EPA-600/2-77-172
August 1977
Environmental Protection Technology Series
                                 VENTURI  SCRUBBER
                              PERFORMANCE  MODEL
                                Industrial Environmental Research Laboratory
                                      Office of Research and Development
                                     U.S. Environmental Protection Agency
                                Research Triangle Park, North Carolina 27711


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                                      EPA-600/2-77-172
                                            August 1977
  VENTURI  SCRUBBER
PERFORMANCE  MODEL
                  by

        Shui-Chow Yung, Seymour Calvert, and
             Harry F. Barbarika

                A.P.T., Inc.
         4901 Morena Boulevard, Suite 402
           San Diego, California 92117
            Contract No. 68-02-1328
               Task No. 13
             ROAP No. 21ADL-002
          Program Element No. 1AB012
         EPA Task Officer: Leslie E. Sparks

      Industrial Environmental Research Laboratory
       Office of Energy, Minerals, and Industry
         Research Triangle Park, N.C. 27711
               Prepared for

      U.S. ENVIRONMENTAL PROTECTION AGENCY
        Office of Research and Development
            Washington, D.C. 20460

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                          ABSTRACT

     A review and evaluation of the available venturi scrubber
design equations are presented.  Calvert's differential equation
for particle collection and Boll's differential equation for
pressure drop are selected for numerical solution and the results
presented graphically.
     The particle collection and pressure drop of venturi scrub-
bers can be approximated by the collection occurring in the ven-
turi throat and by the drop acceleration loss respectively.  Sim-
plified equations were derived by applying Calvert's and Boll's
equations to the venturi throat section.  The new design equa-
tions are  much simpler to use and compare  well with available
performance data.
     This report was submitted in partial fulfillment of Contract
Number 68-02-1328, Task Number 13 by Air Pollution Technology,
Inc. under the sponsorship of the U.S. Environmental Protection
Agency.  This report covers the period March 1, 1976 to May 30,
1976, and work was completed as of June 30, 1976.
                              11

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                           CONTENTS


                                                          Page

Abstract	   ii
                                    i
Figures	   iv

Tables	   ix

Abbreviations and Symbols  	   x

Acknowledgement  	   xv



       1.  Introduction	    1

       2.  Summary and Conclusions  	    4

       3.  Literature Search  	   16

       4.  Comparison of  Model with Experimental Data.  .  .   41

       5.  Performance Model  	   61

       6.  Comparing Model Predictions with Performance
           Data	114

       7.  Design Analysis	128

       8.  Entrainment Separator  	 161




References	191

Appendix	195
                                iii

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                       FIGURES

Number                                          Page
 1-1    Venturi Scrubber System 	     3

 3-1    Target Efficiency Results  of Various
        Investigators 	    20

 3-2    Drag Coefficient of a Sphere	    27

 4-1    Dimensions of GAP Venturi  Scrubber  .  .    43

 4-2    Comparison of Predicted Pressure Drop
        with Experimental Data from Wen and
        Uchida	    44

 4-3    Comparison of Predicted Pressure Drop
        with Experimental Data from Wen and
        Uchida	    45

 4-4    Comparison between Behie and Beeckmans1
        Prediction and Experimental Data from
        Wen and Uchida	    46

 4-5    Comparison of Predicted Pressure Drop  by
        Modified Calvert's Equation with Data
        from Wen and Uchida	    51

 4-6    Prototype Venturi Scrubber Used by Boll    52

 4-7    Comparison of Boll's Pressure Drop Data
        with Theory	    53

 4-8    Dimension of Pease-Anthony Venturi
        Scrubber Used by Brink and Contant. .  .    55

 4-9    Comparison of Brink and Contant Experi-
        mental Data with Theories	    57

 4-10   Dimensions of the Ekman and Johnstone
        Venturi	    58

 4-11   Comparison of Eleman and Johnstone's
        Pressure Drop Data with Theories  ...    59

 5-1    Chart for Obtaining u| for a Circular
        Duct	    72
                            iv

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                    FIGURES (continued)


Number

 5-2   Chart for Obtaining u5 for a Rectangular
       Duct	7	73

 5-3   Chart for Obtaining p| for a Circular Duct  74

 5-4   Chart for Obtaining p^j for a Rectangular
       Duct	: . 7	  75

 5-5   Chart for Obtaining Penetration for Circu-
       lar Duct	76

 5-6   Chart for Obtaining Penetration for Circu-
       lar Duct	  77

 5-7   Chart for Obtaining Penetration for Circu-
       lar Duct	  7S

 5-8   Chart for Obtaining Penetration for Circu-
       lar Duct	  79

 5-9   Chart for Obtaining Penetration for Circu-
       lar Duct	80

 5-10  Chart for Obtaining Penetration for Rectan-
       gular Duct	  81

 5-11  Chart for Obtaining Penetration for Rectan-
       gular Duct	  82

 5-12  Chart to Obtain Penetration for Rectangular
       Duct	  83

 5-13  Chart to Obtain Penetration for Rectangular
       Duct	  84

 5-14  Chart to Obtain Penetration for Rectangular
       Duct	  85

 5-15  Chart to Obtain Penetration for a Rectan-
       gular Duct	  .  86

 5-16  Chart to Obtain Penetration for a Rectan-
       gular Duct	  87

 5-17  Concept of a Hypothetical Section   ....  88

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                    FIGURES (continued)


Number

 5-18  Chart for Obtaining LH for a Circular Duct   90

 5-19  Chart for Obtaining LH for a Rectangular
       Duct	   91

 5-20  Ventrui Scrubber for Sample Calculation. .   93

 5-21  Predicted Grade Efficiency Curve  	   98

 5-22  Predicted Grade Efficiency Curve  	  110

 6-1   Experimental and Predicted Performance of
       AAF Kinpactor 32 Venturi  Scrubber  	  116

 6-2   Experimental and Predicted Performance for
       AAF Kinpactor 32 Venturi  Scrubber  	  117

 6-3   Predicted and Experimental Penetration for
       Venturi Scrubber Used by  Brink and Contant  118

 6-4   Predicted and Measured Penetration for
       Chemico Venturi Scrubber   	  121

 6-5   Predicted and Experimental Grade Efficiency
       Curve for Chemico Venturi Scrubber  . .  . .122

 6-6   APS Electrostatic Scrubber  	  123

 6-7   Experimental and Predicted APS Venturi
       Scrubber Performance  	  124

 6-8   Predicted and Experimental Performance for
       Venturi Rod Scrubber	126

 7-1   Venturi Scrubber Integrated Penetration,
       "Pt" versus "dp50/dpg", with "K  " as para-
       meter,  "a =2.5"	134
                o
 7-2   Venturi Scrubber Integrated Penetration,
       Pt versus d 5Q/d  , with  k   as parameter,
        n    •••••*« t.^ •  * • •  « *  .  , ^   B •  J. j»)
7-3   Venturi Scrubber Integrated Penetration,
      Pt versus d 5Q/d  , with K   as parameter,
      a=7.5 . . .  .  .  .  . .  .  .  \°.  . . .
                                                   136
                            VI

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                   FIGURES  (continued)


Number                                             Page
7
7
7
7
-4
-5
-6
-7
"Pt" versus
"a =2.5" . .
g
"Pt" versus
"a =5" . . ,
g
"Pt" versus
"a =7.5" . ,
g
dpa50/dpg v<
meter . . ,
"B"
"B"
"B"
3TSUS
with "Kpg"
with "K "
with "Kpg"
"B-'.with '
as parameter,
as parameter,
as parameter,
'K " as para-
. 138
. 139
. 140
. 141
 7-8   Effect of Throat Length on Penetration .  .  .  142

 7-9   Effect of Throat Length on Performance .  .  .  144

 7-10  Predicted Venturi Scrubber Performance, K rn
       versus B	? .  145

 7-11  Effect of Gas Velocity and Liquid to Gas
       Flow Rate Ratio on Performance Cut Diameter  147

 7-12  "B" vs "K   '' for venturi throat of infinite
       length . ?	148

 7-13  Predicted Venturi Performance, "dpaso" ver-
       sus QL/QG with "UG" and " P" as Parameter. .  149

 7-14  Aerodynamic Cut Diameter Versus Pressure
       Drop with Liquid to Gas Ratio as Parameter .  150

 7-15  Impaction parameter vs aerodynamic cut
       diameter for a venturi design  	  154

 7-16  Pressure drop vs aerodynamic cut diameter
       for venturi design example 	  157

 7-17  Impaction parameter vs QT/Qr for venturi
       design example	160

 8-1   Cyclone with tangential gas inlet	155

 8-2   Generalized flooding and pressure drop
       correlation for packed beds (Perry, 1963). .  174
                           VII

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                   FIGURES  (continued)

Number

 8-3  Theoretical and experimental collection
      efficiencies of rectangular aerosol jets. . 176

 8-4  Theoretical impaction efficiency as a func-
      tion of inertial parameter for different
      targets	177

 8-5  Friction factor, f, versus Reynolds num-
      ber, NR  G for wire mesh entrainment se-

      parator with entrainment load	182

 8-6  Pressure drop due to presence of liquid in
      the knitted mesh with the crimps in the
      same direction	183

 8-7  Pressure drop due to presence of liquid in
      the knitted mesh with the crimps in the
      alternate direction	,	183

 8-8  Drag coefficient versus Reynolds number
      after Foust et al (1959) , with sphericity
      i|> as the parameter	187

 8-9  Drag coefficients for flow past inclined
      flat plates (data from A. Page § F.C. Jo-
      hansen, (1927)  	 187
                            viii

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                       TABLES
Number
 2-1   Correlation for Particle Collection in
       Venturi Scrubber	
 2-2   Correlations for Pressure Drop in Venturi
       Scrubber 	   8

 2-3   Entrainment Separator Design Equations .  .  12

 3-1   Empirical Equations for Average Liquid
       Drop Size and Their Applicable Ranges  .  .  25

 3-2   Correlations for Pressure Drop in Venturi
       Scrubber	  37

 4-1   Wen and Uchida's Experimental Pressure
       Drop Data on O.A.P. Venturi Scrubber  ...  42

 4-2   Wen and Uchida's Experimental Data and
       Predictions by Boll and by Behie and
       Beeckmans	  48

 8-1   Bed Porosity, e, for Various Packing
       Materials	171

 8-2   Experimental Values of j, Channel Width
       as Fraction of Packing Diameter  	

 8-3   Packing Factors "F", for Dumped Pieces
       (m2/m3)	172

 8-4   Packing Factors "F" for Grids and Stacked
       Pieces  (m2/m3) .;	173
                            ix

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                                                    2
            ABBREVIATIONS AND SYMBOLS

Latin
A      «  cross-sectional area,  cm2
A      *  cross -sectional area at the duct inlet, cm
 o
A      =  total projected area of baffles per row in
          the direction of inlet air flow, cm2
A      =  ratio of exit to inlet duct cross-sectional
          area, dimensionless
A      =  throat cross-sectional area, cm2
a2     =  specific area of mesh, cm2/cm3
B      =  dimensionless liquid-to-gas flow-rate tatio
          parameter, dimensionless
                 !L  /  UGO  \
                 PG  \uGo-udo/
                              °'5
                  G
          dimensionless parameter
b      =  duct breadth, cm
b      =  spacing between two consecutive baffles  in
          same row, cm
C1     =  Cunningham slip factor, dimensionless
CD     =  drag coefficient, dimensionless
CDQ    =  initial drag coefficient, dimensionless
c      =  concentration of particles,  g/cm3
c      =  capillary number
 3.
c^     =  number concentration of drops, #/cm3
Cj     =  concentration of particles  in  the main
          stream of gas, g/cm3
D      =  diffusivity of particle, cm2/s
d      =  cyclone diameter, cm
d      =  collector or packing diameter, cm
d,     =  liquid drop diameter, cm
d      =  equivalent diameter, cm
 eq

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         Abbreviations and Symbols (continued)

d      =  mean drop diameter, cm
d      =  nozzle diameter, mm
d      =  initial inlet or outlet duct diameter, cm
d      =  particle diameter, cm or ym
d      =  aerodynamic particle diameter, umA
 pa
d      =  cut diameter, ymA
dR(,    =  required cut diameter, ymA
d      =  venturi throat diameter, cm
E      =  collection efficiency, fraction
E,     =  eddy diffusivity of liquid drops, cm2/s
E      =  eddy diffusivity of particles, cm2/s
F      =  drop flux, g/cm2-s
F      =  packing factor, m2/m3
Fg     =  foam density
                                               if
f      *  empirical  constsnt, dimensionless
f      =  friction factor, dimensionless
ft     =  average friction factor of the venturi
          throat, dimensionless
r      =  average friction factor of the convergent
          section, dimensionless
f,     =  average friction factor of the divergent
          section, dimensionless
g      =  conversion factor
H,     =  fractional liquid  hold-up,, fraction
j      =  ratio  of channel width to packing
          diameter,  dimensionless
K      =  inertial parameter, dimensionless
K      =  inertial parameter at  venturi  throat,
 pt
          dimensionless
K      =  initial inertial parameter,  dimensionless
K      =  inertial parameter for mass  median  particle
          diameter,  dimensionless
k      =  Boltzman1 s constant
                            XI

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         Abbreviations and Symbols (continued)

          dimensionless length parameter
          •z o r   0   /u  -u, \°-5
               Do  G  /  Go  do I
           2 dd PL    V  UGO  /
H      =  length, cm
X.      =  venturi throat length, cm
lz     =  thickness of mesh pad, cm
M      =  liquid-to-gas mass flow-rate ratio, dimensionless
mG     =  gas mass flow rate, g/s
nu     =  liquid mass flow rate, g/s
N      =  number of jet stages in the tube bank, i.e.,
          (number of rows) - 1
N      =  number of collection transfer units
n      -  cyclone vortex component, dimensionless
n      =  number of zigzag baffle rows
P      =  drop flight path length, cm
Pt(d ) =  particle penetration for particles with
          diameter d , fraction
Pt     =  overall penetration, fraction
p      =  local pressure, dyne/cm2
p      =  component of "p" associated with wall
 w
          friction, dyne/cm2
Q,     =  source strength, #/cm3
QG     =  gas volumetric flow rate, cm3/s
QT     =  liquid volumetric flow rate, cm3/s
 Li
R      =  radius (for circular duct) or half-width
          (for rectangular duct) at the start of a
          given duct, cm
Rd     =  washing factor for divergent section, dimensionless
Rt     =  washing factor for venturi throat, dimensionless

S      =  dimensionless parameter characterizing slope
          of the given duct
          2 tan 3
                                   °-5
                  ——     I
                   Do PG \ Go" do>
                         XII

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         Abbreviations and Symbols (continued)

s      =  specific surface of drops .formed, cm2/cm3
T      =  gas temperature, °K
t      =  time, s
u,     =  liquid drop velocity, cm/s
u,     -  initial drop velocity, cm/s
UG     =  gas velocity, cm/s
Up     =  initial gas   velocity, cm/s
uGt    =  ^as velocitv at tne venturi throat, cm/s
u,     =  liquid velocity, cm/s
u      =  relative undisturbed upstream velocity, cm/s
u      =  particle velocity, cm/s
u.     =  tangential gas velocity, cm/s
u      -  drop terminal centrifugal velocity, cm/s
  c c
Up     =  dimensionless gas velocity in x  direction
u      =  dimensionless particle velocity  in x direction
v      =  dimensionless gas velocity in y  direction
 &
v      =  dimensionless particle velocity  in y direction
w      =  width of baffle, cm
       =  weight of particles collected, g
X      =  dimensionless parameter
       =  5  *t CDo PG  . .
           16 dd PL
x      =  coordinate perpendicular to gas  flow,  cm
y      =   coordinate perpendicular  to  gas  flow,  cm
z      =   axial  coordinate,  cm
Greek Symbols
3      =   half angle of  divergence  or  convergence, degrees
£      =   head-loss ratio  for  throat,  dimensionless
£,     =   head loss ratio  for  divergent section,  dimensionless
6      =   distance from  collector center,  cm
                            Xlll

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         Abbreviations and Symbols (continued)
p      =  gas density, g/cm3
p      =  manometer  fluid density, g/cm3
p,     =  liquid density, g/cm3
p      =  particle density, g/cm3  ;,
6      =  divergence angle or baffle angle,  degrees
61     =  convergence angle, degrees
92     =  divergence angle, degrees
n      =  single drop collection efficiency,  fraction
]JG     =  gas viscosity, poise
yL     =  liquid viscosity, poise
VG     =  kinematic viscosity of gas,cm2/s
cf>      =  rate of deposition, g/s
a      =  surface tension, dyne/cm
AP     =  pressure drop, cm W.C.
AP,    =  dry pressure drop, cm W.C.
AT     =  temperature change, °K
Superscript
*      =  dimensionless parameter
Dimensionless numbers
NRed   =  ^r°P Reynolds number  based on diameter
NReo   =  initial drop Reynolds number
NSc    =  Particle Schmidt number
N'sh   =  particle Sherwood number
                             xlv

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                       ACKNOWLEDGEMENT

     A.P.T., Inc. wishes to express its appreciation for excellent
technical coordination and for very helpful assistance in support
of our technical effort to Dr. Leslie E. Sparks,  EPA Project
Officer.
                                xv

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                          CHAPTER 1
                        INTRODUCTION

     Venturi scrubber is one type of gas atomized spray scrubber.
It employs gradually converging, then diverging sections.  The
venturi throat is the section between the converging and diver-
ging sections.  Usually liquid enters the venturi upstream of
the throat through nozzles.  Alternately, the liquid may flow
along the converging section walls until reaching the throat.
                   y
At the throat, the/liquid is shattered into drops by the high
velocity gas.  Sometimes the liquid is introduced as pre-atomized
drops at" or before'the throat through a pressure nozzle.  The
venturi may have a round, square, or rectangular cross section.
For the rectangular duct, the breadth of the duct is usually in-
variant and only duct width diverges or converges.
     Venturi scrubbers have been widely recognized as having a
high collection efficiency'for fine particles and have been
successfully used for years to remove particles and mists from
gas streams.  Particle collection efficiency in a venturi
scrubber generally increases with pressure drop.  High pressure
drop (100 cm W.C. or 40 in. W.C.) venturi scrubbers can effi-
ciently collect submicron particles.
     The venturi scrubber has several distinct advantages when
compared with other scrubber types.  The scrubber construction
is simple, thus the initial capital investment is low.  Through
adjusting pressure drop by varying liquid flow or gas velocity,
it can be made to collect even submicron fume with good effi-
ciency.  Due to the absence of moving parts, it can be used  for
the collection of sticky particles.
     The venturi scrubber also has disadvantages:  It requires
high pressure drop for the collection of submicron particles
which results in a high operating cost, and its applicability

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for mass transfer problems is limited due to the co-current
nature of the gas-liquid flow.  To prevent possible water pollu-
tion problems, it also requires water treatment facilities.
     Figure 1-1 describes a commonly encountered venturi
scrubber system.  It consists of a venturi scrubber, an en-
trainment separator, liquid treatment facilities, and gas and
liquid movers.
     The atomized liquid drops or liquid entrainment must be
separated from the gas stream before the; gas is emitted into
the atmosphere.  There are a number of -devices which are commonly
used as entrainment separators which are added either within the
venturi outlet duct or in another vessel.  Zig-zag baffles, cy-
clone separators, and guide vanes causing rotation of the gas
stream are frequently used for this purpose.
     In the present study, only the design of venturi scrubber
itself and its entrainment separator will be reviewed and evalua-
ted.

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Emission
  Prom
 Source
ntrainment
Separator
                                                                Stack
                                          Liquid
                                        Treatment
                 Figure 1-1. Venturi scrubber system,

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                      CHAPTER 2
               SUMMARY AND CONCLUSIONS

     Venturi scrubbers are used extensively for the collec-
 tion of small particles.  The major impediment to their practi-
 cal use is that they have high pressure drops which result in
 high operating cost.  With a better understanding of the
 fundamentals of the operation of this type of scrubber,
 the pressure drop could be lowered without affecting
 particle collection.
     The objectives of the study reported here were to  (1)
 review and evaluate all available venturi scrubber perfor-
 mance models and design models (2) recommend the best
 model and  (3) prepare a design manual based on this model.

 LITERATURE SEARCH
 Particle Collection Efficiency
     The particle collection efficiency of a venturi scrub-
 ber is influenced by many parameters, such as particle size
 and size distribution, gas velocity, liquid-to-gas ratio,
 etc.  There are several mathematical models available for
 the prediction of particle collection efficiency in a ven-
 turi scrubber.  All models are based on particle impaction
 on liquid drops.  Table 2-1 summaries all models.
 Pressure Drop
     Pressure drop in a venturi consists of two parts,
namely acceleration loss and wall-friction loss.  Most of
the losses are due to acceleration and these may
be calculated from hydrodynamics.  Wall-friction loss
depends  on scrubber geometry and usually is determined
experimentally.   Table 222 lists several available corre-
lations  for the  prediction of pressure drop in a venturi

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           TABLE 2-1.  CORRELATION FOR PARTICLE COLLECTION

                       IN VENTURI SCRUBBER
Investigator
                                         Correlation
Ekman § Johnstone
  (1951)
Pt(dp) = exp
                                      3 n P s
                                      490
                                          P s"|
                                          ,OOOJ
Calvert  (1968)
                        c    u,,   fiu-iOA  \4r
                                                n  dz
                               G   V"G  "r-
Calvert (1970)        Pt(d ) = exp
                                     2 QL  UG  PL  dd
                                     55 Q y
                      F(Kpt,  f)  - K
                                   pt
                                                  F  (K   , f)
                                                    f  *  °-7
                                        1.4 In
                                   0.7  +  Kpt  £
Morishima et al.
  (1971)
                      Pt(d)  -  exp   -  (Rt  +  Rd)
                                                 dX
                      R   =
                            '0
                                       U
                           2d
                                               ur \
                                                \j \  j v
                                               TT- I  dX
Dropp § Akbrut
   (1972)
                     Pt(dp) = exp
                                                            dz

Boll  (1973)
                     Pt(dp) = exp
                                               m
                                                       n ur - u,
                                                          G    d
                                               mG/\pL
                                                                 dt
                                                        continued

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                      TABU-:  2-1.  (Continued)
  Investigator
                              Correlation
  Behie § Beeckmans   Pt(d)= exp
    (1973)
   Taheri § Sheih
     (1975)
 H -
                 If
       9c,         9cj
       	d =  _  „   	d
       3t      d  9z
where
      A  =  cross-sectional area, cm2
      c  =  concentration of particulates,  g/cm3
     c,  =  number concentration of drops,,  #/cm3
     d,  =  drop diameter, cm
     Ed  =  eddy diffusivity of drops, cm2/s
     E   =  eddy diffusivity of particle, cm2/s
      F  =  drop flux, g/cm2-s
      f  =  empirical constant
      t  =  inertial parameter at venturi throat,
          dimensionless
      £  =  length, cm
    mG  =  gas mass flow rate, g/s
    nu  =  liquid mass flow, g/s
     P  =  drop flight path length, cm
Pt(dp)  = penetration for particles with  diameter,
         K
              d  , fraction
         Qd = source strength,  #/
                            cm-
                                           continued

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where      Q~ = volumetric gas flow rate, cm3/s
           QL = volumetric liquid flow rate, cm3/s
            s = specific surface of drops, cm2/cm3 of gas
            t = time, s
           u, = drop velocity, cm/s
           Up = gas velocity, cm/s
           u  = drop particle relative velocity cm/s
            x = rectangular  coordinate, perpendicular
                to  the  direction of flow
            X = dimensionless distance
            y = rectangular  coordinate, perpendicular
                to  the  direction of flow
             z = rectangular  coordinate, in the direction
                of  flow
            p, = liquid  density, g/cm
             n = single  drop  collection efficiency, fraction

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         TABLE 2-2
Investigator
  CORRELATIONS FOR  PRESSURE  DROP

  IN VENTURI SCRUBBER


              Correlation
Matrozov (1953)    AP  =  AP,  +  1.38 x 10"3 uj'?
Yoshida et al.
          «.

