EPA-600/2-76-054
March 1976                   Environmental  Protection Technology Series
  CONTROL  OF STEEL  PLANT SCARFING EMISSIONS
        USING  WET  ELECTROSTATIC  PRECIPITATORS
                                   Industrial Environmental Research Laboratory
                                        Office of Research and Development
                                       U.S. Environmental Protection Agency
                                  Research Triangle Park, North Carolina 27711

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                RESEARCH REPORTING SERIES

 Research reports of the Office of Research and Development, U.S. Environmental
 Protection Agency,  have  been grouped  into five series. These five  broad
 categories were established to facilitate further development and application of
 environmental technology. Elimination of traditional grouping was consciously
 planned to foster technology transfer and a maximum interface in related fields.
 The five series are:

     1.    Environmental Health Effects Research
     2.    Environmental Protection Technology
     3.    Ecological Research
     4.    Environmental Monitoring
     5.    Socioeconomic Environmental Studies

 This report has been  assigned  to the  ENVIRONMENTAL PROTECTION
 TECHNOLOGY series. This series describes research performed to develop and
 demonstrate instrumentation,  equipment, and methodology to repair or prevent
 environmental degradation from point and  non-point sources of pollution. This
 work provides the new  or improved technology required for the control and
 treatment of pollution sources to meet environmental quality standards.
                    EPA REVIEW NOTICE

This report has been reviewed by  the U.S.  Environmental
Protection Agency, and approved for publication.  Approval
does not signify that the contents necessarily reflect the
views and policy of the Agency, nor does mention of trade
names or commercial products constitute endorsement or
recommendation for use.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.

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                           EPA-600/2-76-054
                           March 1976
           CONTROL  OF  STEEL  PLANT

          SCARFING  EMISSIONS USING

      WET ELECTROSTATIC  PRECIPITATORS
                     by

              John Varga,  Or.

       Battelle-Columbus  Laboratories
              505 King Avenue
           Columbus,  Ohio  43201
      Contract No.  68-02-1323, Task 32
             ROAP  No.  21AQR-042
         Program  Element  No.  1AB015
  EPA Project Officer:  Robert  C. McCr1ll1s


Industrial  Environmental  Research Laboratory
  Office of Energy, Minerals,  and Industry
      Research Triangle Park,  NC  27711
                Prepared for

    U.S.  ENVIRONMENTAL  PROTECTION AGENCY
     Office  of  Research and Development
          Washington,  DC  20460

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                           SUMMARY

The purpose of scarfing slabs,  blooms, and billets is discussed as an
introduction to a discussion of the control of emissions from scarfing
machines.  Some technical design information pertaining to the design
of wet electrostatic precipitators is presented, as is the limited amount
of information available on the  characteristics of scarfing emissions.
Operating characteristics are given for several electrostatic precipi-
tators presently in operation.

This report was prepared in response to Item AM-5 of the  Protocol of
the First Working Meeting of the  US/USSR Task Force on Abatement
of Air Pollution from the Iron and Steel Industry.
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                        TABLE OF CONTENTS

                                                                  Page

I.  INTRODUCTION	      1

II.  TRENDS IN THE USE OF SURFACE CONDITIONING IN THE
  UNITED STATES IRON AND STEEL INDUSTRY	      3

III.  AIR-POLLUTION CONTROL FOR  SURFACE CONDITIONING
  OF STEEL	 .	  .      5,

IV.  CHARACTERIZATION OF EMISSIONS   	      9

V.  SCARFING MACHINE WET ELECTROSTATIC PRECIPITATOR
  DESIGN CHARACTERISTICS	    11

      Electrostatic Precipitator Parts   	    11
      Wet Electrostatic Precipitator	    14
            Wet-Dust-Collection  Fundamentals	    15
      Horizontal-Flow Wet Electrostatic Precipitator	    23
      Range of Applications	    24
            Scarfer Wet Electrostatic Precipitator Design Data   .    25

VI.  REFERENCES	    28
                          LIST OF FIGURES

Figure  1.  Two types  of rectifier circuits for an electrostatic
           precipitator	    12

Figure  2.  Typical duct-type electrostatic precipitator	    13

Figure  3.  Typical pipe-type electrostatic precipitator    ....    13


                          LIST OF TABLES
Table 1.  Air-Pollution Control Systems  on Surface-Conditioning
          Operations	     6

Table 2.  Surface Conditioning Air-Pollution Control Systems in
          the U.  S.  Iron and Steel Industry	     7
                                  v

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                          LIST OF TABLES
                              (Continued)
                                                                  Page

Table 3.  Scarfing Machine Wet Electrostatic Precipitator
          Dust Loadings	      9

Table 4.  Nomenclature for Wet-Dust-Collection Fundamentals  .     18

Table 5.  Design Characteristics  and Operating Conditions for
          Scarfing Wet Electrostatic Precipitators	     26

Table 6.  Design Operating Conditions and Test Results  for
          Scarfing Wet Electrostatic Precipitators	     27
                                  VI

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                         I.  INTRODUCTION
Scarfing is a process that is used to remove surface defects from
steel slabs, blooms, and billets before rolling into  semifinished
products.  A mixture of gaseous fuel and oxygen is  used to burn away
the defects.  The scarfing may be  selective on individual defects or it
may be over the  entire surface of the slab,  bloom,  or billet.   The
operation is usually done after the slab, bloom, or billet has been
heated to the rolling temperature,  but it may also be done on cold
steel.

There are about  122  rolling mills of various types in the iron and
steel industry of the United States,  of which about 59 have scarfing
operations for the removal of  surface defects.   Scrubbers, cyclones,
baghouses, water flumes with water sprays, and wet and dry electro-
static precipitators are used to control emissions from about 47 of
the scarfing installations.

This Protocol Report discusses the application of wet electrostatic
precipitators for the  control of emissions from scarfing operations;
it is based on available published information and additional informa-
tion supplied by iron  and  steel companies.

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       II.  TRENDS IN THE USE OF SURFACE CONDITIONING
       IN THE UNITED STATES IRON AND STEEL INDUSTRY
 Because of the specifications established by customers,  many semi-
 finished steel products must be free of surface defects.  Surface
 conditioning,  the designation for the removal of surface defects, is
 done by hand and machine chipping,  by hand and machine grinding, and
 by hand and automatic scarfing.  Until the early 1930's,  hand chipping
 was the only method used for removing surface defects.  Chipping
 machines and grinding machines were developed to make surface
 conditioning less laborious.

 Scarfing is a surface-conditioning method that uses high-purity  oxygen
 to oxidize  the surface of the steel and remove the defects.  A fuel gas,
 such as acetylene or natural gas,  is used in combination with the oxy-
 gen.  The  purpose of the fuel gas is  to ensure that the  steel is heated
 to a sufficiently high temperature, about  870 C (1600 F), so that the
 high-purity oxygen can react with the steel and remove the surface
 defects.

