EPA-600/1-78-025
April 1978
Environmental Health Effects Research Series
                       EFFECTS  OF NITROGEN  DIOXIDE
    ON PULMONARY  FUNCTION IN HUMAN  SUBJECTS
                                         Health Effects Research Laboratory
                                        Office of Research and Development
                                       U.S. Environmental Protection Agency
                                  Research Triangle Park, North Carolina 27711

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                RESEARCH REPORTING SERIES

Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology.  Elimination of traditional grouping  was  consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:

      1.  Environmental  Health Effects Research
      2.  Environmental  Protection Technology
      3.  Ecological Research
      4.  Environmental  Monitoring
      5.  Socioeconomic Environmental Studies
      6.  Scientific and Technical Assessment Reports (STAR)
      7.  Interagency Energy-Environment Research and Development
      8.  "Special" Reports
      9.  Miscellaneous Reports
This report has been assigned to the ENVIRONMENTAL HEALTH EFFECTS RE-
SEARCH series. This series describes projects and studies relating to the toler-
ances of man  for unhealthful substances or conditions.  This work is generally
assessed from a medical viewpoint, including physiological or psychological
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clude biomedical  instrumentation and health research techniques  utilizing ani-
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 This document is available to the public through the National Technical Informa-
 tion Service, Springfield, Virginia 22161.

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                                                  EPA-600/1-78-025
                                                  April 1978
EFFECTS OF NITROGEN DIOXIDE ON PULMONARY FUNCTION
                    IN HUMAN SUBJECTS
           AN ENVIRONMENTAL CHAMBER STUDY

                             By

                    H.  David Kerr,  M. D.
                   Thomas J. Kulle, Ph. D.
                  Mary Lou McUhany, M. D.
                        Paul Swidersky
           University of Maryland School of Medicine
                    Department of Medicine
                Division of Pulmonary Diseases
                    29 South Greene Street
                 Baltimore, Maryland  21201
                             And
                 The Johns Hopkins University
              School of Hygiene and Public Health
         Department of Environmental Health Sciences
                    615 North Wolfe Street
                 Baltimore, Maryland  21205
                   Contract No. 68-02-1745

                        Project Officer

                     Dr. Brock T. Ketcham
              Health Effects Research Laboratory
               Environmental Protection Agency
        Research Triangle Park, North Carolina   27711
            U.S. Environmental Protection Agency
              Office of Research and Development
              Health Effects Research Laboratory
        Research Triangle Park,  North Carolina   27711

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                         DISCLAIMER
   This report has been reviewed by the Health Effects
Research Laboratory, U.S. Environmental Protection Agency,
and approved for publication.  Approval does not signify
that the contents necessarily reflect the views and policies
of the U.S. Environmental Protection Agency, nor does
mention of trade names or commercial products constitute
endorsement or recommendation for use.
                             11

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                                  FOREWORD
     The many benefits of our modern, developing, industrial society are
accompanied by certain hazards.  Careful assessment of the relative risk of
existing and new man-made environmental hazards is necessary for the estab-
lishment of sound regulatory policy.  These regulations serve to enhance
the quality of our environment in order to promote the public health and
welfare and the productive capacity of our Nation's population.

     The Health Effects Research Laboratory, Research Triangle Park,
conducts a coordinated environmental health research program in toxicology,
epidemiology, and clinical studies using human volunteer subjects.  These
studies address problems in air pollution, non-ionizing radiation, environ-
mental carcinogenesis and the toxicology of pesticides as well as other
chemical pollutants.  The Laboratory develops and revises air quality
criteria documents on pollutants for which national ambient air quality
standards exist or are proposed, provides the data for registration of new
pesticides or proposed suspension of those already in use, conducts research
on hazardous and toxic materials, and is preparing the health basis for
non-ionizing radiation standards.  Direct support to the regulatory function
of the Agency is provided in the form of expert testimony and preparation
of affidavits as well as expert advice to the Administrator to assure the
adequacy of health care and surveillance of persons having suffered imminent
and substantial endangerment of their health.

