Development of the Westvaco Activated Carbon Process for SOx Recovery as Elemental Sulfur: Volume II

EPA-600/2-76-135b
May 1976
Environmental Protection Technology Series
                 DEVELOPMENT OF THE WESTVACO
                 ACTIVATED  CARBON  PROCESS  FOR
           SOX  RECOVERY AS ELEMENTAL SULFUR
                              Volume I - Appendix
                               Industrial Environmental Research Laboratory
                                    Office of Research and Development
                                   U.S. Environmental Protection Agency
                              Research Triangle Park, North Carolina 27711

-------
               RESEARCH REPORTING SERIES

Research reports of the Office of Research and Development, U.S. Environmental
Protection  Agency, have been grouped into five series. These five broad
categories were established to facilitate further development and application of
environmental technology. Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The five series are:

     1.    Environmental Health Effects Research
     2.    Environmental Protection Technology
     3.    Ecological Research
     4.    Environmental Monitoring
     5.    Socioeconomic Environmental Studies

This report has been  assigned  to the ENVIRONMENTAL  PROTECTION
TECHNOLOGY series. This series describes research performed to develop and
demonstrate instrumentation, equipment, and methodology to repair or prevent
environmental degradation from point and non-point sources of pollution. This
work provides the new  or  improved technology required for the control and
treatment of pollution sources to meet environmental quality standards.
                    EPA REVIEW NOTICE

This report has been reviewed by  the U.S.  Environmental
Protection Agency, and approved for publication.  Approval
does not signify that the contents necessarily reflect the
views and policy of the Agency, nor does mention of trade
names or commercial products constitute endorsement or
recommendation for use.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.

-------
                                         EPA-600/2-76-135b

                                         May 1976


      DEVELOPMENT OF THE WESTVACO

         ACTIVATED  CARBON PROCESS

FOR  SOX RECOVERY AS ELEMENTAL SULFUR

              VOLUME  II--APPENDIX
                          by

     G. Nelson Brown, Carl M. Reed, Albert J. Repik,
       Robert L. Stallings,  and Samuel L. Torrence

                       Westvaco
                       Box 5207
         North Charleston,  South Carolina 29406
                Contract No. 68-02-0003
                 ROAPNo. 21ACX-085
              Program Element No. 1AB013


        EPA Project Officer: Douglas A. Kemnitz

       Industrial Environmental Research Laboratory
         Office of Energy,  Minerals, and Industry
           Research Triangle Park, NC  27711


                     Prepared for

      U.S. ENVIRONMENTAL PROTECTION AGENCY
           Office of Research and Development
                 Washington, DC 20460

-------
                       TABLE OF CONTENTS
Section                                                     Page
 A        DETAILED RAW DATA AND DATA ANALYSIS                 1
 A-l         Experimental Results of Gravimetric Flow         2
               Experiments
 A-2         Computer Calculations - Sorption Rate Data      26
               and Models
 A-3         Comparison of Westvaco Model to Experimental    52
               Sorption Data
 A-4         S02 Sorption Rate Studies in 1" Diameter        79
               Fixed Bed
 A-5         SO? Sorption Studies in 6" Diameter Fluid       83
               Adsorber
 A-6         Multiple Regression Analyses                    95
 A-7         Comparison of Multiple Regressions to           99
               Differential Rate Data
 A-8         Comparison of Multiple Regressions to 6"       120
               Diameter Fluidized Bed Runs
 A-9         S02 Sorber Design - Effects on Size            142
 A-10        Reaction Rate Studies for Sulfur Generation    224
               in 1" Diameter Fixed Bed
 A-ll        Sulfur Generation Experimental Data            238
 A-12        Detailed Results of Integral Runs              247
 A-13        Data from Solvent Extraction Experiments       378
 A-14        Literature Survey for Recovery of Sulfur       388
               by Solvent Extraction
 A-15        S02 Activity and Pore Volume Determination     398
               of Solvent Extracted Carbon
 A-16        Experimental Results of Bench Scale Recycle    435
               Tests - Solvent Extraction versus Hydrogen
               Treatment
 A-17        Post-Treatment Results of Ammonium Sulfide     471
               Solvent Extracted Carbon
 A-18        Literature Study on Solvent Extraction         497
 A-19        Detailed Data from Combined Sulfur             506
               Stripping/H2S Generation Studies
 A-20        Derivations                                    553
                               ill

-------
Section                                                    Page
 A-21        Sample Calculations for Integral Testing       605
 A-22        Computer Programs                              613
 A-23        Detailed SC>2 Sorber Data Analysis              650

 B        DETAILED PILOT PLANT INFORMATION                  664
 B-l         Analytical Techniques                          665
 B-2         Integral Pilot Plant Operation                 697
 B-3         Blueprints                                     706
 B-4         Pilot Plant Operating Manual                   726
 B-5         Safety Program for Pilot Plant Operation of    789
               Westvaco Process

 C        DETAILS OF PROCESS COMMERCIALIZATION              815
 C-l         1,000 MW Utility Boiler Flue Gas Clean-up,     816
               Detailed Economic Evaluation
 C-2         15 MW Detailed Equipment Design and Cost       825
                              iv

-------
             APPENDIX



            SECTION A



DETAILED RAW DATA AND DATA ANALYSIS

-------
                       APPENDIX A-l



EXPERIMENTAL RESULTS OF THE GRAVIMETRIC FLOW EXPERIMENTS

-------
                GRAVIMETRIC    FLOW   EXPERIMENTS
Run:          138 . G
Dry Weight:   97.30 mg.
Deflection:   -10.80 mg.
C02:          H.3%
S0:          2000 ppm
NO:
02:
H20:
t:
150 ppm
0.7%
10%
200°F
% H2S04:     72.51
Correction:  0.4735
Date:        April 21, 1971
Ft:   1000 cc/min.
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
189
190
200
210
220
230
240
250
260
270
280
290
300
306
Load
mg. H2S04/g- C
3.39
5.65
7.09
8.22
9.35
10.28
11.00
11.72
12.44
13.16
14.59
15.93
17.37
18.71
20.04
23.23
26.62
'29.80
32.79
35.87
38.85
41.73
44.60
47.48
50.36
53.13
55.91
58.58
61.36
63.93
66.60
71.84
76.88
81.71
86.43
90.96
95.79
100.62
105.55
110.79
116.03
121.07
126.10
131.14
136.28
141.32
146.25
151.18
156.22
161.25
166.08
168.96
Mean Load
mg. H2$04/g. C
2
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
no
120
130
140
150
160














•





Rate
mg. H2S04/g. C/min.
3.3402
2.4152
1.6958
1.1614
0.8530
0.72Q7
0.6989
0.6783
0.6680
0.6578
0.6372
0.6269
0.6064
0.5858
0.5755
0.5653
0.5498
0.5396
0.5344
0.5242
0.5190
0.5139
0.5087
0.5087
n.5036
0.5036
0.4985
0.4933
0.4882
0.4882
0 . 4882
0.4830

-------
GRAVIMETRIC   FLOW   EXPERIMENTS
Run:
Dry Weight:
Deflection:
C02:
S02:
139
101.30 mg
-9.83 mg.
11.335
2000 ppm
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
no
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
Load
mg. H2S04/g. C
9.28
11.65
13.33
14.61
15.89
17.08
18.26
19.15
20.14
21.13
23.10
25.17
27.15
29.22
31.29
36.43
41.46
46.50
51.33
56.17
61.01
65.75
70.58
75.22
79.86
84.70
89.34
93.98
98.72
103.26
107.90
116.98
126.26
135.44
144.52
153.50
162.29
170.48
178.58
186.57
194.18
201.88
209.28
216.78
224.09
231.29
238.30
245.21
252.02
258.64
264.46
                 NO:
                 02:
                 H20:

                 Ft:
150 ppm
2.0%
10.0%
200° F
1000 cc/min.
% H2S04--     73.58
Correction:  0.4805
Date:        April 22,
1971
Mean Load
mg. H2S04/q- C
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
220
240
260













* Rate
mg. H2S04/g. C/min.
9.5953
6.9497
5.1135
2 . 8924
.7473
.4610
.2833
.1846
.1155
.0464
.0365
.0168
1.0069
0.9970
0.9872
0.9773
0.9674
0.9576
0.9526
0.9427
0.9378
0.9329
0.9279
0.9230
0.9181
0.9082
0.8983
0.8885
0.8786
0.8638
0.8490
0.8342
0.8193
0.7996
0.7848
0.7453
0.7108
0.6663

-------
                GRAVIMETRIC   FLOW   EXPERIMENTS
Run:
Dry Weight:
Deflection:
G02:
S02:
140
99.86 mg.
-9.78 mg.
11.3*
2500 ppm
NO:
02:
H20:
t:
Ft:
150 ppm
2.0%
10.02!
200° F
1000 cc/min.
% H2S04:
Correction:
Date:
 72.91
 0.4761
'April 23, 1971
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
210
220
i 230 .
240
246
Load
mg. H2S04/g. C
6.91
9.11
11.02
12.42
13.92
15.22
16.52
17.82
19.03
20.23
22.63
25.14
27.54
29.84
32.04
37.65
43.16
48.47
53.68
58.88
64.09
69.20
74.20
79.31
84.42
89.33
94.23
99.34
104.45
109.25
114.06
123.77
133.29
142.60
151.71
160.73
169.34
177.65
185.66
193.47
201.38
209.29
216.90
225.72
233.83
238.03
Mean Load
mg. H2S04/g. C
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
no
120
130
140
150
160
170
180
190
200
220
240









Rate
mg. H2S04/g. C/min.
6.2588
4.5063
2.1330
1.7725
1.5522
1.4070
1.3219
1.2568
1.2217
1.1566
1.1316
1.1166
1.1015
1.0865
1.0765
1.0665
1.0565
1.0465
1 .0365
1.0314
1.0214
1.0114
1.0064
0.9964
0.9914
0.9764
0.9563
0.9463
0.9363
0.9213
0.9063
0.8862
0.8712
0.8512
0.8362
0.7961
0.7561

-------
               GRAVIMETRIC   FLOW    EXPERIMENTS
Run:
Dry Weight:
Deflection:
C02:
502=
141
100.50 mg.
-11.35 mg.
11.3%
1500 ppm
NO:
02:
H20:
t:
Ft:
150 ppm
2.0%
10.0%
200 °F
1000 cc/min.
% H2S04:     74.01
Correction:  0.4834
Date:        April 26, 1971
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
210
220
230
"240
250
260
270
280
290
300
310
320
330
340
350
360
366
Load
mg. H2S04/g. C
6.07
8.36
9.75
10.85
11.94
12.94
13.83
14.83
15.82
16.82
18.81
20.80
22.79
24.78
26.77
31.64
36.52
41.39
45.97
50.35
54.73
59.00
63.18
67.46
71.64
75.62
79.70
83.78
87.96
92.04
96.12
104.08
111.94
119.70
127.36
134.83
142.69
150.25
157.31
164.68
171.74
178.61
185.37
192.24
199.00
205.47-
211.64
217.61
223.38
228.96
234.33
239.10
243.98
248.46
253.23
257.91
262.29
264.78
Mean Load
mg. H2S04/g. C
2
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
no
120
130
140
150
160
170
180
190
200
220
240
260









'









Rate
mg. HgSO^g. C/min.
6.9154
5.7015
3.1343
1.5423
1.2637
1.1294
1.0597
1.0149
0.9950
0.9800
0.9751
0.9602
0.9502
0.9403
0.9254
0.9154
0.9055
0.8955
0.8856
0.8756
0.8706
0.8657
0.8557
0.8458
0.8408
0.8308
0.8159
0.8010
0.7861
0 . 7662
0.7463
0.7214
0.7015
0.6766
0.6517
0.6269
0.5721
0.5224
0.4627

-------
GRAVIMETRIC   FLOW   EXPERIMENTS
Run:          142
Dry Weight:   99.18mg.
Deflection:   -11.64 mg.
C02:          11.3*
S02:
                 NO:
                 02:
                 H20:
                 t:
150 ppm
2.0%
10.01
200° F
1 H2S04:     71.88
Correction:  0.4694
Date:        April 27, 1971
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
?80
290
300
310
312
Load
mg. H2S04/g. C
6.25
7.66
9.07
10.18
11.39
12.60
13.61
14.62
15.63
16.54
18.25
19.96
21.78
23.59
25.41
29.74
34.08
38.31
42.75
46.98
51.02
55.05
59.08
63.12
67.05
71.08
74.71
78.34
82.17
85.80
89.53
96.69
104.36
112.12
119.78
127.24
134.70
142.06
149.22
156.48
163.44
170-30
176.95
183.10
189.66
196.01
202.16
208.11
214.16
220.00
225.45
230.59
231.50
                 Ff.    1000 cc/min.
Mean Load
mg. H2S04/g. C
2
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
no
120
130
140
150
160
170
180
190.
200
220
240















Rate
mg. H2S04/g. C/min;
7.0075
5.1220
2.9744
1.3410
1.1595
1.0536
0.9831
0.9377
0.9125
0.9074
0.8923
0.8822
0.8671
0.8570
0.8469
0.8369
0.8268
0.8167
0.8066
0.8016
0.7915
0.7814
0.7764
0.7663
0.7562
0.7512
0.7360
0.7209
0.7058
0.6907
0.6755
0.6604
0.6453
0.6251
0.6050
0.5848
0.5445
0.5041

-------
                GRAVIMETRIC   FLOW   EXPERIMENTS
Run:
Dry Weight:
Deflection:
C02:
S02:
143
100.02 mg.
-12.38
11.3%
500 ppm
NO:
02 :
H20:
t:
150 ppm
2.0%
10.0%
200 °F
1000 cc/m1n.
Correction:
Date:
72.45
0.4732
April 28, 1971
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
310
320
330
340
350
360
370
380
390
400
410
420
Load
mq. H2S04/Q. C
4.50
6.10
7.40
8.50
9.50
10.50
11.40
12.00
12.90
13.60
15.00
16.50
18.00
19.40
20.70
24.00
27.09
30.29
33.49
36.59
39.59
42.49
45.39
48.39
51.19
53.99
56.59
59.59
62.49
65.39
68.09
73.49
78.88
84.18
89.48
94.68
100.08
105.78
111.18
116.68
122.08
127.37
132.47
137.87
142.97
148.17
153.47
158.77
163.97
169.07
173.77
177.86
182.26
186.46
190.66
194.96
198.76
203.56
208.16
212.66
217.06
221.56
225.75
Mean Load
mg. H2S04/g. C
2
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
220


























Rate
mg. H2S04/q. C/min.
4.6491
2.9794
1.4497
1.1498
0.9648
0.8498
0.7698
0.7199
0.6849
0.6649
0.6549
0.6399
0.6299
0.6249
0.6149
0.6049
0.5999
0.5949
0.5849
0.5799
0.5749
0.5699
0.5649
0.5599
0.5549
0.5499
0.5449
0.5349
0.5249
0.5149
0.5049
0.4949
0.4799
0.4699
0.4599
0.4449
0.4149

•



















V



•

-------
                GRAVIMETRIC   FLOW   EXPERIMENTS
Run:          144 -  G
Dry Weight:   98.68  mg.
Deflection:   -10.07 mg.
C02:          11'3%
503:          2000 ppm
NO:
02:
t:
Ft:
150 ppm
3.5%
10.0%
200°F
1000 cc/m1n.
% H2S04:     73.31
Correction:  0.4788
Date:        April 29, 1971
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
Load
mg. H2S04/g. C
7.60
10.03
12.16
14.09
15.91
17.73
19.36
20.98
22.50
24.12
27.16
30.20
33.14
36.08
38.91
46.01
53.10
60.09
67.09
73.98
80.97
87.86
94.65
101.34
108.23
115.02
122.11
129.00
135.79
142.48
149.07
162.04
174.40
186.46
198.52
209.97
221.02
231.96
242.30
252.23
261.96
271.08
279.89
288.61
297.02
Mean Load
mg. H2S04/g. C
4
6
8
10
12
14
16
18
20
25
30
35
40
. 45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
220
240
260
280






Rate
mg. H2$04/g. C/min.
7.2963
5.1176
3.4455
2.1078
1.9457
1.8494
1.7734
1.7075
1.6417
1.5505
1.4998
1.4745
1.4593
1.4491
1.4390
1.4289
1.4187
1.4086
1.3985
1.3934
1.3883
1.3833
1.3731
1 . 3681
1 . 3630
1.3529
1.3427
1.3326
1.3174
1.2971
1.2819
1.2566
1.2262
1.1958
1.1654
1.0995
1.0336
0.9627
0.8918

-------
                GRAVIMETRIC   FLOW   EXPERIMENTS
Run:         145 . G
Dry Weight:  100.90 mg.
Deflection:  -2.31 mg.
S02:         2000 ppm
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
Load
mg. H2S04/g. C
8.92
11.40
12.98
14.47
15.86
17.24
18.53
19.92
21.31
22.70
25.27
27.85
30.33
• 33.00
35.48
41.13
46.78
52.43
57.88
63.43
68.78
74.23
79.68
84.94
90.19
95.34
100.59
105.65
110.80
115.76
120.91
130.92
140.63
150.05
159.27
168.29
177.01
185.53
194.15
202.48
210.51
217.84
224.98
232.31
238.85
NO:   150 ppm
02:   2.0%
H20:  10.0%
t:    200°F
Ft:   1000 cc/min.
% H2S04:     72.61
Correction:  0.4742
Date:        April 30, 1971
Mean Load
mg. H2S04/g. C
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
' 60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
220
240








Rate
mg. H2S04/g. C/min.
8.9197
7.0862
5.2032
3.6670
2.0317
1.4668
1.4073
1.3677
1.3380
1.2834
1.2438
1.2141
1.1893
1.1645
1.1447
1.1298
1.1150
1.1001
1.0902
1.0803
1.0704
1.0605
1.0505
1.0406
1.0357
1.0208
1.0010
0.9812
0.9613
0.9316
0.9118
0.8821
0.8573
0.8Z7fi
0.7978
0.7384
0.6739








                                             1.0

-------
              GRAVIMETRIC    FLOW   EXP-ERIMENTS
Run:          148-6
Dry Weight:   100.94 mg.
Deflection:   -9.02 mg.
C02:          11.»
$03:          2500 ppm
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
Load
mg. H2S04/g. C
26.25
36.95
44.09
50.53
56.07
61.72
66.48
71.23
75.69
80.15
88.07
95.80
103.53
"110.86
117.79
133.94
1 48. 70
162.47
176.02
188.83
200.52
211.12
221.02
229.54
237.07
244.11
250.94
257.58
264.22
270.85
277.29
290.07
301.76
312.17
321.28
329.80
338.02
346.05
353.68
360.11
366.55
372.70
378.64
384.29
389.14
NO:   150 ppm
02:   2.0%
H20:  10.0%
t:    150°F
Ft:   1000 cc/min.
% H2S04:     57-18
Correction:  0.3734
Date:        May 7, 1971
Mean Load
mg. H2S04/g. C
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
. 55
60
65
70
75
80
85
90
95
100
no
120
130
140
150
160
170
180
190
200
220
240
260
280
300
320
340
360
380

Rate
mg. H2S04/g. C/min.
37.9433
34.9713
32.2469
29.8197
27.4916
25.3121
23.2812
21.3989
19.6156
15.3061
11.7396
8.9657
7.2816
6.6475
6.1423
5.6965
5.3002
4.9534
4.7058
4.4977
4.3293
4.1708
4.0222
3.8934
3.7745
3.5566
3.3386
3.1405
2.9622
2.7937
2.6352
2.4866
2.3281
2.1785
2.0408
1.7832
1.5554
1.3572
1.1888
1.0402
0.9015
0.7628
0.6*39
0.5350

                                            11

-------
                GRAVIMETRIC   FLOW   EXPERIMENTS
Run:         149 -  G
Dry Weight:   105.38 mg.
Deflection:   -10.58 mg.
C02:         11.32
502'         1500 ppm
NO:   150 ppm
02:   2.0%
H20:  10.0%
t:    150°F
Ft:   1000 cc/min.
% H2S04:     56.86
Correction:  0.3713
Date:        May 10, 1971
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
no
120
130
140
150
160
170
180
190
200
210
220
230
240
Load
mg. H2S04/g. C
24.10
34.07
40.71
46.02
50.67
55.04
58.74
62.26
65.57
68.80
74.97
• 81.04
86.73
92.33
98.03
112.36
126.21
138.64
150.31
161.32
171.95
182.29
192.16
201.46
210.48
218.92
226.80
234.39
241.41
248.05
254.22
266.18
276.81
286.68
296.17
305.37
313.53
320.74
327.67
334.03
339.91
345.61
351.11
356.33
361.17
Mean Load
mg. H2S04/g. C
10
12
14
16
18
20
25
30
35
40
45
50
55
60
" 65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
220
240
260
280
300
320
340
360





Rate
mg. H2S04/g. C/min.
26.5705
24.1032
21.8258
19.7381
17.9351
16.2744
12.5261
9.6318
7.4492
6.1207
5.1243
4.5549
3.8622
3.5586
3.3488
3.2027
3.0888
3.0129
2.9512
2.8895
2.8326
2.7757
2.6665
2.5622
2.4673
2.3771
2.2965
2.2016
2.1067
2.nilR
1.9121
1.8077
1.5942
1 . 3855
1.1909
1.0154
0.8541
0.7117
0.5883
0.4R87





                                              12

-------
               GRAVIMETRIC   FLOW   EX P. ERIMENTS
Run:          150 - 6
Dry Weight:   105.66 mg.
Deflection:   -11.50 mg.
C02:          ll.W
S02:          500 ppm
NO:
02:
H20:
t:
Ft:
150 ppm
2.0%
10.03
150°F
1000 cc/min.
% H2S04:     53.33
Correction:  0.3482
Date:        May 11, 1971
Time
mi nutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
no
1*0
130
140
150
160
170
180
190
200
210
220
230
240
Load
mg. H2S04/g. C
22.43
29.34
33.50
37.01
40.22
42.97
45.33
47.51
49.69
51.68
55.74
59.53
63.13
67.01
70.89
80.54
90.48
99.75
109.12
118.40
127.67
136.66
145.37
153.98
161.93
169.60
177.17
184.46
191.56
198.37
205.09
218.44
231.40
243.61
254.31
264.05
273.33
282.23
290.93
299.36
307.50
314.78
321.79
327.84
332.95
Mean Load
mg. H2S04/g. C
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
220
240
260
280
300
320
340





Rate
mg. H2S04/g. C/min.
30.3805
24.7965
21.0581
17. .9349
15.2849
13.0134
11.0733
7.3822
5.0161
3.5018
2.7447
2.2714
2.0963
.9544 .
.8976
.8739
.8455
.8361
.8171
.7982
.7793
.7651
1.7462
1.7083
1.6846
1.6373
1.5947
1.5569
1.5190
1.4717
1.4291
1.3913
1 . 3439
1.2493
1.1546
1.0411
0.9275
0.7855
0.6388
0.4921





                                           13

-------
               GRAVIMETRIC   FLOW   EXPERIMENTS
Run:
Dry Weight:
Deflection:
C02:
151 - G
101.36 mg.
-11.68 mg.
11.3%
2500 ppm
NO:  150 ppm
02:  2.0%
H20: 10.0*
t:   300°F
Ft:  1000 cc/min.
* H2S04:     81.86
Correction:  0.5346
Date:        May 12, 1971
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
no
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
310
320
330
340
350
357
Load
mg. H2S04/g. C
3.55
5.82
7.40
8.88
10.26
11.35
12.43
13.42
14.31
15.19
16.77
18.35
19.83
21.21
22.59
26.05
29.20
32.16
35.22
38.18
41.04
44.00
46.86
49.72
52.58
55.35
58.11
60.87
63.73
66.50
69.16
74.59
80.01
85.24
90.37
95.50
100.63
105.47
109.91
114.34
118.49
122.93
127.17
131.12
134.96
138.61
142.27
145.92
149.37
152.92
156.37
160.12
163.77
167.32
170.78
174.03
176.20
Mean Load
mg. H2S04/g. C
2
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180























Rate
mg. H2S04/g. C/min.
3.5221
2.5355
1 . 7856
1.3319
1.1247
0.9866
0 . 8879
0.8139
0.7597
0.7202
0.6511
0.6166
. 0.5919
0.5821
0.5722
0.5673
0.5624
0.5574
0.5476
0.5426
0.5328
0.5229
0.5130
0.5032
0.4982
0.4834
0.4637
0.4440
0.4242
0.4045
0.3798
0.3552
0.3256
0.3009























                                             14

-------
GRAVIMETRIC    FLO
          EXPERIMENTS
Run:         152 - G
Dry Weight:   105.94 mg.
Deflection:   -12.67 mg.
CO?:         11.»
S02:         1500 ppm
                 NO:
                 02:
                 H20:
                 t:
150 ppm
2.0%
10.0%
300°F
1000 cc/min.
* H2S04:     82.66
Correction:  0.5398
Date:        May 14, 1971
Time
minutes
1
2
3
4
5
6
7
8
9
lo
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
'75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
310
320
330
340
350
360
370
380
390
400
420
440
4fiO
480
500
520
" 	 510 "
560
5RO
600
Load
mg. H2S04/g. C
1.32
2.27
3.02
3.87
4.63
5.29
5.95
6.51
7.17
7.83
9.06
10.19
11.33
12.37
13.50
16.05
18.50
20.77
23.13
25.39
27.75
30.02
32.19
34.36
36.44
38.32
40.31
42.19
44.08
45.88
47.67
51.16
54.56
57.67
60.79
63.72
66.74
69.85
72.78
75.61
78.72
81.74
84.58
87.60
90.52
93.35
96.00
98.36
100.72
102.98
105.44
108.08
110.44
112.80
115.16
117.61
119.78
122.05
124.22
126.39
128.56
132.81
136.87
141.02
145.18
149.05
152.92
156. 8" ft
IBoTSB 	
164.24
167.64
Mean Load
mg. H2S04/g. C
2
4
6
8
10
12
14
16
IP
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
no
120
130
140
150
160







































Rate
mg. H2.S04/g. C/min.
0.8873
0.7363
0.6796
0.613fi
0.5758
0.5175
0.5192
0.6003
0.4861
0.1720
0.4436
0.1200
0.3965
0.377fi
0.3K34
0.3493
0.3304
0.3lfi2
0.3068
0.2Q73
0.2P79
0.2785
0.2690
0.2643
0.2549
0.2454
0.2360
0.2265
0.2171
0.2077
0.1935
0.1R41







































                   15

-------
                 GRAVIMETRIC   FLOW   EXPERIMENTS
Run:
Dry Weight:
Deflection:
C02:
S02:
153 - G
103.18 mg.
-8.23 mg.
-8.50 mg.
11.3*
2500 ppm
                                   NO:
                                   02:
                                   H20:
                                   t:
150 ppm
2.0%
10.0%
150°F
1000 cc/min.
Correction:
Date:
61.24
0.3999
May 18, 1971
Time
minutes
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
22
24
26
28
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
2lO
220
230
240
250
260
270
280
i?90
300
Load
mg. H2S04/g. C
25.10
32.86
37.89
42.55
46.62
50.01
53.60
57.08
60.28
63.58
66.87
69.88
72.79
76.08
77.99
81.99
85.00
88.00
91.01
93.91
99.73
105.25
110.87
116.59
122.12
135.39
148.19
160.50
172.13
183.76
194.90
205.27
215.45
225.24
234.54
243.26
251.60
259.45
266.91
281.06
294.44
306.55
317.60
327.39
337.18
346.48
354.91
362.47
369.45
376.33
382.73
388.64
394.46
399.79
404.83
409.48
413.94
41S.49
422.76
Mean Load
mg. H2S04/g. C
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
no
120
130
140
150
160
170
180
190
200
220
240
260
280
300
320
340
360
380
400
420
440
460
480
500
520
540
560









Rate
mg. H2S04/g. C/min.
29.0754
26.0709
23.0665
20.4497
17.9298
15.7007
10.9517
7.1719
5.5728
4.5067
4.0124
3.6763
3.3727
3.2855
3.2080
3.1401
3.0771
3.0238
2.9705
2.9269
2.8785
2.8397
2.7719
2.7040
2.6362
2.5683 .
2.4908
2.4230
2.3454
2.2582
2.1807
2.1031
1.9287
1.7639
1.5895
1.4150
1.2309
1.0467
0.8820
0.7463
0.6203
0.5330
0.4652
0.4071
0.3683
0.3392
0.3101
0.2714
0.2520
0.2326









* Run 153 - G continued on next page.
                                               16

-------
               GRAVIMETRIC   FLOW   EXPERIMENTS
(CONTINUED FROM PREVIOUS PAGE)
Run:
Dry Weight:
Deflection:
CO,
S02
153 - G
103. 18 mg
-8.23 mg.
-8.50 mg.
11.3%
2500 ppm
Time
Minutes
310
320
330
340
350
360
~ 370
380
390
400
410
420
430
440
450
460
470
480
490
500
510
520
530
540
550
560
570
580
590
600
610
620
630
640
650
660
670
680
690
700
710
720
730
740
750
Load
mg. HjSO/i/g. C
427.02
431.29
435.26
439.23
443.01
446.60
450.47
454.16
458.03
461.91
465.69
469.28
473.06
476.74
480.42
484.01
487.50
- 490.89
494.18
497.29
500.29
503.20
506.11
508. 82
511.73
514.54
517.25
519.97
522. 58
525.20
527.82
530.43
532.86
536.34
539.45
542.64
545.65
548.46
551.17
553.89
556.50
559.12
561.45
563.68
565.61
                                NO:
                                02:
                                H20:
                                t:
                                Ft:
150 ppm
2.0%
10.0%
150°F
1000 cc/min.
% H2S04:    61.24
Correction: 0.3999
Date:       May 18,  1971
                                             17

-------
               GRAVIMETRIC    FLOW   EXPERIMENTS
Run:         157 -  Q
Dry Weight:   104.66 mg.
Deflection:   -10.56 mg.
C02:         11.3%
SO?:         2000 ppm
Time
mi nutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
Load
mg. H2$04/g. C
7.93
10.13
12.04
13.85
15.77
17.39
19.11
20.64
22.36
23.98
27.33
30.48
33.73
36.98
40.13
47.96
55.80
63.54
71.47
79.02
86.28
99.08
110.93
122.59
134.15
145.61
157.18
168.26
179.06
189.66
199.98
210.11
219.85
229.51
238.87
248. 33
257.60
266 .67
275.37
283.87
291.99
299.92
306.99
313.97
320.56
326.96
NO:
02:
H20:
t:
150 ppm
2.0%
15.0%
200° F
1000 cc/min.
% H2S04:     67.91
Correction:  0.4435
Date:        May 31, 1971
Mean Load
mg. H2S04/g. C
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
220
240
260
280
300
320





Rate
mg. H2S04/g. C/min.
7.6916
5.7806
3.7264
2.1020
.9014
.8154
.7581
.7103
.6816
.6339
.6243
.6148
.6052
.5861
.5765
.5574 •
.5383
.5288
.5192
.5001
1.4905
1.4714
1.4523
1.4428
1.4237
1 . 3854
.3472
.3090
.2708
.2326
.1943
.1561
.1179
.0892
.0606
.0128
0.9555
0.8886
0.8122
0.7357
0.6593


.


                                           18

-------
             GRAVIMETRIC   FLOW   EXPERIMENTS
Run:
Dry Height:
Deflection:
COo:
S02:
158 - G
104.96 mg.
-14.86 mg.
11. 3%
500 ppm
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
220
240
260
280
300
320
340
360
380
400
420
440
460
480
500
520
540
B60
580
600
Load
mg. H2S04/g- C
0.86
1.62
2.29
2.95
3.53
4.19
4.67
5.24
5.72
6.19
7.15
8.00
8.86
9.72
10.58
12.39
14.10
15.82
17.53
19.25
20.87
24.20
27.34
• 30.49
33.35
35.82
38.21
40.49
42.78
44.87
47.07
48.97
50.69
52.50
54.21
55.93
59.26
62.50
65.74
68.98
72.12
75.27
78.70
82.13
85.46
88.61
91.65
94.61
97.47
100.23
102.80
105.28
107.76
no. 14
112.42
114.52
                               NO:
                               02:
                               H20:
                               t:
150 ppm
2.0%
10.0%
300°F
1000 cc/min.
% HZS04:     77.62
Correction:  0.5069
Date:        June 1, 1971
Mean Load
mg. H2S04/g. C
2
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
no
120
130
140
150
160
170
180
190





















Rate
mg. H2S04/0. C/min.
0.6955
0.5526
0.4735
0.4373
0.4097
0.3859
0.3659
0.3478
0.3325
0.3173
0.2877
0.2639
0.2439
0.2287
0.2144
0.2020
0.1915
0.1820
0.1734
0.1667
0.1601
0.1543
0.1496
0.1448
0.1401
0.1353
0.1277
0.1191
0.1124
0.1058
0.0991
0.0934
0.0877
0.0819
0.07R2





















Run 158 - G continued on next page.
                                          19

-------
GRAVIMETRIC   FLOW   EXPERIMENTS
(CONTINUED  FROM PREVIOUS PAGE)
             158  - G
             104.96 mg.
             -14.86 ing.
             11.3%
Run:
Dry Weight
Deflection
S02:
Time
minutes
620
640
660
680
700
720
740
760
780
800
820
840
860
880
900
920
940
960
980
1000
1020
1040
1060
1080
1100
1120
1140
1160
1180
1200
1220
1240
1260
1280
1300
1320
1340
1360
1380
1400
1420
1440
1460
1480
1500
500 ppm.
Load
mg. H2S04/g. C
116.71
118. 9T
121.23
123.43
125.76
128.14
130.53
132.81
135.19
137.67
139.96
142.15
144.44
146.53
148.53
150.25
152.06
153.87
155.58
157.39
159.20
160.92
162.54
164.35
166.06
167.87
169.59
171.30
173.02
174.83
176.64
178.45
180.07
181.69
183.21
184.93
186.64
188.17
189.60
191.03
192.55
194.07
195.50
196.93
198.36
NO:
02:
H20:
t:
Ft:
                        150 ppm
                        2.0%
                        10.0%
                        300°F
                        1000 cc/min.
% H2S04:
Correction:
Date:
77.62
0.5069
June 1 , 1971
                             20

-------
               GRAVIMETRIC   FLOW   EXP-ERIMENTS
Run:          160 - G
Dry Weight:   102.06  ing.
Deflection:   -11.12  mg.
0)2:          H.3%
SOg:          2000 ppm
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
Load
mg. H2S04/g. C
4.90
7.15
8.82
10.09
11.66
12.93
14.11
15.09
16.07
16.95
18.62
20.09
21.56
22.93
24.20
27.53
30.57
33.71
36.65
39.58
42.52
48.30
53.69
58.50
62.81
67.51
72.11
76.72
81.32
85.83
90.05
94.16
98.47
102.88
107.39
111.70
116.30
120.91
125.51
130.41
135.31
140.60
145.89
150.99
155.50
159.12
NO:
02:
H20:
t:
150 ppm
2.Q%
5.0%
200°F
1000 cc/min.
             80.42
Correction:  0.5252
Date:        June 9, 1971
Mean Load
mg. H2S04/g. C
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160















Rate
mg. H£S04/g. C/min.
3.8017
2.6749
1.8910
1.3717
1.1660
1.0288
0.9112
0.8328
0.7643
0.6663
0.6271
0.6075
0.5R79
0.5683
0.5585 .
0.5389
0.5291
0.5193
0.5095
0.4997
0.4801
0.4703
0.4654
0.4605
0.4507
0.4409
0.4311
0.4213
0.4164
0.4115
0.4115















                                            21

-------
               GRAVIMETRIC   FLOW   EXPERIMENTS
Run:         161  - G
Dry Height:   99.64 mg.
Deflection:   -9.76 mg.
C02-         11-3%
SOg:         2000 ppm
Time
mi nutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
Load
mg. H2S04/g. C
8.03
10.44
12.24
13,95
15.25
16.66
17.96
19.07
20.27
21.48
23.69
25.99
28.20
30.31
32.52
37.64
42.65
47.47
52.29
57.21
61.92
71.36
80.89
89.82
98.25
106.78
115.11
123.44
131.67
139.90
148.03
156.76
165.19
173.73
182.06
189.88
197.61
205.14
212.57
219.69
226.62
233.04
239.46
245.58
251.91
257.53
NO:   300 ppm
02:   2.0%
H20:  10.0%
t:    200°F
F:   1000 cc/min.
% H2S04:     73.03
Correction:  0.4769
Date:        June 10, 1971
Mean Load
mg. H2S04/g. C
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
no
120
130
140
150
160
170
180
190
200
220
240
260








Rate
mg. H2S04/g. C/rrrin.
8.1794
5.8711
4.2152
2.7098
.7061
.4352
.2947
.1943
.1542
.1040
.0739
.0438
.0337
1.0136
0.9936
0.9835
0.9635
0.9534
0.9534
0.9434
0.9434
0.9334
0.9334
0.9233
0.9133
0.9033
O.R932
0.8731
0.8531
0.8430
0.8230
0.8029
0.7828
0.7627
0.7326
0.6724
0.6122
0.5420








                                           22

-------
              GRAVIMETRIC    FLOW   EXPERIMENTS
Run:          162  - G
Dry Weight:   103.02 mg.
Deflection:   -11.12 mg.
CO?:          11.S
$02:          2000 ppm
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
Load
mg. H2S04/g. C
7.86
10.10
12.13
14.17
16.50
18.83
20.97
23.30
25.72
28.05
32.91
37.86
42.90
' 48.05
53.39
67.95
82.99
97.65
112.70
128.13
143.27
171.23
197.15
222.29
246.36
267.81
286.06
302.08
316.06
329.16
341.10
351.19
360.61
369.83
378.57
387.11
395.46
403.32
411.09
417.88
423.90
429.04
434.09
438.75
443.89
448.46
NO:
02:
H20:
t:
0 ppm
2.0%
10.0*
200°F
1000 cc/min.
* H2S04:     74.59
Correction:  0.4871
Date:        June 11, 1971
Mean Load
mg. H2S04/g. C
2
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
60
70
80
90
100
no
120
130
140
150
160
170
180
190
200
220
240
260
280
300
320
340
360
380
400
420
440



Rate
mg. H2S04/g. C/min.
9.3671
7.8626
6.2124
4.0769
2.3685
2.1355
2.0967
2.1161
2.1646
2.2035
2.3199
2.4170
2.5044
2.5723
2.6403
2.7082
2.8053
2.8926
2.9509
2.9897
3.0188
3.0188
2.9994
2.9703
2.9412
2.8829
2.8344
2.7762
2.7179
2.6500
2.5723
2.4073
2.2326
2.0384
1 . 8443
1.6502
1.4366
1.2134
1.0289
0.8639
0.7183
0.5824
0.4950



                                           23

-------
               GRAVIMETRIC    FLOW   EXP-ERIMENTS
Run:         163 -  G
Dry Weight:   99.18 mg.
Deflection:   -11.15 mg.
C02:         H.3%
S02:         2000 ppm
Time
mi nutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
Load
mg. H2S04/g. C
4.13
6.96
9.07
11.09
12.81
14.32
15.83
17.24
18.75
20.17
23.09
25.71
28.43
30.95
33.37
39.42
45.27
51.02
56.77
62.92
68.76
80.66
91.95
103.35
114.44
125.13
135.41
145.59
155.88
165.86
175.54
185.32
194.60
203.67
212.04
219.80
227.47
234.62
241.78
248.94
255.80
262.25
268.60
274.85
280.80
286.55
NO:
02:
H20:
t:
50 ppm
2.0%
10.0%
200 °F
1000 cc/min.
% H2S04:     73.33
Correction:  0.4789
Date:        June 14, 1971
Mean Load
mg. H2S04/g. C
2
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
220
240
260
280






Rate
mg. H2S04/g. C/min.
4.1641
3.4281
2.7929
2.2686
1.8653
1.7141
1.6132
1.5326
1.4620
1.4116
1.3107
1.2603
1.2402
1.2301
1.2099
1.1998
1.194ft
1.1898
1.1847
1.1797
1.1696
1.1595
1.1494
1.1393
1.1343
1.1192
1.0990
1.0788
1.0486
1.0284
0.9982
0.9780
0.9478
0.9276
0.8974
0.8671
0.8066
0.7461
0.6755
0.6050






                                           24

-------
               GRAVIMETRIC    FLOW   EXPERIMENTS
Run:
Dry Weight:
Deflection:
CO?:
S02:
164 - G
98.02 mg.
-12.73 mg.
11.3%
150 ppm
NO:
02:
H20:
t:
Time
minutes
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290.
300
310
320
330
340
350
360
370
380
390
Load
mg. H2S04/g. C
2.75
4.49
5.71
6.73
7.65
8.57
9.49
10.41
11.32
12.24
13.87
15.61
17.24
18.87
20.40
24.48
28.26
31.93
35.50
39.07
42.54
49.38
56.01
62.74
69.68
76.41
83.55
90.29
97.33
104.06
110.49
117.53
124.26
130.99
137.42
143.95
150.38
156.70
163.23
169.46
175.88
182.11
187.82
194.35
200.37
206.18
212.20
217.91
223.73
229.44
235.16
240.87
246.38
251.79
257.09
150 ppm
2.0%
10.0%
200°F
1000 cc/min.
Correction:
Date:
73.10
0.4774
June 15, 1971
Mean Load
mg. H2S04/g. C
2
4
6
8
10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
160
170
180
190
200
220
240

















Rate
mg. H2S04/g. C/min.
2.4791
1.7139
1.1120
0.9692
0.8988
0.8468
0.8264
0.8060
0.7856
0.7754
0.7447
0.7345
0.7141
0.7039
0.6937
0.6886
0.6886
0.6835
0.6835
0.6835
0.6835
0.6835
0.6835
0.6835
0.6835
0.6835
0.6733
0.6631
0.6631
0.6529
0.6427
0.6376
0.6325
0.6223
0.6121
0.5917
0.5713
0.5407

















                                            25

-------
                            APPENDIX
                                             A-2
 COMPUTER CALCULATIONS  -  SORPTION RATE DATA AND MODELS
CARBON C - 71   23

JUlN  MlKlilK =   1 '10 - G
I | Ml- 1 RATUKl -  200.  Ul ;",
                             21  71
TllAL  M-CIW RAIT  =  1000.0 CC/MI'I

I'M iU".l:iJf  C(!2 •-    11.3
IM ,.;U ".(   L2 -=     0. 7
PI .•'.U-.Nl'  1120 =    1 0.0

CU'JC.r.'-lTKAT H)N S02  =  2000.0  I1!'?--
CC \:Cl"J KAI [UN1  ,\f.)  •-   100.0  PPV
rM.'0

        O.OOOoO
                          RAFI-,  tiMS
          00 y,v>
          OHB7()
          0 1. 0 1 'j
          Ul U-0
          01 10'.)
          01't'jO
          018 I i
       0.0,:'! 7!)
       0.02900

       0.03620
       0.0 1'} (if.
       O.O'i.lO]
       0.0', /13
       C.00076
       0.0'>'i3h
       O.OOiiOl
       0.06 I6J
          C t> 0 2 6
          06'I'J'J
          0/20 I
       0
       0
       0
       0
       0
       0
       0. li)P>l
       0. 11876
       O.I I 602
        ,01! 70 1
        .09'i,'6
                                        0. 002'. 2
                                        0.00] 7-j
                                        O.OU123
                                        O.OOlJFi'V
                                        0.00062
                                        0. HOU').}
                                        0.0000 I
                                        O.OOO'.V
                                          , OOO'ib
                                          . OOO'io
                                          .000^6
                                          00()''«2
                                          00' >'• "-1
                                          00040
                                          CJCOj-J
                                          OU01-;
                                          0003 9266
                                    26

-------
                         Carbon,- C - 71 —
                           ^\ MU.v?ER  =   1/39   "  "
                           Tc"P£«ATim- =  200.  DEG F

                          ' U:TAL
                                    C2
                                            11.3
                                             2.0"
                                            10.0
                                     1D\' SG2  =  2000.0 PPM
                                     ICN   NO  =   150.0 PPM
PE~CE:.T H2S04
SAT'jk-TEO  LCA'
                                             73.58
                                                  0.38 GKS  H2SU4/GK C
Ni
O.C0294
0-00441
O.C0589
O.CCV36
O.COS33
O.OiC30
0.01177
0.01324
0.01^72
0.01339
0.02207
0.:-2575
0.03311
O.C3679
C. 040 47 J •.•'.
O.C5151
C.'.'.SIS
O.C5336
O.C6254
C.C6622
0.06990
0.07353
C.C3C94
C. COB 30
C. 09565
C. 10301
C. 11037
0.11773
0.12509
0.13930 '.
• 0.16138
C. 17659
C . 1 9 1 3 1
RATE, GMS H2S04/GM C-KIN
0-00706
O.Q0511
0,00376 .
O.CC213 . ;;-:
0-00129 .-••..'• • '•••..
0.00108
0.00094
0.00087
:• C. 0003 2
• . 0.00077
0.00076
0.00075
0. 00074
0.00073
: - 0.00073
- •. .^./••. ••• -. 0.00072
.."•, : • 0.00071
0.00070
0.00070
0.00069
0.00069 ...:. -•
0.00069 •:'!'•'.!:'?. £
0.00068 **'•'••"
0.00066
0.00068
0.00067
0.00066
0.00065
0.00065
0.00064
0.00062
0.00061
i .: - .. 0.00060 :.'-.
'"":. ''•;'• • 0.00059 •!/ :
0.00058
C. 00055
0.00052
t. 00049
                                                                                          KESTVACO
                                                                                          -4.94551
                                                               -5.56706
                                                               -6. 13291
                                                               -6.63297
                                                               -6.80795
                                                               -6.93355
                                                              _-7. 00967
                                                               -7 ".06 57 5
                                                               -7.11958
MCDweSTVACO
    -4.93773
_ -5.25248
    -"5.55145"
    -6. 11336
    -6.50946
    -6.7J047"
    -6.90213
                                                                                          7.12772
                                                                                          7. 12TC6
                                                                                         -7. 12561
                                                                                         -7.12491
                                                                                          7. 12420
                                                                                          7. 12336
                                                                                          7.11746
                                                                                          j. 1166';
                                                                                          7. 11047
                                                                                          7. 10413
                                                                                          7 . 09790
                                                                                          7.09140
                                                                                          7.0S479
    _.
   -7-02626
   -7.06996
   -7.05901
   -7 '.05754
   -7.04*44
 __-7. 03522
   -7.02378
   -7.01230
   -7.00070_
  ~-i.95Se5
   -6.97131
                                                                               -6.92435
                                                                               -6.90641
                                                                              ~''
                                                                                         -7.05737"
                                                                                         -7.04279
                                                                                         -_7._02773
                                                                                         -7.01735
                                                                                         -7.00746
                                                                                         :6... 99659
                                                                                         -6.9853?"
                                                                                         -6.97949
                                                                                         r£..96706.
                                                                                         -6.9534l""
                                                                                         -6.93C96
                                                                              -6.S6957
                                                                              76_vp3180
                                                                               6. H 2 94
                                                                               6.75232
                                                                               6.67473
                                                                               6.63667
                                                                               6-55679
                                                                               6.52073
                                                                               6. 39;! 31
                                                                               6.30600
                                                                               6.22046
    AMUNDSQN
    3.33011"
    2.55679
 _____ 1.88126
  ""1.064 I i"
    0.64233
    0.53750
    0.47213"
    0 . 4 J ? B I
 _____ 0.4l_0 i9_
    C . 3ti'-9 /
    0.31133
 ____ O.i7408
  ~0.37C44"
    0.3661)0
 __ 0.36319
    6.":i"5Y55
    0 . 3 S 5 -U
 ____  0.35230
    0.33046""
    0. 34682
_..0.3_4_502 _
    0.34321
    0.34137
_ _  0.33057
    0.3? 77 7 ""~
    0.33413
____ 0...3 3.0.43 _
    0.32683
    C. 32324
_ Q. 3 177.9 _
   6.3"l2~35
   0.30690 .
__ C..J01/.2_
   0.29417
   0.23873
                                                                                                                                 0.26150
                                                                                                                                 0.24513

-------
                        RU
       '  139

.  0^3 M2S04/GM
 O.CC683
 0-J"857
 O.C'J98l_  __
 0.0-1075
 O.CU69
 0.01257
                                                  4 22 71

                                                       JOST^

                                                    0-'-6663
                                                    0.
                                                    O.B5530
                      :    *    0.014J9
                      	O.Cl'-32__	
                               r>. •• i <^^«;      ~
                               0.
                               0.01700
                               0.01652
                               C.01993 "
                               O.C2150
                               O.C2302
                             "~~
ro
CO
 O.C30il
_0.03421_
' O.C3777
 0.04133
 O.C4439_
 0.--4338"
 O.C5193
. O.C5535_.
 O.C5876
 0-C5232
 O.C6574
"0.06915
 0.07264
 0.07593
 0.07939"
 0.05607
 p.09290_
~0.09966
 0.10634
 0- 11295_
"0.11941
 0-12544
J3. 13140_
 0". 13726
 0. 14288
 0.14854
"O. 15399"
 0. 15951
                             _
                      1.C«>20'J
                      1.13551
                      1.21'-65_
                      l .26538
                      1.^.1202
                      I. SI 1S7
                      1.60184~
                      1.67441
                      1. '373b_
                      l.Vfc5}l
                      1.96631
                      2.C4590_
                      2. U3lb
                      2- 17760
                                                    2.31C6b
                      2.
                      2.'i06S4
                      2. 43397
                      2.45341"
                                                    2.5C070_
                                                    2.51912
                                                    2.55594
                                                    .2.58336_
                                                    2.63396
                                                    2.63312
                                                    2.65615_
                                                    2.67976
                                                    2.71048
                                                    _2-73974_
                                                    2. 768 10
                                                    2.79960
AVCOX
0.99741
O.S96H
O.S9481
0.^9350
O.S9?.19
o.^goss
0.^2956
0.98824 -} ..
0.c-8692 - . •
0.'-B360
O.«8025
0.17688
0.973 49 " ~
0.97007
C.';66A3
0.'/6316
0. )5967
0. -55615
0.-/5261
0.94904
0.94544
0. 34132
C.93S17
0.934^8
0.93077 ...:.
0.92326 : :':': :: "
•'•' 0.91563 ' •'•''- .
0.90786
O.fa9997
0.89192
C. 88374 •- : ;•
c. 87539 ;;• ;:; '•.-:•. :.:
C. 86639 • . :
0.85321
0.84936
0.63107
0.81195
0.79136"
AVCOY
0.2H32S
0.39112
0.53156
O.T3975
1.55562
i • d60 ^O
2. Hb03
2.29455
2.^3669
2.59760
2.62241
2.67322
~ 2.69950
2. 7263 1
2.^533?
2.78126
2.80973
2.83848
2.b5333
2.38334
2. b98^i
2.91364
2.V2933
2.94439
2.96C60
2.99288
3.02586
3.05923
3. 09371
3.1<-671
3.20157
3.25S37 :
3.31762
3.39936
3.46347
3.64703
3.52404
4.0794<»
TRACORX
-O.d077»
-0.01 169
-0.01561
-C. 01955
-0.02351
-0.02748
-0.03147
-0. 03548
-0.03950
-0.04962
-0.05934
-0.07018
-0.03062
-0. CO 117
-0. 10183
-0. 1 L261
-0. 12350
-0. 13452
-0.14565
-0. 15692
-0. 16H31
-0.17983
-0. 1V149
-0.20328
-0.21521 :
-0.23952 .'',-
-0.26443
-0.28998
-0.31620
-C. 34312
-0.37079
-0.39924 •••'':
-0.42853
-0.45o71
-0.48982
-0.55511
-0.62496
-0.70005
ruacoRv
I.T613J
O.s
-------
                Carbon  - C - 71  -  23
  i4~  ""
= 200.  DEO F
                                                  71
                           H20
                                    U._3
                                   ""z'.O
                                    10.0
                                 SU2  =  2500.PPM
                  CG-CENTKATICN  NO  «   150.0  PPK
                           H2S04 =   72.91
                           D LOADING =   0.38 GMS H2S04/GK  C
N>
VO
Xt' GKS H2S04/GM C
0.00292
O.CC437
C.OC5SJ
O.C-Q72T
0.00375
O.C1021
0.01 167
0.01312
0.01458
O.C1S23
O.C2187
C. 02552
C. 02916
0.03231
0.03645
0.04010
0-C4375
C. 04739
O.C5104
' 0.05463
•-: ' O.C5S33 -••••-•»-."
! 0.06197 : :'. ""/-:;
0.06562 ' .,. ' .
0.06926
0.07291
C.C8020
; • 0.06749 ,
: O.C9f73 . "•••;'..' . ;,.
0.10207 :'-":, :'•.-;
0.10936
0.11666
0.12395
0.13124 :
0.13353 • 'I
0.145S2
C. 16040
0.17498
P.ATE, GMS M2S04/GK C-MIN
0.00456
0.00329
C. 00156
O.OC129
0.00113
0.00103
0.00096
0.00092
0.00039 .-./.,;;..'
- . 0.00034 >';•-
; - O.OOC33. •••'•' •••-:'^:
0.00031
0.00030
O.OO079
-. '... '.' O.OC078
. -:/.:: >,.'-:4.,' .0.00078
. :. "i ,-0.00077
0.00076
0.00076
_ 0.00075 	
~T~- -; 0.00074 ;> .:<-.:'•*
•-•'..'. •:-.:. 0.00074 S.xi*'.§
''.;'". 0.00073 "•'•":;'•»
0.00073
0.00072
0.00071
-- ' • •• , 0.00070
:. .-.;:.-;,;. •'•'•:•'• ..0.00069
'..:,.:': : '•:... ••-• ..0.00068 	
0.00067
0.00066
0.00065
-v .- . ;. ••,..." O.C0064 •:-;.:>
:;;::'.-'; '•'": ....,,, o.ooo&2 	 :^''l
'">''' '•'•" " ' 0.00061'" "•'"'^;
0.00058
0. 00055
                                                                               -S. 3^201
                                                                               -6-6'U J4
                                                                               -6.760'.<
                                                                               -o.rtSSuli
                                                                               -6. 'VI 14'->
                                                                                7.04J9&
                                                                                V.U4 ?!(>
                                                                                7.U:>046
                                                                -'-,.75744
-6.
-6.
-6.

-0.
-6.
                                                               -6.924L3
                                                               -6.91134

                                                               -b.o»204
-6 . P':

-6.K24J5

-f .77i47

-6.7^505


-6. 50367

-6.51424
-b.'
-$.'
                                                                                        0.45/f>'1
0.35<> iO
0. 33/31
0. 13002
0.32P&5
0.32124
0. 31&<>7
0 v 3 1 39 5
i! . 3 1 1 0 3
0. 30.-. 12
C. 3C'>20
0.30. -12;)
0. 3CfoO
0.2V /C.S
0.29496
0.29351
0. 29069
0.26913
0.284/6
                                                                                        0.27 JC6
                                                                                        0. 26c'6 *
                                                                                        0.26-.-U
                                                                                        0 . 2 5 •' J 4 5
                                                                                        0.254 Jb
                                                                                                                       0.24 487
                                                                                                                       •....23/17
                                                                                                                       C.22. •>!
-------
RUN riUKbER » I'D 4
_.XP^iv = , CP.S H2SC4/GM C
C-COSOi
o.-vj^s*
	 . 0.0080 5
O.CU900
O.C1015
	 . _0.011 10
~c.ci2c-4
G. j!2T-<
O.C133?
0.01',75
O.C155C
0,01333 	
o . o 2 o o <3
0.^2176
	 0.02336
0.0*74.5
0 . 0 3 1 * <•
	 0 . ."> 3 5 3 4
'0.0391'.""
O.C4293
C.f)<-&73
0.05045
C. 05410
	 0.05732 	
0.06155
0-C&513
0.06370
O.C7243
0.07615
C.C7965
0.03316
0.09024
0-0?7i3
0.10397
C. 11061
C. 11719
C. 12347
0.12952
0.13536
0.14106
0.14683
0.15259
0.l5Ei4
0.16457 •;
0.170^9
0.17355
23 71
JOST
0.«9A22
0.75277
0. 033^5
l.iO'.3'f
1.2316'.
1-3^)173 |
I.'i5?92
i.-ji-?3<.
1. 62 165
I.f.^)'i95
1.«1823
1.00943
l.-*420V
2.U6S36
2. Ii038
2.27632"
2.3cS3JS
2.^759a
2.55505
2.62058
2.675.05
2.72527
2.77263
2.81021
2. 24319
2.8^834
2.91103
2.9J392
2.95452
2.7H164
3.00521 .,-
3.C«-741
3.08700
3.12591
3.16422
3.19998
3.23976
3.28123 :
3.32435
3.36739
3.40539
3.44052
3.47739 ;:
3. 49390 ,:';
3.51936 ."
3.54369
AVCtlX
O.V'<744
0 . '; •) & 1 S
o.'y;4tih
0.<; ;JS6
0.9"2^7
0.900 I*
ti.'H.'lk;
0.'/h!>3>
0.'J'J70'.
0.9^37-j
O.9bO'. J
0.977()-»
0.9737 .i
O.O/Oii
0.-i»-694
| O.TfrSbl
0. V6000
0.95657
0.9'.i30'S
0. 94953
C.0'.5')7
0.942J8
0.93077
0.9*512
0.031',^
0.924C2
0.91647
0.90S79
0.900-JS
O.S9JOJ
'J.CU494
O.h/670
0.fa662-J
0.35973
0.85099
\ 0,63294
I O.bl40s



  •WC'.IY
I'.S* ?:>•>
o. r i*Q-i i

i.•/ }'•'<•>
2 . 5'/ < '11
;'. /<•.-: 2 7
3. I'1521
3.21500

3.27653
3, JJ314
3. J245J
3.35705

3. 41) 70 d
3.4', 127
i , 4 < 0 o 3

3.5/1557
3.o234u
3.
3.n6'J2'J
3 . -! i 5 6 2
4.D2329
«... 10056
4. 30710
4.5349S
                   - 0.0 ' 11 H
-r,..',6:)5i
-o.o.'-;>'5


-0.11152
-0.12230


-O.IU5J7
-0.16664
-0. 1/504-
-0.18957
-0.2012*
-0.21 3,!3
-C.23706
-0.26692
-0.31252

-U.31671

-C.4X367
-0.45342
-0.4j;40d
-0.54837
-0.6170o
                       ;).'..il /••

                      -o.'.7-, n
                      -U . 6'»'/ a1,
                      -, 1 , / •) / -J ^
                      —' I . •". )-i f L-
                      -0. -•> U 7

                      -I .'J31 )•)


                      -1.1
                                            .l'.(2 7
                                            . 1 >f v?
                                            . I 'j 7 d -i
                                            .17727
                                           i. n;&7o
                                           i. nc-jy
                                          -1./-U'
                                           1.2'V'Jb7
                                           1.21612
                                           1 .
                                           1.2 >H05
                                           1.31420
                                           1. 33062-
                                           1.3->30:>
                                           1.37S12
                                           1. 3^334
                                           1.41 112
                                           1.4-^027
                                           1.51182
-------
Car-bra  C - 71 - 23
                               71
TEv.PERATURc » 200. OEG F
TOTAL FLOW  RATE = icoo.o CC/MI.N
         cri2  =_
        ~ '02'*=
Pb^CENT  M2C  =
_
  2.0
 10.0
CG^CfcMTRATIO'l S02 = 1500.0  PPM
CONCENTRATION  NO =  130.0  PPM
3fcRCc'.T  H2S04 =  74.
SAIuKATED  LOAOING =
                     01
       0.3B GHS H2S04/GM  C
X, GKS H2SIA/GM C
0.001«3
0.00296
0.00444
0.00592
O.C0740
O.OCS83
0.01036
0.01184
O.C1332
0. 01*60
0.01850
0.02220 .
0.02590
0.02960
0.03330
0.03700
O.G4071
0.04441
0.04811
O.C5181
: , 0.05551 ;:.
0.0592!
0.06291
0.06661
0.07031
0.07401
0.03141
0.08881
0.09621
0.10361
0. 11101
0. 11842
0.12582
: 0.13322
0.14062
0. 14802
0.16282
0. 17762
0.19243
P.ftTS, GKS H2S04/GM C-H1N
0.00512
0.00422
0.00232 .. : •: . •....
C. 00114 . ... I/....:.
o. 00094 . > .';••:. ';••'-
C.OOOS4
O.OC073
0.00075
0.00074
0.00073
0.00072
0.00071
0.00070
0.00070
0.00063
- . '..' 0.00068
. 0.00067
O.C0066
0-00066
0.00065
.:: . - • 6.00064
••'•'•'. . . 0.00064.
0.00063
C.OC063
0.00062
0.00061
• ; . . . . C.OC060
0.00059
*1'-', ^: . O.C0058
0.00057
0.00055
0.00053
0.00052 ; :'.: .-' :'
• :.:'V.;--- ?JUVC" • 0.00050 •-::^-^:^i
"•". " 0.00043..' "?;::••".
0-OOC46
0.00042
0.00039
	 " -' 0.00034
                                                                     weSTVACO
                                                                     -5.27107
                                                                     -5.46018
                                                                     -6.C5457~
                                                                     -6.75975
                                                                     -6.95501
                                                                     -7.C6339"
                                                                     -7.12310
                                                                     -7.16223
                                                                     -"7.17805"
                                                                     -7.18020
                                                                     -7. ia4Q2_
                                                                    ""-?. Id913
                                                                     -7.18921
                                                                     -7. 10917_
                                                                    "->. 1945J
                                                                     -7.19466
                                                                     _-7.19469__
                                                                     -7.19483
                                                                     -7.19486
                                                                     -7.19300
                                                                     -7.18939"
                                                                     -7.18357
                                                                     r7.'lS358
                                                                    '-7.18348"
                                                                     -7.17753
                                                                     r7. 17747_
                                                                     -7. 17'l"09
                                                                     -7. 16442
                                                                     -7.15745_
                                                                     -7. 15667
                                                                     -7.15584
                                                                     r.7..16.187_
                                                                     -7.16114
                                                                     -7.16774
                                                                     -7.17478
                                                                     -7.18217"
                                                                     -7.20771
  MODWESTVACO
     -5.26717
 	-5_.452J5_
     -6.0~423~1
     -6.74404
    _-6.93535
     -7.03974'
     -7.C9545
 	-7.13062
     -7.~i42.V7"
     -7.1-4947
 	 -7.13411
    "-7. 12893"
     -7.11861
 	-7.1CS07

     -7.CV221
 __	-7.03139
     -'7.07056 '
     -7.C5950
 	^7.04843
     -7V63143""
     -7.01419
     -6.99076
     -6.97293
_^	-6.96085
    "-V.92998"
     -6.89322
     -6.86550
     -6."83»2"9~
     -6.61032
     -6.7 B 84 5_
     -6.75903
     -6.73607

     -6.6S365
     -6.64326
     -6.59796
                                                                                                  AMUNUSON
                                                                                                 " 3.41206
                                                                                                  2.U1312
                                                                                                  I. 54646
                                                                                                 ~b.7o097
                                                                                                  0.62351
                                                                                                  0.55725
                                                                                                  0.52286
                                                                                                  0.50075
                                                                                                  0.49093
                                                                                                  0.48J53
                                                                                                 0.47376
                                                                                                 0.46B8J
                                                                                                 0.46394
                                                                                                 0.45659
                                                                                                ~
                                                                                                 0.44677
                                                                                                 0.44184
                                                                                                 0.43696
                                                                                                 0.43202
                                                                                                  _
                                                                                                0.42714
                                                                                                0.42220
                                                                                                0.40992
                                                                                                0 .4025 7 _
                                                                                                0.39V2I
                                                                                                0. 38786
                                                                                                P-.3J804 __
                                                                                                C.3~6t>22
                                                                                                0.35594
                                                                                                Q. 3.1 6 1.2 _
                                                                                                0.33383
                                                                                                0.32155
                                                                                               .P.. 30931 __
                                                                                                0.28227
                                                                                                0.25775
-------
                 RIP! NU
                                141
                                          4 26 71
                       0.00449
                       0.00619
                       U. 00722
                       O.OObOj"
                       O.CCS34
                       C.CC956
                       O.C1G2*
                       0.01093
                       O.C1171
   JOST_
6.33390
0. 45487
0.62362
C.'7471V"
CO
                        0.01 392
                        0.0153^
                        O.C16S7
 0.02342
 0.02703
 C.03063
 0.03402
 0.03726
 0.04J51_
"d.04367
 0.04676
 0.04993
 '0.05392
 0.05597
 0.05699__
"0.06201
  .06510
  .0/.312
  .07114
  .07703
  .Cc<285_
  .03S59
  ,09426
  .09979
  .10560
  .11120
  .11643.
 C" .'12188
 C.12710
 0.13219
""O.:13719
 0.14223
_0.14728_
 6715207
 0.15663
 C-16I05
"0.16532"
 0.16945
 i'Vu 2 533
 1.09333
 1 .15302
 l'. 2 04 9 7
 I.RT29S
 1.3f>4'6
       "
                                             1.47222
                        0.
                        C.
                        0.
                        0.
                        O.
                        0.
                        0.
                        0.
                        0.
                        0.
                        0.
                         "
 I .60142
 1 .66491
 1.71385
 1.76354"
 1.61140
_1 . 65 1.5V
 1~.V:J9"34
 1.92A74
 1.95285
 l.Vb036
 2. C 1C 14
 2.03_433_
 2.05626
 2.07376
 2.09193
 2.L3B57
 2. 14203
 2. 17269
 2.20115
 2.22790
 2.25479
 2.27262
 2-29316
                                             2.33337
                                             2.36026
                                             2.38295
                                             "2.40538
                                             2.42465
                                             2^444 3 3
                                             2.46600
                                             2.48987
                                             2-51i70
                                                  "
AVCOX
0.99870
0.99740
0.9V609
0.9947!',
>,. 0.99347
0.99Z15
0.-90083
0.90950
• 0.98B1 r .
0.98684
0.93350
0.98013
0.97674
0.97333
0.96989
0.96642
0.96294
0.95942
0.9558B
0.95232
0.94873
0.94510
0.94146
0.93773
0.93407
•• 0.93034 : ; ' .
0.9227H :: :
0.91509
0.90727
0.89931
0.8912;. . '
0.88296 . ;.:i, -
.0.87456 ,~ ;;:::,; :..
0.86598
0.85724
0.84831
0.82987 .-.'-, :•,
o.8io57 •'• ::
. -.0. 7903). : ':O:-
4VCOY
0.2930B
0.35548
0.64&64
1-31411
1.60382
1. 794 54
. 1.91257
1.99700
2.03694
2.06011
2.07851
2.11076
2.13297
2.15543
2.19014
2.21406
2.238Z7
2.26326
2.^dS56
2.31470
2.32799.
2.34117
2.36853
2.39625
2.41051
2.43952
2.4«<-07
2.5302S
2.57824
2.64520
2.71573
2.B0947
2.8S917
2.99550
3.10995
3.23298
3.54266
• 3- £7? 70
4.3SC27 :
                                             2.5670!>
                        cYi7696
                        0.18057
                        0.16389
                        0. 16742
  2.62774
  2.65325
  2.691 90_
  2V72122
  2.75043
  2.731II_
TR4CORX
-0.00390
-0.00732
-0.01175
-0.01570
-0.01967
-0.02365
-0.02765
-0.03166
-0.03069
-0.03973
-0.04992
-0.06021
-0.07060
-0.08111
-O.C9172
-0. 10246
-0. 11330
-0.12427
-0-13536
-0. 14657
-0.15791
-0. 16938
-0. 18098
-0. 19272
-0.20460
-0.21662 :
-0.24110
-0.26620
-0.29195
	 -0.31837 	
-0.34552
-0.37342 . ::.y'::
1 	 ^0.40212 	 ..;..,..,.
-0.43167
-0.46211
-0.49352
-6.55945. ' ::.;v
-0.63004 .;.;-.. :- .,.
( -0.70600 : .

TSACURY
l.iT273l
1.03429
0.'-3597
-0.27316
-0.47239
-U. 58475
-0.648<-5
-0.69165
-0.71 145
-0.72664
-0.73165
-0.74705
-0.75752
-0.76799
-0.7S i96
-0.79483
-0.30570
-O.S1681
-O.B27V3
-O.i',3928
-0.64501
-O.t5065
-0.66227
-0.67391
-O.U7934
-O.b9lo0
-0.90990
-0.92333
-0.94711
-0.97275
-0.99906
-1.03300
-1.06097
-1.C57U
-1.1346:.
-1.17343
-1.26488
-1.35576
-1-47711

                         0. 19596
-------
                Carbon- C - 71 -  23
                     NUM9E'R'«~  142  	4 27~7l	
                 TEr-PERATUKE =  200.  OtG F

                 TOTAL  FUGw RATC"~= "i~aQ0.6~ CC/MTN
               ..PfcB,CENr_CLi2 =	11.3_
                Pt^CENr   02 '-'  "2/0
                PLD,CEMT  H2U =   10.0

                CC\c E'l r p.Tr i ON" sof" *~ iTJoo". O~"PPM"
                CCNCENTRATION  NC =   150.0 PPM
                PERCENT  H2S04 =""71.88"               	"
                       TED LOADING =    0.38 (JHS H2S04/GM  C
U>
u>
X, G."!S H2SC4/GM C RATE,
0.00144
0.00238
0.00431
C.OC575
0-U'J719
O.CQ863
0.01006
	 0.01150
0 . U 1 2 9 '•
0.01433
	 0 . 0 1 7 J 7
C. 02156
0.02516
O.C2375
0.03235
0.035V4
0.03953
0.04313
0.04672
' 0.05032
0.05391 r- """' ' "
0.05750
O.C6110
C.D6469
0.06S29
O.C7133
0.07907
0.06626
0.09344
0.10063
0. 10782
0.11501
0.12220
0.12933
0.13657
0.14376
0.15814
0.17251
&>.S H2SC4/GI'. C-MIN
0.005C4
C. 00363
0-00214
O.OOC96 '" ' ri.'.V.
O.OOCB3 -::':""~
0.00076
0.00071
0.00067
0.00066 •. .: •;
C. 0006 5 •' •-'•: -:>'<,•
O.OC064 -,;:. .,;.".
0.00063
0.0.0062
C. 00052
O.OOC61
0.00060
0.00059
0.00059
0.00058
0.00058
0.00057 .. .. ..':,; '-:'•-.
O.OQC56 ''"f;,':-;5vy::::;
0.00056 -:-:i-:-::'-.
0.00055
0.00054
0.00054
0.00353 r : "
.: 0.00052 .-;.S;::M
0.00051 -': •'/;• " '
0.00050
0.00049
0.00047
0.00046 ,••:.: •••- w -
0.00045 :: ^:>:r -:;;
O.Cf,043 '"• •""•"•"•'
O.COC42
0.00039
0.00035
H6STVACO
-5.28716
-5.59679
-6. 13647
-6.92926
-7.070R4
-7.16276"
•••••-• -7.22813
-7.27152
-7.29485
-7.29653
-7.303'.'.
.. ' -7.30484
-7.31203
-7.31357
-7.31514
-7.31662
-7.31826
-7.3199V
-7.32166
••"... -7.31704
-.7.31876
-7.32052
-7.31573
-7.31749
.'•'•. -7.31929
.•;:; '.:"• -7.31433
-7.31117
-7.30772
-7.30411
-7.30034
',;•- -7.29652
-7.29237
-7.28SOO
-7.29152
-7.29510
-7.2V909
-7.30771
	 __ -7.317.81,
MOO«ESTVACO~"
-5.23337
-5.50919
-fa. 12506
-6.91402
-7.C5175
-7.13930
-7.20129
-7.24079
-7.2t
-------
                          RU\ r.UKS
                                         142
                                                    4 27 VI
OJ
XPRIME, nvS H2SQ4/GM C
0.004^.9
0.00551
0. 00652
0.00 O2
o. tea 19
0.00',J06
C. 00973
0.01051
0.01123
C. 01189
0.01312
0.01^35
0.01566
C.C1696
O.Ciy26
0.0213o
0.02450
0.02754
0.03073
0.03377
0.03667
0.03957
C.C4247
0.0'.537
0.04320
C. 05109
0.05370
0.05531
C. 05906
0.06167
O.C6435
O.C6950
0.07501
0.08059
O.OS61C
O.C9146
0.096? 7
0.10211
0.10726
0.11243
0. 1174S
0. 12241
0.12719
0.13161
0. 13633
0.14089
0.14531
0. 14959
' 	 0.15394 ~ . , ." -
0.15814
0.16205
0.16575
0.16640
JCST
0.22259
0.36324
0.4',016
0.54664
o . fc ; o 7 1
O.S6243
0.71554
C -7A126
O.t'JlOo
0.84112
0-91477
O.°7560
1.02201
1.0^154
1.C-J501
1. Ift9^7
1.22465
1-27101
1.. 301 71
1.33257 ;
1.36339
1.36994
1.412S7
1.4326^
1.'.5242
1.46793 ,::/-':
1.4S971 -•".
1.50948
1.52373
1.54036
1.57390 •;;••
1.58272 . .
1-59970
1.61307
1.62606
i. 64006
1.65251 .•:
1.66483
1.67813 ._
1.66922
1.70241
1.71552
1.72967 --..•••.••
i.74756 :.:,;••:':
1.76C46 ....
1.77441
1.76925
1.60494
1.81891 ,. ,,.
1.S3366 '-i
1.E5124
1.S7031
1.37497
| /VCOX
I6.TVU74
0.^9747
, 0.r.V620
j 0.<:9',93
0. '.9.165
0 . T 9 2 3 S
0.99109
o.?8?si ; .-.; ;
0-?bH52 -'':'
0.98723
0.98398
0.98071
0.97743
0. 97M1
0.^7073 • •.-.
0.96742
0. '76 404
0.96064
O.S5721 .. ' . ..
C. 953 76 ..: '• : • •'•
j 0.95023 : . -
|! 0.9-'i678
?S C. 94325
0.93969
0.93610
0.93249
0.92518
0.91776
0.91021
0.93254
O.B9473 , :..
. 0.83678 : ., ..;.:.• ;
0.67S69 .-•• ';"";- •--.' '':.
0.67045
0.85204
0.85347
0.8*580
,0.81734
;'" .
AVCUY |
0.1 ,'853 |
0.27161 !
0.4c>773
l.'037ii
1.H963
1.32043
1.41512
1.48364
1.324&1
1.5331S j
1.S5912
1.57697
I.tj-4i4
1.62335 !
1. 6^-270
1.66233
1.68264
1.71345
1.7247d
1.75554
1 . 757S8
1.7B040
1. 7V 187
1.S1549 \
l.y'3973 ' 1
I.SS198 j
l.«"023 , [
1.92982 |
1-97111 I
2.01^20 S
2.Ci?5i ||
2.10661 . I
2.15591 1
2.22558
2.29951
2.37895
2.55502
Z.75979 ^; |
TRACORX
"-O.CC37-7
-0.00760
-0.01141
-0.01523
-C.OIOIO
-0.02296
-C.026S4
-O.U307J
-O.U3464
-U,C3b5?
-0.0^^44
-0.03342
-0.06850
-0.07868 --
-O.CR096
-0.0-3936
-0. 10986
-0. 12047
-C. 1311'/"
-0. 14204
-0.15300
-0. 164C3
-0. 17529
-0. 18662
-0. 1930S
-0.20968 ••. .'..
-0.23329
-0.25746
-0.23224
-0.30764
-0.33371
-0.36047 . -•:.....: -.,.
-0.38797
-0.41625
-0.44535
-0.47532
-0.53811
-0.60510
TRAC01Y
1 . H 6 8 1
1. Vj337
0. T59J7
-IJ.U36/6
-O.I. "..'18
-0.27/96
-0. .14722
-0.3)450
-0.42174
-C.'.2M4
.. -0.44412
-0.45551
-O.'f /2f f
-0.4644^
-O.f<634
-C.&0322
-0.52036
-0.53266
-0.54510"
-0.55132
-0.56400
-0.576S4
-0.56326
-0.59635
-0.60962
-0.61626
-0.63670
-0.65743
-0.67860
-0.70022
-0.72247
-0.74508
-0.76821
-0.30002
-0.83270
-0.86666
-0.93SC6
-1.01515

-------
                   Carbon- C - 71 -  23
                     1U?1 M!ft»ea=   143'      4 28 71
                     TE.-'PErt.-.TURE =  200.  DEG F
                           FLCU RATE =  1000.0 CC/MIN
 Pf'.CENT C02  =
"ptHCENT  C2  =
 PfcRCENT H20  =
                                      11.3
                                       2.6"
                                      10.0
                    CC-;CE\T3AUON S02
                    CUNCE.'JT«AT;ON  NO
                       500.0 PPK
                       150.0 P?;I
                     PERCENT H2STV »   72.45
                     SATURATED LOAOlMG  =    0.33 GN'S H2S04/GM  C
Ul
X, r.l'S ii2StJ4/GK C RATE,
0.00145
O.C0290
O.OOA35
O.C0530
0.0072^
0.00869
O.C10U
O.OH;.'?
O.C130'.
O.C1A49
O.CiSil
0.02173
C. 02536
0.02893
C. 03269
0.03623
0.03935 : .. • .
0.043
-------
CO
                                     O.CJ32',
                                     O.C-/4'./
                                     'J. 0'. ii'j
                                      0 . C 0 'i '! 7
                                      O.C1195
                                      O.C13^'<-
                                      O.C14C6
                                      0 . 0 i 5 'J 'J
                                      0.01 739
                                      0.01963
                                      0.02195
                                      C. 02^-2 6
                                      0.02651
0.0307D
O.OJ26"
0.03506
C.C.-370J
0.03912
0.04iCO
0.04317
O.C4527
0.04 73d
0.04933
C. 05 324
0.05715
0.06099
0. 064o3
0.0686D
0.07251
0.07664
0.06055
O.CE'53
  CB
                                     a. | ...-,•,.
                                     'j . i f> 3 7 1>
                                                           0.3 :
                                                           0.4>3/o
                     0.<-'-U49
                     0.50745
                     0.55210
                     0.54557
                     O.ol345
                     0.04033
                     0.66679
                     0.7L3B9'
                     U.7o426
                     0.79744
O.S/160
O.AV312
  912'27
  V2702
  94372
  95H69
  v/562
  96441
  99395
1.00264
1.01356
1.03299
1. 04990
1.C6578 "
1.07977
1. 09-336
1.10333
1. 10912
  11732
  12380
  13062
  137o5
  14614
  15130
  15850
  16442
  L6918
1.17362
1.1784'J
l.ld'3/6
1.1 5140
1.20286
1.21169
1.22141
1.23070
1.23895
1 .24999
HUN NUMOtR =






































AVCUX
0 . fi 9 <3 7 3
0.99745
0.99617
0..99489
0.99360
0.99231
0.99102
0.9d97 1
0.9ciB4.i
0.98712
0.983B5
0.98056
0.97724
0.97390
0. V 7O54
0.16716
0.96375
0.96031
0.95686
0.95337
0.94986.
0.94633
0.94277
0.93918
0.93556
O. 93192
0.92454
0.91705
0.90943
0.9016b
0.89379
0.8S576
..O.H7759
0.66926
C.S6076
O.S5210
O.fc3422
1*3 4 28 71
A'/CCY
0. 1<.{J44
C . 2 j 1 6 5
0.4/605
0.00022
0.71531
0 . (-. I 2 I 1
0. '•••)& 5 1
0. J'.>ti^5
1 . '••) 764
1.03795
1.05380
1 . U / h-j 0
1.0J562
I. 13439
1.12235
1.14090
1-. 15041
l.lf.008
1. 1 /991
1. 1-^009
1.20044
1.2109/
1.22169
1.23260
1.24370
I.2o501
	 	 1.26653
1.29021
1.31479
1.34032
1. 36637
1.31449
. 	 _ 1.43307
1.46866
1.50061
1.55120
1.6633/
TRACCRX
-0.003112
-O.OC7t>6
-O.U1151
-0.01537
-0.01925
-0.02314
-O.C2705
-0.03098
-C.03'»l>2
-0.03C33
-0.0223
0-r>1046
0.33504
0.20012
0. 10925
0. 04223
-O.OJ761
-O.U3724
-0.05240
'' -0.07557
-0.0)132
-0.09929
-0.11542
-0.13102
-0. 14012
__ -0.14849
-O.i6544~
-0. 1740J
-0. 18269
-0. IV 142
-0.2002J
-0.20912
-0.21809
-0.22714
-0.23626
-0.2:>480
-0.27367
-0.29291
-0.31252
-0.33253
-0.3633O
-O.i8436
-0.40587
	 -0.43903 	
-0. 50884 ~
                      1.25VU5
                      1.26564
I ..
1.
                        • / 710
                         .". 5 9 O
-------
    CARBON C - 71 -23
r
c
c
f
    RUM NUnJEK  =   144 - 6    4 29 71
    TEMPERATURE =  200.  DFT, F

    TOTAL FLOW  RATE  =  1000.0 CC/MIN
PERCENT  C02 =   11.3
PERCENT   02 =    3.5
PERCENT  H20 =   10.0

CINCFMTRATIOU SU2 =
CONCENTRATION  NO =
2000.0 PPt-i
 150.0 PPM
PERCENT  II2S04  =   73.31
SATURATED LOADING =   0.38
       CMS H2S04/GM C
    X,  CMS  H2SD4/GM
           0.00293
           0.00440
           0.00586
           0.00733
           0.00880
           0.01026
           0.01173
           0.01320
           0.01466
           0.01833
           0.02199
           0.02566
           0.02932
           0.03299
           0.03665
           0.04032
           0.04399
           0.04765
           0.05132
           0.05498
           0.05865
           0.06231
           0.06598
           0.06964
           0.07331
           0. OP,064
           O.CH797
           0.09530
           0. 10263
           0. 10906.
           0.11730
           0. 12465
           0.13196
           0.13929
           0.14662
           0.16120
           0.17594
           0.19061
           0.20527
                        RATtt GPS
              H2SD4/GM C-MIM
                 0.00')3'j
                 0.00375
                 0.00253
                 0.00155
                 0.00143
                 0.00136
                 0.00 130
                 0.00125
                 0.00120
                 0.00114
                 0.001)0
                 0.00108
                 0.00107
                 0.00106
                 0.00105
                 0.00105
                 0.00104
                 0.00103
                 0.00103
                 0.00102
                 0.00102
                 0.00101
                 0.00101
                 0.00100
                 0.00100
                 0.00009
                 0.00098
                 0.00098
                 0.000-J7
                 C.00095
                 0.00094
                 0.00092
                 0.001)90
                 O.OOOH3
                 0.00085
                 o.oooai
                 0.00076
                 0.00071
                 0.00065
                                                           WESTVACO
                                                           -5.22311
                                                           -5.57390
                                                           -5.96561
                                                           -6.45310
                                                           -6.529)8
                                                           -6.5/599
                                                           -6.61390
                                                           -6.64786
                                                           -6.68315
                                                           -6.73022
                                                           -6.75328
                                                           -6.76000
                                                           -6.75996
                                                           -6.75647
                                                           -6,75285
                                                           -6.74930
                                                           -6.74547
                                                           -6.74165
                                                           -6.73775
                                                           -6.73019
                                                           -6.72252
                                                          -6.71465
                                                          -6.71045
                                                          -6.70235
                                                          -6.69421
                                                          -6.67745
                                                          -6.66023
                                                          -6.64235
                                                          -6.62774
                                                            .61648
                                                            .60074
                                                            ,59237
                                                            .58774
                                                            ,58284
                                                          -6.57766
                                                          -6.57099
                                                          -6.56341
                                                          -6.55990
                                                          -6.55583
-6.
-6.
-6.
-6.
-6.
                                       37
-------
     CAKfiON C - 71 - 23
     RUN NUMBER =   145  - G    A  30  71
     TEMPERATURE =  200.  DEC  F.

     TOTAL FLOW RATE  =  1000.0 CC/MIN

     PERCENT  C02 =    0.0             	
     PERCENT   U2 =    2.0
     PERCENT  H20 =    10.0

     CONCENTRATION  S02  =  2000.0 PPM
     CONCENTRATION   NO  *   150.0 PPM

     PERCENT  H2S04  =  72.61
     SATURATED LOADING  =   0.38 CMS H2S04/GM  C
r
X, CMS H2S04/GM C
       0.00290
       0.00436
       0.00581
       0.00726
       0.00871
       0.01017
       0.01162
       0.01307
       0.01452
       0.01815
       0.02178
       0.02541
       O.Q2-904
      - 0.03267
       Q.03630
       0.03994
       0.04357
       0.04720
       0..05083
       0.05446
       0.05809
       0.06172
       0.06535
       0.06898
       0.07261
       0.07987
       0.08715
       0.09439
       0.10165
       0.10891
       0.11618
       0.12344
       0.13070
       0.13796
       0.14522
       0.15974
       0.17426
 RATE, CMS H2S04/GM C-MIN
             0.00648
             0.00-315
             0.00378
             0.00266
             0.00148
             0.00107
             0.00102
             0.00099
             0.00097
             0.00093
             0.00090
             0.00088
             O.OOOB6
             0.00085
             0.00083
             0.00082
 	...0.00081 _	
             0.00080
             0.00079
             0.00078   	
             0.00078
             O.Q0077
            .. 0.00076
             0.00076
             0.00075
             0.00074
             0.00073
             0.00071
....	      0.00070  ...
             0.00068
             0.00066
             0.00064
             0.00062
            ' 0.00060
         	 0.00058
             0.00054
             0.00049
WESTVACO
-5.03189
-5.25814
-5.56315
-5.90916
-6.49575
-6.81763
-6.85510
-6.87969
-6.89768
-6.92936
-6.95062
 /  O f f t f\
 O » t »_» -t O. w
-6.97495
-6.98562
-6.99227
-6.99475
-6.99720
-6.99980
-6.99788
-6.99591
-6.99390
-6.99185
-6.98985
-6.98771
-6.98069
-6.97128
-6.96638
-6.96125
-6.95599
-6.96094
-6.95527
-6.96048
-6.96029
-6.96599
-6.97220
-6.98572
-7.00892
                                       38
-------
CAHUON C - 71 -23

RUN NUI-'HCR  =   140 -=• G    5
TEMPLRAIUKE =  150. DEG  F
                                 7  71
     TOTAL FLOW RATE = 1000.0 CC/HIN
(

C
PERCENT C02 = 11.3 ........ j
PERCENT . 02 = 2.0
PERCENT H20 = 10.0
CONCENTRATION S02 = 2500.0
CONCENTRATION NO = 150.0
PERCENT H2S04 - 57.18
SATURATED LOADING = 0.38
X, GMS H2S04/GM C RAT
0.00229
0.00343
0.00457
0.00572
0.00686
0.00801
0.00915
0.01029
0.01144
0.01429
0.01715
0.02001
0.02287
0.02573
n.O?R59
0.03145
" 0.03431 . . 	
0.03717
0.04003
0.04288
0.04574
0.04860
0.05146
0.054-52
0.05718
0.06290
0.06862
0.0743 1
0.00005
0.08577
0.09149 -:
\
0.09721 	
0.10292
0. 10864
0. 11436
0. 12580
0. 11723
0.14067
0. 16010
0. 17154
0.18290 ._... .
0. 19441
0.20585
0.21728 .. ..



PPM
PPM

GMS H2S04/GM C
Et -GMS H2SU4/GX C-MIN
0.0? 170
0.02000
0.01C44
0.01705
0.01572
0.01447
0.01331
0.01??. 4
0.01122
O.OOB75
0.00671
0.00513
0.00416
0.00380
0.00351
0.00326
	 	 __;.'. 0.00303 	
0.00283
0.00269
	 	 . 0.00257 	 	
0.00248
0.00238
0.00230
0.00?23
0.002L6
0.00203
0.00191
0.001BO
0,. 00 169
0. 00160
0.00151

0.00142
0.00133
0.00125
O.fJOll?
0.00102
0.00089
0.00078
0.00068
0.00059
0.00052
0.00044
0.00037
. ....... ..;.. 0.0003 I.
                                                           WESTVACO
                                                           -3.82459
                                                           -3.90312
                                                           -3.93119
                                                           -4.05639
                                                           -4. 1 346?
                                                           -4.21415
                                                           -4.294 71
                                                           -4. 3/59?.
                                                           -4.459 04
                                                           -4.70013
                                                           -4.95756
                                                           -5.21921
                                                           -5.41930
                                                           -5.50237
                                                           -5.57331
                                                           -->,64U4H
                                                             ,70435
                                                              76372
                                                             .80662
                                                             .84341
                                                             .87305
                                                             ,90176
                                                          -5.92937
                                                          -5.95318
                                                          -5.97538
-5,
-5«
-5,
-5,
-5.
-5.
                                                                 .01697
                                                                 .06203
                                                                 ,10466
                                                                 , 14423
                                                                 .18355
                                                                 .22233
                                                                 .26035
                                                                 .30579
                                                                 ,35135
                                                                 ,39535
                                                                 .40620
                                                                 .57693
                                                                 ,66498
                                                                 .74676
                                                                 .82689
                                                              -6.91357
                                                              -7.02084
                                                              -7.12669
                                                              -7.24405
                                                          -6,
                                                          -6,
                                                          -6.
                                                          -6.
                                                          -6.
                                                          -6,
                                                          -6.
                                                          -6.
                                                          -6,
                                                          -6.
                                                          -6.
                                                          -6,
                                                          -6,
                                                          -6.
                                                          -6,
                                      39
-------
CARBON C  71 - J>3
RUN NUKKI:R  =
TLMPLKATIMC  -
149 _ G
150. DEG
    5 10 71
TOTAL  PLOW  RATE  =  1000.0 CC/MIN
PEI'CLNI  C02  =
PERCENT   02  =
       T  H20  -
CONCENTRATION
CONCENTRATION
  11.3
   2.0
  10.0

502 =
 NO =
1500.0
 150.0
                                 PPM
                                 PPM
C

C
PERCENT  H2S04  =   56.66
SATURATED  LOADING =   0.38 CMS H2S04/GM C
    CMS
H2S04/GM
0.00569
  C0682
  00796
  00910
  0102 5
  0113/
  0142 I
  01706
  01990
  02274
  02559
  02843
0.03127
0.03412
  0 -)ty:jo
  03980
  04264
  04549
  04833
  05117
  05402
  05686
  06255 ..
  06023
  07392
  07960
  09529
  09098
  09666
  10235
  10 « 0 J
  11372
  12509
  13646
  14784
  15921
  17058
  1819S
  19332
          RATE,
        0,
        0.
        0.
        0.
        0.
        0,
        0,
        0,
        0.
        0.
        0.
CMS H2S04/GM C-MIN
       0. 0 l'i 1 I
       0.013/1
       0.01241
        .01122
        .01020
        .00925
        .00712
        .00548
        .00424
        ,00348
        .00291
        ,00259
        ,00220
        ,00202
        .00190
        .00182
        ,001.76
        ,00171
        ,00168
        .00164 	_
        .00161
        ,00158
        ,00152
        ,00146
        .00140
        .00135
        ,00131
        .00125
        ,00120
        .00114
        ,00109
        ,00103
        ,00091
        ,pO()79
        .00068
        .00058
        ,00049
        ,00040
                       0.
                       0.
                       0,
                       0.
                       0.
                       0.
                       0,
                       0.
                       0,
                       0.
                       P-
                       C.
                       0.
                       p.
                       0.
                       0.
                       .0.
                       0.
                       0.
                       0.
                       0.
                       C).
                       0.
                       0.
                       0.
                       0.
                       0,
                       0.
                       0.
                       0.
                       0.
                       0.
                       C.
                       0.
                       0.
                       C.
                                       WKSTVACO
                                       -4.17746
                                       -4.27187
                                       -4.36807
                                       -4.4655r>
                                       -4. 1^827
                                       -4.6'i23f)
                                       -4.90639
                                       -5.16134
                                       -5.41044
                                       -5.59894
                                       -5.76863
                                       -5.87837
                                       -6.03522
                                           10890
                                           16141
                                           19770
                                          22552
                                          24193
                                          25409
                                          26661
                                          2/781
                                          28935
                                          31173
                                          33356
                                          35289
                                                            -6.
                                                            -6.
                                                            -6,
                                                            ~~O i
                                                            -6.
                                                            -6,
                                                            -6.
                                                            -6.
                                                            -6.
                                                            -6.
                                                            -6.
                                                            -6.
                                                            -6.3713.8
                                                            -6.
                                                            -6,
                                                            -6,
                                                            -6,
                                                            -6,
                                                            -6,
                                                            -6.
                                        00033
       0.20470
                       0.00028
                                         .30677
                                         .40949
                                         .43368
                                         .45950
                                         .48964
                                         .52466
                                         .60669
                                       -6.70137
                                       -6.80490
                                       -6.91410
                                       -7.03421
                                       -7.16077
                                       -7.29206
                                       -7.41469
                                  40
-------
c
c
c
c
c
c
c.
    CARBON C  - 71  - 23

    RUN  NUMBER  =   150 - G    5 11 71
    TEMPERATURE =  150.  DEC F
    TOTAL PLOW  RATE  = 1000.0 CC/MIM
PERCENT CU2 =   11.3
PERCENT  02 =    2.0
PERCENT H20 =   10.0
CONCENTRATION S02 =  500.0 PPM
COMCEiURAI ION  NO =  15C.O PPM
PERCENT II2S04 =  53.33
SATURATED LOADING =   0.38 CMS  H2S04/GM  C
   CMS
H2S04/GM C
0.00427
0.00534
0.00640
0.00747
0.00051
0.00960
0.01067
0.01333
0.01600
0.01867
0.02133
0.02400
0.02666
0.02933
n, n.\?oo
0.03466
0.03733
0.04000
0.04266
0.04533
0.04800
0.05066
0.05333
0.05866
O.OC.400
0.06933
0.07466
0.07999
0.00533
0.09066
0.09599 ..v
0.10133
0.10666
0.11733
0. 12799
0. 13866
0.14932
0. 1 5999
0. 17066
0. Hi 132
RATE, CMS H2SG4/GM C-MIN
0.01620
0.01322
0.01123
0.00956
0.00815
0.00694
0.00591
0.00394
0.00268
0.00187
0.00146
0.00121
0.00112
0.00104
0.001.0]
0.00100
0.00098
0.00098
0.00097
0.00096
0.00095
0.00094
0.00093
0.00091
0.00090
O.OOOH7
0.00085
0.00083
0.00081
0.00078
0.00076
0.00074
0.00072
0.00067
0.0*0062
0.00056
0.00049
0.00042
0.00034
0.00026
WE3TVACO
-4. Ill 34
-4.31159
-4.47216
-4.62934
-4. 78685
-4. 94486
-5. 10.142
-5.50164
-5.&UO/6
-6.23278
-6.46898
-6.65079
-6.72350
-6.78601
-6.60707
-6.81275
-6.82027
-6.81757
-6.82009
-6.82261
-6.82518
-6.82513
-6.62776
-6.83325
-6.83043
-6.64194
-6. 85099
-6.81)736
-6.86407
-6.87 744
-6.88821
-6.89606
-6.91 140
-6. 94459
-6.98196
-7.04219
-7. 11253
-7.23136
-7.3B840
-7.59702
                                       41
-------
     CARBOii C - 71 - 23

     RU', raJ,'mi:R  =   131-G    51271
     UM'r'LKAIURE  = 300. DEC F
C
c;
c
r
TOTAL I:LUU  RATE  - 1000.0 CC/MIN

IMiKCEiJT Cu2  =    1.1.3
1'hRU.NT   02  =     2.0
I'tf'.CLIil H2C  =    10.0
Ct/MLtKTRM I(J-\I  Su2 -
GU.-iCEuTRATlUN   NO =
                     2 '300.0 I'PI"
                      150.0 PPM
      T II2SU4  =   81.86
SATURATED  LOAIJI.MG =   0.38 CMS H2S04/GN C
        CMS
c
c
       H2S04/GM
       0.00164
       0.00327
          00'(91
          00633
          00819
          009b2
          0 11 'i 6
          0131 0
          0 14 7 3
          01637
          02046
          02456
          C2S6f>
       0. n * ° 7 A
       0.03684
          t)4'093
          04502
          04912
          05321
          05730
          06139
          06549
          06958
          07367
          07777
          Gt. 186
          00003
          09823
          10642
          11460
          12279
          1 J09H
          13916
                         RATE,  GMS  H2SL'4/f,H C-
  00208
  00146
  00109
  00092
  00081
  00073
  00067
  00062
0.00059
0.00053
  00050
  OOC48
                                            0,
                                            0.
                                            o.
                                            0.
                                            0.
                                            0.
                                            0,
                                            0.
                                            0,
                                            0
                                            0
                                            0
  00047
  00046
  0004-6
  00046
  00045
  00044
 .00044
 .00043
 .0004-2
0.00041
0.00041
0.00040
0.00018
 .00016
 .00035
 .00033
 .00031
 .00029
 .00027
                                            G,
                                            0,
                                            0,
                                            0,
                                            0,
                                            0.
                        wnsivACo
                        -5.844 5 4
                        -6
                        -6
                        -6
                        -7
                        -7
                        -7
                        -7
            0. 14735
                                       G.OC025
                                                                 . 5 L 5 I. 5
                                                                 .80393
                                                                 .96862
                                                                 .09522
                                                                 . 19619
                                                                 .27076
                                                                 .34 320
                                                                 .39210
                                                                 .48165
                                                                 ,52464
                                                                 .55394
                                                                 . 'i S f Q ')
                                                                 i 56422
                                                                  36082
                                                                  5 5735
                                                                 ,55398'
                                                                  55920
                                                                  53384
                                                                  56131
                                                                  56713
                                                                  5 7 3 1 'j
                                                                  57916
                                                                  37570
                                                                 39222
                                                                 60598
                                                               7.62076
                                                               7.63690
                                                               7.65407
                                                               7.68575
                                                               7.72037
                                                               7.77396
                                                               7.81827
-1,
-7.
-7.
-7.
-7.
-7.
-7,.
-7.
-7.
-7.
-7.
-7.
-7.
-7.
-7.
-7.
-7.
                                        42
-------
CARBON C - 71 - 23
RUN NUMIJHU =  152- G     5  14  71
         RT = 300. OEG  F
TuTM. FLOW KAIt -  1000.0  CC/MM

i>I: KIT NT CO? =   11.3
I'LKCI. HT  U2 =    2,0
\'( :<(,! fU 1120 =   10.0
Cn^ClliJTRATION
co\ceiMri
-------
CAW-OV! C-7-1-23

RUN WUMbEK    r;3-«     5 10 71
TKMPJ''.KATURl!:  - IbO.  DEF J'1
TOTAL
          M  RAT I:
1000.0 CC/C. I
(•I.RCr;;l C02
       I   (//
       l H2U
CO'JCLMKAI I(H(
CIWU'NfRATION
                 11.3
                  2.0
                 10.0

              .SO?  --- 2000.0 PPM
               I JO  =   150.0 f'PK
tMRCKNI 112 504  -   61.24
SAUiRATU) LOADING -   0.3)i !,KS  II2S04/1,,
   GMS H2SU4/GM
       0.00612
       0.007 iO
       0.
         .00(JO /
         00 9 8 0
         0110?
         0 1 'J 3 1
         01837
         02 I 'i*
         024 !>0
         027!>6
         03062
         03368
         01674
         03-^81
         04287
         04593
         04099
         0520^
         05512
         06124
         06736
         07349
         07961
         08') 74
         091(16
         0979(1
         10411
         11023
       0. 11636
       0.12248
         13473
         15922
         17147
         1837?.
         19597
         20822
         22046
         23271
         24496
         26946
         2bi 10
         29J95
         30(>20
         311140
         33070
                         KATl;,  GMS
      0.34294
                112 SI I'. /(•,;•; C-.-11.J
                    0.01 /HI
                    0.0109 7
                    O.Ol-i I 3
                    0.01202
                    0.010*8
                    0.00962
                    0.00671
                    0.00439
                    0.00341
                    G. 002/6
                    0.00246
                    0.00220
                    0.00207
                    0.00201
                    0.00196
                    0.00192
                    0.00188
                    0.00185
                    0.00102
                    0.00179
                    0.00176
                    0.00174
                    0.00170
                    0.00166
                    0.00161
                    G.00 157
                    0.00103
                    0.00140
                    0.00144
                    0.00138
                    0.00134
                    0.00129
                    o.ociia
                    O.OClOd
                    0.00097
                    0.00087
                    0.00070
                    0.00064
                    0.00054
                    O.OOO46
                    O.i>0033
                    0.00033
                    O.OOU2U
                    0.00020
                    0.0"023
                    0.00021
                    0.90019
                    0.0001 I
                    0.00010
                    O.Q0014
wf. STVAL'l)
- .(i I 1)9
  ,117/8
  ,2 56'> 2
                                                             .61166

                                                             . 37(140
                                                            5.6221/
                                                              ,91340
                                                              ,01221
                                                              ,011960
                                                              , 10691
                                                              , I X IH f
                                                              . 13417
                                                              , 14532

                                                              , 16207
                                                              . 16740
                                                              , 1746b
                                                              ,17869
                                                              ,IB 346
                                                              , lbU4ti
                                                              . 19369
                                                           -6. 19919
                                                           -6.21491
                                                              22501
                                                              24090
                                                              25291
                                                              26564
                                                              ,30348
                                                              34157
                                                              39 166
                                                              ,40090
                                                              ,52975
                                                              62742
                                                              72976
                                                              .82285
                                                              .92790
                                                              .992 76
                                                              ,03374
                                                           -7.06207

                                                           -6.99403
                                                           -6.93017
                                                           -6.8H200
                                                           -6.7 J429
                                                           -6.02802
                                  44
-------
     CAKI'.UN C - 71 -  23
 c;
 c
 c
 c
 c
 c
c
c.
c
c
c
RUN UUMNCK - 157- G 53171
TLMPtRAlURE - 200. DEC F
TOTAL FLOW RATE
PIHCCMF C02 =
PlUCRiT 02 =
PLRCCNT 1120 =
= 1000. 0
11.3
2.0
15.0
CC/MIM

      COMCC.NTRAFICJN SU2 = 2000.0  PPM
      CCMCENTRAF IUM  M'J =  150.0  PPM
PERCENT H2SU4 =  67.91
SATURAFtD LOADING =   (
                      3a  CMS H2S1K/CM C
CMS
H2S04/GM
0.00272
0.00407
    0
    0
    0
    0
    0
    0
    0
    0
    0
    0
    0
    n
    0
    0
    0
    0
    0
    0
    0
    0
    0
    0
    0,
    0,
    0,
    0.
    0.
    0,
    0.
    0.
    0,
    0,
    0.
    0.
    0.
    0.
    0.
    0.
         00679
         0095).
         0 1 0 B 7
         01222
         01358
         01698
         02*037
         02377
         02716
         n '} 0 5 6
        .03735
        .OA075
        ,0441 A
        ,04754
        ,05093
        ,05433
        ,05772
        .06112
        ,06451
        ,06m
         07470
        ,08149
         Oot>2«
         09507
         10106
         10o66
         11545
         12224
         12903
         13502
         14940
         16298
         17657
         19015
         20373
                         RATI-,  GKS
            0.217J1
H2SU4/GN C-MIN
   0.00522
   G.00393
   0.00253
   O.UC 14 i
   O.OC. 129
   0.0012 3
   0.00119
   0.00116
   0.00114
   .0.0011 I
   C.00110
   0.00110
   0.00109
   0.00108
   0.00107
   0.00106
   0.00104
   0.00104
   0.00103
   0.00102
   0.00101
   0.00 100
   0.00099
   0.00098
   0.00097
   0.00094
   0.00091
   0.00089
   0.00086
   0.00064
   0.00081
   0.000/9
   0.00076
   0.00074
   O.OOC72
   0.00069
   0.00065
   0.00060
   0.00055
   0.00050
   O.OU045
WtiiTVACO
-5.24744
-5.52946
-5.96490
-6.53302
-6.63047
   67310
   /Ol'jO
   72538
   73860
   75807
   75456
   75094
   74733
   74963
   14 •> ^ 3
   74026
   75064
   74 678
   74292
   74530
   74135
   74377
   74624
   74210
   74461
   74988
   7 5 5 3 4
   76109
   76 7 Ib
   7/35 5
   78040
   78756
   79516
   79447
   79364
   7«253
   78006
   78802
   80883
   83352
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       -6
                                                       *~ 6
                                                       -6
                                                       -6
                                                       -6
                                                           -6.86298
                                      45
-------
     CARBON C - 71 - 23
rr
I
KUN Nuc.ubk =   150 - G    6
1 t-r.PtRATURC =  300.  OCG F
                            I 71


TLTAL FLOW  RATE  =  1000.0 CC/MIN
I'LRU.NT
              coz =
               U2 =
              1120 =
r
i.
CONCENTRATION
CL,'MCI:NTRATION
                 ii.3
                  2.0
                 10.0

               502  =
               NO  =
                           500.0
                           150.0
                     PPM
                     PPM
PH
               139/2
                              RAJ Cr  GMS
            0. 14748
                                   II2S04/GM C-MIfJ
                                      0.00054
                                      0.00043
                                      0.00037
                                      0.00034
                                      0.000 52
                                      0.00030
                                      0.00024)
                                      0.00027
                                      0.00026
                                      0.00025
                                      0.00022
                                      0.00020
                                      0.00019
                                      0.00018
                                      0.00017
                                      0.00016
                                      0.00015
                                      0.00014
                                      0.00013
                                      0.00013
                                      0.00012
                                      0.00012
                                      0.00012
                                      0.00011
                                      0.00011
                                      o.ooou
                                      0.00010
                                      O.OOU09
                                      0.00009
                                      O.OOOOb
                                      0.OOOC8
                                      0.00007
                                      0.00007
                                      O.OXi()06
                                      0.00006
WEST VAC C)
-7.52013
-7.74602
-7.89637
- 7.97176
-8.032/9
-8.08846
-8.13 ('til
-8.18400
-8.224/6
-8.26730
-0.35452
-8.43005
-8.49792
-8.55121
-d.60'459
-8.65286
-8.69480
-8.73411
-8.77080
-0.79036
-8.82677
-8.85154
-8.87019
-8.69036
-8.91077
-8.9 3 280
-8.9646-.I
-9.00770
-9. 03 til 7
-0.0/048
-9.10688
-9.13622
-9. 16838
-9.20501
-9.24431
                                         46
-------
     CARBON C - 71 - 23
 c

 C

 C

 C
RITJ NUMBER =  160-6     6   971
ThMPtRATURE = 200.  DEC  F

TllfAL FLOW KATE = 10UO.O CC/MIN

PtRCFNT CC12 =   11.3
PC-vCENT  02 =    2.0
PLUtUNT H2U =    5.0

COJCtNTKAl ION S()2 = 2000.0  PPM
CONCENTRATION  NO =   150.0  PPM

PLKCL-NT' H2Sei4 =  80.42
SATURATED LOADING- =   0.36. QMS H2S04/GM C
         GMS
 C.


 C
       0.
       0.
       0,
       0.
       0.
       0.
       0.
       0.
       0.
       0.
H2SH4/GM
0.00322
  ,00483
  ,00643
  ,00804
  ,00965
  ,01126
  ,0120?
  ,01448
  ,01608
  ,02010
  ,02413
0.02815
0.03217
0 * V -> O 1 )
0.04021
0
0
0
0
0
0
0
0
0
0
0
0
0.
0.
0. 12063
0.12867
                         RATE,  GMS
               04825
               05227
               05629
               06031
               06 A3 4
               •06 in 6
               072 3«
               07640
              00846
              0965IJ
H2S04/GM C~M(,\i
   0.00306
   0.002L5
   0.00 152
   0.00 110
   0. OU09<*
   0.0 (.!•() U 3
   C.OC073
   0.00067
   0.00061
   0.00054
   0.00050
   O.ooo4y
   0.00047
   0.. 000* 6
   0.00045
   0.00043
   0.00043
   0.00042
   0.00041
   0.00040
   0.00039
   0.00038
   0.00037
   0.0.0037
   0.00036
   0.00035
   0.00035
   C.00034
   0.00033
   0.00033
   0.00033
wtsrvAcn
-5.78171
-6. 12897
- 6 . 4 7 1 4 (5
-6.78822
-6.94636
-7.06719
-7. 18421
-7.26979
-7.35121
-7.47732
-7.52672
-7.54711
-7.56841
-7. 590'-9
-7.59632
-7.62014
-7.62645
-7.63295
-7.63965
-7.64658
-7.67393
-7.68174
-7.67922
-7.67665
-7.6648 \
-7.67960
-7.6741 I
-7.66832
-7.6503J
-7.63169
-/.60020
r
V
                                       47
-------
      Kin  I.'UI'BI i'. -   lol -  (i     6  10  VI
      I b ,'•'»•' IfRMUUl. -  200.  OLG  f:

      TUf/.i.  FLO< KMC- = 1000.0 CC/MIM
PffKCl. IjT
               (.02 =
                U2 -
               1 1 20 =
                 11.3
                  2.0
                 10.0

               S02  =  2000.0 PPM
                NO  =•  300.0 PPM
      Pt:RCTNT  II2S04 =  73.03
      SAl'UKATtrO LOADING -   0.3U  CMS  H2S04/GM C
      CO'.'CI'NTKAT
X, GMS H2SU4/GM  C
                               KAIF:
                02191
                02^56
                02921
                03286
                O^'-'^l
                04 OU
                04332
                047^7
                05)112
                   77
 O.I
 0.00730
 0.00876
 0.01022
 0.0116B
 0.0131 5
 0,
 0,
 0.
 0.
 0.
 0,
 n
 0.
 0.
 0.
 <•>.
 0.
 0.
 0.
 0,
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
 0.
0.
0.
0.
                0620o
                06573
                06938
                07303
                08033
                08764
                09494
                10224
                12413
                I 3 1 4 'j
                13876
                14606
                1606 /
H2S04
   P.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   C.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
   G.
   0.
   C.
   0.
   0.
   0.
   0.
   0.
   0.
   0.
                                         /GI" C-MIN
                                         001J97
                                         00429
                                         00308
                                         OOlVil
                                         0012!>
                                         0010'j
                                         0009S
                                         00087
                                         00084
                                         00081.
                                         000/8
                                         00076
                                         00075
                                         00074
                                         000/3
                                         000/2
                                         00070
                                         00070
                                         00070
                                         00069
                                         00069
                                         00068
                                         OOCiSU
                                         00067
                                         00067
                                         00066
                                         0006^
                                         00064
                                         00062
                                         00062
                                         OOU60
                                         000-j')
                                         000^7
                                         qOU'>6
                                         00054
                                         00049
                                         00045
                                         00040
h'FSTVACU
-5. 11272
-5.44042
-5.76707
-6.20578
   .66451
   .83348
   ,93254
   .00929
   .03945
   ,07388
   .09138
                                                               -6
                                                               -6
                                                               -6
                                                               -7
                                                               -7
                                                               -7
                                                               -7
                                                               -7. 10956
                                                                   10892
                                                                   11809
                                                                   1274'3
                                                                   126 •'j 6
                                                                   13672
                                                                   1 3634
                                                                   12530
                                                                   12467
                                                                   11338
                                                                   11262
                                                                   10107
                                                                   10026
                                                                   09933
                                                                   OU626
                                                                   07283
                                                                   07029
                                                                   06751
                                                                   05278
                                                                   04942
                                                                   04600
-7,
""" I i
-7,
-7.
-7,
-7.
-7.
-7.
™* I «
-7.
-7,
-7,
-7,
-7,
-7,
-7.
-7.
-7.
-7.
-7.
                                                               -7.04239
                                                               -7.03858
                                                               -7.04811
                                                               -7.06938
                                                               -7.09426
                                                               -7.14204
i.
                                        48
-------
CARBON C - 71  - 23

RUM  NUMUI-'R  =   16? - G    6
Tfcl-'PtKATURi: =  200. DFG  F
                             11  71
TUT/VL FLOW  RAl'K =  1000.0 CC/MI.N
(
(

(

(

(


(


(


(


(


(


C


(


(


(


(


(


(

•
C


f
V
. PL'0 7
-5.97719
-5.99394
-6.00188
-5.91142
                                    49
-------
      CARBON C  - 71 -  23
(

c

(

(
(
(
(
HUN NUK1U k  =
TLMJI;UAIIMI:  =
        161 - G
        200.  DC-G
                              b  14  71
TOTAL FLCW  RATH  =  1000.0 CC/f'IM

I'LRCErjT C02  =    11.3

PERCENT H20  =    10.0

CU\CK*TRAT10'J  Sl)2  =  2000.G PPM
C OX: t-iNTRAT I ON  Nf!  =    50.0 PF'M
PIRCLUT H2SU4  =   73.33
SATURATED LOADING  =
   3HS
II2S04/GM
0.00147
0.00293
0.00440
0.00587
0.007',3
0.00880
  01027
  01 173
  01320.
  01467
  01833
  02200
  02567
  02933
  03300
  03666
  04033
  044 00
  04766
  05133
  05500
  05866
  062 )3
  06600
  06966
  07333
  08066
  08800
  (19533
            U. 1 0266
              ,117*3
               12466
               13199
               139)3
               14666
               1 ft m
       0.
       0.
       0.
       0.
       C.
       0.
       C.17599
       0.19066
       0.20532
J
0.38 GMS M2SD4/GW C
RATI-, GMS H2SU4/OM C-,^IN
0.00305
0.00 f. 5 1
0.00205"
0.00166
0.00137
" 	 0.00126
0.001 18
O.OC1 12
0.00107
0.00104
C. 00096
O.OC092
0.00091
0.00009
0.00089
0.00088
O.OOOfcS
	 0.00007
0.0(>087
O.OOOrf?
0.00086
0.00035
0.00084
	 0.00084
0.00083
0.00082
O.OOOH1
0.00079
0.00077
0'. OOU75
0.00073
0.00072
0.00070
o.ooooa
0.00066
0.00064
O.OC059
0.00055
0.00050

WL-STVACll
-5. 7U759
-5.97820
-6.17923
-6. 38323
-6.57505
-6.65564
-6.71235
-6. 75963
-6.802«0
-6.83 387
-6.89-795
-6.92697
-6.93275
-9.25706
-6=936 5 b
-6.93434
-6.92778
	 -6.92112
-6.91444
-6.90758
-6.90496
-6.9022(3
-6.89956
-6.89677
-6.8894 3
-6.1; 9 094
-6.8';i495
-6. H7870
-6.8 1, 1 1> (-,
-6.87502
-6.87803
-6.87094
-6.87399
-6.86639
-6.H6948
-6.S7288
-6. 85029
-6.88884
-6.91364
                                            0.00044
                                                                  -6.94325
                                        50
-------
     CARBON C - 71 -  23
(
c
RUM NUf-'WER
  164 -
= 200. DEC  F
                              6 15 71
   '  TOTAL  FLC'fc RATE =  1000.6 CC/MIN
PtRCENF C02 = 11
I'tRCtM 02 = 2
PIKCt-NT H2U = 10
CUNCtNTRATtQN S02
CL'JChKT RAT tOU .\C5
PfcRCEI-JT "H2SU4 =" 7
SATURATED LOADING
X, GMS H2S04/GM C
0.00146
0.00292
O.C0439
0.00585
0.007U
0.00877
0.01023
0.01 170
0.01316
0.01462
0.01827
0.02193
0.02553
0.02924
0.032B9
0.03655
0.04020
0.04386
0.04751 '
0.05117
0.05482
0.05848
0.06213
0. 065 79
0.06*) 4 4
0.07310
6.0b04l
0.08772
0.09503
0. 10234
0.1C965
0.11696
0.12427 """
0.13158
0.13889
0.14620 '
0.16092
0.17544
.3 • ••• . .
.0
.0
= 1000.0 PPM
= 15C.O PPfo
3.10
= 0.38 GMS II2S04/GM C
RATF:, GMS U2SU4/GM C-MI.V
0. 00 181
0.00 12 '3
" 	 '' 	 : "" '0. 00031.
0.00071
0.00066
0.0006^
0.00060
0.00059
0.00057
0.00057
0.00054
0.00054
0.00052
0.00051
"" 	 " 	 "0.00051
0.00050
O.OOC50
0.00050
0.00050
0.00050
0.00050
0.00050
0.00050
	 0. 00050
0.00050
O.OOU50
0.00049 	 	
0.00048
0.00048
0.00048
< • 0.00 04 7
''..' O.C0047
V ' : 	 " 0.00046
G. 00045
0.00045
O.OOU43
0.00042
' 0.00040




WHSTVACU
-6.3093.5
-6.67460
- 7 . 1 0 3 J 3
-7.23667
-7. 30837
-7. 36403
-7. 3ti447
-7.40551
-7.42717
-7.43624
-7. 46659
-7.47022
-7.488L3
-7.49215
-7.49627
-7.49306
-7.48236
'-7.47898
-7.46805
-7.45700
-7-44582
-7.43451
-7.42308
-7.4115?
-7.39982
-7.38793
-7.37891
-7.36947
-7.34414
-7.33366
-7.32272
-7. 30328
-7.2831.2
-7.27038
-7.25704
-7.26015
-7.23066
-7.21668
                                         51
-------
                      APPENDIX    A-3






COMPARISON OF WESTVACO MODEL TO EXPERIMENTAL SORPTION DATA
                          52
-------
                   RUN NUMBtR
                                  139
                                            4  22  71
Ul
U>
      RATECt I )  = COEF *
            WHERE COEF =
                POKfcR »
                   XS =
                 YS02 =

 XUl.GMS H2S04/GM C

        0.00294
        0.00441
        0.00539
        0.00736
        O.OC8B3
        0.01030
        0.01177
        0.01324
        0.01472
        0.0183-}
        0.02207
        O.Q2575
        0.02943
        0.03311
        0.03679   "
        0.04047
        0.04415
        0.04783
        0.05151
        C. 05518
 "   '-    0.03336
        0.06254
        0.06.622
""" .....  0.06990
        0.07353
        0.0*094
                                          (l.-XIIJ/XS)  * 
-------
  RUN NUMBER
                          4 23 71
      KATECtI) *
_XU > tGMS H2S04/GM

        0.00292
        0.0043?
        0.00583
        O.OCU21
        0.00875
        0.01021
        0.01167
        0.01312
        0.01453
        0.01323
        0.02167
        0.02552
        0.02916
        0.03281
        0.03645
        0.04010
        0.04375
        0.04739
        0.05104
  •      0.05468
        0.0r)333
        0.06197
__.	 .  0.06562
        0.06926
        0.07291
        O.OK020
        0.OK 749
        0.09478
	0,10207
        0.10936
        0.11666
	._    0.12395
        0.13124
        0. 13853
        0. 14582
        0.16040
        0.17498
OEF * tl.-Xin/XS) * 
-------
                   RUN NUMBER  =   141
                                            4 26 71
Ul
      RATECt I I = CGEF *
            WHERE COEF =
                POwtR «
                   XS =
                 YSOZ =

 X( I J ,GHS H2S04/GM C

        0.00148
        0.00296
        0. 00444
        0.00592
        0.00740
        O.OUSBS
        C.C1C36
        0.01184
        O.C1332
        0.01430
        0.01850
        0.02220
        0.02590
        0.02960
        0.03330
        0.03700
        0.04071
.....    0.04441
        0.04811
      * 0.05181
        0.05551
        O.C5921
        0.062V1
                                          (l.-Xtn/XS) * 
-------
                   RUN NUMOtR
                                            4 27 71
                              i)  =  cotF * (i.-xm/xsi
                              WHERE COEF =   0.01050
                                  POr-ER =   0.40500
                                     XS =   0.33000
                                   YSU2 =   0.00100
                              * (YS02»**POW£R
Ui
                  XU >,GMS  H2S04/GM  C
0.00144
0.00285
0.004J1
O.C0575
0.00719
0.00963
0.01006
C.01150
O.C1294
0.01438
0.01797
0.07156
0.02516
0.02875
0.03235
0.03594
0.03953
O.C431 3
0.0^.672
0.05032
0.05391
O.OD750
0 . U
-------
                           RUN h'JMBER =  133 -G
                          4  21  71
                          RATEC(il= COEF * (l-XUI/721 * Y2C2«*.4I *-(Y02**.63)
                             WHERE  COEF= .000159 * EXPt 552CM I/ t T *460) ))
                                     XS=   0,38000         T= 200.00000
                                       =	D.00200	YUZ=	Q.00700__
                                                       * (YH20**,73)
Ul
YH20= O.I 0000
XI! ) |G«S H2S04/GH-C 	 RAT£_,_GMS. H2SOW.SH._C-HIN. ,_._CALCULATtU RATE, GKS H2S04/GH. C.-M]
0.00145 ' 0.0024220 0.0004622
0..00290 O.OC17S13 O.OC04604
0.00435
0.00530
o.nn7?s
0.00870
0.01015
0.01160 .
0.01305
0.01450
O.OlBil
0.02175
0.02538
0.03263
0.03625
0.04351
0.04713
0.05438
0 . OS50 1
O.OM63
0.06526
0.06888
0.07251
0.07976
0.08701
0. Q9426
0.10151
0.10876
0. ) IfrO? 	
0.0012296
0.00-58421
0.0005291
0.0005068
0.0004918
0.0004S44
O.C004770
0.0004546
0.0004397
0.0004173
0.0004099
0.0003913
0.0003875
O.OC03763
0 * CCO^ "* °6
0 .fOO 3^^9 ,,. .
O.U003689
0.0003652
O.OCC3iM5
O.OU03577
0.0003540
0.0003540
0.0004587
0.0004569
0.0004551
0.0004534
O.OC04516
0.0004498
O.OOC44BO
0.0004463
0.0004418
0.0004374
0.0004330
0.0004286
0.0004241
0.0004197
O.OC0415i
O.COC4109
0.0004064
0^0004D?0
0.00039f6
0.0003932
0.0003643
0.0003799
0.0003666
0.0003577
0.0003400
0.0003312
n.nom??*
IN 	 .UIFFd.J.
0.0019598
	 0.0012908 ...
0.0007710
0.0003U52
0.0001634
O.CC00757
0.0000552
0.0000420
0.0000363
0.0000307
0.0000202_
0.0000171
0.0000067
0.0000038
0.0000068
O.OOC0098
0.0000166
0.0000196
0.0000189
0.0000219
O.OC00213
0.0000205
0, DODO 199
O.OOC0154
0.0000147
0.0000)0"*
0.0000051
0.0000000
0.0000140
0.0000228
. . D. 0000279.. _
KEAN DEVIATION =   0.0000186    ROOT  ,".EAN  SOUARE  DEVIATION
RESIDUAL-SUK-OF- SdUARES _=_U.U850E--0-^	
KEAN PERCENT DEVIATION  =    4.484&6H
                                                                                         0.0000222
-------
                   KUN NUMbtR
                                  143
                                            4 28 Tl
Ul
oo
                       KATEC< I )  = CtJEF *
                              HHtRE COEF =
                                  »0*ER =
                                     xs =
                                   YSUZ =

                  XII) ,OM'S  H2S04/GM C
0.00145
0.00290
O.OC4J5
O.C0580
O.O0724
O.C'C869
O.G1014
C.01159
O.U1304
0.01449
0.01811
0.02173
0.02536
0.02898
0.03260
0.03622
0.03985
0.04347
0.04709
0.05071
0.05434
0.05796
0.06158
0.06520
0.06883
0.07245
O.OT969
0.08694
0.00413
0.1014?
0. 10867
0.1159?
0.12316
0. 13041
0.13765
0.14490
0.15939
                              * (YS02)**POKER
                    0.01050
                   0.40500
                   0.-.3QOO
                   0.00050

                 RATE,  G.XS H2S04/GM C-MIN   CALCULATED RATEt CMS H2S04/GM C-HIN
0.0033683
0.0021586
0.00105C3
0.0008330
0. CCC6990
0.0006157
0.0005577
0.000521&
O.OOC4962 	 	
O.OOC4817
O.COD4745
0.0004636 ~ ~~ ~ '
O.CC04564
O.CC04527
O.OCC445i>
0.0004382
C, 0004346
0.0004310 	 " ~- " ' •-"- 	
O.OCC4238
0.0004201
0.0004165 	 " " 	 "
C. 0004129
O.OOC4093
0.0004056
0.0004020
0.0003984
0.0003948
O.D003875
O.CGC3S03
C. 0003730
0.0003658
0.0003586
0.0003477 	 "
0.0003404
0.0003332
0.0003223
0.0003006
0.0004815
O.OOC4797
0.0004773
0.0004760
0.0004741
0.0004723
0. 0004705
0.0004636
0.0004663
0.0004649
0.0004603
0.0004557
0.0094511
0.0004465
O.OOC4419
0.0004373
0.0004327
O.C0042B1
O.C004235
0.0004189
C.C004142
0.0004096
0.0004C50
0.0004004
0.0003958
0.0003912
O.OG03820
0.0003723
Q-.C003636
0.0003543
0.0003451
O.C003359
0.0003267
O.C003175
0.0003033
0.0002990
0.000.2806
    DIFFtI »

0.0025368
0.0016789
O.OOC5725
O.OC03570
0.0002249
0.0001434
0.0000873
0.0000530
0.0000294
C.OOOOIS3
0.0000142
0.00000^9
0.0000053
0.0000062
0.0000036
0.0000010
  .0000020
  .0000029
  .0000003
  .0000013
O.OOC0023
O.OOC0033
0,0000042
0.0000052
0.0000062
0.0000072
C.C000128
0.0000148
0.0000167
0.00001.87
O.OOU0207
O.C000226
0.0000210
C.0000230
O.CC00249
0.0000233
O.C000200
                                                                                                             0.
                                                                                                             0.
                                                                                                             0.
                                                                                                             C.
                  MfcAN DEVIATION =
                                      0.0000154   ROOT MEAN SQUARE DEVIATION
                                                                                  0.0000231
-------
 RUN  NUMBER »   139 -G
•, 22 71
RATtC(l)= CCCF  *  U-XU)/72I * Y202**.4I  *  (YQ2**.63)
        COEF=  .000159  » EXPI5520*(t/• ,;•..'"
0.0006791
0.0006755
n.onnAAfu
0.0006610
0.0006538
O.OOO^'tf.'i
0.0006356
0.0006247
n.nonhiTH
0.0006028
0.0005883
fi-or>ns77i
0.0005484
0.0005230
n.nnrx.od^
ROUT MEAN .SQUARE DEVIATION =
L5155E-06 	 	 . , 	 .-.„ -

_.RAT£t .GHS_H2SQ'./CM.C.-MIN ._
0.0008920
0,0008885
0.0008850
0.0008815
0.0008781
0.0008746
0.0008711
0.0008676
0.0008641
0.0008554
0.0008467
o.oooaiao
0.0008293
0.0008206
o.oooai 19
0.0008032
0.0007945
0.000/858
0.000/771
. .0.0007684 	 	 , 	 	
0.0007597
0.0007510
O..OO.C.7A2? .. - 	 	
0.0007336
0.0007249
0. 000/075
0.0006901
0.0006727
0.0006553
0.0006379
0.0006205
O.OOOftOiO
0.0005856
0.0005682
n.oons5on
0.0005160
0.0004812
0..0004.46'. _. 	 _ 	
0.0000678

	 DIFF.(.U_
0.0061682
0,00 ',220 I
0.00211775
0.0012467
0« 0004076
0.0002004
0.0000/31
O.OOOCO'.O
0. OOU0434
0. 0000055
0.0000841
0.00001)99
O.OOOOHH5
0.0000870
0.0000(J'..5
0. 00001!', 1
O.OOOOH27
0.0000t;12
0.0000/62
. 0.0000/48 	
O.OOU0697
0.0000646
0,OOnoS95
0.0000544
0.0000494
0.0000392 __
0.0000291
0.0000109 :
0.0000008
0.0000023
0.0000042
0.00001Q8
0.0000172
0.0000201 :
_0.0000266_.. ..
0.0000324
0.0000418
0..000043.9-,.. -

                                                59
-------
   RUM KUMttER »

  RATECd )=  COCF
     WHERE COEF=
             XS =
                140-G
•> 23 71
                * (l-X(I)/72)  *  Y202*<'.4) * (Y02**.63>
                .000159 * EXP(5520*( 1/i T f'.60 )))
                  0.38000          T=  200.00000
                                 Y.()2~	.O.r.020.0.0			
                              *  (YH20**.73»
	.YS02-	0.00250	
.           YM20=    0.10000

., Xt 1 1 ,GMS II2S04/CH.C	RAJE->._.GHS-H2S04/_GI>UC.-M1N	CALC.ULAT.CO
                                                                      C«S._N2SO't/CM..CrHl.N..
                                                                      .OIFFd.l.
0.00292
	 0.004J7 _..
0.00583
0.00729
0.00875
0.01021
0.01167
0.01312
0.01458
0.01823
0.02187
0.02552
0.02916
•0.03281
0.03645
0.04010
O. 04 37 5
0.04739 '
0.05104
- - 0*05468 	
0.05833
0.06197
0.06926
0.07291
0.08020
O.;08749
0.09478
• -0. 10207 —
0. 10936
0.11666
	 0.-12395,. _
0. 13124
0. 13853
0. 14*8?
0.16040
0.17498
0.0045633
__.. 	 	 0.0032855 	 _.„ 	 . 	
0.0015552
0.00.12923
	 0..001131.7
0.0010258
0.0009638
0.0008907
0.0008433
n.orinn;>';o . ..•_.
0.0008141
0. 0008031
0.0007849
0,0007776
0.0007630
0.0007557
0.0007447
0.0007374 : : . '
Oi "'10 7^*1
0.0007265
0.0007223
0.0007119 ..„. -,
0.0006972
0.0006899
, „- , . „ 0.0006827 -' ' •., •
0.0006717
0.0006608
0.0006461
0.0006352 .:'• :
0.0006206 . / •• ' •":..• .1 . . .• .
	 ... 	 	 _. o.000'-0q7 ' • :
0.0005804
0.0005513
0.0009753
	 0.0009716.... 	 	 	
0,0009678
0.0009640
0.0009603
0.0009565
0.0009527
0.0009489
O.OC09452
0.0009357
_ 	 0.0009263 „_
0.0009169
0.0009075
, o.oooagno
0.0008886 .
0.0000792 • ..'.;;'
0.0008603
0.0008509
.. .. 0.0008414 	 	
0.0008320
0.0008226
0.0008037
0.0007943
0.0007566
0.0007377
0.0007000
0.0006811
0.0006434
0.0006246 . .;' .,;•...:
0.0005680
0.000530J
0.0035879
.. 0.002 3 140.
O.OOO'JU/'i
0.0001715
0.000069',
O.OOOOU1
0.0000326
0.000054373
0.0000052
0.0000773
0.0000715
0.0000635
0.0000593
0.0000478
0.0000362.
0.0000283
0.0000204
0.0000162
0.0000082
0.0000040
O.OOOQ04Q
0.0000124
0.0000210
MEAN DEVIATION  » .  0.0000620   ROUT  MEAN SQUARE DEVIATION
RESIDUAL  SUM  OF SOUAR6S '• 0.16349f,-0t                  :.  ,
MtAN PCRCENL-OEVUnON^=	8.0887070	...J	'.	
                                       0.0000715
                                                   60
-------
  RUN  NUMBER =  l'il-G
'( 26 71
 RATEC(l)*  COEF * (l-Xtl)/72)  «• Y202**.*) *  (Y02**.63) * — - . 0.096?!. ~
0.10361
O.U101
	 _ . 0. 118*?
1 0.12582
( 0.13322
0,1*802
6. 16282
--. — .. o. 17762
0.192*3 , ;
-- HFAN nrviAriritj A
0.0051 181
	 	 _ 0.00*2177
0.002319?
O.OQ11*15
. 	 	 .., 	 .0..000935J
0.0000359
0.00078*3
	 	 	 0.00075U 	 _ 	 	 	
0.000736*
0.0007253
	 0.0007217
0.0007106
O.OOOY032
. „ 	 , . . 0. 0006959
0.00068*9
0.0006/75
	 	 	 . Q. 0006/02.. 	 	 	 .
0.0006628
0.000655*
	 	 	 ..a. 0006*00.
0.0006*07

0.0006260
0.0006223
n.onrif.i/,9
0.0006038
0.0005928
0.0005671
0.0005523
0.0005192
0.0005008
0.000*8?3
0.000*6*0
0.000*23*
.0.0003*2*
.n.nooo??n. R£inr Mr-AU SQUARE .DEVIATION..".. ...
0.0007981
0.0007950
0.000/919
0.0007888
O.Q007056
0.0007825.
0.000779*
0.0007763
0.0007732
0.0007700
0.0007622
0.00075**
0. 0007*66
0.0007388
0.000/310
0.0007232
0.000715*
0.0007076
0.0006998
0.0006920
0.00068*2
0.000676*
0.0006686
0.0006608
0.0006530
0.0006*5?
0.0006296
0.00061*0
0.0005828
0.0005672
0.0005360
0.0005203
0.00050*7
0.000*891
0.000*579
0.000*267 	 „. .-
0.0003955
0.00003*9 	 	 _..
0.00*3200
0.003*2*7
0.0015278
0. 0003527
0.0001*96
0.0000') 3*
0.00000*9
0.0000251
O.COOOJ68
0.0000** 7
0.0000*06
0.0000*38
0.0000*3*
0.0000*29
0.0000*61
0. 0000*5 /
0.0000*5.4
O.OOOOV.9
0.0000***
0.0000**0
0.0000399
0.0000357

0.00003*8
0.0000307
0.0000303 .
0.0000257 .
0.0000212
0.0000166
0.0000157
0.00001*8
	 O.OOG01.76_
0.0000168
0.0000196
0.000022* 	
0.0000252
0.00003*5
	 ;. __0. 0000*01 	
0.0000531
 RESIUUAL  SUM OF SOUAIUS '  O.*023'.>(.-07
 MUN PERCENT DEVIATION  '    5.5525713
                                                  61
-------
    RUN NUMBER
                  142-C
27 71
   RATECU) = COEF * (l-XUI/72)  *  Y202**.4) * IY02**.63) *  (YH20+*.73)
      KHEKE  COEF = .000159 *  EXP ( 5520*< 1 / I T+460) ) >
              XS =   0.3BOOO          T=  200.00000
  	  ..._YSG2 = ....0.00100	Y02=___.. 0.02000							
            YH20=   0.10000
      ) iGMS.II2SO'i/GM C..
                          .RATE,  GMS-.H2S04/GM_.CrK IN....CALCULATED  RATet__GMS .JfZS04/CM_C.-.MIN._-
                                                                         ( )__.
0.00144
o.oo2aa
0.00431
0.00575
0.00863
0.01006
0.01 ISO
0.01294
0.014.18
.0.01717 	 	 	
0.02156
0.02516
0.02875 	
0.03235
0.03594
0.04313
0.04672
.0.. 05032 - , - - —
0.05391
0.05750
0.06469
0.06829
0.. 07 188 	
Of07907
0.08626
0. 09^44 t 	
0. 10063
0.10782
. 0»-1 1 501..,.. 	 	 , 	
0.12220
0.12938
0.13657
0.14376
0.15814
0. 17251 	 _.
0.0050370
0.0036017
0.0021J80
O.OP09639
0.0007573
0.0007067
0.0006740
0.0006559
0.0006522
_ . 0.0006414 	 ._ 	 	 ;. 	
0.0006341
0.0006233
....0.0006160 	 	 	 	 _ 	
0.0006088
0.0006016
0.0005943
0.0005070
0.0005798
0.00056U9
0.0005617
0.0005508
0.0005436
	 _0. 00 05400 	 . 	
0.0005290
0.0005182
0.0004965
0.0004055
	 0. 0004 74 7_ — 	 	 	 „,„ 	 „,
0.0004638
0.0004493 . v
0.0004204
0.0003914
.n.ooowi 	 	
0.0006787
. . 0.0006761
0.0006735
0.0006710
- ,-Q. 00066 84
0.0006658
0.0006632
0.0006607
0.0006501
0.0006555
..... 0.0006491.. 	 _• 	 	
0.0006426
0.0006362
0.0006297 . 	 ... _.
0.0006233
0.0006168
0.0006104
0.0006040
0.0005975
0.0005911
0.0005846
0.0005782
..0.0005717
0.0005653
0.0005589
	 0.0005524 	 , 	 „
0.0005395
0.0005266
0.0005009
0.0004880
	 Q. 00.0475 1 	 _, 	
0.0004622
0.0004493
0.0004364
0.0004235
0.000.3978
	 Q.. 0003720. . 	 _
0. 004.1 V>«3
0.0014644
0.0002929
0,0001651
0.0000915
0.0000434
0.0000134
0.0000022
O.OOOUOJ3
	 O..OOOOU/ 7..
O.OOOOOU5
0.0000129
_..._ 	 0.0000137.
O.OOOOi. 45
0.0000153
0.0000161
O.OUUOU-.9
0.0000177
0.0000149
0.0000157
0.0000165
o.nonnn?
0.0000145
0.0000153
	 	 O.OOO.OL24..
0.0000105
O.OOQ0085
0.0000044
0.0000024
	 0, 0000004_
0.0000016
0.0000000
0.0000016
0.0000032
0.0000064
	 ' ..0.00000.96..
  MEAN  OEVIATIOfJ ='   0.0000107   ROOT  MEAN  SQUARE DEVIATION
-. RESIOUAl. SUM 01- SOUAR£$-.-.-0.5792bE-08	^^	^		
  MEAN  PERCENT DEVIATION =   1.8736451
                                    0.0000135
                                                    62
-------
 RUN NUMBER =  143-G
'. 28 71
RATEC(I)= COCF * «l-X(I)/72)  *  Y202*».4)  * (Y02**.65)
   WHERE CGHI-- ..000159 *  fXP ( 5520* ( I/ ( T *460 ) ) )
           XS=   0.38000          T =  200.00000
   		Y.S02=..  0.00050....	Y02 =	0.0700Q	
         YH20=   0.10000
                              * 
X(I),GMS-H2S04/G.M. C 	KATJi. ..CHS  U2Sn4/GM_.C-MIN .. .CALCUI.ATCO .RATE,  CMS l!2SO't/GM .C-MIN.
                                                                      otpni
0.00145
0.00290 ... _ 	
0.00'i35
0.005BO
0.00724 . 	 ...._ ...
0.00869
0.01014
	 ......O.Q11S9 . .. 	 	 ...
0.01304
0.0l'i'.9
. 0.01811 	 	 	 ...
0.02173
0. 02536
	 	 0.02098 	 	 	
0.03260
0.03622
0 . 0 J9 B 5.
0.04347
0.04709
fi,n«,r>7 J
0.05434
0.05V96
0 m 0 O I *^ '}
0.06520
0.06C83
... _. . 0.07245
0.07969
0.0869't
ft ftG& 1 A
0. 10143
0. 10867
— - 0.11592
0.12316
0.13041
ft - 1 17/. K
0.14490
0*. 15939
0.0031683
.O..OQ21'JE6... 	 	 ... .
0.0010503
Q. 0008350
0.000699.0.., .
0.000615V
0.00055/7
.0.0005216. 	
0.000'i9()2
0.000481V
0.000'fY'iS. 	 , .
0.0004636
0.0004564
0.0004527 	 r 	 : 	 	
0.0004455
0.0004382
0.0004 Vi 6
0.0004310
0.0004238
0 ,no<1420'
0.0004165
0.0004129
f) .(Hift'.OO 1
0.000405h
0.0004020
!).0003984._ 	 	 	 _ 	
0.000394B
0.0003875
P.0003PO^
0.0003/30
0.0003650
O.OOO^ORh . 	 ,~- -
0.0003477
0.0003404
0 jO-10** '»?
0.0003223
0.0003006
0.0005143
0.0005124
0.0005104
0.000501)4
0.0005065
0.0005045
O.Q005025
.0.0005006
0.0004986
0.0004966
0.0004917
0.0004868
0.0004819
.O.C004769
0.0004720
0.0004671
0.0004622
0.0004573
0.0004523
0.00044/4
0.0004425
0.0004376
O..C00432&
0.0004277
0.0004228
0.0004179
0.00040)10
0.0003'K!2
o. 000.3 an j
0.0003785
0.0003687
0.0003500
0.0003490
0.0003391
0.0003293
0.0003194
0.0002997
0.0028539
0.0016462
0.0005399
0.0003246
0. OOd 19,° 5
0.0001112
O.U000552
0.0000210
0.0000024
0.0000149
O.OOCOJ 12
0.0000212
0.0000255
	 	 	 '0.000024a...
0.0000265
0.0000208
0.0000275
0.0000262
0.0000286
0.0000273
0.0000260
0 . 0 0 ^ n "^ f: 7
0.00(JO2i4
0.0000^21
0.0000208
0.0000105
0.0000133
0.0000107
O.U000081 ,
0.0000055
0.0000029
0.0000003
0.0000013
0.0000013
0.0000039
0,0000029
0.0000008
MEAN DEVIATION =   0.0000173    ROOI  HCAN SQUARE DEVIATION
RESIDUAL SUM OF SQUARES  * 0.13il7',t-07
MEAN PERCCNV DEVIATION =	3»941>U342-	
                                                                0.0000212
                                                63
-------
   HUN NUMBER
144-G
                              29 71
  RAUC(l)= COEF  »  U-XIII/72) * Y202**.4I  *  (Y02**.63)  * (YH2U**.73)
     KHE1E COCP =  .000159 » EXP ( 5520* (I/ ( T + 4iiO ) 1 )
              XS-    0.30000         T= 200.00000
		_  -_.YSn2=.	0.00200	VD2-.	0..03500			,	
           YH20*    0.10000

.. XII ),GHS. H2S04/GII C	RATE., -GHS..H2SX14/.GM C.-M1N—.GALCUI.ATCO.JlATEi .CMS  HZS04/GH_C_-MJ.N	OIFF(.I) .
0.00201
n.nn/.4n
0.00086
0.00/33
0-fWlRftf)
0.01026
0.01173
0.01320
0.01466
0.01833
0.02199
0.02566
0.02932
0.03299 	 _., 	
0.03665
0.0't032
. .0.04399 	 ___.
0.04765
0.05132
0.0^498
0.05865
0.06231
V.1 » VO'1 ^ tf -
0.06964
0.07331
0.08064
0.08797
0.09530
0. 10263 v , 	
0.10996
0.11730
-0.12463 	
0.13196
0.13929
0. 14662
0.16126
0.17594
0. 19061
0.20527
0.0053409
0.0037.517 ' -._...
0.0025259
0.001'>452
n.nnf/.?f>/.
0.0013558
0.0013001
O.OOIP518 	 - 	 - 	 	
0.0012035
0.0011367
0.0010995
0.0010810
0.0010698
	 0.0.010623.. 	 	 ,. 	 	
0.0010549
0.0010474
	 0 . 001 0400 	 '- 	 _._
0.0010326
0.0010252
O.OOlO?i5
0.0010178
0.0010141
Cf t r~. ™i \ tj P .', ,'„
0.0010030
0.0009992
n ,prnioiia
0.0009d4.3
0.0009769
n >OOOr)6S8
0.0009509
0.0009398
0. 0^09212
0.0008909
0.0008766
n.onog«i<,
-------
 RUN NUMBER =   K5-G
30 71
RATEC(I)=  COEF  *  ll-X(I)/72)  * Y202**.4) * (Y02**.63)
   WHERE COEF =  .000159 * EXP15520*f I/(T+460)))
           XS =    0.38000         1=  200.00000
                           * (YH20**.73)
YM20= 0.10000
Xlll.GHS. H2S04/GM.C. 	 RAIE
0.00290
_ ... 0.00436. 	 	 	 	 ......
0.005BI
0.00726
...0.00871 	 	 	
0.01017
O.OU62
0.01307 	 _ . .
0.01452
0.01815
	 0.02178 	 	 .
0.02541
0.02904
.0.03P6/ . ........
0.03630
0.03994
	 __ 0.04357 	 ...
0.04720
0.00083
0.05809
0.06172
0.06898
0.07261
0.07987
0.08713 •
0'.09439
0.10891
0.11618
0.13070
0.13796
	 	 0. 14522- 	 	 . 	
0.. 15974
0.17426
I...GMS H2S04/GM..C.-MIN
0.0064766
	 0.0051454 	 	 	
0.0037780
0.0026626
. _ O.d014752 	 	
0.0010650
0.00102ia
. 0.00099.! I
0.0009715
0. 0009 j I 9
... .0.0009031 . . _ 	 	
O.OOOH816
0.0008635
0.0008312
0.0008203
O.OOOfl(]9C,
0.00079U8
0.0007916
0.0007772
0.0007700
0.0007556
0.0007520
0.0007268
0.0007124
0.0006764
0.0006621
O.OO06405
0.0006225
0.0006009
_... 0 .0005793..-.. 	 -
0.000536?
0.0004893
...CALCULATED KATE. ..CMS.. H2SP4/GU C-HLN
0.0008921
„., 	 	 _ . 0,0008887
0.0006852
0.0008818
0.0008749
0.0008715
0.0008680
0.0008646
O.OOOU560
	 	 	 0.0000474. 	 	
0.0008388
0.0008302
0-000il?17
0.0003131
O.OOOH045
. 	 . 0.0007959
0.0007873
0.0007787
0.0007701
0.0007615
0.0007530
0 .OOO /<«'n4
0.0007358
0.0007272
0.0007100
0.0006928
0.0006757
0-0006505
0.0006413
0.0006241
0-0006069
0.0005U98
0.0005726
	 	 	 0 .0005554 	 ....
0.0005211
0.0004867
IHFFI I)
0.0055045
0.00'.,">66
0.002H928 	
0.001 HiOO
0.000'i969
0.0001VOI
0.000150'i
0.000 1 <")0
0.0001069
0.0000759
0.0000'i57
0.0000427
0.0000 "13 3
0.0000? 39
0.0000181
0.0.000159
0.0000137
0.0000115
0.0000129
0.0000143
0.0000157
0.0000171
0.000019B
0.0000248
0.00003L2.
0.0000340
0.0000368
0. 0000395
0.0000351
0.0000379
0,0000335
0.0000327
0.0000283
0..0000239.
0.0000151
0.0000026
MEAN DEVIATION  =    0.0000418    ROOT MEAN SQUARE DEVIATION -
RCSinUAL  SUM  OF SQUARIS  "  O.H287E-06
                                                              0.0000594
                                                 65
-------
 RUN  NUMOFR =  148 -G
          5  7 71
 RAteCtt)--  COEF
    WHERE  COCT=
            xs-
	 ..YS02 =
          YH20 =
* (l-XID/72) * Y202**.41  *  (Y02*».63)  *  tYH20**.731
.00015'* * EXP(5520*< l/IT + 460)JI
  0.38000         T=  150.00000
  0.00250	.Y02-^__.0.02000			
  0.10000
 XII 1 ,GKS  H2S04/GM C
                        RATE,..CMS II2SQ4/GM..OMIH    CALCULATE) RAf d-GMS-H2S04/GH. CrHtN	
o.oo,v9
0.00343
0.00'i')7
O.OCW2
0 006(36
0.00801
0.00915
0.01029
0.01144
0.01'i29
0.01715
0.02001
0.02287
0.025/3
0.02859
0.03145
0.03't 34
0.03717
0.04003
-0.04288
0.045/4
0.0'i860
0. OS 1 kf\
0.05432
0.05/18
0.06200
0.06862
0.07'.33
. 	 0.00005-
0.085J7
0.001'.9
OiC972l
0. 10292
0. 10864
0 1 1 'i 3 6
0.12580
0.13723
	 .0. 148&7-
0. 16010
0.17154
0. 1829U
0. 19441
0.20565
- 	 - 0.21728-
0.0216960
	 	 0.0199966. 	 	 	 	 - 	 	 	
O.Q1B43U8
0. 01/0509
n r(l IS71/J7
0.01'.47J'i
0.0133122
p,ni?2Ti9
0.0112162
0.008Y'.-20
0,n(u,y|?7
0.0051266
0. 0041636
0.00380LO
0.0035122
0.0032573
0.00''0'<07
0.0028324
0.0026908
0.00?^71N
0.0024755
O.OOZlU't^ '
« 0 . lr'r'
0.0004362
0.0003682
. .. _ .... . . ... Q.nPi"i xrmq
0.0019301
.. . 0.0019333 	 	 	 	 _.
0.0019274
0.0019215
0.0019156
0.0019098
0.0019039
0.0018980
0.0010922
O.OOUI775
0.001B62B
0.0018401
0.0018335
.0.0018108 ,. 	
0.0018041
0. 0017894
0.0017747
0.0017601
0.00174'J4
-.0.0017307 	 - 	 	
0.001*7160
0.0017014
rt f\f\\fftf"J
0.0016/nrv,QAO
0.0005166
0.0005259
0.0005Z95.-
C.EAN DEVIATION  =    0.0014892   ROUT MtAN SQUARC DEVIATION
RESIDUAL SUM OP SQUARES-=^0*2-9836l:-03	:	
MEAN PERCENT DEVIATION  =   47.7267456
                                                                0.0028397
                                                  66
-------
 RUN NUMBER

KAIEC(I)= COEF
            *  149 -G
                           5 10 VI
                 * U-Xin/72) * Y20?**.4)  « (Y02**.63)  *  WI20**.73)
     WHERE  CO£F=  .000159 * CXI' I 5520*{ 1 / ( T «460 ) ) )
             XS=    0.38000          T=  150.00000
   _  ..... „ YSQ2 = ._.- 0.00150. ________ YU2- ...... ..0..02QOO _____________________ . _
           YH20=    0.10000
._ XdJ.GMS- H2SO'i/.GH_C-  - - ..RAIE*-JGHS..H2SQ/1/.GH C-.M1H. . ..CALCULATED. .RATE .1. CHS H2S04/.CM .CrHIN _.
                                                                                               . Dif-ru i.
0.00569
.Q...OQ682 	 __. 	 _.
0.00796
0.00910
... .0.01023 	 	 	 _
0.01137
0.01421
0..01706- _ , .....
0.01990
0. 02274
. 0.0.''i59-.-. .. _ .. — _.
0.0?343
0.03127
0.03412- 	 	
0.03696
0.03980
0.04264 - — - - . -
0.04549
0. 04833
0.05117. 	
0.05402
0.05686
0 O6''i';
0.06823
0.07392
. 0.07960
0.08529
0.09098
. _ . _ _ 	 o# 09666 > • •
0. 1023i
0.10803
n 1 1 17?
0.12509
0.13646
0 14784- —
0,15921
0. 170U8
	 ft t Q 1 f> r:
0. 19332 - -I
0.204?0
0.01<>10UO
	 JO. 01 37051
0.012MOI
0.01-12231
	 	 J) . 0 1 0 1 9 73. 	
0.0092536
0.0071223
... - .0.0054766
0.00't,?3'i6
0.00.1'iH02
_..O.DO?.9137 	 _ .. .
0.0025U99
0.0021960
.. 	 Q. 00202 \'i
0.00190',!
0.0018211
. 	 0..00175&J
O.OOU131
0.0016781
_..- . O.OU16'(3Q
.0.0016106
0.00107S3 J
-U.UU1 •> 102 -_
0.0014569
0.0014029
0-.00l3'il6
0.001305.T
0.001251C
0.001197'J
0.0011439
0.00101J72
0.001^^79
0.000906'>
0.000787"
-0, 00067 7 I
0.0005774
0.0004856
0 .000404 7
0.0003345
0.0002779
0.0015665
	 „. 	 0.0015618
0.0015570
0.0015523
- _. . 0. 0015475
0.001542?
0.0015300
0.0015 189
0.0015071
0.0014952
	 	 _ _ 	 0. 0014833
0.0014714
0.0014595
0.0014476
0.0014357
0.0014238
0.0014L19
0.0014000
0.00l3fi0l
0.0013762
0.0013643
0.0013524
^ r* '« * T i i /
0.00130'iS
0.0012810
n.nni?S77
0.0012334
o.ooi2096 . :-;. •'•
n.oni i nsn .•••'*.'•
0.0011620
0.0011382
0.001 1144
0.0010668
0.0010192
' . , n.nnn^7i A . .
0.0009240
0.0008704
0.0000:'!19 . -
0.0007813
0.0007337
0 . 0 1 3 5 4 1 4
P . 0 K' ! '» 3 J
O.C1U05 !1
0.0096 708
o.oy >'t, '>()'<
0.00/7109
0.00';5915
0.0039*577
o.oo;.' rs.ub
0.lilH99
O.OU04685
0.0003973
0.0003444
0.000313;?
0.0002900
0.000/'66I<
0.0002463
O.OOD2259
o . o o n ' & 7 f.
0.0001.521
0.0001219
0.0000944
0.0000724
0.0000422 "
0.000012L
0.000018!
0.0000510
n.nnnciHAA
0.0001604
0.0002314
0.000,'>94S
0.0003467
0.0003908
O-OOO'.;1/,?
0.0004468
0.0004558
  MEAN  DEVIATION  «    0.0011285   R'JOf  MEAN  SQUARE DEVIATION
  RESIDUAL  SUM OF SOUARHS « 0.19Q76E-03
  MEAN  PEKCCNT DEVIATION = - 39.9634B57	_-,	:	 	
                                                                  0.0023497
                                                   67
-------
   RUN NUMBER =   150-G
5 11 71
        11= COCP  *  ll-X(l)/72l  « Y202»».4) *  (Y02**.63)
     WHKRE COEF-  .000159  *  CXP(5520*(I/(T*460)))
             XS--    0.30000          1=  150.00000
     .._. _--YS02-.--  0.00050	Y02=	0.020CO-.
           YII20--    0.10000
                                                          * (YH20**.73J
.. XII ),GMS H2S04/CK. C	RATE, ..CMS H2-SOWGK.C--.MIN	CALCULATF.O..RA.TE, .GHS H2S04./GM..C-HIN...
                                                                      OIFPtt)
0.00427
0. 00533
0.00640
0.0074V
_ 	 0.00853 	
0.00960
0.01067
_.. 	 	 0.01333 	
0.01600
0.01867
... . .. 0.02133
0.02400
0.02666
0.0793 A
0.03200
0.03'r66
- ... 0.03713 .. _
0.04000
0.04266
0.04533
0.04800
0.05066
Q f\r, i t •»
0.05866
0.06400
0.069J3
0.07466
0.07999
	 - -0.08533 	
0.09066
0.09599
- 0^40133
0.10666
0. 11733
- . 	 0.12799 	
0..13866
0.14932
0.15999
0^17066
0.18132 '
0.0162019
-O.Ol32?'iO
0.0112303
0.0095647
	 . 	 a.oo'a 15 i/i 	 : 	
0.0069400
0.0059054
	 0.0039369 	
0.0026751
0.0013675
. 	 0.0014637 	
0.001211 J
0.0011180
0.0010423
0.0010120
0.0009994
0.0009042
0.0009/92
0.0009691
0. onrioc.no
0.0009489
0.0009413 . '
	 0. "nno-
0.0009110
0.0008984
0.0008732
0.0008505 :.
0.0008303 /. ..: ;:-,
0.0008101 . . •••';'
0.0007849
0.0007621
C. 0007420
0.0007167
0.0006663 ;!
0. 0^06157
0.0005562
0.0004946
. - .0.0004109. 	
0.0003407
0.0002624
0.0010133
	 0.0010104
0.0010075
0.0010047
_:._ 	 _u 	 : 	 0 . 00100.1fl 	
0.0009VB9
0.0009960
	 0. 0009889 	
0.0009817
0.0009745
_ 	 	 	 	 0.0009673
0.0009601
0. 0009529
0.00094'J7
0.00093U5
0.0009313
0,0109241
0.0009169
0.0009097
. .,-0.0009026
0.0008954 :.
0.0008882 -
.... •_ • _ _ _.R.onnnnin . . •• :
0.0008666
0.0008522
Q. 000837ft
0.0008235 ..-•'., :
0.0008091 -:::<:.:>. i..
• '. . L. . n_onfi7Q^7 • ' ., ''•
0.0007803
• 0.0007659
O.OOO?'1!''
0.0007372
'"•-.'. ;,: 0.0007084
.rt,nnphjaf.
0.0006509
0.0006221
n, oOnr>.•:•••<
0.0000212 '*'$
n.nr)oniri'»
0..0000046
0.0000038
n.nnnnnqA
0.0000205 '.,
0.0000421 •.::;'
fi.finoo&39
0.0000956
0.0001275
n.nnoi ?/i4
0.0002239
0.0002734
 HFAN  OCVIAIION -   0.0003888    RUOT  MEAN SQUARE DEVIATION
 RtSlOUAL  SUM OF SOUARfS = 0.37030E-04
 MtAN  I'tRCtNT.DEVIATION.=- -20.6231304	,		_„,	...
                                      0.0010436
                                                  68
-------
RUN NUMBER =  151 -G
                             12 71
 RATECU) = COEF * tl-Xtn/721  * Y202**.'.)  *  IY02**.63) *  (YH20**.73)
    WHERE  COCT= .000159  *  EXP( 5520* ( I/ I T + ',60) I )
            XS=   0.38000          T= 300.00000
      ______ Y-S02 = -. 0.00250 _________ _Y(]2? ___ 0..020QQ ____________ _____ _  _  _________
          YH20=   0.10000                                           ...  ...... ~

_X1I ) ,GMS-H?S04/GM..C ---- IRATE, ...GHS..H2SO'i/CH..C-:MIN. __ CALCUI.ATED..RATI;,  CMS H2S04/.GM. C-N1 N.
                                                                                                IMFP.U )
0.0016*
..0..00327 ..._
0.00491
0. 00655
... . .0.00819 	 	
0.00982
0.01146
O.OI.HO
0.01473
0.01637
. 0..02046
0.02456
0.0286"*
0.0327'i . .
0.03684
0.04093
.0.04502 -
0.04912
0.05321
	 0.05730 	
0.06139
0.06549
0.0695U 	
0.07367
0.07777
0*08186
0.09005
0.09823
0. 10642 -
0. 11460
0.12279
0. 1309.8
0.13916
0.14735
0.0028032
	 — .. 	 JO. 0020756. . 	 , 	
0.0014617
0.0010903.
_. 	 	 	 0.000.9207. 	 	 	 _...
0.00000/6
0.0007268
	 	 ... 0.000666")
0.0006219
0.0005896
.. ... .. 	 0. 000*5330
O.OOOiiO't/
0.0004U45
__. 0..0004765
0.000*684
0.0004644 .
0.0004604 , ,
0.0004563
0.0004483
	 , 	 o . 00044 42_.™ 	 	 	
0.0004361
O.OU04200
ri_nnn/( i
O.OOO'il iv
0.0004078
J3. 0003957
0.0003796
0.0003635
0 .000147?
0.0003311
0.0003109
O.f>00?90l
0.0002665
0.0002463 .
0.0003256
0.0003242
0.0003228
0.0003214
	 	 	 .0.0003200
0.00031U6
0.0003172
0.0003L57
0.0003143
0.0003129
... . 	 	 0.0003094
0.00030'>9
0. 0003024
0.000?9Hrt
0.00029'j3
0.0002910
O.OOQ?fif'.l
0.0002847
0.0002812
	 ._, 	 0.000277V
0.0002742
0.0002707
D,000?67l
C • vwvt.o3£t
0.0002601
0.0002566
0.0002495
0.0002425
0,nno^'4S',
0.0002204
0.0002213
0.00021'. 3
0.0002073
0.0002002
0.0025576
0 .001 /S 1 'i
0.001 13H9
0.00076B9
	 	 .0. 0006007.
0.00040-n
0.000409/
0.000 3l»05
O.OOOJO/6
0.0002766
0.00022 U.
0.000190'.)
O.OOtH«22
0.000 I I'll
0 . 000 1731
0.0001726
0.0001721
0.0001715
0.0001670
	 0.0001665 	
0.0001620
0. 000l'i74
0.00011^6
n, non I A«'<
0.0001477
0.0001391
0.0001301
0.0001210
_ . .. Q..Q0011LU _
0.0001027
0.0000096
0.0000/65
O.OOU0593
0.0000461
 MfrAN DEVIATION =   0.0001712    RCOf MFAN SQUARE  OCVIAT10N
 RES10UAL SUM OF SQUARES *  0.10021E-05
-HtAN -PERCENT-HE VI AH ON-.-	36.7831726—-,,	,	_~
                                                                 0.0001892
                                                   69
-------
RUN NUMBER =  152-G
5 14  71
RATECU 1= COEF
MHERE COEM
XS =
YSQ? =
YH20 =
XII »,r,MS..H2S04/
0.00165
0.00331
0.00496
0.00661
. 	 . . 0.-00827..
0.00992
0. 01157
.0.01323
0.0l'i88
0.01651
0.02066
0.02480
0.02891
0.03J06
0.03/20
0.0'. 133
- 0,04546 -
0.04960
0.05373
	 -0.05786 -
0.06199
0.06613
0.07026
0.07439
0.07853
- - - 0*0 3266 -
0.09093
0.09919
0. 10746-*
0.11572
0.12399
	 0. 13226.
MEAN DEVIATION
RtSlOUAL. SUM OP
* (l-XID/72) * Y202*».4) * (Y02»*.63) * (YH2U**.73I
.000159 * EXP(5520*( 1/IT+460II J
0.38000 1= 300.00000
n.nnisn Yn? = o.o?noo
0.10000
CM C. RATEf CMS H2SO'}62
0.000'iOlB
0.0003902
	 0.000 W,67 	 _..
0.000.1 '.72
0.00032/7
0.000 HI ^1
O.OOOiOU'i
0.0002S8V
. n.non?v*i
0. 000261'.
0.0002536
	 O-0002/i 5.7 	 : 	 	
0.0002380
0.0002302
n oor'JZ?'-
0.0002185
0.0002107
	 .,. 0.0002028
0.0001951
0.0001872 :- -
.'..-'..'.'.. 	 . P, 00" 1795- : .
0.0001717
0.0001599
0.0n0lr'22
0.0000539 ROOT MEAN SQUARE
SQUARtS-S- 0. 17.109L-06 - ._
	 CALCULATED. RAT E ... GHS .H2SU4/GfL£rHI N 	
0.0002654
0.0002643
0.0002631
0.0002619
O.OOOP60B
0.0002596
0.0002585
0.0002573
0.0002561
0.0002550
	 .....-„ 	 	 0.0002521 .. 	 	 	 ...
0.0002492
0.0002463
0.0002434
0.0002405
0.0002376
(l.000,'347
0.0002318
0.00022B9
	 	 „_ 	 0.0002260_ 	
0.0002231
0.0002202
•• • . • ii-onu./i Y <
0.0002144
0.0002115
0-00020RA
0.0002028 .. . .
, '••: . 0.0001970 " '"."•
••'•"•' o.oooi^i y '• •
0*0001854
0.0001796
, , , n.nnn)7^f«
DEVIATION = 0.00008H "-;vv • ;
— 	 O.lPF(.l) ._
0.0004680
.O.OOOJ444
0.0002987 	
0.0002453
0.000215?
0.0001929
0.0001707
0.0002389
0.0001457
0.0001352
0.0001146
0.0000900
0. OOD0015
. .0.000060 /
o.oooo'j';9
0.0000511
0.0000384
0.0000296
0.0000247
.0.0000198 	
0.0000149
0.0000100
U •. WU U U ti j*J.
0.0000041
0.000000-8
0^0000057
0.0000077
0.0000098
n.nnnoi \ 7
0.0000137
0.0000197
0. 00002. Ui

                                            70
-------
 RUM NUMBER =  153-G

RATEC(D=  COF.F
                          5  18  71
               * (l-XIM/72)  * Y202*».4)  *  (Y02*».63) * tYH20**.73)
   WHERt  COtF = .000159 *  FXP(5520*(t/ ,
0.07349
0.07961
0Tnnr,74
0.09186
0.09798
0» ln'»l I
0.11023
0.11636
0. 12240
0.13473
0. 14698
0. \*o??
0.17147
0.18372
	 . . 0. 19597 	 ,_.-
0.20822
0.22046 •
	 ... 0T?^?7i
0.24496
0.25721
	 	 . 0. 26946
0.28170
0.29395
	 -.-0.30620 	 	
0.31845
0.33070
- 	 O.J429',
MEAN DEVIATION = 0.0007441
-HE SI DUAL- SUK-J)r.-_SCUARES-K~.0»
MtAN PERCENT DEVIATION = 39
0.0178058
._ 0.0159658 	
0.0141259
0. 0125234
0.0109802 _
0.0096151
0.006V068
.0.0043921
0.0034128
0.002V599
.0.0024-..72 .._. 	 i 	
0.0022S14
0.0020654
.....0.0020120 	 . . ,
O.U019646
0.0019230
.. ..Q .00 1 Wt'i 	 ,.: 	
0.0018518
0.0018191
	 Q .00 1 7.924 	 	
0.0017628
0.001/3'JO
_.o.noi/,9/s
0.0016559
0.0016144
O.noi r>72fl
0.0015254
0.0014838
n,Ofi)/>TA'4
0.0013829
0.0013355
n.nn) ?R79
0.0011811
0.0010802
0.00097"*
0.0008665
0.0007538
-0.0006'tlO. 	 	 	 —
0.0005401
0.0004570
0.0003799.. , . . 	 	
0.0003264
0.0002849
0.000249 5
0.0002255
0.0002077
_,.0. 0001899. 	 	 	 	 	
0.0001662
0.0001543
_0. 0001424 • 	
ROOT MEAN SQUARE DEVIATION
1 7 7 A-H r- - fi 1
.2494659
0.001919',
	 Q.0019UI 	
0.0019069
0.0019006
0.001H943
0.0018880
0.00187i!.l
0.0018566
0.001840U
0.00 182 5 I
	 0.,00180'K,
Q.0l>ll'i.\r
0.001 7700
0.00] «>22
0.001 /465
0.0017308
	 0.0.017151 	
0.0016994
0.0016836
_— ..0...00 1667-9. 	 , 	
0.0016522
0.0016365
0.001605.0
O.OOl5Mt>
0.0015422
0.0015107
0.0014793 -.•••:
0.0014478 V
	 0.0014164 :
0.0013850
0.0013535
o.onj3P?i
0.0012592
0.0011963
0,001 1H4 ^
0.0010706
0.0010077
	 0.00094. 40
0.0000019
0.0008190
... _. 0.0007562. 	 	
0.000693 1
0.000630't
	 0.0005675 . . ._
0.0005046
0.00044 18
	 	 0.0003789 	
0 0003160
0.0002531
0-000190?
0.0019649

0.015HU63
	 ... .0.0140527
0.0122191
0.0106^2!)
0 . 0 0 V 0 8 S 9
0.00/72/1
0.0048345
0.0025355
0.0015/19
0.000934U
0.00064 /«
0.0004'j 1 1
0.0002H75
0.00'J/"f9(i
0.0002U<1
0.0001 922
	 	 O.OOOU.93
0.0001524
0.0001355
	 	 .__.0. 0001245. ....
0.0001106
0.0001026
O.OOOU9/5
u.OOoOoi j
0.0000723
0.0000621
0.0000461
0.0000360
O.OOD0199
0.0000020
o.ooooini
0.00003',)
0.0000/81
0.0001)6!
...0. .000 1600..
0.0002040
0.0002539
0.000303U...
0.0003418
0.00016?0
0.0003/63
O.OOO'J/,69
O.OU03455
0.000311)2 .
0.0002 I'll
0.0002140
	 . O.OOOIU90
0.0001498
0. 0000988
0.00004/fl ...


