EPA-600/2-76-282
December 1976
Environmental Protection Technology Series
            NATIONAL  DUST COLLECTOR  MODEL  850
                     VARIABLE  ROD  MODULE VENTURI
                                 SCRUBBER  EVALUATION
                                  industrial Environmental Research Laboratory
                                       Office of Research and Development
                                      U.S. Environmental Protection Agency
                                Research Triangle Park, North Carolina 27711

-------
               RESEARCH REPORTING SERIES

Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into five series. These five broad
categories were established to facilitate further development and application of
environmental technology. Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
Tho five series are:

     1.   Environmental Health Effects Research
     2.   Environmental Protection Technology
     3.   Ecological Research
     4.   Environmental Monitoring
     5.   Socioeconomic  Environmental Studies

This report has been assigned  to the ENVIRONMENTAL  PROTECTION
TECHNOLOGY series. This series describes research performed to develop and
demonstrate instrumentation, equipment, and methodology to repair or prevent
environmental degradation  from point and non-point sources of pollution. This
work provides the new or  improved technology required for the control and
trejitment of pollution sources to meet environmental quality standards.
                    EPA RE VIEW NOTICE

This report has been reviewed by the U.S.  Environmental
Protection Agency, and approved for publication.  Approval
doos not signify that the contents necessarily reflect the
views and policy of the Agency, nor does mention of trade
names or commercial products constitute endorsement or
recommendation for use.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.

-------
                                        EPA-600/2-76-282
                                        December 1976
  NATIONAL  DUST  COLLECTOR MODEL  850

            VARIABLE  ROD  MODULE

       VENTURISCRUBBER  EVALUATION
                          by

Seymour Calvert, Harry F. Barbarika, and Charles F. Lake

             Air Pollution Technology,  Inc.
            4901 Morena Boulevard, Suite 402
               San Diego, California  92117


                Contract No. 68-02-1869
                 ROAP No. 21ADM-029
              Program Element No. 1AB012


          EPA  Project Officer: Dale L. Harmon

       Industrial Environmental Research Laboratory
         Office  of Energy, Minerals, and Industry
           Research Triangle Park, NC 27711


                     Prepared for

      U.S. ENVIRONMENTAL PROTECTION AGENCY
           Office of Research and Development
                 Washington, DC 20460

-------
                         ABSTRACT

     The performance of a National Dust Collector Model 850
variable rod module venturi scrubber was measured at an in-
dustrial installation.  Fine particle collection efficiency
as a function of particle size was computed from the data
taken.
     The scrubber tower was operated at 1,010 Am3/min at
35°C with a total pressure drop of 224 cm W.C. (88 in W.C.)
with a pressure drop across the venturi module of 178 cm
W.C. (70 in W.C.).  The emission source was an iron cupola
which processes ductile iron and gray iron, with the later
producing a higher grain loading than the former.
     The ductile iron source particulates had a mass mean
diameter range of 0.25 to 0.84 ymA with a standard deviation
range of 1.5 to 2.0.  The gray iron source particulates had
a mass mean diameter range of 0.54 to 1.9 ymA with a standard
deviation range of 1.5 to 1.8.
     The overall average collection efficiency for ductile
iron melting was 98.7% and for the gray iron melting the
average collection efficiency was also 98.7% even though
the cupola emission is lower for ductile iron than for gray
iron melting.
                             111

-------
                     TABLE OF CONTENTS
Abstract	iii
List of Figures	   v
List: of Tables	vii
List, of Abbreviations and Symbols	ix

Sect ions
Introduction  	   1
Conclusions ..... 	   2
Source and Control System 	   3
Test Method	   7
Conditions for Runs	10
Operating Conditions	  12
Cascade Impactor Particle Data	  13
Diffusion Battery Data	  16
Particle Penetration	  17
Opacity	  22
Economics	  23
Operating Problems	  25
Mathematical Model	  26

References	  32
Appendix A	  33
Appendix B	  48
                            IV

-------
                       LIST OF FIGURES
No.


 1        Schematic  Flow Diagram  of  Scrubbing
          System	   4
 2        Schematic  of Scrubber Tower	   5
 3        Modified E.P.A. Sampling Train with
          In-Stack Cascade Impactor	   8

 4        Penetration versus Aerodynamic Particle
          Diameter for Ductile Operation 	  19

 5        Penetration versus Aerodynamic Particle
          Diameter for Gray Operation	  20

 6        Actual and Predicted Particle Penetration
          versus Aerodynamic Particle Diameter for
          Ductile Operation	28

 7        Actual and Predicted Particle Penetration
          versus Aerodynamic Particle Diameter for
          Gray Operation	29

A-l       Inlet and Outlet Size Distribution
          for Run 2	39

A-2       Inlet and Outlet Size Distribution
          for Run 3. . .  .	39

A-3       Inlet and Outlet Size Distribution
          for Run 4  (heated inlet cascade impactor) ...  40

A-4       Inlet and Outlet Size Distribution
          for Run 5	40
A-5       Inlet and' Outlet Size Distribution
          for Run 6  (heated inlet cascade impactor) ...  41

A-6       Inlet and Outlet Size Distribution
          for Run 7	41

A-7       Inlet and Outlet Size Distribution
          for Run 8	42

A-8       Inlet and Outlet Size Distribution
          for Run 9	42
A-9       Inlet and Outlet Size Distribution
          for Run 10 (heated inlet cascade impactor)   .  .  43

A-10      Inlet and Outlet Size Distribution
          for Run 11 (heated inlet cascade impactor)   .  .  43
                              v

-------
No.                                                    Page

A-ll     Inlet and Outlet Size Distribution
         for Run 12(heated inlet cascade  impactor).  .  .  44
A-12     Inlet and Outlet Size Distribution
         for Run 13	44

A-13     Inlet and Outlet Size Distribution
         for Run 14	45

A-14     Inlet and Outlet Size Distribution
         for Run 15	45
A-15     Inlet and Outlet Size Distribution
         for Run 16 and 16P 	
A-16     Inlet and Outlet Size Distribution
for Run 16 and 16P	46
         for Run 17 (heated inlet cascade impactor)
                                                         46
A-17     Diffusion Battery Data for Ductile
         Operation	

A-18     Diffusion Battery Data for Gray
         Operation	
                              VI

-------
                       LIST OF TABLES
No.

 1       Test Run Summary . .  . .x	11

 2       Operating Conditions 	  12

 3       Inlet and Outlet Size Distribution Summary  .  .  14

 4       Overall Penetration Summary	21

 5       Opacity Summary	22


A-l      Inlet and Outlet Size Distribution Data
         for Run 1	34
A-2      Inlet and Outlet Size Distribution Data
         for Run 2	34

A-3      Inlet and Outlet Size Distribution Data
         for Run 3	34

A-4      Inlet and Outlet Size Distribution Data
         for Run 4	34
A-5      Inlet and Outlet Size Distribution Data
         for Run 5	35

A-6      Inlet and Outlet Size Distribution Data
         for Run 6	35

A-7      Inlet and Outlet Size Distribution Data
         for Run 7	35

A-8      Inlet and Outlet Size Distribution Data
         for Run 8	35

A-9      Inlet and Outlet Size Distribution Data
         for Run 9	36

A-10     Inlet and Outlet Size Distribution Data
         for Run 10	36

A-ll     Inlet and Outlet Size Distribution Data
         for Run 11	36

A-12     Inlet and Outlet Size Distribution Data
         for Run 12	36
                             VII

-------
No.                                                    Page

A-13     Inlet and Outlet Size Distribution Data
         for Run 13	   37

A-14     Inlet and Outlet Size Distribution Data
         for Run 14	   37

A-15     Inlet and Outlet Size Distribution Data
         for Run 15	   37

A-16     Inlet and Outlet Size Distribution Data
         for Run 16	   37

A-17     Inlet and Outlet Size Distribution Data
         for Run 16P	   38
A-18     Inlet and Outlet Size Distribution Data
         for Run 17	   38
                             Vlll

-------
           LIST OF ABBREVIATIONS AND SYMBOLS

 Latin
 C1  - Cunningham slip correction factor
 d,  - drop diameter, cm
 d   - particle diameter, ym
d    - aerodynamic particle diameter, ymA
 pa
d    - geometric mass mean particle diameter, ym or ymA
 IT O
 Fj  - correction factor, dimensionless
 £   -  throat length, cm
 AP  -  pressure, cm W.C.
 QG  -  gas flow rate, cm3/sec
 QL  -  liquid flow rate, cm3/sec
  r  -  rod radius, cm
  T  -  temperature, °C
UG   -  gas velocity in the throat, cm/sec

Greek
                                              ,  1/2
ymA  -  aerodynamic particle diameter, ym (g/cm )
 p   -  particle density, g/cm3
 a   -  geometric standard deviation of particle  size distribution
  6
                             IX

-------
                       INTRODUCTION

     Air Pollution Technology, Inc. (A.P.T.) conducted
a performance evaluation of a National Dust Collector
Model 850 variable rod module venturi scrubber in accor-
dance with E.P.A. Contract No. 68-02-1869, "Fine Particle
Scrubber Evaluations."
     The objective of the performance test was to deter-
mine fine particle penetration as a function of particle
size and scrubber parameters.
     Simultaneous inlet and outlet particle sampling
measurements were taken on the scrubber during a test
period from August 19, 1975 to August 28, 1975.
     In-stack cascade impactors, total filters using
impactor blank runs, condensation nuclei counters and
a portable diffusion battery were used to obtain mass
loadings and size distribution data.  The results of
these series of tests on the National Dust Collector
Model 850 variable rod module venturi scrubber  are pre-
sented in the text.

