United States
Environmental Protection
Agency
Environmental Sciences Research
Laboratory
Research Triangle Park NC 27711
EPA-600 2-80-023
January 1 980
Research and Development
Cross-Country
Urban and Rural
Measurements of
NO. and SO*

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                  RESEARCH REPORTING SERIES


 Research reports of the Office of Research and Development, U.S. Environmental
 Protection Agency, have been grouped into nine series. These nine broad cate-
 gories were established to facilitate further development and application of en-
 vironmental technology. Elimination of traditional grouping was consciously
 planned to foster technology transfer and a maximum interface in related fields.
 The nine series are:

     1. Environmental Health Effects Research

     2. Environmental Protection Technology

     3. Ecological Research

     4. Environmental Monitoring

     5. Socioeconomic Environmental Studies

     6. Scientific and Technical Assessment Reports (STAR)

     7. Interagency Energy-Environment Research and Development

     8. "Special" Reports

     9. Miscellaneous Reports

 This report has been assigned to the ENVIRONMENTAL PROTECTION TECH-
 NOLOGY series. This series describes research performed to develop and dem-
 onstrate instrumentation, equipment, and methodology to  repair or prevent en-
 vironmental degradation from point and non-point sources of pollution. This work
 provides the new or improved technology required for the control and treatment
 of pollution sources to meet environmental quality standards.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.

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                                           EPA-600/2-80-023
                                           January 1980
CROSS-COUNTRY URBAN and RURAL  MEASUREMENTS
                of NOX and  S02
                     by
                 Lee Langan
              Michael A. Peache
            Jean Jacques Garbarz

     Environmental Measurements,  Inc.
     San  Francisco, California   94111

                    and

              Ralph E. Baumgardner
               Robert K. Stevens

 Atmospheric Chemistry and Physics Division
 Environmental Sciences Research  Laboratory
Research  Triangle Park, North Carolina 27711
           Contract No. 68-02-2484
               Project Officer

              Ralph Baumgardner
 Atmospheric Chemistry and  Physics Division
 Environmental Sciences Research Laboratory
Research Triangle Park, North  Carolina 27711
   ENVIRONMENTAL SCIENCES RESEARCH LABORATORY
       OFFICE OF RESEARCH AND DEVELOPMENT
      U.S. ENVIRONMENTAL PROTECTION AGENCY
  RESEARCH TRIANGLE PARK, NORTH CAROLINA  27711

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                                 DISCLAIMER
     This report has been reviewed by the Environmental  Sciences Research
Laboratory, U.S. Environmental Protection Agency, and approved for pub-
lication.  Approval does not signify that the contents necessarily reflect
the views and policies of the U.S. Environmental  Protection Agency, nor
does mention of trade names or commercial products constitute endorsement
or recommendation for use.

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                           ABSTRACT
     Total sulfur and oxides of nitrogen measurements, gathered
along two long-distance routes across the United States, are
presented in this report.  Supportive information describing the
instrumentation, procedures, moving laboratory, and regional
meteorological conditions are provided.

     Over 300,000 measurements were made.  Points consisting of
ten-measurement averages have been plotted; they are also pre-
sented in a graphic analysis.  This analysis consists of fre-
quency distribution plots of segments of the trip, for example,
through rural areas and crossing urban developments. These plots
provide a means of classification of the degree of pollution
present and monitored with this moving laboratory technique.

     The data were gathered from Denver, Colorado, to Raleigh,
North Carolina, in August 1576, and from Los Angeles, California,
to Raleigh, North Carolina, in November 1976.  In November the
laboratory stopped at six rural locations to record time-
averaged data, which are also presented.
                               111

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                       CONTENTS


Abstract	iii
Figures and Tables	   vi
Acknowledgements	  vii

     1.  Introduction  	    1

     2.  Equipment and Operating Procedures  ...    4
         Air Quality Moving Laboratory . 	    4
         The MAP System	    7
         Measurement Instrumentation 	    7
         Calibration	   10
         Operations	   12

     3.  Data Presentation	   16

     4.  Discussion	   45
         Moving Results  	   45
         Stationary Measurements 	   45

     5.  Analysis	   46
         Total Sulfur Results	   47
         Nitrogen Oxides 	   48

Appendix
     A.  Ammonia Filter Data	   65
                           v.

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                           FIGURES






 Number                                                  Page








   1        Routes of travel for both trips                2



   2        The AQML at a New Mexico stop site             5



   3        The AQML and interior details                  6



   4        A typical printout of MAP System averages      8



   5        The AQML during calibration                   11



   6        Ground-level temperatures and wind            14



   7        Surface wind direction and speed              15



 8-26       Moving data plots                          17-35



  27        Trip 1 Data Summary                           36



  28        Trip 2 Data Summary                           37



29-35       Stopped data plots                         38-44



36-50       Data presentations                         50-64








                           TABLES




   I        Participants in the program                  vii



   2        Stopped data summary                          16



   3        Ammonia filter data                           65
                             VI

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                              ACKNOWLEDGEMENTS

      Data  collection  and  equipment maintenance  during the cross-
country trips  were performed  by  the  persons  from Environmental
Measurements,  Inc. and the U.S.  Environmental Protection Agency
listed in  the  table below.
                                      Table 1

                   Participants in the Cross-Country Measurement Program
         Individual
        Ralph Baumgardner   Denver-St. Louis
          (EPA)
        Gary Klauber
          (EMI)
        Keith Kronmi Her
          (EMI)
        Lee Langan
          (EMI)
        GiIbert Newcomb
          (EMI)
        Richard Paur
          (EPA)
        Michael Peache
          (EMI)
        Philip Schug
          (EMI)
        Robert Stevens
          (EPA)
        Wi11iam Vaughan
          (EMI)
        Charles White
          (EMI)
Trip I               Trip 2

                   Los Angeles

                   Dal las-Raleigh

                   Jackson-Raleigh

Denver-St. Louis

Denver-Kansas City

Denver

St. Louis-Raleigh

St. Lou is-Lexington    Phoenix-Jackson

Kansas City-St. Louis

Kansas City-Raleigh    Los Angeles-Phoenix

                   Los Angeles-Dallas
ResponsiblIity

Calibration

Operations

Operations,
 Engineering
Software,
 Operations
Engineering,
 Operations
Calibration

Operations,
 Meteorology
Engineering,
 Operations
Calibraticn.
 Operations
Operations,
 Cal ibrations
Software,
 Operations
       Data reduction  and report  preparation  were accomplished by
 Lee  Langan,  Michael  Peache,  Jean  Jacques  Garbarz,  Joan Geary,
 and  Evelyn  More.
                                       vii

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                           SECTION  1

                          INTRODUCTION
     On two occasions in 1976, very sensitive, rapid-response
air quality analyzers were driven across the United States to
seek data background levels and to observe cross-urban effects.
This report presents the results of these trips.  The results may
be -of interest to those concerned with air quality in rural re-
gions, with the fate of sulfur or nitrogen oxides, and with the
establishment and monitoring of national standards.