 (1960) (1965)
                         Pr U,
AP =
                     a =
                         2  tan 0i
                 4  £.
                      -  «
                                  4 f
Geiseke  (1968)      AP  =
                          76
              Aiip  +  mT  AiiT
                 U     Li    Lj
                         Am
                              %  + UG2 - uLl - UL2)J
Yamauchi et al.
(1964)

Tohata et al.
(1964)


AP » 0,

Pr
AP =
*v 2

*
3 (AT)

UGt
gc
£
c
tan 0
~o.z

[•
p
6 G
2
'i
UGt
gc

(•

,«L\
Q /

- (Ml
wJ
f
+
i
d +
6 tan 02 J
^+
-F ^
t d..
                                             (continued)

-------
                    TABLE  2-2.  (Continued)
Investigator                      Correlation



                                         /Q \°'26
Volgin et al.       AP  =  3.32  x 10"6  u2  LM
 (1968)                               Gt  We/
Calvert  (1968)      AP  =  1.03 x 10~3
Gleason et  al.      AP  =  2.08  x 10"5  u *  (0.264 QT  + 73.8)
 (1971)                               bt          L.
Boll (1973)    _Ap   UG|  - u|      /<   /l^c

                - -    -           Jg   
-------
where   d  = throat diameter, cm
        d  - inlet, pr outlet duct diameter, cm
         f = friction factor, dimensionless
        £  = average friction factor of the throat
        f"  = average friction factor of convergent
         \*s
             section, dimensionless
        £\ = average friction factor of the divergent
             section, dimensionless
        g  = conversion factor
         L*
        H  = throat length, cm
         M = liquid-to-gas mass ratio
        mG = gas mass flow rate, g/s
        m, = liquid mass flow rate, g/s
         L
        Qr = gas volumetric flow rate, cm3/s
        QT = liquid volumetric flow rate,  cm3/s
         L
        Up = gas velocity, cm/s
       Up  = gas velocity at the throat, cm/s
        u^ = liquid drop velocity, cm/s
        u, = liquid velocity, cm/s
         t = time , s
         z = rectangular coordinate in the direction
             of flow, cm
        AP = pressure drop, cm W.C.
       AP, = dry pressure drop, cm W.C.
        AT = temperature change, °K
3
         PG =  gas density,  g/cm3
         Pm =  manometer  fluid  dnesity,  g/cm
         GI =  convergence angle, degree
         02 =  divergence angle, degree
          C =  coefficient on divergent  loss of gas
              flow, dimensionless
         5t =  head-loss  ratio  for  throat,  dimensionless
         £j =  head-loss  ratio  for  divergent section,
             dimensionless
                             10

-------
scrubber.  Correlations by Matrozov  (1953), Volgin et  al.
(1968), Gleason et al  (1971) and Hesketh  (1974) are experi-
mental correlations.   All others are theoretical equations.
lintrainment  Separator
      The  entrainment separator is an integral part of the
scrubber  system.  Generally, any device that can be used to
collect particles can  also be employed to knock out entrain-
ment.   However,  due to economical reasons, only a few  find
practical usage.  Calvert, et al.  (1975)  have evaluated
several suitable  entrainment separators experimentally.
Table 2-3 lists several common entrainment separators  and
their design equations.
CONCLUSIONS
     The  principal objectives of this study were achieved.
The following conclusions can be drawn.
      (1)  Collection by atomized liquid drops is  the prin-
cipal collection  phenomena in a venturi scrubber.  Even
though each  investigator presented a different equation
for the prediction of  particle collection in a venturi
scrubber, most of these equations can be reduced to the
same  basic model, i.e.,

                                3 u_  QT. n
                       ,    f
             In 04"  C A  l —  i	
             *" ill Jr L  \^ Cl  J    i ij~ 	r  ~ ~	\	~3— \* **          ^ *-  J- j
                     P    •£    G  <• G" r}  d

where  Pt(d  ) = penetration for particles with  diameter d  ,
                fraction
          u   = relative  velocity between dust  and  drop,
                cm/s
          Up - gas velocity,  cm/s
          d, = drop diameter, cm
           n = single  drop collection  efficiency,  fraction
          Q  , = liquid volumetric flow  rate, cm3/s
           Li
           z = length, cm
                             11

-------
                     TABLE  2-3.   ENTRAINMENT  SEPARATOR DESIGN  EQUATIONS
         Separator Type        Investigator
Design Equation
         Gravity  Settler
fv)
         Sieve  Plate
                                                         = 1 - exp (-40 F| Kp}
Mesh
Packed Bed
Tube Bank
Cyclone
Zig-zag Baffles
2 1
Bradie § Dickson E = 1 - exp (-T ~ a, &, n)
- (1969) 3 TT z Z
Jackson § Dalvert Pt = 1 - exp
(1966)
- V Z r
2.(j + j') Ce - Hd) 3~ p
Calvert § Lundgren E = 1 - (1 - n. )N
(1970) •"
Leith § Licht In Pt
C1971)
Calvert et al. n = 1 - exp
(1974)
1
»- _ /O>* it \~ • • " " i"
fpj /^u-i U . . \ i ?n +
= _ o d f d tg\ rnll)t
i yy.-,\ Q c. / 1
C0.393 dc)°-1If~
1 2.5.
u>tc nw8
57.3 ur b tan 8
L u
                                                                                   continued

-------
                    TABLE 2-3. (continued)

Where      a2 = specific area of mesh, cm2/cm3
            b = settler width or baffle spacing within row, cm
            d = cyclone diameter, cm
           d  = packing diameter, cm
           F^ = foam density
           H, = fractional liquid  hold-up in the bed
            j = ratio of channel width to packing diameter
           K  = inertial parameter, dimensionless
            & = settler length, cm
           A2 = thickness of  mesh pad, cm
            N = number of jet stages in the tube bank
              = (number of rows) - 1
            n = cyclone vortex or number of zig-zag rows
           Qg = volumetric gas flow rate, cm3/s
        Pt(d,) = penetration for drops with diameter d,,
                fraction
            T = gas temperature, °K
            t = residence time, s
           Up - gas velocity, cm/s
           u  = drop  terminal settling velocity, cm/s
           u,  = centrifugal gas velocity, cm/s
           t \-t
           u.  = tangential velocity of gas, cm/s
            w = width of baffle, cm
            6 = bed length, cm
           p, - drop  density, g/cm3
           u_ = gas viscosity, poise
            G
            0 = angle of inclination of the baffle to
                the flow path, degree
            ri = target efficiency of cylindrical wire,  fraction
           n. = collection efficiency for a given drop  dia-
            3   meter in one  stage of rectangular jet impinge-
                ment, fraction
            e = packed bed porosity

                            13

-------
          A generalized method for applying  equation  2-1 to
predict particle collection in a venturi was  developed.
     (3)  Particle collection predicted by equation 2-1
agrees'satisfactorily with performance data.
     (4)  Most of the particle collection occurs  in
the venturi throat.  The solution  to equation  2-1 for the
venturi throat, using the inertial collection efficiency
correlation proposed by Calvert (1970)  and assuming a zero
initial drop velocity is,
In Pt(dp)
   B
               0.7
                                1'5
                                   + 4
                                     '-
                                                  -u* \
                                                   ude)
                                                       8.5
 where
          - 5.02
           K
            po
                 po
           + 0.7 [
                         4 K   +4.2-5.02
                            po
      u j
u*  = _d£ = dimensionless drop velocity,
 de   U/-I...
                                                        (2-2)
                                                        (2-3)
            =  2
         1 -
                                                 1
                                                   0-5
                                                        (2-
  B = W/te
                        DO
                                                         (2-5)
        ^
        P  P
      po
      9 yr d
                         = inertial parameter based on
                           throat velocity, dimensionless
                                                          (2-6)
                            14

-------
            3 ,£t CD I PGV
        L = ——	 = dimensionless throat length  (2-7)
              2 dd PL "

and,    C'  =  Cunningham slip factor, dimensionless
       CDQ  =  initial drag coefficient, dimensionless
        d   =  particle diameter, cm
        &t  =  venturi throat length, cm
       u^e  =  liquid drop velocity, cm/s
       uGt  =  gas velocity at tne venturi throat, cm/s   *^~
        PQ  =  gas density, g/cm3
        PT  =  liquid density, g/cm3
        p   =  particle density, g/cm3
        y~  =  gas viscosity, poise

     Equation  2-2 slightly underestimates the particle collec-
tion occurring in a venturi scrubber.  For most industrial ven-
turi scrubbers, particle collection can be predicted closely
by neglecting the first term in the right hand side of equation
(2-2).
     (5)  Pressure drop predictions by the modified Calvert's
equation and by Boll's equation agree with experimentl data.
The modified Calvert's equation has the following form,
                                   fe)
AP = 1.03 x 10"3 u*  u  '1^1                 (2-8)
where   AP = pressure drop, cm W.C.
        Q  = gas flow rate, cm3/s

      (6)  The use of a drag coefficient from the "Standard Curve"
gives a better fit between model and experimental data  than does
Ingebo's correlation.
                                15

-------
                      CHAPTER 3
                  LITERATURE SEARCH v

     The literature survey and background information dis=
cussed in this chapter summarize what could be distilled from
a survey of the background information and represent
what was known at the onset of this study.
COLLECTION MECHANISM
     The basic approach to the study of collection of small
particles is through the evaluation of unit mechanisms that
can occur in the control device.    Tne  "Scrubber Hand-
book", Calvert, et al. (1972), discusses five basic unit
mechanisms, namely:
     (1)  Collection by drops
     (2)  Collection by cylinders
     (3)  Collection of particles by bubbles
     (4)  Deposition from a moving aerosol in pipes and ducts
     (5)  Collection of particles by liquid jets.  Of the
five, collection by drops is the predominant mechanism
occurring in the venturi scrubber.
     Particle collection by liquid drops may arise through
several mechanisms or phenomena, such as inertial collection,
interception, diffusion, electrostatic collection, and
gravitational collection.  All investigators have concluded
that inertial impaction is the principal mechanism of par-
ticle collection in a venturi scrubber for particles larger
than 0.5 ym in diameter.  For particles smaller than 0.1  urn
in diameter, diffusional collection prevails.
Inertial Impaction
     A drop moving through a gas will sweep out a cylindri-
cal volume equal to the product of drop cross sectional  area,
relative velocity between gas and drop and time.  However,
not all of the particles in this gas volume will necessarily
impinge upon and be collected by the drop.
                            16

-------
    As the gas stream approaches the drop, the fluid stream-
lines spread around it, while a particle suspended in the gas
stream tends to move in a straight line due to its inertia.
Therefore, as the gas flows around the drop, the particle keeps
moving toward the drop.  Due to the fluid drag some particles,
especially the smaller ones, will be deflected from their path
toward the drop and carried by the gas around the drop.
    The trajectory of the particle determines the target effi-
ciency of the drop.  Target efficiency is defined as the ratio
of the number of particles striking the drop to the number which
would strike it if the streamlines were not diverted by the drop.
If the particles bounce rather than stick on impaction, this
definition of efficiency is incorrect.  Thus an assumption is
always made that all the particles adhere on striking.
    Three factors determine the inertial impaction efficiency.
The first is the velocity distribution of the gas flowing by
the drop, which depends on  the drop Reynolds number.  The se-
cond factor, is the trajectory of the particle .  This depends
on the mass of the particle, its air resistance, the size of
the drop, and the flow rate of the gas stream.  The third fac-
tor is the adhesion of the particles to the drop.  Each of these
factors is discussed below.
    The drop Reynolds "Nne(i" number is defined as ,
                          u  pr dj
                           o  b  a                       ,  ->
where "u "  is  the undisturbed upstream air velocity, with
respect to  the drop;  "PG" amd "yG" are respectively the air
density and viscosity,  and  "d^"  is the drop diameter.  At high
values of "NR  d" (potential  flow) , the parting of  the gas stream-
lines occurs close  to the drop.  Except near the  drop  surface,
the flow pattern corresponds to  that of an ideal  gas.  When  the
Reynolds number  is  low,  flow is  governed by viscosity  (viscous
flow) and the  effect  of the disturbance created by the drop  is
                                17

-------
noticed at relatively large distances upstream.  The sudden
spreading of the streamlines at high Reynolds numbers enhances
the influence of particle inertia and therefore causes a higher
collection efficiency than at low "NRe(j."
    If all field forces are ignored and if it is assumed that
the particles obey Stokes' law, then the equations of particles
motion can be derived by equating the particle inertia force to
the air drag on the particle.  The equations in dimensionless
form are:
                 da
                                                          (3-2)
Kp dt " (v
where :
K - Pp
p sic
U
P u
G - V

d2 u
P o
! dC
VP
Vn =
P u_
                                                          (3-3)
     UG
UG = %
 t =
                    2  UQ  t
                                u.
                                                          (3-4)
                                                   (3-5);  (3-6)
                                                   (3-7);  (3-8)
                                                          (3-9)
    where   K  =  inertial  impaction parameter,  dimensionless
           p  =  particle  density,  g/cm3
           d  =  particle  diameter, cm
           u  =  undistrubed upstream gas  velocity with
                respect to the  drop, cm/s
           yG  =  gas  viscosity,  poise
           d,  -  drop diameter,  cm
                               18

-------
          C! = Cunningham correction factor
           t = time, sec
          u  = particle velocity  component in the X direction
          v  = particle velocity  component in the Y direction
          UG = gas velocity  component  in the X direction
          V-, = gas velocity  component  in the Y direction
    The dimensionless inertial parameter, K , which character-
ized the motion of the particle, has a physical meaning.  It is
the ratio of the particle "stopping distance" to the radius of
the collector.  The particle stopping distance is that distance
it would travel before coming to rest if injected into a still
gas with velocity "u ", when all forces on the particle except the
drag force are zero.
    The solutions to the equations of motion depend upon the
velocity field assumed.  Figure 3-1 shows theoretical and ex-
perimental target efficiencies for a single drop.  As revealed
by this figure, target efficiency depends on drop Reynolds num-
ber and inertial impaction parameter.
    Walton and Woolcock's (1960) experimental data agree quite
well with Langmuir and Blodgett's (1946) and Herne and Fonda's
(1960) theoretical calculations for potential flow0  That Walton
and Woolcock's drop Reynolds numbers often fell substantially
below the criterion for potential flow was apparently unimpor-
tant.  For potential flow and for values of "K " greater than
0.2, the experimental values of inertial collection efficiency
for spheres can be approximated by the correlation (Calvert,
1970):

                                                          C3-10)
   Diffusional  Collection
        Small particles,  in the  sub -micron size  range,  are
                                19

-------
  1.0
o
•H
•P
U
rt
!H
m
w
l.Ranz § Wong (1952) experimental data  -
  700
-------
rarely collected by inertial impaction or interception
because they follow the gas streamlines surrounding the
collecting body, and their ratio of d /d  is small.  In a
                                     P  ^
still gas, small particles move freely across gas stream-
lines due to random bombardment from gas molecules.  Some
of the particles hit the collector  and are removed from
the gas.
     If one estimates that the aerosol concentration near
the collector surface takes the form, Hidy and Brock (1970)
                               r
                          i _
                       c.
where "r " is the collector radius, "6" is the distance from
the collector center  and "c." is the concentration of par-
ticles in the main body of the gas stream, then the concen-
tration gradient at the collector surface is:

                        *„   - ^                    (3-12)
The rate  of deposition, 
-------
        T = temperature, °K
       C1 = Cunningham correction  factor, dimension! ess
       y_ = gas viscosity, poise
       d  = particle diameter, cm

     For an aerosol flowing past a spherical  collector,  the
 rate of diffusion increases and becomes a. function  of  the
 Reynolds and the Schmidt numbers.  The Schmidt number  "Nc  "
                                                         oC
 is a dimensionless group indicating the ratio of  convective
 and diffusive transfer rates  (at constant ND  ).   The Schmidt
                                           KG
 number is defined as
 For  low diffusivities , leading to high Schmidt numbers
 (Ng  - 106), and  low  Reynolds numbers  (NR  ,  < 3)  Levich
 (1962) showed that:

            * = 2 TT Dp rd c. N^ Nsci/3              (3.16)

 For  large Reynolds numbers  (600  - 2,600) and (Ngc ~ 106 ,
 Akselrud  (1953) showed that,

            * - 1.6 w Dp rd c. NRed- N^            (3.17)

 For  Reynolds number = 100 - 700  and Schmidt  number *  103,
 Garner et al. (1958a  and 1958b)  showed that,

            * = 1.9 TT Dp rd c. NRed^ NSc^            (3-18)

     Johnstone and Roberts  (1949) presented  an  expression for
estimation of single drop collection efficiency  due  to
Brownian diffusion.  Their expression is
                4 D  N'
            n = |ur-u,.d,                               (3-19)
                I G  d| d

                            22

-------
 where    n = single drop collection efficiency, dimensionless
         Dp = particle diffusivity, cmz/s
         d^ - drop diameter, cm
         UG = gas velocity, cm/s
         u^ = drop velocity, cm/s
       N'g,  = particle transfer number analogous to the Nusselt
              number for heat transfer or the Sherwood
              number to mass transfer, dimensionless

By using the semi -theoretical equation of Frossling for
"N '   "  i e>
   Sh '     »

             N'sh = 2 + 0.552 N°'N"3               (3-20)

equation 3-19 becomes
          n =
              I G  d
(2.0.552 NR-NSC-)        (3-21)
where  Nc  = Schmidt number defined by equation 3-15
        oC
      N_  , = drop Reynolds number

LIQUID DROP SIZE
     As mentioned earlier, the principal collection mechanism
occurring in a venturi scrubber is the collection of particles
by liquid drops. The collection efficiency of a drop depends
on its size.  Thus, in order to model the particle col-
lection by a venturi scrubber, we must have some knowledge
about the atomized liquid drop size.
     Hesketh et al. (1970), based on a study performed on a
small venturi scrubber, claimed two types of atomization
can occur.
Cloud-Type Atomization
     This type of atomization can be achieved when nozzles
larger than 1 mm I.D. are used and when gas velocity is
above the critical gas velocity.   The critical gas velocity is
                            23

-------
defined by the following equation
UG> critical  (cm/s)
                                             Q.5
                                   47,205
                                 d (mm
                                               466-3    (3"22)
     This type of atomization yields small drops and gives
lower drop acceleration which results in better particle
collection than drop type atomization.
Drop-Type Atomization
     Several correlations are available for estimating the
average liquid drop size in drop type atomization.  These cor-
relations are based on different mechanisms of atomization under
various operating conditions.  Each is applicable to a certain
range of operation conditions and physical properties of fluids,
such as viscosity, density, and surface tension.  They are sum-
marised in Table 3-1.
                           ^
     Most of the data taken in pneumatic atomization are
for liquid injection, either parallel or opposite to the
gas flow and with a small apparatus.  Venturi scrubbers
are quite large in comparison and normally have the liquid
injection across the gas flow.  While it is questionable
that these correlations would apply to a venturi scrubber,
they have been so applied.
     The most widely quoted correlation is that of Nukiyama
and Tanasawa, which gives the Sauter mean diameter, even
though almost all investigators doubted its applicability
to a full-size venturi scrubber.  Boll (1973), after com-
paring the results of Nukiyama and Tanasawa with those of
several subsequent investigators, stated that Nukiyama
and Tanasawa correlation is subject to an uncertainty
factor of two.
     In a later study, Boll et al. (1974) measured the
atomized drop size in a full-scale venturi scrubber by means
of a transmissometer.  They showed that the N-T equation
gives  values of mean drop size that are accurate within
about  50% for L/G's and throat velocities of commercial
                            24

-------
              TABLE 3-1.  EMPIRICAL  EQUATIONS FOR AVERAGE LIQUID DROP SIZE
ts)
en
AND THEIR APPLICABLE RANGES
Investigators
Nukiyama § Tanas aw a
(1938,1939,1940)
Mugele (1960)
Gretzinger §
Marshall (1961)
Kim § Marshall
(1971)
Equations
°- i° \" i PL fVM"
, _ O.OD / O \ , oppl 1 I 1
d UG K) ' V" o^ / K^
dd ,, ,B/W, u \C
-3 — = A/N 11 1 fA PL r Trr rnn^-tTnt'-l
d V Re / \ 	 rt 	 / v.'^>D>(-' «i<^ v-UJio 1.0.11 1.0 _/
r -, O.lt
1 mT 1
dm = 0.26 Ji NDor
m mr ReG
L b J
11 °-32
rt o-ti y T
d - 0 51°
"m " (UG pG)0'57 A°-36pL°'16
/mG \n
/ ^L\oa7 \mT/
+ 1 °nl I \ i* r
T -L . oy i - — - • i 	 —
\pLa / u's*
n = -1 for nu
"£ <3
n = -0.5 for mr/mT >3
b L
Applicable ranges
un,(cm/s)
101* -sonic
velocity
101* -sonic
velocity
101* -sonic
velocity
7.5 x 10 3-
sonic
velocity
mG/mL
1.8 -15
1.8 -15
I -15
~_
0.06-40
yL(poiseJ
0.1-0.46
I
0.01-0.3
0.01-0.5
where d, = Sauter mean drop diameter, cm PL = liquid density, g/cm3
d = mean drop diameter, cm yT = liquid viscosity, poise
m ij
d^ = nozzle diameter, cm mi " mass flow rate of liquid, g/s
n Jj
UG = relative -velocity, cm/s mG = mass flow rate of gas, g/s
a = surface tension, dyne/cm A = flow area of atomizing air
Q = volumetric flow rate, cm3/s ur = relative velocity between gas and liquid,

-------
interest.  For the particular venturi geometry they used,
the N-T equation consistently over estimates mean drop dia-
meter at high -gas velocities and under estimates it at
low-gas velocities.  They presented the following empirical
equation to correlate their drop data.

