet In liffcci
IGW
                  !GW/5w"
                  tliyif?
                      sw
           New  Monitoring
            Requirements
           Not Yet In  Effect
                                 New  Monitoring
                                   Requirements
                                 Not Yet In effect
                                                                 Slate Discretion
               g«OW/SW
               O^, Waiver,
               *   "
              ' Calendar to be adjusted to dale of final regulations.
              2 Vulnerable systems only (based on Vulnerability Assessment).
              -* Waiver based on monitoring results.
              4 Numbers shown in each monitoring period refer to number of samples |>cr sampling point per year.
              * Gross Beta is a screen for Ua-22K and an MCI. standard.
               (iross Alpha is a screen for Ka-226 and uranium, anil an M( 'I. staiulanl.
                                                                                              I/cycle

-------
         Summary   of   Proposed   Monitoring   Requirements  for   kadionuclides
                                   Base   Requirements
           Contaminant
            Gross  Beta
          (Vulnerable systems)
            Radon - GW
                               YRS 2 • 3 • WOT, PER.
  Gross  Alpha
Ka-226,  Ra-228,
     Uraniu
    (Compositing is
      permined)
                                                GW/SW - I per
                                                3-year period
                              GW/SW-Annually
              nregulated
             Contaminant
                Pb-210
I
s
I
3
1
a1
(st
I
                                                                System  is  out
                                                               of   compliance
                                                                      IF:
                                                                Average of I sample + I
                                                                mandatory confirmation
                                                                sample > MCI.
                                                                Y|T?i;r INITIAL PERIOD
                                                                  Annual average of
                                                                  <|iianerlysam|>le!>
                                                                  > MCL
                                                                 ALL OTHER YEARS
                                                                   I sample > MCL
                                                               Average of I sample + I
                                                               mandatory confirmation
                                                               sample > MCL
                                                                     N/A
                                                                                       Increased
                                                                                       Frequency
                                                                                     Triggered  by
                                                                                  N o n - c o in |i I i a n c c
                                                                                  Monthly if oui of
                                                                                  ctMiipliance. Uciiirn 10
                                                                                  huse when 3 mo. < MC
                                                                                  VR . I - INITIAL PERIOD
                                                                                  Continue t|iiaricily if
                                                                                  oui of compliance.
                                                                                  Annually when avenige
                                                                                  ol -4 <|uaiicrs < MCI.
                                                                                    ALL OTHER VEARS
                                                                                   Quarterly if eriod
Waiver reduces
lo I  per 9-year
|>eri(xl
                      N/A

-------
                         Radon in  Water
 The proposed radon regulation will provide a substantial public health benefit
 compared with  other drinking water regulations and other environmental
 regulatory programs administered by EPA.

 • The regulation will reduce the exposure to radon of 17 million consumers whose
    household water comes from a public water system served by ground-water
    sources.

 • The regulation, when implemented, may result in an estimated avoidance of about
    80 cancer cases per year.


 Radon  comes from the natural break-down of uranium in soil, rock and water.

 • Radon is a volatile gas and is not a problem in drinking water from surface water
    sources.

 • Radon may be present in drinking water from ground-water sources.

    -   Public water supplies with ground-water or mixed ground and surface water
        sources would be required to monitor for radon and  to provide treatment or
        find an alternative source of water if the radon MCL is exceeded.

    -   Radon also may be present in drinking water from private wells not regulated
        by EPA.


 The primary health hazard conies from breathing air containing radon.

 •  Breathing air containing radon can damage lung tissue and increase the risk of
    lung cancer.                     .

    —   Radon in water generally accounts for about 5% of the total indoor air
        concentration in homes with ground-water sources of drinking water.

    -   EPA estimates that indoor radon may result in 8,000-40,000 lung cancer deaths
        annually.

    —   The higher the level of radon, the greater the  risk of developing lung cancer.

    -   Smokers  exposed to radon may have up to ten times the risk of contracting
        lung cancer as never-smokers exposed to the same radon levels.
8—Radionuclides in Drinking Water Fact Sheet

-------
     —   Radon present in drinking water is released into indoor air during household
         water use such as showering and washing clothes.

     -   As an average, every 10,000 pCi/1 radon in water contributes about 1 pCi/1
         radon to indoor air for an average house.
                                                                        •-V- •
     -   On average, outdoor levels of radon range from 0.2 pCi/1 to 0.7 pCi/1.

