EPA-600/2-76-036d February 1976 Environmental Protection Technology Series DESIGN AND OPERATING PARAMETERS FOR EMISSION CONTROL STUDIES: Kennecott, Hurley, Copper Smelter Industrial Environmental Research Laboratu.. Office of Research and Development U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 ------- RESEARCH REPORTING SERIES Research reports of the Office of Research and Development, U.S. Environmental Protection Agency, have been grouped into five series. These five broad categories were established to facilitate "urther development and application of environmental technology. Elimination OT traditional grouping was consciously planned to foster technology transfer and a maximum interface in related fields. The five series are: 1. Environmental Health Effects Research 2. Environmental Protection Technology 3. Ecological Research v V ; 4. Environmental Monitoring : 5. Socioeconomic Environmental Studies ..,.., This report has been assigned to the ENVIRONMENTAL PROTECTION TECHNOLOGY series. This series describes research performed to develop and demonstrate instrumentation, equipment, and methodology to repair or prevent environmental degradation from point and non-point sources of pollution. This work provides the new or improved technology required for the control and treatment of pollution sources to meet environmental quality standards. EPA REVIEW NOTICE This report has been reviewed by the U.S. Environmental Protection Agency, and approved for publication. Approval does not signify that the contents necessarily reflect the views and policy of the Agency, nor does mention of trade names or commercial products constitute endorsement or recommendation for use. This document is available to the public through the National Technical Informa- tion Service, Springfield, Virginia 22161. ------- EPA-600/2-76-036d February 1976 DESIGN AND OPERATING PARAMETERS FOR EMISSION CONTROL STUDIES: KENNECOTT, HURLEY, COPPER SMELTEfl by I. J. Welsenberg and J. C. Serne Pacific Environmental Services, Inc. 1930 14th Street Santa Monica, California 90404 Contract No. 68-02-1405, Task 5 ROAP No. 21ADC-061 Program Element No. 1AB013 EPA Project Officer: R. D. Rovang Industrial Environmental Research Laboratory Office of Energy, Minerals, and Industry Research Triangle Park, NC 27711 Prepared for U.S. ENVIRONMENTAL PROTECTION AGENCY Office of Research and Development Washington, DC 20460 ------- TABLE OF CONTENTS A. INTRODUCTION AND SUMMARY 1 B. PLANT LOCATION, ACCESS AND OVERALL GENERAL ARRANGEMENT . 1 C. PROCESS DESCRIPTION .... 5 D. EMITTING EQUIPMENT 7 a. Reverberatory Furnaces 7 b. Converters . 7 c. Other Emitting Equipment 9 E. EXISTING CONTROL EQUIPMENT 9 F. GAS SYSTEM DUCTWORK 10 G. SULFUR BALANCE AND GAS COMPOSITION AT SYSTEM EXIT ... 10 H. GAS CHARACTERISTIC VARIATION 19 I. STACK DESCRIPTION 20 J. PRESENT TECHNIQUE FOR SOLID WASTE HANDLING 20 K. FOOTING AND STRUCTURAL REQUIREMENTS 20 L. EXISTING AND POTENTIALLY AVAILABLE UTILITIES 21 M. POTENTIAL NEW CONTROL EQUIPMENT INSTALLATION PROBLEMS. . 21 REFERENCES 22 ------- LIST OF FIGURES Page 1. LAND CONTOUR MAP OF SMELTER AREA 2 2. OVERALL SMELTER GENERAL ARRANGEMENT 3 3. GENERAL SMELTER LAYOUT 4 4. PROCESS FLOW SHEET 6 5. REVERBERATORY FURNACE GAS SYSTEM DUCTWORK 11 6. FLUE NO. 3 12 7. CONVERTER GAS SYSTEM DUCTWORK 13 LIST OF TABLES I. REVERBERATORY FURNACE DATA ..... 