-------
                     CONCLUSIONS

     Experimental test results are presented for a National
Dust Collector Model 850 variable rod module venturi scrubber
treating emissions from a cupola melting ductile iron and
gray iron.  The scrubber tower operated at a total system
pre.ssure drop of 224 cm W.C. while the venturi module sec-
tion pressure drop was 178 cm W.C.  Overall particle pene-
tration ranged from 1.0% to 2.0% for ductile operation and
1.0',; to 1.6% for gray operation.  Average overall particle
penetration was 1.3% for both the gray and ductile iron
melting.
     The particle penetrations for both ductile and gray
operations at various particle diameters were compared to
predicted results.  Agreement was reasonable for particles
with a diameter greater than 0.8 umA. The actual particle
penetration for particles smaller than 0.8 ymA was less than
tha-; predicted, based on inertial impaction alone.
     Some particle growth prior to the venturi rod module
could have occurred to account for the increase in actual
efficiency at the smaller sizes.  Particle collection due
to flux/condensation effects in the cooling section of the
tower could also have contributed to the collection effi-
ciency of the fine particles.
     Economic data were supplied by the user for 1967 in-
stallation and operation.  Total initial costs \vere $556,000
while the total annual costs were $96,000.

-------
                SOURCE AND CONTROL SYSTEM

     The emission source was an iron cupola which operated
for ten hours per day.  The cupola melted both the relatively
clean ductile iron and the dirtier gray iron.
     The primary component of the scrubbing system was a
National Dust Collector Model 850 variable rod module ven-
turi scrubber.  The nominal capacity was 623 m3/min at 21°C
(22,000 CFM at 70°F).   The variable rod module could be
operated at pressure drops from 100 to 230 cm W.C. (40 to
90 inches W.C.).  The venturi module consisted primarily of
several parallel rods positioned normal to the gas flow. The
gas was moved through the scrubber by two induced draft Buf-
falo 91 blowers used in series.  Each blower, run by a 261
kW (350 HP) motor, was capable of drawing 114 cm W.C. (45
inches W.C.).
     The overall scrubbing system is shown in Figure 1.  Gas
flow from the cupola is controlled by adjusting the combus-
tion air flow.  The charge door is usually open so air con-
tinually leaks into the cupola tower.  The temperature at
the top of the cupola tower is only about 175-205°C instead
of the usual 870°C temperature encountered with most cupolas.
     A series of quench sprays are introduced at the entrance
of the connecting duct between the cupola tower and the scrub-
ber.  About 350 £/min of fresh water is used in the quench
section.  The temperature of the gas is reduced to about 35°C
by the quench sprays.   The gas is saturated when it reaches
the scrubber.
     As shown in Figure 2, the scrubber consists of the fol-
lowing sections:
     1. A pre-spray section which sprays scrubbing liquor
into the gas stream at the rate of 470 5,/min.  This pre-
spray has slight cooling effect, which may cause some con-

-------
      To
 Atmosphere
GO
C
•H
C W
0)  C
X rt
rt
^
•i->
CO
c
•rt
£
     E C
     
-------
 Gas Outlet
   18-21°C
       Cooling
        Decks
Separator  Deck
Collector  Deck
 Variable  Rod
    Module
                        15°C
                           r T


0Q0Q0Q0000°0Q
                   11	i_
                       1,700 £/min
                         35°C
                        	U
                         470 £/min
                         35°C
                     Cooling Water
                        Sprays
                       Cooling Water
                          Return

                       Scrubber Liquor
                          Return
                      .Scrubber Liquor
                       Spray

                        Pre-Scrubber
                      /Liquor  Spray

                        »—-  Gas Inlet
                            1,010  AmVmin
                            35°C
                Quench/Scrubber  Liquor
                       Return
       Figure 2.  Schematic  of  scrubber tower

-------
densation growth of the particles, and it may collect some
particles as it settles out onto the bottom of the scrubber
tower.  The drops from these sprays are not carried through
to the variable rod module.  The liquor returned from this
section is sent to the sludge tank.
      2. The high energy section, which consists of a scrub-
ber liquor spray of 1,700  5,/min and the variable rod module
is  next.  The pressure drop across the variable rod module
is about 178 cm W.C. when  the total pressure drop across
the whole tower is 224 cm W.C.  The temperature of the scrub-
ber liquor is about 35°C and the ratio of liquid to gas vo-
lume  flow rates in this section is about 1.68 £/m .
      3. The collector deck, consisting of 7.6 cm of loose
2.5 cm diameter marbles, separates out the entrained liquid
from  the high energy section.  The returned scrubbing liquor
is split into two streams, with 80 percent going to the
recycle tank and 20 percent going to the sludge tank.
      4. Above the collector deck is a plate which collects
the water from the cooling section.
      5. The gas is cooled prior to leaving the scrubber
tower in a cooling section consisting of sprays and two
decks of single layer 2.5 cm diameter marbles.  The cooling
water is supplied at about 15°C at the rate of 6,740 £/min
to cool the gas to about 18-21°C.  There is no carryover of
entrainment from the cooling section.

-------
                         TEST METHOD

     The performance characteristic of the National Dust
Collector Model 850 variable rod module venturi scrubber
was determined by measuring the particle size distribution
and mass loading of the inlet and outlet gas sample simul-
taneously.
     For the tests performed in August 1975, modified
E.P.A. type sampling trains with in-stack University of
Washington Mark III (U.W.) cascade impactors were used
for particle measurements above 0.3 ymA.  Figure 3 shows
a schematic diagram of the modified sample train.  Greased
aluminum substrates were used in the impactors to prevent
particle bounce and minimize wall losses.  Low velocity
impactor jet stages were used for the majority of test
runs on the inlet sampling to increase the sampling time.
     The Air Pollution Technology portable screen diffu-
sion battery (A.P.T.-S.D.B.) was used for particle mea-
surements from 0.1 ym to 0.01 ym (actual).
     The A.P.T.-S.D.B. uses Brownian diffusion to accom-
plish the size fractionation of particles smaller than
~0.1 ym.  Because smaller particles diffuse more readily
than larger ones, successively larger particles are cap-
tured as they proceed through the battery.
     Using a condensation nuclei counter  (CNC) to deter-
mine the total number of particles at various points in
the battery, one can obtain data which will correspond to
a unique size distribution.  The size distribution compu-
tation was based on calibration of the S.D.B. in the A.P.T,
laboratory.
     Computation of size distributions from the data on
penetration was accomplished through the use of measure-
ments of density, pressure, temperature, flow rate, and
moisture, in addition to the CNC calibration factors.

-------
oo
a
                                          THERMOMETER
                          CASCADE
                          IMPACTOR
                                  STACK
                                  WALL
                                             w?
                                          r
                                                        IMPINGER TRAIN
                                ~\
                                          I	ICE_BA.TH	|
                                        THERMOMETERS
                                                              r~  1 JROTOMETER
                                                                     VACUUM
                                                                     GAUGE
                        ORIFICE METER
 DRY GAS METER  VACUUM
                PUMP
SILICA
 GEL
DRYER
            Figure 3.   Modified  EPA  sampling train with in-stack cascade  impactor.

