4vEPA
United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park NC 27711
EPA-450/2-88-003a
April 1988
Air
Air Emissions
Species Manual
Volume I
Volatile Organic
Compound
Species Profiles
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EPA-450/2-88-003a
Air Emissions-Species Manual
VoJume I
ซ
Volatile Organic Compound
Species Profiles
By
Gunseh Sagun Shareef
William A Butler
LuJs A Bravo
Margie B -Stockton
Radian Corporation
Research Triangle Park, Worth Carolina 27709
Contract No, 68-02-3994
Work Assignment No ,122
William B Kuykendal, Project Officer
Office of Air Quality Planning and Standards
Office of Air and Radiation
U S Environmental Protection Agency
Research Triangle Park, North Carolina 27711
J David Mobley, Project .Officer
Air and Energy Engineering Research Laboratory
Office of Research and Development
U S Environmental Protection Agency
Research Tnangle Park, North Carolina 27711
April 1988
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This report has been reviewed by the Office of A,ir Quality Planning and Standards, U.S. Environmental
Projection Agency, and approved for publication as received from the contractor. Approval does not signify
that the contents necessarily reflect the views and pplicies.pf the Agency, neither does mention of trade
names or commercial products constitute endorsement or recpmmendation for use.
EPA-450/2-88-003a
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FOREWORD
This report is the result of a cooperative effort between the Office of
Air Quality Planning and Standards' Air Quality Management Division (AQMD)
and the Office of Research and Development's Air and Energy Engineering
Research Laboratory (AEERL). The Overall management of the program was the
responsibility of AQMD. AEERL was responsible for the development of
selected VOC species profiles as well as; program review.
;.*]
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- ABSTRACT
The U S. Environmental Protection Agency (EPA) has several ongoing
activities that require speciated volatile organic compound (VOC) or
particulate matter (PM) profiles from several source categories In 1980,
EPA published the "Volatile Organic Compound (VOC) Species Data Manual,
Second Edition" (EPA-450/4-80-015) which provided VOC species profiles for
some emission source categories,..; More ^recently, EPA published the "Receptor
Model Source Composition Library" -(!s6^n^c^H^tfed;^nlJi1ie^PM"data base. As in the VOC
profile data base, the PM data base also'&Stuaitis^profile assignments
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VOLUME I - VOLATILE ORGANIC COMPOUND (VOC) SPECIES PROFILES
i'ri -i <.';:
CONTENTS
Foreword ................ .' C';'tvV..-;ij 1 ;ฃ]$;; It&v :.;.; .............. '.....' i i i
Abstract ................. f .... .v.,,^fc.a;.,. ,.;,... ... , .............. .-.5. i ; : . .iv.
Tables ................. '..:.'.... ^'.v'.3/.:1:0.;-.: ...................... ,,f. . vU
Executive Summary ....... i'lV. . P.; ^'yPC^o, '&.>ป?. .-. .' ................. .'.':.' viii.
1 . Introduction ---- '.'. //. '.'. .'.' . .1 . . '.-'.- .......................... t .1,
2. VOC Species Profile -'FOiffat iariฃ Application ........ !\ ..'..!. 5
2.1 VOC Species Prof i Te^F.^rinat ^-^^ ........... ;:.....- ---- . e &
2.2 VOC Species Prof ifes .;. ^'. . '. , ....... ........ ...c... ...... ..... , ,9 ..
2.3 VOC Speci es 'Profile <$p!pt i ttftfon :.~. .-. . : ____ . . . .ฃ: . .' . . . . : ; '9
2.3.1 Document, Use; ^.-^. .>..ซ/.ป..:.-.. .-.-.: r ---- .;. .\ . . .7.-. .- . . .\ 9 ;
2.3.2 Exampl e b'f Use 'of Prof i 1 e ...................... '9
3. VOC Species Profiles ^ P^i^'aritf AVea SduVces . . J . /.\V. . f. T 12 '
3 . 1 External Combusjtiionj:$cn lฃf:s .-.,.. .>..ฃ, ---- . . . ______ -... .-:. ........ 21
3 . 2 Internal Combustion -Engines .................... . v... . . .32 .
3.3 Carbon Black Production .......... V... ......... -. .\:v. . . 3'8 '''
3.4 Pai nt Manufacture,; .ฃ.j.t-.':. .:,..,.-.>,. . .%.... ...... ...... ...... . ---- 40
3 . 5 Varn i sh Manufacture V7. . . . .'. '.'.'.. . . . . ............. ..... 42
3.6 Plastics PrbductflbrP^A/;^;.;-.'-.'."../1. ........... :..r. .?.:'/ 44-'
-' ซ
3.7 Printing Ink Mayirufaiptuj^;; :. .&#-. . .;. . ....... ...... ...:.. . . . .;. .-\r. 50 :.
3.8 Synthetic Organic Fiber" Production ................... 52 c>
3.9 Organic Chemical-^afifilTf^hture J. ./. ............. . . . . . . . 5'4 '
3 . 10 Food and Agriculture^,,. .r.>;. . .;..>;>;.,. . . ............ .... .?. . lit o
3.11 Primary and Secondary Metal Production ......... . ...... 113 ;
3.12 Asphalt Products $W#. .^U^.-:.;. ....... ....%.'...;.. 124
3.13 Petroleum Pro.dJLiclis:, >.,.: v?.,-T(t v .,;,.;. . ..... . .;. ---- r... ... ---- 130. :
3 . 14 Plywood Products :".'. r.v.".r '.''.'. . ........................ . . 139
3.15 Synthetic Rubbed* t>^ttac^'dnp.?;?. .f.-t ;;;-. .*.l :. "1 . "lr. .;': . '. ": .r.^T 14f
3.16 Oil and Gas Production .;.....ป,-..-.ซ*..;.... .^^v....-.:-.,;...? .,-s;; 146;:?:!
3.17 Textile Products ........ ........?;..,.,. ,". ..150 '
3.18 Organic Solvent^Ey^P&^tiAn1 - - ^T. .'.i .^^ .::.. .''^' 155
3.19 Surface Coft:ing9Op'0ftVo|iis/3i..',.., ;.-.v.-.(. .-.......... ^..,. K, 184
3.20 Storage, Transpbrtatfoh^^ahH Marketing of '^.-,
Petroleum:1 P^odUGt's $;.*&<:<%':.}... i.':.'... iv. ... .T'21^ ;
3.21 Printing/Publi^b-iflgn^rP.?65565-* "' "' :..!! 235;:.
3.22 Organic Chemicat'Stor'age!..!.....'. '. 245 ,
3.23 Railcar,^TahksiIPruek^alfld; DrfeCieahing^ 1.;..."'..: I'i::' 3*18!-
3.24 Solid Waste^Di spqs-aU,.....,.,u. ;-,v.w; .* ;..;;...; -325 -3
3.25 Wood Combus!?6n^^:Cv)v:C.:..:.'.... : 330
3.26 Mobile Sources - Gasoline Fueled Vehicles 334
3.27 Aircraft 349
3.28 Forest Fires ....-... 356
References '..-..: 358
V
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CONTENTS:T(iQp,ntinued)
Appendices
A. Literature Search and VOC Species Profile Development A-l
B. Industry-Specific Average VOC Profiles and "Zero"
Profile B-l
C. VOC Profile Assignments C-l
D. Chemical Species Data File D-l
E. Chemical Species Classification E-l
F. Data File Description F-l
G. VOC Speciation Test Program '. G-l
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t ':> TABLES
Table Page
2-1 Sample Profile 6
,.)'('; 2 ii / D3uc' ..li/v .
; ~ ( , , ,*1 '-,"'
i . v.!' " .; \
V'l 1
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EXECUTIVE SUMMARY
The U. S. Environmental Protection.; Agency (EPA) has several ongoing
activities that require speciated .volatile-, organic compound (VOC) or
particulate matter (PM) profiles from several source categories. Some of
these activities include preparation of air toxics and acid precipitation
emission inventories, receptor modeling, and ozone strategy development. In
an effort to update the available speciated VOC and PM profile data bases,
EPA has initiated studies to (1) revise the "Volatile Organic Compound (VOC)
Species Data Manual - Second Edition" (EPA-450/4-80-015) ; and (2) update the
"Receptor Model Source Composition Library" (EPA-450/4-85-002) . The revised
PM species profile data base is contained>in Volume II of this document.
This document (Volume I) contains., the;.' updated VOC species profile data base.
The objective of the current "study-Was1 to (1) evaluate, revise, and
""-.risq j ':
update the 1980 VOC Data Manual; (2) incorporate the new VOC profiles
developed in this study from readily available existing data into the
updated VOC species profile data base; and.. (3) incorporate the new VOC
profiles developed as a result of the VOC speciation field program in the
"i ' :."', ' J :/' :-,'
updated VOC species profile data base.
', ." ' '. i'*.-. !"!;- . " '.
Overall, there are over 250, original VOC profiles in this document. Of
these profiles, about 30 percent are extracted from the 1980 VOC Data
.- .': j ;', ."' !j ~J. 7 ' : : . "
Manual, about 65 percent are new profiles developed from existing data or
based on engineering judgement, and about 5 percent are new profiles from
'. ' ' '. '. :' 3 " ~ . ' )
the VOC species field program. In addition, this document contains about
' ' T> f.'OC-,' .V ;:f i i '
50 industry-specific average profiles. The profiles from the 1980 VOC Data
' ' " ' '
,
Manual cover the following source categories: petroleum products, surface
'. -i.'-i;- S'u -''>', i:li '!,'" ". "
coating operations, external and internal combustion, solid waste disposal,
. .. '. 'z ;:.. "VGJ V'-; 10 '":
primary and secondary metal production, and asphalt production. Most of the
' - '' j\l ~ 1J 'jt'i ' ' S1XV11 "0 J '0";
new profiles developed from existing data represent the following source
. -'.. ~i ~sf!ie b:.. us' pnf "fftsf- '.. '
categories: organic chemical manufacturing, storage of organic chemicals,
' ' j -! ; r"'"010 !-}p5'f9Vf' Ji'tf.'.'
vaircraft emissions, oil and gas production, surface coating operations,
: . .. cr; ze^ I -to'i IBnrno 'i.^
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mobile sources, and gasoline evaporation. The profiles for the last three
categories were replacements for poor quality and/or outdated profiles in
the 1980 VOC Data Manual. -i = ;;: <'.:-
Control device identification1'' y - "' '.-.-
References
Data source ',"'ป' <-'<>''
Source Classification Code "(SC'C:)rii
Chemical species identified by:-:Storage and Retrieval of Aerometric
Data (SAROAD) code, Chemical?A.bsjt;rac-t System (CAS) number, species
name, molecular weight, weight percent
.. i iC "M",: .; ; : .
Date
. In addition to the VOC profiles, this document contains VOC profile
assignments for all SCC's in the National Emissions Data System (NEDS) and
applicable NEDS area source codes and additional area source codes used in
the National Acid Precipitation Assessment" Program (NAPAP). Ideally, a
.,. " i i
profile would be needed to represent each one of these categories. However,
t. > C, ('. ''., -'
the number of categories to be characterized is much larger than the
available profiles. Therefore, profile" assignments that involve linking a,
VOC profile to a source category that does not have an original profile
assignment are developed using engineering judgement.
Source category profile assignments are especially important in
activities such as preparation of air toxics and acid precipitation emission
inventories and acid precipitation modeling studies. For several SCC's,
profile assignments using engineering judgement were not possible; however,
* j " , Ciif "iLudti *,:'!?:: '..
in such cases, industry-specific average^profiles were developed. These
profiles were developed from original profiles representing other SCC's
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within the same industry group. The industry-specific average profiles are
intended for use only if there is no other information available. In
addition, a "zero" profile which is ahl'.bverall average based on all the VOC
profiles in the data base was developed/ This profile is intended for use
only as a default profile to represent those SCC's characterized by "zero"
or "negligible" VOC emission factors'.according to the document "Criteria
Pollutant Emission Factors for the 1985i"Emissions Inventory"
(EPA-600/7-87-015) and for which the' States or any other agency have
reported nonzero emissions. -.
.'_.*. .., J_> C j" 5D '
-'".-' Unrpno
9fiT
3"f9omun S
I x
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SECTION 1
INTRODUCTION
:)-.;'' >:' .
The U. S. Environmental Protection Agency (EPA) has several ongoing
activities that require speciatedvuvola-tile organic compound (VOC) profiles
from several source categories. Some, of these activities are preparation of
acid precipitation and air toxics emission inventories and ozone strategy
development.
As part of an effort to update the available speciated VOC and PM
profile data bases, EPA has initiated studies to (1) revise the "Volatile
Organic Compound (VOC) Species Data Manual - Second Edition"
(EPA-450/4-80-015); and (2) update the "Receptor Model Source Composition
Library" (EPA-450/4-85-002). In the PM area, the updated PM species profile
data base containing the profiles from the Source Composition Library and
the new PM profiles developed from existing data are compiled in Volume II
of this document. Initial efforts in the VOC area have resulted in new
profiles developed from literature review. Another study in the VOC area
consisted of a field sampling program where new profiles were developed
based on original data for selected source categories. The VOC profiles
compiled in Volume I of this document are primarily based on (1) 1980 VOC
Data Manual, (2) interim document, and (3) field sampling program.
Revision of the 1980 VOC Data Manual consisted of identifying poor
quality and/or outdated profiles and replacing them with new VOC profiles.
Profiles for which there were no replacements were retained in the data base
even if the profiles were of low data quality. In cases where there were
several profiles representing a given source category, the most general
profile with the highest quality level was selected. The profiles extracted
from the 1980 VOC Data Manual were included in the current work without any
changes except revisions made to data quality indicators for pure
solvent/product profiles. The original references used in developing these
profiles in the 1980 VOC Data Manual were also included as part of the
references listed in this report. The profiles from the 1980 VOC Data
Manual are identified by profile numbers ranging from 0001 through 0333.
x 1.
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The new VOC profiles were deyel;op
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The activities where VOC "spdcTes profiles are applied typically employ
SCC codes for point sources and the NEDS area source codes to represent
emission source categories. Ideally, each source category would be
characterized by an appropriate VOC profile. Since there are much fewer
species profiles than source categories, a VOC profile is assigned to other
source categories that are judged to be similar to the source category(ies)
having the original profile. This document contains VOC profile assignments
for all the SCC's in the NEDS data base and the applicable NEDS area source
codes. In addition, profile assignments are provided for area source codes
used in the NAPAP studies. The development of VOC profile assignments is
discussed in detail in Appendix C. Also included in this appendix are the
listings of the assignments for both point and area sources.
To provide the reader/user with guidance on the overall quality of data
contained in each profile, an arbitrary scheme (A, B, C, D, E) similar to
the one used in AP-42 was used to rank each profile. For example, Profile
Data Quality A was assigned to profiles that were considered representative
of the total population of sources within a given SCC and that were based on
sound analytical techniques with full documentation. Profiles b'ased on
engineering judgement and that may not be considered representative of the
total population were assigned Profile Data Quality E. A more detailed
discussion on profile data quality is contained in Section 2.
Data quality indicators were also used to characterize the VOC profile
assignments. Where the VOC profile assignment is based on an original
profile, the data quality indicator reflects the Profile Data Quality on the
profile (see Section 3). In cases where the assignment is based on
engineering judgement, the data quality is typically lowered one or more
levels depending on how well the profile represents the "new" category.
For several SCC's, profile assignment using engineering judgement was
not possible. In such cases, industry-specific average profiles were
developed from original profiles- representing other SCC's within the same
industry group. These profiles''have numbers starting with 9 and are
recommended for use only if there is no other information available. In
addition, Profile 0000 which is; xi'ri: ove'ral 1 average based on all the profiles
in the data base was developed.;-'fTh'i's profile is intended for use only as a
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default profile in applications such as emission inventory development. The
"zero" profile is applied to those SCC's characterized by "zero" or
"negligible" VOC emission factors and for which the States or any other
agency have reported nonzero VOC emissions. The SCC's with "zero" and
"negligible" emission factors were identified from the document "Criteria
Pollutant Emission Factors for the 1985 NAPAP Emissions Inventory"
(EPA-600/7-87-015).
This document is divided into four sections with numerous supporting
appendices. Section 1 contains this introduction. Section 2 describes the
VOC species profile format and discusses the applicability of VOC profiles
in various activities. Section 3 contains the VOC profiles for both point
sources and area sources, followed by the list of references.
There are seven appendices that provide additional information:
Appendix A - Literature Search and VOC Species Profile Development
Appendix B - Industry-Specific Average Profiles and "Zero" Profile
Appendix C - VOC Profile Assignments
Appendix D - Chemical Species Data File
Appendix E - Chemical Species Classification
Appendix F - Data File Description
Appendix G - VOC Speciation Test Program
4
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SECTION 2
VOC SPECIES PROFILE FORMAT AND APPLICATION
2.1 VOC SPECIES PROFILE FORMAT
Table 2-1 is an example of the format used in presenting the VOC
profiles for this document; it is basically the same as that used in the
1980 Data Manual except for a few changes. Although the profiles in the
1980 Data Manual contain chemical classification information for each
species, this information is not included in this document, since there are
several different classification schemes currently used. However, two
examples are included in Appendix E. Another item that is not included in
the new VOC profile format is information on volumetric or molar composition
(volumetric or molar percentages). Several manual users indicated that this
information is of very little use in their work. Each of the entries in
Table 2-1 is described below:
Profile name: In a majority of the cases, the profile name is the
descriptor used for the applicable source category. In cases where a
particular profile is applicable to more than one source category, a more
general term is used to identify a given profile.
Profile number: This is a unique number assigned arbitrarily to a
profile. A numerical listing of all the VOC profiles in this document is
provided in Appendix A.
Profile data Quality: A ranking scheme is employed to assign data
quality indicators to each profile. This approach is similar to the one
used in the 1980 Data Manual and also consistent with the approach used in
AP-42 for emission factors. The following criteria were used in assigning
data quality indicators:
Data Quality A: Data set based on a composite of several tests
using analytical techniques such as GC/MS and can
be considered representative of the total
population.
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TABLE 2-1. SAMPLE PROFILE
PROFILE NAME:Terephthalic Acid/Dimethyl Terephthalate
Distillation and Recovery Vent.
PROFILE NUMBER:1024
PROFILE DATA QUALITY:C
CONTROL DEVICE .-Condenser
REFERENCE(S): 29
DATA SOURCE:Composite profile developed using data from four
emission sources (weighted according to emission
rates); one data set is based on vent analysis, and the
others are based on engineering calculations.
SCC
50103104
SAROAD CAS
NUMBER NUMBER
43301 67-75-1
43350 115-51-6
43432 79-92-9
43503 75-50-0
45204 95-54-6
SPECIES
NAME
METHYL ALCOHOL
DIMETHYLETHER
METHYLACETATE
ACETALDEHYDE
0-XYLENE
MOL.
WEIGHT
32 . 04
46 . 07
74.08
44.05
106.16
PERCENT
WEIGHT
7.77
66.64
16.33
8 . 43
0 . 83
SUM TOTAL
100.00
DATE :04-21-1988
. 6
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Data Quality B: Data set based on a composite of several tests
using analytical techniques such as GC/MS and can
be considered representative of a large percentage
of the total population. Profiles from the VOC
field sampling program are assigned data quality
"B."
Data Quality C: Data set based on a small number of tests using
analytical techniques such as GC/MS and can be
considered reasonably representative of the total
population.
Data Quality D: Data set based on a single source using analytical
techniques such as GC/MS; or data set from a number
of sources where data are based on engineering
calculations.
Data Quality E: Data set based on engineering calculations from one
source; data set(s) based on engineering judgement;
data set(s) with no documentation provided; may not
'be considered representative of the total
population.
Control device: This entry is used to indicate if the profile data
represent an emission stream downstream or upstream of a control device (if
present) since the composition of the uncontrolled and controlled streams
may be significantly different.
Referenced): This entry identifies the primary reference(s) used in
developing the profiles. If more detailed information is required, the
user/reader should consult these references.
Data source: This entry briefly describes the basis of the composition
data used in the profile (e.g., number of tests, number of sources,
analytical methods, how data were composited, etc.). More detailed
information about the data used can be obtained from the references
indicated.
SCC: This entry is the code for the source category for which the
profile was originally developed. These codes are obtained from the current
National Emission Data System (NEDS) for point sources (1-01-001-01 through
' 7
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5-03-900-10) and area sources (01 through 64). Area source codes from 65
through 115 developed under NAPAP are also considered. A listing of area
source codes and their descriptions is presented in Table C-3 of Appendix C.
Composition data: Each species in the profile data is identified by a
SAROAD code, CAS number, species name, molecular weight, and weight
percentage. SAROAD codes were obtained from Volume V of the Aeros Manual
Series (third edition, September 1986). For species not contained in this
manual, new SAROAD codes have been assigned following the methodology
employed in the Aeros Manual.
In some profiles, the weight percentages are followed by peak
identifiers (ID's). The peak ID's indicate groups of two or three species
identified as a single peak in GC and/or GC/MS analysis. In this document,
one of the species in a given peak is arbitrarily assigned the total weight
percentage corresponding to the peak. For example, in Profile 1097,
peak (1) represents butyraldehyde and crotonaldehyde. The weight percentage
for butyraldehyde is indicated as 1.24, while that for crotonaldehyde is
listed as 0.00. A footnote is included at the end of such profiles to
explain peak ID and its use.
It should also be noted that in some profiles, a given species appears
more than once with different weight percentages and as part of different
peaks. This is primarily due to the inability to distinguish between
isomers of a given species in interpretation of raw GC/MS data. For
example, in Profile 1192, the species isomers of undecane appears three
times with different weight percentages: (1) zero percent, as part of
peak (15) shared with octahydroindene (0.04 percent) and Cll olefins (zero
percent); (2) 3.03 percent as a single peak; and (3) zero percent, as part
of peak (17) shared with isomers of butylbenzene (0.10 percent).
Most of the CAS numbers were obtained from the National Air Toxics
Information Clearinghouse Data Base (1985) and the Registry of Toxic Effects
of Chemical Substances (1983 supplement to the 1981-82 edition). For some
species/group of species, CAS numbers were not identified.
Date: This entry will be used to indicate the date the profile was
last reviewed/updated by EPA.
8
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2.2 LIMITATIONS OF DATA
All data identified through the literature search efforts were used as
reported when developing the new profiles in this study. Only those data
sets with sufficient documentation were included. No attempt was made to
verify the completeness/accuracy of the data. The profile data
(i.e., species and weight percentages) extracted from the 1980 VOC Data
Manual were incorporated in the updated VOC data base with no changes.
In some cases, the profiles may not be a full characterization of the
emission source. Therefore, the user/reader is cautioned to use these
profiles with discretion. Nevertheless, the profile data quality indicator
provides a qualitative measure of confidence in a particular profile.
Profiles for individual sources may vary considerably from the values
provided in this document. Therefore, profiles in this document should not
be used to characterize specific sources; rather, they should be used for
screening purposes. Source-specific data should always be preferred to the
use of literature data presented in this document.
2.3 VOC SPECIES PROFILE APPLICATION
There are several ongoing EPA activities that require speciated VOC
data as an input parameter. These activities include preparation of air
toxics emission inventories, ozone strategy development, and preparation of
acid precipitation inventories. The primary use of the 1980 Data Manual has
been in ozone related studies. It is anticipated that the updated VOC
profile data base will be applied in preparation of emission inventories as
well. This section will briefly discuss how to use this document and
provide a specific example to illustrate how to use VOC species profiles in
preparation of air toxics emission inventories.
2.3.1 Document Guide
In addition to the VOC profiles contained in Section 3, Appendix C in
this document includes VOC profile assignments for all the VOC profiles.
This appendix also contains a listing of area source codes and their
-------
descriptions. Appendix A contains a numerical listing of all the profiles
and their location in this document.
To identify the applicable profile for a given source category, the
reader should (1) refer to Table C-l or C-2 in Appendix C; (2) identify its
location from Table A-l in Appendix A; and (3) locate the actual profile in
Section 3.
2.3.2 Example of Use of Profile
The easiest way to describe how profiles might be applied is to present
a hypothetical example: A State air pollution control agency is interested
in developing an air toxics emission inventory for the State. An earlier
study conducted for the State has identified a list of toxic/potentially
toxic compounds from several emission sources. The emission rates of these
individual compounds will be used as an input to the proposed air toxics
regulatory program for the State.
The profiles can identify the relative amounts of individual compounds
in a given emission stream. In most cases, emission factors are available
for total VOC's where the compound breakdown is not specified (e.g., AP-42
or the Criteria Pollutant Emission Factor document). The information
contained in this document supplements these general emissions data. For a
given source category, the appropriate VOC species profile should be
identified using Appendix C and the total VOC emission factor should be
multiplied by the weight fractions for each compound in the profile to
determine compound-specific emission factors.
In this example, formaldehyde is one of the toxic compounds on the
State's list and airport operations are a major emission source. From
Appendix C, the reader/user identifies the profile appropriate for airport
operations. Aircraft emissions are classified as area sources, and
Table C-3 lists three types of airport operations (civil, military,
commercial). Since the airport in question is commercial, the appropriate
profile for area source code 047 is Profile 1098. To locate Profile 1098,
the reader should refer to Table A-l in Appendix A where the location of
each profile is given. From this table, Profile 1098 is on page 352. If
10
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the reader/user is concerned with point sources, the SCC and the VOC
emission factor for a particular category can be obtained from NEDS or the
Criteria Pollutant Emission Factor document.
The weight percentage of formaldehyde in Profile 1098 is 15.00.
Applying the weight fraction of formaldehyde to the total VOC emissions for
the airport of 500,000 Ib/yr, formaldehyde emissions are estimated as
500,000 x 0.15 = 75,000 Ib/yr. The reader/user should review the "Data
Source" description for the profile to ensure that the data apply to the
specific situation on hand. If there are questions, the reader may wish to
review the original document on which the profile is based.
11
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SECTION 3
VOC SPECIES PROFILES - POINT AND AREA SOURCES
This section contains all the VOC profiles grouped in 29 separate
sections according to source categories. The profiles representing point
sources are presented first, followed by those representing area sources.
The profiles are ordered numerically within each subsection. The following
list can be used to identify and locate the profiles within each section.
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
3.1
0001
0002
0003
0004
0005
0195
0217
1085
Profile 1178
Profile 1185
SECTION 3.2
Profile 0007
Profile 0008
Profile 0009
Profile 1001
SECTION 3.3
Profile 1002
SECTION 3.4
Profile 1094
SECTION
Profile
3.5
0066
SECTION 3.6
Profile 0068
Profile 1004
Profile 1005
EXTERNAL
External
External
External
External
External
COMBUSTION
Combustion
Combustion
Combustion
Combustion
Combustion
- Residential Fuel -
BOILERS
Boiler
Boiler
Boiler
Boiler
Boiler
Natural
- Residual Oil
- Distillate Oil
- Natural Gas
- Refinery Gas
- Coke Oven Gas
Gas
Coke Oven Blast Furnace Gas
External Combustion Boiler - Coal-Slurry
Fired.
Coal-Fired Boiler - Electric Generation
Coal-Fired Boiler - Industrial
INTERNAL COMBUSTION ENGINES
Natural Gas Turbine
Reciprocating Diesel Fuel Engine
Reciprocating Distillate Oil Engine
Internal Combustion Engine - Natural Gas
CARBON BLACK PRODUCTION
Chemical Manufacturing - Carbon Black
Production
PAINT MANUFACTURE
Paint Manufacture - Blending Kettle
VARNISH MANUFACTURE
Varnish Manufacturing - Bodying Oil
PLASTICS PRODUCTION
Manufacturing - Plastics - Polypropylene
Plastics Production - Polystyrene
Plastics Production - Polyester Resins
Page Number
22
23
24
25
26
27
28
29
30
31
33
34
35
36
39
41
43
45
46
47
12
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Page Number
SECTION 3.6 - PLASTICS PRODUCTION (Continued)
Profile 1009 - Plastics Production - Acrylonitrile-
Butadiene Styrene Resin
Profile 1091 - Plastics Production - Polyvinyl Chlorides
and Copolymers
SECTION 3.7
Profile 0072
SECTION 3.8
Profile 1092
SECTION 3.9 -
Profile 0076 -
Profile 0078 -
Profile 0079 -
Profile 1006 -
Profile 1023 -
Profile 1024 -
Profile 1025 -
Profile 1027 -
Profile 1028 -
Profile 1029 -
Profile 1030 -
Profile 1032 -
Profile 1033 -
Profile 1034 -
Profile 1035 -
Profile 1037 -
Profile 1038 -
Profile 1039 -
Profile 1040 -
PRINTING INK MANUFACTURE
Printing Ink Cooking
SYNTHETIC ORGANIC FIBER PRODUCTION
Synthetic Organic Fiber Production -
Nylon Batch Production Process
ORGANIC CHEMICAL MANUFACTURE
General Pesticides
Ethylene Dichloride - Direct Chlorination
Chemical Manufacturing - Flares
Phthalic Anhydride - o-Xylene Oxidation
Main Process Stream
Terephthalic Acid/Dimethyl Terephthalate
Crystallization, Separation and Drying
Vent
Terephthalic Acid/Dimethyl Terephthalate
Distillation and Recovery Vent
Terephthalic Acid/Dimethyl Terephthalate
Product Transfer Vent
Ketone Production - Methyl Ethyl Ketone
(MEK)
Acetone - Light Ends Distillation Vent
Acetone - Acetone Finishing Column
Aldehydes Production - Formaldehyde -
Absorber Vent
Aldehydes Production - Acrolein -
Distillation System
Aldehydes Production - Acrolein - Reactor
Blowoff Gas
Chloroprene - Butadiene Dryer
Chloroprene - Chloroprene Stripper and
Brine Stripper
Organohalogens - Ethylene Dichloride -
Ethylene Dichloride Via Direct
Chlorination - Distillation Vents
Organohalogens Production - Ethylene
Dichloride - Ethylene Dichloride Via
Oxychlorination
Organohalogens Production - Ethylene
Dichloride - Caustic Scrubber
Fluorocarbons/Chlorof1uorocarbons -
General
48
49
51
53
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
13
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Page Number
SECTION 3.9 -
Profile 1041 -
Profile 1042 -
Profile 1043 -
Profile 1044 -
Profile 1045 -
Profile 1046 -
Profile 1047 -
Profile 1048 -
Profile 1049 -
Profile 1050 -
Profile 1051 -
Profile 1052 -
Profile 1053 -
Profile 1054 -
Profile 1056 -
Profile 1057 -
Profile 1058 -
Profile 1059 -
Profile 1060 -
Profile 1061 -
Profile 1062 -
Profile 1064 -
Profile 1065 -
Profile 1066 -
Profile 1067 -
Profile 1068 -
Profile 1070 -
Profile 1071 -
Profile 1072 -
Butyl Acrylate
Cumene Distillation
Vent
ORGANIC CHEMICAL MANUFACTURE (Continued)
Fluorocarbons/Chlorof1uorocarbons -
Distillation Column
Fluorocarbons/Chlorof1uorocarbons -
Fugitive Emissions - General
Acrylic Acid - Quench Absorber
Organic Acids Production - Formic Acid
Organic Acids Production - Acetic
Anhydride - Distillation Column Vent
Esters Production - Acrylates - Ethyl
Acrylate
Esters Production
Cumene Production
System Vent
Cyclohexane - General
Cyclohexanone/Cyclohexanol - Phenol
Hydrogenation Process - Distillation
Vinyl Acetate - Inert Gas Purge Vent
Vinyl Acetate - OL Purge Vent
Vinyl Acetate - Inhibitor Mix Tank
Discharge
Vinyl Acetate - Refining Column Vent
Ethylene Oxide - Oxygen Oxidation Process
Reactor - CO, Purge Vent
Ethylene Oxiae - Oxygen Oxidation Process
Reactor - Argon Purge Vent
Ethylene Oxide - Stripper Purge Vent
Methyl Methacrylate (MMA) - Hydrolysis
Reactor, MMA and Light Ends Distillation
Unit
Methyl Methacrylate (MMA) - Acid
Distillation and MMA Purification
Nitrobenzene - Reactor and Separator Vent
Washer and Neutralizer Vent
Benzene
Olefins Production - Ethylene - Compressor
Lube Oil Vent
Propylene Oxide - Chlorohydronation
Process - General
Styrene -
Styrene -
Styrene -
Alcohols
General
Benzene
Recycle
Vent
Alcohols
Styrene Purification
Production - Methanol - Purge Gas
Production - Methanol -
Distillation Vent
Chlorobenzene - Tail
Gas Scrubber
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
14
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Page Number
SECTION 3.9 -
Profile 1073 -
Profile 1074 -
Profile 1075 -
Profile 1076 -
Profile 1077 -
Profile 1090 -
Profile 1093 -
Profile 1120 -
SECTION 3.10 -
Profile 1188 -
SECTION 3.11 -
Profile 0011 -
Profile 0012 -
Profile 0013 -
Profile 0014 -
Profile 0016 -
Profile 1036 -
Profile 1089 -
Profile 1202 -
SECTION 3.12 -
Profile 0023 -
Profile 0024 -
Profile 0025 -
Profile 0026 -
Profile 1007 -
SECTION 3.13 -
Profile 0029 -
Profile 0031 -
Profile 0035 -
Profile 0039 -
Profile 0047 -
Profile 0051 -
Profile 0316 -
Profile 0321 -
SECTION 3.14 -
Profile 1189 -
ORGANIC CHEMICAL MANUFACTURE (Continued)
Chlorobenzene - Benzene Drying Distillation
Monochlorobenzene
Chlorobenzene - Vacuum System Vent
Chlorobenzene - DiChlorobenzene
Crystallization
Chlorobenzene - DiChlorobenzene Crystal
Handling/Loading
Fluorocarbon Manufacturing - CF 12/11
Fluorocarbon Manufacturing - CF 23/22
Acetylene
FOOD AND AGRICULTURE
Fermentation Processes
PRIMARY AND SECONDARY METAL PRODUCTION
By-Product Coke Oven Stack Gas
Blast Furnace Ore Charging and Agglomerate
Iron Sintering
Open Hearth Furnace with Oxygen Lance
Basic Oxygen Furnace
Secondary Aluminum - Pouring and Casting
Secondary Metal Production - Gray Iron
Foundries - Pouring/Casting
Primary Aluminum Production
ASPHALT PRODUCTS
Asphalt Roofing - Spraying
Asphalt Roofing - Tar Kettle
Asphaltic Concrete - Natural Gas Rotary Dryer
Asphaltic Concrete - In Place Road Asphalt
Mineral Products - Asphaltic Concrete
PETROLEUM PRODUCTS
Refinery Fluid Catalytic Cracker
Refinery Fugitive Emissions - Covered
Drainage/Separation Pits
Refinery Fugitive Emissions
Refinery Fugitive Emissions
Seals Refinery Gas
Refinery Fugitive Emissions - Relief Valves,
Liquified Petroleum Gas
Natural Gas
Pipe/Valve Flanges
Pump Seals - Composite
PLYWOOD PRODUCTION
Pulp and Paper Industry - Plywood Veneer Dryer
Cooling Towers
Compressor
103
104
105
106
107
108
109
110
112
114
115
116
117
118
119
120
121
125
126
127
128
129
131
132
133
134
135
136
137
138
140
15
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Page Number
SECTION 3.15
Profile 0272
Profile 0273
Profile 0274
Profile 1008
SECTION 3.16
Profile 1010
Profile 1011
Profile 1012
SYNTHETIC RUBBER PRODUCTION
Automotive Tires - Tuber Adhesive
Automotive Tires - Tuber Adhesive White
Sidewall
Automobile Tire Production
Rubber and Miscellaneous Plastics Products
Fabricated Rubber Products - Styrene/
Butadiene Rubber
OIL AND GAS PRODUCTION
Oil and Gas Production - Fugitives -
Unclassified
Oil and Gas Production - Fugitives -
and Fittings - Liquid Service
Oil and Gas Production - Fugitives -
and Fittings - Gas Service
Valves
Valves
SECTION 3.17
Profile 1095
TEXTILE PRODUCTS
Textile Products - General Fabric
Operations - Dyeing and Curing
Profile 1096 - Textile Products - General Fabric
Operations - Tenter Frame
SECTION 3.18
Profile 0085
Profile 0087
Profile 0088
Profile
Profile
Profile
Profile
Profile
Profile
0089
0090
0197
0271
0275
0277
1,1,2-Tri chloroethane
Toluene
Domestic Solvents
Trichloroethylene
Dichloromethane
Tri chlorotri f1uoroethane
Profile 1021
Profile 1142
Profile 1149
Profile 1192
Profile 1193
Profile 1195
Profile 1196
SECTION 3.19
Profile 0127
Profile 0219
Profile 0220
Profile 0221
ORGANIC SOLVENT EVAPORATION
Perchloroethylene - Drycleaning
Degreasing - 1,1,1-Trichloroethane
Degreasing - Trichlorofluoromethane
(Freon 11)
Degreasing
Degreasing
Solvent Use
Degreasing
Degreasing
Degreasing
(Freon 113)
Degreasing - Open Top - Chlorosolve
Furfural
Methanol
Degreasing
Drycleaning
Degreasing Composite
Drycleaning Composite
SURFACE COATING OPERATIONS
Surface Coating - Varnish/Shellac
Surface Coating Paint Solvent - Acetone
Paint Solvent - Ethyl Acetate
Paint Solvent - Methyl Ethyl Ketone
142
143
144
145
147
148
149
151
153
156
157
158
159
160
161
162
163
164
165
166
167
168
172
176
180
185
186
187
188
16
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Page Number
SECTION 3.19
Profile 0222
Profile 0223
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
0225
0226
0227
0228
0229
0282
0288
0289
0290
0291
0292
1003
- Mineral Spirits
Ethyl Alcohol
Isopropyl Alcohol
Isopropyl Acetate
Lactol Spirits
Naphtha
Butyl Acetate
- Butyl Alcohol
- Cellosolve
- Methyl Alcohol
Dimethylformamide
Profile 1013 -
Profile 1016 -
Profile 1017 -
Profile 1018 -
Profile 1019 -
Profile 1020 -
Profile 1026 -
Profile 1031 -
Profile 1088 -
Profile 1187 -
Profile 1194 -
SURFACE COATING OPERATIONS (Continued)
Surface Coating - Enamel - Cellosolve Acetate
Surface Coating - Varnish/Shellac Solvent -
Xylene
Surface Coating - Primer
Surface Coating Solvent
Surface Coating Solvent
Surface Coating Solvent
Surface Coating Solvent
Surface Coating Primer -
Surface Coating Solvent
Surface Coating Solvent
Surface Coating Solvent
Surface Coating Solvent
Surface Coating Solvent
Surface Coating Operations - Coating
Application - Solvent-base Paint
Surface Coating Operations - Coating
Application - Water-base Paint
Surface Coating Operations - Thinning
Solvents - Composite
Surface Coating Operations - Coating
Application - Lacquer
Surface Coating Operations - Coating
Application - Enamel
Surface Coating Operations - Coating
Application - Primer
Surface Coating Operations - Coating
Application - Adhesives
Surface Coating Operations - Thinning
Solvent - Hexylene Glycol
Surface Coating Operations - Thinning
Solvent - Ethylene Oxide
Surface Coating Operations - Adhesive
Application
Citrus Coating
Autobody Repair
SECTION 3.20 - STORAGE, TRANSPORTATION, AND MARKETING OF
PETROLEUM PRODUCTS
Profile 0100 - Fixed Roof Tank - Commercial Jet Fuel (Jet A)
Profile 0296 - Fixed Roof Tank - Crude Oil Production
Profile 0297 - Fixed Roof Tank - Crude Oil Refinery
Profile 0305 - Fixed Roof Tank - Crude Oil Marine Terminal
Profile 1014 - Gasoline - Summer Blend
Profile 1015 - Gasoline - Winter Blend
Profile 1100 - Gasoline Refueling
Profile 1190 - Gasoline Marketed
189
190
191
192
193
194
195
196
197
198
199
200
201
202
204
205
206
207
208
209
210
211
212
213
214
218
219
220
221
222
224
227
230
17
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Page Number
SECTION
Profile
Profile
Profile
Profile
3.21
0166
0182
0183
0332
Profile 0333
Profile 1022
Profile
Profile
SECTION
Profile
Profile
Profile
Profile
1086
1191
3.22
0230
0299
0301
0304
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
1103
1104
1105
1106
1107
1108
1109
1110
1111
1112
1114
1115
1116
1118
1119
1121
1122
1123
1124
1125
1126
1127
1128
1129
PRINTING/PUBLISHING PROCESSES
Printing Press - Letterpress Inking Process
Printing Press - Gravure General Solvent
Printing Press - Gravure Printing Solvent
Printing Press - Lithography Inking and
Drying
Lithography - Inking and Drying - Direct
Fired Dryer
Printing/Publishing - Ink Thinning
Solvents - Methyl Isobutyl Ketone
Pri nti ng/Flexographi c
Graphic Arts - Printing
Cyclohexane
Heptane
Flexographic, n-Propyl
Profile 1055 -
Profile 1069 -
Profile 1087 -
ORGANIC CHEMICAL STORAGE
Fixed Roof Tank - Hexane
Fixed Roof Tank
Fixed Roof Tank
Printing Press
Alcohol
Organic Chemical Storage - Methylamyl
Ketone
Organic Chemical Storage - N-Propyl
Acetate
Organic Chemical Storage/i-Butyl
i-Butyrate
1-Pentene
Acetaldehyde
Acetic Acid
Acetic Anhydride
Acrolein
Acrylic Acid
Acrylonitrile
Adipic Acid
Aniline
Benzyl Chloride
Butyl Acrylate
Butyl Carbitol
Butyl Cellosolve
Carbitol
Carbon Tetrachloride
Chloroform
Cresol
Cumene
Cyclohexanol
Cyclohexanone
Cyclopentene
Diethylene Glycol
Diisopropyl Benzene
Dipropylene Glycol
236
237
238
239
240
241
242
243
246
247
248
249
250
251
252
253
254
255
256
257
258
259
260
261
262
263
264
265
266
267
268
269
270
271
272
273
274
275
276
18
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Page Number
SECTION 3.22
Profile 1130
Profile 1131
Profile 1132
Profile 1134
Profile 1135
Profile 1136
Profile 1137
Profile 1138
Profile 1139
Profile 1140
Profile 1141
Profile 1144
Profile 1145
Profile 1146
Profile 1147
Profile 1148
Profile 1150
Profile 1151
Profile 1152
Profile 1153
Profile 1154
Profile 1155
Profile 1158
Profile 1159
Profile 1160
Profile 1162
Profile 1163
Profile 1164
Profile 1165
Profile 1166
Profile 1168
Profile 1171
Profile 1172
Profile 1173
Profile 1174
Profile 1175
Profile 1176
Profile 1197
Profile 1198
Profile 1199
Profile 1200
ORGANIC CHEMICAL STORAGE (Continued)
Dodecene
Epichlorohydrin
Ethanolamines
Ethyl Acrylate
Ethyl Benzene
Ethyl Ether
Ethyl Mercaptan
Ethylene Dibromide
Ethyleneamines
Formaldehyde
Formic Acid
Heptenes
Isobutyraldehyde
Isobutyl Acrylate
Isobutyl Alcohol
Isoprene
Methyl Acetate
Methyl Acrylate
Methyl Carbitol
Methyl Cellosolve
Methyl Styrene
Methylal1ene
Methyl t-Butyl Ether
m-Xylene
Nitrobenzene
N-Butraldehyde
N-Decane
N-Dodecane
o-Xylene
Pentadecane
Piperylene
Propionaldehyde
Propionic Acid
Propylene Oxide
p-Xylene
Tert-Butyl Alcohol
Toluene Diisocyanate
Isooctane
Pentane
Isopentane
Cyclopentane
SECTION 3.23
Profile 1078
RAILCAR, TANK TRUCK, AND DRUM CLEANING
Railcar Cleaning - Low Vapor Pressure,
High Viscosity Cargo (Ethylene Glycol)
Profile 1079 - Railcar Cleaning - Low Vapor Pressure,
Medium Viscosity Cargo (o-Dichlorobenzene)
277
278
279
280
281
282
283
284
285
286
287
288
289
290
291
292
293
294
295
296
297
298
299
300
301
302
303
304
305
306
307
308
309
310
311
312
313
314
315
316
317
319
320
19
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Page Number
SECTION 3.23
Profile 1080
Profile 1081
Profile 1082
Profile 1083
SECTION
Profile
Profile
Profile
Profile
3.24
0121
0122
0202
0203
SECTION 3.25
Profile 1084
Profile 1167
RAILCAR, TANK TRUCK, AND DRUM CLEANING
(Continued)
Railcar Cleaning - Low Vapor Pressure,
High Viscosity Cargo (Creosote)
Tank Truck Cleaning - Medium Vapor
Pressure, Medium Viscosity Cargo (Methyl
Methacrylate)
Tank Truck Cleaning - Low Vapor Pressure,
Low Viscosity Cargo (Phenol)
Tank Truck Cleaning - Low Vapor Pressure,
High Viscosity Cargo (Propylene Glycol)
SOLID WASTE DISPOSAL
Open Burning Dump - Landscape/Pruning
Bar Screen Waste Incinerator
Solid Waste Landfill Site - Class II
Solid Waste - Animal Waste Decomposition
WOOD COMBUSTION
Residential Wood Combustion (C1-C6)
Residential Wood Combustion
SECTION 3.26
Profile 1101
Profile 1186
Profile 1201
Profile 1203
MOBILE SOURCES
Light-Duty Gasoline Vehicles
Heavy-Duty Gasoline Trucks
Light-Duty Diesel Vehicles
Light-Duty Gasoline Vehicles
Emissions
Profile 1204 - Light-Duty Gasoline Vehicles
Emissions
SECTION 3.27
Profile 1097
Profile 1098
Profile 1099
AIRCRAFT
Aircraft Landing/Takeoff (LTO)
Aircraft Landing/Takeoff (LTO)
Aircraft Landing/Takeoff (LTO)
Aviation
Exhaust
Evaporative
Military
Commercial
General
SECTION
Profile
3.28
0307
FOREST FIRES
Miscellaneous Burning - Forest Fires
321
322
323
324
326
327
328
329
331
332
335
338
341
343
346
350
352
354
357
20
-------
3.1 EXTERNAL COMBUSTION BOILERS
External combustion sources include utility, industrial, commercial and
institutional boilers; commercial and domestic combustion units; process
heaters, furnaces, and kilns. Coal, oil, and natural gas are the major
fossil fuels used by these sources.
21
-------
PROFILE NAME:External Combustion Boiler - Residual Oil
PROFILE NUMBER:0001
PROFILE DATA QUALITYsB
CONTROL DEVICES UNCONTROLLED
REFERENCE(S)s58,59
DATA SOURCE:Information based on stack sample for residual oil
analysed by GC/MS.
SCC : 1030040.1 39000499 39000403 39000402 39990002 39990012 1010040:.
10200401
SARD AD CAS SPECIES MOL.. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43201 74-48-8 METHANE 16.04 11.00
43212 106-69-8 N--BUTANE 58.12 14.00
43231 110-05-3 HEXANE 86.17 5.00
43502 50-00-0 FORMALDEHYDE 3O.03 4200
43551 67-76-1 ACETONE 58.08 28,00
SUM TOTAL. 100,00
DATE :04-21-1988
22
-------
PROFILE NAMEsExternal Combustion Boiler - Distillate Oil
PROFILE NUMBER;0002
PROFILE DATA QUALITY:8
CONTROL DEVICE:Uncontrolled
REFERENCE(S)558,59
DATA SOURCE:Information based on stack sample for residual oil
analysed by GO/MS.
SCC : 10300501 10500205 39000502 10100501 39000596 39000599 39990001
39990011 10200501 10500105 39000503
3AROAD CAS
NUMBER NUMBER
43105
43106
43107
43122
43204
43212
43214
43220
43231
43232
43502
74-49-6
106-69-8
"7 ฃ% . ^ ^ - ^
/ \J D.i^. O
109-96-0
110-05-3
142-28-5
50-00-0
SPECIES
NAME
ISOMERS OF
ISOMERS OF
ISOMERS OF
ISOMERS OF
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
HEXANE
HEPTANE
HEXANE
HEPTANE
OCTANE
PENTANE
FORMALDEHYDE
MOL .
WEIGHT
86.17
100.20
114.23
72.15
44.09
58.12
58.12
72.15
86.17
100.20
30 . 03
PERCENT
WEIGHT
5 . 20
2 . 60
4.70
5 50
1 . 20
12 .20
4 . 1 0
4 . 70
10. SO
0 . 30
48 70
SUM TOTAL
100.00
DATE :04-21-1988
23
-------
PROFILE NAME:External Combustion Boiler
Natural Gas
PROF ILE NUMBER : 0003
PROFILE DATA QUALITYsB
CONTROL DEVICEsUncontrolled
REFERENCE( S):58, 59
DATA SOURCE:Information based on stack sample for natural gas
analyzed by GC/MS.
SCC : 10100601 10300601 39000602 39000603 39990003 3999001.:
5 39000699
10200601 10500106 10500206
SAROAD CAS
NUMBER NUMBER
43105
43122
43201 74-48-8
43204 74-49-6
43212 106-69-8
43220 109-96-0
43248 43-32-B
43502 50-00-0
45201 71-14-2
45202 108-88-3
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF PENTANE
METHANE
PROPANE
N-BUTANE
N-PENTANE
CYCL.OHEXANE
FORMALDEHYDE
BENZENE
TOLUENE
MOL
WEIGHT
86.17
72 . 1 5
16.04
44 . 09
58.12
72.15
84.16
30 . 03
78.11
92.13
PERCENT
WEIGHT
1 . 00
9. 00
56 . 00
4 . 00
9 . 00
6 . 00
.1 . 00
8 00
4 . 00
2 . 00
SUM TOTAL
100.00
24
DATE :04-21-1988
-------
PROFILE NAME:External Combustion Boiler - Refinery Gas
PROFILE NUMBER:0004
PROFILE DATA QUALITYsC
CONTROL DEVICE:Uncontrolled
REFERENCE( S):58, 59
DATA SOURCE:Information based on stack sample for refinery gas
analyzed by GC/MS.
3CC
10200701
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43202 74-48-0
43204 74-49-6
43205 79-92-9
43212 106-69-8
43214 75-52-5
43502 50-00-0
SPECIES
NAME
METHANE
ETHANE
PROPANE
PROPENE
N-BUTANE
ISO-BUTANE
FORMALDEHYDE
MOL,
WEIGHT
16.04
30 . 07
44 . 09
42 . 08
58.12
58.12
30 . 03
PERCENT
WEIGHT
7 . 60
20 . 90
18 ,,90
17.50
23 ,,10
4 . 40
7 60
SUM TOTAL.
100,00
DATE :04-21-1988
25
-------
PROFILE NAME:External Combustion Boiler - Coke Oven Gas
PROFILE NUMBERS 0005
PROFILE DATA QUALITY:B
CONTROL DEVICE:Uncontrolled
REFERENCE(S);58, 59
DATA SOURCE:Information based on stack sample analysed by BC/MS,
SCC
10 2 0 0 7 0 7 3 9 O 0 0 7 0 ^
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43202 74-48-0
43203 74-48-1
43205 79-92-9
43206 540-04-8
45201 71-14-2
SPECIES
NAME
METHANE
ETHANE
ETHYLENE
PROPENE
ACETYLENE
BENZENE
MOL .
WEIGHT
16.04
30.07
28.05
42 . 08
26 . 04
73.11
PERCEN"
WEIGHT
82 . 3O
2 . 50
11.70
0 . 30
0 80
1 . 90
SUM TOTAL.
100 ,,00
DATE :04-21-1988
26
-------
PROFILE MAME:Residential Fuel - Natural Gas
PROFILE NUMBER;0195
PROFILE DATA QUAL.ITY:C
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCE:Information based on composite survey data and BC/MS
analysis of grab sample.
SCC
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43201 74-48-8 METHANE 16.04 100.00
SUM TOTAL 100.00
DATE :04-21-1988
27
-------
PROFILE NAMEsCoke Oven Blast Furnace Gas
PROFILE NUMBERs0217
PROFILE DATA QUALITYsB
CONTROL DEVICE:Uncontrolled
REFERENCE(S):49
DATA SOURCE:Information based on composite survey data and GC/MS
analysis of sampling train catch.
SCC : 39000701
SAROAD
NUMBER
CAS
NUMBER-
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WE 16HT
43201 74-48-8
43202 74-48-0
43203 74-48-1
43205 79-92-9
43213 106-69-9
45201 71-14-2
METHANE
ETHANE
ETHYLENE
PROPENE
BUTENE
BENZENE
16.04
30.07
28.05
42.08
56 .10
78.11
40.90
.1 .40
2.80
5. 50
6.40
43.00
SUM TOTAL
100,00
DATE :04-21-1938
28
-------
PROFILE NAME:External Combustion Boiler - Coal-Slurry Fired
PROFILE NUMBER:1085
PROFILE DATA QUALITYsC
CONTROL DEVICE:Not reported
REFERENCE(S):16
DATA SOURCE:Information from one source test where data were
obtained using GC.
sec
10200213
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43140
43201 74-48-8
43202 74-48-0
43220 109-96-0
C7-C16
METHANE
ETHANE
N-PENTANE
163.32 39 ,,33
16.04 20.00
30.07 38.66
72.15 2.00
SUM TOTAL
100.00
DATE :04-21-1988
29
-------
PROFILE NAME:Coal-Fired Boiler - Electric Generation
PROFILE NUMBER:1178
PROFILE DATA QUALITYsE
CONTROL DEVICE:ESP
REFERENCE(S)s82
DATA SOURCE:Not described
SCC
10100202
SAROAD
NUMBER
43202
43204
43212
43213
43221
43227
43231
43232
43245
43247
43264
45202
45203
45204
45205
90014
CAS
NUMBER
74-48-0
74-49-6
106-69-8
106-69-9
78-87-4
60 -/ __ -r *--\ T
X. / / 4L. O
110-05-3
142-28-5
110-05-3
108-80-7
108-88-3
100-04-4
95-54-6
108-83-3
8720-05-9
SPECIES
NAME
ETHANE
PROPANE
N-BUTANE
BUTENE
ISO PENTANE
CIS-2-PENTENE
HEXANE
HEPTANE
1-HEXENE
2 , 4-DIMETHYLPENTANE
HEPTENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
1-DECENE
MOL .
WEIGHT
30 . 07
44 . 09
58.12
56.10
72 . 1 5
70.13
86.17
100 .20
84.16
100.20
98.18
92.13
106 ,,16
106.16
106.16
140.22
SUM TOTAL
PERCENT
WEIGHT
2 09
.1 , 78
0 98
0 . 79
1.22
1 .05
9.45
1 . 50
3 . 63
6 39
3 . 69
5 62
11.25
8.66
39 . 23
2.67
100.00
DATE :04-21-1988
30
-------
PROFILE NAME:Coal-Fired Boiler - Industrial
PROFILE NUMBER:1185
PROFILE DATA QUALITY:D
CONTROL DEVICE:Scrubber
REFERENCE(S):82
DATA SOURCE:Stack gas samples collected in Tedlar bags and analyzed
by a GC.
SCC
10200204 14
SAROAD CAS
NUMBER NUMBER
43202 74-48-0
43203 74-48-1
43204 74-49-6
43205 79-92-9
43206 540-04-8
43212 106-69-8
43213 106-69-9
43214 75-52-5
43215 11.5-51-7
43220 109-96-0
43221 78-87-4
43231 110-05-3
43247 108-80-7
43262 96-63-7
43263 591-17-4
45201 71-14-2
45202 108-88-3
45203 100-04-4
45204 95-54-6
90010 108-83-3
SPECIES
NAME
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
N-BUTANE
BUTENE
ISO-BUTANE
ISOBUTYLENE
N-PENTANE
ISO PENTANE
HEXANE
2 , 4-D I METHYLPENT ANE
METHYLCYCLOPENTANE
2-METHYL HEXANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
MOL.
WEIGHT
30 . 07
28.05
44 . 09
42 . 08
26 . 04
58.12
56.10
58. 12
56.10
72.15
72.15
86.17
100. 20
84.16
100.20
78 . 1 1
92.13
106.16
106.16
106.16
PERCENT *
WE I GHT
17.79
0 . 00
5 . 20
0.77
.1.5.43
6.38
6.09
3 . 00
0 . 00
1.18
1.24
7 . 80
0 . 00
2.90
0 . 00
3 . 78
8.39
5.67 -
2 . 60
11.76
(1
(1
(2
(2
(3
(4
(4
(3
SUM TOTAL
100.00
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species i:
assigned the weight percent.
DATE :04-21-1988
31
-------
3.2 INTERNAL COMBUSTION ENGINES
The major types of engines in this category are gas turbines and large,
heavy duty, general utility reciprocating engines. Stationary internal
combustion engines find applications in electrical power generators, in gas
pipeline pump and compressor drives and in various process industries. The
majority of gas turbines are used in electrical generation for continuous,
peaking or stand-by power. The primary fuels used are natural gas and No. 2
(distillate) fuel oil, although residual oil is used in a few applications.
32
-------
PROFILE NAME;Natural Gas Turbine
PROFILE NUMBERs 0007
PROFILE DATA (3UALITY s C
CONTROL DEVICE:Uncontrolled
REFERENCE(S);58, 59
DATA SOURCE:Composite profile developed using data based on GC/MS
analysis of fuel combustion exhaust.
SCC :
SAROAD
NUMBER
20200201
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43201 74-48-8
43502 50-00-0
METHANE
FORMALDEHYDE
16.04
30.03
SUM TOTAL
70.00
30. 00
100.00
DATE : 04-21-1.988
33
-------
PROFILE MAME:Rec.i.procating Diesel Fuel Engine
PROFILE NUMBER:0008
PROFILE DATA QUALITY:C
CONTROL DEVICEsUncontrolled
REFERENCE(S) : 53 ,:. 60
DATA SOURCE:Composite profile developed using data based on GC/MS
analysis of fuel combustion exhaust,,
SCC
2 0200401 204 00402
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43202 74-48-0
43203 74-48-1
43205 79-92-9
43206 540-04-8
43213 106-69-9
43218 106-69-0
45201 71-14-2
SPECIES
NAME
METHANE
ETHANE
ETHYLENE
PROPENE
ACETYLENE
BUTENE
1,3-BUTADIENE
BENZENE
MOL .
WE' 1 GHT
16.04
30 . 07
28.05
42 . 08
26 . 04
56.10
54.09
78 . 1 1
SUM TOTAL
PERCENT
I..JFTRHT
1 1 , 60
2 . 80
28.70
17.30
11.30
13 . 40
7 00
7 ,. 90
100 ซ 00
DATE 304-21-1988
34
-------
PROFILE NAME;Reciprocating Distillate Oil Engine
PROFILE NUMBER:0009
PROFILE DATA QUALITY:D
CONTROL DEVICE:Un con t ro11ed
REFERENCE(S):58, 60
DATA SOURCES Composite profile developed using data based on 6C/M3
analysis of fuel combustion exhaust.
20300101 20100102 20200102
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43202 74-48-0
43203 74-48-1
43205 79-92-9
43206 540-04-8
43213 106-69-9
43218 106-69-0
45201 7.1 -14 -2
SPECIES
NAME
METHANE
ETHANE
ETHYLENE
PROPENE
ACETYLENE
BUTENE
1,3-BUTADIENE
BENZENE
MOL
WEIGHT
16.04
30 . 07
28.05
42 . 08
26.04
56.10
54 ,,09
78.1.1.
PERCENT
WEIGHT
11.60
2 . 80
23 . 70
17 ,,30
1.1.30
1.3 ,,40
7 ., 00
7 ,,90
SUM TOTAL
100.00
DATE :04-21-198ฃ
35
-------
PROFILE NAME:Internal Combustion Engine - Natural Gas
PROFILE NUMBER:1001
PROFILE DATA QUALITY:B
CONTROL DEVICE:Not reported
REFERENCE(S):1
DATA SOURCE:Composite profile developed using samples taken from
two reciprocating engines operating under normal
conditions. Samples were analyzed using both a
FID/PID GC and the MBTH method.
SCC
20300201 20100202 20200204 20200202
SAROAD
NUMBER
43105
43106
43107
43108
43109
43120
43122
43124
43125
43201
43202
43203
43204
43205
43206
43212
43214
43215
43216
43217
43220
43224
43226
43228
43230
43231
43232
43233
CAS
NUMBER
74-48-8
74-48-0
74-48-1
74-49-6
79-92-9
540-04-8
106-69-8
75-52-5
115-51-7
624-46-6
590-01-1
109-96-0
109-96-1
646-60-8
513-33-9
96-61-0
110-05-3
142-28-5
111-16-9
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF BUTENE
ISOMERS OF PENTANE
C9 OLEFINS
CIO OLEFINS
METHANE
ETHANE
ETHYL.ENE
PROPANE
PROPENE
ACETYLENE
N-BLITANE
ISO-BUTANE
1SOBUTYL.ENE
T-2-BUTENE
CIS-2-BUTENE
M-PENTANE
1-PENTENE
TRANS-2-PENTENE
2-METHYL-2-BUTENE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
MOL .
WEIGHT
86. 17
100.20
114.23
128.25
142.23
56,, 10
72,15
127 ,,05
140 .27
' 16.04
30 , 07
28 . 05
44 , 09
42.08
26 . 04
58 = 12
58. 12
56 1 0
56.11
56,, 11
72 1 5
70 . 13
70. 13
70.13
86.17
86.17
100.20
114.23
PERCENT
WEIGHT
0 .
0 ,:
'- ' ,
0 ป
o
0
0 .
0 .
0.
/ 0;?
14
0
y.:!
1.
0.
1
'"' n
0
0
0
0.
0 .,
0 ซ
0 .
0.
0 .
0 .
0.
02
04
'"' '"!
01
'. ) ,-'
''' /-,
1 3
O-'"f
02
ป 69
OO
63
91
69
-.: 2
00
43
02
.1.3
02
13
0 1
0 1
01 '
02
02
02
02
36
-------
:ontinned (profile=1001
SARQAD
NUMBER
43235
43238
43241
43242
43247
43248
43261
43262
43264
43265
43269
43291
43295
43298
43502
43503
43511
45102
45109
45110
45201
45202
45203
45204
45205
45207
45208
45211
45212
45225
98040
CAS
NUMBER
111-18-2
124-41-5
1120-02-4
287-79-3
108-80-7
4~r _ ~r "? _ a
_* .ป' .iL. O
108-88-2
96 63-7
111-16-0
124-41-8
75-58-2
589-93-4
96-6 1--0
50-00-0
75-50-0
"7 Q ... D O _-. /**^
/ C) OO jL
71-14-2
108-83-3
100-04-4
95-54-6
108-83-3
108-86-8
95 56 6
611-11-3
620-01-4
526-67-8
763-32-1
SPECIES
NAME
MONAIME
N-DECANE
N-UNDECANE
CYCLOPENTANE
2 , 4-D I METHYLPENTANE
CYCLONE XANE
METHYLCYCL.OHEXANE
METHYLCYCLOPENTANE
HEPTENE
OCTENE
1-NONENE
2 , 2-D I METHYLBUTAIME
3-METHYLHEXANE
3-METHYLHEPTANE
FORMALDEHYDE
ACETALDEHYDE
I SOBUTYRALDEHYDE
ISOMERS OF XYLENE
C3/C4/C5 ALKYLBENZENES
CIO AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M- XYLENE
1,3,5-TRIMETHYLBENZENE
1,2, 4-TR I METHYLBENZ ENE
0-ETHYLTOLUENE
M-ETHYLTOLUENE
1,2, 3-TR I METHYLBENZENE
2-METHYL-l-PENTENE
MOL.
WEIGHT
.'128 . 2^
142.28
156.31
70.14
100. 20
84.16
85.16
84.16
98.13
112.21
127.05
86.17
100.20
114.23
30 . 03
44.05
72 . 1 1
106 . 16
134.21
134.22
78 . 1 1
92.13
106 ,,16
106', 16
106. 16
120.19
120.19
120.19
120.19
120.19
84.16
SUM TOTAL
PERCENT
WEIGHT
o , o i
0 . C'! 1
0 . 0 1
0 . 02
0.01
0 . 0 1
0. 02
0 . 04
0 . 0 1
0.01
0 0 1
0 . 0 1
0 . 0 1
0 . 02
0 . 8 i
0 . 03
0 . 02
0 . 02
0 , 0 i
0 . 0 .1
0 ., 1 1
0 , 04
0 . 0 i
0 ,, 0 1
0 . 0 i
0 ,, 02
0.01
0 . 0 1
0.01
0.01
0 . 02
.1. 00 . 00
37
DATE : 04-2.1-1988
-------
3.3 CARBON BLACK PRODUCTION
Carbon black is produced by the reaction of a hydrocarbon fuel such as
oil or gas with a limited supply of combustion air at temperatures in excess
of 2,000 F. The unburned carbon is collected as an extremely fine black
fluffy particle, 10 to 500 nm in diameter. The principal uses of carbon
black are as a reinforcing agent in rubber compounds (especially tires) and
as a black pigment in printing inks, surface coatings, paper and plastics.
The major process to manufacture carbon black is the oil furnace process.
Emission sources include the main process vent, the dryer vent, the
pneumatic transport system vent, the vacuum cleanup system vent, and
fugitive sources.
38
-------
PROFILE NAMEsChemical Manufacturing - Carbon Black Production
PROFILE NUMBER:1002
PROF ILE DATA QUAI... ITY ; D
CONTROL DEVICE:Uncontro11ed
REFERENCE(S):9
DATA SOURCE:Profi 1 e was developed from emiss.1 ons data t.hat was an
average of six sampling runs at a representative plant.
sec
30100504
SAROAD
NUMBER
CAS
NUMBER
43201 74-48-8
43203 74-48-1
43204 74-49-6
43206 74-48-2
432.12 106-69-8
43214 75-52-5
43933 433-35-1
43934 75-51-0
SPEC IES
NAME
METHANE
ETHYLENE
PROPANE
ACETYLENE
N-BUTANE
ISO-BUTANE
CARBONYL. SUL.FIDE
CARBON SUL.FIDE
MOL.
WEIGHT
PERCENT
WEIGHT
16.
28 n
44,
26.
58
58.
60 .
76 .
04
O5
09
04
12
12
08
14
22 . 40
1 . 40
0 . 20
40. 10
0 . 20
0 . 1 0
8 . 90
26 70
SUM TOTAL.
100.00
DATE :04-22-1988
39
-------
3.4 PAINT MANUFACTURING
Paint manufacture involves the dispersion of a colored oil or pigment,
usually in an oil or resin, followed by the addition of an organic solvent
for viscosity adjustment. Only the physical processes of weighing, mixing,
grinding, tinting, thinning, and packaging take place. No chemical
reactions are involved. These processes take place at room temperature in
large mixing tanks. The primary factors affecting VOC emissions from paint
manufacture are types of solvents used and mixing temperature.
40
-------
PROFILE NAME:Paint Manufacture - Blending Kettle
PROFILE NUMBER:1094
PROFILE DATA QUALITY:D
CONTROL DEVICEsUncontrol led
REFERENCE(S): 52
DATA SOURCE: Seven test runs were clone to sample the exit vent of
the blending kettle. Analytical method and sampling
method are not reported.
SCC : 30101401
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43552 78-89-3 METHYL ETHYL KETONE 72.10 19.35
45202 108-88-3 TOLUENE 92.13 80.65
SUM TOTAL 100.00
DATE :04-21-1988
41
-------
3.5 VARNISH MANUFACTURE
Processes involved in varnish manufacturing include mixing, blending,
and heating. Varnish is cooked in open or enclosed gas-fired kettles.
Cooking temperatures and times range from 93-340ฐC and 4-16 hours,
respectively.
42
-------
PROFILE IMAMEs Varnish Manufacturing - Bodying Oil
PROF 1L.E NUMBER s 0066
PROFILE DATA QUALITY:D
CONTROL DEVICE:Uncontrolled
REFERENCE(3):61
DATA SOURCE:Information based on engineering evaluation of survey
data.
SCC
30101501
SAROAD CAS
NUMBER NUMBER
43367
43551 67-76--1
43552 78-89-3
43560 563-38-4
SPECIES
NAME
GLYCOL ETHER
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
MOL. .
WEI BUT
106.12
59 . 08
72 ,,10
100. 16
SUM TOTAL
PERCENT
WEIGHT
3 . 00
38 . 70
41 . 60
16.70
100 . 00
DATE :04 21-1988
A3
-------
3.6 PLASTICS PRODUCTION
The manufacture of most resins or plastics begins with the
polymerization or linking of the basic monomer, usually a gas or liquid,
into high molecular weight noncrystalline solids. The manufacture of the
basic monomer is not considered part of the plastics industry; it is usually
accomplished at a chemical or petroleum plant. The manufacture of most
plastics involves an enclosed reaction or polymerization step, a drying
step, and a final treating and forming step. Treatment of the resin after
polymerization varies with the proposed use. The major VOC emission sources
in plastics manufacturing are the emissions of raw materials or monomers,
emissions of solvents or other volatile liquids during the reaction, and
emissions of solvents during storage and handling of thinned resins.
-------
PROFILE NAMEsManufacturing - Plastics -- Polypropylene
PROF ILE NUMBER:0063
PROFILE DATA GUALITYsC
CONTROL DEVICEsUncont.rolied
REFERENCE(S)s59, 60
DATA SOURCE:Information provided by polypropylene manufacturers
engineering evaluation of literature data.
SCC s 30101802
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43205 79-92-7 PROPEME 42.08 100.00
SUM TOTAL 100 ,,00
DATE :04 21-1988
45
-------
PROFILE NAMb.: Plastics Production - Polystyrene
PROF ILE NUMBER s1004
PROFILE DATA QUALITY:D
CONTROL DEVICE;Not reported
REFERENCE ( S) : 1
DATA SQURCEsEngineering judgement based on survey of plants
in South Coast Air Basin and literature review
conducted by California Air Resources Board (CARD)
SCC
30101317
SAROAD CAS
NUMBER NUMBER
45203 100-04-4
45220 100-04-5
SPECIES
NAME
ETHYLBENZENE
STYRENE
MOL .
WEIGHT
106.16
104.14
PERCENT
WEIGHT
10.00
90 . 00
SUM TOTAL
100.00
DATE :04-21-1988
46
-------
PROFILE NAME s Plastics Production - Polyester Resins
PROFILE NUMBER si005
P R 0 FIL. E D A T A QUA L. IT Y 3 E
CONTROL DEVICE:Not reported
REFERENCE(S)s1
D ATA S 0 U R C E ; E n q i n e e; r i n g j u d g e m e n t
30101.837
SAROAD CAS SPECIES MO!... PERCEN"1
NUMBER NUMBER NAME WEIGHT WEIGHT
45220 100-04-5 STYRENE 104.14 100.00
SUM TOTAL 100,00
DATE :04-22-1988
47
-------
PROFILE NAME: Plastics Production - Aery lonitri le-Bu.tadiene-
Styrene Resin
PROFILE NUMBER:i009
PROFILE DATA QUALITY:E
CONTROL DEVICES Not reported
REFERENCE(S):1
DATA SOURCE:Engineering judgement.
SCC :
SAROAD
NUMBER
30101349
CAS.
NUMBER
SPECIES
NAME
43704 107-71-1
45220 100-04-5
ACRYLONITRILE
STYRENE
MOL.
WE IGHT
53.06
104.14
PERCENT
WEIGHT
60.00
40ป00
SUM TOTAL
100.00
DATE :04-21-1988
48
-------
PROFILE NAMEsPlastics Production - Polyvinyl Chlorides and
Copolymers
PROFILE NUMBER:1091
PROFILE DATA QUALITY:C
CONTROL DEVICE:Scrubber
REFERENCE(S) s 50
DATA SOURCEsSource emission tests for vinyl chloride of two latex
incinerators. Three test runs were performed on each,
SCC : 3010.1801
SAROAD
NUMBER
43860 75-
CAS
NUMBER
-50-4
SPECIES
NAME
VINYL CHLORIDE
MOL
WEIGHT
62 . 50
SUM TOTAL
PERCENT
WEIGHT
100.00
100 n 00
DATE :04-21-1988
49
-------
3.7 PRINTING INK MANUFACTURE
The major types of printing ink are: letterpress, lithographic,
flexographic, and rotogravure inks. The ink types vary greatly in
composition. The processes involved in printing ink manufacture include:
(1) cooking the vehicle and addition of dyes, (2) grinding the pigment into
the vehicle, and (3) replacing water in the wet pigment pulp with an ink
vehicle. The ink vehicle is cooked to 93-315ฐC for 8-12 hours. Pigment and
vehicle mixing is done with dough mixers or in agitated tanks. Horizontal
or vertical mills are used for grinding.
50
-------
PROFILE: NAME sprinting Ink Cooking
PROFILE NUMBERS 0072
PROFILE DATA QUALITYnD
CONTROL DEVICE:Uncontrolled
REFERENCE(S): 62
DATA SOURCEsEngineering evaluation of organic emissions control
strategy report.
3CC
30102001
SAROAD CAS
NUMBER NUMBER
43118
43248 43-32-8
4330.1 67-7 5-- 1
43302 64-41-5
43304 67-76-0
43305 71-13-3
43435 138-82-7
43551 67-76-1
43552 78-89-3
45106
45203 100-04-4
SPECIES
NAME
MINERAL SPIRITS
CYCLOHEXANE
METHYL ALCOHOL
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
N-BLITYL ALCOHOL
M-BUTYL ACETATE
ACETONE
METHYL ETHYL. KETONE
ISOMERS OF DIETHYLBENZENE
ETHYLBENZENE
MOL .
WEIGHT
114.00
84.16
32 , 04
46 . 07
60,09
74.12
116,16
58 . 08
72.10
134.21
106.16
PERCENT
WEIGHT
25.50
5, -00
5 . 00
2.50
38 . 00
3 00
4 00
5 50
5 . 00
3 . 50
3 . OO
SUM TOTAL.
100r00
DATE :04-21-1988
51
-------
3.8 SYNTHETIC ORGANIC FIBER PRODUCTION
Semi-synthetic fibers result when natural polymeric materials such as
cellulose are dissolved or dispersed and then spun into fine filaments.
True synthetic fibers result from addition and other polymerization
reactions that form long chain molecules. The manufacture of true synthetic
fibers begins with the preparation of extremely long, chain-like molecules.
The polymer is then spun in one of four ways: melt spinning, dry spinning,
wet spinning, or core spinning. Emissions may occur during these processes
or during drying of the finished fiber.
52
-------
PROFILE NAMEsSynthetic Organic Fiber Production - Nylon Batch
Production Process
PROFILE NUMBER t1092
PROFILE DATA QUALITYsD
CONTROL DEVICE:Not reported
REFERENCE(S):51
DATA SQURCE:The evaporator vessel vent stack was sampled during
three separate evaporation cycles with one
hexamethylenediamine emissions run performed during
each cycle. Total organic carbon as carbon cations
were recalculated using a molecular weight, ratio for
conversion to hexamethylenediamine.
SCC : 30102401
SAROAD CAS SPECIES ' MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43776 124-40-4 HEXAMETHYLENEDIAMINE 116.20 100.OO
SUM TOTAL 100 ,,00
DATE :04-21-1988
53
-------
3.9 ORGANIC CHEMICAL MANUFACTURING
The organic chemical industry is a large and diverse industry producing
a large number of intermediate and end-product organic chemicals. A large
proportion of the emissions from the chemical manufacturing industry occur
as organic vapors. Organic particulate emissions may also be generated in
some processes. The emissions typically contain raw material (including
impurities) used and intermediate and final products formed during the
manufacturing process. Emissions sources include storage and handling
emissions, reactor process emissions, separation process emissions, fugitive
emissions, and secondary emissions (e.g., from waste treatment).
54
-------
PROFILE NAME:General Pesticides
PROFILE NUMBER:0076
PROFILE DATA QUALITY:C
CONTROL DEVICE:Uncontrolled
REFERENCE(S):60, 63
DATA SOURCE Engineering evaluation of information contained
within State of California pesticide use reports,
SCC
3O 1033 12 30103311
3AROAD
NUMBER
43105
43115
43116
.431 18 N
43122
43204
43212
43214
43220
43231
43805
45102
45201
45202
CAS
NUMBER
74-49-6
106-69-8
75-52-5
109-96-0
110-05-3
74-49-3
1330-02-7
71-14-2
108-88-3
SPECIES
NAME
ISOMERS OF HEXANE
C-7 CYCLOP ARAFF INS
C-8 CYCLOPARAFFINS
MINERAL SPIRITS
ISOMERS OF PENTANE
PROPANE
N-BUTANE
ISO-BUTANE -
N-PENTANE
HEXANE
METHYLENE BROMIDE
ISOMERS OF-XYLENE
BENZENE
TOLUENE
MOL-
WEIGHT
86.17
98.19
112.23
114.00
72.15
44.09
58.12
58.12
72.15
86.17
173.85
. 106.16
78.11
92.13
SUM TOTAL
PERCENT
WEIGHT
8.10
1 5 . 40
1 . 60
1 5 . 00
3.10
1 . 80
4 . 40
1 . 40
3.20
3.70
10. OO
1 5 . 00
12.30
5 . 00
100.00
DATE :08-10-1988
55
-------
PROFILE NAME:Ethylene Dichloride - Direct Chlorination
PROFILE NUMBER:0078
PROFILE DATA QUALITY:C
CONTROL DEVICE:Uncontrolled
REFERENCE(S):64
DATA SOURCE:Information obtained from ethylene dichloride storage
facility.
SCC : 30112599 30112502
SAROAD
NUMBER
CAS
NUMBER-
SPEC IES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43815 107-70-2
ETHYLENE DICHLORIDE
99.00
SUM TOTAL
100.00
100.00
DATE :04-21-1988
56
-------
PROFILE NAME:Chemical. Manufacturing - Flares
PROFILE NUMBER s 0079
PROFILE DATA QUALITY:D
CONTROL DEVICE:Uncontrolled
REFERENCE(S) : 60
DATA SOURCE:Engineering evaluation of composite survey data,
SCC
50190099
SARQAD CAS
NUMBER NUMBER
43120
43203 74-48-1
43205 79-92-9
43206 540-04-8
43213 106-69-9
43248 43-32-8
43301 .67-75-1
43302 64-41-5
43304 67-76-0
43305 -71-13-3
43438 140-08-5
43502 50-00-0
43503 75-50-0
43510 123-37-8
43601 75-52-8
43602 75-55-9
43704 107-71-1
43801 74-48-3
43812 75-50-3
43860 75-50-4
45102
45201 71-14-2
45202 108-88-3
45220 100-04-5
45300 108-89-2
45401
SPECIES
NAME
ISOMERS OF BUTENE
ETHYLENE
PROPENE
ACETYLENE
BUTENE
CYCLOHEXANE
METHYL ALCOHOL.
ETHYL ALCOHOL
ISO-PROPYL. ALCOHOL
N-BUTYL ALCOHOL
ETHYL ACRYLATE
FORMALDEHYDE
ACETAL.DEHYDE
BUTYRALDEHYDE
ETHYLENE OXIDE
PROPYLENE OXIDE
ACRYLONITRILE
METHYL CHLORIDE
ETHYL CHLORIDE
VINYL. CHLORIDE
ISOMERS OF XYLENE
BENZENE
TOLUENE
STYRENE
PHENOL
XYLENE BASE ACIDS
MOL .
WEIGHT
56.10
28.05
42.03
26.04
56.10
84.16
32 . 04
46 . 07
60 . 09
74.12
100.11
30 . 03
44.05
72.12
44.05
58 . 03
53 . 06
50 . 49
64 . 52
62 . 50
106.16
78 . 1 1
92.13
104.14
94.11
230 . 00
SUM TOTAL
PERCENT
WEIGHT
8 . 90
21 .60
9 . 00
1 00
4 1 0
1 80
5 . 40
1 . 40
2 . 50
0 . 50
0 . 80
i . 70
0 . 70
0 . 80
4 . 60
1 . 40
3 . 00
0 . 90
7.20
0 60
' 1 . 30
.1.0.00
4.10
3 . 40
2 . 00
1 . 30
100.00
57
DATE :04-21-1938
-------
PROFILE NAMEsPhthalic Anhydride -- o-Xylene Oxidation - Main
Process Stream
PROFILE NUMBER;1006
PROFILE DATA QUALITYsE
CONTROL DEVICE sNo t repor ted
REFERENCE(S):1
DATA SOURCE:Engineering judgement, based on review of literature
data (see references listed on page 113 of
Reference 1)
SCC
30101901
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
HOL, PERCENT
WEIGHT WEIGHT
43603 108-83-6
45204 95-54-6
45402 65-58-0
45601 85-54-9
MALE1C ANHYDRIDE
0-XYLENE
BENZOIC ACID
PHTHALIC ANHYDRIDE
98.06
106.16
122=13
148.00
SUM TOTAL
20. 00
10 . 0 0
10 . 00
60. 00
100.00
DATE :04-22-1988
58
-------
P R CD F11.... E N ft M E s T e r e p h t h a 1 i c A c i d / D i m e t h y 1 T e r e p h t h a 1 a t e
Crystallization., Separation and Drying Vent
PROFILE NUMBER;1023
PROF ILE DATA QUAL1TY:D
CONTROL DEVICE:Scrubber
REFERENCE(S):29
DATA SOURCE;Composite profile developed using data from two
emission sources (weighted according to emission
rates); each data set is based on engineering
calculations.
SCC : 30103103
SAROAD CAS
NUMBER NUMBER
43301 67-75-1
45450 120-06-6
SPECIES
NAME
METHYL ALCOHOL
D I METHYL TEREPHTH AL ATE
MO I, .
WEIGHT
32 . 04
.194.19
PERCENT
WEIGHT
99.97
0 . 03
SUM TOTAL .1.00.00
DATE s04-21-1988
59
-------
PROF ILE NAME s Terephtha 1 ic Ac id /Dimethy .1 Terephtha 1 ate
Distillation and Recovery Vent.
PROFILE NUMBER s 1024
PROFILE DATA QUALITY;!)
CONTROL DEVICE;Condenser
REFERENCE(S):29
DATA SOURCE:Composite profile developed using data from four
emission sources (weighted according to emission
rates); one data set is based on vent analysis, and
others are based on engineering calculations.
the
SCC
30103104
SAROAD CAS
NUMBER NUMBER
43301 67-75-1
43350 115-51-6
43432 79-92-9
43503 75-50-0
45204 95-54-6
SPECIES
NAME
METHYL ALCOHOL
DIMETHYLETHER
METHYLACETATE
ACETALDEHYDE
0-XYLENE
MOL .
WEIGHT
32 . 04
46 ป 07
74.03
44 . 05
106.16
PERCENT
WEIGHT
7,77
66,64
16 ,,33
8 = 43
0,83
SUM TOTAL
DATE :04-21-1988
60
-------
PROFILE NAMEsTerephthalie Ac id/Dimethyl Terephthai ate Product
Transfer Vent
PROFILE NUMBERS 1025
PROFILE DATA QUALITYsE
CONTROL DEVICES Not reported
REFERENCE(S):29
DATA SOURCES Information based on engineering calculations from one
emission source.
SCC
30103105
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43404 69-91-7
43432 79-92-9
43503 75-50-0
45206 106-64-3
45403 100-02-0
SPECIES
NAME
METHANE
ACETIC ACID
METHYL ACETATE
ACETALDEHYDE
P-XYLENE
TEREPHTHALIC ACID
MOL .
WEIGHT
16.04
60.05
74.08
44.05
106.16
166,, 14
PERCENT
WEIGHT
17.23
1 ,,35
75 . 00
1 . 69
3 38
1.35
SUM TOTAL
DATE :04-21-1988
61
-------
PROFILE NAMEsKetone Production - Methyl Ethyl Ketone (MEK)
PROF ILE NUMBER:1027
PROFILE DATA QUALITY:E
CONTROL DEVICE:Uncontrolled
REFERENCE(S):39
DATA SOURCE:Information based on design calculations from one
emission source.
SCC ; 30109105
SAROAD
NUMBER-
NUMBER
43314 78-89-2
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
S-BUTYL ALCOHOL
74.12
SUM TOTAL
100.00
100.00
DATE : 04-21-1983
62
-------
PROFILE NAME:Acetone - Light Ends Distillation Vent
PROFILE NUMBER:1028
PROFILE DATA QUALITYsD
CONTROL DEVICE:Scrubber
REFERENCE(S):21
DATA SOURCE:Information based on vent analysis from one emission
source.
SCC
30109153
SAROAD CAS
NUMBER NUMBER
43204 74-49-6
43205 79-92-9
43212 106-69-8
43213 106-69-9
43551 67-76-1
SPECIES
NAME
PROPANE
PROPENE
N-BUTANE
BUTENE
ACETONE
MOL.
WEIGHT
44 . 09
42 . 08
58. 12
56.10
58 . 08
PERCENT
WE I GHT
13.00
24 . 00
33 n 00
20 . 00
.1 0 * 0 0
SUM TOTAL
100.00
DATE :04-21-1988
63
-------
PROFILE NAME:Acetone - Acetone Finishing Column
PROFILE NUMBER:1029
PROFILE DATA QUALITY:D
CONTROL DEVICE:Condenser
REFERENCE(S):13
DATA SOURCE:Composite profile developed using data based on
engineering calculations from two emission sources
(weighted according to emission rates).
SCC
30109154
BAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43503 7 5--50-0
43551 67-76-1
ACETALDEHYDE
ACETONE
44.05
58.03
SUM TOTAL
38 03
61,= 97
100.00
DATE :04-21-1988
64
-------
PROFILE NAME s Aldehydes Production - Formaldehyde - Absorber-
Vent
PROFILE NUMBER:1030
PROFILE DATA QUALITY:D
CONTROL DEVICE:Scrubber
REFERENCE(S):41
DATA SOURCE:Composition data based on vent analysis from one
emission source.
SCC : 30112005
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43301 67-75-1
43430 107-73-3
43457 109-93-5
SPECIES
NAME
METHANE
METHYL ALCOHOL
METHYL FORMATE
METHYLAL
MOL .
WE I GHT
16.04
32 . 04
60. 05
76 . 09
PERCENT
WEIGHT
4.28
7.43
63 . 43
24 ,,86
SUM TOTAL
100,00
DATE 504-2.1-1988
65
-------
PROFILE NAME:Aldehydes Production - Acrolein - Distillation
System
PROFILE NUMBER:1032
PROFILE DATA QUALITYsE
CONTROL DEVICEsUncontrolled (sent to flare)
REFERENCE(S):34
DATA SOURCE;Information based on material balance from one
emission source.
SCC s
SAROAD
NUMBER
30112033
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT-
PERCENT
WEIGHT
43503 75-50-0
43505 107-70-8
ACETALDEHYDE
ACROLEIN
44.05
56.07
SUM TOTAL
.1.9 ,,58
80 ,,42
100,00
DATE s04-21-1988
66
-------
PROFILE:: NAMEs Aldehydes Production ..... Acrolein - Reactor Blcwoff
PROFILE NUMBER: 1033
PROFILE DATA QUALITY:!)
CONTROL DEVICE sUncontrol led (sent to incinerator)
REFERENCE ( S ) s 34
DATA SOURCE: Information based on analysis and material balance from
one emission source.
SCC
30112099
SAROA'D CAS
NUMBER NUMBER
43204 74-49-6
43205 1.1.5-30-i
43505 107 70--8
SPECIES
NAME
PROPANE
PROPENE
ACROLEIN
MOL .
WEIGHT
44.09
42 08
56 . 07
PERCENT
WEIGHT
24,70
37 ,,65
37,65
SUM TOTAL
100.00
DATE :04 22-1988
67
-------
PROFILE NAMEsChloroprene - Butadiene Dryer
PROFILE NUMBER:1034
PROFILE DATA QUALITYrD
CONTROL DEVICE:UncontroIled
REFERENCE(S)slO
DATA SOURCEsInformation based on analytical data from one emission
source.
SCC s 30112402
SAROAD CAS
NUMBER NUMBER
43218 106-69-0 1
SPECIES
NAME
,3-BUTADIENE
MOL .
WEIGHT
54 . 09
SUM TOTAL
PERCENT
WEIGHT
100.00
100 00
DATE :04-21-1988
68
-------
PROFILE NAMEsChloroprene - Chloroprene Stripper and Brine
Stripper
PROFILE NUMBER s1035
PROFILE DATA QUALITY:E
CONTROL DEVICE:Condenser
REFERENCE (S ) : .1.1
DATA SOURCE.: Information based on engineering calculations from one
emission source.
SCC : 30112407 30112406
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
43862 126-69-8
CHLOROPRENE
MOL .
WEIGHT
88.. 54
SUM TOTAL
PERCENT
WEIGHT
100,, 00
100.00
DATE s04-21-1988
69
-------
PROFILE NAMEsOrganohalogens - Ethylene Dichloride - Ethylene
Dichloride Via Direct. Chlorination - Distillation
Ven ts
PROFILE NUMBERS.1037
PROFILE DATA QUALITYsC
CONTROL DEVICE:Uncontrolled
REFERENCE(S):36, 37
DATA SOURCEsComposite profile developed using data based
analysis from two emission sources (weighted
to emissions rate).
on uC
according
SCC 5 30112506
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43202 74-43-0
43203 74-48-1
43812 75-50-3
43815 107-70-2
43860 75-50-4
SPECIES
NAME
METHANE
ETHANE
ETHYLENE
ETHYL CHLORIDE
ETHYLENE DICHLORIDE
VINYL CHLORIDE
M'OL .
WEIGHT
16.04
30 . 07
28.05
64 = 52
99 . 00
62 . 50
PERCENT
WEIGHT
18.35
3 29
60 . 60
6 . 62
1 .1 . 1 0
0 04
SUM TOTAL
10000
DATE :04-21-1988
70
-------
PROFILE NAMEsQrganohalogens Production - Ethylene Dichloride -
Ethylene Dichloride Via Oxychlorination
PROFILE NUMBER:1038
PROFILE DATA QUALITYsD
CONTROL DEVICE:Uncontrolled
REFERENCE(S):36
DATA SOURCEsInformation based on routine GC and wet chemistry
analyses from one emission source.
SCC : 30112501
SAROAD
NUMBER
4
4
4
4
4
4
3201
3202
3203
3812
3815
3860
CAS
NUMBER
74-48-8
74-48-
74-
75-
-48-
-50-
-0
-1
-3
107-70-2
75-
-50-4
99999
SPECIES
NAME
METHANE
ETHANE
ETHYLENE
ETHYL CHLORIDE
ETHYLENE DICHLORIDE
VINYL CHLORIDE
UNIDENTIFIED '
MOL .
WEIGHT
16
30
28
64
99
62
86
.04
. 07
.05
. 52
. 00
. 50
. 00
PERC
WE IB
3.
0
10
43
36
1 ,.
4.
73
44
a _'!
ENT
HT
8
. 40
.7
21
09
5
SUM TOTAL
1OO00.
DATE :04-21-1988
71
-------
PROFILE IMAME:Organahalogens Production - Ethylene Dichloride -
Caustic Scrubber
PROFILE NUMBER:.1039
PROFILE DATA QUALITYsC
CONTROL DEVICE!Scrubber
REFERENCE(S):36, 37
DATA SOURCE:Composite profile developed using data based on GC
analysis from two emission sources (weighted according
to emissions rate).
SCC
30112504
SAROAD CAS
NUMBER NUMBER
43201
43202
43203
43812
43815
43860
99999
74-48-8
74-43-0
74-48-1
75-50-3
107-70-2
75-50-4
SPECIES
NAME
METHANE
ETHANE
ETHYLENE
ETHYL CHLORIDE
ETHYLENE DICHLORIDE
VINYL CHLORIDE
UNIDENTIFIED
MOL .
WEIGHT
16
30
28
64
99
62
86
.04
.07
.05
. 52
. 00
50
. 00
PERCENT
WE I GHT
12
1
30
27
18
4
~\ _
.94
71
. 50
30
.19
13
2L-..<-
SUM TOTAL
100.00
DATE :04-21-1988
72
-------
P R U I- IL E NAME; FI u o r o c a r b o n s / C h 1 o r o f 1 u o r o c a r b o n s - Gene r a 1
PROF' ILE NUMBER : 1040
PROF ILE DATA QUALITY:D
CONTROL DEVICE:Condenser/uncontro1 led
REFERENCE(S):27, 42 '
DATA SOURCE:Composite profile developed using data from seven
emission sources (weighted according to emissions
rate); each data set is based on operating and design
calculations.
SCC : 30112701
SARD At
NUMBER
43811
43821
43823
43839
43840
43841
43842
43843
43844
) CAS
< NUMBER
75-56-4.
76-61-1
75-57-8
75-57-0
-v c; cr /i ฃ
f \.,' i_* T" CD
/ O "*" ฃ) .1 ~" .it!
76-61-3
76 -61 -4
75-54-7
SPEC I ES
NAME
TRICHLGROFLUOROMETHANE
TR I CHLOROTR I FLUOROETHANE
D I CHLOROD I FLUOROMETH ANE
TETRAFLUOROMETHANE
CHLOROD I FLUOROMETHANE
DICHLOROTETRAFLUORETHANE
CHLOROPEMTAFLUOROETHANE
HEXAFLUOROETHANE
TR1 FLUOROMETHANE
MO
WE
13
18
12
88
86
.1.7
.1 5
13
70
L PERCENT
I BUT WEIGHT
7.38 0.01
7 , 38 5 94
0.91 0*06
.01 10 ,,02
.47 13.91
0 . 92 4 . 29
4.47 4.76
8 ,,01 38,99
.01 22.01
SUM TOTAL. 100 ,.00
DATE :04 22-1988
73
-------
P R 0 F: IL E N A lvl E ; FI u. o r oca r b o n s / C h 1 o r a f 1 u o r o c: a r b o n s - D i s t ilia t i o n
Col Limn
PROFILE NUMBER si041
P R 0 FI!.... E D A T A QIJ A!.... IT Y : D
CONTROL DEVICE:Uncontrolled/vacuum jet
REFERENCE(S):27
DATA SOURCES Composite profile developed using data from two
emission sources(weighted according to emissions rate)
based on vent analysis, and the other on engineering
c a1c u1 a t ions.
SCC : 30112702
SAROAD CAS
NUMBER NUMBER
43804 56-62-5
4381.1 75-56-4
43823 75-57-8
43843 76-61-4
43344 7 5.... 54-7
43845 75-57-9
SPECIES
NAME
CARBON TETRACHLORIDE
TR I CHLOROFUJORQMETHANE
D I CHLOROD I FLUOROMETH ANE
HEXAFLUOROETHANE
TR I FLUOROMETHANE
CHLOROTR 1 1- LUOROMETHAME
MOL
WE 1 6HT
1 53 . 84
137 ,,38
120 91
138.01
70.01
1.04 = 46
SUM TOTAL.
PERCENT
WEIGHT
0.12
0 , 24
0 , 2 :!
79 . 54
3 . 98
.1.5 , 91
100 00
DATE :04-22-1988
74
-------
PROFILE: NUMBER;; 1042
F' R 0 F I i... E D A "i" A Q LI A1... IT Y ;; E
CONTROL. DEVICES Not reported
RE F ERE NICE (S) s 27
D A T A S 0 U i::;; C E !! I n f D r m a t i o n f r o m one? e > n i s s i. o n s o u r c e
3AROAD CAS
NUMBER NUMBER
SPECIES
NAME
MGL. PERCEi-.il"
WEIGHT HEIGHT
43811 75 56 4
43323 75 57--8
T RI C: H L 0 R 0 F i.... U 0 R 0 !v! E T H A N E
DI CHL.ORGD I FL.UOROMETHANE
SUM TOTAL
DATE s 05 02 3.9SS
75
-------
PROFILE NAME:Aery lie Acid - Quench Absorber
PROF ILE NUMBER:1043
PROFILE DATA QUALITY:E
CONTROL DEVICE:Uncontrolled
REFERENCE(S):28
DATA SOURCE:Information based on design material balance from
one emission source.
SCC
301132;
SAROAD CAS
NUMBER NUMBER
432O4 74-49-6
43205 79-92-9
43404 69-91-7
43407 79-91-7
43438 140-08-5
43503 75-50-0
43505 107-70-8
43551 67-76-1
SPECIES
NAME
PROPANE
PROPENE
ACETIC ACID
ACRYLIC ACID
ETHYL ACRYLATE
ACETALDEHYDE
ACROLEIN
ACETONE
MOL .
WEIGHT
44 . 09
42 . 08
60.05
72 . 06
100.11
44.05
56 . 07
58 , 08
PERCENT
WE I GHT
63.13
14,. 67
1. 17
15.09
1.01
0 . 03
3.77
1 . 09
SUM TOTAL
100 ,. 00
DATE s04-21-1988
76
-------
PROFILE NAMEsOrganic Acids Production - Formic Acid
PROFILE NUMBER:1044
PROFILE DATA QUALITYsD
CONTROL DEVICE:Condenser
REFERENCE(S):25
DATA SOURCEsComposite profile developed using data based on
engineering estimates from six emission sources
(weighted according to emission rates).
SCC :
SAROAD
NUMBER
30113299
CAS
NUMBER
43403 64-41-6
43404 69-91-7
43552 78-89-3
SPECIES
NAME
FORMIC ACID
ACETIC ACID
METHYL ETHYL KETONE
MOL.
WEIGHT
46.03
60 = 05
72.10
PERCENT
WEIGHT
6.67
60. OO
100.00
SUM TOTAL.
DATE 504-21-1988
77
-------
PROFILE NAMEE;Organic Acids Production - Acetic Anhydride - -
Distillation Column Vent
PROFILE NUMBER:1045
PROFILE DATA QUALITY:D
CONTROL DEVICE:Uncontrolled
REFERENCE(S):33
DATA SOURCE:Information based on typical vent analysis from one
emission source.
SCC
30113303
SAROAD CAS
NUMBER NUMBER
43404 69-91-7
43551 67-76-1
43604 108-82-7
45201 71-14-2
SPECIES
NAME
ACETIC ACID
ACETONE
ACETIC ANHYDRIDE
BENZENE
MOL,
WEIGHT
60.05
58 . 08
102.09
73.11
PERCENT
WEIGHT
58 . 00
34 n 00
6 . 00
2 . 00
SUM TOTAL
100.00
DATE :04-21-1988
78
-------
PROFILE NAMEsEsters Production - Acrylates - Ethyl Aery late
PROFILE NUMBER:1046
PROFILE DATA QUALITYsC
CONTROL DEVICEsUncontrolled
REFERENCE(S):3i
DATA SOURCE:Composite profile developed from two profiles each
based on measurement (weighted according to emissions
rate).
SCC
30113799
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43302 64-41-5
43351 60 02-7
43438 140-08-5
99933
SPECIES
NAME
METHANE
ETHYL ALCOHOL
ETHYL ETHER
ETHYL ACRYLATE
DENATURANT
MOL .
WEIGHT
16.04
46 . 07
74,12
100.11
32 . 04
PERCENT
WE I GHT
4.88
7,88
37 . 88
20,19
29= 16
SUM TOTAL.
100,00
DATE :04-21-1988
79
-------
PROFILE NAMEsEsters Production - Butyl Aery late'
PROF ILE NUMBER:1047
PROFILE DATA QUALITY:E
CONTROL DEVICE s Uncontro11ed
REFERENCE(S):28
DATA SOURCE:Information based on material balance from one emission
source.
