EPA-600/2-77-023S
February 1977
Environmental Protection Technology Series
                 INDUSTRIAL  PROCESS  PROFILES FOR
                   ENVIRONMENTAL USE:  Chapter 19.
                                       The  Clay Industry
                                   Industrial Environmental Research Laboratory
                                        Office of Research and Development
                                       U.S. Environmental Protection Agency
                                                Cincinnati, Ohio 45268

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                 RESEARCH REPORTING SERIES

 Research reports of the Office of Research and Development, U.S. Environmental
 Protection  Agency, have been grouped into five series. These  five broad
 categories were established to facilitate further development and application of
 environmental technology. Elimination of traditional grouping was consciously
 planned to foster technology transfer and a maximum interface in related fields.
 The five series are:

     1.     Environmental Health Effects Research
     2.     Environmental Protection Technology
     3.     Ecological Research
     4.     Environmental Monitoring
     5.     Socioeconomic Environmental Studies

 This report has  been assigned  to  the ENVIRONMENTAL PROTECTION
 TECHNOLOGY series. This series describes research performed to develop and
 demonstrate instrumentation, equipment, and methodology to repair or prevent
 environmental degradation from point and non-point sources of pollution. This
 work provides the new or improved technology required for the control  and
 treatment of pollution sources to meet environmental quality standards.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.

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                                            EPA-600/2-77-023S
                                            February 1977
         INDUSTRIAL  PROCESS  PROFILES

            FOR ENVIRONMENTAL  USE

                  CHAPTER 19

              THE  CLAY  INDUSTRY
                      by

  J.  T.  Reding,  K.  E.  Bishop,  P.  E.  Muehlberg
              and B.  P.  Shepherd
                 Dow  Chemical
            Freeport,  Texas   77451

     Terry Parsons and Glynda  E.  Wilkins
              Radian  Corporation
             Austin,  Texas   78766
           Contract No.  68-02-1319
               Project Officer
               Alfred B.  Craig
   Metals and Inorganic Chemicals Branch
Industrial Environmental  Research Laboratory
             Cincinnati,  Ohio  45268
INDUSTRIAL ENVIRONMENTAL RESEARCH LABORATORY
     OFFICE OF RESEARCH AND DEVELOPMENT
    U.S. ENVIRONMENTAL PROTECTION AGENCY
           CINCINNATI, OHIO  45268

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                                 DISCLAIMER
       This report has been reviewed by the Industrial Environmental Research
Laboratory - Cincinnati, U.S. Environmental Protection Agency, and approved
for publication.  Approval does not signify that the contents necessarily
reflect the views and policies of the U.S. Environmental Protection Agency,
nor does mention of trade names or commercial products constitute endorsement
or recommendation for use.

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                           TABLE OF CONTENTS
                              CHAPTER 19
                                                                       Page
INDUSTRY DESCRIPTION	      1
    Raw Materials	      2
    Products	      3
    Companies 	      4
    Environmental Impact	      7
    Bibliography	      8

INDUSTRY ANALYSIS 	      9
    Clay Production Segment 	     11
        Process No. 1. Mining	     13
        Process No. 2. Crushing	     15
        Process No. 3. Drying	     17
        Process No. 4. Dry Grinding	     19
        Process No. 5. Wet Concentrating	     21
        Process No. 6. Final Drying	     23
    Brick Manufacture Segment 	     25
        Process No. 7. Extruding	     27
        Process No. 8. Brick Drying	     28
        Process No. 9. Firing	     29

Appendix A - Raw Material  List	     33
Appendix B - Products List	     35
Appendix C - Companies and Products	     39
                                  iii

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                             LIST OF FIGURES
                                CHAPTER 19

Figure                                                             Page
   1      Clay Industry Chemical Tree	    10
   2      Clay Industry Flowsheet	    12
   3      Brick Manufacture Flowsheet	    26
                                     IV

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                              LIST OF TABLES
                                CHAPTER 19

Table                                                             Page
  1       Clay Production Statistics for 1973	     3
  2       Uses of Products of the Clay Industry	     4
A-l       Raw Materials Used in 1973	    34
B-l       Primary Uses of Clay Products	    36
C-l       Kaolin, Ball Clay, Fire Clay, Bentonite,
           and Fuller's Earth Producers	    40
C-2       Common Clay, Brick, and Structural
           Clay Producers	    51

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                                ACKNOWLEDGEMENTS
This document was prepared for EPA by Dow Chemical, U.S.A.,  Texas  Division
under contract number 68-02-1329, Task 8.  The authors were  J.  T.  Reding,
K. E. Bishop, P. E. Muehlberg, and B. P. Shepherd.  Their contributions
are gratefully acknowledged.

Helpful review comments from G. C. Robinson were received and incorporated
into this chapter.
                                       vi

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                                  CLAY


 INDUSTRY  DESCRIPTION

       For the  purpose  of this  study  the  clay  industry  consists  of companies
 involved  in  mining  of  clay  minerals, beneficiating  of  clay  minerals,  and
 brickmaking.   The minerals  vary  in chemical composition  and physical  pro-
 perties and  are  difficult to define.   Usually clays  are  natural,  earthy,
 fine-grained,  hydrated aluminum  silicates which  are  plastic when  wet,
 rigid  when dry,  and vitreous when fired.

       Imprecise  definitions and  liberal  usage and interpretation  of terms
 make attempted classification  and organization of the  clay  industry very
 difficult.  The  U.S. Bureau of Mines segregates  the  clay industry into
 six categories,  according to clay type.  The  six clays are  ball clay,
 bentonite, fire  clay,  fuller's earth,  kaolin, and common clay plus shale.
 This chapter treats the clay industry  in two  segments:   Clay Production
 and Brick Manufacture.

     The  flowsheets of Figure  2  and 3  show processes included in  the
 industry.  The first processes are mining and crushing of the clay ore.
 The crushed  clay can be sold,  or it can  be extruded, dried,  and fired
 to  form bricks;  or  it  can be dried and ground to desired fineness, or
 it  can be separated from wastes  using  wet methods and  then  dried.

     The  clay  industry  is very fragmented.   There are over 500 mining
 or  manufacturing operations in the United States.  In 1974,  individual
 plant  production capacities of finished clay product ranged  from 20 to
 500 metric tons  per day.  Approximately 60,000 persons are employed in
 the industry.

     In 1973 approximately  58.9 x 106 metric tons of domestic clays
 valued at  $355 x 106 were sold or used by producers.

     Clay  suitable  for  commercial use  is found in all 50 states, and in
 1973 it was mined in every  state except Alaska, Rhode Island, and
 Vermont.   Leading states  in clay production were Georgia with 7.0 x 10°
 metric tons, Texas  with  5.2 x  106 metric tons, Ohio  with 4.3 x 106
 metric tons, North  Carolina, Alabama,  and California.  Most clay
 mining operations are located  in rural  areas.   Brick processing is
 often  located  in metropolitan  areas.

     Various types  of clay  are obtained from different parts of the
 country.   Tennessee produced 63.7 percent of the total  domestic ball
 clay in 1973.  Total ball clay production in the 8 producing states
was 697,000 metric  tons.  Bentonite totaling 2,790,000 metric tons
was produced in 15  states, and the leading producer was Wyoming with
 68.7 percent of the total.  Fire clay  totaling 3,700,000 metric tons
was produced in 20  states with Ohio,  Pennsylvania,  Missouri, and
Alabama accounting  for approximately 78 percent of the total.  Fuller's
earth totaling 1,030,000 metric tons was produced in 9 states with

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Georgia and Florida accounting for approximately 76 percent of the
total.  Kaolin totaling 5,450,000 metric tons was produced in 16 states
with Georgia and South Carolina accounting for approximately 88 per-
cent of the total.   Common clay totaling 45,300,000 metric tons was
produced in 47 states with Texas, North Carolina, Ohio,  Georgia,
California, Alabama, Michigan, and Pennsylvania accounting for
approximately 50 percent of the total.

     The clay industry is expected to  grow at an annual  rate of 4
percent between now and the year 2000.   The demand for clay should  be
155 + 30 x 106 metric tons in the year 2000.   Present reserves are
sufficient to meet the projected demand.

     No information was available concerning on-site power or steam
generation.   It is believed that electricity is purchased from power
companies.

Raw Materials

     A clay is a naturally occurring sediment or sedimentary rock
composed of one or more minerals and accessory compounds.  The sediment
is usually rich in hydrated silicates  of aluminum, iron, or magnesium;
hydrated alumina; or iron oxide.  Most particles are of colloidal or
near-colloidal size and the material commonly develops plasticity when
pulverized and wetted.  Further information on clay minerals is found
in Appendix A.

      Clay minerals are non-toxic; moreover, one of the uses of  clay  is in
medicines and Pharmaceuticals.

     A serious environmental problem in the clay industry is the poor
condition of  abandoned or unused open-pit mines.  It is believed that
little effort has been made in the past to return old mines to a usable
condition.  In recent years, however,  some states have enacted laws
that  require  open pits to be backfilled and covered with vegetation to
restore the mined-out areas.  Some abandoned  pits have been  converted to
recreational  facilities: fishing  lakes  and at least one  golf  course.

      Another environmental problem is  waste  water from  processing plants
that is high  in suspended solids.  Most states  require clay  producers to
install settling ponds to prevent contamination of the streams.

      Dust emissions in clay mining generally are not of major  concern
because clay  is usually one-fourth water  by weight.  Dust emissions
from stockpiled clay may occur as moisture evaporates from  the  clay.
A few plants in or near metropolitan areas have air-pollution  problems.

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Products
1973.
     Table 1 is a presentation of the various types of clays produced in
              Table 1.  CLAY PRODUCTION STATISTICS FOR 1973
                                                  en







•P
o
3

O
s-
Cu
Common
Clay and
Shale





Kaolin

Fire Clay



Bentonite


Fuller's
Earth
Ball Clay
C
4-*

u
C 'I-
o s_
•I- -p
•P Ol
U E
3
00 TJW3
r>> o o
O"i 5- r~*
r- OL ^— '
45.2







5.45

3.70



2.79


1.03

0.70
ro
^~
O

i— C
to O
-P •!-
0 -P
1— O
3

O O
i.
^^ ex
76.8







9.3

6.3



4.7


1.8

1.2

C f*~ "*
•1--OO-

cvo
0 0

o 43^3-
u
CU 3 *
3 -O CM
i~™ O r*v
as i~ 
> O_ i—
74.0







136.9

29.2



29.3


22.8

10.8
CU C
-P O

3 "P"" *O
cr> -P +J co
c  u c r^
>r- 
-O -P T3 O •—
us ns o s-
OJ -P S- O) C
_l OO Q. D_ -r-
Texas
North Carolina
Ohio
Georgia
California
Alabama
Michigan
Pennsylvania
Georgia
South Carolina
Ohio
Pennsylvania
Missouri
Al abama
Wyomi ng
Mississippi
Montana
Georgia
Florida
Tennessee














(10.7%)
(8.3%)
(7.3%)
(5.6%)
(5.1%)
(4.9%)
(4.3%)
(4.2%)
(75.4%)
(12.6%)
(26.9%)
(21.9%)
(20.4%)
(8.8%)
(68.7%)
(9.3%)
(5.8%)
(39.0%)
(36.8%)
(63.7%)
       Table 2 lists some of the uses of products from the clay industry.
  A more complete duscussion of products is found in Appendix B.

