-------
Sulfur Mustard
Name: _ ID no: .
(C1CH2CH2) S
Formula: . H. I.:
Solubility: H O(cold): 800 g/lOOcc H.O(hot): NA g/lOOcc
@ 20°C -2
Density: 1.274 g/cc @ Vapor pressure:0.05mm Hg@ 10°C
(Liquid)
5.4 (air=l) @ 20°C O.lmm Hg @ 20°C
(Gas)
MP 13.5°C BP 227.8°C @ 0'2mm HS @ 30°C
Flammability hazard: Severe. Decomposition products are flammable.
Explosive hazard: Decomposition products may be explosive.
Volatile hazard: Severe. Fumes in air. Evolves toxic, flammable and
possibly explosive gases when heated to decomposition.
Toxicology: Highly toxic by contact with skin and mucous membrane. A
blister gas. Highly toxic by inhalation and ingestion. May be fatal.
TLV: In air; 0.0003 mg/m
Estimated _5
Provisional limit: In air: 3xlO"6 mgV In water: 1.5x10 mg/1
• Estimated Estimated
Special precautions: Respirator, protective clothing. Impure sulphur
mustard will corrode iron and steel containers with a pressure rise.
Comments: Not acceptable for underground storage without treatment
Treatment products are essentially nontoxic. Underground storage of
products is optional.
307
-------
Name: TNT (Trinitrotoluene) _ ID no: 418
19
Formula: ___L _ H.I.:
Solubility; H O(cold):Insolu- g/lOOcc H?0(hot):Insoluble g/lOOcc
_£ ble _£
Density: 1.65 g/cc @ 20°C Vapor pressure.0.042mm Hg@ 80°C
@ 0.1D6mm Hg@ 100°C
n @ O @
MP 81 C Autoignition temp 570 C (Explodes)
Flammability hazard: Severe. See explosive hazard.
Explosive hazard: Severe. A high explosive, normally requiring initi-
ation by a primary explosive to detonate but may detonate when subjected
to a flame or percussion.
Volatile hazard: Severe. May emit toxic fumes upon explosive decom-
position.Nonvolatile at ambient conditions.
Toxicology: Toxic by inhalation of fumes and ingestion. Skin contact
causes staining and in some individuals, dermatitis.
3
TLV: In air; 1.5 mg/m
o
Provisional limit: In air: 0.015 mg/m In water: 0.075 mg/1
Special precautions: Treatment at point of origin recommended due to
transport hazard. Explosive.
Comments; Not acceptable for underground storage without treatment.
Treatment products are essentially nontoxic. Underground storage of
products is optional.
308
-------
Name: Tear Gas (CN) or Chloroacetophenone ID nQ. 422.107
H.T.:
CQH_OC1
Formula: g ' „ T . 12
Solubility; H O(cold) : Insol- g/lOOcc H,0(hot) : NA g/lOOcc
— - uble _± -
Density; 1.321 g/cc @ 20°C Vapor p res sure«.o 12mm Hg3 0°C
0.16mm Hg @ 50°C
MP 58-59°C BP 247°C
Flammability hazard; Slight. Decomposition products may be flammable.
Explosive hazard; Slight. Decomposition products may be explosive.
Volatile hazard; Severe. Emits toxic fumes in air and when heated.
When heated to decomposition evolves toxic fumes of chlorides and
possibly H-. Reacts with steam to evolve HCL fumes.
Toxicology: Highly toxic by contact with skin and mucous membranes
especially eyes. Toxic by inhalation and ingestion.
TLV: In air; 0.30 mg/ra
*j
Provisional limit; In air; 0.003 mg/m In water; NA mg/1
Special precautions; Respirator, protective clothing. Avoid heating.
Comments: Will react with water or steam to produce toxic and corrosive
fumes. Not acceptable for underground storage without treatment. Treat-
ment products are essentially nontoxic. Underground storage of products
is optional.
309
-------
. Tear Gas (CS) (2-Chlorobenzylidene malononitrile)Tri . 423
• ^^••^^^^•••MMM^B^B^^^^^^^MMMMM—•••••••MBM^^^HHnMWM^^BW^M^B^^K^VBMMBH^ A-U Tl O • ^MOTBWMI
C, ^H.N.Cl
Formula: __±LL1 H.I.: li.
Solubility; H20(cold): NA g/lOOcc H20(hot): NA g/lOOcc
Density: NA
Vapor pressure: NA @
9
MP 95°C BP 310-315°C @ @
Flammability hazard; Slight. Products of hydrolysis w/moisture may
be flammable.
Explosive hazard: Nonexplosive.
Volatile hazard; Severe. Used as an aerosol for riot control. Forms
highly toxic solid with moisture. When heated to decomposition emits
toxic fumes.
Toxicology: Highly toxic by contact w/skin and mucous membranes. Hy-
dro lyzes w/moisture to yield highly toxic malonic acid nitrile.
TLV:
In air: 0.40
mg/m"
Provisional limit: In air: 0.004 mg/m In water: 0.020
Special precautions: Avoid heating and contact with moisture.
protective clothing.
mg/1
Respirator,
Comments; Not acceptable for underground storage without treatment.
Treatment products are essentially nontoxic. Underground storage of
products is optional.
310
-------
Name: Tetrazene ^ ^ 542
C H ON
Formula: * ° y u T . 18
" ~^^^^^^^^^™^^™^^^^~^™^**^^^™^^^™^««»"""^^"«"™«i^™^^™^^ tl • X • • M^^—M_«
Solubility: H20(cold);Insolu- 8/100cc H20(hot):Insoluble g/lOOcc
ble (Decomposes)
Density: 1.05 g/cc (3 3000 psig* Vapor pressure: NA @
Flammability hazard: Severe. Easily ignited.
Explosive hazard; Severe. Used as an initiating explosive in ignition
caps. Sensitive to very mild thermal, mechanical or electrical shock.
Volatile hazard: Severe. May emit toxic fumes upon explosive decom-
"position.Nonvolatile at ambient conditions.
Toxicology: Unknown. Assumed to have only mildly toxic effects.
TLV; In air; NA mg/m3
o
Provisional limit; In air: NA mg/m In water; NA mg/1
Special precautions: Treatment at point of origin recommended due to
transport hazard. Explosive.
Comments; *A "fluffy" solid, hence the density determination was made
under pressure. Not acceptable for underground storage without treatment,
Treatment products are essentially nontoxic. Underground storage of prod-
ucts is optional.
311
-------
Name: VX (Persistent Nerve Gas)
C H 0 SNP
Formula: __Ii_£°_±
Solubility: H O(cold): NA g/lOOcc H-O(hot): NA g/lOOcc
Density: 1.1 g/cc @ 25°C Vapor pressure: 12-14 @ 25°C
(Liquid) mg/m3
@ <§
0 (3 @
BP 300 C L L
Flammability hazard: Slight. May evolve flammable H^S when heated to
decomposition.
Explosive hazard: Slight. May evolve explosive ELS when heated to
decomposition.
Volatile hazard; Low volatility, but extreme toxicity makes even low
volatility an extreme toxic hazard at ambient temperatures. Vapor
pressure increases with heating. When heated to decomposition may
evolve toxic fumes including H^S.
Toxicology: Extremely toxic by ingestion, inhalation, and absorption
through skin. A "nerve gas". May be fatal.
3
TLV: In air; 0.0003 mg/m
^Estimated -
Provisional limit: In air: 0.000003 mg/m In water: NA mg/1
Special precautions: Respirator, protective clothing. Avoid heating.
*
Comments; Much information on this compound is classified. Maximum con-
centration by U.S. Army recommendation. Not acceptable for underground
storage without treatment. Treatment products are essentially nontoxic.
Underground storage of products is optional.
312
-------
Name: - Zinc Arsenate _ _ _ ID MJ 453
Zn (AsO )
Formula: - 2 - _ -- __ _ H.I.: _ —
Solubility: H O(cold):Insolu- g/lOOcc H 0(hot):Insoluble g/lOOcc
— ble _£
Density: 3.309 g/cc @ 15°C Vapor pressure: NA @
@ @
@ @
Flammability hazard: Nonflammable.
Explosive hazard: Nonexplosive.
Volatile hazard: Nonvolatile.
Toxicology: Extremely toxic by ingestion and inhalation of dust. May
be fatal.
TLV: In air; 0.5 mg/m
as As
Provisional limit: In air; 0.005 mg/m In water: 0.05 mg/1
as As as As
Special precautions: Respirator.
Comments: Acceptable for underground storage without treatmentCom-
patible with rock salt, gypsum, potash, shale (1), shale (2). Ixmestone,
and granite lithology.
313
-------
Name: Zinc Arsenite ID no. 454
Zn(As02)2
Formula: ________^__________^^____^___________________ H. I.: _
Solubility; H O(cold): Low g/lOOcc H O(hot) : NA g/lOOcc
Density: NA @ Vapor pressure: NA @
Flannnability hazard: Nonflammable.
Explosive hazard: Nonexplosive.
Volatile hazard: Nonvolatile.
Toxicology: Highly toxic by ingestion and inhalation of dust. May be
fatal.
3
TLV; In air; 0.5 mg/m
as As _
Provisional limit; In air: 0.005 mg/m In water: 0.05 mg/1
as As as As
Special precautions: Respirator.
Comments; Acceptable for underground storage without treatment. Com-
patible with rock salt, gypsum, potash, shale (1), shale (2), limestone,
and granite lithology.
314
-------
Name: Zinc Cyanide ID no: _457_
Zn(CN) 16
Formula: H. I.:
Solubility; H20(cold):0.0005 g/lOOcc H O(hot): NA g/lOOcc
Density: 1.852 g/cc @ Vapor pressure: NA @
@ o @
Decomposition temp. 800 C
Flammability hazard; Severe. Evolves flammable hydrogen cyanide in
even weak acid environments. CO- in air is sufficient to evolve hy-
drogen cyanide.
Explosive hazard: Severe. May evolve hydrogen cyanide on decom-
position, resulting in an explosive hazard. See flammability hazard
above.
Volatile hazard; Severe. Evolves hydrogen cyanide gas on contact
with air, moisture, heat, acids, or acid fumes.
Toxicology: Extremely toxic by ingestion and inhalation of dust. Mod-
erately toxic by long term skin contact. May be fatal.
. 3
TLV: In air; 5.0 rag/m
as CN o ,
Provisional limit: In air: 0.05 mg/mJ In water: 0.01 mg/1
as CN as CN
Special precautions; Respirator. Avoid contact with air, moisture,
Tieat, acids, or acid fumes.
, . . u n Not acceptable for underground storage with-
Comments; Weak base in ^2°' ^°ts are essentially nontoxic. Underground
out treatment. Treatment products are essentido- y
storage of products is optional.
315
-------
APPENDIX B-2
HAZARD INDEX OF CANDIDATE WASTES
316
-------
Hazard Index 10-25: Not Acceptable - Must Be Treated (All Substances Containerized)
Hazard Index 6-9: Optional Treatment
Hazard Index 0-5: Containerization Only
Substance
Acrolein
Aldrin
Ammonium Chromate
Ammonium Bichromate
Ammonium Picrate
Antimony Pent a -
fluoride
Antimony Trifluoride
Arsenic Trichloride
Arsenic Trioxide
Benzene Hexachloride
Boron Hydrides
Bromine Penta-
fluoride
Cacodylic Acid
Cadmium (as a solid)
Cadmium, Powdered
Cadmium Chloride
Cadmium Cyanide
Cadmium Fluoride
Cadmium Nitrate
Cadmium Oxide
I.D.
No.
8
13
21
22
27
28
36
43
50
51
55
61
505
66
80
81
82
83
84
478
479
85
Flammab le
0 to 7
7
1
7
7
7
0
0
0
0
1
7
7
1
0
7
0
7
0
5
0
Explosive
0 to 7
7
1
0
0
7
0
0
0
0
1
7
7
1
0
7
0
7
0
5
0
Evolve Gas
in air or
Water
0 to 3
0
0
3
3
0
3
3
3
0
0
3
3
0
0
0
0
3
0
0
0
Evolve Gas
with heat
0 to 3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
0
3
0
2
0
Soluble in
H20
0 to 2
2
1
2
2
2
2
2
2
2
1
2
2
2
0
0
2
2
2
2
0
Toxic
0 to
3
3
3
3
3
2
3
3
3
2
2
3
3
2
1
2
3
2
3
3
2
Hazard
Index
(H.I.)
22
9
18
18
21
11
11
11
7
8
25
25
9
3
18
5
24
5
17
2
-------
CO
M
00
Substance
Cadmium Phosphate
Cadmium Potassium
Cyanide
Cadmium Sulfate
Calcium Arsenate
Calcium Arsenite
Calcium Cyanide
Chlordane
Chlorine
Chlorine Trifluoride
and Pentafluoride
Chromic Acid
Copper Acetoarsenite
Copper Acetylide
Copper Arsenate
Copper Chlorotetrazole 518
Copper Cyanide
Cuprous Cyanide
Cyanides
DDD
DDT
Demeton
Detonators & Primers
Diazodinitrophenol
(DDNP)
2, 4-D
Dieldrin
Dimethyl Sulfate
I.D.
No.
86
480
481
87
88
91
484
105
106
114
490
517
119
518
120
128
129
136
137
491
520
521
135
149
160
Flammable
0 to 7
0
7
0
0
0
7
1
5
7
5
1
7
0
7
7
7
7
1
1
1
7
7
1
1
5
Explosive
0 to 7
0
7
0
0
0
7
1
5
7
5
1
7
0
7
7
7
7
1
1
1
7
7
1
1
5
Evolve Gas
in air or
Water
0 to 3
0
3
0
0
0
3
3
3
3
0
0
0
0
0
3
3
3
0
0
0
0
0
0
0
3
Evolve Gas
with heat
0 to 3
0
3
0
0
1
3
3
3
3
0
3
3
0
3
3
3
3
3
3
3
3
3
3
3
3
Soluble in
H20
0 to 2
0
2
2
1
1
2
1
2
2
2
1
0
0
1
0
0
2
1
1
1
0
1
1
1
1
Toxic
0 to
3
2
2
3
2
2
2
3
3
3
3
3
2
2
2
2
2
2
3
3
3
0
2
2
3
3
Hazard
Index
(H.I.)
2
24
5
3
4
24
12
21
25
15
9
19
2
20
22
22
24
9
9
9
17
20
8
9
20
-------
VO
Substance
Dinitro Cresols
Dinitrotoluene (DNT)
Dipentaerythritol
Hexanitrate
(DPEHN)
Endrin
Fluorine
GB
Gellatinized Nitro-
cellulose
Glycol Dinitrate
Gold Fulminate
Guthion
Heptachlor
Hydrogen Sulfide
Lead Arsenate
Lead Arsenite
Lead Azide
Lead Cyanide
Lead 2, 4 Dinitrore-
sorcinate (LDNR)
Lead Styphnate
Lewisite
Magnesium Arsenite
Manganese Arsenate
Mannitol Hexanitrate
Mercuric Chloride
I.D.
No.
162
165
522
170
200
287
523
525
526
495
496
221
235
236
529
239
530
531
243
245
500
532
253
Flammable
0 to 7
4
7
7
1
6
0
7
7
7
1
1
7
0
0
7
7
7
7
0
0
0
7
0
Explosive
0 to 7
4
7
7
1
2
0
7
7
7
1
1
7
0
0
7
7
7
7
0
0
0
7
0
Evolve Gas
in air or
Water
0 to 3
0
0
0
0
3
2 -
0
1
0
0
0
3
0
0
0
3
0
0
3
0
0
0
1
Evolve Gas
with heat
0 to 3
1
3
3
3
3
3
3
3
3
3
3
3
1
1
3
3
3
3
3
0
0
3
3
Soluble in
H20
0 to 2
1
1
1
1
2
2
0
2
0
1
1
2
1
0
2
1
0
0
2
1
1
0
2
Toxic
0 to
3
3
3
2
3
3
3
1
3
3
3
3
2
2
2
2
2
2
3
3
3
2
1
3
Hazard
Index
(E.I.)
13
21
20
9
19
10
18
23
20
9
9
24
4
3
21
23
19
20
11
4
3
18
10
-------
Substance
Mercuric Cyanide
Mercuric Diammonium
Chloride
Mercuric Fulminate
Mercuric Nitrate
Mercuric Sulfate
Mercury
Organic Mercury
Cmpds.
Methyl Parathion
Nickel Carbonyl
Nickel Cyanide
Nitrocellulose
Nitrogen Mustard
Nitro glycerin
Parathion
Pentaborane
Pen tachlo ropheno 1
Pentaerythritol
Tetranitrate (PETN)
Perchloric Acid
(72% strength)
Perchloryl Fluoride
Picric Acid
Potassium Arsenite
Potassium Chroma te
Potassium Cyanide
I.D.
No.
254
503
533
255
256
257
258
274
293
295
534
306
307
321
505
322
319
324
326
338
341
343
344
Flammable
0 to 7
7
0
7
3
0
0
7
7
7
7
7
1
7
7
7
0
7
7
5
7
0
5
7
Explosive
0 to 7
7
0
7
3
0
0
1
7
7
7
7
1
7
7
7
0
7
7
5
7
0
0
7
Evolve Gas
in air or
Water
0 to 3
3
3
2
2
2
2
1
0
3
3
0
3
0
0
3
0
0
3
3
0
0
0
3
Evolve Gas
with heat
0 to 3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
0
0
3
Soluble in
H20
0 to 2
2
1
0
2
2
2
1
2
1
0
0
1
1
2
2
1
0
2
1
1
2
2
2
Toxic
0 to
3
3
3
2
3
3
3
3
3
3
2
1
3
3
3
3
3
3
2
1
3
3
3
2
Hazard
Index
(H.I.)
25
10
21
16
10
10
16
22
24
22
18
12
21
22
25
7
20
24
18
21
5
10
24
-------
u>
NJ
benzfuroxan (KDNBF)
Silver Acetylide
Silver Azide
Silver Cyanide
Silver Styphnate
Silver Tetrazene
Smokeless Gunpowder
Sodium Arsenate
Sodium Arsenite
Sodium Cacodylate
Sodium Chromate
Sodium Cyanide
Sodium Bichromate
Sulphur Mustard
TNT
Tear Gas (CN)
Tear Gas (CS)
Tetrazene
VX
Zinc Arsenate
Zinc Arsenite
Zinc Cyanide
I.D.
No.
345
536
537
538
370
539
540
541
376
377
382
386
387
379
543
418
107
422
423
542
288
453
454
457
Flammable
0 to 7
5
7
7
7
7
7
7
7
0
0
1
5
7
5
7
7
1
1
7
1
0
0
7
Explosive
0 to 7
0
7
7
7
7
7
7
7
0
0
1
0
7
0
7
7
1
0
7
1
0
0
7
Evolve Gas
in air or
Water
0 to 3
0
0
0
0
3
0
0
0
0
0
0
0
3
0
3
0
3
3
0
3
0
0
3
Evolve Gas
with heat
0 to 3
0
3
3
3
3
3
3
3
0
0
3
0
3
0
3
3
3
3
3
3
0
0
3
Soluble in
H20
0 to 2
2
1
0
0
0
2
2
2
2
2
2
2
2
2
1
0
2
2
0
2
0
1
1
Toxic
0 to
3
3
2
3
3
2
2
2
2
3
3
2
3
2
3
3
2
2
2
1
3
2
2
2
Hazard
Index
(H.I.)
10
20
20
20
22
21
21
14
5
5
9
10
24
10
24
19
12
11
18
13
2
3
23
-------
APPENDIX B-3
WASTE TREATMENT PROCEDURES
322
-------
KEY TO APPENDIX B-3
LO
to
LO
TREATMENT PRODUCTS
LEGEND
*E = EVIRONMENTAL RISK
•il.I. = HAZARD INDEX
•T.L. = TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
-------
Pages 325 through 357 of Appendix B-3, Waste Treatment Procedures, refer
to Table 7, CANDIDATE WASTES WHICH ARE ACCEPTABLE FOR UNDERGROUND STOR-
AGE IN CONTAINERS WITH NO TREATMENT. (Candidates listed in alphabetical
order by name.)
Note: Wherever possible both the mandatory and optional treatment proce-
dures have been shown. The optional treatment procedures may be
most significant in treating a variety of unknown original waste
forms, and might also be useful for optimizing the use of under-
ground space through improved handling and storage.
324
-------
TREATMENT PRODUCTS
*E » ENVIRONMENTAL RISK
*H.I. " HAZARD. INDEX
*T.L. - TREATMENT LEVEL
T.L. " 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Co
NJ
Ui
NAME
C,2H8C16
TREATMENT
Dilute: Concentrate
w/activated carbon & regen-
erate carbon in furnace.
Treat products same as below.
Cone: Incineration w/after-
burner & scrub w/dilute
caustic soln (NaOH assumed)
r"
*
i
TOXIC
NAME
FORM
-n
r~
^
r-
m
m
X
TJ
O
CO
m
m
o
i—
<
to
§
NONTOXIC
NAME
Ash (Possible)
NaCl + Na2CO,
+ NaOH + H20
FORM
Powder
Dilute
Soln
*E
p
1-
m
m
x
o
m
m
o
r-
m
C/»
£
-------
TREATMENT PRODUCTS
U>
fo
ON
NAME
As2°3
H3As04 + HN03 +
N203 + H20
N203
Slurry
Mg3(As04)2
TREATMENT
Treat w/hot HN03 + H20
Treat w/Mg(OH)2 + H20
Scrub w/dilute
Caustic Soln
(NaOH assumed)
Filter & Mash
vaporate (Optional )
.
j~
»
1
2
3
4
TOXIC
NAME
H3As04 + HN03 +
N203 + H20
N203
Mg3(As04)2 +
Mg(N02)2 + Mg(N03)2
+ Mg(OH)2 + H20
Mg3(As04)2 +
Mg(OH)2 + H20
Mg3(As04)2
+ Mg(OH)2
FORM
Soln
Gas
SI urry
Damp Solid
Insol
Solid
^D
J&
I
r-
m
rrl
X
i
s
m
r*
m
§
X
X
NONTOXIC
NAME
NaN02 + NaOH
+ H20
Mg(N02)2 +
Mg(N03)2 +
Mg(OH)2 + H20
H20
FORM
Dilute
Soln
*E
Dilute
Soln
*E
Vapor
P
z
S
r—
m
m
X
i—
g
m
m
g
p-
&
to
s
X
-------
TREATMENT PRODUCTS
*E " ENVIRONMENTAL RISK
*H.I. " HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. • 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U>
NJ
NAME
We
TREATMENT
Dilute: concentrate w/acti-
vated carbon beds w/ regenera-
tion of carbon In furnace.
Treat products same as below.