 In the United States iron and steel industry (excluding most mini-steel
 mills),  about  130  rolling mills of various kinds are used for  rolling
 slabs, blooms,  and billets. (1)  Automatic scarfing machines are
 installed in line with the mills to condition the surfaces of slabs and
 blooms before they enter the first stand of the mill.  Billets  are
 usually surface conditioned in the  cold state before they are reheated
 for further rolling.   However, some  steel companies  surface-condition
 slabs and blooms  after they have cooled to ambient temperatures.
 There are  57 mills,  located at various  steel plants, with automatic
 scarfing machines,  one plant using scarfing for surface conditioning
 cold billets, and four plants that use  grinding of cold slabs,  blooms,
 and billets as a means of surface conditioning. i^"-")  Scarfing is used
 more than any other method for  surface conditioning of steel. In 1935
 about 1  percent  of the steel produced in the United States was condi-
tioned by scarfing.  This increased to about 41 percent in 1968.

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          in.  AIR-POLLUTION CONTROL FOR SURFACE
                     CONDITIONING OF STEEL
The emissions generated during scarfing are primarily iron oxide
fumes.   There may be a small amount of carbon dioxide and/or car-
bon monoxide depending on the carbon content of the steel.  The higher
the carbon content of the steel, the higher will be the fume emission
rate.*35)

Wet and dry electrostatic precipitators, scrubbers,  cyclones,  bag-
houses,  and water flumes with sprays are used to control emissions
from scarfing operations.  The distribution of the different types of
air-pollution control systems in integrated and nonintegrated steel
plants is given in Table 1.  A detailed list of  the control systems is
given in Table 2. (1-32)

The distribution of surface-conditioning installations in Table 1
accounts for 44 installations.  There are three additional installations
under construction for which detailed information is not as yet avail-
able. Of the 47 mills with automatic scarfing machines, 43 have some
type of air-pollution control facilities.   The remaining four installa-
tions use grinders for  surface conditioning of the  slabs,  blooms, and
billets.

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    TABLE 1.  AIR-POLLUTION CONTROL SYSTEMS ON SURFACE-CONDITIONING OPERATIONS

Type of Mill
Integrated Plants
Slabbing
Blooming
Billet
Rail
Dry
ESP

2
1
3
1
Wet
ESP

5
4
2


Scrubber Cyclone Baghouse

6 l^a)
3 1 l
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TABLE 2.   SURFACE CONDITIONING AIR-POLLUTION CONTROL SYSTEMS IN THE U.S. IRON AND STEEL INDUSTRY
Company & Location Type of Mill
Atlantic Steel Co.
Atlanta, Ga.
Armco Steel Corp.
Houston, Texas
Kansas City, Mo.
Middletown, Ohio
Babcock & Wilcox Co.
Koppel, Pa.
Bethlehem Steel Corp.
Burns Harbor, Ind.
Johnstown, Pa.
Los Angeles, Cal.
Sparrows Point, Md.
Copperweld Corp.
Warren, Ohio
Carpenter Technology Corp.
Bridgeport, Conn.
CF & I Steel Corp.
Pueblo, Colo.
Crucible Inc.
Midland, Pa.
Ford kotor Co.
Dearborn, Mich.
Inland Steel Co.
East Chicago, Ind.
J & L Steel Corp.
Aliquippa, Pa.
Cleveland, Ohio
Pittsburgh, Pa.
Jessop Steel Co.
Owensboro, Ky.
Kaiser Steel Corp.
Fontana, Cal.
Lukens Steel Co.
Coatesville, Pa.
Phoenix Steel Corp.
Phoenixville, Pa.

Blooming
Blooming
Slabbing
Blooming
Slabbing

Blooming
Slabbing
Blooming
Billet
Blooming
Slabbing
Blooming
Blooming
Blooming
Blooming

Blooming

Slabbing

Blooming
Blooming
Slabbing
Blooming
Slabbing
Blooming
Blooming
Slabbing

Plate
(e)
Annual Capacity
tonne

435,456
589,680
1,360,000
752,976
2,358,720

453,600
3,084,480
2,195,424
884,520
612,360
2,721,600
2,639,952
480,816
181,440
563,371

1,020,600

3,628,800

1,134,000
1,632,960
2,903,040
1,918,728
2,449,440
1,647,475
145,152
2,830,464

521,640

net tons

480,000
650,000
1,500,000
830,000
2,600,000

500,000
3,400,000
2,420,000
975,000
675,000
3,000,000
2,910,000
530,000
200,000
621,000

1,125,000

4,000,000

1,250,000
1,800,000
3,200,000
2,115,000
2,700,000
1,816,000
160,000
3,120,000

575,000

Type of Control
Equipment

Baghouse
High-energy scrubber
High-energy scrubber
High-energy scrubber
High-energy scrubber

High-energy scrubber
High-energy scrubber
High-energy scrubber
Wet ESP
Baghouse
Wet ESP
Wet ESP
Wet ESP^c)
Baghouse
(c)

(c)

Water flume ft sprays

Water flume & sprays
Water flume & sprays
Water flume & sprays
Wet ESP
Wet ESP
Cyclones
Baghouse
Wet ESP


Venturi scrubber
Gas
Flow

Nm3/min ACFM References

(b)
3,996
2,834
1,304
2,834

2,550
3,117
2,834
737
(b)
4,251
708
1,417





2,692

2,550
2,267
2,834
3,542
2,834
2,834

2,324





141,000
100,000
46,000
100,000

90,000
110,000
100,000
26,000

150,000
25,000
50,000





95,000

90,000
80,000
100,000
125,000
100,000
100,000

82 , 000




2
3
3
3
3

4
5
6,7
8,9
10
10
10
11
12
12

12

13

14
14
14
15
15,16
15
17
18

19
20

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TABLE 2. (Continued)
Company & Location Type of Mill -
Republic Steel Corp.
Buffalo, N.Y.
Cleveland, Ohio
Youngstown, Ohio
Roblin Steel Co.
Dunkirk, N.Y.
Timken Co.
Canton, Ohio
United States Steel Corp.
Braddock, Pa.
Duquesne, Pa.
Fairless Hills, Pa.
Gary, Ind.


Homestead, Pa.
W-P Steel Corp.
Steubenville, Ohio
Y.S. & T Co.
East Chicago, Ind.
Campbell, Ohio
Blooming
Blooming
Slabbing
Billet
Blooming
(f)
(g)
Slabbing
Slabbing
Blooming
Slabbing
Slabbing
Billet
Rail
Bar
Bar
Slabbing
Slabbing

Slabbing
Blooming
Annual Capacity
tonne net tons
781,099 861,000
925,344 1,020,000
2,574,634 2,838,000
635,040 700,000
1,584,878 1,747,000

535,248 590,000
2,268,000 2,500,000
1,496,880 1,650,000
1,542,240 1,700,000
2,630,880 2,900,000
2,558,304 2,820,000
1,088,640 1,200,000
618,710 682,000
453,600 500,000
186,883 206,000
2,792,362 3,078,000
1,385,294 1,527,000

2,363,348 2,604,000
1,545,869 1,704,000
Type of Control
Equipment
Wet ESP
Wet ESP
Wet ESP
Wet ESP
Baghouse W)
Baghouse(d)
Baghouse
Scrubber
Wet ESP
Esp(g)
Esp(g)
ESP
ESP
ESP
ESP
ESP
Multi-cyclones^
Low-pressure scrubber

High-energy scrubber
High-energy scrubber
Gas
Flow
Nm3/min ACFM^
1,700
2,343
2,834
1,275
1,417

5,951

2,834
2,343
3,259
2,692
1,757
879
1,757
1,757
232


2,834
2,834
60,000
75,000
100,000
45,000
50,000

210,000

100,000
75,000
115,000
95,000
62,000
31,000
62,000
62,000
8,200


100,000
100,000
References
21
22
22
22
23
24
25,26
27
27
27,28
27
29
29
29
29
29
30
31
/

32
32
(a) ACFM - actual cubic feet per minute.
(b) Scarfing emissions are exhausted to a common baghouse also controlling electric-arc
melting-furnace emissions.
(c) Under construction.
(d) Conditioning of slabs, blooms, or billets is done by grinding.
(e) Ingot scarfing.
(f) Selective grinding of billets.
(g) Selective scarfing of cold billets at several scarfing stations.
(h) To be replaced by wet electrostatic precipitators .