8 II. EMISSION SOURCE, CONTROL EQUIPMENT, CONTAMINANT AND EMITTED QUANTITY 15 III. EMISSIONS 16 11 ------- A. INTRODUCTION AND SUMMARY The purpose of this report is to present background design data on the Kennecott Copper Corporation, Chino Mines Division Smelter at Hurley, New Mexico in sufficient detail to allow air pollution control system engineering studies to be conducted. These studies are primarily concerned with lean SO- streams that are currently not being captured. Physical layout of the smelter and surrounding area along with existing smelter and control equipment is presented. Ductwork that would be considered for future system tie-in is defined. Emissions from operating equipment, gas flow rates, temperatures, sulfur balance and process flow sheet are included. Utilities, stack dimensions, footing requirements, and solid waste handling are defined. Available area for new control equipment, gas characteristic variation and potential new control equipment installation problems are discussed. The major uncontrolled source of SO- and particulate at this smelter is the reverberatory furnace with approximately 88,330 tons per year of SO and 6,833 tons per year of particulate emitted (Ref.l). There appears to be sufficient space and utility availability to install additional control equipment. B. PLANT LOCATION, ACCESS AND OVERALL GENERAL ARRANGEMENT The Kennecott Copper Corporation Smelter is located adjacent to the town of Hurley, New Mexico. A portion of the USGS map, showing land contours of the immediate area, is presented in Figure 1. Design altitude for the plan is 5,700 ft. with latitude 32°41' and longitude 108°07' Overall plant and smelter general arrangement are shown in the drawings, Figures 2 and 3. The primary particulate emission sources are the crushing and screening operations and the reverberatory furnaces and converters. The primary sources of sulfur dioxide are the reverberatory furnaces and the converters. Ore source is from the local Kennecott open pit mine and is primarily in sulfide form. -1- ------- ------- b^ V*« SAFETY 3pTfrrr3:OFFicE __. rfjtSUSJssJl^ KCNNECOTT COPPER CORPORATION T A L MINING. DIVISION CHINO MINES DIVISION HURUEY, NEW MEXICO a80*3 ------- . --- / V "'vjs-"->«* ,' '>--iW» v I \ CO M.C_E jl_T^_*J_£ ft F L.u_? | ..'.^'^ g. «i»'*rt» EI- r?T x-vfrtai? IP oo ^^ "^ i cVilcTllH £nit» cjBctlS! ^-Xj (»//ftr?J»7I Figure 3 KENNECOtT COPPER CORP. S DIVISION,1 * GENERAL SMELTER L'AYOOt ' y v-' ' n y-y' ^--: r ------- The smelter portion of the plant consists of the initial ore handling and mixing equipment, rotary dryer, two reverberatory furnaces, four Peirce- Smith converters, a fire refining furnace, a rotary lime kiln, and three holding furnaces. The pollution control equipment consists of multi-cyclones, rotoclones and cyclones for the crushing and screening operations and the lime kiln. Part (.40%) of the gases leaving the reverberatory furnace pass through a precipitator for particulate control. The gases from the converters are passed to a double contact sulfuric acid plant to control the SCL and are conditioned before entering this plant by passing through precipitators and scrubbers for particulate and temperature control. Figure 2, showing overall plant site, indicates space for new control equipment could be found adjacent to the acid plant on the slag dump. Considerable additional area is available to the east of the smelter. C. PROCESS DESCRIPTION The smelter flow sheet diagram is shown in Figure 4. The feed in the form of precipitates, concentrate, lime and flue dust is fed to a rotary dryer which removes a major portion of the moisture to minimize excess pressures in the reverberatory furnace. The partly dried material is then passed to one of two reverberatory furnaces where it is processed to matte. The reverberatory furnace uses preheated air, flux and fuel to produce slag and matte. The matte is then taken to the four converter lines where normally three operate at any one time. The converters produce blister copper which is then placed in a holding furnace and is further refined in the refining furnace and cast into ingots. This is one of two smelters in the United States that does not make copper anodes. Gases from the rotary dryer pass through a cyclone and scrubber and then out the stack. Gases from the reverberatory furnace pass through a waste heat boiler, a precipitator and out the stack. Gases from the con- verters pass to a gas cleaning system which consists of settling chambers, air to -5- ------- Inputs 300"F Concentrates Precipitates Lime Flue Dust 625' Dryer off Gas 60,000 ACFM 350°F, 170°F D.P. 510' 200,000-260,000 SCFM 0.3-0.8% SO, 700F JPrecipitatod -JPrecipitatod JPrecipitatoa Air to Gas Heat Exchanger I Settling Chamber Converter off GasS. 36,000 SCFM/ConverterN 108,000 SCFM Max. s 36,000 SCFM VA.