SCC : 30113710
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.. PERCENT
WEIGHT WEIGHT
43305 71-13-3
43438 140-08-5
43440 141-13-2
N-BUTYL ALCOHOL
ETHYL. ACRYLATE
BUTYL ACRYLATE
74.12 70.38
100.11 14., 81
128,17 14.81
SUM TOTAL.
10000
DATE :04-22-1988
80
-------
PROFILE NAMErCumene Production - Cumene Distillation System
Vent
PROFILE NUMBER:1048
PROFILE DATA QUALITY:C
CONTROL DEVICEsUncontrolled
REFERENCE(S):8
DATA SOURCE:Composite profile developed using data based on gas
analyses from two emission sources (weighted according
to emissions rate).
SCC s 30115606
SAROAI
NUMBEF
43202
43204
43214
43245
45201
45203
45210
5 CAS
'< NUMBER
74-48-0
74-49-6
75-52-5
110-05-3
71-14-2
100-04-4
98-88-8
SPECIES
NAME
ETHANE
PROPANE
ISO-BUTANE
1-HEXENE
BENZENE
ETHYLBENZENE
CUMENE (1SOPROPYL BENZENE)
MOL .
WEIGHT
30 . 07
44 . 09
58.12
84.16
78.11
106.16
120.20
PERCENT
WEIGHT
1.19
53.35
0 . 89
5,47
38.47
0.61
0 . 03
SUM TOTAL 100.00
DATE :04-2.1-1983
81
-------
PROFILE MAMEsGyclohexane -'General
PROFILE NUMBER:1049
PROFILE DATA QUALITYsD
CONTROL DEVICE:Not reported
REFERENCE(S)s3
DATA SOURCE:Information based on vent stream analysis from one
emission source.
SCC :
SAROAD
NUMBER
30115701
CAS
NUMBER
SPECIES
NAME
43201 74-48-8
43202 74-48-0
43204 74-49-6
43212 106-69-8
43214 75-52-5
43220 109-96-0
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
ISO PENTANE
MOL.
WEIBHT
16,
30,
44,
58,
58,
04
07
09
12
12
15
15
PERCENT
WEIGHT
16.07
28.93
SUM TOTAL
3 04
3.04
100.00
DATE :04-21-1988
82
-------
PROFILE NAME:Cyclohexanane/Cyclahexanol - Phenol Hydrogenation
Process - Distillation Vent.
PROFILE NUMBER:1050
PROFILE DATA QUALITYsE
CONTROL DEVICE:Condenser
REFERENCE(S):12
DATA SOURCE:Information based on engineering calculations from one
emission source.
SCC : 30115822
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43248 43-32-8 CYCLOHEXANE 84.16 49.86
43317 108-89-0 CYCLOHEXANOL 100.16 10.26
43561 108-89-1 CYCLOHEXANONE 98.15 10.26
45201 71-14-2 BENZENE 78.11 25:07
45501 100-05-7 BENZALDEHYDE 106.13 4.56
SUM TOTAL 100.00
83
DATE :04-21-1988
-------
PROFILE NAMEsVinyl Acetate - Inert Gas Purge Vent
PROFILE NUMBER:1051
PROFILE DATA QUALITY:C
CONTROL DEVICE:Condenser/uncontrolied
REFERENCE(S):22, 23
DATA SOURCE:Composite profile developed from data based on vent
analyses from two emission sources (weighted according
to emission rates).
SCC
30.11670
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL,, PERCENT
WEIGHT WEIGHT
43203 74-48-1
43404 64-41-7
43453 108-80-4
99999
ETHYLENE
ACETIC ACID
VINYL ACETATE
UNIDENTIFIED
28.05
60 .05
86.09
86.00
SUM TOTAL..
74.97
4 i 8
16.68
4.17
100ป00
DATE :04-22-1988
84
-------
PROFILE NAME:Vinyl Acetate ~ C02 Purge Vent
PROFILE NUMBERS 1052
PROFILE DATA QUALITYsC
CONTROL DEVICE;Unc on tro11ed
REFERENCE*S):22, 23
DATA SOURCE:Information based on vent analyses from two emission
sources.
SCC :
SAROAD
NUMBER
30116703
CAS
NUMBER
SPECIES
NAME
MOL .
WE IGHT
PERCENT
WE IGHT
43203 74-48-1
ETHYLENE
28.05
SUM TOTAL
100 :, 00
100.00
DATE :04-21-1988
85
-------
PROFILE NAMEsVinyl Acetate - Inhibitor Mix Tank Discharge
PROFILE NUMBER:1053
PROFILE DATA QUALITYsE
CONTROL DEVICE;Not reported
REFERENCE(S):23
DATA SOURCE:Information from one emission source based on
engineering calculations.
SCC
30116704
3AROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WE 1SHT
43453 108-80-4
VINYL ACETATE
86.09
SUM TOTAL
100.00
10000
DATE :04-21-1988
86
-------
PROFILE NAMErVinyl Acetate - Refining Column Vent
PROFILE NUMBER:1054
PROFILE DATA QUALITY:E
CONTROL DEVICE:Uncontrolled
REFERENCE(S):24
DATA SOURCE:Not reported
SCC :
SAROAD
NUMBER
30116799
CAS
NUMBER
SPECIES
NAME;
MOL.
WEIGHT
PERCENT
WEIGHT
43453 108-80-4
43503 75-50-0
VINYL ACETATE
ACETALDEHYDE .
86.09
44.05
46.00
54. OO
SUM TOTAL.
100., 00
87
DATE :04-21-1988
-------
PROFILE NAMEsEthylene Oxide - Oxygen Oxidation Process
Reactor - C02 Purge Vent
PROFILE NUMBER:1056
PROFILE DATA QUALITYsD
CONTROL DEVICE:Uncontro11ed
REFERENCE(S)s35, 40
DATA SOURCE:Composite profile developed using data reported from
three plants.
SCC s 30117410
SAROAD CAS SPECIES MOL. ' PERCENT-
NUMBER NUMBER ' NAME WEIGHT WEIGHT
43203 74-48-1 ETHYLENE 28.05 100.00
SUM TOTAL 100.00
DATE :04-21-1988
88
-------
PROFILE NAME:Ethy lane Oxide - Oxygen Oxidation Process
Reactor - Argon Purge Vent
PROFILE NUMBER:1057
PROFILE DATA QUALITY:D
CONTROL DEVICE sUncontro11ed
REFERENCE(S):35, 40
DATA SOURCE?Composite profile developed from information from three
emission sources (weighted according to emission rate).
SCC
301.1.7411
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME:
MOL,
WEIGHT
PERCENT
UJ EIGHT
43201 74-48-8
43202 74---48--0
43203 74-48-1
METHANE
ETHANE
ETHYLENE
16.04
3
-------
PROFILE NAMEsEthylene Oxide - Stripper Purge Vent
PROFILE NUMBER;1053
PROFILE DATA DUALITY:E
CONTROL DEVICE;Not reported
REFERENCE(3):35
DATA SOURCE:Information based on one emission source,
30117421
SAROAD
NUMBER
4320.1. 74-
43203 74-
CAS
NUMBER
-48-8
-48-1
METHANE
ETHYLENE
SPECIES
NAME
MQL .
WEIGHT
16.04
28.05
PERCENT
' WEIGHT
24.38
75,62
SUM TOTAL 100.00
DATE 504-21-1988
90
-------
'PROFILE NAME;Methyl Methacrylate MIMA) - Hydrolysis Reactor,
MMA and Light Ends Distillation Unit
PROF I i_E NUMBER s 1059
PROFILE DATA QUALITYsD
CONTROL DEVICE:Uncontro11ed
REFERENCE(S):30
DATA SOURCE:Information based on measurements from one emission
source.
SCC s 30119012 30119010
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43301 67-75-1
43350
43430 .107-73-3
43441 80-06-6
43551 67-76-1
SPECIES
NAME
METHANE
METHYL ALCOHOL
METHYL FORMATE
METHYL. METHACRYLATE
ACETONE
MOL
WE I SHT
16.04
32.04
0 00
60 . 05
100. 13
58 . 08
PERCENT
WElHHT
1 . 79 '
4 5 5
88 88
1 ,67
0 .. 72
2 . 39
SUM TOTAL
100.00
DATE 504-22-1988
91
-------
PROFILE NAMEsMethyl Methacrylate (MMA) -- Acid Distillation and
MMA Purification
PROFILE NUMBER:1060
PROFILE DATA OUALITYsE
CONTROL DEVICE:Condenser
REFERENCE(S) 5 30
DATA SOURCE:Information based on one emission source.
sec
30119014 30119013
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL .
WEIGHT
PERCENT
'WEIGHT
43301 67-75-1
43350 115-51-6
43441 80-06-6
METHYL ALCOHOL
DIMETHYLETHER
METHYL METHACRYLATE
,
46.07
100.13
59.21
13,, 16
27.63
SUM TOTAL
100 n 00
92
DATE -.04-21-1988
-------
PROFILE NAME:Nitrobenzene - Reactor and Separator Vent - Washer
and Neutralizer Vent
PROFILE NUMBER:1061
PROFILE DATA QUALITYrE
CONTROL DEVICE:Not reported
REFERENCE(S)514
DATA SOURCE:Information based on design calculations from one
emission source.
SCC
30119502 30119504
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
45201 71-14-2
45702 98-89-3
BENZENE
NITROBENZENE
MOL.
WEI BUT
78. 11
123.11
PERCENT
WE I GMT
99..71
0,, 29
SUM TOTAL
100.00
DATE :04-21-1988
93
-------
PROF ILE NAME:Ben 2ene
PROFILE NUMBER:1062
PROFILE DATA QUALITYsD
CONTROL DEVICE:Absorber
REFERENCE(S)s 2, IS, 43
DATA SOURCE:Information based on engineering calculations from
four emission sources representing four SCC's.
SCC : 30110002 30121104 30117505 30121123
SAROAD CAS ' SPECIES MOL. PERCENT-
NUMBER NUMBER ' ' NAME WEIGHT WEIGHT
45201 71-14-2 BENZENE ' 78.11 .100.00
SUM TOTAL 100.00
DATE :04-21-1988
94
-------
PROFILE MAME;Qlet ins Production
Oil Vent.
Ethylene - Compressor Lube
PROFILE NUMBER! 1064
PROFILE DATA.QUALITY:C
CONTROL DEVICE:Not reported
REFERENCE(S):44
DATA SOURCE:Composite profiles developed using data from five
emission sources determined by helium tracer sampling
and mass spectrometer analysis (weighted according to
emission rates).
SCC
30119745
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43202 74-43-0
43204 74-49-6
43212 106-69-8
43220 109-96-0
43301 67-75-1
45201 71-14-2
45202 108-88-3
SPECIES
NAME
METHANE
ETHANE
PROPANE
N-BUTANE
N-PENTANE
METHYL ALCOHOL
BENZENE
TOLUENE
MOL .
WE I GHf
16.04
30 07
44 . 09
58.12
72.15
32,04
78,11
92.13
PERCENT
WEIGHT
12.46
37.75
23 . 86
1 5 0 .1
8 . 07
0.27
2 . 07
0.51
SUM TOTAL.
100.00
DATE :04-21-1988
95
-------
PROFILE NAME 3Propy 1 ene Oxide - Chlorchydronation Process -
General
PROFILE NUMBER;1065
PROFILE DATA GUALITYrD
CONTROL DEVICE:Scrubber
REFERENCE(S)538
DATA SOURCE:Information based on emissions data from two process
units. Data for the last three species derived from
dividing 16.50 by 3.
SCC
30120502
SARGAI
NUMBER
43201
43202
43204
43205
4383S
99999
) CAS
* NUMBER
74-4S-8
74-48-0
7 4 -4 9 -6
115-50-1
26638-81-7
SPEC II-S
.NAME
METHANE
ETHANE
PROPANE
PROPENE
PROP YLEME D I CHL.OR I DE
UNIDENTIFIED
MO
. WE;;:
16
30
44
42
1.1
86
l_ .
I SHT
. 04
07
.09
. 03
2 99
00
PERCENT
WE 1 6 HI"
0. 51
5 02
;' / ;-;;;: -;
5 50
r.'i : ,_~\ -. J
5 . 50
SUM TOTAL-
100 ,; 00
DATE s04 22-1988
96
-------
PROFILE NAMEsStyrene - General
PROFILE NUMBER:1066
PROFILE DATA QUALITYsD
CONTROL DEVICEsNot reported
REFERENCE(S):46,47
DATA SOURCEsComposite profile developed using data based on typical
composition and design information from two emission
sources.
sec
30120601
SARDAE
NUMBEF
43201
43202
43203
45201
45202
45203
45220
) CAS
* NUMBER
74-48-8
74-48-0
74-48-1
71-14-2
108-88-3
100-04-4
.100-04-5
SPECIES
NAME
METHANE
ETHANE
ETHYLENE
BENZENE
TOLUENE
ETHYLBENZENE
STYRENE
MOL .
WEIGHT
16.04
30 . 07
28.05
73 . 1 1
92. 13
106.16
104.14
PERCENT
WEIGHT
21.73
6.53
24 . 39
."> - "} r-\
t- * M l"L O
9 n 21
9 . 94
4.91
SUM TOTAL
100.00
DATE :04-21-1988
97
-------
PROFILE NAMEsStyrene - Benzene Recycle
PROFILE NUMBER:1067
PROFILE DATA QUALITYrD
CONTROL DEVICE:Condenser
REFERENCE(S):47
DATA SOURCE:Information from one emission source based on vent
analysis.
SCC : 30120602
SAROAL
NUMBEF
43201
43202
43204
43212
43220
43224
45201
) CAS
? NUMBER
74-48-8
74-48-0
74-49-6
106-69-8
109-96-0
109-96-1
71-14-2
SPECIES
NAME
METHANE
ETHANE
PROFANE
N--BUTANE
N--PENTANE
i-FENTENE
BENZENE
MOL .
WEIGHT
16,04
30 . 07
44 . 09
58.12
72.15
70.13
78 . 1 1
PERCENT
WEIGHT
34 . 72
6,10'
0.75
2.1.64
1.22
1 ,,19
34 . 38
SUM TOTAL.
100.00
DATE :04-21-1988
98
-------
PROFILE NAMEsStyrene - Styrene Purification
PROFILE NUMBER:1068
PROFILE DATA QL)ALITY:E
CONTROL DEVICE:Condenser
REFERENCE(S):46
DATA SOURCE:Information from one emission source based on
engineering calculations.
SCC : 30120603
SAROAD CAS
NUMBER NUMBER
45201 71-14-2
45202 108-88-3
45203 100-04-4
45220 100-04-5
BENZENE
TOLUENE
SPECIES
NAME
ETHYLBENZENE
STYRENE
MOL
WEIGHT
78.11
92.13
106.16
104.14
PERCENT
WEIGHT
41.46
19.51
19.51
19.51
SUM TOTAL
100.00
DATE s04-21-1988
99
-------
PROFILE: NAME;Alcohols Production - Methanol - Purge Gas Vent
PROFILE NUMBER;1070
PROFILE DATA QUALITYsC
CONTROL DEVICE:Uncontrolled
REFERENCE(S):17
DATA SOURCE:Composite profile developed using data based on mass
spectrometer analysis from two emission sources
(weighted according to emission rates).
SCC : 30125002
SAROAD
NUMBER
CAS
NUMBER'
43201 74-48-8
43301 67-75-1
43350 115-51-6
SPECIES
NAME
METHANE
METHYL ALCOHOL
DIMETHYLETHER
MOL.
WE 16HT
16.04
32.04
46.07
SUM TOTAL
PERCENT
WEIGHT
86,71
1.54
11.75
100.00
DATE :04-21-1988
100
-------
PROFILE MAMEsAlcohols Production - Methanol - Distillation Vent
PROFILE NUMBER:1071
PROFILE DATA QUALITY:D
CONTROL DEVICE!Condenser
REFERENCE(S)517
DATA SOURCE:Information from one emission source based on mass
spectrometer analysis.
SCC :
SAROAD
NUMBER
30125003
CAS
NUMBER
SPECIES
NAME
MOL.
WE ISHT
PERCENT
WEIGHT
43301 67-75-1
43350 115-51-6
METHYL ALCOHOL
DIMETHYLETHER
32.04
46. 07
1.73
98.27
SUM TOTAL
100.00
DATE : 04-21-.1.988
101
-------
PROF IHE NAME s Ch1oroben zene
Tail G a. s S c r u b ta e r
PROFILE NUMBER;1072
PROFILE DATA QUALITY:D
CONTROL DEVICE:Sc rub be r
REFERENCE(S):4, 6, 7
DATA SOURCEsComposite profile developed using data from three
emission sources (weighted according to emission
rates); one set of data is based on analysis of stack
samples and the other two on engineering calculations
SCC ; 30130101
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL .
WE I BUT
PERCENT
WEIGHT
45201 71-14-2
45301 108-39-7
45808 2531-12-6
BENZENE
CHLQROBENZENE
DICHLOROBENZENES
78.11 56.95
112.56 37=19
147,01 5.36
SUM TOTAL
DATE 504-22-1988
102
-------
PROFILE NAME:Chiorobenzene -- Benzene Drying Distillation
PROFILE NUMBER:1073
PROFILE DATA QLIALITYsD
CONTROL DEVICE:Condenser
REFERENCE(S):4, 7
DATA SOURCE:Composite profile developed using data based on
engineering caluclations from two emission source?
(weighted according to emission rates).
5CC
30130102
SAROAD
NUMBER
45201
45801
CAS
NUMBER
71-14-2
108-89-7
SPECIES
NAME
BENZENE
CHLOROBENZENE
MOL .
WE I GHT
78.11
112.56
SUM TOTAL
PERCENT
HEIGHT
95.04
4 . 96
100 . 00
DATE :04-21-1988
103
-------
PROFILE NAME sMonoc h1orobensens
PROFILE NUMBER:1074
PROFILE DATA QUALITYsD
CONTROL DEVICE;Condenser/not reported
REFERENCE(S):5, 7, 50
DATA SOURCE:Information from two emission sources representing SCC
301-301-05 and measurement data from one emission
source representing SCC 490-003-02.
SCC : 30130105 49000302
SAROAD CAS
NUMBER NUMBER
SPECIES
NAME
45801 108-89-7
CHLOROBENZENE
MOL .
WEIGHT
112.56
SUM TOTAL
PERCENT
WEIGHT
10000
100.00
DATE :04-21-1988
104
-------
P R 0 F" IL E N A M E ; C h 1 o r o b e n / e n e -- V a c u u. m 3 y s t e m Van t
PROFILE: NUMBER51075
PROFILE DATA QUALI TV:D
CONTROL DEVICE:Steam jet
REFERENCE(S):4
DATA SOURCEsComposite profile developed using data from three
emission sources (weighted according to emissions
rate). Two sets of data are based on measurement and
on e on en g i. n e e r ing c a 1 c u 1 a t i on s .
SCC : 30130106
SAROAD CAS - SPECIES HOL..
NUMBER NUMBER NAME . WEIGHT
45201 71-14-2 BENZENE 78.11 1.9.62
45301 1-08-89-7 CHLOROBENZENE 112.56 56 ,,83
45805 95-55-1 0-DICHLOROBENZENE 147.01 4,96
45806 541-17-1 M-DICHLOROBENZENE 147.01 0.63
45807 106-64-7 P-DICHLOROBENZENE 147.01 17 ,,96
SUM TOTAL.
DATE e04-22-1988
105
-------
PROF ILL NAMEsChlorobenzene - Dichlorobenzene Crystallization
PROFILE NUMBER:1076
PROFILE DATA QUALITYsE
CONTROL DEVICE:Carbon bed
REFERENCE(S)57
DATA SOURCES Information from one emission source based on
engineering estimate.
SCC : 30130107
SAROAD ' CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME ' WEIGHT WEIGHT
45807 106-64-7 P-DICHLOROBENZENE 147.01 100.00
SUM TOTAL 100.00
DATE :04-21-1988
106
-------
PROFILE NAMEjChlorobenzene - Dichlarobenzene Crystal Handling/
Loading
PROFILE NUMBER:1077
PROFILE DATA QUALITY:E
CONTROL DEVICE:Uncontrolled
REFERENCE(S);4
DATA SOURCEsInformation based on engineering calculations for one
emission source.
sec
30130108
SAROAD CAS
NUMBER NUMBER
45201 71-14-2
45801 108-S9-7
45805 95-55-1
45807 106-64-7
SPECIES
NAME
BENZENE
CHLORO BENZENE
0-DICHLOROBENZENE
P-DICHLOROBENZENE
MOL
WEIGHT
78.11
112.56
147.01
147.01
SUM TOTAL
PERCENT
WEIGHT
0 . 1 1
0 . 1 3
5.31
94.45
100 ., 00
DATE :04-21-1988
107
-------
PROFILE NAME;Fluorocarbon Manufacturing - CF 12/11
PROFILE NUMBERS 1090
PROFILE DATA QUALITYsD
CONTROL DEVICEsUncontrolled
REFERENCE(S):27
DATA SOURCEsInformation from one plant based on engineering
calculations on two emission sources.
SCC i 30112720
SAROAD CAS
NUMBER NUMBER
43804 56-62-5
43811 75-56-4
43823 75-57-8
SPECIES
NAME
CARBON TETRACHLORIDE
TRICHLOROFLUOROMETHANE
D I CHLOROD I FLUOROMETHANE
MOL .
WE I GHT
153=84
137.38
120.91
PERCENT
WEIGHT
19.90
40 76
39 . 34
SUM TOTAL 100,00
DATE :04-21-1988
108
-------
PROFILE NAMEsFluorocarbon Manufacturing - CF 23/22
PROFILE NUMBER 51093
PROFILE DATA QUALITYsD
CONTROL DEVICE;Condenser
REFERENCE(S):42
DATA SOURCE:Information from one plant based on engineering
calculations on two emission sources.
3CC : 30112730
SARQAD CAS
NUMBER NUMBER
43803 67-76-3
43840 75-54-6
43844 75-54-7
SPECIES
NAME
CHLOROFORM
CHLOROD I FLUOROMETHANE
TRIFLUOROMETHANE
MOL .
WEIGHT
119.39
86 . 47
70.01
SUM TOTAL
PERCENT
WEIGHT
2 73
33 . 34
63. 93
100.00
DATE :04-21-1988
109
-------
PROFILE NAME:ACETYLENE
PROFILE NUMBER:1120
PROFILE DATA QUALITYsE
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 30114005 30114004
SAROAD CAS
NUMBER NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43206 540-04-8
ACETYLENE
26.04
SUM TOTAL
100.00
100.00
DATE -.04-21-1988
110
-------
3.10 FOOD AND AGRICULTURE
This category includes farming operations and meat and crop processing.
Processes involved in the production of food and agricultural products
include harvesting, refinement, preservation, storage and handling, and
packaging. Refinement processes can include cleaning, drying, grinding,
mixing, and fermentation. Particulate emissions are the dominant emission
type from this source category.
Ill
-------
PR0FILE NAME:Fermentation Precesses
PROFILE NUMBER si 188
PROFILE DATA QUALITY:C
CONTROL DEVICE:Not. reported
REFERENCE(S)s 88
DATA SOURCE 5 Emissions data from four fermentation units in a
whiskey distillery analyzed by GC.
SCC : 30201004 30201003 30201002
SAROAD CAS
NUMBER NUMBER
43302 '64-41-5
43306 78-88-1
43330 123-35-3
43433 141-17-6
SPECIES
NAME
ETHYL ALCOHOL
ISOBUTYL ALCOHOL
ISOAMYL ALCOHOL
ETHYL. ACETATE
MOL .
WEIGHT
46.07
74.12
88.15
38.10
SUM TOTAL.
PERCENT
WEIGHT
99 . 56
0 . 03
0 . 09
0 . 32
100 00
112
DATE :04-21-1988
-------
3.11 PRIMARY AND SECONDARY METAL PRODUCTION
Primary metal production involves many processes which basically
produce metals in elemental form from unprocessed and impure ore. Secondary
metal operations involve the cleaning, melting, refining, and pouring of
metals recovered from scrap. Each process in primary and secondary metal
production is a potential source of emissions.
113
-------
'PROFILE NAME:; By Product. Coke Oven Stack Gas
PROFILE NUMBER s 0011
PROFILE DATA QUALITYsC
CONTROL DEVICE;Uncontrolled
REFERENCE(S):58, 59
DATA SOURCE:Composite profile based
two different coke oven
on test, samples taken from
stacks and analyzed by GC/MS,
5CC
3 0 3 0 O 3 0 4 303003 06 303 00303 30300302 30 300305
SAROAD CAS
NUMBER NUMBER
43201 74-43-8
43202 74-48-0
43203 74-48-1
43204 74-49-6
43205 79-92-9
43206 540-04-8
43213 106-69-9
43218 106-69-0
45201 71-14-2
45202 108-88-3
SPECIES
NAME
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
BUTENE
1,3-BUTADIENE
BENZENE
TOLUENE
MOL .
WEIGHT
16.04
30 . 07
28.05
44 . 09
42 . 08
26 . 04
56.10
54 . 09
78 . 1 1
92.13
PERCfc.M I"
WEIGHT
45.30
S 00
27.70
0 . 50
1 . 90
1 . 20
0.10.
0.50
14. 10
0 :, 70
SUM TOTAL
10000
114
DATE -.04-21-1988
-------
PROFILE NAME;Blast Furnace Ore Charging and Agglomerate
Charging
PROFILE NUMBER:0012
PROFILE DATA QUALITYsC
CONTROL DEVICE:Uncontrolled
REFERENCE(S)559
DATA SOURCE:Information based on one grab sample from blast furnace
exhaust.
SCC
3 0 3 0 0802 30 300801
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43822
SPECIES
NAME
METHANE
TR I METHYLFLLJOROS I LANE
MOL .
WEIGHT
16.04
92 . 00
PERCENT
WEIGHT
1 5 . 80
84 . 20
SUM TOTAL
100.00
DATE :04-21-1988
115
-------
PROFILE NAME:Iron Sintering
PROFILE NUMBER:0013
PROFILE DATA QUALITYsC
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCE:Information based on one grab sample from sintering
plant.
SCO : 30300313
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43202 74-43-0
43203 74-48-1
43205 79-92-9
43206 540-04-8
SPECIES
NAME
METHANE
ETHANE
ETHYLENE
PROPENE
ACETYLENE
MOL.
WEIGHT
16.04
30 . 07
28.05
42 . 08
26 . 04
PERCENT
WEIGHT
73 . 30
3 00
5.90
3 . 00
14.80
SUM TOTAL
100.00
DATE -.04-21-1988
116
-------
PROFILE NAME:Open Hearth l-urnace With Oxygen Lance
PROFILE NUMBER:0014
PROFILE DATA QUALITYsC
CONTROL DEVICEsElectrostatic Precipitator
REFERENCE(S):59
DATA SOURCE: Information based on two samples at. precipitator inlet
and outlet.
SCC
30300901
SAROAD CAS
NUMBER NUMBER
43231 110-05-3
43232 142-28-5
43822
45201 71-14-2
45202 108-88-3
SPECIES
NAME
HEXANE
HEPTANE
TR I METHYLFLUOROS I LANE
BENZENE
TOLUENE
MOL .
WEIIGHT
86.17
100.20
92 . 00
78.11
92 . 1 3
PERCENT
WEIGHT
7 . 00
35 ,,30
40 . 00
13 ,.60
3 60
SUM TOTAL
1.00.00
DATE :04-21-1988
117
-------
PROFILE NAME;Basic Oxygen Furnace
PROFILE NUMBER:0016
PROFILE DATA QUALITY:C
CONTROL DEVICE:Electrostatic Precipitator
REFERENCE(S)s59
DATA SOURCEsInformation based on one sample at precipitator outlet
3CC
30300913 30300914
SAROAD
NUMBER
43201
43204
43822
74
74
CAS '
NUMBER
-48-8
-49-6
METHANE
PROPANE
SPECIES
NAME
TR I METHYLFLUOROS I LANE
MOL.
WE
16
44
92
I
tt
GHT
04
09
00
PE
WE
11
39
49
R
1
N
"
CENT
GHT
10
90
00
SUM TOTAL.
100.00
DATE :04-21-1988
113
-------
P R 0 FIL E N A M E s S e c o n d a r y A1 u m i n u. m - P o u. r i n g and Casting
PROF ILE NUMBER:1036
PROFILE DATA QUALITYsD
CONTROL DEVICE;Not reported
REFERENCE(S)s 57
DATA SOURCE:Information from a laboratory study where data were
collected using liquid and gas chromatography methods,
SCC
30400114
SAROAD CAS
NUMBER NUMBER
45701 62-25-3
46110 101-16-8
46111 101-17-9
46112 103-37-9
46114 1OO-06-8
SPECIES
NAME
ANILINE
METHYLENEB I S ( C6H4NCO )
4,4-METHYLENE DIANILINE
PHENYL ISOCYANATE
4-METHYL ANILINE
MOL ,
WEIGHT
93.13
250.27
198.17
119.13
1O7.17
SUM TOTAL
PERCENT
WEIGHT
70 . 84
0 . 03
0.01
23n61.
5.51
100 . 00
119
DATE :04-21-1988
-------
PROFILE NAME:Secondary Metal Production
Pouring/Casting
PROFILE NUMBERS 1089
PROFILE DATA QUALITY:B
Gray Iron Foundries --
CONTROL DEVICE:Not reported
REFERENCE(S): 49
DATA SOURCE:Exhaust gases from twelve binder systems and sand
formulations were sampled by enclosed hood during the
pouring of gray iron. Air grab samples were analysed
by GC; reagent bubblers were analysed by ion specific
electrodes, titration, GC,, or spectrophotometric
methods; sorbent tube samples were analysed by GC
SCC : 30400320
SAROAD CAS
NUMBER NUMBER
43502 50-00-0
43505 107-70-8
43520
45201 71-14-2
45202 108-88-3
45204 95-54-6
45205 108-33-3
45300 108-89-2
45604 98-80-0
45740
46701 91-12-3
SPECIES
NAME
FORMALDEHYDE
ACROLEIN
TOTAL C2-C5 ALDEHYDES
BENZENE
TOLUENE
0-XYLENE
M-XYLENE
PHENOL
FURFURYL ALCOHOL
TOTAL AROMATIC AMINES
NAPTHALENE
MOL .
WEIGHT
30 . 03
56.07
72.12
78.11
92.13
106.16
106.16
94.11
98.10
93 . 13
123.11
PERCENT
WEIGHT
0 . 70
0 3 3
24.20
34 70
14.10
5 n 50
6. 50
6 . 40
0 . 07
7 . 42
0 . 08
SUM TOTAL.
100.oo
DATE -.04-21-1988
120
-------
PROFILE NAME:Primary Aluminum Production
PROFILE NUMBER:1202
PROFILE DATA QUALITY:D
CONTROL DEVICE:Baghouse
REFERENCE(S):95
DATA SOURCE:Average profile based on EPA Method 625 from a
Soderberg primary aluminum plant. The unidentified
species represents those pollutants detected below the
detection limit.
SCC : 30300102 30300103
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43211 760-02--3 3--METHYL-1-PENTENE 84.16 0.00 (5 )
43212 106-69-8 N-BUTANE 58.12 16.31
43213 106-69-9 BUTENE 56.10 1.35 (1 )
43214 75-52-5 ISO-BUTANE 58.12 7.22
43215 115-51-7 ISOBUTYLENE 56.10 0.00 (1 )
43216 624-46-6 T-2-BUTENE 56.11 1.60 (2 )
43217 590-01-1 CIS-2-BUTENE 56.11 1.04' (3 )
43220 109-96-0 N-PENTANE ' . 72.15 3.33
43221 78-87-4 ISO PENTANE ' - 72.15. 7.91
43222 463-38-1 2,2 DIMETHYLPROPANE 72.17 0.00 (2.)
43223 563-34-1 3-METHYL-l-BUTENE 70.13 0.19'.
43224 109-96-1 1-PENTENE 70.13 0.32' (4 )
43226 646-60-8 TRANS-2-PENTENE 70.13 0.68
43227 627-72-3 CIS-2-PENTENE 70.13 0.34
43228 513-33-9 2-METHYL-2-BUTENE 70.13 0.81
43229 107-78-5 2-METHYLPENTANE 86.17 ' 1.13 .(6 )
43230 96-61-0 3-METHYL PENTANE 86.17 0.58
43231 110-05-3 HEXANE 86.17 0.45 (8 )
43232 142-28-5 HEPTANE 100.20 0.18
43234 563-37-0 2,3 DIMETHYL-1-BUTENE 84.16 0.00 (6 )
43235 111-18-2 NONANE 128.25 0.02
43238 124-41-5 N-DECANE 142.28 0.02
43242 287-79-3 CYCLOPENTANE 70.14 0.24 (5 )
43243 78-87-5 ISOPRENE . 68.12 0.01
43245 592-24-6 1-HEXENE 84.16 0.12 (7 )
43247 108-80-7 2,4-DIMETHYLPENTANE 100.20 0.14
43250 540-08-1 2,2,4-TRIMETHYLPENTANE 114.22 0.19
43252 565-57-3 2,3,4-TRIMETHYLPENTANE 114.22
121
-------
continued (prof1Ie=i202)
3AROAD
NUMBER
43261
43262
43263
43270
43272
43274
43276
43277
43278
43279
43280
43281
43282
43283
43284
43285
43286
43289
43290
4329 i
43292
43295
43296
43297
43298
43299
45110
45201
45202
45203
45204
45205
45206
45207
45208
45209
45217
45225
45300
46701
46705
46706
46707
46708
46709
CAS
NUMBER
108-88-2
96-63-7
591-17-4
922-26-2
693-38-0
565-55-3
79-92-8
c o *~y _- f^> "t o
76O-02-4
107-70-6
503-31-3
625-52-4
75-58-2.
142-22-0 .
589-93-4
592-22-8
589-95-7
71-14-2
108-88-3
10O-O4-4
95-54-6
108-83-3
106-64-3
108-86-8
95-56-6
.103-36-1
135-50-3
526-67-8
108-39-2
91-12-3
208-89-8 .
8T TT Q
O OO T
86-67-7
35-50-8
120-01-7
SPECIES
NAME
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-METHYL HEXANE
3-METHYL-T-2-PENTENE
METHYLCYCLOPENTENE
2,3 DIMETHYL FENTANE
2,3 DIMETHYLBUTANE
2,4-DIMETHYLHEXANE
2,5-DIMETHYLHEXANE
2-ETHYL--1-BUTENE
2,3,3 TRIMETHYLFENTANE
1-BUTYNE
2-BUTYNE
C--3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
C6 OLEFINS
2,3 DIMETHYLHEXANE
. 2,2-DIMETHYLBUTANE
CYCLOPENTENE
3-METHYLHEXANE
2-METHYLHEPTANE
4-METHYLHEPTANE
3-METHYLHEPTANE
1-METHYLCYCLOHEXENE
CIO AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
1,3,5-TRIMETHYLBENZENE
1,2, 4-TRIMETHYLBENZENE
N-PROPYLBENZENE
1,2 DIETHYLBENZENE
1,2,3-TRIMETHYLBENZENE
PHENOL
NAPTHALENE
ACENAPHTHYLENE
ACENAPHTHENE
FLUORENE
PHENANTHRENE
ANTHRACENE
MOL.
WEIGHT
98.21
84.16
100.20
84.16
82.14
100.20
86.17
114.22
114.22
84.16
114.22
54.09
54 . 09 .
84.16
84.16
84.16
112.20
84.16-
114.22
86.17
68.11
100.20.
114.23
114.23
114.23
96.17
134 . 22
73.11
92.13
106.16
106. 16
106.16
106.16
120.19
120.19
120.19
134.22
120. 19
94.11
123.11
1 52 . 20
154.21
166.22
178.23
178.23
PERCENT
WEIGHT
0 . 07
0 . 43
0 . 00
0 . 00
0 . 27
0 . 00
0.31
0 . 06
0 . 00
0 . 00
0 . 0 5
0 . 00
0 . 00
0 . 00
0.18
0 . 07
0.01
0 . 09
. 0 . 00
0.21
0.1Q
0.19
0. 02
0 . 03
0 . 02
0 . 00
0 . 06
0 . 50
0 . 52
0.14
0 . 08
0 . 00
0.15
0.11
0 .08
0.01 .
0 . 0 1
0 , 03
3.35
5.74
10.10
0.61
3 . 50
7 . 30
7 . 50
(9 )
(10)
(9 )
(10)
(10)
122
-------
continued (profile=1202)
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
46710 206-64-0
46713 129-90-0
46715 218-80-9
46716 56-65-3
46719 50-03-8
90O02
90004
90005
90006
98033
98O44 496-61-7
99911
99912
99916
99917
99918
99999
FLUORANTHENE
PYRENE
CHRYSENE
BENZO (a) ANTHRACENE
BENZO (a) PYRENE
2,3,5-TRIMETHYLHEXANE
3,5 DIMETHYLHEPTANE
2,5 DIMETHYLHEPTANE
2,3 DIMETHYLHEPTANE
2,2,5-TRIMETHYLHEXANE
INDANE
3,4 DIMETHYLOCTANE
l-METHYL-3-ETHYLBENZENE
1-METHYL-3N-PROPYLBENZENE
l-METHYL-3-ISOPROPYLBENZENE
2-METHYLDECANE
UNIDENTIFIED
202.26
202.26
128.25
128.26
128.26
128.26
128.26
118.18
142.29
119.19
134.22
134.22
156.32
86.00
3,85
2 .80
0.14
0.16
0.12
0.01
0.02
0.00
0. OO
0 .08
0. 01
0.04
0.06
0.01
0.04
0. 03
6.56
SUM TOTAL
100.00
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
123
DATE :08-12-1988
-------
3.12 ASPHALT PRODUCTS
This category includes manufacture of asphalt roofing felts and
shingles that involve saturating fiber media with hot asphalt by means of
dipping and/or spraying. Preparation of the asphalt saturant (blowing)
consists of oxidizing the asphalt by bubbling air through the liquid
asphalt. Potential sources of emissions include spraying and dipping, air
blowing, hot asphalt storage, and tar kettles. Hot-mix asphalt paving
operations are also included in this category. A typical hot-mix paving
plant consists of an oil- or gas-fired rotary dryer, a screening and
classifying system, a weighing system for asphalt cement and aggregate, a
mixer, and the necessary material handling equipment. Potential sources of
emissions include the rotary dryer, asphalt-aggregate mixer, truck loading
area, and asphalt oil storage.
124
-------
PROFILE NAME;Asphalt. Roofing - Spraying
PROF1LE NUMBER:0023
PROFILE DATA QUALITYsD
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCE:Information based on composite survey data and engi-
neering evaluation of literature data.
SCC : 30500112
SAROAI
NUMBEF
43105
43106
43107
43202
43203
43204
43212
43214
43220
43231
43232
) CAS
* NUMBER
74-48-0
74-48-1
74-49-6
106-69-8
75-52-5
109-96-0'
110-05-3
142-28-5
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ETHANE
ETHYLENE
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
HEXANE
HEPTANE
MOL.
WEIGHT
86.17
100 .20
114.23
30 . 07
28.05
44.09
58.12
58.12
72.15
36.17
100.20
PERCENT
WEIGHT
1 2 . 00
11 ,,00
1 . 00
1 00
2 . 00
13 .00
18.00
8 . 00
18 . 00
2 . 00
14 . 00
SUM TOTAL
100 ,,00
DATE :04-21-1988 "
125
-------
PROFILE NAME;Asphalt Roofing Tar Kettle
PROFILE NUMBER:0024
PROFILE DATA QUALITYsC
CONTROL DEVICE;Uncontrolled
REFERENCE(S)s59
DATA SOURCEsInformation based on one sample taken with gas bottle
and charcoal tubes.
SCC
30500104
SAROAD
NUMBER
43105
43107
43115
43116
43117
43121
43122
43201
43202
43203
43204
43205
43212
43213
43214
43220
43224
43231
43232
43233
43242
45201
45202
CAS
NUMBER
74-43-8
74-43-0
74-48-1
74-49-6
79-92-9
106-69-8
106-69-9
75-52-5
109-96-0
109-96-1
110-05-3
142-28-5
111-16-9
287-79-3
71-14-2
108-88-3
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
ISOMERS OF PENTENE
ISOMERS OF PENTANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
N-BUTANE
BUTENE
ISO-BUTANE
N-PENTANE
1 -PENTENE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
BENZENE
TOLUENE
MOL .
WE I BHT
86.17
114=23
98.19
112.23
126.26
70.13
72.15
16.04
30 . 07
28.05
44 . 09
42 . 08
58.12
56.10
58.12
72.15
70.13
86.17
100.20
114.23
70.14
78 . 1 1
92.13
SUM TOTAL
PERCENT
WEIGHT
3.40
7 . 40
2 . 90
0 . 40
1 50
0 . 50
1.10
21.30
5.40
0 . 30
10.20
2 . 00
11.60
7 . 00
0 . 70
6 . 30
3.20
4 . 90
2 . 00
2 . 70
2 . 50
0 SO
1.90
1 00 ., 00
DATE :04--21-1988
126
-------
PROFILE NAMEsAsphaltic Concrete - Natural Gas Rotary Dryer
PROFILE NUMBER:0025
P R 0 FIL. E D ATA Q U A LIT Y : D
CONTROL DEVICE 5 Un contro11ed
REFERENCE(S)s6o
DATA SOURCE:Information based on test data,
30500201
SARD AD
NUMBER
43.105
43122
43201
43204
43212
43220
43248
43502
45201
45202
CAS
NUMBER
74-
74-
106
48-
49-
8
6
. jL. Q . Q
OT O
109-96
43-
"T O ..ซ
' .&.
-0
8
50-00-0
71-
108
14-
-88
'~?
!"r,
ISOMERS
ISOMERS
METHANE
PROPANE
N-BUTANE
N-PENTAN
SPECIES
NAME
OF HE XANE
OF PENTANE
E
CYCLONE XANE
FORMALDEHYDE
BENZENE
TOLUENE
MGL
WE I
86
72
16
4.4
58
'7 1?
84
30
78
92
.
B
(3
1
1
0
0
1
I
J.
HT
7
5
4
9
JM!
Fi
.16
a
0
:.'.<
.11
B
1
T
PE
WE
1.
'"/ II
56
4 it
Q
6
1.
8.
4,,
i a
RCEMT
TOUT
00
00
. 00
00
00
00
00
00
00
00
SUM TOTAL
100.00
DATE :04-21-1988
127
-------
PROFILE MAMEsAspha.lt.ic Concrete? - In Place Road Ashpalt
PROFILE NUMBER:0026
PROFILE DATA QUALITY:B
CONTROL DEVICEsUncont.ro! led
REFERENCE(S)s59
DATA SOURCE:Information based on GC/MS laboratory test samples,
SCC s 30500202
SAROAD
NUMBER
43105
43115
43122
43201
43202
43203
43204
43205
43212
43213
43214
43220
43231
45201
CAS
NUMBER
74-48-8
74-48-0
74-48-1
74-49-6
79-92-9
106-69-8
106-69-9
75-52-5
109-96-O
110-05-3
71-14-2
SPECIES
NAME
ISOMERS OF HEXANE
C-7 CYCLOPARAFFIN3
ISOMERS OF PENTANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
N-BUTANE
BUTENE
ISO-BUTANE
N-PENTANE
HEXANE
BENZENE
MOL .
WE 1 6HT
86.17
98.19
72.15
16.04
30.07
28.05
44 . 09
42 . 08
58.12
56. 10
58.12
72.15
86.17
78.11
SUM TOTAL
PERCENT
WEIGHT
8 ,,10
3.70.
5 . 70
15.70
4 . 60
~ 2 ,,00
5 . 50
3.90
10.10
5,90
1 1 . 20
5 . 30
8 . SO
9 , 50
100 .00
128
DATE :04-21-1988
-------
F:'ROFILE NAME: Mineral. Products - As p ha 1 tic Concrete
PROFILE
PROFILE
NUMBER si007
DATA QUALITY;
CONTROL DEVICE s Uncontrolled
REFERENCE(S)s1
DATA SOURCEsA composite sample made up of equal amounts of two
samples each of slow-cure asphalt was prepared and
distilled to generate organic samples representative
of emissions during application. Distillates were
analysed by GC and BC/MS.
: 30500203 10S
SAROAD
NUMBER
43111
43113
43130
43131
43238
43241
43255
43467
45107
45703
46701
46702
46711
98063
98083
CAS
NUMBER
124-41-5
1120-02-4
112-24-3
25551-11-7
91-12-3
SPEC I ES
NAME
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
C 5 SUBST I TUTED CYCLONE X ANE
C6 SUBSTITUTED CYCLDHEXANE
N-DECANE
N-UNDECANE
N-DODECANE
C4 SUBSTITUTED CYCLCHEXANGNE
TRIMETHYLBEMZENE
2 , 2 D I CHLORON I TROAN I L 1 ME
NAPTHALENE
METHYL NAPHTHALENES
C2 ALKYL INDAN
N-PENTYLCYCLOHEXANE
TRIMETI-IYLDECENE
MO!....
WEI
170
198
1 54
170
142
156
170
154
120
207
123
142
146
154
182
GHT
.32
.38
. 30
"TO
.28
.31
M O -'
26
.19
.02
.11
.20
.23
. 30
. 35
PE
IMP::
9
4
.!> ป
.<:'!. a
7 .
13
2.
8.
-.I1 u
6
10
11
2 .
5
RCENT
IGH'V
59
12
16
1.2
87
73
,56
38
89
94
54
.19
.21
04
62
SUM TOTAL.
10 0 ,, 0 0
DATE :04-22-1988
129
-------
3.13 PETROLEUM INDUSTRY
The petroleum industry includes petroleum refining and natural gas
processing. Petroleum refining involves the production of several fuels,
oils, and feeds for the petrochemical industry from crude oil. Refining
processes include distillation, conversion, treatment, and storage and
handling processes. The most significant sources of emissions include
transfer and handling operations, vacuum distillation, catalytic cracking,
thermal cracking, boilers, and heaters. Natural gas processes include
condensate removal and "sweetening."
130
-------
PROFILE NAME;Refinery Fluid Catalytic Cracker
PROFILE NUMBERS 0029
PROFILE DATA QUALITYsC
CONTROL DEVICE:Uncontro11ed
REFERENCE(S); 59
DATA SOURCE:Information based on EC/MS analysis of sampling train
catch taken with stack extension.
SCC ; 30600201
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43105
43201 74-48-8
43502 50-00-0
ISOMERS OF HEXANE
METHANE
FORMALDEHYDE
86.17
16.04
30.03
13,00
36. 00
51 .00
SUM TOTAL
100ป00
DATE 504-21-1988
131
-------
PROhlLE NAME;Refinery Fugitive Emissions - Covered Drainage/
Separation Pits
PROFILE NUMBER:0031
PROFILE DATA QUALITYsC
CONTROL DEVICE:Uncontro11ed
REFERENCE(S): 59
DATA SOURCE:Information based on five separate refinery API
separators and process drain hydrocarbons emissions
tests.
SCC s 30600504 30600503
SAROAD CAS
NUMBER NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43105
43115
43116
43122
43201
43202
43204
43212
43214
43220
4323.1
45201
74-48-8
74-48-0
74-49-6
106-69-8
75-52-5
109-96-0
110-05-3
71-14-2
ISOMERS OF HEXANE
C-7 CYCLOPARAFFINS
C-S CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE ..
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
HEXANE
BENZENE
86.17
98.19
112.23
72.15
16.04
30 . 07
44 . 09
58.12
58.12
72.15
86.17 .
78 . 1 1
12.20
16,90
5 . 20
10. 10
2 . 90
1 70
5 . 90
14.30
4 . 50
12.00
11.90
2. 40
SUM TOTAL
10 0 . 0 0
DATE -.04-21-1988
132
-------
PROFILE NAME:Refinery Fugitive Emissions - Cooling Towers
PROFILE NUMBER s 0035
PROFILE DATA QUALITY:C
CONTROL DEVICE:Uncontro11ed
REFERENCE(S)s 49
DATA SOURCE:Information based on xylene extraction and BC analysis
of water samples at inlet and outlet.
BCC
3 0600702 30600701
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MO! PERCENT
WEIGHT WEIGHT
43.122
ISOMERS OF PENTANE
72.15
SUM TOTAL
100.00
100.00
133
DATE :04-21-1988
-------
PROFILE NAME:Refinery l-ugitive Emissions - Compressor Seals
Refinery Gas
PROFILE NUMBER:0039
PROFILE DATA QUALITY:D
CONTROL DEVICE;Uncontrolled
REFERENCE(S)s 59
DATA SOURCE:Information based on composite survey data, GC/MS
analysis of grab sample taken at leak.
sec
30600804
SAROAD
NUMBER
43105
43106
43122
43201
43202
43204
43205.
43212
43213
43214
43220
43231
74-
74-
CAS
NUMBER
48-8
48-0
74-49-6
79-
92-9
106-69-8
106
75-
109
-69-9
52-5
-96-0
110-05-3
ISOMERS
ISOMERS
ISOMERS
METHANE
ETHANE
PROPANE
PROPENE
N-BUTANE
BUTENE
SPECIES
NAME
OF HEXANE
OF HEPTANE
OF PENTANE
ISO-BUTANE
N-PENTANE
HEXANE
MOL
WEIGHT
86.
.100
72.
16.
30 .
44.
42.
58.
56.
58.
72.
86.
.17
. 20
15
04
07
09
08
12
10
12
15
17
PERC
WE 1 6
1.
0.
8.
13
r
-------
PROFILE NAMEs Refinery Fugitive l-missions - Relief Valves,
Liquified Petroleum Gas
PROFILE NUMBER!0047
PROFILE DATA QUALITY:C
CONTROL DEVICE:Uncon trolled
REFERENCE(S)560
DATA SOURCE:Information based on composite survey data, engineering
evaluation of literature data.
SCC
3060080;
SAROAD CAS
NUMBER NUMBER
43202 74-48-0
43204 74-49-6
43205 79-92-9
43214 75-52-5
SPECIES
NAME
ETHANE
PROPANE
PROPENE
ISO-BUTANE
MOL.
WEIGHT
30 . 07
44 . 09
42 . 08
58,12
SUM TOTAL-
PERCENT
WEIGHT
4 . 1 0
90 40
5.10
0 . 40
100 00
135
DATE : 04-2.1-1988
-------
PROFILE NAME:F1 a res
Natural Gas
PROFILE NUMBER s 0051
PROFILE DATA QUALITYsD
CONTROL DEV ICE: Line on iro 11 ed
REFERENCE(S) :60
DATA SOURCE:Information based on composite survey data, engineering
evaluation of literature data
sec
30600903
SAROAD CAS
NUMBER NUMBE
43201 74-48-8
43202 74-48-0
43204 74-49-6
43502 50-00-0
SPECIES
R NAME
METHANE
ETHANE
PROPANE
FORMALDEHYDE
MOL .
WEIGHT
16.04
30 . 07
44 . 09
30 . 03
SUM TOTAL
PERCENT
WEIGHT
20 . 00
30 00
30 . 00
20 . 00
100 . 00
DATE :O4-21-1988
136
-------
PROF ILE NAME ; Pi pe/Va1ve F1anges
PROFILE NUMBER:0316
PROFILE DATA QUALITY:C
CONTROL DEVICE:Uncon tro11ed
REFERENCE(S):59
DATA SOURCE:Engineering evaluation of test data,
sec
30600801
SAROAD
NUMBER
43105
43106
43.107
43108
43109
43115
431.17
43122
432O1
43202
43204
43205
43212
43214
43220
43231
43232
43233
43235
43238
43248
45102
45201
45202
CAS
NUMBER
74--48-B
74-48-0
74-49-6
79-92-9
106-69-8
75-52-5
109-96-0
110-05-3
142-28-5
111-16-9
111-18-2
124-41-5
43-32-8
71-14-2
108-83-3
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
C-7 CYCLOP ARAFF INS
C-9 CYCLOP ARAFF INS
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
PROPENE
N-BUTANE
ISO-BUTANE
N-PENTANE
HEXANE
HEPTANE
OCTANE
NONANE
N-DECANE
CYCLOHEXANE
ISOMERS OF XYLENE
BENZENE
TOLUENE
MOL
WEIGHT
86.17
100 .20
114.23
128.25
142.28
98.19
126.26
72.15
16.04
30.07
44 . 09
42 . 08
58.12
58.12
72.15
86.17
100.20
. 114.23
128.25
142.28
84.16
106.16
78.11
92. 13
SUM TOTAL
PERCENT
WEIGHT
1 .60
0 . 80
0 . 40
0 . 50
0 . 30
0 n 20
'0. 10
7 . 30
28 . 60
5 . 80
1 1 . 50
0.10
18.30
7 . 40
7 . 70
3 . 40
1 . 40
1 . 80
0 . 60
0 . 80
0.10
0 . 20
0.10
0 . 50
100. 00
137
DATE :04-21-1988
-------
PROFILE NAME5Pump Seals - Composite
PROF ILE NUMBER 5 0321
PROFILE DATA QUALITYsC
CONTROL DEVICE:Uncontrolled
REFERENCE(S)s 59
DATA SOURCE:Engineering evaluation of test data,
SCC : 30600803
SAROAD
NUMBER
43105
43106
43107
43108
43109
43115
43116
43117
43122
43201
43202
43204
43212
43214
43220
43231
43232
43233
43235
43238
43248
45102
45201
45202
CAS
NUMBER
74-48-8
74-48-0
74-49-6
106-69-8
75-52-5
109-96-0
110-05-3
142-28-5
111-16-9
111-18-2
124-41-5
43-32-8
71-14-2
108-38-3
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE-
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
HEXANE
HEPTANE
OCTANE
NONANE
N-DECANE
CYCLOHEXANE
ISOMERS OF XYLENE
BENZENE
TOLUENE
MOL .
WEIGHT
86.17
100.20
114.23
128.25
142.23
93.19
112.23
126.26
72 . 1 5
16.04
30 . 07
44 . 09
58.12
58.12
72.15
86.17
100.20
1.14.23
128.25
142.28
84.16
106.16
78.11
92.13
SUM TOTAL.
PERCENT
WE 1 6HT
5 . 50
4. 10
2 . 30
3,10
1 . 90
1 . 10
0 . 1 0
0 . 80
6 . 60
3 . 30
1 .20
3 . 70
3. 10
0 . 80
11.1 0
11 .00
8 . 50
12.00
3 . 9O
5.10
0 . 50
1 . 30
0 . 5O
3 . 00
100.00
138
DATE :04-21-1988
-------
3.14 PLYWOOD PRODUCTION
Plywood is made by adhering layers of thin wood or veneers onto a wood
core. Processes involved in plywood production include: (1) sawing wood
into veneers, (2) drying, (3) application of adhesive, (4) hot press
operation, and (5) finishing. Finishing may include sanding, trimming, or
treatment.
139
-------
PR0FILE NAME s Pu1p and Paper Indus t ry - PIywood Veneer Dryer
PROFILE NUMBER;1189
PROFILE DATA QUALITYsC
CONTROL DEVICE: Not. reported
REFERENCE(S)s89
DATA SOURCEsEmissions data from 4 plywood veneer dryers analyzed by
FID/GC and GC/MS.
SBCC s 30700714 307007/15 30700711 30700712 30700713
SAROAD CAS
NUMBER NUMBER
43204 74-49-6
43256 80-05-8
43257 127-79-3
90050 5794-40-6
90051 123-33-3
90052
90053 5939-92-5
SPECIES
NAME
PROPANE
A-PINENE
B-PINENE
CAMPHENE
MYRCENE
B-PHELLANDRENE
D-LIMONENE
MOL .
WEIGHT
44.09
136.24
136.24
136.24
136.24
136.24
136.24
PERCENT
WEIGHT
0 n 03
52.71
34.44
1 .27
.1 . 87
1 . 69
7 ,,99
SUM TOTAL 100.00
DATE :04-21-1988
140
-------
3.15 SYNTHETIC RUBBER PRODUCTION
Emulsion type and solution type polymerization reactions are used to
produce styrene-butadiene copolymers. The emulsion products can be sold in
either a granular solid form, known as crumb, or in a liquid form, known as
latex. Copolymers of styrene and butadiene can be made with properties
ranging from those of a rubbery material to those of very resilient plastic.
Uncontrolled VOC emissions may pass to the atmosphere during the emulsion
crumb process and from blending/coagulation tanks and dryers.
141
-------
PR0F11...E NAME : Au tCDmo t i v e T i re s -- Tuber Ad hes i ve
PROFILE NUMBER 50272
PROFILE DATA QUALITYsC
CONTROL DEVICEsUncon trolled
REFERENCE(S):59
DATA SOURCE:Information based on composite survey data and GC/MS
^-analysis of grab sample.
SCC :
SAROAD
NUMBER
30800.1.21
CAS
NUMBER
43106
43107
43115
43116
43231
43232
43233
43248
43262
45201
45202
110-05-3
142-28-5
111-16-9
43-32-8
96-63-7
71-14-2
1 U o ~* o o "*" -<
SPECIES
NAME
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
HEXANE
HEPTANE
OCTANE
CYCLONEXANE
METHYLCYCLOPENTANE
BENZENE
TOLUENE
MOL..
WEIGHT
PERCENT
WE IRHT
100.20
114.23
98.19
1.12.23
86.17
100 ,,20
114.23
84.16
84.16
78 . 1 .1
92 . 1 3
4 . 70
0 80
43 ,, 20
6 00
5 80
1 90
0 . 40
.1.6 30
17.70
2.80
0 . 40
SUM TOTAL
100.OO
DATE :04-21-1988
142
-------
PROFILE NAMEs Automotive Tires
Tuber Adhesive White Side wall
PROF ILE NUMBER:0273
PROFILE DATA QUALITY;C
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCE:Information based on composite survey data and GC/MS
analysis of grab sample.
SCC ; 30800101 30800120
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL
WEIGHT
PERCENT
WEIGHT
43105
43106
43231 110-05-3
43242 287-79-3
43243 43-32-8
43262 96-63-7
452O1 71-14-2
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
HEXANE
CYCLOPENTANE
CYCLOHEXANE
METHYLCYCLOPEMTANE
'BENZENE
86.17
100.20
86.17
70.14
84.16
84.16
78.11.
24 .20
0 20
33. 60
0 .20
0.40
33, 70
7 . 70
SUM TOTAL
100.00
143
DATE :04-21-1988
-------
PROFILE NAME:Automobile Tire Production
PROFILE NUMBER;0274
PROFILE DATA QUALITY:C
CONTROL DEVICEsUncontrolled
REFERENCE(S): 59
DATA SOURCE:Information based on composite survey data and GC/MS
analysis of grab sample.
SCC
30102601
SAROAD
NUMBER
43.115
43116
43248 43-
43262 96-
CAS
NUMBER
-32-8
-63-7
SPECIES
NAME
C-7 CYCLOPARAFFINS
C-8 C YCLOP AR AFF I NS
CYCLOHEXANE
METHYLCYCLOPENTANE
MQL. .
WEIGHT
98,19
1.12.23
84.16
84.16
PERCENT
WEIGHT
99.84
0 08
0 04
0 04
SUM TOTAL
100.OO
DATE :04-21-1988
144
-------
PROFILE NAME: Rubber and Miscel laneous Plas.tics Products -
Fabricated Rubber Products - Styrene/Butadiene
Rubber
PROFILE NUMBER:1008
PROFILE DATA QUALITY:D
CONTROL DEVICE:Nat reported
REFERENCE(S)si
DATA SOURCE Engineering judgement based on reported emissions
(AP-42) of butadiene and styrene from the emulsion
polymerisation process.
SCC :
SAROAD
NUMBER
30800699
CAS
NUMBER
SPECIES
NAME
43218 106-69-0
45220 100-04-5
1,3-BUTADIENE
STYRENE
MQL .
WEIGHT
54 .09
104.14
PERCENT
WEI I BUT
60.00
40.00
100.00
DATE s04-21-1988
145
-------
3.16 OIL AND GAS PRODUCTION
The oil and gas production industry includes the following processes:
exploration and site preparation, drilling, crude processing, natural gas
processing, and secondary or tertiary recovery. The principal products of
this industry are natural gas and crude oil. Sources of VOC emissions from
this industry include blowouts during drilling operations, storage tank
breathing and filling losses, wastewater treatment processes, and fugitive
leaks in valves, pumps, pipes, and vessels.
146
-------
PROFILE NAME:Oil and Gas Production - Fugitives - Unclassified
PROFILE NUMBER:1010
PROFILE DATA QUALITY:D
CONTROL DEVICE;Not reported
REFERENCE( S ) s 1
DATA SOURCE;Composite
using the
Reference
count for
E^asin.
profile developed from profiles 1011, 1012
procedure described on ppป 100-112 of
Is compositing based on relative equipment
gas and liquid service for South Coast Air
SCC
31088801
SAROAD CAS
NUMBER NUMBER
43105
43106
43107
43115
43116
43122
43201
43202.
43204
43212
43214
45201
SPECIES
NAME
ISOMERS OF
ISOMERS OF
ISOMERS OF
HEXANE
HEPTANE
OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
74-48-8
74-48-0
74-49-6
106-69-8
75-52-5
71-14-2
ISOMERS OF
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
BENZENE
PENTANE
MOL .
WEIGHT
86.17
100.20
114.23
98.19
112.23
72 . 1 5
16.04
30 . 07
44 . 09
58.12
58.12
78 . 1 1
SUM TOTAL
P
ERCIZNT
WEIGHT
8
9
6
1
0
4
4
6
9
6
0
0
. 08
. 48
.99
. 30
.50
.29
6.31 '
.99
.48
.19
. 30
.10
100.00
DATE :04-21-1988
147
-------
PROFILE NAMEsO.il and Gas Production - Fugitives - Valves and
Fittings - Liquid Service
PROFILE NUMBER:1011
PROFILE DATA QUALITYsD
CONTROL DEVICE:Not reported
REFERENCE(S):1
DATA SOURCE:Based on liquid service species data developed for
American Petroleum Institute.
3CC 5 31000101
3AROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL .
WEIGHT
PERCENT
WEIGHT
43105
43106
43107
43115
43116
43122
43201 74-48-8
43202 74-48-0
43204 74-49-6
43212 106-69-8
43214 75-52-5
45201 71-14-2
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
BENZENE
86.17
100.20
114.23
98.19
112.23
72.15
16.04
30.07
44.09
58.12
58.12
78.11
SUM TOTAL
9.90
1.1.60
&. 70
.1.60
0.60
5.60
37. 6O
6.40
1O. 1.0
7 40
0,, 40
0. .10
100 n 00
DATE :04-21-1988
148
-------
PROFILE NAME: Oil and Gas Production - Fugitives - Valves and
Fittings - Gas Service
PROFILE NUMBER:1012
PROFILE DATA QUALITYsD
CONTROL DEVICE;Not reported
REFERENCE(S):1
DATA SOURCE: Based on gas service species data developed for
American Petroleum Institute.
SCC : 31000203
SAROAD CAS
NUMBER NUMBER
43105
43106
43107
43115
43116
43122
43201 74-48-8
43202 74-48-0
43204 74-49-6
43212 106-69-8
43214 75-52-5 .
4520.1 71-14-2
SPECIES
NAME
ISOMERS OF HEXANE
ISOMER3 OF HEPTANE
ISOMERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
BENZENE
MOL .
WE I GHT
86.17
100.2O
114.23
98.19
112.23
72 . 1 5
16.04
30.07
44.09
58.12
58.12
78.11
PERCENT
WEIGHT
5 . 20
6.10
4 . 60
0 . 90
0 . 30
2.10
61.30'
7 ,. 90
7 . 00
4 . 30
0 . 20
0 . 1 0
SUM TOTAL
100.00
149
DATE : 04-21-.1988
-------
3.17 TEXTILE PRODUCTS
The textile manufacturing industry converts natural and man-made fibers
into fabrics and other textile products. Fibers are processed into yarns
which are woven, knit, or otherwise processed into fabrics. The fabrics are
then dyed, printed, and/or finished. Finished fabrics are then converted
into apparel or other products such as upholstery, sheeting, and draperies
by the apparel industry. Potential emission sources include process unit
operations, vented fugitive emissions, and chemical and fuel storage tanks.
150
-------
PROFILE NAME;Tex tile Products - General Fabric Operations
Dyeing and Curing
PROF ILE NUMBER:1095
PROFILE DATA QUALITY:B
CONTROL DEVICE:Not reported
REFERENCE(S):20
DATA SOURCE:Air emissions were sampled with a modified SASS and
analyzed by GC/MS. Profile reflects composite of
weighted data from the exhaust of dyeing and curing
processes at four plants.
SCC
33000198 33000199
SAROAD
NUMBER
43132
43133
43134
43313
43408
43454
43455
43456
43460
43461
43462
43463
43464
43465
43466
43650
43780
45109
45226
45227
45228
45229
45232
45233
45310
45311
45402
45451
CAS
NUMBER
104-47-7
57-71-3
112-23-0
124-41-7
112-26-8
92-25-4
1321-17-0
103-32-7
65-58-0
131-11-3
SPECIES
.NAME
ALIPHATICS
PARAFF I NS ( C 16--C34 )
P AR AFF INS/ OLEF INS ( C 1 2-C 1 6 )
2-ETHYL HEXAMOL
PALMITIC ACID
METHYL PALMITATE
METHYL MYR1 STATE
METHYL STEARATE
METHYL Cll ESTER
METHYL C12 ESTER
METHYL. C13 ESTER
METHYL C.14 ESTER
METHYL CIS ESTER
METHYL C19 ESTER-
METHYL C20 ESTER
OXYGENATES
DIMETHYL ALKYL AMINES
C3/C4/C5 ALKYLBENZENES
BIPHENYL
METHYL BIPHENYL
ETHYL STYRENE
DI VINYL BENZENE
DIPHENYL ETHANE
ETHYL-PHENYL-PHENYL-ETHANE
C8 PHENOLS
C9 PHENOLS
BENZOIC ACID
DIMETHYL PHTHALATE
MOL.
WEIGHT
100. 00
352 , 43
197.38
130.23
256,43
270.46
242.41
298 . 52
314.28
. 338.56
362.58
386 . 60
410., 62
506 . 68
530 ป 70
86 . 00
59 . 1 1
134.21
154.21
168.24
132.21
130.02
182.27
2.10 . 3:2
122.16
136.19
122.13
194.19
PERCENT
WEIGHT
5 . 02
0 ., 78
0 . 0 7
0 . 4 1
39 54
7 , 53
0 .32
9.44
0 . 0 1
0 . 02
0 0 1
0 . 03
0 04
0 02
0 ป 0 1
0 , 1 9
0.43
2 . 07
0 . 48
0 . 1 0
0 . 54
0 . 04
0.25
O 37
0 06
0 . 26
1 49
4.27
151
-------
c a n t i n u. e d ( p r a f i 1 e::: 10 9 5 )
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL
WEIGHT
PERCENT
WEIGHT
45452
45454
45455
45470
45703
45704
45705
46102
46103
46701
46702
46703
99999
84-47-2
131-11-8.
136-66-7
1817-77-8
84
9.1-
46-1
24 1
I '? "ซ
J. 4;.. ._'
28804-48-8
DI BUTYL. PHTHALATE
DIPROPYL PHTHALATE
BUTYL BENZDATE
DI-C8 ALKYL PHTHALATE
2,2 DICHLORONITROANILINE
BROMODINITROANILINE
BROMODINITROBENZ ENE
ANTHRAQUINONE
AMINOANTHRAQUINONE
NAPTHALENE
M E T H Y L N A P H T H A L E N E S
DIM E T H Y L. N A F'T H A L E N E
UNIDENTIFIED
278
250
178
300
207
262
247
208
'""t -""i "?'
123
142
156
86.
.35
. 30
.23
. 53
.02
ป 03
.02
.23
. 23
, 11'
. 20
...^ _.,.
00
() n 29
0 . 02
22 . 07
0 47
0.12
0 . 03
0 . 96
1 ,25
(j o 04
0 . 3 7
0 .. 1 7
0 12
0 . 25
SUM TOTAL
100.00
152
DATE :04-22-1988
-------
PROFILE NAMb:Tex tile Products - General Fabric Operations -
Tenter Frame
PROFILE NUMBER:1096
F' R 0 FIL EDA T A QU A LIT Y : B
CONTROL. DEVICE : Not reported
REFERENCE(S):20
DATA SOURCEsAir emissions were sampled with a modified SASS train
and analyzed by GC/MS. Profile reflects composite of
weighted data from the exhaust of tenter frame
operations at four plants.
SCC :
SARQAD
NUMBER
43132
43133
43134
43454
43455
43456
43470
43650
43950
43951
45109
45226
45227
45228
45229
45230
45232
45233
45402
4545.1
45452
45455
45470
45703
45705
45808
45830
45831
33000104
CAS
NUMBER
112-23-0
124 --41 -7
j j s-t r*, / ฃj
1. JL .t:.. .ป:_ O O
111-18-0
556 66 jC
92-25-4
1321-17-0
103-32-7
O O " O O ""* O
131-11-3
84-47-2
136-66-7
2531-12-6
SPEC I ES
NAME
ALIPHATICS
PARAFF I NS ( C16-C34 )
PARAFF I NS/OLEF 1 NS ( C12-C16 )
METHYL PALM IT ATE
METHYL MYR1STATE
METHYL STEARATE
METHYL DODECANOATE
OXYGENATES
OCTAMETHYLCYCLOTETRAS I LOX ANE '
SILOXANE
C3./C4/C5 ALKYLBENZENE8
BIPHENYL
METHYL BIPHENYL.
ETHYL STYRENE
D I VINYL BENZENE
D I ( ETHYLPHENYL ) ETHANE
DIPHENYL ETHANE
ETHYL-PHENYL-PHEIMYL-ETHANE
BENZOIC ACID
DIMETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZOATE
DI-C8 ALKYL PHTHALATE
2 , 2 D I CHLORON I TRO AN I L I NE
BROMOD I N I TROBENZ ENE
DICHLOROBENZENES
TRICHLOROBENZENES
TETRACHLOROBENZENES
i'iOL
WEI
100
352
197
270
242
298
214
86.
2'96
76 .
134
154
168
132
130
210
182
210
122
194
278
178
300
207
247
147
181
215
6HT
. 00
.43
.38
,46
.41
ป 5 2
3 !:::i
00
,,62
08
.21
.21
.24
.21
.02
-r .-\
,27
. 32
.13
.19
.35
-p;-r,
. 53
02
. 02
,.01
.45
. 90
PEE:
WE
14
' ' .^
0 u
8.
5
1.1
0 .
0
<-;,
.1 .
....
'".''
O r
5.
On
i") ,
1 .
2..
0.
7
0 ป
20
0 ,,
0' .
1 ,,
0 .
'";,
0.
RCENT
IS.3HT
. 90
'*-"' -J.'1
02
99
84
, > r'i
. OC5
0 3
35
13
16
49
12
08
4 1
61
0 1
16
07
24
19
51
. 06
15
.11
21
13
9O
14
153
-------
c o n t i n u e c! ( p r o f i 1 e = .10 9 6 )
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL. PERCENT
WEIGHT WEIGHT
46102 84 46-1
46701 91-12-3
46702
46703 28304-48-8
99999
ANTHRAQUINONE
NAPTHALENE
METHYL NAPHTHALENES
DIMETHYL NAPTHALENE
UNIDENTIFIED
::<..) 8,
123.il
142.20
156,23
86.00
SUM TOTAL
1 .36
i . 63
0.26
0,42
0.62
100.. 00
154
DATE ;04-22-1988
-------
3.18 ORGANIC SOLVENT EVAPORATION
Organic solvent evaporation is a source of emissions with several
operations. These operations include but are not limited to: dry cleaning,
degreasing, petroleum and chemical storage, surface coating applications,
asphalt related processes, solvent use, printing, and graphic arts.
155
-------
PROFILE NAMEsPerchloroethvlene - Dry' Cleaning
PROFILE NUMBER:: COS 5
PROFILE DATA QUALITY:E
CONTROL DEVICE s Uncon tro11ed
REFERENCE( S):59, 60
DATA SOURCE;Engineering judgement.
SCC s 40100103 40100.101
SAROAB CAS ' SPECIES MO I... PERCENT
NUMBER NUMBER NAME WEK3HT WEIGHT
43817 127-71-4 PERCHLOROETHYLENE 165.83 100.00
SUM TOTAL 100,00
DATE s04-22-1988
156
-------
PROFILE NAME s Degreasing - 1,1,1 Trichloroethane
PROFILE NUMBER;0087
PROFILE DATA QUALITYsB
CONTROL DEVICE:Uncontro11ed
REFERENCE(S):49
DATA SOURCEsEngineering judgement and calculations from composite
survey data.
SCC :
SAROAD
NUMBER
40100202
CAS
NUMBER
SPECIES
NAME
MOL..
WEIGHT
43814 71-15-6
1,1,1-TRICHLOROETHANE
133.42
SUM TOTAL.
PERCENT
WE IGHT
100.00
100.00
DATE :04-21-1988
157
-------
PR0FILE MAME:D egreasing - T r i c h1o ro f1u o rome t h a ne (Freon 11)
PROFILE NUMBER:0088
PROFILE DATA QUALITY:E
CONTROL DEVICE:Uncontro11ed
REFERENCE(S):59
DATA SOURCEsEngineering judgement and calculations from composite
survey data.
SCC ; 40100258
SARGAD CAS SPECIES MOL. PERCENT-
NUMBER NUMBER NAME WEIGHT WEIGHT.
43811 75-56-4 TRICHLOROFLUOROMETHANE 137.38 100 ,,00
SUM TOTAL. 100 = 00
DATE :04-22-1988
158
-------
PROFILE NAME: Deqreasing - 1 ,, I 2-Trich loroethane
PROFILE NUMBERS 0089
PROFILE DATA QUALITYsE
CONTROL. DEVICE : Uncon tro 1 1 ed
REFERENCE(S)s 59
DATA SOURCE:Engineering judgement and calculations from composite
survey data-
40100259
SAROAD CAS SPECIES - MQL. PERCENT
NUMBER NUMBER NAME " WEIGHT UJEIGHT
43820 79-90-5 1,1,2-TRICHLOROETHANE 1-33.42 100.00
SUM TOTAL 100.00
DATE :04-22-1988
159
-------
PROFILE NAMEsDegreasing - Toluene
PROFILE NUMBERS 0090
PROFILE DATA QUALITY:E
CONTROL DEVICE s Un contro11ed
REFERENCE(S) s 59
DATA SOURCE: Engineering judgement,, calculations from composite
survey data.
SCC ! 40100256 40100206
SAROAD CAS SPECIES - MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
45202 108-88-3 TOLUENE 92.13 100.00
SUM TOTAL. 100.00
DATE :04-22-1988
160
-------
PROFILE NAME;Solvent Use - Domestic Solvents
PROFILE NUMBER:0197
PROFILE DATA QUALITY;D
CONTROL DEVICEsUncontrolled
REFERENCE(S):59
DATA SOURCEsEngineering evaluation of literature test data,
SCC s 95
SAROAD CAS
NUMBER NUMBER
43214 75-52-5
43302 64-41-5
43304 67-76-0
43367
43369 57-75-6
43435 133-82-7
43502 -50-00-0
43551 67-76-1
45101
SPECIES
NAME
ISO-BUTANE
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
GLYCOL ETHER
PROPYLENE GLYCOL
N-BUTYL ACETATE
FORMALDEHYDE
ACETONE
NAPHTHA
MOL
WEIGHT
58.12
46 . 07
60 . 09
106,12
76.00
1.16.16
30 03
58 . 08
114.00
PERCENT
WE 1 GHT
5 . 30
36.90
38 . 50
8 . 30
3 . 2O
1 . 30
0 . 60
.1 . 40
4 . 50
SUM TOTAL 100.00
DATE :04-21-1988
161
-------
PROFILE NAME 5Deqreasinq - TrichIoroethylene
PROFILE NUMBER;! 0271
PROFILE DATA QUALITY:E
CONTROL DEVICE sUncontrolled
REFERENCE(S):71
DATA SOURCE: Engineering judgement.; information based on composite
survey data and inspection of solvent formulation.
SCC s 40100255
SARQAI) CAS SPECIES MOL.
NUMBER NUMBER NAME . . WEIGHT
43824 79-90-6 TRICHLQRQETHYLENE 131.40 100,00
BUM TOTAL-
DATE s04-22-1988
162
-------
P R 0 FIL E N A M E :: D e g r e a s i n g - I) i c h 1 o r o m ethane
PROFILE NUMBER:0275
PROFILE DATA QUALITY:E
CONTROL DEVICE!Uncontro11ed
REFERENCE(3):59
DATA SOURCE:Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC : 40100224 40100302 40100254 40100204
SAROAD
NUMBER
43802
' CAS
NUMBER
75-50-2
SPECIES
NAME
METHYLENE CHLORIDE "
MO!
WEIGHT
84.93
SUM TOTAL
PER
WEI
100
100
CENT
!.:;!-! T
. 00
. 00
DATE :04-22-1988
163
-------
PRQFILfc. NAME:Deqreasinq - Trichlorotrifluoraethane (Freon 113)
PROFILE NUMBER:0277
PROFILE DATA QUALITYsE
CONTROL DEVICE : Lincon t ro 1 1 ed
REFERENCE(S):59
DATA SOURCE: Engineering .judgement; information based on composite
survey data and inspection of solvent formulation.
SCC : 40100106 40100257 40100207 40100105
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43821 76-61-1 TRICHLOROTR'IFLUOROETHANE 187.38 1OO.OO
SUM TOTAL 100.00
DATE :04-22-1988
164
-------
P R 0 FIL E N A M E :D e g r e a s i n g - 0 p e n "I" o p - C h 1 o r o sol v e
PROF ILE NUMBER:1021
PROFILE DATA QUALITYsE
CONTROL DEVICE;Not reported
REFERENCE(S):1-
DATA SOURCE:Engineering .judgement.
SCC
40100208
SARD AD
NUMBER
CAS
NUMBER
43302 64-41-5
43802 75-50-2
SPECIES
NAME
ETHYL ALCOHOL.
DICHLOROMETHANE
MOL .
WEIGHT
46.07
84.94
SUM TOTAL
PERCEM'
WEIGHT
100.00
DATE : 04-21-1988
165
-------
PROF ILE NAME:FURFURAL
PROFILE NUMBER:1142'
PROFILE DATA QUALI TV : E
CONTROL DEVICE s Contro11ed/Uncontro11ed
REFERENCE(S)s 76
DATA S'OURCEsEngineering judgement.
SCC ; 49000104
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL. PERCENT
WEIGHT UiFIhHT
45503 98-80-1
2-FURFURAL
96.O9
SUM TOTAL.
100.00
'I OO . 00
DATE ;04-22-1988
166
-------
PROF ILE NAME : METHANOL
F:'ROF I LE NUMBER : 1149
PROFILE DATA QUALITYsE
CONTROL DEVICE:Controlled/Uncontrol led
REFERENCE(S):76
DATA SOURCE: Engines ring .judgement.
SCC s 40100301
SAROAD
NUMBER
CAS
NUMBER
SPEC IES
NAME
MO I. .
WEIGHT
F'ERCEN"
WEIGHT
43301 67-75-1
METHYL ALCOHOL
32.04
SUM TOTAL.
100.00
100OO
DATE :04-22-1988
167
-------
PROFILE NAME sDegreasing
PROFILE NUMBER:1192
PROFILE DATA QUALITY:B
CONTROL DEvICE:Unc on t ro11ed
REFERENCE(S)5 90
DATA SQURCEsSix mineral spirit samples from two companies combined
in equal amounts by volume. Headspace analyzed by
GC/MS. 1974 consumption data used to combine mineral
spirit composite with pure chlorinated solvents.
SCC : 40100221 40100201 40100303 40.100251
BAROAD
NUMBER
43109
43110
43110
43110
43111
43111
43111
43112
43113
43113
43124
43124
43124
43125
43125
43125
43125
43125
43125
43135
43138
43138
43141
43146
43146
43146
43146
43146
CAS SPECIES
NUMBER NAME
ISOMERS OF DECANE
ISOMERS OF UNDECANE
ISOMERS OF UNDECANE
ISOMERS OF UNDECANE
ISOMERS OF DODECANE
ISOMERS OF DODECANE
ISOMERS OF DODECANE
ISOMERS OF TR I DECANE
ISOMERS OF TETRADECANE
ISOMERS OF TETRADECANE
C9 OLEFINS
C9 OLEFINS
C9 OLEFINS
CIO OLEFINS
CIO OLEFLNS
CIO OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO PARAFFIN
C-8 OLEFINS
C-8 OLEFINS
C8 PARAFFIN
Cll OLEFIN
Cll OLEFIN
Cll OLEFIN
Cil OLEFIN
Cll OLEFIN
MOL .
WEIGHT
142.28
1 56 . 30
156.30
1 56 . 3O
170.32
170.32
170.32
184.36
198.38
198.38
127,05
127.05
127.05
140.27
140.27
140.27
140.27
140.27
140.27
142.28
112.23
112.23
114.23
154.29
154.29
154.29
154.29
154.29
PERCEN'1
WEIGHT
4.36
0 . 00
3 . 03
0 00
0 . 26
0,18
0 . 47
0 . 03
0 , 09
0.01'
0 . 00
0 . 00
0 <. 00
0 . 04
0 . 00
1.11
0 . 00
0 . 00
0 . 00
0 . 00
0 . 49
0.51
0 . 00
0 , 00
0 . 06
0 . 00
0 . 00
0 . 23
(15)
(17)
(25)
(2 )
(5 )
(3 )
(10)
(7 )
(4 )
(8 )
(6 )
(6 )
(1 )
(1 )
(16)
(13)
( 1 5)
(14)
168
-------
continued (profile=1192)
SAROAD CAS
NUMBER NUMBER
43146
43146
43147
43147
43147
43147
43147
43.147
43148
43148
43150 825-55-4
43151
43152
43231 110-05-3
43232 142-28-5
43235 111-18-2
43261 108-88-2
43238 1673-89-7
43565
45105
45105
45.105
45105
45105
45105
45105
45105
45105
45105
45105
45105
45107 25551-11-7
45108
45108
45202 108-88-3
45204 95-54-6
45210 98-88-8
45240 103-36-1
45245
45245
45245
45245
45245
45303
45304
SPECIES
NAME
Cll OLEFIN
Cll C3LEFIN
C12 OLEFIN
C12 OLEFIN
C12 OLEFIN
C12 OLEFIN
C12 OLEFIN
C12 OLEFIN
C9H16
C9H16
C10H18
C11H20
C12H22
HEXANE
HEPTANE
NONANE
METHYLCYCLOHEXANE
ETHYLCYCLOHEXANE
D I METHYLC YCLOBUT ANONE
ISOMERS OF BUTYLBENZEME
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBEMZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
ISOMERS OF PROPYLBENZENE
TOLUENE
0-XYLENE
CUMENE (ISOPROPYL BENZENE)
PROPYLBENZENE
C5-ALKYLBENZENE
C5-ALKYLBENZENE
C5-ALKYLBENZENE
C5-ALKYLBENZENE
C5-ALKYLBENZENE
C4-ALKYLPHENOL
C5-ALKYLPHENOL
MOL .
WEIGHT
154.29
154.29
168.32
168.32
168.32
168.32
168.32
1.68.32
124.23
124 . 23
138.25
152.23
166.31
86.17
100.20
123.25
85.16
112.23
98.14
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
120.19
120.19
120.19
92.13
106.16
120.20
120.20
145.25
145.25
145.25
145.25
145.25
150.2.2
164.25
PERCENT
WEIGHT
0 . 00
0 . 00
0 . 00
0.02
0 . 00
0 . 04
0 . 0 1
0 s 00
0 ,, 32
0 . 0 7
0 . 00
0 . 00
0 . 00
0 ,. 1 3
27. 59
2.S4
5.97
0.26
0.19
0.12
0 . 09
0 ,. 00
0 . 1 0
0 , 00
0 . 09
0 . 03
0 . 04
0.04
0 . 1 0
0 . 69
0 . 03
1.00
0.15
0 . 76
20 . 88
0 . 57
0.11
0 . 1 5
0 . 00
0 . 00
0 . 00
0 . 02
0 . OS
0.12
0 . 00
(24)
(13)
(26)
( 32 )
(22)
(25)
(27)
(3 )
( 1 .1. )
( 13)
(32)
(22)
(24)
( 20 )
(19)
(.29)
(21)
(9 )
(B )
(17)
(12)
(16)
(7 )
(6 )
( 28 )
( 30 )
(27)
(26)
(33)
169
-------
continued (profile-1192)
SAROAD CAS SPECIES
NUMBER NUMBER NAME
45304 C5-ALKYLPHENOL
45320 DI METHYL-BENZYL ALCOHOL
45808 DICHLOROBENZENES
46202 OCTAHYDROINDENE
46202 OCTAHYDROINDENE
46601 2782-29-4 TETRAMETHYLTHIOUREA
46701 91-12-3 NAPTHALENE
46747 METHYLINDAN
46748 METHYLDECALIN
46748 METHYLDECALIN
46748 METHYLDECALIN
46748 METHYLDECALIN
46748 METHYLDECALIN
46748 METHYLDECALIN
46753 91-11-8 DECALIN
90010 108-83-3 M-XYLENE AND P-XYLENE
90028 METHYLHEXANE
90029 METHYLHEXENE
90047 METHYLMONANE
90048 METHYLDECANE
90049 METHYLUNDECANE
90064 DIMETHYLCYCLOPENTANE
90066 NONADIENE
90067 DIMETHYLHEXANE
90070 DIMETHYLOCTANE
90070 DIMETHYLOCTANE
90071 DIMETHYLUNDECANE
90072 METHYLPROPYLCYCLOHEXANE
90073 METHYLISOPROPYLCYCLOHEXANE
90075 ETHYLOCTENE
90076 DIMETHYLNONANE
90076 DIMETHYLNQNANE
90077 ETHYLOCTANE
90080 ETHYLMETHYLCYCLOPENTANE
90081 ETHYLHEXANE
90083 ETHYLMETHYLCYCLOHEXANE
90085 ETHYLMETHYLOCTANE
90089 ETHYLDIMETHYLCYCLOHEXANE
90090 ETHYLPROPYLCYCLOHEXANE
90090 ETHYLPROPYLCYCLOHEXANE
90091 TETRAMETHYLCYCLOBUTENE
90094 TRIMETHYLHEPTANE
90096 TRIMETHYLOCTANE
90096 TRIMETHYLOCTANE
90098 TETRAMETHYLCYCLOPENTANE
MOL .
WE 1 6HT
164.25
122.16
147.01
244 . 00
244 . 00
132.25
123.11
132 . 21
170.34
170.34
170.34
170.34
170.34
170.34
138.25
106. 16
100.20
93.18
142.28
156.32
170.34
99.19
124.23
114.23
140.27
140.27
184.36
168.32
140.27
100.16
211.41
211.41
142.29
112.21
114.23
126.24
156.31
141.27
154.29
154.29
110.19
142.29
156.31
156.31
126.24
PERCEN'
WEIGHT
0 . 06
0.05
0 . 00
0 . 08
0 . 04
0 .02
0 . 1 0
0 . 0 1
0 . 00
0 . 0 5
0 . 00
0 . 00
0 . 03
0 00
0.19
0 . 76
4,, .16
0 , 40
2.46
1 46
0.10
2.31
0 . 07
1 . 09
0 . 39
0 . 59
0 . 00
0.65
0.18
0.14
0.21
0 . 49
0 . 08
0-. 02
0.16
2.24
0.22
0 . 04
0 . 00
0 . 20
0.01
0.71
0 . 1 5
0 . 00
0 . 22
T
(9 )
(15)
( 33 )
(23)
(25)
(10)
(11 )
(21)
(18)
*
(2 )
(4 )
( 3 1 )
(14)
(19)
(12)
170
-------
continued (profile=1192)
SAROAD
NUMBER
90101
90102
90104
90104
90105
90106
90107
90108
98058
98059
98060
98062
98063
98082
98091
CAS SPECIES
NUMBER NAME
BUTYLCYCLOHEXANE
METHYLPROPYLNONANE
METHYLOCTANE
METHYLOCTANE
PROPENYLCYCLOHEXANE
METHYLNONENE
METHYLDECENE
METHYLDODECANE
TR I METHYLCYCLOPENT ANE
DIMETHYLCYCLOHEXANE
TRIMETHYLCYCLOHEXANE
D I ETHYLCYCLOHEX ANE
N-PENTYLCYCLOHEXANE
ETHYLHEPTENE
DIMETHYLHEPTANE
MOL.
WEIGHT
140.27
183.35
128.26
128.26
141.23
140.26
154.29
184.36
112.16
112.12
129.27
140.27
154.30
127.05
128.26
PERCENT
WEIGHT
0 . 53
0.11
0.85
1.55
0 . 07
0 . 09
0.25
0 . 06
1.17
0.35
0 . 80
0.25
0.16
0.10
0.05
(5 )
(20)
SUM TOTAL
100.00
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
171
DATE :04-23-1988
-------
PROFILE NAME:Drycleaning
PROFILE NUMBER51193
PROFILE DATA QUALITY:B
CONTROL DEVICE:Uncontrolled
REFERENCE(S):90
DATA SOURCE:Five mineral spirit samples from two companies combined
iii equal amounts by volume. Headspace analyzed by GC/MS
SCC
40100102
SAROAD
NUMBER
43109
43110
43110
43110
43110
43111
43112
43124
43124
43125
43125
43125
43125
43135
43135
43135
43136
43138
43146
43146
43146
43146
43146
43146
43147
43147
43147
43150
CAS SPECIES
NUMBER NAME
ISOMERS OF DECANE
ISOMERS OF UNDECANE
ISOMERS OF UNDECANE
ISOMERS OF UNDECANE
ISOMERS OF UNDECANE
ISOMERS OF DODECANE
ISOMERS OF TR I DECANE
C9 OLEFINS
C9 OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO PARAFFINS
CIO PARAFFINS
CIO PARAFFINS
C9 PARAFFIN
C-8 OLEFINS
Cll OLEFINS
Cll OLEFINS
Cll OLEFINS
Cil OLEFINS
Cll OLEFINS
Cll OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
ISOMERS OF C10H18
MOL.
WEIGHT
142.28
156.30
1 56 . 30
156.30
1 56 . 30
170.32
184.36
127.05
127.05
140.27
140.27
140.27
140.27
142.28
142.28
142.28
128.25
112.23
154.29
154.29
154.29
154.29
154.29
154.29
168.32
168.32
168.32
138.25
PERCENT *
WEIGHT
11.28
7.92
0 . 00
0 . 00
0 . 00
1.12
0.05
0 . 00
0 . 02
0 . 42
1.63
0 . 00
0.10
0 . 74
0 . 00
0 . 00
0 . 00
0 . OO
0.10
0 . 00
0 . 88
0 . 00
0 . 00
0 . 00
0.10
0 . 02
0 . 00
0 . 07
(19)
(14)
(24)
.
(7 )
(12)
(6 )
(4 )
(2 )
(1 )
(18)
(17)
(16)
(6 )
(20)
(25)
(26)
172
-------
continued (profile=1193)
SAROAE
NUMBER
43150
43150
43151
43151
43151
43151
43151
43151
43151
43153
43235
43261
43288
43336
43397
43566
43567
45105
45105
45105
45105
45105
45105
45105
45105
45105
45107
45108
45108
45113
45202
45203
45204
45209
45210
45215
45238
45245
45303
45304
45304
45320
45801
45808
46202
CAS
! NUMBER
111-18-2
108-88-2
1678-89-7
25551-11-7
108-88-3
100-04-4
95-54-6
103-36-1
OQ_~QO O
Vo oo o
98-80-6
108-89-7
2531-12-6
SPECIES
NAME
ISOMERS OF C10H1B
ISOMERS OF C10H18
ISOMERS OF C11H20
ISOMERS OF C11H20
ISOMERS OF C11H20
ISOMERS OF C11H20
ISOMERS OF C11H20
ISOMERS OF C11H20
ISOMERS OF C11H20
C1OH16
NONANE
METHYLCYCLOHEXANE
ETHYLCYCLOHEXANE
OCTANOL
TR I METHYLCYCLOHEX ANOL
TR I METHYLCYCLOPENTANONE
TETRAMETHYLPENTANONE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
ISOMERS OF PROPYLBENZENE
C11H10
TOLUENE
ETHYLBENZENE
0-XYLENE
N-PROPYLBENZENE
CUMENE (ISOPROPYL BENZENE)
TER T-BUTYLBENZENE
ETHYLTOLUENE
C5-ALKYLBENZENES
C4-ALKYLPHENOLS
C5-ALKYLPHENOLS
C5-ALKYLPHENOLS
DIMETHYLBENZYLALCOHOL
CHLOROBENZENE
D I CHLOROBENZENES
OCTAHYDROINDENES
MOL.
WEIGHT
138.25
138.25
152.28
152.28
152.28
152.28
152.28
152.28
152.28
136.24
128.25
98.21
112.23
130.26
142.24
125.11
157.25
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
134.22
120.19
120.19
120.19
142.20
92.13
106.16
106.16
120.19
120.20
134.21
120.19
148.24
150.22
164.25
164.25
122.16
112.56
147.01
244 . 00
PERCENT
WEIGHT
0 . 00
0 . 00
0.10
0 . 00
0 . 00
0 . 00
0 . 07
0 . 1 5
0 . 00
0.10
6.96
0 . 02
0 . 59
0 . 10
0.17
0.15
0 . 64
1.89
1.00
0 . 07
0 . 00
0 . 3 5
0 . 00
0.31
0.12
0 i 00
2.23
0 . 98
0 . 00
0 . 00
0 . 50
0.35
1 . 56
0 . 00
0 . 34
0.31
0 . 38
0.10
0 . 38
0.17
0 . 00
0.15
0 . 26
0 . 00
0.17
(5 )
(ID
(9 )
(12)
(15)
(25)
( 22 )
(14)
(8 )
(3 )
(13)
( 23 )
(18)
(19)
(9 )
(24)
(10)
(21)
(6 )
(23)
(7 )
(26)
(27)
(10)
173
-------
continued (profile=l193)
SAROAD CAS
NUMBER NUMBER
46601 2782-29-4
46602 95-51-9
46701 91-12-3
46748
46748
46753 91-11-8
46753 91-11-8
90010
90045
90047
90048
90049
90055
90066
90070
90071
90072
90074
90076
90076
90076
90077
90081
90082
90083
90089
90090
90094
90094
90095
90096
90096
90097
90098
90101 1678-89-9
90104
90105
90107
90109
90109
90110
90110
90111
90112
90113
SPECIES
NAME
TETRAMETHYLTH I OUREA
BENZOTHIAZOLE
NAPTHALENE
METHYLDECALINS
METHYLDECALINS
DEC AL INS
DECALINS
M-XYLENE AND P-XYLENE
METHYLHEPTANE
METHYLNONANE
METHYLDECANES
METHYLUNDECANE
PENTYLCYCLOHEXANE
NONADIENE
DIMETHYLOCTANES
DIMETHYLUNDECANE
METHYLPROPYLCYCLOHEXANES
DIMETHYLDECANE
DIMETHYLNONANES
DIMETHYLNONANES
DIMETHYLNONANES
ETHYLOCTANE
ETHYLHEXANE
ETHYLMETHYLHEXANE
ETHYLMETHYLCYCLOHEXANES
ETHYLDIMETHYLCYCLOHEXANE
ETHYLPROPYLCYCLOHEXANES
TR I METHYLHEPTANES
TR I METHYLHEPTANES
TRIMETHYLHEXENE
TRIMETHYLOCTANES
TR I METH YLOCT ANES
TRIMETHYLDECANE
TETRAMETHYLCYCLOPENTANE
BUTYLCYCLOHEXANE
METHYLOCTANES
PROPENYLCYCLOHEXANE
METHYLDECENE
PROPYLHEPTENES
PROPYLHEPTENES
DIETHYLMETHYLCYCLOHEXANES
D I ETHYLMETHYLCYCLOHEXANES
ISOPROPYLMETHYLCYCLOHEXANE
DIMETHYLOCTYNE
PENTYLIDENECYCLOHEXANE
MOL.
WEIGHT
132.25
135.19
123.11
170.34
170.34
138.25
138.25
106.16
114.23
142.28
1 56 . 32
170.34
154.29
124.23
140.27
184 . 36
168.32
225.43
211.41
211.41
211.41
142.29
114.23
128.26
126.24
141.27
154.29
142.29
142.29
126.24
156.31
156.31
182.35
126.24
140.27
128.26
141.23
154.29
141.28
141.28
111.20
111.20
140.27
138.25
443.11
PERCENT
WEIGHT
0 . 0 5
0.05
0.35
0 . 00
0. 55
0 . 07
0 . 53
'"> '".'jt.
.i . ..:. o
0 . 02
4.17
4.19
0.91
0 . 43
0.17
6.49
0 . 24
5.99
0 . 29
0 57
0.57"
1 , 34
0.21
0 34
o.io
4.27
0.95
0 . 50
3 n 58
2.31
0.35
0,35
0 . 00
0 . 02
0.55
1.68
.1 . 49
0.77
0 . 67
0 . 34
0.21
0 . 29
0 . 26
0.43
0.10
0 . 17
(27)
(22)
( 20 )
(4 )
(15)
(6 )
(11)
(13)
(8 )
(21)
( til
174
-------
con t inued ( prof i i e-1193 )"
SAROAD CAS
NUMBER NUMBER
901.14
90118
90.1.20
98059
9.8060
93060
98062
98091
98091
SPECIES
NAME
D I M E T H Y L B U T Y L C Y C L 0 H E X A N E
OCTAHYDRGPENTALENE
PROPYLCYCLOHEXANE
D I METHYLCYCLOHEXANE
TRIMETHYLCYCLOHEXANES
TR I METH YLC YCLOHE X ANES
D I ETHYLCYCLOHE X ANE
D I METHYLHEPTANES
D1METHYLHEFTANES
MQL .
WE I BUT
168.32
' 225.20
126.24 .
1 1 '"' 1 '"?
JL .L .ฃ. n JL ji
. ,...,-.. ..-,-_
..1 ..:.. 7 * JL. /
129.27
140.27
128.26
128.26
SUM TOTAL
PERCENT
WEIGHT
0 , 0 5
0 . .1 0
2.11
0 4 7
-1.72 .
0 . 29
0 . 4 5
0.45
0 . 1 0
100 . 00
(1 )
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
175
DATE :05-03 1988
-------
PROFILE NAME:Degreasing Composite
PROFILE NUMBER:1195
PROFILE DATA QUALITY:B
CONTROL DEVICE:Uncontrolled
REFERENCE(S):90,92
DATA SOURCE:Composite profile developed using Profile 1192 and
consumption data for solvents used in degreasing
industry.
SCC : 78
4O1OO29S
SAROAD
NUMBER
43109
43110
43110
43110
43111
43111
43111
43112
43113
43113 .
