United States Environmental Protection Agency Office of Water Regulations and Standards Washington, DC 20460 September 1980 Water <&EPA Phosphorus Water Quality Standards Criteria Summaries A Compilation of State/Federal Criteria ------- PHOSPHORUS Water Quality Standards Criteria Summaries A Compilation of State/Federal Criteria September 1980 U. S. Environmental Protection Agency Office of Water Regulations and Standards Washington, D. C. 20460 ------- NATIONAL SUMMARY OF STATE WATER QUALITY STANDARDS PHOSPHORUS SEPTEMBER, 1980 PREPARED FOR UNITED STATES ENVIRONMENTAL PROTECTION AGENCY CRITERIA AND STANDARDS DIVISION 401 M STREET, S. W. WASHINGTON, D. C. 20460 PREPARED BY NALESNIK ASSOCIATES INCORPORATED 505 ELEVENTH STREET, S. E. WASHINGTON, D. C. 20003 Contract Number 68-01-6058 Project Number WA-80-A055 ------- INTRODUCTION This digest is compiled to provide general information to the public as well as to Federal, State, and local officials. It contains excerpts from the individual Federal-State water quality standards establishing pollutant specific criteria for interstate surface waters. The water quality standards program is implemented by the U. S. Environmental Protection Agency where responsibility for providing water quality recommendations, approving State-adopted standards for interstate waters, evaluating adherence to the standards, and overseeing enforcement of standards compliance, has been mandated by Congress. Standards, a nationwide strategy for surface water quality management, contain three major elements: the use (recreation, drinking water, fish and wildlife propagation, industrial, or agricultural) to be made of the navigable water; criteria to protect these uses; and an antidegradation statement to protect existing high quality waters, from degradation by the addition of pollutants. Water quality criteria (numerical or narrative specifications) for physical, chemical, temperature, and biological constituents are stated in the July 1976 U. S. Environmental Protection Agency publication Quality Criteria for Water (QCW), available from the Government Printing Office, Washington, D. C. The 1976 QCW, commonly referred to as the "Red Book," is the most current compilation of scientific information used by the Agency as a basis for assessing water quality. This publication is subject to periodic updating and revisions in light of new scientific and technical information. Criteria for phosphorus in State water quality standards are the subject of this digest. Phosphorus criteria for water are established to provide a threshold level which when exceeded would most likely result in aquatic life toxicity, due to elemental phosphorus, and excessive aquatic plant growth, caused by phosphate phosphorus which is an essential plant nutrient. Phosphorus and phosphates usually enter a waterbody from land runoff, human and animal excretia, decaying vegetation, and industrial processes and detergents. Once combined with other nutrients in a waterbody, their removal becomes tedious and expensive. The 1976 Quality Criteria for Water recommends a phosphorus criterion of: 0.10 ug/1 yellow (elemental) phosphorus for marine and estuarine waters. There is no freshwater criterion. Since water quality standards experience revisions and upgrading from time to time, following procedures set forth in the Clean Water Act, individual entries in this digest may be superseded. As these revisions are accomplished and allowing for the States to revise their standards accordingly, this digest will be updated and ------- reissued. Because this publication is not intended for use other than as a general information resource, to obtain the latest information and for special purposes and applications, the reader needs to refer to the current approved water quality standards. These can be obtained from the State water pollution control agencies or the EPA or Regional Offices. Individual State-adopted criteria follow: ii ------- REFERENCES A California Water Quality Standards by River Basins, c.a. 1975 For more detailed information on selected basins, sub-basins and stretches of streams and coastal areas refer to California State Water Quality Standards. p Delaware Water Quality Standards, March 25, 1979 Idaho Water Quality Standards, c.a. September, 1979 Missouri Water Quality Standards, c.a. February, 1978 E American Samoa Water Quality Standards, Revised July, 1973 Territory of Guam Water Quality Standards, Sept. 1975 Trust Territory of the Pacific Islands Water Quality Standards, October 21, 1973 H Virgin Islands Water Quality Standards, Aug. 1973 ENVIRONMENT REPORTER, The Bureau of National Affairs, Inc. Washington, D. C. 20037 1 Pages 701:0501-0509, February 16, 1979 2 Pages 706:1004-1008, July 20, 1979 3 Pages 711:0542-0544, August 5, 1977 4 Pages 716:0603, March 26, 1976 5 Pages 726:1005, 1011-1013, March 7, 1980 Basic Water Quality Standards adopted May 22, 1979, have not yet been submitted to EPA for formal approval. 