     This study was designed to look at the adverse effects, if any, of
inhalation of Nİ2 by human subjects with known diagnosis of asthma or      —•
chronic bronchitis.  N02, at the levels studied, often is present in "smog"
type atmospheres as are individuals with respiratory illness.  This study
gives some insight into the effect of a specific pollutant  (NO2) at a known
concentration  (.5 ppm) and time  (2 hours) on an already compromised human
respiratory system.  Results from this investigation will provide data on
the spectrum of pulmonary responses in two large classes of the population
at risk.   The data will aid HERL in further defining short-term adverse
effects of this specific pollutant.
                                      John H. Knelson, M.D.
                                            Director,
                               Health Effects Research Laboratory
                                      111

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                                 ABSTRACT

Twenty human subjects with asthma and chronic bronchitis and ten normal,
healthy adults were exposed to 0. 5 ppm of nitrogen dioxide (NO2) for two
hours in an environmental chamber.   They engaged in one 15-minute,
light to medium-exercise stint on a bicycle ergometer during this period.
The subjects with asthma experienced the greatest symptoms with exposure
to NO2ğ i. e.,  seven of. thirteen noting slight burning of the eyes, slight
headache,  and chest tightness or labored breathing with exercise.  One
each of the subjects with chronic bronchitis and the healthy,  normal
group experienced slight nasal discharge.  Significant changes from
control values for the group as a whole with exposure to NO2 were observed
for the following pulmonary function tests:  quasi-state compliance for
the twenty subjects with asthma  and chronic bronchitis as well as for
the ten normal subjects, and functional residual capacity for the twenty
subjects with  asthma and chronic bronchitis.  Subjects with asthma
and chronic bronchitis as separate groups (n = 13 and 7 respectively) did
not show any significant changes in pulmonary function with the  NO2
exposure,  even though the group of thirteen subjects with asthma experienced
the greatest symptoms.
                                     IV

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                              CONTENTS



                                                        Page


  Abstract                                                iv


  List of Tables                                           vi


  Acknowledgments                                       V11


  Sections


  I    Conclusions                                         1


  II    Recommendations                                   2


 III    Introduction                                         3


 IV    Materials and Methods                               4
         t

 V     Experimental Phase (Results)                        9


 VI    Discussion                                         16


VII     References                                         17


       Glossary                                           20
                                   v

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                             TABLES
No.                                                      Page

 1      Anthropometric Data,  Smoking History, and
        Symptoms During Exposure to Nitrogen Dioxide
        of 30 Human Subjects Classified According to
        Diagnosis                                         11

 2      Mean Values of Ventilatory Function Derived
        from Spirometry                                  12

 3      Mean Values of Tests Derived from
        Plethysmographic Measurements                   13

 4      Mean Values of Tests Derived from Single-
        Breath N2 Elimination Rate                        14

 5      Mean Values of Tests Derived from
        Measurements of Transpulmonary Pressure        15
                                VI

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                            ACKNOWLEDGMENTS
The authors wish to thank Richard L. Riley,  M. D.  for guidance in
this investigation.
                                     vii

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                                  SECTION I

                                CONCLUSIONS

 The symptoms reported were minimal, did not correlate with functional
 changes, and are of doubtful significance.

 The results of this investigation are in general negative, which is in
 itself useful.   It appears that no significant alteration in pulmonary
 function is likely to result from a two-hour exposure to 0. 5 ppm NO2
alone in normal subjects or patients with chronic obstructive pulmonary
 disease. The few significant changes  reported here may be due to
 chance alone.

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                                SECTION II

                           RECOMMENDATIONS


It is of interest to compare this NO2 study with a previously reported 6-hour
ozone exposure study with normal human subjects, also conducted in our
environmental  chamber, using the same 0. 5 ppm concentration.   With ozone
(0. 5 ppm for 6  hours), significant decrements in pulmonary function occurred
with exposure for the 20 subject group as a whole in specific airway
conductance, pulmonary resistance, forced vital capacity,  and 3-second
forced expiratory volume.  However, no  significant changes in specific
airway conductance and forced vital capacity occurred following the first
two-hours of ozone exposure; the changes reached significance only after
four and six hours, respectively, of exposure.  Subjects, who experienced
symptoms, in general,  were those who developed objective evidence of
decreased pulmonary function.

With this study we are reasonably confident that exposure of patients with
asthma and chronic bronchitis to 0. 5 ppm NO2 for two hours does  not
produce  a significant decrement in pulmonary function.  Exposure of 0.5
ppm NO2 for longer than two hours could  result in a significant decrement
and possible correlation with the symptoms experienced with exposure.

Concern could  be expressed for patients with COPD exposed to 0.5 ppm
NO2 for longer  than two hours, i. e.,  six hours.  Further studies using
increased exposure time appear appropriate.

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                             SECTION HI



                           INTRODUCTION


    Nitrogen dioxide (NO2) levels in urban air pollution episodes in the



U.S.  (1962 - 1968) have been measured between 0. 10 and 0. 80 parts per



million (ppm) as a maximum hourly average with short-term peaks as high



as 1.27 ppm (1).   The industrial hygiene occupational exposure for nitrogen



dioxide is set by the American Conference of Government Industrial Hygienists



(ACGIH) at 5 ppm as a ceiling value not to be exceeded (2).  Limited studies



of the toxic  effects of NO2 in man generally have considered high exposure



levels (0. 5 to 5. 0 ppm) for periods of time from ten minutes to three hours.



