EPA-660/3 74-004a
March 1974
                                      Ecological  Research Series
      Turbulent  D if fusion  In
       Liquid Jets:  Part I

                                   Office of Research and Development
                                   U.S. Environmental Protection Agency
                                   Washington, D.C 20460

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            RESEARCH REPORTING SERIES
Research reports of the  Office  of  Research  and
Monitoring,  Environmental Protection Agency, have
been grouped into five series.  These  five  broad
categories  were established to facilitate further
development  and  application   of   environmental
technology.   Elimination  of traditional grouping
was  consciously  planned  to  foster   technology
transfer   and  a  maximum  interface  in  related
fields.  The five series are:

   1.  Environmental Health Effects Research
   2.  Environmental Protection Technology
   3.  Ecological Research
   Hm  Environmental Monitoring
   5.  socioeconomic Environmental Studies

This report has been assigned  to  the  ECOLOGICAL
RESEARCH  series.   This series describes research
on the effects of pollution on humans,  plant  and
animal   species,  and  materials.   Problems  are
assessed   for   their   long-   and    short-term
influences.    Investigations  include  formation,
transport, and pathway studies  to  determine  the
fate  of  pollutants and their effects.  This work
provides the technical basis for setting standards
to  minimize   undesirable   changes   in   living
organisms   in   the   aquatic,   terrestrial  and
atmospheric environments.

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                                                   EPA 660/3-74-004a
                                                   March 1974
           TURBULENT DIFFUSION IN LIQUID JETS:   PART I

             Measurement of Particle Concentration
                   By a Light Scattering Probe
Charles H. Tinsley,  Warren S. Stevenson and Victor  W.  Goldschmidt
                  Engineering Experiment Station
                School  of Mechanical Engineering
                         Purdue University
                   Lafayette, Indiana 47907
                      Project No. 16070 DEP
                     Program Element 1BA025

                         Project Officer

                       George R. Ditsworth
       Pacific Northwest Environmental Research Laboratory
            National  Environmental Research Center
                     Corvallis, Oregon  97330
                          Prepared- for

              OFFICE  OF RESEARCHED DEVELOPMENT
             U.S.  ENVIRONMENTAL PROTECTION AGENCY
                    WASHINGTON, D.C.  20460
For sale by tbe Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402 - Price $1.16

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                   EPA REVIEW NOTICE
This report has been reviewed by the Office of Research
and Monitoring; Environmental Protection Agency and approved
for publication.  Approval does not signify that the con-
tents necessarily reflect the views and policies of The
Environmental Protection Agency, nor does mention of trade
names or commercial products constitute endorsement or
recommendation for use.
                         ii

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                             ABSTRACT
A technique for measuring particle concentrations in turbulent flows
was investigated.  This technique is the measurement of the light
scattered from an incident beam by the solid contaminants  present.

The results show that for moderate concentrations the scattering
system gives proportional increases in count to increases  in particle
concentration.  The limitations of this system are the signal  to noise
ratio and the condition of singular scattering by the particles.

Suggestions on refinements on the correlation technique used are
made and observed phenomena which require further investigation
are discussed.

This report was submitted in (partial) fulfillment of Contract
16070 DEP under the (partial) sponsorship of the U.S. Environmental
Protection Agency.
                                iii

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                      CONTENTS



Section                                           Page

   I      Conclusions                              1

  II      Recommendations                          3

 III      Introduction                             5

  IV      Experimental Apparatus Description       21

   V      Measurements and Results                 33

  VI      Discussion of Results                    49
              r
 VII      Discussion of Measurement Errors         51

VIII      Acknowledgements                         57

  IX      References                               59

   X      Glossary of Symbols                      63

  XI      Appendix                                 65

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                           FIGURES


 No.                                                      Page

 1.  Optical System Used For Light Transmission             7
     Measurements.

 2.  Probe With Miniature Photocell (Fiber Optics Probe).   8

 3.  Angular Distribution of Scattered Light For
     Particles Used.                                        10

 4.  Optical Geometry Defining Scattering Volume.           12

 5.  Angular Scattering Distribution For Various Values
     of Size Parameters.                                    13

 6.  Variation of Dimensionless Length With Solid Angle.    17

 7.  Effective Traversing Length.                    '       19

 8.  Schematic Fluid Flow System.                           22

 9.  Inlet Section and Test Region.                       "  23

10.  Velocity Measurement Instrumentation.                  25

11.  Optical System.                                        26

12.  Schematic of the Electronic System.                     28

13.  Electronics Used in Signal Analysis.                   29

14.  Particle Size and Number Measurement System.           31

15.  Frequency vs. Diameter For Lycopodium Spores.          35

16.  Frequency vs. Diameter for Microbeads.                 36

17.  Dimensionless Distance vs. Dimensionless Velocity.     37

18.  Observed Count Per Second Versus  Position For Dow
     Beads.                                                 40

19.  Count Per Second Versus Position  For Lycopodium
     Spores.                                                41

20.  Observed Count Per Second Versus  Concentration For
     Dow Beads.                                             42
                            vi

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21.  Observed Count Per Second Versus Concentration For
     Lycopodium Spores.

22.  Observed Count Per Second Versus Sensitivity For
     Dow Beads.

23.  Observed Count Per Second Versus Sensitivity For
     Lycopodium Spores.

24.  Typical Coulter Counter Counts vs. Concentration
     For Dow Beads.

25.  Typical Coulter Counter Counts vs. Concentration
     For Lycopodium.

26.  Observed Count Per Second Versus Position For
     Lycopodium Spores (Different Alignment).

27.  Count Per Second Versus Position Upper and Lower
     Limits.

28.  Observed Count Per Second Versus Concentration
     Upper and Lower Limits.
                           Vll

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                          TABLES






No.                                                    Page



1.  Particle Data.                                     33



2.  Particle Supplies and Properties.                  34
                          viii

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                         SECTION I

                        CONCLUSIONS
It was found in this investigation that light scattering can
be used to measure concentration profiles in internal turbu-
lent flows in regions not adjacent to the wall.

Other important conclusions reached in this investigation are
presented below.

     1.  Changes in concentration levels resulted in
         proportional changes in counts per second at
         the sampler.

     2.  For low concentrations of solids with specific
         gravity close to one, the concentration profiles
         closely approximated that of the velocity.  How-
         ever, for higher concentrations the similarity
         becomes increasing less pronounced.

     3.  For a given alignment the scattering system
         seemed insensitive to changes of particle size
         and real index of refraction.

     4.  The use of a Coulter counter was not feasible
         as a check of concentration levels.  A more
         practical system would be to use a fiber optic
         probe.

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                        SECTION II

                      RECOMMENDATIONS
This study was limited to the investigation of the possible
use of a light scattering probe as a particle concentration
sampler,

     1.  The use of alternate sampling methods might
         be considered when applicable.  For instance,
         when sampling droplets or bubbles the use of
         a modified hot wire or hot film anemometer
         may well be more convenient and reliable.

     2.  The actual sampling volume of the light scat-
         tering probe has to be selected to eliminate
         multiple particle scattering signals, as well
         as to permit a dependable calibration of the
         samples.

     3.  Techniques for signal to noise optimization
         should be studied in future tests if a device
         of the type described is to be employed.

     4.  Additional studies are necessary to determine
         the exact count per second and particle number
         density relationships.  These studies should
         follow the direction taken by M.J. Fischer and
         F.R. Kause (1967) or that suggested by H.L.
         Morse et al.  These authors used a two point
         correlation method by either using two beams
         or two detectors.  This allows correlation to
         help eliminate unwanted noise.