     The West-to-East traverses extended from Denver, Colorado,
to Raleigh, North Carolina, in August, and from Los Angeles,
California, to Raleigh in November.  Nearly 8,000 kilometers were
driven.  The general routes are shown in Figure 1.

     The surveys were conducted by Environmental Measurements,
Inc.  (EMI) with the support of two U. S. Environmental Protection
Agency  (EPA) contracts:  Purchase Order DA-6-99-6876A and Contract
68-02-2484.  The report was prepared under Purchase Order DA-7-
3954A.  The sensors included a total sulfur gas monitor, a dual-
chamber nitrogen oxide and nitrogen dioxide monitor, and a state-
of-the-art ammonia monitor.

     Most of the data were gathered while moving, and an effort
was made to stay away from nearby motor vehicles that could in-
fluence results.  Of necessity each traverse extended over several
days; the intent was to-cover distances between major urban sites
with continuous data.  Generally, the day's operations began and
ended with calibrations ,of all instrumentation.  Periodically, on
some days, stopped data were gathered at rural sites for a few
hours.

     The equipment and operating procedures are discussed first.
A presentation of the results and the relevant meteorological
conditions follows.  The concluding sections (4 and 5) contain
observations, discussion, and analyses.

     This dual set of long-distance, en route measurements has
demonstrated the value of moving environmental monitoring by this
technique.  The overview of the geographic distribution on a
broad scale and the long distances of low levels interconnecting
the urban anomalies depict the consistency of the air contamina-
tion.  The regional plateaus of higher concentrations show the

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              TRIP  I
         Denver to Raleigh
            August 1976
              TRIP 2
       Los Angeles to Raleigh
           November I 976
Figure 1.   Routes of travel with  each traverse day delineated.   Shading indicates peri-
            ods of monitoring while  dark.   Stopped data  locations are noted by  asterisk.

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diffusion and collective gathering of many localized sources un-
der low wind conditions.  The background levels provide observa-
tions necessary for the use of regional modeling.  The peaks and
urban anomalies allow comparison of separate metropolitan sites
using a rapid and relatively inexpensive reconnaisance method.
Highly sophisticated instruments can be used in the field to
cover large areas, to provide monitoring otherwise prohibitive
in cost if a fixed-base network is established.  And, if need be,
anomalous conditions can be traced, at the time of their occur-
rence, by traversing up-wind of the initial contact.

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                            SECTION 2

               EQUIPMENT and OPERATING PROCEDURES


     The EMI Air Quality Moving Laboratory  (AQML) was an out-
fitted Dodge Maxivan designed for routine regional or local
surveys.  Data processing instrumentation was supplied by EMI;
the high sensitivity analyzers and calibration and collection
equipment were supplied by EPA.

     The EMI/EPA staff developed operating procedures for the
unique conditions of this continuous long-range measurement pro-
gram.  These ranged from the logistics of subsistence and main-
taining a suitable pace to the details of quality assurance.
Most operations became routine, making it apparent that such a
technique of measurement could be maintained without undue stress,
given a protocol and reliable equipment.

     Data processing en route was automatic, requiring operator
interaction only about each half hour.  After the fact, editing
and plotting were straightforward and included adjusting all tra-
verses to a common coordinate system, reducing all measurements
to common stored engineering units, and plotting the results.

     The large data base suggested the use of larger computer
memories.  Fortunately, these have evolved with desktop computers
since the project's field work.  A Hewlett-Packard Model 9845B
was used for final data analysis.


AIR QUALITY MOVING LABORATORY

     The Dodge Maxivan used for the cross-country measurements
is pictured at one of the stationary stop sites in Figure 2.
This vehicle contained a standard support installation:  an in-
board 3.5kW Onan generator, an EMI MAP-II navigational and data
system, two automotive air conditioners, desk space with four
below-table racks for analyzers, a glass and Teflon air intake
manifold with pump, a storage closet for operating and cali-
brating gases, and a Hewlett-Packard 9830A programmable calcula-
tor with peripheral printer, plotter, and tape cassette.

     To this array were added EPA's analyzers:  a Meloy Model 285
flame photometer total sulfur monitor, a Thermo Electron chemi-
luminescent NO/NOX monitor (trip 1) and Aerochem chemiluminescent

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Figure 2.  The EMI AQML proceeded a short distance off a New
           Mexico highway to gather stopped data near Lordsburg
           (8 November 76).
NO/NOX ammonia monitor  (trip 2), and related calibration equip-
ment and gases.  Some chart recorders and test instruments were
also present.  Figure 3 shows some of the equipment inside the
van.  The AQML proved sufficiently comfortable with two air con-
ditioners, but it was crowded when four people were present,
along with their luggage for the long trip.

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The EMI Air Quality Moving
Laboratory
HP9830, MAP-II System, and
plotter inside the moving van
Meloy analyzer  (below) and
calibrating apparatus next
to the HP9830 printer
Cross-calibration at EPA-RAMS
Site 108
Figure 3.  The Air Quality Moving Laboratory and interior details.