6 Pages 731:1002-1009, September 8, 1978 7 Pages 746:1008-1014, October 19, 1979 8 Pages 751:0504-0505, January 25, 1980 9 Pages 765:0512-0515, January 30, 1976 10 Page 761:0503-0504, 1973 iii ------- 11 Page 766:0504-0509, October 5, 1979 12 Pages 771:0502-0504, September 29, 1978 13 Pages 776:0504-0506, April 10, 1979 14 Pages 781:0501-0502, May 18, 1979 15 Pages 786:0501-0502, August 29, 1975 16 Page 791:0583, May 26, 1978 17 Pages 796:0103-0108, February 16, 1979 18 Pages 801:1001-1002, Sept. 29, 1978 10 Page 806:1003, March 30, 1979 ?n Page 811:1043, 1974 21 Pages 816:0602-0607, 0642-0648, 1974 99 Pages 821:0502-0505, June 30, 1978 oq Pages 831:0501-0510, February 21, 1975 94 Page 836:0502, June 30, 1978 oc Pages 841:0507-0537, December 7, 1979 9fi Pages 846:0501-0508, November 17, 1978 97 Pages 851:1001-1023, December 15, 1978 98 Pages 856:1001-1002, July 18, 1978 9Q Pages 861:1002-1007, August 11, 1979 on Pages 866:1004-1009, December 28, 1979 31 Pages 871:0501-0506, November 25, 1977 19 Pages 876:1001-1043, May 26, 1978 00 Pages 881:1001-1007, September 21, 1979 id Pages 886:0513-0524, August 29, 1975 OK Pages 891:1001-1129, November 16, 1979 IV ------- 36 Pages 901:0501-0505, November 3, 1978 VI Pages 906:0501-0506, October 13, 1978 OQ Pages 911:0501-0507, June 22, 1979 on Pages 916:0541-0544, April 14, 1978 40 Pages 921:1001-1003, August 13, 1976 41 Pages 926:0541-0563, January 26, 1979 49 Pages 931:0501-0508, May 26, 1978 A") Pages 936:1001-1003, June 27, 1975 44 Pages 941:1001-1005, May 26, 1978 45 Pages 946:0501-0520, July 14, 1978 46 Pages 951:1002-1003, April 28, 1978 47 Pages 956:1001-1007, January 11, 1980 48 Page 741:1002, November 23, 1979 4Q Pages 896:0301-0310, March 31, 1978 ------- PHOSPHORUS State Alabama Alaska Criteria Value in mg/1 Not specified Not specified Designated Stream Use All All Arizona1 The mean annual total phosphate concen- trations of the following waters shall not exceed the values given below nor shall the total phosphate or total nitrate con- centrations of more than 10 percent of the samples in any year exceed the 90 percent values given below. Unless other- wise specified, indicated values also apply to tributaries to the named waters. Total phosphates as PO.mg/1 0.04 Mean annual 0.06 90 pet-value Colorado River from Utah border to Willow Beach (main stem) 0.06 Mean annual 0.10 90 pet-value 0.08 Mean annual 0.12 90 pet-value 0.10 Mean annual 0.15 90 pet-value 0.50 Mean annual 0.80 90 pet-value 0.30 Mean annual 0.50 90 pet-value Colorado River from Willow Beach to Parker Dam (main stem) Colorado River from Parker Dam to Imperial Dam (main stem) Colorado River from Imperial Dam to Morelos Dam (main stem) Gila River from New Mexico border to San Carlos Reservoir (exclud- ing San Carlos Reservoir) Gila River from San Carlos Reservoir to Ashurst Hayden Dam (including San Carlos Reservoir) -1— ------- State Arizona (con't) Criteria Value 0.30 Annual mean 0.50 90 pet-value 0.20 Annual mean 0.30 90 pet-value 0.20 Mean annual 0.30 90 pet-value 0.50 Mean annual 0.80 90 pet-value 0.30 Mean annual 0.50 90 pet-value Designated Stream Use San Pedro River Verde River Granite Creek) (except Salt River above Roosevelt Lake Santa Cruz River from international boundary near Nogales to Sahuarita Little Colorado River above Lyman Reservoir Arkansas The above standards are intended to protect the beneficial uses of the named waters. Because regulation of nitrates and phosphates alone may not be adequate to protect waters from eutrophication, no substance shall be added to any surface water which produces aquatic growth to the extent that such growths create a public nuisance or interferrence with beneficial uses of the water defined and designated in Reg. 6-2-65. Federally promulgated in June, 1976. The