-D../ 4-4.5% SO. PROCESS FLOW & SULFUR BALANCE Kennecott Copper Co /Hurley Branch prepared June ,1975 PACIFIC ENVIRONMENTAL SERVICES Figure 4 ------- gas heat exchangers, precipitators, and scrubbers. The cleaned gases then pass to a double contact sulfuric acid plant and then to the acid plant stack. Temperatures, volume flows, and SO- percentages are shown on the flow sheet. D. EMITTING EQUIPMENT a. Reverberatory Furnaces Two reverberatory furnaces are installed. Dimensions are 125 feet long by 35 feet wide by 25 feet high. The draft for the furnace is generated entirely by the stack. A top charge tripper system feeds the furnace which takes a side^wall charge. Only one reverberatory furnace is operated at a time. A suspended arch roof is used to facilitate repair during operation. Oxygen quantities of 1 to 2 percent total gas volume are used for burner combustion. One reverberatory furnace is now down for refurbishing. This takes approximately 8 months. If a long campaign is planned, the system must be designed to handle maximum leakage on the last day of operation. Launders will be covered completely with hooding in the new, reworked reverberatory furnace. Table I summarizes reverberatory furnace design data from Reference 3. b. Converters There are four Peirce-Smith converters 13 feet in diameter by 33 feet long. Normally only three of these converters are active at one time with the fourth being repaired. Each converter has a close-fitting water-cooled hood with a sliding front door to aid in sealing when the converter is rolled in. Only shut-off dampers are used for each hood system. -7- ------- TABLE I: REVERBURATOKY FURNACE DATA (Reference 3) "'."-..I'.Ci; ar:E;:sio:cs Length. Inside Firing End Flue End Height Inside Firine End ' Flue End Side Wall Thickness at Slag Line Side Kail Thickness above Slag Line Roof Thickness Area Gas Uptake FIRING DATA c Amount of Fuel per Day Fuel per Ton of Solid Charge Fuel per Ton of Total Charge Temp. Exit Gases Per Cent Calories Recovered in Steam Is Automatic Draft Control used? Type Waste Hoat Boilers PP.Oil'JCT DATA Depth Molten Charge Tons Slag per 24 Hours Method Slag Disposal Tens Matte per 24 Hours Vol. Gas per 24-Hour Standard Condition Per Cent Cu in Matte 121 Ft. 10 in. 28 ft. 8 in. 28 ft. 8 in. 11 ft. 5 in. 11 ft. 5 in. 4 ft. 3 in. 20 in. 20 in. 146 sq. ft. ' Natural gas 5,056,000 5,998 . 2408°F 51.54 . No Stirling, three pass and one pass 33 in. 539 Dumped hot 621 63,800,000 cu. ft. 34.85 " I"-:":.'.I:TO-.:V DATA Kind of uric!., I'.oof Side Walls Kcatth Material Type and Location of Water Cooling CHARGE DATA PER 24 HOURS Wt. Hot Calcine Ut. Raw Concentrate Av. Moisture in Raw Cone. Pet. Kt. Crushed Ore Wt. Flue Dust Wt. and Nature of Flux Wt. Liquid Converter Slag V.tnere and How is Furnace Charged Wt. and Nature of Fettling Material Silica Silica Crushed Quartzite slag cover None None 689 tons (dry) 8.74 None 9 tons 38 tons limerock 449 tons 77 tons copper precipitates Vibrator conveyors 70 ft. along sidewalls 30 tons mine ore 70 pet. Si 0 ------- c. Other Emitting Equipment Material handling in the feed preparation area during crushing and screening operations generates particulate. The refining furnace generates small quantities of SO , NO and L X particulate. Leaks in ducts