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              IV.  CHARACTERIZATION OF EMISSIONS
 The fume generated during a scarfing operation is predominantly iron
 oxide.  No information is available pertaining to the size distribution
 of the emissions or specific chemical composition.  It has been re-
 ported that the loss in yield for scarfing billets varies from 3 to
 6 percent depending on the types of steel scarfed. (36)  However, most
 of this loss is in the form of metal splatter rather than fume.  Several
 factors that influence  the amount of metal removed include:  (1) speed
 of the semifinished product through the  machine,  (2) oxygen pressure
 at the scarfing head,  (3) temperature of the steel,  and (4) the chemi-
 cal composition of the steel. (35, 37-40)  iniet and outlet dust loadings
 for several wet electrostatic precipitator installations are given in
 Table3.<10>22)
     TABLE 3.  SCARFING MACHINE WET ELECTROSTATIC PRECIPITATOR DUST LOADINGS
Type of
Mill
Billet
Billet
Blooming
Blooming
Slabbing
Slabbing
Gas
Nm3/min
643
1,032
740
1,700
2,018
2,891
Flow

ACFM
22,
36,
26,
60,
71,
102,
700
400
100
000
200
000
Inlet
grams/Nm3
2.0-48.0
1.329-2.528
5206
0.093-0.101
0.027-0.389
0.400-2.002
Loading

grains/SCFD
0.50-3.
0.332-0.
1.3
0.023-0.
0.007-0.
0.100-0.
00
631
025
097
500


Outlet
grams/Nm3
0.
0.
0.
0.
0.
0.
028-0
009-0
015-0
003-0
017-0
026-0
.029
.057
.047
.004
.026
.056
Loading

grains/SCFD
0.0070-0.
0.0023-0.
0.0038-0.
0.0008-0.
0.0042-0.
0.0065-0.
0073
0143
0117
0009
0064
0139
Nm /min - normal cubic meters per minute.
ACFM   - actual cubic feet per minute.
SCFD    - standard (normal) cubic feet, dry.
grain,   - 1/7000 pound.

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          V.  SCARFING MACHINE WET ELECTROSTATIC
            PRECIPITATOR DESIGN  CHARACTERISTICS
 This section is concerned with design fundamentals for tube or pipe-
 type wet electrostatic precipitators and duct-type (i.e. , those that
 use plates for collection) wet electrostatic precipitators.  Dry electro-
 static precipitators are not considered.  Dry electrostatic precipita-
 tors have had severe corrosion problems and the trend is toward the
 use of wet electrostatic precipitators.  Seven dry electrostatic  pre-
 cipitators are listed in operation in Table  1.  Two of these  installa-
 tions are scheduled for replacement by wet electrostatic precipita-
 tors. (27)  This will bring the number of wet electrostatic precipitators
 in operation to 14.
ELECTROSTATIC PRECIPITATOR PARTS*

The three basic parts of any precipitator installation are:
      (1) Power supply
      (2) Collection area
      (3) Dust-removal  area.

The power  supply generally consists of a single-phase, high-voltage
transformer, appropriate  control equipment, and a bridge rectifier
circuit.   The rectifier circuit  can be either a full-wave or double half-
wave circuit, as shown in  Figure 1.

Rectifier design has progressed from the mechanical rectifier to the
high-voltage Kenotron vacuum tube,  selenium, or silicon rectifiers.
Normal  transformer  ratings are between 15 and  25-kva, 440-volt
primary and 50 to 75-kv secondary.  To limit short-circuit current
surges,  the transformer primary circuit usually contains a ballast
4 Reprinted from Iron and Steel Engineer.  Electrostatic Precipitator Primer. J. Katz. by permission
 of the Association of Iron and Steel Engineers, pp. 21-40,  May 1964.

                                    11

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                         HIGH VOLT.
                          TRANS.
BRIDGE
RECTIFIER
PRECIPITATOR
(-) PROPER
               LOW VOLTAGE
               INPUT
                       FULL-WAVE CIRCUIT SCHEMATIC
                         HIGH VOLT.
                          TRANS.
BRIDGE
RECTIFIER
 PRECIPITATOR
 -) PROPER
             LOW VOLTAGE
             INPUT
                                           GRD.    .—i
                                           RETURN -±-
                    DOUBLE HALF-WAVE CIRCUIT SCHEMATIC
           Figure 1.  Two types of rectifier circuits for an
                      electrostatic precipitator
resistance or a reactor.  Manual or automatic control is used to
regulate electrical conditions in the  precipitator dust-collection area.

The collection area consists of either ducts or pipes with high-voltage
discharge electrodes uniformly spaced and of uniform length, as
illustrated in Figures 2 and 3.  Collecting electrodes (the metal sur-
faces that collect the particles) are at ground potential and are  con-
nected directly to the frame of the precipitator.  The collecting-
surface design varies with the manufacturing company and process.
The collecting surface of ducts  may  consist of perforated or solid
metal plates up to 1.4 x 6. 0 meters  (4. 5 x 20 feet).  Normally a
precipitator has  three to four duct sections  in series.  The  duct width
may be 200 mm  (8 inches), although 250 mm (10 inches) ducts are
sometimes  employed in cleaning gases that  contain large quantities of
dust.  There can be  five or six  discharge electrodes equally spaced
                                   12

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                              • —->	-JT	jf- — —•*- Clean gas flow
The mam discharge /\r / /
electrode frame is s^\ /S
suspended by post //f //\

precipitator roof.
This maintains
electrical clearance
from grounded
collecting plates.





Usually stiffener 	 »-
baffles are present
on ends to help '
/
minimize erosion '
/







'

/
/ /
(






X
>
r/
/
?







f'

/
s .
y






/
/
/ /
*
\







/
.
/

v







/
/
/
f







/
;
/

/ x //\*

'/y/y
/\ / /\/
Y





j
/
/

V
^'
A\
S )
A/
/ &
/ L
I °
A

a

by dust. / / O/'Q / 9 0
Dirty gas flow -^ 	 -^ 	 ^ 	 '
,V 	

_ L
~
* Collecting plates are
/tied into the top shell
of the precipitator.
Spacer plates at the
bottom keep plates
properly aligned.
Plates can be rapped
separately or in
sections by a bar
connecting the ends
or bottoms.