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             Table 2.  USES OF PRODUCTS OF THE CLAY INDUSTRY
     PRODUCT                                   USES

 Common Clay and Shale               brick, portland cement, lightweight
                                    aggregate, sewer pipe, tile


 Kaolin                              paper coating/filling, brick, rubber,
                                    firebrick, ceramics
 Fire  Clay                           firebrick, refractory mortar/cement,
                                    high-alumina refractories, foundry
                                    sand
 Bentonite                           foundry sand, iron ore pelletizing,
                                    drilling mud, filtering, clarifying,
                                    decolorizing
 Fuller's Earth                      oil/grease absorbents, pet absorbent,
                                    pesticides
Ball Clay                           sanitary ware, pottery, tile, china/
                                    dinnerware
It should be noted that the term "common"  when used in  describing  a  type
of clay is not meant to imply mediocrity or baseness.   Common  clay is
defined by the U.S. Bureau of Mines  as  "a  clay or claylike  material
which is sufficiently plastic to permit ready mold and  vitrification
below 1,100°C."

Companies

      The clay industry is highly fragmented.  Over 500 companies  are
included in the industry company lists  of  Appendix C.   Most companies
in the industry are primarily clay or brick producing companies.

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     Companies producing  85  percent  of the total  ball  clay in 1974
were as follows.

     Bell Clay Company
     Cyprus  Industrial Minerals
     Kentucky-Tennessee Clay Co.
     Old Hickory Clay Co.
     Southern Clay  Products, Inc.
     H. C. Spinks Clay Co.

     Companies producing 75  percent of the total bentonite clay in
1974 were as follows.

     Americal Colloid Co.
     Benton Clay Co.
     Cal-Min Co.
     Dresser Minerals
     Filtrol Corp.
     International  Minerals  & Chemical Corp.
     McKittrick Mud Co.
     NL Industries, Inc.
     Western Clay Co.
     Wyo-Ben Products, Inc.

     Companies accounting for 50 percent of the total fire clay
production in 1974 were as follows.

     Cedar Heights Clay Co.
     Combustion Engineering  Co.
     Coosa Clay Co.
     Frederick J. Dando Co.
     Dixie Clay Co.
     Eberhart Coal, Inc.
     Freeport Brick Co.
     A. P. Green Refractories Co.
     Harbison-Walker Refractories Co.
     Kaiser Refractories
     Kimble Coal  Co.
     Reese Bros.
     Thomas Bros. Coal Co.
     Union Clay Co., Inc.
     Wellsvilie Firebrick Co,

     Companies producing 75  percent of the fuller's earth clay in 1974
were as follows.

     Engelhard Minerals & Chemical Corp.
     Floridin Co.
     Georgia-Tennessee Mining Co.
     Medusa Cement Co.
     Mid-Florida Mining Co.
     Milwhite Co.,  Inc.
     Oil Dri Corp.  of Georgia
     Thor Mining Co.
     Waver!y Mineral Products Co.

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      Companies  producing  65  percent of the total  kaolin in 1974 were
 as  follows.

      American Industrial  Co.
      Anglo-American Clays Corp.
      Carolina Ceramics,  Inc.
      Cyprus  Mines Corp.
      Engelhard  Minerals  & Chemicals Corp.
      Freeport Kaolin Co.
      Georgia Kaolin Co.
      J.  M. Huber Corp.
      National Kaolin Products  Co.
      Richtex Corp.
      Southeastern Clay Co.
      Taylor  Clay Products Co.
      Thiele  Kaolin  Co.

      Companies  producing  approximately 20  percent  of  the  common clay
 and shale in 1974 were as follows.

      Barrett Industries
      Bay Prairie Aggregate Corp.
      Belden  Brick Co.
      Boren Clay Products  Co.
      Carolina Solite Corp.
      The Claycraft  Co.
      The Feather!ite Corp.
      The Feather!ite Co.  of  San Antonio
      General  Wadsworth Brick Co.'
      Hydraulic  Press Brick Co.
      Marion  Brick Corp.
      Pine Hal!  Brick and  Pipe  Co.
      The Rich!and Brick Co.
      Sanford  Brick  Co.
      Solite  Corp.
      Strawn  Materials
      Superock,  Inc.
      Texas Industries, Inc.
      Trotti  & Thomson

More  complete lists  of producers of clays  and brick are found  in
Appendix  C.

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Environmental Impact

     Dust emissions in the clay industry are considered to be a minor
problem.  Clay usually contains 20 to 30 percent moisture and dust
emissions from mining and beneficiation are minimal.  Dust is released
from stockpiled clay, especially bentonite, which is stockpiled for
weathering.  A few plants in or near metropolitan areas have air-
pollution problems.

     Approximately 98.percent of clay ore is mined by the open-pit
method.  This results in unusable land unless efforts are made to
landscape the mined out areas.  Unused or abandoned open-pit mines are
probably the major environmental problem of the industry.

     Another major environmental problem is water pollution.  As
overburden is removed and clay is mined, water percolates through the
soil.   It becomes high in suspended solids and is usually allowed to
run'off to streams.  This problem can be alleviated if a sump or
settling basin is provided for the percolating water.

     Common clay has an average waste-to-clay ratio of 0.25 to 1.
Kaolin has the highest waste-to-clay ratio, 7 to 1.  In 1973 kaolin
clay mining generated approximately 30 to 40 x 106 metric tons of waste
while common clay mining generated approximately 10 to 15 x 10$ metric
tons of waste.  It is assumed that these wastes are largely used for
landfill.

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Bibliography

     Ampian, S. 6. Clays.  In: Minerals Yearbook, 1972, Volume I.
Schreck, A. E.  (ed.).  Bureau of Mines, U. S. Dept. of the Interior.
Washington, D.  C., U. S. Government Printing Office, 1972. p. 301-326.

     Ampian, S. 6. Clays in 1973.  In: Mineral Industry Surveys.
Bureau of Mines, U. S. Dept. of the Interior.  Washington, D. C.,
U. S. Government Printing Office, 1974.  5p.

     Grim, R.  E. Applied Clay Mineralogy.  New York, McGraw-Hill Book
Company, Inc.,  1962.  405p.

     Grim, R.  E. Clays (uses).  In: Kirk-Othmer Encyclopedia of
Chemical Technology.  Standen, A. (ed.).  New York, John Wiley and
Sons, Inc., 1967.  5^:580-586.

     Hosterman, J. W. Clays.  In: United States Mineral Resources,
Geological Survey Professional Paper 820.  Brobst, D. A., and
W. P. Pratt (eds.).  Washington, U. S. Government Printing Office,  1973.
p. 129.

     Kaolin Clays and Their Industrial Uses.  New York, J. M. Huber
Corporation, 1949. p. 15-34.

     Keller, W. D. Clays (survey).  In:  Kirk-Othmer Encyclopedia of
Chemical Technology.  Standen, A. (ed.).  New York, John Wiley and
Sons, Inc., 1967.  5^:541-560.

     Murray, H. H. Clay.  In: Industrial Minerals and Rocks, 3rd
Edition.  Gill son, J. L. (ed.).  New York, The American Institute of
Mining, Metallurgical, and Petroleum Engineers, 1960.  p. 259-284.

     Robinson,  C.  G.   Clemson University, Personal Communication
(August,  1976).

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INDUSTRY ANALYSIS

     Many data relating to the clay industry are available and are
considered accurate.  Variations .in operating parameters occur because
of the variety of raw materials used.  Companies are believed to use
the same type of equipment for mining and crushing.  Only kaolin and
fuller's earth are beneficiated to any appreciable extent,  Beneficia-
ting equipment for these clay minerals is believed to be basically
similar.

     The chemical tree of Figure 1 gives a qualitative overview of the
clay industry from a raw material-end product-use standpoint.  The
basic products are the clays of the six basic,categories - ball  clay,
bentonite, fire clay, fuller's earth, kaolin, and common clay plus
shale.  End uses as shown on the figure are many.

     The process flowsheets, Figures 2 and 3, show the processes used in
manufacturing beneficiated clays and bricks.  The interior of each of the
rectangular "process blocks" appearing on the flowsheet represents at
least one of the sequential, real processes of the clay industry.   A
number and title have been placed within each of the process blocks.
These identifying symbols are used,in the process descriptions later
in this report.


     Flag symbols at the upper right-hand corner of the process  block
indicate the nature of the waste streams, if any, discharged from  the
process.  A circle is used for atmospheric emissions, a triangle for
liquid wastes, and a rhombus for solid wastes.   The flags do not
differentiate between inadvertent (fugitive) and designed wastes.

     A verbal process description has been written to characterize each
process further, to relate it to other processes, and to quantify  its
operating parameters.

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  Raw
Materials
Products
Applications
                    Beneficiated-
                       01 ays
Clay
Ores
                     Crushed
                     Common •
                      Clay
                       Adhesives
                       Alum
                       Animal  Feed
                       Animal  Litter
                       Face Brick
                       Catalysts
                       China/Dinnerware
                       Drilling Mud
                       Porcelain
                       Fertilizers
                       Filters
                       Firebrick
                       Floor Absorbents
                       Foundry Sand
                       Gypsum Products
                       Cosmetics
                       Medicines
                       Pharmaceuticals
                       Mortar and Cement
                       Paint
                       Paper Coating/Filling
                       Pelletizing
                       Pesticides
                       Plastics
                       Pottery
                       Rubber
                       Sanitary Ware
                       Tile
                       Tile
                       Face Brick
                       Common Brick
                       Portland Cement
                       Lightweight Aggregate
                       Crockery
                       Drilling Mud
                       Brakes and Clutches
                       Flower Pots
                       Flue Linings
                       Linoleum
                       Pottery
                       Sewer Pipe
              Figure 1.  CLAY INDUSTRY CHEMICAL  TREE
                               10

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CLAY PRODUCTION

   The Clay Production Segment of the clay industry includes operations
involved in mining the clay, beneficiating the clay, and preparing a
commercial product.  The processes considered are Mining, Crushing,
Drying, Dry Grinding, Wet Concentrating, and Final Drying.

   Figure 2 is a process flowsheet which characterizes further this
segment of the industry.
                                  11

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                                                                                                               Zn or Na
                                                                                                                 salts
                                                                                                              Na silicate
                                                                                                                   t
ro
Mining
1
                                                                                                                  Wet
                                                                                                            concentrating
                                                                                                       Heat-
Crushing
2
Drying
3
                                                                                                                                                                .To sales.
                                                                                                                                                                 Fig. 3
                                                                                Figure 2.  CLAY PRODUCTION FLOWSHEET

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CLAY PRODUCTION                                         PROCESS NO. 1


                                MINING

1.  Function

    This process (See Figure 2) removes clay ore from open-pit mines and
    forwards it to crushing, Process 2.  Overburden is removed and ore
    extracted using drag lines, mechanical shovels, graders, loaders,
    and similar equipment.  The clay is transported by trucks, conveyor
    belts, or rail to plant bins or stockpiles.  In a few instances
    other types of mining processes may be used.  These processes
    include underground mining and hydraulic mining.  Blasting is
    occasionally necessary in fire clay mines.  Shale planers are some-
    times used.

2.  Input Materials

    • 1 to 10 metric ton clay ore per metric ton clay product.