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THE MAP SYSTEM

     The EMI MAP II navigational and data  system operates  under
the control of the HP-9830, which provides all  data  formating  and
printing.  Each of the analyzers was connected  to an analog-to-
digital channel of MAP; sampling was performed  each  20 meters
along the route of travel.  Each 200 meters the average measure-
ment was listed, together with the position and time of the last
sample, and plotted in realtime.  While the AQML was stopped,
three-second samples stored every 30 seconds were obtained.
These data were stored on tape cassettes for subsequent analysis;
they were also plotted in realtime for review by the operator.
When only two analyzers were in use, switching  on the chemilumi-
nescent monitor and scrubbing on the flame photometric monitor
were noted by automatic formating changes  in the data listings.

     A partial list from trip 1  (shown in  Figure 4)  is typical of
the visual data.  Each 1i.ne contains location,  time, digitized
analyzer data, and the difference in seconds and meters since the
preceding line.  Each event covered a grouping  of consistent data
(between two known points, stopped data, a calibration, and the
like).  Because of the limit of the 9830's memory, no event of
200-meter data exceeded 50 kilometers  (250 lines of  data).  En  ->
route, this was about an hour of data, referred to as a set of
data.  Each cassette could store six sets  of data, so more than
two cassettes were rarely used for each day's data.

     In addition to the data averaging, the MAP computer derives
the actual position of the vehicle each meter along  the route.
By combining this position with the bearing of  the vehicle, moni-
tored by the gyrocompass installed in the  van,  a new Cartesian
(x,y) coordinate is calculated.  These north-south and east-west
distances are added to a position defined  at the beginning of
each event.  Every 200 meters a new position is identified.

     A quasi-Universal Transverse Mercator (UTM) system of geo-
graphic locations was attempted because values  from  this accepted
framework were used at the beginning of each trip.   The UTM ref-
erence is not, however, contiguous across  the country.  Due to
the earth's curvature, several grids intersect.  The initial UTM
reference was simply continued for each trip so that the plotted
routes that follow are equal-area projections across the United
States.


MEASUREMENT INSTRUMENTATION

     A high resolution total sulfur monitor manufactured by Meloy
Laboratories, Inc. was installed in the AQML.   Sensitivities
on the order of one part per'billion  (ppb) were obtained.
A chemiluminescent monitor manufactured by the  Thermo Electron
Corporation was installed to measure total nitrogen  oxides  (NOX)

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Figure 4.   HP-9830 printout of MAP system  averages in  the  dis-
             tance mode (every 200 meters) showing the location
             (x,y),  the time, the  total  sulfur  (TS), the values
             for  NO or  NOX  from the TECO readings,  the distance
             (D)  between two  averages, and the time (T)  between
             those averages.                     ~~~
                                     8

-------
and nitric oxide  (NO) in August;  a  prototype  chemiluminescent
monitor produced by Aerochem Research  Laboratories  was  used  in
November.  Bendix Corporation and Research  Triangle Institute
double-dilution calibration systems were  used for spanning the
low level concentrations of both  systems; a sulfur  dioxide per-
meation tube and NO gas cylinder  were  concentration sources.
Ultra high purified zero air produced  by  Scott Merrin,  Inc.  was
used to attain zero levels to monitor  potential  instrumental
drifts at these low levels.  Frequent  "zeroes" in the total  sul-
fur were also obtained by using a Meloy SO2 scrubber manufactured
by Meloy.

     Background gaseous sulfur measurements were made with the
Meloy Model SA-285, which uses the  flame  photometric detector
as its measurement "principle.  The  measurement is of the chemi-
luminescense produced when gaseous  sulfur compounds  are burned in
a hydrogen-rich flame.  The reaction emits  a  broad  band of light
with its maximum at 394nm.  The intensity of  the emission is  di-
rectly proportional to the square of the  sulfur  concentration.

     This monitor is designed to  have  optimum sensitivity and
stability to allow for measurements as low  as 1  ppb.  Sample  air
is drawn continuously through the detector  at a  controlled flow
rate of 200cc perx minute.  Hydrogen is applied to the detector at
a positive flow of 150cm3 per minute.  The  light emission is  mea-
sured with a cooled photomultiplier tube.   The current output of
the photomultiplier tube is linearized and  connected to a voltage
before display on a meter or recorder.  By  using selective chemi-
cal scrubbers supplied with the unit,  it  is possible to remove
hydrogen sulfide  (H2S) or sulfur  dioxide  (S02).  By measuring the
total sulfur present, then placing  the appropriate  scrubber  in
line, it is possible, by measuring  the difference in signal,  to
determine specifically the S02 or H2S.

     Measurements of background levels of NO  and nitrogen dioxide
 (N02l were made during the August trip with a Thermo Electron
Model 12 NO-NOX monitor.  This instrument can measure NO and  N02
from 0 to 10.00. ppb with a detectable minimum  of  2 ppb by using
the gas phase chemiluminescent reaction of  nitric oxide and  ozone.
A high temperature thermal converter converts NO2 to NO, allowing
for measurement of NOx  (N02 + NO) and  the determination of N02
present by subtraction  (NOx - NO).

     Sample air is pulled through the  NO  detector at a  flow  rate
of 100.cc per minute where it reacts with  ozone at a reduced  pres-
sure of 10 torr.  A switching valve gives a response for NO;  then
the sample is sent through the thermal converter for a  NOX  (NO +
N02l measurement.  A red-sensitive  photomultiplier  tube with  an
optical filter observes the light from the  reaction of  NO to  03
in the detector and converts it to  an  electrically  amplified sig-
nal.  An output signal for both NO  and N02  is possible.

-------
     Measurement of background levels of NO and NO2 were made
during the November trip with a prototype nitrogen dioxide,  nitric
oxide, and ammonia monitor manufactured by Aerochem Research La-
boratories.  This monitor also uses the reaction of NO and 03  as
its measurement principle.  Using a detector especially designed
by Aerochem to increase the residence time for the NO:03 reaction,
the Aerochem monitor is capable of measuring NO, NO2, and ammonia
 (NH3) from 0 to 500 ppb with minimum detectable limit of 1 ppb.
The monitor has two NO:03 detectors, each capable of measuring NO
or NOX by using a thermal converter.  The monitor was set up for
the study with one channel having a low temperature  (300°C)  con-
verter in line to measure NO + NO2 and the other channel having
a high temperature  (1000°C) converter to convert NO2 and NH3,
giving a signal for NO, N02, and NH3.  The sample air is pulled
into  the monitor at a flow of SOOcc per minute, half of the  flow
going to each detector.  Ozone flow for the reaction is generated,
using a single ozone generator with the flow being split into  each
detector.