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                        SECTION III

                       INTRODUCTION



                     SCOPE OF PROJECT

The stated objectives of the work sponsored under Contract
#16070DEP, were twofold.  One to establish an effective
method of tracking contaminants in a liquid jet, including
the use of a laser system.  Two to determine the diffusion
due to turbulence of contaminants of different size and
density.  The second objective was fully met.  An earlier
report "Turbulent Diffusion in Liquid Jets" dealt directly
with it.  On the other hand the first objective was only
partly met.  It is now discussed in this report.  The
second objective was met through the research of Dr. Strong
C. Chuang.  His doctoral thesis was completed on August
1970.  The research into the use of a laser as a sampling
device was conducted by Mr. Charles H, Tinsley as part of
his M. S. studies at Purdue University.


                    PROJECT BACKGROUND

Knowledge of the properties of two phase flow systems,
such as solid-gas, solid-liquid and liquid-gas, is impor-
tant in many aspects of engineering.  In recent years ap-
plications in nuclear reactor development, chemical pro-
cesses, dispersion of contaminants in waterways, and the
dispersion of particulate matter into the atmosphere have
called for knowledge of the concentration and concentration
gradient of the dispersed phases.

Several techniques for the experimental evaluation of the
distributions of dispersed phases have been proposed.  One
is the hot wire impact method developed by Goldschmidt and
Eskinazi  (1966).  This has been used to measure aerosol
particle concentrations  (HDuseholder  (1968)) and Lee (1970)
and to measure bubble concentrations (Chuang (1969)), all in
free turbulent jets.  This method consists of inserting a
hot wire probe into the flow and measuring the signal re-
sulting from the impact of bubbles or liquid droplets on
the wire.  Soo et al  (1964) investigated several different
methods for measuring concentration distribution and mass
flow.  The more successful of these was the light attenua-
tion method.  In this method light is projected perpendicular
to the flow stream and the transmitted (unattenuated) light
is measured on the other side.  The amount of light received
by the detector can be related to the size and the concentra-
tion of particles in the flowing medium.  Phelps (1968)

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evaluated this dependence of light transmitted on the aver-
age concentration, particle diameter and particle properties.
The experimental arrangement is shown in Figure 1.  Soo et al
(1964) used a modification of this method employing a fiber-
optic probe.  This has the same dependency on particle size
and properties and particulate concentration as shown by Phelps
for the amount of light received.  The primary difference bet-
ween these two methods is that the test section for the experi-
ments of Soo et al is defined by the geometry of the probe,
and the test section for Phelps is defined by the cross-section
of the flow.  Consequently, Soo et al are able to obtain a
gradient and Phelps is only able to obtain an average concen-
tration.  The disadvantage in the method of Soo et al is that
a probe must be inserted into the flow field.  An example of
the type of probe used by Soo et al is shown in Figure 2.
This probe was used by Peskin and Baw to obtain concentration
profiles in pipe flow with solids and air as the two consti-
tuents .

The method used for the measurements reported herein was
light scattering.  In this method no physical probe is in-
serted into the flow.  The concentration is measured in a
finite volume which is determined by the geometry of the op-
tics.  This method has been used previously by Rosensweig,
Hottel and Williams 1961, while studying the concentration
gradient in free turbulent flows of a gas-solid mixture.  In
this study the phases are solid-liquid and the turbulent flow
under consideration is an internal flow.  The object of this
study was to evaluate the feasibility of using a light scat-
tering system to determine the concentration and concentra-
tion gradient of the solid particles in a turbulent internal
flow.

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A.  Spectra-Physics model 124
    Stabilite gas laser X = 6328 A

L-  Condensing lens

L_  Collimating lens

B.  Test cell

C.  Interference filter

D.  RCA IP-28 photomultiplier tube

E.  PPI Laboratory photometer

F.  Leeds & Northr
    strip recorder

C.  D.C. power supply
E.
•up Speedomax
b
•ply
G



I— 1
B
^^^
i

J
•

L
— J

••^
                FIGURE  1  - OPTICAL  SYSTEM USED FOR

          LIGHT TRANSMISSION MEASUREMENTS  (PHELPS  (20))

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                                                                                     FLOW
00
    I-GLASS ROD
   PHOTOCELL -
TO VOLTMETER_
                                      FIGURE 2  PROBE WITH MINIATURE PHOTOCELL

                                                PESKIN AND BAW (18)

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                 THEORETICAL BACKGROUND

        Scattering Parameters and System Response


Light that traverses a medium may be transmitted, absorbed
or scattered.  There are certain parameters of the medium
and of the incident light that determine to what degree
transmission, absorption, and scattering occur.  These
phenomena are related such that the amount of light not
transmitted  (extinction) is equal to the sum of losses
due to scattering and absorption.

     In equation form:

     Extinction = Absorption + Scattering                  (1)

A brief summary of these parameters and their effect on
extinction, primarily taken from Green and Lane (1957),
is given here.

The relative index of refraction of a particle suspended in
a medium affects extinction.  The relative index of refrac-
tion is given by:


          n particle                                       (2)
     n  _ __i	
          n  fluid

where n = real part of the complex index of refraction (n - iko)

      i =  -1

      k  - a x
      K° ~ 4rT

with a = absorption coefficient, and X =  wavelength of the
                                          incident beam

Scattering systems generally utilize particles which have a
zero absorption coefficient, thereby maximizing the amount
of the signal obtained by scattering alone.  The effect of
the index of refraction on the angular distribution of scat-
tered light is shown in Figure 3 for the two types of parti-
cles studied.

Two other important parameters for scattering systems are the
angle 9 subtended between the beam and the detector, and the
solid angle,  a  viewed by the detector.  These angles help
determine the length of the scattering volume.  When the angle,
9, is zero the scattering system reduces to a transmission
system and the scattering volume is maximum.  For angle,  9,

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                                              6 =  30
                                                              (Microbeads)

                                                                  (Dow)
                            10^         10*         IQ6          108
FIGURE 3 - ANGULAR DISTRIBUTION OF SCATTERED LIGHT FOR PARTICLES USED

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equal to ninety degrees the scattering volume is minimum.
These angles are shown in Figure 4.

Another important parameter in scattering studies is the
ratio of the incident light.  This parameter is the size
parameter defined by:

     q = 2rrrA                                            (3)

where

     r = radius of the particle

     X = the wavelength of the incident light

Theoretical angular distributions of scattered light were
obtained for particles used in this study from an I.B.M.
computer program called Dame.  This program has the capa-
bility of calculating scattering distributions for a size
parameter up to 5000.  The distributions obtained are pre-
sented in Figure 5 as a function of size parameter.

There have been several theories proposed to explain the
relationship between the incident beam and losses associated
with the scattering and absorption.  For the size range of
particles used the appropriate theory is that developed by
Mie.  A detailed explanation of this theory is given by Van
de Hulst  (1957).  For the type of scattering experiments
conducted in this study a detailed examination of Mie's
theory is not needed.  The underlying assumption of this
study is that the light scattered is directly proportional
to the number of scatterers in the control or scattering
volume.  This is true as long as single or independent scat-
tering is the only type present.  Sinclair (1950)  has stated
that this assumption is valid as long as the distance between
particles is ten or preferably a hundred times the radius of
the particle.