                                                     71
-------
 RUN MIUBER «  157 -G
5 31 71
RATECIl)= COEF * Il-XIM/72) * Y202**.4> * (Y02**.63t *  (YH20**.73>
   WHERE COEF = .000159 * EXP15520 *(I/IT4460)))
           XS=   0.30000         1= 200.00000
         _YSQ2=.	0.00200	Y02j=
YH20= 0.15000
.XII) .CMS .H2SQ4/GH..C 	 RATE., _GMS .H2S.Q.'u'GK_C-J-UN 	 CALCULArEO_flAJ£.«__GMS .H2SOV..GM .C-MLN. 	 Plf.F.U )
0.00272 0.0052234 0.0012000 0.0040234
0.00407 0.0039256 0.0011956 O.OOPMnn
0.00543
0.00679
	 0.00815
0.00951
0.01087
	 O.OJ222.
0.01350
0.01698
0.02037
0.02377
0.02716
0.03056
0.03395
0.03735
0.04075
0.04414
0.04754
0.05433
0.05772
	 0 • Oo i-1 £• -
0.06451
0.06791
-. 0.07474)
0.08149
0.08828
0.09r>07
0. 1U186
0.10866
0. 11145
0. 12224
0,12903
- 	 - .0. 13582—
0. 14940
0.16298
-0. 17657 -
0. 19015
0.20373
0.21731
MCAN Of VI AT ION
RESIDUAL SUM OF
0.0025J06
0.0014275
n.OOlPOl? 	
0.0012328
0.0011939
	 	 	 0.0011615 	 _„_
0.0011420
0.001 1096
0.001 lO'll
0.0010966
0.0010901
. . . . 	 -.-0.0010771 	 	 , .
0.0010706
0.0010576
_ 0.0010447
0.0010382
0.0010317
0.0010122
0.0009992
O.OOOV/98
0.0009668
0.000q408
0.0009149 ..:.; '•:•-.
0.0008089 : :
	 ... 0.1008630, ''";••
0.0008371
0.0008110
O.Qnn7A';j
0.0007592
0.0007397
0.0006878
0.0006489
0.0005516
0.0004996
__•-• _ 	 0.0004477
« 0.0000383 ROOT MEAN SQUARE
SQUARES..* 0.57829E-07 	
0.0011913
0.0011870
_. _. 	 	 0.0011827
0.0011784
O.OOU740
	 0.0011697 .
0.001 1654
0.0011546
* ' 0.0011430
0.0011330
0.0011222
	 	 I... 0.0011114 .. .
0.0011006
0.0010R98
0.0010790
0.0010682
0.0010574
0.001046'!
0.0010358
0.0010250
.... ._ 	 _.0.»001DL42
0.0010034
0.0009926
''.:••;• . 0.0009494
', ' 0.0009278
0.0008846
0.0008630
0.0008198
0.0007982
0.0007334
0.0006902
0.0006038
0.0005606
n,0i)0r>174
DEVtATlON -- 0.0000406
0.0013393
0.0002405
0.00010H6
0.0000545
0.0000199
	 	 	 ...0,0000083....
O.OOU0234
0.0000450
0,000040?
O.OOOU3C.4
0.0000:121
	 	 0.0000343 	
0.0000300
0.0000322
0.0000344
0.0000300
0.0000257
0.0000?79
.: . ..:. 0.00002.36
•- ' ' ' 0.0000258 ;
0.0000258
n.onnfMn?
.•" ' ' 0.0000345 .;•
..; 0.0000309' ,
0.0000476
0.0000520
0.0000563
O.OOU0607
O.OOU0586
n. 0000564
0.0000456
0.0000414
0.0000436
0.0000523
0.0000610
Q.000069/

                                                  72
-------
  RUN
      NUMBER =  158 -G
I 71
 RATECIII-  COEF * fl-Xtl)/72) * Y202»*.4)  * (Y02**.63> *  (YH2D** .73)
    WHERE COEF- .000159 * EXP'( 5020* ( I/ ( T K60) ))
            XS=   0.38000          1-  300.00000
    	YSD2«	0..00050	.	Y02=_	0.0.2000		     _	
          YM20=   0.10000                           ~            '            "  "    	~	"

., XU).GMS..H2S04/GM C	-RATE ,..CMS_ H2S0.4/GK .C-K1U. ...CALCIILAT tl)  RATE,..CMS H2S04/GM_C-MIN	  OIFF(| )...
0.00155
O.OOJ1Q 	 .. ...
0.00466
0.00621
. 0..00776 	 , 	
0.00931
0.0108/
O.m2.42 ., 	
0.01307
0.01552
O.XH9'iQ 	 _..
0.02329
0.02717
... J)..031Q5 	 _ „_. ..
0.03<,93
0.03881
	 0.0'>'.>
o.ooo 16 '.a
0.0001630
0.0001613
0.0001595
0.0001577
0.0001560
0.00015'.2
0.000.15 25
0.0001507
0.0001't90
	 0.0001472..
0.0001455
0.0001437
0. 0001420
0.0001402
d.ooonu'i
	 .0.0001367..
0.0001332
0.0001297
0. 0001^6?
0.0001227
0.0001192
0.0001156
0.0001121
0.0001006
_.. .IK 000.10 5. 1..
O.OOOJ6B8
O.OOl.ViH'i
O.OOOl'J/9
0.0001 /OS
O.OuOl',97
0.0001320
0.0001 171
0.0001038
0.0000926
0.0000315
0.0000603
0.0000'.36
O.OOC029a
0.0003.153
0.0003224
0.0000026
0.0000038
0.000009!*
0.0000144
	 0.0000178 	
0.0000212
0.0000239
0.0000258
0.0000278
0.0000297
0. 000031 7_._
0.0000341
0.0000372
O.OOOOHB9
0.0000405
0.0000422
0.0000431 	
0.0000441
0.0000451
__ 	 	 . . Q...OOOQ46Q. ...
 MEAN DEVIATION =   0.0000609    ROUT  MEAN SQUARE DEVIATION
 RES I DUAL-SUM OF-SOUARES_»-.a»28291E-06	
 MEAN PERCENT DEVIATION =   17.356/352
                                                                 0.0000988
                                                   73
-------
  RUN NUMBER =   160 -G
                          6   9  71
 RATECU) = COEF  *  (l-Xlll/72)  *  Y202*».4)  *  (YU2**.63)  * (YH20**.73J
    WHbRi; COCF=  .0001-59  *  EXP I 5520* (I/ ( T *460 ) i )
            XS=    0.38000          T* '200.00000
         _YSf)2 =	Q. 007.00	Y02=	0.02000	
YH20 =
XI 1 1 iGMS..t!2S04
0.00322
0 ..004 11 J
0.006'. 3
0.00804
0-00965
0.01126
0.01287
	 0.01448
0.01608
0. 020 10
0.02413
0.023 1 '.>
0.03217
0.03619
0.04021
0.04423
0.0482'j
0.05227
0.05629
JO, 06031
0.06434
0.06836
0.07640
0.08042
0. OH846
0.09650
0.10455
. . - .. O.-l 1259
0.12063
0.12867
0.05000
/GM C 	 RA.I.E,..GMS_li2.S04/G.H
0.0030573
n.nn?| si?
0.0015207
0.0011031
0.0009377. ..
0.0000274
0.0007328
	 	 	 0.0006697... ..
0.0006146
0.0005358
.-...:., 	 	 .._ . .0.000.5043 	
0.0004806
0.0004728
_ . . _ 	 	 _ 0.0004570 	
0.0004491
0.0004334
0.00r>
0.0004176
0.0004097
0.0004nio
0.0003861
0.0003782
0.0003703
0.0003625
0.0003546
0.0003467
0.0003388
0.0003.309
0.0003309
CL-MUL. CALCULA.T.EO_RATE, .CMS ..H2SOWCM C.-JU.N
0.0005374
0.0005351
0.0005320
0.0005303
0.0005259
0.0005236
_ 	 	 	 	 0.0005? 1.3 	 	
0.0005190
0.0005133
	 . 	 : ._ 	 	 0.00050/6 	 	 	
0.0005018
0.0004961
	 .„._. _ 	 ,.. _.„ _ 0.0004 904 .. . . . •
0.0004U46
0.0004709
'.;. 0. 000473?
0.0004674
0.0004617
0.0004502
• .-• ; ; o. 0004445. :
O.OOC'.33Q
0.0004273
: . : ••;. • • 0.0004043 :. ..•
;';?."•". '-''. •': '•' 0.0003929 ,;; •'•/; \", .
0.0003699
0.0003585
OIFF(t )
0.0025199
0.0016161
0.0009879
0.0005726
0.0004095
0.0003014
0.0002092
0.0001484..
0.0000956
0.0000225
.... 0.0000033
0.0000133
0.0000233
0.0000333
0.0000355
0.0000455
0.0000477
0.0000498
0.0000520
fl. 000054 L
0.0000641
0.0000663
n. 0000627
0.000064S
0.0000612
0.0000577 •
0.0000541
0.0000465
0.0000390
0.0000275
 MtAN DEVIATION -   0.0000670   ROOT MEAN SQUARE DEVIATION
 RfcSIOUAL SUM OF SQUARES = O.?1707!l-06
• MEAN PERCEfJl-DEVlAflON =—13,8535900—	
                                                                0.000091't
                                                  74
-------
RUN NUnilPK =   161 -(!
                         6 10 71
RATECI 1 1- COC-r
WHCKC coor-
xs-
YSU2--
YH20-
X(l ) .CMS .H2';(>4/
0.00292
0.00'. 30
o.oor.H'i
0.00/10
o.o on/ 6
0.01022
O.OIU.H
0.0131 r>
0.01461
0 . 0 1 U 2 6
0.02191
0.02V./.
0.02921.
O.OJja/i
0.03651
O.O'iOl /
.. ..0. U43H2
0.04/47
0.051U
	 0.0547 7
0.051142
0.0620«
0 n A '» r *
0.06930
0.07303
. . .. 0.0003.3
•0.08764
0.09494
0. 10224
0. 109',4
0. 1 I(,!I5
0 . I 2 •'* 1 .5 .
0. 1 1145
0. 138/6
0. 14606
0. 1606 /
0 . 1 / 5 2 /
- 0.189'ia
Ml. AN IKVI AI KIN
Rl 3) * (YH2U**.7.3I
.000159 * tXIM 5520« I I/I 1*4601 1 i
0.30000 1= 200.00000
.. 0.00200 . 	 YU2- ,.0.02.000
0. 10000
•T,;i c. RA.rr, C.MS M;-Mi4/r,n C-MIN CALCULATCU
0.00'.. 97 14
0.0042(17 / 	 	
0.0030/114
0.00] 9/90
O.OO.l.'46U 	 	 _
0.0010481
0. 0009455
0.000(1/22
O.OUIKI429
0.000 flu/. 3
0.000/H'i 1 , 	
o. (10 o//,.-: .1
0.000 /',49
0.0007402 	 _
0.000/25/,
0.000 7 U12
	 0.000/03.',
0.0006963
0.0006963
	 0.0006^90 ....' 	 _. 	 	 	
0.0006P.90
O.OOU6JH 7
11. llt'll'W.M 1 i
0.0006/43
0.0006670
	 	 _. . o.0006T,9/ . 	 	
0.0006523
0.0006W6
	 	 	 •. 	 0.0006210 	 	 	 	 _.
0.00061-1.'.
0.0006010
O.OOOMI64 _ _ .
0.001)571 /
0.000','. /O
0. nnO', 35:1 	 	
0.0004.91 1
0.0004471
0.1)00 J'j'.iO ... - 	
0.0000', 61 ROOT M1:AN SQUARE OEVIATIIIN '
^i IIAUI ( .. n. i I'l'ioi -n/>




RAIT, CHS II2S04/GM C-ttIN
0.00011920
O.OOOBf.ifl6
O.OOOHUM
0.0008UI/
0.00007U2
0.0000/43
O.UOOU/1 3
0.00006/9
0,0000644
0.000li')',«
0.0008471. _ 	 	
0.0000.3115
0.0000299
O.OOOU212
O.OOOH126
0.0008019
0.0007V5 i
0.000/867
0.0007780
..0.0007694 	 	 	
0.0007607
0. 0007521
ri 90<"i '4 TS
O.OOOTVio
0. 0007262
. 0.000/009. 	 	 	 	
0.0006916-
0.0006/44
. 0. 0006571.
0.0006398
0.0006225
0.000605.3 	
O.OOO'.KiaO
0.0005 /o;
0.0005514
0.0005109
0.0004843
0.000449R
0.0000651




OlIIMl)
0. 0050014
0.00 13991
0.002 19.12
0.00109/3
. .0.000 36 / 1
0.0001 / 14
0.0000 ,'42
0.000004 1
0.0000215
0.000049!.
0.0000629
0.0000/62
0.0000/49
o.oooofJin..
0.00001169
0.00001357
0,000091 /
0.0000904
o.ooooaio
. 0.0000404. ...
0.0000718
0.0000704
. 0.0000618. ..
0.0000'-05
0.0000592
0.0000492
0.0000193
0.0000 J6/
. 0.000.0:i4 1
0.0000242
0.00002] 5
O.OOUOU1.9 . .
0.000016 i
0.001,0117
0.00001 1)4
0.00002 /(I
0.00001/2
O.OU00539

                                                 75
-------
KUII NUMHP.R -  162-G
6 11 71
RACC-Cltr- COCF * (l-XtI)/72)
Wllf.KE Cl)EF= .000159 * HXPI
XS= 0.38000
.. .. . .YS02= .0.00200 	
YH20 = 0.10000
XI I ) .GMS-M2S04/CH C- _.RATE-..-
0.00149
.. .. 0.00298 - 	 	
0.00448
0.00597
0.00746
0. 0009'j
0.01044
0.01193 .. . .. . . 	 	
0. 01343
0.01492
0.0186S
0.02238
0.02611
0.02934
0.03)57
0.03779
0.04475 	 ..-. ...
0.05221
0.0596/
	 O. 06 Z 13 	 	
0.07459
0.08205
0.09697
0. 10443
0.11180 ,....___.
0.11934
0. 12680
0* 13426
0. 14172
0. 14918
0. 16410
0. 17902
0. 19395
0.. 20085 	 .... -
0.22377
0123869
- . ... 0.25361 . . . „ .. 	 - -
0.26852 ,
0.28344 '
- 	 0.29836 . - 	 -
0.31328
0.32820
WAN DEVIATION = 0.0010756
Rl MODAL SUM OF SCIIARt-S » 0.4
-MEAN PERCCM DC VI AT J ON . -._ 63.
* Y202**.4)
T= 200.
....Y02--.. 0.
* (Y02«*.63) * (YH20**.73I
460) ) I
00000
(17000
.CMS .H2SCK/GM..C--HIN 	 CALCULATED. .RAT.E, CHS
0.0069869 0.0008954
0.0050647 - .0.0008919
0.0046338
0.0030410
0.0017667.
0.0015929
0.0015639
0.0015.71)4..
0.0016146
0.0016436
0.001 7304
0.0016028
0.001116(10
0.00) 9107
0.0020200
0.002092'i .
0.0021576
0.00220 1 1
0.0022300...
0.0022517
0.0022517
'* ^ C *I 2 ** "Z **
0.0022155
0.0021938
.0.0071504
0.0021142
0.0020708
. 0.-007073-3-
0.0019766
0.0019107
,. 0.001.7956.™
0.0016653
0.0015204
O.UQ13/V/ .
0.0012309
0.0010716
-0.0009051-
0.0007675
0.0006444
.0.000r>3'i8
0.0004344
0.0003692
HOOT MF.AN
0115 lt-04
B6044J1 	
O.OOOU884
0.0008 8 '.»
0.0008(113
0.0008778
0.0008743
	 _._ 	 	 	 	 	 	 0.0008707
0.00006/2
0.000(1637
0.0008548
0.0008460
0.00083/2
. ., . ... 0.00002(14
0.0008196
O.OOOU107
.. _ . _ _ 	 _. ...0.0007931
0.0007754
0.00075/8
. . .„' 	 , 	 	 	 	 	 	 0.0007401.
0.000722S
0.0007049
0.0006877
0.0006696
0.0006519
0.0006343
. . 0.0006166
0.0005990
0.0005637
0.0005460
0^0005 108
0.0004755
0.0004402
0.0004049
0.0003696
0.0003343
	 	 _.. 	 	 0.0007.990
0.0002637
: 0.0002 2 04
0.0001931
0.00015/8
0.0001226
SQUARE DEVIATION = 0.0011491

K2S04/GH_C-.mN 	 OIFIMI)
0.0060915
0.0037455 	
0.0021561
o • o o o u y 5 '(
0.0007151
0.0006897
	 _ 	 0.0007077
0.000/474
0.0007799
.. 	 .. 	 	 0.0000756
0.0009568
0.0010300
	 0.0010903
0. GUI 1491)
O.OOI7.U9 1
0.00l79')'i
0.00131)22
0.0014433
	 „ 	 	 	 0 . 00 1 4 89r; 	
0.0015292
0.0015409
	 	 O.OQ1.55.0Q..... .
0. 0015460
0.0015419
O.Ofll "5161
'.;•' 0.0014976
. ;'..::.. 0.0014718
0.0014129
0.0013/26
0.0012849
O.OOU898
0.001O003
	 ___ 	 	 0.0009708 _..
0.0008613
0.000/3/3
,.. 	 , 	 .. . . 0.0006061 ...
0.0005037
0.0004160
.. . 	 	 	 	 	 0.000'Vt?6
0.0007766
0.0002467

                                               76
-------
 RUN NUMBER  -   163-G
6 1'. 71
RATtC47) „, .-. .- 	
0.0004953
0.0004 4 U.

.RA.Tl:i._GMS..II2S
0.0008851.
0.00080)6
0.0008 lu I
0.0008/47
0.00.08712 	
0. 000867 '/
0.0008643
O.OOOB556
0.0008409
0.000(1 'Jit 2
0.0008296
0.000820'y
0.000111 22
0.00080 )'..
0.0007949
0.000/062
0.0007775 . ....
0.00076CO
0.0007602
O 0 ') O 7 f\ 1 5
0. 000/428
0.0007342
...0.0007255 	 . _.„ 	 	
0.0007001
0.0006908
O . OO06 73 4
0.0006561
0.0006387
ft - OOQ6 21'.
0.0006040
0.000506/
. 0.0005644.. .. __ 	 .
0.0005520
0.0005173
.. 0.0004826 	 	
0.0004479
0.00041.32

	 	 uif-r ( i )
0.0021580
0.0016210 	
0.00 I 1 595
0.0007V 85
O.OOOV162
0.0003788
0.0003083
0.000 2 527
O.OOU2044
0.000 I ft}')
o.oooiov;
o.oooo 1 1 1
o.oooo n 2
0. IM.l'll) !.>;<
0. OIH)l)(i.'> i
O.UOII06 Id
0.0000/26
O.OlKU) / 76
0.0000325
0.00110875 ,
O.OOC08L8
0.0000901
0 » 0000'* L 4

0.0000976
... 0.0000952 	
0.00009/8
0.0001003
0.001)0955 .
0.0000980
0.0000932
O.OOOQ95B
O.OOC0910
0.0000935
.. ..O.DOOOB87 ..
0.0000(130
0.0000742
0.0000'.'. 5 . ...
0.00004 74
0.0000304
 HI Al-j  1)1 VI ANON -   0.0001008    UllllI Ml_Afj
 RIS1UUAI  SUM 01' SoUAKfj - 0.44449J-06
 MIAN  I'iKCi.Nr UI.VIAIION  .  12.0020390  .
                                           '.UUAIU.  ULV1 Al ION
                                                                 0.0001143
                                                   77
-------
ItllN  MJKIU'i
                           6 15 /I
RATtU 1 1= C'lCr- * (1-XII 1/72)
MiCRE COI r- .000159 » CXC
XS= 0.3POOO
.. . . _ .YS02- . 0.00100 .. .
YH2G = 0.10000
Xlll.GMS ll2SO'i/G."! C .. RATlir
0.00146
0.0029?
0.00439
0.00505
0.00711 	
O.OOH7 1
0.01023
0.01 1 10
0.01316
0.01462
0 . 0 1 II ,' I
0.0?1''3
0.02',1, a
o.-'.r.
- 	 0.0621 i ... — 	
0.06579
0.06944
.... 0.0/310 	 — ._
0.0004!
0 . 0 II 7 7 2
0.09503 	 	 • 	
0.102.34
0. 10965
-0.1 1696. 	 	 .. - 	 -
0.12427
0 . 1 3 1 5 1)
O.IJBII'J ... .
0.14620
0. 160fi?
0. 1/544
M.M DrviAIlllN 0.00001.?!!
I'l. Ml.HIAl SUM HI SOUAKI. !> . 0.
<• Y202'> •:•.'.)
(5520*1 )/(T,
T= 200.
. Y02 = .. .0.

IK: ;;rs:;wG
0.0018122
0.0012529
0.000012-)
0.00070)35
. . 0.0006570 .
0. 0006 190
0.000604 t
0.00051)-.,;'
0.0005/4 »
O.OOO'.C.i,!!
0.0005',4'i
0. 0005. U,'»
0. 000 V ? 20
0 .OOOM'ift
0.0005U/1
O.OHO50 l'i
0.00050 J4
0.0004'; 76
0. 0004096
., O.OQO'.')')6
0.000'i'iOC,
0, rinn'.«M/,
.. 0.0004-J96.
0.0004996
0.0004996
0.0004996
0.0004922
0.00048'r7
0 0 0 0 't f * ^ 7
0.00047 73
0. 0004690
• 0.0004661 -

0.0004549
0.000'<4 /',
0.0004 V3
0.0004 176
O.OU03953
KHlll h| AN
1 /069I -06
* (Y02**.63) * (YH20**.73)
460) ))
00000
02000.. 	 	 .... . 	 	 	 	 	 .

M C-M1K .....CALCULATED. RA.T.Ei CHS 11250',/GH .C-'ilN 	
0.0006707
	 	 	 0.0006760 .......
0.0006734
0.0006703
... ... 	 .... . .. ..... 0.0006602
0.0006656
0.00066?-;
	 _ ..... 0.000660J
0.0006'. / /
0.00065-51
_ 	 U.00064U1;
0. OUU64 20
O.OOiK* '54
0. 0006 21! 7
0.000622 i
0. 00061',,!
... . 	 	 	 	 0.0006092
0.0006026
0.0005961
	 0.0005095
0.0005)) 30
0.000576',
	 	 ._ . 	 (j.ouuu.'iv-; ... 	
0.00056:* (
O.OOOli'JMl
0.0005502
0.000-53/1
0.0005240
-0.0005 109
0.0004970
0.0004047
	 	 	 , 	 	 	 	 0.0004/16 _
0.. 0004 5 85
0.00044'.',
	 . . 0.0004 323 	 	
0.0004192
0.000.5930
	 	 	 0. 000.5667 	
.".OUARl OPVIA110H >• 0.00007JO






	 .01 PC II )
0.001 1316
0.0005 761)
0.000 1 V;5
0.00003/7
0.00001 12.
0.0000465
0.00005UH
0.000071 I
0.00001)34
0. 000008 J
O.OUOlO'il
0. 0001050
0.0001 1 Vi
0 . 0 0 0 11 4 3
0.0001 15?
0.000 I 124
0. 00010511
0.0001030
O.OOU0965
0.0000099
O.OOOCKU4
0.0000768
0.00007^?
0.00006 ji
0.0000571
0.0000506.. 	
0.0000449
0.0000393
0.0000?62_
0.0000205
0. 0000149
0.0000055 .....
0.0000039
0.0000095
O.OOOOJ52
O.OOD013',
0.0000247
0.00002RI5. .


                                                     78
-------
                     APPENDIX A-4






S02 SORPTION RATE STUDIES IN 1 INCH DIAMETER FIXED BED
                          79
-------
                                      llAll
                                                            2 7)
   Tl I'l'l iiAK'RE  •   200,->0r>''<0  T
   tl-A'l  VI LOCI 11 ••     O.M'iTlll.  0'<  /MR
   HIM T •,'.);> ''oi r n>Aci )(•*<  (ti'Yi  •     Ct00?uoc
   lldll l(!0 full  ri'A-.TIO'i  »     0.059?i:7
   IHLI.T OXYGI-N  '-'Glf fl'/'llON  "     0«037I.:-3
   INI FT C02 M':,.r HUCTIJ.l  -     O.Of.OOOO
   IMl'T NO HO! F.  niACTH.M «     0,000000
   IH'-ll lilCFiT  6,\S HMC  FRACTION  -  .   0.900S63
   IMI:T CARBON  ULICIJT  •    >:.,nooooi  GMS
   T01AL GAS CLOW »     S.32991;'*  SO!H
                                                           (WET)
TIMI:

0.
20.
40.
60.
CO.
100.
120.
no.
no.
ieo.
200.
220.
240.
26P.
2BO.
300.
320.
340.
360.
ERACC
HOLF

0.
0.
0.
0.
0.
0.
0.
0.
• o.
0.
0.
0.
0.
0.
0.
0.
p.
0.
0.
RATE Of
FRACTION S02

OOOOUOE
'.•COCuC ..
420000L
4700001.
46000GE
560000F

00
J$
-03
-03
-03
-03
7'iOPOOl-03
910POC'!.
lOBCPilC
i ? 5 po or
140POO!
1560i Ot
1 70000!
10200PE
1940001
206POOI
216P001
2?iOPOI
?32000t
•-CJ
-02
-02
-02
-C?
-Ot!
-02
-02
-02
-02
-07
-P.!
S02 SOtPTJON •
H2'.,
GUS
0.
0.
0.
04 LOADING RATC 0
ACID/'.-
OOOOOOC
1", 33 1 0 E-
677?2!>l
o . i oo v ; o i.
0.
0.
0.
0.
0.
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0.
0.
0.
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1 3 i A 7 6 E
16M05E
19<>':<.4E
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?',7317C
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30569ft
3 ? 4 9 Ci V f;
3^V> ] 6i;
35S063F
3631'. 7t.
372 ? 0 7 1!
3BI02/I.
366JP5E
^\ C
00
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-01
00
00
00
00
00
00
00
00
00
00
00
00
00
00
HO
00
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0
0
0
o
0
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0
o
0
0
o
0
0
o
0
0
0
0
0
! II2SO.V SO-?'
/.CID/OM e -I
.OOOOOCif 00
i 1593 ^6f_-02
„ 1&4£!70!--1'<:
. lfc**C78t-02
* X6^' 107E- or
. UL 17*11-02
, l',2709f-OS
.1309-*2E-Ol:
. H9i^rf.-o/
, 107-J /fif-0?
. 9 6 9 £ ? .'? r - 0 3
,8i903r! -03
. 7620'! ?': -d )
*t7t!910r-03
. '.' 9 f> 7 7 V 1 - 0 3
.5126'.vr-03
.4',3370C-03
,387'?'.9r-03
.3J2L.27L-03
1033V6C-02
   AVI RACE K/il T or  .VoflCTluv HP

   TO H LoADi/vg cp  Ji,V  C<«5/icilj/ftt C
              CAS
                     SO? SOUPI IUM  RAff
                                                      3   8
 S"A(T  VI I 0(1 TV  -     r.r>
 INLI  I  ST."1 V;M.I  f ^ACI 10\
 IMf  1  -VC "01  '  rr,ATT |(r,

        CO?  '-'C.l  f  I r.'ACT ION

        I'.I'M GAS  VOL
 IM.I  T  cA'-<"()\  «ricni •    4i.'ocoon
 T'-TAL  f-A.S  H.:i\!      ],, .i.'QPO  f.CfH
                                f  0'.  /n'<
                                l  -     0.002701)
                                 O.OdlC89
                                    0.03'.710
                                 0,0000JO
                                C.000000
                                '< -     0.90746'.
   T I •->(
.•.l'!9.-.:.r
               1 !  f rac 1 1C',  ',('?
                                       XS ACIU/('" C
                                                        RATE Or  H?sn>.  -iOI'PTION
                                                           0VS  AC ID/ d1'. C-VIN
0.
70.
'.C .
63.
PC.
IOC.
!?( .
1 '• " .
!6C.
1 a ^.
™r .
7.T.
?<•' •
n-r.
o.c"r •:':)(
o.i!. •:-•:. rr
0 . 1 d .. '. 00!
0. 1 •;
0,
c.
0.
0.
0.
a
^
j
o
t.

tj? -\
'it,'.
»'><>
•Jf.B
•• v Oii!<. ;n
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- ;.'
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*.96ft / ' [
. H,i,2 ).'!
. l',3is\
. i'j'ni.',(

.(-6 JO'. )f
.'•Oll'd 71
«'j'j'. 7V1I
.OJ/'. ! 11
.'• '36 ';,' -"
.i.397 Ml
• 426? -i j^
.^>19'i76l
00
—03
-03

-03

-0..
-01
-O.I
-03
-0 3
-03
-03
-•03
               or ;,r-j
1«  A  LofitifCt ''/  /.Vf
                             ION •     OO9907Bt-03
                            uf

                             A I )>/(./•/ C  =0. OS'/L-

                              =   /.CO   f)/M-(
                                                                          c  --A/Ay
                                        80
-------
                   S02
                                RATE
                                                 3  '.75
SA-5

TEMPEPATUtU  «   2CO.OOOCSO F
SPACE VCLOCI'il  •     O.fc0?3£.7l. 0"ACTION -    0»CJ9f.9o
INLET OXYGEN' k'-nir FRACTION "    0.0j~032
INLFT CO?  HOI.i  FRACTION •=    OtOOOOOO
INLET NO MOLL  FRACTION  •    O.UOOOOC
INLET 1*1 ra  GAS HOLE Ff;ACTICf. "•     0.9039?:)
INLFT CA'':"'Vi WCIGHT »   ICiiAOOJO QMS
TOTAL GAS  HOW  =     3161299V SCFH
                                                 (WET)
  TIME
  0.
 20«
 404
 604
 80t
1004
1204
'.A04
1504
            MOLC FRACTION S02
              O.OOOOOCE 00
              0.110000E-03
              O.IJOOOOE-OS
              0.210000E-0;!
              0.270000E-03
              04310000E-03
              C4320POOS-03
              C.330000E-03
AVERAGE  RATE OF S02 SORPTHiN
         SAft' t'K 'ji'AniJA- tip
TO
H2SG(, LOADING
CMS ACID/CM C

 O..OOOOCOE 00
 CU3543S2L-C1
 0.701126E-01
 0.10J5'»6E 00
 0.140294E 00
 04174003E 00

 0.23969E-: Op
 O.J5S963E 00

 0.169H5i:-02
                                                     0.1V75.'i?.-;2
                                                     0. 17; S "j;'.--02
                                                     0.170o:SC-C:
                                                     0.166'lTtE-OJ
                                                     o.l6-r.'iu--:2
                                                     o. i6jo^::-:.'Z
                                                     Ot
                      S02 SORf'TJON  RATE
   SA-6
   TFMPERATUHE  •  2004000030 f
   SPACE  VELOCITY .    0.601045E 04  /HR
   INLET  S02  COLE FRACTION (DRYl «     0.002640
   INLET  H20  MULE FRACTION -     0.007703
   INLET  OXrCiPfi MOlf- FRACTION -    0«03'-lp6
   INLET  C02  MOLE FRACTION •    04000000 !
   INLET  NO HOI.f: FRACTION -    0,000000
   INLEi  INERT  CAS KOLE FRACTION -•     0.905-J66
   INuFT  CARBON WEIGHT  «   204720001 CMS
   TOTAL  GAS  FLOW »    7.329909 SCFH
                                                    3  5 71
                                                    (WET)
                                                               0.002487
     TIME
     Ot
    15t
    304
    404
    804
   1004
   120(
   1404
   IfrO.
   H04
              MOLE  FRACTION SOZ
                 O.OOCOOOE 00
                 0.67:>eOOr-03
                 0.£.OC'00'of-03
              p.saocc/of-03

              04120000E-02

AVEHAGE RATE  CF  $02  SOSPTION
                                     H?SO* LOADING
                                     GKJ ACID/GM  C

                                      04000000E 00
    Ot112i!U7f 00

    0.167i.r/l' 00

    o.2i;>6'.tai-: oo
    042366VOE 00

    04127-.45E-02
10 A
                of  /S.'l &M) Acti>/(?n C  -  C./A3E-02
                                                   RATE OF H2J04  tORF'TION
                                                      GMS Acin-'CM C-^a KM
                                                           0. 13670 1;->1J
                                                           0.121C •/•/."••02
                                                           O.ilOi'.'.S-OJ
                                    81
-------
                    SO? SORI'TION  »AU
 SA-7
 TEvPF,.''CTION "    0,000000
 INLET IMrm  GAi KH L FRACTiC'; •     0.6776*8
 INLtT CAkl'.ON Wl'Il.HT  •   62.KI0006 GMS
 VOTAL GAS I LOW  «    20.02
Oi 128CCOF-02
0.12COOCr-02
0.129000O02
0.130000E-02
OF 502 iCRPTION
(If SopfriOfi> vf
of !?.¥ 6MS /kip/
y VtU-KITY ="'
O.OOOOOOE 00
0.245902E-01
	 0.&021S3E-01 	 —
O.S'j5201!-01
0.''OB250F-01
— 0.867062E-01 	 	
0. J03227E 00
Ci 1 200-H" 00
• 0.136V11E 00 • •• •
0.153753E 00
0.1V-0')66E 00
0.810709E-03

fc/ti c = 0-0tl&-0l &M
[yft \— v "
1.50 -ff/itc - -
O.OOOOOOF 00
0.79'-060['~03
0. 76W4**5f -03
0.7620«.1C-03
0. 7()8t*(* S>C*'0>
O.fll967'^f-03 - 	 	 	
0.832'.(!2C-03
0.8269r-03
0.83B886E-03
O.B32<.82i'-C3


S /lOI/S/H C - ftl/V


    5A-0
                    20?.000030 F
    SI'ACF Vf.LDCIlr  =     O.'^3a9'.9l  P/f  /Hi?
    INIF1 502  *LllE  F'lACTI'JN IDRV>  »     0.002800
    INLTT H?0  «OLf  rRACTION «    0.060!,7a
    INLFT OXYGIH  VQLF  FRACTION «    0.03<.gl5
    IHLHT C02  "OLC  FPACTION «    0.000000
    INLFT NO MOIF FRAfTION •    0.000000
    INLET INCRT GAS '•'OLE FRAtTION  '     0.90)716
    INLET CARBON  WEICSHT »   B2.P60000  G^S
    10TAL GAS  FLOW  •    2B.V22999 SCFH
   (WET)
              0.002630
1 |KF

0.
20.
'40.
60.
60.
100.
l?0.
UO.
160.
IPO.
200.
220.
240.
2(,0.
283.
300.
320.
3'.0.
MOLF
	 _.. .
0.
0.
' "~" 0.
0,
0.
0.
0.
0.
p.
0.
c ,
0.
0.
0.
0.
0.
0.
0.
FRACTION S02

OOOOOCF 00
fioooor-o'3
160000E-02 	
205000L-02
?C'.OOOC-02
20:SPOO!:-02 	 —
2c(»000f-02
2060POi*-0?
20^000f--0? 	
2000POI -02
2120POC-02
2) 1000T-02 • '•
22'jOPOC -02
2?'JOOOI -02
230000F-02
2 320POt:-02
2370001-02
2<.'(000l>02
H2S
G'«
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
D.
;j4 LOADING
ACItJ/GM C
dOOOOOC 00
336f."-01
H9'491(.f:-01
9948P1F-01
109468F 00
119<-57f' 00
129243F 00
138624E 00
U7397F 00
10t>2V4f 00
16 2 4'* fir 00
1692&1.F 00
1758 /ft" 00
1B702PI 00
lU73'j!L 00
RATE 0
°us
0
0
0
0
0
o
o
Q
... 	 g
0

— 	 o
0
0
g
0
0
• • — o
F H2SCX. SOBI'
ACIO/G" o"
.UOOOUOE 00
.U577PE-02
.009879C-03
.'.'061 '4F-03
,i06l /'if -03

,'.99<./Dr -03

,
-------
                       APPENDIX A-5


  S02  SORPTION  STUDIES  IN 6"  DIAMETER FLUID BED ADSORBER


                                                        Page

1.  Experimental Results of S02 Sorption Runs  and        84
      Material  Balances

2.  Calculation of Rate of Sulfuric  Acid Formation       88
      from Runs in Continuous Fluidized Bed Unit
                             83
-------
             APPENDIX A-5-1

EXPERIMENTAL RESULTS OF S02 SORPTION RUNS
          AND MATERIAL BALANCES
                  84
-------
   RUN NUMli:U   SA-?l
   UAH     6   » 71
                                 CARIJON
                                              9632'..
  'I Nil  I'  ". '.mill".  i,(i t. Ai-i'.nn
   niiiii i  ;.  MIM iii'.  D,J  r.Ai'i'.iiiJ
    INI I  i  MI/  iDAiilNr, IIM  (.AKhti.i
  "OUT 1. 1 I  Ml/  I.CADIUG  O.I CAI'dfrV

   S02  CON!CI?n RATION  IM  INLFT GAS =
  I.SOX  CDNCfNlKATlUN  IN  I HJ 1'LCT "GAf. -"'
                                              o.'iO  1.
                                              '•,,''•  -•:.
                                           o.o     i r.'i  ;.i)//i u  c.
                                           O.lUfV l.i.S  C,II,VL;1  C

                                                2009. PPM
                                                  16',. PPM .........
   .VULUMl: X  H2II j=  .13.0  X ' "  -:- '• .   :f
   " VuLUFtf 'V"u/"~=' " ''n"2"'i' '   --•—- ..... —----
   CUMCEiaRATIUN OF ,MO=       150.0  PPM
  " TOT AL'7; AS  FL"0-A~RATF== ---------- IZf STf
  U INl.AK GAS VLLOC1TY  =  .. :-;:,;;;-' \?
                                          \- v/ St?C.
                                  200VO
   "TOTAL '.r>PACr Vrt Of. ITY -• •
                                         . " 171'fR .
          S MII i uii.  UITO "i'  c
'lilJVI I I SO/ l.i.AOIMG MM 'CAKIU1N-- ......  "O.PtYj.T  I! US  'S0?/l.!i  C
                                             ;}')'. 6.  PPM
                                             1101. 'PPM
 S(J/  r.LHCrfJl !'.AT IDN  IN  iriLPT GAS "
 Sl,>  Ciii-iCf. Ml i< AVION  [M l,UTl.i;-T  C,AS"
 VIM UMI  '!!  H.'-'il  -'  1 ^.0 '(,
'VU.llH!  '..  I!/'   -   'i .^. K
 ClifJl.l.i^TK'M I (li-l I.I I-   N(J-

"TUAI.  ;;AS  ii.ir/j  KATI:.-=
 t. Ml AK C^S  v/l.ldCIIY

1 Tl'.,v|'t-i',AIUKr       "  -
                                   ?..<' FI/SI.I

                                  l.O DTCT "
"TUI Al.
             i; v/i:f.tiC'lTY ' ='
                                 3')Tr).  "17KR
 p (Hii-i LI s su L i u i<  i n r tj "u r'Ac r o ';<
    Nns SHU-UK  HUT ni: KF
   SUI.fUl;  ACCOUNT f-0  I-UR"
                                        OT'i i '.7  t TI s / i
                                        o.3a/)»

                                        "  "9?..3' 31"
                               85
-------
  rul I I.K i Al.  ll/VL/vrll.l  I'UK  Ml/ :>lliP'ACf. "VL'YOC 1TY"  -     ";s« VI ." T'/illl
               u "ifjiu Ki:AcTtfK' ""=    ""0". 2T;:o "t oS/n,^"
         SULTUK our  oi: KL-ACTOK-     0,203?  LBS/HR
   MAIbKIAL  IlALANCt  FOR S02 SORPT10U
  KUM NUK'BfK   SA-2't         CARQON
  CATC    6 16  71
  PUII I  T  4 SUI.FU'v flN  CAUiif'N    i       ^,'i't  -:',
 MNLM  S()2 LUADIIjr, ON CAKl'OM -     0.0     LBS  Si)2/L»  C
 "cun.i;T  sn2 LOADING  ON CAiunw-'-^onzjo  LIIS  so2/L!rc

  S02 CliiJCL'NTHAl KJ'I IN IMLIl  GAS  -       391)2. PPM
 ' S02 CONCrNTRATIO-l IM aUTLIT'OAS-  	  I'O?:!. PPM

  VIILUMI  •;; 1120  =  I3.o  •;;              .  V ..  •
  ViiLUI-'l:  o 02   :-   't./i'Z    	""    "	~         '	.-..:•..
  CO"IC.[ Nl'RAI ION Ol: ,N(J=      150.0  PPM

 'TOTAL GAS TC'OW  «'ATI.:="  	O6'i ."IV'S'CTIi	~"   	-	-	
 : I. I NF \'\  ;, AS  Vf I.('•(, I I V  •.--       • 2 .0 'f T/ Sl;C

 ~Tf>'Pl RATURT         =-•-  -2TO.'


 '.TOTAL  sPAct: "ycLucirv  --       n,
'POU^CS SULIUR  I,'-iTO KI.'AC'IOK  " 7--"":'  ' U"; •l'>r.T"l l-"/(,R
 POUNDS SULLOR  UUr  Ol-  KfACIdR-     O..U'.6  LUS/IIR
 't si/11 UK A('.COOMI!:I! I-HR
-------
  MATERIAL BALANCE FOR  SQ2 SORPflOM
 RUN  NUf-'nFR   SA-25        CARBON      9612't.
 DATE    6 17  71
       '«"'sUt>'UT<"OM~'C"ARunrr^'"~«"' --------- lyr'nr^-- — - — "—•
IOUTLKT  s SULFUR ON CARBON   = ::,    4.02 •«          :
r INLET  SOP LOADING ON . CARB'UN * ?':' < 0.0-'  l.tiS • SOZ/Lft C
"oo TL e t ' SOT TO AD i HG~IW ~rAr:.^:i::' b.;j7. %   -:  '":'••' •:'"•"•
? INLI'T  S02 LUAUING OM CARBO'M. -.". '- •'•• 0.0:' :>; I.B5 Sij2/LB C
"OUT LET  SC2"LOAinilG ON"C'ARTJaN='"":: ..... 'O^TZt'O-T 3S"-Sa2/TiI C
 SC2  CC.NCENTKATION IN IMLE'T  GAS =      20^>0.  PPM
   2- CONCENTRAT 1 OM" 1'IST T'UTLEr^GAS^;;;"-"- -/i'6-.— PPH
i: VOLUME  ^ H20  -  13 . 0  -''.^l
'•VCL'UMir .:; •02"""'^  ^.3"^      '    ....-^-.
 CCMCENTRATICN  OF N0=      150.0 PPM
TT G T A L' G A'S~nTTlW~ R'A T F=	   1TB S7 U ; SC
JLINFAR GAS Vi:LOCITY =        2.3 FT/SFC
"T EMP'il'K'ATURF
    NOS" SULlHjR"  INTCr'rtF AT,T'HR"'"""   OT/T7F L
 POUNDS  SULFUR  OUT  OF REACTOR-    0.2370  LBS/HR
   -SULCUR" ACCOUNTT.o"
                       87
-------
              APPENDIX A-5-2

CALCULATION OF RATE OF SULFURIC ACID FORMATION
   FROM RUNS IN CONTINUOUS FLUIDIZED BED UNIT
                   88
-------
  CALCULATION OF RATE  OF  SG2 SDRPT10N  FROM
            FLUIDIZEO  BED  RLACTOR
 RUN NUKliF.R   SA-21
 OATh    6   8 71
                           CARBON
5 INLET %  SULFUR OM C ARBON ': •>:.- .
?CUTLEI_ %  SULFUR Ofj CARBON' '""'=-.
""INLCT ~$02"'TOAi)TMO~ ON"C"A'fU$0'r^r
 CUTLET SU2  LOADING DM CARfJOM=
96324.
                                   T. 23' :;r"''5- -;:;''-
                                   "OT'O"" ---- \TDTS' '5G2/L1VT.' ""
                                    0.1168  LBS  S02/LB C
F'S'0'2 CONC t}'iTiTA"T I ON 1 ,N
|SG2 CONCENTRATION  IN OUTLET  GAS=
                                          164.  PPM
                            1'50.0 PPM
 VOLUME  .10?   =  4.2
 CONCENTRATION OF .M0~
i TOTAL GAS  FLOW RATE=.:/-:.::;i:: 12^9. 0 ;.
I; LINEAR GAS  VELOCITY:^ f^    2.'*  FT/SEC
 TEMPERATURE
                            200.0 DEC F
! TOTAL SPACE
AVG
LBS
* STAGE
r
2
3
4
5
6 ,
7
8
P- "i f:t Wt &
ACID LOADING AVERAGE S02 AVERAGE RATE OF
H2S04/LB C CONCENTRATION ACID FORMATION
0.0213
0.0426
0.0662
0.0920
0.1480 ' .
0.1817
0.2266

PPM LbS H2SH4/LH C-HlN '
251. 0.00076
42t>.
607.
808.
10 Lei.
1247.
1507.
1827.
'•• W:-'\' v'.y^k-:^""1' :-!-:'';::'v ::-::' :••'!•/ :'.•:•*' •
••'• ,'•'. :'.-::.'.'::'..: ;: '•'. •'•..': .-.:. • . '. > ;..' '. •• ':•';'• '
0.00076
0.00084
0.00092
0.00092 	
0.00108
0.00120
0.00160
;?;•::. :'-::^':0'.r :'v.':, •;>••': ?-:/-:: •:-'-•: '*-i?\
 OVERALL RATE  OF  ACID FORMATION  =
                                         0.10113E-02
                             89
-------
  CALCULATION OF RATE OF  502 SOrtPTION  FROM
             FLUIDIZF.D BED  REACTOR
 RUN  MUMMER   SA-22         CARBON      9632'f.
 CAJF.    6_ 16  71	^	   ___	^

i INLET v,  SULFUR ON  CARBON •. \--= 'v' •'•• •'.':./ 6 .40' "% '"•,;••';-'. \'":.;-:^.:'^::,:'\';-•
;• OUTLET '*  SULFUR ON CAR30H -'l^'feW; • • AVtjT.X -';"l_"':'"'"' :?'''V 'v'::'.:' ' '•
"iNLl-'-T ^02 "LOADING "ON" CARtic'N ="J  oTo  "   QTs so?7LB"c"
 OUTLC-T S02  LOADING-ON CARBO,M=     0.1.468 LBS SU2/LB  C

F'SU?: "fCj.N.C'il'NI 'RAT IOt.!'"rir"i"NLF.'T" GA "$""="""/ ~TOV6"7""PPM     '.	
! $02  CtNCtiNTKATION  IM OUTL I.T.. GAS=   ;'  <  11 !il . PI>M

"vOLOi'.'i- :'.;"  1120""= 1 i.p""r*    ;--—-—--	-    ,..----.-	—..-
 VOLUf'u K  02   =  /t.2  'S
 CONCOTRATION OF  NO--    _ ir>P«o  PPM      	

? TOTAL GAS FLOW RATS:=,  .  1140. 0' SCFH -  .'".X. V'•-' ::     ':''."
M.INEAR GAS  VELOCITY  =^''_-'JL£^. FT/^ij ,:•:•'  .^ .   '•  ;

 TEMPERATURF          =      200.0  DEC F


[ TOTAL .SPACC. VELOCITY '^}: ;;;;f;'"39's|9/  . I/HRf "?£:;'-'f:.'' '''•.U'-';^;':?';-:'


    '  "   AVG  ACID LOADING,    AVERAGE S02    AVF.RAGE KATE OF
         .LB$_H.2Sn4/Lrj _C_    CONCENTRATION   A C_I 0  PORMAJJOM
f"STAGE. v."w;".,;,' -t~::'-,;• J;].:"/::t^-;^:-^:^                     '''C-i^'

                             -'::y^'••••'Q'• ooiL2/Cii'
   2           0."6'"""    Ibl^"""     "^'^"OT06T21""
   3           0.08R8              190't.            0.00113
   /»         _P«li!.lA_       	?21?'	    0.00132
   5"	..""  "bTl!»3T              2'j^j,            OV00123 ""
   6       .    0.187S              2868.            0.00139
   7.  .      0.227/t^	^^'-^	.	
   B"""	    0."2/72""  **~~~~  ~"^    369i>".  "  "
 OVERALL RATE  OF ACID FORMATION  =
0. 13983E-02
                                90
-------
I
  CALCUIATICN  (!F RATF. OF SD2  SLJRPTION FROM
            FLUID17(:D BED REACTOR
 RUN HUFBER   SA-23       CARBON      96324.
 OATL   6  If.  71
 INLGT £ SULI;UR (JN CARBON " ^.:- '":.;' :f: .0,40 -^
 OUTLET ?,  SULFUR ON CARBON  '  = ''" ' ':: :>4 . 9 I X
 1INLL T SU2 "LOAD I N'G "ON CARROiT "="":	"aYTr"^"
 GUTLf-T S02  LOADING ON CARBON=     0.1008 LbS  SU2/LIS  C

 S02 CONCr^TRATION' IN TNI.FT GA$~=	 ~7.W). 'PPM	
           T RATION IN i:un. tl  GAS=     .    0. PPM
 VLLU^L %  02   =   4.2 %
            ICM OF NO-'      1'jO.O  PPM
; TCVAl. tiAS  FLOW KATt":=     1106.0  SCI M
UlAIUAR GAS  VELOCITY -  .;:   2.1  FT/SCC
 TEMPCRATURE         =     200.0  DEG F
 TOTAL SPACE :VEl OC 11Y -      3*341.  1/HR
 STAGE
   3
   7
   fl
AVG ACID LOADING
LBS H2S04/LB C
• E
o.
0.
0.
0-
6.
0.
0.
0.
008 7
0260
0477
0 70 3
O9'j4 "'
1241
1562
1909 	
- ;' ••:•'" V •'>.':-•.;
AVERAGE S02 AVERAGE RATE OF
CONCf-MTRATION ACID FORMATION
PP 1 LfS
46.
183.
388.
621.
1475. :';'"; '',.'-
'""'
^J-^M'-^^^^f^x'^--'
O.OC035
D.OU071 " ~ ~
0.00009
0.00092
'"0.00103 	 """•"
0.00) 17
. 0.001 U


 OVERALL RATE OF  ACID FORMATION =       0.97531E-03
                               91
-------
  CALCUIATION  OF RATE OF S02  SORPT10N FROM
             FLU IIM ZED BED RFACTOP.
 RUM  NUMBTR   SA~2'i        CARBON      96326.
 CATi:    6  16  71
 INLET % SULFUR C)M  CARBON  . ;. ;. = ;:•; •./-. '^Q .40> % •• v-^',-; •;;:• '^'^.^
 CUT LI: f '<  SULFUR ON CA-sOCM  .V - ^ '*;':.. 5:1 M^X " •£ ••; [^ i ^''-'
 I NLL T" SO?  LOADING"ON CA'R'lUJN ""=."   "oro"""   Ui'S "S'027L'(i" "C"
 OUTLET SO/?  LOADING ON CARUON=    0.1230  LBS S02/LO C
 'Sl)2  CONCENTRAT'lOf!  1 N "IMLFV'GAb"=~Z.'"'
 SC/'  CO.\'Cf.:,NTRATlUM  IN OUTLET  GAb'=."'- •: .  10 /«.
'VGl.UMi.  ;j"ll?0 = 13.0  l^  ":	
 VI,I  UMF.  K 02   =  A .6  £
 CIIMCL'VI KAT ION 01"  N0=      I'iO.O PPM
. TtiTAL  GAS  FLO.fi RAIL"= .: :;  96A . 0 SCt;H :.: :•
 L iMEAft' GAS  VELOCITY  =   ; : . ';'2 .0. .FT/StC"
 TEMPERATURE          =      250.0 DEG  F
                r i n r t i \/ —      TO//   1/tiO
         AVG  ACID LOADING    AVERAGE  S02    AVERAGE  RATt OF
          LOS  HZSO't/LB C    COiJCF>jTRAT ION   ACID FORMATION
fSfAGif " .." •,  '  :.-::'"'' vi^-^B:•:>:"' """T-;"lP>M^^v:;:':O-Li3^n<2S"TjV/"LC7'C-n.
   2           O
   3           0.0730              L795.            O.OOL02
   A    _     _0_. 1002   _____   _?_l?J_*  ____   _ °'001013
   S" .....  """ ""0.1282 '"••".' .;.;:•". .'^~"  2^70^ :••:;•;; -  .~T "o;ob)'ll'
   6      "    0 . I 'i 3 0 :  :'" •••• • ' ••• ; ••- -.-. / -: •'. : 2 7 3 1 v *&•£>:. ""/'"" 0.00099.
   7          _°           '    ''"
   8 ........  "•'" ..... 6
 OVERALL RATE  OF ACID FORMATION =       0. 12288E-02
                                   92
-------
I
I
  CALCULATION OF RATH  OF  SU2 SORPTION  FKOM
            FLUID1ZED  BED  REACTOR
 RUN NUt'BER  SA-25        CARliON      96324.
 DATE    6  17 71
i INLET  -X  SULTUR ON CARBON ";   =       0.40 S     .:;}-•..
'ouii.nr  *. sui.ri'R ON  CARBON   =_      4.0? %    ""•'•",.."
"IW.I.1  SOyTuADI'JG ON "CAlU!'0;-J~="    "C'Yir~'~TfeS''~S'02'/LIV "C"
 OUTLET  SG^ LOADING  ON  CARBOM-    0.0837 LliS S02/LB  C
                     IN  RL CT "GA"S""=' "rT"~-7D7&." PPM'
     CONCENTRATION  IN  IJUVLTT GAS = :;/:^. V'v4 11 .  PPM
' VOi.UMif ^
 VC'LUf'.lI  %  02  =  4.1  ^
 CLU(;t:i\TRATIGM OF N0=      I'iO.O PPK
 TOTAL  GAS  FLO-V KATt=     1 09'j . 0 .SCFH
 L INF. AR CA   V12LOC 1 TY =        2.^
 TCKPFRATURE        =      250.0 UEG  F
STOTAL  SPACF VELOCITY  -      38(v.  I/HR
         AVG ACID LOADING    AVERAGE  S02    AVERAGE RME  OF
          LBS H2S04/LB  C    CONCENTRATION  AC10 FORMATION
STAGI
1
2
3
4
5 ;: : . ;
: 6 i:/v:'': .,'>
7 •:. ":..
8
0.0140
0.0307
0.0464
0.0657
' O.Oi',32
0. 1043
0.1279
0. lb!31
434.
*~ "6"44T
813.
996.
lid/.
1 i»J6.
1621 .
18b6.
                                                 O.OCO'j6
                                                ~0~T)'0'U6T
                                                 0.00063
                                                 0.00077
                                                 OT'OO 0 TO
                                                 0.0008^
                                                 0.0000'j
                                                 DTO'OTG'9"'
 OVFRALL RATE  OF ACID FORMATION =       0.77687E-03
                                93
-------
  CALCULATION OF RATE  OF SC2  SORPTION FROM
            FLUIDIZEO  BED RtACTOR
 RUN Nl)f-T>l:R  SA-26
 UAH    6  18 71
CARBON
96324.
; iNLi-.i  '.r.  SULFUR ON  CAIUWN '   •=  \:. :
lUuriH  '-.; SULFUR ON CARBCN  .'=":•>:"
"iflLLT  S'G2" LH'AUfNG  UM CARlWi" ="*"
 UUTLI. r  SU2 LOADING ON CARBON=

' St)2 CU\C'!:>n RAT I OM  I N I f-OT~ G'A'S" '="
; SC2 CUW.iiNT RATION  IN OUTLET GAS =
         ~ff.~o	CTnrsDz/Ui  c
          0.1210  LliS  Sd2/LB  C

         ._	705'i; "PPM	'"	
'VULUMt.  :;\ H2C'"-" l"'j'.U~'
 VCLUMf  i 02  -  4.3
 C L N C I: N r K A V i Ij N  0 F  \ U =
 LSO-0  PPM
* TOTAL  GAS I-LOW R ATE=  ', ,"1 168 .:0. :SCFH. "-^:
J L INEAR GA-S. VtLOC I TY .="'"."I/:;,,:>;: i ,2'2 .;3;.
 TtMPtRATURE
; TOTAI  SPA'CF VCLOCITY -
 200.0  DEG F
       t>.  l/HR

STAGE
1
3
4
5
(,
7
U
AVG ACtD LOADING
LtJS II2S04/LB C C
^?oJo?7V;S^S
0.0377
0.0583
0.0817
" 0.1068 ..." '
0.1346'
0.1660 •"•:: :-:•'• :
0.19/4
AVERAGE SO
.ONCF..NT.UTI
••fpf>.;vl'5.2:i-'e
324.
S34-
758.
1003.

2 AVERAGE RATE OF
ON ACIO FORMATION
•.,v|p;;i ;vyv :.:• :•• : 0 ; 0 0 0 y 2 ;• ; . ;> !;. 9; ; .- ^: ;.
~^ ' "DTO'OiTbF"
0.00088
0.00099
:::;y'::'";.-':^ .0.00110 ' -t\.'
:;;fe;;":;::'V':;'...0.00133 "-••• .:• •".'"
0.00133
 OVERALL  RATE OF ACID FORMATION =
                0. 10476E-02
                               94
-------
        APPENDIX A-6





MULTIPLE REGRESSION ANALYSES
               95
-------
  DIFFERENTIAL BED DATA -  EFFECT DF  VOLUME FRACTION OXYGEN ON RATE
  RUMS 138,139,144
  VARl = LN 02
  LMRATE/I 1-LOAOING/.38) )
  VAR( 1)=-0.400088E  Oi'f  VAFU  2 ) *-0 i70a355E 01
             ''
  SIANCARD DEVIATTniM^
  VAKI 1>= 0.647692E  00,  VAR(  2)= 0.409425E 00
^SIMPLE CPRREI.AT iriNi  r.npFF i f-l FNTS
  VARS( it  n*  o.iooooe  01,  VARS<  i»  2)= o.98395£ oo

  S TEP Ml.lMRCft   <           FMTii.B A/A3 1 A^f g _ l'
  STANDARD ERROR  OF  ESTIMATE=  0. 7345897E-01
  R SQUARED =  0.9681584E  00
 _ GOODNESS QP  FtT.FI .   It   f^l)= ..... n.?7ft^QO?F Q4
  CONSTANT TERM * -O.<.59506*£  01        AMTJLOG CONSTANT TERM =  0. 1010158E-01
  VAR      CQEFF         STO D£V    T VALUP     BETA COEFF
    1   0.62198E 00  0.118245E-01     52.6013   0.98395E 00
DIFFERENTIAL  BED  DATA  -  EFFECT OF VOLUME FRACTION V»ATER  ON  RATE
RUNS  157,139,160
VAR1  =  LN H20
VAR2  =  LN1RATE/I1-  LOAD ING/.38))
AV^AGFS			
VARI  1J=-0.234333E  01,  VARl 2>=-D.708523E 01
VARI 1)= 0.^^1023E  00,  VAK(  2)= 0.337632E 00

<;IMPI F r.riRRFiATinrj  r.
VARSI  It  U=  O.IOOOOE Olt VARSI L, 2)= 0.9^259E 00

     'NUHBPg.  I  .................. eKrE»..VARl.ARLF  I
STANDARD ERROR  OF  ESTIMATE=  0.1032892E 00
R SOUARtD =   0.907^175E 00
       «; nF  FITTF>    if  92)=
COMSTA:>4T TERM  = •  -. 537632511 01  :      .ANTILOG  COf4STANT  TERM *  0.^62 s:;;; •  STU o=v  ;  :T VALUE     BETA  COEFF
            '       "'
  1   0.72927E  00  0.242858E-01    30.0265    0.95259E 00
                                       96
-------
 DIFFERENTIAL BED DATA - REGRESSION TO FIND ORDER OF S02
                         AND LOADING WITH ORDERS FOR H20 AND 02
                         FIXED FROM RUNS I AND II
 RUNS 139,140,14 ItI42t143,148,149,150,151,152,153,158
 _VAR1 = LN S02	
 VAR2 = I/TEMP                    "                             "
 VAR3 = LN(RATE/(l-LOAD/.38HH20**Mn02**Pn
 AVERAGES	,	_._	. .	
 VARJ 1)=-6.659038E  Ol7  VAR(  2J=  0.152275E-02, VAR (  3)'=-0.2944826 01

 STANDARD DEVIATIONS            	
 VAR( 1)= 0.627714E 00,  VARl  2)= 0.119787E-03, VAR{ 3)= 0.856011E 00
LSIMPLE^CORRELAJION COEFFICIENTS
 VARSJ  I, 1»= O.IOOOOE 01, VAR'Sl  1,  2>=  0.14132E  00,  VARS(  I,
 VARSt  2, 2)= O.IOOOOE 01, VARS(  2,  3)=  0.80794E  00
; STEP NUMBER  1           ENTER VARIABLE  2
: STANDARD ERROR OF ESTIMATE3   0.5050560E 00
_R SQUARED ~ __p..6.5277_2lE_00	:	
 GOODNESS OF FIT,Fl    1,  3~92)=  0.7369407E 03
 CONSTANT TERM = -0.1173662E  02
 VAR      COEFF  	   S,TQ_QEV
                                        ANTILOG CONSTANT  TERM
                                   T  VALUE      BETA  COEFF
                         COEFF
       0.57736E 04 0.212683E 03
                                    27.1467    0.80794E  00
                                                                   0.46« 00
                   0.7995579E-05
  STEP NUMBER  2           ENTER VARIABLE  1
  STANDARD ERROR OF ESTIMATE=   0.4065425E 00
 _R_SQUARED_?	0. 7755923E  00	
  GOODNESS OF FIT,F~(   2,  391)=  0.6756807E 03 :
 CONSTANT TERM « -0.8010632E  01
 VAR      CQgFF         STD  DEV
                                        ANTILOG  CONSTANT  TERM
                                   T VALUE     BETA  COEFF   ;
                   0.3319150E-03
                        COEFF
   1   0.48276E 00 0.330011E-01
__ 2. __ ja*
                                    14.6287
0.35401E 00
0.7579IE 00
                                       97
-------
 DIFFERENTIAL  BED STUDIES - REGRESSION  TO FIMD ORDER OF SOZ                   III
                             AND LOADING WITH  ORDERS FOR H20 AND 02
                             FIXED FROM  RUNS  I AND II
 RUNS  139,1401141,142.1431148,149,150,251,152.153.158
_VAR1  = IN_S02_ _ ,
 V-AR2  * I/TEMP            -.        ,•:•>•„,' v.v ..-  :  ••'   ,   :• .-. .'•<••.••!.'•<•„.:  ':•«..-.  .-:•>   .'.
 VAR3  * tNIl-  LOADING/. 38)       v • • •• VxV"'- •"::'~;v:'.. •"•' ^V'X' •''*••• "': •''•'-'>: . 1?-''-''".',:'-i ..;•• '
                                        '  '          '     '            •   •   "
 AVERAGES
 VARI  1I=-0.659038E 01, VAR( 2)» 0.152275E-02,  VARI  3I—0.253406E 00, VARI  41— 0.319822E 01

 STANDARD  DEVIATIONS    ~~        .       ~                          ~  !
 VARI  II'  0.627714E 00, VAR( 2)> 0. 119787E-03,  VARI  3>- 0.272UOE 00, VARI  4)* 0.912883E 00
 SIMPLE CORRELATION COEFFICIENTS                                                                     '  •
 VARSI  1,  11=  0.10000E 01, VARSI l,'2l«  0.14132E  00,  VARSI 1, 3I*-0.15079E  00,  VARSI 1, 41- 0.38742E 00
_¥.ARS|  2j_2)-_0.1000.0E_Qlt-JMBS.( ..2,.J.L«r0. 1B505E  00.  VARSI 2. 4)' 0.70257E  00	
 VARSI  3,  3)-  0.10000E 01, VARSt 3» 4>«  0.351476  00

_SJ£P...NUMBER_J	ENTEB. VARJLABLE	2_
 STANDARD  ERROR OF  ESTIMATE*  0.6504441E  00
 R SQUARED -   0.4936111E 00
,OOODNESS_OF. F1T.RI	It.. J92J_« _..Q.*3.821084.E_Q3	,	„__
 CONSTANT  TERM • -0.1135137E 02         ANTILOG CONSTANT TERM »  0.1175337E-04
 VAR       COEFF        STD OEV    T VALUE     BETA COEFF    ,.    • >
	:	CO.E£E	,	,	       :/'; •...-><.,;, : .  '.  "
   2   0.53542E 04  0.2T3907E 03    19.5476   0.70257E  00

 	ENI£fi_«A)UABIJE	3_
 STANDARD  ERROR OF  ESTIMATE-  0.4723298E  00
 R SQUARED «   0.7336542E 00
         t  np  FIT,FI    ?.
 CONSTANT TERM  >  -0.1199815E 02        ANTILOG  CONSTANT TERM «  0.6155597E-05
 vAR      COtt-f        b)U UtV    T VALUE     BETA COEFF
	COFFF.    	             	
•   2   0.60573E 04  0.202397E 03    29.9278    0.79483E 00                  ,: *
£ '/J.   0.16726E 01  0.890985E-01    18.7720    0.49B55E 00           .. ,  , '  '^, ..

 STEP NUMBER  3          ENTER VARIABLE  1
 STANDARD ERROR OF  ESTIMATE'  0.3417416E 00
_a_SflUAREO_«	O.B609285E_00._		
 GOODNESS OF  FIT.FI    3, 390)-  0.8047700E 03         .         --'•--   ,Jv: V;>
 CONSTANT TERM  «  -0.7980425E 01        ANTILOG  CONSTANT TERM -  0.3420941E-03
                  	STD DEV    T VALUE	BETA COEFF              : .
                         COEFF
   1   0.52844E  00  0.279714E-01    18.8922    0.36337E 00
  _2	0.51121 E_D4_0.147.447£_flL3____JL8...ILZ5-5	p.75216E 00
   3   0.18299E  01  0.650004E-01    28.1518    0.54S4SE 00
                                                  98
-------
                        APPENDIX A-7





COMPARISON OF MULTIPLE REGRESSIONS TO DIFFERENTIAL RATE DATA
                             99
-------
                                             MODEL A
RATECU I = COEFF *  11-X( I >/XS)**A *  (YS02**B)  *  (Y02**C)  *  (YH20**D)
   WHERE COEFF= K * EXP(-F./R* (I/(T+460) ))

        T=    200.         XS=    0.38      YS02=  0.00200        Y02=   0.007      YH20=   0.100
     -E/K=   5520.         A=   1.000          B=    0.400          C=   0.630         0*   0.730
        K=0.000159
                                             MODEL B



fUTFCII 1 = COF.FF * U-XII)/XS)**A * (YSQ2**B> *  (Y02**C> *  (YH20**D)
   WHERE  COEFf= K * b'XP (-E/R* ! I/ U+460 ) 5)

        T=    200.        XS=    0.38      YS02= 0.00200       YCI2=    0.007       YH20=   0.100
     -E/R=   5416.    ,     A=   1.000          B*   0.480 "        C=    0.620          0=   0.730
        K=0.000332
                                              MODEL C


RATECIU'COEFF  «  ( 1-XI I )/XS> **A  *  (YSC)2**BI  * (Y02**C) * (YH20**D)
   WHERE COEFF= K  *  E XPC-E/R* ( L/(T + 460M )

        T=    200.         XS=    0.38      YS02= 0.00200       Y02=   0.007       YH20=   0.100
     -E/R=   5732.          A=    1.830         B=   0.530         C=   0.620          0=   0.730
        K=0.000342
                                            100
-------
            FU3 HUMBED » 138-G
                                          21 71
Xt.IltGKS HZS04/GM C    RATE, GMS H2SC4/GM C-NJN
0.0024220
0.0017513
0.0012296
0.0008421
o.ooo&ies
0.0005291
0.0005068
O.CCC4918
1.0004844
O.OC04770
0.0004620
0.0004546
0.0004397
0.0004243
0.0204173
0.03040S9
0.0003987
0.0003913
0.0003875
0.0003801
0.0003763
0.0003726
0.0003689
0.0003689
0.0003652
O.C003652
0.0003615
0.0003577
0.0003540
0.0003540
O.OC03540
0.0003502
      _
       O.CC290
       o.co<.;5
       0.005BO
       O.C07.->5
       0.00870
       0.01015
       C.01160 '
       0.01305
       0.01450
       0.01813
       0.02175
       0.02538
       O.C2900
       0.03263
       O.JS625
       O.G3988
       0.04351
       0.0*713
       0.05076
       O.05438
       O.C5801
       0.06163
       0.06526
       0.06888
       0,07251
       0.07976
       0.08701
       0.09426
       0.10151
       0.10876
       0.11602
                                [MODELJl]

                   CALCULATED RATE.  GKS H2S04/GH C-HIN
0.0004622
0.0004604
0.0004567
0.0004569
0.0004551
0.00'J4S34
O.OC04516
0.0004498
0.0004480
0.0004463
0.0004418
0.0004374
0.0004330
O.OOC4286
0.0004241
0.0004197
0.0004153
0.0004109
O.O004064
0.0004020
0.0003976
0.0003932
0.0003887
0.0003843
0.0003799
0.0003754
0.0003666
0.0003577
0.0003489
0.0003400
0.0003312
0.0003223
                                      [MODEL B]

                         CALCULATtO  RATEt OHS H2SC4/GM C-MIN
 O.OOOS268
 O.OOC5248
 0.0005228
 0.0005207
 0.0005187
 0.0005167
 O.POC5147
' 0.0005127
 0.0005107
 0.00050E6
 0.0005036
 O.OG049S5
 0.0004935
' O.OOC48S5
 0.0004834
 O.C004784
 0.0004733
 0.0004683
 0.0004632
 0.0004562
 0.0004531
 0.0004481
"0.0004430
 0.0004380
 0.0004330
 0.0004279
 0.0004178
 0.0004077
 0.0003976
 0.0003876
 0,0003775
 0.0003674
                                        [MODEL C]

                           CALCULATED RATE. CMS  H2S04/3* C-HIN
 0.00064CI
 0.0006357
 0.0006112
 O.C006267
'0.0006223
 0.0006179
 O.OOC6135
 0.0006091
 0.0006047
 0.0006003
 0.0005895
 0.0005787
 0.0005680
 0.0005575
 0.0005470
 0.0005366
 O.OC0526J
 0.0005160
 0.0005059
 0.0004959
 0.0004859
 0.0004761
 0.0004663
 0.0004566
 0.0004471
 0.0004376
 0.0004189
 0.0004C05
 0.0003826
 0.0003650
 0.0003478
 0.0003310
                                                      MEAN DEVIATION -    0.0000186    ROOT MEAN SQUARE  DEVIATION
                                        [MODEL A]    " RESIDUAL  SUf* OF SQUARES  = 0.128506-07
                                                      MEAN PERCENT DEVIATION •>   4.4846649
                                                                                                                             0.0000222
                                        [M03EL B]
                         MEAN DEVIATION «    0.0000531   ROOT MEAN  SQUARE  DEVIATION
                         RESIDUAL  SUM OF SQUIRES  =  0.85176S-07
                         MEAN PERCENT DEVIATION -  13.5773V26
                                                                                                                             0.0000572
                                                       MEAN DEVIATION  =   0.0000939    ROOT MEAN SQUARE DEVIATION
                                        [MODEL C]     'RESIDUAL  SUM OF SQLHRES - 0.27103E-06
                                                       MEAN PERCENT DEVIATION  =  22.8247833
                                                                                                0.0001021
-------
     RUN NUMBER « 139-0
                                        U 2? 71
MlltGMS HZS04/GM C

       0.00294
                                      [MODEL A]

RATE, CMS HZSC4/GM C-M1N   CALCULATED RATE, CHS H2S04/I.H C-HIN
            [MODEL B]
CALCULATED RATE, GHS H2S04/GH C-HIN
                                                                                                                               [MODEL C]

                                                                                                                  CALCULAtED'RATE,  CHS HZS04/GM C-N1N
 0.00589
 0.00736
 O.OOB83
 0.01039
 0.01177
 0.01)24
 0.01-.72
 0.01839
 0.02207
0.02-143
0.03311
O.C3->79
0.040*7
0.04415
0.04783
O.UM51
0.05r>18
0.058B6
0.06254
0.06622
0. 06-190
0.07J58
0.08094
0. 08830
0.0'V>65
0. 10301
0.11037
0.11773
0. 12f.09
0. 13244
0.13980
0.14716
0.16168
0.17659
0.19131
                             0.0070602
                             0.0051134
                             0.0037625
                             0.0021232
                             0.0012E57
                             0.0010750
                             0.0009443
                             0.0008716
                             0.0003203
                             0.0007699
                             0.0007627
                             O.0007462
                             O.0007409
                             O.0007336
                             0.0007264
                             0.0007191
                             0.0007118
                             0.0007046
                             0.0007009
                             O.OU06936
                             0.0006900
                             0.0006864
                             0.0006627
                             0.0006791
                             0.0006755
                             0.0006683
                             0.0006610
                             0.0006538
                             0.0006465
                             0.0006356
                             0.0006247
                             0.0006138
                             0.0006028
                             0.0005B83
                             0.0005775
                             0.0005464
                             0.0005230
                             O.OOC4903
                                     0.0008920
                                     0.0006865
                                     o.oooaaso
                                     0.0008815
                                    "0.0008781
                                     0.0008746
                                     0.0008711
                                     O.OOOB676
                                     0.0008641
                                     0.0008554
                                    " 0.0008467
                                     0.0008380
                                     0.0008293
                                    " 0.0008206
                                     O.OCT08U9
                                     0.000(1032
                                     O.O007945
                                     0.0007858
                                     0.0007771
                                     0.0007684
                                     0.0007597
                                     0.000/510
                                     0.0007423
                                     0.0007336
                                     0.0007249
                                     0.0007075
                                     0.0006901
                                     0.0006727
                                     0.0006553
                                     0.0006379
                                     0.0006205
                                     O.OOD6030
                                     0.0005856
                                     0.0005682
                                     0.0005508
                                     0.0005160
                                     0.0004812
                                     0.0004464

s
' *
•
... x *

?

• • , •'•
t '-',/;

l._t__
''•'::.: !•/'•"•, ••
0.0010060
0.0010021 '.'..:
0.0009982
0.0009942 -: -I .- ' :'
O.C009903
O.O009864
0.0009825
0.00097B5 .: -. <
0.0009746
0.0009648
0.0009550
0.0009452
0.0009354
0.0009255
0.0009157
0.0009059
0.0008961
0.0008863
0.0008765
0.0008666 -•- <
O.D008568 .,:;;•....
0.0008470 !r- S
O.OOOH372
0.0003274
0.0008176
^T" 0.0007979" -.-r-'^
', - ' 0.0007783 ., ' :; ;.•:;:•'
0. 0007587 :,..».
0.0007390
0.0007194
O.OOO6998
0.0006801 -'^'/f- :
0.0006605 '"- -'••-'
	 O.OOJ6409 -; ..,,.
0.0006212
0.0005820
0.0005427
> •:••. ••• -. 0.0005035 ••'.. . ••• -••:•
0.0012185
0.0012096
0.0012CH
:" 0.0011925
0.0011839
0.0011753
0.0011668
0.0011582
O.O01149T
: ; 0.0011286
0.0011077
0.0010370
0.0010664
0.0010460
,: 0.0010258
:-\ ."•. :• 0.0010058
0.0009859
. 0.0009662
0.0009467
.. . ; r: • 0.0009274
;., . , ..'. 0.00090B3
• : • •- : , • •-.'• 0.0008893
O.OO08706
O.OOOB520
0.0008336
7V7T' >,"" "0 x' ":'.'" 0.0007973"'
! - -'• •'•'.-:' : 1 0.0007616
i..' .• '.-. :'"•" : ..,; . 0.0007270
0.0006929
0.0006596
0.0006271
.';••... :, 0.0005952
•>il- •;»• .. Oi0005642
,. . -- /... •'•'., , 0.0005339
0.0005043 	 ~"
0.0004475
0.0003938
'; ••;>.-, 0.0003433
                                          KEAN  DEVIATION =   0.0000556    ROOT  MEAN SQUARE DEVIATION
                           [MODEL A]    "  RESIDUAL SUM  OF SQUARES - 0.1S155E-06
                                          MEAN  PERCENT  DEVIATION *   7.6649427
                                                                                                                      0.0000678
                                          MEAN  DEVIATION  -   0.0031246    ROOT MEAN SQUARE  DEVIATION
                           [MODELS]      RESIDUAL SUM  OF SQUARES = 0.62780E-06
                                          MEAN  PERCENT  DEVIATION  =  17.6211090
                                                                                                                      0.0001379
                                          MEAN  DEVIATION =   0.0031848    RIJUT  MEAN SQUARE DEVIATION
                           [MODEL C]       RESIDUAL SUM  OF SQUARES » -0.15190E-05
                                          MEAN  PERCENT  DEVIATION =  25.8319580
                                                                                                                      0.0002145
-------
                  EOT 3UMS3 » lltO-G
                                              23 71
       ~XiI),GMS H2S04/BH C    RATE, GMS M2S04/GN C-KIN
           [MODEL'A]
CALCULATED RATE. CMS H2S04/G.M C-KIN
           [MODEL B]

CALCULATED RATE, CMS M2S04/GH C-MN
            [MODEL C ]

CALCULATED RATE, CMS H2SO*/GM C-HIN
O
U>
0.00292
0.00437
0.00583
0.00729
0.00875
0.01C21
0.01167
0.01312
O.C1458
O.OU23
0.02187
0.02552
0.02916
0.03281
0.03645
0.04010
0.04375
0.04739
0.05104
0.05468
0.05633 :
0.06197
0.06562
0.06926
0.07291
0.08020 -
0.08749
0.09478
0.10207
0.10936
0.11666
'- . , 0.12395
0.13124
0.13B53
0.14582
0.16040
0.17498
0.004S&33
0.0032855
0.0015552
0.0012923
0.0011317
0. 0010258
0.0009638
0.0009163
0.0008907
: 0.0003431
0.0008250
0.0003141
O.OOOB031
0.0007922
V ; 0.0007849
0.0007776
0.0007703
0.0007630
0.0007557
0.0007520 ' 	 '
0.0007447
0.0007374
0.0007333
0.0007265
0.0007228
: . . 0.0007119
.. .!...'".. 0.0006972
• 0.0006899
0.0006827
0.0006717
0.0006608
0.0006461
0.0006352
0.00062C6
0.0006097
0.0005804
0.0005513 '
0.0001753
., ..^. ..;,.. 0.0009716
... ' >r'r ."•;,=•"'• 0.0009678 . <•
.,--::.: . 0.0009640
0.0009603
0.0009565
0.0009527
:' - .'.' ':•;:',-'•';. '-: 0.0009489
::. -••:. "-. O.OOO9452
•-": "- .;" ->••'.;:'.•' 0.0009357 „
0.0009263
0.0009169
0.0009075
: \ .; .- . 0.0008980
"Cx -'."-.:;•.' J'- , 0.0008886
"'•'.. .';•':• •". ••••.•- 0.0008792
O.O008697
0.0008603
0.0008509
* 0.0008414
0.0008320
0.0008226
0.0008132
0.0008037
0.0007943
	 0.0007754
0.0007566
0.0007377
0.0007189
0.0007000
0.0006811
•!.'"• ,'vi ,,..;.. . 0.0006623 .-.:,>.
'"-.-' ••.-• "-V •'••'i''- . 0.0006434 '•'•
•• • ••>••.-. 0.0006246 ••••'
0.0006057
0.0005680
0.0005303
0.0011198
" ' ' 0.0011155 . . • ;
< ' ' x . 0.0011112 ' -.'.:;".. •
0.0011069
0.0011025
0.0010982
O.O010939
' , ' 0.0010895 - 	
o.ooioe52 '•'.. :
O.OO10744
0.0010635
0.0010527
•0.0010419
0.00103H ,:.;.-. ... • ,: •„
'•'•••' • 0.0010202 :!: '.'f.: ':. . • > - '.;
, , 0.0010094
0.0009986
0.0009878
0.0009769
'"•"" -,""' 0.0009661 '
< O. 0009553
, . 0.0009445 ' ,
0.0009336
0.0009228
0.0009120
, 0.0008903
0.0008687 '
< . 0.0008470 j.s-i
0.0008254
0.0008037
0.0007821
<•"- - ??:. ;'• •'**>!,•' 'IK**-.' • O.O007604 • '» '' •• v
:'v- •:,'•;'•; v '"V- ;;1".-" ', j • ' 0.0007388 ' ' •.•
•., .,"' 
-------
                  R'JH NUMBER • lUl-0
                U 26 71
o
-p-
               H2S04/GM c
RATEt'GMS H2S04/GM C-M1N
           {MODEL A]

CALCULATED RATE, CMS H2S04/GK C-MIN
           [MDDEL 3]

CALCULATED RATE. CHS H2SC4/GH C-KIN
           [MODEL C]

CALCULATED RATE, CMS M2S04/GN C-HIN
0.00146
O.C0296
0.00444
0.00592
0.00740
0.00888
0.01036
0.01184
0.01332
0.01480
0.01650
0.02220
0.02590
0.02960
0.03330
0.03700
0.04071
0.04441
0. 04611
0.05181
0.05551
0.05921 .:• :
0.06291
O. 06661
0.07031
0.07401 •"
C. 08141 *
o.cesei
O.C9621
0.10361
0.11101
0.11842 . > ... -
-. ' 0.12582 ." ' '
0.13322
0.14062
0.14802
0.16282
0.17762
0. 192*3
0. 0051181.
0.0042197
0.0023197
0.0011415
0.0009353
O.OOOD359
0.0007843
0.0007511
0.0007364
0.0007253
0.0007217
0.0007106
0.0007032
O.OC06959
0.0006849
0.0006775
O.U006702
0.0006628
0.0006554
O.OG064tiO
0.0006443
0.0006407
0.0006333
O. 0006260
0.0006223
0.0006149
0.0006038
0.0005928
0.0005818
0.0005671
0.0005523
•:•-• 0.0005339
1 C. 0005192 '
0.0005008
0.0004823
0.0004640
0.0004234
0.0003866
0.00
O.OOO7981
. - ., ;. • •••(•• 0.0007950. •••:•• •••••'.
.:i ' ''^::':;' ;VX:.; 0.0007919. v,'";;.>^.--.
••-••-•-•• 0.0007883 v
O.O007856
0.0007825
0.0007794
0.0007763
'-•'•;.. O.OC07732
• 0.0007700
0.0007622
0.0007544
0.0007466
. ,..;, : 0. 0007388
0.0007310
- :- '."••• 0.0007232 - - -
0.0007154
0.0007076
0.0006998
"'•' , . • 0.0006920
: -••'. . O.OOC6842 •• :• .•: :•
'.',">:'••.*• •: .: ~ <>.s .., . 0.0006764 '.-.-' •'."•'.
0.0006686
0.0006608
0.0006530
0.0006452 •;.•:?•,< '-. '•'••:
0.0006296 .'"••: '.V ?.'.
0.0006140 ' : . •".
0.0005984
0.0005828
0.0005672
- V "•« '!•:•' C" ••• 0.0005516
.••-.• ' ; •'/; 'I ; :": 0.0005360
: -.•;• •"' " 0.0005203
0.0005O47
0.0004891
0.0004579
- . 0.0004267 . • .
• •' ••.;'.• -'-A.: 0.0003955.' *.V "':
0.0008797
i .• • : .: . O.OOOS762
«.Jt; ,-:-.;• .„ .-v:;-'.;: ., ,~ o.ooos728
' ...• *.»:•::. ...' • O.OOOB694
O.OOOS659
0.0006625
O.C008590
0.0008556
0.0008522
0.0008487
O.U00640I
O.O008315
0.0008229
0.0006143
. ,-, O.C008057
0.0007971
O.CU07B35
0.0007799
0.0007713
- ~ :'- ;;•<:.?-•;. .. c.0007627
: :•::•••• .!.": •'" 0.0007541
'':•';'•,; '"\ -x ">•'.-'•; ; .. 0.0007455
0.0007369
0.0007283
0.0007197
.:; J-;v;:-'' yfyit^'Kfi'::,, 0.0007111
••••-;-,' • -:•. •'•:.' ; ^^^Ki^:5.<:.^^:V 0.0006939
,•':•''•* •' fc^vST-'.lAii: ' 0.0006767
0.0006595
0.0006423
0.0006251
" ; 0.0006079
*, - O.O005907
0.0005735
0.0005563
0.0005391
0.0005047
•.<.:., •..-.-.• ., • 0.0004703
•::. "••': ,*,:,'::> ...|-;"..- ,. 0.0004359
0.0010536
0.0010461
0.00103S6
0.0010311
0.0010236
0.0010162
O.OC10038
0.0010014
0.0009941
0.0009067
O.OOO9685
0.0009504
0.0009325
. O.OO09148
'• 0.0008972
0.0008797
0.0008624
0.0008453
' O.OOOU2U3
• 0.0008115
0.000794B
0.0007783
0.0007620
O.OO07458
0.0007297
•. , 0.0007139
:. ' 0.0006826
0.0006519
0.0006219
0.0005926
0.0005639
•';•"'• : 0.0005358
>"•'•:*'-. ':-• >"' . 0.0005084
:. i ••::. ...; : •. 0.0004316 	 _
0.0004555
0.0004301
0.0003812
•• •-•••;. ••-, ••-• • •:."' • 0.0003350
'•"'.' •'••' ' ..•:' ; : : •'-'•- 0.0002915 ':•'
                                                     MEAN DEVIATION =    0.0000328   ROOT  MEAN SQUARE DEVIATION
                                        [MODEL A]      RESIDUAL SUM OF SQUARES = 0.40Z35E-07
                                                     MEAN PERCENT DEVIATION -   5.5525742
                                                                                         0.0000349
                                                  "MEAN DEVIATION  =    0.0000982   ROOT  MEAN SQUARE DEVIATION
                                       [MODEL B]      RESIDUAL SUM OF SQUARES = 0.32985E-06
                                                     MEAN PERCENT DEVIATION =  16.2963409
                                                                                          0.0001000
                                                     MEAN DEVIATION  =    O.OOC1283    ROOT MEAN SQUARE DEVIATION
                                        [MODEL C]      RESIDUAL SUM  OF SQUARES * 0.7V487E-06
                                                     MEAN PERCENT  DEVIATION =  19.5493622
                                                                                          0.0001552
-------
            RU3 NUMBER
                                        U 27 71
XIII.CMS HZSO*/CM C     HATEt CMS H2SO*/G« C-HIN
       0.001*".
       O.OC2S8
       0.07431
       0.0057'i
       0.00719
       0.00843
       C. 01004
       C. 01150
       O.Cl*38
       0.01797
       0.02156
       0.02516
       0.02575
       0.03235
       0.0359*
       0.03953
       0.0*313
       0.0*672
       0.05012
       0.05191
       0.05750
       0.061 10
       0.06*69
       0.06829
       o.oTiae
       0.07907
       0.08626
       0.093*4
       0. 10063
       0.10792
       U. 11501
       0.12220
       0.12V38
       0.13657
       0.14376
       0.15814
       0.17251
0.0050370
0.003*817
0.0021380
O.OOP9639
0.0008334
0.0007573
0.0007067
0-OC06740
O.OCQS559
0.0006522
0.0006*1*
0.00063*1
0.0006233
0.0006160
0.00060b8
0.0006016
0.00059*3
0.0005870
O.C0057V8
O.CU05762
0.0005689
0.0005617
0.0005561
0.0005508
0.0005*36
0.0005*00
0.0005290
0.00051S2
0.0005073
0.0004965
0.000*655
0.000*7*7
0.000*638
0.0004*93
O.OU043*9
0.0004204
0.000391*
0.0003623
             [MODEL A]

 CALCULATED RATE. CMS H2S04/GM  C-MIN

            0.000678T
            0.0006761
            0.0006735
 _.    .    0.0006710
            0.0006684
            0.0006658
 	   0.0006632   _
            0.0006607
            0.0006501
  _     _   0.0006555
          ~ O.OC06'.91
            0.0006426
	    __   O.OO0636Z
            C.OC06297
            0.0006233
            0.0006168
            O.OCQ610*
            0.0006040
            0.0005975
 "	    • 0.0005911
            0.0005046
            0.00057B2
            0.0005717
            0.0005653
            0.0005509
            O.OOC5524
            0.000539S
            0.0005266
            0.0005138
            0.0005009
            0.0004880
            0.0004751
            0.0004622
_.	 ..  . 0.0004493
            0.0004364
            0.0004235
        	  0.0003978
            0.0003720
                                                                     [K032L B]

                                                        CALCULATEO~~RATEt GMS  H2S04/OM C-MIN
             [MODEL C]

CALCULATED RATE.  CMS H2S04/GM C-MIN
0.00072*2
- ••••'.:*:. 0.000721*
:•: . : • : 0.0007187
:•', :. • . • 0.0007159
0.0007132
0.000710*
0.0007077
0.00070*9
0.0007022
L-** ~ 0.0006994 . •
0.0006926
0.0006857
0.0006788
;:A- : •: . :>-:.:. 0.0006719
•;"j:- •"> ::'i 0.0036651 -'"•'"
"•\: : ': ••• O.noa65B2
O.C006513
0.0006*44
O.C006376
0.0006307
0.0006238
O. 0006169
0.0006101
0.0006032
6.0005963
O.OOC589*
0.0005757
0.0005619 :.-.
O.OC05482
0.00053*4
0.0005707
. 0.0005069
0.000*932
0.0004794
0.000*657
0.000*519
0.000*24*
0.0003969
o.oooasoo
0.00084*1
. O.OOOU383 :•
0.0008324 	
0.0008265
0.0008207
0.0008149
0.00011091
:. . • - 0.000803*
. ' . : 0.0007976
0.0007833
0.0007692
0.0007551
V-;; ,,;• ,.-. ,-, .i ; 0.0007*12
••- . •"':::'•' •".• 0.0007273
:. '• •.••••"•. , f 0.0007136
0.0007001
0.0006866
0.0006733
,,- ::,;,% ; 0.0006600 . •
ii.s.,. •;.•••?•••.... 0.0006*69 -'-'•''
• '.. 0.00063J9 .
0.0006211 "'
0.0006083
0.0005957
f •••>-. '^., •:,• V :-,'•.• -0.0005832 ,-• '. . '
•:••'••• •-. ,.' • 0.0005585 ' .
•-..-'?• .. :i,:;;^-y:< :-? 0.00053*3 ••' ' '• .•
0.0005107
0.000*875
0.00046*8
•v • - •' •• '''• 0.000**25 -'
>;V .''•"/. '•;<..• 10.000*208 " , ,
-• • 0.0003996
0.0003789
0.0003587
0.0003197
• . ,i. 0.0002828
                                                 MEAN DEVIATION  =    0.0000107    ROOT MEAN  SQUARE  DEVIATION
                                    I MODEL A]     RESIDUAL SUM OF SQUARES  = 0.579355-08
                                                 MEAN PERCENT DEVIATION »   1.8738451
                                                                                         0.0000135
                                                 MEAN DEVIATION  «    0.0000444    ROOT MEAN  SQUARE  DEVIATION
                                    [MODEL B]     RESIDUAL SUM OF SQUARES  - 0.68234E-07
                                                 WEAN PERCENT DEVIATION "   8.1341553
                                                                                         0.0000462
                                                 MEAN  DEVIATION -   0.0000788    ROOT MEAN SQUARE  DEVIATION
                                    [MODEL C]     RESIDUAL SUM  OF SQUARES  « 0.25634E-06
                                                 MEAN  PERCENT  DEVIATION «  13.9007187
                                                                                         0.0000895
-------
             SKI TOXBEH - 1U3-C
            U 28 71
XII I.CMS H2S04/GX  C    RATEt GM$ H2S04/CM-C-MIN
       0.0014*
       O.OC293
       0.00*35
       o.ooseo
       0.0072*
       0.008IS9
       0.01014
       0.01159
       0.01304
       0.0144*
       O.OIB11
       0.02173
       0.02536
       0.02898
       0.03260
       0.03622
       0.03985
       0.04347
       O.U4709
       C.C5071
       0.05434
       C.05796
       0.06159
       0.06520
       0.06883
       0.07245
       0.07969
       O.08694
       0.09418
       0.1C143
       0.10867
       0.11592
       O.12316
       0.1J041
       0.13765
       0.14490
       0.15939
 0.00336B3
 0.0021586
 O.OOIC10J
 0.0008330
 O.C006990
 0.0005157
 0.0005577
 O.CC05216
 O.CC.G4962
 O.OC04BIT
 0.0004745
 O.C0046J6
 0.0004564
 0.0004527
 0.0004455
 0.00043B2
 0.0004346
 O.C/004310
 0.0004238
 O.OC04201
 0.0004165
 0.000*129
 0.0004093
 O.O004056.
 0.0004020
 0.0(103964
 0.0003943
 0.0001B75
 0.0003B03
 0.0003730
 O.OOC36SB_
 0.00035S6
 0.0003477
 0.0003404
 0.0003332
0.0003223
0.0003006
                                 [MODEL A]

                    CALCULATED RATE, CMS H2S04/GM C-MIN
 0.000514J
 0.0005124
 0.0005104
 0.0005084
 0.0005065
 0.0005045
 0.0005025
"O.OC05006
 0.00049B6
 0.0004966
"0.0004917
 O.C004R68
 0.0004019
 0.0004769
 0.0004720
 0.0004671
 0.0004622
 0.0004573
 0.0004523
 0.0004474
 O.C004425
 0.0004376
 0.0004326
 0.0004277
 0.0004228
 0.0004179
 O.OC04080
 0.0003982
 0.0003833
 0.0003765
 0.0003687
 0.0003588
 0.0003490
 0.0003391
 0.0003293
 0.0003194
 0.0002997
                                       {MODEL B]

                          CALCULATED  RATE. CMS H2S04/SH C-MIN
            [MODEL C)

CALCULATED  RATE, CMS HZS04/CK C-KIN
0.0005192
,'": .,: ,.. ;.. 0.0005172
; ' 0.0005152
'.-•••:'. :. 0.0005132
0.0005113
0.0005093
0.0005073
0.0005053
* - - '- . 0.0005033
0.0005013
O. 0004963
0.0004914
0.0004B64
0.0004814
,-' 7' ' 0.0004765
. - ~ C.OC04715
0.0004665
O.C004616
O.O004566
..v-f.) ... s- , 0.0004514 , '
::";,v*- -".. 0.0004467
:.:< i ;:,: 0.0004417
0.0004367
0. 0004318
0.0004268
O.OOC4218
0.0004119 :, .: : ."..'.
0.0004019 '•''•'
0.0003920
0.0003821
0.0003721
'" 	 "' 	 0.0003622 .\/ ;,.:,- .
O.OOO3523 ' : - ' ~
0.0003423
0.0003324
0.0003225
0.0003026
0.0005887
0.0005845
O.O005004
0.0005763
0.0005723
0.0005682
0.0005642
0.0005601
0.0005561
0.0005521
0.0005421
0.0005322
-0.0005224
0.0005127
0.0005030
.: 0.0004935
0.0004840
0.0004746
0.0004653
'• . •.:•: 0.0004561
•:.; 0.0004470
, J .. \-~ -:'• 0.0004379
0.0004289
0.0004200
0.0004112
-X ' ••.-;.-:•. '!.-•,.•••:... O.OCC4025 •-
'•• .-.•..; .' : •: O.C003685 • •
0.0003520
0.0003358
0.0003200
• . ,. - ; •;'"-. ' ... . 0.0003046
' "• ' •'- • -•••:- - - 0.0002894
•". ,:.-.. „'. ,.;: 0.0002747
0.0002603
0.0002462
0.0002191
                                                MEAN DEVIATIOM  =    0.0000173    ROOT MEAN SQUARE  DEVIATION
                                  [MODEL A]      RESIDUAL SUM OF SQUARES  = 0.13874U-07
                                                MEAN PERCENT DEVIATION -   3.9458380
                                                                                         0.0000212
                                                MEAN  DEVIATION  =   0.0000202    ROOT MEAN SQUARE  DEVIATION
                                  [MODELS]   '   RESIDUAL SUM OF SQUARES  = 0.174A8E-07
                                             '   MEAN  PERCENT DEVIATION =   4.6428303
                                                                                         0.0000237
                                                MEAN  DEVIATION =   0.0000443    ROOT MEAN SQUARE  DEVIATION
                                  [MODEL C]     RESIDUAL SUM  OF SQUARES = 0.76i88C-O7
                                                KEAN  PERCENT  DEVIATION  =  11.0762110
                                                                                         0.0000496
-------
           E'JTf SVMEER • liU-G
                                       29 71
XIDtCKS H2S04/GH C
                     KATE, CHS H2SC*/GM C-MIN
           [MODELS]

CALCULATED RATE, GMS H2SO4/SM C-MIN
            [MODEL B]

CALCULATED RATE, CHS H2S04/GM C-MIN
            [KOBE! C]

CALCULATED RATE,  CMS HZSOWGM C-MIN
0.00213
O.CO**0
0.00596
0.00713
0.00830
0.01026
0.01173
0.01330
0.01*46
0.01833
0.02199
0.02566
0.029J2
O.C32TJ
0.03645
0.0*032
0.0*3*9
O.C*7i5
0.05132
0.05*98
O.C58S5
. 0.06231
0.0.6598
0.0696*
0.07331
1 o.caoi*
0.08797
O.C9530
0.10263
0.1C936
0.11730
"! ' .' 0.12*63
0.13196
•:" 0.13929
0.1*662
0.16128
0.1759*
0.19061
0.20527
0.0053*89
0.0037517
0.0025251
0.0015452
C. 001*26*
0.0013559
0.0013001
0.0012518
0.0012035
0.0011367
0.0010995
0.0010810
0.0010698
0.0010623
0.00105*9
0.0010*7*
0..0010'.00
0.0010326
0.0010252
0.0010215
0.0010178
0.00101*1
0.0010066
0.0010030
0.0009992
0.0009918
; '. 0.00098*3
. 0.0009769
0.0009658
0.0009509
0.0009398
0.0009212
0.0008989
' O.OOOB766
0.00005**
0.0008060
0.0007577 •
0.0007058
0.0006538
0.0012691
0.00126*1 " '
0.0012592
" 0.00125*3
0.0012*93
0.0012***
0.0012395
0.00123*5
0.0012296
0.0012173
0.00120*9
0.0011926
0.0011803
0.0011679
0.0011556 " .".-*,
0.0011*32
0.0011309
0.0011186
0.0011062
0.0010939 •.>"%.'- <•>'.-. • •• JS<,v. ;.' ••• ..;••
0.0010816 •:•-•"": ,',,.. ••" " ••v":- <••••
0.0010692 •• "•-•••• ' ' ' • •" • :-'f'''i' '•'••'• "-'
0.0010569
O.O010**5
0.0010322
'". 	 """ 	 o. 0010075- •C:^.V:.-:;;T;";:U:;-; S^;;:':'?^'1
0.0009829 v:^;;" !'.- ' .'' .i "' f$":r- -'••
0.0009582 • • ••• • ••'• :-.. •• •• :•;••-:•. .: . ,
0.0009335
0.00090S8
0.00088*2
. :•'.';,';"-,• ' ;;,..?:.•.?! vV*'S."';.k 0.0003595 'V^ " ;••;' >;':.- • 	 „"
'•'*•*••':• ••-.;-•'••*.• '."•'•' 0.00083*8 ':'r '' '-' : • • •• •
•"'• ' '< . :i i l: o.oooeioi ..:.;!.. :•
0.0007855
0.0007361
0.0006868
• .•• ":'..:Y- ::-.i: 0.000637* •: ,~ ,y\r. - :'•.-• -"*..:., ••>.,.••:•
•-. . . •:--. .-. . • • ;;-• •:-.. 0.0005881 -.:.:., v.:. >••/: ^ - •<'•• «-:'-\?* •• i...;>-
0.001*233
0.001*178 : -
0.001*123 ;V
0.001*067
0.001*012
0.0013957
0.0013901
0.00138*6 -.
0.0013791 ">;•'" '"'"'
0.0013652
0.001351*
0.0013375
0.0013237
O.OOU099
0.0012960
0.0012822 •
0.001268*
0.00125*5
0.0012*07
0.0012269 ••:-•:• : .•„ '
: 0.0012130
0.0011992 •!..
0.001185.3
0.0011715
O.OOU577
O.OOU300 '•'•'' '; • ;--'V •;:>•
0.0011023 : ":M:. •,- •';.••
: . 0.00107*7 >•;'•' • .'• '
0.0010*70
0.0010193
0.0009916
0.00096*0 .».--.
0.0009363 ' ''•
0.0009086
0.0008809
0.0008256
0.0007703
0.00071*9 , : .
?,;. 0.0006596 . ' ":.',•••• •'/..
0.0017239
0.0017117
0.001699S
0.0016873
0.0016752
0.0016631
0.0016510
0.0016390
0.0016271
0.0015973
0.0015678
0.0015386
0.0015096
0.001*808
0.001*523
'.••••• 0.001*2*1
0.0013961
0.0013683
0.0013*08
- '•• •-:,:.. '•,!..... . s 0.0013136
0.0012866
: ' :•;•: 0.0012599
0.001233*
0.0012072
0.0011812
. ';. :;.••...;•• ,.,;. ; . O.OOU301
;. •.;••..•.,*, ,::;.;•;.• 0.0010799
• .;::.>:^;.. :. '•' 0.0010308
0.0009828
0.0009358
0.0008898
i..:.i .::• *'•:•', o.oooe**9
: •••••: ' • .- o.oooaoio
•.. ,:;;.. 	 •'•;.; .-.• 0.0007592
0.0007165
0.0006363
0.000560*
• ; ; ,-•- 0.0004889
V.'j'-;/'.>-viv.«i- 0.000*219 ••••'• •
                                              MEAN  DEVIATION =    0.0090647   ROOT MEAN  SUUARE DEVIATION
                                 [MODEL A]     RESIDUAL SUM Of SQUARES « 0.17218E-06
                                              MEAN  PERCENT DEVIATION  *   fa.5631943
                                                                  0.0000712
                                              F.EAN DEVIATION -    0.0001368'  ROOT MEAN  SQUARE DEVIATION
                                 [MODEL B]     RESIDUAL SUM OF SQUARES * 0;8886lE-06
                                              MEAN PERCENT DEVIATION «  13.0999966
                                                                  0.0001617
                                 [MODEL C]
  MEAN DEVIATION  »    0.0002509   ROOT  MEAN SQUARE DEVIATION
  RESIDUAL SUM OF SQUARES = 0.27905E-05
  Hf-AN PERCENT DEVIATION =  2
-------
                  ROT KUMBEB « 1U5-C
U 30 71
       XII),GHS HZS04/GN C    RATE, GHS H2S04/GH C-HIN
                   [MODELS]

        CALCULATED RATE, GHS H2304/SM C-HIN
           [MODEL B]
CALCULATED RATE, CMS H2S04/GH C-HIN
            [MODEL C].

CALCULATED RATE, GHS H2SO4/6H C-HIN
O
CO
0.00290
0.00436
0.00531
0.00726
0.00871
o.oioir
0.01162
0.01307
O.C1452
0.01915
0.02178
0.025*1
0.02904
0.03267
0.03630
0.03994
0.04357
0.04720 .
0.05093
' . 0. 05446
One ano
O.C6172
0.04535
0.06698
0.07261
"" 0.07987
0.08713
0.09429
0.10165
0.10391
0.11618
0.12344 -
'•' 0.13070 '
0.13796
0.14522
0.15974
0.17426
0.0064766
0.0051453
0.0037780
0.0026626
0.0014752
0.0010650
0.0010218
0.0009931
0.0009715
O.C009319
O.COC0031
0.0003616
O.OC08635
0.0008455
0.0008312
O.OOOP203
O.OCOB096
0.0007988
O.OOO7916
0.0007644
OPOfl 1777
0.0007700
0.0007628
O.O007556
0.000752C
0.0007412
0.0007268
. '.. : 0.0007124
0.0006980
0.0006764
0.0006621
0.0006405
0.0006225
0.0006009
0.0005793
0.0005362
0.0004893
0.0008921
-.-•; .'••.•>:..• 0.0008887 ' - *
:, '-"',\\:. ";;';.•.•; ,'.o.oooas52 "" ' ^
' " .'•"••'•'' 0.0008818 < ..
0.0008783
0.0008749
0.0008715
> ,,J c - - 0.0008680 *'•*
0.0008646
; '• * - ' - 0.0008560
0.0008474
0.0008388
0.0008302
0.0008217
0.0008131 f
0.0008045
0.0007959
0.0007873
0.0007787
, V ;. „ . : . 0.0007701
-•••-.• .--•••-• '- -,-:' ' •' A non7&is
. •'. '•. •'''. *;: '"'/' ..;. : 0.0007530 .
0.0007444
0.0007358
0.0007272
'" ' 	 0.0007100 	 ' "
0.0006928
0.0006757 	 .._. 	
0.0006585
0.0006413
0.0006241
, ,, 0.0006069 - - • •
" "' ' ,' 0.0005898 . ' -v, , ,
0.0005726 . 	 ' 	 ,
0.0005554
0.0005211
0.0004867
0.0010061
0.0010023
O.OOC9984
0.0009945
0.0009906
0.0009868
0.0009829
O.C009790
0.0009751
__ 0.0009654 ^1 : • '.' ... . .
0.0009558
0.0009461
0.0009364
0.0009267
0.0009170 '
0.0009073 •••.'• • '
O.OOOS976
o.oooaa»o
0.0008783
0.0008686 • . • . ;•-•• . •; • • .,.
OOOC8589 •" " ""
0.0008492 '^i'--. ••• ' ;•>•? i--
0.0008395
O.O008298
O.C008201
0.0008008 .r.,-,. .:. . : - .
0.0007814 •?.-'••/ ~:'^- ' . 'f--- -i •:"'•'
0.0007620 '•' 'I--. '"',-• ,.". '' .'• •' -
0.0007427
0.0007233
0.0007039
• 0.0006845 .-'-. '•:•-•: •" : • 'V. , '/. '
0.0006652 ••• •• • '•• •'•
0.0006458 . ' ' £":" ' '
0.0006264
0.0005877
0.0005489
0.0012187
0.0012101
0.0012016
0.0011930
O.OC11846
0.0011761
0.0011677
O.C011592
0.0011509
0.00113CO
0.0011094
0.0010869
0.0010686
0.0010484
0. 0010265
O.OC10037
0. 0009890
0.0009696
0.0009503
0.0009312
0 .C 009 123
0.0008936
O.OC087SO
0.0008566
0.0008384
• O.OOOS025
0.0007674
0.0007329
O.OG06992
0.0006661
0.0006339
0.0006023
0.0005715
0.0005414
0.0005120
0.0004556
O.OOC4021
                                        [MODEL A]
         MEAN DEVIATION =   O.O0004I8    ROOT MEAN SQUARE  DEVIATION
         RESIDUAL SUM  OF SQUARES » 0.11267E-06 '
         MEAN PERCENT  DEVIATION »   4.9554777
                                                                                                                       0.0000594
                                                      MEAN DEVIATION  =    O.CC00602   ROOT  MEAN SQUARE DEVIATION
                                        [MODEL B]       RESIDUAL SUM OF SQUARES = 0.13U6E-06              ... ......
                                                      MEAN PERCENT DEVIATION -   7.9813900
                                                                                                                       0.0000640
                                                      MEAN DEVIATION  =   0.0001177    ROOT  KEAN SQUARE DEVIATION
                                        [MODEL C]       RESIDUAL SUM  OF SQUARES = 0.58060E-06
                                                      MEAN PERCENT  DEVIATION =  14.6390228
                                                                                                                       0.0001347
-------
           HOT HUMEH « 1U8-G
                                     5  7 71
                                                         [MODEL A]
[MODEL B]
XCD.GHS H2S04/GM C    RATE, CMS H2S04/GM C-KIN  CALCULATED RATE, CMS H2S04/C1 C-MIN  CALCULATED RATE, CMS H2S04/GK C-H1N
             [MODEL C]

CALCULATED RATE,  GHS HZS04/CH C-HIN
C. 00229
0.003*3
0.00*57
0.00572
0.00686
0.00801
0.00915
0.01029
0. 01141.
	 0.01429
0.01715
0.02031
0.02237
' 0.02573
0.02659
0.031*5
0.03*31
0.03717
0.0*003
0.0*238
0.0*57*
0.0*860
0.051*6
0.05*32
0.05718
O.C6290 ...,../
0.06862 . '
0.07*33
O.CS005
0.06577
0.091*9
7 o.o972i ; •
0.10232 : ,
0.10364 ...-•.-
0. 11*36
0.12530
0.13723
•0.1*867 ' '
0.16010
: 0.1715*
0. 16298
0.19*41
0.20535
0.21728
0.0216960
0.0199966
0.018*388
0.017051)9
0.0157197
0.01*473*
0.0133122
0-0122359
0. 0112162
O.OC87520
O.O067127
0.0051Z66
0.00*1636
0.0038010
0.0035:22
O.OOJ2573
0.0030307
O.C02S3Z4
0.0026908
0.0025718
0.002*755
0.00238*9
0.0022999
0.0022262
0.00215D3
0.0020337
0.0019090 .
0.0017957
0.0016936
0.001597*
0.0015068
0.001*218
0.0013312
0.0012*57
0.0011669
0.0010196
0.000889* '
0.0007760
0.0006798
0.00059*8
0.0005155
0.000*362
0.0003682
0.0003059
0.0019391
V'«..;:.- ^ •-• - 0.0019333
'. ..•-*.".:: -"".. 0.0019274 '
', • • -: 0.0019215. . ,
0.0019156
0.0019093
0.0019039
0.0018980 -. .; , :>•
.• .' .,,',••.' - 0.0018922 '..':.-•'" '';-,-'. • : '
• 0.0018775 . " '
0.0018628
0.0018*81
0.0018335
, . -,,;. . •-...! 0.0018188 <
..' -; >; f,' : 0.00180*1
0.001789*
0.00177*7
0.0017601
0.0017*54
0.0017307
0.0017160 s
, * " 0.0017014
0.0016867
0.0016720
0.0016573
0.0016280
0.0015986
0.0015693 * -<
0.0015399
0.0015105
0.001*812
• •'•:•.••• •-'•'-'• 0.0014518 •;•• :- ", ' •':•..• : '.• -.
".".x.C'' •,"%<- '•.:>': . 0.001*225 ' >''•*•..*« f .'i- '•..%* - '••-•''>'''' .<;''
: .... . •-• -;x: . <;- .•:*...;. 0.0013931 :•;•„•,•-... -.-v^. ... ....
0.0013638
0.0013051
0.0012*63
. .. '-:•:. •-,... 0.0011876 :;, -••••'•.-. :>
" •' <':•-,. :Ai?j..;.;. - O.OOH289 l's.,\ '-.-. .r.;: '• :. •:•... ,:• :f: -,:,-
:'-• •• •: "••'• 0.0010702 •••••-•< •• • .. : .. •;,...
0.0010115
0.0009528
0.00089*1
; ....;.. 0.0008354 ' .
0.0021979
0.0021912
0.00218*5
0.0021779
0.0021712
0.00216*6
0.0021579
0.0021513
O.OC21**6
0.00212bO
0.0021113
0.00209*7
0.0020731
0.0020614
C..00?0**8
0.0020282
O.OC20115
0.00199*9
•O.OC19783
.. 0.0019616
0.0019*50
O.C019284
0.0019117
0.0018951
0.0018784
O.OOl8<-52
0.001B119
O.OD177S6
0.0017*5*
0.0017121
0.0016788
0.0016*55
0.0016123
0.0015790
0.0015*57
0.001*792
0.001*126
Q.0013'61
0.0012795 .:
'••• 0.0012130
0.0011*65
0.001C799
0.0010134
0.0009468
0.002«03i
0.0027881
. 0.0027726
0.0027572
0.0027413
0.0027264
0.0027111
0.002695B
0.0026806
	 0.0026*27
0.0026050
0.0025675
0.002530S
.: : 0.002*934
0.0024567
0.002*202
0.00238*0
0.0023481
. 0.0023124
V '." 0.0022769
0.0022*17
• , •••' -A... 0.0022067
0.0021720
0.0021376
0.0021033
• •••-• • -"'."•''•;-;: •;.:. v; 0.0020357
..;.:.: ' •' 0.0019690
' . >'- ... > 0.0019033
0.001B387
0.0017750
0.001712*
;, -, ,. ".":;•• .•, .: . 0.. 0016508
. . " ":' :,. 0.0015903
: ' ... "".*• 0.0015307
0.001*722
0.0013583
0.0012*96
„ - ' .:; . O.OOU430
. .,..:. ;..'. •••••.':.: : . 0.0010418
•••• • • • •' '•• X . . 0.0009*48
0.0008521
0.0007638
0.0006798
, . •;.;. '.,' ; D. 0006004 ..
                                              MEAN DEVIATION  =    0.0014892   ROOT  MEAN SQUARE DEVIATION
                                [MODEL A]      RESIDUAL SUM OF SQUARES = 0.29836E-03
                                              MEAN PERCENT DEVIATION "  47.7Z67*56

                                              MEAN DEVIATION  «    O.OOJ4-132   ROOT  M(-A,M SQUARE DEVIATION
                                [MODELS]      RESIDUAL SUM OF SQUARES = 0.27639E-03
                                              MEAN PERCENT DEVIATION =-  51.2974701

                                              MEAN DEVIATION  =    0.00.'1621   RUOT  MCAN SCUARE DEVIATION
                                [KOI-EL C]      RESIDUAL SUM OF SQUARES * 0.23324S-03
                                              MEAN PCRCCNT DEVIATION =  33.4808197
                    0.0028397
                    0.0027331
                    0.0025108
-------
           RU3 NUMBER »  1U9-0
5 10 71
Xltl.CHS HZSO*/GK C    pATEt CMS H2SO*/GH C-MIN
                    [MODEL A]

        CALCULATED RATE, CMS H2S04/CM C-HIN
            [MODEL B]

CALCULATED RATEi GHS H2S04/GM C-MIN
             [MODEL C]

CALCULATED RATE. CHS H2SQ4/GH C-MIN
0.00569
0.00682
O.C0796
0.00910
0.01023
0.01137
0.01*21
0.01706
0.01990
0.0227*
0.02559
0.026*3
0.03127
0.03*12
0.03696
0.03930
0.0*26*
0.0*549
O. 0*633
O.C5H7
0.05*32
0.05686
0.06255
0.06623
0.07392
'< 0.07960
O.OB529
0.09093
0.09666
0.10235
0.10803
0.11372
0.12509
0.136*6
0.1*78*
0.15921
0.17058
0. 18195
0. 19332
0.20*70
0.0151080
0.0137051
0.012*101
0.0112231
0.0101979
0.0092536
0.0071223
0.005*766
O.OC".2356
0.0029137
0.0025B99
0.002196D
0.002023*
0.00190*1
0.0018211
O.OU17563
0.0017131
0.0016781
0.0016*30
0.0016106
0.0015703
0.0015162
0.0014569
0.001*029
0.0013516
0.0013058
0.0012518
O.OC11979
0.0011*39
0.0010872
0.0010279
O.OC09065
O.OC07878 ::
0.0006771
0.000577*
0.000*856 '
0.000*0*7
0.00033*5
0.0002779
0.0015665
<• .,..":. 0.0015618 ,-. ,,,:..,.
0.0015570 : '••
0.0015523
0.0015*75
0.0015*27
0.00153CB
0.00151E9
. • ••-.';•'' ••>••'• 0^0015071 •-•:.;••<:..::;•:-,:-:
0.001*952 '•'..'
0.001*833
0.001*71*
0.001*595
:, - : ••••• >. ' 0.001**76
" V;,7'.' '•'.' 0.001*357
-..! 0.001*238
0.001*119
0.001*000
• 0.0013801
.. . .„• v.. ; . 0.0013762
. : , . ;..;K:-/S" 0.00136*3
• ;- : •'•" 0.001352*
0.0013286
0.00130*8
0.0012810
	 o.ooi2572 ;r^: -:';••'; ".,' :
0.001233* '" ':-'V; '•',/-"•'-' •'• •
0.0012096
0.0011058
0.0011620
0.0011382
•:•<••_ ., ••, .; :..>.:• .•'. 0.00111** ,- ' •, .
~ -••--.. •:•••-•• 0.0010668 •-. : . . .
(,' •':-'••:••'.:' , o.ooioi92 :«•--:•>;;. :.-^L;
0.0009716
0.00092*0
0.000876*
'• '•••• '•;• 0.0008289 ' ' '
	 -',.-.- '-. . 0.0007813 • '•-.: -... .-
. :: •• : '•:'.. 0.0007337 t 	 - : ;
0.00170*5
<-.. ..." . •••:. •••!'••' 0.0016993
->•>• •:• ''' :.';?• 0.00169*1
' 0.00168B9
0.0016837
O. 0016786
0.0016656
:••:'•' • •'-;' ••• 0.0016S27
f > .-' ' ; 0.0016397
. ; ." 0.0016268
0.0016138
0.0016009
0.0015679
0.0015750
;, 0.0015621
O. 0015*91
O.CC15362
0.0015232
0.0015103
0.001*973
0.001*8**
0.001*71*
0.001**55
0.001*197
0.0013938
,. . ?\.f .;.:: •.:,'-.,.:.• 0:0013679 . -
:V> ; .-.-:;- -• .", 0.0013*20 . •.• ,
-,-.', ••:.'- '••• ''••- '.--' 0.0013161
O.OC129C2
0.00126*3
0.001238*
.•.v,:-.-.- :u.:' 0.0012125 . . .
->,;:•• ,;.\ .,.;<- 0.0011607 '''-
' ::„. .,:....-, :'. O.OOU090
0.0010572
0.001005*
0.0009536
0.0009018
. . ;. ..... 0.0000500
.. •;•-• •" .. 0.0007983
0.0021036
0.0020V19
0.0020802
0.0020570
O.OU2045S
O.OC2C167
O.OOIS3BI
0.0019'j97
0.0019315
0.001903*
O.OOIH756
0.0018*79
0.0018204
0.0017931
0. 0017660
0.0017391
0.001712*
. 0.0016859
0.0010595
0.001633*
••'":. 0.001607*
0.0015560
0.001505*
0.001*555
• • •- • 0.001*06*
'•••-•• 0.00135S1
. 0.0013105
0.0012637
0.0012177
0.0011724
. :- ' 0.0011280
.". 0.0010*1*
',"••'.' " 0.0009580
0.0008777
0.0008006
0.0007268
0.0006562
0.0005889
0.00052*9
                                [MODEL A]
        MEAN DEVIATION =    0.0011285   ROOT  MEAN SQUARE DEVIATION
        RESIDUAL SUM OF SQUARES « 0.19876E-03
        MEAN PERCENT DEVIATION =  39.9634857
                                                                                                                0.0023497
                                [MODEL B]
         SEAN DEVIATION  *   0.0010806    ROOT MEAN SQUARE  DEVIATION
         RESIDUAL SUM  OF SQUARES = 0.18962t-03
         MEAN PERCENT  DEVIATION) »  40.9921875
                                                                                                                0.0032951
                                [MODEL C]
         MEAN DEVIATION »   O.OC09072    ROOT MtAM SQUARE  DEVIATION
         RESIDUAL  SUM OF SQUARES =  0.16619E-03
         MCAN PFRCF.NT DEVIATION *   25.7657623
                                                                                                                0.0021485
-------
          R'JS rUMBES • 150 -G
                                     5 11 71
                                                         [MODEL A]
[MODEL B]
[MODEL C]
XdltGNS H2SO*/GM C    RATE,  CHS H2S04/GM C-MIN   CAtCUUATEO RATE, CHS H2SO*/6M C-H1N  CALCULATED RATE, CMS  HZSO+/GH C-HIN  CALCULATED RATE, CMS H2S04/GM C-H1N
0.00427
O.C5533
O.C0540
C.C0747
O.CI553
O.C0960
0.01C67
0.01333
0.01600
• 0.01867
O.C2133
0.02*00
0.02566
0.02933
0.03200
0.03^66
0.03733
o.o<-ooo
0.0*266
0.0*533
0.0*833
0.05266
0.05333
O.C5666
0.06400
O.C6933
O.C7466
0.07999
O.OS533
O.C9C66
0.09599
0.10133
C. 10666
0.11733
0.12799
0.13666
C. 1*932
- - - - 0.15999
0.17066
0.18132
0.0162019
0.01322*0 ' ' -.-
0.0112303
0.00956*7
0.009151*
0.0069*00
0.005905*
0.0039369 , , ,'i
0. OUZ6751 - ';•• ' •
0.0018675 '•''•"• 1
0.001*637
O.OC12113
0.0011180
0.0010*23
0.0010120
0.0009994
O.0&098*2
O.G009792
0.0009691
O.OC0959Q 	
0.0009*69
0.0009*13
0.0009312
0.0009110
0.000898*
O.OU08732 . 	
O.O008505 •
0.000(5303 - :
0.0008101
0.00078*9
0.0007621
0.0007*20 " - ' ' ;; .
0.0007167 ,V, •.•£•:".;'-;
0.0006663 . ;- ", • ....
0.0006157
0.0005552
0.000-'.9*6 '
0.000*189 . • ••
0.0003*07 ., . .. .:'.,
0.000262*
0.0010133
• •< • ' c. 001010* '•: "•.-.•.'•. V: .'•••:••,•- ;.~
0.0010075 •...'••;','.'•'• •"'•If •"-'..
. 0.00100*7 •".': ..... -.:'.:..< •'.,
0.0010018
0.0009989
0.0009. 0.0009385 ;". v ; .'•,-.;;•
'• 0.0009313 . -. , . .':<•-'•">
0.00092*1
0.0009169
'0.0009097
0.0009026
0.000895*
0.0008882
0.0008810
0.0008666
0.0003522
" ,. 0.0008378 :.. -: :.»; ..
0.0008235 ;-. • >'-; " '
0.0008091 ' . ' /',
0.00079*7
0.0007803
0.0007659
->' 0.0007515 : 	 : ;V .: ,
0.0007372 . ' •.••
, v . 0.000708* •' . .,-.
0.0006796
0.0006509
0.0006221
0.0005933 . ' > -: :•-, ...-•.;
'•":(•.• 0.00056*6 ;...;..;,-.,. •!•:„;: :.:-•••• f* 3 :-:-&
0.0005358 ' ' . :~ • .
0.001009T
0.0010069
0.00100*0
0.0010011
0.0009983
0.000995*
0.0009925
•;..-.'• 0.000985*
0 .0009782
: 0.0009711
0.0009639
0.0009557
0.0009*96
. 0.0009*2*
0.0009352
0.00092B1
0.0009209
0.0009137
0.0009066
0.000699* - '
0.0006922 • '•'•,'
0.0008051
0.0008779
O.C008636
0.2008*92
0.00083*9
0.0003206
0.0008062
0.0007919
0.0007776
0.0007632
0.0007*89 '.; •
0.00073*5
0.0007059
0.0006772
0.0006*86
O.OC06199
. '-: 0.0005913
:V V 0.0005626 • " I -:.;'
' : . O. 0005339
C. 0011833
0.0011771
0.0011710
0.00116*9
0.0011589
0.0011527
0.0011*67
0.0011316
0.0011165
0.0011016
0.0010868
0.0010720
0.001057*-
0.0010*28
O.OC102U*
0.00101*0
0.0009997
0.0009855
0.0009714
-. "• 0.000957*
. .:.«• ' 0.0009435
"-' : ' ' 0.0009297
0.0009160
O.OOOBSBS
0.0006620
O.OC08355
. , -• •••' '• 0.0008095
> - ....' . 0.0007838
0.0007585
0.0007336
O.OCC7090
•; , ..;.,... .. ... 0.00068*8
0.0006610
.: .: 0.00061*6
0.0005697
0.000526*
0.000*8*6
': 0.000***.*
. . - - 0.000*057
0.0003687
                                              MEAN DEVIATION «    0.0003888    ROOT  MEAN SQUARE DEVIATION
                                 [MODI, A]      RESIDUAL SUM  OF SQUARES - 0.37030E-04
                                              MEAN PERCENT  DEVIATION «  20.6231384
                    0.0010436
                                              MEAN DEVIATION =   0.0003903    ROOT MEAN SQUARE  DEVIATION
                                 [MODEL B]      RESIDUAL  SUM  OF SQUARES = 0.37110E-04
                                              MEAN PERCENT  DEVIATION =  20.6951752
                    0.0010447
                                              MEAN DEVIATION =   0.0003336    ROOT MFAN SQUARE  DEVIATION
                                 [MODEL C]      RESIDUAL  SUM OF SQUARES = 0. VU41 E-04
                                              MfcAN PERCENT DEVIATION  t  U.1673651
                    0.0009962
-------
                  RUT) KUMBEH - 151-0
                                             5 12 71
                                                                [MODEL A]
[MODEL B]
                                                                                                                                    [MODEL C]
        XU1.GHS MZSO*/GM C   RATE, CMS  H2SOVGM C-HIS   CALCULATED RATE. CMS H2S04/GK C-HIN CALCULATED RATE. CMS H2SOWGM C-HIN   CALCULATED RATE, CMS H2S04/SN C-f
t-0
0.00164
0.00327
0.00*91
0.00655
0.00819
O.OC982
0.0!l*6
0.01310
0.01*73
0.01637
0.020*6
0.02456
0.02265
0.0327*
0.0363*
0.0*093
0.0*502
0.0*912
0.05321
0.05730
0.06139
0.065*9
0.06958
0.07367
0.07777
0.08186
0.09005
0.09823
0.106*2
0.11*63
0.12279
0.13098
0.13916
0.1*73*
0.0028832
0.0020756
0.001*617
0.0010903
O.C009207
0.0008076
O.OOC7268
O.C006663
0.0006219
O.C035395
0.0005330
0.00050*7
0.000*8*5
0.000*765
O.OOO*68*
0.600*6**
0.000*60*
0.000*563
0.0'JO**83
O.COO***2
0.000*361
0.000*280
0.000*199
0.000*119
0.000*078
0.0003957
0.0003796
0.0003635
0.0003*72
0.0003311
0.0003109
0.0002908
0.0002665
0.0002*63
0.0003256
. :.-•,-.. :::,;.,„,•. 0.00032*2
. V,:;\ :•:• .. <•-•;: o. 0003229
•-••• : 0.000321*
0.0003200
0.0003186
0.0003172
•:- 0.0003157
''•' ' •' 0.00031*3
'."• 0.0003129
0.000309*
0.0003059
0.000302*
• . ; -'•'' ...:. ',-'.. 0.0002988
. -, ' •- -. •: • :•'.;' 0.0002953
" -:'v?i-> ..::.' 0.0002918
0.0002883
0.00028*7
0.0002812
' • 0.0002777 ...... • .'. ,.:.:i :
, ', 0.00027*2 . ;-'':lv V>.- ;' "- '•":• :.'"<*
, . . ' / - 0.0002707 . V-; •.:*• :; •- ' ':: '/ : '"'
0.0002671
0.0002636
0.0002601
v;*-V' ,.•.;•>.. ,-..•.:••: 0.0002566 " 	 "" ""
:'" :.' ::~-.',;s:*;;.^:..:.v: --0.0002*95
1 ' ' ••'•'• -•'.":- 0.0002*25
0.000235*
0.000228*
O.C002213
'-.••:•••• ;;,»;,v;:-..: 0.00021*3 • ; ',c -,.;•, '/• '•'.".';,."
; - : .;' -: 0.0002073 : ' -; • ": -- '•• ~
:, .-.'•' >..vO. 0002002 >Vi: ..-''• J ?,:"' •'..:'
0.0003817
0.0003BOO
0.000378*
0.0003767
0.0003751
0.000373*
0.0003718
0.0003701
0.0003685
0.0303663
0.0003627
0.0003506
O.C0035**
0.0003503
0.0003*62
0.0003*20
0.0003379
0.0003338
O.OC03297
0.0003E55
0.000321*
.. '.. 0.0003173
0.0003131
0.0003C90
0.00030*9
0.0003008
0.0302925
0.00028*2
0.0002760
0.0002677
0.0002595
.--.-.••; 0.0002512
'"••..:. 0.0002*30
'-.•: ;" 0.00023*7
0.0004*02
.; : 0.000*367
0.000*332
U. 000*293
0.000*263
0.000*229
0.000*195
0.000*161
0.000*127
0.000*093
0.000*009
0.0003926
0.00038**
0.0003762
~ •''.- • • . 0.0003682
.. ": ; 0.0003602
0.0003522
0.0003***
. 0.0003366
' - ••-. '-•-:- . 0. 0003290
...•'.• •• • ':'.' :".''•'•.•*. ''.: 0.000321*
. . -' \ : • < :':-; 0.0003139
0.000306*
0.0002991
0.0002918
..••-•-..••' '., •; »-,X...y :• : 0.00028*6
.•',.'.".'•;''•. - ' -'.'•• / •*••'-•>:. 0.0002705
':' : J : ' -.'-.•-?'•!>." 0.0002567
0.0002*32
0.0002300
0.0002172
, .... .:-..• . • ..:••••. . o.ooo<;o'.7
. :. , . ..:: '•. ! i ;> •• 0.0001926
•••• -' - ' .- :;', '-..". :; 0.0001808
                                                      KEAN DeVIATION  *    O.OC01712   ROOT  MEAN SQUARE DEVIATION
                                        [MODEL A]      RESIDUAL SUM OF SQUARES - O.IC021E-05"
                                                   .  KEAN PERCENT DEVIATION =  36.78317Z6
                     0.0001892
                                                      MEAN DEVIATION  -   O.OC01Z45    ROOT  KEAM SQUARE DEVIATION
                                       IKODEL B]       RESIDUAL SUM  OF SQUARES « 0.59380E-06
                                                      MEAN PERCENT  DEVIATION =  Z5.8966827
                     0.0001456
                                                      MEAN DEVIATION  »    0.0001238   ROOT  MEAN SQUAKE DEVIATION
                                       [MODEL C]       RESIDUAL SUM OF SQUARES = 0.5C217E-06
                                                      MEAN PERCENT DEVIATION =  27.5743^61
                     0.0001339
-------
           B'-~ TOHSHI "  152-G
                                     5 !'•> 71
                                                         [MODEL A]
                                             [MODEL B]
XCI1.GHS H2S04/GH C    RATEt CHS H2S04/GM C-NIN  CALCULATED RATE, CMS  H2S04/G1 C-MIN  CALCULATED RATE,  GKS HZS04/G* C-MIN
             [MODEL C]

CALCULATED RATE,  CMS HZS04/5H
O.OO165
O.C0331
O.C0496
O.CC661
0.00327
0.00992
0.01157
0.01323
0.01*38
0.01653
O.C2066
C. 02*80
0.02693
0.03306
0.03720
0.0*133
0.0*5*6
0.04960
O.C5373
0.05784
0.04199
0.06613
0.07026
0.07*39
O.C7853
O.C8266
O.OV093
0.09919
0.10746
0.11572
0.12399
0.13226
0.0007334
O.OC06086
0.0005618
0.0005072
0.000*760
0.000*526
0.000*292
0.000*962 .V-,. .... ' . . :..
0.000*018
0.0003902
0.0003667
0.0003*72
0.0303277
0.0003121
O.OC0300*
0.0002SB7
0.0002731
0.0002614
0.0002536
• • 0.0002*57
0.0002380
0.0002302
0.0002224
0.00021B5
0.0002107
0.0002028
0.0001951
0.0001872 , ,
0.0001795
0.0001717
0.0001599
0.0001522 .
O. 0002654
. 0.0002643 '., .::: . . rv>;: • '
0.0002631 ' , ' ' . ...
0.0002619
0.000260.8
0.0002596
0.0002585
-.„••••. 0.0002573: .- „•;.*..;;.'•:• • • <.. ,.:.:-
'"••• 0.0002561 '••',;.••>'"'! '" T-V-.-'.V. .-:
0.0002550 '•';: :.::.. i ''.'. . ' " ::
0.0002521
0.0002*92
0.0002*63
0.0002434
0.0002*05
0.0002376
0.00023*7
0.0002318
O.C002289
0.0002260 .:.,:• ' -., • -,.•:.. •••,.-.•. ,
0.0002231 ..:,'4'»' ."ii-.V " : '*' • l
0.0002202 -..-/' ; '; ' •'': •
0.0002173
O.C002144
0.0002115
0.0002086
0.0002028
0.0001970
0.0001912
0.0001854
0.0001796
: ;••: ;6. 0001738 : ..•:';*' .. ',;.;.' . . .-. "
0.0002987
0.000297* : ' '
O.OOOE9frl
0.0002 9', 8
0.0002935
0.0002921
0.0002908 , .'.
0.0002B95 : . • . -••;-•
O.C0028d2 ••-•'."
0.0002069
0.0002637
0. 000280*
0.0002771
0.0002739 - . • ' .:... : .
0.0002706 ' •'•' '•:.' ':*: •"•. '•''.' :.'-:•
0.000267* 	 -..'.
0.00026*1
0.0002608
0.0002576
0.0002543 •
O.C002510
0.0002473 ' - ,
0.00024*5
0.0002*12
0.0002380
0.0002347 , -.- ,. •, - •' •'•••. .. >v
0.0302282 ' : -,'' ,. ... • '.
'. 0.0002217 - ;'-. ;" ..:, '. •"••'
0.0002151
0.00020S6
O.OC02021
O.OB01956 • :
0.0003158
0.0003331
0.0003304
O.OUOJ251
0.0003225
0.000319B
0.0003172
O.OOD3146
0.0003055
0.0002991
0.0002Q28
0.0002365
0.0002S01
n.nOP?741
O.OU02681
0.0002620
0.0002561
0.0002501
0.00024*3
0.0002365
0.0002328
O.COC2272
0.0002216
0.0002160
'.*':• 0.0002052
.V'"i- 0.00019*6 -" 	
0.00018*2
0.00017*1
0.00016*3
0.0001547
                                 [MODEL A]
MEAN DEVIATION -   0.0000539    ROOT MEAN SQUARE  DEVIATION
RESIDUAL  SUM OF SQUARES =  0.17109E-06 .
MEAN PERCENT DEVIATION =   15.9290390
                                                                                                                0.0000811
                                              MEAN DEVIATION «   0.0000475    ROOT MEAN SQUARE  DEVIATION
                                 [MODELS]      RESIDUAL  SUM OF SQUARES =  0.11412E-06
                                              MEAN PERCENT DEVIATION "   16.0720062
                                                                 0.0000663
                                              MEAN  DEVIATION =   0.0000292   ROOT MEAN  SQUARE DEVIATION
                                 [MODEL C]      RESIDUAL  SUM OF SQUARES  =  0.67109t-07
                                              MEAN  PERCENT DEVIATION  =   8.2095785
                                                                                                                0.0000508
-------
       swi SUMBEH - 153-0
5 18 Tl
    (                                                       [MODEfTA]

XtU.GXS  H2SO*/G« C    RATE. GHS H2SO*/GH C-HIN   CALCULATED RATE. GWS H25oi/GN C-HIN
                                                             [MODEL B]
                                                                                      CALCULATED RATE, CHS H2SO4/KH C-MIN
[MODEL C ]
                                                                                                                             CALCULATED RATi, CMS H2SM/&N C-MN
O.OC61Z
0.00735
O.OCS57
C'. 00960
C. 01102
C. 01225
0.01531
t. oie37
0.02143
0.02450
C. 02756
0.03062
0.03363
0.0367*
0.03T91
0.04297
0.04593
C. 04699
C. 05205
C. 05512
C. 05818
0.0612*
C. 06734
C. 07349
0. 07961
0.0857*
C. 09166
C. 09798
0.10411
0.11023
C. 11636
0.12248
O.H47J
C'. 14698
0.15922
0.1714T
0.18372
0.19597
0.20E22
t. 22046
C. 23271
C. 24496
0.25721
0.26.946
0.23170
0.29395
0.30620
0.31845
0.33070
0.3429*
0.0178058
0.0159658
0.0141259
0.012523*
0.0109602
O.OU'96151
O.OU6 7C6B
0.0041921
0.0034123
0.0027599
0.01)24572
0.0022514
O.OC20&54
O.CC2D120
0. 01-19646
O.OOH230
0.001884*
O.OOU516
O.OOIB191
0. (,01702*
0.0017628
0.001~390
0.0316975
0.0016559
0.0016144
0.0015728
0.001525*
0. 0011838
0.0014363
O.C013S29
O.CC13355
0.0012379
0.0011S11
0.0010302
0.0009734
0.0008665
0.0007538
0.0006410
0.0005401
0.000*570
0.0003799
0. (,00326*
O.OOU2849
0.0002493
O.COD2255
0.0002077
0.0001899
0.0001662
O.OC.01543
0.0001*2*
0.001919*
0.0019131 ,
; 0.0019069
0.0019006
0.0018943
0.0018080
0.0018723
0.0018566 ' ... - " ; '
0.0018*03 '-..•.'; .-. . . . .
0.0018251 ' - .' •'.'
0.001809*
0.0017937
0.0017780
0.0017622 .;' ;
0.0017*65 .'• ... ,:. --.•:"
•0.0017308 ' • ' ".'
0.0017151
0.001699*
0.0016836
•• -..-• •-. . 0.0016679 ' ' .
.-•''• 0.0016522 •"*."..: ' ".' f .,:•"•'•";.
"'• ••'• • 0.0016365 :• •"'•..•-,'•"• , ! .,.' -
0.0016050
0.0015736
0.0015*22
. .'., i •.».;,•-;,-::. 0.0015107 ..-••••• .,.:•
.••••'.••'••"•. :..i .-:'•:• 0.001*793 • :- :/.". ''.,';•;.
0.001**78 >
0.001416*
0.0013850
0.0013535
.."<•, -.... „:....,: . ., 0.0013221 . •:•,;•.••,...:.,:..
•"- '.••-,- - 0.0012592 ' :i'-.*-" ; •-'.;••. A"
"... '.;,;; ..'r.^ 0.0011963 •".'."; -, > ;.;..
0.001133*
0.0010706
0.0010077
0.0009*48 , • , . , . :-,
. - - ' - 0.0008819 -•:*"-j:'-'.,; «".:" .."•'
o.ooo8i90 •'.'.-••'•' ;:•/.,..'.
0.0007562
0.0006933
0.000630*
.. . ,. .:..:. 0.0005675 .; , ::,:,u. ,'• . -
.' ' ...,.:• '• 0.0005046 -.••...'.- ',-.
0.0004418 ^ ' ^Lii; ' '
0.0003789
0.0003160
0.0002531
. ..'.-. • 0.0001902 .••..."•;. •'•.• ••'". ..•',
                                                                                                _0.0021755
                                                                                                  0.002168*
                                                                                                  0.0021613
                                                                                                  0.00215*1
                                                                                                  0.0021*70
                                                                                                  0.0021399
                                                                                                  0.0021221
                                                                                                  O.U021043
                                                                                                  O.OU2U864
                                                                                                _0.0020686
                                                                                                ~0.0020508"
                                                                                                  0.0020330
                                                                                                _0.0020152
                                                                                                  0.001997* "
                                                                                                  0.0019795
                                                                                                  O.C019617
                                                                                                ~O.OOD<.39~
                                                                                                  0.0019261
                                                                                                  0.0019083
                                                                                                  0.0018905
                                                                                                  0.0018726
                                                                                                  0.00185*8
                                                                                                  0.0018192 "
                                                                                                  0.0017B35
                                                                                                  O.OC17479
                                                                                                "0.0017123"
                                                                                                  O.OC16766
                                                                                                  O.OC16410
                                                                                                ' O.OC1605* '
                                                                                                  0.0015697
                                                                                                  0.0015341
                                                                                                ' 0.001*955
                                                                                                  0.0014272
                                                                                                _0.0013559
                                                                                                  0.0012847
                                                                                                  0.001213*
                                                                                                  0.0011*21
                                                                                                 "0.0010709
                                                                                                  0.0007996
                                                                                                _O.OC09283
                                                                                                  0.0008570
                                                                                                  O.C007653
                                                                                                  0.0007145
                                                                                                " 0.0006432 "
                                                                                                  0.0005720
                                                                                                  0.0005007
                                                                                                  0.000*29*
                                                                                                  0.0003582
                                                                                                  O.OOG2869
                                                                                                 ~0.0002156
                                                                                                  _0.002T5IT
                                                                                                   0.0027352
                                                                                                   O.OU271B9
                                                                                                 _ 0.002702*
                                                                                                   O.0026861
                                                                                                   0.0026698
                                                                                                   O.0026293
                                                                                                 "0.0025B90
                                                                                                   0.0025490
                                                                                                 _ 0.0025093
                                                                                                   0.0024699
                                                                                                   0.002*308
                                                                                                   0.0023919
                                                                                                   0.002353*
                                                                                                   0.0023151
                                                                                                   0.0022771
                                                                                                   0.0022394
                                                                                                   0.0022020
                                                                                                   0.00216*9
                                                                                                   0.0021280
                                                                                                   0.0020915
                                                                                                   0.0020552
                                                                                                 " O.OOH835
                                                                                                   0.0019130
                                                                                                   0.0018436
                                                                                                   0.001775*
                                                                                                   0.00170S*
                                                                                                   0.0016425
                                                                                                   0.0015778
                                                                                                   0.00151*3
                                                                                                   0.001*520
                                                                                                   0.0013909 '
                                                                                                   0.0012722
                                                                                                   0.001158*
                                                                                                   0.0010*94
                                                                                                   0.0009*53
                                                                                                   0.000t<.62
                                                                                                  ' 0.0007521
                                                                                                   O.OC06630
                                                                                                   0.0005791
                                                                                                   0.0005003 '
                                                                                                   OtO00*268
                                                                                                   0.0003587
                                                                                                   0.0002959
                                                                                                   0.0002387
                                                                                                   0.0001371
                                                                                                   0.0001413 "
                                                                                                   o.odoioi*
                                                                                                  _0.0000675
                                                                                                   0.0000*00"
                                [MODEL A]
       MEAN DEVIATION =    0.0007W1    ROOT  MEAN  SCUARF. DEVIATION
       RESIDUAL SUM OF  SQUARES *  O..17760t-03
       MEAN PERCENT DEVIATION =   39.2*94659
                                                                                                                       0.0019649
                                             MEAN  DEVIATION  =    0.0007402    ROOT MEAN SQUARE DEVIATION
                                [MODELS]     RESIDUAL  SUM  OF SQUARES  = o.i65i5E-03
                                             MEAN  PERCENT  DEVIATION »  47.5648651
                                                                                                                       0.0018948
                                             MEAN  DEVIATION  =    0.0006324    100T  MEAN SQUARE DEVIATION
                                             RESIDUAL  SUM OF SQUARES  = '0. 13940fc-03
                                             MEAN  PERCCMT DEVIATION «   22.1421509
                                                                                                                       0.0017408
-------
           Httt SUMEES » 157-0
                                        5 31 71
                                                             [MODEL..A]
[MODEL  B]
                                      [MODEL C]
XII),CMS H2S04/OM C    RATE,  CMS H2S04/GM C-MIN   CALCULATED RATF, GHS K2SO*/6M C~«I(t  CALCULATED RATE, GHS H2S04/GM C-HIN     CALCULATED RATE, GHS HJS04/SM C-MN
O.OC272
0.00407
O.OC543
O.OC679
O.OCSIS
O.CC951
0.01037
0.01222
0.01358
0.01693
0.02037
0.02377
0.02716
0.03056
0.03395
•. 	 _ 0.03735
O.OA075
0.04414
0.04754
0.0509J
'•':.• 0.05433
0.05772
0.06112
0.06451
0.06791
•;. -v . 0.07*70
: .' l ' 0.08149
», ' - O.OC828
O.C9507
0.10186
0.10866
; 0.11545
".-'- ' 0.17224
. 0.12903
0.15582
0.14940
0.16298
~ 0.17657
0. 19015
0.20373
0.21731
0.0042234
0.0039256
0.0025306
0.0014275
0.0012912
0.0012328
0.0011939
0.0011615
0.0011420
O.GU11096
O.OCH0.31
0. 0010966
0.00109C1
0.0010771
-- 0.0010706
0.0010576
O.CCIC447
0.0010382
0.0010517
. .' . 0.0.010107
•": : , 0.0010122
' 0.0009992
0.0009363
0.0009798
0.0009668
. 0.0009408
" '. . O.OCC9149
0.003SSS9
0.0008630
0.0003371
0.0008110
:. ' f. . .... 0.0007eSl - '
' . ••.' 0.0007592
0.0007397
0.0007203
0.0006673
0.00004B9-
! 0.00060J4 "
O. 0005516
0.0004996
0.0004477
0.0012000
•;.••• v. 0.0011956
. '.r^v 0.0011913
-•• ' 0.001187O
0.0011827
0.0011784
0.0011740
0.0011697 - *
0.0011654
0.0011546
0.0011438
0.0011330
•0.0011222
; . ... :'.,".-; O.OOU114
• v " "' '•'.'.:.• *"\" 0.0011006
s ..' ,.,.,: 	 0.0010898
0.0010790
0.0010682
O.C010574
' . ", ' 0.0010466
•* • 0.0010358
0.0010250
0.0010142
0.0010034
0.0009926
~\ 0.0009710 •"•' '! "' "
0.0009494 >
0.0009278
0.0009062
0.0008846
0.0006630
0.0008414
0.0008198
- > > , 0.0007982
0.0007766
0.0007334
0.0006902
1 . :"T?""r^TT!~~o. 0006470 ~" -—.— - —
•"•••• '•'••'. '':•.'': '..• 0.0006038 ' , •:
O.O005606
0.0005174
 0.
"o.
 0.
 p
 6.
 o.
_o
 0.
 0.
 0.
"o.
 0
_0
 0.
 0.
 0
 0.
 0.
 o.
"o.
 p.
 6.

 0.
 0.
"o
 0.
 0.
"o.
 0.
 0.
"o
 0
 0.
" 0
 0
 0
"o
 0
 0
""o
                                                                                                    OOU534_
                                                                                                    0013485
                                                                                                    001J436
                                                                                                    0013388
                                                                                                    001333?"
                                                                                                    0013290
                                                                                                    0013241
                                                                                                    0013193
                                                                                                    0013144
                                                                                                    0013022
                                                                                                    O012900"
                                                                                                    0012779
                                                                                                    0012657
                                                                                                    0012535""
                                                                                                    0012413
                                                                                                    0012291
                                                                                                    0012170 '
                                                                                                    0012048
                                                                                                    0011926
                                                                                                    0011804"
                                                                                                    0011682
                                                                                                    0011561
                                                                                                    0011439 "
                                                                                                    0011317
                                                                                                    0011195
                                                                                                    0010952"
                                                                                                    OC10708
                                                                                                    0010464
                                                                                                    0010221 "
                                                                                                    0009977
                                                                                                    0009734
                                                                                                    0009490"
                                                                                                    0009246
                                                                                                    0009003
                                                                                                    0008759"
                                                                                                    0008272
                                                                                                    0007735
                                                                                                    0007297"
                                                                                                    COO6810
                                                                                                    000632 3_
                                                                                                    0005836
                                      0.0016400
                                      0.0016292
                                      O.OC16184
                                      0.0016077
                                     '0.0015970
                                      O.UOl58t4
                                      0.0015757
                                     " 0.0015651 "
                                      O.OC15546
                                      0.0015283
                                      0.0015023
                                      0.0014764
                                      0.0014508
                                     "0.0014253
                                      0.0014001
                                      0.0013750
                                      0.0013502
                                      0.0013256
                                      0.0013011
                                      0.0012769
                                      0.0012529
                                      0.0012291
                                      0.0012055
                                      0.0011821
                                      0.0011590
                                      0.-0011132
                                      0.0010683
                                      O.OOI024J
                                      0.0009811
                                      0.0009.187
                                      0.0008972
                                     .0.0008565
                                      O.OOC8167
                                      0.0007778
                                     ' 0.0007397
                                      0.0006661
                                      0.0005961
                                     " 0.0005296
                                      0.0004667
                                      0.0004074
                                     ' 0.0003518
                                                 MEAN DEVIATION  =    0.0000383    ROOT  MEAN SQUARF DEVIATION
                                    [MODEL A]     RESIDUAL  SUM OF  SQUARES  = 0.5T829E-07
                                                 MEAN PERCENT DEVIATION »   4.8161469
                      0.0000406
                                                  MEAN DEVIATION  =   0.0001583    ROUT  MEAN  SQUARE DEVIATION
                                    [MODEL B]      RESIDUAL  SUM OF SQUARES = 0.88629E-06
                                                  MEAN PERCENT DEVIATION  »  18.1086273
                       0.0001591
                                                  MEAN  DEVIATION »   0.0002095   ROOT MEAN  SQUARE  DEVIATION
                                    [MODEL C]      RESIDUAL SUM  OF SQUAKE5 =  0.21175E-05
                                                  MLAN  PERCLNF  UtVIAUUN =   2
                       0.0002460
-------
                  BUS NUMBER - 158-G
6  1 71
                                                                [MCDEt-A]
                                                      [MODEL Bj
[MODEL Cj
         XIIItGNS H2SCH/GM C    RATE, CHS H2504/GM C-KIN  CALCULATED RATE, CMS" H2SOWGM C-HJN  CALCULATED RATEt  CMS H2S04/GH C-HIM  CALCULATE!) RATE, CMS H2S04/3K C-HH
CTl
0.00155
0.00310
O.OC466
e.or62i
0.0077&
C.CC931
0.01087
0.0 '-2*2
0.01397
0.01552
0.019*0
O.C?329
0.02717
0.03105
0.03493
0. 03681
0.0*269
0.0*657
O.OSO*5
•••.• 0.05433
0.05821
0.06210
0.06598
0.05986
0.0~'37*
0. 0^762
0.03538
; . . - 0.0931* ;
0.10091
0.1086?
0.11643
0.12*19
0. 13195
0.13972
0.1*7*8
0.0005393
0.000*289
0.0003675
O.OC'339*
0.0003180
0.0002995
0.00028*0
0.0002700 -•„:,..,:..
0.0002591
0.0002*63 • .
0.0002233
O.CCC2048
O.CC01S93
-C.CC.31775
-O.C0016A* -- •--
0.0001563 ••'..'.','
0.0001<.66
0.0001*13
O.OC013**
0.000129* '••'• -;• .-? • •. .
0.00012*3 ' "<:,'" V:< •:,'•'• . ..
0.0001198 . .' •.••;".''•.' ••;-
O. 0001161
0.0001124
O.OCOIOC7
0.0001050
0.0000991 ", „
0.000092*
0.0000872
0.0000821
0.0000769
0.0000725 .'•••.••• ••„..••
O.OD036S1 '* ' :"
0.0000636 ••-. '
0.0000591
0.0001TU
0.000170*
0.0001697
0.0001690
0.0001683
0.0001676
0.0001669
0.0001662
0.0001655
0.00016*8
0.0001630
0.0001613
0.0001595
0.0001577
0.0001560
0.00015*2
0.0001525
0.0001507
0.0001*90
, ... 0.0001*72 : :: -.'•: •• '- :.t : ,-' , . .
.h 0.0001*55 r ',:• • "'.•",' . •<:•'•.•:•* •-
:'• •" 0.0001*37 . .•>.•• . •'-- ••• ' ;;:.--%••..
0.0001*20
0.0001*02
0.00013B*
. O.OC01367
' 0.0001332
0.0001297
0.0001262
0.0001227
0.0001192
: 0.0001156 ,. ••.". V.: •. ; :.-,•:•; : :
O.OOOU21 " ' . -' , 05
                                                                           0.0000988
                                                       MEAN DEVIATION -    0.0000627   ROOT  MEAN SQUARE DEVIATION
                                         [MODEL B]      RESIDUAL SUM OF SQUARES = 0.28891E-06
                                                       KEAN PERCENT DEVIATION «  19.354'»617
                                                                                                                        0.0000998
                                                       MEAN DEVIATION =    O.C000497   ROOT
                                         [MODEL C]      RESIDUAL SUM OF SQUARES = 0.26197t-06
                                                       MEAN PERCENT DEVIATION =   5.0350761
                                                                                                  SOUARE DEVIATION
                                                                                                                        0.0000950
-------
         EOT BUH3ER - l60-C
6  9 71
                                                        [MODEL A]
                                                      [MODEL B]
[MODEL C]
XU),GMS H2S04/GM C    RATE,  GHS H2S04/GM C-H1N   CALCULATED RATE, CMS H2S04/GH C-H1N  CALCULATED RATE, GHS H2S04/GH C-H1N  CALCULATES f»»TE, 6-.' ;
' '• "••' 0.0005326 ... ?'".•--
: .. 0.0005305 . ' '. . . :".
0.0005282
0.0005259
0.0005236
. .•• :•.•"•:':••• ;•--• 0.0005213 : •. . . . - '
.---. -.-, - i': '••:.'. ' *.'"-. 0.0005190 ' ..V,.':*"' "c
. . •'•:. 0.0005133 :
0.0005076
0.0005018
.0.0004961
0.0004904
0.0004846
0.0004789
O.OOC4732
0.0004674
0.0004617
: :;;-,:',..- 0.0004560 . , :.'
:. :•.•';••::•/:..'•'•••'!•'>••. 0.0004502 .: : • -.,
-'•<-> •:., -•:,'• .:• 0. 0004445 s 'V. . / : '' '
0.0004388 	
0.0004330
0.0004273
< • 0.0004158 .; .' . .'
0.0004043 •>'•;!.•, . •
0.0003929 ",:'-'< :;
0.0003814
0.0003699
0.0003585
0.0006061
0.0006035
0.0006009
0.00059BJ
0.0005957
0.0005932
0.0005906
0.0005880
0.0005S54
O.OOC5799
0.0005725
0.0005660
0.0005595
0.0005531
0.0005466
0.0005401
O.O005337
0.0005272
0.00052O7
0.0005142 .
', Oi000507E
0.0005013
0.0004948
0.0004884
0.0004819
O.OO04690
O.C004560
0.0004431
0.0004302
0.0004172
0.0004043
0.000733!>
0.0007279
O.CCC7J2Z
0.0007165
0.000710J
.. ' 0.0007052
O.OD06943
0. 0006664
0.0006S09
0.0006473
0.000633S
• O.OOC62C4
O.C006072
0.0005941
0.0005812
0.0005684
0.0005557
' O.C005431
"' -. 0.0005307
'- 0.0005184
0.0005062
0.0004941
0.0004822
. y ..-.,<;. . s 0.00045S8
• .-'. •••" 0.0004359
;.:' . • • 0.0004135
o. 000391 r
0.0003704
0.0003497
                                              MEAN DEVIATION =   0.0000670   ROOT MEAN  SQUARE DEVIATION
                                   [MODEL A]    RESIDUAL  SUM OF SQUARES  «  0.21707E-06
                                              MEAN PERCENT DEVIATION =   13.8535995
                                                                            0.0000914
                                              MEAN DEVIATION »   0.0001035   ROOT MEAN  SQUARE DEVIATION
                                   [MODEL B]    RESIDUAL  SUM OF SQUARES  =  0.311-J26-06
                                              MEAN PERCENT DEVIATION =   24.1104126
                                                                           .0.0001095
                                              MEAN DEVIATION »   0.0001149    ROOT MRAN SQUARE  DEVIATION
                                   [MODEL C]    RESIDUAL  SUM OF SOUARSS =  0.39982t-06
                                              MEAN PERCENT DEVIATION =   26.84Hb60
                                                                            0.0001240
-------
                    FU3 :fUM2ES - 161-C
   6  10 71
                                                                  [MODEL A]
                                                        [.MODEL 3]
[MODEL C ]
           Xm.GMS H2S04/GM C    RATE,  CMS H2S04/GM C-MIN  CALCULATED RATE, CMS H2S04/GM C-HIN   CALCULATED RATE. GMS.H2S04/GH C-KIN  CALCULATED RATE, CMS H2S04/GH C-H1N
CD
0.00292
0.00438
O.OC584
0.00730
O.GC376
O.C1022
0.01168
0.01315
0.01461
0.01626
0.02191
O.C2556
0.02921
- - O.OJ286
0.03651
0.04017
0.04332
0.04747
0.05H2
"•';" 0.05477 ' ' .
0.0584E
0.0420B
0.06573
0.06938
0.07303
0.08033
: 0.08764
0.09494
0.10224
0.10954
0.11485
• . ' • 0.12415
; 0.13145
0.13876
0.14606
0.16367
0.17527
0.18988
0.0059734
O.OC42377
0.0030784
0.0019790
O.OC12460
0.0010481
0.0009455
0.0008722
O.OOOC429
O.OC080A3
0-QC07B43
0.0037623
O.OC075_•
0.0008051 : .>.. :..'•"•/ -. ':• '•'"•
0.0008817 •'•• ',-'•• '"-:•-'': :'.
0.0008782
0.0008748
0.0008713
..- -.,.. ...<..-; • 0.0008679 - -"C ,. »-
0.0008644
0.0008558 ' * :
0.0008471
0.0008385
.0.0008299
.-.' >.:.- :.- - • ••,:" O.oooa'212
; ' ':' • : 0-0008126
: . ,....:;' . • : 0.0008039
0.000/953 "' '
0.0007867
0.0007780
•-,-•/ ,;-?V;v •-, - -0.0007694 •:'•••'• (-»' •-..-' - ^•l"1.^
*>.-. ':,,•'•"• ' 0.0007607 "-' ..';'.•'. - .:••'•••'*:••
.'•''., • - . 0.0007521 -"•• : .: • ''it.'- "•*.
0.0007435
0.0007348
0.0007262
- =. •. - , ' -:i '•: ... :,- 0.0007089 , ' " " ""' 	
•:-;.'' ;'v,':':fV::-Kv'* 0.0006916
•• ••'?•••<• •"•'•-• '-•:-"•:- 0.0006744
0.0006571 	
O.OC06398
0.0006225
T: ';:-.;::::;.;.;;...;... 0.0006053 - 	 - —
•;'.'.- ':••; - 0.0005880
•: • .i . r •.-.•'••-.-• *••- '•-:- 0.0005707
0.0005534
0.0005189
0.0004843
•' . '-.»•* 0.0004498 .-' .• ..-,.•
0.0010061
0.0010022
:•': ,. 0.0009983
0.0009944
0.00099C5.
0.0009866
0.0009827
0.0009783
0.0009749
0.0009652
0.0009554
0.0009457
0.0009359
0.0009262
0.0009165
0.0009067
0.0008970
0.0008872
0.0008775
0.0008677 - •
-:/' o.oooasao
0.0008483
C.C008385
O.OC0828B
0.0008190 .
0.0007995 ." .- ': :
0.0007601 . ..;: -.
0.0007606
O.OOOT411
0.0007216
O.0007021
0.0006826 - >
0.0006631
0.0006437
0.0006242
a.0005852
0.0005462
:' 0.0005073
0.0012186
0.0012100
0.0012014
0.0011923
O.OOI1H43
0.0011757
O.OU11671
O.OOI15t8
0.001 1504
0.0011294
O.OOllOdf
o.ooioeei
0.0010676
0.0010474
0.0010273
'- - 0.0010074
0.0009877
0.0009681
0.0009488
; 0.0009296
0.0009106
O.OOOB917
O.OOOU731
O.OOOSS46
0.0008363
•;; , ••••• , , O.OOOBOOJ
.;., , • ' , ••:'-,' 0.0007649
0.0007)03
0.0006965
0.0006633
O.OOC6309
0.0005992
."•.'•'»: ... . 0.0005683
••• : 0.0005381
0.0005087
0.0004521
0.0003965
..•• 0.0003480
[MODEL A]
                                                        MEAN  DEVIATION =   0.0000561   ROOT MtAN  SQUARE DEVIATION
                                                        RESIDUAL  SUM OF SQUARES  = 0.13990E-06
                                                        KEAN  PERCENT DEVIATION =   8.0388994
                                                                                                                          0.0000651
                                            [MODEL B]
            MEAN DEVIATION *   0.0001371    ROOT MEAN  SQUARE DEVIATION
            RESIDUAL  SUM OF SQUARES -  0.67857E-06
            MEAN PERCENT DEVIATION =   20.5054016
                                                                                                                          0.0001434
                                            [MODEL C]
            MEAN DEVIATION =   0.0001771    ROOT KRAN  SQUARE DEVIATION
            RESIDUAL  SUM OF SQUARES  =  0.14490C-05
            MEAN PERCENT DEVIATION =  24.4635620
                                                                                                                          0.0002095
-------
         P,'JS 3UKBHR
                                    6 15 71
                                                        [MODEL A]
[MODEL B]
[MODEL C]
XII),GPS H2S04/G.1 C.   RATE,  GMS H2SC4/GM C-MIN   CALCULATED RATEt CHS HZS. '
0.08041 ; - ••:••
'•'•'', . 0.09772
0.05503
0.13234
0.10965
0.11696
i. 0.12427
. , _ 0.13158
0.13889
0.14620
0.16082
0.17544
0.0018122
0.0012529
0.0008129
0.0007085
0.0006570
0.0006190
0.0006041
0.00050^2
0.0005743
0^0005668
O.OOC5444
O.C005369
O.OC05220
0.0005146
0. 000*071
0.0005034
0.0005034
0.0004996
O.C004996
0.0004996
0.000499&
0.08C<-996
O.OU04996
0.0004996
0.0004996
0.0004996
O. 0004922
0.0004647
0.0004847
0.0004773
0.0004693
0.0004661
0.0004624
0.0004549
0.0004474
O.OC04325-
0.0004176
0.0003953
0.0006787
••-. ' ;.-•-•• 0.0006760
'--'•.,..,.'•-< v>v;:c. 0.0006734 '<•.".• :-~: ." " -
'• •'.'.' - 0.0006708 . : '. • ••'.'.•
0.0006682
0.0006656
C. 0006629
•• : ••• O.COC6603 ;..-.,.. a . ,
.-''.; :..'..V- ... 0.0006577 •:';.•..'."••"..",•.. .-
: • ''•'•' '"'•••: 0.0006551 '•-'" '•')' "
0.0006485
0.0006420
0.0006354
...::, ,\".. .„ 0.0006289
. ? ''. '-'• ,.'•!' ::':^;-r-- 0.0006223
• •.:'•, 'i:..'. '•' 0.0006158
0.0006092
0.0006026
0.0005961
O.OO05895 ' ' ' 	 "" '
0.0005830
0.0005764
0.0005699 	
0.0005633
0.0005568
0.0005502 	 Y 	
0.0005371 »
0.0005240 _j 	
0.0005109
0.0004978
0.0004847
0.0004716 • " ~, ,, '
0.0004585
0.0004454 ' :
0.0004323
0.0004192
0.0003930
... ,; .,:„, .-..,,.: ;.i.J, ,.,„,... .v, • 0.0003667 ,: • .-,,.,.. ..•:., .;••• jy-, ..-..•. . •
0.0007241
0.0007213
0.0007135
O.OC07157
0.0007129
0.0007101
0.0007074
0.0007046
O.OOC7018
0.0006990
O.COG6920
O.CC06S50
0.0006780
0.0006710
0.0006640
0.0006570
0.00065OO
0.0006430
0.0006360
O.OOC6290
0.0006220
0.0006151
0.0006081
0.0006011
0.0005941
0.0005871
0.0005731
0.0005591
0.0005451
0.0005312
0.0005172
0.0005032
0.0004892
0.0004752 :
0.0004612
0.0004473
0.0004193
": 0.0003913
0.0003499
0.0008419
: 0.0008380
0.0006120
O.OOUIJ2&1
O.ODOU701
O.OOCB142
0.0008CB4
0.00(Jh025
: . 0.000?V66
0.0007821
0.0007677
0.0007534
••'••• 0.000731J
.. ; . 0.000/252
0.0007113
0.0006975
0.0006839
0.0006703
0.0006569
. . ' j'.' . , 0.0006436
: 0.0006304
0.0006174
0.0006044
0.0005916
i . •-,-.'• * .'. ' .••-•• 0.0005790
: s - ' « -, 0.0001540
: •'•-.i.'-f'-:. - '• ' : " 0.0005295
O.OOO^i
0.00048^0
0.0004591
. ".-. ' ••--.-. ' • • 0.0004366
.,' •:>' '•:': • ; '• "" 0.0004147
• '-••-.• V?;'--: 0.0003932
0.0003723
0.0003519
0.0003127
• 0.0002756
                                              MEAN DEVIATION =   0.0000628    ROOT MEAN SQUARE  DEVIATION
                                 'MODEL A]      RESIDUAL SUM  OF SCUARES = 0.17069E-06
                                              MEAN PERCENT  DEVIATION =  12.2738953
                     0.0000730
                                              MEAN  DEVIATION -   0.00009*3   ROOT KEAN  SOUARE DEVIATION
                                 [MODEL B]      RESIDUAL SUM OF SCUAKHS  = 0.36657E-06
                                              MEAN  PERCENT DEVIATION =  18.3562317
                      0.0001070
                                              MEAN DEVIATION »   0.0001336   ROOT KEAN  SOUARE DEVIATION
                                 [MODEL C]      RESIDUAL  SUM OF SQUARES  =  0.75555E-06
                                              MEAN PERCENT DEVIATION =  26.1*30359
                      0.0001537
-------
                   APPENDIX A-8

        COMPARISON OF MULTIPLE REGRESSIONS
       TO 6 INCH DIAMETER FLUIDIZED BED RUNS
                                                    Page

Westvaco Model by Stepwise Regression Compared       121
  to Continuous S02 Sorber

Westvaco Model by Multiple Regression Compared       128
  to Continuous S02 Sorber

Westvaco Model by Multiple Regression (Loading       135
  Factor Order) Compared to Continuous S02
  Sorber
                        120
-------
             APPENDIX A-8-1

  WESTVACO MODEL BY STEPWISE REGRESSION
    COMPARED TO CONTINUOUS S02 SORBER
             Westvaco Model
dXv  _  ,  _-E/RT n    xv N Yn   Ym  Yp
 dt      K e      U " 0.38;  S02 Y02  H20
where  -E/RT = 5520°R

       n     =0.50

       m     = 0.63

       p     = 0.73

       k     = 1.59(10-4) gms. H2S04/gm. G-min.
                   121
-------
        S02 SDRBER  DESIGN

  RUN NUMBER      SA-21   DATE   6  7  71

 _Ji'LAk CAP(HiN_RATiE j=	?_*J!.1 J?_ .Mii/JJR,				

  HEIGHT OF CARBON/STAGE =    2.25 INCHCS ,-   '.:;;;;*;;.'..,.,;.».--,,..,„,,:,.,	-. ..,.-..-,.•,.>•»•..    ,.,.•   .......
  DIAMETER OF VESSEL =  6.0  INCHES       '   -  -  *  ' '•'•   •••••:•••-.••.-•>:<. •/*•>•' •:,..;.•. v. •.-.•./. «..*•. i.1^..-..   .....,.,••:.-,., s.
  CARbON USED =   96324.
  TOTAL  GAS I LOW  RATE =      1247.  SCFH
 _I_NLEJ_SO? Cf)NCFNTRAT_IpN_^__	20p_2i__PPM _
r INLET  NO c'OMCfcNTRATIO"N"=     " ISO.  PI'B
  IMLET  02 VOLUME FRACTION  =  0.0420
	INLr.LJI2tl_VpLf)ME_FRACJ | ON *  Q...13QO. :... .	
  UUTLET S02 CO'-JCENT RAf'l IJN  =       165. PI'H
^_T_EM PER AI U R. C
STAGE
r i
2
3
i 6
[ 7
8
9
	 0.22... .
= 200.0 DEC, . F
S02 CONCENTRATION
PPM
2009.
1799.
1574.
1357.
1093.
847-
. . 608. 	
3B6.
200.
165.0001

ACID LOADING
. LBS ACIU/1.0 CARBON
0.17BB
0. ll>42
0. 1279
0.1002
0.0715
0.0147
0.0
0.0
0.0
  TOTAL  CARBON  REQUIRED  =      20.75  I NOIL'S
  TOTAL  STAGES  REQUIRED  ASSUMING  2.25  INCHES  CARBON/STAGfc = 9.22
  SPACE  VELOCITY  =      3672. l/HR

 .PRESSURE DROP ACROSS  CARBON -	io.3i». JNCUC-S HZO
  PRESSURE DROP  ACROSS  PLATES =      5.19  INCHES M20
  TOTAL  PRESSURE  DROP ACROSS STAGES  '     15.56 INCHES  1120

  RATECI1 )=COEFF  * (1-X I 1 1/XS) **A  *  (YSCI2*«D)  * (Y02**C) *  (YH2C**D)
 	WHE.R-E_C.OtCF.5.K <• CXPJ-E/H*! I/ lTt/.601 I I	
           T«     200.         XS=     0.38       YS02=                 Y02=    0-OH2        YH2O    0-130
       _:;E/.R_i	5.5.aQ.		...A"	l_.(jQ.O	B=	0.400	    .C*	0.6.30.  '	0; 	0.73(L
           K«0.000159
                                                  122
-------
       S02  SORUER DESIGN

  RUN NUMBER     SA-22    DATE  6  15  71

  TOTAL CARBON RATE  =   3. 260_J.RS/HR
•OUTLET  CARBON LOADING »""o". 2 2V/9 "Vll'S" AC Fl)
;  HEI&IH  OF  CARHON/STAGE -   2.35  INCHES
;  0.1 AHE TEJ>;>* ^, f'^f.:*:+^& •"?;»•'-'' <:-.;>r''^
 I  PRESSURE.. DROP..ACRgSS_..CA^fiON....-/::::r::.t;lPy8.'J;:>;i-NCHES";)H2U .-^:if^^^!^£^afM^^l^-i::i^f:^P-'^<^^^
   PRESSURE OROP ACR~OS~S PLATtS =      5.**  INCHES H2U
   TOTAL  PRESSURE  DROP ACROSS STAGES  =     16.33  INCHES H20
 £—__„_,_		   ———
 !
 ^	RATE EXPRESSION  USED IN OESIGN CALCllLATIONS
   RATECU l^COEFF  *  ll-XI I )/XS)**A  * (YS02**D)  * (Y02**C1  *  (YH20**[)I
   -__BHERE. COE F F ' K  «  E X P I -f. /R * I 1/ I T * *60 II I	 „
           T'    200.         XS-     0.38   .    YS02«       .     ,   Y02=    0'0>42       YH20=    0-130
       _-E/R=	.ss?p,_	•;;.;,:.,...A».: „,..L-QOQ-'        •:»*•  : o.*oo	„	„_!>_	^*AQ	   _.^f....^_P±J3p
           K-o".obb"r59        ~                             -----                  	-.
                                                123
-------
       S02' SORBER DESIGN
  RUM  NUMBER
                 SA-23   DATE  6 16 71
  TOTAL CARBON RATE =  3.350 IBS/MR
OUTLET CAROUN LOADING = 0.16660 LUS AC I D/IB CARBON.,.,; :.;.,;;. ;:;j";^.<;::";;!:', :.;:.•: '-V ••: • >•.-; > T^;', -'-i '•V,:;:::>V'^::!-'\^::i:':J'--W:it;i:;'";
HEIGH1 Of- CARBON/STAGE = 2.40 INCHES.. :'^^V£'^^?'^ >:&&^:r":> .. W?; ^Zl^'^^ff'.'*- ,
: DIAMETER OF VESSEL * 6.0 NCHES .- /V-^:^S;^l::J^
CARBON USED = 96324.
TOTAL GAS FLOW RATE = 1106. SCFH
INLET SCI2 CONCENTRATION = 2009. PPM
INLET NO CONCENTRATION. = 150. PPK .
; INLET 02 VOLUME FRACTION = 0,0420
: INJJLT H?O voLyME FRACTION = 0.1400 :
OUTLET SU2 CONCt NTRAT I UN = 91. PPM
TEMPERATURE •= 200.0 DfC. F

••• :i::- ••' '*f':i'!>'*^''VV«* TOTAL CARBON REQUIRED » 20.36 INCHES * - 	 	 	 ' 	 ,.,..
  TOTAL STAGES RFUU1REO ASSUMING 2.40  INCHES  CARBON/STAGE = 8 ..48

        yti nr I ry g	3J10   I/HP.
^PRESSURE DROP ACROSS CAKBUN
j' PRESSURE OkOP ACRQSSIPLATEl
       10.ia  INCHES  HZO
  TOTAL PRESSURE DROP ACROSS STAGES  =
                                          15.27  INCHES H2G
     RATE EXPRESSION USED  IN DESIGN .CALCULATIONS
  RATECII)=COEFF * (1-X(I)/XS!*«A  *  (YSM?**G>  * (Y02**CI * (YH20**D)
     WHERE CUEFF = K * EXP(-E/R*I I/(T+460 I) I
          T-    200.
       -E/R*   5520.
      ...._	K°-Q...O.Q015
-------
      S02 SOKUER DESIGN
 RUM NUMHCR
                SA-24
                         DATE  6 16 71
 TOTAL CARBON RATE -   3.190 LBS/HR
 OUTLET CAKHUN LOADfNG"=="o".lHllJ'. LBS'
 HtlGHT OF CARBON/STAGE  =    2.45 INCHES ;
JMAHETCR OF VESSEL =	6.0 INCHES ,!<• y>;.,..
 CARBON' USED =  96324.
 TOTAL GAS FLOW RATE  =       965. SCFH
 INLET S02 CCNCr(ifRATION =	39B2. PPM
 OUTLET S02 CONCENTRA1 ION
                                 10?8. PPM
_Ii"EIM.iy?E_
     STAGE
               250.0  OEG.  F
            SO2 CONCENTRATION
                    PPM
                                     AC 1 0 LOADING
                                  LCS ACIO/LD CARBON
                                     .      O.IB83
2
3
5
. 6 '.-y:,--- '•
7 ."•;•••,:'.
8
9
1 1 ... --.,::,; •
\ '0.65 ' 'C:y-:;;
}762.
35?7.
3277.
3012.
-•>• 273-i.
2150.
1848.
1544.
•f*' •• 1254.. .:••;", ::.V/':i.,::vi,,-:. .-i.:
. 10 78. 0002 ]Ki;;X&&^
0. 1 701
0.1507
0. 1300
0.10H2 ;. . ...,<. :. ,-;.:,*VJ;..V, ;•.--.-- ..•..'• .:-:,...<. - .-:. .>.^; " .. ; -^ '•.:.. '
0 . 0853;. :;: :/:':-.;:.- ! ';. ^^•^^'•^•i .V '!"(• f'::^ ''.:• :''••••; V,! -:' '•, . ':<»™-:S.''::^>:' "-,':'. \ • .:•
0.0614 •::''i'-':r:S,'-:-I:-:-cif';:.i:i^':::.v :'-;:-iii^t.''J'.* '•'•''-.'' •^y:i--f:..::-l^}';! ,
0.0369
0.0119
0.0
;So;|g|||»
TOTAL CARBON REQUIRED
TOTAL STAGES REQUIRED
                              20.55  INCHES
                                             .-,CARBON/STAGE. af
 PRESSURE  DROP  ACROSS CARBOM
 -PREi5u&E__DBPJ:Lj'C!?.o.S S..,.PL A T e s_
                                  U.27 INCHES H20
                                   7 .It 1 NC H t SH2 0
 TOTAL PRESSURE  DROP, ACROSS STAGES
                                        21.*1 INCHES H20
    RATE  EXPRESSION USED IN DESIGN CALCULATIONS
 RATEC(M=COEFF,  *  1 1-X 1 I)/XS )**A *  (YS02**[()  *  (Y02**C) * (YH20**U)
    HHERE  CriEFF*.K  *  EXP (- C/R* ( U I T+460 ) ) ) :      '           :   -:
    T=    250.
 -E/R=   5520.
	^KFa..000159_
                            xs
                                   0.38
                                  I. 000
                                                    O.'.OO
                                                                 Y02 =
                                                                   C =
                                                                         0«0't6
                                                                         0.630
                                                                                     YH20 =
0.1 30
0.7JO
                                            125
-------
       S02 SORBtR DESIGN

  RUH NUMBER     SA-75   DATE   6  17  71
 _LP-IH       _.     __ -      .
  OUTLET CA"RbON~ I fMIMNG -  0 ."liJOl 7 "llilT AC I 0/LI.I CARBON
  HEIGHT OF CARrtON/SUGt =    2.35  I'MCHT-r
  DIAME.IEK QFJ/FSSEL - ___ 6.0 .INCHES ______ ................
  CAKUUN USED =963/4.
  TOTAL GAS FLOW RATH =      109'..  SCHI
  INLET S02 CONCF'-IIKATJUN  ;___  202b.  PPM
  INLET "NO "ctiWcrMTRAT ION ' '=     " 150 .
  INLET 0<> VOLUME FRACTION =   0.0410
|__INLfcT H_20_VOLLme (-RACT I ON_i._OjJ[JjOO
        " "             ""      "
                                        PPM
  TEMPLRATURH_=_250.0 PEG.  F-
r S
STAGE
I
2
3
r 	 ~r
? 7
8
9
10
0 . .5 7
02 CONCENTRATION
PPM
2020.
Ibii.
1679.
1^)00.
inn. '
960.
7U6.
619.
411.0000
ACID LOADING
LDS ACIIJ/LI) CARBON
. . 0 . 1 2 02 .••'
0. 1124
0.0962
0.079H
. •'.. '. . 0.0467
•'- "<*•• ••'=;'- '0.0304
0.0145
0.0
0.0
0.0.
  TOTAL CARBON REQUIRED  =      2A.36 INCHES
  TOTAL STAGES REQUIRED  ASSUMING 2.35 IMCHE5. CARBON/STACE =10.37
  SPACE VELOCITY  -
  PRESSURE UROP ACROSS  CARBON  =     12.IB INCHES H20
  PRESSURE DROP ACROSS  PLATES  *      6.09 INCHES H20
  TOTAL PRESSURE DROP ACROSS  STAGES =    IB.27 INCHES H20
     RATE EXPRESSION  USED  IN DESIGN CALCULATIONS

  RATECt I » = COEFF *  Il-Xt I )/XSI**A * (YS02**8) *  (Y02*<-C )*JYH20**0)
     WHtRE
* EXP(-t/R*( l/IT-1460) ) )

                0.38
       -E/R-
          K=0.000159
                                                      0.400
                                                                     c=
                                                                          b.630
                                                                                          =
                                                                          0.130
                                                                        " 07730 "
                                              126
-------
       S02  SORBER DESIGN

 RUN NUMOER     SA-26   DATE  6  18  71
TOTAL CARBON RATE = 3.400 LBS/HK
; OUTLET CARBtJN LOADING * 0
! HEIGHT OF CARIJON/STAGE =
: DIAMETER Uh VESSEL = 6.0
CARBON USED = 96324.
TOTAL GAS FLOW RATE «
INLET S02 CONCENTRATION =
1 INLET NO CONCENTRATION =
{. INLET 02 VOLUME FRACTION
|_ INLET H20 VOLUME FRACTION
OUTLET S02 CONCENTRATION
TEMPERATURE = 200.0 DEC.
| $02 CONCENTRAT
i STAGE PPM
I 	 1 2055.
2 lf>31.
3 1595.
4 1350.
f 5 1100.
| •*.; 6 ... 851.
i . :/ 7.1. 	 611.
8 390.
9 200.
10 60.
i 0.14 46.0000
i 	 •-'- 	 	 -- 	 •'
.IH'JZS LUS AC1U/LU .CARBON , :
2.30 INCHES
.INCHES - ....,'•
1186. SCFH
150. PPH ' •. :. •. .: .•••••: ..-..'.• ••"V:.:.:^-;: T" T.v:- •:.;-::":: ":.;"- "•: . -•-' ••""':-[1,..' -'•'••-. - •
= • 0.0430 .:'••••• -' ~^^Q^'\^'^^^^^?^^^^-^ -: :'&^^^.^:'. • •• .
- n Hftfi'-^'s- • -•-••^--.:*^^ •••V.-<.:v'-x^sr:.^;^^^;/:.v-.^i«*i: •:•:..• -«i'.-^.-:>- ^•.^••.-. ,., . .'
....... O.» IjUU. v>.:' ,<:.:.:••....,. ........ ; .^v^.. S: »^i-»' ;». .; ;: i '•:.^.v.;;. ..C^.T-'.;. -'..I •,. v'.t ,"•'. .V- .• .. .
= 46. PPM
F
ION -'.-. ,ACtO LOADING ; ,•:;
LBS ACID/LB CARDON :
'" . ... .. " • :•'.. .. 0.1853 . , •- ' -••;/•. -•••:•
0. 1639
0.1414
0.1180
: 0.0941 ' ' ' ...
: ,,, , 0.0704 •.>'."
. ' ,.,"". '. :.:';.-, ' 0.0475.
0.0264
0.0083
0.0
0.0
  TOTAL CARBON REQUIRED =      23.31  INCHES
  TOTAL STAGES REQUIRED ASSUMING  2.30  INCHES CARBON/STAGE =10.14
  SPACE VELOCITY =  -   3110.  l/HH
  PRESSURE DROP ACROSS CArtftON  =     U.66 INCHES H20
  PRESSURE DROP ACROSS PLATES  «      5.83 INCHES H20
  IP!AL_PRESSURE PROP ACROSS STAGES =   	17.48 INCHES H2p
r	  " ~™~	
     RATE EXPRESSION USEU  IN  DESIGN  CALCULATIONS

  RAJECiJ )=COEFF * J1-X(I >/XSI**A  «  (YS02**B1 » (Y02««C 1  *  (YH20«*D)  ________„„______	
r^"  HHtRE CtlEFF = K" *"CXP(-E/R*(l/(Ti460l H                            ~        "             "" :"   ..:

\  ' ':>,'••   T«	, 200. _  ....".'. :.XS«  	0.38 '     VSU2--	YQg" .... 0.0^.3 '	YH20=    0.1 3JL
  ~"    -E/R=   '55201""         A«~  1.000         B«  "0.400          "C=   0.630         D=  " 6~~."/30
          K=0.000159
                                            127
-------
             APPENDIX A-8-2



   WESTVACO MODEL BY MULTIPLE REGRESSION

     COMPARED TO CONTINUOUS S02 SORBER
              Westvaco Model
 dXy     ,   -T       Xy x  n    m
 __  =  k e
where -E/RT = 5416°R



      n     =0.48



      m     = 0.62



      p     = 0.73



      k     = 3.32(10-4) gms. H2S04/gm. C-min
                   128
-------
       S02  SORBER DESIGN

 RUN  NUMBER     SA-21   DATE  6   7  71

 TOTAL .CA.UJ}.OiLKAIE..«  2.910 LBS/HR	
 CUTLET  CARBON LOADING = 0.17885  LBS ACID/LB CARBON
 HEIGHT  OF CARBON/STAGE =   2.25  INCHES
_JCLl AM EIE R  0 F.._V E S S E L.. »_. 6. J). 1 .MCHtS	
 CARBON  USED =  96524.
 TOTAL GAS FLOW RATE =     1247.  SCFH
_l;JL£J..SUZ.-COJJCJ:.NIRA.IJJMi_ =	.2009, J>PJ1	
 INLET NO  CUMCENTRATION =       150.  PPM
 INLCI 02  VOLUME FRACTION »  0.0120
._I;-------
      S02  SORBER DESIGN

 RUN NUMBER     SA-22   DATE  6 15 71

_TOTAL CARBON  RATE  =   3.260 LBS/HR
 CUTLET  CARBON LOADING = 0.22479 LBS ACID/LB  CARBON
 hCIGHT  OF  CARBON/STAGE =   2.35 INCHES
 L.IAKcTE*  OF VESSEL =.6.0 INCHES		
 CAKBCN  USED =  96324.
 TOTAL GAS  FLOW RATF  =     1141. SCFH
 INLFT SD?  CONCtNTKAT I UN « __   .3946. PPM	;	
 INLbT NO  CONCENTRATION *~	150. PPM
 INLET 02  VOLUKL" FRACTION *  0.0420
 INLFT M20  VOLUME FRACTION. = _0.1300	.	
"OUTLET  502 CONCENTRATION =     1151. PPM

 TEMPERATURE = 200.0  DEC. F __           	
            S02 CONCENTRATION        ACID LOADING
     STAGE          PPM            LBS AC10/LB  CARBON
	      1            3946,   _        	0.2248.   .
         2            3658.                  0.1972
         3       .     3333.                  0.1661
         4   __       2970.	    	0.1314	
         5            2574.                  0.0935
         6            2151.                .  0.0530
	7	17.14..	0.0_1.11
         8          *  1277.                  0.0
     0.31        1151.0005                  0.0
..TOTAL CAP.BON...REQU.IRED..=	_l.9_v53...!.NC.Ht.5	
 TUTAL STAGES REQUIRED ASSUMING 2.35 INCHES CARBON/STAGE = 8.31
. S P AC E. V E UiciT.V..=	3 5J_Q.  .
L/HfL.
 PRESSURE 0VROP  ACROSS  CARBON =     9.76  INCHES H20     .  ,
_PRESSURF,. DBOP. ACROSS  PLATES =  .   4.,8y..JNCHES H20    ..._,
 TOTAL PRESSURE  DROP ACROSS STAGES =     14.65  INCHES  H20
    KATE EXPRESSION  USED  IN DESIGN CALCULATIONS
 RATECII) = COEFF *  11-XI II/XS>**A * (YS02**B) *  (Y02**C)  * 
-------
      S02  SORBER DESIGN

 RUN NUKbER     SA-23   DATE  6  16  71

JOWL. CARBON P.AT.E =  .3.3SO LBS/HR  ______  _    ___
 UU11ET  CAKBOfl LOADING = 0.16660  LBS ACID/LB CARBON
 HEIGHT  l)f: CARBON/STAGE =   2.40  INCHES
_i,IAMET£K  OF. VESSEL .? ____ 6..Q_LiCU£5
 CARBON  UitO -  96324,,
 TOTAL  GAS FLOW RATE "     1106. .SCHH
 LNkEJL  $Q2._C_QNCE.NI.f.; .....
_. 0.0123 \
0.0 i • •
0.0
:-.:V:. ., :,:.•: : ..-.- '•'. ' '•:'•. , • ' • -. ' '
•••••"•• -'• ' ' '• • 	
  TOTAL  STAGES REQUIRED ASSUMING  2.40 INCHES CARBON/STAGE  =  8.25
V  PRESSURE  DROP ACROSS CARBON =      9.90 INCHES H20     -:.'•
LERESSURf .BRUP-.ACROSS.. PLAT£S._=	_..4_, 9i_JjNI.CHE5_H2.0	
  TOTAL  PRESSURE DROP ACROSS STAGES  =     14.85 INCHES H2U
     RATE  EXPRESSION USED IN DESIGN  CALCULATIONS
^ATECI I I=COEFF * ( l-X( I ) /XS 1 **A * (YS02**E» * (YOJ
WHERE COEFF = K * EXPI-E/R* ( I/ ( T*460 ) ) 1
T =
-E/R=
200.
5416.
XS =
A»
0.38
1.000
Y02*
B=
>**C) *
~oToT£
0.480
                                                              vH2**l
YH20=
   C«
                                                                        0.130
                                                                        0.620
                                                                                         0=    0.730
                                             131
-------
      S02 SORBER DESIGN
 RUN NUMBER
                SA-24   DATE  6  16  71
 TOTAL CARBON RATE =  3.190LBS/HR  ........ _ ..... _
 OUTLET CARBON LOADING - 0.1883'. LDS  ACIU/LB CARBON
 HEIGHT OF CARBtlN/STAGE
                            2.45  INCHES
_DJAK£ICft OF VESSEL -  6.0  INCHES
 CARBON USED =  96324.
 TOTAL GAS FLOW RATE --
_INLET SU? CONCENTRATION^
 "INLET NO CONCENTRATION «
 INLET 02 VOLUME FRACTION =
 INLET H2U VOLUME FRACTION
 OUTLET S02 CONCENTRATION -
                            965.  SCFH
                                3982. PPK
                                156..  PPM
                             0.0460
                              0.1300 __
                                 1078.  PPM
JLEMKERATURE
STAGE
	 .. 1 ...
2
3
4



5
6
7
8
9
10
0.32
= 350.0 DEC. F
S02 CONCLNTKA1 ION
PCM
5982,
3720.
3439.
3139.
2823.
2495.
2157.
1317.
1480.
1170.
1078.0002

ACID LOADING
LBS ACID/LB CARBON
0-1883 _^
0.1667
0.1434
0.11B6
0.0925
0.0654
0.0375 i
0.0093 /
0.0
0.0
0-0 ., „'.:•:„ • ... ,.',.. „ - ;
 TOTAL CAR60N REQUIRED =     25.28  INCHES
 TOTAL STAGES REQUIRED ASSUMING 2.45  INCHES CARBON/STAGE  =10.32
 SPACE VELOCITY =
                      2332. 1/HR
 PRESSURE DROP ACROSS CARBON =    12.64  INCHES H20
 PRESSURE DROP ACROSS PLATES =     6.32  INCHES H20
JTOTAL PRfcSS.URfc_ DROP. ACROSS .STAGES.. =	18.96  JNCHCS  H2CL	
    RATE EXPRESSION USED IN DESIGN CALCULATIONS

.RATECt I ) = COEFF * ( 1-X I I I / XS I »*A . * 1 YS02**6 ).. *_
    WHERE  COEFF=K * EXPI-E/R* ( I/ ( T+460 ) ) )
         T= __..250. ...... ______ XS* __  _0.3fi__     Y02=
      -E/R=   5416.         A=    1.000         B-
         K=0. 000332
                                                         *.IYH20**DI
                                                     0.0'(6   __
                                                     0.480
 =  ,0.130	  ..  				
C=   0.620         0=    6.730
                                           132
-------
       S02 SCIRBER DESIGN

 RUN NUMBER     SA-25    DATE  6 17 71

_JQTAL_CAR_BQN _RALE_f_-3.210_LBS/HR	.	
 OUTLET CARBON LOADING =  0.12817 LBS AC1D/LB  CARBON
; HEIGHT OF CARBON/STAGE  =   2.35 INCHES
_D.I A.METE.R .OF. .V£SSEL^=__6.,ja._JJi.Clt£S	
 CARBON USED -  9632'..
 TOTAL GAS FLOW RATE -      1094. SCFH
  INLET_SQ2 CONCENTRATION  -   _ 2028._ PPM_ __ _ _	
rINLET NO CONCENTRATION  =      150. PPM
  INLET 02 VOLUME FRACTION =  0.0410
_JNLF.T H.20 ..VOLUME. F.RAQJ.I.CN__=__0J.13.00			
 OUTLET S02 CONCENTRATION =      411. PPM

 TEMPERATURE = 250.0 DEG._F	
"            S02 CONCENTRATION        ACID LOADING
i     STAGE         PPH             LBS ACIU/LB CARBON
;	.1	2.Q28->	0.. 128^	
         2           1834.                 ' 0.1104
         3           1636.                   0.0923
,	4	.	14.37.;	.0,0741. _
                     1239.                   0.0559
                     1045.                   0.0382
                            	'  •-	  0.0210	
                      679.                   0.0047
                      515.                   0.0
                 _4 H..OOO-0 ,  ,   ,	0 ,J)	
  TOTAL CARBON RtQUlRfcD  =      22.80 INCHES
  TOTAL STAGES REQUIRED  ASSUMING 2.35 INCHES CARBON/STAGE = 9.70
  SPACE VELOCITY = ,     2934.  1/HR
                                      ^4.0_I NCME.S_H2Q	
  PRESSURE DROP ACROSS  PLATES =     5.70  INCHES  H20
  TOTAL PRESSURE DROP ACROSS STAGES =     17.10  INCHES H20
   .._RAT.£..£XP.R£5S1QN..1JSED_..IN^DES.LGN_£A.LCU1A_TJO_NS-
  RATEC(I) = COEFF *  (1-X(I I/XS)**A * (YS02*»BI  *  (Y02**CI * (YH20**D>
 ___ WHERE COEFJ:=K.*_..EXP.(-E/R*iayj.T.±4.60.JLU	-	—
          T=    250.         XS=    0.38        Y02=    0.041      YH20=    0.130
               5416^	^	A=	L..OaO-	BL-.	Q.4dO	£±	O..I.6.2P	..JJ? .-.0
          K=0.000332
                                              133
-------
       S02 SURBER DESIGN

  RUN NUMBER     SA-26   DATE   6  18  71

_JOTAL  CARBUU RATE =  3.400 LBS/Hft            _   ,. _		
  CUTLET CAkl'CN LUAU1NG = O.IB528  LBS ACID/LB CARBON
  HEIGHT cr LARHOM/STAGE -   2.30  INCHES
  C1AMETER Or VESSFL -_ 6.0  INCHES _			_.	
'CARBON USED -  9&324o
  TOTAL  GAS ROW RATE =      1106.  SCFH
  INLET  SC2 CONCENTRATION =     2055. PPM       	 _j	
  INLET  NC CONCEPT RAT'i ON =      150'.  PPM
  INLET  0? VOLUME FRACTION =   0.0430
  INLET  H20 VOLUME TRACTION  -   0.13_00	.	,	
  CUTLET SU2 CONCENTRATION -       46.  PPM

  TI-MPiRATURl  - 200.0 !)F&. f
             SU2 CONCENTRATION         ACID LOADING
      STAGE         PPM            LBS  ACIU/LB CARUON
         1           20^5.      		P.je>3	'.	
         2           1(306.                   0.1615
         3           l'.''.c>.                   0.1366
         4           12/7.                   0. 1111  _
         .5           1010.                   0.0856
         (S            75?.                   0.0609
         7	___51$.   _      ^	   	O.OJ82	
         8            308.                   0.0185
         9            H5.                   0.0030
      0.90_      ... .46.0000	Q.O				



  lofAL  CARBON REQUIRED =     22.77  INCHES       '     ""
  TOTAL  STAGES REQUIRED ASSUMING 2.30 INCHES  CARBON/STAGE = 9.90

"SPACE  VELOCITY -     3185.' 1/HR "        "      '.        "~~~ '.-.'•.
                                                            ;"   ,^, ^ , . '/ '

...PRESSURE OR.QP ACROSS. CARBQN._.=	11 .3_C_ INCHES H.2.Q     ... .... ' '.'  ',.  .
  PRESSURE DROP ACROSS PLATES =     5.69 INCHES H20
  TOTAL  PRESSURE DROP ACROSS STAGES =     17.08 INCHES H20



     RATE. EXPRESSION  USED IN DESIGN CALCULATIONS   ..   _ 			

  RATEC1 I ) = COEf-r t U-X( I I/XS)**A  * (YS02**ll|  * (Y02**O * (YH20**D)
     WHLKE  COEFMK *  EXP(-f./R» ( I/ ( T+460 )} I .	._		
          T=     200.
       -E/R-    5416.
          K=0.00033^
 0.38
1.000.
0.043
.0.480
                                                                  YH2()=
0.130
0.620
                                                   	0«._... 0.730
                                              134
-------
                APPENDIX A-8-3

WESTVACO MODEL BY MULTIPLE REGRESSION  (LOADING
FACTOR ORDER) COMPARED TO CONTINUOUS S02  SORBER
                Westvaco Model

  dXv
dXv     ,   -E/RT
-jrr  =  k e  ' ^
  where -E/RT = 5732°R

        A     =1.83

        n     = 0.53

        m     = 0.62

        p     = 0.73

        k     = 3.42(10"4)  gms.  H2S04/gm. C-min
                      135
-------
      S02 SORBER DESIGN

 RUN NUMBER     SA-21   DATE   6   7 71

_TOTAL CARBON RATE -   2.910 LBS/HR	
 OUTLET CARBON LOADING =  0.17885  LBS  ACID/LB CARBON
 HEIGHT Of- CARBON/STAGE =   2.?5  INCHES
 OIAItTER LT VESSLL •-=  6.0  INCHES	..._		
 CARBON USED "»  96324.
                            1247.  SCFH
                              _2009.  PPM
                                150.  PPM
                               0. 1300 ...... ...
                                  165.  PPM
 TOTAL GAS FLOW  RAFE  =
 INLET SO? CONCENTRATION  =
"INLET NO CONCENTRATION  «
 INLtT 02 VOLUME  F-RAC1IO.M =
 INLET H20 VOLUME  TRACTION *
 OUTLET S02 CONCEN1 RATION =

_TEHPfRATURC = ?00.0  F)FG.  F                  .     	„
            S02  CONCCNTRAT10N        ACID LOADING
     STAGE         PPM             LBS ACIO/LB CARBON
	   1    	   2009,  .		__ D«J7.8e	
        2           1840.                   0.1590
        3           1649.                   0.1367
        .4  		1436.	Q..U17.	
        5           1202.                   0.0843
        6            .951.                   0.0549
	7.__			692..	,	CW)24e>	
        8            443.                   0.0
        9            231.                   0.0
	0.41		165 ..0.001	0...0.	



