A Cooperative Project between the U.S. Environmental Protection Agency and the Printing Trade Associations Nationwide DRAFT October 994 SCREEN PRINTING CASE STUDY 2 EPA TECHNOLOGY ALTERNATIVES FOR SCREEN RECLAMATION In business today, being responsive to the environment means learning new proce- dures and using new tools to do the same job with less environmental impact. Decisions about the purchase of equipment and chemi- cals for screen reclamation or other produc- tion processes depend not only on cost, availability, and performance, but also on whether environmental concerns can be addressed. Addressing environmental con- cerns means understanding the comparative human and ecological risks of the alternatives being considered. This case study, developed for screen printers like you, is brought to you by the U.S. Environmental Protection Agency's (EPA's) Design for the Environment (DIE) Program with assistance from the Screenprint- ing and Graphic Imaging Association Interna- tional (SGIA). Through the DflE Screen Printing Project, EPA and the screen printing ' working together to identify alter- native work practices, products, technologies, and pollution prevention options that are cost- e&cttw and safer for yonr workers and the environment. With a focus on screen reclama- tion, the DfE Screen Printing Project has con- centrated on providing the chemical risk and pollution prevention information, along with performance and cost information, so that you arc better equipped to incorporate environ- mental concerns in your day-to-day business operations. As you consider changing your recla- mation practices, this case study can help you understand the possible occupational health and environmental benefits of alternative tech- nologies. This information, combined with cost and performance information, is critical to help you raake more informed decisions about your chemical usage. This is the second in a series of case studies focusing on the screen printing indus- try that EPA has developed to illustrate how the DfE concepts can be incorporated into screen printing operations. This case study focuses on different technologies that can be utilized in screen reclamation. The DfE Screen Printing Project identified seven potential sub- stitute technologies that may be environmen- tally safer than traditional screen reclamation, including: high pressure water blasters, auto- matic screen washers, sodium, bicarbonate spray, media blasting, pulse light energy tech- nologies, stripping technologies, and emulsion chemistry. This study describes three screen reclamation technologies that may enable you to change both the types and amounts of chemicals you use: • High pressure screen washers • Automatic screen washers • Sodium bicarbonate (baking soda) spray Of the seven alternative technologies listed above, these three were selected because screen printers expressed an interest in learning more about these technologies. ------- DRAFT October 1994 This case study presents: • Descriptions of two commercially available technologies that can reduce a facility's usage of tradi- tional solvent-based ink removers. • Description of a technology now under development that could fur- ther reduce the costs and potential health risks of screen reclamation. • Comparative cost, performance and risk information for three reclama- tion technologies. The costs and risks for each of the three substitute technologies are compared to the costs and risks of a traditional screen reclamation system. The traditional system used in the comparison consists of lacquer thinner as the ink remover, a sodium perio- date solution as the emulsion remover, and a xylene/acetone/mineral spirits/cyclohexanone blend as the haze remover. These chemicals were selected because screen printers indi- cated they were commonly used in screen reclamation. In both the cost and risk comparisons, it was assumed that these chemicals •were applied manually to 6 screens per day, each 2,127 in2 (approximately 15 ft2) in size. High-Pressure Screen Washers Two high-pressure screen recla- mation systems were reviewed. In addition, the performance of one sys- tem was evaluated in a print shop as part the DfE Screen Printing Project. High-pressure washers typically work as follows. Excess ink is carded off the screen prior to cleaning. No ink remover is applied to the screen. An emulsion softener or remover is applied and allowed to work, typically for anywhere from ten seconds to less than one minute. The ink and stencil are then removed by a high-pressure water blaster sprayed on both sides of the screen at pressures of up to 3,000 pounds per square inch (psi). If nec- essary, a haze remover is then applied and allowed to work. Again, the high-pressure water blaster is used to rinse off the haze and the haze remover. Cleaning usually takes place in a washout booth where the rinse water can be collected. While this technology may require significant water use, most emulsion and haze removal products are formulated to allow discharge to sewers. Where ink residues in the rinse High Pressure Washer water exceed wastewater permit con- centration limits, such as for suspended solids, manufacturers also supply a variety of filters. Some improved filtra- tion systems allow rinse water to be reused. Filter wastes are typically dis- posed of as hazardous waste. Risk In general, the benefits of high- pressure washes are that they reduce both chemical use (eliminating ink removers) and worker exposure (less scrubbing required). The DfE Screen Printing Pro- ject found that the occupational risks of this system were notably lower than the risks associated with the traditional solvent-based reclamation chemicals. For the traditional screen reclamation system, health risks associated with both daily inhalation and skin contact with the chemicals, particularly with organic