43124
43124
43124
43125
43125
43125
43125
43125
43125
43135
43138'
43138
43141
43146
43146
43146
43146
43.146
CAS SPECIES
NUMBER NAME
ISOMERS OF DECANE
ISOMERS OF UNDECANE
ISOMERS OF UNDECANE
ISOMERS OF UNDECANE
ISOMERS OF DODECANE
I SOMERS OF DODECANE
ISOMERS OF DODECANE
ISOMERS OF TR I DECANE
ISOMERS OF TETRADECANE
ISOMERS OF TETRADECANE
C9 OLEFINS
C9 OLEFINS
C9 OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO PARAFFINS
C-8 OLEFINS
C-8 OLEFINS
C8 PARAFFIN
Cll OLEFINS
Cll OLEFINS
Cll OLEFINS
Cll OLEFINS
Cll OLEFINS
MOL.
WEIGHT
1.42 . 28
156.30 '
156.30
156.30
170.32
170.32
170.32
184.36
198.38
198.38
127.05
127.05
127.05
140.27
140.27
140.27
140.27
140.27
140.27
142.28
4 1 ^ "^Tป
1 J.^. -i-O
112.23
114.23
154.29
154.29
154.29
154.29'
154.29
PERCENT *
WEIGHT
1 . 33
0.93
0 . 00
0 . 00
0 . 08
0.14
0 . 06
0.01
0 . 03
0 . 00
0 . 00
0 . 00
0 . 00
0.01
0 . 00
0.34
0 . 00
0 . 00
0.00
0 . 00
0.15
0.16
0 . 00
0 . 00
0 . 00
0 . 07
0 . OO
0 . OO
(15)
(17)
125)
(23)
.i.27)
fen
(2 )
(5 )
(3 )
( 10 )
(7 )
(4 )
(8 )
(6 )
(6 )
(1 )
(1 )
(16)
(15)
(18)
(14)
176
-------
c o n t i n u e cl ( p r a f i 1 e-.1.19 5 )
SAROAD
NUMBER
43146
43146
43147
43147
43147
43147
43147
43147
43143
43148
43150
43151
43152
43231
43232
43235
43248
43261
43288
43314
4335.1
43551
43552
43565
43802
43814
43817
43821
43824
45102
45105
45105
45105
45105
45.105
45105
45105
45105
45105
45105-
45105
45105
45107
45108'
45108
CAS
NUMBER
110-05-3
142-28-5
111-13-2
110-08-7
108-88-2
1678-89-7
78-89-2
60-02-7
67-76-1
/ CJ ~~ 8 v C'
75-50-2
71-15-6
127-71-4
7 6 -6. 1.--1
79-90-6
1330- 02 -7
<-) l= cr rr. 1 .... ) ! .. -7
.*:- \J \ J \J X ..I Jl. /
SPECIES
NAME
Cll OLEFIMS
Cll OLEFINS
C12 OLEFIMS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
C12 OLEFINS
ISOMERS OF C9H16
ISOMERS OF C9H16
ISOMERS OF C10H18
ISOMERS OF C.11H20
C12H22
HEXANE
HEPTANE
NONANE
CYCLOHEXANE
METHYLCYCLOHEXANE
ETHYLCYCLOHEXANE
S-BUTYL ALCOHOL
ETHYL ETHER
ACETONE
METHYL. ETHYL KETONE
D I METHYLCYCLOBUTANONE
METHYLENE CHLORIDE
1,1,, 1-TRICHLOROETHANE
PERCHLOROETHYLEME
TR I CHLOROTR I FLUOROEJH ANE
TRICHLOROETI-IYLENE
ISOMERS OF XYLENE
ISOMERS OF BUTYL.BENZENE
ISOMERS OF BUTYLBENZENE
I S 0 M IE R S 0 F B U T Y !.... B E N Z E N E
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE.
ISOMERS OF. BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS. OF ' BUTYLBENZENE
ISOMERS 'OF BUTYLBENZENE'
ISOMERS OF BUTYLBENZENE'
ISOMERS OF BUTYLBENZENE
TRIMETHYL.BENZENE
ISOMERS OF PROPYLBENZENE
. ISOMERS OF PROPYLBENZENE
MOL .
WEIGHT
154.29
154.29
168.32
168.32
168.32
168.32
168.32
168.32
124 . 23
124.23
138.25
152 ,,28
166.31
86.17
100.20
12.8.25
84.16
98.2.1
112.23
74. 12
74.12
58 . 08
72.10
98 ,,14
84 ,,93
133 ,,42
165.83
187.38
131 .40
106.16
134.22
134.22
134 . 22
134.22
134 .,22
.134 . 22
134 .22
134 ,,22
134.22
134.22
134,22
134.22
120.19
120.19
120.19
PERCENT'
WEIGHT
0
0
o
o
o
o
o
o
o
o
o
0
o
o
B
0
o
1
o
0
o
1
J.
o
4
-;;,
7
4
2
"*.
0
o
0
o
0
0
o
0
o
o
0
o
0
o
o
02
. 00
.01
0 1
. 00
. 00
. 00
. 00
. 02
.10
. 00
00
. 00
. 04
44
.87
.10
83
. 08
70
80
. 40
. 1 0
, 06
1 0
2 29
, 40
,,10
1 09
c 40
04
0 3
OO
. 03
00
. 03
,,0.1.
.0.1.
. 0 1
. 03
.2.1
.01
3 1
.05
. 23
(13)
(24)
( 32 )
(25)
(27)
(26)
( 22 )
! 3 )
( 1 1 )
(13)
(32)
(22)
24)
20 )
19)
29 )
( 21 )
(9 )
(B )
(17)
(12)
( 1 6 )
( 7 )
(6 )
177'
-------
continued (profile=1193)
SAROAD
NUMBER
45201
45202
45204
45209
452.10
45245
45245
45245
45245
45245
45303
45304
45304
45320
45808
46202
46202
46601
46701
46747
46748
46748
46748
46748
46748
46748
46753
90010
90028
90029
90047
90048
90049
90064
90066
90067
90070
90070
.90071
90072
90073
90075
90076
90076
90077
CAS
NUMBER
71-14-2
1 O O " O Q -'
95-54-6
103-36-i
98-88-8
2531-12-6
2782-29-
91 12-3
91-11-8
SPECIES
NAME
BENZENE
TOLUENE
0-XYLENE
N-PROPYLBENZENE
CUMENE (ISOPROPYL BENZENE)
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5--ALKYLBENZENE3
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C4-ALKYLPHENOLS
C5-ALKYLPHENOLS
C5-ALKYLPHENOLS
DIMETHYLBENZYLALCOHOL
DICHLOROBENZENES
OCTAHYDROINDENE3
OCTAHYDROINDENES
TETRAMETHYLTHIOUREA
NAPTHALENE
METHYL INOANS
METHYLDECALINS
METHYLDECALINS
METHYLDECALINS
METHYLDECALINS
METHYLDECALINS
METHYLDECALINS
DECALINS
M-XYLENE AND P-XYLENE
METHYLHEXANE
METHYLHEXENE3
METHYLNONANE
METHYLDECANES
METHYL. UNDECANE
DI METHYL.CYCLOPENT ANE
NQNADIENE
. DIMETHYLHE X AIMES
DIMETHYLOCTANES
DIMETHYLOCTANES
.DIMETHYLUNDECANE .....
:METHVLPROF'YLCYCL.OHE'XANES "
METHYL. ISQPRQPYLCYCLQHEXANE
ETHYLOCTENE
D.IMETHYLNONANES
DIMETHYLNONANES
ETHYLOCTANE .
MOL. .
WEIGHT
78.11
92.13
106.16
120.19
120.20
148.24
148.24
148.24
148.24
148.24
1 50 . 22
164.25
164.25
122.16
147.01
2 44.0O
244 . 00
132.25
123 . 1.1
132.21
170=34
170.34
170.34
170,34
170,34
170.34
1.38.25
106. 16
10O , 20
98. 18
142.28
.1. 56 . 32
170 ,,34
99.19
124.23
114.23
140.27
140,27
134.36
168 . 32
140,27
100.16
211.41
211.41
142.29
P
W
1
a
0
o
0
o
O
0
o
o
o
0
0
o
0
o
o
0
o
o
{_)
0
0
o
o
o
o
0
1
0
o
o
0
0
o
o
o
o
o
o
o
o
o
0
o
ERCEN1
EIGHT
. 00
.29
17
.05
.03
. 00
. 00
,02
, 00
. 0 1
04
. 00
02
02
. 00
. 02
,, 0 1
. 0 1
, 03
., 00
. 02
. 00
. 00
00
, 00
.0.1.
:, 06
";: 'T
27
1.2
. 75
.45
03
,,71
,, 02
a O'O1
i 8
., 12
00
.20
.06
. 04
.15
. 06
= 02
( 28 )
(27)
( 30 )
(26)
i, .-'-.- )
(9 )
(15)
(' ;:;;;:;; \
( 1 O )
f "."' '! ''
( 2:3 )
{ 25 j
(11;
( 18 ,i
( '?9 '>
-.. .,... f f
(2 )
(4 )
(31)
( 14)
178
-------
continued (profile=1195)
SAROAD CAS
NUMBER. NUMBER
90080
90081
90083
90085
90089
90090
90090
90091
90094
90096
90096
90098
90101 1678-89-9
90102
90104
90104
90105
90106
90107
90108
98058
98059
98060
98062
98063
98082
98091
SPECIES
NAME
ETHYLMETHYLCYCLOPENTANE
ETHYLHEXANE
ETHYLMETHYLCYCLOHEXANES
ETHYLMETHYLOCTANE
ETHYLDIMETHYLCYCLOHEXANE
ETHYLPROPYLCYCLOHEXANES
ETHYLPROPYLCYCLOHEXANES
TETRAMETHYLCYCLOBUTENE
TR I METHYLHEPTANES
TRIMETHYLOCTANES
TR I METHYL-OCTANES
TETRAMETHYLCYCLOPENTANE
BUTYLCYCLOHEXANE
METHYLPROPYLNONANE
METHYLOCTANES
METHYLOCTANES
PROPENYLCYCLOHEXANE
METHYLNONENE
METHYLDECENE
METHYLDODECANE
TR I METHYLC YCLOPENT ANE
DIMETHYLCYCLOHEXANE
TRIMETHYLCYCLOHEXANES
D I ETHYLCYCLOHEX ANE
N-PENTYLCYCLOHEXANE
ETHYLHEPTENE
D I METHYLHEPTANES
MDL.
WEIGHT
112.21
114.23
126.24
156.31
141.27
154.29
154.29
110.19
142.29
156.31
156.3.1.
126.24
140.27
183.35
128.26
128.26
141.23
140.26
154.29
184.36
112.16
112.12
129.27
140.27
1 54 . 30
127.05
128.26
SUM TOTAL
PERCENT
WEIGHT
0.01
0 .05
0 . 69
0 . 07
0 . 0 1
0 . 00
0 . 06
0 . 00
0 . 22
0.05
0 . 00
0 . 07
0.16
0 ., 03
0 . 26
0.47
0 . 02
0 . 03
0 - 08
0 . 02
0 . 36
0.11
0 . 24
0 . 08
0.05
0 . 03
0 . 02
100 . 00
(19)
(12)
(5 )
(20)
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
179
DATE :05-02-1988
-------
PROFILE NAMEsDrycleaning Composite
PROFILE NUMBER:1196
PROF I I_E DATA QUALITY : B
CONTROL DEVICE:Uncontrolled
REFERENCE(S)s90, ,91
DATA 30URCEI; Composi te profile developed from Profile? 1193 and
consumption d a ta f o r solvent usage in dryc1ean i ng
industry
SCC
79
40.100198
SAROAD CAS
NUMBER NUMBER
43109
43110
43110
43110
43110
43111
43112
43124
43124
43125
43125
43125
43125
43135
43135
43135
43136
43138
43146
43146-
43146
43146
43146 .
43146
43147
43147
.43147 . . - .
43150' '' ' '" " .' ''
SPECIES
NAME
ISOMERS OF DECANE
ISOMERS OF UNDECANE
ISOMERS OF UNDECANE
ISOMERS OF UNDECANE
ISOMERS OF UNDECANE
ISOMERS OF DODECANE
ISOMERS OF TR I DECANE
C9 OLEFINS
C9 OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO PARAFFINS
CIO PARAFFINS
CIO PARAFFINS
C9 PARAFFIN
C--8 OLEFINS
Cll OLEFINS
Cll OLEFINS
Cll OLEFINS
Cll QLEFINS .
C.1.1 OLEFINS
Cll OLEFINS . .
C12 OLEFINS
C12 OLEFINS
,.;C12. OLEFINS, -.-,..
ISOMERS OF CibHiS* ' ' ''
MOL .
WEIGHT
142.28
156.30
156,30
156.30
1 56 . 30
170.32
184 ,,36
127,05
127 ,,05
140.27
140,27
140 ,,27
140 27
142.28
142.28
142,28
128,25
112 .23
154 ,,29
154.29
154.29
154.29
154.29
154.29
168 . 32
168.32
. . . .. 168.32
138.25
PERCENT
WEIGHT
1 .74
1 n 2'?
0 , 00
0 , 00
0 . 00
0 . 1 7
0.01
0 * 00
0 . 00
0 . 0 i
0 00
0 , 07
0 2 5
0 . 00
0 ป 00
0 * .1 1
0 ,. 00
0 00
0 -, 00
0 . 00
0 00
0 . 0 1
0 r i 3
0 . 00
0 . 0 1
0 . 00
0 . 00
0 = 00
< i 8 )
180
-------
continued (profi16=1196)
SAROAD CAS
NUMBER NUMBER
43150
43150
43151
43151
43151
43151
43151
43151
43151
43153
43235 111-18-2
43261 108-88-2
43288 1678-89-7
43336
43397
43566
43567
43817 127-71-4
43821 76-61-1
451 0 5
45105
45105
45105
45105
4 f> 1 o 5
45105
45105
45105
45107 25551-11-7
45108
45108
45113
45202 108-88-3
45203 100-04-4
45204 95-54-6
45209 1 03-36-- 1
45210 98-88-8
45215 98-80-6
45238
45245 ' '':'"'
45303
45304
45304
45320'
45801 108-89-7
SPECIES
NAME
ISOMERS OF C10H18
ISOMERS OF C10H18
ISOMERS OF C11H20
ISOMERS OF C11H20
ISOMERS OF C11H20
ISOMERS OF C11H20
ISOMERS OF C11H20
ISOMERS OF C11H20
ISOMERS OF C11H20
C10H16
NONANE
METHYLCYCLOHEXANE
ETHYLCYCLOHEXANE
OCTANOL
TR I METHYLCYCLOHEX AIMOL
TRIMETHYLCYCLOPENTANONE
TETRAMETHYLPENTANONE
PERCHLOROETHYLENE
TR I CHLOROTR I FLUOROETHANE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS 0 F B U T Y L B E N Z E N E
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
TRIMETHYLBENZENE
ISOMERS OF PROPYLBEMZENE
ISOMERS OF PROPYLBENZENE
C11H10
TOLUENE
ETHYL-BENZENE
0-XYL.ENE
N-PROPYLBENZENE
CUMENE (ISOPROPYL BENZENE)
TERT-BUTYLBENZENE
ETHYLTOLUENE
C5-ALKYL.BENZENES " '.' '"
C4 ALKYLPHENOLS
C5-ALKYLPHENOLS
C 5- ALKYLPHENOLS
DIMETHYLBENZYLALCOHOL
CHLOROBENZENE
MO!
WEIGHT
138.25
138,25
152.23
152.23
152.28
152.28
152.28
1'v? ">ซ
152.2B
136.24
128.25
98.21
112.23
130.26
142 ,,24
125.11
157 ,,25
165.83
187.38
134.22
134.22 .
134.22
134.22
134.22
134 ,,22
1 34 . 22
134,: 2 2
134,22
120 19
120,, 19
120 . 19
142.20
92. 13
106.16
1 0 6 . 1 6
120,19
120 . 20
134.21
120 ,,19
148.24
150 ,,22
164.25
164.25
122.16
112.56
PERCENT
WEIGHT
0.01
0 . 00
0 n 00
0 . 0 1
0 . 00
0 . 00
0 . 0 1
0 00
0 . 02
0 . 0 1
1 . 07
0 00
0 . 09
0 0 1
0 . 03
0 . 02
0 1 0
82 09
3 ., 00
0 ,, 29
0,,01
O.i 05
0 . 0 5
0 ,, 00
0 00
0 0 2
0 = 15
0 00
0 34
0.15
0 . OO
0 . 00
0 OS
0 . 0 5
0 24
0 . 0 5
0 0 5
0 ., 0 5
0 06
0 . 0 1
0 . 06
0 . 00
0 03
0 . 02
0 04
(11)
(15)
(22)
(25)
(8 )
(9 )
( 12)
(14)
(3 )
( 1 3 )
( 23 )
(19)
i 24 '
(21 )
( .1. 8 }
( 1 0 )
( 9 )
(6 )
( 2"::^ )
(7 )
(26)
(27)
'181
-------
continued ( prof .i. le=1196)
SARD AD CAS
NUMBER NUMBER
45808 2531-12-6
46202
46601 2782-29 4
46602 95-51-9
46701 91-12-3
4674S
46743
46753 91-11-8
46753 91-11-8
90010
90045
90047
90048
90049
90055
90066
90070
90071
90072
90074
90076
90076
90076
90077
90081
90082
90083
90089
90090
90094
90094
90095
90096
90096
90097
90098
90101 1678-89-9
90104
90105 ...
90107 '.".''
90109
90109
90110
90110'
90111
SPECIES
NAME
DICHLOROBENZENES
OCTAHYDRO I NDENES
I E TRAMETHYLT H 1 0 U R E A
BENZOTHIAZOLE
NAPTHALENE
METHYLDECALINS
METHYLDECALINS
DEC AL INS
DEC ALUMS
M-XYLENE AND P-XYLENE
METHYLHEPTANE
METHYLNONANE
METHYLDECANES
METHYLUNDECANE
PENT YLC YCL..OHE X ANE
NONADIENE
DIMETHYL OCTANE 3
D I METHYLUNDECANE
METHYLPROPYLCYCLOHEXANES
DIMETHYLDECANE
DIMETHYLNONANES
DIMETHYLNONANES
DIMETHYLNONANES
ETHYLOCTANE
ETHYLHEXAIME
E T H Y L M E T H Y L H E X A N E
ETHYLMETHYLCYCLOHEXANES
ETHYLD I METHYLCYCLCHEX ANE
ETHYLPROPYLCYCLQHEXANES
TR I METHYLHEPTAIMES
TR I METHYL.HEPTANES
TRIMETHYLHEXENE
TRIMETHYLOCTANES
TRIMETHYLOCTANES
. TRIMETHYLDECANE
TETRAMETHYLCYCLOPEiMTANE
BUTYLCYCLOHEXANE
METHYL(3CTANES
... PROPEMYLCYCLOHE.XAME
" 'METHYLDECENE ' -.-
PROPYLHEPTENES
PROPYLHEPTENES
D I ETHYLMETHYLCYCLOHEXANES
D I ETHYLMETHYLCYCLOHEXANES
. ISOPROPYLMETHYL.CYCLOHEX ANE.
MOL
WEI
147
244
132
135
123
170
170
133
138
106
114
142
156
170
154
124
140
184
168
225
. 211
211
21 i
142
114
128
1 2 ti
1.41
154
142
142
126
156
156
182
.126
140
128
141
'' 154
1 4 1
141
111
.1 1 1
140
GHT
.01
. 00
25
.19
.11
. 34
. 34
.25
. 25
.16
"\ ":;
.28
ซ.,. ....^
.34
.29
f^f "!
., 77
. 36
n _'."' 2
. 43
. 41
.41
.41
.29
B -t~ :''.'
26
ซ 24
,27
. 29
.29
~ ' <::>
.24
., 3 1
3 1
a O -."'
. 24
. 27
.26
o ^:.'!-j!'
.29
,28
.28
. 20
. 20
,, 27
PERCENT
WE I GHT
0 ,: 00
o .03;
o . o i
0 . 0 1
0 0 5
0 . 08
0 = 00
0 . 08
0 . 0 1
0.35
0 . 00
0 64
0 ,, 64
0 1 4
0 . 07
0 03
1 , 00
0..04
0 4E)
0 , 04 j
0 . 09
0.21
0 09
0 . 03
0 . 0 5
0 . 0 1
0 ,. 66
0 . 1 5
0 08
0.55
0,35
0 . 0 5
0 = 00
0 = 05
0 . 00
0 .. 03
0 . 26
0 . 23
0 1 2
0 * 1 0
0 . 0 5
0 . 03
0 . 04
0 .. 0 4'
0 07
182
-------
c on t i ntied ( pro f i 1 e= 1196)
SAROAD
NUMBER
90112
90113
901.1.4
90118
90120
98059
98060
98060
98062
98091
98091
CAS SPECIES
NUMBER NAME
D1METHYLOCTYNE
PEMTYL I DENECYCLOHEX ANE
DIMETHYLBLITYLCYCLOHEXANE
OCTAHYDROPENTALENE
PROP YLCYCLOHEX ANE
D I METHYLCYCLOHEX ANE
TRIMETHYLCYCLOHEXANES
TR I METHYLCYCLOHEX ANES
DIETHYLCYCLOHEXANE
D I METHYLHEPTANES
DIMETHYLHEPTANES
MOL .
WEIGHT
138.25
443.11
168.32
225.20
126.24
112.12
129.27
129.27
140.27
128.26
128.26
PERCENT
WEIGHT
0 0 1
0 03
0 . 0 i
0.01
0 . 33
0 . 07
0 . 26
0.04
0 . 07
0 . 07
0.01
(17)
(2 )
(1 )
SUM TOTAL
100.00
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
"183
DATE :05-03-1988
-------
3.19 SURFACE COATING OPERATIONS
Surface coating operations primarily involve the application of paint,
varnish/shellac, lacquer, enamel, or paint primer for surface decoration
and/or protection before products are marketed. Adhesives, as the name
implies, involve the application of a bonding agent for the purpose of
adhering materials together. A number of basic industrial coating
operations are utilized, including spraying, flowcoating, roller coating,
dipping and electro-coating. There are variations and combinations of these
operations, each designed for a special task. The coatings applied in these
operations vary widely as to composition and physical properties. In order
to accelerate the drying of the solvents used in the surface coatings, a
drying or baking operation is usually an integral part of the basic coating
process.
184
-------
PROFILE NAMEsSurface Coating - Varnish/Shellac
PROFILE NUMBER:0127
PROFILE DATA QUALITY:D
CONTROL DEVICE Uncontrolled
REFERENCE(S)s59
DATA SOURCEsEngineering evaluation of literature test data,
SCC : 40200310 40200301
SAROAD CAS
NUMBER NUMBER
43367
43551 67-76-1
43552 78-89-3
43560 563-38-4
SPECIES
NAME
GLYCOL ETHER
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
MOL.
WEIGHT
106.12
58 . 08
72.10
100.16
PERCENT
WE I BHT
3 . 00
38 . 70
41.60
16.70
.SUM TOTAL 100.00
DATE -.04-21-1988
185
-------
PROFILE NAME:Surface Coating Paint Solvent - Acetone
PROFILE NUMBER 50219
PROFILE DATA QUALITY:E
CONTROL DEVICEsUncontrolled
REFERENCE(S): 59
DATA SOURCE:Engineering judgement; information based on composite
survey data and inspection of solvent information.
SCC
40200902
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43551 67-76-1
ACETONE
58. OS
SUM TOTAL
100.00
100.00
DATE :04-22-1988
186
-------
PROFILE NAME:Paint Solvent - Ethyl Acetate
PROFILE NUMBER:0220
PROFILE DATA QUALITYsE
CONTROL DEVICE:Uncontrolled
REFERENCE(S): 59
DATA SOURCE:Engineering judgement; information based on composite
survey data and inspection of solvent information.
SCC
40200909
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIBHT
43433 141-17-6
ETHYL ACETATE
88.10
SUM TOTAL
100.00
100.00
DATE 504-22-1988
187
-------
PROFILE NAME:Paint Solvent - Methyl Ethyl Ketone
PROFILE NUMBER:0221
PROFILE DATA QUALITYnE
CONTROL DEVICES None
REFERENCE(S):59
DATA SOURCE:Engineering judgements! information based on composite
survey data and inspection of solvent information.
SCC : 40200918
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43552 78-89-.:
METHYL ETHYL KETONE
72.10
SUM TOTAL
100.00
100 n 00
DATE :04-22-1988
188
-------
:'ROFILE NAME:Surface Coating - Enamel. Cellosolve Acetate
:'ROFILE DATA QUALITY :E
:OIMTROL DEVICEsUncontrolled
REFERENCE(S): 59
DATA SOURCE:Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
3CC : 40200907
3AROAD
MUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43452 111-11-9
CELLOSOLVE ACETATE
132.16
SUM TOTAL
100.00
100.00
DATE :04-22-1988
189
-------
PROFILE NAME.-Surface Coating - Varnish/Shellac Solvent - Xylene
PROFILE NUMBER 50223
PROFILE DATA QUALITYsE
CONTROL DEVICE5Uncontrolled
REFERENCE(S): 59
DATA SOURCE 5 Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC 5 40200924
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45102 1330-02-7
ISOMERS OF XYLENE
106.16
SUM TOTAL
100.00
100.00
DATE ;04-22-1988
190
-------
PROFILE NAMEsSurface Coating - Primer - Mineral Spirits
PROFILE NUMBER;0225
PROFILE DATA QUALITYsB
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCE:Engineering judgement, information based oncomposite
survey data, inspection of solvent formulation.
SCC : 40200920
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43107 ISOMERS OF OCTANE 114.23 0.80
43108 ISOMERS OF NONANE 128.25 27.30
43109 ISOMERS OF DECANE 142.28 69.30
43110 ISOMERS OF UNDECANE 156.30 2.60
SUM TOTAL 100.00
191
DATE :04-21-1988
-------
PROFILE NAME:Surface Coating Solvent - Ethyl Alcohol
PROFILE NUMBER:0226
PROFILE DATA QUALITYrE
CONTROL DEVICEsUncontrolled
REFERENCE(S): 59
DATA SOURCE:Engineering judgement; calculations from composite
survey data and inspection of solvent formulation.
SCC : 40200910
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43302 64-41-5
ETHYL ALCOHOL
46.07
SUM TOTAL
100.00
10000
DATE ;04-22-1988
192
-------
PROFILE NAME:Surface Coating Solvent - Isopropyl Alcohol
PROFILE NUMBER:0227
PROFILE DATA QUALITYsE
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCE:Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC
40200912
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEI6HT
43304 67-76-0
ISO-PROF'YL ALCOHOL
60.09
SUM TOTAL
100.0O
100.00
DATE s04-22-1988
193
-------
PROFILE NAME:Surface Coating Solvent - Isopropyl Acetate
PROFILE NUMBER:0228
PROFILE DATA QUALITYsE
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCE Engineering judgements information based on composite
survey data and inspection of solvent formulation.
SCC
40200913
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43444 108-82-4
ISOPROPYL ACETATE
102.13
SUM TOTAL
100.00
100.00
. DATE :04-22-1988
194
-------
PROFILE NAMEsSurface Coating Solvent - Lactol Spirits
PROFILE NUMBER 5 0229
PROFILE DATA QUALITYsE
CONTROL DEVICES Uncontrolled
REFERENCE(S)s 59
DATA SOURCE:Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC
40200915
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43119
LACTOL SPIRITS
114.00
SUM TOTAL
100.00
100.00
DATE s04-22-1988
195
-------
PROFILE NAME;Surface Coating Primer - Naptha
PROFILE NUMBERS 0282
PROFILE DATA QUALITY:E
CONTROL DEVICE s Uncon t ro11ed
REFERENCE(S)s59
DATA SOURCE;Enqineering judgement 5 information based on composite
survey data and inspection of solvent formulation..
3CC :
SAROAD
NUMBER
45.1.01
40200921
CAS
NUMBER
NAME
NAPHTHA
MOL.
WEIGHT
114.00
SUM TOTAL
PERCENT
WEIGHT
100.00
10000
DATE :05-03-1988
196
-------
PROFILE NAME:Surface Coating Solvent - Butyl Acetate
PROFILE NUMBER;0288
PROFILE DATA QUALITY 5E
CONTROL DEVICE:Uncontrolled
REFERENCE(S): 59
DATA SOURCE Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC
40200903
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43435 138-82-7
N-BUTYL ACETATE
11.6.16
SUM TOTAL
100.00
100.00
DATE :04-22-1988
197
-------
PROFILE NAME:Surface Coating Solvent - Butyl Alcohol
PROFILE NUMBER:0289
PROFILE DATA QUALITYsE
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SQURCE:Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC :
SAROAD
NUMBER
40200904
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WE I BUT
43305 71 -.13-3
N-BUTYL ALCOHOL
74.12
SUM TOTAL
100.00
10000
DATE :04-22-.1988
198
-------
PROFILE NAME:Surface Coating Solvent - Cellosolve
PROFILE NUMBER:0290
PROFILE DATA QUALITYsE
CONTROL DEVICE:Uncontrolled
REFERENCE (S) -.59
DATA SOURCE Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC : 40200906
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43311 110-08-5
CELLOSOLVE
90.12
SUM TOTAL.
100.00
100.00
DATE 504-22-1988
199
-------
PROFILE NAME:Surface Coating Solvent - Methyl Alcohol
PROF ILE NUMBER s 0291
PROFILE DATA QUALITYsE
CONTROL DEVICEsUncontrolled
REFERENCE(S)s 59
DATA SOURCE Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC : 40200917
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43301 67-75-1
METHYL ALCOHOL
32.04
SUM TOTAL
100.00
100.00
DATE 304-22-1988
200
-------
PROFILE NAME:Surface Coating Solvent - Dimethylformamide
PROFILE NUMBER:0292
PROFILE DATA Ql)ALITY:E
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCE:Engineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC : 40200908
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43450 68-81-2
DIMETHYL FORMAMIDE
73.09
SUM TOTAL
100.00
100.00
DATE :04-22-1988
201
-------
PROFILE NAME:Surface Coating Operations
Solvent-base Paint
PROFILE NUMBER:1003
PROFILE DATA QUALITY:B
- Coating Application -
CONTROL DEVICE:Uncontrolled
REFERENCE(S):1
DATA SOURCE:Composite of profiles 1017 (lacquer), 1019 (primer),
and 1018 (enamel) in proportion to individual emission
totals for the South Coast Air Basin.
SCC : 40200101 40200110
3AROAD
NUMBER
43108
43232
43247
43248
43261
43277
43288
43308
.43433
43435
43459
43551
43552
43560
43562
43563
45102
45104
45.107
45202
45203
45204
98057
9SO58
98059
98060
98090
98091
CAS
NUMBER
142-28-5
108-80-7
110-08-7
108-88-2
1678-89-7
ill.- 17-2
141-17-6
138-82-7
67-76-1
78-89-3
108-81-1
11 0-04-0
7379-91-6
1330-02-7
25551-11-7
i 08-83-3
100-O4-4
95-54-6
1640-08-7
SPECIES
. NAME
ISOMERS OF NONANE
HEPTANE
2 , 4-DIMETHYLPENTANE
CYCLOHEXANE
METHYLCYCLOHEXANE
2,4-DIMETHYLHEXANE
ETHYLCYCLOHEXA'NE
BUTYL CELLOSOLVE .
ETHYL ACETATE
N-BUTYL ACETATE
C5 ESTER
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
METHYL AMYL KETONE
2-METHYL-3-HEXANONE
ISOMERS OF XYLENE
ISOMERS OF ETHYLTOLUENE
TRIMETHYLBENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
ETHYLCYCLOPENTANE
TR I METH YLC YCLOPENT ANE
DIMETHYLCYCLOHEXANE
TRIMETHYLCYCLOHEXANES
METHYLHEPTENE
DIMETHYLHEPTANES
MOL..
WEIGHT
128.25
100 .20
100.20
84.16
98.21
114.22
112.23
118.17
88.10
116.16
130.19
58 . 08
72.10
100. 16
114.21
114.19
106.16
120.19
120.19
92.13
106.16
106.16
98.19
112.16
112.12
129.27
1 1 *""> "T**">
128.26
PERCENT
WEIBHT
2.79
2.94
1 . 70
0.52
3.61
7 . 20
1.43
6.48
2 . 04
9 . 50
1.26 .
1.27
0 . 54
0 . 36
0 . 33
3.75
3.70
0 . 20
0.11
37 . 37
0 . 54
4.47
0.22
0.17
4.01
1.66
0.15
0 . 67
202
-------
continued (profile=1003)
SAROAD
NUMBER-
GAS
NUMBER
SPECIES
NAME
MOL. PERCENT
WEIGHT WEIGHT
SUM TOTAL
100". 00
203
DATE .-08-10-1988
-------
PROFILE NAME:Surface Coating Operations - Coating Application -
Water-Base F'aint
PROFILE NUMBER:1013
PROFILE DATA QUALITY:B
CONTROL DEVICE:Uncontrolled
REFERENCE(S):1
DATA SQURCErSeven coatings with the largest emissions in California
representing four product types were combined in
proportion to 1980 California sales and the composite
was distilled. The organic and aqueous layers of the
distillate were analyzed by GC/MS.
SCC
40200201 40200210
SAROAD
NUMBER
43110
43238
43241
43305
43312
43313
43318
43320
43370
43371
43372
43391
43453
43454
43457
43458
43562
43801
438O2
43812
43835
43836
45201
98106
CAS
NUMBER
124-41-5
1120-02-4
71-13-3
112-23-5
104-47-7
123-34-2
107-72-1
107-74-5
142-29-1
108-8O-4
112-23-0
109-93-5
110-04-0
74-48-3
75-50-2
75-50-3
78-88-4
71-14-2
SPECIES
NAME
ISOMERS OF UNDECANE
N-DECANE
N-UNDECANE
N-BUTYL ALCOHOL
2- ( 2-BUTOXYETHOXY ) -ETHANOL
l-ETHOXY-2-PROF'ANOL
2-ETHYL HEXANOL
D I ACETONE ALCOHOL
ETHYLENE GLYCOL
HEXYLENE GLYCOL
D I BUTYL ETHER
2-BUTYLTETRAHYDROFURAN
VINYL ACETATE
METHYL PALM IT ATE
METHYLAL
SUBSTITUTED C9 ESTER (C12)
METHYL AMYL KETONE
METHYL CHLORIDE
METHYLENE CHLORIDE
ETHYL CHLORIDE
1-CHLOROBUTANE
3- ( CHLOROMETHYL ) -HEPTANE
BENZENE
ETHYLISOPROPYL ETHER
MOL.
WEIGHT
156.30
142.28
156.31
74.12
162.18
104.15
130.23
116.16
62 . 07
118.18
130 . 23
128.19
86 . 09
270.46
76 . 09
218.24
114.21
50 . 49
84.93
64.52
92.57
148 ..68
78.11
88.15
PERCENT
WEIGHT
1 . 00
0.21
0.12
20 . 09
0 . 78
1.46
1.01
0 . 78
0 . 58
1 . 43 .
0.24.
0.15
0.12
0.36
26 ..97
28.58
1 . 04
0.55
5.52
0 . 62
2.21
0 . 62
0 . 36
5 . 20
SUM TOTAL
100.00
DATE :04-22-1988
204
-------
PROFILE NAME:Surface Coating Operations
Composite
PROFILE NUMBER:1016
PROFILE DATA QUALITYsB
- Thinning Solvents -
CONTROL DEVICE!Uncontrolled
REFERENCE(S):1
DATA SOURCEzA composite sample was prepared based on sales volume
from nine commercially available solvents used with
architectural coatings. The composite was distilled
and the distillate analyzed by GC and GC/MS.
SCC : 40200901 82
SAROAD
NUMBER
43108
43109
43110
43125
43126
43127
43128
43129
43150
43232
43241
43261
43304
43435
43552
43570
43802
43837
45202
45203
45205
45206
45501
45502
45601
98062
98082
CAS
NUMBER
825-55-4
142-28-5
1120-02-4
108-88-2
67-76-0
138-82-7
78-89-3
75-50-2
106-69-4
108-88-3
100-04-4
108-83-3
106-64-3
100-05-7
1O4-48-O
85-54-9
SPECIES
NAME
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
CIO OLEFINS
C2 CYCLOHEXANE
C3 CYCLOHEXANE
C5 CYCLOHEXANE
C4 SUBSTITUTED CYCLOHEXANE
C10H18
HEPTANE
N-UNDECANE
METHYLCYCLQHEXANE
ISO-PROPYL ALCOHOL
N-BUTYL ACETATE
METHYL ETHYL. KETONE
ALKENE KETONE
DICHLOROMETHANE
ETHYLENE D I BROMIDE
TOLUENE
ETHYLBENZENE
M-XYLENE
P-XYLENE
BENZALDEHYDE
P-TOLUALDEHYDE
PHTHALIC ANHYDRIDE
D I ETHYLCYCLOHEX ANE
ETHYLHEPTENE
*
MOL.
WEIGHT
128.25
142.28
156.3O
140.27
112.22
126.24
154.30
1'42 . 28
138.25
100.20 .
156.31
85.16
60 . 09
116.16
72.10
72.10
84.94
.187.88
92.13
106.16
106.1.6
106.16
106.13
120.16
148.00
140.27
127.05
SUM TOTAL
PERCENT
WEIGHT
5.24
6.47
1.63
7.18
2.89
1 . 99
0.91
2.89
4.45
3 . 07
2.51
6.72
4.91
9 . 27
4 , 06
1 . 99
1.22
0.91
15.22
0 . 93
1.65
1.07
0 . 76
1.05
0.76
7.96
2 . 26
100 . 00
205
DATE :04-21-1988
-------
PROFILE NAME:Surface Coating Operations
Lacquer
PROFILE NUMBER:1017
PROFILE DATA QUALITY:B
- Coating Application -
CONTROL DEVICE:Uncontrolled
REFERENCE(S):1
DATA SOURCE:Distillates of four lacquer samples attained from
surface coating facilities were combined in proportion
to the emission facility and analyzed by GC and GC/MS.
SCC
40200401 40200410
SAROAD CAS
NUMBER NUMBER
43108
43232 142-28-5
43261 108-88-2
43277
43288 1678-89-7
43435 138-82-7
45102
45202 108-88-3
45204 95-54-6
98057 1640-08-7
98058
98060
98090
SPECIES
NAME
ISOMERS OF NONANE
HEPTANE
METHYLCYCLOHEXANE
2,4-DIMETHYLHEXANE
ETHYLCYCLOHEXANE
N-BUTYL ACETATE
ISOMERS OF XYLENE
TOLUENE
0-XYLENE
ETHYLCYCLOPENTANE
TR I METHYLCYCLOPENT ANE
TR I METH YLCYCLOHEX ANE
METHYLHEPTENE
MOL.
WEIGHT
128.25
100.20
85.16
114.22
112.23
116.16
106.16
92.13
106.16
- 98.19
112.16
129.27
112.22
PERCENT
WEIGHT
4 . 43
10.17
15.25
0 . 76
0 . 79
14.90
1 . 04
44.59
3.14
1.68
1.29
0.8.1
1.14
SUM TOTAL
100.00
DATE :04-21-1988
206
-------
PROFILE NAME .-Surface Coating Operations
Enamel
PROFILE NUMBER:10.18
PROFILE DATA QUALITY:B
Coating Application -
CONTROL DEVICE:Uncontrolled
REFERENCE(S):1
DATA SOURCE:Distillates of five enamel samples obtained from
coating facilities were combined in proportion to
facility emissions and analysed by SC/MS. Four
samples from coating manufacturers were also combined
and analyzed. The two data sets were then averaged.
SCC
40200510 4020050.1
3AROAD
NUMBER
43232
43248
43433
43435
43459
43551
43552 '
43560
43562
43563
45102
45104
45107
45202
45203
45204
CAS
NUMBER
142-28-5
110-08-7
141-17-6
138-82-7
67-76-1
78-89-3
108-81-1
110-04-0
7379-91-6
1330-02-7
25551-11-7
ioa-aa-3
100-O4-4
95-54-6
SPECIES
NAME
HEPTANE
CYCLOHEXANE
ETHYL ACETATE
N-BUTYL ACETATE
C5 ESTER
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
METHYL AMYL KETONE
2-METHYL-3-HEXANONE
ISOMERS OF XYLENE
ISOMERS OF ETHYLTOLUENE
TRIMETHYLBENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
MOL.
WEIGHT
100.20
84.16
88.10
116.16
130.19
58 . 08
72.10
100.16
114.21
114.19
106.16
120.19
120.19
92 . 13
106.16
106.16
PERCENT
WEIGHT
1.56
"? O"7
8.96
9.41
5.51
5.57.
2.36
1.57
3.62
16.44
11.56
0.88
0 . 50
15.90
2.36
1 1 . 53
SUM TOTAL
100.00
DATE :08-10-1988
207
-------
PROFILE NAME:Surface Coating Operations - Coating Application -
Primer
PROFILE NUMBER:1019
PROFILE DATA QUALITYrB
CONTROL DEVICE Uncontrolled
REFERENCE(S):1
DATA SOURCE:Distillates of three primer samples from surface
coating facilities were combined (weighted according
to emissions from each facility) and analyzed by
SC/MS.
SCC 5 40200610 40200601
SAROAD CAS
NUMBER NUMBER
43108
43232 142-28-5
43247 108-80-7
43261 108-88-2
43277
43288 1678-89-7
43308 111-17-2
43435 138-82-7
45102
45202 108-88-3
45204 95-54-6
98059
98060
98091
SPECIES
NAME
ISOMERS OF NONANE
HEPTANE
2 , 4-DI METHYLPENTANE
METHYLCYCLOHEXANE
2 , 4-DIMETHYLHEXANE
ETHYLCYCLOHEXANE
BUTYL CELLOSOLVE
N-BUTYL ACETATE
ISOMERS OF XYLENE
TOLUENE
0-XYLENE
DIMETHYLCYCLOHEXANE
TR I METHYLCYCLOHEXANE
DIMETHYLHEPTANE
MOL.
WEIGHT
128.25
100.20
100.20
85.16
114.22
112.23
118.17
116.16
106.16
92.13
106.16
112.12
129.27
128.26
PERCENT
WEIGHT
3.45
1.94-
2.66
2 . 50
11.09
2 . 08
10.13
8.42
1.45
44.31
2.23
6.26
2.43
1 . 04
SUM TOTAL
10O.00
DATE :04-21-1998
208
-------
PROFILE NAMEsSurface Coating Operations - Coating Application -
Adhesives
PROFILE NUMBER:1020
PROFILE DATA QLJALITYsB
CONTROL DEVICE:Uncontrolled.
REFERENCE(S):1
DATA SOURCE:Disti1lates of three adhesive samples from coating
facilities and a coating manufacturer were combined
(weighted according to emissions from each facility)
and analysed by GC and GC/MS.
SCC : 40200706 40200707
SAROAD CAS
NUMBER NUMBER
43122
43231 110-05-3
43262 96-63-7
43322 110-06-4
43551 67-76-1
43552 78-89-3
43560 108-81-1
45202 108-88-3
SPECIES
NAME
ISOMERS OF PENTANE
HEXANE
METHYLCYCLOPENTANE
1,4 BUTANEDIOL
ACETONE
METHYL ETHYL KETONE
METHYL 1SOBUTYL KETONE
TOLUENE
MOL.
WE I 6HT
72.15
86.17
84.16
90.12
58 . 08
72.10
100. 16
92. 13
PERCENT
WE I GHT
56 . 04
0 . 90
3.22
11.17
13.28
11.17
0 . SO
3.42
SUM TOTAL
100.00
DATE :04-22-1988
209
-------
PROFILE NAME:Surface Coating Operations - Thinning Solvent -
Hexylene Glycol
PROFILE NUMBER:1026
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not reported
REFERENCE(S):1
DATA SOURCE Engineering judgement.
SCC : 40200927
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43371 107-74-5
HEXYLENE GLYCOL
118.18
SUM TOTAL
100.00
100.00
DATE s04-22-1988
210
-------
:'ROFILE NAME: Surf ace Coating Operations - Thinning Solvent
Ethylene Oxide
3ROFILE NUMBER:1031
::'RQFILE DATA QUALITY:E
:ONTROL DEVICE:Not reported
REFERENCE(S)si
DATA SOURCE:Engineering judgement.
3CC :
3AROAD
MUMBER
40200928
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WE I BUT
^3601 75-52-8
ETHYLENE OXIDE
44.05
SUM TOTAL
100.00
100.00
DATE :04-22-1988
211
-------
PROFILE NAME:Surface Coating Operations - Adhesive Application
PROFILE NUMBER:1088
PROFILE DATA QUALITY:C
CONTROL DEVICE!Direct flame incinerator
REFERENCE(S):48
DATA SOURCE:Volatile organics source test. Exhaust gases from one
laminating machine were allowed to enter the control
device. Three one-hour test runs were performed at the
inlet and outlet of the control device. Outlet
concentrations are shown here.
SCC
40200710 40200701
SAROAD CAS
NUMBER NUMBER
43232 142-28-5
43304 67-76-0
43433 141-17-6
43551 67-76-1
43552 78-89-3
43560 563-38-4
45202 108-88-3
SPECIES
NAME
HEPTANE
ISO-PROPYL ALCOHOL
ETHYL ACETATE
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
TOLUENE
MOL.
WEIGHT
100.20
60 . 09
88.10
58 . 08
72.10
100.16
92.13
PERCENT
WEIGHT
36 . 50
6 . 10
13.30
14.20
5 . 30
4 . 30
20.30
SUM TOTAL
100.00
DATE :04-21-1988
212
-------
PROFILE NAME:Citrus Coating
PROFILE NUMBER:1187
PROFILE DATA QUALITY:D
CONTROL DEVICE Uncontrolled
REFERENCE(S):59
DATA SOURCE:Composite profile developed from profiles 0293, 0294,
and 0295 from the 1980 VOC Data Manual.
SCC
40299996 40299995 40299997 40299998
SAROAD CAS
NUMBER NUMBER
43231 110-05-3
43248 110-08-7
45102 1330-02-7
45104
45107 25551-11-7
45108
45201 71-14-2
45202 108-88-3
452O3 100-O4-4
SPECIES
NAME
HEXANE
CYCLOHEX'ANE
ISOMERS OF XYLENE
ISOMERS OF ETHYLTOLUENE
TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
BENZENE
TOLUENE
ETHYLBENZENE
MOL .
WEIGHT
86.17
84.16
106.16
120.19
120.19
120.19
78.11
92.13
106.16
PERCENT
WEIGHT
1 1 . 33
14.37
26.94
6.51
9.67
1.34
1 . 04
20.12
8.68
SUM TOTAL
100.00
DATE .-04-22-1988
213
-------
PROFILE NAME:Autobody Repair
PROFILE NUMBER:1194
PROFILE DATA QUALITY:B
CONTROL DEVICE: Uncontrolled
REFERENCE ( S) : 90
DATA SOURCE : Twel ve automotive aftermarket paint and thinner samples
of acrylic lacquer and alkyd enamel from three paint
manufacturers combined using market statistics.
Semivolatiles analyzed by GC/MS.
SCC : 78 40100217 83 40100236 40100295 40100335 40100336
40100398 40100399 4020.1620 40100235 40100296 40100297 40100215
40100216 40100299 40100298
SAROAD CAS
NUMBER NUMBER
43107
43109
43110
4312.4
43124
43125
43125 '..'
43125
43.146
43146
43146
43148
43151
43232 142-28-5
43235 111-18-2
43261 108-88-2
43273 110-08-8
43288 1678-89-7
43294
43331
43335
43337 112-23-5
43410
43469 124-41-4
43472
43473
43474
43476
SPECIES
NAME
ISOMERS OF OCTANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
C9 OLEFINS
.C9 OLEFINS
.CIO OLEFINS. .
CIO OLEFINS . .
CIO OLEFINS
Cll OLEFINS
Cll OLEFINS
Cll OLEFINS
ISOMERS OF C9H16
ISOMERS OF C11H20
HEPTANE
NONANE
METHYLCYCLOHEXANE
CYCLOHEXENE
ETHYLCYCLOHEXANE
C7 OLEFINS
DIMETHYLPENTANOL
METHOXYETHOXYETHANOL
BUTOXYETHOXYETHANOL
HEXADECANOIC ACID
BUTOXYETHOXYETHANOL ACETATE
BUTOXYBUTENE
ETHYLHEXANOATE
METHYLMETHYLPROPENOATE
DIMETHYLHEXANEDIOATE
MOL.
WEIGHT
114.23
142.28
156.30
127.05
127.05
140.27
140.27
140.27
154.29
154.29
154.29
124.23
152.28
100.20
128.25
98.21
32.14
112.23
. 98.13
117.21
120.0O
148.00
286.42
162. .00
128.21
144.24
100.13
174.20
PERCENT
WEIGHT
1.27
0 . 94
0.57 .
0 . 00
0 . 94
0 . 02 1
0.18
0 . OO
0 . OO
0 . 00
0 . 03
0.02
0 . 00
4.35
2.48
3.93
0 . 32
1.57
0.05
0.41
0 . 00
0 . 57
0.01
T T^
1.75
0.11
0 . 32
0 . 08
(10)
(1 )
214
-------
continued (profile=1194)
SAROAD
NUMBER
43477
43567
43568
45102
45102
45105
45105
45108
45108
45201
45202
.45221
45226
45245
45245
45247
45404
45452
45470
45477
45601
46204
46701
46702
46702
46747
46747
46750
46753
90028
90047
90O48
90048
90064
90070
90076
90076
90080
90O81
90083
90104
90105
90115
90115
90117
CAS
NUMBER
1330-02-7
1330-02-7
71-14-2
108-88-3
25013-31-4
92-25-4 .
34-47-2
85-56-7
85-54-9
91-12-3
91-11-8
5989-92-5
SPECIES
NAME
D I METHYLPENTANED I DATE
TETRAMETHYLPENTANONE
NONENONE
ISOMERS OF XYLENE
ISOMERS OF XYLENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF PROPYLBENZENE
ISOMERS OF PROPYLBENZENE
BENZENE
TOLUENE
- METHYL STYRENE
BIPHENYL
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C6-ALKYLBENZENE
DIMETHYLETHYLBENZOICACID
D I BUTYL PHTHALATE
DI--C8 ALKYL PHTHALATE
' BUTYLBENZYLPHTHALATE
PHTHALIC ANHYDRIDE
DIHY.DROXYNAPTHALENEDIONE
NAPTHALENE
METHYL NAPHTHALENES
METHYL NAPHTHALENES
METHYL I NDANS
METHYL I NDANS
DIMETHYLINDANS
DECALINS
METHYLHEXANE
METHYLNONANE
METHYLDECANES
METHYLDECANES
D I METHYLCYCLOPENTANE
DIMETHYLOCTANES
DIMETHYLNONANES
DIMETHYLNONANES
ETHYLMETHYLCYCLOPENTANE
ETHYLHEXANE
ETHYLMETHYLCYCLOHEXANES
METHYLOCTANES
PROPENYLCYCLOHEXANE
TRIMETHYLHEXANES
TRIMETHYLHEXANE3
LIMONENE
MOL.
WEIGHT
132.00
157.25
138.25
106.16
106.16
134.22
134.22
120.19
120.19
73.11
92.13
118.19
154.21
143.24
148.24
162.27
179.22
278.35
300 * 53
- . 1.92.00
148.00
160.00
123.11
142.20
142.20
132.21
132.21
146.00
138.25
100.20
142.28
156.32
1 56 . 32
99.19
140.27
211.41
' 211.41
112.21
114.23
126.24
128.26
141.23
128.26
128.26
136.24
PERCENT
WEIGHT
0 . 81
1 '. 30
6.77
14.55
6.12
0 . 44
8.66
0 . 00
4.36
1.51
8.65
0.18
0 . 02
1.14
0 . 34
0 . 02
0.01
0.01
- 0.30
1.17 ' .
0.11.
0.05
1.46
0.15
0.13
0 . 00
0 . 00
0.05
0..00
2.16
0 . 26
0,05
0 . 08
0.81
0.11
0.18
0 . 08
0.13
5.32
1 . 00
1 . 20
0.18
0.41
0 . 34
0.11
(6 )
(1 )
(12)
(6 )
(11)
(12)
(11)
(9 )
(9 )
(8 )
(3 )
(7 )
215
-------
continued (profiIe=ii94)
SAROAD CAS
NUMBER NUMBER
90118
90121
90122
90128
98057 1640-08-7
98058
98059
98060
SPECIES
NAME
OCTAHYDROPENTALENE
METHYLETHYLHEPTANE
TETRAMETHYLHEXANE
ISOPROPYLCYCLOHEXANE
ETHYLCYCLOPENTANE
TR I METH YLC YCLQPENTANE
DIMETHYLCYCLOHEXANE
TRIMETHYLCYCLOHEXANES
MOL.
WEIGHT
225.20
142.22
145.31
126.25
98.19
112.16
112.12
129.27
PERCENT
WEIGHT
0 . 00 ( 5 )
0-.00 (4 )
0 . 08 ( 2 )
0.32
0.41
1.17
3.47
0 . 70
SUM'TOTAL
100.00
m
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
216
DATE :08-10-1983
-------
3.20 STORAGE, TRANSPORTATION, AND MARKETING OF PETROLEUM PRODUCTS
The storage, transportation, and marketing of petroleum liquids
involves many distinct operations, each of which represents a potential
source of VOC evaporative loss. Petroleum liquids are transported or
conveyed by tankers, barges, tank cars, tank trucks, and pipelines. Refined
fuels are delivered by tank trucks to service stations, commercial accounts,
and local bulk storage plants. Emission sources include working and
breathing storage losses, and loading, transit, and refueling losses.
Refueling losses include evaporative emissions that occur from vapor
displacement during vehicle refueling operations.
217
-------
PROFILE NAMErFixed Roof Tank - Commercial Jet Fuel (Jet A)
PROFILE NUMBER:0100
PROFILE DATA QUALITYsC
CONTROL DEVICE:Uncontrolled
REFERENCE(S):65
DATA SOURCE:Engineering evaluation of literature data,
SCC : 40301013
SAROAI
NUMBEF
43232
43233
43235
43238
43241
43255
43258
43259
43260
3 CAS
~< NUMBER
142-28-5
111-16-9
111-18-2
124-41-5
1120-02-4
112-24-3
629-95-5
629-95-4
629-96-9
SPECIES
NAME
HEPTANE
OCTANE
NONANE
N-DECANE
N-UNDECANE
N-DODECANE
N-TRIDECANE
N-TETRADECANE
N-PENTADECANE
MOL.
WEIGHT
100.20
114.23
128.25
142.28
156.31
170.33
184.36
198.38
212.41
PERCENT
WEIGHT
0.10
0 . 50
4.70
19.60
20 . 30
18.20
17.70
1 1 . 70
7 . 20
SUM TOTAL
100.00
DATE s04-21-1988
'218
-------
PROFILE NAME:Fixed Roof Tank - Crude Oil Production
PROFILE NUMBER:0296
PROFILE DATA QUALITYsC
CONTROL DEVICE Uncontrolled
REFERENCE(S):59, 72
DATA SOURCE:Engineering evaluation of test data and literature data
SCC
40301010 40301109 40301011 40301012
SAROAD CAS
NUMBER NUMBER
43115
43116
43122
43201 74-48-8
43202 74-48-0
43204 74-49-6
43212 106-69-8
43214 75-52-5
43220 109-96-0
43231 110-05-3
43232 142-28-5
43233 111-16-9
45201 71-14-2
SPECIES
NAME
C-7 CYCLOP ARAFF INS
C-8 CYCLOP ARAFF INS
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
. HEXANE
HEPTANE
OCTANE
BENZENE
MOL.
WEIGHT
98.19
112.23
72.15
16.04
30 . 07
44 . 09
58.12
58.12
72.15
86.17
100.20
114.23
78.11
SUM TOTAL-
PERCENT
WEIGHT
1.30
0 . 5O
1 . 50
6 . 20
5 . 60
17.60
27.10
1 . 50
14.60
7 . 90
.9.20
6 . 90
0 1 0
100 . 00
219
DATE s04-21-1988
-------
PROFILE NAME:Fixed Roof Tank - Crude Oil Refinery
PROFILE NUMBER s 0297
PROFILE DATA QUALITYsC
CONTROL DEVICEsUncontrolled
REFERENCE(S):59, 72
DATA SOURCE:Engineering evaluation of test, data and literature
data.
SCC : 40400301 40400302
SAROAD
NUMBER
43105
43106
43107
43122
43201
43202
43204
43212
43214
43220
43231
43232
45201
45202
CAS
NUMBER
74-48-8
74-48-0
74-49-6
106-69-8
75-52-5
109-96-0
110-05-3
142-28-5
71-14-2
108-88 -3
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
HEXANE
HEPTANE
BENZENE
TOLUENE
MOL.
WEIGHT
86.17
100.20
114.23
72.15
16.04
30 . 07
44 . 09
58.12
58.12
72.15
86.17
100.20
78.11
92.13
SUM TOTAL
PERCENT
WE I GHT
5.10
5 . 00
0 . 40
11.20
8 . 80
2 . 70
16.10
20 . 80
9.30
10.10
4 . 70
2 . 00
2 . 40
1 . 40
100 a 00
DATE s04-21-1988
220
-------
PROFILE NAME:Fixed Roof Tank - Crude Oil Marine Terminal
PROFILE NUMBER:0305
PROFILE DATA QUALITY:C
CONTROL DEVICE:Uncontrolled
REFERENCE(S):72
DATA SOURCEsEngineering evaluation of literature data.
SCC : 40600253
SAROAI
NUMBEF
43201
43202
43204
43212
43220
43231
43232
43233
) CAS
* NUMBER
74-48-8
74-48-0
74-49-6
106-69-8
109-96-0
110-05-3
142-28-5
111-16-9
SPECIES
NAME
METHANE
ETHANE
PROPANE
N-BUTANE
N-PENTANE
HEXANE
HEPTANE
OCTANE
MOL.
WEIGHT
16.04
30 . 07
44 . 09
58.12
72.15
86.17
100.20
114.23
PERCENT
WEIGHT
2 . 60
3 . 70
1 5 . 80
30 . 20
18.50
8 . 80
10.80
9 . 60
SUM TOTAL 100.00
DATE :04-21-1988
221
-------
PROFILE NAME:Gasoline - Summer Blend
PROFILE NUMBER:1014
PROFILE DATA QUALITY:B
CONTROL DEVICE:Uncontrolled
REFERENCE(S)si
DATA SOURCE:A composite of four product types combined in
proportion to 1979 sales figures for California
was used to develop vapor samples which were?
analyzed using a dual detector FID/PID GC.
SCC : 40301106 40301103 40400106 40400109 40301006 40400213 40400405
40400120 40400206 40400209 40301009 40400203 40400406 40301003
40400112 40400115 40301203 40400103
SAROAD
NUMBER
43105
43106
43107
43108
43120
43122
43124
43125
43202
43204
43212
43214
43216
43217
43220
43223
43224
43225
43226
43227
43228
43230
43231'
43232
43233
43242
43245
43247
CAS
NUMBER
74-48-0
74-49-6
106-69-8
75-52-5
624-46-6
590-01-1
109-96-0
563-34-1
109-96-1
563-34-2
64.6-60-8
627-72-3
513-33-9
96-61-0
110-05-3
142-28-5
111-16-9
287-79-3
592-24-6
108-80-7
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NOIMANE
ISOMERS OF BUTENE
ISOMERS OF PENTANE
C9 OLEFINS
CIO OLEFINS
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
T-2-BUTENE
CIS-2-BUTENE
N-PENTANE
3 METHYL- 1 -BUTENE
1-PENTENE
2-METHYL-l-BUTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-METHYL-2-BUTENE
3-METHYL PENTANE
HEXANE ' ' ' '
HEPTANE
OCTANE
CYCLOPENTANE . .
1-HEXENE
2 , 4-D I METHYLPENT ANE
MOL.
WEIGHT
86 ,,17
100.20
114.23
128.25
56.10
72.15
127.05
140.27
30.07
44 . 09
5 8.. 1.2
58.12
56-. 11
56 . 1 1
72.15
70.13
70.13
70.13
70.1.3
70. 13
70.13
86.17
86.17
100 . 20
114.23
7.0.14
84.16
100.20
PERCENT
WEIGHT
4.78
1.53
0 ,05
0 . 02
1.11
26.79
0 . 03
0 . 00
0 . 08
1.25
22.95
9,83
1.21
0.98
S . 56
0 . 40
1 . 02
1 . 93
1.61
0 . 79
.1 . 04
2 . 34
1 ,84
0.32
0.02
0 . 72
0.27
0.51
222
-------
continued ( prof .i. le=1014 )
SAROAD
NUMBER
43248
43250
43252
43261
43262
43270
43271
43278
43289
43291
43292
43293
43294
43295
43298
43299
4.5102
45110
45201
45202
45203
45204
45207
45208
45211
45215
452.18
45225
46712
98033
98034
98035
98054
CAS
NUMBER
110-08-7
540-08-1
565-57-3
108-88-2
oy z."^_"7
/ o o ป /
922-26-2
592-21-2
75-58-2
142-22-O
27236-64-0
589-93-4
1330-02-7
71-14-2
108-88-3
100-04-4
95-54-6
108-86-8
95 5c> 6
611-11-3
98-80-6
141-19-5
526-67-8
95-51-6
40504-45-7
592-24-8
107-73-1
SPECIES
NAME
CYCLOHEXANE
2,2, 4-TR I METHYLPENTANE
2 , 3 , 4-TR I METHYLPENTANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
3-METHYL-T-2-PENTENE
3,5, 5-TR I METHYLHE X ANE
2,5-DIMETHYLHEXANE
C6 OLEFINS
2 , 2-D I METHYL-BUTANE
CYCLOPENTENE
4-METHYL-T-2-PENTENE
C7 OLEFINS
3-METHYLHEXANE
3-METHYL.HEPTANE
1-METHYLCYCLOHEXENE
ISOMERS OF XYL.ENE
CIO AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLEIME
1 , 3 , 5-TR I METHYLBENZENE
1,2, 4-TR I METHYLBENZENE
0-ETHYLTOLUENE
TERT-BUTYLBENZENE
M-D I ETHYLBENZENE
1,2, 3-TR I METHYLBEN ZENE
INDENE
2,2, 5-TR I METHYLHEX ANE
T-2-HEXENE -
C-2--HEXENE
2,4, 4-TR I METHYL- 1 -PENTENE
MOL.
WE 1 6HT
84.16
114.22
114.22
98.21
84.16
84.16
128.26
114.22
84.16
86.17
68 . 1 1
84.18
98.18
100.20
114.23
96.17
106.16
134.22
78.11
92.13
106.16
106.16
120.19
120.19
12 O.I 9
134.21
134.22
120.19
116.16
128.26
84.16
84.16-
112.22
PERCENT
WEIGHT
0.26
0 . 49
0 . 08
0.13
1 . 66
0 . 09
0 . 1 0
0 . 1 1
0 . 06
1 . 23
0.25
0.25
0 . 06
0 . 49
0 . 07
0 . 05
0 . 1 5
(D . 0 1
0.77
0 . 66
0 . 04
0 , 0 5
0 02
0 . 06
' 0 0 5
0 n 00
0 00
0 0 5
0.01
0 ., 02
0 . 30
0 . 42
0 . 02
SUM TOTAL
100.00
223
DATE :04-22-1988
-------
PROFILE NAMEsGasoline
Winter Blend.
PROFILE NUMBER:1015
PROFILE DATA QUALITYsB
CONTROL DEVICEsUncontrolled
REFERENCE(S)si
DATA SOURCEsFour product types combined in proportion to 1979 sales
figures for California was used to develop vapor
samples that were analysed using a dual detector
FID/PID GC.
SCC s 40400104 40301104 40400110 40400101 40400118 40400107 4030.1.201
40400113 40301101 40400201 40400211 40400401 40400402 40400207
40301007 40301004 40301001 40400204
SAROAD
NUMBER
43105
43106
43107
43108
43109
43120
43122
43124
43138
43202
432O4
43212
43214
43216
43217
43220
43223
43224
43225
43226
43.227
43230
43231
43232
43233
43235
43238
43242
CAS
NUMBER
74-48--0
74-49-6
106-69-8
75-52-5
624-46-6
590-01-1
109-96-0
563-34-1
109-96-1
5 6 -2- - 4 i
646-60-8
627-72-3
96-61-0
110-05-3
142-28-5
111-16-9
111-18-2
124-41-5
287-79-3
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF BUTENE
ISOMERS OF PENTANE
C9 OLEFINS
C-8 OLEFINS
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
T-2-BUTENE
CIS-2-BUTENE
N-PENTANE
3-METHYL-l -BUTENE
1-PENTENE
2-METHYL-l-BUTENE
TRANS-2-PENTENE
CI3-2-PENTENE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
NONANE
' N-DECANE
CYCLOPENTANE
MOL.
WEIGHT
86.17
100.20
114.23
128.25
142.28
56.10
72.15
127.05
112.23
30 . 07
44.09
58.12
58.12
56.11
56.11
72.15
70. 13
70.13
70.13
70.13
70.13
86.17
86.17
100.20
114.23
128 . 25
142.28
70.14
PERCENT
WEIGHT
4 . 03
3.41
1.44
0.4.1
0.06
1.28
16.09
0 . 27
0.21
0 . 04
1. 10
24 97
13.94
1 .1.3
0 . 84
5.44
0.25
0 . 7 1
0 . 82
1 . 09
0 . 56
2.25
1.86
0.85
0 . 24
0 . 03
O.01
0.7O
224
-------
continued (profi16=1015)
SARQAD
NUMBER
43245
43247
43248
43252
43261
43262
43265
43271
43278
43284
43289
43291
43292
43293
43294
43295
43298
43299
43820
45102
45109
45201
45202
45203
45204
45207
45208
45209
45210
45211
452.12
45215
45218
45225
45801
46701
90013
98033
98034
98035
98040
98041
98044
98054
98056
CAS
NUMBER
592-24-6
108-80-7
110-08-7
565-57-3
108-88-2
96-63-7
111-16-0
592-21-2
625-52-4
75-58-2
142-22-0
27236-64-0
589-93-4
79-90-5
1330-02-7
71-14-2
108-88-3
100-04-4
95-54-6
1 <_) 8 8 6 8
95-56-6
103-36-1
98-88-8
611-11-3
620-01 -4
98-80-6
141-19-5
526-67-8
108-89-7
91-12-3
40504-45-7
592-24-8
763-32-1
496-61-7
107-73-1
590-08-3
SPECIES
NAME
1-HEXENE
2 , 4-D I METHYLPENTANE
CYCLOHEXANE
2,3, 4--TR I METHYLPENTANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
OCTENE
3,5, 5-TRIMETHYLHEXANE
2,5-DIMETHYLHEXAIME
2-METHYL-2-PENTENE
C6 OLEFINS
2 , 2-D I METHYLBUTANE
CYCLOPENTENE
4-METHYL-T-2-PENTENE
C7 OLEFINS
3-METHYLHEXANE
3-METHYLHEPTANE
1-METHYLCYCLOHEXENE
1,1, 2-TR I CHLOROETHANE
ISOMERS OF XYLENE
C3/C4/C5 ALKYLBENZENE5
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
1,3, 5-TR I METHYLBENZENE
1,2, 4-TR I METHYL.BEMZENE
N-PROPYLBENZENE
CUMENE (ISOPROPYL BENZENE)
0-ETHYLTOLUENE
M-ETHYLTOLLJENE
TERT-BUTYLBENZENE
M-D I ETHYLBENZENE
1,2,3-TRIMETHYLBENZENE
CHLOROBENZENE
NAPTHALENE
C-2-OCTENE '
2 , 2 , 5-TRIMETHYLHEXANE
T-2-HEXENE
C-2-HEXENE
' 2-METHYL-l-PENTENE
3-HEPTENE
INDANE
2,4, 4-TR I METHYL- 1-PENTENE
ISQVALERALDEHYDE
MOL.
WEIGHT"
84.16
100.20
84.16
114.22
98.21
84.16
112.21
123.26
114.22
84.16
84.16
86.17
68.11
84.18
98.18
100.20
.1.14.23
96.17
133.42
106.16
134.21
78.11
92.13
106.16
.1.06.16
120.19
120.19
120.19
120.20
120.19
120.19
134.21
134.22
120.19
112.56
123.11
112.21
128.26
84.16
84.16
84.16
98.19
118.18
112.22
86.14
PERCENT
WE I GHT
0.41
0 . 70
0 . 54
0 . 1 1
0 . 54
2.54
0.06
0.45
0 . 3 5
0 . 1 1
0.65
0.97
0 . 24
0.20
0 . 09
1 . 07
0 . 44
0.18
0 . 02
0 . 76
0 . 02
1 58
2 . 1 1
0 . 22
0.31
0 . 03
0 . 09
0.02
0.01
0.03
0 . 09
0 . 0 1
0 00
0 04
0 . 02
0 . 0 1
0 , 03
0.17
0 . 44
0 . 1 5
0 . 0 5
0 . 03
On 01
0.05
0 . 0 1
' 225
-------
continued (profile=1015)
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WE IGHT
SUM TOTAL
100.00
226
DATE s04-22-1988
-------
PROFILE NAME sRef ueling
PROFILE NUMBER si100
PROF I L.E DATA QUAL. ITY s C
CONTROL DEVICE : Uncon tro 1.1 ed
REFERENCE(S):54
DATA SOURCE;Composite profile developed using data from refueling
four cars fueled with unleaded/winter blend gasoline.
Data obtained by 6C/FID are weighted according to
hydrocarbon emissions.
3CC : 40600401 40600403
SAROAD
NUMBER
43136
432.11
43212
43213
43214
43215
43216
43217 '
43220
43221
43222
43223
43224
43226
43227
43223
43229
43230
4323.1
43232
43234
43235 .
43238
43242
43243
43245
43247
43250
CAS
NUMBER
760-02-3
106-69-8
106-69-9
75-52-5
115-51-7
624-46-6
590-01-1
109-96-0
78-87-4 '
463 38-1
563-34-1
109 96 1
646-60-8
627-72-3
513-33-9
107-78-- 5
96-61-0
110-05-3
142-28-5'
563-37-0
111-18-2
124-41-5
287-79-3 '
78-87-5
592-24-6
108-80-7.
540-08-1 '
SPECIES
NAME
C9 PARAFFIN
3-METHYL-l-PENTENE
M-BUTANE
BUTENE
ISO-BUTANE
ISOBUTYLENE
T-2-BUTENE
C I S-2-BUTENE
N-PENTANE
ISO' PENTANE -
2,2 D I METHYLPROPAME
3-METHYL-l -BUTENE
1-PENTENE
TRANS-2-PENTENE
CIS 2-PENTENE
2-METHYL-2-BLITENE
2-METHYL.PENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
2 , 3 DIMETHYL. i-BUTENE
NONANE
N-DECANE
CYCLOPEMTANE
ISOPRENE
i-HEXENE
2 , 4 D.I. METHYLPENTANE ,
2,2, 4-TR I METHYLPENTANE
MOL
WEIGHT
128 ,,25
84. 16
58.12
56. 10
58.12
56. 10
56 . 1 1
56 . 1 i
72.15
72 1 5
72.17
70 ,,13
70 ,,13
70.13
70. 13
70,13
86,, 17
86.17
86.17
100 ซ 20
84. 16
123.25
142.28
70,, 14
68,12
84.16
100 . 20
114.22
PERCENT*
WEIGHT
o . 00 ( :
0 . 00 (
32 63
2 . 69 (
14.45
0.00 (
3.19 i
2 ,,07 (
6 , 66
15 ,,83
0 00 (
0 37
0 . 64 (
1 36
0 . 68
1.61
2 26 (
I ,16
0 9 0 (
0,,35
0 .-. GI'I !
0.04
0 . 03
0,47 (
0 02
0 ,,23 (
0 28
0 37
1.7)
5)
1)
1)
2)
3 )
2)
4 )
6 }
S )
6)
5)
7)
227 '
-------
continued (profile=l100)
SAROAD
NUMBER
43252
43261
43262
43263
43270
43272
43273
43274
43276
43277
43278
43279
43280
43281
43282
43283
43284
43285
43286
43289
43290
43291
43292
43295
43296
43297
43293
43299
451.10
45201 .
45202
45203
45204
45205
45206
45207
45208
45209
45217
45225
90002
90004
90005
90006
98033
CAS
NUMBER
565-57-3
108-88-2
96-63-7
591-17-4
9^ *"* 'n JL ""*
ji ^. .*::. O *:~
693-38-0
110-08-8
565-55-3
79-92-8
c;oo '~> 1 _.-^
%. V 4~ 4~ 0. jL.
760-02-4
107-70-6
503-31-3
' -"^ K:: c: -* /i
O j~ O i_i *;. *r
75-58-2
H /I 'n >"w* f-v
J. *+ .ป:.. ,r:^ ..:.. '_'
589-93-4
592-22-8
589-95-7
71 -14 -2
108-88-3"
100-04-4
95-54-6
108-83-3
106-64-3.
108-86-8
T O "~ D o ~~ &
1 03-36- i
jL 35- 50 -3
^\ '"i jL ' "7 _ Q
V.I.&.O O / O
SPECIES
NAME
2 , 3 , 4-TR I METHYLPENTAME
METHYLC YCLOHE X ANE
METHYLCYCLDPEIMTANE
2-METHYL HEX ANE
3-METHYL-T-2-PENTENE
METHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENT ANE
2,3 DIMETHYLBLITANE
2,4-DIMETHYLHEXANE
2, 5-DIMETHYLHEXANE
2-ETHYL-l-BUTENE
2,3,3 TR I METHYLPENTANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
C6 OLEFINS
2,3 DIMETHYLHEXANE
2 , 2-D I METHYLBUT ANE
CYCLOPENTENE
3 METHYLHEXANE
2-METHYLHEPTANE
4-METHYLHEPTANE
3-METHYLHEPTAME
1 -METHYLC YCLOHE XENE
CIO AROMATIC
BENZENE
TOLUENE
ETHYLBEiMZENE
0 XYLENE
M-XYLENE
P- XYLENE
.1 , 3 , 5-TR I METH YL.BEN Z ENE
1,2, 4-TR I METHYLBENZENE
N-PROPYLBENZENE
1,2 DIETHYLBENZENE
1,2, 3-TR I METHYLBENZENE
2 , 3 ,, 5-TR I METHYLHEXANE
3 i 5 D I METH YLHEPT ANE
2,5 DIMETHYLHEPTANE
2 ', 3 D I METH YLHEPT ANE
2', 2 , 5-TR 1 METHYLHEXANE
MOL .
WE I GHT
114.22
93.21
84.16
100 20
84,16
32.14
82. 1.4
100 . 20
86. 17
114.22
114.22
84. 16
114.22
54 . 09
54 . 09
84., 16
84. 16
8 4 ,,1.6
1.12.20
84 ,,16
114 22
86.1.7
68 . 1 1
10O .20
114.23
.1.14. 23
114.23
96.17
134 ,,22
78 . 1 1
92.13
106,16
106,, 16
106. 16
106.16
1.20.19
120.1.9
120. 19
134.22
120.19
128.25
128.26
128 . 26
128.26
128.26
PERCENT
WEIGHT
0 . 06
0 . 1 4
0 8 5
0 . 00
0 00
0 . i 7
0 , 53
0 . 00
0.62
0. 1.2
0 . 00
0 ซ 00
0.10
0 ,, 00
0 . 00
0 . 00
0 . 36
0 . 1 3
0 , 02
0 . 1 8
0 ., 00
0 . 42
0.19
0 . 38
0 ,: 03
( "! , O.'-)
0 04
0 . 00
0 1. 1
i o o
i 03
0 28
0 1 5
0 . 00
0 . 29
0 . 2 1
0,15
0 ., 02
0 . 0 1.
0 . 06
0 . 0 1
0 . 04
0 . 00
0 , 00
0-. 16
( 9 i
(10)
( 9)
( 1 0 )
( 10)
( 11 )
(11)
( 7)
( 3 )
( 4)
( 3)
w>
( i 3 ,:
( 1 3 )
(12)
(15)
(17 )
( 16)
(16)
( 14)
( 1 4 )
(JJ?)
228
-------
continued (profile=1100)
SAROAD CAS
NUMBER NUMBER
98044 496-6.1-7
99911
99912
99916
99917
99918
99999
SPECIES
NAME
INDANE
3,4 DIMETHYLOCTANE
l-METHYL-3-ETHYLBENZENE
1-METHYL-3N-PROPYLBENZENE
i-METHYL-3- 1 SOPROPYLBENZEME
2-METHYLDECANE
UNIDENTIFIED
MOL.
WEIGHT
118. IS
142.29
119.19
134.22
134.22
156.32
86 . 00
PERCENT
WEIGHT
0.01
0 . 08
0.11
0 . 02
0 08
0 . 0 5
3 . 44
SUM TOTAL
100.00
K
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
229
DATE :05-03-1988
-------
PROFILE NAME:Gasoline Marketed
PROFILE NUMBER:1190
PROFILE DATA QUALITYsB
CONTROL DEVICE:Uncontrolled
REFERENCE(S) :90
DATA SOURCEsFourteen samples of leaded, unleaded and unleaded pre-
mium grades from five oil companies composite based on
1984 national sales data. Headspace analysed by GC/MS.
Profile represents summer blend gasoline from one
bulk terminal distribution region.
SCC
54
SAROAD CAS
NUMBER NUMBER
43105
43109
43110
43110
43111
43111
43113
43115
43124
43124
43124
43124
43125
43125
43135
43135
43135
43136
43138
43138
43141
43142
43143
43144
43145 '
43146
43146
43146
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
ISOMERS OF UNDECANE
ISOMERS OF DODECANE
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
C-7 CYCLOP ARAFF INS
C9 OLEFINS
C9 OLEFINS
C9 OLEFIN3 .
C9 OLEFINS
CIO OLEFINS
CIO OLEFINS
CIO PARAFFINS
CIO PARAFFINS
CIO PARAFFINS
C9 PARAFFIN
C--8 OLEFINS
C-8 OLEFINS
C8 PARAFFIN
C7 PARAFFINS
C5 OLEFIN
C5 PARAFFIN
C5 PARAFFIN/OLEFIN
Cll OLEFINS
Cll OLEFINS
Cll OLEFINS
MOL .
WE I GHT
86.17
142.28
1 56 . 30
156.30
170.32
170.32
198.38
98.19
127.05
127.05
127.05
127.05
140.27
140.27
142.28
142.28
142.28
128.25
112.23
112.23
114.23
100.20
70.13
72.15
70.13
154.29
154.29
154.29
PERCEN"!
WE I GHT
0 .
0.
0 ,
0.
0.
0 .
0.
0.
0 .
0.
0.
0 ,
0 .
0 n
0
0 .
o ,
0.
0 .
0.
3
0 .
1.
2.
1 ,
0
0 .
0 .
10
10
00
09
05
00
02
05
01
(JO
08
0.1.
00
04
oo
00
oo
48
21
OO
84
04
91
09
08
00
04
01
- #
(12)
( 1 5 )
(6 )
(11)
(8 )
(18)
(4 )
(2 )
(13)
(12)
230
-------
continued (profile=l190)
SAROAD CAS
NUMBER NUMBER
43148
43143
43148
43149
43213
43214
43215
43231
43232
43242
43261
43262
43264
43272
43273
43288
43292
43395
43565
45105
45105
45106
45107
45108
45111
45112
45112
45201
45202
45203
45204
45209
45210
45220
45221
45238
45243
45244
45245
45245
45245
45245
45245
45245
45245
106-69-9
75-52-5
115-51-7
110-05-3
142-28-5
287-79-3
1O8-88-2
96-63-7
693-38-0
110-08-8
1678-89-7
142-22-0
2555-1-11-7 '
71-14-2
108-88-3
100-04-4
95-54-6
103-36-1
98-88-8
100-04-5
25013-31-4
SPECIES
NAME
ISOMERS OF C9H16
ISOMERS OF C9H16
ISOMERS OF C9H16
C8H14
BUTENE
ISO-BUTANE
ISOBUTYLENE
HEXANE
HEPTANE
CYCLOPENTANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
HEPTENE
METHYLCYCLOPENTENE
CYCLOHEXENE
ETHYLCYCLOHEXANE
CYCLOPENTENE
C7H120
DIMETHYLCYCL.OBUTANONE
ISOMERS OF BUTYLBENZENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF DIETHYLBENZENE
TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
C10H12
ISOMERS OF C10H10
ISOMERS OF C10H10
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
N-PROPYLBENZENE
CUMENE (ISOPROPYL BENZENE)
STYRENE
METHYL STYRENE
ETHYLTOLUENE
ETHYL'DIMETHYLBENZENE
TETRAMETHYLBENZENE
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES' '
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES
C5-ALKYLBENZENES
MOL .
" WEIGHT
124.23
124.23
124.23
110.20
56.10
58.12
56.10
86.17
100.20
70.14
98.21
84 . 16
98.18
82.14
82.14
112.23
68 . 1 1
112.17
98.14
134.22
134.22
134.21
120.19
120.19
132.22
130. 19
130.19
78.11
92. 13
106.16
106.16
120.19
120.20
104.14
118.19
120.19
122.21
134.22
148.24
143.24
148.24
148.24
143.24
148.24
148.24
PERCENT
WEIGHT
0
0
0
0
0
2
0
TJ
1
o
o
0
o
0
o
0
o
o
0
:','.'
0
o
4
o
0
o
o
3
1
4
6
0
0
0
o
3
1
1
o
0
o
o
0
o
0
00
. 02
. 00
. 00
.14
.65
,14
.91
.84
.16
.21
.68
.03
.45
. 04
.08
.18
. 04
.05
.18
03
.02
.29
.76
. 04
. 00
. 00
. 25
5 22
.07
.41
. 92
...,. ...,.
.17
.05
.61
.24
. 03
,,35
.04
.83
.09
.02
.05
.05
(7 )
(5 )
(6 )
(13)
(9 )
(17)
(16)
(18)
( 20 )
(14)
(17)
(24)
231
-------
continued (profile=i190)
SAROAD CAS
NUMBER NUMBER
45246
45247
45247
45247
45247
45247
45247
45248
45248
45248
45248
45249
45501 100-05-7
45801 108-89-7
46115
46701 91-12-3
46702
46746
46747
46747
46747
46749
46750 ---
46750
46750
46751
46752
46754
46755
90010
90023
90024
90025
90025
90026
90027
90028 '
90029
90029
90039
90041 4313-35-9
90043 '
90044
90045
90046
SPECIES
NAME
C5-ALKYL.BENZENES ( UNSAT . )
C6-ALKYLBENZENE
C6-ALKYLBENZENE
C6-ALKYLBENZENE
C6-ALKYLBENZENE
C6-ALKYLBENZENE
C6-ALKYLBENZENE
C4-ALKYLSTYRENES
C4-ALKYLSTYRENES
C4-ALKYLSTYRENES
C4-ALKYLSTYRENES
C7-ALKYLBENZENE
BENZALDEHYDE
CHLOROBENZENE
D I METHYLNAPHTHYR I D I NE
NAPTHALENE
METHYL NAPHTHALENES
C2-ALKYLNAPTHALENE
METHYL I NDANS
METHYL I NDANS
METHYL I NDANS
METHYLD I HYDRONAPHTHALENE
DIMETHYL I NDANS
DIMETHYL I NDANS
DIMETHYL. I NDANS
DIHYDRONAPTHALENE
DIMETHYLINDENE
ETHYLIMDAM
TRIMETHYLIIMDAN
M-XYLENE AND P-XYLENE
METHYL.BUTENE
METHYLBLJTADIENE
METHYLPENTENES
METHYLPENTENE3
METHYLPENTANE
METHYLC YCLOPENT AD I ENE
METHYLHEXANE
METHYLHEXENES
METHYLHEXENES
METHYLHEXADIENE
METHYLC YCL'OHE X AD I ENE
METHYLHEXANAL
METHYLHEPTYME
METHYLHEPTANE
METHYL.CYCLOHEXENE
MOL .
WEIGHT
146=25
162=27
162.27
162.27
162.27
162.27
162.27
160.26
160.26
160.26
160.26
176.30
106.13
112.56
160.00
123.11
142.20
158.24
132.21
132.21
132.21
176.21
146 . 00
146- 00
146.00
162.19
144 .00
3.18.89
333 . 92
106.16
70.13
68.12
84,16
84. 16
86.. 17
30.14
100.20
98 = 18
98.18
. 96.17
94 1 5
146.36
110.20
114.23
96. 17
PERCENT
WE I GHT
0 . 0 5
0 . 00
0 . 00
0 . 02
0 . 06
0 . 00
0 . 03
0 . 04
0 . 00
0.01
0 . 02
0 . 00
0 . 00
0 . 03
0 . 0 1
0 . 80
0 . 64
0 = 1 0
0 . 52
0 0 1
0 , 00
0.01
0 = 42
o . do
o . oo
0 . 06
0 . 0 i
0.04
0 06
15,28
0 . 06
0 . ( I) 1
0 . 4 1
0 . 43
1 .76
0 . 04
1 . 68
0 , 00
0 . 03
0.25
0 . 02
0 92
0 . 02
0,35
0 . 1 4
(22)
(24)
(21)
(26)
( 23 )
(23)
(26)
(25)
(25)
(21)
(15)
^y
^^
( 20 )
( 19 )
( 1 )
( 3 )
232
-------
continued (profile=1190)
SAROAD CAS
NUMBER NUMBER
90047
90048
90054
90056
90058 142-28-6
90059
90060
90061
90062
90063
90064
90065
90065
90067
90067
90068
90069
90070
90070
90071
90074
90078
90079 .
90080
90081
90082
90083
900E33
90084
90085
90086
90087
90091
90092
90093
90094
90094
90095
90096
90097
90099 ' '
90100
90103
90104
98044 496-61-7 .
SPECIES
NAME
METHYL.NONANE
METHYLDECANES
PENTENYNE
HEX ENE
HEXADIENAL
HEPTADIENAL
DIMETHYLBUTANE
DIMETHYLBUTENE
D I METHYLPENTANE
DIMETHYLPENTENE
D I METHYLCYCLOPENT ANE
D I METHYLCYCLOPENTENES
D I METHYLCYCLOPENTENES
DIMETHYLHEXANES
DIMETHYLHEXANES
D I METHYLHE X AD I ENE
DIMETHYLETHYLCYCLOHEXANE
DIMETHYLOCTANES
DIMETHYLOCTANES
DIMETHYLUNDECANE
DIMETHYL..DECANE
ETHYLPENTENE
ETHYLCYCLOPENTENE
ETHYLMETHYLCYCLOPENTANE
ETHYLHEXANE
ETHYLMETHYLHEXANE
ETHYLMETHYLCYCLOHEXANES
ETHYLMETHYLCYCLOHEXAMES
ETHYLHEPTANE
ETHYLMETHYLOCTANE
ETHYL.B I CYCLOHEPTANE
ETHYLD I METHYLPENTANE
TETRAMETHYLCYCLOBUTENE!
TR I METHYLPENTANE
TR !!! METHYLPENT AD I ENE
TR I METHYLHEPT ANES
TR I METHYLHEPTANES
TRIMETHYLHEXENE
TR I METHYLOCTANES
TRIMETHYLDECANE
OCTATRIENE
NONENE
PENT AD I ENE
METHYLOCTANES
INDANE
MQL .
WEIGHT
142.28
156.32
68.12
84.16
111. 16
125.19
87.18
85.17
101.2.1
99 . 20
99.19
97.18
97.18
114 ,,23
114.23
111.20
140.26
140.27
140.27
184.36
225.43
98.19
96.17
112.21
114.23
128.26
126.24
126.24
128.26
156.31
223 42
128 ,,26
110.19
114.22
107.16
142.29
142.29
126.24
. 156.31
182.35
108.19
127.05
68. 13
128.26
118.18
PERCENT
WEIGHT
0,21
0. 12
0 . 03
0 . 40
0 . 03
0 . 02
2.29
0 . 30
0.36
0 . 02
0 1 5
0.22
0 . 09
0 . 48
0 . 28
0 .1 0
0 . 09
0.04
0 . 02
'0 . 00
0 07
o . 0:3
0 . 06
0.12
(!) . 24
0.21
0 . 04
0 . 02
0 . 02
0 . 02
0 n (!) .1
0.13
0 . 0 4
0 68
0 . 0 5
0 . 09
0 . 0 5
( ~.i . 0 4
0 . 07
0 . 03
0 . 0 .1.
0 . 03
0.04
0. 55
0.44
(8 )
(11 )
(14)
( 19 )
(4 )
(5 )
( 10 )
233
-------
continued (profile=l190)
SAROAD
NUMBER
98058
98059
98060
98091
99999
CAS SPECIES
NUMBER NAME
TR I METHYLCYCLOPENT ANE
D I METHYLCYCLOHEX ANE
TRIMETHYLCYCLOHEXANES
DIMETHYLHEPTANES
UNIDENTIFIED
MOL.
WEIGHT
112.16
112.12
129.27
128.26
86 . 00
SUM TOTAL
PERCENT
WEIGHT
0 . 09
0.10
0 . 02
0.16
0 . 00
1 00 . 00
(1 )
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
234" '
DATE :04-22-1988
-------
3.21 PRINTING/PUBLISHING PROCESSES
Printing may be performed on coated and uncoated paper as well as other
surfaces such as metals and fabric. Printing always involves the
application of ink by a printing press. Typical printing processes include
application of a relatively high solvent content material to the surface of
a moving web or film, rapid solvent evaporation by movement of heated air
across the wet surface, and solvent-laden air exhausted from the system.
235
-------
PROFILE NAME:Printing Press - Letterpress Inking Process
PROFILE NUMBER:0166
PROFILE DATA QUALITYsD
CONTROL DEVICE:Catalytic Afterburner
REFERENCE(S):59
DATA SOURCE:Information based on composite survey data and GC/MS
analysis of sampling train catch.
SCC : 40500211 40500201
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43201 74-48-8 METHANE 16.04 63.00
43202 74-48-0 ETHANE 30.07 24.00
43204 74-49-6 PROPANE 44.09 12.00
43212 106-69-8 N-BUTANE 58.12 1.00
SUM TOTAL 100.00
236
DATE :04-21-1988
-------
PROFILE NAMEsPrinting Press - Gravure General Solvent
PROFILE NUMBERS 0182
PROFILE DATA QUALITY:C
CONTROL DEVICEsUncontrolled
REFERENCE(S):59
DATA SOURCE:Information based on composite survey data and engi
neering evaluation of literature data.
SCC : 40500511 40500501 40500512
SAROAD CAS
NUMBER NUMBER
43118
43248 43-32-8
43301 67-75-1
43304 67-76-0
43305 71-13-3
43435 138-82-7
45106
45203 100-04-4
SPECIES
NAME
MINERAL SPIRITS
CYCLOHEXANE
METHYL ALCOHOL
ISO-PROPYL ALCOHOL
N-BUTYL ALCOHOL
N-BUTYL ACETATE
ISOMERS OF DIETHYLBENZENE
ETHYLBENZEME
MOL.
WEIGHT
114.00
84.16
32 . 04
60 . 09
74.12
116.16
134.21
106.16
PERCENT
WEIGHT
51.00
10.00
6 . 00
6 . 00
6 . 00
8 . 00
7 . 00
6 . 00
SUM TOTAL
100.00
DATE 504-21-1988
237
-------
PROFILE NAME:Printing Press - Gravure Printing Solvent
PROFILE NUMBERs0183
PROFILE DATA QUALITY:D
CONTROL DEVICE:Uncontrolled
REFERENCE(S):60
DATA SOURCE:Information based on calculations from composite survey
data.
SCC : 40500513
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43118 MINERAL SPIRITS 114.00 83.OO
45102 ISOMERS OF XYLENE 106.16 4.00
45202 108-88-3 . TOLUENE 92.13 13.00
SUM TOTAL 100.00
DATE :04-21-1988
238
-------
PROFILE NAME:Printing Press - Lithography Inking and Drying
PROFILE NUMBER s 0332
PROFILE DATA QUALITY:D
CONTROL DEVICE:Thermal afterburner ,
REFERENCE(S):59
DATA SOURCE:Information based on composite survey data and 6C/MS
analysis of sampling train catch.
SCC : 40500401 40500411
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43201 74-48-8
43203 74-48-1
43205 79-92-9
43213 106-69-9
43224 109-96-1
43502 50-00-0
METHANE
ETHYLENE
PROPENE
BUTENE
1-PENTENE
FORMALDEHYDE
16.04
28.05
42.08
56.10
70.13
30.03
17.10
2.00
33.60
13.60
11.90
21.80
SUM TOTAL
100.00
DATE :04-21-1983
239
-------
PROFILE NAME:Lithography - Inking and Drying-Direct Fired Dryer
PROFILE NUMBERS0333
PROFILE DATA QUALITY:D
CONTROL DEVICE:Uncontrolled
REFERENCE(S)s 59
DATA SOURCE:Information based on composite survey data and 6C/MS
analysis of sampling train catch.
BCC : 40500199 40500101
SAROAD CAS
NUMBER NUMBER
43201
43202
43204
43212
43214
43304
43802
74-48-8
74-48-0
74-49-6
106-69-8
75-52-5
67-76-0
75-50-2
SPECIES
NAME
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
ISO-PROPYL ALCOHOL
DICHLOROMETHANE
MOL.
WEIGHT
16
30
44
58
58
60
84
.04
.07
.09
.12
.12
.09
.94
PERCENT
WEIGHT
37.66
9.99
3.30
1.1.49
1 . 80
0 . 90
34 . 87
SUM TOTAL
100.OO
DATE : 04-2.1.-1988
240
-------
PROFILE NAMEsPrinting/Publishing - Ink Thinning Solvents -
Methyl Isobutyl Ketone
PROFILE NUMBER:1022
PROFILE DATA QUALITY:E
CONTROL DEVICE:Uncontrolled
REFERENCE(S)si
DATA SOURCEsEngineering judgement.
SCC ". 40500507
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43560 108-81-1 METHYL ISOBUTYL KETONE 100.16 100.00
SUM TOTAL 100.00
DATE :04-22-1988
241
-------
PROFILE NAME:Printing/Flexographic
PROFILE NUMBER 51086
PROFILE DATA QUALITYsC
CONTROL DEVICErNot reported
REFERENCE(S):19,32
DATA SOURCE 5 Composite profile developed using data from volatile
organic source tests at two facilities.
SCC : 40500301 40500311 40500312
SAROAD CAS
NUMBER NUMBER
43551 67-76-1
43552 78-89-3
43560 563-38-4
45202 108-88-3
SPECIES
NAME
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
TOLUENE
MOL.
WEIGHT
58 . 08
72.10
100.16
92.13
SUM TOTAL
PERCENT
WEIGHT
24.47
54.27
14.78
6.48
100.00
DATE :04-21-1988
242
-------
PROFILE NAME:Graphic Arts - (Printing)
PROFILE NUMBER:1191
PROFILE DATA QUALITY:B
CONTROL DEVICE:Uncontrolled
REFERENCE(S) s 90
DATA SQURCE:Distrillates from five samples of lithographic, roto-
gravure, flexographic, and letter press inks from four
printing companies composite based on 1978 emissions
data. Semivolatiles analysed by GC/MS.
SCC : 40500701 40500601 80
40588801
SAROAD
NUMBER
43114
43125
43155
43156
43248
43273
43332
43333
43334
43335
43434
43444
43474
43475
45304
45330
45402
45452
45456
45706
45731
9O03O
90049
9OO71
90077
90096
90097
90125 '
CAS
NUMBER
43-32-8
110-08-8
109-96-4
108-82-4
65-58-0
84-47-2
26471-16-5
544-47-3
629-99-7
SPECIES
NAME
ISOMERS OF PENTADECANE
CIO OLEFINS
ISOMERS OF HEPTADECANE
ISOMERS OF OCTADECANE
CYCLOHEXANE
CYCLOHEXENE
DIMETHYLOCTANOL
DIMETHYLHEPTANOL
METHYLHEPTANOL
METHOXYETHOXYETHANQL
N-PROPYL ACETATE
ISOPROPYL ACETATE
METHYLMETHYLPROPENOATE
METHYLETHYLPENTANOATE
C5-ALKYLPHENOL
BIPHENYLOL
BENZOIC ACID
D I BUTYL PHTHALATE
BUTYL I SOPROPYLPHTHAL ATE
N-PHENYL ANILINE
TOLUENE DIISOCYANATE
HEXADECANE
METHYLUNDECANE
DIMETHYLUMDECANE
ETHYLOCTANE
TRIMETHYLOCTANE
TRIMETHYLDECANE
HENEICQSANE
MOL.
WEIGHT
212.41
140.27
240 . 47
254 . 50
84.16
82.14
159.29
145.26
131.24
120.00
102.15
102.13
100.13
0 . 00
164.25
170.00
122.13
278.35
171.22
169.24
174.17
226.45
170.34
184.36
142.29
156.31
182.35
296.59
PERCENT
WEIGHT
0 . 1 5
0.18
3.69
1.69
4.57
0 . 22
0 . 06
0 04
0 . 0 7
0 . 04
27 . 44
30.10
0 . 03
0 u 03
0.18
0 . 07
0 . 02
9 . 99
12.76
0 . 04
0 . 03
3' a 32
1 . 70
0 . 2 5
0 . 44
0.81
0 . 30
0 30
243
-------
continued (profile=119i)
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
90126 112-29-8
90127
90130 87-74-5
EICOSANE
NONADECANE
CARYOPHYLLENE
282.56
268.53
0.48
0.89
204.41 0.11
SUM TOTAL
100.0O
244
DATE :04-21-1988
-------
3.22 ORGANIC CHEMICAL STORAGE
Five basic storage vessel designs are used for organic chemical
storage: fixed roof, external floating roof, internal floating roof,
variable vapor space, and pressure. Typically, organic liquids in the
chemical industry are composed of pure chemicals or mixtures of chemicals
with similar true vapor pressures. Sources of emissions from organic
chemicals in storage include: fixed roof breathing losses, fixed roof
working losses, floating roof standing storage losses, floating roof
withdrawal losses, variable vapor space filling losses, and pressure tank
losses.
245
-------
PROFILE NAME:Fixed Roof Tank - Hexane
PROFILE NUMBER s 0230
PROFILE DATA QUALITY:E
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCE 5 Engineering judgement; information based on composite
survey data and inspection of stored product formula-
tion .
SCC
40717603 40717604
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43231 110-05-3
HEXANE
86.17
SUM TOTAL
100.00
100.00
DATE s04-21-1938
246
-------
PROFILE NAME;Fixed Roof Tank - Cyclohexane.
PROFILE NUMBER:0299
PROFILE DATA QUALITYsE
CONTROL DEVICES Uncontrolled
REFERENCE(S):59
DATA SOURCEsEngineering judgement; information based on composite
survey data and inspection of stored product formulation
SCC : 40717601 40717602
SAROAD CAS
NUMBER NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43248 110-08-7
CYCLOHEXANE
84.16
SUM TOTAL
100ป00
100.00
DATE 504-22-1988
247
-------
PROFILE NAME:Fixed Roof Tank -- Heptane
PROFILE NUMBER:0301
PROFILE DATA QUALITYsE
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCE:Engineering judgement; information based on composite
survey data and inspection of stored product formulatio
SCC : 40701605 40701606
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43232 142-28-5
HEPTANE
100.20
SUM TOTAL
100.00
100.00
DATE s04-21-1988
248
-------
PROFILE NAME:Printing Press - Flexographic,, n-Propyl Alcohol
PROFILE NUMBER:0304
PROFILE DATA QUALITY:E
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCEsEngineering judgement; information based on composite
survey data and inspection of solvent formulation.