naturally occurring nitrogen/phos- phorus ratio shall not be significantly altered due to municipal, industrial, agri- cultural or other waste discharges, nor shall total phosphorus exceed 100 ug/1 in streams or 50 ug/1 in lakes and reservoirs due to any such discharges. All A California Concentration not to be exceeded: (Total Phosphorus) 0.2 mg/1 0.1 mg/1 0.05 mg/1 Marine habitat, warm freshwater habitat (Basin 3) Cold freshwater habitat, fish spawning (Basin 3) Water contact recreation or non-contact water recreation (Basin 3) -2- ------- State Colorado1 Criteria Value Not specified Designated Stream Use • All Connecticut Delaware 7 Florida B None other than of natural origin There shall be no point source discharge into any natural lake or pond or tributary surface waters which will raise the phos- phorus concentration, of the receiving surface waters, including phosphorus con- tained in suspended matter to an amount in excess of 0.03 mg/1. Not specified O.OOOl(Elemental) Drinking water supply Recreation, agricultural, industrial, fish, and wild- life habitat AU Shellfish harvesting recreation, fish and wildlife Georgia 9 Hawaii Not specified Total phosphorus, not greater than 0.020 mg/1 Not greater than 0.025 mg/1 Not greater than 0.030 mg/1 Not greater than 0.20 mg/1 except not greater than 0.05 mg/1 for waters entering lakes or reservoirs. AU Class AA Class A Class B Classes 1 and 2 Idaho 10 Not specified AU Illinois11 After December 31, 1983, phosphorus as P shaU not exceed 0.05 mg/1 in any reser- voir or lake with a surface area of 20 acres or more, or in any stream at the point where it enters any such reservoir or lake. For the purposes of this Rule (203C) the term 'reservoir or lake' shaU not include low level pools constructed in free flowing streams or any body of water which is an integral part of an operation AU, except Lake Michigan -3- ------- State Criteria Value Designated Stream Use Illinois (con't) which includes the application of sludge on land. Point source discharges which comply with Rule 407 of this Chapter shall be in compliance with this Rule 203(c) for purposes of the application of Rule 402 of this chapter. 0.007 All Lake Michigan Indiana 12 0.03 mg/1 monthly average 0.04 mg/1 daily average 0.1 mg/1 Maximum value, except in waters flowing westward into Illinois. Inner Harbor Gary Harbor, Burns Harbor, and Lake Michigan Grand Calument River and Indiana Harbor Ship Canal 13 Iowa Kansas 14 Kentucky 15 0.04 mg/1 (total phosphorus) Free from substances attributable to municipal, industrial, agricultural or other sources in concentrations or combinations which will cause or contribute to the growth of aquatic plants or algae in such degree as to create a nuisance, be unsightly or deleterious, or be harmful to salmonid fishes or the natural biota. Not specified Not specified Not specified Wolf Lake and Wolf Lake Channel Natural spawning, rearing or imprinting areas, and migration route for Salmonid Fishes. All All All Louisiana 16 Not specified Nutrients: The naturally occurring nit- rogen-phosphorous ratio shall be main- tained. On completion of detailed studies on the naturally occurring levels of the varies macro and micro nutrients the state will establish numerical limits on nutrients where possible. All All -4- ------- State Maine 17 Maryland 18 Criteria Value Total phosphorus shall not exceed 15 parts per billion The total phosphorus concentration shall not exceed 50 parts per billion at measured in samples taken at or near the surface of the water. The state recognizes that certain waters of the State are eutrophic or are approaching eutrophic conditions. All dis- charges to waters which are eutrophic or potentially eutrophic, when so identified by the State, shall be treated as necessary to reduce eutrophic effects. The State shall require that wastewaters, containing nutrients which cause or may cause eutro- phication be given advanced waste treat- ment prior to discharge, or be disposed of by spray irrigation on land, or by other practicable procedures which will avoid direct discharge to surface waters. Designated Stream Use GP-A GP-B Massachusetts 19 The discharge of nutrients, primarily phosphorus or nitrogen, to waters of the Commonwealth will be limited or prohi- bited by the Division as necessary to prevent excessive eutrophication of such waters. There shall be no new or increased