solvents, were significant. For the high-pressure screen reclamation system, health concerns were related to unprotected skin contact with the recla- mation chemicals. Dermal exposures could be reduced dramatically, howev- er, by wearing gloves. Ecological risks from discharges to the water were not a concern for either the traditional sys- tem or the high-pressure blaster sys- tem. General population risks from air releases also were not a concern for either system. Performance Performance of a high-pressure water blaster was evaluated by DfE staff at a volunteer printing facility where the technology was in place. During the demonstration, the technology's perfor- mance was very good. On screens with solvent- and water-based inks, the sten- cil dissolved easily, leaving no emulsion residue on the screen. Ink stains on these screens were completely removed by the haze remover even before the waiting period or pressure wash. Recla- mation results were fairly similar for UV- curable ink as well. Cost The DfE Screen Printing Project also estimated the cost of equipment, labor, and chemicals for the high-pres- sure wash. Assuming that 6 screens are reclaimed daily and each screen is 2,127 in2 in size, the cost estimate for the high-pressure washer totaled $4.53 per screen. This estimate was compared to that of the traditional screen reclamation system (using lacquer thinner, sodium periodate, and a solvent blend). Using the same assumptions, the estimated reclamation cost using the traditional system is $6.27 per screen: 30 percent more than the high pressure wash, with the greatest savings coming from the reduced labor costs for the high-pres- sure washer. Equipment costs, estimated at $5,300 (installed) account for just 12 percent of the per screen costs. This estimate does not include filtration units, which range in price from $1,300 to $12,000, although maintenance and operating costs vary widely. Automatic Screen Washers There are several different types of automatic screen washers, and although most are used for ink removal only, automatic systems for emulsion and haze removal are also available. The major benefits of automatic screen washers are reduced solvent losses, reduced labor costs, and reduced worker ------- EFA DRAFT October 1994 exposures. The DfE Screen Printing Pro- ject identified a wide variety of auto- matic screen washers on die market and found significant differences in the chemicals used and costs. Costs vary Automatic Screen Washer based on the level of automation (such as conveyors), system capacity, and complexity of the equipment. The basic component of the automatic screen washers is the wash unit, an enclosed box that can house a variety of screen sizes (up to 60 in. by 70 in.). After a screen is clamped inside the wash unit and the top closed, the cleaning process begins. A mobile mechanical arm sprays solvent onto the screen through pressurized nozzles (30 to 150 psi) for any preset number of cleaning cycles. Since the systems are enclosed to reduce solvent losses, volatile solvents, such as mineral spir- its, are often recommended because of their efficacy. There are, however, a number of alternative formulations offered by equipment manufacturers. Used solvent drains off the screen and is directed to a filtration system to remove particulates (inks and emul- sion). Following the filtration step(s), reclaimed solvent is typically reused. Some systems have separate wash, rinse, and air dry cycles or separate tanks for washing and rinsing. Solvent reservoirs must be replenished intermit- tently and changed once or twice a year. Filter wastes are typically dis- posed of as hazardous waste. Risk Compared to manual application of the traditional screen reclamation chemicals, the DfE risk evaluation of automatic screen washers found that worker inhalation exposures to the volatile organics used in solvents (min- eral spirits and lacquer thinner) were reduced by as much as 70 percent. Although health risks associated with dermal exposures to the chemicals remained high, these risks could be reduced dramatically if gloves are worn while handling the screens. Since the automatic screen washer is used for ink removal only, the risks associated with emulsion and haze removal remained the same as the traditional system's risks for these steps. Performance As described above, there are several types of automatic screen wash- ers, and for each type there are several manufacturers. Because of the resources required to do a full demon- stration of the equipment commercially available, performance demonstrations of automatic screen washers were not conducted as part of this project. Cost The DfE Screen Printing Project estimated costs for two automatic screen washers, assuming that the washers were used for ink removal only and that six screens (2,127 in2 each) were reclaimed per day. Screen reclamation costs using an automatic screen washer ranged from a low of $4.13 to $10.14, compared to $6.27 for traditional reclamation. The largest cost com- ponent is typical- ly equipment cost. Additionally, the savings of switching to this tech- nology would be greater if this costing accounted for the labor savings of workers moving on to other tasks once the screen is loaded in the washer. It is important to note that the cost per screen of the more automat- ed, higher-cost washer would be much lower if it operated nearer to its capacity of over 100 screens per day. Sodium Bicarbonate Spray A sodium bicarbonate (baking soda) spray technology was evaluated by the DfE Screen Printing Project to determine if it is potentially adaptable as an alternative screen reclamation technology. This technology is currently used for removing coatings, such as paint, grease, or teflon, from metal parts. In these applications, the technol- ogy has been successful in replacing hazardous cleaning chemicals. Based