Measurements of pulmonary function have shown conflicting results; in    —--



some cases marked increase in pulmonary resistance was observed with



exposure, while no change in pulmonary function was reported by other



investigators (3,4, 5).  Epidemiologic and pulmonary function studies of



children and their families living in neighborhoods with elevated NO2 levels



(proximity to large TNT plant) have demonstrated diminished pulmonary



function (FEV     ) and/or an excess of lower respiratory illnesses
             U. i D


(6, 7, 8).  Horvath, et. al., exposed normal human subjects to 0. 5 ppm NO2



for two hours,  observing no significant decrement in pulmonary function (9).





     Few controlled studies employing  specific NO2 exposures have been



performed on subjects  with chronic pulmonary disease.  The  purpose of this



investigation was  to determine if measurable pulmonary function effects



occur breathing 0. 5 ppm (940 fig/m ) nitrogen dioxide for two hours in

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patients with asthma and chronic bronchitis and in normal subjects.


                              SECTION IV



                     MATERIALS AND METHODS



    In order to restrict environmental effects to nitrogen dioxide, these



experiments were carried out with subjects confined to an environmentally



controlled chamber.  A more detailed description of the environmental



chamber facility is presented in a previously published paper (10).


                                     o
Temperature was maintained at 75 ħ1  F with relative humidity 45 ħ5%.



All room  air was exhausted to the outside, instead of recirculating it



through the  conditioning system, enabling precise control of nitrogen



dioxide concentration during the exposure phase.  A complete room air



exchange  occurred every 2. 5 minutes.  Air entering the 2. 1 x 4. 3 x  2. 4



meter (7x14x8 foot) exposure room was passed through high-efficiency



particulate absolute filters and activated carbon filters approaching class



100 cleanliness (<100 particles >0. 5;um/foot ) or (<3534 particles >0.5yum/m ).




    Nitrogen dioxide, in compressed gas  cylinders of 6000 ppm



concentration,  was accurately mete red into the exposure room of the



chamber via the room air input diffuser.  For the safety of the human



subjects,  the NO2 concentration was  monitored, recorded, and controlled



continuously by two NO2 analyzers,  one employing the colorimetric method,



the other  the coulometric method.  The colorimetric analyzer has good



accuracy  but a long response time (90% of full scale indication) of nine

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minutes; whereas, the coulometric analyzer used had a response time




within one-half a minute, but with somewhat less  accuracy,  thus being




able to rapidly indicate changes in  NO2 concentration in the exposure room




when they occurred.  Prior to and following the NO2 study, the two




analyzers were checked for standardization with an accurate NO2 source




at the National Bureau of Standards  (NBS),  Gaithersburg,  Maryland, using




the Federal Register Method described in Code of Federal Regulations




40 CFR,  Part 50.







     In order to assure accurate setting of the NO2 concentration for each




exposure study, the colorimetric analyzer was  calibrated in the laboratory




prior to and on the day of the NO2 exposure of each subject.  An NBS




calibrated NO2 permeation tube in a temperature-controlled portable




permeator was used as the calibrator for setting the span controls on the




analyzer.  In addition,  the coulometric analyzer was also checked for




standardization at NBS midway between the two-year study.







     Prior to initiating the subject exposure studies,  an NO2 concentration




profile was taken of the chamber exposure  room at four- and six-foot levels




above the chamber room, representing sitting and standing  levels of the




subject's mouth and nose.  The range of concentrations varied between




".47 and 0. 52 ppm NO2.







     Nitrogen dioxide mon tor strip  chart recordings wer. made during

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each subject exposure.  Means and standard deviations were determined




from three minute data points over the two-hour exposure period.  The




means of the various exposures ranged between 0.49 and 0.51 ppm,  with




the standard deviations ranging from 0. 01 to  0. 02 ppm.







    Thirteen subjects with asthma,  seven with chronic bronchitis,  and




ten normal, healthy subjects, were  studied.  Informed consent was




obtained from each subject after the nature of the procedure had been




fully explained.  Smokers  were asked to abstain for 24 hours prior to,




and during the two days of the research.  Twenty-three subjects were




male and seven female.  Each subject served as his own control.  The




order of subject study in pairs and the sequence of physiological tests




was not varied.