Cone: Incineration w/after-
burner & dilute caustic
scrubber (NaOH assumed)
— i
r—
»
1
TOXIC
NAME
FORM
p
|
r~
m
X
8
t— t
m
§
to
%
NONTOXIC
NAME
NaCl + Na2C03
NaOH + H20
Ash (possible)
FORM
Dilute
Soln
*E
Powder
z
i
r-
m
X
m
m
§
V,
%
-------
TREATMENT PRODUCTS
OJ
N3
00
NAME
(CH3)2As02H
As203
Gas + Soln
Slurry
Mg3(As04)2 4 H20
TREATMENT
Incineration w/afterburner
& condense 9 110°C
Treat w/hot HN03
Treat w/excess Mg(OH)2
Filter & wash
Evaporate (Optional)
;H
r"
'*
1
2
3
4
5
TOXIC
NAME
As203
H3As04 4 N203 4
HN03 + H20
N2°3
Mg3(As04)2 4
Mg{N02)2 4- Mg(N03)2
+ Mg(OH)2 4 H20
Mg3(As04)2 +
Mg(OH)2 4 H20
Hg3(As04)2 +
Mg(OH)2
FORM
Solid
Soln
Gas
Slurry
Damp Solid
Solid
;jj
1
m
m
i
s
m
§
s
t/>
^
X
X
NONTOXIC
NAME
C02 + H20
Mg(N02)2 4 Mg(N03),
4 Mg(OH)2 4 H20
H20
FORM
Gases
Dilute
Soln
*E
Vapor
£
r—
m
m
i
m
m
°
%
§
X
X
t-t O »-i
-------
10
NAME
TREATMENT
No Treatment Necessary
*T.L. - TREATME
T.L. - 0 - C<»
ALL an
TREATMENT PRODUCTS CONTAIf
—i
i—
TOXIC
NAME
FORM
p
i—
m
m
X
o
m
m
o
i—
i
NONTOXIC
NAME
FORM
-Tl
1—
m
m
X
•o
o
m
m
I
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
- TREA
CONTAINERIZED ONLY.
•-H O l-H
m T3 »_»
O O O
o
Q.'
on
o
•jo
o o o r-
o
ac
o
-------
u>
u»
o
TREATMENT PRODUCTS
*E « ENyiROKMEWTAL PIS*
*H.I. • HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. • 0 - CONTAINERIZED ONLr.
AU OTHER LEVELS INCLUDE
CONTAINERS.
NAME
CdCl2
Cd(OH)2 + C«C12 +
Ca(OH)2 + H20
CdO + CaC12 *
Ca(OH)2 + H20
CdO * H?0
TREATMENT
Treat v/Ca(OH)2 * Hfl
Incinerate * scrub w/ water
Filter & wash
Evaporate (Optional)
-4
1
2
3
4
TOXIC
NAME
Cd(OH)2 * CaCl2 +
Ca(OH)2 H2C
CdO * CaCl2 «•
Ca(OH)2 + H20
CdO * H^
CdO
FORM
Slurry
Slurry
Damp
solid
Solid
t
t
r-
t*i
X
ft
8
H
90
90
2
ri
•"
S
I*C
X
IT
X
NOKTO/IC
NAME
C«C12 + Ca(OH)2
+ H?0
FORM
Dilute
Soln
*£
/apor
p
§
m
m
X
^F
&
m
m
r^
?;
R
i
-------
TREATMENT PRODUCTS
*E « ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
•T.L. • TREATMENT LEVEL
T.L. " 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
UJ
NAME
CdF2
Slurry
TREATMENT
Treat w/excess Ca(OH)2
Evaporate 9 320°C (Optional)
-H
J
*
1
2
TOXIC
NAME
Cd(OH)2 + CaF2 +
Ca(OH)2 + H20
CdO + CaF2 +
Ca(OH)2
FORM
Slurry
Solid
y>
^
r—
m
m
V
g
r*!
9C
o
^i
<^
&
T
/
NONTOXIC
NAME
H20
FORM
Vapor
,,
^
£
r-
m
m
X
f—
8
m
m
£
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. • 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
TREATMENT
No Treatment Necessary
r~
TOXIC
NAME
FORM
?
r~
m
EXPLOS
<
m
m
g
s
CO
s
NONTOXIC
NAME
FORM
g
r~
m
m
X
-o
r~
o
CO
s
m
s
s
CO
S
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
U)
Co
GJ
TREATMENT
No Treatment Necessary
TOXIC
NAME
FORM
NONTOXIC
NAME
FORM
-------
TREATMENT PRODUCTS
10
NAME
CdS04
Slurry
TREATMENT
Treat w/Ca(OH)2
Evaporate @ 320°C (Optional)
—i
*
1
2
TOXIC
NAME
Cd(OH)2 + Ca(OH)2
+ CaS04 + H20
CdO + Ca{OH)2 +
CdSO.
4
FORM
Slurry
Solid
£
f
r-
m
X
8
m
90(
m
§
%
X
°r
NONTOXIC
NAME
H20
FORM
Vapor
5
£
r~
m
m
X
i—
K
s
m
r*
in
%
X
•O CJI CJ1 , t
-------
OJ
u>
Cn
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. • 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Ca3(As04)2
Slurry
Mg3(As04)2 +
Mg(OH)2 + H20
TREATMENT
Treat w/Mg(OH)2
Filter & wash
Evaporate (Optional)
r1
*
1
2
3
TOXIC
NAME
M93(As04)2 t
Ca(OH)2 + Mg(OH)2
+ H20
Mg3(As04)2 *
Mg(OH)2 + H20
Mg3(As04)2
+ Hg(OH)2
FORM
Slurry
Damp
Solid
Solid
p
>
5
•n
rri
X
O
s
m
2
ri
(/I
£
NONTOXIC
NAME
Ca(OH)2 +
Mg(OH)2 + H20
H2°
FORM
Dilute
Soln
*E
Vapor
3
i—
m
m
X
P=
O
ft
m
m
P
n^
in
8
X
-------
ENVIRONMENTAL RISK
TREATMENT PRODUCTS
to
U>
NAME
CaAsOjH
Slurry
N2°3
Slurry
Damp solid
TREATMENT
Oxidize with hot HN03
Treat with Mg(OH)2
Dilute alkaline scrubber
(NaOH assumed)
Filter & wash
Evaporate (Optional)
— <
f-
*
1
2
2
3
4
TOXIC
NAME
Ca3(As04)2 + N203
+ HN03 + H3As04 +
N2°3
Mg(N02)2 + Mg(N03)2
Mg(OH)2 + H20
Mg3(Aso4)2 +
Mg(OH)2 + H20
Mg3(As04)2 +
Mg(OH)2
FORM
Slurry
Gas
Slurry
Damp solid
Solid
g
3
r*
m
m
X
s
m
m
§
*/>
^
X
X
NONTOXIC
NAME
NaOH + NaN02 -
H-0
Mg(N02)2 +
Mg(N03)2 +
Mg(OH)2 + H20
H20
FORM
Dilute
soln
*E
Dilute
soln
*E
Vapor
5
£
m
m
X
-o
I—
o
m
m
§
s
S
X
*-• o <-»
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U>
CO
NAME
C2H302)2Cu.3Cu(As02)2
Cu(N03)2 + H.jAs04
+ IIH03 + H20
"' :12°3 ' C02
Slurry
Cu(OH)2 + CuO +
Mq(OH), + Mg,(AsO, ),
c j Q 2.
TREATMENT
Incineration w/afterburner
& scrub w/HN03 (hot)
Treat w/Mg(OH)2
Fil ter & wash
Evaporate w/heat (Optional)
— i
"^
1
2
3
4
TOXIC
NAME
N2°3 * C02
Cu(N03)2 + HM03 +
N203 + C02 +
H3As04 + H20
Cu(OH)2 + CuO +
Mg3(As04) +
Mg(N03)2 + Mg(N02)2
+ MgC03 + Mg(OH)2
Cu(OH)2 + CuO +
Mg3(As04)2 +
Mg(OH)2 + H20
CuO + Mq(OH)2 -r
Mg3(As04)2
FORM
Gas
Soln
Slurry
Damp
Solid
Sol id
-n
r~
-n
m
X
-a
i~
o
m
m
<
rn
n
X
X
NONTOXIC
NAME
Mg(no3)2 +
Mg(N02)2 + MgC03+
Mg(OH)2 + H20
H20
FORM
Dilute
Soln
*E
Vapor
£
^
5
i-
m
m
X
O
to
m
m
r~
is\
%
X
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. « TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Co
W
03
NAME
TREATMENT
No Treatment Necessary
i-
TOXIC
NAME
FORM
|
m
m
?
o
m
m
§
8
NONTOXIC
NAME
FORM
5
m
m
X
r*
o
m
g
i
S
o
m
3
S
o
c
0
f
0
o
ro
R
m
o
$
U)
0
T:
o
o
ro
*— i
z
r-
3
1
O
ro
3
B»
O
3O
—I
i
-H
f-
F
|
Jr
o
c
u>
o
ro
a
z
*
S1
s
T
T
VI
Q»
ro
b
5
VO
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 » CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U>
NAME
C8H6C1203
TREATMENT
Dilute: concentrate w/acti-
vated carbon beds w/carbon
regeneration in furnace. Treat
products same as below.
Cone: incineration w/after-
burner & scrubbing w/dilute
alkaline soln (MaOH assumed)
-t
*
1
TOXIC
NAME
FORM
£
•jC
CD
m
X
•o
0
y>
•n
m
§
fi
%
NONTOXIC
NAME
NaCl + Na2CO, +
MaOH + H20
Ash (possible)
FORM
Dilute
soln
*E
^owder
-n
X
m
m
X
-o
m
m
O
i—
(/>
%
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. " HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U>
4^
O
NAME
(C1C H ) C H Cl
TREATMENT
Dilute: Concentration with
activated carbon w/ regener-
ation of carbon 1n furnace.
Treat products same as be-
low.
Cone: Incineration w/after-
burner & scrubbing w/dilute
alkaline solution (NaOH
assumed)
i-
*
1
TOXIC
NAME
FORM
?
|
r-
m
m
X
o
s
m
K
£
NONTOXIC
NAME
NaCl + Na2C03 +
NaOH + H20
Ash (possible)
FORM
Dilute
soln
*E
Powder
£
ji
t-
m
X
•o
g
m
m
q
^
-------
Tf'iATMFNT PRODUCTS
*E = ENVIRONMENTAL RISK
••'.I. - HAZARD INDEX
•T.L. = TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
\ '.Mi.
(CK6,,4)2C2HC13
!'!,. . .'•': '17
Jilute: concentrate w/acti-
vated carbon w/regeneration
of carbon in furnace. Treat
jroducts same as below.
Cone: incineration w/after-
burner & scrubbing w/dilute
alkaline soln (NaOH assumed)
»
1
i')/ir
vi«.
FORM
TJ
1»
^
S
m
X
O
£
m
o
i —
<
t/>
(/>
NONTOXIC
NAME
NaCl + Na2C03 +
NaOH 4- H«0
Ash (possible)
FORM
Dilute
soln
*E
Powder
-n
r-
£
g
m
m
X
0
l/>
m
m
O
r—
m
(.0
^
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Ni
NAME
CH OPS
TREATMENT
Dil: concentration w/activa-
ted carbon beds w/carbon re-
generation in furnace. Treat
products same as below.
Cone: incineration w/after-
burner & scrubbing w/dilute
alkaline soln (NaOH assumed)
—i
r-
*
1
TOXIC
NAME
FORM
>
^
m
m
X
-o
i
m
r-
§
NONTOXIC
NAME
Na CO +
34 23
+ NaOH + H20
Ash (possible)
FORM
Dilute
soln
*E
Powder
5
<£
r~
m
m
i—
o
i/i
m
m
§
s
in
%
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*>!.!. * HAZARD INDEX
*T.L. = TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Co
.>
U)
NAME
C H OC1
P-'JMENT
Jilute: concentrate w/activa-
ted carbon beds w/carbon re-
generation in furnace. Treat
iroducts same as below.
Cone: incineration w/after-
burner 8 scrubbing w/dilute
caustic soln (NaOH assumed)
— i
*
1
TOXIC
MAM;:
FORM
?
|
m
m
X
0
m
m
P
m
CO
§
NONTOXIC
NAME
NaCl + Na.CO,
+ NaOH + H20
Ash (possible)
FORM
Dilute
soln
*E
Powder
-n
r~
|
I —
m
m
x
'a.
m
m
o
Lo
%
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. » TREATMENT LEVEL
T.L. • 0 « CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C H Cl 0
TREATMENT
Dilute: concentrate w/activa-
ted carbon beds w/regeneration
of carbon in furnace. Treat
products same as below.
Cone: incineration w/after-
burner & scrub w/dilute
caustic soln (NaOH assumed)
i—
*
1
TOXIC
NAME
FORM
P
^
r—
m
m
X
O
LO
m
m
O
r—
£
NONTOXIC
NAME
NaCl + Na2C03
+ NaOH + H20
Ash (possible)
FORM
Dilute
soln
*E
Powder
>
1
m
X
T)
3
m
m
O
00
%
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. = HAZARD INDEX
•T.L. = TREATMENT LEVEL
T.L. = 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Co
-P-
Ui
•(AMC
C10H12N303PS2
:•;;.,! "HI
Hlute: cone w/activated car-
ion beds w/carbon regenerated
in furnace. Treat products
same as below.
Cone: incineration w/after-
>urner & scrubbing w/dilute
caustic soln (NaOH assumed)
— i
i —
*
1
TOXIC
N«Mf.
FORM
-n
J*
^
OT
| —
m
n
X
T)
O
m
m
§
on
t/1
NONTOXIC
NAME
+ Na2S03 + NaNOx
t NaOH + H?0
Ash (possible)
^JRM
Dilute
soln
*E
Powder
-n
i —
>
£
i~
m
m
X
•o
g
n
m
0
r—
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. " 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
CO
NAME
C10H5C17
TREATMENT
Dilute: concentrate w/activa-
ted carbon w/carbon regenera-
ted in a furnace. Treat pro-
ducts same as below.
Cone: incineration w/after-
burner & scrubbing w/dilute
caustic soln (NaOH assumed)
r-
*
1
TOXIC
NAME
FORM
£
^
m
m
X
TS
m
m
o
i—
<"
8
NONTOXIC
NAME
Nad + Na2C03
+ NaOH + H20
Ash (possible)
FORM
Dilute
soln
*E
Powder
5
5
m
m
X
-o
r~
0
&
m
R
3
£
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
Ml. I. = HAZARD INDEX
•T.L. = TREATMENT LEVEL
T.L. = 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
OJ
NAME
TREATMENT
No Treatment Necessary
r4
if
TOXIC
NAME
FORM
•3
I
r—
m
m
X
-o
o
l/l
<
m
n
O
r-
rn
6
I/}
NONTOXIC
NAME
FORM
5
1
CD
I—
m
m
X
13
O
rn
m
O
I—
t/i
B
\/i
O
m
r-
s
JO
•c
o
3
VI
c
0
-
o
0
m
-o
-H
-n
o
JO
3:
X
Irt
o
o
-
z
1—
3
50
O
-
-n
0
p-
o*
o
-1
o
-I
r-
*
X
*
S
i
>
-o
cr
o
z
m
D
a.
•j-,
1
D
3
T>
O
ac
0
jj
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. - 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
00
NAME
TREATMENT
No Treatment Necessary
—i
i—
'»
TOXIC
NAME
FORM
FLAMMABLE
EXPLOSIVE
m
§
<
m
to
$
NONTOXIC
NAME .
FORM
FLAMMABLE
EXPLOSIVE
m
g
fi
%
-------
TREATMENT PRODUCTS
'•E = ENVIRONMENTAL RISK
M.I. = HAZARD INDEX
*T L. = TREATMENT LEVEL
T.L. =• 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U>
4>-
vo
NAME
Mg3(As03)2
SI urry
no
Mg3(As04)2 +
H20(Damp sol id)
TREATMENT
Treat w/hot IIN03
Filter & wash & neutralize
filtrate
Scrub w/dilute
caustic soln
(NaOH) assumed
Evaporate (Optional)
r—
»
1
2
2
3
TOXIC
NAME
Mg3(As04)2
+ N2°3
N,0,
2 3
Mq (AsO ) + H 0
Mg3(As04)2
FORM
Slurry
Gas
Damp sol id
Solid
r—
|
r—
m
X
•o
0
n
m
O
r~
u-.
#
X
X
NONTOXIC
NAME
NaNO + NaNO
+ Main + H-0
NaNO- + flaOH
+ H20
H20
FORM
Dilute
soln
*E
Dilute
soln
*E
Vapor
s>
x»
i —
m
m
X
O
tn
m
m
O
r~
<"
%
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
CO
Ul
o
NAME
TREATMENT
No Treatment Necessary
— <
r-
^
TOXIC
NAME
FORM
g
*f
r~
m
rn
X
o
CO
m
m
o
i—
to
g
NONTOXIC
NAME
FORM
g
JZ
1—
m
m
X
O
s
m
O
s
tn
§
o
m
•n
o
70
%
3
o
o
CJ
o
m
•o
-H
-n
o
1
?
-p.
o
o
OJ
t— «
r*
-n
0
0
OJ
S
x»
s
Ul
o
•-«
-)
s
—1
1—
F
S
jg
E
f
^
O
z
?
1
0
D*
3
O>
0)
3
Pt
O
O
Ul
-------
TREATMENT PRODUCTS
»E = ENVIRONMENTAL RISK
•M.I. = MAZARD INDEX
•T.L. = TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C15C6OH
TREATMENT
)ilute: concentrate w/activa-
ted carbon beds w/regeneration
of carbon in furnace. Treat
iroducts same as below.
Cone: incineration w/after-
burner & scrub w/dilute
caustic soln (NaOH assumed)
— i
*
1
TOXIC
NAME
FORM
-n
i —
^
no
m
m
X
o
1/1
m
m
-c
[/>
&>
NONTOXIC
NAME
NaCl +Na2C03
+ NaOH + H20
FORM
Dilute
soln
*E
5
jj
m
m
X
-o
m
m
O
r"
i/>
V)
-------
TREATMENT PRODUCTS
*t • ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. » TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
CO
Ln
N>
NAME
KAs02
Soln + gas
Slurry
Damp sol id
TREATMENT
Treat w/hot HN03
Treat w/Mg(OH)2
Filter & wash
Evaporate (Optional)
— i
r-
V
1
2
3
4
TOXIC
NAME
K3As04 + N203 +
HN03 + H20
N,0,
2 3
Mg3(As04)2 +
Mg(N02)2 +
Mg(N03)2 +
Mg(OH)2 + KOH +
KN03 + KN02 + H20
Mg3(As04)2 +
Mg(OH)2 + H20
Mg3(As04)2
Mg(OH)2
FORM
Soln
Gas
SI urry
Damp solid
Solid
?
I
K
m
0
s
m
o
r~
c?
§
X
X
NONTOXIC
NAME
Mg(N02)2 +
Mg(N03)2 +
Mg(OH)2 + KOH +
KN03 + KN02 +
H20
FORM
Dilute
soln
*E
Vapor
5
i
i—
m
m
X
•o
i
m
m
o
K
i
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
M.I. = HAZARD INDEX
*T.L. = TREATMENT LEVEL
r.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U)
Ui
U>
NAML
Na2HAs04
Slurry
Mg3(Aso4)2 + H2o
TREATMENT
Treat w/Hg(OH)2
Fil ter ft wash
Evaporate (Optional)
•H
*
1
2
3
TOXIC
NAME
Mg3(As04)2
+ Mg(OH)2
+ NaOH + H20
Ng3(As04)2 +
Mg(OH)2 + H20
Hg3(As04)2 +
Mg(OH)2
FORM
Slurry
Damp solid
Solid
-n
i—
r~
m
X
•o
o
LTt
m
m
o
r-
K
£
NONTOXIC
NAME
NaOH + Mq(OH)2
H20
FJRM
Dilute
soln
*E
Vapor
£
r-
m
m
X
-o
o
m
m
O
I—
t/i
%
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. » HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. - 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Oi
NAME
Na,As03
Soln + Gas
Slurry
Hg3(As04)2 +
Mg(OH)2 + H20
TREATMENT
Treat w/hot HN03
Treat w/Mg(OH)2
Filter & wash
Evaporate (Optional)
—i
*
1
2
3
4
TOXIC
NAME
Na3As04 + N203
+ HN03 + H20
N2°3
Mg3(As04)2 +
Mg(N02)2 + Mg(N03)2
Mg(OH)2 + NaOH
+ NaN03 + NaN02
Mg3{As04)2 +
Mg(OH)2 + H20
Mg3(As04)2 +
Mg(OH)2
FORM
Soln
Gas
Slurry
Damp solid
Solid
£
5
r~
m
X
|2
o
m
m
°
s
in
§
X
X
NONTOXIC
NAME
Mg(N02)2 +
Mg(N03)2 + Mg(OH^
+ NaOH + NaN03
+ NaN02 + H20
H20
FORM
Dilute
soln
*E
Vapor
p
2
r
i—
m
m
X
|H
b>
3
m
°
s
(/>
%
X
-------
CO
Ul
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. * HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C H 0 AsNa
Na.,0 (from precipita-
tor)
As203 (from condenser
HjAs04 + HN03 + N203
+ H20
N 0
SI urry
Damp solid
TREATMENT
ncineration at 1000° c w/
fterburner & precipitator,
ondense 0 120°c
ilute w/H,0
c
reat w/hot HN03
Treat w/Mg(OH)2 + H20
Scrub w/dilute caustic soln
NaOH assumed)
Filter & wash
Evaporate (Optional)
— t
1
2
2
3
3
4
5
TOXIC
NAME
Na20
As203
H3As04 + HN03
N2°3 3
Mg3(As04)2 +
Mg(N02)2 + Mg(N03)2
+ Mg(OH)2 + H20
Mg3(As04)2+ Mg(OH)2
+ H20
Mg3(As04)2 +
Hg(OH)2
FORM
Crystals
'owder
Soln
Gas
Slurry
Damp sol id
Solid
£
£
5
•n
«
yi
Tl
m
e
s*
X
X
X
NONTOXIC
NAME
CO + H 0
NaOH + H,0
L.
NaNO. + NaOH
2
Mg(N02)2 +
Mq(N03)2 + Mg(OH),
H20
FORM
Gas
Soln
(recycle)
Dilute
soln
*E
Dilute
soln
*E
Vapor
P
s
m
m
X
•o
r~
o
i/>
m
m
o
r—
s
e
X
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. « HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. " 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Ln
ON
NAME
TREATMENT
No Treatment Necessary
— i
r—
*
TOXIC
NAME
FORM
g
1
1—
m
m
X
-o
P"
8
S
m
s
tn
s
NONTOXIC
NAME
FORM
5
g
i—
m
m
X
-o
1—
g
s
m
3
S
§
O
pn
3
TO
:x
&
CO
f*
vt
O
*»
ro
CD
ro
o
0
m
TJ
3
I
3
CO
J/T
o
fa.
Ni
O
ro
z
5
3
1
o
ro
-n
0
e>
o
m
VI
70
•o
t-H
—1
r~
f1
3
g
?
13
CO
^
O
ro
?
f?