discharges of nutrients into lakes and ponds, or tributaries thereto. Existing discharges containing nutrients which encourage eutrophication or growth of weeds or algae shall be treated. Acti- vities which may result in non-point dis- charges of nutrients shall be conducted in accordance with the best management practices reasonably determined by the Division to be necessary to preclude or minimize such discharges of nutrients. AU Michigan 20 1.0 (monthly average effluent concen- tration goal) AU Minnesota 21 The standards provide for an effluent limit of 1.0 mg/1 where the effluent affects a lake or reservoir. AU -5- ------- State 22 Mississippi Missouri -D Montana 23 Nebraska Nevada 24 Criteria Value Not specified Not specified Not specified Not specified Total phosphate shall not exceed 0.15 in any stream at the point where it enters any reservoir or lake, nor 0.075 in any reservoir or lake, nor 0.30 in streams and other flowing waters. Designated Stream Use All AU All AU Drinking water supply with treatment by disinfection only suitable for aquatic life habitat, wildlife propa- gation, agricultural use, recreation, boating and esthetics. Total phosphates shall not exceed 0.3 Total phosphates shall not exceed 1.0 See Nevada State Water Quality Criteria Compilation 1979, for specific stretches of stream. Drinking water supply with treatment by disinfection and filtration only, for agricultural use, aquatic life and wildlife propa- gation, recreation, indus- trial supply and esthetics Domestic water supply following complete treat- ment, agricultural use, aquatic life, wildlife pro- pagation, recreation, and industrial supply 2fi New Hampshire None, except as naturally occurs None in such concentrations (generally less than 0.015 ppm) that would impair any usages assigned to this class unless naturally occurring Water supply (after disin- fection) All, except water supply (after disinfection) -6- ------- State New Hampshire (con't) Criteria Value There shall be no phosphorus in such con- centrations that would impair any usages assigned to the specific class involved. Where treatment to remove phosphorus is required under this regulation such treat- ment shall remove phosphorus to the maximum extent technically feasible. In all lakes and ponds: There shall be no new point discharge of wastewater containing phosphorus. In addition there shall be no new discharge of wastewater containing phosphorus to tributaries of lakes or ponds that would encourage eutrophication or growth of weeds or algae in such lakes and ponds. Any point discharge of wastewater existing as of the date of adoption of these rules and regulations and containing phosphates in concentrations which encourage eutrophication or growth of weeds or algae, shall be treated to remove such phos phates to the maximum extent technically feasible. The preceding shall not apply to any con- dition due to natural causes. Designated Stream Use All All AU New Jersey 27 Phosphorus as total P shall not exceed 50 ug/1 in any reservoir, lake, pond or in a tributary at the point where it enters such bodies of water, unless it can be demonstrated that total P is not a limiting factor considering the morpho- logical, physical, chemical and other characteristics of the water body. Phosphorus at total P shall not exceed 50 mg/1 in any reservoir, lake, pond or in a tributary at the point where it enters such bodies of water, unless it can be demonstrated that total P is not a limiting factor considering the morpho- logical, physical, chemical and other characteristics of the water body. 0.7 Fresh, non-tidal designated for public water supply, biota, recreation, indus- trial, agricultural, and any other reasonable use. Fresh, non-tidal designated for natural biota, recrea- tion, industrial, agricul- tural, and any other reasonable use. All uses in central Pine Barrens -7- ------- State New Mexico 99 New Yorkzy 28 Criteria Value Not specified Concentration should be limited to the extent necessary to prevent nuisance growths of algae, weeds and slimes that are or may become injurious to any bene- ficial water use. Designated Stream Use All . All uses of International boundary waters North Carolina 30 0.0001 (Elemental) All North Dakota 31 0.1 - 0.2 depending upon type of drinking water treatment process utilized 0.025 (goal) All All lake uses Ohio32 Total phosphorus as P