SCC : 40700817 40700818
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43303 71-12-8 N-PROPYL ALCOHOL 60.10 100.00
SUM TOTAL 100.00
DATE :04-21-1988
249
-------
PROFILE NAME:Organic Chemical Storage - Methylamy1 Ketone
PROFILE NUMBER:1055
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not reported
REFERENCE(S):1
DATA SOURCE Engineering judgement.
SCC
40706813 40706814
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43562 110-04-0
METHYL AMYL KETONE
114.21
SUM TOTAL
100.00
100.00
DATE :O4-21-1988
'250
-------
PROFILE NAME:Organic Chemical Storage - N-Propyl Acetate
PROFILE NUMBER:1069
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not reported
REFERENCE(S):1
DATA SOURCE Engineering judgement.
SCC : 40704421 40704422
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43434 109-96-4
N-PROPYL ACETATE
102.15
SUM TOTAL
100.00
100.00
DATE :04-21-198S
251
-------
PROFILE NAME:Organic Chemical Storage - i-Butyl i-Butyrate
PROF ILE NUMBER:1087
PROFILE DATA QUALITYsE
CONTROL DEVICE:Not reported
REFERENCE(S):1
DATA SOURCEsEngineering judgement.
SCC
40704423 40704424
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEI6HT
PERCENT
WEIGHT
43451 297-78-8
ISOBUTYL ISOBUTYRATE
144.21
SUM TOTAL.
100.00
100.00
DATE ;04-22-1988
252
-------
PROFILE NAMEsl-PENTENE
PROFILE NUMBER s1103
PROFILE DATA QUALITYsE
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40782009
SAROAD
NUMBER
CAS
NUMBER-
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEI6HT
43224 109-96-1
1-PENTENE
70.13
SUM TOTAL
100.00
100.00
DATE :04-21-1988
253
-------
PROFILE NAMEsACETALDEHYDE
PROFILE NUMBER:1104
PROFILE DATA QUALITYsE
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE Engineering judgement.
SCC :
SAROAD
NUMBER
40781201
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43503 75-50-0
ACETALDEHYDE
44.05
SUM TOTAL
100.00
100.00
DATE 504-21-1988
254
-------
PROFILE NAME:ACETIC ACID
PROFILE NUMBER51105
PROFILE DATA QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S) -.76
DATA SOURCE:Engineering judgement.
SCC : 40704002 40704001
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43404 69-91-7
ACETIC ACID
60.05
SUM TOTAL
100.00
100.00
DATE .: 04-21-1988
255
-------
PROFILE NAME:ACETIC ANHYDRIDE
PROFILE NUMBERs1106
PROFILE DATA QUALITYsE
CONTROL DEVICEnControlled/Uncontrolled
REFERENCE(S): 76
DATA SOURCE:Engineering judgement.
SCC : 40700402 40700401
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43604 108-82-7
ACETIC ANHYDRIDE
102.09
SUM TOTAL
100.00
100.00
DATE s04-21-1988
256
-------
PROFILE NAMEsACROLEIN
PROFILE NUMBER:1107
PROFILE DATA QUALITY:E
CONTROL DEVICE s Contro11ed/Uncontro11ed
REFERENCE(S):76
DATA SOURCEsEngineering judgement.
SCC
40781202
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WE IBHT
43505 107-70-8
ACROLEIN
56.07
SUM TOTAL
100.OO
100 00
. DATE -.04-21-1988
257
-------
PROFILE NAME:ACRYLIC ACID
PROFILE NUMBER si 108
PROFILE DATA QUALITYsE
CONTROL DEVICE .-Control led/Uncon trol led
REFERENCE(S): 76
DATA SOURCE;Engineering judgement.
SCC s 40704003 40704004
SAROAD CAS
NUMBER NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43407 79-91-7
ACRYLIC ACID
72.06
SUM TOTAL
100.00
10000
DATE s04-21-1988
258
-------
;'ROFILE NAMEsACRYLONITRILE
:'ROFILE NUMBER: 1109
:'ROFILE DATA QUALITYsE
:ONTROL DEVICE:Con trolled/Uncontrolled
-------
PROFILE NAMEsADIPIC ACID
PROFILE NUMBER:1110
PROFILE DATA QUALITYsE
CONTROL DEVICEsControlled/Uncontrolled
REFERENCE(S):76
DATA SOURCES Engineering judgement.
SCC
40704005 40704006
SAROAD
NUMBER
CAS
NUMBER-
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43409 124-40-9
ADIPIC ACID
146.14
SUM TOTAL
100.00
100.00
DATE :04-21-1988
260
-------
PROFILE NAME5ANILINE
PROFILE NUMBERS 1111
PROFILE DATA QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE-.Engineer ing judgement.
SCC : 40703201 40703202
SAROAD
NUMBER
CAS
NUMBER-
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45701 62-25-3
ANILINE
93.13
SUM TOTAL
100.00
100.00
DATE 304-21-1988
261
-------
PROFILE NAME:BENZYL CHLORIDE
PROFILE NUMBER:1112
PROFILE DATA QUALITYsE
CONTROL DEVICEsControlled/Uncontrolled
REFERENCE(S):76
DATA SQURCE:Engineering judgement.
SCC
40706001 40706002
SAROAD
NUMBER
CAS
NUMBER-
SPECIES
NAME
MOL.
WEIGHT'
PERCENT
WEIGHT
45810 100-04-7
BENZYL CHLORIDE
126.59
SUM TOTAL
.1.00.00
100.00
DATE :04-22-1988
262
-------
PROFILE NAME:BUTYL ACRYLATE
PROFILE NUMBERs1114
PROFILE DATA QUALITYsE
CONTROL DEVICE:Contro11ed/Uncontro11ed
REFERENCE(S):76
DATA SOURCE{Engineering judgement.
SCC : 40704403 40704404
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIBUT
PERCENT
WEIGHT
43440 141-13-2
BUTYL ACRYLATE
128.17
SUM TOTAL
10000
100,, 00
DATE s04-21-1983
263
-------
PROFILE NAME:BUTYL CARBITQL
PROFILE NUMBERs1115 :
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40705202 40705201
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43379 112-23-5
BUTYL CARBITOL
162.23
SUM TOTAL
100.00
100.00
DATE :04-21-1988
264
-------
PROFILE NAME:BUTYL CELLOSOLVE
PROFILE NUMBER:1116
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40705204 40705203
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43308 111-17-2
BUTYL CELLOSOLVE
118.17
SUM TOTAL
100.00
100.00
DATE :04-21-1988
265
-------
PROFILE NAME:CARBITOL
PROFILE NUMBER:1118
PROFILE DATA QUALITY:E
CONTROL DEVICEsControlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40705205 40500302 40200905 4O705206
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43377 111-19-0 CARBITOL 134.18 100.00
SUM TOTAL 100.00
DATE :04-21-1988
' 266 ' '"" ' ' '
-------
PROFILE NAME:CARBON TETRACHLORIDE
PROFILE NUMBER:1119
PROFILE DATA QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering Judgement
SCC : 40706005 40722001 40722002 40706006
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43804 56-62-5 CARBON TETRACHLORIDE 153.84 100.00
SUM TOTAL 100.00
DATE :04-21-1988
267
-------
PROFILE NAME:CHLOROFORM
PROFILE NUMBERs1121
PROFILE DATA QUALITYsE
CONTROL DEVICE!Control led/Uncontrolled
REFERENCE(S): 76
DATA SOURCE:Engineering judgement.
SCC : 40722004 40722003
SAROAD
NUMBER
CAS
NUMBER-
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43803 67-76-3
CHLOROFORM
119.39
SUM TOTAL
100.OO
100.00
DATE :04-21-1988
268
-------
PROFILE NAMEsCRESOL
PROFILE NUMBER:1122
PROFILE DATA QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC
40703604 40703603
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45605
CRESOL
108.14
SUM TOTAL
100.00
100.00
DATE :04-21-1988
'269
-------
PROFILE NAME:CUMENE
PROFILE NUMBER:1123
PROFILE DATA QUALITYrE
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE .-Engineering judgement.
SCC : 40703605 40703606
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
45210 98-88-8 CUMENE (ISOPROPYL BENZENE) 120.20 100.00
SUM TOTAL 100.00
DATE 5 04-21.-1988
270'' '
-------
PROFILE NAME:CYCLOHEXANOL
PROFILE NUMBER:1124
PROFILE DATA QUALITY:E
CONTROL DEVICE:Contro11ed/Uncontro11ed
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40700807 40700808
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43317 108-89-0
CYCLOHEXANOL
100.16
SUM TOTAL
100.00
100.00
DATE :04-21-1988
271
-------
PROFILE NAME:CYCLOHEXANONE
PROFILE NUMBER:1125
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE Engineering judgement.
SCC : 40706802 40706801
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MQL.
WEIGHT
PERCENT
WEIGHT
43561 108-89-1
CYCLOHEXANONE
98.15
SUM TOTAL
100.00
100.00
DATE :04-21-1983
272
-------
PROFILE NAME:CYCLOPENTENE
PROFILE NUMBER:1126
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE Engineering judgement.
SCC : 40782011
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43292 142-22-0
CYCLOPENTENE
68.11
SUM TOTAL
100.00
100.00
DATE :04-21-1988
273 .
-------
PROFILE NAME:DIETHYLENE GLYCOL
PROFILE NUMBER:1127
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SQURCEzEngineering judgement.
SCC
40705210 40705209
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43373 111-14-6
DIETHYLENE GLYCOL
106.12
SUM TOTAL
100.00
100.00
DATE :04-21-1988
274
-------
PROFILE NAME'.DIISOPROPYL BENZENE
PROFILE NUMBER:1128
PROFILE DATA QUALITY:ฃ
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC
40703607 40703608
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45236
DIISOPROPYL BENZENE
162.28
SUM TOTAL
100.00
100.OO
DATE :04-21-1988
275
-------
PROFILE NAMEsDIPROPYLENE 6LYCOL
PROFILE NUMBER:1129
PROFILE DATA QUALITY:E
CONTROL DEVICE:Contro11ed/Uncontro11ed
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC
40705605 40705606
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43374 106-66-7
DIPROPYLENE GLYCOL
134.18
SUM TOTAL
100.00
100.00
DATE :04-21-1988
276
-------
PROFILE NAME:DODECENE
PROFILE NUMBER si130
PROFILE DATA QUALITYrE
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40702002 40702001
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
90001 112-24-4
DODECENE
168.32
SUM TOTAL
100.00
100.00
DATE :04-21-1988
277
-------
PROFILE NAME:EPICHLOROHYDRIN
PROFILE NUMBER:1131
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40706013 40706014
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43863 106-68-8
EPICHLOROHYDRIN
92.53
SUM TOTAL
100.00
100.00
DATE :04-21-1988
278
-------
PROFILE NAME:ETHANOLAMINES
PROFILE NUMBER:1132
PROFILE DATA QUALITY:E
CONTROL DEVICE Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40703203 40703204
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43777 141-14-5
ETHANOLAMINE
61.08
SUM TOTAL
100.00
100.00
DATE :04-21-1988
279
-------
PROFILE NAMEsETHYL ACRYLATE
PROFILE NUMBER:1134
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40704408 40704407
SAROAD
NUMBER
CAS
NUMBER
43438 140-08-5
SPECIES
NAME
ETHYL ACRYLATE
MOL.
WEIGHT
100.11
SUM TOTAL
PERCENT
WEIGHT
100.00
100.00
DATE s04-21-1988
280
-------
PROFILE NAME:ETHYL BENZENE
PROFILE NUMBER:1135
PROFILE DATA QUALITY:E
CONTROL DEVICE Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE Engineering judgement.
SCC : 40703610 40703609
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45203 100-04-4
ETHYLBENZENE
106.16
SUM. TOTAL
100.00
100.00
DATE :04-21-1988
281
-------
PROFILE NAME:ETHYL ETHER
PROFILE NUMBER:1136
PROFILE DATA QUALITY:E
CONTROL DEVICE:Contro11ed/Uncon tro11 ed
REFERENCE(S):76
DATA SOURCE Engineering judgement.
SCC : 40720802 40720801
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43351 60-02-7
ETHYL ETHER
74.12
SUM TOTAL
100.00
100.00
DATE :04-21-1988
282
-------
PROFILE NAME:ETHYL MERCAPTAN
PROFILE NUMBER si137
PROFILE DATA QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC 5 40723201 40723202
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43902 75-50-1
ETHYL MERCAPTAN
62.13
SUM TOTAL
100.00
100.00
DATE :04-21-1988
:'' 283
-------
PROFILE NAMEsETHYLENE DIBROMIDE
PROFILE NUMBER si138
PROFILE DATA QUALITY:E
CONTROL DEVICErControlled/Uncontrolled
REFERENCE(S)s76
DATA SOURCE:Engineering judgement.
SCC : 40706016 40706015
SAROAD
NUMBER
CAS
NUMBER-
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43837 106-69-4
ETHYLENE DIBROMIDE
187.88
SUM TOTAL
100.00
100.00
DATE :O4-21-1988
284
-------
:'ROFILE NAMEsETHYLENEAMINES
:1ROFILE NUMBER: 1139
^ROFILE DATA QUALITY:E
:ONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S): 76
)ATA SOURCE:Engineering judgement.
3CC : 40703206 40703205
3AROAD
JUMBER
CAS
NUMBER-
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
13778
ETHYLENEAMINES
43.07
SUM TOTAL
100.00
100.00
DATE :04-21-1988
285
-------
PROFILE NAME:FORMALDEHYDE
PROFILE NUMBER:1140
PROFILE DATA QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE Engineering judgement.
SCC : 40717208 40717207
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43502 50-00-0
FORMALDEHYDE
30.03
SUM TOTAL
100.00
100.00
DATE :04-21-1988
286
-------
PROFILE NAME:FORM1C ACID
PROFILE NUMBER:1141
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC
40704008 40704007
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43403 64-41-6
FORMIC ACID
46.03
SUM TOTAL
100.00
100.00
DATE :04-21-1988
287
-------
PROFILE NAME:HEPTENES
PROFILE NUMBER:1144
PROFILE DATA QUALITY:E
CONTROL DEVICE:Contro11ed/Uncontro11ed
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40702004 40702003
SAROAD
NUMBER
CAS
NUMBER-
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43264
HEPTENE
98.18
SUM TOTAL
100.00
100.00
DATE :04-21-1988
288
-------
PROFILE NAME:ISOBUTYRLDEHYDE
PROFILE NUMBER:1145
PROFILE DATA QUALITYrE
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40717210 40717209
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43511 78-88-2
ISOBUTYRALDEHYDE
72.11
SUM TOTAL
100.00
100.00
DATE :04-21-1988
289
-------
PROFILE NAME:ISOBUTYL ACRYLATE
PROFILE NUMBER:1146
PROFILE DATA QUALITY:E
CONTROL DEVICE.-Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCEsEngineering judgement.
SCC : 40704410 40704409
SAROAD
NUMBER
CAS
NUMBER-
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43468 106-66-8
ISOBUTYL ACRYLATE
128.19
SUM TOTAL
100.00
100.00
DATE -..04-21-1988
290
-------
PROFILE NAME:ISOBUTYL ALCOHOL
PROFILE NUMBER:1147
PROFILE DATA QUALITYsE
CONTROL DEVICE-.Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40700811 40700812
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43306 78-88-1
ISOBUTYL ALCOHOL
74.12
SUM TOTAL
100.00
100.00
DATE :04-21-1988
291
-------
PROFILE NAME:ISOPRENE
PROFILE NUMBER:1148
PROFILE DATA QUALITYrE
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC
40782007
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43243 78-87-5
ISOPRENE
68.12
SUM TOTAL
100.00
100.00
DATE :04-21-1988
292
-------
PROFILE NAME:METHYL ACETATE
PROFILE NUMBER:1150
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE Engineering judgement.
SCC : 40704413 40704414 40200916
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43432 79-92-9
METHYLACETATE
74.08
SUM TOTAL
100.00
100.00
DATE :04-21-1988
293
-------
PROFILE NAME:METHYL ACRYLATE
PROFILE NUMBER:1151
PROFILE DATA QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE Engineering judgement.
SCC : 40704415 40704416
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43437 96-63-3
METHYL ACRYLATE
86.09
SUM TOTAL
100.00
100.00
DATE :04-21-1988
294 '
-------
PROFILE NAME:METHYL CARBITOL
PROFILE NUMBER:1152
PROFILE DATA QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE Engineering judgement.
SCC t 40705211 40705212
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43378 111-17-3
METHYL CARBITOL
120.15
SUM TOTAL
100.00
100.00
DATE :04-21-1988
295
-------
PROFILE NAME:METHYL CELLOSOLVE
PROFILE NUMBER:1153
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC
40705213 40705214
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43310 109-98-4
METHYL CELLOSOLVE
76.11
SUM TOTAL
100.00
100.00
DATE :04-21-1988
296
-------
PROFILE NAME:METHYL STYRENE
PROFILE NUMBER:1154
PROFILE DATA QUALITY:ฃ
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE Engineering judgement.
SCC : 40703611 40703612
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45221 25013-31-4
METHYL STYRENE
118.19
SUM TOTAL
100.00
100.00
DATE :04-21-1988
297
-------
PROFILE NAME:METHYLALLENE
PROFILE NUMBER:1155
PROFILE DATA QUALITY:E
CONTROL DEVICE-.Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC
40782008
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
90011
METHYLALLENE
54.09
SUM TOTAL
100.00
100.00
DATE :04-21-1988
298
-------
PROFILE NAME:METHYL t-BUTYL ETHER
PROFILE NUMBER:1158
PROFILE DATA QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE Engineering judgement.
SCC
40704801 40704802
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43376 628-82-4
METHYL T-BUTYL ETHER
88.15
SUM TOTAL
100.00
100.00
DATE :04-21-1988
299
-------
PROFILE NAME:M-XYLENE
PROFILE NUMBER:1159
PROFILE DATA QUALITYsE
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC
40703618 40703617
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45205 108-83-3
M-XYLENE
106.16
SUM TOTAL
100.00
100.00
DATE :04-21-1988
300
-------
PROFILE NAME:NITROBENZENE
PROFILE NUMBER:1160
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40708002 40708001
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45702 98-89-3
NITROBENZENE
123.11
SUM TOTAL
100.00
100.00
DATE :04-21-1988
301
-------
PROFILE NAME:N-BUTRALDEHYDE
PROFILE NUMBER si162
PROFILE DATA QUALITY:E
CONTROL DEVICErControlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC s 40717206 40717205
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43510 123-37-8
BUTYRALDEHYDE
72.12
SUM TOTAL
100.00
100.00
DATE s04-21-1988
302
-------
>ROFILE NAMEsN-DECANE
:'ROFILE NUMBER: 1163
:'ROFILE DATA QUALITY:E
:ONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
)ATA SQURCErEngineering judgement.
3CC
40701602 40701601
3AROAD
DUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEK3HT
PERCENT
WE I SI-IT
*3238 124-41-5
N-DECANE
142.28
SUM TOTAL
100.0O
100.00
DATE :04-21-1988
303
-------
PROFILE NAME:N-DODECANE
PROFILE NUMBER:1164
PROFILE DATA QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40701603 40701604
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43111
ISOMERS OF DODECANE
170.32
SUM TOTAL
100.00
100.00
DATE -.04-21-1988
304
-------
PROFILE NAME:0-XYLENE
PROFILE NUMBER si165
PROFILE DATA QUALITYsE
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S): 76
DATA SOURCE:Engineering judgement.
SCC : 40703619 4070362O
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45204 95-54-6
0-XYLENE
106.16
SUM TOTAL
100.00
100.00
DATE :04-21-1988
305
-------
PROFILE NAME:PENTADECANE
PROFILE NUMBER." 1166
PROFILE DATA QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE Engineering judgement.
SCC : 40701610 40701609
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43114 ISOMERS OF PENTADECANE 212.41 100.00
SUM TOTAL 100.00
DATE :04-21-1988
306
-------
PROFILE NAME:PIPERYLENE
PROFILE NUMBER si168
PROFILE DATA QUALITYsE
CONTROL DEVICE:Controlied/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40782010
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45750 504-46-9
PIPERYLENE
68.12
SUM TOTAL
100.00
100.00
DATE :04-21-1988
307
-------
PROFILE NAME:PROPIONALDEHYDE
PROFILE NUMBER:1171
PROFILE DATA QUALITYrE
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S): 76
DATA SOURCErEngineering judgement.
SCC
40717211 40717212
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43504 123-33-6
PROPIONALDEHYDE
58.08
SUM TOTAL
100.00
100.00
DATE :04-21-1988
308
-------
PROFILE NAME:PROPION1C ACID
PROFILE NUMBER:1172
PROFILE DATA QUALITY:E
CONTROL DEVICE:Contro11ed/Uncontro11ed
REFERENCE(S):76
DATA SOURCEsEngineering judgement.
SCC
40704009 40704010
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43405 79-90-4
PROPIONIC ACID
74. OS
SUM TOTAL
100.00
100.00
DATE :04-21-1988
309
-------
PROFILE NAMErPROPYLENE OXIDE
PROFILE NUMBER:1173
PROFILE DATA QUALITYrE
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCEsEngineering judgement.
SCC : 40720804 40720803
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43602 75-55-9
PROPYLENE OXIDE
58.08
SUM TOTAL
100.00
100.00
DATE :04-21-1988
310
-------
PROFILE NAME:P-XYLENE
PROFILE NUMBER:1174
PROFILE DATA QUALITY:E
CONTROL DEVICE:Con tro11ed/Uncontro11ed
REFERENCE(S):76
DATA SOURCE-.Engineer ing judgement.
SCC
40703622 40703621
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45206 106-64-3
P-XYLENE
106.16
SUM TOTAL
100.00
100.00
DATE :04-21-1988
311
-------
PROFILE NAMEsTERT- BUTYL ALCOHOL
PROFILE NUMBER si175
PROFILE DATA QUALITYsE
CONTROL DEVICErControlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement.
SCC : 40700805 40700806
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43309 75-56-0
TERT-BUTYL ALCOHOL
74.12
SUM TOTAL
100.00
100.00
DATE :04-21-1988
312
-------
PROFILE NAME:TOLUENE DIISOCYANATE
PROFILE NUMBER:1176
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCE Engineering Judgement
SCC
40706403 40706404
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45731 26471-16-5
TOLUENE DIISOCYANATE
174.17
SUM TOTAL
100.00
100.00
DATE :04-21-1988
313
-------
PROFILE NAME:Isooctane
PROFILE NUMBER:1197
PROFILE DATA QUALITY:E
CONTROL DEVICE:Controlled/Uncontrolled
REFERENCE(S):76
DATA SOURCEsEngineering judgement
SCC : 40300113
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME . WEIGHT WEIGHT
43250 540-08-1 2,2,4-TRIMETHYLPENTANE 114.22 100.00
SUM TOTAL 100.00
DATE :04-22-1983
314
-------
PROFILE NAME:Pentane
PROFILE NUMBER:1198
PROFILE DATA QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S)576
DATA SOURCE Engineering judgement.
SCC : 40300115
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43220 109-96-0
N-PENTANE
72.15
SUM TOTAL
100.00
100.00
DATE :04-22-1988
315
-------
PROFILE NAME:Isopentane
PROFILE NUMBER:1199
PROFILE DATA QUALITYsE
CONTROL DEVICE:Con troI led/Uncontrolled
REFERENCE(S):76
DATA SOURCEsEngineering judgment
SCC : 40300114
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43221 78-87-4
ISO PENTANE
72.15
SUM TOTAL
100.00
100.00
DATE :04-22-1988
316
-------
PROFILE NAME:Cyclopentane
PROFILE NUMBERS 1200
PROFILE DATA'QUALITY:E
CONTROL DEVICE:Control led/Uncontrolled
REFERENCE(S):76
DATA SOURCE:Engineering judgement
SCC
40300210
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43242 287-79-3
CYCLOPENTANE
70.14
SUM TOTAL
100.00
100.00
DATE :04-22-1988
317
-------
3.23 RAILCAR, TANK TRUCK, AND DRUM CLEANING
Rail tank cars, tank trucks, and drums are used to transport about
700 different commodities. Rail tank cars and most tank trucks and drums
are in dedicated service (carrying one commodity only) and, unless
contaminated, are cleaned only prior to repair or testing. Cleaning agents
include steam, water, detergents, and solvents which are applied using steam
hoses, pressure wands, or rotatory spray heads. Vapors from cleaning which
are not flared or dissolved in water are emitted to the atmosphere.
318
-------
='ROFILE NAME:Railcar Cleaning - Low Vapor Pressure, High
Viscosity Cargo (Ethylene Slycol)
PROFILE NUMBER:1078
=-ROFILE DATA QUALITY:D
CONTROL DEVICE:Not reported
REFERENCE(S):55
DATA SOURCE:Information based on measurement from one emission
source.
3CC : 49000301
3AROAD
MUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43370 107-74-5
ETHYLENE GLYCOL
62.07
SUM TOTAL
100.00
100.00
DATE :04-21-1988
319
-------
PROFILE NAME:Rail Car Cleaning - Low Vapor Pressure, Medium
Viscosity Cargo (o-Dichlorobenzene)
PROFILE NUMBER:1079
PROFILE DATA QUALITYsD
CONTROL DEVICE:Not reported
REFERENCE(S):55
DATA SOURCE:Information based on measurement from one emission
source.
SCC : 49000303
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45805 95-55-1
0-DICHLOROBENZENE
147.01
SUM TOTAL
100.00
100.00
DATE :04-21-1988
320
-------
ROFILE NAME:Rail Car Cleaning - Low Vapor Pressure, High
Viscosity Cargo (Creosote)
ROFILE NUMBER:1080
ROFILE DATA QUALITY:D
ONTROL DEVICE:Not reported
EFERENCE(S): 55
ATA SOURCE:Information based on measurement from one emission
source.
CC
49000304
AROAD
UMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIBHT
PERCENT
WEIGHT
6210 8001-15-9
CREOSOTE
130.19
SUM TOTAL
100.00
100.00
DATE :04-21-1988
321
-------
PROFILE NAME:Tank Truck Cleaning - Medium Vapor Pressure,
Medium Viscosity Cargo (Methyl Methacrylate)
PROFILE NUMBER:1081
PROFILE DATA QUALITY:D
CONTROL DEVICE:Not reported
REFERENCE(S):55
DATA SOURCE:Information based on measurement from one emission
source.
SCC : 49000403
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43441 80-06-6
METHYL METHACRYLATE
100.13
SUM TOTAL
100.00
100.00
DATE :04-21-1988
322
-------
PROFILE NAME:Tank Truck Cleaning - Low Vapor Pressure, Low
Viscosity Cargo (Phenol)
PROFILE NUMBER:1082
PROFILE DATA QUALITY:D
CONTROL DEVICE:Not reported
REFERENCE(S): 55
DATA SOURCE:Information based on measurement from one emission
source.
SCC
49000404
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45300 108-89-2
PHENOL
94.11
SUM TOTAL
100.00
100.00
DATE :04-21-1988
323
-------
PROFILE NAME:Tank Truck Cleaning.- Low Vapor Pressure, High
Viscosity Cargo (Propylene Glycol)
PROFILE NUMBER:1083
PROFILE DATA QUALITY:D
CONTROL DEVICE:Not reported
REFERENCE(S):55
DATA SOURCE:Information based on measurement from one emission
source.
SCC : 49000405
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43369 57-75-6
PROPYLENE GLYCOL
76.00
SUM TOTAL
100.00
100.00
DATE :04-21-1988
324
-------
3.24 SOLID WASTE DISPOSAL
Solid waste sources can be industrial, urban, agricultural, or
construction. Solid waste may be disposed of in landfills or land
application units or incinerated. A large percentage of urban and
industrial waste is burned. Waste burning processes include open burning-
and controlled and uncontrolled incineration where significant particulate
emissions may be generated.
325
-------
PROFILE NAME:Open Burning Dump - Landscape/Pruning
PROFILE NUMBER:0121
PROFILE DATA QUALITY:C
CONTROL DEVICEsUncontrolled
REFERENCE(S):60
DATA SOURCE Calculations from composite survey data and engineering
evaluation of literature data.
SCC
50100202 25
SAROAD CAS
NUMBER NUMBER
43121
43203 74-48-1
43204 74-49-6
43206 540-04-8
43212 106-69-8
43213 106-69-9
43214 75-52-5
43220 109-96-0
43224 109-96-1
43231 110-05-3
43232 142-28-5
43233 111-16-9
SPECIES
NAME
ISOMERS OF PENTENE
ETHYLENE
PROPANE
ACETYLENE
N-BUTANE
BUTENE
ISO-BUTANE
N-PENTANE
1-PENTENE
HEXANE
HEPTANE
OCTANE
MOL.
WEIGHT
70.13
28.05
44 . 09
26 . 04
58.12
56.10
58.12
72.15
70.13
86.17
100.20
114.23
SUM TOTAL
PERCENT
WEIGHT
1 1 . 80
19.40
1.90
1.90
1 . 90
5.90
1 . 90
1.90
11.80
13.90
13.90
13.80
100.00
326
DATE :04-21-1988
-------
PROFILE. NAME:Bar Screen Waste Incinerator
PROFILE NUMBER:0122
PROFILE DATA QUALITY:D
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCE:Calculations from composite survey data and GC/MS
analysis of grab sample.
SCC
50100102 50100101
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43202 74-48-0
43203 74-48-1
43205 79-92-9
45201 71-14-2
SPECIES
NAME
METHANE
ETHANE
ETHYLENE
PROPENE
BENZENE
MOL.
WEIGHT
16.04
30 . 07
28.05
42.08
78.11
PERCENT
WEIGHT
80 . 40
2.70
8 . 70
0 . 50
7.70
SUM TOTAL
100.00
DATE :04-21-1988
327
-------
PROFILE NAMEsSolid Waste Landfill Site - Class II
PROFILE NUMBER:0202
PROFILE DATA QUALITY:C
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59
DATA SOURCE:Information based on composite survey data and GC/MS
analysis of grab samples.
SCC
50200602
SAROAD CAS
NUMBER NUMBER
43123
43201 74-48-8
43202 74-48-0
43204 74-49-6
43212 106-69-8
43214 75-52-5
43220 109-96-0
43242 287-79-3
43817 127-71-4
45102
45202 108-88-3
SPECIES
NAME
TERPENES
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
CYCLOPENTANE
PERCHLOROETHYLENE
ISOMERS OF XYLENE
TOLUENE
MOL.
WEIGHT
136.23
16.04
30 . 07
44 . 09
58.12
58.12
72.15
70.14
165.83
106.16
92.13
PERCENT
WEIGHT
0.10
98 . 70
0.10
0.10
0 . 20
0.10
0.10
0.10
0 . 30
o.io
0.10
SUM TOTAL
100.00
DATE :04-21-1988
328
-------
PROFILE NAME:Solid Waste - Animal Waste Decomposition
PROFILE NUMBER:0203
PROFILE DATA DUALITY:C
CONTROL DEVICE:Uncontrolled
REFERENCE(S):59, 67, 68, 69, 70
DATA SOURCE:Information based on composite survey data and engi-
neering evaluation of literature data.
SCC
71
73
74
75
72.
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43202 74-48-0
43302 64-41-5
43304 67-76-0
43434 109-96-4
43551 67-76-1
43721 75-50-7
43740 75-55-3
SPECIES
NAME
METHANE
ETHANE
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
N-PROPYL ACETATE
ACETONE
ETHYL AM I NE
TRIMETHYLAMINE
MOL.
WEIGHT
16.04
30 . 07
46 . 07
60 . 09
102.15
58.08
45.09
59.11
PERCENT
WEIGHT
70 . 00
20 . 00
2 . 00
2 . 00
2 . 00
2 . 00
1 . 00
1 . 00
SUM TOTAL
100.00
DATE : 04-21-1988
329
-------
3.25 WOOD COMBUSTION
Wood is burned in industrial/commercial boilers to obtain heat energy
and to alleviate waste disposal problems in the pulp and paper industries.
Residential wood burning is commonly used to supplement conventional heating
systems. In the industrial sector, the burning of wood waste in boilers is
mostly confined to those industries where wood is available as a by-product.
A variety of boiler configurations is used for burning wood waste. These
include dutch oven configurations, spreader stokers, and tangentially-fired
or cyclone-fired boilers. Residential wood stoves are usually radiating or
circulatory designs constructed from cast iron, heavy gauge sheet metal, or
stainless steel. Emissions from wood combustion are affected by furnace
design and operating conditions, and fuel characteristics such as fuel
composition, moisture content, and effective burning surface area.
330
-------
PROFILE NAMErResidential Wood Combustion (C-l - C-6)
PROFILE NUMBER.-1084
PROFILE DATA QUALITY:D
CONTROL DEVICE:Catalyst
REFERENCE(S):15
DATA SOURCE:Five samples were taken into a preevacuated 3-liter
glass bulb. Four test runs were with a catalyst in
use, one when it was not. Samples were analysed using
a combination of mass spectrometry and trace gas
chrornatographic techniques. (See also profile 1167).
SCC
12
06
19
SAROAD CAS
NUMBER NUMBER
43201 74-48-8
43202 74-48-0
43203 74-48-1
43204 74-49-6
43205 115-50-1
43213 106-69-9
43214 75-52-5
43302 64-41-5
45201 71-14-2
99999
SPECIES
NAME
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
BUTENE
ISO-BUTANE
ETHYL ALCOHOL
BENZENE
UNIDENTIFIED
MOL.
WEIBHT
16.04
30 . 07
28.05
44.09
42 . 08
56.10
58.12
46 . 07
78.11
86 . 00
PERCENT
WEIBHT
38 . 39
5.21
16.38
1.37
2 . 00
0 . 49
0 . 09
16.47
18.91
0 . 68
SUM TOTAL
10O.OO
DATE :04-22-1988
331
-------
PROFILE NAME:Residential Wood Combustion
PROFILE NUMBER:1167
PROFILE DATA QUALITY:C
CONTROL DEVICE:Uncontrol.led/Catalyst
REFERENCE(S):77, 78, 79, 80, 81
DATA SOURCE:Composite profile developed from literature data from
66 tests. Tests weighted by burn rate and catalyst./
non-catalyst tests equally weighted. Profile based on
all species identified. (See also Profile 1084).
SCC : 19
12
SAROAD
NUMBER
43319
43502
43503
43504
43510
43511
45300
46701
46702
46704
46705
46706
46707
46708
46709
46710
46713
46714
46715
46716
46717
46718
46719
46720
46721
46722
46723
46724
CAS
NUMBER
71-14-0
50-00-0
75-50-0
123-33-6
123-37-8
78-88-2
108-89-2
91-12-3
208-89-8
83-33-9
86-67-7
85-50-8
120-01-7
206-64-0
129-90-0
218-80-9
56-65-3
205-59-2
207-70-9
50-03-8
193-33-5
191-12-2
53-37-3
198-85-0
192-29-2
SPECIES
NAME
PENTANOL
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
BUTYRALDEHYDE
ISOBUTYRALDEHYDE
PHENOL
NAPTHALENE
METHYL NAPHTHALENES
PHENYLNAPHTHALENES
ACENAPHTHYLENE
ACENAPHTHENE
FLUORENE
-PHENANTHRENE
ANTHRACENE
FLUORANTHENE
PYRENE
BENZO(g,h,i) FLUORANTHENE
CHRYSENE
BENZO (a) ANTHRACENE
BENZO (b) FLUORANTHENE
BENZO (k) FLUORANTHENE
BENZO (a) PYRENE
INDENO(l,2,3-cd) PYRENE
BENZO (g,h,,i) PERYLENE
DIBENZO(a,h) ANTHRACENE
PERYLENE
BENZO (e) PYRENE
MOL.
WEIGHT
88.15
30 . 03
44.05
58 . 08
72.12
72.11
94.11
123.11
142.20
204 . 27
152.20
154.21
166.22
178.23
178.23
202 . 26
202 . 26
252.32
228.29
228 . 30
252 . 32
252.32
252.32
276 . 34
276 . 34
278.35
252.32
252.32
PERCENT *
WEIGHT
0.25
0 . 66
0.24
0.18
2 . 08
1 . 70
6.84
43.65
0 ..00
0 . 00
7.19
1.22
2.59
16.84
0 . 00
3 . 63
3.35
1 . 30
2.39
0 . 00
1.14
0 . 00
0 . 9O
0 . 66
0 . 00
0 . 04
0 . 06
0 . 09
M
1
(i
(2
(2
(3
(3
(4
(4
(5
(5
332
-------
continued (prof 116=1167)
SAROAD CAS
NUMBER NUMBER
46725 191-12-4
46726 191-10-1
46727
46728
46729
46730
46731
46732
46733
46734 27208-83-3
46735 195-51-7
46736
46737
46738
46739
46740
46741
46742
46743
46744
46745.
SPECIES
NAME
ANTHANTHRENE
CORONENE
METHYL-ANTHRACENES
METHYL-PHENAMTHRENES
C2-ALKYL-ANTHRACENES
C2-ALKYL-PHENANTHRENES
CYCLOPENTA-ANTHRACENES
CYCLOPENTA-PHENANTHRENES
METHYL-FLUORANTHENES
CYCLOPENTA ( c , d ) PYRENE
BENZO ( c ) PHENANTHRENE
METHYL-BENZ ANTHRACENES
METHYL-BENZPHENANTHRENES
METHYL-CHRYSENES
C2-ALKYL-BENZ ANTHRACENES
C2-AL.KYL-BENZOPHENANTHRENES
C2-ALKYL-CHRYSENES
BEIMZOPYRENES
D I BEN Z ANTHRACENES
DIBEIMZPHENANTHRENES
DIBENZOPYRENES
MOL.
WEIGHT
276.34
300 . 36
192.26
192.26
158.24
206 . 28
247.36
190.25
216.29
226.28
228 . 30
242 . 33
f\/\i~\ ~T -r
^H-^:. . oo
^4.T> "!"-?
J!.*TJ:, ..ซ-'
256.35
230.31
256.34
252.32
278.35
278 . 36
302.38
PERCENT
WEIGHT
0 .OB
0 . 03
0 . 93
( > . 00
0.17
< ) . 00
0.14
< ) . 00
0 . 40
0.22
0 . 07
0.21
0 . 00
0 . 00
0.41
0 . 00
0 . 00
0 . 29
0 . 03
0.00
0 . 02
(6 )
(6 )
(7 )
(7 )
(8 )
(8 )
(9 )
(9 )
(9 )
(10)
(10)
(10)
(11)
(11)
SUM TOTAL
.100.00
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
333
DATE :05-03-1988
-------
3.26 MOBILE SOURCES
Because of their widespread use, the internal combustion gasoline
powered engine in mobile applications is a major source of VOC emissions.
Gasoline fueled light-duty vehicles account for about 75 percent of VOC
emissions from mobile sources (1983). Automotive VOC emissions consist of
exhaust emissions that occur from the tailpipe, evaporative emissions that
occur from (1) the gas tank as the temperature rises during the day, (2) the
carburetor after the engine has been shut off (hot soak emissions), and
(3) emissions from vehicle refueling. This section also contains data on
diesel vehicles. Profile data for refueling are included in Section 3.20.
334
-------
PROFILE NAME:Light Duty Gasoline Vehicles
PROFILE NUMBER:110i
PROFILE DATA QUALITY:B
CONTROL DEVICE:Catalyst
REFERENCE(S):56
DATA SOURCE:Composition data collected using GC/FID and DNPH
methods for exhaust and evaporative (hot soak)
emissions from 45 cars were composited. Based on. AP-42
(4th. edition), data were weighted according to travel
fractions.
SCC : 30
29
28
27
3AROAD CAS
NUMBER NUMBER
43135
43136
43201
43202
43203
43204
43205
43206
43208
43209
43211
43212
43213
43214
43215
43216
43217
43218
43220
43221
43223
43224
43226
43227
43228
43229
43230
43231
74-48-8
74-49-0
74-48-1
74-49-6
115-50-1
74-48-2
463-34-0
74-49-7
760-02-3
106-69-8
106-69-9
75-52-5
115-51-7
624-46-6
590-01-1
106-69-0
109-96-0
78-87-4
563-34-1
109-96-1
646-60-8
627-72-3
513-33-9
107-78-5
96-61-0
110-05-3
SPECIES
.NAME
CIO PARAFFINS
C9 PARAFFIN
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE .
PROPADIENE -
METHYLACETYLENE ( PROPYNE )
3-METHYL-l-PENTENE
N-BUTANE
BUTENE
ISO-BUTANE
ISOBUTYLENE
T-2-BUTENE
CIS-2-BUTENE
1,3-BUTADIENE.
N-PENTANE
ISO PENTANE
3-METHYL-l-BUTENE
1-PENTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-METHYL-2-BUTENE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
MOL.
WEIGHT
142
128
16.
30 .
28.
44.
. 42-.
26.
40.
40 .
84.
53.
56.
58.
56.
56.
56.
54.
72 .
72.
70.
70 .
70 .
70.
70.
86.
86.
86.
.28
.25
04
07
05
09
08
04
06 .
06
16
12
10
12
10
11
11
09
15
15
13
13
13
13
13
17
17
17
PERCENT
WEIGHT
0.
0.
10
1.
3.
1.
0.
0.
0.
0.
0.
9.
0.
1 .
0.
0.
0.
1.
o
6.
0 .
0.
0.
0.
0.
1.
1.
0.
16
00
.07
41
92
62
00
75
08
06
00
48
85
70
00
55
50
68
88
54
15
32
68
38
98
76
09
87
( 20 )
( 1)
( 1)
(7)
(3)
( 2 )
( 2 )
( 4)
( 5)
(' 3)
( 6)
( 3)
(10)
335
-------
continued (profile=il01)
SAROAD
NUMBER
43232
43233
43234
43235
43238
43241
43242
43243
43245
43247
43248
43250
43252
43261
43262
43263
43270
43272
43273
43274
43276
43277
43278
43279.
43280
43281
43282
43283
43284
43285
43286
43237
43290
43291
43292
43295
43296
43297"
43298
43299
43502
43503
43504
43505
43515
CAS
NUMBER
142-28-5
111-16-9
563-37-0
111-18-2
124-41-5
1120-02-4
287-79-3
78-87-5
592-24-6
108-80-7
110-08-7
540-O8-1
565-57-3
108-88-2
96-63-7
591-17-4
922-26-2
693-38-0
110-08-8
565-55-3
79-92-8
592-21-2
760-02-4
107-70-6
503-31-3
625-52-4
590-07-8
75-58-2
142-22-0
589-93-4
592-22-8
589-95-7
50-00-0
75-50-0
123-33-6
.107-70-8
123-37-9
SPECIES
NAME
HEPTANE
OCTANE
2,3 DIMETHYL-1-BUTENE
NONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
ISOFRENE
1-HEXENE
2, 4-D I METHYLPENTANE
GYCLOHEXANE
2,2, 4-TR I METHYLPENTANE
2 , 3 , 4-TR I METHYLPENTANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-METHYL HEXANE
3-METHYL-T-2-PENTENE
METHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENT ANE
2,3 DiMETHYLBUTANE
2 , 4-D I METHYLHEX ANE
2 , 5-D I METHYLHEX ANE
2-ETHYL-l-BUTENE
2,3,3 TR I METHYLPENTANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-FENTENE
2-HEXENE
DIMETHYLHEXENE
2,2 DIMETHYLHEXANE
2,3 DIMETHYLHEXANE
2,2-DIMETHYLBUTANE
CYCLOPENTENE
3-METHYLHEXANE
2-METHYLHEPTANE
4-METHYLHEPTANE
3-METHYLHEPTANE
i-METHYLCYCLOHEXENE
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACRQLEIN
CROTONALDEHYDE
MOL.
WEIGHT
100.20
114.23
. 84.16
128.25
142.28
156.31
70.14
68.12
84.16
100 .20
84.16
114'. 22
114.22
98.21
84.16
100.20
84.16
82.14
82.14
100.20
86.17
114.22
114.22
84.16
114.22
54 . 09
54 . 09
84.16
84.16
84.16
112.20
114.22
114.22
86.17
68.11
100.20
114.23
114.23
114.23
96.17
30 . 03
44.05
58 . 08
56 . 07
70 . 09
PERCENT
WEIGHT
0
0
0
0
0
0
0
0
o
0
^
1
0
0
0
o
0
0
0
1
0
0
o
0
1
o
o
0
o
0
o
o
0
0
o
1
0
0
o
0
0
0
o
o
0
.65
.31
. 00
.19
.16
.53
.35
.07
.31
.58
.79
.97
. 12
.50
.78
. 00
. 00
.01
.00
. 40
.69
.63
. 00
. 00
.09
. 00
. 00
. 00
.42
.16
. 12
.05
. 00
.21
.37
.06
.19
.45
.36
. 00 .
.74
.28
.02
.06
. 02
( 8
( 7
( 9
(12
(11
(13
(11
(14
(14
( 9
( 5
( 6
(10
(15
( 4
(16
(16
336
-------
continued (profile=110i
SAROAD
NUMBER
45110
45201
45202
45203
45204
45205
45206
45207
452O8
45209
45216
45217
4521B
45225
45501
90O02
90003
90004
.90005
90006
90007
90008
90009
90042
98033
98044
99910
99911
99912
99913
99915
99916
99917
99918
99999
CAS
NUMBER
71-14-2
108-88-3
100-04-4
95-54-6
108-83-3
106-64-3
108-86-8
95-56-6
103-36-1
135-59-8
135-50-3
141-19-5
526-67-8
100-05-7
691-13-2
13269-95-8
496-61-7
538-89-2
SPECIES
NAME
CIO AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
1 , 3 , 5-TR I METHYLBENZENE
1, 2, 4-TR I METHYLBENZENE
N-PROPYLBENZENE
S-BUTYLBENZENE
1,2 D I ETHYLBENZENE
M-D I ETHYLBENZENE
1,2, 3-TR I METHYLBENZENE
BENZALDEHYDE
2,3, 5-TR I METHYLHEX ANE
2,4 DIMETHYLHEPTANE
3,5 DIMETHYLHEPTANE
2,5 DIMETHYLHEPTANE
2,3 DIMETHYLHEPTANE . -
4-METHYL-i-PENTENE
2-METHYLOCTANE
2 , 4 , 5-TRIMETHYLHEPTANE
T-3-HEXENE
2 , 2 , 5-TRIMETHYLHEXANE
INDANE
2,4 DIMETHYLOCTANE
3,4 DIMETHYLOCTANE
l-METHYL-3-ETHYLBENZENE
l-METHYL-2-ETHYLBENZENE
ISOBUTYLBENZENE
1-METHYL-3N-PROPYLBENZENE
l-METHYL-3- 1 SOPROF'YLBENZENE
2-METHYLDECANE
UNIDENTIFIED
SUM
MOL.
WEI6HT
134.22
78.11 .
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
134.21
134.22
134.22
120.19
106.13
128.25
128.26
128.26
128.26
128.26
84.16
128.26
142.29
84.16
128.26
113.18
142.29
142.29
119.19
119.19
134.22
134 . 22
134.22
156.32
86 . 00
TOTAL
PERCENT
WEIGHT
2 . 02
0 . 00
5.14
0.77
1.56
0 . 00
2.56
1.87
2 . 30
0 . 48
0.11
0 . 59
0 . 59
0 . 66
0 . 08
0 . 09
0.11
0 . 00
0 . 73
0 . OO
0 . 00
0.01
0 . 26
0 . 29
0 . 46
0 . 52
0 . 07
0 . 74
1.06
0.21
0. 55
0.17
0 . 38
1 . 08
8.46
100.00
(12)
(15)
(13)
( 20 )
(19)
(19)
(17)
(17)
(18)
( 7)
V
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent. It was assumed that 85 percent of peak (3) is
due to n-Butane and 15 percent is due to 1,3-Butadiene.
337
DATE :08-10-1988
-------
PROFILE NAME:Heavy Duty Gasoline Trucks
PROFILE NUMBER:1186
PROFILE DATA QUALITY:C
CONTROL DEVICE:Uncontrolled
REFERENCE(S):35,36,37,38
DATA SOURCE:Exhaust emissions from four trucks combined with diur-
nal and hotsoak emissions from passenger car using
leaded gasoline.
SCC :
36
38
35
3AROAD CAS
NUMBER NUMBER
43135
43136
43201
43202
43203
43204
43205
43206
43208
43209
43211
43212
43213
43214
43215
43216
43217
43218
43220
43221
43223
43224
43225
43226
43227
43228
43229
43230
74-48-8
74-48-0
74-48-1
74-49-6
115-50-1
74-48-2
463-34-0
74-49-7
76O-O2-3
106-69-8
106-69-9
75-52-5
115-51-7
624-46-6
590-01-1
106-69-0
109-96-0
73-37-4
563-34-1
109-96-1
563-34-2
646-60-8
627-72-3
513-33-9
107-78-5
96-61-0
SPECIES
NAME
CIO PARAFFINS
C9 PARAFFIN
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
. .ACETYLENE '
PROPADIENE
METHYLACETYLENE (FROPYNE)
3-METHYL-l-PENTENE
N-BUTANE
BUTENE
ISO-BUTANE
ISOBUTYLENE
T-2-BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
ISO PENTANE
3-METHYL-i-BUTENE
1-PENTENE
2-METHYL-l-BUTENE
TRANS-2-FENTENE
CIS-2-PENTENE
2-METHYL-2-BUTENE
2-METHYLPENTANE
3-METHYL PENTANE
noL.
WEIGHT
142
123
16.
30.
28.
44.
42.
26.
40 .
4O.
84.
58.
56.
58.
56.
56.
56.
54.
72.
72 .
70.
70.
70.
70.
70.
70.
36.
86.
.28
.25
04
07
05
09
08
04
06
06
16
12
10
12
10
11
11
09
15
15
13
13
13
13
13
13
17
17
PERCENT
WEIGHT
0.
0.
'n
jl.
0.
4.
0.
1.
2 .
~ 0 .
0.
0.
22
1.
T
0.
0.
0.
0 .
4.
11
0.
0.
0.
0.
0.
0 ..
2 .
1.
00
00
45
69
35
00
57
66
11
24
00
.42
11
43
00
89
67
00
36-
.04
14
41
00
82
97
11
31
54
(19)
(18)
(1 )
(5 )
' (3 )
(2 )
(2 )
(3 )
(4 )
(4 )
(6 )
338
-------
continued ( prof ile=1136 '.
SAROAD
NUMBER
43231
43232
43233
43234
43235
43238
43241
43242
43243
43245
43247
43248
43250
43252
43261
43262
43263
43270
43272
43273
43274
43276
43277
43278
43279
43280
43283
43284
43290
43291
43292
43295
43296
43297
43298
45201
45202
45203
45204
45205
45206
45207
45208
45209
45216
CAS
NUMBER
110-05-3
142-28-5
111-16-9
563-37-0
111-18-2
124-41-5
1120-02-4
287-79-3
78-87-5
592-24-6
108-8O-7
110-08-7
540-08-1
565-57-3
108-88-2
96-63-7
591-17-4
922-26-2
693-38-0
110-08-8
565-55-3
79-92-8
592-21-2
760-02-4
625-52-4
75-58-2
142-22-0
589-93-4
592-22-8
589-95-7
71-14-2
108-88-3
100-04-4
95-54-6
108-83-3
106-64-3
108-86-8
95-56-6
103-36-1
135-59-8
SPECIES
NAME
HEXANE
HEPTANE
OCTANE
2,3 DIMETHYL-1-BUTENE
NONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2 , 4-D I METHYLPENTANE
CYCLOHEXANE
2,2, 4-TR I METHYLPENTANE
2 , 3 , 4-TR I METHYLPENTANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-METHYL HEXANE
3-METHYL-T-2-PENTENE
METHYLCYCLOPENTENE '
. CYCLOHEXENE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
2,4-DIMETHYLHEXANE
2 , 5-DIMETHYLHEXANE
2-ETHYL-l-BUTENE
2,3,3 TR I METHYLPENTANE
C-3-HEXENE
2-METHYL-2-PENTENE
2,3 DIMETHYLHEXANE
2,2-DIMETHYLBUTANE
CYCLOPENTENE
3-METHYLHEXANE
2-METHYLHEPTANE
4-METHYLHEPTANE
3-METHYLHEPTANE.
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
1,3, 5-TRIMETHYLBENZENE
1,2,4-TRIMETHYLBENZENE
N-PROPYLBENZENE
S-BUTYLBENZENE
MOL.
WEIGHT
86.17
100.20
114.23
84.16
128.25
142.28
156.31
70.14
68.12
8.4.16
100*. 20
84.16
114.22
114 .22
98.21
84.16
10O.20
84.16 '
.. 82.14
82.14
100.20
86.17
114.22
114.22
84.16
114.22
84.16
84.16
114.22
86.17
68.11
100 . 20
114.23
114.23
114.23
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
134.21
PERCENT
WEIGHT
1 . 53
0 . 73
0 . 24
0 . 00
0.11
0 . 1 1
0.14
0 . 48
0 . 1 0
0 . 28
0 . 64 .
0 . 00
1 . 50
0 . 26
0 . 26
1.11
0 . OO
0.00
0 .03
. 1 . 58
0 . 00
0 . 98
0 . 42
0 . 00
0 . 00
0 . 42
0 . 00
0 . 34
0 . 00
0.22
0 . 29
0 . 00
0 . 26
0.25
0.35
1.75
2.98
0 . 67
0.91
1.86
0 . 00
1.21
1.44
0.31
0.05
(8 )
(6 )
( 5 )
(7 )
(10)
(9 )
(11)
(9 )
(11)
(11)
(13)
(13)
(7 )
(8 )
(14)
(12)
(10)
(14)
( 16)
(18)
(17)
(17)
339
-------
continued (profile=1186)
SAROAD
NUMBER
45217
45218
45225
45235
45241
45242
90002
90003
90004
90(505
90006
90008
90015
90016
90017
90032
90033
90034
90036
90037
90038
98033
98035
98044
98054
99908
99909
99912
99913
99916
99918
99999
CAS
NUMBER-
IS 5- 50-3
141-19-5
526-67-8
104-45-8
821-19-4
6434-47-2
624-42-3
592-24-8
496-61-7
107-73-1
SPECIES
NAME
1,2 DIETHYLBENZENE
M-DIETHYLBENZENE
1,2,3-TRIMETHYLBENZENE
BUTYL BENZENE
4-PHENYL-l-BUTENE
T-1-PHENYLBUTENE
2, 3 ,5-TR I METHYLHEX ANE
2,4 DIMETHYLHEPTANE
3,5 DIMETHYLHEPTANE
2 , 5 DIMETHYLHEPTANE
2,3 DIMETHYLHEPTANE
2-METHYLOCTANE
3-METHYLOCTANE
4-METHYLOCTANE
METHYLCYCLOOCTANE
1-UNDECENE
CYCLOPENTYLCYCLOPENTANE
T-2-NONENE
PENTYNE
HEXYNE
CIS-1,4 DIMETHYLCYCLOHEXANE
2 , 2 ., 5-TR I METHYLHEX ANE
C-2-HEXENE
INDANE
2,4, 4-TR I METHYL- 1-PENTENE
2,3 DIMETHYLOCTANE
2,6 DIMETHYLOCTANE
l-METHYL-3-ETHYLBENZENE
l-METHYL-2-ETHYLBENZENE
1-METHYL-3N-PRQPYLBENZENE
2-METHYLDECANE
UNIDENTIFIED
SUM
MOL.
WEIGHT
134.22
134.22
120.19
134.21
131.20
131.20
128.25
128.26
128.26
123.26
128.26
128.26"
128.26
128.26
127.25
1 54 . 30
138.25
. 126.24
68.12 .
82.15
112.22
. 128.26
84.16
118.18
112.22
167.31
167.31
119.19
119.19
134.22
1 56 . 32
36 . 00
TOTAL
PERCENT
WEIGHT
0 . 30
0.23
0 . 26
0.21
0 . 26
0 . 23
0 . 08
0 . 08
0.00
0.13
0 . 00
0 . 04
0.31
0 . 39
0 . 33
0.14
0.46
0.17
0.19 - >
0 . 02 "
0 . 08
0.24 .
0.11
0 . 32
1.73
0 . 52
0 . 07
0.16
0 . 00
0.16
0 .63
5 . 07
100.00
(15)
(15)
(16)
(12)
(19)
"The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
340
DATE :08-10-1988
-------
PROFILE NAME:Light-Duty Diesel Vehicles
PROFILE NUMBER:1201
PROFILE DATA QUALITY:C
CONTROL DEVICE:Uncontrolled
REFERENCE(S): 83, 84, 94
DATA SOURCE:Species data by carbon number from three cars combined
with aldehydes data from two cars. Cl to C43 organics
analyzed using a combination of FID and solvent extract
ion. Aldehydes measured by 2, 4-DNP method. Mol. Wts.
of Ci to C7 based on species distribution data (1 car);
C8 to C43 based on hydrogen to carbon ratio of 2.
SCC : 111
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43502 50-00-0
43503 75-50-0
43504 123-33-6
43505 1.07-70-8
43512 66-62-1
43515 123-37-9
45501 100-05-7
99101
99102
99103
99104
99105
99106
99107
99108
99109
99110
99111
99112
99113
99114
99115
99116
99117
99118
99119
99120
99121
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACROLEIN
HEXANAL
CROTONALDEHYDE
BENZALDEHYDE
C-l COMPOUNDS
C-2 COMPOUNDS
C-3 COMPOUNDS
C-4 COMPOUNDS
C-5 COMPOUNDS
C-6 COMPOUNDS
C-7 COMPOUNDS
C-8 COMPOUNDS
C-9 COMPOUNDS
C-1Q COMPOUNDS
C-li COMPOUNDS
C--12 COMPOUNDS
C-13 COMPOUNDS
C-14 COMPOUNDS
C-l5 COMPOUNDS
C-16 COMPOUNDS
C-17 COMPOUNDS
C-18 COMPOUNDS
C-19 COMPOUNDS
C-20 COMPOUNDS
C-21 COMPOUNDS
30 . 03
44.05
58 . 08
56 . 07
100.16
70.. 09
106.13
16.04
28.55
42.. 08
57 . 08
71 .00
79.12
93.18
112.00
126.00
140.00
154.00
168 . 00
132.00
196.00
210.00
224 . 00
238 . 00
252.00
266 . 00
280 . 00
294 . 00
8.61
2.91
1.77 (1
0 . 00 ( 1
0 . 08
1.01
0.55
5.80
19.94
5.21
4 . 08
2.36
4 . 30
2.89
1.13
0.75
3 . 52
3.58
2 . 20
3 . 43
4.45
4.35
3.49
3/06
2 . 04
1.56
0.91
0.75
341
-------
continued (profile=1201)
SAROAD CAS
NUMBER NUMBER
99122
99123
99124
99125
99126
99127
99128
99129
99130
99131
99132
99133
99134
99135
99136
99137
99138
99139
99140
99141.'
99142.
99143
C-22
C-TT
-^ '-'
C--24
C-25
C-26
C-27
C-28
C-29
C-30
C-31
p T '?
*_ _' X.
C-T-T
JปO
C-34
C-35
C-36
C-37
C-38
C-39
.C-40
. C-41
C-42
C--43
SPECIES
NAME
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS
COMPOUNDS .
COMPOUNDS
COMPOUNDS
COMPOUNDS
MOL.
WEIGHT
308
322
336
350
364
378
392
406
420
434
448
462
476
490
504
518
532
546
560
574
588
6O2
. 00
.00
. 00
. 00
. 00
. 00
. 00
. 00
. 00
. 00
. oo
. 00
. 00
. 00
. 00
. 00
. 00
, 00
. 00
. 00
.00
. 00
PERCENT
WEIGHT
0 . 59
0.43
0 . 48
0 . 54
0 . 44
0.22
0 . 32
0.14
0.32
0 . 29
0 . 27
0 . 22
0.24
0.16
0 . 20
0 . 08
0.05
0 . 11
0 . 02
. 0.05
0 . 02
0.01
SUM TOTAL
100.00
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
342
DATE :08-12-1988
-------
PROFILE NAME:Light-Duty Gasoline Vehicles - Exhaust
tf'RUFILE NUMBER: 1203
PROFILE DATA QUALITY:B
CONTROL DEVICE:Catalyst
REFERENCE < S):56, 06
DATA SOURCE:Composition data collected using GC/FID and DNPH
methods 'for exhaust emissions (see Appendix A -far
details: see also Pro-file 1101).
SCC : 28
29
30
SAROAD CAS
NUMBER NUMBER
433.35
4
4
4
4
4
4
4
3 1 36
3203.
3202
3203
3204
3205
3206
id. 3 2 08
|-3209
4323.1
4
4
4
4
4
4
4
4
4
3212
3 ^:! 1 3
3214
3215
3216
3217
3218
3220
T '"*'"> -I
Oil.^l
43223
4
4
4
4
3224
3226
? '-i -ป -r
O .ฃ.<ฃ. /
3228
43229
4
3230
43231
74-48-8
74-48-0
74-48-
74-49-
115-50
74-48-
463-34
74 49-
760-0.2
1
6
-
2
7
3.
0
"'.*'
106- -69-- 8
106-69
75-52-
i -i rป; _ r.: i
I JL ป...' w. I
6^/1 1 J.
.ฃ._ 1 "T C3
590-0 1
106-69
109-96
78-87-
563-34
5
-
...
_.
9 '
""t
6
1
0.
-O
4
-
1
109-96-1
646-60-8
/ '-v-r -y 'T
GtL/ ~ t .C.
513--33
107-77
96-61-
110-O5
-3
....
....
0
._
9
5
3
SPEiCIES
NAME
CIO PARAFFINS
C9 PARAFFIN
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
PROPADIENE
METHYL ACETYLENE ( PROP YNE )
3-METHYL- 1 -PENTENE
N- BUTANE
BLITENE
ISO-BUTANE
ISOBUTYLENE
T-2-BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N- PENTANE .
ISO PENTANE
3-METHYL- 1 -BUTENE
1 -PENTENE
TRANS-2-PENTENE
CI.S-2-PENTENE
2-METHYL-2-BLITENE
2--METHYL PENTANE
3-METHYL PENTANE
HEXANE
MOL.
WEIGHT
14
12
16
30
28
44
42
26
40
40
84
58
56
58
56
56
56
54
72
72
70
70
70
7O
70
86
86
86
t... ,.^ -^
^. ป ^LO
8.25
. 04
. 07
.05
.09
.08
.04
.06
. 06
. 16
. 12
. 10
. 12
. 10
. 11
. 11
. 09
. 15
. 15
. 13
. 13
. 13
. 13
. 13
17
. 17
. 17
PERCENT *
WE I GUT
0.
0.
3. 0
1.,
8.
1
00
.
" )
/
4
97
'">
.1.
2.88
O,
j'.'. ii
o.
o.
0 .
3 .
O.
0.
3 .
0.
0.
0.
1.
3 .
0 .
0.
0.
0.
0 .
1.
0.
0.
00
2
3.
1.
0
8
5
;j
1 1
1
OO
6
4
.i^.
1
00
4
6
O
'"7
/
60
5
1
1
3
2
5
_,;;'
8
6
:!.
8
9
4
G
1
-
/
6
7
(20)
1)
1)
7)
3)
2)
4)
5)
3)
6)
8)
10)
343
-------
c Q n t i n u e d (p r o -f i 1 e = 12 0 3)
SARQAD
NUMBER
43232
43233
43234
43235
43238
43241
43242
43243
43245
43247
43248
43250
43252
43261
43262
43263
43270
43272
43273
43274
43276
43277
43278
43279
4328O
43281
43282
43283
4.;!.284
43285
43286
43287
43290
43291
43292
43295
43296
43297
43298
43299
43502
43503
43504
43505
CAS
NUMBER
142-28-5
111-16-9
563-37-0
111-18-2
124-41-5
1120-02-4
287-79-3
78-87-5
592-24-6
108-80-7
110-08-7
540-08-1
565-57-3
108-88 2
96-63-7
591-17-4
922-26-2
693-38-0
110-08-8
565-55-3
79-92-8
592- -2 1-2
760-02-4
107-70-6
503-31-3
625 52-4
590-07-8
75-58-2
142-22-0
589-93-4
592-22-8
589-95-7
50-00-0
75-50-0
123-33-6
107-70-8
SPECIES
NAME
HEPTANE
OCTANE
2,3 DIMETHYL-1-BUTENE
NONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
ISOPRENE
1-HEXEME
2,4-D1METHYLPENTANE
CYCLOHEXANE
2,2,4-TRIMETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
METHYLCYCLOHEXAME
METHYLCYCLOPENTANE
2-METHYL HEXAME
3-METHYL-T-2-PENTENE
METHYLCYCLOPENTENE
CYCI...OHEXENE
2,3 DIMETHYL PEMTANE
2,3 DIMETHYLBUTANE
2f4-DIMETHYLHEXANE
2, 5-DIMETHYLHEXANE
2-ETHYL-l-BUTENE
2,3,3 TRIME THYLPENTANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
2,2 DIMETHYLHEXANE
2,3 DIMETHYLHEX ANE
2,2-DIMETHYLBUTANE
CYCLOPENTENE
3-METHYU-IEXANE
2-METHYLHEPTANE
4-METHYLHEPTANE
3-METHYLHEFTANE
1-METHYLCYCLOHEX ENE'
PORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACROLEIN
MOL.
WEIGHT
100.20
114.23
84. 16
1 28 . 25
142.28
156.31
70. 14
68. 12
84. 16
100.20
84. 16
114.22
114. 22
98.21
84. 16
1 00 . 20
84 . 1 6
82. 14
82. 14
100.20
86. 17
114.22
114.22
84. 16
114.22
54 . 09
54.09
84. 16
84. 16
84. 16
112.20
114.22
114.22
86. 17
68. 11
100.20
114.23
114. 23
114.23
96n 17
30 . 03
44 . 05
58.08
56.07
PERCENT
WE I CiHT
0 . 53
0 . 30
0. OO
0. 25
0.20
0 . 60
0 . 00
0. 17
0.22
0. 53
3 . 2 <\
1 . 95
0 . 1 1
0. 47
0.63
0. 00
O. 00
0 . O 2
0. OO
1.25
o . 5 ;.
0 . 00
0. 63
0. 00
i . 1 O
O. 00
0. Oo
0 . OO
O. 2.:.'
o.o a
0 . 1 3
0 . 0 7
0. OO
0 . 7 :'.
0 . 27
0.92
0. 22
0.5 2
0 . 36
0 n OO
1 . 42
O.49
0. 05
0 . 1 5
( 8)
( 7)
< 9)
(12)
(11)
(13)
(11)
( 1 3 )
(13)
( !
(14;
( 9)
( 5)
( 6)
(10)
( 1 5 )
( 4)
(16)
U6)
344
-------
c o n t .i n u e d (p r ofile=12 0 3)
SARQAI
NUMBEF
43515
431.10
45201
45202
45203
45204
45205
45206
45207
45208
45209
45216
45217
452:1.8
45225
45501
70002
90003
90 004
90005
|>O006
PPOOO?
90008
90009
90042
98033
980'M
99910
99911
99912
99913
99915
99916
99917
99918
99999
) CAS
'; NUMBER
123-37-9
"7 -t -| t\ '"t
/ A .1. A
-------
PROFILE NAME:Light-Duty Gasoline Vehicles - Evaporative
PROFILE NUMBER:1204
PROFILE DATA QUALITY:B
CONTROL DEVICE:
REFERENCE(S):56, 86
DATA SOURCE:Composition data collected using GC/FID for evaporative
emissions (see Appendix A for details; see also Pro File
1101).
30
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
431.33
43136
43201 74-4B-8
43202. 74-48-0
43203 74-4B-l
43204 74-49-6
43205 115-50-1
43206 74-43-2
43208 463-34-0
43209 74-49-7
43211 760-02-3
43212 106-69-8
43213 106-69-9
43214 75-52-5
43213 115-51-7
43216 624-46-6
43217 590-01-1
432.10 106-69-0
43220 109-96-0
43221 73-87-4.
43223 563-34-1
43224 109-96-1
43226 646-60-8
43227 627-72-3
43228 513-33-9
43229 107-77-5
43230 96-61-0
4323.1. 11O-O5-3
CIO PARAFFINS
C9 PARAFFIN
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
PROPADIENE
METHYLACETYLENE (PROPYNE)
3-METHYL-1-PENTENE
N-BUTANE
BUTENE
ISO-BUTANE
ISOBUTYLENE
T-
-BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
ISO PENTANE
3-METHYL-1-BUTENE
1-PENTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-METHYL-2-BUTENE
2-METHYL PENTANE
3-METHYL PENTANE
HEXAME
142.28
128.25
16.04
30.07
28.05
44.09
42. OB
26.04
40.06
40.06
84. 16
58. 12
56. 10
58. 12
56. 10
56. 11
56. 11
54.09
72. 15
72. 15
70. 13
70. 13
70. 13
70. 13
70. 13
86. 17
86. 17
86. 17
0. 0'?
0.. 00
0. 04
0.03
O. O3
I. 54
O. 00
.0. 01
0. 02
0. 00
0. 00
28. 3 V
O. Of)
6.56
0.06
0. 00
0. & 1
0.00
4.67
13.60
0. 1B
0.62
1 .. 1 .1
1.13
0.7 4
1)
1 )
77
3)
2)
2)
4)
5)
3)
( 6)
346
-------
cont i nued (prof i1e1204)
SAROAD
NUMBER
43232
43233
43234 .
43235
43238
43241
43242
43243
43245
43247
43248
43250
43252
43261
43262
43263
43270
43272
43273
43274
|3276
13277
43278
43279
43280
43281
43282
43283
43284
43285
43286
43287
43290
43291
43292
43295
43296
43297
43298
43299
43502
43503
43504
43505
CAS
NUMBER
142-28-5
111-16-9
563-37-0
111-18-2
124-41-5
1120-02-4
287-79-3
78-87-5
592-24-6
108-80-7
110-08-7
540-08-:!.
cr A KT _i=r7 :;
W-'Ot.1 V..1 / -ป'
108 88-2
96-63-7
591-17-4
922-26-2
693-38-0
11 0-08-8
565-55-3
79-92-8
592-21-2
760-02-4
107-70-6
503- 3 3. -3
625-52-4
590-07-8
75-58-2
1 42-22-0
589-93-4
592-22-8
589-95-7
50-00-0
75-50-0
123-33-6
107-70-8
SPECIES
NAME
HEPTANE
OCTANE
2,3 D I METHYL- 1-BUTENE
NONANE
N-DECANE
N-UNDECANE
CYCLDPENTANE
ISOPRENE
1-HEXENE
2 , 4-D I METHYLPENT ANE
CYCLOHEXANE
2, 2, 4-TR I METHYLPENT ANE
2 , 3 , 4-TR 1 METHYLPENT ANE
METH Y LCYCLOHE X ANE.
METHYLCYCLOPENTANE
2-METHYL HEXANE
3-METHYL-T-2-PENTENE
METHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENT ANE
2,3 D I METHYLBUTANE
2 , 4-D I METH YLHE X ANE
2, 5-DIMETHYLHEXANE
2-ETH YL- 1 -BUTENE
2 , 3 , 3 TR I METHYLPENT ANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
2,2 DIMETHYLHEXANE
2,3 DIMETHYLHEXANE
2 , 2-D I METHYLBUTANE
CYCLOPENTENE
3-METH YLHE X ANE
2-METHYLHEPTANE
4-METHYLHEPTANE
3-METHYLHEPTANE
1 -METHYLCYCLOHEXENE
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACRQLEIN
MOL.
WEIGHT
1 00 . 20
114.23
84 . 1 6
128.25
142.28
156.31
70. 14
68 . 1 2
84 . 1 6
100.20
84. 16
114. 22
114. 2.2
98.21
84.16
100.20
84. 16
82. 14
82. 14
100.20
86. 17
114.22
114. 22
84. 16
114.22
54.09
54 . 09
84.16
84. 16
84. 16
112. 20
114.22
114.22
86. 17
68. 11
10O.20
1 1 4 . 23
114. 23
114.23
96. 17
30 . 03
44.05
58.08
56 . 07
PERCENT
WEIGHT
0.52
0.24
0. 00
0 . 1 2
0.20
0 . 09
0. 00
0 . 00
0 . 3'?
0.5'?
1 . 33
0.59
0.5f:;
0.33
0.84
0 . 00
0. 00
O. O7
0. OO
1 . 03
1 . 04
0. 00
O.48
0 . OO
0 . 4 .1
0.00
0. 00
0. OO
0. 64
0 .. 03
O. 05
Or, 05
O. 0'-''
1 . 68
0. 20
0.77
0. 22
0. 10
0.35
0 ., 00
0 . 00
OnOO
0 . 00
0. 00
( 8)
( 7)
( 9)
(12)
(11)
(13)
(11)
(13)
(13)
(14)
( 1 4 )
( 9)
( 5)
( 6)
(10)
(15)
( 4)
(16)
(16)
347
-------
con t i nu'ed
-------
3.27 AIRCRAFT
Aircraft engines are primarily reciprocating piston and gas turbine.
Aircraft emissions of concern typically occur during landing/takeoff (LTO)
cycles. Each class of aircraft has its own typical LTO cycle which includes
all of the normal flight and ground operation modes. These operations are
divided into five modes: approach, taxi/idle in, taxi/idle out, takeoff,
and climbout.
349
-------
PROFILE NAME:Aircraft Landing/Takeoff (LTD) - Military
PROFILE NUMBER:1097
PROFILE DATA QUALITY:B
CONTROL DEVICE Uncontrolled
REFERENCE(S):53
DATA SOURCE:Composite profile developed from data for a CFM-36 jet
engine fired with JP-5 fuel at idle, 307. thrust and 807.
thrust. Data collected by 6C/MS and DNPH analyses were
combined according to average LTD cycle times obtained
from AP-42 (4th. Edition) for military aircraft.
SCC
46
SAROAD
NUMBER
43111
43113
43114
43121
43137
43140
43201
43202
43203
43204
43205
43206
43213
43217
43218
43220
43224
43228
43229
43232
43233
43235
43238
43241
43245
43255
43258
43259
CAS
NUMBER
74-48-8
74-48-0
74-48-1
74-49-6
79-92-9
540-04-8
106-69-9
590-01-1
106-69-0
109-96-0
109-96-1
513-33-9
107-78-5
142-28-5
111-16-9
111-18-2
124-41-5
1120-02-4
110-05-3
112-24-3
629-95-5
629-95-4
SPECIES
NAME
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
ISOMERS OF PENTADECANE
ISOMERS OF PENTENE
C16 BRANCHED ALKANE
C7-C16
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
1-PENTENE
2-METHYL-2-BUTENE
2-METHYLPENTANE
HEPTANE
OCTANE
NONANE
N-DECANE
N-UNDECANE
1-HEXENE
N-DODECANE
N-TRIDECANE
N-TETRADECANE
MOL.
WEIGHT
170.32
198.38
212.41
70.13
226.45
163.32
16.04
30 . 07
28.05
44 . 09
42 . 08
26 . 04
56.10
56.11
54 . 09
72.15
70.13
70 . 13
86.17
1O0.20
114.23
128.25
142.28
156.31
84.16
170.33
184.36
198.38
PERCENT
WEIGHT
0.19
0 . 20
0.18
0 . 76
0.16
0 . 32
9.37
0.91
18.36
0 . 19
5.44
4.4.1
' 2 . 06
0 . 50
1.89
0.22
0 . 89
0.21
0.41
0 . 07
0.05
0.13
0 . 44
0 . 54
0 . 86
1.07
0 . 67
0.59
350
-------
continued (profile=1097)
SAROAD
NUMBER
43260
43264
43265
43269
43502
43503
43504
43505
43510
43512
43513
43514
43515
43551
45201
45202
45203
45204
45220
45231
45235
45300
45501
46701
46702
90010
90014
90019
90020
90030
90031
CAS
NUMBER
629-96-9
111-16-0
124-41-8
50-00-0
75-50-0
123-33-6
107-70-8
123-37-8
66-62-1
107-72-2
78-89-8
123-37-9
67-76-1
71-14-2
108-88-3
100-04-4
95-54-6
100-04-5
104-45-8
108-89-2
100-05-7
91-12-3
108-83-3
8720-05-9
544-47-3
629-97-7
SPECIES
NAME
N-PENTADECANE
HEPTENE
OCTENE
1-NONENE
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACROLEIN
BUTYRALDEHYDE
HEXANAL
GLYOXAL
METHYL GLYOXAL
CROTONALDEHYDE
ACETONE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
STYRENE
PENTYL BENZENE
BUTYL BENZENE
PHENOL
BENZALDEHYDE
NAPTHALENE
METHYL NAPHTHALENES
M-XYLENE AND P-XYLENE
1-DECENE
C6H1803SI3
C8H2404SI4
HEXADECANE
N-HEPTADECANE
MOL.
WEIGHT
212.41
98.18
112.21
127.05
30 . 03
44.05
58 . 08
56.07
72.12
100.16
58 . 04
72 . 07
70 . 09
58.08
78.11
92.13
106.16
106.16
104.14
148.25
134.21
94.11
106.13
123.11
142.20
106.16
140.22
222 . 47
296 . 60
226.45
240 . 46 ,
SUM TOTAL
PERCENT *
WEIGHT
0 . 26
0 . 54
0 . 30
0.26
15.47
4.83
0 . 98
2.38
1.24
0 . 22
2.18
2 . 06
0 . 00
2.41
2 . 02
0 . 55
0.18
0 . 20
0.41
0.21
0.26
0.26.
0.57
0.60
0 . 52
0 . 30
0.17
6.96
2.37
0.12
0.01
100.00
( 1)
( 1)
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
351
DATE :04-21-1988
-------
PROFILE NAME:Aircraft Landing/Takeoff (LTD) - Commercial
PROFILE NUMBER:1098
PROFILE DATA QUALITYsB
CONTROL DEVICE:Uncontrolled
REFERENCE(S):53
DATA SOURCE:Composite profile developed from data for a CFM-36 jet
engine fired with JP-5 fuel at idle, 307. thrust and 807.
thrust. Data collected by BC/MS and DNPH analyses were
combined according to average LTD cycle times obtained
from AP-42 (4th. Edition) for commercial aircraft.
SCC
48
SAROAD
NUMBER
43111
43113
43114
43121
43137
43140
43201
43202
43203
43204
43205
43206
43213
43217
43218
43220
43224
43228
43229
43232
43233
43235
43238
43241
43245
43255
43258
43259
CAS
NUMBER
74-48-8
74-48-0
74-48-1
74-49-6
79-92-9
540-04-8
106-69-9
590-01-1
106-69-0
109-96-0
109-96-1
513-33-9
107-78-5
142-28-5
111-16-9
111-18-2
124-41-5
1120-02-4
110-05-3
112-24-3
629-95-5
629-95-4
SPECIES
NAME
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
ISOMERS OF PENTADECANE
ISOMERS OF PENTENE
C16 BRANCHED ALKANE
C7-C16
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
1-PENTENE
2-METHYL-2-BUTENE
2-METHYLPENTANE
HEPTANE
OCTANE
NONANE
N-DECANE
N-UNDECANE
1-HEXENE
N-DODECANE
N-TRIDECANE
N-TETRADECANE
MOL.
WEIGHT
170.32
198.38
212.41
70.13
226.45
163.32
16.04
30 . 07
28.05
44 . 09
42 . 08
26.04
56.10
56.11
54 . 09
72.15
70.13
70.13
- 86.17
100.20
114.23
128.25
142.28
156.31
84.16
170.33
184.36
198.38
PERCENT
WE I BHT
0.18
0.19
0.17
0 . 73
0.14
0 . 30
9.56
0 . S3
17.42
0.18
5.15
4.17
1.97
0 . 48
1 . 80
0.21
0 . 84
0 . 20
0 . 39
0 . 06
0.05
0.13
0 . 42
0 . 53
0 . 82
1.07
0 . 66
0.58
352
-------
continued (profile=1098)
SAROAD
NUMBER
43260
43264
43265
43269
43502
43503
43504
43505
43510
43512
43513
43514
43515
43551
45201
45202
45203
45204
45220
45231
45235
45300
45501
46701
46702
90010
90014
90019
90020
90030
90031
CAS
NUMBER
629-96-9
111-16-0
124-41-8
50-00-0
75-50-0
123-33-6
107-70-8
123-37-8
66-62-1
107-72-2
78-89-8
123-37-9
67-76-1
71-14-2
108-88-3
100-04-4
95-54-6
100-04-5
104-45-8
108-89-2
100-05-7
91-12-3
108-83-3
8720-05-9
544-47-3
629-97-7
SPECIES
NAME
N-PENTADECANE
HEPTENE
OCTENE
1-NONENE
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACROLEIN
BUTYRALDEHYDE
HEXANAL
GLYOXAL
METHYL GLYOXAL
CROTONALDEHYDE
ACETONE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
STYRENE
PENTYL BENZENE
BUTYL BENZENE
PHENOL
BENZALDEHYDE
NAPTHALENE
METHYL NAPHTHALENES
M-XYLENE AND P-XYLENE
1-DECENE
C6H1803SI3
C8H2404SI4
HEXADECANE
N-HEPTADECANE
MOL.
WEIGHT
212.41
98.18
112.21
127.05
30 . 03
44.05
58 . 08
56 . 07
72.12
100.16
58 . 04
72.07
70 . 09
58 . 08
78.11
92.13
106.16
106.16
104.14
148.25
134.21
94.11
106.13
123.11
142.20
106.16
140.22
222.47
296 . 60
226.45
240.46
SUM TOTAL
PERCENT *
WEIGHT
0 . 26
0 . 54
0.28
0 . 24
1 5 . 00
4.65
0.95
2.27
1 . 20
0.21
2.54
1.97
0 . 00
2.45
1.94
0 . 52
0.17
0.19
0 . 39
0.19
0.24
0.24
0.55
0 . 57
0 . 49
0 . 29
0.17
9.10
2.92
0.12
0.01
100.00
( 1)
( 1)
""The numbers In the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
353
DATE :04-21-1988
-------
PROFILE NAME:Aircraft Landing/Takeoff (LTD) - General Aviation
PROFILE NUMBER:1099
PROFILE DATA QUALITYsC
CONTROL DEVICE:Uncontrolled
REFERENCE(S):53
DATA SOURCE:Composite profile developed from data for a CFM-36
jet engine fired JP-5 fuel at idle, 307. thrust, and 807.
thrust. Data collected by SC/MS and DNPH analyses were
combined according to average LTO cycle times obtained
from AP-42 (4th. Edition) for general aviation.
SCC
47
SARQAD
NUMBER
43111
43113
43114
43121
43137
43140
43201
43202
43203
43204
43205
43206
43213
43217
43218
43220
43224
43228
43229
43232
43233
43235
43238
43241
43245
43255
43258
43259
CAS
NUMBER
74-48-8
74-48-0
74-48-1
74-49-6
79-92-9
540-04-8
106-69-9
590-01-1
106-69-0
109-96-0
109-96-1
513-33-9
107-78-5
142-28-5
111-16-9
111-18-2
124-41-5
1120-02-4
110-05-3
112-24-3
629-95-5
629-95-4
SPECIES
NAME
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
ISOMERS OF FENTADECANE
ISOMERS OF PENTENE
C16 BRANCHED ALKANE
C7-C16
. METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
1-PENTENE
2-METHYL-2-BUTENE
2-METHYLPENTANE
HEPTANE
OCTANE
NONANE
N-DECANE
N-UNDECANE
1-HEXENE
N-DODECANE
N-TRIDECANE
N-TETRADECANE
MOL.
WEIGHT
170.32
198.38
212.41
70.13
226.45
163.32
16.04
30 . 07
28.05
44 . 09
42 . 08
26.04
56.10
56.11
54 . 09
72.15
70.13
70.13
86.17
100.20
114.23
128.25
142.28
156.31
" 84.16
170.33
184.36
198.38
PERCENT
WEIGHT
0.16
0.17
0 . 1 5
0 . 64
0.13
0 . 27
10.95
0.92
15.48
0 . 20
4.59
3.69
1.79
0.45
1.57
0.19
0.75
0 . 18
0.35
0 . 06
0 . 04
0.15
0 . 42
0.52
0 . 76
1.21
0 . 66
0 . 59
354
-------
continued (profile=1099)
SAROAD
NUMBER
43260
43264
43265
43269
43502
43503
43504
43505
43510
43512
43513
43514
43515
43551
45201
45202
45203
45204
45220
45231
45235
45300
45501
46701
46702
90010
90014
90019
90020
90030
90031
CAS
NUMBER
629-96-9
111-16-0
124-41-8
50-00-0
75-50-0
123-33-6
107-70-8
123-37-8
66-62-1
107-72-2
78-89-8
123-37-9
67-76-1
71-14-2
108-88-3
100-04-4
95-54-6
100-04-5
104-45-8
108-89-2
100-05-7
91-12-3
108-83-3
8720-05-9
544-47-3
629-97-7
SPECIES
NAME
N-PENTADECANE
HEPTENE
OCTENE
1-NONENE
FORMALDEHYDE
ACETALDEHYDE
PROP I ON ALDEHYDE
ACROLEIN
BUTYRALDEHYDE
HEXANAL
GLYOXAL
METHYL GLYOXAL
CROTONALDEHYDE
ACETONE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
STYRENE
PENTYL BENZENE
BUTYL BENZENE
PHENOL
BENZALDEHYDE
NAPTHALENE
METHYL NAPHTHALENES
M-XYLENE AND P-XYLENE
1-DECENE
C6H1803SI3
C8H2404SI4
.HEXADECANE
N-HEP-TADECANE
MOL.
WEIGHT
212.41
98.18
112.21
127.05
30.03
44.05
58.08
56 . 07
72.12
100.16
58 . 04
72.07
70 . 09
58 . 08
78.11
92 . 13
106.16
106.16
104.14
148.25
134.21
94.11
106.13
123.11
142.20
106.16
140.22
222.47
296 . 60
226.45
240.46
SUM TOTAL
PERCENT *
WEIGHT
0.27
0.52
0.25
0.22
14.14
4.32
0 . 90
2 . 06
1.19
0 . 20
2.53
1.81
0 . 00
2.93
1.79
0 . 49
0.15
0.18
0.37
0.17
0 . 22
0.22
0 . 53
0.51
0.44
0.26
0.15
11.77
4.20
0.14
0.01
100.00
( 1)
( 1)
The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
355
DATE -.04-21-1988
-------
3.28 FOREST FIRES
A forest "wildfire" is a large-scale natural combustion process that
consumes various types of botanical specimens growing outdoors in a defined
geographical area. The size and intensity of a wildfire is dependent on
such variables as the local meteorological conditions, tree types and their
moisture content, and the weight of consumable fuel per acre (fuel
loadings). Forest fire emissions are a complex mixture of solids, liquids,
and gases. Carbon dioxide and water vapor constitute over 90 percent of the
total mass emitted.
356
-------
PROFILE NAME:Miscellaneous Burning - Forest Fires
PROFILE NUMBER:0307
PROFILE DATA QUALITY:C
CONTROL DEVICE:Uncontrolled
REFERENCE(S):73
DATA SOURCE Engineering evaluation of literature data,
SCC
SAROAD
NUMBER
43120
43122
43201
43202
43203
43204
43205
43206
43209
43212
43213
43214
43218
43223
99999
CAS
NUMBER
74-48-8
74-48-0
74-48-1
74-49-6
79-92-9
540-04-8
74-49-7
106-69-8
106-69-9
75-52-5
106-69-0
563-34-1
SPECIES
NAME
ISOMERS OF BUTENE
ISOMERS OF PENTANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
METHYLACETYLENE (PROPYNE)
N-BUTANE
BUTENE
ISO-BUTANE
1,3-BUTADIENE
3-METHYL-l-BUTENE
UNIDENTIFIED
MOL.
WEIGHT
56.10
72.15
16.04
30 . 07
28.05
44.09
42.08
26 . 04
40 . 06
58.12
56.10
58.12
54 . 09
70.13
86 . 00
SUM TOTAL
PERCENT
WEIGHT
0.92
0.15
9.82
10.47
19.11
0.35
3.93
8 . 40
0.41
0 . 24
0.81
0.11
0.52
0.17
44.59
100.00
357
DATE :04-21-1988
-------
REFERENCES3
1. Oliver, W. R. and S. H. Peoples, Improvement of the Emission Inventory
for Reactive Organic Gases and Oxides of Nitrogen in the South Coast
Air Basin, Volumes I and II, Final Report (Prepared for California Air
Resources Board), May 1985.
2. Smith, D. W., E. I. DuPont de Nemours and Company, Wilmington, DE,
Letter dated February 3, 1978 to D. R. Goodwin, U. S. Environmental
Protection Agency.
3. Zanotti, M. P., Gulf Oil Company - U. S., Letter Dated January 26, 1978
to D. R. Goodwin, U. S. Environmental Protection Agency.
4. Dwlewski, S. W., Hydroscience, Inc., Knoxville, TN, Trip Report for
Visit to PPG Industries, Inc., Natrium Plant, New Martinsville, WV,
September 7 and 8, 1977.
5. Peterson, C. A., Hydroscience, Inc., Knoxville, TN, Trip Report for
Visit to Monsanto Chemical Intermediates Company, Sauget, IL,
October 27, 1977.
6. Wurzer, H. J., Montrose Chemical Corporation of California, Henderson,
Nevada, Letter Dated March 7, 1978, to D. R. Goodwin, U. S.
Environmental Protection Agency.
7. Beale, J., Dow Chemical, U.S.A., Midland, MI, Letter Dated
March 14, 1978 to L. B. Evans, U. S. Environmental Protection Agency.
8. Mull ins, J. A., Shell Oil Company, Houston, TX, Letter Dated
October 25, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
9. Serth, R. W. and T. W. Hughes, Source Assessment: Carbon Black
Manufacture, EPA-600/2-77-107k (NTIS No. PB 273068), U. S.
Environmental Protection Agency, Research Triangle Park, NC,
October 1977.
10. Meyer, A. J., Denka Chemical Corporation, Houston, TX, Letter Dated
March 26, 1979 to D. R. Goodwin, U. S. Environmental Protection Agency.
References 2-8, 10-14, 17-18, 21-47, and 50 are available in the Synthetic
Organic Chemical Manufacturing Industry New Source Performance Standard
project files at EPA's Office of Air Quality Planning and Standards at
Research Triangle Park, NC.
358
-------
11. Smith, H. A., E. I. DuPont de Nemours and Company, Wilmington, DE,
Letter Dated November 28, 1978 to D. R. Goodwin, U. S. Environmental
Protection Agency.
12. Bess, F. D., Union Carbide Corporation, Charleston, WV, Letter Dated
May 5, 1978 to L. B. Evans, U. S. Environmental Protection Agency.
13. Edwards, J. C., Tennessee Eastman Company, Kingsport, TN, Letter Dated
September 25, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
14. Hughes, L. P., Mobay Chemical Corporation, Pittsburgh, PA, Letter Dated
January 31, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
15. Allen, J. M., W. H. Piispanen, and M. Cooke, Battelle Columbus
Laboratories, Study of the Effectiveness of a Catalytic Combustion
Device on a Wood Burning Appliance, Prepared for Industrial
Environmental Research Laboratory, U. S. Environmental Protection
Agency, Publication No. EPA-600/7-84-046 (NTIS No. PB84-171545),
March 1984, 47 p.
16. DeRosier, R. and L. R. Waterland, Acurex Corporation, Environmental
Assessment of a Watertube Boiler Firing a Coal-Water Slurry, Volume I,
Technical Results, Prepared for U. S. Environmental Protection Agency,
Publication No. EPA-600/7-86-004a (NTIS No. PB86-159845),
February 1986.
17. Copeland, D. A., Rohm and Haas Texas Inc., Deer Park, Texas, Letter
Dated May 19, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
18. Lorine, D. J., Conoco Chemicals, Baltimore, MD, Letter Dated
February 17, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
19. New Jersey State Department of Environmental Protection, Division of
Environmental Quality, Report of Emission Tests, N.J.D.E.P.,
I.D. No. 083068, September 3, 1985.
20. McCurley, W. D. and G. D. Rawlings, Monsanto .Research Corporation,
Source Assessment: Cotton and Synthetic Woven Fabric Finishing,
Prepared for U. S. Environmental Protection Agency, Publication
No. EPA-600/2-80-042a (NTIS No. PB81-161937), January 1980, 192 p.
21. Mull ins, J. A., Shell Oil Company, Houston, TX, Letter Dated
October 25, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
22. Smith, D. W., E. I. DuPont de Nemours and Company, Wilmington, DE,
Letter Dated September 18, 1978 to D. R. Goodwin, U. S. Environmental
Protection Agency.
359
-------
23. Carpenter, K. G., U. S. Industrial Chemicals Company, Letter Dated
August 17, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
24. Bousquek, E. W., National Starch and Chemical Corporation, Letter Dated
August 22, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
25. Betts, C. N., Sonoco Products Company, Hartsville, SC, Letter Dated
October 10, 1979 to D. R. Goodwin, U. S. Environmental Protection
Agency.
26. Tretter, V. J., Jr., Georgia-Pacific Corporation, Portland, OR, Letter
Dated July 19, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
27. Smith, D. W., E. I. DuPont, Wilmington, DE, Letter Dated
January 7, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
28. DeRose, C. R., Celanese Chemical Company, Houston, TX, Letter Dated
April 21, 1978 to L. B. Evans, U. S. Environmental Protection Agency.
29. Edwards, J. C., Tennessee Eastman Company, Kingsport, TN, Letter Dated
August 31, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
30. Blackburn, J. W., Hydroscience, Inc., Knoxville, TN, Trip Report for
Visit to Rohm and Haas Company, Deer Park, TX, November 1, 1977.
31. Blackburn, J. W., Hydroscience, Inc., Knoxville, TN, Trip Report for
Visit to Union Carbide Corporation, Taft, LA, June 1, 1978.
32. New Jersey State Department of Environmental Protection, Division of
Environmental Quality, Report of Emission Test, N.J.D.E.P,
I.D. No. 030050, June 2, 1986.
33. Helsel, R. W., Hydroscience, Inc., Knoxville, TN, Trip Report for Visit
to Celanese Chemical Company, Pampa, TX, March 1, 1978.
34. Bess, F. D., Union Carbide Corporation, South Charleston, WV, Letter
Dated April 21, 1978 to L. B. Evans, U. S. Environmental Protection
Agency.
35. Lawson, J. F., Hydroscience, Inc., Knoxville, TN, Trip Report for Visit
to BASF Wyandotte Corporation, Geismar, LA, July 12, 1977.
36. DeBernardi, J. A., Conoco Chemicals, Westlake, LA, Letter Dated
May 16, 1978 to D. R. Goodwin, U. S. Environmental Protection .Agency.
37. Samel son, R. J., PPG Industries, Letter Dated June 2, 1978 to
D. R. Goodwin, U. S. Environmental Protection Agency.
360
-------
38. Stuewe, C. W., Hydroscience, Inc., Knoxville, TN, Trip Report for Visit
to Dow Chemical USA, November 16-17, 1977.
39. Mull ins, J. A., Shell Oil Company, Houston, TX, Letter Dated
June 22, 1978 to D. R. Goodwin, U. S. Environmental Protection Agency.
40. Lawson, J. F., Hydroscience, Inc., Knoxville, TN, Trip Report for Visit
to Celanese Chemical Company, Pasadena, TX, June 21 and 22, 1977.
41. Dehnke, T. H. and J. F. Lawson, Hydroscience, Inc., Knoxville, TN, Trip
Report for Visit to Celanese Chemical Company, Bishop, TX,
July 26, 1977.
42. Smith, D. W., E. I. DuPont de Nemours and Company, Wilmington, DE,
Letter Dated August 21, 1978 to D. R. Goodwin, U. S. Environmental
Protection Agency.
43. Cundiff, T. W., Pfizer, Terre Haute, IN, Letter Dated April 16, 1979 to
D. R. Goodwin, U. S. Environmental Protection Agency.
44. Walsh, J. P., Exxon Chemical Company USA, Baton Rouge, LA, Letter Dated
February 10, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
45. Smith, A. G., Shell Oil Company, Houston, TX, Letter Dated
February 22, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
46. Kuykendall, C. R., El Paso Products Company, Odessa, TX, Letter Dated
January 31, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
47. Berry, F. E., Gulf Oil Chemicals Company, St. James, LA, Letter Dated
January 27, 1978 to D. R. Goodwin, U. S. Environmental Protection
Agency.
48. New Jersey State Department of Environmental Protection, Division of
Environmental Quality, Report of Emission Test, N.J.D.E.P.,
I.D. No. 30147, May 28, 1986.
49. Scott, W. D., C. E. Bates, and R. H. James, Chemical Emissions from
Foundry Molds, Transactions of the American Foundrymen's Society,
Volume 86, 1978, pp. 203-208.
50. Taylor, L., Georgia Department of Natural Resources, Letter Dated
January 19, 1979 to M. M. Lowry, Section Chief, Air Quality Control
Section, Georgia Department of Natural Resources.
51. Entropy Environmentalists, Inc., Stationary Source Sampling Report EEI
Ref. No. 2549, Hexamethylenediamene Emissions Testing, T-37 Evaporator
Process Vent, July 3, 1984.
361
-------
52. Tucker, T. N., Area Supervisor, Southwestern Ohio Air Pollution Control
Agency, Letter Dated May 22, 1986 to E. L. Martinez, Chief, Source
Analysis Section/AMTB, U. S. Environmental Protection Agency.
53. Spicer, C. W.,'et al., Battelle Columbus Laboratories, Composition and
Photochemical Reactivity of Turbine Engine Exhaust, Report
No. ESL-TR-84-28, Prepared for Air Force Engineering and Services
Center (RDVS), Tyndall AFB, FL, September 1984.
54. Bond, A. E., et al., Self-Service Station Vehicle Refueling Exposure
Study, U. S. Environmental Protection Agency, Research Triangle Park,
NC, 1985, Presented at the 1986 EPA/APCA Symposium on Measurement of
Toxic Air Pollutants, Raleigh, NC, April 1986.
55. Earley, D. E., et al., Monsanto Research Corporation, Source
Assessment: Rail Tank Car, Tank Truck, and Drum Cleaning State of the
Art, Publication No. EPA-600/2-78-004g (NTIS No. PB 280726),
April 1978, p. 22.
56. Sigsby, J. E., Jr., et al., Volatile Organic Compound Emissions from
46 In-Use Passenger Cars, Environmental Science and Technology,
Volume 21, No. 5, 1987, pp. 466-475.
57. Renman, L., et al., Determination of Isocyanate and Aromatic Amine
Emissions from Thermally Degraded Polyurethanes in Foundries, Am. Ind.
Hyg. Assoc. J., 47(10), pp. 621-628, October 1986.
58. Compilation of Air Pollutant Emission Factors, Volume I: Stationary
Point and Area Sources, Fourth Edition, AP-42, U. S. Environmental
Protection Agency, Research Triangle Park, NC, September 1985.
59. Taback, H. J., et al., Control of Hydrocarbon Emissions from Stationary
Sources in the California South Coast Air Basin, Volume II, KVB, Inc.,
Tustin, CA, June 1978.
60. Sonnichsen, T. W., KVB Engineer.
61. Hughes, T. W., et al., Source Assessment: Prioritization of Air
Pollution from Industrial Surface Coating Operations, U. S.