The single scattering assumption has been used by many
investigators; Green and Lane (1957) give the following
simplified scattering expression:
       = krPn
where
     I = the scattered light intensity
     r = the radius of the scatterers
     P = parameter determined experimentally
     n = number of scatterers
                          11

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                                                   Pinhole apertures  (394 microns)

                                                   Photomultiplier Tube  (detector)
                                                 -  Bandpass  Filter  for  6328 A
                                                   Angle  between detector  and  beam
                                                   (30°)

                                                   Solid  angle  formed by detector
                                                   (0.4°  planar angle)

                                                   Diameter  of  incident beam (2mm)

                                                   Distance  between  apertures  (2inches)

                                                   Length of scattering volume

                                                   Distance  of  the scattering  volume
                                                   from origin  of a   (5 inches)
                                                                  s
FIGURE 4 - OPTICAL GEOMETRY DEFINING THE SCATTERING VOLUME

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                                                                                9 = 30'
        5 = 150
u>
                                                                                                      q
                                                                                                      q
                                                                                                	q
                                                                                          (Microbeads) n
        9 = 150
                 FIGURE 5 - ANGULAR SCATTERING DISTRIBUTIONS FOR VARIOUS VALUES OF SIZE PARAMETER

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Rosensweig, Hottel and Williams  (1961) extended this
simplified expression to the signal  (current) produced
by the phototube which is given by:

     i.-I  /r*  «.                                  (5>

where
     I  is the phototube signal

     S  is the overall system sensitivity and is constant
        for .a given optical arrangement and alignment

     f* is given by    lim  —  and is defined as the average
                    vs —* °  s
        particle density contained within -the control volume.

     N  is the average number of particles contained in V


The desirable relation between I . S and f* is
                                5

     Is = Sf*                                           (6)


Rosensweig et al (1961) state that clearly V must be small.
However, decreasing V increases all noise levels of the sy-
stem.  Therefore an optimization is needed.  They also show
that if a point concentration is to be obtained from equa-
tion (5) the concentration profile must not have large curva-
ture.  These conditions are controlled by the geometry of the
optics and by the velocity profile in the medium.

The relation between the count from an electronic counter,
monitoring the phototube output, and the number of parti-
cles per unit volume can now be obtained.  Under the assump-
tion of homogenous flow, the total number of particles count-
ed is attributed to the passage of a frozen concentration
pattern through the scattering volume V .  The pattern passes
at a velocity U - the local mean velocity of the flow field.
The average time for one particle to pass through the scat-
tering volume is given as:
                                                       (7)

where

      b = diameter of the beam
     U  = stream velocity
                          14

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The length D/2 represents an average cross-sectional
length for the circular beam.  The time it takes  for
a length V /A  to pass through the scattering volume
j _        SB
is:

     V
      S  = At
     us
where
     V  =  scattering  volume
      S

     A  =  cross-sectional  area  of the  scattering
           volume  defined as L D, .

     L  =  the  length  of the volume  formed by the
           interception of  the solid angle and the
           beam.   (shown in Figure 4)

 If  the average number of particles  per unit scattering
 volume is  given by:


     r* =  £                                    (9)
where
      ,%/
      N   =  total number  of particles contained
           in V
               s

      V   =  scattering volume
      S
and the  total number of particles contained in the system
volume is  N then the particle  density  is given by:


      r   =  v                                   <10>

and for  homogenous  flow
         CV
      I- I                                    n-n
      v "~ v                                    *  '
           s

The number of counts per second is then given by the number
of  particles per unit scattering volume divided by the time
for one  scattering  volume to be convected through the volume.
In  equation form this is:
                         15

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    6  . r* v5                                         (12)
    0     At 5

where

    6  = count/second
    V  = Scattering volume
     s
or substituting for T * from equation 9 and for A t from
equation 8

    «  -I  v
But |s - |SSo

    6S = S ASU                                         (13)


For a desired count the number of particles and ultimately
the weight of the particles were determined by the relation-
ship expressed by equation 13.
           Resolution of the Scattering Volume

The length of the scattering volume may be determined dir-
ectly from the geometry of the optics.  The angle as is de-
termined by the diameter of the pinhole apertures which
limit the field of view of the photomultiplier tube.  The
angle 9 is the angle between the photomultiplier tube and
the incident beam.  These variables are all shown in Figure
4.  The equation that describes the dependence of the scat-
tering length upon the geometry is given by:

       _     sin oos        sin 
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.20 -•
.16 -•
.12
.08 --
.04 -
                      L
                       s
                      -- — versus ft

                      Ld
                                                          0 - 10
           .<  (SOLID ANCLE FORMED BY DETECTOR)
            s
          FIGURE 6 - VARIATION OF DIMENSIONLESS

               LENGTH WITH SOLID ANCLE u
                            17

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The effective length for transversing the test  section  is
longer than Ls by a Length equal to AL^ and AL2-   The lengths
AI« and AL2 are shown in Figure 7 and are given by:
     AL, =  b  tan  (9 + a)                                (15)
       1   2


     AL0 = °b  tan  (0 - a)                                (16)
       2   2

This total length is the dimension which limits the ability
to make measurements close to the wall.

The conditions that are necessary in order that the volume
be small are:

     a.  large values of Q (Max. = 90° )

     b.  small diameter pinholes

     c.  large distance between apertures

     d.  small distance between the center of the
         aperture and the beam

Equation 14 is derived neglecting the effects of refraction
at the walls of the test section.  This effect is generally
negligible provided angle a is very small.
                           18

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                            INCIDENT  BEAM
                                           PINHOLE
                                           APERTURE
FIGURE 7 - EFFECTIVE TRAVERSING LENGTH
                    19

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                      SECTION IV


          EXPERIMENTAL APPARATUS DESCRIPTION



The experimental apparatus may be divided into various
subsystems - the fluid flow system, optical system, parti-
cle measuring system, and the electronic system.


         Description of the Fluid Flow System

A schematic of the fluid system is shown in Figure 8.
The system consists of a plenum chamber, a reservoir, a
one-third horsepower centrifugal pump with a bronze head
and an Aqua-Pure water filter.  All piping used was made
of Polyvinyl Chloride  (plastic pipe) to insure that the
system remained as rust free as possible.  The plenum
chamber was made of Plexiglass and had dimensions of I1
x 1' x 2.5'.  The inlet section from the plenum to the test
section was constructed from a cylindrical Plexiglass piece
cut at 45° angles in such a manner that when it was reunit-
ed, it formed a bell shape inlet section for a square chan-
nel as shown in Figure 9.  The plenum chamber also had an
overflow weir that consisted of a 3/4 inch diameter pipe.
The reservoir was constructed from a fifty-five gallon
drum that had been treated to prevent rust.  The reser-
voir had four holes located in its bottom, leading to
valves 3, 4, 5, 6.  Valve No. 5 is used1 to help control
the amount of flow going to the reservoir from the con-
stant speed pump.  All four valves allowed the separation
of the reservoir from the rest of the system.  Valve 4 is
between the reservoir and the drain.  Valves 7, 8, 9, are
for further flow control.  They allow either complete,
partial, or no flow through the filter.  Valve 11 is to
control the weir draining rate and valve 12 is to control
the plenum draining rate.  The remaining valves (1, 2)
were to allow collection of a flowing sample from the test
region.

The test section located immediately downstream of the in-
let nozzle was made of Plexiglass and designed in such a
manner that it could be detached from this position and
interchanged with another section of the channel.  The
test section is shown in Figure 9.