3.  Operating Parameters

    • Overburden depth - 1 to 30 meters
    • Overburden-to-day ratios as high as 15:1
    • Clay depth - 2 to 15 meters
    • Recoverable clay content in ore - 10 to 99 percent

4.  Utilities

    • Fuel for equipment - 2000 to 15000  kcal per metric ton clay
      product.

5.  Waste Streams

    • Dust emissions are estimated to be less than 0.01 metric ton per
      metric ton clay product.
    • Stripped overburden ranges from 1 to 15 metric tons per metric
      ton clay product.

6.   EPA Source Classification Code

    None
                                 13

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References

Cooper, J. D. Clays.  In:  Mineral  Facts and Problems, Bulletin 630.
Bureau of Mines, U.  S.  Dept.  of the Interior.  Washington, D.  C.,
U.S. Government Printing Office, 1965.  p.  227-240.

Kaolin Clays and Their Industrial  Uses.  New York,  J. M.  Huber
Corporation, 1949.   p.  15-34.
                          14

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CLAY PRODUCTION                                         PROCESS NO. 2


                              CRUSHING

1.  Function

    This process (See Figure 2) crushes ore from Process 1 into small
    lumps and forwards the lumps to Process 3 (drying), Process 5 (wet
    concentrating), or Process 7, Figure 3 (extruding).  Some crushed
    clay is marketed as a product without further processing.

    Primary crushing of fire clay, common clay, and shale is usually
    done with jaw or gyratory crushers, single roll crusher, or hammer
    mills.  If needed, secondary crushing and grinding are generally
    by hammer mills, by dry pan, or by wet pan.  Secondary crushing is
    •usually followed by screening.  Ball clay is usually processed in a
    shredder.  Often bentonite does not require crushing, but goes di-
    rectly to Process 3.  Single-roll crushers are usually used to crush
    fuller's earth and kaolin.  Crushing is followed by screening.

2.  Input Materials

    • 1 to 10 metric tons clay ore per metric ton clay product,

3.  Operating Parameters

    • Primary crushing product size - 5 cm maximum
    • Secondary crushing product size - 2 cm maximum
    • Typical roll  size for roll crusher - 1 meter diameter x 0.5
      meter length

4.  Utilities

    • Electrical energy - 1 to 5 kWh per metric ton clay product.

5.  Waste Streams

    • Dust emissions from crushing are estimated to be less than 0.01
      metric ton per metric ton clay product.

6.  EPA Source Classification Code

    None

7.   References

    Cooper, J. D. Clays.  In: Minerals Facts and Problems, Bulletin 630.
    Bureau of Mines, U.  S. Dept. of the Interior.  Washington, D. C.,
    U.  S. Government Printing Office, 1965.  p. 227-240.
                                   15

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Grim, R.  E. Applied Clay Mineralogy.   New York,  McGraw-Hill  Book
Company,  Inc., 1962.   p. 333-405.

Robinson, C. G.  Clemson University,  Personal Communication
(August,  1976).

Taggart,  A. F.  In: Handbook of Mineral  Dressing.  New York,
John Wiley and Sons, Inc., 1945.  p.  4-55 to 4-77.
                             16

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CLAY PRODUCTION                                         PROCESS NO. 3


                                DRYING

1.  Function

    This process (See Figure 2) receives crushed clay from Process 2
    and evaporates water from the clay.  The dry clay then goes to dry
    grinding, Process 4.  Bentonite and fuller's earth are often
    processed in this manner while other clays are often processed
    in other ways.  Clay usually containing 20 to 30 percent water is
    dried in a rotary dryer.  Heated combustion products passing through
    the dryer evaporate water from the clay.  Water content of the
    exiting  clay is 1 to 15 percent.  Additional drying usually occurs
    in Process 4, grinding.

2.  Input Materials

    • 1.3 to 2 metric tons crushed clay per metric ton clay product.

3.  Operating Parameters

    • Dryer size - 2.5 meter  diameter x 18 meter length
    . Dryer thermal efficiency -50 percent
    • Feed rate - 9 metric tons per hour

4.   Utilities

    • Electrical energy - 1 to 5 kWh per metric ton clay product.
    • Dryer fuel - 100,000  to 300,000  kcal per metric ton clay
      product.

5.   Waste Streams

    . Combustion products may contain hydrocarbons, sulfur oxides, or
      nitrogen oxides, depending on combustion practices and fuel.
      With efficient combustion practices and low sulfur fuel  the
      major constituents should be water vapor,  carbon dioxide, and
      nitrogen.

6.   EPA Source Classification Code

    3-05-008-01 Drying
                                 17

-------
7.    References

     Grim, R.  E.  Applied  Clay  Mineralogy.  New York, McGraw-Hill Book
     Company,  Inc.,  1962.  p. 381.

     Kaolin Clays and  Their  Industrial  Uses.  New York, J. M. Huber
     Corporation, 1949. p. 15-34.

     Robinson, C. G. Clemson University, Personal Communication
     (August,  1976)

     Taggart,  A.  F.  Handbook of Mineral Dressing.  New York, John Wiley
     and Sons, Inc., 1945.  p. 17-08 to 17-12.
                                 18

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CLAY PRODUCTION                                         PROCESS NO.  4


                             DRY GRINDING

1.  Function

    This process (See Figure 2) grinds dry or partially dried clay from
    Process 3 to desired sizes.  Bentonite and fuller's earth are
    usually processed in this manner.
    Ball, rod, or roller mills are generally used to grind partially
    dried clay to specific sizes.  Typically a ring-roller mill  with
    an internal Whizzer classifier is used.  Hot gases are often
    introduced to the mill to complete the drying of the clay.   The
    mills are equipped with automatic throwout devices to eliminate
    oversize impurities such as silica sand.  Screening is used  to
    obtain desired size fractions.  The resulting products are primarily
    used as fillers in rubber and paint.  They are shipped in bulk or
    in muHi-walled paper bags.

2.  Input Materials

    • 1.1 - 1.2 metric tons dry or partially dried clay per metric ton
      clay product .

3.  Operating Parameters

    • Typical grinding capacity - 3 to 8 metric tons per hour
    • Whizzer classifier size - 3 meters diameter
    • Typical feed moisture content - 8 to 10 percent
    • Typical outlet moisture content - 1 percent
    • Product size
         Bentonite fractions ranging from 20-mesh to minus 1500-mesh.
         Fuller's earth fractions ranging from minus 15-mesh, plus
         30-mesh to minus 90-mesh.

4.  Utilities

    • Electrical energy - 25 kWh per metric ton clay product.
    • Fuel - 0 to 100,000 kcal per metric ton clay product.

5.  Haste Streams

    • Dust - 0.05 metric ton dust per metric ton dry product escapes
      to the air without control.  If a cyclone dust collector  is  used,
      emissions are reduced to 0.01 metric  tons dust per metric ton
      clay product.
                                 19

-------
    •  Solids - 0.05 to 0.2 metric tons coarse impurities per metric
      ton clay product may be rejected from the clay.

6.  EPA Source Classification Code

    3-05-008-02 Grinding

7.  References

    Cooper, J. D.  Clays.  In:  Minerals Facts and  Problems,  Bulletin
    630.   Bureau of Mines, U. S.  Dept.  of the Interior.   Washington,
    D.  C., U.  S. Government Printing  Office,  1965.   p.  227-240.

    Grim, R. E. Applied Clay Mineralogy.   New York,  McGraw-Hill  Book
    Company, Inc.  1962.

    Kaolin Clays and Their Industrial  Uses.   New York,  J.  M.  Huber
    Corporation, 1949.   p. 15-34.

    Taggart, A. F.  Handbook of Mineral  Dressing.   New  York,  John Wiley
    and Sons,  Inc.,  1945.   p. 6-08, 9-07  to 9-13,  9-34.

    Snow, R. H. Size Reduction and Size Enlargement.   In:  Chemical
    Engineers' Handbook, 5^ Edition.   Perry,  R. H., and C.  H. Chilton
    (ed.).   New York, McGraw-Hill  Book  Company,  1973.   p.  8-46.
                                20

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CLAY PRODUCTION                                         PROCESS NO.  5


                          MET CONCENTRATING

1.   Function

    This process (See Figure 2) removes impurities from clay coming
    from Process 2.  The purified clay is forwarded to final drying,
    Process 6.  Most kaolin clay is processed in this manner; however,
    some kaolin is processed by dry processing methods.

    Crushed clay (or in some cases hydraulically mined clay) is mixed
    (blunged) with water in the presence of a dispersing agent such
    as sodium silicate.  The slurry is then purified by letting sand,
    mica, and other impurities settle in a sedimentation tank.  Two
    size fractions are usually obtained from the purified water-clay
    suspension using a Hydrosettler or a continuous Sharpies or Bird
    centrifuge.  The fine fraction (<1 micron diameter) is used as
    a pigment and for paper coating while the coarser fraction is used
    as paper filler.  The sized clay may be bleached using zinc or
    sodium salts to reduce insoluble iron oxides to the ferrous form.

    Finally, the clay particles may be pumped as a slurry to drying,
    Process 6, or they may be collected on piate-and-frame filters or
    drum filters before drying.

2.   Input Materials

    • 1.3 to 7 metric tons crushed clay per metric ton clay product.

3.   Operating Parameters

    • Settling tanks - 200 cubic meters in volume
    • Water suspensions carry 5 to 25 percent clay
    • Mixer (blunger) size - 2 meters x 3 meters x 6 meters
    • Centrifuge size - 2 meters diameter x 2 meters long
    • Plate-and-frame filter size - 1 meter x 1 meter
    • Filter pressures - start at 0.35 kg per cm^ and end at 4.2 kg
      per cm^

4.   Utilities

    • Electrical energy - 1 to 3 kWh per metric ton clay product.
    • Water - 4 to 20 metric tons per metric ton clay product.

5.   Waste Streams

    • Solids - 0.1 to 7 metric tons per metric ton clay product.
    • Water - 4 to 20 metric tons water per metric ton clay product.
      This water may contain up to 1 percent suspended clay.
                                 21

-------
6.   EPA Source Classification Code
    None
7.   References
    Grim,  R.  E.  Applied Clay Mineralogy.  New  York, McGraw-Hill  Book
    Company,  Inc.,  1962.  p.  381.
    Robinson, C. G. Clemson  University,  Personal  Communication
    (August,  1976).
    Taggart,  A.  F.  Handbook  of Mineral  Dressing.   New York,  John Wiley
    and Sons, Inc., 1945.  p. 8-58 to 8-60,  16-19  to  16-20.
                                22

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CLAY PRODUCTION                                         PROCESS NO. 6


                             FINAL DRYING

1.  Function

    This process (See Figure 2) dries wet beneficiated clay from
    Process 5,  The dry clay is then ready for shipment.

    Filter cake from Process 5 contains approximately 30 percent
    moisture.  It is dried in tunnel or rotary dryers.  If heated
    above 540°C, the clay can be calcined.  Clay slurry from Process 5
    is dried using spray dryers.

2.  Input Materials

    • 1.3 metric tons filter cake per metric ton clay product or 2
      metric tons clay slurry per metric ton clay product.

3.  Operating Parameters^

    • Rotary dryer size - 2.5 meter diameter x 18 meter length
    • Thermal efficiency ~50 percent
    • Feed rate - 9 metric tons per hour

4.  Utilities

    • Electrical energy - 5 kWh per metric ton clay product.
    • Fuel - 300,000 to 600,000 kcal per metric ton clay product.