?
t
/t
D
3
1»
D
3
f*
Jl
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
M.I . = HAZARD INDEX
•T.L. = TREATMENT LEVEL
T.L. = 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Ln
NAME
Zn(As02)2
Slurry
N2°3
Slurry
Damp solid
TREATMENT
Treat w/hot HN03 + H20
Treat w/Hq(OH)2
Dilute caustic scrubber (NaOH
assumed)
Filter & wash
Evaporate (Optional)
r1
*
i
2
2
3
4
TOXIC
NAME
Zn3(As04)2 + N203
+ UNO, + H,AsO. +
334
N2°3
Zn3(As04)2 +
Mg(N02)2 + Mg{N03)2
+ Hg3(As04)2
+ Mg(OH)2 + H20
Zn3(As04)2 +
Mg3(As04)2 +
Mg(OH)2 + H20
Zn3(As04)2 +
Mg(OH)2
FORM
Slurry
Gas
Slurry
Damp solid
Solid
~n
^
g
i —
m
m
X
-a
o
n
m
o
r-
R
§
X
X
NONTOXIC
NAME
NaNO- + NaOH
2
Mg(N02)2 +
Mg(N03)2 + Mg(OH),
+ H20
H20
FORM
Dilute
soln
*E
Dilute
soln
+ F
Vapor
r—
P-8*
m
m
X
"O
r-
o
m
m
§
m
t/t
e
X
-------
Pages 359 through 404 of Appendix B-3, Waste Treatment Procedures, refer
to Table 8, CANDIDATE WASTES WHICH ARE ACCEPTABLE FOR UNDERGROUND STOR-
AGE IN CONTAINERS AFTER TREATMENT. (Candidates listed in alphabetical
order by name.)
358
-------
u>
Ui
SO
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. » HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 « CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
(NH4)2Cr04
Slurry
Soln + precipitate
Cr(OH)3 + H20
TREATMENT
Reduction w/S02
Precipitation by adjusting
PH > 9.5 (NaOH assumed)
Filter
Evaporate w/heat (Optional)
— i
*
1
2
3
4
TOXIC
NAME
(NH4)2S03 +
Cr2(S04)3 + S02 +
H20
Cr(OH)3
(NH4)2S03 + NH4OH +
Na2S04 + (NH4)2S04
+ NaOH + Na.SO, ^
Cr(OH)3 + H20
FORM
Slurry
Precipi-
tate
Soln
Sludge
Crystals
g
^
K
m
x
•o
L/)
m
m
R
tn
P
Si
X
X
NONTOXIC
NAME
(NH4)2S03 + NH4OM
+ Fla2S04 +
(NH4)2S04 + NaOH +
Na0SO, + H00
23 2
FORM
Dilute
soln
*E
Vapor
-n
i —
I
I"
m
m
x.
TJ
O
m
m
o
r"
u>
%
X
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
(NH4)2Cr20?
Slurry
Soln + precipitate
Cr(OH)3 + H20
TREATMENT
Reduction w/S02
Precipitation by adjusting
PH > 9.5 (NaOH assumed)
Filter & wash
Evaporate w/heat (Optional)
—i
r-
'»
1
2
3
4
TOXIC
NAME
(NH4)2S03 +
Cr2(S04)3 + S02 +
H20
Cr(OH)
•3
(NH4)2S03 +
NH4OH + Na2S04 +
(NH4)2S04 + NaOH +
Na2S03 + H20
Cr(OH), + H,0
•3 £
Cr203
FORM
Slurry
Precipi-
tate
Soln
Sludge
Crystals
P
1
i—
rri
m
X
-D
r~
O
w
rn
m
g
m
CO
^
X
X
NONTOXIC
NAME
(NH4)2S03 *
"4^ 2 4
(NH4)2S04 + NaOH
+ Na,SO- + H,0
23 2
FORM
Dilute
soln
*E
Vapor
5
I
i—
m
m
X
-o
i
m
m
£
€/>
§
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. " 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
NH4C6H2N30?
Hg + H20
TREATMENT
Controlled Incineration w/
afterburner & precipitator
& condense (20°C)
Scrub gases w/d1lute caustic
soln (NaOH assumed)
Purify & recycle
—t
r—
*
1
2
TOXIC
NAME
PbO + metal oxides
Hg + H20
FORM
Solid
Liquid
P
|
m
rn
X
R
m
?
m
§
X
NONTOXIC
NAME
NaNO + Ma CO t
NaOH t H.O
FORM
Dilute
soln
*E
-n
^
r"
m
m
X
R
m
m
§
to
8
-------
ON
Ni
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. " 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
SbF5
Slurry
Soln
Sb2Sx + H20
H2S + H20 & S02 + C02
+ H20
HC1 + HF + H20
Sb
CaF2 + CaCl2
Ca(OH)2 + H20
TREATMENT
Dissolve in dilute HCI &
saturate w/H2S
Filter & wash
Air strip H2S
Roast w/carbon
\
Incinerate & scrub w/dilute
caustic (NaOH assumed)
Treat w/1 ime (Ca(OH2))
Recycle or store
Evaporate (Optional )
£
V
1
2
3
3
4
4
4
5
TOXIC
NAME
Sb2Sx + HCI + HF +
H2S + H20
Sb,S + H,0
c x t.
HCI + HF + H2S +
H20
H2S + H20
HCI + HF + H20
Sb
SO, + CO, + H,0
222
CaF2 + CaCl2 + H^O
+ Ca(OH)2
Sb
CaF2 + CaCl2 +
Ca(OH)2
FORM
SI urry
Precipi-
tate
Soln
Gas
Soln
Solid
Gas
Slurry
Solid
Solid
g
I
i—
m
X
X
X
X
X
1
m
X
i
•— i
X
X
X
X
X
38
rn
§
m
C/)
§
X
X
X
X
X
X
X
I°C
NONTOXIC
NAME
Na SO + Na CO
NaOH + H20
H2n
FORM
Dilute
soln
*E
Vapor
e
1
m
m
X
-o
i
m
m
\
in
§
-------
LO
CT>
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
SbF3
Slurry
Soln
Sb2Sx + H20
H2S + H20 &
S02 + C02 + H20
HC1 + HF + H20
Sb
CaF2 + CaCl2 +
Ca(OH)2 + H?0
TREATMENT
Dissolve in dilute HC1 &
saturate w/H2S
Filter & wash
Air strip of H?S
Roast w/carbon
Incinerate & scrub w/dilute
caustic (NaOH assumed)
Treat w/lime (Ca(OH)2)
Recycle or store
Evaporate (Optional)
— t
*
1
2
3
3
4
4
4
5
TOXIC
NAME
Sb2Sx * HC1 + HF +
H2S + H20
Sb2Sx + H20
HC1 + HF * H2S +
H2S + H20
IIC1 + HF + H20
Sb
SO, + CO, + H,0
2 Z Z
La r A T caLin °"° H*iU
i Z c
*• Ca(OH)2
Sb
CaF2 + CaCl2 +
Ca(OH)2
FORM
Slurry
Precipi-
tate
Soln
Gas
Soln
Solid
Gas
Slurry
Solid
Solid
-n
t>
|
Tl
X
X
X
X
X
1
m
X
2
Z
•n
X
X
X
X
X
,38
m
§
Tl
CO
g
X
X
X
X
X
X
X
)"(
NONTOXIC
NAME
Na SO + Na CO
NaOH + H20
H20
FORM
Dilute
soln
*E
Vapor
§
p
r—
m
m
X
r*
g
m
m
§
s
in
e
X
-------
TREATMENT PRODUCTS
NAME
AsCl3
Ca~(AsO-)0 + CaCl« +
O J C. €.
Ca(OH)2 + H20
Al ternate
AsC1l
H3As04 + HC1 + HN03
+ N?03 + H20
HC1 + N203 (gases)
Slurry
Mg3(As04)2 + Mg(OH)2
TREATMENT
Treat w/excess Ca(OH)2
Evaporate
Treat w/hot HN03 + H20
Treat w/excess Mg(OH)2+H20
Scrub w/dilute caustic soln
(NaOH assumed)
Filter & wash
Evaporate (Optional)
—i
r-
'*
1
2
1
2
3
4
TOXIC
NAME
Ca3(As03)2 + CaCl2
+ Ca(OH)2 + H20
Ca3(As03)2 + CaCl2
+ Ca(OH)2
H3As04 + HC1 +
HNO, + N,0, + H,0
3 23 2
HC1 + N203
Mg3(As04)2 + MgCl2
+ Mg(N02)2 +
Mg(N03)2 + Mg(OH)2
+ H20
Mg3(As04)2 +
Mg(OH)2 + H20
Mg3(As04)2 +
Mg(OH)2
FORM
Soln
Very sol-
uble
Granular
Solid
Soln
Gases
Slurry
Damp solid
Solid
P
i
r-
m
m
X
-o
5
l/l
m
m
|
m
in
§
X
X
NONTOXIC
NAME
H20
NaCl + NaNO,
c.
NaOH + H20
MgCl2+Mg(N03)2+
Mg(N02)2+Mg(OH)2
H20
FORM
Vapor
Dilute
soln
*E
Dilute
soln
*E
Vapor
g
i
i—
m
m
X
-o
I
m
m
o
r~
K
§
X
X
*-« O i-t
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Ui
NAME
Cd
Cd
TREATMENT
Melt & cast into solid
Store or recycle
—i
i —
*
1
TOXIC
NAME
Cd
FORM
Solid
g
r"
m
1
m
X
I
O
CO
m
m
•<
O
r~
m
X
NONTOXIC
NAME
FORM
-n
i—
r—
m
m
X
0
m
0
i—
CO
»— »
§
3
30
3:
O
o.
en
o
Q.
»j
>
0
0
m
-o
— <
TI
o
33
3:
n
Q.
OO
0^
Q.
L*>
>
z
-H
*S
I—
3
70
:x
o
00
-n
0
s
>
o
i/>
r>
»
-a
— )
i
— i
(—
#
:c
*•
3
C
<->
a.
z
s
o
a*
a.
3
c
3
-o
i
Q-
fl>
5
a.
o
z
p
CO
no
-------
TREATMENT PRODUCTS
NAME
Cd(CN)2
Slurry
CdO + CaCl2 +
Ca(OH)2
CdO + H20
TREATMENT
Cone: Dilute-
Dilute: Oxidation w/hypo-
chlorite ion (Ca(OCl)2
assumed)
Evaporate g 500°C
Wash & filter
Evaporate (Optional)
-H
*
1
2
3
4
TOXIC
NAME
Cd(OH)2 + CaCl2 +
Ca(OCl)2 + CdC03 +
N2 + H20
CdO + CaCl2 +
Ca(OH)2
CdO + H20
CdO
FORM
Slurry
Solid
Damp solid
Solid
p
fe
5
r—
m
m
X
P
3
m
90
90
R
S
£
X
X
)°C
X
)°C
NONTOXIC
NAME
C02 + N2
C02 + N2 T 02 +
H20
CaCl2 + Ca(OH)2 +
H,0
FORM
Gases
Gas
Dilute
soln
*E
Vapor
?
§**
r~
m
m
r"
a
m
m
3
f^
ISI
£
X
X
X
*-• O •-"
ro -& H-.
-------
to
TREATMENT PRODUCTS
*E - ENVIRONMENTAL RISK
*ri.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Cd(N03)2
Slurry
CdO + Ca(N03)2 +
Ca(OH)2
CdO + H20
TREATMENT
Cone: f, dilute :
Treat w/excess Ca(OH)2
Evaporate 9 320°C
Wash & filter
Evaporate (Optional)
t
.
»
1
2
3
4
TOXIC
NAME
Cd(OH)2 + Ca(M03)2
+ Ca(OH)2 + H20
CdO + Ca(N03)2 +
Ca(OH)2
CdO + H20
CdO
FORM
Slurry
Solid
Damp sol id
Solid
^
CD
_
X
o
m
90
Of
90
m
5~
I—
<
IS.
£
X
°c
X
l°(
X
NONTOXIC
NAME
,,2o
Ca(NOJ? + Ca(OH).
'
+ H20
H,0
FORM
Vapor
Dilute
soln
*E
Vapor
i—
£
1
r-
m
x
r"^
O
m
m
m
1/1
%
X
X
-------
u>
(^
00
TREATMENT PRODUCTS
*E - ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. " 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME~ "
Cd(CN)2 ' KCN
Slurry
CdO +• CaCl2 + KOH +
Ca(OH)2
CdO + H20
TREATMENT
Oxidize with hypochlorite
ion (Ca(OCl)2 assumed)
Evaporate P 500°C
Wash & filter
Evaporate (Optional)
i—
^
1
2
3
4
TOXIC
NAME
Cd(OH)2 + KOH +
CaCl2 + Ca(OCl)2 +
CdC03 + K2C03 + N2
CdO + CaCl2 +• KOH +
Ca(OH)2
CdO + H20
CdO
FORM
Slurry
Solid
Damp sol id
Solid
•n
r*
X
^
m
m
X
-a
t/)
m
qr
90
m
ni
^
X
X
)°C
X
D°C
NONTOXIC
NAME
C02 + N2
C02 + N2 + 02 +
H20
CaCl, + KOH +
Ca(OH)2 + H20
HO
FORM
Gas
Gas
Dilute
so In
*E
Vapor
•n
r~
m
m
X
-o
0
m
m
o
i—
to
%
X
X
X
-------
VO
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
M.I . " HAZARD INDEX
H.L. - TREATMENT LEVEL
T.L. - 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Cr03
C.r2(SO,,)3 + S02 -
II20
Slurry
Cr(OH)3 + H20
TREATMENT
Reduction w/SO?
Precipitation by adjusting
Pll > 9.5 (NaOH assumed)
Filter ft dilute filtrate
Evaporate (Optional)
— i
i
»
1
2
3
4
TOXIC
NAME
Cr,(SO. ), + SO, +
C
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. " 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
00
-~J
O
NAME
Cu2C2
TREATMENT
Detonation
^
f-
4
1
TOXIC
NAME
CuO + CuC03
FORM
Solid
i—
^
r~
m
m
X
f—
o
(/I
m
m
§
in
S
NONTOXIC
NAME
FORM
>
1
r"
m
m
X
-o
I—
g
m
m
§
s
S
O
|T
r~
*n
c
n
c
o
+
0
c
o
u>
t/>
o
CL.
-
^
O
o
m
T:
s
<->
c
o
+
o
c
o
o
W
3
a.
-
-
2
S
c
o
IO
s
a*
in
o
;o
i— i
i
— i
r*
F
S
§
£
<-,
ro
o
ro
z
x>
?
o
o
0
o
-p.
n
T>
0.'
n>
x
tn
_>
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. » HAZARD INDEX
•T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U>
NAME
Copper Chlorotetra-
zole
TREATMENT
Controlled incineration w/
afterburner & preci pita tor,
scrub gases with/dilute al-
kaline soln (NaOH assumed)
— i
*
1
TOXIC
NAME
CuO
FORM
Solid
;3
>
^
CO
r-
m
m
X
r*
0
i/)
m
m
o
r~
CO
%
NONTOXIC
NAME
NaNO + NapCO, +
NaOH + Nad +
H-0
FORM
Dilute
soln
*E
-n
r~
v
3
(—
m
m
X
r-
o
s
m
P
m
to
Si
-------
ho
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. " HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Cu(CN)2
Slurry
CuO + CuC03 + H20
TREATMENT
Oxidation w/hypochlorite ion
(NaOCl assumed)
Filter & wash
Evaporate with heat (Optional
i—
*
1
2
)3
TOXIC
NAME
Cu(OH)2 + CuC03 +
Nad + NaOCl +
H20 + N2
Cu(OH)2 + CuC03 +
H20
CuO
FORM
Slurry
Damp solic
Solid
-n
r~
|
m
o
CO
m
<
o
m
to
%
X
NONTOXIC
NAME-
C02 i- N2
NaCl f NaOCl +
N, + H20
H20 + C02
FORM
Gas
Dilute
soln
*E
Gas
r"
i
m
x
'o
CO
m
m
<
r-
CO
%
X
X
X
-------
TREATMENT PRODUCTS
*E « ENVIRONMENTAL RISK
•M.I. - HAZARD INDEX
•T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
LO
-J
bo
NAME
CuCtl
Slurry
Cu(OH)2 + CuC03 t
TREATMENT
Oxidation w/hypochlorite
ion (NaOCl assumed)
Filter & wash
Evaporate w/heat (Optional)
r-
*
1
2
3
TOXIC
NAME
Cu(OH)2 + CuC03 +
N2 + MaCl + MaOCl +
Cu(OH)2 + CuCO^ +
H n
2
CuO
FORM
SI urrv
Damp solid
Solid
-n
i—
^
CD
m
m
X
T3
0
m
m
O
1—
^
$
X
NONTOXIC
NAME
C02 + N2
NaCl + NaOCl +
. .
2 2
H2o * cn2
FORM
Gas
Dilute
soln
*L
Gas
-n
I
f—
m
X
-o
8
m
m
o
r-
1/1
%
X
X
X
-------
TREATMENT PRODUCTS
*E - ENVIRONMENTAL RISK
*H.I. » HAZARD INDEX
*T.L. » TREATMENT LEVEL
T.L. " 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Cyanides
Slurry
Damp sol id
TREATMENT
Oxidation w/hypochlorite
ion (NaOCl assumed)
Filter & wash
Evaporate (Optional)
-H
»
1
2
3
TOXIC
NAME
Heavy metals as
C03 or OH + N2
+ NaCl + NaOCl +
H20
Heavy metals as
OH or C03 t H20
Heavy metal oxides
or carbonates
FORM
SI urry
Damp solid
Solid
p
>•
£
r~
m
m
X
8
m
m
g
i/>
§
X
NONTOXIC
NAME
C02 + N,
N2 + NaCl + NaOCl
+ H20
u A A rr\
H20 + C02
FORM
Gas
Dilute
soln
*E
Vapor
?
^
<£
r~
m
X
0
l/>
m
m
o
r~
en
%
X
X
X
-------
TREATMENT PRODUCTS
*E » ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
LJ
vj
Ui
NAME
=520
llg + H20
TREATMENT
Controlled incineration w/
afterburner 8 precipitator ft
condense (20°C). Scrub gases
w/dilute caustic soln (NaOH
assumed)
Purify 4 recycle
—i
*
1
2
TOXIC
NAME
PbO + metal oxides
Hg + H-0
FORM
Solid
Liquid
?
•^
£
r-
m
m
X
0
m
m
o
£
X
NONTOXIC
NAME
NaNO + Na0CO, +
x 23
NaOH + H20
FORM
Dilute
soln
*£
?
1—
m
m
X
r~
o
i/»
s
m
^
m
S
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. " 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C6H205N4
Hg + H20
TREATMENT
Controlled incineration w/
afterburner f, orecipitator R
condense (20°C). Scrub gas-
es w/dilute caustic soln
(NaOH assumed)
Purify & recycle
r—
»
1
2
TOXIC
NAME
PbO + metal oxides
Hg + H20
FORM
Solid
Liquid
P
£
r-
m
m
X
o
m
m
o
i—
to
§
X
NONTOXIC
NAME
NaNO + Na CO +
NaOH + H20
FORM
Dilute
soln
*E
£
P
r~
m
m
X
"O
k
m
m
?
CO
8
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
•H.I. - HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. • 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
to
NAME
(NO ) C II CM
IU, * II20
TREATMENT
Controlled incineration w/
afterburner ?i nrecipitator &
condense (20"C). Scrub aases
w/dilute caustic soln (NaOII
cissuined)
Purify fi recycle
—4
r—
*
1
2
TOXIC
NAME
PbO + metal oxides
Hq + H20
FORM
Solid
Liquid
-n
I—
^
r-
m
X
o
m
m
O
r~
on
S
X
NONTOXIC
NAME
NaNfl + Na,CO. +
x i 3
NaOH + H.,0
FORM
Dilute
soln
*E
£
?
r-
m
m
X
•o
o
rn
m
O
r—
S
8
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.l. • HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. • 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U>
««J
00
NAME
C10H16N6°19
Hg + H20
TREATMENT
Controlled incineration w/
afterburner & precipitator &
condense (20°C). Scrub qases
w/dilute caustic soln (NaOH
assumed)
Purify & recycle
.-*
If
1
2
TOXIC
NAME
PbO
+ metal oxides
Hg + H20
FORM
Sol id
Liquid
p
J»
*£
r~
m
m
22
o
(SI
m
m
o
r~
s
§
X
NONTOXIC
NAME
NaNOx + Na2C03 +
NaOH + H20
FORM
Dilute
soln
*E
p
§•**
r~
m
m
X
r~
0
m
m
o
i—
ft
%
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
00
•vl
vo
NAME
F2 (SiF4 and/or HF
possible contami-
nants)
HF + SiF4 + CF4
Slurry
TREATMENT
Reaction w/charcoal
Scrub w/Ca(OH)2
Evaporate (Optional)
— i
*
1
2
3
TOXIC
NAME
HF + SiF4 (possib-
ly) + CF4
CaF2 + CaSi03 +
Ca(OH)2 + H20
CaF2 + CaSi03 +
Ca(OH)2
FORM
Gas
Slurry
Solid
i>
^
r—
m
m
X
•D
O
m
0
%
X
NONTOXIC
NAME
CF4
H2n
FORM
Gas
Vapor
x>
s
1—
rri
X
•o
o
CO
m
m
<
P
s
%
X
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
00
O
NAME
C4H1002PF
Slurry
TREATMENT
Incineration w/afterburner &
scrub w/caustic soln (Ca(OH).
assumed)
Evaporation (Optional)
_-<
J-
»
1
2
TOXIC
NAME
CaF2 + Ca2P207 +
CaC03 + Ca(OH)2 +
H20
CaF2 + Ca2?207 +
CaC03 + Ca(OH)2
FORM
Slurry
Solid
?
^
i—
m
m
X
^
S5
<
m
m
?