      Using thermal converters with each detector and an ammonia
scrubber with one detector, it was possible to measure background
levels of NH3 by subtracting the difference between the signal
with  the scrubber and the signal generated without the scrubber.
These results were monitored only experimentally during the  trips.


CALIBRATION

      At the beginning of the project, an effort was made to  cali-
brate the measuring instruments each morning and evening.  This
allows for conversion of response units to convenient and fami-
iar units:  parts per billion  (ppb).  As the program continued,
at least one calibration was made each day  (Figure 5).

      Two calibration systems were used during the studies.   The
first, a Bendix Model 8851 calibration system, has capabilities
for generating known concentrations of NO and NO2  (using the gas
phase titration of NO with 03) and of sulfur compounds and NH3
(using permeation tubes).  A cylinder of NO at 49 ppm  (standardized
by the National Bureau of Standards' Standard Reference Method) was
diluted to produce concentrations from 0.01 ppm to 0.50 ppm  using
the Bendix system, which has dilution flow control up to SOOOcc
per minute.  The chemiluminescent NO-NOX monitors were calibrated
for NO by this technique.

     The Bendix system also has a permeation tube oven that  pro-
vides controlled temperature to within 0.1° at 25°C.  Dilution air
passes through the oven housing the permeation tubes of either
S02,  H2S,  or NH3-  Permeation rates for each of these tubes  were
determined gravimetrically before the beginning of the study.
                               10

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Figure 5.  Calibrations were normally accomplished twice a day,
           before and following the travel.
Using the permeation system of the Bendix, calibration concentra-
tions of SC>2, H2S, and NH3 between 0.010 and 0.50 ppm could be
generated.

     The second calibration system used in the study was a double
dilution permeation system built by Research Triangle Institute to
deliver known concentrations of gases below 0.010 ppm.  Using the
RTI system, known concentrations of SC>2, ^S, and NH3 were gener-
ated between 0.001 and 0.010 ppm.  The RTI permeation calibration
system consists of two automatic flow controllers, a temperature-
controlled permeation tube oven, and an automatic digital readout
of flows and temperature.  Two mass-flow controllers control air
flow of the permeation oven and dilution flow between 200 and
10,OQOcc per minute.  Zero air entering the unit is split, part
going through one flow controller to the permeation oven, providing
flow over the permeation tube, and part going through the second
flow controller, providing dilution flow.  A glass capillary allows
IQOcc per minute of air flowing over the permeation tube to be
mixed with the dilution air, giving a double dilution to the ori-
ginal concentration.  Temperature within the permeation oven is
controlled to within 0.10°C.  The double dilution system was used

                               11

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to achieve very low concentrations  for  S02  for  calibration across
the usual ambient range observed.   Careful  selection  and calibra-
tion of the flows with a bubble  tube  resulted in  three-point
calibrations ranging  from  10  to  25  ppb  of SO2-  The instrument
received at least one three-point calibration every survey day
and one or two span checks at the 25-ppb level  to confirm the
stability of instrumental  calibration under the vibration and
temperature conditions experienced  in the AQML.  Although there
was some zero drift observed  with occasional high temperatures,
it amounted to fewer  than  7 to 8 ppb  S02 and was  confirmed by
monitoring zero air,  as opposed  to  mere SOX scrubbing.   These
drifts have been  removed from the data.  The stability  of the
calibrations was  excellent during the course of the study, re-
quiring no changes in calibration factors over  a  given  week of
moving measurements.

      Periodically an  SOX scrubber was inserted  into the sample
line  to confirm that  the principal  signal was SC>2 •  Generally,
SOX scrubbing brought the  instrument  response to  within 2-3 ppb
of  zero air readings, indicating that the majority of sulfur was
coming  from SOX and not H2S.   The only  place an appreciable (10
ppb)  H2S signal was observed  with the SOX filter  in place was in
Eastern Texas and Western  Louisiana.


OPERATIONS

      After the morning calibration  the  AQML was driven  along the
least-travelled route to the  next major urban area.   Individuals
shared the load of driving and monitoring the data gathering.
Periodic interaction  was required with  the  automated  system,
route planning, and usual  observations.  The intent was to tra-
verse interurban  regions in a continuous survey.   A conscious
attempt was made  to stay away from  traffic  or,  when this proved
difficult, to stay away from  any truck  or automobile  by either
passing or dropping back.   The measured effect  of an  adjacent
vehicle's pollution is obvious in the data  plots.  Data spikes
are common but of short duration.   They have not  been removed
from  the data.  Diesel trucks created larger anamolies  in nitro-
gen and sulfur oxides than did gasoline-powered automobiles.

     Seven times during the second  trip the  AQML was  stopped to
make stationary measurements  in  conjunction  with  filter samples
taken at the same time and  analyzed for NH3  by  the Air  Monitoring
Center of Rockwell International, as  described  in Appendix A.
The sites chosen to make the  stationary measurements  were several
kilometers off the highway  in  rural areas.   Stationary  and filter
data were collected near Lordsburg, New Mexico; Shreveport,
Louisiana;  Jackson,  Mississippi;  Ragland, Alabama; Commerce,
Georgia;  and Silver City,  North  Carolina.   In addition,  one set
of stationary data only was collected near  Superior,  Arizona.
                                12

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     Included in Appendix A is a letter  from Willard Richards of
Rockwell International describing the  filter analysis, along with
a table of the results.