 TOTAL CARBON REQUIRED -      21.17  INCHES
 TOTAL STAGES REQUIRED ASSUMING 2.25 INCHES CARBON/STAGE = 9.41

 SPACE VELOCITY  =     3600. 1/HR                   .      V  ;     .:                    ~

.PRESSURE DROP ACROSS CARBON.  =	10.5fa. I NCHES H20 ._..U;^11	.'....	__IL.^__			_
 PRESSURE DROP ACROSS PLATES  «=      5.29 INCHES H2U
 TOTAL PRESSURE UROP ACROSS STAGES  =    15.87 INCHES H20



.   .RATE EXPRESSION USED  IN DESIGN  CALCULATIONS	 		

 RATECIII=COEFF *  (1-XI I I/XS)**A *  (YSC2**B) * (Y02**C) *  (YH20**D>
.._ WHERE CDEFF--K. * CXPI-E/R* (1/J T.f 46QJJ J					

         T=     200.        XS=    0.38       Y02=   0.042      YH20=    0.130
	 -E/R=...  5732.  ...    .  .A=_.1.83JQ_	__	B=. . ..0.530			C=.   .0.620.     „  D=    0..730
         K=0.000342
                                              136
-------
       S02  SORBER DESIGN
                 SA-22    DATE   6 15 71
 RUN  NUMBER
_J.QT_AL  CAKBON RAT.E_ = .._3..260 LBS/HR			
 OUTLET  CARUON LOADING  *  0.22479 LbS ACIU/LB  CARBON
 HEIGHT  t:F CARBON/STAGE =   2.35 INCHES
_U1AKE.TER .OF.-.V.ESSE.L _= ._&c.0....1j " 6
'. • , 7
8
9
200.0 DEC, F
CONCENTRAT ION
PPM
3772.
3569.
... 3329,. . ..
3045.
2712.
2322,
1875.
1381.

ACID LOADING
LBS ACID/LB CARBON
0.2248
0.2082
0.1887
	 _ 	 0.1657
0.1386
0.1067 ' - '•' . ' •:'*: '•• - '• ": •"• '-a •;•<"
0.0694
0.0266
0.0
                                          	A..Q.	
  TOTAL  CARBON P.EQUIRCO =      22.24 INCHES
  TOTAL  STAGES REQUIRED ASSUMING 2.35 INCHES  CARBON/STAGE = 9.46
  SPACE  VELOCITY =
L_P_R£3SUG.E_DRQP_
                        3135.  1/HR
  PRESSURE  DROP ACROSS  PLATES  =
  TOTAL  PRESSURE DROP ACROSS' STAGES
                                     ,L,12 _LNCJiES__H2Q	
                                     5.56  INCHES H20
                                           16.68 INCHES H20
                          _LN. D.ES1G1.JLALCUIAT1UN.S. „
	RATt. EXPRESSION

  RAIECII ) = COE1:F *  (1-XI I )/XSI**A *  (YS02**B)  * (Y02**C> *  (YH20**D)
	WHERE CGtFF'K  *  EXP(-E/_R* I1/..I J_*46a»J I	.	™
          T*    200.
       TE/.R=.	-5Z32.
          K=0.000342
 XS=    0.38
...A?.._....»..6.3 0._..
                                                Y02=   0.042
                                              	B»_  0.530
                                                                  YH20=
                                                                           0.130
                                              137
-------
       $02  SORBER  DESIGN

 RUN NUMBER      SA-23   DATE  6 16 71

_!OTAL  CARBON  RATF  =   3.350 L9S/HR 	_„._
 OUTLET CARBON LOADING = 0.16660 LBS ACILVLB CARBON
 HEIGHT OF CARBON/STAGE =   2.40 INCHES
__UlAKETER  OF VESSEL =  .6.0.INCHES. 			
 CARBON USED =  96324.
 TOTAL  GAS FLOW RATE  -     1106. SCFH
.JNLET  S02 CONCENTRATION .=	2.0.0.9._. PPM	
 INLET  NC  CONCENTRATION -      150. PPM
 "INLET  02  VOLUME  FRACTION -  0.0420
 INLET  H2D VOLUME FR*CTI ON. .= __0...1.300.	
 OUTLET S(J2 CONCENTRATION ='       91."~PPM~

 TEMPERATURE  = 200.0  DEC.  F   _
            S0~2 CONCENTRATION         ACIO LOADING
     STAGE          PPM            LBS ACIO/LB CARBON
         I           2009._   _	_			  .0.1666	
         2            1764.                   0.1463
         3            1537.                   0.1240
   	4   	1,2.70..   	Q.0999	
         5             989.                   0.0745
         6             707.                   0.0491
	 _   7_	_4.42*,_      _  	0.0252.
         8             220.                   0.0051
     0.79         91.0000                  0.0
JTOTAL CARBON.  REQUI.R.EU_»
 TOTAL STAGES  REQUIRED  ASSUMING 2.40 INCHES CARBON/STAGE = 8.79

_.S_PACE: VELOCITY.? ____ 32J.4.  1/HR_ __________ ^ ______ , __ . _____ , ____ , __ ^

 PRESSURE DROP ACROSS CARBON  =     10.54 INCHES H20    :;  . •'.. ••••-. •;-•::
_P.RtSSURE DROP. ACROSS PLATES  =   __ S.^T^INCHES H20   ' ^'.'.f* ". '.  "
 TOTAL PRESSURE DROP ACROSS  STAGES =    15.82 INCHES H20
    RATE EXPRESSION USED  IN  DESIGN CALCULATIONS
 RATEC ( i - COE FF *  i i-x (  ) / xs > **A*  i vs2**B )  * ( v2**c  * "vH2o**o  '
    WHERE COEFF'-.K  *  EXP l-E/R« ( It I T + 460 I I )
          s    200.         XS=     o38        Y02=   o.042      VH20=   6.'l30 ...... ~     :
         R=   5732.          A=    1.830          B=   0.530         C=   0.620          0=   0.730
         K=0. 000342 ......... ________
                                              138
-------
       S02 SORBER DESIGN

  RUN  NUMBER     SA-24   DATE   6  16  71

 .TOTAL CARBON. RATE . = ._.?.. .190. LBS/HR	
  OUTLET  CARBON LOADING = 0.18034  LOS  ACIO/LB  CARBON
  HEIGHT  CF  CARBON/STAGE =   2.45  INC-HES
_OJAMETER. OF VLSSEL_»	6._0_1NCHLS	
  CARBON  USED =  9632'..
  TOTAL GAS  FLOW RATE =      965.  SCFH
_1 NLEJ__S02_CONC.ENJ_RAT [ ON «	3.982 ._PPH	
  INLET  NO CONCENTRATION =       150.  PPM
  INLET  02 VOLUME FRACTION =  0.0460
  INLET  H20 VOLUME. FRACT I_CN_=__0. 1_30_0_	
 "OUTLET S02 CONCENTRATION =      1078.  PPM
 JE.MPERATURE.; 250.0 OE6,_R	
S02
STAGE
„ 	 .JL.._ _
2
3
A ... '
5
6
7
8 .
9
10
11
0.04
CONCENTRATION ACID LOADING
PPM LBS ACID/LB CARBON
3982. 0.1883
3800.
3597.
3371.
3117.
2836.
2525.
, 2185.
1821.
1439.
1090.
1078.0002
0.1733
0.1565
0.1378
0.1168
0.0936 -:'.-:'' ; ' ••••'•' ' ' ' ::-- •••''•'
0.0679
0.0398
0.0096
0.0
0.0 : -• - '
0.0
,_JDJLAJL_CARBOS_R£ QU I RED. =.__ ___  ^_     ___________
j  TOTAL  STAGES REQUIRED ASSUMING  2.45  INCHES CARBON/STAGE =11.04
                        18Q .  1/HR
  PRESSURE DROP ACROSS CARBON =     13.52  INCHES H20
^_PAESSURE._ DROP-ACROSS . P.LATES_=	6.^.76_JNCHES_ H20		
I  TOTAL  PRESSURE DROP ACROSS Si AGES =     20.28  INCHES H20
     RATE  exPRESSIOM USED IN DESIGN CALCULATIONS
  RATl'C(I)»CUEFF * I l-X ( I )/XS) **A  *  **B)  *  IY02**C)  * (YH20**DI
     WHERE  COEFF-K *  tXPI-t/R»I I/IT + 4601I)
          T=    250.        XS=     0.38        Y02«   0.046      YH20=   0.130
       -E/R*   5732.         A*    1.830          B=   0.530         C=   0.620          0-    0.730
          X=0.000342	-'		..-_	—		-:	—		
                                              139
-------
       S02 SORBER DESIGN

  RUN NUMBER     SA-25   DATE  6  17 71

  TOTAL CARBON RAT f =  3.270 LBS/IIR
  OUTLET CARBON LOADING - 0.12817 LBS ACID/LB  CARBON
  HEIGHT OF CARBON/STAGE =   2.35 INCHES
  DIAMETER OF VESSEL =__6.0 INCHES	
 "CARBUN USED =  9f<324.
  TOTAL GAS FLOW RATE =     1094. SCFH
  INLtT S02 CONCENTRATION ^_   _2028. PPM   _     	
 "iNLtT NO CONCENTRATION""*'  ~" i so ."PPM	"
  INLET 0           .        '            \   :
_PBESSURE.'*DRPJ>_.ACROSS_CARBOri.=	11.61 INCHES H20
  PRESSURE DROP ACROSS PLATES -     5.80 INCHES H20
  TOTAL  PRESSURE DROP ACROSS' STAGES =    17.41 INCHES H20
     RATE .EXPRESSION USED IN DESIGN CALCULATIONS
  RATECII I = COEFF * I1-X(I I/XS)**A * (YS02**B) *  
-------
       S02 SOR6ER DESIGN

 RUN  NUMBER     SA-26    DATE  6  18  71

_TO.TAL .CARBON..RAJE..?_....3.,AOo.LBS^HR._	
 UUTLtT  CAROON LOADING  = 0.1852B LBS ACIO/LB CARBON
 HEIGHT  OF CARBON/STAGE =   2.30 INCHES
_DIAMETEK OF_VESSC.L. = _&,0._.U&. PPM_	
 INLET NO CONCENTRATION =      150. PPM
 INLEt 02 VOLUME FRACTION =  0.0430
_.INLE1 H20 VOLUME. FRAC.TICN_=	.0..13QO.....	
 OUTLET  Sl)2 CONCENTRATION -       46.  PPM

_TEMPERATURE =...200.0 DEC. f	   . 	_.
             S02 CONCENTRATION        ACID LOADING
      STAGE      ,    PPM             LBS  ACID/LB CARBON
                      2055,	 _ _Q_.1853
                      1879.                   0.1685
                      1685.                   0.1500
                                            _Q.,_1296
                                              0.1080
                                              0.0850
                                      '	Q»06.16._
                                              0.0390
                                              0.0186
   ,	10	IAD,           	_
  -.;•;   0.83          46.0000      ;    >:  :     0.0
  TOTAL CARBON REQUIRED =     24.92  INCHES
        .STAGED'KE.QU 1 RE0,AJSU.MJNfi,1-.3J)_'INCHE_S_ CARBOhi/STAGED?..lp..JJ_
  SPACE VELOCITY = -     2910. 1/HR
  PRESSURE DROP ACROSS  CARBON =     12.46  INCHES H20
  PRESSURE DROP ACROSS  PLATE.S =     6.23  INCHES H20
  TOJAL . PRESSURE. DROP AC.ROS,S_3JAG.E.S-. = .	18.69.. 1.NCHES....H20..,	
     RATE EXPRESSION  USED IN DESIGN CALCULATIONS

...RATEU I I-CQEFF *  < 1-X( I I/X$)**A.. * .(YS02**B)_Jf_ tYQ2**CJ.. *_t.YH2.0**D)		_	  	 	
     WHERE CQEFf:=K  *  EXPI-E/R* (I/ I T+460) ) )

	T»_	?JX>*	1_...  X.S.;	_0,.3.8...	V.Q2=	O.,0_43	YJ120*	0..1.30	
       -E/K'   5732.          A=   1.830          B-   0.530          C=   0.620          D=    0.730
          K=0.000342
                                              141
-------
                        APPENDIX A-9


             S02 SORBER DESIGN - EFFECTS ON SIZE
Appendix    A-9 includes the detailed results of the S02 sorber
design study which encompassed the effects of the following
parameters on reactor size:

     1)  Inlet S02 Cone.  -  2,000 PPM

     2)  Inlet 02 Cone.  -  0.046 mole fraction
     3)  Inlet H20 Cone.  -  0.13 mole fraction

     4)  Outlet Acid Loading on C  -  0.183 Ib. acid/lb. C

     5)  Temperature  -  200°F
     6)  Linear Gas Velocity  -  4 ft./sec.
     7)  Carbon Bed Depth/Stage  -  9 inches.


Each parameter was varied separately while holding all others
constant at the base conditions given in parameters in the
preceding list.

The results are summarized in Figures    A-9-1 to    A-9-10,
in which the dependence of reactor size on each parameter is
shown graphically.  Figure    A-9-1 shows the effect of inlet
S02 concentration on carbon requirement for a S02 removal of
90%, while Figure    A-9-2 presents the same effect but for a
specific outlet S02 concentration of 50 ppm.  All other cases
are based on a S02 removal of 90%.  Figures    A-9-3 through
   A-9-6 show the effects of 02 concentration, H20 concentra-
tion, outlet acid loading, and temperature.  Figure    A-9-7
shows the effect of linear velocity at carbon bed depths of 4,
9, 18 and 32 inches.   Figures    A-9-8 through    A-9-10 show
the effect of carbon bed depth at linear velocities of 2, 3,
and 4 ft./sec., respectively.

The raw results as obtained from the computer program are
presented following the figures.
                             142
-------
                  Figure A-9-1
Effect of inlet S0£  concentration on carbon required
to  remove 90%  of  the S02
00
                  -  40
                  •a
                  c
                  3
                  a-
                  &
O-
OJ
a


§
J2
10
•4J
O
                                                           Outlet Acid Loading:
                                                           Linea.- Gas Velocity:
                                                           Carbon Bed Depth/Stage:
                                                           Inlet Og Concentration:
                                                           Inlet HgO Concentration
                                                           Temperature:
                                           0.184 Ib. Acid/lb. Carbon
                                           4  Ft./Sec.
                                           9  Inches
                                           0.046 Volume Fraction
                                           0.13 Volume Fraction
                                           200° F
                                                     1500       2000        2500

                                                     Inlet S02 Con:entration, ppm
                                             3000
                                                                            3500
4000
-------
        Figure  A-9-2
                         Effect of inlet S0£  concentration on
                         carbon required to achieve  an  outlet
                         S02 concentration  of 50  ppm
   70
   60
 CO
   50
 OJ
 V-i
•H

 cr 40
4J
CX
0)
Q

a
O
30
4J
O
H
   20
   10
                                   Outlet Acid Loading:
                                   Linear Gas Velocity:
                                   Carbon Bed Depth/Stage:
                                   Inlet 02 Concentration:
                                   Inlet H20 Concentration:
                                   Temperature:
0.184 Ib. Acid/lb. Carbon
4 Ft./Sec.
9 Inches
0.046 Volume Fraction
0.13 Volume Fraction
200°F
              500       1000       1500      2000       2500

                                Inlet SOg Concentration, ppm
                                                          3000
            3500
4000
                                      144
-------
    Figure  A-9-3
Effect of inlet  02  concentration on
carbon required  to  remove  90% of an
inlet  S02 concentration of 2,000 ppm
   70
  60
  50
4)
.C
U
•o
c
   40
   30
a
4->
O
  20
  10
                   Outlet Acid Loading:
                   Linear Gas Velocity:
                   Carbon Bed Depth/Stage:
                   Inlet HgO Concentration:
                   Temperature:
                0.184 Ib. Acid/lb. Carbon
                4 Ft./Sec.
                9 Inches
                0.13 Volume Fraction
                200°F
              0.02
  0.04         0.06        0.08

  02 Concentration, Volume Fraction
0.10
0.12
                                  145
-------
       Figure A-9-4.   Effect  of  inlet  H£0  concentration  on
                          carbon  required  to remove  90%  of an
                          inlet S02  concentration of 2,000 ppm
   70
   60
   so
o
c
sr 40
5
o.
&   ,
§ '
•e
S30
                  Outlet Acid Loading:
                  Linear Gas Velocity:
                  Carbon Bed Depth/Stage:
                  Inlet 02 Concentration:
                  Temperature:
            0.184 1b. Acid/lb.  Carbon
            4 Ft./Sec.
            9 Inches
            0.046 Volume Fraction
            200°F
  20
  10
               0.04
0.08        0.12         0.16

H20 Concentration, Volume Fraction
                                                             0.20
0.24
                                    146
-------
      Figure A-9-5.
Effect of outlet acid  loading on
carbon required  to  remove  90% of
an  inlet  S02  concentration of
2,000  ppm
  140
  120
V)

u

* 100
 *
•a
   80
a.
£
   60
a
   40
   20
         Linear Gas Velocity:
         Carbon Bed Depth/Stage:
         Inlet 02 Concentration:
         Inlet HgO Concentration:
         Temperature:
4 Ft./Sec.
9 Inches
0.046 Volume Fraction
0.13 Volume Fraction
200°F
                                _L
             0.05      0.10      0.15      0.20       0.25

                       Outlet Add Loading, Ibs. Acid/lb. Carbon
                                 0.30
             0.35
                                    147
-------
     Figure A-9-6
         Effect of temperature  on carbon
         required  to  remove  90% of an inlet
         S02 concentration of  2,000  ppm
   90
   80
   70
VI

I  60
•o
2
   50
f!
o.
g

1  40
,2
   30
   20
   10
                  Carbon Bed Depth/Stage:
                  Outlet Acid Loading:
                  Linear Gas Velocity:
                  Inlet Og Concentration:
                  Inlet H20 Concentration:
                       9 Inches
                       0.184 Ib. Acid/lb.  Carbon
                       4 Ft./Sec.
                       0.046 Volume Fraction
                       0.13 Volume Fraction
     175
200
225          250

       Temperature, "F
275
300
325
                                    148
-------
      Figure  A-9-7
                    Effect of linear  gas velocity on

                    carbon required to  remove  90% of an

                    inlet SC>2 concentration of 2,000 ppm
                    at various carbon bed depths/stage
   80 -
   70 -
   60 -
VI
01

u
c
•o
OJ

•r-
3
cr

&
a*
o

•o
-------
               Figure A-9-8,
Effect  of  bed  depth on carbon required to remove  90%  of  an
inlet SC>2  concentration of 2,000  ppm  and  the  pressure drop
across  carbon  + plates
Ui
o
                 60
                •i
                •6
                t
                "5
               •5
               a.
               &

               S
               •e
                 40
                 30
                 20
                 10
                                                                                                               70
                                                                             60
                                                                                §
                                                                                •e
                                   Outlet Add Loading:
                                   Linear Gas Velocity:
                                   Inlet 02 Concentration:
                                   Inlet H£0 Concentration:
                                   Temperature:
                         0.184 Ib. Acid/lb. Carbon
                         2 Ft./Sec.
                         0.046 Volume Fraction
                         0.13 Volume Fraction
                         200° F
                                                                             40
                                                                             30
                                                                                                                  £
                                                                                                                  o.


                                                                                                                20o
                                              12
                     16
20
24
28
32
36
 10
40
                                                     Settled Bed Depth, inches
-------
Figure  A-9-9
Effect  of  bed  depth on carbon required to remove  9070 of  an
inlet S0£  concentration of 2,000  ppm  and  the  pressure drop
across  carbon  + plates
  60
 I
 u

 * 50
 £
 tx
 &
 o
 _ 30
 a
   20
   10
                                                                             60
                                                                               Si
                                                                             50.2
                                                                               t.
                                                                               3
                             Outlet Acid Loading:
                             Linear Gas Velocity:
                             Inlet 02 Concentration:
                             Inlet HgO Concentration:
                             Temperature:
0.184 Ib. Acid/lb,  Carbon
3 ft./sec.
0.046 Volume Fraction
0.13 Volume Fraction
200 °F
                                                                                                40
                                                                             30
           20?
                                                                             10
                               12        16        20        24

                                      Settled Bed Depth/Stage, inches
                                                28
         32
36
40
-------
           Figure A-9-10
hO
Effect  of bed depth  on  carbon required to remove  90%  of an
inlet S02 concentration of  2,000  ppm and  the  pressure drop
across  carbon + plates
                                                       Outlet Acid Loading:
                                                       Linear Gas Velocity:
                                                       Inlet Og Concentration:
                                                       Inlet H20 Concentration
                                                       Temperature:
                                           0.184 Ib. Acid/lb. Carbon
                                           4 Ft./Sec.
                                           0.046 Volume Fraction
                                           0.13 Volume Fraction
                                           200°F
            20
                                                   16       20       24

                                                 Settled Bed Depth/Stage, inches
-------
              APPENDIX A-9-1

EFFECT OF CARBON BED DEPTH/STAGE ON THE TOTAL
  CARBON BED DEPTH REQUIRED TO REMOVE 90% OF
   AN INLET S02 CONCENTRATION OF 2000 PPM
     Linear Gas Velocity,
     	ft. /sec .	    Run Number

               2               Test-1
               2               Test-27
               2               Test-28
               2               Test-29
               2               Test-30

               3               Test-3
               3               Test-31
               3               Test-32
               3               Test-33
               3               Test-34

               4               Test-4
               4               Test-5
               4               Test-6
               4               Test-7
               4               Test-8
               4               Test-9
               4               Test-10
               4               Test-11
                  153
-------
      S02 SORBER DESIGN

RUN  NUMBER    TEST-1    DATE   7 27 71

TOTAL CARUON RATE = 25.320 LBS/HR
OUTLET'CARBCN "LOAD ING =  6YT8375 ' LOSi""AC I D /'LB  CARBON
HEIGHT OF CARBON/STAGE  =    2.45 INCHES
D I AME TER OF V ES SE L_ =  18_.0_I_NCHES^__^	
CAR DON" USED""="  	~o>
TOTAL GAS FLOW RATE =      948'.. SCFH
INLET S02 CONCENTRATION^ 	_2..000* PP^	
"INLET 'NCTCON'CENTRAYlON  =  .~   T'50". PP'M: ; ;.• ••,''"•'•••}:;.*"!';"
INLET 02 VOLUME FRACTION  =  0.0460 ,   .;;   ::':  ;;" .:' •; :
INLET H20 VOLUME FR AC T I 0_N_=___0. 1_300_ -^ ^ '- ' '/j'v v--::j.
UUTLET"SU2 CONCENTRATION "=    """200 . "P"PM~ "~	
TEMPERATURE = 200.0  DF.G.  F	   	
	    S62'~CON'CENfRATTUN       "TcTO" LOAD ING'"*	
     STAGE         PPM    ,  .-.;:••"::.  LBS ACID/LB CARBON
        1  :          2000.-:-;>-:v:.'':.:;l'-::-::Xr::^:    -..'-0.1837
                     1723.                    0.1553
                                             0.1249
                                             0.0933
3
A
5
C
7
1426.
1117.
807.
511.
252.
                                             0.031?.
                                             0.0047
     0.23        200.0001                    0.0
TOTAL  CARBON REQUIRED  =      17.71 INCHES
TOTAL  STAGES REQUIRED  ASSUMING 2.45  INCHES;CARSON/STAGE  -:7.23
SPACE  VELOCITY =      3637.  1/HR
PRESSURE DROP ACROSS  CARBON .='.  ', : 8.86  INCHES H20
PRESSURE DROP ACROSS  PLATES, = :/•   4 .43;-INCHES H20
IUT_AL  PRESSURE DROP ACROSS .STAGES =;; :p3»28  INCHES H2o;
                               154
-------
     S02 SORBER  DESIGN
RUN NUMBER
               TESY-3   DATE   7  27  71
 TOTAL  CARBON RATE = 37. 98_0__L.BS/HR   __ ______
"OUTLET CARBOKfTbAUTNG" "="0". 1837b  LbS ACT07TB~CARB"ON~
 HEIGHT CF CARBON/STAGE =    I. 85  INCHES,
J31AMETER OF VESSEL =  18.0  INCHES _ ________ ____ _
 CARBON l"US"ED"= ..... ~" ..... 6."
 TOTAL  GAS FLOW RATE =     14227.  SCFH
 INLET  S02 CONCENTRATION = _  200p_. PPM
" I N L E f  N 0 " "CO N C EN T R A T 1 0 N ='" ~~~ ^"7l 5 : 0"."
 INLET  02 VOLUME FRACT ION  -  • 0.0460
 INLET  H20 VOLUME FRACTION  =  Q.I 300
 OUT LET 'SU"2~CONC"EN"firAnON "=
                                    "P P M"
                                    ___
                                 "200. PPM
TEMPERATURE  =  200.0 DEG. F
1- ;::: STAGE
2
3
4
•':.-.• "A1". iMv:1-:-' •:'. 6 X
^^OV^TH
8
9
10
: 11
: I i
;.--•: . • 12
S02 CONCENTRATION
::: :••,-- PPM
:iV; '"':^' '2000.
1858.
1711.
1558.
£'••£•' • I"--- .124*f*^.:w
920.
761.
607.
" ' £A 1 •:.:J!"'lv:::O
f O JL . : :,:.v.v:: :•:,...
ACID LOADING
LBS ACID/LB CARBON
0.1837
0.1692
0.1541
0.1385
:^%;.a :J:!*v,::;.:-i.;:.;-":.. ' 0. 1225 •..•.• -. v •.. . • • : ;.f ::;::i ;:,,-..-t
w4pps.f/:,;:>. . .'•. 0.1061 '". :-vi:::--:^: ••.^Sii^iJ,.-
'-:•, '•:•: .•:-.• •'•'•; *-.-' : :•: .•:•" ••;•' '-:-:•:•: ;.-••: .. __ ,,•.,•...•.••••.• - • •••.•.•>•-. .• •. .-• ;• • • •
.•:••.•;•:•• .• . : . . ; •:•.- •:• ;•:.,: f\ f\ (i G A - •• • ••• • • .-...-., :•• ••••• •* •• - - •- -
••.•••;; ' ' '•/ -.• • ••-•".-.' 	 •'-: - . -, • \j v \) o ^y o -:•' .-:•. . . • • , ' • ; : - "•:;:-••.-. :••-,• - :•.- •.-.'•
0.0731
0.0568
0.0410
On ~j A i '.''••• - •
* UC-O 1 .. ••.-...,... •:.•..•;..•.:
K:§ff::m. ^M ":. o .0122 " ' ""' v-^*f^:^:'.. • .
lii:;v;:i'^,;:;i^:;:::;'; ..; o . o . &&&:'•£**<'' '
    0.06
                 200.0001
0.0
TOTAL CARBON  REQUIRED  =      24.16 INCHES
TOTAL STAGES  REQUIRED  ASSUMING;;!.851.INCHE.S CARBON/STAGE  =13.06
SPACE VELOCITY  =
                      4000.  1/HR
PRESSURE""i3ROT"ACROSS  CARBON =  ;; 12.08 INCHES H20
PRESSURE DROP  ACROSS  PLATES =; 6.04 INCHES H20
TOTAL PRESSURE  DROP ACROSS STAGES = >;:v' 18.12  INCHES  H20
                             155
-------
      S02 SORBER DESIGN
 RUN NUMBER
              TEST-4
DATE  7 27 71
 TOTAL  CARBON RATE =__5^0_ IBS/HR	
"6 U T L E r C A R B 0 N ~ 10AD'ING = "6". 18 375 GTS" ACID*
 HfclGHT OF CARbON/STAGE =   1.65 INCHES
 DIAMETER OF VESSEL - 18.0 INCHES
"CARBON
 TOTAL
 INLET
 INLET
                                             CARBOf
       USED =      0.
      GAS FLOW RATE =    18969.  SCFH
      S02 CCNCFNTRATION_=_    2000. PPM
     "NOCCNCENTRATTO'N =
 INLET 02 VOLUME FRACTION =
 INLET 1120 VOLUME FRACTICN =
 OUTLET SO 2" CONCENTRATION "=
       150.
     0.0460
      0.1300
PPM"
                                200".  PPM'
TEMPJERATURE = 200 .0_ DEG._ F _
     	~'~S02~C'ONCE>yfRATION"
    STAGE         PPM
       I -:          2000.
                                     ACID  LOADING
                                  LBS ACID/LB  CARBON
                                           0.1837 ,
2
3
4
5
6
7
8
9
id
.:•:,.:••• '•• n
14
15
16
; 17 .
i " 0.86
1905.
1807.
1706.
1604., -.:;
1285.
1176.
1067.
958:. v;
850^-vP*
744.- :••::;>.
640.
539.
442.
351.
267.
200.0001
0.1740
0.1640
0.1537
'•h^mMt'f&i.Q'1'*!*- 	
0.1105
0.0993
0.0881
•^^m^:^--.:. '- 0.0770 , . . ••.:•;.• , . •', -: •:,..;.-, . ... -:;,
!;::$l;1^IS?':-;i;.;^ 0.0659 '', '
-------
      S02 SORBER DESIGN

 RUN  NUMBER    TEST-5   DATE   7  27  71

 TOTAL CARBON RATE = 50.640 JJ3S/HR
 0 U T L E T C AR BCN L0 AOTNG " = "0 .18 37 5~"L 8S~~ACTOTtFTARWfT
 HEIGHT OF CARBON/STAGE =   4.00 INCHES
 DIAMETER OF VESS_EL_ =  18_._0  INCHBS	"
"CARBONi""USED"=	     "0.    ~"   "           w
 TOTAL GAS FLOW RATE =     18969. SCFH
 INLET S02 CONCENTRATION =	  2000. PPM
 INLET NCTCUNCENTRAT ION"=" "    "T5
 INLET-02 VOLUME FRACTION =   0.0460
 INLET H20 VOLUME FRACTION ^   0.1300
"OUTLET S02r CONCENTRATTON =
TEHPERATUR
|:
I • STAGE
!v i
, 3
:"..: •-.-:.. '•'• :--'--' J;r':-;':
8
. ' * 0.56
i
,-_*_ 	 	 .,—.—.-,.•
E = 200.0 DEG. F
S02 CONCENTRATION ; ;
.PPM- •• '•4w:i*-:;v:
\2000..:::"Hiif:;i
1772.
1531.
1279.
;,:.: -:::X:'.:.:. 1023.
;.;->•;.;:• i;,V.. -.;,.768. '
..-'"-.'::'..:::,•':'. 525.
306.
200.0001

:. AC TO" LOAD ING " " ; -- 	 	
LBS ACID/LB CARBON . :
••:-..v:::xi. :V, :: 0. 1837 ;/' ..1: -f: '
0. 1604
0.1357
.0.1099
0.0836
0.0575
0.0326
0.0102
' 0.0
 TOTAL CARBON REQUIRED ^J^J^V. 22: INCHES^    _    	
"tCTAL STAGES REC07"RiEO ASSUMING "4.00  INCHES~CARBON/SrAGE

 SPACE VELOCITY =     3764.  1/HR
 PRESSURE  DROP ACROSS CARBON  -     17.11  INCHES H20
 P R E S S UR_1 J3R C l>_ ACR_OS S PLATES  =	8.56  INCHES H20	
'TOTAL  PRESSURE"DROP" ACROSS STAGES  =     25~.67~ INCHES H2o
                          157
-------
      S02 SCRBER DESIGN

 RUN NUMBER    TEST-6    DATE   7 27 71

 TCTAL CARBON RATE _= 50._6A_0 _L_BS/_H_R	
"OUTLET""CARBONLOADING V~0.~1.83T5 LBS ACID/LB CARBON"
 Ml: I GMT OF CARBON/STAGE  =    6.00 INCHES
 OIAPFTER OF VESSEL. =  18.0  INCHES ^^y^-/---^;^;:-^^. _
"CARBON" USED" = """   b.
 TOTAL GAS FLOW RATE =     18969. SCFH
 INLET S02 CONCENTRATION_=	2000. PPM
 INLET" NO" CONCENTRATION"~=   ~   f5bT PPM        '
 INLET 02 VOLUME FRACTION  ~  0.0460
 INLFT H20 VOLUME  FRACTION  -  •:, 0. I3QQ
~ OUTLET'~S02~CONCWTRA"fiW =      200."
$02" CONCENTRATION: M^rf. v ACID LOADING
STAGE PPM •:-:-x: M^iWilP;: LBS ACID/LB CARBON
'1 2000.:.pl||lli 0.1837
2 1663.
3 1299.
4 922.
*.-.. .••:•-.•• . •' 5 -• :.v;..;'-.-:;.: :..:' ••••;"' .-^•SSa.v^^-:;:::-::?.:::™*;1::'-^:::;-::-:::;-^:-.:-.?;-.^-,.
;-: .•: .• - . . •:-- ..-..J .-..-..•. :•-. ..•..--•. -•--; .:.....•.:-.... :•..-:• •* -»v •• ••.:-.-:-:•>.•:-:•::-:-:•:-:•:•:-::••:•:-:-:>:-.•:-•-:•/:•:•:•: :-::-r-Xv.- ,->.-,/:
;•• • .; . ' >v.v ;;. • - ; ;'•... <: ;.y -•:':' '.-x:' '• : • . : • : : ••-. • •• '• '-• • -:.:-. •• •-•• ' : •.; : -•:.x;.v<.:-:;:;:;:;1;1v:;:;:-'-> x-::>'-.-:- -:-1-'-:yX;>:-:-: .;:;••:< :• • •:••-
I^MCo'vi^l^r:';---^v2'ob;ooo'r:^II^M^K^.
0
0
0
i 0
:;.:0
;i-::0
. 1492
.1119
.0734
.0360 •:•.-. .. ;,:,:.,:-.-::•,, :.-,v..;::;;:,:-
.0035 •;;?;:• '^^•••^••^.'^•: v? :;'
. o .•::.;:-;" \i',:'r:'.x r^:K':':s-x::;':' ••''•....''.'??'."•
                              36.88 INCHES
TOTAL CARBON  REQUIRED =
TOTAL STAGES  REQUIRED ASSUM ING-. 6.00: INCHES  CARBON/STAGE =.,6.15
 SPACE VELOCITY =
                      3492. l/HR
                                          INCHES  H20
PRESSURE DROP _ACROSS_CARBON_f__	18.		
PRESSURE" "DRCP  ACROSS' PLATES =-\.:.j;-.. 9".22-."INCHES'"Hzo
TOTAL PRESSURE  DROP ACROSS STAGES =     27.66 INCHES H20
                            158
-------
      S02 SORBER DESIGN

 RUN NUMBER    TEST-7    DATE  7 27 71

 TOTAL CARBON RATE  =  50.64_p__LBS/HR
 OUTLET' CA'RBON"'LOADrNG~="0.183T5 ITS'" AC TBTLB~C/AR'BON""
 HEIGHT OF CARBON/STAGE =   9.00 INCHES  .vT  ,:  ;
 DIAMETER OF VESSEL = _ 18 . ?_I_N£HES      , ^:  : *:\:     V: :
"CARBON usEi>" =	---g^ ——   -.-    	  -~^   -
 TOTAL GAS FLOW RATE  =     18969. SCFH
 INLET S02 CCNCENTRAT10_N _=   	2000. PPM
 INLET NO COMCENTRAnON"= """"" ;  150. PPM"""'™     ~""~"
 INLET 02 VOLUME FRACTION =  0.0460     •   ;      ^
 INLET H20_y_CLUME  FRACTION  =. :-,0. 1_300A. x/!j"^£:;.?':"':-;-;:'
 OUTLET S02 CONCENTRAflbN =     ""200. PP~M~    ""

J§?lp-EMiyM_= 200.0_0_EG. F	
      	S02"CWc"ENfRAT10N        AC 10 Td'AD I"N"G
     STAGE     .     PPM             LBS ACIU/LB CARBON
        1           ..2000.                  °_«i83J_
                                            "0."1329
                                            0.0774
                                            r\
                      I -^ \S V                  • " "
    _____
2
3
4
1504. (
962. I
438. !
 TOTAL CARBON REQUIRED  =      40.76 INCHES
 TOTAL STAGES REQUIRED  ASSUMING 9.00 INCHES CARBON/STAGE = 4.J3

 SPACE VELOCITY =     3161.  1/HR
                                   20 . 3 8'
 PRESSURE DROP ACROSS  PLATES =    10.19  INCHES  H20
 TOTAL PRESSURE DROP ACROSS STAGES =     30.57  INCHES  H20
                           159
-------
      SQ2 SORBER DESIGN

 RUN NUMBER    TEST-8    DATE  7 27 71

 TOTAL CARBON RATE  = 50.640 LBS/HR             _   _
"6"UtLC"f™CARBON~LpA'0"lNG =' 0.113375 Lt5S AC 10/I5~CARSON
 HEIGHT OF CARBON/STAGE  =   12.00 INCHES
 0I A Y E T E R 0 F _ V E S S E L _f_JL8_.0_ INC HES 1               	
"CARI!UN"USEb "= 	~" 0.
 TOTAL GAS FLOW RATE =     18969..SCFH
 INLET SC2 CONCENTRATION =	_2009'_ p_p?l_      	  _
 INLHT NO CONCENTRATION"^	^  "" 1"50T PPM"  "   ""   ~~~
 1NLLT 02 VOLUME FRACTION  =  0.0't60
 INLCT H20 VOLUME F.RACTIGN_=	°JLJ^L?°_^	,	
"OUTLET S02~CG"NCENTRAnW~=~~     200. PPM

 TEMPERATURE = _200_.0 DEG_.  F		'	^_	
      """"    S02 CONCENfRAT'lO.N   ~^~   AX ID LOAD ING
     STAGE       V;   PPM             L6S ACID/LB CARBON
.:.. .  '  :  1' < :':'':'•:: :?:D;:;  ZOOO.                    0.1837  .  :
        2            1351.                    0.1173
        3             650.                    0.0454
     0.72        200.0001                    0.0
 TOTAL CARBON REQUIRED  =      44.67 INCHES
 TOTAL STAGES REQUIRED  ASSUMING12.00 INCHES  CARBON/STAGE = 3.72
 SPACE VELOCITY =      2884.  1/HR

 PRL"SSURE_DROP_ ACROSS  CARBON =    22.33  INCHES H20
'PRESSURE D'RO'P ~ACROSS"PLA"TES =    11.17  INCHES H20
 TOTAL PRESSURE DROP  ACROSS  STAGES =     33.50  INCHES H20
                               160
-------
      S02 SORBER DESIGN

 RUN NUMBER    TEST-9    CATE  7 27 71

 TOTAL CARBON RATE  =  50.640 LBS/HR
 OUTLET CARBON LOADING  =  0.18375 LBS ACID/LB  CARBON
 HEIGHT OF CARBON/STAGE =  18.00 INCHES
 DIA M E T IE R _OJ:_V E_SS_E_L_=_ 18.0 INC HE S   _____	
"CARBON 'USED ="     "  0.
 TOTAL GAS FLOW RATE =     18969. SCFH
 INLET S02 CONCENTRATION =	2000. ?P!t__	„_
 INLET "NCI"~CO'NCENtR"ATlON""=      I'JOi PPM:
 INLET 02 VOLUME  FRACTION =  0.0460
 INLET H20 yCLUME_ FRACTION =  0.1300	
"OUTLEt""S02" CCNCENTRATToN =      200". PPM

 TEMPERATURE = 200.0 DEG. F	    _
       	"~S02"CONCENT"RATl'ON '.: '-\ ";'•'''•  "AC I'D  LdAOiNG "~"
     STAGE          PPM        ':;::: LBS ACJD/LB CARBON
'  _    I.;"   .::;;. _, 2000.  :::/.:i:.V'i::i:x:>:.;v ...•:.   .0,^837..-..:
    "  "2            Y666.           "    .   0.0880
     0.93         200.0001                   0.0
 TOTAL CARBON REQUIRED:=  :.  .52.70 INCHES
TOTAL STAGES" REQUIRED  ASSUMING'IS.OO  INCHES  CARBON/STAGE = 2.93"
 SPACE VELOCITY =     2444. 1/HR
 PRESSURE DROP ACROSS  CARBON =    26.35  INCHES  H20
 PRESSURE DROP ACROSS  PLATES ='/•-'^ 13.17; INCHES  H2D	
TdfAL PRESSURE"DROP ACROSS STAGES =     39.52  INCHES H20
                              161
-------
      S02  SGRBER DESIGN

 RUN  NUMBER   TEST-10   DATE  7 27 71

JOTAL CARBON RATE  = 50.640 LBS/HR	   __
 UUTLbt CARSONT'OADING = 0". 13375 UBS ACID/LB CARBON
 HEIGHT OF CARBON/STAGE =  24.00 .INCHES
 DIAMETER  OF VESSEL = 18.0 INCHES
 CARBON  USED =      0.
 TOTAL  GAS  FLOW RATE =     18969.  SCFH
JNLET  SC2_CCNCENTRATIGN_=  	20_0_0_. _PPM
 INLET  NO" CONCENTRATION"^""	   rod. PPM
 INLET  02  VOLUME FRACTION =   0.0460
 INLET  H20  VCLUME FRACTION =  0.1300
 OUTLET  S02 CONCENTRATION *      200. PPM
S02
STAGE
. ' I
2
0.48
CONCENTRATION
PPM
2000.
808.
200.0001
ACID LOADING
L8S ACID/LB CARBON
0.1837 .../
0.0616
0.0
    A   C ARBON REQUI RED =     59.61 INCHES
                                                             __
       STAGES  REQUIRED ASSUMING. oo INCHES CARBON/STAGE = 2.48

 SPACE  VELOCITY = _ 2161.  i/HR
 PRESSURE  DROP  ACROSS CARBON -    29.81 INCHES H20
 PRESSURE  DROP  ACROSS PLATES = 	14.90 INCHES H2Q	
"TOTAL' PRESSURE DRQP'ACROS'S STA'GES~=    44.71 INCHES H20
                           162
-------
      S02 SORBER DESIGN
RUN NUMBER
              TEST-11    DATE  7 27 71
 TOTAL CARBON  UTE  =  50 . 6VOL B S/HR
                            _
"OUTLHT "CARBON LOADING  =  0.18375 Ll~S~~/rClWrB"Tfi"R'BflN~
 HEIGHT OF CARBON/STAGE =  32.00 INCHES :;•:/:•• v:.:::::::<.
 CARBON USED =       0.
 TOTAL GAS FLOW RATE  =     18969. SCFH
 INLET Sp2_CCNCE.NTRATION_= _^	2000. PPM
"INLET "NO"CCNC;ENTRAriON"--	    i~5b'."r~ppM"~~
 INLET 02 VOLUME FRACTION  =   0.04&0   ,,•'•'.••'
 INLET H20 yCLUME  FRACTICN =   0.1300_
 OUTLE T "502" CO'NCEN TR AT ION  =       200 .TP'M

 TEMPERATURE = POO.O  DEC.  F
            .$02.CONCENTRATION
     'STAGE         PPM
        (l            2000.
                                     ACID  LOADING  x..
                                  LBS  ACID/LB  CARBON
                                      • .•:*'.;;., ••-:. 0. 1837 •<"^
        2
     0.19
                     510.
                 200.0001
                               0.0311
                               0.0
 TOFALl
TOTAL
      CARBON
      STAGES
_REQU_I_R_ED'
 REQUIRED"
       70.10 INCHES
 SPACE VELOCITY =
 ASSUM1NG32.00INCHES  CARBON/STAGE = 2.19

1838. 1/HR
 PRESSURE DROP ACROSS  CARBON =
 PRESSURE DROP ACROSS  PLATES =
 TOTAL PRESSURE DROP  ACROSS STAGES -
                                  •35.05  INCHES H20
                                   17.52 INCHES H20	
                                        '52.57  INCHES H2"0"
                            163
-------
      502  SORBER DESIGN

 RUN  NUMBER   TEST-27   DATE  7 30 71

 TOTALL CARBON RATE = 25.320 LBS/HR          	   	
 OUTLET "CAR&'CNTbAD'iN'Gi = 6.18375 LUS ACID/LB CARETON
 HEIGHT OF CARBON/STAGE =   4.00 INCHES
                    = 18.0. INCHES
 CARBON USED =      0.
 TOTAL  GAS FLOW RATE =     9484. SCFH
 INLET_SC2_CONCENTRATION_f	2_P0.°_^ PPH.
""lNUET~N"C~CONCENTPrAfiON"- ..'-;.^-: "150". .PPM::-,"
 INLET  02 VOLUME FRACTION = ^(3.0460 :r-: W;:
 ^LE^J^O^ VOLUME FRACT I CN - ••:, :.Q. 1 300J-:.: f • ; !
"OUTLET su2" CCNCENTRA'TIUN =      200. PPM

 TEMPERATURE = 200.0 DEC. F
            S02 CONCENTRATION        ACID LOADING  ••
     STAGE         PPM            LBS ACID/LB CARBON.
        1    '        2000.                  0
2
3
4
1556.
1072.
S89.
0.1383
0.0887
0,0392
                 2 oo. ooo i^:;mmm$*m^ ^•^ ±o. o.
TOTAL  CARBON REQUIRED =     19.78 INCHES
TOTAL  STAGES REQUIRED ASSUMING 4.00 INCHES CARBON/STAGE  =  4.94

SPACE  VELOCITY.>     3257. 1/HR
 PRESSURE  DRCP ACROSS CARBCN =     9.89.INCHES H20
 PRESSURE  DROP ACROSS PLATES =     4.94 INCHES H20
 TOTAL  PRESSURE DROP ACROSS STAGES =    14.83  INCHES  H20
                            164
-------
     S02 SORBER  DESIGN

RUN NUMBER    TEST-28    DATE  7 30 71

TOTAL CARBON  RATE  = 25.320 LBS/HR
OUTLET CARBON  LOADING =  0.18375 LBS ACIO/L8 CARBON
HEIGHT OF CARBON/STAGE =   9.00 INCHES;
DIAMETER CF VESSEL:-  18.0 INCHES
CARBON USED =       0.
TCTAL GAS FLOW  RATE =      9484. SCFH
 NLET S2CCNCENTRATION        OO  PPM
         __ ___ _. _
"INLET NO "CONCENTRATION  =   ../;•• ispr PPM
INLET 02 VOLUME  FRACTION =  0.0460
INLET H20 VOLUME  FRACTION = ; 51 0.1 300
OUTLET S02 CONCENTRATION =       200. PPM

TEMPERATURE  =  200.0  DEG. F
           S02 CONCENTRATION        ACID LOADING
    STAGE   :       PPM            LBS ACID/LB CARBON
   ;:•:'" •;:l::::.r••-,•:• Ti:••v'w '2000.                  ..0.1837 •....
       2            1066.                   0.0880
    0.93         200.0001                   0.0
TOTAL taRBONREtR'EPOX:?
TOTAL STAGES REQUIRED  ASSUMING "9.00 "INCHES CARBON/STAGE  =  2".93

SPACE VELOCITY  - _ 2444.  I/HR             __ ........... __ _

PRESSURE DROP ACROSS  CARBON =    13.17 INCHES H20 ^^^§^51^
        -.-OROP- ACROSS .PES:-:^-:g^'::-:---6\' 5 9:. INCHES
TOTAL "PRESSURE DROP"  ACROSS STAGES =    19.76  INCHES H2o
                           165
-------
      S02 SORBER DESIGN
 RUN NUMBER
TEST-29   DATE   7  30  71
 TOTAL CARBON RATE = 25.320_LB$/HR  	 	
 CUTLET "CARBON" LOADING"'=~~"6 Vi aaYs TBS ACID/LB CARBON"
 HEIGHT OF CARBON/STAGE  =   18.00  INCHES,;;,;;
 DIAMETER OF VESSEL = 1.8.0  INCHES J'J*v£&*:/ii:
"CARBON'US'ED ------- o."~ "
 TOTAL GAS FLOW RATE =      9484.  SCFH
 INLET S02_ CCNCENTRATICN_=	2.00_0_._PPM
 INLET" NO" CONCENTRATION  =   "'  "150." PPM""
 INLET 02 VOLUME FRACTION =   0.0460
 INLET H20 V 0 L U K' E F R A C T I CN_  =  . 0. 13 00	
 OUTLET so2" CONCE"NTRAT"ION =       200. "PP"M~
I' "STAGE
\ .•••-. . 1.
0.10
:;';-:-..:/'.----. : PPM
•""'. ;':;'^.-;.'' .2000,
200.0001
ACID LOADING ,
IBS ACID/LB CARBON :-
0. 1837 x -:.>/
0.0181
0.0
 TOTA'L CARBON REQUIRED' -C y  37.83:-JNCHES  		
 TO"TAL STAGES REQUiRETASsuMiNl3l8.""oo INCHES CARBON/'STA'GE  =  2.10"
 SPACE  VELOCITY =
        1701.  1/HR
 PRESSURE DROP ACROSS CARBON  =
 PMSSURE_DROP__ACROSS_ PLATES  =   __
"ftiTAl"PRESSURE DROP"  ACROSS STAGES
                     18.93 INCHES H20
                      9.46 INCHES H20
                           28.39 INCHES H20"
                           166
-------
      S02 SORBER DESIGN

 RUN NUMBER   TEST-30   DATE  7 30 71

_TOTAL CARBON JATE = 25.320 LBS/HR	
 outLET~CAR'BON LOA'DiNG"'=" o"."i8375 "Cos ACi D/LB  cA'RBON"
 HEIGHT OF CARBON/STAGE =  32.00  INCHES
 DIAMETER Of VESSEL _f l8_.
-------
      S02 SORBER DESIGN

 RUN NUMBER   TEST-31   DATE  7 30  71

 TOTAL CARBON RATE = 37^9_80 LBS_/HR_
"OUt LET""CARBON ' LOADTNG" =. 0/10375  LBT'ATl ~07CB~~C'AR~BO"N
 HEIGHT OF CARBON/STAGE =   4.00  INCHES
 DIAMETER OF VESSELV;= 1^9_JLNCJjES	
 CARBON USED =	0."
 TCTAL GAS FLOW  RATE =    14227.  SCFH
 INLET S02 CONCENTRATION^	_?00.P_- PPM_
 INL E T "NtTCONC E N TR AT I ON =    ""  150T~ PP'M".,'
 INLET 02 VOLUME FRACTION =  0.0460       '
 INLET H20 VOLUME FRACTION ~  Q.I 300    •<
'OUTLET "S'02"CONCEN'tRATiON =       200.  P'PM
TEMPERATURE = 200.0 DEC. F
?.-"" .. " S02 CONCENTRATION
I STAGE : PPM
i V ••• 1 "'•' >:":. : 2000.
2 1699.
3 1376.
4 1040.
C " >;. ,; .' :: ' 0 . 7 5 I ? . i- . , v "' ; 2 0 0 . 0 0 0 .1;':; . :«; W^

: ACID LOADING
' LBS ACID/LB CARBON
... 0.1837
0.1529
0.1198
0.0854
.i. ••?:•• :.::••:??.•;• -x >;;•,-,..:-. -0.0512 . -..-;-::_ .••..:•:-.:•:
•£"#&&&:. :.:\ '.0 .0196 ::.^^i::\f ^.iv- -;;:-:
^kltSS^x?,0 * Q :?1 11^. v.:^: -¥'X\' '
 TOTAL'CARBON REQUIRED =     26.99  INCHES
 TOTAL STAGES REQUIRED ASSUMING 4.00  INCHES CARBON/STAGE - 6.75
 SPACE  VELOCITY =     3579. 1/HR

 PRESSURE  DROP ACROSS CARBON =     13.50  JNCHE_S H20	
 PRESSURE"'DRoFACRoss.PLATES =      6.75~rNCHES~"H20-
 TOTAL  PRESSURE DROP ACROSS STAGES  =     20.24 INCHES H2U
                           168
-------
       S02 SORBER  DESIGN

  RUN NUMBER    TEST-32   DATE  7 30 71

  TCTAL CARBON _RATE__^_37_. 980 LBS/HR
  OUTLET "CARBON "LOADING =  0. l8375"~LBS~
  HEIGHT OF CARBON/STAGE =   .9.00 INCHES:
  DIAMETER OF V ESSEL_= 18.0 INCHES
 "CARBON USED"=~~"  "   bT"
  TOTAL GAS FLOW  RATE =    14227. SCFH
  INLET S02 CONCENTRATION^  	  2A00- f?M
 "INLET W"CONCENTRATrdN>. " ...••.150.""PPM™
  INLET 02 VOLUME  FRACTION =  0.0^60
  INLET H20 VOLUME FRACTION - .0.1300
      "	SO 2" CONCENTRATro.N" =      20"6~.
 OUTLET
  TEMPERATURE =  200.0 DEC. F
  " "	" ~~ S02l'C 0 NC E N TR A T" I ON"
       STAGE     s;    PPM
  ;•'•-  •<:••:  i4l?i.tFi;f>:    2000.
         2
         3
      0.72
                                  " ~~"A"CTO~ro A D FN1S"	
                                   LBS  ACID/LB CARBON
                     650.
                 200t0001
OV1173
0.0454
0.0
  TCTAL CARBON  REQUIRED =     33.50 INCHES
  TOTAL STAGES  REQUIRED ASSUMING 9.00  INCHES  CARBON/STAGE = 3.72
C SPACE VELOCITY  =
                      2884.  1/HK
 PRESSURJLP_ROP ACROSS CARDQN  -
"PRESSURE DROP""ACROSS PLATES  =
 TOTAL  PRESSURE DROP ACROSS  STAGES  =
                                     6^75__I NCHES__H20	
                                     8.38  INCHES  H20
                                           25.13  INCHES H20
                               169
-------
      S02 SORBER DESIGN

 RUN NUMBER   TEST-33    DATE   7 30 71

 TOTAL CARBON RATE = 37.98p__L_BS_/HR __
 OUTLET" CARBON LO~A~DTNG'"=~0. 183~75 "LliS TCTD/LB  C'A~R"B~0~N
 HEIGHT OF CARBON/STAGE  =   18.00 INCHES
 C 1 AMCTER_ 0F_VESSEL «  18_. 0  1NCHES_^______	
'•CARBON USED "=      0."" ~
 TOTAL GAS FLOW RATE =     14227. .SCFH
 INLI:T SC2 CONCENTRAT I ON_=	2000. PPM	
"INLET NO ""CCNCENTR'ATION"*~     fso'T'ppM
 INLET 02 VOLUME FRACTION  =   0.0460
 INLET H20_ VOLUME FRACTION  =   0. 1300
'OUTLET "S02 CCNCENTRATION  =       200. PPM
ERATURE = <
S02
STAGE
1
2
0.48
?00.0 DEC. F
CONCENTRATION
PPM
2000.
808.
200.0001

ACID
LBS ACI


LOADING
D/LB CARBON
0.1837
0.0616
0.0
 TOTAL CARBON REQUIRED  = :: :   44.71 INCHES; ____ __ __ ___
       STT AGES' REQUrRED TSSUMINGIS.OO INCHES  CARBON/STAGK =
 SPACE VELOCITY =      2161.  l/HR
 PRESSURE DROP ACROSS  CARBON =:    22.36  INCHES  H20
 PR_ESSyRE_DRCP ACR_OSS_ PL AT_ES__=__ _^_1_1_._18 _INCHES  H20	
 "TOTAL" P"RESSUR"E"D"ROP'ACROSS STAG'ES =  "" 33753 TNCHE'S H2"o
                               170
-------
      S02 SORBER DESIGN

 RUN NUMBER   TEST-34    DATE   7 30 71

 TOTAL CARBON RATE = 37.980 j-BS/HR
"OUTLET"" CARBON TOADlNG = O.Tel 75 "LlS ACID/LB"~CAR"BON —
 HEIGHT CP CARBON/STAGE  = , 32 , 00 INCHES \           .:.
 DIAMETER OF VESSEL =  Ij.O INCHES ^/^.X&^Z"::-.'. :.'•: ': ."' ''..
             '    '~'~
 TOTAL GAS FLOW RATE =     14227.  SCFH
 INLET_S02 CONCENTRATION  =_ __  200p._P_P_M
 INLET NO "CCNCFNTR'AtiO'N "-"  "  "Tl50T PPM"
 INLET 02 VOLUME FRACTION =  0.0^60  .  ::
 INLET H20 VOLUME FkACTiqN_^ __ 0_. JL 3D 0_ £^_
 OUTLET $02 "CONCENTRAI 'ION" =      "200. "PPM
STAGE
1
2
0.00
S02 CONCENTRATION .':
PPM
2000.
204.
200.0001
ACID LOADING
LBS ACID/LB CARBON
0.1837
0.0
. 0.0
 TOTAL STAGES REQUIRED  ASSUMING32.00 INCHES CARBON/STAGt  =  2.00"

 SPACE VELOCITY =     1508.  1/HR
 PRESSURE DROP ACROSS CARBON  = ;• r:: :i'32.03'::INCHES H20
 PRESSURE DROP_ACRpSS_ PLATJES  =  Y  16 •« 02^ I NOME S H20	
TcfTAl PRESSURE"~DROP ACRCSS "SFAGES" =    48.o"5 INCHES H20
                             171
-------
                  APPENDIX A-9-2

EFFECT OF THE LINEAR GAS VELOCITY ON THE TOTAL CARBON
  BED DEPTH REQUIRED TO REMOVE 90% OF AN INLET S02
              CONCENTRATION OF 2000 PPM
       Carbon Bed Depth/Stage,
       	inches	     Run Number

                  4                  Test-27
                  4                  Test-31
                  4                  Test-5

                  9                  Test-28
                  9                  Test-32
                  9                  Test-7

                 18                  Test-29
                 18                  Test-33
                 18                  Test-9

                 32                  Test-30
                 32                  Test-34
                 32                  Test-11
                     172
-------
     S02 SOR&ER  DESIGN         •

RUN NUMBER     TEST-5   DATE   7 27  71
 TOTAL JDARBON RATE  =  5C	    	      	
""OUTLET CARB'CN TOADfNG = 6.1B37~5 LBS  A CID / L B CTfTBOlTTr
 HEIGHT OF CARBON/STAGE  =
JD IA M E TER _OF VESSEL = 18''.(
 CARBON USED =      0.
 TOTAL GAS FLOW RATE  =    18969. SCFH
J_NL.^T._1°1__C°.NCFIIRAJJ ON =      2000._ PPM  ___________
 I"NLET NO CCM^ENTR'At IO"N" = ..:,:: .,-, 150."  V9]^^:::<^:-.:^amK
.. INLET 02 VOLUME  FRACT ION := vifl '   '":'"':>™*--^>">• »--—-•—-
 INLET H20 VOLUME FRACTION  :=;::-.
"OUTLET~S02"CONCE"NTRA"Tro.N =

 TEMPERATURE = 200.0  DEC. F
                                  20 0. TPfi
|" S02
I STAGE
I , I 	
2
3
4 •
CONCENTRAT
PPM :/•;•;;;:••£
1772.
1531.
1279.
ION • -::v-x.:;v:::-::-.#- V AC 1 D . LOAD I NG >.i- v:^-:::.:*^-::;.- '•'*".
:;:|:::J|||g::;;.LBS AC 1 0/LB C ARBON: V/^^lf |i|«>'<:S>
0.1604
0.1357
0.1099
      56
                      306.
                 '200.0001
0.0102
0.0
TOTAL CARBON  REQUIRED >=?; ::.:; :: 34;22 JINCHES;
TCTAL STAGES  REQUIRED ASSUMING  4.00  INCHES CARbON/STAGE  =8.56
SPACE VELOCITY  =
                       3764. 1/HR
PRESSURE DROP  ACROSS CARBON; =
PRESSURE DROP  ACROSS PLATES =
TOTAL PRESSURE  DROP ACROSS STAGES  =
                                   17.11  INCHES H20 :5:»-»::«:i*-;¥V:V
                                    8.56;!::;INCHES H20^.:W:^	
                                          25.67 INCHES H20
                            173
-------
      S02 SORBER DESIGN

 RUN NUMBER    TEST-7   DATE  7 27 71

 TOTAL CARBO_N JUTE = 50.640 LBS/HR	
IJUTTETCARBON LOADING = 0.1837.5 LBS /
 HEIGHT OF CARBON/STAGE =   ;,9.00 INCHES
      ;TER OF VESSEL = is.o
_.
 CARBON USED =~     0.
 TOTAL GAS FLOW RATE =    18969. SCFH
  NLETS02 CNCENTRATION =     2000. PPM
 INLET" NO" CONCENTRATION -.  -:.;. ,,, 150.,PPM .
 INLET 02 VOLUME FRACT ION.,=:?; '0.0460;•wMiHl
. 1NLET_JJ20^VCLUME FRACTICiN ~ >.Q.
"OUTLET s"o2 CONCENTRATION =      200. PPM

 TEMPERATURE = 200.0 DEC. F
2
3
4
1504.
962.
438.-
0.1329 1
0.0774 /
0.0237
                 200,OOCl               -   0.0
 TOTAL CARBON REQUIRED =     40.76 INCHES
 TOTAL STAGES REQUIRED ASSUMING 9.00 INCHES CARBON/STAGE = 4.53
 PRESSURE DROP ACROSS CARBON =    20.38  INCHES  H20
 PRESSURE DROP ACROSS PLATES -    10.19  INCHES  H20
 TOTAL PRESSURE DROP ACRCSS STAGES =     30.57  INCHES  H20
                           174
-------
       S02 SORBER  DESIGN

  RUN NUMBER     TEST-9   DATE  7.27  71
                                               .'- -. •  ' • •" -V
  TOTAL £ARBON  RATE  - 50.640 LBS/HR	  '_  	
 WTLET CARBaTTLOAblNG = 0.18375 ~LBS ACID/LB... CA~RBON
  HEIGHT OF CARBON/STAGE:=  18.00
  DIAMETER OF VESSEL =18.0 INCHES
  CARBON USED  =       0.
  TOTAL GAS  FLOW  RATE =    18969. SCFH
 JNJ-.ET__Sp2. P.CNCENTRATl ON =     2000. _____
  INLET NO  CONCENTRATION = .;;.:•;;,,. ISO. PPM   .
  INLET 02  VOLUME FRACTION - ;0.0460
  INLET H2p_VC_LUMC FRACTION = " 0.1300	
 'OUfLEf~S"02 CCNCENTRAT I ON =      200.  PPM
  TEMPEP.ATURE_= _200_^0 DEC. _F	
              S0~2  C 0 NC E NTR AT I ON aiiiif ^ >• AC 10 LCTAOING"
      STAGE          PPM        l|p:?:i,;BS;.ACID/LB .CARBON
          1            2000.     ^i^i^ili^iiiK?"'-b_»_l_837.'^''^
        f~~2  "~^*^~"    1066.                •   0.0880
      0.93         200.0001                 ^0»0
  'TOTAL STAGES  REQUIRED ASSUMINGIS.OO  INCHES  CARBON/STAGF. =  2.93
  x                                          ''  *
  SPACE VELOCITY  =     2444. 1/HR    .             	
w.   ,,
^PRESSURE  DROP  ACROSS CARBON =     26.35  INCHES H20
^PRESSURE  DROP  ACROSS PLATES =:::::?i 13.17  INCHES H20	
  TOTAL PRESSURE DROP ACROSS STAGES =     39.52 INCH'ES H20
                             175
-------
      S02  SORBER DESIGN


 RUN NUMBER   TEST-ll   DATE  7 27 71


 TOTAL CARBON RATE = 50.640 LBS/HR
"CARBO'N USED =      o.
 TOTAL GAS FLOW RATE =    18969. SCFH
_!NLET_SG2_CCNCENTRATION =     2000. PPM
~I"NLET~NO"CCNCEN"TR"ATION - ;.
 INLET 02 VOLUME FRACTION =
 INLET H20 VCLUME FRACTION^ V
"OUYLTT S02 CONCENTRATION =      200. PPM


 TEMPERATURE = 200.0 PEG. F

 TOTAL STAGES REQUIRE'!) ASSUMING32.00 INCHES CARBON/STAGE  =  2.19"


 SPACE VELOCITY =     1838.;l/HR
 TOTAL PRESSURE DROP ACROSS STAGES -    52.51  INCHES  H20
                            176
-------
       S02 SORBER DESIGN

  RUN NUMBER   TEST-27    DATE  7 30 71      ':'--.;?'oV'

  T(?TAL CARBON RAIL-  =25*320 LBS/HR	'	
 "OUTLET" CARBCN LOADING = 0.18375 UBS ACID7TO CARBW
  HEIGHT OF CARBON/STAGE-; •<: 4 „ 00 INC H E S, i. ^•^••. iAfe-':V!
  D IAMET V.R OF VESSEL • =  18.0 •' INCHES -i-' ^.:.}&%::&±>^&*-£
  CARBON' USED =       o.
  TOTAL GAS FLOW RATE =     9484. SCFH
  INLET _S02 CONCENTRATION _=	 _ 2000. PPM 	      __
 TNLET^NC CONCENTRATION^ :::;F 'T5"0.  PPM""
  INLET 02 VOLUME FRACTION =! 0.0460
 JNLET H20__VaLyME  FRACTION  -0.1300	
  OUT LET'S 02 C"CNCEN"fRATrD"N =      200". PPM

  TEMPERATURE = 200.0 OEG. F
           : ,:::::S02::CONCENTRATION;:?:.::J;:;:;l:::V ACID LOADING  • ,:
r:::^-:;;::^                              LBS ACID/LB CARBON:
^^M^fi''l&^;^lp^o'ob^:Pf::^P•  ,- .: .,   o.ios?.-:^
"   "     2          '  ll56^   "'^^      T^TT  571383
         3            1072.             ••-••'•'   0.0887
         4             589.               '    0
  TOTAL CARBON  REQUIRED =      19.78 I~NCHES
  TOTAL STAGES  REQUIREDASSUMING 4.00 INCHES CARBON/STAGE  = 4.94

  SPACE VELOCITY *      3257.  1/HR
  PRESSURE DRCP ACROSS  CARBON =     9.89 .INCHES H20
  PRESSURE DROP ACROSS  PLATES -     4.94 INCHES H20
  TOTAL PRESSURE  DROP  ACROSS STAGES =    14.83 INCHES  H20
                            177
-------
        S02  SORBER DESIGN              "

  RUN NUMBER    TEST-28    DATE  7.30 71

  IP™!- CARBON RATE = 25.320 LBS/HR
 1 U I M ^ ^* *S I '» L* V> I » I •* >~1 • l~    «_^w_*fc.** l».brvf---i              ^ ^         	
 TuTLET"C~ARBON LOADTNG = 0.18375  LBS AC 1D / L8  C AR BOlT.: .V ;:::,:.:,,;;:
 HEIGHT OF CARBON/STAGE =•• 9.00  JNCHE.S/:;;:^;;::^
 DIAMETER. CF VESSEL'' =.,18.0 INC^ESfe-fe^^                   **:?-vl
  CARBON US'EO =      0.
  TOTAL GAS  FLOW RATE =      9484. SCFH
  J NkEI__S°2  CC.NCEN'TRAT K1J1       2000. PPM
  "INLET NO CONCENTRATION  = ;.,;::^':;r,i5p.:..ppK~,	
  INLET 02 VOLUME' FRACTION  =^-^'^Q^bQ:;:^^^;^^i^^'-^-:^^. ||;f4
             yCLUME FR ACT I GN "-'::V-;'Q. Vsob;--^'-:^^                 f3g
             "CONCENfRATION  =      200.  PPM

  TEMPERATURE  =200.0 DEC.  F
S02
STAGE
i

2
0.93
CONCENTRATION
PPM
?000.

•'• 1066»
200.0001
ACID LOADING - •.;: .; ..-. :.<,.;&
LBS ACID/LB CARBON : : -v ;^i;::;
0.1837 :::"-s '•'•«':*:-•:••-•;

0.0880
' 0.0 _;.
..;,::•::::.;:>;.:
•\'.-:: •-:.•>-';! ::
....: .;:.::;:>:•. '•



  TOTAL STAGES  REQUIRED ASSUMING 9.00  INCHES- CARBON/STAGE =  2.93

  SPACE VELOCITY =     2444.  1/HR
'PRESSURE -DROP ACROSS
                                 ^W
                                         ::H.NCHEs-/H2o;:':--;;;;.:i:--:i-::t1|D^:l^
£':. PRESSURE  0R0P ACR0SS PL ATE'S>  -"---
                                            19.76  INCHES H20
TOTAL  PRESSURE DROP  ACROSS STAGES =
                            178
-------
      S02 SORBER DESIGN      -       -
                                  ' ''"*-.

 RUN NUMBER   TEST-29   DATE  7 30 71

              RATE = 25.320 LBS/HR
 OUTLET CARBON LOADING = 0.183~75 LBS  ACtD/LB  CARBON
 HEIGHT CF CARBON/STAGE; =  18.00 INCHES;;^;;.^:!^^^'-:
J)IAPETER_ CF VESSEL = . 18.0 . INCHESj^MflllB"'"	
 CARBON LIlTED = "     0.
 TOTAL GAS FLOW RATE =     9484. SCFH
 INLET S02 CCNCENTRATIQN =     2000.  PPM
                               150. PPM
 INLET  NO CONCENTRATION =   •:
 INLET  02 VClUME FRACTION =^
 INLET_ H20 VOLUME FRACTICN = ^,0>1300
"bUTlET S02 CONCENTRATION =
                                 200. PPM
 TEMPERATURE = 200.0 DEC. F
J STAGE
i • i
2
0.10
S02 .CONCENTRATION
PPM
e . 2000,
383.
200.0001
.ACID LOADING : . • SH: -;v./^:, .• •
iLBS AC I D/LB CAR&QU^rV-^^" ::'v
, ,, -• 0'k1837'^t^^is^V^-'.)V.
0.0181
0.0
 TOTAV'STA&ES REQUfRED ASSUM1NG18.00  INCHES CARBON/STAGE = 2". LO

 SPACE VELOCITY =	   1701. I'/hfR' =     -  -          	

 PRESSURE DROP ACROSS-CARBCN =
 PRESSURE DROP ACROSS PLATES":,-
                                  18.93
                                   9.46  INCHES.
 TOTAL PRESSURE DROP ACROSS STAGES =
                                        28.39  INCHES  H20
                            179
-------
        S02 SORBER DESIGN                 '.   .,  ... '    .

  RUN  NUMBER   TEST-30    DATE  7 30  71      ''.   -V"':-

  TOTAL CARBON RATE  = 25.320 LBS/HR	'
  ~OUtiL'ET"CARBCN LOADING = 0.18375  LBS  ACIO/LB CARBON
                           '                            "'
  HEIGHT OF CARBON/STAGE '-  32.00  i,,v,,,^- ,, ::,,::;:  ,,:.:;,::..   :,-.:
  _DI AKEY £R_0 F__VESSEL  ='"'18.0 .INCHES *::^^Mi%^^l^,-{i$?'Z
  CARBON USED =       0.
  TOTAL  GAS FLOW RATE  =      9484.  SCFH
  INLET_SC2 CCNCENTRAT10N  =2000.  PPM
  "TNLET  NO "CONCENTR'ATHTN" =  :•;:::;  -.156.: PPM..;•;;
  INLET  02 VOLUME FRACTION =-0.0460 i',:^'^
  _l N.LE.I  H20_yCL UME  FR AC T IC N_ =' '•••'<) ^ 1300 -y::;:;:-:!:
  bUT"LE"r'Sb2 CONCENTRATION =       200."~PPM.

  TEMPERATURE = 200.
        .:. ,,:.::,S02 CONCENTRATION         ACID LOADING
              •: . .,  ?iPPM             LBS ACID/LB CARBON
              ::  :  :^:.-V2000.                   0.1837
       0.67        200.0001                 .  0.0
t'-'TOTAL  CARBON 'RE"CUIRE'D.-.:;=S; #&5^
I0TOTAL  STAGES REQU IRED ASSUMING32..0,0 ...I.NCHES':: CARBON/STAGE =1.67:
  •*     '                               "  --'." * ' i  > .
  SPACE  VELOCITY =      1206. 1/HR           •-•.',
?.:•'• PRESSURE DROP ACROSS  CARBON.^^'•'•r. 26.71 INCHES  H20  ;,;,;;; :;;y;.,i:;.;
|:i PRESSURE DROP ACROSS  'PLATESf^ij1^ 13.36:;; INCHES  H20 '»''"$^i*?*;KJ
         PRESSURE DROP; ACROSS -STAGESl^^WiQl^.INCHES. H20-  g^ : x
                               180
-------
       S02 SORBER DESIGN          ,

  RUN NUMBER    TEST-31   DATE  7 30 71

  TOTAL_£ARB_ONI _RA_TE _~  37. 9130 I.BS/HR
 "OUTLET CARBON LOTOffiG =  0»l¥375 L¥
  HEIGHT OF CARBON/STAGE >••:   :4.00INCHES:
  DIAMETER OF VESjELs:- 1816.' INCHES?-;fi;:y;U^
  CARBON USED =       0.
  TCTAL GAS  FLOW  RATE =     14227. SCFH
  INLET Sp2_CONCENTRATiqNI_=_	 20°°' _pf.M
 "iNLET'NO CONCENTRATION = •...  .^1507 PPM"
  INLET 02 VOLUME  FRACTION <:x0.0460:i::H :.:"
  INLET H20  VOLUME  FRACTICN -""• 0.1300
  OUTLET "S02 CONCENT RATION"_ =      200. "PPM

  TEMPERATURE_=_200.0 DE_G_.__F	
             S02"CONCENTRATION  '  ~"AC ID  LOADING"
      .STAGE          PPM            LBS ACID/LB  CARBON
         1^	   2000..	0.1837 :M'^
     "   2            1699".    '               07T529
         3            1376.                  . 0.1198
         4            1040.                   0.0854	
     J^n^r^lll^:l»:C:',7p6',;:;;;:;; ^:isMii&M::'6.ObiYW^.
                 !?::;li?Mv.>.397'£::::::

   OTAL CARBON  REQUIRED .'<::-• .v^ 26.99:  INCH'ES .v
  TOTAL STAGES  REQUIRED ASSUMING 4.00  INCHES
  SPACE VELOCITY  =      3579. l/HR

 _P_RESSURE DROP ACROSS CARBON =    13.50  INCHES H20
" PRE:SSURE""OROP ACROSS PLATES = -^^ b.js • INCHES. H2ti: -/;,;,w^«.;
"•- TOTAL PRESSURE  DROP ACROSS: STAGESV=^.v^:!::70^24.>.INCHES;-H2g:WI:ij
                              181
-------
      $02 SORBER DESIGN

 RUN NUMBER   TEST-32    DATE  7 30 71
 TCTAL CARBON R.AJJ_=_AI^.M5 J^M/Jl?. __
"OUTCEfCARBON LOADING  -~:" 0 .1 8 3 7 5 L6S  ACTp/LB
'  OUTl ET'CARBON  LOADING ~":" 0 »18 3 7 5  L6S .ACTp/LB"CAR00"N  ...  ..,-...; s::UV •.'.:.;,;
  HEIGHT OF CARBON/STAGE = -••.9.'00 .l^ES^^;^^^^-^?.^}-^^^^
^_DIAKETER_ 0F • V ESSE L• • - -,' 18 . 0 •'I NC'HE S ;::::.;;:gg;|||g||||i|g
  rADUfiK»iicPn=       n.
 CAR13UN USED =       0.
 TCTAL GAS FLOW RATE  =     K227. SCFH
 JNLET S02 CONCENTRATION  =     2000. PPM
"rNLE"t"NO'~C6NCENTRATlON =   ,:> i'.JLSO. ;PPM .j.
 INLET 02 VOLUME FRACTION —.'v
 INLET H2p__yj]LUME  FRACTION -T	
"onuYLErsoT"l;"o'NcTNrRATroN~=      200. PPM

 TEMPERATURE = 200.0  DCG» F
            ..... S 0 2 .. C 0 NC E N TR A T I'D N.J-;- .:. •! >f C iixl % : A CTD LOADTNG
            --^^^^^^
                                                CARBON ':;-:"''':^::'^iii|li!^
                         V^Si^
        2             351.                    0.1173
        3             650.                    0.0^54
     0.72        200.0001                   ' 0.0
 TCTAL CARBON REQUIRED  =      33.50  INCHES
 TOTAL STAGES REQUIRED  ASSUMING 9.00  INCHES  CARBON/(ST«GE  =  3.72

      ~               ?e 84 .  i /HR ' !^^^^mf&n^£^^^-2-^f^^^^m
 PRESSURE DROP_ACRGSS        _
'PRESSURE DROP ACROSS' PLATES =     8.38  fNCHES H20
 TOTAL PRESSURE DROP  ACROSS STAGES =  .   25«13 INCHES H20
                           182
-------
      S02 SORBER DESIGN

 RUN NUMBER   TEST-33    DATE   7 30 71

 TOTAL CARBON__RAYE ^37.980 LBS/HR
"OUTLET "CARBON LO AIDING = 0.18375 TBS
 HEIGHT OF CARBON/STAGE.=  18.00 INCHES:
 C IAMETER OF VESSEL... - . 18.0  INCHES-;:::-::::.-.-.-.>H^M^^^I^
 .     .                             _ _
"CARBON USED =      0.
 TOTAL GAS FLOW RATE =     14227.  SCFH
 I NL E T_ S C <1_CONC E N T R A T I ON  = ___ 2 OOP. P P M
"rNL'Et NC" CONCENT RA'TTON =::,.;.  ' 150.. PPM
 INLET 02 VOLUME FRAC.T ION •=: 0.0^60
INLET H20 VOLUME  TRACTION --
OUTLET S02 ~f.C~NCENTRATl6'N =

TEMPERATURE_=^_2p_0.0  DEGJL_F	
           SU2,CONCENTRATION.
    STAGE
       r
                               0. 1300
                                  200. PPM
                                  •::x ••::•: AC I D • L0ADI NC'•."-':: -j
                                   LaS ACID/LB CARBON
                                            0.1837 :::
        2
     0.48
                     808.
                 200.0001
0.0616
0.0
"TOfAL STAGES REQAHRED  ASSUMING18.00 INCHES CARBON/STAGE = 2.4T

 SPACE.VELOCITY =     2161 c  i/HR
 PRESSURE
 PRESSURE _. ^	^_	,      	_.
 TOTAL PRESSUfiiE DROP  ACROSS STAGES -    33.53  INCHES  H20
                              183
-------
      S02 SORDER DESIGN

 RUN NUMBER   TESY-34   GATE   7  30 71

 TOTAL CARBON JA_TE = 37.980 LDS/HR	
~CUTL£f"CAR80N LOADING = 0.18375 LUS AC1D/LB CARBOTT
 HEIGHT Or CARBON/STAGE =  32.00 INCHES..>•;....^::«:-::4':;,:u:ij|>
 DIAMETER CF VESSEL =  18.0 INCHES :.. ry^iXBijiffiV:U^li^.
'CARBON USED =      o.
 TOTAL GAS FLOW RATE =     14227.  SCFH
 INLET SO? CONCENTRATION =	2000.  PPM
TNLET" NO" CONCENTRATION' =   ;: .. :150".  PPM,.:.:.;::
 INLET 02 VOLUME FRACTION  = r 0,0 4 6 0 :^'^&f;
 INLET H20 VOLUME FRACTION =; V0.1300
OUTLET S02 CONCENTRATION^ 200. PPM
TEMPERATURE •- 200.0 DEC. F
STAGE
2
o.co
S02 CONCENTRAT ION ;;::i:;: : y:
pp^'-^KM^M^s
204.
200 ..rtnni

/::.ACID LOADING ,,; ;.' ':.,. •:;£;$&&• v: -A:
ISVAC'ID/LB CARBON ."V: •••¥^-j^S\^,
ilSIIO '0.1837: -v, '••• ; ':^*9#£%$$.?%
0.0
. 0.0
 TOTAL CARBON RECUIRED;•'-.%•••;•• ,:.:V64.07 :INCHES'•".•^^••^
 TOTAL STAGES REQUIRED ASSUMING32.00 INCHES CARBON/STAGt = 2.00

 SPACE VELOCITY =     X508.  1/HR
 PRESSURE DROP ACROSS CARBON  =     32.03 INCHES H?.Q
 PRESSURE DROP ACROSS PLATES  -:  :" i ISiO^VkNCHES H2(f
 TOTAL PRESSURE DROP ACROSS  STAGES -    ^8«OS  INCHES  H20
                            184
-------
                   APPENDIX A-9-3

EFFECT OF THE INLET 02 CONCENTRATION ON THE TOTAL CARBON
    BED DEPTH.REQUIRED TO REMOVE 90% OF AN INLET S02
                CONCENTRATION OF 2000 PPM
                             185
-------
       S02 SORBER DESIGN

  RUN NUMBER    TEST-7   DATE  7  27  71          .

  TOTAL CARBON RATE = 50.640 LBS/HR	_      _    "	
 ~bUTrET"CAR"BWTOADING = 0.1837.5 IBS  AC IJD/LQ CARBON" ..".,;.,i...:;.;..., .v.......,:;.. ,
  HEIGHT OF CARBON/STAGE > -.;C:..9.00' INCHES  '^MKiif^&^^fQ^M^^y
 _PlA-NEJLIB. _OF VESSEL = 18.0; INCHES   . .; .  .  ffxrlfe;;^
 TA'RBON USED =     "o.
  TOTAL GAS FLOW RATE =     18969.,  SCFH
  INLET S02 CONCENTRATION =	2000.  PPM
  INLET 02 VOLUME FRACTION =  . . ^0 . 0 A 6 0
   .   __
  OUTLET  S02" CONCENTRATION
  TEMPERATURE = 200.0 PEG. F
         2   "       1504.                   0.1329
         3            962.                   0*0774.
         4            -'tjC.                   O.G237
  TOTAL CARBON REQUIRED =     40.76  .INCHES
  TOTAL STAGES REQUIRED ASSUMING  9.00 INCHES CARBON/STAGE = 4.53
^: :S P AC E' VELCC IT YH='f:: ;-^
  PRESSURE DROP ACROSS CARBON  -     20.38 INCHES H20
  PRESSURE DROP ACROSS PLATES  =     10.19 INCHES H20
  TOTAL PRESSURE DROP ACRCSS STAGES =    30.57 INCHES  H20
                              186
-------
       S02  SORBER DESIGN

  RUN NUMBER    TEST-12   DATE   7  27  71

  TOTAL  CARBON RATE = 50.640 LBS/IIR
  'CUTLET  CARBON LOAOfNG"'=" O'.'l 037fi" L TiS ~AC IDYCTfCARBON"
  HEIGHT  OF CARBON/STAGE =   0.00 INCHES
  DIAMETER  OF  VESSEL ~  1_8»0  INCHES   _ i __i __
  CAR BUM  USED  -      67 	"~"'          "~
  TOTAL  GAS FLOW RATE =     HJ969. SCFH
  INLET  S02 CONCENTRATION =    _ 2000.  PPM _
  INLET  NO  CONCENTRATION^	"~" ~150'.~P'N"",~. 3""~
  INLET  02  VOLUME FRACTION  =   0.0200 :; .;>:: ::      •
  INLET  H20 VOLUME FRACTICN  ^..^l-iOp,    ; ________
  "OUTLET  s'o'2  CONCENTRATi'dN""= "   " 20b.~"pp~M

  TEMPERATURE  = 200.0 DEC.  F
              S02. CONCENTRATION  ,       ACID LOADING  ~'
      STAGE          PPM :  ::::,:;• ;:;'';:    LBS ACID/LB CARBON
            "                ':^^--^^--:'.. ^..  o.
&' _iii'- ;^^ i.1^^. Uu_.   •••-_•
          2            1699.                   0.1530
          3            1377.                   0.1199
          4            1041.                   0.0855

  TOTAL  CARBON REQUIRED =   '•   60.80  INCHES
  TOTAL  ST'AGES REQUIRED ASSUMING  9.00 .INCHES CARBON/STAGE  =  6.76
         VELGC I  Y       2l9.

  PRESSURE  DROP A C R 0 S S C A R B ON =     30. 4 0 INC H E S H2 0 __  m_
  "PRESSURE"  DROP" "ACROSS "PTAT"ES""="    15.20 INCHES H20
  TOTAL  PRESSURE DRCP ACROSS STAGC-S =     45.60 INCHES  H20
                             187
-------
      S02 SORBER DESIGN
 RUN NUMBER
TEST-13   DATE  7 27  71
 TOTAL CARBON RAJEjf_ 50.640 JJISVHR	
~ffUfL'Ef""CA"RB6N""LOAOINe""=""oTl8375  IBS  ACTDTLB CARBW
 HEIGHT OF CARBON/STAGE =    9.00  INCHES
_D I A ME T ER_ C F_V E S S E L JL 19 . P_J.NCHE_S__	,	
 CARBON USED =      0." """
 TOTAL GAS FLOW RATE =     18969.  SCFH
 INLET S02 CCNCENTRATICN_ =	2000.  PPM	
""INLET" NO"CONCENTRATION""=       1~50T"~	"
 INLET 02 VOLUME FRACTION  =•  0.0300
 INLET H20_VCLUME FRACTION =0.1300
"OUTLET S02~ CONC'ENTR'AT'TON"*      "200T
                       PPM
                         PPM
STAGE:
!•>••;•'
2
3
4
••.,-• "-,5v.-;-
^/•v0.53;:-.-,v:
S02 CONCENTRATION
PPM
-.:! .2000.
1616.
1199.
773.
:. -:.V:,-:-. »- -•• 378. .:-:-::/:
•;•-:- 2 oo. ooo i M-S
ACID LOADING ^
LBS ACID/LB CARBON :;
0.1837 '".. ••••'; •. ..;,,..:
0.144A
0.1017
0.0580
mm^, ::::c;,, .••. o.or/6.,.^._,-::.-.. ........
WZSvtst. i.:;: :?*;:*%*£ Jv 0.0 ••••• ''• ^-'••- • ' •'• 'A^:- K-S'* '•> '••»' ••'••' ••••'"•
myV!-ffiKX^M;Vf
-------
      S02 SORBER DESIGN

 RUN NUMBER   TEST-14   DATE   7  27  71

 !PJ"AL C.AR!i.ON_RA-lE "... 50*640 LBS/HR   	
"OUT"L"ET~C"A"R¥ON""LOAOING =;  o. r83"75~TB~s~ AC 1 D/FBTARBON"""
 HEIGHT OF CARBON/STAGE =   9.00 INCHES
_D IAMETER_ eF_Vj[SSE L  =  18.0  INCHES  '	
 CARBON~usED =   	   o.
 TOTAL GAS FLOW  RATE =     18969.  SCFH
 INLET S02 CONCENTRATION^ __2000. PPM
"INLET"NCTCONCENTRATTON" =  "  " i"5C)7
 INLET 02 VOLUME FRACTION  =   0.0600
 INLET H20 VCLUME FR_AC_TICN =   0.1300
 OUTLET "S02" CCNC'ENTRA'T i'0'N "= "    200 .
TEI*
f:-;--. •-.'.'

|- :,.- ••;.
1PERATUR
STAGE
•:,;• . l>
2
3
4
0.05
,E = 200.0 DEC. F
S02 .CONCENTRATION
PPM
2000.
1419.
788.
223.
:..::: 200.0001 :Vx:;:::::v-::

ACID LOADING : ;
LBS ACID/LB CARBON ' ;V
o. 1837 . . .;•;•••• .;.''"..; ;.:-{'.-K:
0.1243
0.0595
0.0017
:.:.::•::.'., •..-^•••- ::;...: ;.. 0.0 .. .' . . .:f:; ;;:
 TOTAL CARBON REQUIRED =      36.42  INCHES
 TOTAL STAGES REQUIRED ASSUMING  9.00 INCHES CAR B3N/ STAGE = 4. 05
SPACE VELOCITY,*
                      3537.  1/HR
 PRESSURE DROP ACROSS CARBON  *     18.21  INCHES H20
 PRESSURE DROP ACROSS PLATES  •      9.11  INCHES H20
 TOTAL PRESSURE DRO.P ACROSS STAGES  »     27.32 INCHES H20
                            189
-------
      S02  SORBER DESIGN

RUN  NUMBER   TEST-15   DATE  7 27  71

TOTAL CARBON RATE = 50^640 LBS/HR_
'CUTLET ' CAR'NCN LOA'D1'NG~ = " 6 . 1 8 3 7 5""L JJS~7kin'TJ7 L B . CWfl'ON""
HEIGHT OF CARBON/STAGE =   9.00  INCHES
DIAMETER  U F  V E S S E L = 18 OWCHES
CARBON
TOTAL
INLET
INLET
INLET
INLET
OUTLET
USED = 0.
GAS FLOW RATE =
S02 CONCENTRATION =
NO CONCENTRATION =
02 VOLUME FRACTION
H20 VOLUME FRACTION
S02 CONCENTRATION
18969
= 0.
=
. SCFH
2000. PPM
1000 •:,;;: 'v:';:;-':i; :•';>••:; • ...
200. PPM
 TEMPERATURE = 200.0 DEG. F
i; STAGE
!• " ' :•••;• 1
2
3
0.2»
S02 COivCr-NTRATlOM
PPM
2000.
1220.
403.
200.0001
ACID LOADING
LBS ACIO/LB CARBON
0.1837
0. 1039
0.0201
0.0
 TOTAL  CARBON REQUIRED =     29.51  INCHES
 TOTAL  STAGES REQUIRED ASSUMING 9.00  INCHES CARBON/STAGE =  3.28
 SPACE  VELOCITY =     ^365. 1/HR

J?.RE_SSyRE_DROP ACROSS CARBON - ::    14.76  I NCHES_^H20_	
 PRESYUR~£  DROP'TCROSS PLATES =    " 7.38"""l"NCHE"S H20
 TOTAL  PRESSURE DROP ACROSS STAGES  =     22.13 INCHES H20
                            190
-------
                 APPENDIX A-9-4

EFFECT OF THE INLET H20 CONCENTRATION ON THE TOTAL
CARBON BED DEPTH REQUIRED TO REMOVE 90% OF AN INLET
           S02 CONCENTRATION OF 2000 PPM
                     191
-------
      S02 SORBER DESIGN               .

 RUN NUMBER    TEST-7   DATE  7 27  71

 TOTAL CARBON RATE = 50.640 LBS/HR	
T)UTrErcTRBON"TnA€ING =. 0.1837.5.-.LBS  AC I D/.LB CARBON
 HE IGHT 'OF CARBON/ STAGE *  '
•DIAMETER OF VESSEL '= 18 .0
 CARBON USED =      0.
 TOTAL GAS FLOW RATE =     18969. SCFH
 INLET S02 CONCENTRATION =	2000. PPM
 INLET NO CONCENTRATION -.
                               '150.
 INLET 02 VOLUME FRACT ION . =l:;.OV0460-i!^^|;|||i§|||g^^
 INLET H20 VCLUME FRACTION =:,::>:• 0i" 130&iK^jSM^MMJm
"OUTLET 502 CONCENTRATION =
 TEMPERATURE = 200.0 DEC. F
                                 200.  PPM
            .502 CONCENTRATION.
                                      ACID  LOADING
     0.53:Ma:.::.::.U:200.0GOI
                                        ;:;;;.;:-::| ;.0.0.j:g
STAGE
1
2
3
4
PPM
2000.
1504.
962.
LBS ACID/LB CARBON ^^Xtf*^ '" -:•
:;-v:V:'.: - 0.1837 •••'••'' :: ''•'''"'?'' :*-"'A:S-:V. :.••••"'
	 . ,. -:'-v';V ."•»«-'• -::.-.;,• ••..-.•:.:•. v':- ::' • •-'.—.-"
0.1329
0.0774
0.0237
 TOTAL CARBON REQUIRED =     40.76  INCHES
 TOTAL STAGES REQUIRED ASSUMING 9.00  INCHES CARBON/STAGE = 4.53
;.;.; ...;•.'.;•• ::.-; •••';; •y^-'.ViY
SPACE VELCC
•;:.:-. . •/•. ;- : .-•;•>-.;..;..• ,:
• . . • .••• ••-: •• • -•-•..
.•'.-. •''•;-.';'.'.• ••'.'..'.•'.•,•.•.:•:-'.'.•;•' .'.-..','.•.•' .".'
:TY:..= --':'--:;:'iK3l6'ii'
•' ••v-.V/'ir i:.--'-: V' J:?:::W::.:^:::!':';"::''' •-.•:".
	 .••••--•••• . -• • ••.-••-•-• •-•••:.•.•:-••.
:;:J:s:.':;s:?;
•1/HR:

•:-::';:-:•::;:••'•••••:
;|;|?;::;s.;;:|::.v.
;;;x:;;;;-.;::.j:i:?S;j;2x
.':'.•'':'£"'•' '.•'.'?'''x'x':'.
:';:•:-::: ••'•:. .;::•>:••:••
f&:-V£tifK
ii:¥Siffii-i£:!-i?::;%
Jiiggi:;; •:':"»:
•'•. •! .-"•, '•':'- ' '•'• '•.
£^&&£?g$*.^t
;-;:.;i;:.:.::::;: ^;^3x££'& ^^l
;>:;:>:•>. ';V'1::'".:;v;:''';::'"':'OX''::::;:;':-t':*
•'•' •; -•'•- ••'•':';-'/-.:.:v ;':••.' •::.:;'•-;'•'•:•:•
:-X':-.-
•:•;•:•>
;''|;';| •
'•: >::::
<:,•:•: :'.\-..>
--•.;-;•>:: •:.:-• v
•"^*S**:
••; •:':•• :-':: •
 PRESSURE DROP ACROSS CARBON =     20.38  INCHES H20
 PRESSURE DROP ACROSS PLATES =     10.19  INCHES h20
 TOTAL PRESSURE DROP ACRCSS STAGES =     30.57 INCHES H20
                           192
-------
       S02  SORBER DESIGN

  RUN NUMBER    TEST-19   DATE   7 27 71

  TOTAL CARBON  RATE = 50._640_LBS/HR_  _  _  _
  OUTLET CARBON i TOADTNG "=  0.18375 LBS ACT07FB"*"CARBON
  HtlGHT OF CARBON/STAGE =   9.00 INCHES
  PIAAET_?.?  °.f. VESSEL = IB. 0  INCHES          _____
 ""S'EO"=""~ "  0.         ~~"
  TOTAL GAS  FLOW RATE =     18969.  5CFH
  INLET S02  CONCENTRATION  =      2000. PPM
  INLET NO  CONCENTRATION  =       150. PPM
  INLET 02  VOLUME FRACTION  =   0.0460 ^  .: :  . ,. ,•:     .  . ;•;
  INLET H20 VCLUME FRACTJ CN =   0.1000 :;;^   ,_;•:;,. \..^_ •,
  "OUTLET"S02" CbNCENtRAYlON  =       200." PPM

  _I?M.p.f?*iyM. '= 200.0 DEC. _F	
              S02""CO'NC"ENtR"ATION.        ACIOTOADTNG	"
      STAGE         PPM             LBS ACID/LB CARBON
  ..__._._	•i'y.ii::y•:!.:,,, .  :;V;V; 2000.            l:^":1-  ' 0• !837__ . ••..
         2            1586.                   .671413
         3            1136.                   0.0952
         4             680.                   0.0486
                       '.275. •:£:y%j^£^%;:&.,.,.;.c
 -TQJ.A.i .PA_R._60N REQUIRED -	46.94 INCHES	n	
: TYOTAL "STAGEST REQUIRED... ASSUMING^ aOJ^CHES^

L^SPACE.  VELOCI TV.. « 	2744<'ffiHRj^

  PRESSURE  DRCP ACROSS CARBON =    23.47  INCHES  H20
  PRESSURE  DROP ACROSS PLATES_=	  I K73_ INCHES  H20 . _   „„_
f TOTAL  PRESSUR'E"DROP"rAC"RdSS" STAGes"=.;i.  35,20  INCHES  ;H20 :  :v
                             193
-------
      S02 SORBER DESIGN
 HUN NUMBER
         TEST-20   DATE   7  27  71
 TOTAL  CARBON RATE = 50.64_0_LHS/HR	
"OUT L C T C A R B ON U6 A f) ING" = " O . l"8 3 7 5" L B S A CI 0 / L 8 C A~RB 0 N"
 HiflGHT OF CARBON/STAGE =   9.00  INCHES    :. .
 DIAMETER OF VESSEL = 1_8.0  INCHES, .,...;.-. ^.•..••^4\---t''\
 CARBON USL:l)"=  	  0.""	
 TIITAL  GAS f:LOW RATE =    18969.  SCFH
 INLET  SC2 CONCTNTRATION =	2000. PPM
 'INLLT  NO CGNCENTRAI IUN = "    Tf->6.~
 INLET  02 VOLUME FRACTION =  0.0460
 INLET  H20 VCLUME FRACT I CN_=_ 0.1 f>00
 OUTLET S02" CO.NCENTRAT ION -"
                               "PPM
                             200. "PPM
 TEMPERATURF. =200.0 DEG._F _
          "~Sb2""CONClENTRAT'lON'"
     STAGE         PPM
   2
   3
    _
0.21
                    _
                    1452.
                     856.
                   __ 302_.
                 200.0001;
   ACID LOADING
L8S ACIO/L8 CARBON
         0.1837 _
        "071277"
         0.0665
         O._0098
        "0.0  "
 TOTAL CARBON REQUIRED =      37.93  INCHES
 TOTAL STAGES REQUIRED ASSUMING  9.00  INCHES CARBON/STAGE
                                                      =  4.21
 SPACE VELOCITY =
                  3396.  l/HR
 PRESSURE DROP ACROSS CARBON =     18.97
 PRESSURE DROP ACROSS PLATES =      9.48
 TOTAL PRESSURE DROP ACROSS STAGES  =
                                    INCHES H20
                                    INCHES H20
                                    28.45 INCHES
                    H20
                           194
-------
      S02  SCRBER DESIGN

RUN  NUMBER   TEST-21    DATE   7 27 71

TOTAL CARBON RATE = 50.640 LBS/HR
OUTLE T""CARBON LOADING "*""b7llT375TBS""A'CTD7rB'~'C'AR'BON"
HEIGHT OF CARBON/STAGE  =   9.00 INCHES'":      :.    ,
DIAMETER  OF VESSEL = 18_.J)_ INCJHEJJV^ _ '^^^ ^  . ;:-':
CARBON USED" =~Cf.~"    "	          '~~^~      ~
TOTAL GAS FLOW R-ATE-=     18969. SCFH
INLET S02 CCNCENTRATION_=__ ,___ 2000. PPM
J'NLE T :NQ':TONC t-NTR AT i ONT =~V~  - A so".;
INLtT 02  VOLUME FRACTION*^ :'!ol0460'   :":-".
INLET H20 VCLUMb FRACTION =  ,0.20pp_   _
CUTLET SW CONCENTRATION "=   '   "200V PPM

V . | i
STAGED
2
3
0,66
i.E ='20Q;o DEC. F
j |/I T ',*'•' ~
' : •"' PPM
1335.
618.
200.0001
•i .. •'.: '"• rMu! I!.-.
ACID LOADING T
v LBS ACID/LB CARBON ; : r;:.
0. 1837 ' C •:
. 0.1156
0.0422
0.0
"TOTAL "CARBON REQUIRED =      32.90 INCHES
TOTAL  STAGES REQUIRED ASSUMING 9.00 INCHES CARBON/STAGE  = 3.66
 SPACE  VELOCITY = "  ;.   39T5^"l/HR

JPRESSURE CROP ACROSS  CARBON  =;  16.45 INCHES H20	
 PRESSURE DROP 'ACROSS "PLATES' =     8.23 INCHES H20
 TOTAL  PRESSURE DROP ACROSS  STAGES =    *24.68  INCHES  H20
                         195
-------
                 APPENDIX A-9-5

EFFECT OF THE INLET S0£ CONCENTRATION ON THE TOTAL
     CARBON BED DEPTH REQUIRED FOR 90% REMOVAL
                          197
-------
       S02 SORBER DESIGN

 RUN  NUMBER   TEST-35   DATE  7 27 71

__TOTAL  CARBON RATE = 12.690 LBS/HR
 OUTLET CARBO~N LOADING = 0.10375 LBS ACID/LB  CARBON
 HEIGHT IJF CARBON/STAGE -   9.00 INCHES
 DIAMETER OF VESSEL * 18.0 INCHES     _     	...
"CARBON USED -      o.
 TOTAL  GAS FLOW RATE =    18969. SCFH
 INLET  S02 CONCENTRATION =      500. PPM
 INLbT  NO CONCENTRATION =  "  150. PPM   "	"
 INLET  02 VOLUME FRACTION *  0.0460
 INLET  1120 VOLUME: FRACTION =  .0.1300	
'OUTLET S02 CONCENTRATION =       bo. PPM

_TEMPERATURE = .200.0. DEC.. F
STAGE
1
2
0.69
S.02 CONCENTRATION
PPM
500.
237-
50.0000
ACIO LOADING
LBS ACID/LB CARBON
_ . 0.1837 .
0.0761
0.0
  TOTA1,  CAHPON RF.QUI.RED *     2.4.23 INCHES               .	
 "TOTAL  STAGES REQUIRED ASSUMING 9.00  INCHES CARBON/STAGE  = 2.69
_S.PACE ..VELOCJ.IV._=	5.3_16_._L/HR	
 PRESSURE  DROP ACROSS CARBON =    12.12  INCHES H20
_PReSSUR.E_URtJP_.ACR.Q.SS.P_LAT_ES._5	&._06_JJ-JC_H.E5_H2_q
 TOTAL  PRESSURE DROP ACROSS STAGES =     18.17  INCHES  H20
    RATE  EXPRESSION USED IN DESIGN CALCULATIONS
 RATECIII=COEFF  *  (1-X(I)/XS)**A * (YS02**BI *  (V02**C)  * (YH20**D)
    WHERE  COEFF-K  *  EXPI-E/R*(II iT*460)))
          T=     200.         XS=    0.38       Y02=    0.046      YH20*   0.130
      -E/R"    5520.          A=   1.000         B=    0.400         C=   0.630          U=    0.730
        _.K"0.000159	_..._._  ..	__	_.._	.,_					_	
                                             198
-------
       S02  SCRBER DESIGN

 RUN NUMBtR   TEST-36   DATE   7  27 70

jr.U.T.AL.CARHON._RATE = 25..380 ..LRS/HR . .
 OUTLET  CARHON LOADING = 0.13375 LUS  ACIl)/l."(J"CARBON
 HEIGHT  (IF CARBON/STAGE =   9.00 INCHES
..DIAfETER  (^ .VESSEL..1. l.8.Q...HCt.CS	
 CARBON  USED -      0.
 TOTAL CAS FLOW RATE =     18069. .SCFH
_LNLE.J_S02._CP_N.C.F.MKATinN... =	looo., .PP.KL	
 INLET NO  CONCENTRATION »       150.  PPM
 INLET 02  VOLUME FRACTION  «   0.0460
 .INLET. H2C) VOLUME FRACTION =.  ..Q. U00_
 OUTLET  S02 CONCENTRATION  *       100. PPM
_JtMPLRATUKt V?00.0 DEC.  F	
             S02 CONCENTRATION         ACID LOADING
      STAGE         PPM             IBS ACID/LB CARBON
.	... .1 		  1000.			OL,.W7._	
         2            635.                   0.1092
         3            247-                   0.0299
	0.43 	LOO..OOOQ			0,.0,..__
  TOTAL  CARBON REQUIRED =      30.84 INCHES
  TOTAL  STAGES REQUIRED ASSUMING  9.00 INCHES CARBON/STAGE  *  3.43
  SPACE  VELOCITY *     4177.  l/HR      :

  ppp$«;iipp  [,qnP ACROSS CARBON ."	15.42 INCHES H20	
  PRESSURE  DROP ACROSS "LATES '      7.71 INCHES H/ll
  TOTAL  PRESSURE DROP ACROSS  STAGES =     23.13 INCHES H20
        ;. EXPJxnss.lON-USED-.JtJ.

 RATECII)«COEFF * U-XII )/XS) **A  *  =- —0.130....
          K«0.000159
                                            199
-------
       S02 SORBER DESIGN

 RUN  NUMBER   TEST-37   DATE   7  27  71

 TOTAL  CARI10N RATE = 38.060 LBS/HR
 "dilUt-T CARBON "LOADING = 0.18375 UBS  ACID/IB CARBON
 HEIGHT UF CARBON/STAGE =   9.00 INCHES
 uIAKETER OF VESSEL •'- 18.0  INCHES.  _._.. 	
 "CARBON USED =      0.
 TOTAL  GAS FLOW RATC =    18969. .SCFH
 INLET  S(!2 CONCENTRATION =	1500.  PPM     			
 "INIET'NO CONCENTRATION =       150. PPM
 INLET  02 VOLUME I'KACTION =   0.0460
 INLET  H2(l VC.LUME FRACTION f   0_.1300	  _    	
 "OUTLET so2 CONCENTRATION =       it>o.  PPM
 TEMPfcKATUKE « 200.0 DEG. F
             S02 "CONCtNlRAI ION         ACID LOAUING
      SlAGt          PPM             LBS  ACiO/LB CARBON
         1            1?>00.           _    	0. 1837
         I            1062.                   0.12'.l
         3             587.                   0.0092
         i\    	   J63._ _   	     _ _p_.00i5
      0.03         150.0001                   0.0
 TOTAL CAROON REOUIREO =     36.31  INCHES
-JfllAL S J ACE S_REQU J.KEO_ASS_UMlN.G_9_._eO  \ NCH£$_..C_ARBON./ SI AG.C__r_..'s_._03	,	

 SPACE VELOCITY =     3547. 1/HR                    .             :   '
 PRESSURE  DROP ACROSS PLATES =      9.OB  INCHES H20
J.Q.TAU._PRESSURE._DRp.P. ACROSS.3JA6Ei.«_ _2J_li4_IN£H£S..H2a	
    RATE  EXPRESSION USED IN DESIGN CALCULATIONS

..RATECU ) = COEFF * (l.-X( I )/XS.).**A * (ySD2**B)  * (V02**C) *  (YH2q**D).	
    KHCRE COEFF = K » EXPI -E/R*t I/(T + 460)))

	..  ..   T=  ..  200.  .. _    X3=    0..38	_...y02= .. 0,046.	YH20=. ,._O.J30
      -F/R=    5520.          A=   1.000          B=   0.400          C=    0.630          0=    0.730
          K-0.000159
                                                 200
-------
       S02  SORBER DESIGN

 RUN  NUMBER   TEST-38    DATE   7 27 71
_T.PTAL  CARBON. RATF =  50..75Q LOS/MR   _	   	
• OUTLET CARBON LOADING =  0.18375. LttS~AC.1 "b/LB~ CARBON"
 HEIGHT OF CARBON/STAGE  =   9.00 INCHES
_P1AMF.TF.R. OF..VESSFL *_ l8.0_LNCJiF.S	
 CARBON USED -      0.
 TOTAL  GAS FLOW RATF:  =     18969. SCFH
 IN'l.ET_SP2 CONCENTRATION  =  _  2000. PPM	
 INLET  NO CONCENTRATION  =      150. PI>M
 INLET  02 VOLUME FRACTION =  0.0160
_..)_NLET .H2Q .VG.LUME FP ACT.I ON _?.__Q, 1 300
 OUTLET S02 CONCENTRATION -      200.' PPM

_!Er,PERATURF:. '...200.0  DEC. F	
             S02 CONCENTRATION        ACIO LOADING
      STAGE         PPK             UBS ACIU/LB  CARDON
		I  		  ..2000.. ..__._.		Q.1HJ7
         2           1504.                  0.1330
         3             962.                  0.0777
		A  	     
-------
      S02 SORBER DESIGN

 RUN NUMBER   TEST-39   DATE   7  27  71

 TOTAL CARBON RATE = 63.440 LBS/HR      . .		
"CUTLET CARBON LOADING » o.13375 LBS  ACID/LB CARBON
 HEIGHT OF CARBON/STAGE «   9.00 INCHES
 DIAMETER OF VESSEL =  IB.p INCHES    		_	
"CARBON USED =      o.
 TOTAL GAS FLOW RATE =    18969.  SCFH
 INLET S02 CONCENTRATION =_  _ 2500.  PPM  	
 INLET NO CONCENTRATION =      150.  PPM
 INLET 02 VOLUMF FRACTION *  0.0460
 INLET H2H VOLUME FRACTION «   0.1300		
"CUTLET su2 CONCENTRATION =       250.  PPM

 TEMPERATURE = 200.0 DEC. F
            S02 CONCENTRATION         AC IU  LOADING
     STAGE         PPM            LBS  ACIO/LB CARBON
        1   ._      2500. .   _     .  _..... .P..J.837..
        2           1953.                   0.1391
        3           1358.                   0.0904
        4    _     _ ?62..	   	Q.041.7
        5            253.                   0.0000
     0.01        249.9999                   0.0
.TOTAL CARBON PFOUIREO «  _  45.01  INCHES
 TOTAL STAGES K( QUIRED A'SSUMING 9.00  INCHES  CARBON/STAGE = 5.01

 SPACF VELOCITY       2ft5.8.t_JL/t
 PRESSURE DROP ACROSS CARBON =    22.53  INCHES  H20
.PRESSURE DROP ACROSS PLATES.. =	 l.U27_J NCHE.S...H2.0		
 TOTAL  PRESSURE OftOP ACROSS STAGES =     33.80  INCHES H20
    RATE  EXPRESSION USED IN DESIGN CALCULATIONS
 SATECI I I^COEFF * t I.-X( 1 )/XS)**A *  (YS02**B)  *  (Y02**C)  * (YH20**D)
    WHERE COEFF = K * EXPI-E/R* ( \l ( T+'t60 I I I

         T*    200.         XS=    0.38        Y02=    0.046      YH20=   0.130   	
      -E/R*   5520.          A=   1.000          B«    0.400         C=   0.630          D=    0.730
         K=0.000159
                                            202
-------
       S02 SDRBER  DESIGN

  RUN NUMBER    TEST-40   DATE  7 27 71

_J.QtAL. CARBON. RA1E...T...76. 130 L.BS/HR ____       ___
  OUTLET CARBON  LtJAUING = 0.18375 LBS Aclu/LO  CARBON""
  HEIGHT OF CAKbON/STAGE «   9.00 INCHES
i_U.l.A^£.TfH. Qf-VE.SSE.L._«._1.8..0-IMCHES     ____
  CARBON USEO =0.              __
  TOTAL GAS FLOW RATE  =    18969.' SCFH
_lN.L,tJ_.S02_C-a/K.E.MLR-AT.LOM..r _______ JflQQ. PPM __ ____
:  INLET NO' CONCENTRATION =      150. PPM
  JNIET 02 VOLUME  FRACTION *  0.0460
L_lI4LEt_H20. VOLUME. FRACT.10N_.= __Q._l_3iiD ___ ____
  OUTLET S02 CONCENTRATION =      300. PPM

_J.EMPERATURE =_200,Q  OEG, .F ____________ . _____ _______ ._
             S02 CONCEN1RATION        ACID LOAOJNG
•      STAGE          CPM            LBS ACID/LB CARBON
_______ ..... 1 _________ .JOOO. ____________________    .O.L8J.7
         2           2409.                   0.1435
         3            1768.                   0.0998
                                              .a «
         5             316.                    O.OU5
      0.42         300.0000                    0.0
  TOTtl  r.ARRIlN RFQtltRFn =	48. 78 IMf.HF!;	
;  TOTAL STAGES REQUIRED ASSUMING 9.00  INCHtS  CARBON/STAGE = 5.42 :.-:  : ,  :

_.SAAC£ -VEI.OCI TJf_=__
  PRESSURE DROP  ACROSS  CARBON »    24.39  INCHES  W
  TOTAL PRESSURE  DROP  ACROSS STAGES =     36.59  INCHES H20
$.   •         ,-   •-,• - *'.;  .•»>..  .:  • -  •--   ••••  " ^*; -y^j^k'^
     RATE EXPRESSION  USEO IN DESIGN CALCULATIONS
  *ATECU»=COEFF *  ( l~K( I )/XS)**A * -------
       S02 SORBER DESIGN

  RUN NUMBER   TEST-41   DATE  7 27  71

_TOTAL CARBON.RATE =101. 500 . IBS/MR   	 . _	___..
  OUTLET CARBGN LOADING = 0.18375 LUS  ACID/LD CARBON
  HEIGHT OF CARBON/STAGE =   9.00 INCHES
_DIAMF.THR OH VESSEL = 18.0.  INCHES.		
  CARBON USED *      6.
  TOTAL GAS FLOW RATC =    10969. SCFH
_ INLET S02 CONCENTRATION «_    _4QOC).  PPM  __
  INLCT NO CONCENTRATION =       150. PPM
  INLET 02 VOLUME FRACTION =  0.0'<60
  INLET H20 VOLUME FRACTION ?_  .0.1300			
  OUTLET SU2 CONCENTRATION =      400.  PPM

 _TEMPFRATURE = 200.0 DEC-. F   _     .      ._.	  .
             S02 CONCENTRATION         ACID LOADING
      STAGE         PPM            IBS  ACID/LB CARDON
_       1           4000.        _  		0.. 1837    ..
         2           3332.                  0.1496
         3           2612.                  0.1128
 _       4	      1867.	   0.0747
         5           1143.                  0.0377
         6            510.                  0.0054
	.0...2Q	4QQ nO.QO.0.	J3,0		
  TOTAL  CARBON REQUIRED =     55.79  INCHES
  TOTAL  STAGES REQUIRED ASSUMING 9.00  INCHES  CARBON/STAGE  = 6.20
  SPACE  VELOCITY =     230<3, 1/HR

_RRESSURE .DROP. ACROSS..CA.RBON •-:	?.7.9D_IilCHESi_H2D	
  PRESSURE DROP ACROSS PLATES '-    !.3.95  INCHES  H20
  TOTAL  PRESSURE DROP ACROSS STAGES *     41.84  INCHES  H20
    ..RATE.JXPRCSS10N USEQ..JN -DESIGN CALC.ULAT.IONS.
 RATECII)=COEFF * (1-XII)/XS)**A *  (YS02**B)  *  (Y02**CI  * 
-------
                  APPENDIX A-9-6

EFFECT OF THE INLET SC>2 CONCENTRATION ON THE TOTAL
      CARBON BED DEPTH REQUIRED TO ACHIEVE AN
        OUTLET S02 CONCENTRATION OF  100 PPM
                           205
-------
       $02 SCROER DESIGN

  RUN NUMBtR   TEST-36    DATE  7 27 70

_TDL4J._£ AR BON...R 4 T E. ..= .2_5_.J 8 0_Lfl SZHR_
  OUTLET CARBON LOADING  «  0.18375 LBS ACID/LB CARBON
  HEIGHT (IF CARBON/STAGE =   9.00 INCHES
  CARBON USED =       0.
  TOTAL GAS FLOW  RATE  =     18969. .SCFH
  INLET SQ2 CONCENTRATION,*	1.00
-------
      S02  SURBER  DESIGN

 RUN NUMBER    TEST-49   DATE  7 27 71

JLOT.AL CARBON. .RATF  =03.570 LBS/HR
 CUTLET CARBON  LOADING = 0.18375 LBSACID/LB CARBON
 HEIGHT OF CARBON/STAGE =   9.00 INCHES
 OJAHETER  OF  VESSEL _= 18.0 INCHES_	
"CARBON USED  ^       o.
 TOTAL GAS FLOW RATE =    18969. SCFH
_INLET SQii CONCENTRATION .5   _ 2000.  PPM  	
 "INLET NO  CONCENTRATION '=     "I"*O"."PPM"" "   "	"~
 INLET 02  VOLUME  FRACTION -  0.0460
 INLET H20 VOLUME FRACTION *  0.1300  _	
 OUTLET S02 CONCENTRATION -      lOO.Vf'M

 TtMCtRATURL  =  200.0 OEG. F
            S02 CONCENTRATION        ACIOLOAOIHC"
     STAGE          PPM            LBS ACIU/L8 CARBON
        1            2000,               _ Q.l(!37
        2            liO-V,                  6.13^7
        3             968.                  0.0838
        A             451.     	   _     Q.Q338
	"O.B«       "166.0060                  6.6
 TOTAL CARBON  RFQUIRFO =     43.90 INCHES
__TQTAL_S.TAGES. REQU IReO_ ASS.UM I NG. 5, .OJJ..I NCHE.5._ CARBON/ STAGE _=__4.88__

 SPACE VELOCITY =      2934. I/HP.
 PRESSURfc  UKUP  ACROSS CARbOH =    21.95 INCHES H20
 PRESSURE  DROP  ACROSS PLATES =    10.98 INCHES H20
 _TOTAL_PRESSURE DROP ACROSS STAGES_=	J2.93_INCJ1ES_H20__
    RATE  EXPRESSION USED IN OESIGN CALCULATIONS

        l )=COEFF  *  (1-XI1 1/XSI**A *_ ( YS_C2**B I. * _ I Y02**C ) *._LYH2a**PJ.	  			
    hHERE  COEFF=K  * EXPt-E/R*(I/(T+460)))

          T=    200.        XS=     0.38       Y02=	0.0'.6_	._ YK2P5...  0.110    	 _	 	
      -E/R=    5520.         A=    1.000         B=   0.400          C»    0.630          0=   0.730
          K=0.000159
                                             207
-------
       S02 SORBER  DESIGN

  RUN NUMBER    TEST-50   DATE  7 27 71

_TOTAL CARBON.RAU  = 11Q..OOO LRS/HR	
  OUTLET C AC, II ON  LOADING = 0.18375 LHS ACIU/LB CARBON
  HEIGHT Or CAROON/STAGE -'  9.00 INCHES
  OlAMEH* uf VESSFl,_=L IB.Q INCHSi. ____________ __
  CARIHJU USED -       0.
  TOTAL GAS FLOW RATF =    18969. SCFH
  INLI 1 SO? COUCrNTP.AT10N_=.     .4000. ..P.PM ____________________
  INLET NO CONCfcNfUATlhN "=      150. PPh
  INLET 02 VOLUME  FKACT10N =  0.0460
  INLET ll^O VO.LUMb FRACT[ON. = ___O.UOO.__. ____________ . _______
  OUILEI S02 CONCENTRATION -      100.  PPM

      E MATURE =.200.0 DfG. f  ..... ____ .._  ....... _ ....... .
             SC12 CONCENTRATION        ACID  LOADING
      STAGt          PPM            LBS  ACIU/Lli CAkOON
         1    ...   .   .3000., ....... __________ ...... 0..1837 ......
         2            3332.                   0.1523
         3            2620.                   0.1187
        ..'t         ..  186"?, ______ ___ ...... _______ 0.08
-------
                 APPENDIX A-9-7

EFFECT OF THE INLET SC>2 CONCENTRATION ON THE TOTAL
  CARBON BED DEPTH REQUIRED TO ACHIEVE AN OUTLET
            S02 CONCENTRATION OF 50 PPM
                           209
-------
       S02 SORBER DESIGN

  RUN  NUMBER   TEST-35   DATE  7 27 71

 _LPTAL CARBON RATE  = 12.69Q.L6S/HR
__                          .
r  OUTLET  CARBOli LOAUING = 0.18375 LBS ACIO/LB CARBON      .'
i  HEIGHT  UF  CARBON/STAGE »   9.00 INCHES             .    i  . •- '.
LPJAMETER  OF_V£SSEL_=_ la.q INCHES ___     •••' • ":. .-.. -'"}.
 CARBON USED «       0.
 TOTAL  GAS  FLOW RATE =     18969. SCFH
_1NLET  S02  CONCENTRATION =	500. PPM	
f: iwit'i  NO CONCENTR'ATION' =~    "isb. PPM
I. INLET  02 VOLUME FRACTION «   o.04&o
L.INIE.T  H20  VOLUME FRACTION =	Q._130.Q	
 OUTLET SO? CONCENTRATION «        i6.  PPM

 TEMPERATURE -  200.0 DEC. f
£.'v •'••:. STAGE
1
2
0.69
S02 CONCENTRATION
PPM
500.
237.
50.0000
ACID LOADING ;i ; .;: -
•>'LBS ACID/LB CARBON, ••••'•';. '••. "•'' , i-;™' -' •. -'?•... : s •. ••;. ••• , .•• •'••'.?.'" •• •: >
0.1837 :.. ! ."..
0.0761
0.0
        CARBON_RE9UI.REO  =   __ 24. 23_ INCHES.
 TOTAL  STAGES  REQUIRED  ASSUMING 9.00 INCHES CARBON/STAGE = 2.69
_iPA.QE  VELOCITY  =	5316.  1/HR			

 PRESSURE  OROP ACROSS  CARBON »     12.12  INCHES H20
/PRESSURE  DROP ACROSS  PLATES =      6.06  INCHES H20	„	
 IUIAL  KKtSiUkt  DROP ACROSS  STAGES =     18.17 INCHES H20
I-: :: RATE EXPRESSION USED  IN  DESIGN  CALCULATIONS
 RATECU ) = COEFF *  Il-X (I I/XS)**A  *  (YS02**B)  * (Y02**C)  * (YH20**D)
    WHERE COEFF-K  » EXP(-E/R*(I/IT+460)))
         T«    200.         XS*     0.38        Y02«    0.046      YH20«=   0.130
      -E/R*   5520.         A»    1.000          B-    0.400         C«   0.630          0»    0.730
   	_.K-0.000159.	,	,	'.	L.	.	
                                              210
-------
     S02  SI1KBER DESIGN

RUN NUHHFR    TFST-'jl   OATP   7 27 71

TOTAL CARBON RATf = 5" 1 Ysu2**o"r *  (Y02*'*cT~*"TYH2ov*br
    WHtRH CUEFF'K *  EXP(-E/«*I 1/(T+'.601 I I
         I>    200.
      -E/R«   5520.
         K'O.000109
                                  '67Ja"
                                  i.ooo
Y02"
  B=
0.046
0.400
"YH26-
    C-
0.130
0.630
0.730
                                             211
-------
        S02  SORBER DESIGN

  RUN  NUMBER   TEST-04    DATE   7 27 71

_J£TAL  CARBON RATC *lll«.4PO LBSVHR	
  OUTLET  CARRON LOADING =  0.18375 IBS ACID/IB CARBON
  HtlGMT  OF C.ARBCJN/STAGC  =   9.00 INCHES
_PIAMCUK  OF. VfSSEL...!L.18.«.D_LMCJi£i__	
  CARBCN  USfcU =      0.
  TOTAL  GAS FLOW RATE =     18969. SCFH
	1 .NLE 1_ .S.O.Z. ..C.ON.C.E NT P. AT_.LO.N_=	A 0_00._ P P.M	
  INLET  HU  CONCENTRATION  =       150. PPM
  INLET  O/  VClUf-r FRACTION  *   0.0460
             VOLUME F.RAC.T1QN_* ._0,JJQP_
  CUTLET  SU2 CONCENTRATION  =        50. PPM

  JEMPCRATUKt = 200.0 DEC.  F     _..  	
              S02 CONCENTRATION         AC I 0 LOAOJNG
      STAGE          PPM             IBS AC10/LB CARBON
 .	   1     . .__    4000.          _	Q.1837_
          2            3332.                   0.1527
          3            2621.                   0.1195
 _......   Jt ...  ...-'-.	 1893,	,		..0.0656... ...
          5            HUB.                   0.0528
          6      '       567.                   0.0239
 		_I	115.	Q.QD.Sfl	
      0.25.         -50.0000                   0.0
  TOTAL CARBON  RFQUIP.ED =     65.21  INCHES
._TOTA( MAUI-S  RbUUIRfcO AS!>UnlNL.      5520.         A«    1.000         B«    O.'iOO         C=    0.630         0=    0.730
          K=0. 000159
                                              212
-------
                 APPENDIX A-9-8

EFFECT OF THE OUTLET H2S04 LOADING ON CARBON ON THE
   TOTAL CARBON BED DEPTH REQUIRED TO REMOVE 90% '
     OF AN INLET S02 CONCENTRATION OF 2000 PPM
                     213
-------
       S02 SORBER DESIGN

  RUN NUMBER    TEST-7    DATE   7  27  71

  TOTAL CARBON  RATE  = 50.640 LBS/HR
["OUTLET CARBON" LOADING  =  0.1837.5  LUS  AC ID/LB~CARBON
i  HEIGHT OF CARBON/STAGE =
I  DIAMETER OF VESSEL  =
  _
  CARBON USED =      0.
  TOTAL GAS FLOW RATE =     18969.  SCFH
  JNLET S02 CGNCfrNTRATlQN_j=	2000^ PPH
  TNYETWO~TONCENTRATlON  =    :,,  150~7 .
  INLET 02 VOLUME FRACTION  =  '0.0460
  INLET  '20VCLUME  FRACT I CN ~  0.
  OUTLET S02 CONCENTRATION  =       200.  PPM

  TEMPERATURE = 200.0 DEC.  F
< - STAGE
^ 1
2
3
S02 CONCENTRATION
PPM
2000.
1504.
962.
438.
,ACID LOADING ,,;%•: -:,.^^f, + .- . .
LBS AC 1 D/LB C ARBON ^f^fe^;' .'•.;
0.1837 ,^:s::yUSil? ^A?- ; /
0.1329
0.0774
0.0237
  TOTAL CARBON REQUIRED =     40.76  INCHES
  TOTAL STAGES REQUIRED ASSUMING  9.00  INCHES CARBON/STAGE = 4.53
|: SPACE VELCCITY.,=;;;;;4:g3i:61r;^
                                                         :I:S?^^*^as;'
  PRESSURE DROP ACROSS  CARBON  -     20.38 INCHES H20
  PRESSURE ORRP ACROSS  PLATES  =     10.19 INCHES H20
  TOTAL PRESSURE DROP ACRCSS STAGES =     30.57 INCHES H20
                            214
-------
       S02 SORBER  DESIGN

  RUN NUMBER    TEST-16   DATE  7 27 71

  TOTAL CARBON  RATE  = .50_^40_ L__BS/HR	
  "OUTLET cARBONToADiNG = o.oTrel LBS ACro7lT~cAR'BON"
  HEIGHT OF CARBON/STAGE =   9.00 INCHES
  DIAMETER OF VESSEL = 18j.O__I_NCHES	„____	
  "CARBON usED"-^	cT. "       ^ '•' '       ""
  TOTAL GAS FLOW  RATF =    18969. SCFH
  INLET S02 CONCENTRATION =_	2000._PPM	
  INLET NO CONCENTRATION"^""  """ ~II>O.~P"£H~~:':.  ~
  INLET 02 VOLUME  FRACTION =  0.0460    ::   : :
  INLET H20 VLLUME FRAC.] I CN_f___p_._l_300 ___	
  OUTLET" so2 coNCENTRAnoN =      200". PPM"

  TEMPERATyRE = 2.00.0 DEG_._F	    	
           "r'sdY""CONCENTRATION     "  ACID LOA'D'ING
   :   STAGE:;     .    PPM          .  LBS ,ACl D/LB CARBON
                      2000.                  0.0919
         2            1291.                  0.0192
         3             588.                  0.0
      0.75         200.0001                  0.0
  TOTAL CARBON  REQUIRED =     33.76 INCHES
  TOTAL STAGES  REQUIRED ASSUMING 9.00 INCHES CARBON/STAGE  - 3.75

r"TpATEnin!UbciTY^                               ••,:, -rii^^^C^

?  PRESSURE  DRpP_ACRgSS CARBON V\:   16;88  INCHES  H20 ::'.'' ^Lj^LJ-••;.•::•?'••
""'PRESSUR'E "DROP ACROSS'TLAT'ES =    " a"."^4  INCHES""H2"o"
  TOTAL PRESSURE DROP ACROSS STAGES =     25.32  INCHES  H20
                             215
-------
      S02 SORBER DESIGN
 RUN NUMBER
TEST-17   DATE  7 27 71
 TOTAL CARBON RATE = 50-640  LBS/HR     	
 OUTLET "CARBON LOADTNG"'= 0". 27"562 WS "AC I DTOTTlARBON
 HtlGHT OF CARBON/STAGE =    9.00  INCHES   " i:. • ;:v.. v. :J  :;
_DUMETF:R OF VESSEJ. = _18.0 INCHES	^JlIilMliS^-'^
 CARBON "USfcD"="""  ~ 0.
 TOTAL GAS FLOW RATE =     18969.  SCFH
 INLET S02 CONCENTRATION =   _   2000. PPM_    __
 INLET NO CONCENTRATION'--    "  TSO.'PPNT"   ;'•--—-
 INI.ET 02 VOLUME FRACTION  ~  O.OA60        A',. ••
 INLET H20 VCLUME  FRACTICN =__0^1300    _^_  ;  _
 OUTlET SU2"CCNCCN'TKATfUN""-"""    "200. "P'PM
 TEMPERATURE = 200.0 DEC. F
            "502 CONCENTRATION
     STAGE
        __
        5
     0.32
    :PPM
    ,.  2000
  "ACID LOADING
LBS ACID/LB CARBON
         0.2/56  :...;'
                    1409.
         _
       665.
         0.2't79
         0.2151
         0.1780
           1388
           1019
   200.0001
0.
0.
0.0912
 TOTAL CARBON REQUIRED =    ;  56.90  INCHES
 TOTAL STAGES REQUIRED ASSUMING 9.00  INCHES CARBON/STAGE-^ 6.32
 SPACE  VELOCITY =
        2264. 1/HR
 PRESSURE DROP ACROSS_CARBCN =  	_28_.45 J_NCHES H20    __
"PRESSURE DROP" ACROSS "PLATES'^    "14.22  INCHES "H2o"
 TOTAL  PRESSURE  DROP ACROSS STAGES =     42.67 INCHES H20
                           216
-------
      S02 SOR8ER DESIGN

 RUN NUMBER   TEST-18   DATE   7 27  71

JJ?TAk CARBO_N RATE = 50.640 LBS/HR
 CUUETCA~RBCN 'LOADTNG" = 0%3675~0  LBS~ ACTD/TF
 HEIGHT OF CARBON/STAGE =   9.00  INCHES
 DIAMETER QF yESSEL = 18.0 INCHES
"CARBON'USED~ = '"
                         CARBON
0.
 TOTAL
 INLET
"INLET
 INLET
 INLET
 OUTLET
                PPM
GAS FLOW RATE =     18969.  SCFH
S02 CONCENTRATIONI _=	_200p.  PPM
NO CONCENTRATION"^   "   "156".
02 VOLUME FRACTION  =  0.0460
H 20 VOLUME F R ACT! ON  -   0_._l 3 0 0_
 S02" CONCENTRATION  =   " 	"
             200. PPM
 TEMPERATURE = 200.0 OEG._F  _
           "S"02 CONCENTR AT ION
     STAGE         PPM
        l.:'.-:'-.-:'"V- . -    2000. •'•••••••T
                 ACTt5 LOAOTNG" "
              LBS ACID/LB CARBON
              ;         0.3675
2
3
4
5
6
/
8
9
10
n
12
13
14
0.38
1967.
1925.
1872.
1806. .,«
'1723. "3 \
1 622.+. T^
1498.
1348.
1173.
970.. -vx
7 4 6. ••'•;;•£
510. :?
281.
200.0001
0.3641
0.3598
0.3544
^.::f:.:*.:-..?,i*;.:^.:-.<.. 0.3476 , .: ••:•-/•: •;..
;:::;>i:•M:ii::;i..tr^,:::.::iC:v•:r:,v.:i•.••o ^^qi ' ..••;:> ;-:- ;--r. ":
-.;•. .v.;.::::v:*'f •.?:..'. T;V,:, -Af-:.:, .', U * * * J L : - '. - .•-..••,
••^•••^•^^'^•^}:-'- 0.3281 :••'.••• '..:• . ;•=•••:••:••
0.3160
0.3008
0.2827
'^:::,K^-m'(<:m^----: ' ;.; 0.2620
^i^liJiitiiSW'f :i';-:-' 0. 2390
::;::t^!Nv|!|5-:;;i:;:^?::::l:', 0.2143
0.1914
0.1831
JOTAL CARBON R F_Q UIR iD _=_ _ ili*:38  I NCHESl	.	,	
 TOT'AL"S"TAGES"REQUTRED~ASSUMING  9.00  INCHES CARBON/STAGC =14.38
 SPACE VELOCITY =
   996. 1/HR
 PRESSURE DROP ACROSS CARBON =     64.69  INCHES H20
_PRESSURE DRCP ACROSS P_LATES _=_ _32 ._34_JNCHES H20	
 TOTAL PRESSURE DROP ACROST STAGES =     97.03 INCHES H20
                           217
-------
                   APPENDIX A-9-9

EFFECT OF THE TEMPERATURE ON THE TOTAL CARBON BED DEPTH
 REQUIRED TO REMOVE 90% OF AN INLET S02 CONCENTRATION
                      OF 2000 PPM
                       218
-------
      S02 SORBER DESIGN

 RUN NUMBER    TEST-7   DATE  7 27 71
 TOTAL CARBON RATE =_
"OUTL'ET" C "ARBOirLOAD ING
 HEIGHT OF CARBON/STAGE =
_DIAH E1ER_OF_VESSEL = 18.0
 CARBON "US ED" =
 TOTAL GAS
       S02
      "NO""
                     50JL640J.BS/HR
                       = . 0."1837.5
                          LBS  ACt.D/LB  CARBON"
                     :9.00 INCHES.
                     INCHES
JNLET
 INLET
 INLET
 INLET
 "OUTLET
             o.
    FLOW RATE =     18969.  SCFH
    CGNCENTRATION_f_	2000. PPM
   CONCENTRATTON =    .:,, 150.  PPM"
02 'VOLUME
                 FRACTION =
                  P R ACT I CN =
   150
: 0.0460 v
 :;,0 . 1 300
 S02 CONCENTRAlON =
                                 200.  PP'M
            _= 200 <._^ 	
            S02"CONCENfRAflON
, STAGE
; i
2
3
PPM
2000.
1504.
962.
438.
LBS ACIP/LB CARBON
0. 1329
0.0774
0.0237
                ^2 00,000 i::,
                                            0.0
 TOTAL CARBON REQUIRED =     40.76 .INCHES
 TOTAL STAGES REQUIRED ASSUMING 9,00  INCHES  CARBON/STAGE = 4,
                                                              53
 SPACE VELOCITY =
                      3161. 1/HR
 PRESSURE DROP ACROSS CARBON =    20.38  INCHES  H20
 PRESSURE DROP ACROSS PLATES -    10.19  INCHES  H20
 TOTAL PRESSURE DROP ACRCSS STAGES =     30.57  INCHES H20
                           219
-------
      S02 SORDER DESIGN

 RUN NUMBER   TEST-22   DATE   7  27  71

 TOTAL CARBON RATE = 48.790 LBS/HR
 OUTLET CARBCN LOADING = 0.18375  LBS  ACID/LB CARBON
 HEIGHT OF CARBON/STAGE =   9.00  INCHES
_OIAMETCR OF VESSEL = 18.0.. INCHES  .;•   -v -:::;;;.'•'::;• <-v::  ^__
 CARBON USEO~=0.	
 TOTAL GAS FLOW RATE =     18276.  SCFH
 INLET S02 CCNCENTRATIO_N_= _ __200_0_._  PPM	
 INLET NO CONCENTRATION "-" "	TSO". PPM~ " ."."
 INLET 02 VOLUME FRACTION  =  0.0460    .<  .  ;
 INLFT H20_ VOLUME FRACTION  -  0. 1300  '''''"'.
 OUTLET s"02 "CCNCENTRATION"^"      2601 "PPM"

STAGE
1
2
3
4
5
0.52
S02 CONCENTRATION
.PPM • - "•.. : ,:••;.•
. ..'.:;, . 2000. i. i .
1615.
1198.
771.
376.
200 . GOO 1
ACID LOADING
•-•. LBS ACID/LB CARBON A :*
.:;i:;::.:-'-;".;:'::-'.. :•:•••• 0.1837 /:\,":^^:
0.1443
0.1016
0.0579
0.0174
/•* rs
w * o
       CARBON_   _		
"TOTAL"STAGE'S "REQUIRED. ASSUMING  9".oo""iNcvrE"sT'CARBON/sTAGF;=  5T52

SPACE  VELOCITY =     2498.:1/HR:
 PRESSURE  DROP ACROSS CARBON =     24.84 INCHES H20
 PRESSURE  DROP ACROSS PLATES =_  _L2'42 INCHES H20
 TOTAL  PRESSURE DROP ACROSS" STAGES ="'T 37.27" INCHES ~H2lf
                               220
-------
      S02  SCRBER DESIGN

RUN  NUMBER   TEST-23    DATE   7 27 71

TOTAL CARBON RATE = 47.070 LBS/HR
OUTLET "CARBON LOAD I N(T ="'OVl 8375~niT"^CTiJ7rB~C"7rRBON'
HEIGHT OF CARBON/STAGF.  =    9.00 INCHES
DIAMETER  OF VESSEL =_l_8_.0  INCHES ::
CARBON USED =	0.   '"       ~  ———     ~
TOTAL GAS FLOW RATE =     17633. SCFH
INLI-T SG2 _CCNCENTRATION =_    2000_. PPM
"INLF. T NG~'CONCENTRAT ION "="       T50- ~"PPM""""~™~"™:~"
INLET 02  VOLUME FRACTION  =  0.0460   '.:-.--.''x '•'• • • ::'^^\ • •
INLET H20 VOLUME '-RACTICN_^	9_«J._300     :;;..: . :..':^:.:.;•-
"OUTLET S02" CONCENTRATION"^      200T"PPM  —-^   :-
TEMPERATURE
| STAGE.....
2
3
. 6
0.71
= 250.0 DEG. F
S02 CONCENTRATION
, ;.; : PPM
:''::•'•.: I'T.^:--" 2000'.'
1697.
1371.
1033.
2CoJoQr-fiiiSl


ACID LOADING
LBS ACID/LB CARBON
0. 1837
0.1527
0.1193
0.0846
:;,::;,-::s,;;::--.:-,:: ,,.,..: 0.0503.
?f:p^d^::;--. .-o.oias:
Wfiti&t&ti'-L 0..0

YOTAL":CARBON""REC!U"IRED  =   ;  ;60".37
TOTAL  STAGES REQUIRED  ASSUMING 9.00 INCHES  CARBON/STAGE = 6.71
SPACE  VELOCITY =      1984.  1/HR

PRESSURE DROP ACROSS  CARBON _=	^P.-1?  INCHES  H20
PRE SSURE DRCP' "ACROSS"~PL ATES" -' ""  "f5 .09""lNCHES""H2'd	""
TOTAL  PRESSURE- DROP ACROSS  STAGES =     45.27  INCHES H20
                               221
-------
     S02 SORBER DESIGN
 RUN NUMBER
             TEST-24    DATE  7 27 71
 TCTAL CARBON RATE = 45.470  LBS/HR  _
"OUTLET CARBON LOADI "NG~~ =  O.T8375 TBS ATTD7LO~T7iRBON'
 HEIGHT OF CARBON/STAGE =    9.00  INCHES
 DIAMETER OF VESSEL_= i?_._0__INCHES__	|	
"CARBON USED~=~~    o.
 TOTAL GAS FLOW RATE =     17033.  SCFH
 INLET S02 CONCENTRATION  ^_ __  200°'_ ?P1
 INLET NO CONCENTRATION -  "   "	i'50T "PP"M~
 INLET 02 VOLUME FRACTION  =   0.0460     :
 INLET H20 VOLUME FRACTICN_=   0.1300  -:
"OUTLET""S02"CCNCENTRAT ION  =
                                    __
                                 ^OO.'P'PM"
TEMPERATURE =  275.0  DGG.  F
            S02
STAGE :
                   PPM
                                     "AC rO"'LO'AD"lNG' .......
                                  L8S ACIO/LB CARBON
1 •.. -:-
3
4
*>

6
: 7
8
0.10
',. 2000.
1758.
1500.
1231.
957, :

688 . ;. j:>
220.
200.0001
'.• •"• V s : o.i837
0.1589
0.1325
0. 1049
¥,:v.-:-../.-: .-.-vxaV; .;,-:'..•:-., 0.0769

;.:gi:x:|-: x;:.; ^-:^.ff:yr, ?:?T: ; : : . Q . 0 4 9 4
f E^Miilll^ll^lC: 0.0236
0.0014
0.0
 TOTAL CARBON REOU IRED_ =___   7 2_._9 4 ^I_NCH E S  ____     ___ _
"TOTAL STAGES REQUIREl)~ASSUMfNG 9.00 INCHES CAR~BW/ STAGE
                                                          ____
                                                          = 8.10"
 SPACE VELOCITY =
                      1586.  1/HR
 PRESSURE DROP ACROSS  CARBON  =;;
 PRESSURE DROP ^CRO'SS|]-AT_§S__=_
                    "
                                  36.47:  INCHES  H20
                                  18.23  INCHES  H20
 TOTAL PRESSURE DROP  ACROSS  STAGES =
                                         54.70  INCHES H2O
                          222
-------
      S02 SORBDR  DESIGN

 RUN NUMBER    TEST-25   DATE   7  27 71

 TOTAL CARBON  RATE = *1.*980_ LBS/HR
 OUTLET CARBON  LOADTNG~= "O'Tl"8375~H'S"~AC1 WLTfTTRBOW
 HhlGHT CF CARBON/STAGE =   9.00 INCHES
 DIAMETER OF V E S S EJL_ =_ 18 . 0 _INCHIES_^         	
"CARHON"USEDi •="•"   ~ o."~	*  '       ~"
 TCTAL GAS FLOW RATE =     16473. SCFH
 INLET S02 CONCENTRATION =    _j?000_.  PPM _
 INLFT NO "CONCbNTRAT ION""= '"	" " l50V "PPM':'~
 INLET 02 VOLUME  FRACTION =  0.0460    .;•'"•
 INLET 1120 VOLUME FRACTION =__0_.J3qO  _ ::;^
 OUlLliT S02 CONC'ENTRAtTON""^" " '   "2'66. ~P"P~M"

 TtMPERATURE =  300.0 DEG. F
'	  •	~s"o
     STAGE  . .
        2
        3
        8
        9
     0.72
;ONCENTRAf I'ON~" ""
PPM
•:• •;.; .2000.
1803.
1596.
1380.
115«,
0-3 C
^ ^ ^ *
716.
508.
319.
200.0C01
ACID LOAD ING" 	 ~" ~"
L8S ACJO/L8 CARBON :
' .0.1837 ./%••: :.'.
0.1636
0.1423
0.1202
0.0975 	
0 07^7
0.0522
0.0309
0.0115
0.0
 TOTAL 'CARBON'Rif"QUTREU~=      87.44 INCHES"
 TOTAL STAGES  REQUIRED ASSUMING  9.00 INCHES CARBON/STAGE = 9.72
 SPACE VELOCITY  =.;,;,. ' 1279.  1/HR; \;-,,:..:f.'-M;,.,::;,:V: : ;.,.^?i> •:,:;•.>.-

 PRESSURE DROP ACROSS CARCCN  ='    43.72 INCHES  H2Q1	;___:
"PRESSURE" DROP"' ACRCSS^P'LATES' =  " 21.86 INCHES  H2b"
 TOTAL PRESSURE  DROP ACROSS  STAGES =    65.58  INCHES H20
                             223
-------
              APPENDIX    A-10
REACTION RATE STUDIES FOR SULFUR GENERATION
       IN 1 INCH DIAMETER FIXED BED
                      224
-------
                                                                 RATE OF SULFU" GENERATION
                                                                       BENCH SCALE
                                                                                                       3  10 71
CO
Ul
- SG-72

  SPACE VELOCITY
~ I'-E^T GAS  CLCV.'
 ' *F:G"T  CF
                                     O.IOO'S^E Ofc /HI
                                  T£  =       233.00 SCC/MlN
                                   UNLCAC.-FD *      11.900 G-«S
                                                                    LOADED
                                                                                   15.00 CMS
              - INLET orBCE"jT  u2s  ,      30.000
                INLET "OLAR M2S  CONCENTRATION •
                INLET SJLFURIC ACI2 LOADING •
                                       0.42B571 MOLES H2S/MOLE  INERT  GAS
                                     0.206000 GYS H2S04/GM CARBON.
                FINAL OJTL£T  PERCENT  SULFUR LOADING CN CARBON  -       is,040
                FINAL C'JTL"*  SULFUR  LOADING ON CARBOA »        0.227 CMS S/GM CARSON
              ~ INITIAL TF.-'PERAT',-°E  =      2"'C.CO F
                wtxr-'jn' TEVOERATUPE  «      355.00 F
                FINAL TE^ERA-LRF  -       302.00 F
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CO
cc
oo
00
CO
00
00
00
00
00
00
00
00
00
00
CO
CO
00
CO
CO
oo
00
00
00
CO
oc
00
190345E 02 --UNUTES
                                                                                        M2504 LOADING
                                                                                        J3MS ACID/OK  C

                                                                                         0.206000E 00
                                                                                       ' 0.1S1530E CO
                                                                                         0.157061E CO
                                                                                         0.121500E 00
                                                                                         o.eea&boE-oi
                                                                                         C.6369eS£-Cl
                                                                                         0.507661E-01
                                                                                         0.3&5569E-2i
                                                                                         C.25352CE-C1
                                                                                         C.l6lfc!)6E-Ol
                                                                                         O.B66C67E-02
                                                                                         C.202475E-C2
                                                                                        -C.A21576E-02
                                                                                        -C.964649E-02
                                                                                        -0.14Q561E-C1
                                                                                        -C.1772b8E-Cl
                                                                                                       0.23561.-5C-C1
                                                                                                       0.2626b6E-Oi
                                                                                                       0.269716E-01
                                                                                                       0.315? JOE-Oi
                                                                                                       0.34E115E-01
                                                                                                       0.381C.J4E-01
                                                                                                       0.422512E-C1
                                                                                                      -C.470749E-C1
                                                                                                        • 50
                                                                                                      -0.656274E-;!
                                                                                                      -C.687628E-Oi
                                                                                                      -C.7i6c49E-01
                                                                                                      -0.7460S9E-C1
                                                                                                      -0.775269E-01
                                                                                                      -0.804479E-C1
                                                                                                      -0.8775C5E-0'.
                                                                                                                       RATE  ACIU
                                                                                                                       GX ACID/OM C-.XI.\.

                                                                                                                          O.OOOCOCt  00
-C.102»26:.-01
-0.9S865'-i-o2
-0.804'-l;>c-02
-C.613-'o»t-02
-0.509/74C-02
-0.408o6o--C2
 0.34- s2»c.-02
                                                                                                                         -0.302i:3tit-02
                                                                                                                         -0.24118^t-02
                                                                                                                         -0.19947 ^t-02
                                                                                                                         -0.167;9/;-02
                                                                                                                         -0.14605it-22
                                                                                                                         -0.124266C-02
                                                                                                            -0.16 /U9/L-02
                                                                                                            -0.16 I'j'S ^L-C2
                                                                                                             0.24iigjc.-02
                                                                                                            -0.241. feiL-02
                                                                                                           -0. 167^9 'L-02
                                                                                                           -0.16 /V9/S-02
                                                                                                           -0.16 '^9/c-02
                                                                                                           -0.l46C5i£-02
                                                                                                           •0. 146C5.C-C2
                                                                                                           -O.l46c5i--02
                                                                                                           -C.l46o5.t-C2
                                                                                                           -C.lfc6C-5iC.-OZ
                                                                                                           -0.i46C5.i-02
                  ;rF C- "Cli OECO'-'^OSiTION  =    -0.457S76E-02 AT    0.19C345E 02 MINUTES
                  vra*/;E =iTF OF ACID  0£CC"PCS IT I0\ UP TO ?C PERCENT ACID UTILIZATION  •
                                                                                            -0.931299E-02
-------
                                           	RATE OF SULFUK GENEKATION
                                                      BENCH SCALE
SG-?5
SPACF VELOCITY  =     0.116^37E  04  /HR
INEPT GAS FLOW  RATE  *       5SJO.OO SCC/"*IN
WEIGHT OF CARBONt  UNLOADED =       25.600  QMS
                                          LOADED
                  32.20 CMS
INLET PERCENT H2S  *       30.000
INLET MOLAR Has  CONCENTRATION  =
INLET SULFURIC ACID  LOADING  =
                           0.428571 VOLES H2S/MOLE INERT GAS
                         0.206000 GMS H2S04/GM CARBONt
FINAL OUTLET PERCENT  S'JLFUR  LOADING  ON  CARBON B      15.600
FINAL OUTLET SUL^U* LOADING  ON  CARBC\ »       0.196 GMS S/GM CARBON
INITIAL TEMPF9ATU9E »      '270.00  F		
MAXIMUM TFMPERATURF «      338.00  F
FINAL TEMPERATURE  =       318.oo F
                                                                            3 16 71
         PERCENT  H2S
                    PERCENT 502
 0.0
 2.0
 4.0
 6.0
 8.0
10.0
12.0
14.0
16.0
18.0
O.OOOOOOE
O.OOOOOOE
O.OOOOOOF
0.240000F
0.7600COF
0.148000F
0.20600CE
0.266000E
0.296000F
0.300000E
00
00
00
01
01
02
02
02 -'
02
02
O.OOOOOOE
	 O.OOOOOOE
O.OOCOOOE
U.'JUOOOOt
O.OOOOOOE
O.OOOOOOE
O.OOOOOOE
-- - C. OOOOOOE
O.COOOOOE
O.OOOOOOE
00
00
00
00
00
00
00
00
00
00
PERCENT C02
                                      O.OOOOOOE 00
                                   	O.OOOOOOE 00-
                                      0.OOOOOOE 00
                                      O.OOOOOOE 00
                                   	0.0000'JOE 'JO
                                      O.OOOOOOE 00
                                      O.OOOOi-'OE 00
                                   	OiOOOOUOE -JO
                                      O.OOOOOOE 00
                                      O.OOOOOOE 00
MOLAR CONC H2S
H2S04 LOADING
GMS ACI-/GM C
RATE
O.OOOOCOE 00
O.OOOOCOE 00
O.OOOOOOE 00
0.245901E-01
O.S22510E-01
0.173708E 00
0.259445E 00
0.362397E 00
0.420454E 00
0.428571E CO
0.2060JOE 00
0.1776&6E 00
0.1493/2E 00
0.1218 l£-01
0.7722 '3E-01
0.6322iSE-Ol
0.5544V2E-01
0.5299»2E-Ol
0.527270E-01
O.OOOCO-- 00
•»0«14i V6'^-01
-0. 14A ij6--<^-01
-0« 13i-!'41-'--01
-0«114-9?^-01
-C.84ictt^'--02
~0.55i:=-6-"--02
-0.21c-j9w^-02
-0«268i2*'t-c3
0.00^-Ovw 00
A+t* «f
                                     0.773 f-
-------
                                                     RATE OF SULFUR GENERATION
                                                           BENCH SCALE
     SG-2*

     SPACE VELOCITY  «     0.992250E 03 /HR
     INERT GAS  FLOW  RATE «       309.00 SCC/MIN
     WEIGHT OF  CARBON*  UNLOADED *      16.000 CMS
                       LOADED
                   20*00 CMS
      INLET PERCENT  H2S *       30.000
      INLET MOLAR  H2S CONCENTRATION »
      INLET SULFUR 1C ACID  LOADING *
        0*428571 MOLES H2S/MOLE INERT GAS
      0.206000 CMS H2S04/GM CARBONt
     FINAL OUTLET  PERCENT SULFUR LOADING ON CARBON »      18.400
     FINAL OUTLET  SULFUR LOADING ON CARBON *       0.229 GMS S/GM CARBON
     INITIAL  TEMPERATURE *      270.00 F     ~  -
     MAXIMUM  TEMPERATURE -      321.00 F
     FINAL TEMPERATURE »      303.00 F
                                                         3 11 71
ro
      TIME      PERCENT H2S
       0.0    O.OOOOOOE 00
       2.0    O.OOOOOOE 00
       4.0    0.1600COE 01
       6.0    0.440000E 01
       8.0    0.820000E 01
      10.0    0.114000E 02
      12.0    0.154QOOE 02
      14.0    0.186000E 02
      16.0    0.196000E 02
      19.0    0.2020COE 02
      21.0    0.212000E 02
      23.0    0.234000E 02
      26.0    0.256000E 02
      28.0    0.268000E 02
      31.0    0.284000E 02
      35.0    0.300000E 02
      37.0    0.300000E 02
 PERCENT S02
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOCOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
 PERCENT C02
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
O.OOOOOOE 00
MOLAR CONC H2S
  O.OOOOOOE 00
  O.OOOOOOE 00
  0.162601E-01
  0.460251E-01
  0.893246E-01
  0.128668E 00
  0.182033E 00
  0.228501E 00
  0.243781E 00
  0.253132E 00
  0.269035E 00
  0.305483E 00
  0.344086E 00
  0.366120E 00
  0.396643E 00
  0.428571E 00
  0.428571E 00
H2SC4 LOADING
GMS ACID/GM C
           00
           00
           00
           00
           00
0.2C6000E
0.181864E
0.158187E
0.1358C6E
O.U5482E
0.974853E-01
0.820988E-01
0.695234E-01
0.586866E-01
0.434718E-01
0.34Q397E-01
0.260817E-Q1
0.173145E-01
0.131771E-01
0.919110E-02
0.739333E-02
0.739333E-02
      ACID LOADING «    0.205999E-01 AT    0.248757E 02 MINUTES
      RATE OF ACID DECOMPOSITION «   -0.278624E-02 AT    0.2487S7E 02 MINUTES
      AVERAGE RATE OF ACID DECOMPOSITION UP TO 90 PERCENT ACID UTILIZATION »   -0.709168E-02
RATE ACID DECOMP.
CM ACID/GM C-MIN.

   O.OOOOOOE 00
  -0.12067SE-01
  -O.U6Q97t-Oi
                   -Q.844456E-02
                   -0.69419JE-Q2
                   -0.563J50E-02
                    C.449215t.-o2
                    0.34658 /t-32
                    0.237690E-02
                    C.175647E-02
                    O.OOOOOi-E  OC
                    O.OOOOOOE  00
-------
                                                                     RATE OF SULFUR GENERATION
                                                                           BENCH SCALE
                  -  SG-23

                     SPACF  VELOCITY *    C.100654E Oft  /MR
                  -  :*E»T  GAS FLOW 9ATIT *       155.00  SCC/vlN
                     v.'FK'MT Cc CARBON. UNLOADED  *        7.9»0 G«S
                                                                        LOADED
                                                                                       10.00 CMS
                     INLET ocqcci,T _2s -      30.COO            ••  —	•-••  •-  	  --- •
                     INLET WOLAS H2S CONCENTRATION =    0.428571  «OLES H2S/MOLE INERT GAS
                     INLET SULPU"?IC ACID LOADING "    0.206000  GKS M2S04/GM  CARBON.