•<
t/i
%
NONTOXIC
NAME
H20
FORM
Vapor
5
r
r"
m
m
X
-o
r~
o
i/)
-------
TREATMENT PRODUCTS
*E - ENVIRONMENTAL RISK
*H.l. - HAZARD INDEX
"T.L. - TREATMENT LEVEL
T.L. • 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U)
00
NAME
PNC
Hy * 11,0
TREATMENT
Controlled incineration w/
afterburner R precipitator &
condense (20°C). Scrub gases
w/dilute caustic soln (llaOH
assumed)
Purify 5 recycle
— i
*
1
2
TOXIC
NAME
PbO +
metal oxides
Hg + H-0
FORM
Solid
Liquid
?
|
I—
rn
X
r-
0
m
m
O
m
t/i
%
X
NONTOXIC
NAME
NaNO * Na2C03 +
NaOH + H^O
FORM
Dilute
soln
Tl
^
r"
m
m
X
m
m
o
r-
%
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
CO
00
NJ
NAME
Pb(N3)2
Pb
TREATMENT
Electrolytic destruction
Recycle or store (Optional)
— i
r-
'»
1
2
TOXIC
NAME
Pb
FORM
Solid
| FLAMMABLE
EXPLOSIVE
m
P
s
to
s
NONTOXIC
NAME
N2
FORM
Gas
g
i—
m
EXPLOSIVE
m
%
X
-------
TREATMENT PRODUCTS
*E « ENVIRONMENTAL RISK
*H.l. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
00
00
LO
NAME
Pb(N3)2
Hg + H20
TREATMENT
Controlled incineration w/
afterburner & precipitator &
condense (20°C). Scrub gases
w/dilute caustic soln (NaOH
assumed)
Purify & recycle
— i
*
1
2
TOXIC
NAME
PbO +
metal oxides
Hg + H20
FORM
Solid
Liquid
-n
i—
|
1—
m
X
o
m
S
m
S
X
NOHTOXIC
NAME
NaNO + Ha,CO, +
x 23
NaOH + H20
FORM
Dilute
soln
?
i
i—
m
X
o
t/»
m
m
o
r-
S
-------
u>
00
TREATMENT PRODUCTS
*E =• ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. " 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Pb(CN)2
Slurry
PbO + NaCl
PbO + H20
TREATMENT
Oxidation w/hypochlorite ion
(NaOCl assumed)
Evaporate w/heat ( 315°C)
Dilute, filter & dilute
filtrate
Evaporate (Optional)
r-
1
2
3
4
TOXIC
NAME
Pb(OH)2 + NaCl +
PbC03 + NaOCl +
PbO + NaCl
PbO + H.O
PbO
FORM
Slurry
Solid
Damp solid
Solid
|
m
m
x
»— i
s
m
£
S
§
X
NONTOXIC
NAME
C02 + N2
N2 + 02 + H20 +
co2
NaCl + H-0
H20
FORM
Gas
Gas
Dilute
soln
*E
Vapor
g
r~
m
m
X
r—
m
m
s
CO
8
X
X
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
•H.I. « HAZARD INDEX
•T.L. - TREATMENT LEVEL
T.L. - 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
00
Ul
NAME
CcH206N2Pb
Hg + H20
TREATMENT
Controlled incineration w/
afterburner f> orecipitator ft
condense (2n°C). Scrub gases
w/dllute caustic soln (NaOH
assumed)
Purify 6 recycle
r—
*
1
TOXIC
NAME
PbO +
metal oxides
Hg + H20
FORM
Solid
Liquid
-n
r~
£
r-
m
X
T3
O
n
m
O
r—
V)
%
X
NONTOXIC
NAME
,'JaOII + H2n
FORM
Dilute
soln
*E
£
i
r~
m
m
X
"O
O
I/I
m
pn
O
U)
%
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
00
NAME
C H ON Pb
TREATMENT
Controlled incineration w/
afterburner & preclpitator,
scrub gases w/dilute caustic
soln (NaOH assumed)
—i
i—
*
1
TOXIC
NAME
PbO
FORM
Solid
>
^
i—
m
m
X
-o
CD
m
m
§
t/l
§
NONTOXIC
NAME
NaNO + Na.CO, +
X Z 3
NaOH + H20
FORM
Dilute
soln
*E
5
s
1—
m
m
X
•a
r*
o
en
s
o
r~
3
S;
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
•H.I. • HAZARD INDEX
•T.L. - TREATMENT LEVEL
T.L. - 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
00
NAME
C6H(M02)3(02Pb)
llg + H20
TREATMENT
Controlled incineration w/
afterburner & precipitator.
Condense P 20°C R scrub gases
w/dilute caustic soln (NaOH
assumed)
Purify R recycle
— <
*
1
2
TOXIC
NAME
PbO +
metal oxides
Hg + HJ)
FORM
Solid
.inuid
p
^
CD
1 —
m
m
x
o
m
i
i/>
8
X
NONTOXIC
NAME
NaMO + lla,CO, +
NaOH + H20
FORM
Dilute
soln
*F
>
5
r-
m
rn
X
-o
r"
0
t/>
m
m
s
s
S
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
OJ
00
00
NAME
CgH(N02)3(02Pb)
TREATMENT
Controlled incineration w/
afterburner & precipitator.
Scrub gases w/dilute caustic
soln (NaOH assumed)
p
*
1
TOXIC
NAME
PbO
FORM
Solid
g
§
r-
m
m
X
0
on
m
m
o
«=
-------
U)
c»
TREATMENT PRODUCTS
*L = ENVIRONMENTAL RISK
••I.I. - HAZARD INDEX
•T.L. - TREATMENT LEVEL
T.L. - 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C2H2ASC13
Soln
Al ternate
Gas
Soln + Gas
Slurry
Mg3(As04)2 +Ma(OH)2
+ H?0
TREATMENT
Cone: fi dilute:
Controlled incineration w/
afterburner w/caustic scrub-
ber (Ca(nn)? assumed)
Evaporate (Optional)
Controlled incineration w/
afterburner
Treat w/hot Hfl03 soln
Treat w/Mg(OII)2 soln
Fil ter 4 wash
Evaporate (Optional)
r*
#
1
2
1
2
3
4
5
TOXIC
NAME
CaCl2 + Ca3(As03)2
+ Ca(OH)2 + H20
Cad2 + Ca3(As03)2
+ Ca(OII)2
HC1 + A$203 + C02
HC1 + H.,As04 +
N203 + C02 + HM03
N203 + C02
MgCl + Mg(NO,)z +
MgCO, + Mq(flO,), +
J J (.
Mg(OH)2 + H?0
Mg3(As04)2 +
Mg(OH)2 + H20
WW«™*
FORM
Soln
Crystal-
1 ine .solid
fias
Soln
Gas
Slurry
Damp sol id
Solid
™n
i—
r—
m
m
X
LOSIVE
m
o
r"
m
X
Y
X
NONTOXIC
NAME
H2°
Hf|(fl03)2 + MqtniOj
"2°
FORM
Vapor
Dilute
soln
*E
Vapor
-n
i —
CO
1 —
m
X
O
m
m
0
(-0
§
X
X
o
3>
r~
|
3
CO
Aj
y>
in
O
c»
\j
-f
3
in
o
X
NJ
1/1
O
o.
U1
-
:>
n
m
-4
•n
o
3O
z
(->
CU
(->
ro
+
n
Oi
u>
3>
trt
O
OJ
(\)
+
o
Cb
0
nn
f\3
1C
no
O
Ln
O
3
_.
en
,_
z
-H
>
1—
S
73
2
O
-
TJ
O
^D
31
c
^
J»
a*
o
rn
t^
o
»
-o
—1
o
z
— i
1 —
»
DC
*
-n
O
f—
1*
n
\j
^c
3>
y>
(->
Z
>
i5
1
i/i
c-h
fl>
C3
^»
o
ro
4=.
UJ
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. « HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. « 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C6H86
Hg + H20
TREATMENT
Controlled incineration w/
afterburner & precipltator,
condense (20°C) & scrub gases
•I/dilute caustic soln (NaOH
assumed)
Purify & recycle
. '
»
1
2
TOXIC
NAME
PbO + metal oxides
Hg + H20
FORM
Solid
liquid
fiJ
^
£
1—
m
X
o
s
m
f.
¥
•c
on
%
X
NONTOXIC
NAME
NaNOjj + Na2C03
+ NaOH + H20
FORM
Dilute
soln
*E
?
^?
1
r*
m
X
r~
8
n-
5
P
m
w
S!
VI
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
Ml. I. » HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
VO
NAME
Hg(ONC)2
Hg + H20
TREATMENT
Controlled incineration w/
afterburner & precipitator &
condense (20°C) scrub gases
w/dilute caustic soln (NaOH
assumed)
Purify & recycle
— i
I
*
1
2
TOXIC
NAME
PbO + metal oxides
Hg + H20
FORM
Solid
liouid
^3
^
g
i—
m
m
X
o
m
m
0
oo
£
X
NONTOXIC
NAME
NaNO.. + Na2COj
+ NaOH + H20
FORM
Dilute
soln
*E
§
r3
m
frl
X
J3
o
CO
s
m
0
1—
?n
l/l
S
-------
u>
vo
N)
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Ni(CN)2
Slurry
NiO + NaCI
NiO + H20
TREATMENT
Oxidation w/hypochlor1te ion
(NaOCl) assumed
Evaporate @ 240°C
Dilute, filter & wash
Evaporate (Optional)
r1
^
l
2
3
4
TOXIC
NAME
Ni(OH)2 + N1C03 +
NaCI + N2 + NaOCl
N10 + NaCI
NiO + H?0
*
NiO
FORM
Slurry
Solid
Damp solid
Solid
p
>
i$
1—
m
m
X
o
t/1
%
m
o
r-
<
t/i
§
X
NONTOXIC
NAME
C0? + N2
«»,.,,.„,.
Nad + H?0
'
H20
FORM
Gas
Gas
Dilute
soln
*E
Vapor
P
^
J
I—
m
m
X
m
m
P
m
*/>
%
X
X
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Co
\o
co
NAME
C3H5(ON02)3
Hg + H20
TREATMENT
Controlled incineration w/
afterburner ft precipitator,
condense 0 20°C & scrub gase;
w/dilute caustic soln (NaOH
assumed)
Purify & recycle
— i
i
*
1
2
TOXIC
NAME
PbO + metal oxides
Hg + II20
FORM
Solid
liquid
Tt
r™
>
X
r-
m
m
X
O
CO
s
m
i—
<
c?
§
X
NONTOXIC
NAME
NaNOx + Na2C03
+ NaOH + H20
FORM
Dilute
soln
-n
r~
3
r~
m
m
X
o
m
m
°
m
l/>
%
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
lo
vo
NAME
C(CH2N03)4
Hg + H20
TREATMENT
•Controlled incineration w/
afterburner & precipitator,
condense 0 20°C & scrub gases
w/dilute caustic soln (NaOH
assumed)
Purify & recycle
i—
*
1
2
TOXIC
NAME
PbO + metal oxides
Hg + H20
FORM
Solid
Liauid
3>
^
r~
m
m
X
o
CO
m
m
6
Vt
%
X
NONTOXIC
NAME
NaNOx + Na2C03
+ NaOH + H20
FORM
Dilute
soln
*E
5
£
r-
m
m
X
-o
i—
9
m
m
ft
%
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. » HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
vo
Ln
NAME
(:io2)3c6H2OH
llg + H20
TREATMENT
Controlled incineration w/
afterburner & precipitator,
condense @ 20°C X scrub gases
w/dilute caustic soln (NaOH
assumed)
Purify & recycle
r*
*
i
2
TOXIC
NAME
PbO + metal oxides
Hg + H20
FORM
Solid
1 iquid
r-
5
r-
m
X
•o
0
m
m
o
r~
•;
i/i
^
X
NONTOXIC
NAME
NaNOx + Na2C03
+ NaOH + H20
FORM
Dilute
soln
*E
?
E
i—
m
m
X
S
m
m
O
r-
00
S
i
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 « CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U>
NAME
K2Cr04
Slurry
"recipitate + soln
Cr(OH)3
TREATMENT
Reduction w/S02
Precipitation by adjusting
PH > 9.5 (NaOH assumed)
Filter ?. dilute filtrate
Evaporate w/heat (Optional)
-H
if
l
2
,
4
TOXIC
NAME
K2S03 + Cr2(S04)3
+ S02 + H20
Cr(OH)3
I^SOg + NagSO^ +
Ma2S03 + NaOH +
KOH + H20
Cr(OH). + H2n
O L.
Cr203
FORM
SI urry
Precipi-
tate
Soln
Sludoe
Crystals
rj
3
i—
m
X
T)
r~
o
t/i
m
m
•5
I—
«^
m
Vi
§
X
NONTOXIC
NAME
Ma2S03 + KOH +
-
n&2 4 23
+ NaOH + H?0
FORM
Dilute
soln
*E
Vapor
>
9
r~
m
m
X
•o
5
rn
m
§
r"
m
CO
§
X
s
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. > HAZARD INDEX
*T.L. * TREATMENT LEVEL
T.L. - 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U>
NAME
K2Cr20?
Slurry
Precipitate + soln
Cr(OH)3 + H?0
TREATMENT
Reduction w/S02
Precipitation by adjusting
PH 9.5 (NaOH assumed)
Filter ft dilute filtrate
Evaporate w/heat (Optional)
— i
r—
*
1
2
3
4
TOXIC
NAME
W ; £<».'3
Cr(OH),
K.SO-j + "a,Sn. +
KOH + f'a2S13 +
NaOH + H20
Cr(OH), * H2n
FORM
Slurry
Precipi-
tate
soln
Sludoe
Crystals
r—
^
r-
m
m
X
o
CO
m
m
§
£
CO
X
NONTOXIC
NAME
•ta^sn, + w +
K2sn + Na2sna
+ "aOH + H2n
FORM
Dilute
soln
*E
Vapor
r-
•f
^j
r-
m
m
X
5
rri
m
o
r—
CO
s
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.l. - HAZARD INDEX
*T.L. « TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
OJ
vo
00
NAME
C10H4N406K
Hg + H20
TREATMENT
Controlled incineration w/
afterburner & precipitator,
condense @ 20°C & scrub gases
w/dilute caustic soln (NaOH
assumed)
Purify & recycle
— i
r~
*
i
2
TOXIC
NAME
PbO + KOH + metal
oxides
Hg + H-O
FORM
Damp sol id
Liquid
p
ir
5
r~
m
X
r~
o
m
m
o
r"
m
1/1
%
X
NONTOXIC
NAME
NaNO + Na.CO,
x 23
+ NaOH + H20
FORM
Dilute
soln
*E
§
?
i—
m
m
X
I—
b>
m
m
o
i—
?S
1/1
8
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. « HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U>
vo
vo
NAME
AgCN
Slurry
AgCl + H?0
TREATMENT
Oxidation w/hypochlorite ion
(NaOCl assumed)
Filter 8 wash
Evaporate (Optional)
—i
4
1
2
3
TOXIC
NAME
AgCl + Ha-CO, +
NaOH + N2 + NaOCl
+ HgO
AgCl + H,0
AgCl
FORM
Slurry
Damp sol ic
Solid
r-
1
CD
r-
m
m
X
o
m
m
s
X
NONTOXIC
NAME
C02 + N2
NaOH + MaOCl + '\2
+ Ma^CO, + H_0
FORM
Gas
Dilute
soln
*E
Vapor
-n
r*
f
m
m
X
•o
8
m
m
0
r—
v,
&
X
X
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
O
O
NAME
#541
Hg + H20
TREATMENT
Controlled incineration w/
afterburner & precipitator,
condense @ 20°C & scrub gases
w/dilute caustic soln (NaOH
assumed)
Purify & recycle
— *
r-
*
1
2
TOXIC
NAME
PbO + metal oxides
Hg + H20
FORM
Solid
liquid
i>
^
i—
m
m
X
-a
o
m
m
3
^
§
X
NONTOXIC
NAME
NaNO + Na,CO,
x 23
+ NaOH + H20
FORM
Dilute
soln
*E
5
1
i—
m
m
x
•D
0
C/>
m
m
o
r—
t/i
VI
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*M.|. « HAZARD INDEX
*T.L. - TREATMENT LEVEL
M. • 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
NJ?Cr04
51 urry
^oln + precipitate
Cr(nil)3 + H20
TREATML . f
Reduction w/SO?
Precipitation by adjusting
P!l>9.5 (NaON assumed)
Filter K dilute ''iltrate
Evaporate w/heat (Optional)
— i
*
1
2
3
loxir.
NAME
Cr,(SO. ), + f,'a.,SO,
C H J C J
+ sn, + n,o
2 2
Cr(OHK
'laOH + f'a0sn4 +
fla2S03 + H.O
Cr(OH), + H,0
1 ;:
F'lRV
Slurry
precini-
tato
soln
MUHOP '
Crvst-ils
-n
i—
\
CO
r—
m
m
X
-o
0
m
m
3
00
C1
X
NONTOXIC
NAME
'la2S03 + fla2S04
+ NaOH + H,0
FORM
Dilute
soln
*F
Vapor
•n
I—
J>
f
m
X
•o
o
-c
m
m
O
i~
^
$
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Na2Cr207
Slurry
Soln + precipitate
Sludge
TREATMENT
Reduction w/S02
Precipitation by adjusting
PH > 9.5 (NaOH assumed)
Filter & dilute filtrate
Evaporate w/heat (Optional)
.-•
*
1
2
3
4
TOXIC
NAME
Cr2(S04)3 + Na2S03
Cr(OH)3
Na2S04 + NaOH +
Cr(OH)3 + H20
Cr203
FORM
SI urry
Precipi-
tate
soln
Sludge
Crystals
P
^
t—
m
m
X
0
£
m
3
S
§
X
NONTOXIC
NAME
NaS03 + Na2S04
+ NaOH + H20
H20
FORM
Dilute
soln
*E
Vapor
p
§•**
m
m
X
r-
bi
-C
m
m
s
ft
in
8
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
'H.I. - HAZARD INDEX
•T.L. * TREATMENT LEVEL
T.L. - 0 « CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
O
CO
NAME
C7M5°6N3
Hg + H20
TREATMENT
Controlled incineration w/
afterburner & preci pita tor,
condense 0 20°C & scrub gases
w/dilute caustic soln (NaOH
assumed)
Purify & recycle
— i
*
1
2
TOXIC
NAME
Hg + H-0
Metal oxides + PbO
FORM
Liquid
Solid
-n
r~
ap
K
m
X
r—
l/>
n
m
O
r*
m
OT
X
NONTOXIC
HfiHE
NaNO + Na-CO-
+ NaOH + H20
FORM
Dilute
soln
*E
i—
?
s
m
X
i —
O
CO
m
m
*c
o
r~
ft
I/O
e
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. « HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. • 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
O
.p-
NAME
C H ON
Hg + H20
TREATMENT
Controlled incineration w/
afterburner & precipitator,
condense @ 20°C & scrub gases
w/dilute caustic soln (NaOH
assumed)
Purify & recycle
—i
i—
»
1
2
TOXIC
NAME
Hg + H20
Metal oxides + PbO
FORM
Liquid
Solid
>
£
r-
m
m
X
-O
O
m
m
o
i—
CO
P
X
NONTOXIC
NAME
NaNO,, + Na-CO,
+ NaOH + H20
FORM
Dilute
soln
*E
5
^
r-
m
m
X
-o
o
m
m
s
IS)
e
VI
-------
Pages 406 through 444 of Appendix B-3, Waste Treatment Procedures, refer
to Table 9, CANDIDATE WASTES WHICH MUST BE TREATED AND WHOSE TREATMENT
PRODUCTS CONSTITUTE AN ENVIRONMENTAL RISK ONLY. (Candidates listed in
alphabetical order by name.)
405
-------
O
ON
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. - 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
TREATMENT PRODUCTS CONTAINERS.
NAME
C3H40
TREATMENT
Dilute: concentrate by sub-
merged combustion.
Cone: Incineration w/after-
burner
— t
i—
1
TOXIC
NAME
FORM
p
1—
m
m
x
m
m
§
NONTOXIC
NAME
C02 + H20
FORM
Gas
5
m
m
X
-o
g
m
§
to
X
0
m
s
5
CO
a*
H
tu
t/i
a*
cr
0
<
n>
_
o
ACCEPT.
-TI
O
?
<->
O
\)
+
3:
\>
o
CT
a>
v>
_,
3
Z
-<
>
r—
-n
o
?
o
ro
rj
-n
o
x>
a*
o
00
0
71
5
»-«
O
—1
'»
X
»
s
c
o
A>
u1
o
NAME: Acrolein
o
o
oo
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.l. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
NH C H N 0
TREATMENT
Controlled incineration
w/afterburner & caustic scrub-
ber (dilute soln) (NaOH
assumed)
— t
i —
*
1
TOXIC
NAME
FORM
-n
f—
7
CO
i —
m
m
X
•o
o
UO
m
m
o
r~
%
NONTOXIC
NAME
NaNO + Na0CO-,
+ NaOH + HpO
FORM
Dilute
Soln
*F
*t
i —
m
X
-o
f—
o
m
m
<
o
f—
s
%
-------
TREATMCNT PRODUCTS
M • IHVIHONMtNTAL RISK
*H.I. - HAZARD INDEX
H.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
O
00
NAML
Hb\ , !iOf)
TRLATMENT
lncinor.it ion w/aqueous scrub-
hinn
r—
*
1
TOXIC
NAME
FORM
g
£
P*
m
m
x
?
o
I/)
s
m
g
1/1
K
NONTOXIC
NAML
H3B03 ' H20
FORM
Dilute
Soln
*L
g
?
I—
m
m
X
•o
r*
w
s
m
s
ts*
%
-------
TREATMENT PRODUCTS
M: « ENVIRONMENTAL RISK
•H.I . • HA?ARD INDEX
•T,L. • TRfATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
l,«!l).
TREATMENT
Cone: dllutimi
Oil ulc: ox iila 1 inn
w/hy|)ui:hlori IP ion ((la(nci)n
as Mimeil)
J_
'»
1
1
TOXIC
NAME
FORM
n
1
J.
1
U3
m
X
-o
f—
0
1/1
£
m
<
0
r-
m
£
NONTOXIC
•MM!
Cad- i C.iCO, •
N? >• Ca(OC1)2 •
H?n
N, < cnr,
'- '
filRM
Snln
•1
Cuis
g
1
f—
m
m
X
Tl
r~
o
C/l
m
«c
0
r"
U1
§
X
X
o
m
>
i—
•n
o
xt
3:
c~>
Oi
C~i
+
r~>
O)
i~>
o
_.
o
(~>
OJ
0
o
o
-»•
n:
vj
O
LO
0^
3
-»
m
J»
o
o
n
-o
—1
-n
o
73
•x.
o
o
•p
rt
o
tu
a
o
<"
t_t
z
_^
^
r~
-n
o
n
X
o
»\j
43.
s
>
a*
R
00
O
77
Tl
—1
O
Z
_j
.
*
3C
t— «
»
-n
o
c
o
a>
o
3
\i
z
>
^
r->
OJ
o
3
r>
^<
(U
3
a.
p
o
vO
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. " HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C10H6C18
TREATMENT
Dilute: concentrate w/acti-
vated carbon beds a/regener-
ation of carbon in furnace.
Treat products same as below.
Cone: incineration w/after-
burner & scrub w/dilute caus-
tic soln. (NaOH assumed)
i—
*
1
TOXIC
NAME
FORM
g
£
i—
m
X
-o
'o
t— »
m
m
O
r—
CO
§
NONTOXIC
NAME
NaCl + Na2C03 +
NaOH + H20
Ash (possible)
FORM
Dilute
soln
*E
Powder
£
1
r~
m
>e
0
S
m
g
00
^
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
ci2
TREATMENT
Scrub w/caustic soln (NaOH
assumed)
—i
r-
*
1
TOXIC
NAME
FORM
-n
i—
3>
3
m
m
X
-o
o
CO
m
m
g
CO
g
HONTOXIC
NAME
NaOCl + NaOH +
HO
FORM
Soln
*E
(Recycle)
i—
5
m
m
X
0
s
m
O
1—
s
^
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. • 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C1F3, C1F5
C12 + CF4
TREATMENT
Reaction w/tharcoal
Scrub w/caustic soln (NaOH
assumed)
r-
»
1
2
TOXIC
NAME
C1-, + CF4
FORM
Gas
~n
r~
>
i—
m
m
x
•o
o
to
<
m
m
g
«=
w
§
X
NONTOXIC
NAME
C
NaOCl + NaOH +
H20
CF.
4
FORM
Solid
Soln
*E
(Recycle)
Gas
?
>
^
i—
rri
m
X
•o
0
•<:
rri
m
<:
o
i—
-<
en
£
X
X
-------
TREATMENT PRODUCTS
H = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C H 0 N
TREATMENT
Controlled incineration as a
slurry w/afterburner & scrub-
bing w/dilute caustic soln
(NaOH assumed)
—t
r-
*
1
TOXIC
NAME
FOPM
-n
i—
3
^ff
i —
m
m
X
-o
«=:
m
m
o
i —
8
NONTOXIC
NAML
NaNO + Na0cn +
y 2 i
NaOH + H00
FJRM
Dilute
soln
-n
i—
r-
m
X
-o
o
m
m
O
t/i
%
i
-------
•P-
h-1
-P-
*E = ENVIRONMENTAL RISK
*H.I. " HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
TREATMENT PRODUCTS CONTAINERS.