-------
     During an impactor run, inlet or outlet fine particle
size measurements were taken with the portable diffusion
battery.  Since the system remained fairly constant during
the test period, inlet and outlet S.D.B. measurements on
different days were considered to approximate simultaneous
sampling.
     Impactor blank runs on the outlet were performed
periodically to insure that the greased aluminum substrates
did not react with the stack gases.  A blank impactor run
consisted of an impactor preceded by two glass fiber filters
run at identical sample conditions as the actual sampling
runs.
     Gas flow rates for all tests were determined by means
of a calibrated standard-type pitot tube along with in-
stack taps for continuous wet and dry bulb temperature
measurements.  Velocity traverses of the inlet and outlet
were performed according to the E.P.A. standards and
average velocity points selected for one-point sampling.
Sample flow rates were measured with the usual E.P.A.
train instruments so as to obtain isokinetic sampling.
      The  inlet  sample  port  was  located  five  duct  diameters
 downstream  from the  connecting  duct  entrance and  one  diameter
 upstream  of  the scrubber  inlet.  The  outlet  port was  located  in
 the outlet stack one duct diameter after a  section of  straight-
 ening vanes.  Straightening vanes were  installed  to counteract
 the tangential  spin  of  the  gas  caused by the tangential  inlet
 port  to  the  stack.   Sampling of  the  outlet  could  not be  done
 directly  after  the scrubber  (before  the  fans) because  of the
 high  negative pressure  which the  sampling train pump could
 not   handle.  Velocity  traverses  of  the  inlet revealed fully
 developed flow  while the outlet  traverse indicated that  the
 gas still had some tangential velocity  component.  Therefore,
 inlet flow rate measurement should be more  reliable than
 outlet  flow  rate measurement.

-------
                   CONDITIONS FOR RUNS

     A total of seventeen simultaneous inlet and outlet
impactor sample runs was performed on the venturi scrubber.
Also, three blank impactor runs were performed and indicated
no reaction of the greased aluminum substrates with the
filtered gases.  All runs were made in-stack.  Runs 1-3,
16P, and 17 were performed with high velocity jet impactor
stages while runs 4-16 were performed with low velocity
jet impactor stages to increase the sampling time on the
inlet sample.  Runs 16 and 16P were performed on the same
day to compare low velocity jet impactor stages with high
velocity jet impactor stages.
     During ductile iron operation, the inlet cascade impac-
tors for runs 5, 15 and 16P were heated enough to remain at
stack gas temperature.  The inlet cascade impactors for runs
4, 16 and 17 during ductile operation were heated somewhat
above the stack gas temperature.  For gray operation the in-
let cascade impactors for runs 7, 8, 9, 13, and 14 were
maintained at the stack temperature, while those for runs
6, 10, 11, and 12 were heated. These two types of cascade
impactor samples were taken at the inlet to measure the
actual diameter of the particles in the system due to the
water quench sprays prior to the inlet sampling port ver-
sus the dry particle diameter that would be measured with
a heated impactor (above source gas conditions).
     The venturi was operated at 178 cm of w.C. pressure
drop for all the runs while the total system pressure
drop was 224 cm of W.C.   As shown in Table 1, which sum-
marizes the test runs made, runs 1-5 and 15-17 were per-
formed on the ductile iron operation while runs 6-14 were
performed on the gray iron operation.
                            10

-------
                Table  1.  TEST RUN  SUMMARY
DATE
8/19/75
8/19/75
8/20/75
8/21/75
8/21/75
8/22/75
8/22/75
8/25/75
8/25/75
8/25/75
8/25/75
8/26/75
8/26/75
8/26/75
8/27/75
8/27/75
8/27/75
8/27/75
8/28/75
8/28/75
8/28/75
8/28/75
RUN
NO.
IB
1
	
2
3
4*
5
6*
7
8
2B
9
10*
11*
12*
13
3B
14
15
16*
16P
17*
OPERATION
Ductile
Ductile
Gray
Ductile
Ductile
Ductile
Ductile
Gray
Gray
Gray
Gray
Gray
Gray
Gray
Gray
Gray
Gray
Gray
Ductile
Ductile
Ductile
Ductile
SAMPLE DEVICE
Blank
C.I.
D.B.I. (IX)
C.I.
C.I.
D.B.I.(3X)
C.I.j
r T (D.B.O.(2X)
L* • i • )
C.I. }
C.I.
C.I.
Blank
C.I.
C.I.
C.I.


D.B.O.(2X)

D.B.O.(2X)
D.B.I. (IX)
C.I. '
C.I.
Blank
C.I.
C.IJ
C.I.
C.I.
C.I.

D.B.I.(SX)


D.B.I.(3X)
i
MASS LOADING
(mg/DNm3)
INLET
	
	
	
2,050
2,103
1,429
1,811
2,058
1,912
2,227
	
2,313
1,877
2,106
2,287
2,264
2,316
1,964
1,789
2,253
1,392
OUTLET
25.7
23.6
	
20.9
24.5
28.0
27.0
32.0
30.7
35.8
38.2
58.5
39.3
52.9
27.9
24.0
26.5
23.0
21.2
24.8
24.8
21.2
NOTES:  1.  C.I. = Cascade Impactor Run
        2.  D.B.I.(nX) = Diffusion Battery Run on Inlet
        3.  D.B.O.(nX) = Diffusion Battery Run on Outlet
        4.  n = Number of Runs
        5.  B = Blank Impactor Run
        6.  * = Heated Cascade Impactor Above Source Gas
                Temperature (Inlet)
                             11

-------
                    OPERATING CONDITIONS


     The operating conditions of the variable rod venturi

scrubber for the period of sampling are shown below:


            Table 2.  OPERATING CONDITIONS
CONDITION
INLET SAMPLE PORT
OUTLET SAMPLE PORT'
Temperature

Velocity

Am3/inin

ACFM

DNmVmin @ 0°C

DSCFM @ 21°C

Vol !; H20 Vapor

Stat:.c Pressure
     32-35°C

9.2 m/sec(30.3fps)

      1,010

     35,700

        772

     27,300

       6.6

   -1.1 cm W.C.
     57-66°C

25.3 m/sec(83.1fps)

      1,230

     43,500

        871

     30,800

       3.3

    +0.38 cm W.C.
Pressure Drop Across Tower

Pressure Drop Across Venturi Module

Superficial Velocity Through
Scrubber Tower (Diameter 3.12m)
based on inlet ACFM
                  224 cm W.C.

                  178 cm W.C.



                  2.19 m/sec
"Outlet sample port located in exit stack after straight-
 ening vane section used to reduce tangential spin of ga.s
 caused by inlet (tangential) to stack.  For this reason
 outlet flow rates may not be as reliable as inlet flow rates
                             12

-------
              CASCADE IMPACTOR PARTICLE DATA

     Sets of data were obtained from the variable rod
module venturi scrubber as described in the Test Method
section.  Fully developed flow enabled representative
one-point sampling.  Identical one-point sample locations
were used for all the data points.
     Particle concentration, particle size and sampled
volumes for cascade impactor runs are tabulated in the
Appendix in Tables A-l through A-18.  Size distribu-
tions for the impactor runs are given in Figure A-l
through A-16 located in the Appendix.
     A summary of the inlet and outlet size distribution
tests is given in Table 3.
     In this report, the symbol "d  " refers to aero-
dynamic diameter, which is equal to the particle dia-
meter (d ) in microns (ym) times the square root of the
particle density (p ) in grams per cubic centimeter
(g/cm3)  times the square root of the Cunningham slip
correction factor (C1).  The symbol "jjmA" represents
the units of aerodynamic size.
                 V

     The symbol "d  " refers to the geometric mass mean
                  tr o
aerodynamic particle diameter for a given size distribution
     Average sample times for the inlet were three to
four minutes depending on the mass loading, while the
outlet sample times averaged approximately forty-five
minutes to one hour.
                           13

-------
   Table 3.   INLET AND OUTLET SIZE DISTRIBUTION SUMMARY
           OPERATION           INLET           OUTLET
                                    ag      V ymA
1
2
3
4(1)
5
6(2)
7(3)
8C4)
g(5)
10
11
12
13(6)
14
15^
16
16P
17
Ductile
Ductile
Ductile
Ductile
Ductile
Gray
Gray
Gray
Gray
Gray
Gray
Gray
Gray
Gray
Ductile
Ductile
Ductile
Ductile

0.69
0.76
0.25
0.27
1.10
1.51
0.56
0.54
0.62
1.90
0.62
0.59
0.72
0.84
0.58
0.71
0.49