      A    6.75 x 106 * 5.28 x 1012 (QL/QG ), ™*2         ,-
      d, = -            {3
       d                  1.602
where     d, = Sauter mean drop diameter, ym
       QL/QG = liquid-to-gas ratio, m3/m3
          u. = gas velocity at liquid injection point, cm/sec
DRAG COEFFICIENT
     The inertial impaction parameter, "K " is also a func-
tion of the relative velocity between particle and drop.  The
atomized liquid drops will be accelerated by the gas.  The
effect of acceleration on the drag coefficient has been studied
by Hughes et al. (1952), Ingebo (1955), Torobin et al. (1960),
Crowe  (1961), and others.  Hughes et al. state that as a
general rule, acceleration drag exists and that it is higher
than the drag for steady motion.  Ingebo' s results disagree
with this statement.  He obtained acceleration drag coefficients
lower  than those predicted by the standard curve,  (see Figure
3-2).  According to Ingebo, the drag coefficients  "CD" for
drops  can be correlated fairly well with the Reynolds number
according to the following empirical expression:
                       CD '
                             Red
Where    CD - drag coefficient
       NRed = drop R®vnolds number

This expression is applicable for a Reynolds number  range  of
6 to 800  and spheres with a diameter range of  20  to  120
                            26

-------
I    io2
o
•H
o

u   10



BJ


O
 C5

O
    0.1
   0.01

     0.
               Stokes  Law
             0.1
                                            Ingebo  (1956)
                            10
1CP10*10*107
                                N^e-Reynolds Number



                    Figure 3-2. DRAG  COEFFICIENT OF A SPHERE .
                                     27

-------
microns.  Calvert (1968) used the Ingebo data and simplified
the above equation to
               CD = T"  £°r  10°  <  NRed <  50°          (3-25)
                D   NRed

However, this expression is applicable for a Reynolds num-
ber range between 100 and 500.  While this range is more
narrow than the range of the original correlation, it is
the range that is of interest for venturi scrubbers. Calvert
stated that this correlation is also a fairly good approxima-
tion for the Reynolds number up to 1,000.
     The Ingebo correlation and the Standard curve have
been used in the modeling of venturi scrubber by different
investigators.  However, Boll (1973) concluded that in the
case of a venturi, the Standard curve of the drag coeffi-
cient is the better choise.  He argued that Ingebo injected
the particles or drops as a small concentrated stream into
the center of a much larger duct.  Thus, the high central
concentration of slowly moving drops or particles would
have much the same effect as a stationary prorous body in
the duct.  Consequently, some of the gas must have flowed
around the mass of drops rather than between them, reducing
the actual gas velocity in the vicinity of the individual
     *
drops.  This would have lowered the actual drop accelera-
tion and reduced the apparent drag coefficient, accounting
for the low C~ values .
     Dickinson and Marshall (1968) approximated the Standard
curve by the following correlation
                                                       C3-26)
                            28

-------
SCRUBBER  COLLECTION  EFFICIENCY
     Calvert (1968 , 1970), by performing a material balance
for dust over a differential scrubber volume with the assump-
tion of constant liquid holdupi, obtained a differential
equation for the prediction of venturi scrubber performance.
This equation is

                  dc . 3  Kl"d " dz                  ,, „,
                  C       2 ddUG                     (    }

where   c = dust concentration, g/cm3
       u  = ut)~ud relative velocity between particle and
            liquid drop,  cm/s
        r| = single drop collection efficiency, fraction
       d, = drop diameter, cm
       Up = gas velocity, cm/s
        z = distance, cm
       H, = drop holdup or volume fraction of drops at
            any point
            udA
       Q  = liquid flow rate, cm3/sec
        L
       ud = drop velocity,  cm/sec
        A = cross-section area,  cm2
     By substituting  the defining equation of "H^" and "u "
into equation  3-27, one obtains
                dc .                  .
Another  assumption  in  the  derivation  of  this  equation  is
that particle velocity is  the  same  as  gas  velocity.
     Calvert -(1970)  and Calvert  et  al.  (1970)  applied
equation 3-28 to  the venturi throat .and  obtained  the
                            29

-------
following simplified equation for predicting particle
penetration
Pt(d )- exp
2 \ uGtpl cld p
  55 CL y"     M^pt'
                                                      (3-29)
where Pt(d )= penetration of particles with diameter d t
              fraction
         QT = liquid flow rate, cm3/s
          i-j
         QG = gas flow j-ate, cm3/s
            = average liquid drop diameter given by
           ,
              the empirical correlation of Nukiyama
              and Tanas awa, cm
        u   = velocity of the gas in the throat, cm/s
         bt
         Vip   gas viscosity, poise
         p. = liquid density, g/cm3
           L
        K   = inertial parameter evaluated at the velocity
              of the gas in the throat.
"F(K   f)" is a parameter defined by the following equation
    PL ,
                      i   r  , ..  /K   f + 0.7 \
                   "^  [       l^TTT - )
                                              (3-30)
                          •     - -       /

                  0.49
                                          f + 0.
"f" is an empirical parameter.  For hydrophobic  aerosols   a
value of 0.25 is suggested by Calvert .for this parameter.
For hydrophilic particle materials  it, is usually  equal to
0.5.
     Boll (1973) took into account the particle  collection,
occurring in the venturi throat as well  as  in the  divergent
and convergent section of the venturi, and  presented the
following integral equation for the calculation  of particle
penetration
                            30

-------
                                                       C3-31}
where  NC  =  number  o£ collection units
           =  -  In Pt(dp)
        M  =  ratio of liquid-mass flow rate  to gas-mass-
             flow rate
        PG  =  gas  density,  g/cm3
        p,  =  liquid density, g/cm3
        n  =  target  efficiency,  fraction
        t  =  time, s
        d,  =  liquid drop diameter given by Nukiyama
             and Tanasawa correlation, cm
        UG  =  gas  velocity, cm/s
        u,  =  liquid drop velocity, cm/s
" |ur-Uj|" is the relative velocity between gas and drops.
 This velocity depends on the geometry of the venturi scrub-
 ber.  Boll assumed that the gas is incompressible.  Thus,
 the gas velocity at any location in the scrubber is given  by

                              mG
                       UG " A~7                      (3-32)
                               U
 where nu = gas mass  flow rate,  g/s
        A = cross-sectional  area  of the scrubber, cm2
 The drop velocity  is equal  to the time integral of drop
 acceleration
                          0
                         pr  (up  - u.
/r, \J f, I Up   1*1 I
T 57 LV^i CD dt             ('-")
 where  u,. =  initial velocity  of  the drop,  cm/s
         di
         Cn =  drag  coefficient
                             31

-------
Boll used the Standard curve for CD for solid spheres due to
Lapple and Shepherd  (1940).
     Boll's equation, i.e., equation 3-51 can be reduced
to  Cal vert's differential equation.  Thus, these two
equations are essentially the same.
     Behie and Beeckmans  (1973) also gave a differential
equation for aerosol capture in the venturi scrubber.  Their
equation is
                                                      (3-34)
where  c  = dust concentration , g/cm3
       F  = v-drop mass flux, g/cm2-s
       PL = liquid density, g/cm3
       n  = target efficiency* fraction
       u... = gas velocity ,  cm/s
        b
       u, = drop velocity , cm/s
       d, = drop diameter , cm
       z  = the distance from the origin in the direction
            of gas flow ,  cm
     This equation is equivalent to Cal vert's differential
equation for particle collection in a venturi scrubber.
     Calvert, Boll and Behie  and Beeckmans all assumed that
the particle velocity is the  same as gas velocity.  How-
ever, Dropp and Akbrut  (1972), after evaluation of venturi
performance data taken from several power plants, concluded
that the model will  over-predict the efficiency of a venturi
scrubber for big particles if gas velocity is substituted
for particle velocity.  This  is because while the fine par-
ticles move at practically the same velocity as the gas, the
velocity of large particles differs markedly from the gas
velocity.   Big particles move at a lower velocity than the  gas
which results in a lower  impaction parameter and lower ef-
ficiency.   Dropp and Akbrut proposed the following equation
to predict venturi scrubber performance.
                            32

-------
Pt(d ) = exp
'.3A,  i
 T /  CCT cT7  u
  *r   11  tl
               P'         "J  *G "d  ud
                          o
dz
                                                      (3-35)
where  Pt(d ) » penetration for particles with
                diameter d , fraction
           QL = liquid-flow rate, cm3/s
           QQ = gas-flow rate, cm3/s
           u  = particle velocity, cm/s
           u^ = drop velocity, cm/s
     This equation has the same form as Galvert's differ-
ential equation except particle velocity is used in Dropp
and Akbrut's equation.
     Calvert derived his equation by considering particle
collection by all liquid drops existing in a unit volume.
Ekman and Johnstone (1951) employed another approach to
arrive at an equation for the calculation of particle
collection in a venturi scrubber.  They looked upon a
single liquid drop as a unit and followed the drop to
determine its particle collection for its entire flying
path length.  Total particle collection of the venturi
scrubber is then the sum of the collection of all liquid
drops.  Ekman and Johnstone's equation is,

               Pt(dJ = :exp  - ,nnnnnn                (3-36)
                   P'
                    490,000
where  Pt(d ) = penetration for particles with diametet
                d  , fraction
            n = single drop impaction efficiency, fraction
            P = length of effective path of liquid drop, cm
            s = specific surface of drops formed in
                scrubber, cm2/cm3
     Morishima et  al. (1972) used the same approach as Ekman
and Johnstone and  considered the particle collection in the
                            33

-------
venturi throat and in the divergent section.   They arrived
at the following equation

             Pt(d) = exp  I- (R.  + R,)  ^1             (3-37)
                          I (Rt
"R " and "R," are, respectively, the washing factor of gas
in the venturi throat and in the divergent section.  Wash-
ing factor is defined as the volume of gas swept clean by
a liquid drop per unit volume of liquid drop.  For venturi
throat and divergent section, the defining equations for
these two washing factors are,

                       ur   /    u,\
                            1 -      dx
                      max
where  I. = venturi throat length, cm
         C
        X = dimensionless distance
            x_
          " *t
       d, = drop diameter from Nukiyama and Tanas aw a
            correlation, cm
        n = target efficiency


       0  =     t  ' cm
        0   2 tan §L
                  2
       d  = venturi throat diameter
        0 = divergence angle

     All investigators cited earlier had assumed that the
liquid drop distribution is uniform across the duct  and
there is no turbulent mixing between drops and particles.
In reality, the drop concentration across the venturi
                            34

-------
throat is far from uniform (Taheri and Raines (1969),
Boll (1973)).  Taheri and Sheih (1975) took turbulent mix-
ing and liquid drop distribution across the duct into
account and obtained the following equations for predict-
ing the transport and diffusion of the particles and water
drops.
     —•— = - u  ——
     at      G az
                        a2c
       'd= - u
        ^+f5F]-Vldd CuG-ud)  ccd
                                      (3-40)
3c,
     at      "d  az    "d  l"ay^
where   c - particle concentration, g/cm3
       Cj = number concentration of liquid drop, #/cm3
       u,, = gas velocity, cm/s.
       u, = drop velocity, cm/s
       E  = eddy diffusivity of particle, cmz/s
       E, = eddy diffusivity of drop, cm2/s
        x = rectangular coordinate, perpendicular to
            direction of the flow, cm
        y = rectangular coordiante, perpendicular to
            the flow, cm
        z = rectangular coordiante, in the direction
            of flow, cm
       Q, = source strength of drops, #/cm3
In all the above mentioned performance models, the liquid
drops were assumed to have one size, namely the Sauter mean
diameter calculated from Nukiyama  and Tanasawa's empirical
correlation.  In reality, the liquid drop size varies widely.
Morishima et  al.  (1967)-performed  a mathematical analysis
to determine  the influence of liquid drop size distribution
on the particle impaction and diffusion  collection effi-
ciency.  They found that as the range of size distribution
                            35

-------
widens, the impaction efficiency decreases.
PRESSURE DROP
     Pressure drops for gas flowing through a venturi scrub-
ber consists of the friction loss along the wall of the
scrubber and the acceleration of liquid drops.  Friction
loss depends largely upon the geometry of the scrubber.
Acceleration losses, which are frequently predominant in
the venturi scrubber pressure drop, are fairly insensitive
to scrubber geometry and in most cases can be predicted
theoretically.
     There are several correlations available, both theo-
retical and experimental correlations, for the prediction
of pressure drop in a venturi scrubber.  They are summa-
rized in Table 3-2.
     Correlations by Matrozov, Yamanchi et al., Volgin et al.,
Gleason et al., and Hesketh are experimental correlations.
Matrozov1s correlation and Volgin1s correlation were
obtained mainly on small-size venturi scrubbers.  Yama-
uchi's correlation was based on experimental data taken
from a venturi scrubber with high temperature gas flow
(100°C - 900°C).  Hesketh's correlation is an experimental
correlation he obtained after he had evaluated  data
obtained from many fixed throat venturi scrubbers.
     Equations proposed by Yoshida et al., Calvert, Tohata
et al., Boll and  Behie and Beeckmans are theoretical
correlations.  Calvert derived his equation by use of
Newton's law to obtain the force required to change the
momentum of liquid at a given rate.  Wall friction and
momentum recovery by the gas in the divergent section
were neglected in the derivation.  All other theoretical
equations were derived from the equations of motion and
momentum balance.  Geiseke's equation also accounts for
the mass transfer between liquid and gas.  Boll's equa-
tion is similar to that of Geiseke's except Boll had
                            36

-------
         TABLE  3-2.  CORRELATIONS FOR PRESSURE DROP

                     IN VENTURI SCRUBBER
Investigator
              Correlation
Matrozov .(1953)    AP = AP, + 1.38 x 10"3 ui'°8 / QT
                          Cl                V3t  I  Li
                                0.6 3
                            CM
                            \5c/
Yoshida et al.

 (I960) (1965)
AP =
                    n —>
PG UGt
 2 g.
                                    4 £
                                 S
              4 £
                                                       d
Geiseke  (1968)     AP =
          [
      mr Aur + mT  AyT
       b   b    L  ' 1
                        Am,
                             (uGl + UG2  - UL, - UL2)]
Yamauchi et al,
 (1964)
AP = 0.3 (AT)"0-28
Tohata et al.
 (1964)
AP =
PG UGt
   Sc

    £
         [• •
                       92]
                                             + £
                                         (continued)
                            37

-------
                 TABLE 3-2. (continued")


Investigator                     Correlation
Volgin et al.       AP =  3.32  x  10
 (1968)
                                        /Q x°-26
                                    u2  ( ^    (
                                        V^/
Calvert  (1968)     AP = 1.03 x 10
Gleason et al.     AP - 2.08 x 10"5 u2 (0.264 QT  +  73.8)
  (1971)                              bt         L
 Boll  (1973)      _   u 2 -  2
                           u^  r
                                §c^o   G^^
                                           1         u dx
                               eq           6Cx*0  "eq
                                                      2
Behie § Beeck-        /   6F   \fl   r      ,      . 2 T     1  -
 mans (1973)    dp =  - (^djl^/p   CD  PG  ^G'11^  "T" J  dt
Hesketh         AP = 1.36 x 10 "* u~i pr A"-133
 (1974)                           Gt  G  t
                      r          /QT\              /QT\2i
                       0.56 * 935U^  + 1.29 x  10"5 Ji
                      L          \Q^/              \Qn/ J
where   At = throat cross-sectional area,  cm2
        AQ = duct cross-sectional area, cm2
        d^ = liquid drop diameter, cm

       d   = equivalent duct diameter,  cm

                                             (continued)

                            38

-------
where   dt = throat diameter, cm
        dQ = inlet of outlet duct diameter, cm
         f = friction factor, dimensionless
        ft = average friction factor of  the throat,
             dimensionless
         c = average friction factor of  convergent section
        f^ - average friction factor of  the divergent
             section, dimensionless
        g  = conversion  factor
        &t = throat length, cm
         M = liquid-to-gas mass ratio
        nig = gas mass flow rate, g/s
        m. = liquid mass  flow rate, g/s
        Q,, = gas volumetric flow rate, cm3/s
        QL = liquid volumetric flow rate,  cm3/s
        UG = gas velocity, cm/s
       uGt = ^as velocity at tne throat, cm/s
        u, - liquid drop  velocity, cm/s
        u, = liquid velocity, cm/s
         Li
         t - time, s
         6 = rectangular  coordinate in the direction
             of  flow, cm
        AP = pressure drop, cm W.C.
       AP, = dry pressure drop, cm W.C.
        AT = temperature  change, °K
        pr = gas density, g/cm3
         b
        p  = manometer  fluid dnesity, g/cm
        GI = convergence  angle, degree
        92 = divergence  angle, degree
         5 = coefficient  on divergent loss of gas
             flow, dimensionless
        E,  = head-loss  ratio for throat, dimensionless
        £, = head=loss  ratio for divergent section,
         a
             dimensionless
                             39

-------
neglected the mass transfer between phases.  Equations by
Tohata et al,, Yoshida et al., and Boll contain terms
attributed to wall friction.  While Tohata et al. and
Yoshida et al. had used different values for the friction
factors in the covergent throat and divergent section,
Boll suggested a single value for all sections.  A value
of 0.027 was suggested by Boll for the friction factor "f"
because it gives a slightly better fit in the shape of the
pressure drop curves he obtained experimentally.
                            40

-------
                      CHAPTER 4
      COMPARISON OF MODEL WITH EXPERIMENTAL DATA

     There are numerous venturi scrubber performance data
reported in literature.  However, most of these data were
found to be of a limited value for the testing of perfor-
mance models.  This is because some important information,
such as scrubber geometry, water injection method, particle
size distribution, etc. was generally not given.  In the
following sections, only those data which have been ob-
tained under contolled conditions and for a well-defined
scrubber system will be utilized to test the performance
models.
COMPARISON OF PREDICTED PRESSURE DROP WITH EXPERIMENTAL
DATA
Data by Wen and Uchida
     Wen and Uchida (1972) obtained pressure drop data on
a pilot scale O.A.P. venturi scrubber.  Their pressure drop
data are shown in Table 4-1.  Figure 4-1 shows the dimensions
of the scrubber.
     Figures 4-2 through 4-4 compare pressure drop predic-
tions by various models with Wen and Uchida's data.  For
the O.A.P. scrubber, the water injection nozzle is at the
start of the convergent section.  According to Wen and
Uchida, the gas cools down quickly to scrubber outlet
temperature once it is in contact with water  (within 5 cm
from the water injection point).  Thus, in  calculating
the predicted pressure drop, the volumetric gas flow rate
was adjusted for this temperature drop plus the volume
increase due to vaporized water.
     As can be seen from Figures 4-2 to 4-4, Calvert's equation
consistently over estimates the pressure drop.  Predictions
by Volgin et al. and Hesketh ar6 always lower than data.
                            41

-------
TABLH4-1.  WEN AND UCHIDA'S EXPERIMENTAL PRESSURE DROP
           DATA ON O.A.P.  VENTURI SCRUBBER
Run
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
IS
16
17
18
19
Gas Temp. °c
Inlet
154.4
160
160
157.2
148.9
154.4
135
154.4
160
148.9
148.9
148.9
148.9
121.1
148.9
148.9
148.9
121.1
148.9
Outlet
46.1
43.3
46.1
43.3
37.8
43.3
43.3
43.3
46.1
46.1
46.1
37.8
43.3
43.3
46.1
46.1
37.8
35
40.6
Inlet gas
Flow rate
Am3 /rain
29.4
30.8
29
34.8
34.2
28.5
28.6
30.3
29.8
25.5 '
25.5
31.2
25.5
25.5
25.5
25.5
31.2
25.5
25.5
Liquid
Flow rate
I fc/min
37.9
37.9
37.9
37.9
37.9
56.8
37.9
37.9
56.8
37.9
37.9
37.9
56.8
37.9
37.9
56.8
37.9
37 . 9
37.9
r Pressure
Drop
cm W.C.
22.2
21.8
19.8
30.5
29
22.9
21.6
21.3
24.1
21.8
19.8
29
22.9
21.6
21.3
23.4
31.5
25.9
21.8
                       42

-------
04
                                                     28.9cm
28.9 cm
                                     Figure 4-1.  Dimensions of OAP venturi scrubber.

-------
                                       iiJLi'ir;4:.fJ-l:

                    [iff  0 Calvert's Prediction ^
                    r. j j-   ,                        -,.,
                           Hesketh's Prediction
 0        10         20        30         40         50
             EXPERIMENTAL PRESSURE DROP,  cm 1ft.C.

Figure 4-2. Comparison of predicted pressure drop with
            experimental data from Wen and Uchida.
                             44

-------
       u
       •s
       E
       u
o
Q
       o;
       s
       co
       CO
       Q
       W
       O
           36
   32
          28
          20
          16
 Boll's  equation
  ^iiiil^J,!::^,:.!.!; [jjlLiU.
;i Volgin's equation ;
U-r- ----t—---J—I ' i ' i I : : ', i , i ' - I--	Ll-l-li
.:,	, j, . ., i i; r, ' .  rr,,,
             16       20       24      28        32      36
                EXPERIMENTAL PRESSURE DROP, cm W.C.
Figure  4-3.   Comparison  of predicted pressure  drop with
              experimental data from Wen and Uchida.
                           45

-------
      36
       12
         12
16      20      24     28      32

EXPERIMENTAL PRESSURE DROP, cm W.C.
36
Figure 4-4.   Comparison between Behie and Beeckmans'  prediction
             and experimental data from Wen and Uchida.
                           46

-------
Predictions by Boll and by Behie and Beeckmans are slightly
better, but still have .a tendency to under estimate
pressure drop.
     The only difference between models by Boll and by
Behie and Beeckmans is that Behie and Beeckmans neglected
wall-friction loss.  In a venturi scrubber, most of the
pressure drop is due to acceleration of liquid drops.
Table 4-2 proves this statement.  Table 4-2 lists Wen and
Uchida'a data along with predictions by Boll's equation
and by Behie and Beeckman's equation.  Behie and Beeckmans'
equation always predicts a lower pressure drop than Boll's
equation.  The difference between the predictions by these
two equations is equal to the wall friction.  The last
column in Table 4-2 shows the values of wall friction for
all runs.  For this particular  scrubber geometry, the con-
tribution of wall friction is less than ten per cent of
the total loss.
     Calvert's equation is based on the assumptions that
all liquid drops accelerate to  the gas velocity in the
throat and that none of the drop momentum is converted to
pressure in the diffuser.  It is possible that in some
scrubbers, liquid drops do not  have sufficient residence
time to accelerate to  the gas velocity in the throat.  In
order to take this fact into account, a correction factor
was developed and added to Calvert's equation.  The new
equation now reads

             AP = 1.0 x 10"3 u*e UG* /QL\              (4-1)
where  AP = pressure,  cm W.C.
      Up. = gas velocity in  the  throat,  cm/s
       Q. = liquid  flow rate,  cm3/s
        L
       Q  = gas flow rate, cm3/s
                            47

-------
TABLE 4-2.  WEN AND UCHIDA'S EXPERIMENTAL DATA
            AND PREDICTIONS BY BOLL AND BY
            BEHIE AND BEECKMANS
Run
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
Experimental
AP, cm W.C.
22.2
21.8
19.8
30.5
29
22.9
' 21.6
21.3
24.1
21.8
19.8
29
22.9
21.6
21.3
23.4
31.5
25.9
21.8
Prediction, cm W.C.
Boll
19.2
19.9
18.9
22.7
20.4
27.5
19.1
19.8
88.7
16.8
16.8
20.4
24.9
17.4
16.&
21.9
20.3
17.2
16.7
Behie § Beeckmans
17.4
18
17.1
20.4
18.1
25.3
17.4
17.9
26.4
15.3
15.3
18.4
23
15.9
15.3
20.4
18.3
15.7
15.2
Wall Friction
cm W.C.
1.8
1.9
1.8
2.3
2.3
2.2
1.7
1.9
2.3
1.5
1.5
2
1.9
1.5
1.5
1.5
2
1.5
1.5
                      48

-------
 where u*g  = correction factor, dimensionless
 and
*

_ Ude ?
UGt "
1 - X2 + (X
" •- ** VJ TV D *••
X = Do PG
                                                      (4-2)
        uGt = gas velocity in the throat, cm/s
        ude = drop velocity at the exit of the throat,
              cm/s
          Si = throat length or distance between liquid
              injection point and the exit of throat, cm
         d^ = drop diameter from Nukiyama and Tanasawa
              correlation, cm
         PG = gas density, g/cm3
         PL = liquid density, g/cm3
        CL  = drag coefficient at the liquid injection
              point
     "CD " is the drag coefficient obtained from Standard
durve for spheres.  Drop Reynolds number is defined as

where  ND   , - drop Reynolds number
        Re, d
         u,  = initial drop velocity, cm/s
           v = kinematic viscosity of gas, cm2/s
     The physical meaning of "u|e11 is the  fraction of gas
velocity to which the liquid drops have accelerated.   If
liquid drops are accelerated to  gas throat velocity, "u£
is equal to 1 and equation 4-1 reduces to Calvert's
equation.  Pressure drop prediction by equation  4-1 is
                            49

-------
lower than Wen and Uchida's data as shown in Figure 4-5.
     Wall friction and pressure recovery in the diffuser
were neglected in the correction factor to Calvert's equa-
tion, however, Boll's predictions are no better than the
modified Calvert's equation.
     Predictions based on the "standard" drag coefficient
are better than,those based on Ingebo's  correlation, as
shown in Figure 4-5.  Because Ingebo's drag,coefficients
are low, drop velocity and pressure drop predictions are
low.
Boll's Data
     Boll (1973) derived an equation to predict the pres-
sure drop in a venturi scrubber.  He obtained some pressure
drop data on a proto type venturi scrubber to confirm his
equation.  The cross-sectional dimensions of the venturi
scrubber throat was 35.6 cm x 30.5 cm (14 x 12 inches).
The throat length was 30.5 cm (12 in,).  The convergence
and divergence angles were 25° and 7°, respectively.
Figure 4-6 is a sketch of the venturi scrubber used by Boll.
     Figure 4-7 shows the comparison between Boll's data
and theories by various investigators.  The pressure drop
was expressed in terms of the number of throat velocity
heads, i.e. ,
     Number of velocity heads lost =	
                                     2*c  ^
     where   AP = pressure drop predicted by theory, cm W.C.
             gc = 980 cm/s2
             PG = gas density, g/cm3
             PL = water density, g/cm3
            uGt = gas velocity in the throat, cm/s
     As can be seen, Calvert's equation predicts  too high a
pressure drop for liquid-to-gas ratio above 0.7 &/m3.  Hes-
Keth's equation gives too low a pressure drop.  Volgin's
equation gives a different slope.