and at other pieces of equipment can release SO and particulate. Ladles holding matte and slag produce visible fugitive emissions. The rotary dryer for processing the reverberatory furnace feed produces particulate. E. EXISTING CONTROL EQUIPMENT The existing electrostatic precipitator installed to control the particulate from the reverberatory furnace is considerably under capacity. It was designed originally for 80,000 SCFM and there is over 200,000 SCFM currently generated by the furnace. It is an American.Standard unit (company not now in business). Dimensions of the reverberatory furnace precipitator are 43 feet high, 50 feet in length, and 22 feet wide. It is stub-nosed against the reverbera- tory furnace and connected with very little duct work. The inlet duct to outlet duct dimension is 17 feet. A Chemico 600-ton-per-day double contact sulfuric acid plant has been installed and was started up in December 1974 to handle all of the gases from the converter collection system. Gas conditioning before the acid plant includes precipitators, scrubbers, drop-out chambers and heat exchangers. The plant can handle a maximum short term load of 900 tons per day. There were some problems with the preheater, however, the system seems to be operating reasonably well at the present time. Particulate control in the ore crushing and handling area is accom- plished by multiple cyclones and rotoclones. The rotary dryer for reverb feed uses a cyclone and scrubber. -9- ------- F. GAS SYSTEM DUCTWORK A plan view of the reverberatory furnace gas system ductwork is shown in Figure 5. Flue gases from the four waste heat boilers pass through individual ducts into Flue No. 3. Sixty percent (by volume) of the gas flow goes directly to Flue No. 5 and then to a 510 foot tall stack. The remaining 40% of the gas flow in Flue No. 3 passes through Flue No. 4 and into an electro- static precipitator. Downstream of the precipitator, the cleaned gas rejoins the bypassed gas in Flue No. 5 before entering the 510-foot stack. As seen in Figure 6, an elevation view, Flue No. 3 is balloon-shaped, approximately 17.5 feet in diameter and 132 feet long. Flue No. 4 is 12 feet wide, 14.5 feet high, and 50 feet long. Watercooled hoods collect the offgases from the four converters. The converter offgas system ductwork is shown in Figure 7. Larger particles are removed from the gases in a settling chamber. The gases then travel through high velocity circular flues to air-cooled heat exchangers. The cooled gases then pass through three parallel electrostatic precipitators. The dust-free gases travel via round duct, 72 inches in diameter, to a double contact acid plant. A manual bypass valve permits venting the dust- free gases directly to a 625-foot tall stack in the event the acid plant is down. G. SULFUR BALANCE AND GAS COMPOSITION AT SYSTEM EXIT Typical Sulfur Balance Data Based on Data From Smelter Sulfur Balance Report: Sulfur in TPD Reverberatory 324.5 Secondaries 26.8 Total 351.3 (maximum estimated at 525 TPD) Sulfur Fixed Reverberatory slag 18.2 Sulfur that would report to acid plant 196.5 Reference 4 Total 214.7 Sulfur emitted to atmosphere Reverberatory offgas plus fugitives 130.5 Acid plant emissions 6.1 Total 136.6 -10- ------- No. 4 LI 11 H 71 No. 3 No. 2 No.l Waste Heat Boilers 25' 32.5' 35' 32.5' 7' 50' , 16' N 132' 0 50' SCALE 1" - 50' PU\N REVERBERATORS FURNACE GAS SYSTEM DUCIWRK Kennecott/Hurley June, 1975 PACIFIC ENVIIWEKTAL SERVICES -ii- Figure 5 ------- o ' 53 0) Waste Heat Boiler Bldg. § O cd , « I El. 5723' &i ri ^ L Flue No. 4 X 14' 6' ElfVATION (LOOKING Soum) 30' SCALE 1" = 30' FUENO, 3 Kennecott/Hurley June, 1975 PACIFIC ENVHOierWL SERVICES -12- Flgure 6 ------- o ss M 0) 4J M 0) 1 O cS i 30-40' Elev. ' rfj / 1 CM O M 0) §1 «. M 0) §1 3 "CZJ in 1 Bins u - 1 Flux Bii r^ ConveyoO^ i 3 . 