     Summary maps of meteorological conditions are plotted in
Figures 6 and 7.  The conditions were  noted during the traverses,
but the overview was derived from the  U.S. Weather Bureau's daily
maps representing the 0700 EST status.   The data plotted are taken
from these publications and display the  condition most represen-
tative and nearest the moving laboratory as it proceeded across
the country.  The 0700 wet and dry bulb  temperatures and the 24-
hour variation for the day are plotted in Figure 6 for each of
the 18 survey days; upper-level wind speeds and directions com-
plement these.  In Figure 7 ground winds and the movement of re-
gional highs are plotted to reflect forces on the pollution move-
ments .
                                13

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            TRIP I
         Denver to Raleigh
           August 1976
             TRIP 2
       Los Angeles tc Raleigh
           November 1976
                                                                     24.5 - 26.5 MPS
             TRIP I
         Denver to Raleigh
           August 1976
                                                                       -»-Dry Bulb
                                                                        Wet Bulb
                                                                        Minimum
     TRIP 2
Los Angeles to Raleigh
   November 1976
Figure 6.   Ground-level temperatures and  500  mb  wind direction
              and  speed  plotted for 0700  EST each day.
                                      14

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           TRIP I
       Denver to Raleigh
         August 1976
           TRIP 2
      Los Angeles to Raleigh
         November 1976
Figure 7.   Surface wind direction and  speed  and daily movement
             of major  high pressure centers influencing measurements.
                                  15

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                             SECTION 3

                         DATA PRESENTATION
     Most of  the  data are presented in a two-figure format,  one
per sampling  day.   Total sulfur is on each top graph and  nitro-
gen oxides on the one below.   On both, the road has been  plotted
above the data.   Locations of cities and times are indicated
along the roads.   On  those occasions when the distance covered
during  the day of sampling exceeded the maximum allowed by the
plotting frame (440km),  the remainder of the data was placed in
the right hand top corner of each graph.  The figures, 8  through
26, conclude  this section in chronological order.  Figures 27
and 28  are the trip summaries from preliminary reports.

     Scrubbing of SOX is apparent on the data plot when sharp
vertical lines fall to 3ppb or less of total sulfur.  Data during
stopped measurement periods of the second trip are listed in
Table 2 below.  In each  case, these are rural sites several  kilo-
meters  off the highway (refer to Figure 2 on page 5), and they
are composed  of sets  of  30-second averages (3-second samples)
over an approximately two-hour mid-afternoon period.  About  30%
of the  time the S02 was  scrubbed, which provided a total  sulfur
result  and an SO2  result.   The stopped data are spatially indi-
cated on the  road  and are plotted as a function of time in Figures
29 through 35, which  follow the moving data.  The total sulfur is
above the nitrogen oxides;  scrubbing and NOX-NO switching are
shown in the  data.
                  TABLE  2.   STOPPED DATA SUMMARY
       DATE

      7 Nov 76
      8 Nov 76
     15 Nov 76
     17 Nov 76
        Nov 76
     19 Nov 76
     20 Nov 76
1
    S ITE
   (near)

Superior, AZ
Lordsburg, NM
Shreveport, LA
Pelahatchie, MS
Ragland, AL
Commerce, GA
Si Iver City, NC
                                 TOTAL
                                SULFUR
                                 (ppb)
    S02    MEASUREMENT
(TS-scrubber)  PERIOD
   (ppb)     (minutes)
                                 22.24
              63.
              180.
              122.
              127.
              120.
              126.
              161.
                                16

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       PPB
         U5/H1
         400
       50-
          200
         •IBB
                                JUL
                                            H0 KM
                               OISTHNCE;: i	1  HB KM
Figure 8.    August 18 -  1600-2300 MDT - Colorado




                                     17

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      PPB
         B/H3
         M0B
         3BB
         -2BB
         •IBB
                  O

                  O
  o
o o
                                    SB
                                       IBB
                               =f=
                                                       0
                                                       o
                       0
                       01
                              BISTRNCE:
H0 KM
PPB
IEBB-
IZ0B-
U1
U
e>
NITRDBEN DXI
ID
i
HB0-

B-
BBB-
H00-
V •
a-

IU Z UI < <
^ o -J u x
_J H -I UJ K
• l l O *^ Z ^
> Z > UJ X
UJ « (fl I/I <
d S 5 5
•K 5 S
^ „, i, Jl ^ i. 1 '

	 _ _, 	 _ , -H 	 , 	 • ^
g | <0 ZS" M
."3 U. " I
1 HM
1- ~ Z
« S "> jl
J 1 1
1 — u^Y^-^n 	 L^^n_jpjH_r|jn_^kj-t rkJ-J. rT^w^'U-J
DI5TRNCE: 1-


Figure 9.   August  19 - 1QOO-2400 MDT  - Colorado-Kansas
                                    18

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       PPB
       IS0-
         -300
       100-
      o:  --2BB
       SB-
          H00
         -100

                                1
                                           1
                              DISTRNCE:
HB KM
Figure 10.  August 20  -  0000-0100,  1300-1800 CDT - Kansas-Missouri




                                    19

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        PPB
        ISO-
         SB-
           •HH e
          -300
           •ZHH
                                                        -I	1	h-
                                BISTRNCE:
                                              HB KM
        PPB
       IEB0--
       1200
       HBB-
                z
                o
                z
               -I	1-
                                                  H	1	1	(_
                                              HB KM
Figure  11.  August 24  - 2000-2300 CDT - Missouri-Illinois



                                      20

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Figure 12.  August 25 -
1100- 230Q CDT - Illinois-Indiana-Kentucky




        21

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        PPB
          UB/H'
        ISH-
          •30H
        I Eta-
           HBB
          •ZBB
          •IBB
                               DISTRNCC:
                                             40 KM
Figure 13.  August  26 -  1000-1900 EOT  - Kentucky-Virginia




                                    22

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Figure 14.  August 27 - 1000-1600 EOT - Virginia-North Carolina




                               23

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        PPB
        IS0
           JE/H3
           H0B
        100
           •200
           •IBB
                                            H
DI5TRNCD
                                              H0 KM
         PPBl
        H004
                                            H	
                                            -I H0 KM
Figure  15. November  3 - 1900-2100 PST -  Los Angeles
                                     24

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Figure 16.  November 4 - 1300 PST to 0200 MST - California-Arizona
                               25

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Figure 17.  November 7 - 1100-2000 MST - Arizona
                               26

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        PPB
           UB/H3
        I5H-
        100-
           300
           H00
           -100
                                DISTHNCt:
                                             H0 KM
Figure 18.   November  8 - 1300-2200  MST -  Arizona-New Mexico