shall be limited to the extent necessary to prevent nuisance growths of algae, weeds, and slimes that result in a violation of the water quality standards set forth in Chapter 3745-1 of the Ohio Administrative Code. In areas where such nuisance growths exist, phos- phorus discharges from point sources determined significant by the Ohio Environmental Protection Agency shall not exceed a daily average of one mill- gram per liter as total P, or such stricter requirements as may be imposed by Ohio EPA in accordance with the International Joint Commission (US-Canada agreement) Warmwater habitat, excep- tional warm water habitat, seasonal warm water habi- tat, limited warm water habitat (with specific exceptions), cold water habitat, and Lake Erie. Oklahoma 33 Not specified The total phosphorus concentration and the nitrogen/phosphorous concentration ratio shall be limited to present eutrophi- cation problems. Where historical data on nitrogen and phosphorus does not exist, sample points upstream of the point of discharge shall be used to calculate the natural nitro- gen/phosphorus concentration ratio. The application of this standard shall be determined on a case by case basis. Compliance with this standard shall be determined at the end of the mixing zone. All All -8- ------- State. 34 Oregon 35 Pennsylvania Rhode Island 36 VJ South Carolina South Dakota 39 Tennessee Texas40 Utah41 38 Vermont 42 Criteria Value Not specified P, 0.03 P* 0.10 Pg 0.13 None in such concentration that would impair any usages specifically assigned to said Class. New discharges of wastes containing phosphates will not be permitted into or immediately upstream of lakes or ponds. Phosphates shall be removed from existing discharges to the extent that such removal is or may become technically and reasonably feasible. Not specified Not specified Not specified Not specified 0.05 0.025 There shall be no discharge of wastes to Class A waters that do not meet or exceed the technical and other require- ments for such waters nor shall there be any discharge of wastes containing any form of nutrients which would encourage - eutrophication or growth of weeds or algae. Designated Stream Use All See Drainage Lists A through E of Pennsylvania Water Quality Standards for applicable uses and streams AU All All AU All Recreation, aesthetics, aquatic life All uses in lakes and reservoirs All -9- ------- State Criteria Value Designated Stream Use Vermont (con't) There shall be no new or increased dis- charge of wastes after May 27, 1971 containing any form of nutrients which would encourage eutrophication or growth of weeds and algae in any lake, pond or reservoir. Any discharge of wastes existing prior to May 27, 1971 containing soluble or other nutrients which would encourage eutrophication or growth of weeds and algae in any lake, pond, or reservoir shall receive the highest practical degree of treatment currently available to remove such nutrients. ,,. . . 43 Virginia In impounded waters, the total phosphate as phosphorus (P) should not exceed 50 ug/1 in any stream where it enters a lake or reservoir nor 25/ug/l within the lake or reservoir. Class I, H, HI, IV, V, and VI waters Washington 44 46 Wisconsin Wyoming 47 Not specified 45 West Virginia Not specified Not specified Not specified All All All All American Samoa Not specified The naturally occurring atomic ratio of NO3-N to PO.-P in a body of water will be maintained. Similarly, the ratio of inorganic phosphorus (orthophosphate) to total phosphorus (the sum of inorganic phosphorus, dissolved organic phosphorus, and particulate (phosphorus) will be main- tained in the ratio and amount as it occurs in the receiving waters naturally. All Recreation, aquatic life District of Columbia 48 Not specified All -10- ------- State Guam Puerto Rico 49 Virgin Islands H Criteria Value Total phosphorus shall not exceed 0.025 mg/1 Total phosphorus shall not exceed 0.05 mg/1 Total phosphorus shall not exceed 0.10 mg/1 0.025 Trust Territories6 0.025 The naturally occurring ratio of the con- centrations of nitrogen to phosphorus will be maintained in all waters. 0.050 Designated Stream Use AA A, 2b, I, 2b, n, C 2a-I, 2a-n All fresh water uses and preservation of coastal water natural phenomena Drinking water supply All All except preservation of natural phenomena »H.S. GOVERNMENT PRINTING OFFICE: 1980- 341-082/108 -11- ------- |