                     PP.AL CUTLET = E = CE',. SULF'JS LOADING ON  CARBON «       20.720
                     FI'.AL 0'JTL£T S'JL^L". LOADING ON CARBON «       0.260 CMS S/GM CARB3N
                     INITIAL TE"P£RAT'J'S »      270.00  F      '   	— -----
                     MAXlvu* TE''3E'?ATU'fr =      330.CO  F
                     FINAL TEvt>ERAT-j=£ •      320.OC F
           3 10 71
OO
TIVE
0.0
2.0 •
4.0
e.o
10.0 --•
17.0
14.0
16.0
18.0
20.0 .
2?.0
24.0
26.0
2? . 0
3C.O
32.0
34,0 -
n f ft
Jc . 0
3f .0
40.0 "•
44.0
46.0
-50. 0 -
53.0
56.0
'59.0 —
62.0
65.0
PERCENT H2S
O.OOOOOOE 00
O.tJOCOOE CO
0.1B4COOE 02
C.192000E 02
0.192COIE C2
0.1 92 CO
c.is-cc
C. 17400
0.15SCC
o.iseoo
C.:960U
c.2i-;:
C * 2 1 6 0 Z
*"" 2 1 ** " n
0.234::
0.214C3
C9 "a "• ^ •*
. / 1 -J - *•
0.256"
0.2361C
0.23600
c.233:o
0.24-CC
0.25230
E 02
E 02
E S2
E 02
E 02
E C2
E C2
E 02
c f\2
E 02
E 02
E C2
r ^9
. u£
c 02
E C2
E 32
E C2
E C2
E 02
C.263C30F 02
C.270COCF C2
C.274rCDE 02
0.2">4COOE 02
PERCENT 502
O.OOOOOOE
- O.C30300E
O.OOOOOCE
0.000003E
0.030000E
O.OCOOOOE
O.OOOOCCE
O.OOCCOCE
O.OCC30CE
3.3C3C30E
c.occ3":oE
0.303C30E
C.303700E
f* r* ^, n — ft ^i —
S.SOO:OCE
O.C030COE
n o .-\ • ,~\ A '\ c
C . u w ^ o u v ^
/> »>A«^/N^-^
'. • u J ^ J J w'C
3. 003CC CE
C< 00><003E
O.OO;OOOE
O.OCCOOCE
- G.503033E
D.COCOOC'E
" O.OOOOOOE
OlOSS'OCc
:.300000£
00
00
00
00
CO
00
00
00
00
'.'3
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00
CO
r>"
00
30
00
AH
uu
00
S3"
00
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CO
00
00
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PERCENT C02 MOLAR CONC H2S
0.
• '0.
0.
COOOOOE
OOOO'JCE-
COOOOOE
O.OOOOOOE
	 — o.
0.
0.
	 o.
0.
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0.
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0.
0.
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0.
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0.
— •• — o.
0.
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	 o.
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3 .
0.
0.
0.
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3000C3E
COCC-JOE
OOCOOOE
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COC303E
030CUOE
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C300COE
030CCOE
OOOO'JOE
030030E
,T"Jf> "* -'* AF
U JU— \- v/C
OOOOwOE
OOCCiOE
OOCOCOE
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OOOOOOE
OCOOJCE
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OOOOuOE
OOOOOOE
00
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00
00
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00
00
03 	
00
00
oo 	
00
00
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00
00
co 	
o *\
•J U
00
co 	 •
00
CO
00
30
CO
00
00
00
3.000COOE
00
0.401606E-C2
0.225490E
0.237623E
0.237623E
0.237623E
0.225490E
C.210S53E
0.21951IE
0.231527E
0.243781E
C.2722-64E
C.278772E
0.278772E
0.256281E
0.272264E
0.27B772E
07Q fc 7 1 1 ~
*t?D 'WA^
0.344086E
0.308900E
0.33890CE
0.312335E
0.329787E
0.336b98E
0.351351E
0.369S63E
0.377410E
0.37741CE
00
00
CO
00
CO
CO
00
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03
00
00
CO
00
00
00 ~
nf>
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00
30
00
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CO
00
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00
00
oc
H2S04 LOADING
G"S ACIO/GX C
0.206000E 00
0.131716E CC
0.163854E OC
0.1414^4? 00
0.1305;>4E 00
0.1196B5E 00
0.1084/OE 00
0.964S75E-01
3.843343J-01
0.727762E-01
0.619063E-01
0.522COCE-31
0.434!, ,'SE-Ol
C .3496C3E— 01
0.257529E-01
O.l64403£-C'i
0.77279CE-32 "
»n 5~5Tri.c-.ra
O titJc i L*»!l v .*
-0.632314E-C2
-0.121438E-01
-0.257662E-D1
-0.3Z4327E-C1
-0.44722sE-Oi
—0 .52fi50oE— 01
-0.6006"4E-C1
-0.65c:676E-Oi
-0<"355£3E-Ol
-C.74926SE-C1
RATE Ado ^tCOi'.J.
G.»; ACID/CM C-XJ,,.
O.CCO^OOt 00
" -0.12063^-01
-0.57S014L-C2
— 0.54-3'»7*t-c2
-0.54J47>L-02
-0.54347*^-02
-0.576vl«-i-02
-0. 62024411-02
-0.59'-02 = t-02
-3.56oo3it-02
-0.526» = -.t-02
-0.444t)8pt-02
-C.426J6it-C2
™fi ii. 7 A *ftir"*O?
-o!490i7>£-02
-C.444c8it.-02
-0.426;6i--C2
-0.24U464L-02
" -O.J4C,uC'l--02
-0. J4060'£.-02
-3.333=3.^-32
-C.2oll6At-C2
-0.260>2»t-32
-0.219 '3at-02
-C.16709/i-02
-C.l4ibl;t-32
-3.l4iifclac-C2
                    ACID  LOADING =    C.205999E-01 'AT     0.311104E  02 MI.NUTES
                    PATE  Oc  «CID :ECOVCOSIT!ON »   -C.465116E-02  AT    0.31110'E 02 MINUTES
                    AVE°AGE  ^ATE Cc ACJ3 Drr:'-'POSIT lOV U°  TO  90 PERCcNT"ACIO UTIT.IZA" ION =
-0.571293E-02
-------
                                                                     RATE OF SULFUR  GENERATION
                                                                      -	 BENCH SCALE
                    SS-?1

                    SPACE VELOCITY »    0.10<,59BE C
K>
VQ
Tf-'E
0.0
?.o
''.0
6.0
P. 5
11.0
13.0
15.0
1 7 . 0 - - -
19.0
21.0
22.0 •
25.0
?7.C
29.0
31.0
33.0
• 35.3
37.3
30. c
^ 1 • C
**"'*«
51.3

5"". 3
• c c . ^
61.0
O.OOOOOOE
0.1<>OOCOC
0.19<.COCF
C.2C630CE
C.2130Cr.F
0. 2?**CCOE
C.216000E
0.2C2300F
0.19»COO?
0.2C2033F.
C'.2?7330F
0.223333F
C.23S003E
0,2'T-030E
0.2'.B303E
C.2'-53C';E
3.25'-f)0'JE
0.203003E
C.2620COF
3.2h?OJ'-F
3.262"00C
c!2700^F
?:2~o3lE
C.2?6000F
C.290000F
C.2^^000r
0 . 3 ? 0 0 C '• E
OC
02
02
02
02
02
C2
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02
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02
C2
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02
02
02
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02
32
02
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32
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PERCENT 502
0.
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0
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PERCENT C02 MOLAR CONC M2S
.OOOOOOE
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0.162790E
0«2'>069'tE
0.259i't5E
0.265822E
0.288659E
0.275510E
0.253132E
0.2'-6BB2E
0.253132E
0.2B2051E
0.295336E
0.3C3903E
0.322751E
0.329787E
0.329787E
0.3<.C''82E
0.3'.770SE
0.355313E
0.355C13E
0.355013E
C.369863E
C.369663E
0.377410E
0.377410E
0.3950'tlE
0.392757E
0.403560E
O.^OE'-SOE
0.^16A33E
3.^28571£
O.'.?f 571E
00
00
00
oo
00
00
00
00
00
03
00
00
00
00
00
00
00
00
00
00
00
CO
03
00
00
00
03
oc
00
cc
CO
00
                                                    M2S04 LOADING
                                                    GMS ACI3/GM C

                                                     0.2063JOE 00
                                                     0.165L-02


                                                                       -0.1511'3'.t.-o2
                                                                                                                                    wGwE. 00
                                                                                                                                    JO.- oo
                       :3 LO'Di-.r, =     3.205990^-31 />r    c.<-662ieE 32 «INUTES
                        E C= ;C1D SECCVDOS: r!0\ =   -0.155761E-02 AT     0.<»66218E  02  MINUTES
                       E'AJE si'r OF  ACIC  OrCO-'''»OSlTiO>: u-> TO 90 PERCENT  ACID UTILIZATION «
                                         -0.373*63E-C2
-------
                                                           KATE OF SULFUR GENERATION
                                                                 BtNCH SCALE
                                     1 71
           SG-<»3
           SPACt VELCClf'Y =   " "b". 309191E  03 /HR
           INERT GAS FLOW RATE =      7064.00 SCC/MIN
           WEIGHT UF CARBONi UNLOADED =     1179.000 GMS
LOADED
1486.00 GHS
           INLET PERCENT H2S =       29.700
           INL§T_MOL_AR H2S CONCENTRATION  =     0.422475 MOLES H2S/MQLE INERT GAS
           INLET suLfURIC ACIO LOADING""«     o.i366oo GMS H2S04/GM~CARBUN,

           5.INAL OUTLET PF.RCENT  SULFUR  LOADING ON CARBON =	21.080	
          "FINAL OUTLET SULFU«" LOADING  ON CARBON = "     0.266 GMS  S/GM CARBON
           INITIAL TEMPEKATURE =      290.00 F
           MAXIMUM TEMPERATURE =      3*0j-?ll_f	
           FINAL TEMPERATURE =     ""320^00 >    .            "      ~      ~~
to
U>
o
TIME
0.0
10.0
20.0
30.0
40.0
50.0
60.0
70. 0
60.0
90.0
100.0
110.0
ACID
RATE
PERCENT H2S
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.270000E 02
0.290000E 02
0.29^0006 02
0.297000E 02
0.280000E 02
PERCENT S02 PERCENT C02
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
LOADING = 0.136000E-01 AT
OF ACID DECOMPOSITION = -0.
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.331655E 02 MINUTES
3690596-02 AT 0.331655E
MOLAR CONC H2S
0.0
0..0
0.0
0.0
0.0
0.0
0.0
0.369863E 00
0.40B451E 00
0.
-------
                                                          RATE OF SULFUR GENERATION
                                                                BENCH SCALE
          SG-44

          "SPACE  VELOCITY  =    0.309191E 03 /HR~	
          INERT  GAS  FLOW  RATE  =     7064.00 SCC/KIN
          WEIGHT  OF  CARBON,  UNLOADED =    1179.000 CMS
    LOADED
                               1486.00 CMS
           INLET  PERCENT  H2S =      29.000
           INLET  MOLAR  H2S CONCENTRAT ION_ =
           INLET  SULFURIC ACIO LOADING =
 __ 0.408451  MOLES H2S/MOLE _
"0.136000 CMS H2S04/GM CARBON,
                   GAS
                                      9  2 71
          FINAL  OUTLET  PERCENT SULFUR LOADING ON CARBON
          FINAL  OUTLET  SULFUR LOADING"ON CARBON =
          INITIAL  TEMPERATURE =      250.00 F
          _MAXIMUM  TEMPERATURE =	355.00 JF	
          FINAL  TEMPERATURE =""  " 310".00 F  "
       22.040
0.278 GMS S/GM CARBON
           THE  "    PERCENf H2S
to
u>
             0.0  "  0.0
            10.0    0.150000E 01
          _20.0	0.130000E_01
            30~.0    6.930000E" 01 "
            40.0    O.ll^>000t 02
            50.0    0.145000E 02
          ""60.0    0.270000E 02
            70.0    0.285COOE 02
            80.0    0.290000E 02
           "90.0 "   0.293000E 02~
           100.0    0.290000E 02
           110.0    0.29COOOE 02
PERCENT 502
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
OOOE-01 AT 0.387428E
ION = -0.246304E-02 AT
PERCENT C02
0.0
0.0
0.0
0.0
0.0
0.0
0.0
o.o :•-'
0.0
0.0
0.0
0.0
02 MINUTES
0.387428E
MOLAR CONC H2S
0.0
0.152284E-01
OM31712E-01
0.102536E 00
0.129943E 00
0.169591E 00
0.369863E 00
0.398601E 00
0.408451E 00
0.414427E 00
0.408451E 00
0.408451E 00
02 MINUTES
H2
GM

^i
»
— i
-l
-l
-i
— i

                                     H2S04 LOADING
                                     GMS ACID/GM C
                                                                         ~ACI"D OECOMP".
                                                                    GM ACID/GM C-KIN.
                                       0.100984E 00
                                       0.665441E-01
                                       0.359172E"-01
                                       0.103907E-01
                                      -0.122069E-01
                                      -6.243253E-Or
                                      -0.264410E-01
                                      1°-JL26 871 2E- 0 1_
                                      -0.266lOiE-01
                                      -0.263491E-01
                                      -0.263491E-01
                                                                        0.0
                                                                       -0.343504E-02
                                                                       -0.345301E-02
                                                                       -0.2672366-02"
                                                                       -0.243294E-02
                                                                       -0.208659E-02
           ACID LOADING =    0.:
           RATE OF ACIO DECOKPO!	  		          	
          "AVERAGE RATE OF ACID DECOKPO'SITION UP TO 96 PERCENf ACID UTILIZATION =   -o.302348E-02
                                                                        0.860399E-04
                                                                        0.0
                                                                        6.52205~9E-64~
                                                                        0.0
                                                                        0.0
-------
OJ
                                                           RATE  OF  SULFUR GENERATION
                                                                 BENCH SCALE
                                       9   2  71
          SG-45
          SPACE VELOCITY  =     0.528427E 03~~/H~S
          INERT GAS  FLOW  RATE  =    11827.00 SCC/MIN
         JUL!GHT_PF"  CARbO.M,  UNLOADED =    1151 ..Oqo. QMS
    LOADED
•1451.00 CMS
          INLET PERCENT  H2S =      30.000
          INLE_L_MOLAR JH2S  CONCENTRATION^	0.428571  MOL|S_M2S/MCIL£ INERJ GAS
          INLET SULFUR 1C ACID' LOAD ING" =    O."l3600~0  GMS~ H2S04/GM CARBON",
         JF INAL_ OUTLET _f>ERCENT SULFUR LOADING DN CARBON  «
          FINAL OUTLET  SULFUK LOADING ON CAiRBON =
          INITIAL TEMPERATURE =      260.00 F
         _MAXIMUM TEHPERATURE_=_	315.00_F	
          FINAL TEMPEKATURE  =      300.0b"F
       20.400
0.257 GMS S/GM CARBON
TIME
" b.o
10.0
20.0
30.0
40.0
50.0
ACID
*ATE
PERCENT H2S
0.0
0.100000E 01
0.185000E 02
0.270000E 02
0.300000E 02
0.300000E 02
PERCENT S02
0 = 0
0.0
0.0
0.0
0.0
0.0
LOADING = 0.136000E-01 AT 0.2641306
CF ACID DECOMPOSITION = -0.164731 E-02 AT
PERCENT CC2
0.0
o.o .' ;:,. ,
0.0 -• •"••- •••-.
0.0
0.0
0.0
02 MINUTES
0.264130E
MOLAR CONC H2S
0.0
0.101010E-01
0.226994E 00
0.369863E 00
0.428571E 00
0.428571E 00
02 MINUTES
H2S04 LOADING
GMS ACID/GM C
0.136000E 00
0.725501E-01
0.261037E-01
0.660623E-02
0.220852E-02
0.220852E-02

RATE ACID OECOMP.
GM ACID/GM C-MIN.
0.0
-0.626933E-02
-0.301994E-02
-0.879543E-03
0.0
0.0

          AVERAGE RATE  OF^ACID DECOMPOSITION UP TO 90  PERCENT  ACID UTILIZATION
                            -0.391689E-02
-------
                                                           RATE OF SULFUR GENERATION
                                                                 BENCH SCALE
           SG-46
           SPACE VELOCITY'S     o.930io7E 02 YHR	""
           INERT GAS FLOW  RATE  =      2392.00 SCC/MIN
           HEIGHT OF CARBON,  UNLOADED =    1124.000 CMS
                  LOADED
1417.00 CMS
           INLET PERCENT  H2S  =       18.000
           JNLET MOLAR  H2S  CONCENTRATION =_
           INLET SULFURIC ACID  lOADING" ="
_ °-2A9!1.2  MOLES  H2S/MOLE JNERT_GAS_
0.136000  GMS  H2S04/GM CARBON,
           FJNAL OUTLET  PERCENT  SULFUR k°ADI_NG_ ON CAR30N
           FINAL'OUTLET  SULFUR LOADI.NG'ON CARBON =
           INITIAL  TEMPERATURE =      255.00 F
           MAXIMUM  TEMPERATURE =	3
-------
                                                          RATE OF SULFUR GENERATION

                                                                BtNCH SCALE
                                                                                        1 71
          SG-47


          SPACE  VELOCITY =    0.7749276 03 /HR
          INERT  GAS FLOW RATE =    16584.00 SCC/MIN

          _*l£iGHl_UF CAR3QNt_UNLpADEi}_5	1126.000 CMS
                                                   LOAD£0
1419.00 'CMS
           INLET  PERCENT H2S =      27.300

           INLET  HULAR H2S CONCENTRATION =
           INLET  SULFURIC ACID LOADING =
                                    0.375516 HOLES H2S/HQLE  INERT GAS
                                  0.136000 &MS H2SO4/GM CARBON.
JLINAL__OUTLET_ PERCENT SULFUR LOADING ON CARBON
 FINAL OUTLET "SULFUR LOADING ON CARBON =
 INITIAL TEMPERATURE =      250.00 f
_MAXIMUM JLEMPERATURE_^	385.00 F	
 FINAL TEMPERATURE =      310.00 F
                                                                20.44Q
                                                         0.258 GMS S/GM CARBON
U>
TIME
0.0
10.0
_ 20.0
30.0
40.0
50.0
PERCENT H2S
0
0
0
0
0
0
.0
. 182000E
.Z27000E
.260000E
.266000E
.273COOE
02
02
02
02
02 _.
PERCENT S02
0
0
0
0
0
0
.0 ,
. 0
.0 . . ...:.;,-. .
.0
.0
.0
PERCENT C02
0
0
0
0
0
0
.0 ;
.0 :••£-. ..::••-:;•
.0 , ,.-;^"-. ••::"'
.0
.0
.0
MOLAR CONG H2S
0.0
0.222494E
0.293661E
0.351351E
0.362398E
0^3755166
00
00
00
00
00
H2S04 LOADING RATE ACIt) iJECOKP.
GMS ACID/GM,C GM ACID/GC C-KIN.
0.136000E 00
0.792515E-01 '•;
i0.54.0331E-01
0.426499E-01
0.386470E-01
0.372385E-C1
0.0
-0.328595E-02
-0.175773E-02
-0.518fc98E-03
-0.281692E-03
0.0
-------
                                                           RATE OF SULFDK GENERATION
                                                                 BENCH SCALE
                                                    9  2 71
           SG-48
U>
           SPACE VELOCITY  =     0.101530E  04 /HR
           INERT GAS FLOW  RATE  =     22383.00 SCC/KIN
           •.EIGHT OF CARBON,  UNLOADED *     1134.000 CMS
                 LOADED  -
1429.00 GMS
           INLET PERCENT H2S  =       33.800
           INLET'MOLAR H2S  CONCENTRATION f
           INLET "SULFURIC AC 10  LOADING ~="
_ 0.510574 HOLES H2S/MOLE  INERT  GAS
0.136000 GMS H2S04/GM CARBON,"
           FINAL OUTLET  PERCENTJSULFUR  LOADING ON CARBON =
           FINAL OUTLET  SULFUR LOADING"ON CARbON =
           INITIAL TEMPERATURE =       250.00 F
           MAXIMUM TEMPERATURE, f	385.00_F	
           FINAL TEMPERATURE  = ~    290.~00 F
                     19.080
             0.240  GMS  S/GM  CARSON
           TIME
             0.0
             10.0
PERCENT H2S
0.0
0.219000E 02
0.324000E 02
PERCENT
0.0
0.0
0.0
0.338000E 02 0.0
IING = 0.1360COE-01 AT
S02 PERCENT C02
0.0 V
0.0
0.0
0.0
0.142038E 02 MINUTES
MOLAR CONC H2S
0.0
0.280410E 00
0.479290E 00
O.510574E 00
H2S04 LOADING RATE
GMS ACID/GM C GM I
0.136000E 00
0.294148E-01 ' -
-0.820515E-02 ' -
-0. 127066E-01
                                                                    RATE  AC'ID DECOMP.
                                                                    GM  ACID/GM C-MIN.
             30.0
            RATE  OF  ACID DECOMPOSITION =   -0.421767E-02 AT    0.142036E 02 MINUTES
            AVERAGE  RATE OF ACID DECOMPOSITION UP TO 90 PERCENT ACID UTILIZATION =   -0.591159E-02
                                                                        0.0
                                                                      -0.662369E-02
                                                                      -0.900292E-03
                                                                        0.6
-------
                                                         RATE  OF  SULFUR  GENERATION
                                                               BENCH  SCALE
                                                   9  2 71
         SG-49
         SPACE VELOCITY =    0.181932E 03  /HR
         INERT GAS FLOW RATE =      2*32.00 SCC/MIN
         WEIGHT OF CARBQNt UNLOADED =     1118.000 CMS
                 LOADED
1409.00 GKS
         INLET PERCENT H2S =       57.000
         INLET MOLAR H2S CONCENTRAJION_*_
        "INLET SULF-URIC ACID LOADING  =
  1.325531 MOLES H2S/HOLE INERT GAS
0.136000 GMS H2SOWGH CAROON,
        _fJNAL_OUTLeT _PE_RCENT SULFUR. LOADING  ON  CARBON
         FINAL OUTLET SULFUR LOADING  ON CARBON =
         INITIAL TEMPERATURE =       250.00 F
         MAXIMUM TEMPERATURE 5	385.00 J:	
         FINAL TEMPERATURE =      275.00 F
                    16.360
             0.206 GMS S/GM CARBON
U>
         TIME
           0.0
          10.0
         _2p.«P_
          30.0
          38.0
         AVERAG!
PERCENT H2S PERCENT S02
0.0 '-'-' 0.0
0.0 0.0
0.220000E 02 0.0 .
0.325000E 02 0.0
0.<»50000E 02 0.0
PERCENT C02
0.0
0.0 :
o.o ;•'...-. .'•;
0.0
0.0
MOLAR CONC H2S
0.0
0.0
0.262051E 00
0.481481E 00
0.818182E 00
H2S04 LOADING
GMS ACID.'GM C
0.136000E 00
0.939578E-01
0.56388^E-01
0« 26
-------
                                                          RATE OF SULFUR GENERATION
                                                                HtNCH SCALt
                                                                                                   2  71
          SG-51

          SPACE VELOCITY  =     0.105J47E  03 /HR
          INFRF r,AS FLOW  KATE  =      2446.00 SCC/MIN
          ViblGHT OF tARBONt  UNLOADED =     1194.000 GMS
                                                    LOADfcO
_L505. 00 _GMS	
          INLET PERCENT  H2S  -       34.500
          JNLET MOLAR  H2S  CONCENTRATION =
          INLET SULF4JRIC ACID  LOADING =
                                    0.526718  MOLES  H2S/MOLE  INERT GAS
                                  0.136000 GMS  H2S04/GM  CARBONf
_FJNAL_pUTLET PERCENT SULFUR LOADING ON CARBON  =	13^840
 FINAL OUTLE'T"SULFUR" LOADING ON CAR"BON =
 INITIAL TEMPERATURE =      235.00 f
"F INAL TEMPERATURE"~»      2io.Fo "F"   ~  ~~
                                                         0.174 GMS S/GM CARBON
LO
TIME
0.0
10.0
20.0
30.0
40.0
50.0
60.0
: 70.0
80.0
90.0
100.0
110. 0
120.0
130.0
140.0
~"ibo.o
160.0
170.0
IBO.O
190.0
200.0
210.0
PERCENT H2S
0.0
0.0
0.0
OvO
0*0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.540000E 01
0.188000E 02
0.235000E 02
0.360000E 02
0.310000E 02
0.345000E 02
0.345000E 02
0.345000E 02
PERCENT S02
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0 __
0.0
0.0
0.0
0.0
0.0
0.0
0.0
PER(
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
ENT C02 MOLAR CONC H2S
0.0
. •::-•-;,:•'•-.. ;- 0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.570825E-01
0.231527E 00
0.307190E 00
0.562500E 00
0.449275E 00
0.526718E 00
0.526718E 00
0.526718E 00
INUTES
H2S04 LOADING
GMS ACIU/GM C
0.136000E 00
0.120268E 00
0.104536E 00
0.888035E-01
0.730713E-01
0.573392E-01
0.416071E-01
0.256749E-01
0.101428E-01
-0.558928E-02
-0.213214E-01
-0. 370535E-01
-0.527856E-01
-0.685177E-01
-0.833973E-01
-0.948193E-01
-0.1025C6E 00
-0.105250E 00
-0.105872E 00
-0.1G7029E 00
-0. 107029E 00
-6.107029E 00
RATE ACID OECOMP
GM ACID/GM C-MIN
0.0
-0.157J21E-02
-0.157321E-02
-0.157321E-02
-0.157321E-02
-0.157321E-02
-0.157321E-02
-0.157321E-02
-0.157321E-02
-0.157321E-02
-0.157321E-02
-0.157321E-02
-0.157321E-02
-0.157321E-02
-0.140272E-02
-0.881682E-03
-0.655691E-03
0. 106P76E-03
-0.231306E-03
0.0
0.0
" 0.0 "
           ACID LOADING =    0.136000E-01 AT	0.77802'>E 0;
           RATE OF ACID DECOMPOSITION - " -0. 1573^2IE-02 AT    0.778025E 02 MIMUTES
           AVERAGE RATE OF ACID UECtHPOS1TIUN UP TO 90 PERCENT ACID UTILIZATION *   -0.157321E-02
-------
         APPENDIX    A-11





SULFUR GENERATION EXPERIMENTAL DATA
                 238
-------
           -'OS-.! SuLJTJr. AMD SC-2 AZ^IYSES 01C  CAKBGN
             AS A FU:::YI.;IC D? IBS ?cs nux DSC-?
             / "•• O ~~ a TI   >   — .	•• „. -     .    -H  -•  _ _ _ \
             Vc2>  F fc.t   >o".; -^S ar.^.    0  -j  r.C;
IOTA.L SUIFuK AHD S02 AKA.LYSES  ON CARBON
  AS A FUuCIIOS OF SIK3 FOR Hull 3SG-8
  ( 325°? s.t  1C % H2S and   0 % H20)
i
i
Elapsed Ti.-e ,
=in. 'IOC
Total Sulfur, j SOg Analysis, * 1
^ ! Its. S02/100 TDS. C
C j 5-3 i 14.63
r - ' ' "• -, -, i
C . ~ ' ; - i-
! ?'-• ; ^-3 i 17.6
i;c

n 0 r
7-6
7.2
18.2
16.4
i 15-' 3.5 i 13-95
: 175 : C.4
• ^ r
235 9-6
to
U)
VO




260
230
~-'0
330
^--^
;.cu
390
425
450
1^90
1
9-1
9-7
9-4
1C. 4
11.8
10.5
11-5
—
—
12.21
11.18
9-4
8.56
7.5
6.4
5-52
^-75
4.1
3-56
3-12
2-95
*• Meaz-orei SO; evolution oy H202  corubb:r.g when careen
  heated  LO 1000°F
Elapsed Tice,
tain. /ICO
0
20
1*0
60
30
100
120
iko "
160
180
200
220
21)0
260
280
300
320
3l+0
360
380
ItOC
420
1*40
1*60
1)80
500
Total Sulfur,
%
6.48
7.40
8.00
7-92
8.44
8.72
9.12
9-76
9.80
9-6
10.04
10.48
n.32
11.48
3J..68
11.96
12.4
12.60
13.08
11.6
13.4
13.3
13-68
13.4
13.96
14.52
S02 Analysis,
Ibs. SOp/100 Ibs. C
14.77
17-53
19-57
19-36
16.95
16.00
14.38
13-75
12.85
11.26
9-93
9-96
7.80
6.46
5-54
5-19
4.75
3-73
2.94
3-27
3-03
2.82
2.64
1.54
2.27
2.73
-------
                    Cr-l:-L  S'Jui?. >.;._/  S02 AlilYSSS C"..'  CA.KECii

                     AS A JLI;CIIO:; o?  II:-E ?CR ?.~j~.\ rs^-9
15
                                                  0 •; X2C)
TOTAL SULFUR AKD S02 ANALYSES  OK CARBON

  AS A FUNCTION CF TE-E FOR ROT DSG-10


  ( 325 °F at 20.8$ HgS and   0  $ E2o)
to
4>
O
-in. /IOC
.

-
*"
1 ^
\ '-'
; 55
75
95
•» -, c
I ^-*>
i i>5
1 175
200
220
260
520
550
275
4oo
425
450
475
500
Tccal Sulfur,


•7 " -
I . v,'^
7.&0
S.32
8.08
9.c4
9.16
9-88
10.20
1C. -2
10.52
12.0
12.76
13-60
14.04
14.23
14.08
14.60
14.52
14.60
14.76
15.20
SCp Analysis,
Its. 30? ICO Its. C


** — r^7
17.4
1S.T3
16.28
16.96
14.48
12-73
12.53
11.04
9-73
8.57
4.47
3-39
3.70
3-13
2.98
2.58
2.97
2.96
2.64
3-06
Elapsed. Tiae ,
min . /ICO
0
10
30
50
75
100
225
150
175
200
225
250
275
300
325
350
375
400
425
450
475
500
Total Sulfur,
*
6.0
7-7
8.5
8.7
9-8
9-6
io.4
11.4
11.5
12.5
13.5
13-7
14.3
15-3
14.0
15.4
14.1
14.9
15-2
15-4
14.6
14.8
302 Analysis
Ibs. S02/100 Ibs. C

15-1
18.3
19-6
17.5
13-9
11.5
9-26
9-14
8.02
6.64
5-23
3-97
3-58
2.70
2.76
2.35
2.S3
2.38
2.68
2.65
2.39
-------

T03VL SUJVFUR AM) 302 AIK.LYSSS CN CA.B30N
  AS A ?-JI\CTIOH OF 3II/S FO?. EUII DSC-12

  ( 315°?  at  5-3$ H2S and  30 %

Slapsed Ti™e, ! -CTs.1 Sulfur, ZC-.- Analysis
„-•„ '"0'^ ' ;'- ' "v>s. SCs'lCO loo. C
• ; t
• >-r - r * - : -,
1 <• , 1 - .- - — * —
ic ; E.S: i 18.76

*."'
! =z
i

11-1
O.lj
15.4
1C . 12 1- - 5
ic. :s
12.43 1
11. f-' 11-42
I —^ , 12. oO i 7-~~

t
150
175
N> 1 20C
+> 225
13-32
14.20
15.20
15.44
1-1 2?0 | 16. vO
6.69
5-36
3.92
2.86
2,50
275 I 15-50 2.765



325 16 . c
350
375
I }. -^f^
1 425
450


475
500
16.64
16.46
16.76
17.00
16.04
17.20
16.46
2.449
2.248
2.42
6.49
2.41
2.65
2.175
2.53
Elapsed Time,
min./lOC
0
15
22
to
70
100
125
150
200
250
275
300
Total Sulfur.
%
6.4
6.60
8.4
7.03
7-52
7-2
7-36
7-^
7-96
8.0
8.20
7-84
SOg Analysis
IDS. SC2/100 its. C
16.08
	
17.30
16.8
17.04
17.34
17.48
17-74
18.8
17.28
17.48
16.80
-------
TOTAL SULFIG. AID C02 Al^LYSES 01' CA.-iQ:


  i 51:;F  it  5-3f; H23 ar.d  20 •;', >;2c)
TOTAL SUEF^ A:E 302 AIALYSES  oic CAI^D
  AS A FUHCTICH 0? TBS FOR RUN  DSC-i

              5-3-5 H23 and   1C£ :-I2o)

£i;in!/icr'
cf
! :
' C j 6.6t
1C ! c.20
S02 Analysj.3
Its. SC2/1CO 1'os. C

15.5
17-1
JO ! 7 .2,6 : lD.92

50 i 7-20
! 75 ! 7-12
I ICC ! c.OO
17-73
17.6
17. 6t
I :^r : 7--o ! 17.25
; 150

"75
N3 2CO
-P-
N>

225
2C0
• ~-~"^
! ~~^
''. 350


too
't25
•7 V" ' 17 £8
j . ~~r ^- 1 . '-'^
3. CO
7-2t
3.32
S.co
o.bO
17-99
17-73
17.93
17.9
15.68
? 0- ! -'5.68
8.12
8.20
6.8t
15- 3t
It. 32
It. 57
Elapsed Tims .
nin./100
0
25
ko
6c
75
100
125
150
175
200
225
250
275
300
325
350
375
too
1*25
t50
t75
500
Total Sulfur,
",j
(• ^

7.00
7.2t
7.12
7.52
7-36
7-12
6.96
7.2t
8.0
7.2
9-28
8.60
6.8
8.60
9.00
8.92
7-6t
7-72
7.36
8.68
9-6
S02 Analysis
Its. SOa/100 Its. C
18.15
l'^92
16.63
15. t3
20.3
21.1
18.0
17-3
17.63
18.2
15.65
15.2
13-35
13. 7t
Ik.kd
12.76
10.83
10.6
9-96
9-26
9-39
8.t7
-------
                    TOTAL SULFUR AJSD SC>2 ANALYSES OS CAHBOH
                      AS A FUNCTION OF TIM3 FOR HUN DSG-15
                                                                      TOTAL SULFUH AND SOg ANALYSES ON  CARBON
                                                                        AS A FUNCTION OF THE FOR RUN DSG-16
(275 °F at
                                       E23 and   0 %
(  275°F at
and
U>
| Zlapsed Tine,
nin./lOO
I 	 ,
0
15
30
50
75
100
125
15C
175
200
250
275
300
350
375
VOG
1*25
1*50
!*75
500
Total Sulfur,
/-'
6.12
e.kk
6.51
7.62
7.68
7.72
8.00
8.08
8.96
9-00
8.2
9.0
9.2
10.0
10.1
11.0
11.2
_11.2
, "l0.8
11.1
502 Analysis ,
los. SCto/'lCO Ibs. C
1
11*. 1
15-5
16.3
15-8
lit. 5
U.2
13.7
12.9
12.4
™
12.05
11.29
10.12
9.32
S.29
9.12
7-51
6.90
6.60
7-03
5-j 35
Elapsed Time,
min./lOO
15-
30
50
75
100
125
150
175
200
225
250
300
325
375
koo
1+25
450
U75
500
Total Siilfxir,
%
6.1
7. U
7.8
8.9
9.7
.10. ^
9-6
10.6
10.8
11.2
11.3
10.1
11. k
11.8
12.1
13.8
13.3
13.5
13.7
S02 Analysis,
Its. SQ2/100 Ibs. C
15; 80
15-19
13.75
12.21*
11.50
	
9.25
B,6k
7-73
7-^3
6.97
6.28
5-57
lj.75
U.W
^.99
3.1*3
U.31
3.37
-------
                    -CTA1  SULFy? A1C2 502 AlIAliSZS Oi: CA330K
                      AS A FuiiCTic:; :? :r~-z ?o?. ?:j.i 330-17

                      ( 2?5°F  at 25-4$ EgS and   0 % ;-;23)
TOIA.L SULFUR ACT S0£ AKALYSES ON CARBON
  A3 A FUNCTION OF TBS FOR RUN DSG-18

  !  325 °F at  5-0-p H2S and   0 % H20)
            Slapsea Tine,   I   Total sulfur,  !      302 Analysis,
              -in./ICO               *        '   Has. SCc/lOO  Its.  C
N)

0
20
40
s^ w
.
6. 84
	
15-23
—
9.6 10.99
9-1- ! 9-79
; 30 11.72 ! 7.5
j 125 i 11-25 6.47
150
175
225
250
275
3.00
325
350
375
400
425
450
475
500
12.60 5-68
13-52 4.36
14.12
13.76
13.54
5.6
4.38
4.86
15.0 : 4.9
14.48 3.74
15.0 ! 3-93
15.2
15-32
14.68
15-72
3.24
3.64
4.97
5.28
14.8 5-6
15.36 5-19
Elapsed Tine ,
min./iOC
0
20
40
60
30
100
125
150
175
225
250
275
300
325
350
375
i|00
1+25
450
475
500
Total Sulfur,
%
6.7
6.6
6.8
7-1
8.2
7-3
5.8
6.8
7-1
7.1
7.2
3.1
8.8
9.8
9A
—
—
___
—
—
"••"
S02 Analysis
Ibs. S02/1CO Ibs. C
15.1
15-7
16.44
16.0
15.0
14.5
13-1
12.0
8.75
8.45
8.62
—
6.57
5.6
4.95
4.66
4.32
4.06
3-7
4.36
3-93
-------
                     TOBi.Ii SULFUR AND S02 ANALYSES ON CARBON
                       AS A FUNCTION OF TIME  FOR HUH DSC-19

                       (  325"F at 9-1% H2S and   0  % H2C)
TOTAL SULFUR AHD S02 ANALYSES OK CARBON
  AS A FUNCTION OF TIMS FOR RUN DSG-80

  ( 325"? at 18.2$ EgS and   0 % H20)
N>
-P-
Elapsed Tine,
•»— - -V, / ~ f*f\
la^Ji . » .JLVW
0
j-5
30
50
Total Sulfur, |
ci i
8.5
6-9
S.O
7-9
75 " 8A
100 | 8.5
125
150
.L'f ^>
200
225
250
275
300
350
375
Uoo
^25
ir50
VT5
500
8.5
9-1
10.2
10.1
10,2
10.8
11.7
H-9
12.0
13-1
12.8
12.6
12.2
Z2..1
32.. 3
S02 Analysis
Ibs. S02/100 IDS. C
16.1
16.21
15-33
lit, 65
12.92
ll.C-7
9-25
7-96
7-52
6.22
if. 78
3-75
3.82
3^5
3-31
2.94
3-21
2.97
3-05
2.95
3-25
Elapsed Time,
min./lOO
0
15
35
65
100
125
150
175
200
250
275
300
325
350
375
425
if 50
VT5
500
_
Total Sulfur,
5-9
7.8
8.2
9.5
11.3
10-9
11-5
12.8
13-2
13.3
13. if
13.7
lif.5
13.5
13.3
13.lt
14. 5
13.2
14.5

S02 Analysis,
Its. S02/100 Its. C
15.0
l6.3
14.6
12.0
9-16
T.05
6.25
4.68
4.6
3-49
3.38
3.52
3.19
3.19
3.6l
4.03
3.48
2.99
4.13

-------
TOTAL SULFUR AJO) SO 2


  ( 325°? at  26.~:  EC
^jYSi.5 s^_\ CAR30I7
 ?0a BUS DSC-21

=id   C 5 K2C)
                                                                                              TOTAL SULFUH A3D S02 ANALYSES OH  CARBON
                                                                                                AS A FUNCTION OF TIME FC3 RUN DSG-22

                                                                                                (325 °F at 37-6£ H2S and   0
to
ilapsed Tide,
ain . /ICO
;
0
25
50
t '
i '^
! 3?
100
125
150
175
200
225
250
275
300
i 325
i 350
j 375
too
! t25
t50
t75
500
Total Sulfur, '. £0g Analysis,
;1 1 Ibs. SOg/iOO Ibs. C
7.6
6.t
10. '•*
11.3
12.3
12.6
15.5
T 5 £
13.9
it. 9
15-1
15-0
15.1
15-2
it. 7
15-2
15. c
15.0
15.3
15- 1
15 A
15.21
16.52
12.3
10.73 I
9-7
7-95
6.31
5.02
4.19
3.77
3.59
3.37
3.12
3.37
I'M
3.33
2.86
j 2.6
2.83
1.13
3-03 .
•Elapsed ?ine,
min . /100
0
20
t5
70
100
125
150
175
200
225
250
300
325
350
375
too
1*25
450
t75
500
To-jal Sulfur, .' SOg Analysis,
% | Ibs. S02/100 Ibs. C
6.t
8.0
9.1
11.6
It. 3
It. 2
lt.0
It. 7
15.0
15.3
it. 7
15.lt
It. 7 •
It. 7
It. 3
16.2
15.5
13.7
It. 2
15.1
15.03
13.39
9.37
7.12
t.35
t.05
t.2t
3-30
3.39
2.85
2.33
2.5
2.76
3.35
2.29
2.61
3.53
5-38
2.76
2.81
-------
                        APPENDIX A-12


              DETAILED RESULTS OF INTEGRAL RUNS
                                                         Page
 1.   Experimental Data and Results for Integral           248
       Run IR-1-4 (188 - 243 hours)

 2.   Experimental Data and Results for Integral           260
       Run IR-1-5 (246 - 262 hours)

 3.   Experimental Data and Results for Integral           271
       Run IR-2-6 (37 - 51 hours)

 4.   Experimental Data and Results for Integral           283
       Run IR-2-6 (51 - 66 hours)

 5.   Experimental Data and Results for Integral           295
       Run IR-2-7 (66 - 81 hours)

 6.   Experimental Data and Results for Integral           307
       Run IR-2-7 (81 - 96 hours)

 7.   Experimental Data and Results for Integral           319
       Run IR-2-7 (96 - 111 hours)

 8.   Experimental Data and Results for Integral           331
       Run IR-2-7 (111 - .126 hours)

 9.   Experimental Data and Results for Integral           343
       Run IR-2-8 (144 - 148 hours)

10.   Experimental Data and Results for Integral           354
       Run IR-2-8 (148 - 156 hours)
                    i
                    i
11.   Experimental Data and Results for Integral           365
       Run IR-2-8 (156 - 168 hours)
                             247
-------
              APPENDIX A-12-1
EXPERIMENTAL DATA AND RESULTS FOR INTEGRAL
       RUN IR-1-4 (188 - 243 hours)
                   248
-------
     S!
                                          -      -              .                                           -  _            2/23/74

                                     STATUS REPORT CF  OPERATING CONCITICNS FC!;.  INTEGRATED OPERATION OF  S02  RECCVERY PROCESS
fO
-P-
:
ij
.1


!;!
4,





OPERATING PERIC3:
DATE: 2/23/74
GATE: 2/24/74





PRCCESS ELAPSED TIKE
P





LES



TIME CF RECCRC: Z3:15 'IRS TC Z4: 0
TIME CF RECCRC: 0: 0 .IRS TC 6:15


CF PERIOD: START 18il.CC HRS / END

HRS
HRS










-
.

243. CO HRS LENGTH CF PERICD: 55.00 HRS
FCR OPERATING PERICO:






->
!*
f'
l".
'"*

••a
n
--
IT


*


3ti
S .
fa"
= s
r.

5 ,
U3
I'-'

>;-
t
>--:

u
5 -'
-..
5

3"
S02 SCR8ER
2:15
6: 15
13:15
17:15
21:15
1: 15
5:15

2:15
6:15
13:15
17:15
2 1 : 1 5
1:15
5:15

23:15
6:15

.
1:15
9:15
17:15
1: 15


2:45
14: 2
3:15
12: 15
l: 2
5:15

19:15
4: 2
11:15
19:15

11:15
19:15
HRS
H.SS
HRS
H.RS
HRS
HSS

HRS
HRS
HRS
H^S
HRS
HRS

HRS
HRS


HRS
HRS
HRS
HRS


HRS.
HSS
HSS
HRS
HR.S"

HRS
HRS
HSS
HRS
HRS
191.00
195. CC
226.00
23C.CO
234. CC
23S.CC
242. CC
A V E

191. CO
195. CO
226.00
23C.OO
234. CO
233. CC
242.00
A V E
188.00
243.00
A V E
19C.OO
195. CO
23C.CO
238. CO
A V c

191.50
2C2.30
216.00
225. CO
237.80
242.00
A V E
134. CO
192.20
2CC.CO
zee. co
316. CO
22''.. t3
Z32.CO
HRS
HRS
HRS
HRS
HRS"
HRS
R A

HRS
HRS
HRS
HRS
HRS
HRS
(ET)
(ET)
ItT)
(ET)
(ET)
(ET)
(ET!
G E_s

(ET)
(ET)
(6T)
(ET)
(ET)
(ET)
H-RS_JLE!J 	
RAGE:
HRS
HRS
R" A
HRS
HRS
HRS
HRS
R A
H.RS
HRS
HRS
HRS
HRS
HSS
R A
HRS
HRS
HSS
HRS
HRS
HAS
(ET)
(ET)
G E :

(ET)
(ET)
(ET)
(ET)
G E :

(ET!
(£T)
IET)
(ET)
(ET)
(ET!
G E :
!ET)
i£T)
SET)
!£T)
(ET!
(ET!
(ET!
S02 CCNC INLET FLUE G->S
S02 CONC INLET FLUE G.'S
S02 CCNC INLET FLUE G"S
S02 CCNC INLET FLUE G/IS
S02 CCNC INLET FLUE G^S
S02 CCNC INLET FLUE G;>S
SC2 CCNC INLET FLUE G-1S
SC2 CCNC INLET FLUE C-,!S

S02 CCNC CUTLET FLUE £S
SC2 CCNC CUTLET FLUE GAS
SC2 CCNC CUTLET FLUE c;*s
S02 CCNC CUTLET FLUE S*S
H20 CCNC INLET FLUE G,!S
H20 CCNC INLET FLUE G..'S
H20 CCNC INLET FLUE G.SS

CRIFICE PRESSURE DRCP
CRIFICE PRESSURE CRCF
CRIFICE PRESSURE DRCP
CRIFICE PRESSURE CRCP
.CRIFICE PRESSURE DRCP

ORIFICE TEMPERATURE
CRIFICE TE'-'PERATtSc
CRIr.ICE TEKFERATLRE
CRIFICE TEMPERATURE
CRIFICE TEMPERATURE
CRIFICE TEMPERATURE
CRIFICE TEMPERATURE
WEIGHT CYCLCNS CUST
WEIGHT CYCLCNE DUST
WEIGHT CYCLCNS DUST
HEIGHT CYCLC.\£ CUST
WEIGHT. CYCLCSE OUST
ncIGHT CYCLCN-E CUST
-EIGHT CYClO.E CUST
(GS-
(GS-
(GS-
-
1DP-
10?-
(OP-

(TL-
iTL-
(TL-
!TL-
ITL-
(TL-
(TL-
1 l>~
i 2-
l C-
( C-
( C-
( C-
1 C-
10)
10)
10)
10)
10)
10)
10 )
1C)
16)
16)
16)
16)
16!
16 )
16)
16)
10)
1C)
10)

10)
1C)
10)
10 !
10)

1C)
1C!
10)
10!
1C)
10)
1C!"
11 !
11)
11 )
11 )
il !
U !
11 ;
/ Y10(1,T) =
/ YlO(ltT) =
/ Y1011.T) =
/ YlO(l.T) =
/ YlOi l.T) =
/ YlO(l.T) =
/ YlO(ltT) =
/ AY10A =

/ Y16(1,T) =
/ Y1611tTI =
/ Y16I1.T) «
/ Y16t 1 TT) =
/ Y16(1,T) =
/ Y 16 (l.T) =
/ Y16(1,TI =
/ AY16A =
/ Y10(4,T) =
/ Y10(4,T) «
/ AV10D =

/ C?10(T) =
/ DPiom =
/ CPIC(T) =
/ CP10IT) =
/ AQPIO =

/ TLlOiTj =
/ TLlOiT) =
/ TLIO!") =
/ TLIO(T) <*
1 TLlO(T) =
/ TLIOIT! =
/ ATL10 *
1 C C 1 1 ! T ! =
/ COli(T) »
/ CCll(T) =
/ CD1HT) -
/ CCll(T) -
2C90.000
2296.000
2240.000
2240. COO
2290.000
2290.000
2240.000
2240.857

28.000
70.000
150. COO
175.000
162. ^CO
165. OCC
157.500
131.143
10.000
1C. COO
1C. CCO

2.400
2.400
2.400
2.400
2.400

204.000
308. COO
306. CCO
3C6.COO
309. COO
312. CCO
307. SOO
C.O
1.250
1.200
1.400
1-530
1.6CO
t;
ppy (VCLUKE) .<
PPf (VCLUME) :s
PP." (VCLUME)
PPM (VCLUKE)
PPK (VCLUKE)
P?f (VCLUKE)
PPN (VCLUHE)
PPf ( VCLUME) L-i
_
PPM (VCLUMc) :,
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                                                                                                                       2/23/74      PAGE   5

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RATE
RATE
RATE

FUR C C t
CCLLECTE;
COLLECTS:
CCLLECTES
CCLLECTEC
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                                    STATUS REPORT CF OPERATING CONDITIONS FCR INTEGRATED OPERATION OF S02  RECCVERV  PROCESS
                                                                                                                                  PAGE
NJ
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OPERATING PERIOD:
	 QiT = : 2/23/74 T1XE CF RECCRC

PROCESS ELAPSED TIME CF PER.ICO:


0: C rK
START 168..
": sitMKARY CF INTEGRATED PROCESS PERFORMANCE:
S
.:-
b
r *
r*
("•'
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1.

2.
3.

4.

S02 REMOVAL

H2S UTILIZATION
ACIO CONVERSION (TO SULF'JR)

1-2 UTILIZATION (TO H2S)

PRS02 =

PVCS *

PHCHS =
j
S TC 24: C HRS
I C 6s 1 5 rRS i
CC HRS / ENC 243.00 f-RS LENGTH OF PERICC: 55.00 HRS v
-— — — •- 	 	 • 	 • 	 •-• 	 i
T
, i
9
94.15 Z (ACTUAL) 90. C S (GCALI ,-t
'.,
9C.97 S (ACTUAL) 95. C J (GOAL) ;«
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36.56 % (ACTUAL! 99.0 J (GOAL) W
rJ
72.29 % (ACTUAL) 90. C I (GOAL) - >J
r» §'
-
y
5.
6.
SULFUR RECOVERY
H2 UTILIZATION 4" UNIT
PRS
PUH2 =
63.38 % (ACTUAL) 1CO.O 1 (GOAL) OF SCRBEC SC2
18.34 Z (ACTUAL) 25. C S (GOAL) OF STRIPPED SL'LFUR a
93.53 % .-,
=» 71
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RESIDUAL SULFUR ON CiRECN
CARBON RECYCLE RATE IDS)
ACIO LOADING INLET CAREON 6" UNIT

MOISTURE CCNTENT INLET CARBON 6" UNIT
ACID LOADING INLET CiRECN 8" UNIT
^ i?. nnrsTURF CCNTENT INLET CARBCN 8" UNIT
:i
3*
r"
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"i
w
HI.
,
13.
14.

TOTAL AC'D CONVERTED 6" UNIT
SULFUR CONVERSION (TO K2S)
L">T Sill PLR TPNCENSER EFFICIENCY




X9CA =
RC90 =
X301C -

X301B »
X302C =
X302B =

PVC
PSCI-S =
ERV400=


fAJCR EVENTS CURING OPERATING PERICC:
SCIVED PRCBLEC ViITH OFF-GAS ANALYSIS FROM SUl

AT ENC CF PERICC LOWERED hYCRCGEN
C.C337 L8 S/L6 C w
29.922 LB C(DB)/HR . " jj
:J
C.256C LB ACIC/L8 C -:
^
C.C934 L8 H20/LB C s»
, !
C.256C LB ACIC/LB C rf
C.0934 LB H2C/LB C ^

?5.59 * • ^
87.40 S p
1*5.58 S a
''•

U
FJR GENERATOR J
FLOW RATH TO 120 CFH
-------
N)







STATUS RP.PCRT CF OPERATING CCNCtTICNS
OPERATING PSRIOC:
DATE: 2/23/74 TIME CF RECCRC: 23:
CATE: 2/26/74 TIME OF RECCRC: 0:

PRCCESS ELAPSED TIXE CF PERIOD: START
SULFUR MATERIAL BALANCE (USING PRCCESS H2S):

FCR INTEGRATED CPERATICN
IE t-RS TC
0 HRS TC

188. CO HRS


24: C
6: 15
~7~ENO


HRS
HRS

243. CO


2/23/74
CF S02 RECCVERY PROCESS



HRS











LENGTH OF PERIOD: 5


PAGE 9 ")
\
J

',.
:
S:00 HftS !.
1
' 1
..

p


;
r
E


tt
r
S 0 2
; N
INLET GAS AS S02
INLET C AS RESIDUAL S
TOTAL IN:

CUT
OUTLET GAS AS S02
CUTLET CARSON
CYCLCNE CUST
CCLLECTCR DUST
CiRECN WEEPAGE
TCTAL OUT:
6" DIA CARBO
s c: R B
( ',- l!i> I
( C- lit 1
t S i- 1 (i ) /

( c- i;:) /
( :> li.) /
< ':- i;:> /
(C'.- K'l /
 /
R GEN

BC12A
SI300

BC201A
BD301A
S0300
ERA


3.5C93
3. 5093

3.
C.
3.
T C R

5093
0
'5C9~3


LS
LS

LB
LB
LB


SULFUS/HR
SU'LFUR/HR

SULFUR/HR
SULFUR/HR
S'JLrUR/HR

^
-'
-^
'.i
:.,
r.-.
^1
t1' '«.'
«;
ft!
Ai/
,7"
»S
•I?1
K;
t N
INLET GAS AS H2S tCYL)
INLET GAS AS H2S (PRCC)
INLET CARBCN
TCTAL IN:

CUT
CUTLET GAS AS H2S
OUTLET GAS AS SC2
OUTLET CARBON

{ c-zc;.) /
< C-iCi ) /
t c-jc:. > /
-------
NJ
Ul
CO

1' *
i';
3]
'4,
•V
'*•
1
* '•

r*
i?
»i
''i.

H 2 S
GENERATOR
I N
INLET CARECN


CUT
CUTLET
CLTL3T
CUTLET
CYCLCNE
FILTER
T

T C T


CA°.3CS
GAS AS
GAS AS
CUST
CUST
C T A
C
A L IN:

'
H2S
S


L CUT:
V E R A L L
( C-
1RV-


( C-
< G-
( C-
( 0-
(RV-
S L L
•'SULFUR
•C2)
'.CO


!.C3)
:.c^t)
id)
1C2)
:.cc>
F U
/ 3C202A
/ SHOO


/ SC103A
/ BG1048
/ SCIONS
/ BD101A
/ 8D102A
/ S0100
R 8 A
S T
=
_


C
•s
-
S
9
9


1
7
1
C
0
R I P
.7849
.7849


.OC85
.6705
. 6 i C C
-C042
.0
= 10.2933
t A
N C
E
P E
L8
LE

L3
LE
LE
LS
LB
LS

2/23/74 PAGE 10
R
SULFUR/HR !>
SULFUR/HR i.
'Si
«.
SULFU'S/HR '•;
SULFU3/HR ;,
SULFUR/HR iJ
SULFUR/HR I,,1
SULFUR/H.R Ijj
j
rfa f h
--
I N

-i INLET GAS 18"
t :
•X
:r
-t
INLET G
CUT
CUTLET
CYCLCNE
AS 8"

GAS 18
CUST

UNIT AS SC2
UNIT AS CYL H2S
T C T A L

" UNIT AS SC2
13" UNIT
-.;. CCLLECTC3 DUST IS" UMT
=> CASECV XEErAGE 13" UMT
~ CYCLCNE CUST 6" UNIT
cv
•~.
'x
??
S*
21
OUTLET
•OUTLET
CUTLET
OUTLET
CYCLCN;
FILTER

«
GAS 8"
GAS 8"
GAS 4"
GA S 4 "
CUST
CUST 4


UNIT AS H2S.
UNIT AS SC2
UNIT AS H2S
UNIT AS S
4" UN: IT
" UNIT
TOTAL S


t 3-
S L t

I G-
( C-
( C-
(CV.-
( C-
( G-
( G-
( G-

1C)
F U

13)
Hf
121
i.21
,!C5)
:;c5 )
1C4 )
{ C-iOl!
! C-IC2)
U L P

U R


/ BG10A
/ BG201B
R I N

/ 8G13A
/ BDUA
/ S012A
/ BCK12A
/ EC 301 A
/ BG2Q58
/ BG2D5A
/ seiche
/ 8G104S
/ ED 101 A
/ HC102A
OUT


X.
•

=
=
=
;=
=
=
=
=
:


2
C
2

C
0
f*
c
0
0
0
c
1
0
2


.6933
.0
.6983

.1579
.~G170"
. CO 1 2
.0
.6331
.2359"
.C
.6100
.00<.2
.7253


IB
LE
LB
LS"
LE
L S"
IB
LB
LB
LS
LS
» P
LS
LB

','
SULFUR/HR '^
SULFUR/HR i,
SULFUR/r.R - . ''ri
...
SULFUR/HR 7i
SULFUR/HR T<
SULFUR/HR aj
SULFUR/HR " W
SULFUR/H3 V
SULFUR/HR :i
SULrUR/HS . -j
SULFUR/HR „'
SL'LF^R/HR ,.
SliLFUR/i-S :-
SULFUR/HR ^
B?
3* 3«(

^










































1
^i

,.
j*
», •**
"5
«;

       rt-
-------
                                                                                            2/23/74
                                                                                                        PAGE 11
hVCRCGEN MATERIAL  BALANCE:
t[
I*
•',.
'L

! N


S U L F

INLET GAS AS H2
•i_ INLET GAS AS H2S (CYL)
f .
i
*.-
•»
INLET GAS AS H2S (PRCC)
INLET GAS AS 1-20
INLET Ci'KSCN


T C

T A L IN:

UR GENERATC

! G-rC3) /
{ 6-ZC3> /

' BG203C =
' BG203B =
1 G-l':3) / EG203 =
( G-rOS! / BG203D =
( c-?/:i) / ec2o\ir =
(RV-::CO /

' H20C =

R

0.
c.
c.
c.
0.
1.



C09/
0 "
4793
1663
4S67
1420


LB
"LB"
LS"
Le
LE
LE


HYCRC-GEN/f-R
HYCRCGEN/hR
HY:RCG=N/HR
HYCRC5E.M/HR

'='
.
:
.;
>
9
•
CUT

:i
,j
•5
:--.
-.:
ts_"i "^
in -*-
VQ '"'
W
*»
!*
;-i
OUTLET
OUTLET
CUTLET
CUTLET
T


I N
INLET
I'iLET
CUT
OUTLET
CUTLET
CUTLET
T
GAS
GAS
GAS
AS H2
AS H2S
AS H2C
CAR3CN
C T

H 2

GAS
A L CUT:

S GENERA

AS HZ
CAR3CN
T C
GAS
GAS
GAS
C T
T A U IN:
AS 1-2
AS (-2S
AS h20
A .L CUT:
{ G-:.:-:5> /
( G-::I:SJ i
f G-.1 :s ) i
\ C-2C2) /
!RV--1CC) 1

T C R / 3 U

1 G-l'3) >
! c-?:: ) >
(Rv-t:ci /
i • G-I:«) /
{ G-i;^) /

IRV-ICC) y
' BG2C5C =
' EG205H =
' EG205C =
' SC2C2r =
' 1-C20C =

L F Li R

' BG103C =
' BC202H =
' HI IOC =
' BG104C =
' BG104H =
' BG104D =
' i-OiOO =
0.
r\ ^
C •
^
U •
0.

S T R

C.
C.
C.
0.
0.
r>
•* *
0.
0023
C43C
O 7 c £
0 2 19
9025
I P
6630
0219
6C49
0093
4 793
1934
6624
LB
LE
LB
i- £?

P E

LE
LE
LE
L8
"LE"
LE
LE
HYCRCGcN/HR
HYCRCGEN/HR
hYCRCGEN/r-R
HYCRCGEN/I-R

R

HYCSCGEN/hR
HYCRCGS^/t-R
HYCRCGEN/KR
HYCRCGEN/hR
HYCRCGEN/hR'
HYERCGEM/VR
HYCRCGEM/rR
&
>
-
•a
^
T;
~3
-t.
.
--•
;,
-,
JO
-
i*1 ' K
?J



















• i
*
-------
              APPENDIX A-12-2
EXPERIMENTAL DATA AND RESULTS FOR INTEGRAL
       RUN IR-1-5 (246 - 262 hours)
                   260
-------
                                                                                                                     2/26/73
                                                                                                                                 PAGE   1
Ni
                                   STATUS REPORT CF OPERATING CONDITIONS FOR INTEGRATED OPERATION CF soz RECOVERY PROCESS
(:>. 	
i.-i
i.i


V
v
i''

OPERATING PEPICO:
CftTE: 2/26/73 TIKE OF RECCRC: "• 9:15 h>< TC 24: 0
CATE: 2/27/73 TIME OF RECCRC: 0: 0 h-.S TC 9:15


PROCESS ELAPSEC TIPE


CF PERICD: START 246 .CO HRS / END
HRS
HRS

270.



: 't
i'!
,,l
CO HRS LENGTH GF PERIOD: 24.00 HRS :.l
PROCESS VARIABLES FCR OPERATING PERICD:






h
i
~y.
'•«• ^
>r
is
M
'•r
.i*

72
=3
•"•I
"""•

W
~i
\"
r*


'•
j.

1 ^

r"

'4i
r '

'.^
•^


13:15 HRS
18: 2 HRS
21:15 HR S
l: 15 H.RS
5:15 HRS
13:15 HRS
19: 2 HRS
21:15 HRS
1:15 HRS
5:15 H.RS
21:15 HRS


13:15 HRS
22:15 HSS
6:15 rRS


13:15 HRS
22:15 HRS
6:15 HRS

11:15 V-RS
3:15 HRS

11:15 HRS
3: 15 HRS

16:15 HRS
0:15 H.RS




25C.OO HRS (ET)
254. SD HRS (ST)
25c.CC r 3 S ( C T )
262. CO HRS (ET)
266.00 H?.S 
267. CO j-'S (ET!
AVERAGE:

243. CO HRS (£T)
254.00 H=.S (ET)
T C T A L :
S i T E :
243. :C r?S (ET)
264. CD !--. S IcT)
T G T 4 L :
RATE:
253. CO HRS (ET)
261.00 HRS (ET)
TOTAL:
5. - T E :

S 0 2 3 C R
S02 CCNC INLET FLLE G*3
S02 CCN'C INLET FLUE G/3
S02 CGNC IN-Lci FLUc Gti
S02 CCNC I.NLET FLLE GAS
S02 CCNC INLET FLUE G«S
S32 CCNC INLET FLUE G«S
S02 CCfiC CUTLET FLUE G4S
S02 CCNC CUTLET FLUE G«<
S02 CONC CUTLET FLUE G££
S02 CCNC CUTLET FLUE GAS
S02 CCNC CUTLET FLLE G*£
S02 CCNC CUTLET FLUE Gi£
H20 CCNC INLET FLUE G/S
H20 CCNC I.NLET FLUE G-
1CX-
(Ci*-


10) /
10) /
1C ! /
10) /
1C 1 /
10) /
16) /
16) /
16 ) /
16) /
16! /
10) /
10) /

1C! /
10) /
10) /
1C) /

1C ) /
1C! /
10 ; /
1C ) /'
IT * /
L t 1
11) /
11 !/
11! /
12 ) /
12) /
12 ) /
12) /
12! /
12) /
_-2.l./.

Y 10 ( 1 T T ) =
Y10(1,T) =
10 ( 1 » T ) —
YlO(ltT) =
YlOIltT) =
AY10A =
Y16!1,T) =
Y16!1,T) =
Y16U,T) =
Y16! 1 f T ) =
Y16(1,T) =
Y 1 0 ! 4 1 T i =
AY10C =

CPiOIT) =
C? 10 IT) =
DPIO'.T) =
SOP10 =

TL10(T! =
TLlO'Ti =
TLIC;T) =
A 7 L 1 C =

COU(T) =
CC11 IT! =
^D! 1 =
CC121T) =
C012!T) =
K012 =
RD12 »
CVJ12 (T ! =
V.'C'
9. £00 S (VCLU'ME) t=
9.SOO S iVCLUri = ) ~:
-,-•
2.400 INCHES H20 •..;
2.400 INCHES H20 ..
2.250 INCHES H20 ;,:
2.383 INCHES H20 -j
ES
2C7.000 CFG c r.
30?,. COO CSG r
203. COC CHC F
2C4.333 CEG F ;,
,
0.0 LE CUST ;
4.200 L? C'JST
4.2".'0 LE COST
o..c£2 Lr :JST/HR
-1
C.O Li CUST
2.700 L= CUST ' .,
2.700 is :usr • ' ' ,
0.169 IB CUSI /HR •
C.O Lc CUST ,:
O.C54 LZ CUST ,,
O.C56 LE CUST .]
O.COV LS CUST/HR
;,
                       11:15 HRS   2-3.CO HRS iET)
                                                       S TGT S  CN  CYCLCNE  2LST
                                                                                       C- II) / C1K1.T)  =
                                                                                                                  7.0feO ?  (HEIGHT)
-------
N>
          AVERAGE  :

._5_HAS	C._0 2_N R S_l £ Tl

          A V ~E R A G E  :
                                                          S  TOT S CN CYCLCiNE

                                                         _?_TPLJL_CN_CC|-LECTQR_ CI S L
                                                          x  TOT s CN cciVecTOR "ci.sr
<  D- 11) /

I  D- 12) / C12U.T)
   2/2f/73      PAGE   2

7.0cO t  (WEIGHT)

7.060 X  (HEIGHT)
                                                                                          < D- 12) /
                                                                                                        A012*   =
                             _
                              7. "080
                                                                                                                                U EIGHT)
-------
to
i
I 6" 0 I A
v 17:15 HRS 254.00 HRS ( ET ) ? TOT
pi 1:15 HRS 262. CO HRS (ET) S TOT
i'j 5:15 HRS 266.00 HRS (ET) % TOT
|'L_ • AVERAGE:* TOT
'•*!
!'i 17:15 HRS 254. CO HRS (ET) % H20
•: 1:15 HS.S 262. CO HP.S 1ET) 1 H20
iri 5:15 HRS 266. CC HRS (ET) t H2C
!«! AVERAGE:? H20
f» 9:15 HRS 246.00 HRS (ET ) WElGt-T
'•> 9:15 HRS 27C.CO HRS ( ET ) WEIGHT
«! TOTAL: WEIGHT
»i RATE: V.EIGHT
U: 9:15 HRS 27C.OO HRS tET) S TOT
}*' . A V E R A G E : % TOT
•!«
-«
t".
C7
&
u
C A R 8 O. K PR
S ON I\'LET CAR8CN
S CN INLET CAPSCN
S CN INLET CAPECN
S CN INLET CAHeCiV

CN INLET CARBCN
CN INLET CARBCN
CN INLET CARECN
ON INLET CAR8CN
CYCLCNE OUST
CYCLCNE OUST
CYCLCNE OLST
CYCLCNc CUST
S CN CYCLCNE DUST
S CN CYCLONE CLST






E C 0 N C I
•CS-301 )
(CS-3C1)
fCS-301 1
(CS-301)

(CS-301)
(CS-301 )
(CS-301)
(CS-301 )
( 0-301)
( 0-301)
« D-3C1)
{ D-301)
( 0-301)
( 0-301)






T
/
/
/
/
"/
/
r
/
i
/
/
i
i
i






t 0 N c R
Z301U.T) =
Z30K1.T) =
Z3GHltT) =
AZ301A = .

Z301I2tT) =
Z30K2.T) =
7 3O 1 I ? . T 1 ~
AZ301B =
C030KT) -
CD30KT) =
WD301 =
RD301 =
0301(1. T) =
A0301A =






2/26/73 PAGE 3
8.440 t (V.EIGHT)
7.600 * (WEIGHT)
8.560 ? (WEIGHT)
8.200 * ( HEIGHT)

7.790 3 (HEIGHT)
7.460 3 (ViEIGKT)
6.790 % (V,EIGHT)
7.347 S (hEIGHT)
0.0 LB CUST
0.0 LB CUST
0.0 L3 CUST
0.0 L3 CUST/HR
0.0 S (WEIGHT)
0.0 S (KEIGrT)


•-





'.
:
t
,';
--.

7J
,'4
r*
-*
...
-i
»
-2
13
-*
H '
fc! -.
1 :
f> '•>
P




-
13
HI
pi
(-(-._.
P
C-
	
I-!
Ij 	 	 "








,


























-,
-,

_;
t.
•— • • i '
-i
-------
                                                                                                                         2/26/73
                                                                                                                                     PAGE
to
                                                                 SULFUR
                                                                                 GENERATOR
1,4:45 HRS
23: 2 HRS
12:32 HRS
0:15 HRS

i 14:45 HRS
E

12:32 HRS
' 0:15 HRS
i
n
I 14:45 HRS
23:26 HRS
i
12-32 HRS
: 0:15 HRS


14:45 HRS
i 23:26 HRS
'
12:32 HRS
0:15 HRS
•
14:45 HRS
23:26 HRS


9:15 HRS
9:15 HRS
21: 15 HRS


21:15 HRS
21:15 HRS


21: 15 HRS
9:15 HRS
17! 15 HRS
1:15 HRS
5:15 HRS
251.50 HRS (ET)
259.80 HRS (ET)
AVERAGE :
249.30 HRS (ET)
261. CO HRS iET)
AVERAGE:
251.50 HRS (ET)
6C.20 HRS (ET)
AVERAGE:

249.30 HRS ( ET )
261.00 hRS (ET)
AVERAGE :
251.50 HRS (ET)
26C.20 HRS (ET)
AVERAGE:
249.30 HRS (ET)
261. CO HRS (ET)
AVERAGE:

251.50 HRS (ET)
26C.20 HRS (ET)
AVERAGE :
249.30 HRS ( ET )
261. CO HRS (ET)
AVERAGE:
251.50 HRS (ET)
26C.20 HRS (ET)
AVERAGE:

246.00 HRS (ET)
27C.CO HRS (ET)
AVERAGE:
253. CO HRS (ET)
AVERAGE:

253.00 HRS tET)
AVERAGE:
258.00 HRS !ET)
AVERAGE:

258.00 HRS (£T)
AVERAGE:
246.00 HRS (ET)
254.00 HRS (ET)
262. CO H?S IcT) 	
266. CO HRS i£T)
AVERAGE :
S02 CONC CUTLET GAS
SC2 CONC CUTLET GAS
S02 CCNC CUTLET GAS
H2S CONC INLET GAS
H2S CONC .INLET GAS
H2S CONC INLET GAS
H2S CCNC CUTLET GAS
H2S CCNC CUTLET GAS
H2S CGNC CUTLET GAS

H2 CONC INLET GAS
H2 CONC INLET CAS
H2 CONC INLET GAS
H2 CCNC CUTLET GAS
H2 CON'C CUTLET GAS
H2 CCNC CUTLET GAS
H2C CCNC INLET GAS
H20 CCNC INLET GAS
H20 CONC INLET GAS

H20 CCNC CUTLET GAS
H2C CONC CUTLET GAS
H20 CCNC CUTLET GAS
N2 CQNC INLET GAS -
N2 CONC INLET GAS
N2 CONC INLET GAS
N2 CONC CUTLET GAS
N2 CCNC CUTLET GAS
M2 CONC CUTLET GAS

N2 INLET VCL FLOW RA'fg
N2 INLET VCL FLOVi RATE
N2 INLET VCL FLCVi RATE
Z TOT S ON INLET CA3'3Ch
% TOT S CN IN'LET CASeC!'.

S TOT S CN CUTLET CA16CN
Z TOT S CN CUTLET C«ECJ(
% H20 ON INLET CARBC-i
S H20 ON INLET CARBCV

% H20 ON CUTLET CAF-ECN
? H20 QK CUTLET CARECN
% ACIC ON CUTLET CAR2C!*
% ACID ON CUTLET G£R!=C:>
% ACID CN CUTLET CAREC.t
% iCIC ON CUTLET CA3ECA
% ACID ON CUTLET CARHCN
(GS-206) /
(GS-206) /
(CS-2C6! /
(GS-2CC) /
(GS-200) /
CGS-200) /
(GS-206) /
(GS-2C6) /
(GS-206) /

(GS-2CO) /
(GS-2CO) /
(GS-2CO) /
(GS-2C6) /
«GS-2C6) /
(GS-206) /
(GS-2CC) /
(GS-200) /
«GS-200> /

IGS-206) /
(GS-206) /
(GS-2C6) /
CGS-2CO) /
(GS-200) /
(GS-2CO) /
(GS-206) /
(GS-206) /
(GS-2C6) /

( G-2CO) /
< G-200) /
< C— 2CO) /
(CS-302! /
(CS-302) /

1CS-2CO) /
(CS-2CO) /
(CS-302) /
(CS-302) /

JCS-2CO) /
{CS-2CO! /
(CS-2CC) /
JCS-2CO) /
(CS-2CO) /
1CS-2CO) /
(CS-2CC) /
Y2C6(ltT) =
Y206IltT) =
AY206A =
Y200(2tT) =
Y200(2iT) =
AY200B "
Y206(2,T) =
Y206(2»T) =
AY206E =

Y200(3,T) =
Y2CC(3tT) =
AY200C =
Y206(3tT) =
Y2060.T) =
AY206C =
Y2CC(4,T) =
Y2COI4.T) =
AY200C =

Y206(4,T) =
Y206(4,T) =
AY206D =
Y200(5,T) =
Y20C(5,T! =
AY20CE =
Y206(5tT) =
Y2C6C5»T! =
AY2G6E =

G20C<;,T) =
G2CO(5,T) =
AG2COE =
Z302(UT) =
AZ3C2A =

220C(1,T) =
AZ20C* =
Z3C2I2.T) =
AZ302B =

2200(2, T) =
AZ200E =
Z2C013,T ) =
Z200I3.T) =
Z^OCOrT) =
Z2CCi3, 5 i *
AZ2CCC =
0.960
1.100
1.030
28.300
25.700
27.000
1.000
0.720
0.860

0.0
0.0
0.0
0.0
0.0
0.0
10.200
11.200
10.700

48.300
48.200
43.250
58.900
58.500
58.700
49.500
49.800
.49.650

180.000
180.000
180.000
8.200
B.200

24.000
24.000
7.350
7.350

0.240
0.240
0.940
1.210
1.310
i.iJC
1.140
? (VCLUHE)
* 1 VCLUME I
* (VCLUKE)
* (VCLUME)
X (VCLUME)
T (VCLUME)
% (VCLUME)
? (VCLUME)
S (VCLUME)

1 (VCLUME)
* { VCLUME )
? (VCLUME)
% (VCLUKE1
* ! VCLUM E )
S (VCLUME)
S (VCLUME) ' -•
? (VCLUME!
? (VCLUME)

? (VCLUME)
S. (VCLUME)
S (VCLUME)
? (VCLUME)
S (VCLUME)
S (VCLUME)
* (VCLUME)
? (VCLUME)
Z (VCLUHE)

CFH (7C CEG F)
CFH (70 DEC F)
CFH (70 CEG F)
? (WEIGHT)
? (HEIGHT)

? (V,EIC-nT)
S {V.£!GrT)
J (V.EIGHT)
% (WEIGHT)

S (WEIGHT)
.3 (XE:C-:-.TJ
" (WEIGHT)
? (WEIGHT)
% CnEIGHTJ
k ! ? t i u r T )
? (WEIGHT)
j

t'
',
1 1
i .
•3.
ill
..'

-k
7
' J
73
_y
^
-t
"
-,
W
ta
-
_
-.
-^
\
j.
„-
.,
-
^
.-
.S

.-
..
-
''
-------
                                                                                                                          2/26/73
                                                                                                                                      PAGE
                                                    H 2 S
                                                             GENERATOR /SULFUR
                                                                                                 STRIPPER
Si
ON
Cn
V
Ij
Jt
4" '
i!

i*!

I-.

v
>l
>!
:»
R

H

r-
*
7.'
n
f'i
i«
H
Li
P
P
P
y
P
P
i. 	
i**

iJ
.,
<...
..
.11: 8 HRS
15: 8 HRS
" 1:26 HRS

12:32 HRS
0:15 HRS
11: 8 HRS.
15: 8 HRS
1:26 HRS

12:32 HRS
0:15 H°.S


12:32 HRS
0: 15 hRS
12:32 HRS
0:15 HRS

13:15 HRS
19:15 H«S
1S15 HRS


12:15 HRS
16:15 H?.S
20:15 HRS
0:15 HRS
4:15 HRS

9M5 HRS
9:15 HRS


3:15 HRS

21:15 HRS






247.90 HRS tET)
251.90 HRS 1ET)
262.20 HRS (ET)
AVERAGE:

249.30 HRS (ET)
261.00 HRS (ET)
AVERAGE:
247.90 HRS (ET)
251.90 HRS (ET)
262.20 HRS tET)
AVERAGE:
249.30 HRS (ET)
261. CO HRS (ET)
'- V E R A G E :

249.30 HRS (ET)
261. CO HRS (ET)
AVERAGE:
249.30 HRS (ET)
261. CO HRS (ET)
AVERAGE :
25C.CO HSS -ET)
256. OC HRS (ET)
262. CO HRS IET)
AVERAGE:

249. CO HRS (ET)
253. CO HRS (ET)
257. CO HSS !ET)
261. CO HRS (ET)
265.00 HRS (ET)
TOTAL:
RATE:
246. CO HRS IET)
27C.CO HRS <£T)
TOTAL:
RATE:
C.O HRS (ET)
AVERAGE:

258.00 HRS (ET)
AVERAGE:





H2 CONC INLET GAS
H2 CCNC INLET GAS
H2 CONC INLET GAS
H2 .CONC INLET GAS
"
H2 CONC OUTLET GAS
H2 CCNC CUTLET GAS
H2 CONC OUTLET GAS
M2 CCNC INLET GAS
N2 CONC INLET GAS
N2 CONC INLET GAS
N2 CCNC INLET GAS
N2 CQNC CUTLET GAS
N2 CCNC CUTLET GAS
N2 CCNC CUTLET GAS

H2S CCNC CUTLET GAS
H2S CONC CUTLET GAS
H2S CCNC CUTLET GAS
H20 CCNC CUTLET GAS
H20 CONC CUTLET GAS
H20 CCNC CUTLET GAS
N2 IKLET VCL FLOW RATE
N2 INLET VCL FLCW RATE
N2 INLET VCL FLOW RATE
N2 INLET VCL FLCW RATE

WEIGHT CYCLCNE CUST
WEIGHT CYCLCNE CCST
WEIGHT CYCLCNE CC'ST
WEIGHT CYCLCNE CCST
WEIGHT CYCLCNE OUST
WEIGHT CYCLCNE CUST
WEIGHT CYCLCNE CUST
WEIGHT FILTER CUST
WEIGHT FILTER CUST
WEIGHT KILTER CCST
HEIGHT FILTER CUST
% TOT S ON CYCLCNE CCST
% TOT S CN CYCLCNE CUST

X TOT S ON FILTER OLST
% TOT S CN FILTER CLST





,,
58.000 ? (VCLUHS)
57.133 t (VCLUME) . :t
53.900 ? (VCLUHE) :j
53.500 ? (VCLUHE) ;:»
58.700 31 (VCLUHE)
Sji
28.300 ? (VCLUME) -.'
25.700 ? ( VCLUME) -
27.000 S (VCLUME) ' W
10.200 ? (VCLUNE)
11.200 S (VCLUKE) i,
10.700 ? (VCLUME) .-,
175.000 CFH (7C CEG F) :'*
175.000 CFH (7C CEG F) :-|
175.000 CFH (7C DEG f) -,
175.000 CFH (70 CEG F) ^
.,'
0.0 LB CUST
0.055 LB CUST :-3
0.070 L6 CUST - y
0.064 LB CUST i.'
0.066 LB CC'ST (J
0.255 L6 CUST -J
0:016 IS CUST/HR
0.0 LE CUST ^
0.0 LB CUST 0
0.0 LE CUST
0.0 LB CUST/HR ^
24.000 ? (WEIGHT) L!'
24.000 I (WEIGHT) d
•^
24.000 ? (WEIGHT)
24.000 ? (WEIGHT) ' - :;
'2
bi
..,
- 1
if
-------
                                                                                                                              2/26/73
                                                                                                                                          PAGE
                                                                  CARBON
ON
k 	 21:_15 HRS 258. CO HRS t ET ) S RESICUAL S CN CARBCf.
'. AVERAGE:* RES 1C
'' 	 21:15 HRS 258. CO HRS 
UAL 3 C
UAL H2C
L'AL_H2C
RECYCLE
RECYCLE
S U L
N CARBC;,
CN CAR-r:N
ON CAR !CI*

RATE
RATE
FUR CON
 -i
5* -•
'
** . a

bo »
3: —
p*
bi


















^
r*
-------
                                                                                                                          2/2e/73




                                      STATUS  REPORT  CF  OPERATING CONDITION'S FCR  INTEGRATED  OPERATION OF S02 RECCVERY PROCESS
hJ

i —


_
•

i.
OPERATING FiRISD:
CATE: 2/26/73 TIME CF RECCRC
CAT£: 2/27/73 TIME OF RECCRC

PRCCESS ELAPSED TIKE CF PERIOD:
: 9:15
: 0: C

H*J TC 24: 0 HRS
H3S TO 9:15 HRS


,
s
START 246. (C hRS / END 270.00 f-RS LENGTH CF PERIOD: 24.00 HRS
SLyfiRY CF INTEGRATED PRCCESS PERFORMANCE:

S02 REHCVAL.

PRS02 =

S3. 71 X (ACTUAL) 90.0 % (GCAL)
I
•^
•'.
r ' ::
1 *•
•-• 3.
•i
- 4.
3
*: 5.
= 6.
rs
7.
r~\
3.
•» 9.

H2S UTILIZATION
ACID COVERSICN (TO SULFUR)

H2 LTILIZiTICN (TO H2S)

SULFUR RECOVERY
t-2 UTILIZATION 4" UNIT

RESIDUAL SULFUR ON CARBON
CiRSCN RECYCLE RATE (28)
—ACID LCACING INLET Ci.ReCN 6" UNIT

•--' 10. fOISTURc 'CONTENT INLET CARSON fc" UNIT
i- 11.
al 1?.

13.
14.
» 15.
r1 '•
,
'2

•*;
ACID LCiC!V3 INLST CiRECN 3" UNIT
_fOI.STURr *CNTENT_ INLET CARBON 8" UNIT

TOTAL ACIC CONVERTED 8" UNIT
SL'LCL-S CCNVEKSiO'.1 (TO H2S)
SULFLR CCNCENSER EFFICIENCY


V4JCR EVENTS DURING CPERATIMG PERIOD:
iT START OF PERIOD CUT h2 FLOVi TO
FUV2S »
PVCS -

FhCKS =

PRS =
PUH2 =

X90A =
RC90 =
X301C =

X3018 =
X302C =
X3023 =

PVC =
PSCHS =
£R\'4CO =


120 CF!-.
96.23 * (ACTUAL) 95. C * (GCAL)
87.96 5 (ACTUAL; 99.0 $ ;GCALI

69.39 S (ACTUAL) 90. C * (GCAL)

77.43 Z (ACTUAL! 100.0 % (GOAL) CF SCR8EO SQ2
21.64 % (ACTUAL) 25.0 * (GOAL) OF STRIPPED SULFUR
ICO. CO Z

C.C331 L8 S/L5 C
;:9.91S LB C1CB1/HR
0.2453 L3 ACIC/ie C
•
(i.lC14 LB S2C/LS C
c.2453 Lb ;::C/LS c
C.1C14 LB H2C/L6 C

93. SC %
77.72 S
97.14 S


FRC!' 132 CFH
••
-„
•-•
r
*;!
-;
:i
14
"5
J
'-J
-^
'-•=
^
;s
;._,'
3
..
t.
•_v
-
-------
                                                                                                                           2/26/73

                                      STATUS  REPORT CF OPERATING  CONDITIONS FCP. INTEGRATED OPERATION  OF S02 RECOVERY PRCCESS
                                                                                                                                        PAGE  S
                              OPERATING PERIOD:
                                  _EALE_:	2X 2 6 /13_
                                  _CAT£:   2/2.7/73_
jrjM£ OF RECORD:   9:15  MRS. TO  24: 0 HRS
 TIKE OF RECORD:	0:  0  t.RS  TG	9:15 HRS
                                   PRCCESS  ELAPSE^..TIX-E CF PERIOD:	S_TART__2't( .CC HRS /gNC   2'70.CO"t-_RS	LE-NC-TH CF PERIOD;    24.00 HRS
                              SULFUR MATERIAL  6A(.ANCE (USING PRCCESS  H2S1:	
                                                                        S 0 2
                                                                                _S C R S E R
                                       I N
                                              INLET GAS _A_S_S02
                      t  G- 13)  /  BG10A =
                                               2.5609  LE SULFUR/HR
N>
CT>
00
I
1
t
\
i
;
.
•
c
i
1
j
I
,.
I
I
!
*
t
i • — " "" ' •"
3
INLET C AS RESIDUAL
TOTAL

CUT
OUTLET GAS AS SC2
CUTLET CARBON
CYCLONE OUST
COLLECTOR DUST
CARSON hEEPAGE
TOTAL 0
6" D I A

I N
INLET CARBON
TOTAL
CUT
OUTLET CARBON
CYCLCNE OUST
TOTAL C


I N
S ( C- 1 1 i I
I N : (RV- 1C) i

{ G- 13 ,
( C- 12 t i
< 0- 111 i
< C- 12) i
(Cfe- 121 -
U T : (RV- 1C!' i
CARBON PR


t C- 12i .
I N' :  ,
U T : (RV-3CCI i
SULFUR G 1: I

,
' BC11A =
' SI10 =

r BG13A =
' 8C12A =
' BD11A =
' BD12A «
f BCU12A <•
' S010 =
E C 0 N D I T


I BC12A «
' SI 300 =

1 BC201A =
f BD301A =
t SO 300 =
•i E R A T C R


C.?8B9
3.5498

0.1610
3.3849
O.C186
C.CU9
O.CC08
3.5772
I 0 N E


3.3849
3.3649

3.3849
0.0
3.3849



LS
L6

LS
LE
LE
L8
LE
LE
R


LE
LS

LE
L8
LB



SULFUR/HR
SULFUR/H3

SULFUR/HR " •- ?
SULFUR/HR -.:
SULFUR/FR r
SULFUR/HR -,
SULFUR/HR . r
a

•
3
SULFU3/HR :
SULFUR/HR - -
-^
SULFUR/HR -
SULFUR/HR a
SULFUR/HR -
•«
,
-:
                                              IMLET GAS AS H2S  (CYL)
                                              INLET GAS AS H2S  (PRCC)
                                             _^ '- EI_CIR_B ON
                                                     T C T A  L
                                                                   1  N ;
                      {  G-2C1I / SG201B
                      <  G-2C1i / BG203R *
                     J_<>2C 1 I_/_BC201 A '
                      (RV-2CCI /  SI200 =
                                                        6.6729  L*  SULFUR/HR
                                                       __3.3349_LB_SULFUR/hR_
                                                       10.0579  LE  SULFUR/HR
                                     CUT
OUTLET GAS  AS  t-2S
OUTLET GAS  AS  SC2
CUTLET CAR3C.N
                                                   T C   A L
                                                                 OUT
                                                                             ( G-2C5 I / BG205B  =
                                                                             ( G-2C5 i / 3C-20SA  =
                                                                            _L_C- 2 C 2_)_/_B C 2 0 2A_y
                                                                             (RV-2CC I /  ~S0200  =
                                               0.2513 L2 SULFUR/HR
                                               C.3010 LE SUS-FUR/hR
                                               9.5749 LB SULFJR/i-R
                                              10.T271 L"e SULFUP'/HR
-------
                                                                     2/26/73
                                                                                  PAGE
H 2 S
         GENERA -TOR
                                    FUR
                                             STRIPPER
1;
• !
s'
.
':
i

*•

i
T,
r
I
^
a
•i
t*
J
„
„'
12
1
3
„;
•I
a
"

n
i
ij
J
J
•*•
J
1 N
INLET CAR8CN
T C T A L IN:

CUT
OLTLET CARBON
OUTLET GAS AS H2S
CUTLET GAS AS S
CYCLCNE CUST
FILTES CUST
TCTAL OUT:
OVERALL

I N
INLET GAS 18" UNIT AS SC2
INLET GAS 8" UNIT AS CYL H2S
TOTAL
CUT
OUTLET GAS 18" UNIT AS SC2
CYCLCNE CUST 18" UNIT
COLLECTOR DUST 18" UNIT
CARBCN ViEEPAGE 18" UNIT
CYCLCNE CUST 6" UNIT
CUTLET GAS 8" LNIT AS H2S
CUTLET GAS 8" UNIT AS SC2
OUTLET GAS 4" UNIT AS K2S
CUTLET GAS 4" UNIT AS S
CYCLCNE DUST 4" UNIT
FILTER CUST 4" UNIT
TOTAL S


.








{ C-.1C2)
(RV-iC C)


( C--.C3)
I G-U4!
< G--C4!
< C-U.1)
( C-U21
(RV-iCC)
S t L 1 U


1 G- 1CI
( G-2C1I
s u L r u

( G- !3)
< D- 11)
« C- 12)
(CV.- 12)
t C-3C1)
G-2C5)
G-2C5)
G-K4)
G-K4)
D-1C1)
0-1C2)
U L F I A











/ BC202A
/ snoo


/ SC103A
/ 6G104E
/ SC-.104S
/ eoioiA
/ BD102A
/ S0100
R B A


/ BG10A
/ 8G201B
R I N

/ BG13A
/ SOUS
/ 8012A
/ ECW12A
/ E0301A
/ BG205B
/ 8G205A
/ BG1046
/ BG104S
/ BD101A
/ B0102A
OUT












=


:s
=:
Si
=
=
L A


-
:

s
s
3
^
S
X
=
=
:











9.5749
9.5749


C.9889
6.6729
1.8583
O.CC38
0.0
9.5240
N C E


2.5609
0.0
2.5609

0.1610
C.0186
0.0119
0.0008
0.0
0.2513
0.3010
0.0
1.85S3
0.0038
0.0
2.6067











LE
LB


LB
LE
LB
LB
LS
LB



LB
LB
LE

LE
LB
LB
LB
LB
LE
LB
LB
LB
LB
LB
LB











SULFUR/HR
SULFUR/HR


SULFUR/HR
SULrUR/H.R
SULFUR/HR
SULFUR/HR
SULFUR/HR
SULFUR/HR



SULFUR/H.R
SULFUR/HR
SULFUR/hR

SULFUR/HR
SULFUR/HR
SULFUR/HR
SULFUR/HR
SULFUR/H.R
SULFUR/HR
SULFUR/HR
SULFUR/HR
SULFUR/KR
SULFUR/HR
SULFUR/HR
SULFUR/HR











-
'.
• i
•
;"l
r
'3
't
»y
-5
**
""!
v«

„
* n
s*
H
ri
•^

3
iu
bJ
c.
1
w
, t
•1
J
«J
*9
—
J
J
'";
-------
1 1
'.!
I-' .
'»;
(i
. I 	 	 	
i-
i"
u:
HYDRCGEN ."ATE3IAL BALANCE:

I N
INLET
IXLET
INLET
i^LET

S U

GAS AS H2
GAS AS I-2S (CYL)
GAS AS H2S (PRCC)
GAS AS r20
CAR3CS
TCTAL I N
L F I/ R i; 6

( G-2C3)
*< C-2C3)
! G-2C3)
( C-2:3)
', c-2;u
: IR\-2CC)
N 6 R /» T C

/ 3G2C3C =
/ BG2C3B =
/ 8G203 =
/ BC-2030 =
.' BC2Clh =
/ HI2CO =
R

C.O
c.o
0.4170
C-U52
C.4869
1.0691

LE
L2
t- r- r-
ru ru m
LS
2/26/73 PAGE 10


HYCRCGEN/HR
HYCRCGEN/hR
HYCRCGEN/HR
HYCnCGEN/r-R
HYCRCGEN/rR
HYCRCGEN/r-.S
i^
j)
:,
•.
•
i'
-,'
';! •.,'
?' CUT t»
r-
1 •
f1!
1.'


p
DLTLcT
Ci.;TLeT
OLTLcT
OUTLET
T


GAS AS H2
G1S AS H2S
GAS AS K20
CARBON
C T A L OUT

H 2 S GENE
{ C.-2C5)
. I C-2C5)
( C-2C5)
( 02:2)
: (RV-aiC)

R A T C f. / S
/ BG205C =
/ EG205h =
/ SG205D =
/ 8C202H. =
/ K12CC =

U L F U R
C.C
0.0157
C . S S C 9
0.0199
0.9166

STRIP
L8
LE
LS
LE
LB

P
hYCRCGSN/HR
KYCRCGEN/KR
HYCRCGEN/HR
hYCRCGEN/HR
HYCRCGEN/HR

E R
t
^
''•'.
:*
73
* i N y
•n
i
P
i.
£,'
i,'
H
ta

ES '
INLET
If.'LET
CUT
CLTLET
CL'TLET
CLTLET
1


GAS AS H2
CARSCN
TCTAL IN
GAS AS H2
GAS AS M2.S
GAS AS H20
C T A L OUT


< U-II3)
< C-2C2)
: (R'/-i:C)
C r,- 1 C4 J
( G-IC'V)
( G-IC4)
: ..; (R'/-1CC)


/ EG103C «
/ 8C202*- =
f nice =
/ EGIC4C =
/ EGlO^h =
/ BG.104D =
/ H01CO =


C.6C09
0.0199
0.6208
C.O
C.4170
C.1652
C.5822


LE
LE
LE
LB
LE
LH
Lfi


HYCRCGEN/HR
HYCRCGEN/HR
HYCRCGEN/HR
HYCRCGEN/HS
HYCRCGEN/HR
HYCRCGEN/HR
HYCRCGEN/H.R


•^
-4
1
-%
n
U.'
»'
• rr
•a
^
Si
=.' y
*_! • ' -j
H ' ^
»j> • ijc
'•*•' ~"
:_, ' -:


ij
I • ' ' - " • — • • — — - — -




























-
•1*

•-.
UV
-------
              APPENDIX A-12-3
EXPERIMENTAL DATA AND RESULTS FOR INTEGRAL
        RUN IR-2-6  (37 - 51 hours)
                     271
-------
                                                                                                                              4/21/74

                                       STATUS  REPORT CF OPERATING CONDITIONS  FOR 'NfEGRATEQ  CPER4TICN CF  SC2  RECCVERY PROCESS
                                                                                                                                           PAGE   1
                              C?E"-
Q
3
j|
,5-


0
I-'
(4
'-:
S02SCRBER -7
16: 2
18: 1:
22:15
2: 15
6:15
20: 32
22:15
2:15
6: 15
16:15
6:15


18:15
2: 15
1C: 15


20:26
21:26
22:53
0:45
2:15
6: 15

4:15
1 x : ! 5
HRS
HRS
H.RS
HRS
HRS
MRS
hRS
HRS
HRS
_hRS 	
hRS


HRS
HRS
r.RS


HRS
HRS
HRS
"RS
HRS
HRS

HRS
hRS
« ?C:15 HRS

it
^l



4:15

4:15
12: 15


HRS

HRS


33.60
39. CO
42.00
47. CO
51. CO
A V E
41.30
42. CO
47. CO
51. CO
A V E
37. CO
51. CO
A V E

39. CO
47. CO
55. CO
A V E

41.20
42.20
42. 6C
45.50
47. CO
51. CO
A V E
25.00
3 3. CO
41. CO
49.00
T
HRS (ET)
H'SS (ET)
HRS JET)
KRS (ET)
HRS (ET!
RAGE:
.-HRS..!E!> 	
HRS (ET)
HRS (ET)
H.RS (ET)
RAGE:
HRS (ET)
hRS (ET)
RAGE:

HRS (ET)
HSS (ET!
hRS (ET)
RAGE:

HRS (ET)
HRS (ET)
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HSS (ET)
HRS (ET)
HRS (ET)
RAGE:
HRS (ET)
HSS (ET)
HRS (ET)
HRS (ET)
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RATE:
25. CO HRS <£T)
33. CO
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HRS (ET)
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S02 CCNC INLET- FLLE GAS
S02 CCNC INLET ?LUE Ct~
SC2 CCNC INLET FLUE G£S
S02 CCNC INLET FLLE GJS
S02 CCNC INLET FLUE GiS
S02 CCNC INLET FLUE G££
S02 CCNC CUTLET FLLE G ' i
S02 CCNC CUTLET FLUE CiC,
S02 CCNC CUTLET FLUE G.':i
S02 CCNC CUTLET FLUE G/-".
S02 CCKC CUTLET FLUE G.-,';
H20 CCNC INLET. FLUE G.!.'.
H20 CCNC INLET FLUE GAf,
h20 CCNC INLET FLUE GAS

CRIFICE PRESSURE ORCP
CRIFICE PRESSURE CROP
CRIFICE PRESSURE ORCP
CRIFICE PRESSURE ORCP

ORIFICE TEMPERATURE
CRIFICE TE'-'PERATLRE
CRIFICE TENP'JRATURc
ORIFICE TEt-'PERATLSE
ORIFICE TEMPERATURE
CRIFICE TEPFERATV.RE
CRIFICE TEr-'FERATLRH
HEIGHT CYCLCNE CLST
w = 'C-:-T CYCLCN; CUST
HEIGHT CYCLCNE CLST
HEIGHT CYCLCNE CLST
' WEIGHT CYCLCNE CUST
WEIGHT CYCLCNE DUST
HEIGHT CCLLECTCR DUST
WEIGHT CCLLECTCR DLST
U=IGHT CCLLECTCR DUST
WEIGHT CCLLECTCR DUST
-------
                                                                                                                                 "i/21/74
                           12:15
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                                                                                                                         4/21/74
                                                                                                                                      PAGE  3
                                                         C 1  A
                                                                  C A R B C N
                                                                                  PRECCNDITICNER
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SQ2 CCNC CUTLET GAS
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!-2S CCNC INLET GAS
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H2S CCNC INLET GAS
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i-2 CONC INLET GAS
H2 CCNC INLET GAS
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S-2 CCNC CUTLET GAS
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r-2 CCNC CUTLET GAS
H20 CCNC INLET GAS
H20 CCNC INLET GAS
H20 CONC INLET GAS
H20 CCNC INLET GAS
H2C CCNC CUTLET GAS
H2S CCNC CUTLET GAS
H2Q CCKiC CUTLET GAS

N'2 CQNC INLET GAS
N2 CONC INLST GAS
M2 CCNC INLET GiS
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(GS-2CC) /

(GS-2C6) /
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4/21/74 PAGE 4
0.700 J (VOLUME)
0.990
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46.900
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7.500
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4/21/74 PAGE 6
49.400 % (VCLUME)
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45. CO HRS (ET)
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/ AY1CSE -

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/ G!CC(5,T! =
/ AGIQOE =

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/ ACL01A =

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50.500
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55.200
35.000
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7. £00
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                                                                                                                                 W21/74
                                                                                                                                              PAGE
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16:15 HRS 37. CO HRS (ET) CARBCN RECYCLE RATE
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S U L F L R C C

Ifc:i5 HRS 37.00 HSS (ET) WEIGHT SULFUR CCLLEC1EC
6--15 KRS 51. CO HRS !ET) WEIGHT SULFUR COLLECTED
TOTAL: HEIGHT SULFUR COLLECTS
RATE: WEIGHT SULFUR COLLECUC









•

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. .
ENTCRY HCPPER
!CS- 90) / Z90(1,T) =
.'CS- 50) / 290 (1-
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STATUS REPORT CF OPERATING CONDITIONS FOR
"i
3;
• •
OPERATING PERIOD:
CAT=: 4/21/74 TIME CF RSCCRC
CATE: 4/22/74 TIXE C~ RBCCRC
: 16:15 HR
: 0: Q H!:
IJvTEGRA
5 TO
S TC
4/21/74 . PAGE 8
TED OPERATION OF S02 RECOVERY PRCCESS
24: 0 HRS
6:15 HSS
i
:
.
'.' •
k.
PRCCESS ELAPSED TIKE CF PFRIH3:
START 37,
CC HRS
/ END 51. CO f-RS LENGTH OF PERIOD: 14.00 hRS
•' SUMMARY GF INTEGRATED PRCCESS PERFORMANCE:
—
;.

1. S02 REfCVAL

PRSC2 =

97. 7S

% (ACTUAL) 90. C ? (GCAL)
.
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t!
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%
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2. r2S UTILIZATION
3. ACID CONVERSION ( TC SULFUR)

4. 1-2 UTILIZATION (TO H2S)

5. SULFL'R RECOVERY
6. (-2 UTILIZATION 4" UNIT
FVCS '

PHChS =

P«
PUH2 =
£•2.94
{.3.99

fcO.76

C.C
c.c
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S (ACTUAL! 95.0 * (GCAL)
% (ACTUAL! 99.0 ? IGCAL)

Z (ACTUAL) 90. C \ (GCAL)

S (ACTUAL) 100.0 % (GCAL) Or SCRBEO SC2
? (ACTUAL) 25. C \ (GCAU) OF STRIPPED SULFUR
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8. CARBON RECYCLE RATE (DS!
S. ACID LCADING i.\LET CARECN 6" UNIT

1C. ."OISTURE CONTENT INLET CARSCN 6" UNIT
11. ACID LCACING INLET CARECN 8" UNIT
12'. H.OISTURE --CKTENT INLET CAR8CN 8" UNIT

13. TOTAL ACID CONVERTED 6" UNIT
14. SULFUR CONVERSION (TO K2S )
15. SULFUR CONDENSER EFFICIENCY


PAJCX EVENTS DURING OPERATING PERIOD:
BY-PASSED 18" UNIT OUST COLLECTOR
X90A =
RC90 =
X301C =

X3018 =
X302C =
X3028 »

PVC =
PSCI-S *
ERV400=


37.0 HRS.
C.C337
;<,32i
C. 2134

C.. 1411
C..2134
C.. 1411

S8.15
i;!C.63
C.O



LB S/LE C
L8 C(OE)/HR
LB ACIC/L3 C

L3 H2C/L3 C
LB ACIC/L9 C
LB H2C/LB C

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%
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-t
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b^
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PLUS GAS STARTED 37.4 hRS. AT 3 FT/SEC.
CYLINDER I-2S TC £" UNIT STARTED 4C
.0 HRS.
L, H' TC 4" UNIT STARTED 40.6 HRS.; GAS VELOCITY


:'..G FT/ScU.
„,,'
' S
                                 CFF GAS 4"""LMT GCI.\G TO BURNER
-------
STATUS REPCP.T
f'; OPERATI'.G PtSTCC:
CATS: i/j.s/74
-
P.
..•t

I ft
•: INLET
:• INLET
•-
;i
C L- T
-. C-.TLET
i' CUTLET


GAS AS S02
c AS SESICL*L s
T C T A L IN:

GAS AS S02
CARSCN
•V y CYCLCNE CUST
Vf y CCLLECTCR CUST
v-> « CARECN
=s T
H
2*
W I N
pi INLET
'35
W ' C U T .._..._
r, CUTLET
V.ESPAGE
C T A L CUT:
6" 0 I A C A


CA33CN
T C T A L IN:

CA33CN
ic CYCLC.NE CUST
=- T
1 '
k>

- i IN 	
L- INLET
U ' INLET

,^,
CUT
-. OL'TLE i
V CL'TLET
• :- CUTLET
'.- T
C T A L CUT:
S U L


GAS AS H2S !CYL!
GAS AS r2S (PRCC)
T C T A_L I N :


GAS AS H2S
GAS AS SC2
CAS8CN
C T A L 0 U _T . :

s o 2 :
( G-
( C-
iRV-

! G-
/ r~
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! C-
( C-
IC..-
(Rv-
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( C-
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( C-
( C-.
(SV-
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( G-
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13) /
11) /
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11) /
12) /
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iCl) /
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? G-?C5) /
( G-2C5) /
I C-2C2! /
1P\-
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E R
8G1CA =
BC11* =
SI 10 =

BCi3i =
3C12A =
BD11A =
B012/S =
BCW12A =
SO 10 =
CONDI


EC12A =
SI 300 =

8C201A =
60301A =
S0200 =
E R A T C R


6G2G1B =
6G203R =
3C2014 =
SI20C =


EC-2053 =
EG20SA =
8C202A =
S0200 =


2.
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3.

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3.


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LB
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L6
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SDLFUR/HR
SULFUR/HR
SLLFUR/i-R

SLiLFUR/hR
SL.'LrUR/1-R
SCLFUR/hR
SULFUR/HR
S(JLFUR/I-R
SULFliR/HR



SULFUR/hR
SLLFUR/rR

SULFUR/I-R
SULFUR/HR
SULFUR/i-R



SULFUR/!-R
SULFUS/HR
SULFUR/t-R
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-------
                                                                                                                        4/21/74
                                                                                                                                    PAGE 10
OO

H 2 S G E \
ERATCR/SL
I N
INLET CAR30N


CUT
OUTLET
CUTLET
CUTLET
CYCLCNE
FILTEP
T


i M
TCTAL I


CAR3C\:
CAS AS h2S
GAS AS S
CUST
CUST
C T A L C U
0 V E R A


INLET GAS 18" UNIT AS
INLET GAS 3" UNIT AS
T C T
CUT
OUTLET
CYCLCNE

N :


-


T :
L L


SC2
CYL H2S
A L

GAS 18" UNIT AS SC2
CUST 13" UMT

COLLECTOR CUST 18" UMT
CAR2CN hEEPAGE 18" UMT
CYCLCNE CUST 6" UMT
CUTLET
OUTLET
CUTLET
GAS 8" UNIT AS
H2S
GAS 8" LN'IT AS SC2
GAS 4" UMT AS
OUTLET GAS 4" UNIT AS
CYCLCNS CUST 4" UNIT
FILTER CUST 4" UNIT






T C T A





H2S
S.
L S





{ C-2-:2)
(Rv-i :ci


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( G-i:i)
( c-i:ii
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tRv-i:ci
S U L F L


( G- 10:
( G-2C1:
S U L F L

< G- 13!
< D- 11!
( C- 12!
-------
                                                                                                                     4/21/74
                                                                                                                                 PAGE  11
                           HYORCGEN  MATERIAL
OO
N>
V

S U L F
*
UR CENERATC
R




!;]
IN . !.|
INLET
INLET
INLET
INLET
INLET

GAS AS
GAS AS
GAS'AS "
GAS AS
CAR3CN
T C T
H2
H2S 
(RV-i:O 1
' 5G205C =
' BG20SH =
' EG205C =
' BC202H =
' H02CO =

L F U R

' 8G103C =
' BC2C2H =
' H100 =
' BG104C =
' 8G104H =
C
0
C
0
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0
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6158
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0.7855

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C
0
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LE
LB
L3
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P E

L6
~L8
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LE
LE
LS
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HYCRCGEN/HR
HYCRCGEN/HR
HYCRCGEN/HR
HYCRCGEN/HR

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HYCRCGEN/HR
HYCRCGEN/HR
HYCRCGEN/HR
KYCRCGEN/HR
HYCRCGEN/HR
HYCRCGEN/HR
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U
n
H
H
a
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18
'~i
^
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-------
              APPENDIX A-12-4
EXPERIMENTAL DATA AND RESULTS FOR INTEGRAL
       RUN IR-2-6 (51 - 66 hours)
                     283
-------
oo
                                                                                                                        4/22/74




                                     STATUS REPORT OF OPERATING CONDITIONS F0:i  INTEGRATED OPERATION OF  SC2 RECOVERY PROCESS
                                                                                                                                    PAGE
                             OPERATING PERIOD:

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55. CD HRS
59.00 HRS
63.00 HRS
67.00 HRS
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56.00 HRS
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51.03 HRS
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S
S02 CCNC INLET FLUE G,1S
S02 CCNC INLET FLUE G.sS
S02 CCNC INLET FLUE <5i»S

S02 CONC CUTLET PLUS CIAS
SQ2 CONC CUTLET FLUE GAS
S02 CCNC CUTLET FLUE CAS
S02 CCNC CUTLET FLUS GAS
S02 CCNC CUTLET FLUE CAS

H20 CCNC INLET PLUS G >S
H20 CCNC INLET FLUE SAS
H20 CCNC INLET PLUS MS

B E R

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0.0
0.0
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4/22/74 PAGE 2 ]
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                                                                                                              4/22/74
                                                                                                                         PAGE   3
                                                6"  0  I A
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25.600
23.12C
24.210
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8.200
8.000
8.100
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1.950
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59.30 HRS (ET)
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SI.CO :-SS (ET!
AVERAGE:

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H2 CONC INLET GAS
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N-2 CQ\C INLET GAS
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                                                                                                                                      PAGE  7
                                                                CARBON
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                                                                                          T  0  R  Y
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17:15 HRS 62.00 HP.S (ET) Z RESIDUAL S CN CARET*
AVERAGE: ? R6SICUAL S CN CARECN

9:15 HRS 54-00 HRS (ET) % RESIDUAL H20 CN CAVJCN
13:15 HRS 5S.OC HSS IET) I R = $!CU£i. H2C QN CA*:CN
17:15 HRS 62. CO HRS (fT) % RESIDUAL H2C CN CA*=CN
21:15 HRS 66. C; HRS (£TI % RESIC'JiL H2C CN' C/U5CN

6:15 HRS 51. CO HRS ( ET ) CARSC^ RECYCLE PATE
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A 7 C i"^ O

C9C(1,T) =
C90:i,T) =
AC90A =
3.640
3.600
3.960
3.920
3.830

2.230
2.230
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31.000
31.000
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21:15 HRS 66. CO HRS (ET) fcEIC-H.T SULFUR COLLECTS
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RATE: HEIGHT SULFUR CCLLECTEC
{ S-4C1) /
t S-«C1) /
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OPERATING PERIOD:
CATE: 4/22/74 TIKE OF RECC

PRCC5SS ELAPSEC TIfE CF PFRICD:

RC: £:15 It.
START 51 .

4/22/74 .PAGE 8
INTEGRATED OPERATION OF S02 RECOVERY PROCESS
S TO 21:15 KRS :'

CC_HRS
SUfKARY CF INTEGRATED PROCESS PERFORMANCE:
1. S02.3S.yOV.AL._.

. 2. V-2S UTILIZiTICN
3. iCIC CCNVS'.SIC'; < TC SULFUR)
4. h2 UT!L!ZAT!CM (TO H2S )

5. SUCFLS RSCCVERY
6. 1-2 UTILIZATION 4'-.tMT

7. RESIDUAL SUIFU» ON CARBCN

B. CARECN RECYCLE RATE (08)
«!. iCIO LC»;i'.t- :-;L>T CiRSON 6" UNIT
PRS02 =

PUH2S =
PVCS =
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FRS
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X9QA =

PC90 =
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96.56

84.73
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80.76

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25. 121
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/ END £6. CO HRS LENGTH OF PERIOD: 15.00 HRS >-
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S (ACTUAL) 90.0 ? (GCAL) «
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X (ACTUAL) 95.0 S (GCAL) te'
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13. TC-»iL iCiJ CCNV5RTSD C" UMT

14. SULFLR CC.XVERSIC^ (TC K2S)
15. SULFUR CCNCENSER EFFICIENCY

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MAJCR EVENTS DURING OPERATING P6RICC: .:.
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-------
                                                                                                                             4/22/74


                                        STATUS REPORT CF  OPERATING CONDITIONS FCR  INTEGRATED OPERATION CF SC2 RECOVERY  PROCESS
                                                                                                                                         PAGE  9
V£>
OPERATING PERIOD:
TATF: 4/22/74 TIME C? RECORD

PROCESS =LAPSEC TIME CF PFRtCC:

SULFUR MATERIAL BALANCE (USING CYLI.NCER
: 6:15 H?S TO

START 51

H2S):

.CC HRS


21:15 HRS

/ END 66




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LENGTH CF PERIOD: 15.00 I-RS


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CYCLCf.E 'CUST
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9.6073
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4/22/74 PAGE 10
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VYCRC E.N/hR
HYCRC EN/1-3
^YCSC ES/l-R


HYCRC EN/i-R
KYCc.CGEN/rR
HYCRCGE?;/HR
HYCaCGEN/rS
HYCRCGEN/VR

E R

HYCRCGEN/i-R
hYCSCGEN/1-R
HYC?.CGEiN/rR
MYCRCGEN/HR
HYCRCGEN/HR
KYCRCGEN/HS
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                                                    C T
                                                               OUT:
-------
              APPENDIX A-12-5
EXPERIMENTAL DATA AND RESULTS FOR INTEGRAL
        RUN IR-2-7 (66 - 81 hours)
                     295
-------
                                                                                                                         4/22/7*


                                      STATUS REPORT CF OPERATING  CCNCITIONS FCR INTEGRATED OPERATION CF S02 RECOVERY PROCESS
                                                                                                                                      PAGE   1
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CATE: 4/23/74 T




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PROCESS VAR!A9i = «:
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CF PERICC: START tl ..CC HRS / END

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71.03 VPS
75. CO HR3
75. CO H?.S
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71. CO HRS
75. CO HRS
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66. CO .-RS
81.00 HRS
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71. CO HRS
7S.CO HRS
S7.CC HRS
A V E R A

66. bO HRS
69.10 HRS
73. CO HRS
76.10 HRS
79.CO HPS
81.00 HRS
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73.00 HRS
81. CO HRS
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S02 CCNC INLET FLLE G.'S
S02 CCNC INLET FLUE GAS
S02 CONC CUTLET FLUE K IS
S02 CCNC CUTLET FLUE G.S3
SC2 CCNC CUTLET FLUE 0.!S
SC2 CCNC CUTLET FLUE >".!S
S02 CCNC CUTLET FLUE R,SS
H20 CCNC INLET FLUE G 55
H20 CCNC INLET FLUE G 5:5
H20 CCNC INLET FLUE G IS

ORIFICE PRESSURE DROP
CRIFICE PRESSURE DROP
ORIFICE PRESSURE CRCP
CRIFICE PRESSURE DRCP

CRIFICE TEMPERATURE
CRIFICE TEMPERATURE
CRIFICE TEMPERATURE
CRIFICE TEMPERATURE
CRIFICE TEMPERATURE
CRIFICE TEMPERATURE
CRIFICE TEMPERATURE

WEIGHT CYCLCNE CUST
WEIGHT CYCLCNE DUST
WEIGHT CYCLCNE OUST
WEIGHT CYCLCNE DUST
WEIGHT CYCLCNE CUST

B E R

4: 15
12:15
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WEIGHT CCLLECTCR OUST
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L6 CUST
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PAGE  2
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                                                                                                                                            PAGE   3
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16: 15 HRS

21:56 Has
2:56 HRS
0:56 HRS
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21:15 HRS
12:15 HRS

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9:15 HRS


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4/22/74 PAGE 4. j
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32.900
29.600
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                                                                                                                                       PAGE
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23:15 HRS 68. CO HRS IET) HEIGHT SULFUR CCLLECTEC
3:15 HRS 72. CO HRS (ET) WEIGHT SULFUR CClLcCT^C
7:15 HRS 76.00 HI^S (ET) V.ESCHT SULFUR CCLUCTEC
11:15 HSS 3C.CO H-i.S !ET) USICHT SULFUR CCLLECT:.C
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                                                                                ~                                           4/22/74



                                        STiTUS REPORT CF OPERATING CONDITIONS  FC^i  I,\TEGRATED OPERATION OF S02 RECOVERY  PROCESS
PAGE  8
o
CO

r"- CPERiTIN3P?RICO:
I.,
pi GATE: 4/22/74 TI*£ CF RECCRC
i'1 CAT = : 4/23/74 TIKE CF RECCRC
: 21:15 t
: 0: 0 :-
: i
•RS TC 24: 0 HRS :
•RS TC 12:1= HRS

PRCCESS £LA?SEC TIKE CF PERIOD:
START fce.CC HRS / END 61. CO >-RS LENGTH CF PERICD: 15.00 HRS
;•: SUKXARY CF INTEGRATED PRCCESS PERFORMANCE:
ta
ft 1. SC2 REfCVAL
'",
H: 3. ACID CONVERSION ! 70 SULFUR)
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>>. 4. t-2 UTILIZATION ( TC H2S>
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!• 5. SLLFLR RECOVERY
f;
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» 6. ^ UTILIZATION 4" UMT

PRS02 =

PVCS =

PI-CHS »

FRS
FUH2 =
'i
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96.29 3 (ACTUAL) 90.0 * (GCAL)

94.31 Z liCTUii.) 55. C S -:CCAL)
81.66 % (ACTUAL! 99. C ? (GCAL) •-
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78.56 I (ACTUAL) 9C.C ? (GCAL)
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97. 4C -i (/.CTUAL) iCO.C S CC-CAL! OF SGS3HC SC2
33.20 % (ACTUAL: 25. c % (GOAD CF STRIPPED SULFUR
KO.CO %
pj ;i
tJ 7. RESIDUAL SULFUR CM CARECN
! t • ' "" , , ...
F--
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p 9. ACID LCACISC- IMLET CARECN 6" UNIT

W 1C. COISTURE CONTENT INLET CARBCN 6" UNIT
p 11. ACID LOADING IMLET CARECSv 8" UNIT
t- 12. "OISTURr CONTENT INLET CARSCN 8" UNIT
ps
i. 13. TOTAL ACIC CCNVEPTEO £" UNIT
;.-: 14. SLLFUR CCNVC-SSICN ITO H2S1
i
15. SULFUR CONDENSER EFFICIENCY

X9CA -
RC90 =
X301C =

X3013 =
X202C »
X3028 =

FVC »
PSCI-S =
EP.V40C-

C.C513 L8 S/LE C ;«
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C.2158 LB ACIC/LB C :t
T
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C.1307 L3 h2C/L6 C =.
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'-•':• CAJCR EVENTS DURING OPERATING PERICC:
« ' S'niTCHEO TC PRCCESS H2S AT 66.4.HRS._
L V.ITH INLET PRESSURE AT 46" TC 52"
H20
43
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VI
I- SULFUR CONDENSER *>AS CN STREAH CURING PERICi:
-------
                                                                                                                  4/22/74     PAGE



                               STATUS  R=?C*T  CF  CPERATIN-G  CCNCITICNS FCR INTEGRATES CPERATICS CF 
PRCCESS ELAPSE
SULFUR V.ATFRIAI P.il 4K.

TIME" CF PERICD: STAR
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T " 46


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LENGTH CF PERICC: 15.00 hRS


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OUTLET GAS 8"
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CYCLCNE CUST 4
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                                                                                                                     4/22/74
                                                                                                                                  PAGE  11
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AS H2
AS H2S
AS H20
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H 2

GAS
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AS H2
CARBON
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-------
              APPENDIX A-12-6
EXPERIMENTAL DATA AND RESULTS FOR INTEGRAL
       RUN IR-2-7 (81 - 96 hours)
                     307
-------
                                                                                                                        4/23/74



                                      STATUS  REPCRT  CF OPERATING CCNCITICNS FCF  INTEGRATED  CPERATICN  OF  SC2  RECOVERY  PROCESS
                                                                                                                                    PAGE
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OPERATING P£R!CO:
	 	 CATE: 4/23/74
V
CATE: 4/24/74
TIME CF RF.CCRC:--. 12:15 i-?.!; T:
C 54: 0 HRS :'
TIME CF RECCRC: 0: 0 HRS TO 3:15
PRCCESS SLAP'SFC Tl'fF CF PFRTCD: START- PI .rr na<; / FKT
PRrcs.ss v:aiiP'p<; PTR PPI



15: S
18:15
22:15
2:15
15:20
18:15
22:15
0:32
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12:15



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HRS
HRS
HRS
HRS
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18:15
2:15

• 14:32
16:26
19:15
21:20
l: 15
3:15


12:15
20:15
4: 15



12:15


12; 15
2C:15
4:15


HRS
HRS

HRS
hRS
HSS
HRS
HRS
HRS


HRS
HRS
HRS



HRS
HSS


H3S
HRS
HRS



33.90 HRS
67. CO HRS
91.00 HRS
95. CO HRS
A V E R A
84.10 HRS
67.00 HRS
91. CO HRS
93.30 HRS
95.00 HRS



(ET!
(ET)
(ET)
(ET1
G E :
(ET)
JIETJ_
(ET)
(ET)
(£T)
AVERAGE:
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96.00 HRS (ET)
A V E R A

67.00 HRS
95. CO HRS
A V £ R A

83.20 HRS
65.20 HRS
S3. CD hRS
9C.10 HSS
94. CD H?.S
96. CO HRS
A V E R A

31.00 HRS
8S. CO HRS
97. CO HRS_
T 0 T A
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31.00 HRS
97.00 HRS
T 3 T A
RAT

SI. CO hi»S
=9. CO HRS
97. CO HRS
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(ST)
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S 0 2 SCR
S02 CCNC INLET FLLE G.'S
S02 CCNC INLET FLLE Gi S
S02 CCNC INLET FLUE G/S
S02 CCNC INLET FLLE G< S
SC2 CCNC INLET FLUE G/S
S02 CCNC CUTLET FLL'E i. AS
SC2 CCNC CUTLET FLLE CAS
SC2 CCNC CUTLET FLUE CAS
S02 CCNC CUTLET FLLE (-AS
SC2 CCNC CUTLET FLUE (.AS
S02 CCNC CUTLET FLUE Ci.'i
H20 CCNC INLET FLUE GiS
H20 CCNC INLET FLLE G.'S
H20 CCNC INLET FLUE G^S

CRIFICE PRESSURE CRC?
CRIFICE PRESSURE DSC?
CRIFICE PRESSURE ORO°

CRIFICE TEMPERATURE
ORIFICE TEMPERATURE
CSIF1CE TEMPERATURE
GRIFICc TEf-'FERATUSE
GRIF1CE TEFFERAYLRc
CRIFICE TEMPERATURE
GRIFICE TE!*PERATLRE

WEIGHT CYCLCNE DLST
V.EIGHT CYCLC.NE CLST
WEIGHT CYCLCNE DUST
WEIGHT CYCLCNE CUST
WEIGHT CYCLCNE CUST

VsEIGHT CCLLECTOR DUST
fcElGHT CCLLECTCP. DLST
WEIGHT COLLECTOR DUST
hEIGHT CCLLECTCR DUST

WEIGHT CAKSCN '.iOEPAGS
UEiGHT CARSCN WEEPAG6
WEIGHT CAR8CN WEEPAGE
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B E R
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/ YlO(l.T) =
/ AY10A =
/ Y1651.T) =
/ Y16(1,T) =
/ Y16I1.T) =
/ Yl&tl.T) =
/ Y16U.T) =
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/ YiOtl.Tl =
/ Y10(4,T) =
/ AY10C =

/ r P i o i T i -
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/ ADP10 =

/ TL101T) =
/ TLIO(T) =
/ TLlOiT) =
/ TLIO(T) =
/ TLIO(T) =
/ TLIO(T) »
/ ATL1C =

/ C01KT) =
/ C01KT) =
/ CD1KT) =
/ «D11
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/ CD121T) =
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/ k-012 =
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/ CV.121T) =
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4/23/74 PAGE 2 ]
1
0.125 IS CUST ' j
C.008 L3 CUST/HR |
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6.740
7.120
7.300
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6.740
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12:15 t-RS S.CO r'.S !£T) ? TOT S CN I .'.'LET CA3:C.. {CS-iClJ / 2301(i,T) =
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	 A V F R A G F : * THT' S CN IMET CiRFr;, (CS-301) / iVZ301* =
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4:15 HRS 97. CO HRS (ET) WEIGHT CYCLCNE OUST < D-301! / CD30KT) =
T C T S L : WEIGHT CYCLCNE CUST { C-2C1 ) / WD3C1 =
RATE: WEIGHT CYCLCNE CCST < c-3ci> / PDSOI =
12:15 HRS 81. CO HRS (ET) % TOT S CN CYCLCNE CLS" 1 0-3CI) / C30K1.T) =
3:15 HRS 96. CO HRS ( ET ! t TOT S ON CYCLCNE DL'SV I C-3011 / D1O1!1.T) =
AVERAGE: * TOT S CN CYCLCNE OUS'" 1 D-301) / AD301A =









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8.640 1 (WEIGHT)
8.560 % (WEIGHT)
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8.605 % (WEIGHT)
8.800 * (WEIGHT)
6.400 S (WEIGHT!
7.500 ? (WEIGHT)
7.567 5 (WEIGHT)

0.0 LE CUST
0.0 LB CUST
0.0 L6 CUST
0-0 IS CUST/HR
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                                                                                                                 4/23/74
                                                                                                                            "PAGE
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2. H2S UTILIZATION
3. ACiO CCNVERSIC.N I TC SULFUS)

4. H2 UTILIZATION I TO K2S)

5. SULFUR RECOVERY
6. H2 LTILIZATICN 4" tMT

7. RcSICUAL SULFUR ON CARSCN
8. CAR80N RECYCLE RATE (D6!
9. ACIO LCACING INLET CtRECK S" UNIT

10. H01STURE CCNTEttT l^aET CARSCN 6" UNIT
11. ACID LCACING IMLET CARBON S" UMT
12, C.CISTL'RE CCNTENT INLET CARBCN 8" UNIT

13. TOTiL ACIC CCNVERTtD S" U.NIT
14. SULFLR CC.\VERSIO\' iTC H2S)
15.  »
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L.J 	 SAMPLE FROM 18" UNIT UNDER POSITIVE PRESSURE

-------
                                                                                                                        4/23/74




                                      STATUS R5?CRT CF CPERATING CCNCITICNS FCR 1MEGRATEO OPERATIC* CF  S02  RECOVERY  PROCESS
                                                                                                                                    PAGE   9
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                                                                                                                                     PAGE  10
                                                    H 2 S
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                                                                                                                      4/23/74
                                                                                                                                  PAGE 11
                           HYQRCGEN MATERIAL  Bi
u>
I-1
oo

IN.
TKIPT
T OL' f C T
INLET
I\LET
INLET
CUT
CUTLET
OUTLET
OUTLET
OUTLET
T


GAS AS.
r • c * c
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CAR3CN
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CARBCIM
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H2
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r2
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FUR G = N

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HYCRCGEN/hR H,
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lj

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INLET
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CASSCN
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C T A
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H2

A L IN:
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(Rv-lfC) /
( G-1C4) /
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! G-H4J /
(RV-:tCi /
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BG103C =
EC202H =
HUGO =
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0.
C.
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-------
              APPENDIX A-12-7
EXPERIMENTAL DATA AND RESULTS FOR INTEGRAL
       RUN IR-2-7 (96 - 111 hours)
                     319
-------
                                                                                                                        4/24/74
                                                                                                                                    PAGE
CO
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1 !
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4


STATUS REPCRT CF
OPERATING FERICO:
riTF: «/24/74



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4/24/74 PAGE 6 >
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                                                                          PAGE   7
C A F, 3  C  N
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                                                                                                                                            PAGE
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                                      STATUS RSPGRT  OF  OPERATING  CCNCITICNS  fC-: INTEGRATED  OPERATION  Cf S02 RECCVE3Y PROCESS
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                                                                                                                                       PAGE 10
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                                                                                                                     PAGE  11

   NYORCGEN ViTERIAL  BALANCE:
                                           SULFL'R    GENERATOR
            J  *
                     INLET G/,S AS  H2         	t  G-2C':0  / 3G203C"=   _ 0.0 ""   lie HY
                    _!NLET_GiS AS  h2S_'!  / BC2033  ^_I_0.0     12 KYCRCGEM/i-R '
                     i'.LET GAS AS  H2S:?*CC>        ('3-2C:.V/ 2-203 "=     C. 3'i'lf IS" V.YCRCG £',/HS"
                     :N'.HT GAS AS  1-20                f  C— 2C2:l  / EG2C3D  =     G.:-A51 IS HYCRCGEN/rR
                    _:.'i:.S_T_Ci.*3C';	(  C-2C;. ;_/__6C201 h__f	C.•!05*_L2 rYCRCGEN/KR_
                            T C T  A L	I  N :	(RV-2CC)  /  Ht2CO  =     0.9917 LE~HYCRCG'EN/rR
           CUT
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	IN       _	                     	
	:'.l£T CIS AS_H2	'	(_G-li;i)_ /_BG103C_=	0.4521 12 HYCaCO£N/!-R
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           C L1  T	     .   __	       .	   	    	  	   	 .
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                   "ctTLET C*S  AS _r20	i~G-l :•'•")"/ 6G10'iC~=      'C.2'22l''_£
                          T"L T  A  L    "b'JT:      (RV- ICCi  /  hQICC' =      0.5632 L3
-------
              APPENDIX A-12-8
EXPERIMENTAL DATA AND RESULTS FOR INTEGRAL
       RUN IR-2-7 (111 - 126 hours)
                     331
-------
                                                                                                                                        PAGE   1
                                     STAr'jS 3EPCRT  CF  OPERATING CCiNCITICNS FCR  INVEGSATEO CPERiTICM  CF  SC2 RECOVERY  PROCESS
                            OPERATING  PERIOC:
                                - CATE:   4/24/7*
                                 CAT E:
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                         _TI.UE  CF RECCRC:    0:  0 HRS  TC	9:15  rRS
	PS CC EC S . E L i?SEC _T_L'H_CF__P:R_!_CD_:	_ST A Rj___1 _1_1_..0 C H RS  /  EN5_'126.CC HRS
                                                                                                                LENGTH CF  PERiCD:   15.00  HRS
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                                                                                                                             4/24/74
                                                                                                                                         PAGE   3
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17:38 HRS
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19:2e HRS
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17:36 H?.S
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19:26 HRS i_
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18: 1 5 HRS. _
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124.90 HRS (ET)
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H2S CCNC
H2S CCKC
H2S CCN'C
H2S CCNC
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INLET GAS
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INLET GAS
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INLET GAS __ _.

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H20 CC.\C CUTLET GAS
H20 CCNC CUTLET GAS

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CN INLET c*= :;c;-.
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1:15 HRS 113. CO HRS (ET)
5:15 HRS 122.00 HRS (ET)
9:15 HRS 126.00 HRS (ET)
AVERAGE:
21:15 HRS 114. CO HRS (ET)
1:15 HRS 118. CO HRS (ET)
5:15 HRS 122.00 HRS (ET)
9:15 HRS 126. CO HRS (ET)
AVERAGE:

























% TOT S CS CUTLET C*U!CN
S T:T s CN CUTLET CA^CN
S TOT S CN CUTLET CA»;!CN
? H2C CN INLET CAR8C\
% H2C 'CS INLET CAR3C\
% H20 CN INLET- C'AROC\
* H2C .CN INLET CAREC.N
Z H2C CN INLET CAR5C\
2 H20 CN CUTLET CARSIN
? H2d CN CUTLET CAREZf.
Z H20 CN CUTLET CAR2C!.
S H20 CS CUTLET CAREt;,
% H20 CN CUTLET CARS:i,
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* ACIC CN CUTLET CARECN
2 ACIC CK CUTLET CAR3CK
S ACIO CN CUTLET CAR2CIV










,









.




ICS-2CC) / 2200(1. T) =
•CS-2CC) / Z2COI1.T) =
(CS-iCO) / AZ200A =
(CS-302) / 2i:2!2-T! =
(CS-3C2I / Z2C2(2TTi =
JCS-3C2) / Z3C2(2,T) =
(CS-3C2) / AZ3C28 =
CCS-2CC) / Z200(2,T) =
ICS-2CC) / Z20C'.2,T) =
(CS-2CO) / Z2CC(2.T) =
SCS-2CC) / Z200'.2fT! =
JCS-2CC) / AZ20CE =
(CS-2CO) / Z200(3,T) =
(CS-2CC) / Z200O.T) =
(CS-2CO) / Z20C(3,T) =
ICS-2CC) / Z2CC(3,T) =
ICS-2CO) / AZ200C =




















-
•
•


4/24/74 PAGE 5
19.640 5 (WEIGHT)
19.960 ? (WEIGHT)
19.640 % (WEIGHT)
5.900 ? (WEIGHT)
&.900 J (WEIGHT)
7.900 1 (WEIGHT)
9.100 ? (WEIGHT)
7.450 % (WEIGHT)
2.900 I (WEIGHT)
2.400 S (WEIGHT)
2.800 S (WEIGHT)
3.200 ? (WEIGHT)
2.825 S (WEIGHT)
3.040 S (WEIGHT)
2.400 * (WEIGHT)
2.350 * (WEIGHT)
2.450 ? (WEIGHT)
2.560 S (WEIGHT)

























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                                                                                                                          4/24/74
PAGE
                                                   H 2  S
                                                                 N E R A TOR  /
                                                                                    tJL F U R
                                                                                                 STRIPPER
U>
u>
l: 2 HRS
21:15 HPS
4:45 HRS

6:15 HftS
23: 2 HRS
3:50 HRS
9:26 HRS

1: 2 HRS
• 21: 15 HRS
4:45 HRS
6:15 HRS
23: 2 HRS
3:50 HRS
9:26 HSS
6:15 KRS
23: 2 HRS
3:50 HRS
9:26 HRS
6:15 HRS
23: 2 HRS
3:50 HRS
9:26 HRS
18:15 HRS
9:15 HRS

20:15 HRS
4:15 HRS



20:15 HRS .
4:15 HRS


21:15 HRS
1:15 HRS
5: 15 HRS
9:15 HRS


18:15 HRS

115 HRS
93.80 HSS 
121.00 HSS (=T)
TOTAL:
RATE:

114. CO HRS (ET)
113. CO HRS !ET!
122. CO HSS !ET)
176. CO H5S !£T)
AVERAGE:

11 '..CO HRS tET)
** *?#• 0 "} ^ ^ ^ ' ^ ~ )
A V ERASE:
(-2 CCNC INLET CAS
H2 CCNC IKLET GAS
H2 CCNC SKLET GAS
HZ CC\C INLET GAS

K2 CCNC CUTLET GAS
H2 CONC CUTLET GAS
H2 CONC CUTLET GAS
>2 CCMC CUTLET GAS
H2 CCNC CUTLET GAS

N2 CCKC INLET GAS
N2 CCKC INLET GAS
M2 CCKC INLST GAS
N2 CCNC INLET GAS
N2 CCNC CUTLET GAS
N2 CONC CUTLET GAS
S'2 CCNC CUTLET GAS
N2 CGN'C CUTLET GAS
M2 CCNC CUTLET GAS
H2S CCNC CUTLET GAS
H2S CCNC CUTLET GAS
H2S CCNC CUTLET GAS
H2S CCNC CUTLET GAS
H2S CCNC CUTLET GAS
H20 CCN'C CUTLET GAS
H20 CCNC CUTLET GAS
H20 CCNC CUTLET GAS
H2Q CCN'C CUTLET GAS
i-20 CCNC CUTLET GAS
N2 IN-LET VCL FLOW RATE
N2 INLET VCL FLOS* RATE
N2 INLET VCL FLOW RATE
HEIGHT CYCLCNE DLST
hEIC-HT CYCLCNE CUST
HEIGHT CYCLCNE CUST
WEIGHT CYCLCNE OLST

WEIGHT FILTER CLST
WEIGHT FILTER CUST
fcrlGHT FILTER CUST 	 	
. W?!GHT FILTER OUST

% TOT S CN CYCLONE DUST
% TOT S CN CYCLCNE CLST
S 7DT S CN CYCLONE OUST
% TCT S CN CYCLCNE CtST
% TOT S CN CYCLCNE CLST

S TOT S CN FILTER OUST
* TCT S CN F'LTcR DL-S't
% TOT S CN FILTER CLST
(GS-1CO) / Y100(3,T) =
tGS-ICO) / Y1CC!3,T) =
1GS-1CO) / Y100(3,T) =
(GS-1CC) / AY1CCC =

«GS-108) / Y10B!3,T) «
IGS-iOS) / Y108t3,7> =
 / Y10S(4,T) =
JGS-106) / Y1C6(4,T> =
{GS-1C8J / Y1C6<4TT) =
JGS-103) / Y10S(4,T) =
5GS-108I / AYiCSO =•
( G-1CC) / G10CI5.1) =
t G-1CO! / G100(5,T) =
I G-100) / AG10CE =
< D-101 / C010KT! =
(0-101 / CD10KT) =
( C-1C1 / «0101 =
( C-101 / ftClOl =

« D-102 / C0102(T! =
( D-102 / CD1C2IT) =
( C-1C2 / v;ci02 =
? D-102 / RC102 =

( 0-1C1) / ClCl(lfT) -
! 0-101; / 0101(1, T) =
? D-lCi; / CiOiEltTi »
( D-1C1) / CICKi.T) =
1 D-1C1 ) / A0101A =

( 0-102) / CIO 2! 1,7) =
i 0-1C2 1 / C.102 i • ,7 ) =
{ 0-1C2) / AC102; =
50.600 t (VCLUKE)
51. COO J (VCLUME)
50.700 3 ! VCLUKE)
50.767 * (VCCUKE)

. 0.0 1 (VCLUME)
0.0 ? ( VCLUKE)
0.0 % (VCLU"=)
0.0 5 (VCLUME)
0.0 S ( VCLUME)

49.400 % ( VCLUME)
49.000 S (VCLUME)
49.300 J (VCLUME)
49.233 S (VCLUME)
52.200 ? (VCLU.XE!
52.200 S (VCL'JXE)
52.603 3 (VCLUME!
52. iOO % iVCLUMt!
52.425 S (VCLUME)
29.900 S t VCLUKE)
27.700 * (VCLUME!
26.300 3 (VCLUMJ)
26.500 Z (VCLUKE)
27.725 S (VCLUME)
17.600 ? (VCLUME)
19.700 % (VCLUME)
20.200 ? (VCLUME)
20.600 ? I VCLUME)
19.525 3 I VCLUKE)
1Z1.C03 CFK (7C CEG F)
121.000 CrH (7C CEG F)
121.000 CFH (7C DEC F)
0.0 LB CUST
O.COS LB CUST
O.C06 L6 CUST
O.C01 LB CUST/HR

0.0 LE CUST
0.0 LB CUST
C.O LB CUST
0.0 LS CUST/HR

2.440 3 (HEIGHT)
4.CCC 3 (HEIGHT)
'..640 ? ('.EirtHTl
3.960 ? !V. = 'GH7)
4.010 ? (SEIGHT)

0.0 S (UEIGHT)
0.0 5 l'*-IGrT)
0.0 J (WEIGHT)

"
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f
;-;
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.
-------
                                                                                                                                   PAGE
                                                             CARBON
                                                                            INVENTORY
                                                                                                 HOPPER
U>
CO
71:
1:
5:
9:


21:
1:
5:
9:

15
H<*S
114. CO
15 hRS 118. :0
15 HRS 12J.CO
1.5 hRS 	 126, CO

15
15
15
15


HRS
HRS
HRS
.HRS

A V E
" 114. CO
US. CO
12Z.CC
126. CO
A V E
HSS
HSS
H3S
R A
HPS
H5S
HSS
"R A
(ET)
I=T>
(ET)
J ET 1 	
G E :

(ET)
(ET)
!ET)
1ST)
G E :
^ RESIDUAL S ON CARBCN
S RESIDUAL S CH CAR3CN
s RESIDUAL s CM CARECN
t RESIDUAL S CN CA38CN
t RESIDUAL S CM CARBCN

% RESIDUAL H2C
S RESIDUAL H2C
t RESIDUAL H2C
* RESIDUAL H2C
% RESIDUAL H20

CM CARECN
CN'CASSCN
ON CAR6CN
ON CARECN
ON CARECN
?CS- 9C) /

T (WEIGHT) [i
I (WEIGHT) \'
— - I,
! (WEIGHT) 1.
? C«EIGHT)
? (ViEIGHT) '•
* ('.EIGHT) j.
S (WEIGHT) t>
iij
18:
9:
15
1.5
HRS
HRS
111.00
126. CO
A V E
HRS
HRS
R i
IET)
G E :
CARECN RECYCLE
CAP8CN RECYCLE
CAR3GN RECYCLE
RATE
RATE
RATE
1 C- 90) /
J C- 901 /
1 C- 901 /
C901I.T) =
C90(1,T> =
31.000
31.000
31. COO
L8 KAT'L/HR M
LB. PiT'L/HR --i
LE ^AT'L/HR ft
T«






S U L
FUR C C N
DENSER


•;?
'-^
22:
2:
6:
15
15
15
10:15




HRS
HRS
HRS
HRS


115.00
119. CO
123. GO
127.00
T

HRS
HSS
HSS
"HRS
0 T
R A
(ET)
(£T)
IET)

A L :
T E :
WEIGHT SULFUR
WEIGHT SULFUR
WHTGH.T SULFU3
HEIGHT SULFUR
WEIGHT SULFUR
WEIGHT SULFUR
COLLECTEC
COLLECTEC
CCLLECTEC
CCLLECTEE
CCLLECTEC
CCLLECTEC
S-401) /
S-401) /
S-401) /
S-401) /
S-401) /
S-401) /
S40KT) =
S401IT) »
S40K7) =
S40HT) =
. HS401 =
RS401 =
0.0
7.000
6.750
7.200
21.050
1.754
LB SULFUR j..
LB SULFUR *,
L6 SULFUR j,
LB SULFUR ij
L8 SULFUR ;V
L3 SULFUR/HR ~4
"*
a
sJ
-------
CO
Co
vo
f 	
I
4 •
•*• \
v
STATUS REPORT CF OPERATING CONDITIONS FC!
f'| OPERATING PERIOD:
>>'. CAT*: 4/24/74 TIME CF RPCCR£: 18:1? :
«'.
is!"
V
6
ni
\>L
CATE: 4/25/74 TIHE-DF RECCRC: 0: C :



PROCESS ELAPSED TIKE CF PERICO:
v
4/24/74 PiCE 8 '
: INTEGRATED OPERATION CF SC2 RECCVERY PROCESS i
i
•RS TC.
rRS TC

START lli.CC WRS
24
• 0 HRS
-.
9:15 HRS


END" 126.00 VRS LENGTH CF PERICO: 15.00 hRS
.
,
SUCVARY GF INTEGRATED PROCESS PERFGRKAMIE:

1.

S02 RSPQVAL

FRS02 >

•55. 3C

2

(ACTUAL) SO.C I (C-CAL)

-
?» - . -r
K
W
ft
N
s
w
2.
3.

4.

5.
6.
h2S UTP IZATICN
AC 1.0 CCXVERSICN (TO SULFUR)

H2 UTILIZftTICN (TO HZS )

SU.FLR RECOVERY
h2 UTILIZATION 4" UNIT
FVCS -

PH.CHS -

FRS '«=
FUH2 "
?9.B5
72.73

67.36

' 79.01
27.93
ICC. 00
X
2

X

 ?S.C % (GCAL)

JACTUiL) 50. C t CGCSLJ
,
(ACTUAL) 1CC.C * IGCAL) OF SGRBEC SC2
(AC'UAL) 25.0 S C GCAL ) OF STRIPPED SULFUR

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c:-
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P
LJ
k-
U
7.
8.
RESIDUAL SULFUR ON CARBON
CASSCS RECYCLE RATE (CE)
9. ACIO LOADING INLET CiREC.N 6" UNIT

10.
11.
12.

13.
14.
15.







MOISTURE CONTENT IMLET CAR2CN 6" UNIT
ACIC LCACI.NG INLET CARSCti 8" UNIT
KBISTURE CONTENT INLET CARBCN 8" UNIT

TOTAL ACIC CONVERTED 6" UNIT
SULFLR CCM/ESSICS -TO HZS)
SULFUR CONDENSES EFFICIENCY


KAJOR EVENTS DURING OPERATING PERIOD:
PILCT PL^NT PLJCEC ON STAKC3Y AT
129.6 !-RS. TC CORRECT CARBON FE'EC
AT STG 6 CF THE 4" UNIT.

X90A »
RC90 »
X301C *

X301B "
X302C -
X302B -~

PVC
PSCI-S '
ERV400-



PR03LEM


C.C42S
2S.C44
C.2159

C.1C13
C.2I59
C.1C.13

84.36
£4.45
179.64






LB
LB
L3

LS
LB
LS

t
%
%






S/LE C
C!CB)/KS
ACiC/LB C

1-20/LE C
ACIC/L3 C
1-20/L8 C










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STATUS REPORT CF OPERATING CCNCITIONS FCft INTEGRATED OPERATION CF SC2
OPERATING PERIOD:
CAT": 4/24/7* TIME C?"*£CCSC:
CATS: W2S/7* TIKE CF RCCCRC:

PRCCESS ELAPSED TIME CF PERICD:
18:15 !JSS
0: 0 HRS

START 111. CC
TC 24: 0 HSS
TC 9:15 KRS







HRS / END 126. CC fcRS
'i/2'./7<. PAGE
RECOVERY PROCESS



9

,
•;
LENGTH CF PcRICC: 15.00 HRS .,
SCLFUR K4TESI«U BALANCE (USING PRCCESS -H2S) :



! N
INLET GAS 4S S02
INLET C AS RES10U«L S
T C T A L IN:

CUT
OUTLET GAS AS SC2
OUTLET .CARBCN
CYCLCNE CUST
COLLECTOR OUST
C*RECh SEEPAGE
TCTAL OUT:
6" D 1 A C A


S 0 2 S C
( 6-' 13)
< C-- 11)
IRV-- 10)

I 6- 13)
1 C- 12)
C C- il)
t D- 12 >
CCfc- 12)
1RV- 1C)
R B 0 N P


R B E R
/ SGlOi =
/ BC11A =
/ SI10 =

/ BGI3A =
/ 3C12A =
/ SOU A *
1 8012A '
1 ECW12A =
/ SOIC =
R E C 0 N D I T



2.3257
1.2431
3.572E

0.1095
3.29C3
0.0133
O.C
O.CC04
3.^135
I C N



LE
LB
LB

LE
L3
LS
LS
LB
L6
E R



S'JLFUR/hR
SULFUR/HR
SULFUR/:-R

SULFUR/HR
SL'LFUR/l-R
SULFtS/l-R
SULFUR/FR
SULFUR/HR
SULFUR/HR

T
= 3
•1

('<
(J
--
"I
V


t<
^
_'
L, ~ • _,'
* IN - =
P
to
^
PS
i
S*
a* •
t '
to
r'
	 •- • •" • ••'
'**
1 ;• '
5 -
j..
Lr
Ui
U
•-
INLET CARSON
TCTAL IN:
CUT
OUTLET CARBON
CYCLCKE GUST
TCTAL OUT:
S U L

I N
ISLET GAS AS H2S (CYL)
INLET GAS AS S2S (PRCC)
INLET CARSON
TCTAL IN:

CUT
CUTLET GAS AS H2S
OUTLET GAS AS SC2
CUTLET CARBON
TCTAL OUT:
( C- 12)
• 1RV-3CC)

< C-2C1)
< C-301)
IRV-3CC)
FUR G E


1 G--2C1)
( G-2C1)
! C-2C1)
UV-2CC)


( G-2C5)
( G-3C5)
( C-2C2I
(U--2CO
/ BC12A =
/ SI300 =

/ EC 201* =
/ 80301A =
/ S0300 =
N E R A T C R


/ BG201S =
/ 3C203R =
/ BC201A =
/ SI200 =


/ 3G2055 =
/ 8G205A =
/ 8C202A =
/ S02CO =
3.2903
3.2903

3.2903
0.0
3.2903



0.0
5.2043
3.29C3
8.5952


O.C070
C.2491
7.7806
LE
LS

LE
LB
LS



LB
L8
LE


r- r- r*
m to n>
LE
SULFUR/HR
SL'LFUR/HR

SULFUR/HR
SULFUR/KR
SULFUR/HR



SULFUR /HR
SULF'JR/HR
SULFUR/hR


SULFUR /HR
SCLFUR/HR
SULFUR/HR
SULFUR/HR
-S

23
y
>
!o
U
U1
:'l
/U
-s
*,
:-'
H

fi
-------
4/24/74
PAGE 10

fi
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H
i,,
p
e
K
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H
H
ij
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H
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u
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34.
i .
i .
L
P

P=


U
i!".
L
i
H2S GENERA!
IN-
INLET CARBCN . -
T C T A L IN:
•
CUT
OUTLET CARBON
CUTLET GAS AS H2S
OUTLET GAS AS S
CYCLCNE CUST
FILTER CUST
TCTAL OUTt
OVERALL

I N
INLET GAS 18" UNIT AS SC2
INLST GAS B" UNIT AS CYL H2S
TOTAL
CUT
OUTLET GAS 18" LSIT AS S02
CYCLCf^E CUST 18" UNIT
COLLECTOR DUST IS" UffIT
CARBCN WEEPAGE 18" UNIT
CYCLCNE DUST 6" L'.NIT
CUTLET GAS 8" LNIT AS_H2S.._.
OUTLET GAS 3" UNIT AS SC2
CUTLET GAS 4" UNIT AS H2S
CUTLET GAS 4" U.'ilT AS S
CYCLCNE CUST 4" LMT
FILTER CUST 4" U.NIT
TOTAL S












r o R / s u i
i C--2C2) /
MRV-1CC) /
«

C--1C3) /
G--1C4) /
G- 1C4) /
D- 1C1) /
C-1C2) /
(RV-1CC) /
S L '. F U R


( G- 1C) /
( G--2C1) /
S U . F U R

J G- 13) /
Q- 11) /
3- 12) /
CVr- 12) /
0--3C1) /
G-2C5) /
3-:2C5.) /
G--IC4) /
G-1C4! /
C-iCl) /
C-1C2) /
U L r- U R











-
.FUR
8C202* =
SHOO =


BC103« =
BC-104B =
BG104S =
B010LA =
S0102A =
S0100 =
B A L J


8G10A =
EG 20 IE =
I N :

BG13A =
BD11A =
ECK12A =
E03C1* =
BG2053 =
8G205* =
EG104E =
3G1C4S =
BD101* =
60102* =
OUT:












STRIPPER
7.5244 L8 SULFUR/H.R
7.5244 LB SULFUR/HR


1.2431 LS SULFUR/HR
5.2248 LB SULFUR/HR
1.7542 Lfi SULFUR/HR
C.QOOO LE SULFUR/HR
C.O LB SULFUR/HR
8.2022 LB SULFUR/HR
> K C E


2.3297 LB SULFUR/HR
C.O L8 SULFUR/HR
2.2297 13 SULFUS/HR

0.1C95 LH SULFUR/HR
0.0133 LB SULFUR/HR
0.0 LB SULFUR/HR
O.C004 LB SULFUR/HR
O.C LB SULFUR/HR
O.C070 LE SL'LFUR/HR
C.2491 LS SULFUR/H.R
C.O LS SULFUR/HR
i.7542 L2 SULFUS/HR
G.CCCC L3 SULFUR/KR
C.O LB SL'LFUR/HR
2.1335 LS SULFUR/HR











_
1
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                                                                                                                                   PAGc  11
U>
i
j HYC3CGEN MATERIAL BALANCE:
i
!'•

Is1
:•
i'!
»»
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\*'
H
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r
r"1
»-
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73
v<
t-i
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I N
IMLET
INiLET
I?iL£T
INLET


•: u T
OLTLcT
CUTLET
CUTLET
DLTLET
T

I N
s u

GAS AS H2
GAS AS H2S JCYL)
C-iS iS H2S (PRCC)
GiS AS H2C
CAP3CX
TOTAL IN


GAS AS H2
GAS AS K2S
GAS AS H20
CAR3C.N
C T A L CUT
H 2 S GENE

INLET GAS AS H2
INLET
CUT
OUTLET
OUTLET
OUTLET
T
CASSON
T C T A L IN
GAS AS H2
GAS AS H2S
GAS AS H20
C T A 1 OUT
L.f U R C E
. •
t G-2C3J
( G-2(31
( C— 2C3)
! C— 2C3)
:  m ru

LE
LS
LS
LS
P
"L8
LE
LE
LB
LS
IB
LE
j
•' \
\
KYCRCGEN/HR
HYCRCGEN/HR -:
HYCRCGEN/rR
HYCRCGEN/HR t.
.1

HYCRCGEN/HR .>
KYCRCGEN/H-R -<
HYCRCC-E.V/HR •..;
KYCRCGEH/HR »•?
'.»
E R W
i_'
HYCRCGEN/HR al
HYCRCGEN/HR i.;
HYCRCGEN/HR '-,'
HYCRCGEN/HR '-j
HYERCGEM/HR ~i
HYCRCGSX/I-R k.
HYCRCGEN/HR ;,J
^ • 3S
-3
5-i S-'
BS
3-
1 ,










,







ZS
^

-'
U -=

M
-------
              APPENDIX A-12-9
EXPERIMENTAL DATA AND RESULTS FOR INTEGRAL
       RUN IR-2-8 (144 - 148 hours)
                     343
-------
                                                                                                                              PAGE  1
-C;
                                STATUS REFCRT CF CPERATING CCNCITICNS l:C-:-t  INTEGRATED OPERATIC* CF SC2 RcCCVERY PROCESS
/; 	 ~
i i
ii.
I4;
'j;
OPERATING PERIOD:
CAT=: 4/?t/74



PRCCESS


ELAPSEC TIfE
TtHE OF XECCRC: 3U '. HRS TC 7U5


CF PERIOD: START 14-V.CC hRS / ENO
HRS







I4S.CO HRS LENGTH CF PERtCC: 4.00 HRS
*•
if
PROCESS VARIABLES
FCR OPERATING PERICC:
v>
*•«
s?
)-;
i •
S-'
T*
!;
j2
a
LV
r1.
rs
S-
H
a

JS

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i/-'
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4:33
10:26

4:38
10:45
3:15
7:15


9:15
3:15
5:15
6:15
7:20
•4:15
12: 15

4:15
12:15


4:15
12:15



4:15
12:15

4:15


HRS
HRS

HRS
H.RS
HRS
HRS


HRS
HRS
HRS
HRS
HRS
HRS
HN»

HRS
HRS


HRS
HRS



HRS
H.RS

HRS
12: 15 HAS


145.40
151.20
A V 6

145.40
151.50
A V E
144.00
148.00
A V E

15C.CO
A V =
144.00
146. CO
147.00
148.10
A V E
145. CO
153. CO
T
145.00
153. CO
T

145.00
153. CO
T


145.00
153- CO
A V E

145. CC
.1.5 3. CO




HSS (ST)
HRS (ET)
RAGS:

HRS
HRS
=! A
"HRS
R A

HRS
R A
HRS
"HRS
HRS
"HRS
R A
..HRS
HSS
C T
R A
.HRS
HRS
0 T.
R A
HSS
HRS
G.T.
R A

H?.S
R A
HRS
HSS

JET)
(ET)
G E :
!ET>
(ET)
G E :

(ET)
G E :
(ET)
(ET)
(ET1
IET)
G E :
fET)
(ET)
A L :
T E :
(ET)
(ET)
i L :
T E : ..
(ET)
(ET)
A L :
T E :

(ET!
(ET)
G £ :

i£T)
(ET)
S C 2 SCR

502 CC'-.'C INLET r-Llt GJS
S02 CCNC iXLET FLLE G.SS
S02 CCNC INLET FLLE C aS

S02 CCNC CUTLET FLLE C-AS
S02 CCNC CUTLET FILE GAS
SC2 CCNC CUTLET FLLE C-AS
H20 CC-.'C INLET FLUE GtS
H20 CCK'C INLET FLUE G&S
1^20 CCNC INLET FLLL cos

CRIFICE-PRESSURE CfCP
CRIFICE PRESSURE 01 CP
CRIFICE TENFFRATU*!1
CRIFICE TEMPERATURE
CRIFICE TEfPERATLRi:
ORIFICE TEfFERATURi;
ORIFICE TEKPERATU*-:
WEIGHT CYCLCNE CUS f
WEIGHT CYCLC'NE CLSf
WEIGHT CYCLCNE CUSf
WEIGHT CYCLCNE DLST
WEIGHT CCLLECTCR DJST
WEIGHT COLLECTOR C'JST
WEIGHT CCLLECTCR CJ.ST
WEIGI-T CCLLECTCS CUST
HEIGHT C4RBCN WEEP«1E
hEIC-HT C*ReCN '.-rtEFA.'E
WEIGHT CARSCN WEEFA,;E
HEIGHT CARBCN KEEFAiJE

3 TOT S C.N CYCLC.1'E i^L'ST
1 TCT Z CN CYCLC.VE :-LST
S TCT S CN CYCLC^.£ '.'LET

S TOT S CN CCLLEC'Q-.l CLST
% TCT S CN CCLLEC'C.5 CUST
>» m* r r-v /" m i zr~ r-,"t r- 1 CT
B E R

!GS-
£GS-
(GS-

 /
i: : /
li 1 /

12) /
12) /
•• '• •> \ I


Y1C11.T) =
Y10I1.TJ =
AY10A =

Yl&tl.T) =
Y16C1,T! =
AY16*
Y10I4.T1 =
AY10D =

CPIO(T) =
AOP10 =
TLIO(T) =
TL101T) =
T| 1 T f T 1 =

TL10(T) =
ATL10 =
CD1KT) =
CDH(T) =
•KD11 =
RD11 =
CD12IT) = ,
CC12!T) =
WC12 =
SO 12 =
CW 1 2 ( T ) =
CVJ 1 2 '. T ! = .
KCV-.12 =
RCK12 =

Cllli-T) =
D i i ; i , ~ : =

C1211.T) =
C12il,T) =
*•>'?£ =




2COO.OOO PPH (VCLUKE)
1975.000 PPf (VCLUC.E)
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                                                                                                                       4/24/74
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INLET GAS AS h2S (CYL)
INLET GAS AS H2S tPROC)
INLET CARSON
TOTAL IN':

CUT
OUTLET GAS AS h2S
CUTLET GAS AS S02
CUTLET CAS8CN
TCTAL CUT:

{ 0-2C1)
1 1.-2C1)
( C-2C1)
t-!"-ZCC)


{ G-2C5)
( G-2C5)
t C-2C2)
1 t'--2CC)

/ BC2013 =
/ BG2C3R =
/ 3C201* =
/ SI2CO =


/ 3C205E =
/ S02CO =

0.0 LE SULFUR/hR
5.5679 LE SULFUR/t-a
3.3638 LE SULFU^/HR
3. 9367 16 SULFUr/hR

_
C.C07A LE SULFUR/i-R
3.2615 LB SULFCR/hn
8.1A44 L2 SULFL.R/HR
6.4133 L3 SULFUR/i-R
I?
a .... — ...... . ... .
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Oi
f 	 	 	 	
i
T:
*
.i'
••
'i
,t
f'
S
'7
w


-li
/ J

a
w
H
F*
s*
e»'
3>
'«
'. ' f
b*
-^,
fc
1^
r':
, 	 -.
lo
L-
1 1 	 . 	
1 r 	 	 — • 	
r'
. 	
H2S GEKERA
I N
INLET CAR^C?C
TOTAL IN: '

CUT
CUTLET CARBON
CUTLET GAS AS H2S
CUTLET C-AS AS S
CYCLCNE CUST
?ILT£R CUST
TCTAL CUT:
OVERALL

t N
INLET GAS IS" UNIT AS SC2
INLET GAS 8" UNIT AS CVL H2S
TOTAL
CUT
CUTLET GAS 18" UNIT AS SC2
CYCLCI\E CUST 18" L'NIT
COLLECTOR CUST 16" UMT
CARSCN V.EEPAGE IS" UNIT
CYCLCNE C'JST 6" LMT
CUTLET GiS 8" UMT AS H2S
OUTLET GAS 8« UNIT AS sc2
CUTLET GAS A" UNIT AS H2S
CUTLET GAS 4" UNIT AS S
CYCLCNt CUST 4" UNIT
FKTER CUST 4" LMT
TCTAL S










TOR/ S U L
t C-2C2) /
(RV -ICC) . /


1 C-1C3) /
( G-1C4) /
r G-lCn) /
( C-iCI) /
( C-IC2) /
(R'i--lCC) /
S L .FUR


( C— 1C) /
( C— 2C1) /
S '- . ? U R

( C— 131 /
i t- 11 > /
{ r- 12} /
(CV- 12) /
( [ -3C1! /
t C-2C5) /
i C- C5) /
( G- C4) /
( (.- C4) /
< L'-- Cl) /
'. t:-!C2) /
U L r U ft
,









F L R
SC2026
SI1CC


SC103A
3G104B
EG10R


SUS.FUR/i-3
SULFUR/t-R
S^,L^l.'i^/^?.
SULFUR/1-R
SULFUR/l-R



SULFUR/HR
SULFUR/I-R
SULFUR/l-S

SULFUR/hR
SULFUR/hR
SULFUR/rR
SULFUR/HR
S'.LFL'R/l-a
SULFUR/i-R
SULFUR/i-R .
SCLFUR/rR
SULFUR/hR
SULFUR/HR . •
SULFUR/t-R










\
•
'.

.
-



. -
"1
•j,
••
'-,
«
72
-t
:4
-'

r.
3,
Zl
^
,
;,
-
•-T
f-
a
-E
-»
.-
-t
-------
u>
t
1 HYD*CG£N MATERIAL BALANCE:
> S U L F
»3_ _
'•; IN
• = ' iNLET GAS AS H2
INLET GAS AS 1-2S (CYL)
'"' INLET GAS AS H2S (PRCC) -
I'' INLET GAS AS H2C
':•: IN' £T CARSON
-.-. • T C T A L I N :
:;i
;r CUT
?* OUTLET GAS AS H2
\i. OUTLET GAS AS H2S
p OUTLET GAS AS >-2C
'•. OUTLET CAR3CN
TCTALOUT:
\\
t'-.
'••- H2S GENERA
U IN
p INLET GAS AS H2
'si INLET CARBON
U.
~ - CUT
-.-. CUTLET GAS AS H2
i. CUTLET GAS AS H2S
to1 CUTLET GAS AS 1-20
e-- TCTALOUT:
r I
S-.
;s
'fc:
U



f=

L; R G E

t (,-:>C3)
( c-;:c3)
( c;-;!C3)
( G-,!C3>
( >;jci)
{RV-:!CC>


I C-;!C5)
< G-.2C5)
( :-.?c2)


T 0 =. / S U

< G-IC3)
( C-JC2)
CRV-1CC)
< C-1C4)
J G-1C4)
1 C-1C4)
iP'-lCC)









N E R A T C R

/ BG203C =
/ 8G203B =
/ BG203 =
/ 8G203D =
/ BC201H =
/ *I200 =


/ SG205C -
/ EG205H =
/ EG205C =
/ BC202H =
/ H3200 =

L F t R S

/ BG103C =
/ BC202H »
/ HIiOO =
/ BG104C «
/ BG104H =
/ SG1040 =
/ i-OICO =








4/26/74 PAGE 10


0.0 LE HYCRCGEN/1-R
O.C LE HYCRCGEf
-------
             APPENDIX A-12-10
EXPERIMENTAL DATA AND RESULTS FOR INTEGRAL
       RUN IR-2-8 (148 - 156 hours)
                   354
-------
OJ
Ui
     Ci
                                                                                                                      4/26/74


                                    STATUS REPORT Cr OPERATING CONDITIONS F:!R  INTEGRATED  OPERATION  CF  SC2 RECOVERY  PROCESS
                                                                                                                                  PAGE
I
!«:
OPERATING PERIOD:
CiTE: 4/26/74


TTJ'5 OF RSCCRC: 7:15 HRS

TO 15:15 HRS



':
.
•••: PROCESS ELi?S=C TtVE OF PERIM: START K.S.CC HRS / END 156. CO HRS LENGTH CF PERIOD: 8.00 HRS ;.
ft .
jti

PROCESS




',
VARIABLES PCS OPERATING PERICC: . !•
fi . >
i'= SC2SC-RBER
'**; ••
P
W

••»
L,'
10:26 «tS
14:26 HRS
13:15 HRS


10:45 hRS
14:32 HRS
IS: 15 H.RS
151.20 HRS (ET)
155.20 HRS (ET)
159. CO HRS (ET)
AVERAGE:

151.50 HRS (£T)
155.30 HRS (ET!
159. CO HRS !ET)
AVERAGE:
S02 CC.NC INLET FLUE 'iS
S02 CCNC INLET FLUE i..*S
S02 CCNC I.NLET FLUE 3*3
S02 CCNC INLET FLU'E 5*S

S02 CONC CUTLET FLUE GJS
SC2 CCNC CUTLET FLUE GiS
502 CC.NC CUTLET FLUE GJS
S02 CCNC CUTLET FLUE CAS
(GS- 1C) /
tGS- 1C) /
(GS- 10) /
tGS- 1C) /

!GS- 16) /

TOTAL:
SATE:
(-20 CONC INLET FLUE 0-KS (sTJ
161. CO K-S ;£Ti
WEIGHT CCLLECTCR OUST
WEIGHT CCLLECTCR OUST
WEIGHT CCLLECTCR OUST
WEIGHT CCLLECTCR CUST

WEIGHT CiRSCN WEEPiCE
WSIGH.T C/..-.ECN V.SEPiCE
V.EICKT CiRSCN '.vEEPtCE
WEIGHT CARECN W'ErP;C =

* TCT S CN CYCLONE CUiiT
S TCT S C.N CYCLCNS CUI-T
I TCT S C.S CYCLCKE CU5.T
( 0- 12) /
1 D- 12) /
5 D- 12! /
< C- 12) /

!CW- 12) /
:cv.- 12: /
«.Cl.- 12) /
-------
        f»



        (r

        I ;—
        h«
                                                                                                                            
-------
Ul
                                    _I51.CO. .KS

                                      4 V S S
 6"  OIA     CARBON

	?_JCT__S_.CN_ INL.ET

:    S TCT S  CN I'.'LET
                       _1C:15 Has	151.CO HRS  1ST)
                       _.1«:15 HRS	155.CO I-^S  (6T>
                       _1S_:15 HRS	153.00
                        2C:15
                         7:15  HRS
                        15:15  hR5_
  A V E S A G  6  :

__153.-0 !-.s!S..!cTi__
 161.00 J-RSjl£TJ	
"	T_C T_Ali_:	
       R"A T  £ ;

 148.CO rSS  (ET!

  A~~ v" 'E~T'~A~G' e'T"
     i H2o"oN"i\LEt"CARBON"
     S H20 CN  INLET CARBCN
     V h20~CV INLET ""
    _V.ZIGHT  CYCLC.'JE DUST	
    J»EJGHT_CYCLCKE CUST_J__
    _hEIGKT  CYCLCN'E'DUST   ' '
     ME IGh77~C'Y'Cl"CN£ DUST    "

     s  TOT s C.N CYCLCKE CLSV
    _S_T07_S C^_C^CLCNS_OLS"
     X  TO'r S~CN CVCLCNE DUST"
4/26/7* PAGc 3
PRSCONCITICNER
iCS-iCl) / Z3GU1,7) = 9.080 3 (WEIGHT)
iCS-30;! / Z3CI;l,TS = 9.niO ? ttiEIGH.T)
(CS-3C1) / AliOIi » 9.470 ? (kEIG^T)
(CS-3C1) / Z3CH2.T! = 7.000 S («£IGt-T)
ICS-3C1) / i3CH2,T) = 7.000 Z (UEIGHi)
{CS-3~1) / £331(2. T) = 5.603 S (V.EIGHT)
(CS-3C1) / AJ301E = 6.533 5 !V.£;GI-T)
{ D-3CI5 / CD301iT: = 0.0 L3 CUST
S D-301) / CD3:i:T! » 0.0 LS CUST
I D-30U / K3301 = 0-0 LS CL'ST
( C-3C1J / RD3C1 = C.O LS CbST/hR
r C-3C'n / DSOltltT) = C.O S thEJGhT!
S 3-3CI) / CSQUl.t) = C.O % {hilGhTJ
1 C-301) / AD30Li = 0.0 S IhEIC-HT)













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13:32 HRS
.. 14:56 HRS
	
13:32 HRS
., 14:56 HRS
13:32 HRS
14:5fc HRS


13:32 HRS
14:56 HRS


13:32 HRS
7:15 HRS
15:15 HRS


1C: 15 H~S
14: 15 HRS

10:15 HRS
14:15 HRS
13:15 HSS
10:15 HRS
14: 15 HRS
18:15 HRS
10:15 HRS
14:15 HRS
18:15 HRS

10: 15 HRS
14:15 HRS
IS: 15 HRS

154.30
A v E
155.70
V e
" 154.30
A V E
15.5*70
A V E
154.30
A V E
155.70
A V 6

154.30
A V t
155.70.
A V =

154.30
A V E
IAS. 00
156. CO
A V E

155.00
i V E

151. CO
155. GO
159. jO

151. CO
155.00
15?. CO
A V £
151-00
155. CO
159. CO
A V £
151. DO
155. CO
159.00
A V E
HRS 1ST)
RAGE:
HRS !ET)
AGE:
HRS 
HSS ;ET; . .
rRS (ET)
RAGE:
S02 CCNC CUTLET GAS
S02 CCNC CUTLET GiS
H2S CCNC INLET GAS
H2S CCi>C INLET GAS
H2S CCNC CUTLET GAS
H2S CCNC CUTLET C-iS
H2 CGNC INLET GAS
H2 CCNC INLET GAS
H2 CGNC CUTLET GAS
H2 CCN'C CUTLET GAS
H20 CC.NC INLET GAS
H20 CONC INLET GAS

H20 CONC CUTLET GAS
H20 CCriC CUTLET GiS
N2 CCNC INLET GAS
N2 CCNC INLET GAS

N2 CONC CUTLET GAS
N2 CCNC OUTLET GAS
M2 IN'.ET VCL FLO* RA" =
N2 INLET VCL FLC'rf RATE
N2 INLET VCL FLGH RJ"E

Z TGT S CN INLET OSKSCN
s: TOT s CN I::LET C^P-::CN
X TOT S CN INLET CiRHCN

? TOT S CN- CUTLET C^=, tC\
% TOT S CN CUTLET CJI'.cCv
S TCr S Ci\ CUTLET C^-.£C<
% TCT S C.\ CUTLET C^KEC>
% H20 CN INLET CARBCIi
% H2C ON INLET CARSC:.
S H20 CN INLET CARSC.\
% H20 CN INLET C.1RBC.-;
S H2u CN CUT'.cT CAR2CI
? H20 CN CUTLET C*R3::r
S J-20 ON CUTLET CARB^
? H2C ON CUTLET CAR3'^
S ACID ON' CUTLET CA3:LN
? AC!D CN CUTLET C*' :CN
* ACIC CN CUTLET CA?3llN
% ACIC ON CUTLET CARKN
(G?-2C6)
iGS-2Ci!
!GS-20C)
(GS-2CO)
SGS-2C6)
1C-S-206)
{6S-2C01
JGS-2CC)
(GS-2C6)
(GS-2CO)
(GS-2CC)

tGS-206 )

(VCLUHE)
(VCLU«E)

(VCLUHE)
(VCLUME)
FK !7C CEG F)

:
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1
4
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n
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CFH !7C CEG r)
CFH (7C CEG F) -•

i
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s
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I '« EIGHT)
! WEIGHT)

(V.EIGHT)
!WcIGHT)
(HEIGHT)
("EIGHT!
(WEIGHT)
IViEIGHT)
(-EIGHT)
(weiGHT;
(hEIGHT)
(HEIGHT)
(HEIGHT)
(HEIGHT)
(l-EIGHT)
(V.EIGHT)
(V.EIGHT)
..

Z*
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VO

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1

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7
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*
7:15
8: 8
12: 8
14:32

7:15

3: 3
12: 8
14:32
8: E
12: c
14:32
HR.S 	
HRS
hRS

HRS

HRS
HRS
H^S
«?.s
hRS
H.RS
8: £ r"*S

-
-^
~
^
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•si
=;
12: a
14:32

7:15
15:15


12:15
2C:15
hRS
H-;S

H.RS
HRS


HRS
HXS
143.00 HRS
A V E S A"
148.90 HRS
152.90 HRS
155.30 HRS
A V = R A
14S.CC i-P:S
A V E R A

148.90 HRS
152.90 HRS
155. 20 >-?s
A V E S i
I*.1:. SO *-^S
152.^0 rSS
155.30 HRS
A V E R A
152.50 'rSS
A '] = R A
i-'-3.CO HsS
156. CO HRS
A V ERA

153. CO HRS
iil.CO HRS
TOT
R A
K 2
tET)
G E :
SET)
(ET!
(ET!
G E :
(£T)
G £ :

«£T)
(2T)
C E :

; £- )
(ET)
(ET!
G E :
(£T)
?£T)
C, E :
C£T>
G E :

(ET)
iET)
A L :
T F. :
S GENERATOR /SUL
H2 CCNC- INLET GAS
\-Z CCNC INLET GAS
1-2 CCNC CUTLET EAS
H2 CCNC CUTLET GAS
H2 CCNC CUTLET GAS
F2 CCNC CUTLET GAS
N2 CCNC INLET GAS
N2 CCNC IKLET CAS

N2 CONC CUTLET GAS
N2 CCNC CUTLET GAS
.":2 CCVC CL7LET GiS
.'<2 C~-v" CUTL-T GJS

H2S CCNC CL'TLST GAS
H2S CCKC CUTLET CAS
F2S CCKC CUTLET GAS
H2S CCNC CUTLET GAS
r20 CCNC CUTLET G.'-S
5-20 CCKC CUTLET GiS
H20 CC.'-C CUTLET GAS
H2Q CCKC CUTLET GAS
N2 IN:LET VCL FLCH RATE
"2 INLET VCL FLCr. P.ATE
N2 INLET VCL FLC'« RATE

WEIGHT CYCLCNE CLST
V.rlGHT CYCLCNE CL-ST
V.EI3HT CYCLCNH ELST
WEIGHT CYCLCNE DLST
FUR S
?GS-1CC! /
iGS-ICO! /
(GS-1C6) /
{GS-108! /
«GS-10S) /
(GS-1GS) /
(GS-iCO) /
i
•^
--
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                                                               C A
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;:
1C :is K.RS ]'. • ,,-n (.?<; ipT)
li:15 r'.S 159. 'JO >-?$ t")
• V c ? »- c -
" R E5IC
« :-.£S r.
UAL s CN CARS:?
•J.'L s c;-; c>?.=:f
UAL s c-i C"^;:
!CS- 9C / Z=C!1,T) =
scs- -"C / Z'.cii.r; =
•:cs- ?c / ;•:'.•::. ,T 5 =
CCS- 9C / A:-;:a =
3. SCO
4.iiO
4.c£v
« ! 'A E I G H T )
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1 !V<3IGhT;


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_... 10:;? H?.S isi.-f! HR« (-T)
14:15 HR5 15K.CC HRS (ET)
18: 15 H».S 15S.CO !-RS <£T)
t v S " i G t :
7:15 r-RS 14S.C.O t-%3 !37)
15:15 f~.S 156. CO !-».S i£7)
AVERAGE:


1C:!5 H?.S 151. CO H3S !ET!
14:15 V-RS 155. CO HRS (£T)
15:15 S^S 156. CO r=.S itT!
20:20 H.RS 161.10 HRS IcT)
0:15 HRS 165. CG HRS (ET)
3:15 MRS 168.00 HRS tET)
T n -r ^ i .
1 Si I A t. '
RATE:
•



™ R5SIC
Z RESIC
L'AL H2C CN CA^fCv
UAL H2C CN Ci5.;C«
S RESiDUiL H2C CN C4SfC:\
3  / LI <1 i ft 1 —
C S-4CU / RS4C1 =




2.230
2.230
2.230
2.2ZC
71 ' ' "-
31. COO
31.000


0.0
3.700
13.300
4.200
5.CCC
3. CCO
2.024




? HEIGHT)
? ISEIGHT)
t i. -EIGHT)
LE iv^T'L/HR
L3 J-'AT'u/HR
LS XAT'L/rR


L3 SULFUR
LE SLLFUS
L2 SULFUR
LS SULFUR
LS SL'L'UR
L3 SULFUR
1 Q ' ' i[ CMO
LS SULFUS/HR




:




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ON
j
STATUS REPORT CF OPERATING CCNCITICNS FCR
r-: OPERATING PERIOD:
>: CATE: */2c/7A TlCt CF RECCRC: 7:1= H!
.1
•- PRCCESS ELAPSEC TK'c CF PERIOD: START 14 =

r-.
'»' SUXyiRY CF INTEGRATED PRCCESS PERFCRKANCE:
* 1. S02 RHyCVIL P-RSG2 =
•
ir 2. H2S UTILIZATION Pl)h2S =
'=.; 3. ACID CGNVESSICri (TO SULFUR) PVCS =
':i 4. 1-2 UTILHATICN 1 TC H2S ) PhCi-S =

;•« 5. SULFUR RECOVERY PRS
'f.'
t-. 6. V-2 UTILIZATION A" UNIT PU'S-2 =

W 7. RESIDUAL SULFUR CN CARSON X90A =
!_ j '
fc- 8. CASECN RECYCLE RAT= (CE! RC90 =
1 .
t 9. ACIO LCACIK-- INLET CARSCN 6" U.MT xsoic =
y
i« 1C. MOISTURE CCKTEKT INLET CARBCN 6" UNIT X301B =
to'
H 11. ACID LCiDING ISLET CARECN 8" UNIT X302C =
U 12. KOISTURS CC'.TE\T INLET CA^aC?>: £" UMT X302B =.
I;
a 13. TOTAL AC'" CC\VFRTFD S» UMT • PVC

jc; 1«. SULFUR CCNVcSSICN (TO H2S) PSCt-S =
C 15. SULfUR CCNCENSER EFFICIENCY £RV4CO«

n
• ; MATS FV=\TS CURING" CFERATING PERIOC:
Li 	 "
CUT CN C02 TD 40 CFH IN 4" UMT AND
'J REDUCED N2 TC 66 CFh AT 148.1 MRS.
U ATTEMPT TO TURN STEAM CN TO 4" UNI.I...AI ..
IXJ 150.3 !-*S. UNSUCCESSFUL DUb IU LKUlU.H^iO IN
\J 	 STEAV LIME. ELEX SULFUR FRCV RfcCl^UULAI Ii-.^
4/26/7A PAG; 7
INTEGRATED OPERATION CF S02 RECCVERV PRCCESS ,
i
S TC 15:15 HRS

.r'-i VR<; / p\n i?&.co HRS LENGTH CF PERIOD: e.oo FRS .,
i
:t
56.03 ? (ACTUAL) 9C.O ? (GCAL) '>

57.80 Z (ACTUAL! "55. C 31 (GCAL)
il.99 % (ACTUAL) ??.C t (GCAL)
iC.90 ? (ACTUAL) 90.0 3 (GCAL)
-
33.34 * (ACTUAL) 1CC.O S (GCAL) OF SCRBED S02
3C.75 3 {ACTUAL 3 25. C S (GCAL) CF STRIPPED SULFUR
ICC. CO S
;;
C.C467 LB S/LB C ::
T.
2E.957 LS C:C£I/HR W
C.2637 LB ACID/US C
:,-
C.C916 LE H2C/LB C
W
C.2637 LB ACID/LE C
C.C926 L3 h2C/LS C :,
t-;
64.17 % -i
z*
72.87 % -.
113.32 2 ;
.,
;.,
<;
t ;
„
r
PCT TG CVERFLCV. ?Ct 	 "' 	 ^
-------
                                                                                   4/26/74




STATUS REPORT CF OPERATING  CCNCIT1CNS FCP-  INTEGRATED CPER4TICN CF S02 RECCVCRV PROCESS
                                                                                                PAGE   S
r. 	
I •
ll
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-------
             APPENDIX A-12-11
EXPERIMENTAL DATA AND RESULTS FOR INTEGRAL
       RUN IR-2-8 (156 - 168 hours)
                     365
-------
                                                                                                                                    PAGE
                                     STATES REPCS.T CF OPERATING CCNCITIONS  FC:  INTEGRATED GPERATICN: CF SC2 RECCV'SY PROCESS
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CATS: <./ 27/74

PRCCESS ELAPSE: TIME
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(VCLUME) i;1
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(VCLUKE) «
(VCLUVE)
(VCLUXE) '-i
! VCLUHE) ,1
:-y
(VCLUHE)
(VCLUME)
73
(VCLUWE) :•
(VCLUME) .-=
(VCLUME) ri
(VCLUME) _-;
(VCLUMEI ;,
(VCLUME) r
(VCLUHS)
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(VCLUME) ;,
(VCLUHE) :,
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(VCLUME) J
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CFH (7C CEG F) ^
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(V.EIGHT)
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(XEICHT)
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                           2:15
                                 h'.S
                          22: 15  -RS
  A V E  S  i  5 6  :

J55.CO  I--.S  (£Tj	
 155.CO  rSS'i'ET)
 153.:3  r3S  1ST)
_157.CO _(-?S_lST5
...X.'V .-  s  i  G E ^-_

J55.CO  HS"JET)~
 15?.co  i-=:s  JET;
 153.CG  r^S  IET}

~i V E~H~A~~5"'£  :
                                                              ?  f-ZC CN  IN'LET C/SS6CN
_S_H2D_C\  CUTLET
 S -r2C CN~CU7LET"CAR8t.\
 * -1-2C CN  CUTLET Cs3.SCv
_?_!-2C CN'  CUTLET C.'-
JS_*C I P_CN_CUTl. = T_C A R E : N
 S AC'i'C  CN CUTLET  '
                                                                                                iCS-302)  /     AZB025  =

                                                                                               JCS-200 )._/_:2CO ! 2, T 1 _=_

                                                                                                (CS-2CC!  .
 JCS-2CC>_ /_    iJ2CCE  =

JCS-2CC!_/_Z2CO!3,T)  =_
 1C S-2C C 1" /" Z 2C 0 ! 3, T )" =
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 'CS-2CC?  /  ZiCCiB.T)  =
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                                 3.100 ?
                                "3.2CC ?
                                 2.7CC ?
                                                                                                                                         (*>EICHT>
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                                                                                                                                3.500 3  i »£!GrT)_
                                                                                                                                3.E2C ?  IVEIGt-T)
                                                                                                ICS-2CC)  /
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                                  _
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o
        w
        L,r
-------
                                                                                                                       4/26/74
                                                                                                                                   PAGE
                                                  H  2  S
                                                           GENERATOR/!. JLFUR
                                                                                               STRIPPER
                      17:15 HR
                                                       H2  CCNC INLET GAS
CO
16:20 H9S
19: 15 H1RS
20:24 HRS
21:38 HRS
17:15 HRS


16:20 r-?S
19:15 HkS
2C:2t HRS
£ !.- 2. >i r"^ S
0:15 HRS
1:15 rR S
3:15 HRS
16:20 HRS
19:15 HRS
20:2i HRS
3 i * "3 ;> ijO C
3: 15 HRS _


16:23 HRS
15:15 rRS
20:26 HIS
21:3= HRS
•0:15 -RS
1:15 HRS
3:15 HRS
15:15 H.R3
3:15 HRS


20:15 hRS
3:15 HRS


20:15 HRS
3:15 HRS

14:15 HRS
15:15 HRS
22: 15 rRS
2:15 HRS
AVERAGE:'
157. 10 HRS (ET!
16C.CO H'RS !£T)
161. 2C HSS (ET!
162.40 HRS 1£T)
AVERAGE :
153.00 H"
TOTAL:
RATE:

161.00 HRS iET)
153. CO HRS (ET)
TOTAL:
RATE;

155.00 HRS (5T>
15S.CO H:'.S (ET)
16!. CO HRS !JT)
167. CO HSS tET)
!-2 CCNC INLET GAS
H2 CC\C CUTLST G4S
H2 CCNC CUTLET GAS •
H2 CCNC CUTLET GAS •
H2 CCNC CUTLET GAS
H2 CCNC CUTLET GAS
N2 CCNC I.NLET GAS
N2 CCNC INLET GAS

N2 CCNC CUTLET GAS
NZ CCNC CUTLET GAS
N2 CCNC CUTLET CAS
M2 CCK.C CUTLHT GAS
\!2 CCNC CUTLET GAS
N2 CONC CUTLET GAS
N2 CONC CUTLET GAS
N2 CCNC CUTLET GAS
H2S CCNC CUTLET GAS
H2S CCNC CUTLET EAS
I-2S CCNC CUTLET GAS
t-?^ (" f* N: *~ f" ! ' T 1 P T f* fi %.
H2S CC.NC CUTLET CAS
H23 CCNC CUTLET GAS
H2S CCNC C'JTLET GAS
H2.S CCNC. CUTLET GAS _.