                            50

-------
     34
     30
  S
  o
  O
  OS
  o
  m  20
  CO
  CO
  w
  OS
  H
  u
  oS
  OH


     10
                 T,
                 Do
                 D
                     from  standard  curve
       from Ingebo's  correlation j i:•:
        10
Figure 4-5,
               20                  30       34

   EXPERIMENTAL PRESSURE DROP,  cm  W.C.


Comparison of predicted pressure drop by modified
Calvert's equation with data  from  Wen and Uchida.
                        51

-------
en
txj
                         Liquid
                         Inlet
                 Figure 4-6.  Prototype venturi scrubber used by Boll

-------
H
en
o
Q
<
w
u
o
_!
W
o
OS
3C
   2.0
   1.8
   1.6
   1.4
   1.2
   1.0
   0.8
   0.6
   0.4
               j|il!l!i!!iii ilillilliliJl
               ' Calvert's
               \' equation
                          nozzles   -H
; Modified  Calvert's !l!
i equation
                           ; uGt=9150  cm/s
                                                              Hesketh's i
                                                              equation  ]
                       Boll's equation
                                                ill Caverage)
                                                ":
                            Modified Calvert?s
                            equation

                            u. =4050  cm/s
              0..2      0.4     0.6      0.8      1.0     1.2      1.4

                           LIQUID TO GAS  RATIO, 1/m3 of gas
                                              1.6
        Figure 4-7.   Comparison of Boll's  pressure drop data  with theory.
                                       53

-------
     The range of gas velocity in throat covered by Boll
was 45.8 m/s  -  91.5  m/s  (150  -  300  ft/s).   The
line representing the predictions by Boll's equation
was an average curve for the predicted pressure drops.
Even though Boll's equation slightly under estimates pres-
sure drop at low values of liquid-to-gas ratio and slightly
over estimates at high liquid-to-gas ratio, the agreement
between his data and equation is considered to be satis-
factory.
     Predicted pressure drops by modified Calvert's equa-
tion for throat velocities of 40.5 m/s  and  91.5 m/s
are also shown in Figure 4-7.  Since Boll operated his
venturi scrubber in this throat velocity range, the area
bounded by these two theoretical lines represents the
range of expected pressure drops.  The fact that Boll's
theoretical curve, which is the average of predicted pres-
sure drops, lies within this area signifies that the modi-
fied Calvert's equation and the more complicated Boll's
equation predict pressure drop in equal accuracy.
Brink and Contant's Data
     Brink and Contant (1958) perform a thorough study on
an industrial-scale Pease-Anthony venturi scrubber.  The
scrubber had a rectangular cross section.  Its throat
measured 15.2 x 86.4 cm (6 x 34 inches) with a straight
section 30.5 cm (12 inches) long.  The angle of the con-
vergent section was 25°; the divergent section had an angle
of 2.2° for 152 cm (5 ft) following the vneturi throat and
then an angle of 15°.  Figure 4-8 is a sketch of the Pease-
Anthony venturi scrubber.
     Brink and Contant's pressure drop data are compared
with theories by various investigators in Figure 4-9.
Again, Calvert's equation consistently over predicts  the
pressure drop and Hesketh's equation consistently under
estimates the pressure drop.  Both Boll's equation and
                            54

-------
en
                                  Liquid  Inlet
                                         86.4  cm breadth

                                                     2.2°
                 Figure 4-8,
Dimension of Pease-Anthony venturi scrubber used by
Brink and Contant.

-------
 the  modified  Calvert's  equation compare favorably with
 experimental  observations.  As can be seen from Figure 4-9,
 Boll's  equation  is  in better  agreement with Brink and Con-
 tant's  data for  90  spray  jets and the modified Calvert's
 equation  is in better agreement with 45 spray jet data.
 Overall,   the modified  Calvert's equation predicts  slightly
 better  than Boll's  equation for this particular scrubber
 geometry.
 Ekman and Johns tone Data
      Ekman and Johnston (1951) ha^e measured pressure drop
 across  a  laboratory-scale venturi scrubber.  Figure 4-10
 shows the venturi  scrubber used by Ekman and Johnstone.
 The  venturi throat  was  3  cm  (1-3/16") in diameter and 3.8
 cm long.   The convergent  and  divergent angles were  25° and
 7°,  respectively.   Water  was  introduced in three ways:
from  a single 32  mm jet injected downstream along the axis
of the throat radially outward from a brass pipe 32  mm in
inside diameter with four 18.5 mm holes,  and radially
inward from a single 32 mm jet at the entrance of the throat.
Ekman and Johnstone recorded a higher pressure drop  for
radial inward injection.
      Figure 4-11  compares Ekman and Johnstone's experimental
data with theoretical predictions.   As can be seen,  only
Boll's equation and the modified Calvert's equation are in
agreement with data.
Conclusions
      Based on this evaluation, we can condlude that both
Boll's equation and the modified Calvert's equation are ade-
quate for the prediction of pressure drop in a venturi scrub-
ber.  Since the modified Calvert's equation is simpler, we
will  choose it as the venturi scrubber design equation.
However, the method for applying Boll's equation to predict
pressure drop will  also be given.
                            56

-------
   2.5
CO
o
   2.0
O
ctf
a:
UH
O
§  1.5

 «v
ac


a.
                            f 90 spray jet
                            ^ 45 spray jet
   1.0

      1.0.     1.2      1.4      1.6     1.8      2.0

          LIQUID TO GAS RATIO,  i/m3  of  gas



 Figure 4-9.  Comparison of Brink  and Contant experi-

              mental data with  theories.
                  57

-------
             Liquid
     Gas
00
                     Figure  4-10.   Dimensions  of the Ekman and Johnstone  venturi.

-------
   1.4
H

S  1
J
Q
<
W
x

>-
H
1.0
u
o

>  °

H
<<  .
O
05

^  0
PH
O
  6 --
o
2
E
<3


D-,
<
   0.4
0.2
                                               ;Data for radial
                                               [outward injection;;;
                                                Data for radial
                                                inward injection
              0.2     0.4    .0.6     0.8      1.0

                       LIQUID.TO  GAS RATIO,  £/m3
                                                   1.2
1.4    1.6
    Figure 4-11.   Comparison  of Eleman and Johnstone's pressure
                   drop  data with theories.
                               59

-------
PARTICLE COLLECTION
      Most authors (except Taheri and Sheih)  cited in the last
chapter use the same basic model for the prediction of particle
collection in a venturi scrubber, i.e.,
                            (uG-ur)A
                                           n dz         (4-4)
u  = relative velocity between dust and drop,  cm/s
where   c = dust concentration
          = relative velocity
       Up = gas or dust velocity, cm/s
        A = duct cross-sectional area, cm2
       TJ = drop radius, cm
          = single drop collection efficiency, fraction
       QL = liquid volumetric flow rate, cm3/s
        z = axial distance, cm

      Boll (1973) and Behie and Beeckmans (1973) had demonstrated
the success of this equation in predicting venturi scrubber perfor-
mance by comparing theoretical predictions with experimental
data.  Thus,  we will choose this equation as the particle col-
lection design equation for venturi scrubber.
      No general solution for this equation was found in the,
literature.  In order to calculate the particle collection ef-
ficiency, one must integrate this equation numerically, taking
into account the scrubber geometry.  It is inconvenient to use this
equation to predict venturi scrubber performance.
      A generalized method for predicting venturi scrubber
performance by equation (4-4) was developed in this study.
This method is similar to that used by Hollands and Goel (1975)
to obtain pressure drop in venturi scrubber.  Detailed deriva-
tion of the generalized method will be presented in the next
chapter.
                               60

-------
                       CHAPTER 5
                   PERFORMANCE MODEL
                                             i
In this chapter, we will present the generalized method for
predicting venturi scrubber performance by using both Boll's
p'ressure drop equation and Calvert's modified pressure drop
equation combined with Calvert's differential equation for
particle collection.  The method was developed by Hollands and
Goel (1975).  However, they only covered Boll's pressure drop
equation.  Their method was extended to Calvert's differential
equation for particle collection.
MATHEMATICAL MODELING
     The basic equations governing the particle collection
and pressure drop in a venturi scrubber were developed by
Calvert (1968, 1970) and Boll (1974); rewritten here after
some rearrangement they are:
c   UG   (uG-ur)
                              A
du,
a
dz
G
3
4
3 PG
PG
PL
CD
(V
dd
(VU
Ud)2
ud
d)2
c.
mL
                                                        (5-2)
    -                                   (VmG)
 dz " PGG  dz " 4 p  d     u      A "    m
B.C. at z=0, C=CQ; ud=udo ; UG=UGO; p=pd

where   A = duct cross-sectional area, cm2
        c = dust concentration, g/cm3
       CD = drag coefficient, dimensionless
       dj1 = drop diameter, cm
       d,  = hydraulic diameter of the duct, cm
        £, = friction factor, dimensionless
                            61

-------
       m
        G
     gas mass flow rate, g/s
       mr = liquid mass flow rate, g/s
        LI
        p = pressure
       Q  = liquid volumetric flow rate, cm3/s
        LI
       r _, = drop radius , cm
       u, = drop velocity, cm/s
       u~ = gas velocity, cm/s
        u
u
            relative velocity between gas and liquid drop,
            cm/s
            rectangular coordinate in the direction of flow
       PL = liquid density, g/cm3
       p,, = gas density, g/cm3
        n = single drop collection efficiency, dimensionless

     Several assumptions were made in the derivation of these
equations.  They are:
    (1)  The flow is one-dimensional, incompressible and
         isothermal.
    (2)  Liquid drops are uniformly spread across the duct
         and the drop diameter is invariant with axial
         distance.
    (3)  Drops are of uniform diameter.
     We will introduce several additional assumptions:
    (4)  There is no wall loss of liquid drops.
    (5)  At any cross section of the scrubber, liquid
         fraction is small.  Therefore, at any location, the
         gas velocity can be calculated by the following
         equation:
                            mr
                       ur = _£-                          (5-4)
                        (j   n A
                            PGA
where  m^ = gas mass flow rate, g/s
        A = duct cross-sectional area, cm2
       PG = gas density, g/cm3
                            62

-------
     Duct cross-sectional area depends on location .and can be
be determined from the following general formula:
                 A - AO ^ 1 + ^p-* 1                   (5.5)
                                                   *
                 j = 1 for rectangular duct
                 j = 2 for circular duct
where  AQ = cross-sectional area of the duct at the start of
            a section, cm2
        R = radius (for  circular duct) or half width  (for
            rectangular  duct) at the start of a given
            section, cm
        3 = half angle of divergence or convergence, degree
"3" is positive when duct is diverging and is negative when
duct is converging.
     Equation (5-5) assumes that for rectangular duct, duct
breadth remains unchanged; only duct width is converging or
diverging.
    (6)  The drag coefficient is governed by the following
         relationship as suggested by Hollands and Goel
         (1975) :
                   C-. =  (constant) N"°*5
                    jj               KB
where  Cn  = drag coefficient  applying  at  z=0, dimensionless
       Up  = gas velocity  at z=0,  cm/s
       u,  = drop velocity at  z = 0,  cm/s

"Cr> " is determined  from the "standard  curve"  using a Reynolds
  Do
number calculated on  the basis of  the relative velocity
applying at the beginning  of the duct,  i.e.,
                            63

-------
                       .                                 C5.7)
                  K6,O        v

where  NR    = drop Reynolds number at the beginning of
        XX t* 9 \J
               the duct, dimensionless
          d, = drop diameter, cm
           VQ= kinematic viscosity of gas, cm2/s

     The equation for the standard curve, due to Dickinson
and Marshall (1968), is:
CDo ' °'22 + ~-  l +0'15
              Re , o
                                       NRe,o)
                                            '
    (7)  Liquid drop diameter is that predicted by Nukiyama
         and Tanasawa correlation.
    (8)  Particles are flowing at the same velocity as gas,
         then Equation (5-1) can be reduced to:


           - ~ = 	u  I  d IT1) n dz                   (5'9)

    (9)  Particle collection is primarily due to inertial
         impaction.  We will use the simplified equation
         by Calvert (1970) to estimate the single drop
         target efficiency.


              n - PL-)'
                  \K  + 0.7/

                  C' p  d 2  |uG-ud|
where        K  = 	£—£	                      (5-11)
              P        9 UG dd
If one defines total pressure as:

             PT - p.+ %p  U2                            (5-12)
                            64  .

-------
Equation (5-3) can be written  as:
 dp
   T
  dz
    •z Pp/^n\ ur~uj I UP~UJ I/mT\   (M+l)  f  00U*
    -i  ^1^1  u  dIG  dl/L\   v    ^KGG
= --—1 — 1	 —	±      (5.13)
    4 pT  \d,/      Uj       \A/       2d,
where   M = m,/nu
             L  (j                              '
          = liquid to  gas mass  flow  rate  ratio

     The hydraulic diameter  "d^"  is  given for  a circular
duct by:
                dh = 2  (R +  z tan 6)                    (5-14)

and for a rectangular  duct by:
                d, o 2b  (R   + z tan  g)                  (5_15)
                 n   b  + R   + z tan  g

where   R = radius (for  circular  duct)  and half-width
            (for rectangular duct) at  the start of a
            given section, cm
        b = duct breadth for a  rectangular duct,  cm

     Equations  (5-2),  (5-9)  and  (5-13)  are the governing
equations for venturi  scrubber performance.  These equations
are now non-dimensionalized, using "Ug "  as  the characteristic
velocity scale, M^PGUG 2" as the  characteristic pressure scale,
     ~  d,  p, /  ur   \o.s
and  - —5- -2- j	——)  as  the  characteristic length  scale
     3 CDo PG  \uGo"udo/  f°r "the  equations below
(in the case of dh, RQ ,  and b,  duct  length  "A"  is  used as
characteristic length  scale),  i.e.,
                    u * =   -                          (5-16)
                     d    u~
                            Go
                            65

-------
                  * =
                                   U
                                    Go
                                           0.5
                             (5-17)
                 n* =
                 PT
                             (5-18)
By using these definitions, we  obtain
                 u
     u -u, =
                  Go
UGo ud
      G  d   /I + z tan p \j    UGQ
             ^       K.    '
           = u
              Go
, tan 3 2 ad
*T iii	• • .1—.- .• ^^—  i
    PL /  UGO   \
    pG\UGo-Udo/
                                               0.5
                       -jj

                     1
                                                     .-u
(5-19)
           Let S =
           Let 5
                   2 tan  6   dd    PL  /   UGo
                                               0.5
                     3R
CDo  PG
                             (5-19b)
"S" is the dimensionless parameter characterizing the slope of
a given duct and it has the  following characteristics
           S < o  for convergent  section
           S = o  for venturi  throat
           S > o  for divergent section.
By substituting equation (5-19b) into equation (5-19) , we have:
                     =  U
                         Go
                                         - u
                            66

-------
Fi-om equation (5-10) we have:
             K
      n  =
          K
C'
9
C1
9
PP
WG
PP
UG
d 2
P
dd
d 2
P
dd
u - u j
^ G d
Vud

+ 0.7
           (1
    (1  + Sz*)'3
                        - u
                           d
                                po
                                                          (5-20)
             C' p      "
 where  K
                        Go
         po      9 yr d,
         r          b  d

 By substituting equations (5-17), (5-19), and (5-20) into

 equation (5-9), we have:

                                               3
                               I
dc _   1.5R
c    d  tan
                           S
                                                    rjjdz*  (5-21)

 Let  B =
              PG CDo
                 (11    \°-5
                 UGo  \

               UGo-Udo/
                                     (5-22)
 then we obtain
         In Pt
           B
                              Sz*)"3-u*
u* f|(l + Sz*)'3-^!* 0.7>
                         dz*
                                                   (5-23)
                             67

-------
where  L  = dimensionless  duct  length
3

CDO
2d,
a
*
pd
P

G

UGo
-udo"
«
                                    0.5
       i,  = duct length, cm

Equation (5-23) is the general equation  to  predict  particle
collection by  inertial impaction  in  a venturi  scrubber.
By following the same procedures  as  the  derivation  of
equation (5-23), the following equations  are obtained for
drop velocity  and pressure drop:
       dz*
dz*
    =  (1
                    u
                                         -J -  Ud|]
                                                 0.5
                      2 u*
                         a
                                            .  u8
                                                 0.5
                              us
     + CM + i) f (i + Sz*)"
                     djL
B.C. at z*=0, u*=uJQ, p*=0

        d* = 2R* (1 + Sz*)  Circular  duct
        ,*   2 b* R*(l + Sz*) _   .  '       ,   .
        dr = 	^	J Rectangular  duct
         n   b* + R*(l + Sz*)

         f = friction factor, dimensionless
        b* = b/£ = dimensionless  duct breadth,
        R* = R/£ = dimensionless  radius
(5-24)
                                                        (5-25)
                                                 (5-26)
                           68

-------
     The first terra on the right hand side of equation (5-25)
represents the pressure change associated with the accelera-
tion of liquid drops; the second term, is the wall friction
loss.  From this equation, it seems that the contributions
of the liquid acceleration loss and the wall friction loss
to the total pressure loss are additive.  Therefore, one may
write:
                   *    *    *
                  PT = Pd + PW                         (5-27)-

where   p* = total pressure, dyne/cm2
        p^ = component of p* associated with liquid flow,
             dyne/cm2
        p* = wall friction component of p£, dyne/cm2
By this definition, we have:
                              ~j
                         Sz*)~- u
                                  *
                                                        o.s
dp£   ^	^	
dz*                         u*
                             a                         (5-28)
and
dpw = (M + 1) f (1 + Sz*)"2j
dz*            d* L
                n
                                                       (5-29)
with boundary conditions

          at z* = 0, pj = 0, p* =  0                    (5-30)

Equations (5-23), (5-24), (5-28),  and  (5-29) are the final
forms of the governing equations.
     For each section of the venturi scrubber,  its pressure
drop and particle penetration  can  be calculated from equations
(5-23), (5-24), (5-28), and  (5-29).  Since pressure drops
are additive, the overall pressure drop  for  the venturi
                             69

-------
sci'ubber is,
              AP,
                 CAP),
                                                      (5-31)
where   AP» = overall pressure drop, dyne/cm2
      (AP).  = pressure drop of a section of the venturi
              scrubber, dyne/cm2
     The venturi scrubber is a scrubber with a convergent
section, a throat section, and a divergent section connected
in series.  Particles that are collected in one section cannot
be collected in another section.  Therefore, if the particle
penetration for each section is known, the overall penetra-
tion for the venturi scrubber will be,
         Pt(dp) -  n  Pt(dp)I
                                               (5-32)
where   Pt(d ) = overall penetration for particles with
                 diameter "d ", fraction
      Pt(d )   = penetration of a section, fraction
          p J i
SOLUTION
     The analytical solution to equation (5-29) is,
   p*  =  (M-M)f
         ho
                                                      (5-33)
              1 - A
where  F  = .
        W   I4CA0.5
                   -2
                                for  circular duct
                                                (5-34)
F  = J- 11 + R*(Ar-l)(l+b*-*R*)'
 w   Ar2 [           	
                                      for rectangular
                                          duct
                            70

-------
and    Ar = the ratio of exit to inlet cross-sectional area
          = (1+SL)^
      d£Q = dimensionless hydraulic diameter at duct
            inlet, cm
        f = friction factor, dimensionless

     A value of f=0.027 was suggested by Boll because it
seemed to give a slightly better fit in the shape of the
pressure drop curves than other values of "f".
     Equations (5-23), (5-24), and (5-28) are solved by
numerical integration on a digital computer.  Figures 5-1
through 5-16 show the results of a numerical integration for
the range of L, S, and K   of interest and for udo=0.  These
figures along with equation (5-32) may also be used to deter-
                      *
mine penetration for u, ^0.  The method is discussed in the
following paragraphs.
     The drop velocity at the beginning of the divergent
section differs from zero.  We will use the divergent section
to illustrate the method of applying Figures 5-1 through 5-16
to determine the particle collection efficiency of a section
where at its inlet the liquid drop velocity is not zero.
     Refer to Figure 5-17 in order to find the penetration
of the divergent section ABCD, we project it in the upstream
direction with the same divergence angle "g", i.e., add an
imaginery section FEBA to the upstream of ABCD as depicted
in Figure 5-17 by the dashed lines.  The result is two ven-
turi divergent sections connected in series.  The outlet of
the imaginary added on section is the inlet of the real sec-
tion.  By equation (5-32) the particle penetration for the
real divergent section ABCD is equal to,

                      =   FECD                        (5-35)
                        p.                            l     J
                        FtFEBA
                            71

-------
3.0()
2.00
1.00 r
Oo75
0.50
0.25
                                                    -0.2I-0.1---0.05' -0.02--9.01
     ffjchange of
     '^scale
     o.oi
0.1
1.0
                                                                 10
                                                            100
     Figure 5-1. Chart for obtaining u5 for a circular  duct.

-------
3.00
2.00
1.00
0.75
0.50
0.25
    0.01               0.1                 1.0





                                 (L + LH) F



    Figure 5-2. Chart for obtaining u5 for a rectangular duct.
100

-------
     6.0
ft.
-o.os:: -o.o2p -o'.oi
                                                             0.5.1- -0.2:7-0.1'
            change

            of scale
                                                                         I. i^ii^ilP^i'llJ^iHiia'iiMJiMJitMiliirti im_ w*\ fniLJi' ii i o injit 'i  i »Mii« lliillw iiiMiii^B T 0 Of
                                                                         ; i i jjii jiiMijff'iP "ii ™i"i ii^^ Lrr^^5^^^*iT'''"»iiP2M^^ __ __.. p
                                                                                     10
                            100
        Figure 5-3.   Chart for obtaining p*|  for  a  circular  duct.

-------
en
     P.
                                                                                ]••• I-!-1 ft^
                                                                              - , - j -- - - -g -. ... i  - , -M. —L	\—(.

                                                                              , ^   rx i-\ ^i  y^ /% -1 ! T
                                                                           -o.osf -o.oz- --.  i
              change
              of scale
                                                                              iob^-R
          0.01
1.0
10
100
           Figure 5-4.   Chart for obtaining  pj| for a rectangular duct.

-------
              0.0
o\
                      Circular  duct:
                 0.01
0.1
                                                                                                 100
                 Figure 5-5. Chart for obtaining penetration for circular duct.

-------

    ^Circular  duct1-
 0.01
                                                                                 100
                                      LH)F
Figure 5-6. Chart  for  obtaining penetration  for  circular  duct.

-------
              .3
oo
        •P
        P-,
                   • . , I

                   Circular duct
                 •••••mil nmiMEi iiHHni minii inn nm MI in mnmniniiiiin iniiiin ininii inn mm m m
                 .01
.1
                                                                                   10
                                                                   100
                                                     (L + LR)F
               Figure 5-7. Chart for obtaining penetration for circular duct-

-------
•P
a,
rt
            rt-n
          Circular duct
      0.1
.1
10
100
                                             LH)F
      Figure  5-8. Chart for obtaining penetration for circular duct.

-------
              1.0
00
o
         4-J


         c
         iH
         s—s

         ft.
                                                                                                  100
                                                (L  +  LR)F
               Figure 5-9. Chart for obtaining penetration for circular duct.

-------
      O.Q
•p
P-,
     0.04
     0.03
     0.02
     0.01
        0. 01
      Figure 5-10. Chart for obtaining penetration for rectangular  duct.
100

-------
00
c-o
       •P
       CL,
       fi
             0.16
             0.12
                   Rectangular, duct
             0.08
             0.04
                                    o.i                 i.o                   10

                                               (L + LH)F

               Figure 5-ll.Chart  for obtaining penetration for rectangular duct.
100

-------
           0.3
00
           0.2
           0.1
                jIRectaneular duct
                              '
              0.01
                                                                                              100
                                            (L + LR)F

            Figure  5-12. Chart to obtain penetration for rectangular duct.

-------
        0.5
CO
            TtRectangular duct
              t-   •  ••••'*	™-,  «-n-
        0.2
        0.1
         0
          0.01
0.1
                (L
1.0
                                                    LR)F
100
         Figure 5-13. Chart  to  obtain penetration  for  rectangular duct.

