oEPA UniMdSt Environment*! Protection Agency OHice of Solid Waste ana Emergency Respons« DIRECTIVE NUMBER: 9443.02(85) TITLE: Clarification of the Definition of the Charac- teristic of Ignitability for Hazardous Wastes APPROVAL DATE: 2-26-85 EFFECTIVE DATE: 2-26-85 ORIGINATING OFFICE: office of solid waste E FINAL D DRAFT LEVEL OF DRAFT DA — Signed by AA or DAA D B — Signed by Office Director D C — Review & Comment REFERENCE (other documents): OSWER OSWER OSWER VE DIRECTIVE DIRECTIVE Dl ------- PART 261 SUBPART C - CHARACTERISTICS DOC: 9443.02(85) Key Words: Regulations: Subject: Addressee: Originator: Source Doc: Date: Summary: Ignitabe Wastes, Exclusions, Aqueous Waste, Paint Filter Test, Free Liquids Clarification of the Definition of the Characteristic of Ignitability for Hazardous Wastes Kevin J. Walter, Bureau of Technical Services, Division of Environmental Enforcement, Department of Environmental Conserva- tion, State of New York, 50 Wolf Road, Albany, NY 12233-0001 John H. Skinner, Director, Office of Solid Waste #9443.02(85) 2-26-85 All aqueous wastes that are ignitable only because they contain alcohols (alcohol referring to any chemical containing the hydroxyl [-OH] functional group) are excluded from regulation. The Agency intends that the exemption of "a liquid, other than an aqueous solution containing less than 24 percent alcohol by volume" exclude potable beverages only. Because of the ambiguities in the- current ignitability definition, the Agency is developing changes to replace the alcoholic solution exclusion with a generic exclusion for those wastes which, while possessing a flash point below 60°C, do not continue to burn, or, if they do burn, release enough energy to cause a major fire. Steps are also being taken to expand the ignitability characteristic to include wastes that are physical solids. Test method 9095 should be employed until the Agency officially adopts a method for identifying "free liquids" for use in the land disposal regulations. Any material passing through the paint filter is a liquid. An "aqueous solution" is one in which water constitutes at least 50 percent by weight of the sample. The Agency has not officially approved any test methods for determining a waste's water content; however, a competent laboratory should be able to make such a determination using standard techniques. ------- 9443.02 (85) FEB 2 6 1985 Mr. Kevin J. Walter Bureau of Technical Services Division of Environmental Enforcement Department of Environmental Conservation State of New York 50 Wolf Road Albany, New York 12233-0001 Dear Mr. Walter: I an writing in response to your recent letter requesting clarification of the definition of the characteristic of irjnit- ability for hazardous waste*. Your understanding that the word* "It is a liquid, other than an aqueous solution containing less than 24 percent alcohol by volume* were intended to exclude -alcoholic beverages, such a wine, and non-liquid materials is correct. However, while the Agency's intent was that this exemption apply to potable beverages only, because the terra "alcohol" was used instead of "ethanol," all aqueous wastes which are iqnitable only because they contain alcohols (here using trve term alcohol to mean any chemical containing the hydroxyl l-OH] functional group) are excluded from regulation. While the Agency completes the process of officially adopt inn a method for identifying "free liquids," for use in the land disposal regulations, it is our Current practice to employ Method 9095 (see "Test Methods for Evaluating Solid Waste, SW-945") for such purposes. Any material passing through the paint filter is deemed to be a liquid. With respect to what constitutes an "aqueous solution," such a solution is one in which water Is the primary component. This means that water constitutes at least SO percent by weight of the sample. Although, we have not officially approved any test methods for determining a waste's water content, anv competent laboratory should be able to make such a determination using standard techniques (e.g., Karl Fisher tltratlon, C-r.). Wo share your concern over the ambiguities in the current ignitability definition and have a progran underway to correct the characteristic's shortcomings. Specifically, changes are under development to replace the alcoholic solution exclusion ------- - 2 - with a generic exclusion for those wastes which, while possessing a flash point below 60*C» neither continue to burn nor, if they do burn* release enough energy to cause a major fire. In addition, steps are being taken to expand the ignitability characteristic to include wastes which are physical solids. Both of these changes will involve proposal and promulgation of specific definitional test methods and thresholds. I hope this information clears up any questions you may have about the ignitability characteristic. If you have any further questions concerning any of the hazardous waste characteristics, please contact David Friedman, of my staff, at-. 202-382-4770. Sincerely yours, John H. skinner Director Office of Solid Waste bcc: G. A. Lucero, WH-527 A. Corson David Friedman Regional Solid Waste Branch Chiefs Hotline ------- |