 •   Drinking water contaminated with radon may add some minor risk of developing
     stomach or other internal organ cancer.  This risk is small compared to the risks
     from breathing indoor air containing radon.

 EPA is taking action to protect public health from radon in air and radon in
 water to the highest degree possible, given existing mitigation technologies.

 •   Central water treatment for radon by public water systems is affordable and
     technologically feasible. Under the Safe Drinking Water Act, EPA is proposing to
     regulate radon at a level public water systems can achieve—300 pCi/1. Radon at
     this  level contributes about 0.03 pCi/1 of radon in air.  This corresponds to an
    estimated lifetime cancer risk of approximately 2 x 10"* (2 in 10,000) and is
    consistent with EPA's risk guidelines for regulating drinking water contaminants.
    This risk may vary for individuals.

 •  Concerning radon in air, EPA has proposed to keep its current action level of
    4 pCi/1, corresponding to an  estimated lifetime risk of 1-5 x 10'2 (1-5 in 100)
    because the Agency believes that level can be achieved consistently and
    economically in homes, given current technology. The new Citizen's Guide,
    scheduled for publication in Fall 1991, also will provide information on testing
    methods to determine radon levels in homes.
All homes should be tested for radon in air.                          :

•  Most radon in household air comes from soil gas which seeps into the home
    through the foundation.
          • - "- . '• ^.'     "'-'*'            -
•  Information about radon testing and mitigation of household air can be found in
    the following EPA publications:

    -  A Citizen's Guide to Radon: What It Is and What To Do About It; and
    —  Radon Reduction Methods: A Homeowner's Guide.

•  Information about radon in air can be requested by calling 1-800-SOS-RADON or
    by contacting the State Radon office.

                                           Radionucitdes in Drinking Water Fact Sheet—9

-------
 Some homes with private wells also should be tested for radon in water.

 •  After testing the air for radon and finding levels above EPA's current action
     guideline of 4 pCi/1. homeowners with private wells should consult with their State
     drinking water office to obtain information on laboratories to test for radon in
     water, and test the water.  After testing, homeowners should select the mitigation
     strategy that is most cost-effective for reducing radon exposure for the individual
     home.

     -  In the majority of cases, the appropriate mitigation strategy will be controlling
        the soil gas  contribution to indoor air before treating the water to remove
        radon.

 •  If treatment of radon in private wells is appropriate, the most effective treatment is
     to remove the radon from the water before it enters the home. This is called
     point-of-entry (POE) treatment.

 •  Two basic types of POE water treatment are available.

     -  Aeration Systems

            Forced air bubblers remove  radon gas from the water.

     -  Granular Activated Carbon (GAQ Systems
            Filters remove radon from the water.  Homes with high levels of radon in
            water should not use GAC to remove  radon.

•  Treatment at the tap is called point-of-use (POU) treatment.  POU treatment will
    fail to reduce the most important risk from radon in water, breathing radon in
    indoor air transferred from water.

•  Information  about radon in drinking water can be requested by calling the Safe
    Drinking Water Hotline (1-800-426-4791) or contacting the State Drinking Water
    Office.
10—Radionuclides in Drinking Water Fact Sheet

-------
   FOR MORE INFORMATION ABOUT RADON IN INDOOR AIR
     EPA Radon Information Hotline
          S  1-800-SOS-RADON
  EPA  Regional Offices Radiation Program Managers
 EPA Region 1
 Pesticides and Toxic
  Substances Branch
 JFK Federal Bldg., Rm. 2311
 One Congress Street, 11th floor
 Boston, MA  02203
 (617) 565-4502

 Connecticutjdassachusetts,
 Maine, New Hampshire,
 Rhode Island, Vermont

 EPA Region 2
 Air and Waste Management
 Division
 26 Federal Plaza, Rm. 1137-L
 New York, NY  10278
 (212) 264-4110

 New Jersey, New York, Puerto
 Rico, Virgin Islands

 EPA Region 3
 Air Programs Branch
 Special Program  Section
 (3AM12)
 841 Chestnut Street   .
 Philadelphia, PA  19107
 (215) 597-8320

 Delaware, Maryland,
 Pennsylvania, Virginia, West
 Virginia, District of Columbia

 EPA Region 4
 Air, Pesticides, and Toxics  :
 Management Division
 245 Courtland Street, NE
 Atlanta, GA  30365
 (404)347-3907