5.  Waste Streams

    • Combusion product gases may contain hydrocarbons, sulfur oxides
      or nitrogen oxides» depending on combustion practices and fuel.
      With efficient combustion practices and low sulfur fuel the major
      constituents of the combustion gases should be water vapor,
      nitrogen, and carbon dioxide.

6.  EPA Source Classification Code

    3-05-008-01 Drying

7.  References

    Cooper,  J.  D.  Clays.   In: Minerals Facts and Problems, Bulletin 630.
    Bureau of Mines,  U.  S.  Dept. of the Interior.  Washington, D. C.,
    U.  S.  Government Printing Office, 1965.  p. 227-240.

    Grim,  R.  E. Applied Clay Mineralogy.   New York, McGraw-Hill  Book
    Company,  Inc.,  1962.   p,  381.
                                23

-------
Kaolin Clays and Their Industrial  Uses.   New York,  J. M.  Huber
Corporation, 1949.   p. 15-34.

Robinson, C. G.  Clemson University,  Personal  Communication
(August, 1976).

Taggart, A. F.  Handbook of Mineral  Dressing.   New York,  John Wiley
and Sons, Inc.,  1945.  p. 8-58  to 8-60,  16-19 to  16-20.

Porter, H.  F. Gas-Solid Systems.  In: Chemical Engineers' Handbook,
5th_ Edition.  Perry, R. H., and C.  H. Chilton (ed.).  New York,
McGraw-Hill Book Company, 1973.  p.  20-60.
                           24

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BRICK MANUFACTURE

    The Brick Manufacture Segment of the Clay Industry is very fragmented
with over 500 manufacturing plants in operation producing common brick
and face brick.  The segment is old with well established manufacturing
processes.  Emissions are not a serious problem in this segment of the
Clay Industry.

    The process flowsheet of Figure 3 shows brick manufacturing processes.
The symbols used in the flowsheet are described in the Industry Analysis
section of this report.
                                25

-------
ro
                                                                             Heat
                                          Extruding
              Fig.  2
                                                                                                                     Heat-
Drying
8
F1Hng
9
                                                             Figure  3.   BRICK MANUFACTURE  FLOWSHEET

-------
BRICK MANUFACTURE                                       PROCESS NO. 7


                              EXTRUDING

1.  Function

    This process (See Figure 3) extrudes crushed common clay from
    Process 2, Figure 2, cuts the extrusion into bricks, and forwards
    the wet, unfired bricks to brick drying, Process 8.  If the natural
    mined clay does not contain enough water for extrusion, crushed
    common clay is mixed with water in a pug mill and extruded by
    auger under vacuum to remove air.  As the clay is extruded into a
    ribbon, it is cut into brick sizes, usually with a wire.

2.  Input jjaterials

    . 1.2 to 1.3 metric tons wet, crushed common clay per metric ton
      dried, unfired brick.

3.  Operating Parameters
    •  Vacuum - 6 to 11  cm Hg
    •  Up to 100 x 106 bricks per year per plant

4.  Utilities

    •  Electrical  energy - 2 to 5 kWh per metric ton  brick  product.
    •  Water - 0.1  metric tons per metric ton brick  product.

5.  Waste Streams

    None

6.  EPA Source Classification Code

    None

7.  References

    Norton, F. H.  Refractories.   New York, McGraw-Hill  Book Company,
    1968.  p. 108-152.

    Plummer, H.  C.  Brick and Tile Engineering Handbook of  Design.
    Washington,  D.C., Structural  Clay Products Institute,  1950.
    p.  13-22.

    Robinson, C.  G.  Clemson University,  Personal  Communication
    (August, 1976).

    Taggart, A.  F.  Handbook of Mineral  Dressing.  New York, John Wiley
    and  Sons, Inc.,  1945.   p.  3-13 to 3-18.


                                    27

-------
BRICK MANUFACTURE                                   PROCESS NO. 8

                             BRICK DRYING

1.  Function

    This process (See Figure 3) dries wet, unfired bricks from Process
    7 and forwards the dry, unfired bricks to firing, Process 9.

    Waste heat from the cooling section of the kiln is generally used
    to dry the bricks.  This heated, ambient air is introduced into the
    dryer.  Make-up heat, if needed, may be provided by combustion of
    fuel.  Bricks pass through the dryer on a conveyor and emerge ready
    for  firing, Process 9.

2.  Input Materials

    • 1.2 to 1.3 metric tons wet, unfired bricks per metric ton dried,
      unfired brick.

3.  Operating Parameters

    • Temperature - 100 to 175°C
    • Thermal efficiency -35 percent

4.  Utilities

    • Fuel - 300,000 kcal per metric ton brick product.

5.  Waste Streams

    If make-up heat is provided by fuel combustion, the combustion gases
    may contain sulfur oxides, hydrocarbons, and nitrogen oxides, de-
    pending on combustion practices and fuel used.  The use of low-sulfur
    fuels and efficient combustion practices result in mostly water vapor,
    nitrogen and carbon dioxide in the gases.  The dryer exhaust contains
    about 0.2 kg water vapor per kg dry material.

6.  EPA Source Classification Code

    None

7.  References
    Norton, F.H. Refractories.  New York, McGraw-Hill Book Company, 1968.
    p.  108-152.

    Plummer, H.C.  Brick and Tile Engineering Handbook of Design.  Washington,
    D.C., Structural Clay Products Institute, 1950.  p. 13-22.


                                  28

-------
Handbook of Mineral Dressing.  Taggart, A.  F.  (ed.).   New  York,
John Wiley and Sons, Inc., 1945.  p.  17-04 to  17-07.

Robinson, C. G. Clemson University, Personal Communication
(August, 1976).
                             29

-------
 BRICK  MANUFACTURE                                   PROCESS NO. 9

                                FIRING

 1.   Function

     This  process (See Figure 3) vitrifies dried bricks from Process 8
     to produce  a final product.

     Dried,  unfired bricks are fed through a continuous tunnel kiln or
     a  batch kiln.  Refractory-topped cars are used to transport the
     brick through tunnel kilns.  In the continuous process the combustion
     gases are drawn from the hot section toward the charging section
     where they  are exhausted through the kiln stack.  Proper regulation
     of draft and pressure prevents mixing of combustion gases with the
     ambient air in the cooling section.  In batch kilns the brick are
     placed  in the kiln, fired, cooled, and then removed.

 2.   Input Materials

     •  1 metric  ton dried, unfired bricks per 0.92 metric ton brick product.

 3.   Operating Parameters

     •  Temperature - 900 to 1430°C
     •  Firing time - 40 to 250 hours

 4.   Utilities

     •  Fuel  - 250,000 to 3,000,000 kcal per metric ton brick product.

 5.   Waste Streams

     .  Exhaust from the kiln stack contains combustion gases, water, and
       excess air.  The combustion gases may contain sulfur oxides, nitrogen
       oxides, and hydrocarbons, depending on combustion practices and fuel
       source.  With efficient combustion and low-sulfur fuel the main con-
       stituents of the combustion gases should be carbon dioxide, water,
       and nitrogen.

     .  Fluorides and sulfur oxides may be exhausted from the clay.  The
       concentrations exhausted vary widely depending on the type of clay
       being fired.

6.  EPA Source Classification Code

    None
                                  30

-------
7.  References

    Norton, F. H.  Refractories.  New York, McGraw-Hill  Book Company,
    1968.  p. 192-221.

    Plummer, H. C. Brick and Tile Engineering Handbook  of  Design.
    Washington, D. C., Structural Clay Products Institute, 1950.
    p. 13-22.

    Handbook of Mineral Dressing.  Taggart, A. F.  (ed.).   New York,
    John Wiley and Sons, Inc., 1945.  p. 17-04 to  17-07.

    Robinson, C. G. Clemson University, Personal  Communication
    (August, 1976).
                                   31

-------
   APPENDIX A



RAW MATERIAL LIST
       33

-------
 RAW MATERIAL LIST

     Ball clay, fire clay,  and kaolin  are chiefly composed  of  kaolinite
whose structural  formula is Al4Si40lO  (OH)o  or  Al203-2Si02-2H20.
Kaolinite is 45 percent Si02,  39 percent Al203, and  13.6  percent  H20
with lesser amounts (<1 percent) of iron, magnesium,  calcium,  sodium,
and potassium oxides.  In addition to  kaolinite,  ball  clay  may contain
sericite micas and fire clay usually contains other  materials  such  as
diaspore, ball  clay, bauxite clay, and shale.

     Bentonite is chiefly composed of montmorillonite  which has a
theoretical formula of (OH)4Si8Al4020nH20-   In  reality it always
differs from the formula because of substitutions within  the lattice
of magnesium, iron, zinc, nickel, lithium, and  others  for aluminum.
In addition aluminum or phosphorous sometimes substitutes for  silicon.

     Most fuller's earth is chiefly composed of attapulgite (MgsSisOoQ-
(OH2)4-4H20).  Attapulgite is 55 percent Si02,  10 percent A^,  10.5
percent MgO, 3.5 percent Fe203, 0.5 percent  K20,  and 20 percent H20.

     Common clay/shale is chiefly composed of the mineral illite  which
has the structural formula of ^(SieAl2^14020(0^4.

      Brick clays must meet fairly stringent standards relating to
 manufacturing  quality and  fired product properties.  Illite,  kaolinite,
 or montmorillinite may be  the predominant minerals  in brick raw  materials
 Other minerals present are mica, quartz, and feldspar.

      Mining and  benefidating of clay minerals produces  varying  amounts
 of wastes.  Table A-l contains estimates of  raw material  usage in 1973.


                Table A-l.   RAW MATERIALS USED IN 1973
Product

Common Clay/Shale
Kaoli n
Fire Clay
Bentonite
Fuller's Earth
Ball Clay

Total
       1973
    Production
(IP6 metric tons)

      45.2
        .45
        .70
        ,79
        .03
       0.70

      58.9
Typical
Waste- to-
Clay Ratio

   1:4
   7:1
   1:1
 Estimated Total
 Mined Material
(IP6 metric tons)
    55 to 60
    35 to 45
       to 10
       to 9
   2.5 to 3.5
   1.2 to 1.8
                    7
                    7
                  108 to 130
                                    34

-------
 APPENDIX B
PRODUCT LIST
     35

-------
 PRODUCT  LIST

     Ball clay is defined as a plastic, white-firing clay used
 principally for bonding in ceramic ware.

     Bentonites are composed mainly of the clay mineral montmorillonite.
 High-swelling or sodium bentonites are produced chiefly in Wyoming,
 Montana, and South Dakota.  Calcium or low-swelling bentonites are
 produced in other states.

     Fire clay is defined as detrital material, either plastic or rock-
 like, containing low percentages of iron oxide, lime, magnesia, and
 alkalies to enable the material to withstand temperatures to 1500°C or
 higher.

     Fuller's earth is defined as a nonplastic clay or claylike
 material, usually high in magnesia, which has adequate decolorizing and
 pijrifying properties.

     Kaolin is defined as a white claylike material approximating the
 mineral  kaolinite.  It has a specific gravity of 2.2-2.6 and a fusion
 point of 1785°C.  The other kaolin-group minerals, such as halloysite
 and dickite, are encompassed.

     Common clay is defined as a clay or claylike material which is
 sufficiently plastic to permit ready molding and vitrification below
 1100°C.  Shale is a consolidated sedimentary rock composed chiefly of
 clay minerals which has been both laminated and indurated during
 burying  under other sediments.