    A two-day study procedure was employed; on the first or control day




the subjects  remained in the exposure room for two hours breathing




filtered clean air.  On the second day, they breathed 0. 50 ppm nitrogen




dioxide  for two hours at the same time of the  day.  Pulmonary  function




tests were performed in sequence (spirometry, plethysmography, and




single breath nitrogen elimination rate) at the beginning and following




the two  hour chamber confinement on  both day 1 and day 2.  The remaining




two physiological tests (pu'.r.ionary resistance and compliance)  were done




following the above tests .*  y at the end of the two hour confinement on




day 1 and day 2.  Bicycle erne-meter exercise at a light-to-moderate

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work load of 60-100 watts, depending upon the subject's physical




characteristics and tolerance, at 60 RPM for 15 minutes was performed




during the first hour on both day 1 and day 2.  All pulmonary function




tests were performed in a seated position to insure comparability of




lung volumes from the various tests.  To assure technically satisfactory




subject performance, the subjects repeatedly executed each test,  except




those requiring the esophageal balloon, during preliminary practice




sessions and before confinement on both days.







     Ventilatory function testing was performed as a single forced vital




capacity (FVC) by standard technique employing a waterseal direct




writing spirometer.  All volumes were expressed in liters (L.) at body




temperature,  pressure, saturated (BTPS).







     Airway resistance (Raw) and volume of thoracic gas (Vtg) were




determined by the whole-body pressure plethysmographic technique of




DuBois, et. al. (H) with certain technical modifications  (10).  Each of




ten panting breaths for Raw and  Vtg at functional residual capacity (FRC)




were determined by computer analysis of analog tape recordings of




pressures,  flow, and volume. Airway resistance measurements




determined at 1 L/sec.  airflow (0. 5 L/sec. inspiratory  to 0.5 L/sec.




expiratory) were converted to specific airway conductance (SGaw  =




1/Raw/Vtg), using the V% at which each Raw was measured,  and




expressed as the mean of the t^n panting breaths.  Practice sessions




                                  7

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enabled most subjects to perform the panting maneuvers of Raw and



Vtg at or very close to FRC.   Total lung capacity (TLC) was expressed



as the sum of FRC and the inspiratory  capacity, and residual volume



(RV) was expressed as the difference between FRC and the expiratory



reserve volume.  All lung volumes were expressed in liters  and



SGaw as I/cm H2O x sec. units.





    Tests of single breath nitrogen elimination rate were calculated



from  an XY plot of expired nitrogen concentration  vs.  expired volume



from  TLC to RV following a full inspiration of 100% oxygen from RV



to TLC.  Rate of expiration was controlled to not exceed 0. 5 L/sec.



Phase III was expressed as change in percent alveolar nitrogen con-



centration per liter of expired volume, and was determined from the



best fit straight line of the alveolar sample mid-portion of the XY plot.



Phase IV ("closing volume") was measured from RV to the Phase  Ill-



Phase IV junction  (12). One reader performed all of the line-fitting



procedures.





    Pulmonary  resistance (R  ) and compliance (C  ) were determined by
                            L                   L


the electronic subtracter  method of Mead and Whittenberger  (13).   In order



to stabilize volume history, each subject fully inflated his  lungs to TLC



prior to performing tb^ quasi-static  and dynamic compliance maneuvers.



Dynamic compliance -,vas  performed  at frequencies of  16 breaths  per



minute (C  dyn. 16), 32/min.  and 48/min. in rhythm with an audio
         L


                                 8

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metronome while maintaining a tidal volume of one liter for 8 to 10
breaths at each breathing frequency.  To determine O  dyn.,  a portion
                                                   L
of the trans pulmonary pressure proportional to airflow was subtracted
by manual potentiometer adjustment for the best fit straight line XY
oscilloscope  display of this resultant pressure vs. tidal volume.  For
R  ,  a portion of transpulmonary pressure proportional to volume change
 J_ğ
was  subtracted in a similar fashion with straight line fitting of the XY
plot  of this pressure vs. airflow.   All subtractions and readings were
performed from playback of analog tape recordings of  airflow, volume
change, and transpulmonary pressure.  This procedure enabled re-
reading of the recordings to verify values and also to standardize the
length of time each subject performed at the different frequencies,  thereby
avoiding excessive alveolar ventilation from prolonged measurement.
Pulmonary resistance was expressed as cm H2O/L/sec.  and was not
corrected for the Vtg at which it was measured.  All compliance data
were expressed as ml/cm H2O.