The velocity profiles were measured with the device shown
in Figure 9.  The measuring instrument was a Pace differential
                           21

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Sampling
bypass
 (1)

J+
        (6)
                reservoir
                    (3)
                                                plenum
                                       filter
                                                   (7)
                                                   a>
                                                               (11)
                                                             orifice
                                                             meter
                                                         drain
             FKJURE 8 - SCHEMATIC-FLUID FLOW SYSTEM
                                22

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(1)   Test section
(2)   Inlet nozzle
(3)  Pilot tube with
    traversing device
                 Photomultiplier tube
  FIGURE 9 - INLET SECTION AND TKST
               23

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transducer and the probe was made  from  0.035"  I.D.  wire
tubing.  The traversing mechanism  used  a micrometer to
position the probe.  The electronics used  for  velocity
measurement are also shown  in Figure 10.   The  electron-
ics consisted of a carrier  demodulator  and a VIDAR  digital
voltmeter with external controls- allowing' timer averaging
of the velocity profile.
                    Optical System

The optical  system consisted of a helium-neon  laser,  a
photomultiplier tube, a narrow band filter, and  two pin-
hole apertures.  The system is as shown in Figure  11.
This arrangement was chosen as a compromise between scat-
tering volume  size and signal to noise ratio.  In  general
as the angle between the beam and the photomultiplier was
decreased, the scattering volume length increased  and the
signal to noise ratio decreased reaching a minimum at the
zero degree  angle.  The prism shown in Figure  11 was used
just to change the direction of the beam and has no ef-
fect on the performance of the overall system.  The wave-
length of the  laser and the narrow band filter used was
6328 A.  The apertures were approximately 310  microns in
diameter.                       •'>'

To aid in understanding the operation of the system and
the purposes of each component a,detailed explanation is
presented.  A uniform beam is incident upon the test sec-
tion normal to the flow direction.  The normal condition
was chosen to minimize any aberrations due to  refraction.
The test section was chosen to have flat walls to  elimin-
ate the need for a compensator box to compensate for the
effect of curvature as was found necessary in  work done
in internal flows with a Doppler,system by Denison (1969).
A system that involved the use of a lens that  would focus
the collimated beam down to a particular point was tried.
It was discovered that with such a system, it  would be
necessary to refdcus the system at each point  in the flow
field as the concentration gradient was taken.  This was
due to the change in optical path and consequently the
change in effective focal length of the lens.

If small particles are seeded into the flow system, they
will scatter radiation in all directions.  The pinhole
apertures that are placed between the photomultiplier
tube and the flow field,  together with the geometrical
relationship between the incident beam and the photomul-
tiplier tube, define the cone that intercepts  the beam.
The common region between the cone and the incident beam
defines the scattering volume.  The particles  entering the
scattering volume will scatter light in all directions,
                           24

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(l)   External timer        (5)   Carrier demodulator
(2)   External start and : stop (6)  Probe and transversing
(3)   Vidar digital voltmeter      mechahism
(£)   Calibration mechanism   (7)  TransduceU
  FIGUKE  10-  VELOCITY  MEASUREMENT INSTRUMENTATION
                     25

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(1)   Laser

(?)   Prism
(3)   Apertures  ani  b
     filter
CO   Photomultiplier
              (5)   Laser  power
               11  -  OPTICAL
                 26

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                                          I
some of which  is  received by the photomultiplier tube.
The narrow band filter, which is placed directly in front
of the photomultiplier  tube,  limits  the wavelength of
light that reaches  the  tube.   Therefore,  only radiation
that is the  same  wavelength  as the  filter bandpass ex-
cites the tube.   The  signal  received by the tube is then
proportional to the scattered radiation from the parti-
cles, from scattering due to turbulence of  the water
 (Gurvich,  (1968)) and from background  radiation from
the room within the filter bandpass.   Both  of the latter
effects were found  to be negligible  in this study.

The entire optical  system was mounted  on a  large alumin-
um plate which was  in turn mounted on  a lathe bed in such
a manner as  to allow  the scattering  volume  to be traversed
across the flow.  Mounting the optics  in this manner limit-
ed vibrations  and allowed the whole  optics  to move  normal
to the section where  concentration gradients  were taken.
                     Electronic  System

 The  electronic  system used  in  the  analysis of  the  signal
 from the photomultiplier  tube  is shown  in Figures  12 and
 13.   This  system  consisted  of  an oscilloscope, bandpass
 filter, an a.c. amplifier,  an  oscillator, a visicorder
 and  an  electronic counter.

 The  signal from the photomultiplier tube was first chan-
 nelled  to  the oscilloscope,  and  simultaneously to  the a.c.
 amplifier  from  which it entered  the bandpass filter.  The
 signal  was amplified to enable it  to trigger the electron-
 ic counter.  The  amplification factor was ten  times the
 input signal.   The bandpass  filter was used to improve the
 signal  to  noise ratio.  After  passing through  the  bandpass
 filter, the  signal was simultaneously sent to  the  oscillo-
 scope and  to the  electronic  counter.  Since the signal had
 the  appearance  of shot noise,  the  filtered and unfiltered
 signals were observed on  the oscilloscope to insure that the
 bas±c- form of the signals was  not "changed.

 The purpose  of  the oscillator  was  to serve as  a standard
 when  in connection with the  oscilloscope, by which the
 electronic counter could be  calibrated for sensitivity
 versus  accurate count setting.

 The visicorder was used to double  check the effect of the
bandpass filter,  to compare  the  intensity of light received
 from  the different types of  particles used, and also to
 check on the count received  from the counter at various
 locations.
                          27

-------
            photorcultiplii
            tube
NJ
00
             oscillator
                                                  filter
                                                                     amplifier
O
                                                                    oscilloscope
                             FIGURE 12 - SCHEMATIC OF THE ELECTRONIC SYSTEM USED

-------
 (1)  Vifccorder          (5)
 (2)  Oscilloscope
 (9)  Narrow band filter (6)
 CO  Electronic counter (?)
Photomultiplier tube
voltage power supply
Oscillator
A.C. anplifier
KIIURE 13- ELECTONICS USED IN SIGNAL ANALYSIS
                   29

-------
                Particle Measuring System

This system consisted of only a microscope and an analyti-
cal balance.  The size distribution of the particles was
determined by measuring a sample of the particles used
under the microscope.  The microscope at high magnifica-
tion will give the diameter to  +  1 micron.   It was  origin-
ally proposed that size determination be done optically.
While the theory was sound, the system would involve an
extensive calibration.  This was not considered feasible
for the scope of the present study.  Separation of  the
particles by size was also investigated.  The results of
this investigation showed that only for gross differences
in diameter or properties is separation by size feasible.
Particles that were obtained from the manufacturers though
not uniform in diameter, represented the best practical
size separation that is presently available.

The analytical balance was used to measure the amount of
particles that were to be added to the fluid system.  The
balance was accurate to 1/100 milligram.  This system is
shown in Figure 14.
         Average Concentration Measuring Device

In order that values obtained from the light scattering
experiments could be verified, a Coulter counter was used.
The Coulter counter works on the principle that the pre-
sence of particles passing through a small orifice changes
the electrical path through the orifice.  This device is
thereby able to determine the particle size and concentra-
tion that is present in a small sampling vessel.

Concentration measurements from this device were determined
from small samples taken at each concentration level that
was used.  The samples were taken with a bypass arrange-
ment from the^ reservoir that can be seen in Figure 8 and
was controlled by valves (1)  and (2).