NAME
(CH3)2S04
TREATMENT
Cone: dilution
Dilute: incineration w/after-
burner & scrub w/dilute caus-
tic soln (NaOH assumed)
r—
'*
1
TOXIC
NAME
FORM
»
i
i—
m
m
X
-o
r~
s
m
g
m
to
§
NONTOXIC
NAME
NaOH + H20
FORM
Dilute
soln
*E
g
1
r"
m
m
X
-o
0
m
°
4/1
§
o
m
3>
r"
3
1
Z
O*
\3
CO
o
L*J
+
5
SJ
c->
o
+
z
o>
o
+
n:
"O
o
o
c
if
(/»
0^
3
-a
m
s
0
m
3
Tl
1
n>
i/>
3
O
rf
at
o
o
i<
z
_-l
t— t
3
|
o
ro
o
3
i
C
p-
>
D*
O
m
f)
0
?D
i—*
"O
—4
i
.
I~
*
DC
•— t
"*
3
§
C
n
oc
CO
ro
CO
^°
>
S
o
f
rt-
3-
*<
CO
c
-h
Q|
rt-
ro
s
rt
<<^
t/>
c
-h
O»
rt)
O
"
O
a\
0
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
H
Ln
NAME
C7H605N2
TREATMENT
Dilute: concentrate w/acti-
vated carbon beds w/regener-
ation of carbon in furnace.
Treat products same as below.
Cone: incineration w/after-
burner & scrub w/dilute caus-
tic soln (NaOH assumed)
r<
*
1
TOXIC
NAME
F.1RM
T|
J —
S»
^
ro
r-
m
m
x
O
m
m
o
r~
<;
s
NONTOXIC
NAME
NaNO + Na0CO- +
x 23
NaOH + H00
Ash (possible)
FORM
Dilute
soln.
Powder
-n
i—
?
l
m
m
x
o
m
m
0
m
u.
£
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
(N02)2CfiH3CH3
TREATMENT
Mix w/NaHC03 & solid combust-
ibles & incin w/afterburner
& scrubbing w/dilute caustic
soln (NaOH assumed)
-H
r~
*
1
TOXIC
NAME
FORM
g
£
m
m
X
•a
°
s
m
g
t/i
&
NONTOXIC
NAME
NaNOx + Na2C03 +
NaOH + H20
Ash
FORM
Dilute
soln
*E
Powder
5
i
m
n
X
-o
o
m
m
00
^
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. « HAZARD INDEX
*T.L. » TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
•*SML
C10M16"6°1Q
mtATHLNT
Controlled incineration as a
slurry w/afterburner ?i scrub-
bing w/dilute caustic soln
(tlaOH assumed)
r—
*
1
TOXIC
NAME
PIRM
x>
5
r-
r^
m
~
""
m
<
n
£
NONTOXIC
NAME
'IriNO + Na-CO- +
< C '
F.1RM
Dilute
soln
*E
-n
9
s
33
m
X
r~
o
1/1
m
m
s
LO
e
^-
3
m
J>
~n
o
^3
I
Z
o>
z
o
+
z
Of
ro
O
o
U)
-*•
o>
s
-I-
VJ
0
0
n>
yi
0
3
.
m
>
o
0
•o
-4
-n
2
n
3
O
O>
•o
•o
*<
^ t
z
— 1
J»
P"
TI
o
JO
•x.
z
o
3
|
3
o'
3
in
3
ro
o
-n
O
^
r—
>
0*
o
m
o
TO
-a
— i
i
—i
i—
*
^
•— •
"»
-n
o
n
X
c
r—
l>
o
o_
^
o^~
o
o
z
t>
£
o
1
CJ
-a
re
o
3C
O
Ul
tv
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
I-"
00
NAME
PNC
TREATMENT
Controlled incineration as a
slurry w/afterburner & scrub-
bing w/dilute caustic soln.
(NaOH assumed)
r~
»
1
TOXIC
NAME
FORM
i>
5
r—
m
m
o
i— i
m
m
§
s
%
NONTOXIC
NAME
NaNO + Na2C03 +
NaOH + H20
FORM
Dilute
soln
*E
£
4
i—
m
m
X
r~
o
(/i
m
m
s
s
8
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
vo
NAME
C2H4(ON02)2
TREATMENT
Controlled incineration w/
afterburner & scrub w/dilute
caustic soln (NaOH assumed)
—i
i—
*
1
TOXIC
NAME
FORM
g
1
I—
m
m
x
o
t/>
m
m
£
NONTOXIC
NAME
NaNOx + Na2C03 +
NaOH + H?0
FORM
Dilute
soln
*E
f
c
r~
X
s
m
m
o
r"
s
Cn
8
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
H2S
Sour water
Sour gas
H-,S + Amine
H,S + H,0 or
c £.
H2S (residual) or
H?S (amine regenera-
tion)
so2
TREATMENT
Strip w/steam
Scrub w/ amine soln
Amine regeneration w/heat
Claus-Beavon Process
Scrub w/dilute caustic soln
(NaOH assumed)
— t
r—
*
1
1
2
2
2
3
>r
4
TOXIC
NAME
H2S + H20
H2S + Amine
H2S (residual)
H,S
C.
so2
£.
FORM
Gas
Soln
Gas
Gas
Gas
T1
1—
m
X
X
X
X
m
X
o
CO
m
X
X
X
X
m
O
r~
CO
S
X
X
X
X
X
NONTOXIC
NAME
H20
Amine
S
Na2SO, + NaOH +
FORM
Liquid
Soln
( Recycl e)
Solid
(Recycle)
Dilute
soln
*E
g
I—
m
X
m
X
r~
o
co
m
m
o
r"
s
£
m
r—
-n
0
S
S
CO
0
**
w
o
DC
+
•o
o
c
VI
o
ZJ
CO
o
T
-pi-
rn
o
o
m
-o
o
i
S1
M
o
ew
o
o
<
-
p
I
CD
ro
*TI
0
|
I—
ft*
^
CO
2
i
-H
r-
*»
ac
'»
0
r~
ro
CO
z
?
nr
1
i
D
^
-t>
i.
1>
0
"
j»
0
SJ
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C6H8(N03)6
TREATMENT
Controlled incineration w/
afterburner & dilute caustic
scrubber (NaOH assumed)
i
-i
r—
4
1
TOXIC
NAME
FORM
g
5
r-
m
m
x
-o
o
CO
m
m
o
r~
CO
%
NONTOXIC
NAME
NaNO + Na2C03 +
NaOH + H20
FORM
Dilute
soln
*E
~n
r"
2
m
m
X
-o
r-
o
m
m
O
r-
s
oo
^
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
ISJ
NAME
C8H1005SPN
TREATMENT
Dilute: concentrate w/acti-
vated carbon beds w/regener-
ation of carbon in furnace.
Treat products same as below.
Cone: incineration w/after-
burner & scrub w/dilute caus-
tic soln (NaOH assumed)
— <
r—
if
1
TOXIC
NAME
FORM
,
5
1—
m
m
X
v>
m
m
s
in
%
NONTOXIC
NAME
NaNOx + Na2C03 +
NaOH + H20
FORM
Dilute
soln
*E
£
4
r~
m
m
X
r—
o
m
EVOLVE
(/>
8
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. « TREATMENT LEVEL
T.L. " 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NJ
to
NAME
Ni(CO)4
Ni
TREATMENT
Carefully expose to air
Recycle (Optional)
r~
'+
1
TOXIC
NAME
FORM
-n
^
DO
i—
m
m
X
r~
0
LO
s
m
<
0
m
£
NONTOXIC
NAME
Ni
co2
FORM
Solid
Gas
E»
•J
m
X
o
m
rri
«:
o
i—
00
s
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. • 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
-P-
NS
NAME
[C6H,005(N02)x]n
Slurry
TREATMENT
Treat w/10% NaOH soln
Dilute
— 4
r~
1
2
TOXIC
NAME
NaN03 + cellulose
+ NaOH + H20
FORM
Slurry
»
i—
m
X
0
m
m
0
s
to
$
NONTOXIC
NAME
NaNO, T NaOH +
cellulose + HjO
FORM
Dilute
soln
*E
5
i—
m
X
-o
r~
m
m
0
P"
s
to
£
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
.p-
N3
Ul
NAME
[C6H1005(N02)x]n
TREATMENT
Controlled incineration w/
afterburner & scrub w/dllute
caustic soln (NaOH assumed)
r-
*
1
TOXIC
NAME
FORM
?
f
r~
m
m
X
-o
k
m
m
g
S
NONTOXIC
NAME
NaNOx + Na2C03 +
NaOH + H20
FORM
Dilute
Soln
*E
£
5
r~
m
X
•o
o
m
g
§
-------
TREATMENT PRODUCTS
*E - ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C6H12C13N
TREATMENT
Dilute: concentrate by ad-
justing PH > 7 & centrifuge.
Treat product same as below.
Cone: incineration w/after-
burner & scrub w/dilute caus-
tic soln (NaOH assumed)
i—
1
TOXIC
NAME
FORM
p
IJJ
r~
m
x
o
m
m
s
%
m
°
s
§
-------
TREATMENT PRODUCTS
*E - ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. • 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C3H5(ON02)3
TREATMENT
Controlled incineration w/
afterburner 4 scrub w/dilute
caustic soln (NaOH assumed)
—i
r*
*
1
TOXIC
NAME
FORM
g
5
m
X
TJ
O
CO
m
m
o
V*
%
NONTOXIC
NAME
NaNOx + Na2C03 +
NaOH + H20
FORM
Dilute
soln
*E
-n
2
r"
m
m
X
-o
o
m
m
°
fi
^
-------
TREATMENT PRODUCTS
*t • ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
00
NAME
C,0H4N05PS
TREATMENT
Dilute: concentrate w/acti-
vated carbon beds w/ regener-
ation of carbon in furnace.
Treat products same as below.
Cone: incineration w/after-
burner & scrub w/dilute caus-
tic soln (NaOH assumed)
—i
i—
*
1
TOXIC
NAME
FORM
-n
r~
|
m
m
X
m
m
-c
to
£
NONTOXIC
NAME
NaNOx T Na2C03 +
Na2S03 + Na3P04 +
NaOH + H20
FORM
Dilute
Soln
*E
?
p
r-
m
m
X
•o
s
m
m
£
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
10
NAME
B5H9
TREATMENT
Incineration w/aqueous scrub-
bing
r~
*
1
TOXIC
NAME
FORM
-n
i —
•^
CD
1—
m
m
X
•a
0
m
<
0
i—
t/i
£
NONTOXIC
NAME
H3B03 + H20
FORM
Dilute
Soln
*E
>
p[
m
X
13
0
s
m
<
0
i—
[/>
S
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
00
O
NAME
C(CH2N03)4
TREATMENT
Controlled incineration w/
afterburner & scrub w/dilute
caustic soln (NaOH assumed)
rj
1
TOXIC
NAME
FORM
|
r~
m
m
X
s
m
§
§
£
NONTOXIC
NAME
NaOH + H20
FORM
Dilute
soln
*E
5
r~
m
m
X
I
s
m
g
s
8
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
HC104
Soln
TREATMENT
Dilute & reduce w/S02
Treat w/ caustic & dilute
(NaOH assumed)
—i
r-
*
1
2
TfiVT C
1 UA1 L
NAME
H2S04 + HC1 +
H SO + H 0
so.
c
FORM
Soln
Gas (Re-
cycle)
-T,
>
g
2
Tl
m
x
O
en
S""
m
o
s
2
SI
X
X
NAME
Na,SOy, + Na-,SO +
NaCl + NaOH +
H~0
FORM
Dilute
soln
*E
3
1
R
r
m
^
l/l
<
m
o
0
t>
s
_^
a>
"S
o
3T
o*
o
o
CL
*o
-h
LQ
0
z
O
CO
ro
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. " 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C103F
C12+CF4+C02
TREATMENT
Reaction w/charcoal
Scrub w/dilute caustic soln
(NaOH assumed)
r-
1
2
TOXIC
NAME
C12+CF4+C02
FORM
Gas
>
r—
m
m
X
-o
r~
o
HH
m
P
3
&
X
NONTOXIC
NAME
NaOCHNa2C03+
NaOH+H20
CF4
FORM
Dilute
soln
*E
Gas
5
r~
m
m
X
•o
§
s
m
g
s
on
8
X
X
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. » TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
U)
NAME
(NO ) C H OH
TREATMENT
Controlled incineration w/
afterburner & scrub w/dilute
caustic soln (NaOH assumed)
-H
r-
*
1
TOXIC
NAME
FORM
T)
r—
4
CD
m
m
X
-o
0
m
m
o
r—
CO
%
NONTOXIC
NAME
NaNO + Na,CO,
x 23
NaOH + H,0
2
FORM
Dilute
soln
*E
•n
i
i—
m
m
X
T3
(—
0
m
m
o
r"
s
8
-------
TREATMENT PRODUCTS
*E - ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Lo
NAME
KCN
TREATMENT
Oxidation w/hypochlorite ion
(NaOCl assumed)
-H
r-
1
TOXIC
NAME
FORM
g
1—
m
m
X
o
CO
s
m
§
CO
s
NONTOXIC
NAME
C02 + N2
KC1 + NaOH +
Na2CO, + KOH + N2
+ K2C03 + NaOCl +
H20
FORM
Gas
Soln
*E
g
r~
m
m
X
-o
r"
o
<=
§
is
CO
8
X
X
-------
TREATMENT PRODUCTS
*E » ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
CH NO K
TREATMENT
Controlled incineration w/
afterburner & scrub w/dilute
caustic soln (NaOH assumed)
r*
7
1
TOXIC
NAME
FORM
p
1
J>
m
m
X
T3
<
m
rn
2
«e
"n
£
^
NONTOXIC
NAME
NaNOx + Na,,C03 +
KOH + NaOH + H20
FORM
Dilute
soln
*E
-n
I
30
T]
m
K
I
<
m
§
rn
£
D
m
>
s
33
3C
Z
o>
z
o
+
z
o>
o
C~)
0
-J
4-
s
n:
+
z
di
O
z
±
o
0
o
c
n>
(/)
0^
3
m
>
o
D
"*1
3
-n
o
2
z
D
(/t
3
O
DJ
T3
TD
^<
E
-H
fr
S
yo
2
0
3
3
5
ct
o*
3
V>
o
r\i
O
s
|
r-
j>
o*
o
rn
t/»
o
30
T3
-H
i
-H
f—
*
X
•— i
»
-n
3
>•
O
oo
I
**
:z
^
0?
7^
>
S
-a
o
«-*•
assium
0
3"
r+
3
D
3
N
-h
I
X
Of
^
S
CD
O
z
p
tJl
UJ
CTv
-------
*E • ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
TREATMENT PRODUCTS CONTAINERS.
NAME
#541
TREATMENT
Controlled Incineration w/
afterburner 4 scrub w/d1lute
caustic soln (NaOH assumed)
£
*
1
TOXIC
NAME
FORM
1
r~
m
m
r-
0
m
m
§
s
to
NONTOXIC
NAME
NaOH+H20
FORM
Dilute
soln
*E
5
r-
m
m
X
TJ
r~
1
m
1
tn
o
m
>
r*
3
£
Z
01
K5
+
z
o*
\J
8
U)
+
a;
Oi
o
+
T
\)
0
0
c
s
(/)
0
3
m
R
O
r*i
TJ
— 1
~n
o
a>
Vt
^
o
r+
&
T)
•o
Cc*
z
•— 1
-H
*— •
3>
r-
s
?
f
I
3
rf
O
3
(/>
0
J^
s
cr
j>
0*
S
c/)
o
TO
T3
-<
i
-H
r-
"»
X
'»
S
c
<:
D>
^
o-
o>
i
§
s;
m
in
v»
e
3
O
O
i
n>
-i
o
o
Ln
-^
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
to
NAME
NaCN
TREATMENT
Oxidation w/hypochlorite ion
(NaOCl assumed)
-H
1 —
*
,
TOXIC
NAME
FORM
P
J
r—
m
m
X
•o
o
m
g
CO
£
NONTOXIC
NAME
C02 4 N
NaCl + Na-CO-j *-
NaOII + tl. f
2
NaOCl > H20
FORM
Gas
Soln
*C
P
2
r~
m
X
T3
O
m
m
<;
o
s
^
X
X
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
OJ
CO
NAME
C4H8SC12
TREATMENT
Incineration w/afterburner & *
scrub w/dilute caustic soln
(NaOH assumed)
—i
i—
if
1
TOXIC
NAME
FORM
g
4
r—
m
m
X
o
s
m
o
r~
to
£
NONTOXIC
NAME
Nad+NaOH+H20
FORM
Dilute
soln
*E
5
^
r"
m
m
X
TJ
r—
0
m
m
R
S
^
s
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. " HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
00
lO
NAME
C7H506N3
TREATMENT
Controlled incineration w/
afterburner & scrub w/dilute
caustic soln (NaOH assumed)
— (
r—
*
1
TOXIC
NAME
FORM
£
|
T|
m
x
o
CO
m
m
<
o
i —
L/l
§
NONTOXIC
NAME
NaNO +Na.CO,+
X 2 3
NaOH+HpO
FORM
Dilute
soln
*E
-n
i
i —
m
m
x
•o
:D
L/>
m
m
o
r~
<
rn
§
H*
3
m
j*
3
33
IE
Qt
0
X
+
z
a
S3
O
0
LU
+
z
QJ
O
IE
+
x
\j
0
o
c
<~t
ro
v>
o
3
_.
m
2»
n
m
3
*n
1
%
fD
trt
3
0
€-»•
eu
•o
"^
*<
_
2
—4
&
-n
o
TO
2
z
o
3
|
3
r+
O
3
0
_
a*
a
CO
o
30
•o
—1
i
—i
i—
**
x
i— i
"*
s
p
r~
>
(->
•^j
re
71
0
3%
Z
*j
z
J>
^
— 1
z
-H
C3
z
O
-e»
CO
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. " 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C8H7OC1
TREATMENT
Dissolve in benzene (CgHg) S
incinerate w/afterburner &
scrub w/dilute caustic soln
(NaOH assumed)
r-
*
1
TOXIC
NAME
FORM
?
5
r-
m
m
°
S
m
§
s
to
S
NONTOXIC
NAME
NaCl + Na2C03 +
NaOH + H.O
£
FORM
Dilute
soln
*E
S
4
m
m
X
-o
1—
K
m
m
§
s
S
s?
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
C,0H6N2C1
TREATMENT
Hydrolyze w/95: ethyl alcohol
+ H^O & incinerate w/after-
burner & scrub w/dilute caus-
tic soln (NaOH assumed)
—i
r-
*
1
TOXIC
NAME
FORM
"n
i —
^
i —
m
m
X
-o
o
m
m
<
o
K
%
NONTOXIC
NAME
NaNOx + Na2C03 +
NaOH + H20
FORM
Dilute
soln
"n
^[
r"
m
m
X
-o
o
m
m
o
r—
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
-P-
.£»
to
NAME
C H ON
2 7 9
TREATMENT
Controlled Incineration w/
afterburner & scrub w/d1lute
caustic soln (NaOH assumed)
r-
1
TOXIC
NAME
FORM
Zj
r—
m
m
o
to
m
m
g
§
NONTOXIC
NAME
NaNO Na2C03 +
NaOH + H20
FORM
Dilute
soln
*E
g
I—
m
m
X
-o
o
s
m
g
s
8
-------
U3
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
TREATMENT PRODUCTS CONTAINERS.
NAME
C1]H2602SNP
TREATMENT
Incineration w/afterburner &
scrub w/dilute caustic soln
(NaOH assumed)
r—
*
1
TOXIC
NAME
FORM
£
i
s
rri
X
r~
o
rri
i
m
£
NONTOXIC
NAME
NaNO + Na-,CO, +
x 23
NaOH + H20
FORM
Dilute
soln
*E
-n
i
33
m
X
-o
r-
g
m
m
§
s
§
TI
s
yo
3
(U
Z
&
sj
o
o
-t-
01
0
I/)
O
**+
ai
c
+
Oi
o
Z
0
-t-
n>
o
m
>
o
n
m
3
-n
o
I?
!rt
3
O
&
O
— •
Z
H
S
yo
0
CO
o
5
1 —
a*
o
rn
w
o
n
—1
i
—1
'»
F
S
JO
£
n
_i
S3
7»
O
13
£
»
X
-o
0>
•*•
3
*"*"
T>
ft)
7>
/l
O
O
ro
S
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. " 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Zn(CN)2
Soln
TREATMENT
Oxidation w/hypochlorite
ion (Ca(OCl)2 assumed)
Treat w/excess Ca(OH)2
r-
*
1
2
TOXIC
NAME
ZnCl2 + CaCl2 +
Ca(OH)2 + Zn(OH)2
CaC03 + ZnC03
+ Ca(OCl)2 + N2
+ H20
FORM
Soln
?
^
m
m
X
"O
o
CO
I— 1
m
m
§
t/i
§
X
NONTOXIC
NAME
C02 + N2
Zn(OH)2 + CaCl2
+ CaCO, + ZnCO,
3 3
+ Ca(OCl)2 + N2 +
Ca(OH)2 + H20
FORM
Gas
Slurry
*E
5
J
m
m
x
•o
0
m
m
o
i—
t/>
8
X
-------
Pages 446 through 454 of Appendix B-3, Waste Treatment Procedures refer to
Table 10, CANDIDATE WASTES FOR WHICH TREATMENT WAS UNAVAILABLE OR IN-
SUFFICIENT AND REQUIRE FURTHER STUDY. (Candidates listed in alphabetical
order by name.)
445
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. " 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
TREATMENT
r-
TOXIC
NAME
FORM
FLAMMABLE
EXPLOSIVE
m
o
NONTOXIC
NAME
FORM
FLAMMABLE
EXPLOSIVE
m
o
r—
m
_
m
r-
3
£
0
O
3
i
t— «
t— t
3
3T
3
3
0
in
O
ro
0
o
J»
o«
r>
5
o
-H
f-
i— I
»
-n
o
S
0
Ol
s1
CD
>
s
O-
c
§.
O)
ff
o
o
CJ1
ro
-------
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. » TREATMENT LEVEL
T.L. " 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
TREATMENT PRODUCTS CONTAINERS.
NAME
TREATMENT
—i
i—
*
TOXIC
NAME
FORM
Tfl
i
[—
rri
n
D
l/l
5
m
m
o
r—
CO
%
NONTOXIC
NAME
FORM
-n
r*
1
i—
m
X
•o
1—
o
CO
<
m
s
2
D
rri
S
I
o
m
-n
o
z
p-
s
I
3
3
o"
3
1/1
O
ro
o
s
1
r~
o
—I
o
—i
i-
?
S
p
r-
z
o
0>
ft)
o
s
en
3
Q.