. 2.0
2.0
1.6
1.5
1.7
1.8
1.6
1.5
1.6
1.6
1.6
1.6
1.6
1.6
1.5
1.7
1.8
0.48
0.52
0.52
- 0.52
0.56
0.58
0.56
0.52
0.63
0.63
0.81
0.51
0.51
0.52
0.50
0.48
0.48
0.49
1.7
1.8
1.9
1.8
1.8
1.7
1.8
1.6
.1.6
1.7
1.7
1.6
1.6
1.5
1.7
1.7
1.7
1.7
(1)   Run 4  had 40%  of the 5th stage holes plugged on the
     inlet  sample.
(2)   Run 6  had 301  of the 3rd stage holes plugged on the
     inlet  sample.
(3)   Run 7  had 30%  of the 6th stage holes plugged on the
     inlet  sample.
(4)   Run 8  had 20%  of the holes plugged on stage 6 of the
     inlet  sample.
(5)   Run 9  had 30%  of the holes plugged on the inlet 6th stage.
(6)   Run 13 had four holes plugged on both the inlet 5th and
     6th stages.
(7)   Run 15 had 50% of the holes plugged on the inlet 4th stage,


                             14

-------
      Isokinetic sampling was undertaken for all the test
runs; however, isokinetic conditions are not that crucial
for sampling fine particles.  For example, the error
caused by sampling 4 ymA particles at a velocity 501
higher or lower than the gas stream velocity would only
be about 2 or 3% of the concentration.
      Single point sampling is also generally sufficient
when  measuring fine particle size and concentration.  The
fine  particles will be distributed well in the gas stream,
except in cases where streams with different particle
concentrations have not had sufficient time to mix.  To
illustrate that one-point sampling is sufficient for fine
particles, we may note that Stokes stopping distance of
a 3 ymA particle with an initial velocity of 15 m/sec
(50 ft/sec) is about 0.04 cm (0.016 inches) and for a
1 ymA diameter particle is one-ninth of that.  Since the
stopping distance is the maximum that a particle can be
displaced from a gas streamline by going around a right
angle bend, it becomes apparent that fine particle dis-
tribution in the gas stream will be negligibly affected
by flow direction changes.
     No inlet data were obtained for run 1 due to the ex-
cessive vacuum pulled at the start of the run which over-
loaded the impactor.
     Runs 9, 10, and 11 were not used as part of the data
set because two of the five spray nozzles in the scrubber
liquor spray section were disconnected while these runs were
being made.
    Analysis of the data from the inlet cascade impactor
runs was made to determine the effect heating the impac-
tors above the stack temperature had on the size distri-
butions.  No definite trend of the heated impactor runs
toward smaller size distributions than the unheated im-
pactor runs could be seen.

                           15

-------
                  DIFFUSION BATTERY DATA

     Diffusion battery data were taken during August 20 to
August 28, 1975.  The runs were made alternately on inlet
and outlet sample locations as shown in Table 1, while
impnctor runs were being performed.
     Since operation of the scrubber was fairly constant
over the testing period the inlet and outlet samples were
averaged resulting in one set of data each for the ductile
and gray operations.
     Figures A-17 and A-18 in the Appendix contain the inlet
and outlet size distributions for the various tests made.
Diffusion battery penetration data are discussed in the
particle penetration section.
                           16

-------
     Isokinetic sampling was undertaken for all the test
runs; however, isokinetic conditions are not that crucial
for sampling fine particles.  For example, the error
caused by sampling 4 ymA particles at a velocity 501
higher or lower than the gas stream velocity would only
be about 2 or 3% of the concentration.
     Single point sampling is also generally sufficient
when measuring fine particle size and concentration.  The
fine particles will be distributed well in the gas stream,
except in cases where streams with different particle
concentrations have not had sufficient time to mix.  To
illustrate that one-point sampling is sufficient for fine
particles, we may note that Stokes stopping distance of
a 3 ymA particle with an initial velocity of 15 m/sec
(50 ft/sec) is about 0.04 cm (0.016 inches) and for a
1 ymA diameter particle is one-ninth of that.  Since the
stopping distance is the maximum that a particle can be
displaced from a gas streamline by going around a right
angle bend, it becomes apparent that fine particle dis-
tribution in the gas stream will be negligibly affected
by flow direction changes.
     No inlet data were obtained for run 1 due to the ex-
cessive vacuum pulled at the start of the run which over-
loaded the impactor.
     Runs 9, 10, and 11 were not used as part of the data
set because two of the five spray nozzles in the scrubber
liquor spray section were disconnected while these runs were
being made.
    Analysis of the data from the inlet cascade impactor
runs was made to determine the effect heating the impac-
tors above the stack temperature had on the size distri-
butions.  No definite trend of the heated impactor runs
toward smaller size distributions than the unheated im-
pactor runs could be seen.

                           15

-------
                  DIFFUSION BATTERY DATA

     Diffusion battery data were taken during August 20 to
August 28, 1975.  The runs were made alternately on inlet
and outlet sample locations as shown in Table 1, while
impactor runs were being performed.
     Since operation of the scrubber was fairly constant
ove.r the testing period the inlet and outlet samples were
averaged resulting in one set of data each for the ductile
and gray operations.
     Figures A-17 and A-18' in the Appendix contain the inlet
and outlet size distributions for the various tests made.
Diffusion battery penetration data are discussed in the
particle penetration section.
                           16

-------
                  PARTICLE PENETRATION

    Particle penetration versus particle aerodynamic
diameter was computed and is shown in Figures 4  and 5
for ductile and gray iron operations respectively.
Penetrations for a few of the runs are not shown because
either their size distributions or their total loadings
were outside a standard deviation from the mean of the
set of data within which the run belonged.
    The penetrations were calculated by a computer pro-
gram which uses a mathematical formula based on the log-
normality of the inlet and outlet size distributions.
Previous calculations of penetrations have been done by
manually and visually determining the ratio of the slopes
of the outlet and inlet cumulative mass versus particle
size curves at different particle sizes.  Within the li-
mits of the particle sizes measured, the accuracy of the
log-normal penetration equation depends only on how well
the data fit log-normal distributions.  Since the particle
size data have many other inaccuracies because of the dif-
ficulties of measurement, the log-normal penetration is
accurate enough, considering the ease with which it can
be used.  It is also most advantageous to eliminate the
subjective errors possible with the visual method.  How-
ever, when the data are not log-normal the manual method
of determining penetration must be used.
    Diffusion battery data yield penetration related to
physical size while cascade impactor data are in terms of
aerodynamic size.  In order to put the results on the same
basis, it is necessary to know the particle density so
that one can convert physical size to aerodynamic size
                            17

-------
(or vice versa).   In Figures 4 and 5 a value of 3 g/cm3 for
density has been used to convert the physical diameter based
on calculated diffusion battery penetrations to penetrations
based on aerodynamic particle diameter.
    The penetration plots indicate an increase in effi-
ciency for particles smaller than 0.2 ymA.  From these re-
sults and published literature, it is evident that smaller,
more highly diffused particles experience increased col-
lection efficiency.
    An overall penetration summary for runs 1 through 17
is presented in Table 4.  Total inlet and outlet mass
loadings were taken by cascade impactors.
    Although Figures 4 and 5 show penetrations for ductile
and gray iron operations separately, there was no signi-
ficant difference in the penetrations between the two oper-
ations.  Likewise, the average overall penetration for both
the ductile operations and the gray operation was 1.31.
                           18

-------
                 Diffusion
                 Battery
0.001
    0.1     0.2       0.5    1.0     2.0      5.0

          PARTICLE AERODYNAMIC DIAMETER, ymA

Figure 4.   Penetration versus aerodynamic particle
           diameter for ductile operation.
                    19

-------
    1.0
    0.5
    0.1
c>
oi  0.05
ul
o
m
2;
m
P.
   0.01
  0.005
                    Diffusion

                    Battery
  0.001


        0.1     0.2        0.5     1.0      2.0       5.0


             PARTICLE  AERODYNAMIC  DIAMETER, ymA



 :igure  5.   Penetration  versus  aerodynamic particle

            diameter for gray operation.
                       20

-------
Table 4.  OVERALL PENETRATION SUMMARY
RUN
NO.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
16P
17
MASS LOADING
mg/DNm3
INLET
	
2,050
2,100
1,430
1,8.10
2,060
1,910
2,230
2,310
1,880
2,100
2,290
2,260
2,320
1,960
1,790
2,250
1 ,390
OUTLET
23.6
20.9
24.5
28.0
27.0
32.0
30.7
35.8
58.5
39.3
52.9
27.9
24.0
23.0
21.2
24.8
24.8
21.2
OVERALL, Pt
1
	
1.02
1.17
1.96
1.49
1.55
1.61
1.61
2.53
2.09
2.51
1.22
1.06
0.99
1.08
1.39
1.10
1.52
                 21

-------
                           OPACITY

     Opacity for the outlet stack of the National Dust
Collector Model 850 variable rod module venturi scrubber
were taken by employees trained and certified by the State
Air Quality Control Sections.  Readings were made five
times a day from 8:00 a.m. to 4:00 p.m. every two hours.
     A summary of the daily average reading is presented
below in Table 5:

                Table 5.  OPACITY SUMMARY
DATE
8/19/75
8/20/75
8/21/75
8/22/75
8/25/75
8/26/75
8/27/75
8/28/75
Average
for Test
AVERAGE OPACITY, %
13
11
8
11
25
33
2
13
15
                             22

-------
                         ECONOMICS

     The cost of installing and operating air pollution
equipment is a function of many direct and indirect cost
factors.  These factors can be grouped into two cost cate-
gories initial costs and annual operating costs.
     Cost data for the initial and annual cost was supplied
by the user.  The unit was originally built in 1967 as a
fixed hole orifice venturi and in early 1975 was modified
to a variable rod module type to alleviate plugging prob-
lems.  Shown below are the cost factors for the unit.
F.O.B. shipping and delivery charges were not available,
but should be about $15,000.