1 fl m i 7P Coi f\f Settling Chamber High Velocity Flue - Circular 80 Ft. Elev. '' 3H2 ' ^^ t1*^ \ 1 *' L- i f- J 1 L /* D X ft Cooling Air T ^Blowers Gas Coolers Ele ctrostatic Pre cipitators Manual Bypass Valve 3 Blowers Ground Level Variable Speed 45,000 SCFM 6.5 - 7.0" W.C. Acid Plant 90 Ft. Elev. fice N I ' i i ri * I t i I 0 50' SCALE 1" - 50' CONVERTER GAS SYSTEM DUCIWRK Kennecott/Hurley June, 1975 PACIFIC ENVIRMNTAL SERVICES Figure 7 -13- ------- Emissions stated in tons per year for the various pieces of equipment studied are shown in Table II. Table III summaVizes stack test data. This information taken from Reference 1 is somewhat contradictory to the data obtained and accepted by the smelter; however, it appears to be typical for water, SO., and oxygen content. There is no evidence of chlorine, fluorine, arsenic, or other potentially harmful constituents. Zinc, tin, iron, and copper particulates have been de- tected and have been lumped into the particulate emission values shown in Table I. The following is an estimate obtained from smelter personnel of the gas and dust composition from the reverberatory furnace. GAS DUST CO 8.3% Cu 47.4% S02 3.0% (High value) Fe 9.5% H20 19.1% (High value) S 9.6% N2 67.6% Si02 19.0% 02 2.0% A1203 2.1% CaO 0.4% Grain loading in the gases leaving one reverberatory furnace ranges from 0.4 to 0.8 grains per ACF (0.9 to 1.7 gr/SCF). For short periods (5-10 min.) 2.5-4.0 gr/SCF has been detected. Another estimate was noted to be 0.97 gr/SCF maximum and 0.45 gr/SCF average. A puff situation occurs which may generate from 0.3 to 1.5 gr/SCF. -14- ------- TABLE II. EMISSION SOURCE, CONTROL EQUIPMENT, CONTAMINANT A^D EMITTED QUANTITY Type Unit notary Dryer Precipitate Reverberatory Furnace Reverberatory Furnace Converter Converter Converter Converter Fire Refining Furnace. j Rotary Line Kiln | Hoi-din,; Furnace Holding Furnace Hold ing . Furnace Primary \ 1 Crushing & \ -Screening ) Secondary \ Crushi:.s / ar.j ? Screening ) ; Scr = e:-.ir.;; S-ecr.ir.g Screening ?,re,,,r.s Type of Control Equipment Cyclone & Baffle Spray Electrostatic Precipitator Electrostatic Precipitator Settling Chamber A/G Heat Exchanger Acid Electrostatic Plant Precipitators Scrubbers None Cyclone None None None Mul tic lone Mul tic lone Rotoclone Rotoclone Rotoc lone Rotcclone Rotoclone Plot ocioi-.e Rot o*-. lone xoco,:. . Installation Date 1965 1937 1950 1938 1938 1940 1972 1940 1941 1942 1943 1951 Type of Air Contaminant Particulate Copper \ Zinc I so2 > Particulate ' Tin Iron so2 . Particulate Carbon, S02> N0x> Cu SO 2 so2 so2 so. Particulate Particulate Particulate Particulate Particulate Particulate Particulate . Particulate Particulate Particulate Particulace Quantity E.*nittfed Per Year (tons) N/A S02 - 102,000 Particulates - 275 SO. - 145,000 ) controlled by acid . , , .. > plant uith 2,500 ppm Particulates - 1,000 ( ^ <,-«.<-nI f SO emissions / w"2 **>*** N/A S/A Estimated to be very low S/A N/A S/A 107.9 1C.O 77.6 1.03 11.1 34.9 8.14 11.0 12.0 16.41 53.34 0.45 Ln I ------- TABLE III. EMISSIONS REVERBERATORY FURNACE Particulate After Precipitator so2 so3 NO x CO,, Volume Flow CONVERTERS Particulate After Precipitator so2 so3 NO x co2 °2 Volume Flow Volume Flow out stack Dilution 25.6 TPD 18.72 TPD 242 TPD = 1.07% 4.5 TPD 3.38 ppm 5.5 % b.v. 2.0 % b.v. 17.2 % b.v. 176,000 SCFM «§ 70°F) 8.15 TPD 5.68 TPD 489 TPD 1.4 TPD 1.96 ppm 2.3 .5 19.7 % b.v. % b.v. % b.v. 130,860 200,000 SCFM (@ 70 F) SCFM 69,000 SCFM Reference 1. -16- ------- Later data than the above supplied by the smelter personnel Indicated the following for the furnace emissions: FURNACE EMISSIONS Particulate 27 TPD HO 4.0% to 7.0% b.v. S02 7400-8700 PPM SO 220 PPM C02 2.0% b.v. 02 17.0% NO 1.0-7.0 PPM x SO 550 Ibs/hr (sulfuric acid mist) HO 5%-7% b.v. Cl none F_ none NO none x Arsenic, Selenium, and Zinc mostly in the form of Sulfides. Lead tied up in the slag. Particulate size range is currently being investigated and is not available. -17- ------- PARTICULATE OUT OF REVERBERATORY FURNACE Element Cu Fe Mo Pb Si Approx. Al As Ba Hg Mg Mn Ni Sn W Zn /« D . W . 