                             SECTION V
                 EXPERIMENTAL PHASE (RESULTS)
     The odor of nitrogen dioxide was  readily perceptible at the 0. 50  ppm
concentration, but most subjects reported that they became unaware  of
the odor after 15 minutes  of exposure.  None of the subjects considered
the odor to be unpleasant.  Subjects were asked to keep note of symptoms
they might experience; following vhe exposure study, they were

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specifically asked about cough,  sputum, irritation of mucous membranes,




and chest discomfort.  Symptoms reported were in general mild and




more frequently reported by subjects with asthma.   Only one chronic




bronchitis patient and  one normal subject experienced the very mild




symptom of slight rhinorrhea (Table 1), while more than half (seven of




thirteen) asthma patients reported some degree of chest tightness,




burning of the eyes, headache or dyspnea with exercise and exposure to




NO2.  There did not appear to be any relationship between  history and




symptoms.







    Although asthma patients experienced the most symptoms,  no




significant changes were observed in any of the parameters of pulmonary




function  (Tables 2 to 5).  Normal subjects disclosed variance in the pre-




exposure (0-Hour) Phase IV nitrogen elimination rate; but, there was




no significant difference between the control and exposure  (2-Hour)




values (Table 4).  After NO2 exposure, a significant decrement  in




static compliance was noted in normal subjects but not observed in either




patient group; while there were no significant changes in dynamic




compliance for any subject  group (Table 5). Chronic bronchitis




patients demonstrate variance in the pre-exposure (0-Hour) Phase III




nitrogen elimination >-ate,  although no significant difference was shown




between the control si c. exposure (2-Hour)  values (Table 4).  No other




significant differer          '-served in any of the  pulmonary function




tests.  When the data  :"? - ^'.? t\venty patients are considered together,






                                 10

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                              TABLE 1

ANTHROPOMETRIC DATA, SMDKING HISTORY, AND SYMPTOMS DURING EXPOSURE TO
NITROGEN DIOXIDE OF 30 HUMAN SUBJECTS CLASSIFIED ACCORDING TO DIAGNOSIS
Subject
NO.

1
2
3
4
5
6
7
10
11
12
Mean
S.D.
Sex

M
M
M
M
M
M
M
M
M
M


Age
(years)

44
29
42
63
39
26
28
29
22
23
34.5
12.7
Height
(cm)

188
175
183
174
173
183
190
183
179
190
181.8
6.4
Weight
(kg)
Normal
73
66
77
64
70
70
92
83
79
83
75.7
3.7
Smoking
History *
(n = 10)
+
+
0
0
0
0
0
•f (pipe)
0
0
3/10

Symptoms
During Exposure f

0
0
0
+ (nasal discharge)
0
0
0
0
0
0
1/10
















Chronic Bronchitis (n = 7)
13
17
20
21
26
29
30
Mean
S.D.

8
9
14
15
16
18
19
22
23
24
25
.27
28
Mean
"S.D.
* 0,
to,
M
M
M
M
F
F
F



M
M
M
M
M
F
F
M
F
M
M
M
F


53
25
30
24
32
24
24
30.3
10.5

41
23
30
22
24
19
21
21
38
50
20
20
19
26.8
10.0
nonsmoker; +,
no symptoms;
171
165
188
175
168
168
161
170.8
8.7

161
178
165
164
185
159
166
173
160
175
175
185
171
170.5
8.9
smoker
+, symptom
86
99
92
75
75
61
76
80.6
12.7
Asthma
68
75
64
65
64
62
62
68
49
80
72
69
73
67.0
7.6
o
4- (pipe)
4-
--
-r
O
-
3/7

(n = 13)
0
0 (former smoker)
-i- 'occasional)
7
-
0
r

;"•
0 former smoker)
r
light)

-.• ,- :

0
0
0
0
+ (nasal discharge)
0
0
1/7


0
0
+ (chest tightness)
+ (slight headache)
0
+ (slight burning of
0
0
+ (chest tightness)
+ (chest tightness)
+ (slight burning of















eyes)




eyes)
+ (dysonea with exercise)
0
7/13




experienced.
                                       11

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MEAN VALUES OF VENTILATORY FUNCTION DERIVED FROM SPIRQMETRY
Subject
Groups
Normal Subjects
(n = 10)
Mean