  Scrubber § Auxiliaries
    a. Fans, motors and motor starters          $136,200
    b. Ducting                                    88,000
    c. Liquid and solid handling and treatment    45,000
    d. Instrumentation                             7,800
    e. Electrical material                        55 ,000
                                         Total  $332,000
  Scrubber Installation Cost
    a. Erection                                 $120,600
    b. Plumbing                                   61,900
    c. Electrical                                 36,000
    d. Engineering                                15,500
                                         Total  $234,000

  Total Initial Cost (1967 prices)              $566,000
                            23

-------
Annual Costs include the following factors:

Operating Costs
  a, Utilities                                  $ 37,000
  b. Labor                                        20,000
  c. Supplies and materials                       12,000
  d. Treatment and disposal                        4,000
                                         Total  $ 73,000
Maintenance Costs
  a. Labor                                      $ 10,000
  b. Materials                                     6,000
                                         Total  $ 16,000
Plant Overhead, Space, Heat,
 Light, Insurance                               $  7,000

Total Annual Costs                              $ 96,000
                           24

-------
                   OPERATING PROBLEMS

    The primary operating problems of the scrubber were
alleviated when a fixed orifice venturi high energy
section was replaced with the present variable rod module
section.  Impurities in the scrap iron had caused plug-
ging of the fixed orifices.
                           25

-------
                 MATHEMATICAL  MODEL

    The venturi rod scrubber is essentially several Ven-
turis or orifices connected in parallel.  The performance
of venturi-type scrubbers has been modeled extensively.
The most recent survey and model are by Calvert, et al
1976, which will be used here, (see Appendix B).
    The pressure drop is,

    AP = 1.03 x 10"3 FX Ugt (—]                  (2)
                              G
where:
    AP = pressure,  cm W.C.
   u.p  = gas velocity in the throat, cm/sec
     k
    Q  = liquid flow rate, cm3/sec
    Qp = gas flow rate, cm3/sec
    F  = correction factor, dimensionless

The correction factor, "Fj" is the ratio of the drop ve-
locity at the end of the throat to the throat gas velo-
city.  This ratio is a function of the throat length,
drop size, and the throat gas velocity.  Since a geo-
metric description of the throat region is not available,
throat length, drop size, and throat gas velocity must
be estimated.  The pressure drop across the venturi is
known (178 cm W.C.), as is the liquid to gas flow rate
ratio (0.00168).
    The approach taken was to assume certain values of
"F " (which is equivalent to assuming certain throat
lengths)  in order to calculate the theoretical penetra-
tions and then relating these throat lengths to a pro-
bable geometry of the venturi rod module.   The assumed
                            26

-------
values and the resultant values of other parameters,
using equation (2) and Appendix B are as follows:
F
0.5
0.75
1.0
*t
cm
5.5
24
oo
uGt
m/s
143
117
101
dd
cm
0.0088
0.0096
0.0103
    Using the above table and the theoretical equation
for penetration presented in Appendix B, three penetra-
tion curves were generated.   These curves are shown as
the dashed lines in Figures  6 and 7.  The solid lines
are the penetrations calculated from the inlet and out-
let cascade impactor data previously presented in Fi-
gures 4 and 5.  It is obvious from the figures that
the correction factor, "F!", is probably around 0.75.
This value of "F " and the corresponding throat length
(24 cm) can be related to the venturi rod geometry in
the following manner:
    1.  Assume spacing between the parallel rods is
       equal to the rod radius.
    2.  Assume the angle of divergence of the jets be-
       tween the rods is 20  degrees, as given in Perry,
       1963 for two dimensional turbulent free jet.
    3.  Assume the throat begins one radius upstream
       of the plane of the rod centerline.
    4.  Assume the throat ends where adjacent jets
       intersect, based on the 20 degree jet diver-
       gence angle.
    The formula for the radius of a rod would then be,

    r = £/ (1 +  cot  10°)                     (3)
                            27

-------
     1.0
     0.5
o
IH
Ir-i
U
li,
o
tz;
     0.1
0.05
    0.01
   0.005
   0.001
                 0.2       0.5      1.0      2.0      5.0

               PARTICLE AERODYNAMIC DIAMETER, ymA

      Figure 6.  Actual  and predicted particle penetration
                 versus  aerodynamic particle diameter for
                 ductile operation.
                       28

-------
   0.001
Figure 7.
          1    0.2       0.5     1.0    2.0

             PARTICLE AERODYNAMIC DIAMETER, ymA
                                       5.0
Actual and predicted particle penetration versus
aerodynamic particle diameter for gray operation,
                      29

-------
So, for £  = 24 cm, the rod radius would be 3.6 cm and
the rod diameter would be 7.2 cm (2.8 inches).   This rod
diameter is within reason, but it should be noted that
it i:> only a very rough estimate, based on the  fit between
penetration data and theory and the four assumptions
listed above.  The fourth assumption probably overesti-
mates the throat length.
     The model used here assumes that collection is by
inertial impaction on drops, occurring only in  the throat
region of the venturi.  The data agree with the model in
the range of 0.8 to 2.0 ymA diameters but show  greater
efficiency below 0.8 ymA.  Thus, the model is fairly
close for the larger particles of interest.  However,
the particles smaller than 0.8 ymA diameter are less af-
fected by inertia than by other forces, such as diffu-
siophoresis, thermophoresis and Brown i.an motion. Diffu-
siophoresis, and thermophoresis, two of the flux/conden-
sation (F/C) mechanisms are effective in regions where
the liquid spray drops are cooler than the gas  and the
gas is saturated.  Some condensation may have caused
particle growth between the inlet sampling port and the
variable rod module.  Here the pre-scrubber sprays may
have been a few degrees cooler than the gas, so that
enough particle growth could have occurred prior to the
venturi rod module to increase the collection efficiency
of the smaller particles.
     In the cooling section of the tower F/C effects could
have caused the cooling spray drops to collect  fine parti-
cles,  The cool ing'spray water temperature was  about 20°C
lower than the gas temperature.  Collection by  Brownian
diffusion is less efficient on a mass basis than the
other types and would not be important in the size regime
that was measured in these tests.
                             30

-------
     Another section of the system where small particle
collection could have occurred was the section containing
the two blowers in series.   The high velocity and extreme
turbulence in the blowers may have been effective in cau-
sing particle collection.
                            31

-------
                      REFERENCES
Calvert, S.,  S.  Yung,  and H.F.  Barbarika,  "Venturi
     Scrubber Performance Model," A.P.T.,  Inc.,  San
     Diego,  California.   EPA Contract  No.  68-02-1328,
     Task No. 13,  July 1976.

Perry, J.H.,  Chemical Engineer's Handbook, 4th Ed.,
     1963.
                            32

-------
      APPENDIX A






Size Distribution Data
           33

-------
Table A-l.   INLET AND OUTLET SIZE DISTRIBUTION DATA
            FOR RUN »1
TMHArr™
STAGE
NUMBER
Precutter
§ Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET
M
cum
(mg/DNm3)
	
	
. . _
	
	
	
	
	
...
dpc
(ymA)
	
	
	
	
	
	
	
	
---
...
OUTLET
Mcum
(mg/DNm3)
23.6
23.5
23.5
23.5
23.1
22.6
22.6
13.8
4.9
dpc
(pmA)
	
19.8
8.7
3.4
1.7
0.97
0.54
0.31
...
. 0.810
Table A-2.
INLET AND OUTLET SIZE DISTRIBUTION DATA
FOR RUN 92
IMFACTOR
STAGE
NUMBER

Precutter
5 Nozzle
1
2
3
4
S
6
7
Filter
Sample
Volume
INLET

Mcum
(mg/DNm3)
2,050
2,050
2,030
2,030
2,000
1,910
1,690
1,140
435

Pc
(umA)
	
26.1
11.4
4.4
2.2
1.3
0.71
0.43
---

0.039
OUTLET

Mcum
(mg/DNm3)
20.9
20.9
19.7
19.3
18.8
18.8
18.2
11.3
3.9

dPc
(umA)
	
20.1
8.8
3.4
1.7
0.99
0.54
0.31
...