 Figure 2.  Typical duct-type electrostatic precipitator
                     Clean Gas Flow
* \ Negative output from
_ ' power suoplv to

-r L j i ^

tied into the shell of \ /

which is at ground ~
potential. Header
provides support to /
pipes and acts as a
shield between
dirty and clean gas.


The number of pipes 	 »•
per electrical set
may vary from 50 to
100. Pipe diameters
vary between 300
and 380 mm (12 and
15 inches). Pipe
length averages 3.6
./IC.
/
x^





s*-
t
r-
T>
1




t
1
-l>
I1
1
1
x



/ 1 | insulated disc arge
X l S electrode frame.
r ~y i 1C IT) /
-\-7 4 1 ^ — ' — /
^ ISC
±y
. —





i





B*





, —
t
D
OP A
^1 '





~K
1
i!





C^T
n
i
i





i
i
i
:
^
/





r.
/
For wet precipitators,
weir rings on top of
each pipe provide
uniform water flow
over the insides of the
pipes. The header
serves as a base for
the water reservoir.

* 	 Weights or other methods
hold the discharge wires
plumb. The bottom
frame (not shown) keeps
wires properly spaced.
to 4.6 meters (12 ' 	 ' 	 1 _ J _ J _ Dirty gas flow
to 15 feet).
Figure 3.  Typical pipe-type electrostatic precipitator
                            13

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in each 1.4-meter (4. 5-foot) duct section.   These discharge electrodes
receive the high-voltage rectifier output and are suspended in parallel
from a framework that is insulated from ground by ceramic insulators.

Pipe-type  collecting units are normally used for cleaning blast-furnace
gas,  removing tar from coke-oven  gas, cleaning scarfing-machine
emissions, and in recent years have been considered for cleaning
reclamation (sinter) plant emissions.  Pipe units differ from duct units
primarily  in having only one discharge electrode for each collecting
electrode;  duct units  have several discharge electrodes in each duct.
(See Figures 2 and 3. )

Both pipe-type and duct-type wet precipitators normally use water
flowing over the collecting surfaces to flush the emissions from the
collecting  surfaces.  The practice for wet electrostatic precipitators
on scarfing operations is to  flush the  collecting surfaces periodically
after a given number of slabs, blooms,  or billets have been scarfed.
The  flushing period is influenced by the kind of semifinished product,
the type of steel,  and the amount of steel removed during the scarfing
operation.

WET ELECTROSTATIC PRECIPITATOR

The  use of wet electrostatic precipitators for control of emissions from
industrial  sources was generally restricted to rather specialized appli-
cations such as  on acid mist, coke-oven off-gas, blast furnaces, and
detarring applications.  The method of cleaning was in most cases
intermittent and of the wetted-wall type.
As a result of much more  stringent local, state,  and Federal emission
regulations, condensable materials were added to the total particulate
loading.  The removal of organic condensables, which are very difficult
to wet and  which form small droplets in the 0. 1 to 2-micron range,
requires scrubber pressure drops in the range from 1000 to ISOOkg/m^
(40 to 60 inches of water gage).  Because the  wet electrostatic pre-
cipitator is always operated at saturation temperature (100  percent
relative humidity), it will remove organic materials with a  condensa-
tion  temperature higher than or equal to the gas saturation temperature.
It will also remove solid dust particles in the submicron range and
gaseous contaminants soluble in the spraying  liquor.  Emissions are
removed with very low energy consumption  and a pressure drop
usually less than 13 kg/m^ (0. 5 inches of water gage).  The electric
power input through the high-voltage power  supplies is quite low,  from
14 to 23 kw/m3/min (0. 5 to 0. 8 kw/1, 000 actual ft3/min).

                                   14

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 The recent development of a continuously sprayed,  parallel plate,
 frame electrode and horizontal flow design has provided industry with
 a realistic alternative to high-energy scrubbers.  The theory of opera-
 tion, description of the  design, and the power consumption are  dis-
 cussed in the following  sections.

 Wet-Dust-Collection Fundamentals(55>

 The corona generation and the charging and discharging processes in
 the wet electrostatic precipitator are, in general terms, similar to what
 takes place in a conventional dry electrostatic precipitator except for
 some important differences.

 Because the gas in the wet precipitator is always saturated with water
 vapor,  the current and voltage relationship is  somewhat  different
 from that in the dry precipitator.   With increasing amounts of water
 vapor,  the spark-over voltage increases  (i. e. , the voltage at which the
 field breaks down),  but  the corona  current at a given voltage is  lower.
 When solid  particles and droplets enter the electrostatic field, they will
 cause a local distortion of the electrostatic field between the electrode
 and the collecting plate.  Some of the electric-field lines intersect the
 particles, and ions generated by the corona discharge will tend  to travel
 along lines  of maximum voltage gradient  or along the field lines; there-
 fore, some of the ions will collide  with the particles and the  charge
 gradually builds  up on the particles.

 This process continues until the charge on the particles is so high that
 it diverts the electric-field lines  away from the charged particles, pre-
 venting new ions from colliding with the dust  particles.  When this state
 has been reached, the particles are said  to be saturated with charge.
 Theory shows that the saturation charge value and charging time are
 dependent upon electric-field strength, size of the particle, the dielec-
 tric  constant of the particle,  and the  relative  position of the particle in
 the field.  This  charging process is said  to be field dependent and is the
dominant process down to a particle size  of 0. 2 j-im. For smaller
particles, the so-called diffusion charging process  is the  dominant
mechanism; this is governed by the random thermal motion of the ions
and is not limited to a saturation  charge.

As soon as the charging process of the particle starts, the resulting
 electrostatic force will pull the particle toward the  collecting plate.
This force,  together with the gravitational and the-drag forces,  and the
gas-flow distribution in the field determine the particle trajectory and
 its point of collection.

                                   15

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In a dry electrostatic precipitator, the dust buildup on the collecting
plate limits the maximum voltage at which the precipitator can operate.
For dust layers with high resistivity (greater than 2 x ICr" ohm-cm)
the voltage drop can be from 10 to 20 kv.  This condition lowers the field
strength in the space between the electrode and the dust deposit surface,
and results in a lower saturation charge, which again gives a lower
electrostatic force.  If, on the  other hand, the resistivity of the dust
layer is lower than 10? ohm-cm, the electrostatic force holding the dust
particle on the plates is low, and reentrainment can become a serious
problem during the electrode- and plate-cleaning  (rapping) cycle and also
during the steady operation,  having the overall effect of lowering the
precipitator collection efficiency.

For a continuously sprayed wet electrostatic precipitator,  the pre-
viously discussed problems are nonexistent.  The spray liquid drops
form a  film on the collecting plates which continuously washes off the
dust that is being collected.  The  resistivity of the liquid film is the
governing  factor in the dust-discharging process  and not the resistivity
of the dust layer itself.   Reentrainment problems are also nonexistent,
because the collected particles are instantaneously and continuously  re-
moved from the point of collection and are washed down as a light
slurry.  The exit loading is,  therefore,  much more stable and does not
have  the characteristic sharp increase that the dry electrostatic pre-
cipitator has during the collection-plate- and electrode-rapping cycles.