Day 1 Day 2
(Control) (Ex;xji.:,nre)
FVC
0-f'
•'. 30

4.05
4.14

4.91
4.98

9.79
10.00

3.70
3.94

1.84
1.82

..29
•'.27

4.06
4.10

4.98
4.94

9.04
9.55

3.69
3.74

1.81
1.67
Standard
Error of
Difference
in Means

0.05
0.03

0.05
0.04

0.05
0.03

0.54
0.42

0.10
0.13

0.10
0.08
Patients with Asthma
(n = 13)
Mean

Standard
Error of
Day 1 Day 2 Difference
(Control) (Exposure) in Means

4.51
4.42

3.15
3.12

4.15
4.09

5.76
5.93

2.51
2.65

1.37
1.25
•
4.49
4.38

3.25
3.14

4.18
4.07

5.85
5.86

2.83
2.70

1.23
1.24

0.07
0.05

0.07
0.05

0.06
0.05

0.27
0.30

0.18
0.13

0.08
0.04
Patients with Chronic Bronchitis
(h = 7)
Mean

Standard
Error of
Day 1 Day 2 Difference
(Control) (Exposure) in Means

4.88
4.81

3.66
3.50

4.47
4.38

8.14
7.20

3.15
2.71

1.63
1.55

4.93
4.82

3.64
3.51

4.51
4.38

8.07
7.51

3.02
2.81

1.63
1.53

0.04
0.06

0.04
0.08

0.03
0.06

0.61
0.47

0.12
0.23

0.08
0.07
                             12

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                                                                      TABLE  3

                                           MEAN  VALUES OF  TESTS DERIVED  FROM  PLETHYSMOGRAPHIC MEASUREMENTS
Subject
Groups

SGaw
0-Hour
2-Hour


Day 1
(Control
.218
.246
Normal Subjects
(n = 10)
Mean
Patients with Asthma
(n - 13)
Standard
Error of
Day 2 Difference
) (Exposure) In Means
.219
.238
.014
.014
Mean
Day 1
(Control)
.137
.137
Day 2
(Exposure)
.136
.142
Standard
Error of
01 f ference
1n Means
.007
.012
Patients with Chronic
(n= 7)
Mean
Day 1 Day 2
(Control) (Exposure)
.196 .185
.198 .180
Bronchitis
Standard
Error of
01 f ference
In Means
.016
.014

All Patients
(n = 20)
Mean
Day 1
(Control)
.158
.159
Day 2
(Exposure)
.153
.156

Standard
Error of
Difference
in Means
0.007
0.009
TLC
 0-Hour
 2-Hour
7.24
7.38
7.37
7.44
0.13
0.17
6.47
6.32
6.65
6.49
0.11
0.11
6.67
6.63
6.87
6.86
0.11
0.13
6.54
6.44
6.741"
6.63*
0.08
0.08
FRC
 0-Hour
 2-Hour
3.83
3.91
3.90
3.83
0.10
0.13
3.37
3.19
3.40
3.38
0.09
0.13
3.42
3.37
3.57
3.57
0.09
0.13
3.39
3.26
3.46
3.45*
0.07
0.09
RV
 0-Hour
 2-Hour
*p < . 05

tp<.025
1.99
2.08
2.08
2.16
0.12
0.18
1.96
1.90
2.16
2.11
0.09
0.12
1.79
1.82
1.94
2.04
0.08
0.11
1.90
1.87
2. oaf
2.09t
0.07
0.09

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                              TABLE 4



MEAN VALUES OF TESTS DERIVED FROM SINGLE-BREATH N., ELIMINATION RATE
Subject
Groups

Phase III
0-Hour
2-Hour
Phase IV
0-Hour
2-Hour
Phase IV
+ RV
0-Hour
2-Hour
*p < . 05
tp<.01
Normal Subjects
(n = 10)
Mean
Day 1
(Control)
1.15
1.13
0.62
0.54
2.61
2. 62'


Day 2
(Exposure)
1.26
1.08
0.47*
0.65
2.55
2.81


Standard
Error of
Difference
1n Means
0.13
0.13
0.06
0.07
0.14
0.20


Patients with Asthma
(n * 13)
Mean
Day 1
(Control)
1.42
1.30
0.44
0.36
2.44
2.30


Day 2
(Exposure)
1.58
1.41
0.35
0.39
2.54
2.54


Standard
Error of
Difference
in Means
0.18
0.11
0.06
0.06 •
0.09
0.13


Patients with Chronic
(n = 7)
Mean
Day 1
(Control)
1.14
1.15
0.41
0.48
2.20
2.30


Day 2
(Exposure)
0.85?
0.92
0.53
0.39
2.47
2.43


Bronchitis
Standard
Error of
Di f f erence
1n Means
0.07
0.10
0.13
0.18
0.15
0.18



All Patients
(n = 20)
Mean
Day 1
(Control)
1.32
1.28
0.43
0.41
2.35
2.30


Day 2
(Exposure)
1.33
1.22
0.41
0.39
2.51
2.50



Standard
Error of
Difference
in Means
0.13
0.07
0.06
0.07
0.08
0.10



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                                                                                TABLE 5

                                               MEAN VALUES OF TESTS DERIVED FROM MEASUREMENTS OF TRANSPULMONARY PRESSURE
           Subject                  Normal Subjects          Patients with Asthma         Patients with Chronic Bronchitis             All Patients
           Groups	(n '  10)	(n " 13)	(n = 7)	(n = 20)	