     Table B-l lists the  primary uses for products of  the clay industry.


               Table B-l.  PRIMARY USES OF CLAY PRODUCTS

                                            (% of Product Used in the
 Product and Uses of Clay in 1973              Application Shown)

 Common Clay and Shale
     Brick                                         45.1
     Portland Cement                               25.4
     Lightweight Aggregate                         23.4
     Sewer Pipe                                     3.7
     Tile                                           1.6
     Other                                          0.8

Kaoli n
     Paper Coating and Filling                     40.6
     Brick                                          6.4
     Rubber                                         6.1
     Fire Brick                                     5.2
                                 36

-------
           Table B-l  (Cont'd).  PRIMARY USES OF CLAY PRODUCTS
                                             (% of Product Used  in  the
Product and Uses of Clay in 1973                 Application  Shown)

     Aluminum Sulfate and Other Chemicals           3.8
     Fiberglass                                     3.2
     Sanitary Ware                                  3.0
     Refractory Grogs and Crudes                    2.6
     Paint                                          2.2
     Portland Cement                                1.8
     Oil Refining Catalysts                         1.5
     Fertilizers                                    1.2
     Adhesives                                      1.1
     Plastics                                       1.0
     Exports                                       14.6
     Other                                          5.7

Bentonite
     Foundry Sand                                  25.7
     Iron Ore Pelletizing                          25.3
     Drilling Mud                                  18.6
     Filtering, Clarifying, Decolorizing            5.5
     Animal Feed                                    4.5
     Waterproofing and Sealing                      1.9
     Pesticides and Related Products                1.2
     Exports                                       14-3
     Other                                          3.0

Fuller's Earth
     Oil and Grease Absorbents                     31.3
     Pet Absorbent                                 29.3
     Pesticides and Related Products               15.4
     Drilling Mud                                   5.8
     Fertilizers                                    3.4
     Filtering, Clarifying, Decolorizing            2.6
     Exports                                        9-7
     Other                                          2-5

Ball Clay
     Sanitary Ware                                 £*.4
     Pottery                                       22-2
     Tile                                          16.2
     China/Dinnerware                               5.8
     Electrical Porcelain                           2-2
     Brick                                          }-'
     Exports                                       JJ-J
     Other                                         16-5
                                   37

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            Table B-l (Cont'd).  PRIMARY USES OF  CLAY  PRODUCTS
                                        (% of product Used in the
Product and Uses of Clay 1n 1973            Application Shown)

Fire Clay
     Firebrick                                     60.1
     Refractory Mortar and Cement                  12.7
     High-Alumina Refractories                      6.2
     Foundry Sand                                   5.6
     Refractory Srogs and Crudes                    4.4
     Sewer Pipe                                     2.5
     Flue Linings                                   2.2
     Tile                                           1.2
     Brick                                          1.1
     Exports                                        1.0
     Other                                          3.0
                                  38

-------
      APPENDIX C



COMPANIES AND PRODUCTS
         39

-------
Table C-l.   KAOLIN, BALL CLAY, FIRE CLAY, BENTONITE, AND FULLER'S
                           EARTH PRODUCERS

Location
Company (City and State)
American Colloid Corp. Skokie, 111
Anglo-American Clays
Corp. Atlanta, Ga.
Ashburg Graphite
Mills, Inc.
Ashland Ch. Co., Cleveland,
Foundry Prod. Div. Ohio
Archer, Daniels, Midland Cleveland,
Co., Foundry Prod. Div. Ohio
Alexandria Fire Clay Alexandria,
Co. Pa.
American Clay Tyler,
Forming Plant Texas
Alsey Refractories Alsey, 111.
ACF Corp. Canfield, Ohio
American Industrial Sandersville,
Clay Co. Ga.
Product
c
•1—
*o

X







X
to
o
r—
to
CO










1C
;_>
i_
•r-





X
X
X
X

Bentom'te
	 1
X

X
X
X





to
S-
0) .C
•mttm t_
3 «3
J_ 1 ' f










                                 40

-------
Table C-l (cont'd)
KAOLIN, BALL CLAY, FIRE CLAY, BENTONITE, AND



  FULLER'S EARTH PRODUCERS
Company (City and State)
Babcock & Wilcox Augusta,
Refractory Div. Ga.
Baker, J. T.
Chem. Co.
Burgess Pigment Sandersville,
Co. Ga.
Bell Clay Co. (TAM Gleason,
Div., NL Industries) Tenn.
Benton Clay Co. Mills, Wyo.
Black Hills
Bentonite Co. Mills, Wyo.
Cedar Heights Oak Hill,
Clay Co. Ohio
Chemical Heights
Clay Co.
Charles B. Crystal
Co., Inc. New York, N.Y.
C-E Minerals, Div.
Comb. Engr.
Cyprus Industrial
Minerals Co.
Product
£
"o
X
X
X



X


X
X
to
o
r—
to
co



X


X



X
o
U-






X


X
X
Bentonite




X
X
X
X
X


i/)
i.
i— -4J
"3 to
U_ LlJ








X


                                 41

-------
Table C-l (Cont'd)
KAOLIN,  BALL CLAY,  FIRE CLAY,  BENTONITE, AND
  FULLER'S EARTH PRODUCERS

Location
Company (City and State)
Can-Tex Industries Mineral Wells,
Div. Harsco Corp. Tex.
Crescent Brick New Cumberland,
Co. W. Va.
Carolina Ceramics,
Inc. Columbia, S.C.
Clay City Uhrichsv.il le,
Pipe Co. Ohio
Corundite Mass ill on,
Refractors Co. Ohio
Cairo Production
Co. Thomas, Ga.
Grossman Co. Sayreville, N.J.
Chicago Fire
Brick Co. Chicago, 111.
Ceramic Color & New Brighton,
Color Mfg. Co. Pa.
Chromalloy American
Corp. New York, N.Y.
Dresser Minerals, Div.
Dresser Ind. Houston, Tex.
Product
c
•g--
"o
3










X
>>
CO
i—"
CJ
r—
r™*
>
tO
r—
CJ

i.

i— i~.
3 re
Lu UJ





X





                                 42

-------
Table C-l (Cont'd).  KAOLIN, BALL CLAY, FIRE CLAY, BENTONITE, AND
                       FULLER'S EARTH PRODUCERS
Location
Company (City and State)
Dickey, W. S., Clay Kansas City,
Mfg. Co. Mo.
Dando, Frederick Irondale,
J., Co. Ohio
Davis Firebrick Co. Oak Hill, Ohio
Delhi Foundary Cincinnati,
Sand Co. Ohio
Edgar Plastic
Kaolin Co. Edgar, Fla.
Engelhard Minerals Decatur, Ga.
Entrada Industries Salt Lake City,
Interstate Brick Div. Utah
El Paso Brick Co. El Paso, Tex.
Elgin-Butler Brick Co. Austin, Tex.
Eureka Fire Brick Mt. Braddock,
Works Pa-
Freeport Kaolin Co. Twiggs, Ga.
Floridin Co.
Product
c
•T—
O
to
2*:





X




X

>>
01
O
t——
f~
m
ect




X







>>
«
o

-------
Table C-l (Cont'd)
KAOLIN, BALL CLAY, FIRE CLAY, BENTONITE, AND
  FULLER'S EARTH PRODUCERS

Location
Company (City and State)
Freeport Minerals Co.
France, J. H. Snoe Shoe,
Refractories Pa.
Georgia Kaolin Co. Twiggs, Ga.
Ga.-Tenn. Mining
& Chem. Co. Jefferson, Ga.
Great Lakes Detroit,
Foundry Sand Co. Mich.
Green, A. P. Refractories
Refractories Pueblo, Colo.
Garfield Refractories Co. Bolivar, Pa.
Harbison-Walker
Refractories
Harris Mining Co.
Haber, J. M. Twiggs &
Corp. Warren, Ga.
Hamrnill &
Gillespie, Inc.
Harrison & Crossfield
(Pacific, Inc.)
Product
c
•1—
o
2
X

X





X
X
X
X
>>
re
r— •
O
1— •
IB
CD


X









>J
US
O

-------
Table. C-l (Cont'd).  KAOLIN, BALL CLAY, FIRE CLAY, BENTONITE, AND
                       FULLER'S EARTH PRODUCERS
Location
Company (City and State)
Hickman, Williams
& Co. Chicago, 111.
Haws Refractories Co. Johnstown, Pa.
Hyzer & Southampton,
Lewellen Co. Pa.
I
International Minerals Libertyville,
& Chem. Corp. Ill,
Industrial Minerals
Corp.
Inland Refractories Co. Cleveland, Ohio
Keener Sand & Clay Co. Columbus, Ohio
Kaiser Refractories Oakland, Cal .
Kentucky Tennessee
Clay Co. Mayfield, Ky.
Kaul Clay Co. Toronto, Ohio
Lawrence Refractories
Co. Pedro, Ohio
Louisville Fire
Brick Works Louisville, Ky.
Product
c
•1—
"a
2












>>
«3
O
r—
1C
ca




X
X






$
o
ai
•r—
U_
X
X
X
X

X
X
X
X
X
X
X
Bentonite
X


X
X
X
X





l/»
i_
o
U. UJ












                                 45

-------
Table C-l (Cont'd).
KAOLIN, BALL CLAY, FIRE CLAY, BENTONITE, AND
  FULLER'S EARTH PRODUCERS
Location
Company (City and State)
Massillon Massillon,
Refractories Co. Ohio
Mid-Florida
Mining Co.
Meridan Petroleum Co.
Milwhite Co., Inc.
Mallinckrodt, Inc.
Mutchler Chem.
Co. Inc.
Materials for
Industry, Inc. Ambler, Pa.
Mt. Savage Pittsburg,
Refractories Co. Pa.
McCrody, Inc. Pittsburg, Pa.
Metropol i tan Canton ,
Ind., Inc. Ohio
NL Industries, Inc.
Baroid Div.
f-
Northern Chem. Inc.
Product
c
•r~
"a
s




X
X






>>
,
fd
r— •
O
CD
$_
•r—
u.
X






X
X
X


Bentonlte



X


X



X
X
C/l
S-
o> .£:
r- 4.*
r— i,
=5 
-------
Table C-1 (Cont'd).  KAOLIN, BALL CLAY, FIRE CLAY,  BENTONITE,  AND
Location
Company (City and State)
NL Industries, Inc.
Tarn Div.
Navron Mining &
Chem. Co.
New Castle New Castle,
Refractories Co. Pa.
North American Cleveland,
Refractories Ohio
N. J. Silican Sand Millville, N.J.
Old Hickory Clay Co. Paducah, Ky.
Oswald Refractories Co. St. Louis, Mo.
Ohio Fire Brick Co. Oak Hill, Ohio
Pfizer Minerals,
Pigment & Met. Div.
Porth Warner
Industries, Inc.
Pacific Clay Products Los Angeles, Cal .
Preskrey Refractories
Corp. Taunton, Mass.
Product
c
•i—
r— •
O
2












>>
03
CJl
*
03
X
X



X



X


>>

O)
i_
*T*"
u.
X

X
X
X
X
X
X

X
X
X
Bentonite








X




i.