H2C CCNC CUTLET G&S
H2C CCNC CwTLET GAS
H2C CC.NC CUTLET GAS
H20 CCNC CUTLET GAS
H20 CCNC CUTLET GAS
H20 CCNC CUTLET GAS
H20 CCNC CUTLET GAS
H20 CCNC CL'TLET GAS
N2 INLET VCL FLCX RAT£
•;2 INILET VCL FLCV- RATE
iN2 INLST VCL FLCV. RATE

SvEIGHT CYCLCNE CLST
HEIGHT CYCI.CNE CLST
V.EIGHT CYCLCNE CLST
WEIGHT CYCLCNE CLST

WEIGHT FILTER CUST
WEIGHT FILTER CLST
WEIGHT FILTER CUST
HEIGHT FILTER CUST

3 TOT S CN CYCLCNc CLST
% TCT s CN CYCLCNS OLST
2 TC" S CN CYCLCNE CL£"
% TOT S CN CYCLCNE CLS'
«CS-iCOi /
tGS-lCE) /
iGS-icaj- /
SGS-1CS! /
C'G S"~ I G £ ) /
CGS-1CC! /
JGS-1CC) /

CGS-106! /
(GS-1CS! /
C'C-S-IOS) /
JGS-10S) /
(GS-103! /
(GS-10S) /
(GS-10E) /
(GS-10E! /
rGS-lOE) /
iGs-ioai /
fi^C 1^31 /
I3S-1CE) /
(GS-iO£! /
JGS-108! /
(GS-lCe! /

(GS-1021 /
iGS-lCE) /
JGS-iCc! /
•GS-ioa; /
(GS-10e) /
(GS-103) /
SGS-ioe: /
1SS-1C ! /
( G-1C ) /
! S-1C ) /
: c-ic ) /

< C-IC ) /
1 C-IC ) /
! 2-10 ! /
t C-1G ! /

5 D-1C2) /
{ 0-102) /
J 0-1C2! /
5 C-102) /

I C- 1 C 1 ) /
< C-ICi) /
c c-ioi ;• /
t o-io: ) /
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Y1C6(3,T !
YlGSJ2tT)
Y1CS!3,T !
AY10SC
Y10DI5.T!
AY1CCE

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YlC3(r, T)
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Y i06 \ 5 1 i 1
Y108i5,Ti
Y1C3(5,T)
Y1GS(5,T)
AYlOcc
Y1C3;2,T!
Y1CS(2,T)
Y1C8(2,TJ
Vl^S*1? f * "
T i-.j O t £ s I /
Y10S!2,T)
Y108(2,T)
AY108B

YJ03 ( 4, T I
Y^I i^'I1
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YiC8x4,T)
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V.'DIOI
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CCi02(7)
RD1C2

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C1C 1(1,7)
C1C1U.T •
= 4E.500 ' ;VCL'JVE)
C.2GC S SVCLUXE)
0.0 S t VCLUME)
= 0.0 J ! VCL-JKE)
C.O ? (VCLUME)
C.050 ? (VCLUME)
51.500 S (VCLUME)
51.500 S (VCL'J."£)

56. COO ! (VCLC^E)
52.400 ? (VCLUX.E!
= 54.200 S (VCLL'ME)
53.2CO ? (VCLUMS1 .
52.50C ? !VCLUHE)
= 54.100 ? t VCLUME)
52.600 t (VCLUME)
53.571 ? (VCLU.Vc)
23.300 (VCLUME)
•= 25.600 (VC4.lJC.EJ
24.4CO t VCLUME)
— 1 ^ i.^^ ' /\'f"ll!>^Cl
= 26.100 ;VCLU;-;E)
= 24.100 (VCLUKE)
. 26.100 (VCLUME1
*> 25.029 (VCLUCE)

22.400 (VCLUKEJ
24. ICO (VCLLJKEJ
23.4GC- S ! VCLUME)
= 23.300 % (VCLUME)
= 21.000 * (VCLUKE)
= 21-400 % (VCLUME!
21.000 ? (VCLUHE)
22.371 S (VCLUME)
127. OCO C?H (7C C=G F)
127.000 CFH (70 CEG F)
= 127.000 CFH (70 CEG F)

0.0 L8 CUST
0.0 12 CUST
C.O LS CUST
C.O IS CUST/HR

O.C LS CUST
= G.O LE CUST
= 0.0 LS CUST
O.C LE CUST/HR

» 4.t6C S (VcIGH.T)
4.t2C % (WEIGHT)
= 4.;~0 ? («=IGHT) ;
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j

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                                                                                                                                      PAGE

                                                        I TCT S  CN  CYCLCXE CLST         ( D-lCl)  /    A315XA »       A.490  S  (hEIGHT)
                                                        JLJCT_JS_?1_?1»J5
-------
                                                                                                                              4/26/7*.
                                                                                                                                           PAGE
U>
~J
CJ
14-.ll
13:15
22:15
2:15


14:15
13:15
: 22:15
2:15

H.RS
HRS
HRS
h?5_
HRS"
HRS
hRS
HRJ

155. CO
159. CO
16 2. CO
157. CO
t V E
" 155.00
159. CC
163. CO
167. CO
A V E
hRS
t-=!S
r-, S
R. -
f-RS
l-RS
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(ET)
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S E :'
C A R 8 C N i ^ V
3 R=S!D'JAL s CN c*.'.ec:\
* >e$!Cu*'L s CN c^secs
S RESIDUAL S CN CAR3C;\

S RtSlCUAL H2C ON CARSC!-
* RESIDUAL H2C CN CJRHLM.
% RESI3U4L H2C CN CiRcUi
t S-SiCU'L H2C CN CiR2'>

E N' T C R Y
(CS- 90) /
CCS- 90) /
;cs- ^c:- /
!CS- 9C) /



15:15
3:15
HRS
HRS
156.CO
lfc3.CC
A V t
HRS
•r'r.*
R A
t JT )
G~S :
CA^ECN RECYCLE RATE
CA33CN RECYCLE RATE
CiRSC\ RECYCLE RATE
( C- 90; /
! C- 90) .'
i C- 90 > /
C9D 1 1 » t i
C90'. 1,T !
=
IT
=
31.000
31.000
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SULFUR CO
N C E N S 2 ft




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14:15
15: 15
2C:15
. C : 1 5
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-
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hRS
HRS

hRS
HRS

15;. CO
155. CO
156.00
161. CO
165. CO
163. CO
T
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h^S
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•-.SIGi-T SULFUR CCLLECT;-.
*EIGriT SULFUR CCLLECT=":
V.HIGI-T SULFUR CCLLECTE:
V
-------
                                     STATUS REPCRT OF  OPERATING  CONDITIONS FCR INTEGRATES OPERATION Cf SC2 RECOVERY  PROCESS
CO

'
OPERATING PERIOD:
C6TE: 4/24/74 TIME CF RECCRC:
CATF: 4/27/74 TIX= 2F RFCCRC:
15:15 H
AS TC 24". 0 HRS

0: 0 h^S TO 3=15 HRS
.:

PROCESS ELAPSED TIKE CF PERIOD:
START 156
.CC hRS / END 166. CO rRS LENGTH CF PERICD: 12.00 hRS
SUHVARY CF INTEGRATED PROCESS PERFCRCANCE:

••,

1. S02 RE.-CVAL

PRSC2 «

95.14 ? (ACTUAL) 90. C 31 (GCAL)
..
t
•3

•- •:'
'':•
r.
--


•~
2. r2S UTILIZATION
3. AC 10 CCNVERSICN I TO SULFUR)

4. (-2 LTILIZATICN ( TC H2S)

5. SULFUR RECOVERY
6. (-2 UTILIZATION V U'HT
PU!-2S *
PVCS =

PHCl-S -

PRS
PU!-2 =
ICC. CO S (ACTUAL! 95. C ? (GOAL)
63.69 % ? ACTUAL! 99. C 5 (GCAL)

62.46 * (ACTUAL) SC.C S (GCAL)

88.08 % (ACTUAL) 1CC.C S (GOAL) CF SCR3EC SC2
33. 2C ?. (ACTUAL! 2S.C S (GCAL) OF STRIFPEC SULFUR
c c . g 3 5;
;
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7. RESICUAL SULFUS ON CAReCN
3. CAR5CN RECYCLE RATE (DB)
?. ACID LCACING I\L=T CARECN 6" UNIT

1C. XCMSTURE CONTENT INLET CAR3CN 6" UNIT
11. ACID LCACUiC- INLET C«ECN 81: Ur: I T
b2. ."Q! STL-RE CONTENT T.NLET CARBON 8" UNIT

13. TOTAL JCIC CONVERTED 8" UNIT
1*. SULFLR CC^VE?3iC^f 1 "C- *2S S
i?. iLiFLS CCN--ENSER EFFICIENCY

X9CA =
RC90 *>
X3C1C =

X301S =
X3C2C =
X3023 =

PVC =
PSCi-S =
ERViCG =

C.C431 LS S/LE C
Zfi.917 LB C«DE5/HS
C.2159 LB ACIC/L3 C

C.C932 L3 P2C/LE C
C .215S L3 iCI:/LE C
C.C932 LB H.2C/L3 C
.
75.96 S
SC.7C Z
172.04 S



•*

.,
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77
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fijCR EVENTS DURING OPERATING PERICC:
f'j- c"? cc2 TC •»•' u>;r~ :
-------
                                STATUS SzPCRT CF OPERATING CCNCITKNS PCS INTEGRATED GPER2TIC.X C? SC2 RECCVERY PROCESS
CO
OPERATING PERIOD:
futfi 4/2t/?4 TIVE QF RECCRC: 15:
CATE: 4/27/74 T;*E Of RECCRC: o-.

PRCteSS SLAPSEC TlYE CF PERICD: START
SULFUR MATERIAL BALANCE (USING PROCESS h2S):


S 0 2
I N
INLET GAS AS S32
INLET C AS PESIDUAL S
T C T A L IN:

CUT
CUTLET GAS AS SC2
CUTLET CiRSOi
CYCLCKE CUST
CCLLECTCR OUST
CtReCfv V,EE?AG£
TCTAL CUT:
6" OiA CAR30

I N
I.NLET CAR3CN
TCTAL IN:
CUT
OUTLET CAR6CN-
CYCLCNS CUST
TCTAL OUT:
S U L F U

I N
INLST GiS AS I-2S (CYL)
!.\LET GAS AS r2S (PftCC)
INLET CiR3CfJ
T C T A I IN:

CUT
CLTLET GiS i.5 H2S
CUTL3T US ii SC2
CUTLET C-3.-,CN
T C T i L OUT:
15 HRS
0 HRS

156. CC
-


S C :
( G- 13)
( C- 11)
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t G- 13)
( C- 12)
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( C- 12)
(CV,- 12)
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< C-2C1)
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! G-2C5!
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/ 3G1CA
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/ 3012A
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/ 3C12A
/ SI3CC

/ .SC201 A
/ SC3G1A
/ SC30G
S = R a


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/ KG2G3R
/ SC2C14
/ SI20C


/ 2G2C52
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LENGTH CF PERICC: 12. CO HRS




SULFUR/H*
SL.'L.CUR/HR
SLLfUX/HR

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SL.LFUR/I-R
SULFUR/l-R
SULFUR/f-R
SULFUS/HP.
SULFUR/hR



SvLrUR/1-R
SULFUR/HR

SULFUR/t-R
S'uLFUR/hR
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SLLFUR/l-R
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CUTLET CiRBCN
OUTLET GAS AS 1-2S
CUTLET GAS iS S.
CYCLCNc uUST
FILTER CUST
TOTAL OUT:
OVERALL

I .N
INLET GAS IS" UNIT AS SC2
INLET GAS 8" UNIT AS CVL H2S
TOTAL
CUT,
CU'TLET GAS 18" LNIT AS SC2.
CYCLCNE CUST 18" LNIT
COLLECTOR CUST 13" UNIT
CARBCN XEEPAGE 13" UNIT
CYCLONE CUST 6" UNIT
CUTLET GAS 8" UNIT AS H2S
OUTLET GAS 8" UN.IT AS SC2
CUTLET GAS 4" UNIT AS H2S
CUTLET GAS 4" UNIT AS S
,C'YCLC\E CUST 4* UNIT
FILTER CUST 4" LNIT
T G T A L S
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( C-H2!
U_ L'F I! R

/ SI10C =


/ BC1C3A =
/ BGLO^S =
c 01 C i /i ~
/ b0102A =
/ SC100 =
R B A L A


/ SG10A =
/ 6G201E =
R IN:

/ BG13A =
/ B011A =
/ ED12A =
/ 8D3C1A =
/ BC-2058 =
/ EG2C5A =
/ BG1CAS =
/ EG1C4S =
/ 3D1C1A =
/ 3D102A =
GUT:
7.
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1.
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SULFUR/f-R
SULrUR/HR



SULFUR/HR
SULFUR/HR
SULFUR/t-R

SULFUR/HR
SULFUR/HR
SULF'JR/i-R
SL'LFU'R/i-R
SULFuR/J-R
SU'LFUR/V-R
SULFUS/rR
SULFUR/l-R
SLL?ljR/t-R
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-------
                                                                                             <./26/74
                                                                                                         PAGE  12
HYORCGE^ fATESIAL  BALANCE:
                                    SULFUR     CEKERATCR
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              APPENDIX A-13





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                                                                  CHARLESTCII  SESZAHC.I C7LIIT7
-------
                            APPENDIX A-14
           LITERATURE SURVEY  FOR RECOVERY OF SULFUR
                       BY  SOLVENT EXTRACTION
I.   SULFUR RECOVERY -  REVIEW ITEMS
     1.   Berthelot, Ch. Recovery of sulfur in the coke plants in Germany.
             Genie Civil 113, pp. ^01-6 (1938).

     2.   Berthelot, Ch. Recovery of sulfur in coal-carbonization plants
             and petroleum refineries.  Genie Civil  116, pp. 6-7 (19^0).

     3.   Brabant, M. Desulfurization of (town) gas and sulfur recovery
             processes.  J. usines Gaz 6k, pp. 33-^3, ^9-56, 69-75 (19*4-0).

     k.   Brabant, M.  Desulfurization of gas and processes for recovery of
             sulfur.  Schweiz. Ver. Gas-u. Wasserfach.  Monats-Bull. 21, pp
             26-30, Ul-2, 96-100,
     5-  Bulian, W.; Dittmar, A., and Feher,  F.  Removing elementary sulfur
            from natural gas.  Erdoel Kohle, Erdgas, Petrochem. 20 (12),
            pp. 849-52 (1967).

     6.  Evans, E. C. et al-Special study of  sulfur removal and recovery
            from fuels.  J. Inst. Fuel 29, pp.  138-9 (1956) .

    *7«  Goar, B. G.  Today s sulfur recovery processes.  Hydrocarbon Process.
            1968, U7(9), PP. 2^8-52.

     8.  Grosskinsky, 0.  Recovery and utilization of nitrogen and sulfur pro-
            duced in coal carbonization.  Bergbau - Arch. 5/6, pp. 1^6-52
            (19^7) .

    *9.  Kronacher, H. K.  Modern Desulfurization Processes in Germany.
            Gas-Age Record 68, (2), pp. 37-56 (1931)-
 * Filed in Charleston Research Center
       Translated into English

                                  388
-------
 10.  Lissner, A.  The importance of the sulfur of coal in the German
         raw-material economy.  Tech. Niederdonau 1, 197-9, 218-21
*11.  Lorenzen, G.  Purification of Gases with Special Attention to
         Desulfurization and the Recovery of Sulfur.  Chem. Fabrik
         12(1,2) :6-23 (1939).
 12.  Muhlert, F.  Recovery of by-product nitrogen and sulfur in the
         coke-oven and gas industries.  Brennstoff-Chem., 10, pp. 1*87-
         90 (1929).

*13.  Powell, Alfred R.  Recovery of  sulfur from fuel gases.  Ind. Eng.
         Chem. 31, PP- 789-96 (1939)-

  14.  Rosendahl, F.   Recovery of coke-oven gas products.   Oel u. Kohle
           ver. Petroleum, 36, pp.  229-^3 (19^0).

  15.  Secchi, I. M.   Recovery of sulfur from coke-oven gases.  Chim.
           e industria (Italy) 19,  187-91 (1937).

 *l6.  Sweeney, E. L.  and Sands, A.  E.  The removal of free sulfur
           from spent oxide.   Gas Age - Record 779  pp. 657-62 (1936).

  17.  Thau A.  Extraction and utilization of fuel-gas sulfur.  Z. Ver.
           deut.  Ing.,  Beiheft Folge 1938, no. 3, pp. 8l-6.

  18.  Wagner, P.  Utilization of spent oxide from gas works.  Rev.
           Prod.  Ghim.,.2U, pp.  397-^ (1921).
                                 389
-------
II.   SOLVENTS  FOR SULFUR EXTRACTION

      A.   Ammonium Compounds

              1.   Aoki, T.; Morikawa, M. and Akiyama, Y. to Sumitomo Chem.
                     Co.  Recovery of sulfur from hydrogen sulfide.  Japan
                     patent 582,626.  April 12, 1958.

              2.   Collin, F. J. A-G.  Extraction of sulfur from fumes con-
                     taining hydrogen sulfide.  British patent 7^8,037-
                     April 18, 1956.

              3.   Gluud, W., Schonfelder, R. and Riese, ¥. Purification of
                     sulfur from gas plants.  Brennstoff-Chem. 8, pp. 168-9
                     (1927).

              ^-   I. G- Farbenind. A-G.  Gas purification.  British patent
                     320,190.  Aug. 25, 1928.

              5.   Pieters, H. A. J.  Removal of hydrogen sulfide from gases.
                     Brennstoff-Chem. 18, 373-6 (1937).
             6.  Wallis, E.  Recovery of sulfur in a marketable form from
                     flue gases.  Brit. Chem. Eng. 7, pp.  833-6 (1962).

             7.  Williams, P. E.  Treatment of spent oxide.  British patent
                     596.  Jan. 9, 1909.

      B.   Aliphatic Hydrocarbons and Derivatives

             1.  Alexander Wacker Gesellschaft fur electrochemische Industrie
                     G.m.b.H.  Recovering sulfur from used gas-purifying
                     masses.  Brit, patent 508,966.  July 7, 1939.

             2.  Bonner, L. C.  Treating gas purifier.  British patent 10,780.
                     May 1,
              3.   Every, R. L.  and Grimsley, R. L. to Continental Oil Co. Pre
                     paring  dispersable  sulfur.  U. S. patent 3,318,666.-

              k.   Genther  et  Franke.  Extraction  of sulfur.  French patent
                     377,82*1.  May 15, 1907-
                                  390
-------
            5.   Muszkat,  K.   Production  of free  sulfur  from hydrogen  sul-
                    fide-absorbing materials  in  the Warsaw Gas Works.  Gas  i
                    Woda 17,  pp.  235-8  (1937).

            6.   Roga,  B.   Gas purification masses  as  a  source for the re-
                    covery of sulfur.  Przeglad  Gorniczo-Hutniczy 30, pp.
                    i+32-6 (1938).

            7.   Simpson,  C. H.  Extraction of sulfur  from  material contain-
                    ing elemental sulfur.   U. S. patent 3,063,817.  Nov. 13,
                    1962.

            8.   Stobe, R.   Reclaiming sulfur  from  the mass  used for gas
                    purification.   German  patent 708,031.   June 5,
C.   Aromatic Solvents
            1.   Anon.  Recovery of the  sulfur  from spent oxide.  Gas World
                    57,  197 (1912).

            2.   Becigneul,  J.   Obtaining sulfur from gas-purifying materials,
                    U. S. patent 833,573.   (1907).

           *3.  Bradley, G. W. and Barritt, D.  T.   Sulfur.   British  patent
                    72^,119.  Feb. 16, 1955.

            k.  Germogenova, E. V.  Utilization of  mixed  solvents  for the
                    extraction of sulfur from sulfur  ores.   Mineral.   Syr'e
                    1937, no. 5, pp. 28-35.

            5.  Herold, P.  to I. G.  Farbenind.   A.-G.   Purifying coke-oven
                    gases,  etc.  German patent  570, M*8.   Sept.  26, 1928,

            6.  Hunt, E. J. and Glidden, W. T.   Recovering sulfur  from
                    tarry spent oxide.  U. S. patent  105,996-   April 29,
                    1913.

            7.  Jaeger, A.   Sulfur extraction from spent  gas-purification
                    using tetralin (and low temp,  tar oils).  Brennstoff
                    Chem. 3, p. 356 (1922).
                                  391
-------
         8.  Katewinkle, R.  Recovery of sulfur from spent oxide by
                 means of tetralin.  Brennstoff Chem.  3, PP«  310-1
                 (1922).

         9.  Kuster, 0. R. to Lummus Co.  Continuous counter current
                 crystallization.  U. S. patent 3,337,30?. Aug. 22,
                 1967.

       *10.  Prchlik, J. ; Hlinak, L. and Kartakova, C. D.  Recovery of
                 sulfur from spent gas works purification mass.   Paliva
                 3U, PP. 298-305 (195*0.

        11.  Rosen, R. to Standard Oil Dev. Co. Removal and recovery of
                 free sulfur from gas -purification materials, etc.  U.
                 S. patent 2,195,870.

        12.  Soc. d Eclairage, Chauffage et Force Matrice. Removing
                 sulfur and nitrogen from exhausted gas-purifying mass-
                 es.  French patent
        13.  Suru, J.  The desulfurization of gases.  Technikai Kurir 8,
                 pp. 31-2 (1937).
        1^.  Weil, J. A.  to Imperial Industries Ltd.  Sulfur.   British
                 patent 561,370.   May 17, 19^.

        15.  Wohlwill, M. to Metallgesellschaft Akt.-Ges.   Reclaiming
                 sulfur from gases.   German patent 707,132.  May 15,
D.  Organic Sulfur Compounds

         1.  Anderson, W.   Cyanogen compounds;  sulfur.   British patent
                 127,128.   June 15, 1918.

         2.  Capell, R. G.; Wright, J.  H.  and Cruse,  Wm. A.  to Gulf Re-
               •  search and Dev. Co. Recovery  of elemental sulfur from
                 sulfur-bearing solid mineral matter,  u.  S. patent
                 2,897,065.  July 28, 1959-
                               392
-------
         3.   Chemische Fabrik Phonix, Rohleder and Co.  Recovery of
                 sulfur from extracts of gas-purifying masses.   German
                 patent 182,820.  Nov. 16, 1905.

         k.   Deal, Carl H. and Papadopoulos, M. N. to Shell Oil Co.   Re-
                 moval of sulfur-containing gases from gaseous  mixtures.
                 U. S. patent 3,363,989.  Jan. 16, 1968.

        *5.   Potsdamer, L. S.  Notes on sodium prussiate.   J.  Ind.  Eng.
                 Chem., 11, pp.  769-70 (1919).

         6.   Strauss, F.  to Gottfried Bischoff K.-G.  Extraction of
                 sulfur-containing materials.  German patent 1,1^7,566.
                 Apr. 25, 1963.

         7.   Strauss, F. to Gottfried Bischoff K.-G.   Recovery  of sulfur
                 from gas purification masses. German patent 1,131,192.
                 June lU, 1962.

E.  Other Organic Solvents

         1.   Johnson, E. J.  A theory of fluidization and  its applica-
                 tion to sulfur recovery by solvent extraction.   Inst.
                 Gas Engrs. Publication no. 378 (a),  39 pp.  (1950).

        2.  Murphy, E. J. Removal of sulfur from spent oxide.   J. Gas Lighting
                136, pp. 396, pp. 396-7 (1916).

        3.  Sawa, M.. to Nittetsu Mining Co., Ltd.  Crystallization of sulfur in
                solvent refining.  Japan patent 6318,207.   Sept. lk, 1963.
                                    393
-------
III.   USE  OF ACTIVE  CARBON IN  SULFUR  RECOVERY FROM GASES

       1.  Bakes, W. E.; King, J. G. and Sinnat,  F.  S.   Sulfur  compounds  in
               water gas and their removal.   Dept.  Sci.  Ind. Research, Fuel Re-
               search, Tech. Paper 31, 35 pp. (1931).

       2.  Braeuer, H. ¥.; Rogge, K.  Natural gas refining  by desulfurization
               with active charcoal.  Erdoel, Erdgas Z.  1967, 83(5), PP-  170-8.

       3.  Brychta, M.  Separation of sulfur from Lurgi  generator gas.  Paliva
               36, pp. 391-9 (1956).

       k.  Carbonisation et charbons actifs.  Desulfurizing gases.  British
               patent k79,klO.  Feb. k, 1938.

       5.  Englehardt, A.  Use of active materials  at coke  ovens and gasworks.
               Glukauf 73, pp. 925-33 (1937).

      * 6.  Fischer, F. and Kloeckner, L.  New method for the purification of
               viscose exhaust air.   Wasser, Luft Betr.  10(12), pp. 833-5 (1966).

      * 7.  Grantham, L. F.; Larsen,  C. M. to N.   American Rockwell Corp.  Sulfur
               production from flue gases.  U. S. patent 3,^38,733.

       8.  Griffiths, H. Activated carbons-modern applications for adsorptive
               processes.  Chem.  Trade J. 96, pp.  235-6  (1935).

       9-  Hoffman, Th.  New methods and goals in desulfurizing illuminating gas.
               Chem. App. l6, 6l-63, 120-1 (1929).

      10.  Rollings, H. and Evans, E. V.  Report  on  removal of  sulfur compounds
               from town gas down to 10 grains per 100 cubic feet.  Institute of
               Gas Engrs. Pub. no. 1^6/^3, 21 pp.  (1936).

      11.  Knauf, G.  Application of activated carbon for sulfur removal  in gas
               purification.  Energietechnik 1968,  17 (ll), pp. 14-85-8.
                                   394
-------
*(T)12.  Koenigstuhl, M. D.  Extraction of sulfur from the hydrogen sulfide
             of coke-oven and other gases by means of activated charcoal.
             Coke and Chem. (U.S.S.R.) 1932, no. 7, pp. 32-7.

    13-  Kostrikov, V. I.; Keltsey, N. V., and Nivin, P. I,  Use of one
             sorbent to remove both hydrogen sulfide and carbon disulfide
             from rayon-industry waste gases.  Khim. Volokna 1968(2).

    l4.  Krczil, F.  Catalytic oxidation of hydrogen sulfide in presence of
             active carbon.  Chem.-Ztg. 6l, pp. 2*4-7-8, 2^9, 267-8, 269-70
             (1937).

    15.  Metallgesellschaft A-G.  Removal of hydrogen sulfide from gas mix-
             tures.  French patent 1,388,^53.  Feb. 5, 1965.

    16.  Weuwirth, F.  Desulfurization of gas with Koflach lignite charcoal.
             Berg-u.  Huttenmann.  Jahrb., 76, pp. 1-13(1928).

    17.  Stanisz, Z.  Regeneration of sulfur from gases by means of activated
             charcoal.  Przeglad Chem. 2, pp. 530-1 (1938).

    18.  Thoma, M. Fine purification of gas.  Schweiz, Ver. Gas-u.  Wasserfach.,
             Monats-Bull.  16, pp. 257-68(1936).

    19.  Todd, E. W.  Removal of sulfur from illuminating gas by activated
             carbon.  Nova Scotian Inst. Sci., 17, Pt. 2, pp. 12-3 (1928).

    20.  Visconti, Y. S.  Obtaining elementary sulfur.  Rev. brasil. guim.
             (Sao Paulo) 22, pp. ^15-18(19^6).

*(T)21.  Waeser, B.  Desulfurizing gases.  Chem.-Ztg. 52, pp.. 617-8, 638-Uo,
             658-9 (1928).
                                    395
-------
IV.   SOLVENT EXTRACTION OF SULFUR FROM CARBON

      A.  Ammonium Sulfide

             *1.   Comm. on Gas Mfg.  of the  Assoc. Technique.  Gas purification
                      by activated carbon and  recovery of sulfur in the solid
                      form.  Gas Journal, 184, pp.  526-7 (1928).

          *(T)2.   Egorov, N.  N., et al. Purification of gases with activated
                      carbon.   Chapter IV,  pp. 37-47 of "Removal of Sulfur
                      from Coke-Oven and Other Fuel Gases," Moscow, 1950.

          *(T)3.   Engelhardt, A.  The use of active charcoal in the gas in-
                      dustry.   Gas-u. Wasserfach 71, pp. 290-7 (1928).

              4.   Evans, K.;  Pearson, H. P., and Reisemann, E. Industrial
                      Applications of Active Carbon.  Trans. Inst. Chem. Eng.,
                      Dec. 6,  1929, pp. 62-83.

              5.   Gouthiere and Co., and Ducanel, P.  Recovery of sulfur from
                      used gas-purifying masses.  Ger. Patent 245,570.  July 14,
                      1910.

              6.   Kazarnovskii, S. and Pisarev,  K.  The purification of gases
                      from hydrogen sulfide by oxidation on activated charcoal.
                      J. Chem. Ind.  (Moscow) 12,  pp. 913-21 (1931).

              7.   Prchlik, J.   Removal of active carbon of sulfur from waste
                      gases obtained during production of town gas in the Lurgi
                      generator.  Prace Ustavu Vyzkum Paliv 1963(6), pp. 138-50.

              8.   Reichert, 0. and Stemmler, H.  to  Spinnfaser Akt.-Ges.  Recovery
                      of sulfur from activated filter charcoal.  Ger. patent
                      1,054,655.  April 9,  1959-

          *(T)9.   Spechal, W.   Sulfur removal from  synthesis blue gas by active
                      charcoal.  Gas-u-Wasserfach 94, pp. 679-8U  (1953).

             10.   Szilagyi, I.  Method to purify and to remove sulfur from  the
                      raw gases produced.from lignite.  Magyar Kern.  Lapja  4,
                      pp. 24-5 (19^9)-
                                       396
-------
       11.  Tyulyukov, A. and Khronova, M.  The purification ol' gasen con-
                taining hydrogen sulfide by active charcoal.  J. Chem.
                Ind. (u.S.S.R.) 12, pp. 2^7-5^ (1935).

       12.  Zel'venskii, Ya. D. and Volkov, A. E.  Gas purification from
                hydrogen sulfide by oxidation on active carbon.  Trudy
                Gosudarst. Nauch.-Issledovatel.  i Proekt. Inst. Azot.
                Prom. 1952, no. 1, pp. 131-8 (1953).

B.  Organic Solvents

        1.  Becigneul,  J. J. M.  Extracting sulfur from spent gas-
                purifying materials.   Brit, patent 9»800.

       *2.  Braeuer, H.  W. and Fischer, F.   Recovery of carbon disulfide
                with simultaneous removal of hydrogen sulfide.   DECHEMA
                monograph 1968, 59(10^5-1069),  173-89.

        3.  Brychta, M.   Desulfurizing coke-oven  gas by activated carbon.
                Prace Ustavu Vyzkum Palio 1962(U), pp.  169-232.

        U.  Cornillaux.   Extracting and purifying sulfur.   French patent
                353,932, March 25,  1905.

       *5.  Fischer, F.  and Kloecker,  L. to Pintsch Bamag  A.-G.  Process
                of regenerating activated carbon  saturated with hydrogen
                sulfide and an organic solvent present in  exhaust air or
                oxygen-containing gases.  German  patent 1,259»8U5,
                Feb. 1,  1968.

       *6.  Riedl, R.;  Brychta, M., and Praskova, D.  Regeneration  of spent
                activated charcoal used for the adsorption of hydrogen
                sulfide from pressure  gas by toluene and xylene. Sv.
                Vyspke  Skoly Chem.-Technol. Praze, Oddil Fak. Technol.
                Paliv Vody 3, no. 1,  5-3^ (1959).

       *7.  Schreiber,  F.  Use of tetralin in sulfur recovery from active
                charcoal used for gas  purification.  Brennstoff-Ohem., 3,
                PP. 355-6 (1922).
                                  397
-------
                       APPENDIX A-15
        S02 ACTIVITY AND PORE VOLUME DETERMINATION
                OF SOLVENT EXTRACTED CARBON
                                                        Page

1.   S02 Activity of Solvent Extracted Carbon            399

2.   Surface Area and Pore Volume Distribution of        420
      Solvent Extracted Carbon
                            398
-------
            APPENDIX A-15-1



S02 ACTIVITY OF SOLVENT EXTRACTED CARBON
               399
-------
GRAVIMETRIC   PLOW   EXPERIMENTS
RUJI:
Dry Weight:
Dol'lnction:
Carbon :
3 2' Mi
<>'j. 'i2 me.
2t
• > ' "',: -
2000 ppm
EXV-1
NO:
02:
H20:
t:

0 pt>m
6p
200° F

FL:
                                                       3500 c-c/min.
                                                       76.66
                                           Correction:  0.5007
                                           Date:       March 23, 1971
Time
minutes
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
32
•A
:tf
•!H
40
42
44
46
liff
r>0
52
54
56
58
(,0
>'<'>
70
Load
nig. HaSOl|/g. C
6.57
8.86
10.63
11-99
13-34
14.80
16.26
17.83
19 . 50
21.37
23.04
24.92
26.64
28.67
30.65
32.74
34.82
• 36.80
38.99
41.18
43.27
45.45
47.96
50.25
52.65
54.94
57.44
60.05
f.2.55
65.05
f.9.85
75.06
79.86
Ml). 97
»')-VV
<)4.'*7
]00.t>8
10'l.lM
110.51
115.1-2
120 . 52
125. 7 S
JSO.M4
lv'..05
l4l.2»
15^.2'-
]..',. 24
Mean Load
tng. HgSOii/g. C
if
6
8
10
12
lit
16
18
20
25
30
35
4o
45
50
55
60
65
70
75
80
85
90
95
100
110
120.
130
i4o
150
160
170
180
190
200
220
21+0
260
280
300
320
3!tO
360
380



Rate
mg. %30^/g. C/min.
4.3520
3-5446
2.4395
1.6681
1.3553
1.4283
1.5325
1.6264
1.7098
1.8766
1.9912 '
2.0955
2.1789
2.2623
2.3249
2.387^
2.4291
2.4708
2.5021
2.5334
2.5542
2.5751
2.5959 '
2.6063
2.6063
2.6063
2.6063
2.5959
2.5646
2 . 5229
2.4917
2.4500
2,'WK
2.335-1
2.2621
2.1268
1.9808
1.8140
1.6785
1.5221
1.3866
1.2198
1.0530
0.8862



                        400
-------
                GRAVIMETRIC   FLOW   EXPERIMENTS
(CONTINUED FROM PREVIOUS  PAGE)
Run:
Dry Weight:
Deflection:
S02:
Carbon:
129- G
95-92 nig.
-2.53 rag.
2000 ppni
EXV-1
NO:
02:
H20:
t:
0 ppm
3-5$
ft
200° F
Ft:          1500 cc/min.
$ HgSO^:     76.66
Correction:  0.5007
Date:        March 23,  1971
Time
minutes
75
80
85
90
95
100
io(;
110
115
120
125
130
135
ikO
11*5
150
155
160
165
170
175
180
185
190
195
200
205
2.10
215
220
Load
nig. HgSOij/g. C
177.33
188.70
200.17
211.53
222 . 58
21'«.11
2k 1 . 12
252.92
26.1.78
270.5l|
278.77
286.80
291*. in
301.1*0
308.38
315.16
321.52
327.88
33^.2U
3'*0.60
3't6.61t
352.90
35«.53
361). 16
369.58
37^.90
VfH.W
.VM.W
Wf.'jl
391-37
                                         401
-------
GRAVIMETRIC   FLOW   EXPERIMENTS
Run:
Dry Weight:
Deflection:
S02:
Carbon:
130-0
101.7U mg.
-2.55 mg.
2000 ppm
EXB-1
HO:    0 ppm
02:    3-5*
HgO:   6%
t:     200°F
                                                        1500 cc/min.
                                                        76.66
                                           Correction:   0.5019
                                           Date:        March 2k, 1971
Time
minutes
1
2
3
It
5
6
7
8
9
30
12
ll)
16
18
20
22
2U
26
28
30
35
l»o
1*5
50
55
60
65
70
75
80
85
90
9';
300
110
120
330
3 >(0
350
160
170
180
390
KOO
. 210
220
2'jO
«l|0
,"'.>0
i'M
."70
280
'f III
•iuo
110
:«o
H'J
Ixsad
m«. H2SOl,/g. C
5.11
5.90
6.39
6.88
7-37
7.76
8.16
8.li5
8.85
9.2't
9-93
10.52
11.21
11.89
32.68
13.37
llt.3.5
Il4.8lt
15-73
16.51
18.58
20.71*
22.90
25.3.6
27.1*2
29-98
32. Ok
35-29
37.81*
110.59
1*3. Mt
'16.29
1*9.31*
52.29
58.1*8
6k. yr
71-95
79-12
86.30
93-28
100.65
108.12
115.1*9
122.76
129. 61|
136.52
I'l.-i.llO
]50.(M
.156.67
11,2.77
I6((.'i,,
17li.5t,
lllu. ',i,
J»5.77
J'M .17
Tlh.2!)
20.1 . 30
Mean Load
mg. H2SOl4/g. C
1|
6
8
10
32
3.1*
3.6
18
20
25
30
35
1*0
'•5
50
55
60
65
70 ,
75
80
85
90
9'J
100
110
120
130
l'*0
150
3.60
170
180
190
200






















Rate
rag. HgSOlj/fi. C/min.
. 3.M'><>3
0.5» 17
0.31(1)0
0.32!i'i
0.33'(2
O.Vi'tO
0.3M7
0.38.-M
o. 1*128
o. n5.2i
O.liyl'*
0.5 '308
0.5701
0.5<>9n
0.6291.
0.6'ib7
0.66?U
0.6t3o
O.i>,'7>)
0.7077
0.7175
0.7175
0.7273
0.7273
0.7273
0.7175
0.7077
0.^979
0. 66S.lt
0.6W?
0.6291
o.wv;
0.5/01
O.^liO'i
0.5011






















             402
-------
GRAVIMETRIC
Run:
Dry Weight :
Deflection :
S02:
Carton :
131- G
102.52 mg.
-2.1*5 rag.
2000 ppm
EXV-2B
NO:
02:
t:
0 ppm
3.5*
200* F
FLOW  EXPERIMENTS

                   *v
                                                      1500 oc/min.
                                          Correction:   0.1*851
                                          Date:        March 25, 1971
Time
minutes
1
2 •
3
1*
5
6
7
8
9
10
12
ll*
16
18
20
22
21*
26
28
30
35
1*0
1*5
50
55
60
65
70
75
80
85
90
95
100
110
120
330
Jl|0
150 •
.160
370
180
1^0
2
l.Y'l.70
183.38
.191.. 57
l<)<>.',7
207.76
;M',.57
2J2.98
230.10
2.16.H3
21*3.27
2l(9.)(l
255-56
261.1*1
266.68
Mean Load
mg. HgSOl^/i;. C
1*
6
8
10
12
ll*
16
18
20
25
30
35
1*0
1)5
50
55
60
65
70
75
80
85
90
95
100
110
120
130
ll*0
150
160
170
180
190
200
220
21*0
260



















Rate
mi-. H2SOl|/r- C/rain.
7.5595
U.8771
1.7070
0.5365
0.5365
0.51162
0.5560
0.5657
0.5755
0.61U5
0,61*38
0.6730
0.7121
0.71*13
0.7603
0.8096
0.8369
0.;V,6l
p. «97l*
O.yi69
0.9H61*
0.9559 •
0.9-'5'7
0.9852
0.991*9
l.OlWt
1.02l(2
1.021*2
1.021(2
1.001*7
0.9751*
0.91*62
0.9071
0.668:
0.81911
0.7316
0.61(38
0.5'»62
















'


            403
-------
Run:
Dr.y W.'ir.ht.
C-it-l on:
101 .'/O mi1;.
-3.74 u\i'..
li'KX) ppm
KXB-2
                                     NO:
                                     II20:
0 ppm
V//,
r/
200°F
              1500 cc/niln.
              72,06
Corroi-tlon:  0.4706
Date:         March 30,  1971
Time
minutes
]
2
3
4
5
6
7
8
9
10
12
14
16
18
20
22
24
26
28
30
35
40
45
50
55
60
65
70
75
80
85
90
9'J
100
110
J20
no
I'lO
.1^0
JnO
.170
1 :•'.<>
I'KI
2OO
21'.)
220
230
240
2'jU
2'.0
2/0
i'.".0
Lofid
mg. IlgSO^A;. C
8.44
9-13
9.r>2
9.81
10.40
10.79
11.09
11.38
11.68
11-97
12.56
13-25
13.94
14.62
15.21
15.90
If.. 68
17-27
18.06
18.84
20.71
22.67
24.63
26.59
28.56
30.52
32.58
34.74
36.80
38.96
41.22
43-57
45.83
4;-i.i8
'-•!.. I')
',.'..-<>)
M.Y',1
f.('.2B
74 .'iM
:•;().:/,
'-<..'!'>
".;.i.'i
'i.'.'M
j ( <•* . •>;>
IC". "1
31',.U
IL'O.'K'
12... SO
i-'.j. •;•-••
ny.'>°.
J.4 -i . .J,^
r4.(.;'7
Mean Load
mg. H2SOj+/g. C
It
6
8
10
12
Ik
16
18
20
25
30
35
4o
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
lltO























Rate
mg. HgSO^/g. C/isin.
8.6850
5-6919
2.3553
0.3925
0.3435
0.3435
0.3435
0.3533
0.3631
0.3925
0.4220
o.44i6
0.1*612
0.4809
0.5005
0.5201
0.5299
0.5397
0.5^96
0.5594
0.5692
0.5790
0.5888
0.5888
0.5888
0.5888
0.5888
0.5790
0.5692























                                       404
-------
Run:
Dry Weight:
Deflection:
S02:
Carbon:
GRAVIMETRIC   FLOW   EXPERIMENTS

                   NO:
33't-G
99.98 mt;.
-2.83 my.
2000 ppm
EXV-2C
0 ppm
3.5?,

200° F
                                             Ft:
             1500 cc/min.
             7!*.77
Correction:  0.1*883
Date:        April 12, 1971
Time
minutes
1
2
3
l*
5
6
7
8
9
10
12
lit
16
18
20
25
30
35
1*0
U5 l
50
55
60
65
70
75
80
85
90
95
100
110
120
130
lUO
150
.160
170
JBO
190
200
2K)
2HO
230
2'tO
250
?/<0
270
280
200
300
Load
mr,. HgSO^/g. C
32.I|0
13. yo
l't.90
15.90
16.90
17.90
18.80
19.80
20.80
21.90
23.90
25.91
27-91
29.91
31-91
37.11
te.31
^7.71
53.01
58.61
61*. 31
70.11
76.02
81.92
88.02
93-92
99.82
105.92
111.92.
118.12
12l*.12
135-93
I't7.53
158.83
169.93
iHo.yi*
i<):i..6i*
20.1. 9'*
,2.11.9'*
221.5')
2 -|i ).8';,
2-tO.tf';
2'iM.lO
2'..(..'i')
Ht'Ji.lfi
272.05
27').jr,
2H5.06
2',«.66
209. l/,
30'). 26
                                     405
Mean Load
mg. HgSOtj/g. C
6
8
10
12
11*
16
18
20
25
30
35
1*0
i*5
50
55
60
65
70
75
80 '
85
90
95
100
. 110
120
130
ll*0
150
160
170
180
190
200
220
2l*0
260
280
300





'






Rate
mg. HgSO^/g. C/min.
12.2525
9.5019
6.7511)
3-1*507
1.1002
1.0002
0.9902
0.9902
1.0102
1.01*02
1.0602
1.0802
1.1002
1.3202
1.1302
1.1502
1.1602
1.1802
1.1902
1.2002
1.2002
1.2102
1.2102
1.2102
1.2102
1.2102
1.2002
1.1902
1.1602
1.11*02
1.1102
1.0902
1.0502
1.0202
0-9502
0.8702
0.8002
0.7101
0.6201












-------
               i; li A V I  M K T li  I  C    !•' 1 0 W   K X I' M R J M K N T !5
Hun:
Dry Weight:
Deflection:
S02:
Carbon:
lOO.H* mg.
-5-53 mg.
2000 ppm
EXV-3B
NO:   0 ppm

HgO:  6%
t:    200°F
                                                Ft:
Correction:
Date:
1500 cc/min.
77. OU
0.5031
May 1*, 1971
Time
minutes
1
2
3
li
5
C
7
H
9
.10
\?
Ill
16
18
20
25
30
35
140
U5
50
55
60
65
70
75
80
B5
no
."10
;>?o
:• -;o
;-'iO
Load
:r:G. llgSO^/g. C
6.09
7-39
8.29
9.. 19
10.19
:n .08
K',08
.13.08
Hi. OH
J5.08
17. ?8
19. W
. 21.77
2^.07
26Ji6
32.75
39. 7U
^7-23
55-12
63-i+l
71.50
79.79
88.18
96.56
105.25
313.7li
122.1.3
.130. IIP
.138.51
.1)16.60
15)1.38
169.66.
lH)i . Di
.197.82
2.10.80
223.19
235.17
2)16.^5
257. OH
^if.7.0?,
27''». 21
?;>i.yo
292 . w
>3VY
.1 . (",038
1 . 55?8
1 . 5029
l.kk&O
1.3980
1.31 (31
1.2283
l.l]8)i.
1.0036
0.8838
0.7639





                                    406
-------
C, K A V I M K T R  I  C   FLOW   EXPERIMENTS
Run:
Dry Weight:
Deflection:
S02:
Carbon:
H47-G
103.3 nig.
-5.26 mg.
2000 ppm
EXB-2
NO:
02:
HgO:
t:

                       0 ppm
                       200°
Correction:
Date:
1500 cc/min.
76.11
0.14970
May 6, 1970
Time
minutes
1
2
3
It
5
6
7
8
9
10
12
l!|
16
18
20
25
30
35
40
't5
50
55
60
65
70
75
80
85
90
95
100
3 10
320
.130
:iiio
150
.160
170
J8o
i_yo.
poo
210
?20
230
PUO
Load
ing. H2S01|/g. C
li.26
5.52
6.29
6.97
7-65
8.23
8.81
9.ii9
10.07
10.711
.12.00
13.36
l)i. 81
16.16
17 -.62
.21.20
2)4.97
28.9't
32.81
37.07
l»l.62
k6.U6
51.78
57-10
62.62
68.23
7h. ll)
.80.33
86.53
9?. 82
99.?1
:n?.?7
:ip:..f«:
!;•!«. 99
35J -86
l6li.)|)i
r/A.)|)i
•i ' ' '. ) -pi
!<:•>, •) )
1 ' )<).>'/>
PI 1.1 9
;>:•;'. 13
>",:?. 68
^ij.ox
253.. 19
r6P.it 9
Mean Load
mg. HgSOj^/g. C
2 n
k
6
8
10
... 12
Ik
16
18
20
25
30
35
1)0
)i5
50
55
60
65
70
75
80
85
90
95
100
110
120
130
l!|0
.150
160
.170
180
190
P.OO
??Q
P)|0
:-'6o






Rate
mg. li^SO^/s. C/:ain.
k. 355^
2.14.003
0.77^3
0.6775
0.6581
0.658.1
0.6630
0.6727
0.6872
0.7065
0.7598
0.8227
0.8808
0.9388
0.9872
i.0308
1.07^3
1.1130
1.1518.
1.1905
1.2292
1. 2W5
1.2679
1.2873
1.2969
1 . 3066
1.3163
1.3163
l . 3066
1.2969
1.2776
1.2582
1.2389
1.2098
1.1808
.1 .1518
.1.0889
] .()!(>•{
Q.<)WV,






                    407
-------
GRAVIMETRIC   FLOW   EXPERIMENTS
Run:
Dry Weight:
Deflection:
S02:
Carbon :
154-G
117.04 mg.
-5-53 mg.
2000 ppm
EXA-1
NO:
02:
HjO:
t:

                       0 ppm
                       200 °F
!t!
                                            Correction:
                                            Date:
1500 cc/min.
71.24
0.4652
May 26,  1971
Time
minutes
1
2
3
)|
5
6
•(
0
9
JO
.1?
14
16
18
20
25
30
35
40
45
50
60
70
80
90
:ioo
.110
.IPO
J'J,0
I'lO
11)0
160
.170
180
190
?00
?10
220
?30
?l|0
250
tf>0
270
r.".o
?' )0
"<00 j
Load
r,ie. H2S01(/g. C
0..17
0.34
0.60
0.77
0.94
.1 . .1 1
1.37
.1 . 5'i
1.79
1.97
2.31
2.73
3-08
3.42
3-67
4.53
5-30
6.07
6.75
7-43
8.03
9.31
10.li2
11.53
12.65
13.67
.Hi. 70
_Lk- 5>
1 6 . V
l/.oy
jy.f")
18.37
39.22
20. ?'j
21 . 36
22.73
2)|..l8
25-72
27-17
28.96
30. y>
3?.3U'
3'i.l»
3«i. 'V.
:;7.M.'i
;'».fl,"
Mean Load
mg. H^SOj/g. C
2
It
6
8
10
-, 12
:4
16
18
20
22
24
26
28
30
3?
34
36
38
40


























Rate
mg. HgSOjj/g. C/min.
0.2153
0.1692
0.1393
0.1?56
0.1128
0..1008
0.0897
0.0705
0.0880
0.109)1
0.1282
0.1427
0.1521
0.1623
0.1692
0.1777
. .0.1837
0.1897
0.1931
0.1965


















^







                     408
-------
  0 R A V 1 M !•; T K I C   F 1, 0 W   EXPERIMENTS
Run:         J5'j-G
Dry Weight:  108.52 mg.
Dofleetlon:  -5-85 mg-
             2000 ppm
D02:
Carbon:
                                 NO:   0 pprj
                                 02=   3-5V
200°?
                                                Ft:
                                                Correction:
                                                Date:
1500 cc/rain.
76.99
0.5028
May 27, 1971
EXB-3
Time
minutes
1
2
3
It
5
6
7
8
9
10
.12
lit
16
18
20
25
30
35
itO .
1*5
50
55
60
65
70
75
80
85
90
95
100
110
.120
J30
DK>
J',0
1 60
JYO
JfiO
1 <>0
,'•00
;MO
;-20
:?_;0
piio
250
260
270
p8o
?90
300
Load
ing. H2SO),/g. C
3.87
14.88
5.62
6.36
7.10
7-83
8.57
9-31
10.014
10.78
12.35
13-91
15.57
17-23
18.89
23. Ill
28.20
33-27
38.89
U5.06
51-33
57.96
61*.. in
70.77
77.22
83.76
91.23
98.51
105-79
113. .16
120.53
135-09
lfi9-37
: 6:^.38
177.29
iyi.9!>
;;o6.oii
;?io.f,«
;>•<•. 58
:'Mi.66
;">:.;. oo
r>< />.('.«
PYY . oo
;>«.•,. <>:,
P<'6.17
•j,o'i . or1
^i3.f.i
:;;o.05
;::'3.05
.Tj'i-9'S
3)12.06
Mean Load.
mg. H2SOi+/g. C
2
1*
6
8
10
12
lit
16
-- 18
20
25
30
35
1*0
»I5
50
55
60
65
70
75
80
85
90
95
100
110
120
130
ll)0
150
160
170
180
.190
200
220
2liO
?60
;-ao
••jOQ
320
3liO








Rate
mg. H2SO^/g. C/min.
3-8703
1.9812
0.7925
0.7l)-6^
0.76148
0.7833
0.8109
0.8386
0.8662
0.8938
0.9583
.1.0229
1.0781
1.12142
. 1.1703
1.2072
1. 2l4l40
1.2809
1.3085
1.3362
1.3638
1 . 3822
1.1(007
1.14191
1.^375
DA67
1.14652
1.1471414
l.VfWk
1.1)652
1.U560
1.^375
1 . li099
J . 391)1
J • 3638
l .330?
l.?
O.'W^l
O.R017
0.6'OJ








                       409
-------
               i; H A  V  I  M K T H 1  C   !•' I. <> W   K  X  1' K  K I  M !•! N T !'.
Hun:         3 >(>-(";
Dry Weigh' :  103.60 ing.
Deflection:  -5-90 i::g.
             2000 ppra
             EXC-1
NO:   0 pp:n
02:   3-5"
H20:
S02:
Carbon:
Time
minutes
3
2
3
)i
5
6
y
8
9
10
12
Hi
16
18
?0
25
30
35
1*0
145
50
55
60
65
70
75
80
t'j
90
0';
.1.CX)
no
.12(1
1 -if)
l'in
!'.)<)
ViO
jyo
IMO
1Q( >
20d
2.10
220
2<0
2UO
2'/>
P-.0
270
,'^••0
L>'»U
•iOO
Load
me- H2::o)(/g. c
9.27
10.1(2
31.29
12.16
32.93
33.80
Di.67
15.1('i
16.33
37.30
18. H2
20.66
22.39
2U.33
25-97
30.60
35-52
1+0. 61*
l*6.ll*
51. 7!*
57-53
63.51
69.50
75.68
81.76
88.03
oH.2l
100. ^9
106 . r>G
132. 8'i
3.:i-).i3
13.1. 1 H
1 1(2. <.>5
iVl.'l'i
,lf.',.r,l|
jyi'..'1'.j
.!(''.. '17
]<>Y.10
2i • .1,1')
23.i.,.>'i
22-\. Ij
2 -U.' . ;i J,
2lfO.S-l
2lj';.,,S
2'ii', . 3..S
• 1, , . '")
27>\,'7
jy--."-;
^•i.-':fi
^•••'.'is
;M'i.]y
                                  t:
      200 CF
                                                               Ft:
                                                               % HgSOj,.:
                                                               Correction:
                                                               Date:
1500 ce/min.
75-15
0.1*908
May 28, 1971
Mean Load
mg. HgSO^/g. C
6
8
10
12
Hi
16
38
-, 2.0
25
30
35
l|0
1)5
50
55
60
65
70
75
80
85
90
95
100
110
120
130
l'*0
350
160
iyo
.180
190
?_oo
220
ii'lO
2/,0
280
.












Rate
mg. H2SO^/g. C/min.
7.1i*29
1+.1988
1.1390
0.8687
0.8301
0.8398
0.8591
0.878)f
0.9266
0.97^9
.1.0232
1 . 0?lU
1.100)i
1.1293
1.1583
1.1873
1.1969
1.2162
1.2259
1.2355
1-2355
1.2355
1.2355
1-2355
1.2259
1.2162
1.3-969
1.1680
l.lif«6
1..U97
1.0907
. 1.0610
1.02 =52
().
-------
GRAVIMETRIC  FLOW  EXPERIMENTS
Run:
Dry Weight:
Deflection:
SO :
Carbon :
159-G
102.26 mg.
-5-93 mg.
2000 ppm
EXA-2
NO:
V
HO:
tf

0 ppm
3-5*
%
200° F

                                            '.V
             1500 cc/mln.
             79- 44
Correction:   0.5188
Date:         June 7, 1971
Time
minutes
1
2
3
>t
5
6
7
. 8
9
10
12
14
16
18
20
25
30
35
ho
45
50
60
70
Ro
VO
100
11,0
120
1.30
I'lO
150
160
170
180
190
200
2.10
' ??0
230
2'c.)
no
260
','/0
?.",o
;>• m
300
Load
ng. H2SOl,/g. C
2.64
3-52
3.91
4.20
li.'jO
k.(f)
II.B-J
5.0^
5.28
5.38
5.67
5./r
6.26
6.55
6.75
7-53
• 8.31
9-00
9.68
10.37
11.05
12 . 52
13.89
.15-45
Jfi.'tf
I,",J|H
19-95
21.51
P3.0H
24.64
26.31
i'7-07
29-73
31 • 39
33.15
31' • 91
36.77
3>"-63
ii0.5»
ii;;.54
hh.'j-*
46//4
4't.H'i
51..24
'>V'>
56.13
Mean Load
ing. HaSOlj./g. C
4
6
8
. 10
••' ie
1)1
16
18
20
25
30
35
40
45
50
55






























Rate
nig. HgSO^/g. C/min.
0.3071
0.1604
0.1408
0.1418
0.1438
0.1457
0.1486
0.1516
0.1555
0.1633
0.1741
0.1868
0.2005
0.2151
0.2318.
0.2494












•

















                     411
-------
GRAVIMETRIC  FLOW  EXPERIMENTS
Run:
Dry Weight:
Deflection:
S02:
Carbon:
165-G
106.92 mg.
-5-97 mg.
2000 ppm
EXA-3
NO:
02:
HgO:
t:

0 ppm
3-5$
656
200° F

t
                                                       1500 cc/min.
                                              2h:     77-85
                                           Correction:  0.5084
                                           Date:        June 16,  1971
Time
r.inutes
1
2
3
4
5
6
7
8
9
10
12
14
16
10
20
25
30
35
40
45
50
60
70
80
90
100
110
120
130
140
150
1 60
170
180
190
POO
?10
2PO
'30
shn
'50
•('/>
'(<>
;'r>
> .-)8
^'i?.70
',"j\ . »'.
;'u).4'(
;'i»i'.".o
'.''(<'••'/>
:''-'J.v'"
P "l.l.-',
P >{. I'l
•^05.40
•jo i.'iM
:. 03
•]..Y'l
Mean Load
mg. HpSOjj/g. C
	 	 • • ' — ' ' "
2
4
6
• 8
-'10
12
Ik
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
3.40
150
160
170
180
190
POO
220
2l)0
260
?;*o
300
3?o







Rate
ing. HpSOk/g. C/rain.
4.2088
2.5907
1.6835
1.1785
0.9727
0.8605
0.7669
0-7202
0.7108
0.7295
. 0.7856
0.8230
0.8698
0.9166
0.9540
J. . 0007
1.0382
1.0156
1 • 1130
1.1504
1.1785
1.2065
1.2252
1.2439
1-2533
1.2626
.1.2813
1.283.3
• 1.2720
1.2626
1.2439
1.2252
1.1972
1.1691
1.1504
1.1130
1.0382
0.95)10
0.8605
0.766)
0.6640
0 . 563 f>







                    412
-------
GRAVIMETRIC  PLOW  EXPERIMENTS
Run:
Dry Weight:
Deflection:
S02:
Carbon:
166-0
101.36 mg.
-6.09 mg.
2000 ppm
EXA-4
NO:
02:
HgO:
t:

0 ppm
3-5$
6$
200° F

Ft:
Correction:
Date:
                                                         1500  co/tnin.
                                                         77.20
                                                         0.5042
                                                         June  21, 1971
Time
minutes
1
2
3
It
5
6
7
8
9
10
12
It
16
18
20
25
30
35
40
45
50
60
70
80
90
100
110
120
130
I'lO
.100
.1.60
J.YO
.1 HO
1 'X>.
;?oo
21.0
;vo
;>30
P'lO
250
260
270
2MO
2-)0
'•(00
Load
ing. H2SO^/g, C
4.o4
5.82
7.20
8.29
9.27
10.26
11.25
12.33
.1,3.32
lit. 31
16.18
18.15
19.93
21.80
23.78
28.12
• 32.66
37.19
iH. 83
46.47
51.30
61.76
73-01
84.55
96.98
110.00
12P.93
135.06
l4Y.'lO
1 V.i. 83
172.36 . . . .
LS'l . 19
.1 >J'j . Y'l
;K>6.3v
P,l/).'j'3 . ..
226. >'!
23S.Y9
P'i4.0Y
2V-;.B'j
Pfr'.Oli-
069. »3
2YY.'t3
2811.63
291.5'!
2->H.L5
30'i . 66 . ... ...
Mean Load
mg. H2SOij/g. c
2
.4
6
8
' 10
12
14
16
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
1.10
120
130
140
150
160
170
180
190
POO
220
240
260
280
300





Rate
mg. HgSO^/g. C/min.
4.0450
2.4862
1.6180
1.1346
1.0359
0.9767
0.9471
0.9373
0.9274
0.9175
0.9077
0.9126
0'.9175
0.9422
0.9570
1.0014
1.0359
1.0754
1.1099
1.1444
1.1691
1.1938
1.2135
1.2332
1.2480
1.2579
1.2727
1.2727
1.262H
1.2579
1.2382
J .2184
1.1938
I.l6)i2
i.J3'i6
1.0951
1 .0162
0.0274
0.828Y
0.7202
0.6215





                     413
-------
GRAVIMETRIC  FLOW  EXPERIMENTS
Run:
Dry Weight:
Deflection:
S02:
Carbon:
167-G
107-14 mg.
-5-99 mg.
2000 ppm
EXA-5
NO:
02:
H20:
t:

0 ppm
3-5$
6$
200°F

 t
Correction :
Date:
                                                       1500 cc/min.
                                                       77-51
                                                       0 . 5062
                                                       June 23,  1971
Time
ninuteo
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
25
30
35
40
45
50
60
70
80
90
.100
no
IP'O
1.30
UlO
1^0
160
170
180
1^)0
?00
210
?J.'0
•30
J'|0
•"jO
'l:i)
'(()
': '•< )
'•)•}
•sou
Load
inc. HgSOjj/g. C
3-17
4.67
5-69
6.53
7-37
8.12
8.87
9.52
10.17
10.83
12.13
13.44
14.75
16.15
17-55
21.09
24.64 .
28.19
31-83
35-56
39.39
47.23
W-44
64.60
74.30
84.66
95-30
106. 4 o
117.51
128.62
139.54
I.b0.64
161.56
172.58
J83.22
193. 2 L
202.91
212. 'j 3
22L.95
231.10
2S'.'.';/1
PW.iM
P'jY.'jl
f'(,fi.".j
L'lV.OY
;>Y;i.:(...
Mean Load
ing. HgSOjj/g. C
2
4
(>
8
' 10
12
14
16
18
20
25
30
35
ho
45
50
55
60
65
70
75
80
85
90
95
100
110
120
130
i4o
150
160
170
180
190
200
220
240
260
2MO






Rate
mg. l^SO^/g. C/min.
2.7067
1.6054
0.9_520
0.7467
0 . 7000
0.6814
0.6720
0.6814
0.6860
0.6907
• 0.709^-
0.7280
0.7560
0.7840
0.8167
0.8494
0.8867
6.9240
0.9614
0.9894
1.0080
1.0360
1.0500
l.o64o
1.0780
l . 0420
l . 1060
1 . .1 107
1.1107
.1.3014
1 . 0920
1.0780
1.0594
1.0407
1 . 0174
0.9894
0.9334
0.8yi7
0.7840
0.70^4






                     414
-------
GRAVIMETRIC
FLOW
                                   EXPERIMENTS
Run:
Dry Weight:
Deflection :
S02:
Carbon:
if, 9- a
100.50 ing.
-5.91 n«-
2uOO ppm
]•:>:••;- 4
NO:
02:
H20:
t:

0 ppm
3f~ ^
• )"!'
6%
200° F

                     Ft:
                     Correction:
                     Date:
                                                          1500 cc/inin.
                                                          78.24
                                                          0.51105
                                                          June 25, 1971
Time
minutes
1
2
3
l)
5
6
7
8
9
10
12
lit
16
18
20
25
30
35
ho
45
50
60
70
80
90
100
110
120
I'-JO
.11)0
150
IhO
.170
IMG
J'lO
2UO
2.1 n
220
2-iO
2-'.0
2''0
;>r,o
270
,''',(}
','.'l<>
':< )0
Load
m.";. H230i|/(;. C
1+.73
6.17
7.06
ti.or,
8.96
9.95
10.95
11. 9'J-
12.9U
13-93
16.02
18.31
20.50
22.89
25.17
30.95
37. lH
Mt.68
52. Mi
60.80
69.65
88.36
107.96
128.26
11*9.25
169.75
189.75
20H.96
226.97
2l)3.(.rt
2!>Q.oO
275-02
|_ 290.05
30.5 . 08
l.Tt.'H
•J,20.''7
j, j,<,. ','.:>.
Vin. 17
V..'.. :2
V l-'l .'..')
W.2'i
•;7< I . ' in
••.-.7.1"
-.••••I.IM
)|E 1 ] t\>> t
h>>{.'/t.
Moan Load
rng. HaSOl^/R. C
1)
6
8
10
-' 12
14
3.6
1.8
20
25
30
35
Uo
45
50
55
60
65
.70 .
75
80
85
90
95
100
110
120
130
1.40
150
160
170
180
190
200
2.?0
2'lO
2f,0
2MO
HOO
•;HO
••;'iO
•li .0
VH>
lino

Rate
mg. HjjSO^/g. C/min.
3-l«4l
1. 2'I38
0.9254
0.9552
0.9751
1.0149
1.0348
1.0647
1.0945
1.1741
1.2637
1.3433
1.4229
1.4975
1.5672
1.6418
1.7015
1.7612
1.8109
1.8607
1.8905
1.9204
1.9602
1.9900
2.0100
2.0498
2.0697
2 . 0796
2.0796
2.0697
2.059V
2 . 0398
2.0000
1.9'".C2
l.Ol.Oli
1.7"' 0
l.
-------
G R A V I M K T H I C   ]•' L 0 W   K X P K H I M E NTS
I'uri:
Dr.y WeM'L:
D< •riwt.jon:
C02:
Carbon:
1.7"-'!
.Kv'.'.'i nit'.
-5. 'i.l me,.
2000 ppm
EXB-5
                   NO:
                   HgO:
C) ppm
3.5$
6*
200° F
]?t:          3-500 I'
$ HgSOj,:     78.4?
Correction:  0.532)4
Date:        June 28, 1971
Time
minutes
1
2
3
It
5
6
7
8
9
10
32
3.1)
36
3.8
20
25
30
35
Uo
>45
50
60
70
80
90
100
110
120
HO
1'jO
ISO
'li.U
170
i.'-;o
3 ' '0
2oo
23.0
2.-i '
2 -;(.'
.-.'llO
2M>
i.'i i)
270
2.''d
2' 40
J,t «.)
J, It)
j- );^
•> -ll '
Load
mr.. T!?SOb/«. C
U.19
6.33
7.79
8.87
9-9'*
11.01
32.08
3.3.06
13-93
1)4.71
16.56
3.8.61
20.65
22 .<>0
25-23
31.18
37.61
14)4.72
52.51
60.80
69.66
88.56
108.73
329.87
150.lt|
170.01
188.91
206.55
223-79
2'i0.55
2y>.M
27.1.. 0)+
2M . 3 0
2'i',.8i,i
307. f»
-11'".. 00
•:2».5i
', ;.-f.O^
•;'ii,.(.S
-;•-']. is
','•1 .in,
-;.,".. |.-i
'.Y'«.< !
'.-'. 1 .»'li
-•,--;y.2,;>.
•;• i -i . .12
••.•i.".. 87
)K''I .o-j
llU'^.UO
Mean Load
mg. H2SO^/g. C
2
If
•6
8
10
12
14
16
18
20
25
30
35
1)0
'45
50
55
60
65
70
75
80
85
90
95
100
1J.O
320
130
lUO
.1.50
160
370
180
wo
200
220
2*10
A ,0
2H<>
',00
^20
.)l|0
-:f'.o
--i»o
InOO



Rate
mg. HgSO^/g. C/min.
^. 38)43
2.7280
1.5680
1.^322
1.0035
0.9353
•0.9256
0.9^99
0.98^0
1.0279
I.l¥t8
1.2U22
1.3396
3..U322
1.5101
1.5881
1.6660
1.73^2
1.7927
1.8)463
1.8950
1.9339
1.9729
1-9973
2.0216
2.0)460
2.0703
2.0752
2.0703
2.0557
2.02.16
.V.9B75
1.9)186
l . 90uf>
3.H706
1.8.1YO
3..7050
l-'/C-'V-i
i.'i m.
3 .271--!
1..I2())J
D.')7'H
o.^v/o
0.7210
o.r.oaq
0.52bl



                     416
-------
                r, K A V I  M K T li T C   V T, 0 W   V X I' K R T M K N T I',
Run:
Dry Weight:
Deflection:
S02:
Carton:
171-C!
101.80 nig.
-6.22 mg.
2000 ppm
EXA-4
Time
minutes
1
2
3
14
5
6
•I
8
9
.10
X?
3.4
16
18
20
25
30
35
1+0
U5
50
60
70
80
90
100
330
120
1 '.()
1.4 0
I'/'
K.d
:iY''>
.U'f'
]nO
21 >'')
2JO
22"
2-:o
24 o
2',...
2.'0
270
2.' 0
2' -C>
•inn
Load
mg. HgSO^/g. C
5-50
7-56
9.014
30.32
11.. 20
12. 2H
13-26
lH.35
1^-93
l'j.82
37-°'.)
3.8.76
20.04
21.U1
22.99
26.82
31.04
• 35-66
1*0.37
U5.28
50.29
60.81
71.51
82.91
9'i-79
.106.88
31 9- 35
131.93
l.'i'i.Ol
.V/-.80
l(>7.r;<'i
17H . * .rt
380.30
.v>',).:i2
2i'.'i.Wi
23.8. liy
227.70
236.7!)
24S.68
2[.;'i . .«
2i..-!.'-!7
270.02
2V.J.2M
2J-.4.7.7
?•>').{•'('
;?»...*>•;
J2'
U2C
t:
H20:
0 ppm
3.536
e*
200° F
                          *t:
             1500 cc/niJn.
             77.04
Correction:  0.5031
Date:        June 29, 1971
Mean Ixsad
mg. HgSO^/g. C
2
It
6
8
10
"' 32
lit
16
18
20
25
30
35
ItO
it5
50
55
60
65
70
75
80
85
90
95
100
110
120
130
140
150
3/.0
170
18'0
190
200
220
240
260
280
300





Rate
mg. HgSO^/g. C/min.
6.5815
3-6337
2.4558
1.5226
1.2083
0.9921
0.874.3
0.7«59
0.7466
0.7367
0.7957
0.8^46
0.9037
0.9627
0.9921
1.0314
1.0609
1.0904
1.1198
1.1395
1.1591
1.1788
1.3886
1.2083
.1.23.81
3.. 2279
1.2377
1.2475
.1.2 ',77
.1.21 H.I
J.lHHi,
1 ..l'/)l
3 . 1297
3 .1002
1.0609
.1.02.16
0.9528
0.8743
0.7859
0.6876
0 . 5094





                                      417
-------
r; R A v :i M !•; 'i1 K i c
                          LOW   K X ]' K K 1 M E N T !i
Him:
Pry Welch t:
Deflection :
S02:
Carbon:
172- G
100. ll* m;'..
-6.13 mg.
2000 ppm
EXC-2
NO:
02:
H20
t:

                          0 ppm
                          200° F
Ft:          1500 cc'/rain.
% H2SOi+:     76.89
Correction:  0.5021
Date:        July 8, 1971
Time
minutes
\
2
>>
1(
5
(',
7.
B
9
1.0
.12
111
16
18
20
25
30
35
1(0
'45
50
60
70
HO
90
100
110
.120
.1 «)
ll|()
ISO
-|.'.Q
17U
I.'"-)
I'/O
;_'-.o
..' 10
.'.w
?.'-.<•>
•^«
.?'.o
' 'i "
,-yo
':'• '-ll
.' "'
',()!)
Load
me.. H2SOj,/c;. C
i JlO
5 • 19
(>. -iO
7.S')
H . vy
•).2'i
K). 19
1i).')M
11. HM
' 12. (',8
I'l-.'iH
16 . 1.7
17-97
19.87 .
21.77
26.86
32.15
37.85
1*3.714
50.33
57-02
71 . 10
«fj.f,8
.10^.26
.ll'i.'M
l',f,.K.I.
J5',.7'
170. ','•
j. '-;,,. N'I
2ul .22
<-'!'.. 1.0
iNo. •;•:
2Mi.)|,,
2'>-.2i4
271.52
2 U..-M
2- "1. 7s.'
-iill .'•.-.
•i.'.ir.
^ . i -.
•MI .«.';
•''- '.'>.?
•.' '.11
•'.....' u
.1 •; . ' .' i
V(".i .'>
                     418
Moan Load
me- l^SO^/g. C
2
l|
6
.•- 8
10
12
111
ir,
18
20
25
30
35
ko
1+5
50
55
60
65
70
75
80
85
90
.95
.100
.1JO
.120
1 J,0
1'40
150
160
170
.1.80
190
200
220
2UO
2.'0
280
WO
#0
•s'.o
Vfl


Rate
mg. HgSOjj./g. C/min.
2.9^59
]..877'i
1.2l|«3
0.9087
0.8238
0.0.1H9
O.H'MH
0.87.-S8
0.9*7
0.9J87
1.0136
1.0/85
l.lUSlf
1.2033
1.2582
1.3132
1.3581 •
1.1*030
1.14-1*30
1.1*779
1.5179
1.5W
1.5728
1.5978
.1 .6177
:i .6 <77
.1 .u;a
•l.''77Y
)..^Hr!d
l.C>777
l.f.f.77
I.c,'i77
1.6227
1.5978
1.5678
1.5279
l.'*530
1. 368.1.
1.2682
J . 1.68'i
J .oi>8s
0.
-------
GRAVIMETRIC   FLOW   EXPERIMENTS
Run:
Dry Weight:
Deflection :
S02:
Carbon:
175-G
102. 56 ing.
-6.16 ing.
2000 ppra
EXC-3
NO:
02:
H20:
t:

0 ppm
3.5%
6.0$
200° F

t
                                                        1500 cc/min.
                                                        73-58
                                            Correction:  0.1+980
                                            Date:        July 16, 1971
Time
inj nutos
1
2
3
k
5
6
7
8-
9
10
12
lit
16
18
20
25
30
35
1+0
U5
50
60
70
80
90
100
110
120
130
l!|0
150
160
170
180
300
200
230
<«(>
2 '•',()
2'iO
2'.<0
?V>0
270
2.<<>
2')0
3(10
Load
ing. HgSOli/K. C
6.3^
8.29
9-5<>
10.l|\
11.31 -
12.09
12.77
13.W
1H.1.1+
1.1+.72
16.19
17.55
19.01
20. 1*8
22.01+
26.23
30.91
. 36.08
lU.Mt '
1*7.19
53-33
66.50
80. 5'+
95- H6
1.10.18 .
125-39
lit 1.38
157.37
172.87
.188.09
201.93
21.lt. 90
228 . 16
21(1.22
253- Jil
265. Ill
276. <0
.2H7.(i'i
2', ,'7. 00
'.U) . IK'I
.', I'l .'i)|
32 x.('.r;
^1.71.
•i -i'-).ii.i
',iir,.;,;!
Hr< '<.')'(
Mean Load
mg. HgSOl^/g. C
2
1+
6
8
10
-, :i2
ii*
16
18
20
25
30
35
1+0
't5
50
55
60
65
70
75
80
85
90
95
1.00
110
120
130
1^0
150
160
170
180
190
200
220
21+0
260
280
300
320
i'K)



Rate
mg. HgSOij/g. C/min.
8.239],
5 • 1677
3.120.1
1.7'i53-
0.8970
0.7110
0.6533
0.6728
0.7215
0.7605
0.8678
0.9555
1.0238
1.1018
1.1603
1.21.88
1.2676
1.3066
1-3358
1.37W
i.i+oin
1A333
1.1(528
lA?23
I.li91.8
1.5113
.1.5308
1.5503
1.5601
1.5601
1-5503
1.5308
1.5113
1.U821
l.Ul+31
l.l+oUi
1 . 3066
1.2188
1.1.1|08
1.0628
0.0653
0.8678
0.760',",



                     419
-------
                        APPENDIX A-15-2
           SURFACE AREA AND PORE VOLUME DISTRIBUTION
                  OF SOLVENT EXTRACTED CARBON
  Surface area and pore volume distribution measurements were
  made by means of nitrogen isotherms on the Englehard Isorpta,
  Englehard Industries, Inc., Newark, New Jersey.  The surface
  area was calculated from the BET equation12* and the pore
  volume distribution with a computer program we have using the
  Roberts13 method of pore determination.  In the tables given
  in this section, REL P is relative pressure and VOLUME is
  volume adsorbed of nitrogen in cc./g. C.  Other designations
  are S = surface area in m2/g. C; C = the BET constant, and
  R = the correlation coefficient.  PORE RADIUS is the range
  of pore size in A; VOL is the volume in cc./g. C in that
  range; and CUMV is the cumulative volume to that point.
     *References are listed in Bibliography,  Section 8,  in
Volume I.
                             420
-------
        SAMPLE:  EXA-1
    RFL  P
v/OLUME
U. 1423
o. i 7a2
0.2141
0. 3219
0.4296
0.5374
0.6452
0. 7529
O.t,607
0.9685
S 193.
C -34
R 0.9980
0.09.13
0.0990
0.1015
0.1078
0.1135
0. 1182
0.1226
0.1260
0.1318
0.1389
7
.257

PORE RADIUS
     VOL
CUMy/
1000.
500.
400.
300.
200.
150.
100.
90.
dO.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
U.
12.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
10.
0.0012
0.0006
O.OOC9
0.0016
0.00 I1* "
0.0027
0.0009
0.0011
O.OC13
0.0017
0.0021
0.0015
0.0018
0.0022
0.0029
0.0043
0.0063
0.0041
0.0055
0.0070
0.0076
A. 0.0114
0.0012
0.0018
0.0026
0.0042
U.OObY
O.OOt'4
0.0093
0.0103
0.0116
0.0133
0 . 0 lt> 7
0.0172
0.0191
0.0213
0.0242
0.0285
0.0353
0.0394
0.0449
0.0519
0.05vl>
0.0700
                  421
-------
          SAMPLE:  EXA-2
REL P
VOLUME













PORE
1000.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
0.1488
0.1865
0.2243
0.3375
0.4508
0.5641
0.6773
0.7906
0.9039
0.9869
S 167.7
C -28.
R 0.9991
RADIUS
500.
400.
	 300. 	
200.
150.
	 100. - -
90.
80.
70.
60.
50.
45. 	
40.
35.
30.
25.
20.
18.
16.
14.
12.
10.
0.0856-—
0.0878
0.0900
0.0966 	
0.1028
0.1003
0.1133 	
0.1180
0.1234
0.1287 .-

132

VOL
0.0009
0.0004
	 0.0007 	 	
0.0013
0.0012
0.0023 — 	
0.0008
0.0010
0.0012
0.0016
0.0023
--0.0015 	 	
0.0019
0.0024
... .. . 0.003i
0.0048
0.0078
0.0047
0.0059
0.0070
0.0077 	 	
0.0077













CUMV
0.0009
0.0013
0.-0020 	
0.0032
0.0045
0.0068 	 - 	
0.0076
0.0085
0.0097
0.0113
0.0136
0.0151 	
0.0170
0.0195
0.0227
0.0275
0.0353
0.0400
0.0459
0.0529
0.0606 " ' '
0.0683
                 422
-------
           SAMPLE:  EXA-3
REL P
VOLUME













PORE
1000.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
lb.
16.
14.
12.
0.1488
0. 1865
0.2243
0*3375
0.4508
0.5641
0.6773
0.7906
0.9039
0.9869
S 	 650.9
C -20.
R 0.9983
RADIUS
500.
400.
300.
200.
150.
— 100. -
90.
80.
70.- 	
60.
50.
_._-_... 45.
40.
35.
30. 	
25.
20.
18.
16.
14.
12.
10.
0.3620
0.3684
0.3731
0.3850
0 . 3 94 8
O.'»027
0.4096
0.4161
0.4231
0.4296-- •
•
340

VOL
0.0010
0.0005
0.0008
0.0016
0.0015
	 0.0029 	 - 	
0.0010
0.0012
- 0.0016 - -
0.0021
0.0030
— 0.0021 	
0.0026
0.0034
	 0.0045 	 -
0.0066
O.Olll
-- 0.0071 	 	
0.0094
0.0120
0.0151 	
0.0210













CUMV
0.0010
0.0015
0.0023
0.0039
0.0054
0.0084-
0.0093
0.0106
0.0121 	
0.0142
0.0173
-0.0194 	
0.0220
0.0254
-0.0299
0.0365
0.0476
0.0547
0.0641
0.0761 "
-0.0912
0. 1122
                 423
-------
    REL P
             SAMPLE:   EXA- 5
VOLUME
0. 1428
0.1791
C.2153
0.3241
0.4328
0.5416
0.6504
0.7591
0.8679
0.9766
0.3382
0.3430
0.3478
0.3588
0.3683
0.3759
0.3831
0.3898
0.3975
0.4093
     S    620.8
     C     -22.416
     R  0.9985
PORE RADIUS
     VOL
CUMV
1000.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
10.
0.0026
O.OG10
0.0015
0.0026
0.0023.
0.0041
0.0013
0.0015
0.0019
0.0025
0.0035
0.0024
0.0029
0.0036
0.0048
0.0069
o.oion
0.0066
0.0092
0.0117
0.0133 -
0.0201
0.0026
0.0037
0.0052
0.0079
0.0102
0.0143
0.0155
0.0171
0.0190
0.0215
0.0250
0.0274
0.030H
0.0339
0.0387
0.0456
0.0564
0.0630
0.0722
0.0840
0.09'M
0. 1174
                    424
-------
          SAMPLE:  EXB-3
    REL P
VOLUME
0.1426
0. 1788
0.2151
0.3237
0.4323
0.5409
0.6495
0.7581
0.8667
0.9753
S 667.
C -22
R 0.9986
0.3636
0.3690
0.3734
0.3855
0.3956
0.4039
0.4115
0.4184
0.4257
0.4350
5
.456

PORE RADIUS
     VOL
CUMV
1000.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
10.
0.0015
0.0007
0.0010
0.0019
0.0018
0.0034-
0.0011
0.0014
0.0018
0.0024
0.0034
0.0023
0.0029
0.0038
0.0051
0.0074
0.0119
0.0073
0.0097
0.0125
0.0156
0.0187 -
0.0015
0.0022
0.0032
0.0051
0.0069
0.0104
0.0115
0.0129
0.0146
0.0 1 70
0.0204
0.0227
0.0256
0.0294
0.0345
0.0419
0.0538
0.0611
0.0708
0.0833
0.0990
0.1176
               425
-------
           SAMPLE:  EXB-4
    REL P
    0.9741
VOLUME
0.1425
0.1786
0.21^8
0.3232
0.4317
0.5402
0.6487
0.7571
0.8656
0.3720
0.3772
0.3816
0.3931
0.4023
0.4100
0.4167
0.4237
0.4309
0.4407
     S    680.1
     C     -22.182
     R  0.9986
PORE RADIUS
     VCL
CUMV
1000.
500.
400.
30U.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40. .
35.
30.
25.
20.
18.
16.
14.
12.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
10.
0.0021
0.0008
0.0013
0.0022"
0.0020 '
O.OC35
O.OOll'
0.0014
0.0013
0.0024
0.0034
0.0023
0.0030
0.0039
0.00.49
0.0063
0.0106
0.0068
0.0089
0.0115
0.0148
--•0.0189
0.0021
0.0030
0.0042
0.0064
0.0084
0.0119
0.0130
0.0144
0.0162
0 . 0 1 b 5
0.0219
0.0242
0.0272
0.0310
0.0360
0.0423
0.0529
0.0597
0.06U6
0.0800
0.0948
0.1137
                   426
-------
       SAMPLE:   EXB-5
REL P
VOLUME
.. -












PORE
1000.
500.
400,
300.
200,
	 150*
100.
90.
80.
-- - - \f *^ w
70.
60.
50»
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
0.1484 ...
0.1860
0.2237
0.3366
0.4496
0.5626
0.6755 	
0.7885
0.9015
0.9994 ....
S 	 -73K4
C -19.
R 0.9983
RADIUS
500.
400.
	 300. 	
200.
150.
	 100* 	
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
10.
o.4ioa 	
0.4169
0.4213
0.4334_ __,_.
0.4439
0.4530
0.4 60! 	 ,_.
0.4679
0.4756
0.4842

859

VOL
0.0011
0.0005
	 0.0009_.^...
0.0017
0.0017
... 	 0.0032... ..
0.0011
0.0013
0.0017 .
0.0023
0.0034
u 	 O.OQ24
0.0030
0.0038
0.0051 . ..
0.00/3
0.0128
0.0080 .
0.0102
0.0125
0.0148
0.0188













CUMV
0.0011
0.0017
	 	 fl.0026 	
0.0043
0.0059
._ 	 0.0091 	 	
0.0102
0.0115
0.01 H
0.0156
0.0190
o.opn
0.0243
0.0282
_ 	 0.0332
0.0405
0.0533
_ . 0.0613
0.0714
0.0839
0.0988
0.1175
               427
-------
           SAMPLE:  EXC-1
    REL  P
VOLUME
0. 1426
0. 1788
0.2151
0.3237
0.4323
0.5409
0.6495
0.7581
0.8667
0.9753
S 628.
C -22
R 0.9985
0.3442
0.3489
0.3531
0.3634
0.3722
0.3805
0.3873
0.3937
0.4007
0.4132
0
.024

PORE RADIUS
     VOL
CUMV
1000.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
10.
0.0040
0.0014
0.0020
0.0031
0.0025
0.0041 •
0.0012
0.0015
0.0018.
0.0023
0.0032
0.0021
0.0027
0.0034
0.0045
0.0065
0.0115
0.0073
0.0086
0.0104
0.0127
0.0174 '
0.0040
0.0054
0.0074
0.0105
0.0130
0.0171
0.0 l»3
0.0197
0.021r>
0.0238
0.0270
0.0291
0.0318
0.0353
0.0398
0.0463
0.0578
0.0651
0.0737
0.0841
0.0963
O.U41
                 428
-------
              SAMPLE:  EXC-2
      REL  P
        VOLUME
       R
   736.8
    -20
0.9982
 PORE  RADIUS
 1000.
 500.
 400.
 300.
 200.
 150.
.100.
  90.
  80.
  70.
  60.
  50.
  45.
  40.
  35.
  30.
  25.
  20.
  18.
  16.
  14.
  12.
 500.
 400.
 300.
 200*.
 150.
 100.
 -90.
 80.
 70.
	60 »
 50.
 45.
- 40.
 35.
 30.
 25.
 20.
 18.
 16.
 14.
 12.
 10.
0.4102
0.4172
0.4232
0.4348
0.4459 	 ._
0.4553
0.4624
0.4688 	
0.4768
0.4838
t
• 304 ..
VOL
	 0.0003 	
0.0004
0.0007
0.0016-
0.0017 '
0.0035
0.0012-
_ ,. — ._— - -^0 ^ ^f %^*«r ^ff^-f-m^,
0.0015
0.0019
0.0024
0.0034
0.0021
	 0*0026—
0.0033
0.0044
. .-0.0068.-.-
0.0132
0.0086
0.0109 ..
0.0125
0.0133
- 0.0262 .-











CUMV
	 „.„_.._ 0.0003
0.0007
0.0014
0.0030
0.0047
0.0082
0.0094
0.0109
0.0127
0.0151
0.0185
0.0206
— 	 0.0232
0.0266
0.0310
	 0.0378
0.0510
0.0596
_. 0.0705
0.0831
0.0964
	 0.1226
                   429
-------
            SAMPLE:  EXC-3
    REL P

    0.1478
    0.1853
    0.2228
    0.3353
    0.4478
    0.5604
    0.6729
    0.7854
    0.8979
    0.9880
VOLUME

0.4228
0.4291
0.4338
0.4453
0.4553
0.4634
0.4707
0.4780
0.4857
0.4925
     S    752.8
     C     -19.881
     R  0.9983
PORE RADIUS
     VOL
1000..
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
. 500.
400.
300.
-—200*.
150.
100.
-. .... . 90.
80.
70.
... 60.
50.
45.
	 40.
35.
30.
25.
20.
18.
16.
14.
12.
--•- 10.
. ... -0.0006
0.0004
0.0007
0.0015
0.0016
0.0032
0.0011
0.0014
0.0018
0.0024
0.0034
0.0024
- ~~ 0.0030-
0.0039
0.0050
, 0.0070
0.0113
0.0071
- 0.0096
0.0119
0.0142
	 -.._ 0.0202-
  CUMV

 0.0006..
 0.0010
 0.0017
-O..0032-
 0.0048
 0.0079
 0.0090
 0.0104
 0.0121
 0.0145.
 0.0179
 0.0203
-0.0233-
 0.0272
 0.0322
 0.0391
 0.0504
 0.0575
 0.0671
 0.0790
 0.0933
 0.1135
                    430
-------
              SAMPLE:  EXD-1
    REL- P
    0.1860
    0.2237
    0.3366
    0.4496
    0.5626
    0.6755
    0.7885
    0.9015
    0.9919
VOLUME.

0.0769
0.0792
0.0818
0.0896
0.0964
0.1019
0.1072
0.1121
0.1176
0.1236
     S    158.4
     C—-.  -37.043
     R  0.9995
PORF RADIUS
     VOL
CUMV
* v >^ v* »
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
400.
300.
	 200. 	 	
150.
100.
	 90. 	
80.
70.
60. -.-..
50.
45.
40.
35.
30.
25. .,
20.
18.
16.
14.
12.
10.
0.0009
0.0004
0.0007
0.0013
0.0012
0.0024
0.0008
0.0010
0.0012
0.0017
0.0024
0.0016
o_no ?o
\J % \J \J *-~ v
0.0026
0.0035
0.005 1
Vr 
-------
           SAMPLE EXH-1
REL P
VOLUME-













PORE
1000.
500.
400.
300.
200.
150.
100.
90.
BO.
70.
60.
50.
45.
40.
35.
30.
25.
20.
IB.
16.
14.
12.
0.1484
0. 1860
0.2237
0.3366
0.4496
0.5626
0.6755
0.7H85
0.9015
0.9919
S 721.
C -19
R 0.9984
RADIUS
500.--
400.
300.
..... 200.
150.
100.
- 90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
10.
0.4065
0.4106
0.4156
0.4278
0.4383 -
0.4471
0.4544
0.4619 	
0.4696
0.4781
7
.848 - 	 -~- -----

vot
	 -0.0014
0.0006
0.0010
0.0018 	
0.0017
0.0032
O.OOU
0.0013
0.0017
0.0023
0.0034
0.0025
0.0031 	
0.0040
0.0049
0.0069
0.0121
0.0078
0.0102
0.0127
0.0150
0.0192
                           CUMV

                          0.0014
                          0.0021
                          0.0030
                          0*0048
                          0.0065
                          0.0097
                          0.0108
                          0.0121
                          0.0138
                            0162
                            0196
                            0220
                          0.0251-
                          0.0291
                          0.0340
                          0.0409
                          0.0531
                          0.0608
                          0.0711
                          0.0837
                          0.0987
                          0.1179
                432
-------
         SAMPLE:  EXN-1
    REL  P      VOLUME
0. 1426
0.1788
0.2151
0.3237
0.4321
0.5409
0.6495
0.7581
0.8667
0.9753
0.1570
0.1603
0.1638
0.1721
0.1791
0.1850
0.1900
0.1944
0.1996
0.2074
     S    302.4
     C     -26.573
     R.  0.9988
PORE RADIUS
VOL
CUMV
1000.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
10.
0.0015
0.0007
0.00 10
0.0017
0.0016 .
0.0028
0.0009
0.0011
0.0013
0.0017
0.0024
0.0016
0.0018
0.0023
0.0031
0.0049
0.0083
0.0052
0.0068
0.00 86
0.0103 -
0.0148
0.0015
0.0022
0.0032
0.0049
0.0065
0.0093
0.0102
0.0112
0.0126
0.0143
0.0167
0.0182
0.0201
0.0224
0.0255
0.0304
0.0388
0.0440
0.0508
0.0594
0.0697
0.0844
                433
-------
         SAMPLE:  EXV-1
    REL  P
VOLUME
0.1428
0.1769
0.2149
0.3231
.0.4313
0.5395
0.5477
0.7559
0.&641
0.9722
S 667.4
C- -22.
R 0.9985
0.3628
0.3636 .
0.3733
0.3851
0.3950
0.4031
0.4103
0 . 4 1 6.8
0.4242
0.4350
«
544 	
•
PORE RADIUS
     VOL
CUMV
1000.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
500. '
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
Id.
16.
14.
12.
10.
0.0022 .
0.00.09
C.0014
0.0024
0.0022-
0.0040
0.0012
0.0015
0.0019
0.0025
0.0034
0.0023
0.002H
0.0035
O.C047
O.OOfO
0.0115
0.0071
0.0096
0.0123
0.0149 '
. 0.0204
. 0.0022
0.0031
0.0045
0.0070
0.0092
0.0131
- 0.0144
0.0159
0.0178
0.0203
C.0237
0.0260
0.0238
0.0323
0.0369
0.0439
0.0554
0.0625
0.0721
0.0844
0.0994
0.1198
          434
-------
                       APPENDIX A-16
        EXPERIMENTAL RESULTS OF BENCH SCALE RECYCLE
   TESTS - SOLVENT EXTRACTION VERSUS HYDROGEN TREATMENT
1.   S02 Sorption Results from 1" Diameter Fixed Bed      436
      for (NH4)2S Extracted and H2S Generation
      Carbon Samples

2.   S02 Sorption Results from Differential Rate          448
      Apparatus for (NH4)2S Extracted and H2S
      Generation Carbon Samples

3.   Sulfur Generation from 1" Diameter Fixed Bed for     453
      (NH4>2S Extracted and H2S Generation Carbon
      Samples

4.   (NH4>2S Extraction Experimental Results              462

5.   Pore Volume Distribution Runs for (NH4>2S            468
      Extracted and H2S Generation Samples after
      Sixth Cycle
                            435
-------
                        APPENDIX A-16-1

    S02 SORPTION RESULTS FROM 1"  DIAMETER FIXED BED
        FOR (NH4)oS  EXTRACTED AND  H2S  GENERATION
                        CARBON  SAMPLES
                 S02 SORPTION  RATE
                                             8  31 71
RXT-6-1A
JENPFRATURE  =_ 2p8.00QOOO_F	
SPACC VELOCITY «    0.299939E  0~4
INLET S02  MOLE FRACTION (DRY)  =
                               /HR
                                 0.002760
INLET H20 MOLE  FRACTION «__ _.Q.0.9997.8._	.
INLET OXYGEN  HOLE FRACTION =    0.035403
INLET C02 MOLE  FRACTION =    0.0
INLET NO KOLE FRAt.II.ON = „__ 0.000149
INLET INERT GAS MOLE FRACTION =    6.861992
INLET CARBON  WEIGHT =   40.000000 GMS
J.OTAL..GAS. J.COW _=	._7.0.61549_5.CFH	
               (WET) =
           0.0024H4
  TIME
           MOLE FRACTION.S02.
H2S04 LOADING
CMS ACID/GM C
RATE OF  H2S04 SORPTION
   GMS ACID/GM C-MIN
0. .
30.
60.
90.
120.
150.
. 180. _ .
210.
240.
_..260. . ._
0. M!>000t-0.*
0.315000E-03
0.396000E-03
._ 	 0..450000E.-03. 	
0.660000E-03
0.660000E-03
0.600000E-03 _
0.750QOOE-03
0.920000E-03
0.900000E-03
O.u
0.241539E-01
0.478977E-01
0.709748E-01
0.927576E-01
0.113503E 00
0.134545E 00
0.155143E 00
0.174160E 00
...0.186343E. 00
O.U
0.805129E-03
0.777798E-03
0.760674E-03
0.691522t-03
o.egisi'ZE-oj
0.711279E-OJ
0.661885E-03
0.605905E-03
0.612491E-03
AVERAGE  RATE OF S02 SORPTION
                                0.705465E-03
                                436
-------
                   S02 SORPTION RATE
                                    8 31 71
 RXT-6-2A
 TEMPERATURE  =  209.000000 F              _
"SPACE  VELOCITY =    0.299961E 04"/HR	~
 INLET  S02 MULE FRACTION (DRY) =    0.002760
 INLET  H20 MOLE FRACTION *    0.100021
 INLET  OXYGtN MOLE  TRACTION =    0.035045
 INLET  C02 MOLF FRACTION =    0.0
 INLET  NO HOLE FRACTICN =    0.000)50
 INLET  INEK1  GAS MOLE FRACTION =    0.862302
 INLET  CARPON WEIGHT =   29.899994  GMS
 TOTAL  GAS FLOW =    5.278689 SCFH
                                      (W6T) =
                           0.002484
   TIME
     0
    30
    60
    ?.P
   120
   150.
MOLE FRACTION S02
H2S04 LOADING
GMS ACID/GM C
RATE OF II2S04 SORPTIC.N
   GMS ACID/GM C-I-'1N
0.150000E-03
0.150000E--03
0.510000E-03
0.690000E-03
"0.102000E-0?"" 	
0.100500E-02
0.108000E-02
0.120000E-02
0.0
0.257a'tf»E-01
0.497908E-01
0.711296E-01
0.699^030-01
0. 107213E 00
0.124180E 00
0.140185E 00
0.0
0.859484E-03
0.740934E-03
	 0.681660E-03.
f\ K i "\f\ n i™» i~ ^ "»
Wft^i£.'^"w V_*
0.57/929E-03
0.55J231t-03
0.513715E-03
  210
 AVERAGE,RATE  OF  S02 SORPTION =
                       0.642B48E-03
                          437
-------
                    S02 SORPTtON RATE
                                    8 31 71
  RXT-6-3A
	TEMPERATURE =  199.000000 F _	
  SPACE Vl:i.OCitY *    0.299982E O'l /HR
  INLET S02 HOLE FRACTION (DRY) =    0.002780
iiJNLCT H20 MOLE FRACTIQM =.  .  0.100036	
  INLET OXYGEN MOLE FRACTION =    0.034975
  INLCT C02 MOLE FRACTION =    0.0
  INLIT NO fOLE FRACTIUN =    0.000150
  INLET INERl GAS MOLE FRACTION =    0.862338
  INLUT CARBON WEIGHT =   30. 11999!> CMS
  TUTAL GAS FLOW =    5.3180.99 SCFH  _     _
                                      (WET)
                           0.002502
    TIME
MOLE FRACTIOM S02
H2S04 LOADING
GMS ACID/GM C
RATE OF H2SO't SORPTIO^
   CMS AC10/GM C-I-'.IN
_ -. 0. ...,.
30.
60.
90.
, 120.
150.
. .lap, ..
210.
240.
0.270000E-03
0.270000E-03
0.420000E-03
0.585000E-03
«,. 780nnoe-0*
0.1035006-02
0.102000E-02
0.916000E-03
0.885000E-03
0.0
0. 2^79796-01
O.A88546E-01
0.7U557E-01
0.920782E-01
0..110576E 00
0.127892E 00
0.145794E 00
0.164363E PO
0.0
0.82659BC-03
0.777199E-03
0.722862E 03
0.65B644e-03
&.574667E-03
0.579607E-03
0.613856E--03
0.624065t-03
  AVERAGE  RATE  OF  S02  SORPTION =
                       0.672186E-03
                           438
-------
                   S02 SORPTtON RATE
              8 31 71
 RXT-6-4A
 TEMPERATURE =_  204.000000 F 	   _
 SPACE  VELOCITY  =    0.299933E 04 "/MR
 INLET  S02 MOLE  FRACTION (DRY) =    0.002780
 INLET  H20 MOLE  FRACTION =    0.100043
 INLET  OXYGEN MOLE FRACTION =    0.034948
 INLET  C02 MOLE  FRACTION =    0.0
 INLET  NO fOLE FRACTION =    0.000150
 INLET  INERT GAS MOLE FRACTION ' ="    0.862364
 INLET  CARBON WEIGHT =   29.500000  GMS
 TOTAL  GAS FLOW  =    5.207779 SCFH
                (WET)
           0.002502
   TIME      MOLE FRACTION S02
     0. _      0.120000E-03
    30.        0.120000E-03
    60.        0.570000E-03
    90.     _  0.750000E-03
   120.        0.764000F-03
   150.        0.930000E-03
	180.   	0.1Q3500E-02	
•   210.        0.120800E-02
   240.        0.120800E-02
   270.        0.1275006-02
   290.        0.135000E-02

 AVERAGE  RATE OF S02 SORPTION =
H2S04 LOADING
GMS ACIO/GM C

 0.0
 0.262754E-01
 0.503282E-01
_0.712694E-P1
 0.912524E-01
 0.110346E 00
 0.128102E 00
 0.144485E 00
 0.160013E 00
 0.175210E 00
 0.184874E 00

 0.616974E-03
RATE OF H2S04 SORP1ION
   GMS ACIO/GM C-MIN

 	0.0
     0.875846E-03
     0.727676E-03
     C.668408t-03
     0.663799E-03
     0.517605E-03
     0.517605E-03
     C.495544E-03
     0.470849E-03
                        439
-------
                   S02 SORPTION RATE
                                                 8 31 71
RXT-6-5A

TEMPERATURE  =  206.000000 F 	
SPACE  VELOCITY =    0.299917E 04 /HR
INLET  S02  MOLE FRACTION (DRY) «     0.002780
INLET  1120. MOLE FRACTION. =	Q.*_LQ.0.0.26_.		
INLET  OXYGEN MOLE FRACTION =    0.035019
INLET  C02  MOLE FRACTION =    0.0
1NLLT  NO MOLE FRACTION =.    O.OOOIVJ.
INLET  INERT  GAS MOLE FRACTION =     0.862311
INLET  CARBON WEIGHT -   29.279999 CMS
.TOTAL  GA.S . FLOW =	5..168670_._$.CJH _  	
                                                              0.002502
  TIME . __   MOLF  FRACTION S02
                                  H2SO't  LOADING
                                  CMS  ACIO/GM C
                RATE OF  H2SOA
                   GMS AC1U/GM C-HI'N
    0.
   30.
   60.
   90,
  120.
  IbO.
  210.
  240.
  270.
  300.
  320.
              0.270000E-03
              0.270000E-03
              0.720000E-03
          	D.87.0000E.-Q3-
              0.107000E-02
              0.105000E-02
          	Q..1.0.3.5 0.0 E-Q2_
              0.117000E-02
              0.135000E-02
          	0..1A2500E-02.
              0.150000E-02
              0.150000E-02
0.0
0.247928E-01
O.A73632E-01
0.669702E-01
0.0
0.82642BH-03
0.678264E-03
 0.102332E 00
.0_«JL19A94E_P.O..
 0.136064E 00
 0.151078E 00
           00
           00
 0.186275E 00
 0*^7'>'»CCH C3»
 0.569610E-03
...0 ..5_7.ft,549E.-_0_3_..
 0.530099E-03
.Q,44614_OE-03..
 6.42l445t-03
 0.421445E-03
AVERAGE RATE  OF  502  SORPTION
                                   0.563127E-03
                            440
-------
                   S02 SORPTION RATE
                                    8 31 71
 RXT-6-6A
_TGMPERATURE_ =  199.000000 F         __   	
 SPACE  VELOC ITY "~=	6729862 1 FT 04 ~/ll~R	
 INLET  S02 MOLE FRACTION (DRY) =    0.002700
 INLET  H20 MOLE FRACTION =    0.100015
"INLET  OXYGEN MOLE FRACTION =    0.034935
 INLET  C02 MOLE FRACTION =    0.0
 INLET  NO MOLE FRACTION =    0.000150
"INLET  INERT GAS MOLE FRACTION" ="   0'. 862405
 INLET  CARBON WEIGHT =   28.500000 GMS
 TOTAL  GAS FLUW =    5.009249 SCFH
                                      UET)  =
                           0.00243U
   TIME
MOLE FRACTION S02
H2S04 LOADING
GMS ACID/GM C
RATE OF H2S04
   CMS ACID/GM C-MIN
0.
30.
60.
90.
120.
150.
180-
210.
240.
270.
280.
0.0
0.0
0.390000E-03
0.780000E-03
0.855000E-03
0.930000E-03
0.108000E-02
0.121500E-02
0.118500E-02
0.12'4500E-02
0.129000E-02
0.0
0.265547E-01
0.5H916E-01
0.719927E-01
0.905072E-01
0.108284E 00
0.124954E 00
0.1'i0223E 00
0.154976E 00
0.169581E 00
0.174277E 00
U.O
0.88&157I>03
0.757301E-03
0.629445E-03
0.604857E-03
0.580270E-03
0.531094C-03
0.4K6tt3ot-ui
0.496671E-03
0.477001c-03
0.462248E-03
 AVERAGE RATE OF S02 SORPTION =
                       0.600290E-03
                        441
-------
                    S02 SORPTION RATE
                                    8 31 71
  RXT-7-1A

 ^TEMPERATURE =  20.6.000000 £	..
  SPACE VELOCITY =    0.299977E 04 /HR
:  INLET S02 MOLE FRACTION (DRY) =    0.002740
L INLET H20 MOLE FRACTION ~ 	0.099965_ 		
  INLET OXYGEN MOLE FRACTION =    6.035398
  INLtT C02 MOLE FRACTION a    0.0
.. INLtT NO MOLE FRACTION =    0.000149
  INLET INERT GAS MOLE FRACTION =    0.862024
:  INLET CARBON WEIGHT =   40.000000 GMS
,_ryiAL GAS_rLOw =    7.062449 S.CFH	:_
                                      (WET>
                           0.002466
    TIME
MOLE FRACTION S02
H2S04 LOADING
GMS ACID/GM C
RATE OF H2S04 SORPTION
   GXS ACIO/GN C-MIN'
.0.150000C— 03
0.150000E-03
0.210000E-03
0.300000E-03
0.330000E-03
0.345000fc-03
0.570000E-03
0.600000E-03
0.750000C-03
0.0
0.255899E-01
0.508834E-01
0.754359E-01
0.993956C-01
0.123133!: 00
0.145685E 00
0.166977E 00
0.183979E 00
0.0
0.852998E-03
0.8:j3237E-03
0.803596E-03
0.79Jl7l6t-03 """
U. /bH/Yt-t-03
0.714674E-03
0.704793E-03
0.655392E-03
:!: AVERAGE RATE OF S02 SORPTION =
                       0.770802E-03
                           442
-------
                   S02 SORPTION RATE
8 31 71
 RXT-7-2A
.TEMPERATURE =  203.000000 F
 SPACE  VELOCITY" = ~r~ b.299962'E~ "oV/HR	~
 INLET  SU2 MOLE FRACTION (DRY) =    0.002760
.INLET  H20 HOLE FRACTION =    0.099964
 INLtT  OXYGLN MOLE FRACTION =    0.034952
 INLET  C02 MOLE FRACTION =    0.0
 INLET  NO KOLE FRACTION =    0.000150
 INLET  INER1 GAS MOLE FRACTION =    0.862't!>2
 INLET  CARBON WEIGHT =   32.409988 GMS
 TOTAL  GAS FLOW =    5.722059 SCFH
  (WET)  =
O.C02't84
J I ME
0.
30.
60.
90.
120.
150.
180.
210.
240.
••270.
300.
330.
360.
390.
420.
A 50.
480.
4B5.
'ERAG
	 MOLE FRACTION S02
0.138000E-02
0.138000E-02
0.158500E-02
'.'. 0.163500E-02
0.174000E-02
0.186000E-02
0. 180000E-02
0.16650QE-02
0.162000E-02
0.166000E-02
0.177000E-02
0.166500E-02
0.165000E-02
0.180000E-02
0.186000E-02
0.198000E-02
0.204000E-02
0.202000E-02
E~R ATF"OF '1'02~ SORPT fON
H2SOA LOADING RATE OF H2SOA SORPTION
GMS AC1D/GM C GKS AC ID/ CM C-M1N
0.0 0.0
0.136341E-01 0.454471E-03
0.2625b6E-01 0. 3869!>9t-03
0.376173E-01 _ 0. 370492E-03
0.482134E-01 0. 33591 3t-03
0.576980E-01 0. 296394F-03
0.660062E-OI 0. 31ol54E-03
0.770376E-01
0.880783E-01
0.991436E-01
0.109468E 00
0.119768E 00
	 0.130660E.OQ 	
C.140886E 00
0-150074E 00
0.158373E 00
"""O. 165783'E 00
0.166985E 00
0.337610E-03
0.360613t-03
0.375432E-03
0.362259E-03.
0.326033E-03
0.360613E-03
0.365552E-03
0.316154E-03
0.29639AE-03
C.25687tjE-03 .
0.237115C-03
0.243702E-03

                           443
-------
                  S02 SORPTION  RATE
                                     8  31 71
RXT-7-3A

TEMPERATURE_= _ 20.^.000000. F	„	
SPACE VELOCITY =    0.299944E  0'*  /MR
INLET S02 MULE FRACTION  (URY)  *     0.002780
INLCT H20 MOLE FRACTION  =  __Q_._lOOpfi5	:
INLET OXYGF.N MOLE FRACTION =    0.035078
INLET co2 MOLE FRACTION  =    o.o
INLET NC MOLE FRACTION =   0.000149
INLET INERT GAS MOLE  FRACTION  *     0.862216
INLET CARBON WEIGHT =    27.289993 GMS
TOTAL GAS FLOW =    4.8 17.819__SC,FH.	
                                       (WET)  -
                            0.002502
  TIME
    0. . _
   30.
   60.
   90. _
  120.
  150.
  1 HO -   _
  210.""
  240.
 ..27Q._	
  300.
  330.
 -360.	
  390.
  420.
 __450.	
  480.
  510.
 .^520.		
MOLE FRACTION S02
  0.117000E-02
  6.117000E-02
  O.l'tlOOOE-02
  0.144000E-02
  0.153000E-02
  0.168000E-02
  h, l is?OOr>F-0?
  0.180000E-02
  0.177000E-02
  0.186000E-02
  0.194000E-02
  0.188500E-02
  .0.187000E.T02_
  0.195000E-02
  0.196500E-02
  0.189000E-02.
  0.196500E-02
  0.208000E-02
  0.2100.0QE-02,
H2S04 LOADING
GMS ACIO/GM C
RATE OF H2S04  SORPTICN
   GMS 'ACID/GM C-KIN
0.0
0.159041E-01
0.306227E-01
0.440078E-01
0.568002E-01
0.684072E-01
0.795696E-01
0.901394E-01
0.999683E-01
0.109501E 00
0.118194E 00
0.126763E 00
	 , 	 .0... 135.6.7.8 E. .00..
0.144272E 00
0.152397E 00
0.160818E 00
0.169240E 00
0.176722E 00
- 	 _. 0.,. 1.7 3 9 9.4 E. 00
0.0
0.530136E-03
0.451109t-Q3
0.441231E-03
0.411596E-03
0.362205E-03
0.381961E-03
0.3226911: -03
0.332569E-03
0.302935E-03
C.276593E-03
0.294703E-03
672 7 3 300 E - 0 3
0.268361E-03
C.293056E-03
0.268361E-03
0.230494E-03
0.223908E-03
AVERAGE RATE OF S02 SORPTION
                       0.335513E-03
                          444
-------
                  $02 SORPTION  RATE
                                    8 31 71
RXT-7-4A
TEMPERATURE =  202.000000  F
SPACE VELOCITY =    0. 299954E~"~04  /HR  "
INLL-T 502 MOLE FRACTION  (URYJ  =    0.002780
INLET H20 MOLE FRACTION  =     0.100010
INLET OXYGEN MOLE  FRACTION =    0.034786
INLET C02 MOLE FRACTION  =     0.0
INLET NO MOLE FRACTION =   0.000149
INLET INERT GAS MOLE FRACTION  =    0.862560
INLET CAKUUN WEIGHT =    24.750000 GMS
TOTAL GAS FLOW =    A.369549  SCFH
                                      (WET) =
                           0.002^02
  TIME
MOLE FRACTION S02
H2S04 LOADING
GMS ACIO/GM C
RATE OF II2S04 SORPTION
   GMS ACID/GM C-I'.IN
:".. 0 .
30.
60.
90.
1 120.
'• iyO.
. 180.
210.
240.
270.
; 300.
330.
360.
390.
420.
450.
480.
510.
540.
570.
0.135000E-02
0.135000E-02
0.167000E-02
0.180000F:-02
0. 186000E-02
0* i*' >OvV^u"" O" C.
0.186000E-02
0.195000E-02
0.192000E-02
0.201000E-02
O.183000E-02
0.171000E-02
0.165000E-02
0.165000E-02
0.156000E-02
0.162000E-02
0.162000E-02
0.192000E-02
0.200000E-02
0.200000E-02
0.0
0.141270E-01
0.266733E-01
0.369969E-01
0.463819E-01
0.5502COC-C1
0.636702E-01
0.723143E-01
0.806620E-01
0.887133E-01
0.972093E-01
0.107187E 00
0.1180'34E 00
0.129217E 00
0.140825E 00
0.152581E 00
0.164041E 00
0.174018K 00
0.182119E 00
0.189825E 00
0.0
0.470900t:-03
0.365524E-03
0.322714E-03
0«3029t)6E-03
n •> 7 J 7 I o c — r> i
0.302956E-03
0.273319E-03
0.283198E-03
0.253561E-03
0.312835E-03
0.352351E-03
0.372110E-03
0.372HCE-03
0.401747E-03
0.38L989E-03
0.381989E-03
0.2H3198E-03
0.2b6n54e-03
0.2')6b54fc-03
AVERAGE RATE OF S02 SORPTION
                       0.327393E-03
                         445
-------
                   S02 SORPTIQN RATE
                                                8 31 71
 RXT-7-5A

 TEMPERATURE  =__?03.000QQp_JF	,_
 SPACE  VELOCITY =    0.299947E 04 /HR
 INLET  S02  MOLE FRACTION IUE_-JQ1...
  0.9A8716E-01
  0.103639E 00
  0.1102>9E 00
  0.116335E 00
  0.121744L 00
.__0.126.700F 00
  0.131228E 00
  0.135452E 00
  0.139602E 00
  0.144047F 00
  0.148493E 00
	0_.J..52.7.9IE 00
  0.157015E 00

  0.206751t-03
RATL-
  : H2S04
  ACID/OK C-NIN
0..0
0.263462E-03
0.24b995E-03
0.276635E-03
0.246995E-03
0.2272.36^-03
0.256875E-03
0.227236E-03
0.204183E-03
0.246995E-03
0.246995E-03
0.263462.t-03
0.2272.36E-03
0.223942E-03
0.217356E-03
0.1fi7717E-03
0. 172097E-03
0. l^^07tE-0^_
0.143257L-03
0. 13U317L-03
0.13BJ17L-03
0. 15 HO 7 71: -03
0.138317C-03
0_. 14U197C-03
0. 133378F-03
                         446
-------
                  S02 SORPT10N RATE
             8 31 71
RXT-7-6A
TEMPERATURE = 203.000000 F
SPACE VELOCITY *" 0. 299986E
INL1IT 5112 MOLE FRACTION (DRY)
INLET H?0 MOLE FRACTION =
INLET OXYGEN MOLE FRACTION =
IMLET C02 MOLE FRACTION =
INLET NO MOLE FRACTION = 0
INLET INERT GAS MOLE FRACTION

04 /HR
- 0.002760
0.099932
0.014928
0.0
.000150
0.862bl7


(WET) = 0.0024K-'.





INLET CARBON WEIGHT = 23.349991 CMS
TOTAL GAS FLOW = 4.122819
	 TIME _.MOLE FRACTION .502

0. 0. 163500E-02
30. 0.163500E-02 	
60. 0.171000E-02
90. 0.192000E-02
,-j. 120. 0.198000E-02
? 150. 0.204000E-02
ISO. 0. 1950CCE- 02
210. 0.198000E-02
240. 0.201000E-02
270. 0.213000E-02
i: 300. 0.207000E-02
: 330. 0.211000E-02
345. 0.210500E-02
360. 0.210000E-02
390. 0.216000E-02
420. 0.1.95000E-02
! 450. 0.205000C-02
* 480. 0.207000E-02
__ 510. 	 .0..2.15QOOE-02 	
540. 0.19500QE-02
570. 0.195000E-02
600. 	 0.206000E-02
630. 0.204000E-02
660. 0.210000E--0.?
690. 0.207000E-02
710. 0.207000E-02
SCFH
H2S04 LOADING
CMS ACID/CM C
0.0
O.lll 160E-01 '
0.218615E-01
0.311990E-01
0.392026E-01
0.466133E-01
0.5*,1722E-01
0.620275E-01
0.695064E-01
0.764042E-01
0.829256E-01
0.695458E-01
0.927694E-01
0.96017BE-01
0.102243E 00
0.109209E 00
0.116718E 00
0.123635E 00
0.130057E 00
6.137073C 00
0.145076E 00
0. 152-5366 00
0.159552E 00
0.166370E 00
0.173039E 00.
0.177584E 00

RATE OF H2SO'( SOKPTION
CMS AC1U/GK C-J'IN
	 0.0
0.370535E-63
0.345832E-03
0.2/6666E-03
0.2'.>6904E-03
0.237142F-03
0.26t7S5i'-03
0.256904E-03
0.247023E-03
0.207'50CE-03
G.22/26H--03
0.214087E-03
0.215734E-03
0.217381E-03
0.197619E-03
0.266785E-03
0.233849E-03
0.227261E-03
_0.200912E-03
0.26f>785t--OJ
0.266785L-03
0.2305'55E-03
0.237142E-03
0.217381E-03
0.227261E-03
0.227261E-03
AVERAGE RATE OF 502 SORPT10N
0.24705/E-03
                           447
-------
                   APPENDIX A-16-2
   SOo  SORPTION  RESULTS  FROM DIFFERENTIAL RATE
     APPARATUS FOR  (NH4)2S EXTRACTED AND H2S
              GENERATION CARBON  SAMPLES
                    GRAVIMETRIC FLOW EXPERIMENTS
Run:       180-G          SO?.:
Dry Weight:  95.10 mg        NO:
Deflection:  -6.18 mg.       02=
Carbon:     Virgin,         HgO:
            C-70-7T
2000 ppm
150 ppm
3.5#
6.055
          200°F
          1500 cc/min.
          75.11*
Correction:  0.1(907
Date:      August 3, 1971
Time
minutes
1
2
3
It
5
6
7
8
9
10
12
1>)
16
18
20
?5
30
35
1)0
1)5
50
60
70
80
90
100
330
120
330
11)0
150
360
170
180
190
200
230
2?P
230
2')0
250
260
270
280
290
300
Load
mg. HpSOlj/g. C
ll).72
37.35
39.35
20.93
22.08
23.fl)
2l) . 1(0
25.55
26.71
27.87
29-97
32.07
3l).17
36.38
38 . 1)9
Itl4.36
iio.aii
55.1)2
61.20
66.88
72.55
83.70
95-06
106.1)1
33.7.67
128 . 39
130.80
31)9.21
159-52
]6o.liO
379.18
380.06
198.32
207.36
215.77
223.76
231.1)1)
239.32
?1)6.27
253. 1(2
260.36
266.93
273-50
279.81
285.91
291.90
Mean Load
mg. HgSOlt/g. C
6
8
10
12
ll)
16
18
20
25
30
35
1)0
1)5
50
55
60
65
70
75
80
85
90
95
100
110
120
130
ll)0
350
160
170
180
190
200
220
2l)0
260
280
300







Rate
HIR. H2S01t/g. C/min.
36.21)63
13.9327
11. 63 93
9.1(637
6.5720
3.2597
1.8822
1.5563
1.1672
1.0726
1.0726
1.1251
1.1356
1.1356
1.11)62
1.1567
.1 . 1 567
1.1567
1.1567
1.1567
1.1567
1.1567
. l.ii)62
1.11)62
1.1251
1.1 oia
1.0936
3.0726
1.0515
1.0305
1.0095
0_.9881)
0.9569
0.9253
0.8623
0.7886
0.7150
0.6309
0.51)68







                             448
-------
                          GRAV1MKTK1C FLOW
Run:         185-G
Dry Weight:   97.2U mg.
Deflection:   -5-9^ me-
Carbon:      RXT-6-3C
S02:
NO:
02:.
"20:
2000 ppm
150 ppm

6.07,
t:
Ft:
% IIpl.'Ol.:
Correction :
Date :
200°F
1500 en /win.
77-72
0.5076
August 20, 1971
Time
minute's
1
V
3
)i
c;
(>
7
8
9
10
12
Hi
16
18
20
25
OA
35
1(0
'(5
50
60
70
80
90
100
1.10
120
a 30
]1|0
350
160
170
100
190
POO
210
220
230
2'iO
250
260
2?0
?80
290
300
Load
mf,. }If>t:oj,/p:. C
5.55
8.6)-i
11 .00
1.3.27
J 5 . 3?
17. OY
18.9;'
20.57
22.21
23.76
26.1i3
29.21
31.78
3l*. 25
36.71
1)2.37
':7 . 72
52.55
57.28
61.81
66.23
7^.56
82.68
90.60
98.72
106. 6li
1 Hi. 66
12?. it 8
130.19
:i 37 • 70
I'i5.?.l
152. 'it
159-30
166. :i 9
173.08
179.86
186.65
193. '»li
199-9?
206 . 50
212.67
218.63
22'i.6o
230. !) 6
236.3''
21(1.88
Moiui Load
mg. Up;:/)],/,";. C
2
1|
6
8
'1 0
1?
Ill"
16
1H
20
25
30
35
)|0
'*5
50
rr
s s
60
65
70
75
80
85
90
95
100
110
120
130
ihO
150
360
170
l8o
190
200
220
2*40



•




Rate
rn.'-. Hp:/i)|/r:. 0/min.
5.01(12
it. 7306
3.77>42
3.":',37
2.1..V)P
2. fill)
2. 00 '".3
1.851-1
1.7277
] .621(8
1.1(500
1.3318
1.2230
1.1261
1.01490
0.9821
0.9255 ~"
0.8896
0.8536
0.8381
0.8227
0.812)4
0.8073
0 . 8021
0.7970
0.7970
0.7919
0.776*1
0.7610
0.7*156
0.7302
0.71)17
0.69)1?
0.6736
0.6582 •
0.61(27
0.5965
0.5502








                              449
-------
GRAVIMETRIC FLOW EXPERIMENTS
Run:         1B6-G
Dry Weipht:   101-70 mg.
Deflection:   -6.35 mg.
Carbon:      RXT-7-3C
     NO:
     H20:
2000 ppm
150 ppm
3.5%
6.0%
t:
Ft:
             200°F
             1500 cc/min.
             75-56
Correction:  O.li93li
Date:        August 23, 1971
Time
minutes
]
2
3
lj
5
6
7
8
9
10
12
• 111
.16
.18
20
25
'.•r>
35
1*0
1*5
50
60
70
80
90
HOG
110
120
330
.1.1)0
150
l6o
170
180
390
200
210
220
230
?1|0
2^0
260
270
280
290
300
Load
mg. H2SOl|/K. C
6.78
8.95
10.ll2
11.50
12.29
12.90
13.67
11*. 36
15 . Ok
15-73
16 .21
18.19
19.'i7
20.55
21.73
2l*.39
27.l'i
29.60
31.96
3l*. 32
36.68
1*0.90
1*5-23
1*9.16
52.90
56.M
60.28
61*. 01
67.1*5
71.1*8
75.22
79.35
83.1*8
87.1)1
91 .05
9k . 59
98.03
101.57
105.53
1 09.W)
113 .27
lif.ll
120 .9'i
121* . 78
128.1)2
131.86
Mean Load
ing. E2SOk/E- C
It
6
8
10
12
1>*
16
18
20
25
30
35
1*0
1(5
50
55
f$n
65
70
75
80
8=5
90
95
100
110
120
130













.




Bate
rag. HgSOli/fl. C/nrin.
5.5261
3.6185
2.26.16
1 . 37^6
0.8505
0.7030
0.6391
0.591*9
0.5605
0.5015
0.1(720
0.1)523
O.Ul25
0.1*277
0.1)228
0 . 1*179
O . 1(1 7Q
0.1)179
0.1*179
0.1*179
0.1)130
O.liOSl
0.1*031
0.3982
0.3933
0.3736
0 . 3589
0.3392


















   450
-------
                          GRAVIMETRIC FLOW  CALCULATIONS
Run:         187-G
Dry Weight:  91.92 ing.
Deflection:  -5-98 mg.
Carbon:      RXT-7-5C
S02:
NO:
02:
HgO:
2000 ppm
150 pj)m
3.5#
6.0?
t:           200°F
Ft:          1500 cc/min.
% H2S01(:     75.83
Correction:  0.1)952
Date:        August 2l), 1971
Time
minutes
1
2
3
1*
5
6
7
8
9
10
12
Ik
16
18
20
25
3n
35
1)0
1*5
50
60
70
80
90
100
110
120
130
ll)0
150
160
170
180
190
200
210
220
230
2)|0
250
260
270
280
290
300
Load
mp. UjjEOij/f-. C
7.29
1.0.K'
ia.97
13.27
in . 1*7
15. >*5
J6.l)3
17-30
18.06
18.71
19-9-1
21.00
22.19
23.39
21*. 1*8
27.09
90. ^0
31.98
33.9'+
36.01
37-86
1)1 .78
!)5.1»7
J)9 - ] 7
52.65
55- 92
59-10
62.66
65.93
68.97
7-1.91
75.17
78.1)1)
81.59
81*. 75
87-79
91.06
9't.-10
97.69
101.07
I0l).33
107.27
109.99
112.92
].15.5lt
117.93
Mean Load
mg. H2BOi,/g. C
1*
6
8
10
12
Hi
.1.6
18
20
25
30
35
1*0
1*5
50
55
60
65
70
75
80
85
90
95
100
110
120














,




Rate
mg. HpSOjj/g. C/trdn.
6.1)730
lt.7868
3.3616
2.T'08)|
1. Ii687
1.1151
0.8975
0.7398
0.636li
0.1*896"
0.1*569
0.')297
0.1*080
0.3916
0.3808
0.3753
0.3699
0.3590
0.3536
0 . 3l*8l
0 . 3372
0.3261)
0.3209
0.301)6
0.29^7
0.2665
0.2393



















                               451
-------
                          GRAVIMETRIC FLOW EXPERIMENTS
Bun:          188-G             S02:
Dry Weight:   100.66 mg.         NO:
Deflection:   -5-96 mg.          02:
Carton:      RXT-6-5C          HoO:
2000 ppra
150 ppm
3.555
6.0%
t:           200°F
Ff.          1500 cc/min.
% H2SOi,:'     76.97
Correction:  0.5027
Date:        August 25, 1971
Time-
minutes
1
'•i
t
3
!j
S
.. . £ . .
7
8
9
.10
12
111
16
18
20
25
on
35
1.0
U 5
50
60
70
80
90
100
:I.LO
120
130
I'lO
150
160
.170
180
J90
200
210
220
230
2lib "
2^0
260
270
2CO
290
300
Load
mg. Il2S01)/R. C
7.15
.10.53
13.31
15-50
37.6(1
19. 5Y
21 . 36
23.15
2>i.7)4
26 . 33
29 . 31
32.39 •
3'i.«7
37-55
liO.Oli
JJ5.90
n:n o£
J.IL. . ..^-
56.'i3
61.10
65.67
70 .Oil
78.1)8
86.83
9'i.87
102.52
109-97
117.23
12l).li8
131.53
138.1)9
I'i5.3l)
1 52 . 39
159.15
365.71
172 . 36
170. ft;1
iSli.ftB
390.611
136.70
202.56
20C.52
?l'i.39
220 . 1 S
225.91
23-1 .27
vtiM
Mean Load
m;-;. HoSOIj/g. C
If
6"
B 	 ~
10
If?
Ill
. 16
18
20
25
30
35
1)0
'15
50
55
f,r\
65
70
75
80
85
90
95
100
110
120
130
lliO
150
160
170
180
190
200
220
?1|0









Rate
mg. HgSOli/g. C/iriiii .
6.3332
li.6U93
3.6956
3.0995
2.6376
2.37^3
2.1111
1.9'i22
.1.8180
1.5895
I.)i355
1.3:i63
1.2170
1.1276
1.01)81
0.993li
0 . 9li3ft
0.9090
O.G7l)2
0.81»9l*
0.8295
0.8lU6
0.79W '
0.7799
0.7699
0.7^51
0.7252
0.7053
0.690i|
0.6706
0.6557
0.6)i57
0.6259
0.61.10
0.591.1
0.5563
0.5166









                                452
-------
                    APPENDIX A-16-3

   SULFUR GENERATION FROM 1 INCH DIAMETER FIXED BED
FOR (NH4)2S EXTRACTED AND H£S GENERATION CARBON SAMPLES
                           453
-------
                                                RATF OF  SULFUR GENERATION
                                                      BtNCH SCALE
 RXT-6-IB

 SPACE VELOCITY =     0.100125E  04  /HR
 INFRT GAS FLOW RATE  =       623.00 SCC/MIN
 i^EIGHT OF CARBON,  UNLOADED  *       32.000 GHS
                                                          LOADED
 INLET PERCENT H2S  ~       38.000
 INLET MOLAR H2S CONCENTRATION  -
 INLET SULFURIC ACID  LOADING  =
                                           0. 612903 MOLES H2S/MO_Lt
                                         0. 1137600 CMS H2S04/GM CARBON,
                                                       l.68
_*P_-JLP.GMS


 GAS
        FINAL OUTLET PERCENT SULFUR LOADING ON CARBON =	  	
4S      FINAL OUTLET SULFUR LOADING ON CARBON =    "  0.248~GMS S/GM CARBON
Ui      INITIAL TEMPERATURE =      270.00 F
-!>•      MAXIMUM TEMPERATURE =	315.00 F	
      "FINAL TEMPERATURE =      310.00 'f
                                                                                            8  31  71
PERCENT S02
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
PERCENT CO2
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
MOLAR CONC H2S
0.0
0.214505E-01
0.219512E 00
0.199041E 00
0.319261E 00
0.562500E 00
0.612903E 00
0.612903E 00
H2S04 LOADING
GMS ACIO/GM C
0.187600E 00
0. 102135E 00
0. 322466E-01
-0.250390E-01
-0.752A60E-01
-0.996606E-01
-0.103237E 00
-0*!03237E 00
RATE ACID DECOMP.
GM ACIO/GM C-KIN.
0.0
-0.167B86E-01
-0.111666E-01
-0.1174776-01
-0.833515E-02
-0.143072E-02
0.0
0.0
 TIME     PERCENT H2S
   0.0    0.0
   5.0    0.2100006 Oi
	10.0	0.180000E 02
  15.0    0.166000E 02
  20.0    0.242000E 02
 _25.0    0.360000E 02
  30.0 " 0.380000E 02
  35.0    0.380000E 02

 ACID LOADING -    0.1876bOE»01 AT0.111771E 02 MINUTES
 RATE OF  ACID DECOMPOSITION »   -0.113034E-01 AT    0.111771E 02. MINUTES
 AVERAGE  RATE OF ACID DECOMPOSITION UP TO 90_PERC_ENT ACID UTILIZATION =
                                                                                 -O.I5696CE-01
-------
Ul
Ul
                                                       RATK OF  SULFUK  GENEKAHUN
                                                              BENCH  SCALE
                                                                                       ri  31  71
       RXT-6-2B
       SPACE VELOCITY  =     0.500870E 03 /HR
       INERT GAS  FLOW  RATE  »      291.00 SCC/NLN
      _ME|GHT._QF. CARBON,  UNL QA.D JE D_2	29.900 CMS
                                                    LUADEO
33.61 GMS
       INLET PERCENT  H2S ^      32.000
       LNLE_T_MOLAR_ H2S CONCENTRATION =
       INLET SULFURIC *CID LOADING »
                                     Q.47058B HOLES H2S/MOLE INERT GAS
                                   0.139600 GMS H2SQ4/GM CARBON,
 FJNAL Oj^f).EX.I^RGEN.T'SULFUR  LQA01NG ON CARBON
 FINAL OUHET, SULFUR  LOADING  ON  CARBON -
 INITIAL TiHP€RATURE  *      280.00 F
JLAXIMUM TEMPERATURE.;	300.00 F	
 FINAL TEHPERATURE =       298.00 F
                                                              15.420
                                                      0.184  GMS  S/GM  CARBON
       TIME
          PERCENT H2S
PERCENT S02 PERCENT C02
0.0 .
0.0
0.0
0.0
0*0
O.O
0.0
0.0
0*0
0.0
0.0
0.0
MOLAR CONC H2S
0.0
0.140251E
0.216545E
0:2903236
0.470588E
0.470588E
00
00
00
00
00
H2S04 LOADING RATE ACID DECOMP.
GMS ACID/GM C GM ACID/GM C-MIN.
0.139600E 00 .
0.827747E-01
, 0.4131326-01
0.104992E-01
-0.229061E-02
-0.229061E-02
0.0
-0.468745E-02
-0.360485E-02
-0.255795E-02
0.0
0.0
                 0.0
                 0.123000E 02
               __0. 178000E__02
                 0.225000E 02
                 0.3200OOE 02
               _._.0.320000E 02

        ACID  LOADING =    0.139600E-01 AT    0.288769E 02 MINUTES      ^    ?
        RATE  OF ACID DECQMPQSLI JON j?	-0_.2J>mM-0_2_ AJL..	a»_28,8769E _Ql_H.LNUTeS
        AVERAGE RATE OF ACID DECOMPOSITION UP TO 90 PERCENT  ACID  UTILISATION
                                                                           -0.369408E-02
-------
Ul
                                                      RATE  OF  SULFUR GENERATION
                                                            BENCH  SCALE
                                                                                    8 31 71
      RXT-6-3B

      SPACE  VELOCITY  =     0.^996025  03  /HR
      INERT  GAS  FLOW  RATE  =   =    293.00 SCC/MIN
      WEIGHT  OP  CAHBONt  UNLOADED =       30.120  CMS
                                                   LOADED
35.95 CMS
       INLET  PERCENT  H2S =      32.500
       INLET  MOLAR  H2S CONCENTRATION^
       INLET  SULFUR 1C AClD LOADING =
                                    0.481481 MOLES H2S/MOUE INERT £&S
                                  0.167100 GMS H2S04/GM CARBON*
 FINAL Ot/TLET PERCENT SULFUR LOADING ON CARBON
 FINAL OUTLET SULFUR LOADING ON CARBON -
 INITIAL TEMPERATURE =      270.00 F
 MAXIMUM 'TEMPERATURE^*	HP_.00_F	
'FINAL TEMPERATURE'-      298.od" r
                                                            17.910
                                                           GMS  S/GM  CARBON
      TIME
          PERCENT H2S
0.0
10.0
20.0
30.0
40.0
50.0
60.0
0.0
0.0
0.250000E 01
0.263000E 02
0.2750006 02
0.310000E 02
0.325000E 02
PERCENT S02 PERCENT C02 KOLAR
0.
0.
0.
0.
O.
0.
0
0
0
0
0
0
0.0
7100E-01 AT 0,,
0
0
0
0
0
0
0
oO
.0
.0
.0
.0
.0
.0
2 MINUJE.S_ 	
0
0
0
0
0
0
0
CONC H2S
.0
.0
.256410E-01
.356852E
.379310E
.449275E
.481481E
00
00
00
00
H2S04 LOADING RATE ACID DECOMP.
GMS ACID/GM C GM AC1D/GM C-MIN.
0
0
0
-0
-0
-0
-C
. 167100E 00
.9881UE-01
.323407E-01
.882351E-02
.249071E-01
— •;•- - -. - - ^ ,^_L-^ 	 — r ------ :
0.0
-0.682888E-02
-0.6465216-02
-0.
-0.
-0.
0.
176763E-02
144910E-02
456781E-03
0
      ACID LOADING =    0      		
      RATE OF ACID DECOMPOSITION  =    -0.468147E-02  AT     0.237971E  02  MINUTES
      AVERAGE RATE OF ACID  DECOMPOSITION  UP  TO 90 PERCENT ACID UTILIZATION  =   -0.633341E-02
-------
                                                 RATE Of SULFUR GENERATION
                                                       BtNCH SCALE
 RXT-6-4B
  SPACE  VELOCITY =    0.500339E 03 /HR
  INERT  GAS  FLOW RATE =      287.00 SCC/MIN
 Jrf.EIGHT.pF  CARBON,  UNLOADED_•	29.500 CMS
                                                        LOADED
36.69 QMS
  INIET  PERCENT H2S =      30.000
  INLET  MOLAR H2S CONCENTRATION =
  INLET  SUtFURIC AC 10 LOADING =
                                         0.428571 MOLES_ H2S/MOLE_LNERJ_GAS_
                                       0.185300 GMS H2S04/GM CARBON,
_F INAL_OUTLET PERCENT,SULFUR LOADING ON CARBON =
Ui    FINAL OUTLET SULFUR LOADING ON CARBON
^J    INITIAL TEMPERATURE »      305.00 f
    _HAXIWUM TEMPERATURE * 	   311.00__f_ ___
      FINAL tEMPERATURE »      297.00 F
                                                           1V.48Q
                                                                                           a  31  71
                                                0.2<»2 CMS S/GH CARBON
TIME PERCENT H2S
-1 M ' '
0.0
15.0
30.0
45.0
60.0
0.0 , , .
0.8500QOE 01
0.223000E 02
0.262000E 02
0.300000E 02
PERCENT S02
0.0
0.0
0.0
0.0
0.0
PERCENT C02
0.0
OeO
0.0
0.0
0.0
MOLAR CONC H2S
0.0
0.928962E-01
0.287001E 00
0.355013E 00
0.428571E 00
H2S04 LOADING RATE ACID DECOMP.
GMS ACID/GM C CM ACID/GM C-MIN.
0.185300E 00 i
0. 103996E 00
0.532245E-01
0.303382E-01
0.225I27E-01
0.0
-0.476142E-02
-0.200812E-02
-0.104339E-02
0.0
-------
                                                       RATF DP SULFUR f.FNFRATION
                                                             BENCH SCALE
                                                                                     8  31  71
-P-
Ul
oo
        RXT-6-5B

        SPACE  VELOCITY =    0.500410E 03 /HR
        INERT  GAS .FLOW RATE *      285.00 SCC/MIN
        NEIGHf'OF'CARBON, UNLOADED =      29.280 QMS
                                                   LOADED,.?.	35._80 GM_S_
        INLET PERCENT H2S =      34.200
        INLET MOLAR H2S CONCENTRATION -
        INLET SULFUR 1C ACID LCiADlNG~~=
                                 	OOE-Ol AT
S02 PERCENT CO2
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.237^58E 02 MINUTES
MOLAR CONC H2S
0.0
0.204082E-01
0.695187E-01
0.43B849E 00
C.497006E 00
0.519757E 00
0.519757E 00
H2S04 LOADING
CMS ACID/GH C
0.186000E 00
0.775295E-01
-0.235415E-01
-0.800750E-01
-0.837527E-01
-0.8^5599E-Oi
-0.8^5599E-01
RATE ACID OECOMP.
GW ACID/GM C-MIN.
0.0
-0.708655E-02
-0.63896CE-02
-0. 114821E-02
-0.322871E-03
0.0
0.0
       ACID LOADING  =     0.1      	
       RATE OF ACID  DECOMPOSITION =   -0.668019E-02 AT    0.237458E 02 MINUTES
       AVERAGE RATE  OF  ACID DECOMPOSITION UP TO 90 PERCENT ACID UTILIZATION =   -0.693688E-02
-------
                                                RATE  OF SULFUR GENERATION
                                                      BENCH SCALE
                                                   8 3i 71
RXT-7-IB
SPACE VELOCITY  =     0.494292E  03  /HR
INERT GAS  FLOW  RATE  »       312.00 SCC/MiN
HEIGHT Of  CARBONt  UNLOADED ......   32.410 GMS
                 LOADED
38.60 GMS
INLET PERCENT  H2S  *       26.800
1NLET MOLAR  H2S  CONCENTRATiON =
INLET SUIFURIC ACID~ LOADING "»
  0.366120 MOLES H2J7 MOIE_ INERT GAS
0.167400 GMS H2S04/GM CARBON*
LlJS!AL.OUTLET  PERCENT SULFUR LOADING ON CARBON
FINAL OUTLET  SULFUR LOADING ON CARBON =
INITIAL  TEMPERATURE =      273.00 F
MA_XIMUM  TEMPERATURE _•	303.00 F	
FINAL TEMPERATURE  *      302.00 F      ;
                    17,970
             0.214 GMS S/GM CARBON
TIME      PERCENT H2S
  0.0     0.0
  30.0     0.6500006 01
_60_. Q	Q . 252 OQQ.E_fl2
  90.0     0.256000E 02
 105.0     0.268000E 02
 ACID  LOADING -    0
 RATE  OF  ACID DECOMPOSITION
PERCENT S02
o.o . : •:. .. .•;••••,..•.
L 0.0 :-' .- •:,:-s''-:. :
> 0.0
> 0.0
I 0.0
PERCENT C02 MOLAR CONC H2S
0.0 0*0
0.0 0.695187E-01
0.0 . 0.33689SE 00
0.0 0»?44086E 00
0.0 0.366120E 00
H2S04 LOADING
GMS ACID/GM C
0.167400E 00
0.278739E-01
-0.407232E-01
-0.5151-V3E-01
-0.538338E-01
RATE ACID OECOMP.
GM ACIO/GM C-MIN.
0.0
-0.416300E-02
-0.410U5E-03
-0.30926*E-03
0.0
L67400E-01 AT 0.3A8693E 02 MINUTES
5ITION = -0.355388E-02 AT 0.3^8693E 02 MINUTES
DECOMPOSITION UP TO 90 PERCENT ACID UTILIZATION = -O.A07793E-02
-------
-p-
ON
O
                                                        RATE  OF  SULFUR  GENERATION
                                                              BENCH SCALE
                                                                                     B 31  71
        RXT-7-2B

        ~SPACE  VELOCITY -     0.615268E 03 /KR ~
        INERT  GAS  FLOW RATE  =      315.00 SCC/MIN
        WEIGHT  OF  CARBON,  UNLOADED =      26.330 CMS
                                                   LOADED
32.41 CMS
         INLET  PERCENT  H2S  =      26.300
         INLET  MOLAR  H2S  CONCENTRATION =
         INLET  SULFURIC ACID LOADING «
                                    0.356852 MOLES H2S/MpLE__INERJ_GAS
                                  6.168900 GMS H2S04/GM CARBON,
_FINAL OUTLET PERCENT SULFUR LOADING ON CAK80N
 FINAL OUTLET SULFUR LOADING"ON CARBON =
 INITIAL TEMPERATURE *      270.00 F
 MAXIMUM TEMPERATURE =      315.00 F	
 FINAL TEMPERATURE *      ~300JOO F
                                                              18.070
                                                       0.222  GMS  S/GM  CARBON
        TIME
PERCENT H2S
0.0
0.0
0.0
0.400000E 01
0.230000E 02
0.245000E 02
0.260000E 02
0.255000E 02
0.260000E 02
PERCENT S02
0.0
0.0
0.320000E
0.300000E
0.0
0.0
0.0
0.0
0.0
0.263000E 02 0.0
ING = 0.168900E-01 AT 0
01
00

PERCENT C02
0.0
0.0
0.0
0.0
0.0
0.0
0.0
o.o - •,
0.0 :
0.0
.295749E 02 MINUTES
MOLAR CONC H2S
0.0
0.0
0.0
0.417973E-01
0.298701E 00
0.324503E 00
0.351351E 00
0.342282E 00
0.351351E 00
0.356852E 00
H2S04 LOADING
GMS ACID/GM C
0.168900E 00
0.137777E 00
0.106655E 00
0.480550E-01
0.155062E-01
0.115598E-01
0.990935E-02
0.903412E-02
0.728368E-02
0.704382E-02
RATE ACID OECOMP.
GM ACID/GM C-MIN.
O.O
-0.622
-------
                                                  RATE  OF  SUI FIIK GENERATION
                                                        BENCH SCALE
                                                    8  31  71
  RXT-7-5B

"SPACE VELOCITY =    0.500329E 03 /HR "~     ~'~
  INERT GAS FLOW RATE =      237.00  SCC/MIN
__MilGH.L OF...CARBON»_ UNLOADED =       2*.320 CMS
                ;J  LOADED
30.90 CMS
  INLET PERCENT HZS =      28.000
  INLET MOLAR H2S CONCENTRATION =_
  INLET SULFURIC ACID LOADING -
	0.388889 MOLES H2S/MOLE INERT GAS
 0.18*000 CHS H2S04/GM CARBON*
_JF INAI._.OUTLET _PEJU:ENT SULJUR LOADING  ON  CARBON
  FINAL OUTLET SULFUR LOADING ON CARBON
  INITIAL TEMPERATURE =      270.00  F
  MAXIMUM TEMPERATURE =	  310.00 j
  FINAL TEMPERATURE =      300.00  F
                     19*350
              0.246 CMS S/GM CARBON
TIME
0.0
15.0
_30.0.
60.0
75.0
90.0
105.0
120.0
PERCENT H2S
0.0
0.1000QOE 01
0.800000E 00
0. 175000E 02
0.175000E 02
0.183000E 02
0.185000E 02
0.157000E 02
PERCENT S02
0.0
0.0
0.0 	
0.0
0.0
0.0
0.0
0.0
0.0 	
PERCENT C02
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0,0
MOLAR CONC H2S
0.0
O.IOIOIOE-OI
0»806452E-02
0.212121E 00
0.212121E 00
0.223990E 00
0.226994E 00
0.1862AOE 00
0««28571£ 00
H2S04 LOADING
CMS ACID/GM C
: O.ie^OOOE 00
: 0.102195E 00
0.212486E-01
-0.975879E-01
-0.135261E 00
-0.171670E 00
-0.206<>9<»E 00
-0.2*5341E 00 :i
-0.256918E 00 ;
RATE ACID DECOMP.
GM ACID/GM C-M1N.
0.0
-0.538193E-02
-0.5*1086E-02
-0.251157E-02
-0.251157E-02
-0.234293E-02
-0.230025E-02
: -0.287930E-02
0.563822E-03
  ACID LOADING =    0.184000E-01  AT     0.307191E  02 MINUTES
  RATE_OF_ JVC. ID _DECOMPOS IT I ON. .=	-0.53^137E-02 AT	0. 30 7191E 02 MINUTES
  AVERAGE RATE OF ACID  DECOMPOS'lTION UP TO 90 PERCENT ACIOUTILIZATION =   -0.539510E-02
-------
                           APPENDIX A-16-4

           (NH4)2S EXTRACTION EXPERIMENTAL  RESULTS
RIM:       RXT-T-1C

CARBON USED:  RXT-T-1B
SOLVENT USED:  15?
                  Solution
Waiih Number
1





2



3



b



5



6



' T



6



9



10


i


2


3"


Time,
minutes
0
2
5
8
11
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
>
10
15
0
5
10
15
0
5
10
15
0 •
5
10
15
0
5 -•
10 -
15
0
5
10
0
5
10
0
5
10
Temperature ,
°F
100
102
105
105
105

120
111
110
103
105
102
105
108
110
107
107
105
102
101
102
100
115
ICO
100
103
120
105
105
105
105
107
100
100
110
100
105
100
115
108
105
105
95
100
110
110
105
110
305
105
105
Circulation Rate, ml./mln.
(NHIiJaS
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
91-
->^
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35









H20









































60
60
60
60
60
60
60
60
60
ml. (HE It) 28
Added
~50





-50



~50



—50



-50



-50



^50



,-50



~50



-50











ml. (NHltJj: +
Sulfur Dralr.ed





19-5



36



37



36



3li.5



32



32



32.5



33


30


l46«


37*


39*
      ••1. HjO Dr«in«4
     ••After mtcr vmehlng, Bteamed for 2 hours at 1,000 cc/min.
                                  462
-------
CA'UOIl I '.Ml: R»
Vftcli Kvjalwr
2
3
*
5
6
7
0
9
10
11
12
13
111
15
1
2
3"
T-7-2»
Time,
0
5
10
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
: J
10
15
0
5
10
15
0
5
10
3;
0
5
10
15
0
5
10
15
0
5
10
15
0
10
15
0
5
10
15
0
5
10
15
0
J
10
15
0
5
10
15
0
5
10
15
POLUTIOII arm: i^J (i.',:i,).,:! :;cjutlon
'!''•.', iviiture ,
102
106
105
111
110
100
106
115
109
109
111 .
103
110
10k
109
115
105
105
J09
1X0
)00
110
103
117
100
109
105
120
100
102
123
100
110
98
112
110
105
111
110
110
69
106
110
100
110
102
111
111
112
103
110
110
90
100
112
90
110
110
310
327
105
110
110
120
111
111
111
i'"r ]~'^~ r '^j
35 '
35
35
Vi
35
.35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35


















60
60
60
60
60
60
60
60
60
60
60
60
p.!, (KIU,);;:
—50
-50
-50
-50
-50
-50
-•50
-50
~50
-50
-50
-50
-50
-50
~50



nl . (!i!l|,Nf! *
t'ul f'lf rr:»!no1
25
«2
25


llO
29.6
U6.2
53
51.5
1.2
1.8
1.8
lib
82.5
36.5'
!2.5«
66.3"
"After vater vn
                   it«nm«d for 2 hour* n,t 1,000 cc/mln.
                      463
-------
     RXT-7-3C
CWKSI U1ED: BXT-7-3H SOLVENT USED! 151 (HIH^S Solution
V&Blt Itiunlitr
1
I
3
H
5
6
7
6
9
10
11
12
13
it
15
1
P
f"
Tlr,e,
rtltvit'e
0
5
10
15
0
5
10
15
0
5
ID
15
0
5
10
15
0
5
10
15
0
5
10
15
0
•>
10
15
0
5
10
15
0
•5
in
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
100
15
0
5
10
15
0
5
10
Ttfovcrriture,
•T
105
102
105
105
112
100
106
100
110
100
IOC
10?
102
100
101
101
101
95
101
101
105
100
101
101
101
101
101
101
100
98
101
100
100
101
100
102
101
101
101
100
101
100
101
100
98
100
101
102
105
101
101
100
101
95
102
10?
110
100
lOli
102
103
101
101
101
100
101
101
100
100
105
101
Clrculitlon fljtlt.-, ri)./«.ln.
fuiiii)?;'
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35



KiO















60
60
60
60
60
60
60
60
60
60
60

"''/JuM1*5


50
50
50
50
50
50
50
50
50
50
50
50
50
70"
50«
50-

Sulfur PrnlnM
16
1.5
51
U
1.8
U7
>*
50
VI
37
10
17

55
1,6
111."