The results obtained from this instrument proved to be un-
reliable for the fluid (deionized water) and concentrations
used.
                         30

-------
(1)   Microscope
(2)    Analytical Balance
       FIGURE Hf - PARTICLE SIZE AND NUMBER
               MEASUREMENT SYSTEM
                   31

-------
                        SECTION V

                MEASUREMENTS AND RESULTS


               Particle Size Measurements

The particle size was determined by measurement with a
microscope.  The standard deviation and average were
calculated from the following equations:
     -
     D =   S  f. x.
          d=l
                            (17)
^ - D)2
                                                   (18)
where

     N = Number of particles sampled

     x.= Diameter of a given particle

     f = Frequency of occurrence for that particle dia-
         meter

     T = Standard deviation of the particle diameter

     5 = Average diameter

The results obtained are given in the following table:


                         Table I
TYPE OF PARTICLE
Lycopodium Spores
Microbeads
Dow Beads
D
31.66 p,
34.3 ji
45.4 |a
T
2.23 p
4.74
8.9
n
i Unavailable
1.51
1.587
                         33

-------
The frequency of occurrence of sizes for Lycopodium  and
for microbeads can be found in Figures 15 and 16 »  The
density and other properties of Lycopodium were  taken
from Rouhiainen and Stachiewicz  (1970) .  The other par-
ticle properties were taken from manufacturer's  data and
can be found in Table II.
                        TABLE II

            PARTICLE SUPPLIERS AND PROPERTIES
MANUFACTURER
    OR         MATERIAL
  SUPPLIER
                                          INDEX
                            DIAMETER       OF     SPECIFIC
                                      REFRACTION  GRAVITY
Carolina
Biological
Supplies

Dow
Chemical
Microbeads
Minnesota
Mining
Reflective
Products
             Lycopodium
             Spores
             Styrene
             divinyl-
             benze

             Soda-lime
             silca glass

             Glass
32.2
34.3
1.587
            1.51

            1.5
           0.621
1.05
           1.5

           1.5
                  Velocity Measurement

The measurement of the velocity was done prior to any of
the concentration runs.  The nozzle and flow field is
shown in Figure 16.  The mean velocity in the test sec-
tion was found to be 8 feet per second.  The correspond-
ing Reynolds number based on the hydraulic diameter is 5.76
x 10^.  Velocity profiles were found to be flat over most
of the test section in both horizontal and vertical direc-
tions.  A typical profile is shown in Figure 17.
               Concentration Measurements

The particles were injected into the plenum chamber and
                          34

-------
                                  f versus x.
D - 31.66
T -  2.23 u
             24   25   26  27   28   29   30   31    32    33   34    35
                   DIAMETER x  , MICRONS
FIGURE 15 - FREQUENCY VERSUS DIAMETER FOR LYCOPODIUM SPORES
                              35

-------
  100..
o
u

tn
O
w
S3
   80
   60.
   40
   20"
D - 34.3 p

T -  4.74p
                                   f versus x
     10
  15
20
25
30
35
40
                       DIAMETER x  , MICRONS
      FIGURE 16 - FREQUENCY VERSUS DIAMETER FOR MICROBEADS
                               36

-------
     1.0 ..
  w
  S
  o
  H

  H
  X
  O
  M
  W
  as

  o
  M
  H
      ,8 --
      ,2 ..
                           y/h vs. U/U
           X   U - 7.87 ft/sec

                   vertical


           0  U  = 8.145 ft/sec
                   horizontal
                                                       i
                                     °d
                                      6

                                      I
                                     "O
                                     b
                                                  i0
                                                    o
        0.0
.2
,4
.6
1.0
          II                                         FT/SFC
          --, RATIO OF VELOCITY TO AVERAGE VELOCITY,
FICURE 17 - DIMENSIONLESS DISTANCE VERSUS DIMENSIONLESS VELOCITY
                                37

-------
allowed to disperse for one hour to one and one-half
hours before any data was taken.  This time was deter-
mined experimentally as the time delay necessary for a
consistent count.  The procedure for data collection
was as follows:

     1.  Check to insure the following equipment
         was turned on at least one-half hour be-
         fore a run.

         a.  Oscilloscope
         b.  High voltage power supply
         c.  Visicorder oscillograph
         d.  Laser
         e.  Electronic Counter (set at maximum
             sensitivity)

     2.  The inner wall of the test section was
         located.  (The location of the wall was
         determined by the scattering pattern at
         the interface between the wall and the
         air.

     3.  Dial positioner was zeroed.  (This dial
         was used to determine step size of tra-
         verses of the scattering volume in the
         test section)

     4.  All room lights were turned off.

     5.  Readings of the count per second were
         obtained at positions spaced 0.10 inch
         apart.

     6.  Visicorder oscillograph and count per
         second readings were obtained at posi-
         tions 1, 4 and 7 which correspond to
         the two wall regions and the center of
         the test section.

     7.  Electronic counter sensitivity was varied
         from a voltage threshold of 55 m.v. to
         104 m.v.

     8.  The concentration level was changed.
         (For lycopodium spores a wetting agent
         must be used.   For this investigation
         Industroclean cleanser was added to the
         system.)
                         38

-------
   - 9.  Electronic Counter was set back to maxi-
         mum sensitivity  (55 m.v.).

    10.  Steps 2-19 were repeated.

The data for the point concentration measurements were
taken as an arithmetic average of the values taken at
the point.  Typical distributions for each type of par-
ticle run is presented in Figures 18-23 .
                 Coulter Counter Results

Typical results obtained for a few of the runs from the
Coulter counter are presented in Figures 24 and 25-  T^6
Coulter counter proved to be a poor choice of a check for
the results obtained from the scattering system.  The
primary reason is that the Coulter is extremely sensitive
to contaminants in the water used.  The Coulter counter
would give high counts for clear water and give counts on
the -same order of magnitude for samples obtained from the
particulate system.  In fact, in some cases higher counts
were obtained for clear water (uncontaminated deionized
water).  The scattering system did not show this sensi-
tivity to clear water contamination; however, if it had
a zero level could have been set and exact counts could
have been obtained by substracting this known zero level
from obtained values.
                       39

-------
O - ix
D - 2X
A • 3X
25.
20.
•0
S
8 is.
U4
en
PS
w
Pi
g
8
5.

IX - 7.76 x 10* |S«i£ia
A
""A A A

••••>
n n n o n a
n n n 	 __n_
O u w
—
i I I i II 1
123 45 67
               POSITION
FIGURE 18 - OBSERVED  COUNT PER SECOND
   VERSUS POSITION  FOR DOW BEADS
                   40

-------
        O
   35
   30
   25
   20
8  15
w
w
PL,
8
   10
a
                           TT
                                    O
                                     O
                                                                O
                   -D-
0-8X


a, 4x


A   2X


O   IX

IX - 2.02 x 1,05 particles
                 -


                     CL
TT
                                                                A
                  O
                                     i
         12345



                        POSITION



            (DISTANCE BETWEEN POINTS = 0.10")
       FIGURE 19 - OBSERVED COUNT PER SECOND VERSUS

             POSITION FOR LYCOI'ODIUM SPORES
                             41

-------
     25.0
Q
S5
8
Ul
I
     20.0
     15.0
     10.0
      5.0
          A
          O
          a
          IX
   position //7

   position #4

   position //I
   1  milliter of
   10% concentration
                                                          I
                      IX
2X
3X
                         CONCENTRATION
            F1CURE 20 - OBSERVED COUNT PER SECOND
             VERSUS CONCENTRATION FOR DOW BEADS
                              42

-------
o
u
w
to

PS
o
u
      30
      25
      20
15
     10
               position //I


               position //4


               position //7


          IX = .0161 gins
                  2X
                      4X
6X
8X
10X
                       CONCENTRATION
           FIGURE  21  - OBSERVED COUNT PER SECOND

       VERSUS CONCENTRATION  FOR LYCOPODIUM SPORES
                               43

-------
o
u
w
tn
W
o.
o
u
      10
       5 __
40
                    60         80         100