-------
Table C-l (Cont'd).  KAOLIN, BALL CLAY, FIRE CLAY, BENTONITE, AND

Location
Company (City and State)
Peerless Mineral
Products Co. Conneaut, Ohio
Pyro Dlv. Oak Hill, Ohio
Petti nos, Geo. Bala Cynwyd,
F., Inc. Pa.
t
Pembring Mountain
Clays Co.
Porter Hk. Co., Inc. Pittsburg, Pa.
Rowley, Geo. A. & Co. Philadelphia, Pa.
Royal, H. M., Inc. Trenton, N.J.
i
Remmey, Div. Philadelphia,, Pa.
Spinks, H. C.
Clay Co.
Southeastern Clay Co.
Superior Material Co., Inc.
Solomon, L. A. &
Bros., Inc.
Sinclair Mineral &
Chem. Co.
Product
c
•r™
T—
o
CO
1£









X



>>
(O
o
(O
CD








X




>•>
0}
t— "
O

c~ i-
T3 td
Lu U.J










X
X
X
                                   48

-------
Table C-l (Cont'd),
KAOLIN, BALL CLAY, FIRE CLAY, BENTONITE, AND
  FULLER'S EARTH PRODUCERS
Location
Company _ (City and State)
Swank Refractories Johnstown,
Co. Pa.
Stevens, Div. Macon, Ga.
Superior Clay Uhrichsville,
Corp. Ohio
Thompson Hayward
Chem. Co.
Thiele Kaolin Co.
Thompson-Weinman
& Co.
Trans-Oceanic Huntington
Minerals Pk., Cal.
Thor Mining Co. Thomas, Ga.
United Materials & Richmond,
Richmond Brick Co. Calif.
Vanderbilt, R. T.
Co., Inc.
Waverly Mining Products Thomas, Ga.
Wyo-Ben Products
Product
c
•r—
"o
to
v:




X
X



X


>>
re
r— •
0
fO
CQ












>>
re
c_>
 jc
1 — ^-»
1— i.
3 re
U. LU



X



X


X

                                  49

-------
Table C-l (Cont'd).
KAOLIN, BALL CLAY, FIRE CLAY, BENTONITE, AND
  FULLER'S EARTH PRODUCERS
Location
Company (City and State)
Wilber Ellis Co.
Wellsville Fire Well svi lie,
Brick Co. Mo.
Whitehead Bros. Florham Park,
Co. N.J.
Wittekind, Cincinnati,
N. J. Co. Ohio
Woodbury Hoi 1 idaysburg ,
Clay Co. Pa.
Ferro Corp. Electro
Refractories &
Abrasives
Georgia Vitrified
Brick & Clay Co. Harlem, Ga.
Product
G
•1—
o
2







>,
IQ
O
"(0
00







>>
to
o
cu
u_

X
X
X
X
X
X
Bentonite
X






Fuller's
Earth







                                 50

-------
Table C-2.  COMMON CLAY, BRICK, AND  STRUCTURAL  CLAY  PRODUCERS
Company

Frame Brick & Title Co., Inc.
Henry Brick Co., Inc.
Jenkins Brick Co., Inc.
Keego Clay Products Co., Inc.
Birmingham Clay Products
Stephenson Brick & Tile Co.
Stephenson Brick Co., Inc.
Watkins Brick Co., Inc.
Huntsville Brick & Tile Co.
Excelsior Brick Co., Inc.
Jenkins Brick Co., Inc.
Alabama Brick & Tile Co.
Bickerstaff Brick Co., Inc.
Glen Gery Corporation
Watco Corporation
Bickerstaff Clay Products Co.
Cordova Brick Co., Inc.
Cambell Clinton Construction, Inc.
Zenith Glazed Products
Grabe Brick Co., Inc.
Tucson Pressed Brick Co.
Wheeler Brick Co., Inc.
Hope Brick Works
Acme Brick Co., Inc.
Acme Brick Co., Inc.
Malvern Brick & Tile Co.
Eureka Brick & Tile Co., Inc.
First Worth Corp.
First Worth Corp.
First Worth Corp.
Port Costa Clay Products
Craycroft Brick Co., Inc.
Atkinson Brick Co., Inc.
Davidson Brick Co., Inc.
Landau & Associates, Inc.
San Valle Tile Kilns
Lawrence P. McNear Co.
Cannon Brick Co., Inc.
California Clay Products
San Jose Brick & Tile Ltd.
Kraftile Company
Sumpf Hans Company
Castaic Clay Mfg. Co.
Pacific Clay Products
Selectile Corp., Inc.
Pacific Clay Products
    Location
(City and State)

Piedmont, Al.
Selma, Al.
Coosada, Al.
Brewton, Al.
Birmingham, Al.
Birmingham, Al.
Lovick, Al.
Birmingham, Al.
Huntsville, Al.
Montgomery, Al.
Montgomery, Al.
Decatur, Al.
Phenix City, Al.
Cardova, Al.
Cordova, Al.
Birmingham, Al.
Cordova, Al.
Phoenix,Az.
Tempe, Az.
Tucson, Az.
Tucson, Az.
Jonesboro, Ar.
Hope, Ar.
Perl a, Ar,
Malvern, Ar.
Malvern, Ar.
Clarksville, Ar.
Fort Smith, Ar.
Malvern, Ar.
Perla, Ar.
Port Costa, Ca.
Fresno, Ca.
Los Angeles, Ca.
Los Angeles, Ca.
Los Angeles, Ca.
Los Angeles, Ca.
San Rafael, Ca.
Sacramento, Ca.
Stockton, Ca.
San Jose, Ca.
Fremont, Ca.
Fresno, Ca.
Castaic, Ca.
Los Angeles, Ca.
La Habra, Ca.
Alberhlll, Ca.
                                 51

-------
Table C-2 (Cont'd).  COMMON CLAY, BRICK, AND STRUCTURAL CLAY PRODUCERS
Company

H. C. Muddox Company
Higgins Brick & Tile Co.
Missouri Valley Brick Co., Inc.
Colorado Brick Company, Inc.
Colorado Brick Co.
Denver Brick & Pipe Co., Inc.
Robinson Brick & Tile Co.
Lakewood Brick & Tile
Summit Pressed Brie1 Tile
Kelsey Ferguson Brick
Michael Kane Brick Co., Inc.
Plasticrete Corporation
Plasticrete Corporation
Delaware Brick Co., Inc.
Deleware Brick Co., Inc.
West Brothers Brick Co., Inc.
United Brick Corporation
Alhambra Tile Co., Inc.
Bickerstaff Clay Products
Burns Brick Co., Inc.
Cherokee Brick & Tile
Merry Companies, Inc.
Chattahoochee Brick Co., Inc.
Peavy Concrete Products Div.
Plainville Brick Co., Inc.
Clay Bickerstaff Products
Georgia Carolina Brick Co.
Merry Companies, Inc.
Burns Brick Co., Inc.
Brick Designs, Inc.
American Brick Co.
Brisch Brick Co., Inc.
Illinois Brick Co.
Illinois Brick Co.
Illinois Brick Co.
Illinois Brick Co., Inc.
Structural Glazed Masonry
Clow Corporation
New Albion Brick Co.
Eastern Illinois Clay Co.
Galesburg Brick Co.
Hydraulic Press Brick
Ristokrat Clay Products Co.
Colchester Brick & Tile Co.
Richards Brick Co., Inc.
Hydraulic Press Brick Co.
Hill  Brick Co., Inc.
Clay Products Co., Inc.
     Location
(City and State)

Sacramento, Ca.
Chino, Ca.
San Diego, Ca.
Longmont, Co.
Denver, Co.
Denver, Co.
Denver, Co.
Lakewood, Co.
Peublo, Co.
E. Windsor Hill, Ct,
Middletown, Ct,
Hamden, Ct.
North Haven, Ct.
Wilmington, De.
New Castle, De.
Washington, D. C.
Washington, D. C.
Miami, Fl.
Barth, Fl.
Macon, Ga.
Macon, Ga.
Savannah, Ga.
Atlanta, Ga.
Atlanta, Ga.
Plainville, Ga.
Columbus, Ga.
Augusta, Ga.
Augusta, Ga.
Macon, Ga.
Lake Park, Ga.
Riverdale, II.
Chicago, II.
Maywood, II.
Franklin Park,  II.
Chicago, II.
Blue Island,  II.
Chicago, II.
Wheaton, II.
Albion,  II.
Saint Anne,  II.
E. Galesburg,  II.
Streator,  II.
Tonica,  II.
Colchester,  II.
Edwardsville,  II.
Aledo,  II.
E. St.  Louis,  111.
Springfield,  II.
                                  52

-------
Table C-2 (Cont'd).  COMMON  CLAY,  BRICK, AND STRUCTURAL CLAY PRODUCERS
Company

Illinois Brick Co.
Western Brick Co.
Silbrico Corporation
Continental Brick Co.
Streator Brick Systems, Inc.
Galesburg Brick Co., Inc.
Peoria Brick & Tile Co., Inc.
Boston Bricks & Con. Products Co.
Arketex Ceramic Corporation
Bloomfield Shale, Inc.
Majenica Tile Co., Inc.
Jackson Brick & Holloware
American Precast Concrete
American Virtified Product
Adams Clay Products Co., Inc.
Martinsville Brick Co., Inc.
Colonial Brick Corporation
Marion Brick Corporation
Jackson Brick & Hollow Ware
IU Industrials, Inc.
Roll, Inc.
Redfield Brick & Tile
Rockford Brick & Tile Co.
Sheffield Brick & Tile Co.
Oskaloosa Clay Products
Adel Clay Products Co.
Des Moines Clay Co.
Roll, Inc.
Carlisle Brick & Tile Co.
Kalo Brick & Tile Co., Inc.
Kalo Brick & Tile Co., Inc.
Vincent Clay Products Co., Inc.
Sioux City Brick Tile Co.
Harsco Corporation
Harsco Corporation
United Brick & Tile Co.
Goodwin Tile & Brick Co.
Harsco Corporation
Harsco Corporation
Roll, Inc.
Harsco Corporation
Carlisle Brick & Tile Co.
Ballou Brick Co.
Humboldt Brick & Tile Co.
Kansas Brick & Tile Co., Inc.
Acme Brick Co., Inc.
General Finance, Inc.
    Location
(City and State)

Danville, II.
Danville, II.
La Grange, II.
Albion, II.
Streator, II.
Alton, II.
Peoria, II.
Springfield, II.
Brazil, In.
Bloomfield,  In.
Huntington,  In.
Brownstown,  In.
Indianapolis, In.
Crawfordsville,  In.
Martinsville, In.
Martinsville, In.
Cayuga, In.
Brazil, In.
Brownstown,  In.
Crawfordsville,  In.
Mason City,  la.
Redfield, la.
Rockford, la.
Sheffield, la.
Oskaloosa, la.
W. Des Moines, la.
Des Moines,  la.
Ottumwa, la.
Carlisle, la.
Fort Dodge,  la.
Fort Dodge,  la.
Fort Dodge,  la.
Sioux City,  la.
Mason City,  la.
Redfield, la.
Abel, la.
Des Moines,  la,
Des Moines,  la.
Grimes, la.
Des Moines,  la.
Ottumwa, la.
Carlisle, la.
Sergeant Bluff,  la.
Humboldt, Ks.
Hoisington, Ks.
Weir, Ks.
Concordia, Ks.
                                   53

-------
Table C-2 (Cont'd).  COMMON CLAY, BRICK, AND STRUCTURAL CLAY PRODUCERS
Company