                                     27

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        PPB
        [EBB-
       I2BB-
        H00-
                                       o
                                       <
                              DISTRNCE: i	1 HH KM
Figure 19. November  9  - 1500-2200 MST - New Mexico-Texas
                                   28

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       PPB
       I EBB- •
       I2B0--
       H00--
                                 B0B-
                                 HBB-
                                                                    D:
                                                                    o
                                          too.—Mlfv_rv
                                D iSTRIKE: i~
                                               M0 KM
Figure  20.  November 10  - ILOQ MST to  2400  CST  - Texas
                                      29

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       PPB
         UG/HJ
       ISB-
         •HB0
        SB-
          •Z0H
          •IBB
                              DISTRNCE:
-I 40 KM
Figure 21.  November 14 -  1200-2000 GST - Texas-Louisiana




                                    30

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       PPB
       150-
UB/M3
           00
          200
                                          -t-
                              DISTHNCE:
                                  H0 KM
Figure  22. November 15  - 1400-2400 CST  -  Louisiana-Mississippi
                                   31

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Figure 23.  November 17  -  1000-1900  CST -  Mississippi-Alabama




                               32

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                             DI5THNCE: i	! '10 KM
Figure 24.   November  18  - 1000 CST to  2100  EST - Alabama-Georgia




                                 33

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Figure 25.   November  19  -
1000-2100 EST - Georgia-North Carolina




     34

-------
        PPB
        I Se-
          H0B
          30B
          •200
          -100
                                DI5TRNCE:
H0 KM
        PPB
                                 RTF
                                DISTRNCE::
                                              H0 KM
Figure 26.   November 20  - 1000-1800  EST  - North Carolina
                                     35

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                                                    ROUTE OF TRAVEL (1 CR = 60 KM)

                                              HEAVY INTERSTATE TRAFFIC
Figure 27.   Trip  1 data  summary - Denver to  Raleigh  - August 18-27,  1976

-------
                                                    fUTRQGEH OXIDES
                                        lM^JL-^J«Jl(l^^
                                               d|..     HI1ROSBI OXIDES
                                        WfllL-~.-t.
Figure 28.   Trip 2 data summary - Los Angeles  to  Raleigh
            November 4-20, 1976 (before data adjustments)
                               37

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     57.
     HJ.
   a *•
   ^"-»
   •t]
   a a.
     SB-
     am.
     IB-
Figure 29.  Stop site east  of Phoenix  (Superior,  AZ) - November 1;

            stationery data only (no filter  samples)
                                38

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  SI.





  HI.





  31-





  21-





  II •
  su-
  it-
Figure  30.   Stop site  #1 - November 8 - Lordsburg, NM
                                  39

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    01



    MB



  3  38

  /-\
  •o

  B  a
  •w


    IB
    saa
    IBS-
Figure  31.   Stop site  #2 - November 15 - Shreveport, LA
                                 40

-------
   a
   HI
 3 »
   IBB
Figure 32.  Stop site #3 - November 17  - Pelahatchie,  MS
                               . 41

-------
   HH.




 3 38-
   tan
 g
   ZBB
   I0B
Figure  33.   Stop site #4 - November 18 - Ragland,  AL
                                 42

-------
   38.
   ..
   II.
   jl
D)
Figure 34.  Stop  site #5 - November  19  - Commerce, GA
                                 43

-------
a
  sail
  sun
  3SB
  IBB
Figure 35.  Stop site  #6 - November  20  - Silver City,  NC
                                 44

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                            SECTION  4

                            DISCUSSION

MOVING RESULTS

     These results  clearly show long distances of consistant
quasi-uniform data  between urban islands of higher content.
Rural levels differed  regionally; between some cities the  levels
were very low, while higher backgrounds existed between others.

     Low levels of  total  sulfur,  below one part per billion, were
experienced; plumes of over a hundred ppb were crossed;  tens of
ppb were common in  urban  measurements.   Higher rural backgrounds
were present from the  Mississippi River east.

     In the nitrogen oxides'  plot the switching to NO measurements
during the August trip clearly results in troughs, which demon-
strates that NOX mainly consists of NO2.  During the November trip
only NOx was recorded.

     There was a purposeful intent to travel on and off  the Inter-
state Highway System along the route.  The Interstate segments of
travel resulted in  much higher NOX levels due  to the traffic.  The
effect in the total sulfur results was less obvious and  more
closely related to  individual vehicles.  Diesel vehicles were very
sulfurotis.  Travel  in  and for some distance east of Los  Angeles
reflected the content  of  air breathed by many  automobile commuters.
NOX levels were normally  in excess of 300-400  ppb.

     Low levels of  NOX were observed to a few  ppb in the western
deserts.  In the South, levels rose to tens of ppb;  in urban areas
and on highways levels exceeded hundreds of ppb frequently.  Off
heavily travelled streets,  upwind of concentrated traffic, levels
of several tens of  ppb remained in urban locations.


STATIONARY MEASUREMENTS

     At the seven stop sites  the levels of sulfur were less than
10 ppb except at the last site,  where levels of 50 ppb were
reached.  The NOX measurements showed background levels  of less
than 25 ppb at all  sites  except Stop Site #6,  which was  near a
dairy feed lot in a heavily agricultural region.   The NOX signal,
which was often above  50  ppb  during this final test,  was almost
entirely removed by the NHs denuder.

                               . 45

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                           SECTION  5

                            ANALYSIS


     After the cross-country trips, it was possible to reduce the
data to a calibrated form and to plot them as a function of dis-
tance.  A variety of plots were reviewed, and the preliminary
analysis of the data, resulting from an overview of these plots,
was presented in preliminary reports.   Plots of this nature are
found in Section 3.  It was obvious that anomalies of pollution
occurred in the vicinity of cities that were crossed during the
trips and that these were separated by broad regions of consid-
erably less pollution.  A method of displaying an overview of
these data in some uniform fashion was sought.