-------
            1.0
00
                  Rectangular duct
             0
              0.01
                                                                                               100
             Figure 5-14. Chart  to obtain penetration  for  rectangular  duct.

-------
oo
                  Rectangular duct
            0.01
                                                                                             100
                  Figure 5-15.  Chart to obtain penetration for rectangular duct

-------
CO
-J
          2.4


          2.2



          2.0



          1.8



          1.6



          1.4
            Rectangular duct

            V - 10
            F = 1-SL
      m
   1.2



5  1.0
•M
OH
      PH
         0.8
         0.6



         0.4



         0.2


           0
             0.01
                           0.1
10
                                               1.0

                                           (L+LH)  F

             Figure 5-16.  Chart  to  obtain penetration for rectangular bed,
100

-------
                    Z = 0
Figure 5-17.   Concept of a hypothetical  section.
                  88

-------
     If we adjust the length of the imaginary section in
such a way so that the liquid drop velocity at the inlet of
the imaginary divergent section is zero, then "Ptcc~n" and
                                                 TELL)
"PtpEBA" can be obtained from Figure 5-3 through 5-16 and
penetration for the real section can be calculated from
equation 5-35.
     The length of the imaginary section "*•„", can be deter-
mined by integrating equation 5-2 with the following boundary
conditions:
              at  z = 0, ud = udo

                  z = _JIH, Ud = o

     Figures 5-18 and 5-19 are the results of the integra-
tion for a circular duct and a rectangular duct respectively.
"Lij" is the dimensionless counterpart of "&LJ" and is defined
by,
              LH  =
     In calculating  "PtFECD"  and  "PtFEM",  it  is necessary
to use the gas and liquid parameters  at  the inlet  of  the
imaginary added  on section,  i.e.,  at  z=-H^.  From  the geometry
of the duct, parameters  at  z=-&H  are  related to  the known
parameters at  z=0, i.e., at  the  inlet of the real  duct, by
the following  equations,

               L'  =  (L+LH)  (1-SLH)  j/2                (5-37)

               S'  = S (1-SLH)  "J/2  -1                  (5-38)

            u*'   = u*  (l-SLH)j                        (5-39)
                            89

-------
       100
CM O
 53-
                                      u
                                       do
        Figure  5-18.  Chart  for  obtaining LR for a circular duct. >

-------
100
 10  +n-
1.0
0,1
                                     •: o. o.o. o —-:"_


                                                        1.

                   50:  30 ' 20 !  15 -  i 10.0 .7.0^5.0!
            0.25
1.0
1.25
1.5
                               u
                                do
 Figure 5-19.  Chart for obtaining  L   for  a  rectangular duct.

-------
           and B'  =  B(1-SLH)"J/2                       (5-40)

 where prime (')  refers  to z=  -Si^.   Detailed derivation o£
 these equations  is  given in Appendix A.
SAMPLE CALCULATION
     To illustrate the application of these figures to predict
the performance of a venturi scrubber, we will calculate the
pressure drop and particulate collection for the venturi
scrubber shown in Figure 5-20.   We will predict its perfor-
mance for the following operating conditions:
     QG = 800 Am3/min
     Q.L/QG = 1.33 £/m3
     Gas temperature = 20°C
Particle Collection
  Convergent Section - Water is injected at the start of the
  throat.  Therefore, there is  no particle collection in the
  convergent section.
  Throat Section - The water is assumed to be  injected with
  no axial momentum so that "u, " is equal to  zero.  The
  gas velocity at the inlet of  the throat is calculated to
  be 8,060 cm/sec.  Thus,  the drop diameter according to
  Nukiyama and Tanasawa is:
A, = —
              1V
                 .
                 d              Q
                   =  0.0107  cm
           Drop  Reynolds  number
                     d,  /ur  -u,  \
             N      =   d  \~Go  do/
             Re,o        v

                   =  0-0107  C8060-0)
                          0.15
                            92

-------
VD
                                      LIQUID
                                      INLET
                                    Breadth = 81.3 cm
                Figure 5-20 .   Venturi scrubber for sample calculation.

-------
 From Standard curve, or from equation  (5-8):
               So ' °'22
                             Re , o
                   = 0.22 + —  [l +  (0.15)(575)°-6)
                            575  L                  J

                   - 0.545
                L    1
                     2  dd  \PL    "Go
                   = 2.79



                B  =
   /  u    \0>5
L_ |    Go  )

Do \UGo"Udo/
                    \QG/\PG/ CDo  \"Go "do


                   = 2.03

     For venturi throat, S=0.  Since u-, =0, we  have  L =0

and F=l.

             = "Go  pa =     (8060)  (1Q-8)
          po   9 UG dd   (9)  (1.8 x 10-"*)  (0.0107)
      or  dpa =  (0.215 Kpo)°'5  umA
Read  "-F  In  Pt/B"  from Figures 5-10 to 5-16 for L=2.79  and

S=0 for various  "K  ", we obtain the following:
                             94

-------
V
0.2
0.5
0.7
1
2
5
10
dpa' ^mA
0.21
0.33
0.39
0.46
0.66
1.04
1.5
-F In Pt/B
0.044
0.176
0.272
0.41
0.77
1.3
1.7
Pt(d )
v paj
0.91
0.7
0.58
0.44
0.21
0.071
0.032
  D i ve r gen t S e c t i on - At the exit of the venturi throat, the
  drop velocity is:
         u  F2 = 0.78 (Figure 5-2)
       i.e.,ud = (0.78)  (8060) = 6287 cm/s
            ujj = 0.78

At the start of the divergent section, gas and drop velocities
are the same as at the throat exit.  Therefore, at the begin-
ning of the divergent section:
            Go
               = 8060 cm/s
       and u,  = 6287 cm/s
            do
       Drop Reynolds number is

                 dd  (UGo""d)=  (0.0107)  (8060  - 6287)
         N
          Re,o
v
0.15
               = 126
From Standard curve or by equation  (5-8):
                          95

-------
      So
                           0.5
c _ 2 tan 3  d
    '"s:
                        PL /  UGo  \'

                        P  \u-u/
          =  0.177

                /-    _   ,.,   ,,   , 0.5

        L =  I I
            2    dd
            !G /uGo"udo\
            PT. \   uno   /
          = 12.5


 We need "L^" which can be  found  by  using Figure 5-19,
      L
      -
      U
Therefore, LR = 2.0  (0.78)2  =  1.2


       L + Lu = 13.7
            n

            F = 1 -  SLH =  1  -  0.177  (1.2)  = 0.788


Thus, (L+LH)F =10.8


          LHF = 0.95


   and  SF-°-5 = 0.2

                ur  d 2
          K   =  Go   Pa =  4.65 d 2
           PO   9 u, dd         P*


    or    dpa = (0.215 Kpo)°-5   ymA


               /QT\/PT\  ^   I   ur    ^
      -, L\(-k\ JL     GO
      "VV\PG; CDO iuGo-U(

      = 2.54


                    96

-------
Read "-F In Pt/B"  from Figures 5-10 to 5-14 at SI'-0*5 =0.2 and
(L+LH)F=10.8 and 0.95 for various K  , we obtain:
    n                              po'
KPO
0.2
0.5
0.7
1.0
2.0
5.0
10
dpa,ymA
0.21
0.33
0.39
0.46
0.66
1.04
1.5
(-F In Pt/B)
L+LH
0.037
0.148
0.233
0.35
0.68
1.25
1.75
Pt(d )
Pa L+LH
0.89
0.62
0.47
0.32
0.11
0.018
0.0035
(-F In Pt/B)T
LH
0.035
0.142
0.213
0.315
0.57
0.93
1.15
Pt(d J
pa LH
0.89
0.63
0.50
0.36
0.16
0.05
0.025
     The penetration for the whole venturi scrubber is calcu-
lated with the help of equation  (5-32), i.e.,
                              throat
                                       IT,
dpa,vimA
Pt
0.21
0.91
0.33
0.69
0.39
0.55
0.46
0.39
0.66
0.14
1.04
0.025
1.5
0.0045
     Figure 5-21 shows the result of this calculation.  For
this particular scrubber geometry and operating conditions,
the particle collection in the divergent section contributes
little to the overall scrubber collection efficiency as shown
in the figure.

Pressure Drop
     We will use both the modified Calvert's equation and Boll's
equation to predict the pressure drop of the sample venturi
scrubber.
                            97

-------
o
I—I
H
U
2
O
H
W
w
                                  VENTURI THROAT
  0.01
       0.1
             1.0


PARTICLE DIAMETER, ymA
       Figure 5-21.   Predicted grade efficiency curve.
                            98

-------
Modified Calvert's Equation  - Modified Calvert's equation is;
                  AP = 1.03 x  ID
                                 " 3
For the present example, ufi  =8060  cm/s
          and    ~   =  1.33  x  lO"3

                \Q/
Therefore,  drop  diameter  by  Nukiyama  and  Tanasawa:






                d, = ^ + 91.s(^i)

                 d   UG       V




                   = 0.0107 cm





   ;        Drop Reynolds number




                   . dd (UGo"Udo)

              Re,o        v

           t

                     0.0107  (8060-0)  =  5?5

                           0.15




 From Standard curve, or  from equation  (5-8):




               (:„_ = 0.545
                      5  £t So  PG  ,  .
          and    x =  ...  ; -  +  -1-
                      16 dd  PL
                    =  1.35
       u* =  21  - x2  4  (x1*  *  x2)0-5
        d     L


          =  0.80
                             99

-------
Therefore, pressure drop is:

       AP = (1.03xlO-3)(0.80)(8060)2(1.33xlO-3)

          = 71.5 cm W.C.

Boll's Equation - The procedure to calculate the pressure drop
using Boll's equation is to calculate wall friction loss  and
acceleration loss separately.  The sum of the two losses  is
the total pressure drop.
    Convergent section
 A. Wall friction
     p* = CM + 1)F F  ,  f = 0>027
     *w     d*      w '
        -     i
        - —s-  1
             ho
                  R*(Ar-l)(l+b*+R*)
          A* L       2fb*+R*)       J

                 exit cross-sectional area
      and   Ar =
                 inlet cross-sectional area
 At the convergent section inlet:

     u,,  = 2500 cm/s -.'
      bO
       M = 0
       £ = 62 cm
       b = 81.3 cm
       R = (0.5)(65.4) = 32.7 cm

     d   = 2b(R + & tan 3)                                fg ,,,
      ho   b + R + H tan 0                                l    )
           (2H81.3) 32.7 +  (62) tan  20°
             81.3 + 32.7 + (62) tan 20°
         = 65.8 cm
                            106

-------
By
the definition of dimensionless parameters, we have:
        b* = 1L1 = 1.31
              62
        R* =  f   = 0.527


        ho-~ = l-°6

        A  -  C81.3H20.5)
         r    (81.3)(65.4)
Therefore,
        F  =    1     l  +  0.527(0.31-1)(1+1.51+0.527)
         w    (0.31)2            2(1.31+0.527)

           =  7.48

        p* =     Ap      =  (0.027)(7.48)    Q  lg
         w    l    p  u_2         1.06
              •->• '    G  Go
     '.  A   =  (Q.19)(1.2xlQ-3)(2500)2
    ' '  Pw           (2)(980)

           =  0.73 cm W.C.


B. Acceleration  loss

There is no water in this  section,  therefore  acceleration
loss is zero, i.e.,

       Apd -  0


Total pressure drop  in  convergent  section:

        Ap =  Ap  + Ap,  = 0.73  cm W.C.
                            101
                               !

-------
(2)   Throat section
 A.   Wall loss

 At  the throat inlet:

      un  = 8060 cm/sec
       bO
        b = 81.3 cm
        R = (0.5)(20.3) = 10.2 cm
        3 = 0
      dho = 18.1 cm
and     M = —  — = •••••'•""•"— =1.1
            Or  p-   1.2xlO-3
             b   b
              •   = n
                   u*
       Ar = I

       Fw ' !
Therefore,

       p. = Ci.i * 1KO.Q27) = 0>Q956
        w-         0.593

and    AP = C0.0956).(1.2xlQ-3)(8060)2
                    (2) (980)

          = 3.8 cm W.C.


 B.  Acceleration loss

 From Nukiyama and Tanasawa correlation, we have:

       dd = 0.0107 cm

      udo = °

 Drop Reynolds number

    N     = dd(UGo"Udo) = (0.0107)(8060-0)  =
     Re>°        v               0.15
                            102

-------
From equation  (5-8) :



    CDo - 0.22 * J±  (l +  (0.15H575)0-6)


        = 0.545
      L -
               JDo /pG\/uGo"udo^
          2    dd \PL    UGo
        = 2.79


For venturi throat, 3=0, S=0,  F=l.

From Figure 5-4, we obtain:




      —{— = 1.6        for  (L + LH)F  =  2.79


                Apd
Since   p^ =	       ,  we have


             77" PG UGo
             1-6M PG UGo
           =  (1.6)(l.l)(1.2xlO"3)(8060)2

                        (2) (980)


           =  70 cm W.C.


Therefore, total pressure  drop  in  venturi  throat
        Ap = Apw + Ap^ = 2.79  +  70
             72.79 cm W.C.
                            103

-------
(3)  Divergent Section
 A.  Wall loss
 At  divergent section inlet:
    u
     Go
      b
      R
      6
      M
      I
8050 cm/s
81.3 cm/s
(0.5K20.3)
7.5°
1.1
171 cm
          2b (R + I tan B)
          b + R + £ tan 8
              = 10.2 cm
          (2)(81.5) [10.2 +  (171) tan  7.5°
             81.3 + 10.2 +  (171) tan  7.5°
    dho
= 46.7 cm

= dho = 46.7
   I    171
           = 0.273
     A_ =
(81.5)(65.4)
(81.3)(20.3)
                 3.22
          D   in?
     R* = £ = iiL_i = o.06
          a   m

     b* = b = ii^l = 0.475
          £   171
and  Fw =
          3.222
          0.115
       1 +
             0.06(5.22-1)(1+0.06+0.475)
                  2(0.475+0.06)
     ,* =
      W
  .1 + 1)(0.027) (0.115)
        0.273
                           104

-------
Since p  = — - -  ,  we have

               PG UGo
     Ap  = CO'025)(1.2xlQ-3)(8060)2
       w            (2) (980)
         = 0.99 cm W.C.
B. Acceleration loss
In the divergent section,  liquid  drop  diameter  is the same
as in the throat,  i.e., d,=0.0107  cm.  At  the divergent sec-
tion inlet, drop velocity  is  equal  to  the  velocity  at the
throat exit.  From Figure  5-2, we  obtain:

    u|F* = 0.78    for  (L+LH)F = 2.79   and   SF-05= 0
   •'' udo =  (°'78) C8060)
         =  6287  cm/s
     u   =  8060  cm/s
       Go
   Drop Reynolds number

         _ dd(UGo-Udo)
   NRe,o
                v
            (0.0107)(8060-6287)  =
                    0.15
Using equation  5-8, we  obtain C=0.93
           1 tan  g  dd  ^L /   UGo
           3    R    CDo  PG \UGO-U
         = 0.177
                            105
Do
   0.5

-------
        T  _ 3 „ CDo PG
        ]_, — -—
            «    dd PL \  UGo   /




          = 12.5




From Figure 5-19, we obtain:





      LH




      "f~





Therefore, LH =  2.0 (0.78)2  =  1.2




       L + LH =  13.7





            F =  1  - SLR = 1  -  0.177  (1.2)  = 0.788






Thus, (L+LR)F =10.8




          LHF =  0.95
           ri



   and  SF-°-5 =  (0.177) (0-788) "°"5 = 0.199





From Figure 5-4, we obtain
       2	     =1.0


        M
              H
           LH
         L+LH       (0.788)2
                                ..77
                            106

-------
               (0.788)
                 J+LH

               APd
Since  p* = 	  ,  we have
             1   p  u  2
            ?tr   G  GO
      Ap* =    (0.179)(1.2xlQ-3)(8060)2
        d            (2)(980)

          =  -  7.1  cm W.C.
                                             >.
Negative pressure  drop  is  equivalent  to pressure recovery by
the gas.  Total pressure drop  in  the  divergent section is
then equal to:

       Ap =  0.99 -  7.1  = -6.11  cm W.C.

     The pressure  drop  for the  whole  venturi scrubber is equal
to the sum of  convergent,  throat  and  divergent section loss.

       Ap (overall)  = 0.73 + 72.79  -  6.11
                     = 67.4 cm W.C.

     The difference  in  predictions  by the modified Calvert's
equation and by Boll's  equation is  4.1 cm W.C.  However, the
modified Calvert's  equation is  simpler to use as proven by
this calculation example.

PARTICLE COLLECTION  IN  THE VENTURI  THROAT
     For a venturi  scrubber, most of  the particle collection
action occurs  in the throat section where the relative velo-
             !
city between particles  and drops  is highest.  Thus,  it would
be desirable to obtain  an  expression  for particle collection
in a venturi throat.
                            107

-------
     For particle collection in a venturi  throat,  equation

(5-23) reduces to:
Equation (5-24) for liquid drop velocity become-s:




                    -TT- =  o                            <5-42)
                     dz*     2u*
                               d



We will solve these two equations  for  the  special  case

U*, =0, i.e., initial liquid drop velocity  is  zero.   By

rearranging equation (5-42), we have:


                      2u*

              dz* =     d
                    -. - • •; , E
                     h_u*\i.5   d




By substituting equation  (5-43) into  (5-41),  we  obtain:
         Pt
                    0


The closed form solutions to equations  (5-44)  and (5-42)  are:
 in
        E'
  ito/l-»J* "ilX

     \         o/
                                             0.5
                        po
- 5 02 K°'5 //l-u*\+   -       '1        po
  5'U^      1 Ud)  KpQ
                                  \ tan't1/'  "^
                                  jtan V    0.7
            KPO
            (*  I
           rr "" J I

            no/
                                       - 5-02
                      po-


                                                          C5-45)


                            108

-------
and   u* -  2  1  - x2  +  (xk  -  x2)
                              2, 0.5
(5-46)
                               CL
     K   _ dpa uGt                                        f    ^
     Kpo - 911717                                        C5-48)
              b   0.
                                                          f5-49)
                                                          *•    '
      &t = venturi  throat  length,  cm
     CDQ = drag  coefficient  for  drops  at  the venturi throat
           inlet, dimensionless

"CDo" is a function of  drop  Reynolds number and  is obtained
from "Standard Curve."
Drop Reynolds number  is  defined  as:
               dj ur.
       NRe,d - ~^                                    (5-5»5

     For an infinite length venturi throat, u| approaches unity
and equation (5-45) reduces  to:
 Pt(d )- exp - B
     Equations  (5-45) and  (5-51) were used  to predict  the
particle collection  for the venturi  scrubber mentioned in
the last section.  Figure  (5-22) shows  the  calculation results
along with the  grade efficiency  curve obtained  in  the  last
section.  As can be  seen,  there  is little difference between
the three curves.  For this particular  scrubber geometry » we
can assume that the venturi throat is of infinite  length and
its particle collection is that  predicted by equation  (5-51).
                            109

-------
   1.0
H
U
2
O
H
W
2:
w
  0.01
                             VENTURI THROATS
                                     VENTURI  THROAT
                                    iINFINITE  LENGTH
0.1 -rt^
      0.1
                            1.0


                  PARTICLE DIAMETER, ymA
10
     Figure 5-22.  Predicted grade efficiency curve.
                          110

-------
PARTICLE COLLECTION BY DIFFUSION
     In all previous developments, particle collection by
impaction is assumed to be the only collection phenomenon
occurring in a venturi scrubber.  This assumption is true
for particles with diameters larger than 0.5 micron.
Particles smaller than 0.1 jam in diameter are rarely
collected by inertial impaction because they follow the gas
streamlines surrounding the liquid drops.  For particles in
this size range, diffusional collection is usually the pre-
dominant collection phenomenon.  In the following sections,
we will derive an expression for the prediction of particle
collection by diffusion in a venturi scrubber.
     Again, we will use Cal vert's differential equation as
our starting equation.  His equation is:
                                                         C5-S2)
                  d  d
where  c = particle  concentration,  g/cm3
      UG = gas velocity,  cm/s
      u, = drop velocity,  cm/s
      Q  = liquid  flow  rate, cm3/s
       W
      Qf = gas flow  rate,  cm3/s
       n = single  drop  collection efficiency,  dimensionless
     According  to  Johnstone and Roberts  (1949), single drop
didjfusional collection efficiency is given by the following
equation:
              4  D
     n  =
          hrudldd
                     2  +  0.552
(5-53)
where  D   =  particle  diffusivity,  cm2/s
      ND   =  drop  Reynolds  number,  dimensionless
                                           2 /
       vn  =  kinematic viscosity of gas,  cm /s
        b
                             111

-------
     By using the same  dimensionless  parameters defined

earlier (equations  (5-16),  (5-17),  (5-20)  and (5-22)  we have:
                      u
 n =
                      dd UGo
                                                  3  - u*|
                                        -  u
                                                          (5-54)
and -
      dc
           4 B D

                   _2
           uGo dd ud
                             0.5
                      U
where  B = — — —
                        Go
           CDo\VpG\UGo-Udo
                   u
         = 0.552



           4 B D
                     Go
                          0.5
- u*°'5  dz*
   d
                            N   °-5  —
                            NRe,o U
                                  \ p
let   BD =
           uGo dd
(5-55)
                                                          (5-56)
(5-57)
                                                          (5-58)
we have:
        B  r
 _ dc = J> 2 + E  (l+Sz*)~J - u*
    c    u*[                   <
Upon integration, we obtain:
                                0.5
                                     dz*
                                   -  u
                                        °-5
                                            dz*
                                                          (5-59)
(5-60)
     Equation  (5-60)  is  the  final  equation describing the par-

ticle collection by diffusion  in a venturi scrubber.  Plots

similar to Figures 5-1 through 5-10 can be constructed.
                             112

-------
     For venturi throat (S=0) and for the special case that
initial drop velocity is zero (u^ =0), the analytical solu-
tion to equation (5-60) is:
                             113

-------
                      CHAPTER 6
  COMPARING MODEL PREDICTIONS WITH PERFORMANCE DATA

     There are numerous venturi scrubber performance data
scattered in literature.  However, most of these data
are of little use in model comparison because either
scrubber geometry information or particle informa-
tion, e.g.  size distribution and loading are not available
In the following sections, only those data with well de-
fined scrubber geometry and particle parameters will be
compared with  the mathematical model.
Data by Calvert, et al
     Calvert, et al (1975) measured the performance of
an American Air Filter Kinpactor 32 venturi scrubber.
The scrubber is used to control the emission from an
asphalt aggregates dryer.
     The scrubber operating conditions during the test
were as follows:
     1. Gas flow rates were as shown in the tabulation
below.