                                             Standard                           Standard                           Standard                           Standard
                      	Mean             Error of     	   Mean	Error of   	Mean	Error of           Mean	    Error of
                       Day""!       Day 2Difference    Day!      Day 2     Difference    Day 1      Day 2     Difference    Day 1     Day 2      Difference
_,         	(Control)   (Exposure)    in Means   (Control^  (Exposure)   in Means   (Control)  (Exposure)   in Means   (Control)  (Exposure)   in Means
tn

          RL
           2-Hour      2.00        1.94        0.10       4.41        4.43        0.19       3.23        3.17        0.11       4.00        3.99        0.13


          CL Stat
           2-Hour      346         286*         18        269         253          10        366         334          18        303         282f         9


          CL dyn 16
           2-Hour      196         197          12        160         159           6        210         207           9        178         176          5


          CL dyn 32
           2-Hour      190         189          18        137         131           7        187         193          14        153         150          7


          CL dyn 48
           2-Hour      194         194          21        121         123           7        155         170           8        133         140          6
          *p<.025
          tp<.05

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significant increases were noted in TLC, FRC, RV,  and static compliance




on the exposure day (Tables  3 and 5).







                                SECTION VI







                                DISCUSSION







    A double-blind study would have been desirable for this research.




However, the odor of NO2 is detectable at 0.5 ppm, thus making a double-




blind study impractical.  The symptoms reported in this study were in




general mild and more frequently reported by the subjects with asthma.




Although these patients experienced the most symptoms no significant




changes in pulmonary function were observed.







    Considering the 13 patients with asthma and the seven patients with




chronic bronchitis, significant changes in some pulmonary function para-




meters only occurred when they were  grouped together as 20 subjects.




These changes in compliance, distribution of ventilation and static lung




volumes (TLC,  FRC,  RV) suggest some degree of change in elastic




properties.   However,  no meaningful change in function can be implied as




significant differences also were generally observed prior to exposure.




There were no significant changes in any of the flow resistance parameters




by spirometry,  plethysmography, or esophageal balloon techniques.
                                     16

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                            SECTION VII



                          REFERENCES







1.   Air Quality Criteria for Nitrogen Oxides,  National Air Pollution




    Control Administration, Washington, D. C. , Publication No.




    AP-84, 1971.







2.   American Conference of Government Industrial HygieniBts: Threshold




    Limit  Values for Substance in Workroom Air.  Adopted by ACGIH,




    1976.







3.   Abe, M. 1967.  Effects of Mixed NO2 - SO2 Gas on Human Pulmonary




    Functions.  Bulletin Tokyo Med. Dent. Univ.,  14;  415-433.







4.   Suzuki, T.  and K.  Ishikawa 1965.  Research on Effect of Smog on




    Human Body, Research and Report on Air Pollution Prevention




    No.  2; 199-221, (In Japanese).







5.   Rokaw, S. N., et. al. 1968.  Human Exposures to Single Pollutants -




    NO2 in a Controlled Environment Facility (Pre-Print of  Presentation




    at the  Ninth AMA Air Pollution Medical Research Conference),




    Denver.







6.   Shy, C. M., Creason,  J. ?. , Pearlman,  M. E., McClain,  K. E. ,




    Benson, F. B. ,  anc ^'oung.  V. M.  1970.   The Chattanooga School




    Study. Effects  of Corn.rrv,.r.ity Exposure to Nitrogen Dioxide, Methods,




    Description of Pollutant F.v^oiure and Results of Ventilatory Function




    Testing.  J.  Air Pollut. Contr. Assn.,  20 (8); 539-545.







                                 17

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7.    Shy, C.M., Creason,  J. P., Pearlman, M. E., McClain, K. E.,




    'Benson,  F. B. , and Young,  M. M. 1970.  The Chattanooga School




     Children Study:  Effects of Community Exposure to Nitrogen




     Dioxide.  Incidence of Acute Respiratory Illness, J. Air Pollut.




     Contr. Assn., 20 (9):  582-588.
 8.   Pearlman, M. E., Finklea, J. F., Creason,  J. P., Shy, C.M.,




     Young,  M. M.,  and Horton, R. V. M.  1971.  Nitrogen Dioxide and




     Lower Respiratory Illness, Pediatrics,  47 (2);  391-398.







 9.   Horvath, S. M., and L. J. Folinsbee.  1977.   Effects of NO2 on




     Lung Function in Normal Subjects.  Report Under Contract with




     University of California  EPA No. 68-02-1757.







10.   Kerr, H. D.  1973.  Diurnal Variation of Respiratory Function




     Independent of Air Quality:  Experience with an Environmentally




     Controlled Exposure Chamber for Human Subjects, Archives of




     Environmental Health, 26;  144.