1.036
                                                            Table A-3.   INLET AND OUTLET SIZE DISTRIBUTION DATA
                                                                         FOR RUN *3
IMF/ '"TOP,
STAGE
NUMBER
Precutter
§ Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNn3)
INLET
M
cum
(mg/DNm3)
2,100
2,100
2,080
2,080
2,060
1,910
1,760
1,280
169
d
Pc
(ymA)
	
26.6
11.6
5.5
2.3
1.3
0.72
0.43
	
0.019

OUTLET
M
cum
(mg/DNm3)
24.5
24.5
23.1
23.0
22.6
22.1
21.2
11.8
5.8
d
PC
(umA)
	
19.8
8.7
3.4
1.7
0.97
0.54
0.31
	
0.796

Table A-4.  INLET AND OUTLET SIZE DISTRIBUTION  DATA
            FOR RUN #4
IMPACTOR
STAGE
NUMBER

Precutter
5 Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET
M
cum
(mg/DNm3)
1,430
1,430
1,420
1,410
1,370
1,310
1,290
1,250
517
d
pc
(umA)
	
38.7
3.3
1.9
1.05
0.63
0.35
0.20
	
0.018

OUTLET
M
"cum
(mg/DNm3)
28.0
28.0
27.0
26.8
26.5
25.7
24.5
14.4
5.5
d
pc
(ymA)
---
20.4
9.0
3.5
1.8
1.0
0.55
0.32
	
1.005


-------
       Table A-5.
INLET AND OUTLET SIZE DISTRIBUTION DATA
FOR RUN #5
Table A-7.  INLET AND OUTLET SIZE DISTRIBUTION DATA
            FOR RUN #7
IMPACTOR
STAGE
NUMBER

Precutter
§ Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET
M
cum
(mg/DNm3)
1,810
1,810
1,760
1,720
1,710
1,690
1,690
1,590
420
d
pc
(ymA)
	
38.7
3.3
1.9
1.1
0.63
0.35
0.20
	

0.009

OUTLET
M
cum
(mg/DNm3)
27.0
27.0
24.9
24.9
24.2
23.6
23.2
16.6
6.8
d
pc
(umA)
	
24.2
10.6
4.1
2.1
1.2
0.65
0.38
	

0.711

IMPACTOR
STAGE
NUMBER
Precutter
§ Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET
M
cum
(mg/DNm3)
1,910
1,910
1,840
1,820
1,810
1,740
1,620
436
268
d
PC
(umA)
	
44.8
19.6
7.6
3.8
2.2
1.2
0.73
	

0.010

OUTLET
M
cum
(mg/DNm3)
30.7
30.7
28.5
28.1
27.5
27.1
26.9
19.5
8.0
d
PC
(wmA)
	
24.2
10.6
4.1
2.1
1.2
0.65
0.38
	

0.713

en
       Table A-6.
INLET AND OUTLET SIZE DISTRIBUTION DATA
FOR RUN #6
IMPACTOR
STAGE
NUMBER

Precutter
§ Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET
M
cum
(mg/DNm3)
2,060
2,060
2,050
2,050
1,980
1,090
556
132
24.0
,
pc
(umA)
	
46.6
4.0
2.3
1.3
0.76
0.42
0.24
---

0.025

OUTLET
M
"cum
(mg/DNm3)
32.0
32.0
30.4
30.2
29.8
29.2
28.2
21.3
6.9
H
PC
(ymA)
	
24.7
10.8
4.2
2.1
1.2
0.7
0.4
	

0.691

                                                                              Table A-8.
            INLET AND OUTLET SIZE DISTRIBUTION DATA
            FOR RUN #8
IMPACTOR
STAGE
NUMBER

Precutter
5 Nozzle
1
2
3
4
5
6
7
Filter
Sample
Vo 1 ume
(DNm3)
INLET

M
cum
(mg/DNm3)
2,230
2,230
2,220
2,190
2,140
2,080
1,470
485
78.6

V
(umA)
	
42.0
3.6
2.1
1.1
0.69
0.38
0.22
	

0.015

OUTLET

Mcum
(mg/DNm3)
35.8
35.8
32.9
32.3
32.0
32.0
31.4
25.0
9.2

dPc
(vimA)
	
24.4
10.7
4.1
2.1
1.2
0.66
0.38
	

0.520


-------
Table A-9.
INLET AND OUTLET SIZE  DISTRIBUTION  DATA
FOR RUN #9
IMP AC TOR
o i/\uc
NUMBER

Precutter
§ Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET
M
cum
(mg/DNm3)
2,310
2,310
2,310
2,290
2,240
2,210
1,810
393
36.6
d
PC
(umA)
	
42.7
3.7
2.1
1.2
• 0.70
0.38
0.22
---

0.011

OUTLET
M
cum
(mg/DNm3)
58.5
58.5
56.5
56.5
56.3
56.0
54.5
35.5
10.9
d
PC
(ymA)
	
26.4
11.6
4.S
2.3
1.3
0.72
0.41
	

0 .595

Table A-10.  INLET AND OUTLET SIZE DISTRIBUTION DATA
             FOR RUN #10
IMPACTOR
STAGE
NUMBER

Precutter
5 Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET
M
cum
(mg/DNm3)
1,880
1,880
1,860
1,850
1,830
1,730
1,220
286
47.6
H
PC
(umA)
	
43.8
3.8
2.2
1.2
0.71
0.39
0.23
...

0.010

OUTLET
M
cum
(mg/DNm3)
39.3
39.3
35. 7
35.7
35.4
35.2
34.6
22.5
5.9
,
pc
(vmA)
---
24.2
10.6
4.1
2.1
1.2
0.65
0.38
	

0.529

Table A-ll,
                                                                                    INLET AND OUTLET SIZE DISTRIBUTION DATA
                                                                                    FOR RUN 011
IMPACTOR
SlAGt
NUMBER

Precutter
§ Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DMm3)
INLET
M
cum
(mg/DNm3)
2,110
2,110
" 2,090
2,070
2,030
1,900
1,380
298
18.6
d
PC
(umA)
	
43.4
19.0
7.4
3.7
2 .1
1.2
0.71
	

0.011

OUTLET
M
cum
(mg/DNm3)
52.9
52.9
51.3
50.9
50.9
50.8
50.4
31.3
10.7
d
pc
(umA)
	
24.2
10.6
4.1
2.1
1.2
0.65
0.38
	

0.524

                                                           Table A-12.
             INLET AND OUTLET SIZE DISTRIBUTION DATA
             FOR RUN #12
IMPACTOR
STAGE
NUMBER

Precutter
§ Nozzle
1
2
3
4
S
6
7
Filter
Sample
Volume
(DNm3)
INLET
Mcun,
(mg/DNm3)

2,290
2,290
2,270
2,260
2,230
2,150
1,420
378
29.8
V
(unA)

	
45.0
3.8
2.2
1.2
0.73
0.40
0.23
	

0.010

OUTLET
Mcum
(mg/DNm3)

27.9
27.9
26.1
26.1
25.9
25.7
25.5
20.8
6.9
V
(VimA)

- - -
24.7
10.8
4.2
2.1
1.2
0.67
0.39
	

0.506


-------
         Table A-13.
INLET AND OUTLET SIZE DISTRIBUTION DATA
FOR RUN #13
                                                                                 Table A-15.
INLET AND OUTLET SIZE DISTRIBUTION DATA
FOR RUN #15
IMPACTOR
STAGE
NUMBER

Precutter
§ Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET
M
cum
(mg/DNm3)
2,260
2,260
2,250
2,230
2,190
2,110
1,500
388
37.9
d
pc
(ymA)
	
43.5
3.7
2.1
1.2
0.71
0.39
0.23
---

0.011

OUTLET
M
cum
C mg/DNm3)
24.0
24.0
23.0
23.0
23.0
23.0
23.0
18.1
7.3
d
PC
(ymA)
	
24.7
10.8
4.2
2.1
1.2
0.67
0.39
---

0.508

IMPACTOR
STAGE
NUMBER

Precutter
§ Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET
M
cum
(mg/DNm3)
1,960
1,960
1,950
1,930
1,880
1,580
645
154
0.0
d
pc
(ymA)
	
7.4
3.8
2.2
1.2
0.71
0.39
0.23
	

0.010

OUTLET
M
cum
(mg/DNm3)
21.2
21.2
20.7
20.5
20.4
20.2
19.8
15.2
6.5
d
PC
(ymA)
	
24.3
10.6
4.1
2.1
1.2
0.66
0.38
	

0.692

CM
         Table A-14.
INLET AND OUTLET SIZE DISTRIBUTION DATA
FOR RUN #14
IMPACTOR
STAGE
NUMBER

Precutter
5 Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET

Mcum
(mg/DNm3)
2,320
2,320
2,320
2,320
2,240
2,150
1,440
325
52.0
.
pc
(ymA)
	
10.6
4.4
2.5
1.4
0.83
0.46
0.26
...