                COUNTER SENSITIVITY  (mV)
120
          FICURE 22 - OBSERVED COUNT PER  SECOND

            VERSUS SENSITIVITY FOR DOW  BEADS
                             44

-------
O

J3
(O



fi
O
u
     25
     ~~    O * point //I



          *-J • point #4



          A - point #7
     20
15
     10
                                                              A
         0
               25
50
75
100   112.5
                COUNTER SENSITIVITY,  (raV)




          FIGURE 23 - OBSERVED COUNT  PER SECOND

        VERSUS SENSITIVITY FOR LYCOPODIUM SPORES
                               45

-------
SO
 I
 o
 o

 o
 M

 g
 O


 Si
 (X,
 8
       2.5
2.0
       1.5
1.0
        .5
        .2
                            J_
                                I
                                             IX -  10 ml of 1%

                                             concentration
                   IX        2X       3X



                        CONCENTRATION
                                         4X
5X
         FIGURE 24 - TYPICAL COULTER COUNTER COUNTS

             VERSUS CONCENTRATION FOR DOW BEADS
                              46

-------
xO

 o
 en
 w
 I
 u
 u
 OS
 w
 eu
      12   -
      10
       8
                                             IX - 0.0161 gma
                  IX         2X        3X



                       CONCENTRATION
4X
5X
        FICUKG 25 - TYPICAL COULTER COUNTER COUNTS

           VERSUS CONCENTRATION FOR LYCOPODIUM
                                47

-------
                     SECTION VI

                DISCUSSION OF RESULTS
The primary results obtained are presented in Figures
18 through 24; they illustrate typical data.  Figures
20 and 21 show that a change in concentration results
in a corresponding change in counts per second and is
expressed by a linear relationship for moderate concen-
tration levels.  It can be seen by comparing Figures 18
and 19 (which show the response of Dow beads and lycopo-
dium spores) that similar concentrations levels give
similar counts per second.  Figures 18 and 19 also show
that the concentration profile, like the velocity pro-
file/ is flat across the test section for moderate con-
centrations.  At high concentration levels a noticeable
assymetry in the profile was observed.  The exact ex-
planation for this effect is not known.  Figures 22
and 23 show the response of the system to varying de-
grees of sensitivity.  These figures show that a corres-
ponding response to a concentration change was obtained
at all levels of sensitivity tested.

Figures 24 and 25 show the response of the Coulter count-
er to various concentrations.  For lycopodium spores the
response is almost linear; however, for dow beads the
response was nonlinear.  It was concluded from these
results and attempts at calibration, with this fluid and
these concentrations levels, that the Coulter's results
were not accurate.
                         49

-------
                    SECTION VII

          DISCUSSION OF MEASUREMENT ERRORS
The data presented in the previous chapter illustrate
typical experimental results obtained with the system.
Due to the nature of the experiment rather large varia-
tions were observed in some of the measurements.  The
source and magnitude of these variations is discussed
here.
                 Effect of Alignment

One of the disadvantages of this system is the sensi-
tivity to alignment.  The amount of light received is
directly related to the angle between the detector and
the incident beam.  One assumption that has been made
is that the detector and the beam are in the same plane
and that the pinholes and the beam are aligned.  Devia-
tions from these conditions can greatly effect the re-
sults obtained at the counter.  An example of this is
seen by comparing the results shown in Figures 18 and
26.  For the same number concentration different counts
per second were obtained.  Consequently, the actual
value of the count per second is not significant - only
the relative effect of changing the number concentra-
tion for a particular instrument alignment can be mea-
sured.
          Concentration Measurement Error

The only error presented here is the error in consistent
counts.  Figures 27 and 28 show the variation in concen-
tration profile and system response respectively.  These
figures were obtained ,by taking the largest deviation
from the average.  These curves show that the system re-
sponse was very good because the error in the count shown
could be expected just from the nature of turbulent flow.


         Particle Suspension Considerations

To avoid the effect of particles separating from the flow
and becoming attached to some portion of the system, all
runs were made in one continuous sweep.  The particles
were assumed to remain suspended throughout the run.  The
effect of particles separating from the system was noted
when particles slightly heavier than water were used.  For
                          51

-------
   300.
   250.
   200.
8  150.
w
w
fx.


H
o
u
   100.
    50.
                             3        4



                            POSITION
                                                  IX - 2.02 x 10J particles


                                                 •  - 16X


                                                     - 8X

                                                       Clear  water
          FIGURE 26 - OBSERVED COUNT PER SECOND VERSUS

      POSITION FOR LYCOPODIUM SPORES (DIFFERENT ALIGNMENT)
                                52

-------
                                                      =  Lower  limit


                                                  A  -  Upper  limit



                                                  C.'  »  Average  values
g
o
u
U4
U4
o
o
    0
                         3         4



                           POSITION
         FIGURE  27  -  OBSERVED COUNT PER SECOND VERSUS

                POSITION'UPPER AND LOWER LIMITS
                              53

-------
    30
    25
    20
1   IS
a
8
    10
                       A *  Upper  limit
                       O *  Average Value
                       D *  Lower  limit
            IX
3X
5X
7X
9X
                     CONCENTRATION
      FIGURE 28 - OBSERVED COUNT PER SECOND VERSUS
         CONCENTRATION UPPER AND LOWER LIMITS
                            54

-------
these particles the count first steadied and then rapidly
began to decrease.  The lighter particles seemed to remain
suspended in the fluid rather well.  This was determined
by allowing the system to run for several hours and then
rechecking the count/sec of particles.
                          55

-------
                    SECTION VIII

                  ACKNOWLEDGEMENTS
The reported work was the result of the Master of
Science research of Mr. Charles H. Tinsley, Jr.
Professors Victor W. Goldschmidt and Warren Stevenson
acted as supervisors of his work.

The support of the project by the Water Quality Office
Environmental Protection Agency, and the help provided
by Mr. George Ditsworth, Project Representative is
acknowledged.

The assistance of the staff of the School of Mechanical
Engineering and its Ray W. Herrick Laboratories during
the final stages of the work reported is also gratefully
acknowledged.
                          57

-------
                      SECTION IX

                      REFERENCES
Anderson, T.B.  and  R. Jackson.   "A Fluid Mechanical
Description of  Fluidized Beds."   Industrial and Engi-
neering Chemistry Fundamentals.   Vol.  8 pp. 137-144
February 1969.

Becker, H.A., H.A.  Hottel  and G.  Williams.  "On Light-
Scatter Technique for the  Study  of Turbulence and Mix-
ing."  Journal  Fluid Mechanics,  Vol. 30, part 2, pp.
259-284.                                         ^

Born, Max and Emil  Wolf.   Principles of Optics.  Per-
gamon Press, 1959.

 Chuang, Strong  C.   "Turbulence Diffusion of Small Gas
Bubbles in an Axi-Symmetric Water Jet."  Ph.D. Thesis
School of Mechanical Engineering, Purdue University,
1969.

 Denison, E.B.   "Pulsating  Laminar Flow Measurements
with a Directionally Sensitive Laser Velocimeter."
Ph.D. Thesis, Purdue University,  1969.

Fischer, M.J. and F.R. Kause.  "The Crossed-beam
Correlation Technique."  Journal  of Fluid Mechanics,
Vol. 28, part 4, pp 705, 1967.

Goldschmidt, V.W. and S. Eskinazi.  "TVo Phase Tur-
bulent Flow in  a Plane Jet."  Journal  of Applied
Mechanics, Vol. 33  Series  E, No.  4, December,  1966.

Green, H.L. and W.R. Lane.  Particulate Clouds, Dust
Smokes and Mist.  D. Van Nostrand Company, Inc. Chapter
4, 1957.

Gurvich, A.S.   "The Determination of Turbulence Char-
acteristics from Light Scattering Experiments".  At-
mospheric and Oceanic Physics, Vol.4,  No. 2, 1968.