Environmental Protection Agency, Publication No. EPA-650/2-75-019a
(NTIS No. PB 243423), February 1975.
62. Trijonas, J. C. and K. W. Arledge, Utility of Reactivity Criteria on
Organics Emission Control Strategies in the Metropolitan Los Angeles
AQCR, U. S. Environmental Protection Agency, Publication
No. EPA-600/3-76-091 (NTIS No. PB 257706), August 1976.
63. Pesticide Use Report, Annual 1976, Department of Food and Agriculture,
Agricultural Chemicals and Food.
362
-------
64. Danielson, J. A., Air Pollution Engineering Manual, U. S. Environmental
Protection Agency, Research Triangle Park, NC, AP-40 (NTIS
No. PB 225132), May 1973.
65. Mayrsohn, H. and J. Crabtree, Source Reconciliation of Atmospheric
Hydrocarbons in the South Coast Air Basin, 1975, California Air
Resources Board, December 1976.
66. Zimmerman, P. R., Tampa Bay Area Photochemical Oxidant Study - Final
Appendix C: Determination of Emission Rates of Hydrocarbons from
Indigenous Species of Vegetation in the Tampa/St. Petersburg Area,
Publication No. EPA-904/9-77-028 (NTIS No. PB 297057/2), 1977.
67. Bethea, Robert N., Solution for Feedlot Odor Control Problems, Journal
of APCA, Volume 22, No. 10, October 1972.
68. Horton, R. and D. Daniels, The Energy and Fertilizer Potential of
Natural Organic Wastes, June 1976.
69. Aschbacher, P. W., Air Pollution Research Needs Livestock Production
Systems, Journal of APCA, Volume 23, No. 4, April 1973.
70. Keller, R. M. and C. Cowherd, Identification and Measurement of
Atmospheric Organic Emissions from Natural and Quasi-Natural Sources,
Interim Report for EPA Contract No. 68-02-2524, July 1977.
71. Formica, P. N., Controlled and Uncontrolled Emission Rates and
Applicable Limitations for Eighty Processes, Prepared for U. S.
Environmental Protection Agency, OAQPS, Research Triangle Park, NC,
Publication No. EPA-340/1-78-004, April 1978.
72. Hydrocarbon Emissions from Fixed-Roof Petroleum Tanks, Engineering
Science, Inc., Sponsored by the Western Oil and Gas Association,
July 1977.
73. Sandberg, D. V., et al.,- Emissions from Slash Burning and the Influence
of Flame Retardant Chemicals, J. Air Poll. Cont. Assoc., Volume 25,
No. 3, March 1975.
74. Black, F. and L. High, Diesel Hydrocarbon Emission - Particulate and
Gas,Phase, Symp. of Diesel Particulate Emission Measurement and
Characterization, May 1978.
75. Springer, K. J. and T. M. Baines, Emissions from Diesel Versions of
Production Passenger Cars, Society of Automotive Engineers, Paper
No. 770818, September 26-30, 1977.
76. Butler, W. A. and M. B. Stockton, Engineering Judgement, Radian
Corporation, July 1987.
77. Residential Wood Heater Test Report, Tennessee Valley Authority
(Tables 6, 7, 13, 20, 27, and 33), Phase II Testing, Volume I, Energy
Use Test Facility, August 1983.
363
-------
78. Allen, J. M., W. H. Piispanen, and M. Cooke, Study of the Effectiveness
of a Catalytic Combustion Device on a Wood Burning Appliance, Battelle
Columbus Labs, Ohio, Publication No. EPA-600/7-84-046 (NTIS
No. PB84-171545), March 1984, Table 6, page 22.
79. DeAngelis, D. G., D. S. Ruffin, and R. B. Reznik, Preliminary
Characterization of Emissions from Wood-Fired Residential Combustion
Equipment, Interagency Energy/Environmental R&D Program Report,
Publication No. EPA-600/7-80-040 (NTIS No. PB80-182066), March 1980.
80. Leese, K. E. and S. M. Harkins, Integrated Air Cancer Project - Source
Measurement, Research Triangle Institute, March 1986.
81. Cottone, L. E. and E. Messer, Test Method Evaluations and Emissions
Testing for Rating Woodstoves, Publication No. EPA-600/2-86-100 (NTIS
No. PB87-119897), October 1986.
82. U. S. Environmental Protection Agency, Regional Air Pollution Study -
Point Source Emission Inventory, Publication No. EPA-600/4-77-014 (NTIS
No. PB 269567), March 1977.
83. Carey, P. and J. Cohen, Comparison of Gas Phase Hydrocarbon Emissions
from Light-Duty Gasoline Vehicles and Light-Duty Vehicles Equipped with
Diesel Engines, U. S. Environmental Protection Agency, Technical Report
CTAB/PA/80-5, September 1980.
84. Braddock, J, M. and R. L. Bradow, Emission Patterns of Diesel-Powered
Passenger Cars, Society of Automotive Engineers, Paper No. 750682,
June 3-5, 1975.
85. Data obtained from personal communication with Frank Black, U. S.
Environmental Protection Agency, July 1987.
86. Black, F. and L. High, Passenger Car Hydrocarbon Emissions Speciation,
Publication No. EPA-600/2-80-085, May 1980, page 5.
87. Black, F., et al., SAE Technical Paper, Emissions"from In-Use
Heavy-Duty Gasoline Trucks, Presented at the Fuels and Lubricants
Meeting and Exposition, October 8-11, 1984, Baltimore, MD.
88. Carter, R. V. and B. Linsky, Gaseous Emissions from Whiskey
Fermentation Units, Atmospheric Environment, Volume 8, pp. 57-62, 1974.
89. Cronn, D. R., et al., Chemical Characterization of Plywood Veneer Dryer
Emissions, Atmospheric Environment, 8(2), pp. 201-211, 1983.
90. VOC species profiles developed by Radian Corporation from test program
(see Appendix G for details), September 1987.
364
-------
91. Meeting Summary, Meeting with Safety-Kleen, Radian Corporation, and
U. S. Environmental Protection Agency, Research Triangle Park, NC,
November 12, 1986.
92. Organic Solvent Cleaners - Background Information for Proposed
Standards. EPA Report No. EPA-450/2-78-045a (NTIS No. PB80-137912).
U. S. Environmental Protection Agency, Research Triangle Park, NC,
October 1979.
93. Shareef, G. S., Engineering Judgment, Radian Corporation, August 1987.
94. Braddock, J. M. and P. A. Gabele, Emission Patterns of Diesel-Powered
Passenger Cars, Part II, Society of Automotive Engineers, Paper
No. 770168, February 28-March 4, 1977.
95. Department of Ecology, State of Washington, Source Test Report 85-14,
Kaiser Aluminum and Chemical Corporation, September 24-26, 1985.
365
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APPENDIX A
LITERATURE SEARCH AND VOC SPECIES PROFILE DEVELOPMENT
-------
APPENDIX A
LITERATURE SEARCH AND VOC SPECIES PROFILE DEVELOPMENT
This appendix briefly summarizes the literature search conducted in
this study and describes how new VOC profiles were developed from these
data.
A.I LITERATURE SEARCH AND DATA REVIEW
Before conducting a literature search to collect new data, the 1980
Data Manual was carefully reviewed to identify poor quality and/or outdated
profile data, and data gaps. The data confidence levels assigned to each
profile in the Data Manual were used as a criterion for poor quality.
Profiles for the following source categories were identified to be of poor
quality: surface coating, printing press, solvent use, solid waste
incineration, petroleum industry, chemical manufacturing, textiles, mineral
products, and internal combustion engines. Conversations with users of the
Data Manual have helped to identify outdated data (e.g., mobile sources,
gasoline storage/marketing/ handling, and organic solvent usage).
The first step in data collection was to conduct a computerized
literature search of the Engineering Index, Chemical Abstracts, and National
Technical Information Services data bases. The key words (and -several
combinations) used in the search included the following:
VOC Volatile matter
Volatile organic compound Smog
Speciation Exhaust emissions
Organic species profiles Gasoline motor vehicle emissions
Profiles Diesel motor vehicle emissions
Emission inventories (air) Organic solvents
Photochemical modeling Hydrocarbon composition
A-l
-------
Chemical species distribution
Species
Particulate matter profiles
PM10
PM
Particles
Hydrocarbon emissions
Reactive organic compounds
Reactive hydrocarbons
Cleaning solvents
Household (consumer) products
Asphalt
Petroleum products
Textile industry
Degreasing
Vegetation
Natural emissions
Biogenic
The literature search efforts also focused on the following list of
toxic/potentially toxic air pollutants:
Arsenic
Asbestos
Benzene
Beryl1i urn
1,3-Butadiene
Cadmium
Carbon tetrachloride
Chloroform
Chromium
Coke oven emissions
Ethylene dibromide
Ethylene dichloride
Ethylene oxide
Formaldehyde
Gasoline vapors
Mercury
Methylene chloride
Perch!oroethylene
Polycyclic organic matter
Radionuclides
Trichloroethylene
Vinyl chloride
Vinylidene chloride
Although no particulate matter (PM) profiles are contained in the interim
document, the computerized literature search efforts also included PM
species. Information identified relating to PM species will be used in the
second phase of this study.
One of the key references used in this study was a study conducted for
the California Air Resources Board (Improvement of the Emission Inventory
for Reactive Organic Gases and Oxides of Nitrogen in the South Coast Air
A-2
-------
Basin, Reference 1). Other sources of information reviewed included the
National Acid Precipitation Assessment Program (NAPAP), Northeast Corridor
Regional Modeling Project (NECRMP), State data files, Atmospheric Sciences
Research Laboratory, Environment Canada, and Section 114 responses and trip
reports from several standard development activities. See Section 4.0
References for a complete listing of references used to develop the new
profiles. (This list does not include the documents that were also reviewed
but not found useful.)
A.2 VOC SPECIES PROFILE DEVELOPMENT
A.2.1 Profile Development Based on Existing Data
All data identified through the literature search efforts were used as
reported. No attempt was made to verify their completeness. Only those
data for which original documentation was available were included. The data
used in developing the profiles were available in different forms. Some of
the data were already expressed as weight percentages. In other cases,
calculations were necessary to convert from volumetric percentage (or mole
percentage) and emission flow rate (volumetric or mass rate) to weight
percentages.
For several cases, data available from a number of facilities/sources
were combined in proportion to the VOC emissions from each facility/source
to develop a composite profile. For example, in developing Profile 1070
(methanol production - purge gas vent), two sets of data each based on
volume percent were available. The first calculation consisted of .
conversion from volume percent to weight percent. Assuming 100 Ib. moles of
VOC gas mixture, the weight of each species in the mixture was calculated by
multiplying its volume percent by its molecular weight. The weight
percentages were calculated by dividing the weight of each species by the
total weight and multiplying by 100. These calculations are summarized
below:
A-3
-------
Stream A Stream B
Species
Methanol
Dimethyl
ether
Molecular
Weiqht
32.04
46.10
Vol
%
0.20
1.72
Weight
Ib
6.41
79.29
Weight
%
0.39
4.78
Vol
%
2.62
12.08
Weight
Ib
83.94
556.89
Weight
%
4.18
27.72
Methane 16.04 98.08 1573.20 94.83 85.29 1368.05 68.10
1658.90 2008.88
These two streams were combined in proportion to their VOC emissions to
develop Profile 1070. The VOC emission rates for Stream A and B were
1059 Ib/hr and 462 Ib/hr, respectively. The data for Stream A were weighted
by a factor of [1059/(1059 + 462)] = 0.6963 and for Stream B were weighted
by a factor of [462/(1059 + 462)] =0.3037 as shown below:
Composite Data:
Species Weight %
Methanol (0.39 x 0.6963) + (4.18 x 0.3037) = 1.54
Dimethyl ether (4.78 x 0.6963) + (27.72 x 0.3037) = 11.75
Methane (94.83 * 0.6963) + (68.10 x 0.3037) = 86.71
In a few cases, developing composite profiles was based on more complex
calculations. For example, in developing Profile 1101 (light duty gasoline
vehicles) for calendar year 1987, exhaust and evaporative .(hot soak)
emission composition data for 46 in-use passenger cars using two different
fuels were composited using information from AP-42 (fourth edition). Data
from the 46 in-use passenger car study did not contain measurements of
diurnal emission composition. Therefore, diurnal emission composition data
were estimated using data from two other studies (see References 1 and 2 at
the end of this appendix).
The data set from the 46-car study was representative of in-use
vehicles from 1975 to 1982. For model years <1975 and >1982, it was assumed
that the data for model years 1975 and 1982, respectively, would be
A-4
-------
representative. For model years <1975, this is equivalent to assuming the
effect of noncatalyst vehicles on the overall profile will be small due to
their small travel fraction.
In developing Profile 1101, average exhaust and evaporative emission
profiles for each model year were weighted according to the exhaust and
evaporative hydrocarbon emission rates reported in AP-42 for light duty
gasoline vehicles - low altitude (includes tampering). Then, the composite
profile for each calendar year was weighted in proportion to the travel
fraction for that model year to yield Profile 1101. The travel fractions
were calculated using the information in AP-42. In the profile data,
15 percent of n-butane in exhaust emissions was assumed to exist as
1,3-butadiene (see References 2 and 3 at the end of this appendix).
In addition to Profile 1101, Profiles 1203 and 1204 were developed
using the 46-car study to represent exhaust and evaporative emissions,
respectively, from light-duty gasoline vehicles. The approach used in
developing these profiles was the same as that used for Profile 1101 except
for the step where the exhaust and evaporative emissions data were
composited.
Table A-l provides a numerical listing of new profiles contained in
this document including the profile name and its location in this volume.
A.2.2 Profile Development Based on Engineering Judgement
Pure Component Pr'ofiles - For several categories representing storage
of pure organic chemicals or use of pure solvents in operations such as dry
cleaning, degreasing, or surface coating, new VOC profiles were developed
using engineering judgement. In all cases, these profiles consisted of a
single species with a weight percent of 100.
Industry-Specific Average Profiles - In characterizing SCC's with
profile assignments, there were several instances where it was difficult to
make profile assignments based on engineering judgement. For such SCC's,
industry-specific average profiles were developed from original profiles
representing other SCC's within the particular industry group. These
profiles have profile numbers beginning with 9 and they are assigned a data
A-5
-------
quality level of "E." The industry-specific average profiles are
recommended for use only if no other information is available. These
profiles are presented in Appendix B.
"Zero" Profile - Profile 0000 is an overall average of all the VOC
profiles in the data base. It is intended for use as a default profile in
emission inventory development applications to characterize nonzero VOC
emissions reported for SCC's that are associated with "zero" or "negligible"
VOC emission factors. The SCC's with "zero" or "negligible" VOC emission
factors are based on the document "Emission Factors for the 1985 NAPAP
Emissions Inventory" (EPA-600/7-87-015).
A-6
-------
TABLE A-l. PROFILE LISTING
Profile
Number
0001
0002
0003
0004
0005
0007
0008
0009
0011
J 0012
0013
0014
0016
0023
0024
0025
0026
0029
0031
0035
0039
0047
r
Profile Name
*,
External Combustion Boiler - Residual Oil
External Combustion Boiler - Distillate Oil
External Combustion Boiler - Natural Gas
External Combustion Boiler - Refinery Gas
External Combustion Boiler - Coke Oven Gas
Natural Gas Turbine
Reciprocating Diesel Fuel Engine
Reciprocating Distillate Oil Engine
By- Product Coke Oven Stack Gas
Blast Furnace Ore Charging and Agglomerate
Iron Sintering ;
Open Hearth Furnace with Oxygen Lance
Basic Oxygen Furnace
Asphalt Roofing - Spraying
Asphalt Roofing - Tar Kettle
Asphaltic Concrete - Natural Gas Rotary Dryer
Asphaltic Concrete - In Place Road Asphalt
Refinery Fluid Catalytic Cracker
Refinery Fugitive Emissions - Covered Drainage/Separation Pits
Refinery Fugitive Emissions - Cooling Towers
Refinery Fugitive Emissions - Compressor Seals Refinery Gas
Refinery Fugitive Emissions - Relief Valves, Liquified Petroleum Gas
Page
Number
22
23
24
25
26
33
34
35
114
115
116
117
118
125
126
127
128
131
132
133
134
135
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
0051
0066
0068
0072
0076
0078
0079
0085
0087
0088
0089
0090
0100
0121
0122
0127
0166
0182
0183
0195
0197
Profile Name
Natural Gas
Varnish Manufacturing - Bodying Oil
Manufacturing - Plastics - Polypropylene
Printing Ink Cooking
General Pesticides
Ethyl ene Di chloride - Direct Chi ori nation
Chemical Manufacturing - Flares
Perchloroethylene - Drycleaning
Degreasing - 1,1,1-Trichloroethane
Degreasing - Trichlorofluoromethane (Freon 11)
Degreasing - 1,1,2-Trichloroethane
Degreasing - Toluene
Fixed Roof Tank - Commercial Jet Fuel (Jet-A)
Open Burning Dump - Landscape/Pruning
Bar Screen Waste Incinerator
Surface Coating - Varnish/Shellac
Printing Press - Letterpress Inking Process
Printing Press - Gravure General Solvent
Printing Press - Gravure Printing Solvent
Residential Fuel - Natural Gas
Solvent Use - Domestic Solvents
Page
Number
136
43
45
51
55
56
57
156
157
158
159
160
218
326
327
185
236
237
238
27
161
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
0202
0203
0217
0219
0220
0221
0222
0223
0225
ฃ 0226
0227
0228
0229
0230
0271
0272
0273
0274
0275
0277
0282
0288
Profile Name
Solid Waste Landfill Site - Class II
Solid Waste - Animal Waste Decomposition
Coke Oven Blast Furnace Gas
Surface Coating Paint Solvent - Acetone
Paint Solvent - Ethyl Acetate
Paint Solvent - Methyl Ethyl Ketone
Surface Coating -"Enamel - Cellosolve Acetate
Surface Coating -.Varnish/Shellac Solvent - Xylene
Surface Coating - Primer - Mineral Spirits
Surface Coating Solvent - Ethyl Alcohol
Surface Coating Solvent - Isopropyl Alcohol
Surface Coating Solvent - Isopropyl Acetate
Surface Coating Solvent - Lactol Spirits
Fixed Roof Tank - Hexane
Degreasing - Trichloroethylene
Automotive Tires - Tuber Adhesive
Automotive Tires - Tuber Adhesive White Sidewall
Automobile Tire Production
Degreasing - Dichloromethane
Degreasing - Trichlorotrifluoroethane (Freon 113)
Surface Coating Primer - Naphtha
Surface Coating Solvent - Butyl Acetate
Page
Number
328
329
28
186
187
188
189
190
191
192
193
194
195
246
162
142
143
144
163
164
196
197
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
0289
0290
0291
0292
0296
0297
0299
0301
0304
g 0305
0307
0316
0321
0332
0333
1001
1002
1003
1004
1005
1006
Profile Name
Surface Coating Solvent - Butyl Alcohol
Surface Coating Solvent - Cellosolve
Surface Coating Solvent - Methyl Alcohol
Surface Coating Solvent - Dimethylformamide
Fixed Roof Tank - Crude Oil Production
Fixed Roof Tank - Crude Oil Refinery *
Fixed Roof Tank - Cyclohexane
Fixed Roof Tank - Heptane
Printing Press - Flexographic, n-Propyl Alcohol
Fixed Roof Tank - Crude Oil Marine Terminal
Miscellaneous Burning - Forest Fires
Pipe/Valve Flanges
Pump Seals - Composite
Printing Press - Lithography Inking and Drying
Lithography.- Inking and Drying-Direct Fired Dryer
Internal Combustion Engine - Natural Gas
Chemical Manufacturing - Carbon Black Production
Surface Coating Operations - Coating Application - Solvent-base Paint
Plastics Production - Polystyrene
Plastics Production - Polyester Resins
Phthalic Anhydride - o-Xylene Oxidation - Main Process Stream
Page
Number
198
199
200
201
219
220
247
248
249
221
357
137
138
239
240
36
39
202
46
47
58
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
1007
1008
1009
1010
1011
1012
1013
1014
1015
1016
1017
1018
1019
1020
1021
1022
1023
1024
1025
1026
Profile Name
Mineral Products^ - Asphaltic Concrete
Rubber and Miscellaneous Plastics Products - Fabricated Rubber Products -
Styrene/Butadi ene
Plastics Production - Acrylonitrile - Butadiene - Styrene Resin
Oil and Gas Production - Fugitives - Unclassified
Oil and Gas Production - Fugitives - Valves and Fittings - Liquid Service
Oil and Gas Production - Fugitives - Valves and Fittings - Gas Service
Surface Coating Operations - Coating Application - Water-base Paint
Gasoline - Summer Blend
Gasoline - Winter Blend
Surface Coating Operations - Thinning Solvents - Composite
Surface Coating Operations - Coating Application - Lacquer
Surface Coating Operations - Coating Application - Enamel
Surface Coating Operations - Coating Application - Primer
Surface Coating Operations - Coating Application - Adhesives
Degreasing - Open Top - Chlorosolve
Printing/Publishing - Ink Thinning Solvents - Methyl Isobutyl Ketone
Terephthalic Acid/Dimethyl Terephthalate - Crystallization, Separation
and Drying Vent
Terephthalic Acid/Dimethyl Terephthalate - Distillation and Recovery Vent
Terephthalic Acid/Dimethyl Terephthalate - Product Transfer Vent
Surface Coating Operations - Thinning Solvent - Hexylene Glycol
Page
Number
129
145
48
147
148
149
204
222
224
205
206
207
208
209
165
241
59
60
61
210
-------
TABLE A-l. PROFILE LISTING (Continued)
ro
Profile
Number
1027
1028
1029
1030
1031
1032
1033
1034
1035
1036
1037
1038
1039
1040
1041
1042
1043
1044
1045
1046
Profile Name
Ketone Production - Methyl Ethyl Ketone (MEK)
Acetone - Light Ends Distillation Vent
Acetone - Acetone Finishing Column
Aldehydes Production - Formaldehyde - Absorber Vent
Surface Coating Operations - Thinning Solvent - Ethylene Oxide
Aldehydes Production - Acrolein - Distillation System
Aldehydes Production - Acrolein - Reactor Blowoff Gas
Chloroprene - Butadiene Dryer
Chloroprene - Chloroprene Stripper and Brine Stripper
Secondary Aluminum - Pouring and Casting
Organohalogens - Ethylene Dichloride - Ethylene Dichloride Via Direct
Chlorination - Distillation Vents
Organohalogens Production - Ethylene Dichloride - Ethylene Dichloride Via
Oxychlori nation
Organohalogens Production - Ethylene Dichloride - Caustic Scrubber
Fluorocarbons/Chlorofluorocarbons - General
Fluorocarbons/Chlorofluorocarbons - Distillation Column
Fluorocarbons/Chlorofluorocarbons - Fugitive Emissions - General
Acrylic Acid - Quench Absorber
Organic Acids Production - Formic Acid
Organic Acids Production - Acetic Anhydride - Distillation Column Vent
Esters Production - Acrylates - Ethyl Acrylate
Page
Number
62
63
64
65
211
66
67
68
69
119
70
71
72
73
74
75
76
77
78
79
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
1047
1048
1049
1050
1051
1052
1053
1054
> 1055
E 1056
1057
1058
1059
1060
1061
1062
1064
1065
1066
1067
Profile Name
Esters Production - Butyl Acrylate
Cumene Production - Cumene Distillation System Vent
Cyclohexane - General
Cyclohexanone/Cyclohexanol - Phenol Hydrogenation Process - Distillation Vent
Vinyl Acetate - Inert Gas Purge Vent
Vinyl Acetate - C02 Purge Vent
Vinyl Acetate - Inhibitor Mix Tank Discharge
Vinyl Acetate - Refining Column Vent
Organic Chemical Storage - Methyl amyl Ketone
Ethylene Oxide - Oxygen Oxidation Process Reactor - C02 Purge Vent
Ethylene Oxide - Oxygen Oxidation Process Reactor - Argon Purge Vent
Ethylene Oxide - Stripper Purge Vent
Methyl Methacrylate (MMA) - Hydrolysis Reactor, MMA and Light Ends
Distillation Unit
Methyl Methacrylate (MMA) - Acid Distillation and MMA Purification
Nitrobenzene - Reactor and Separator Vent - Washer and Neutral izer Vent
Benzene
Olefins Production - Ethylene - Compressor Lube Oil Vent
Propylene Oxide - Chlorohydronation Process - General
Styrene - General
Styrene - Benzene Recycle
Page
Number
80
81
82
83
84
85
86
87
250
88
89
90
91
92
93
94
95
96
97
98
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
1068
1069 .'
1070
1071
1072
1073
1074
1075
1076
1077
1078
1079
1080
1081
1082
1083
1084
1085
1086
1087
Profile Name
Styrene - Styrene Purification
Organic Chemical Storage - N-Propyl Acetate
Alcohols Production -Methanol - Purge Gas Vent
Alcohols Production - Methanol - Distillation Vent
Chlorobenzene - Tail Gas Scrubber
Chlorobenzene - Benzene Drying Distillation
Monochl orobenzene
Chlorobenzene - Vacuum System Vent
Chlorobenzene - Di Chlorobenzene Crystallization
Chlorobenzene - Di Chlorobenzene Crystal Handling/Loading
Railcar Cleaning - Low Vapor Pressure, High Viscosity Cargo (Ethylene Glycol)
Railcar Cleaning - Low Vapor Pressure, Medium Viscosity Cargo
(o-Dichlorobenzene)
Railcar Cleaning - Low Vapor Pressure, High Viscosity Cargo (Creosote)
Tank Truck Cleaning - Medium Vapor Pressure, Medium Viscosity Cargo
(Methyl Methacrylate)
Tank Truck Cleaning - Low Vapor Pressure, Low Viscosity Cargo (Phenol)
Tank Truck Cleaning - Low Vapor Pressure, High Viscosity Cargo (Propylene
Glycol)
Residential Wood Combustion (C1-C6)
External Combustion Boiler - Coal -Slurry Fired
Pr i nt i ng/Fl exograph i c
Organic Chemical Storage/i -Butyl i-Butyrate
Page
Number
99
251
100
101
102
103
104
105
106
107
319
320
321
322
323
324
331
29
242
252
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number . .
1088
1089
1090
1091
1092
1093
1094
1095
1096 -
1097
1098
1099
1100
1101
1103
1104
1105
1106
1107
1108
1109
1110
Profile Name
Surface Coating Operations - Adhesive Application
Secondary Metal Production - Gray Iron Foundries - Pouring/Casting
Fluorocarbon Manufacturing - CF 12/11
Plastics Production - Polyvinyl Chlorides and Copolymers
Synthetic Organic Fiber Production - Nylon Batch Production Process
Fluorocarbon Manufacturing - CF 23/22
Paint Manufacture - Blending Kettle
Textile Products.- General Fabric Operations - Dyeing and Curing
Textile Products - General Fabric Operations - Tenter Frame
Aircraft Landing/Takeoff (LTO) - Military
Aircraft Landing/Takeoff (LTO) - Commercial
Aircraft Landing/Takeoff (LTO) - General Aviation
Gasoline Refueling
Light Duty Gasoline Vehicles
1-Pentene
Acetaldehyde
Acetic Acid
Acetic Anhydride
Acrolein
Acrylic Acid
Acrylonitrile
Adipic Acid
Page
Number
212
120
108
49
53
109
41
151
153
350
352
354
227
335
253
254
255
256
257
258
259
260
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
1111
1112
1114 ^
1115
1116
1118
1119
1120
1121
1122
1123
1124 ;
1125
1126
1127
1128
1129
1130
1131.
1132
1134
1135
Profile Name
Aniline
Benzyl Chloride
Butyl Acrylate
Butyl Carbitol
Butyl Cellosolve
Carbitol
Carbon Tetrachloride
Acetylene
Chloroform
Cresol .
Cumene
Cyclohexanol
Cyclohexanone
Cyclopentene
; Diethylene Glycol
Diisopropyl Benzene
Dipropylene Glycol
Dodecene
Epichlorohydrin
Ethanol amines
Ethyl Acrylate
Ethyl Benzene
Page
Number
261
262
263
264
265
266
267
110
268
269
270
271
272
273
274
275
276
277
278
279
280
281
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
1136
1137
1138
1139
1140
1141
1142
1144
1145
1146
1147
1148
1149
1150
1151
1152
1153
1154
1155
1158
1159
1160
Profile Name
Ethyl Ether
Ethyl Mercaptan
, Ethyl ene Di bromide
Ethyl eneamines
Formaldehyde
Formic Acid
Furfural
Heptenes
Isobutyraldehyde
Isobutyl Aery late
Isobutyl Alcohol
Isoprene
Methanol
Methyl Acetate
Methyl Acrylate
Methyl Carbitol
Methyl Cellosolve
Methyl Styrene
Methyl all ene
Methyl t-Butyl Ether
m-Xylene
Nitrobenzene
Page
Number
282
283
284
285
286
287
166
288
289
290
291
292
167
293
294
295
296
297
298
299
300
301
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
1162
1163
1164
1165
1166
1167
1168
1171
1172
1173
1174
1175
1176
1178
1185
1186
1187
1188
1189
1190
1191
1192
* *
Profile Name
r
N-Butyraldehyde
N-Decane
N-Dodecane
o-Xylene
Pentadecane
Residential Wood Combustion
Piperylene
Propionaldehyde
Propionic Acid
Propylene Oxide
p-Xylene
Tert-Butyl Alcohol
Toluene Diisocyanate
Coal -Fired Boiler - Electric Generation
Coal -Fired Boiler - Industrial
Heavy-Duty Gasoline Trucks
Citrus Coating
Fermentation Processes
Pulp and Paper Industry - Plywood Veneer Dryer
Gasoline Marketed
Graphic Arts - Printing
Degreasing
Page
Number
302
303
304
305
306.
332
307
308
309
310
311
312
313
30
31
338
213
112
140
230
243
168
-------
TABLE A-l. PROFILE LISTING (Continued)
Profile
Number
1193
1194 ;
1195
1196
1197
1198
1199
1200
1201
1202
1203
1204
Profile Name
Drycleaning
Auto Body Repair
Degreasing Composite
Drycleaning Composite
Isooctane
Pentane
Isopentane
Cyclopentane
Light-Duty Diesel Vehicles
Primary Aluminum Production
Light-Duty Gasoline Vehicles - Exhaust Emissions
Light-Duty Gasoline Vehicles - Evaporative Emissions
Page
Number
172
214
176
180
314
315
316
317
341
121
343
346
-------
REFERENCES FOR APPENDIX A
1. Black, F. and L. High, Passenger Car Hydrocarbon Emissions Speciation,
EPA Report No. EPA-600/2-80-085, U. S. Environmental Protection Agency,
Research Triangle Park, NC, May 1980.
2. Data obtained from personal communication with P. A. Gabele, U. S.
Environmental Protection Agency, July 1987.
3. Memorandum from John E. Sigsby, Jr., ASRL/EPA, to John Summerhays, EPA
Region 5, concerning review of report "Air Toxics Emission Inventory
for the Southeast Chicago Area," January 30, 1987.
4. Telephone conversation with Penny Carey of OMS/EPA concerning
percentage of 1,3-butadiene in vehicle emissions where it is reported
as n-butane/l,3-butadiene, March 24, 1987.
A-20
-------
APPENDIX B
INDUSTRY-SPECIFIC AVERAGE PROFILES AND "ZERO" PROFILE
-------
APPENDIX B
INDUSTRY-SPECIFIC AVERAGE PROFILES AND "ZERO" PROFILE
This appendix contains the industry-specific average profiles developed
from original profiles representing specific SCC's within the particular
industry group. These profiles are recommended for use only if no other
information is available. Since there is no specific SCC associated with
these profiles, the entry for SCC designation on the profile is modified as
"no original SCC."
This appendix also contains Profile 0000 which is an overall average of
all the VOC profiles in this document. This profile is intended for use as
a default profile to characterize nonzero VOC emissions reported by States
or any other agency for SCC's with "zero" or "negligible" VOC emission
factors in the "Criteria Pollutant Emission Factors for the 1985 NAPAP
Emissions Inventory" (EPA-600/7-87-015).
A numerical listing of the profiles included in this appendix is given
below:
Profile Number Profile Name
.0000 . Overall Average . . .
9001 External Combustion Boilers - Industrial - Average
9002 Internal Combustion - Average
9003 Industrial Processes - Average
9004 Chemical Manufacturing - Average
9005 Plastics Production - Average
9006 Synthetic Organic Fiber Production - Average
. 9007 Alcohols Production - Average
9008 Food and Agriculture - Average
9009 Primary Metal Production - Average
B-l
-------
Profile Number Profile Name
9010 Secondary Metal Production - Average
9011 Mineral Products - Average
9012 Petroleum Industry - Average
9013 Pulp and Paper Industry - Average
9014 Rubber and Miscellaneous Plastics Products - Average
9015 Oil and Gas Production - Average
9016 Textile Products - Average
9017 Drycleaning/Degreasing - Average
9021 Surface Coating Operations - Average
9022 Solid Waste Disposal - Average
9023 Thinning Solvents - Average
9024 Petroleum Product Storage - Average
9025 Bulk Terminals - Petroleum Storage Tanks - Average
9026 Printing/Publishing - Average
9027 Transportation and Marketing of Petroleum
Products - Average
9028 , Organic Chemical Storage - Average
9029 Organic Chemical Storage - Fixed Roof Tanks -
Alcohols - Average
9030 Organic Chemical Storage - Fixed Roof Tanks -
Alkanes - Average
9031 Organic Chemical Storage - Fixed Roof Tanks -
Alkenes - Average
9032 Organic Chemical Storage - Fixed Roof Tanks -
Amines - Average
9033 Organic Chemical Storage - Fixed Roof Tanks -
Aromatics - Average
B-2
-------
Profile Number Profile Name
9034 Organic Chemical Storage - Fixed Roof Tanks -
Carboxylic Acids - Average
9035 Organic Chemical Storage - Fixed Roof Tanks -
Esters - Average
9036 Organic Chemical Storage - Fixed Roof Tanks -
Glycol Ethers - Average
9037 Organic Chemical Storage - Fixed Roof Tanks -
Glycols - Average
9038 Organic Chemical Storage - Fixed Roof Tanks -
Halogenated Organics - Average
9039 Organic Chemical Storage - Fixed Roof Tanks -
Isocyanates - Average
9040 Organic Chemical Storage - Fixed Roof Tanks -
Ketones - Average
9041. Organic Chemical Storage - Floating Roof Tanks
Aldehydes - Average
9042 Organic Chemical Storage - Floating Roof Tanks
Alkanes - Average
9043 Organic Chemical Storage - Floating Roof Tanks
Ethers - Average
9044 Organic Chemical Storage - Floating Roof Tanks
Halogenated Organics - Average
9046 Organic Chemical Storage - Pressure Tanks -
Alkenes - Average
!
9047 Organic Solvent Evaporation - Miscellaneous -
Average
B-3
-------
PROFILE NAME:Over all Averaae
PROFILE NUMBER:0000
PROFILE DATA G1UALITY:E
CONTROL DEVICE:NOT APPLICABLE
REFERENCE(S):93
DATA SOURCE:Profile based on average of all profiles,
SCC : NO-SCC
3AROAD
NUMBER
43105
43106
43107
43108 .
43109
43110
43111
43113
43114.
43115
43116
43117
43118
43119
43120
43121
43122
43125
43126 ,
43127
43129
43130
43131
43132
43133
43140
43141
43143
CAS SPECIES-
NUMBER NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
' ISOMERS OF DEGANE
ISOMERS .OF UNDECANE
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
ISOMERS OF PENTADECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
MINERAL SPIRITS
LACTOL SPIRITS
ISOMERS OF BUTENE
ISOMERS OF PENTENE
ISOMERS OF PENTANE
CIO OLEFINS
C2 CYCLOHEXANE
C3 CYCLOHEXANE
C4 SUBSTITUTED CYCLOHEXANE
C5 SUBSTITUTED CYCLOHEXANE
C6 SUBSTITUTED CYCLOHEXANE
ALIPHATICS
PARAFFINS (C16-C34)
C7-C16
CQ PARAFFIN
C5 OLEFIN
noL.
WEIGHT
86.17
100.20
114.23
128.25
142.28
1 56 . 30
170.32
198.38
212.41
98.19
112.23
126.26
114.00
114.00
56.10
70.13
72.15
140.27
112.22
126.24
142.28
154.30
170.32
100.00
352.43
163.32
114.23
70.13
PERCENT
WEIGHT
0 . 54
0.25
0.15
0.19
0 . 40
0.05
0 . 46
0 .01
0 . 42
0.71
0 . 05
0 . 00
0 . 64
0 . 36
0 . 0 5
0.05
1.11
0 . 03
0.01
0 . 0 1
0.01
0.01
0.01
0.10
0 . 02
0.15
0 . 02
0.01
B-4
-------
can tinned ( prof i .1 e~oOOO )
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43144 C5 PARAFFIN 72.15 0.01
43145 C5 PARAFFIN/OLEFIN 70.13 . O-.OO
43150 ISOMERS OF C10H18 138.25 0.01
43155 ISOMERS OF HEPTADECANE 240.47 0.01
43156 ISOMERS OF OCTADECANE 254.50 0.01
43201 74-43-8 METHANE 16.04 7.36
43202 74-48-0 ETHANE 30.07 1.39
43203 74-48-1 ETHYLENE 28.05 2.86
432O4 74-49-6 PROPANE 44.09 2.40
43205 115-50-i PROPENE 42.08 1.40
43206 74-48-2 ACETYLENE 26.04- 0.86
43212 106-69-8 N-BUTANE 58.12 1.81
43213 106-69-9 BUTENE 56.10 0.40
43214 75-52-5 ISO-BUTANE . 58.12 0.42
43216 624-46-6 T-2-BUTENE 56.11 0.01
43218 106-69-0 1,3-BUTADIENE 54.09 0.67
43220 109-96-0 N-FENTANE . 72'. 15 0.71
43221 78-87-4 ISO PENTANE 72.15 0.08
43224 109-96-1 1-PENTENE 70.13 0.54
43225 563-34-2 2-METHYL-l-BUTENE . 70.13. 0.01
43226 646-60-8 TRANS-2-PENTENE ' . 70.13' 0.01
43227 627-72-3 CIS-2-PENTENE 70.13 0.00
43228 513-33-9 2-METHYL-2-BUTENE ' . . 70.13 0.00
43229 107-78-5 .2-METHYLFENTANE 86.17 0.02
43230 96-61-0 3-METHYL PENTANE 86.17 0.03
43231 110-05-3 HEXANE 86.17 1.37
43232 142-28-5 HEPTANE 100.20 1.40
43233 111-16-9 OCTANE 114.23 0.21
43235 111-18-2 NONANE 128.25 0.09
43238 124-41-5 N-DECANE ' 142.28 0.54
43241 1120-02-4 N-UNDECANE , 156.31 0.14
43242. 287-79-3 CYCLOPENTANE 70.14 0=01
43243 78-87-5 ISOPRENE 68.12 0.4O
43245 592-24-6 1-HEXENE 34.16 0.03
43247 108-80-7 2,4-DIMETHYLPENTANE 1OO.20 O.04
43248 110-08-7 CYCLOHEXANE 34.16 0.90
43250 540-08-1 2,2,4-TRIMETHYLPENTANE 114.22 0.01
43255 112-24-3 N-DODECANE 170.33 0.19
43256 80-05-8 A-PINENE 136.24 0.35
43257 127-79-3 B-PINENE 136.24 0.23
43258 629-95-5 N-TRIDECANE 184.36 0.10
43259 629-95-4 N-TETRADECANE 198.38 0.07
43260 629-96-9 N-PENTADECANE 212.41 0.17
43261 108-88-2 METHYLCYCLOHEXANE 98.21 0.13
43262 96-63-7 METHYLCYCLOPENTANE 84.16 0.27
B-5
-------
continued ( prof i le=0000 '.
SAROAD
NUMBER
43264
43273
43277
43280
43281
43282
43283
43284
43285
43286
43288
43291
43292
43295
43301
43302
43303
43304
43305
433.06
43308
43309
43310
43311
43313
43314
43317
43318
43322
43350
43351
43367
43369
43370
43371
43373
43374
43376
43377
43378
43379
43403
43404
43405
43407
CAS
NUMBER
110-03-8
107-70-6
503-31-3
625-52-4
1678-89-7
75-58-2
142-22-0
589-93-4
67-75-1
64-41-5
71-12-8
67-76-0
71-13-3
78-88-1
111-17-2
75-56-0 '
109-98-4
110-08-5
78-89-2
108-89-0
104-47-7
110-06-4
115-51-6
60-02-7
57-75-6
107-72-1
107-74-5
111-14-6
106-66-7
628-82-4
111-19-0
111-17-3
112-23-5
64-41-6
64-41-7
79-90-4
79-91-7
SPECIES
NAME
HEPTENE
CYCLOHEXENE
2 , 4-D I METHYLHEX ANE
2,3,3 TRIMETHYLPENTANE
1-BLJTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
ETHYLCYCLDHEXANE
2 , 2-D I METHYLBUTANE
CYCLOPENTENE
3-METHYLHEXANE
METHYL ALCOHOL
ETHYL ALCOHOL
N-PROF'YL ALCOHOL
ISO-PROPYL ALCOHOL
N-BUTYL ALCOHOL
ISQBUTYL ALCOHOL
BUTYL CELLOSOLVE
TERT-BUTYL ALCOHOL
METHYL CELLOSOLVE
CELLOSOLVE
l-ETHOXY-2-PROPANOL
S-BUTYL ALCOHOL
CYCLOHEXANOL
2-ETHYL HEXANOL
1,4 BUTANEDIOL
DIMETHYLETHER
ETHYL ETHER
GLYCOL ETHER
PROPYLENE GLYCOL
ETHYLENE GLYCOL
HEXYLENE GLYCOL
D I ETHYLENE GLYCOL
D I PROPYLENE GLYCOL
METHYL T-BUTYL ETHER
CARBITOL
METHYL CARBITOL
BUTYL CARBITOL
FORMIC ACID
ACETIC ACID
PROP I ON 1C ACID
ACRYLIC ACID
MOL.
WEIGHT
98.18
82.14
114.22
114.22
54 . 09
54 . 09
84.16
84.16
84.16
112.20
112.23
86.17
68.11
100.20
32 . 04
46 . 07
60.10
60 . 09
74.12
74.12
118.17
74.12
76.11
90.12
104.15
74.12
100.16
130.23
90.12
46 . 07
74.12
106.12
76 . 00
62 . 07
118.18
106.12
134.18
88.15
134.18
120.15
162.23
46 . 03
60.O5
74 . 08
72 . 06
PERCENT
WEIGHT
0.51
o-.oi
0 . 06
0.00
0 . 02
0.01
0.01
0.01
0 . 0 1
0 . 00
0 . 02
0 . 00
0 . 40
0 . 0 1
1 . 40
1.36
0 . 42
0.73
0 . 69
0.42
0 . 44
0 . 42
0 . 39
0 . 36
0 . 00
0 , 34
0.45
0 . 00
0 . 04
1.12
0 . 62
0 . 0 5
0 . 38
0 . 37
0 . 36
0 . 39
0 . 66
0 . 33
0 . 46
0 . 39
0 . 39
0 . 42
0 . 73
0 . 40
0.45
B-6
-------
continued (profile=0000)
3AROAD
NUMBER
43408
43409
43430
43432
43433
43434
43435
43437
43438
43440
43441
43444
43450
43451
43452
43453
43454
43455
43456
43457
43458
43459
43467
43468
43469
43472
43502
43503
43504
43505
43510
43511
43513
43514
43520
43551
43552
43560
43561
43562
43562
43563
43567
43568
43570
CAS
NUMBER
57-71 --3
124-40-9
107-73-3
79-92-9
141-17-6
109-96-4
138-82-7
96-63-3
14O-08-5
141-13-2
80-O6-6
108-82-4
68-81-2
297-78-8
111-11-9
108-80-4
112-23-0
124-41-7
1 -I ^ป_''^/. O
_L J. ji. x_O O
109-93-5
106-66-8
124-41-4
50-00-0
75-50-0
123-33-6
107-70-8
123-37-8
73-88-2
107-72-2
78-89-8
67-76-1
78-89-3
108-81-1
108-G9-1
110-04-0
110-04-0
7379-91-6
SPECIES
NAME
PALMITIC ACID
ADIPIC ACID
METHYL FORMATE
METHYLACETATE
ETHYL ACETATE
N-PROPYL ACETATE
N-BUTYL ACETATE
METHYL ACRYLATE
ETHYL ACRYLATE
BUTYL ACRYLATE
METHYL METHACRYLATE
ISOPROPYL ACETATE-
DIMETHYL FORMAMIDE
ISOBUTYL TSOBUTYRATE
CELL050LVE ACETATE
VINYL ACETATE
METHYL PALMITATE
METHYL MYRISTATE
METHYL STEARATE
METHYLAL
SUBSTITUTED C9 ESTER (C12)
C5 ESTER
C4 SUBSTITUTED CYCLOHEXANONE
ISQBUTYL ACRYLATE
BUTOXYETHOXYETHANOL ACETATE
BUTOXYBUTENE '
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACROLEIN
BUTYRALDEHYDE
I SOBUTYRALDEHYDE
GLYOXAL
METHYL GLYOXAL
TOTAL C2-C5 ALDEHYDES
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
CYCLOHEXANONE
METHYL AMYL KETONE
METHYL AMYL KETONE
2-METHYL-3-HEXANONE
TETRAMETHYLPENTANONE
NONENONE
ALKENE KETONE
MOL.
WEIGHT
256.43
146.14
60.05
74.08
88.10
102.15
116.16
86 . 09
IQO.il
128.17
100 ..13
102.13
73 . 09
144.21
132.16
86 . 09
270.46
242.41
298.52
76 . 09
'218.24
130.19
154.26
128.19
162.00
128.21
30 . 03
44.05
58 . 08
56 . 07
72.12
72.11
58 . 04
72.07
72.12
58 . 08
72.10
100.16
98.15
114.21
114.21
114.19
157.25
138.25
72.10
PERCENT
WE I GHT
0 . 20
0 . 40
0.21
0.71
0 . 44
0 . 49
0 . 58
0 . 38
0 . 50
0 , 43'
0 . 46
0 . 47
0 . 36
0 . 39
0 . 36
0.55
0 . 08
0 . 03
0.11
O..'l7
0.09
0 . 02
0.01
' 0.38
0.01
0.01
1.55
0 . 84
0 . 42
0 . 77
0 . 44
0 . 42
0 .02
0 . 02
0.12 . .
1.47
1OO
.ฃ. ji-
0 . 56
0 . 53
0 . 50
0.01
0 . 07
0 . 00
0 . 02
0.01
B-7
-------
continued (profile=0000)
SAROAD
NUMBER
43601
43602
43603
43604
43704
43721
43740
43776
43777
43778
43302
43803
43804
43805
43811
43812
43814
43815
43817
43820
43821
43822
43823
43824
43835
43837
43838
43839
43840
43841
43842
43843
43844
43845
43860
43862
43863
43902.
43933
43934
43950
43951
45101
45102
45104
CAS
NUMBER
75-52-8
75-55-9
108-83-6
108-82-7
107-71-1
75-50-7
75-55-3
124-40-4
141-14-5
75-50-2
67-76-3
56-62-5
74-49-3
75-56-4
75-50-3
71-15-6
107-70-2
127-71-4
79-90-5
76-61-1
75-57-8
79-90-6
78-88-4
106-69-4
26638-81-7
75-57-0
75-54-6
76 61 ji
76-61-3
76-61-4
75-54-7
75-57-9
75-50-4
126-69-8
106-68-8
75-50-1
433-35-1
75-51-0
556-66-2
1330-02-7
SPECIES
NAME
ETHYLENE OXIDE
PROPYLENE OXIDE
MALE 1C ANHYDRIDE
ACETIC ANHYDRIDE
ACRYLONITRILE
ETHYLAMINE
TRIMETHYLAMINE
HEX AMETHYLENED I AM I NE
ETHANOLAMINE
ETHYLENEAMINE3
DICHLOROMETHANE
CHLOROFORM
CARBON TETRACHLORIDE
METHYLENE BROMIDE
TR I CHLOROFLUOROMETHANE
ETHYL CHLORIDE
1,1, 1-TRICHLOROETHANE
ETHYLENE D I CHLORIDE
PERCHLOROETHYLENE
1 ., 1 , 2-TR I CHLOROETHANE
. TRICHLOROTRIFLUOROETHANE '
TRIMETHYLFLUOROSILANE
D I CHLOROD I FLUOROMETHANE
TR I CHLOROETHYLENE
1-CHLOROBUTANE
ETHYLENE DIBROMIDE
PROPYLENE D I CHLORIDE
TETRAFLUOROMETHANE
CHLOROD I FLUOROMETHANE
DICHLOROTETRAFLUORETHANE
CHLOROPENTAFLUOROETHANE
HEXAFLUOROETHANE
TR I FLUOROMETHANE
CHLOROTR IFLUOROMETHANE
VINYL CHLORIDE
CHLOROPRENE
EPICHLOROHYDRIN
ETHYL MERCAPTAN-
CARBONYL SULFIDE
CARBON SULFIDE
OCTAMETHYLCYCLOTETRASILOXANE
SILOXANE
NAPHTHA
ISOMERS OF XYLENE
ISOMERS OF ETHYLTOLUENE
MOL.
WEIGHT
44.05
58 . 08
93 . 06
102.09
53 . 06
45.09
59.11
116.20
61.08
43 . 07
84 . 94
119.39
153.84
173.35
137.38
64.52
133.42
99 . 00
165.83
133.42
187.38
92 . 00
120.91
131. 4O
92.57
187.88
112.99
88.01
36.47
170.92
1 54 . 47
133.01
70.01
104.46
62 . 50
38.54
92.53
62.13
60 . 08
76.14
296.62
76 . 08
114.00
106.16
120.19
PERCENT
WEIGHT
0 . 38
o : so
0 . 07
0.35
0 . 58
0 . 00
0 . 00
0 . 67
0 . 44
0 44-
0,75
0.51
0.65
0 . 03
0.61
0 . 29
0 . 43
0 . 58
0 .70
0.35.
0.40
0 . 69
0.35
0 . 43
0.01
0 . 42
0 . 02
0 . 03
0.16
0.01
0 . 02
0 . 40
0 . 30
0.05
. 0 . 42
0 . 34
0 . 42
0 . 33
0 . 03
0 . 09
0.01
0 . 00
0 . 47
0 , 70
0 . 04
B-8
-------
continued (p ro f i1e=0000)
SAROAI
NUMBEF
45105
45106
45107
45108
45109
45110
45201
45202
45203
45204
45205
45206
45207
45208
45210
45212
45220
45221
45226
45228
45232
45233
45236
45233
45243
45244
45245
45300
45401
45402
45403
45451
45452
45455
45456
45477
45501
45502
45503
45601
45605
45701
45702
45703
45705
) CAS
? NUMBER
25551-11-7
71-14-2
108-88-3
10O-04-4
95-54-6
108-83-3
106-64-3
108-86-8
95-56-6
98-88-8
620-01-4
100-04-5
25013-31-4
92-25-4
1,03-32-7
108-89-2
65-58-0
100-02-0
131-11-3
84-47-2
136-66-7
85-56-7
100-05-7
104-48-0
98-80-1
85-54-9
1319-97-3
62-25-3
98-89-3
SPECIES
NAME
ISOMERS OF BUTYLBENZENE
ISOMERS OF DIETHYLBENZENE
TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
C3/C4/C5 ALKYLBENZENES
CIO AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
1,3, 5--TR IMETHYLBENZENE
1 ,2,4-TR.IMETHYLBENZENE
CUMENE (ISOPROPYL BENZENE)
M-ETHYLTOLUENE
STYRENE
METHYL STYRENE
BIPHENYL
ETHYL STYRENE . . .
DIPHENYL ETHANE
ETHYL-PHENYL-PHENYL-ETHANE
DI ISOPROPYL BENZENE .
ETHYLTOLUENE
. ETHYLDIMETHYLBENZENE
TETRAMETHYLBENZENE
C5-ALKYLBEIMZENES
PHENOL
XYLENE BASE ACIDS
BENZOIC ACID
TEREPHTHALIC ACID
DIMETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZOATE
BUTYLISOPROPYLPHTHALATE .
BUTYLBENZYLPHTHALATE
BENZALDEHYDE
P-TOLUALDEHYDE
2-FURFURAL
PHTHALIC ANHYDRIDE
CRESOL
ANILINE
NITROBENZENE
2,2 DICHLORONITROANIL.INE
BROMODINITROBENZENE
MOL.
WEIGHT
134.22
134.21 .
120.19
120.19
134.21
134.22
78 . 1 1
92.13
106.16
106.16
106. 16
. 106.16
120.19
120.19
120.20
120.19
104.14
118.19
154.21
132.21
182.27
210.32
162.28
120.19
iปn*-v *~ป ซ
^.^ . JL 1
134.22
148.24
94.11
230 . OO
122.13
166.14
194.19
278.35
178.23
171.22
192.00
106.13
120.16
96 . 09
148.00
108.14
93.13
123.11
207 . 02
247 . 02
PERCENT
WEIGHT
0.06
0-.03
0 . 1 1
0 .02
0 . 03
0 . 0 1
2.82
2 . 04
0.65
0 . 59
0 . 57
0 . 40
0 . 03
0.01
0 . 38
0 . 03
1.20
0.41
0.01
'; 0.03
0 . OO
0.01
0 . 38
0 . 02
0 , 00
0 . 00
0 . 00
0.44
0 . 00
0 . 04
0 . OO
0 . 06
0 . 04
0.21
0.05
0 . 00
0 . 02
0 . 00
0 . 37
0 . 20
0 . 38
0 . 79
0 . 33
0 . 0 1
0 . 0 1
B-9
-------
con tinned (prof i1e=0000)
SAROAD CAS
NUMBER NUMBER
45731
45740
45750
45801
45805
45807
45808
45810
45830
46102
46112
46114
46210
46701
46702
46705
46706
46707
46708
46710
46711
46713
46714
46715
46717
90001
90010
90011
90014
90019
90020
90021
90026
90028
90030
90047
90048
90049
90050
90051
90052
90053
90060
90064
90067
58-88-9
504-46-9
108-89-7
95-55-1
106-64-7
2531-12-6
100-04-7
84-46-i
103-37-9
100-06-8
8001-15-9
91-12-3
208-89-8
83-33-9
86-67-7
85-50-8
206-64-0
129-90-0
218-80-9
205-59-2
112-24-4
8720-05-9
544-47-3
5794-40-6
123-33-3
5989-92-5
SPECIES
NAME
TOLUENE DIISOCYANATE
TOTAL AROMATIC AMINES
PIF'ERYLENE
CHLOROBENZENE
0-DICHLOROBENZENE
P-D I CHLOROBENZENE
DICHLOROBENZENES
BENZYL CHLORIDE
TR I CHLOROBENZENES
ANTHRAQUINONE
PHENYL ISOCYANATE
4-METHYLANILINE
CREOSOTE .
NAPTHALENE
METHYL NAPHTHALENES
ACENAPHTHYLENE
ACENAPHTHENE
FLUORENE
PHENANTHRENE
FLUORANTHENE
C2 ALKYL INDAN
PYRENE
BENZO ( g , h , i ) . FLUORANTHENE
CHRYSEIME
BENZO (b) FLUORANTHENE
DODECENE
M-XYLENE AND P-XYLENE
METHYLALLENE
1-DECENE
C6H1803SI3
C8H2404SI4
METHYLPROPANE
METHYLPENTANE
METHYLHEXANE
HEXADECANE
METHYLNONANE
METHYLDECANES
METHYLUNDECANE
CAMPHENE
MYRCENE
B-PHELLANDRENE
D-LIMONENE
DIMETHYLBUTANE
D I METHYLCYCLOPENTANE
DIMETHYLHEXANES
MOL.
WEIGHT
174.17
93.13
68.12
112.56
147.01
147.01
147.01
126.59
181.45
208 . 23
119.13
107.17
130.19
123.11
142.20
1 52 . 20
154.21
166.22
178.23
'202.26
146.23
2O2.26
O e *-> T^
^T~\Q /*^O
^.^1 1) . iv
252.32
168.32
106.16
54 . 09
140.22
222 . 47
296.60
58.12
86.17
100.20
226.45
142.23
156.32
170.34
136.24
136.24
136.24
136.24
87.18
99.19
114.23
PERCENT
WEIGHT
0
o
o
0
0
0
0
o
o
o
o
o
0
o
o
0
o
o
0
0
0
0
o
o
o
0
o
o
0
0
o
o
o
0
o
0
o
0
o
o
o
0
o
o
o
.66
.04
.40
.71
.40
.72
.02
.42
.01
.01
.12
:03
.37
.18
.04
.02
. 00
. 01 .
. 06
.01
.04
.01
. 00
.01
. 00
.50
.13
.40
.01
.09
. 03
.01
.01
. 03
.01
.02
.02
.01
.01
.01
.01
.05
.01
.01
. 00
B-10
-------
continued (profile=0000)
SAROAD CAS SPECIES MQL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
90070 DIMETHYLOCTANES 140.27 0.03
90072 METHYLPROPYLCYCLOHEXANES 163.32 . 0;01
SUM TOTAL 100.00
B-ll
DATE .-08-12-1988
-------
PROFILE NAMEsExternal Combustion Boilers - Industrial - Average
PROFILE NUMBER:9001
PROFILE DATA QUALITYsE
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles
representing the source category 102XXXXX
SCC : No SCC
SAROAD
NUMBER
43105
43106
43107
43122
43140
43201
43202
43203
43204
43205
43206
43212
43213
43214
43215
43220
43221
43231
43232
43247
43248
43262
43263
43502
43551
45201
45202
45203
CAS
NUMBER
"
74-48-8
74-48-0
74-48-1
74-49-6
79-92-9
540-04-8
106-69-8
106-69-9
75-52-5
115-51-7
109-96-0
78-87-4
110-05-3
142-28-5
108-80-7
43-32-8
96-63-7
591-17-4
50-00-0
67-76-1
71-14-2
108-88-3
100-04-4-
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF PENTANE
C7-C16
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
N-BUTANE
BUTENE
ISO-BUTANE
.ISOBUTYLENE
N-PENTANE
ISO PENTANE
HEXANE
HEPTANE
2 , 4-D I METHYLPENTANE
CYCLOHEXANE
METHYLCYCLOPENTANE
2-METHYL HEXANE
FORMALDEHYDE
ACETONE
BENZENE
TOLUENE
ETHYLBENZENE
MOL.
WEIGHT
86.17
100.20
114.23
72.15
163.32
16.04
30 . 07
28.05
44 . 09
42.08
26 . 04 .
58.12
56.10
58.12
56.10
72.15
72.15
86.17
100.20
100.20
84.16
84.16
100.20
30 . 03
58 . 08
78.11
92.13
106.16
PERCENT
WEIGHT
0 . 89
0.37
0 . 67
2 . 07
5.62
25.34
11.41
1.67
4.19
2.65
2.32
9.24
0.87
1.64
0 . 00 .
1.93
0.18
3 . 37
0 . 04
0 . 00
0. 14
0 . 4 1
0 . 00
15.19
4 . 00
1 . 38
1.48
0.81
B-12
-------
continued (profile=900i)
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45204 95-54-6
90010 108-83-3
0-XYLENE
M-XYLENE AND P-XYLENE
106.16
106.16
0.37
1.68
SUM TOTAL
100.00
B-13
DATE :04-21-1988
-------
PROFILE NAMEsInternal Combustion - Average
PROFILE NUMBER:9002
PROFILE DATA G1UALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting source category 2XXXXXXX.
SCC
No SCC
SAROAD
NUMBER
43105
43106
43107
43108
43109
43120
43122
43124
43125
43201
43202
43203
43204
43205 .
43206
43212
43213
43214
43215
43216
43217
43218
4322'0'
43224
43226
43228
43230
43231
CAS
NUMBER
74-48-8
74-48-0
74-49-1
74-49-6
79-92-9
540-04-8
106-69-8
106-69-9 . '-
75-52-5
115-51-7
624-46-6
590-01-1
10.6-69-0 .
io^-^^o '-
109-96-1
646-60-8
513-33-9
96-61-0
110-05-3
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF BUTENE
ISOMERS OF PENTANE
C9 OLEFINS
CIO OLEFINS
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
- ACETYLENE ' -
N-BUTANE
BUTENE- - - -.--....
ISO-BUTANE
ISOBUTYLENE
T-2-BUTENE
CIS-2-BUTENE
1,.3-BUTADIENE ,
N-PENTANE '"" '""'" " ' ' " '
1-PENTENE
TRANS-2-PENTENE
2-METHYL-2-BUTENE
3-METHYL PENTANE
HEXANE
MOL.
WEIGHT
86.17
100.20
114.23
128.25
142.28
56.10
72.15
127.05
140.27
16.04
30 . 07
28.05
44 . 09
42 . 08
26 . 04
58.12
56.10
58.12
56.10
56.11
56.11
. :. 54 . 09 '
72.15
70.13
70.13
70.13
86.17
86.17
PERCENT
WE I GHT
0.01
0.01
0.01
0 . 00
0.01
0 07
0 ป 03
0.01
0.01
42.47
4.90
14.51
0.73
9 . 07
5.73
0.25
6 . 70
0.11
0.01
0.03
0.01
3 . 50
0 . 03
0 . 00
0 . 00
0 . 00
0.01
0.01
B-14
-------
continued (profile=9002)
SAROAD
NUMBER
43232
43233
43235
43238
43241
43242
43247
43248
43261
43262
43264
43265
43269
43291
43295
43298
43502
43503
43511
45102
45109
45110
45201
45202
45203
45204
45205
45207
45208
45211
45212
45225
9804O
CAS
NUMBER
142-28-5
111-16-9
111-18-2
124-41-5
1120-02-4
287-79-3
108-80-7
43-32-8
108-88-2
96-63-7
111-16-0
124-41-8
75-58-2
589-93-4
96-61-0
50-00-0
75-50-0
78-88-2
71-14-2
108-88-3
100-04-4
95-54-6
108-83-3
108-86-8
95-56-6
611-11-3
620-01-4
526-67-8
763-32-1
SPECIES
NAME
HEPTANE
OCTANE
NONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
2 , 4-D I METHYL-PENT ANE
CYCLOHEXANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
HEPTENE
OCTENE
1-NONENE
2 , 2-D I METHYLBUTANE
3-METHYLHEXANE
3-METHYLHEPTANE
FORMALDEHYDE
ACETALDEHYDE
I SOBUTYRALDEHYDE
ISOMERS OF XYLENE
C3/C4/C5 ALKYLBENZENES
CIO AROMATIC ,
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
1,3, 5-TRIMETHYLBENZENE
1,2, 4-TRIMETHYLBENZENE
0-ETHYLTOLUENE
M-ETHYLTOLUENE
1,2, 3-TR IMETHYLBENZENE
2-METHYL-l-PENTENE
MOL.
WEIGHT
100.20
. 114.23
128.25
142.28
156.31
70.14
100.20
84.16
85.16
84.16
98.18
112.21
127'. 05
86.17
100.20
114.23
30 . 03
44.05
72.11
106.16
134.21
134.22
78 . 11
92.13
106.16
106.16
106.16
120.19
120.19
120.19
120.19
120.19
84.16
SUM TOTAL
PERCENT
WEIGHT
0.01
0.01
0 . 00
0 . 00
0 . 00
0 . 01
0 . 00
0 . 00
0.01
0.01
0 . OO
0 . 00
0 . 00
0 . 00
0 . OO
0.01
7 . 70
0.01
0.01
0.01
"0.00
0 . 00
3 . 98
0.01
0 . 00
0 . 00
0 . 00
0.01
0 . OO
0 . 00
0 . 00
0 . 00
0 . 01
1 00 . 00
B-15
DATE :04-21-1988
-------
PROFILE NAME:Industrial Processes - Average
PROFILE NUMBER:9003
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S): 93 .
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 3XXXXXXX .
SCC : No SCC
3AROAD
NUMBER
43105
43106
43107
43108
43109
43111 .
43113
43115
43116
43117
43118
43120
43121
43122
43130
43131
43132
43133
43134
43201
43202
43203
43204
43205
432O6
43212
43213
43214
CAS
NUMBER
74-48-8
74-48-0
74-48-1
74-49-6
115-50-1
74-48-2
106-69-8
106-69-9
75-52-5
. SPECIES
NAME
ISOMERS OF HEXANE
I30MERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
C-7 CY.CLOPARAFFINS
C-8 CYCLQPARAFFINS
C-9 CYCLOPARAFFINS
MINERAL SPIRITS
ISOMERS OF BUTENE
ISOMERS OF PENTENE
ISOMERS OF PENTANE
C5 SUBSTITUTED CYCLOHEXANE
C6 SUBSTITUTED CYCLOHEXANE
ALIFHATICS
PARAFFINS (C16-C34)
PARAFFINS/OLEFINS (C12-C16)
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
N-BUTANE
BUTENE
ISO-BUTANE
MOL..
WEIGHT
86.17
100.20
114.23
128.25
142.28
170.32
. 198.38
98.19
112.23
126.26
114.00
56.10
70.13
72.15
154.30
170.32
100.00
352.43
197.33
16.04
30 . 07
28.05
44 . 09
42 . 08
26 . 04
58.12
56.10
58.12
PERCENT
WEIGHT
1.11
0 . 39
0.29
0 . 04
0 . 02
0.10
0 . 03
1,87
0.14
0 . 02
0.41
0 . 09
0.01
1.75
0 . 04
0 . 03
0 . 20
0.04
0 . 00
9 . 02
1 . 80
5.94
4.85
2 . 09
1.59
2.49
0.45
0 . 53
B-16
-------
continued (profile=9003
SARQAD
NUMBER
43218
43220
43221
43224
43231
43232
43233
43235
43238
43241
43242
43245
43248
43255
43256
43257
43262
43301
43302
4.3304
43305
43306
43314
43317
43318
43330
43350
43351
43367
43403
43404
43408
43430
43432
43433
43435
43438
43440
43441
43453
43454
43455
43456
43457
43460
CAS
NUMBER
106-69-0
109-96-0
78-87-4
109-96-1
110-05-3
142-28-5
111-16-9
111-18-2
124-41-5
1120-02-4
237-79-3
592-24-6
110-08-7
112-24-3
80-05-8
127-79-3
96-63-7
67-7-5-1
64-41-5
67-76-0 .
71-13-3
78-88-1
78-89-2
108-89-0
104-47-7
123-35-3
115-51-6
60-02-7
64-41-6
64-41-7
57-71-3
107-73-3
79-92-9
141-17-6
138-82-7
140-08-5
141-13-2
80-06-6
108-80-4
112-23-0
124-41-7
112-26-8
109-93-5
SPECIES
NAME
1.,3-BUTADIENE
N-PENTANE
ISO PENTANE
1-PENTENE
HEXANE
HEPTANE
OCTANE
NONANE
N-DECANE
IM-UNDECANE
CYCLOPENTANE
1-HEXENE
CYCLOHEXANE
N-DODECANE
A-PINENE
B-PINENE
METHYLCYCLOPENTANE
METHYL ALCOHOL
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
N-BUTYL ALCOHOL
ISOBUTYL ALCOHOL
S-BUTYL ALCOHOL
CYCLOHEXANOL
2-ETHYL HEXANOL
ISOAMYL ALCOHOL
DIMETHYLETHER
ETHYL ETHER
GLYCOL ETHER
FORMIC ACID
ACETIC ACID
PALMITIC ACID
METHYL FORMATE
METHYLACETATE
ETHYL ACETATE
N-BUTYL ACETATE
ETHYL ACRYLATE
BUTYL ACRYLATE
METHYL METHACRYLATE
VINYL ACETATE
METHYL PALMITATE
METHYL MYRISTATE
METHYL STEARATE
METHYLAL
METHYL Cll ESTER
MOL.
WEIGHT
54 . 09
72.15 .
72.15
70.13
86.17
100.20
114.23
128.25
142.28
156 ..31
70 ..14
34.16
84.16
170.33
136.24
136.24
84.16
' 32 . 04
46 . 07
. . - 60 . 09
74.12
74.12
74.12
100.16
130.23
88.15
46 . 07
74.12
106.12
46 . 03
60 . 05
256.43
60.05
74 . 08
88.10
116.16
100.11
128.17
100. 13
86 . 09
270 . 46
242.41
298.52
76 . 09
314.28
PERCENT
WEIGHT
0.61
1:01
0 . 03
0.04 .
1.14
0.65
0.17
0.05
0 . 09
0 . 08
0.03
0 . 06
0 . 77
0.19
0 . 53
0.35
0 . 52
1..95
1.12
0.41
0.75
0 . 00
1.01
0.10
0 . 00
0 . 00
2.82
0 . 38
0 . 03
0.07
0 . 98
0 . 40
0.66
0 . 92
0 . 00
0.04
0 . 36
0.15
0 . 29
1.64
0.17
0 . 06
0 . 22
0.25
0 . 00
B-17
-------
continued (prof ile=9003)
SAROAD
NUMBER
43461
43462
43463
43464
43465
43466
43467
43470
43502
43503
43505
43510
43520
43551
43552
43560
43561
43601
'43602
43603
43604
43650
43704
43776
43780
43801
43803
43804
43805
43811
43812
438.15
43821
43822
43823
43838
43839
43840
43841
43842
43843
43844
43845
43860
43862
CAS
NUMBER
111-18-0
50-00-0
75-50rO
107-70-8
123-37-8
67-76-1
78-89-3
108-81-1
108-89-1
75-52-8
75-55-9
108-83-6
108-82-7
107-71-1
124-40-4
74-48-3
67-76-3
56-62-5
74-49-3
75-56-4
75-5O-3
107-70-2
76-61-1
75-57-8
26638-81-7
75-57-0
75-54-6
76-61-2
76-61-3
76-61-4
75-54-7
75-57-9
75-50-4
126-69-8
SPECIES
NAME
METHYL C12 ESTER
METHYL C13 ESTER
METHYL C14 ESTER
METHYL C15 ESTER
METHYL C19 ESTER
METHYL C20 ESTER
C4 SUBSTITUTED CYCLOHEXANONE
METHYL DODECANOATE
FORMALDEHYDE
ACETALDEHYDE
ACROLEIN
BUTYRALDEHYDE
TOTAL C2-C5 ALDEHYDES
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
CYCLOHEXANONE
ETHYLENE OXIDE
PROPYLENE OXIDE
MALE 1C ANHYDRIDE
ACETIC ANHYDRIDE
OXYGENATES
ACRYLONITRILE
HEX AMETH YLENED I AM I NE
DIMETHYL ALKYL AMINES
METHYL CHLORIDE
CHLOROFORM
CARBON TETRACHLORIDE
METHYLENE BROMIDE
TRICHLOROFLUOROMETHANE
ETHYL CHLORIDE
ETHYLENE D I CHLORIDE
TR I CHLOROTR I FLUOROETHANE
TR I METH YLFLUOROS I LANE
D I CHLOROD I FLUOROMETHANE
PROPYLENE D I CHLORIDE
TETRAFLUOROMETHANE
CHLOROD I FLUOROMETHANE
DICHLOROTETRAFLUORETHANE
CHLORQPENTAFLUOROETHANE
HEXAFLUOROETHANE
TRIFLUOROMETHANE
CHLOROTR I FLUOROMETHANE
VINYL CHLORIDE
CHLOROPRENE
MOL.
WEIGHT
338 . 56
362.58
386 . 60
410.62
506 . 68
530 . 70
154.26
214.35
30 . 03
44.05
56 . 07
72.12
72.12
58 . 08
72 . 10
100.16
98.15
44.05
58 . 08
98 . 06
102.09
86 . 00
53.06
11 6. 2O
59.11
50 . 49
119.39
1 53 . 34
173.85
137.38
64.52
99 . 00
187.38
92 . 00
120.91
112.99
88.01
86.47
170.92
154.47
138.01
70. Ol
104.46
62 . 50
98.54
PERCENT
WEIGHT
0 . 00
0 . 00
0 . 00
0 . 00
0.00
0 . 00
0 . 02
0 . 00
1.82
1.24
1 . 20
0 . 0 1
0 . 24
1.82
1.27
0.17
0.10
0.05
0.01
0 . 20
.0 .06
0.01
0 . 64
1.01
0 . 00
0 .01
0 . 03
0 . 20
0.10
0.77
0.85
1.68
0 . 06
1.75
1 . 06
0 . 06
0.10
0.48
0 . 04
0.05
1 . 20
0.91
0.16
1 . 07
1 . 01
B-18
-------
continued (profile=9003
SAROAD
NUMBER
43933
43934
43950
43951
45102
45106
45107
45109
45201
45202
45203
45204
45205
45206
45210
45220
45226
45227
45228
45229.
4523.0
45232
45233
45300
45310
45311
45401
454O2
45403
45450
45451
45452
45454
45455
45470
45501
45601
45604
45701
45702
45703
45704
45705
45730
45740
CAS
NUMBER
433-35-1
75-51-0
556-66-2
1330-02-7
25551-11-7
71-14-2
103-88-3
100-04-4
95-54-6
108-83-3
106-64-3
98-88-8
100-04-5
92-25-4
1321-17-0
103-32-7
108-89-2 .
65-58-0
100-02-0
120-06-6
131-11-3 ,
34-47-2
131-11-8
136-66-7
100-05-7
85-54-9
98-80-0
62-25-3
98-89-3
1817-77-8
101-16-8
SPECIES
NAME
CARBONYL SULFIDE
CARBON SULFIDE
OCTAMETHYLCYCLOTETRASILOXANE
S.ILQXANE
ISOMERS OF XYLENE
ISOMERS OF DIETHYLBENZENE
TR I METHYL-BENZENE
C3/C4/C5 ALKYLBENZENES
BENZENE
TOLUENE
ETHYLBENZENE
0- XYLENE
M-XYLENE
P-XYLENE
CUMENE (ISOPROPYL BENZENE)
STYRENE
BIPHENYL-
METHYL BIPHENYL
ETHYL STYRENE
DI VINYL BENZENE
DI (ETHYLPHENYL) ETHANE
DIPHENYL ETHANE
ETHYL-PHENYL-PHENYL-ETHANE
PHENOL
C8 PHENOLS
C9 PHENOLS
XYLENE BASE ACIDS
BENZOIC ACID
TEREPHTHALIC ACID
DIMETHYL TEREPHTHALATE
DIMETHYL PHTHALATE
D I BUTYL PHTHALATE
DIPROPYL PHTHALATE
BUTYL BENZOATE
DI-C8 ALKYL PHTHALATE
BENZALDEHYDE
PHTHALIC ANHYDRIDE
FURFURYL ALCOHOL
ANILINE
NITROBENZENE
2,2 DICHLORONITROANILINE
BROMOD I N I TROAN I L I NE
BROMODINITROBENZENE
METHYLENE ( b ) 4-PHENYL I SOCYANATE
TOTAL AROMATIC AMINES
MOL.
WEIGHT
60 . 08
76.14
296.62
76 . 08
106.16
134.21
120.19
134.21
78.11
92.13
106.. 16
106.16
106.16
106.16
120.20
104.14
154.21
168.24
132.21
130.02
210.32
182.27
210.32
94.11
122.16
136.19
230 . 00
122.13
166.14
194.19
194.19
273.35
250.30
178.23
300 . 53
106.13
148.00
98.10
93.13
123.11
207 . 02
262 . 03
247 . 02
250.27
93.13
PERCENT
WEIGHT
0 . 09
0 . 27
0 . 02
0 . 01
0.18
0 . 04
0 . 09
0 . 06
7.05
1 .49
0 . 43
0. 16
0 . 07
0 . 03
0 . 00
3.01
0 . 03
0 . 00
0 . 06
0.01
0 . 00
0.01
0 . 02
1 . 09
0 . 00
0 . 00
0 . 0 1
0.12
0.01
0 . 00
0.12
0 . 0 1
0 . 00
.0.43
0.01
0.05
0.61
0 . 00
0 . 72
0 . 00
0 . 04
0 . 00
0 . 02
0 . 00
0 . 07
B-19
-------
continued (profile=9003)
SAROAD CAS
NUMBER NUMBER
45801
45805
45806
45807
45808
45830
45831
46102
46103
46111
46112
46114
46701
46702
46703
46711
90050
90051
90052
90053
98063
98083
99933
99999
108-89- 7
95-55-1
541-17-1
106-64-7
2531-12-6
84-46-1
82-24-1
101-17-9
103-37-9
100-O6-8
91-12-3
288O4-48-8
5794-40-6
123-33-3
5989-92-5
SPECIES
NAME
CHLOROBENZENE
0-DICHLOROBENZENE
M-DICHLOROBENZENE
P-D I CHLOROBENZENE
DICHLOROBENZENES
TRICHLOROBENZENES
TETRACHLOROBENZENES
ANTHRAQUINONE
AM I NOANTHRAQU I NONE
4,4-METHYLENE DIANILI-NE
F'HENYL ISOCYANATE
4-METHYLANIL.INE
NAPTHALENE
METHYL NAPHTHALENES
DIMETHYL NAPTHALENE
C2 ALKYL INDAN
CAMPHENE
MYRCENE .
B-PHELLANDRENE
D-LIMONENE
N-PENTYLCYCLOHEXANE
TRIMETHYLDECENE
DENATURANT
UNIDENTIFIED
MOL
WEIGHT
112
147
147
147
147
181
215
208
223
193
119
107
123
142
156
. 146
136
136
136
136
154
182
"T'T*
36.
.56
.01 .
.01
.01
.01
.45
.90
~>"T
.23
.17
. 13
.17
.11
.20
.23
.23
.24
.24
.24
.24
.30
.35
04
00
SUM TOTAL
PERCENT
WEIGHT
2.01
0 . 1 0
0 . 0 1
2.15
0.06
0 . 03
0 . 00
0 . 03
0 . 00
0 . 00
0.24
0 . 06
0 . 09
0.11
0.01
0.11
0.01
0 . 02
0.02
0.08
0 . 02
0 . 06
0 . 29
0 . 20
100.00
B-20
DATE :08-10-1988
-------
PROFILE NAME:Chemical Manufacturing - Average
PROFILE NUMBER:9004
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 301XXXXX
SCC : No SCC
SAROAI
NUMBEF
43105
43115
43116
43118
43120
43122
43201
43202
43203
43204
43205
43206
43212
43213
43214
43220
43221
43224
43231
43245
43248
43262
43301
43302
43304
433O5
43314
43317
) CAS
* NUMBER
74-48-8
74-48-0
74-48-1
74-49-6
115-50-1
74-48-2
106-69-8
106-69-9
75-52-5
109-96-0
78-87-4
109-96-1
110-05-3
592-24-6
110-08-7
96-63-7
67-75-1
64-41-5
67-76-0
71-13-3
73-89-2
108-89-0
SPECIES
NAME
ISOMERS OF HEXANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
MINERAL SPIRITS
ISOMERS OF BUTENE
ISOMERS OF PENTANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
N-BUTANE
BUTENE
ISO-BUTANE
N-PENTANE
ISO PENTANE
1-PENTENE
HEXANE
i-HEXENE
CYCLOHEXANE
METHYLCYCLOPENTANE
METHYL ALCOHOL
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
N-BUTYL ALCOHOL
S-BUTYL' ALCOHOL
CYCLOHEXANOL
MOL
WEI
86.
98.
112
114
56.
72.
16.
30 .
28.
44.
42.
26.
58.
56.
58.
72.
72.
70.
86.
34.
34.
84.
32.
46.
6O.
74.
74.
100
BHT
17
19
.23
.00
10
15
04
07
05
09
08
04
12
10
12
15
15
13
17
16
16
16
04
07
09
12
12
. 16
PERCENT
WEIGHT
0.12
1.75
0 . 03
0.61
0.13
0.'05
5 . 07
.1 . 38
8.29
3.45
2.67
2.14
1 . 34
0 . 37
0 . 07
0.24
0.05
0 . 02
0 . 06
0 . 08
0 . 86
0 . 00
2.92
o.i a
0.61
1.12
1.52
0.16
B-21
-------
continued ( prof i.le=9004 )
SAROAD
NUMBER
43350
43351
43367
43403
43404
43430
43432
43435
43438
43440
43441
43453
43457
43502
43503
43505
43510
43551
43552
43560
43561
43601
43602
43603
43604
43704
43776
43801
43803
43804
43805
43811.
43812.
43815
43821
43823
43838
43839
43840
43841
43842
43843
43844
43345
43860
CAS
NUMBER
115-51-6
60-02-7
64-41-6
64-41-7
107-73-3
79-92-9
138-82-7
140-08-5
141-13-2
80-06-6
1.08-80-4
109-93-5
50-00-0
75-50-0
107-70-8
123-37-8
67-76-1
78-89-3
108-81-1
108-89-1
75-52-8
75-55-9
108-83-6
108-82-7
107-71-1
124-40-4
74-48-3
67-76-3
56-62-5
74-49-3
75-56-4
75-50-3
107-70-2
76-61-1
75-57-8
26638-81-7
75-57-0
75-54-6
76-61-2
76-61-3
76-61-4
75-54-7
75-57-9
75-50-4
SPECIES
NAME
DIMETHYLETHER
ETHYL ETHER
GLYCOL ETHER
FORMIC ACID
ACETIC ACID
METHYL FORMATE
METHYLACETATE
N-BUTYL ACETATE
ETHYL ACRYLATE
BUTYL ACRYLATE
METHYL METHACRYLATE .
VINYL ACETATE
METHYLAL
FORMALDEHYDE
ACETALDEHYDE
ACROLEIN
BUTYRALDEHYDE
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL .KETQNE
CYCLOHEXANONE
ETHYLENE OXIDE
PROPYLENE OXIDE
MALEIC ANHYDRIDE
ACETIC ANHYDRIDE
ACRYLONITRILE
HEXAMETHYLENEDIAMINE
METHYL CHLORIDE
CHLOROFORM
CARBON TETRACHLORIDE
METHYLENE BROMIDE
TRICHLOROFLUOROMETHANE
ETHYL CHLORIDE
ETHYLENE D I CHLORIDE
TR I CHLOROTR I FLUOROETHANE
D I CHLOROD I FLUOROMETHANE
PROPYLENE D I CHLORIDE
TETRAFLUOROMETHANE
CHLOROD I FLUOROMETHANE
D I CHLOROTETRAFLUORETHANE
CHLOROPENTAFLUOROETHANE
HEXAFLUOROETHANE
TR I FLUOROMETHANE
CHLOROTR I FLUOROMETHANE
VINYL CHLORIDE
MOL.
WEIGHT
46 . 07
74.12
106.12
46 . 03
60.05
60.05
74 . 08
116.16
100,11
128.17
100.13
86 . 09
76 . 09
30 . 03
. 44.05
56 . 07
72 ..12
58 . 08
72.10
100.16 .
98.15
44,05
58 . 08
98 . 06
102.09
53 . 06
116.20
50 . 49
119.39
153.84
173.85
137.38
64.52
99 . 00
187.38
120.91
112'. 99
38.01
36 . 47
170.92
154.47
138.01
70.01
104.46
62 . 50
PERCENT
WEIGHT
4.22
0.57
0.05
0.10 .
1.47
0 . 99
1.38
0 . 06
0 . 54
0 . 22
0 . 43
2.46
0 . 38
0 . 03
1.86
1.79
0.01
2.31
1.91
0.25
0.16
0 . 07
0 . 02
0 . 30
0 . 09
0.95
1.52
0.01
0 . 04
0 . 30
0.15
1.15
1.28
2.52
0 . 09
1.59
0 . 08
0.15
0..72
0 . 07
0 . 07
1 . 80
1.36
0 . 24
1.61
B-22
-------
continued (profile=9004)
SARO'AD
NUMBER
43862
43933
43934
45102
45106
45201
45202
45203
.45204
45206
45210
45220
45300
45401
45402
45403
45450
45501
45601
45702
45801
45805
45806
45807
45808
99933
99999
CAS
NUMBER
126-69-8
433-35-1
75-51-0
1330-02-7
71-14-2
108-88-3
100-04-4
95-54-6
106-64-3
98-88-8
100-04-5
108-89-2'
65-58-0
100-02-0
120-06-6
100-05-7
85-54-9.
98-89-3
108-89-7
95-55-1
541-17-1
106-64-7
2531-12-6
SPECIES
NAME
CHLOROPRENE
CARBONYL SULFIDE
CARBON SULFIDE
ISOMERS OF XYLENE
ISOMERS OF DIETHYLBENZENE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
P-XYLENE
CUMENE (ISOPROPYL BENZENE)
STYRENE
PHENOL
XYLENE BASE ACIDS
BENZOIC ACID
TEREPHTHALIC ACID
DIMETHYL TEREPHTHALATE
BENZALDEHYDE
PHTHALIC ANHYDRIDE
.NITROBENZENE -.- . .
CHLOROBENZENE
0-DICHLOROBENZEME
M-DI CHLOROBENZENE
P-D I CHLOROBENZENE
DICHLOROBENZENES
DENATURANT
UNIDENTIFIED
MOL.
WEIGHT
88.54
60 . 08 .
76.14
106.16
134.21
78.11
92.13
106.16
106.16
106.16
120 . 20
104.14
94.11
230 . 00
122.13
166.14
194.19
106.13
148.00
123.11-
112.56
147.01
147.01
147.01
147.01
32 . 04
86 . 00
SUM TOTAL
PERCENT
WEIGHT
1.52
0: 13
0.40
0.25
0.05
8.49
1 . 80
0.65
0.16
0.05
0 . 00
3. .91.
1.55
0 . 02
0.15
0 . 02
0 . 00
0 . 07
0.91
0.00
3 . 02
0.16.
0.01
T --V-\
..' jLji.
0 . 09
0 . 44
0 . 29
100.00
B-23
DATE :08-10-1988
-------
PROFILE NAME:Plastics Production - Average
PROFILE NUMBER: 900 5
PROFILE DATA QUALITYsE
CONTROL DEVICE:Not Applicable
REFERENCE(S) : 93
DATA SOURCE: Average profile developed from original profiles repre
senting the source category 301018XX
SCC
No SCC
SAROAD CAS
NUMBER NUMBER
43205 79-92-9
43704 107-71-1
43860 75-50-4
45203 100-04-4
45220 100-04-5
SPECIES
NAME
PROPENE
ACRYLONITRILE
VINYL CHLORIDE
ETHYLBENZENE
STYRENE
MOL.
WEIGHT
42 . 08 .
53.06
62 .50
106.16
104.14
PERCENT
WEI6HT
20 . 00
12.00
20 . 00
2 . 00
46 . 00
SUM TOTAL
100.00
DATE :04-21-1988
B-24
-------
PROFILE NAME:Synthetic Organic Fiber Production - Average
PROFILE NUMBER:9006
PROFILE DATA QUALITYsE
CONTROL DEVICErNot Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 301024XX
SCC : No SCC
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43776 124-40-4
HE XAMETHYLENEDIAMINE
116.20
SUM TOTAL
100.00
100.00
DATE :04-21-1988
B-25
-------
PROFILE NAME:Alcohols Production - Average
PROFILE NUMBER:9007
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 301250XX
SCC : No SCC
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43201 74-48-8 METHANE 16.04 43.35
43301 67-75-1 METHYL ALCOHOL 32.04 1.64
43350 115-51-6 DIMETHYLETHER 46.07 55.01
SUM TOTAL 100.00
B-26
DATE :04-21-1988
-------
PROFILE NAMEsFood and Agriculture - Average
PROF ILE NUMBER:9008
PROFILE DATA QUALlTYsE
CONTROL DEVICE;Not Applicable
REFERENCE(S) s 93
DATA SOURCEsAverage profile developed from original profiles repre
senting the source category 302XXXXX.
;- * % .-'
oLL
No SCC
SAROAD CAS
NUMBER NUMBER
43302 64-41-5
43306 78-88-1
43330 123-35-3
43433 141-17-6
SPECIES
NAME
ETHYL ALCOHOL
ISOBUTYL ALCOHOL
ISOAMYL ALCOHOL
ETHYL ACETATE
MOL .
WEIGHT
46 . 07
74.12
88,15
88.10
PERCENT
WEIGHT
99 . 56
0 03
0 . 09
0 . 32
SUM TOTAL
100.00
DATE 205-02-1988
B-27
-------
PROFILE NAME:Primary Metal Production - Average
PROFILE NUMBER:9009
PROFILE DATA QUALITY.-E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCES Average profile developed from original profiles repre-
senting the source category 303XXXXX
SCC : No SCC
SAROAI
NUMBER
43201
43202
43203
43204
43205
43206
43213
43218
43231
43232
43822
45201
45202
) CAS
* NUMBER
74-48-8
74-48-0
74-48-1
74-49-6
79-92-9
540-04-8
106-69-9
106-69-0.
110-05-3
142-28-5
71-14-2
108-88-3
SPECIES
NAME
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
BUTENE
1,3-BUTADIENE
HEXANE
HEPTANE
TR I METHYLFLUOROS I LANE
BENZENE
TOLUENE
MOL.
WEIGHT
16.04
30 . 07
28.05
44 . 09
42 . 08
26 . 04
56.10
54 . 09
86.17
100.20
92 . 00
78.11
92.13
SUM TOTAL
PERCENT
WE I GHT
29.10
2 . 20
6.72
8 . 08
0 . 98
3 . 20
0 . 02
0.10
1 . 40
7.16
34.64
5.54
0 . 86
100.00
B-28
DATE :O4-21-1988
-------
PROFILE NAME:Secondary Metal Production - Average
PROFILE NUMBER:9010
PROFILE DATA QUALITYsE
CONTROL DEVICErNot Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 304XXXXX
SCC
No SCC
SAROAD
NUMBER
43502
43505
43520
45201
45202
45204
45205
45300
45604
45701
45740
46110
46111
46112
46114
46701
CAS
NUMBER
50-00-0
107-70-8
71-14-2
108-88-3
95-54-6
108-83-3
108-89-2
98-80-0
62-25-3
101-16-8
101-17-9
103-37-9
100-06-8
91-12-3
SPECIES
NAME
FORMALDEHYDE
ACROLEIN
TOTAL C2-C5 ALDEHYDES
BENZENE
TOLUENE
0-XYLENE
M^-XYLENE
PHENOL
FURFURYL ALCOHOL
ANILINE
TOTAL AROMATIC AMINES
METHYLENEBIS(C6H4NCO)
4,4-METHYLENE DI ANILINE
PHENYL ISOCYANATE
4-METHYLANILINE
NAPTHALENE
MOL.
WEIGHT
30 . 03
56 . 07
72.12
78.11
92.13
106.16
106.16
94.11
98.10
93.13
93.13
.250.27
198.17
. 119.13
107.17
123.11
SUM TOTAL
PERCENT
WEIGHT
0.35
0.17
12.10
17.35
7.05
2.75
3.25
3 . 20
0 . 04
35.42
3.71
0.01
0 . 00
1 1 . 80
2.75
0 . 04
100.00
DATE :04-21-1988
B-29 .
-------
PROFILE NAMEsMineral Products - Average
PROFILE NUMBER:9011
PROFILE DATA .QUALITY:E
CONTROL DEVICEsNot Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 305XXXXX
SCC
No SCC
SAROAD
NUMBER
43105
43106
43107
43111
43113
43115
43116
43117
43121
43122
43130
43131
43201
43202
43203
43204
43205
43212
43213
43214
43220
43224,
4323 i
43232
43233
43238
43241
43242
CAS
NUMBER
74-48-8
74-48r-0 .
74-48-1
74-49-6
79_.92-.9 .
106-69-8
106-69-9
75-52-5
109-96-0
109-96-1 . . .
110-05-3
142-28-5
111^-16-9 ,
124-41-5
1120-02-4
287-79-3
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
ISOMERS OF PENTENE
ISOMERS OF PENTANE
C5 SUBSTITUTED CYCLOHEXANE
C6 SUBSTITUTED CYCLOHEXANE
METHANE
ETHANE -
ETHYLENE
PROPANE
PROPENE -
N-BUTANE
BUTENE . .
ISO-BUTANE
N-PENTANE
. IrPENTENE
'HEXANE '
HEPTANE
OCTANE ..-,.- .
N-DECANE
N-UNDECANE
CYCLOPENTANE
MOL.
WEIGHT
86.17
100.20
114.23
170.32
198.38
98.19
112.23
126.26
70.13
72.15
1 54 . 30
170.32
16.04
30 . 07
28.05
44 . 09
42.08
58.12
56.10
58.12
72.15
> 70.13
86.17
100.20
114.23
142.28
156.31
70.14
PERCENT
WEIGHT
4 . 9O
2 . 20
1.68
1.92
0 . 62
1.32
0 . 08
0 . 30
0.10
3.16
0.83
0 . 62
18.60
2 . 20
0 . 86
6.54
1.18
9.74
2.58
3.98
7.12
0.64
3.14
3.20.
0.54
0 . 57
1.56
0 . 50
B-30
-------
continued (profile=9011)
SARQAD CAS
NUMBER NUMBER
43248 43-32-8
43255 112-24-3
43467
43502 50-00-0
45107 25551-11-7
45201 71-14-2
45202 108-88-3
45703
46701 91-12-3
46702
46711
98063
98083
SPECIES
NAME
CYCLOHEXANE
N-DODECANE
C4 SUBSTITUTED CYCLOHEXANONE
FORMALDEHYDE
TR I METHYLBENZENE
BENZENE
TOLUENE
2,2 DICHLORONITRO ANILINE
NAPTHALENE
METHYL NAPHTHALENES
C2 ALKYL INDAN
N-PENTYLCYCLOHEXANE
TRIMETHYLDECENE
MOL.
WEIGHT
84.16
170.33
154.26
30.03
120.19
78.11
92.13
207 . 02
123.11
142.20
146.23
154.30
182.35
PERCENT
WEIGHT
0 . 20
3.71
0 . 48
1 . 60
1.78
2.86
0 . 78
0 . 79
1.31
2 . 04
2.24
0.41
1.12
SUM TOTAL 100.00
B-31
DATE :04-21-1988
-------
PROFILE NAME:Petroleum Industry - Average
PROFILE NUMBER:9012
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 306XXXXX
SCC
No SCC
SAROAD
NUMBER
43105
43106
43107
43108
43109
43115
43116
43117
43122
43201
43202
43204
43205
43212
43213
43214
43220
43231
43232
43233
43235
43238
43248
43502
45102
45201
45202
CAS
NUMBER
74-48-8
74-48-0
74-49-6
79-92-9
106-69-8
106-69-9
75-52-5
109-96-0 .
110-05-3
142-28-5
lil-rl6-9
111-18-2
124-41-5 . .
43-32-8'
50-00-0
71-14-2
108-88-3
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
C-7 CYCLOF'ARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
PROPENE
N-BUTANE
BUTENE
ISO-BUTANE
N-PENTANE
HEXANE
.HEPTANE
OCTANE
NONANE
. N-DECANE . .
CYCLOHEXANE
FORMALDEHYDE
. . I30MERS OF XYLENE . .
BENZENE
TOLUENE
MOL.
WEIGHT
86.17
100.20
114.23
128.25
142.28
98.19
112.23
126.26
72.15
16.04
30 . 07
44 . 09
42 . 08
' 58.12
56.10
58.12
. 72.15
86.17
100.20
114.23
128.25
142.28
84.16
30 . 03
. . 106.16
78.11
92.13
SUM TOTAL
PERCENT
WEIGHT
4.16
0 . 63
0 . 40
0.45
0 . 28
2.27
0 . 66
0.11
16.64
13.01
6.05
19.69
1.75
7.99
0 . 1 5
2.89
4.80
3.86
1.24
1.73
0 . 56
0.74
0.08 -
8.88
0.19
0.38
0 . 44
100.00
DATE :04-21-1988
B-32
-------
PROFILE NAMEsPulp and Paper Industry - Average
PROFILE NUMBER:9013
PROFILE DATA QUALITYsE
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 307XXXXX
SCC s No SCC
SAROAD CAS
NUMBER NUMBER
43204 74-49-6
43256 80-05-8
43257 127-79-3
90050 5794-40-6
90051 123-33-3
90052
90053 5989-92-5
SPECIES
NAME
PROPANE
A-PINENE
B-PINENE
CAMPHENE
MYRCENE
B-PHELLANDRENE
D-LIMONENE
MOL.
WEIC3HT
44 . 09
136.24
136.24
136.24
136.24
136.24
136.24
PERCENT
WEIGHT
0 . 03
52.71
34.44
1.27
1.87
1 . 69 '
7.99
SUM TOTAL
100.00
DATE :04-21-1988
B-33
-------
PROFILE NAMEsRubber and Miscellaneous Plastics Products - Avg
PROFILE NUMBER:9014
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 308XXXXX
sec
No SCC
SAROAD
NUMBER
43105
43106
43107
43115
43116
43218
43231
43232
43233
43242
43248
43262
45201
45202
45220
CAS
NUMBER
106-69-0
110-05-3
142-28-5
111-16-9
287-79-3
43-32-8
96-63-7
71-14-2
108-88-3
100-04-5
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
C-7 CYCLOP ARAFF INS
C-8 CYCLOPARAFFINS
1,3-BUTADIENE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
CYCLOHEXANE
METHYLCYCLOPENTANE
BENZENE
TOLUENE
STYRENE
MOL.
WEIGHT
86.17
100.20
114.23
98.19
112.23
54.09
86.17
100.20
114.23
70.14
84.16
84.16
78.11
92.13
104.14
SUM, -TOTAL
PERCENT
WEIGHT
8 . 07
1.63
0 . 27
14.40
2 . 00
20 . 00
13.13
0 . 63
0.13
0 . 07
5.57
17.13
3 . 50
0.13
13.33
100.00
DATE : 04-21-1988
B-34
-------
PROFILE NAME:Oil and Gas Production- - Average
PROFILE NUMBER 59015
PROFILE DATA QUALITYsE
CONTROL DEVICEsNot Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 310XXXXX
SCC
No SCC
SAROAD CAS
NUMBER NUMBER
43105
43106
43107
43115
43116
43122
43201 74-48-8
43202 74-48-0
43204 74-49-6
43212 106-69-8
43214 75-52-5
45201 71-14-2
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
BENZENE
MOL.
WEIGHT
86.17
100.20
114.23
98.19
112.23
72.15
16.04
30.07
44 . 09
58.12 .
58.12
78.11
PERCENT
WEIGHT
6.64
7.79
5.79
1.10
0.40
3.20
53.80
7.44
8.24
5.24
0.25 "
0.10
SUM TOTAL
100.00
DATE :04-21-1988
B-35
-------
PROFILE NAME:Textile Products - Average
PROFILE NUMBERS 9016
PROFILE DATA QUALITYsE
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 330XXXXX
SCC : No SCC
SAROAD
NUMBER
43132
43133
43134.
43318
43408
43454
43455
43456
43460
43461
43462
43463
43464
43465
43466 '
43470
43650
43780
43950
43951
"45109
45226
45227'
45228
45229 .
45230
45232
45233
CAS
NUMBER
104-47-7
57-71-3
112-23-0
124-41-7
112-26-8
111-18-0
556 66 i
92-25-4
1321-17-0.