Gas Parameters
Temperature
Pressure during
pitot runs
Actual m3/min
ACFM
DS m3/min
DSCFM
Vol I H20 vapor

Inlet Duct
149°C
+73.5 cm W.C.
799
28,200
429
16,300
21
Outlet
Scrubber
Outlet Duct
57°C
+0.5 cm W.C.
-
;
-
13
Chimney
49°C
+0.02 cm W.C.
670
23,700
500
19,000
11.8
                         114

-------
     2. Water flow rate to the venturi scrubber was re-
        ported by the plant as approximately 1.06 m3/min
        (28,0 GPM) .  Water temperatures were 32°C (90°F)
        and 63°C (145°F) for the inlet and outlet streams,
        respectively.
     The performance predicted by equation 5-23 is compared
with experimental measurements in Figure 6-1.  The prediction
agrees with the average of the measurements.
     Predictions by Calvert's equation for venturi scrubbfer
are shown in Figure 6-2.  As can be seen, the experimental
results lie between predictions for f = 0.25 and 0.5.  A "f"
value of f = 0.4 will give better fit between Calvert's
model and data than other values of "f".
Brink and Contant's Data
     Brink and Contant  (1958) obtained performance data
on a Pease-Anthony venturi scrubber installed in a phos-
phoric acid plant.  The dimensions of the scrubber are
shown in Figure 4- 8.  Brink and Contant gave a grade effi-
ciency curve for the following scrubber operating conditions:
     1) Throat velocity of gas: 66.4 m/sec (218 ft/sec).
     2) Liquid flow rate: 757 £/min (200 GPM).
     Figure 6-3 shows the model predictions for (1) par-
ticle collection occurring in the venturi throat, (2)
combined particle collection in venturi throat and di-
vergent section, (3) particle collection occurring in the
venturi throat and the  throat is of infinite length.
     The particle diameters given by Brink and Contant
are actual size.  However, aerodynamic particle diameter
is used in the mathematical model.  Aerodynamic particle
diameter is related to  actual diameter by the following
expression:
                         115

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     l.Q
2
O
2:
O
PH
u
a,
      0.1
     0.01

                   Experimental data?
                   Predicted by
                !  throat model
                           iiiniiiiiniiifliitr
         0.1
        Figure 6-1
             1.0


  PARTICLE DIAMETER,  pmA
Experimental and predicted performance
of AAF Kinpactor 32  Venturi scrubber.
                           116

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    1,0
o
I—I
H
U
o
M
H
w
PM

w
nJ
U
I—I
H
rt
<
PU
    0.1
    0.01
                                        Calvert's model
                                        f » 0.25
           Calvert's model
           £ = 0.5
t. Experimental  Data
                        PARTICLE  DIAMETER,  ymA



          Figure 6-2.  Experimental and predicted performance
                       for AAF Kinpactor 32 Venturi scrubber.
                        117

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  1.0
E-
U
o
I—I
H
W
PH


W
H^
U
t—I

H
0(5
  0.1  j
 0.01
venturi throat
with infinite
throat length
                                    venturi throat
      0.1
                      1.0
                                                        10
                      PARTICLE DIAMETER,  ymA
      Figure 6-3.  Predicted and experimental penetration
                   for venturi scrubber used by  Brink
                   and Contant.
                       118

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where:
     d   = aerodynamic particle diameter, ymA
      d  = actual particle diameter, urn
      p  = particle density, g/cm3
      C' = Cunningham slip factor, dimensionless
     Aerodynamic diameter was transformed to actual dia-
meter based on equation 6-1.  A particle density of 2.6
(for MgP205) was assumed in the calculation.
     As can be seen, the experimental data have a higher
penetration than predicted.  This discrepancy probably is
caused by non-uniform liquid drop distribution as mentioned
by Boll (1973).  For this particular venturi scrubber, the
prediction based on infinite throat length assumption is
close to the prediction for the actual scrubber.
Data by Calvert et al
     Calvert et al (1974) measured the performance of a
Chemico venturi scrubber operating on the flue gas from
a coal fired utility boiler.  The scrubber might more
accurately be described as a variable annular orifice
type because its throat is formed by a movable "plumb
bob" concentrically mounted in a conical "dental bowl."
     The scrubber operating conditions during the test
period were as follows:
     1. Gas flow rates were as shown in  the  tabulation
below and on the following page:
     Duct                      Inlet            Outlet
Temperature               163.0°C(325°F)      54.0°C(130°F)
Pressure during pitot run  60.0 cm Hg         60.0 cm Hg
A m3/min                     13,400              12,700
ACFM                        4.75xl05              4.5xl05
DN m3/min                    6,300                7,150
                          119

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    Duct                      Inlet           Outlet
DSCFM                        2.4x105         2.7x10s
I H20 vapor (vol.)             6.01           15.0%

     The flow measured by the outlet velocity traverse
is judged to be more reliable because the velocity dis-
tribution was much more regular than at the inlet. Based
on 7,120 DNm3/min (2.7xl05DSCFM), the inlet flow rate
would be 15,300 Am3/min (5.4xl05ACFM), which is 8% higher
than the design flow rate of 14,200 Am3/min (5xl05ACFM).
     2. Slurry flow rate to the scrubber was reported by
the plant as approximately 24.6 m3/min (6,500 GPM) .
     Since the throat length and divergent angle for this
scrubber were unknown, we will assume that it is equiva-
lent to the venturi throat of infinite length.  The throat
velocity of the gas was calculated to be 42 m/sec and the
liquid to gas ratio was 1.75 £/m3.  Figure 6-4 shows the
model prediction along with experimental data.  The agree- ,
ment between the two is reasonably well.  Figure 6-5 com-
pares data with predictions by Calvert's equation  for
venturi scrubber.  A value of 0.5 for the empirical constant
will make the model agree with data.
Data by Calvert et al
     Calvert et al (1976) reported the performance test
conducted on an APS electrostatic scrubber.  When
the charge inside the scrubber is turned off, the electro-
static scrubber becomes a venturi scrubber.  The dimensions
of the scrubber are shown in Figure 6-6.  The measured per-
formance of the scrubber is shown in Figure 6-7 along with
predictions by equation 5-23 and by Calvert's equation for
f = 0.25 and f = 0.5.   The scrubber operating condition was:
     1. QL/QG =1.4 £/m3
     2. QG = 21 Am3/min
                         120

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o
I—I
H
u
o
I—I
H


H
W

W
PL,

W

U
PL,
 Experimental
1 data
  0.01
                               1.0

                    PARTICLE DIAMETER,
       Figure 6-4.  Predicted and measured penetration for
                    Chemico venturi scrubber.
                       121

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  1.0
H
U
o
I—I
H
w
PL,

W
J
u
 0.01
         Calvert's
       -!  equation, £=0.5
                                     Calvert's
                                     equation, £=0.4
                Experimental

                data
     0.1
                              1.0

                     PARTICLE DIAMETER, ymA
10
    Figure 6-5.  Predicted and experimental grade efficiency
                 curve for Chemico venturi  scrubber.
                       122

-------
                                                LIQUID INLET
                        t
                        "* 6
                        CM
                        1
                                            cm      cm
tsj
                         Figure 6-6   -  APS Electrostatic Scrubber

-------
  1.0
E-
U
O
w

gO.l

w
•J
U
ss
 o.oi
                                      p  Calvert's
                                        model,  £-0.25M
                                        if Predicted by
                                        r| equation 5-23
        I | Experimental a
        i Data
                       Calvert's
                      ; model,  £=0.5 :
                                            Model for  in-
                                            finite throat
                                            length
                                           Illtlliiiiiiiiiiiiiiimttiniiiiii
      o.i
                               1.0

                 PARTICLE DIAMETER,  ymA
                                                         10
      Figure 6-7.  Experimental  and predicted APS  venturi
                   scrubber  performance.
                     124

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     As can be seen, in small particle regions, neither
model agrees with experimental data.  The models predict
too high a penetration.  Between the two models, equation
5-23 gives a better prediction than Calvert's equation.
Data by Calvert et al
     Calvert et al (1974) obtained performance data on
an Environeering Venturi-rod scrubber (Model A33 Hydro-
Filter) .  This device consists primarily of several par-
allel rods which are positioned in a duct with some space
between the rods so that gas can flow between them.  Water
is introduced upstream from the rod bed and is atomized by
the gas stream as it flows between the rods.  Strictly
speaking, this scrubber is not  a venturi scrubber but is
one type of gas atomized spray scrubber.
     The scrubber was installed to control the emission
from an iron melting cupola.  The scrubber operating con-
ditions during the performance test runs were:
     1. QL/QG = 2.4 £/m3
     2. Gas velocity in the space betweed rods was cal-
        culated to be 196 m/s
     This scrubber operates like a rectangular free jet.
Since we do not know the expansion angle of the jet and
the total jet length, we will assume that the scrubber
operates like a venturi throat with throat length  equal
to five times and ten times the jet width.  Figure 6-8
shows the calculation results along with experimental
data..  The experimental data lie  in the area bounded by
the curves for throat length equal to five times and ten
times jet width.
CONCLUSIONS
     Based on these comparisons, the following  conclusions
can be drawn:
     1. If the venturi scrubber geometry is well defined,
then the model prediction agrees with experimental data.

                          125

-------
    1.0
o   0.1
U
O
I—I
H
H
W
2
w
W
U

b  o.oi
 0.001
                          \l-Prediction for throat :|ii
                           length equal to five  fi
                         :*JHr times rod spacing     r-
        ^Prediction  for
        [infinite  throat
         length
         ; •; T rr.r .r: i
        ^Prediction for throat
          length equal to ten
         • times rod spacing
      0.1
      0.5     1.0

PARTICLE DIAMETER, ymA
                                                  5.0
      Figure  6-8.   Predicted and experimental performance
                    for venturi rod scrubber.
                   126

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     2. liquation 5-23 gives better predictions than Cal-
vert's model.  Another advantage of equation 5-23 is that
it contains no empirical constants.  However, Calvert's
model  is simpler to use than equation  5-23.
     3. If the venturi scrubber throat length is long
enough  (dimensionless throat length, "L",  larger than 2),
then the scrubber performance can be approximated by the
particle collection occurring in a straight  tube of in-
finite  length.
                           127

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                       CHAPTER 7
                    DESIGN ANALYSIS

      In this chapter, we will discuss the factors that
 affect the performance of a venturi scrubber, design
 techniques, and the optimization of the venturi scrubber
 design.  Several factors have an influence on the per-
 formance and the design of a ventari scrubber.  Some
 of these factors are:
      1.  Throat length of the scrubber
      2.  Throat velocity and liquid-to-gas ratio
      3.  The size distribution of the particles to be
          collected.
Effect of Inlet Particle Size Distribution on Performance
     The overall (integrated) penetration, Ft", of any device
on a dust of any size distribution will be
= r;/*
W
     P
                          pt (ddw
where  FT      = overall penetration, fraction
       Pt /d \  = penetration of particles with diameter d
       W       = total weight of particle, g
        \n*
       dw      = particle weight corresponding to the interval
                 d Id j  of particle size, g
     The number and weight size distribution data for most
industrial particulate emissions follow the log normal law.
Hence, the two well established parameters of the log normal law
law adequately describe the size distributions of particulate
matter.   These parameters are the geometric mean weight dia-
meter, "d  ", and the geometric standard deviation,  "a " .
         pg                                           &
     The log-normal particle distribution density is:
                          128

-------
dw
d(ln dp)
f (dp) '
1
(2irh.n 
-------
     Based on the conclusion of the  last  chapter, the per-
formance of a venturi scrubber can be  approximated by the
particle collection occurring in a straight  tube of  infi-
nite length if the dimensionless throat  length  is larger
than 2.  Since most industrial venturi scrubbers have
dimensionless throat length between  2  and 3, we will use
the infinite throat length model to  represent the perfor-
mance of the venturi scrubber.  The  penetration for  the
venturi scrubber is then given by equation 5-46, i.e.,
                4K   + 4.2 -  5.02
Pt(dJ = exp "
;-o  (i * F) t«->S
                                vpo

                                                      (7-7)
where  Pt(d ) = penetration for particles  with diameter
                d ,  fraction
            B = flimensionless liquid-to-gas  ratio
                parameter
               •    ••  ^^ i
               «W  _
          K   = inertial parameter
              = d* p   C' ur.
                 P p	bt
                   9  ^G dd
           d  = particle diameter, cm
           d, = liquid drop diameter, cm
           C' = Cunningham slip factor,  dimensionless
          ufit = gas throat velocity,  cm/s
           p  = particle density,  g/cm3
           PL = liquid density, g/cm3
           PG = gas density,  g/cm3
           Ur = gas viscosity,  poise
                        130

-------
 The  diameter for which collection efficiency is 501  is


 designated cut diameter "d    ",  i.e.,
                           pa5o

               Pt = 0.5 when d  =  d
                              p    pas o


 In terms of cut diameter, equation 7-7  becomes
 ln(0.5)=-B
                     4-2 - 5-02
                               K
                                p5o
where "K   " is the inertial parameter for d
        Pso                  r
                                                       (7-8)
and is defined as
          K
                 uu. d 2
           pso
                                                       (7-9)
By rearranging equation 7-8, we obtain
 B = -
                    in  (0.5)  (Kpso  *  0.7)
4K    + 4.2 - 5.02 K _0
  pso               P°u
                                l  *    -)  tan

                                    pso/
(7-10)
 By substituting  equation  7-10  into  equation  7-8,  we  have



                      In  (0.5)  (K^n  +  0.7)

     Pt(d  )  •  exp
                                 -0.5
                                                        (7-11)
                           131

-------
From equation 7-4,
         d   = d   exp    (2)   xln a
          pa    Pg   r   '
                             0.5
                                    g
By using this expression,  we get for the inertial parameter,
        K
          po


             = b K


where  b = exp ( 2(2)°'sxln a  )
uGt dpa _ UGt
9 UG
^d
Pg exp
2(2)°'5xln a
5 UG
d

                                                        (7-12)
            K
            P8
     Since


      Pso _ [

     V" \
          let  Y = dpa50
                     Pg
                                                       (7-12a)
                                                        (7-13)
By substituting equations 7-12 and 7-13 into equation  7-11 and

after rearranging,  we get,
Pt(d )
        = exp
               0.693 (Y2 K   + 0.7)
                     Kpg + 0.7)
                        - 5.02
                                                   tan
         4 Y2 K n + 4.2 - 5.02 Y K0'5
               PS                 PS
                                      (l +
                                                        (7-14)
                          132

-------
By substituting equation  7-14  into equation  7-6, we have
Pt =
00
oo
4 b Kpg *

y2 -f
Cb KPg
4.2 - 5.02 (b K
v Pg
A 7 _ c; n? Y K"0-5
4.Z b.02 Y Kpg
K +0.7)
+ 0.7)
I0-5 (l + °'7 Uan-Jb V
\ Kpg/ ^ °'^
11 + °*7 It-in"1 J Pg
\ Y2Kna/ ^ 0.7

                                                             dx
                                                       (7-15)
     Equation  7-15  is  the  final  equation  relating  the
overall penetration "Pt" to  inlet  particle  size  distribu-
tion  (d   ,  a )  and  to  the  inertial parameter for the mean
particle  diameter "K  ''•
                     ir o                     -,., .
     Figures 7-1 through  7-3 are plots  of "Pt" versus
(d     /d   ) with "K " as  parameter for various  "0 " values.
These  plots are exact  solutions  of equation 7-15,  accounting
for log-normal particle size distribution as given by
equation  7-2.
     The  overall penetration can also be  determined by know-
ing the size distribution  and liquid-to-gas mass flow  rate
ratio.  By  substituting equation (7-12) into equation  (.7-7),
we obtain,
Pt(dp) = exp
   5.02
               -B
                     4  b
b K
                       pg
                             0.7
                         0.7
                                   (7-16)
                          133

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       1.0
       0.5
       0.2
  l£   o.i
   z
   o
      0.05
   H
   P4
   2

   £  0.02

   J
   1-1


   i  o.oi

   §
     0.005








     0.002





     0.001
          0.02    0.05  0.1   0.2
Figure 7-1.
Venturi scrubber  integrated penetration,

"Ft" versus "dp50/dpg", with "Kpg ' as



parameter,
                       "v2-5"
                   134

-------
o
I—I

H



H




a,
o
     0.002
     0.001	

         0.01 0.02
0.05  0.1   DTT


     dpso/ pg
        Figure  7-2.   Venturi scrubber integrated penetration, Pt

                     versus dp50/dpg» with Kpg as Parameter> ag=5'
                             135

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       1.0
2
O
2
W
W
>
O
     Q.Q5
     0.02
     0.01
     0.005
        0.005 0.01 0.02
Q.I  0.2
0.5   1.0   2.0
                           Pso
         Figure  7-3.  Venturi scrubber integrated penetration,
                     Pt versus d   /d  , with K    as parameter,
                                -t  /  r o        to

                     a =7.5.
                      g
                           136

-------
Equation 7-6 now becomes
Pt =
5.02 (bK
          •7  V    bJW  LCU1   ^-077:1                (7-17)
     Figures 7-4 through  7-7 are the solutions for equa-
tion 7-17.
Throat Length of the Scrubber
     For a venturi scrubber, most of the particle collec-
tion occurs in the venturi throat.  From the results of the
last chapter, for a well-designed scrubber there is only
a slight difference between the grade efficiency curves of the
venturi throat and the whole venturi.  Thus, in the follow-
ing design analysis, we will assume that particle collec-
tion only occurs in the venturi throat.  This approach will
give us a conservative design.
     For particle collection in a venturi scrubber, the
collection efficiency is  predicted by equations (7-45 to 7-47).
Figure 7-8 shows the graphical -form of this equation.
This figure applies both  to the circular duct and the rec-
tangular duct.
     Under a specific operating condition, the performance
of the venturi scrubber depends on the throat length as
revealed by Figure 7-8.   The longer the throat, the more
efficient the scrubber.   This dependence is more profound
for larger particles, i.e., larger K   .  Thus., in design-
ing a venturi scrubber, we should use a long throat.  How-
ever, we should not use a longer throat than necessary
because the pressure drop will increase with increasing
throat length.  The final choice of throat length should
be a compromise of the two.  A close inspection of Fig-
ure 7-8 reveals that a dimensionless throat length of
2 to 3 would be sufficient.  Further increase in the
                          137

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         1.0
         0.5
                                       100
       0.001
Figure 7-4.  "Pt" versus "B" with "K  " as parameter,
             "a  = 2.5".            pg
               138

-------
          1.0
          0.5
      O
      I—t
      E-
      W
      2
      W
      (X
      O
         0.05
                                         500
         0.01
                           B
Figure 7-5. "Pt" versus  "B"  with "K  " as parameter,
             rr  =
             °
                   139

-------
      1.0
o
h- 1
H
<
&
E-i
W
2
W
P-,
w

o
Oi
      0.1
     0.05
     0.01
                                     1000
                                     2000
                                     5000
                      B
 Figure  7-6.   "Ft" versus "B" with  "K   "  as parameter,
               • I    = 7 CTI             Pg
                ag   '-* •
                140

-------
                                  ;s|1000

                                    1500
                                    2000
    0.01
Figure 7-7.   Pa5°  versus  "B"  with "K  " as parameter,
                141

-------
          2.0
t .„
          1.0
  ...ji	i....
- change of
                                                                                               100
                        Figure 7-8.   Effect  of  throat length on penetration,

-------
dimensionless throat length will  increase pressure drop
with little gain in scrubber performance  (Figure 7-9).
     It is possible to predict the performance cut diam-
eter, "dpso" from Figure  7-8 if the scrubber operating
condition is known.  Figure 7-10  is a simplified plot of
Figure 7-8.  For an industrial-size venturi scrubber, "B"
is usually larger than 1.  As can be seen from Figure 7-10,
the performance "K   " is almost  constant for dimensionless
throat length, "L", larger than 2, and "K   " becomes a
...                                        ps o
function of "B" or liquid-to-gas mass flow-rate ratio.
For  a venturi scrubber with dimensionless throat
length between 2 and 3,  the correction factor "u, " in
                                                de
the  modified Calvert's pressure drop equation is approxi-
mately equal to 0.8.  therefore,  the expected pressure
drop is

     AE (cm W.C.) = 8.24  x lO'^fup (£HL_j|( ,-L\         (7-18)
                               L  b v sec/J  \QG/

Throat Velocity and Liquid-to-Gas Ratio
     The principal collection mechanism occurring in  a ven-
turi scrubber is the collection by drops.  It is a known
fact that  the target efficiency of a drop increases by
decreasing the diameter  and increasing the relative velo-
city between the gas and the drop.  However, smaller  drops
accelerate faster than do bigger  drops with the results that
the  relative velocity goes to  zero earlier in the case of
smaller drops.  Consequently,  there exists an optimum drop
diameter for particle collection.  Since  atomized liquid
drop diameter is a function of  gas velocity and liquid-to-
gas  flow ratio, therefore, there  exists  an optimum  combina-
tion of throat gas velocity and  liquid-to-gas ratio.
     Figure 7-11 shows the theoretical effect of  throat  gas
velocity and liquid-to-gas flow  rate ratio on the perfor-
mance cut  diameter of the venturi scrubber.   Properties
                          143

-------
rt  0.05
   0.01
                                                               100
500 1000
                                            K
                                             po
     Figure 7-9.  Effect of throat length on performance.

-------
42.
en
                 100
                 50
                 10
                 0.5
                 0.1
                   0.05
                   50    100
500 1000
                                        K
                                         PS o
                                                        U
G
                  Figure 7-10. Predicted Venturi scrubber performance  K  5o   vs.  B.

-------
of air and water at room temperature were used to con-
struct this figure.  For other liquid/gas combinations
and conditions, one should construct different plots.
     Optimum liquid drop diameter can easily be obtained
from Figure 7-11.  For instance, if the gas throat velocity
is known, then the optimum drop diameter will be that
which gives the smallest aerodynamic cut diameter.
     If the scrubber required performance cut diameter
is known, optimum throat velocity and gas-to-liquid ratio
can be determined from Figure 7-11.  Figure 7-12 shows the
relationship between "B" and "K so".  This curve was
calculated from equation (7-8) and is applicable to all
scrubber operating conditions.  From this graph, we can
calculate the anticipated cut diameter and pressure drop
for various throat velocity and liquid-to-gas ratio com
binations.  Figure 7-13 shows such a calculation for air-    '<
water system at 25°C.  Figure 7-14 is the cut diameter
pressure drop relationship with water flow rate as parameter
for this system.
 Design  Procedure
      The  information presented  in  this  chapter  allows one to
 design  a  venturi  scrubber  to  meet  a required "FT".   The
 general method does  not  use  Figures 7-13 and 7-14 since they
 represent the  specific case  of  an  air-water  system at 25°C.
 If the  conditions are  close  to  those for these  two figures
 then  the  procedure  is  simplified.
      The  general  procedure is as  follows:
      1) Determine required cut  diameters:  First find the
 aerodynamic  geometric  mass mean diameter of  the incoming
 dust  at the  temperature  expected  in the venturi.   Then,
 construct a  plot  of  1C    vs d^Qcn  (required)  by,
                      Pg      pd.3 0
        a) Obtaining several  K   - B pairs using Figures
 7-4 to 7-6  (depending on  a  ).
                          o
        b) Knowing  d  ,  obtain d   50  for each of the K
 B  pairs using  Figure 7-7.

                         146

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 5,000
 1,000
w
PL,

O
OS
a
;=>
ex
   100
    10
      0.1
              1.0


AERODYNAMIC CUT DIAMETER, ymA
                                                         10
 Figure  7-11.  Effect  of gas  velocity and liquid to gas flow

               rate  ratio on  performance cut diameter.
                      147

-------
      10
o-  ex
     1.0
     0.5  —
     0.1
         0.1
                       K
0.5  2 1.0
  = dp50 C> Pp uGt
10
                        p50
                                9 ^G dd
    Figure  7-12.   "B"  vs  "K ,  "  for venturi throat of infinite
                   length.
                            p50
                      148

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   2.0
H
W
ID
U
CJ
2:
>•<
o
o
  0.1
     0.2
     Figure  7-13
0.6
1.0
3.0
                                         6.0
       QL/QG' £/m3
Predicted venturi performance, "d
QL/QG with "UG" and "AP" as parameter.
                                                     pa so
         vs.
                           149

-------
                   5.0
C/l
o
               w
               H
               w
CJ


U
t— (

S
               Q
               O
               OS
                   1.0
                   0.5 fc
                  0.1
                                                        .-.:.-!- - ..: i-_-:i:_;-^=3;L:.T---ri-:.r--i~.-r3.---.;:L-J._l
                      1.0
                                  10                        100


                                  PRESSURE DROP,  cm W.C.
1,000
                  Figure 7-14.   Aerodynamic cut diameter versus pressure  drop with  liquid  to  gas

                                  ratio as  parameter.