~TI
_i
3
3
D
0
S
LJ1
-------
TREATMENT PRODUCTS
*E « ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
TREATMENT
00
TOXIC
NAME
FORM
NONTOXIC
NAME
FORM
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. " 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
TREATMENT
VO
TOXIC
NAME
FORM
NONTOXIC
NAME
FORM
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
Ml. I. - HAZARD INDEX
•T.L. - TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
TREATMENT
-C-
Oi
O
TOXIC
NAME
FORM
NONTOXIC
NAME
FORM
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. « 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
TREATMENT
Ln
TOXIC
NAME
FORM
NONTOXIC
NAME
FORM
-------
TREATMENT PRODUCTS
*E " ENVIRONMENTAL RISK'
•II. I. - HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. " 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
TREATMENT
Ui
ro
TOXIC
NAME
FORM
NONTOXIC
NAME
FORM
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. » TREATMENT LEVEL
T.L. - 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Ui
CO
NAME
TREATMENT
r~
*
TOXIC
NAME
FORM
-n
1
m
m
X
-o
r~
o
to
m
m
§
n
i/>
£
NONTOXIC
NAME
FORM
g
I
t-
m
m
X
o
s
m
o
<
R
§
O
m
3
TO
3;
O
m
-o
-H
3
i
z
H
r—
3
0
tn
0
n>
ro
3
3
rt-
3
in
O
ro
s
c
^
i^
o
m
o
o
r-
*
-^
-n
o
i
p-
2:
o
rt-
CU
— '
CT
m
2
?
cn
0>
-j
ra
i?
SJ
IV
3
0>
0
z
p
Ul
*>
CD
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
TREATMENT
Ui
TOXIC
NAME
FORM
NONTOXIC
NAME
FORM
-------
Pages 456 through 464 of Appendix B-3, Waste Treatment Procedures, refer
to Table 11, CANDIDATE WASTES WHICH ARE NOT RECOMMENDED FOR UNDERGROUND
STORAGE IN ANY FORM. (Candidates listed in alphabetical order by name.)
455
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. " 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
Ui
NAME
BrF5
Br, * CF4
Br2
TREATMENT
Reaction w/charcoal
Condense in ice cooled trap
Recycle
— i
r-
»
1
2
TOXIC
NAME
Br2 + CF4
Br2
FORM
Gas
Liquid
>
£
r-
m
X
X
m
X
•o
m
m
o
i—
CO
§
X
X
NONTOXIC
NAME
CF4
FORM
Gas
g
I
m
m
X
T3
O
m
rn
R
t/l
8
X
-------
TREATMENT PRODUCTS
*E - ENVIRONMENTAL RISK
*H.I. " HAZARD INDEX
*T.L. • TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
HgClg
Slurry
Solution
Hg + H20
Hg
TREATMENT
Treat w/HgS
Incinerate ( 360°C) in pres-
ence of air, condense & scrub
w/caustic soln (NaOH assumed]
Dilute
Separate Hg
Recycle
i—
*
1
2
3
3
TOXIC
NAME
HgS + HC1 + H2S +
H20
Hg + H20
NaCl + Na2S03 +
NaOH + H20
Hg
FORM
Slurry
Liquid
Solution
Liquid
?
5
m
X
m
X
%
m
X
)
m
s
m
CO
8
X
X
X
NONTOXIC
NAME
NaCl + Na2SO, +
NaOH + H20
H20
FORM
Dilute
soln
*E
Liquid
3
j>
5
K
m
x
•o
CO
m
m
P
CO
£
-------
Oi
00
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Hg(CN)2
Slurry
Hg + H2 + H20
SI urry
Hg + H20 & Hg
TREATMENT
Oxidation w/hypochlorite ion
(NaOCl assumed)
Treat w/NaBH.
Mist eliminator
Remove Hg & dilute filtrate
Purify & recycle
—i
r-
*
1
2
3
3
4
TOXIC
NAME
HgCl, -r Hg0CO, +
C £3
HgO + Na2Co3 +
Nad + NaOH +
NaOCl + H20
Hg + H2 + H20
Na2C03 + Nad +
NaOH + Na,BO, +
Hg + H20
Hg + H20
Hg
Hg
FORM
Slurry
Gas
Slurry
Liquid
Liquid
Liquid
p
5
i—
m
X
m
X
^
o
s
X
§
m
§
X
X
X
X
X
X
NONTOXIC
NAME
CO, * N2
H2
Na2C03 + Nad +
NaOH + Na,BO, +
•J -J
2
H20
FORM
Gas
Gas
Dilute
soln
*E
Liquid
5
&
i-
m
X
m
X
•v
r—
o
m
X
m
i—
§
X
X
-------
Ln
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. " HAZARD INDEX
*T.L. " TREATMENT LEVEL
T.L. - 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Hg(NH3)2ci2
Soln
SI urry
Liquid
Soln
Hg
TREATMENT
Decompose In hot H,,0
Treat w/H2S
Incinerate & condense & scrub
w/caust1c soln
(NaOH assumed)
Separate Hg
Dilute
Recycle
— i
,
*
1
2
3
4
4
TOXIC
NAME
HgCl2 + NH4OH +
HgS + (NH4)2S +
un 4- M ^ + H n
nv» i * n«o ~ \\i\\j
Hg + H,0
z
Na,SO, + NaNO
c, J X "r
NaCl + NaOH + H20
Hg
FORM
Soln
SI urry
Liquid
Soln
Liquid
,,
>
3
DO
m
X
m
x
-a
o
s
x
m
rn
§
X
X
X
X
NONTOXIC
NAME
H20
NaNOv + Na,SO, +
x Z 3
NaCl + NaOH +
H20
FORM
Liquid
Dilute
soln
*E
§
1—
m
m
x
P?
§
m
m
<
s
§
-------
TREATMENT PRODUCTS
*E = ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. - 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Hg(ONC)2
Hg + H20
TREATMENT
Controlled incineration
w/afterburner & condense @
20°C & scrub gases w/dilute
caustic soln (NaOH assumed)
Purify & recycle
— )
if
1
2
TOXIC
NAME
Hg + H20
Hg
FORM
Liquid
Liquid
-n
i—
i~
m
m
X
r~
o
t/l
<
m
m
R
m
is>
%
X
X
NONTOXIC
NAME
NaNOy + Na2C03 +
NaOH + H20
H20
FORM
Dilute
soln
*E
Liquid
2
r—
m
rn
x
r~
0
<
m
m
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. " HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 " CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
Hg(N03)2 • H2o
Liquid
Soln
Hg
TREATMENT
Incinerate, condense & scrub
w/caustic soln. (NaOH assumed
Remove Hg
Dilute
Recycle
_,
»
1
2
2
TOXIC
NAME
Hg + H20
NaNO + NaOH +
Hg
FORM
Liquid
Soln
Liquid
,
&
£
CD
m
m
X
"w
o
m
m
o
<
LO
%
X
X
X
NONTOXIC
NAME
H 0
NaNO + NaOH +
X
H20
FORM
Liquid
Dilute
soln
*E
r"
Z
s
r~
m
m
X
o
(/I
s
m
§
r^
t/>
S
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. • HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NJ
NAME
Hgso4
Liquid
Soln
Hg
TREATMENT
Incinerate & condense & scrub
w/cajstic soln. (NaOH assumed
Remove Hg
Dilute
Recycle
_,
I~
1
2
2
TOXIC
NAME
Hg + H20
Na2SO, + NaOH +
H20
Hg
FORM
Liquid
Soln
Liquid
*
Jf
I—
m
m
X
r~
0
t/i
m
m
o
|—
m
£
X
X
NONTOX1C
NAME
H20
Na2SO, + NaOH +
2
FORM
Liquid
Dilute
soln
*E
^
m
m
X
i—
O
s
o
1—
ft
e
-------
TREATMENT PRODUCTS
*E • ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 • CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
TREATMENT
Hg
Recycle
TOXIC
NAME
FORM
NONTOXIC
NAME
FORM
-------
TREATMENT PRODUCTS
*E » ENVIRONMENTAL RISK
*H.I. - HAZARD INDEX
*T.L. - TREATMENT LEVEL
T.L. • 0 - CONTAINERIZED ONLY.
ALL OTHER LEVELS INCLUDE
CONTAINERS.
NAME
CgHg02Hg & Hg(CH3)2
Liquid
Slurry
Hg
TREATMENT
Incinerate w/afterburner &
condense & scrub w/caustic
soln. (NaOH assumed)
Remove Hg
Dilute
Recycle
r-
1
2
2
TOXIC
NAME
Hg + H20
NaNOx + Na2C03 +
Na2S03 + NaCl +
NaOCl + NaOH +
Hg
FORM
Liquid
Slurry
Liquid
£
r-
m
X
o
(/I
s
m
g
t/i
%
X
X
X
NONTOXIC
NAME
H 0
NaNO + Na,CO, +
Na2S03 + NaCl +
NaOCl + NaOH +
FORM
Liquid
Dilute
soln
5
m
m
X
r—
m
m
t—
s
%
X
-------
APPENDIX B-4
PROJECTION AND GEOGRAPHIC DISTRIBUTION OF
CANDIDATE WASTE VOLUMES
465
-------
S.I.C. code: 22
Industry: Textile mill products
ID
no.
51
83
322
376
22
345
386
379
338
253
255
Waste name
Acceptable for un-
derground storage
with no treatment
Arsenic Trioxide
Cadmium Chloride
Pentachlorophenol
Sodium Arsenate
Acceptable for un-
derground storage
after treatment
Ammonium Bichromate
Potassium Bichro-
mate
Sodium Chromate
Sodium Bichromate
Underground storage
of treatment pro-
ducts is optional
Picric Acid
Not recommended for
underground stor-
age
Mercuric Chloride
Mercuric Nitrate
Waste
gen
factor
%
incr
per yr
14.0
3.0
1.7
1.7
1.7
1.7
3.0
3.0
Volume m3 (ft3)
1975 1980 1985
8.10
(286)
270.43
(9,550)
8.78
(310)
293.36
(10,360)
9.54
(337)
321.68
(11,360)
466
-------
S.I.C. code:
22
Industry: Textile mill products
Percentage Distribution
ID
no.
345
386
379
Waste name
Acceptable for under-
ground storage after
treatment
Potassium Dichromate
Sodium Chromate
Sodium Dichromate
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
38
10
38
14
18
14
2
3
2
1
39
57
39
5
3
5
1
1
2
6
2
467
-------
S.I.C. code:
24
Industry:
Lumber and wood
Percentage Distribution
ID
no.
253
Waste name
Not recommended for
underground storage
Mercuric Chloride
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
1
3
12
6
27
14
17
4
16
468
-------
S.I.C. code:
26
Industry:
Paper and allied products
ID
no .
322
345
105
160
221
258
Waste name
Acceptable for un-
derground storage
with no treatment
Pentachlorophenol
Acceptable for un-
derground storage
after treatment
Potassium Bichro-
mate
Underground storage
of treatment pro-
ducts is optional
Chlorine
Dimethyl Sulfate
Hydrogen Sulfide
(
Not recommended for
underground stor-
age
Organic Mercury
compounds
Waste
gen
factor
1%
0.033%
330 pprn]
%
incr
per yr
3.0
1.7
6.5
3.0
3.0
3.0
3 3
Volume m (ft )
1975 1980 1985
0.16
(5.6)
0.64
(22.5)
1,293.80
(45,690)
0.18
(6.4)
0.74
(26.1)
1,499.87
(52,967)
0.21
(7.4)
0.86
(30.2)
1,738.76
(61,404)
^ /
469
-------
S.I.C. code:
26
Industry: Paper and allied products
Percentage Distribution
ID
no.
160
Waste name
Underground storage of
treatment products is
optional
Dimethyl Sulfate
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
50
50
470
-------
S.I.C. code:
2812
Industry:
Chlor-alkali industry
ID
no .
105
257
Waste name
Underground storage
of treatment pro-
ducts is optional
Chlorine
Not recommended for
underground stor-
age
Mercury
Waste
gen
factor
29%
%
incr
per yr
6.5
6.5
Volume m3 (ft3)
1975 1980 1985
40,210.12
(1.42xl06)
0.54
(19)
50,687.41
(1.79xl06
0.73
(26)
63,996.39
(2.26xl06)
1.01
(36)
471
-------
S.I.C. code:
2812
Industry: Chlor-alkali industry
Percentage Distribution
ID
no.
105
257
Waste name
Underground storage of
treatment products is
optional
Chlorine
Not recommended for
underground storage
Mercury
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
1
1
19
19
9
9
20
20
43
43
5
5
3
3
472
-------
S.I.C. code:
2819
Industry:
Industrial inorganic chemicals
ID
no.
51
83
85
86
481
21
22
36
43
50
82
84
114
128
200
343
345
386
379
480
Waste name
Acceptable for un-
derground storage
with no treatment
Arsenic Trioxide
Cadmium Chloride
Cadmium Oxide
Cadmium Phosphate
Cadmium Sulfate
Acceptable for un-
derground storage
after treatment
Ammonium Chromate
Ammonium Bichromate
Antimony Pentafluo-
ride
Antimony Trifluo-
ride
Arsenic Trichloride
Cadmium, Powdered
Cadmium Cyanide
Chromic Acid
Cuprous (Copper)
Cyanide
Fluorine
Potassium Chromate
Potassium Bichro-
mate
Sodium Chromate
Sodium Bichromate
(
Cadmium Potassium
Cyanide
Waste
gen
factor
0.05%
500 ppm!
%
incr
per yr
14.0
14.0
14.0
14.0
1.7
1.7
1.7
1.7
1.7
1.7
1.7
14.0
3 3
Volume m (ft )
1975 1980 1985
100.58
(3,552)
0.85
(30)
3,352.87
(118,405)
28.23
(997)
109.42
(3,864)
0.92
(33)
3,645.44
(128,737)
30.70
(1,084)
119.05
(4,204)
1.01
(36)
3,962.59
(139,937)
33.41
(1,180)
473
-------
S.I.C. code:
Industry:
2819
Industrial inorganic chemicals
ID
no .
61,
505
91
105
106
324
326
338
387
457
253
503
254
255
256
257
Waste name
Underground storage
of treatment pro-
ducts is optional
Boron Hydrides
Calcium Cyanide
Chlorine
Chlorine Trifluoridt
Perchloric Acid
(72%)
Perchloryl Fluoride
Picric Acid
Sodium Cyanide
Zinc Cyanide
Not recommended for
underground stor-
age
Mercuric Chloride
Mercuric Diammonium
Chloride
Mercuric Cyanide
Mercuric Nitrate
Mercuric Sulfate
Mercury
Waste
gen
factor
%
incr
per yr
6.5
3.0
3.0
3.0
3.0
3.0
3.0
Volume m3 (ft3)
1975 1980 1985
1,370.54
3
(48.4x10 )
1,730.17
•j
(61.1x10 )
2,183.24
•i
(77.1x10 )
474
-------
S.I.C. code:
2819
Industry: Industrial inorganic chemicals
Percentage Distribution
ID
no.
200
343
345
386
387
254
Waste name
Acceptable for under-
ground storage after
treatment
Fluorine
Potassium Chr ornate
Potassium Dichromate
Sodium Chromate
Underground storage of
treatment products is
optional
Sodium Cyanide
Not recommended for
underground storage
Mercuric Cyanide
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
1
19
19
15
1
10
6
6
24
10
100
16
1
1
3
16
7
1
1
24
7
15
60
60
3
15
21
10
10
11
21
15
1
1
15
15
5
1
1
5
10
1
1
5
10
475
-------
S.I.C. code:
Industry:
282
Plastics
ID
no.
8
165
253
258
Waste name
Underground storage
of treatment pro-
ducts is optional
Acrolein
Dinitrotoluene
Not recommended for
underground stor-
age
Mercuric Chloride
Organic Mercury
Compounds
Waste
gen
factor
.0015%
(15 ppm]
%
incr
per yr
3.0
3.0
Volume m3 (ft3)
1975 1980 1985
0.29
(10.2)
0.34
(11.8)
0.39
(13.7)
476
-------
9R9
S.I.C. code:
Industry: Plastics
Percentage Distribution
ID
no.
257
253
258
Waste name
Not recommended for
underground storage
Mercury
Mercuric Chloride
Organic Mercury Com-
pounds
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
5
10
5
12
21
12
10
21
10
2
16
2
40
14
40
18
7
18
10
10
10
3
2
3
477
-------
S.I.C. code:
2834 (3843)
Industry: Pharmaceutical preparations
Percentage Distribution
ID
no.
257
258
Waste name
Not recommended for
underground storage
Mercury
Organic Mercury Com-
pounds
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA. ENC WNC SA ESC WSC M W
6
6
35
35
18
18
9
9
10
10
3
3
6
6
1
1
12
12
478
-------
S.I.C. code:
2842
Industry:
Polishes and sanitation
ID
no.
135
136
137
105
Waste name
Acceptable for un-
derground storage
with no treatment
2, 4-D
DDD
DDT
Underground storage
of treatment pro-
ducts is optional
Chlorine
Waste
gen
factor
%
incr
per yr
1.0
6.5
3 3
Volume m (ft )
1975 1980 1985
685.27
(24.2xl03)
863.67
(30.5xl03)
1,090.20
(38.5xl03)
479
-------
2851
S.I.C. code: _
Indus try: Paints and allied products
ID
no.
83
85
481
490
322
21
114
128
129
345
386
379
257
258
Waste name
Acceptable for un-
derground storage
with no treatment
Cadmium Chloride
Cadmium Oxide
Cadmium Sulfate
Copper Acetoarse-
nite
Pentachlorophenol
Acceptable for un-
derground storage
after treatment
Ammonium Chroma te
Chromic Acid
Cuprous (Copper)
Cyanide
Cyanides
Potassium Dichromat<
Sodium Chromate
Sodium Bichromate
Not recommended for
underground stor-
age
Mercury
Organic Mercury
Compounds
Waste
gen
factor
3.0%
2%
.0125%
125 ppm
%
incr
per yr
14.0
14.0
14.0
3.0
1.7
1.7
1.7
1.7
1.7
1.7
3.0
I
3.0
3 3
Volume m (ft )
1975 1980 1985
0.62
(22)
99.31
(3,507)
3.31
(117)
125.67
(4,438)
0.07
(2.3)
4.98
(176)
1.20
(42.5)
108.06
(3,816)
3.60
(127)
136.72
(4,828)
0.07
(2.6)
5.61
(198)
2.32
(81.9)
117.54
(4,151)
3.94
(139)
148.74
(5,253)
0.08
(2.9)
6.37
(225)
480
-------
S.I.C. code:
2851
Industry: Paints and allied products
Percentage Distribution
ID
no.
83
85
481
21
114
129
345
386
379
257
258
Waste name
Acceptable for under-
ground storage with
no treatment
Cadmium Chloride
Cadmium Oxide
Cadmium Sulfate
Acceptable for under-
ground storage after
treatment
Ammonium Chromate
Chromic Acid
Cyanides
Potassium Dichromate
Sodium Chromate
Sodium Dichromate
Not recommended for
underground storage
Mercury
Organic Mercury Com-
pounds
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
3
3
3
3
3
3
3
3
3
3
3
23
23
23
23
23
23
23
23
23
23
23
30
30
30
30
30
30
30
30
30
30
30
6
6
6
6
6
6
6
6
6
6
6
10
10
10
10
10
10
10
10
10
10
10
4
4
4
4
4
4
4
4
4
4
4
8
8
8
8
8
8
8
8
8
8
8
1
1
1
1
1
1
1
1
1
1
1
15
15
15
15
15
15
15
15
15
15
15
481
-------
S.I.C. code:
2869
Industry:
Organic chemicals industry, NEC
ID
no .
322
21
22
36
43
114
128
287
243
345
379
Waste name
Acceptable for un-
derground storage
with no treatment
Pentachlorophenol
Acceptable for un-
derground storage
after treatment
Ammonium Chromate
Ammonium Bichromate
Antimony Pentaf luo-
ride
Antimony Trifluorid<
Chromic Acid
Cuprous (Copper)
Cyanide
GB (Nerve Gas)
Lewisite
Potassium Bichro-
mate
Sodium Bichromate
Waste
gen
factor
5%
(50,000
ppm)
%
incr
per yr
3.0
1.7
1.7
1.7
1.7
Volume m3 (ft3)
1975 1980 1985
0.10
(3.6)
0.12
(4.1)
0.14
(4.8)
482
-------
S.I.C. code: 2869
Industry: Organic chemicals industry, NEC
ID
no .
8
105
106
160
165
523
221
534
306
324
338
541
387
543
107,
422
423
288
Waste name
Underground storage
of treatment pro-
ducts is optional
Acrolein
Chlorine
Chlorine Trifluorid<=
Dimethyl Sulfate
Dinitrotoluene
Gelatinized Nitro-
cellulose (PNC)
Hydrogen Sulfide
Nitrocellulose
Nitrogen Mustard
Perchloric Acid
(72%)
Picric Acid
Smokeless Gunpowder
Sodium Cyanide
Sulfur Mustard
Tear Gas (CN)
Tear Gas (CS)
VX (Nerve Gas)
Not recommended for
underground stor-
age
66 Bromine Pentaf luo-
1 ride
253 Mercuric Chloride
257
258
Mercury
Organic Mercury
Compounds
Waste
gen
factor
%
incr
per yr
6.5
6.5
3.0
3.0
3.0
3 3
Volume m (ft )
1975 1980 1985
6,484.59
(229xl03)
0.04
(1.4)
0.23
(8.1)
8,155.29
(288xl03)
0.05
(1.9)
0.27
(9.4)
10,307.38
(364xl03)
.08
(2.6)
0.31
(10.8)
483
-------
S.I.C. code:
2869
Industry: Organic chemicals industry. NEC
Percentage Distribution
ID
no.
322
Waste name
Acceptable for under-
ground storage with
no treatment
Pentachlorophenol
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
6
20
32
11
8
8
11
1
3
484
-------
2879
S.I.C. code:
Industry Agriculture chemicals, pesticides
ID
no .
13
51
55
80
87
88
490
119
135
136
137
491
149
170
495
496
Waste name
Acceptable for un-
derground storage
with no treatment
Aldrin
Arsenic Trioxide
Benzene Hexachlo-
ride
Cacodylic Acid
Calcium Arsenate
Calcium Arsenite
Copper Acetoarse-
nite
Copper Arsenate
2, 4-D
DDD
DDT
Demeton
Dieldrin
Endrin
Guthion
Heptachlor
Waste
gen
factor
3%
(30,000
ppm)
1%
(10,000
ppm)
20%
5%
(50,000
ppm)
2.5%
(25,000
ppm)
%
incr
per yr
Volume m3 (ft3)
1975 1980 1985
3.54
(125)
0.37
(13)
4,190.91
(148xl03)
679.61
(24x-103)
13,818.69
(488xl03)
0.37
(13)
0.37
(13)
0.37
(13)
1.42
(50)
1,387.53
(49xl03)
485
-------
S.I.C. code:
2879
Industry:
Agriculture chemicals, pesticides (continued)
ID
no .