103-32-7
SPECIES
NAME
ALIPHATICS
PARAFFINS (C16-C34)
PARAFFINS/OLEFINS (C12-C16)
2-ETHYL HEXANOL
PALMITIC ACID
METHYL PALM IT ATE
METHYL MYRISTATE
METHYL STEARATE
METHYL Cll ESTER
METHYL C12 ESTER
METHYL C13 ESTER
METHYL C14 ESTER
METHYL C15 ESTER
METHYL C19 ESTER . - .
METHYL C20 ESTER -
METHYL DODECANOATE
OXYGENATES -
'DIMETHYL ALKYL AMINES
. OCTAMETHYLCYCLOTETRASILOXANE
SILOXANE ' .
' C3/C4/C5 ALKYLBENZENES
BIPHENYL ;.;' " - ' " ' .' '-
' METHYL BIPHENYL . ' ' '
ETHYL STYRENE
. , D1VINYL BENZENE .... ... .
DI(ETHYLPHENYL) ETHANE
DIPHENYL ETHANE
ETHYL-PHENYL-PHENYL-ETHANE
MOL .
WEIGHT
14.03
352 . 43
197.38
130.23
256.43
270 . 46
242.41
298.52
314.28
- 338 . 56
362 . 58
386 . 60
410.62
506 . 63
530 . 70
214.35
86 . 00
59.11
296,62
76 . 08
134.21
' 154.21
"168.24
132.21
130.02
210.32
182.27
210.32
PERCENT
WEIGHT
9.96
1.81
0 . 04
0 . 20
19.77
8.26
3 . 08
10.66
0 . 00
0.01
0 . 00
0 . 04
0 . 02
0.01
0 . 00
0.01
0 . 27
0.2.1
1 . 06
0 . 58
2.78
1 . 30
0 . 09
2.97
0 . 32
0 . 00
0.71
1.22
B-36
-------
continued (profile=9016)
SAROAD CAS
NUMBER NUMBER-
ASS 10
45311
45402
45451
45452
45454
45455
45470
45703
45704
45705
45808
45830
45831
46102
46103
46701
46702
46703
99999
65-58-0
131-11-3
84-47-2
131-11-8
136-66-7
1817-77-8
84-46-1
91-12-3
28804-48-B
SPECIES
NAME
C8 PHENOLS
C9 PHENOLS
BENZOIC ACID
DIMETHYL PHTHALATE
D I BUTYL PHTHALATE
DIPROPYL PHTHALATE
BUTYL BENZOATE
DI-C8 ALKYL PHTHALATE
2,2 DICHLORON I TRQ ANILINE
BROMOD I N I TROAN AL I NE
BROMODI NITROBENZENE
DICHLOROBENZENES
TR I CHLOROBENZ ENES
TETRACHLORQBENZENES
ANTHRAQUINONE
AMINOANTHRAQUINONE
NAPTHALENE
METHYL NAPHTHALENES
DIMETHYL NAPTHALENE
UNIDENTIFIED
MOL.
PERCENT
WEIGHT
122.
136.
. 122.
194.
278.
250.
178.
300 .
207 .
262.
247.
147..
181.
215.
208 .
223.
123.
142.
156.
16
19
13
19
35
30
23
53
02
03
02
01
45
90
23
23
11
20
23
86 . 00
SUM TOTAL
WEIGHT
0
0
0
5
0
0
*-\
j^.
0
o
0
1
o
1
0
1
0
1
0
0
o
. 03
.13
.87
. 73
. 40
.01
1.06
.31
.11
.01
.08
. 06 .
.45
.07
. 30
. 02
. 00
.22
.27
.43
100.00
B-37
DATE :04-21-1988
-------
PROFILE NAME:Drycleaning/Degreasing - Average
PROFILE NUMBER:9017
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not .Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 401XXXXX.
SCC
No SCC
SAROAD
NUMBER
43109
43110
43111
43112
43113
43124
43125
43135
43136'
43138
43141
43146
43147
43148
43150
43151
43152
43153
43231
43232
43235
43248
43261
43288
43301
43302
43314
43336
CAS
NUMBER
110-05-3
142-28-5
111-13-2
110-08-7
108-88-2
1678-89-7
67-75-1
64-41-5
78-89-2
SPECIES
NAME
ISOMERS OF DECANE
ISOMERS OF UNDECANE
ISOMERS OF DODECANE
ISOMERS OF TR I DECANE
ISOMERS OF TETRADECANE
C9 OLEFINS
CIO OLEFINS
CIO PARAFFINS
C9 PARAFFIN
C-8 OLEFINS
C8 PARAFFIN
Cll OLEFINS
C12 OLEFINS
ISOMERS OF C9H16
ISOMERS OF C10H18
ISOMERS OF C11H20
C12H22
C10H16
HEXANE
HEPTANE
NONANE
CYCLOHEXANE
METHYLCYCLOHEXANE
ETHYLCYCLOHEXANE
METHYL ALCOHOL
ETHYL ALCOHOL
3-BUTYL ALCOHOL
OCTANOL
MOL.
WEIGHT
142.28
156.30
170.32
184.36
198.38
127.05
140.27
142.28
; 128.25
.112.23
114.23
154.29
168.32
124.23
138.25
152.28
166.31
136.24-
86.17
10O.20
128.25
84.16
98.21
112.23
32 . 04
46 . 07
74.12
130.26
PERCENT
WEIGHT
1.36
'0.95
0.18
0.01
0.01
0 . 00
0.29
0 . 06
0 . 00
0.09
0 . 00
0.11
0 . 02
0 . 04
0.01
0 . 02
0 . 00
0.01
0 . 0 1
2.57
0.85
0.01
0 . 56
0 . 07
7.14
2.14
0 . 0 5
0.01
B-38
-------
continued (prof ile=9017)
SAROAE
NUMBER
43351
43397
43551
43552
43565
43566
43567
43802
43811
43814
43817
43820
43821
43824
45102
45105
45107
45108
45113
45201
45202
45203
45204
45209
45210
45215
45238
45245
453O3
45304
45320
45801
45808
46202
46601
46602
46701
46747
46748
46753
90010
90028
90029
90045
90047
) CAS
* NUMBER
60-02-7
67-76-1
78-89-3
75-50-2
75-56-4
71-15-6
127-71-4
79-90-5
76-61-1
79-90-6
1330-02-7
25551-11-7
71-14-2
108-88-3 .
100-04-4
95-54-6
103-36-1
98-88-8
98-80-6
108-89-7
2531-12-6
2782-29-4
95-51-9
91-12-3
91-11-8
SPECIES
NAME
ETHYL ETHER
TRIMETHYLCYCLOHEXANOL
ACETONE
METHYL ETHYL KETONE
DIMETHYLCYCLOBUTANONE
TR I METHYLC YCLOPENTANONE
TETRAMETHYLPENTANONE
DICHLOROMETHANE
TR I CHLOROFLUOROMETHANE
1 , 1 , 1-TRICHLOROETHANE
PERCHLOROETHYLENE
1,1, 2-TRICHLQRQETHANE
TR I CHLOROTR I FLUOROETHANE
TR I CHLOROETHYLENE
ISOMERS OF XYLENE
ISQMERS OF BUTYLBENZENE
TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
C11H10
BENZENE
TOLUENE .
ETHYLBENZENE
0-XYLENE
N-PROPYLBENZENE
CUMENE (ISOPROPYL BENZENE)
TERT-BUTYLBENZENE
ETHYLTOLUENE
C5-ALKYLBENZENES
C4-ALKYLPHENOLS
C5-ALKYLPHENOLS
DIMETHYLBENZYLALCOHOL
CHLOROBENZENE
DICHLOROBENZENES
OCTAHYDROINDENES
TETRAMETHYLTHIOUREA
BENZOTHIAZOLE
NAPTHALENE
METHYL I NDANS
METHYLDECALINS
DEC AL INS
M-XYLENE AND P-XYLENE
METHYLHEXANE
METHYLHEXENES
METHYLHEPTANE
METHYLNONANE
MOL.
WEIGHT
. 74.12
142.24
58 . 08
72.10
98.14
.125.11
157.25
84.94
137 . 38
133.42
165.83
133.42
187.38
131.40
106.16
134.22
120.19
120.19
142.20
78.11
92.13'
106.16
106.16
120 . 19
120.20
134.21
120.19
148.24
1 50 . 22
164.25
122.16
112.56
147.01
244.00
132.25
135.19
123.11
132.21
170.34
138.25
106.16
100.20
98.18
114.23
142.28
PERCENT
WEIGHT
0 . 06
0.01
0.10
0 . 08
0.02
0 . 0 1
0.05
12.44
7.14
3,74-
13.53
7.14
' 7.65
8.65
0 . 24
0 . 44
0 . 28
0.17
0 . 00
0.07
'9.27
0 . 03
0.18
0 . 04
0 .04
0 . 03
0 . 03
0 . 02
0 . 04
0 . 02
0 . 02
0 . 02
0 . 00
0 . 02
0 . 0 1
0 . 00
0 . 04
0 = 00
0 . 0 5
0 . 07
0.26
0 . 39
0 . 04
0 . 00
0 . 58
B-39
-------
continued (profi1e=9017)
SAROAD CAS
NUMBER NUMBER
90048
90049
90055
90064
90066
90067
90070
90071
90072
90073
90074
90075
90076
90077
90080
90081
90082
90083
90085
90089
90090
90091
90094
90095
90096
90O97
90098
90101 1678-89-9
90102
90104
90105
90106
90107'
90108
90109
90110
90111
90112
90113
90114
90118
90120
98058
98059
9S060
SPECIES
NAME
METHYLDECANES
METHYLUNDECANE
PENTYLCYCLOHEXANE
D I METHYLC YCLOPENTANE
NONADIENE
DIMETHYLHEXANES
DIMETHYLOCTANES
DIMETHYLUNDECANE
METHYLPROPYLCYCLOHEXANES
METHYL I SOPROPYLCYCLOHEXANE
DIMETHYLDECANE
ETHYLOCTENE
DIMETHYLNONANES
ETHYLOCTANE
ETHYLMETHYLCYCLOPENTANE
ETHYLHEXANE
ETHYLMETHYLHEXANE
ETHYLMETHYLCYCLOHEXANES
ETHYLMETHYLOCTANE
. ETHYLDIMETHYLCYCLOHEXANE
ETHYLPROPYLCYCLOHEXANES
TETRAMETHYLCYCLOBUTENE
TRIMETHYLHEPTANES
TRIMETHYLHEXENE
TR I METHYLOCT ANES
TRIMETHYLDECANE
TETRAMETHYLCYCLOPENTANE
BUTYLCYCLOHEXANE
METHYLPROPYLNONANE
METHYL-OCTANES
PROPENYLCYCLOHEXANE
METHYLNONENE
METHYLDECENE
METHYLDODECANE
PROPYLHEPTENES
D I ETHYLMETH YLC YCLOHEX ANES
ISOPROPYLMETHYLCYCLOHEXANE
DIMETHYLOCTYNE
PENTYLIDENECYCLOHEXANE
DIMETHYLBUTYLCYCLOHEXANE
OCTAHYDROPENTALENE
PROPYLCYCLOHEXANE
TR I METHYLCYCLOPENTANE
DIMETHYLCYCLOHEXANE
TRIMETHYLCYCLOHEXANES
MOL.
WEIGHT
. 156.32
170 .,34
154.29
99.19
124.23
114.23
140.27
184.36
168.32
140.27
2^5 . 43
100.16
211.41
142.29
112.21
114.23
128.26
126.24
156.31
141.27.
154.29
110.19
142.29
126.24
156.31
182.35
126.24
140.27
183.35
123.26
141.23
140.26
154.29
134.36
141.28
111.20
140.27
138.25
443.11
168.32
225.20
126.24
112.16
112.12
129.27-
PERCENT
WEIGHT
0 . 49
0 . 09
0 . 04
0 . 22
0.02
0.10
0 . 64
0 . 02
0 . 32
0 . 02
0 . 02
0 . 0 1
0 . 28
0 . 02
0 . 00
0 . 04
0.01
0.57
0.02
0 . 08
0 . 06
0.00
0 . 56
0 . 03
0 . 04
0 . 00
0 . 07
0.19
0.01
0.35
0 . 07
0.01
0 . 08
0.01
0.05
0.05
0 . 04
0.01
0.01
0 . 00
0.01
0.18
0.11
0 . 07
0 . 24
B-40
-------
continued (profiIe=9017)
3AROAD
NUMBER
98062
98063
96082
98091
CAS SPECIES
NUMBER NAME
D I ETHYLC YCLOHEX ANE
N-PENTYLCYCLOHEXANE
ETHYLHEPTENE
DIMETHYLHEPTANES
M'OL.
WEIGHT
140.27
154.30
127.05
128.26
PERCENT
WEIGHT
0 . 06
0.01
0.01
0 . 0 5
SUM TOTAL
100.00
B-41
DATE :08-12-1988
-------
P R 0 FIL E N A M E : S u r face C o a t i n q U p e r a t i o n 3 -- A v e r a q e
PROFILE NUMBER:9021
PROFILE DATA QL)ALITY:E
CONTROL DEVICE:Mot Applicable
REFERENCE(S);93
DATA SOURCE:Averaqa profile developed from original profiles repre-
senting the source category 402XXXXX.
SCC : No SCC
SAROAD CAS
NUMBER NUMBER
4
4
4
4
4
4
4
4
4
4
-:;
J'
"Tt
-T
"T,
|7|
Tj
";
3
3
43
4
T;
43
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
T|
Tt
'"'
."'
T;
T;
T;
-T
'T
3
...r
7;
107
108
109
110
119
122
125
126
127
128
129
15O
23.1
232
238
241
247
248
261
262
277
288
301
302
304
3305
T
"^
308
311
110-05-
142-28-
124-41-
1120-02
":r
5
5
-4
108-80-7
110-08-7
108-38
96-63-7
"'>
1678-89-7
67-75-1
64-41-5
67-76-0
'71 1 T T
/ JL .L ' '
111-17-
110-03-
?
5
SPECIES
NAME
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
LACTOL SPIRITS
ISOMERS OF PENTANE
CIO OLEFINS
C2 CYCLOHEXANE
C3 CYCLOHEXANE
cs CYCLOHEXANE'
C4 SUBSTITUTED CYCLOHEXANE
ISOMERS OF C10H18
I-IEXANE
HEPTANE
N-DECANE
N-UNDECANE .
2 ., 4-D I METHYLPENTANE
CYCLOHEXANE
METHYLCYCLOHEXANE
METHYL.CYCLQPEMTANE
2,4-DIMETHYLHEXANE
ETHYLCYCLOHEXAIME
METHYL ALCOHOL
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
N-BUTYL ALCOHOL
BUTYL CELLOSOLVE
CELLOSOLVE
MOL
WEI
114.
128
142
156
114
72 .
140
112
126
154
142
133
86.
.100
1 4'"-'1
156
100
84.
98.
34.
.1.14
112
32.
46.
60.
74.
113
90.
GHT
.
a
m
2
2
2
T;
T;
5
8
0
. 00
15
,
2
7
. 22
.24 .
.
.
j.
a
'.
''':
r~',
ji
7
^
"T1
~\
0
8
5
0
8
1
.20
16
2
;
*
.
1
6
2
2
Ij.'
j:ป
PERCENT
WEIGHT
0
1
2
0
3
1
0
0
.0
0
'0
0
0
1
o
o
o
0
o
o
0
o
. 03
.44
.53
.17
"^,3
.87
.24
. 10
.07
. 03
.10
.15
.41
.87
. 0 i
.09
.15
.57
.94
. 11
.64
.14
04 3 . 33
07 3.33
09 3
1
.
1
2
1
'^_
7
4
o
j.
. 70
00
, 55
""i ""**
B-42
-------
continued (profile-9021)
SARD AD
NUMBER
43312
43313
43318
43320
43322
43367
43370
43371
43372
43377
43391
43432
43433
43435
43444
43450
43452
43453
43454
43457
43458
43459
43551
43552
43560
43562
43563
43570
43601
43801
43802
43812
43835
43836
43837
45101
45102
45104
45107
45108
45201
45202
45203
45204
45205
CAS
NUMBER
i"i *~ฐ^ - ^ "** ..... *-\
J. J^. JU. -...' \J
104-47-7
123-34-2
110-06-4
107 72-1
10 7-7 4- 5
1 42-29-- 1
111-19-0
79-92-9
141-17-6
138-82-7
108-82-4
68-81-2
111- 1.1- 9
108-80-4
112-23-0 .
109-93-5
67-76-1
78-89-3
1 08-81 7 1
110-04-0
7379-91-6
75-52-8
74-48-3 -
"7 '"N inn 1"^ l"\ ป. *"^
/ u.1 X..1 I,.' ฃ.
75-50-3
78-88-4
106-69-4
1330-02-7
25551-11-7
71-14-2
108-88-3
100-04-4
95-54-6
108-83-3' '
SPECIES
NAME
2--- ( 2-BUTOX YETHOX Y ) -ETHANOL
1 -.-ETI-IO X Y-2-PROP ANQL
2-ETHYL HEXANOL
D I ACETONE ALCOHOL
1,4- BUT AIMED I OL
GLYCOL ETHER
ETHYLENE GLYCOL.
HE XYLENE GLYCOL
D I BUTYL ETHER
CARBITOL
2 - B U T Y L T E T R A H Y D R 0 F U R A N
METHYLACETATE
ETHYL. ACETATE
N-BUTYL ACETATE
I SOPROPYL ACETATE
DIMETHYL FORMAMIDE
CELLOSOLVE ACETATE
VINYL ACETATE
METHYL PAL..MITATE
METHYLAL
SUBSTITUTED C9 ESTER (C12)
C5 ESTER
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
METHYL AMYL KETONE
2-METHYL-3-HEXANONE
ALKEIME KETONE
ETHYLENE' OXIDE
METHYL CHLORIDE
METHYLENE CHLORIDE
ETHYL CHLORIDE
1-CHLQRQBUTANE
3- ( CHLOROMETHYL ) -HEPTANE
ETHYLENE: DI BROMIDE
NAPHTHA
ISOMERS OF XYLENE " ' "'
ISOMERS OF ETHYLTOLUENE
TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
. BENZENE . . - . .-'.
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE . ' ;
MOL .
WEIGHT
162.18
104. 15
130.23
116.16
90.12
106.12
62 . 07
118.18
130.23
134. 18
128. 19
74.08
88.10
116.16
102.13
73.09
132.16
86 . 09
270.46
76 . 09
218.24 '
130.19
58 . 08
72.10
100. 16
114.21
114.19
72.10
44.05
50 . 49
84 . 93
64 . 52
92.57
148 . 68
187.88
114.00
' 106.16
120.19
120.19
120.19
78.1.1.,.-
92.13
106.16
106.16
.106.16
P
W
o
o
o
o
o
o
o
-.,.
3
o
,J;i
4
5
.,,.
o
-'.''
0
0
0
o
o
5
5
0
0
0
o
3
0
0
o
0
o
0
3
4
0
0
0
. 0
6
0
0
0
ERCEMT
EIGHT
. 0-3
.-, 0 5
. 03
. 03
.37
.10
,, 02
38
. 0 i
a .!!' .ซ'
.01
a O'O
.14
.05
,. ...';i...''i
33
33
00
= 0 1 .
.90
.95
.23
n / /
. 50
79
.18
. 67
. 07
. 33
.02
n .IM. .<::.
02
.07
.02
. 03
3 3
.82
.25
.34
.04
.05
.72
.42
.71
. 06
B-43
-------
continued (profile-9021
SAROAD CAS
NUMBER NUMBER
45206 106-64-3
45501 100-05.-7
45502 104-48-0
45601 35-54-9
98057 1640-08-7
98058
98059
93060
98062
98082
98090
98091
98106
SPECIES
NAME
P-XYLENE
BENZALDEHYDE
P-TOLUALDEHYDE
PHTHALIC ANHYDRIDE
ETHYLCYCLOF'ENTAME
TR I METHYLCYCLOPENT ANE
D.TMETHYLCYCLOHEXANE
TR I METHYLCYCLOHEX AMES
DIETHYLCYCLOHEXANE
ETHYLHEPTENE
METHYLHEPTENE
DIMETHYLHEPTANES
ETHYL. 1 SOPROPYL ETHER
MOL .
WEIGHT
106.16
106.13
120.16
148.00
98.19
1.12.16
112a 12
129,27
140 ,,27
127.05
112.22
128.26
88.15
PERCENT
WEIGHT
0
0
0
0
o
o
o
o
o
o
0
o
0
.04
. 03
.04
.03
. 06
.05
34
16
.- -, ^
,,08
04
. 06
. 17
SUM TOTAL
10000
B-44
DATE :05-03-1988
-------
PROFILE NAME:Solid Waste Disposal - Average
PROFILE NUMBER:9022
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 5XXXXXXX
SCC : No SCC
SAROAD
NUMBER
43121
43123
43201
43202
43203
43204
43205
43206
43212
43213
43214
43220
43224
43231
43232
43233
43242
43817
45102
45201
45202
CAS
NUMBER
74-48-8
74-48-0
74-48-1
74-49-6
79-92-9
540-04-8
106-69-8
106-69-9
75-52-5
109-96-0
109-96-1
110-05-3
142-28-5
111-16-9
287-79-3
127-71-4
71-14-2
108-88-3
SPECIES
NAME
ISOMERS OF PENTENE
TERPENES
METHANE
ETHANE
ETHYLENE
PROPANE
F'ROPENE
ACETYLENE
N-BUTANE
BUTENE
ISO-BUTANE
N-PENTANE
1-PENTENE
" HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
PERCHLOROETHYLENE
ISOMERS OF XYLENE
BENZENE
TOLUENE
MOL.
WEIGHT
70.13
136.23
16.04
30 . 07
28.05
44 . 09
42 . 08
26 . 04
58.12
56.10
58.12
72.15
70.13
86.17
100.20
114.23
70.14
165.83
- 106.16
78.11
92.13
. SUM TOTAL
PERCENT
WEIGHT
3 . 93
0 . 03
59 . 70
0,93
9-. 37
0 67
0 . 1 7
0 . 63
0 . 70
1.97
0.67
0 . 67
3 a 93
4.63
4.63
4 . 60
0 . 03
0. 10
0.03
2.57
o . 0:3
100 . 00
B-45
DATE :04-21-1988
-------
PROFILE NAME:Thinning Solvents - Average
PROFILE NUMBER s 9023
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S)s 93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 402009XX
SCC : No SCC
SAROAD CAS
NUMBER NUMBER
43107
43108
43109
43110
43119
43125
43126
43127
43128
43129
43150 825-55-4
43232 142-28-5
43241 1120-02-4
43261 108-88-2
43301 67-75-1
43302 64-41-5
43304 67-76-6
43305 71-13-3
43311 110-08-5 :
43371 107-72-1 .
43377 111-19-0
43432 79-92-9
43433 1-41-17-6 .
43435 138-82-7
43444 108-82-4
43450 68-81-2
43452 111-11-9
43551 67-76-1
SPECIES
NAME
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
LACTOL SPIRITS
CIO OLEFINS
C2 CYCLOHEXANE
C3 CYCLOHEXANE
C5 CYCLOHEXANE
C4 SUBSTITUTED CYCLOHEXANE
C10H18
HEPTANE
N-UNDECANE
METHYLCYCLOHEXANE
METHYL ALCOHOL
ETHYL ALCOHOL
ISO-PROPYL ALCOHOL
N-BUTYL ALCOHOL
CELLOSOLVE
HEXYLENE GLYCOL
CARBITOL
METHYLACETATE '
ETHYL. ACETATE ' ' '
N-BUTYL ACETATE
ISOPROPYL. ACETATE ...
DIMETHYL FORM AM IDE
CELLOSOLVE ACETATE
ACETONE
MOL.
WEIGHT
114.23
128.25
142.28
156.30
114.00
140.27
112.22
126.24
1 54 . 30
142.28
138.25
100.20
156.31
85.16
32 . 04
46 . 07
60.. 09
74.12
90 ..12
118.18
134.18
74 . 08
88.10
116.16
102.13
73 . 09
132.16
58 . 08
PERCENT
WEIGHT
0 . 04
1.55
3.61
0 . 20
4 . 76
0 . 34
0.14
0 . 09
0 . 04
0.14
0.21
0 . 1 5
0.12
0 . 32
4.76
4.76
5 . 00
4.76
4.76
4.76
4.76
4.76
4.76
5 . 20
4.76
4.76
4.76
4.76
B-46
-------
continued (profile=9023)
SAROAD
NUMBER
43552
43570
43601
43802
43837
45101
45102
45202
45203
45205
45206
45501
45502
45601
98062
98082
CAS
NUMBER
78-89-3
75-52-8
75-50-2
106-69-4
.108-88-3
100-04-4
108-83-3
106-64-3
100-05-7
104-48-0
85-54-9
SPECIES
NAME
METHYL ETHYL KETONE
ALKENE KETONE
ETHYLENE OXIDE
DICHLOROMETHANE
ETHYLENE D I BROMIDE
NAPHTHA
ISOMERS OF XYLENE
TOLUENE
ETHYLBENZENE
M-XYLENE
P-XYLENE
BENZALDEHYDE
P-TOLUALDEHYDE
PHTHALIC ANHYDRIDE
DIETHYLCYCLOHEXANE
ETHYLHEPTENE
MOL.
WEIGHT
72.10
72.10
44.05
84.94
187.88
114.00
106.16
92.13
106.16
106. 16
106.16
106.13
120.16
148.00
140.27
127.05
SUM TOTAL
PERCENT
WEIGHT
4.96
0 . 09
4.76
0 . 06
0 . 04
4.76
4.76
0 . 72
0 . 04
0 . 08
0.05
0 . 04
0 . 05
0 . 04
0 . 38
0.11
100 . 00
B-47
DATE :04-21-1988
-------
PROFILE NAMb:Petroleum Product Storage - Average
PROFILE NUMBER:9024
PROFILE DATA QUALITYzE
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 403XXXXX
SCC : No SCC
SAROAD
NUMBER
43105
43115
43116
43122
43201
43202
43204
43212
43214
43220
43231
43232
43233
43235
43238
43241
43255
43258
/I T*"*e;Q
*f J'jfi.OT-
43260
45201
CAS
NUMBER
74-48-8
74-48-0
74-49-6
106-69-8
75-52-5
109-96-0
110-05-3
142-28-5
111-16-9
111-18-2
124-41-5
1120-02-4
112-24-3
629-95-5
/.OO_oe;_/r
Oj-if VO ~~*t
629-96-9
71-14-2
SPECIES
NAME
ISOMERS OF HEXANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
ISOMERS OF PENTANE
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
N-PENTANE
HEXANE
HEPTANE
OCTANE
NONANE
N-DECANE
. N-UNDECANE
N-DODECANE ' -
N-TRIDECANE
N "TCTT"CปAT^C7f"*/\NICr '
~" 1 c. 1 KwDtLrMNt. .-
N-PENTADECANE
BENZENE'
' . ' - -.
MOL.
WEIGHT
86.17
98.19
112.23
72.15
16.04
30 . 07
44 . 09
58.12
58.12
72.15
86.17
100.20
114.23
128.25
142.28
156.31
,170.33
184.36
. , .' 1-OQ ~TQ
.'... IVo . Oo
212.41
78.11
SUM TOTAL
PERCENT
WEIGHT
2.86
0 . 42
0.16
0 . 49
2.01
1.81
5.70
8 . 78 '
0.49
4.73
2.56
3.01
2 . 40
1.52
6.35
6.57
5.89
5.73
"? ~7O
_' / V
2.33
32.41
100.0O
DATE :04-21-1988
B-48
-------
PROFILE NAME:Bulk Terminals - Petroleum Storage Tanks - Average
PROFILE NUMBER:9025
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 404XXXXX
sec
No SCC
SAROAD
NUMBER
43105
43106
43107
43108
43109
43120
43122
43124
43125
43138
43201
43202
43204
43212
43214
43216
43217
43220
43223 .
43224
43225
43226
43227
43228.
43230
43231
43232
43233
CAS
NUMBER
74-48-8
74-48-0
74-49-6
106-69-8
75-52-5
624-46-6
.590-01-1
109-96-0
563-34-1 .
109-96-1
563-34-2
646-60-8
627-72-3
513-33-9
96-61-0
110-05-3
142-28-5
111-16-9
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISOMERS OF NONANE
ISOMERS OF DECANE
ISOMERS OF BUTENE
ISOMERS OF PENTANE
C9 OLEFINS
CIO OLEFINS
C-8 OLEFINS
METHANE
ETHANE
PROPANE
N-BUTANE
ISO-BUTANE
T-2-BUTENE
CIS-2-BUTENE . -
N-PENTANE
. 3-METHYL-l-BUTENE - .
1-PENTENE
2-METHYL-l-BUTENE
TRANSr-2-PENTENE
CIS-2-PENTENE
2-METHYL-2-BUTENE
3-METHYL. PENTANE
HEXANE
HEPTANE
OCTANE
MOL.
WEIGHT
86.17
100.20
114.23
128.25
142.28
56.10
* 72.15
127.05
140.27
112.23
16.04
30 . 07
44 . 09
58. 12
58.12
56.11
56.11
72.15
70.13
70.13
70.13
. 70.13
70.13
70.13
86'. 17
86.17
100.20
114.23
PERCENT
WEIBHT
1.75
3.41
0.65
0.15
0 . 02
0 . 82
.18.57
0. 10
0 . 00
0 . 07
3 . 02
0.97
6 . 33
23 . 60
11.35.
0 . 80
0.62
8.28
0 . 23
0 . 59
0.95
0 . 93
0.46 -
0 . 36
1.58
2.88
1 . 09
0 . 09
B-49
-------
continued (profile=9025)
SAROAD
NUMBER
43235
43238
43242
43245
43247
43248
43250
43252
43261
43262
43265
43270
43271
43278
43284
43289
43291
43292
43293
43294
43295
43298
43820
45102
45109
45110
45201
45202
45203 .
45204
45207
45208
45209
45210
45211
45212
45215
45218
45225
45801
46701
46712
90013
98033
98034
CAS
NUMBER
111-18-2
124-41-5
287-79-3
110-05-3
108-80-7
43-32-8
540-08-1
565-57-3
108-88-2
96-63-7
111-16-0
922-26-2
592-21-2
625-52-4
75-58-2
142-22-0
27236-64-0
589-93-4
96-61-0
79-90-5
71-14-2
JLOo~"8o''J>
10O-04-4
95-54-6
108-86-8 '
95-56-6
103-36-1
98-88-8
611-11-3
620-01-4
98-80-6 . .
141-19-5
526-67-8
108-89-7
91-12-3
95-51-6
40504-45-7
SPECIES
NAME
NONANE
N-DECANE
CYCLOPENTANE
1-HEXENE
2 , 4-D I METHYLPENTANE
CYCLOHEXANE
2,2, 4-TR I METHYLPENTANE
2,3, 4-TR I METHYLPENTANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
OCTENE
3-METHYL-T-2-PENTENE
3, 5, 5-TRIMETHYLHEXANE
2,5-DIMETHYLHEXANE
2-METHYL-2-PENTENE
C6 OLEFINS
2 , 2-D I METHYLBUTANE
CYCLOPENTENE
4-METHYL-T-2-PENTENE
C7 OLEFINS
3-METHYLHEXANE
3-METHYLHEPTANE
1,1, 2-TR I CHLOROETHANE
ISOMERS OF XYLENE
C3/C4/C5 ALKYLBENZENES
CIO AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
- 1,3,5-TRIMETHYLBENZENE
1,2,4-TRIMETHYLBENZENE
N-PROPYLBENZENE
CUMENE (ISOPROPYL BENZENE)
0-ETHYLTOLUENE
M-ETHYLTOLUENE
TERT-BUTYLBENZENE
M-DIETHYLBENZENE
1,2, 3-TR I METHYLBENZENE
CHLOROBENZENE
NAPTHALENE
INDENE -
C-2-OCTENE
2 ,2, 5-TRIMETHYLHEXANE
T-2-HEXENE
MOL.
WEIGHT
128.25
142.28
70.14
84.16
100.20
84.16
114.22
114.22
85.16
84.16
112.21
84.16
128.26
114.22
84.16
84.16
86.17
68.11
84.18
98.18
100.20
114.23
133.42
106.16
134.21
134.22
78.11 .
92.13
..'. 106.16
106.16
120.19
120.19
120.19
120.20
120.19-
120.19
134.21
134.22
120.19
112.56
123.11
116.16
112.21
128.26
84.16
PERCENT
WEIGHT
0.01
0 . 00
0 . 49
0.23
0 . 42
0.27
0.17
0 . 07
0 . 23
1.44
0 . 02
0 . 03
0.19
0.16
0 . 04
0 . 24
0.75
0.17
0. 16
0.05
0 . 54
0.17
0.01
0.3.1.
0.01
0 . 00
1.63
1 . 43
0 . 09
0.13
O.O2
0.05
0.01
0 . 00
0 . 03
0 . 03
0 . 00
0 . 00
0 . 03
0.01
0 . 00
0 . 00
0.01
0 . 07
0.25
B-50
-------
continued (profile=9025)
SAROAD CAS
NUMBER NUMBER
98035 592-24-8
98037 108-88-2
98040 763-32-1
98041
98044 496-61-7
98054 107-73-1
98056 590-08-3
SPECIES
NAME
C-2-HEXENE
1-METHYLCYCLOHEXENE
2-METHYL-l-PENTENE
3-HEPTENE
INDANE
2,4, 4-TRIMETHYL-l-PENTENE
ISQVALERALDEHYDE
MOL.
WEIGHT
84.16
96.17
84.16
93.19
118.18
112.22
86.14
PERCENT
WEIGHT
0 . 20
0 . 08
0 . 02
0.01
0 . 00
0 . 02
0.00
SUM TOTAL 100.00
B-51
DATE :04-21-1988
-------
PROFILE NAME:Printing/Publishing - Average
PROFILE NUMBER:9026
PROFILE DATA QUALITYsE
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 405XXXXX
SCC : No SCC
SAROAD
NUMBER
43114
43118
43125
43155
43156
43201
43202
43203
43204
43205
43212
43213
43224
43243
43273
43301
43304
43305.
43332 .
43333
43334
43335
43377
43434
43435.
43444
43474
43475
CAS
NUMBER
74-48-8
74-48-0
74-48-1
74-49-6
79-92-9
106-69-8
106-69-9
109-96-1
43-32-8
110-08-8
67-75-1
67-76-0
71-13-3
! . -
'...: v ..: ',-.
111-19-0
109-96-4
1.38-82-7
108-82-4
SPECIES
NAME
ISOMERS OF PENTADECANE
MINERAL SPIRITS
CIO OLEFINS
ISOMERS OF HEPTADECANE
ISOMERS OF OCTADECANE
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
N-BUTANE
BUTENE
1-PENTENE
CYCLOHEXANE
CYCLOHEXENE
METHYL ALCOHOL
ISO-PROPYL ALCOHOL
N-BUTYL ALCOHOL
DI'METHYLOCTANOL ' '
D I METHYLHEPTANOL
METHYLHEPTANOL .
METHOXYETHOXYETHANOL
CARBITOL . ' ' '
N-PROPYL ACETATE
N-BUTYL ACETATE
ISOPROPYL ACETATE
METHYLMETHYLPROPENOATE
METHYLETHYLPENTANOATE
MOL.
WEIGHT
212.41
114.00
140.27
240 . 47
254.50
16.04
30 . 07
28.05
44 . 09
42.08
58.12
56.10
70.13
84.16
82.14
32 . 04
60 . 09
74.12
159.29
145.26
131.24
120.00
134.18
102.15
116.16
102.13
100.13
0 . 00
PERCENT
WE I BHT
0 . 02
16.75
0 . 02
0.46
0.21
10.01
3 . 00
0.25
1 . 50
4 . 20
0.13
1 . 70
1.49
1.82
0 . 03
0.75
0.75
0.75 .
0.01
0.01
0.01
0.01
12.50
3 . 43
1 . OO
3.76
0 . 00
0 . 00
B-52
-------
continued (profile=9026)
SAROAD
NUMBER
43502
43551
43552
43560
45102
45106
45202
45203
45304
45330
45402
45452
45456
457O6
45731
90030
90049
90071
90077
90096
90097
90125
90126
90127
90130
CAS
NUMBER
50-00-0
67-76-1
78-89-3
563-38-4
108-88-3
100-04-4
65-58-0
84-47-2
26471-16-5
544-47-3
ft
629-99-7
112-29-8
87-74-5
SPECIES
NAME
FORMALDEHYDE
ACETONE
METHYL ETHYL KETONE
METHYL ISOBUTYL KETONE
ISOMERS OF XYLENE
ISOMERS OF DIETHYLBENZENE
TOLUENE
ETHYLBENZENE
C5-ALKYLPHENOL
BIPHENYLOL
BENZOIC ACID
D I BUTYL PHTHALATE
BUTYL I SOPROPYLPHTHAL ATE
N-PHENYLANILINE
TOLUENE DIISOCYANATE
HEXADECANE
METHYLUNDECANE
DIMETHYLUNDECANE
ETHYLOCTANE
TRIMETHYLOCTANE
TRIMETHYLDECANE
HENEICOSANE
EICOSANE
NONADECANE
CARYOPHYLLENE
MOL.
WEISHT
30 . 03
58 . 08
72.10
100.16
106.16
134.21
92.13
106.16
164.25
170.00
122.13
278.35
171.22
169.24
174.17
226.45
170.34
184.36
142.29
156.31
182.35
296.59
282.56
268.53
204.41
SUM TOTAL
PERCENT
WEIGHT
2.73
3 . 06
6.78
14.35
0 . 50
0 . 88
2.44
0.75
0 02
0 . 0 1
0 . 00
1 .25
1 . 60
0.01
0 . OO
0.41
0.21
0.03
0 . 06
0.10
0 . 04
0 . 04
0.06
0 . 1 1
0.01
100.00
B-53
DATE : 04-21-1988
-------
PROFILE NAME:Transportation and Marketing of Petroleum Products
-Average
PROFILE NUMBER:9027
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S): 93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 406XXXXX
SCC
No SCC
SAROAD
NUMBER
43105
43109
43110
43111
43113
43115
43124*
43125
43135
43136
43138
43141
43142
43143
43144
43145
43146'
43148
43149
43201
43202
43204
43212
43213
43220
43231
43232
43233
CAS
NUMBER
. i j
74-48-8
74-48-0 -
74-49-6
106-69-8
106-69-9
109-96-0 .
110-05-3
142-28-5
111-16-9
SPECIES
NAME
ISOMERS OF HEXANE
ISOMERS OF DECANE
ISOMERS OF UNDECANE
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
C-7 CYCLOPARAFFINS
. C9 OLEFINS
CIO OLEFINS
CIO PARAFFIN
C9 PARAFFIN
C-8 OLEFINS
C8 PARAFFIN
C7 PARAFFIN
C5 OLEFIN
C5 PARAFFIN
C5 PARAFFIN/OLEFIN
Cll. OLEFIN . .
C9H16 ......
C8H14 " '....':' " '.:'""'
METHANE "
ETHANE ' . '
PROPANE .
N-BUTANE ' ' .
BUTENE
N-PENTANE
HEXANE
HEPTANE
OCTANE
MOL.
WEIGHT
86.17
142.28
156.30
170.32
198.38
98.19
127.05
140.27
142.28
128.25
112.23
114.23
100.20
70 . 13
72.15
7O.M.3
1.54 . 29
124.23
110.20
16.04 -
30 . 07
44.09
58.12
56.10
72.15
86.17
100.20
114.23
PERCENT
WEIGHT
0.05
0.05
0 . 04
0 . 02
0.01
0 . 02
0.05
0 . 02
0 . 00
0 . 24
0.10
1.92
0 . 02
0.95
1 . 04
0 . 54
0 . 02
0.01
0.00
1 . 30
1.85
7.90
15.10
0 07
9.25
6.35
6.32
4 . 80
B-54
-------
continued (profile=9027)
SAROA[
NUMBER
43242
43261
43262
43264
43272
43273
43288
43292
43395
43565
45105
45106
45107
45108
45111
45112
45201
45202
45203
45204
45210
45220
45221
45238
45240
45243
45244
45245
45246
45247
45248
45249
45501
45801
46115
46701
46702
46746
46747
46749
46750
46751
46752
46754
46755
) CAS
* NUMBER
287-79-3
108-88-2
96-63-7
693-38-0
110-08-8
1678-89-7
142-22-0
502-24-1
25551-11-7
119-96-2
71-14-2
108-88-3
100-04-4
95-54-6
98-88-8
100-04-5
25013-31-4
103-36-1
,
-
100-05-7
108-89-7
91-12-3
SPECIES
NAME
CYCLOPENTANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
HEPTENE
METHYLCYCLOPENTENE
CYCLOHEXENE
ETHYLCYCLOHEXANE
CYCLOPENTENE
C7H120
DIMETHYLCYCLOBUTANONE
ISOMERS OF BUTYLBENZENE
ISOMERS OF DIETHYLBENZENE
TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
C10H12
C10H10
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
CUMENE (ISOPROPYL BENZENE)
STYRENE
METHYL STYRENE
ETHYLTOLUENE
PROPYLBENZENE
ETHYLDIMETHYLBENZENE
TETRAMETHYLBENZENE .
C5-ALKYLBENZENE
C5-ALKYLBENZENE. (UNSAT.)
C6-ALKYLBENZENE
C4-ALKYLSTYRENE . ' ' . -
C7-ALKYLBENZENE
BENZALDEHYDE
CHLOROBENZENE
D I METHYLNAPHTHYR I D I NE
NAPTHALENE
METHYL NAPHTHALENES
C2-ALKYLNAPTHALENE
METHYL INDAN
METHYLD I HYDRONAPHTH ALENE
DIMETHYLINDAN
D I HYDRONAPTHALENE
D'l METHYL I NDENE
ETHYL INDAN
TRIMETHYLINDAN
MOL.
WEIGHT
70.14
85.16
84.16
98.18
82.14
82.14
112.23
68 . 1 1
112.17
98.14
134.22
134.21
120.19
120.19
132.22
130.19
78.11
92.13
106.16
106.16
120.20
104.14
118.19
120.19
120.20
122.21
134.22
145.25
147.24
162.27
'160.26
176.30
106.13
112.56
160.00
.123.11
142.20
158.24
132.21
176.21
146.00
162.19
144.00
318.89
333 . 92
PERCENT
WEIGHT
0 . 08
0.10
0 . 34
0.01
0.22
0 . 02
0 . 04
0 . 09
0 . 02
0 . 02
1 . 60
0.01
2.14
0 38
0 . 02
0 . 00
1.62
7.61
2 . 03
3.20
0.16
0 . 08
0 . 02
1 . 90
0.46
0 . 62
0.51
0.71
0 . 02
0.05
0.03
0 . 00
0 . 00
O.O1
0 . 00
0 . 40
0.32 '
0.05
0 . 26
0 . 00
0.21
0 . 03
0 . 00
0 . 02
0 . 03
B-55
-------
continued (profile=9027)
SAROAD CAS
NUMBER NUMBER
90010 108-83-3
90021
90022
90023
90024
90025
90026
90027 26472-20-4
90028
90029
90039
90041 26472-20-4
90043
90044
90045
90046
90047
90048
90054
90056
90058 142-28-6
90059
90060
90061
90062
90063
90064 ' .
90065
90067
90068 .... ....
90069 ;"' ."'...'
90070
90071
90074 '- -.. :".-' .
90078 ' - ' '
90079
90080 ', . . .
90081
90082
90083
90084
90085
90086
90087
90091
SPECIES
NAME
M-XYLENE AND P-XYLENE
METHYLPROPANE
METHYLPROPENE
METHYLBUTENE
METHYLBUTADIENE
METHYLPENTENE
METHYLPENTANE
METHYLCYCLOPENTAD I ENE
METHYLHEXANE
METHYLHEXENE
METHYLHEXADIENE
METHYLCYCLOHEX AD I ENE
METHYLHEXANAL
METHYLHEPTYNE
METHYLHEPTANE
METHYLCYCLOHEXENE
METHYLNONANE
METHYLDECANE
PENTENYNE
HEXENE
HEXADIENAL
HEPTADIENAL
DIMETHYLBUTANE
D I METHYLBUTENE
D I METHYLPENTANE
D I METHYLPENTENE
DI METHYLCYCLOPENTANE
D I METH YLCYCLQPENTENE
DIMETHYLHEXANE .
.DIMEJHYLHEXADIENE . .,'.'.
D I METHYLEtHYLCYCLOHEX ANE
DIMETHYLOCTANE
DIMETHYLUNDECANE
D I METHYLDECANE
ETHYLPENTENE ' '
ETHYLCYCLOPENTENE .
ETHYLMETHYLCYCLOPENTANE ,
ETHYLHEXANE
ETHYLMETHYLHEXANE
ETHYLMETHYLCYCLOHEXANE
ETHYLHEPTANE
' ETHYLMETHYLOCTANE
ETHYLB I CYCLOHEPT ANE
ETHYLD I METHYLPENTANE
TETRAMETHYLCYCLQBUTENE
MOL.
WEIGHT
106.16
58.12
56.10
70.13
68.12
84.16
86.17
160.23
1 00 . 20
98.18
96.17
94.15
146.36
110.20
114.23
96.17
142.28
156.32
68.12
84.16
111.16
125.19
87.18
85.17
101.21
99 . 20
99.19
97.18
114.23
111.20
140.26
140.27
184.36
' 225.43
98.19
96.17.
112.21
114.23
128.26
126.24
128.26
156.31
' 223.42
128.26
110.19
PERCENT
WEIGHT
7.64
1.32
0 . 07
0 . 03
0 . 00
0 . 44
0 . 88
0 . 02
0 . 84
0.01
0.12
0.01
0 . 46
0.01
0.17
0 . 07
0 . 1 0
0 . 06
0.01
0 . 20
0.01
0.01
1.14
0.15
0.18
0.01
0 . 07
0.15
0 . 38
0.05
0 . 04
0 . 03
0 . 00
0 . 03
0.01
0 . 03
0 . 06
0.12
0. 10
0 . 03
0.01
0.01
0 . 00
0 . 06
0.02
B-56
-------
continued (profile=9027)
SAROAD CAS
NUMBER NUMBER
90092
90093
90094
90095
90096
90097
90099
90100
90103 504-46-9
90104
98044 496-61-7
98058
98059
98060
98091
99999
SPECIES
NAME
TR I METHYLPENT ANE
TR I METHYLPENT AD I ENE
TRIMETHYLHEPTANE
TRIMETHYLHEXENE
TRIMETHYLOCTANE
TRIMETHYLDECANE
OCTATRIENE
NONENE
PENT ADI ENE
METHYL-OCTANE
INDANE
TR I METHYLCYCLOPENTANE
DIMETHYLCYCLOHEXANE
TRIMETHYLCYCLOHEXANE
DIMETHYLHEPTANE
UNIDENTIFIED
MQL.
WEIGHT
114.22
107.16
142.29
126.24
156.31
182.35
108.19
127.05
68.13
128.26
118.18
112.16
112.12
129.27
128.26
86 . 00
PERCENT
WEIGHT
0 . 34
0 . 02
0 . 07
- 0 . 02
0 . 03
0.01
0 . 00
0 . 0 1
0 . 02
0.27
0 22
0 . 04
0 . 0 5
0.01
0 . 08
0 n 00
SUM TOTAL
100.00
B-57
DATE :04-21-1988
-------
PROFILE NAME:Organic Chemical Storage - Average
PROFILE NUMBER:9028
PROFILE DATA QUALITYsE
CONTROL DEVICEsNot Applicable
REFERENCE(S) s 93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407XXXXX.
No SCC
SAROAD CAS
NUMBER NUMBER
43111
43114
43224
43231
43232
43238
43243
43248
43264
43292
43303
43306
43308
43309
43310
43317
43351
43373
43374
43376
43377
43378
43379
43403
43404
43405
43407
43409
109-96-1
110-05-3
4 f\ f"* o r-i d
J. *T -::. .t~ O v.1
124-41-5
78-87-5
1 10-08-7
142-22-0
71-12-8
78-88-1
111 17-2
75-56-0
109-98-4
108-89-0 '
60-02-7
111-14-6 ' ,
106-66-7
628-82-4
.11.1-19-0. .
111-17-3
112-23-5
64-41-6.
64-41-7
79-90-4
79-91-7
124-40-9
SPECIES
NAME
ISOMERS OF DODECAME
ISOMERS OF PENTADECANE
1-PENTEME
HEXANE
HEPTANE
N-DECANE
I SOPRENE
CYCLOHEXANE
HEPTENE
CYCLOPENTENE
M-PROPYL. ALCOHOL
ISOBUTYL ALCOHOL
BUTYL CEL.LOSQL.VE
TERT-BU.TYL ALCOHOL '
METHYL CELLOSOLVE '
' CYCLOHEXANOL . ' . . .
ETHYL ETHER ' '
. DIETHYLEIME GLYCOL. '. .'.
DIPROPYLENE BLYCOL
METHYL T-BUTYL ETHER
CARB.I.TOL. , .--. . ... . .
. METHYL CARBITOL ' '
BUTYL CARBITOL
FORMIC ACID
ACETIC ACID
PROP I ON 1C ACID
ACRYLIC ACID
ADIP'IC ACID
MOL .
WEIGHT
170,32
212.41
70.13
86. 17
100.20
142.23
68.12
84.16
98.18
68.11
60 . '1 0
74.12
118.17
74.12
76.11
100.16
74.12
' 106.12
134.18
-. - 88.15
.; 134.18
120., 15
162.23
46.03
60 . 05
74.08
72 . 06
146.14
PERCENT
WE I GHT
1 .
1.
1.
1 .
1
1 :,
-1. 0
1.
1.
if
1 ,,
1.
1..
1
1.
1.
1.
1.
1 I,
1
1.
1.
1.
1.
1.
.1 It
1 .
1.
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
47
B-58
-------
c o n t i n u e d ( p r a f i 1 e - 9 0 2 8 )
SAROAD
NUMBER
43432
43434
43437
43438
43440
43451
43468
43502
43503
43504
43505
43510
43511
43561
43562
43602
43604
43704
43777
4377S
43803
43804
43837
43863
43902
45203
45204
45205
45206
4 52 10.
45221
45236
45605
45701
45702
45731
45750 "
458.10
90001
900.11
CAS
NUMBER
79-92-9
109-96-4
96-63-3
140-08-5
141-13-2
297-78-8
106-66-8
50-- 00-0
75-50-0
123--33-6
107 70-8
.123-37-8
78-88-2
108-89-1
110-04-0
75-55-9
108-82-7
107-71-1
141-14-5
67-76-3
O o o .ปฃ ~" *D
106-69-4
106-68-8
75-50-1
100-04-4
9 5 -54 -6
108-83-3-'
106-64-3
98-88-8
25013-31-4
1319-97-3.
62-25-3 .
98-89-3
58-88-9
504-46-9'
100-04-7
112-24-4
SPECIES
NAME
METHYL-ACETATE
N-PROPYL ACETATE
METHYL ACRYLATE
ETHYL ACRYLATE
BUTYL ACRYLATE
ISOBUTYL ISOBUTYRATE
ISOBUTYL ACRYLATE
FORMALDEHYDE
ACETALDEHYDE
PROPIQNALDEHYDE
ACROLEIN
BUTYRALDEHYDE
1SOBUTYRALDEHYDE
CYCLOHEXANONE
METHYL AMYL KETOME
PRQPYLENE OXIDE
ACETIC ANHYDRIDE
ACRYLONITRILE
ETHANOLAMINE
ETHYLENEAMINES
CHLOROFORM
CARBON TETRACHLORIDE
ETHYL.ENE D I BROMIDE '
EPICHLQROHYDRIN
ETHYL MERC APT AN
ETHYLBENZENE
0-XYLENE
M-XYLENE ' '
P-XYLENE .
' CUMENE '( I3QPROPYL BENZENE)
METHYL. STYRENE
DIISOPROPYL BENZENE
CRESOL ....
ANILINE.
NITROBENZENE
TOLUENE DIISOCYANATE
PIPERYLENE ' ' '
BENZYL CHLORIDE
. DODECENE
METHYLALLEIME
MOL n
WEIGHT
74.08
102, 15
86 . 09
100.11
128 ,,17
144.21
.1.28.19
30 03
44 ,,05
53 . 08
56 ,, 07
72.12
72 1.1
98.15
114.2.1
58 . 08
102 . 09
53 . 06
61.08
43 . 07
119.39
153.34
187.88
92 53
62.13
106.16
106.16
106.16
106.16
. 120 . 20
118.19
162.28'
108.14"
93. 13
123.11
174.17
68.12
126.59
168 .32
54 . 09
SUM TOTAL
PERCENT
WE I SHT
1 . 47
i . 47
i . 47
1.47
1.47
1 . 47
1 . 4 7
1 ,, 47'
i ,,47
i.,,4'7
1.47
1 . 47
1.47
1 . 47
1 .47
1.47
1.47
1.47
1.47
1.47
1 ,:47
1 47
1 . 47
1 . 47
1,47
1.47
1 . 47
1 . 47
1 . 4 7
i . 47
1.47
1 . 47
1 . 47
1 . 47
1.47
1.47
1.47
1.47
1 . 47
.1 47
100 . OO
B-59
DATE S05-O3-1988
-------
PROFILE NAMErOrganic Chemical Storage - Fixed Roof Tanks
Alcohols - Average
PROFILE NUMBER:9029
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407008XX
SCC
No SCC
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43303 71-12-8
43306 78-88-1
43309 75-56-0
43317 108-89-0
N-PROPYL ALCOHOL
ISOBUTYL ALCOHOL
TERT-BUTYL ALCOHOL
CYCLOHEXANOL
60.10
74.12
74.12
100.16
25.00
25.00
25.00
25.00
SUM TOTAL
100.00
DATE :04-21-1988
B-60
-------
PROFILE NAMEiOrganic Chemical Storage - Fixed Roof Tanks
Alkanes - Average
PROFILE NUMBER:9030
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S): 93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407016XX
SCC : No SCC
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43111 ISOMERS OF DODECANE 170.32 25.00
43114 ISOMERS OF PENTADECANE 212.41 25.00
43232 142-28-5 HEPTANE 100.20 25.00
43238 124-41-5 N-DECANE 142.28 25.00
SUM TOTAL 100.00
B-61
DATE 504-21-1988
-------
PROFILE NAME:Organic Chemical Storage - Fixed Roof Tanks
Alkenes - Average
PROFILE NUMBER:9031
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407020XX
SCC :
SAROAD
NUMBER
No SCC
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WE IGHT
43264
90001 112-24-4
HEPTENE
DODECENE
98.18
168.32
50.00
50.00
SUM TOTAL
100.00
DATE s04-21-1988
B-62
-------
PROFILE NAME:Organic Chemical Storage - Fixed Roof Tanks
Amines - Average
PROFILE NUMBER:9032
PROFILE DATA GUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407032XX
SCC : No SCC
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43777 141-14-5 ETHANOLAMINE 61.08 33.33
43778 -- ETHYLENE AMINES 43.07 33.33
45701 62-25-3 ANILINE 93.13 33.33
SUM TOTAL 100.00
DATE :04-21-1988
B-63
-------
PROFILE NAME:Organic Chemical Storage - Fixed Roof Tanks
Aromatics - Average
PROFILE NUMBER:9033
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407036XX
SCC : No SCC
SAROAD CAS
NUMBER NUMBER
45203
45204
45205
45206
45210
45221
45236
45605
100-04-4
95-54-6
108-83-3
106-64-3
98-88-8
25013-31-4
SPECIES
NAME
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
CUMENE (ISOPROPYL BENZENE)
METHYL STYRENE
DI ISOPROPYL BENZENE
CRESOL
MOL.
WEIGHT
106
106
106
106
120
118
162
108
.16
.16
.16
.16
.20
.19
.28 .
.14
PERCENT
WEIGHT
12.
12.
12.
12.
12.
12.
12.
12.
50
50
50
50
50
50
50
50
SUM TOTAL 100.00
DATE s-04-21-1988
B-64
-------
PROFILE NAME:Organic Chemical Storage - Fixed Roof Tanks
Carboxylic Acids - Average
PROFILE NUMBER:9034
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407040XX
SCC : No SCC
SAROAD
NUMBER
CAS
NUMBER-
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43403 64-41-6
43404 69-91-7
43405 79-90-4
43407 79-91-7
43409 124-40-9
FORMIC ACID
ACETIC ACID
PROPION1C ACID
ACRYLIC ACID
ADIPIC ACID
46.03
60.05
74.08
72.06
146.14
20.00
20.00
20.00
20.00
20.00
SUM TOTAL
100.00
DATE :04-21-1988
B-65
-------
PROFILE NAME:Organic Chemical Storage - Fixed Roof Tanks
Esters - Average
PROFILE NUMBER:9035
PROFILE DATA QUALITY:E
CONTROL DEvICEsNot Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407044XX
SCC
No SCC
SAROAD CAS
NUMBER NUMBER
43432 79-92-9
43434 109-96-4
43437 96-63-3
43438 140-08-5
43440 141-13-2
43451 297-78-8
43468 106-66-8
SPECIES
NAME
METHYLACETATE
N-PROPYL ACETATE
METHYL ACRYLATE
ETHYL ACRYLATE
BUTYL ACRYLATE
ISOBUTYL ISOBUTRYATE
ISOBUTYL ACRYLATE
MOL.
WEIGHT
74 . 08
102.15
86 . 09
100.11
128.17
144.21
128.19
PERCENT
WEIGHT
14.29
14.29
14.29
14.29
14.29
14.29
14.29
SUM TOTAL
100.00
DATE : 04-2.1-1988
B-66
-------
PROFILE NAME:Organic Chemical Storage - Fixed Roof Tanks
Blycol Ethers - Average
PROFILE NUMBERS9036
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407052XX
SCC
No SCC
SAROAD CAS
NUMBER NUMBER
43308 11 1-17-2
43310 109-9S-4
43373 111-14-6
43377 111-19-0
43378 111-17-3
43379 112-23-5
SPECIES
NAME
BUTYL CELLOSOLVE
METHYL CELLOSOLVE
DIETHYLENE GLYCOL
CARBITOL
METHYL CARBITOL
BUTYL CARBITOL
MOL.
WEIGHT
118.17
76.11
106.12
134.18
120.15
162.23
PERCENT
WEIGHT
16.67
16.67
16.67
16.67
16.67
16.67
SUM TOTAL
100.00
DATE :04-21-1988
B-67
-------
PROFILE NAME:Organic Chemical Storage - Fixed Roof Tanks
Glycols - Average
PROFILE NUMBER:9037
PROFILE DATA QUALITY-.E
CONTROL DEVICE:Not Applicable
REFERENCE(S)593
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407056XX
SCC : No SCC
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43374 106-66-7
DIPROPYLENE GLYCOL
134.18
SUM TOTAL
100.00
100.00
DATE SO4-21-1988
B-68
-------
PROF I LIE: NAME:; Organic Chemical Storage Fixed Roof Tanks
Halogenated Organics - Average
PROFILE NUMBER;9038
PROFILE DATA QUALI TY;; E
CONTROL DEVICESNot Applicable'
REFERENCE: (s): 93
DATA SOURCE: Average? profile developed from original profiles repre-
senting the source category 407060XX.
No SCC
SAROAD CAS
NUMBER NUMBER
43804 56-62-5
43837 106-69-4
43S63 106-63-8
4 5 ฃ3 10 100-04-7
SPECIES
NAME
CARBON TETRACHLOR I DE
ETHYLENE D I BROMIDE
EPICHLOROHYDRIN
BENZYL CHLORIDE
MOL .
WEIGHT
153.34.
137.88
92 53
126.59
PERCENT
WEIGHT
25 00
25 00
25 ,,00
25 00
SUM TOTAL
100.00
DATE ;05-03-1988
B-69
-------
PROFILE NAMEsOrganic Chemical Storage - Fixed Roof Tanks
Isocyanat.es - Average
PROFILE NUMBER:9039
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407064XX
SCC
No SCC
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
45731 26471-16-5
TOLUENE DIISOCYANATE
174.17
SUM TOTAL
100.00
100.00
DATE :04-21-1988
B-70
-------
PROFILE NAMEsOrganic Chemical Storage - Fixed Roof Tanks
Ketones - Average
PROFILE NUMBER 59040
PROFILE DATA QUALITY:E
CONTROL DEVICErNot Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407068XX
SCC : No SCC
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43561 108-89-1 CYCLOHEXANONE 98,15 50.00
43562 110-04-0 METHYL AMYL KETONE 114.21 50,00
SUM TOTAL 100.00
DATE :04-21-1988
B-71
-------
PROFILE NAMEsOrganic Chemical Storage - Floating Roof Tanks
Aldehydes -- Average
PROF ILE NUMBER : 904.1
PROFILE DATA QUALITY:E
CONTROL DEVICE:Not Applicable
REFERENCE(S)s93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407172XX
SCC : No SCC
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43502 50-00-0 FORMALDEHYDE 30.03 25.00
43504 123-33-6 PROPIONALDEHYDE 58.08 25.00
43510 123-37-8 BUTYRALDEHYDE 72.12 25.00
43511 78-88-2 ISOBUTYRALDEHYDE 72.11 25.00
SUM TOTAL .100.00
B-72
DATE 504-21-1988
-------
PROFILE NAMEsOrganic Chemical Storage Floating Roof Tanks
Alkanes - Average
PROFILE NUMBER:9042
PROFILE DATA QUALITY:E
CONTROL DEVICEsNot Applicable
REFERENCE(S)t93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407176XX
SCC
No SCC
SAROAD
NUMBER
CAS
NUMBER
SPECIES
NAME
MOL.
WEIGHT
PERCENT
WEIGHT
43231 110-05-3
43248 43-32-8
HEXANE
CYCLOHEXANE
86.17
84.16
SUM TOTAL
50.00
50.00
100.00
DATE :04-21-1988
B-73
-------
PROFILE NAME:Organic Chemical Storage - Floating Roof Tanks
Ethers - Average
PROFILE NUMBER:9043
PROFILE DATA QUALITYlE
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407208XX
SCC
No SCC
SAROAD
NUMBER
43351 60-
43602 75-
CAS
NUMBER
-02-7
-55-9
SPECIES
NAME
ETHYL ETHER
PROPYLENE OXIDE
MOL.
WEIGHT
74.12
58 . 08
PERCENT
WEIGHT
50 . 00
50 . 00
SUM TOTAL
100,00
DATE :04-21-1988
B-74
-------
PROFILE NAME:Qrganic Chemical Storage - Floating Roof Tanks
Halogenated Organics - Average
PROFILE NUMBER:9044
PROFILE DATA QLJALITYsE
CONTROL DEVICEsNot Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407220XX
SCC s No SCC
SAROAD CAS SPECIES MOL. PERCENT
NUMBER NUMBER NAME WEIGHT WEIGHT
43803 67-76-3 CHLOROFORM ' 119.39 50.00
43804 56-62-5 CARBON TETRACHLORIDE 153.84 50.00
SUM TOTAL 100.00
DATE :04-21-1988
B-75
-------
PROFILE NAME:Organic Chemical Storage - Pressure Tanks -
Alkenes - Average
PROFILE NUMBER:9046
PROFILE DATA QUALITYsE
CONTROL DEVICE:Not Applicable
REFERENCE(S):93
DATA SOURCE:Average profile developed from original profiles repre-
senting the source category 407820XX
SCC
No SCC
SAROAD CAS
NUMBER NUMBER
43224 109-96-1
43243 78-87-5
43292 142-22-0
45750 504-46-9
90011
SPECIES
NAME
1-PENTENE
ISOPRENE
CYCLOPENTENE
PIPERYLENE
METHYLALLENE
MOL.
WEIGHT
70.13
68.12
68.11
68.12
54.09
PERCENT
WEIGHT
20 . 00
20 . OO
20 . 00
20 . 00
20 . 00
SUM TOTAL
100.00
DATE :04-21-1988
B-76
-------
PROFILE NAME:Organic Solvent.Evaporation Miscellaneous- Average
PROF I L..E NUMBER ; 9047
PROFILE DATA GUALITYsE
CONTROL DEVICE:Nat Applicable
REFERENCE(S):93
DATA SOURCEsAverage profile developed from original profiles repre-
senting the source category 490XXXXX.
SCC : No SCC
SAROAD CAS
NUMBER NUMBER
43369
43370
43441
45300
45503
45801
45805
46210
57-75-6
107- 72-1
80--06-6
108-89-2
98-80-1
108-89-7
95-55-1
8001-15-9
SPECIES
NAME
PROPYL.ENE BLYCOL
ETHYLENE GLYCOL
METHYL. METHACRYLATE
PHENOL
2-FURFURAL
CHLOROBENZENE
0-D I CHLOROBENZENE
CREOSOTE
MOL .
WEIGHT
76. 00
62 . 07
100,, 13
94.11
96 . 09
112.56
147.0.1 -
130.19
PERCENT
WEIGHT
12.
12.
12.
12 .
12.
12.
12.
12,
50
50
50
50
50
50
50
50
SUM TOTAL
.100 .00
DATE ;05-02-1988
B-77
-------
APPENDIX C
VOC PROFILE ASSIGNMENTS
-------
APPENDIX C
VOC PROFILE ASSIGNMENTS
The activities where VOC species profiles are applied typically employ
Source Classification Codes (SCC's) for point sources and area source codes
from the National Emissions Data System (NEDS) to represent the emission
source categories. Ideally, each source category would be characterized by
an appropriate VOC (and/or PM) profile. However, there are a limited number
of VOC species profiles that represent a relatively small number of source
categories. To increase the usefulness of a given VOC profile and to
characterize those source categories for which there are no profiles, VOC
profile assignments are made based on engineering judgement.
For several SCC's in the Criteria Pollutant Emission Factor document,
the VOC emission factor is designated as "zero" or "negligible."
Profile 0000 was assigned to these categories. As described in Appendix B,
Profile 0000 is an overall average of all the profiles in the VOC species
profile data base. It is intended for use as a default profile in
large-scale computer applications of the VOC data base for developing
emission inventories. In such applications, the "zero" profile will not be
used unless nonzero VOC emissions are reported by the States or any other
agency for an SCC which is designated in the Criteria Pollutant Emission
Factor document as having a "zero" or "negligible" emission factor. For
some SCC's, profile assignments were made although the VOC emission factor
was "zero" or "negligible." These SCC's involved profiles with high data
quality levels. "
There were several cases where it was not possible to make an
assignment based on engineering judgement. For these cases,
industry-specific average profiles were developed from original profiles
representing individual SCC's within the particular industry group.
Table C-l is the listing of all the point source categories that are
characterized by the VOC profiles included in this document. Descriptions
of the source categories represented by SCC's can be obtained from "Criteria
C-l
-------
Pollutant Emission Factors for the 1985 NAPAP Emissions Inventory"
(EPA-600/7-87-015). Table C-2 is the listing for the area source codes. In
addition to the area source codes from NEDS, profile assignments are
provided for additional area source codes used in the National Acid
Precipitation Assessment Program (NAPAP). A listing of area source codes
and their descriptions are presented in Table C-3.
The entry "Data Quality" in the two tables is based on the Profile Data
Quality description. Where the VOC profile assignment is based on an
original profile, this parameter reflects the Profile Data Quality as it
appears in Section 3. In cases where the assignment is based on engineering
judgement (as indicated by an asterisk [*]), the data quality is lowered one
or more levels, depending on how well the profile represents the "new"
source category. If an original profile represents a pure compound, then
the data quality is kept the same when this profile is used to represent the
source categories describing the storage of that compound. For
industry-specific average profiles,, the data quality level associated with
the assignment is "E." These profiles are recommended for use only if there
is no other information available.
C-2
-------
TABLE C-l. POINT SOURCE PROFILE ASSIGNMENTS
Page No.
04/19/88
sec
10100101
10100102
10100201
10100202
10100203
10100204
10100205
10100212
10100217
10100221
10100222
10100223
10100224
10100225
10100226
10100301
10100302
10100303
10100304
10100306
10100401
10100404
10100405
10100406
10100501
10100504
10100505
10100601
10100602
10100604
10100701
10100702
10100801
10100901
10100902
10100903
10101001
10101002
10101101
10101201
10101301
10101302
PROFILE
NUMBER
1178*
1178*
1178*
1178
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
0001
0001*
0001*
0001*
0002
0002*
0002*
0003
0003*
0003*
0004*
0004*
0005*
1084*
1084*
1084*
0003*
0003*
0003*
0122*
0122*
0001*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
B
C
C
C
B
C
C
B
C
C
D
D
C
E
E
E
C
C
C
E
E
C
C - 3
-------
Page No.
04/19/88
TABLE C-l. (Continued)
sec
10200101
10200107
10200201
10200202
10200203
10200204
10200205
10200206
10200210
10200212
10200213
10200217
10200219
10200221
10200222
10200223
10200224
10200225
10200226
10200229
10200301
10200302
10200303
10200304
10200306
10200307
10200401
10200402
10200403
10200404
10200405
10200501
10200502
10200503
10200504
10200505
10200601
10200602
10200603
10200604
10200701
10200704
PROFILE
NUMBER
1185*
1185*
1185*
1185*
1185*
1185
1185*
1185*
1185*
1185*
1085
1185*
1185*
1185*
1185*
1185*
1185*
1185*
1185*
1185*
1165*
1185*
1185*
1185*
1185*
1185*
0001
0001*
0001*
0001*
0001*
0002
0002*
0002*
0002*
0002*
0003
0003*
0003*
0003*
0004
0004*
QUALITY
E
E
E
E
E
D
E
E
E
E
C
E
E
E
E
E-
E
E
E
E
E
E
E
E
E
E
B
C
C
C
C
B
C
C
C
C
B
C
C
C
C
D
C - 4
-------
Page No.
04/19/88
TABLE C-l. (Continued)
sec
10200707
10200710
10200799
10200802
10200804
10200901
10200902
10200903
10200904
10200905
10200906
10200907
10201001
10201002
10201101
10201201
10201301
10201302
10201401
10201402
10201403
10201404
10300101
10300102
10300103
10300205
10300206
10300207
10300208
10300209
10300211
10300214
10300216
10300217
10300221
10300222
10300223
10300224
10300225
10300226
10300305
PROFILE
NUMBER
0005
0004*
0004*
0005*
0005*
1084*
1084*
1084*
1084*
1084*
1084*
1084*
0003*
0003*
1084*
0122*
0122*
-0001*
0003*
0004*
0002*
0001*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
1178*
QUALITY
B
D
0
C
C
E
E
E.
E
E
E
E
C
C
E
E
E
C
C
D
C
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 5
-------
Page No.
04/19/88
TABLE C-l. (Continued)
sec
10300306
10300307
10300309
10300401
10300402
10300403
10300404
10300501
10300502
10300503
10300504
10300601
10300602
10300603
10300701
10300799
10300901
103009t)2
10300903
10301001
10301002
10301201
10301301
10301302
10301303
10500102
10500105
10500106
10500110
10500202
10500205
10500206
10500209
10500210
20100101
20100102
20100201
20100202
20100702
20100901
20100902
20101001
PROFILE
NUMBER
1178*
1178*
1178*
0001
0001*
0001*
0001*
0002
0002*
0002*
0002*
0003
0003*
0003*
0004*
0004*
1084*
1084*
1084*
0003*
0003*
0122*
0122*
0001*
0122*
1178*
0002*
0003
0003*
1178*
0002
0003
1084*
0003*
1098*
0009
0007*
1001
1001*
1098*
1098*
0000
QUALITY
E
E
E
B
C
C
C
B
C
C
C
B
C
C
0
D
D
D
D
C
C
E
E
C
E
E
C
B
E
E
B
B
D
C
C
D
D
C
0
C
C
E
C - 6
-------
Page No.
04/19/88
TABLE C-l. (Continued)
sec
20200101
20200102
20200103
20200104
20200201
20200202
20200203
20200204
20200301
20200401
20200402
20200403
20200501
20200901
20200902
20201001
2020-1002
20300101
20300102
20300201
20300202
20300301
20301001
20301002
20400101
20400102
20400201
20400301
20400302
20400401
20400402
28888801
28888802
28888803
30100101
30100102
30100103
30100104
30100105
30100106
30100107
30100108
PROFILE
NUMBER
1098*
0009
1098*
0009*
0007
1001
0007*
1001
1101*
0008
1201*
1201*
0009*
1098*
1098*
1001*
1001*
0009
1098*
1001
1001*
1101*
1001*
1001*
1098*
1098*
9002
0007*
1001*
1101*
0008
9002
9002
9002
1110
1110
0299
0000
1110
0000
1110
0000
QUALITY
C
0
C
E
C
C
0
C
C
C
D
D
E
C
C
D
D
0
C
C
0
C
0
0
C
C
E
0
D
C
C
E
E
E
E
E
E
E
E
E
E
E
C - 7
-------
Page No.
04/19/88
TABLE C-l. (Continued)
sec
30100109
30100180
30100199
30100305
30100306
30100307
30100308
30100309
30100399
30100501
30100502
30100503
30100504
30100506
30100507
30100508
30100509
30100599
30100601
30100603
30100604
30100605
30100699
30100799
30100801
30100802
30100803
30100804
30100805
30100899
30100901
30100902
30100910
30100999
30101011
30101012
30101013
30101014
30101015
30101021
30101022
30101023
PROFILE
NUMBER
0000
1110
1110
9004
0003*
0001*
9004
9004
9004
1002*
0000
1002*
1002
0000
0003*
0000
0000
1002*
0307*
0307*
0307*
0000
9004
9004
0000
0000
0000
0000
0000
9004
9017
9017
9017
9017
0000
0000
0000
0000
0122*
0000
0000
0122*
QUALITY
E
E
E
E
C
C
E
E
E
E
E
E
D
E
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 8
-------
Page No.
04/19/88
TABLE C-l. (Continued)
sec
30101030
30101099
30101101
30101198
30101199
30101202
30101203
30101204
30101205
30101206
30101299
30101301
30101302
30101303
30101304
30101399
30101401
30101402
30101499
30101501
30101502
30101503 -
30101505
30101599
30101601
30101602
30101603
30101699
30101702
30101703
30101704
30101705
30101706
30101707
30101708
30101799
30101801
30101802
30101803
30101805
30101807
30101808
PROFILE
NUMBER
0122*
0122*
0000
0000
9004
0003*
0000
0000
0000
9004
9004
0000
0000
0000
0000
9004
1094
0000
1094*
0066
0066*
0066*
0066*
0066*
0000
0000
0000
9004
0000
0000
0000
0000
0000
0000
0000
9004
1091
0068
0068*
1056*
1056*
1056*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
E
D
E
E
E
C - 9
-------
TABLE C-l. (Continued)
Page No.
04/19/88
8
sec
30101809
30101810
30101811
30101812
30101813
30101814
30101815
30101816
30101817
30101818
30101819
30101820
30101821
30101822
30101827
30101832
30101837
30101838
30101839
30101840
30101842
.30101847
30101849
30101852
30101860
30101861
30101863
30101864
30101865
30101866
30101870
30101871
30101872
30101880
30101881
30101882
30101883
30101884
30101885
30101890
30101891
30101892
PROFILE
NUMBER
1056*
1056*
1056*
1056*
1056*
1056*
0000
0000
1004
0000
1004*
0000
0000
1009*
1009*
1004*
1005
1005*
1005*
1005*
1005*
1005*
1009
1040*
1056*
1056*
1056*
0000
0000
0000
1005*
0000
1005*
1005*
0000
0000
0000
0000
1005*
9005
9005
9005
QUALITY
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
E
E -
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 10
-------
Page No.
04/19/88
TABLE C-l. (Continued)
sec
30101893
30101894
30101899
30101901
30101902
30101904
30101905
30101906
30101907
30102001
30102002
30102003
30102004
30102005
30102099
30102101
30102102
30102103
30102104
30102105
30102106
30102107
30102108
30102110
30102111
30102112
30102113
30102120
30102199,
30102201
30102301
30102304
30102306
30102308
30102310
30102312
30102314
30102316
30102318
30102319
30102320
30102321
PROFILE
NUMBER
9005
9005
9005
1006
0000
1006*
0000
0000
1006*
0072
9026
9026
9026
9026
9026
0000
0000
0000
0003*
1185*
0000
0000
0000
0003*
0003*
0000
0000
0003*
9004
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
QUALITY
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
C
E
E
E
E
C
C
E
E
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 11
-------
TABLE C-l. (Continued)
Page No.
04/19/88
10
sec
30102322
30102399
30102401
30102402
30102405
30102410
30102414
30102415
30102416
30102421
30102422
30102423
30102424
30102425
30102426
30102427
30102499
30102501
30102505
30102599
30102601
30102602
30102608
30102609
30102610
30102611
30102612
30102613
30102614
30102615
30102616
30102617
30102625
30102630
30102699
30102701
30102704
30102705
30102706
30102707
30102708
30102709
PROFILE
NUMBER
0000
0000
1092
1005*
1040*
1009*
0068*
1091*
1061*
9006
9006
9006
9006
0000
0000
9006
9006
0000
1045*
0000
0274
0274*
0274*
0274*
0000
0000
0000
0274*
0274*
0274*
0274*
0274*
0274*
0274*
0274*
0000
0000
0000
0000
0000
0000
0000
QUALITY
E
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
D
0
D
E
E
E
D
D
D
D
D
D
D
D
E
E
E
E
E
E
E
C - 12
-------
TABLE C-l. (Continued)
Page No.
04/19/88
11
sec
30102710
30102711
30102712
30102713
30102714
30102717
30102718
30102720
30102721
30102722
30102723
30102724
30102725
30102727
30102728
30102729
30102730
30102801
30102803
30102804
30102805
30102806
30102807
30102820
30102821
30102822
30102823
30102824
30102825
30102903
30102904
30102905
30102906
30102907
30102908
30102920
30102921
30102922
30102923
30102924
30102925
30103001
PROFILE
NUMBER
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0003*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
0
C - 13
-------
TABLE C-l. (Continued)
Page No.
04/19/88
12
sec
30103002
30103003
30103004
30103020
30103021
30103022
30103023
30103024
30103025
30103099
30103101
30103102
30103103
30103104
30103105
30103199
30103201
30103202
30103203
30103204
30103299
30103301
30103311
30103312
30103399
30103402
30103403
30103404
30103405
30103406
30103410
30103411
30103412
30103414
30103415
30103420
30103425
30103430
30103435
30103499
30103501
30103502
PROFILE
NUMBER
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
1024*
1024*
1023
1024
1025
1024*
9004
9004
9004
9004
9004
0076*
0076
0076
0076*
1036*
1036*
1036*
1036*
1036*
1036*
0000
0000
1092*
1132
1092*
1092*
1132
1092*
- 1092*
0000
0000
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
E
E
E
E
E
D
C
C
D
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
C - 14
-------
TABLE C-l. (Continued)
Page No.
04/19/88
13
sec
30103503
30103506
30103507
30103510
30103515
30103520
30103550
30103551
30103552
30103553
30103554
30103599
30103801
30103901
30103902
30103903
30104001
30104002
30104003
30104004
30104005
30104006
30104007
30104008
30104009
30104010
30104011
30104012
30104013
30104101
30104102
30104103
30104104
30104199
30104201
30104202
30104203
30104204
30104301
30104501
30105001
30106001
PROFILE
NUMBER
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
9004
9004
9004
0000
0000
0000
0000
0000
9004
0000
0000
0000
0000
0000
9004
9004
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0202*
0000
0000
9021
9004
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
C - 15
-------
TABLE C-l. (Continued)
Page No.
04/19/88
14
sec
30106002
30106003
30106004
30106005
30106006
30106007
30106008
30106009
30106010
30106011
30106012
30106099
30107001
30107002
30109101
30109105
30109110
30109151
30109152
30109153
30109154
30109180
30109199
30110002
30110003
30110004
30110005
30110099
30111103
30111199
30111201
30111202
30111299
30112001
30112002
30112005
30112006
30112007
30112011
30112012
30112013
30112014
PROFILE
NUMBER
0000
9004
9004
9004
9004
9004
9004
9004
9004
9004
9004
9004
0000
0000
1028*
1027
1027*
1028*
1028*
1028
1029
1028*
0221
1062
1062*
0000
1062*
1062*
9011
9011
0000
0000
9004
1030*
1030*
1030
1030*
1030*
1032*
1032*
1032*
1032*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
D
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
C - 16
-------
TABLE C-l. (Continued)
Page No.
04/19/88
15
sec
30112017
30112021
30112031
30112032
30112033
30112034
30112037
30112099
30112199
30112401
30112402
30112403
30112404
30112405
30112406
30112407
30112480
30112501
30112502
30112504
30112505
30112506
30112509
30112510
30112511
30112512
30112514
30112515
30112520
30112521
30112522
30112524
30112525
30112526
30112527
30112528
30112529
30112530
30112531
30112532
30112533
30112534
PROFILE
NUMBER
1032*
1032*
1032*
1032*
1032
1032*
1032*
1033
1032*
1034*
1034*
1034*
0000
0000
1035
1035
1034*
1038
0078
1039
0000
1037
1038*
1070*
1070*
1070*
1070*
0000
0085
0085
0085
0085
0087
0087
0087
0087
0087
0271
0271
0271
0271
0271
QUALITY
E
E
E
E
E
E
E
D
E
E
D
E
E
E
E
E
E
0
C
c
E
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 17
-------
TABLE C-l. (Continued)
Page No.
04/19/88
16
sec
30112535
30112540
30112541
30112542
30112543
30112544
30112545
30112546
30112547
30112550
30112551
30112552
30112553
30112555
30112599
30112699
30112701
30112702
30112703
30112720
30112730
30112740
30112780
30113004
30113005
30113201
30113205
30113210
30113221
30113222
30113223
30113224
30113227
30113299
30113301
30113302
30113303
30113380
30113701
30113710
30113799
30114001
PROFILE
NUMBER
1072
1091*
0000
1091*
1091*
1091*
1091*
1091*
0000
1091*
1091*
1091*
1091*
1091*
0078
9004
1040
1041
0000
1090
1093
0277
1042
0003*
0003*
1070*
9004
1032*
1043*
1043*
1043*
1043*
1043*
1044
1045*
1045*
1045
1045*
1046
1047
9004
0000
QUALITY
D
E
E
E
E
E
E
E
E
E
E
E
E
E
C
E
- D
D
E
D
D
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
D
E
C
E
E
E
C - 18
-------
TABLE C-l. (Continued)
Page No.
04/19/88
17
sec
30114002
30114003
30114004
30114005
30115201
30115301
30115310
30115311
30115312
30115320
30115321
30115322
30115380
30115601
30115602
30115603
30115604
30115605
30115606
30115607
30115680.
30115701
30115702
30115704
30115780
30115801
30115802
30115803
30115821
30115822
30115880
30116701
30116702
30116703
30116704
30116780
30116799
30116901
30116902
30116903
30116904
30116905
PROFILE
NUMBER
0000
0000
1120
1120
0000
1034*
1034*
1034*
1034*
1034*
1034*
1034*
1034*
1048*
1062*
1048*
1048*
1062*
1048
1048*
1048*
1049
0000
0000
1049*
1050*
1050*
. 1050*
1050*
1050
1050*
1052*
1051
1052
1053
1052*
1054
1062*
0000
0000
0000
0000
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
D
D
E
C
D
D
D
E
E
E
E
E
E
E
E
E
D
C
C
E
D
E
E
E
E
E
E
C - 19
-------
TABLE C-l. (Continued)
Page No.
04/19/88
18
sec
30116906
30116980
30117401
30117402
30117410
30117411
30117421
30117480
30117601
30117610
30117611
30117612
30117613
30117614
30117615
30117616
30117617
30117618
30117630
30117631
30117632
30117633
30117634
30117680
30118101
30118102
30118103
30118104
30118105
30118106
30118107
30118108
30118109
30118110
30118180
30119001
30119002
30119003
30119004
30119010 .
30119011
30119012
PROFILE
NUMBER
0000
1062*
1057*
1057*
1056
' 1057
1058
1057*
9004
9004
0000
0000
0000
0000
0000
9004
0000
9004
9004
9004
9004
9004
9004
9004
1176
1176
1176
1176
1176
1077*
1176
1176
0000
0000
1176
1059*
1059*
1059*
1059*
1059
1059*
1059
QUALITY
E
E
E
E
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
D
C - 20
-------
TABLE C-l. (Continued)
Page No.
04/19/88
19
sec
30119013
30119014
30119080
30119501
30119502
30119503
30119504
30119505
30119506
30119580
30119701
30119705
30119706
30119707
30119708
30119709
30119710
30119741
30119742
30119743
30119744
30119745
30119749
30119799
30120201
30120202
30120203
30120204
30120205
30120206
30120210
30120211
30120280
30120501
30120502
30120503
30120504
30120505
30120506
30120507
30120508
30120509
PROFILE
NUMBER
1060
1060
1059*
1062*
1061
1062*
1061
1062
1062*
1062*
1064*
9004
0000
9004
9004
9004
9004
1064*
0000
1064*
0000
1064
1064*
9004
1082*
1082
1082
1082
1029*
1082
1082
1082
1082
1065*
1065
1065*
1065*
1065
1065*
1065*
1065*
0000
QUALITY
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
E
E
E
E
C
E
E
E
D
D
D
D
D
D
D
D
E
D
E
E
D
E
E
E
E
C - 21
-------
TABLE C-l. (Continued)
Page No.
04/19/88
20
sec
30120520
30120521
30120522
30120523
30120524
30120525
30120526
30120527
30120528
30120529
30120530
30120531
30120532
30120540
30120541
30120542
30120543
30120544
30120545
30120546
30120547
30120548
30120549
30120550
30120551
30120552
30120553
30120554
30120555
30120580
30120601
30120602
30120603
30120680
30121001
30121002
30121003
30121004
30121005
30121006
30121007
30121008
PROFILE
NUMBER
1173
1173
1173
0000
1173
1173
1173
1173
1173
1173
1173
1173
1173
1173
1173
1173
0000
1173
1173
0068*
1173
1173
1173
1173
1173
1173
1173
1173
1173
1173
1066
1067
1068
1066*
9004
9004
9004
0000
9004
9004
9004
9004
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
'E
E
E
E
E
D
D
E
E
E
E
E
E
E
E
E
E
C - 22
-------
TABLE C-l. (Continued)
Page No.
04/19/88
21
sec
30121009
30121010
30121080
30121101
30121102
30121103
30121104
30121121
30121122
30121123
30121124
30121125
30121180
30125001
30125002
30125003
30125004
30125005
30125010
30125015
30125020
30125021
30125025
30125099
30125101
30125102
30125103
30125104
30125180
30125201
30125301
30125302
30125305
30125306
30125315
30125316
30125325
30125326
30125380
30125401
30125405
30125406
PROFILE
NUMBER
9004
9004
9004
1062*
1062*
1062*
1062
1062*
1062*
1062
1062*
1062*
1062*
1070*
1070
1071
1070*
0226
0226
0000
9007
9007
9007
9007
1078*
1078*
1078*
0000
1078*
1136
9004
9004
1070*
1070*
0226
0226
1027*
1027*
9004
9004
1109
1009*
QUALITY
E
E
E
E
E
E
D
E
E
D
E
E
E
E
C
D
D .
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
E
E
E
E
E
E
C - 23
-------
TABLE C-l. (Continued)
Page No.
04/19/88
22
sec
30125407
30125408
30125409
30125410
30125411
30125412
30125413
30125415
30125416
30125417
30125418
30125420
30125499
30125801
30125802
30125803
30125805
30125806
30125807
30125810
30125815
30125816
30125817
30125880
30125899
30130101
30130102
30130103
30130104
30130105
30130106
30130107
30130108
30130110
30130135
30130180
30130201
30130202
30130203
30130280
30130301
30130302
PROFILE
NUMBER
1109
1109
1109
1110
0000
1110
1110
1034*
1110
0000
1110
1110
9004
1073*
1073*
1062
0090
0090
0090
1174
0223
0223
0223
0223
0223
1072
1073
1073*
1072*
1074
1075
1076
1077
0000
1072*
1072*
1119
1119
1119
1119
9004
9004
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
D
D
E
E
D
D
E
E
E
E
E
E
E
E
E
E
E
C - 24
-------
TABLE C-l. (Continued)
Page No.
04/19/88
23
SCC
30130303
30130304
30130305
30130380
30130401
30130402
30130403
30130404
30130405
30130480
30130501
30130502
30130503
30130504
30130505
30130580
30180001
30181001
30182001
30183001
30184001
30187001
30187002
30187003
30187004
30187005
30187006
30187007
30187008
30187009
30187010
30187097
30187098
30187501
30187502
30187597
30187598
30188501
30188502
30188503
30188504
30188505
PROFILE
NUMBER
9004
9004
9004
9004
9004
9004
9004
9004
9004
9004
1131
1131
1131
1131
1131
1131
9004
9004
9004
9004
9004
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
.E
E
E
E
E
E
E
E
E
E
E
E
C - 25
-------
TABLE C-l. (Continued)
Page No.
04/19/88
24
sec
30188599
30188801
30188802
30188803
30188804
30188805
30190001
30190002
30190003
30190004
30190011
30190012
30190013
30190014
30190099
30199998
30199999
30200101
30200102
30200103
30200104
30200199
30200201
30200202
30200203
30200299
30200301
30200401
30200402
30200403
30200404
30200410
30200501
30200502
30200503
30200504
30200505
30200506
30200507
30200508
30200509
30200510
PROFILE
NUMBER
0000
9004
9004
9004
9004
9004
0002*
0001*
0003*
0004*
0002*
0001*
0003*
0004*
0079
9004
- 9004
9008
0000
0000
0000
9008
1032*
1032*
0000
9008
0000
0000
0000
0000
0000
0000
9008
9008
0000
0000
0000
0000
0000
0000
0000
0000
QUALITY
E
E
E
E
E
E
C
C
C
D
C
C
C
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 26
-------
TABLE C-l. (Continued)
Page No. 25
04/19/88
PROFILE
SCC NUMBER QUALITY
30200511 0000 E
30200512 0000 E
30200601 9008 E
30200602 9008 E
30200603 0000 E
30200604 0000 E
30200605 0000 E
30200606 0000 E
30200607 0000 E
30200608 0000 E
30200609 0000 E
30200610 0000 E
30200611 0000 E
30200699 9008 E
30200701 9008 E
30200702 9008 E
30200703 0000 E
30200704 0000 E
30200705 0000 E
30200711 0000 E
30200712 0000 E
30200713 0000 E
30200714 0000 E
30200721 0000 E
30200722 0000 E
30200723 0000 E
30200724 0000 E
30200731 0000 E
30200732 0000 E
30200733 0000 E
30200734 0000 E
30200741 0000 E
30200742 0000 E
30200743 0000 E
30200744 0000 E
30200745 0000 E
30200751 0000 E
30200752 0000 E
30200753 0000 E
30200754 0000 E
30200755 0000 E
30200756 0000 E
C - 27
-------
TABLE C-l. (Continued)
Page No.
04/19/88
26
sec
30200760
30200771
30200772
30200773
30200774
30200781
30200782
30200783
30200784
30200785
30200786
30200787
30200788
30200789
30200790
30200791
30200799
30200801
30200802
30200803
30200804
30200805
30200806
30200899
30200901
30200902
30200903
30200904
30200905
30200998
30200999
30201001
30201002
30201003
30201004
30201103
30201104
30201105
30201106
30201199
30201201
30201202
PROFILE
NUMBER
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
9008
9008
0000
0000
0000
0000
0000
9008
0000
1188*
0000
0000
0000
1188*
1188*
0000
1188
1188
1188
0000
1188*
1188*
1188*
1188*
9008
9008
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E .
E
E
E
E
E
E
E
E
E
E
E
D
- E
E
E
D
D
E
C
C
C
E
D
D
D
D
E
E
C - 28
-------
TABLE C-l. (Continued)
Page No.
04/19/88
27
sec
30201203
30201204
30201205
30201206
30201301
30201401
30201501
30201599
30201601
30201699
30201799
30201899
30201901
30201902
30201903
30201904
30201906
30201907
30201908
30201909
30201911
30201912
30201913
30201914
30201915
30201916
30201917
30201918
30201919
30201920
30201999
30202001
30202002
30202101
30202102
30202105
30202106
30202201
30202601
30202801
30203001
30203099
PROFILE
NUMBER
9008
9008
9008
9008
1084*
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
0000
0000
0000
0000
9008
0000
9008
9008
9008
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 29
-------
TABLE C-l. .(Continued)
Page No.
04/19/88
28
sec
30203103
30203104
30203105
30203106
30203107
30203108
30203109
30203110
30203111
30203201
30203202
30203299
30203399
30203601
30203801
30288801
30288802
30288803
30288804
30288805
30290001
30290002
30290003
30299998
30299999
30300001
30300002
30300101
30300102
30300103
30300104
30300105
30300106
30300107
30300108
30300109
30300110
30300111
30300199
30300201
30300302
30300303
PROFILE
NUMBER
0000
0000
0000
0000
0000
0000
0000
0000
0000
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
9008
0002*
0001*
0003*
9008
9008
0000
0025*
1202*
1202
1202
0000
1202*
0000
1202*
0000
0000
0000
0000
0011*
0003*
0011
0011
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
C
E
E
E
E
E
D
0
E
E
E
E
E
E
E
E
E
C
C
C
C - 30
-------
TABLE C-l. (Continued)
Page No.
04/19/88
29
sec
30300304
30300305
30300306
30300307
30300308
30300309
30300310
30300311
30300312
30300313
30300314
30300315
30300316
30300399
30300401
30300502
30300503
30300504
30300505
30300506
30300507
30300508
30300509
30300510
30300511
30300512
30300513
30300514
30300515
30300516
30300517
30300518
30300521
30300522
30300523
30300524
30300525
30300526
30300527
30300528
30300599
30300601
PROFILE
NUMBER
0011
0011
0011
0000
0011*
0000
0000
0000
0000
0011*
0011*
0000
0000
0011*
0011*
0016*
. 0016*
0000
0000
0016*
0016*
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
9009
0016*
QUALITY
C
C
C
E
E
E
E
E
E
D
D
E
E
E
D
D
D
E
E
0
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
C - 31
-------
TABLE C-l. (Continued)
Page No.
04/19/88
30
sec
30300602
30300603
30300604
30300605
30300610
30300611
30300613
30300614
30300615
30300616
30300617
30300699
30300701
30300702
30300703
30300704
30300801
30300802
30300804
30300805
30300808
30300809
30300811
30300812
30300813
30300814
30300815
30300816
30300817
30300818
30300819
30300820
30300821
30300822
30300823
30300824
30300825
30300826
30300827
30300831
30300832
30300833
PROFILE
NUMBER
0016*
0016*
0016*
0016*
0000
0016*
0000
0000
0016*
0016*
0016*
0016*
0016*
0016*
0016*
0016*
0012
0012
0000
0000
0000
0000
0013*
0000
0013
0000
0000
0000
0000
0000
0013*
0000
0000
0013*
0000
0013*
9009
0000
0000
0000
0000
0000
QUALITY
D
D
D
D
E
D
E
E
D
D
D
D
D
D
D
D
E
E
E
E
E
E
D
E
C
E
E
E
E
E
0
E
E
D
E
D
E
E
E
E
E
E
C - 32
-------
TABLE C-l. (Continued)
Page No.
04/19/88
31
sec
30300834
30300899
30300901
30300904
30300906
30300907
30300908
30300910
30300911
30300912
30300913
30300914
30300915
30300916
30300917
30300918
30300919
30300921
30300922
30300923
30300924
30300925
30300931
30300932
30300933
30300934
30300935
30300936
30300998
30300999
30301001
30301002
30301003
30301004
30301005
30301006
30301007
30301008
30301009
30301010
30301011
30301012
PROFILE
NUMBER
0000
9009
0014
0016*
0014*
0014*
0014*
0000
0014*
0000
0016
0016
1089*
0012*
0012*
0012*
0012*
1089*
0000
1089*
0000
1089*
1004*
0000
1009*
0003*
1089*
1089*
9009
9009
0000
0000
0000
0000
0000
0000
0000
0000
1089*
0000
0000
0000
QUALITY
E
E
C
D
D
D
D
E
D
E
C
C
C
D
D
D
D
C
E
C
E
C
E
E
E
D
C
C
E
E
E
E
E
E
E
E
E
E
C
E
E
E
C - 33
-------
TABLE C-l. (Continued)
Page No.
04/19/88
32
sec
30301013
30301014
30301015
30301016
30301017
30301018
30301019
30301020
30301021
30301022
30301023
30301024
30301025
30301026
30301099
30301101
30301102
30301199
30301201
30301202
30301299
30301301
30301401
30301402
30301403
30301499
30302301
30302302
30302303
30302304
30302305
30302306
30302307
30302308
30302309
30302310
30302311
30302312
30302313
30302314
30302315
30302316
PROFILE
NUMBER
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
9009
0000
0000
9009
0000
0025*
0025*
0000
0000
0025*
0025*
9009
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0003*
0001*
1085*
0000
0000
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
D
D
E
E
C - 34
-------
TABLE C-l. (Continued)
Page No.
04/19/88
33
sec
30302321
30302322
30302401
30302402
30302403
30302404
30302405
30302406
30302407
30302408
30302409
30302410
30302411
30303002
30303003
30303005
30303006
30303007
30303008
30303009
30303010
30303011
30303012
30303014
30303015
30303016
30303099
30388801
30388802
30388803
30388804
30388805
30390001
30390002
30390003
30390004
30390011
30390012
30390013
30390014
30390023
30390024
PROFILE
NUMBER
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0025*
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
9009
9009
9009
9009
9009
9009
0002*
0001*
0003*
0004*
0002*
0001*
0003*
0004*
0051*
0079*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
C
D
C
C
C
D
E
E
C - 35
-------
TABLE C-l. (Continued)
Page No.
04/19/88
34
sec
30399999
30400101
30400102
30400103
30400104
30400105
30400106
30400107
30400108
30400109
30400110
30400111
30400112
30400113
30400114
30400120
30400150
30400199
30400204
30400207
30400208
30400209
30400210
30400211
30400212
30400214
30400215
30400217
30400219
30400220
30400221
30400223
30400224
30400230
30400231
30400232
30400233
30400234
30400235
30400236
30400237
30400238
PROFILE
NUMBER
9009
1036*
1036*
1036*
0000
0000
0000
0000
0000
1036*
9010
9010
9010
9010
1036
9010
1036*
1036*
9010
0025*
0011*
0003*
0012*
0012*
0012*
0014*
0014*
0014*
0014*
0014*
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
D
D
E
D
D
D
D
D
D
E
E
E
E
E
E
E
E
E
E
E
E
C - 36
-------
TABLE C-l. (Continued)
Page No.
04/19/88
35
sec
30400239
30400299
30400301
30400302
30400303
30400304
30400305
30400310
30400315
30400320
30400325
30400330
30400331
30400332
30400333
30400340
30400341
30400342
30400350
30400351
30400352
30400353
30400354
30400355
30400356
30400357
30400358
30400360
30400370
30400371
30400398
30400399
30400401
30400402
30400403
30400404
30400405
30400406
30400407
30400408
30400409
30400410
PROFILE
NUMBER
0000
9010
1089*
1089*
0000
1089*
1089*
1089*
0000
1089
1089*
1089*
1089*
1089*
1089*
0000
0000
0000
0000
1089*
0000
1089*
1089*
1089*
0000
0000
0000
0000
1089*
1089*
9010
9010
0000
0000
0000 -
0000
0000
1089*
1089*
0000
0000
0000
QUALITY
E
E
C
C
E
C
C
C
E
B
C
C
C
C
C
E
E
E
E
C
E
C
C
C
E
E
E
E
C
C
E
E
E
E
E
E
E
D
D
E
E
E
C - 37
-------
TABLE C-l. (Continued)
Page No.