     Initial attempts were to prepare plots of correlation vs the
separation of data points.  The initial assumption was that, over
broad regions, adjacent and even widely separated data points
ould be similar for rural areas^and dissimilar for urban areas.
Therefore, one could provide an analysis to separate the charac-
ter of the region traversed.  This approach did not proceed well,
primarily because most of the data points were near the noise
level of the gaseous concentration being measured.  One part per
billion does not correlate very well with two parts per billion,
and such threshold values were not uncommon in the western states.
Another way was sought,  j

     While preparing these materials, Environmental Measurements
was visited by an associate from France, Dominique Rust from the
Commissariat de Energie Atomique  (CEA).  He described a technique
suggested by Dr. Pierre Zettwoog to provide a common format for
similar long-distance traverses conducted by CEA.  The technique
is to provide a frequency distribution for the occurrence of a
given concentration in a given set of data.  Once this is calcu-
lated, a cumulative frequency distribution provides an integrated
value that is distinctive for similar sets of data points.  This
method proved useful, as follows:

     In the data that were accumulated for the two transcontinen-
tal trips, common dimensions have been used in Figures .36 through
50.  The concentration for both nitrogen oxide and total sulfur
is plotted as the log of concentration from one part per billion
to one thousand parts per million on the abscissa.  On the ordi-
nate, the left edge is from 5-20% of the frequency occurrence of


                               46

-------
the concentrations, which are plotted as dots.   The right ordi-
nate is 100% of the cumulative frequency distribution (integral
curve), plotted as a  solid line.   If the cumulative plot is  steep,
the data tend to be contained within a narrow region.  To the  left
they are of lower concentrations,  and to the right they represent
more significant pollution.   A more gradual slope represents a
broader distribution  of  the occurrence of the contaminants.

     The presentations are ordered by showing the total sulfur
data first and then the  results from the nitrogen oxide measure-
ments.  In each case  the results  of the first trip are presented
and followed by those of the second trip.  Throughout both trips,
while the data were gathered at 200-meter increments, each data
point represents an average of ten samples.  Thus, for example,
the 19,026 points represented in  the second trip's total sulfur
presentation actually represents  190,260 samplings of the analy-
zers.

     In each graph a  location is  identified, together with the
number of data points used for the presentation.   For each trip
and for each gas the  results of the entire trip are presented  on
a single page.  The variation in  the number of  points used for
each gas is a result  of  minor periods when one  or another instru-
ment may have been off during the course of the trip.  The "En-
tire Trip" results are followed by subsets in urban areas tra-
versed by the trip and by subsets in regional rural traverses
between cities.  Each takes a distinctive form.   No attempt  was
made to modify the data  that were recorded on the trip other than
to reduce them to engineering units.  The spikes  that occur  as a
result of traffic are thus intermixed with the  results of tran-
secting the touchdown of plumes or the general  air throughout  the
cities on the route.  Periodic daily calibrations and spans  are
also not excised from the data, but they represent a relatively
small portion of the  total data points and should not bias the
results in any significant fashion.  To a first order approxima-
tion, these summary data represent the air breathed by the occu-
pants of the vehicle  as  it traversed across the United States.
TOTAL SULFUR  RESULTS

     An overview of Trip 1 versus Trip 2 would indicate  that  the
results of both  trips are similar with 90% of the measurements
made falling  beneath approximately 11 ppb total sulfur.

     Selected urban sites show quite distinct differences,  how-
ever.  In Trip 1,  for example, 90% of the total sulfur results in
Denver fall below 8 ppb; yet in Louisville, this cut-off is ap-
proximately 100  ppb.   This same higher level represents  Birming-
ham, Alabama,  from the second trip.  The results from Phoenix and
Los Angeles show somewhat nore sulfur than do those from Denver
                                47

-------
 (90% below 12 ppb); these appear to be related to automotive
traffic.

     Rural results are also rather similar.  The Great  Plains
trip between Denver and Kansas City is comparable to  the  desert
trip between Phoenix and El Paso, with very little presence  of
total sulfur.  The trip across the Allegeny Mountains from Lex-
ington to Raleigh shows distinctly more total sulfur  presence;
the trip from Dallas to Birmingham across the southern  Mississ-
ippi River valley shows a higher level and distinctly more pre-
sence of total sulfur.  The time of the Lexington-Raleigh tra-
verse was August 26-27, 1976, during the occurrence of  a  persis-
tent elevated pollution episode, as defined by later  analysis of
regional data.

     One must keep in mind that these data are presented  as  a
preliminary analysis of the total results in an effort  to present
a means by which the regional data can be quantatively  compared.
They represent results as. they occurred over randomly chosen
times of travel; thus they may be assumed to be good approxima-
tions of what one may find at any time.
NITROGEN OXIDES

     The results of the nitrogen oxide measurements are more
difficult to evaluate because they were measured on each trip
with different instruments and because on the first trip there
was a periodic switching between the measurement of total nitro-
gen oxides and NO.  The second trip measured only total nitrogen
oxide measurements.  Whereas it would be highly desirous to sepa-
rate these data, this has not been done because the data were not
gathered in a fashion to make this analysis convenient.  The
results of Trip 1 represent lower concentrations because of the
values obtained when measuring NO only.

     On Trip 2 one of the instruments that was used had a range
position, which, when the measurements exceeded this range,
rested at a limit.  The fact that this was not monitored at all
times is obvious in the results of the data shown in the entire
trip.  The large peak of over 3% occurrence at about 90 ppb
represent this limit; these data should be spread to higher con-
centrations.

     It must be remembered that frequent routes on both these
trips are on Interstate highways and that there are frequent
occurrences of automobiles' and other vehicles' proceeding just
in front of the measuring vehicle.  Spikes of measurements occur
throughout the trips, but these spikes have little correlation.
They were left in the data, again to represent the air that the
operators and drivers were breathing.
                               48

-------
     With these limitations  in mind,  the summary representations
still retain an intriguing overview of these cross-country trips.