Therefore, for a wet electrostatic precipitator, the operation is not
influenced by the resistivity of  the dust layer.  The major parameters
that must be considered are the particles' dielectric constant and size.

To better  understand the effect of  low dielectric  constants  on
horizontal migration distance of the particle, a mathematical model of
the particle collection mechanism was developed.  The analysis was
based upon a field-charging process and a particle or droplet which had
to traverse the whole net field spacing (one half of the plate-to-plate
spacing).  Particles  of different sizes with dielectric constants of 2,
10, and  78 were investigated.

The unit consisted of parallel collecting plates with a separation of 2r.
The velocity profile between  the plates was  assumed to be flat (plug flow)
and turbulent drag forces were  neglected. Centered between two plates
was an electrode frame,  with electrode spacing assumed sufficiently
close to provide an approximately uniform electrostatic field near the
plate surface.  The field strength was approximately 70 percent of the
field that was to be produced by a  solid discharge-plate electrode, or
                                   16

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                           E = -0. 70 dv/dr.                         (1)

The nomenclature for the equations is given in Table 4.

The current density under no-load condition will be

                               J = i/Ac.                             (2)

The ionic space charge can be determined from the current density -
electric field  equation:

         J = N0ejUjE  (E = mean  electrostatic field  strength).         (3)

The saturation charge for a nonconductive particle is

                                 e       2
                         qs= 12— 7T£0adE.                       (4)

The relative dielectric constant, £,  for a conducting particle approaches
infinity and is equal to one for a perfect insulator.

The expression for the charge as a function of time is


                                                                   (5)
where r is a charging time constant or

                             r = 4e0/N0ejU                          (6)

The particle-size range examined is larger than 0.2 jum,  so the diffu-
sion charge can be omitted.

If we  start with a particle entering the field halfway between two plates
and without any charge, the force  balance is divided  into three different
components:

      x - axis, the direction of the electrostatic field
               (transverse to gas flow)
      y - axis, the direction of the gravitation force
               (vertically down)
      z - axis, the direction of the gas flow
               (horizontal and axial).

                                  17

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TABLE 4.   NOMENCLATURE FOR WET-DUST-COLLECTION
            FUNDAMEN TALS
       A         =      67Ta7)/m = constant
       Ac        =      Collection area
       aj        =      Particle diameter
       B         =      qsE/m = constant
       ci        =      Particle inlet loading
       co        =      Particle outlet loading
       E         =      Electrostatic field strength
       e         =      Electric charge
       F         =      Force
       g         =      Gravitational constant
       i         =      Current
       J         =      Current density
       In        =      Natural logarithm
       m        =      Particle mass
       N0        =      Number density of free ions
       V         =      Gas flow rate
       q         =      Charge
       qs        =      Saturation charge
       r         =      Net field spacing
       sx        =      Transverse distance
       sz        =      Horizontal distance
       T         =      Migration time for collection
       t         =      Time
       v         =      Voltage
       w         =      Velocity
       Wgas      =      Gas average velocity
       wx        =      Transverse particle  velocity
       wz        =      Horizontal particle velocity
       x         =      Transverse horizontal distance
       y         =      Vertical distance
       z         =      Horizontal axial distance
       e         =      Dielectric  constant
       €0        =      Permittivity of free space
       9         =      Viscosity of gas
       r\         -      Collection  efficiency
       /Ji         =      Carrier mobility  of the gas
       TT         =      3.1416
       T         =      Charging time constant
       co         =      Migration velocity parameter
                              18

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The force balance is then as follows:

                      ZFX = Fqe - Fx - Fix = 0                    (7)

                      ZFy = Fg - Frjy - Fiy = 0                    (8)

                      SFZ = F^ - Fiz = 0 .                        (9)

The electrostatic force can be expressed as

                                                                  (10)
Substituting Equations (1),  (4), and (5) in Equation (10) gives


                             £ad-eT-   •       °'49>
                                  t+
which shows the influence of the dielectric constant, the particle size,
and the field strength on the electrostatic force.

The gravitational force  is

                              Fg = mg .                            (12)

The viscous  force, assuming Stoke 's Law applies (laminar flow),  is

                             F^ = 67iad0w      ,                   (13)

and the inertia force can be expressed as

                            Fi = m dw/dt .                         (14)

If we  assume that a spherical particle with a radius a is moving in this
field, it will be charged to carry an  amount of g (coul) charges, and the
force balance in the transverse direction, after substituting Equations
(10),  (13), and (14) in Equation (7), becomes:

                   qE = 67Tad7)wx - m dwx/dt = 0 .                  (15)

Substituting Equation (5) into Equation (15) gives
                                   19

-------
                         £                  dwx
                     qs—E -67Tad0wx = m — ;                   (16)


let

                     A = 6-nai^e/mand B = qgE/m .                   (17)

Substituting this in Equation  (16) and integrating gives
           f e"At
The term  \  	dt cannot be integrated but can be approximated using
          ^/   t~r •
a series solution:
                                        oo
Then,  by using this expression in Equation (18) and integrating it once
more with the  following initial conditions

                t = 0, wx = wxo = 0 and sx = sxo = 0 ,
the travel distance sx becomes
       sx =
                      oo

          •  Fin — +  Y  [(A (t+T)]n - (AT)n)/n-njl  - r In — .
            L    T    / ;                          J        T
The migration distance is from 0 to 150 mm (0 to 6 inches),  and the
migration time,  T,  needed for the particle to be collected can then be
found for sx =  150 mm (6 inches) by a trial-and-error solution of
Equation (19).
                                  20

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In order to obtain the horizontal distance needed for the particles to be
collected, the force balance in the z direction must be considered,  i. e. ,
Equation (8).  This expression becomes

                   6-na.^O (Wtf-c,  - w7) = m dw7/dt ,                  (20)
                            gat>     *        &

where (wgas ~ wz) is the relative velocity between the particle and  the
gas.  Integrating Equation (20),  using the constants given by Equa-
tion (17) gives

                                         + wzoe~At '                (21)

where w   is the initial particle velocity along the z-axis.   The hori-
zontal travel distance becomes, then,
       = J wzdt = wgas  [t + 1   e-At - 1 ]  - I
sz=\  wzdt = weas  |t + i-   e-~L-l  |   -£WZO   e-At-l .  (22)
Then, by using the travel time calculated from Equation (17), the hori-
zontal traveling distance can be calculated as a function of particle
(droplet)  size and dielectric constant.  With two 5-jUm particles or con-
densed droplets, one with a dielectric constant of 2 (e. g. ,  a condensed
hydrocarbon droplet) and one with a dielectric constant of 78 (e. g. ,
pure  water droplet), migration across a field spacing of 150 mm
(6 inches) with an applied voltage of 50 kv and a gas velocity of
0. 9 m/sec (3 fps) will take a horizontal distance of 2. 2 m (7. 2 ft)
and 1.2 m (3.9 ft),  respectively.  Therefore, the low-dielectric particle
takes almost twice the  horizontal distance before being collected.  This
analysis points to the fact that condensable hydrocarbons (tars) and
other materials with a  low dielectric constant will be much more  dif-
ficult to collect than conductive particles, and this has been confirmed
by measurements.