11.   DuBois, A. B., Botelho, A. F.,  Comroe, J. H., Jr. 1956.  A New




     Method  for Measuring Airway Resistance in  Man Using a Body




     Plethysmograph: Values in Normal Subjects and in Patients with




     Respiratory  Diseases, Journal of Clinical Investigation,  35:  327.
                                  18

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12.   Anthonisen, N. 1972.  Report of Informal Session on "Closing




     Volume" Determinations, Federation Meetings, Atlantic City,




     New Jersey.







13.   Mead, J.,  and Whittenberger,  J. L. 1953.   Physical Properties




     of Human Lungs Measured During Spontaneous Respiration,




     Journal of Applied Physiology, _5:  779.







 14. Kerr,  H.D., Kulle, T. J., Mcllhany, M. L. and Swidersky,  P.




     1975.  Effects of Ozone on Pulmonary Function in Normal Subjects -




     An Environmental Chamber Study,  American  Review of Respiratory




     Disease, 111:  763-773.
                                   19

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                           SECTION VIII


                            GLOSSARY

Plethy smog r aphy - Body box method for determining airway resistance
and static lung volumes.

Single Breath Nitrogen Elimination Rate - Percentage rise in nitrogen
fraction per unit of volume expired.

Pulmonary Resistance (Rj^) - The sum of airway resistance and viscous
tissue resistance.

Static Compliance (C^ stat^ ~ Measure °f elastic recoil with no or
insignificant airflow.

Dynamic Compliance (Cy  dvnJ ~ Volume change per unit of trans -
pulmonary pressure minus the pressure of pulmonary resistance
during airflow.
                                 20

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                                  TECHNICAL REPORT DATA
                           (Please read Instructions on the reverse before completing)
 REPORT NO.
 EPA-600/1-78-025
                             2.
                                                          3. RECIPIENT'S ACCESSION NO.
 TITLE AND SUBTITLE
 Effects of Nitrogen Dioxide on Pulmonary Function
 in Human Subjects
               5. REPORT DATE
                 April 1978
               6. PERFORMING ORGANIZATION CODE
 AUTHOR(S)
 H.  David Kerr, Thomas J.  Kulle,  Mary Lou Mcllhany
 and Paul Swidersky	
                                                          8. PERFORMING ORGANIZATION REPORT NO.
 PERFORMING ORGANIZATION NAME AND ADDRESS
 University of Maryland  School of Medicine
 Baltimore, Md 21201, and
 The Johns Hopkins University
 Baltimore, Md 21205	
               10. PROGRAM ELEMENT NO.

                  1AA601
               11. CONTRACT/GRANT NO.

                 68-02-1745
12. SPONSORING AGENCY NAME AND ADDRESS
  Health Effects Research  Laboratory
 'Office of Research and Development
  U.S.  Environmental Protection Agency
  Research Trianale Park,  N.C.  27711
                                                           13. TYPE OF REPORT AND PERIOD COVERED
RTP,NC
<. SPONSORING AG-ENCY CODE '"•'

 EPA 600/11
15. SUPPLEMENTARY NOTES
16. ABSTRACT
  Twenty human subjects with asthma and chronic bronchitis and ten normal, healthy
  adults were esposed to  0.5 ppm of nitrogen dioxide  (N02) for two hours in an  environ-
  mental chamber.  They engaged in one 15-minute,  light to medium-exercise stint  on
  a bicycle ergometer during this period.  The subjects with asthma experienced the
  greatest symptoms with  exposure to NC>2ğ i.e., seven of thirteen noting slight
  burning of the eyes, slight headache, and chest  tightness or labored breathing  with
  exercise.  One each of  the subjects with chronic bronchitis and the healthy,  normal
  group experienced slight nasal discharge.  Significant changes from control.values
  for the group as a whole with exposure to NC>2 were  observed for the following
  pulmonary function tests:   quasi-state compliance for the twenty subjects with  asthma
  and chronic bronchitis  as well as for the ten normal subjects, and functional residua
  capacity for the twenty subjects with asthma and chronic bronchitis.  Subjects  with
  asthma and chronic bronchitis as separate groups (n = 13 and 7 respectively)  did  not
  show any significant changes in pulmonary function  with the NO2 exposure, even  though
  the group of thirteen subjects with asthma experienced the greatest symptoms.
17.
                               KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
  b. IDENTIFIERS/OPEN ENDED TERMS  C.  COS AT I Field/Group
  respiratory system
  nitrogen dioxide
  air pollution
  exercise (physiology)
  respiratory diseases
                              06 F, P, T
13. DISTRIBUTION STATEMENT

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