on the technology's success in other applications, it appears to be a promis- ing substitute for chemical screen recla- mation systems. Because the sodium bicarbonate spray technology had never been tested for screen reclamation, DfE staff conducted a one-day site visit to the equipment manufacturer's facility. Three imaged screens were inked with three types of ink. An inked screen was placed inside an enclosed cleaning booth, and the screen was passed, back and forth, under the sodium bicarbon- ate spray. No chemicals other than the sodium bicarbonate were used during the reclamation. Risk The DfE project did not under- take a risk assessment of this spray technology for a number of reasons. Sodium bicarbonate has been shown to be a fairly innocuous chemical, and it is not a skin irritant. In addition, it is a common ingredient in baked goods, toothpaste, and detergents. If this tech- nology proves to be a viable alterna- tive for screen reclamation in the future, a detailed assessment of the human health and environmental risk should be conducted. Performance The performance demonstration showed that cleaning the screen with a pressurized sodium bicarbonate spray alone, without water, resulted in exces- sive damage to the screen. Performance clearly improved when the sodium ------- FOR DRAFT October 1994 bicarbonate spray was combined with a pressurized water spray for screens with solvent-based ink and water-based ink. Typically, the emulsion came off in stringy rolls, and ink flaked off rather than dissolved. A 100 in2 area took approximately 15 minutes to clean. Fol- lowing this cleaning, there were either significant haze or ink residue spots. Slightly greater spray pressures or slightly longer times resulted in visual Sodium Bicarbonate Spray Enclosure screen damage or a ripped screen. Cleaning of UV-curable inks was inef- fective. No evaluation of subsequent use of these screens was made. Based on these limited demon- strations, initial results indicate that with further testing and research, this may be a promising new screen reclamation technology. Some modifications are needed to clean the screens faster and with less possibility of screen damage. For example, the physical support behind the screen greatly reduced the stress on the mesh. Use of hot water was suggested as a means of improving emulsion removal. Other modifications may include decreasing the sodium bicarbonate particle size, or modifying the delivery rate and pressure of the sodium bicarbonate and water sprays. Further testing is needed before a defin- itive evaluation of performance can be given. Cost Since the available equipment was not designed specifically for screen reclamation, we have assumed that the cost of equipment modified for screen reclamation would be similar to the cost of the equipment used in the per- formance demonstration. The available equipment ranges from $32,000 to $52,000, including a filtration system. The sodium bicarbonate itself costs between $0.65 to $0.75 per pound, based on amount purchased, and approximately one pound is sprayed per minute. If this technology proves to be a feasible alternative for screen reclamation after further development, a more detailed cost analysis can be conducted. The Design for the Environment Approach This case study describes three distinct screen reclamation technologies that could offer you the means to reduce employee exposures to chemi- cals. These technologies may also reduce the total cost of screen reclama- tion (which includes equipment, labor, reclamation products, and waste dis- posal costs). One of the technologies under development (sodium bicarbon- ate spray), offers the benefit of using relatively benign chemicals. The industry and EPA partici- pants in the DfE Screen Printing Project expect that the findings of this and other case studies can be transferred to screen printing operations throughout the U.S. and abroad. The benefits these technologies may offer include reduced occupational exposures and risks, fewer chemicals used for each screen reclamation, and reduced time spent on screen reclamation. The EPA's Design for the Envi- ronment Program encourages you to evaluate systematically the technolo- gies, practices, and procedures in your facility that may impact the environ- ment. Our goal in working with screen printers is to help you to make more informed choices, now and in the future, by catalyzing the search for and evaluation of cleaner alternatives. With this case study and others like it, we hope to illustrate the application of this goal and the pursuit of continuous environmental improvement. Through these efforts, we hope to assist printers in reducing pollution at its source. For more information on the technologies discussed here, contact your equipment suppliers. For more detailed information on other techno- logical and chemical alternatives, see the summary of the DfE Screen Printing Project full technical report, entitled the Cleaner Technologies Substitutes Assessment (CTSA). Additional case studies and other information products summarizing the evaluation of screen reclamation alternatives are also avail- able. To obtain other case studies or the draft Screen Reclamation CTSA, contact: U.S. EPA National Center for Environmental Pub- lications and Information (NCEPI) P.O. Box 42419 Cincinnati, OH 45242-2419 Fax: 513-891-6685 For a trade association information, please contact: Screenprinting and Graphic Imaging ' Association International (SGIA) 10015 Main Street Fairfax, VA 22031 Phone: 703-385-1335 dsX*1 For more informatiSn _ EPA's Design for the Environment Pro- gram contact: Pollution|Pr^ent^n Information U.S. 410 M Street^W Washington: DC ^ jyy. ,,. Phonej 2UZ?260-1023::. : v Fax: * WIU \l,-"'-4 O^ Recycled/Recyclable • 1T2 wm Printed with Soy/ConoJa tnEon paper that contarns at least 50% recycled fi ------- |