1-25 2-20 .1 - .5 .2 - 2.0 60.0. 2.0 .01 - .15 .5 None .2 .01 .001 - .02 .1 - 1.0 None 2.0 - 30 95% thru 200 mesh SO y SO. SO, 246 short tons 242 98.4% 4 1.6% Reference 5 -18- ------- H. GAS CHARACTERISTIC VARIATION It can be expected that SO concentration in the offgas from the reverberatory furnace will vary significantly with time. This results from the variation in time required for decomposition or reaction of the various sulfide ores charged to the furnace. This variation in SO content has been known to vary as much as 10 to 1 within a given charging time cycle. While no data are yet available from this smelter concerning this point, it should be considered for control system design. SO concentration in the converter offgas will also vary considerably for an entirely different reason. The operation of a converter usually includes three slag blows and one copper blow. Between these blows the converter may be rolled out for slag pouring or material charging. When the converter is not blowing, the hood above the converter is closed off by dampers so that the gases do not pass through the collection system to the acid plant. An attempt is always made to maintain at least one converter blowing gases into the system at any given time. Usually 18,000 to 20,000 SCFM will be introduced to the converter tuyeres. Additionally, 100 to 120% dilution air is added to this gas flow resulting in a total gas flow from each converter in the range of 35,000 to 40,000 SCFM. When a converter is blowing there will usually be approximately 38,000 SCFM with an SO content in the range of 4.0 to 4.5% Because of the normal fluctuation in converter feed and operation, the SO concentration can vary over a relatively wide range. In addition, the gas volume flow from the converter line to the control system acid plant can usually vary over a wide range from maximum to zero. Operation of the control system must be conducted in a manner to compensate for these fluctuations. Acid plant operation at this smelter appears to be typical providing reasonably satisfactory control. Significant on-time data have not yet been accumulated because of the relatively short time the plant has been in operation. -19- ------- I. STACK DESCRIPTION Reverberatory Stack Height 510 feet Diameter 26 feet Draft 24.2" Hg Absolute Acid brick lined Converter Stack Height 625 feet Diameter 33 feet Draft This stack presently not being used. Acid brick lined Acid Plant Stack Height 200 feet Diameter 10 feet Draft (forced) Steel J. PRESENT TECHNIQUE FOR SOLID WASTE HANDLING Slag from the reverberatory furnace is taken to the slag dump. Dust from the precipitator in the converter gas cleaning system is taken by screw conveyor into a pug mill where it is processed to allow handling for feeding to the reverberatory furnace via loaders. K. FOOTING AND STRUCTURAL REQUIREMENTS If construction is to be carried out in some areas, footing tests would be required. A major portion of the area adjacent to the smelter is old slag dumps. It will be necessary to conduct footing tests to determine detailed footing requirements. However, if slag is assumed for determining footings, then the most conservative (highest cost) estimate will result. There is also a large amount of consolidated rock in the area. -20- ------- No local codes apply. Seismic zone 2, 20 PSF wind load and 20 PSF snow load are used for design. L. EXISTING AND POTENTIALLY AVAILABLE UTILITIES The smelter produces its own electricity. They have recently added 30 megawatt capacity. This leaves approximately 15 megawatts