04/19/88
36
sec
30400411
30400412
30400413
30400414
30400499
30400501
30400505
30400506
30400507
30400508
30400509
30400510
30400511
30400512
30400513
30400521
30400522
30400523
30400524
30400525
30400526
30400527
30400528
30400599
30400601
30400699
30400701
30400702
30400703
30400704
30400705
30400706
30400707
30400708
30400709
30400710
30400711
30400712
30400713
30400714
30400715
30400716
PROFILE
NUMBER
0000
0000
0000
0000
9010
9010
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
9010
1089*
9010
0014*
0014*
0014*
0014*
0000
0000
0014*
1089*
1089*
1089*
0000
0000
0000
1089*
1089*
0000
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
D
D
D
D
E
E
D
C
C
C
E
E
E
C
C
E
C - 38
-------
TABLE C-l. (Continued)
Page No.
04/19/88
37
sec
30400717
30400718
30400720
30400721
30400722
30400723
30400724
30400725
30400726
30400730
30400731
30400799
30400801
30400802
30400803
30400805
30400806
30400807
30400809
30400810
30400811
30400812
30400814
30400818
30400824
30400828
30400834
30400838
30400840
30400841 ,
30400842
30400843
30400851
30400852
30400853
30400854
30400855
30400861
30400862
30400863
30400864
30400865
PROFILE
NUMBER
1089*
1089*
1089*
0000
0000
0000
0000
0000
0000
1089*
1089*
1089
0000
1036*
1036*
1036*
1036*
1036*
1036*
1036*
1036*
0000
0000
0000
1036*
1036*
1036*
1036*
0000
1036*
1036*
1036*
0000
0000.
0000
0000
0000
1036*
1036*
1036*
1036*
1036*
QUALITY
C
C
C
E
E
E
E
E
E
C
C
B
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 39
-------
TABLE C-l. (Continued)
Page No.
04/19/88
38
sec
30400866
30400867
30400868
30400869
30400870
30400871
30400872
30400873
30400874
30400875
30400876
30400877
30400899
30400901
30400999
30401001
30401002
30401004
30401005
30401006
30401007
30401008
30401010
30401011
30401099
30402001
30402002
30402003
30402004
30402099
30402201
30402210
30404001
30404901 .
30405001
30405099
30488801
30488802
30488803
30488804
30488805
30490001
PROFILE
NUMBER
0000
1036*
1036*
1036*
1036*
0000
0000
0000
0000
0000
0000
0000
9010
1036*
1036*
0003*
0000
0003*
0000
0000
0014*
0014*
0000
0000
9010
9010
0000
0000
9001
9010
0003*
1036*
1091*
0000
9010
9010
9010
9010
9010
9010
9010
0002*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
D
E
E
D
D
E
E
E
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
E
C
C - 40
-------
TABLE C-l. (Continued)
Page No.
04/19/88
39
sec
30490002
30490003
30490004
30490011
30490012
30490013
30490014
30490023
30490024
30499999
30500101
30500102
30500103
30500104
30500105
30500110
30500111
30500112
30500113
30500198
30500199
30500201
30500202
30500203
30500204
30500205
30500206
30500207
30500208
30500299
30500301
30500302
30500303
30500304
30500307
30500308
30500309
30500311
30500312
30500313
30500314
30500315
PROFILE
NUMBER
0001*
0003*
0004*
0002*
0001*
0003*
0004*
0051*
0079*
9010
1007*
1007*
1007*
0024
0024*
1007*
1007*
0023
1007*
9011
1007*
0025
0026
1007
1007*
0000
0025*
0025*
0025*
1007*
9001
0000
0000
0003*
9001
0000
0000
0003*
0001*
1185*
0003*
0001*
QUALITY
C
C
D
C
C
C
D
D
D
E
E
E
E
C
D
E
E
D
E
E
E
D
B
C
E
E
E
E
E
E
E
E
E
C
E
E
E
C
C
E
C
C
C - 41
-------
TABLE C-l. (Continued)
Page No.
04/19/88
40
sec
30500316
30500398
30500399
30500401
30500402
30500403
30500404
30500405
30500406
30500499
30500501
30500502
30500503
30500504
30500505
30500598
30500599
30500606
30500607
30500608
30500609
30500610
30500611
30500612
30500613
30500614
30500615
30500616
30500617
30500618
30500619
30500699
30500706
30500707
30500708
30500709
30500710
30500711
30500712
30500714
30500715
30500716
PROFILE
NUMBER
1185*
9011
9011
0000
0000
0000
0000
0000
0000
9011*
9001
0000
0000
9001
9011
9011
9011
9001
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
9011
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 42
-------
TABLE C-l. (Continued)
Page No.
04/19/88
41
sec
30500717
30500718
30500719
30500799
30500801
30500802
30500803
30500899
30500901
30500902
30500903
30500904
30500905
30500906
30500907
30500908
30500909
30500910
30500999
30501001
30501002
30501003
30501004
30501005
30501006
30501007
30501008
30501009
30501010
30501011
30501012
30501013
30501014
30501015
30501016
30501017
30501021
30501022
30501023
30501024
30501030
30501031
PROFILE
NUMBER
0000
0000
0000
9011
9001
0000
0000
9011
0003*
0003*
0003*
0000
0000
0000
0000
0000
0000
0000
9011
9001
9001
9001
9001
9001
9001
9001
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
QUALITY
E
E
E
E
E
E
E
E
C
C
C
E
E
E
E
E
E
E
E
_ฃ
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 43
-------
TABLE C-l. (Continued)
Page No. 42
04/19/88
PROFILE
SCC NUMBER QUALITY
30501032 0000 E
30501033 0000 E
30501034 0000 E
30501035 0000 E
30501036 0000 E
30501037 0000 E
30501038 0000 E
30501039 0000 E
30501040 0000 E
30501041 0000 E
30501042 0000 E
30501043 0000 E
30501044 0000 E
30501045 0000 E
30501046 0000 E
30501047 0000 E
30501048 0000 E
30501049 0000 E
30501050 0000 E
30501090 0000 E
30501099 9011 E
30501101 0000 E
30501106 0000 E
30501107 0000 E
30501108 0000 E
30501109 0000 E
30501110 0000 E
30501111 0000 E
30501112 0000 E
30501113 0000 E
30501114 0000 E
30501115 0000 E
30501120 0000 E
30501199 9011 E
30501201 9011 E
30501202 9011 E
30501203 9011 E
30501204 9011 E
30501205 9011 E
30501206 9011 E
30501207 0000 E
30501208 9011 E
C - 44
-------
TABLE C-l. (Continued)
Page No. 43
04/19/88
PROFILE
SCC NUMBER QUALITY
30501209 9011 E
30501211 9011 E
30501212 9011 E
30501213 0000 E
30501214 0000 E
30501215 0000 E
30501221 0000 E
30501222 0000 E
30501223 0000 E
30501224 0000 E
30501299 9011 E
30501301 9011 E
30501399 9011 E
30501401 9011 E
30501402 9011 E
30501403 9011 E
30501404 9011 E
30501406 9011 E
30501407 0000 E
30501408 9011 E
30501410 0000 E
30501411 9011 E
30501412 9011 E
30501413 0000 E
30501414 9001 E
30501415 0000 . E
30501499 9011 E
30501501 9001 E'
30501502 0000 E
30501503 9001 ' E
30501504 0000 E
30501505 0000 E
30501506 0000 E
30501507 0000 E
30501508 0000 E
30501509 0000 E
30501510 0000 E
30501511 9001 E
30501512 9001 E
30501513 9001 E
30501514 0000 E
30501515 0000 E
C - 45
-------
TABLE C-l. (Continued)
Page No. 44
04/19/88
PROFILE
SCC NUMBER QUALITY
30501516 0000 E
30501517 0000 E
30501518 0000 E
30501519 0000 E
30501520 9001 E
30501521 0000 E
30501522 0000 E
30501599 9011 E
30501601 0000 E
30501602 0000 E
30501603 9001 E
30501604 9001 E
30501605 9001 E
30501606 9001 E
30501607 0000 E
30501608 0000 E
30501609 0000 E
30501610 0000 E
30501611 0000 . E
30501612 0000 E
30501613 0000 E
30501614 0000 E
30501615 0000 E
30501616 0000 E
30501617 9001 E
30501699 9011 E
30501701 0000 E
30501702 .0000 ' E
30501703 9001 E
30501704 9001 E
30501705 9001 E
30501799 9001 E
30501801 0000 E
30501899 9001 E
30501901 9001 E
30501902 0000 E
30501903 0000 E
30501904 0000 E
30501905 0000 E
30501999 9011 E
30502001 0000 E
30502002 0000 E
C - 46
-------
TABLE C-l. (Continued)
Page No. 45
04/19/88
PROFILE
SCC NUMBER QUALITY
30502003 0000 E
30502004 0000 E
30502005 0000 E
30502006 0000 E
30502007 0000 E
30502008 0000 E
30502009 0000 E
30502010 0000 E
30502011 0000 E
30502012 0000 E
30502013 0000 E
30502014 0000 E
30502015 0000 E
30502016 0000 E
30502020 0000 E
30502099 0000 E
30502101 0000 E
30502102 9001 E
30502103 0000 E
30502104 0000 E
30502105 0000 E
30502106 0000 E
30502201 0000 E
30502299 9001 E
30502401 0000 E
30502499 0000 E
30502501 0000 E
30502502 0000 E
30502503 0000 E
30502504 0000 E
30502505 0000 E .
30502506 0000 E
30502507 0000 E
30502508 9001 E
30502509 0000 E .
30502510 0000 E
30502511 0000 E
30502599 0000 E
30502601 0000 E
30502699 9011 E
30503099 9011 E
30503101 0000 E
C - 47
-------
TABLE C-l. (Continued)
Page No. 46
04/19/88
PROFILE
SCC NUMBER QUALITY
30503102 0000 E
30503103 0000 E
30503104 0000 E
30503105 0000 E
30503106 0000 E
30503107 0000 E
30503108 0000 E
30503109 0000 E
30503110 0000 E
30503111 0000 E
30503199 9011 E
30503201 0000 E
30503202 0000 E
30503203 0000 E
30503204 0000 E
30503205 0000 E
30503206 0000 E
30503299 9011 E
30503301 0000 E
30504001 0000 E
30504002 0000 E
30504003 0000 E
30504010 0000 E
30504020 0000 E
30504021 0000 E
30504022 0000 ' E
30504023 0000 E
30504024 0000 E
30504025 0000 E
30504030 0000 E
30504031 0000 E
30504032 0000 E
30504033 0000 E
30504034 0000 E
30504036 0000 E
30504099 9011 E
30510001 0000 E
30510002 0000 E
30510003 0000 E
30510004 0000 E
30510005 0000 E
30510006 0000 E
C - 48
-------
TABLE C-l. (Continued)
Page No. 47
04/19/88
PROFILE
SCC NUMBER QUALITY
30510007 0000 E
30510101 0000 E
30510102 0000 E
30510103 0000 E
30510104 0000 E
30510105 0000 E
30510106 0000 E
30510107 0000 E
30510108 0000 E
30510196 0000 E
30510197 0000 E
30510198 0000 E
30510199 9011 E
30510201 0000 E
30510202 0000 E
30510203 0000 E
30510204 0000 E
30510205 0000 E
30510206 0000 E
30510207 0000 E
30510208 0000 E
30510296 0000 E
30510297 0000 E
30510298 0000 E
30510299 9011 E
30510301 0000 E
30510302 0000- . E
30510303 0000 E
30510304 0000 E
30510305 0000 E
30510306 0000 E
30510307 0000 E
30510308 0000 E
30510396 0000 E
30510397 0000 E
30510398 0000 E
30510399 9011 E
30510401 0000 E
30510402 0000 E
30510403 0000 E
30510404 0000 E
30510405 0000 E
C - 49
-------
TABLE C-l. (Continued)
Page No.
04/19/88
48
sec
30510406
30510407
30510408
30510496
30510497
30510498
30510499
30510501
30510502
30510503
30510504
30510505
30510506
30510507
30510508
30510596
30510597
30510598
30510599
30515001
30515002
30515.003
30515004
30515005
30588801
30588802
30588803 "
30588804
30588805
30590001
30590002
30590003
30590011
30590012
30590013
30590023
30599999
30600101
30600102
30600103
30600104
30600105
PROFILE
NUMBER
0000
0000
0000
0000
0000
0000
9011
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
9011
0000
0000
0000
0000
0000
9011
9011
9011
9011
9011
0002*
0001*
0003*
0002*
0001*
0003*
0051*
9011
0001*
0003*
0001*
0003*
0003*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
. -E
C
C
C
C
C
C
D
E
C
C
C
C
C
C - 50
-------
TABLE C-l. (Continued)
Page No.
04/19/88
49
sec
30600106
30600107
30600108
30600199
30600201
30600202
30600301
30600401
30600402
30600503
30600504
30600505
30600506
30600602
30600603
30600701
30600702
30600801
30600802
30600803
30600804
30600805
30600806
30600807
30600811
30600812
30600813
30600814
30600815
30600816
30600817
30600818
30600819
30600820
30600821
30600822
30600901
30600902
30600903
30600904
30600999
30601001
PROFILE
NUMBER
0004*
0003*
0202*
9012
0029
0000
0029*
9012
9012
0031
0031
9012
9012
9012
9012
0035
0035
0316
0047
0321
0039
0321*
0321*
0321*
0047*
0047*
0047*
0047*
0047*
0047*
0321*
0321*
0039*
0039*
0031*
0047*
0002*
0001*
0051
0079*
0079*
9012
QUALITY
D
C
E
E
C
E
D
E
E
C
C
E
E
E
E
C
C
C
C
C
D
D
D
D
E
E
E
E
E
E
E
E
E
E
E
E
D
D
D
D
D
E
C - 51
-------
TABLE C-l. (Continued)
Page No.
04/19/88
50
sec
30601101
30601201 -
30601401
30601599
30609902
30609903
30609904
30609911
30609912
30609913
30609914
30610001
30688801
30688802
30688803
30688804
30688805
30699998
30699999
30700101
30700102
30700103
30700104
30700105
30700106
30700107
30700108
30700109
30700110
30700199
30700203
30700211
30700212
30700213
30700214
30700215
30700221
30700222
30700223
30700231
30700232
30700233
PROFILE
NUMBER
1007*
9012
9012
9012
0001*
0003*
0004*
0002*
0001*
0003*
0004*
9012
9012
9012
9012
9012
9012
9012
9012
0000
9001
0000
9001
9001
9001
9001
9001
9001
9001
9001
0000
0000
0000
0000
0000
0000
9001
9001
9001
0000
0000
0000
QUALITY
E
E
E
E
C
C
C
C
C
C
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 52
-------
TABLE C-l. (Continued)
Page No.
04/19/88
51
sec
30700234
30700299
30700301
30700302
30700303
30700304
30700401
30700402
30700499
30700501
30700597
30700598
30700599
30700701
30700702
30700703
30700704
30700705
30700706
30700707
30700708
30700709
30700711
30700712
30700713
30700714
30700715
30700798
30700799
30700801
30700802
30700803
30700804
30700805
30700806
30700807
30700808
30700896
30700897
30700898
30700899
30701199
PROFILE
NUMBER
0000
9013
0000
0000
9001
0000
9001
9001
9013
0000
9001
9001
9001
1189*
0000
0000
1189*
1189*
1189*
1189*
0000
1189*
1189
1189
1189
1189
1189
1189
1189
0000
0000
0000
0000
0000
0000
0000
0000
9013
9013
9013
9013
9013
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
D
E
E
D
D
D
D
E
D
C
C
C
C
C
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 53
-------
TABLE C-l. (Continued)
Page No.
04/19/88
52
sec
30701301
30701399
30702098
30702099
30703001
30703002
30703096
30703097
30703098
30703099
30788801
30788802
30788803
30788804
30788805
30788898
30790001
30790002
30790003
30790011
30790012
30790013
30790023
30799998
30799999
30800101
30800102
30800103
30800104
30800105
30800106
30800107
30800108
30800109
30800110
30800120
30800121
30800122
30800123
30800197
30800198
30800199
PROFILE
NUMBER
9013
9013
9013
9013
0000
0000
0000
0000
0000
0000
9013
9013
9013
9013
9013
9013
0002*
0001*
0003*
0002*
0001*
0003*
0051*
9013
9013
0273
0274*
0274*
0274*
0272
0274*
0274*
0274*
0000
0000
0273
0272
0274*
0274*
0274*
0274*
0274*
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
C
C
C
C
E
E
E
C
D
D
D
C
D
D
0
E
E
C
C
D
D
D
D
D
C - 54
-------
TABLE C-l. (Continued)
Page No.
04/19/88
53
sec
30800501
30800699
30800701
30800702
30800703
30800704
30800705
30800720
30800721
30800722
30800723
30800724
30800799
3Q8900Q1
30890002
30890003
30890011
30890012
30890013
30890023
30899999
30900198
30900199
30900201
30900202
30900203
30900204
30900205
30900206
30900207
30900208
30900298
30900299
30900301
30900302
30900303
30900304
30901001
30901097
30901098
30901099
30901101
PROFILE
NUMBER
0274*
1008
9021
0000
9021
9021
0000
1005*
1005*
1005*
1005*
1005*
9014
0002*
0001*
0003*
0002*
0001*
0003*
0051*
9014
9003
9003
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
9003
9003
9003
9003
0000
QUALITY
D
D
E
E
E
E
E
E
E
E
E
E
E
C
C
C
C
C
C
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 55
-------
TABLE, C-L (Continued)
Page No.
04/19/88
54
SCC
30901102
30901103
30901104
30901199
30901501
30901601
30901604
30901605
30901606
30901607
30902099
30902501
30903004
30903005
30903006
30903099
30904001
30904010
30904020
30906001
30906099
30988801
30988802
30988803
30988804
30988805
30990001
30990002
30990003
30990011
30990012
30990013
30990023
30999997
30999998
30999999
31000101
31000102
31000103
31000104
31000105
31000199
PROFILE
NUMBER
0000
0000
9003
9003
0000
0024*
0000
1007*
1007*
1007*
9010
9003
9003
9003
9003
9003
9003
0000
9003
9003
9003
9003
9003
9003
9003
9003
0002*
0001*
0003*
0002*
0001*
0003*
0051*
9003
9003
9003
1011
1011*
1011*
1011*
1011*
1011*
QUALITY
E
E
E
E
E
D
E
0
0
0
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
C
C
C
C
D
E
E
E
D
E
E
E
E
E
C - 56
-------
TABLE C-l. (Continued)
Page No.
04/19/88
55
sec
31000201
31000202
31000203
31000204
31000205
31000206
31000207
31000299
31000401
31000402
31000403
31000404
31000405
31000411
31000412
31000413
31000414
31000415
31088801
31088802
31088803
31088804
31088805
31088904
31100199
31100299
31299999
31307001
31307002
31390001
31390002
31390003
31399999
31400901
31401001
31401002
31401101
31401102
31499999
31501001
31501002
31501003
PROFILE
NUMBER
0000
1012*
1012
1012*
0051*
1012*
1012*
1012*
0002*
0001*
0001*
0003*
0004*
0002*
0001*
0001*
0003*
0004*
1010
9015
9015
9012
9015
9015
9003
9003
9003
0122*
0122*
0002*
0001*
0003*
9003
0000
0122*
0122*
0000
0000
9003
0000
9026
0000
QUALITY
E
E
D
E
E
E
E
E
C
C
C
C
D
C
C
C
C
D
D
E
E
E
E
E
E
E
E
E
E
C
C
C
E
E
E
E
E
E
E
E
E
E
C - 57
-------
TABLE C-l. (Continued)
Page No.
04/19/88
56
sec
31502001
32099997
32099998
32099999
33000101
33000102
33000103
33000104
33000105
33000198
33000199
33000201
33000202
33000211
33000212
33000213
33000214
33000298
33000299
33000399
33000499
33000599
33088801
33088802
33088803
33088804
33088805
36000101
39000199
39000201
39000203
39000289
39000299
39000389
39000399
39000402
39000403
39000489
39000499
39000501
39000502
39000503
PROFILE
NUMBER
1031
9016
9016
9016
0000
1096*
0000
1096
0000
1095
1095
9023
9023
9023
9023
9023
9023
9023
9023
9016
9016
9016
9016
9016
9016
9016
9016
0000
0000
0000
0000
1178*
0000
1178*
0000
0000
0000
0001*
0000
0002*
0000
0000
QUALITY
E
E
E
E
E
0
E
B
E
B
B
E
E
E
E
E
E
E
E
E
. E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
E
C
E
E
C - 58
-------
TABLE C-l. (Continued)
Page No.
04/19/88
57
sec
39000589
39000598
39000599
39000602
39000603
39000605
39000689
39000699
39000701
39000702
39000788
39000789
39000797
39000798
39000799
39000801
39000889
39000899
39000989
39000999
39001089
39001099
39001299
39001389
39001399
39990001
39990002
39990003
39990004
39990011
39990012
39990013
39990014
39990022
39990023
39990024
39999993
39999994
39999995
39999996
39999998
39999999
PROFILE
NUMBER
0003
0000
0000
0000
0000
0003*
0003*
0000
0217
0000
0004*
0005*
0000
0000
0000
0005*
0005*
0000
1084*
0000
0003*
0000
0000
0122*
0000
0002
0001
0003
0004*
0002
0001
0003
0004*
0079*
0051*
0079*
9003
9003
9003
9003
9003
9003
QUALITY
C
E
E
E
E
C
C
E
B
E
C
C
E
E
E
C
C
E
E
E
C
E
* E
E
E
B
B-
B
D
B
B
B
D
E
E
E
E
E
E
E
E
E
C - 59
-------
TABLE C-l. (Continued)
Page No. 58
04/19/88
sec
40100101
40100102
40100103
40100104
40100105
40100106
40100198
40100199
40100201
40100202
40100203
40100204
40100205
40100206
40100207
40100208
40100215
40100216
40100217
40100221
40100222
40100223
40100224
40100225
40100235
40100236
40100251
40100252
40100253
40100254
40100255
40100256
40100257
40100258
40100259
40100295
40100296
40100297
40100298
40100299
40100301
40100302
PROFILE
NUMBER
0085
1193
0085
1193*
0277
0277
1196
1196
1192
0087
0085
0275
0271
0090
0277
1021
1195
1195
1195
1192
0087
0085
0275
0271
1195
1195
1192
0087
0085
0275
0271
0090
0277
0088
0089
1195
1195
1195
1195
1195
1149
0275
QUALITY
E
B
E
C
E
E
B
B
B
E
E
E
E
E
E
E
B
B
B
B
E
E
E
E
B
B
B
E
E
E
E '
E
E
E
E
B
B
B
B
B
E
E
C - 60
-------
TABLE C-l. (Continued)
Page No.
04/19/88
59
SCC
40100303
40100304
40100305
40100306
40100335
40100336
40100398
40100399
40100401
40100499
40188801
40188802
40188803
40188804
40188805
40188898
40200101
40200110
40200201
40200210
40200301
40200310
40200401
40200410
40200501
40200510
40200601
40200610
40200701
40200706
40200707
40200710
40200801
40200802
40200803
40200810
40200898
40200899
40200901
40200902
40200903
40200904
PROFILE
NUMBER
1192
0085
0087
0271
1195
1195
1195
1195
0085
9017
9017
9017
9017
9017
9017
9017
1003
1003
1013
1013
0127
0127
1017
1017
1018
1018
1019
1019
1088
1020
0000
1088
1003*
1003*
1003*
1003*
1003
1003*
1016
0219
0288
0289
QUALITY
B
E
E
E
B
B
3
B
E
E
E
E
E
E
E .
E
B
B
B
B
D
D
B
B
B
B
B
B
C
B
E
C
C
C
C
C
B
C
B
E
E
E
C - 61
-------
TABLE" C-r. (Continued)
Page No. 60
04/19/88
SCC
40200905
40200906
40200907
40200908
40200909
40200910
40200911
40200912
40200913
40200914
40200915
40200916
40200917
40200918
40200919
40200920
40200921
40200922
40200923
40200924
40200925
40200926
40200927
40200928
40200998
40201001
40201002
40201003
40201004
40201101
40201103
40201104
40201105
40201111
40201112
40201113
40201114
40201115
40201116
40201199
40201201
40201210
PROFILE
NUMBER
1118
0290
0222
0292
0220
0226
1015*
0227
0228
1014*
0229
1150
0291
0221
1022
0225
0282
0090
0225*
0223
1062*
9023
1026
1031
9021
0003*
0002*
0001*
0000
1003*
1003*
0000
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
QUALITY
E
E
E
E
E
E
o;
ฃ
E
E
E
E.
E
E
E
E
E
E
E
E
C
E
E
E
E
0
0
0
E
0
0
E
0
0
D.
0
0
D
D
0
0
0
C - 62
-------
TABLE C-l. (Continued)
Page No.
04/19/88
61
sec
40201301
40201303
40201304
40201305
40201399
40201401
40201402
40201403
40201404
40201405
40201406
40201431
40201432
40201433
40201434
40201435
40201436
40201437
40201438
40201499
40201501
40201502
40201503
40201504
40201505
40201531
40201599
40201601
40201602
40201603
40201604
40201605 '
40201606
40201619
40201620
40201621
40201622
40201623
40201624
40201625
40201626
40201627
PROFILE
NUMBER
1003*
1003*
0000
1003*
1003*
1003*
0000
1003*
0000
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
0000
1003*
0000
1003*
1003*
1003*
1194*
. 0000
1194*
0000
1194*
1194*
1194*
1003
1194*
1194*
1194*
1194*
1194*
1194*
1194*
QUALITY
D
D
E
D
D
D
E
D
E
D
D
D
D
D
D
D
D
D
D
D
D
E
D
E
D
D
D
C
E
C
E
C
C
C
B
C
D
C
D
C
C
C
C - 63
-------
TABLE C-l. (Continued)
Page No.
04/19/88
62
sec
40201628
40201629
40201630
40201631
40201632
40201699
40201702
40201703
40201704
40201705
40201721
40201722
40201723
40201724
40201725
40201726
40201727
40201728
40201731
40201732
40201733
40201734
40201735
40201736
40201799
40201801
40201803
40201804
40201805
40201806
40201899
40201901
40201903
40201904
40201999
40202001
40202002
40202003
40202004
40202005
40202031
40202032
PROFILE
NUMBER
1194*
1194*
1194*
1194*
1194*
1194*
0000
1003*
0000
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
0000
1003*
1003*
1003*
1003*
1003*
0000
1003*
1003*
0000
1003*
0000
1003*
1003*
1003*
QUALITY
D
C
D
C
D
D
E
D
E
D
D
D
0
0
D
D
D
D
D
D
D
D
D
D
D
D
D
E
D
" D
D
D
0
E
D
D
E
D
E
D
D
D
C - 64
-------
TABLE C-l. (Continued)
Page No.
04/19/88
63
sec
40202033
40202034
40202099
40202101
40202103
40202104
40202105
40202106
40202107
40202108
40202109
40202131
40202132
40202133
40202199
40202201
40202202
40202203
40202204
40202205
40202299
40202301
40202302
40202303
40202304
40202305
40202306
40202399
40202401
40202402
40202403
40202404
40202405
40202406
40202499
40202501
40202502
40202503
40202504
40202505
40202531
40202532
PROFILE
NUMBER
1003*
1003*
1003*
1003*
1003*
0000
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
0000
1003*
0000
1003*
1003*
1003*
0000
1003*
0000
1003*
1003*
1003*
1003*
0000
1003*
0000
1003*
1003*
1003*
1003*
0000
1003*
0000
1003*
1003*
1003*
QUALITY
D
D
D
D
D
E
D
D
D
D
D
D
D
D
D
D
E
D
E
D
D
D
E
D
E
D
D
D
D
E
D
E
D
0
D
D
E
0
E
D
0
D
C - 65
-------
TABLE C-l. (Continued)
Page No.
04/19/88
64
sec
40202533
40202534
40202535
40202536
40202537
40202599
40202601
40202602
40202603
40202604
40202605
40202606
40202607
40202699
40288801
40288802
40288803
40288804
40288805
40290023
40299995
40299996
40299997
40299998
40299999
40300101
40300102
40300103
40300104
40300105
40300106
40300107
40300108
40300109
40300110
40300111
40300112
40300113
40300114
40300115
40300116
40300150
PROFILE
NUMBER
1003*
1003*
1003*
1003*
1003*
1003*
1003*
0000
1003*
0000
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
0051*
1187
1187
1187
1187
9021
1014*
0297
1015
0297*
0100*
0100*
0297*
1062
0299
1200
0301
0230
1197
1199
1198
0090
0100*
QUALITY
D
D
D
D
D
D
D
E
D
E
D
D
D
D
D
D
D
D
D
D
D
D
D
D
E
D
E
D
E
D
D
E
E
E
E
E
E
E
E
E
E
D
C - 66
-------
TABLE C-l. (Continued)
Page No.
04/19/88
65
sec
40300151
40300152
40300153
40300154
40300155
40300156
40300157
40300158
40300159
40300160
40300161
40300198
40300199
40300201
40300202
40300203
40300204
40300205
40300207
40300208
40300209
40300210
40300211
40300212
40300213
40300214
40300215
40300216
40300299
40300302
40301001
40301002
40301003
40301004
40301005
40301006
40301007
40301008
40301009
40301010
40301011
40301012
PROFILE
NUMBER
0297*
0100*
1062
0299
1200
0301
0230
1197
1199
1198
0090
9024
9024
1014*
1014*
0297*
0297*
.0100*
0100*
1062*
0299
1200
0301
0230
1197
1199
1198
0090
9024
1014*
1015
1014*
1014
1015
1014*
1014
1015
1014*
1014
0296
0296
0296
QUALITY
E
D
E
E
E
E
E
E
E
E
E
E
E
D
D
E
E
. D
D
E
E
E
E
E
E
E
E
E
E
D
B
D
B
B
D
B
B
D
B
C
C
C
C - 67
-------
TABLE C-l. (Continued)
Page No.
04/19/88
66
sec
40301013
40301014
40301015
40301016
40301017
40301018
40301019
40301020
40301021
40301097
40301098
40301099
40301101
40301102
40301103
40301104
40301105
40301106
40301107
40301108
40301109
40301110
40301111
40301112
40301113
40301114
40301115
40301116
40301117
40301118
40301119
40301120
40301130
40301131
40301132
40301133
40301134
40301135
40301140
40301141
40301142
40301143
PROFILE
NUMBER
0100
0100*
0100*
0100*
0100*
0100*
0297*
0297*
0297*
9024
9024
9024
1015
1014*
1014
. 1015
1014*
1014*
1014*
1014*
0296
0296*
0100*
0100*
0100*
0100*
0297*
0297*
0296*
0100*
0100*
0297*
9024
1014*
0296*
0100*
0100*
0297*
9024
1014*
0296*
0100*
QUALITY
C
D
D
D
D
D
E
E
E
E
E
E
B
D
B
C
D
C
D
D
C
D
D
D
D
D
E
E
D
D
D
E
E
C
D
D
D
E
E
C
D
D
C - 68
-------
TABLE C-l. (Continued)
Page No.
04/19/88
67
sec
40301144
40301145
40301150
40301151
40301152
40301153
40301154
40301155
40301197
40301198
40301199
40301201
40301202
40301203
40301204
40301205
40301206
40301207
40301299
40388801
40388802
40388803
40388804
40388805
40399999
40400101
40400102
40400103
40400104
40400105
40400106
40400107
40400108
40400109
40400110
40400111
40400112
40400113
40400114
40400115
40400116
40400117
PROFILE
NUMBER
0100*
0297*
9024
1014*
0296*
0100*
0100*
0297*
9024
9024
9024
1015
1014*
1014
0100*
0100*
0297*
1062
9024
9024
9024
9024
9024
9024
9024
1015
1014*
1014
1015
1014*
1014
1015
1014*
1014
1015
1014*
1014
1015
1014*
1014
1014*
1014*
QUALITY
D
E
E
C
D
D
D
E
E
E
E
B
D
B
D
D
E
D
E
E
E
E
E
E
E
B
D
B
B
D
B
B
D
B
B
D
B
B
D
B
D
D
C - 69
-------
TABLE C-l. (Continued)
Page No.
04/19/88
68
SCC
40400118
40400119
40400120
40400151
40400152
40400153
40400154
40400199
40400201
40400202
40400203
40400204
40400205
40400206
40400207
40400208
40400209
40400210
40400211
40400212
40400213
40400250
40400251
40400254
40400301
40400302
40400303
40400304
40400305
40400401
40400402
40400403
40400404
40400405
40400406
40400407
40400408
40400409
40400410
40400411
40400412
40400413
PROFILE
NUMBER
1015
1014*
1014
9025
9025
9025
9025
1015*
1015
1014*
1014
1015
1014*
1014
1015
1014*
1014
1014*
1015
1014*
1014
9025
9025
9025
0297
0297
0297*
0297*
0297*
0000
1015
0000
1014*
0000
1014
0000
0297*
0000
0100*
0000
0100*
0000
QUALITY
B
D
B
E
E
E
E
C
B
C
B
B
C
B
B
C
B
C
B
C
B
E
E
E
C
C
D
D
D
E
B
E
C
E
B
E
D
E
D
E
D
E
C - 70
-------
TABLE C-l. (Continued)
Page No.
04/19/88
69
sec
40400414
40400497
40400498
40500101
40500199
40500201
40500202
40500203
40500211
40500212
40500301
40500302
40500303
40500304
40500305
40500306
40500307
40500311
40500312
40500401
40500411
40500412
40500413
40500501
40500502
40500503
40500506
40500507
40500510
40500511
40500512
40500513
40500598
40500599
40500601
40500701
40588801
40588802
40588803
40588804
40588805
40600101
PROFILE
NUMBER
0297*
9025
9025
0333*
0333*
0166
1014*
0225
0166
0166*
1086
1118
0290
0226
0227
0304
0282
1086
1086
0332
0332
0332*
0227
0182
0292
0220
0221
1022
0090
0182
0182
0183
9026
9026
9026
9026
1191
1191*
1191*
1191*
1191*
1190*
QUALITY
E
E
E
D
D
D
E
E
D
E
C
E
E
E
E
E
E
C
C
D
D
E
E
C
E
E
E
E
E
C
C
D
E
E
E
E
B
B
B
B
B
C
C - 71
-------
TABLE C-l. (Continued)
Page No.
04/19/88
70
sec
40600126
40600130
40600131
40600132
40600133
40600134
40600135
40600136
40600137
40600138
40600139
40600140
40600141
40600142
40600143
40600144
40600145
40600146
40600147
40600148
40600149
40600160
40600161
40600162
40600163
40600197
40600198
40600199
40600231
40600232
40600233
40600235
40600236
40600237
40600238
40600239
40600240
40600241
40600242
40600243
40600244
40600245
PROFILE
NUMBER
1190*
0297*
1190*
0297*
0100*
0100*
0297*
1190*
0297*
0100*
0100*
0297*
1190*
0297*
0100*
1190*
0297*
0100*
1190*
0297*
0100*
0100*
0297*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
1190*
0297*
0100*
1014*
QUALITY
C
E
B
D
D
D
E
B
D
D
D
D
B
D
D
B
D
D
B
D
D
D
E
B
B
D
D
D
B
B
B
B
B
B
B
B
B
B
B
D
D
E
C - 72
-------
TABLE C-l. (Continued)
Page No.
04/19/88
71
sec
40600246
40600248
40600249
40600250
40600251
40600253
40600254
40600255
40600256
40600257
40600259
40600298
40600299
40600301
40600302
40600305
40600306
40600307
40600399
40600401
40600402
40600403
40600499
40602234
40688801
40688802
40688803
40688804
40688805
40700401
40700402
40700497
40700498
40700801
40700802
40700803
40700804
40700805
40700806
40700807
40700808
40700809
PROFILE
NUMBER
0100*
0297*
0100*
1014*
0297*
0305
0305*
0100*
1014*
0297*
9027
1190*
1190*
1190*
1190*
1190*
1190*
1014*
1190*
1100
1100*
1100
1190*
1100*
9027
9027
9027
9027
9027
-1106
1106
1106
1106
0289
0289
1027*
1027*
1175
1175
1124
1124
0226
QUALITY
E
D
D
E
E
C
D
D
E
E
E
D
D
B
B
B
B
C
C
C
C
C
C
C
E
E
E
E
E
E
E
E
E
E
E
C
C
E
E
E
E
E
C - 73
-------
TABLE C-l. (Continued)
Page No.
04/19/88
72
SCC
40700810
40700811
40700812
40700813
40700814
40700815
40700816
40700817
40700818
40700897
40700898
40701601
40701602
40701603
40701604
40701605
40701606
40701609
40701610
40701611
40701612
40701613
40701614
40701697
40701698
40702001
40702002
40702003
40702004
40702097
40702098
40703201
40703202
40703203
40703204
40703205
40703206
40703297
40703298
40703601
40703602
40703603
PROFILE
NUMBER
0226
1147
1147
0227
0227
0291
0291
0304
0304
9029
9029
1163
1163
1164
1164
0301
0301
1166
1166
0282
0282
0282
0282
9030
9030
1130
1130
1144
1144
9031
9031
1111
1111
1132
1132
1139
1139
9032
9032
1062*
1062*
1122
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E .
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 74
-------
TABLE C-l. (Continued)
Page No.
04/19/88
73
sec
40703604
40703605
40703606
40703607
40703608
40703609
40703610
40703611
40703612
40703613
40703614
40703615
40703616
40703617
40703618
40703619
40703620
40703621
40703622
40703623
40703624
40703697
40703698
40704001
40704002
40704003
40704004
40704005
40704006
40704007
40704008
40704009
40704010
40704097
40704098
40704401
40704402
40704403
40704404
40704405
40704406
40704407
PROFILE
NUMBER
1122
1123
1123
1128
1128
1135
1135
1154
1154
1005*
1005*
0090
0090
1159
1159
1165
1165
1174
1174
0223
0223
9033
9033
1105
1105
1108
1108
1110
0000
1141
1141
1172
1172
9034
9034
. 0288
0288
1114
1114
0220
0220
1134
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 75
-------
TABLE C-l. (Continued)
Page No.
04/19/88
74
SCC
40704408
40704409
40704410
40704411
40704412
40704413
40704414
40704415
40704416
40704417
40704418
40704419
40704420
40704421
40704422
40704423
40704424
40704497
40704498
40704801
40704802
40704897
40704898
40705201
40705202
40705203
40705204
40705205
40705206
40705207
40705208
40705209
40705210
40705211
40705212
40705213
40705214
40705215
40705216
40705217
40705218
40705297
PROFILE
NUMBER
1134
1146
1146
0228
0228
1150
1150
1151
1151
1081*
1081*
1053*
1053*
1069
1069
1087
1087
9035
9035
1158
1158
1158
1158
1115
1115
1116
1116
1118
1118
0290
0290
1127
1127
1152
1152
1153
1153
0000
0000
0000
0000
9036
QUALITY
E
E
E
E
E
E
E
E
E
D
0
E
E
E
E
E
E
E
E
E
E
E ,
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 76
-------
TABLE C-l. (Continued)
Page No.
04/19/88
75
sec
40705298
40705601
40705602
40705603
40705604
40705605
40705606
40705607
40705608
40705609
40705610
40705697
40705698
40706001
40706002
40706003
40706004
40706005
.40706006
40706007
40706008
40706009
40706010
40706011
40706012
40706013
40706014
40706015
40706016
40706017
40706018
40706019
40706020
40706021
40706022
40706023
40706024
40706097
40706098
40706401
40706402
40706403
PROFILE
NUMBER
9036
0000
0000
1078*
1078*
1129
1129
0000
0000
1083*
0000
9037
9037
1112
1112
0000
0000
1119
1119
1074*
1074*
1079*
1079*
1076*
1076*
1131
1131
1138
1138
0078*
0078*
0000
0000
0085
0085
0271
0271
9038
9038
0000
0000
1176
QUALITY
E
E
E
C
C
E
E
E
E
C
E
E
E
E
E
E
E
E
E
C
C
C
C
C
C
E
E
E
E
B
B
E
E
E
E
E
E
E
E
E
E
E
C - 77
-------
TABLE C-l. (Continued)
Page No.
04/19/88
76
sec
40706404
40706497
40706498
40706801
40706802
40706813
40706814
40706897
40706898
40707601
40707602
40707697
40707698
40708001
40708002
40708097
40708098
40708401
40708402
40708403
40708404
40708497
40708498
40717205
40717206
40717207
40717208
40717209
40717210
40717211
40717212
40717297
40717298
40717601
40717602
40717603
40717604
40717697
40717698
40718097
40720801
40720802
PROFILE
NUMBER
1176
9039
9039
1125
1125
1055
1055
9040
9040
1109
1109
1109
1109
1160
1160
1160
1160
0000
0000
1082*
1082*
9028
9028
1162
1162
1140
1140
1145
1145
1171
1171
9041
9041
0299
0299
0230
0230
9042
9042
9046
1136
1136
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C
C
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 78
-------
TABLE C-l. (Continued)
Page No.
04/19/88
77
sec
40720803
40720804
40720897
40720898
40722001
40722002
40722003
40722004
40722005
40722006
40722007
40722008
40722009
40722010
40722097
40722098
40722801
40722802
40722803
40722804
40722805
40722806
40722897
40722898
40723201
40723202
40723297
40723298
40781201
40781202
40781601
40781602
40781603
40781604
40781605
40781699
40782001
40782002
40782003
40782004
40782005
40782006
PROFILE
NUMBER
1173
1173
9043
9043
1119
1119
1121
1121
0078*
0078*
0000
0000
0087
0087
9044
9044
0219
0219
0221
0221
1022
1022
9028
9028
1137
1137
1137
1137
1104
1107
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
QUALITY
E
E
E
E
E
E
E
E
B
B
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 79
-------
TABLE C-l. (Continued)
Page No. 78
04/19/88
sec
40782007
40782008
40782009
40782010
40782011
40782099
40782401
40782499
40783201
40783202
40783203
40783299
40784801
40784899
40786001
40786002
40786003
40786004
40786099
40786401
40786499
40787201
40787299
40799997
40799998
40899995
40899997
40899999
49000101
49000102
49000103
49000104
49000105
49000199
49000201
49000202
49000203
49000204
49000205
49000206
49000299
49000301
PROFILE
NUMBER
1148
1155
1103
1168
1126
9046
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
9028
9028
9028
9028
9028
1193*
0221
1022
1142
0271
9047
9047
9047
9047
9047
9047
9047
9047
1078
QUALITY
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
. E
E
E
E
E
E
E
E
E
E
E
C
E
E
E
E
E
E
E
E
E
E
E
E
D
C - 80
-------
TABLE C-l. (Continued)
Page No.
04/19/88
79
sec
49000302
49000303
49000304
49000399
49000401
49000402
49000403
49000404
49000405
49000499
49090011
49090012
49090013
49090023
49099998
49099999
50100101
50100102
50100201
50100202
50100505
50100506
50100507
50100508
50100510
50100511
50100512
50100601
50100602
50100603
50100604
50100701
50100702
50100703
50100704
50190005
50190006
50190010
50200101
50200102
50200103
50200104
PROFILE
NUMBER
1074
1079
1080
9047
0219
0085
1081
1082
1083
9047
0002*
0001*
0003*
0051*
9047
9047
0122
0122
0121*
0121
0122
0122
0122*
0121*
0121*
0122*
0122*
9022
9022
9022
0121*
9022
9022
9022
0000
0000
0000
0000
0122*
0122*
0000
0122*
QUALITY
D
0
D
E
E
E
D
D
D
E
C
C
C
E
E
E
D
D
E
C
D
D
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
C - 81
-------
TABLE C-l. (Continued)
Page No.
04/19/88
80
sec
50200105
50200201
50200202
50200301
50200302
50200505
50200506
50200601
50200602
50200901
50290005
50290006
50290010
50300101
50300102
50300103
50300104
50300105
50300106
50300107
50300108
50300109
50300201
50300202
50300203
50300204
50300501
50300506
50300601
50300602
50300603
50300701
50300801
50300810
50300820
50300901
50390005
50390006
50390010
PROFILE
NUMBER
0121*
0121*
0122*
0122*
0122*
0122*
0122*
0079*
0202
0000
0000
0000
0000
0122*
0122*
0000
0122*
0121*
0000
0122*
9022
0122*.
0121*
0122*
9022
9022
9022
0122*
0079*
9022
9022
9022
9022
9022
9022
0000
0000
0000
0000
QUALITY
E
E
E
E
E
E
E
D
C
E
E
E
E
E
E
E
E
D
E
E
E
E
D
E
E
E
E
E
D
E
E
E
E
E
E
E
E
E
E
C - 82
-------
TABLE C-2. AREA SOURCE PROFILE. ASSIGNMENTS
Page No.
03/25/88
81
AREA SOURCE CODE
001
002
003
004
005
006
007
008
009
010
Oil
012
013
014
015
016
017
018
019
020
021
022
023
024
025
026
027
028
029
030
031
032
033
034
035
036
037
038
039
040
041
042
043
PROFILE NUMBER DATA QUALITY
1185*
1185*
0002*
0001*
0195
1084
1178*
1178*
0002*
0001*
0003*
1084
1185*
1185
0005*
0002*
0001*
0003*
1084
0004*
0122*
0122*
0122*
0121*
0121
0121*
1101
1101
1101
1101
1101*
1101*
1101*
1101*
1186
1186
1186
1186
1186*
1201*
1201*
1201*
1201*
E
E
C
C
C
D
E
E
C.
c:
c
D
E
0
C
C
C
C
D
D
E
E
D
D
C
D
B
B
8
8
C
C
C
c
c
c
c
c
E
D
D
D
D-
C - 83
-------
TABLE C-2. (Continued)
Page No.
03/25/88
82
AREA SOURCE CODE
044
045
046
047
048
049
050
051
052
054
055
056
057
058
059
060
061
062
063
064
071
072
073
074
075
076
077
078
079
080
081
082
083
084
085
086
087
088
089
090
091
092
093
PROFILE NUMBER
1201*
1201*
1097
1099
1098
1178*
1201*
0001*
1.186*'
1190,
0000
1099*
0000
0000
0000
0307
0307*
0307*
0001*
0307*
0203
0203
0203
0203
0203
0203*
0203
1195
1196
1191
9014
1016
1194
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
1003*
9003
DATA QUALITY
0
D
B
C
B
E
0
C
0
B
E
0
E
E
E
C
0
0
0
0
C
C
C
C
C
0
C
B
B
B.
ฃ
B
B
0
D
D
D
0
0
0
D
0
E
C - 84
-------
TABLE C-2. (Continued)
Page No. 83
03/25/88
AREA SOURCE CODE PROFILE NUMBER DATA QUALITY
094 9028 E
095 0197 D
096 1178* E
097 0001* C
098 0003* C
099 0000 E
100 9022 E
101 9004 E
102 9025 E
103 9012 E
104 9003 E
105 9004 E
106 9006 E
107 9015 E
108 1007 C
109 9022 E
110 . 1101* D
111 1201 C
112 0000 E
113 0000 E
114 0000 E
115 0000 E
C - 85
-------
TABLE C-3. AREA SOURCE CODE DESCRIPTIONS
Area
Source Code
Category Description
001
002
003
004
005
006
007.
008
009
010
Oil
012
013
014
015
016
017
018
019
020
021
022
023
024
025
026
027
028
029
Residential Fuel - Anthracite Coal
Residential Fuel - Bituminous Coal
Residential Fuel - Distillate Oil
Residential Fuel - Residual Oil
Residential Fuel - Natural Gas
Residential Fuel - Wood
Commercial/Institutional Fuel - Anthracite Coal
Commercial/Institutional Fuel - Bituminous Coal
Commercial/Institutional Fuel - Distillate Oil
Commercial/Institutional Fuel - Residual Oil
Commercial/Institutional Fuel - Natural Gas
Commercial/Institutional Fuel - Wood
industrial Fuel - Anthracite Coal
Industrial Fuel - Bituminous Coal
Industrial Fuel - Coke
Industrial Fuel - Distillate Oil
Industri-al Fuel - Residual Oil
Industrial Fuel - Natural Gas
Industrial Fuel - Wood
Industrial Fuel - Process Gas
On-Site Incineration - Residential
On-Site Incineration - Industrial
On-Site Incineration - Commercial/Institutional
Open Burning - Residential
Open Burning - Industrial
Open Burning - Commercial/Institutional
Light-Duty Gasoline Vehicles - Limited Access Roads
Light-Duty Gasoline Vehicles - Rural Roads
Light-Duty Gasoline Vehicles - Suburban Roads
C - 86
-------
TABLE C-3. AREA SOURCE CODE DESCRIPTIONS (Continued)
Area
Source Code Category Description
030 Light-Duty Gasoline Vehicles - Urban Roads
031 Medium-Duty Gasoline Vehicles - Limited Access Roads
032 Medium-Duty Gasoline Vehicles - Rural Roads
033 Medium-Duty Gasoline Vehicles - Suburban Roads
034 Medium-Duty Gasoline Vehicles - Urban Roads
035 Heavy-Duty Gasoline Vehicles - Limited Access Roads
036 Heavy-Duty Gasoline Vehicles - Rural Roads
037 Heavy-Duty Gasoline Vehicles - Suburban Roads
038 Heavy-Duty Gasoline Vehicles - Urban Roads
039 Off-Highway Gasoline Vehicles
040 . . Heavy-Duty Diesel Vehicles - Limited Access Roads
041 Heavy-Duty Diesel Vehicles - Rural Roads
042 Heavy-Duty Diesel Vehicles - Suburban Roads
043 Heavy-Duty Diesel Vehicles - Urban Roads
044 Off-Highway Diesel Vehicles
045 Railroad Locomotives
046 Aircraft Landing and Takeoff (LTO) - Military
047 Aircraft Landing and Takeoff (LTO) - Civil
048 Aircraft Landing and Takeoff (LTO) - Commercial
049 Vessels - Coal
050 Vessels - Diesel Oil
051 Vessels - Residual Oil
052 Vessels - Gasoline
054 Gasoline Marketed
055 Unpaved Road Travel
056 Unpaved Airstrip LTOs
057 Construction
058 Miscellaneous Wind Erosion
059 Land Tilling
C - 87
-------
TABLE C-3. AREA SOURCE CODE DESCRIPTIONS (Continued)
Area
Source Code Category Description
060 Forest Wild Fires
061 Managed Burning - Prescribed
062 Agricultural Field Burning
063 Frost Control - Orchard Heaters
064 Structural Fires
071 Beef Cattle Manure Field Application
072 Dairy Cattle Manure Field Application
073 Hog and Pig Manure Field Application
074 Broiler Chicken Manure Field Application
075 Other Chicken Manure Field Application
. 076 Anhydrous Ammonia Fertilizer Application
077 Beef Cattle Feed Lots
078 Degreasing
079 Drycleaning
080 Graphic Arts (Printing)
081 Rubber and Plastics Manufacturing
082 Architectural Coating
083 Auto Body Repair
084 Motor Vehicle Manufacturing
085 Paper Coating
086 Fabricated Metals
087 Machinery Manufacturing
088 Furniture Manufacturing
089 Flat Wood Products
090 Other Transportation Equipment Manufacturing
091 Electrical Equipment Manufacturing
092 Ship Building and Repairing
093 Miscellaneous Industrial Manufacturing
094 Miscellaneous Industrial Solvent Use
C - 88
-------
TABLE C-3. AREA SOURCE CODE DESCRIPTIONS (Continued)
Area
Source Code Category Description
095 Miscellaneous Nonindustrial Solvent Use
096 Minor Utility Sources - Coal
097 Minor Utility Sources - Oil
098 Minor Utility Sources - Gas
099 Minor Point Sources
100 Publicly Owned Treatment Works (POTWs)
101 Fugitive Emissions from Synthetic Organic Chemical
Manufacture
102 Bulk Terminals and Bulk Plants
103 Fugitive Emissions from Petroleum Refining Operations
104 Process Emissions from Bakeries
105 Process Emissions from Pharmaceutical Manufacture
106 Process Emissions from Synthetic Fibers. Manufacture
107 Crude Oil and Natural Gas Production Fields
108 Cutback Asphalt Paving Operations
109 Hazardous Waste Treatment, Storage; and Disposal
Facilities
110 Transportation Composite
111 Light-Duty Diesel Vehicles
112 Tire Wear
113 Paved Roads
114 Marine Aerosol
115 Volcanic Ash
C - 89
-------
APPENDIX D
CHEMICAL SPECIES DATA FILE
-------
APPENDIX D
CHEMICAL SPECIES DATA FILE
In this appendix, Table D-l presents an alphabetical listing of all
species used in the profiles including their molecular weight, SAROAD code,
and CAS number. Table D-2 presents the same information ordered according
to SAROAD codes.
If the CAS number for a species were not readily available, this is
indicated by a "0" in the appropriate column. This does not mean that the
CAS number for a particular species is zero. For several uncommon species,
it was difficult to find or calculate molecular weights. An estimate is
provided for these species. In cases where a species represents a group or
class of compounds, an average molecular weight value is provided.
D-l
-------
TABLE D-l. SPECIES DATA FILE (ALPHABETICAL LISTING)
Page No. 1
03/30/88
MOLECULAR
WEIGHT
133.42
133.42
134.22
134.22
120.19
120.19
120.19
54.09
90.12
54.09
92.57
140.22
104.15
98.18
84.16
119.19
119.19
134.22
134.22
96.17
127.05
70.13
154.30
207.02
114.22
72.17
114.22
128.26
86.17
100.20
84.16
86.17
128.26
114.22
167.31
114.22
114.22
128.25
128.26
142.29
112.22
142.29
SAROAD
NUMBER
43814
43820
45217
45237
45225
45208
45207
43218
43322
43281
43835
90014
43313
90057
43245
99913
99912
99917
99916
43299
43269
43224
90032
45703
43287
43222
43250
98033
43291
43274
43234
43276
90006
43290
99908
43280
43252
90002
90003
99910
98054
90009
SPECIES NAME
1,1,1-TRICHLOROETHANE
1,1,2-TRICHLOROETHANE
1,2 DIETHYLBENZENE
1,2,3,4 TETRAMETHYLBENZENE
1,2,3-TRIMETHYLBENZENE
1,2,4-TRIMETHYLBENZENE
1,3,5-TRIMETHYLBENZENE
1,3-BUTADIENE
1,4 BUTANEDIOL
1-BUTYNE
1-CHLOROBUTANE
1-DECENE
l-ETHOXY-2-PROPANOL
1-HEPTENE
1-HEXENE
l-METHYL-2-ETHYLBENZENE
l-METHYL-3-ETHYLBENZENE
l-METHYL-3-ISOPROPYLBENZENE
1-METHYL-3N-PROPYLBENZENE
1-METHYLCYCLOHEXENE
1-NONENE
1-PENTENE
1-UNDECENE
2,2 DICHLORONITROANILINE
2,2 DIMETHYLHEXANE
2,2 DIMETHYLPROPANE
2,2,4-TRIMETHYLPENTANE
2,2,5-TRIMETHYLHEXANE
2,2-DIMETHYLBUTANE
2,3 DIMETHYL PENTANE
2,3 DIMETHYL-1-BUTENE
2,3 DIMETHYLBUTANE
2,3 DIMETHYLHEPTANE
2,3 DIMETHYLHEXANE
2,3 DIMETHYLOCTANE
2,3,3 TRIMETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
2,3,5-TRIMETHYLHEXANE
2,4 DIMETHYLHEPTANE
2,4 DIMETHYLOCTANE
2,4,4-TRIMETHYL-l-PENTENE
2,4,5-TRIMETHYLHEPTANE
CAS NUMBER
71556
79005
135013
488233
526738
95636
108678
106990
110634
107006
78864
8720509
0
592767
592416
0
0
0
0
0
124118
109671
821954
0
590738
463821
540841
0
75832
565593
563780
79298
0
0
0
0
565753
0
0
0
107391
0
D - 2
-------
Page No. 2
03/30/88
TABLE D-l. (Continued)
MOLECULAR
WEIGHT
114.22
100.20
128.26
114.22
167.31
162.18
128.19
54.09
130.23
84.16
96.09
84.16
100.20
70.13
84.16
70.13
84.16
114.19
156.32
114.23
128.26
86.17
100.20
142.29
128.26
128.26
148.68
98.19
86.17
70.13
84.16
84.16
114.23
100.20
128.26
198.17
84.16
84.18
107.17
114.23
128.26
131.20
SAROAD
NUMBER
43277
43247
90005
43278
99909
43312
43391
43282
43318
43279
45503
43285
43263
43225
98040
43228
43284
43563
99918
43296
90008
43229
90040
99911
90004
43271
43836
98041
43230
43223
43211
43270
43298
43295
90015
46111
90007
43293
46114
43297
90016
45241
2,
2,
2,
2,
2,
2-
2-
2-
2-
2-
2-
2-
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-1
2-1
3,
3,
3,
3,
3-
3-
3-
3-
3-
3-
3-
3-
3-
4,
4-
4-
4-
4-
4-
4-
SPECIES NAME CAS NUMBER
4-DIMETHYLHEXANE 0
4-DIMETHYLPENTANE 108087
5 DIMETHYLHEPTANE 0
5-DIMETHYLHEXANE 592132
6 DIMETHYLOCTANE 0
(2-BUTOXYETHOXY)-ETHANOL 112345
BUTYLTETRAHYDROFURAN 0
BUTYNE 503173
ETHYL HEXANOL 104767
ETHYL-1-BUTENE 760214
FURFURAL 98011
HEXENE 0
METHYL HEXANE 591764
METHYL-1-BUTENE 563462
METHYL-1-PENTENE 763291
METHYL-2-BUTENE 513359
METHYL-2-PENTENE 625274
METHYL-3-HEXANONE 7379126
METHYLDECANE 0
METHYLHEPTANE 592278
METHYLOCTANE 0
METHYLPENTANE - 107835
3 DIMETHYLPENTANE 562492
4 DIMETHYLOCTANE 0
5 DIMETHYLHEPTANE 0
5,5-TRIMETHYLHEXANE 0
(CHLOROMETHYL)-HEPTANE 0
HEPTENE 0
METHYL PENTANE 96140
METHYL-1-BUTENE 563451
METHYL-1-PENTENE 760203
METHYL-T-2-PENTENE 922612
METHYLHEPTANE 0
METHYLHEXANE 589344
METHYLOCTANE 0
4-METHYLENE DIANILINE 101779
METHYL-1-PENTENE 691372
METHYL-T-2-PENTENE 27236460
METHYLANILINE 100618
METHYLHEPTANE 589537
METHYLOCTANE - 0
PHENYL-1-BUTENE 0
D - 3
-------
Page No. 3
03/30/88
TABLE D-l. (Continued)
MOLECULAR
WEIGHT
136.24
154.21
152.20
44.05
60.05
102.09
58.08
26.04
56.07
72.06
53.06
146.14
100.00
72.10
223.23
93.13
276.34
178.23
208.23
136.24
136.24
106.13
78.11
228.30
252.32
252.32
252.32
276.34
252.32
228.30
252.32
122.13
252.32
135.19
126.59
154.21
170.00
262.03
247.02
56.10
128.21
148.00
SAROAD
NUMBER
43256
46706
46705
43503
43404
43604
43551
43206
43505
43407
43704
43409
43132
43570
46103
45701
46725
46709
46102
90052
43257
45501
45201
46716
46719
46717
46724
46721
46718
46735
46714
45402
46742
46602
45810
45226
45330
45704
45705
43213
43472
43337
SPECIES NAME CAS NUMBER
A-PINENE 80568
ACENAPHTHENE 83329
ACENAPHTHYLENE 208968
ACETALDEHYDE 75070
ACETIC ACID 64197
ACETIC ANHYDRIDE 108247
ACETONE 67641
ACETYLENE 74862
ACROLEIN 107028
ACRYLIC ACID 79107
ACRYLONITRILE 107131
ADIPIC ACID 124049
ALIPHATICS 0
ALKENE KETONE 0
AMINOANTHRAQUINONE 82451
ANILINE 62533
ANTHANTHRENE 191264
ANTHRACENE 120127
ANTHRAQUINONE 84651
B-PHELLANDRENE 0
B-PINENE 127913
BENZALDEHYDE ' 100527
BENZENE 71432
BENZO (a) ANTHRACENE 56553
BENZO (a) PYRENE 50328
BENZO (b) FLUORANTHENE 205992
BENZO (e) PYRENE 192972
BENZO (g,h,i) PERYLENE 191242
BENZO (k) FLUORANTHENE 207089
BENZO(c)PHENANTHRENE 195197
BENZO(g-,h,1) FLUORANTHENE 0
BENZOIC ACID 65850
BENZOPYRENES 0
BENZOTHIAZOLE 95169
BENZYL CHLORIDE 100447
BIPHENYL 92524
BIPHENYLOL 90437
BROMODINITROANILINE 1817738
BROMODINITROBENZENE 0
BUTENE 106989
BUTOXYBUTENE 0
BUTOXYETHOXYETHANOL 112345
D - 4
-------
Page No. 4
03/30/88
TABLE D-l. (Continued)
MOLECULAR
WEIGHT
162.00
128.17
134.21
178.23
162.23
118.17
192.00
140.27
171.22
72.12
16.04
140.00
154.00
168.00
182.00
196.00
210.00
224.00
238.00
252.00
266.00
28.55
84.16
112.21
280.00
294.00
308.00
322.00
336.00
350.00
364.00
378.00
392.00
406.00
42.08
84.16
420.00
434.00
448.00
462.00
476.00
490.00
SAROAD
NUMBER
43469
43440
45235
45455
43379
43308
45477
90101
45456
43510
99101
99110
99111
99112
99113
99114
99115
99116
99117
99118
99119
99102
98035
90013
99120
99121
99122
99123
99124
99125
99126
99127
99128
99129
99103
43283
99130
99131
99132
99133
99134
99135
SPECIES NAME
BUTOXYETHOXYETHANOL ACETATE
BUTYL ACRYLATE
BUTYL BENZENE
BUTYL BENZOATE
BUTYL CARBITOL
BUTYL CELLOSOLVE
BUTYLBENZYLPHTHALATE
BUTYLCYCLOHEXANE
BUTYLISOPROPYLPHTHALATE
BUTYRALDEHYDE
C-l COMPOUNDS
C-10 COMPOUNDS
C-ll COMPOUNDS
C-12 COMPOUNDS
C-13 COMPOUNDS
C-14 COMPOUNDS
C-15 COMPOUNDS
C-16 COMPOUNDS
C-17 COMPOUNDS
C-18 COMPOUNDS
C-19 COMPOUNDS
C-2 COMPOUNDS
C-2-HEXENE
C-2-OCTENE
C-20 COMPOUNDS
C-21 COMPOUNDS
C-22 COMPOUNDS
C-23 COMPOUNDS
C-24 COMPOUNDS
C-25 COMPOUNDS
C-26 COMPOUNDS
C-27 COMPOUNDS
C-28 COMPOUNDS
C-29 COMPOUNDS
C-3 COMPOUNDS
C-3-HEXENE
C-30 COMPOUNDS
C-31 COMPOUNDS
C-32 COMPOUNDS
C-33 COMPOUNDS
C-34 COMPOUNDS
C-35 COMPOUNDS
CAS NUMBER
124174
141322
104518
136607
112345
111762
85687
1678939
0
123728
0
0
0
0
0
0
0
0
0
0
. 0
0
592438
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
D - 5
-------
Page No. 5
03/30/88
TABLE D-l. (Continued)
MOLECULAR
WEIGHT
504.00
518.00
532.00
546.00
57.08
560.00
574.00
588.00
602.00
71.00
79.12
93.18
98.19
112.00
112.23
112.23
126.00
126.26
134.22
140.27
142.28
132.22
136.24
152.24
154.29
142.20
162.23
168.32
166.31
226.45
146.23
112.22
158.24
256.35
230.31
256.34
206.28
158.24
126.24
146.23
134.21
142.28
SAROAD
NUMBER
99136
99137
99138
99139
99104
99140
99141
99142
99143
99105
99106
99107
43115
99108
43116
43138
99109
43117
45110
43125
43135
45111
43153
43396
43146
45113
45610
43147
43152
43137
46711
43126
46729
46739
46740
46741
46730
46746
43127
45250
45109
43129
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
SPECIES NAME CAS NUMBER
C-36 COMPOUNDS 0
C-37 COMPOUNDS 0
C-38 COMPOUNDS 0
C-39 COMPOUNDS 0
C-4 COMPOUNDS 0
C-40 COMPOUNDS 0
C-41 COMPOUNDS 0
C-42 COMPOUNDS 0
C-43 COMPOUNDS 0
C-5 COMPOUNDS 0
C-6 COMPOUNDS 0
C-7 COMPOUNDS 0
C-7 CYCLOPARAFFINS 0
C-8 COMPOUNDS 0
C-8 CYCLOPARAFFINS 0
C-8 OLEFINS 0
C-9 COMPOUNDS 0
C-9 CYCLOPARAFFINS 0
CIO AROMATIC 0
CIO OLEFINS 0
CIO PARAFFINS . 0
C10H12 0
C10H16 0
C10H160 0
Cll OLEFINS 0
C11H10 0
C11H140 0
C12 OLEFINS 0
C12H22 0
C16 BRANCHED ALKANE 0
C2 ALKYL INDAN 0
C2 CYCLOHEXANE . 0
C2-ALKYL-ANTHRACENES 0
C2-ALKYL-BENZANTHRACENES 0
C2-ALKYL-BENZOPHENANTHRENES 0
C2-ALKYL-CHRYSENES 0
C2-ALKYL-PHENANTHRENES 0
C2-ALKYLNAPTHALENE 0
C3 CYCLOHEXANE 0
C3-ALKYLSTYRENE 0
C3/C4/C5 ALKYLBENZENES 0
C4 SUBSTITUTED CYCLOHEXANE 0
D - 6
-------
Page No. 6
03/30/88
TABLE D-l. (Continued)
MOLECULAR
WEIGHT
154.26
150.22
160.26
154.30
130.19
70.13
72.15
70.13
154.30
148.24
146.25
164.25
86.13
84.16
170.32
162.27
222.47
98.18
100.20
176.30
163.32
96.17
112.17
114.23
122.16
110.20
296.60
127.05
128.25
136.19
136.24
113.16
134.18
76.14
153.84
60.08
204.41
90.12
132.16
112.56
86.47
119.39
SAROAD
NUMBER
43467
45303
45248
43128
43459
43143
43144
43145
43130
45245
45246
45304
43399
43289
43131
45247
90019
43294
43142
45249
43140
43154
43395
43141
45310
43149
90020
43124
43136
45311
90050
43779
43377
43934
43804
43933
90130
43311
43452
45801
43840
43803
SPECIES NAME CAS NUMBER
C4 SUBSTITUTED CYCLOHEXANONE 0
C4-ALKYLPHENOLS 0
C4-ALKYLSTYRENES 0
C5 CYCLOHEXANE 0
C5 ESTER 0
C5 OLEFIN 0
C5 PARAFFIN 0
C5 PARAFFIN/OLEFIN 0
C5 SUBSTITUTED CYCLOHEXANE 0
C5-ALKYLBENZENES 0
C5-ALKYLBENZENES (UNSAT.) 0
C5-ALKYLPHENOLS 0
C5H100 0
C6 OLEFINS 0
C6 SUBSTITUTED CYCLOHEXANE 0
C6-ALKYLBENZENE 0
C6H1803SI3 . 0
C7 OLEFINS 0
C7 PARAFFINS 0
C7-ALKYLBENZENE 0
C7-C16 0
C7H12 0
C7H120 0
C8 PARAFFIN 0
C8 PHENOLS 0
C8H14 0
C8H2404SI4 0
C9 OLEFINS 0
C9 PARAFFIN 0
C9 PHENOLS 0
CAMPHENE 5794036
CAPROLACTAM 105602
CARBITOL 111900
CARBON SULFIDE 75150
CARBON TETRACHLORIDE 56235
CARBONYL SULFIDE 463581
CARYOPHYLLENE 87445
CELLOSOLVE 110805
CELLOSOLVE ACETATE 111159
CHLOROBENZENE 108907
CHLORODIFLUOROMETHANE 75456
CHLOROFORM 67663
D - 7
-------
Page No. 7
03/30/88
TABLE D-l. (Continued)
MOLECULAR
WEIGHT
154.47
88.54
104.46
228.29
112.22
56.11
70.13
300.36
130.19
108.14
70.09
120.20
84.16
100.16
98.15
82.14
226.28
247.36
190.25
70.14
68.11
138.25
136.24
138.25
32.04
210.32
300.53
116.16
278.35
278.35
302.38
278.36
130.23
278.35
147.01
120.91
84.94
170.92
140.27
106.12
111.20
162.19
SAROAD
NUMBER
43842
43862
43845
46715
90038
43217
43227
46726
46210
45605
43515
45210
43248
43317
43561
43273
46734
46731
46732
43242
43292
90033
90053
46753
99933
45230
45470
43320
46743
46722
46745
46744
43372
45452
45808
43823
43802
43841
98062
43373
90110
46751
SPECIES NAME CAS NUMBER
CHLOROPENTAFLUOROETHANE 76153
CHLOROPRENE 126998
CHLOROTRIFLUOROMETHANE 75729
CHRYSENE 218019
CIS-1,4 DIMETHYLCYCLOHEXANE 624293
CIS-2-BUTENE . 590181
CIS-2-PENTENE 627203
CORONENE 191071
CREOSOTE 8001589
CRESOL 1319773
CROTONALDEHYDE 123739
CUMENE (ISOPROPYL BENZENE) 98828
CYCLOHEXANE 110827
CYCLOHEXANOL 108930
CYCLOHEXANONE 108941
CYCLOHEXENE 110838
CYCLOPENTA(c,d)PYRENE - 27208373
CYCLOPENTA-ANTHRACENES 0
CYCLOPENTA-PHENANTHRENES 0
CYCLOPENTANE 287923
CYCLOPENTENE 142290
CYCLOPENTYLCYCLOPENTANE 0
D-LIMONENE 5989275
DECALINS 91178
DENATURANT 0
DI(ETHYLPHENYL) ETHANE 0
DI-C8 ALKYL PHTHALATE 0
DIACETONE ALCOHOL 123422
DIBENZANTHRACENES 0
DIBENZO(a,h) ANTHRACENE 53703
DIBENZOPYRENES .0
DIBENZPHENANTHRENES 0
DIBUTYL ETHER 142961
DIBUTYL PHTHALATE 84742
DICHLOROBENZENES 2531226
DICHLORODIFLUOROMETHANE 75718
DICHLOROMETHANE 75092
DICHLOROTETRAFLUORETHANE 76142
DIETHYLCYCLOHEXANE 0
DIETHYLENE GLYCOL 111466
DIETHYLMETHYLCYCLOHEXANES 0
DIHYDRONAPTHALENE 0
D - 8
-------
TABLE D-l. (Continued)
Page No.
03/30/88
8
MOLECULAR
WEIGHT
160.00
162.28
59.11
73.09
156.23
194.19
194.19
122.16
87.18
118.00
85.17
168.32
98.14
112.12
99.19
97.18
225.43
179.22
140.26
128.26
145.26
111.20
174.20
114.23
112.20
146.00
144.00
160.00
211.41
140.27
159.29
140.27
138.25
101.21
132.00
117.21
99.20
184.36
182.27
250.30
134.18
130.02
SAROAD
NUMBER
46204
45236
43780
43450
46703
45451
45450
45320
90060
43471
90061
90114
43565
98059
90064
90065
90074
45404
90069
98091
43333
90068
43476
90067
43286
46750
46752
46115
90076
90070
43332
90124
90112
90062
43477
43331
90063
90071
45232
45454
43374
45229
SPECIES NAME
DIHYDROXYNAPTHALENEDIONE
DIISOPROPYL BENZENE
DIMETHYL ALKYL AMINES
DIMETHYL FORMAMIDE
DIMETHYL NAPTHALENE
DIMETHYL PHTHALATE
DIMETHYL TEREPHTHALATE
DIMETHYLBENZYLALCOHOL
DIMETHYLBUTANE
DIMETHYLBUTANEDIOATE
DIMETHYLBUTENE
DIMETHYLBUTYLCYCLOHEXANE
DIMETHYLCYCLOBUTANONE
DIMETHYLCYCLOHEXANE
DIMETHYLCYCLOPENTANE
DIMETHYLCYCLOPENTENES
DIMETHYLDECANE
DIMETHYLETHYLBENZOICACID
DIMETHYLETHYLCYCLOHEXANE
DIMETHYLHEPTANES
DIMETHYLHEPTANOL
DIMETHYLHEXADIENE
DIMETHYLHEXANEDIOATE
DIMETHYLHEXANES
DIMETHYLHEXENE
DIMETHYLINDANS
DIMETHYLINDENE
DIMETHYLNAPHTHYRIDINE
DIMETHYLNONANES
DIMETHYLOCTANES
DIMETHYLOCTANOL
DIMETHYLOCTENES
DIMETHYLOCTYNE
DIMETHYLPENTANE
DIMETHYLPENTANEDIOATE
DIMETHYLPENTANOL
DIMETHYLPENTENE
DIMETHYLUNDECANE
DIPHENYL ETHANE
DIPROPYL PHTHALATE
DIPROPYLENE GLYCOL
DIVINYL BENZENE
CAS NUMBER
0
0
0
68122
28804888
131113
120616
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
103297
131168
106627
1321740
D - 9
-------
Page No. 9
03/30/88
TABLE D-l. (Continued)
MOLECULAR
WEIGHT
168.32
282.56
92.53
30.07
61.08
88.10
100.11
46.07
64.52
74.12
62.13
132.21
210.32
45.09
106.16
223.42
112.23
98.19
96.17
122.21
141.27
172.35
128.26
150.22
28.05
187.88
99.00
62.07
44.05
43.07
96.14
128.26
127.05
114.23
144.24
318.89
88.15
126.24
112.21
128.26
156.31
142.29
SAROAD
NUMBER
90001
90126
43863
43202
43777
43433
43438
43302
43812
43351
43902
45228
45233
43721
45203
90086
43288
98057
90079
45243
90089
90129
90087
45302
43203
43837
43815
43370
43601
43778
43392
90084
98082
90081
43473
46754
98106
90083
90080
90082
90085
90077
SPECIES NAME CAS NUMBER
DODECENE 112414
EICOSANE 112958
EPICHLOROHYDRIN 106898
ETHANE 74840
ETHANOLAMINE 141435
ETHYL ACETATE 141786
ETHYL ACRYLATE 140885
ETHYL ALCOHOL 64175
ETHYL CHLORIDE 75003
ETHYL ETHER 60297
ETHYL MERCAPTAN 75081
ETHYL STYRENE 0
ETHYL-PHENYL-PHENYL-ETHANE 0
ETHYLAMINE 75057
ETHYLBENZENE 100414
ETHYLBICYCLOHEPTANE 0
ETHYLCYCLOHEXANE 1678917
ETHYLCYCLOPENTANE 1640897
ETHYLCYCLOPENTENE 0
ETHYLDIMETHYLBENZENE 0
ETHYLDIMETHYLCYCLOHEXANE 0
ETHYLDIMETHYLOCTANE 0
ETHYLDIMETHYLPENTANE 0
ETHYLDIMETHYLPHENOL 0
ETHYLENE 74851
ETHYLENE DIBROMIDE 106934
ETHYLENE DICHLORIDE 107062
ETHYLENE GLYCOL 107211
ETHYLENE OXIDE 75218
ETHYLENEAMINES 0
ETHYLFURAN 0
ETHYLHEPTANE 0
ETHYLHEPTENE 0
ETHYLHEXANE 0
ETHYLHEXANOATE 0
ETHYLINDAN 0
ETHYLISOPROPYL ETHER 0
ETHYLMETHYLCYCLOHEXANES 0
ETHYLMETHYLCYCLOPENTANE 0
ETHYLMETHYLHEXANE 0
ETHYLMETHYLOCTANE 0
ETHYLOCTANE 0
D -10
-------
TABLE D-l. (Continued)
Page No.
03/30/88
10
MOLECULAR
WEIGHT
100.16
98.19
154.29
120.19
202.26
166.22
30.03
46.03
98.10
92.09
61.09
106.12
58.04
296.59
125.19
100.20
98.18
226.45
286.42
111.16
138.01
116.20
100.16
86.17
84.16
118.18
82.15
118.18
116.16
276.34
72.15
58.12
60.09
88.15
116.16
128.19
74.12
144.21
134.22
56.10
72.11
56.10
SAROAD
NUMBER
90075
90078
90090
45238
46710
46707
43502
43403
45604
43380
43368
43367
43513
90125
90059
43232
43264
90030
43410
90058
43843
43776
43512
43231
90056
43371
90037
98044
46712
46720
43221
43214
43304
43330
43446
43468
43306
43451
99915
43215
43511
43120
SPECIES NAME
ETHYLOCTENE
ETHYLPENTENE
ETHYLPROPYLCYCLOHEXANES
ETHYLTOLUENE
FLUORANTHENE
FLUORENE
FORMALDEHYDE
FORMIC ACID
FURFURYL ALCOHOL
GLYCEROL
GLYCOL
GLYCOL ETHER
GLYOXAL
HENEICOSANE
HEPTADIENAL
HEPTANE
HEPTENE
HEXADECANE
HEXADECANOIC ACID
HEXADIENAL
HEXAFLUOROETHANE
HEXAMETHYLENEDIAMINE
HEXANAL
HEXANE
HEXENE
HEXYLENE GLYCOL
HEXYNE
INDANE
INDENE
INDENO(l,2,3-cd) PYRENE
ISO PENTANE
ISO-BUTANE
ISO-PROPYL ALCOHOL
ISOAMYL ALCOHOL
ISOBUTYL ACETATE
ISOBUTYL ACRYLATE
ISOBUTYL ALCOHOL
ISOBUTYL ISOBUTYRATE
ISOBUTYLBENZENE
ISOBUTYLENE
ISOBUTYRALDEHYDE
ISOMERS OF BUTENE
CAS NUMBER
0
0
0
0
206440
86737
50000
64186
98000
56815
0
0
107222
629947
0
142825
0
544763
0
142836
76164
124094
66251
110543
0
107415
0
496117
95136
193395
78784
75285
67630
123513
110190
106638
78831
297858
538932
115117
78842
0
D -11
-------
TABLE D-l. (Continued)
Page No.
03/30/88
11
MOLECULAR
WEIGHT
134.22
130.19
138.25
152.28
124.23
142.28
134.21
170.32
120.19
240.47
100.20
86.17
128.25
254.50
114.23
212.41
72.15
70.13
120.19
198.38
184.36
156.30
106.16
68.12
102.13
126.25
113.22
140.27
86.14
114.00
136.24
147.01
134.22
120.19
106.16
106.16
98.06
16.04
120.00
116.00
158.20
86.09
SAROAD
NUMBER
45105
45112
43150
43151
43148
43109
45106
43111
45104
43155
43106
43105
43108
43156
43107
43114
43122
43121
45108
43113
43112
43110
45102
43243
43444
90128
90116
90111
98056
43119
90117
45806
45218
45212
45205
90010
43603
43201
43335
43569
46203
43437
SPECIES NAME CAS NUMBER
ISOMERS OF BUTYLBENZENE 0
ISOMERS OF C10H10 0
ISOMERS OF C10H18 0
ISOMERS OF C11H20 0
ISOMERS OF C9H16 0
ISOMERS OF DECANE 0
ISOMERS OF DIETHYLBENZENE 0
ISOMERS OF DODECANE 0
ISOMERS OF ETHYLTOLUENE 0
ISOMERS OF HEPTADECANE 0
ISOMERS OF HEPTANE 0
ISOMERS OF HEXANE 0
ISOMERS OF NONANE 0
ISOMERS OF OCTADECANE 0
ISOMERS OF OCTANE 0
ISOMERS OF PENTADECANE 0
ISOMERS OF PENTANE 0
ISOMERS OF PENTENE 0
ISOMERS OF PROPYLBENZENE 0
ISOMERS OF TETRADECANE 0
ISOMERS OF TRIDECANE 0
ISOMERS OF UNDECANE 0
ISOMERS OF XYLENE 1330207
ISOPRENE 78795
ISOPROPYL ACETATE 108214
ISOPROPYLCYCLOHEXANE 0
ISOPROPYLCYCLOPENTANE 0
ISOPROPYLMETHYLCYCLOHEXANE 0
ISOVALERALDEHYDE 590863
LACTOL SPIRITS 0
LIMONENE 5989275
M-DICHLOROBENZENE 541731
M-DIETHYLBENZENE 141935
M-ETHYLTOLUENE 620144
M-XYLENE 108383
M-XYLENE AND P-XYLENE 0
MALEIC ANHYDRIDE 108316
METHANE 74828
METHOXYETHOXYETHANOL 0
METHOXYMETHYLBUTANONE 0
METHOXYNAPHTHALENE 0
METHYL ACRYLATE 96333
D -12
-------
TABLE D-l. (Continued)
Page No.
03/30/88
12
MOLECULAR
WEIGHT
32.04
114.21
168.24
100.16
314.28
338.56
362.58
386.60
410.62
506.68
530.70
120.15
76.11
50.49
214.35
72.10
60.05
72.07
100.16
100.13
242.41
142.20
270.46
298.52
118.19
88.15
192.26
242.33
242.33
242.33
216.29
192.26
74.08
134.17
40.06
76.09
54.09
68.12
70.13
94.15
98.21
96.17
SAROAD
NUMBER
43301
43562
45227
43559
43460
43461
43462
43463
43464
43465
43466
43378
43310
43801
43470
43552
43430
43514
43560
43441
43455
46702
43454
43456
45221
43376
46727
46736
46737
46738
46733
46728
43432
45550
43209
43457
90011
90024
90023
90041
43261
90046
SPECIES NAME CAS NUMBER
METHYL ALCOHOL 67561
METHYL AMYL KETONE 110430
METHYL BIPHENYL 0
METHYL BUTYL KETONE 591786
METHYL Cll ESTER 0
METHYL C12 ESTER 0
METHYL C13 ESTER 0
METHYL C14 ESTER 0
METHYL C15 ESTER 0
METHYL C19 ESTER 0
METHYL C20 ESTER 0
METHYL CARBITOL 111773
METHYL CELLOSOLVE 109864
METHYL CHLORIDE 74873
METHYL DODECANOATE 111820
METHYL ETHYL KETONE 78933
METHYL FORMATE 107313
METHYL GLYOXAL 78988
METHYL ISOBUTYL KETONE 108101
METHYL METHACRYLATE 80626
METHYL MYRISTATE 124107
METHYL NAPHTHALENES - 0
METHYL PALMITATE 112390
METHYL STEARATE 112618
METHYL STYRENE 25013154
METHYL T-BUTYL ETHER 628284
METHYL-ANTHRACENES 0
METHYL-BENZANTHRACENES 0
METHYL-BENZPHENANTHRENES 0
METHYL-CHRYSENES 0
METHYL-FLUORANTHENES 0
METHYL-PHENANTHRENES 0
METHYLACETATE 79209
METHYLACETOPHENONE 0
METHYLACETYLENE (PROPYNE) 74997
METHYLAL 109375
METHYLALLENE 0
METHYLBUTADIENE 0
METHYLBUTENE 0
METHYLCYCLOHEXADIENE 4313579
METHYLCYCLOHEXANE - 108872
METHYLCYCLOHEXENE 0
D -13
-------
TABLE D-l. (Continued)
Page No.
03/30/88
13
MOLECULAR
WEIGHT
127.25
80.14
84.16
82.14
170.34
156.32
154.29
176.21
184.36
173.85
84.93
250.27
142.22
0.00
114.23
131.24
112.22
110.20
96.17
146.36
100.20
98.18
132.21
130.19
140.27
100.13
142.28
140.26
128.26
86.17
84.16
58.12
56.10
168.32
183.35
170.34
114.00
136.24
58.12
116.16
74.12
142.28
SAROAD
NUMBER
90017
90027
43262
43272
46748
90048
90107
46749
90108
43805
43802
45730
90121
43475
90045
43334
98090
90044
90039
90043
90028
90029
46747
90119
90073
43474
90047
90106
90104
90026
90025
90021
90022
90072
90102
90049
43118
90051
43212
43435
43305
43238
SPECIES NAME CAS NUMBER
METHYLCYCLOOCTANE 0
METHYLCYCLOPENTADIENE 0
METHYLCYCLOPENTANE 96377
METHYLCYCLOPENTENE 693890
METHYLDECALINS 0
METHYLDECANES 0
METHYLDECENE 0
METHYLDIHYDRONAPHTHALENE 0
METHYLDODECANE 0
METHYLENE BROMIDE 74953
METHYLENE CHLORIDE 75092
METHYLENE(b)4-PHENYLISOCYANATE 101688
METHYLETHYLHEPTANE 0
METHYLETHYLPENTANOATE 0
METHYLHEPTANE 0
METHYLHEPTANOL 0
METHYLHEPTENE 0
METHYLHEPTYNE 0
METHYLHEXADIENE 0
METHYLHEXANAL 0
METHYLHEXANE 0
METHYLHEXENES - 0
METHYLINDANS 0
METHYLINDENE 0
METHYLISOPROPYLCYCLOHEXANE 0
METHYLMETHYLPROPENOATE 0
METHYLNONANE 0
METHYLNONENE 0
METHYLOCTANES 0
METHYLPENTANE 0
METHYLPENTENES 0
METHYLPROPANE 0
METHYLPROPENE 0
METHYLPROPYLCYCLOHEXANES 0
METHYLPROPYLNONANE 0
METHYLUNDECANE 0
MINERAL SPIRITS 0
MYRCENE 123353
N-BUTANE 106978
N-BUTYL ACETATE 138227
N-BUTYL ALCOHOL - 71363
N-DECANE 124185
D -14
-------
TABLE D-l. (Continued)
Page No.
03/30/88
14
MOLECULAR
WEIGHT
170.33
240.46
212.41
72.15
70.14
154.30
169.24
102.15
60.10
120.19
198.38
184.36
156.31
114.00
123.11
123.11
268.53
124.23
128.25
127.05
138.25
220.36
147.01
120.19
106.16
244.00
225.20
296.62
114.23
130.26
108.19
112.21
86.00
147.01
120.16
106.16
256.43
352.43
65.14
197.38
68.13
88.15
SAROAD
NUMBER
43255
90031
43260
43220
90035
98063
45706
43434
43303
45209
43259
43258
43241
45101
46701
45702
90127
90066
43235
90100
43568
45301
45805
45211
45204
46202
90118
43950
43233
43336
90099
43265
43650
45807
45502
45206
43408
43133
43139
43134
90103
43319
SPECIES NAME CAS NUMBER
N-DODECANE 112403
N-HEPTADECANE 629787
N-PENTADECANE 629629
N-PENTANE 109660
N-PENTENE 25377724
N-PENTYLCYCLOHEXANE 0
N-PHENYLANILINE 0
N-PROPYL ACETATE 109604
N-PROPYL ALCOHOL 71238
N-PROPYLBENZENE 103651
N-TETRADECANE 629594
N-TRIDECANE 629505
N-UNDECANE 1120214
NAPHTHA 0
NAPTHALENE 91203
NITROBENZENE 98953
NONADECANE 0
NONADIENE ' 0
NONANE 111842
NONENE 0
NONENONE 0
NONYLPHENOL 25154523
0-DICHLOROBENZENE 95501
0-ETHYLTOLUENE 611143
0-XYLENE 95476
OCTAHYDROINDENES 0
OCTAHYDROPENTALENE 0
OCTAMETHYLCYCLOTETRASILOXANE 556672
OCTANE 111659
OCTANOL 0
OCTATRIENE 0
OCTENE 11.1660
OXYGENATES 0
P-DICHLOROBENZENE 106467
P-TOLUALDEHYDE 104870
P-XYLENE 106423
PALMITIC ACID 57103
PARAFFINS (C16-C34) 0
PARAFFINS (C2-C7) 0
PARAFFINS/OLEFINS (C12-C16) 0
PENTADIENE 0
PENTANOL 71410
D -15
-------
TABLE D-l. (Continued)
Page No.
03/30/88
15
MOLECULAR
WEIGHT
68.12
148.25
154.29
443.11
68.12
165.83
252.32
178.23
94.11
119.13
204.27
148.00
68.12
200.00
40.06
44.09
42.08
141.23
58.08
74.08
126.24
112.99
76.00
58.08
141.28
202.26
74.12
134.21
76.08
104.14
218.24
131.20
56.11
84.16
126.24
84.16
166.14
136.23
74.12
134.21
215.90
88.01
SAROAD
NUMBER
90054
45231
90055
90113
90036
43817
46723
46708
45300
46112
46704
45601
45750
43381
43208
43204
43205
90105
43504
43405
90120
43838
43369
43602
90109
46713
43314
45216
43951
45220
43458
45242
43216
98034
90034
90042
45403
43123
43309
45215
45831
43839
SPECIES NAME CAS NUMBER
PENTENYNE 0
PENTYL BENZENE 0
PENTYLCYCLOHEXANE 0
PENTYLIDENECYCLOHEXANE 0
PENTYNE 0
PERCHLOROETHYLENE 127184
PERYLENE 198550
PHENANTHRENE 85018
PHENOL 108952
PHENYL ISOCYANATE 103719
PHENYLNAPHTHALENES 0
PHTHALIC ANHYDRIDE 85449
PIPERYLENE 504609
POLYETHYLENE GLYCOL 25322683
PROPADIENE 463490
PROPANE 74986
PROPENE 115071
PROPENYLCYCLOHEXANE 0
PROPIONALDEHYDE 123386
PROPIONIC ACID 79094
PROPYLCYCLOHEXANE 0
PROPYLENE DICHLORIDE 26638197
PROPYLENE GLYCOL 57556
PROPYLENE OXIDE 75569
PROPYLHEPTENES 0
PYRENE 129000
S-BUTYL ALCOHOL 78922
S-BUTYLBENZENE 135988
SILOXANE 0
STYRENE 100425
SUBSTITUTED C9 ESTER (C12) 0
T-1-PHENYLBUTENE 0
T-2-BUTENE 624646
T-2-HEXENE 40504557
T-2-NONENE 6434782
T-3-HEXENE 13269528
TEREPHTHALIC ACID 100210
TERPENES 0
TERT-BUTYL ALCOHOL 75650
TERT-BUTYLBENZENE 98066
TETRACHLOROBENZENES 0
TETRAFLUOROMETHANE 75730
D -16
-------
TABLE D-l. (Continued)
Page No.
03/30/88
16
MOLECULAR
WEIGHT
134.22
110.19
126.24
145.31
157.25
88.23
132.25
92.13
174.17
117.15
93.13
72.12
70.13
181.45
131.40
137.38
187.38
150.17
70.01
59.11
120.19
129.27
142.24
112.16
125.11
182.35
182.35
92.00
142.29
128.26
126.24
333.92
168.32
156.31
107.16
114.22
86.00
86.09
62.50
230.00
SAROAD
NUMBER
45244
90091
90098
90122
43567
43952
46601
45202
45731
45732
45740
43520
43226
45830
43824
43811
43821
43375
43844
43740
45107
98060
43397
98058
43566
90097
98083
43822
90094
90115
90095
46755
90123
90096
90093
90092
99999
43453
43860
45401
SPECIES NAME
TETRAMETHYLBENZENE
TETRAMETHYLCYCLOBUTENE
TETRAMETHYLCYCLOPENTANE
TETRAMETHYLHEXANE
TETRAMETHYLPENTANONE
TETRAMETHYLSILANE
TETRAMETHYLTHIOUREA
TOLUENE
TOLUENE DIISOCYANATE
TOLUENEISOCYANIDE
TOTAL AROMATIC AMINES
TOTAL C2-C5 ALDEHYDES
TRANS-2-PENTENE
TRICHLOROBENZENES
TRICHLOROETHYLENE
TRICHLOROFLUOROMETHANE
TRICHLOROTRIFLUOROETHANE
TRIETHYLENE GLYCOL
TRIFLUOROMETHANE
TRIMETHYLAMINE
TRIMETHYLBENZENE
TRIMETHYLCYCLOHEXANES
TRIMETHYLCYCLOHEXANOL
TRIMETHYLCYCLOPENTANE
TRIMETHYLCYCLOPENTANONE
TRIMETHYLDECANE
TRIMETHYLDECENE
TRIMETHYLFLUOROSILANE
TRIMETHYLHEPTANES
TRIMETHYLHEXANES
TRIMETHYLHEXENE
TRIMETHYLINDAN
TRIMETHYLNONENE
TRIMETHYLOCTANES
TRIMETHYLPENTADIENE
TRIMETHYLPENTANE
UNIDENTIFIED
VINYL ACETATE
VINYL CHLORIDE
XYLENE BASE ACIDS
CAS NUMBER
0
0
0
0
0
75763
2782914
108883
58849
0
0
0
646048
0
79016
75694
76131
112276
75467
75503
25551137
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
108054
75014
0
D - 17
-------
TABLE D-2. SPECIES DATA FILE (ACCORDING TO SAROAD CODE)
Page No. 1
03/30/88
MOLECULAR
WEIGHT
86.17
100.20
114.23
128.25
142.28
156.30
170.32
184.36
198.38
212.41
98.19
112.23
126.26
114.00
114.00
56.10
70.13
72.15
136.23
127.05
140.27
112.22
126.24
154.30
142.28
154.30
170.32
100.00
352.43
197.38
142.28
128.25
226.45
112.23
65.14
163.32
114.23
100.20
70.13
72.15
70.13
154.29
SAROAD
NUMBER
43105
43106
43107
43108
43109
43110
43111
43112
43113
43114
43115
43116
43117
43118
43119
43120
43121
43122
43123
43124
43125
43126
43127
43128
43129
43130
43131
43132
43133
43134
43135
43136
43137
43138
43139
43140
43141
43142
43143
43144
43145
43146
SPECIES NAME CAS NUMBER
ISOMERS OF HEXANE 0
ISOMERS OF HEPTANE 0
ISOMERS OF OCTANE 0
ISOMERS OF NONANE 0
ISOMERS OF DECANE 0
ISOMERS OF UNDECANE 0
ISOMERS OF DODECANE 0
ISOMERS OF TRIDECANE 0
ISOMERS OF TETRADECANE 0
ISOMERS OF PENTADECANE 0
C-7 CYCLOPARAFFINS 0
C-8 CYCLOPARAFFINS 0
C-9 CYCLOPARAFFINS 0
MINERAL SPIRITS 0
LACTOL SPIRITS 0
ISOMERS OF BUTENE 0
ISOMERS OF PENTENE . 0
ISOMERS OF PENTANE 0
TERPENES 0
C9 OLEFINS 0
CIO OLEFINS 0
C2 CYCLOHEXANE 0
C3 CYCLOHEXANE 0
C5 CYCLOHEXANE 0
C4 SUBSTITUTED CYCLOHEXANE 0
C5 SUBSTITUTED CYCLOHEXANE 0
C6 SUBSTITUTED CYCLOHEXANE 0
ALIPHATICS 0
PARAFFINS (C16-C34) 0
PARAFFINS/OLEFINS (C12-C16) 0
CIO PARAFFINS 0
C9 PARAFFIN 0
C16 BRANCHED ALKANE 0
C-8 OLEFINS 0
PARAFFINS (C2-C7) 0
C7-C16 0
C8 PARAFFIN 0
C7 PARAFFINS 0
C5 OLEFIN 0
C5 PARAFFIN 0
C5 PARAFFIN/OLEFIN 0
Cll OLEFINS 0
D -18
-------
Page No. 2
03/30/88
TABLE D-2. (Continued)
MOLECULAR
WEIGHT
168.32
124.23
110.20
138.25
152.28
166.31
136.24
96.17
240.47
254.50
16.04
30.07
28.05
44.09
42.08
26.04
40.06
40.06
84.16
58.12
56.10
58.12
56.10
56.11
56.11
54.09
72.15
72.15
72.17
70.13
70.13
70.13
70.13
70.13
70.13
86.17
86.17
86.17
100.20
114.23
84.16
128.25
SAROAD
NUMBER
43147
43148
43149
43150
43151
43152
43153
43154
43155
43156
43201
43202
43203
43204
43205
43206
43208
43209
43211
43212
43213
43214
43215
43216
43217
43218
43220
43221
43222
43223
43224
43225
43226
43227
43228
43229
43230
43231
43232
43233
43234
43235
SPECIES NAME CAS NUMBER
C12 OLEFINS 0
ISOMERS OF C9H16 0
C8H14 0
ISOMERS OF C10H18 0
ISOMERS OF C11H20 0
C12H22 0
C10H16 0
C7H12 0
ISOMERS OF HEPTADECANE 0
ISOMERS OF OCTADECANE 0
METHANE 74828
ETHANE 74840
ETHYLENE 74851
PROPANE 74986
PROPENE 115071
ACETYLENE 74862
PROPADIENE 463490
METHYLACETYLENE (PROPYNE) 74997
3-METHYL-l-PENTENE 760203
N-BUTANE 106978
BUTENE 106989
ISO-BUTANE - 75285
ISOBUTYLENE 115117
T-2-BUTENE 624646
CIS-2-BUTENE 590181
1,3-BUTADIENE 106990
N-PENTANE 109660
ISO PENTANE 78784
2,2 DIMETHYLPROPANE 463821
3-METHYL-l-BUTENE 563451
1-PENTENE 109671
2-METHYL-l-BUTENE 563462
TRANS-2-PENTENE 646048
CIS-2-PENTENE 627203
2-METHYL-2-BUTENE 513359
2-METHYLPENTANE 107835
3-METHYL PENTANE 96140
HEXANE 110543
HEPTANE 142825
OCTANE 111659
2,3 DIMETHYL-1-BUTENE 563780
NONANE 111842
D -19
-------
Page No. 3
03/30/88
TABLE D-2. (Continued)
MOLECULAR
WEIGHT
142.28
156.31
70.14
68.12
84.16
100.20
84.16
114.22
114.22
170.33
136.24
136.24
184.36
198.38
212.41
98.21
84.16
100.20
98.18
112.21
127.05
84.16
128.26
82.14
82.14
100.20
86.17
114.22
114.22
84.16
114.22
54.09
54.09
84.16
84.16
84.16
112.20
114.22
112.23
84.16
114.22
86.17
SAROAD
NUMBER
43238
43241
43242
43243
43245
43247
43248
43250
43252
43255
43256
43257
43258
43259
43260
43261
43262
43263
43264
43265
43269
43270
43271
43272
43273
43274
43276
43277
43278
43279
43280
43281
43282
43283
43284
43285
43286
43287
43288
43289
43290
43291
SPECIES NAME
N-DECANE
N-UNDECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2,4-DIMETHYLPENTANE
CYCLOHEXANE
2,2,4-TRIMETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
N-DODECANE
A-PINENE
B-PINENE
N-TRIOECANE
N-TETRADECANE
N-PENTADECANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-METHYL HEXANE
HEPTENE
OCTENE
1-NONENE
3-METHYL-T-2-PENTENE
3,5,5-TRIMETHYLHEXANE
METHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
2,4-DIMETHYLHEXANE
2,5-DIMETHYLHEXANE
2-ETHYL-l-BUTENE
2,3,3 TRIMETHYLPENTANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
2,2 DIMETHYLHEXANE
ETHYLCYCLOHEXANE
C6 OLEFINS
2,3 DIMETHYLHEXANE
2,2-DIMETHYLBUTANE
CAS NUMBER
124185
1120214
287923
78795
592416
108087
110827
540841
565753
112403
80568
127913
629505
629594
629629
108872
96377
591764
0
111660
124118
922612
0
693890
110838
565593
79298
0
592132
760214
0
107006
503173
0
625274
0
0
590738
1678917
0
0
75832
D -20
-------
Page No. 4
03/30/88
TABLE D-2. (Continued)
MOLECULAR
WEIGHT
68.11
84.18
98.18
100.20
114.23
114.23
114.23
96.17
32.04
46.07
60.10
60.09
74.12
74.12
118.17
74.12
76.11
90.12
162.18
104.15
74.12
100.16
130.23
88.15
116.16
90.12
88.15
117.21
159.29
145.26
131.24
120.00
130.26
148.00
74.12
106.12
61.09
76.00
62.07
118.18
130.23
106.12
SAROAD
NUMBER
43292
43293
43294
43295
43296
43297
43298
43299
43301
43302
43303
43304
43305
43306
43308
43309
43310
43311
43312
43313
43314
43317
43318
43319
43320
43322
43330
43331
43332
43333
43334
43335
43336
43337
43351
43367
43368
43369
43370
43371
43372
43373
SPECIES NAME CAS NUMBER
CYCLOPENTENE 142290
4-METHYL-T-2-PENTENE 27236460
C7 OLEFINS 0
3-METHYLHEXANE 589344
2-METHYLHEPTANE 592278
4-METHYLHEPTANE 589537
3-METHYLHEPTANE 0
1-METHYLCYCLOHEXENE 0
METHYL ALCOHOL 67561
ETHYL ALCOHOL 64175
N-PROPYL ALCOHOL 71238
ISO-PROPYL ALCOHOL 67630
N-BUTYL ALCOHOL 71363
ISOBUTYL ALCOHOL 78831
BUTYL CELLOSOLVE . 111762
TERT-BUTYL ALCOHOL 75650
METHYL CELLOSOLVE 109864
CELLOSOLVE 110805
2-(2-BUTOXYETHOXY)-ETHANOL 112345
l-ETHOXY-2-PROPANOL 0
S-BUTYL ALCOHOL 78922
CYCLOHEXANOL 108930
2-ETHYL HEXANOL 104767
PENTANOL 71410
DIACETONE ALCOHOL 123422
1,4 BUTANEDIOL 110634
ISOAMYL ALCOHOL 123513
DIMETHYLPENTANOL 0
DIMETHYLOCTANOL 0
DIMETHYLHEPTANOL 0
METHYLHEPTANOL 0
METHOXYETHOXYETHANOL 0
OCTANOL 0
BUTOXYETHOXYETHANOL 112345
ETHYL ETHER 60297
GLYCOL ETHER 0
GLYCOL 0
PROPYLENE GLYCOL 57556
ETHYLENE GLYCOL * 107211
HEXYLENE GLYCOL 107415
DIBUTYL ETHER 142961
DIETHYLENE GLYCOL 111466
D -21
-------
Page No. 5
03/30/88
TABLE D-2. (Continued)
MOLECULAR
WEIGHT
134.18
150.17
88.15
134.18
120.15
162.23
92.09
200.00
128.19
96.14
112.17
152.24
142.24
86.13
46.03
60.05
74.08
72.06
256.43
146.14
286.42
60.05
74.08
88.10
102.15
116.16
86.09
100.11
128.17
100.13
102.13
116.16
73.09
144.21
132.16
86.09
270.46
242.41
298.52
76.09
218.24
130.19
SAROAD
NUMBER
43374
43375
43376
43377
43378
43379
43380
43381
43391
43392
43395
43396
43397
43399
43403
43404
43405.