  •U. IlpO A t>iuln-d
•"After water vuolilng, ntnuw-il for 2 houra fit 1,000 cc/mln»
                           464
-------
             RXT-T-liC
CARBON
                                BOIVHIT USEDi  15?
                                                         Solution
Vni.li llu«l«T
1
2
3
k
>
6
7
8
9
10
I
11
12
13
111
15
1
2
3"»
Time.
ml mi I* it
0
5
10
15
•K .
•10
»....
: o -
i 5 .0
10 •
W '...
0
5
19
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
Q
5
10
i;
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
J
10
15
Ttimjif ruture ,
Op
100
95
J101
101
105
101
102
102
110
102
103
103
100
103
103
103
110
10?
102
102
lOll
10?
105
105
95
100
100
100
106
100
101
IIS
91
95
1CI>
100
91
99
101
100
108
100
ICE
103
99
105
101
98
90
99
100
100
91
100
100
101
91
100
K'l
103
95
96
100
103
90
106
112
1H
190
126
J25
118
Circulation Fta
.. («!II,)?S
35
35
35
35
35
35
35
35
35
3?
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35



te, nl./nln.
H?n









•





60
60
60
60
60
CO
60
Co
60
£0
ft) '
CO
Bl. (BnO?s
Aisled
100
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50"
50"
50"'
«ll. (KI!,,S .!•: »
Sulfur I'rH, -1
52
n
i
1.9
1.7
1.9
51
51
1.8 •
U
53.5
S3
55
51
1.8
eo
Ii5«
59"
tg»
            »1. ll?0 Added
            •1. II.-O llrtlnod
            AftKr water wnahlnKi •tpwned  for t houra fti  1(000 cc/lnil).
                                    465
-------
KSl!         MT-1-5C

CARBON UGO>!  RICT-7-5B
SOLVENT VSED:  15* (HH|,)zB Solution
V»h Kumber
1
2
3
14
b
6
7
8
9
10
31
ia
13
lit
15
1
2

Tln.e,
alni!t>>n
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
0
5
10
15
0
5"
10
i;
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
.15
0
5
10
15
0
5
10
15
0
10
15
0
5
10
15
0
5
10
15
Teir.s*ruture,
'f
100
es
90
103
100
100
109
10?
ICO
100
100
100
100
100
100
100
100
100
100
ICO
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
ICO
100
100
100
ICO
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Cliviil.alon lii
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
as
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35



li-io "















65
«5
65
65
65
65
65
65
65
65
«5
6;
ml. (»i!i.):?s
AdiV>!
100
50
50
50
50
JO
50
50
50
50
50
50
50
50
50
100*
50"
50*
ml. (hMI.)?:'>
Rul fur IH-Rlnpd
1.9
1.6
111
50
59
50
19
60
1.8

1.2
50
1.3
*
50
56"
50"
1.6"
          •nl. ll.iO Added
         •*nl. H.,0 Druliioil
        •«»ft»r untcr vinli
                               utenmed for 2 Hour» »t 1,000 tc/«ln.
                                      466
-------
KUHt          RXT-7-6C

C/UIBOK USKD:  SXT-T-6B
                               SOtVm USEDl  15*
Wash Humtwr

1
2
3
14
5
c
T
8
9
10
11
1?
13
ll>
15
1
i
3...
Time,
mlmiteg
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
15
0
5
JO
15
0
5
10
.ly
0
5
10
15
0
5
10
15
0
5
10
15
0
5
10
35
0
5
10
35
0
5
10
15
0
5
10
15
0
5
10
15
0
»
10
15
T> mpc r ttture ,
°F
100
120
100
100
100
100
100
100
95
100
100
100
100
100
100
105
105
105
105
105
110
105
100
100
95
100
100
100
105
100
100
100
95
100
100
110
95
100
100
100
95
100
100
100
105
100
100
100
105
100
100
100
95
100
100
100
105
100
100
ICO
100
10*,
105
105
105
105
111
110
110
110
..CJrcul.tlnn Rut
dim)-:!
35
35
55
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35



e. »l.Mn.
M















60
Co
Co
60
to
£o
60
60
Co
CO
Co
60
nl. (NUl);S

91
50
50
50
50
50
50
50
50
50
50
50
50
50
50
100"
50"
*'
ml. (HI! ) S «

1>5

19
1.6
16
5k
53
fc2
lift

57
H
50
51
k3
72
5P"
75"
  •ml. >l?0 AcMrd
 "ml. lljO Umliied
•"Aftrr vnur m>nlilnr,< lt««m"l fur ? houri
                                                    1,000 cc/Rln.
                                        467
-------
                  APPENDIX A-16-5

PORE VOLUME DISTRIBUTION RUNS FOR  (NH4)2S  EXTRACTED
   AND H2S GENERATION SAMPLES AFTER  SIXTH  CYCLE
                    SAMPLE:  EXV-1
               REL  P
VOLUME
0. 1428
0. 1789
0.2149
0.3251
0.4313
0.5395
0.6477
0.7559
O.C641
0.9722
0.3628
0.3606
0.3733
0.3851
0.3950
0.4031
0.4103
0.41 6.8
0.4242
0.4350
                S    667.4
                C      -22.544
                R  0.9985
           PORE RAUIU!
     VOL
CUMV
1000.
500.
400.
300.
200.
150.
10U.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
13.
16.
14.
12.
10.
0.0022
0.0009
0.0014
0.0024
0.0022-
0.0040
0.0012
0.0015
0.0019
0.0025
0.0034
0.0023
0.002H
0.0035
0.0047
O.OOfO
0.0115
0.0071
0.0096
0.0123
0.0149 '
0.0204
0.0022
0.0031
0.0045
0.0070
0.0092
0.0131
0.0144
0.0159
0.0178
0.0203
0.0237
0.0260
0.0238
0.0323
0.0369
0.0439
0.0554
0.0625
0.0721
0.0044
0.0994
0.1198
                        468
-------
           SAMPLE:  RXT-6-6C
         REL  P
VOLUME
0.1487
0.1863
6.2238
0.3365
0.4492
0.5619
0.6745
0.7872
0.8924
0.9900
S
C
R 0.
0.4417
0.4461
6.4532
0.4688
0.4794
6.4838
0.4922
0.4995-
0.5075
0.5156
794.2
-20.632
9986
PORE RADIUS
VOL
CUMV
1000.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
16.
14.
12.
500.
400.
300.
200.
150.
100.
90.
80.
70.
60.
50.
45.
40.
35.
30.
25.
20.
18.
	 16. 	
14.
12.
10.
„ 0.0006 ..
0.0004
0.0008
0.0017
0.0018
0.0037
0.00i2_
0.0015
0.0020
0.0026
0.0037
0.0024
0.0030
0.0039
0.0059
0.0081
0.0058
0.0043
0.0100
0.0153
0.0215
0.0301
0.0006
0.0010
0.0018
0.0034
0.0053
,- '0.0090
. ._.. 0.01 0.2...
:o.oii7
0..0137
0.0163
0.0199
0.0223
0.0253
0.0292
0.0350
0.0431
0.0489
0.0532
0.0632
0.0785
0.1000
0.1301
             469
-------
          SAMPLE:  RXT-7-6C
         REL P
VOLUME
0.1487
0.1863
0.2238
0.3365
0.4492
0.5619
0.6745
__0.7872
0.8999
0.9900
0.3417
0.3490
0.3530
0.3646
0.3742
0.3823
0.3895
0.3959
0.4031
0.4099
           S    617.8
           C     -20.604 _
           R  0.9983
PORE RADIUS
VOL
CUMV
1000.
500.
400.
_ .300. 	
200.
150.
IOQ*_
90.
80.
	 70. 	
60.
50.
	 45. 	
40.
35.
_ . 30.......
25.
20.
	 18. 	
16.
14.
12.
_ 500.
400.
300.
._200.
150.
100.
	 9.0,
80.
70.
60.
50.
45.
	 .40., 	
35.
30.
	 25.
20.
18.
	 16,
14.
12.
10.
0.0008
0.0004
0.0007
0.0015
0.0016
0.0031
,.Q,OQIO _
0.0013
0.0016
0.0022
0.0031
0.0021
. 	 0,0026..
0.0034
0.0047
0.0070
0.0112
0.0071
— 	 0.0093 _
0.0119
0.0147
0.0185
0.0008
0.0012
0.0020
0.0034
0.0050
0.0081
0,009}
0.0104
Oo0120
0.0142
0.0173
0.0194
__.0.,0220_
0.0254
0.0301
.___0..0371
0.0483
0.0554
, 	 0^0647:
0.0766
0.0914
0.1099
            470
-------
                       APPENDIX A-17
    POST-TREATMENT RESULTS OF AMMONIUM SULFIDE SOLVENT
                     EXTRACTED CARBON
1.   Experimental Conditions for Isothermal and          472
      Thermal Post-Treatments of (NH4)£S Extracted
      Carbon

2.   Experimental Results for Determination of the       475
      S02 Activity of Post-Treated (NH4)2S Extracted
      Carbon Samples Using Differential Rate
      Apparatus

3.   S02 Sorption Rates for Determination of the         486
      S02 Activity of Post-Treated (NH4)2S Extracted
      Carbon Samples Using Differential Rate
      Apparatus
                            471
-------
                               APPENDIX A-17-1

                EXPERIMENTAL CONDITIONS  FOR ISOTHERMAL AND
           THERMAL POST-TREATMENTS  OF  (NH4>28  EXTRACTED CARBON
RUN NO.:

TYPE CARBON:

DESCRIPTION OF RUN:
EXPERIMENTAL CONDITIONS:
RXT-T-6C-1

RXT-7-6C

Run at 1000°F for 2  hrs. with 30% H2

Weight of Carbon:    0.5 gms
Bed Temperature:   1000°F
Inlet H2 Concentration:   30%
Gas Flows:   N2 - 19A cc/min.;    H2 - 8.3 cc/min.
RUN NO.:                 RXT-7-6C-U

TYPE CARBON:              RXT-T-6C

DESCRIPTION OF RUN:       Run at 800°F for U hrs. with H2;  2 hrs . preheat time

EXPERIMENTAL CONDITIONS:  Weight of Carbon:   0.5 gms
                         Bed Temperature:   800°F
                         Inlet -H2 Concentration:   305?
                         Gas Flows:  N2 - 19-U cc/min.;    H2 - 8.3 cc/min.
RUN NO.:

TYPE CARBON:

DESCRIPTION OF RUN:

EXPERIMENTAL CONDITIONS:
RXT-T-6C-5
RXT-7-6C

Run at 1200°F for k  hrs. with H2;  2 hrs. preheat time
Weight of Carbon:    0.5 gms
Bed Temperature:   1200°F
Inlet H2 Concentration:  30%
Gas Flows:   N2 - 19.!+ cc/min.;    H2 - 8.3 cc/min.
                                      472
-------
RUN NO.:                   RXT-7-6C-6

TYPE CARBON:               RXT-7-6C

DESCRIPTION OF RUN:       Run at 1000°F for U hrs. with H2

EXPERIMENTAL CONDITIONS:  Weight of Carbon:  0.5 gms
                          Bed Temperature :   1000°F
                          Inlet H2 Concentration:   30$
                          Gas Flows:   N2 - 19.^ cc/min.;
                                                             H2 - 8.3 cc/min.
RUN NO.:

TYPE CARBON:

DESCRIPTION OF RUN:

EXPERIMENTAL CONDITIONS:
RXT-7-6C-7

RXT-7-6C

Run at 1000°F for U hrs. with N

Weight of Carbon:  0=5 gms
Bed Temperature:  1000°F
Inlet H2 Concentration:  0
Gas Flows:   N2 - 27-7 cc/min.;
                                                             2 hrs. preheat period
                                                             H  - 0
RUN NO.:
TYPE CARBON:

DESCRIPTION OF RUN:
EXPERIMENTAL CONDITIONS:
RXT-7-6C-8
RXT-7-6C
Run at 1000°F for
Weight of Carbon:
                                              hrs. with CO;  2 hrs. preheat period
                                             0.5 gms
                          Bed Temperature:  1000°F
                          Inlet CO Concentration:
                          Gas Flows:   N2 - 19-^ cc/min.;
                                                            CO - 8.3 cc/min.
                                       473
-------
RUN NO.:
TYPE CARBON:
WEIGHT OF CARBON:
DESCRIPTION OF RUN:
RXT-7-6C-9
RXT-T-6C
0.5 gms
(1)  Washed for 15 minutes with 50 ml. of a 2% NH^OH  solution
     at 77°F
(2)  Three distilled H20 washings of 50 ml for 15 minutes
     each at 77°F
(3)  Heat the sample in a 1,000 scc/min. purge of N2  for
     1 hour at UOO°F
RUN NO.:
TYPE CARBON:
WEIGHT OF CARBON:
DESCRIPTION OF RUN:
Virgin Washing with
Virgin, C-70-77
0.5 gms
Same as RXT-7-6C-9
               474
-------
                 APPENDIX A-17-2

EXPERIMENTAL RESULTS FOR DETERMINATION OF THE S02
ACTIVITY OF POST-TREATED (NH4>2S EXTRACTED CARBON
    SAMPLES USING DIFFERENTIAL RATE APPARATUS
                        475
-------
CAICULATIIINS fUK &KAVIHIIHIl flllM l«l'lH|MlNli
MUM NO. •
UMl •
UKV Hl.>
COKRtUION-
Tint
(MINI
1.00
^ 	 2.00
3.00
4.00
5.00
6.00
7.00
6.00
9.00
10.00
11.00
12.00
13.00
14.00
15.00
16.00
1 7. 00
18.00
19.00
20.0(1
21.00
22.00
. . 23.00
24.00
25.00
... . 26.00..
27.00
28.00
29.00
30.00
33.00
	 36.00
, 39.00
42.00
. 	 	 45.00
48.00
51.00
. . .5-4.. 00
57.00
60.00
63.00
66.00
69.00
72.00
' 75.00
78.00
. - ...Bl.OO.
84.00
87.00
.'.^. ..90.00 „
93.00
96.00
99.00
102.00
105.00
108.00
111.00
114.00
117.00
120.00
126.00
132.00
138.00
144.00
150.00
156.00
162.00
168.00
174.00
180.00
IH6.00
142.00
198.00
204.00
210.00
216.00
222.00
22K.OO
2J4.00
240. 00
246. DO
252 . f'U
25H.OO
264.00
270.00
276.00
tH/.PO
2rlil.n(i
244 .5200
0.5200
0.5200
0 5200
0.5200
0.5200
0.5200
0.5200
0.5200
. ......0..5200.
0.5200
0.5200
0.5200
0.5200
0.5200
g.5200
0.5200
0.5200
	 _. 0,5.200.
0.5200
0.5200
0.5290
0.5200
0.5200
0.5200
0.5200
0.5200
0.5200
0.5200
0.5200
0.5200
0.5200
0.5200
0.5206
0.5200
0.5200
0.5650
0.5650
0.5650
0.5650
0.5650
0.5650
0.5650
0.5650'
0.5650
0.5650.
0.5&50
0.5650
0.5650
0.5650
0.5650
.0.565J
0.5650
0.5650
0.5650
0.6050
0.6050
0.6050
O.fcO'-O
0.605D
P.W50
0.6'J^l)
0.6.150
0.6.1MI
O.M'M)
C.fcC'M
O.CPIO
11.KI50
0.<*>>SO
. 	 _ D.6050
O.hOSO
P.C..1SO
0. 6^50
O.M'SO
2000. PPM HUP •
150. PPK Fl 'I "
J.5 < M2iU4 *
6.0 I
CHART
INCHES
7.40
8.0A
8.16
B.27
8.36
8.49
8.60
8.70
8.80
B.91
	 9.0.2...
9.14
9.22
. . . . ... ..9-31 .
9.42
0.52
0.62
0.71
0.81
0.91
1.02
1.14
.25
.36
.47
*58
.69
.79
J.90
2.00
2.32
2.66
2.98
3. JO
j ,63
).9~6 '
4.28
4.60
4.91
5.23
5. 56
5.89
6.21
6.52
6.86
7.19
7.51
7.83
8.16
B.47
8.79
9.10
0.34
0.66
0.97
1.27
1.57
1.87
	 	 2,11 	
2.47
3.05
3.62
4.19
4.77
5.32..
5.88
6.41
. _ .._ 	 6.95 .
/.49
8.00
8.59
0.45
1.41
1.85
2.24
2.72
3.15
4.56
1.97
4.J8
4.77
5.16
5.54
5.42
6.24
6.66
7.0U
1. 11
1. 11}
8.04
2OU. DIG. r.
15CO. CC/MIN 	
75.14 S

PICKUP
IMG H2SO4I
1.61998
. 	 1.75998.
1.87997
1.9N947
2.09996
2.20998
2.3149U
2.4199B
2. 51997
2.62997
Z. 73997
2.B5999
2.93997
3.0299U 	
" 	 3.I399S
3.2.3997
i. 13998
3.42998
3.52998
J. 62997
3.7S9V7
3.80999
3.96999
4.07997
4.U997
	 r 	 4., 2999.1. 	
4.40197
4 ,,5099 8
. 4.61998 	
4.71999
5.03998
	 5,37997 	
5.69998
6.01997
6B3'*990
6. 67990 	
6.99998
7.31998
7.62997
7.94^40
8.27998
0. 60999
8.92998
9.23997
9.57997
9.90997
10.22998
10.54997
10.87997
11.1H997
11.50998
11.81998
12.05998
12.37997
12.68997
12.98997
13.28998
13.5B998
	 	 . J 3. 88998
14.18997
14.76997
. 	 _ 15.3)998
15.90997
16.48997
	 17.03998
17.59998
18.12997
	 _. . 16.66998
14.20908
19.71999
	 20.21494
20.66448
21.12497
2 1.56-148
22.00448
22.41497
22.8649ft
23.27998
21.6H44T
."•4.09498
24.40941
24.67497
25.2549S
2"1 . 6 J44H
20.00146

2I>. 71944
27.0H'I'IU
21.419'iH
2 7. 7*i *'IU
                      476
-------
tALUIlAIIIUll II.K u
                      Ull. rili
RUN NM. »
DA 11 «
DRY WT..
COKREC HUN-
TINE
l.CO
z.oo
3.00
4.00
5.(/0
6.00
7.00
8.00
9.00
10.00
11.00
12.00
13.00
	 	 .14.00 ..
15.00
16.00
17.00
18.00
19.00
.20.00
21.00
22.00
	 J3.00
24.00
2'*. 00
	 	 26.00.-
27.00
28.00
	 ... 27.00 .
30.00
33.00
_.. 	 J6.DO
39.00
42.00
	 45.00
48.00
91.00
.. -SA.OO .
57.00
60.00
63.00
66.00
69.00
72.00
75.00
78.00
SI. 00
84.00
87.00
90.00
93.00
96.00
99.00
102.00
105.00
108.00
111.00
114.00
117.00
120.00
126.00
132.00
138.00
144.00
150.00
156.00
162.00
168.00
174.00
1HO.OO
lUh 00
192.00
1 9ll. 00
204.00
210.00
216.00
222.00
22(1.00
234. PO
240.00
246.00
252.00
2SH.OO
2*4.00
270.00
2 H«. UO
2H2.00
2HH.OO
2V4.1'0
300.00
189 ',11,- .
8 31 U 1411 *
1H.KI, MG , 02 *
-6.22 HG 1120 »
HASS DIM
0.4'JOO
. 	 _ O.'t'JOO
0.4900
'J.1,'100
O.VIOO
0. VJOO
0.5.300
. 0.5300
0.5100
0.5300
_ 	 0.5100
0. 5JOO
0.5300
	 . .. . ...0..5300
D.4300
0.5300
	 0.5300
0.5300
0.5300
	 0,5300
0.5300
0.5300
	 	 0..5300..
0.5300
0.5300
_. 	 0. 5300..
0.5300
0.5300
	 . 3.5300
0.5300
0.5300
	 	 , 	 a, 5300.
0.5300
0.5300
	 	 0.5300.
0.5300
0.5300
0.5300
0.5300
O.'iJOO
0.5300
0.5300
0.5300
0.5300
0.5300
0.5300
0-5300
0.5750
0.5750
0.5750
0.5750
0.5750
0.5750
0.5750
0.5750
0.5750
0.5750
0.5750
0.5750
0.5750
0.5900
. 0.5400
0.5900
0. 5900
0.5900
0.5900
0.5900
0.5900
J.4900
0.5900
d . 5900
0 . 5900
0.5VOO
0.4900 .
0. V'OO
J.VIOO
c.vioo
0.5'JOO
C.VIOO
(.'.d^CO
0.6400
0.6400
O.b'.OO
0 . 1.4 0 0
0 .6400
.d.htri)
O.hiPO
0,6400
O.'i'itiJ
i'.6lPt)
2'IOU. I'M* l| HP • 200.
150. IM'H ||!| • 1500.
3.4 T II21IJ4 = 75.55
6.0 X
i it AH r
7.60
	 	 .._ 7.9} 	 : 	
8.18
8.311
H. 56
B.72
0.86
. 1.03 	
1.21
1.37
	 	 1.53
1.69
1.85
?,00
2.17
2.32
2.47
2.6f
2.77
_ 	 -. 	 -2..9.Q 	 .. 	
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3.16
... 	 	 _. 3,20 	 _ .
3.40
3.50
... 	 ._ .3,60 	 i
3.70
3.80
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3.99
4.34
... ._ 	 	 4.65 	 . 	
5.00
5.31
5,61
5.92
6.21
6n51
6.81
7.10
7.39
7.68
7.97
8.25
8.52
8.81
9..09
0.30
0.59
0.87
1.16
1.43
1.71
1.99
2.26
2.54
2.81
3.09
... 3.35 	 	
3.61
1.09
.1.63 	 	
2.17
2.69
3.20
3.71
4.22
4.73
5.21
5.64
6.17
6.66
7.16
.f.64 . ..
11.13
H.61
4.08
9.44
10.00
0.40
O.K3
1.26
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2.09
2.49
2.lt9
3.27
3.65
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(KG M2504)
0.51999
0.829 ft
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2.1299V

2.45000
2.60-199
2,76999
2.92000
3.09000
3.23999
	 3.3H998 	 _
3.52998
1.60999
	 3,81999
3,93')99
4.01999
. . .. ,«•.«. 20000
' 4. 3 1999
4.42000
	 A.51S.9S 	
4. (2000
4i71999
	 ...*.ei'J9» 	
4,90999
5.25999
. 	 5,59999. 	
5.92000
6.23000
6,52993
6.84000
7.12999
7,42997
7.7300C
n. 01999
8,31000
8,59999
8.8H998
5,17000
9,43999
9.73000
10., Q099?
10.21999
10.50999
'10.78999
11.07999
11.34999
11.62999
11.90994
12.17999
12.45999
12.73000
13,00999
13.26999
13.52998
14.00999
14.54999
15.09000
15.60999
16.12000
16,62999
17.13998
17.64999
18.12-J94
18.60999
1 9. 09000
19.57999
20.0f999
20,56000
21.04999
21.52998
21. 90998
22.4S999
22.92000
23.31999
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24.17999
24.59999
24.009*»9
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(Mil • 1 2 It .
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CURRCCTIUN* -6.43 Ht
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	 (MINI... ...
1.00
2.00
3.00
4.00
5.00
6.00
7.00
8.00
9.00
10.00
11-00 . .
12.00
11.00
.. .. 14.00 ._ . .
15.00
16.00
17.00
18.00
19.00
20.00
21.00
22.00
. 	 .23.00 	 	
24.00
25.00
26. OQ
27.00
26.00
29.00
30.00
33.00
	 	 36.00
39.00
42.00
45.00
46.00
51.00
. . 	 54.0O
57.00
60.00
63.no
66.00
69.00
	 . .72.00 _ 	
75.00
78.00
... 61.00
84.00
87.00
90. on
93.00
96.00
99.00
102.00
105.00
108.00
111.00
114.00
117.00
120.00
126.00
132.00
138.00
144.00
150.00
156.00
162.00
168.00
174.00
180.00
1H6.00
19?. 00
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204.00
210.00
216.00
222.00
228.00
234.00
240.00
24r>.00
252.00
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264.00
270.00
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2C2.00
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0.5000
0.5000
0.5000
0»5000
0.5000
0.5009
0.5000
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0.5000
0.5000
0.5000
0.5450
0.5450
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0.5450
0.5450
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0.5450
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0.5850
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0.5950
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7.59
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8.05
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U.58
8.73
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9.01
9.15
9.28
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0.45
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0.78
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0.98
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2.27
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3.44
3.66
3.87
4.09
4.30
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4.72
4,93
5.1*
5.34
5.55
.... ... . 5.75
5.95
6.15
6.35
6.5*
6.73
6.91
7.10
7.29
7.46
7.66
7.8*
8.02
8.20
8.56
0.93
1.30
1.68
2.04
2.40
2.75
3.09
1.42
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4.76
5.07
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6.69
7.01
7.32
7.61
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(MC M2S04I 	
0.59999
0.83998
.05998
.24998
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.73999
.88998
' 	 2.01999
2.15999
2.2B999
2.329'H
2.45998
	 ^,.57997 	
2.6799U
2.78998
_. 	 2,811997. .. _._
2.98997
3.07997
	 3,16997
3.25990
3. 35997
3.44997
3.52997
3.61996
3.70998
3. 78998
3.85997
	 ._ 3.92998 	
4.00998
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4.50993
4.7*997
*.'J7997
	 	 	 5.21997 . .
5.44997
5.66997
5.87997
6.09998
6.30997
	 	 7.4i997
t. 72997
6.93997
7.1499B
7.34998
7.55997
7.75998
7.95998
8.15997
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8.54997
8.73997
8.91997
9.10997
9.29997
9.48997
9.66997
9.84998
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10.20998
10.56998
10.93997
11.30997
11.68997
12.04997
12.40997
12.75998
	 13.09998
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13. 77997
14.10997
14.43-197
14.76997
15.07997
15. 39998
15.72997
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16.69997
17.01997
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6.00
7.00
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9.00
10.00
11.00
12.00
13.00
... ._ 14.00.
15.00
16.00
17.00
Id. 00
1 1.»0
20.00
21.00
22.00
	 21.00
24.00
25.00
11,. 00
27.00
28.00
29.00
30.00
' 33.00
	 36.00
39.00
42.00
. . .45.00.
48.00
51.00
	 	 -54.00
57.00
60.00
. . 63.00
66.00
69.00
.._.._ 	 72.00-
75.00
78.00
81.00
84.00
87.00
90.00
93.00
96.00
99.00
102.00
105.00
1011.00
111.00
114.00
1 17.00
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1 26 . 00
132.00
1 18.00
144.00
150.00
1 56.00
162.00
168.00
1 K.OO
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192.00
198.00
204.00
210.00
216.00
222.00
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0.5000
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0.5000
0.5900
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0.5450
0.5450
0.5450
0.5450
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0.6200
0.6200
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0.6200
0.6200
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8.29
	 	 _ 	 8,73
9.14
9.52
0.73
1.08
1.39
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1.95
2.21
2.46
2.71
2.94
3.16
3.37
3.60
3.60
4.00
4.20
	 4,40. -
4.59
4.76
4.94
5,11
5.29
	 5 ^4__5
5.61
5.79
5.96
6.13
6.66
7.14
7.62
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0.01
0.50
0.99
1.47
1.92
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2.83
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. .. 	 .. J.91 ._
4.19
4.63
5.Q8
5.51
5.95
0.41
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1.60
2.00
2.40
2.80
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3.59
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4.37
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7.99
8.67
9.34
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2.26
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3.39
3.91
4.44
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CAICUIAIIONS FlIX ORAVIMlIRIC tLdtl LKPlklMI MlS
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UAU . 9 t 71
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CMKtCMON- -6.18 HG
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	 (UNI ...
1. 00
2.00 	
3.00
4.00
5.00
6.00
7.00
8.00
9.00
10.00
11.00 	
12.00
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	 14.00
15.00
16.00
17.00 	
18.00
19.00
20.00 . . ._ 	 	
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	 23.00
24.00
25.00
	 26.00.
27.00
28.00
	 .29.00 	 „.. 	
30.00
33.00
36.00
39.00
42.00
45.00
48.00
51.00
	 5.4.00. . ..
57.00
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63.00
66.00
69.00
72.00
75.00
78.00
81.00 	
84.00
87.00
90.0"
93.00
96.00
99.00
102.00
105.00
108.00
111.00
114.00
117.00
120.00
126.00
132.00
138.00
144.00
150.00
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162.00
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174.00
180.00
186.00
142.00
148.00
204.00
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MASS DIAL

0.5100
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0.5100
0.5100
0.5100
0.5100
0.5100
0.5550
0.5550
0.5550
0.5550
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0.5550
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0.5550
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0.5550
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0.5550
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0.6000
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0.6000
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0.6000
0.6000
0.6000
0.6000
0.6000
0.6000
0.6000
0.6000
0.6000
0.6000
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0.6350
0.6350
0.6350
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0.6150
0.6150
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0.49
0.70
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2.64
2.80
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3.09
3.22
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3.63
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3.90
4.30
4.68
5.05
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7.26
7.61
7*58
8.32
8.68
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9.36
0.87
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1.59
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2.30
2.66
3.00
3.36
3.70
4.04
4.37
4,70
5.02
5.34
5.66
6.29
6.91
0.44
1.02
1.60
' 2.16
2.71
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3.80
4. 35
4.89
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5.41
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76.19 t

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0.62997
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1.15447
1.39998
1.649VB
1 ,89998
2. 12947
2.26997
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2.69998
2.90997
3.10997
3. 29497
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3.66448
3.82997
3.9999B
4. 169VU
4.33998
_ 	 ^__ 	 4.40997 	 	
4.639'JB
4. 79997
4.93447
5.08998
5.21997
_ 	 	 J>i3'»998 	
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5.62997
.._ 	 : 	 _._ 5,76997 	 	
5.89998
6,29997
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7.04997
7.40947
7.7899U
8.16998
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8,8899(1
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10.31996
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11.37997
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12.93997
13. 29497
13.65997
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14.35997
14.69998
15.03998
15.36998
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16.65997
17.28998
17.90997
18.43997
19.01997
19.59998
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20.70498
21.25998
21.79997
22.34093
22.88948
23.4094J
23.92448
24.43497
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25.44496
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27.37997
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               480
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DATt -
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1.00
	 2.00..
3.00
4.00
5.00
6.00
7.00
8.00
9.00
10.00
11.00
12.00
13.00
. 14.00
15.00
16.00
.. . 17.00
18.00
19.00
	 20.00 .
21.00
22.00
. . _ . 23.00
24.00
25.00
	 ..26.00
27.00
28.00
_ 29.00
30.00
31.00
.. 36,00
39.00
< 42.00
45.00
44.00
51.00
14 > 00
57.00
60.00
61.00
66.00
69.00
72.00
15.00
78.00
81.00
84.00
87.00
90.00
93.00
96.00
99.00
102.00
105.00
108.00
111.00
114.00
117.00
120.00 •
126.00
132.00
U8.00
144.00
150.00
156.00
162.00
168.00
174.00
180.00
186.00
197.00
198.00
204.00
210.00
216.00
727.00
228.00
2)4.00
740. (10
740.00
257.00
258.1)0
264.00
770.00
210.00
787.00
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300.011
194 SO/ * 2000.
9 1 71 NO > ISO.
103.30 MG 02 » 3.5
-5.98 MG M2O • 6.0
MASS DIM

0.5150
.. ... __ . . Q,5150
0.5150
0.5150
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0.5150
0.5150
0.5150
0.5150
0.5150
	 0.5I5C,
0.5150
0.5150
0.5150
0.5150
0.5600
	 . .0.5600
0-5600
0.5600
	 	 	 0,5600 ... ..
0.->600
0.5600
	 0.5600 	
0.5600
0.5600
0,5600
0.5600
0.5600
0,5600
0.5600
0.5600
. .... ... 0,5600
0.5600
0.5600
0.5600
0.5600
0.5600
0.5500
0.5600
0* S6CG
0.5600
0.5600
0.5600
0.5600
0.5600
0.5600
0.5600
0.5600
0.5600
0.5600
0.5600
0.5600
0.5600
0. 5600
0.5600
U.560U
0.5600
0.5600
0.5600
0.5600
O.SeOO
0.5600
0.560J
0.5600
0.5900
0. 5WO
0.5900
0.5)00
0.5900
0.!>->00
0.5900
U.590J
0.5^00
0.5900
0.5900
11.5900
O.VIOO
0.5"tlO
O.VIOQ
0. V'OO
O.VOO
o.'> too
3,'i'XIO
O.ViOO
O.'.'IOO
O.yiOO
U.V100
U.V100
0. ••">('
U.4'100
Pl'« tlW • 20U.
PPM HI) • 11(10.
< H2SU4 * 75.6V
*
CHART
IMCMFS
/.78
7.87
7.9t
8.06
. 8.16
(1.26
8.37
8.47
8.5*
8.67
B.74
8.82
8.90
8.99
	 9.06"
0.12
.,0.20 	
0.29
0.37
_. .0,45.
0.53
0.61
	 .0.69
0.7£.
0.83
0.8.9
0.96
1.01
.09
.15
.32
. .50
.66
.65
2.01 _
2.18
2.34
2.50
2.67
2.62
2.96
3.10
3.25 '
3.39
3.53
3.67
3. 80
3.94
4.08
4,21
4.34
4.47
4.59
4.12
4.87
5.00 .
5.14
S.27
5.40 . 	
5.54
5.8C
6.0!. . .
6.30
6.55
O.R2
1.09
1.35
1.60 .
l.t>5
7. ID
2.36
2.61
2.86
.3.10
3.34
*.->r
l.HO
4.C7
4.24
4.45
4.65
4.1)5
5.04
5. .'4
'» . 4 It
-J.fc'l
*>.9C
I..I 1
6. Ik
1. .Ml
UL(». F.
Lt/MIN


PICKUP
(MG H2S04)
.49998
.58998
.67998
.77998
.87997
.97998
i 2.08998
2.18997
2.29997
2.38998
2.45998
2.53998
2.61998
2.70998
2.79997
2.83998
	 2.9199H
1.0099U
3.0S19B
3.16*98
3.24998
3.32997
3.40997
3.47998
3.54997
1.6099J}
3.67998
3.72998
3.8099U
3.86998
4.03998
_ 4_. 21999
4.39998
4.56998
4.72998
4.89996
5.05998
5.21999
5.38998
5.53796
5.67998
5.81998
5.96999
6. 10999
6.24998
6.38998
	 6.51997_._
6.65997
6.79997
6.9J998. _
7.05998
7.18997
7.30998
7.43997
7.58998
7.71999
7.85999
7.9B99T
». 11998
B.2599H
8.51997
8.7699?
9.01997
9.26997
9.53998
9.8099B
10.06998
10.31998
10.56998
1C.B19)U
1 1 .07^97
11.32997
11.57997
11.81998
12.059VU
12.289'I8
12.51997
17.73997
17.959'»B
1.1. 16998
11. 164'IU
I.I.56')'Hi
14.40'M/
I4.61'l')tl
I4.lt4'l'll(
1 '< . 0 7 't 't /
ls.,-'rr»i
                   481
-------
C»tCUL»riONl  FIIK GHAvmiKIt  FlUw
RUN HO. •
UAH •
(IKT »!.•
CORRECT KiM-
HUE
(HI'll
1.00
2.00
J.OO
4.00
5.00
6.0(1
7.00
8.00
9.00
10.00
11.00
12.00
13.00
14.00
15.00
16.00
17,00
18.00
19.00
20.00
21.00
22.00
.. 23.00
24.00
25.00
26.00.
27.00
28.00
29.00
30.00
33.00
36.00
39.00
42.00
.. 45.00
48.00
51.00
_...54...00
57.00
60.00
63.00
66.00
69.00
.._ 72.00
75.00
78.00
ai.oo
84.00
87.00
90.0k
93. CO
96.00
99.00
102.00
105.00
108.00
111.00
114.00
117.00
120.00
126.00
132.00
138.00
144. PO
190.00
156.00
162.00
168.00
174.00
180. PO
180.00
192. PC
198.00
204.00
210.00
216.00
22. '.00
22H.OO
234. PO
240. PO
246.00
252.00
2V..PO
264.00
270.00
27o.l'0
2H.'.OJ
2HH.HP
,"i4 . ro
ll/l'.OO
195 SU2 • 2000. PCM
•1 10 71 (in • l',0. PPK
104.70 HG U2 • 3.5 1
-5.87 MO H20 « 6.0 (
MASS DIAL
.
0.5200
0.5200
0.5/00
0.5200
0.5200
0.5200
0.5200
0.5200
0.5200
0.5200
0.5205
c.5200
0.5200
. 0.5650 ..
0.5650
0.5650
0,5650
0.5650
0.5650
. 	 0.5650. 	 	
0.5650
0.5650
0.5650
C.5600
0.5650
. . 0,5650
0.5650
0.5650
, 	 	 	 0.565D _ 	
0.5650
0.5650
jO. 5650
0.5650
0.5650
.. 0,5650. . 	 .
0.5650
0.5650
	 0.5650 	
0.5650
0.5650
0.5650
0.5650
0.5650
	 0.5650 	
0.5650
0.5650
0^5650
0.5650
0.5650
O.'ih'iO
0.5650
0.5650
0.5650
0.5650
0.5650
0.5650
0.5650
0.5650
0.565P
0.5650
0.5650
0.6100
0.6100
0.6100
O.blOO
0.6100
0.6100
0.6100
0.6210
0.6250
0.62SO
0.6250
0.6250
0. 62V
0.(i25P
0.6250
O.h/SO
0. h2')t1
0.6.">0
0.1.250
<).02'.i>
o.*»2-)0
0.6/'>e
0. t>2'>0
il.(,.".0
O.h2'»0
ll.l/Sl)
O.f. 2'tO
II. (•.">('
U.I.,' '.0
I EMP '
Mil -
M2SU4 •

CHART
IMCMFS
7.49
7.69
7.88
8.04
8.20
«. 35
8.50
8.63
8.76
8.b9
9.01
9.12
9.23
....0.2'. .
0.35
0.46
0.56 .
0.66
0.76
	 .0.87.
0.97
1.06
-1.14
1.24
1.34
1.43
1.51
1.59
i.«.69._.
1.78
2.04
	 4,29,
2.54
2.79
3,04
3.29
i.53
JU 78
4.0l"
4.25
4.49
4.72
4.96
5.19
5.43
5.66
5.9.0
6.13
6.36
6 so
a. 82
7. Ob
7.30
7.54
7.77
8.00
8.23
8.46
S.69
3.91
4.36
C.tll
1.27
1.7)
2.18
2.62
3.06
. I.4B
0.40
l.il
1. /O
2. I'l
.' . t.O
I.UI
1.44
I.H6
• . / '1
4. 10
*•.! 1
•••••I
'..'11
^. 1U
t. . l> -1
i.PI
1.44
7 »ll 2
t . 1 li
C.1)*
I'.ni
'i . .' 3
• 200. ore. F.
1M.O. CC/MIN
76.92 I

PICKUP
(Mb H2SII4I
0.91997
1.11996
1.30447
1.46947
1.62997
1. 77947
1.4249S
2.05997
2.18947
2.3194*
2.43497
2.54497
2.65997
2.66497.
2. 77997
2.88997
2, 989') 1
3.08997
3. 18997
3.29997
3.34496
3.48997
3.56948
3.66-197
3.76997
	 	 , 	 .3. 5)5947. 	 . .
3.43997
4.01997
	 . ...4 ,11 9-9 6 	
4.20998
4.46997
4.71997
4.9690.7
5.21997
5.46997
5.71997
5.95998
	 	 ...... 6, 2099B... __
6.43997
6.67998
6.91997
7.14996
7.38997
7,61996
7.85997
8.06997
8.32997
t. 55997
8.78996
9.01997
4.24997
9.50996
9.72997
4.46447
10.19997
10.42998
. ' 10.65997
10.88997
11.11996
11.33947
11.78996
12.23997
12.69997
13. 15997
U.60'197
14.04'I9;
ll.4H')9(
14.9099/
1 '< . 3/'l94
15. 759-IB
lo. IB'l I'l
16.619 IB
1 7.079'IB
If. 4 »•>•(•»
17. Hf.'llIH
If .2H44H
If. /1'1'W
14. 1,"|.| 1
I'l .5 I'HH
l'l.9 ).|'I4
2f. ll'l'ld
20. /24'lrt
21. 1 1'1'IH
21. 4'lrl'IB
21.H(,'M,1
22. '4'l9il
/,' 
-------
IALCUIAI IDNS ru« GKAVIMHRIC HUW
HUN NO. • 196 502 • 2000. PPM
DATE • 9 14 71 (W » lr>q. PPH
DRY HI.- 100.42 HC O2 • 3.5 »l
COKRECtlON' -6.22 MO H20 • 6.0 I
TIME
. .IMINI
i.oo
	 ..2.00.. 	
3.00
4.00
...5,00
6.00
7.00
8.00 _
9.00
10.00
. . 11.00 . . .
12.00
13.00
._.14.00 	
15.00
16.00
. . _..17.00 	
18.00
19.00
	 20.00 	
21.00
22.00
.. _ 23.00 	
24.00
25.00
_ ..26.00 	
27.00
28.00
29.00
30.00
33.'00
36.00
39.00
42.00
4 5.. 00
48.00
51.00
54.00
57.00
00.00
	 63. .00 .. _
66.00
69.00
17.00
75.00
78.00
81.00
84.00
87.00
90. nn
93.00
96.00
99.00
102.00
105.00
108.00
111.00
114.00
120.00
126.00
132.00 . .
1 Jfl.OO
144.00
150.00
156.00
162.00
168.00 	
174.00
IbO.OO
186.00
192.00
198.00
204.00
210.00
216.00
222.00
228.00 •
234.00
240.00 	
246.00
2*2.00
264.00
270.00
? IA nn
2B2.00
288.00
294.00 	
300.00
MASS DIAL
0.5000
	 O.SOOO
0.5000
0.5000
	 ,0.5000..._
0.5000
0.5000
.. . 	 0.5000
0.5000
0.5000
. 	 . 0.5000
0.5000
0.5000
..... ... . _0,5000 . .
0.5000
0.5000
	 	 	 	 0.5.00D
0.5000
0.5000
	 0.5000
0.5000
0.5000
. 	 0.5000
0.5000
0.5000
p. 5000
0.5000
0.5000
	 o.r,ooo
0.5000
0.5400
0.5400
0.5400
0.5400
0.5400
0.5400
0.5400
0.5400
0.5400
0.5400
0.5400
0.5400
0.5-400
0.5400
0.5400
0.5400
0.5400
0.5400
0.5400 .
0.5400
0.5400
0.5400
0.5400
0.5400
0.5400
0.5400
0.5400
0.5400
	 	 9,5400.. 	
0.5400
0.5400
0,5400
0.5400
0.5400
0.5400
0.5400
0.5400
0.540Q
0.5400
0.5400
0.6400
0.5400
0.5400
0.5400 	 _ ...
0.5400
0.5400
_ 0.5400 	 _ ...
0.5400
0.5400
0.5400
0.5400
0.5400
0.540D
0.5400
0.5400
0.5.400 . _
0.5400
0.5400
0*5400
0.5400
n»f > 200. ore,. F.
f 1 [| • 1500. CQ/MIN
t«S04 • 75.78 I
CHART 1
HIGHER (M!
7
7
7
7
7
7
7
f
7
7
a
8
8
8
8
8
8
8
8
8
8
8
8
8
8
a
8
8
8
8
0
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
.44 (
.54 (
.60 !
.65
.71
.77
.82
.88
.93
.98
.04
.10
.16
,2_1. 	 	 	 	
.26
.31
.36
.40
.44
• 19
.54
.59
.63
MCKUP
;_ii2S04) 	
). 79999
1.89999
). 95999
.00999
.06999
.12999
.17999
.23999
.28999
.34000
.39999
.45999
.51999
.56999
.62000
.67000
.71999 ___
.75999
.79999
.84999
.89999
.95000
.98999
.68 2.03999
.72 2.07999
.76 2.120DO
.so ;
.85 i
'.•}} ";
.93 i
,0.3 	 <
.14 i
.26 i
.37 i
.48 ;
.59 i
.6? 3
.79 :
.69 :
'!'09 3
.19 :
.29 5
'.15999
'.20999
'.25000 	 .
'.28999
'.28998
'.38998
.49998
.61998
.72998
'.83998
'.94993
1.04997
1.14998"
.3499B
1.44998
1.54997
.64998
.39 3.74998
.49 3.84998
.59 3.94998
2.69 4.04997
2.78 4.13998
2
3
3
3
3
3
3
3
	 3
3
3
4
4
4
4
4
4
5
5
5
5
5
6
. 6
6
J»
6
6
7
7
7
7
.7
7
8
,.. 8
a
8
. 8
.97 4.32997
.06 4.41998
.15 4.50998
.24 4.59998
.32 4.67998
.40 4.75998
.49 4.84998
.57 4.92998
.66 5.01997
.74™ 	 	 " 5.09990
.90 5.25998
,08 . . 5.43997
.26 5.61998
.44 5.79997
.61 5.96997
.80 6.15997
.98 6.33998
,16 , 6;51997
.34 6.69998
.51 6.86998
.70 7.05998
.87 7.22998
.05 7.40997
.72 7.57997
.40 7.75998
.58 7.93997
.75 8.10999
.93 	 ~ 8.28998
.10 8.45998
.27 ....... 	 ..8.62997 	
.43 8.789V8
.60 8.95998
-77 9.12997
.94 9.29997
.10 9.45998
.27 9.62997
.44 9.79997
.60 9.95998
.77 10.12997
B.91 10.28998
                       483
-------
CALCULATIONS FUR  GKAVIMUHIC  HI,.! CXI'CHlMbNTS
RUN NO. •
DMt •
DRV Hi.-
COHRfCT ION"
TIME
I«!NI
1.00
2.00
3.00
4.00
5.00
6.00
7.00
. 8.00 	
9.00
10.00
1KOO
12.00
13.00
14.00 .
15.00
16.00
17.00
18.00
19.00
20.00
21.00
22.00
23.00
24.00
25.00
	 __26.00_. .
27.00
28.00
29.00
30.00
33.00
36.00
39.00
42.00
45.00
48.00
51.00
S4.00
57.00
60.00
63. 00
66.00
69.00
J2.0.0 _
, 75.00
78.00
fll.nn
84.00
87,00
on. on
93.00
96.00
99.00
102.00
105.00
100.00
111.00
114.00
117.00
120.00
126.00
132.00 .
\iU.UO
144.00
_. 150.00
I5(..<>0
162.00
168.00
174.00
180.00
106.00
192.00
198.00
204.00
210.00
216.00
222.00
228.00
234.00
240.00
246.00
757.00
„ 	 2b.a.co..
264.00
270.00
216.00 .
282.00
200-00
294.00
300.00
197 S02 • 2000. PPM
9 15 71 _ HI) » j 50. PP«
Vfl.30 MC 02 • "" 3.5 X
-6.09 MC H20 • 6.0 »
MASS DIAL
0.4900
0.4900
0.4900
0.4900
0. 4VOO
0.4900
0.4900
.. 	 0,4900 	 . 	
0.4<)00
0.4900
0.4900
0.4900
0.4900
0.4900
0.4'!00
> 0.4900
	 O.',900
0.4900
0.4900
0.4900
0.4900
0.4900
	 0-4-(00 	
0.4900
0.4900
	 0.. 4.90.0 	 	
0.4900
0.4900
0.4900
0.4900
0.5350
0.5J50
0.5300
0.5350
0.5350
0.5?50
0.5350
0.5*50
0.5350
0.5353
0.5300
0.5350
0.5350
0.5350 , ,
0.5350
0.5350
0.5350
0.5350
0.5)50
0.5350
0.5350
0.5350
0.5350
0.5350
0.5350
0.5350
0.5350
0.5350
0.5350
0.5350
0.5350
. . . 0.5359 _
0.5350
0.5350
	 0.5}',0 _.„ .
0.5350
0.5350
0.5350
0.5350
0.5350
_0.535Q
0.5350
0.5350
0,5350
0.5350
0.5350
0.5)50
0.5350
0.5350
0.5350
0.5350
0.5350
0.5350
0.5350
0.5350
0.5350
0.5350
0.5J50
O.S1SO
O.SJSO
IfHf • 200
FID « ...151.0.
112 SO* " /4.73
CHART
INCHC-S
7.52
7.63
7.70
7.77
7.83
7.89
7.96
_...8,P2 	
8.09
8.15
8.21
8.28
8.34
8.40
8.45
8.50
8.54
8.59
8.64
8,69
8.74
8.78
8.8? .
8.116
8.90
..J1..94 	
B.9B
9.02
9.07
9.11
0.08
0.19
0.30
0.41
0.52
0.62
0.73
0.83
0.93
!.04
1.1 'i
1.25
1.36
1.47
1.57
1.67
1.77
'..86
1.96
2.06
2.15
2.25
2.35
2.45
2.55
2.65
2.74
2.84
7.93
3.01
3.20
_.- ».»«.. _ .._
3.57
3.75
,.3.93. 	
4. 10
4.30
4_,48
4.65
4.02
5.00
5.18
5.35
5.52
5.70
5.88
6.06
6.24
6.42
6.60
6. BO
6.98
'•*•*,
7.35
7. S3
7.70
7.89
8.07
6.23
8.39
. OEG. F.
CC/MIN 	
I
PICKUP
(Hb H2SU4I
1.12997
J.2399.7_ _
1.30998
1.37997
1.43997
1.49998
1.56998
1.62997
1.6999!)'
1.75998
1.B1998
1.88998
1.94998
2.00998
2.05998
2.10999
2. 14998
2. 19990
2.24998
2.29997
2.34998
2.30998
2.42998
2.46997
2.5099B
2.54997 	
2.58998
2.62997
2.67998
2.71997
2.68997
2.79997
2.90997
3.01997
3.12997
3.22998
3.33998
3.43997
3.5399B
3.64998
3.7*998
3.85999
3.96997
4.07997
4.17998
4.27998
4.37997
4.46997
4.56998
4.66998
4.75996
4.85999
4.95998
5.05998
5.15997
5.25998
5.34998
5.44998
5.53998
5.61998
5.80998
5.99998
6.17998
6.35999
6.53998
6.70998
t. 90997
7.08998
7.25998
7.42998
7.60999
7.78998
7.95998
8.1299T
8.30998
8.48997
8.66998
8.84948
9.02998
9.20998
9.40997
«. 56998
9.77998
9.95998
10.13998
10.30998
10.49998
10.67998
10.83978
10.99998
                       484
-------
CM.CULA1ION& F(lK GRAVIMETRIC FIOH
P.IIN NO. > 198
UAIC •_ .9 Ib
DRV WT." 103.10
CORRECTION* -5.10
...

—
—
-

-
TIME
(MINI
1.00
._ 2.00 	 _
3.00
4.00
5.00
6.00
7.00
8.00 	
9.00
10.00
	 11.00
12.00
13.00
..14.00 _ 	 „
15.00
16.00
	 17.00 	
18.00
19.00
.. 20,00.. .. ... _
21.00
22.00
. 23.00 _
24.00
25.00
. 26.00 	 	
27.00
28.00
29..00
30.00
33.00
	 36.00 	 	
39.00
42.00
45.00
48.00
51.00
54.00
57.00
60.00
	 63.00 	
66.00
69.00
7J.OO
. 75.00
78.00
ni.no
84.00
87.00
90.00
93.00
96.00
99.00
102.00
105.00
108.00
111.00
114.00
117.00
120.00
126.00
J32.00
138.00
144.00
150.00
156.00
162.00
Ib8.00
174.00
180.00
la(>, oo
192.00
198.00
204.00 	 	
210.00
71b.OO
222.00
228.00
734.00
24,0.00
246.00
25?. 00
256*00
204.00
270.00
27b»00
782.00
2 1)1). 00
294 .00
300.00
SII2 • 2000. PPM
71 HO « (50. PPM
KG 02 • 3.% *
MB H2U ' 6.0 *
MASS DIAL
0.5100
0.5100
0.5100
0.5100
0.5100
0.5100
0.5100
J>.5100 ..
0.5100
0.5100
0.5100
0.5100
0.5100
	 0, 55.50 	 . 	
0.5550
0.5550
.. . __..0, 5550
0.5550
0.5550
0.55SO
0.5550
0.5550
	 	 .0.5550
0.5550
0.5550
0.5550
0.5550
0.5550
O.SI'.O
0.5550
0.5550
0.55'jO
0.5550
0.5550
0.5550
0.5550
0.5550
0.5550
0.5550
0.5050
	 0.5550 _ 	 	 	
0.5550
0.5550
0.5550
0.5550
0.5550
O.5550
0.5550
0.5550
O.S550
0.5550
0.5550
0.5550
0.5550
0.5550
0.5550
0.5550
0.5550
0.5550
0.5550
0.4550
0.5550
0.5550
0.5550
0.5550 	
0.5550
0.6000
0-6000
O.bOOO
0.6000
O.bOOO
0.6000
0.6000
0.6000
O.bOOO
0.6000
O.hOOO
0.6000
0.6000
0.6000
0.6000
0.6000
p.6000
0.6000
0.6000
0. 61)00
O.hOOO
0.6400
0.6400
T6MP .
Fit) •
H2SD4 >
CHART
INCHES
8.11
8.19
8.27
8.34
8.42
8.50
8.58
8.67
8.74
8.81
ft. 89
8.98
9.06
0.07
0.13
0.19
9,21
0.34
0.41
0.46
0.55
0.62
0.69
0.76
0.82
O.flS
0.97
1.03
J.JQ
1.08
1.37
-L.57
1.76
1.95
2.14
2.32
2.51
2.70
2.89
3.08
	 3,27._
3.46
3 '.64
. — 3.82
4.01
4.20
4,40
4.59
4.79
4.99
5.18
5.38
5.58
5.77
5.97
6.18
6.39
6.69
6.80
7.01
7.47
7.84
8.25
8.67
9.06
9.49
0.89
-J.2,9
l.bB
2.08
2.48
2.89
3.30
	 J.71
4.11
4. SI
_ .t'1*'
5.36
5.74
*.U
6.S7
6.41
	 1, it
7.69
B.07
	 a. 45 _
8.8)
0.94
	 l.iO_.
1.46
200. UCC. f.
1500. CC/KIN
77.32 %
PICKUP
IMG H2S04I
1.90997
1.9B997
2.06998
2.13998
2.21999
2.29999
2.37997
2.46999
2.51998
2.60999
2.68999
2.77998
2.85999
2.86906
2.92998
2.98997
3.06998
3.13998
3.20998
3.27998
3.34998
3.41998
3.48997
3.55998
3.61998
3.68999
3.76997
3.82999
3.89998
3.87997
4.16998
4.36998
4.55998
4.74998
4.93999
5.11998
5.30998
5.49998
5.68999
•5.R7997
6.06998
6.25998
6. 43999
6.61998
6.80998
6.99998
7. 19998
7.38998
7.58998
7.7B998
7.979V8
6.17998
B. 37997
8.56998
8.76997
8.97998
9.18999
9.48997
9.59998
9.80998
10.21999
10.63998
11.04999
11.46999
11.87997
12.28998 ""
12.68999
13.08998
13.47998
13.87997
14.27998
14.68999
15.09998
15.50998
15.90997
16. 10998
16.74998
17.15997
17.53998
17.9299B
I8.3199U
18.70998
19.00998
I9.4H997
19.8699*
20.24998
20.62997
20.73997
' 20.99
-------
                 APPENDIX A-17-3

 S02 SORPTION RATES FOR DETERMINATION OF THE S02
ACTIVITY OF POST-TREATED (NH4>2S EXTRACTED CARBON
   SAMPLES USING DIFFERENTIAL RATE APPARATUS
                       486
-------
          CAICUIATIONS fllh GkAVIHtlHIL film




     C-70-77 (VIRGIN)




.. .RUN NO, •  180 	
IMH « 9 "»
tut m.. 95.10
.COSKElUllN' -6.18
. MEAN LUAU 	
CMS S02/100 GKS C
0.87202 ...
0.4)410
0.99B43
1.05519
1.11195
1.16871
1.22189
1.27449
1.32867
1.38543
1.44477
1.49637
	 1.54023.: 	
1.59105
1.64601
	 1.69761
1.74663
I. 79565
.. 	 ...1.84725 . .
1.90142
1.96076
	 	 2. U2011. -
2.07686
2.13»M
.- 	 2.19030 .._.
2.24714
2.30132
2.35550
2.40968
2.51604
	 	 	 2.68831 	
, 2.85859
3.02371
3.19141
3.36168
3.52939
.. .3.69450 	
3.B5704
4.01958
4.18728
• 4.35756
4.52525
4.6B779
' 4.B5549
5. 02834
. 1 . 5.19604 . _
5.36116
5.52886
._ 5.69398 ..
5.05651
6.01905
6.16095
6.30543
6.46797
6.62534
6.78014
6.93494
7.0H974
7.24454
7.47157
7.76827
8.06239
6. 15908
8.65062
t. 93700
.9.211)21
9.4')427
9.77291
10.04331
10. 30431
10.54040
10. /K426
11.01645
11.24149
11.467'It
1 I.6H9H2
11.906S4
12.111110
12. 3/91,5
11. •> 16U5
I2.7I//9
I?.')!1)'!'.
1 1.1 I/UI
I3.3/5M
I J.MI.H4
1 \.i:'llr./
1 1. MH.'HO
|4.0' )'. i
14.,' I'*.1',
71 NO • 150.
Cf. 02 « 3.5
MC. . .IliD." 	 6.0.
	 D1FFMENUAL RATE
HOM S02/GM C-M1N
. _ 	 	 0.72239 .
0.61917
0.56760
0.56760
0.56760
0.56760
. .0.516O2
0.51595
0.56760
	 0.56760
0.61925
0.41273
	 	 0.46445 	
0.56760
0.51595
	 	 0.51602 ..
0.46438
0.51602
. 	 0.5159i_,
0.56760
0.61925
	 	 0..56760 	
0,56752
0.56760
..- 	 _ 0.56760 .
0.56760
0.51602
	 0.56760 . ..
0.51602
0.55038
_ 	 	 0.584J9. 	
0.55041
0.55038
0.56760
0.56760
0.55041
0.55036
0.53319
0.55U41
0.56760
0.56760
0.55038
0.53319
0.58479
0.56760
.. ...... 0.55041
0.55038
0.56760
0. 53119
0.55041
0.53319
0.41280
0.5503B
0.53319
0.51600
0.51600
0.51600
0.51600
0.51597
0.49Bt>0
0.49020
0.49019
0.49B60
0.47300
0.4B159
0.45579
0.46440
0.46439
0.43U60
0.429V9
0.3U699
0. »95'>9
0.37H40
O.I7U40
0. I6-JM
0. I6^H()
0. «'-260
0.3'i2'j'l
0.)'>2I>0
0. 13540
O.llViU
0. l^itllO
0. I26HU
O.llHl'
O.Jlal-
U.."'/41
o . 1 1 n r
O.»'r ini
0.? l.'l>
?fn F(T1 • 1SOO.
t H2UI4 * 75.14
-' 	 - 	
MEAN LOAD
CMS ACID/100 &MS I
l.J35?B '
1.4)799
I. 52885
1.61577
1.70260
1. 71)959
1.87256
1.V5157
2.03452
. ... 2.12144 ._._
2.21231
2.29132
	 . _. ..2.J5B4T 	
2.4374'V
2.52045
	 2.59946 	
2.67452
2.74959
2.82860.
2.91155
3.00242
. 	 ..3.0?329_. _
3.1B020
3.26710
.. . 	 Jj 35402 	 _
3.44093
3.52369
3,60666
3.63982
3.B5575
	 	 4,11640. 	 	
4.3T722
4.63006
4.04684
5.14758
5.40437
5.65721
5.90609
6.1549U
6.41177 ...
6.67251
6.92930
7,17818
7.43496
7.69965
7.95644
8.20928 	
8.46606
B. 71890
8.9677H
9.21667
9.43396
9.65519
9.90407
10.14506
10. 38209
10.61913
10.85617
11.CV320
11.44085
11.89517
12.'34553
12.74985
13.^4626
13.69470
14.11539
14.5I8IU
14.')t>477
15.37950
15.7785'!
16.15388
16.51 tin
l6.8hU9)
17.2lt5H
17.1oO?9
17.9UU04
III./ JIH-I
111.5-iSlll
III. I1797H
l').l'!5H2
I9.5019/
I'l.lU'lll/
/0.10K4I
2U.4C471
2C.((''/05
,'0.'if/'>4
<•!.;• '>Mill
21.->t'.'/o
tl.H'iSt.
CC/MIN
t
.
DIFFtKI-NTIAL R4Tt
MOM ACID/CM C-MIN
1.10616
0.94810
O.B6913
0.06913
O.B6913
0.8691 1
0.79016
0.79004
0.86913
0.86913
0.94822
0.63199
0.7112C 	
0.86913
0.79004
	 O.J9016 	
0.71107
0.79016
0.79004
0. 869 13
0.94822
. 	 .0..86913 ..: 	
0.86901
0.86913
_ 	 _._0.«.8t9l 3 	 _...
0.86913
0. 79016
	 0..86913. 	
0.79016
0.84277
	 0*89545 	
0.84281
0.84277
0.86913
0.86913
0.84261
0.34277
0.81645
0> C*t2t> 1
.0.86913 	
0.86913
0.84277
C. 81645
0.89545
O.B6913
_ 	 0.84281 	 ._.
0.84277
0.86913
0.81645 	
0.84281
0.81645
0.63211
0.84277
0.81645
0.79012
C. 79012
0.79012
0.79012
0.79008
0.76378
0.75062
0. 75060
0.76370
0.72428
0.7)744
0.69793
0.71112
0.71109
0.67161
0.65R4 »
0.59258
O.o0'i74
0. 5/942
0.5/042
a. 56624
0.56626
0.5»'"*2
0.5 i9'fl)
0.53'l'»2
U.51 157
0.->l 1S7
-------
C»ltUl»l IDNi MIR bkAVIMtIkIL  ILIIW I I l>l ft I Ml Nl !>
RUN NO. • l»9
UAIt • 8 31 71
MY NT.- 98.86 MG
CUKKECIIUN- -6.27. MO
MEAN LOAD
GKS~S02/100 GKS C
0.31687 	
0.48160
(j. 5988V
0. 69371
0.77856
0.85341
0.93077
1.01811
1.10296
1.16201
1.26266
1.34251
1..419B1 	
1.49971
1.57958
	 1.65443 . .
1.72680
1.B0166
	 . 	 1.67403. 	
1.9)641
2.00129
	 2.06617
2.12607
2.18096
	 2.230J7 	
2.28078
' 2.31068
	 2.38059
2.42801
2.53780
.2.70998 .
2.87468
3.03189
j. 18410
3.336)2
3.48605
?-*'*;>;»''
i. TU 300
1.93023
4.07496
4.21969
4.36442
	 4.50666 . .
, ' 4.64391
4.78365
4.925S9
5.04816
5.1729}
	 .5.31517 	
5.45740
i. 59714
5.73439
5.B74I3
6.011)6
6.14B62
6.28587
6.42312
6.55787
6.68763
6.87229
/ 7. 12682
7.39632
7.66083
7.91785
8.17238
8.42691
8.68144
8.92849
9.16804
9.40760
9.64965
9.89669
10.14)74
10. in 1,29
10.625)4
I0.867*>0
Il.0'l4t8
11. 1/406
l|.M8f>6
11.74577
11.91.0 IB
12. 11/49
U.lMoO
li.s-UM
I.'. /Ill 16
I/.976UO
1 1. l«,5f.5
1 1. 3Vi««)
| i. *> \'t'tt>
5I>2 • 2000. fl'H
NO • 150. PPM
02 - 3.i J
M2.D •.... 6.0 < 	
DIFFERENTIAL RATfr
MGK S02/GM 0-HIN tMS
	 1,54713
1.34751
0.99U14
O.R983H
0.798',7
0.69870
0.84650 	 ..
O.B9U30
0.79B54
	 0.79854
0.79H47
0.79854
0.74U66 _
0.84(i76/
0. IS7<,«
0. 14') JS
0. 14IU4
0. 11/71
. . O.JI271
0. llhU7
0. Ul.U'l
0. «>' "'
0. II Ml 1
7CHP • 700.
Fill T.C/C.
H2S04 " 75.55

HttH ICIAU
At ID/ 100 CMS C
0.51581
0.7174t.
0.91705
.06225
.19216
.30679
.42525
.55899
.6889U
.81118
.93345
2.00572
2,17418
2.29645
2.41873
2.53335
2.64416
2.75879
	 .2 ..869,6] 	 	
2.96513
3.06448
3.16383 	
3.25554
3.3)960
_ . 3.4160.2. 	
3.49244
3.568H6
3. 64528
3.7178b
3.86601
4.14966
4.40186
4.64258
4.87566
5.10875
5.33801
5.56345
5.79272
6.01116
6.23978
6.46140
6.68302
6.9008?
7.11098
7.32496
7.54276
7.72999
7.92104
' ,8...UOa5 	
' 8.35665
8.'57063
" 8°". 7807B
" '8.99476
9.20492
9.41506
9.62524
9.83540
10.04173 	
10.24043
10.52119
10.91294
11.32561
11.71064
12.12421
12.51196
12.90370
11.29345 	
13.67174
14.01856
14.40539
14. 77603
15.154H
15.52876
15.89942
16.27005
16.61)04
l6.V.1t>47
I7.JJVJV
17.(.6H'>&
1/.')')0
0.5094/
0.54761)
P. 54770
O.M49S
0.577/7
P.su*).. 7
0. S094'*
0.4H1'I'»
0.4H4U1
0.47U6
U.4U4UI
                   488
-------
          CALCULATION'.. FIIK GKAVlMttKIC  film
IUT-7-6C-4
 .RUN NO.  •   191
     U»U  «   9  2 71
   (IHV nl.-  100.56 HC
CCHKEUlUN*   -6.43 HC
                            S02 •  2000. PPM       ICMP
                            HO *   ISO. PPM       Fit)  »
                            01 *    3.5 t        II2S04  •
                           1120.-	6.Q.I		
                                                     200. DEC. F.
                                                   1500. CC/KIH
                                                   76.20 (
   ..HE AH LOAD
CMS SU2/100  (.MS  C
                      PIFFCHENUAU RATE
                      M(iM !>02/GM C-HIN
                                        MEAN  LOAD
                                    CMS ACID/100 CMS C
                 DIFFtRCNTlAl PATE
                 MOM  ACID/CM C-MIN
3.35629
0. 47011
0.57156
0.66063
0.74476
IJ.B2394
0.89B17
0.96745
1.03425
;.-. 1.10106
1.14312
1.U51B
_ . .. 1.24704
1.30147
1.35143
- .-. 1.40539
1.454BH
1.50189
	 1.54643
1.59097
1.6)796
1.6H499
1.72705
1.76911
. 	 .- . 1.81366
1.65572
1.69283
	 1.92747
1.96459
2.05119
?r 17490
2.29119
2.40748
2.52378
2.64007
2.75141
2.R57B1
2.96421
3.G7U6U
3.39720
3.38216
3.46628
. . 3.58773
3.68917
3.79062
3.BB960
3.96857
4.0B754
4.27006
4.36961
4.46116
4.55518
4.64921
4.74076
4.82963
1.91690
5.C0796
5.14159
S.690H9
S. 117 199
6.05214
6.227H1
6. 564 12
6.71217
7.0b41 1
7.22741
7.3H579
7.54167
7.H64HO
f. 14 1 14
P.H0604
	 1.18762
1.0BB70
0. 94025
. O.B4126
O.B4126
0.74234
0.74226 	 	 _
0.64334
0.69200
0.64334
0.19764
0.64334
0.5918)
0.49489
0.54435
. 0.494B2
0.49439
0.44536
O.44S16
0.44543
0.49402
fl. 44536
0.39590
0.44536
	 	 	 0.44543 	 	 _..
0.39590
0.34636
	 0.34644
0.39590
0.44536
0.37941
0.39587
0.37939
0.39590
0.37939
0.36290
0.34641
0.36290
0.34039
1.63099
0.34641
0.34641
... 0.32990 ... ..
0.34639
0.32993
0.32990
0.32990
0.32990
0-JI 14.?
0.31342
0.'29690
0. '3 1 342
0.31342
0.31342
0.29690
0.29693
0.29690
0.29691
0.29692
0.10516
0.30516
O.U 142
0.296V2
0.29692
0.^(1867
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0.27218
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0.26393
0.27216
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0.2619?
0.26 I'll
0.2556B
0.^.4557
0.719B5
0.87520
1.01159
1.14041
1.26165
1.37532
1.48140
1.58370
1.68600
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1.99288
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2.77715 	
2.64157
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3. (0628
3.14088
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3.50834
3.68646
3.b6453
4.C4260
4.21310
4.37602
4.53894
4.70185
5.20197
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5.04905
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0.68195
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0.68195
0.60622
0.68195
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0.60622
0.53037
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0.60622
0.68195
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0.60618
0.58094
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0.55569
0.53045
0.55569
0.53041 .
2.60370
0.53045
0.53045
0.50516
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0.50520
0.50516
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0.47992
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2.03326
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0.99161
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3.07541
3.26905
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3.64114
3.81199
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4.14232
4.30558 	
4.45746
4.60934
4.76121
4.90928
5.05356
5.18645
5.31174
5.44463
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5.02431
5.95720
6.08629
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8. 17835
8.52386
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9.26424
9.61734
9.96660
10.31216
10.65388
11.07154
11.41324
11.679C2
12.U1694
12.35106
12.68139
12.96514
13.29647
13.63059
13.94572
14.25327
14.55702
14.86076
15.16451
15.46446
15.76061
16.05676
16.49339
17.07051
17.62865
18.16400
10.69176
19.21191
19. F2450
20.2251-8
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3.11343
2.B8551
1.59460
2.65771
2.35413
2.27800
1.97442
1.97431
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1.74651
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1.59472
1.74651
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1.51882
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1.44281
1.44281
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1.29091
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1.11370
1.16438
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0.65810
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0.98717
0.98717
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                               490
-------
         CALCULATIONS FOR GfUVlHtfHIC FLOW
R«f-7-6C-6
RUN NO. - 193
DATE • 9 7 71
I>RY 1.1. • 10?. 82 MG
CLRKECIION- -6.lt) MC
HtAN IUAD
CMS S02/100 CMS C
0.36777
0.49601
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0.7)797
0.85895
0.9(509
I. 06461
1.15172
1.22)76
1.3*719
1.45659
1.55095
1.64290
1.73242
1.81464
1.89454
1. 97661
i. 05907
2.13650
2.20909
2.26409
2.35668
2.426B5
2.49460
2. 56235
2.63252
2.69543
2.7SB33 . .
2.82366
2.95190
i. 14063
3.32210
3. 49673
3.67778
3.66168
4.03831
4.21252 ..
4.39157
4.56578
4.73999
4.91178
5.08115
	 5.25052 	
5. 41990
5.62556
	 S.B2B81 	
6.00302
6.17723
	 6.34902
6. 52124
6.69261
6.86198
7.0313S
7.19589
7.35000
7.51770
7.67497
7.82982
7.9H46H
6.21444
8.51699 .__
8.79524
9.06382
9.34449 _
9.6?0i)
9.6X690
10.15506
1 (>.4IBdO
IC.6H25I
10.94627
ll.2U2r5
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11.70361
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12.6«'I01
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1.25824
1.30653
1.16144
1.20980
1.20980
1.11300
0.67749
1.06463
1.01626
1,01619
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0.91946
0.91446
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0.77422
0.82273
0.82266
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0.725B5
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0.59685
0.59663
0.56456
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0.54844
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	 0.54844 ....
0.58071
0.79041
0.56456 	
0.596*5
0.56456
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0.54646
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0.54U44
0.53232
0.53232
0.51617
0.51619
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0.42746
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0.5631)
0.75951
0.94847
1.13001
1.31526
1.49310
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1.76357
1.92289
2.07850
2.23040
2.37489
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2.65277
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2.90101
3.02699
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3.3e266
3.49752
3.60866
3.71611
3.81985
3.92359.
4.03104
4.12737
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4.32374
4.52010
4.80909
5.08697
5.35743
5.63160
5.91319
6.18365
6.45042
6.72459
6.49134
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7.52116
7.78052
8.03987
8.29922
8.61415
8.92536
9.19213
9.45889
9.72194
9.98670
10.24806
10.50741
10.76676
11.01870
11.26694
11.51147
11.7522V
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12.22653
12.57851
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13.46772
13.87897
14. JOB76
14.73113
15.14238
15.5444*
15.95370
16.35,762
16.76147
17.154?!
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2.00063
1. 77845
1.85251
1.65251
1.7042B
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1.63021
1.55616
1.55604
1.48198
1.40792
1.40792
1.33386
1.18552
1.25980
1.25969
1.25969
1.11146 	
1.11157
1.18552
1.03740
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0.96323
1.11157
1.03740
0.88917
1.03740
0.96334
0.98799
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0.91389
0.88921
	 	 0.93662 	 . ..
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0.71631
0.71631
0.69160
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0.66691
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0.629H5
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                            491
-------
         C4lCUl»IIONi Ft)« GKAVIHllKIt
                                        IHI'tRIMtNl!,
R«T-7-lt-7
RUN Ml. • 194
DAM • 'I 1 71
DRY Hi." 10). JO HG
COHftfU ION* -5. 911 KG
MEAN tO/10
CMS SU2/100 CMS C
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1.45945
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1.64846
1.68195
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1.77287
1.60398 ...
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1.89250
1.97624
2.06237
2.14611
2.22507
2.30402
2.38298
2.45954
2.5)849
2.615C5
2.68444
2.75143
2.82081
2.89020
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3.02418
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3.15337
3.22037
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3.34717
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1.46919
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3.79219
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4.99804
5. 11766
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0.43064
0.43064
0.47854
0.47U47
0.47054
0.52636
0.47847
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0.38282
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	 	 .95268 .. .. .
2.01862
2.06675
2.11022
2.17250
2.2)476
	 2.29340
2.35202
2.4106)
2.46925
2. 52420
2.575»9
2.62312. . ...
2.67075
2. /1471
2.76234 . 	
2.8136)
2.89789
3.C2612 	
3.15801
3.2862)
3.4071) ......
3.52803
3.6489)
3.76617
3.B117C7
4.004)0
4.U054 	
4. 21312
4.319)7
4.42562
4.52820
4. 6307 H
	 4.72969
4.82860
4.9)118
	 	 - 5.0)010 . 	
5.12536
5.22061
5.31220
5.40)79
5.50637
5.60896
5. 70768
5.60679
.... _. 5.90J04
6.0009A
6.14750
... 	 6.))43.4__ 	
6.51752
6.70070
6.89171
7.08905
7.2t>322
7.47006
7.05)24
7.tf)642
8.C2326
8. /lull
».)-»J29
8.57280
8.74866
8.-J20HS
V.Ob'IU
<).2IJ42)
9.4154)
9,1/2'((
4
IU.6IS41
10. Mix, I
10. "1. '.I)
1 1.1 HUH.
. DEC. F.
LC/HIN
i

D1FFERCNT1AL RAT6
MC.M HCIU/uH C-HIN
0.65942
0.65942
0.7)276
0.7)265
0.7)276
0.80600
0.7)265
O.U0600
0.6595)
0.51285
0.58619
0.58619
	 0.65942 	
0.65942
0.29315
0.58619
0.6594?
0.58619
0.58619 	
0.58619
0.58608
0.58619
0.51296
G. 51285
0.4)973 	 ..
0.51285
0.366)8
	 0..58619
0.43961
0.41520
_ 0.4)965
0.4)961
0.41520
. . O.)9079 .. _ .
0.41520
O.)9079
O.)9079 	
0.41520
0.366)S
	 0.34193 .. 	 	 _
O.)4193
0.36638
0.34193
O.)419i
0.34193
O.)1749
0.34193
0.34193
	 O.)l752 . 	
O.)l752
0.31749
0.29311
0.3174S
0.366)8
O.)1752
0. 34193
O.)l749
O.)175?
0.34193
O.M751
0.30530
0.30530
0.)O5)0
0.32973
0.)2973
0.31751
O.)05)3
0.30530
0.305)0
0.31751
0.305)0
0. 105)0
O.?9)0<)
0.29)09
0.28087
0.280S7
O.26H67
0..'6D67
0.25646
0.24424
0..'4424
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0./4424
0. ."*)»')
O.J'i64'.
(<..">646
o..'iiiiur
o./iii'iir
C. .'tiHt*/
                              492
-------
         CALCULATION!!  rim (.RJVIHICRIC  HUH KPCRIMINIi
KT-7-6C-8
RUN Nl). > 19i
U»H • 9 10 71
DRY HT.» 104.70 MC
CURRECIIUN' -5.87 HO
MEAN LUAD
CMS SO// 100 CMS C
0.489 16
0.5H292
0.66689
C. 74165
0.81802
O.BH999
0.9'.,716
1.019%)
1.00190
1. 14187
1.19705
1.24983
1,27861
1. 10740
1.36017
1.41051
I. 4585)
1.50651
1.55681
1.00726
I. 65284
1.6936)
1.7)6111
1. 78478
1.830)7
1.0711%
1.90953
1.95271
1.49829
2.06225
2.20460
2.J2454
2.44449
'2.56444
2.684)8
2. 8019)
2.91948 ..
3.034ft}
3.147)7
3.26252 . 	 ..
3.37527
). 48802
3.60077
3.71352
3.82627
	 3.93902
4.05176
4.16211
	 4.27247
4.38262
4.50036
4. 61551
4.725R&
4.83861
4.9489h
5.0593?
5.16966
5.28001
5.38797
5.54869
5.76460
5.9H290
6.20360
6.42190 . ;._ .
6.6)041
6.84651
7.0'-2H2
7.2S43)
7.45B24
7.hf>451>
7.U/OKI.
8.072)7
II.26-JOI)
8.4W
0.6?4*>0
tl.K 71140
•i.nos:
V.//IX, I
9.4/C"»4
v.M..'tlfi
9.7
10.0I'<4«
ll<./>/Wll
10.41141.'
lU.5l>4Ci
l|i.7M'>r>
ll'.'M4,">
11. 1 .".'.. I
II.//OI*
S02 • 2000. t>t>H
NO » 150. PPM
02 • 3.5 %
H2tl - 6.0 X
01FF[ftf:NTIAL RATE
KCH S02/CH C-MIN CMS
0.95955
0.91160
0.76767
0./6767
0.71965
0.71972
0.62367
0.62374
0.62374
0.57572
0.52777
0.52777
0.04795
0.52777
0.52777
0.47981
0.47974
0.47981
0,52.117.
0.47974
0.4)106
0.38)84
0.47974
0.47981
0.43179
0.3&.)»4
0.}8)b4
0.47974 _..
0.4)186
0.41580
0.399U2
0.39982
0.39982
0.39982 _ . . .
0.39962
O.J8)64
0.39982..
0.36783
0.38384
0.38381 	 - .
0.36783
0.38)84 .
0.3678) 	
0.38)84
0.36783
0.)8384
0.36783
0.367(f3
0.36785 	 	
0.3678)
'0.41500
0.35164
0.3D3H4
0.3678)
0.36765
0.367B3
0.36783
. 0.16783 	
0.351B4
0.359H4
. 0.35VU5. 	 	 _
0. 16781
0.367D4
0.359B4
0. 15184
0. 151114
0.335115
0.3)5i>6
0. I4J84
O..I4 3HS
0. I41U4
0. )2 tan
0.3^7U6
0.343H4
0. )15l)'>
0. 14 *ri5
0. 127(16
0. *2'H4
O.J1906
0.11 'HIS
0. U 1M,
0. U1U6
0. I0)x;
P.."<'jll(>
a.)otvt
Q..'HIHl
0. ,'lt /I) /
O.^'/'/l'M
{l..''l«ll
TEMP • 200.
Fill • 1500.
H2S04 • 76.92

MEAN LOAD
ACIU/100 &Ki C
.' 0.74.9)4
0.89260
.02117
.13872
.25259
.36279
.46565
.56115
.65666
.74B49
.8)298
.91379
.95787
2. 00195
2.08217
2.15991
2.23)37
2.3U6B4
-2.3»39fl . .
2.46112
2.53092
2.593)7
2. 6594(1
2.73295
2.80275 	
2.86519
2.92397
2.99008. 	
3.05988
3.18845
3.37579
3.55945
3.74312
). 92679 	 	
4.11046
4.29045
4.47045
4.64677
4.61941
. .4.99574 	
5.1663d
!>.)4103
..5.51)67 	
5.68632
5.85697
6.03162
6.20426
6.37324
-6.54221
6.71119
6.89118
7.06750
7.23648
7.40912
7.57BIO
7.74708
7.91605
6.08502
8.25032
8.4964)
8.82704
9.16111
9.49926
9.H3)'>4
10. 16047
10.4S372
10.79963
11. Kit A:
11.42044
11.71614
12.05225
12.360K)
l2,t>b2U3
l2.'i(OVI
1 .).<•«, 3 J
13.59506
1 1. /OJl'J
14.204h4
U.502IH
14. Ml.25
15.0Bli44
l'>.SI/-lt,
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|5.»ll II
t6./y6nj
t6.4 ttU'1
II../4 >!.'
l/.i'vl)1'.'
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CC/KIN
I

UlfftRENTIAL RATE
KC.K ACiu/cp C-MIN
- _L. 46932
.395119
.1/550
.17550
.10196
.10207
0. 95499
0.^5511
0.95511
O.tol-,7
0.80814
0.80814
0.07343
0.80814
0.80814
0.7)472
0.73460
0.73472
0.8U814
0.73460
0.66129
0.58775 . ._..
0. 7)460
0.73472
0.66118
0.58775
0.58775
	 0.. 7 3460
O.D6129
0.63670
0.61223
0.6122)
0.61223
.__ 	 0.61223
0.61223
O.D6775
0.61223 	
0.56324
0.56775
	 	 .0.58771 ... 	 	
0.56324
0.58775
0.56324
0.58775
0.56)24
0.5S775
0.56324
0.56324
	 . 0.56327 	
0.56324
0.6)670
0.53676
0.58775
0.56324
0.56327
0.56324
0.56324
0.56324
0.53876
0.55100
0.55102
0.56)24
0.56)26
0.55100
0. 5)876
0.51876
0.51427
0.5142'!
0.5/650
0.526'.2
0.52650
0.5020)
0.50201
0.52650
0.51427
0.52hS2
0.50?C)
O.S020I
0.4H9/9
0.4n'l7f
0.417'.)
0.4/751
C.46MO
0.45104
0.46S30
0.440110
P. 4411 III'
C.4.'H'>7
U.4I611
                            493
-------
          CALCUUUONS FUR GRAVIMtrHIC  FLOM

a«r-7-6C-»

  BUN NO.  •   l">6           SU2 •_ 2000,  PPM  	 TfMP «_  200. PEO.  f.
     OAlf  •   9  14  71       140 «   150.  PPH      Fill *  1500. CC/MIN
   OdY WT.-  100.42 HC      02 •    3.5  *      H2S(K '  75.78 *
*EAN LOAD OlFf EfUNTIAL RATS H6AH LOAD . .. DIFFERENTIAL RATE 	
iKS S02/100 SHS C KGM S02/GM C-MIN CMS ACID/100 CHS C MfcH ACIU/GM C-MIN
n.4tftAq O.49?R590
1.20363
1.24136
1,2790?
1.31305
1.34324
	 1.J7719 _.. 	
1.41493
1.45266
1.4«662
1.52057
1.55453
1.58472
1.61490
1.64836
1.68262
1.71301
1.76582
1.84506
1.93184
2.01862
2.10163
2.18464
2.26387
2.33933
2.414UO
2.49026
._ 	 Z..5657.3 	 	
2.64119
2.71665
2.79212
2.86758
2.94304
3.01850
3.09019
3.16188
3.23357
3.30149
3.36941
3.43732
3.50147
3.56184
3.62590
3.69012
3.75427
3.61841
3.90897
4.03725
4.17309
4^30892
4.44098
4.576BI
4.71642
4.85225
4.98809
5. 12015
5.25598
5.39182
5.92387
5.65593
5.78799
•i.9238)
6.05589
6.18795
6.32001
6.44630
6.57281
t.6'1732
6.82561
6.95)89
7.07841
7.20292
— .. 7.J31Z1.
7.4557?
7.50024
	 7.f04,T6 	 	
0.402/6
0.37734
0.45276
0.45276
0.37/34
0.45276
0.37/34
0.37734
0.45276
0.45276
0.45276
0.37734
0.37V34
0.37734
0,37722
0.30192
0.301110
	 0,37/34 	 	 _.
0.37734
0.37/34
0.301(10
0.37734
0.30180
0.30192
0.30189
0.37734
0.30192
0.30180
0.25156
0.27670
0.30184
0.27670
0,27670
0.27670
0.25152
0.25156
O..O156
0.25152
0.25156 _
0.25152
0.25156
0.25156
0.25152
0.25156
0.25152
0.22643
0.25152
0.22&38
0.22642
0.22638
0.22638
0.20124
0.20124
0.2263B
0.20124
0.22638
0.20124
0.20124
0.22638
0.22640
6.22638
0.21381
0.23B97
0.22640
0.72638
0.22640
0.21381
0.23897
0.21381
0.22638
0.21381
0.22640
0. 22638
0.21383
	 0.226)8
0.21381
0.21381
0.20U4
0.213HI
0.213HI
0.21381
0.20124
0.21381
0.21381
0.20124
0.21381
	 O..2012i 	
                               494
-------
          CALCULATIONS FOR GRAVIMETRIC FLOW EXPERIMENTS
 R»T-7-6C

   RUN  NO.  •
     DATE  •
    DRY UT.»
197	__W>2_'	200p._PPH 	  TEMP »   200. DEC. f_.
91571        NO-   150.>PM""    Tin*1500. CC/HIN
98.30 MG      02  •     3.5  X       H2S04 >   74.7) X
          -.JltQ
     MEAN  LOAD
'CMS  S02/100 CHS C
       _PIFFERENTIALJUTE_
        MGH S02/GK C-MIN
_ _M£AN LOAD
 CMS ACID/100 CM$"C~
 DIFFERENTIAL  RATE
"MGM ACIO/CM C-MIN"
0.58831
0.61299
0.66774
0.70001
0.72980
0.76208
0.79*34
O.B2662
O.B5BB9
. ._0. 88867 .
0.92095
0.95322
. .... 0. 9830.1. _
1.01031
1.03514
.. .... 1.05748-..
1.07982
1.10464
1.15429
1.17663
1.19641.
1.21634
1.2)620
	 	 1.25606 .
1.27592
1.29578
.--1.31812
1.34046
1.36280
, 	 .1.41742
1.47203
1.52664
— .. .1.57811...
1.63090
1.68303
	 1.73268
1.78481
1.83694
... .- -1.88.90J _
1.94368
1.99829
2.10007
2.14972
2.24404
2.29369
2.38802
2.4)767
2.48732
2.53696
2.5B661
2.6)37B
2.68094
2. 72811
2.77031
2.83733
2.93166
	 ).02351_
3.11287
3.20224
3.28912
3.38097
3.475)0
3.56218
3.64658
3.733'.,
).822S)
3.90971
3.99411
	 4.08099 	
4.170)6
4.25972
4.34909
4.4)845
4.5770?
4.62215
4.71648
4.80833
4.90017
4.9H954
5.0764Z
5.16579
5.25763
5.3*203
i.*Z147 ...
0.54612 0.90085 0.83625
0.34757
0.3*7*9
0.29787
0.29795
0.3*7*9
0.29787
0.34757
0.29787
0.297B7
0.34757
0.29787
p. 29787
0.24825
0.24825
0.19B56
0.24825
0.24825
	 _ 0.24818
0.24825
0.19B<>)
0.19846
0.19856
0.19863
3.96927 0.
t.022*B 0.
.07189 0.
.11751 0.
.16693 0.
.2163* 0.
.26575 0.
.31517 0.
.36078 0.
.41020 0.
.45962 0.
.50523 0.
.54704 0.
.58505 0.
.61926 0.
53221
53210
45612
45623
53210
45612
5)221
45612
45612
5)221
45612
45612
)801)
38013
30404
.653*7 0.38013
.69148 0.38013
.72949 0.38002
.76750 0.
.80171 0.
1.8)212 0.
38013
30*15
30404
1.8625) 0.30404
1.89294 0.30415
L. 92)35 - 0.30404
0.19863 1.95376 0.30*15
0.19856 1.98417 0.30*04
O.J4B25 2.01B37 0.38013
0.19856 • 2.05258 0.
0.18204 2.08679 0.
Or|R?G4 2.170*2 0.
30404
27875
27875
0.18204 2.2540* 0.27875
0.18204 2.33767 0.27875
O.16r>5Q 2.41749 0.25342
0.1B204 2.49732 0.
0.16548 2.5771* 0.
0.165SO 2.65316 0.
27875
25338
25342
O.lBiO* 2.7)299 O.iloty
0.16550 2.81281 0.25342
0.18704 2.B9264 0.27875
0.1B202 2.97626 0.
0.18204 ' 3.05988 0.
0.16550 3.13970 0.
0.16550 3.21573 0.
0.16548 3.29175 0.
0.14894 3.36397 0.
0.16550. 3.4)619 0.
0.16550 3.51222 0.
n.l<.R94 3.58444 0.
0.16550 .65666 0.
0.16548 .73268 0.
0.16550 .80870 0.
0.16548 .88472 0.
0.16550 .96075 0.
0.1489* *. 03297 0.
0.16550 4.10519 0.
0.1*B9* 4.17741 0.
0.13240 4.24203 0.
0.15722 4.34466 0.
0.15722 4.48911 0.
0.14894 4.62975 0.
0.1*895 *. 76659 0.
0.1*89* 4.90)42 0.
0.14067 5.03646 0.
0.16549 5.17710 0.
0.14895 5.32154 0.
0-14.067 5.45458 0.
0.14067 5.58383 0.
0.14895 5.71687 0.
0.14894 5.85370 0.
0.14067 5.98674 0.
0.14067 6.1I59B 0.
0.14895 6.24902 0.
0.14894 6.)8Srtft 0.
0.14895 6.52270 0.
0.14U9* 6.65954 0.
0.141195 6.79638 0.
0.14894 6.9)322 0.
0.16549 7.07766 0.
0.141195 7.22210 0.
0.15722 7.36275 0.
0,1*894. 7.50)39 0.
27871
27875
25342
25342
25338
22806
25342
25342
2J58.P.6 	
25342
25338
253*2
25338
253*2
22806
25)42
22B06
20273
2407*
2407*
22806
22808
22806
21539
25)40
22808
2153?
215)9
22808
22806
215)9
21539
22808
22806
22808
22806
22808
22806
25340
22808
24074
22806
0.14895 7.6*02) 0.22808
0.1*067 7.77)27 0.21539
0.15722 7.91011 	 0.2407*
0.14BV4 8.05075 0.
0.132*0 8.17999 0.
.__ 	 0.1)i40. _ 8. 30163 0.
22806
2027)
2027)
                                 495
-------
      CALCULATIONS f(JK ORAVIMETRIC FLOW  EUPtRIMtNTS




C-70-77  TBfATCO HUH 2« NH4UM
HUN NO. • 198 S02 • 2000. PPM TFMP • 200. DEC. F. 	 r 	
OAII: . ~9 16 'll~ NO • 	 150. "»M FITI '• '" 1500. tC/HIN ~
DRY MT.- 103.10 MC O2 * 3.5 X H2S04 • 77.32 *
CO?R£CTlyN« -5.|0 KG H20 « 6.0 *
K£AN LOAp
GUI S02/100 CMS C
0.95503

	


<
-----
"*

-•

	



0.99421
1.0)094
1.06763 	
1.10686
1.14604
1.18767
1.22665
1.2611)
1.29787 ..
1.33950
1.38113
. ..1.40316 ....
1.42031
1.44969
1.48397
1.52071
1.55499
I.5H977
1.62356
1.65784
1.692J2
1.72641
1.75824
1. 79QOB
1.82681
1.86109
-1.H9Z93.
1.97129
2.09128
2*. 1B6Z9
2.27984
2.37290
2.46350..
2.55411
2.64717
2.74022
2.83328
2.92633
3.01918..
3.10999
3.19815
•• 3.38181
3.47731
1.57787
3.66832
3.76628
a. 86 178
3.95728
4.05523
4.15074
4.24624
4.34664
4.44950
4.57438
4.67479
4.75315
4.90498
5.10823
$.31148
5.51473
5.71790
... 5.91879
6.11714
6.31)05
. 6.50651
6.69996
6.89587
7.0942,
7.29502
7.49583
.. 1.69416 _..
7.89009
8.09579
. B. 30)94
8.49739
8.68595
_ B. 87696... _
9.06797
9.2565)
9.44754
9.63854
9.62466
J0.0107I_ _
10.11076
10.221)1
10.J4070 	
DIFFERENTIAL RATE
MGH S02/CH C-HIN
0.39182
0.39182
0.34287
~~ 0.39182
0.39175
0.44084
0.34280
0.34287
0.39182
0.44077
0.39182
Q..04895
0.29305
0.29)85
	 0.39162 	
0.)42B7
0.34280
0.34280
0.342B7
0. 14780
0.34287
0.29)85
0.391 /•>
0.29)92
0.47345
0.32650
0.31019
0.31019
0.31019
0.79185
0.31019
0.31019
0.51019
0.31016
0.31019
0.11019
0.29387
0.29385
0.11019
0.31019
0.32650
O.V1019
0.32650
0.32650.
0.31019
0.32650
0.32650
0.31019
0.32650
0.34285
0.34285
0.48974
0.17958
0.34285
0.3)468
0.3428)
0.33468
0.3428)
0.33466
	 0... J34.de 	 	
0.32652
0.32650
. £.3.10.15 . .
0.32650
0.32652
. . 	 0.33468 . ..
0.31466
0.3)468
	 0.32650. 	
0.32652
0.35416
... 	 0.33466 	
0.31019
0.31835
0.31835 , ,
0.31815
0.31019
0.31019
0.31019
0.11018
0.08979
0.21224
. „ .D.llZil ..
MEAN LOAD
CMS AC ID/ 100 CMS C
1.46239
1.52238
1.57863
1 .63488
1.69488
1.75487
1.81862
1.87861
1.93111
1.98736
2.05110
2.11485
2.14860
2.17484
2.21984
	 2. 27233. _ 	
2.32858
2.38108
2.4)358
2.48607
2.53857
2.59107
2.64356
2.692)1
2.74106
2.797)0
2.84980
2.89855
3.01854
3.20228
3.49101
3.63350
3.77224
3.91098
4.05347
4.19597
4.33845
4.48094
4.62343
4.76218
4.89716
5.03590
5.17840
5.32464
5.47088
5.61712
5.76711
5.91334
6.05959
6.20957
6.35581
6.50206
6.65580
6.81329
7.00453
7.15827
7.27826
7.51075
7.82198
8.13321
8.44444
8.75566
9.06314
9.36688
9.66686
9.96309
10.259)1
10.55929
	 	 10.6630)
11.17050
11.47798
	 	 .11.78171 	
12.08170
12.39666
	 .12.71541 	
13.0116)
13.300)7
	 13.5928*
13.8853)
14.1 7406
. 	 14.46654
14.74902
15.04401
15.12899
15.51272
15.65147
15.84645
DIFFERENTIAL RATE
MCH AC10/CM C-MIN
0.59997
0.59997
0.52502
0.59997
0.59997"
0.59986
0.67504
0.52491
O. 52502
0.59997
0.67493
0.59997
0.07495
0.44995
0.44995
0.59997
0.52502
0.52491
Q. 52502
0.52491
0.52502
0.52491
0.52502
0.44995
0.52502
0.59986
0.45007
0.52491
0.72497
0.49996
Q.47497
0.47497
0.47497
0.44995
0.47497
0.47497
0.47497
0.47494
0.47497
0.47497
0.44999
0.44995
0.47497
0.47497
0.49996
0.47497
0.49996
0.49996
0.47497
0.49996
0.49996
0.47497
0.49996
0.52498
0.52498
0.74992
0.27498
0.52498
0.51247
0.52496
0.51247
O. 52496
0.51245
0.51247 	
0.49998
0.49996
0.48747
0.49996
0.49998
	 0.5124? 	
0.51245
0.51247
	 0-49996 __
0.49498
O.S4997
0.51245
0.47497
0.48747
0.46747
0.48747
0.47497
0.44996
0.47497
0.4749T
0.47496
0.1)749
0.32499
0.324*1
                              496
-------
                        APPENDIX A-18

           LITERATURE STUDY ON SOLVENT EXTRACTION


 A literature survey on the removal of sulfur from carbon" by
 extraction was made.

 The paper by Prchlik,  et al.14  was of particular interest.
 The paper discussed a detailed study based on both literature
 and experimental work of sulfur extraction from spent gas
 works purification mass (iron oxide).   Literature references
 on 10 solvent systems  for sulfur extraction from spent purifi-
 cation mass were given.  Solubility data for sulfur in various
 solvents were given.  These data are shown in the following
 section.  Diagrams of bench scale extraction apparatus and
 proposed commercial equipment are given.   In reviewing various
 solvents and running bench scale tests,  Prchlik,  et al.  reached
 the following conclusions:

      1)  Carbon disulfide,  while an excellent solvent,  is
          discounted due to the-health  and explosion hazards
          inherent in its  handling.

      2)  Chlorinated solvents,  trichloroethylene  and dichloro-
          benzene, were discounted primarily due to cost
          although it was  also mentioned  that trichloroethylene
          will not remove  the  pitch or  naphthalene present in
          the gas being treated.

      3)  Tetralin was  considered an  excellent solvent but was
          discounted because of  expense and difficulty in
          removing it from the purification mass.

      4)  A toluene-xylene mixture was  considered  the best
          solvent in view  of the  requirement to remove pitch
          and naphthalene  as well  as  sulfur to regenerate the
          purification mass.

Ammonium sulfide was not  considered  by the authors,  presumably
because of its  reactivity with  the iron  oxide.

Equilibrium  Data -  Sulfur-Solvent  Systems

      Solubility of  Sulfur in  Ammonium  Sulfide

No extensive  data on the  solubility  of sulfur in  ammonium
sulfide was  found.   Previous  extraction processes  operated
near  room temperature and under  these  conditions  the solubility
was reported  to be  18-2470 by  weight  of sulfur in  solution14'15.
Since the  pressure  of H2S and NH3 were important  for extraction
studies  at higher temperatures  these data  are shown in
Tables A-1B-1 and A-18-2  and  Figure  A-18-1.

                            497
-------
Table A-18-1.
VAPOR PRESSURES OF H2S, NH3,  AND H20
OVER AQUEOUS (NH4)2S SOLUTIONS
Temp . ,
°C
20
20
20
20
20
40
40
40
40
60
60
60
60
NH3,
% by Wt.
1.38
2.68
6.77
8.05
9.41
2.31
5.88
7.21
9.34
3.22
5.54
6.80
9.00
H2S,
% by Wt.
1.40
2.68
6.81
8.03
9.40
2.33
5.86
7.26
9.36
3.25
5.56
6.81
9.05
Vapor Pressure, mm. Hg
H2S
53.3
65.6
130.1
154 . 8
190.0
92.0
183.4
220.5
293.2
134.1
205.0
250 . 9
365.0
NH3
0
0
0
5.6
13.0
8.2
22.2
26.9
30.4
25.5
48.5
76.1
145.0
H20
16.3
16.2
15.8
15.1
14.3
49.1
44.7
48.4
47.9
125.1
127.3
113.5
105.0
Table A-18-2.
VAPOR PRESSURES OF H2S, NH3,  AND H20
OVER AQUEOUS (NH4)2HS SOLUTIONS
Temp . ,
°C
20
20
NH3,
% by Wt.
0.80
2.14
2.97
H2S,
% by Wt.
1.58
4.23
5.93
Vapor Pressure, mm. Hg
H2S
115.7
163.0
197.6
NH3
0
0
0
H20
13.9
15.2
16.1
                       498
-------
Figure A-18-1.


1000
    Equilibrium vapor pressures of hydrogen
    sulfide and ammonia over aqueous
    ammonia solutions at 20°C
                            Hydrogen Sumde
                                 2.On
                                 l.On
                                 0.5
   0
0.2         0.4        0.6        0.8

        Mole H7S/Mole NH  (R)
             £        O

            499
-------
     Solubility of Sulfur in Carbon Disulfide

The solubility of sulfur in carbon disulfide is strongly
dependent upon temperature, reaching 9070 at 98°C.   Data from
the literature on solubility are contained in Table A-18-3  .
          Table A-18-3.
SOLUBILITY OF SULFUR IN
CARBON DISULFIDE
Temp. ,
°F
-110
-100
-90
-80
-70
-60
-50
-40
-30
-20
-10
% Sulfur
in Solution
1.0
1.5
2.0
2.5
3.2
4.2
5.5
7.1
9.5
12.0
15.0
Temp . ,
°F
0
10
20
30
40
50
60
70
80
90
98
7o Sulfur
in Solution
19.0
23.5
30.0
38.5
50.0
60.0
66.0
71.0
78.5
86.0
90.1
     Solubility of Sulfur in Xylene

The solubility of sulfur in meta and para-xylene is up to
21.8% in solution is shown in Table A-18-416.   There is no
solid phase of sulfur in equilibrium with the solution above
21.8% and a liquid-liquid separation occurred.  There was
                            500
-------
        Table A-18-4.  SOLUBILITY OF SULFUR IN XYLENE


     m-Xylene

          Temp.. °C    % Sulfur in Solution
             25                1.969
             45                3.604
             80               10.29

     Rhombic Sulfur-p-Xylene
          % Sulfur in Solution    Equilibrium Temp. , °C
                  11.0                     85.0
                  13.95                    92.5
                  17.85                   100.5

     Monoclinic Sulfur-p-Xylene
          % Sulfur in Solution    Equilibrium Temp., °C

                  16.25                    98.2
                  16.3                     98.0
                  17.85                   103.3
                  20.38                   106.0
                  21.8                    107.0
apparently the formation of amorphous sulfur.  Table A-18-5
gives the solubility results before measurable amounts of
amorphous sulfur were formed.


These data indicate that sulfur and p-xylene are initially
mixcible in all proportions above about 190°C.  However, if
the equilibrium temperature is maintained, reseparation of
liquid phases occurs, probably due to the formation of
                            501
-------
  Table A-18-5.
SOLUBILITY OF SULFUR IN p-XYLENE ABOVE
21% CONCENTRATIONS BEFORE PHASE
SEPARATION
% Sulfur
in Solution
20.38
21.8
25.9
27.95
28.04
30.22
31.95
34.6
34.9
39.9
44.0
Equilibrium
Temp . , °C
94.0
101.0
117.7
124.5
124.2
130.0
137.3
144.5
149.0
158.5
167.0
% Sulfur
in Solution
44.1
45.7
46.3
48.3
61.7
71.2
81.0
85.6
87.9 .
90.0
91.0
Equilibrium
Temp . , °C
167.5
171.0
175.0
175.0
190.0
190.0
184.0
176.0
162.5
150.0
143.0
amorphous sulfur,  resulting in a rise in the temperature
of complete miscibility.   The equilibrium temperatures
finally obtained are contained in Table A-18-6.
       Table A-18-6.
     SOLUBILITY OF SULFUR IN p-XYLENE
     AT ELEVATED TEMPERATURES
70 Sulfur
in Solution
16.25
21.8
25.9
27.8
27.95
29.1
30.22
31.95
34.6
34.9
36.0
Equilibrium
Temp . , °C
80
109.0
121.7
127.0
129.0
132.0
133.7
141.5
148.25
150.0
154.0
70 Sulfur
in Solution
39.9
44.0
44.1
45.7
46.3
48.3
87.9
90.0
91.0
96.2

Equilibrium
Temp. ,°C
165.0
174.5
174.5
179.5
183.5
196.0
177.0
155.0
147.5
84.0

                          502
-------
The equilibrium temperature rises with  sulfur  concentration
below 48.3/o and decreases with  sulfur concentration  above
87.9/0.  There does not appear to be  a maximum, however.  Rather
the low and high concentration  curves appear to be entirely
separate.  The temperatures above which two phases exist and
below which one phase exists are:
            S in Solution,    Equilibrium Temp.,
                 44.0
                 46.3
                 48.3
                 87.9
                 90.0
                 91.0
        235.0
        220.0
        206.0
        187.0
        203.0
        205.0
Smisek and Cerney17 also present data on the solubility of
sulfur in xylene as shown in Table A-18-7.  These data agree
rather well with the literature information in previous tables
              Table  A-18-7.
SOLUBILITY OF SULFUR
IN XYLENE
Temperature,
°C
25
45
85
100
107
Concentration ,
Wt. %
1.73
3.24
10.78
18.8
24.1
                            503
-------
The following equilibrium data as presented in Prchlik's
article!^ are referenced to the original author:

     System:  Sulfur-Benzene18
Temp . , °
25
54
84
C g. S/100 g. Sat
2.074
5.165
13.02
. Soln.



System: Sulfur -Toluene
Soln.
Temp . ,
OF
-10
0
0
13
15.5
20
23
25
35
40
50
54
60
70
80
83.5
90
100
Dissolved g. of S
in 100 g. of
Sat. Solns .
0.576
0.923
0.897
1.545
1.649
1.827
1.889
2.018
2.722
2.35
3.68
4.85
5.27
7.83
11.1
11.64
15.3
20.9


Determined By
Jacek19
Jacek19
Hildebrand-Jenks 18
Delaplace20
Jacek19
Delaplace20
Delaplace20
Hildebrand-Jenks 18
Hildebrand-Jenks L 8
Burden-Newling 2 !
Burden-Newling
Hildebrand-Jenks 18
Bur den - Newl ing 2 ^
Bur den - Newl ing
Bur den- Newl ing2 ^
Hildebrand-Jenks l 8
Bur den-Newl ing •"•
Bur den - Newl ing 2 1
System: Sulfur-p-Xylene22
Temp . , °
85
92.5
98.0
100.5
107.0
117-121
124-129
C g. S/100 g. Sat.
11.9
13.95
16.3
17.85
21.8
25.9
27.95
Soln.







                            504
-------
Bituminous
Pitch Oil Fraction
Temp . B . P .
°C S.G.
15
30
50
80
100
110
120
130
, °C: 80-100
: .87
2.1
3.0
5.2
11.8
15.2
	
	
	
85-120
.88
2.3
4.0
6.1
13.7
18.7
23.0
27.0
	
120-220
.882
2.5
5.3
8.3
15.2
23.0
26.2
32.0
38.7
i i
Coal)zz
by Boiling Point
150-200
.885
2.6
5.8
8.7
21.0
26.4
31.0
38.0
43.8
210-300
1.01
6.0
8.5
10.0
37.0
52.5
105.0
	
	
Range
220-300
1.02
7.0
8.5
12.0
41.0
54.0
115.0
	
	
505
-------
                        APPENDIX A-19
      DETAILED DATA FROM COMBINED SULFUR STRIPPING/H2S
                     GENERATION STUDIES
                                                        Page

1.  Run SHG-1                                            507

2.  Run SHG-2                                            512

3.  Run SHG-3                                            517

4.  Run SHG-5                                            522

5.  Run SHG-7                                            527

6.  Run SHG-8                                            532

7.  Run SHG-9                                            537

8.  Run SHG-10                                           542

9.  Run SHG-11                                           548
                            506
-------
                        RUN SHG-1
A.  EXPERIMENTAL DATA - IJ2.S GENERATION/S STRIPPING

    1.   Virgin Carbon
        a.  % Sulfur (Combustion Anal.), Psc

    2.   Inlet Carbon -
        a.  %, Sulfur (Combustion Anal.), Psi
        b.  Acid Titration, Pvi
        c.  Material Rate, RI
7.
                                               =  0.65%


                                               =  20.70%

                                               =  40.6 Ibs./hr.
    Intermediate
    a.   Stage 8,
    b.   Stage 7,
        Stage 6,
        Stage 5,
        Stage 4,
        Stage 3,
        Stage'2,
        Stage 1,
        c
        d
        e
        f
        g
        h
Stage Carbon
% Sulfur, PS8
% Sulfur, PS7
% Sulfur, Ps6
% Sulfur, PS5
% Sulfur, PS4
% Sulfur, Ps3
% Sulfur, PS2
% Sulfur,
    Outlet Carbon
    a.   %, Sulfur (Combustion Anal.), Pso
    b.   Material Rate, R0
                        /
    Inlet Gas
    a.   % H2 (26.0% by Rota)
    b.   H2 Gas Rate (55% @ 4.3 PSI)
    c.   N2 Gas Rate (25.8% of 640 @ 4.3 PSI)

    Intermediate Stage Gas Analysis

                      H2S  % N2   % SO2  % H20
                                                      15.79%
                                                      37.3 Ibs./hr.
                                                      26.8 Chrom.  %
                                                      66 CFH @ 70°F
                                                      188 CFH @ 70°F
                                                    % CO   % CO2







1
2
3
*j
4
^r
5
«/
6
\*'
7
Outle
a.
b.
c .
d.
e.
f .

g-
h.
7°
10
01
lo
7
10
7
to

7
lo
7
10
21.4
4.1
21.8
1.3
18.1
16.0
15.8
0
0
2
0
6
6
8
t Gas Analys
H2
H?S
N2
SO?
H20
CO

CO?
Sulfur




(as
.88

.96

.0
.2
.4
is




si)
72
70
71
91
71
71
71






.0
.4
.7
.1
.9
.4
.0





i
0
0.3
0
0
0
0
0






0.08
0.56
0
0
0.14
0.49
0.90

=
—
=

=
0
0
0
0
0
0
0
1 ^
16
4
68
6


1







f^ nt
.27o
1%
.3%
f\ Of
.2/0
.3%
f\m
n i
* \J fo
S7
. ~> lo
0.04
0.05
0.04
0.04
0.04
0.05
0.10






                           507
-------
 8.
        Temperature
          Stage  Carbon/Gas, °F

            1
            2
            3
            4
                                     Stage  Carbon/Gas,°F
                  768/800
                  111/
                  781/800
                  778/
                                  5
                                  6
                                  7
                                  8
801/806
799/
---/801
734/
  9.
        Cyclone Product
        a.   Sulfur                     =
        b.   Material Rate              =
        c.   7o Material +40 Mesh
        d.   % Material -40 Mesh

B.   SULFUR MATERIAL BALANCE,  SULFUR REMOVAL, AND H2S CONVERSION
  1.  Run Start
 3

 4,

 5.

 6.

 7.


 8.

 9.
10.

11.
12.

13.
     Run Times
         Run Time
         Steady State Period
         Inlet Carbon Analysis
         Outlet Carbon Analysis
Inlet Sulfur Loading,
Outlet Sulfur Loading, PSQ

Inlet Material Rale, Rsi
Outlet Material Rate, RSo
Cyclone Sulfur Loading, P
                                           -1680-1690
                                          1680-1890
                                          1720-1890
                                          1647-1817 (-73 tnin)
                                          1776-1946 (+56 rain)

                                          20.70%
                                          15.79%
                                          40.6 Ibs./hr.
                                          37.3 Ibs./hr.
                                 scy
        Cyclone  Material  Rate,  RSCy    =  0.0055 Ibs./hr.
        Gas  Rate In,  qT                =  254 CFH @ 70°F
        N2 Rate  In,  q^2                =  188 CFH @ 70°F
        H2 Cone.  In,  100
        112 Cone.  Out,  100

H2S Cone. Out, 100

S02 Cone. Out, 100 ygo

1120 Cone. Out., 100 (yH2o)o

CO Cone. Out, 100 YcOo
C02 Cone. Out, 100 (vr)
                    " ^

Sulfur Vapor Out, RSVO
                                 O
          negligible
          in balance
                            508
-------
                                               GAS AND CftRBON  rLOW RATES
                                                                                                      j g- - r.?

^—f- -
p _
r
•«=:,-•>, NOTTS'


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GAS PLOW RAT^^
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fiR

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                            RUN SHG-2


A•   EXPERIMENTAL DATA - H2S GENERATION/S STRIPPING

    1.   Virgin Carbon
        a.  % Sulfur (Combustion Anal.), PSC       =

    2.   Inlet Carbon - Precursor C-72-108 - Act.  (0.598)(10~3)
        a.  % Sulfur (Combustion Anal.), Psi       =  20.31%
        b.  Acid Titration, Pv£                    -
        c.  Material Rate, Ri                      =35.1  Ibs./hr

    3.   Intermediate Stage Carbon
        a.  Stage 8, % Sulfur, Ps3
b.
c .
d.
e .
f.
g-
h.
Stage
Stage-
Stage
Stage
Stage
Stage
Stage
7,
6,
5,
4,
3,
2,
1,
7
/o
7
/o
7
/o
7
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7
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7
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7
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Sulfur,
Sulfur,
Sulfur,
Sulfur,
Sulfur,
Sulfur,
Sulfur,
PS7
PS 6
PS 5
PS4
PS3
PS2
PSI
    4.   Outlet Carbon
        a.   % Sulfur (Combustion Anal.), Pso       =   4.85%
        b.   Material Rate,  Ro                      =29.1 Ibs./hr.

    5.   Inlet Gas
        a.   % H2 (29.3% by Rotameter)              =  32.0 Chrom. %
        b.   H2 Gas  Rate (57 RRx1.1 FF =   3 PSI)  =  67 CFH @  70°F
        c.   N2 Gas  Rate (41% of 360 @ 3 PSI)       -  162 CFH @ 70°F

    6.   Intermediate Stage  Gas Analysis

          Stage  %  H2   %Jt2_S  % N2   % SO2  % H20  % CO   % CQ2


                                       0.1   0.52     0    0
                                       00        00
                                       0     0.25     0    0
                                       00        00
                                       0     0.41     0    0.05
                                       0     0.61     0    0.1

    7.
                                                      10.0%

                                                      6S'.570

                                                       8.5%
                                                       0
                                                       1.25%
                                                       5.5%
                              512






1
2
3
4
5
6
7
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a .
b.
c .
d.
e .
f .
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h.
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%
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7
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H?.S
N2
SOy
H20
CO
C02
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24.
24.
21.
13.
10.
8
7
2
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4.
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16.
sis







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0
4
1
9








73.3
72.8
74.3
74.6
71.2
73.3








SD
-------
8.   Temperature
      Stage  Carbon/Gas, OF
        1        942/997
        2        970/
        3        982/997
        4        967/

9.   Cyclone Product
    a.  Sulfur
    b.  Material Rate
    c.  % Material +40  Mesh
    d.  % Material -40  Mesh
                                       Stage  Carbon/Gas,°F
                                         5
                                         6
                                         7
                                         8
                                        1001/997
                                         970/
                                         —7970
                                         840/
                                       =  3131  (Start
B •   SULFUR MATERIAL BALANCE, SULFUR REMOVAL, AND H2S CONVERSION

    1
 3


 4

 5

 6


 7


 8

 9

10

11
12

13
Run Start

Run Times
a.   Run Time
b.   Steady State Period
c.   Inlet Carbon Analysis
d.   Outlet Carbon Analysis

Inlet Sulfur Loading, Psi
Outlet Sulfur Loading, PSo

Inlet Material Rate, Rsi
Outlet Material Rate, RSO
Cyclone Sulfur Loading, P
                                       3131  (Started C  at
                                             Feeder +95 min)
                                       3226-3408
                                       3262-3408
                                       3167-3313
                                       3326-3472

                                       20 . 31%
                                       4.85%
                                       35.1  Ibs./hr.
                                       29.1  Ibs./hr.
                                                     (+36)
                                                     (-95)+36
                                                     (+64)+36
                                 scy
                                                %
                                                 °
                                                ;./hrj
Cyclone Material Rate, Rscy    =   0.0033  Ibs

                               =   162  CFH @ 70°F

                               =   32.0 vol. %
                                                       negligible
        Gas Rate In,
        N2 Rate In,
        H2 Cone. In, 100
        H2 Cone. Out, 100
               100
              Out,

              Out,  100 yso

              Out,  100

             Out,  100
              Out,  100
        H2S Cone

        S02 Cone

        1120 Cone

        CO Cone.
        C02 Cone

        Sulfur Vapor Out, RSvo
                               513
-------
             Ss
                      33 ai-
                                                      GAS  AND CARBON FLOW RATES
                                 TYP£
                                        NO.
H',tt.  Pr^ss.
De.-jsit;/;   3-5
 - Prccsure at Outlet, cf ?.ol&=eter Read at N2 Hotaacter Outlet;   App. - Ga.-. F.'ov
6 - K2 Ficv for Lever Carton Seal Leg;   LTA-101 - Ng Flow for Upper Carbon Se> 1 :
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                                                                    GAS  ANALYSIS
                                                                                                                               4" OIA. REGENERATOR
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r.9055 REFERENCES;
•1BD
II^HtllVilVi^i'^*-1
1 ftZ - C,:**?:•„'•* a* •-••e --c f.'.'-i: •-:: c":.-<-~.l ' i
;
i
kn qp
1 ! : ! • ! i • i ill 1
1 • • i i i 1 i i
0 aog.rn',To:~p<: 1i« 'i5« cii |»i» rc"C> -!«•—•- ;?•>! "rf ire' 1 «>•»»' 'to i ' ' <"»a
J 1
s icftrr
V.
t.o| | ^'^
S-4!


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?Jo I'll ;?'"! »7"'/r'- 7' -J5" .^tr '?>: ''~o ••»:'?:'-' «•<•.-. ' «-"^"c7^i ! '/j?7
y^-^rn 	 i 	 rj— 	 V— ! 	 77-^ 	 J7-U- 	 i 	 j 	 ^ 	 1 	 ! 	 i 	

J ! .
'ft-. i??o We •?/•!.'
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•raturvi.
L'zjf.a.j&i
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1 • • . • 1 ! ! i :
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fcf&'iTf £Vc'f7o ff> {c-s/se*1;?* •&'-,-: '.r- T/:'- ' HV i--" ' ' ' "VJo
?9"'?A2J S5J /a,-r'-H- .r~J./c«>";«j !f.o "•."•?•:- 'W1 1 ?5>' ^^ '' ' i •=• ^^ I
(iiitaMi ISSP-IcSJ'?'!-''^ ^c 'Sw :?r Emit.
-------
                            RUN  SHG-3


A.  EXPERIMENTAL DATA - H2S GENERATION/S STRIPPING

    1.  Virgin Carbon
        a.  7o Sulfur (Combustion Anal.), PSC

    2.  Inlet Carbon -
        a.  7. Sulfur (Combustion Anal.), Psi       =   20.35%
        b.  Acid Titration, Pv±                    =
        c.  Material Rate, R±                      =30.9  Ibs./hr.

    3.  Intermediate Stage Carbon
        a.  Stage 8, 7. Sulfur, Ps8
b. Stage 7, 70 Sulfur, PS 7
c. Stage 6, 7o Sulfur, P$6
d. Stage 5, 7» Sulfur, PSS
e. Stage 4, 7. Sulfur, PS4
f. Stage 3, 7> Sulfur, Ps3 =
g. Stage 2, 7o Sulfur, Ps2
h. Stage 1, 7. Sulfur, PSI
4. Outlet Carbon
a. 7o Sulfur (Combustion Anal.), Pso = 2.8270
b. Material Rate, Ro =23.85 Ibs./hr.
5. Inlet Gas
a 70 H2 (27.2% by Rotameter) = 29.870
b H2 Gas Rate (4570 Scale, Assume 1.1 PSI) = 52 CFH @ 70°F
c. N2 Gas Rate - = 139 CFH <§ 70°F
6. Intermediate Stage Gas Analysis
Staee % H? 70 H?S 7. N? 7. SO? 7» H?0 70 CO 7o C02





1
2
A
H
e:
3
ft
D
7
7. Outlet
a.
b.
c.
d.
e .
f.
g.
h.
7
10
7
10
7
10
7»
7
10
7
/O
7
10
21
3
22
21
19
^^ ^
13
5
Gas
H2
H2S
N2
S02
H20
CO
.2
.6
.6
.2
.7
.8
.7
Analys






C02
Sulfur (as
0 73.3 0
0 72.4 0.27
0 75.0 0
2.9 74.0 0
2.4 76.0 0
4.0 74.8 0
16.1 76.1 0
is






si)
0 0
0.63 0
0.002 0
0.16 0
0.22 0.2
0.48 0.04
0.48 0

3
15
70
0


— 1
8
0
0
0
0
0
0
0.08

.17.
.270
.77o
no/
.9/0
y\ frt
.8/0
,070
                              517
-------
8.   Temperature
      Stage  Carbon/Gas,  °F

        1
        2
        3
        4
                                       Stage  Carbon/Gas,°F
                   1130/1203
                   1168/
                   1178/1200
                   1147/
5
6
7
8
1147.1205
1115 /
 — /1192
 914
    9.  Cyclone Product
        a.   Sulfur                     —
        b.   Material Rate              =
        c.   % Material +40 Mesh
        d.   % Material -40 Mesh

B.   SULFUR MATERIAL BALANCE,  SULFUR REMOVAL,  AND H2S CONVERSION

                                       =  3442
                                       -   3442-3670
                                       =   3483-3670 (+41)
                                       =   3375-3562 (-108)+41
                                       =   3555-3742 (+72)+41

                                       =   20.35%
                                       =   2.82%

                                       =   30.9 Ibs./hr.
                                       =   23.85 Ibs./hr.


                                       =   0.0066 Ib./hr.
                                       =   203 CFH @ 70°F
                                       =   148 CFH @ 70°F

                                       =   29.8 vol. %
                                       =   3.08 vol. %

                                       =   15.22 vol. %
1.
2.


3.
4.
5.
6.

7.
8.
9.
10.
11.
12.
13.
Run Start
Run Times
a . Run Time
b. Steady State Period
c. Inlet Carbon Analysis
d. Outlet Carbon Analysis
Inlet Sulfur Loading, Psi
Outlet Sulfur Loading, PSO
Inlet Material Rate, Rsi
Outlet Material Rate, RSo
Cyclone Sulfur Loading, Pscy
Cyclone Material Rate, Rscy
Gas Rate In, qT
N2 Rate In, q^2
H2 Cone. In, 100 (yHo)i
H2 Cone. Out, 100 (yp^'
H2S Cone. Out, 100 (yH2S)o
S02 Cone. Out, 100 yso
H90 Cone. Out, 100 (yj-^O^o
CO Cone. Out, 100 YCOO
C02 Cone. Out, 100 (yrno)
" \*\J 2. o
Sulfur Vapor Out, RSVO
                                       =   0
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                                          0
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                              518
-------
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COLUMN TEMPERATURES. PRESSURES. AND  PRESSURE  DROPS
                                                             RUN NO'
                                                             DATE
                                                                    2. FEB 7J
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-------
                           RUN SHG-5


A.  EXPERIMENTAL DATA - H2S GENERATION/ S STRIPPING

    1 .   Virgin Carbon
        a.  % Sulfur (Combustion Anal.), PSC       =

    2.   Inlet Carbon -
        a.  % Sulfur (Combustion Anal.), Psi       =   19.78%
        b.  Acid Titration, Pvj_                    =
        c.  Material Rate, RI                      =30.9  Ibs./hr.

    3.   Intermediate Stage Carbon
        a.  Stage 8, % Sulfur,  PS8
b.
c .
d.
e.
f.
g-
h.
Stage
Stage
Stage
Stage
Stage
Stage
Stage
7,
6,
5,
4,
3,
2,
1,
7
/o
7
to
7
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7
/o
7
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7
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Sulfur,
Sulfur,
Sulfur,
Sulfur,
Sulfur,
Sulfur,
Sulfur,
PS7
PS 6
?S5
PS4
PS3
PS2
PSI
        Outlet Carbon
        a.   % Sulfur (Combustion Anal.),  Pso       =    4.91%
        b.   Material Rate,  Ro                      =25.1 'Ibs./hr.

        Inlet Gas
        a.   % H2 (10.3% by Rotameter)               =    5.4 Chrom.  %
        b.   H2 Gas Rate  (20 CFH x 1.1)              =22 CFH @ 70°F
        c.   N2 Gas Rate  (48.5% x 360 x 1.1)         =   192 CFH @ 70°F

        Intermediate Stage  Gas  Analysis
          Stage  % H2   % H2S  % N2   % S02  % H20  % CO    % CO 2
1
2
3
4
5
6
7
4.0
0.5
	
0.5
	
0
	
0
0
	
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1.6
	
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79
—
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—
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0
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0
	
0
0.05
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0
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0
0.05
— — .— —
0
	 —
0.01
	
        Outlet  Gas  Analysis
        a.   % H2                                          0
        b.   % H2S                                   =    3.0%
        c.   % N2                                    =   88.0%
        d.   % S02                                   =    0.07
        e.   % H20                                   =    5.4%
        f.   % CO                                    =0
        g.   % C02                                   =    1.4%
        h.   % Sulfur  (as  Si)


                             522
 'o

ro
-------
    8
     Temperature
       Stage  Carbon/Gas,  °F
                                       Stage  Carbon/Gas,°F
            1
            2
            3
            4
                 1144/1212
                 1169/
                 1179/1204
                 1140
5
6
7
8
1170/1208
1139/
 ---/1201
 951/
    9.   Cyclone Product
        a.   Sulfur                     =
        b.   Material Rate              =
        c.   % Material +40 Mesh
        d.   % Material -40 Mesh

B.   SULFUR MATERIAL BALANCE, SULFUR REMOVAL, AND H2S CONVERSION
 1

 2
 3.


 4.


 5.


 6.


 7.


 8.

 9.

10.

11.

12.

13.
        Run Start

        Run Times
        a .   Run Time
        b.   Steady State Period
        c.   Inlet Carbon Analysis
        d.   Outlet Carbon Analysis

        Inlet Sulfur Loading, Psi
        Outlet Sulfur Loading, PSO

        Inlet Material Rate, Rsi
        Outlet Material Rate, RSO
        Cyclone Sulfur Loading, Pscy
        Cyclone Material Rate, Rscy

        Gas Rate In, qj
        N2 Rate In,
        H2 Cone. In, 100
        Ha Cone. Out, 100 (yH2;o

        1I2S Cone. Out, 100 (yH2s)o

        S02 Cone. Out, 100 yso

        H20 Cone. Out, 100 (yH20)o

        CO Cone. Out, 100 YCOO

        C02 Cone. Out, 100 (yc02>o

        Sulfur Vapor Out, RSVO
 3784
 3784
 3865-4135  (+41)
 3760-4027  (-108)+41
 3940-4207  (+72)+41

 19.787o
 4.91%

 30.9 Ibs./hr.
 25.1 Ibs./hr.
 201 CFH @ 70°F
 190 CFH @ 70°F

 5.4 vol. %
 0

 3.0 vol. %

 0.08 vol. %

 5.40 vol. %

 0

 1.40 vol. %
                              523
-------
GAS AND CARBON FLOW RATES
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-------
                                                                       GAS ANALYSIS
                                                                                                                              4" DIA. REGENERATOR
                                                                                                                              RUN NO.
                                                                                                                              EL£J_
                                                                                                                              DATE
                                                                                                                                      -6-r.r
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CARSON SPECIFICATIONS;
  TYPE     	
  SKID NO.
                                         SAMPLE NOT
DATE


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8-4 '
! 4-12 !
OPERATOR


112-5 !
                                                                                                                         READ AND UNDERSTOOD  \-

-------
                                                                                                                   4 D'A.
Ui
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                                            , COLUMN TEMPERATURES.  PRt .SSURES.  AND  PRESSURE  DROPS