0.008

OUTLET

Mcum
(mg/DNm3)
23.0
23.0
22.0
22.0
22.0
22.0
22.0
17.9
5.4

dpc
(ymA)
---
24.7
10.8
4.2
2.1
1.2
0.67
0.39
---

0.408

                                                                                 Table A-16.
INLET AND OUTLET SIZE DISTRIBUTION DATA
FOR RUN #16
IMPACTOR
STAGE
NUMBER

Precutter
fj Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET
Mcum
(mg/DNm3)
1,790
1,790
1,790
1,780
1,760
1,700
1,234
316
28.7
dpc
(ymA)
---
43.7
3.7
2.1
1.2
0.71
0.39
0.23
	

0.010

OUTLET
Mcum
(mg/DNm3)
24.8
24.8
23.5
23.3
23.0
22.5
22.2
18.4
8.2
dpc
(ymA)
...
24.6
10.8
4.2
2.1
1.2
0.66
0.38
	

0.854


-------
Table A-17,
INLET AND OUTLET SIZE DISTRIBUTION DATA
FOR RUN #16P
IMP AC TOR
STAGE
NUMBER

Precutter
§ Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET
M
cum
(mg/DNm3)
2,250
2,250
2,210
2,210
2,200
2,170
2,080
1,390
186
d
pc
(ymA)
—
25.6
11.2
4.4
2.2
1.3
0.69
0.42
	

0.020

OUTLET
M
cum
(mg/DNm3)
24.8
24.8
23.5
23.3
23.0
22.5
22.2
18.4
8.2
d
pc
(ymA)
	
24.6
10.8
4.2
2.1
1.2
0.66
0.38
	

0.854

Table A-18
INLET AND OUTLET SIZE DISTRIBUTION DATA
FOR RUN #17
IMPACTOR
STAGE
NUMBER

Precutter
§ Nozzle
1
2
3
4
5
6
7
Filter
Sample
Volume
(DNm3)
INLET
M
cum
(mg/DNm3)
1,390
1,390
1,380
1,380
1,370
1,330
1,230
757
224
C1
pc
(•ymA)
	
17.6
7.7
3.6
1.5
0.86
0.48
0.29
	

0.043

OUTLET
M
cum
(ng/DNm3)
21.2
21.2
20.5
20.5
20.3
20.2
20.2
15.1
6.0
,
pc
(ymA)
—
24.3
10.6
4.1
2.1
1.2
0.66
0.38
	

0.863

                           38

-------
<*D
         I
         as
         OJ
         1
              3.0
              2.0
              1.0
              0.5
              0.2
=p O.INLET


    AoUTLET
                                                                                      a.
                                                                                      m
                                                                                      E-
                                                                  I
                                                                  o
                                                                  a:
                                                                                            3.0
                                                                                            2.0
                                                                                            1.0
                                                                                            0.5
                        5    10     20   30  40 SO  60 70  80    90  95   98
                                                                                            0.2
                                                                                                    /\ OUTLET
                                                                                                2    5
                                                                                                          0    20   30  40 50 60 70  80    90  95   98
                              MASS  PERCENT UNDERSIZE
                                                                                                            MASS  PERCENT UNDERSIZE
                   Figure A-l   Inlet  and outlet size distribution

                                for  Run »2
                                                                            Figure A-2  Inlet and outlet size distribution

                                                                                        for Hun *3

-------
 a
 P.
as,
m
f-c
ta
I
O!
      3.0
      2.0'
      1.0
      O.SO
0.20
      0.15
)INLET

SOUTLET
           2    5   10   20  30  40 50 60  70 80    90   95   98
                       MASS PERCENT UNDERSIZE
           Figure A-3  Inlet and outlet size distribution

                       foi Run »4  (Heated inlet  cascade

                       inpactor) .
                                                                                3.0
                                                                                2.0
                                                                                1.0
                                                                      CO
                                                                      P-
                                                                    oi
                                                                    10
                                                                    f-
                                                                    ta
                                                         1
                                                         o
                                                         O!
                                                                                0.50
                                                                                0.20
                                                                                0.15
                                                                                    OINLET

                                                                                    AOUTLET
                                                                                     2    5   10    20 30  40 50 60   70   80   90   95   98
                                                                                                  MASS PERCENT UNDERSIZE
                                                                               Figure A-4  Inlet and outlet  size distribution
                                                                                           for Run »5

-------
 rt
 D.
•o

oT
I
       3.0
       2.0
       1.0
       0.50
       0.20
                 S   10    20 30  40 SO 60  70  80   90   95    98
                         MASS PERCENT UNDERSIZE
            Figure A-5  Inlet and outlet size distribution
                        for Run *6  (Heated inlet cascade
                        impactor).
                                                                                09
                                                                                D.
ctf
la
E-
ta
g

§
     5.0

     4.0


     3.0



     2.0
                                                                                     1.0
                                                                                     0.5
                                                                                     0.2-
                                                                                         2     5    10    20  30 40 50  60 70  80   90   95   98
                                                                                                      MASS PERCENT UNDERSIZE
         Figure A-6   Inlet  and  outlet size distribution
                      for  Run  f7

-------
 IS
 a.
as.
ta
a

u
I

§
      3.0
      2.0
      1.0
      0.5
      0.2
OINLET


AOUTLET
                                                                           CD
                                                                           a.
                                                                         a:
                                                                         ta
                                                                         f-
                                                                         la
                                                          a
                                                          o
                                                          an
                                                          la
                                                                                3.0
                                                                                2.0
                                                                                1.0
                                                                                0.5
                                                                                0.2
OINLET


AOUTLET
           25    10     20  30 40 50  60 70  80    90  95   98
                                                                     12     5    10     20  30 40 50 60  70  80    90    95   98
                        MASS PERCENT UNDERS1ZE
                                                                                      MASS PERCENT UNDERSIZE
          Figure A-7   Inlet and outlet size distribution
                       for Run #8
                                                                     Figure A-8   Inlet  and outlet size distribution
                                                                                  for  Run #9

-------
 a
 P.
a
o
B!
      3.0
      2.0
      1.0
      0.5
      0.2
OlNLET


Z^OUTLET
                5    10    20   30  40   50  60  70   80     90   95    98
                                                                          a.
                                                                          ta
5.0



4.0



3.0





2.0
                                                                              1.0
                                                                              0.5
                                                          Q
                                                          O
                                                          o:
                                                                              0.2
                                                                                  0.5 125    10   20  30  40 50 60 70  80    90   95    98
                        MASS PERCENT UNDERSIZE
                                                                                                   MASS PERCENT UNDERSIZE
           Figure  A-9   Inlet  and outlet  size  distribution
                       for Run #10 (Heated  inlet  cascade
                       impactor).
                                                                   Figure A-10  Inlet and .outlet size distribution
                                                                                for Run #11  (Heated inlet  cascade
                                                                                impactor).