-------
     2) Determine performance cut diameters: First determine vis-
cosities, densities, and Nukiyama-Tanasawa coefficients for the
venturi conditions.  Then construct a number of performance
curves corresponding to different QL/QG ratios as follows:
          a) Select a "ur "
                        bO
          b) Drop diameter, d^, from Nukiyama-Tanasawa relation
             (Table  3-2)
          c) NReQ from equation (5-7)(assuming udo=0)
          d) CDQ from equation  (5-8)
          e) Parameter B from equation  (5-22)  (assuming udo=0)
          f) K    from Figure  7-12
          g) dpa50 from equation  (7-9)
          h) K   from equation  (7-13)
          i) AP from equation  (7-18)
Repeat steps  (a)  through  (i)  for  several velocities.  Plot per-
formance K    vs d     curves  on the  same plot as the requirement
curve from Step (1) .   Plot  AP vs  d a_„ on a  separate graph.
                                  'pa s o
     3) Determine required  pressure  drops: The  intersections of
the requirement and performance curves determine the proper
design points.  The corresponding pressure drops required can then
be found from the plot of AP  vs d^oc  .  The  required pressure
                                  TJ £15 0
drops will correspond  to  a  certain QL/QG ratios so  that  the fan
costs versus  the  water and  pumping costs can be compared to allow
selection of  the  optimum  design.
     4) Determine throat  cross-sectional area:  Using  the selec-
ted optimum combination of  AP and QL/QG proceed as  follows,
          a)  From the  design  K    solve equation 7-12a  for UG^ as
a function of d,.
          b)  Substitute this  equation for dd into  the  Nukiyama-
Tanasawa relation and  solve for UG^.
          c)  Divide the volume flow  rate by  ufit to  get  the  throat
cross-sectional area.
                              151

-------
     5) Determine throat length:  Using the design velocity,
perform steps (2a-d) and then, solve equation (5-47) for &.
based on the desired L (2 to 3).
     6) Determine convergence, divergence angles: These have
little effect on particle collection but they do have some ef-
fects on pressure drop.  Of the two, divergence angle is more
important.  Divergence angle should be designed such that,
          a) Boundary layer separation does not occur
          b) Momentum recovery occurs in the divergent section
     The general procedure would be facilitated by use of a pro-
grammable calculator or a digital computer.  As a check, or if
the conditions are close to those of an air-water system at
25°C.  Figures (7-11) and (7-14) can be used in an almost purely
graphical procedure.
     The graphical procedure is as follows (air-water at 25°C),
     1) Determine required cut diameter:  Same as general pro-
cedure.
     2) Determine performance cut diameter:  Use Figure 7-11
and equation (7-12a) to calculate the performance d  50 vs
K   curves for various Qj/Qn ratios.
     3) Determine required pressure drops:  Same as general
procedure except use Figure 7-14 to find required pressure drop.
     Steps (4-8) same as general procedure.
                             152

-------
Venturi Design Example
     The problem of designing a venturi scrubber to control
dust from a typical asphalt plant dryer is illustrated.
     The dust has a log-normal distribution of diameters
described by a geometric standard deviation, a  =5.0 and
a geometric mass mean particle diameter, d   = 18 urn
                                          PS
(physical).  The particle density is 2.6 g/cm3.  The flue gas
flow rate is 567 Am3/min with a gas temperature of 116°C.
The uncontrolled emission rate is 2,310 kg/hr.
     Based on a local Air Pollution Control District rule
for the amount of weight processed, the emission should
not exceed 25 kg/hr. The required efficiency is then:
(2,310-25)/2,310 x 100 = 98.9%.  Thus, the design should
meet an efficiency requirement of 99%.
     Step 1. Specifying the required cut diameters:  First,
the aerodynamic geometric mean diameter must be found.
For air at 116°C the Cunningham slip correction factor
for 18 urn particles is C1 = 1.013.  Thus,

             d  a = 18  (1.013 x 2.6)°'5 = 29.2 umA

Next, a plot of the required cut diameters  (dpaS9) for an
overall penetration of 0.01 is made by using Figures 7-5
and 7-7.  The points which are shown in Figure 7-15 as cir-
cles are listed below:          j
                                 pas o
               B       K	      pmA
               4.3      17000      0.64
               2.8      1,500      0.58
               2.2      2,000      0.55
               1.6      5,000      0.41
               1.4     10,000      0.30
     Step  2.   Specifying  the  performance  cut  diameters:
First the  flow parameters must  be  found.   For air at 116°C
and water  at  25°C,
                         153

-------
 10,000
  5,000
bO
  1,000
    500
                !.J I- « : I I'  t !    I.  I  : .:!"{...
                I .j r/l-i i -!-J I i I I- r T-. ! i* i UUp-j
                             i j i f.i i • ;  LLkLL:
                   Requirement
                              Pt«0.01 -----
                            Performance
                            icurves
                               ;;T^ = o.ooir-
                                               0.002 — r--—-
        0.2
0.4
 0.6

paSO,
0.8
1.0
1.2
    Figure  7-15.   Impaction parameter  vs  aerodynamic cut
                   diameter for a venturi  design.

-------
     Gas Viscosity, u^ - 2.23 x ID"1* g/cm-sec
     Gas density, pfi = 0.907 kg/m3
     Gas kinematic viscosity, v~ = 0.246 cmVsec
     Liquid density, PL = 997 kg/m3
     so,
                     p
                     ~ " 1,099
and the Nukiyama and Tanasawa equation for drop size reduces
to,
                          50      .  M/QL\"
                      uGQ cmsec)

Other design equations to be used are,
            M
            W
             Reo     VG
            CDo = 0.22 + ^- (1 H- 0.15 NJJ0)       (5-8)
                          Keo

                 i   QT  PT
                 ~                  0 . 48
             pso ~   -       — —
                     0.5 * B $5
                     (Based on Figure 7-12)
             paso   I   10-8U
                                                     C7-9)
                           Go
     and
             AP  =  8.24  x 10'*  u*
 Solution  of these equations for various ^L and uGo can be
greatly  facilitated by use of a programmable calculator
                         155

-------
The solution   to  the design equations  are plotted  on  Figures
7-15 and  7-16  for QL/QG ratios  of  0.001, 0.0015, and  0.002.
                                        1
      Step 3.  Determine the required  pressure drops:
The intersections of the performance lines with the require-
ment line in Figure 7-15 determine  the cut diameters  (both
required  and performance).  These  cut  diabeters are repre-
sented on Fig. J-16 as triangles.   The required pressure
drops corresponding to these cut diameter^ are then,
"L
<£
0.001
0.0015
0.002
pas o
ymA'
0.42
0.57
0.675
AP
cm W.C.
67
40
32
Based on the flue-gas rate of 567 Am3/min these QT /Qr
                                                 L  o
ratios represent water requirements of 0.57 m3/min  (150
gal/min) 0.87 m3/min  (225 gal/min) and 1.13 m3/mdn  (300
gal/min) , respectively.  Based on pump and water costs
versus fan costs the designer can select the optimum
design.
       Step 4.  Determine throat cross-sectional area.  In
 order to carry out the calculation illustration we will
 assume that QL/QG = 0.002 and d   0 = 0.675 ymA is the
 optimum.  From Figure 7-15 the required K   =  980.
                                          tr O
                      ~~ 98°
             y yr a-,
                U  Q.

             9(980) (VG)(dd)   9(980) (2.23 x  10-")dd
       u
                                  (29.2 x  10'1*)
ut       A 2               f in i .-- i rt-
-------
  100
e
u
   50
   10
                                     A Design Points
      0.2
1.2
                           "paSO,
  Figure  7-16.   Pressure  drop  vs  aerodynamic  cut  diameter

                 for venturi  design  example.
                       157

-------
      From the Nukiyama-Tanasawa correlation for the pre-
sent example,


             Gt      * G      Gt

Substituting into the expression for "uGt" we have,

      ur+ = 2.3 x 10SU9-  + 7.78 x 10'
       G             kt
      UG  = 5,300 cm/sec

Throat cross-sectional area = 567 x 10— = 1,783 cm3
                              (60)(5300)
Step 5. Determine throat length:
            5300
                 + 7.78 x 10' = 0.0172 cm
          = UGt dd PG  = (5300)(Q.0172)(9.07 x
               yG
                                 2.23 x 10
      CDo = 0.62
Therefore, throat length = /i\/°-0172W	1	\  (L)
                           \3/\ 0.62 /\9.07 x 10-" /

                         = 20.3L cm

If design L = 2, then throat length = 40.6 cm

     Suppose the gas temperature was 25°C, then  the
previously constructed performance curves  (Figures  7-11
and 7-13) could be used.
                          158

-------
      Step  (1);
      At -25°C  C'  -  1.009 for d  = 18 vim so.  d    =18
                              p           '   pga
 (1.009 x  2.6)12  -  29.2 ymA.  Since this is  the same d
 as before,  the  K   -  d     requirement pairs are the
 same.
      Step  (2):
      Using Figure   7-11 and the equation for K  , Figure
 7-17 is generated.  The shaded triangles represent the
 design points where the performance and required K  's
                                            	.„ .    * &
 match.   Thus the results, using Figure  7-14 are
*!§•
1.03
1.1
1.55
1.85
2.8
pa so
ymA
0.30
0.41
0.55
0.58
0.64
AP
cm W.C.
140
74
44
40
44
These results are close to what we obtained using the gen-
eral procedure and a higher  temperature gas.
                            159

-------
 20,000
 10,000
  5,000
 bO
  2,000
  1,000
    500
                          A  Design  Points
                         Gas  Temperature  =  25  C L
                         dpga =  29.2  ymA        j
0.55
0.58

0.64
Figure 7-17.  Impaction parameter vs QT/Qr for
              venturi design example.
                   160

-------
                         CHAPTER 8
                 ENTRAINMENT SEPARATOR

      All scrubber systems include an entrainment separator,
either as an integral part of the scrubber configuration
or as a separate, clearly identifiable device.  There are
a number of devices which are commonly used as entrain-
ment separators.  Zigzag baffles, knitted mesh, packed beds,
cyclone separators, and guide vanes causing rotation of thei  j
                                                             I
gas stream are frequently used for this purpose.  Calvert
et al (1975) had performed a detailed study of entrainment
separators.  The following is an abstract of their study.
ENTRAINED LIQUID INFORMATION
      In order to design a proper entrainment separator, or
to predict the collection efficiency of an entrainment se-
parator, certain entrainment liquid information is needed.
This includes:
      1. Entrainment drop and size distribution.
      2. Quantity or inlet loading.
      An extremely important factor in choosing and design-
ing an entrainment separator is drop size distribution.
Different entrainment separators are limited to certain
drop diameters, below which their efficiency falls off
sharply.  The  size of the drops depends upon the way they
were formed.
      Entrainment rate and size distribution data for gas
atomized spray scrubbers such as Venturis have not been
reported.  Estimates can be made, as discussed below, but
they are very  rough because of uncertainties  in predicting
the characteristics of the initial atomization and the  drop
separation occurring within the venturi diffuser and similar
flow elements.
                           161

-------
      Drop diameter can be predicted by means of the cor-
relation by Nukiyama and Tanasawa (1938-40).   For air
and water at standard conditions the N+T correlation for
Sauter mean diameter is:
      d fern) = 	bU-U    + 92.0 I—               (8-1)
               u (cm/sec)
                b
where:     d   =  Sauter  (volume-surface)  mean  diameter of
                drops,  cm
           Up =  air  velocity  relative  to drops,  cm/s
           Q   =  water flow rate,  m3/s
           Q   =  air  flow rate,  m3/s
     According to Steinmeyer in Perry (1973), the Sauter
mean diameter is typically 70% to 90% of the mass median
diameter.  If the drop size distribution is log normal,
this implies that the geometric standard deviation, "cr "
is about 1.6 for 90% and 2.3 for 70%.
      To illustrate the application of the above to the
prediction of entrainment characteristics for a venturi
scrubber, we can consider the case of a throat air velocity
of 100 m/sec and water to air ratio of 1 £/m3(10 -3m3/m3) .
The gas pressure drop would be about 80 cm W.C. and the
Sauter mean diameter computed from equation (8-1) is 79  ym.
From the typical ratios of mass median to Sauter diameter,
we would expect the mass median drop diameter to range from
88 to 113 ym, with "cr " from 1.6 to 2.3, respectively.
                     o
One would therefore predict that the cumulative entrain-
ment concentration would be related to drop diameter within
the range of high and low values tabulated on the following
page.
                           162

-------
Drop diameter, ym      4     5     10    15    20
High concentration,
  cm3/m3             0.035  0.11    2     8    20
Low concentration,
  cm3/m3               -     -   0.0025  0.06  0.6

      If the entrainment contained 10% solids by weight,
the residual particle concentrations after evaporation
would be such that if one wanted to limit the particle
loading due to entrainment to 0.01 g/m3(0.0044 gr/ft3)
the separation of all entrainment larger than 5 urn diameter
for the high estimate and 16 ym diameter for the low would
be required.  Since particle loadings of this magnitude can
be significant for plume opacity, the example shows the
efficiency with which entrainment must be controlled and
the necessity for good data on entrainment size distribu-
tion and concentration.
DESIGN EQUATIONS FOR ENTRAINMENT SEPARATORS
      The design and operation of most entrainment sepa-
rators are governed by three factors:
      1. Pressure drop
      2. Collection efficiency
      3. Reentrainment velocity and reentrainment rate
      Knowledge of the pressure drop through a separation
system is important in calculating the energy loss incurred
and in selecting the proper pumps and other auxiliary
equipment to overcome that energy loss.
      Collection efficiency or overall collection efficiency
is defined as the fractional collection of the droplets by
the separator, i.e.

            ,   effluent concentration
      n =   1 - 	
                influent concentration
                           163

-------
      When the gas velocity in the entrainment separator
is high, some separated droplets in the separator will be
reentrained in the gas stream.  Because of this reentrain-
ment, the observed collection efficiency of the separator
is less than the primary collection efficiency which is
defined as the efficiency an entrainment separator would
have if reentrainment were not present.
      Reentrainment velocity is the gas velocity at which
drops are first observed to become reentrained in the gas.
The onset of reentrainment will vary for different kinds
of entrainment separators and different operating condi-
tions.  Reentrainment velocity determines the maximum allow-
able gas velocity in the separator.  Reentrainment rate
and drop size distribution are needed for the prediction
of emissions from the system.
      Once design equations predicting the primary effi-
ciency, pressure drop, and reentrainment are available; the
operating characteristics of the entrainment separator
can be established.
      Six different kinds of entrainment separators will
be discussed in this section: cyclone, packed bed, zigzag
baffles, tube bank, mesh, and sieve plate.
Cyclone
      The cyclone is the most commonly used entrainment separa-
tor for venturi scrubbers.  Commercially available cyclones
in standard designs for entrainment separators have a maxi-  .
mum capacity of up to 141 m3/sec (300,000 CFM) of gas. Effi-
ciencies of about 95% are claimed for 5 ym diameter drops
in a well-designed cyclone.  Some manufacturers use a bun-
dle of small cyclones (multicyclones), which can efficiently
collect drops as small as 2 ym in diameter.  However, this
arrangement reduces the capacity of  the  device.
                          164

-------
Primary Efficiency - Leith and Licht (1971) derived an
equation to predict primary collection efficiency in coni-
cal bottom cyclones as pictured in Figure 8-1.  With slight
modification it can be applied to cylindrical cyclones.
      The equation for predicting primary collection effi-
ciency is:
      In Pt =  - 2
                          2da V
                              2n+2
                                     (8-2)
where:
          n  =  1  -
0-3
FT]
2831
o.i n -
,0.393 d_)
1 - v
2.5
         u
Pt =

pd =

\A* 1 **~
 d
tg "
                                     (8-3)
          d_  =
penetration, fraction
drop density, g/cm3
gas viscosity, poise
drop diameter, cm
tangential velocity, cm/sec
mean residence time of the gas in the cyclone,
sec
cyclone diameter, cm
       The  mean  residence  time  of the  gas  stream in  the
 cyclone  is:
           V
       t  =
                                     (8-4)
where:
       V  =  effective volume of the cyclone, cm3
        e
       Q  =  volumetric gas flow rate, cm3/sec
                           165

-------
Figure 8-1.   Cyclone with tangential gas inlet,
                       166

-------
       A = inlet area, cm2
      UG = inlet gas velocity, cm/sec

      The effective volume of the cyclone, "V " is defined
                                             c
as the volume of the cyclone minus the volume occupied
by the exit duct and exit gas core.  The diameter of the
exit gas core can be assumed equal to the diameter of
the exit duct.  Leith and Licht  (1971) gave the following
equations for the determination  of effective volume of a
conical bottom cyclone.
      Ve = V  + 1/2 V2                              (8-5)
where:
      V   =  annular  shaped  cdlume  above  exit  duct  inlet
            to mid-level  of entrance duct

      V   = volume  of  cyclone  below exit  duct  inlet
       2
           to  the  natural  length  of the  cyclone
      v   =   — £- (h  -S)
        2      4     S           12
                                                    (8-7)
                 4

where:
                      • i_* * -i_j 11. •
                                                    (8-8)


  and  L  =  natural  length of the cyclone
d = d -(d -bJ
                           167

-------
                                                   (8-9)
a, b, d ,  d ,  S, h, h_ are cyclone dimensions defined
       G   G         S
in Figure  8-1.
Pressure Drop-Shephard and Lapple (1940) derived an equation
for a cyclone with inlet vanes for pressure drop as a function
of inlet gas velocity and the cycione inlet and outlet
dimensions:
                          2
     AP = 0.000513 pr (—) ( 7>5 ab|                (8-10)
                    G \ab/ \  d2   /
where:
     AP = pressure drop, cm W.C.
     PG = gas density, g/cm3
     QG = gas volumetric flow rate, cm3/sec
      a = cyclone inlet height, cm
      b = cyclone inlet width, cm
     d  = cyclone exit pipe diameter,
      6
                                      cm
Equation (8-]D) can be modified by writing it as a function
of the geometric average of the gas velocity at the cyclone
inlet and outlet:
     AP = 0.000513pGv£ve                            (8-11)

Shepard and Lapple also developed an equation  for  a  cyclone
without inlet vanes:
                         2
     AP = 0.000513pn l^ \\±^±\                     (8_i2)
                      ab/ ' d2 /
                            G
                           168

-------
Packed Bed
      Packed beds of standard design with a capacity of
up to 65 m3/sec (140,000 CFM) are available.  They can
remove drops as small as 3 pm in diameter at 80-901
efficiency.  Superficial gas velocities range from 75
to 240 cm/sec, and pressure drop is generally low, 0.05-
0.1 cm W.C. per cm of bed length.
      Cross flow beds are claimed to have high drainage
efficiency and therefore are less prone to plugging.  Up-
stream washing is recommended to avoid plugging if solids
are present in the drops to be removed.
      Packing in different materials, shapes and sizes is
available.  Various rings are claimed to have high col-
lection efficiency and  low pressure drop.
      Packed beds are often used for mass transfer because
of their high interfacial area.  Thus they are sometimes
employed when simultaneous mass transfer and entrainment
separation are desired.
Primary Efficiency - Jackson and Calvert (1966) and Calvert
(1968) have developed a theoretical relationship between
particle collection efficiency and packed bed operating
parameters:

       Pt  =  1  -  exp
                            (e-Hd)
(8-13)
             A   j  ur
          m   d   d   a
        P     9  "6  dc
where:
        j  =  ratio  of channel  width to packing diameter
      H,  =  fractional  liquid hold-up in the bed
        e  =  bed  porosity , fraction  (Table 8-1)
        A  =  bed  length,  cm
                           169

-------
      d  = packing diameter,  cm
      ur = superficial gas velocity,  cm/sec
      d, = drop diameter,  cm

      The experimental data of Jackson (1964)  were analyzed
to determine appropriate values of "j" to use  in equation
(8-13) with all quantities in the equation known except "j",
which was calculated.   The results are given in Table 8-2
which lists "j" values for various types and sizes of pack-
ing material.  For the manufactured packing materials, "j"
is fairly constant at about 0.16-0.19.  The very low value
of 0.03 for coke may be due to the small passages within
the coke itself, which make each large piece of coke func-
tion effectively as a number of smaller pieces.
Pressure Drop - Perry (1963)  gives a generalized pressure
drop and flooding correlation plot which appears as Figure
                                            p2pm  o.2
8-2, where a dimensional group of function 	nL  ,
                                            PGPL§
(centipoise)  ' , is plotted against a dimensionless group
            L /PG\V'2
of function — I— J  , where "G" and "L" refer to the gas
            G \PL/
and liquid mass fluxes respectively.   "Y" is the ratio
of water density to entrained liquid density.   Values for
the packing factor, "F", for dumped pieces, stacked pieces
and grids are given in Tables 8-3 and 8-4.  If "F" is not
       r*
known, —3 may be used instead.
       c.
Tube Bank
      Tube banks made of streamlined struts have been used
as entrainment separators but no experience with round
tubes has been reported.  Particle collection efficiency
and pressure drop for round tube banks have been studied
and the characteristics appeared promising for entrainment
separation application.
                           170

-------
                           TABLE 8-1

         BED POROSITY,  e,  FOR VARIOUS PACKING MATERIALS

Size
(cm)
1.27
1.9
2.54
3.8
5.1
Stoneware
Raschig
Rings

0.57*
0.67
0.68
0.68
0.75
Carbon
Raschig
Rings

0.71*
	
0.75
0.67
—
Steel
Raschig
Rings
(1/16"
thick)


	
0.92
0.92
—
Stoneware
Berl
Saddles
4


0.65
0.69
0.70
—
Stoneware
Intalox
Saddles


..
0.70
0.81
—
Steel
Pall
Rings


_ _
0.93
0.94

*Treyball (1955)
All other data from Perry (1963)
                           TABLE  8 - 2

                     EXPERIMENTAL VALUES OF
          j, CHANNEL WIDTH AS FRACTION OF PACKING DIAMETER
Size (cm)
1.27
2.54
3.8
7.6 - 12.7
Type of Packing
Berl Saddles, marbles, Raschig Rings,
Intalox Saddles
Berl Saddles, Raschig Rings,
Pall Rings
Berl Saddles, Raschig Rings
Pall Rings
Coke
j
0.192
0.190
0.165
0.03
       Adapted from Jackson  (1964) and Calvert  (1968)
                              171

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                 Tablefi-3.   PACKING  FACTORS,  "F",  FOR DUMPED PIECES (m2/m )
                              Nominal size of packing, cm
                  [0.64]  [0.95]  [1.27]  [1.59]  [1.9]  [2.5]  [3.2]  [3.8]  [5]  [8] [10]
 Raschig  rings,
   ceramic
    .16  cm wall    5,250  3,280
    . 32  cm wall
    .63  cm wall
    .95  cm wall
 Raschig rings,
   carbon
    .16 cm wall
    .32 cm wall
    .63 cm wall
    . 79 cm wall
5,250
1,340
 Raschig rings,
   metal
    .08 cm wall    2,300  1,280    980   560
    .16 cm wall                  1,340   950

 Lessing rings,
   porcelain
    .32 cm wall
    .63 cm wall
 Lessing rings,
   metal
    .08 cm wall
    .16 cm wall
             (1,060)
                                   510
                                               430   210
                                                          121   98
                             920   525
                                               430   210
                                                          118
                             510   380
                             720   450   360   272   187  105
                                  (800)
                                                    (360)
              (630)
                                  (472) (387)  (295)  (200)
           Table  #-3..   PACKING  FACTORS,  "F",  FOR DUMPED PIECES (mVm3)  (continued)
Nominal size of packing, cm
[0.64] [0.95]
Partition ring's
Pall rings,
plastic
Pall rings,
metal
Berl saddles 2,950
Intalox saddles, 2,380 1,080
ceramic
Intalox saddles,
plastic
Super-Intalox,
ceramic
Tellerettes
[1.27] [1.59] [1.9] [2.5] [3.2] [3.8]

318 171 105
230 158 92

790 560 360 213
660 475 322 171

108
200


[5] [8] [10]
262 190
82
66

148
131 72

69 52
100

150
Parentheses denote a value of a/e3, rather  than  empirical F.
                                   172

-------
  Table 8-4.  PACKING FACTORS,"?" FOR GRIDS AND STACKED PIECES
              (m2/m3).
                       Nominal  size  of  packing,  cm
                    2.5  3.8   5        8       10    13   14   15
Wood grid          20     11    8.2        5.9     4.9
^letal grid           8.2
Grid tiles                                           118
Checker brick,
  e=0.55       '                                           135
Raschig rings,
  ceramic
    .63 cm wall                 95         16
    .95 cm wall                           36       12.8
Raschig rings,                           21
  metal
Partition rings,
  diameter
    7.6 cm length                     (1,200)    (725)
   .10.2 cm  length                              (705)             (410)
    15.2 cm  length                                               (375)
Partition rings,
  square set
    7.6 cm length                       (690)    (460)
    10.2 cm  length                              (450)             (275)
    15.2 cm  length                             .                  (26°)
 Parentheses  denote  a value of a/e3,  rather than empirical F.
                                 173

-------
  a,
   •

  u
c
       0.5
       0.2
       0.1
      0.05
   cT1 0.02


   u
   Q.