	       CARBON SPECIFICATIONS:
~~~        TYPE     	
  ~        SKiDNO   	
           SAMPLE NO	
DATE



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4-12
12-8
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                                                       B*o»; TI
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                                IfIA 1-g .
                                         » «t Cariut C«al*r but.
-------
                              RUN  SHG-7


A.  EXPERIMENTAL DATA  -  H2S  GENERATION/ S STRIPPING

    1.  Virgin Carbon
        a.  % Sulfur  (Combustion Anal.), PSC       =
                        Precursor C-72-108                     0
    2.  Inlet Carbon  -  Act.  0.701(10-3); stg. 5 Act. 0.576(10-3)
        a.  7, Sulfur  (Combustion Anal.), Psi       =  20.16%
        b.  Acid Titration,  Pvi
        c.  Material  Rate, Ri                      =30.9  Ibs./hr.

    3.  Intermediate  Stage Carbon
        a.  Stage  8,  7, Sulfur,  Ps8                 =  17.727,
        b.  Stage  7,  % Sulfur,  PS7                 =   6.5670
        c.  Stage  6,  °/0 Sulfur,  PSG                 =   4.847,
        d.  Stage  5,  7, Sulfur,  Ps5                 =   4.447o
        e.  Stage  4,  °L Sulfur,  PS4                 =   3.327o
        f.  Stage  3,  7» Sulfur,  Ps3                 =   3.207,
        g.  Stage  2,  7, Sulfur,  PS2                 =   3.207,
        h.  Stage  1,  7o Sulfur,  PS1                 =   2.327,

    4.  Outlet Carbon
        a.  70 Sulfur  (Combustion Anal.), PSo       =   2.87,
        b.  Material  Rate, R0                      =  25.0  Ibs./hr.

    5.  Inlet Gas
        a.  7o H2 (35.87,  by Rotameter)               =  37.77o
        b.  H9 Gas Rate  (5.7  CFH x 1.1)             =63  CFH @ 70°F
        c.  N2 Gas Rate  (307,  x  360 x  1.05)          =  113 CFH @ 70°F

    6.  Intermediate  Stage Gas  Analysis
          Stage  % H2    7, H2S  7, N2   7, S02  7, H20  7, CO   % C02

            1
            2
            3
            4
            5
            6
            7

    7   Outlet Gas Analysis
        a.  7, H2                                    =   5.2%
        b.  7, H2S                                   =  18-6,4
        c.  % N2                                    =  6^-7/0
        d.  % S02                                   -   0
        e.  7, H-20                                   =   °-4/0
          .   o                                              „.
        g.  7, C02                                   =   1'7/0
        h.  % Sulfur  (as  Si)

                               527
-------
8.
        Temperature
          Stage  Carbon/Gas, °F
            1      1135/1210
            2      H75/
            3      1180/1207
            4      1192
                                   Stage  Carbon/Gas,°F
                                     5       1198/1222
                                     6       1025/
                                     7        — /1192
                                     8
                                               910/
9.
        Cyclone Product
        a.   Sulfur                     =
        b.   Material Rate              =
        c.   7o Material +40 Mesh
        d.   70 Material -40 Mesh

B.   SULFUR MATERIAL BALANCE,  SULFUR REMOVAL, AND H2S CONVERSION
1.   Run Start

2.   Run Times
    a .   Run Time
    b.   Steady State Period
    c.   Inlet Carbon Analysis
    d.   Outlet Carbon Analysis
 3

 4,

 5.

 6.

 7.


 8.

 9.
10.

11.
12.

13.
    Inlet Sulfur Loading,  Psi
    Outlet Sulfur Loading,  PSO
    Inlet Material Rate,  Rsi
    Outlet Material Rate,  RSO
    Cyclone Sulfur Loading,  Pscy
    Cyclone Material Rate,  Rscy
    Gas Rate In,  qT
    N2 Rate In,

    H2 Cone.  In,  100
    H£ Cone.  Out,  100
    H2S  Cone.  Out,  100 (yH2S>o

    S02  Cone.  Out,  100 yso

    H20  Cone.  Out,  100 (yH2o)o

    CO Cone. Out,  100 ycOo
    C02  Cone.  Out,  100 (yc02)o

    Sulfur Vapor  Out,  RSVO
                                           3673
                                           3673-3784
                                           3714-3784  (+41)
                                           3606-3676  (-108)+41
                                           3786-3856  (+72)+41

                                           20.16%
                                            2.80%
                                           30.9 Ibs./hr.
                                           25.0 Ibs./hr.
                                           201 CFH @ 70°F
                                           133 CFH @ 70°F

                                           37.7 vol. 7o
                                            5.20 vol. 70

                                           18.65 vol. 7o

                                           0

                                           6.55 vol. 70

                                           0
                                           1.66 vol. 7o
                         528
-------
                                      GAS AND CARBON "LOW RATES
                                                                                                         PUN NO  5
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-------
                                                                     GAS ANALYSIS
                                                                                                                         PATE
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        CROSS'REFERENCES:
                                        TYPE
                                        SK!D NO.
                                        SAMPLE NO.
DATE SHIFT



8-4
4-12
12-8
OPERATOR



-------
                                                                                                        4 PIA REGENERATOR
                                       COLUMN  TEMPERATURES.  PRESSURES.  AND PRESSURE  DROPS
                                                                                                        RUN NO.
                                                                                                        FEED
                                                                                                        DATE
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-------
                            RUN SHG-8


A.  EXPERIMENTAL DATA - H2S GENERATION/S STRIPPING

    1.  Virgin Carbon
        a.  70 Sulfur (Combustion Anal.), Psc       -

    2.  Inlet Carbon -
        a.  % Sulfur (Combustion Anal.), Psi       =   50.8%
        b.  Acid Titration, Pvi
        c.  Material Rate, RI                      =25.2  Ibs./hr.

    3.  Intermediate Stage Carbon
        a.  Stage 8, % Sulfur, Ps8                 =   4.76%
        b.  Stage 7, % Sulfur, PS7                 =   4.88%
        c.  Stage 6, % Sulfur, Ps6                 =   3.72%
        d.  Stage 5, % Sulfur, PSS                 =   	
        e.  Stage 4, % Sulfur, PS4                 =   3.40%
        f.  Stage 3, % Sulfur, Ps3                 =   3.12%
        g.  Stage 2, % Sulfur, PS2                 =   3.04%
        h.  Stage 1, % Sulfur, PSI                 =   3.56%

    4.  Outlet Carbon
        a.  % Sulfur (Combustion Anal.), Pso       =   2,90%
        b.  Material Rate, Ro                      =24.9  Ibs./hr.

    5.  Inlet Gas
        a.  % H2  (35.8% by Rotameter)              =   36.7%
        b.  H2 Gas Rate  (57 CFH @ 54 x  1.1 FF)      =   63  CFH @ 70°F
        c.  N2 Gas Rate  (30% x 360 x 1.05)         =   113 CFH @ 70°F

    6.  Intermediate Stage Gas Analysis
          Stage  % H2   % H2S  % N2   % 502   % H?0  % CO   % C02

            1
            2
            3
            4
            5
            6
            7     23.1     2.6   69.4      0     0.42    0.01     0

    7.  Outlet Gas Analysis
        a-  % H2                                   =   27.7%
        b.  % H2S                                  =    2.64%
        c.  % N2                                   =   69.4%
        d.  % S02                                  =    0
        e.   % H20                                  =    0.41%
        f.   % CO                                   =    0.017.
        g.   % C02                                  =0
        h.   % Sulfur (as  Si)
                             532
-------
 8.   Temperature
       Stage  Carbon/Gas,  °F
         1
         2
         3
         4
                   1132/1210
                   1168/	
                   1178/1200
                   1150/	
Stage  Carbon/Gas,°F
  5       1178/1210
  6       1178/	
  7       	/1208
  8
 9.
        Cyclone Product
        a.   Sulfur
        b.   Material Rate
        c.   % Material +40 Mesh
        d.   % Material -40 Mesh

B.   SULFUR MATERIAL BALANCE, SULFUR REMOVAL, AND H2S CONVERSION
 1.  Run Start

 2.  Run Times
     a.  Run Time
     b.  Steady State Period
     c.  Inlet Carbon Analysis
     d.  Outlet Carbon Analysis

 3.  Inlet Sulfur Loading, Psi
     Outlet Sulfur Loading, Pso
    4

    5

    6
 8.

 9.

10.

11.
12.
     Inlet Material Rate, Rsi
     Outlet Material Rate, RSo
     Cyclone Sulfur Loading, PScy
     Cyclone Material Rate, Rscy
     Gas Rate In, QT
     N2 Rate In, QN2

     H2 Cone. In, 100
     H2 Cone. Out, 100
        H2S Cone.  Out,  100 (yH2s)o

        S02 Cone.  Out,  100 ySo

        H20 Cone.  Out,  100

        CO Cone.  Out,  100
        C02 Cone.  Out,  100
                                            4172  (Started Feed from
                                                             SHG-5)
                                            4172+108 = 4280+40 = 4320
                                            4280-4457
                                            4320-4457  (+41)
                                            4212-4349  (-108)+41
                                            4392-4529  (+72)+41
    25.2 Ibs./hr.
    24.9 Ibs./hr.
    176 CFH @ 70°F
    113 CFH @ 70°F
13.   Sulfur Vapor Out, RSvo
                           533
-------
                                                                        GAS  AND  CARBON FLOW  RATES
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-------
                                                                     GAS  ANQLYSIS
                                                                                                                            4" DIA. REGENERATOR
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                                           COLUMN  TEMPERATURES.  PRESSURES. AND PRESSURE DROPS
                                                                                                                RUN NO,_S//S.- 8
                                                                                                                DATE  "S/3//3
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DATE



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8-4
4- 12
12-8



                                                                                                            3EAD AND
                                                      ipi  TI -
-------
                            RUN SHG-9


A.  EXPERIMENTAL DATA  - H2S GENERATION/S  STRIPPING

    1.  Virgin Carbon
        a.  % Sulfur  (Combustion Anal.),  Psc

    2.  Inlet Carbon  -
        a.  % Sulfur  (Combustion Anal.),  Psi       =   20.12%
        b.  Acid Titration, Pvi
        c.  Material Rate, RI                       =30.9 Ibs./hr
Intermediate
a .
b.
c .
d.
e.
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6,
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Sulfur,
Sulfur,
Sulfur,
Sulfur ,
PS8
PS?
PS6
PS5
PS4
PS3
PS2
PSI
    4.  Outlet Carbon
        a.  J0 Sulfur  (Combustion Anal.),  PSo      =   2.64%
        b.  Material Rate,  Ro                      =24.6 Ibs./hr.

    5.  Inlet Gas
        a.  % H2 (26.2% by  Rotameter)              =   27.3%
        b.  H2 Gas Rate (48 CFH  x 1.1)             =5.3 CFH @ 70°F
        c.  N£ Gas Rate (37.6 x  360 x 1.1)         =   149 CFH (§ 70°F

    6.  Intermediate Stage  Gas Analysis
                 % H2   % H2S  % N2   % SO2  % H20  % CO   % CO2
1
2
3
4
5
6
7 5.9 14.2 76.4 0 0.5
0
                                                             0.1
        Outlet  Gas Analysis
        a.  % H2                                   -     3.
            b°l UiC                                  =    J.J . U/o
            /o H2^                                       71  7<»
        r   "/ No                                   =    /I. //o
        S'  7 qn->                                  =    0 • °°77o
        O.  /o C)U^                                       c -no/
        e.  % H20                                  =    ^
        f.  % CO                                        "
        g.  % C02
        h.  % Sulfur  (as  Si)
                               537
-------
    8,
     Temperature
       Stage  Carbon/Gas, °F
            1
            2
            3
            4
                1140/1210
                1173/
                1186/1195
                1165/
Stage  Carbon/Gas,°F
  5      1187/1202
  6      1164/
  7      	/1197
  8       918/
        Cyclone Product
        a.  Sulfur
        b.  Material Rate
        c.  % Material +40 Mesh
        d.  % Material -40 Mesh
B.   SULFUR MATERIAL BALANCE, SULFUR REMOVAL, AND H2S CONVERSION
 1.  Run Start

 2.  Run Times
     a.  Run Time
     b.  Steady State Period
     c.  Inlet Carbon Analysis
     d.  Outlet Carbon Analysis
 3


 4

 5

 6


 7


 8.

 9.

10.

11.
12.

13.
        Inlet Sulfur Loading,  Psi
        Outlet Sulfur Loading,  PSo
        Inlet Material Rate,  Rsi
        Outlet Material Rate,  RSo
        Cyclone Sulfur Loading,  Pscy
        Cyclone Material Rate,  Rscy
        Gas Rate In, qT
        N2 Rate In,
        H2 Cone.  In,  100
        H2 Cone.  Out,  100
        H2S Cone.  Out,  100 (yH2s)o

        S02 Cone.  Out,  100 yso

        H20 Cone.  Out,  100

        CO Cone.  Out,  100
        C02 Cone.  Out,  100

        Sulfur  Vapor Out,  RSvo

                                            4469  (Started SG-85C)
     4577-4718
     4618-4718  (+41)
     4510-4610  (-108H41
     4690-4790  (+72)+41

     20.12%

     30.9  Ibs./hr.
     24.6  Ibs./hr.
     201  CFH  @  70°F
     149  CFH  @  70°F
                              538
-------
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-------
T3AS  AN/ LYSIS
4" DIA.  REGENERATOR,
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                                                                                                                                    •a" D:A. RECENERATQR
                                                  COLUMN  TEMPERATURES.  PRESSURES.  AND  PRESSURE  DROPS
                                                                                                                                        NO.
                                                                                                                                      - 3>j^ - •
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              REFERENCES:
                                                SPECIFICATIONS:
TYf




SAMPLE NO
                                                                                          DATE
                                                                                                               OPERATOR
                                                                                         S. Fes. 7 3     4-12
                                                        I-j»*r >a)e»t»» b* C*li^( 9nd It*** lmb>ri
                                                                                                                             j R^AO AND
-------
                            RUN SHG-10
A.  EXPERIMENTAL DATA - H?,S GENERATION/ S STRIPPING

    1 .   Virgin Carbon
        a.  7o Sulfur (Combustion Anal .), Psc       =   0.65%

    2.   Inlet Carbon -
        a.  % Sulfur (Combustion Anal .), Psi       =   19.81%
        b.  Acid Titration, Pvi
        c.  Material Rate, Ri                      =   35 Ibs./hr.

    3.   Intermediate Stage Carbon
        a.  Stage 8, 7? Sulfur, PS8                 =   ---

                                                   =   8.0%
                                                   =   7.8%

                                                   =   7.9%
                                                       5.0
    4.  Outlet Carbon
        a.  % Sulfur (Combustion Anal.), Pso       =   4.21%
        b.  Material Rate, R0                      =28.9  Ibs./hr.

    5.  Inlet Gas
        a.  % H2                                   =   36.1%
        b.  H2 Gas Rate                            =   79  CFH @ 70°F
        c.  N2 Gas Rate                            =   127 CFH @ 70°F

    6.  Intermediate Stage Gas Analysis

          Stage  % H2   % H2S  % N2   % SO 2  % H20  % CO
b.
c.
d.
e .
f .
g-
h.
Stage
Stage
Stage
Stage
Stage
Stage
Stage
7,
6,
5,
4,
3,
2,
1,
7
la
7
10
°l
la
7
/o
7
/o
7
la
7
to
Sulfur,
Sulfur ,
Sulfur,
Sulfur,
Sulfur,
Sulfur,
Sulfur,
PS7
PS 6
PS5
PS4
PS3
PS2
PSI
1
2
3
4
5
6
7
34.3
28.8
15.8
	
5.2
	
- - — —
0
4.0
18.5
	
23.9
	
	
64.8
66.6
65.1
	
59.9
	
	
0
0
0
	
0
	
	
0
0
0.24
	
9.40
	
	
0
0.012
0.052
	
0
	
	
0
0
0.05
	
1.60
	
	
        Outlet Gas Analysis
        a.   % H2                                   =    2.0%
        b.   % H2S                                  =   27.3% 60.0%
        c.   % N2                                   =   60.0%
        d.   % S02                                  =0
        e.   % H20                                  =    9.04%
        f.   % CO                                   =0
        g.   % C02                                  =    1.8%
        h.   % Sulfur  (as  Si)                        =    6.2% (on Dry
                                                    :            Basis)

                              542
-------
    8.
Temperature
  Stage  Carbon/Gas, op
            1
            2
            3
            4
           1132/1215
           1135/1182
           1072/1198
            899/992
        Cyclone Product
        a.  Sulfur
        b.  Material Rate
        c.  % Material +40 Mesh
        d.  % Material -40 Mesh
                               Stage  Carbon/Gas,°F
                                 5      1120/1204
                                 6      1219/1234
                                 7      1024/1200
                                 8      	/1248
                                    25.4%
                                    0.015 Ib./hr.
                                    8.5%
                                    91.5%
B.  SULFUR MATERIAL BALANCE, SULFUR REMOVAL, AND H2S CONVERSION

    1.   Run Start
    8.

    9.

   10.

   11.
   12.

   13.
        Run Times
        a.  Run Time
        b.  Steady State Period
        c.  Inlet Carbon Analysis
        d.  Outlet Carbon Analysis

        Inlet Sulfur Loading, Psi
        Outlet Sulfur Loading, PSo
        Inlet Material Rate, Rsi
        Outlet Material Rate, RSO
        Cyclone Sulfur Loading, Pscy
        Cyclone Material Rate, Rscy
        Gas Rate In, qT
        N2 Rate In,
        H2 Cone. In, 100
        H  Cone. Out, 100
H2S Cone

S02 Cone,

1120 Cone
          Out, 100 (yH2s)0

          Out, 100 ySo
          Out, 100 .(yH20)0

CO Cone. Out, 100 YCOO
C02 Cone. Out, 100 (

Sulfur Vapor Out, RSVO
2463-2818
2574-2818 +90+21 = +111
2481-2725 (-93)+lll
2636-2880 (-62)+lll

19.81%
4.21%

35 Ibs./hr.
28.9 Ibs./hr.
25.4%
0.015 Ib./hr.
206 CFH @ 70°F
127 CFH @ 70°F

36.1 vol. %
2.0 vol. %

27.3 vol. %

0
9.04 vol. % (by difference)

0
1.80 vol. %

0.421 Ib./hr.
                              543
-------
                        SAMPLE CALCULATION

Sulfur in Off-Gas

  Measured Quantities

    Ws  = Weight of  Sulfur Recovered =4.73 gms .  = 0.0104 Ibs.
    Twt = Temperature  of Wet Test Meter = 99°F = PH20 = 6.2% H20
    Q   = Cubic Feet of Gas = 3.35 ft.3 (less Sulfur)
    t   = Elapsed  Time of Sample = 128 minutes

  Calculations

    ,T - Dry Gas Flow  Rate - (M|m, (0^, (1 -
                            = (3.35) (60) (530) (1 - 0.062)
                                      (128) (554)

                            =1.40 CFH @ 70°F
                       (|f) (386) (^) (100)
    % S  (Dry  Basis)  =  -32 -    128
                    _  [ (0.014) (386) (60) (100)]/[(32) (128)]
                                  .  ,0.0104^ ,10~^    ~
                               qT + ( — 3^ — ) (386)

                    =  5 . 8805
                       1.459
                    =  4.03% Si
    RSVO = Ibs. S/hr. =  ^ ^'  (qN2)

                                 / 60
                      =  0.443  Ibs.  S/hr.

Found leak in analysis system  and measured it to be:

                                 = 0.516 CFH @ 70°F
Corrected above sulfur gas  results:
                  ,0. 0104N /qofix / 60 W1 nf)N
                  (	T5	MJOOMTT5TJ-M-LOO)        c  RR
      70-  	3±	128	 _  J .00 _ g  047
      10 D ~  	7^—A1 A A	Tf\	   7^ Q/. 1   u • *•"«>
                           0.0104   N/60N/-,0^N _  (0.0104) (60) (127)
      p      *
      RSVO = t  >. -   i>40_o.516T:Z8~'       (0.884) (128)

                     = 0.700  Ibs./hr.

                               544
-------
                                                                                  GAS  ANALYSIS
                                                                                                  4* DIA.  REGENERATOR
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          CBOSS REFERENCES:
CARBON SPECIFICATIONS;
  TYPE      	
  SKID NO.   	.
  SAMPLE NOl
DATE
V>l/73


SHIFT
8-4
4-12
12-8
OPERATOR
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-------
                                                                       GAS ANALYSIS
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-------
COLUMN TEMPERATURES. PRESSURES. AND PRESSURE


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-------
                           RUN SHG-11


A.  EXPERIMENTAL DATA - H2S GENERATION/S STRIPPING

    1.  Virgin Carbon
        a.  % Sulfur (Combustion Anal.), Psc       =   0.65%

    2.  Inlet Carbon -
        a.  % Sulfur (Combustion Anal.), Psi       =   19.81%
        b.  Acid Titration, Pvi
        c.  Material Rate, RI                      =35.0 Ibs./hr.

    3.  Intermediate Stage Carbon
        a.  Stage 8, % Sulfur, PS8
        b.  Stage 7, % Sulfur, PS?
        c.  Stage 6, % Sulfur, Ps6
        d.  Stage 5, % Sulfur, PS5
        e.  Stage 4, % Sulfur, PS4
        f .  Stage 3, % Sulfur, Ps3
        g.  Stage 2, % Sulfur, PS2
        h.  Stage 1, % Sulfur,
    4.   Outlet Carbon
        a.   % Sulfur (Combustion Anal.) ,  Pso       =   8.27%
        b.   Material Rate, R0     ,                 =   (27.7)  Ibs.  C/hr.
                                                        30.2
    5.   Inlet Gas
        a.   % H£                                   =   0%
        b.   H2 Gas Rate                            =   ---
        c.   N2 Gas Rate                            =   202 CFH @ 70°F

    6.   Intermediate Stage Gas Analysis
          Stage  % H2   % H2S  % N2   % SC-2  % H20  % CO   % CO 2

            1
            2
            3
            4
            5
            6
            7

    7.   Outlet Gas Analysis
        a.   % H2                                   =0
        b.   % H2S                                  a,   1.32%
        c.   % N2                                   =   88.0%
        d.   % S02                                  -   0.82%
        e.   % H20                                  =   9.0%
        f .   % CO                                   =0
        g.   % C02                                  -   2.0%
        h.   % Sulfur (as  Si)
                              540
ro
-------
    8
Temperature
Stage Carbon/Gas , °F
1
2
3
4
1070/1200
1035/1150
1040/1150
925/1020
        Cyclone Product
        a.   Sulfur
        b.   Material Rate
        c.   % Material +40 Mesh
        d.   % Material -40 Mesh
                                       Stage  Carbon/Gas,°F

                                         5      1085/1135
                                         6      1207/1290
                                         7      1170/1215
                                         8       —/1130
31.2%
0.021 Ib./hr.
17.2%
82.8%
B•   SULFUR MATERIAL BALANCE. SULFUR REMOVAL, AND H2.S CONVERSION

    1.   Run Start
3,

4,

5.

6.
    8.

    9.

   10.

   11.
   12.

   13.
        Run Times
        a..  Run Time
        b.   Steady State Period
        c.   Inlet Carbon Analysis
        d.   Outlet Carbon Analysis
        Inlet Sulfur Loading,
        Outlet Sulfur Loading, PSo

        Inlet Material Rate, Rsi
        Outlet Material Rate, RSO
        Cyclone Sulfur Loading,  Pscy
        Cyclone Material Rate, Rscy
        Gas Rate In, qT
        N2 Rate In,
    H2 Cone. In, 100
    H2 Cone. Out, 100

    H2S Cone. Out, 100 (yH2s)o

    S02 Cone. Out, 100 yso

    H20 Cone. Out, 100

    CO Coric. Out, 100
    C02 Cone. Out, 100

    Sulfur Vapor Out, RSVO
2820
2931-2954 +90+121 = 111
2838-2861 (-93)+lll
2992-3016 (+62)+lll

19.08%
 8.27%

35.0 Ibs./hr.
30.85 Ibs./hr.
31.2%
0.021 lb./hr.

202  CFH @ 70°F
202  CFH @ 70°F

0
0

1.32 vol. %

0.82 vol. %

9.0  vol. %

0

2.0  vol. %
                              549
-------
                                                    GAS  AND CARBON :LOW RATES
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-------
                            e>.r-p
                                                                          GAS ANALYSIS
                                                                                                                                    DIA. REGENERATOR
                                                                                                                                  DATE
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CARBON SPECIFICATIONS?
  TYPE     	
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DATE
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-------
                        APPENDIX A-20


                         DERIVATIONS
                                                        Page

1.   Derivation of Response Parameters Used for           554
      Integral Run

2.   Derivation of Mathematical Expressions for           572
      Calculation of Rate of Reaction To Form
      Sulfur - Differential Rate Studies in
      Batch Fluid Bed Reactor

3.   Derivation of Reaction Rate Equations for            588
      Sulfur Generation - For Continuous Acid
      Conversion Runs in 8 Stage, 4 Inch
      Diameter Fluid Bed Reactor
               *

4.   Derivation of Space Velocity Design Equation         597
      for S02 Sorber

5.   Derivation of Design Equations for Sizing of         602
      S02 Sorber
                            553
-------
                       APPENDIX A-20-1

   DERIVATION OF RESPONSE PARAMETERS  USED FOR INTEGRAL RUN


This section contains the equations used to calculate process
performance during integral  testing of  the Westvaco S02
Recovery Process.  Most are  equations used throughout the
process development so the derivations  are not necessarily
repeated in the other sections of Appendix A-20 which contain
other equations used in data analysis in pre-integral
operation.


A.   S02  SORBER

     1.   S02  Removal  Efficiency

         Let  PSR =  per  cent  S02 removal, %

         Then

                      Inlet S02 Cone. -  Outlet S02 Cone.-,
                      -
                     inn r
                PSA = 100 [        Inlet S02 Cone.
                            Outlet S02 Cone..,
                                          J
       2.  Carbon Attrition  Rate

           Let RCD  =  carbon attrition rate,  Ibs. C/hr.
               R18D =  total  material collected from S02 sorber
                          outlet  gas ,  Ibs . /hr .
               XeSc =  residual sulfur loading of regenerated carbon
                          to  S02  sorber,  Ibs.  S/lb. C
               PH20 =  Per cent moisture of dust collected from  S02
                          sorber  outlet gas ,  7o
               PS   =  total  sulfur content of dust collected from
                          S02 sorber outlet gas, %.

           Then


[1]            # Mat'l/hr.  - #C/hr. + # Residual S/hr.  + # H2S04/hr. +  # H20/hr.


           and from above
                                554
-------
                     =  RGB + xeSc RCD + —-^^ + ^ RISD

           but  also the per  cent sulfur  is:

ro-i             Ibs. Residual S/hr. + Ibs. H2S04/hr. (32/98)  =  PS
L J                        Ibs. Material/hr.                  100

           or

r/,1             XeSc RCD + Ibs. H2S04/hr. (32/98)     PS
L J                         RISD               =  100


            therefore  solving for Ibs.  H2S04/hr.
                                                     _98
 [5]             Ibs. H2S04/hr.  =   t^gr (R18D) - XeSc RQDJ32
            Substituting [5] into [2]


[6]        R18DU - ^f>  =  *™ + XeSc "CD + 3'0625(^) R18D ' 3'°625

                RlSDf1 ~ ^j- ~  3'0625^)] = RCDtl + XeSc - 3.0625 XeSc]


                          -     -
L/J
                            [1 - 2.0625
       3.   Residual Sulfur Loading on  Regenerated Carbon to Sorber
            Let PeSc = P®r cent sulfur  on inlet carbon,  "L
                     = Per cent moisture  on inlet carbon, %
                     = material rate into sorber, Ibs./hr.
                x    = Ibs.  G/hr.
                y    = Ibs.  residual sulfur/hr.
                z    = Ibs.  moisture/hr.
                XeSc = Ibs.  sulfur/lb.  C.
            then

                                 555
-------
[1]             x + y-t-z  =

                       100

[3]             y/RTi  -  PeSc/100

[4]             y/x =  XeSc
                     PH20
[2]             z  -   oo

[3]             y  =
            From  [1],  [2],  [3]
                x  =  (1 -   0 _ Z£SfiL
                      V    100   100
            substituting  [3]  and [5]  into [4]

                XeSc  =      (PeSc/100)(RTj)
[6]             XeSc =
                             PeSc
                        100 - P0 - peSc
        4.  Outlet Sulfuric Acid Loading of Carbon from S02 Sorber
            Let Xv   = acid loading,  Ibs.  H2S04/lb. C
                XeSc = residual  sulfur loading of carbon, Ibs.  S/
                           Ib.  C
                PH20 = per cent  moisture of carbon from S02 sorber,  °/0
                PS   = per cent  sulfur of carbon from S02 sorber, 70
                WT   = Ibs. material  out of sorber, Ibs./hr.
                Wc   = Ibs. C/hr.
                WeSc = Ibs. residual  sulfur/hr.
                Wv   = Ibs.  acid/hr.
                WH20 = Ibs. moisture/hr.

                                556
-------
[1]               Wc + WeSc + Wv + WH20  -  WT
                            Wv
                  WH20  =  pH20
                   wT      100
                                 100
[4]               ***  =  XeSc
[5]               ^  =  XV
                  Wc
[5]               Wv  =  XVWC


[4]               Wesc  =  XeSc Wc


              and [5]  and  [4] into  [2]
                  XeScWc + 0.3265  XVWC      ?S
                           WT             100
                  (XeSc + 0.3265  XV)WC  =
                   u     100 vX6Sc + 0.3265 Xv



             and [6]  into [4]  and  [5]


                  wv  =
                          100     sc + 0.3265
                  W GO  =      pr (	
                  WeSc       100   4esc + 0.3265
                                     557
-------
             and from  [3]

                           p
[3]               WH2o  =   3o^wT

             Substituting [6],  [7], [8],  and  [3] into [1]
                        .      ec +      V) ( _        )  +         =
                   100      100      100  'Vxesc + 0.3265 Xv    100   x      i
                      (1 + XeSc + Xv)  =  (1  -     )(XeSc + 0.3265  Xv)


                                      =  XeSc + 0.3265 Xv -     XeSc - 0.3265 Xv

                         . 0.3265 + 0.3265     )  -  -    (l + XeSc)
                                                  PH20,
                         1QQ*1 + XeSc) - XeScd - -fg)
[9]               Xv  =
                             O.oo*c/,   *H20X    PS
                                      558
-------
   B.   SULFURIC ACID CONVERTER
         :JL""™^^^^^^"™^^~    "" " :       ""' ••"• • •••'                                  /
        1•   Outlet Sulfurlc Acid  Loading on Carbon

            Let PVO   = per cent  acid on carbon from unit, wt. 70
                PS    = per cent  sulfur on carbon from unit, wt.  70
                PH20  = per cent  water on carbon from unit, wt. %
                WT    = total  material from unit, Ibs.
                WVQ   = sulfuric  acid on carbon from unit, Ibs.
                Ws    = elemental sulfur on carbon from unit,  Ibs.
                Wc    = weight of carbon on carbon from unit,  Ibs.
                Xvo   = H2S04  loading on carbon from unit, Ibs./lb
                WH20  ~ weight of water on carbon from unit, Ibs.
[1]              ws + wc + wvo + wH2o  =  WT

                WS + 0.3265 Wyo    PS
                     WT          100
r,-,             Wvo  =  Pjffi.
L •» J             WT     100
                 W   ~  100
[5]

           from [3] and  [4]

[3]             wvo =

[4]             WH20 =
                                 559
-------
           from [5]
                wc =
                      Avo
           and substituting [3] into [5]


                      Pv
                Wc    100 XVO
           and [3] into [2]


[7]             WS +
           and [3], [4], [6], and [7] into  [1]
                [P_S_ - o.3265(pJL_)]wT + (—Is — )wT +  (5m) WT + (320) WT =  WT
                 100        100   1   100 Xvo      100       100

           multiplied by Xvo


                Xvo rP_ . 0.3265(fp
[8]             X
                 vo
                       100 - PS - PH20 ~ 0.6735 Pvo
       2.   Outlet Elemental Sulfur Loading  on Carbon (from Acid
             Converter

           Let PS    = per cent sulfur  on carbon from acid conversion,  70

               PVO   = per cent H2S04 on carbon from acid conversion, 7o

               PH20  = Per cent H20 on  carbon from acid conversion,  %
               Xes   = elemental sulfur loading from acid conversion
                          in acid converter,  Ibs .  S/lb. C

               Xesc  ~ residual sulfur  loading from acid conversion
                          in acid converter,  Ibs.  S/lb. C
                                560
-------
               WT    = total  material from acid conversion,  Ibs.   ,
               Wvo   = total  H2S04 from acid conversion,  Ibs.
               Wes   = total  elemental sulfur from acid conversion,
                           Ibs.
               Wc    = total  carbon from acid conversion,  Ibs.
               Wesc  = total  residual sulfur from  acid conversion,
                           Ibs.
               WH20  = total  H20 on carbon from acid conversion,  Ibs
                Wvo + Wes + Wc + WH20 + Wesc  =  WT

                Wes + WeSc + 0.3265 Wvo    PS
                         WT           " 100
                WT   "  100

                WH20 _  PH20
                 WT  ~   100
                Wesc _
                 We
[5]


[6]             wT  =  Xes


          from [3] and  [4]

[3]             Wvo

C4]             WH2o
          from [5] and  [6]

[5]             Wesc  =  Xesc Wc
[6]             Wes   -  Xes  Wc
[7]            Z -  Wesc + Wes -  (Xesc + Xes)Wc
                                 561
-------
 [8]




 [9]
 [10]
 [11]
            and  [3]  into  [2], and  [1]; also  [7] and [4] into [2] and

            [1]  give [8]  and [9],  respectively
         (Xesc + Xes)Wc + Wc
(Xesc + XeS)Wc
                                                   100
                                     WT
            from  [8]
Wc (1+ Xesc + Xes)  =  WT[1 -
                                  1122
                             100    ioo
                                                        ]
                                                        j
 wc  =  WT
                                      PH20

                                 100   100
             _ Pvo
                             1 +
            and [10]  into  [9]  gives
W-r(Xesc + Xes)
                   Pvo   PH20

               1 " 100 "  100

               1 "*" Xesc "^ Xes
+ 0.3265
            multiply , both sides by  (1  -f Xesc + Xes) (100)
 (Xesc + Xes) (100 - Pvo -
                                              0 . 3265 Pvo (1 + XeSc + Xes) - PS (1 + Xesc + Xes)
                  Xesc (100 - Pvo - PH20) + Xes (100 - PVO - PR20) + 0 . 3265 Pvo (1 + Xesc)



                       + 0.3265 PVO Xes  -  PS(! + Xesc) + PS Xes
[12]
           or
                  Xes [100 - PVO - PR20 + 0.3265 Pvo - PS!  -



                       -Xesc(100 - Pvo -PH20 + 0.3265 Pvo - PS) + PS  - 0.3265 Pvo
           then
Xes
                                   - 0.3265 Pvo
         100 - PS - PH20 - 0.6735 Pvo
                                         562
-------
        3-  Hydrogen Sulfide  Utilization in Acid Converter

            Let ?H2S  = Per cent H2S utilization,  %


Til              p-a c  =  /Inlet H2S Cone. - Outlet  H2S Conc.x n nnx
L j              rH2S     <.Inlet H2S Cone.}UUU'


            but 4 moles H20 replace 3 moles H2S;  therefore, H2S con-
            centration has to be put on an inert free basis,
            therefore


r?l              PHO
-------
         5.   S02 Breakthrough from Acid Converter

             Let ZS02      =  S02 evolved from  acid converter,
                                 moles S02/mole H2S04

                 Xvi       =  H2S04 on carbon from S02 sorber,
                                 Ibs.  H2S04/lb. C
                           =  material rate measured into S02 sorber,
                                 Ibs./hr.
                                  cent sulfur on carbon into S02  sorber,
                           =  Per cent H20 on carbon into S02 sorber,  70

                 Rc        =  carbon rate into S02  sorber, Ibs. C/hr.
                           =  nitrogen flow rate  into acid converter,
                                 CFH @ 70°F
                 YS02      =  S02 concentration in  gas from acid  con-
                                 verter, volume fraction
                 YN2       =  N2  concentration in gas from acid converter,
                                 volume fraction
                       RT
                            - (PS)KF -
                                100       100
r~-i              ZQ   _  Moles S02 Evolved in Acid Converter/Hr .
L J               S02  ~    Moles Acid Sorbed in S02 Sorber/Hr.


ron              Moles S02 Evolved      ,f t? N2V JS02s /ft.3 S02/ft.3 Gas. , mole acid N
C3]                              = q»2<-)()( ft.3 N2/ft.3 Gas> (386 ft.3 S02>
                                    (386 YR2)
[4]              Moles Acid/Hr.  =  xvi(  {b  ^ ) RC


                               =  Xv Re/98


            Substituting [1] into [4], then  [4]  and [3] into  [2]

                            0.2539
[5]              ZS02  •  	
                                    (PS)KF   ^20)0-,
                                     564
-------
        6.   H2S Breakthrough from Acid  Converter
            Let ZH2S  = H2S breakthrough  from acid converter,
                           moles H2S/mole H2S04
                Other variables likewise  as  tinder B.5 except
                YH2S = H2S concentration  in  gas from acid converter,
                           volume 70.

            Therefore by a derivation the same as in B.5,  except H2S
            replaces S02 leads to

[I]                       0-2539
    C.   H2S GENERATOR/ SULFUR STRIPPER
        1.   Inlet S Loading on Carbon
            See Section B.2.
        2.   Inlet Acid Loading on Carbon
            See Section B.I.
        3.   Outlet Sulfur Loading on Carbon
            See Section A. 3.
        4.   Hydrogen Utilization
            Let PR2  = Per cent H2 utilization,

                                          of Bnlt
                                                i(ioo)
                                         -
TOT              » n    e TT 4*    H2 Cone. Out
[3]              H2 Out of Unit  =  r—r - ^-—
u  J               *               N2 Cone. Out
                                   565
-------
            Substituting  [2]  and [3] into [1] and  rearranging
            Hydrogen Conversion  to Hydrogen Sulfide

            Let  (PR2S)U  = per  cent hydrogen to hydrogen sulfide, %

                 (qN2)i   - inlet  N2 flow rate, CFH  @ 70°F

                 (qN2)o   = outlet N2 flow rate, CFH @ 70°F
                 (YH2)i   = ^2 concentration in gas  to regenerator,
                               volume fraction
                 OfN2)i   = N2 concentration in gas  to regenerator,
                               volume fraction
                 (YH2S)_  - H2S  concentration out gas to regenerator,
                               volume fraction

                          = ^2 concentration out gas to regenerator,
                               volume fraction.
 [1]              (PHOO)   =  ioo(H2 in Outlet Gas as H2S/Hr
 L  J              ^rHS^      J-vuv              Gas/Hr>
 [2]              H2 as H2S in Outlet Gas/Hr.  » (H2S Conc.)(N  Flow Rafce In)
                                             N2 Cone.
[3]              H2 In Inlet  Gas  =  (       ')(N2 Flow Rate  In)
            Substituting [2] and [3]  into [1]


[4]              (PH?S)   -  100 [(YH2S) n/(YN2> oi
L J              ™2S)u        L(YH2)i/(YN2)i J
                                    566
-------
       6.  Hydrogen Requirement  for Acid  Conversion

           Let  aH2   = H2 requirement for H2S04 conversion to e
                            elemental sulfur,  moles H2/mole S02
                            recovered from  flue gas
r,-i              Moles S02 Recovered _  Moles H2S04 Sorbed
*•                   from Flue Gas    ~  on Activated Carbon



                 a    _  Moles H2 Fed to S Stripper-H2S Generator/Hr .
[2]               HZ     Moles H2S04 Sorbed on Activated Carbon/Hr.




[31              Moles H2 Fed/Hr. -   *'l *2/ft'l Gas (  mole,H2 )
                                    N2 *   hr.   VYN2'  ft.3 N2/ft.3 Gas  386 ft .3 H2


                                    1   (YN2>i
                                 = 386"  "
                 mw^i^o uocn/ /u*  - ('v ^  Ibs.  acid p  ^Ib. C^ /  mole acid N
                 Moles H2S04/Hr. - (Xv)o   lb> c   RC (-^7-) (g8 lbg< acid>


                                = (XV)0 Rc/98


                 n   -  niT^    n   (PHZO)KF
                 RC  -  (RT)KF  [i -- IQQ     100
            Substituting [5] into [4], then [3] and  [4]  into [2]
                         98
                         386  (YH2>
                                                        100   -   10
                       where   (vH2)i    *" H2  concentration into  S
                                              stripper/H2S gen., vol.  frac.

                               (vN2)i    = ^2  concentration into  S
                                              stripper/H2S gen., vol.  frac.

                                         = N2  flow rate into S  stripper/
                                              H2S gen.,  CFH @ 70°F
                                     567
-------
                             (Xv)0     " H2S04 loading in C from S02
                                            sorber,  Ib. -H2S04/lb. C
                             (Re)      - carbon rate from S02 sorber,
                                            Ibs.  C/hr.

                             (RT)VF*   = material rate at Kane  feeder,
                                            Ibs./hr.

                             (PR20)KF  = H20  cone,  on carbon at Kane
                                            feeder,  %

                             (PS)      = S  cone,  on carbon at Kane
                                            feeder,  %
           Carbon Burn-off

           Let  (Re)BO   :
          Ib. carbon  evolved as CO or C02/hr.,
             Ibs. C/hr.
[1]
         Carbon Meas.  as CO in Gas from S Stripper/H2S Gen.
         + Carbon Meas. as CO in Gas from Acid Converter
         + Carbon Meas. as C02 in Gas from S Stripper/H2S Gen.
         + Carbon Meas. as C02 in Gas from Acid Converter
[2]
(Rc)BO
                                                        S Strip .-H2S :Gen. Outlet Gas
                                                         AcidConv. Outlet Gas
           As it turned out  there was no CO detected and the C02  from
           the S stripper/H2S  generator was equal  to the C02 from the
           acid converter  implying that all carbon burn-off occurred
           in the S stripper/H2S generator and Equation [2] reduces  to
                (RC)BO
                          YN2   386
                                       S  Strip.-H2S Gen.  Outlet Gas
            *In calculating  the  carbon rate from this material  rate
      the  attrition rate is neglected, but the  attrition rate  was '
      less  than one per cent  of the total material rate.
                                    568
-------
                      where YC02  * C02  cone.;in S stripper/H2S gen.
                                       outlet gas, volume fraction
                             YN2   = N2 cone,  in S stripper/H2S  gen.
                                       outlet gas, volume fraction
                                   = N2 flow rate from S stripper/H2S
                                       gen.,  CFH @ 70°F
   D.  SULFUR CONDENSER

       1.   Sulfur Recovery
C4]
            Let (PSR)s    ~  Per cent S recovery,  % stripper

                      S   *  Per cent S recovery,  % of S02 recovered
                               from flue gas based on elemental  S
                               recovered

                      s   *  Per cent S recovery,  % of S02 recovered
                               from flue gas based on gas analysis  of
                               gas from acid converter
            a.   Sulfur Recovery - % Sulfur  Stripper
                    (p  )   =  TOO f _ Sulfur Recovered _ ,
                    Vi'SR-'S     ±uu ls in on Carbon - S Out on CarbonJ
                    S  into S Stripper-
[2]                 H2S Generator on   =  S in as S + S in as Acid
                    Carbon

                                     =  [Xes + Xesc + -no
                                                    98 "VOJ  c  hr.
                    S Out S Stripper-
                                              JLD •  w
[3]                 H2S Generator on  =  Xesc RC -^—
                    Carbon
                    S Recovered  =  Res> a measured value, Ibs.  S/hr,
                [2], [3] and  [4],  into [1]
                           100
                              [Xes "*" Xesc "*" qg ^vo ~ XescJ

                                  569
-------
[4]                PSR  =  100
                             [Xes+%^(RT)KF Il-'-ife-
                         where Xes  = S loading  on C, see Section  B.2
                                Xesc = residual S loading on C,  see
                                         Section  A.3

                                XVQ  = inlet acid loading on C to S
                                         strip.-H2S gen., see Section
                                         B.I


           b.  Sulfur Recovery, % of S02 Recovered Based on S Collected


n 1                CP ~\      i nn r   ^ S Recovered in S Condenser/Hr.   n
LU                ^SR-'SS ~  LVV L                         sorber/Hr.J
[2]                Lbs. S/Hr.  =  Res  (measured quantity)




                   Lbs. S Recovered    32 (Xv)
                     as S02/Hr.          98   WT)RF  t1 ~   100      100



               Substituting [2] and [3] into  [1]
                   KF   "  material rate  measured at
                                              Kane feeder, Ibs./hr.

                                (^20)]^ =  % H20 on C measured at Kane
                                              feeder, %

                                (PS)KF   =  % S on C measured  at Kane
                                              feeder, 7<>.
                                 570
-------
        c.
[1]
Sulfur Recovery, % of  S02 Recovered Based on S Values
in Outlet  Gas of Acid  Converter


            1QO L# S Recov. as S02 iru  £ S as H2S + S02 in Outlet.)
         i  __  L:    Sorber/Hr.    J ~ C Gas of Acid  Conv./Hr.  U
      SR'SS            # S Recov. as S02 in S02 Sorber/Hr.
[2]
    # S Recov.  as S02    32,
    in S02 Sorber/Hr .  =  98(Xv)° (RT>KF
[3]
# S as H2S
+ S02/Hr.
                 32
                386
01  ft.3
 J  h77
                        (YH2S)° ~ (YS02)01 ft.3  moles/ft.3. .32 *
                                              386    ~
                                 (YH2S)0 - (YS02)
            Substituting [2] and [3]  into [1]
[4]
    (PSR)SS =100  1 -
                                          98 [(YH2S)
                                                  Q
                      386 (YN2)0
                                                           (PS)KF   CPn2o)KF
                                                                      100
                                                                           ]
                      where (YH2S)O

                             (YS02)0

                             (YN2)0


                             (^2)0

                             (Xv)0

                             (RT)KF

                             (PS)KF

                             (PH20)KF
                             H2S cone, in  outlet gas from
                               acid converter,  vol. frac.

                             S02 cone, in  outlet gas from
                               acid converter,  vol. frac.

                             N2 cone, in'outlet gas from
                               acid converter,  vol. frac.

                             N2 flow rate  £rom acid con-
                               verter, CFH @ 70°F

                             acid loading  on C from S02
                               sorber, see Section A.4

                             material rate measured at Kane
                               feeder, Ibs./hr.

                             % S on C at Kane Feeder, %
                             % H20 on C at Kane Feeder, %.
                                   571
-------
                             APPENDIX A-20-2

             DERIVATION OF  MATHEMATICAL EXPRESSIONS FOR
   CALCULATION OF  RATE OF  REACTION TO FORM SULFUR - DIFFERENTIAL
               RATE STUDIES IN BATCH FLUID BED REACTOR
 It is assumed that  the overall rate of reaction is
               3 H2S + H2SOi|
                                            S + U H20
                       =  Vol. Frac. H20 Out
                       = -Vol. Frac. S02 Out
                       =  Vol. Frac. H2S Out
                       =  Flow Rate of Inert Gas, SCFH
                         PS
                         Xv
                         Xy
                                          Volume of Carbon (Settled Bed,  ft.3)
                                          lb.  Residual Sulfur/lb.  C
                                          Initial % Sulfur
                                          % Sulfur at Any Time t
                                          Initial lb. H2SOU/lb. C
                                          lb.  H2S01*/lb. C at Time  t
 Ql
Flow Rate  of Inert Gas
Vol. Frac. H2S In
Vol. Frac. HgO In
Vol. Frac. S02 In
It will be  assumed that the reactor is differential with respect to the gas.
With this assumption the sulfur analysis of the carbon will be used as a basis
of following the reaction of H2S with H2S01^ to form elemental sulfur which
remains sorbed on the carbon.
                                  572
-------
 If the reactor can be taken to be a single ideal batch reactor if follows that
 [Cl]
(Rate of Loss of A
 Due to Chenu Rxn)
   (Rate of Decrease of
Reactant A within Reactor)
 [C2]


 CC3]
                (_rv).V  =
                                      H-
                                       Vo
                             'o  dt
                           (-rv) dt
                          FC
                                 dFc
                                (-rA)
          t
         *J
                                        dt
 and then if the time period is sufficiently small the average rate, (-
                                         F(J 1+1 + YQ t
 can be taken at the average conversion (—"	•"-).
 LC5]
                           V
                          NAO
£06]
                            (FQ.J
                                               +1
           where  V    =  Volume of reactor» ft.3
                  NV   =  Initial charge of H2S01*, Ib. mole
                  tj   =  Time at j**1 minute
                  Fc i   =  Fraction conversion of HpSOk at j^*1 min.
but
           Bases:   1 Ib.  C
[C7]
                                   573
-------
at t«  Fn   -  Xvi - (XV}J
at *J» FcJ	x^~
Cc8]




and


LC9]
                           and at tj+i,




                           (Xy)^ - (Xy)J+1
                                                     '.- (Xy)J+1
                             (xy)j -
                          y  XVi
LClOj
                   Ky0  =
                        =  XVi V
Cdl]
                                                _
                                                    <
                                                       /
,  Ib.  mole acid/ft.3 C/hr.
          where     =  density of carbon, Ibs./ft.
or
[C12]
                    (xv}.i -
                                                   .  C/min.
where the rate is assigned the average acid loading over the time period

*  to
CC13]
and the average elemental sulfur loading XeS over the time period t^ to t
                                                                  J
                                         574
-------
 A similar derication holds for the rate of sulfur formation and assigned the
 same average properties of sulfur loading and acid loadings.
                         (rs) are =
 The unknowns Xy and Xg are calculated from the measured experimental values
 depending on whether it is assumed that no S02 is evolved or some quantity of
 S02 is evolved.  The derivation of the resulting relationships for each assump-
 tion is given below.

 Assuming Ho S02 Evolved

 If this assumption is made then only one unknown needs to be determined with
 time.  In this case the total per cent sulfur is measured as a function of
 time.

      Let X    =  Ib. C = 1

          Xy   =  Ib. HgSOlj.

          xeSc =  ll3' residual sulfur

          XQC,  =  Ib. elemental sulfur,
           G S

 Then Equations [Cl6] and [C17] need to be solved for Xy and Xes


[C16]                      XV(^Q) + XeSc + XeS
                               Xesc + Xy + Xgs    100


                                Xy  =  Xyid - PC)'
          since  Fyo = 1
                 P|  = P-./100
                  o     o
Cci8]
                                XVi  (1  - PC) + Xes    100
                                    575
-------
Cci9]   X   = PS + ^sc^s •10°) + Xvi(ps - 32.65)  +  FcXvi(32.65  - Ps)
              '""	' ' "'"'   IH Nil" •	-•"• •••   • I                             Ill  I ••.
         es
                                    100 - P
                                           s
[C20]   X      s    esc                    )  [32. 6$  - P]
         es                    100 - P
[C21]
psi(i + x_J -
    32.65 -
esc
                           •si

    also

[C22]   X   - MP)Xvl() = 1-306 X    F
,    ,        ,
LC23]    1.306 Xvi
                   Ps +  Xesc(Ps  - 100) + Xvi(Ps - 32.65)
                            [97-95 -  -306 P  ]
     Therefore  equations  [C20] and LC21] provide the relationship between linknowns
     and measurements needed to calculate the rate of reaction by Equation Cci2].
                                  576
-------
Assuming S02 Evolved - 1000°F H2S04 Analysis

If S02 is evolved the two unkowns need to be determined, in this case
the total per cent sulfur and sulfuric acid content on the carbon as
a function of tiem.  The SOp being evolved also suggests a two step
mechanism for sulfur generation
 [C25]   He30*  +  HsS      S +  SCfe + 2HgO

 [C26]   2HsS + SOfe     35 + 2HsO

 to give the  overall reaction

 [C2?]   HaS04  +  3H3S    kS
Let W  = Ib C = 1 as a basis
     C« "
    Wv = Ib H^S04 on carbon
    wSCb = lb S08 formed ^y reaction CC25]
    W    = Ib residual sulfur on carbon
     esc
    ¥g = Ib elemental sulfur
    F  = fraction of S03 formed in reaction LC25]
         that reacts by reaction [C26]
Then
[C28]   Moles of S03 evolved = Moles SQg  formed by reaction [C25]
                                         not reacting by reaction  LC26]

                             - t1 - F) ^
                                        64

[029]   Moles of Elemental Sulfur formed = Moles formed by reaction  [025]
                                           + moles formed by reaction  [C26]
                                             6k         64

[C30]   Moles HeS04  left on carbon =/ Initial moles  )    ..Moles  HSS04      .
                                     H3S04  on carbon     converted to  S02
                                     X J    Wnn           in rxn.  [025]
                                   __ vi     S0a
                                   " 98  "   6k


                               577
-------
The two experimental measurements are the total  sulfur analysis  and
the S02 analysis as mentioned above.  The total  sulfur analysis  involves
burning of a known weight of sample of carbon containing  sulfur  in 03
at 2600°F to form SQg which is sorbed in a H20g  solution.  The solution
is titrated with a known normality of MaOH using methyl red  as an
indicator.  The total sulfur content of the  carbon  can then  be calculated.
By definition  the weight fraction of sulfur, Ps/100, is given as
                         Ib sulfur as
 r«-vn    ., ^  ^   *.*         . „   ,   -,_*   + ll3 sulfur as HgS04 +  Ib sulfur elemental S
 1C 313 weight  fraction  _ residual sulfur	^   *	
       of sulfur         Ib C +  Ibs S as + Ibs HSS04 + Ib sulfur as elemental S
                                 residual
                                 sulfur
The SQg analysis of. the carbon involves purging a known weight of carbon
with He at 1000°F.  If there is only sulfuric acid on the carbon then
is formed by reaction [C32]

[C32]  HsSO* + C     SCfe + CO + HgO
If, however, there is HgS04 and elemental sulfur on the carbon then
SOj, is formed by reaction [C32] or [033] or both.

[C33]  2H2S04 + S    3SOfe + 2HeO

For the present derivation it will be assumed that the IkS04 will react
with all elemental sulfur preferentially.  This now means that there are
two distinct regions one for when

       Moles of acid       Moles of elemental
       on carbon           sulfur on carbon
                                       578
-------
the other for
 [C35]  Moles of acid      Moles  of Elemental
                      ^  2  x
       on  carbon           sulfur on carbon
For the conditions  given by Equation [034]  then
                                                    M°les  °f
 LC36]  Moles He S04 reacted by reaction  LC33]   =  2  x
                                                     sulfur formed
 [C3T]  Moles BeSO*  reacted by reaction LC32] = M°leS *SO« - m°les H*S04 reacted
                                               left          by reaction [033]
                                                *vi _ %0^    2^
                                               1 98    6h '   ^ 6k' )(

 Then the S02 evolved by reactions  [C32] and [G33] is collected in a
 solution and titrated with a  known normality of NaOH using methyl red
 as an indicator.  Then the S02 analysis is given as

                        Ib SQs evolved     Ib SOfe evolved
 [038]  LB. 303/lb 0 = C ^ reaction  [C32] + by reaction Lc333 .,
                                       «LD L/ "~ J-
Then solving Equations  [C3l] and  [C38] for W    and F yields
CC39]
and
       W
        808
                                     579
-------
Then acid left at time t.  + 1 is
                        J
                           n                       Pesc
                 y   an100    98     2
               = Xvi-981
                                              p
                                           66
and the Ibs of sulfur formed at that time is

            P
       x   =         98      2     ioo     ioo-P       ioo
        68 "
                                                         .
                                                         ;
                              0.66 P
                                    s
                         .   .
                         (32)
For the conditions given by Equation LC35] then all the H2S04 reacts
with the sulfur as assumed and the S02 analysis is given as
                      Ib SOg evolved by
[043]  Ib SOkAb C - (Action [033]   , . (|)(64)[M .

Then solving Equations [C31] and Cc43] for W    and P yields
                                            SOg

^  v
and
                              32
                         XSQ3+   Xvi]  "
           p
            s p       66      32              32
                              98
LC45J  F -
                                -i L 1 -  ...  ]
where X
                     98    96   J  u -1"  ' 100
               D
               'esc
       esc   100 - P
                    esc
                                     580
-------
Then sulfuric acid left on carbon at t  + 1 is
                                      j
      (x)    _98
      UvVi " 96
and Xbs of elemental sulfur formed at that time is
[048]
= 32
                  X
        v:_
                            ] +
66        32
 g 3J6Q,  -^  g
                                                32
                                                                           32
Therefore Equations [cUl] and [c42] or [c46] and [CU8] provide the
relationship between unknown and measured quantities needed to calculate
the rate of reaction by Equation [C12].
                                     581
-------
Assuming SQS Evolved - Acid Leaching Analysis

If S02 is evolved during the differential sulfur generation experiments
then two unknowns need to be determined, the total HfiS04 and total
elemental sulfur on the carbon.

Instead of the carbon analyses used in the previous sections the acid on
the carbon is leached in boiling water and the solution is titrated with
a known normality of NaOH using methyl red as an indicator.  The remaining
sample of carbon plus elemental sulfur is dried, weighed, and analyzed
at 2600°F in 03 for sulfur content as described previously.  The data then
allow the amount of acid, amount of elemental sulfur, and amount of carbon
to be determined, that is X  and X  are given directly.
                           v      s

Beside the rate of acid decomposition, Equation [ci2], the rate of elemental
sulfur formation can also be determined as given by Equation
      (r )    = _J^	^LL±    lbg g/lb g . min
        s ave     t    - t.
                          J
Equation [C12] is the reaction rate of reaction [C25] and Equation [c&9]
is the overall reaction LC2T] rate.  The reaction rate of reaction [C26]
can thus be also determined.

Based on the above nomenclature the following derivation is made relating
the unknowns to experimentally measured quantities:
                                     582
-------
      Let W    = gms acid
           v
         W    = gms elemental sulfur
           es

         W    = gms residual sulfur
           esc

         W    = gms carbon
           c


         \o

      and total sample weight = W



[C50] W = ¥+W   +W    + ¥  + ¥
           v    es    esc    c    HaO



      By acid leaching and NaOH titration get, ¥ ,




l~ne;iT,,    (v  i   i 4.j  y/0.1 moles MaOH v/2 moles acids/98 gms  acid.
LC51J W  =  (xml solution)( - •• - )( - )(- — a - )
       v                 'V1000 ml of soln'Vole WaOH   Mmole acid  '


         =  0.0196 x; gms acid



      By drying of sample get. W   +W    +W=y = weight of sample less
                                es    esc    c         .     ,
                                                     acxd and



[C52] y = W   + W    + ¥
           es    esc    c



      By total sulfur analysis of this sample will get,  P
                                                         s


      P     ¥   + ¥
      By separate analysis earlier of the virgin carton the residual

      sulfur has  been determined,  P
                                   esc
     P         ¥                                P
      esc        esc            Ib residual S	esc

     100   = w    + w  ~  esc'  Ib carbon     ~ 100 - P
              esc    c                                esc


                            P
                    ,        esc
     or X     = ¥  /¥  =
         esc     esc'  c    100 - P
                                 esc
                                      583
-------
 Therefore have W  in terms of measured a quantity,  x,  the ml of solution

 of 0.1N NaOH in lerms of measured quantities.   This involved solving

 Equations [C52], [C53],  and
[C52] y = W   + W    + W
           es    esc    c
[C53]
      P        W   + W
       s	es    esc

      100 ~ W   +'W    + W
             es    esc    c
      W
       esc
                 esc
                                      esc
             100- P       esc    100-P
        c           esc                  esc
 Equation [C52] into [C53] gives
            W   + W
[C55]
[C56] Wes * "esc '
 and [C52] into [C54]  gives

         c
                     esc
      "
       esc
                     esc
                                      esc
                                                             "
                                                        esc
                                                              esc
[C59] W


                100 -
                      esc
                                  esc
                                                   esc
                                                          y

                                                                  (
                                                                       esc

                  esc
                                 esc
                                     584
-------
                 p
             .     esc   . .

      IT       10° - P        WSB     /w
      W    = _ esc          =  ( - )(y _ w
       esc   - — - -    ^ 100Ay    es
                     100 -  P
                            esc
 Equation [c6l] into [C56] gives



            P
[C62] W   + -S£ (y - W  )  = -i-
       es    100 w    esy   100
                p         p    p
      T »   Pi     SSC-i   /S     ©SC

      wes [ x -
            100 - P
[C66] w
       es    100 - P        100
                    esc
      "as
                    esc
 and
             P           P   - P
i  ^o-i         esc r      ,  s    esc

LC68] Wesc = 155 L  y -  (100-P
                               esc
             (P   )(y)   100  - P    - P  + P
LC69]      =   esc
   'J
                100           100 - P
                                     esc
                                     585
-------
                100 - P    P
              /         s \, esc,

LCTO]  Wesc = (100-P   )(
                      esc
 and
LCTI]  W  = y - W   - W
        c        es    esc
                  P  - P           100 - P    P

                /  s    eSC-\     '   -     S • \f
            y - (100 . p   ) y - (100 . p   )( 100

                        esc              esc



                    P  - P         100 - P    P
            r     ,  s    escx   , _ §_\/_eJic.\ i

            C x - (ioo - p   ) - (ioo - P   )(~I5o") ] y
                          esc            esc      r



              100(100 - P   ) - 100(P  - P   ) - (100 - P  )(P    )
            P    x _ esc _  s    esc     _ s   esc   -.

                                100(100 - P   )
                                           esc



              10* - 100 P    - 100 P  + 100 P    - 100 P    + P  P
            P            esc        s        esc        esc _ s   esc  -,

                                   100(100 - P   )
                                              esc
              100(100 - P ) - P   (100 - P )
            r _ s _ esc _ s

                      100(100 - P   )
                                 esc
              (100 - P   )(100 - P )
            r         esc         s
                   100(100- p
                             esc
             100 - P


LC73]  "c - t
 But want X  , and X
           v        es
          X  = W /W
           V    V  C
                                      586
-------
 and
          X   = W  /W
           es    es  c
   from Equations [C51] and [CT3] gives

              0.0196 x
                   ?  .
                    es) y
                100
       \ '
 and Equations [067] and _[C73] give
              P  - P
             ,  s    esc y
             ^100 - P   '
CC78]  W   = _ esc
        es    100 - p
             (P  - P   )(10Q)
|-G7oi  Y
LC79J  X   -
                  _     1QO _ p
                     s         esc

 where P .  P   ,  x and y are measured quantities :
        s   esc

       P    = Total sulfur analysis of residual +  elemental sulfur,  %
        s
       P    = Residual sulfur, %
        esc
       x    = ml of o.l NaOH, ml
       y    = weight of carbon + elemental sulfur  + residual sulfur  after
              acid leaching and drying,  gms
                                     587
-------
                          APPENDIX A-20-3

       DERIVATION OF  REACTION RATE EQUATIONS FOR  SULFUR
          GENERATION  - FOR CONTINUOUS ACID  CONVERSION
       RUNS  IN 8 STAGE, 4 INCH DIAMETER FLUID BED REACTOR
 Calculation of Overall Rate of Reaction Using Carbon Analyses
    Rvi=# mole
    Rc, Ib.  C/hr.
         ,  lb./hr.
          fo S In
                                                (yH2s)  > Vol. Frac. H2S Out
            100
                                                     , CFH @ ?0°F
                              SULFUR
                             GENERATOR
         .,  CFH & 70°F
         i
                                                RVO  = mole
                                                Rc,  Ib. C/hr.
                                                (RT)o, lb./hr.
                                                     % S Out
     (yH2s).j Vol. Fraction H2S In

                                               peSo>   100

Writing a material balance  over the differential element of volume, dV

     input  of acid             =  Rv
     output of acid            =  Rv + dRv
     disappearance by reaction  =  rv dV
                      RV  =  RV + dRy + (-FV) dV

                       =  d[Rvi (1 - F)]  = -Rvi dF

         where  Fc  =  fraction of acid converted.

Therefore Rvi dF = (-rv) dV
                         sV          XFo
                         f  -®L      [     dF
                        Jo  Rvl  " Jo   ^
                              V
                             R
                              •vi
                                     -r-,
                          (-rv)  =   „  ,c
                                     V
                               588
-------
                                   TTD2    h
                           V  -
                              Y • ll3' acidN/  lb. mole
                              Xvi
                                     hr.  /V98 Ibs. acid'

 the total material rate is

         T>       r,     Rvi
         «Ti  =  «ci + ~Z~ '* Rci XeSc


              =  Rci +  °p .V;L + Rci XeSc  =  Rci [l + ^f + XeSc]


        .•R .   _       •	RTi	
         Rvi  -
                                             TrD23iN
                       v
          V avg            -    Xyj           p        ft.-' carbon-hr.
                  70.5  RTJ Xyj  FC           lb. mole acid
                    Xyj
               x _   _- ^   "~™dU^ / " " ™~   O
                    £ VI


since  pc  =  36 Ibs./ft.3


                     RTi Xyj FC	    lb. acid
       (-rv)avg  =  3*2  Yl  ,  Xvi ,  v   w  ~ w ,   lb. C-min.
     [A-l]             3  H2S + H2S01|  - * 4 S + 4 H20
In order to relate the acid loading to per cent sulfur take a basis of  100 lb,
of carbon and '
let   Fv     =  fraction  of sorbed material that is H2SOi| (i.e. rest H20)
      Fc     =  fraction  of acid converted
      WeS    =  weight  elemental sulfur as adsorbed acid
      XeS    =  weight  ratio of elemental sulfur, lb. S/lb. C
                                     589
-------
            =  weight non-acid sulfur on initial carbon  (in matrix  or

                  adsorbed)

      XeSc  =  weight ratio non-acid sulfur on initial carbon  (in

                  matrix or adsorbed^ Ibs. S/lb. C.

      Ps    =  % sulfur/100




 Total Weight of Material = WT = Wt. Carbon + Wt. Non-Acid Initial Sulfur

                              -f Wt. Acid + Wt. Water + Wt. Sulfur Formed




wt. Acid  =  3.06 Ssai . FC3.o6          3>o6 Wesi
Wt. Sulfur Formed  =  h Fc Wegi  (by Reaction lA-l])



Wt. Non-Acid Initial S  =  100 Xesc
WT  =  100 -f- 100 XeSc + 3.06  f2  + FCO Wesi - 3.06
                              FVO
Wt. Acid Related S at Fc  =  WeSi + 3 Fc Wesi


                          =  weSi [1+3 Fcl


  '  _  Total Sulfur  _  	WeSi [l + 3 Fc] + 100
  •c    Total Weight     ^ + ^ ^ + j.^^tt, t F<=[u Mesi . 3^




     [Also   WeSi  =  100 J
Fvo'    ^  "BDi   J—  Fvo-
p.  =  _ 100 XeSJ [l + 3 Fc] + 100 XSG

 s°                          10° x
       100 + 100 Xsc + 3.06 (	==»*) + i^OO X-«n Fr> - 306
                  *^             Tji             ^"^d ^L  ^*
                                 V O
                98
and since Xv^ = — X     and rearranging
                32  eSi
                 100 XeSc •«-       '1 3-32.6 X   - 100
                326 X   [300 + P' (- -
                                    590
-------
Talcing a basis of 100 g. of carbon then the total weight of carbon and
sorbed acid is

   Total ¥t.  =  Wt. Carbon + ¥t. Sulfur in Carbon Matrix + ¥t. Acid
              +  ¥t. Water Associated with Acid
 if FV

    W.
             =  100 * ¥eSc
             =  Fraction Acid in Solution
     w
                                         =  3.o6W
                                                  eSa
                                                          v
Also
                 =  100 XeSc
          ¥T  -  100 + 100 XSc + 3.06 ¥eSa + 3.06 ¥eSa (X " ?V)
                                                          Jc-tr
       if Pc
              =  100 + 100 XSc + 3.06
             Ps _ jo Sulfur
            100 =    100
                                       F.
                                        v
                                                100 XSc
                                    100 + 100 Xsc + 3.06
     Also  XeSa  =
               ¥eSa
                100
Subst.     100 Xesa  =  weSa   int°  ps

                       	100 XeSa + 100 XflC
                       ioo+-iooxflc + 3.06 (100FXeSa)

                         PS [100 + 100 Xgc] - 100 Xgc
                               100 [1 - 3-06
                                             F
                                              v
and since the adsorbed sulfur is present as sulfuric acid
                                  Ps [100 -f 100 XeSc] - 100 Xec

                                        100 [1 - 3.06 —]
                                                      F,r
                                    591
-------
The three equations derived. and- shown in bp&oketsnaJreatfaafcoU&ed
to calculate the conversion of acid to sulfur and the overall rate of
reaction.  These axe general expressions.  For the reactor used in these
experiments

          D     =  U inches
          h     =2.45 inches
          Ns    =8 stages
          xeSc  =  °-28 (measured)
          Fvi   =  0.73

                 (-r)
Sample Calculation

For run SG-38 the experimentally measured values for the calculation are

          HT1   =  53 Ib./hr.
                =  .183
            o
                =  0.73
          Lv
          xg    =  .003
 c
                r .06^ (100 + 0-3) - 100 (.003) -.           lb. acid
v                    100 [i - 3.06 (-—-)                     lb' c
                      0.183 [100 + .3 +           ] ' 32<6 ('253) - °'
                         .326 (.253) [300 + .183 (•— -
          F        -  o.6l
           c
              ,    .   .0032       ..       .
              '
                             (n- ^    + .003)               hr.-lb.
                                   • 73
                                    592
-------
Calculation of Overall Rate of Reaction.Using Gas Analyses
   Re, #C/Hr.
   (xv)IN,
   Psi, % elem.  S
        , CFH @ 70°F
         i' vo1'  frac' H2S
                           1
                               SULFUR
                               GENER-
                               ATOR
                                                     ,  CFH @ 70°F
                                             Rc, #C/Hr.
                                                P_0, % elemental S
                                                 QW
By the same derivation as for conversion based on carbon analyses
-L-    r
RHSi     Jo
                     dF
                     (-'A)
     V
                       [ Fc ]
                ave
                                  -  N
Fraction H0S converted = F  =
          d                     1MHSi
                                     HSf
                                             " N
                                                HSo
                                           N-
                                            'HSi
                     r  Jio-L " %SQ -I
                 v        %si
                                593
-------
 HSi

Basis :  1 hr.




   RHSi = NHSi = C
          w    - f
          WHSo - L  359
                            F

          (q.T)  =  (qij   +    (^BS^      [By Reaction
          (*r>0 =  C * +  f 
-------
therefore  (-r )

              A
     ave
                       (359)(T)(D2)(h)(N)
                                  ,

                                  ^
                                                     (359)(3)(qT)1(YH2S)i
For all runs in present glass unit
              D = U inches

             Ng = 8 stages

              h = 2.V? inches
                       let Y =
(qr}i
                 (16)
but (-r. )    = rate ELS disapp.
       A 'ave         2



             = 3 ^"
                          ave
                                                      # moles H2SOi,.


                                                      ft. 3 c - Hr.
                                       595
-------
     .# moles Acid,. .98$ acid
     ft.3 C - Hr.'l# mole
                                               ft-3 cw 1 hr> \
                                                s # 0^60 min/
For SG-38
 (qT)i  = 381
    Y!  = .320
    YQ  = .088
=  °'9851

=  0.025^
                                      - 0.264 - 0.0282 +  0.00??]  (38l)
                                596
-------
                            APPENDIX A-20-4

   DERIVATION  OF SPACE VELOCITY DESIGN EQUATION FOR  S02 SORBER


Design of an SOU Sorber"
      Rc, #/C/hr.
   qj,  CFH % 70°F
                          D
                                  Temperature = t, °P;   T =  t + 1*60
                                      (Xv)0UT» # H2SCV# C
   (yH2o)
The fluidized bed is  neither a conventional plug flow or back-mix reactor,

however, for the following analysis a basis will be taken that the solid

phase is well-mixed and the reaction is plug flow with respect to the  gas

phase.  The plug flow design equation is
 [Fl]
             V
                  F
dF
                  F
                        -r.
                   vi
  v
               where F  = (l - ~ >
                      v        NYO
    Taken from 0. Levenspiel, Chemical Reaction Engineering, John Wiley and
    Sons, Inc.; pg. 10? - 109, (1962)
                                  597
-------
          The differential rate studies led to an analytical expression.  Therefore



     the  variables in Equation Fl   are



                                  5520              O.kO   0.63   0.73


 [F2J     (-rv) = Q (1.59X10^)6    T   (1 - |^g) 7^   YQ2



                                     for NO concentration  100 ppm



                                                 # moles  _    -#
                 where  Q = conversion factor to — - — — o irom  ,»
                                                 HP • •" I w •        Tf-
H2S% ir 60 min.  ,f  # mole    ..,.  36 #C -,

C-min.JL   Hr.    JL  9^ HSO  JL  ft. 3
                              # C-min.     Hr.


                             (6Q)(36)

                          =    (98)
 [F3]     Ran
 LF3J      s°2
    Basis:  1 hour
                       IK
 [F7]
[F8]     F
CF9]     'v - (i - 77— r- )

                   ^S02;IN



                                          598
-------
[no]
    The acid loading,  X >  will be  taken as  the  loading leaving a stage since

    back mix of the solid  phase was a basis taken for design.  Therefore
    Equation Fl  becomes after making a transformation from  F to y
    using Equations  F9  and F10.
                                                                  S02
[Fll]
      R
        SO.
                                     - P
                                   "vf'
                                                -d y,
                                                   so.
                                                 0.40

                                               so2

                                                         0.63   0.73
                  = (6Q)(36)(l.^)(lO^)e        _ _Xv_
                                98            k    0.38'  y02    y"
If the acid loading,
                                  ° concentration,  and temperature are assumed
    independent of SO  concentration the Equation (Fll)  can  be  integrated to give
 [P12]
         V
       K.
        SOr
              -1
  0.6

  ^  -
0.6  '
[P13]
         V
       Eso
                       0.6
                          r -i _
                          L J-
                                         0-6
                                                      0.6
                   but F   = 1 -
                                 (ysog)f
                                      599
-------
                                  (yso2}f
           therefore  (1 ~ F
                  and F  . = 1 -
            therefore   (l - F
                        0.6
[FlU]
  V
Rso.
                       'IN
                         'IN
)°'6  ]  C  (yso2)f
                                                   0.6    ,     .0.6-
[F15]
         0.6 P (y   )   V
                 S°2IN     ..     .0.6        .0.6
[F16]
       .0.60    ,     .0.60
  (yS02 f     = (yS02 i
                                                 V
                  (y,
                           qn
                           SO
[FIT]
                   0.6
                               IN
                                      98 (12)
                                                                                0
                                                                                       •(386
                                                                          2.    2
                                  DESIGN EQUATION
[F18]
              ,0.6   ,     .0.6
                                              Xv  .  0.63 0-73, 2
                                              3.38^ yo^  yHrtO    *
                                                     2    2
                                            600
-------
          Amount of SO  removal/stage H SO, Material Balance:
                           In = Out  +  Accumulation


                                but Accumulation = 0, since steady state is assumed
                                      = (3B6)(jr»  V98)
  want to solve for (X  ).
                      v i
J20]     ('
F21]     (Xy)f
                                      -  K
                                        ('
                                         ao
F22]
                                MATERIAL BAIANCE
                                         601
-------
                         APPENDIX A- 20 -5

     DERIVATION OF DESIGN EQUATION FOR SIZING OF  S02  SORBER


The 18" diameter S02 sorber was  designed on the following
basis :

     Linear Gas Velocity:  4  ft. /sec.

     Temperature :  200°F

     Inlet S02 Cone . :  2 , 000  PPM

     Outlet S02 Cone.:  200 PPM

     Carbon Rate:  60 Ibs./hr.

     Acid Loading:  18.4 Ibs. H2S04/lb.  C

     Rate Model:
                         5520
                  59x10^4  e  T   (1   Xv ) v  °-40 v 0.63 v  0.73  lb- H2S04
                 .59X1U •»  e     U     ^y      yQ2   yH20     lb. C-min.
         for NO concentration above  100  PPM.
Reactor diameter was calculated based  on material balance and
linear gas velocity restraints.  Linear gas  velocity is bounded
above by the entrainment velocity, Ut, and below by the minimum
fluidizing velocity, Umf .  The following equations from Kunii
and Levelspiel9 were used to estimate  Uf and Umf:
                                                 - 3-37
     Ut, spherical  =   [3.1 g (ps - Pg)dP]l/2 fpr 500000
                           Pg
          where Reo = dP PS
                  P       y
                dp  = particle diameter,  cm
                g   = 980 cm/sec. 2,  acceleration of gravity
                y   = viscosity of gas,  gm/ cm-sec.
                Pg  = gas density, gm/cm^
                             602
-------
                ps  = solid density, gm/cm^
                Umf - minimum fluidizing velocity, cm/sec.

                Ut  = entrained velocity, cm/sec.
The calculated Umf in air for granular carbon with a mean
particle diameter of 0.1 cm and density of 1.0 gm/cc is 0.87
ft./sec. at 70°F and 0.81 ft./sec. at 200°F.  In flue gas at  .
200°F it is essentially the same at 0.82 ft./sec.  Experimental
measurement resulted in a Umf of 0.5 in air at 70°F, which is
more than 407» below the estimated value.  This is not far out-
side Kunii and Levenspiel's +3470 predicted accuracy range.
Shape effects are considered the main reason for the 40%
difference.  The calculated entrainment velocity in air for a
particle diameter of 0.042 cm is 10.7 ft./sec. at 70°F and 11.9
ft./sec. at 200°F.

After allowance for a possible 4070 over prediction, conserva-
tive estimates of 6 ft./sec. at 70°F and 7 ft./sec. at 200°F
are obtained.  Based on these estimates of Umf and Ut a linear
velocity operating range of 0.5 to 6 ft./sec. is indicated.
Because a high linear velocity is desirable in order to mini-
mize the required cross-section area, a value of 8 times the
Umf which is 4 ft./sec. was chosen for the sorber design.

Having specified the linear velocity, the reactor diameter was
calculated from a material balance on sulfur.
     *Umf  is based  on  mean particle diameter,  whereas Ut is
based on the smallest  particle of significant  percentage in the
sample.
                             603
-------
Active C Rate, Rc>  Ibs./hr.
               100  Ibs.  C
Inlet Acid Loading  =  XVj.n =  0
Rc = Ibs. C/hr.
Outlet H2S04 Loading  =
  18.4 Ibs. H2S04/100 Ibs. C
                                   Column
                                  Diameter
                                 —D, in.—
                                         U,  ft./sec.
                                        "Vso = Outlet s°2, mole
                                                            frac
            IN-OUT  =  Accumulation  =  0
                                               Temperature  = 200°F
                                         Linear Gas Velocity =
                                               U,  ft./sec.
                                             = Inlet S02, mole
                                                           frac.

                                           Steady State Assumed
Sulfur Rate In  =  (Rc) (XVln) (||) + (U) (3600) (


              -  1.304 U(YSin)(D2)
                                                   (YSln) (|f|)
    Sulfur Rate Out  =  (Rc)(XVout) (|f) + 1.304 U(YSout)(D2)
                                      98'
                       D
                      F  0.046
                      [u(YSln -
                                     Rc
                                           11/2
                                     YSout)
   Using  the formula and the design basis  presented earlier,  a
   diameter of 19.6 inches was obtained.   Practical engineering
   restraints led to the choice of 18  inches for the sorber
   diameter.   The design conditions were intended as a rough
   guide  only,  and 18 inches was chosen as the most convenient
   diameter from an engineering standpoint.
                                604
-------
                        APPENDIX A-21

           SAMPLE CALCULATIONS FOR INTEGRAL TESTING


The sample calculations for the pre-integral operation are
given in most cases in Appendix A-20 when the derivation of
the equation is presented.  In this section the calculations
for integral operation only are given, but they are also true
for pre-integral operation.


A.  S02 SORBER

    1.  S02 Removal Efficiency

        For Task IV-A integral run, period 2, at elapsed time
        124 hours:

             Inlet S02 + SOs Cone.   =  2,000 PPM
             Outlet S02 + S03 Cone.  =  800 PPM
           PSA  =  100 [1 -
                =  96%
    2.  Carbon Attrition Rate

        For Task IV-A, period 2, 124 hours:

             Rl8D  =  0.188 Ibs. mat'l/hr. (dust rate collected
                         by cyclone)
             Xesc  =  0.0487 Ib. S/lb. C
                         „                   Composition
             PH20  =  6.3%                     of Dust
             PS    =  7.2%
RCD  =
                   [1 -  g  - 3. 0625 () ] (0.188)
                   - [1 - 2. 0625(0. 048/)j -
                   0.716(0.188)
                       0.900

                =  0.149 Ib. C/hr.
                            605
-------
    but dust collector collected 0.12 Ib .  C/hr

       RCD (Total)   =  0.149+0.12
       RGB  =  0.27 Ib. C/hr.
3.  Residual Sulfur Loading on Regenerated Carbon
    Recycled to S02 Sorber            [
    For Task IV -A, period 2, Avg. 111-126 Hrs .
         Pesc  = 4.03%
               - 1-8%
       Y     _        4.03        _  4.03
       Aesc  -
                100 - 1.8 - 4.03     94.17
       XeSc  =  0.0428 Ib .  S/lb. C

4.   Outlet Sulfuric Acid Loading of Carbon from S02 Sorber
    For Task IV -A,  period 2, 125 Hrs.
         PS    =  8 . 28%
         Xesc  -  0.0428 Ib. S/lb. C
         PH20  =  8%

                      0.0487) - 0.0428(1 -       _  ^8*
                   0.3265(1 -
              0.0474
              0.2176
              0.218 Ib.  H2S04/lb.  C
                           606
-------
B.   SULFURIC ACID  CONVERTER

    1.   Outlet  Sulfuric Acid Loading  on  Carbon

            PV   =  2.56%      Composition  of Carbon
            PS   =  19.64%     for  Task  IV -A,
            PH20  =  2.82%      period 2,  124 Hrs .


                , •                2.56                    2.56
                   100  -  19.64 -  2.82  -  0.6735(2.56)     75.82

                -  0.034  Ib.  acid/lb.  C


    2.   Outlet Elemental  Sulfur Loading  on Carbon

        For Task IV -A,  period 2,  Avg.  111-126 Hrs.

             PS   = 19.64%
             PVO  = 2.56%
             PH20 = 2.82%
             Xesc = 0.0428 Ib.  S/lb. C


                          19.64 - 0.3265(2.56)
           X
            esc  -  100 - 19.64 -  2.82  -  0.6735(2.56)


                 =  ^!'!?^ -  0.0487  = 0.2480  - 0.0428
                    75.olo

                 =  0.205 Ib.  S/lb.  C



    3.   Hydrogen Sulfide Utilization in Acid  Converter

        Task IV-A, period 2,  Avg.  115-124 Hrs.

             Outlet H2S = 0.048%
             Outlet N2  = 46.4%
             Inlet H2S  = 27.2%
             Inlet N2   = 27.2%


           pH2s  -  ioo[i-^04-8-^i


                 =  99.8%
                              607
-------
4.  Acid Conversion to Elemental Sulfur in Acid Converter
    Task IV-A, period 2, Avg. 111-126 Hrs.
               =  XPS from sample calculation, B.2 =
                     0.205 Ib. S/lb. C
               =  Xv from sample calculation, A.4 =
                     0.218 Ib. acid/lb. C

       P    =  1QO(98H°-205)
       PVC     10tH132M0.218'
            =  70%
5.  S02 Breakthrough from Acid Converter
                      qN2      = 121 CFH @ 70°F
                      YS02     = 0.0115
                      YN2      = 0.464
                      Xvi      - Xv from sample calc.,  A.4 =
    For Task IV-A,                 0.218 Ib.  acid/lb.  C
               6      RT       - 31 lbs' -t'l/hr.
      Hrs.             (PS)KF   = pesc from sample calc., A.3
                                   4.03%
                      (PH20)KF = PH?0 from sample calc., A. 3
                                   1.8%
       7ort   _  	0.2539(121)(0.0115)	
       ZS02  -                          __   _
                (0.464)(0.218)(31) [ 1 -
1
                                         100    100J
             =  0.12 moles S02/mole acid sorbed on C in S02 sorber

6.   H2S Breakthrough from Acid Converter
    For same task and time period all numbers same but addi-
    tionally
         yH2S = 0.00048
       Z»oc  =    0.2539(121)(0.00048)
        H2b     0.464(0.218)(31)(0.9417)
             =  0.005 moles H2S/mole acid sorbed in S02 sorber
                           608
-------
C.   SULFUR STRIPPER/ H2S GENERATOR
    1.   Inlet Sulfur Loading on Carbon
        From sample calc. B.2 = 0.205 Ib. S/lb. C

    2.   Inlet Acid Loading on Carbon
        From sample calc. B.I = 0.034 Ib . acid/lb. C

    3 .   Outlet Sulfur Loading on Carbon
        From sample calc. A. 3 = 0.0428 Ib. S/lb. C

    4.   Hydrogen Utilization
        Task IV-A, period 2, Avg. 111-126 Hrs .

             (YH2)0 - 0-0
             (YN2)0 - 0.524
             (YH2>i - °-508
                    = °-492

                =  100 F 1 -   <°)/°-524   1
                -  100 LI   (o.508)/0. 492J
                =  100%

    5.   Hydrogen Conversion to Hydrogen  Sulfide
        Task IV-A, period 2, Avg. 111-126 Hrs.

             (YH2S)0 = °-277
             (YN2)0  - °-524
             (YH2>i  = 0.508
             (YN2)i  - °-492
             (o  = 121
             (qN2)i  = 100
            /„   N
            (PH2S)U  =
                    -  62%
                               609
-------
6.   Hydrogen Requirement for Acid Conversion
    Task IV-A, period 2, Avg. 111-126 Hrs .

         (YH2)i   = °-508
(YN2)i
(qN2)i
(Xv)0

(RT)KF
(pS)KF
                  = 0.492
= Xv from sample calc. A. 4 =
    0.218 Ib. acid/lb. C
= RT from sample calc. B.5 =
    31 Ibs./hr.
= PH20 from sample calc. A. 3
= pesc fr°m sample calc. A. 3
                                                 1.87o
                                                 4.03%
       a
                98  0.508   100
                                 _    _
        H2     386 0.492  0.218  777^    ITS   4.03i
                                 31[1 ' Too ~ Torn
            =  4.1 moles H2/mole S02 removed in S02 sorber
7 .   Carbon Burn-off
    Task IV-A,  period 2,  Avg.  111-126 Hrs.

         YC02  =  0.0035
         YN2   =  0 . 492
                 0.492386
                0.027 Ib.  C/hr.
                           610
-------
D.  SULFUR CONDENSER
    la. Sulfur Recovery - % Sulfur Stripped
        Task IV -A, period 2, Avg. 111-126 Hrs.
             Xes   =   Xes from sample calc. B.2 = 0.205 Ib. S/
                          Ib. C
                      - (PH20)KF   (FS>KF-|-3iri  1.8  4. 03-, _
                             —    100  J  3Ui  roll  TolTJ
                          29.2 Ibs. C/hr. from previous calc.
             Xvo   =   Xvo from sample calc. B.I = 0.034 Ib. S/
                          Ib. C
             Res   -   1.75 Ibs. S/hr.

                       r
                       L
                        [0.205 + 32(0.034)/98](29.2)J    6,31
                =  28%


    Ib. Sulfur Recovery - "k of S02 Recovered Based on S Collected
        Task IV-A, period 2, Avg. 111-126 Hrs.
             Res      = 1-75 Ibs. S/hr.
             (Xv)o    • Xv from sample calc. A.4 = 0.218 Ib.
                          H2S04/lb. C
             (RT)KF   - RT from sample calc. B.5 = 31 Ibs./hr.
                        PH20 from sample calc. A.3 = 1.870
                        Pesc from sample calc. A.3 = 4.037o
                               611
-------
Ic.  Sulfur Recovery, % of S02 Recovery Based on S Values
    in Outlet Gas of Acid Converter
    Task IV-A, period 2, Avg. 111-126 Hrs.
         (YH2S)0
         (YS02)0
         (YN2)0
         (o
         (Xv)0

         (RT)KF
         (PS)KF
         (pH20>KF
  YH2S from sample calc. B.5 = 0.00048
  YS02 from sample calc. B.5 = 0.0115
  YN2 from sample calc. B.5 = 0.464
      from sample cal. B.5 = 121 CFH @  70°F
                       A.4 = 0.218 Ib.  acid/

                       B.5 = 31 Ibs./hr.
                       A.3 = 4.03%
Xv from sample calc
  Ib. C
RT from sample calc
PS from sample calc
- PH20 from sample calc. A.3 = 1.8%
       (PSR)
            ss
 100 [ 1 -
                                98[0.00048 + 0.01151(121)
                           386(0.464)(0.218)(31)
                   100[1 - 0.125]
                   88%
                           612
-------
                        APPENDIX A-22


                      COMPUTER PROGRAMS
1.   Stepwise Multiple Regression Program                  614

2.   Program To Make Statistical Calculations on S02       621
      Data

3.   S02 Sorber Design                                     623

4.   S02 Sorption Rate Computer Program - Bench Scale      625

5.   Sulfur Generation Rate Computer Program - Bench       627
      Scale

6.   Computer Program for Gravimetric Flow Experiment      629
      Calculations

7.   Computer Program for Calculation of Differential      631
      Sorption Rate and Model Evaluation

8.   Computer Program for Material Balance Rate            633
      Calculations and Space Velocity for 6" S02
      Sorber

9.   Computer Program for Calculation of Integrated        636
      Pilot Plant Results of Westvaco S02 Recovery
      Process from Steady State Data
                              613
-------
 c
 c
 0
JL_
                               APPENDIX A-22-1


                  STEPWISE MULTIPLE REGRESSION PROGRAM
              DISK OPERATING SYSltM/3t>0  FLIKTKAN   360M-FQ-l   CL  3-d


PROGRAM NUMBER C9(H<»-IBM                                            0005
1130 STEPWISE MULTIPLE REGRESSION PROGRAM, 3/14/66                   0010
REVISED FOR  MULTIPLE RUNS FROM ONE SET  OF DATA BY SAM THOMPSON   3/5/1969
       DIMENSIONS


       DIMENSION ftATM301.CD^Sril3l.lTRANIt3;3).JTRftNl(33)rKTRAN(33).LT^AN(3

      13),RSPNS(8)
       DIMENSION RIJ(30,30),XBAS(30), SIGMAI30)
       DIMENSIN  IGBIQVnB(.3Q) t IplPIt DATYL20>
 C
 C
 r
oeFiNE : oATAi ^:*"*:**::'*;';;:^:i;?;v*:•• >•;?»• -:i•• s
       DEFINE FILE 51 <.00, 100,L , I FA )
       DEFINE FILE 6(^00,100,L,IFB)
c
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- -- ?-:••'• -;;'•< :-;.?•'•• , I :.-;•.>; -v^M^fVi:*!^
M1N = 1
MOUT = 3
READ CONTROL CARD
READtMlN.Sli ..MX.IAt,.NQBS«.<».8.UN..Ny.lNiMQBS2...
;.: ;«i .: ".'•>;:'.;, s: >f ft;/ ;-;-j'ii?:s^:^?5:J^:?.-" •S'f:S>i:S?5*'K%>:S? -;; .': V: KSsSS* •&". SXi?':K J
: :S'-;-^s'---.rf:S%its;.is:;i*ss?ftSS SsSsSfftiX ?KK:.&K:. -s>;-a> :ts:ss;* ••.•-is;s;iKs;; :' ••.?:%*:%*? jwi1

•

0300
5 FORMAT(5I -
0104
'
                                     614
-------
 08/13/71
               FORTMAIN
                                                                                   UOD2
C
c
c
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•c
c
c
c
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NY = NUMBER OF SUBSCRIPT OF Y USED,
FIN= F-VALUE MIN TO BE INCLUDED IN REGRESSION, MUST* NOT BE LESS
THAN FOUT
FOUT= F-VALUE MIN TO BE OUTPUT DM PRINTOUT
IORGN * 1 TO SUPPRESS CONSTANT 	
« 0 OTHERWISE
	 "...- 	 I.RES* BLANK ...3d ZERC TO 3M1T RESmiJALS ANALYSIS
= 1 TO GET RESIDUALS AND ANALYSIS
NL= NUMBER OF HEADER CARDS TO FOLLOW.
ICOM = ALPHAMERIC COMMA
LGANT = 1 TO PRINTOUT A\|Tl-L03 OF ACTUAL Y VALUES IN RESIDUALS
^ANO PREDICTIONS:, .BLANK OTHERWISE.
	 LAHQV ..*. L^IF R£SiUUALS;:Af<6::SC5xB€; PUNCHED FDR COVARIANCE RUM.
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WRITE1MOUT.54}
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                                 :Uaoi!&>i>
       DO  1000  1=1, NL
       WRITEIMOUT,
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  1000 CONTINUE
       IF(NTRAN)641,730,700
 C •«.;:-
   70Q
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    71 FORMAT<^OI2)
       IF{NCONS)b41,730,720
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INITIALIZE.
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       DO 90 J-1,MVAR
                                                                        3<»60

                                                                        0480
 C
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l?B *  I

ftFAft RAIri  UATA
mSK FILE NUMBER  k.
       DO 110 I*1,NOBS2
             'tFni(P^TX'-"yJ3
       OATX(NVIN>
       IFI NT R AN) M1 * 8 W» 750
                                          615
-------
UH/13/7 1
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c
,c
c
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c
A


c
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r


750


760
770
780
790
800
810

820

830
840
845
R47
850
860

870
883
TRANSFORMATION OF RAH DATA
CONTINUE
DO 850 M= lfNTR«t^.*.-&>::^
IltlTRAMM, ,-
JJ=JTRAN•:>.•'.;.•: •'•:•-.••'' •;.•• >•:;-••-' - • "
z*t^i^B?i*iliifi^^
X(J1=-XIK»
DATXI JJ)=-OATXIKK)
GO TD 850
X ( J ) =LOG X 1 K 1 :';t«.% :-V ;^i:::;;:;;?;;:J>::Wf:v;::4^ ^V.;;" : ,\. '< i^ ;, :-',i':'-
0 AT X 1 J J 1 = AL'QG ( 0 4TX f KK| l^i;:;!!^^^ i;l'::« ::;i; ::::i
GO TO 850 :..
X(J)«1/X(K>
DATX(JJ)=l.O/DATX(KKI
GO TO 85Q
*ij>*xi<^x(Li^y
DATXI JJ)=DATX IKK) *OATX(tL)
GO TD 850
XU)sX(K)/XlU

.GO :. TO...S.5Q 	 ,. 	 x 	 • 	 x 	
XIJ)=X(K)+C(L) ^_^
DATXI JJ)=OATXIKK)+CONSTILL> '^
r,n TO S5Q
DATXI JJ)*UATX{KKJ*CaNSTtltl ' ^ - ' - ",
. r,n in HSO 	 , 	 , 	
DATXIJJ) = DATXIKK)**CONSTILL) / 0
GO TO 850
r>4TX(,i,M = <~riN5TIKK1>i"*r-RNST(M ) , i
CONTINUE:;.. • .^iii;*:;|^
WRITE TRANSFORMED DATA IN DISK FILE 5.
CdNTINUg-'v^^;--:-^^^.,: •::'-::;i.:-;^-rW'-:V^i::^
COMTTMIIP.,>4fe:';j:^.^:l:.«:-'tyi;::^?^
IFINOBS-I )110, 883,883
DO 100 J = 1,NVAR
0540
0545
:';0560"/-:--V::i^:;:.^::;
, -: • :. •;•.;; , .;.•;• •:-..
•:. OS W.:i-.;,i»?%.^. -:•.:.
0580
0590
:S.-:^::..^S.SI:v:i'-
S06'3Q:;::'4:Slf-*T:
0640
0660
i^^il^jyi
0700
0720
'i^-.?''.^*:^^.;!-!:
0760
0780
0790':Kj.::i:-^:.*:'w;:--
iVSIIill^lslii
Ofi.i'S-WK-::'8K SK™'*
0820
0840
0850

||||M

•0 895'- r • • '•
: ... . .: . .,-. •:. - r: • .. •- •• -.
0920
       IF!IORGM)U90fS90,fl85
  885  X6ARI J)  =  0. 000,OP;;;  J||
   ..:''•;&.'.'.A.-':....'.: :•:• -.' .' -:.-'.: -S:lljS:iiijijl:
                                                    616
-------
08/11/71
FOIUMAIN
                                                                                OOJ't
  890 DO 100 K=1,NVAR
  100 RU(J,K)=RIJU,K)+DATX( J)*DATX(K>
c
c
c
c
c
L
C
C
c
c
c
c



.!;•:*-;.>•

t jv
C
C
r

c

110 CONTINUE
COMPUTE STANDARD QEVIATIQN$*SQR ROUTE 4S AND STANDARD DEVIATIONS
DO HO 1 = 1, NVA*
XBAR(I)=XBAR •:• -.-. u K-'-A:-?:: ••>•.•.:;:?- . ?;• :•• •'•wmx
TRANSFORM SIGMA VECTOR FRQVI STANDARD DEVIATIONS TO SQUARE
ROOTS OF SUMS OF SQUARES.
• » ' * I - DO ; -:3 1 0 '"• 1 *-i V..N V A *i * s;;>:y :;#>'•: ^ ^> ^ *i :•: »Pi; Ji;i4? :;!s^ I '«;' V. if >-.;I::- riij s ^ .; .£s • ^i?^ . &. >; :;.:O-,:; . : :.':; ;. : :.- :^
BEGIN STEP NUMBER NSTEP.
200 NSTEP*NSTEP+1
riF=nP-i fl- •:•..-,'.: .';'.'''•>'•; <..- ./:.7:i;:;i.:: ':.•••••': p:£« X *&%« A ^'xifa ^•.^^•SSfr^fr?;* i----:'\,"\.-^;, ,.•• .'. '.
0950
0960
0970
0980
0990
1000
1010
1020
1030
1050
1060
1100
1110
1130
1150
1160
1170
1180
1190
1200
1210
IllliSilll:
1270
1280
1290
1300 :•-..; ..-••?'•••• •'.'"..
i/310' ''-''-•: -5 *' '••'--.• •'."-'
;.:.'.:>^:x;|;:fh::;;:-Jv:- -••:•'-.; .
1320
1330
W4SSS
1360
1370
1380
1390
                                           617
-------
08/13/fI
            KUKlhAl.'-j
                                                                                 0035
c
c.
c
c
c



c
c


-: C
:" C
C

W[:: ••••:
c
c
q
.;>:'"::-V:.'

VMAX=0.0
MIN=0
FIND MINIMUM VARIANCE C3NTUBUTION OF VARIABLES IN REGRESSION
EQUATION. FIND MAXIMUM VARIANCE CONTRIBUTION OF VARIABLES
NOT IN REGRESSION: EQUATION.
DO 300 I=l,MINOV
IFIRIJI I, 11-. 03 1) 300, 300, 210
210 VI = RIJ(I,NVAR)*RIJ!NVAR,I)/RUUfI)
I F J V M 240 , 300 , ZZOy^- ^.\;- - ;: ,- . ytf f ''. •':.•: T^- ; :^'^^?^^'^^::- '' • 'Mv
230 VMAX=VI* •••• .,:;;';-:.:i:^
NMAX=1
GO TO 300
240 \IIN = NIN+1
1D(NIN)=I
COMPUTE REGRESSION COEFFICIENT AND ITS STANDARD DEVIATION. 	
B(NIN)-RIJ( I,NVAR)*SIGMA(NVAR)/SIGMA.-':-mii-^^ fW^;<
NMIN=I
300 CONTINUE
JFININ) 641,460,400
«' COMPUTE : CONST 'MT^:X£R%$<-*;&:M$Syt%s
....;.•'•.'..• ••••.:. •.,;•;:.: : ?•'. ;••?:•, i ; JS&&.7 'i:l*lx :^SC^S^:SI^^Sl?^;;^:fi:SSSi&SI: J ' 'sQt : :?«•. • ?i >f M& SI
400 BSUBO=XBAR(NVAR)
DO 410 1=1, MIN
410 8SUBD=BSU80-B{n*XBAR,<^>
: BANT I « EXPIBSU80J
-: K1FINFNTI 64L.AfiO.00 	 1..'...' 	 ^ 	
OUTPUT FOR VARIABLE ADDED
57 FORMATCOSTEP MUH&ER * , I2» 10X» «£NTER VftRlABLg S12I'
58 FORMAT!1 STANDARD ERROR OF ESTIMATE"' , E 15.7 )
R-( l.-RIJ(NVAR,NVAR) )
IDFN=OBS-DF-2.3
1420
1430
1440
1450
1460 : :
-— 	 	 . . : .. .:'. ViV.:-" •' •
1470
1480
1490
1500
1510
k 1520 . ...
1530
1540
1550
1560
1580
1590
"^V:••;-::;^i620•;^l;F•:?.:;:^I
1630
1640
"«&: ^V^" .V^';: '' ''• i-P }
'^Xiti 60" .K j ;•;;; .:.;;: j: .; •;. 1;
1673
1680
1690
1700
1720
1730
1740
1750
1760
       iDFD=OF«-1.0
      F»{SIGMA(NVAR)**2-(SfOF,e**2)
      MBfTFIMOUT.gqt R.1QFN.IDFO.F.8SUBO.
   59 FORMAT!' R SOUARED =',E15.7,/f
     l« GOODNESS OF FIT,F!',14,',',14,')=',E15.7t/t
     ?' CONSTANT TERM « « . E 15. 7 . 7X . ' ANTILDG  CONSTANT  TERK  ='fF.15.7t^,
     3'
     4* '
VAX
C06FF
STQ OEV
T VALUE
BETA CDEFF' ,/,23X,-
                                         618
-------
08/13/71
FURTMAIN
                                                                                     03J6
430
63
C
- C 	
C
c
c
c 	
c
450
J^t;'J:
c
c
c
460
c
C
C
470
77"ife£i\'
c
c
48.Q
••v:S, . $•*
c
c
500
: 	 5,1ft
, „ 120.
530
550
"'
DO 430 I=iiNlN
J=ID(I)
T=B(I)/SIGB(I)
WRITE(3,63)ID(I).Bm,SI&BIM,T,UJU.NVARI
FORMAT!' '.I3,lX,£l3.5,lX,Ei;>.6tFll.4, IX.E13.5J 	
.COMPUTE F LEVEL FOR MINIMUM VARIANCE CONTRIBUTION VARIABLE
IN REGRESSION EQUATION.
FLEVL=VMIN*DF/RIJ(NVAR,NVAR)
IF(FOUT+FL£VL)460, 460,450 	
miTiALlM FOR HHOVAL OF VARIA&LE * FROM EQUATION.
K=NMIN
NENT=0
GOiTO.500
COMPUTE F LEVEL FOR KAXIMIM VARIANCE CONTRIBUTION VARIABLE
NOT IN EQUATION.
IF(FLEVL-FIN)65D,600t470
INITIALIZE FOR ENTRY OF VARIABLE K INTO EQUATION.

OUTPUT FOR VARIABLE DELETED
.FORMAT i « 0 $ T EP '. ^U;MttEM*ri,2 » lOX i rOEtETE V ARI A'B"L::6::;;:;:;«> mK^lMSik
UPDATE MATRIX
D D 540 J * 1 , NV Aft
I F ( 1 -K ) 5 10, 540 , 510 ^:£&&
r nwr i MII C 	 ^g^^.^>*»«^^€:^^ 	 g^A.^.- -^|-^./
DO 530 J = l.NVAR
IF(J-K)520,530,520
CONTINUe
CONTINUE ,
Dfl 560 J»1.NVAR 	 ' 	 ' 	
IF(J-K)550,560,550
RtJ(K,J)=RIJ(K,J)/RUlK,K»
-CDNTINUE
DO 580 I*J.fNVA«'" \;:':\l ••^r+u-f^f/'/^^^.^lA^
1910
1920
1930
1940
1950
i960
1970
1980
1990
2000
2010
2020
2040
2050
2060
2070
2080 ;
2090
2100
;.:;^|:::i;^'- : ^2110 :• :y :i
2130
2140
j||||||||P
2170
2175
iiisy K iZly y \:- :•:<;. ':•:.• X ;:$V:' if. ''( :. ••: :';/' fxf
•;ll':P::::-i:*; ';•> -:y Hty ?<<$?^
2210
2220
2230
2240
2250
2260
2270
2280
2290
•^;.-'«i,.- :—'••'- 2300 :;,.:••<> •
                                                   ifijaiSS;::
                                          619
-------
JB/13/71
                   FOK1MAIN
                                                                                   0007
570 RIJ(I,K)--RIJ([,K)/RlJ(KfK)
5EO CONTINUE
R I J(K,K) = 1.0/RIJ(K,K)
GO TO 200
600 I f i I RE S ) 6 1 0 , 640, 610 ^v.v ,o: ; fesil^^ < A.fc:':M:'.
•• " c •? . •' :. •••:; ;•. • I* f ':< -.5 -: :;;;v;:;;;; ^i^;:> :^Mll?®^&li;v
' C '- MUNT RESIDUALS :-;.-o-:^'-:y:';'.;::»:S;V^^
C
610 IFA=1
WRITE(MOUT.67>
67 FORMATCO 06$ ACTUAL ESTIMATE
:i C
C READ TRANSFORMED VARIABLES FROM F1L6.5 	
C
NMBER = 0
KPUNT = 0
SUMR2S0. 000000 ' >« *'.^;li :•; •:;::>.: !3f*',i;M ;j. •
DO 630 K=liNQ8S2 '!? S W Ji1v"y;:i -:'\ ' v; : % •
READI 5« I FA ) ( DATX 1 11 , I * 1 ^NVi«WlH^I&V-:wS-;
EST=DSUBO
DO 620 I=ltNIN
J=IDI I )
620 E ST=E ST+ B ( I ) *OAT X ( ji^s:-?: /:;:-:'s;.;iii;:::vX:'':::; vj;>-;.;.;:.:.:j ;:-;;?.s;. :;.;:
•< IF I LGANT ) 624t62*V 622.:!fel£ "^ •;:X:'^;^»tlrf
622 E.ST * EXPIESTJ : : •, ^'f3&?£'^^;-Mi&i&£.
2310
2320
2330
2340

2370
2380
RESIDUAL*) 2390


2*30
2440
• >i;;;iy |l|Sillli:. • ?2I
624
      DATX(NVAR)  =  EXP ( DATX( NVAR) >
      RESID=DATX(NVAS)-EST
   6B
    WRI T£ { MOUT, 68 )
    FORMAT 1..'. ...» , lA^fel2.fe'Xi
      IFCLANOV)630,630,625

      PUNr.H RESIDUALS  FDR  ANALYSIS OF CQVAR1ANCE  RUN.
625
      KOUNT * KOUNT  *  I
      MMflFH ...at... MMBPi-t. .».  .t
      RSPNS(KOUNT)  =  RESID
      IF(NMBER-N08S2)626t627»626
  627 WR t TE121VM RSPMS (>» > *;
    4 FORMAT(
 	,	xnuMT ^
630
      CONTINUE
      WRITEI3t69)SUMR2
      FHRMAT ( / , 7Xf
2490
  640

  Ml CAI I  FXI.T;
      END
                                                                             2620
                                          620
-------
                               APPENDIX A-22-2

       PROGRAM  TO MAKE  STATISTICAL CALCULATIONS ON S02 DATA



                                      360N-FO-451   CL 3-8


C      PROGRAM TO MAKE  STATISTICAL CALCULATIONS ON  S02  DATA
C
C      DESIGNED BY G.N.  BROWN
C	m....WRJ.lTEJJ__t^Y_SA['1  THGMP_SO_N_ HAY 12,  1971

C      FIRST  2 CARDS CCNT A IN 'AI..PHAMEP. IC:" IOENT { RCAT i (J-'-J  OF ' L-QUAT fON USED. •
C    _coo-  =_ cor;Fi:|r.iF._Nj__p_Rr:Viour,i.Y JIALCUI.ATIZD FUR USE  IN EQUATION.
C      POWER  = EXPONENT  USED 1 iSTu'oUAT fON         ''            '	:—~~~
C      DMEA.N  = MEAN DEVIATION
C	R_M S  = _R p0 T_ M F. A N  S U UA R E_D If V I A T I 0IM
C   .,  ::R~ATL-C"UT~= CALCULATTD" RA I E  """'^       ~—— ~   ™- ,_-,,„__	
C. .. ;:  .SUM2  = RESIDUAL  SUM OF SQUARES


       DIMENSION RATf:( 100),X(100! ,RAT6C( 100) ,DIFF( 100) , ID! 160) , I DATE (3)
       DUUIJLE PRECISION  ARUN
    2 FORMAT!10F8.0)
   _iJL_Fl^J:!^! l^f ip_vO]	
    A FORMAT! IH1,'  RUN  NUMBER" = ',IX,A5i5X7313,/T
    5 FORMAT(80A1)
    6 FORMAT!'  RESIDUAL  SUM  OF  SQUARES  =',E12.5,/,' MEAN PERCENT  DEVIATI
     '••• FORMAT!1  Xfl ) ,GMS H2S04/G«:C>;:> ^ArE,^:GMS H2S04/GM C-MIN :   CALCULAm
     1TEDRATE,  GMS .H2S04/GM" C - MIN.: -:::: .'s:' :-i ^ >K D IF F. t
    8F^MATsXiFlO. 5, 1 3X ,F 10. 7 , 22X FlO . 7, IVX, F10. 7}
    9 FORMAT!/,'  MEAN  DEVIATION =',F12.7,'    RUDT MEAN SQUARE  DEVIATION
     1=',F12.7>
   10 FORMAT!/,5X,'::::T=I»F8.0,5X,'   XS= ' , F8.2, 5X,'. YS02 = ' , F8.5, 5X f '
  , :, 1Y02=' ,F8.3,!>X,« YH20= ' , FB. 3, / , 5X, ' -E/R = ', F8.0, 5X, ' ,    A= ' , F8 . 3 , 5X : :

     3677F     "  ""    —        •  •—   	         -*    —   —  —
   11 FORMAT!I5)
      M1N
      MOUT  =
      READil
      READ(MINf3)RK,ER»A,B,CiD
   20 READ!WIN,1)ARUN,1 DATE,XS,TFR,PC02,PPMSO.PPMNO,P02, PH20, PH2SO, T
  	^1 F ( T ) 100, lOOjr.25
     '"vTRY'f E"( M'bln,A );::.AP.U'N ,: 11
•r-iS; >•<£? ' WK 1 I t t fiUU ) it I  l\*.\jn I I U «;»,..&: ;:.:•,,;.;.•. .;.;:i>.:.vS:: :;;>*:•:!..; ...> ]f - *fA ••KS:v.;:f :^:?:;\;:x?S '•;Xy:?-.!^&?y-i^y?\:'.
W&-: REAOtMINtMi'—f^^S^
Svt:'-:.:' WR1 TE (MOUT, 5') h D!"[')", I ±r''°**'&™^ w;'s<*-?:^y.sfw:ww:*%KW?V»?*W#~;-» -.-^•
      WRITf(MOUT,5)(ID(I I,1 = 81,160J
      YS02 * PPMSO *  0.000001
      Y02 =• P02  *  .01          	
      YH20.= PH20  * .0V<>t/3• jlyp
      WRITE(MOUT
            ^QUT ,\i'0) T, XS, YSq2;»'Y02vyH2pV£R t A,:0CV^^
      READ(MIN,2)(X!I),1=1,Nl)
      READI MIN,2)1 RATE(I),1 = 1,Nl)
||pfKIRt^:«{-NCl^
                                     621
-------
08/18/71              FORTMAIN
       IF(KTRL)30,'»0,30
   30  NCUS = NCOS +  1
   40  NCUS = NCDS +  NCOS
       1)0  45 I  = It NCUS
    ~"READ(MIN,~2T~ .......... '  "
   45  CONTINUE
     _SUM1 =_0.00_
       SUM"? '= oToo      "  '
       SUM3 = 0.000000
         __    _ _   _______     __
      DO" 5o"~r=f,Nr   ~    "         ~ ..... ~~" ..........
      X(I)  = V
             __
            = SU"M2 +" OJ=Fl
      SUM3  = SUM.'* * D1FF( 1)/RATE( 1)*100.
   50 CONTINUE
           =  SUkT(SUM2/Mll
      APD  =- SUMS / t,ii
      WRUE(MOUT,8) (X( I), RAT Ft I ),RATEC( I ),OIFF( I ) ,  1=1, Ml)
             fr'-OUT ,6) '.SitAPU
      GU  Tn  20      ...• .  ;. 4-  •-
      . c AL L  F x i T   . ' ;'.'." , ;; , : ;:-;'
      END
                                     622
-------
                              APPENDIX A-22-3

                             S02 SORBER  DESIGN



           DISK OPERATING SYSTEM/350 FORTRAN    360N-FO-451   CL  3-8


       REAL NCU
 C
 C     PROGRAM  NUMBER C4762
JC _______ , ___
       DESIGNED bY G.N. BROWN   .  .....   ••.":.  ,.•"%.,: ;..;..•. . -*• .7 :..,
                               ::'::
       S02 SOLDER DESIGN
     :  DIMENSION  ll)( 10) , 1DATE(3),X\MSO),YS02(U50),P'SG2(0!)0)
     :1  FORMAT ( 10A1 ,^X, 312, 6f: 10.0)
    _2JEMMI.( SF1Q.01          :-\_^ll'	,	_ ...  ...	
     3  FORMAT! 1H1,/, '    .   S02 S(Rfl£* DESIGN!',/,/,
      1'  RUM  NUMBER1 ,IOA-1, '    BATE ' . 3 I 3,/, /
                                 ^.S^.J-BS.../!!!..1
      3'  OUTLET  CARBUM LOADING  = ',Ft>.5,' LflS ACIO/LU  :
      . 2...'  I N:;UE_S_.CJU_B ON/ S T A T. E > ' , ,
      1  F5.2)
   '  8 FORMAT!' OJTLET  S02 CONCENTRATION  =',FIO.O,'  PPM')
  _.9.JlQRilAl.JL/_,J
       MX:,- ..3,;
       MY' - 1 ;
   ID  READ IKY, 11 ID,IOATE,NCJ,OT,YS02l,YS020,XV()ur,YU2
   11  FORMAT!/,'  SPA:E VELOCITY  =',FIO.O,'
    13  FORMAT!/,'  PRESSURE DROP  ACROSS CARBON =',F9.2,'  INCHES H23',
     ,1  ., .    /,'  PRESSURE DROP  ACRDSS PLATES . = ',F9.2,'  INCHES H23',     :: :
   • ••': 7        "/._'  TOTAL PRESSURE  DROP  ACROSS STAGES  ='.F9.2.«'  INCHES  H20'
     3)
    1«  FORMAT!/,5X,'     T=',FO.0,5X,'    XS=',F6.2,5X,'  YS02=•,F9.5,5X,•
            , F. 8. li3XJ.l_yjJ7.Q£l1__tLX.,/,5X, ' , z.E7_izij.F_ 8 . .Qxf.X.i .1	A=1,.F 8. ...3.,_5J(_
     2,'     0=' .FB.3.5X, '     C=l,Fa.3,5X,«   ,, 0=' , Fy . 3, / , ^X, <     K=',F8.
                   •  .: .  - -  '••••';.'.• -:--- ' •   ••:^v;:;;'^;-i.r  ;•'.-•'  '"  •'•••"•
                   '     RATE EXPRL-SSION^ USED 1 NJ)ES1G:SL_C A.LC.JLAT H'JS '././.
     1'  RATEC(I>=COEFF  ^ ( 1-X I I) /XS ) ** A « (¥502**^)  *  (YiJ2**C)
     2D)',/,«    WHE^E  COEFF=K *  EXPI -E/R* ( I/ I Tt460 ) ) ) ' )
      LJ5
      CF  •  0.9000000       ... .. : " :  V. .',.• J  .?':;:; i^'VVi'— "'•-•j'^ ' '^'- ':'";
      I F « 1 0 AT E ( 1 ) ) SOD , 500 , 20  A-; ; : " / -S"^; i^JlA^^^ '; :-'^' ^
                                   623
-------
00/19/71              rtl'UMAIN

    20 «U-AniMY,2)YH?0,l>N3,Hrl),T,RC
       XVOUI  =  XV3JI  *  (98./A'i.)
       OTS =  OF * C,92./!>30. )
     _PS021  =  YS321/3..0QPPQI   	
7	  PSL)20~=  'YSC120  /  0.000001

_^._   YSiJZM ) = Y.SQ2I	
       PS02I i )-YS;)?( n/o.uooooi
       XV(I)=XVOUT
	FA .=  QT_J1_YSP21._/_386.0	
..;:   V = H/12. *  (3.1^159*0*1) /..K.<
:;:,-.  ;  00  100 M .= 1,1 Hj^QA.:.j::.;r^.-r.

      TF"=  oF~T"bTi o'ooooo
       P = 6P.*36.*RKf-PXP(ER/(T-KSO) )
       p =  p  if .CF
    30;AB =  YS02(I >**(!. -fl)
     ,_.AC_.= ..J.L«j:fL! *J'-* .tS-Q-iU" V- ( 1 . -_X_\Lt U /.X V5J <_*
       "AD "=~ AH - AC
       IF (AO) 65.65.3S
    31_Y.SP? JI 1 1 ) _5. ( A.B.r AC ) ** (J . iJ>.\ ,jiM.)
     "     "
       IFIXVI
    50 PSU2I l + l)=YSri2( I U)/0. 000001
       IF(YS02(H-1)-YS020)65,55,55
 	5JL_!..7_.LJLJ_
 :;  ..  GO  TO  30. •.,'•.. :'••:. •'"' :'W:.. :.;:;' i&.-;:::. '' -^ >: -;.;,: i' v:,;or/-x-r-.' :••   ;.-,,v.--:J-
 ;v;>. 65 M =  1  " ,f ;iV.x'C:.:^^-^s-^Il^:^.^Vt^W^ -ivlif i*.:;i  '/;i^i;if:

 —r~x ^ = x v, | , _ (Q T / afabTll'TTs'T/ T: )"*J Y7oi2(I J-YS02D)
       1F(XVIN)67,68,.68
 	67.xyjN^=..o...P.ooDaa
 ;.'.  68 HT  =
     -.-.• HT  =  HT* ( YS02 ( I) ** (t. -B) - YS020* *
     .- HT  =
       FRAC  = HT/H
       STAGE - I +  FRA:
       sv  =  OTS /                .,..  ., ,
       DPAC  = TCR  *  p.5  ••:  '-•iv::.;;•>^:••:;•-:V^:;v•V:;••f4¥s••»f::»l^
       GRAP_^-jrCR_*..J[).25	;	' '..•:--"':'               '      '
       TOP = OPAC  *  UPAP
       WRITE(MX,3I1D,IDATE,RC.XVOJT,H,D
             lMX./<)'JCLJ.3
       WRITE(MX,8)PS020
       WRI TE ( MX, 5) T
       3.CL.70_X?.lJ.N.
       WRITE(MX,6)K,PS02(K)iXV(K»
    70 COMT1NUE
           IEJyX..lZJi..RA:.,J'.S.02.0.,
  -     WRITE(MX,7)TCR,H,STAGE
  .  •:•  ; WRITECMX, 11)  SV
       WRIT(:(MX,13IOP.\:,I)PAP,TOP
            t(MX,15)
            KCn, 1<.)T,XVS,Y02,YII21),ER,A,B,C,D1,RK
  .. i.oo_: ON J IMS	
       GO TO 10                          -::•,- ..  ,;   -
       CALL EXIT    '••':;..;-::^;K'^.s'..V''lW	
       c \t:\               ' ''.    ",'., '•.'•;•••'• • '•'•';.","..*.'
                           624
-------
                               APPENDIX A-22-4

            S02  SORPTION  RATE  COMPUTER  PROGRAM  -  BENCH SCALE



                       DISK  OPERATING SYSTEM/360 FORTRAN   360N-FO-451  CL 3-8

 C
 C     CALCULATION  OF  S02 SORPTION RATE
 C
JL__^ J BlIIEjNLJJ_^AM^HgjM£S.OIi,_F £6^26, 1971	  ___„	_„
 C"•.;.. -^:M  5;;::&:<:'rV*^^
 C. .-.'•.  ; D E S IG-N E D  B Y:; G .  N.  B R0WN ;• '*£$|:;?:*;$£] f S-£ I*.|jp^|;:::: SsHl'JsS;&,;>::. i':;!::.^i|;;i!:'f f JWSs•• i;1 ?%:;!:': •-;"•*;

"c    "AR"EA(J) = AREA  UNDER CURVE FROM TIME  = i TO^IME = ^F^;'  : :'"::;^~i^^^
 C     X(J) * S02 LOADINGS
 C     SUMX(J) = CUMULATIVE TOTAL OF SO? J HAni NC^   __	
 C     DXDT(J) = RATE  OF  S02 SORPflON ~                  "  "	     ~~~
     .REAL NOF,NOM
_i^__^_J>_IMENS LQN_I_PMS_( jJ_jJT( 30j , Y ( 50 ) ,X ( 30 ), SUMX ( 50 ) , AREA< 30 ) , DXDT < 50)    .
       DIMENSION L(80)                                         '           "~"
                                                       _ r_      _^ ___
     2  FORMAT (1H1)                                "       "     ~~~   ~"
     3  FQRMAT(18X,V $02  SORPTION RATE • , 10X, 31 3i />
      _F QRMAT L/jJL_T EMP E_RAT U.R E_ =_'_.£I2_-Ai * FS/,« SPACE  VELOCITY =' ,£16. 6 , •_
      1  /HR«,/,»  INLET  S02  MOLE FRACTION (DRY) =» , F12 .6, 5X, •  (WET) =',F12
      2.6,/t' INLET  H20  MOLE FRACTION =',F12.6,/,'  INLET  OXYGEN MOLE  FRAC
     _3I I ON =' ,F12.6 ,_/ , JLJ_N L_ET_CQ2_MO L E_F R ACJ_I_QH f_'_L£]L?_« 6 » / » '  I NLET NO MO
      4LE  FRACTION  =' ,F12.6,7,' INLET INERT GAS MOLE  FRACT ION~= ' , F12.6, / ,
      5« INLET CARBON; WEIGHT =• TF12.6, «,J;.GMS» >
         RMAT ( / , * '   tj ME;     KOL E FRACT ION S02 __ H2S_Q4_LOAOI_NG _RATE_ 0_
      IF HZSO't SORPTIO.N" ,/,33X, • CMS ACID/GM. C      GMS ACII.VGM C-MIN',/)
     6  FORMAT(FIO.O.EIO.O)
   ._
     a  FORMAT c i or-a. o j :              .
     9  FORMAT? ' TOTAL" GAS "FLOW "='.i'F '12.6, ^•
   JLQ__EQRMAJ (/.' •-AV
    11  FORMAT180A1)
    15  READ< INP, 1)( IDATEd ),! = !,3) ,NOBS
 C'     IDATE(I) * NUMERIC  CODE FOR  MONTH, DAY, AND  YEAR  OF  RUN.
                   LR_DiL.OJlS.EaVAUflN_.£pJJ!JT_SJU	.  '	_.._
       IF(NOBS)20c500*20
   20  WRITE(3,2)
	^Eftpj;NP»aiWCJ£OMC.fJ.EM.P.rC2£j.aOiF.iJMQFilt2yP^^
C      WC '» INLET WEIGHT  OF  CARBON, CMS.      '^.-^M^.M^
C,  ,..  CONC"= INLET 502 HOLE FRACTION         WV^m^mm*
C     02F  = INLET OXYGEN  FLOW RATE, SCFH
C     C02F « INLET C02  FLOW RATE,  SCFH
c	NQF_=_INLET NO FLOW RATE.,	S.Q.FH»_S_£FH
C     H20F = INLET H20  FLOW RATE,  SCFH  :
C   1; S02F = INLET 502  FLOW RATE,  SCFH :;:
            •_!NLE_T JLNERT_£_A_S..R.J3W
      WRITE(J.3)( IDATEU),I =
      READlINP,11)(L(I),I=lt80)
      _M.81I£(3.f.UJJU.U.iJ-XiflAl	
      TGFR «  02F * C02F +  NOF +  H20F..,+.
      ..'TGFR v« . TOTAL .GAS, FLOW ..RATEy/^T-^y

                                      625
-------
 09/08/71             FORTMAIN

       SPCVL  =  TGFR /WC  *  0.1699E05
 C     SPCVL  =  SPACE VELOCITY
       H20C  = H20F / TGFR
 C	_H20C  = INLET_WATER MOLE FRACTION
~	CONCW~"=  CONG *  {1~.-H20C)     ',.-':-"  :::A-x:5:"
 C  ':.  CONC.W  =  INLET S02  MOLE FRACTION ON  A!WET
      _02M_=  02F_/_TGFR	 -'  -  jM^^^J%M£i
 C     02M =  INLET 02  MOLE  FRACTION
       C02M  = C02F / TGFR
 C    _C02M= INLET QP.2_MOL E_FR ACT ION
'       NOM =  NO? / TGFR .""".-.   •••• •••••'.   ' -.. ••,'
 C     NOM =  INLET NO  MOLE  FRACTION:;
       G_AS_M_  = GASF_/_TGFR	
 C     GASM  =  INERT GAS MOLE  FRACTION
       WRlTE<3,4)TEMP,SPCVL,CONC,CONCWiH20Cf02M,C02M,NOM,GASM,WC
       WRITE (3,9)TGFR	,	
    /.  SPCVL  = SPCVL/60.!'-^V'S--x:'-:%;:H»:v:y-;'-::l':*'I&::-v-C:;1V::;^
_._."__„	RE AD ( INP.6) ( Tl I) «Y( I ), l^j',HOB^^Q^A
       AREA(l)  =  .00000
       X(l)  =  0.00000
       SUMX(l)  = 0.00000
       DXDTl 1)  = 0.00000 :::
  •...•:••-.:•• N =  NOBS. •-•m^ifiMt^m
  "' "'.'• DO 50  j=2i\*'\\^^:'^'.::^£i\:&'^ :^':-M"
       l -  J-l
       AREA(J)  =<{T«J)-T(I))/2.)  * '(Y(J)+Y(I)>
  	X ( J )__£7 . 3JL? E_r 3 __*. SPCVL  * (CONC *  m^M;x::;t::;g;!:::::||::;idi::-:i?;;;.:,,-,-,::,:-:: :
       GO TO 15   ... :::  :'^;:''\-:^.^^ mf^^ • •".^^^^^^^M^^^M^M^.^^
_ 500. STQP  ..._,
       END
                                   626
-------
                                 APPENDIX A-22-5

         SULFUR GENERATION  RATE COMPUTER PROGRAM  - BENCH SCALE


                       DISK OPERATING SYSTEM/360  FORTRAN   360N-FD-451  CL  3-8

 C
 C      CALCULATION OF  RATE OF SULFUR GENERATION,  BENCH SCALE.
 C
_C	HMJ!EJNL_BY_ SAM JQiQMPSO_N_t_F_EB. 25,  1971
                "" '' T  '  '   "
 C  •. •;•/•;. - ••'*,-<- •' .X.: v':H-s.:::;:vV::-^:.^yVy.H V^^:*.:^^^
 c   .,.\.DEsiGNEDVBY;iGV;Nv;BRowti^
 c                                		
 C      Yd) = MOLAR CONCENTRATION OF H2S         ~^~^  ———
 C      AREA(J) = AREA  UNDER CURVE FROM TIME =  I  TO  TIME  =  1*1
_C	JCUJ. = SULFURIC, ACIJ)_LpAOING
 C      DXDT(J) = RATE  OF~
     v DIMENSION IDATE(3),T(50J,YH2S(50),YS02(50),YC02(50),Y(50),AREA(50>
	     PI M E_N S 10 N_X L50J jLD,XD_T { 5_OJ_,J.J_8 0 >
       I-NP =  i        	         '  """        '   '   u  ""   '  '  	
    15  READ!INP,1)(IDATE(I),1=1,3),NOBS
     I  FORMAT(312,14)_   	               _     	      .	
 C      iDATEtl) * NUMER  CODES "FOR "MONTH,'" DAY AND "YEAR"'." ^yVy    ~TT" • '",..""
 C      NOBS = NUMBER. OF  OBSERVATIONS                   ^S:. Vy.'; "yxy.^;,-.-.:.:-.t
.	__JEXIJT .» i  ,             	.  tj    	tiWf£i'^%-ti$::-:*^::.'-'
       IF(NOBS)20,500,20
    20  WRITE<3,2)
     2  FORMATClHl)	
     8  F 0R M A T ( 10 F 8 . 0 ) ; i -V•'': .0 i'.:. .•:,; <:i:;.,:. ;i•,<&*; fA. • sx •;
     ?;:READ( INPtS) QI'VWC , WL, YI ,SAL,TJ ,TM,Tf
C
c
c
•c ::,
C V:
c
c
c
r.
c
c
.. ;: .-:•. Q !,.=•-
we =•
WL -
YI -
SAL =
:"•"".. 1 1;-; =
••,a\TM^ =
TF =
FH2S
H2SF
FL =
PL' '"-"
SPCVL
SPCVL
CONC
INERT GAS FLOW RATE
WEIGHT OF CARBON
r i N M i_ iV E 1 1? 1 1 1 0 1 i_ o M u/ L
INLET PERCENT H2S
INLET SULFURIC ACID
INITIAL TEMPERATURE,
MAXIMUM TEMPERATURE,
!'- :? .:• ; •':••'•: :>:^S:':*;'-???:::r: y.:'jySx?:?5 y^^i'f: -'&%ii$$ii$i?<'x :.?.? '.'' j_8_Q)	
  WR^fE(3,4)SPCVL,OI,WC,wL,YI ,CONC,SAL,FH2Sy: -o; i. ,^: •: :^i\ •::•:••:.     y :  y
  FORMAT(/,'  SPACE VELOCITY =• ,E16.6, •  /HR't'/t1  INERT  GAS  FLOW RATE
 ^'^12,2,'  SCC/MIN',/L« WEIGHT  Of jCARDONj__UN.LQADE D "' ' F1L»_3-L!-CMS1.
 t,Tx,'LOAbFD^"'TFT2T2%'"G¥s •;/,/,"•  INLET PERCENT H2S  =',F12.3,/,'
 3INLET MOLAR  H2S CONCENTRATION =',F12.6,« MOLES H2S/MOLE  INERT GAS'
 4._/,« INLET  SULFURJC _AC 10 LOAD i NG_»I . F 12 .j& tj_G.Hs: jjzso^/G.M .CARBON »»/
"5,7,«"TiNAL"OUTLET PERCENT SULFUR LOADING ON CARBON =',Fi2.3)
     5»
     '   ITE(3,-9:).F^,;iI,TMfT;Fj;:;:::|::;j;;^^;,i:i;:::;:;:

                                     627
-------
 09/08/71             FORTMAIN

     9 FORMAT*•  FINAL OUTLET SULFUR LOADING  ON  CARBON =ltF12.3tl  CMS S/GM
      1 CARBON',/,'  INITIAL TEMPERATURE =',F12.2,«  F1,/.' MAXIMUM TEMPERA
      2TURE =',F12.2,'  F',/»' FINAL TEMPERATURE =»,Fl2.2f' F'»/)
       DO 30  1=1,NOBS                                   	
       RE AD ( INP, 5 )  T ( 1} , YH2S-I I ), YS02 ( I), YC02 (I)   V: l;^«S;£
     5 F0RMAT(4F10 .0)i;:.:• »y :.P.':•;V:-'.; :- ^^M^iil^i^^l^^^r''"'""
    .  _xm  = SAL	••;:.../..it • :5;;;:>::;:^^^^MM^^^^W^'-	
    30 CONTINUE
       DO 40 1=1,NOBS
      __Xi-I !  ~ YH2S(I)  /  ( 10_Q;_.- < YH2S ( I) +YC02 ( I ) + YS02 ( I JJJ.
    40 CONTINUE"    .   ,
       DO 60 J*  2,NOBS*
       _l=_ J-l			,		:.
             )  =i(t(j)-T(i»/2.>* mn+Yun
       XIJ)= X(I)-(1.458E-3 *(Q1/WC) *  ( CONC* ( T { J )-T ( I ) ) - AREA(JM)
       PX.OT ( J ) ^rJ_«A58E-3_* (Q I /WC) MCONC-Yl J ) >   	_		
    60 "CONTINUE        "
       OXDT(II = 0.00000
   __AREA(1) = P.QOQOO.	„	,		
       DO 65 J=2,NOBS
       I = J - 1
 	_I FUi.J> ^S1L_^.0_._U_6_3 t^liiS	_____™	
    63 TS = TU)MT(J)-Tm)  * ( (0. 1*SAL-X(I) ) / ( X( J)-X( li) )  :   ; A
 •      DXDTS = DXDTCI)  +  (TS-T(IU/(T{Jl-TJI)) * tDXDT(J)-DXDT(I))
 &•*•   XS JL o. 1. *..:SAL    '?:1.:'"-".^:Y.:L .:.......:..-.......:,:. .:V-^:£.t/:-^^:.^^.^^:•
       K = I
       GO TO 68
 	6.5 _CONTI_NUE	._'		,
       IEXIT = 2Vi^^:P	  "
       GO TO
 _ 68 AVER =
       DO 70 J=2,K
       I = J - 1
 	_AVER = AVER -t-  IDXDT(J)  » (T(J> - T(D))
    70 CONTINUE
 '; ,     AVER = AVER'  +  (DXDTS * (TS •^'•T^^l^^^^^i^i^^i^^iM;:
 	AvEE. = _AvjR._/  TS    . :.:.l:.v.:  .•::;:;;:':.'•^':^:-2^X'%%%£^:-??$''$?*'"••;•**
    75 WRITE(3,6)
     6 FORMAT(/,» TIME      PERCENT H2SS7X,'  PERCENT S02S7X,' PERCENT CO
 _    12 _   MQLAg_C.O.NC  H^S	H2S04 LOADJNG     RATE
       WRlTE(3tll>
    11 FORMAT183X,' CMS  ACID/GM C    GM ACID/GM  C-MIN.1,/)
       DO 80 J = 1,NOBS	„,__	_^	
      ""WRITE (3,7) T(I) ,YH2S(I»,YS02( l)tYC02(I»,Y(l),X(n,DXDT(n
     7 FORMAT(F5.1,E16.6,5(3X,E16.6))
 	80 C ON TI NU E	,  	
       GO TO (85,15), IEXIT  AA /•  '^-/••>^^^^-^M^^^jf^M^^^.-:-f\:^
    85WRITE(3,10)XS,TS,UXDTS,TStAVER-: '-•--"•""::^:^K^:^^-A-^W"^^^^:^y
 .. J.O_EQRHA T ( / , i.. AC I D.,LOA.DJ.NG_ .= ^,.E1.6_. 6j-L_AJT_«_,JEl6.6,_'__«INUT ESI, /1_' RA
      IF ACID DECOMPOSITION =',£16.6,' AT',E16.6,« MINUTES'*/, • AVERAGE R
      2ATE OF ACID DECOMPOSITION UP TO 90 PERCENT  ACID UTILIZATION =',E16
.	3 . 61	.	™^^_______	
      GO  TO 15
  500 STOP  ..:^  <
                                      628
-------
                              APPENDIX A-22-6

 COMPUTER PROGRAM FOR GRAVIMETRIC  FLOW EXPERIMENT  CALCULATIONS
                      DISK OPERATING SYSTbM/360 FORTRAN    360N-FO-451  CL 3-8
 C
 C
 C
JL,
 C
 C
  PROGRAM NUMBER C4769
  DESIGNED BY JAN K. EVANS AND G.N. BROWN

  WRITTEN" BY S.R. THOMPSON, 9/9/71
  DOUBLE PRECISION ARUN
  DJJMJ£M51QN__DR A ( 2QO Lt.AJL.DA QJ 2.0.Q > j A t, t) AU A ( 200 > , P I C KUP ( 200 1    __  __
  DIMENSION IOAT£(3),T[ME(200),AMASS(20d),CHARf(200>,DR(20"0>
1 FORMAT(1H1,/,10X,' CALCULATIONS FOR GRAVIMHTRIC FLOW  EXPERIMENTS',
2 FORMAT(A5,1X,3I2)
3 FORMAT180H

4 FO'RMATX,J._
DRV-
40. = Lt-EIiSLtl
       r5X,'

                                                      _PJ?M'
                                                       02
      3*'t6X,' H2S04- *',F7.2,' *',/,'  CORRECTION=',F7.2,' MGS4X,' H20 -•
6 FORMAT(4(3X,F5.0,2F6.0)>
7 FORMAT(F15.5,iX,F16.5,4X,F16.5,AX,F16.5)
fl-JORMATftXt' MEAN. IDA O'_t lit' DIFFERENT I AL
 1' DIFFERENTIAL RATE',/,' GMS SU2/100 GMS C
 2 GMS ACID/100 GMS C    MGM ACIO/GM C-MIN',/)
9._FJQRMAU&* .' TIME'. LAX,' MASS _D IAL '., 13X,'_ CHART '.L5X.'  PI
                                                     MGM  S02/GM C-MIN
      15X»« (MINI1,37X,'
    10 FORMAT2)ARUN,IUATE
       WRITEIMX..U
       READ(MY»3>
      _.W RI.IE LM X.» 3 L	
       WRITE(MX,5JARUN,S02,   T, IDATE,CNO,FR»DW,02,H2SOA,DF,H20
J*.
c
c
f-
c
c
_c_
c;
c
*•
,u
C
c
'.-.,- I DATE
DW
S02~~"
CNO
	 01 	
H20
T
HzVoV
N
          DATE Of RUN
          DRY WEIGHT
          D£FLECU DN._.
          S.02 CONCENTRATION,
          NO  CONCENTRATION,
          02 .-CDNCENTRATIQN,
          H20 CONCENTRATION,
                                  PPM
                                  PPM
                                  PE1,
                                  PPM
               TEMPERATURE, DEGREES F.
               FLOW KAJJEL^ >;	^—•<	~	»
               * H2SO*
               NUMBER OF DATA POINTS
       READ(MY,6l(TIME.tI >iAMASS(.UtCHAR,T( IJ.»!
       HK » (H2S04/100.>*(6^,/98.J
       DO 50 I»ltN
       PICKUP!I) « AMASS(I)*200.0 * CHART(I) + OF - DW
                                    629
-------
 50 CONTINUE
    WRITE(MX,8)
    Nl - N-l         _         _                 ___
    00 60 J « UNI
    DRUI - (PICKUPI J+1I-PICKUP1 J)|/mMEU + l)-TIME( Jl)
    DR(J) - pR*HK  __
    ALOAD(J) * (PICKUP{J+i)+PICkuP(J) l/(2.*6w)**(9B ,/64. )
    ALOADA(J)_- ALQAp(J)*{?8./64.)   _     ______     „
    IF(DR(J»60t55,55
 55 WRITE(MX,7> ALOAD1 J ) t OR ( J ) i ALQADA( J ) » DRA( J J
 >0 CONTINUE      _  _  ______ , _________
    WRITEtMX.ii
    WRITF (MX,5) ARUN,SU2t   T, 1DATE ,CNO , FR,OW ,02 ,H2SC)4 , OF.H20
    DO 70 I  * 1 ,N
    WRITE (MX, 10)  TIME (I I, AMASS I I ) tCHART ( I ) , PICKUP ( 1 I
 70 CONTINUE _ _          _  ____________  ____________________
    GO TO "20
100 CALL EXIT
    END                    ...  .
                                630
-------
                              APPENDIX A-22-7


        COMPUTER  PROGRAM FOR CALCULATION  OF  DIFFERENTIAL
                 SORPTION RATE AND MODEL EVALUATION



              CALCULATION OF DIFFERENTIAL SORPTION  RATE AND MODEL EVALUATION


                       DISK  OPERATING SYSTEM/360 FORTRAN   360N-FO-451  CL 3-8

-.—	-,- DIMENSION. IDATE<3),XC50)tRATE(50),AMSON«50),AVCOY{50),AVCOX(50).
      1TRACY(50),TRACX(50),WVACO(50),WMOO(50)    :                      	
i:     DIMENSION AJOST(70),XPRIM(70),TIMb(70) i ^.'H :. •'       , i-:
""      MOUT = 3	   	       ""	"—.•_:--.-	—.:•...•	-•-•_-i:			

    20 RtADJMlN.DNRUN, I DATE,XS,TFR.PC02,PPMSO,PPMNO,P02,PH20,PH2SO,T
	I FORMAT(I5,lX,3I2,OF_7.p)	
       IF(NRUN) 100, 100,2* '"".""'   -• ::~ .-:"••'T^J-T^T; ~"	;	—--;——--	—-	
 C"     NRUN = RUN NUMBER  •• \.';>:':•-:'••: 'f^v".^%'^^':. iy ^''vrVv - ;-:-"!-^v'..--: :• -:v
 C   _  I DATE = DATE OF RUN'  ;' •'- i":':  •'•; ; :V"<'i^^';:~ •^'>'^'.t'.'•:   '•
 C      XS = CONSTANT,  GMS H2S6V>GMC~~
 C      TFR - TOTAL  FLOW RATE, CC/MIN
 C	 PC02 = PERCENT  C02         	
 C      PPMSO = CONCEiMTRATIciN"Of:""s02",
 C      PPMNO = CONCENTRATION  OF NO, PPM
 C__   P02 = PERCENT 02   __ .,..I..-,.• :.  ;,•;:'.;.
 C      PH20 = PERCENT  H2o"
 C      T  = TEMPERATURE, F
$,_    PH2SO = PERCENT H2_SQ4_
    25 WRITE (MOUT, 2)        "v
     2 FORMAT ( IH1)  ;•:-',.:"';'::^:'&
	REAO(M[N,3)  ^vU'liiiliilii;
     3 FORMAT(80H
      1
       WRITE(MOUT,3)
       READ (MI Nil) Nl          ; , '
       RFADIM1N,4)(XI I),t I'liNl)
       READ(MlN,4)IRATE!I),I=l,Nl)
       READ(MINil) N2
 '   "   RKAD(MIN,4>(XPRIM(I),I=1,N2)  '"-: :  ;.":"^.,^,-^
C      XII)  * MEAN LOAD  (MG H2SOWGM C)   :•       :
C  '    RATeill  » UNCORRE.CTE.D._RATE.J_M.G.J.i2.SJJ.4/GJL.C/l!lLfU_
C      TIME(I)  » TIM(i(MIN.)
C      XPRIM(I)  = MEAN LOAD PRIME  (MG  H2SOWGM  C/MIN)
       WVACX=ALO.G( PPMSO .*_...OP.QO.Q.l.l_,		
""" "  DO  AO 1 = 1 iNl            ••"•:
       X(I)  * (X(I)/1000.) * (PH2SO/100.)
C__    X(I)  NOW  EQUALS LOAD AS H2S04,  GMS_.H2.SOWGM_C  	 	
       RATEU)  = (RATEIII/1000.) * (PH2SO/100.)
C      RATE(I)  NOW EQUALS RATE CORRECTED, GMS H2SOWGM C-MIN
_ AMSONII
  AVCOYJI
  AVCOXd
  TRACYJI
  TRACXd
  WVACOU
                  RATE {i»/ ( PPMSO*. OPQQQ.IJL
                  1. / AMSON(I)
                   L.- (X(I)/XS))**.3333333
              _ = ALOG(AMSON(.U.I	~—-	
                  ALUG(l.-Xm/XS»
                  ALOG(RATEd) /  ( 1 .-X ( I )/XS))
      WMOD( I). =_ALOG.IKATE.(JJ./-<.l».rX.d.l/XSI.**2.L
   AO CONTINUE                    .   ;  :  ;
      DO 50  I *  liN2
      XPKIM.IJJ _" JXPRIMI Ll/lOOOU-JL-LPHZSO/lOOjiJ-.
     "XPRI'MM f NOW EQUALS" LOAD AS H2SO*  PRIME,  GMS H2SO<./GM
      AJOST(I)  -  (PPMSO * T1MEU) *.00000l)  /  XPRIM(I)
                                   631
-------
05/11/71             FDRTMAIN

   50 CONTINUE
    5 FCXXATI/,' KU\  NUM8CR  = • , 1 !>, 5X, 3 13 , / , '  TFXPER AKIRC = '^.0,'  DEG  F1
     li/./t* TCIM  FLIJK  RATfc =',F7.l,' CC/f IN ' , / , I , ' PERCENT  C02 . - ' , F 1 . I
     2,/,' PERCI.-NT  02 =l,F7.l,/,'  PERCENT 1120 = ' , F7. 1 , / , / • '  COMCENTRAT I
     30M S02 = «, F7.lt1 PP.V't/,'  CDNCtrNTKATlC^I  NO =',F7.1i' PPMS/t/i' P
     PERCENT H2S04  ='tF7.2,/,'  SATURATED LOADING =',F7.2,'  GMS  H2S04/GM
     5C'./t/f' X, GMS H2S06/GM  C       RAIE,  GMS M2SD4/GK  C-MIN1)
      VM ITCt POUT, 6) (X( I ) ,i.5)
      W«|TE(MOUT,/) rjRUI'i.lDATE ..... .... ........ . ....... _ _______
      WRITE IMOUT, 10)
   10 FOKHATI'           AVCOX                AVCOY')
      WRITE(KUUTil6MAVCgx(l ) , AVCOY ( I ) f 1 = 1 tNl )
      WIUTEIMOUT, 7) NRUN,lOAft
      wkiTEiMour, ID
   11 FOKMATI1         TRACORX  .................. TRACORYM
      WK1TEIMOUT, 16) (TRACXd ) , TRACY ( I ) , 1=1 »N1 )
      WXIT£(KOUT,7) NRUN.IOATE
   12 FO">r-'AT( '" LNIPPXS02)  =',F10.5>
      WRITE (MOUT, 13)
   13 FORMAT! •      .  WESTVACO   ... MOOWESTVACO?.)
      WRITC(MOUr,U) (WVACOd ),WMOO«I)iI =
   14 FCRKATIF15.5.F15.5)
      GO TO 20         ..... .        .........
  100 CALL EXIT
      END
                                632
-------
                               APPENDIX  A-22-8

  COMPUTER PROGRAM FOR  MATERIAL BALANCE  RATE CALCULATIONS  AND
                   bPACE VELOCITY  FOR 6"  S02 SORBER
                      DISK OPERATING  SYSTlfM/360 FORTRAN   360N-FD-A51  CL 3-8
 c
 C     PROGRAM NUMBER CA765
 C
 C	,	MATERIAL BALANCE, RATE CALCULATIONS, AND SPACE VELOCITY FOR
 ?- .~.;.:. :,T~ sr|T"5TT?~"5rrp.T?'Fnv"T~'~'r~:-~——,,,_....-.,_,„,„.,„..,	,—.	„——
:t~~~™~6»-
 C
.A^iJiljJ^M.?^^^                                       JUNt 1971.

 C     NTYPE = 1 TO DETERMINE TOTAL  SULFUR
 C           = 2 TO DETERMINE S02 AS ACID
"C
c
c
c
c
c
C ' ... .
C -V--.;..
,C. •-,::"•'
C
c
c — "
c
c
c
c
c
-F$~C"~T
XS1N
xsnui
*turjr-
RTOUT
SIN2
;;'OT:::V::':"
:T • ':'."; ,
D
W
H
PCU2
PCH20
CONO
PCC02
-..-.-. ...AJ.
S02 LOAD I NG ON CARBON I N
.''.' :•.-•.' '..-... •->'' •/• ...'.'- :.ou;r.
i? S^TJiT itUTLET .^ATERTAi"
TOTAL OUTLET MATERIAL RATE
INLET S02 CONCENTRATION
= .OUTLET «.! . '.' — ---:T 	 -
;-. TOTAL INLET GAS RATE : 'I ••• ": •'•',:
: = TF.MPSRATUkG'- :/.v :::::!.;;';. •'•;: '/>'•. •
rr
£
\?7VPTfR PiTFSSU'RF Cr^"Rl:CTIOf\i~
DIAMETER OF COLUMN
REACTION RATE CONSTANT
HI IGJIT OF C4ftfJ()N PER STAGE

PEK~CENT~
Tl:KCE7>iT
»/HR
PPM

.i-^-X SCFH',;: :;^,V
.•::,V FARENHEIGHT
PST'"""1"^""
INCHES
INCHES1
PCKCCNT
PERCENT ~
PPM
PERCENT

                        OF.
       n i MEN'S ION ip (10), i dAre (31, YS02 (i d), AR AF < i o), APKUP 11 o), AL E AV 11 o i,
             l    (JNCU-O l.VCTI 10), SPACE j 10), ACTUL( 10)	
i FUR^ATdOAl
.2 FORMAT! IOF8
3 FORMAT!
1
2
- 3
A
3 I 2 , 1 A , F 1 0 . 0 )
01
RUN NUMBER '.10A1,' CARBO^
DATE ',313, /,/,
INLET it 5ULF.UR ON CARBON
OUTLET. {t SULFUR ON CARBON
1NLEI S02 LUADIfiG ON CARBON
4 '.F10.0,/,
-' ,1-10.2,' %',/,
= 'F1C.A, ' LBS S02/LB C1 )
     A FORMAT! «  OUTLET S02 LOADING ON CARBON^'F10.A, •  LBS S02/LB C1/,/,
      I   	 «  S02_ CCVCEHTRATJON IN IMLJJ GAS  jJ/lOj.0, '  ^fflS / f	^

      3        '  VOLUME.* H20 ='F05.1,'  S',/,
      A        •  VOLUME -JS_02  -_^F Op_._l, '  ^' )      .,_.._
    ~5~FOR~M~ATff  CliNCc.jfRAT IO"N"UF" ijO=~rnoTi,' 'PPK1",/"/rrToTAL'~G"A'S"FLT5W R"ATE~~
      I-'FIO 1,'  SCFH'/'  IINEAR GAS VELOCITY ='F10.1,' FT/SEC'/,/,
      2        '  TFHPERATURE        ='F10.1,' DEC F',/,/,/,' TOTAL SPACE  V
   ;  6  FORMAT(•  POUNDS SULFUR INTO KEAGTtW  ='F10.A,« LBS/HR'/,
             JL.P_OU-''^S _S_y_LFU1l UUI °JJt^JJ^^l/)^L^LB?/JHRA^!'-/-'-
      2          . 	
     7 FORMATUHl,'  MATERIAL BALANCE FOR S02 SORPT ION', /,/)
     8 FORMAT! IH1,'  CALCULATION OF RATE OF S02 SORPT ION FROM'/,
 >; 9  euRKATTiH^
                                     633
-------
07/12/71             FORTMAIN
1
2
10 FORMAT!
I
.P;:-;-:' 3( ,'/>
; v'll FORKATI
	 12 FORMAT!
I',/,
13 FORMAT!
KY = 3
NSTGE =
PI = 3.
NSTG1 =
1 DIFFERENTIAL BED RATE DATA VERSUS THAT'/,
• CALCULATED FROM FLUIDIZED BED REACTOR'/,/)
' AVG ACID LOADING AVERAGE S02 AVERAGE RATE OF'/
' LBS H2S04/LO C CONCENTRATION ACID FORMATION1/
' 3TAGF 	 PPK IKS 1I2S04/LB C-rliN
I4,F15.4,F17.0,F17.5)
• 	 ACJUAL StMlt VtLUillY ""CAi-CUl. ATE0 SPACE VELOCITY
' STAGE l/HR l/HR1/)
I4,4X,F14.0,13X,F14.0)
ft
riTTTiTrTTj'RTTT^iTTrBATFTTfyrj^rrjrVTTrYpri-r'ARii-N •
14159265
NS1GH + .1
  , .25 P,E AD t MX , 2 )FV , WSC • XSIN, XSDUT , SOUT , FUOUT ,.SIN2 i SOUT2 iQT , T
   '                   .WtZtHi PC02tPf.H20.CUNO
            *****  MATERIAL  BALANCE *****
      .FAC1 : =  I (1-(PCH20/100 )•)'/ I 1- (VPT/14. 7 ) ) )
      GO TO(30,401,MTYPE
           r^  !. 0 o *~srjnr~ -  i w s"C'5TnjT:rs n 11 r n
      XSUUT=  XSOUT/I(100-1(3.06 * SOUT)/FV))*50)
      FCOUT =  100  /  I 100 + WSC+t153*XSOUT/FV))
                   i'SOUT2*.OC0001'*3?*FACl+RTOUT*l SOUT/ 100)
      FCOU t ' ='"l66" / "( lo'o"
      SLUT =  XSCUT  *  .5  *  100 /  (1  + XSOUT *
      SF1N=QT/359»SIN2*0.000001«32*FAC1+RTOUT«FCOUT*I 1WSC/ 100) •»• ( XS 1M/2 ) )
                      IN •:
   ;•   SFQUT=QT/ i5q*s
   -- '  SFOUt=SFnUT ,<• RTOUT*FCOUT*( I iv'SC/ 100 1 •*•( XSDU7/2 ) >
   ..... STOlJf  =  SUCFl/K  OUT
   50 PCMAF= SFCUT/SFIIM*100
      PCMAF  =  PERCEIjT MATER I AL ACCOUNTED FOR
        ™-T.   . . .          ™__^  " ..... : .......  "™     ~-™^™
C            *****  RATE  CALCULATIONS *****
c                              '
 SUMAf = 0.00000
 DO 100 1*1,NSTGE
_ARAF (
 ARAFI
 ARAFI
 ARAFI
      APKUP
      APKUP
C     APKUP
                           . 000001*9e)/l35')*PI*36*60)
" = "ARAFrn*"(iiyso"2"fr+T)-YSo2nTTt£,Ty7"fo<-*2~* "HIT:
 = ARAFI I ) .*  FAC1       :
 = AVEftAGE RATE OF  ACID FORMATION
T~£—or*oToT)o5oT*  (YS02Tr+n-YTrJ2VnT~*^Y	"
)  = APKUPII)  /  (359 *  RTOUT  * FCOUT)
)  = ACIO  PICKUP
      SAVE = SUMAP
                            634
-------
 07/12/71             FORIMA1N

       ALEAV(I)  = 98*XSlN/64+SUMAP
 C     ALEAVd)  = TOTAL ACID LEAVING PARTICULAR  STAGE
       ALOAO(I)  = 98* XSIN / 64 + SAVE +•  (APKUP(I)J
 C  '   ALOAUH)  = AVERAGE LOADING ON STAGE  I
^~"   '--
 C     CCWCU)-=  AVERAGE: S02. CONCENTRATION
   ICQ:CCNTjNUE ,_;_     __
       ~U ^"""(oT^VMA'VTVTHrfO^^^loOOT *~7T.	—-™,				- ...
       VCT( I )-SlN2*98*.0006oi*FAC17(.36*90*359*W*( l-{ AUQAD( I )/. 38) 1 *U-Z ) )
       V QT ( 1 ) = VOTJ I } * {_(l~ Y S(J2 (I ! /£IjJ2 ) **_U ._-_/. >j( l^YSO 2 ( I+ 1 )/SlN2) **( 1-Z) )

 C     SPACE(I)  =  SPACE  VELOCITY
  	  ACTUL(I)  =  4*l't't*l2*OT /  (PI*U**2*H)
"^C  '   'A'CT'ULT n^s^CTOTfUTTrAirr^EUaCTT?	"	'	~	——	  - -
   130 CONTINUE
       TACTL =  ACTUL(l)  X NSTGF
       "NPAGE = "0~
   HO NPAGE = NPAGE
       GO TO  mi, 1A2, 143, 20), NPAGE
   143
       WRITE(HY,3) 1 D.CARBN. 1DATE ,WSC , SOUT , XSI N
       W RIT E (K V. 5 ) CO;\iO i .Q.T. j U, T , T ACT L
  ^^» 9JLJ ntl5p)160'tl:80').'i NPAGE      u	^	
   150 "WKlfE IKY,6) SFINf SFOUT,f»CMAF
       GO TO HO
   160 WRITE (MY, 10)      	    _____
    -"-fi fy-f7b*~T=ltNSTG(f"        """
       WRITE(MY, 11) I ,ALOAOU),CONC(1),ARAF( I )
   170 CONTINUE
       OVERL = QVERL  *  ( ( ( S IN2-SOUT2 ) *QT )/ ( D**2*HJ )
       OVTRL = OVFRL  *  FAC1  /  8.0
      -WRITE (MY, IV) y
    14 FORMAT (/,/,>,/,/./> /i /,/,/,/./.' OVERALL RATE OF ACID  FORMAT ION
  ""—TmT.TT
       GO TO HO
   180 WRITE1MY.12)
       WR1TF (t"Y, 13) I .ACrOLI I ),SPACE( 1 )
   190  CONTINUE
       GO TO 20
   300  CALL  EXIT
       ENO
                             635
-------
                                APPENDIX A-22-9

   COMPUTER PROGRAM  FOR  CALCULATION  OF  INTEGRATED PILOT PLANT
               RESULTS  OF WESTVACO S02  RECOVERY PROCESS
                           FROM STEADY  STATE  DATA
                       DISK  OPERATING  SYSTEM/360  FORTRAN   360N-FO-451  CL 3-8
        INTEGER    _____    ____  _      ____   __  ___
        P i MEN'S ION" T i 12 ) , HOLD cTz ) ,o i 26 r, AVI AS! , ti ( 26T70NiTf].3 f 4T7RL AB f 7. 377
      1R<7)
      JLCy.1 V*LENCE_(_AV ( .1 )_, AY10AJ , (.AVJ2 ) t AY16A_)_, I AVCJJj AV10D )_»J_AV.H> > »_ADPIO
      i ) ,YAV« 5 r."AT"LioT» ("AV ( feVrwoFi > , ( AvT? r.woizTt < AV ( e ) r^cWi2 ) , < A v< 9 > , AD i
      21A),(AV(10),AD12A),(AV(11) tAZ301A),(AV(12)tAZ301R)f ( AV (13 )
      3 ( AVJ 14 1 , A030 1 A 1 1* ( AV < 1 5 ) t AY200B ) , ( AV < 16 > , AY2_06e ) t ( AV I 1 7 ) t AY2COC ) »
      ~* I AV ( 18 ) ', AY~20~6C )V( AVT19T ,"AY2000T.~ ( AV ( 20 ) rAY2iD6CT,TAV ( 2 1 i't AY200E >VTA~
      5V<22)tAY2066),(AVI23),AG200E)t < AV ( 24) , AZ302 A ) , (AVI 25) ,AZ200A), (AV(
      ^i*.'. • A P°?3. L» I *X ' ?1 ! •. A.?20PJ ) t LA.y I ?.? ) t A2200C KJ AV ( 29 )_t A YJOOC ) t < AV (_30_
      7 ) t A Y 108C )T< A Vl3 1 ) t AY IOOE") ','( AV ( '32Tt"AY 100 E > ."( AVT33 Ft A Y 1088 ) t"( AV (
      SAY 1080) , (AV(35),AGIOCC) , ( AV ( 36 > i WC101 ) f ( AV (37 ) , hC 102) , (AV(38)t
      9A0101A] it 1 AV( 39) » AC102A) , IAVC4C ), AZ90A) t ( AV Ul ) , A£90B ) t ( AV< 42 )» AC90
      IA) , (AVI 43) tWSVOl ) t'fR'l 1 )"t RCil )V tR"(2")'f R012Ti "(R f3" ) 'i RCW12) i (R(4),R03Ci
      21 t(R<5) ,^UIOI),(R(6) ,RD102)» (R ( 7 I , RS40 1 > t ( D ( 1 ) , BG 10A ,BG203C ) , '(BJ16.)»BC2d2AtHOi6b),Tlii'l7),SC206)t 16(18) ,"BC
      81C3A), (51 19),BGl04B),(B(20),BG104S)t IB ( 21 ) f B0101A) , I B ( 22 ) , BD102A ) ,
      9(8(23) tSOlOO )i (P(24) t STBINlf 
-------
03/07/74             FCRTMAIN
                                                                                  CC02
c	XARJAB.Lf-.._A.N]?,..c.0MESPONDING_VALUJ_gF JHE_J>ROCESS ELAPSED TIME.  EACH DATA
C     SET  CONSISTS OF A MAX OF  12  CAT A  CARDS" W FTlT"TTNrfrrrS~PlT"C""ARO;	AN~ORANGF
C     DATA CARD WITH A 1 IN COL. 5  IS AT  THE END OF PACH DATA SET.
	 _WRI TE (_3 , 30_OpJ	
 3000 FCR>ATr/T56,'S 0 2    S" 0 R"TT"E~R«T)	
      LINE- 18
	 DC 20 KL=1,44 	
     "CALL iNPUtTTVH'OLD,NOB)"
      GC  TC  (3,4,5,6,7,8),MODE
    * _N.P_G.1_NJ?P'1'1	
      hRiTE"(3Y40~6or MO,CAY,YR","NPG"
 4COO  FC3K4TUHl,T105,I2,«/',I2,'/M2,TU8,«PAGE • , I2//T39, ' 6"  D I A
 	1   C_A  R  B ON	P RECONOITIONER1/)
      GC  TC  3
       VTR" I" f E ( 3 , 5000'j MO",TAY";"YR7NP5
 5000 FORMAT(1HJ.,T105,I2,'/1,I2,I/',I2,T118,'PAGE • , I2//T51,' S U L F U R
     I     GENERATC R'/>
       LINE*  4
       GC  TC  3
    6  NPG= NPG + 1	
           r(3,"6000") KO.CAY.YR.'NPG
 6COO FCRMATI1H1,T105,I 2,*/',I 2,'/ •,I2,T118,'PAGE SI2//T37,' H 2 S
     1EISERATCR/SULFUR     STR1PPE R1/)
      GC  TC  3
    7NPG* NPG*1
      WRITE(3,7000) PO,DAY,YR,NPG
 7000 FORMAT! 1H1.T105,12,•/',12, «/S12,TH8,'PAGE SI2//T48,' C A R B 0
     IN     INVENTORY     HCPP  E  R'/)	        	
      GC  TC  3
    8WR I  E ( 3 ,800_OJ
         '
 8CdO FOR'VATT/Tsb, '  SULFUR     CONDENSER'/)
      LINE=  LINE+2
    3 IF(N C B)  21,2 U3 0	
   2T"IT-"( N- 3) ~2~2" ,22 , 20"
   22 KTO= KTO+1
      GC TC  20                    	
   30 SUM=  0.0
      DC  1  L=1,NOB
      ET= TIL)
      CALL  TIME(ET,NH,NI")
     _Q^LL_LfC (L I_NE, NPGj^Oj-JAYjjrR^
                                 _
                     NH.NM.ET, (0( I), I"l,13> ,HOLO(L), (UNIT^N ,M
 2500 FOKMATITU, 12,':',I2,' HRS  ',F8.2,«  HRS tET)',
     l.3,4A4)
    1 CONTINUE
      MMN-3)  10,10,9
   10 AV(KT)=  SUM
     ' CALL L PC I L liM'E", NPG JMO, UAY, YR)
      HRITE(3.2601>(D(I)tI-l»10)'i(0(J)tJ-l*fl6),AV(KT)t(UNITtN,M),K«l,«)
                                         637
-------
03/07/74             FCRTPAIN                                                     0003

 2601 FCRMAT(T26.'  TOTAL :•»T43,7A4t2X«6A4,2X,F9.3f4A4>	
      IF(NOfl-l)  51t5l,52
   51 RIKTC)*  AV(KT)
      GO TC 53    	
   52 R(KTC)*  AVtKT)/ (TtN08>-TU) )
   53 NK= N»3
      C ALL L PC ( L I NEtNPGt^Ot DAY tYRJ ____
      WRI~TE"l'3V2fc"62)  IOJ I), I = l,10)t tRLABt KTO.MM) ,MM-1, 3 ) ,R< KTO) .
     l(UNIT(NK,M),M=l,4l
 -1602_F 0£MA TJ J 2 B , 'RATE: ' rT43, 7A4, 2Xt6A4, 2X,F9.3t4A4/)
      LINE = LINE"*I
      KTO= KTO+1
      GC TC 20
    9 AVIKTI*  SUM/NOB
      CrtLL LPCtLINE.NPG,l*0,CAY,YR>
    __ KR 11 E ( 3 , 2 600 M 0 ( N t I = I f 1 0 ) ,J D U ) t Jf 14 f.1 61t_AV ( KTJ , ( UNn(N,M )
 '2"6bO'FORKAf(T"23t"'"A"~V  f~S" A""G E  : ' •', f A3 ,7AT, 2X t6AAT2X, F1?".
      LINE=  LINE+l
  _ 20 CONTINUE ___ _  _____
      ">RSC'2"»  100".d*(l.C-(AY16A/AYT6A))'
      PUH2S  =  ^00.0*(l.C-«AY206B/AY206E)/(AY^OOB/AY2COE)))
                  .0* (t . C  MAY 108C/AY 1C8E )
      P'HCHS
      X9CA  = AZ90A/(ICC.C-AZ9CA-AZ90B)
      RC9C  f_AC.90AJ'(l.C-AZ90B/lpO.O)/i_lip+_X90A) _  _
      X 30 1C" = TAZ 30 1 A"*T17C + X9 0 A ) -~X~90~A~* < 1 00". O"- AZ 30 1 B J ) / ( 0 -T26 5* <
     IAZ301B)-AZ301A)
      X301B = AZ30lB*(l.O+X90A+X301C)/(100.0-AZ301B)
      X3C2C *  (AZ302A*! l.d»X90A )-X90A"*( i 10"676-A'Z302B"fT7( 0. 3265* ( 100.0-
     IAZ302BI-AZ302A)
             _AZ302B*(l.q + X9qA + X302CJ/( iqp.O-AZ_302BJ __
               AZ20bc7< l'dO".0-AZ200A-0^67*TZ2"OOC")
      X2CCA -  UZ200A-32.65*X200C)/I100.0-AZ200A-0.67*AZ200C)-X90A
            »  76.5*X200A/X302C
    _     __ ___
      PVC   =  10.0*(.O-X20DCX302C)
      SGI 088=  AG100E*AY108B*0.0829/AY108E
      PSCHS =  100 . 0*SG 1 C8B/ I[X200 A*RC90J ___
      PRS   •  100Vd*"R"s4Cl/(X200A*RC90')
      BGIOA »  23340. 0*SCRT!AOP10/(ATL10+460.0) )* ( 1-0-A Y10D/1CO .0 )* ( AY 1CA
     1/0. IE 07)/(1.0-VP10D/1 4 .J ) ______
      BG13A «  2 3340. 0*S CRT IAD"P10"/"( AT L 10+460.0) )* ( 1 .0-AY10D/1CO.O )* ( AY16A"
     1/C.1E 07)/(l.O-VP10C/14.7J
    _ PRSl  =  100.0*RS401/(BGIOA-DGI3A) ___  __
     "ERV400-  fOO.O*R~S401/'ABS"(X200A*Rl£9"0-SGl61FJ
      NPG= NPG+1
      HRITE(3i2000> M0t CAY. YR ,NPG
      WRITE<3,2001)
      CALL CATE(MO.DAY,YR,T1,T2)
  	WRITE (3,90^0) _	
"9000 F"CRf"AT'(T16,'"SUMKA»V  OF  INTEGRATED PROCESS PERFORMANCE:'/)
      WRITE(3t9001)  PRSC2
 900l_ FORMATtT8,•  !._  S02  REMOVAL'tT56»«PRS02 «'.T65.F7.21'  % (ACTUAL)1,
"  ""  fr9f, • 9C.'0"~«"(GOA"L)I/J             '      ""
      WRITE(3»9C02)  PUH2S
                                       638
-------
  "/07/74             FORTKAIN
                                                                                     cco,<
            ..-U-"--2-'—.12XJI/T IjLIZATjON«,T96 •' PUH2S -• ,T65, F7. 2,'  t  !,' 95.0  *  (GCALP71
      WRITE(3,9003) PVCS
_9003_7_J	  .   __.	
                	  ""           TG"o"ATrr/T
        FCR.MATI IT8 , l_3.__ACI_g_CONV§RS ION  (TO  SULFUR >',T56 , ' PVC S  = • , T65 , FT . _
       12,'  %  ( ACTUAL >',T91,« 99.0 :TTG~G~ATfr/y ----- ----------------------
                       PHCHS
- ?P.9^"R.';*[I.T8».L*r_.H2_.UTlLIZATrON  (TO  H2S)',T56, 'PHCHS *' ,T65, F7.2. '
       I*  (ACTUAL) ST91, • 90.0 SSTGOALT1?'")' ------------------
        KKITE(3,9005) PRS1.PRS
-- ?00!L FCRJ/ A T ( T 8j • _5_. __ SUL FU R_ REC fW |R YS T 56 , • P R S _ =• , T 65 1 F7 . 2 , •  « (ACTUA
       R)»,T91, '100.0 ? (GOAL) 0> S ORBED S 0 2VT 6 5 , F 7 . 2 , T TTTC'TU 'ATTST 9TT
        '  25.0  *  (GOAL)  OF STRIPPED SULFUR'/)
        WRITE I 3»9006)JH)H2
   9006" ' F C R MA T ( T 8 V ' " 6 .   H 2~lJT"l !

       _WR IT F. (3,9007) X90A
  " 90157 'f- CRN A r n"6-,'f~r.
       1' LB  S/LR  C'/)
        WRIT6(3,9008) _
         C! Aft T8","«~9~. "ACID LOADING TN LET C/TR BONMiJ N7T 'Tf 5 6 , ' X 3 0 1 C
       165FF7.4,'  LB ACIC/LB C'/)
                         _      _   __  ___   ____          _
   9010 FCRNAf (T8V'f67~ PCI sTURE'~CONfE~N~T  INLET  CARBON  6" UNIT*",' f56", 'X3C1B
       l=--'fT65,F7.4, '  LB H20/LB C'/)
        KRITE(3,9011)  X302C
   9011 FORMAT(T8f«u.   ACID LOADING INLET CARBON  8"  uNiT',T56t»X302C =',T
       165,F7.4,'  LB  ACID/LB C'/)
  	  HRITE(3,9012)  X302B
   9012 FORMAT(T8,'12.   ^CISTURE CONTENT  INLET CARBON  8"  UNIT',T56,'X302B"
       1=',T65,F7.4,'  LB H2C/L8 C'/)
        WRITF.(3,9013)  PVC
   9013 FCRKAT(T8»' 13.   TCTAL ACID CONVERTED 8"  UN I T ' , T56 t 'PVC   =',T65,F7
  ___             __      _______ __   ___
   9014 FORMAT fT.8, «"l4.  "SULFUR CONVERSiON (TO H2S) • ,T56, • P~SC"HS =',T65tF7.2
       It1 ?'/)
   ____ W. R! TE ,J«1,20>
   1001  FORMATI20A4)
        WRITE(3,2006)  (0( J ) , J= 1 , 20 )
        FCRCAT J T2J_»20_A4J
     23          "
        GC TO (666, 6651, NTCPT
    665 NPG= ^JPG-fl ___
        W«Tf E(3,2~6"00 )  MO,CAY,YR,NPG
        WRITE(3,2001)
                                        639
-------
03/07/74            FORTCAIN                                                     0005

           CATEtMOtOAY,YR,TltT2)	    	    	
         .   .
      N="6
      NENC= 1
     " BG10A = 23340.0*SORTfAOPiO/(ATL10+460.0))*(1.O-AYlOD/100.0)* * t AY 16A
     1/0.IE 07)/(1.0-VP1CD/14.7)
      BC12A » (0.3265*X302C+X90A)»RC90	
      BOiiA = Ruri*AbTiA7ibo".o '
      BC12A = R012*AD12A/100.0
      ??w l 2 A!__.'P • *?.I5*x302C + X9_0_AJ »RCV<12
      "PC2CiA"~BCf2A~"
            != 0.0329*ftG100E*AYl08B/AY108E
   	BG201B= O.OBj9'»AG200E*AY200B/AY2pOE	
      BG2C3R="0."0"    	"
      GC TC  (7l,72>tNPRH2S
   72_AG2COE- AC100E		  _	
      BG2ClB-"('oTO"829*AC2FOE*AY20dB/AY20'OTr - "BG104B
      IFIBG201BI  172il72,l71
      BG2plB»__OiO	.	,	
      BG2C3RS BG104B
      BG2C5A* 0.0829*AG200E*AY206A/AY206£
      BG?05B» p.0829*AG20pE*AY2p6B/A_Y2p_6E	
      BC2C2A= (X2bdAVX9CA)*RC90
      BC1C3A= X90A*RC90
              RS401                	    	
              . ___
      BCldlA* RD101*AD101A/100.0
      BC1C2A= RU102*AD1C2A/1CO.O
      BC3C1A= Rp30l*AC30lA/l.CO.p
      "SI10 =             ...............
      SC10 = BG13A+eC12A+BDllA4B012A+BCW12A
      S03CO= BC201A+803C1A           _
      SI2CO= BG201B+BC2C1A+BG203R
      SC200= BG205B+BG205A+BC202A
             BCl03AtBGlC4B*BGlQAS*e0101A4-BD102A
      STBIN
      STBCUT« BC13A + BDUA+BD12A+BCW12A  + BG205B+BG2C5A 4- BG104B+BG104S*
      Bplp_lAL*Bp_102J. +  BD301A _ . ___
      ~GG f C ( 60 f 61 1 1 NPRH2S
   61 STBCUT- STBOUT-BG104B
      h.RITE.(3»?t01>_	  	
 9101">CRMA'ffti6f« SULFUR"  MA'TERTAL
      GO TO 62
   60 JkR I T E t 3It 9100 )	
"9100"FORMATTfl6,tSULfrUR  MATERIAL  BALANCE
   62 DC 660 L = UMKT
   	REAOIItlOlO) NSKIP.KT.LOCf(D(I),1=It 131
 ibio'FORMAT(sx",2lit 12fibx,i3A4r'
      GC TO (100,200,300f400t500t600»700,800)fKT
  200_WRlT.(3f 3000J	
      GC'TO 700"  "
  300
                                       640
-------
  03/07/74             FCRTKAIN                                                     OC06

                       *" _ 1 I  *    CARBON    PRECONDITION
                            -"J-L "^"' * " • — — **^ " *•• •   ........ i — LI  Hi ... . ..... _____________ -     . ___ _  _ .. _ __ _ _  _      - ____ .
       ic o t y i
       A c f\  / I
        GC TC 700
    400 WRITE I 3,5100) ___
   5100 F OH PAT t//fi,iT'S  U L  F TTS    G" E N E""R ~A~T~0"in7~}
        GC TC 7CO
   _50C GC TC (501, 502), NEND
              ~"
        CAUL LPC(LINE,NPG»PC,CAY,YR)
    502_WR I T E < 3 , 6 100 ) __  _
     '   F'CRM'AT(/7f37T'  H  2 S    GENERATOR/SULFUR - S T  R  I
       1 P P E R«/)
     - _GO TO 7CO
    600 V««"ltE'('3,9300l
   9300 FCRfAT(//T^2, '  OVERALL    SULFUR    BALANC EV)
  ___ GC^_TO _7CO
   "700 WRU'F'J 3 ."9BOO")     "
   9500 FORN4T(T23, 'IN')
       _GC TC 100   __      __
   "800 W R'i T E I 3", 9 600 !
   9600 FOK^ATt /T22, '  0  U T«)
  _ ICO GC_TC  (101, 102 )t NPRH2S
    102"GC "TO" (101 , 1 OlTTiNTK IP
    103 BGlO^b" 0.0
  _ 1 0 I V.R U E < 3 1 9 700 )  ( n ( I ) ,1 = 1 , 1 3 » BLCC ) ,UN I TN, M ), M« 1 ,
   97CO FC'KKATUSOtlSA'VfF'J.'
    660 CCNTIMUE
        GC TC (63, 666), NEND
     63 NPG= NPG+1
        WRITEI3.9400)  MO, DAY, YR ,NPG
                     ° 5 » 1 2 , • / ' , 1 2 1'/'« I2>T118,'PAGE ',
        N= 13
        NENC  2
        NKT = 18
        BG10AH= 0.00518*AG100E*AY108B/AY108.E
    	BG 2 C 3 C =_0 ._q 0 51 8 * A G 2 0 0 E* A Y 2_0OC/ AY 20 OJ
        B G 2036 = 0". 0:6"518* A GT6'6 E * A Y 2 00 B7 A Y 200 E"
        GC TC <75,76),NPRH2S
     76 BG2C3R= BG104H
        BG'20T8= (0.0"0518*AG2COE*AY200B/AY2CCE) -BG104H
     75 BG203C= 0.0051 8*AG200E*AY200D/ AY20CE
    _ BC201H= 
-------
                 03/07/74
                                     FCRTMAIN
COOS
N>
SY.VBCL
MAX
I*ODE
SYVBCL
KTG
NTCPT
T2
L
J
AY10A
AY2CCE
AY1CCE
AZ906
AZ301B
X3C2B
PVCS
PRS
AY1CD
NKT
A011A
RCwl2
BG2C3R
tC103A
EDIC2A
A~3C1A
SC2CC
LCC
E32030
EG2C5H
HI2CO
AY1QSD
•*C«12
SYMBOL
AV
RLAB
! JTAAFR
LA8EL
CC998
C2COO ""
C'»CCC
LOCATION
0000
00 14
LOCATION
03FC
0410
0424
0438
044C
02C4
0314
033C
0364
C2FO
047C
0488
0498
02CC
04A8
02 E4
0380
03F8
03CB
03E8
02F8
0304
0484
039C
03AC
03A4
0348
02EO
LOCATION
02C4
0518
IJTACOM
LOCATION
011C
~ 	 02!,8
041C
SYMBOL
MET
C
SYMBOL
VP100
KO
LINE
ET
NK
PUH2S
PUH2
PHCHS
RC90
X301B
X200C
PVC
RS401
BG13A
BCUA
6012A
BC201A
BG205A
6G104S
R0102
SI10
SQ100
BG104H
AY20CO
BG2050
H0200
HIIOC
W0301
SYMBOL
B
UNIT
DATE
LABEL
00049
02001
COO 05
LOCATION
0004
0018
LOCATION
C400
0414
C428
043C
0450
C45C
0460
0464
C46C
0474
0480
C48C
0390
03AO
C398
03AC
04AC
C3C8
C3EO
038C
039C
03EC
C3C8
C30C
03BO
0388
C3CO
02F4
LOCATION
0394
C56C
INPUT
LOCATION
0128
02EC
048C
COMMON
SYMBOL
THC
KT
SCALARS
SYMBOL
NPG
CAY
KL
NH
MM
AY2068
AY108C
AY108B
AC9CA
X302C
AZ20CC
SG108B
BG10A
PRSi
3C12A
R012
BG104B
AY206A
B0101A
AD102A
S01C
STBIN
BG203C
BC201H
AY206D
BG103C
H0100
WD101
ARRAYS
SYMBOL
R
CALLED
TIME
LABEL
C0999
02C04
05.000
LOCATION
C006
0068
LOCATION
C4C4
C418
C42C
C44C
0454
C3CC
• 0336
C344
C368
C478
C33C
C4<5C
G3S4
C49C
03A4
C37C
C3CC
C37C
C3E4
C35C
C3B4
G3FC
0354
C3AC
031C
03BC
C3CC
035C
LOCATION
0378
SUBROUTINES
LPC
LOCATION
019C
CJ28
C4CC
SYK3CI.
TKO
LINET
SYMBOL
M
YR
NOB
NK
PRSC2
AY2C6E
AY1C85
X9CA
X301C
AZ302A
AZ2CCA
AG100E
ADP10
ERV4CC
BD11A
AD12A
BG201B
8G205B
R0101
BD3C1A
SC300
STBCUT
AY2COC
BG205C
BC202H
BG104C
won
ViD102
SYMBOL
T

IJTSSQT
LABEL
C0050
030GC
OOC06
LOCATION
OOOC
006C
LOCATION
0408
041C
0430
0444
0458
0318
0340
0468
0470
0320
0324
034C
0200
04AO
03A8
0258
03CO
03CC
0388
0388
03BC
03F4
0304
03A8
03R4
03C4
0208
0354
LOCATION
04B8

SORT
LOCATION
01AA
036C
0526
SYMBOL
N
SYMBOL
NPRH2S
Tl
SUM
I
AY16A
AY200B
' AY100C'
AZ9CA
AZ3CIA
AZ302B
X2COA
PSCHS
ATL10
NEP^D
ROil
BCV.12A
AG2COE
BC202A
A0101A
R0301
SI 200
NSKIP
BG2C3B
AY206C
AZ20C8
BG1040
H012
WS401
SYMBOL
HOLD

IJTFXIT
LABEL
01000
OC004
C6CCC
LOCATION
C010
LOCATION
O'tOC
0420
0434
0448
C2C8
C2FC
" 0"3 34
0360
CtEC
0328
0484
0494
02 C4 ""
04 A 4
C378
cjec
C31C
C3DO
0356
0384
03C4
04tC
0398
03CS
032C
C3CC
02CC
036C
LOCATION
04E8

EXIT
LOCATION
0203
OJCA
C568
-------
                 03/07/74
FGRTKAIN
                                                                                                 000009
CO
COC07
C0021
CC01C
C2602
09CC1
C9C06
C9011
C2CG5
CCC72
09101
CC2CO
CC50C
C930C
C01CO
CC660
C0666
050E
06E8
0864
CAD4
OFFC
1264
1458
163C
1914
1A38
18FC
1CC2
1080
1E14
1FIA
218E
0700C
COC22
02601
00009
09002
090C7
09012
C1001
00172
00060
C03CC
C0501
00700
00102
00063
0620
C6FC
C958
CB1E
1060
12BC
14C4
16CO
1940
1AF8
1C16
1CE8
1DBE
1E3A
1F54
CCCC8
0003C
CC051
C26CO
09003
C9C08
09013
02006
00171
C9100
C4100
C0502
C9500
00103
09400
C68A
07CE
CSS6
OC30
10CB
131C
1534
171C
1948
1BCC
1C2C
ICC2
1CC4
1E60
1F94
08000
02500
00052
OCC20
09004
09C09
09C14
00023
00071
00062
OC4CO
06100
00 800
001C1
OOC76
06AO
0804
0988
OC6E
113C
137C
1590
171E
1950
IB46
1C78
1018
IDEA
1E68
2058
C0003
COCOl
00053
0900C
09C05
09C10
09015
C0665
00061
C101C
05 100
00600
C9600
C9700
C0075
.—.ny,,, 	 	 -_ 	 -__^ T&L"7
C6DC
0840
C
OFAC
11B4
13E8
15E8
1758
1A96
1BB4
1C8C
1D6A
1ECO
1F04
2073
                 COMPILATION COMPLETE
    AMOUNT OF COPKON OC0112
                                                                       AMOUNT  OF  CORE  C10304
                                                           ADDRESS
-------
                DISK OPERATING  SYSTEM/360  FORTRAN

_SUEPCUT_INE jNPUT(ETIME,C6Tft,NCf»)
 INTEGER T'HoYtMo  "
 C:»FNSION ETIKE(12),CATAU2),C(20>
                                                          36CN-FO-451  CL 3-8
      R£AD<1,1002) Kf,N,MCOE,(D(I1,1=1,17)
 1002 FCRMATUXTI2,2X,12,M,4X,17A4)
	cc i 1 = 1,VAX
      REACt 1,1000 I K, ETIMEd ) ,0"ATA(T)
 10CO FCRMATJ 15, 5X,F-10.4,5X,F10. 4)
 	IF(K) 1,1,2
            _
    2 NCE= f-1
      GC TC 3
    1 CCNTINUE
      NCB
      RfcAC(l,lCCl) K
 1CC1 F-CSI"AT( I2
    3 RETURN
      E.NC
         03/07/74
                         INPUT
                                                                                          OC02
SYM8CL
MAX
fCCE
SYM8GL
I
IJTAAFR
LABEL
C1C02
LOCATION
0000
0014
LOCATION
0074
IJTACOM
LOCATION
OOFC
SYMBOL
MET
0
SYM3CL
K

LABEL
01000
LOCATION
0004
0018
LOCATION
0078

LOCATION
0170
COMMON
SYMBOL
THC
KT
SCALARS
SYMBOL
NOB
CALLED

LABEL
00002
LOCATION
COC3
0063
LOCATION
CC70
SUBROUTINES

LOCATION
CISC
SYMBOL
TMO
LI NET
SYMBOL


LABEL
OOCC1
LOCATION SYMBOL LOCATION
OOOC N C010
006C
LOCATION SYMBOL LOCATION


LOCATION LABEL LOCATION
01A2 01C01 01EO i
CCCC3
        01EA
    COMPILATICM COMPLETE
                                  AMOUNT OF COMMON 000112
AKCUNT CF CORE C00624
ADDRESS BASE TABLE
0108
-------
                     DISK OPERATING SYSTEM/360 FORTRAN   360N-FO-451  Ct 3-8

     SUBROUTINE  DATE(MC,DAY,YRtTi,T2)
      INTEGER  DAY,Y«,THC,TMO
      D1PFNSION  0(20)
      COE'fCN MAX, MET, THC,TMO,N, MODE, 0,KT,L1NET
      NfO=  MO
      NCAY= CAY
      T=T2
       _
      CALL  TiMeif I,NHI,NM"D
      CALL  TIME(T2,NH2,NM2)
      IF(NH2-NH1)  3t2,l
    2  IF(NM2-NM1)  3,1
    3  NCAY=  NDAY+l
    1  IF(T-U-24.0)
    5  T=  T-24.0
      GC  TC 3
    *  !F(.^CAY."P*Y-1  6,6,7      	   __
   ~6"~WiTET3720"02T MO, UAY, YR,"NHl,NMI, NH2,NM2
 2002  FCRPATIT20,'  DATE: ' , 12 , '/•, 12,•/',I 2,T41,'TIME CF RECORD:
	11? ,12,'  H R_S	TO	IfJAtlll' L?' '  HRS> >	
      GCTTO "T5"""
    7  GC TC (8,9,8,10,8,10,8,8,10,8,10,8),MO
    8  IF(MOAY-31)  11,11,12
   12  NCAY= NOA"Y-
      NfC=  MO+1
  	GO TO H	
    9"! FTNoTY-28")  11,11 ,lT
   13  NOAY= NOAY-28
      GO  TO  11
   10  IF1NCAY-30)  11,11,14
   14  NOAY=  NOAY-30
   11  IH=  24
      lf=  0
      WRITE I 3,2002)  ^0,DAY,YR.NH1,NKliIH,IM
      IH=  0
      WRITE(3,2002)  NNO,NCAY,YR,IH,If,NH2,NM2
   15  T=  T2-T1
      WR1TEI3.2003)  T1,T2,T
2003  F C R I" A T (/T20,«  PR PC E S S _|L APS ED TIME OF PERIOD:    START 'tF6.2.' HR
    IS" 7" E'ND   ',F6.2,'  MRS"     LENGTH OF PERIOJ1  "TFlcZ,1 HRS'7/5
      RETURN
      END
                                       645
-------
03/07/74
DATE
CC02
SYF3CL
K4X
VCCE
SYFBCL
N*G
72
NP2

UTtCCf
L63EL
CCC02
CCCC6
CCOC9
CC013
LOCATION
COOO
0014
LOCATION
C068
OC84
OODO

TIME
LOCATION
OOEO
0132
0242
C344
COKPILATICN
SYMBOL
MET
0
SYMBOL
MO
Tl
YR


LA8EL
00003
02002
00013
02003
CCHPLETE
LOCATION
0004
00 1 8
LOCATION
COA4
COBO
OOAC


LOCATION
OOFO
0180
0252
037C
AMOUNT OF
COMMON
SYM30L
THC
KT
SCALARS
SYMBOL
NCAY
NH1
IH
CALLED

LABEL
00001
OC007
CCC10
COffCN 000112
LOCATICN
ccoe
C06E
LOCATICN
CCBC
OOC4
CCC4
SUBRCUTINES
^
LOCATICN
COFC
01CA
027C
AVOUNT
SYMBOL
T*G
LINET
SYMBOL
DAY
NM
IP


LABEL
COC05
00008
LOCATION
OOOC
00 6C
LOCATION
OOA8
OOC8
0008


LOCATION
0110
0214
00014 0280
OF CORE 001296 ADDRESS
SYMBOL
N
SYMBOL
T
NH2


LABEL
00004
00012
C0011
BASE TA3
LOCATION
0010
LOCATION
COCO
COCC


LOCATION
0122
0224
LE 0408
-------
                      DISK OPERATING  SYSTEM/360 FORTRAN   360N-FO-451  CL  3-8

       SUBROUTINE TIPE(ET,NH,NM)                              	
       INTEGER THO.TPO
       DIMENSION Dt2C)
              REQUIRED FOR VALUES  MET.THOtTMO
 C      ™  >£t= T  WHEN"ELAPSED~"f iWf'TN HRS;  THIS VALUE NORMALLY"
 C          MET = 2  WHEN ELAPSED  TIME  IN MINUTtS
_c __ THO,  TMC «__TIME CN_2A:qo J:LOCK_WHEJ\I_JET=_O^J_N_HR_S AND MIN, RESPECTIVELY
       CANNON" MAX, PET, f HCt f Mfi,N",NODE,"C, Kf ,L INET '                         ..... "
       NM= 0
___ NH=_ q ________ . __
       GC TO I It 2), MET
     2 ET= ET/60.0
___ 1_ I F ( E T - 1 . 0 I 3 fj^^ _______
     3 IFTEt-0"."65T 5,6,6 ~
     5 NH= THG
___ Nf= THO  ___    ______  _
      ~ G o " f o is                                  ;
     6 T= ET
__ GO_Tq K) ___________
     4 T='er"         "           "
     9 I FIT-24.0 )7t7,8
_ 8 J= T-24.0 ______ , ___
      'GC~TC""'9~ "
     7 IF(T-l.O) 10,10,11
    11 T» T-1.0 ____  ______
       NH= IMH*1
       GC TO 7
    1 A I F ( N K-6 O  1 2 ,3 ,13
    13 Nf=  NK-60
       NH=  NH*1
       GC'TO'l'i"
    12 NH=  NH*THO
    1 7 I FJUNH- 2
-------
                 03/07/74
TIME
                 0002
OO
SYMSCL
^AX
MOCE
SYMBOL
NP
LOCATION
0000
0014
LOCATION
0094
SYMBOL
MET
0
SYMBOL
NH
LOCATION
0004
0018
LOCATION
0090
COMMON
SYM3QL
THO
KT.
SCALARS
SYMBOL
ET
CALLED.
LOCATION
ccoe
0068
LOCATION
ccec
SUBROUTINES
SYFBCL
T*C
LI NET
SYKBOL
T
LOCATION
COCC
006C
LOCATION
0098
SYMBOL
N
SYMBOL

LOCATION
C010
LOCATION

IJTACCM
L4BEL
CCC02
OCC04
CCCIC
CCC16
LOCATION
OOC4
0118
0170
0204
LABEL
00001
00009
00014
00015
LOCATION
OODO
0120
C1B6
0216
\
LABEL
00003
CC008
00013
LOCATION
CCEC
C130
01C6
LABEL
OOC05
OCOC7
00012
LOCATION
OOFO
0142
01E4
LABEL
C0006
coon
00017
LOCATION
01CA
C152
01F4
                 COMPILATION COMPLETE
    AMOUNT  OF  COMMON  000112
                                                                      AMUUN1
CORE
-------
        DISK OPERATING SYSTSM/360  FORTRAN

I^E_ LPC(LINE,NPG,MO,DAY,YR)
                                                               360N-FC-451   CL  3-8
           INTEGER OAY,YR
           DIMENSION  0(20)
        __CCV MC \_ M_AX , MET,THC,TM.C,N,MOPE. C,KT.LINET
           I<=:LINE-LlNETt  1,1,2
         1 LINE=  LINP+1
        	_5G TC  3
         2 I
               :=  t.
              ;= J.PG+l
     	W? I T _EJ_3,1000)  MQtCAY,YR,NPG	
      10CO FCS.WAT(1H1,T105,I2,'/' , 12, '/ ', 12,T 118, • PAGE ',l2Tr
         3 RETURN
           ENC
VO
                 03/07/7A
                   LPC
                                                                                                  OC02
SYV3CL
KiX
SYV5CL
LIVE
LOCATION
0000
0014
LOCATION
CC58
SYMBOL
MET
0
SYMBOL
NPG
LOCATION
0004
0018
LOCATION
C05C
COMMON
SYMBOL
THO
KT
SCALARS
SYMBOL
MO
CALLED
LOCATION
coce
ccfce
LOCATION
CC6C
SUBROUTINES
SYKSOL
IfC
LINET
SYMBOL
DAY
LOCATION
OOOC
006C
LOCATION
0064
SYMBOL LOCATION
N 0010
SYMBOL LOCATION
YR C068
IJTACCM
CCCC1
LOCATION
0062
LABEL
LOCATION
LABEL
01COO
f t~nt tj r^K- r>/%r>i 1 **
%
LOCATION
01CC
A U m ihl T t
LABEL
-ic cnoe rir*~rf
LOCATION
0132
LABEL LOCATION
f*~y-~t* — "ft "'i ff-f 	 ^-i~n i ~^« 	 fc,-^ — i— K —
-------
                        APPENDIX A-23



              DETAILED S02 SORBER DATA ANALYSIS





                                                        Page



1.   Evaluation of Rate Models for S0£ Sorption          651



2.   Effect of Fly Ash on Carbon Activity                659
                           650
-------
                          APPENDIX A-23-1

            EVALUATION OF RATE MODELS FOR S02 SORPTION
     Amundson  Equation

     The Amundson  equation
(1)
      is most  conveniently  rearranged  to  the  form
(2)
            1  dXy  _
 k
Xvs
      in  order  to  allow  the  determination of k and XVs•  Figure
      A-23-1 shows that  the  equation  does not represent  the
      data unless  the  rate constant,  k, and Xvs are S02  concen-
      tration dependent.  The Amundsom parameters extracted
      from the  SO? sorption  rate data are given in Table
      A-23-1.
         Table  A-23-1.   PARAMETERS  FOR AMUNDSON EQUATION FOR
                        S0£  SORPTION  DATA AT  200°F WITH
                        NITRIC  OXIDE
S02 Cone. ,
PPM
2500
2000
1500
1000
500
Rate Constant,
k
0.33
0.38
0.51
0.66
0.97
Saturated Loading,
Xvs
0.499
0.559
0.360
0.390
0.417
     Since there was an apparent effect of S02 concentration on
     the rate constant as shown in Table  A-23-1,  the Amundson
     equation was not considered to be suitable  to represent the
     data.  It is interesting to note that the constant, XVs,
     extracted from the Amundson equation does not disagree
     appreciably with 0.38 which was determined  by extrapolation
     of the experimental data to a zero rate.
                               651
-------
              Figure A-23-1.   Amundson approximation to  sorption data at  200°F with nitric  oxide
Ul
      X +•>
                             0.04
          0.08     •            0,12
Sulfuric Acid Loading on Carbon, gnts Acid/gms Carbon
                                                                                             O 2500 PPM S02

                                                                                             A 2000 PPM S02

                                                                                             e 1500 PPM S02

                                                                                             A 1000 PPM S02

                                                                                             O  500 PPM S02
0.16
                                                                                                             0.20
-------
      Jost Equation

      The Jost equation
(3)
~3t
                    2 aX
      is most conveniently arranged in the integrated form
(4)
      to determine a and b,  second and first order impedances
      (reciprocal rate constants).   The data are presented in
      Figure  A-23-2.    The impedances that were subsequently
      extracted are given in Table  A-23-2.     Again there was no
            Table A-23-2.
               REACTION IMPEDANCES FOR JOST
               EQUATION FOR 302 SORPTICw
               DATA AT 200°F WITH NITRIC
               OXIDE
S02 Concentration,
PPM
2500
2000
1500
1000
500
a
5.844
4.797
5.414
3.261
2.548
b
2.53
2.14
1.71
1.33
0.88
      justification for forcing an apparent dependence of the
      rate  constant on S02 concentration.   Therefore the Jost
      equation was  not considered as  a suitable function to
      represent the S02 sorption rate data.

      AVCO  Equation

      The AVCO equation
(5)
            dXv
                    AXvsy
                          B
                      1  +
                1 -
Xv »
Xvs'
                             T77
                                      1/3
                                   vs
                               653
-------
               Figure A-23-2.   Jost  approximation to  sorption data at 200°F with nitric  oxide
Ul
-P*
                                                                                              O 2500 PPM S02
                                                                                                2000 PPM S02
                                                                                              • 1500 PPM S02
                                                                                              A 1000 PPM S02
                                                                                              D  500 PPM S02
                             0.004
         0.08                 0.12
Sulfuric Acid Loading on Carbon, gms Acid/gm Carbon
0.16
0.20
-------
      can be  arranged in the form
(6)
            dXv/dt
                                        B
                                AXvs (1 -
                                          X
                             1/3
      to  the  data is  given in Figure A-23-3 and the reaction
      parameters  extracted from the experimental data are given in
      Table  A-23-3.
        Table A-23-3.
       REACTION  RATE  CONSTANTS  FOR THE AVCO
       EQUATION  FOR S02  SORPTION DATA AT
       200°F WITH  NITRIC OXIDE
S02 Concentration,
PPM
2500
2000
1500
1000
500
A
-0.75
-1.07
-0.67
-1.63
-1.55
B
2.42
2.70
2.00
2.89
2.14
      It  is  expected that  if the  rate  model  represented  the  rate
      data one  straight  line would  be  obtained  through the data
      which  would  necessarily scatter  about  the curve.   It can be
      seen that a  definite trend  is present  with decreasing  S02
      concentration.   Therefore,  the rate  expression  does not
      represent the  data;  and there is considerable scatter  in
      both of the  rate parameters..   Based  on this the equation
      was not considered as a suitable function to represent the
      S02 sorption rate  data.
     Tracor Equation

     The Tracor  equation
(7)
-  ky
                           Xv
     can be evaluated by  rearranging  to  the form
                               655
-------
   Figure  A-23-3.   AVCO approximation to sorption data at
                     200°F with nitric  oxide
                                                    O  2500 PPM S02

                                                    A  2000 PPM S02

                                                        1500 PPM S02
                                                    A  1000 PPM S02

                                                    D  500 PPM SO?
0.75
0.85
0.95
                                                                      1.05
                                656
-------
(8)
Ln
-  Ln[k] + n Ln [1 -
      to allow the determination of k and n from experimental
      data.     Figure A-2.3-4  shows that the equation does not
      represent the data unless the rate constant is made concen-
      tration dependent.  The rate parameters for the Tracer
      equation are given in Table A-23-4.
           Table A-23-4.
              PARAMETERS FOR TRACOR EQUATION
              FOR  S02  SORPTION DATA AT 200°F
              WITH NITRIC OXIDE
S02 Concentration,
PPM
2500
2000
1500
1000
500
k
0.341
0.383
0.497
0.654
0.777
n
' 0.724
0.563
0.955
0.959
0.951
      Again there is no reason to make the rate constant a function
      of concentration; therefore the Tracer equation will not be
      considered any further.
                               657
-------
            Figure  A-23-4.   Tracer approximation  to sorption  data at  200°F with nitric oxide
OO
                                                                                           O 2500 PPM SO?
                                                                                             2000 PPM S02
                                                                                           • 1500 PPM S02
                                                                                           A 1000 PPM S02
                                                                                           O  500 PPH S0»
                                                                                                     -0.7
                                                           [(1 -
-------
                    APPENDIX A-23-2

         EFFECT OF FLY ASH ON CARBON ACTIVITY
In the application of the Westvaco Process to flue gas
desulfurization, many of the applications are expected to
be on coal fired boilers.  The current pilot plant operates
on an oil-fired boiler; however, the boiler is equipped to
fire coal and the probability exists that in the event of
severe oil shortages the boiler could be fired with coal.
In order to obtain a preliminary assessment of any effects
carbon was exposed to fly ash laden air for 5 days.  This
is comparable to the time the carbon will be exposed to flue
gas during the integral runs.

The equipment used in the tests is shown schematically in
Figure  A-23-5.     Fly ash was metered into an air stream
which fluidized the batches of carbon in a Plexiglass
column.  The unit was set up so that carbon samples could
be taken periodically for ash analysis and S02 activity
measurement.
Conditions

1)  Gas:



2)  C Bed Weight

3)  Fly Ash:
a) Air at room temperature
b) Rate of 3 ft./sec. @ 70°F, 15.7 CFM
     @ 70°F
About 325 grams

a) Source
                   b) Rate
- From boiler combusting
   Southwestern Virginia
   coal
- 15 gms./hr.,  0.24 grains/
    SCF
                   c) Part. Size - 9570 <50y (see Figure
                                      A-23-6   for
                                     distribution)
The fly ash grain loading was chosen to be what was typical
of that from a boiler with a 75% efficient cyclone and no
precipitator.  This is many times the expected loading after
the gas passes through a precipitator.  Chemical composition
of the ash was not determined; however, the particle size
distribution is shown in Figure A-23-6.     Ninety-five
percent of the ash was smaller than 50 microns and over 50%
smaller than 20 microns.
                          659
-------
           Figure A-23-5.   Fluid bed set-up  for  fly-ash exposure tests
                                                                           -*•  To Exhaust
A1r
     Roots-Connarsvilie
           Blower
                                                            lyclone
                      Pressure
                       Gauges /^v.
                                  -
4"0 Plexiglass Unit
   (3 Stages and Plates
   with No Downcomers)

   Plates:  8% Open Area,  1/8" Holes
             on 0.42 Centers
                                                          Gas Rate    = 3 ft./sec. = 15.7 CFM (Air)

                                                          Fly Ash Rate = 15 gms./hr.
-------
           Figure A-23-6.   Size distribution of fly ash
                              used in  carbon  exposure  tests
O)
N
GO

•O
CO
ra
I_
0)
e
n)
L.
0)
QJ
O)
id
O)
OJ
OL.
20
               10
                     20        30        40

                        Average Particle Size,
50
                                   661
-------
 The ash content of the activated carbon is plotted versus
 time in Figure A-23-7.     The results show no noticeable
 increase in the ash content of the carbon over the exposure
 time of 120 hours.  The evaluation of the S02 activity of
 the initial and fly ash treated carbon is shown in Table
 A-23-5.
    Table A-23-5.  EFFECT OF FLY ASH EXPOSURE ON S02
                   SORPTION BY ACTIVATED CARBON
Sample
Virgin Carbon
Virgin Carbon after 120
Hrs . Fly Ash Exposure
S02 Activity*,
Ib. S02/lb. C-min.
0.83x10-3
0. 78xlO"3
 .There is very little difference between the activity of the
 virgin and fly ash exposed carbon;  and for practical
 purposes, within the experimental error of these tests, the
 activities are the same.

 Although long term exposure to flue gas under actual condi-
 tions is necessary to assure that there are no effects 
-------
              Figure A-23-7.   Effect of fly ash exposure on  activated carbon  ash content
CO
      M




      +»
o

t
«t»
o
         4
      J=
                                                                       Run No.  FAET-1
                                                -I-
                 10      20     30      40     50      60      70



                                                  Exposure, hours
                                                                80
90
TOO
                                                                                       no
120
-------
            APPENDIX



           SECTION B



DETAILED PILOT PLANT INFORMATION
              664
-------
                           APPENDIX B-l


                       ANALYTICAL TECHNIQUES
 INTRODUCTION
 The  various  analytical  test  procedures  which were  used to
 evaluate  carbon  samples are  described in  this section  of the
 Appendix.  Many  of  the  analyses  were  used for characterizing  a
 carbon  sample  in terms  of  various  properties which are import-
 ant  to  the economic utility  of the carbon in the fluidized  bed
 S02  removal  process.  Included in  this  group of tests  are
 apparent  density, particle size  distribution,  attrition rate,
 S02  activity,  and pore  size  distribution.   Other analyses such
 as total  sulfur  content, moisture,  and  acid titration  were  used
 primarily to calculate  process performance parameters.   A list
 of the  various tests which are described  in this Appendix is
 given below:
                                                           Page

 1.  Apparent Density                                       666

 2.  Particle Size Distribution                             670

 3.  Attrition Rate                                         672

 4.  S02 Activity                                           675

 5.  Pore Size Distribution and Surface Area                676

 6.  Total Ash Content                                      679

 7.  Total Sulfur Content                                   680

 8.  Moisture Content                                       682

 9.  Acid Titration                                         683

10.  Gas Phase Sulfur Vapor Concentration                   684

11.  S02 Activity                                           686
                             665
-------
APPARENT DENSITY

Scope

This method covers a procedure for determining the apparent
density of granular activated carbon.   For purposes of «^s
test, granular activated carbon is defined as a minimum of 90/0
being larger than 80 mesh.

Apparatus

1.  Vibrator Feeder - See Figures    B-l-1, -2, and -3.
2.  Cylinder, Graduated, Capacity 100 ml.
3.  Balance having a sensitivy of 0.1 g-

Procedure

1   An adequate sample of the carbon to be tested should be
    dried to constant weight at 150±59°C  (for 1 hour).

2.  A representative sample of this dried activated carbon is
    carefully placed into the reservoir funnel so that the
    material does not prematurely flow into the graduated
    cylinder.  If this occurs, return the material to  the
    reservoir funnel.

3.  The sample is added to the cylinder by the vibrator feeder,
    through the feed funnel having a 15/16 inch inside diameter
    stem.

4.  Fill the cylinder, at a uniform rate  not  less than 0.75  or
    to exceed 1.0 milliliter per  second,  up to the 100 ml. mark
    The rate can be adjusted by changing  the  slope of the metal
    vibrator and/or raising or lowering  the reservoir funnel.

5.  Transfer the contents to a balance pan and weigh  to the
    nearest tenth of a gram  (0.1  g.).

Calculations

Calculate the apparent density as follows:

                        ,        Weight  of Activated  Carbon
   Apparent Density, g./cc.  =  	D	
                                666
-------
FIGURE B-l-1.  Apparent density vibrator feeder
                                        •Reservoir Funnel
                                         Clamped to ring stand.
                                         Ring  stand.
                                        •• Metal vibrator-
                                         Door bell  "buzzer
                                        "" peed Funnel clamped
                                         to ring  stand
                                         100-ml.  ASTM graduated
                                         cylinder
                                     	Switch
                                                • Transformer
                                              No Scale
                        667
-------
              Figure B-l-2.  Metal  vibrator
Actual Size
                           668
-------
                                              Figure  B-l-3
              Reservoir Funnel
Feed- Funnel
             [-<	1-5/8"-
Conditions:  - Glass or Metal - Actual Size
-------
 PARTICLE  SIZE DISTRIBUTION

 The  distribution of particle sizes in a given sample  is
 obtained  by mechanically shaking a weighed amount of  material
 through a series of test sieves, and determining the  quantity
 retained  by or passing given sieves.

 Procedure

 1.   Reduce the sample to be tested to 100 grams by means of  a
     riffle.*

 2.   Assemble the nest of five selected sieves in order of
     decreasing size of opening, the sieve having the  largest
     openings mounted on top.  A receiving pan is placed at the
     bottom under the finest sieve.

 3.   Place the 100.0-gram sample in the top sieve, install iron
     cover on top of the assembly and shake on the Ro-Tap
     Machine for 3 minutes with the tapper in operation.**
 4.   Weigh  and  report  the per cent of material retained on each
     sieve.****
     *The sample  is  carefully reduced by repeated passes
 through the  riffle until  the amount  collected  in one  of the
 riffle pans  is  close to 100 grams.   The entire  contents of
 that pan are then emptied onto a balance accurate to  0.1  gram
 and weighed.  No  more  than 5 grams should be added  to or  taken
 from the balance  without  additional  riffling.   For  example,
 if the entire contents from the riffle pan weighed  only 90
 grams,  the additional  10  grams should be obtained by  riffling
 another sample  down  to an approximate 10-gram  portion, after
 which  the entire  contents of that riffle pan are emptied  onto
 the balance.  Removing large quantities from the balance  or
 adding large quantities from the sample stock  without riffling
 will lead to erroneous results.

        When  sieving  samples which are finer than 100  mesh  the
 shaking time must be increased.  Use 10 minute intervals  until
 less than 2  grams are  collected in the receiving pan  in a 10-
 minute  interval.  For  very light density and unusual  shape
 particles, time should be extended to 10 minutes.

    ***rhe sieve  should be lightly brushed with a brass wire
 bristle  brush to  free  particles held in the screen.

    ****The analysis should be rejected if the  sum of the
individual fractions is less than 98 grams or more than 102  grams
                              670
-------
Equipment
1.  Riffle, Jones Sampler - Fisher Scientific Catalog No. 4-941
2.  Sieves - U.S. Standard Sieve Series, 8" Diameter, Full-
    Height Sieves
3.  Ro-Tap - Sieve Shaker, Fisher Scientific Catalog No. 4-906
4.  Brush - For Metal Surfaces, Brass Wire Bristle - Fisher
    Scientific Catalog No. 3-685
                             671
-------
 ATTRITION RATE

 Carbon attrition rate was measured under a specific set of
 conditions in the apparatus shown in the schematic drawing.
 The basic method was to fluidize a 400 gram carbon sample at
 4 ft./sec. linear velocity, and to measure the elutriation
 losses from the sample at 10 minute intervals.   An average
 steady state rate of attrition was obtained from this data.
 The experimental procedure was as follows.

 Procedure

 1.  Prior to the attrition study, analyze feed material for
     moisture content, apparent density, and particle size
     distribution.

 2.  Run a minimum fluidization test on feed sample prior to
     the attrition study unless the fluidization test has been
     run on a sample of the same material.

 3.  Load a 400 gram sample of the carbon to be tested through
     the side port of the attrition column.

 4.  Fluidize the bed and quickly shut gas flow off and allow
     the bed to settle.  Record bed height.

 5-  Start gas flow and timer simultaneously.  Set large
     rotameter at 7070 (superficial velocity, 4 ft./sec.). Make
     sure small rotameter is off.

 6.  Determine elutriation losses every 10 minutes.  Record.
     Save material from the first and last 30 minutes of the
     run.

 7.  Record the elapsed time, rotameter reading, rotameter exit
     pressure, column pressure, bed pressure drop, plate
     pressure drop, and the bed depth every 10 minutes.

 8.  Run for a minimum time of 2 hours and a maximum time of
     3.5 hours.  After 1.5 hours, if ,3 successive dust loadings
     are within 0.05 gram of one another, terminate the run.

 9.  Weigh final bed and record.

*10.  Run particle size distributions on the dust samples
     collected during the run.  Use 80, 100, 150, 200, and 325
     mesh sieves if there is sufficient material, otherwise
     use small sieves--100, 200, and 325.
      *0ptional analysis.


                              672
-------
*11. Run a particle size distribution, apparent density, and
     moisture content on the final bed.  Use appropriate sieves

 12. Calculate bed expansion and attrition rate.
      ^Optional analysis.


                              673
-------
Figure B-l-4.   Schematic diagram of  apparatus used
                 in  room  temperature fluidization
                 experiments
    3Q"
           4" P
        Plexiglass-
          Column
          Distributor Plate
  Air  )	r-,	
Supply /   V/
             Rotorcetcr
                                   I
                             El
Scale
                                   Across
                                  Plate
                                             Cyclone
                                            Dust Hopper
                                                          Column Pressure
                                                         .'.P Across
                                                           Bed
                                         •—--     ^^—-
                                         A  /
                                         Manometers
                           674
-------
SO2 ACTIVITY

The analytical procedure for the S02 activity determination is
basically the same as the procedure used in the S02 sorption
differential rate studies, which is described in detail in
Section 5.1.1.  The 862 activity analysis simply represents a
special case where a specific set of conditions was used.
Basically, the method involved a determination of the 5 hour
average rate of S02 adsorption on a carbon sample in a differ-
ential reactor apparatus, under the following standard set of
conditions:
           Sample Size:           0.1 gm

           Gas Flow Rate:         1,000 cc/min.

           Temperature:           200°F
           Gas Composition, S02:   2,000 PPM
                            NO:   150 PPM
                            H20:   10%
                            02:   2%
                            C02:   11.3%
                            N2:   Balance
           Adsorption Time:       5 Hours
                          675
-------
PORE SIZE DISTRIBUTION AND SURFACE AREA

Measurement of the pore size distribution and surface area of
carbon samples was made using two instruments :   1) Aminco
porosimeter and 2) Engelhard Industries isorpta analyzer,
Model 2A.  The Aminco porosimeter was used in determining
pore volumes in the 100 to 0.012 micron diameter range,
while the Isorpta analyzer was used for smaller pores in the
10-1,000 Angstrom range, and for surface  area determinations.

Porosimeter

The Aminco porosimeter measures pore sizes from 100 microns
to 0.012 microns diameter  and pore volumes as small as 0.0001
ml.  Readout is digital and automatic above atmospheric
pressure and visual below  atmospheric pressure.

Pressure is generated by a motor-driven hydraulic pump.  This
pump operates a reciprocating, double-ended pressure intensi-
fier generating pressures  up to 15,000 psi in the pressure
vessel.

A vacuum system is provided (less pump) for measurements below
atmospheric pressure.

     Procedure

1.  A sample of appropriate size and porosity is placed in a
    penetrometer  (glass tube with graduated capillary stem) .
    The penetrometer, in turn, is placed in a filling device.
    A vacuum pump, available as an accessory, evacuates the
    filling device and permits the penetrometer to be filled
    with mercury.  Pore sizes from 100 to 16 microns are
    determined with the penetrometer in this position.

2.  The penetrometer is then transferred to the pressure
    chamber, where pressures from 0 to 15,000 psi can be
    applied to the mercury and where pore sizes down to 0.012
    microns can be measured.  As pressure is increased mercury
    is forced into smaller and smaller pores, the volumes of
    which are continuously being indicated by the digital
    readout as the mercury is displaced in the stem of the
    penetrometer.  The smallest pore diameter entered by the
    mercury under pressure is stated in the relationship:
         where  D = the diameter of the pore in microns
                      (1 micron = 10~4 Cm. or 3.94xlO~5  in.)
                P - absolute pressure in pounds per  square
                      inch .
                           676
-------
    Pore diameters are determined from the absolute pressure
    on the sample.  For example, if the pressure P at the
    sample is 1750 psi, by substitution in the formula D
    equals 0.1 micron.  Generally the head pressure of mercury
    must be included in calculating absolute pressure when
    the diameters of large pores are being measured.

3.  Pore volumes are read directly from digital readout in
    tenths of a microliter.  The Porosimeter indicates only
    those pores which open to the outside surface of the sample
    and which the mercury is able to enter.  If large openings
    within the sample are connected to the surface by narrow
    pores, their volumes will be indicated at the diameter of
    the narrow pore.

Isorpta Analyzer

The Englehard Industries isorpta analyzer permits low tempera-
ture nitrogen adsorption measurements to be made in a continu-
ous flow system, at predetermined and/or uniformly spaced
relative nitrogen pressure values.  Using the adsorption data
obtained from the Isorpta, the BET surface area and pore
volume distribution of the carbon sample are determined by
Roberts' Method   .    The calculations are made by a computer
program.  Two options are available in the choice of pore
models — the cylindrical pore and the parallel plate.  The
computer program is given in Appendix  A-22.

     Theory of Operation

In principle, the Isorpta is designed to permit variation of
the total pressure of a fixed adsorbate-diluent mixture in
contact with the sample so the adsorbate relative pressure
can be adjusted.

In practice, a dilute mixture of nitrogen in helium is used.
As an example of how the nitrogen relative pressure over the
sample is determined, the nitrogen partial pressure in a 10%
nitrogen in helium mixture at a total pressure of 8 atmo-
spheres is 0.8 atmospheres, equivalent to a relative pressure
of about 0.8, depending on the vapor pressure of the liquid
nitrogen used to cool the sample.  Consequently, to determine
the adsorption at relative pressure 0.8, the pressure in the
sample tube is adjusted to about 8 atmospheres.  When adsorp-
tion is complete, the adsorption at relative pressure 0.3 may
be determined by adjusting the pressure in the sample tube to
3 atmospheres.
                             677
-------
To develop a complete isotherm, pressure in the sample tube is
first set to some low value and adsorption measured.  The
pressure is increased in a stepwise manner allowing adsorption
equilibration at each step.  The size of the step is left to
the discretion of the operator.  If it is desirable, adsorp-
tion at a relative pressure over 0.9 can be determined in the
first adsorption measurement.  However, it is customary to
develop the lower portion of the isotherm below relative pres-
sure 0.6 before approach saturation.  When the sample is
saturated, pressure can be decreased in the same manner to
determine points on the desorption branch of the isotherm.

While pressure in the sample tube is varied, pressure in the
balance of the system is automatically controlled at some low
value near atmospheric pressure, particularly in the thermal
conductivity cell section.  Gas composition changes measured
by the thermal conductivity cell are well within the linear
range of cell response, so no corrections are needed.

With the nitrogen-helium mixture over the sample, the sample
is cooled to liquid nitrogen temperature causing adsorption,
which is indicated by a deficiency of nitrogen measured by the
thermal conductivity cell and correspondingly traced as a peak
on a recorder.  When, at a given relative pressure, adsorption
equilibrium is established, the peak area can be measured and
converted to the volume of gas adsorbed per unit weight of
sample.   Total adsorption at a subsequent point is equivalent
to the algebraci sum of the peaks as defined by increasing or
decreasing pressure.

The range of relative pressures that can be investigated is
limited only by the gas composition and the saturation point.
Further,  other adsorbates besides nitrogen can be used in
mixture with other diluents.
                             678
-------
TOTAL ASH CONTENT

Ash is defined as the mineral oxide constituents of the carbon
Heating a sample to a temperature of 600°C in an oxidizing
atmosphere will completely oxidize all carbon and convert the
mineral constituents to their respective oxides.

Procedure

1.  Weigh 1.00 gram of the sample into a weighed Vycor glass
    crucible without cover.*

2.  Place crucible.and contents into a muffle furnace; set at
    600°C for at least 4 hours.  (For high volatile materials
    such as coal or pitch, devolatilize first over flame
    burner before placing in furnace.)**

3.  Remove from furnace, cool in dessicator and weigh.  (Save
    crucible and ash for iron analysis, if desired.)

4.  Per cent ash is calculated'as follows:
     7 Ash = 100 x rFinal Wt- of Crucible -Prig. Wt. of Empty Crucible
      0                            Wt. of Dry Sample
      *Although Vycor glass crucibles  (30-ml. capacity) are
indicated in this test, platinum or porcelain crucibles may
also be used.

     **For black ash samples use a minimum of 16 hours.
                              679
-------
TOTAL SULFUR CONTENT OF CARBON

Description

Weighed amount of sample is heated to 2600°F and exposed to
flow of oxygen.  Sample is combusted to C02, HaO and SOg gas
which is all passed through hydrogen peroxide solution in which
S02 reacts to form sulfuric acid.   Amount of H2S04 is determined
by titrating with caustic solution.

Materials

1.  Dietert Combustion Analyzer (heated to 2600°F)
2.  Dietert Combustion Boats
3.  0.06 N NaOH Solution
4.  0.9% H202 Solution
5.  Methyl Red Indicator Solution
6.  Cylinder Oxygen

Procedure

1.  Prepare 0.06N NaOH as follows:
    a.  Accurately pipette 60.0 ml. 1.0 N NaOH into a 1,000 ml.
        volumetric flask and bring to volume with distilled
        H20.
    b.  Pour into reagent jar at analyzer marked NaOH.

2.  Prepare 0.9% H202 as follows:
    a.  Bring 30 ml. of 30% H202 solution to volume in a 1,000
        ml. graduated cylinder with distilled H20.
    b.  Pour into reagent jar at analyzer marked H202.

    NOTE:  THIS SOLUTION MUST BE MADE FRESH EVERYDAY.

3.  Prepare a standard for analysis as follows:
    a.  Weigh 0.0250 gms. of sulfur and evenly distribute in
        the bottom of a combustion boat.
    b.  Weigh 0.2500 gms. of virgin carbon, and distribute
        evenly over the sulfur in the combustion boat.

4.  Analysis of Standard
    a.  Combustion analyzer temperature should be 2600°F, ±100°F.
    b.  Fill the reaction vessel to the first hash mark  (50 ml >'
        with the H202 solution; add 1 drop of NaOH from  the
        burette and 2 drops of methyl red indicator.
    c.  Place the combustion boat containing the sample  into
        the combustion tube.  Insert ramrod assembly until the
        rubber stopper fits snugly and turn on the 02 to a
        flow rate of ^ 1.5 l./m.  DO NOT SHOVE THE BOAT  INTO TUBE
    d.   Place the gas dispersion tuFe coming from the analyzer
        into the H202 solution.
                             680
-------
    e.   Shove the boat 1/2 way into the combustion tube using
        the ramrod.  Wait ~-»15 seconds and then shove the boat
        fully into the hot zone of the tube and withdraw the
        ramrod.

        NOTE:  IF THE BOAT WERE SHOVED IMMEDIATELY INTO THE
               HOT ZONE, THE TUBE MAY CRACK, NECESSITATING
               REPLACEMENT.

    f.   Titrate the solution until there is no longer a yellow
        to pink color change, indicating the end point has been
        reached and all of the sulfur has been oxidized.
    g.   Record the total volume of NaOH used.
    h.   Drain the reaction vessel and rinse with distilled H20.
        Turn off the 02, remove ramrod assembly from the tube,
        and remove the boat from the tube, utilizing the sample
        retreiver.  Place the hot boat in the stainless steel
        receptacle under the table.
    i.   The total volume of NaOH used for the titration should
        be 26.2*1.2 ml.  If there is a deviation from this,
        check the following:
        1)  Normality of NaOH solution
        2)  Weight of sulfur used in the standard
        3)  For a cracked combustion tube
        4)  Any other gas leaks in the system.
        5)  DO NOT PROCEED until the situation is remedied.

5.   Analysis of Carbon Sample
    a.   Weigh 0.2500 gins. of sample and place in a combustion
        boat.
    b.   Analyze the same as for a standard sample, Steps 4a-4h.

6.   Calculation of Sulfur Content, in %
    a.   Multiply the total volume of NaOH used by 0.4.

                (ml. 0.06 N NaOH Used  x  0.4)
                             681
-------
MOISTURE  CONTENT*

Procedure

Weigh  carefully  about 5.0 grams of carbon into a tared low form
weighing  bottle.  Place in an oven and allow to dry 3 hours at
110°C  or  1 hour  at  140°C.  Cool in a desiccator and weigh with
cover  on.**


   % Moist   =  (Wt.  of Dish & Sample) - (.Wt. of Dish & Dried Sample) x  1QO
      *This test is intended only for determining the moisture
content of a sample of carbon.  If a larger sample is to be
dried,  a longer time will be required depending on the  size  of
sample and type of container.

     **For a coal sample use a vacuum oven at 100°C for 3  hours
                               682
-------
DIRECT TITRATION OF H2S04 CONTENT OF CARBON

Description

The amount of sorbed acid is determined by direct acid-base
titration using caustic.  A weighed amount of sample is boiled