When considering the removal of condensable hydrocarbons (tar mist),
it should be remembered that the dielectric constants for petroleum
distillates are quite low (i.e., around 2).  For  example, hexane (CfcHj^)
has a dielectric constant of 2 and a boiling point of 69 C (156 F), toluene
(CyHg) has a dielectric constant of 2. 15 and a boiling point of 110 C
(230 F), and naphthalene (CigHg) has a dielectric constant of 2. 54 and
a boiling point of 218 C (424 F).   Other organic liquids like  phenol form-
aldehyde resin have a dielectric constant of 6.6.  Pure  water has  a
dielectric  constant of 78.
                                  21

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The removal efficiency of the wet electrostatic precipitator on a given
gas and dust stream is a function of six basic parameters:

                       Collection Area
                       Operating  Voltage
                       Discharge Current
                       Liquid-to-Gas Ratio
                       Treatment Time
                       Local Average Velocity.


The performance is often stated by the so-called migration velocity.
The higher the migration velocity is,  the better the particulate removal
efficiency or the smaller the wet electrostatic precipitator in terms of
collection area needed to treat the gas flow.  The relationship between
migration Velocity and wet electrostatic precipitator performance is
given below.

                      u = -V/A 0. 508 In (co/Ci) .                    (23)

The efficiency of the unit is given by

                          T)= (l-c0/Ci) 100 ,                        (24)

and when substituting Equation (23),

                       T,= (l-e(-Aw/0.508Q), 100    ,               (25)

which is another expression for the  |Duetsch-Anderson Equation for
precipitator efficiency:

                                   ~ \~V~~)
                          T) = 1 — e

The migration velocity w is a performance  parameter that does not  in
reality  relate directly to the  speed at which the particles migrate to the
collecting plates.  It is a "catch-all" which also includes all operating
parameters not included in Equation (23).
                                   22

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HORIZONTAL-FLOW WET ELECTROSTATIC
PRECIPITATOR

One of the wet electrostatic precipitators can be characterized as a con-
tinuously sprayed, horizontal-flow,  parallel-plate,  and solid-discharge
electrode type.  In terms of gaseous absorption, it can be characterized
as a combination cocurrent and a cross-flow scrubber.

In the application of a wet electrostatic precipitator, it is very important
that the gas to be treated is saturated with water vapor to prevent the
water inside the wet electrostatic precipitator from evaporating, which
causes loss of washing water and dry zones on the internal members.
The saturation of the gas can be done in a spray tower or scrubber up-
stream of the wet electrostatic precipitator, or it can be done in the
inlet section of the wet electrostatic precipitator, or both.

In addition, it is also necessary to obtain a uniform velocity profile
across the wet electrostatic precipitator, and the diffusion of the flow
from the  inlet duct velocity down to the wet electrostatic precipitator
face velocity has to be performed in the inlet section.  Furthermore,
by spraying cocurrent into the inlet section, some of the coarser parti-
cles will  be removed and the  gas-absorption process will be started.
To accomplish this, sections of baffles and sprays are located  in the
inlet cone of the wet electrostatic precipitator.

After passing through the  sections of transverse baffles, the dirty gas
stream then  enters into the first electrostatic field.  Water sprays
located above the electrostatic-field sections introduce the proper
amount of water droplets to the gas stream for  washing of internal sur-
faces.   The particulates and the water droplets in the electrostatic field
pick up a charge and migrate to the collecting plates.  The collected
water droplets form a continuous down ward-flowing film over all the
collecting plates and keep them clean.   The water film and the  collected
particulates  flow down the collecting plates into the  troughs below,
which are sloped to a drain.

The transverse-baffle gas-distribution system combined with the ex-
tended electrode, located upstream and downstream  of each  field,  insures
complete gas-flow uniformity from passage to passage,  and collects
particulates  and droplets by impingement, and by electrostatic forces.
Also, the extended discharge electrode system  improves the collection
efficiency by increasing effective collection area.  At the entry of a
field, particles not captured by the transverse baffles are given an

                                 23

-------
advance charge by the forward-extended electrode before they come into
proximity of the collecting plates.  Thus charged,  the particles start
immediately to migrate toward the leading edge of the plates.   It has
been found that the downstream side of the baffles at the exit of a field
collects a considerable amount of material.  The very small charged
particles escaping the parallel-plate field are pulled into the wake of the
baffles by the slight vacuum resulting from the turbulent dissipation of
energy.  Because the particles have an electrostatic charge, some of them
will be collected on the back side of the  baffles.

All baffles systems are arranged so that a walkway runs across the front
and  the back of each of the electrostatic fields.  The discharge electrode
frames are mounted on collar-type, high-voltage support insulators.
Insulator compartments are heated and pressurized to prevent moisture
and  particulate  leakage into the insulator compartment.

In any particulate and/or gaseous  removal process where a liquid is
used,  it is important to remove the carryover  liquid drops and mists
before reaching the outlet of the equipment.  It has been found that doing
this  electrostatically is highly efficient.  Hence,  the last section is
operated dry, thereby establishing an electrostatic barrier that the
liquid droplets cannot penetrate.  The mist collects on the front side of
the baffles, and the downstream side is dry. However,  some  small
dust particles can penetrate and these will collect on the downstream
baffles.  Therefore,  this surface is  washed intermittently to prevent
buildup of particulates.

RANGE OF APPLICATIONS

During the past 2 years, many new applications have been piloted and
units have been sold and installed following successful pilot-plant work.
The  wet electrostatic precipitator can be used  for applications  on gas
streams containing relatively light dust loading of submicron particles
and/or condensed organic materials forming a submicron fume.
Ordinarily these applications would require very-high-pressure-drop
scrubbers. The energy consumption and operating costs are less than
what would be needed to operate scrubbers.  The water-treatment
requirements for the wet electrostatic precipitator are about the same as
those for scrubbers.

In some applications, where the dust resistivity is  either very  high or
very low,  the wet electrostatic  precipitator can also be applied success-
fully in competition with dry electrostatic precipitators.

                                  24

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Scarfer Wet Electrostatic Precipitator Design Data

There is no information in the published literature pertaining to the
design and operating data of scarfing machine wet electrostatic pre-
cipitators.  Table 5 presents data supplied by some steel companies
for wet electrostatic precipitators installed at their steel plants in the
United States. (22> 27>

There is no published information pertaining to the size distribution of
scarfer emissions or their chemical compositions.  This type of infor-
mation is not available from any steel companies in the United States.

Table 6 presents data on the operating design conditions and test
results for three scarfing wet electrostatic precipitators. '9)  These
data were obtained by the steel plants to verify the performance of the
precipitators.