-------
 CO

 O.
CA
ia
n

u
z

§
O
oi
w
    2.0
    1.0
    0.5
    0.2
          1   2
                     10     20  30  40  50 60  70  80    90  95   98
                        MASS PERCENT UNDERSIZE
Figure A-ll  Inlet and outlet size distribution

             for Run #12  (Heated inlet cascade

             iropactor).
                                                                                 2.0
                                                                                 1.0
                                                                                 0.5
                                                                            n

                                                                            u
                                                                   z


                                                                   g   0.2
                                                                   a.        i
                                                                   w        A
                                                                                           OINLET  (



                                                                                           Z\ OUTLET
                                                                                         2     5    10     20   30 40  50 60 70  80    90  95   98
                                                                                                    MASS  PERCENT UNDERSIZE
                                                                                     Figure A-12  Inlet and  outlet  size distribution

                                                                                                  for Run  #13

-------
 CD

 P.
Z

Q
O
oi
la
      2.0
      1.0
      0.5
      0.2
               OINLET


               Z\ OUTLET
           12     S    10     20   30 40 50  60 70  80   90   95   98
                         MASS  PERCENT UNDERSIZE
  ca
  o,
                                                                              a.
                                                                              tu
                                                                              E-
Q
O
                                                                                    3.0
                                                                                    2.0
                                                                                    1.0
                                                                                    0.5
                                                                                    0.2
                OlNLET


                Z\ OUTLET
                                                                                        2    5   10    20  30 40 50 60  70  80    90    95    98




                                                                                                     MASS PERCENT UNDERSIZE
          Figure A-13   Inlet  and  outlet  size distribution
                        for Run  #14
          Figure A-14   Inlet  and  outlet size distribution
                        for Run  #15

-------

 (9
 CX
    3.0
    2.0
     1.0
     0.5
a

u
§
PS
     9.2
(J INLET

   INLET HEATED

A OUTLET
          12    5   10  ^20  301
                     MASS PERCENT UNDERSIZE
         Figure A-15  Inlet and Outlet  size distribution

                      for Run 016
                                                                                  2.0
                                                                 0)
                                                                 P.
                                                                              at
                                                                              ta
                                                                              H
                                                                I

                                                                §
                                                                ra
                                                                                  1.0
                                                                                  0.5
                                                                                  0.2
                                                                                       =^o
                                                                                              INLET
                                                                        2    5   10    20  30 40 50 60  70  80   90   95    98




                                                                                  MASS PERCENT UNDERSIZE
                                                                        Figure A-16  Inlet and outlet  size  distribution

                                                                                     for Run #17 (Heated inlet  cascade
                                                                                     impactor).

-------
                                                                             0.3
0.2
          S  10    20  30  40 50 60 70  80    90  95   98
                    NUMBER UNDERSIZE
     Figure A-17  Diffusion battery data for ductile operation
                                                                             0.02
2    5   10   20  30 40  50 60 70  80    90  95   98

               NUMBER UNDERSIZE
Figure A-18 Diffusion battery data for gray operation

-------
             APPENDIX B






Venturi Scrubber Performance Model
                   48

-------
           VENTURI SCRUBBER PERFORMANCE MODEL

     Calvert, et al., 1976 have performed a literature
review and evaluation of all available venturi scrubber
performance models.  Their conclusions and recommended
performance model are presented below.
      (1)   Even though each investigator presented a dif-
 ferent equation for the prediction of particle collection
 in a venturi scrubber, most of these equations can be
 reduced to the same basic model, i.e.,
 where  Pt(d )  = penetration for particles with diameter d ,
                 fraction
           u   = relative velocity between dust and drop,
                 cm/sec
           Up  = gas velocity, cm/sec
           d,  = drop diameter, cm
            n  = single drop collection efficiency, fraction
                            1JUC L.1.LI. JL -L UW 1 O. L.^ , U'l' ' '
            z  = length, cm
Q   = liquid volumetric flow rate, cm3/sec
 W
      (2)  A generalized method for applying equation B-l to
 predict particle collection in a venturi was  developed.
      (3)  Particle collection predicted by equation B-l
 agrees satisfactorily with performance data.
      (4)  Most of the particle collection occurs in
 the venturi throat.  The solution  to equation B-l for the
 venturi throat, using the inertial collection efficiency
 correlation, and assuming a zero initial drop velocity, is
                              49

-------
In Pt(dp)_
   B
 K/l-u*\+  0.7
  P°\
         - 5 02 K°'5  1-u*
           b.oz K    i ud
            po
                                                       (B-2)
where  u5
        a
    =  21-
       Pt (d ) = penetration for particles with diameter d  ,
           P                                             P
                fraction
          u
          u
           'Do
           *  =
                volumetric liquid flow rate, cm3/sec
                liquid density, g/cm3
                gas density, g/cm3
                drag coefficient obtained from the "standard curve'
      dimensionless  drop velocity
      u,
                u
                 Gt
          u
          K
 Gt
-po
= drop velocity, cm/sec

= gas velocity in the throat, cm/sec
= inertial parameter based on throat velocity
                C'  dp
                        d
                             50

-------
           C' = Cunningham slip factor
           d  = particle diameter, ym
           p  = particle density, g/cm3
           yG = gas viscosity, poise
           d, = drop diameter, cm
            L = dimensionless throat length
            L =
                  2 dd PL
      Equation B-2 slightly under estimates the particle
collection occurring in a venturi scrubber.  For most
industrial venturi scrubbers, particle collection can be
predicted closely by neglecting the first term in the
right hand side of equation B-2.
     (5)  Pressure drop predictions by the modified Calvert's
equation and by Boll's equation agree with experimental data.
The modified Calvert's  equation has the following form,

             AP = 1.03 x 10"3 F! u 2( L J          (B_3)
where  AP  = pressure, cm W.C.
       uGt = &as velocity in the throat, cm/sec
         'L
        QT = liquid flow rate, cm3/sec
        Qr = gas-flow rate, cm3/sec
        F! = correction factor, dimensionless
                             2    4-  20'5
          Fl =     = 2  l - X2+  (X4- X)
               UGt     I
                        3 ttCDQ PG .
                         16 d  P
                            51

-------
      u,  = drop velocity at the exit of the throat,  cm/sec
       H  = throat length or distance between liquid
            injection point and the exit of throat, cm
       d, = drop diameter,  cm
       PG = gas  density,  g/cm3
       p.  = liquid density, g/cm3
      Cp  = drag coefficient at the liquid injection  point.
    (6)    The use of a drag coefficient from the "Standard
curve" gives a better fit between model and experimental
data than does Ingebo's correlation.
    (7)   The drop diameter can be assumed to be the  Sauter
mean diameter calculated from the Nukiyama-Tanasawa relation,
                          52

-------
                                TECHNICAL REPORT DATA
                          (Please read Instructions on the reverse before completing)
1. REPORT NO.
 EPA-6QO/2-76-282
                                                       3. RECIPIENT'S ACCESSION'NO.
4. TITLE AND SUBTITLE
National Dust Collector Model 850 Variable Rod
  Module Venturi Scrubber Evaluation
                                  5. REPORT DATE
                                   December 1976
                                  6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
Seymour Calvert, Harry F. Barbarika, and
  Charles F. Lake
                                                      8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Air Pollution Technology, Inc.
4901 Morena Boulevard, Suite 402
San Diego, California  92117
                                  10. PROGRAM ELEMENT NO.
                                  1AB012; ROAP 21ADM-029
                                  11. CONTRACT/GRANT NO.

                                  68-02-1869
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC 27711
                                  13. TYPE OF REPORT ANC
                                  Final; 8/75-8/76
                                                 ND PERIOD COVERED
                                  14. SPONSORING AGENCY CODE
                                   EPA-ORD
15. SUPPLEMENTARY NOTES j£RL-RTP project officer for this report is D. L. Harmon,
919/549-8411 Ext 2925, Mail Drop 61.
is. ABSTRACT The reporj. gives results of 3i measurement of the performance of a National
Dust Collector Model 850 variable rod module venturi scrubber at an industrial instal-
lation.  Fine particle collection efficiency as a function of particle size was computed
from the data collected.  The scrubber tower was operated at 1010 std cu meters/min
at 35 C with a total pressure drop of 224 cm (88 in.) W. C. with a pressure drop
across the venturi module of 178 cm (70 in.) W. C. The emission source was an iron
cupola which processes both ductile and gray iron, with the latter producing a higher
grain loading.  The ductile iron source particulates had a mass mean diameter range
of 0.25-0. 84 micrometers A (aerodynamic particle diameter) with a standard devia-
tion range of 1. 5-2.0.  The  gray iron source particulates had a mass mean diameter
range of 0. 54-1. 9 micrometers A with a standard deviation range of 1. 5-1. 8.  The
overall average collection efficiency for ductile iron melting was  98. 7%.  For gray
iron melting, the average collection efficiency was also 98. 7% even though  the cu-
pola emission was lower for ductile iron.
17.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                          b.lDENTIFIERS/OPEN ENDED TERMS
                                               c. CCSATI Field/Group
Air Pollution
Dust Collectors
Scrubbers
Evaluation
Iron and Steel Industry
Furnace Cupolas
Nodular Iron
Gray Iron
Air Pollution Control
Stationary Sources
National Dust Collector
 (Model 850)
13B
13A
07A

11F
13. DISTRIBUTION STATEMENT
 Unlimited
                                          19. SECURITY CLASS (This Report)
                                           Unclassified
                                               21. NO. OF PAGES
                                                    63
                      20. SECURITY CLASS (Thispage)
                      Unclassified
                                                                   22. PRICE
EPA Form 2220-1 (9-73)
                                          53

-------