in water and the amount of acid leached off is determined by
direct titration.

Materials

1.  Hot Plate
2.  Magnetic Stirrer
3.  50 ml. Burette
4.  250 ml. Beaker
5.  0.1 N NaOH and 0.03N NaOH
6.  Watch Glass
7.  Methyl Red Indicator

Procedure

1.  Prepare 0.1 N NaOH and 0.03 N NaOH as follows:
    a.  Accurately pipette 100.0 ml. of 1.0 N NaOH into a 1,000
        ml. volumetric flask and bring to volume with distilled
        H£0.  Use 30 ml. for 0.03 N NaOH.
    b.  Rinse burette with this solution, empty, and refill to
        0 ml. mark.

2.  Analysis of Sample
    a.  Weigh 1.0000 gms.  of sample to be analyzed and transfer
        to a 250 ml. beaker containing 50 ml. of distilled
        H20.
    b.  Cover beaker with a watch glass and bring to a slow boil
        on the hot plate.   Boil for 5 minutes.
        1)  After sample has boiled for 5 minutes, remove from
            hot plate, place on magnetic stirrer and add 7-15
            drops of methyl red solution.
        2)  Titrate to end point with 0.1 N NaOH.
    c.  Repeat this procedure for two more boiling-titration
        series.
    d.  Record total volume of NaOH used.

3.  Calculation of H2S04 Content

       % H2S04  =  (ml. 0.1 N NaOH)(0.49)
       % H2S04  =  (ml. 0.03 N NaOH)(0.147)
                                683
-------
DETERMINATION OF SULFUR CONTENT IN GAS PHASE

A method was set up to measure the sulfur content in the gas
phase for operation of the sulfur recovery step during periods
other than during integral operation or before the sulfur
condenser was installed.

A sulfur trap similar to those for the gas chromatograph was
utilized for this purpose.  The complete system (Figure
   B-l-5) consists of the trap, a H2S adsorber, a sample pump
and a wet test meter.  The pump continuously pulls a sample of
vapor through the trap where sulfur condenses and through a
bubbler system containing NaOH which reacts with H£S to form
Na£S and H20, thus preventing carry-over of H2S into the sample
pump and wet test meter.  The latter records the total volume
of nitrogen and hydrogen passing through the system.  Sulfur
is extracted from the condenser by carbon disulfide and
recovered.   Comparison of the gas volume corrected for H2S
measured by the gas chromatograph) and the weighed sulfur
yields the sulfur vapor concentration.
                               684
-------
                                               Figure B-l-5.    Sulfur  sampling system
oo
Ul
                                         Glass
                                         Wool
A      A
                                                            tiaOH
                                                                       D
                                                              Mash Bottles
                                    Stainless Steel
                                      Sulfur Trap
                                     1" HPS x ~2'
                         • o
                          /
                                t '
                                 r
                                 a
                                 c
                                                                                                                     -1-1.5
                                                                                                                       CFK
                                                                                                      Positive
                                                                                                     Displacement
                                                                                                     Sample Pump
                                                                                  Liquid Trap
                                                                                                       Wet Test
                                                                                                        Meter
-------
S02  ACTIVITY ANALYTICAL PROCEDURE

Procedure

      Sample Preparation


1.  Remove oven from around  the sample  envelope.  This part of the opera-
    tion involves two people, one  to hold the top half of the oven while
    the other removes the bottom half.

       CAUTION:  WHEN LOWERING THE LAB  JACK TO ALLOW THE OVEN TO BE
                 REMOVED, DO NOT LOWER  BELOW THE LEVEL OF THE STOP-
                 COCK ON THE ADJACENT McLEON GAUGE.

    Move the lab  jack from under the sample enveloper.

2.  Remove the sample envelope.  Before the sample envelope can be
    removed  the preheat coil of 1/16" stainless steel tubing must be
    removed  and the  Swagelok unions disconnected.

    a.   Remove heating tape  from around the Swagelok union on the inlet
        manifold  and open union with the two wrenches (9/16" and 1/2").
        With the  two 7/16" wrenches open the union leading into the
        nozzle (see  Item K in Figure    B-l-6) .  Remove the preheat
        coil.   Next, open the Swagelok union leading from the purge
        rotameter and unplug the thermocouple.

    b.   Very carefully loosen the  ball  joint clamp (Item B in Fig.    B-l-6)
        but  do not remove the clamp.  This will enable the dispersion
        nozzle to be carefully rotated  out of the bucket and to the
        side of the  bucket.  When  the nozzle is positioned so that the
        bucket will  pass freely by it when the envelope is lowered,
        retighten the clamp.

       CAUTION:   THE QUARTZ  BUCKET IS VERY FRAGILE AND SHOULD NOT
                 BE  SUBJECTED TO ANY BUMPS OF THE NOZZLE OR
                 CRUSHED BETWEEN THE NOZZLE AND THE SAMPLE
                 ENVELOPE.

    c.   With the  nozzle out  of the bucket it is now possible to remove
        the  sample envelope.  While holding the envelope in place with
        one  hand,  loosen the larger ball joint clamp  (Item A in Fig.   B-l-6)
        with the  other hand  and remove.  Use the second hand to hold  the
        nozzle away  from the bucket while the envelope is slowly lowered
        away from the  bucket.
                                  686
-------
Figure  B-l-6.   Detail  of sorption apparatus  sample bucket envelope
                                   SJ 35/25 Pyrex Ball Joint
                                   SJ 18/9 Pyrex Ball Joint
                                   Swagelok Fittinqs and Thermocouple
                                   Gas Injection Tube
                                   Purge Gas Line
                                   Sample Bucket
                                   Dispersion Nozzle
                                   Thermocouple
                                   Suspension Fiber
                                   Swagelok Connection to Preheat  Coil
Gland
                                   687
-------
       CAUTION:  WHEN LOWER INC THE ENVELOPE, BRING THE ENVELOP!';
                 STRAIGHT DOWN SO AS NOT TO TOUCH THE BUCKET OR
                 THE FIBER THE BUCKET IS SUSPENDED FROM WITH ANY
                 PART OF THE ENVELOPE.

3.  Replace the sample.  The bucket is lifted off the balance by bringing
    a sample pan under the bucket and slowly raising until the bucket
    lifts off the fiber.  Forceps are used in handling the bucket while
    off the balance.  The forceps are for lifting the bucket by the bail.
    Do not squeeze the forceps on the bail or it will break.  To empty
    the bucket, place the bucket on a clean sheet of paper and using a
    cotton swab turn the bucket over onto its side.  Now, insert the swab
    in the bucket so it can be burned upside down and the carbon poured
    out.  Now, reright the bucket with the forceps and return to the
    sample pan.  On the Mettler balance, weigh out approximately 100 mg of
    new sample into the bucket.  Return the bucket to the sample pan and
    tap the sample pan gently to spread the carbon sample over the bottom
    of the bucket.  Return the bucket to the balance and reverse the
    procedure previously outlined to replace the sample envelope.  When
    replacing the nozzle in the bucket, be sure to center the bucket in
    the envelope and center the nozzle in the bucket.

4.  Replace the oven.  When the sample envelope has been replaced and
    the ball joint clamps tightened, replace the preheat coil and tighten
    the Swagelok unions.  Reconnect the purge line and tighten the Swagelok
    union.  Plug in the thermocouple and rewrap the heating tape around
    the inlet manifold leading to the preheat coil.  Now the oven may be
    replaced.

       CAUTION;  DO NOT BUMP THE SAMPLE ENVELOPE WITH THE OVEN.
                 ALSO BE CAREFUL OF ADJACENT EQUIPMENT.

    When raising the lab jack, raise the oven until it is just under the
    bottom of the sample envelope but not touching it.  Replace the top of
    the oven and carefully fill in the cracks and open space  with glass
    wool for insulation.

5.  Outgas the carbon sample.  Plug in the fan motor on the oven and turn
    on the regulator (Item G on Figure    B-l-7).   Plug in the heating
    tape on the inlet manifold and start a low flow of nitrogen on the
    purge rotameter (stainless steel float should be set at 9.0 cm).  Open
    the inlet manifold to the sample and close the exit by means of the
    two toggle valves (Items L and M on Fig.    B-l-7). Turn on the Cahn
    balance and start a flow of nitrogen to the sample by opening the
    rotameter all the way.   Turn on the recorder at a slow chart speed.
    Turn the recorder range dial on the Cahn balance control box to 10
    and center pen on the chart with the Mass Dial.  For calibration and
    operation of the balance refer to the instruction manual.
    While  the temperature in the oven is equilibrating to 200°F the
    nitrogen will be purging the water off the sample.
                                     688
-------
oo



, 	

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^
1
A - Magnehelic Pressure Gauge      E
B - Humidifier Thermostat    -      F
C - Sample Thermostat           •  G
0 - Bucket Envelope               H
                                           Fiber Envelope
                                           Electrobalance
                                           Oven Temperature Regulator
                                           Vacuum Pump
J - Thermocouple
K - Vent
L - Inlet Toggle Valve
M - Exit Toggle Valve
                                     Figure  B-l-7.   Sorption  rate apparatus
-------
      Sorption Runs

While the sample is being outgassed and the temperature is equilibrating,
the flows for the mixture gas can be calculated.

      Flow Calculation

A sample  work sheet has  been  included  (Fig.    B-l-8)  for  illustration.  The
concentrations  of  S02, NO, 02, and H2<> must be decided first in addition
to the  total flow  rate of the gas and the temperature of  the run-  The
majority  of  the runs have been made with nitrogen as the  diluent gas and
the  total flow  gas should be  1,000 cc/rain. or less.  A higher flow rate
could cause  too much turbulence around the sample and actually blow the
sample  out of the  bucket.

The  S02 and NO  tanks will have been previously calibrated so their tank
concentrations  are known.

Current experiments have involved a 10% concentration of  water.  For this
concentration the  temperature of the humidifier bath has  been maintained
at 60°C.   It is important that the flow of gas through the humidifier
should  not exceed about  450 cc/min.  For higher water concentrations the
humidifier temperature would  have to be raised.  For calculating the gas
flow through the humidifier refer to (^ in the sample calculation.  Pm
Is the  manifold pressure and  is used in correcting the flows for daily
changes in barometric pressure.  Pbar is the barometric pressure and must
be corrected for expansion of the brass scale due to temperature changes
(see the  HANDBOOK OF CHEMISTRY AND PHYSICS, pp. E-21 - E-22 for
corrections).   PR20 is the saturated vapor pressure of the water at the
temperature of  the humidifier bath.  This information can be found in the
HANDBOOK  OF CHEMISTRY AND PHYSICS, pp. E-6 - E-ll.

After the Pm and the flow of  nitrogen through the humidifier (FN2/H20)
have been calculated, PH, the pressure in the humidifier  must be calcu-
lated in  order  to correct the flow on the N2/H20 rotameter, (|) on the
sample  calculation sheet.  This rotameter setting and the subsequent
rotameter settings can be found in a notebook labeled "Rotameter
Calibrations".

In (3)   the concentrations of  the other gases are calculated and the
rotameter settings corrected.  And finally in  (§), the amount of dry
nitrogen required to bring the total flow up to the amount desired is
determined by subtracting the sum of all other gases from the total flow
and correcting  for the rotameter setting.  The nitrogen,  S02, and NO
rotameters have dual floats for a wider range of flows and it is better
to use  the float that is closer to the midrange of the rotameter rather
than the one closer to one end or the other of the scale.  On the sample
calculation sheet,  the (S)  or (G) after a rotameter setting indicates
a  stainless steel float   (silver)  or a glass float (black).
                                      690
-------
                  Figure B-l-8.    Sample  calculations.
HUH	

DATK	

CARBON
TEMI'KKATURK
       FOU KIIN
                                                             Work
   '   /f)00
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                                                                          )(?., ^  HjO
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              * l'«2/H20
       P»ct
       FS02
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              Pn/760
                                                 a of.
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                                        J
                                                                               £7,7  N.
                                                                       Hoi..
                                      691
-------
      Starting  the Run

Alter the sample has reached the experimental temperature and the flows
have been calculated, the run can be started.

1.  Determining Dry Sample Weight:  Bypass the nitrogen flow to the
    sample by opening the vent toggle valve (Item M in Figure    B-l-7)and
    closing the sample inlet valve (Item L in Fig.    B-l-7). Turn off the
    purge rotameter.  Zero the recorder with the Mass Dial and record
    the Mass Dial reading as four digits after the decimal (e.g.,
    0.5328).  The weight of the sample will correspond to the Mass Dial
    reading times the Mass Dial Range (far left knob).  For example, if
    the Mass Dial Range is set at 200 and the Mass Dial reads 0.5328,
    the sample weight is 200 x 0.5328 or 106.56 mg.  After determining
    the dry sample weight, turn the purge rotameter back on to 9.0 cm
    to keep air out of the sample envelope.

2.  With the sample still bypassed (toggle valve M open, L closed),
    start mixing the gases.  The rotameter for the Q£ is highly stable
    but difficult to set and for this reason a toggle valve at the tank
    is used to control the flow of 02 to the system.  Little if any
    adjustment will need to be done to this rotameter.  The C02 rotameter
    is at the tank and has only the single float.  After the 02 toggle
    valve is opened, the C02 rotameter set, and the NO, S02, and N2
    rotameters set, open the line from the humidifier and set the N2/H20
    rotameter.  To open the humidifier line, close the Vent toggle valve
    and open the Run toggle valve.  After the water is added the flows
    will probably all need to be readjusted.  Allow the flows to equili-
    brate for 4-5 minutes before starting the run.  Meanwhile, set the
    timer to 00000.0, put the chart speed on 1 inch per minute (the
    recorder has the D gear set in place) and line up the recorder on a
    heavy line and turn to standby.  With the recorder turned to standby,
    set the Mass Dial approximately 6 mg heavier (e.g., if the dry weight
    is 0.5328 set the Mass Dial at 0.5600) and record this Mass Dial
    reading on the chart at time zero.  Plug in the vacuum pump and the
    run is ready to be started.

3.  Starting the run will involve a second person to open and close the
    toggle valves L and M, respectively.  In general, the practice has
    been to start a run when the second hand on the wall clock hits 12.
    Fifteen seconds before starting, the vacuum pump rotameter is set
    at 15.0 cm.   When the second hand hits 12, one person opens toggle
    valve L and  closes  toggle valve M and the other person starts the
    timer and turns the recorder from standby to on.  The recorder pen
    will immediately jump up scale which is the result of the sudden
    force of the mixture gas on the bucket.  If, however, the pen does
    not remain on scale, turn the Mass Dial to a higher number (perhaps
    0.5800)  and  record  this new Mass Dial reading on the chart.  At the
    end of the first twelve minutes, turn the chart speed down to 10
    inches per hour.  This is accomplished most efficiently if the
    in./min.  to  in./hr.  inner switch is changed first and the outer
    switch is changed from 1 to 10 (on the D gear set).  For more

                                     692
-------
     complete instructions on operating the recorder, including refill-
     ing the chart or pen, refer to the instruction manual.
     At this point, the run needs only to be periodically monitored,
     that is, if the pen goes off scale reset the Mass Dial so the
     recorder pen is close to zero, and record the new Mass Dial reading
     on the chart and also check the rotameter settings frequently and
     readjust if necessary.  For convenience in later calculations, the
     Mass Dial should be set at a round number except when determining
     dry weight and final weights (e.g., set the Mass Dial at 0.6400
     rather than 0.6387).

      Ending  the Run

When the run has been completed (usually 300 minutes), close valve L
and open valve M.  Turn off the purge rotameter and the vacuum pump
rotameter and re-zero the recorder with the Mass Dial as quickly as
possible.  Record this weight on the chart and turn the vacuum pump
rotameter back to 15.0 cm.  Turn off the timer switch.  Reduce the chart
speed and turn the purge rotameter back to 9.0 cm.  With the mixture gas
bypassed from the sample, turn off the C02, S02, NO and N2/H20 rotameters.
Turn off the 02 toggle valve and loosen the Swagelok connection just
below the toggle valve to vent the 02 line.  Retighten this Swagelok
connection when the 02 rotameter reads 0 and turn off the humidifier line
by opening the Vent valve and closing the Run valve.  Open the nitrogen
rotameter completely and reopen toggle valve L and close valve M.  This
will purge the water off the sample that is dissolved in the acid on the
carbon.  When the recorder trace has leveled off indicating a constant
weight, turn off the purge rotameter and the vacuum pump rotameter and
open valve M and close valve L.  Turn off the nitrogen rotameter and
rezero the recorder with the Mass Dial and record the dry weight.  Turn
the recorder to standby, the recorder range switch on the balance control
box to Z, the Cahn balance to off, and the oven temperature regulator off.
Unplug the vacuum pump and unplug the fan motor to the oven.  Unplug
the heating tape on the inlet manifold and on Friday evening turn the
humidifier temperature bath off.  (Be sure to turn this on again first
thing Monday morning).  Turning off the humidifier bath over the weekend
slows down the evaporation of water from the humidifier and requires less
frequent filling of the humidifier bubblers.
                                      693
-------
Calculations at End of  Run

At the end of  the run the total amount of sulfuric acid is measured on a
dry basis.  The  information is used in calculating an integral rate of
reaction.   The sample calculation and typical strip chart from a run is
given below.

      Integral Rate Calculations

Sample Calculation Run No. 301
                Rat. - (                            »• * C, , ,„„,
     1   Starting Dry Wt. of C - Dry Wt.  (Mass Dial Reading) x 200  (Dial Range)

                              - .5327  x  200 - 106.54 mg.



     2   Final Dry Wt. - Dry Wt. x 200

                      - .6294 x 200 -  125.88 mg.


                   Integral Rate  -  (125.88 - 106.54) t 30Q
                                          106 . 54

                                  -  .0006051


                                    or


                                     .6051 x 10~3
                                    694
-------
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                         APPENDIX B-2

                INTEGRAL PILOT PLANT OPERATION
Introduction
The initial integral run, representing the first operation of
the pilot plant after mechanical integration of the equipment
was completed, is described in this section of the Appendix.
Preparatory work such as drawing up procedures for start-up,
shutdown, and data acquisition is presented, as well as the
initial process performance goals.  Run conditions are given,
and the results of the run are discussed, including material
balances.  To summarize the run results, process performance
goals generally were met or exceeded, and the equipment
operated for about 28 hours, which was equivalent to two full
carbon cycles, or inventory turnovers.

Run Preparation

Preparation was made for an extended integrated run.  This
preparation included, besides that of mechanical and instrumen-
tation, that of setting of run conditions, of start-up and
shutdown procedures, and of data acquisition and preliminary
trend analysis.  The run  conditions are basically those as
given in Table B-2-1.  In line with those conditions, target
goals were set as follows:
     1)  S02 Removal          - 90%
     2)  H2S Utilization      - 95%
     3)  Acid Conversion to S - 99%
     4)  H2 Utilization       - 90%
     5)  Sulfur Recovery      - 25% of Stripper/H2S Gen. Feed

The start-up and shutdown procedures were written to incorporate
the modified operating procedures caused by integration of all
of the pilot equipment. The major differences from past proce-
dures relate to carbon recirculation control from one unit to
the next.  As mentioned in the mechanical section, all of the
carbon flow loop has been checked out satisfactorily.  The
operating procedures were, therefore, developed from the tests.

The data acquisition covers what variables to be monitored and
recorded and at what frequency.  Also, log sheets were prepared
for the variable responses to be recorded.  There were seven
log sheets prepared which included three for gas analyses, one
for carbon analyses, one for carbon material balances, one for
                            697
-------
                      Table B-2-1.   RUN CONDITIONS
RKCYCLt: CAHKON RATE:
                         30 Lbs./Hr.
S02 .SOiUlKR

     Inlet Flue G;is Race:

     Inlet Adsorber Gas Comp.
     Reactor Temperature:
                                   22,650 ACFH @  300°F

                                   S02 - 1600
                                   S03 -   40
                                   NO  -  150 ppm
                                   02  -  3.47.
                                   1120 -  137.
                                   C02 -  117.
                                   ho  - 72.47.
                                                         Nominal stack  concli iion;3;
                                                         no adjustments will  be
                                                         made except  inlet S(>2
                                                         to maintain  1600 ppm.
                                   Stage 1     - 300°F
                                   Stage 2     - 160°F  (Water  Spray Stage)
                                   Stages 3 - 5 - 170-180°F  (No Control - Seek Own Level)
     InlcC N2 Rale:

     Inlet 112S Rate:
                             175.6 CFH @ 70°F

                             71.6 CFH @ 70°F
     Inlet Gas Composition:   l^S  -  28.17.
                             N2   -  71.97.

     Reactor Tempcrnture:     275°F (Average)
                             255-285°F (Range Reactor Bottom to Top)
SULFUR STR1PPER/I12S GENERATOR

     Inlet Gas Rate:


     Inlet Gas Rate:
                             H2 - 75. A CFH @ 70°F
                             N2 - 175.6 CPU 0 70°F

                             H2 - 30Z
                             N2 - 707.
     Reactor Temperature:     1200°F (Average Gas)
                             1000-1250°F (Range in Gas)
     Carbon Flow Split:
                             157. to Top Stage  (4.5 Lbs./Hr.)
                             857. to Stage 4  (26.5 Lbs./Hr.)
CARBON' CONDITIONER

     Inlet Gas Rate:


     Gas Composition:


     Temperature:
                             Air   - 430 CFH @ 70°F
                             Steam - 802 CFH @ 70°F

                             Air   - 357, (Volume)
                             Steam - 657. (Volume)

                             300°F
CARBON 1'RKIir.ATF.R 'll'.Ml'ERAT
                                 600°F
                                      698
-------
gas flow rates and pressure drops and temperature, and one for
critical process response variables.  One gas analysis log
sheet is for routine determination every 4 hours of the flue
gas concentrations of S02, 02, and H20 at the inlet and outlet
of the S02 sorber.  The other two gas analysis log sheets are
for routine determination of the gas concentrations of H20, C02,
H2S, H2, N2, CO and S02 at the inlet and outlet of the sulfur
generator and H2S generator/sulfur stripper every 4 hours.
The carbon analysis log sheet is for the routine determination
every 4 hours of the total sulfur, acid and moisture content
of carbon samples from the S02 sorber, carbon preconditioner,
sulfur generator, and H2S generator/sulfur stripper.  The same
analyses would be made for the intermediate stages but on a
less frequent basis of every one to two days.  The carbon
material balance log sheet is for routine tabulation of carbon
added or removed from the integral pilot plant as dust or
granular carbon.  The carbon samples are taken on an 8 hour
or daily basis and the dust collection is on a similar sheet
for recording these variables every 8 hours for all of the
units.

The primary log sheet is for the critical process variables.
To run the pilot plant on an extended run basis following all
of the variables constantly would require a sizeable effort
in itself.  For this reason 32 process variables were picked
as-primary indicators of the smooth operation of the integral
pilot plant.  This does not mean the other variables are
ignored, but rather are recorded on a less frequent basis.
This log sheet is shown in Figure    B-2-1 because of the
importance in pilot plant control and operation.  These 32
points are indicated in Dwg. No. 2528A in Appendix B-3 and
include 10 temperatures, 8 pressures or pressure drops, 7 gas
flow rates, 5 indications of carbon flow, and 2 indicators of
stable sulfur condenser operation.

To allow preliminary trend analysis during the run, prepara-
tion was made to calculate and plot several responses during
the course of the run.  At the end of the run a more detailed
data analysis would be made.  The responses which are calcu-
lated several times each day are S02 removal efficiency, H2S
utilization efficiency, H2 utilization and conversion to H2S
efficiency, sulfuric acid conversion to H2S, and carbon attri-
tion rate.  A running plot will be made of these responses to
allow a quick effect evaluation of carbon cycling on the
variable.   Besides these efficiencies, material balances will
be made daily for sulfur, H2, H2S, and carbon to lend credence
to the results being obtained.  The material balance will be
particularly important in assessing possible needs of recali-
bration of gas analysis equipment.
                             699
-------
                                              FIGURE B-2-1
                                                                             OPERATING LOG 1
                                                                                 DATC
o
o
-------
The advance preparation made should insure a more meaningful
set of results in line with attaining the target goals
mentioned above.  Particularly it should make us more aware of
process changes that might be necessary to meet the goals.

Integral Run

In preparation for a 15 day run in the S02 pilot plant, a
shorter run was made to evaluate the system under extended
operation.  During the run all equipment was operated at antici-
pated process conditions and cylinder H2S was used.  The initial
goal was to attain at least 3 cycles.  Equipment operation was
stable at the end of 2 cycles when an emergency shutdown of the
boiler, estimated to last several days, resulted in the shutdown
of the S02 removal equipment.  In general, the goals of S02
removal, regeneration gas utilization, and conversions were
approached or exceeded.

     Operating Conditions

The average operating conditions and carbon and gas analyses
are given in Table    B-2-2.  The carbon was circulated through
the pilot plant at a carbon rate of 28.9 Ibs.  C/hr.  The S02
sorber was run at 3 ft./sec. with an inlet S02 concentration of
1600 ppm.  The temperature of the bottom stage was held at
about 300°F, the temperature on the second stage was controlled
at about 160°F with a water srpay, and the temperature of the
subsequent stages averaged about 180°F.  The S02 removal effici-
ency was such that an acid loading of 0.216 Ib. acid/lb. C was
obtained compared to the goal of at least 0.18 Ib. acid/lb. C
loading.  The sulfur generator was run at about 0.3 ft./sec.
with an inlet H2S concentration of about 30 volume 70.  The
temperature was controlled by the moisture content and carbon
temperature set in the carbon preconditioner.   The conditions
in that unit were about 310°F at a steam concentration of about
65% to maintain an acid solution on the carbon of about 0.72
Ib. acid/(lb. acid + Ib. H20).  This was estimated to be suffi-
cient to minimize the premature evolution of H2S04 as S02•

The H2S generator/sulfur stripper was run at 2.5 ft./sec. at
1200°F with an inlet H2 concentration of about 30 volume 7o.
The average temperature of the unit was about 1200°F with
temperatures ranging from about 850 to 1500°F.  The lowest
temperature of 850°F was on the fourth stage where the pre-
heated carbon of about 600°F was fed.  The higher temperature,
near 1500°F, occurred on Stages 5 and 6.  The cause of this
high temperature is being rectified.
                             701
-------
                                         TABLE B-2-2.  AVERAGE OPERATING CONDITIONS AND CARBON AND GAS ANALYSES
UNIT
S02 SORBER:
BOnOM STAGE
TOP STAGES
CARBON PRECOND.
S GENERATOR
H2S GEN./S STRP.
TEHP..
°F
AVG. RANGE
« 2io-
"• 'ft
310 3°V
™ Uf
nm M5 -
1185 149Q
PRES.
DROP
IN.
HpO
21

6
9
21
GAS FLOW RATE,
CFH 3 70°F
FLUE
GAS
15,100

—
AIR



410
STEAM



780
H2S




75
H2




82
N2




176
187
TOTAL S
ANALYSIS
ON C, %
IN
3.4

8.1
8.1
23.0
OUT
8.1

8.1
23.0
3.4
H2S04 AND S CONTENTS
ON CARBON
IN
iWCID/fC
0

0.216
0.216
0.007
#s/*c
0.035

0.035
0.035
0.297
OUT
JACID/IC
0.216

0.216
0.007
0
*S/*C
0.035

0.035
0.297
0.035
GAS
CONCENTRATION
INLET*, S
S02
0.162


—
H2S
--


30.5
H2
—


29.8
«2
«


69.3
72.0
GAS CONCENTRATION
OUTLET*, I
S02
0.0115


0.7
0.28
H?S




2.0
23.4
H2




1.3
H20



*
36.5
**
4.5
•*
CO




0.07
0
C02 ,N2




0.02
0.35




60.9
70.6
o
K>
                        *As determined by a gas chromatograph.

                       **Br difference.
-------
During the run the carbon was  circulated  through  the  equipment
as mentioned at a carbon rate  of  28.9  Ibs.  C/hr.  The estimated
carbon inventory was roughly 430  Ibs.  C so  a  carbon cycle  is
taken as the time required  for the  complete carbon inventory  to
be turned over.  The time for  a cycle  is  about  14 hours.
Steady state is taken as the time required  to get carbon from
theinlet of the S02 sorber  to  the H2S  generator/sulfur stripper,
about 10 hours.  It is then assumed steady  state  is from this
time on.  The stability of  the run  is  measured by the responses
of all carbon and gas analyses for  the run, but the gas analyses
of S0£, H2S, and H2 are the major indicators  of stability  during
the run.

     Main Results

          Gas and Carbon Analyses

The gas and carbon into and out the process units were analyzed
routinely for assessment of the process stability, efficiency,
and for material balances.  The gas and carbon analyses from
the units were effectively  constant for the duration  of the
integral run.  Therefore, the  average  results of  the  analyses
given in Table    B-2-2 are indicative of the results  obtained.
Typically the regenerated carbon from  the H2S generator/sulfur
stripper to the S02 sorber  contained about  0.035  Ib.  S/lb. C.
The carbon from the sorber  averaged an acid loading of about
0.216 Ib. acid/lb. C.  The  carbon from the  sulfur generator
averaged a sulfur loading of about  0.30 Ib. S/lb. C and an
acid loading of about 0.007 Ib. acid/lb.  C.   This means the
sulfuric acid conversion to sulfur  was about  93%.  The gas
analysis from the S02 sorber indicated an inlet S02 concentra-
tion of about 1600 ppm and  an  outlet of about 115 ppm for an
average S02 removal efficiency of 93%.  The gas analysis from
the sulfur generator gave an inlet  H2S concentration  of about
30 volume % and an outlet concentration of  about  2% for a H2S
utilization of about 93%.   The outlet  SC>2 concentration ran
about 0.7 volume % for a premature  evolution  of H£S04 of about
8% of the sorbed acid.  The gas analysis  from the H2S generator/
sulfur stripper was an inlet concentration  of about 30 volume °/0
and an outlet concentration of 1.3% for an  overall H2 utiliza-
tion of about 967o.  The outlet H2S  concentration  was  about
23 volume % for a H2 conversion to  H2S of about 82% and sulfur
conversion to H2S of about  68% (want 75%).

          Material Balances

The gas and carbon analyses were used  to  obtain material
balances for sulfur , hydrogen, and carbon.   These balances are
given in Table B-2-3 on an  individual  unit  basis  and  an overall
pilot plant basis.  The stream identifications are given on
Dwg.  2529 in Appendix B-3 for  the integral  pilot  plant.  The
                             703
-------
TABLE B-2-3.
MATERIAL BALANCE SHEET FOR INTEGRAL
OPERATION OF S02 PILOT PLANT
Stream
NuRber
G-ll & -12 •
C-ll
6-13
C-12
D-ll
D-12
C-13

G-301 I -302
C-12
6-303
C-201
0-301
0-302 '
•
G-204
C-201
G-205
G-205
C-^C*
D-201
'
G-103
C-101
C-102
G-104
G-104
G-104
C-103
D-101

Stream Identity
SQ2 Sorber - Gas In
- Carbon In
- Gas Out
- Carbon Out
- Cyclone
- Dust Collector
- C Weepage
TOTAL
C Precond. - Gas In
- Carbon In
- Gas Out
- Carbon Out
' - Cyclone
- C Filter
TOTAL
S Generator - Gas In
- Carbon In
- Gas Out H;S
- Gas Out S02
- Carbon Out
- C Filter
TOTAL
HgS Gen./S Str. - Gas In
- Carbon In
- Carbon In
- Gas Out HZ*
- Gas Out S
• Gas Out HZ
- Carbon Out
- Cyclone
TOTAL
Overall Balance
Sulfur Balance,
Ibs. S/hr.
In
2.03
1.02
.-
..
..
„
"
3.05
0
3.06

._
»„
—
3.06
6.22
3.06
.-
„
»
_"r-
9.28
0
.1.29
7.30

__
..
mm
Out

..
0.14
3.06
0.02
0.03
0.00
3.25

„
0
3.06
0
—
3.06

...
0.48
o.iv
6.59

9.24

*•«
•>«
5.05
2.52

1.02
0.01
8.59 8.60
8.25 8.42
— i
Hydrogen Balance,
Ib. ?/hr.
In
..
--
..
..
._
..
*"
—

__
__
__
„.
._
--

•••>
— M
imm.
>*
—
~
0.40
0
o


__
••
0.40
0.40
«^«-^MW«
Out
..
—
. —
—
—
~
"
—

__
._
..
_.
..
—

- —
__
- —
__
—
—



0.32
Q
0 02
v * V(*
n
V
0 	
0.34
0.34
•
Carbon. Balance
Ib./hr.
In






























540
•»«H>MM«IM
Out


,



























483
•H^*l^^IM^^^^^HB
                    704
-------
sulfur balances across the S02 sorber, sulfur generator, and
the H£S generator/sulfur stripper gave an in/out ratio of
3.05/3.25,  9.28/9.24,  and 8.59/8.60, respectively.  The overall
sulfur balance was 8.25 Ibs.  S/hr. into the system and 8.42
Ibs. S/hr.  out of the system.  These material balances give
good reliability in the results of the run.

The hydrogen balance indicated 0.4 Ib. H2/hr. into the H2S
generator/sulfur stripper and 0.34 out as H2S and H2.   The
unaccounted for H2 amounts to about 15% of that fed to the
unit.  This is similar to the results of past runs on a one
carbon cycle basis.

A more extended run that the two cycles of the present run is
needed to assess the effect of cycling on the additional H2
usage.  The last H2 and H2S analysis at the outlet was made
near the start of the second carbon cycle, so that the
hydrogen material balance is basically an indication of the
results of the first carbon cycle.

Prior to and during the run a total 540 pounds of carbon were
introduced into the system and 650 pounds of material were
recovered.   The pounds C depends on the values taken for the
amount of sorbed sulfur, moisture, and acid content.  In the
reactors containing the most carbon, also having the most
effect on the balance (S02 sorber and sulfur generator),
these constituents vary from the reactor inlet to outlet, so
for the present material balances an average value across the
column was taken.  Using this method the carbon balance indi-
cated 540 pounds in and 438 pounds out, a difference of 10%.
After the next cyclic run all of the carbon will be regenerated
so a more accurate balance can be obtained.
                            705
-------
                       APPENDIX B-3


                        BLUEPRINTS


Dwg. No.                     Title

INTEGRAL
  2507      Mechanical Integration - 20,000 CFH S02      708
              Pilot Plant - Process Flowsheet

  2511      Mechanical Integration - 20,000 CFH S02      709
              Pilot Plant - Equipment Modifications
              and Relocation

  2528A     Instrumentation for Integrated S02           710
              Recovery Process

  2529      Material and Flow Streams and Sample         711
              Ports

S02 ADSORBER

S-M-11709   Fabrication Details - 18" S02 Adsorber       712

  2401      18" Diameter High-Capacity Fluid Bed         713
              S02 Adsorber at No. 6 Boiler

6"0 PRE-CONDITIONER

  2488      Carbon Pre-heater - 8"0 Moving Bed           714
              Sulfur Generator

8"0 ACID CONVERTER

  2484      Fabrication Details - Moving Bed Reactor     715

  2485      Process Flowsheet (Preliminary Drawing)      716

4"0 UNIT

  2376      4" Diameter Stainless Steel Fluid Bed        7l7
              Reactor (Fabrication)

  2399      4" Diameter Fluidized Bed Regenerator        718
              Located at No. 6 Power Boiler
                            706
-------
Dwg.  No.                      Title                      Page

  2385      Distributor Plate Template - 4" Diameter     719
              Stainless Steel Reactor

  2487      Gas Heater for 8"0 Moving Bed Sulfur         720
              Generator and 4"0 H2S Generator/Sulfur
              Stripper

SULFUR CONDENSER

  2537      Sulfur Condensing System for S02             721
              Recovery Pilot Plant

  2532      Assembly Drawing - Sulfur Condensing         722
              System

GAS CHROMATOGRAPH

30460-B     Schematic of Analyzer                        723

30460-Z     Schematic Flow for Gas Sampling              724

30461-F     Gas Sample Handling System Schematic         725
                            707
-------
708-A
-------
            Mechanical  Integration -  20,000  CFH
            S02  Pilot Plant  - Process  Flowsheet
                                Dwg.  2507
     a

     b
Xv    -;•.%.
i... V-•;•••"•'
 \ /  ft!*ff-"i;Ffie*- i
 V  lf**»«V**  _
 / • r7,^-^
^•v   AW«,*l j(-» . i ^^r i

           (,,.
                                                         T  jf / /: vv? r^>
                                                             "~"
                                                              Westvaco
                                                              CHARLESTON  RESEARCH CENTER
                                                              P. O. BOX S207 NORTH CHARLESTON. S. C. 29486
                                                              HAWNEir c /?e»» MTUJ. ?•; ZJCMCD
                                                               SOUS	1 JMIW. I W.
                                                                            DWG. No. 2507
                                       708-B
-------
         \
   gf'ZZ

ttrg **?T£>n (¥>vet (
                                         C, VfS JpCXCTtb
                                        r- L t
                                                        RK#'B)  i
                                                £-* »T I MM
                                                                1
                                                        S tat t MI*

                                                                                                             #7  "/9-
                                                      709-A
-------
Mechanical Integration - 20,000 CFH
S02 Pilot  Plant  - Equipment
Modifications  and Relocation
Dwg.  2511
                                 A" i.i« At* HOSK.
                                       Westvaco
                                       CHARLESTON RESEARCH CENTER
                                       P. 0. BOX SX07 NORTH CHARLESTON, S. C.
                                            ijc:*k.
                                        SCAU - 1 JO. NO I W.
                                                 O. Ml. I p. - jTjj
                                                 21 J DWG. Na
                       709-B
-------
710-A
-------
Instrumentation for Integrated  SC>2
Recovery Process
Dwg. 2528A
                                              Westvaco
                                              CHARLESTON RESEARCH CENTER
                                              r. 0. IOX 9107 MOUTH CHAKIHTQN. I. c. IMM
                                                a—pssnzTTirETETjr—-^rf
                                                n	1.,..'..-	LI.-	I DWG. No.
                           710-B
-------
711-A
-------
Material and Flow Streams  and
Sample  Ports
Dwg.  2529
                                            CHARLESTON RESEARCH CENTER
                                            f, 8. BOH 5?07 NORTH CmRLESTOM. s. C 21406
                       711-B
-------
                    Vt'tt MIL* VHt loMsTft.0.
                    ID. T« MATCH 1,0, of t, KM lam m
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                                                                                       MOT AFTIMt IU MX SECT lOUt-VWHH
                                                                                       wn ONLY m CLWTT
                                                                                      [-2* CPU*. WITH PUM
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 /liiUaV
                                                                 BOTTOM   DETAIL
                                                                     Jlffclti. OHt
                                                                                                  GENERAL HQTEfr
                                                                      I. HL IMTMtM.1 fU«M. K WltTVACO WifM  YHf •KClVTldU Of tltW*
                                                                      t AIL ttlUFtN* TO M W ACCOM. WHtt i*T[V 5*(t!> Of  AWS.
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Fabrication Details -  18"  S02
Adsorber
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              Carbon  Pre-heater  -  8"0 Moving
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                                  CHARLESTON  RESEARCH CENTER
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                                 720-A
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Gas  Heater for 8"0  Moving Bed
Sulfur Generator and 4"0
Generator/Sulfur Stripper
                                 Dwg.  2487
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                             Westvaco
                             CHARLESTON  RESEARCH CENTER
                             P. 0. BOX 3207 NORTH CHARLESTON, 8. C. 29406
                             DRAWN BY.
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              PRIMARY 4 (MCJc-u* suLPUC  PUMP*
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721-A
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Sulfur  Condensing  System  for

S02  Recovery  Pilot Plant
                    Dwg.   2537
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Assembly Drawing  - Sulfur
Condensing System
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                                            CHARLESTON RESEARCH CENTER
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                                   LIST Of MATERIAL
UNUfSS OTHERWISE SPECIFIED
DIMENSIONS ARE IN INCHES.

TQUERANCES:
MA ERIAL
                            CONtMCT NO
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                                  723-B
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724-A
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                                   REVISIONS
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DESCRIPTION
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                                                                                            IN PLACE Or rERTOBATIC  SCREEN
                                                       725-A
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         Gas  Sample  Handling  System
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     AfAUYZER TO MOUNT 01
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                                     725-B
-------
                        APPENDIX B-4

                PILOT PLANT OPERATING MANUAL
Introduction
1.  S02 Pilot Plant Location and Layout Drawings         727
2.  Block Flowsheets                                     732
3.  Equipment Schematics                                 743
4.  Process Control                                      761
5.  Process Control - 8" Diameter Moving Bed Sulfur      766
      Generator and 6" Diameter Pre-conditioner
6.  Process Control - 4" Diameter S Stripper/H2S         775
      Generator
7.  Pilot Plant Electrical System                        781
8.  Start-up and Shutdown Procedures                     784
                            726
-------
Introduction

The purpose of the operating and instruction manual is to pro-
vide appropriate information on equipment and operating
procedures.  The manual should facilitate the efficient opera-
tion of the equipment as well as provide the necessary informa-
tion to effectively troubleshoot and correct operating problems
which might be encountered.

The operating manual is given in three volumes.   The first
volume contains process description information.  The second
volume contains complete vendor's information on the maintenance
and operation of the equipment.  The third volume contains
mechanical, electrical, instrumentation, and structural drawings
for the S02 recovery equipment at No. 6 boiler at Westvaco's
Charleston Mill.

The abbreviated manual given here is a condensed version of the
first volume covering the information directly needed to operate
the pilot plant.  This includes block flowsheets, schematic
diagrams, start-up and shutdown procedures, and process control
information which consists mainly of calibration curves for con-
trol of flow rates.  The section of process control has been
shortened by omitting the numerous calibration curves for
rotameters and other flow measuring devices.
                                727
-------
               APPENDIX B-4-1



S02 PILOT PLANT LOCATION AND LAYOUT DRAWINGS
                    728
-------
WESTVACO S02 RECOVERY PROCESS
  NO.  6 BOILER  INSTALLATION
          PLOT  PLAN
       729
-------
                    ELEVATION VIEW OF WESTVACO S02 RECOVERY  PROCESS
                     AT NO. 6 BOILER - EAST VIEW FROM COOPER RIVER
 Level  8
 Level  7
 Level  6
 Level  5
 Level  4
 Level 3
Level 2
                      66'
                         Carbon
                         Blender
                                             Bucket Elevators
                                              for Carbon
                                             8"0
                                             Unit
                                                              ?T
                                                                      Carbon Heater
                                                                      4"0 Unit
                                                                Unit
                                                                    Carbon  Cooler
                                                                     4"0 Unit
                                                                        Panel  Board
Level 1
\   \Door
                                      730
-------
                        HESTVACO  S02  PILOT  PLANT

        LOCATIONS  OF  MANUAL  ALARMS  AND  EMERGENCY  EQUIPMENT
                                 MECHANICAL
                                 SHOPS BLDG.
FIRST AID
 TATION
                       POWER
                    HOUSE OFFICE
          POWER
      BOILER  HOUSE
                                    7
SAFETY
EQUIPMENT (OPERATING FLOOR)
           iWESTVACO  PROCESS
           ! PILOT EQUIPMENT
           [AREA
             PROCESS
             UNITS

             OVERHEAD
           I  GAS
                                 *

RE TRUCK
                                                                         AMBULANCE
                               SAFETY  EQUIPMENT
                                (GROUND FLOOR)
                                                                         GAS
                                                                        STORAGE AREA
                                                   MANUAL ALARM SIGNALS
                                                •  MANUAL ALARM ACTUATORS
-------
 APPENDIX B-4-2



BLOCK FLOWSHEETS
     732
-------
(This page intentionally blank.)
          733
-------
733-A
-------
           Mechanical Integration,  20,000  CFH
           S02 Pilot  Plant  Process  Flowsheet
Dwg,  2507
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                                                       CHARLESTON RESEARCH CENTER
                                                       P. 0. »0» 1207 NORTH CHARLESTON. S. C. MW>
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                                   733-B
-------
73A-A
-------
Material Flow  Streams and  Sample
Ports
Dwg.  2529
                                              Westvaco
                                              CHARLESTON RESEARCH CENTER

                                              P. 0. BOX 5207 NORTH CHARLESTON. S. C. 29406
                                               ssra  I JOB NO. wo HO |r>	jTj	
                                              **?»*... ]-.-	I.....T. JPwc. No. 2529
                          734-B
-------
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                       7 35-A
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   Instrumentation for Integrated

   S02  Recovery Process
Dwg,  2528A
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                          735-B
-------
                                  18" 0 S02 SORBER
                                       18" 0
                                    S02 and
                                      Sorber
                                                           -»   2
STREAM
   1
IDENTIFICATION
   Flue Gas
               Flue  Gas
              Sulfur Free
           Activated Carbon
 COMPOSITION
1100 ppm S02*
 4 vol.  % 02
15 vol.  % H20
  150 ppm NO
11 vol.  % C02
   Bal.  N2
110 ppm  S02**
[Balance Same
  as Above]
 2% Elem. S
          *Normal Stack Conditions
         **Minimum S02 Outlet Composition
     FLOW RATE
160-300 CFM e 70°F
                                     180-320 CFM @ 70°F
TEMPERATURE. °F
    300 - 350
                           150 - 220
                                      13 - 25 Ibs./hr.      Room Temperature
                                     736
-------
STREAM     IDENTIFICATION        COMPOSITION            FLOW RATE          TEMPERATURE, °F

  (J)       Sulfuric Acid     0.181* # HgSO^ C      16-30 Total #/hr.        ?0 - 100
            Loaded Carton        h Wt. % HgO
                               Balance Carbon

  (5)         Hot Water           100^ E^>              60 #/hr.                 150
                                        737
-------
                    WATER SPRAY SYSTEM FOR 18"0 S02 SORBER
       To
      Sump
                          Insulated  from H20
                          Heater  to  Column
H-l
 11-2?
ffi 22  120V
                             H20
                           Heater
            Thermostat
   Temp.
Controller
            Electric-
            Pneumatic
            Transducer
                            Water
                            Brooks Rotameter
                            Tube R-6-15-B
                            Carboloy Float
                           Air
                         Operated
                          Valve
                                          anual
                                         Bypass
                                                             Thermocouple
                                                              Stage # 2
                                                                         18"0
                                                                         Unit
      Air
      Brooks Rotameter
      Tube R-6-15A
      S.S. Float
                 Knock-out
                   TraT
                         •Air
                                     Filter
                                                              Regulator
                                               /
                                              "4
                           Booster
                            Pumo
                                            City Water
                                              Supply
                                   738
-------
                               SCHEMATIC OF HgO SPRAY SYSTEM
 Mill
  Air  t-
Supply
—Mxt	
   H20
 and Oil
  Trap
                                                                           To Spray
                                                                           Noz'/J.e on
                                                                          Stage 2 of
    Brook s
   Rotameter
ilator

^VioTT anrl Tulip Hpnt
Exchanger - Insulated
_fcr 	 k-

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A
HgO
Filter
1 Brooks Ro
J 0-129 c
J 0-74.5 #/

	 IsX 	 fc



4 '
^H
I
^^J^HM



/^\ Pressure
^*"^ Gauge
•••
nsulated X
,
                                                                  6
                                                                  Dial
                                                               Thermometer
                                                                            To Suinp
                                  v
                                 !
                           Brooks
                          Rotameter
                          2lf #/Hr.  Full Scale
  Steam
Strainer
and Trap
                               50 psig
                             Steam Supply
                                        739
-------
                          . i|"   REGENERATOR
      ©©©©©©
                             Rogene

                              rator
                                            Carbon Heater
                                         Carbon -Cooler
CTKKAM


   1


   2
        Nitrof.cn


    )i.vilvogcn .Sit'U'J
Pure

Pure
o-6iio CFU e 70° F*    Roora Tcmp< _ 1000

O-llOO CFH G 70° F     Room
*At QlBMsplicric prccsurc.  As the proRjuu-o Jjicrouncs at tlui roLaiiK.-tcr outlet
 the flow incvear.i-s by u i';it-tor of    l'~t j}( Y
                                         '
                            740
-------
STRKAM
  IDMrnFICATlGN
                      COMPOSITION
     FLOW RATE
TEMPERATURE, °F
       Steam
                         *«*
s)
I)
6)
T)
8)
Hydrogen
Carbon Monoxide
Carbon Dioxide
Inlet Gas
Lower Carbon Seal
Pure
Pure
Pure
Note*
Pure
  Leg Nitrogen

Upper Carbon Seal
  Leg Nitrogen

     Off Gas

  Inlet Carbon

  Outlet Carbon
                          Pure
           3 70° F


0-300 cm © 70'F

0-100 CFH © 70*F

0-100 CFH © 70°F

0-61fO CFH © 70°F


   35 CFH @ 70"F


   25 CFH @ 70°F
                                                                        230-1000


                                                                        800-1000

                                                                    Room Temp.-1000

                                                                    Room Temp,-1000

                                                                    Room Temp.-1000


                                                                      Roon Temp.


                                                                      Roon Temp.
                         Note**       0-?lK> CFH© 70°F     Room Temp.-.1000

                         Note***        0-50 Ibs./hr.      Room Temp.-1000

                         Note****.      0-50 Ibs./hr.      Room Temp.-1000
   •^Contains HgS + Inerts for Sulfur  Generation
    Contains Inerts for Sulfur Stripping
    Contain (3 112 + Inerts for HgS Generation

  *«Cont:iins Steam (HgS, SOg Possible); S; HgS (Hg, S Possible)   for  each
    of the abovfc operations, respectively..
«*tCo»tains
                   or S.
****Contalns S (from Sulfur  Generation) or Very Low SSlfur  (HgS Generation or
    Sulfur Stripping)
                           741
-------
                                                            -j^l^ ,_.  aBF  a*/*, _ISJI.-»M»JUJL
742-A
-------
Sulfur Condensing System  for
S02 Recovery  Pilot  Plant
Dwg,  2537
1


^

1
i 1C

f. \ ,
:^>
'
L

c -404 Liauto sut<=^
J mrt.». - I»-L, K«*» T i
i ee.p- ow«i ,1111. _'
1
                                T* • * MCVIMC, Be»
                                                         L,«. (J)
                                                 STEAM TRACIMH MOJIFOit

                                                <30UB*MI« «F CACN LlM • It >M*!r*Y
                                              Westvaco
                                              CHARLESTON RESEARCH CENTER
                                              T 0. »O» S10T HO«TM CH*»LE»TOM. S. C. IMM
                                                SULFUR.
                                                    -.^.^.mnii a.-.7i
                                                    JMttO. I Vo.HO. I
                             742-
-------
   APPENDIX B-4-3



EQUIPMENT SCHEMATICS
        743
-------
                           SCHEMATIC OF EXHAUST  LINES FOR SD0 REMDVAL EQUIPM3KT AT KO. 6 BOILER
                                                                                                                 I.D.
                                                                                                               Fan Blower
                                                                                                    K>
                                                                                                          \
Blender
-------
               PRESSURE DROP GAUGE READING FOR 18" 0 UNIT
(PJ-

•1«tf
On fjC
-Brt

0-8 (^

0-8 (q
00 /St
~8Vj
00 /Si
-8 r


X5-0-5 .
2
9>k
y
DPI-15)
3
J)
WI-14)
4
b
1DPI-13)
5
g\
fDPI-12)
6
g^
riDpi
7















••


18" 0 S02 SORBER







/^ 
-------
         PRESSURE  DROP GAUGE READING THROUGH 18" 0 UNIT
2-0-2
  0-8
             3

             3
  0-8
 0-8
             D


             5
 0-8
         i
         i
         •	fi
 0-8
                       Stage 4
                       Staged
  Stage  2
                                       ->Gas Exit
Blank Plate
                                    Bypass
  Stage 1
                                  X  *	6as Inlet
                                                              Orifice
                                                         IT—
                                                     0-5 L(J5)—I   ^  0.5n

                                                            APor1flce porificc
                                746
-------
THERMOCOUPLE  ARRANGEMENT FOR 18" 0 S02 SORBER
(TL-16) 9
*••
/TI ir^ 	 	 	 '
UL-luJ
/ TI 1 Jl \
(TL-14)
/TI 
-------
         THERMOCOUPLE ARRANGEMENT  FOR 18"  0  S02  SORBER
Tl-9
TI-4
TI-3
TI-2
TI-8
TI-1
TI-5
                                           Gas  Exit
                     Stage 4
                     Stage 3
                      Stage 2
                                TI-7
                    Blank Plate
                                   Bypass
                      Stage  1
                                TI-6
                                                        Heat Exchanger
                                                                Ori fi ce
                                            Gas Inlet
                                                                  TI-10
                                                    Butterfly Valve
                                748
-------
                   GAS SAMPLE LINE ARRANGEMENT FOR 18"  0 S02 SORBER
                  Dekron-Steam Traced & Insulated
   To Gas
Chromatograph
       (GS-15).
        (GS-14)-
       (GS-13)-
        (GS-12)-
       (GS-11)-
       (GS-10)-
•*• Gas Exit
                                             18"  0  S02  SORBER
                                               * - Gas Inlet
          Dekron-Steam Traced  &  Insulated
                                                      To Gas Chromatograph
                                 7A9
-------
    GAS SAMPLE LINE ARRANGEMENT  FOR 18"  0  S02  SORBER
SL-4*,
SL-3
Si-2
SL-8
SL-1
SL-5
                                       -> Gas  Exi t
                    Stage 4
                    Stage 3
                    Stage 2
                  Blank Plate
                                   Bypass
                    Stage 1
                                                      Heat Exchanger
                                               Gas Inlet
                                                         Butterfly Valve
                   750
-------
                         DUST COLLECTION SCHEMATIC  - 18" 0 UNIT
7th_LEVEL 	 _
• i
18" 0
Off-
6th_ LEVEL 	
5thJLEVEL 	
4th LEVEL (I.D
	 — 	 	
TEV 6-2
Unit
Sas m- ' iTi
, 	 .,_. 	 ,flftrnCycl one '
'I"! I c_-| EV 6-

r
Fan Floor)
3rd LEVEL
E
V 2-2
IfEV 2-3
Carbon
Blender
«
(
»
1


EV 6-7 -
:v 6-3-|j- £=
DUST
COLLECTOR
F-l
4-w
^L
EV 6-51
EV 6-8— t|i —
EV 6-9 -ijl —
EV 5-4
EV 4-6 — f
HT-
••I

mm
EV 3-1 H|| 	
EV
	
H- +4
EV 6-6
El


2-'*T
No J
Valve l
Exhaust
J~*to Roof
^
Exhaust Blower
'- E-2
EV 6-16
f + Shroud
6-7
— ||i-
-$-
5
EV 3-
-4-
LV
• r^ 4 "p unit
Carbon
Preheater
EV 5-1
± Shroud
'l'~4"0 Unit
EV 5-3
r 4'ij Unit FU c ?
^ C * -3~*C
EV 4-5
EV 4-4
^Shroud £y ^_2
EV 4-1
3
- Shroud 4"0 Unit
Preheater


     Carbon
Blender Discharge
                                        751
-------
       INSTRUMENTATION CONTROL SCHEMATIC FOR 8" 0 SULFUR GENERATOR
                                       >6"  0 Preconditioner
                                                                      *•   Gas Out
                                                             Cyclone
                                                               (CY-301)
          Variable  Rheostats
                  -205  ERS-206
                                                           8" 0 Moving Bed
                                                           Sulfur Generator

R-8 (Manual  Control)
  R-9
(Manual
Control)
         T   r
         H2S   N2
                                                                         I	
                                             Carbon Bypass
                                                                           Carbon Out
                                     752
-------
  PRESSURE DROP GAUGE READINGS FOR 8" 0 SULFUR GENERATOR
     Carbon  In
   P.    DP
 Orif.  Orif.
 PI-301  DPI-301
(0 - 50) (0  -  2)
                                                         Cyclone
                                                           (CY-301)
                                                                Gas Out
 n
H2S  N2
                        Gas
                      Heater
                                             N2
11
1
-f
22
8" 0 MOVING
BED SULFUR
GENERATOR
(RV-200)
•\ ..r


\ 	
	 ^ udb
31
P Ou
11
P 1
221
                                                                 Out
                                                                    -201
                                                                    -200
                                                                 DP L.S.L.
                                                                 DPI-208
                                     Carbon  Bypass
                                                       N?
                                                           Vibrating  Feeder
                                                                        Carbon Out
                           753
-------
    THERMOCOUPLE ARRANGEMENT FOR 8"  0  SULFUR GENERATOR
Carbor
Gas
Heater
x~^a Tn f"\
Air-Q ° Iff
tf "- 1 i
Steam .1...
(
T
i In
\

12
TI,
L-2
<
TR
101)
9



>
*


,
k
.,6" 0 Preconditioner
s JT^ — "dj> ^u
r ^_pj
1 I Cyclone
13 (TIC-301) V (CY"301)
(Iron-Const.) *
\
      (TIC-302)
     (Iron-Const.)
 rr
H2S  N2
                  (TI, TR,
                  TL-203)

                  (TL-202)


                  (TL-201)
 Gas
Heater
                            (TL-200)
                   TIC-201
                 (Iron-Const.)
                                                 (TL-207)
                                             N2
                                              8"  0 MOVING BED
                                              SULFUR  GENERATOR
                                                         Gas Out
                                 Carbon  Bypass
                                         Vibrating Feeder
                                        -']  (CV-2)

                                                Carbon Out
                   754
-------
                GAS SAMPLE LINE ARRANGEMENT FOR 8" 0 SULFUR GENERATOR
Air-£   J
    Blower
                      Carbon I
                                                                         Gas Out
     To Gas Chromatograph
                rr
 *0ekron - Steam Traced and
                                 Dekron*
-N--

-N--
-iX--


HXh-

60"


48"



36"



24"



12"
                                          ^Dekron
                                       To Gas

                                     Chromatograph
                                                             Cyclone
                                                                To Gas
                                                             Chromatograph
                                                           N2
                                                                      N2
                                                            8" 0 MOVING BED

                                                            SULFUR GENERATOR
                                                                 N?
                                                                  ' Vibrating Feeder
                                                                           I
                                               Carbon Bypass
                                Carbon Out
                                   755
-------
                              DUST COLLECTION SCHEMATIC - 4" 0 UNIT
 6th LEVEL
                               Flare
  4"  0 Unit
   Off-Gas
 5th LEVEL
  8"  0  Unit
   Off-Gas
  r H  e\ H- ^ 4-
  v   v \*ti t *,
  Off-Gas
                    CQW qno
4th LEVEL  (I.D. Fan teveTJ
Cyclone
      CY-101
                                              •Carbon
                                               Filter
                                                                   I.D. Fan Exhaust Blower
                                                                          E-3
3rd LEVEL
                                    From Power
                                   House 3oiler
                                           756
-------
                         DUST COLLECTION SCHEMATIC - INVENTORY HOPPER
                                   4" 0 Unit
                                Bucket Elevator
                                               Exhaust
                                              (To Roof)
7th LEVEL
                              EV  6-10
   7
                EV 6-11 •=•
6th LEVEL
Jrf EV 6-12
                                                    DUST COLLECTOR
                                                         F-4
                              Air Bleed
              Carbon Inventory Hopper
                   on 2nd Level
                 (Operating Level)
                                          757
-------
                     AIR SUPPLY  SYSTEM  SCHEMATIC  FOR SYSTEM
                          ON SOUTH WALL OF  BOILER HOUSE
18" 0 H£0 Cooling^,
Spray System
To Pres. Reg.  of
Pneumatic Valve
at Orifice
Pressure Supply for
Pneumatic Actu-
ator of Butterfly Valve
on Inlet Flue Gas to 18"  9
Main Air Supply
Kane Feeder
                                                          Open (On 2nd Level)
                                                              Air Purge
                                                              Kane Feeder
                                                     Boiler  House  Air Supply
                                      Vent
                                   758
-------
PRESSURE READING SPECIFICATIONS FOR 4 INCH DIAMETER REGENERATOR
                      Carbon Inlet      -\Q

Gas Exhaust 4 	 ...


•








'







Gas Heatpr _,__ 	





4

Staae 8

Stage 7

Stage 6

Stage 5

Stage 4

Stage 3

Stage 2

Stage 1


_J <
\


V A LIC 102
1 9 T
_i_
Carbon Heater
Q DPI -109
/ \
/
O pi-ioi
y
/i npi-ios

A DPI -107
6 V
f\ DPI-106
**rS
A DPI-105
4 Y
A DPI-104
3 S^
A DPI -103
2 Y
A DPI-102
1 ^f
I | »%n T 1 Al
Vy* DPI-IOI
0
A 1
\Pl-103fj
A
Q DPI-100
11 Y
Carbon
Cooler*
                               T
DPI - Pressure Drop

PI  - Absolute
        Pressure
                            759
-------
THERMOCOWIJS SPECIFICATIONS FOR k INCH DIAMBTKR R15GK
                    Carbon Inlet
                         1
                            Carbon
                            Heater
      c-Uii
                                                           j    |nc-io5







'



CJt "\ r

<
Stage 8
Starve 7
Stage 6
Stage '5
Stage U
Stage 3
Stage 2
Stage 1

t 1


P JiA
	 U8
rt li T
C-'LY
__!T
It 1 /*
C-'»6
	 |<6
r \\ c;
c."i?
_Ji5
!|!4
-43
U3
C-i)2
	 J*2
C)l 1
— 41
»»1
	 19



                             (TI, TR, TL-108G)  !	»
                                       	—[      1  HTA-101
                             (TL-108)
                             (TL-107G)	|	1  TIC_ioU
                             (TL-107)
                             (TL-106G)
                             (TL-106)
                                         	j      |  TIC-103
                              (TL-105)
                              (TL-10UG)
                              (TI, TR, TL-10U)
                              (TL-103G)
^      j  TIC-102
                              (TL-102G)
                              (TL-102)
                              (TL-101)
                                               -j      j   TIC-101
                                            C-U9|     j
         TIC-100
                             1(12
       TIC-106
                                  (TI-113)
                              Carbon
                              Cooler
                                                       [    I
              HTA-102
                                          TI-C
    (Fenwal Temperature
     Controller and Controlling
     Thermocouple No.)
                        760
-------
APPENDIX B-4-4



PROCESS CONTROL
     761
-------
-"J
CT>
N)
                       12
                            15
                                   16
                                                     O

                                                     O

                                                     O

                                                     o
                                                       %>
                                         18
             o
19
                                                     O
                                                 O

                                                 O20
                                       *" DIA.  UNIT PANELBOARD
                                                                         25
                                                                        27
                                                                                    28
-------
  1   NO Rota.



  2   S02  Rota.



  3   02 Anal.



  k   Sample  Rota.



  5   Sample  Pump Bypass



  6   Sample  Pump ON-OFF



  7   Orifice Mag.  Ga.



  8   Inlet Gas  Map,.  Ga.



  9   18"  (Zl Press Mag.  Ga.



 10   Press Drop Mag. Ga.



 11   Inlet Valve OPEN-CLOSE



 12   Steam 6" 0 Unit



 13   Steam 18"  0 Unit



 Ik   1/10 Hr. Timer



 15   1 Hi-. Timer



 16   S02  Rota.  18" 0 R-6-15-B, SS, B1K.



 17   02 Anal.



 18   SOg  Anal.



 19   S02  Recorder



 20   Carbon  Level Controller



 21   Stage 1 Mag. Gauge



 22   Stage 2 Mag. Gauge



 23   Stage 3 Mag. Gauge



 2k   Stage k Mag. Gauge



 ITS   Heat Exchanger  Mag. Gauge



 OP   Outlet  Press Mag. Gauge



 OG   Outlet  Gaa Mag. Gauge



 25    Column  Heaters



 P.6    Pprny Water



27    Inlet Gas Temperature Recorder



28    Bailey Bottom Stage A P Recorder
                               763
-------
               AUXILIARY CONTROL EQUIPMENT AND MEASUREMENT
1.  HgO Spray System (Schematic  of System is  attached.)

2.  Analyzers
      A.  S02 Analyzer and Recorder
      B.  NO Analyzer - I0R.
      C.  02 Analyzer
      D.  Moisture Analysis with Packed Tubes of Drierite

3.  Temperature -  Multipoint Recorder
                             764
-------
Gas Flow Rate Control

Control of the gas flow rate through the 18" diameter sorber
is achieved by adjusting the pressure drop across an orifice.
Curves were plotted using the orifice equation, which permitted
the correct pressure drop setting to be determined quickly.  In
order to conserve space the curves are not included here.
However, the orifice equation from which the curves were
generated is:
AP
                  =   143.4(T0 + 460)[
     where  APO

            TO
            Tc
            U
       orifice pressure drop, inches W.G.
       orifice temperature,  °F
       average column temperature,  °F
       linear gas velocity in 18" sorber,
         ft./sec.
                              765
-------
                     APPENDIX B-4-5

PROCESS CONTROL -  8"  DIAMETER MOVING  BED  SULFUR GENERATOR
              AND  6"  DIAMETER PRE-CONDITIONER
                        766
-------
7—	T——7
f               i	r.
-------
                                       AIR FLOW RATE ORIFICE - 6"0 UNIT CARBON PRECONDITIONER
OO
-------
             	_ j	
                               F|n  Scale StAani FW ilfotA  In  6"0 Unit, CFH
                 3E
h*»
                                                 JU>-
                                                              -€)-
                                           1CX
                                                  i i i f
                                                                     
                                           :c>
                                                        :0
                                                                     C>
                                                                                 C3
                                                                                                                t/>
                                                                                                               -m-
                                          :s
*:
                                                                    ~o~
-rK
»«&-
         ts
"0~
                                                                    TT
-w»-
™0»_
                                                   H	T-+-
                                                                                                               "TS~
TO"
-n-
 CD
                                        ^
                                                                                                                m
J>_
_C3_
     ro.
     -&
                                                                                                                m
                                                                                                              —f*T-

-------
—-PROCESS-H 2S-GAS "FLOV
 :'   '    INLETTO     '
        150     200   250  300     400    500   600     800  1000
                 Gas  Flow Rate,  CFH 0  70°F
                     770
-------
   10.0
o
CM
CX
e
o
3
11
-------
                         TIME REQUIRED TO PURGE 8"0 MOVING BED AND  RELATED CARBON

                            HANDLING EQUIPMENT AS A FUNCTION OF THE CARBON RATE
    10.000

     9,000

     C.OOO 1--

     7,000 i

     6,000 -j
     5,000
•o


i

o

•o
41
4->
10

01
Cf


•g
-------
                                                                     Ir0:_su2- SQRBER: ;5s~& IHJNCIIQN: :.:_:
                                                       SO? REMQVftttfRQR-TtiT-FtUf"^ftS-
u>
                                                                   !terininecr"wftTi S02- AnaTyzer, -PPH

                                                             at ;Rpo|rT;Temperature Basisj  :'_']:_.__
-------
RELATIONSHIP BtlHEhN
.ATIONSRT?  BhlHEl
; --1" -I —--H-^
It COBVERSIfN TO SULFUR!TN WVWl
-------
                    APPENDIX B-4-6



PROCESS CONTROL - 4" DIAMETER S STRIPPER/H£S GENERATOR
                       775
-------
ON
        TIC4U
        HC45
        nc4i
HC4IO
TIC47
FIC43
                                   o o
                                   QLFA 101
                               .1C
                              1102
                              HTA
                              102
                             TIC 49
                             HTA
                              IOI
                                    O

                                    O

                                    o

                                    o
                          o
                          o
                                                              PI 101
0
1
2
3
4
5
6
7
8
9

(2)
                                                        LFAIOI
                                                                R6
                                                                                  R2
                                                                    R5  R4  R3  Rl
                                                                           a
                                                                           (3)
                                   4*DIA UNIT PANELBOARD
-------
TI CUll
TI CUlO
TI CU5
TI C^7
TI Ckl.
TI
LIC 102
HTA 102
TI
HTA 101
LFA 101
DPI-1
DPl-2
    •
DPI-3
   «
PPI-1* <
DPI-5
DPI-6
DPI-,7
  »
DPI-8  ,
4
DPI-9
DPIA'-l
PI-2
LIC 101
LFA 101
Fl-101
R-l
R-2
R-3
R-k
R-5
H-6
Carbon Heater Temperature Controller
Gas Heater Temperature Controller
Stages 5 and 6 Temperature Controller
Stages 7 and 8 Temperature Controller
Stages 1 and 2 Temperature Controller
Stages 3 and h Temperature Controller
Carbon Heater Level
Temperature Controller
Temperature Controller
Temperature Controller
LO Plow
Magnehelic Pressure Gauge
Magnehelic Pressure Gauge
Magnehelic Pressure Gauge
Magnehelic Pressure Gauge
Magnehelic Pressure Gauge
Magnehelic Pressure Gauge
Magnehelic Pressure Gauge
Magnehelic Pressure Gauge
Magnehelic Pressure Gauge
Magnehelic Pressure Gauge
Magnehelic Pressure Gauge
Man. Auto level Alarm
Upper Seal Leg
Steam
Flex-Tube Man.
HgSRota. Tube:  R-6-15B, SS, BIK.
H2 Rota. Tube:  R-6-15B, SS
H2S Rota. Tube:  R-8M-25-U BR 1/2 35 G10
C02 Rota. Tube:  R-8M-25-U BR 1/2 35 G10
N2 Rota. Tube:  R-8M-25-4 BR 1/2 35 G10
N2 Lower Seal Leg:  R-6-15A, SS, BIK.
Purge Rotas.
Panic Button
                     777
-------
               AUXILIARY CONTROL EQUIPMENT AND MEASUREMENT

1.  Inlet and Outlet Gas Sample Line
      A.   Both are  tied  into a gas chromatograph.
      B.   The outlet line is heated and insulated.  (Heater controlled by
          thermostat.)
                            778
-------
                            CONSTANT VELOCITY CURVES FOR 4"0 REGENERATOR
              Column Temp
TOO       200      300       400      500       600      700        800      900      1000      1100       1200
                                         qT, CFH * 70°F
-------
Gas Flow Rate Control

In the integrated pilot plant,  direct reading rotameters were
used so that the need for calibration curves was eliminated.
In earlier work before integration,  different rotameters were
used which did require the use  of calibration curves.
                         780
-------
       APPENDIX B-4-7



PILOT PLANT ELECTRICAL SYSTEM
            781
-------
Breaker Box No.  3
    1      Inlet Gas Line Heater (18"0 Unit) Orifice to Column
    2      Inlet Gas Line Heater (18"0 Unit) Orifice to Column
    3      Lights and Plug Mold,  18"0 Unit
    4
    5
    6
    7
    8
    9      Level Controllers  for  18"0 Unit
   10      Heaters,  Steam Line,  18"0  Unit
   11
   12      Heaters,  Steam Line,  18"0  Unit
                            782
-------
Breaker"Box No. 2

    1

    2      Two Heaters  - 4"0 Unit Off-Gas Line  and  Cyclone

    3

    4      Sulfur Condenser Pump Heater Box Fan Motor +  2
              Heaters  (1500 Watt)

    5

    6      Two Heaters; 1  to Carbon Filter, Other to Heater
              Filters  to S Condenser

    7      Chromatograph Module Control (Main Breaker)

    8      Two Heaters; 1  to Carbon Filter, Other to Heater
              Cyclone  to Filters

    9      Receptacles  at  Chromatograph

   10      157o Carbon  Flow to Top Stage of 4"0  Unit (CFC-3)

   11

   12

   13      Pre-Heater  Blower

 14, 16    Heater (Inlet Gas 8"0 Unit)

 15, 17    Power Stat  204  (Heater 8"0 Unit)

 18, 20

 19, 21    Power Stat  205  (Heater 8"0 Unit)

 22, 24    Column Heater (6"0 Unit)

 23, 25    Power Stat  206  (Heater 8"0 Unit)

 26, 28
                                 /
 27, 29

 30, 32    S Condenser  H20 Pump

   31

   33      Vibrating Feeder CV-2 (8"0 Unit C Discharge)

   34      Standby Screw Feeder

                           783
-------
                        APPENDIX B-4-8

               START-UP AND SHUTDOWN PROCEDURES

Start-up Procedure for Integral S02 Pilot Plant

1.  Cut on 6"0 unit blower.
    a)  Cut on Breaker 13, Breaker Box # 2.
    b)  Cut on switch on 8"0 unit panel board.
    c)  Set velocity as-determined by orifice AP for Gauge
        DPI-301.

2.  Set nitrogen flow rate into 4"0 unit and the upper and
    lower seal legs.
    a)  Set pressure at N£ regulator, R-5.
    b)  Set air pressure for inlet gas pneumatic valve at 20
        psig (behind panel board).
    c)  Set flow rates at rotameters.

3.  Cut on automatic slide valve carbon feeder (CFC-4) to
    4th stage of 4"0 unit.
    a)  Set air pressure for Foxboro DP controller at 20 psig.
    b)  Set air pressure for cylinder valve operator at 60 psig.

4.  Cut on vibrating feeder (CV-4)  for 4"0 unit carbon discharge.
    a)  Cut on Breaker 12, Breaker Box # 1.
    b)  Set variac at 10070 (115 volts) .
    c)  Cut on DPDT switch on 4"0 unit panel board to AUTO
        position.

5.  Cut on vibrating feeder (CV-2)  for carbon discharge from
    8"0 unit.
    a)  Cut on Breaker 33, Breaker Box # 2.
    b)  Set air pressure for Bailey DP controller at 20 psig.
    c)  Cut on at vibrator control box.

6.  Set nitrogen flow rate into 8"0 unit and the upper and lower
    carbon seal legs.
    a)  Set pressure at N2 regulator.
    b.  Set flow rate at rotameters.

7.  Cut on main breaker for starting switches.

8.  Cut on 4"0 unit bucket elevator at starter box.

9.  Cut on flue gas blower (FGB-1).
    a)  Drain possible condensate from blower.
    b)  Open valves near blower.
    c)  Close flue gas vaive at stack (should have been closed)
                             784
-------
     d)  Cut on blower at starter box.
     e)  Set air pressure for trunnion valve at 30 psig  (manual
         sta. rd. f+J 9.1) .
     f)  Set air pressure for manual station at 20 psig.
     g)  Set gas flow rate by adjusting inlet gas valve at manual
         station.

10.   Cut on exhaust blowers E-l and E-2 for 18"0 unit.

11.   Adjust pressure at gas outlet of 18"0 unit.
     a)  Close Valves EV-6-2 and open EV-6-1 and EV-6-3.
     b)  Adjust Valves EV-6-4 as necessary for -0.2 to 0.0 DP
         reading.

12.   Cut on vibrating feeder (CV-5) for 18"0 unit carbon
     discharge.
     a)  Cut on DPDT switch to probe control for CV-5.
     b)  Cut on at vibrator control box.


13.   Cut on automatic carbon ball valve feeder (CFC-3) to top
     stage of 4"0 unit with appropriate switch at panel
     board.


14.   Cut on cooling H20 to 4"0 unit carbon cooler.

15.   Cut on Kane gravimetric carbon feeder.
     a)  Cut on Breaker 4, Breaker Box # 1 (should be on).
     b)  Set air pressure at 40 psig at regulator.
     c)  Cut off air pressure at 35 psig at Kane unit.
     d)  Set carbon feed rate.

16.   Cut on vibrating feeder (CV-7) between Kane feeder and 18"0
     unit bucket elevator.

17.   Cut on 18"0 unit bucket elevator at starter box.

18.   When carbon flow at steady state, start system heat-up.

19.   S02 Sorber (18"0 Unit) Heat-up Procedure
     a)  Air Preheater Start-up
         1)  Cut on propane tanks to line pressure of about 35 psi
         2)  Open Valve 1.
         3)  Open Valve 2.
         4)  Cut on igniter.
         5)  Open Valve 3 (crack).
         6)  Open Valve 4 to desired pressure (*>^20 psig at
               3 ft./sec.  should be sufficient for 300°F).
                             785
-------
      b)   Cut  on  inlet gas line heaters.
          1)   Cut on Breakers 20 and 21, Breaker Box #  1;  and
               Breakers 1 and 2, Breaker Box # 3.
          2)   Set three Chromalox temperature controllers  on I.D,
               fan floor at 310°F.

      c)  Cut on water spray to standby.
         1)  Close H20 valve near column (Valve H-l) .
         2)  Open air valve near column (Valve H-2).
         3)  Cut on air on operating floor.
               a)  Set air pressure at regulator at 45 psig.
               b)  Set air flow rate at rotameter.
         4)  Open H20 bypass valve to sump (Valve H-3 on  I.D.
               fan floor near turborod heater).
         5)  Set thermostat at 150°F (on I.D.  fan floor).
         6)  Cut on H20 on operating floor.
               a)  Open H20 Valve H-4.
               b)  Cut on H20 pump.
               c)  Adjust manual bypass to the indicated  flow
                     rate.
         7)  Cut on Breaker 22,  Breaker Box # 1.

      d)  Cut on steam tracing to gas sample lines.

20.   Carbon Preconditioner (6"0 Unit Heat-up)
      a)  Cut on inlet gas heater.
         1)  Cut on starter box.
         2)  Set TIC-302 temperature controller at indicated
               temperature.

     b)  Cut on column heater.
         1)  Cut on Breakers 22 and 24, Breaker Box # 2.
         2)  Set TIC-303 temperature controller at indicated
               temperature.

     c)  Cut on steam tracing to off-gas line,  cyclone, and
         carbon filter.

21.  Sulfur Generator (8"0 Unit Heat-up)
     a)  Cut on inlet gas heater.
         1)  Cut on Breakers 14 and 16, Breaker Box # 2.
         2)  Set TIC-201 controller at indicated temperature.
     b)  Cut on column heaters.
         1)  Cut on Breakers 15,  17, 19, 21, 23 and 25, Breaker
               Box # 2.
         2)  Set Powerstats 204,  205 and 206 at indicated
               settings  indicated by AM 204, 205 and 206.
     c)  Cut on steam tracing to gas sample lines.
                             786
-------
22.   H2S Generator/Sulfur Stripper (4"0 Unit Heat-up)
     a)  Cut on power to controllers.
         1)  Cut on Breakers 7, 9, Breaker Box # 1.
         2)  Cut on heater power switch at panel board.

     b)  Cut on inlet gas heater.
         1)  Cut on Breaker 13, Breaker Box # 1.
         2.  Set TIC-106 controller at indicated temperature.

     c)  Cut on inlet gas plenum heater.
         1)  Cut on Breaker 14, Breaker Box # 1.
         2)  Set TIC-100 controller.

     d)  Cut on column heater.
         1)  Cut on Breakers 15, 16,  17,  and 18, Breaker Box # 1
         2)  Set TIC-101, -102, -103 and -104 controllers.

     e)  Cut on carbon preheater.
         1)  Cut on Breaker 19, Breaker Box # 1.
         2)  Set TIC-105 controller.

     f)  Cut on off-gas line and cyclone heater.
         1)  Cut on Breaker 2,  Breaker Box # 2.
         2)  Set powerstat to get indicated temperature.
 Shutdown Procedure

 1.   Shut off propane;  readjust orifice AP for 18"0 unit as neces-
     sary to maintain indicated velocity.

 2.   Cut off Breakers 13,  14,  15,  16,  17,  18 and 19, Breaker
     Box # 1; and cut off Breaker  2,  Breaker Box # 2.

 3.   Adjust rotameter R-5 as necessary to  maintain gas velocity
     in 4"0 unit.

 4.   Cut off'Breakers 22 and 24, Breaker Box 2;  adjust orifice
     AP for 6"0 unit as necessary  to  maintain gas velocity.  Cut
     off starter box for inlet gas heater  for 6"0 unit.

 5.   Cut off breakers 14,  15,  16,  17,  19,  21, 23 and 25, Breaker
     Box # 2.
                              787
-------
 6.  After all temperatures steady, near 100 F, cut  off  carbon
     flow.
     a)  Cut off Kane feeder.
     b)  Cut off bucket elevator.
     c)  Cut off CV-7.
     d)  Cut off FC-102 (15% flow to 4"0 unit).

 7.  Cut off Breakers 7 and 9, Breaker Box # 1; cut  off  heater
     power switch on panel board for 4"0 unit.

 8.  Cut off gas flow to 8"0 unit.
     a)  USL
     b)  LSL
     c)  column

 9.  Cut off 18"0 unit blowers.
     a)  Exhaust blower
     b)  Dust collector exhaust blower
     c)  Flue gas blower

10.  Cut off blower for 6"0 unit (preconditioner) .

11.  Cut off gas flow to 4"0 unit.
     a)  USL
     b)  LSL
     c)  Column

12.  Cut off main N£ supply.

13.  Cut off Breaker 12,  Breaker Box # 1;  cut off Breaker 33,
     Breaker Box # 2.
                              788
-------
         APPENDIX    B-5
 SAFETY PROGRAM FOR PILOT PLANT
OPERATION OF THE WESTVACO PROCESS
               789
-------
                                              SUMMARY
                                        EMERGENCY PROCEDURES
                                 HYDROGEN SULFIDE OR HYDROGEN RELEASE
HYDROGEN SULFIDE  RELEASE
     CATEGORY  I   -  LEAK IN EQUIPMENT OR GAS SUPPLY
           AT  THE INDICATION THAT H2S IS REACHING DANGEROUS CONCENTRATIONS:
                1.  DON AN ESCAPE MASK, PROCEED TO THE SAFETY EQUIPMENT AREAS AND DON A CANISTER MASK.
                2.  SHUT OFF THE H2S AT THE PANEL BOARD AND IN THE GAS HANDLING AREA.
                3.  IF THERE IS A LARGE LEAK IN THE GAS HANDLING AREA, DON A SCOTT AIR-PAK BEFORE
                   ENTERING TO SHUT IT OFF.   ,
                4.  NOTIFY THE SUPERVISOR.(NAMES AND PHONE NUMBERS POSTED AT PANEL BOARD).
                5.  CHECK H2S LEVELS IN THE GENERAL AREA.  IF THE H2S CONCENTRATION IS BETWEEN 170 -
                   300 PPM AND DOES NOT BEGIN TO DECREASE IN 10 - 15 MINUTES, SOUND THE H2S ALARM.
                   IF THE CONCENTRATION IS ABOVE 300 PPM SOUND THE ALARM IMMEDIATELY AND FOLLOW
                   STEPS 4 AND 5 IN CATEGORY II.
      CATEGORY II  -  PERSONNEL OVERCOME OR UNCONTROLLABLE LEAK
                1.  SOUND THE HaS ALARM.
                2.  DON ESCAPE MASK, GO TO SAFETY'CABINET AND DON CANISTER MASK AND EVACUATE TO UPWIND
                   POINT FROM GAS RELEASE.
                3.  IF PERSON IS OVERCOME AFTER PUTTING ON CANISTER MASK, REMOVE THE VICTIM TO AN
                   UPWIND POINT AND APPLY FIRST AID.
                4.  CALL FIRST AID tEXT. 200) AND REPORT EMERGENCY.
                5.  SUPPLY INFORMATION TO THE FIRST AID SQUAD UPON ARRIVAL.

HYDROGEN RELEASE
     CATEGORY  I   -  EQUIPMENT OR GAS AREA LEAK. .FIRE
                1.  SHUT OFF THE H2 (ALSO H2S IF FIRE) IN PANEL BOARD AND GAS HANDLING AREA.
                2.  IF THERE IS A FIRE, EXTINGUISH WITH A DRY CHEMICAL EXTINGUISHER.
                3.  NOTIFY THE SUPERVISOR.
                4.  TEST FOR FLAMMABLE LEVELS OF HZ AND  IF THEY EXIST SOUND THE ALARM AND FOLLOW THE
                   STEPS IN CATEGORY II, BELOW.
                5.  NOTIFY THE FIRE MARSHALL OF ANY FIRES THAT OCCUR AND ARE  EXTINGUISHED.
     CATEGORY  II   - EXPLOSION, UNCONTROLLABLE LEAK OR FIRE
                1.  SOUND THE H2 ALARM.
               2.  EVACUATE THE BUILDING TO UPWIND POINT.
               3.  IF FIRE OR EXPLOSION IS IN THE BUILDING, SHUT OFF THE HYDROGEN AND  HYDROGEN
                   SULFIDE IN THE GAS HANDLING AREA.
               4.  NOTIFY FIRST AID (EXT. 200) AND THE  FIRE BRIGADE  (EXT.  277).
               •5.  PROVIDE INFORMATION TO THE FIRST AID SQUAD AND  FIRE  BRIGADE UPON ARRIVAL.
                                              790
-------
                       TABLE OF CONTENTS

                                                            Page
SUMMARY - EMERGENCY PROCEDURES                              790

INTRODUCTION                                                792
    Description of Equipment and Location                   792

HYDROGEN SULFIDE                                            797
    Physical Properties                                     797
    Physiological Effects of Hydrogen Sulfide               797
    Responses to Various Concentrations of Hydrogen         798
      Sulfide
    Location and Operation of Regenerator Equipment         799
    Protective Measures for Operating Personnel             799
    Safety Procedures                                       800
    Precautions in Handling and Storage                     800
    Emergency Procedures                                    801
HYDROGEN                                                    803
    Physical Properties                                     803
    Location and Operation of Equipment                     803
    Protective Measures                                     803
    Safety Procedures                                       804
    Emergency Procedures                                    805
    First Aid                    -                           806

SULFUR DIOXIDE                                              807
    Physical Properties                                     807
    Location and Operation of Equipment                     807
    Protective Measures                                     808
    Precautions in Handling and Storage                     808
    Leak Detection                                          809
    First Aid Suggestions                                   809

NITRIC OXIDE                                                811
    Physical Properties                                     811
    Location and Operation of Equipment                     811
    Precautions in Handling and Storage                     812
    Leak Detection                                          813
    First Aid Suggestions                                   813
                               791
-------
                             INTRODUCTION
Pilot plant equipment is located in the area of No. 6 boiler to evaluate
the Westvaco Process for removal of S02 from flue gas with activated
carbon  and for regeneration of the carbon.  Three reactors, an 18 inch
diameter SOg sorber, a 4 inch diameter regenerator, and a 8 inch diameter
regenerator, along with associated feed and handling equipment, will be
used.   Instrumentation is located on a central panel board on the
operating floor level of No. 6 boiler.  Gases to be used in the study are
stored  in the gas handling area between the cooling tower and coal
storage hopper at the east end of the power plant.

At various times hydrogen sulfide, hydrogen, sulfur dioxide and nitric
oxide will be stored in the gas handling area and used in the reactors.
Hydrogen sulfide, sulfur dioxide and nitric oxide are toxic gases and
hydrogen is highly flammable, as is hydrogen sulfide.

Equipment, exhaust systems, and storage areas are designed to minimize
gas leakage into the air.  There always exists, however, the possibility
that gases will escape and the following program is designed to prepare
operators in case of accidental gas release.

All operators will participate in a training program.  Practice in the
program will continue until the operators respond automatically.  This
program will include:

     A.  Information on the Location and Operation of Equipment
     B.  Information on the Location and Practice in the Use of Gas
         Masks
     C.  Instructions Concerning the Alarm Systems, Various Hazardous
         Gas Detectors
     D.  Instruction on the Proper Evacuation Routes
     E.  Location(s) of Telephone(s) To Use in Case of Accidents
     F.  Instruction on First Aid Procedures
     G.  Instructions on the Proper Handling of Cylinders.

Description of Equipment and Location

The pilot plant used to study the development of the Westvaco Process  is
located in the northeast corner of the boiler house near No. 6 boiler  as
shown on the plot plan on the following page.  The pilot plant treats  a
slipstream of the stack gas from No. 6 boiler.  Regeneration equipment in
the same location is supplied by gases from a storage area located between

                                   792
-------
LO
                                                           HESTVACO SO-,  PILOT  PLANT
                                                                        . L.

                                            LOCATIONS  OF MANUAL  ALAR I! S  AND EMERGENCY  EQUIP I-'t NT

1
MECHANICAL
SHOPS 3LDG.
FIRST AID
"STATION


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the coal storage hopper and the cooling tower as shown.  The equipment
consists of an 18 inch SC>2 sorber and k inch diameter and 6 inch
diameter regenerators.  The equipment extends from the operating floor
to approximately the 105 ft. level.  A panel board located on the
operating floor is used to monitor and control the equipment.
Associated materials handling equipment is also in the area.

The following safety items are associated with the equipment:

     1.  General Alarm
         Alarm horns and flashing lights are located at the S02 panel
         board, in the gas storage area and near the panel board for No.
         6 boiler as indicated in the plot plan drawing.  The alarms can
         be activated by push buttons on the panel board or in the gas
         storage area.  The horns can be silenced by buttons at each
         location, but the flashing lights can only be deactivated by a
         button at the S02 panel board.

     2.  Automatic Alarms
         Several automatic alarms are incorporated into the system.  When
         actuated a horn sounds and a master alarm light comes on.  In
         addition a labeled pilot light is actuated.

         a)  Exhaust Gas Flow
             If the exhaust flow rate drops below a pre-set value all
             gases except nitrogen are shut off and an alarm is sounded.
             All gases can also be turned off manually by a switch on
             the panel board.  A steam purge can be put into the equipment
             by turning a switch on the panel board.  If the shroud
             exhaust flow drops below a pre-set value the alarm system is
             actuated.
         b)  High Temperature
             In case of high temperature in the regenerator or carbon
             cooler, an alarm is sounded and a light comes on at the
             panel board.  All heaters can be turned off by a switch on
             the panel board.
         c)  Low Seal Leg Flow
             If there is low purge gas flow in the upper or lower  seaj.
             legs which could allow hydrogen leakage, an alarm sounds
             and a light comes on at the panel board.

         d)  High H2S Flow
             If there is high flow in the H2S line the alarm system is
             actuated.
                               795
-------
3.   Safety Equipment

    Canister gas  masks,  oxygen  cylinders,  and manual resuscitators
    are located in cabinets  on  the  operating floor near the power
    plant office  and  on  the  ground  floor adjacent  to the southeast
    entry door.   A Scott Air-Pak  is located in the ground floor
    cabinet.

1*.   Various Detectors for  Hazardous Gases

    Portable leak, combustibles,  H2S,  SC>2  and NO detectors are
    centrally located in the panel  board area.   The detectors are
    discussed later as they  relate  to  particular gases and the
    operation of  these instruments  are described in Appendix II.

5.   18 Inch S02 Sorber

    The 18 inch SC>2 sorber treats flue gas from Ho. 6 boiler stack.
    The unit is equipped with an  exhaust system to dilute and expel
    to the outside the off gases  from  the  unit.
6.  8" 0 Sulfur Generator

    The 8 inch sulfur generator will use  hydrogen sulfide laden
    reactant gas.   It is equipped with an exhaust system tied to
    the suction side of No.  6 boiler I.D.  fan.
7.  U Inch Regenevator

    The four inch regenerator will use both hydrogen and hydrogen
    sulfide laden reactant gas.  It is equipped with an exhaust
    system tied to the suction side of No. 6 boiler I.D. fan.  It
    is equipped with an exhaust  hood  to pick up, dilute and expel
    to the outside any gases leaking from the equipment.

8.  Gas Storage Area

    The gas storage area has a concrete area for gas storage and
    handling.  The hydrogen sulfide and hydrogen lines cannot be
    used until lock valves are opened with keys kept at the panel
    board for No. 6 boiler when not in use.  The H2S line has a
    flow switch which shuts the gas off in case of excess flow and
    a 75 psig rupture disc and vent line which exhausts into the
    cooling tower.
                          796
-------
                           HYDROGEN SULFIDE
Physical Properties

The major hazards in the using of hydrogen sulfide arise from its
toxicity and flammability.  Therefore, the gas should be used in a well-
ventilated area.  Oxygen, flames, sparks, and sources of excessive heat
should be kept out of the area in which H2S is stored and used.

     Toxicity

Hydrogen sulfide is a gas that is extremely toxic at low concentrations.
The gas is colorless and has a characteristic rotten-egg odor at rela-
tively low concentrations (l - 500 ppm).  At higher concentrations  the
odor is sickening-sweet.  Although the odor of hydrogen sulfide can be
detected at very small amounts, the sense of smell is reduced by con-
tinued exposure.  Above 100 ppm H2S rapidly paralyzes the olfactory
nerve so that the gas is no longer smelled.

     Flammability

H2S is flammable for the concentration range of U.3 to ^5%.   A mixture
of two volumes H2S and 3 volumes oxygen will explode violently when
ignited.
Physiological Effects of Hydrogen Sulfide

The principal mode of entry of H2S into the body is through the lungs.
Skin contact even to high concentrations is not considered significant.
There are three principal effects from exposure to H2S:

     l)  The irritant action of relatively high concentrations on lung
         tissue
     2)  An irritant effect on the eyes which may result from repeated
         exposures to low concentrations, as well as short exposures to
         high concentrations
     3)  The most significant effect—respiratory paralysis from expo-
         sure to high concentrations.
                              797
-------
     Symptoms

Symptoms that occur because of exposure to hydrogen slalfide include:
l) headache, 2) dizziness, 3) nausea, k) dryness and sensation of pain
of the nose and throat, and 5) coughing.  These symptoms occur with expo-
sure at low (500 ppm) concentrations.  At higher concentrations, expo-
sure rapidly produces unconsciousness, cessation of respiration, and
death.  It should be noted that the majority of accidents from H2S expo-
sure resulted when the victim failed to follow recommended rules and
procedures.  Also, H2S and prior consumption of alcohol are a dangerous
combination.  Cases of exposure have shown that it took very little
exposure to the gas to overcome a person who had consumed alcohol l6 -
2U hours before exposure.
Responses to Various Concentrations of Hydrogen Sulfide

The responses to various concentrations of H2S in the atmosphere are as
follows:

     1.  The maximum allowable concentration for prolonged exposure (8
         hours) is 10 ppm .    Slight irritation of the eyes may
         occur at concentrations as low as 10 ppm.

     2.  The minimum concentration for lung irritation is greater than
         20 ppm.

     3.  The maximum concentration for 1 hour without serious conse-
         quences is 170 - 300 ppm.

     U.  A concentration of 300 - 500 ppm is dangerous after 1/2 to 1
         hour exposure, and

     5.  Concentrations greater than 500 ppm rapidly produce unconscious-
         ness, cessation of respiration and death.

Present information indicates that hydrogen sulfide is non-cumulative in
the body.
                              798
-------
Location and Operation of Regenerator Equipment

     Regenerator Unit

The pilot equipment is located in the northeast corner of the building
housing No. 6 boiler and extends from the operating floor (291 level)
to the 115 ft. level.  The area is shaded on the attached plot plan
drawing on page 2.

     Hydrogen Sulfide Cylinders

Hydrogen sulfide cylinders are located in the gas handling area adjacent
to the cooling tower and coal storage hopper.  The area is shaded on the
plot plan  on page  2.  Hydrogen sulfide in amounts up to 1500 - 2,000
Ibs. will be stored in this area.

     Operation of Equipment

The equipment will be operated both on a 16 hrs./day and on an around-the-
clock basis.  At least two operators will be on duty during each shift.
In addition, a supervisor will be in the general area during operation.
Protective Measures for Operating Personnel

Because of the possibility of H2S release and the resulting hazards,
several safety precautions and devices will be used for personnel
protection.

     Safety Devices

1.  Warning Signs:  Signs will be placed at the following locations when
    H2S is being used or produced:  a) at entrance points to  the pilot
    area, b) gas handling area, c) on hazardous gas lines outside  the
    building.
2.  Portable Detectors:  Portable detectors for H2S, explosive gases and
    point leak testing will be located in the panel board area.  In addi-
    tion, there will be a permanent H2S detector and alarm in the panel
    board area.

3.  Personal Safety Equipment:  Each person working in the area will have
    on his person:  a) a belt clipped escape mask, b) a H2_S detector kit.
    One person per shift working in the area will have a lead acetate
    badge which will change color upon exposure to H2S.

k.  General Safety Equipment:  There will  be  general safety equipment
    cabinets located in marked areas on the operating floor near the
    office and on the ground floor near the liquid nitrogen cylinders.

                              799
-------
    These will  contain:  a) 5 Universal gas masks, b) a Scott Air-Pak
    self-contained breathing apparatus, c) 2 oxygen masks  and It oxygen
    cylinders,  d) a hand resuscitator.

5.  Exhaust Systems;  All equipment is equipped with exhaust systems to
    dilute  and  expel toxic gases.  Exhaust lines which carry H2S have
    alarms  to warn of low gas flows.  In addition, the 1* inch unit  and
    flanged points on the carbon and gas heaters are equipped with  hoods
    to pick up  and exhaust any gas which might escape.

6.  Ventilation;  Ventilation is provided in the building  by air movement
    to the  combustion air inlet for the boiler which is inside  the
    building.  Leak tight equipment and exhaust systems are being used
    to prevent  H2S buildup rather than ventilation.
Safety Procedures

A.  "Buddy System"  -  One person  is never to work alone when H2S  is
    being used or produced in equipment.  Also, the two operators  are not
    to work side by side on equipment  containing HgS unless  a third
    person is present.   This system will be used so that if  one man is
    overcome, he can be removed from the contaminated  area by his  buddy.

B,  One man on each shift will be  responsible for placing  the warning
    signs on equipment, in entrances,  etc. before beginning  operation. At
    the end of operation, one man  on that shift will be responsible for
    removing and storing the warning signs.  If the signs  were  in  position
    at all times, whether the equipment was operating  or not, other
    personnel in the area would soon begin to disregard the  signs.

C.  All operators are to read and  understand all aspects of  the safety
    program.

D.  If any type of accident or equipment failure occurs, the operator
    should report this to his supervisor.  Even if the incident is an
    equipment failure which the operator can correct,  this should be
    reported to the supervisor.
Precautions in Handling and Storage of Hydrogen Sulfide

The following general rules should be followed in the handling and
storage of hydrogen sulfide:
                              800
-------
     1.  Never  drop  cylinders  or permit them to strike each other
         violently.

     2.  Cylinders should be assigned  a definite area for storage.  The
         area should be  dry, cool, well-ventilated, and preferably fire
         resistant.

     3.  The  valve protection  cap should be  left in place until the
         cylinder has been  secured against a wall or bench, and is ready
         to be  used.

     H.  Avoid  dragging,  rolling, or sliding cylinders, even for a short
         distance.   They  should be moved by  using a suitable hand truck.

     5.  Never  tamper with  safety devices in valves or cylinders.

     6.  No part of  a cylinder should be subjected to a temperature
         higher than 125°F.

     7.  All  cylinders should be secured with chains when being used or
         stored.
Emergency Procedures

     Equipment or Gas Supply Leakage

1.  At the indication (detector checking or lead acetate paper turns
    black) that H2S has reached a dangerous level, put on the escape
    mask, EVACUATE the area and DO NOT RE-ENTER without a canister  type
    gas mask.

2. . Put on a canister type gas mask and shut off the H2S and H2 supply
    in the gas handling area.

3.  Call supervisor.  Use the telephone located in the power plant  office.

U.  Before re-entering contaminated area, put on a MSA Universal gas  mask.

5.  Check concentration with MSA Universal detector in the following
    areas:  a) panel board area, b) other platform levels of equipment.
    If concentrations of 150 - 300 ppm exist and do not decrease in 10 -
    15 minutes or if concentrations greater than 300 ppm exist, follow
    Steps 1 - 6 on the following page.
                               801
-------
     Overexposure or Uncontrollable Leak

If one person is over-exposed or there  is uncontrollable  leakage:

     1.  Sound the HgS alarm.

     2.  Don the escape mask and EVACUATE the area IMMEDIATELY.

     3.  Put on gas mask in the  safety  cabinets located near the office
         on the operating floor  or  near the liquid nitrogen tanks  on the
         ground floor.

     h.  Remove victim upwind  of H£S leak and apply first aid.

     5.  If breathing has stopped,  artificial respiration should be
         applied.

     6.  Call the  First Aid Squad (Ext.  200) and/or Fire Brigade (Ext.  277)
         and provide information upon arrival.
                             802
-------
                                HYDROGEN
Physical Properties

Hydrogen is  colorless and odorless and the lightest gas known.  It is
non-toxic but can act as an asphyxiant by displacing the necessary
amounts of air required to support life.

      Flammability

The  major hazard associated with the use  of hydrogen is its flammability.
Hydrogen is  flammable over the range of U.O - 75 volume % in air.  The
auto-ignition temperature is 1085°F.  Hydrogen is particularly subject
to leakage and will leak at about twice the rate of nitrogen and oxygen.
Hydrogen diffuses very rapidly to non-explosive mixtures.  For example,
if 300 Ibs.  of liquid hydrogen were spilled in an unconfined area the
   50,000 cubic feet of gaseous hydrogen produced would diffuse to a non-
explosive mixture in about one minute. Hydrogen flames are invisible
except in near darkness.  Only the impurities in the flame are visible.
Dirt or the  dry powder from fire extinguishers have been used to estab-
lish the presence of hydrogen flames.  The material will glow in the
flame.
 Location and Operation of Equipment

 Hydrogen will be used in the k inch diameter regenerator to study H2S
.generation with sulfur loaded carbon.   The  equipment will be operated
 on both an around-the-clock and 16 hrs./day basis.  Hydrogen is
 supplied from the gas handling area where up to about 5,000 - 6,000 cu.
 ft.  of hydrogen will be stored.
Protective Measures

The  following are provided to minimize  the possibility for or warn of
fires:

     1.  Exhaust  Hood and Lines

         An  exhaust  hood draws air across the reactor proper and flanged
         points of the gas and carbon heater to  dilute any hydrogen
         which may leak below the  explosive limit  and exhaust it.  Off
         gases from  the unit  are diluted below the explosive limit and
         expelled to the outside.
                               803
-------
     2.  Explosion Proof Fittings

         Electrical fitting within a five  foot  radius  of heated parts
         of the U inch diameter regenerator  are explosion proof.

     3.  Combustible Gas Detector

         A portable combustible gas detector is supplied to test for
         suspected leakage of hydrogen that  may be  forming combustible
         mixtures.

     U.  Leak Detector

         A portable thermal conductivity leak detector can be  used to
         locate leakage of hydrogen that may be at  levels below the
         lover combustible level.
Safety Procedures

The following specific rules apply when handling hydrogen:

     1.  Never use cylinders of hydrogen in areas where  flames,  exces-
         sive heat, or sparks may occur.

     2.  Utilize only explosion-proof equipment  and spark  proof tools
         in areas where hydrogen is handled.

     3.  Ground all equipment and lines used with hydrogen.

     k.  Never use a flame to detect hydrogen leaks—use soapy water.

     5.  Do not store reserve stocks of hydrogen with cylinders  contain-
         ing oxygen, other highly oxidizing or combustible  materials.

The following general rules should also be followed  in the  handling and
storage of hydrogen:

     1.  Never drop cylinders or permit them to strike each other
         violently.

     2.  Cylinders should be assigned a definite area for storage.  The
         area should be dry, cool, well-ventilated,  and  preferabl^ fire-
         resistant.  Keep cylinders protected from excessive temperature
         rise by storing them away from radiators or other sources of
         heat.  Storage conditions should comply with local and state
         regulations.
                              804
-------
     3.   Cylinders may be stored in the open,  but  in such cases should be
         protected against the extremes of weather and from the dampness
         of the ground to prevent rusting.

     U.   The valve protection cap should be left in place until the
         cylinder has been secured against a wall  or bench, or placed in
         a cylinder stand, and is ready to be  used.

     5.   Avoid dragging, rolling, or sliding cylinders, even for a short
         distance.  They should be moved by using  a suitable hand truck.

     6.   Never tamper with safety devices in valves  or cylinders.

     7.   When returning empty cylinders, close the valve before shipment,
         leaving some positive pressure in the cylinder.  Replace any
         valve outlet and protective caps originally shipped with the
         cylinder.  Mark or label the cylinder EMPTY.  Never store full
         and empty cylinders together.

     8.   Wo part of a cylinder should be subjected to a temperature
         higher than 125°F.  A flame should never  be permitted to come
         in contact with any part of a compressed  gas cylinder.

     9.   Do not place cylinders where they may become part of an electric
         circuit.  When electric welding, precautions must be taken to
         prevent striking an arc against a cylinder.
Emergency Procedures

1.  At the indication that hydrogen is leaking into the building  or that
    a fire has started, a) shut off the hydrogen, b) turn off the heaters,
    c) leave the nitrogen purge on the equipment, d) if the fire  is in the
    equipment turn on the steam purge, e) extinguish any fires with a dr£
    chemical fire extinguisher.  If the fire cannot be extinguished notify
    the Fire Brigade.  After a fire is extinguished the Fire Marshall
   •should be notified.  Notify the supervisor in charge.

2.  After any fire or leak detection do not turn the hydrogen back on
    until cleared with the supervising engineer.

3.  In case of an explosion, uncontrollable fire, or ruptured cylinders,

    a)  Sound the manual alarm.
    b)  Evacuate the area immediately.
    c)  Call the Fire Brigade (Ext. 277).
                                     805
-------
    d)  Shut off all gases  in the  gas handling area if the  explosion or
        fire is in the building.   Leave the nitrogen purge  on.
    e)  Provide information and assistance to the Fire Brigade  upon
        fl.T'T*'! TTftT
    f)  When it'is safe to  enter the area, shut off the heaters and carbon
        flow.

I*.  If a person is injured  apply first aid to prevent shock and control
    bleeding.
First Aid

In case of an accident and injury:

     1.  Call for First Aid Squad - Phone 200.

     2.  Control the bleeding.   Apply in order  as  necessary:

         a)  Direct pressure over wound
         b)  Pressure point
             l)  inner side of  upper arm
             2)  heel of hand against groin
         c)  Tourniquet just above wound.  Apply an information note to the
             victim stating nature of wound (laceration,  fracture, puncture
             wound, etc.), time applied, and your  name.  Tourniquet should
             only be removed by a Medical Dept. representative.

     3.  Start the breathing.   Apply mouth-to-mouth resuscitation:

         a)  Move injured to clean-air atmosphere.
         b)  Remove obstructions in mouth.  Clear  airway.
         c)  Tilt head back and jut chin.
         d)  Seal the nose.
         e)  Cover mouth with tight seal and breathe.
         f)  Rate of breathing  is determined by rate of ability of injured
             to expel air.
         g)  Continue mouth-to-mouth resuscitation until help arrives.
             Do not stop until  relieved by another first aider or a Medical
             Department representative.

     **.  Treat for -possible shock.

         a)  Keep injured lying down and calm.
         b)  Keep from losing body heat*—not too  hot or too cool.
         c)  Possibly elevate to aid circulation.
                                     806
-------
                            SULFUR DIOXIDE
Physical Properties

Sulfur dioxide is a highly irritating, non-flammable, colorless at room
temperature and atmospheric pressure.  It  is  a little more than twice
as heavy as air.  It is soluble  in water to form  a weak solution of
sulfurous acid.  It is readily liquefied and  is shipped in steel
cylinders as a liquefied gas under its own vapor  pressure of about 35
psig at 70°F.

     Toxicity

Sulfur dioxide is a highly irritating gas  in  the  vapor form, readily
detectable in concentrations of  3-5 ppm and providing ample warning of
its presence.  In higher concentrations, the  severely irritating effect
of the gas makes it unlikely that any person  would be able to remain in
such a contaminated atmosphere unless he were unconscious or trapped.

Liquid sulfur dioxide may cause  skin and eye  burns upon contact with
these tissues which results from the freezing effect of the liquid on
the skin or eyes.

Acute exposure to sulfur dioxide has the following effects:  8-12 ppm
causes throat irritation, coughing, constriction  of the chest, tearing,
and smarting of the eyes; 150 ppm causes extreme  irritation and can be
tolerated only for a few minutes; 500 ppm  is  so acutely irritating that
it causes a sense of suffocation.  There are  no known systematic effects
of acute exposure to sulfur dioxide.  The  generally accepted maximum
allowable concentration of sulfur dioxide  for an  8 hour daily exposure
is 10 ppm.

No chronic systematic effects have been observed  in workers exposed
daily to allowable concentrations of sulfur dioxide.
Location and Operation of Equipment

The 18 inch adsorber is used to study S02 sorption with active carbon.
Flue gas from the stack of No. 6 boiler which normally contains 1,000 -
2,000 ppm S02 is used.  In addition S02 may be added from cylinders in
the gas handling area.  The adsorber is equipped with afl exhaust system
to dilute and expel off gases outside the building.
                                     807
-------
Protective Measures

The irritating effect of sulfur dioxide is  readily detectable and pro-
vides ample warning of its presence.   In addition a Universal type
portable detector is provided to test for possible leakage or buildup of
sulfur dioxide.
Precautions in Handling and Storage

The following general rules should be observed in the handling and
storage of sulfur dioxide:

     1.  Never drop cylinders or permit them to strike  each other
         violently.

     2.  Cylinders should be assigned a definite area for  storage.   The
         area should be dry, cool, well-ventilated,  and preferably
         fire-resistant.  Keep cylinders protected from excessive tempera-
         ture rise by storing them away from radiators  or  other sources
         of heat.  Storage conditions should comply  with local and state
         regulations.

     3.  Cylinders may be stored in the open, but in such  cases should
         be protected against extremes of weather and from the dampness
         of the ground to prevent rusting.  During the  summer, cylinders
         stored in the open should be shaded against the continuous
         direct rays of the sun in those localities  where  extreme
         temperatures prevail.

     U.  The valve protection cap should be left in  place  until the
         cylinder has been secured against a wall or bench, or placed in
         a cylinder stand, and is ready to be used.

     5.  Avoid dragging, rolling, or sliding cylinders, even for a short
         distance.  They should be moved by means of a  suitable hand
         truck.

     6.  Never tamper with safety devices in valves  or  cylinders.

     7.  When returning empty cylinders, close the valve before shipment,
         leaving some positive pressure in the cylinder.  Replace any
         valve outlet and protective caps originally shipped with the
         cylinder.  Mark or label the cylinder EMPTY.   Do  not store
         full and empty cylinders together.
                                    808
-------
      8.   No part of a cylinder should be subjected to  a temperature
          higher than 125°P.  Temperatures in excess of 125°F may cause
          a cylinder to become liquid full resulting in excessive hydro-
          static pressure buildup.  Never permit  a flame to come in con-
          tact with any part of a compressed gas  cylinder.

      9.   Before using, read all label information and  data sheets
          associated with the use of sulfur dioxide.

     10.   Suckback may cause a violent reaction within  the cylinder, and
          may leak to the formation of extremely  corrosive conditions;
          therefore, to prevent suckback, a check valve, vacuum break,
          or trap should be employed when using sulfur  dioxide.

     11.   Contents should be determined by weight, since the cylinder
          pressure will remain constant as long as liquid sulfur dioxide
          remains in the cylinder.
 Leak Detection

 Leaks of sulfur dioxide in lines or equipment may be  located by passing
 a squeeze bottle of aqueous ammonia over sites of suspected leaks; dense
 white fumes will be formed near the leak.  Leaks  may  be  less easily
 located by appling oil or soapy water solution to joints; leaks will be
 evident by bubble formation.
First Aid Suggestions

 Call First  Aid (Ext. 200) immediately for anyone who has  had  contact with
 liquid sulfur dioxide or has been exposed to excessive concentrations of
 the gas.  Prior to the physician's arrival, first aid should  be  started
 at once.  The first aid suggestions presented below are believed to be
 common practice in industry.  Their adoption in any specific  case  should
be subject  to the prior endorsement of a competent medical advisor.

     Skin Contact

On skin contact with liquid  sulfur dioxide,  use  an emergency  safety shower
at once.  Clothing  and  shoes  contaminated with sulfur  dioxide should be
removed under the shower.  Sulfur  dioxide should be washed off with very
large quantities of water.  Wash skin  areas  with large quantities  of soap
and water.  Do not  apply  salves or ointments to  chemical burns for 2k
hours.
                                      809
-------
     Eye Contact

If liquid sulfur has entered the eye,  they should be washed promptly
with copius quantities of water for at least  15  minutes.   Chemical neu-
tralizers are not advisable.  It is advisable to irrigate the eyes
gently with water at room temperature  in order to minimize additional
pain and discomfort.  Refer at once to a physician,  preferably an eye
specialist.

     Inhalation

On exposure to excessive concentrations of gaseous sulfur dioxide, the
victim must be carried at once to an uncontaminated  atmosphere and
effective artificial respiration started immediately if breathing has
ceased.  Oxygen (100$) should be administered (by trained personnel
only) as soon as possible after a severe exposure, preferably against a
positive exhalation pressure of 1.25 inches of water.   Oxygen inhala-
tion must be continued as long as necessary to maintain the normal color
of the skin and mucous membranes.  In  cases of severe  exposure,  the
patient should breathe 100$ oxygen under positive exhalation pressures
for 0.5 hour periods every hour for at least  3 hours.   If there  are no
signs of lung congestion at the end of this period,  and if the breathing
is easy and the color is good, oxygen  inhalation may be discontinued.
Throughout this time, the patient should be kept comfortably warm, but
not hot.
                              810
-------
                             NITRIC OXIDE
Physical Properties

Nitric oxide is a colorless, toxic, non-flammable gas, rapidly oxidized
by the oxygen of the air to nitrogen dioxide.  It is shipped in
cylinders as a non-liquefied gas at a pressure of 500 psig at 70°F.

     Toxicity

Nitric oxide is an extremely toxic gas.  It is rapidly converted by  the
oxygen of the air to nitrogen dioxide  (N02).  Thus, in most cases of
exposure to nitric oxide, the individual is being actually exposed to
N02.  The recommended  (American Conference of Governmental Industrial
Hygienists) maximum acceptable concentration of N02 in air is 5 ppm.

The greatest hazard of exposure to N02 comes from the fact that its
serious effects are not felt until several hours after the exposure  in
spite of the fact that dangerous amounts may be breathed before any
real discomfort occurs.  Edema may develop within 6 - 2U hours after
such exposure.  Concentrations of 100 - 150 ppm are dangerous for expo-
sures of 30 - 60 minutes and concentrations of 200 - TOO ppm may be
fatal after even very  short exposures.

Chronic exposure to low concentrations may cause chronic irritation  of
the respiratory tract, with cough, headache, loss of weight, loss of
appetite, dypepsia, corrosion of the teeth, and gradual loss of strength.
Location and Operation of Equipment

Nitric oxide is present at concentrations of about 150 ppm in the flue
gas from No. 6 boiler used in the 18 inch S02 sorber.  Occasionally a
cylinder of nitric oxide may be used in the building and will be marked.

     Detectors

The Universal type portable gas detector can be used to test for
suspected concentrations of nitric oxide.
                               811
-------
Precautions in Handling and Storage

1.  Nitric oxide should be handled only in a well-ventilated area,  pre-
    ferably a hood with forced ventilation.

2.  Self-contained breathing apparatus  should be  available  in convenient
    locations in emergencies.

3.  Areas in which nitric oxide is being handled  should be  provided with
    enough exits to permit personnel to leave quickly in  case of trouble.

U.  Personnel should have available for immediate use gas masks  with
    Universal canisters (Type N, colored red) for emergencies.   These
    canisters are satisfactory only for short exposures (about 5 minutes
    for 2% concentration of N02» 26 minutes  for concentrations of 0.5$)
    and should be changed on an exact time schedule.

5.  Air contamination should be avoided in high pressure  reactions  of
    nitric oxide with organic compounds.  Air contamination would lead to
    the formation of nitrogen dioxide which  could cause an  ignition or
    detonation.

The following general rules should apply in  the handling  and storage of
nitric oxide:

     1.  Never drop cylinders or permit them to strike each other
         violently.

     2.  Cylinders should be assigned a, definite  area for storage.  The
         area should be dry, cool, well-ventilated, and preferably
         fire-resistant.  Keep cylinders protected from excessive
         temperature rise by storing them away from radiators and other
         sources of heat.  Storage conditions should  comply with local
         and state regulations.

     3.  Cylinders may be stored in the open but  in such  cases should  be
         protected against extremes of  weather and from the dampness of
         the ground to prevent rusting.  During the summer, cylinders
         stored in the open should be shaded against  the  continuous
         direct rays of the sun in those localities where extreme
         temperatures prevail.

     k.  The valve protection cap should be  left  in place until  the
         cylinder has been secured against a wan or  bench, or placed
         in a cylinder stand, and is ready to be  used.
                              812
-------
     5.  Avoid dragging, rolling, or sliding cylinders, even for a
         short distance.  They should be moved by means of a suitable
         hand truck.

     6.  When returning empty cylinders, close the valve before ship-
         ment, leaving some positive pressure in the cylinder.   Mark or
         label the cylinder EMPTY.  Do not store full and empty cylinders
         together.

Leak Detection

Small leaks of nitric oxide in lines or equipment may be detected by
means of wet blue litmus paper.  Sites of large leaks of nitric oxide
are also detectable by the formation of reddish-brown W02 where nitric
oxide contacts the atmosphere.
First Aid Suggestions

Anyone exposed to dangerous concentrations of nitric oxide (rapidly con-
verted to NC>2 by the oxygen of the air) or overcome by gas should be
placed immediately in the care of a physician.  Prior to the physician's
arrival, first aid should be started.  Those presented below are
believed to be common practice in industry.  Their adoption in any
specific case should be subject to the prior endorsement of a competent
medical advisor.

     1.  Persons suspected of exposure to dangerous concentrations of the
         gas should be given bed rest for 2k hours and kept under
         observation during this period because of the dangers of develop-
         ing edema.

     2.  Anyone suffering from nitric oxide poisoning should be given
         100$ oxygen if breathing has not stopped or 100$ oxygen with
         artificial respiration, manual or otherwise, if breathing has
         stopped.  No one who has been exposed to nitric oxide should be
         allowed to move until permitted to do so by the attending
         physician.

     3.  If the person collapses after exposure, he should be moved to
         fresh air and kept warm.  The victim should.be laid face down
         with his head and chest lower than his hips to improve drainage
         of fluid from the lungs.  The body can be inclined to about a
         15 or 20 degree angle.  Artificial respiration should be started
         right away.  If possible, oxygen should be administered simul-
         taneously with an inhalator or resuscitator.
                                813
-------
4.  The chances of developing edema will be considerably reduced
    if oxygen is administered with an exhalation back-pressure  of
    2-2.5 inches of water.  If the oxygen is bubbled through
    ethyl alcohol as  it is administered, any frothing likely  in
    the lungs will be lessened.

5-  If a person exposed to nitric oxide commences to cough, has
    difficulty breathing, or feels slightly fatigued, he should
    be given oxygen immediately.  A physician should be called.
    If it is necessary to move the victim, he should be carried on
    a stretcher.   In  no case should he be allowed activity.
                        814
-------
              APPENDIX



             SECTION C



DETAILS OF PROCESS COMMERCIALIZATION
                  815
-------
                    APPENDIX C-l


1,000 MW UTILITY BOILER FLUE GAS CLEAN-UP - DETAILED
                ECONOMIC EVALUATION
                       816
-------
                   MAIN PLANT ITEMS FOR FACTOR  ESTIMATE
                                  (MPI)
           Designation
Adsorber
Regenerator (S Generator)
Regenerator (H2S Gen./S Stripper)
Carbon Cooler
Blowers

Electric Motors

Heat Exchangers


Fired Healers
Carbon Storage
Sulfur Storage
Cyclone Collectors

Bucket Elevators
Belt Conveyors
Shift Reactor
                MPI
                MPI
Unit Cost
$505,000
$ 94,800
$181,000
$ 29.80C
$109,500
$ 47,000
$ 4,000
$ 96,000
$ 9,600
$ 350
$ 14,000
$ 11,200
$ 11,200
$ 11,200
$ 19,000
$ 24,400
$ 50,000
$111,000
$ 16,000
$ 8,200
$ 21,600
$ 8,230
$ 14,500
$ 15,700
$ 14,900
$ 14,000
$ 5,000
$ 12,300
$ 11,800
$ 2,300 .
$ 4,700
$ 36,500
; in 1974 =
; in 1958 =
No. Req'd.
4
4
4
4
4
4
12
4
4
12
4
4
4
4
4
4
4
4
4
4
8
4
2
4
4
2
2
2
2
4
4
_A
138
$43,950
$27,800
Total Cost
$2,020,000
379,200
724,000
119,200
438,000
188,000
48,000
384,000
38,400
4,200
56,000
44,800
44,800
44,800
76,CCC
97,600
200,000
444,000
64,000
32,800
172,800
32,900
29,000
62,800
59,600
28,000
10,000
24,600
23,600
9,200
18,800
146,000
$6,065,100


                             817
-------
                             BATTERY LIMIT FACTOR ESTIMATE
TITLE:  WESTVACO S02 RECOVERY "PROCESS  -"
        BOILER FLUE GAS CLEAN-UP.
                                              MW UTILITY
    Number of MPI's
         134
 Average Cost  of MPI's
  191)8
   229
                                   1974
                                   362
in 1958 -""$27,^00
MPI  (Main Plant  Items) - See Separate List
MUr  (Miscellaneous Unlisted Equipment)
                                           DATE:  August  20, 1974
                                                                 Factor
                                                                 Est. 20%
Estimated
   Cost
                                                       $ 6,065,100
                                                         1,213.000 |
                                                         7,278,100
 Basic Equipment  (MPI  + MUE)
 Field Erection  of
 Basic Equipment
 Equipment  Foundations
 & Structural  Supports
 Piping
 Insulation  -  Equipment
            - Piping
 Electrical
 Instrumentation
 Miscellaneous
 Buildings
   Architectural
   Structural
 Building Services
 (%  of Arch'l ft Struct.)
 Compressed Air
 Electrical Lighting
 Sprinklers
 Plumbing
 Heating
 Vent  & Air Cond.
 Total Services
     High  -  Large  Pet.  of Equip.
     Involving Field Labor,  Large
    _Equij>ment	
     High  Predominance  of Mild  Steel
     Equip.,  Large Fans,  Large _F.gujp_._
                                                                   14
    High  -  Gas  Handling  Significant
    Aint.  of Large  Ductwork	
                                                                   34
     High  -  Significant Lagging
     Regen.  &  Shift  Reaction  at High
     Temperature
     High  -  Significant  Piping,  High
     Temperature
     Mild  Steel
     Solids
                                      Equip., Heavy Drives,
                           Avq. Instrumentation Required,
                                                                   12
     Large  Process, Top  of  Range
     Open A1 r ~P~1 ant wi th Mi nor
     Buildings - Use of Middle of
   -Range
     Low Amount of Building
     Services  - Open Air
       5
       9

       1
       2
       0
     IT
                                                                    1.4
 TOTAL FACTORED ITEMS
                                                                  101
 Direct Cost of Adsorber-Regenerator
 BatteryLimit (F.xcl. Taxes and jat.)	

 Addn'l Battery Limit Items
   Carbon Feeder,  Inert  fifl<; Gpnerator Gasifier, Gasifier
    Scrubber, Fired Gas Heaters & Flue Gas Ductwork

TOTAL DIRECT COST - BATTERY LIMIT
                                                         7,350,900
                                                        14,629,000
                                                         5,611,800


                                                       $20,240,800
                                      818
-------
                   SUMMARY  SHEET FOR  FACTOR  ESTIMATING
TITLE:  WESTVACO S02 RECOVERY PROCESS	
	1.000 MW UTTLfTY BOILER FLUE GAS CLEAN-UP
DATE:   August 20,  1974
                                              Factor
         , Estimated Cost
 Direct  Cost  of Battery Limit

 Storage and  Handling  (Included  in  B/L,
   but  Added Min.  Add.)

 Utilities
   Battery Limit Add'n, Steam and  Elec.
   Available from Existing  Power
   Station - Use Low  B/L

 Servi ces
   Battery Limit Add'n, Minimal
   Services  Required

     TOTAL BATTERY LIMIT +  AUXILIARIES
 Catalyst
   Activated  Carbon:   [Adsorber +
      Regenerator +  6  Hr.  Inventory]
   (12  hrs.)(172 TPHH800/T)
   Shift:   (2,000 ft.3)($26/ft.3)

      TOTAL  DIRECT COST
 Indirect  Costs
   Engineering  &  Supervision     Factor
   Construction Expense          Of Direct
   Contractor's Fee              Costs
   Contingency
  14
  10
   4
  20
            $20,240,800

                404,800



                607,200




                607,200


            $21,860,000



              1,651,200


                 52,000

            $23,563,200
          TOTAL  DIRECT  &  INDIRECT  INSTALLED COST
 11,310,300

$34.873,500
                                 819
-------
COST ESTIMATE
Item
No.

FB-101
A.B.C.D
r t) h^ 9 V J •*


FB-102
A R r n
n,Q,l« , u



FB-103
& 104
A.B.C.D
f



FB-105
A.B.C.D



., 1 Number
Name Req'd.

SO? Adsorber
b


•
S Generator





H2S Gen. /Sulfur
Stripper





Carbon Cooler


';"-

• 4




4





4

.




4


•

Description
CLASS FB
55'0x61' High,
l/2"-l/8" Thick
Carbon Steel;
5 Trays, 1/4" •
Thick, 410 SS
11.3'0x56' High,
1/4" Thick
Alonized 304 SS;
11 Trays, 1/8"
Thick Alonized
304 SS
20. 5 '0x38' w/Top
Section 18.6'0
x!2', 1/4" Thick
Alonized 304 SS;
8 Trays, 1/8"
Thick Alonized
304 SS
14.5-0x12' High,
1/4" Thick 502
SS with one 1/8"
Thick 304 SS
Tray
Comments
- TOWERS
Factored from
Chat. Tank Co.
Quote


Factored from '
Chat. Tank Co.
Quote w/Alonizing
Used Based on
Cost from Alon
Proc., Inc.
Factored from
Chat. Tank Co.
Quote with
Alonizing Used
Based on Quote
from Alon Proc. ,
Inc.
Factored from
Chat. Tank Co.
Quote


CLASS S - DRUMS
S-102
A&B


S-101
A&B



SP-101
A.B.C.D

II "•• 1 •••__!_•
Fresh & Regen.
Carbon Storage

•
Acid Ladened
Carbon Storage



Molten Sulfur
Storage

	
2




2



4


• • i • •
28 '0x60' Verti-
cal Cone Bottom
Tank

'
28'0x60' Verti-
cal Cone Bottom
Tank

39 '0x35' Verti-
cal Carbon
Steel Tank,
Steam Traced
— ——.^ ^ _
i —
Carbon Steel;
Factored from
Chat. Tank Co.
Quote

Carbon Steel ;
Factored from
Chat. Tank Co.
Quote
Literature


, ,i
Purchased
Unit Cost

$505,000


'

$ 94,800





$181,000






$ 29,800




Total Cost

$2,020,000




$ 379,200





$ 724,000






fr 1 1 A nr\r>
V 1 1 3 »OOO




'
$ 24,400


.

$ 24,400



$ 50,000


———_____
$ 48,800




$ 48,800



$ 200,000


^" — — 	 __
   (Cont'd)
    820
-------
COST ESTIMATE    (CONTINUED)
Item
No.
Name
Number
Rec^d.
Description
Comments
Purchased
Unit Cost
Total Cost
CLASS U - MATERIAL HANDLING .
CR-101
& 102
A.B.C.D

U-101
A.B.C.D



U-102
A&B


U-103
A,B,C,C



U-104
A,B,C,D


U-105
A.B.C.D


U-106
A&B



U-107
A&B



Carbon Feed
Rate Control! e


Bucket
Elevator

.

Bucket
Elevator


Bucket
Elevator



Bucket
Elevator


Bucket
Elevator


Belt Conveyor




Belt Conveyor



8



4




2



4




4

.

2



2




2



42 T/Hr.
Gravimetric
Digital Control
Belt Feeder
42' High Bucket
Elev. To Trans-
port C from
Hopper to SOg
Sorber
88' High Bucket
Elev. To Trans-
port C from SO?
Sorber to Hopper
100' High Bucket
Elev. To Trans-
port C from.
Hopper to S
Generator
92' High Bucket
Elev. To Trans-
port C to S
Generator
83' High Bucket
Elev. To Trans-
port Regen. C to
Hopper"
2' Wide x 48'
Long Belt Conv.
To Transport
Make-up C to
Storage Hopper
2' Widex9T+4T
Long Belt Conv.
To Transport C
from Hopper to
S02 Sprber
Factored from
K-TRON Corp. Quote


Literature
t


'
Literature



Literature




Literature



Literature



Literature




Literature

,

$ 18,100



$"8,230




$ 14,500



$ 15,700




$ 14,900



$ 14,000



$ 5 ,000




$ 12,300



$ 144,800 B/L



$ 32,900




$ 29,000



$ 62,800




$ 59,600



$ 28,000



$ 10,000




$ 24,600


-
         (Cont'd)
         821
-------
COST ESTIMATE    (CONTINUED)
Item
No.
Name
Number
Req'd.
Description
Comments
Purchased
Unit Cost
Total Cost
CLASS U - MATERIAL HANDLING (CONT'D)
U-108
A&B
U-109
A.B.C.D
u-no
A.B.C.D
*

CV-101
A,B,C,D

X-101
A.B.C.D
X-102
A.B.C.D
X-104
A.B.C.D
X-103
A.B.C.D
•MM^HHIHMHMIMM
Belt Conveyor
Belt Conveyor
Belt Conveyor

Shift
Converter

Steam Heater
for Sulfur
Generator
Inlet Gas
HgO Condenser
for Inlet Gas
to S Generator
S Condenser
V
HgO Condenser
for C Cooler
Gas Recycle
•«^— •— »^— •— — «^™» ^ B.P
2
4
4

4
2' Wide x 66'+
18' +22' Long Belt
Conv. To Trans-
port C from
Hopper to S02
Sorber
2' Wide x 14'
Long Belt Conv.
To Transport
Spent C to S
Generator
2' Wide x 18'
Long Belt Conv.
To Transport
Regen. C to
Hopper
Literature
1 *
Literature
Literature
CLASS C - CONVERTERS
Shift 1600 1
moles/hr. of
Producer Gas
Based on Infor-
mation from
Girdler Catalysts
CLASS X - -EXCHANGERS
4
4
4
4
WVOpmiHllBBv^M
3.6 MM BTU/hr.,
Steam Heated
27.9 MM BTU/hr.,
Air Cooled
Alonized Shell
& Tube
25.7 MM BTU/hr.,
Alonized Shell
& Tube
24 MM BTU/hr.,
Shell & Tube
...
750 ft.2
2500 ft.2
2500 ft.2
2500 ft.2
••'
$ 11,800
$ 2,300
$ 4,700

$ 36,500

$ 14,000
"$ 11,200
$ 11,200
$ 11,200
1
$ 23,600
$ 9,200
$ 18,800
•
$ 146,000
•
$ 56,000
$ 44,800
$ 44,800
$ 44,800
"
         (Cont'd)
        822
-------
COST ESTIMATE   (CONTINUED)
Item
No.
Name
Number
Req'd.
Description
Comments
Purchased.
Unit Cost
Total Cost
CLASS F - BLOWERS AND PUMPS
F-101
A.B.C.D
F-105
A.B.C.D
F-103,
104 & 105
A,B,C,D
f
M-101
AJB.C.D
M-102
A.B.C.D
M-103
A,B,C,D
M-104
A.B.C.D
M-105
A,B,C,D
Flue Gas
Blower
Regeneration
Gas Blower
Air Blower for
Gas Heaters
4
4
12
438,000 SCFM,
6,837 Hp To Boost
Press, to 45"W.G.
Heavy Duty
19,984 CFM0152"
W.G. G> 150°F
Inlet Temp. ;
Heavy Duty, Rotary
Gas Pump, 684Hp
1 ,000 CFM 
-------
COST ESTIMATE   (CONTINUED)
Item
No.

G-102
A,B,C,D




G-103
A.B.C.D


GH-103
A.B.C.D


GH-102
A.B.C.D


GH-101
A3.C.D


G-101
AAC.D


Name

Gas Producer





Start-up
Heater for $02
Sorber

Gas Heater for
Shift Converter


Gas Heater for
C Preheater


Gas Heater for
H2$ Generator/
S 'Stripper

Inert Gas
Generator


Number
Req'd.

4





4



4



4



4



4



Description
Comments
CLASS G - FIRED HEATERS
9,581 SCFM,
8,844 # Coal/hr.
with Capabilities
up to 9900 #CoaV
hr. Bituminous
Coal
6.8 MM BTU/hr.,
No. 2 Oil Fired


13.1 MM BTU/hr.,
No. 2 Oil Fired


17.6 MM BTU/hr.,
No. 2 Oil Fired


15.1 MM BTU/hr.,
No. 2 Oil Fired


60,000 SCFH
Capacity Kemp
Inert Gas Gen.

McDowell -Well man
Quote



.
North American
Burner, Double
Pipe Heater,
Factored Up
Process Plant
Construction
Estimating &
Engineering
Process Plant
Construction
Estimating &
Engineering
Process Plant
Construction
Estimating &
Engineering
Process Plant
Construction
Estimating &
Engineering
Purchased
Unit Cost

$260,000

'

•.V.

$ 19,000



$ 97,900



$105,600



$ 97,900


•
$ 24,860



Total Cost

$ 1,040,000 B/L



r

$ 76,000



$ 391,600 B/L



$ 422,400 B/L



$ 391 ,600 B/L



$ 99,440 B/L



MISCELLANEOUS



•
Ductwork for
Flue Gas


1



12x'23' Duct



Factored from
Duct Cost for a.
550 MW Install.
with Bypass
$2,862,000


•
$ 2,862,000 B/L



        824
-------
              APPENDIX C-2





15 MW DETAILED EQUIPMENT DESIGN AND COST
                    825
-------
               GENERAL DESIGN BASES FOR PROTOTYPE INSTALLATION


A.  POWER PLANT

    1.   Equivalent Size - 15 MW

    2.   Fuel
        a.  Coal
        b.  Composition (Wt. %)
            1)  Carbon - 55.7%
            2)  Oxygen - 6.1%
            3)  Hydrogen - 3.9%
            4)  Nitrogen - 1.4%
            5)  Sulfur - 3.5%
            6)  Moisture - 9.4%
            7)  Ash - 20%
        c.  Heating Value - 11,100 BTU/lb.

    3.   Combustion Conditions
        a.  Excess Air - 22 vol.  %
        b.  Air-Moisture Content - 60% R.H.  @ 80°F
        c.  Sulfur Combustion
            1)  98% to S02
            2)  2% to S03
        d.  Sulfur Generator Off-gas Recycle to Boiler - 16% of SO? Originating
                                                           from Coal
        e.  Equivalent Coal Firing Rate - 12,714 Ibs./hr.

    4.   Other
        a.  Air Heater Inleakage - 7 vol. %
        b.  Precipitator Efficiency - 99.5%

        i
B.  GENERAL

    1.   Carbon Properties
        a.  Mesh Size - 8x30  (Nominal)
        b.  Bulk Density - 40-43 lhs./ft.3
        c.  S02 Activity - 6JO (Minimum}
        d.  Attrition.No. - *30 (Maximum)
                                                     X
    2.   Carbon Storage
        a.  Make-up - 1 Month's Supply

                            T°tal 9
                                   826
-------
3.   Utilities
    a.   Boiler Feed H20 - 250°F, Saturated
    b.   Service H20
        1)   Temperature - 80°F
        2)   Max. Temp. Rise - 40°F
    c.   Air
            Temperature - 80°F
            Moisture - 60% R.H.  @ 80°F
            rti i

            l\
C.   S02 SORBER

    1.   Inlet Flue Gas  Composition
        a.   S02 -  3,230 ppm
            1)  2,760 ppm from coal
            2)  470 ppm from  sulfur generator off-gas recycle
        b.   $03 -  55 ppm
        c.   NO - 280 ppm
        d.   02 - 4.46 vol.  %
        e.   H20 -  10.3  vol. %
        f.   C02 -  12.6  vol. %
        g.   N2 - 13 vol.  %

    2.   Total  Inlet Gas Flow  Rate - 29,484 scfm

    3.   Linear Gas Velocity - 3 FPS @ 170°F

    4.   Inlet  Gas  Temperature - 330°F

    5.   Outlet Gas Temperature - 200°F

    6.   Column Temperature
        a.   SOa Removal  Stage - 330°F
        b.   Avg. S02 Stages -  170°F

    7.   Inlet  Carbon Temperature - 77°F

    8.   Outlet Carbon Temperature - 300°F

    9.   Inlet  Carbon Loading, Residual Sulfur - 0.04 Ib.  S/lb.  C

  10.   Outlet Carbon Loading, Sulfuric Acid - 0.22 Ib.  H2S04/lb.  C
                              Residual  Sulfur - 0.04 Ib.  S/lb.  C
                              Associated Water - In Equilibrium with
                                                   H2S04 8 330°F

  11.   S02  Removal  Efficiency - 90% S from Coal

  12.  Gas Distributor Plate - 8% O.A.  with 1/8" Dia.  Pucnhed  Orifices on
                                 0.42"  k Centers
                                  827
-------
D.  SULFUR GENERATOR
                                     *

    1.   Linear Gas Velocity -  3.0 fps  & 300°F

    2.   Inlet Gas Temperature  -  265T

    3.   Inlet Carbon Temperature - 300° F

    4.   Outlet Carbon Temperature - 300°F

    5.   Carbon Residence Time  -  40 min.

    7.   No. of Stages/Unit - 11

    8.   Gas Distributor Plate  -  5% O.A. with 1/8"  Dia.  Punched Orifices on
                                  0.53" A Centers

    9.   Chemistry:   70% Conversion H2S04 — » Sulfur
                     15% SOg Evolution Recycled to Sorber
                     15% Unconverted Acid to H2S Genera to r7S Stripper


E.  H2$ GENERATOR

    1.   Linear Gas Velocity -  3.0 fps  @ 500°F
                                         !

    2.   Inlet Gas Temperature  -  1300°F

    3.   Gas Temp, to S Condenser - 900° F

    4.   Inlet Carbon Temperature - 300°F

    5.   Outlet Carbon Temperature - 300°F

    6.   Carbon Residence Time  -  30 Minutes

    7.   No.  of Stages/Unit, for  Carbon Regeneration - 6
                            for  HS Formation -  2
    8.   (ias  Distributor Plate  -  b%  u.A.  with  i/«i;  uia.  Punched Orifices on
                                 0,53"  A Centers

    9.   Chemistry:   Sulfur  to  H?S by  Reaction with H?
                    Acid to Sulfur  by Reaction  with f^S and/or H
                              828
-------
F.  SULFUR RECOVERY
    1.  Operating Temperature Range - 260 to 300°F (Lower Temp.  Preferred)
    2.  Sulfur Purity (Bright) - 99.9 wt. % (Minimum)"
                                 829
-------
Major  Equipment Design
     Integral pilot plant data was used as a basis for major equipment design.
The major vessels to be designed are the S02 sorber, sulfur generator, and
H2S generator/S stripper.  The design procedures used and the results found
are given below.
     $02 Sorber
          Diameter
     From the power plant a certain flue gas is to be treated.  In this case
a  gas  flow  rate typical from a base load boiler of 15 MW was taken.   The flue
gas flow rate was 29,484 SCFM.  The diagram of the S02 sorber is:
                                               Temperature = T, °F
                                        q, Gas Flow Rate
                                        v, Linear Gas Velocity
and, in general:
or solving for the diameter, D:
  [2]
     It is seen from Equation [2] that the diameter of the vessel is a function
of the gas flow rate, q; the linear gas velocity, v; and the temperature, T.
The flue gas flow rate is 29,484 SCFM and if a velocity of 3 ft,/sec. is
                                    830
-------
D =
16.3
ft.
specified at the average temperature 170°F then Equation [2] leads to a SC>2
sorber diameter of:

   [3]

     The linear gas velocity was taken as 3 ft./sec. to afford capability of
variation from 2 to 4 ft./sec.  The temperature was taken as 170°F because
this is the average temperature expected during actual operation of the S02
sorber.
          Space Velocity
     The  procedure used to design  a 502  sorber is given in  detail in Appendix
 A-20-5.  The highlights of the design procedure are repeated below.  The
 plug flow design  equation given by Equation [4] is given
    [4]
     /-Fv.
=   A,
       "'-'-  where:  V     =  volume of carbon
                   RS02  =  mo1ar flow rate
                   Fv    =  fractional conversion
                   /v    =  rate of reaction, acid formation

 by Levenspiel23.     The rate expression was determined from experimental
 results as given by Equation [5].  The molar flow rate of sulfur
                                      831
-------
                                         GX  \    »/•»"
                                    ' "  "0.3V  /50>-
                                                         for NO Cone. > 100 ppm
          where:  rv  =  Ibs. acid/1b. C/min.
                  T   =  temperature, °R
                  Xv  =  acid loading, Ib. acid/1b. C
                  V   =  volume fraction
dioxide, R$02» is given by Equation  [6]  and  the fraction conversion, Fv,  is

   [6]
          where:   qj  =  inlet gas  flow  rate
                         N  =  inlet  S02 concentration, vol. fraction
defined in terms of volume fraction  as  given  by  Equation  [7].  The  volume  of
carbon is given as the height of carbon  times  the cross -sectional  area  of the
reactor.   Making the substitution into Equation  [4]  and  integrating  the design,
Equation  [8] is obtained for any stage j.   In  making the integration
               :   P
                  D   =   reactor  diameter,  inches
                  hj   =   settled  bed  height carbon  for j^  stage,
                                    832
-------
plug flow of the gas and backmix of the solid was assumed.  A material  balance
for acid across the jth stage leads to Equation [9].  Then by stage
          where:  Rc  =  carbon rate, Ib. C/hr.

by stage  calculations Equations [8] and [9] can be used to design a S02
sorber.  By taking the conditions given for the S02 sorber:

     Inlet Flow Rate  =  1 ,909,000 CFH @ 70°F
     Inlet Gas Concentration, S02 (+ $03)       =  3,285 PPM
                              NO                =  280 PPM
                              02                =  4.46%
                              H20               =  10.3%
                              Inerts (N2, 002)  =  Balance
     Outlet S02 Concentration  =  280 PPM
     Average Temperature  =  170°F
     Outlet Acid Loading on Carbon  =  0.22 Ib. H2S04/lb. C
     Carbon Rate  =  6,605 Ibs. C/hr.
     Diameter  =  196 inches (16.3 ft.)
For various assumed bed heights per stage (6, 12 and 18 inches) S02 sorber
designs were obtained as given in Fig. C-2-1  and Tables C-2-1 to -3.  For  four
stages then the carbon bed depth is 11 inches at a space velocity of 2,350
ft.3 gas/ft.3 C/hr.
                                    833
-------
     Figure C-2-1.
Effect of carbon bed/stage on S02
sorber design at 3 ft./sec.
CO

in
M
(U
    2 - -
   0
                                Design Taken
                                @ 4 Stages
       O Number of Stages

       A Total C Bed Depth

       D Space Velocity
      0
                                             --60
    10
15
                                              • 40
                               CO
                               0)
                               J3
                               O
                               C
                                                   JS
                               (1)
                               Q
                                                   CU
                                                   PQ
20
          Carbon Bed Depth/Stage,  inches
                                   - -3000
                                   --2500
                         - -20  o   •-1500
                               cd
                               .u
                               o
                               H
                                   -.2000
                            O
                            O
                            i-4
                            (U
                                           0)
                                           o
                                           (0
                             834
-------
      S02  SCRBER DESIGN

 RUN NLKBDR     GCPD-5    DATE  7  23  74
 TOTAL c0  LBS A(,in/LB  CARGON
 HE.l.GH,T..OF_j;ARBON/.ST AG6__= ___ 1 2 ..0.0. .INCHES   _
 "DIAMETER  ot: VESSEL =196.6 INCHES   ...... ""
 CARBON USED =      0.
 TOTAL.. GAS _.FL.C\>'_RATr-..= _...! 7J.2:1.2.8, .JSCFII
 "INLET SG2  CCNCI:-NTRAT'ION =~     "328'5."~ppM "
 INLET NO  CONCENTRATION =       280.  Pf'f
 INLET. .pZ.VCLyME . F.R ACT I .CN ..-?.... .0..0/.46
 INLET H20  VOLUME FRACTICK =   0.1030
 OUTLET S02 CCNCENTRATION =       2SO. PPM
 TEMPERATURE = 170.0  DEC. F
             S02 CONCPNTRATICN         ACID LOADING
	.STAGE	 _  PPM	  LBS ACID/LB CARBON
       ~"l            "3285"'.     ~"	"""6'."2205	
        2"  	2274.          ""_ 	0.1'(63
	3 __I__1_  .'JL077.	    Q..058!>
     0.71         279.9998           .        0.0
 TOTAL CARDDK REQUIRED  =      44.54  INCHES
                                                                    ___ ^

 SPACE VELOCITY =      2279. 1/HR
 PRESSURE  DRCP ACROSS  CARBCN =     22.27 INCHES  1-20
 PRESSURE  DRCP ACROSS  PLATES =     11.13 INCHES  H20
    RATE  EXPRESSION USED  IN CESIGN  CALCULATIONS

.8 A TEC. II L=COEF.F * J i~.X. (.1, }./:.X.S ) *.*A_*...^YSp2.<^*B.^_^j Y0.2.*Jt\QI_*_.(.y!12.0**ip.L_
    WHERE "C'O'EF"F-K * EXP(-E/R*( i/(T+460j ) )
                                      .3.8 _________ _ ____ JLO?.:: ...... _Q..04.5. __________ Yh.2.Q.=... ........ C...1C?>.
      -E/R-    5520.       ....... A=    1»000      ...  B=^    0.400           C=   0.630
         K=O.C00159    ...... ....... ._ ............ ___ .......... .. ................                .......
                                    835
-------
                                 Table  C-2-2
      S02 SOMBER  DESIGN
HUN  NU'BCK
               GCPD-6    CATC  7  23 74
TOTAI  CARBI;N RATE  =  6&05.coo LBS/HR
CUTLET CARBCN  LOADING = 0.22050 IBS ACID/LB CAROON
HE! GKT CH ..CAR(3CN/ST.AG.E_.= _____ 6.00..INCHES ______________
OIAC.ETER OF VESSEL =196.0  IMCMES ........ _ ..... ------- ...........
CARBON USED =       0.                  .......... ___ ..... ......
T.OT.AL. ..G./-S. .F. L CW _RA.T E.. = _____ L7.Z2 1 ZB.,._SC£t! _________
INLET  S02 CONCENTRATION =
JIJLET  NO CONCENTRATION =
INmT...02..VCLUM6..rRACTION_=_ ...<
INLET  H20 VELUHE  FRACTION =
OUTLET S02 CONCENTRATION =

TElTpERTYuRE =" 170.0* DEC. ~F
            S02 CONCENTRATION
	SLAG E.	£P.M	
                                 3285. PPI"
                                 280. PPI"
                                0.1030
                                   280.  PPK
        1
        2
        3.
                     3285.
                     2761 .
                 	21 6.3 ,_
                     1513.
                      063.
                 	303_._
                 2V9-999J?
    ACID  LOADING
 LB.S... AC.ID/.L8_..CARIVON..
           0.2205
           0. 1821
	!„	aU 382	
           0.0905
           0.0'*28
	OA.P.Q.I.I	
           0.0
TOTAL  CARDCN REQUIRED
SPACE  VELCCITY  -
                               36.28 INCHES
                       2797. 1/HR
PRESSURE DRCP ACROSS CARBCN =     18.1^  INCHES H20
PRESSURE DRCP ACROSS PLATES =      9.07  INCHES H20
.10.1 A.L..P.R.ES.S.UB EJ3JlQ£L_AC.B.QS5_iLA.P.E.S_r	  27.21_I N.C HE S ±12.5
    RATE  EXPRESSION  USED IN DESIGN CALCULATIONS

.(\AT.CC(.I.J.r.C.n.Er.F...*_J_l.r.X(l.)/_XS)**A  * (Y.S02.**I?L±  (YQ?*_*C»  *  (YH20**OI
    WHERE  COEFF = K  »  EXC (-E/R* I 1 / ( T + /i 60 J ) ) 	             	""
 	1=	1.7.0.,.
              5520.
        K-O.CC0159
1.000
                                                3tna=....  0.0/+5
                                                  B= .   O.'/iOO    ""
0 . ) 0 3
C.630
                                     836
-------
                                Table  C-2-3
      S02 SORBER  DESIGN

RUN  NUMBER     GCPD-M   DATE   7  23 74
 TOTAL CARBON RATE  =  6605.COO  LBS/HR
 CUTLET CARBCN  LOADING = 0.22050  LBS ACID/LB  CARBON
 HEIGHT. CF CARBCN/STAGE =  18.00  INCHES
'DIAMETER or- VESSEL =196.6 IN CHE'S	
 CARBON USED =       0.
 TOTAL GAS FLCW RATE_=  1772128.  SCFH
 INLET S02 CONCENT RATION =   '  3285."pP>"
 INLET NO CONCENTRATION =       280.  PPM
 INI E I. .02.,_VCL U f-i.E. F fi AC T 1,0 N. .=....._0.f 0 'i /• 6.
"INLET 1120 VCLUCC FRACIION -' 0.1030"""
 OUTLET S02 CCNCENTRAT1 OK =       280. PPK

"r EM'P¥R A "f'ijRT ="T7o""."o" DEC T"F     	
            S02 CONCENTRATICN.         ACID LOADING
	STAGE	£PM	LBS ACID/LB  CARBQN
        1            3205.             	0.2205'
        2            1826.                   C.I135
                    ?. 9996 :	.,:','-'J.H"H-.  _Q.O	
 TOTAL CAR130N RtGUIIikU =     53.23 iNCHhS .
 TOTAL STAGES REQUIRED ASSUMING18.00 INCHES CARBON/STAGE =  2.96
 S.PACE VELOCITY =      1907. 1/HR

PRESSURE CACP. .ACRP.S.S...CARB.C.N_=	i.2.6,.61_.I.KCHES.. H20^ ...	
 PRESSURE D'KC'P ACROSS PLATES =     13.31 INCHES  H20
 TOTAL PRESSURE DROP  ACRCSS STAGES =    39.92  INCHES  H20
_____ R.AJ.E... E XP.R.C.S.S I.O.N_.US.[?.P_,..I N_,C.E.S..l.GN.. _CALC.UL.ALLQN.S ____________________________ .....

RATECU > = CQEFF *  { 1-X ( I J/XS ) **A  *  [ YS02**B ) "  *  (Y02**C> *  (-YH20**DJ
         T=     170.         XS=     0.38        Y02=   0.045       YH20=    C. 3.03
      r£/.R.r: ____ 5.5.20.. ____________ A.^ _____ UO.QQ ______ j^= ___ O..AQO ___________ _C= _____ £.6.3.0
      '   K=O.C00159  ..... .  ...      .................... ..............
                                    837
-------
     Sulfur Generator
          Diameter
The rate of acid from the S(>2 sorber determines the H2S required for conversion
to sulfur by Equation [10].
Since the acid loading from the sorber was 0.22 Ib.  acid/lb. C and the carbon
rate was 6,605 Ibs. C/hr., then the molar flow rate  of acid is 14.8 moles/hr.
Based on integral pilot runs to get high H2S utilization, lower acid conversions
were obtained.  Seventy per cent of the acid was converted to elemental sulfur
in the sulfur generator and 15% was evolved as S02">  therefore, the molar H2S
requirement is about 31.1 moles/hr. plus the breakthrough of less than 0.1
mole/hr. (99.9% H2S utilization).  The S02 is recycled to the sorber, while
the remaining acid is converted in the H2S generator/S stripper.  Based on
the producer gas an inlet H2S concentration of 22 volume % is obtainable;
therefore, the total inlet gas flow rate into the sulfur generation is given by
Equation [11], to yield 50,800 SCFH (847   SCFM).  As for the S02 sorber,
Equation [12] evolves relating the reactor diameter to the gas flow rate,
linear gas velocity, and column temperature.  For a gas flow of 847 SCFM, a
gas velocity of 3 ft. /sec., and an average temperature of 300°F, the sulfur
generator reactor diameter of:
                                     838
-------
[12]
                                D  =  3.0 ft.
     The velocity was taken as 3 ft./sec. to allow variability of operation and
300°F is the expected average operating temperature.

          Space Velocity
A procedure similar to the one used for desining the S02 sorber was used  to
design the sulfur generator.  The plug flow design Equation [4] provided  a
basis  with the same assumptions of plug flow of the  gas  and  backmix of the solid
to obtain the design relationship.  The rate expression  from differential
reactor measurements is given by Equation [13].   Then  the
          where:   rH2S  =  rate H2S used,  moles  H2S/ft.3  C/hr.
                  T     =  temperature,  °R
                  Xv    =  acid loading, Ib.  acid/lb.  C
                  /H?S  =  H2S concentration, volume fraction
molar flow rate Equation [14] and  the fraction conversion, Equation [15]
   run
   [14]
                                    839
-------
substituted into     Equation  [4]  leads  to  the design  Equation  [16].  This
           i.    D      11^1 (y  V V
          where P   =   — r- U    J>
                D   =   reactor  diameter,  inches
                hj   =   settled  bed  height for jtn stage, inches
combined with the material  balance,  Equation [17]
          where:   Rc   =   carbon  rate,  Ibs. C/hr.

are used to make  stage-by-stage  calculations.  By taking the conditions  below:

     Inlet Gas Flow Rate   =   54,619 ft.3/hr. @ 70°F
     Inlet H2S Concentration   =   22.04 vol. %
     Outlet H2S concentration = 0.04 vol. %
     Outlet S02 Concentration = 1.46 vol. %
     Inlet Acid Loading on Carbon =   0.220 Ib. acid/lb. C
     Outlet Acid  Loading  on Carbon  =  0.033 Ib. acid/lb. C
     Carbon Rate   =  6,605 Ibs.  C/hr.
     Average Column Temperature   =  300°F
     Column Diameter   =   36 inches (3  ft.)
                                   840
-------
     The design procedure was used for various  bed  heights  (5,  10, 15,
17, 20 and 25 inches).   The design results are  given  in  Figure  C-2-2
and Tables C-2-4 - C-2-9.  For 11  stages the settled  carbon bed depth/
stage was 17 inches at a space velocity of 460  sft.^  gas/ft.^ C/hr.
                                 841
-------
   Figure C-2-2.  Prototype sulfur generator design - effect of
                carbon bed depth/stage
o 470- -
SP   25- -
       0
                           4-
                                          I   Design Taken
                                          'jr"at  11 Stages
                5         10         15        20

              Carbon Bed Depth  Per Stage,  inches
                                                             •-105
                                                               103
25
                              842
-------
                          Table  C-2-4
sui.rtn GI.NGKAMON MATERIAL  BALANCE
   rOUC»$  CF SULFUR  IN
   POUNDS  CF SULFUR  OUT
1472.4521
1470.7224
                           J5G..60JJ.	
   CONTRCL VARIAOLE,  Z  «  I.
   HEIGH!  CF CARIJON/STAGE_BASnO ON  SJ T T LIP JBCDJ) FTTH, 1 NCHES
   bi A>f:'TfR~cir""cciui''Ni  "INCH"!:*"'	' 36~."6o	"  "       	
   TOTAL  IKLfT GAS  FLOW RATE, CFH AT 7CF. =  54619.00
   RATH  CONSTANT•=	  3.8000	
  ~KI Nl/i' AC'ffvATTb'N ENC'RCV/CAS LAH~~CONSTANT" =  -26'i'iT'oO
   lF.ITI:RATURt OF  REACTOR =    760.00
   ORDER  CF K F.AC T I ON HIJII^ES^ECT TO H2S ^  _ 0.5000  	'
   "o«bcR""cF"i*'E>.c'T'ro'N" ii'iiM R.Esi't:cf"fo""Ac"Fb LOAD']'NG"=
   CAKUON RATH.LBS/UR =   6605.00
   HUM 111: R CF STAr.fS WHEN KNOWN FOR  7. =2  = it.
        '~"'   '       '"~~""        "
                                        s.occo
YH7SIK -
Yll2:'»OUT B
X'v IN =
XVOUT "
YS02IN =
YS020U1 »
X S 1 N «
0.2204
0.0004
0.2200
0.0326
0.0
0.0146
0.0
   STAGE
            H2S CONC.i  VOL. FRACT.
                                        AC10 LOADING, i LB  H2SO'i/LO C
0.0
1
2
3
4
5
6
7
0,
9
to
11
12
13
11
15
16
17
18
" f<>
20
21
"Y2 	
23
2',
' ?.!•
26
27
- 23-
29
30
31
-3'2"" 	 "
33
34
35
35.77
" 	 0.220'iOO
0. 214560
0.208356
0,201799
0.1-J4906
0.187696
0.1BOJ93
0.172^23
0.164'rl7
0.156208
0.147833
0.139331
0.130743
6.122113
O.H3',05
0.104906
0.096422
0.088079
	 0.079923
b".071999
0.0643'tO
0.057013
	 0.050030
0.0'i3'.34
0.037256
~ "" 0.031522
0.026255
0.021472
6.017105
/ 0.013401
0.01C120
0.007340
0'.00504B
O.OC32Z7
0.001054
0.000097
0.000417
0.033551
0.037627
- 0.041958
0.046535
0.051346
0.056379
0.061616
0.067039
0.072628.
0.078357
0.084203
0.090138
0.096132
0.102156
0.108178
0.114167
0. 120089
0.125912
0.131605
0.137136
0.142476
0.147596
" 0". 1524/0"
0.157075
0. H.13B7
0. 165389
0. 1690.66
0. 172404
0. IV 5i'>7
0.178038
0. 100 128
0.182269
7J. 183868
0.185U9
0.186097
0.1U6766
0.187100
         6l: STACKS
  I'CICMT CF CARBON/STAGE
  TOTAL lltir.MT OF CAKI'ON
 "TbTAL"VCI.UI'r"ci:~CAKUON""
  SPACE VELOCITY
 35.7685
  5.0000
I7fl.n424
       '
               _          ____
          cunic  iet:T"
   . 1982 SCF  GAS/CF CARflOM/IIOUR
                              843
-------
                               Table  C-2-5
 SULFim GENERATION  MATERIAL  BALANCE
    POUNDS  OF SULFUR  IN  =
    POUNDS  CF SULFUR  OUT =
  I472. 4 52 I
  1470.7224
                             SG  610
    CONTROL VARIABLE,  Z ='1.
    HEIGHT  C F C A R BON/SJ AG E BASED.ON__SF:T TL_EJD_fii E0.JDE_PTI1«..LNCHES__=;_	LP-i-Qfi.?.Q_
   "DIAMETER' o"r:~"c'6i.uKiVi "INCHES' =     36.bo
    TOTAL  INLET GAS FLOW RATE,  CFI- AT 70F. =  54619.00
    RATE _CONSTANT =_ _  3.8COO_	
   "MNU'S "ACTiVAiToN  ENERGY/GAS LAW CONSTANT =  -2644.00
    TEMPERATURE OF REACTOR =     760.00
    ORDER  OF REACT ION  KITH RESPECT TO H2S._=. _ .0 ..5.800.			
   "OR'DGR"~OF' ¥EAc'T~lbN"wTfH''R"ES'p'il'CT'""f6'~ACib L"bA'6fNG  =     0.6700
    CAR13CN  RATEiLBS/HR =   6605.00
    NUI'IJCR  OP STAGES  bllF.N KNOWN FOR Z =?_= 11.'   	
   ~FRACT"iCN"oF""iNLET  ACID LOST" AS S02=     0.1495   	
    YH2SIN   =    0.2204
    YI i? soyj_--	Q..,o_Q.p.4	H_!_I	L" J'	,	   .
   "XVIV"    =    0.2200                      ..
    XVCUT    =    0.0326
    YS021 N_ _f	0 ...0	;	
   "YS020UT =0.0146             _
    XS1N     =  "  0.0    	"	 '":	""	-
   . X.SO,UT....  =   _o^2 oio		



   STAGE _'   H2S_CONC.t  VOL. TRACT.  ,  ACID LOAD ING,, LB H2S04/LB  C

	0. 0 	•••••--  -JQ .220 4_0 Q_	                 'O. 0 3 3 5 51 	'""" "''"''
   1                  6.208811                   0.041641
   2      .            0.195867                   0.050676
	3	P...1.8 16.86	0 ..060.574	
   4~'   ~         "   6.166446                 "" 6.671216
   5          "	   0.150354      ^            0.082444
	6	'"". '     	0 .1 3 3 7 0 Q "'"'" '     '    ' '0.09 4 060	       ""''"
   7   ~              67116790"     "  '        "    o.ibTisv?.
   8                  0.099963                 '  0.117617
	9	0.003573	0.129058	
  10      ~     "   "d".06"797"2""    "         "  "6"7i39948~'
  11                  0.053'»92                   0.150055
_J2  _  	'_';	P_. 04 04 3 2 J	0.159)7).
  13                  0.029039           "     '-..bTr67'ri!3
  14                  0.019496                   0*17378',
_..l.|>	P.!jP.Vl.?19_.;	0.179080	
  16                  0.666300               " ~ 6.182995
  17               ~  0.002594                   0.185582
	10	"	0 . 000609	p_. 186968
 18'V)7     "  "       6".'0004")f9                   0.To"? 100         !
 NUMOER CF  STAGES
 HEIGHT CF  CARBON/STAGE =
  "
  TOTAL VCLUME OF CARBON •-
  SPACE VELOCITY
  18.1729
  10.0000
"1UT.7296~
 107.0474
 473.5549
 CUBIC  FEET
SCF  GAS/CF CARBON/HOUR
                                 844
-------
                                  Table  C-2-6
 SULFUR CENllRATTCJN "MATERIAL  BALANCE

     POUNDS  CF SULFlfR  IN  =    1472.4521
     POUNDS  CF SULFUR  OUT =    1470.7224
SULFUR GENERATOR DESIGN     SG 615
     CONTROL  VARIABLE,  I =  1.       	
   _.tl!f !I'HT  CF CA_RljqN/ST_AGE  BASEJDJ3N  SETTLED  BED; DEPTH, INCHES  -	15.00CO
     DI Ai'EI ER ~Cfr COLUMN, """i'NCHES" =     "3"6". 00     "      "   ""           7
     TOTAL  INLET GAS  FLOV, RATE,  CFH AT  70F. =   54619.00
     R.AT.E cpfSSTANJ  -  _  _3«8pop
   "~|7,lN"Us""AC"Tl'VAfTO>7 E"NERG~Y/GXs"Ow"^ONsTANT~^   -2644Td6"'
     TEMPERATURE OF  REACTOR  ='   760.00
     ORDER  OF REACTION. WITH  RESPECT TO  M2S «    P»5,8pp   _ _ "       	
   ~~'bTD^"cTnrEAl:TfON'lm7r^^0.6700""-
     CARDON  RAT[:,L8S/HR =    6605.00
   _ _N.y.MPJB..n(L..sIAG!is M'.ENJS^nwN FOR  z  -?. =_ii«	
     FRACTl C'K "6l': fNLET  ACrc"LOSf~AS~Sp2=" "   07T495" *         "      ""
     YH2SIN   =    0.2204               		'~	  "
     YH2Sf)UT_=J	' 0.0004 "'"  _   H '"' . '  J. " 7  --••-.---..--.— .--	-	-
    ~XV"i"N     =   "672200"
     XVOUT    =    0.0326                                  "   '

   ~Yso2"ouT"=    pToT^lT
   "  XSIN     = 	0.0    	~	r	"	"	-	'_    '•
          —   ---*—•" *•" * ^, ' ^ ^. . ^ '" ' •"•"' »—-•• —•- • • ~ --^-...  . --— •• -  -- •"..•- .--  - - - - •  _,.— -...-.. — -—.-_-..


                                           .•

    STAG!     H2~s~cli~Nc77~"voL". T\\ACt~     TcjD"ToATn74GT»'LB""Yr2SOwTB^c"

    0.0  '"	"" '~Q . 2 20400  --••—-••• •— — •—• p.'o^ggg 1 "	"	'"-'
    1                   6.TO 3 152   '                0."045 591
    2                   0.183076                   0.059604
 ^  3	0_.J6_0629	P.075272	
   "4        *           b.i'36Ti5  '       "        "O7o"92f04
    5  	"""0.111661       ..."	.0.109452
    6   "•  •"••••••        0.007 14_9  	'_	"_ _^L1TJ_"J' Oj 126562^__	"'.'... "'""""'
    7         *          67664""i"20~"       ~        ~O.T42637
    0                   0.043664                   0.156915
   9 •__	P.-P.'L6-6.^	P.I..1.6.8..? 5.2	

   11                   0.005359                   0.183652
   12   ""    '._!_'TJ1J'- P • °Qlo;?-t?	L	M-P'!?66.77	!'"_
"'12.Tf"   "   "         "o'76bbVi9      "          "  oVioVioo"  ""  "    ."



  NUMBER OF  STAGES        =    12.3091
  HEIGHT OF  CAJlflON/STAGni jf	  15.0000	'   __  .^ __ _'_"J	
  TOTArTiF.i'Gtit  OF"CA'KLI'ON' =  'i84".636i
  TOTAL  VCLUMf:  OF CARBON =   100.7598   CUBIC  FEET
  SPACE  VELOCITY          »  466.0989 SCF GAS/CF  CARBON/HOUR
                                   845
-------
                              Table C-2-7
 SULFUR GENERATION  MATERIAL BALANCE

    POUNDS CF  SULFUR IN  =    1472.'.521
    POUNDS OF  SULFUR OUT =    1470.7224
    CON'TRCL VARIABLE.  Z = 1.
    HE IGHT CF  CARBON/STAGE i3AjS.ED_ON_SJjTj;iL.EIOl{LO_J?.^JlL^.JMJ!i£L^.	LL'.OpCO_
    iiVA»
-------
                               Table C-2-8
SULFUR  GENERATION  MATERIAL  NALANCE

   POUNDS OF  SULFUR  IN  •--    1472.4521
   POUNDS CF  SULFUR  OUT =    1470-7224
   CONTROL  VARIABLEt  Z =  1.              	"     	           	
           OF  CAKBON/STAGI-:  BASED _ON _SETTLtO  RED DEPTH, INCHES =    20.00CO
           fr"tfrTToTuMNT""rNc'i:rL-s"~=	' "36~."ob~ ""  "".      ""               	
   TOTAL INLET GAS  FLOV, RATE, CFH  AT  70F.  =   54619.00
	 RATE CONSTANT  =     3.0000      _           ___	
  ""HiV\^U^""AC"TIVAf^6i^TNV:kC^Y/GAYT'AV^1cO^T>VTmV^'=  "~26T'tTb'b
   TE/'PERATUKE 0!" REACTOR  =     760,00       '                  	
 BORDER OF  REACTION  unit  RESPCCT  10  H2S  ~ ~_   0.5000 ___~^ "
   "bRneR""OF "Ri-A ct"i"ON  Vifii"RESI''i;cT"Yo""Ac"ib""t.o'/u)ING""=""   o."676~6~
   CARBON RATE.LOS/HR =    6605.00
  _NUI''BF.R_ CF  STAGES  WI-ICN_ KNOWN FOR I  =2_f  1_1.
""" r:RA"CTT6N~CF" "I'NLEt  AC 1   '"   "'""
  "'YH2SIK   =     0.2204
	YH2SOUT  =.^1^'Q'.QQOV.,"
   XVTN"'  "~=     "o'.22b"o
   XVOUT    =     0.0326
_  YS02JK	=	0_.0_
 ~~Y"S~0~2UU I "=     0 TO 1 "46
   "XSIN " ""=	"0.0 	
	xsgyil~~



  STAGl

  Q.p;^ _""""	    0. 2 204 OQ—--"••--••-•••- -•••-••••          ^
  \                   67T9YS83                    0.049470
  2      -             0.170114                    0.0686rJl
_3	0.139191	0.090236	
 _..                 ^-^^.-^           „-        oTl"l2905
  5    •"   ""	   	0.073104    " '.'.".".	  0.134970    '"'
  6	'"'"	"il"IZllP-P'16..?.3/t__L	1"_1_I"IH'1~._P.-l'^t6?3.     -1
  "7         "         oTb"24''485        ~    "       0.1.70302  '
  8                   O.OC9260                    0.180929
__9	0.00_1571	0.186296
 9"."38      '     '      6Tbo~o"'iT9    "" "         "..  "bTioVIbb"

"JW "***"' ' 'l-" *"^*^**^""'*rTl*—m^M uril^ll -•                                 ^

 NUMBER  CF  STAGES        =     9.3774
 HEIGHT  CF  CARKON/ST/VCF. =    20.0000	 _  .  	 	    .
"f01~Al"HL'll;"liT''OF"''cTR(HJN" = "~"i'ir7.5"4"76'
 TOT/U. VCLUME OF CARBON ---   110.4749   CUBIC  FEC-T
 SPACE VELOCITY 	 =  458.0630  SCF GAS/CF CARBUN/HCUR
                                 847
-------
                              Table C-2-9
 SULFUR GENERATION  MATERIAL  BALANCE

    POUNDS  CF SULFUR IN  =    1472.'.521
    POUNDS  CI-- SULFUR OUT =    1470.7224
SUI.FUR .G.EKC.RAT_p_B_.p.l:.S.LC'IL	SG__62_5_
    CONTROL VARIABLE,  7. =  1 .
    HEIGHT  CF CARBON/ S T AGJ_ I5AS.ED ON  SHTTLEp  BED.DE.PTH, J_NCHES.._^ ____ 2_5....00_CO
    bTAl'ElT:R"dF CbLL;'KN,"""lNCHL:S""="" ..... '"'3 67/00     ""
    TOTAL  INLET GAS  FLOW RATE,  CFH AT  70F. ~   54619.00
    RATH  CONSTANT  =     3.0000             "  ____  _____ u    __  ___ . ______ ___
    "MiNUS" ACT I'VATTbN ENERGY/GAS LAW  CONSTANT  =   -2644.00
    TEMPERATURE OF REACTOR  =     760.00
    OROCR  CF REACTION  KITH  RESPECT TO  II2S =_   0.5000    _      _   _  _
    dRDlER""OF"REAlCfl6"fT W I f tl" RE SPEC T~"f 0 ' AC fo" LOADING =     0.6706"
    CARBON  RATt'tLBS/HR -    6605.00
    NUMBER  CF STAGES U-IEN KNOWN FOR  7.  =2 •=_ 1 1 .    _    __  ____
    F'RACYl'cK"o'F 'jNlET  ACIc"'LbST'~AS S~02=     0.14"95
    •YH2SIN   ~-    0.2204
    YH2Sqyj_= __ 0.0004               "'    '"    ''' '' ' "   "  "  "              ~
    XVI'N" "" ="   672200
    XVOUT    =    0.0326
    y..sp.2n\i_- _ o.o
    "Y"SO£OUT =~"  ~6'.6i46
    XSIN     =    0.0
    x_sjiu
    Js


   ST~AGE

   0.0      "   ...... " ...'.. .0..2204QC I '" ' .._''_'_...,.'Z. 1" Ll"ll 0-033551
   1                  0.192103"   ~    '          ~6".'05'330~3
   2                  0.157099                    0.077736
  .3 _____ ^ ______ P^_l 17 9 19 _______  __ 0 . 1 0 5004
   4                  6.078585  ~            ~    67Y32546
   5                  0.043000                    0.156765
   6 _____ __ ___ ™111_.0_' P.I P !!?•}_   __ Z  __ """"__ "j?« 17<<7^.7
   7                  6.003751      '  ..... .....  67104775
  V.62                0.000420                    0.187100
 ..NM^.RG.R_CF_STAGF.S.    ' '"_=
  IUUGHT ci:~"cAR[inN7sf'AGl:  =
  TOTAL HEIGHT OF CAflflOK  =
     ._
SPACE  VELCCITY
_  7. 61 .81
 "TsToobo
 190.4514
 1.12.1053
'45Yr0669'
                                          cunic  FEE_T
                                        S CF" "GAS/CF "C'AKbGN/HUUR"
                                 848
-------
    H2$ Generator/Sulfur Stripper
The HgS generator/S  stripper is a multi-functional reactor, which removes the
sulfur from the carbon and converts  part of the  sulfur to H2S used in the
sulfur generator to  convert sulfuric acid to sulfur.  The reactor can be
separated into three phases:  1) a carbon preheater, 2) a sulfur stripper,
and 3) a H2S generator, although the function of each  phase overlaps.  In
this reactor any additional sulfuric acid is converted to sulfur.
         Diameter
    The hydrogen requirement was determined in  the integral pilot runs to be
about 3.4 moles H2/mole S02 sorbed.  In addition the total inlet gas flow
rate is determined by the inlet H2 concentration.  With the gasifier and water
gas shift reactor used presently  an  inlet H2  concentration of about
19.4% volume %,  therefore the total gas flow rate is given by Equation [18],
   ^   ^-"H.,6^,
to yield  94,000 SCFH (1,565 SCFM).   Then, as for  the S02 sorber, Equation [19],
   PS]     j>   =  vwrwi^r
for a linear gas velocity of 3 ft./sec., and an average temperature of 1000°F,
the diameter of the  H2S generator/sulfur stripper is:
                               D  =  5.8 ft.
The velocity was taken  as 3 ft./sec.  to allow variability in operation and
1000°F  is the expected  temperature.   In the top stage (carbon preheater section)
                                   849
-------
the temperature expected is somewhat lower,  about 700°F,  therefore the
diameter of that section was set at 5.2 ft.  to maintain  a gas  velocity of 3
ft./sec.
           Space Velocity
 Kinetic studies have  been  conducted  on  sulfur stripping  from  carbon and  for
 H2S formation.   The data are not yet complete enough to  allow a  rigorous
 equipment design as for the $62 sorber  and  sulfur generator.  For this
 reason equipment is sized by the  space velocity concept.   As given by
           23
 Levenspeil   ,     if a reactor is run under  expected operating conditions,
 then design of a similar vessel can  be  made based on equivalent  space
 velocities. This  assumes  no changes in system flow or thermal characteristics.
       For the  integral  pilot runs  sufficient  sulfur removal from the  carbon
 as well as  H2S formation were obtained  in an  8 stage,4 inch diameter  fluidized
 bed reactor.   The  bed,  which operated at an average temperature  of 1200°F,
 had two stages  for H2S  formation and 6  stages for carbon preheat and  sulfur
 removal.  The  space velocity at which the H2S formation  section  was operated
 was about 5700  sft.3  gas/ft.3 C/hr.  The carbon  preheat  and sulfur stripping
 section was operated  at a  space velocity of .about 1900 hr."^.
      In addition to the integral runs a process  variable study was done
 of the effect  of temperature on sulfur  removal,  on space velocity and
 inlet \\2 concentration  on  sulfur removal, and on temperature  on  H2S
 formation.   This data is shown  in  Figures C-2-3  - C-2-6.  The data
 indicates that  lowering the temperature to  1000°F  (Figure C-2-3) decreases
 the  sulfur  removal by about 10%, but Figure C-2-5  indicates that
 at  1200°F most  of  the sulfur  is   removed in  about  5  stages  (space
                                   850
-------
velocity - 1900 hr.'l) as in the integral pilot run.  Therefore for the H2S
generator for sulfur stripping and carbon preheat sections, the space velocity
was decreased by about 15% to 1600 hr."1 to allow for the decrease in
temperature.  This increases the carbon residence time from about 8 minutes
to 21 minutes, so there is an increase of over 2.5 times.  The reason the
space velocity doesn't change by this much is the inlet H2 concentration is
lower in the prototype, 19.5% versus about 30% in the runs shown in Fig. C-2-3  •
-6. As shown in Fig. C-2-4 the decrease in concentration from 30 to 20% has
little effect on the  sulfur removal, but rather the effect on space velocity
is on the increase in gas flow rate to maintain the same molar flow rate of
H£ needed for reaction.
     The effect of temperature on H2S formation is shown in Fig. C-2-6.  Decreas-
ing the temperature from 1200 to 1000°F decreases the conversion from about
72 to about 56%.  This decrease implies a decreased space velocity from about
5700 hr.-1 to about 4400 hr."1, however, in the prototype a space velocity of
3800 hr.""1 was used to assure additional conversion capability if needed.
                                    851
-------
       Figure C-2-3.  Effect of  temperature on sulfur stripping with
                      H2 present
C
O
XJ
o
•o
OJ
o.
Q.
to
100-


 90


 80-


 70-


 60-


 50-


 40-


 30-


 20-


 10-


  0
        700
Equipment:


Linear Gas  Veloc.

Inlet H2 Cone.:

Inlet S Loading:

Carbon Residence
  Time:
8 Stage, 4" 0 Fluidized
    Bed Reactor

2 ft./sec.

27 - 32 Volume %

0.26 Ib. S/lb. C


10-13 minutes
            800
900      1000     1100     1200


    Average Temperature,  °F
                                  1300
                       1400
                                    852
-------
  Figure €-2-^4.  Effect of HZ concentration and gas/solid contact
                 time on sulfur stripping at 1200°F
OJ
                        Equipment:


                        Linear Gas Veloc:
                        Avg. Temperature:

                        Inlet S Loading:
Space Velocity for S
Stripping & 1300 hr.'1
(C Res. Time = 13 min.)
       o—
                                                                 -1
Space Velocity for S
Stripping x 3,000 hr.
                                            (C Res.  Time = 6 min.)
8 Stage, 4" 0 Fluidized
   Bed Reactor

2 ft./sec.
1200°F

0.26 Ib. S/lb. C
                  __!	1            i	!	1—
                  10          20          30          40-

                      I,nlet Hg Concentration, Volume %
                     T~
                      50
                                853
-------
00
Ln
         o

          •
         -O

         3
         CO
              0.28
                     Figure C-2-5.  Sulfur removal  from activated carbon in an 8 stage,  4"0 regenerator
0.26-


0.24-


0.22-


0.20-


0.18-


0.16 -


0.14-


0.12-


0.10-


0.08-


0.06-


0.04-


0.02-
                0.
               Outlet
                          Run:               SHG-7

                          Avg. Temperature:   1200°F

                          Linear Gas Veloc.:  1.8 ft./sec.

                          Inlet H?:          38.0 Volume %
                                       •   4        5


                                           Stage Number
i
7
8
Inlet
-------
          Figure C-2-6.
                         Effect of temperature  on  the  conversion  of
                         sulfur to hydrogen  sulfide
    100
I
r—
3
CO
O.
Q.
CO

M-
O

fc*
CO
CM
X

o
•p

c
o
c
o
o
co
     60 H
    40 -\
     20 H
     0
       700
                   800
900
         1000         1100


Average Temperature, eF
                                                                   1200
1300
                                      855
-------
MANPOWER REQUIREMENTS

     The R&D, plant and maintenance manpower requirements were estimated
from the program schedule use past experience in pilot plant operation
as a guide.
     Engineering design costs were estimated separately as 10% of the
equipment costs based on Peters  & Timmerhaus11.
                                856
-------
                                                MANPOWER DISTRIBUTION
'''___ 	 ' "•!-.-•_ .— "—. - '• ' ' -•• 	 '" 	 "' 	 """ 	 -iiim-ii 	 mill iiiiiiiiii 	 IN 	 MI.I..I 	 •.
A. PILOT PLANT PROGRAM
1. Process Control (Existing
Pilot Unit)
2. Full Scale Fluid Bed Tests
B. PROTOTYPE PROGRAM
1. Prepare Detailed Test Program
2. Prepare Process Design Specs.
3. Detailed Engng. Design & Bids
4. Procurement & Construction
5. Definition of Boiler Opr.
Characteristics
6. Operation
a. Operator Training
b. Start-up
c. Test Program
d. Demonstration Run
7. Data Evaluation & Process
Assessment
TOTALS BY JOB

"• R&D PERSONNEL
Supr .
83
83
55
55
138
388
83

55
166
125
83
249
1,563
.Engr._
1 , 044
1,044
696
695
1,740
4,872
1,044

696
2,088
1,566
1,044
3,132
19,662
Anal.
522

696
696


522


522
522

1,044
4,524
Tech.
3,132
1,044






1,392
2,088
2,088
1,044

PLANT PERSONNEL
Supr .









522
522
1,044

10,788 j 2,088
Qp_r_._









2,088
2,088
8,352

12,528
Supr .









300
300
600

1,200
Maint.









2,088
2,088
4,176

8,352
TOTAL
4,781
2,171
1,447
1,447
1,878
5,260
1,649

2,143
7,774
9,290
12,167
4,423
54,440
00
Ln
-------
                               LABOR COST

                       (See Manpower Distribution)


Supervisor                               1,563 @ $12/hr.     =   $18,756
Engineer & Sci.                         19,662 @ $10/hr.     =    196,620
Analyst                                  4,524 @ $7.50/hr.   =     53,940
Technician                              10,788 @ $5.00/hr.   =     33,930

Plant Operator                          12,528 @ $5.00/hr.   =     62,640
Plant Supervisor                         2,088 @ $7.50/hr.   =     15,660

Maintenance                              8,352 @ $6.50/hr.   =     54,288
Maintenance Supervisor                   1,200 @ $7.50/hr.   =      9,000

     TOTAL                                                       $444,834
Overhead                                                          422,600

     TOTAL D.L.  & Overhead                                       $867,426


Maintenance Material  (100% of Maintenance  Labor)                    54,288

Consultants (1/Month  @ $400/Day)                                    14,400

Travel  (2 Trips/Month @ $200/Trip)                               	14,400
                                   858
-------
                                PROTOTYPE PROGRAM


DIRECT RAM MATERIAL & UTILITIES COST

   Coal (.358 T/hr.)($20/T)                             =   $7.16

   Activated Carbon (25 lbs./hr.)($.40/lb.)             =    10.00

   Power (900 Hp)(.746 KW/hr.)($.0075/KWH)              =     5.03

   No. 2 Fuel Oil  (63 GPH)($.20/Gal.}                   =    12.60

   Water, BFW (12,000 lbs./hr.)($0.18/1,000 Ibs.)       =      .22
          C.W. (250,000 Ibs./hr.)($.012/1,000 Ibs.)     =     3.0

              TOTAL UTILITIES & RAW MATERIAL                $38.00/Hour
START-UP:       (3 Mo. )(l/2 Time)(720 Hr./Mo.)($38/hr.)          =  $41,040

TEST PROGRAM:   (3 Mo.)(3/4 Time)720 Hr./Mo.)($38/hr.)          '=    61,560

DEMONSTRATION RUN:   (6 Mo.)(Full Time)(720 Hrs./Mo.)($38/hr.)  =   164.160

                     TOTAL PROGRAM UTIL. & R.M.                    $266,760
                                   859
-------
                        MAIN PLANT ITEMS FOR ESTIMATE

                                    (MPI)
           Designation

Adsorber

Regenerator (S Generator)

Regenerator (H^S Gen./S  Stripper)

Carbon Cooler

Blowers and Motors


Electric Motors


Heat Exchangers




      Urt a 4-ov»r
'Carbon Storage

Cyclone Collectors


Dust Collector

Bucket Elevators

Belt Conveyors

Shift Reactor

Gas Producer
Unit Cost
$65,700
18,100
24,600
3,700
15,330
6,600
8,610
500
14,500
7,600
1,800
500
3 300
24 ,'300
28,200
26,970
5,040
'15,850
1,470 Avg.
22,000
4,366 Avg.
2,753 Avg.
7,800
87,000

No. Req'd.
1
1
1
1
1
2
1
2
1
1
1
1
1
1
1
2
1
3
1
5

1
_L
32
                                                                   Total Cost

                                                                    $ 65,700

                                                                      18,100

                                                                      24,600

                                                                       3,700

                                                                      15,330
                                                                      13,200

                                                                       8,610
                                                                       1,000

                                                                      14,500
                                                                       7,600
                                                                       1,800
                                                                         500
                                                                      24,300
                                                                      28,200
                                                                      26,970

                                                                      10,080

                                                                      15,850
                                                                       4,405

                                                                      22,000

                                                                      21,830

                                                                      16,520

                                                                       7,800

                                                                      87.000

                                                                    $442,895
                  MPI   -   Average  Cost in 1974  =  $13,840

                  MPI   -   Average  Cost in 1958  =  $ 3,820
                                   860
-------
BATTERY  LIMIT ESTIMATE
TITLE: Westvaco S0£ Removal Process - 15 MW PROTOTYPE UNIT
Number of MPI's —. j-
tost indexes
958 . 1974
32 100 362


Average Cost of MPI's in 1958 = $3,820
MPI (Main Plant Items) - See Separate List
HUE (Miscellaneous Unlisted Equipment}
Basic Equipment (MPI + MUSI)
Field Erection of
Basic Equipment
Equipment Foundations
& Structural Supports
Piping
Insulation - Equipment
- Piping
Electrical
j i fiS i.VUmcn uu L. i CM
Miscellaneous
Bui 1 dings
Architectural
Structural
Building Serv.ices
(% of Arch'1! & Struct.)
Compressed Air
Electrical Lighting
Sprinklers
Plumbing
Heating
Vent 6 Air Cond.
To till Services

High - Large Pet. of Equip.
Involving Field Labor, Large
Equipment
High Predoiirina
_ J9.uJ.P_'_i. J-Ar9P_
~ Hig'h ~- Cfas"lfa7i
Amt. of La roe
nee of Mi Id Steel
Fans, 1. an'c Equip.
dling Significant
Duct'.'ork"
High - Significant Lagging
Regen. & Shift Reaction at High
Temperature
High - Significant Piping, High
Temperature
Mild Steel Equ
Solids
ip. , Heavy Drives,
Hiqh Instrumentation Required.
Solids K;:r:Jlincj
Large Process,
Top of Range
Open Air Plant with Minor
Buildings - Use of Middle of
Range
Low Amount of Building
Services - Open Air
5
9
1
2
0
"17
17*
Sub-Total Factored Items
Total Factored Items Adjusted
Direct Cost of Adsorber-Regenerator
Battery l.imvt jExcl . Taxes and Cat.)

Addn'l flattery Limit Items
Carbon Feeder, Sulfur Flaker ft Inert Gas Generator
TOTAL DIRECT COST - BATTERY LIMIT
DATE: August 6, 197-1
Factor
Est'd.
15%

19
6
82
7.8
14.5
18.5
44.5
5
22.5
3.8
224
224 '


Estimated
Cost
$ 442,900
509,300






1




1,140,800
1 ,650,000
22, /1 00
$1,672,400
    861
-------
            SUMMARY SHEET FOR EQUIPMENT COST ESTIMATION
TITLE:  Westvaco S02 Removal Process
    DATE:  August 6, 1974
 15 MW PROTOTYPE UNIT
Factor
Estimated Cost
 DIRECT COST  OF  BATTERY LIMIT

 STORAGE  AND  HANDLING


 UTILITIES
    Battery Limit Add'n, Steam and
    Elec. Available from Existing
    Power Station - Use Low B/L

 SERVICES
    Battery Limit Add'n, Minimal
    Services  Req'd.

 TOTAL  BATTERY LIMIT PLUS AUXILIARIES


 CATALYST
   Activated carbon:  \ZU% ("Adsorber
                       + Regenerator]
    (1.20)(5.7 hrs.H3.3 TPH)(800/T)
   Shift:  (200 ft.3)($26/ft.3)

TOTAL  DIRECT COST
INDIRECT COSTS
   Construction Expense     Factor of/
   Contractor's Fee         Direct
   Contingency              Costs

TOTAL DIRECT AND INDIRECT INSTALLED
    COST
  10
   4
  20
             $1,672,400
                 50,200
                 53,400
             $1,776,000
                 iR.nnn
                  5,200

             $1,799,200
     611.700

  $2,410,900
                              862
-------
                                TECHNICAL REPORT DATA
                          (Please rrod Instructions on the reverie before completing)
  REPORT NO.   ~~	

j EPA-600/2-76-135b
J4. TITLE AND SUBTITLE
 Development of the Westvaco Activated Carbon
  Process for SOx Recovery  as Elemental Sulfur,
  Volume II—Appendix
7.AUTHOR(s»G.N.  Brown,  C.M.  Reed, A.J. Repik,
 R. L.  Stallings,  andS.L.  Torrence
8. PERFORMING ORGANIZATION REPORT NO
3. RECIPIENT'S ACCESSION-NO.
5. REPORT DATE
 May 1976
6. PERFORMING ORGANIZATION CODE
9. PERFORMING ORGANIZATION NAME AND ADDRESS
 Westvaco
 Charleston Research Center
 Box 5207, North Charleston, SC 29406
10. PROGRAM ELEMENT NO.
1AB013; ROAP 21ACX-085
11. CONTRACT/GRANT NO.
 68-02-0003
 12. SPONSORING AGENCY NAME AND ADDRESS
                                                      13. TYPE OF REPORT AND PERIOD COVERED
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC 27711
13. TYPE OF REPORT ANt
Final; 1/71-6/74
14. SPONSORING AGENCY CODE
 EPA-ORD
is.SUPPLEMENTARY NOTES Project officer for this repOrt is D. A. Kemnitz, Mail Drop 62,
 Ext 2557.
16. ABSTRACT -phc report gives results of a demonstration (in a 20,000-cfh integral pilot
 plant) of an all-dry, fluidized-bed process, using activated carbon for recovering
 SO2 as elemental sulfur. Granular carbon was recycled continuously more than 20
 times between contact with flue gas from an oil-fired boiler and carbon regeneration
 to recover sulfur. During the 315-hour run, carbon performance remained high with
 essentially no chemical and low mechanical losses. Over 90% of the 2000 ppm SOx
 was removed from the flue gas as sulfuric acid by catalytic oxidation and subsequent
 hydrolysis within the carbon granule.  In the two-step regeneration: (1) the acid was
 converted to elemental sulfur at 300F with internally produced H2S,  and (2) an exter-
 nal source of hydrogen at 1000F was used to thermally strip the by-product sulfur
 from the  carbon and produce the required H2S by reaction with the remaining sulfur
 on carbon. Sufficient process and design information was developed from data ob-
 tained in  the integral run and prior stepwise pilot equipment operation to permit
 scale-up  to a 15-MW prototype for a coal-fired boiler. In the preliminary design,
 reducing  gas is produced in a coal gasifier. An economic assessment of a 1000-MW
 conceptual design for  the process indicates  capital and operating costs competitive
 with those of other regenerable systems.
U 	 	 	 —
17..
KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
[ Air Pollution
Flue Gases
Activated Carbon
Sulfur Oxides
Fluidized Bed
Processing
18. DISTRIBUTION STATEMENT
Unlimited
EPA Form 2220-1 (9-73)
Regeneration
(Engineering)
Fuel Oil
Sulfuric Acid
Catalysis
Oxidation

b. IDENTJFIERS/OPEN ENDED TERMS
Air Pollution Control
Stationary Sources
Elemental Sulfur
Westvaco Process
Catalytic Oxidation
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COSATI Field/Gioup
13B
2 IB
11G 2 ID
07B
07D
13H,07A 07C
21. NO. OF PAGES
889*
22. PRICE
863
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