Acme Brick Co., Inc.
Acme Brick Co., Inc.
Excelsior Clay Products
Big Run Coal & Clay Co., Inc.
Owensboro Brick & Tile Co.
Big Run Coal & Clay
H. P. Sipple Brick Co., Inc.
Corbin Brick Co.
General Shale Products Corp,
Bourbon Brick Co.
Athens Caddo Brick Co.
Acme Brick Co., Inc.
Mike Baker Brick Lafytt
Dixie Brick Inc.
St. Joe Brick Works, Inc.
Hammond Baton Rouge Brick
Kentwood Brick & Tile
Mike-Baker Brick Co. New IBR
Mike-Baker Brick Co. New IBR
La Chance Brothers Brick Co.
Champion Brick Co., Inc.
Baltimore Brick Co., Inc.
Chestertown Brick Co., Inc.
Somerville Thomas Co.
Victor Cushwa & Sons, Inc.
Baltimore Brick Co.
Maryland Clay Products, Inc.
Westfield Clay Products Co.
Stiles & Hart Brick Co.
Dacor Mfg. Co., Inc.
K-F Brick Co., Inc.
Comfort Brick & Tile Co.
Town & Country Face
American Cement Corp.
Twin City Brick Co., Inc.
OCHS Brick & Tile Co.
Mississippi Industries
Tri State Brick & T1li Co,
Laurel  Brick & Tile Co., Inc.
Brookhaven Pressed Brick
Columbus Brick Co., Inc.
Clay Products, Inc.
Holly Springs Brick & Tile
Southern Brick & Tile Co.
Savery Brick & Tile Co,
Delta Brick & Tile Co,, Inc.
Louisville Brick Co., Inc.
Delta-Macon Brick & T1li Co,
                                               Location
                                            (City and State)

                                            Kanopolis, Ks.
                                            Buffalo, Ks.
                                            Fredonia, Ks.
                                            Ashland, Ky.
                                            Owensboro, Ky,
                                            Lexington, Ky.
                                            Stanton, Ky.
                                            Corbin, Ky.
                                            Fairdale, Ky.
                                            Lexington, Ky.
                                            Mooringsport, La.
                                            Baton Rouge, La,
                                            Lafayette, La.
                                            Natchitoches, La.
                                            Slide!!, La.
                                            Hammond, La.
                                            Kentwood, La.
                                            New Iberia, La.
                                            Cade, La,
                                            Gorham, Me.
                                            Baltimore, Md.
                                            Baltimore, Md.
                                            Chestertown, Md.
                                            Muirkirk, Md.
                                            Williamsport, Md.
                                            Rocky Ridge, Md.
                                            Beltsville, Md.
                                            Westfield, Ma.
                                            Bridgewater, Ma.
                                            Worchester, Ma.
                                            Middleboro, Ma.
                                            Tecumseh, Mi,
                                            New Hudson, Mi
                                            Detroit, Mi.
                                            St. Paul, Mn.
                                            Springfield, Mn.
                                            Jackson, Ms.
                                            Jackson, Ms.
                                            Laurel, Ms.
                                            Brookhaven, Ms.
                                            Columbus, Ms.
                                            Holly Springs, Ms.
                                            Holly Springs, Ms,
                                            Byhalia, Ms.
                                            Baldwyn, Ms.
                                            Indiana!a, Ms.
                                            Louisville, Ms.
                                            Macon, Ms.
                                 54

-------
Table C-2 (Cont'd).  COMMON CLAY, BRICK, AND STRUCTURAL CLAY PRODUCERS
Company

Masonite Corporation
Columbia Brick & Tile Co.
Midland Brick & Tile Co.
Acme Brick Co., Inc.
Acme Brick Co., Inc.
Midland Brick & Tile Co.
Alton Brick Co., Inc.
Hydraulic Press Brick
Endicott Clay Products Co.
Ferguson & Co., Inc.
Western Brick & Supply Co.
Endicott Clay Products Co., Inc.
Yankee Hill Brick Mfg. Co.
Densmore Brick Co.
Kane Gonic Brick Corporation
Goodrich, W. S., Inc.
Alliance Clay Products
Church Brick Co.
Alliance Clay Products
Glen Gery Corporation
Sayre & Fisher Co.,  Inc.
New Jersey Shale Brick
Curran-Pfeiff Corporation
Kinney Brick Co.
Power! 1 & Minnock Brick Works
Binghamton Brick Co., Inc.
Acme Shale Brick Co., Inc.
Empire Clay Products, Inc.
Nassau Brick Co., Inc.
Jova Manufacturing  Co.,  Inc.
Terry Brick Corporation
Harder Silo Co.,
NL Industries, Inc.
Hanford Brick Co.,  Inc.
Sanford Brick Corporation
Ideal Brick Co., Inc.
Cunningham Brick Co., Inc.
Triangle Brick Co.,  Inc.
Kendrick Brick & Tile Co.
Boren Clay Products Co.,  Inc.
Fletcher Brick Co., Inc.
Statesville Brick Co.,  Inc.
Borden Brick & Tile Co.
Lee Brick & Tile Co., Inc.
Sanford Brick Corporation
Kendrick Brick & Tile Co.
                                               Location
                                            (City and State)

                                            Shuguolak, Ms.
                                            Columbia, Mo.
                                            St. Joseph, Mo.
                                            Harrisonyille,  Mo.
                                            Kansas City, Mo.
                                            Chillicothe, Mo.
                                            Hazelwood, Mo.
                                            St. Louis, Mo.
                                            Endicott, Nb.
                                            Lincoln, Nb.
                                            Nebraska City,  Nb.
                                            Fairburg, Nb.
                                            Lincoln, Nb.
                                            Leganon, NH
                                            Gonic, NH
                                            Epping, NH
                                            Hammonton, NJ
                                            Bordentown, NJ
                                            Winslow, NJ
                                            S. River, NJ
                                            Sayreville, NJ
                                            Somerville, NJ
                                            Edison, NJ
                                            Albuquerque, NM
                                            Coeymans, NY
                                            Binghamton, NY
                                            Hamburg, NY
                                            W. Falls, NY
                                            Farmingdale, NY
                                            Kingston, NY
                                            Kingston, NY
                                            Glens Falls, NY
                                            Niagara Falls,  NY
                                            Burlington, NC
                                            Gulf, NC
                                            Linden, NC
                                            Thomasville, NC
                                            Durham, NC
                                            Mount Holly NC
                                            Pleasant  Gardens, NC
                                            Fletcher,  NC
                                            Statesville, NC
                                            Sanford,  NC
                                            Sanford,  NC
                                            Colon,  NC
                                            Charlotte,  NC
                                  55

-------
Table C-2 (Cont'd).  COMMON CLAY, BRICK, AND STRUCTURAL CLAY PRODUCERS
Company

Nash Brick Co., Inc.
Pine Hall Brick & Pipe
Webster Brick Co., Inc.
Isenhour Brick & Tile Co.
Taylor Clay Products, Inc
Crump!er Brick & Tile Co.
Sanford Brick Corporation
Yadkin Brick Yard Inc.
Kendrick Brick & Tile Co.
Borden Brick & Tile Co., Inc.
Cherokee Brick Co. of N.C., Inc.
Bennett Brick & Tile Co.
Borden Brick & Tile Co., Inc.
Heritage Brick Co.
Basic Ceramics, Inc.
Boren Clay Products Co.
Hebron Brick Co., Inc.
American Vitrified Products
Metropolitan Industries
Summitville Tiles, Inc.
Cleveland Builders Supply
Cleveland Builders Supply
Ohio Clay Co., Inc.
Galena Shale Tile & Brick
Delaware Clay Co., Inc.
Claycraft Co., Inc.
General Hocking Brick Co.
Frederick J. Dano Co.
Marion Brick Corporation
Marion Brick Corporation
Marion Brick Corporation
Belden Brick Co., Inc.
Ohio Brick & Supply Co., Inc.
Richland Shale Brick Co.
Alliance Brick Corporation
Alliance Clay Products Co.
Belden Brick Co., Inc.
Belden Brick Company
Commercial Plating Div.
Glen Gery Corporation
Metropolitan Industries
Natco Corporation
Robertsville Brick
Camp Brick Co., Inc.
Belden Brick Co., Inc.
Claycraft Co., Inc.
Cleveland Builders Supply
   Location
(City and State)

Rocky Mount, NC
Madison, NC
Eden, NC
Salisbury, NC
Salisbury, NC
Roseboro, NC
Norwood, NC
New London, NC
Monroe, NC
Goldsboro, NC
Moncure, NC
Kings Mt., NC
Durham, NC
Lillington, NC
Hendersonville NC
Roseboro, NC
Hebron, ND
E. Liverpool Oh.
Negley, Oh.
Summitville, Oh.
Cleveland, Oh.
Bedford, Oh.
Cleveland, Oh.
Galena, Oh.
Delaware, Oh.
Columbus, Oh.
Logan, Oh.
Irondale, Oh.
Morral, Oh.
Caledonia, Oh.
Marion, Oh.
Somerset, Oh.
Mansfield, Oh.
Mansfield, Oh.
Alliance, Oh.
Alliance, Oh.
Canton, Oh.
Canton, Oh.
Canton, Oh.
East Canton, Oh.
Canton, Oh.
East Canton, Oh.
Robertsville,  Oh.
Mogadore, Oh.
Port Washington, Oh.
Sugarcreek,  Oh.
Newcomerstown,  Oh.
                                  56

-------
Table C-2 (Cont'd).  COMMON CLAY,  BRICK, AND  STRUCTURAL CLAY PRODUCERS
Company

Evans Brick & Pipe Co.
Shepfer & Moomaw Brothers, Inc.
Stone Creek Brick Co.,  Inc.
Strasburg Brick, Inc.
Whitacre-Greer Fireproofing Co., Inc.
Whitacre-Greer Fireproofing Co.
Bel den Brick Co.
Claycraft Co., Inc.
Fairfield Brick Co.
General Clay Products Co.
Medal Brick, Inc.
Claycraft Co., Inc.
Glen Gery Corporation
Bowerston Shale Co.
General Wadsworth Brick Corp.
Claycraft Co., Inc.
Glen Gery Corporation
Stark Ceramics
Larson Clay Pipe Co.
Sapulpa Brick & Tile Corp.
Mangum Brick Co.
Acme Brick Co., Inc.
Superior Clay Products, Inc.
Wewoka Brick & Tile Co.
Acme Brick Co., Inc.
Fram Corporation
First Worth Corp.
Shawnee Concrete Block & Brick
Klamath Falls Brick & Tile
Columbia Brick Works, Inc.
Darling Brick Clay Products
Freeport Brick Co.
Mi Hi ken Brick Co., Inc.
Mil liken Brick Co., Inc.
Colonial Clay Products Co.
Eastvale Clay Products Co.
Eastvale Stnd. Clay Products
General Dynamics Corp.
Metropolitan Industries
Glen Gery Corporation
Glen Gery Corporation
McAvoy Vitrified Brick Co.
Quakertown Brick & Tile Co.
Williamsgrove Clay Products Co.
Glen Gery Shale Brick Corp.
Layton Fire Clay Co., Inc.
Hanley Co., Inc.
   Location
(City and State)