Hanesian, D. and A. Rankel.  "Elutriation from a Mul-
tisize Particle Fluidized  Bed."   Industrial and Engi-
neering Chemistry Fundamentals, Vol. 7, No. 3, August,
1968.

Hino, M.  "Turbulent Flow  with Suspended Particles."
American Society of Civil  Engineers Proceedings, Vol.
89, Journal of  Hydraulics  Division, Hy. 4, July 1963.
                        59

-------
Householder, Michael K.  and V.W. Goldschmidt,   "Tur-
bulent Diffusion on Small  Particles  in  a  Two-Dimension-
al Free Jet,"  Technical  Report FMTR-68-3  School of  Civil
Engineering, Purdue University, Sept. 1968.

Lee, J.B.   "Turbulent Diffusion of Particles  in Plane  and
Circular Jets."  M.S. Thesis, Purdue University, School  of
Mechanical  Engineering,  January 1970.

McGill, D.R.   "Scattering  Experiments."   Development of
Four Experiments for Applied Optics  Laboratory.  M.S.
Thesis, Mechanical Engineering, Purdue University,  1968.

Moder, J.J.  and D.A. Dahlstrom.  "Fine Size, Close-Specific-
Gravity Solid  Separation with Liquid-Solid Cyclone."   Chemi-
cal Engineering Progress,  p. 75, 1952.
                                                   ,- ••
Morse, H.L., B.J. Tullis,  W.R. Babcock and H.S.  Seifert.
"Development,  Application  and Design Specifications of a
Laser-Doppler  Particle Sensor for the Measurement of
Velocities  in  two Phase  Flow Rocket  Exhaust."  Volume  I,
Sudaar, No.  356, p. 56.

Perry, R.L.  and S.M. Henderson.  Agriculture Process Engi-
neering, pp. 184-189, New  York, Wiley, 1955.

Peskin, D.L. and P.S. Baw.  "Solid Density Distribution in
Gas-Solid Pipe Flow."  Technical Report No. 108-ME-F NYO
2930-6.

Petrie, J.C. and D.E. Black.  "Improved Air Distributor
Caps for Fluidized Beds."  Chemical  Engineering  Progress,
Vol. 62, No. 3, March, 1966 p. 82.

Phelps, Jean P. "Particle  Size Determination Using A Laser
Light Transmission Technique." M.S.  Thesis, U.S. Naval Post
Graduate School, March 1968.

Rosensweig, R.E., H.C. Hottel and G.C. Williams. "Smoke-
Scattered Light Measurement of Turbulent Concentrations
Fluctuations."  Chemical Engineering Science, Vol. 15,
pp. 111-129, 1961.

Rouhiaineri, P.O. and J.W.  Stachiewieg.  "On the Deposi-
tion of Small  Particles  from Turbulent Streams."  Journal
of Heat Transfer, Vol. 92, Series 1,  February 1970.

Scholz, J.T. and D.R. Uhlmann and B.  Chalmers.   "Elutria-
tion Particle  Separator."  The Review of Scientific Instru-
ments,  Vol. 36, Number 12, pp. 1813-1816,  December 1965.
                        60

-------
Sinclair, D.  Handbook on Aerosols.   (Washington, B.C.:
U.S. Atomic Energy Commission) p.  84,  1950.

Soo, S.L.  Fluid Dynamics of Multiphase  System,. Blaisdell
Publishing Company, Chapters 1 & 4,  1966.

Soo, S.L., G.J. Trezek, R.C. Dimick  and  G.F. Hohnstreiter.
"Concentration and Mass Flow Distributions in a Gas-Solid
Suspension."  Industrial and Engineering Chemistry Funda-
mentals, Vol. 3, p. 98, May 1964.

Van de Hulst.  Light  Scattering by Small Particles, Wiley
& Sons New York, N.Y., 1957.

Wallis,  G.B.  One Dimensional Two  Phase  Flow, Chapter 8,
p. 175,  1969.

Zenz, F.A.  Fluidiza.ti_on of Particle Systems. Reinhold,
New York, N.Y., 1960.
                           61

-------
                      SECTION X



                 GLOSSARY OP SYMBOLS





A    cross-sectional area of scattering volume defined as L a
                                                           s b


D    average particle diameter



D.    diameter of beam




f    frequency of occurrence for that particle diameter



g    32.2 ft/sec/sec



I    scattered light intensity



I    phototube signal
 S
k    a 'X
 O   4lT



L    length of the volume by interception of solid angle a
 S                                                        S



L    stopping distance for impingement separators
 S



L    free fall travel distance in a cyclone separator
 Vv



mV   millivolts



N    total number of particles added to water



j,    average number of particles in Vg




NS   number of times particle encircles cylindrical portion

     of cyclone separator



N    number of particles sampled



n    real part of refractive index



n1   relative index of refraction



n    number of scatterers



p    parameter determined experimentally used to determine

     light scattered
                           63

-------
                        2TTr
   q     size parameter —jj—



   r     radius of particle



   S     overall system sensitivity




   U     stream velocity



   V     total volume of fluid



   V     scattering volume
    S



   Vic   inlet velocity to cyclone separator




   V     particle velocity




   V.,V  free fall or terminal velocity of one particle
    *tz  G



   x.     diameter of a given particle





   a'     absorption coefficient



   a     solid angle viewed by detector




   F *    average number of particles per unit scattering

         volume



   F      average number of particles per unit volume



AL,&AL_  additive terms to L  for traversing length
  J-   £t                     S



   5     count/sec



   9     angle subtended between the beam and the detector



   X     wavelength of the incident beam



   p     density of particle





   p..     density of fluid





   T     standard deviation of particle size range
                            64

-------
                     SECTION XI

                      APPENDIX
In many experimental investigations, it is necessary
to have a supply of uniformly sized particles.  Parti-
cles obtained from various manufacturers, in a range of
10 to 100 microns, do not adequately meet the uniform
size specifications.  Examples of the types of variance
encountered are given in Table 1.  The objectives of
this appendix are to present a survey of the various
techniques suitable for separation of micron range
particles by size and to examine the most practical
system.
                Filtration Separators

Filtration separators are usually made of cloth or of a
porous element.  This type of separator is commonly used
in conjunction with the removal of a particulate from a
gas stream.  Filter efficiency is dependent on the length
of time in operation.  Filters start at a low efficiency
but increase to values as high as 99.9%.  After a short
period of operation, the pores become elogged from im-
pingement, adherance of fines or by blockage owing to the
larger-sized fractions in the dust being separated.  The
filter will then build up a "precoat" layer on its up-
stream surface and thus the precoat actually serves as a
high efficiency filter bed.

Sieving is another form of filtration separation.  Siev-
ing is a method used to separate the fine particles from
the course ones by means of nested screens.  The sieving
screens are mounted on a metal rim to form cylindrical
pans.  Such pan_s, each of different screen size, are
nested one atop another with the finest at the bottom and
the coarsest at the .top.  The material is placed on the
top and then the screens are shaken.  The difference be-
tween the pans of the nest represent a certain size range
of the material .separated.