235
236
245
500
322
341
376
377
382
453
454
50
128
239
386
91
484
162
Waste name
Acceptable for un-
derground storage
with no treatment
Lead Arsenate
Lead Arsenite
Magnesium Arsenite
Manganese Arsenate
Pentachlorophenol
Potassium Arsenite
Sodium Arsenate
Sodium Arsenite
Sodium Cacodylate
Zinc Arsenate
Zinc Arsenite
Acceptable for un-
derground storage
after treatment
Arsenic Trichloride
Cuprous (Copper)
Cyanide
Lead Cyanide
Sodium Chr ornate
Underground storage
of treatment pro-
ducts is optional
Calcium Cyanide
Chlordane
Dinitro Cresols
Waste
gen
factor
1.85%
(18,500
ppm)
10%
100,000
ppm)
%
incr
per yr
3 3
Volume m (ft )
1975 1980 1985
0.75
(26.5)
5,493.50
(194xl03)
486
-------
S.I.C. code: 2879
Industry: Agriculture chemicals, pesticides (continued)
ID
no .
221
Waste name
Underground storage
of treatment pro-
ducts is optional
Hydrogen Sulfide
274 [Methyl Parathion
321 |Parathion
344
387
253
?55
257
285
Potassium Cyanide
Sodium Cyanide
Not recommended for
underground stor-
age
Mercuric Chloride
Mercuric Nitrate
Mercury
Organic Mercury
Compounds
Waste
gen
factor
5%
(50,000
ppm)
0.1%
(1,000
ppm)
%
incr
per yr
3.7
^3.7
3.7
3 3
Volume m (ft )
1975 1980 1985
3.23
(114)
15.91
(562)
23.53
(831)
3.85
(136)
19.09
(674)
28.23
(997)
4.62
(163)
22.88
(808)
33.84
(1,195)
487
-------
S.I.C. code:
2879
Industry Agriculture chemicals, pesticides
Percentage Distribution
ID
no.
13
51
55
80
87
490
135
137
491
149
170
495
496
235
263
341
377
382
454
386
Waste name
Acceptable for under-
ground storage with
no treatment
Aldrin
Arsenic Trioxide
Benzene Hexachloride
Cacodylic Acid
Calcium Arsenate
Copper Acetoarsenite
2, 4-D
DDT
Demeton
Dieldrin
Endrin
Guthion
Heptachlor
Lead Arsenate
Lead Arsenite
Potassium Arsenite
Sodium Arsenite
Sodium Cacodylate
Zinc Arsenite
Acceptable for under-
ground storage after
treatment
Sodium Chr ornate
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
12
1
12
3
1
8
12
12
12
12
12
12
3
1
1
1
1
1
15
7
15
20
2
7
13
15
15
15
15
15
15
2
7
7
7
20
7
6
14
14
14
80
8
14
12
14
14
14
14
14
14
8
14
14
14
80
14
12
7
7
7
7
7
8
7
7
7
7
7
7
7
7
7
7
7
13
14
30
14
16
30
16
14
14
14
14
14
14
17
30
30
30
30
19
6
21
6
16
21
6
6
6
6
6
6
6
17
21
21
21
21
18
9
9
9
36
9
11
9
9
9
9
9
9
35
9
9
9
9
19
5
5
5
9
5
6
5
5
5
5
5
5
8
5
5
5
5
2
18
6
18
3
6
20
18
18
18
18
18
18
3
6
6
6
6
10
488
-------
S.I.C. code: 2879
Industry: _
Agriculture chemicals, pesticides
Percentage Distribution
ID
no.
162
221
278
321
253
255
257
258
Waste name
Underground storage of
treatment products is
optional
Dinitro Cresols
Hydrogen Sulfide
Methyl Parathion
Parathion
Not recommended for
underground storage
Mercuric Chloride
Mercuric Nitrate
Mercury
Organic Mercury Com-
pounds
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
1
12
12
1
1
1
1
2
1
15
15
7
7
7
7
1
1
14
14
14
14
14
14
1
7
7
7
7
7
7
26
3
14
14
30
30
30
30
6
6
21
21
21
21
9
9
9
9
9
9
70
1
5
5
5
5
5
5
93
18
18
6
6
6
6
489
-------
S.I.C. code: 2892
Industry: Explosives
ID
no.
517
520
529
530
531
27
28
521
165
522
525
532
534
307
Waste name
Acceptable for un-
derground storage
after treatment
Copper Acetylide
Detonators and
Primers
Lead Azide
Lead 2, 4 Dinitro-
resorcinate (LDNR)
Lead Styphnate
Underground storage
of treatment pro-
ducts is optional
Ammonium Picrate,
Dry
Ammonium Picrate,
Wet
Diazodinitrophenol
(DDNP)
Dinitrotoluene
(DNT)
Dipentaerythritol
Hexanitrate
(DPEHN)
Glycol Dinitrate
Mannitol Hexanitrate
Nitrocellulose
Nitroglycerine
Waste
gen
factor
%
incr
per yr
Volume m3 (ft3)
1975 1980 1985
2.38
(84)
6.51
(230)
6.77
(239)
12.83
(453)
458.74
(16,200)
12.60
(455)
1,055.23
(37,265)
11.89
(420)
421.47
(14,884)
442.31
(15,620)
490
-------
S.I.C. code: 2892
Industry: Explosives (continued)
ID
no.
319
338
536
418
542
518
526
533
258
537
538
539
540
Waste name
Underground storage
of treatment pro-
ducts is optional
Pentaerythritol
Tetranitrate
(PETN)
Picric Acid
Potassium Dinitro-
benzfuroxan
(KDNBF)
TNT
Tetrazene
Not recommended for
underground stor-
age
Copper Chlorotetra-
zole
Gold Fulminate
Mercuric Fulminate
Organic Mercury
Compounds
Silver Acetylide
Silver Azide
Silver Styphnate
Silver Tetrazene
Waste
gen
factor
%
incr
per yr
Volume m3 (ft3)
1975 1980 1985
887.14
(31,329)
895.04
(31,608)
9.46
(334)
949.30
(33,524)
19.82
(700)
1.19
(42)
491
-------
S.I.C. code: «289_2__
Industry: Explosives
Percentage D-istr-L'hiiMnn
ID
no.
529
531
521
522
532
534
307
319
536
418
533
Waste name
Acceptable for under-
ground storage after
treatment
Lead Azide
Lead Styphnate
Underground storage of
treatment products is
optional
Diazodinitrophenol
(DDNP)
Dipentaerythritol Hexa-
nitrate
Mannitol Hexanitrate
Nitrocellulose
Nitroglycerine
Pentaerythritol Tetra-
nitrate (PETN)
Potassium Dinitrobenz-
furoxan (KDNBF)
TNT
Not recommended for
underground storage
Mercuric Fulminate
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
1
1
9
9
9
9
9
6
1
9
1
9
1
1
1
1
1
4
34
1
34
1
87
87
87
87
87
39
17
87
17
87
48
42
22
22
1
1
1
1
1
19
10
1
10
1
1
13
13
1
1
1
1
1
2
1
1
1
1
1
1
1
1
1
39
1
1
1
1
492
-------
S.I.C. code:
29
Industry:
Petroleum and petrochemical industry
ID
no.
322
343
345
386
379
221
253
Waste name
Acceptable for un-
derground storage
with no treatment
Pentachlorophenol
Acceptable for un-
derground storage
after treatment
Potassium Chromate
Potassium Bichro-
mate
Sodium Chromate
Sodium Bichromate
Underground storage
of treatment pro-
ducts is optional
Hydrogen Sulfide
Not recommended for
underground stor-
age
Mercuric Chloride
Waste
gen
factor
%
incr
per yr
Volume m (ft )
1975 1980 1985
1.12xl06
39.557x10 )
493
-------
S.I.C. code:
29
Industry* Petroleum and petrochemical industry
Percentage Distribution
ID
no.
81
50
239
120
253
Waste name
Acceptable for under-
ground storage with
no treatment
Cadmium
Acceptable for under-
ground storage after
treatment
Arsenic Trichloride
Lead Cyanide
Copper Cyanide
Not recommended for
underground storage
Mercuric Chloride
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
4
1
1
1
1
12
8
10
10
6
20
16
17
17
9
8
5
5
5
1
14
3
2
2
12
8
3
3
3
10
14
48
42
42
55
4
3
4
4
2
16
13
16
16
4
494
-------
S.I.C. code: 31
Leather tanning
Industry:
ID
no.
51
322
343
345
386
379
253
Waste name
Acceptable for un-
derground storage
with no treatment
Arsenic Trioxide
Pentachlorophenol
Acceptable for un-
derground storage
after treatment
Potassium Chromate
Potassium Bichro-
mate
Sodium Chromate
Sodium Bichromate
Not recommended for
underground stor-
age
Mercuric Chloride
Waste
gen
factor
%
incr
per yr
Volume m (ft )
1975 1980 1985
7.93
(280)
264.54
(9,342)
495
-------
S.I.C. code: 31
Industry: Leather tanning
Percentage Distribution
ID
no.
386
Waste name
Acceptable for under-
ground storage after
treatment
Sodium Chroma te
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
22
29
29
3
8
5
1
3
496
-------
S.I.C. code:
33
Industry: Primary metals
Percentage Distribution
ID
no.
51
387
257
Waste name
Acceptable for under-
ground storage with
no treatment
Arsenic Trioxide
Underground storage of
treatment products is
optional
Sodium Cyanide
Not recommended for
underground storage
Mercury
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
4
3
19
3
1
48
1
7
2
7
1
9
1
1
3
1
10
7
10
70
6
70
7
2
7
497
-------
S.I.C. code:
Indus try: Cold finishing
ID
no.
386
387
Waste name
Acceptable for un-
derground storage
after treatment
Sodium Chromate
Underground storage
of treatment pro-
ducts is optional
Sodium Cyanide
Waste
gen
factor
0.025%
(250 ppi
.00125%
(12.5
ppm)
"/
/o
incr
per yr
)
Volume m3 (ft3)
1975 1980 1985
16,367.22
(578xl03)
138.24
(A, 882)
498
-------
S.I.C. code:
Industry: Blast furnaces
ID
no .
387
Waste name
Underground storage
of treatment pro-
ducts is optional
Sodium Cyanide
Waste
gen
factor
.0045%
(45 ppm)
%
incr
per yr
Volume m (ft )
1975 1980 1985
0.07
(2.6)
499
-------
S.I.C. code: 3312
Industry: Coke plant wastes
ID
no.
387
Waste name
Underground storage
of treatment pro-
ducts is optional
Sodium Cyanide
Waste
gen
factor
.006%
(60 ppm)
%
incr
per yr
Volume m3 (ft3)
1975 1980 1985
1.33
(46.8)
500
-------
333
S.I.C. code: _
Industry: Nonferrous (Brass mill wastes)
ID
no .
379
Waste name
Acceptable for un-
derground storage
after treatment
Sodium Bichromate
(
Waste
gen
factor
1%
10,000
ppm)
%
incr
per yr
1.7
3 3
Volume m (ft )
1975 1980 1985
92.29
(3,259)
100.41
(3,546)
109.28
(3,859)
501
-------
S.I.C. code: 333
Industry Smelting and refining of metals, NEC
ID
no.
51
81
85
82
128
370
386
379
91
293
344
387
457
253
256
257
Waste name
Acceptable for un-
derground storage
with no treatment
Arsenic Trioxide
Cadmium
Cadmium Oxide
Acceptable for un-
derground storage
after treatment
Cadmium, Powdered
Cuprous (Copper)
Cyanide
Silver Cyanides
Sodium Chromate
Sodium Bichromate
Underground storage
of treatment pro-
ducts is optional
Calcium Cyanide
Nickel Carbonyl
Potassium Cyanide
Sodium Cyanide
Zinc Cyanide
Jot recommended for
underground stor-
age
Mercuric Chloride
Mercuric Sulfate
Mercury
Waste
gen
factor
%
incr
per yr
Volume m3 (ft3)
1975 1980 1985
0.04
(1.4)
4.93
(174)
502
-------
S.I.C. code: 3471
Industry: Metal plating and finishing
ID
no .
81
85
481
82
84
114
128
129
239
295
343
345
370
386
379
480
Waste name
Acceptable for un-
derground storage
with no treatment
Cadmium
Cadmium Oxide
Cadmium Sulfate
Acceptable for un-
derground storage
after treatment
Cadmium, Powdered
Cadmium Cyanide
Chromic Acid
Cuprous (Copper)
Cyanide
Cyanides
Lead Cyanide
Nickel Cyanide
Potassium Chromate
Potassium Bichro-
mate
Silver Cyanides
Sodium Chromate
Sodium Bichromate
Cadmium Potassium
Cyanide
Waste
gen
factor
2.3%
23,000
ppm)
3%
5.77%
57,700
ppm)
4.55%
45,500
ppm)
0.04%
(400
ppm)
%
incr
per yr
14
14
14
14
14
14
14
Volume m3 (ft3)
1975 1980 1985
15.86
(560)
3.20
(113)
209.35
(7,393)
322.93
(11,404)
10,763.97
(380,124)
30.50
(1,077)
6.14
(217)
402.58
(14,217)
621.77
(21,957)
20,725.10
(731,896)
58.67
(2,072)
11.84
(418)
774.16
(27,339)
1,197.17
(42,277)
39,904.41
1.409xl06)
503
-------
S.I.C. code: 3471
Industry: Metal plating and finishing
ID
no.
120
91
324
344
387
457
66
253
Waste name
Acceptable for un-
derground storage
after treatment
Copper Cyanide
Underground storage
of treatment pro-
ducts is optional
Calcium Cyanide
Perchloric Acid
(72%)
Potassium Cyanide
Sodium Cyanide
Zinc Cyanide
Not recommended for
underground stor-
age
Bromine Pentafluo-
ride
Mercuric Chloride
Waste
gen
factor
5.4%
(54,000
ppm)
5%
(50,000
ppm)
%
incr
per yr
2.9
Volume m3 (ft3)
1975 1980 1985
12.49
(441)
14.41
(509)
16.62
(587)
504
-------
S.I.C. code:
3471
Industry: Metal plating and finishing
Percentage Distribution
ID
no.
81
84
370
386
379
120
457
Waste name
Acceptable for under-
ground storage with
no treatment
Cadmium
Acceptable for under-
ground storage after
treatment
Cadmium Cyanide
Silver Cyanides
Sodium Chromate
Sodium Dichromate
Copper Cyanide
Underground storage of
treatment products is
optional
Zinc Cyanide
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
13
13
11
11
11
11
11
28
28
18
18
18
18
18
32
32
38
38
38
38
38
5
5
5
5
5
5
5
5
5
5
5
5
5
5
2
2
1
1
1
1
1
4
4
4
4
4
4
4
1
1
1
1
1
1
1
10
10
17
17
17
17
17
505
-------
S.I.C. code:
36
Industry: Battery manufacture, electronics, magnetic tape production
Percentage Distribution
ID
no.
85
22
114
257
Waste name
Acceptable for under-
ground storage with
no treatment
Cadmium Oxide
Acceptable for under-
ground storage after
treatment
Ammonium Dichromate
Chromic Acid
Not recommended for
underground storage
Mercury
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
3
17
17
14
24
33
33
34
29
16
16
17
11
12
12
4
10
8
8
5
3
2
2
2
6
6
6
3
1
4
13
6
6
17
506
-------
37
S.I.C. code: _
Industry: Aircraft plating wastes
ID
no .
129
387
Waste name
Acceptable for un-
derground storage
after treatment
Cadmium Cyanide
Underground storage
of treatment pro-
ducts is optional
Sodium Cyanide
Waste
gen
factor
1.5%
(15,000
ppm)
8.5%
(85,000
ppm)
%
incr
per yr
3 3
Volume m (ft )
1975 1980 1985
119.64
(4,225)
940.12
(33,200)
507
-------
S.I.C. code:
. 37
Industry: Aircraft plating wastes
Percentage Distribution
ID
no.
129
387
Waste name
Acceptable for under-
ground storage after
treatment
Cadmium Cyanide
Underground storage of
treatment products is
optional
Sodium Cyanide
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
12
12
16
16
12
12
9
9
6
6
1
1
10
10
2
2
32
32
508
-------
S.I.C. code:
38
Industry Professional, Scientific, and Control Instruments - Photographic
ID
no .
81
83
21
22
82
479
114
345
253
257
258
Waste name
Acceptable for un-
derground storage
with no treatment
Cadmium
Cadmium Chloride
Acceptable for un-
derground storage
after treatment
Ammonium Chr ornate
Ammonium Bichromate
Cadmium, Powdered
Cadmium Nitrate
Chromic Acid
Potassium Bichro-
mate
Not recommended for
underground stor-
age
Mercuric Chloride
Mercury
Organic Mercury
Compounds
Waste
gen
factor
%
incr
per yr
2.1
2.1
2.1
2.1
Volume m3 (ft3)
1975 1980 1985
0.91
(32.2)
0.99
(35.0)
1.10
(38.8)
509
-------
S.I.C. code:
49
Industry:
Electronic services and combined utilities
Percentage Distribution
ID
no.
50
Waste name
Acceptable for under-
ground storage after
treatment
Arsenic Trichloride
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
5
22
6
4
32
24
7
510
-------
S.I.C. code:
9711
Industry:
National security
ID
no.
81
85
135
376
423
Waste name
Acceptable for un-
derground storage
with no treatment
Cadmium
Cadmium Oxide
2,4-D
Sodium Arsenate
Underground storage
of treatment pro-
ducts is optional
Tear Gas, Irritant
(CS)
Waste
gen
factor
16%
3%
50%
45%
%
incr
per yr
3 3
Volume m (ft )
1975 1980 1985
16.37
(578)
3.79
(134)
511
-------
S.I.C. code: _2Zii
Industry: National security
Percentage Distribution
ID
no.
423
Waste name
Underground storage of
treatment products is
optional
Tear Gas, Irritant (CS)
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
14
19
2
5
25
14
21
512
-------
S.I.C. code:
Industry:
Cooling tower blowdown
ID
no .
.386
Waste name
Acceptable for un-
derground storage
after treatment
Sodium Chromate
Waste
gen
factor
%
incr
per yr
3 3
Volume m (ft )
1975 1980 1985
3,273.44
(115.6xl03)
513
-------
S. I.C. code:
Industry: Cooling tower blowdown
Percentage Distribution
ID
no.
386
Waste name
Acceptable for under-
ground storage after
treatment
Sodium Chromate
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
4
13
15
5
25
10
15
3
10
514
-------
S.I.C. code:
Industry:
Coal combustion wastes
ID
no .
51
257
Waste name
Acceptable for un-
derground storage
with no treatment
Arsenic Trioxide
Not recommended for
underground stor-
age
Mercury
Waste
gen
factor
.0008%
(8 ppm)
%
incr
per yr
3 3
Volume m (ft )
1975 1980 1985
240.69xl03
(8.5xl06)
35.79
(1,264)
515
-------
S.I.C. code:
Industry:
Coal combustion wastes
Percentage Distribution
ID
no.
51
257
Waste name
Acceptable for under-
ground storage with
no treatment
Arsenic Trioxide
Not recommended for
underground storage
Mercury
Bureau of Census region
(1) (2) (3) (4) (5) (6) (7) (8) (9)
NE MA ENC WNC SA ESC WSC M W
2
2
15
15
38
38
7
7
20
20
15
15
4
4
516
-------
S.I.C. code:
Industry:
D 0 D Storage
ID
no .
13
55
85
490
135
136
137
491
149
170
495
496
235
376
114
Waste name
Acceptable for un-
derground storage
with no treatment
Aldrin
Benzene Hexachlorid
Cadmium Oxide
Copper Acetoarsenit
2,4-D
DDD
DDT
Demeton
Dieldrin
Endrin
Guthion
Heptachlor
Lead Arsenate
Sodium Arsenate
Acceptable for un-
derground storage
after treatment
Chromic Acid
Waste
gen
factor
t
;
%
incr
per yr
3 3
Volume m (ft )
1975 1980 1985
0.31
(11)
1,418.00
(50,076)
0.01
(0.4)
0.33
(11.7)
1.35
(47.6)
1,418.00
(50,076)
35,488.72
(1,253,266)
78.15
(2,760)
0.03
(D
0.03
(D
234.44
(8,279)
18.69
(660)
0.11
(3.9)
0.33
(11.8)
517
-------
S.I.C. code:
Industry: POD Storage (continued)
ID
no.
128
520
521
165
522
287
523
529
530
531
243
532
533
307
319
Waste name
Acceptable for un-
derground storage
after treatment
Cuprous (Copper)
Cyanide
Detonators and
Primers
Diazodinitrophenal
(DDNP) (as muni-
tions)
Dinitro toluene (DNT)
(as munitions)
Dipentaerythritol
Hexanitrate (DPEHls
(as munitions)
GB (nonpersistent
Nerve Gas)
Gelatinized Nitro-
cellulose (PNC)
(as munitions)
Lead Azide
Lead 2,4 Dinitro-
resorcinate
Lead Styphnate
Lewisite
Mannitol Hexanitrate
(as munitions)
Mercuric Fulminate
(as munitions)
Nitroglycerine
(as munitions)
Pentaerythritol
Tetranitrate (PETN)
(as munitions)
Waste
gen
factor
)
%
incr
per yr
3 3
Volume m (ft )
1975 1980 1985
0.03
(1)
4,552.81
(160,780)
14,836.63
(523,948
4,552.81
(160,780)
14,558.44
(514,124)
1,694.43
(59,838)
2,325.70
(82,131)
2,408.33
(85,049)
4,304.49
(152,011)
1,673.14
(59,086)
14,298.97
(504,961)
12,993.67
(458,865)
518
-------
S.I.C. code:
Industry: POD Storage (continued)
ID
no .
338
343
345
536
370
541
386
379
418
542
525
534
91
484
Waste name
Acceptable for un-
derground storage
after treatment
Picric Acid
(as munitions)
Potassium Chromate
Potassium Bichromate
Potassium Dinitro-
benzfuroxan
(KDNBF) (as muni-
tions)
Silver Cyanides
Smokeless Gunpowder
(as munitions)
Sodium Chromate
Sodium Dichromate
TNT (as munitions)
Tetrazene (as muni-
tions)
Underground storage
of treatment pro-
ducts is optional
Glycol Dinitrate
(as munitions)
Nitrocellulose
(as munitions)
Calcium Cyanide
Chlordane
Waste
gen
factor
%
incr
per yr
3 3
Volume m (ft )
1975 1980 1985
13,109.69
(462,962)
0.03
(1.)
0.50
(17.8)
3,358.14
(118,591)
5.58
(197.)
0.09
(3.2)
13,904.24
(491,021)
7,262.17
(256,460)
15,455.67
(545,809)
13,624.49
(481,142)
0.08
(3)
0.76
(27)
519
-------
S.I.C. code:
Indus try: POD Storage (continued)
ID
no .
106
521
165
522
523
525
532
274
534
306
307
321
505
319
338
Waste name
Underground storage
of treatment pro-
ducts is optional
Chlorine Pentafluo-
ide
Diazodinitrophenol
(DDNP) (nonmuni-
tions)
Dinitrotoluene (DNT)
(nonmunitions)
Dipentaerythritol
Hexanitrate(DPEHN)
(nonmunitions )
Gelatinized Nitro-
cellulose (PDN)
(nonmunitions)
Glycol Dinitrate
(DDN) (nonmunitions
Mannitol Hexanitrate
(nonmuni t ions )
Methyl Parathion
Nitrocellulose
(nonmunitions)
Nitrogen Mustard
Nitroglycerine
(nonmunitions)
Parathion
Pentaborane
Pentaerythritol
Tetranitrate (PETN)
(nonmunitions)
Picric Acid (non-
munitions)
Waste
gen
factor
)
y
h
incr
per yr
3 3
Volume m (ft )
1975 1980 1985
0.49
(17.4)
9.12
(322)
2,750.66
(97,138)
9.12
(322)
2,699.06
(95,316)
2,889.32
(102,035)
8.61
(304)
2,695.86
(95,203)
2,525.93
(89,202)
2,650.98
(93,618)
898.61
(31,734)
145.07
(5,123)
2,429.09
(85,782)
2,450.78
(86,548)
520
-------
S.I.C. code:
Industry: POD Storage (continued)
ID
no .