Midvale, Oh.
Sugarcreek, Oh.
Stone Creek, Oh.
Strasburg, Oh.
Magnolia, Oh.
Magnolia, Oh.
Sugarcreek, Oh.
Sugarcreek, Oh.
Loarville, Oh.
Baltie, Oh.
Wooster, Oh.
Upper Sandusky, Oh.
Nelsonville, Oh.
Neward, Oh.
Ava, Oh.
Shawnee, Oh.
Magnolia, Oh.
Canton, Oh.
Gnadenhutton, Oh.
Sapulpa, Ok.
Mangum, Ok.
Oklahoma City, Ok.
Ada, Ok.
Wewoka, Ok.
Tulsa, Ok.
Tulsa, Ok.
Oklahoma City, Ok.
Wewaka, Ok.
Klamath Falls, Or.
Portland, Or.
Pittsburg, Pa.
Creighton, Pa.
Pitcairn, Pa.
Pittsburg, Pa,
New Brighton, Pa.
Beaver Falls, Pa.
New Brighton, Pa.
Darlington, Pa.
Darlington, Pa.
Shoemakersville, Pa,
Reading, Pa.
Phoenixville, Pa.
Quakertown, Pa,
Bigler, Pa.
Harrisburg, Pa.
Layton, Oh.
Summerville,  Pa.
                                 57

-------
 Table C-2 (Cont'd).   COMMON  CLAY,  BRICK,  AND STRUCTURAL  CLAY  PRODUCERS
 Company

 Glen Gery Shale  Brick  Corp.
 Lancaster Brick  Co.,  Inc.
 Fenati  Brick  Co.,  Inc.
 Hazelton  Brick Co.,  Inc.
 Hanley  Co.,  Inc.
 Glen Gery Corp.
 Watsontown Brick Co.,  Inc.
 Auburn  Brick  Co.
 Otto Brick &  Tile  Works
 Donley  Brick  Co.,  Inc.
 Monroeville Brick,  Inc.
 Glen Gery Shale  Brick  Corp.
 Alivene Brick Co.
 Milleken  Brick Co.
 Continental Clay Products  Co.
 New Bethlehem Tile Co.,  Inc.
 Broad River Brick  Co., Inc.
 Cheraw  Brick  Works,  Inc.
 J.  L. Anderson Co.
 Salisbury Brick Corp
 Rich!and  Shale Products  Co.
 Angus Brick & Tile  Co.,  Inc.
 Southern  Brick Co.,  Inc.
 Ashe Brick Co., Inc
 Guignard  Brick Works,  Inc.
 Pee  Dee Ceramics,  Inc.
 Rich!and  Shale Products
 Eastern Brick & Tile Co.
 Broad River Brick  Co.
 Waccamaw  Clay Products Co., Inc.
 Carolina  Ceramics,  Inc.
 Richtex Corp
 Black Hills Clay Products  Co.
 Clay Gleason  Products, Inc.
 W. G. Bush &  Co.,  Inc.
 General Shale Products
 Laird Brick Co.
 General Shale Products Corp.
 Old Hickory Brick Co., Inc.
 General Shale Products Corp.
 General Shale Products Corp.
 Gleason Clay  Products, Inc.
W. G. Bush &  Co.
 Clay Burn Mfg. Co.
 Elgin Butler  Brick Co.
Elgin Standard Brick Mfg.
Payne Brick Co.
    Location
(City and State)

Ephrata, Pa.
Lancaster, Pa.
New Castle, Pa.
Hazelton, Pa.
Bradford, Pa.
Watsontown, Pa.
Watsontown, Pa.
Auburn, Pa.
Springs, Pa.
Washington, Pa.
Trafford, Pa.
York, Pa.
New Oxford, Pa.
Cheswick, Pa.
Kittanning, Pa.
New Bethlehem, Pa.
Gaffney, SC
Cheraw, SC
Cheraw, SC
Summerville, SC
Winnsboro, SC
Ninety Six, SC
Ninety Six, SC
Van Wyck, SC
Cayce, SC
Pee Dee, SC
Columbia, SC
Sumter, SC
Blacksburg, SC
Myrtle Beach, SC
Columbia, SC
Columbia, SC
Belle Fourche, SD
Nashville, Tn.
Nashville, Tn.
Chattanooga, Tn.
Puryear, Tn.
Knoxville, Tn.
Greenback, Tn.
Kingsport, Tn.
Johnson City, Tn.
Gleason, Tn.
Gleason, Tn.
Palestine, Tx.
Elgin, Tx.
Elgin, Tx.
Elgin, Tx.
                                  58

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Table C-2 (Cont'd).  COMMON CLAY, BRICK, AND STRUCTURAL CLAY PRODUCERS
Company

Alamo Clay Products Co., Inc.
Texas Brick Co., Inc.
Texas Granite Corp.
Saville Baker Brick Co.
Martin Brick Co.,  Inc.
Ferris Brick Co.
Reliance Clay Products Co.
Acme Brick Co.
Acme Brick Co., Inc.
Barren Brick Co.,  Inc.
Ferris Brick Co.,  Inc.
El Paso Brick Co., Inc.
Teague Brick & Tile Co., Inc.
Acme Brick Co., Inc.
Andy Cordell Brick Co.
Houston Brick & Tile Co.
Roy Champiomont Marble
Saville Baker Brick Co.
Marshall Brick Co., Inc.
Athens Brick Co.,  Inc.
Texas Clay Products, Inc.
Texas Clay Tile, Inc.
Wes-Tex Clay Products
Rio Clay Products
San Jose Brick Co.
Valley Brick & Tile Co.
Barren Brick Co.,  Inc.
Waco Brick Mfg. Co., Inc.
D Hanis Brick & Tile Co.
Acme Brick Co., Inc.
Whiteselle Brick & Lumber
Mineral Wells Clay Products
Reliance Clay Products, Inc.
Acme Brick Co., Inc.
Henderson Clay Products
Major Brick Co., Inc.
Reliance Clay Products, Inc.
Acme Brick Co.
Abilene Brick Co., Inc.
Laredo Brick & Tile Co., Inc.
Acme Brick Co., Inc.
Wes-Tex Clay Products Corp.
Temtex Industries, Inc.
Coachman Industries, Inc.
Interstate Brick Co.
International Pipe Corp.
Densmore Brick Co.
   Location
(City and State)

Elmendorf, Tx.
Brownwood, Tx.
Marble Falls, Tx.
Leesburg, Tx.
Coleman, Tx.
Mesquite, Tx.
Dallas, Tx.
Denton, Tx.
Ferris, Tx.
Palmer, Tx.
Ferris, Tx,
El Paso, Tx.
Teague, Tx.
McQueeney, Tx.
Houston, Tx.
Houston, Tx.
Barker, Tx.
Houston, Tx.
Marshall, Tx.
Athens, Tx.
Malakoff, Tx.
Malakoff, Tx.
Athens, Tx.
Mission, Tx.
McAllen, Tx.
Mission, Tx.
Groesbeck, Tx.
Waco, Tx.
D Hanis, Tx.
Garrison, Tx.
Corsicana, Tx.
Mineral Wells, Tx.
Mineral Wells, Tx.
Mill sap, Tx.
Henderson, Tx.
Henderson, Tx.
Lindale, Tx.
Fort Worth, Tx.
Abilene, Tx.
Laredo, Tx.
Bridgeport, Tx.
De Leon, Tx.
Malakoff, Tx.
Olney, Tx.
Salt Lake City, Ut.
Ogden, Ut.
Essex Junction, Vt.
                                   59

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Table C-2 (Cont'd).  COMMON CLAY, BRICK, AND STRUCTURAL CLAY PRODUCERS
Company

Brick & Tile Corp.
Daniels Brick & Tile Co.
Redford Brick Co., Inc.
General Shale Products Corp.
Webster Brick Co., Inc.
Webster Brick Co., Inc.
Old Virginia Brick Co., Inc.
Locher Brick Co., Inc.
Webster Brick Co., Inc.
General Shales Products
Woodbridge Clay Products Co.
Webster Brick Co., Inc.
International Pipe & Ceramics
Meridian Brick Co., Inc.
Mutual Materials Co.
Mutual Materials Co., Inc.
Chehalis Brick & Tile Co.
Mutual Materials Co., Inc.
Lowell Brick & Tile Co., Inc.
Lowell Brick Co.
Mutual Materials Co.
Interpace Corp.
Continental Clay Products
United Clay Products Co.
Barboursville Clay Mfg. Co.
Charleston Brick & Tile
Capitol Supply Corp.
Weston Jane Lew Brick Tile
Koser Silo Works, Inc.
Lowell Clay Products, Inc.
  Location
(City and State)

Lawrenceville, Va.
Richmond, Va.
Richmond, Va.
Richmond, Va.
Suffold, Va,
Somerset, Va.
Salem, Va.
Glasgow, Va.
Webster, Va.
Richlands, Va.
Manassas, Va.
Webster, Va.
Seattle, Wa.
Seattle, Wa.
Renton, Wa.
Seattle, Wa.
Chehalis, Wa.
Eatonville, Wa.
Lowe!1, Wa.
Everett, Wa.
Seattle, Wa.
Mica, Wa.
Martinsburg, WV
Hedgesville, WV
Barboursville, WV
Charleston, WV
Weston, WV
Weston, WV
Almena, Wi.
Love!1, Wyo.
                                  60

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TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1. REPORT NO.
EPA-600/2-77-023s
2.
4. TITLE AND SUBTITLE
Industrial Process Profiles for Environmental Use:
Chapter 19. The Clay Industry
7. AUTHOR(S)
J.T. Reding, K.E. Bishop, P.E.Muehlberg & B. P. Shepherd
(Dow Chem. ) , & Terry Parsons & Glynda Wilkins, Editors
9. PERFORMING ORGANIZATION NAME At-
Radian Corporation
8500 Shoal Creek Blvd., P.C
Austin, Texas 78766
«ID ADDRESS
). Box 99^8
12. SPONSORING AGENCY NAME AND ADDRESS
Industrial Environmental Research Laboratory
Office of Research and Development
U.S. ENVIRONMENTAL PROTECTION AGENCY
Cincinnati, Ohio ^5268
3. RECIPIENT'S ACCESSIOI*NO.
5. REPORT DATE
February 1977
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
1AB015
11. CONTRACT/GRANT NO.
68-02-1319/ Task 3^
13. TYPE OF REPORT AND PERIOD COVERED
Initial: 8/75-11/76
14. SPONSORING AGENCY CODE
EPA/600/12
)E. SUPPLEMENTARY NOTES
16. ABSTRACT
The catalog of Industrial Process Profiles for Environmental Use was developed as an
aid in defining the environmental impacts of industrial activity in the United States.
Entries for each industry are in consistent format and farm separate chapters of the
study. The clay industry is involved in mining of clay minerals, beneficiating of
clay minerals, and brickmaking. The industry is discussed in two segments: (l) Clay
Production and (2) Brick Manufacture. One chemical tree, two process flow sheets
and nine process descriptions have been prepared to characterize the industry.
Within each process description available information has been provided on input
materials, operating parameters, utility requirements and waste streams. Data re-
lated to the subject matter, including company, product and raw material data, are
included as appendices.
17.
a. DESCRIPTORS
Pollution
Industrial Processes
Chemical Engineering
KEY WORDS AND DOCUMENT ANALYSIS
b. IDENTIFIERS/OPEN ENDED TERMS C. COSATI Field/Group
Process Assessment 13B 11B, 13C
Environmental Impact 13H
Brickmaking 07A
EPA Form 2220-1 (9-73)
61
                                                                                                6USGPO: 1979-659-510/32

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