No major operating or maintenance problems were reported during
start-up and operation of the  wet electrostatic precipitators installed
on the 762 533-mm (30 21-inch)  billet mill and the  1016-mm (40-inch)
blooming mill.  About three years after the wet electrostatic precipi-
tator was installed on the 1143 x 2286-mm (45 x 90 inch) slabbing mill,
a reduction in exhaust capacity resulted in a reduction in the ability of
the hood to capture fume at the scarfer.  It was determined that the
mist eliminator of the separator was becoming clogged and dirt buildup
was  taking place on the precipitator tubes.  Clogging of the mist
eliminator was  resolved by removing approximately two thirds of the
flex rings in the mist eliminator bed and washing down the remaining
rings and bed area.  The buildup of dirt on the precipitator tubes was
eliminated by more  frequent flushing of the modules.   Originally a
module was flushed after every ten scarfs. This was reduced to
flushing after every three scarfs. (9)

Operating and maintenance costs in  1974, for the 1016-mm (40 inch)
blooming mill and 1143 x 2286-mm (45 x 90 inch) slabbing mill,  were
reported to  be $0. 009 per tonne  ($0. 01  per net ton) or  less.  This cost
did not include the cost to operate  and maintain the exhaust fans which
were a part of the original equipment before installation of the wet
electrostatic precipitators. (9)
                                  25

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                       TABLE 5.  DESIGN CHARACTERISTICS AND OPERATING CONDITIONS FOR SCARFING WET ELECTROSTATIC PRECIPITATORS
NO
Item
Gas volume
Gas temperature
Pressure
Inlet dust loading
Outlet dust loading
Number of precipitators
Modules per precipitator
Fields per chamber
Discharge electrodes
per module
per precipitator
Collecting surfaces
per module
per precipitator
Collecting surface
type
material
diameter
length
Reactor rating
Transformer -rectifier
type
KVA
MA
dielectric
Power source
Volts
Hz
Phases
Insulator compartment
ventilation
18 -inch Billet Mill
1, 275 m3/min 45, 000 ACFM
4-66 C 40-150 F
<25 mm < 1 inch
4. 6 grams/m3 2. 0 grains/SCF
0. 02 grams/m3 0. 01 grains/SCF
1
2
1

96
192

96
192

Tube
Stainless steel
25.4 cm 10 inches
4. 6 m 15 feet


Silicon




460
60
3


Blooming Mill Slabbing Mill
2, 125 m3/min 75, 000 ACFM 2, 834 m3/min 100, 000 ACFM
4-66 C 40 -150 F 52 C 125 F
-380 mm -15 inches 12. 7 mm 6 inches
4. 6 grams/m3 2. 0 grains/SCF
0. 02 grams/m3 0. 01 grains/SCF 0. 02 grams/m3 0. 01 grains/SCF
1 1
3 4
1

96 84
288 336

96 84
288 336

Tube Tube
Stainless steel Stainless steel
25.4 cm 10 inches 25.4 cm 10 inches
4. 6 m 15 feet 4. 6 m 15 feet
42 KVA

Silicon
60 60
400 ' 1,200
Askarel

460
60
3
Forced draft, electrically heated

                   ACFM - Actual cubic feet per minute.
Grain = 1/7000 pound.
                                                                                      SCF - Standard cubic foot.

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               TABLE 6.  DESIGN OPERATING CONDITIONS AND TEST RESULTS FOR SCARFING WET ELECTROSTATIC PRECIPITATORS
Item
Design Operating Conditions
Gas volume
Gas temperature
762 x 533 mm
Billet
736 m3/min
10-66 C
(30 x 21 inch)
Mill
26, 000 ACFM
50-150 F
1016 mm (40 inch)
Blooming Mill
708 m3/min 25, 000 ACFM
52 C 125 F
1143 x 2286 mm (45 x 90 inch)
Slabbing Mill
4, 248 m3/min 150, 000 ACFM
38-66C 100 -150 F
  Moisture content
  Average gas inlet loading
  Average gas outlet loading
Test Results
  Gas volume
  Gas temperature
  Moisture content
  Average gas outlet loading
  Scarfing rate
             Saturated
3.43 grams/m3    1. 50 grains/SCFD
0. 07 grams/m3    0. 03 grains/SCFD

643 m3/min      22, 700 ACFM
24 C             75 F
            5. 5 percent
0. 016 grams/m3   0. 007 grains/SCFD
81 tonne/hr       89 net tons/hr
              5 percent
2. 98 grams/m3     1.30 grains/SCFD
0. 07 grams/m3     0. 03 grains/SCFD

739 m3/min       26,100 ACFM
46 C              115 F
            2.1 percent
           2-10 percent
0. 23 grams/m3     0.30 grains/SCFD
0. 07 grams/m3     0. 03 grains/SCFD

2, 889 m3/min     102, 000 ACFM
33 C              91 F
            4. 6 percent
0. 019 grams/m3    0. 008 grains/SCFD    0. 023 grams/m3   0. 010 grains/SCFD
152 tonne/hr       168 net tons/hr       428 tonne/hr      472 net tons/hr
ACFM - Actual cubic feet per minute.
Grain = 1/7000 pound.
SCFD - Standard cubic foot (dry).

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                          VI.  REFERENCES
  (1)  Directory of Iron and Steel Works of the United States and Canada,
      American Iron and Steel Institute,  1974, pp.  19-359.

  (2)  Brown,  D. I. , Mini and Medium Steel Plants of North America -
      A Roundup,  Iron and Steel Engineer, 52:  MM-51,  November 1975.

  (3)  Communication from B. Steiner, Armco Steel Corporation to
      J.  Varga, Jr., Battelle's Columbus Laboratories, July 7,  1975.

  (4)  Large Fan Pulls 90, 000 CFM of Air Through Scrubber at Steel
      Tube Plant,  Industrial Heating,  39:  494,498, March 1972.

  (5)  Labee, C. J. , From Sand to Steel —  The Burns Harbor Story,
      Iron and Steel Engineer, 48:  B18-B48, October 1971.

  (6)  Bethlehem Installing Hot Scarfer System, American Metal Market,
      p.  4, December 27, 1968.

 (7)  Kleinman, M. , Planning and Design of Bethlehem's Hot Scarfing
      Facility at Johnstown,  Iron and Steel Engineer, 47:  108, 110,
      April 1970.

 (8)  Communication from R. C.  McCrillis, Environmental Protection
      Agency to J. Varga,  Jr., Battelle's Columbus Laboratories,
      April 25,  1975.

 (9)  Communication from J. W.  Leming,  Jr. ,  Bethlehem Steel Cor-
      poration to R. C.  McCrillis, Environmental Protection Agency,
      June 27,  1975.

(10)  Communication from H. C.  Henschen,  Bethlehem Steel Corpora-
      tion to J.  Varga,  Jr.,  Battelle's Columbus Laboratories,
      August 8,  1975.

                                  28

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(11)  Communication from F.  Jackson, Copperweld Corporation to
      J.  Varga, Jr., Battelle's Columbus Laboratories, April 29, 1975.

(12)  Kotsch, J. A., and Labee,  C. J.,  Annual Review 1974 - Develop-
      ments in the Iron and Steel Industry,  Iron and Steel Engineer,
      52; D6,  January 1975.

(13)  Communication from H.  B.  Beech, Ford Motor Company to
      J.  Varga, Jr., Battelle's Columbus Laboratories, July 7,  1975.

(14)  Communication from J. R.  Brough, Inland Steel Company to
      J.  Varga, Jr., Battelle's Columbus Laboratories, July 8,  1975.