                Impingement Separator

Impingement separators depend on the inertia of the parti-
cle.   The carrier fluid flows the streamline around an ob-
ject which the particle cannot immediately follow,  due to
the particle momentum.  The particle is, therefore, decel-
erated to zero velocity by striking the object.  After
                        65

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striking the object, the particles are held into place
and collected - usually at shut down.  Collection can be
made by counter current flow or by centrifugal force im-
parted on the carrier gas.  Zenz  (1960) gives a theoretical
explanation of this type of separator.  The important para-
meter is the stopping distance  (L_).  The stopping distance
is a function of the particle velocity, free fall velocity,
and both particle and fluid densities.  For a spherical parti-
cle the stopping distance is given by:

      Ls = "P  PP  Ve                                  (a)
where
      v  = particle velocity

      v. = free fall velocity - v
       T—                         S
      p  = particle density

      pf = fluid density

      g  =32.2 ft./sec/sec
                   Cyclone Separation

The cyclone or centrifugal separator is a device utiliz-
ing radial acceleration for separation of particles suspend-
ed in a gas stream.  It consists of an outer cylindrical-
shell and a cone attachment, and is so arranged that the
dust-laded gas enters tangentially.  This causes a vortex
of gas which ascends up the cone and finally ascends to an
outlet concentric with the outer cylinder.  The particles,
however, are impinged against the curved wall and swirl in
a downward spiral path due to the effect of an outward
centrifugal force imparted by the momentum due to inlet
velocity and the force of gravity.  The minimum diameter,
of the particles separated by this process, is given as a
function of fluid dynamic viscosity, free fall velocity,
fluid inlet velocity, and the difference in particle and
fluid densities.

In order to obtain the function which determines the dia-
meter of the particles to be separated, the distance traveled
by the particle laden gas must be determined.  This distance
is simply 2rrr N  of the cylindrical portion of the cyclone.
The time that it takes the gas to travel this distance is
t  =  2rrr N_A,   where V.  is the inlet velocity to the
            '  ic
                         66

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cylindrical portion of the  separation.  This  also  is the
maximum time allowed for the particles  to travel the dis-
tance LW.  This is given by:

                     .                                ,  %
                     zc                               (b)
        VV. = 2rrr N /V
         t      c s
The terminal velocity can be determined from an equation
given in a succeeding section if the drag  force is com-
puted by Stoke 's law for a centrifugal field.  The terminal
velocity is then given by:

     Vt = 9Dp(Pp - pf)/18 nf                          (c)


Substituting and solving for D  , the following is
obtained:                     "


     Dp=    9
                   Gravity Separator

Gravity settling chambers are the simplest type of parti-
cle-collection equipment.  The principle of operation is
that the fluid velocity is reduced below the free falling
velocity of the particle.  This allows the particles to
settle from the carrier fluid by the influence of gravity.
The rate at which this occurs is dependent upon both fluid
and particle properties.  For similar shapes, the settling
rate (free fall or terminal velocity) becomes dependent
only upon the characteristic length usually the hydraulic
diameter.  In Wallis  (1969) a derivation and also the
correlation are given for the terminal velocity.

Any expanded section in line can constitute a gravitational
settling chamber, however they are usually a long, empty,
horizontal vessel or a long vertical cylinder.  For the
horizontal vessel, the basic idea is to allow the particle
to travel a vertical distance in free fall in less time
than it takes the carrier fluid to flow from inlet to outlet
of the settling chamber.  For the case of equal densities but
different sizes the larger particles will fall out first and
therefore the length of the chamber determines which diameter
particles will settle.  The cylinder settling chamber consists
of a stagnant or very slow moving fluid in which the particles
are dropped.  The time at which a certain diameter particle
reaches a predetermined depth can be determined thereby al-
lowing a known range to be collected.
                          67

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                      Entrainment

Entrainment may be defined as the carry-over of the
particle by the fluid, from the particle bed to and
through the dispersed phase.  The rate of entrainment
depends on factors that involve the apparatus, charac-
teristics of the solid and fluid, for all of these.
The entrainment process can be described in terms of the
free fall or terminal velocity of the particle.  When
the fluid velocity exceeds the velocity of the free fall
of the particle, the particle is carried by the fluid
until either the particle is carried completely from
the column or the particle forces exceed the momentum
of the particle and it returns to the bed.  Unfortunately,
the entrainment rate cannot be modeled by the terminal ve-
locity alone, other effects such as the throwing up of
the particles by the bursting action of the gas at the
particle bed and the concentration of the particles are
important.  Since the entrainment rate is dependent upon
free fall velocity it also allows particle separation by
size.
                      Conclusion

     The methods surveyed were:

           (1)  Filters

           (2)  Sieves

           (3)  Impingement Separators

           (4)  Cyclone Separators

           (5)  Gravity Chambers

           (6)  Entrainment Columns

Of these methods filters do not prove adequate because of
the nature of their operation.  Filtration is essentially
a catch all operation.  Sieving is used by most of the
manufacturers and if this method was chosen no finer dis-
tribution could be obtained.  Impingement separation while
theoretically possible is experimentally infeasible because
it would require a test program for different types of
collector designs.

Gravity separators are useful only when all particles are
to be separated or when the densities or size are widely
                          68

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  different.   Even when the above conditions are satisfied,
  collection  of the particles by the different sizes is
  difficult.   Entrainment was chosen as the more practical
  because  it  allows easy collection and because it can be
  coupled  with either cyclone, filter or sedimentation
  chambers.   The cyclone separator is thought to be the
  best  separator to couple with the entrainment bed because
  it gives a  second chance at size separation.  Closer examin-
  ation reveals that for particles with diameters around 100
  microns  free fall velocity is approximately 0.43 to 1.07
  ft/sec.   However, to separate particles with 4 (j, range
  results  in  air velocity control as being less than .01
  ft/second.   It was concluded that for the particle size
  separation  needed, adequate controls were not available.
^U-S. GOVERNMENT PRINTING OFFICE: 1974 546-319/392 1-3    69

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  SELECTED WATER
  RESOURCES ABSTRACTS

  INPUT TRANSACTION FORM
                             3.  Accession No.
                             w
  4.  Title

 TURBULENT DIFFUSION  IN LIQUID JETS:  PART I
  7.
                                                                   4. ^effotraltt!' ffrg&lsxaitat  '
                                                                     • Reports? &,
 Charles H. Tinsley,  Warren S. Stevenson & Victor  W.  Goldschmi'dt
  9.  Organization
                Engineering Experiment Station
                School  of Mechanical Engineering
                Purdue  University
                .Lafayette. IN 49707
                            10.  Project No.

                                16070 DEP
                            11.  Contract/ Grant No.

                                16070 DEP
                            13.  Type ol Report and
                                Period Coveted
  is. .supplementaryNote* pARj j.IS SUBTITLED:  Measurement of Particle Concentration by a
 Light Scattering  Probe.   Environmental Protection Agency Report number 660/3-74-004«i,
 March 1974
  16.  Abstract       .             •

 A technique for measuring particle concentrations  in turbulent flows was  investigated.
 This technique is the measurement of the light  scattered from an incident beam by the
 solid contaminants present.

 The results show  that for moderate concentrations  the scattering system gives
 proportional  increases in  count to increases in particle concentration.   The
 limitations of this system are the signal to noise ratio and the condition of
 singular scattering by the particles.

 Suggestions on refinements on the correlation technique used are made and observed
 phenomena which require further investigation are  discussed.
  17a. Descriptors


 Equations,  Instrumentation, *Particle Size,  Suspension, Turbulent Flow



  17b. Identifiers

 Lasers, Light  Scattering* * Particle Concentration, * Particle Size Measurement
  17c. COWRR Field & Group  08 B
  18.  Availability
                                            «. .
                 Send To:
                 WATER RESOURCES SCIENTIFIC INFORMATION CENTER
                 U.S. DEPARTMENT OF THE INTERIOR
                 WASHINGTON. D. C. 2O24O
  Abstractor   c  D
| institution Environmental  Prnt.pr.t1nn Aqpnry
WRS1C IO2 (REV. JUNE 1971)

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