344
536
541
387
543
418
107,
422
423
542
288
66
533
Waste name
Underground storage
of treatment pro-
ducts is optional
Potassium Cyanide
Potassium Dinitro-
benzf uroxan (KDNBF)
(nonmunitions)
Smokeless Gunpowder
(nonmunitions)
Sodium Cyanide
Sulfur Mustard
TNT (nonmunitions)
Tear Gas (CN)
Tear Gas, Irritant
(CS)
Tetrazene (nonmuni-
tions)
VX (Persistent
Nerve Gas)
Not recommended for
underground stor-
age
Bromine Pentafluo-
ride
Mercuric Fulminate
(nonmunitions)
Waste
gen
factor
%
incr
per yr
Volume m3 (ft3)
1975 1980 1985
6.71
(237)
0.39
(13.8)
2,599.30
(91,793)
414.02
(14,621)
413.43
(14,600)
14.55
(514)
0.36
(12.8)
3.34
(118)
521
-------
S.I.C. code:
Industry: Federal, State, and Municipal storage
ID
no.
13
51
55
87
135
136
137
491
149
170
495
496
235
484
274
321
254
Waste name
Acceptable for un-
derground storage
with no treatment
Aldrin
Arsenic Trioxide
Benzene Hexachloride
Calcium Arsenate
2,4-D
ODD
DDT
)emeton
Dieldrin
End r in
Guthion
Heptachlor
Lead Arsenate
Underground storage
of treatment pro-
ducts is optional
Chlordane
Methyl Parathion
Parathion
Not recommended for
underground stor-
age
Mercuric Cyanide
Waste
gen
factor
%
incr
per yr
3 3
Volume m (ft )
1975 1980 1985
0.14
(4.9)
1.44
(51)
0.03
(1)
4,866.98
(171,875)
46.24
(1,633)
0.03
(1)
1.02
(36)
15.38
(543)
522
-------
S.I.C. code:
Industry:
Industrial storage
ID
no .
51
80
87
88
490
119
235
236
245
500
341
382
453
454
50
61,
505
Waste name
Acceptable for un-
derground storage
with no treatment
Arsenic Trioxide
Cacodylic Acid
Calcium Arsenate
Calcium Arsenite
Copper Acetoarse-
nite
Copper Arsenate
Lead Arsenate
Lead Arsenite
Magnesium Arsenite
Manganese Arsenate
Potassium Arsenite
Sodium Cacodylate
Zinc Arsenate
Zinc Arsenite
Acceptable for un-
derground storage
after treatment
Arsenic Trichloride
Underground storage
of treatment pro-
ducts is optional
Boron Hydrides
Waste
gen
factor
%
incr
per yr
3 3
Volume m (ft )
1975 1980 1985
159.28
(5,625)
1.65
(58.4)
106.19
(3,750)
523
-------
APPENDIX C
DETECTION, MONITORING, AND CONTROL TECHNOLOGY
524
-------
CONTROL/SAMPLING SYSTEMS
Instrument or Technique
Operating Principle
Operating Range
Limitations
Reliability
Availability
Comments/Description
Filtration (fiber, paper, activated
charcoal, membranes, etc.).
Fluid flow through coarse medium de-
posites particulate load.
Submicron and larger - dependent on
type of filter, fluid load, and flow
time.
Limited quantification - poor to no
qualification size-grading.
Very good, with proper maintenance.
Many filtration systems readily avail-
able.
Filtration systems provide excellent
sampling capability and very good
control (cleaning) capability. It
is necessary to service (clean, re-
place, etc.) the filter media period-
ically for the system to function
well. Identification of particu-
lates can be made using other tech-
niques .
525
-------
CONTROL/SAMPLING SYSTEMS
Instrument or Technique Settling (dust jars, adhesives).
Operating Principle Gravitational deposition of particu-
lates (usually on a "holding" media
such as liquid or adhesive).
Operating Range Particulates commonly greater than
micron size.
Limitations Limited quantification, poor quali-
fication. In a mobile fluid size-
grading is normal.
Reliability Excellent, with proper maintenance.
Availability Many commercial and "home built"
systems.
Comments/Description Settling systems provide simple,
cheap, and limited sampling capa-
bility. Rough quantification is
possible; however, qualification
normally requires other systems.
Problems of separating participates
from "holding" material are inherent
in system.
526
-------
CONTROL/SAMPLING SYSTEMS
Instrument or Technique
Operating Principle
Operating Range
Limitations
Reliability
Availability
Comments/Description
Inertial Collectors (impactors, im-
pingers, cyclones).
Impactors - higher mass particles
lose momentum on contact with de-
flector. Centrifuges - particulates
spin-out of circular fluid flow.
Generally 0.5-50 micron size - in-
creased effectiveness using multiple
stages. Dependent on velocity:
increase velocity = decrease particle
size.
Quantifies within range. Limits
sizing by using multiple stages.
Good - high abrasion of impact sur-
faces common. Dependent on unit
complexity and maintenance procedure.
Many commercial units of several
designs and efficiencies are avail-
able.
Inertial collectors are good for con-
tinuous sampling/cleaning operations
of particulates in heavy-load fluids.
Problems of efficient recovery and
abrasion are common.
527
-------
CONTROL/SAMPLING SYSTEMS
Instrument or Technique
Operating Principle
Operating Range
Limitations
Reliability
Availability
Comments/Description
Precipitators
Electrostatic-charged particles in a
strong electric field are attracted
to poles. Thermal-airborne particles
are driven to cold substrate in a
temperature gradient environment.
All sizes - submicron ranges up to 3
or 4 micron size.
Particles must possess electrical
charge (inherent or induced) small
volume.
High efficiency (up to 98%) good
reliability with maintenance
excellent reliability of perfor-
mance.
Commercially available (several types
& sizes) .
Electrostatic precipitators are high-
ly efficient cleaning/sampling de-
vices up to moderate loads. In gen-
eral, size, efficiency, and cost rise
together. Thermal precipitators are
generally slow, low volume separators.
528
-------
PARTICULATE MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or Technique
Operating Principle
Operating Range
Limitations
Reliability
Availability
Comments/Des cription
Instrument or Technique
Operating Principle
Operating Range
Limitations
Reliability
Availability
Photometric Analyzers (visual opa-
city (Haze), particle illumination).
Light scattered by particulates is
related to mass and concentration.
0.2 micron and larger.
Quantitative analysis, rarely quali-
tative.
Very Good.
Commercial and experimental units.
Photometric analyzers are typically
quantitative detectors. Have long
distance capability using laser.
Limited qualitative analysis with
ultraviolet infrared and other fre-
quency sources. Active experimen-
tation should develop more efficient,
specific, and effective instrumen-
tation.
Tribo-electric.
"Light" emitted from heat of friction.
Unknown
Unknown
Unknown
Under development.
529
-------
PARTICIPATE MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or Technique
Operating Principle
Operating Range
Limitations
Reliability
Availability
Comments/Description
Condensation Nuclei (counters).
Particles injected into super-sat-
urated water vapor will attract and
condense the water.
Submicron and larger. Degree of
saturation controls particle size
(inversely).
Limited quantification. Intermittent
use. Qualification by other means.
Good reliability within design limits.
Commercially available.
Condensation sampling equipment is
efficient on a selective basis.
Substitution of vapor compounds
may allow specific particle capture
and research in this direction is
assumed. Additional experimentation
should provide many improvements and
increase overall usability and appli-
cations.
530
-------
PARTICULATE MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or Technique
Operating Principle
Operating Range
Limitations
Reliability
Availability
Comments/Description
Electric Mobility
Induced charge on particles will
cause conductivity change - meas-
urable.
Submicron and larger.
Quantification probable. Qualifi-
cation - probably limited.
Unknown
Under development.
Concept is sound. State of present
development and future potential
unknown.
531
-------
PARTICULATE MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or Technique
Operating Principle
Operating Range
Limitations
Reliability
Availability
Comments/Description
Acoustical Techniques.
Accelerated particles (>100 m/sec)
entering hexacavity make audible
pressure pulse.
Not well defined.
Unknown
Under development.
Concept is proven. Additional ex-
perimentation required.
532
-------
PARTICULATE MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or Technique
Operating Principle
Operating Range
Limitations
Reliability
Availability
Comments/Description
Electrometer Deflection
Particles having a natural charge
will deflect from electrometer probe
allowing measurement.
Sensitivity will depend on equipment.
Qualitative analysis of equally
charged particles is not presently
possible.
Good potential.
Experimental system in use.
May give rapid quantification and
qualification (within limitations)
of representative particulates.
Research and development continuing.
533
-------
PARTICULATE MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or Technique
Operating Principle
Applications
Limitations
Reliability
Availability
Comments
Atomic Absorption Spectrometry
The sample is converted into an atomic
vapor and the absorption of the atomic
vapor is measured at a selected wave-
length which is characteristic for
each individual element.
Specific testing for particulates
and water streams.
Not suitable for organic compounds.
Usually must be in liquid form or in
solution.
Very reliable.
Presently available from commercial
sources.
Not practical at present for auto-
mation. Some instruments are econom-
ical.
534
-------
PARTICULATE MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or Technique
Operating Principle
Applications
Limitations
Reliability
Availability
Comments
Flame Emission Spectrometry
The sample is vaporized and excited
in a flame to emit radiations that
are characteristic for each element.
Specific testing for particulates
and water streams.
Not suitable for organic compounds.
Usually must be in liquid form or
a solution.
Very reliable for alkali and alkaline
earth metals.
Presently available from commercial
sources.
Not practical at present for auto-
mation. These instruments are econom-
ical.
535
-------
PARTICULATE MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or Technique
Operating Principle
Applications
Limitations
Reliability
Availability
Comments
Emission Spectrometry
Utilizes the characteristic radiation
produced when materials are intro-
duced into thermal or electric
sources.
Specific testing for particulates
and water streams.
Not suitable for organic compounds.
Some samples may need special prep-
aration which usually does not take
very much time.
Very reliable.
Presently available from commercial
sources.
These instruments are expensive.
Ideally adaptable to computer read-
out. Can analyze over 40 elements
in a very short period.
536
-------
PARTICULATE MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or Technique
Operating Principle
Applications
Limitations
Reliability
Availability
Comments
Turbidimetry
Measurement is made of the intensity
of light transmitted through a
medium.
Testing of gas particulates and
water streams.
May not be specific.
Can note changes very quickly.
Presently available from commercial
sources.
Ideal for automation. Instruments
are economical.
537
-------
GAS MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or System
Operating Principle
Limitations
Application(s)
Reliability
Availability
Comments
Instrument or System
Operating Principle
Limitations
Application
Reliability
Availability
Comments
Colorimetric Detectors
Certain compounds react chemically
(oxidation etc) to cause a visible
color change.
Rough quantification is normal, but
lower limits are usually well-defined.
Manual single-test apparatus.
Specific testing of hazardous vapor,
particulates, and gases.
Very reliable within specified limits.
Presently available from commercial
sources.
These detectors provide excellent
periodic or emergency analysis of
a confined environment. Used in con-
junction with continuous, automated
instrumentation they can give fast
specific detection and area isolation
capability.
Glycol Detector
Certain compounds react chemically
(oxidation etc) to cause a visible
color change.
+_ 1 ppm (limit not well defined) .
Detection of glycol vapor
Experimental - good potential.
Under development for NASA.
Formaldehyde gives same color change -
other aldehydes give different colors.
538
-------
Colorimetric Dectors (continued)
Instrument or System
Operating Principle
Limitations
Application(s)
Reliability
Availability
Comments
Hydrogen Sulfide, Chlorine, Mercury
Vapor, Hydrogen Cyanide, Boron Hy-
drides, Chromic Acid, Lead.
Certain compounds react chemically
(oxidation etc) to cause a visible
color change.
Hydrogen Sulfide - 0-50 ppm - im-
mediate response.
Chlorine - 0-20 ppm - immediate re-
sponse . ,
Mercury Vapor - 0-1.0 mg/m .
Hydrogen Cyanide - 1-65 ppm.
Boron Hydrides - 1.0 ppm penta and
deca compounds.
Boron Hydrides - 3.0 ppm diborane.
Chromic Acid - 0.1-0.2 mg/M3.
Lead - 0.05-4.2 mg/M3.
Detection of each.
Excellent - Used as directed.
Commercially available.
Color Change - Magnitude allows rough
concentration analysis.
-539
-------
GAS MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or System Hydrogen Detectors
Operating Principle H~ sensitive catalyst to heat-acti-
vate thermochromic paint and cause
color change.
Limitations 0.5 to 4% in air.
Application(s) Remote or portable H£ monitoring
systems and can be adapted to other
combustible gas systems.
Reliability Good reliability within limits.
Availability Commercially available.
Comments Due to its explosive characteristics
most wastes which evolve H£ gas in
quantity could not be stored in an
underground facility. However, many
products and by-products may evolve
H£ in measurable amounts, and it is
expected that finite changes in H2
concentrations could be an important
indicator of leakage in a restricted
environment.
540
-------
GAS MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or System Microwave Spectroscopy (NASA).
Operating Principle Different gases absorb different
microwave-lengths.
Limitations (range) Only gases composed of polar molecules
can be identified - laboratory system
as developed.
Application(s) Gas analysis including mixtures and
compounds - both quantitative and
qualitative.
Reliability Very good - should improve with
more technology.
Availability System components are commercially
available.
Comments System was developed for NASA and has
proven capability. Research on duel
resonance techniques should improve
overall quality and performance.
541
-------
GAS MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or System Mass Spectroscopy (system).
Operating Principle Different ionized masses (molecules)
can be separated using deflection
fields and measured using electron
multipliers.
Limitations (range) Molecule identification scan rate
must be long enough to confirm
identification. Very low concen-
trations require longer scan times.
Application(s) Excellent qualification of elements
making up air stream. Can be used
for identifying gases and particulates.
Reliability Very good to excellent: using good
standards and techniques.
Availability Several commercial units available.
Comments Spectroscopic analysis provides ex-
cellent identification and adequate
quantification of component elements
in an airstream. The basic system
can be expanded to analyze most
(possibly all) desired elements.
542
-------
GAS MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or System
Operating Principle
Limitations (range)
Application(s)
Reliability
Availability
Comments
Cycloidal-Focusing Mass Spectrometer
(NASA).
As described with addition of vacuum
system for sampling.
Analysis of vapors in the 3 to 100
AMU range (as developed). Limited
accuracy in measuring low concen-
trations and slower response time.
Continuous sampling with very fast
response time (<1.0 sec).
Very reliable as tested.
Developed for and used by NASA.
This monitoring system as developed
for NASA is quite compact and may
provide a portable gas detection
system.
543
-------
GAS MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or System Non-magnetic Flight Mass Specrometer
(NASA).
Operating Principle Partial pressure analyzer. Ion
separation using combined radio-
frequency and direct-current field.
Limitations (range) Quantify and qualify from 2 to 600
atomic mass units (AMU). Tested to
300 AMU. Sensitivity to 10~10 torr,-
60 second scan.
Application(s) Mass no. vs partial press, identifies
chemical nature of constituents -
can be used for continuous automated
sampling.
Reliability Highly reliable up to 300 AMU. Un-
tested from 300-600 AMU.
Availability Prototype developed for NASA - Ex-
perimental .
Comments This unit has very good potential for
providing accurate continuous sample
analysis within the AMU range of
most hazardous gases or their de-
rivatives.
544
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GAS MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or System
Operating Principle
Limitations (range)
Application(s)
Reliability
Availability
Comments
Trace Gas Analysis (system).
Cryogenic airstream fractionating;
chromatograph analysis; mass spectro-
metry analysis.
System capable of identifying some
100 compounds in approximately 90
minutes. Quantify and qualify.
Lab. system for isolating and iden-
tifying compounds. Not automated,
plus requires highly skilled tech-
nicians .
Highly reliable using good laboratory
technique.
System utilizes commercial sampling
units which are all presently avail-
able.
This system is best suited to lab-
oratory analysis and might be a
worthwhile back up or check system
for on-site monitors. Individual
and unique automated and semi-automated
systems have been developed using
gas chromatographs to mass spectro-
meters to infrared spectrometers -
none commercial.
545
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GAS MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or System
Operating Principle
Limitations (range)
Application(s)
Reliability
Availability
Comments
Photoionization Source Mass Spectro-
meter.
lonization by ultraviolet light.
Slower than more common ionization
techniques, but better determination
of complex molecules. Can detect in
the 10 to 100 ppm range.
Best for accurate analysis of gas
composition - especially high
molecular weight gases.
Generally very reliable for identi-
fication of complex molecules.
Single prototype unit - experimental.
Technique is very promising for
specific gas analysis with high
qualification accuracy due to
simplified spectra.
546
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GAS MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or System
Operating Principle
Limitations (range)
Application(s)
Reliability
Availability
Comments
Contaminant Sensor (mass spectrometer).
Differential separation of airstream
using accumulator cells having dif-
ferent sorbencies.
Detection in the 0.5 to 5 ppm range
Quantification if over 100 ppm.
Range of prototype is 2-200 AMU.
Low level (concentration) detection
of hazardous gases.
Very good reliability as developed.
Components of system are available
commercially.
This system is very good for relativ-
ely fast detection of many gases with-
in an airstream and should be quite
useful in monitoring a closed or semi-
closed environment.
547
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GAS MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or Technique
Operating Principle
Applications
Limitations
Reliability
Availability
Comments
Gas Chromatography
Mixtures are separated on a suitable
column. The components are then
identified by a suitable detector.
Quantitative and qualitative analysis
of gases and liquids.
Must be vaporizable at a reasonable
temperature (<400°C). May need more
than one carrier gas, column, and
detector.
Very reliable. Needs good control
of temperature and pressure.
Presently available from commercial
sources.
Can be automated. Prices vary from
economical to moderate. Ideal for
use in conjunction with a mass spec-
trograph.
548
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GAS MONITORS
DETECTION SYSTEMS/TECHNIQUES
Instrument or System
Operating Principle
Limitations
Applications
Reliability
Availability
Comments
Specific Gas Spectrometer (NASA).
Heliarc combustion of gases pro-
duces unique light emissions. Com-
ponents of a gas mixture can be
identified using photomultipliers and
spectrometer analysis.
As developed: detects 02 and H2 in
Argon carrier to less than 5 ppm.
Used to monitor impurities in inert
welding gases.
The technique has proven reliability
as developed.
The technology is available and the
necessary components are commercially
produced.
Although limited as developed, the
technique holds excellent potential
for being expanded to monitor any,
or possibly all components of an
airstream (gaseous elements). The
addition of photomultipliers re-
sponsive to individual gas emission
lines might make a valuable air-
stream monitor.
549
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GAS AND PARTICULATE
MONITORING AND DETECTION TECHNIQUES
Instrument or Technique
Operating Principle
Applications
Limitations
Reliability
Availability
Comments
Visible Spectrometry
Certain compounds react chemically
(oxidation etc) to cause a visible
color change.
Specific monitoring and/or testing
of gas, particulates, vapor, and
water streams.
Some methods are time consuming.
There may be interferences by some
compounds.
If interferences are screened,
these instruments are reliable.
Presently available from commercial
sources.
Can be automated for the detection
of some compounds. Instruments are
economical. Very versatile.
550
-------
GAS AND PARTICULATE
MONITORING AND DETECTION TECHNIQUES
Instrument or Technique
Operating Principle
Applications
Limitations
Reliability
Availability
Comments
Ultraviolet Spectrometry
Certain compounds react chemically
to cause a change in ultraviolet
absorption. Usually 170-400
millimicrons.
Specific testing of vapor, particu-
lates, gas or water streams.
Some procedures are time consuming.
There may be interferences by some
compounds.
If the interferences are screened,
this method can be very reliable.
Presently available from commercial
sources.
Can be automated for the detection
of some compounds. Instruments are
economical and versatile.
551
-------
GAS AND PARTICULATE MONITORING AND DETECTION TECHNIQUES
Instrument or Technique
Operating Principle
Infrared Spectrometry
The study of absorption spectra of
compounds between the approximate
wavelengths of 0.8 to 1,000 microns.
Practically this study is usually
made between 2 and 50 microns.
Applications
Limitations
Reliability
Availability
Comments
Specific and general testing of vapor,
particulates, gas and liquids.
Usually better for organic compounds.
Special treatment needed if water
is present or if the material being
tested is a solid.
Usually very reliable.
Presently available from commercial
sources.
Ideal for automated monitoring of
gases. Some instruments are econo-
mical .
552
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TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1. REPORT NO.
EPA-600/2-75-040
3. RECIPIENT'S ACCESSIOf*NO.
4. TITLE AND SUBTITLE
EVALUATION OF HAZARDOUS WASTES EMPLACEMENT
IN MINED OPENINGS
5. REPORT DATE
December 1975 (Issuing Date)
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
Ronald B. Stone, Paul L. Aamodt,
Michael R. Engler, and Preston Madden
8. PERFORMING ORGANIZATION REPORT NO
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Fenix & Scisson, Inc.
P. 0. Box 15609
Tulsa, Oklahoma 74115
10. PROGRAM ELEMENT NO.
1DB063 (ROAP 24ALL, Task 15)
11. CONTRACT/ER34NX NO.
68-03-0470
12. SPONSORING AGENCY NAME AND ADDRESS
Municipal Environmental Research Laboratory
Office of Research and Development
U.S. Environmental Protection Agency
Cincinnati, Ohio 45268
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA-ORD
15. SUPPLEMENTARY NOTES
Project Officer: Carlton C. Wiles 513/684-4484
16. ABSTRACT
This study assesses the technical feasibility of storing nonradioactive
hazardous wastes in underground mined openings. The results show that a majority
of the wastes considered can be stored underground in an environmentally acceptable
manner if they are properly treated and containerized. Various mine environments
in the United States are applicable for such storage; room and pillar mines in salt,
potash, and gypsum appear to be the most favorable. Although the underground
storage and management of hazardous waste is both technically feasible and environ-
mentally sound, further and more detailed research, including an economic evaluation,
is recommended.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS
c. COSATI Field/Group
Underground storage
^Hazardous materials
Wastes
Waste disposal
Nonradioactive hazardous
wastes
Underground environments
storage
*Technical assessment
*Environmental assessment
13B
18. DISTRIBUTION STATEMENT
RELEASE TO PUBLIC
19. SECURITY CLASS (ThisReport)
UNCLASSIFIED
21. NO. OF PAGES
565
20. SECURITY CLASS (Thispage)
UNCLASSIFIED
22. PRICE
EPA Form 2220-1 (9-73)
553
ftUSGPO: 1976 — 657-695/5365 Region 5-11
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