(15)  Communication from D.  H.  Miller,  Jones & Laughlin Steel
      Corporation to J. Varga,  Jr., Battelle's Columbus Laboratories,
      July 8, 1975.

(16)  J & L 2nd Quarter Earnings Drop 50% Below  1st Qtr. , American
      Metal Market, 82:  2, June  17,  1975.

(17)  Annual Review — Developments in the  Iron and Steel Industry
      During 1973,  Iron and Steel Engineer, 51: D7, January 1974.

(18)  Communication from J. Pounds, Kaiser Steel Corporation to
      J.  Varga, Jr., Battelle's Columbus Laboratories, July 7,  1975.

(19)  Annual Review — Developments in the  Iron and Steel Industry
      During 1974,  Iron and Steel Engineer, 52:  D10,  January 1975.

(20)  McNabb,  A. J. , Cold Ingot Scarfing Machine  - Phoenix Steel,
      Iron and Steel Engineer,  51:  60-63, November 1974.

(21)  Republic  Awards Contract for Precipitator, Iron and Steel Engi-
      neer,  52:  p.  112,  October 1975.

(22)  Communication from W.  Tucker, Republic Steel Corporation to
      J.  Varga, Jr. , Battelle's Columbus Laboratories, July 18,  1975.

(23)  Communication from C. M.  Brown,  Republic Steel Corporation to
      J.  Varga, Jr., Battelle's Columbus Laboratories, July 1,  1975.

(24)  Brown, D. I. , Mini and Medium Steel Plants  of North America —
      A Roundup, Iron and Steel Engineer,  52; MM-55,  November 1975.

                                 29

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(25)  Timken Co. Blueprints $50-Million in Projects, American Metal
      Market/Metalworking News, 81:  p.  28, April 1, 1974.

(26)  Communication from E. Leisser,  Timken Company to J. Varga,
      Jr., Battelle's Columbus Laboratories, May 2,  1975.

(27)  Communication from P. X. Masciantonio, United States Steel
      Corporation to J.  Varga, Jr., Battelle's Columbus Laboratories,
      September 16,  1975.

(28)  Ess, T.  J. , Fairless Works - United States Steel's Newest, Iron
      and Steel Engineer,  31:  F75, June 1954.

(29)  Communication from J.  G.  Munson, United  States Steel Corpora-
      tion to J. Varga, Jr., Battelle's Columbus  Laboratories, July 7,
      1975.

(30)  Double Grinder, Iron and Steel Engineer,  52: p. 115, October  1975.

(31)  Communication from W. P. McShane, Wheeling-Pittsburgh Steel
      Corporation to J.  Varga, Jr., Battelle's Columbus Laboratories,
      July 8,  1975.

(32)  Communication from T. M. Hendrickson,  Youngstown Sheet and
      Tube Company to J.  Varga, Jr.,  Battelle's  Columbus Laboratories,
      May 5,  1975.

(33)  Communication from E. J.  Lancellotti,  Union Carbide Corporation,
      Linde Division to J.  Varga, Jr.,  Battelle's  Columbus Laboratories,
      June 20, 1975.

(34)  Communication from A. L. Hodge, Union Carbide Corporation,
      Linde Division to J.  Varga, Jr.,  Battelle's  Columbus Laboratories,
      January 30, 1969.

(35)  Elliott,  A. C. , and LaFreniere, A.  J. , The Design and Operation
      of a Wet Electrostatic Precipitator to Control Billet Scarfing
      Emissions, Preprint No. 71-159, Air Pollution  Control Associa-
      tion meeting in Atlantic City,  New Jersey, 9 pp. , June 27-July 1,
      1971.
                                   30

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(36)   Glossbrenner,  A.  B., Timken Steel and Tube Division's Approach
      to Bloom and Billet Conditioning, AIME Metallurgical Society
      Conference, Vol.  13.  Bar and Applied Products, Interscience
      Publishers, New York, N. Y.  (1961).

(37)   Trilli, L. J., Hot Machine Scarfing of Semi-Finished Carbon
      Steels, AIME Metallurgical Society Conference, Flat Rolled
      Products II:  Semi-Finished and  Finished, Interscience Publish-
      ers,  New York, N. Y.,  6:  3-17,  I960.

(38)   Whittaker,  R., and Long, R.  L., Factors Affecting the Yield of
      Free-Cutting Steels at Park Gate, ISI Publication 107, The  Iron
      and Steel Institute, 47-55,  1967.

(39)   Keefe, J. M. ,  Optimization of Yield in Wide  Strip Rolling,  Part 2:
      Ingot to Pickled Coil, Optimization of Steel Product  Yield, ISI
      Publication 107, The Iron and Steel Institute, 64-72,  1967.

(40)   McLean, C. J. , Control of Defects  -  Flat Rolled Products, Blast
      Furnace and Steel Plant, 54:  231-240, March 1966.
                                 31

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                                 TECHNICAL REPORT DATA
                          (Please read Instructions on the reverse before completing)
 1. REPORT NO.
 EPA-600/2-76-054
                            2.
            3. RECIPIENT'S ACCESSION-NO.
4. TITLE AND SUBTITLE
Control of Steel Plant Scarfing Emissions Using
Wet Electrostatic Precipitators
            5. REPORT DATE
             March 1976
            6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
John Varga, Jr.
                                                       8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Battelie-Columbus Laboratories
505 King Avenue
Columbus,  Ohio  43201
                                                        10. PROGRAM ELEMENT NO.
             1AB015; ROAP 21AQR-042
            11. CONTRACT/GRANT NO.

             68-02-1323, Task 32
 12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC  27711
             13. TYPE OF REPORT AND PERIOD COVERED
             Task Final; 3-8/75	
            14. SPONSORING AGENCY CODE
             EPA-ORD
is. SUPPLEMENTARY NOTES EpA prOject officer for this report is R. C. McCrillis,  Mail
Drop 62, Ext 2557.
16. ABSTRACT
            The report discusses the purpose of scarfing slabs, blooms,  and billets,
as an introduction to a discussion of the control of emissions from steel plant
scarfing machines.  Some technical design information pertaining to wet electrostatic
precipitators is presented,  as is the limited amount of information available on the
characteristics of scarfing emissions.  Operating characteristics are given for sev-
eral electrostatic precipitators  presently in operation in scarfing applications.  The
report responds to Item AM-5-1 of the  Protocol of the First Working Meeting of the
U.S./USSR Task Force on Abatement of Air Pollution from the  Iron and Steel Industry
                              KEY WORDS AND DOCUMENT ANALYSIS
                 DESCRIPTORS
                                           b.lDENTIFIERS/OPEN ENDED TERMS
                         c. COSATl Field/Group
Air Pollution
Iron and Steel Industry
Scarfing
Electrostatic Precipitators
Air Pollution Control
Stationary Sources
13B
1106, 0503
13H
09C
 3. DISTRIBUTION STATEMENT

 Unlimited
19. SECURITY CLASS (Tins Report)
Unclassified
                                                                    21.
    . OF PAGES

    39
?0. SECURITY CLASS /This naar
Unclassiiied
                         2?. PRICE
EPA Form 2220-1
                                             33

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