43407
43408
43409
43410
43430
43432
43433
43434
43435
43437
43438
43440
43441
43444
43446
43450
43451
43452
43453
43454
43455
43456
43457
43458
43459
SPECIES NAME CAS NUMBER
DIPROPYLENE GLYCOL 106627
TRIETHYLENE GLYCOL 112276
METHYL T-BUTYL ETHER 628284
CARBITOL 111900
METHYL CARBITOL 111773
BUTYL CARBITOL 112345
GLYCEROL 56815
POLYETHYLENE GLYCOL 25322683
2-BUTYLTETRAHYDROFURAN 0
ETHYLFURAN 0
C7H120 0
C10H160 0
TRIMETHYLCYCLOHEXANOL 0
C5H100 0
FORMIC ACID 64186
ACETIC ACID 64197
PROPIONIC ACID 79094
ACRYLIC ACID 79107
PALMITIC ACID 57103
ADIPIC ACID 124049
HEXADECANOIC ACID 0
METHYL FORMATE 107313
METHYLACETATE 79209
ETHYL ACETATE 141786
N-PROPYL ACETATE 109604
N-BUTYL ACETATE 138227
METHYL ACRYLATE 96333
ETHYL ACRYLATE 140885
BUTYL ACRYLATE ' 141322
METHYL METHACRYLATE 80626
ISOPROPYL ACETATE 108214
ISOBUTYL ACETATE 110190
DIMETHYL FORMAMIDE 68122
ISOBUTYL ISOBUTYRATE 297858
CELLOSOLVE ACETATE 111159
VINYL ACETATE 108054
METHYL PALMITATE 112390
METHYL MYRISTATE 124107
METHYL STEARATE 112618
METHYLAL 109375
SUBSTITUTED C9 ESTER (C12) 0
C5 ESTER 0
D -22
-------
Page No. 6
03/30/88
TABLE D-2. (Continued)
MOLECULAR
WEIGHT
314.28
338.56
362.58
386.60
410.62
506.68
530.70
154.26
128.19
162.00
214.35
118.00
128.21
144.24
100.13
0.00
174.20
132.00
30.03
44.05
58.08
56.07
72.12
72.11
100.16
58.04
72.07
70.09
72.12
58.08
72.10
100.16
100.16
98.15
114.21
114.19
98.14
125.11
157.25
138.25
116.00
72.10
SAROAD
NUMBER
43460
43461
43462
43463
43464
43465
43466
43467
43468
43469
43470
43471
43472
43473
43474
43475
43476
43477
43502
43503
43504
43505
43510
43511
43512
43513
43514
43515
43520
43551
43552
43559
43560
43561
43562
43563
43565
43566
43567
43568
43569
43570
SPECIES NAME CAS NUMBER
METHYL Cll ESTER 0
METHYL C12 ESTER 0
METHYL C13 ESTER 0
METHYL C14 ESTER 0
METHYL C15 ESTER 0
METHYL C19 ESTER 0
METHYL C20 ESTER 0
C4 SUBSTITUTED CYCLOHEXANONE 0
ISOBUTYL ACRYLATE 106638
BUTOXYETHOXYETHANOL ACETATE 124174
METHYL DODECANOATE 111820
DIMETHYLBUTANEDIOATE 0
BUTOXYBUTENE 0
ETHYLHEXANOATE 0
METHYLMETHYLPROPENOATE 0
METHYLETHYLPENTANOATE 0
DIMETHYLHEXANEDIOATE 0
DIMETHYLPENTANEDIOATE 0
FORMALDEHYDE 50000
ACETALDEHYDE 75070
PROPIONALDEHYDE 123386
ACROLEIN 107028
BUTYRALDEHYDE 123728
ISOBUTYRALDEHYDE 78842
HEXANAL 66251
GLYOXAL 107222
METHYL GLYOXAL 78988
CROTONALDEHYDE 123739
TOTAL C2-C5 ALDEHYDES 0
ACETONE 67641
METHYL ETHYL KETONE 78933
METHYL BUTYL KETONE 591786
METHYL ISOBUTYL KETONE 108101
CYCLOHEXANONE 108941
METHYL AMYL KETONE 110430
2-METHYL-3-HEXANONE 7379126
DIMETHYLCYCLOBUTANONE 0
TRIMETHYLCYCLOPENTANONE 0
TETRAMETHYLPENTANONE 0
NONENONE 0
METHOXYMETHYLBUTANONE 0
ALKENE KETONE 0
D -23
-------
Page No. 7
03/30/88
TABLE D-2. (Continued)
MOLECULAR
WEIGHT
44.05
58.08
98.06
102.09
86.00
53.06
45.09
59.11
116.20
61.08
43.07
113.16
59.11
50.49
84.94
84.93
119.39
153.84
173.85
137.38
64.52
133.42
99.00
165.83
133.42
187.38
92.00
120.91
131.40
92.57
148.68
187.88
112.99
88.01
86.47
170.92
154.47
138.01
70.01
104.46
62.50
88.54
SAROAD
NUMBER
43601
43602
43603
43604
43650
43704
43721
43740
43776
43777
43778
43779
43780
43801
43802
43802
43803
43804
43805
43811
43812
43814
43815
43817
43820
43821
43822
43823
43824
43835
43836
43837
43838
43839
43840
43841
43842
43843
43844
43845
43860
43862
SPECIES NAME
ETHYLENE OXIDE
PROPYLENE OXIDE
MALEIC ANHYDRIDE
ACETIC ANHYDRIDE
OXYGENATES
ACRYLONITRILE
ETHYLAMINE
TRIMETHYLAMINE
HEXAMETHYLENEDIAMINE
ETHANOLAMINE
ETHYLENEAMINES
CAPROLACTAM
DIMETHYL ALKYL AMINES
METHYL CHLORIDE
DICHLOROMETHANE
METHYLENE CHLORIDE
CHLOROFORM
CARBON TETRACHLORIDE
METHYLENE BROMIDE
TRICHLOROFLUOROMETHANE
ETHYL CHLORIDE
1,1,1-TRICHLOROETHANE
ETHYLENE DICHLORIDE
PERCHLOROETHYLENE
1,1,2-TRICHLOROETHANE
TRICHLOROTRIFLUOROETHANE
TRIMETHYLFLUOROSILANE
DICHLORODIFLUOROMETHANE
TRICHLOROETHYLENE
1-CHLOROBUTANE
3-(CHLOROMETHYL)-HEPTANE
ETHYLENE DIBROMIDE
PROPYLENE DICHLORIDE
TETRAFLUOROMETHANE
CHLORODIFLUOROMETHANE
DICHLOROTETRAFLUORETHANE
CHLOROPENTAFLUOROETHANE
HEXAFLUOROETHANE
TRIFLUOROMETHANE
CHLOROTRIFLUOROMETHANE
VINYL CHLORIDE
CHLOROPRENE
CAS NUMBER
75218
75569
108316
108247
0
107131
75057
75503
124094
141435
0
105602
0
74873
75092
75092
67663
56235
74953
75694
75003
71556
107062
127184
79005
76131
0
75718
79016
78864
0
106934
26638197
75730
75456
76142
76153
76164
75467
75729
75014
126998
D -24
-------
TABLE D-2. (Continued)
Page No.
03/30/88
8
MOLECULAR
WEIGHT
92.53
62.13
60.08
76.14
296.62
76.08
88.23
114.00
106.16
120.19
134.22
134.21
120.19
120.19
134.21
134.22
132.22
130.19
142.20
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
120.20
120.19
120.19
134.21
134.21
134.22
134.22
104.14
118.19
120.19
154.21
168.24
132.21
130.02
SAROAD
NUMBER
43863
43902
43933
43934
43950
43951
43952
45101
45102
45104
45105
45106
45107
45108
45109
45110
45111
45112
45113
45201
45202
45203
45204
45205
45206
45207
45208
45209
45210
45211
45212
45215
45216
45217
45218
45220
45221
45225
45226
45227
45228
45229
SPECIES NAME CAS NUMBER
EPICHLOROHYDRIN 106898
ETHYL MERCAPTAN 75081
CARBONYL SULFIDE 463581
CARBON SULFIDE 75150
OCTAMETHYLCYCLOTETRASILOXANE 556672
SILOXANE 0
TETRAMETHYLSILANE 75763
NAPHTHA 0
ISOMERS OF XYLENE 1330207
ISOMERS OF ETHYLTOLUENE 0
ISOMERS OF BUTYLBENZENE 0
ISOMERS OF DIETHYLBENZENE 0
TRIMETHYLBENZENE 25551137
ISOMERS OF PROPYLBENZENE 0
C3/C4/C5 ALKYLBENZENES 0
CIO AROMATIC 0
C10H12 0
ISOMERS OF C10H10 ' 0
C11H10 0
BENZENE 71432
TOLUENE 108883
ETHYLBENZENE 100414
0-XYLENE 95476
M-XYLENE 108383
P-XYLENE 106423
1,3,5-TRIMETHYLBENZENE 108678
1,2,4-TRIMETHYLBENZENE 95636
N-PROPYLBENZENE 103651
CUMENE (ISOPROPYL BENZENE) 98828
0-ETHYLTOLUENE 611143
M-ETHYLTOLUENE 620144
TERT-BUTYLBENZENE 98066
S-BUTYLBENZENE 135988
1,2 DIETHYLBENZENE 135013
M-DIETHYLBENZENE 141935
STYRENE 100425
METHYL STYRENE 25013154
1,2,3-TRIMETHYLBENZENE 526738
BIPHENYL 92524
METHYL BIPHENYL 0
ETHYL STYRENE 0
DIVINYL BENZENE 1321740
D -25
-------
Page No. 9
03/30/88
TABLE D-2. (Continued)
MOLECULAR
WEIGHT
210.32
148.25
182.27
210.32
134.21
162.28
134.22
120.19
131.20
131.20
122.21
134.22
148.24
146.25
162.27
160.26
176.30
146.23
94.11
220.36
150.22
150.22
164.25
122.16
136.19
122.16
170.00
230.00
122.13
166.14
179.22
194.19
194.19
278.35
250.30
178.23
171.22
300.53
192.00
106.13
120.16
96.09
SAROAD
NUMBER
45230
45231
45232
45233
45235
45236
45237
45238
45241
45242
45243
45244
45245
45246
45247
45248
45249
45250
45300
45301
45302
45303
45304
45310
45311
45320
45330
45401
45402
45403
45404
45450
45451
45452
45454
45455
45456
45470
45477
45501
45502
45503
SPECIES NAME CAS NUMBER
DI(ETHYLPHENYL) ETHANE 0
PENTYL BENZENE 0
DIPHENYL ETHANE 103297
ETHYL-PHENYL-PHENYL-ETHANE 0
BUTYL BENZENE 104518
DIISOPROPYL BENZENE 0
1,2,3,4 TETRAMETHYLBENZENE 488233
ETHYLTOLUENE 0
4-PHENYL-l-BUTENE 0
T-1-PHENYLBUTENE 0
ETHYLDIMETHYLBENZENE 0
TETRAMETHYLBENZENE 0
C5-ALKYLBENZENES 0
C5-ALKYLBENZENES (UNSAT.) 0
C6-ALKYLBENZENE 0
C4-ALKYLSTYRENES 0
C7-ALKYLBENZENE 0
C3-ALKYLSTYRENE 0
PHENOL 108952
NONYLPHENOL 25154523
ETHYLDIMETHYLPHENOL 0
C4-ALKYLPHENOLS 0
C5-ALKYLPHENOLS 0
C8 PHENOLS 0
C9 PHENOLS 0
DIMETHYLBENZYLALCOHOL 0
BIPHENYLOL 90437
XYLENE BASE ACIDS 0
BENZOIC ACID 65850
TEREPHTHALIC ACID 100210
DIMETHYLETHYLBENZOICACID 0
DIMETHYL TEREPHTHALATE 12061.6
DIMETHYL PHTHALATE 131113
DIBUTYL PHTHALATE 84742
DIPROPYL PHTHALATE 131168
BUTYL BENZOATE 136607
BUTYLISOPROPYLPHTHALATE 0
DI-C8 ALKYL PHTHALATE 0
BUTYLBENZYLPHTHALATE 85687
BENZALDEHYDE 100527
P-TOLUALDEHYDE 104870
2-FURFURAL 98011
D -26
-------
TABLE D-2. (Continued)
Page No.
03/30/88
10
MOLECULAR
WEIGHT
134.17
148.00
98.10
108.14
162.23
93.13
123.11
207.02
262.03
247.02
169.24
250.27
174.17
117.15
93.13
68.12
112.56
147.01
147.01
147.01
147.01
126.59
181.45
215.90
208.23
223.23
198.17
119.13
107.17
160.00
244.00
158.20
160.00
130.19
132.25
135.19
123.11
142.20
156.23
204.27
152.20
154.21
SAROAD
NUMBER
45550
45601
45604
45605
45610
45701
45702
45703
45704
45705
45706
45730
45731
45732
45740
45750
45801
45805
45806
45807
45808
45810
45830
45831
46102
46103
46111
46112
46114
46115
46202
46203
46204
46210
46601
46602
46701
46702
46703
46704
46705
46706
SPECIES NAME CAS NUMBER
METHYLACETOPHENONE 0
PHTHALIC ANHYDRIDE 85449 -
FURFURYL ALCOHOL 98000
CRESOL 1319773
C11H140 0
ANILINE 62533
NITROBENZENE 98953
2,2 DICHLORONITROANILINE 0
BROMODINITROANILINE 1817738
BROMODINITROBENZENE 0
N-PHENYLANILINE 0
METHYLENE(b)4-PHENYLISOCYANATE 101688
TOLUENE DIISOCYANATE 58849
TOLUENEISOCYANIDE 0
TOTAL AROMATIC AMINES 0
PIPERYLENE 504609
CHLOROBENZENE 108907
0-DICHLOROBENZENE 95501
M-DICHLOROBENZENE 541731
P-DICHLOROBENZENE 106467
DICHLOROBENZENES 2531226
BENZYL CHLORIDE 100447
TRICHLOROBENZENES 0
TETRACHLOROBENZENES 0
ANTHRAQUINONE 84651
AMINOANTHRAQUINONE 82451
4,4-METHYLENE DIANILINE 101779
PHENYL ISOCYANATE 103719
4-METHYLANILINE 100618
DIMETHYLNAPHTHYRIDINE 0
OCTAHYDROINDENES 0
METHOXYNAPHTHALENE 0
DIHYDROXYNAPTHALENEDIONE 0
CREOSOTE 8001589
TETRAMETHYLTHIOUREA 2782914
BENZOTHIAZOLE 95169
NAPTHALENE 91203
METHYL NAPHTHALENES 0
DIMETHYL NAPTHALENE 28804888
PHENYLNAPHTHALENES 0
ACENAPHTHYLENE 208968
ACENAPHTHENE 83329
D -27
-------
TABLE D-2. (Continued)
Page No.
03/30/88
11
MOLECULAR
WEIGHT
166.22
178.23
178.23
202.26
146.23
116.16
202.26
252.32
228.29
228.30
252.32
252.32
252.32
276.34
276.34
278.35
252.32
252.32
276.34
300.36
192.26
192.26
158.24
206.28
247.36
190.25
216.29
226.28
228.30
242.33
242.33
242.33
256.35
230.31
256.34
252.32
278.35
278.36
302.38
158.24
132.21
170.34
SAROAD
NUMBER
46707
46708
46709
46710
46711
46712
46713
46714
46715
46716
46717
46718
46719
46720
46721
46722
46723
46724
46725
46726
46727
46728
46729
46730
46731
46732
46733
46734
46735
46736
46737
46738
46739
46740
46741
46742
46743
46744
46745
46746
46747
46748
SPECIES NAME CAS NUMBER
FLUORENE 86737
PHENANTHRENE 85018
ANTHRACENE " 120127
FLUORANTHENE 206440
C2 ALKYL INDAN 0
INDENE 95136
PYRENE 129000
BENZO(g,h,i) FLUORANTHENE 0
CHRYSENE 218019
BENZO (a) ANTHRACENE 56553
BENZO (b) FLUORANTHENE 205992
BENZO (k) FLUORANTHENE 207089
BENZO (a) PYRENE 50328
INDENO(l,2,3-cd) PYRENE 193395
BENZO (g,h,i) PERYLENE 191242
DIBENZO(a,h) ANTHRACENE 53703
PERYLENE 198550
BENZO (e) PYRENE 192972
ANTHANTHRENE 191264
CORONENE 191071
METHYL-ANTHRACENES 0
METHYL-PHENANTHRENES 0
C2-ALKYL-ANTHRACENES 0
C2-ALKYL-PHENANTHRENES 0
CYCLOPENTA-ANTHRACENES 0
CYCLOPENTA-PHENANTHRENES 0
METHYL-FLUORANTHENES 0
CYCLOPENTA(c,d)PYRENE 27208373
BENZO(c)PHENANTHRENE 195197
METHYL-BENZANTHRACENES 0
METHYL-BENZPHENANTHRENES 0
METHYL-CHRYSENES 0
C2-ALKYL-BENZANTHRACENES 0
C2-ALKYL-BENZOPHENANTHRENES 0
C2-ALKYL-CHRYSENES 0
BENZOPYRENES 0
DIBENZANTHRACENES 0
DIBENZPHENANTHRENES 0
DIBENZOPYRENES 0
C2-ALKYLNAPTHALENE 0
METHYLINDANS 0
METHYLDECALINS 0
D -28
-------
TABLE D-2. (Continued)
Page No.
03/30/88
12
MOLECULAR
WEIGHT
176.21
146.00
162.19
144.00
138.25
318.89
333.92
168.32
128.25
128.26
128.26
128.26
128.26
84.16
128.26
142.29
106.16
54.09
112.21
140.22
128.26
128.26
127.25
222.47
296.60
58.12
56.10
70.13
68.12
84.16
86.17
80.14
100.20
98.18
226.45
240.46
154.30
138.25
126.24
70.14
68.12
82.15
SAROAD
NUMBER
46749
46750
46751
46752
46753
46754
46755
90001
90002
90003
90004
90005
90006
90007
90008
90009
90010
90011
90013
90014
90015
90016
90017
90019
90020
90021
90022
90023
90024
90025
90026
90027
90028
90029
90030
90031
90032
90033
90034
90035
90036
90037
SPECIES NAME
METHYLDIHYDRONAPHTHALENE
DIMETHYLINDANS
DIHYDRONAPTHALENE
DIMETHYLINDENE
DECALINS
ETHYLINDAN
TRIMETHYLINDAN
DODECENE
2,3,5-TRIMETHYLHEXANE
2,4 DIMETHYLHEPTANE
3,5 DIMETHYLHEPTANE
2,5 DIMETHYLHEPTANE
2,3 DIMETHYLHEPTANE
4-METHYL-l-PENTENE
2-METHYLOCTANE
2,4,5.TRIMETHYLHEPTANE
M-XYLENE AND P-XYLENE
METHYLALLENE
C-2-OCTENE
1-DECENE
3-METHYLOCTANE
4-METHYLOCTANE
METHYLCYCLOOCTANE
C6H1803SI3
C8H2404SI4
METHYLPROPANE
METHYLPROPENE
METHYLBUTENE
METHYLBUTADIENE
METHYLPENTENES
METHYLPENTANE
METHYLCYCLOPENTADIENE
METHYLHEXANE
METHYLHEXENES
HEXADECANE
N-HEPTADECANE
1-UNDECENE
CYCLOPENTYLCYCLOPENTANE
T-2-NONENE
N-PENTENE
PENTYNE
HEXYNE
CAS NUMBER
0
0
0
0
91178
0
0
112414
0
0
0
0
0
691372
0
0
0
0
0
8720509
0
0
0
0
0
0
0
0
0
0
0
0
0
0
544763
629787
821954
0
6434782
25377724
0
0
D -29
-------
TABLE D-2. (Continued)
Page No.
03/30/88
13
MOLECULAR
WEIGHT
112.22
96.17
100.20
94.15
84.16
146.36
110.20
114.23
96.17
142.28
156.32
170.34
136.24
136.24
136.24
136.24
.68.12
154.29
84.16
98.18
111.16
125.19
87.18
85.17
101.21
99.20
99.19
97.18
124.23
114.23
111.20
140.26
140.27
184.36
168.32
140.27
225.43
100.16
211.41
142.29
98.19
96.17
SAROAD
NUMBER
90038
90039
90040
90041
90042
90043
90044
90045
90046
90047
90048
90049
90050
90051
90052
90053
90054
90055
90056
90057
90058
90059
90060
90061
90062
90063
90064
90065
90066
90067
90068
90069
90070
90071
90072
90073
90074
90075
90076
90077
90078
90079
SPECIES NAME CAS NUMBER
CIS-1,4 DIMETHYLCYCLOHEXANE 624293
METHYLHEXADIENE 0
3,3 DIMETHYLPENTANE 562492
METHYLCYCLOHEXADIENE 4313579
T-3-HEXENE 13269528
METHYLHEXANAL 0
METHYLHEPTYNE 0
METHYLHEPTANE 0
METHYLCYCLOHEXENE 0
METHYLNONANE 0
METHYLDECANES 0
METHYLUNDECANE 0
CAMPHENE 5794036
MYRCENE 123353
B-PHELLANDRENE 0
D-LIMONENE 5989275
PENTENYNE 0
PENTYLCYCLOHEXANE 0
HEXENE 0
1-HEPTENE 592767
HEXADIENAL 142836
HEPTADIENAL 0
DIMETHYLBUTANE 0
DIMETHYLBUTENE 0
DIMETHYLPENTANE 0
DIMETHYLPENTENE 0
DIMETHYLCYCLOPENTANE 0
DIMETHYLCYCLOPENTENES 0
NONADIENE 0
DIMETHYLHEXANES 0
DIMETHYLHEXADIENE 0
DIMETHYLETHYLCYCLOHEXANE 0
DIMETHYLOCTANES 0
DIMETHYLUNDECANE 0
METHYLPROPYLCYCLOHEXANES 0
METHYLISOPROPYLCYCLOHEXANE 0
DIMETHYLDECANE 0
ETHYLOCTENE 0
DIMETHYLNONANES 0
ETHYLOCTANE 0
ETHYLPENTENE 0
ETHYLCYCLOPENTENE 0
D -30
-------
TABLE D-2. (Continued)
Page No.
03/30/88
14
MOLECULAR
WEIGHT
112.21
114.23
128.26
126.24
128.26
156.31
223.42
128.26
141.27
154.29
110.19
114.22
107.16
142.29
126.24
156.31
182.35
126.24
108.19
127.05
140.27
183.35
68.13
128.26
141.23
140.26
154.29
184.36
141.28
111.20
140.27
138.25
443.11
168.32
128.26
113.22
136.24
225.20
130.19
126.24
142.22
145.31
SAROAD
NUMBER
90080
90081
90082
90083
90084
90085
90086
90087
90089
90090
90091
90092
90093
90094
90095
90096
90097
90098
90099
90100
90101
90102
90103
90104
90105
90106
90107
90108
90109
90110
90111
90112
90113
90114
90115
90116
90117
90118
90119
90120
90121
90122
SPECIES NAME CAS NUMBER
ETHYLMETHYLCYCLOPENTANE 0
E-THYLHEXANE 0
ETHYLMETHYLHEXANE 0
ETHYLMETHYLCYCLOHEXANES 0
ETHYLHEPTANE 0
ETHYLMETHYLOCTANE 0
ETHYLBICYCLOHEPTANE 0
ETHYLDIMETHYLPENTANE 0
ETHYLDIMETHYLCYCLOHEXANE 0
ETHYLPROPYLCYCLOHEXANES 0
TETRAMETHYLCYCLOBUTENE 0
TRIMETHYLPENTANE 0
TRIMETHYLPENTADIENE 0
TRIMETHYLHEPTANES 0
TRIMETHYLHEXENE 0
TRIMETHYLOCTANES 0
TRIMETHYLDECANE 0
TETRAMETHYLCYCLOPENTANE 0
OCTATRIENE 0
NONENE 0
BUTYLCYCLOHEXANE 1678939
METHYLPROPYLNONANE 0
PENTADIENE 0
METHYLOCTANES 0
PROPENYLCYCLOHEXANE 0
METHYLNONENE 0
METHYLDECENE 0
METHYLDODECANE 0
PROPYLHEPTENES 0
DIETHYLMETHYLCYCLOHEXANES 0
ISOPROPYLMETHYLCYCLOHEXANE 0
DIMETHYLOCTYNE 0
PENTYLIDENECYCLOHEXANE 0
DIMETHYLBUTYLCYCLOHEXANE 0
TRIMETHYLHEXANES 0
ISOPROPYLCYCLOPENTANE 0
LIMONENE 5989275
OCTAHYDROPENTALENE 0
METHYLINDENE 0
PROPYLCYCLOHEXANE 0
METHYLETHYLHEPTANE 0
TETRAMETHYLHEXANE 0
D -31
-------
TABLE D-2. (Continued)
Page No.
03/30/88
15
MOLECULAR
WEIGHT
168.32
140.27
296.59
282.56
268.53
126.25
172.35
204.41
128.26
84.16
84.16
84.16
98.19
118.18
112.22
86.14
98.19
112.16
112.12
129.27
140.27
154.30
127.05
182.35
112.22
128.26
88.15
16.04
28.55
42.08
57.08
71.00
79.12
93.18
112.00
126.00
140.00
154.00
168.00
182.00
196.00
210.00
SAROAD
NUMBER
90123
90124
90125
90126
90127
90128
90129
90130
98033
98034
98035
98040
98041
98044
98054
98056
98057
98058
98059
98060
98062
98063
98082
98083
98090
98091
98106
99101
99102
99103
99104
99105
99106
99107
99108
99109
99110
99111
99112
99113
99114"
99115
SPECIES NAME
TRIMETHYLNONENE
DIMETHYLOCTENES
HENEICOSANE
EICOSANE
NONADECANE
ISOPROPYLCYCLOHEXANE
ETHYLDIMETHYLOCTANE
CARYOPHYLLENE
2,2,5-TRIMETHYLHEXANE
T-2-HEXENE
C-2-HEXENE
2-METHYL-l-PENTENE
3-HEPTENE
INDANE
2,4,4-TRIMETHYL-l-PENTENE
ISOVALERALDEHYDE
ETHYLCYCLOPENTANE
TRIMETHYLCYCLOPENTANE
DIMETHYLCYCLOHEXANE
TRIMETHYLCYCLOHEXANES
DIETHYLCYCLOHEXANE
N-PENTYLCYCLOHEXANE
ETHYLHEPTENE
TRIMETHYLDECENE
METHYLHEPTENE
DIMETHYLHEPTANES
ETHYLISOPROPYL ETHER
C-l COMPOUNDS
C-2 COMPOUNDS
C-3 COMPOUNDS
C-4 COMPOUNDS
C-5 COMPOUNDS
C-6 COMPOUNDS
C-7 COMPOUNDS
C-8 COMPOUNDS
C-9 COMPOUNDS
C-10 COMPOUNDS
C-ll COMPOUNDS
C-12 COMPOUNDS
C-13 COMPOUNDS
C-14 COMPOUNDS
C-15 COMPOUNDS
CAS NUMBER
0
0
629947
112958
0
0
0
87445
0
40504557
592438
763291
0
496117
107391
590863
1640897
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
D -32
-------
TABLE D-2. (Continued)
Page No.
03/30/88
16
MOLECULAR
WEIGHT
224.00
238.00
252.00
266.00
280.00
294.00
308.00
322.00
336.00
350.00
364.00
378.00
392.00
406.00
420.00
434.00
448.00
462.00
476.00
490.00
504.00
518.00
532.00
546.00
560.00
574.00
588.00
602.00
167.31
167.31
142.29
142.29
119.19
119.19
134.22
134.22
134.22
156.32
32.04
86.00
SAROAD
NUMBER
99116
99117
99118
99119
99120
99121
99122
99123
99124
99125
99126
99127
99128
99129
99130
99131
99132
99133
99134
99135
99136
99137
99138
99139
99140
99141
99142
99143
99908
99909
99910
99911
99912
99913
99915
99916
99917
99918
99933
99999
SPECIES NAME
C-16 COMPOUNDS
C-17 COMPOUNDS
C-18 COMPOUNDS
C-19 COMPOUNDS
C-20 COMPOUNDS
C-21 COMPOUNDS
C-22 COMPOUNDS
C-23 COMPOUNDS
C-24 COMPOUNDS
C-25 COMPOUNDS
C-26 COMPOUNDS
C-27 COMPOUNDS
C-28 COMPOUNDS
C-29 COMPOUNDS
C-30 COMPOUNDS
C-31 COMPOUNDS
C-32 COMPOUNDS
C-33 COMPOUNDS
C-34 COMPOUNDS
C-35 COMPOUNDS
C-36 COMPOUNDS
C-37- COMPOUNDS
C-38 COMPOUNDS
C-39 COMPOUNDS
C-40 COMPOUNDS
C-41 COMPOUNDS
C-42 COMPOUNDS
C-43 COMPOUNDS
2,3 DIMETHYLOCTANE
2,6 DIMETHYLOCTANE
2,4 DIMETHYLOCTANE
3,4 DIMETHYLOCTANE
l-METHYL-3-ETHYLBENZENE
l-METHYL-2-ETHYLBENZENE
ISOBUTYLBENZENE
1-METHYL-3N-PROPYLBENZENE
l-METHYL-3-ISOPROPYLBENZENE
2-METHYLDECANE
DENATURANT
UNIDENTIFIED
CAS NUMBER
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
538932
0
0
0
0
0
D - 33
-------
APPENDIX E
CHEMICAL SPECIES CLASSIFICATION
-------
APPENDIX E
CHEMICAL SPECIES CLASSIFICATION
This appendix contains two examples of chemical species classification
schemes (Tables E-l and E-2). Since there are several different schemes
used based on specific modeling needs, chemical species classification data
are not included in the profiles in the text.
E-l
-------
TABLE E-l.
HYDROCARBON SPECIES
=============================
HYDROCARBON SPECIES/CLASS ASSIGNMENTS
FOR 1980 NAPAP INVENTORY VERSION 5.2
SPECIES
SAROAD
CODE
=========
5.2
REACTIVITY
CLASS
UNIDENTIFIED HYDROCARBONS
ISOMERS OF HEXANE
ISOMERS OF HEPTANE
ISOMERS OF OCTANE
ISQMERS OF NONANE
ISOMERS OF DECANE
ISOflERS OF UNDECANE
ISOMERS OF TRIDECANE
ISOMERS OF DODECANE
ISOMERS OF TETRADECANE
ISOMERS OF PENTADECANE
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
MINERAL SPIRITS
LACTOL SPIRITS
ISOMERS OF BUTENE
ISOMERS OF PENTENE
ISOMERS OF PENTANE
TERPENES
METHANE
ETHANE
ETHYLENE
PROPANE
rROPYLENE
ACETYLENE
CYCLOPROPANE
PROFADIENE
KETHYLACETYLENE
N-BUTANE
3UTENE
ISOBUTANE
IS09UTYLENE
1.3-BUTADIENE
ETHYLACETYLENE
N-PENTANE
I50PENTANE
3-METHYL-l-BUTENE
1-PENTENE
CIS, 2-PENTENE
2-METHYL,2-BUTENE
N-HEXANE
N-HEPTANE
N-OCTANE
N-NONANE
43000
43105
43106
43107
43108
4310?
43110
43111
43112
43113
43114
43115
43116
43117
43118
43119
43120
43121
43122
43123
43201
43202
43203
43204
43205
43206
43207
43206
4320?
43212
43213
43214
43215
43218
43219
43220
43221
43223
43224
43227
43228
43231
43232
43233
43235
0?
09
09
09
0?
09
09
09
09
09
09
09
09
09
09
09
15
15
09
15
01
02
10
03
11
09
09
15
15
04
15
05
13
15
15
07
08
15
15
15
15
0?
09
09
09
E-2
-------
TABLE E-l. (Continued)
HYDROCARBON SPECIES
SPECIES
5AROAD
CODE
N-DECANE
N-UNDECANE
CYCLOPENTANE
1-HEXENE
2,4, DIMETHYL PENTANE
CYCLOHEXANE
N-DODECANE
N-TRIDECANE
N-TETRADECANE
N-PENTADECANE
HETHYLCYCLOHEXANE
METHYLCYCLOPENTANE
1-HEPTENE
1-OCTENE
3,3 DIMETHYL, l-PENTENE
N-HEXADECANE
N-HEPTADECANE
N-OCTADECANE
N-NONADECANE
N-EICOSANE
N-HENEICOSANE
N-DOCOSANE
C8 OLEFIN UNK
METHYL ALCOHOL
ETHYL ALCOHOL
N-PROPYL ALCOHOL
I30PROPYL ALCOHOL
N-BUTYL ALCOHOL
ISOBL'TYL ALCOHOL
BUTYL CELLQSOLVE
TERT-BUTYL ALCOHOL
METHYL CELLOSOLVS
CELLOSOLVE
DIACETONE ALCOHOL
ETHYL ETHER
GLYCOL ETHER
SLYCOL
PROPYLENE GLYCOL
ETHYLENE BLYCOL
TETRAHYDROFURAN
ACETIC ACID
METHYL ACETATE
ETHYL ACETATE
PROPYL ACETATE
N-BUTYL ACETATE
43238
43241
43242
43245
43247
43248
43255
43258
43259
43260
43261
43262
43264
43265
43268
43281
43282
43283
43284
43285
43286
43287
43290
43301
43302
43303
43304
43305
43306
43308
43309
43310
43311
43320
43351
43367
43368
43369
43370
43390
43404
43432
43433
43434
43435
REACTIVITY
CLASS
=rcs======
09
09
09
15
09
09
09
09
09
09
09
09
15
15
15
09
09
09
09
09
09
09
15
09
09
09
09
09
09
09
09
09
09
26
09
09
0?
09 -
09
09
28
29
29
29
29
E-3
-------
TABLE E-l. (Continued)
HYDROCARBON SPECIES
ETHYL ACRYLATE
CELLOSOLVE ACETATE
ISOPROPYL ACETATE
HETHYL AMYL ACETATE
ISOBUTYl ACETATE
DIMETHYLFORMAMIDE
ISOBUTYL ISOBUTYRATE
2-ETHOXYETHYL ACETATE
FORMALDEHYDE
ACETALDEHYDE
BUTYRALDEHYDE
ALDEHYDE
ACETONE
METHYL ETHYL KETONE
METHYL N-BUTYL KETONE
METHYL ISOBUTYL KETONE
CYCLQHEXANQNE
ETHYLENE OXIDE
PROPYLENE OXIDE
ACETONITRILE
ACRYLONITRILE
METHYLAMINE
ETHYLAKINE
TRIMETHYLAMINE
METHYL CHLORIDE
DICHLOROMETHANE
CHLOROFORM
CARBON TETRABROMIDE
TRICHLORO-FLUOROMETKANE
ETHYL CHLORIDE
1.1,DICHLOROETHANE
l,l.i.-TRICHLORGETHANE
ETHYLENE DICHLQRIDE
PERCHLOROETHYLENE
METHYLENE BROMIDE
1,1,2-TRICHLOROETHANE
TRICHLOROTRIFLUOROETHANE
TRIMETHYLFLUOROSILANE
DICHLORODIFLUOROMETHANE
TRICHLOROETHYLENE
VINYL CHLORIDE
PRIM. & SEC-ALKYL BENZENES
NAPHTHA
ISOMERS OF XYLENE
DIMETHYLETHYLBENZENE
SPECIES
SAROAD
CODE
BSSSOSS33
43436
43443
43444
43445
43446
43450
43451
43452
43502
43503
43510
43513
43551
43552
43559
43560
43561
43601
43602
43702
43704
43720
43721
43740
43801
43802
43803
43907
43811
43812
43813
43814
'43815
43817
43819 '
43820
43821
43822
. 43823
43824
43860
45100
45101
45102
45103
REACTIVITY
CLASS
15
09
09
09
09
24
09
09
21
22
24
24
25
26
26
26
26
09
09
15
i e?
4 W
09
09
09
09
09
09
09
09
09
09
09
09
1 P
09
09
09
09
09
15
15
20
09
16
20
E-4
-------
TABLE E-l. (Continued)
HYDROCARBON SPECIES
ISOMERS OF ETHYLTOLUENE
ISOMERS OF BUTYLBENZENE
ISOMERS OF DIETHYLBENZENE
ISOMERS OF TRIMETHYLBENZENE
ISOMERS OF PROPYLBENZENE
BENZENE
TOLUENE
ETHYLSENZENE
ORTHO XYLENE
1,3 DIMETHYLBENZENE
1,3,5-TRIMETHYLBENZENE
M-ETHYLTOLUENE
N-BUTYLBENZENE
TERT-BUTYLBENZENE
SEC-BUTYLBENZENE
STYRENE
A-MEWLSTYRENE
1,2,3-TRIMETHYLBENZENE
ISOMERS OF TRIMETHYLBENZENE
TETRAMETHYLBENZENE
TRIVTETRAALKYL BENZENE
PHENOLS
XYLENE BASE ACIDS
CHLOROBENZENE.
1,4 DIOXANE
SPECIES
SAROAD
CODE
45104
45105
45106
45107
45106
45201
45202
45203
45204
45205
45207
45212
45214
45215
45216
45220
45221
45225
45230
45232
45233
45300
45401
45801
46201
REACTIVITY
CLASS
=========r
20
20
20
20
20
16
17
19
18
10
20
20
20
20
20
20
20
20
20
20
20
20
29
20
09
E-5
-------
TABLE E-2. HYDROCARBON SPECIES/CLASS ASSIGNMENTS, 1980
NAPAP EMISSIONS INVENTORY VERSION 5.3
CARBON NUMBER/CLASS ASSIGNMENTS
SPECIES SPECIES I 23 4 3 6 7 3 9 10
SAROAO NAME ! ! ! ! ! ! ! ! !
42B14
43820
43813
99013
43223
45208
99016
43207
43218
46201
93104
98111
98113
98005
43243
98037
43267
43224
4*T 1 ซ
*ww li
43269
*3296 .
43276
98033
43299
43291
43280
43279
43234
99001
43274
98034
99033
43277
43271
43247
43278
98110
43399
98108
98051
43311
43432
98002
98112
43310
43229
43223
98040
43228
9E004
98076
1,1,1-TRICHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,!-DICHLOROETHEHE
1,2,3-TRIKETHYLBENZENE
1,2,4-TRIKETHYL3ENZENE
1,2-DICHLOROPROFAME
1,3,3-TRIMETHYLBENZENE
1,3-BUTADIENE 1.
1,4-DIOXANE 1.
t-CHLOROBUTANE
l-ETHOXY-2-PROPANOL
1-HEPTANOL
1-HEFTEME 1.
1-HEXENE 1. .
1-METHYLCYCLOHEXANE
1-NONENE 1.
1-F-NTENE 1.
1-UNOECENE 1.
2,2.3-TRIMETHYLFENTANE
2.2,4-TRIMETHYLPENTANE
2,2.5-TRIKETHYLHEXANE
2,2,5-TRIMETHYLFENTANE
2,2-DIMETHYLSUTANE
2,3,3-TRIMETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
2,3-DIHETHYL-l-BUTENE 1.
2,3-DIMETHYLBUTANE
2,3-DIHETHYLPENTANE
2,4,4-TRIMETHYL-l-FENT 1.
2,4,4-TRIMETHYL-2-rENT
2,4-DIMgTHYLHEXANE
2,4-DIMETHYLPENTANE
2,4-DIMETHYLPENTANE
2,3-DI-METKYLHEXANE
2-(2-BUTOXYETHOXY)-ETH
2-BUTYLETHANOL
2-3UTYLTETRAHYDROFURAN
2-CHLOROTOLUENE
2-ETHOXYETHANOL
2-ETHOXYETHYL ACETATE
2-ETHYL-1-9UTENE
2-ET'HYL-l-HEXANOL
2-METHOXYETHANOL
2-METHYL PENTANE
2-METHYL-l-BUTENE 1.
2-METHYL-l-PENTENE
2-HETHYL--2-BUTENE
2-METHYL-2-PENTE.NE
2-METHYL-3-HEXANONE
2.
*
-------
TABLE E-2. (Continued)
CAR90N NUMBER/CLASS ASSIGNMENTS
SPECIES SPECIES 1 23 436789 10
SAROAD NAME '. ' ' ','.',',',','
43273
43268
98032
98105
99021
99041
43230
43223
43211
43270
43298
43293
43293
43297
98042
45221
.9SC23
9B097
13503
43404
43331
43702
43206
43303
43704
98078
98085
99001
99013
98020
98026
45201
43402
9B024
99017
99019
98080
43213
98074
43308
43510
98033
43266
98003
43113
43116
43117
98050
98039
98086
98084
2-METHYLHEXANE
3,3 DIMETHYL 1-PENTENE 1.
3,3,5-TRIHETHYLHEXANE
3-fCHLOROMETHYD-HEPTA
3-CARENE 4.
3-HEPTENE
3-METHYL PENTANE
3-METHYL-l-BUTENE 1.
3-METHYL-l-PENTENE 1.
3-METHYL-T-2-PENTENE
3-METHYLHEPTANE
3-METHYLHEXANE
4-METHYL-T-2-PENTENE
4-METHYLHEPTANE
4-NONENE
A-METHYLSTYRENE
A-PINENE 1.
A-TERPINEOL i.
ACETALEHYOE
ACETIC ACID
ACETONE
ACETONITRILE
ACETYLENE
ACROLEIN (ACRYLIC ALDH 1.
ACRYLONITRILE 1.
ALKENE KETONE 1.
ALKYL SUSTITUTED CYCLO
ALLYL CHLORIDE 1.
ANTHRACENE
B-METHYLSTYRENE
B-PINENE 1.
BENZENE
BENZOIC ACID
BENZYL CHLORIDE
BR.ONODICHLOROMETHANE
BROMOFORtt
BUTANOIQL
BUTENE 1. .
BUTYL CELLOSOLVE
BUTYL CELLOSOLVE
BUTYRALDEHYDE
C-2-HEXENE
C-2-ฃCTENE ?
C-3-HEXENE 1.
C-7 CYCLOPARAFFINS
C-8 CYCLOPARAFFINS
C-9 CYCLOPARAFFINS
CIO AROMATICS
CIO OLEriNS t.
C2 ALKYL DECALIN .
C2 ALKYL INDAN
7.
5.
9.
8.
1. I.
3. 2.
6.
3.
4.
4. 1.
8.
7.
2. '2,
8.
3. 2.
1. 1. 1.
S.
6. 1.
1.
1. 1.
T
w
1. 1.
1. 1.
1.
1.
2.
9.5
1.
6. 1.
1. 1.
8.
1. . 5.
1.
1.
1.
1.
4.
2.
4. 1.
4. 1.
2. 1.
2. 2.
6. 2. '
4.
7.
8.
9.
3. 1.
8.
12.
4. 1.
E-7
-------
TABLE E-2. (Continued)
CARBON NUMBER/CLASS ASSIGNMENTS
SPECIES SPECIES 1 23 456789 10
SAROAO NAME 1 i 1 ! ! ! ! ! ! !
98064
43311
98068
9B065
98069
9S066
98070
98073
43512
93067
98073
98071
98093
43299
98072
98093
43294
43313
43290
99049
98038
98096
98030
43807
43804
98031
98087
98088
43443
99020
43823
i3330
43803
43827
99003
43B26
43217
43227
98019
43248
43264
43273
43242
43292
43207
98027
43320
99013
98107
43823
43802
C2 CYCLOHEXANE
C3 ALDEHYDE
C3 ALKYL CYCLOHEXANE
C: CYCLOHEXANE
C4 ALKYL CYCLOHEXANE
C4 CYCLOHEXANE
C4 SUBSTITUTED CYCLOHE
C4 SUBSTITUTED CYCLOHE
C3 ALDEHYDE
CS CYCLOHEXANE
C3 ESTER
C5 SUBSTITUTED CYCLOHE
C6 ALDEHYDE
C6 OLEFINS 1.
C6 SUBSTITUTED CYCLOHE
C7 ESTER
C7-OLEFINS 1.
C3 ALDEHYDE
C8 OLEFINS 1.
C9 AROMATICS
C9 OLEFINS 1.
CARBITQL
CARBON SULFIDE
CARBON TETRABROMIDE
CARBON TETRACHLORIDE
CARBONYL SULFIDE
CARVOflENTHOL 2.
CARVONE 2.
CELLOSOLVE ACETATE
CHLORODIBROMOHETHANE
CHLORODIFLUOROMETHANE
CHLOROFLUOROHYDROCARBO
CHLOROFORM
CHLOROPENTAFLUOROETHAN
CHLQROPRENE 2.
CHLQRQTRIFLUOROMETHANE
CIS-2-BUTENE
CIS-2-PENTENE
CRYOFLOURANE (F 114)
CYCLOHEXANE '
CYCLOHEXANONE
CYCLOHEXENE 1.
CYCLOPENTANE ?
CYCLOPENTENE 1.
CYCLOPROPANE
D-LIHONENE 1.
DIACETONE ALCOHOL
DIBENZOFURAN
DIBUTYL ETHER
OICHLORQDIFLOUROMETHAN
DICHLOROtlETHANE
8.
1.
9.
9.
.10.
10.
10.
10.
ซf
11.
7.
11.
4.
4.
12.
9.
5.
6.
6.
2. 1.
7.
*
A.
1.
6.
6.
3.
1.
6.
6.
4.
3.
3.
3.
4.
4.
2. 2.
6.
I.
I.
'
'1.
1
1.
2.
1.
~~
2.
2.
2.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
2.
1.
1.
1.
E-8
-------
TABLE E-2. (Continued)
CARBON NUMBER/CLASS ASSIGNMENTS
SPECIES
SAROAO
43828
98062
98018
43450
98039
43103
98091
98012
98017
43287
43285
99006
43202
43433
'43438
43302
43812
43331
98106
43219
43721
43203
43258
98061
98037
43203
99014
43815
43370
43601
98082
98011
43302
43368
43367
43286
43282
43232
98077
99007
43281
43231
4337T
98044
98048
98113
43214
43446
43306
43431
98047
SPECIES 1
NAI1E !
DICHLOROTETRAFLUOROETH
DIETHYLCYCLOHEXANE
DIMETHYL ETHER
DIMETHYL FORMAMIDE
DIMETHYLCYCLOHEXANE
OIHETHYLETHYLBEN2ENE
DIHETHYLHEPTANE
DIPIETHYLNAPHTHALENE
DM-2,3.DH-1H-INDENE
DOCOSANE
EICOSANE
EFICHLOROHYDRIN
ETHANE
ETHYL ACETATE
ETHYL ACRYLATE
ETHYL ALCOHOL
ETHYL CHLORIDE
ETHYL ETHER
ETHYL ISOPROPYL ETHER
ETHYLACETYLENE
ETHYLAMINE
ETHYLBENZENE
ETHYLCYCLOHEXANE
ETHYLCYCLOHEXANE
ETHYLCYCLOFENTANE
ETHYLENE
ETHYLENE DIBROMIDE
ETHYLENE DICHLORIDE
ETHYLENE GLYCOL
ETHYLENE OXIDE
ETHYLHEPTENE 1.
ETHYLNAPHTHALENE
FORMALDEHYDE
GLYCOL
GLYCOL ETHER
HENEICOSANE
HEPTADECANE
HEPTANE
HEPTANONE
HEXACHLOROCYCLOPENTADI 1.
HEXADECANE
HEXANE
HEXY^ENE GLYCOL ?
INDAN
INDENE 1.
ISOAMYL ISOBUTYRATE
ISOBUTANE
ISOBUTYL ACETATE
ISOBUTYt ALCOHOL
ISOBUTYL ISOBUTYRATE
ISOBUTYLBENZENE
.2 3 4 5 67'B 9 10
II | 1 I I i i I
I I I 1 I.I i 1 I
2.
10.
%
4*
3.
8.
2. 1.
9.
4. 1.
3. 1.
22.
20.
3.
0.4 ' 1.6
3. 1.
I. 2.
2.
ซl
2. 1.
3. 1.
4.
I. 1.
1.. 1.
8.
8.
7.
i.
2.
1.
2.
1. 1.
7.
3. 1.
1. "
2.
2.
21.
17.
7.
7.
3.
16.
6.
6. .
2. 1.
1.
9.
4.
6.
4.- '
6. 1.
3. 1.
E-9
-------
TABLE E-2. (Continued)
CARBON NUMBER/CLASS ASSIGNMENTS
SPECIES
SAROAD
43213
98036
43120
43103
43109
43106
43112
45104
43106
43103
43106
43107
43114
43122
43221
43121
43113
43111
43110
45102
43243
43444
4J304
9S043
98089
98056
43119
9B022
98045
45212
45205
99008
43201
43432
43301
43720
434iS
43361
43319
43801
43352
98090
43360
98114
43359
43209
98016
43261
43262
43272
43803
SPECIES 1
NAME i
ISOBUTYLENE
ISOBUTYRALDEHYDE
ISOHERS OF BUTENE
ISONERS OF BUTYLBENZEN
ISOHERS OF DECANE
ISOflERS OF DIETHYLBENZ
ISOHERS OF DOOECANE
ISOHERS OF ETHYLTOLUEN
ISOMERS OF HEPTANE
ISOMERS OF HEXANE
I3QME5S OF NONANE
ISOHERS OF OCTANE
ISOMERS OF PENTADECANE
ISOMERS OF PENTANE
ISOMERS OF PENTANE
ISOMERS OF PENTENE
ISOMERS OF TETRADECANE
ISOMERS OF TRIDECANE
ISOMERS OF UNDECANE
ISOMERS OF XYLENE
ISCPRENE
ISOPROPYL ACETATE
ISOPROPYL ALCOHOL
ISOPROPYLBENZENE (CUME
ISOPULEGONE 1.
ISOVALERALOEHYDE
LACTOL SPIRITS
M-CRESOL (3-N-9ENZENOL
M-DIETHYLBENZEN
R-ETHYLTOLUENE
M-XYLENE
MALEIC ANHYDRIDE 1.
METHANE
METHYL ACETATE
METHYL ALCOHOL
METHYLAMINE
METHYL AMYL ACETATE
METHYL AMYL KETONE
METHYL BROMIDE
METHYL CHLORIDE
METHYL ETHYL KETONE
METHYL HEPTENE 1.
METHYL ISOBUTYL KETONE
METHYL ISOBUTYRATE
METHYL N-BUTYL KETONE
METHYLACETYLENE
METHYLANTHRACENE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
METHYLCYCLOPENTENE 1.
METKYLENE BROMIDE
23 436789 10
II I 1 1 1 1 ( >
II I 1 1 I 1 *
1. 1. 1.
2. 2.
2.
3. 1.
10.
2. 1.
12.
1. 1.
7.
6.
9.
a.
15.
3.
5.
I. 2.
14.
13.
11.
I.
1. 1.
5.
i
2. 1.
8.
3. 1.
8.
1.
2. 1.
1. 1.
1.
ซl
0.01 0.99
3. -
1.
1.
8.
7. " '
!.
1.
4.
6.
6.
5.
6.
1.3 1.5
9. I.
7.
6.
4.
1.
E-10
-------
TABLE 1-2. (Continued)
CARBON NUMBER/CLASS ASSIGNMENTS
SPECIES
SAROAD
98010
452:4
43118
4SB01
43212
43433
43303
43238
432S5
43260
43220
98063
43303
4S209
43239
43253
43101
98046
99009
99010
43284
43235
98021
43211
45204
43283
43233
43265
98023
45807
45206
98094
43817
45300
43850
98028
43208
43204
43304
43434
45108
98109
4320S
43369
43602
98013
45216
4.3220
98116
98117
98034
SPECIES 1
NAME !
HETHYLNAPHTHALENE
HETHYLPKOPYLBENZENE
MINERAL SPIRITS
HONOCHLOROBENZENE
N-BUTANE
N-BUTYL ACETATE
N-9UTYL ALCOHOL
N-OECANE
N-DODECANE
N-PENTAOECANE
N-PENTANE
N-PENTYLCYCLOHEXANE
N-PROPYL ALCOHOL
N-PROPYLBENZENE
N-TETRADECANE
N-TRIDECANE
NAPHTHA
NAPHTHALENE
NITROBENZENE
NITROSOMORPHOLINE
NONAOECANE
NONANE
0-CRESOL (2-M-BENZENOL
0-ETHYLTOLUENE
0-XYLENE
OCTAOECANE
OCTANE
OCTENE 'l. '
P-CREEOL (4-M-BENZENOL .
P-DICHLOROBENZENE
P-XYLENE
PENTYL ALCOHOL
PERCHLOROETHYLENE
PHENOLS
PHQS6ENE (COL20)
PHTHALIC ANAHYDRIDE
PROPADIENE
PROPANE
PROPRIONALDEHYDE
PROPYL ACETATE
PROPYLBENZENE
PROPYLCYCLOHEXANONE
PROPJLENE . ; t.
PROPYLENE 6LYCOL
PROPYLENE OXIDE
PROPYlNAPHTHALENE
SEC-BUTYLBENZENE
STYRENE
SUBSTITUTED C7 ESTER (
SUBSTITUTED C9 ESTER (
T-2-HEXENE
23 436789 10
II i | 1 I i i 1
(1 i | 1 I i 1 i
3. 1.
2. 1.
6. 1.
5. 1.
4.
5. 1.
2. 1.
10.
12.
15.
r
U
u.
v
2. 1.
14.
13.
8.
2. 1.
1. 3.
3. 1.
19.
9.
1.
1. 1.
1.
18.
8.
6.
1.
. 5. 1.
1.
4. 1.
2.
1. 4. .
1.
1. 2.
1. 1.
1.5 1.5
1. 1.
4. 1.
2. 1.
9.
1.
3.
2. 1.
6. 1.
3. 1.
1. 1.
9. 1. 2.
10. - 1. 1.
2. 2.
E-ll
-------
TABLE E-2. (Continued)
CARBON NUMBER/CLASS ASSIGNMENTS
SPECIES
SAROAD
9S052
43123
98079
43309
41213
43390
45232
4S202
99018
43214
43226
45233
43S24
43811
43821
43740
4J107
98060
96058
93083
43S22
98014
43241
43000
43860
45401
SPECIES 1
NAME !
T-BUTYLBENZENE
TERPENES 1.
TERPINENE 2.
TERT-BUTYL ALCOHOL
TERT-BUTYLBENZENE
TETRAHYDROFURAN
TETfiAMETHYLBENZENE
TOLUENE
TRANS-1.2-OICHLOROETHE
TRANS-2-BUTENE
TRANS-2-PENTENE
TRI/TETRAALKYL BENZENE
TRICHLOROETHYLENE
TRICHLOROFLOUROHETHANE
TRICHLOROTRIFLOUROETHA
TRIflETHYL AfllNE
TRIMETHYLBENZENE
TRIHETHYLCYCLOHEXANE
TP.IKETHYLCYCLOPENTANE
TRIMETHYLDECENE 1.
TRIMETHYLFLUOROSILANE
TRIHETHYLNAPHTHALENE
UNOECANE
UNIDENTIFIED HYDROCARB
VINYL CHLORIDE
XYLENE BASE ACIDS
23 4367S910
: : : : : : : i :
3. 1.
a.
6.
4.
1. 1. 3.
3. 1.
2. 1.
1.
1.
2.
1. 2.
3.
1.
1.
2.
3.
I. 1.
9.
8.
11.
3.
3. 1.
11.
2. 3.
1.
1.
KIT TO CLASSES:
1 - OLZFINS
2 - PARAFFINS
3 - TOLUENE
<* - XYLENE
5 - FOR.MALDEHTDE
6 - OTHER ALDEHYDES
7 - ETHYLENE
8 - NONREACTIVES
.9 - ISOPRENE
10 - METHANE
K
The SAROAD codes listed here are different for some species from the codes
used in this document. Refer to Section 2.1 for the SAROAD codes used in
this document.
E-12
-------
APPENDIX F
DATA FILE DESCRIPTION
-------
APPENDIX F
DATA FILE DESCRIPTION
The VOC Speciation Data Base consists of five separate files. The
content of each file is as follows:
File
1. GENERAL
2. PROFILE
3. SPECIES
4. SCC
5. AREA SOURCE
Contents
Profile number
Profile name
Profile data quality
Control device
Reference(s)
Data source
Profile number
SAROAD
Weight percent
Peak ID
SAROAD code
CAS number
Molecular weight
SCC
Profile number
Quality indicator
Area source code
Profile number
Quality indicator
F-l
-------
APPENDIX G
VOC SPECIATION TEST PROGRAM
-------
APPENDIX G
VOC SPECIATION TEST PROGRAM
This appendix describes the VOC speciation testing efforts conducted as
part of the overall speciation program to develop original speciated data to
characterize high priority emission sources.
G.I SUMMARY
Source categories where the VOC impacts are the most significant were
selected for sampling: gasoline marketed, degreasing, drycleaning, autobody
repair, and graphic arts. Due to resource limitations, emphasis was placed
on area type emission sources which would not require ambient or stack
sampling. The selection of specific sites for sampling within each category
simply consisted of identifying major users/producers for each category.
Samples were collected in a number of ways. Some of the samples were
obtained from the producers through mail. In some cases, they were
purchased from retail outlets. In other cases, they were obtained directly
from the users.
Sample preparation involved development of proportions for making
composite samples representative of a given category, from individual
samples collected from each category. This was based primarily on data
gathered through literature search, review of vendor literature, and vendor
and trade association contacts. Composite samples from each category were
analyzed using two analytical procedures. These procedures were similar to
SW-846 Method 3810 "Headspace Method" and SW-846 Method 8270 "Gas
Chromatography/Mass Spectrometry for Semi-Volatile Organics." All
analytical determinations were performed using a combination of capillary
gas chromatography with quadrupole mass spectrometry.
Accurate quantitative determinations were made for compounds included
in the calibrations. In addition to these compounds, complete qualitative
analysis was performed for all samples using a computerized library search
6-1
-------
and a skilled interpreter of mass spectral data. In order to determine the
relative weight percentages of compounds in a given sample, the values
calculated accurately were integrated with the semi-quantitative values
based on the qualitative analysis described above. The total organic
content of the samples were then summed and each component was expressed as
a percentage of the whole, consistent with the current VOC species profile
format. A threshold level of 0.01 percent was used to include a compound in
a profile.
The following sections discuss source category and site selection,
sampling and analytical procedures, results, and internal quality
assurance/quality control procedures in detail.
G.2 SELECTION OF SOURCE CATEGORIES AND SAMPLING SITES
G.2.1 Source Category Selection
To determine the source categories where the new and/or improved
1 2
profiles would have significant impacts, the following were reviewed: '
1980 VOC Species Data Manual,
1980 National and Precipitation Assessment Program (NAPAP)
Emissions Inventory, and
New profiles developed from literature review.
Based on this review, the following source categories were selected for
this sampling program:
gasoline marketed,
degreasing,
drycleaning,
autobody repair, and
graphic arts-printing.
G-2
-------
Table G-l presents the Source Classification Codes (SCC's) and the
applicable National Emissions Data System (NEDS) area source codes for these
source categories. As shown in Table G-l, sampling in these categories
would result in speciation of approximately 2,232,000 tons/year of VOC
emissions; this is equivalent to about 10 percent of total national VOC
emissions. Due to time and budget limitations, emphasis was placed on area
type emission sources which would not require ambient or stack sampling.
G.2.2 Selection of Sampling Sites
To characterize the five source categories selected for sampling,
samples from major users/producers in each category were collected and the
composition of potential VOC emissions associated with these products were
characterized by laboratory methods. It was assumed that composition of the
volatile portion of a product reflects the composition of VOC emissions from
operations where the product is used.
Sample acquisition involved clearly defining each of the five source
categories in terms of the products (i.e., types of solvents) used.
Available literature was consulted to determine the major users/producers
and their market share within the five categories. The major producers were
solicited for representative samples. An alternate approach for certain
categories was to purchase some of the products at local retailers once the
products of interest have been specified.
In order to select sites for the gasoline marketed source category, the
leading five oil companies in 1984 sales were identified from the "Basic
4
Petroleum Data Book." The five oil companies and corresponding local
service stations where samples were collected included the following:
1. Chevron (Gulf)
2. Standard of Indiana (Amoco)
3. Texaco
4. Shell
5. Exxon
G-3
-------
TABLE G-l. SOURCE CATEGORIES SELECTED FOR SAMPLING'
SCC/Area
Source Code
54
78,4-01-002
79
83
80
Description
Gasoline marketed
Degreasing
Drycleaning
Autobody repair
Graphic arts-printing
National VOC
Emissions
(tons/yr)
966,000
607,000
300,000
183,000
176.000
2,232,000
% of National
VOC Emissions
4.2
2.6
1.3
0.8
0.8
9.7
Source: Reference 3.
G-4
-------
The 1984 sales data presented for Chevron Corporation reflected the
acquisition of Gulf Corporation. No local Chevron stations could be found,
so only Gulf service stations were selected for collecting samples.
Degreasing and drycleaning operations use similar solvents and the
producers of solvents used in these operations are often the same for each
industry. The main type of solvent used in both industries that is not a
pure compound is mineral spirits. Since evaporative emissions from a pure
solvent can be accurately assumed to be the compound comprising the solvent,
mineral spirits was the only solvent type which was investigated in this
study. Major producers of mineral spirits were identified through contacts
with trade associations and vendor literature review. As a result of these
contacts, one company provided a sample of their main mineral spirit product
and another company sent five of their mineral spirit products through the
mail in 4-ounce sample bottles with minimal headspace.
The main producers of automotive aftermarket paint (i.e., paint applied
after the car leaves the factory) were identified by review of vendor
literature and by talking with sales representatives. The main types of
paint used presently within the industry were identified along with their
tradenames for each main producer. Once the tradenames of the samples were
established, local paint distributors were contacted to see if they carried
the product, along with the compatible thinner. Paint distributors of
DuPont, Sherwin-Williams, and PPG (Ditzler) paints were selected. The' types
of paints and thinners selected are as follows:
DuPont - "Centari," and "Lucite"
Sherwin-Williams - "Acrylyd," "Kern Transport," and Acrylic Enamel
PPG (Ditzler) - "Ditzco"
For the graphic arts industry, the main industry subcategories
identified from Reference 5 were:
1. Rotogravure
2. Lithography
3. Letter Press
4. Flexography
G-5
-------
The main types of printed products (i.e., newspaper, magazine, etc.) made
with each of these printing processes were identified from the Printing Ink
Handbook. Local printers which use these processes were contacted and
samples were obtained by mail or arrangements were made to pick up the ink
samples.
G.3 SAMPLING AND ANALYTICAL PROCEDURES
G.3.1 Sampling Procedures
Table G-2 presents an overview of the sample collection efforts
including information on the number and type of samples collected, the
number of participating companies, and how the samples were actually
obtained.
When samples were obtained on a first hand basis by visiting sites, an
attempt was made to minimize VOC loss. The time the sample was exposed to
the open air was reduced as much as possible. Before taking gasoline
samples, approximately one gallon of gasoline was dispensed to purge the
delivery hose. This gasoline was not desirable because it was exposed to
ambient summer temperatures and may have lost the more volatile components.
Gasoline samples were collected in clean vials obtained from the Radian
laboratory. As soon as each gasoline sample was sealed and labeled, it was
placed in a plastic bag and put in an ice chest. The samples were then
transported to the 4ฐC walk-in freezer at the Radian laboratory.
One sample for the degreasing and drycleaning categories was obtained
directly from the producer. It was stored along with five other solvents
received by mail in the walk-in freezer.
Acquisition of autobody repair paint was a simple matter of purchasing
the desired paint and its compatible/recommended thinner at local paint
distributors. The paint which was in metal cans or plastic bottles, was
then transported to the walk-in freezer.
Most of the printing inks for the graphic arts category were obtained
by site visits. One lithographic ink sample was obtained by mail and taken
to the walk-in freezer. Letterpress, flexographic, and gravure ink samples
6-6
-------
TABLE G-2. VOC SAMPLE COLLECTION
ฃ75
Source Category
Gasoline Marketed
Degreasing
Drycleaning
Autobody Repair
Sample
Acquisition
Site Visit
Mail, Site Visit
Mail, Site Visit
Site Visit
Number of
Samples
14
6
5
12
Number of
Participating
Companies
5
2
2
3
Types of Samples
Leaded, Unleaded,
and Unleaded Premium
Gasoline
Mineral Spirits
Mineral Spirits
Acrylic Enamel, Acrylic
Date
7/14/87
7/16/87,
7/17/87
7/16/87,
7/17/87
7/17/87
Graphic Arts
Site Visit, Mail
Lacquer, and Alkyd
Enamel Paints and
Thinners
Flexographic,
Lithographic,
Gravure, and Letterpress
Printing Inks
7/16/87
-------
were obtained by drawing off ink samples from the actual printing processes.
An attempt was made to minimize the headspace in the sample, but this could
not be monitored carefully because only authorized personnel were allowed
near the moving machinery to extract the sample. In any case, the headspace
was small. Since inks typically contain compounds with high boiling points
(i.e., low volatility), this would have a negligible impact on the results.
The samples were sealed, labeled and stored in an ice chest until taken to
the laboratory.
G.3.2 Compositing Procedures
After all the samples for a given source category were collected, a
composite sample for each source category was developed in the laboratory.
The actual number of samples used to develop the composite sample varied
between categories. At least five samples from each category were included
in each composite.
Composite samples were developed according to the type of data
available for a given category. If product usage data were available, then
the individual samples were mixed in proportion to the usage data. For
example, if 2,000 tons/year of solvent X and 1,000 tons/year of solvent Y
were used in a source category, then the composite sample consisted of
solvent X and solvent Y combined in a two-to-one ratio. If emissions data
were available for a source category, then the composite sample was
developed in proportion to the emissions data. If usage or emissions data
were insufficient, the individual samples for a particular category were
combined in equivalent proportions.
The specific compositing procedure used for each category is described
in detail below. In each case, the composite was prepared in a walk-in
refrigerator at 4ฐC immediately prior to analysis.
G.3.2.1 Gasoline Marketed Composite. In developing the composite for
this category, 1984 sales data for the leading five oil companies was used
A
to determine the percent contribution to U.S. sales. Thirty-eight percent
of the U.S. gasoline market is characterized by this composite sample.
G-8
-------
Breakdown of company sales figures by gasoline type (i.e., leaded, unleaded,
etc.) was based on average data for 1985 and 1986. Amoco no longer carries
leaded gasoline, so the percent contribution to Amoco sales was based only
on unleaded regular and unleaded premium gasoline.
The assumptions used to develop this composite included the following:
(1) the company contributions to the market are based on 1984 sales data;
(2) sample based on Chevron and Gulf sales is represented only by Gulf
gasoline; (3) average of 1985 and 1986 nationwide production data was used
to estimate the percentage of gasoline types per company; (4) gasoline was
only sampled in the Research Triangle area (North Carolina); (5) since
samples were collected in July, this composite does not reflect winter-blend
gasolines.
The proportions in Table G-3 were used to make up 100 ml of the
composite. Of this volume, 30 ml (22.6 g) was put into a 40 ml septum-top
VOA vial and put into a freezer until analysis.
G.3.2.2 Deqreasing Composite. Data of sufficient quality were not
available which could be used to composite the mineral spirit samples. All
six mineral spirit samples were composited by volume in equal amounts as
shown in Table G-3. The final volume of the degreasing composite was
120 mL. Of this volume, 30 ml (23.1 g) was measured into a 40 ml septum
capped VOA vial and stored in a freezer until analysis.
G.3.2.3 Drvcleaninq Composite. Five of the six mineral spirit samples
were composited by volume in equal proportions since no data were available
to permit compositing by varying amounts (see Table G-3). The sixth sample
was not included because of its high volatility. Most mineral spirits used
by small independent dry cleaners have a minimum flash point of around
100ฐF. The sixth sample had a flash point of less than 20ฐF, which was not
typical of petroleum drycleaning solvents and, therefore, was not included
in the analysis.
The final volume of the drycleaning composite was 100 ml. Of this
volume, 30 ml (23.3 g) was measured into a septum capped 40 ml VOA vial and
stored in a freezer until analysis. A duplicate sample was prepared by
G-9
-------
TABLE G-3. COMPOSITE SAMPLE DEVELOPMENT
Sample Identifier
GASOLINE MARKETED
GM-0714-01
GM-0714-02
GM-0714-03
GM-0714-04
GM-0714-05
GM-0714-06
GM-0714-07
GM-0714-08
GM-0714-09
GM-0714-10
GM-0714-11
GM-0714-12
GM-0714-13
GM-0714-14
DECREASING
DD-0716-01
DD-0717-01
DD-0717-02
DD-0717-03
DD-0717-04
DD-0717-05
Sample Description
Gulf leaded
Gulf unleaded
Gulf unleaded premium
Amoco unleaded
Amoco unleaded premium
Texaco leaded
Texaco unleaded
Texaco unleaded premium
Shell leaded
Shell unleaded
Shell unleaded premium
Exxon leaded
Exxon unleaded
Exxon unl eaded premi urn
Mineral spirits
Mineral spirits
Mineral spirits
Mineral spirits
Mineral spirits
Mineral spirits
Percentage
(by Volume)
Contribution
to Composite
7
14
5
14
5
5
10
4
5
10
3
5
10
3
100
16.7
16.7
16.7
16.7
16.7
16.7
100
G-10
-------
TABLE G-3. COMPOSITE SAMPLE DEVELOPMENT (Continued)
Sample Identifier
DRYCLEANING
DD-0716-01
DD-0717-01
DD-0717-03
DD-0717-04
DD-0717-05
AUTO BODY REPAIR
ABR-0717-01
ABR-0717-02
ABR-0717-03
ABR-0717-04.
ABR-0717-05
ABR-0717-06
GRAPHIC ARTS
GA-0716-01
GA-0716-02
GA-0716-03A
GA-0716-03B
GA-0716-04
Sample Description
Mineral spirits
Mineral spirits
Mineral spirits
Mineral spirits
Mineral spirits
DuPont "Centari" acrylic enamel
DuPont "Lucite" acrylic lacquer
Sherwin-Williams acrylic enamel
Sherwin-Williams "Acrylyd" acrylic
lacquer
Sherwin-Williams "Kern Transport"
alkyd enamel
PPG/Ditzler "Ditzco" alkyd enamel
Flexographic (yellow)
Lithographic
Gravure (red)
Gravure (clear)
Letterpress (black)
Percentage
(by Volume)
Contribution
to Composite
20
20
20
20
20
100
25
23
19
17
10
6
100
12.9*
28.5*
20.3*
20.5*
17.8*
100
Based on weight.
G-ll
-------
measuring a second 30 ml volume of the composite (22.8 g) Into a 40 ml
septum capped VOA vial. The duplicate sample was also stored in a freezer
until analysis.
G.3.2.4 Autobodv Repair Composite. The composite for this category
was developed using a method similar to the one used for the gasoline
marketed category. A list of main automotive aftermarket paint producers
with their percent contribution in sales to the market was used to develop
the autobody repair composite (see Reference 8). This information was
coupled with information on main autobody paint types and their percent
contribution to the company-wide paint sales for each company to develop the
criteria for compositing. By obtaining two samples of DuPont paint, three
samples of Sherwin-Williams paint, and one sample of Ditzler paint,
42 percent of the market was characterized. The following assumptions were
made in the development of the composite: (1) paints all cost roughly the
same to remain competitive in the market, thus sales percentages were
assumed to be the same as production percentages; and (2) each company had
the same percent contribution to sales for each type of paint.
Paints were combined with the thinners/reducers according to the
instructions provided on the paint cans resulting in actual paint samples.
Approximately 1:1.25 to 1:1.5 proportions of paint and thinner were used for
each sample. Each paint sample of a certain type and company origin was
then combined according to the scheme presented in Table G-3. The total
volume of this composite was 100 ml, of which 30 ml (27.3 g) was measured
into a 40 ml VOA vial and stored in a freezer until analysis.
Samples of polyurethane and acrylic urethane paints were not considered
because of the potential problems with mixing these paints into the
composite. Paints of this type require an activator to make the paint
harden. This possibly could form lumps of reacted paint in the composite.
In addition, the reactivity of all components with other paint mixtures was
unknown.
G.3.2.5 Graphic Arts Composite. Compositing of graphic arts inks was
based on 1978 nationwide mass emissions. Since the composite was based on
mass emissions, the individual ink samples were composited by weight percent
G-12
-------
according to the proportions shown in Table G-3. Two gravure samples were
mixed in equal amounts to obtain one gravure sample. For this category,
only one company was sampled per each subcategory (flexography, gravure,
letterpress, and lithography).
The total composite amount was 101.0 g. Of this amount, 21.1 g was put
into a 40 ml septum capped VGA vial and stored in a freezer until analysis.
G.3.3 Analytical Procedures
G.3.3.1 Headspace Analysis. All of the composite samples were
subjected to analysis of the headspace of the VOA vials. The headspace of
the gasoline sample was sampled at room temperature. All of the other
composites were allowed to equilibrate in an oven at 90ฐC for one hour
before the headspace was removed for analysis.
The combination of capillary gas chromatography (DB-5 fused silica
capillary column, 30 m, 0.32 mm ID, 1.0 microns film thickness) with
quadrupole mass spectrometry was used to perform all analytical
determinations. For the headspace analyses, a coil of the column was frozen
with liquid nitrogen to allow the introduction of the gaseous materials from
the VOA vial headspace by a direct injection using a gas-tight syringe. The
optimum sample size was determined as 1 ul. The temperature program used
consisted of an initial temperature of -50ฐC for 1 minute and an increase of
6ฐC per minute up to a final temperature of 250ฐC. The analytical system
was tuned using perfluorotributyl amine (FC-43), according to the
manufacturer's specifications. An accurate three-point calibration was
performed using the Air Toxics quantitation standards and surrogates (see
Table G-4).
The calibration samples were prepared as a mixture of compounds in a
static dilution bulb from which gaseous injections were made to calibrate
the analytical system.
G.3.3.2 Semi-Volatile Analysis. A weighed quantity of the composite
was put into a carbon disulfide solution and an analysis of the organic
contents of the carbon disulfide solution was performed using GC/MS in order
G-13
-------
TABLE G-4. CALIBRATION COMPOUNDS FOR HEADSPACE ANALYSIS
Tri chlorof1uoromethane
1,1-Dichloroethene
Methylene chloride
trans-1,2-Dichloroethene
1,1-Dichloroethane
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethene
1,2-Dichloropropane
Bromodi chloromethane
trans-1,3-Dichloropropene
Toluene
cis-1,3-Dichloropropene
1,1,2-Trichloroethane
Chloromethane
Bromomethane
Tetrachloroethene
Di bromochloromethane
Chlorobenzene
Ethyl benzene
m-, p-Xylene
o-Xylene
Bromoform
1,1,2,2-Tetrachloroethane
m-Dichlorobenzene
p-Dichlorobenzene
o-Dichlorobenzene
Styrene
Acetone
2-Butanone
Heptane
Isopropylbenzene
Hexane
Vinyl chloride
Chloroethane
G-14
-------
to assess whether compounds were detected under these conditions when those
same compounds could not be observed in the headspace analysis. Since
carbon disulfide is not a polar compound, it was judged to be an optimal
agent for dissolving any polar or nonpolar compounds that may exist in a
sample. The system was calibrated for the target compounds of SW-846
Method 8270. A three-point calibration was performed for the compounds
listed in Table G-5. The sample size used for this analysis was also 1 uL.
The temperature program used consisted of an initial temperature of 35ฐC for
4 minutes and an increase of 10ฐC per minute up to 270ฐC.
G.4 RESULTS AND DISCUSSION
G.4.1 Headspace Analyses
The technique used for analysis of headspace from composite samples
equilibrated at 90ฐC for 1 hour was similar to SW-846 Method 3810 "Headspace
Method." In this study, the method was intended for identification and
quantification of volatile organic compounds with boiling points less than
-100ฐC.
For analysis of headspace samples, an accurate three-point calibration
was performed for compounds that are designated as Air Toxics Standards (see
Table G-4). In addition to accurate quantitative determination of these
compounds, a complete qualitative analysis was performed on all samples
using the combination of computerized library search techniques and a
skilled interpreter of mass spectral data. Compounds were identified and
semi-quantitative values were calculated using a response factor of one
relative to the analytical standard. By far the major components of most
samples were hydrocarbons; alkanes, alkenes, and aromatic compounds. In
most cases, a definitive identification of specific isomers could not be
made, so a class identification was made (e.g., methyl pentane).
In order to determine the relative percentages of the organic
compounds, the values which are calculated accurately for compounds included
in the calibration curve were integrated with the values calculated on the
basis of a relative response factor of one. The total organic content of
G-15
-------
TABLE G-5. CALIBRATION COMPOUNDS FOR SEMI-VOLATILE ANALYSIS
Benzyl alcohol
Bi s(2-chloroi sopropyl)ether
1,3-Dichlorobenzene
1,2-Dichlorobenzene
Hexachloroethane
2-Methylphenol
N-nitrosodimethyl amine
Phenol
Aniline
Benzoic acid
4-Chloroaniline
2,4-Dichlorophenol
2,4-Dimethyl phenol
Isophorone
Naphthalene
2-Nitrophenol
N-nitrosopiperidine
Acenaphthene
1-Chloronaphthalene
4-Chlorophenyl phenyl ether
Diethyl phthalate
Fluorene
1-Naphthylamine
2-Nitroaniline
Bis(2-chloroethyl)ether
2-Chlorophenol
1,4-Dichlorobenzene
Ethyl methane sulfonate
Methyl methane sulfonate
4-Methylphenol
N-nitroso-di-n-propylamine
2-Picoline
Acetophenone
Bis(2-chloroethoxy)methane
4-Chloro-3-methylphenol
2,6-Dichlorophenol
Hexachlorobutadiene
2-Methylnaphthalene
Nitrobenzene
N-nitroso-di-n-butylamine
1,2,4-Tri chlorobenzene
Acenaphthylene
2-Chloronaphthalene
Dibenzofuran
2,6-Dinitrotoluene
Hexachlorocyclopehtadi ene
2-Naphthylamine
3-Nitroaniline
G-16
-------
TABLE G-5. CALIBRATION COMPOUNDS FOR SEMI-VOLATILE ANALYSIS (Continued)
4-Nitroaniline
Pentachlorobenzene
2,3,4,6-Tetrachlorophenol
2,4,5-Trichlorophenol
Anthracene
di-n-Butyl phthalate
Diphenylamine
Fluoranthene
N-nitrosodiphenylamine
Pentachloronitrobenzene
Phenanthrene
Benzidine
Bis(2-ethylhexyl)phthalate
Chrysene
p-Dimethylaminoazobenzene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Dibenz(a,h)anthracene
di-n-Octyl phthalate
4-Nitrophenol
1,2,4,5-Tetrachlorobenzene
2,4,6-Trichlorophenol
4-Aminobiphenyl
4-Bromophenyl phenyl ether
4,6-Dinitro-2-methylphenol
1,2-Diphenylhydrazi ne
Hexachlorobenzene
Pentachlorophenol
Phenacetin
Pronamide
Benzo(a)anthracene
Butyl benzyl phthalate
3,3-Dichlorobenzidine
Pyrene
Benzo(k)fluoranthene
Benzo(a)pyrene
7,12-Dimethylbenz(a)anthracene
G-17
-------
the sample was then summed and the quantity of each component was expressed
as a percentage of the whole to be consistent with the current VOC species
profile format. A threshold level of 0.01 percent was used to include a
compound in a given profile. See example calculations below for a
hypothetical composite sample.
Assume for composite sample A, the following compounds were identified
and quantified:
Relative % =
Species nq (nq/total nq) 100
Benzene* 80 12.82
Toluene* 100 16.03
o-Xylene* 25 4.01
Isopropylbenzene** 62 9.94
Hexane** 50 8.01
Cyclohexane** 300 48.08
Methylundecane** 7 1.12
TOTAL ng 624 100.01
Compounds that are accurately quantified (i.e., compounds included in the
three-point calibration).
**
Compounds that are identified using computerized library search and a
skilled interpreter of mass spectral data (i.e., compounds not included
in calibration).
G.4.2 Semi-Volatile Analyses
Identification and quantification of semi-volatile organic compounds
(boiling points greater than 100ฐC) was made using procedures similar to
SW-846 Method 8270 "Gas Chromatography/Mass Spectrometry for Semi-Volatile
Organics." This method is very similar to Method 625 proposed in the
Test/Quality Assurance Project Plan. For example, the set of target
compounds used in both methods is the same. Differences between the two
methods are believed to be relatively unimportant as they relate to the
overall program objectives. In analysis of semi-volatile compounds, an
accurate three-point calibration was performed for target compounds of
Method 8270 (see Table G-5).
G-18
-------
As discussed in Section G.4.1 for headspace analyses, accurate
quantitative determination of the target compounds was performed. This was
combined with the qualitative analysis performed on all samples using a
computerized library search and a skilled interpreter of mass spectral data.
The compounds identified in this manner were quantified using a response
factor of one relative to the analytical standard. Similar to the results
observed from headspace analyses, the major components of most samples were
hydrocarbons; alkanes, alkenes, and aromatics. Since a definitive
identification of specific isomers was not possible in most cases, a class
identification was made.
The calculations used for developing the VOC profiles from the
analytical data are the same as those discussed in Section G.4.1 for the
headspace method.
G.4.3 Discussion of Results
G.4.3.1 Gasoline Marketed. Decreasing, and Drvcleaninq Categories. At
the onset of the program, it was anticipated that there would be two
relatively distinct ranges of compounds (according to their boiling points
or molecular weights). These ranges would be characterized by the two
analytical methods. Some overlap was also expected. Comparison of data,
based on headspace and semi-volatile analyses, for some composite samples,
however, showed a different trend. For the gasoline marketed, degreasing,
and drycleaning composite samples, the species identified using the two
methods fall approximately in the same range (according to molecular
weight). For example, headspace analytical results for the degreasing
composite span a range from Cg through C,.. The semi-volatile analysis for
the same composite covers a similar range from Cg through C,^- The
respective ranges for the headspace and semi-volatile analyses for the
gasoline marketed composite were C. through C,2 and Cg through C,2. For the
drycleaning composite, these ranges were C^ through Cj3 and Cg through Cjg.
In the latter case, the identification of a very small quantity of
di-n-butyl phthalate (C,g) in the sample was attributed to possible
contamination prior to sample collection. If contamination did occur, the
G-19
-------
range covered by the semi-volatile analysis for the drycleaning composite
would be Cg to C,2> which is in agreement with the ranges observed for the
other two composites discussed above.
Although there is good agreement in the ranges of compounds identified
and quantitated for the gasoline marketed, degreasing, and drycleaning
composites, it is difficult to compare the percentages for a given compound
from the two analyses for these categories. In some cases, a compound was
reported in one analysis and not reported in the other analysis. The
judgement call made by the computer and/or the analyst during analysis of
the data (i.e., where peaks do not resolve completely, where there is enough
of a valley to decide that another peak is occurring, etc.) was probably one
of the reasons why a compound is observed in one analysis and not in the
other.
In other cases, the values for the same compound were significantly
different. One of the reasons contributing to this discrepancy is probably
the use of semi-quantitative values based on a relative response factor of 1
in the VOC species profiles. In some cases, this may have resulted in a
significant bias in the relative percentages. Due to resource limitations,
it was not possible to fine tune the analytical procedures. It is believed
that some effort on method development would be necessary in order to get
better agreement between the two methods.
G.4.3.2 Autobodv Repair and Graphic Arts Categories. For the autobody
repair and graphic arts composites, a wider range of species was observed
with the semi-volatile analysis. For the autobody repair composite sample,
the ranges spanned using the headspace and semi-volatile analyses were C3
through C,, and Cg through C,g, respectively. The corresponding ranges for
the graphic arts composite sample were Cg through C,ซ and Cg through C2j.
In contrast with the ranges observed for the gasoline marketed, degreasing,
and drycleaning composites, the semi-volatile analysis results for autobody
repair and graphic arts samples covered a wider range. Several compounds
that were not found in the headspace analysis were identified including
significant quantities of phthalates.
G-20
-------
G.4.3.3 VOC Species Profiles. The headspace analytical results were
considered representative of the gasoline marketed, degreasing, and
drycleaning composite samples. The semi-volatile analytical results were
considered representative of the autobody repair and graphic arts composite
samples due to the wider range of compounds identified. Generally speaking,
the headspace method simulates real-life situations more closely than the
method used in identifying and quantifying semi-volatile compounds. In the
latter method, the species in a given sample are forced into a solution
(using carbon disulfide in this case). The solution is then analyzed.
Solubility of the species in a given sample determines the extent to which
the species can be identified and/or quantitated.
The profiles developed in this study include the following:
Profile Number Profile Name
1190 Gasoline Marketed
1191 Graphic Arts-Printing
1192 Degreasing
1193 Drycleaning
1194 Autobody Repair
G.5 INTERNAL QUALITY ASSURANCE/QUALITY CONTROL
G.5.1 Sampling Quality Control
Sampling quality control activities focused on ensuring the cleanliness
of the sampling equipment and the proper logging and documentation of each
sample to avoid loss of sample integrity. The time each sample was exposed
to the open air was reduced as much as possible.
Gasoline samples were collected in vials precleaned by Radian
personnel. Before collecting a gasoline sample, approximately one gallon of
gasoline was dispensed to purge the delivery hose of ambient temperature gas
which may have lost the more volatile compounds due to high summer
temperatures. Letterpress, flexographic, and gravure ink samples were
obtained by drawing off ink samples from the actual printing processes. The
6-21
-------
headspace in the sample vial was minimized as much as possible. The
remaining samples (degreasing, drycleaning, autobody repair, and
lithographic ink) were all purchased or obtained directly in sealed
containers.
Sample compositing procedures were based on proportions developed for
each source category as discussed in Section G.3.2. A minimum of five
samples from each category was included in each composite.
G.5.2 Analytical Quality Control
The analyses for this program were performed using accepted laboratory
procedures in accordance with the specified analytical protocols. The
following general QC procedures were incorporated into the analytical
effort, where applicable:
The Analytical Task Leader reviewed all analytical data and QC
data on a daily basis for completeness and data quality.
t A master logbook was maintained to record all pertinent sample
information.
All hardcopy raw data (i.e., chromatograms, computer printouts,
etc.) were maintained in organized files.
The following sections summarize the results of all analytical QC data.
This includes surrogate recoveries, duplicate analyses, control samples, and
blank samples.
G.5.2.1 Surrogate Compounds. Each sample analyzed was spiked with
surrogate compounds prior to analysis. The use of surrogates is essential
to monitor the efficiency of the analytical process. The compounds were
spiked into the matrix prior to initiation of any sample preparation
procedures (following sample compositing) and carried through the entire
analytical process. The QC criteria is surrogate recovery within
+50 percent. The surrogate results are presented in Tables G-6 and G-7. As
G-22
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TABLE G-6. SURROGATE RECOVERIES OF VOC SAMPLES - HEADSPACE ANALYSES
Surrogates5*
Sample Perfluorobenzene Perfluorotoluene D1Q-Ethylbenzene
Autobody Repair 91 79 74
Drycleaning Composite 90 87 84
Drycleaning Composite 90 88 87
(Duplicate)
Degreasing Composite 79 76 84
Graphic Arts Composite 90 86 97
Gasoline Composite 100 98 92
aAll values reported as percent surrogate recovery.
The QC criterion was surrogate recoveries within +50 percent.
G-23
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TABLE G-7. SURROGATE RECOVERIES OF VDC SAMPLES - CARBON DISULFIDE (SEMI-VOLATILES) ANALYSES
Surrogates '
Sample
Graphic Arts Composite
Drycleaning Composite
Drycleanlng Composite
(Duplicate)
Degreaslng Composite
Autobody Repair Composite
Gasoline Composite
Method Blank
QC Sample
en
2-Fluorophenol
98
94
90
95
87
90
107
102
> a
fO All values reported as percent surrogate
D -Phenol
6
94
79
79
78
83
82
95
95
recovery.
D -Nitrobenzene
100
77
75
77
76
75
105
101
2-Fluorob ipheny 1
101
99
97
97
96
95
105
104
2,4, 6-Trlbromophenol
89
89
97
93
102
101
91
95
D -Terphenyl
110
104
97
100
96
96
122
113
The QC criterion was surrogate recoveries within +50 percent.
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seen from the tables, all surrogate recoveries were well within the QC
criteria, averaging 87 percent for the headspace samples and 94 percent for
the carbon disulfide solutions (semi-volatiles).
G.5.2.2 Method Blank. One method blank sample was processed and
analyzed for the sample set to assess the background levels present in the
analytical system. The method blank was a reagent sample (carbon disulfide)
taken through the entire sample preparation and analytical process. It was
spiked with the same surrogate compounds and quantitation standards as the
field samples so that recoveries could be calculated. (The field sample
results were not corrected for the concentrations of compounds found in the
method blank.)
The compounds and their respective concentrations found in the method
blank were as follows:
Benzene 62.0 ng/uL
Cyclohexane 62.0 ng/uL
C16H30ฐ4 10'6 n9/uL
Cyclohexene 6.4 ng/uL
Methylene chloride 4.2 ng/uL
Unknown 1.7 ng/uL
N-phenylaniline 1.5 ng/uL
The only compounds present in significant quantities were benzene and
cyclohexane. Benzene is a common contaminant found in carbon disulfide and
it is virtually impossible to find carbon disulfide which is benzene free.
Cyclohexane is frequently added to organic solvents as a stabilizer and
cyclohexene is often added to organic solvents as an anti-oxidant. C,gH300.
and N-phenylaniline were both observed in all of the samples analyzed and
are both considered to be chromatographic artifacts from the column. The
unknown is a small quantity of compound that is an artifact of the column or
solvent, which could not be identified. It was not observed in the samples
and is considered to be insignificant in terms of quantity.
G-25
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G.5.2.3 Duplicate Analyses. The composite sample from the dry
cleaning category was analyzed in duplicate for both headspace and
semi-volatile compounds. The duplicate sample was analyzed in order to
evaluate the reproducibility of the analytical methodology for the headspace
and semi-volatiles analyses. The QC criteria for agreement of the two
results for the same compound, in terms of total micrograms, were within
+50 percent for each VOC detected.
In the case of the duplicate drycleaning headspace sample, the compounds
identified were the same, but the signal levels for the compounds in the two
samples differed by approximately 50 percent. This roughly 50 percent
difference was observed for the two results, expressed in total micrograms.
The two samples used to determine results #1 and #2 were taken from the same
composite, at approximately the same volume (22.8 grams in one case,
23.3 grams in the other). The same volume of the headspace was injected
after the vials containing the sample had been heated to 90ฐC. Scan times
are exactly the same for the same compounds. There is no explanation for
the difference in the headspace samples. The only possible explanation is
that, for some reason, substantially less material was delivered to the ion
source in one case than in the other. Since the quantitation standards were
introduced separately from a static dilution bulb, it is possible for the
standards to be consistent while the values obtained for the samples differ.
The close correspondence of the standards shows that there was nothing
inherently irreproducible in the analytical process. The better comparison
is the relative percentages (weight percents) of any two compounds which
appear to be more reproducible than the absolute values (micrograms). Since
the relative percentages are the data that will be used in the VOC species
profiles, this is an appropriate comparison.
The two results for the semi-volatiles duplicate analysis are all
within the QC criteria of +50 percent agreement between results #1 and #2
for the same compound. However, several compounds were identified in the
second analysis in quantities which were nondetectable in the first
analysis. This is not unusual since the presence of a given compound is
decided upon by the computer and/or analyst who must decide what constitutes
a peak. This type of judgement may explain why in some instances a compound
is observed in one analysis and not in the other.
6-26
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REFERENCES FOR APPENDIX G
1. Volatile Organic Compound (VOC) Species Data Manual - Second Edition,
Report No. EPA-450/4-80-015, U. S. Environmental Protection Agency,
Research Triangle Park, NC, July 1980.
2. Wagner, J. K. et al., Development of the 1980 NAPAP Emissions
Inventory, Report No. EPA-600/7-86-057a (NTIS No. PB88-132121),
Prepared for U. S. Environmental Protection Agency, Research Triangle
Park, NC, December 1986.
3. Memorandum from G. S. Shareef (Radian) to R. C. Lagemann (U. S.
Environmental Protection Agency), Entitled "Source Categories
Recommended for the VOC Speciation Testing Program," May 8, 1987.
4. Basic Petroleum Data Book - Petroleum Industry Statistics, Volume VIII,
Number 1, American Petroleum Institute, Washington, D.C., January 1987.
5. "Control of Volatile Organic Emissions from Existing Stationary
Sources - Volume VIII: Graphic Arts - Rotogravure and Flexography,"
Report No. EPA-450/2-78-033 (NTIS No. PB 292490), U. S. Environmental
Protection Agency, Research Triangle Park, NC, December 1978, page 2-8.
6. Printing Ink Handbook, Fourth Edition, Compiled by Product and
Technical Publications Committees, National Association of Printing Ink
Manufacturers, Inc., 1980, Library of Congress Catalog Card
No. 80-84722.
7. Petroleum Marketing Monthly, DOE/EIA-0380, Department of Energy and
Energy Information Administration, 1986 Issues, Table 45.
8. Automotive Body Repair News, 1985-1986 Buyers Guide, Seventh Edition,
Volume 24, Number 8,.July 1985.
G-27
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TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1. REPORT NO.
EPA-450/2-88-003a
3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
AIR EMISSIONS SPECIES MANUAL
VOLUME I. VOLATILE ORGANIC COMPOUND (VOC).
5. REPORT DATE
April 1988
J
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
Gunseli Sagun Shareef, William A. Butler,
Luis A. Bravo. Margie B. Stockton
8. PERFORMING ORGANIZATION REPORT
239-004-07
9. PERFORMING ORGANIZATION NAME AND ADDRESS
10. PROGRAM ELEMENT NO.
Radian Corporation
P. 0. Box 13000
RTP, NC 27709
11. CONTRACT/GRANT NO.
58-02-3994, WA #122
13. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
OAR/OAQPS/AQMD/NPPB/PCS (MD-15)
RTP, NC 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final 8/86 - 4/88
14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
EPA Project Officer: William B. Kuykendal and J. David Mobley
16. ABSTRACT
3 I MAI. I
The U.S. Environmental Protection Agency (EPA) has several ongoing activities
that require speciated volatile organic compounds (VOC) or particulate matter (PM)
profiles from several source categories. In 1980, EPA published the "Volatile
Organic Compound (VOC) Species Data Manual, Second Edition," EPA-450/4-80-015, which
>rovided VOC species profiles for some emission source categories. More recently,
IPA published the "Receptor Model Source Composition Library," EPA-450/4-85-002,
rthich contains PM species profiles for several source categories. As part of an
effort to update the VOC and PM profile data bases, EPA has initiated several
studies. The objective of the current study was to evaluate, revise, and update
1) the 1980 VOC Data Manual, and 2) the Source Composition Library.
The updated VOC species profile data base is contained in Volume I of this
document. The VOC profile data base includes VOC profiles from primarily three
sources: 1) the 1980 VOC Data Manual, 2) new VOC profiles developed from readily
available existing data, and 3) new VOC profiles developed from original data as
a result of the VOC speciation field sampling program. In addition to the VOC
profiles, Volume I contains profile assignments that link a profile to a source
:ategory. For categories where profile data are not available, the profile
assignments are based on engineering judgment.
7.
KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
Volatile Organic Compounds
VOC
Speciation Factors
Emission Factors
18. DISTRIBUTION STATEMENT
Unlimited
b.lDENTIFIERS/OPEN ENDED TERMS
19. SECURITY CLASS fTMs Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COSATI Field/Group
21. NO. OF PAGES
641
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION is OBSOLETE
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