available above that presently being used. Water is obtained from wells. There does not appear to be a limitation on availability of water. A new pumping system would be required if a large quantity of additional water is used. There is no additional gas available for fuel. If additional fuel is required, oil must be used. Steam generated by the smelter is used for electrical power generation. M. POTENTIAL NEW CONTROL EQUIPMENT INSTALLATION PROBLEMS The existing precipitator on the reverberatory furnaces is designed for 80,000 SCFM. Since gas flow is currently in the range of 200,000 SCFM, it will be necessary to add additional particulate collection capability. This could be done by either removing the existing units and replacing with one of larger capacity or adding to these units to match the total gas flow. Since the precipitator is old, it would be advisable to replace it. -21- ------- REFERENCES 1. "Source Emissions Survey of Kennecott Copper Corporation Copper Smelter Converter Stack Inlet and Outlet and Reverberatory Electrostatic Precipitation Inlet and Outlet, Hurley, New Mexico, April 1973," File Number EA 735-09, Ecology Audits, Inc. 2. "Air Quality Source Sampling Report #44, Kennecott Copper Corporation Hurley Smelter Reverberatory Furnace," March 27, 1974, Environmental Improvement Agency. 3. "Outline of Metallurgical Practice," C. A. Haward, D. Von Nostrand & Co., Third Edition, 1952. 4. Kennecott Copper Corp., Chino Mines Division "Average Tons Su.lfer per Day" EC/MM/9 Jan 75 Kennecott Copper Corp., Chino Mines Division Data. -22- ------- TECHNICAL REPORT DATA (Please read Inunctions on the reverse before completing) 1. REPORT NO. EPA-600/2-76-036d 2. 3. RECIPIENT'S ACCESSION-NO. 4. TITLE AND SUBTITLE Design and Operating Parameters for Emission Control Studies :Kennecott, Hurley, Copper Smelter 5. REPORT DATE February 1976 6. PERFORMING ORGANIZATION CODE 7. AUTHOR(S) 8. PERFORMING ORGANIZATION REPORT NO. I.J. Weisenberg and J.C. Serne 9. PERFORMING ORG -vNIZATION NAME AND ADDRESS Pacific Environmental Services, Inc. 1930 14th Street Santa Monica, CA 90404 10. PROGRAM ELEMENT NO. 1AB013; ROAP 21ADC-061 11. CONTRACT/GRANT NO. 68-02-1405, Task 5 12. SPONSORING AGENCY NAME AND ADDRESS EPA, Office of Research and Development Industrial Environmental Research Laboratory Research Triangle Park, NC 27711 13. TYPE OF REPORT AND PERIOD COVERED Task Final; 4-10/75 14. SPONSORING AGENCY CODE EPA-ORD 15. SUPPLEMENTARY NOTES EPA Task Officer for this report is R.Rovang, 919/549-8411, Ext 2557. 16. ABSTRACT rpjie repOr^ gjves background design data for a specific copper smelter. The data is sufficiently detailed to allow air pollution control system engineering studies to be conducted. These studies will be concerned primarily with lean SO2 streams that currently are not being captured. Physical layout of the smelter and the surrounding area is presented, along with existing control equipment. Ductwork that would be considered for future system tie-in is defined. Emissions from operating equipment, gas flow rates, temperatures, sulfur balance, and a process flowsheet are included. Utilities, stack dimensions, footing requirements, and solid waste handling are defined. Available area for new control equipment, gas characteristic variation, and potential new control equipment installation problems are discussed. 17. KEY WORDS AND DOCUMENT ANALYSIS DESCRIPTORS b.lDENTIFIERS/OPEN ENDED TERMS C. COSATI Field/Group Air Pollution Copper Smelters Design Sulfur Dioxide Utilities Air Pollution Control Stationary Sources Emission Control Operating Data Solid Waste Handling Wastes 13B 07B 11F 18. DISTRIBUTION STATEMENT Unlimited 19. SECURITY CLASS /This Report) Unclassified 21. NO. OF PAGES 26 20. SECURITY CLASS (This page) Unclassified 22. PRICE GPA Form 2220-1 (9-73) 23 ------- |