Alabama, Florida, Georgia,
Kentucky, Mississippi, North
 Carolina, South Carolina,
 Tennessee
 EPA Region 5
 Air Toxics and Radiation
  Branch
 (5AR26)
 Chicago. IL 60604
 (312) 353-2206

 Illinois, Indiana, Michigan,
 Minnesota; Ohio, Wisconsin

 EPA Region 6
 Air Enforcement Branch
 (6T-E)
 1445 Ross Avenue
 Dallas.  TX 75202-2733
 (214) 655-7223

Arkansas, Louisiana, New
Mexico, Oklahoma, Texas

EPA Region 7
Air Branch
726 Minnesota Avenue
Kansas  City, KS 66101
(913) 551-7020

Iowa, Kansas, Missouri,
Nebraska
 EPA Region 8
 Radiation Programs Branch
 999 18th Street, Suite 500
 Denver, CO  80202-2405
 (303) 293-1709

 Colorado, Montana, North
 Dakota, Sourth Dakota, Utah,
 Wyoming

 EPA Region 9
 Office of Air Toxics and
 Radiation
 (AM)
 75 Hawthorne Street
 San Francisco, CA  94105
 (415) 744-1045

 Arizona, California, Hawaii,
 Nevada, American Samoa, Guam,
 Trust Territories of the Pacific

 EPA Region 10
 Air Programs Branch
 (AT-082)
 1200 Sixth Avenue
 Seattle, WA 98101
 (206) 442-7660

Alaska, Idaho, Oregon,
 Washington      : "__
                                                Radionuclides in Drinking Water Fact Sheet—11

-------
        FOR MORE INFORMATION ABOUT RADIONUCLIDES
                     AND RADON  IN DRINKING WATER
  EPA Regional Drinking Water Offices
  EPA Region 1
  Groundwater Management and
  Water Supply Branch
  JFK Federal BIdg.
  One Congress Street, llth floor
  Boston, MA  02203
  (617) 565-3610

  Connecticut,Massachusetts,
  Maine, New Hampshire,
  Rhode Island, Vermont

  EPA Region 2
  Drinking/Groundwater
  Protection Branch
  26 Federal Plaza, Rm. 824
  New York, NY 10278
 (212) 264-1800

 New Jersey, New York, Puerto
 Rico, Virgin Islands

 EPA Region 3
 Drinking/Groundwater
  Protection Branch
 841 Chestnut Street
 Philadelphia, PA  19107
 (215)597-8227

 Delaware, Maryland,
 Pennsylvania, Virginia, West
 Virginia, District of Columbia

 EPA Region 4
 Municipal  Facilities Branch
 245 Courtland Street, NE
 Atlanta, GA 30365
 (404) 347-3633

Alabama, Florida, Giorgio,
Kentucky, Mississippi, North
Carolina, South Carolina,
 Tennessee
 EPA Region 5
 Safe Drinking Water Branch
 230 S. Dearborn Street
 Chicago, IL  60604
 (312) 353-2151

 Illinois, Indiana, Michigan,
 Minnesota, Ohio, Wisconsin

 EPA Region 6
 Water Supply Branch
 1445 Ross Avenue
 Dallas, TX 75202
 (214) 655-7155

Arkansas, Louisiana, New
Mexico, Oklahoma, Texas

EPA Region 7
Drinking Water Branch
726 Minnesota Avenue
Kansas City, KS 66101
(913) 551-7032

Iowa, Kansas, Missouri,
Nebraska
 EPA Region 8
 Drinking Water Branch
 999 18th Street, Suite 1300
 Denver, CO 80202-2413
 (303) 293-1713

 Colorado, Montana, North
 Dakota, Sourth Dakota, Utah,
 Wyoming

 EPA Region 9
 Drinking Water & Groundwater
 Protection Branch
 75 Hawthorne Street
 San Francisco, CA  94105
 (415) 744-1818

 Arizona, California, Hawaii,
 Nevada, American Samoa,
 Guam, Trust Territories of the
 Pacific

 EPA Region 10
 Drinking Water Branch
 1200 Sixth Avenue
 Seattle, WA 98101
 (206) 442-1225

Alaska, Idaho, Oregon,
 Washington
  EPA Safe Drinking Water Hotline
           C 1-800.426-4791
12—Radionuclides in Drinking Water Fact Sheet

-------