  "   0.01
     0.005
     0.002
     0.001
                :S\
Pressure drop
 rm w r  «of  /Pressure  Drop,\
 cm W.C. per   in  W.C. per Ff|

 cm packing   \£t<  packing htl
              ht.
                1
         0.01  0.02
          0.05  0.1   0.2     0.5


                        L   /PG] 1/2

                    x = —   —I


                        G   IPLJ


                   (dimensionless)
                                                                     10
          Figure 8-2.  Generalized flooding and  pressure drop

                       correlation for packed beds  (Perry,  1963) .
                                174

-------
Primary Efficiency - Calvert and Lundgren (1970)  found that
the collection efficiency for closely packed rods is given
by the equation for rectangular jet impaction.  The collec-
tion efficiency of each stage of impaction can be found in
Figure 8-3.  Each row of tubes except the first represents
one stage of impaction.  "B" is used as a parameter in
Figure 8-3 and is defined by:

     3 = 2 Jl/b                                      (8-14)

where :
      b = jet orifice width
      £ = distance between orifice and impingement plane
"K " , the inertia parameter, is defined with drop radius,
"r ", rather than diameter.
      Efficiency for the bank of tubes is given by:

      E = 1  - (l-Tij)N                               (8-15)

where :
     n .- = collection efficiency for a given particle
          diameter in one stage of rectangular  jet  im-
          .pingement
      N = number of stages in the tube bank
        =  (number of rows) -1

      If the tubes are widely spaced, the target  efficiency,
"n", can be  calculated from  Figure 8-4.   In this  case  the
efficiency for the entire tube bank is:

      E - i  - (i-n-V                             (8

                           175

-------
                                      :er   Chow
                                            Exp.
                                      LS Theory
                 0.5
                    1.0
1.5
            V*
2p  C
 r*-|-i
                        u
Figure 8-3 -  Theoretical and experimental
             collection efficiencies of
             rectangular aerosol jets.
                 176

-------
 w
 tu
 UH
 w
1.0



0.8



0.6



0.4



0.2



   0
               ^ I	Rectangular half body
                                                    Cylinder
                       (ribbon with woks)
                   Ribbon normal
                   to (lav
                                                 Ellipsoid of
                                                revolution lot
                                                   thick
^•^ Ellipsoid
C~j of revolu-
'^"^ tion. ZO*
 NACA 650,004 -at
 zero angle of
 attack 4t thick
 low-drag symmet-
 rical airfoil
                                          Joukowski 15* thick sym-
                                          metrical airfoil at zero
                                          angle of attack
          0.1
                              10
   100
                                                      d   U
                 INfiRTIAI PARAMETER,  K *  ——^—£—
                                            P     " 14- r1 ®,
Figure 8-4 -  Theoretical  impaction efficiency  as
                 a function of inertial  parameter
                 for  different targets.
                               177

-------
where:
     a1 = cross-sectional area of all the tubes in one row
      A = total flow area
      n = number of rows

Pressure Drop - Pressure drop for gas flow normal to banks
of round tubes can be predicted by means of Grimison's cor-
relations (Perry, 1973).  As an approximation, Lapple  (Perry,
1973) suggests that 0.72 velocity heads are lost per row of
tubes in arrangements of the kind commonly used in heat ex-
changers.  Calvert and Lundgren (1970) found that for  closely
spaced tube banks Lapple's approximation agreed satisfactorily
with experimentally determined pressure drops.
      Houghton and Radford (1939) studied streamline strut
banks and found that for a center-to-center spacing of 2
strut widths  (i.e. open  space = strut width) the pressure
drop was about 0.16 velocity heads per row.  This can  be
expressed as:

     AP = 0.16 N pG (5.3 x 10 '")  (u£)2 cm W.C.      (8-16a)

where:
      Up is the actual gas velocity

Mesh
      Knitted mesh of varying density and voidage is widely
used for entrainment separators.  There are basically  three
different kinds of mesh:   (1) Layers with crimp  in  the same
direction - each layer is actually a nested double  layer.
(2) Layers with crimp in alternate directions  -  this results
in an increase in voidage, reduced sheltering, a decrease
in pressure drop per unit length  and an increase in target
efficiency per layer. (3) Spirally wound layers  - the  pres-
                           178

-------
sure drop is lower by about 2/3 than in layers with crimp
in the same direction, but the creeping of fluids, which
contributes to reentrainment, is expected to be higher.
      Standard mesh 10-15 cm thick having a density of
about 0.15 g/cm3 is used to remove drops larger than 5 ym
in diameter.  Gas velocities range from 0.3 to 5 m/sec and
liquid flow rate is limited by the drainage capacity of the
mesh to 2.5 x 10 "3 g/sec cm2 of mesh.  A lower density mesh
made of standard wires is used when 10-20% higher flow rates
are desired.
      Often two mesh type separators in series are used to
remove drops in the 1-5 ym diameter range.  The first mesh,
normally made of fine wires, coalesces the small drops, and
the second mesh, made of standard wires, removes them.  The
first mesh is operated beyond the flooding velocity and the
second under flooding velocity.  A major disadvantage with
this arrangement is a pressure drop which may reach 25 cm
W.C.
      Some manufacturers use two or three stages of mesh,
the first being coarser and the final being finer, to remove
large and small drops successively.
      A mesh type separator has the advantage that it can
be made to fit vessels of any shape.  Any materials which
can be drawn into the shape of a wire can be used for fab-
rication.  However, mesh separators are limited in appli-
cation because they plug easily.  This can be avoided by
upstream washing, which will decrease removal efficiency and
increase pressure drop.
Primary Efficiency-Eradie and Dickson (1969) present the fol-
lowing expression for primary efficiency in mesh separators:
                           179

-------
      E = 1-exp ( - |  ? a2*2 ")                    (8-17)

where:
     a~ = specific area of mesh,  surface area of wires
          per unit volume of mesh pad, cm2/cm3
     JU = thickness of mesh pad in the direction of gas flow,
          cm
      n = collection efficiency of cylindrical wire

      The collection efficiency of cylindrical wire "n"
can be obtained from Figure 8-4.   The factor of 2/3 in the
exponential was introduced by Carpenter and Othmer (1955)
to correct for the fact that all  the wires in the knitted
mesh are not perpendicular to the flow.  That factor is
the ratio of the projected area of wires perpendicular
to the flow to the cross-sectional area of wires along
the wire length.
          4(l-e)
     a  =    	                                   (8-18)
      L     ac
                    \
Pressure Drop - York and Poppele (1963) have suggested
that the total pressure drop in the knitted mesh is the
sum of the pressure drop in the dry knitted mesh and the
pressure drop due to the presence of liquid:
      AP = APdry + APL                              (8-19)
where:
      AP,   = pressure drop in absence of liquid,  cm W.C.
        APL = pressure drop due to presence of  liquid,
              cm W.C.
      York and Poppele considered the mesh  to be  equivalent
to numerous small circular channels and used the  D'Arcy
formula for pressure drop in a pipe to correlate  the  dry
                           180

-------
pressure  drop through the mesh.  York and Poppele's data
for knitted mesh with crimps in alternated and in same
direction are plotted in Figure 8-5.  Their data are close
to those obtained by Stasangee  (1948) and Shuring (1946).
Similar curves obtained by Bradie and Dickson (1969) for
spiral-wound and layered mesh are also plotted in Figure
8-5.  Figure 8-5 should be used in determining dry pressure
drop, which is calculated from  the expression:

      APdry - -   a                               (8-20)
          7       e

The unit of "AP^  " is in dynes/cm2.  It can be converted
to cm W.C. by dividing it by 981.
      Pressure drop data due to presence of liquid are not
available for all operating conditions or for mesh of dif-
ferent styles.  Values of "APT " obtained by York and Poppele
                             Li
are presented in Figures 8-6 and 8-7, with liquid velocity
                                                  I1T II
as the parameter.   Liquid velocity is defined as  — x—  where
"L" is the volumetric flow rate of liquid and "A" is the
cross-sectional of  the mesh  in liquid flow direction.  The
specifications of the knitted mesh used are shown in the two
figures.
Maximum Allowable Gas Velocity - Several factors govern
the allowable gas velocity through wire mesh for a given
set of conditions:
      1. p, and PG
      2. Liquid viscosity
      3. Specific surface
      4. Liquid entrainment  loading
      5. Suspended  solid content
      Application of the Souders-Brown equation for  the
calculation of allowable vapor velocity for wire mesh mist
eliminator based on gas and  liquid densities has been
suggested by York (1954).
                           181

-------
  1.0


  0.5
  0.1

 0.05
 0.01
             I I I  ' I 11
          Satsangee data (1948)
          and Shuring data (1946)
         JZrimps  in  alternated direction
               Crimps  in same direction
      - Layered mesh—r***
:  Spiral-wound  mesh
          i   i
                        i  i  i
                                ni
     10
            100
1,000
              N
               Re,G
                                          i i
10,000
                          VJ
Figure  8--5.  Friction Factor, £, versus Reynolds
             number, NR  G for wire mesh entrainment
             separator  '  with entrainment load.
                    182

-------
00
            10
           1.0
         e
         o
         0.01
                         'I  I   I  I   I   I  I
I	I
J	i
                    56  7  8  9 10 11 12 13

                                cm/s
         Fig.  8-6.  Pressure  drop  due  to
                    presence  of  liquid in
                    the knitted  mesh with
                    the crimps in  the  same
                    direction .
                                                            10
                                                           1.0
e
o
                                                           0.1
  0.01
                                                                         I   I
                                                                         V
      3  4 S  6  7  S  9  10 11 12
         UG [ PG/(PL'PG)    >  cm/S

  Fig.8-7 .  Pressure drop due to
             presence of liquid in
             the  knitted mesh with
             the  crimps  in the alter
             nate 'direction.

-------
      un     =30.5
       G max
                                  °'5
where "a," varies with operating conditions and mesh de-
sign.  For most cases, a, = 0.35.
Zigzag Baffles
      Baffles can efficiently separate drops greater than
10 ym in diameter, while some of the better designed de-
vices can separate drop diameters of 5-8 ym.  Common gas
velocities are 2.0-3.5 m/sec, and the pressure drop for
a 6-pass separator is about 2-2.5 cm W.C.
      The most common baffle shape is zigzag with 3 to 6
passes.  These can be fabricated from a continuous wavy
plate or each pass is separated, in which case the sepa-
ration distance is normally smaller than the width of the
baffles.  Cross-flow baffles are claimed to have higher
drainage capacity than countercurrent flow baffles.
Primary Collection Efficiency - A model to predict primary
efficiency was developed, based on turbulent mixing.  The
primary collection efficiency of a continuous zigzag baf-
fle section is:
        = 1 - exp
                      57.3 ur b tane
                            b
u.   nw6
 r                        (8-22)
where:
      n = primary collection efficiency, fraction
    utc = drop terminal centrifugal velocity, in the
          normal direction, cm/sec
     UG = superficial gas velocity, cm/sec
      n = number of bends or rows
      6 = angle of inclination of the baffle to the flow
          path, degrees
                          184

-------
      w = width of baffle, cm
      b = spacing between two consecutive baffles in
          same row, cm

      The drop terminal centrifugal velocity can be deter-
mined by performing a force balance on the drop.  The result
is :
                      0.5
U,
                                                   (8-23)
where:
     da = drop diameter, cm
     p, = drop density, g/cm3
      a = acceleration due to centrifugal force, cm/sec2
     CD = drag coefficient
     PG = gas density, g/cm3               „

      If the drop Reynolds number  is  low  (NRg D< 0.1),
Stokes1 law applies.  For this  condition, the drag co-
efficient is given by:

     C  = — ^-                                    (8-24)
          NRe,D
where ND  n  =  drop  Reynolds  number
       Ke , u
               dd  utc  PG
      By  combining  equations  8-23  and 8-24,  we  obtain:
           d5  pj  a
    „   =   d   d _                                   (8-25)
    utc     18  U                                     V
                           185

-------
The acceleration due to centrifugal force is defined by
the following equation:

                2      2
          2 (ur)    2 ur sin 6
      a = 	0.1, another appropriate drag coefficient
should be used in equation 8-23. Foust, et al. (1959)
gave a plot of drag coefficient as a function of Reynolds
number in Figure 8-8, which can be used to determine "u. ".
The effect of surrounding drops on the motion of any indi-
vidual drop is neglected.

Pressure Drop-Determination of the pressure drop is based  on
the drag coefficient, "fD", for a single plate held at an
angle "9" to the flow as presented in Figure 8-9 (Page
and Johanson, 1927) .  Neglecting the effect of neighbor-
ing plates, pressure drop may be expressed as:
                                 , 2
     AP =  E  1.02 x ID'3 f  p  -£ Ji              (8-27)
          i=l              "  b 2  At
where:
     AP = pressure drop, cm W.C.
     A  = total projected area of baffles per- row  in the
          direction of inlet air flow, cm3
     At = duct cross-sectional area, cm2

      The summation is made over the number of rows  of
baffles.
                          186

-------
 10,000
  1 ,000
H
O
H
fe4
k.
^
O
OS
    100 -
                      ifi=0.125

                      ip= 0. 2 2 0

                      i)'=0.6nD

                      =0. 806
     0.001   0.01    0.1     1      10     100    1000   10,000   10s    106


                      Reynolds  nuisher   N.
                                        Re.D
             dd  utc  pr,
                                                  u,
        l:igure 8~8-   Drag  coefficient  versus  Reynolds number after
                      Foust et  al  (1959),  with sphericity ip as
                      the parameter.
           1 .2
         -0.8
        W
        u-
        PJ
        o0.4
        LJ

        C3
                   I      r     i     i     i     r    i     r
                   i      i
   Plate Inclined to Flow

      „ 7"
           Angle of
           Incidence
                j	I
I     i     I   	I
                        20
40
              60
                                                       80
                          ANGLE OF INCIDENCE, degrees
         Figure 8'^.   Drag coefficients  for  flow  past  inclined
                      flat plates (data  from A. Page  Si  F.C.
                      Johansen, (1927).
                                 187

-------
     The actual gas velocity, "UG", in the baffle section
should be used in Equation (8-27).  The actual gas velocity
is related to superficial velocity by:

    ul = ur/cos 9                                 (8-28)
     b    b

Note that the angle of incidence for the second and sub-
sequent rows of baffles will be twice the angle of inci-
dence for the baffles in the first row.
Tray Towers
     Tray towers are vertical channels in which the
liquid and gas are contacted in stepwise fashion on
trays or plates.  The liquid enters at the top and flows
downward by gravity.  On the way, it flows across each
tray and through a downspout to the tray below.  The gas
passes through openings in the tray, then bubbles through
the liquid to form a froth, disengages from the froth,
and passes onto the next tray above.  There are various
tray geometries.  The sieve tray and bubble cap are the
two most common types.
Sieve Plates - Primary efficiency - Taheri and Calvert
(1968) derived an equation for sieve plate primary col-
lection efficiency:

     E = 1-exp (-40 F* K )                        (8-29)
                     *  P

where 0.30 < F. < 0.65,
             x>
         p jdjV,
    Kp • -±±±                                   (8-30)
     P    9"Gdh
where:
    F^ = foam density, ratio of clear liquid height
         to total foam height
    v  = velocity of gas through hole, cm/sec
                         188

-------
     d,  = hole diameter, cm

.Pressure Drop - Perry (1963) has suggested that the
 pressure drop in sieve plates can be calculated accor-
 ding to :
     AP=h+h+hj+h                       rs
           w    ow    dp    r                      I8

 where :
     hw = weir height = 4-9 cm, assume 5 cm, if unknown

    h                                   QT
     ow = head over the weir = 0.143 F  — —
                                      W W-j

                                i  Pr vh
    hAn = dr7 Plate head loss = - -- - ^i
     dP                         c2 PL 2g
                                          tiJ J1 "f" f^ Y*
     h  = residual pressure drop = 0.013
                                           PL
     c2
        = 1.14
0.4 (1.25 - £h) + (1 - £h)2j
(8-32)
 where:
     F  = column wall curvature correction factor = 1.1
      w
     Q,  = liquid flow rate, here in m3/hr
      Li
     w1  = weir length, m
     f,  = fraction of the perforated open area in the
          plate

 Bubble-cap Trays - Equations used to predict primary col-
 lection efficiency and pressure drop of sieve plates can
 also be applied to bubble-cap trays.

 DESIGN PROCEDURES
      The general steps in designing an entrainment separa-
 tor  are as follows:
                          189

-------
     1.  Based on process  condition and separator con-
        figuration,  construct the grade efficiency
        curve for the separation.  Equations  for pri-
        mary efficiency can be used for this  purpose.
        In case the  gas velocity is higher than the
        reentrainment onset velocity,  reentrainment
        should be subtracted from the  primary effi-
        ciency .
     2.  Compute the  collection efficiency for the whole
        population of the drops. This  can be  done either
        graphically  or mathematically.  For graphical
        solution, plot Ft-  versus fraction smaller than
        d, -  (where Pt. is penetration  for drop size d-, -) .
        The  area under the curve is the overall pene-
        tration.  Outlet loading is equal to  inlet
        loading times overall penetration.
     3.  Compute expected pressure drop.
     In  the  process  of designing an entrainment separator,
the steps should be  repeated for different proposed sep-
arator  configurations.  The final configuration can then
be selected  after optimization analysis.
                         190

-------
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Behie, S.W. and J.M. Beeckmans. "On the Efficiency of
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Boll, R.H., "Particle Collection and Pressure Drop in
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Boll, R.H., L.R. Flais, P.W. Maurer, and W.L. Thompson,
 Mean Drop Size in A Full Scale Venturi Scrubber via
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Bradie, J.K.  and A.N. Dickson.  Removal of Entrained
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Brink, J.A. and C.E. Contant, "Experiments on an Indus-
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Calvert, S. "Source Control by Liquid Scrubbing"
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Calvert, S. "Venturi and Ohter Atomizing Scrubbers
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Calvert, S.  Engineering Design of Fine Particle Scrubbers.
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Calvert, S.  and D. Lundgren.  Particle Collection  in
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Calvert, S., N.C. Jhaveri,  and S. Yung, "Fine  Particle
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Calvert, S., S. Yunfe, and J. Leung, "Entrainment  Separator
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                          191

-------
Carpenter, C.L. and D.F. Othmer.  Investigation of Wire
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Crowe, C.T., Ph.D. thesis, University of Michigan,
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Dickinson, D.R. and W.R. Marshall, AIChE Journal, 14,
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Ekman, P.O. and H.F. Johnstons, "Collection of Aerosols
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Fuchs, N.A.  The Mechanics of Aerosols.  The Macmillan
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Garner, F. and R. Suckling, AIChE Journal, £, 114, 1958.

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Gleason, R.J. and J.D. McKenna, paper presented at the
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Gretzinger, J. and W.R. Marshall, Jr., AIChE Journal,  1
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                         192

-------
Hidy, G.M. and J.R. Brock, "The Dynamics of Aerocolloidal
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Matrozov, V.I., 0. Soobscheniya, Nauchno-Tekhnicheskikh
Rabotakh NIVIF, Nos. 6/7, 152,  1953.

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Kogaku, pp 1114-1119, 1967.

Morishima, N., T. Yoshida, Y.  Kosoka,  and  Y.  Nonaka
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Kogaku  Kenkyu Kaishi  (J.  Res. Assoc.  Powder Technol.)
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                         193

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                         194

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APPENDIX A.  DERIVATION OF SCALING FACTOR
     In solving equation 5-23 we assumed ul  =  0.   In order
to find Pt(d ) for other values of u| , we make use of the
following artifice.  Imagine the given duct to be projected
in the upstream direction until a distance !„ is  reached
                                            rl
such that at z = -lu, the liquid velocity is zero.  That is,
the distance IH is that length of a hypothetical duct having
zero initial liquid velocity with established liquid velocity
u
 do
at its exit.  In this Appendix, we will distinguish
quantities referring to the hypothetical duct from those
referring to the given duct by using a prime (') with the
former.  Then  from  the geometry  of  the duct, we get
      r  = r
      and  A1  =  A
            o     o
                        tan
                           tan  3 \ j
                                      (A-l)

                                      (A-2)
      From continuity of gas  flow,  we  have
           "GO*
                  m,
               A'
                 o
                             m.
               = ur  I 1 -
                  Go I
                          lu tan 3
                           n
                                                    (A-3)
      From the definition of C, we have
            Do
                              DQ
                         U
                          Go
                  |uGo-udo|
                                10.5
           f '  =
           LDo
u
u~
Go
Go
-udo
                        0-5
JDo
                         u
                          Go
                                 0.5
                                     IH tan 6 1
                                        ~o   J
                                  J/2
                                                         (A-4)
                            195

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     Using equations A-l through A-4  and  the  definitions


of the various dimensionless parameters,  the  following


relations are obtained:
               /      W         \
          L' = (L + LH)(l  - S LH)                       (A-5)






          S' =  S (l - S LH)":)/2"1                      (A-6)
          ud' = "d1  - S LH                            CA-7)
          B, _/QL

             "
                    G
                          196
             = B (l - S LH)"j/2     •••                    (A-8)



which give the desired scaling factors.

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                                 TECHNICAL REPORT DATA
                           (Please read Instructions on the reverse before completing)
 ^£4^600/2-77-172
                            2.
                                                        3. RECIPIENT'S ACCESSION-NO.
    -c AND SUBTITLE
•    nturi Scrubber Performance Model
                              5. REPORT DATE
                               August 1977
                                                        6. PERFORMING ORGANIZATION CODE
 Shui-Chow Yung,  Seymour Calvert,  and
	Harry F.
                                                        J. PERFORMING ORGANIZATION REPORT NO.
3. PERFORMING ORGANIZATION NAME AND ADDRESS
 A. P.T. ,  Inc.
j 4901 Morena Boulevard,  Suite 402
 San Diego, California  92117
                              10. PROGRAM ELEMENT NO.
                              1AB012; ROAP 21ADL-002
                              11. CONTRACT/GRANT NO.

                              68-02-1328, Task 13
\ ^.SPONSORING AGENCY NAME AND ADDRESS   ~~
\ EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC 27711
                              13. TYPE OF REPORT AND PERIOD COVERED
                              Task Final; 3-6/76	
                              14. SPONSORING AGENCY CODE
                                EPA/600/13
15. SUPPLEMENTARY NOTES  T-p-oT  ornT) 4- „!  ee-     e
                    IERL-RTP task officer for
Drop 61,  919/541-2925.
                                Jg
                                                                   E< Sparks  Mail
   ABSTRACT
               report gives results of a review and evaluation of available venturi
  -..rubber design equations. Calvert's differential equation for particle collection and
|  Boll's differential equation for pressure drop were selected for numerical solution,
?  and the results are  presented graphically. Particle collection and pressure drop of
'.  Fonturi scrubbers can be approximated by the collection occurring in the venturi
•  throat and by the drop acceleration loss, respectively. Simplified equations were
;  derived by applying Calvert's and Boll's equations to the venturi throat section. The
I  new design equations  are much simpler to use and compare favorably with available
j  performance data.
                               KEY WORDS AND DOCUMENT ANALYSIS
                 DESCRIPTORS
                                            b.lDENTIFIERS/OPEN ENDED TERMS
                                           c.  COS AT I Field/Group
; Air Pollution
tScrubbers
• Venturi Tubes
l Design
j Performance
 Mathematical Models
Dust
Flue Gases
Entrainment
Separators
                                           Air Pollution Control
                                           Stationary Sources
                                           Particulate
                                            Venturi Scrubbers
13B
07A
14B
                                            12A
11G
21B
07D
!13. DISTRIBUTION STATEMENT

: Unlimited
                  19. SECURITY CLASS (ThisReport)'
                   Unclassified
                                                                     21. NO. OF PAGES
                                                                         212
                  20. SECURITY CLASS (Thispage)
                   Unclassified
                                                                    22. PRICE
EPA Fo-m 2220-1 (9-73)
               197

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