     As in the total  sulfur  data,  the NOX data for both entire
trips are rather similar, with 90% of the results occuring in less
than 200 ppb.  The results from the urban measurements in Denver,
Louisville, and Phoenix  were all rather similar, with 90% of  the
occurrences falling less than approximately 300 ppb.   Los Angeles
met expectations with the higher occurrence of NOX, and Birmingham,
while notable in total sulfur content, was low in the presence of
NOX-  In the rural results each selected regional traverse had
relatively little traffic.  The trip between Denver and Kansas City
was on a little-travelled U.S. highway, and the peaks and troughs
of the frequency occurrence  resulted from the switching from  the
NO to NOX.  Levels of less than approximately 40 ppb  NOX were
present for 90% of that  trip.  This compares favorably with the
relatively untravelled route between Dallas and Birmingham.   Re-
sults between Lexington  and  Raleigh represent a more  heavily  tra-
velled route and slower  transit times through the mountains.
These compare with the data  gathered between Phoenix  and El Paso;
yet it must be observed  that there were very few vehicles on  the
western route, and the results may represent a more regional  pre-
sence of NOX.

     One is reminded  that the entire purpose of both  of these
trips was to present  an  experimental means of gathering regional
data that might be representative.  In that same light,  the results
here are presented to suggest a convenient form for evaluation.
                               . 49

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   ckJ
                                                      100
 Figure 36.
                                                           z
                                                           o
o
-10/
a:
H-
10
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o
21
U
=i
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U
DL
U.
                              TOTRL SULFUR
                              TRIP NO 1
                              ENTIRE TRIP
                              11700 POINTS
                                                       50-

—i
CQ
t-i
Ct

in
I—i
Q


b

Ld
D
O
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U.

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M


-------
                                                     100
                                                         5
 o
 n
 h
 OL
 I-
 Ul
                             TOTflL SULFUR
                             TRIP NO 1
                             DENVER
                             977  POINTS
                                                         D
                                                         CO
                                                         M
                                                         o:
                                                         i-
                                                         tn
                                                         Hi
                                                         O
                                                     (J

                                                     LJ

                                                     O
                                                     U
 LJ

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 LL
                                                     LJ

                                                     IH

                                                     cr

                                                     r

                                                     u
                    10               100
                     LOG CONCENTRHTION (Ppfl)
                                                  10130
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Figure 37.
                         -51

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                             -53

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                         64

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                                APPENDIX  A


AMMONIA  FILTER  DATA  by  ROCKWELL  INTERNATIONAL
                       Air Monitoring Center

                                         International

                                         In reply refer to AMC76-9S5
       14 December 1976
      Mr. R. K. Stevens
      Environmental Sciences Research Laboratory
      Hall Drop 47
      Environmental Protection Agency
      Research Triangle Park. North Carolina  Z7711

      Dear Bob:

      We have analyzed the  filters which were returned to us from EMI, Project
      148, and summarized tn» results in the attached table.  The right hand
      column gives the observed concentration of ammonia in the ambient air from
      each of the two determinations and, below  the line, the average of the two
      results.   The first four columns give the  information provided by EMI, Inc.
      on the time, location,  and circumstances of the collection of each sample.

      As described on pages  21 through 23 of the first Monthly Report under
      contract  68-02-2463,  "Los Angeles Field Modeling and Measurement Study"
      (LAFMMS), the AHC still has this method under development.   Therefore, im-
      provements in the laboratory procedures are still being devised.  One evi-
      dence of  this is that  the field blanks in  the data reported here had an
      average of more than 30 times as much ammonium on them as the field blanks
      front the  October LAFMMS sampling.   The analysis of two laboratory blanks,
      which were filters  held out of the groups  of filters sent to the field,
      shows that the high blank readings were caused by the laboratory procedure
      for preparing the filters and not by the shipping and field handling pro-
      cedures.   Me are now developing procedures for preparing filters in larger
      quantities with uniformly low blank ammonium contents.

      In three  cases,  the exposed filters contained less  ammonium than the blank,
      Indicating some variability in the blank values.   This  variability contri-
      butes  to  the scatter in the data.   The  general  range of the results appears
      reasonable.

      We would  be  very  Interested to learn  how these  data compare with those from
      the chemi luminescent instrument.   Should you desire to  publish any of these
      data, we  very much  hope that their source will  be clearly acr.nowledgeJ.
      Sincerely yours,
     Hillard Richards
     Project Manager

     Enclosure
                                      65

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        TABLE  3.   AMMONIA FILTER DATA

Slop
51 le *
1



2





3


4



$




6






Laborat

Sample
Date/
Time
11-8-76
1611-1812


11-15-76
1524-1724




11-17-76
1135-1335

11-18-76
1425 EST
1525


11-19-76
1342 EST
1542



11-20-76
1410 EST
1610





cry blanks


Sample
Location
Rt. 81, 4 mi
So. of 1-10
(vicinity of
Lordsburg, NM)
Rt. 157, 2 Km
No. of junet,
LA. * 10 Km
No. of 1-20.


Comment
Holder #3 not
used.


Low stratus.



East of Shreveport,
LA.
Miss. 49, 8 Km
No. Pel aha tehee,
MS. 30 Km East
of Jackson, MS.
9 Km S.Ragland,
AL. » 60 Km
ENE Birmingham.
Refuge Church
Yard.
12 Km NW
Conmerce, GA
(near a creek)
btw. Homer i
Maysville on
Rt. 98, GA.
25 Km WSW
Chapel Hill,
NC. 18 Km ME
Silver City,
NC.






^
Used filter batch.
1608, received
Jackson, MS.

Pine forest area.
Mg NHj/F1lter
1 2 3
blank
1.67 2.13 -




2.07 1.58 1.54





1.23 0.98 1.41


Filter batch 1508, . ,, , qc , ,7
low wind speed. °'41 l'^ l'4/
Clear 8, warm (70°F)

Filter batch 1499
(received
Birmingham, ALO



Filter batch 1499
Near dairy farm/
feedlot, heavy
agricultural
region. Hay odor.


0.45 1.23 1.13




0.53 2.80 1.69


NH3 denuder removes
much of NOx signal.
Also in SOx plume.

.

0.54
1.81
Ammonia
Concentration*
/jq/m3
0.5



-0.6 .
-0.6

-0.6


-0.3
+0.3
0.0
1.8
1.3
1.5

0.9
0.8
0.8


2.6
1.3
1.9






 •The ammonia concentration from each filter and the mean is given.
The technique uses oxalic acid  coated on a
glass fiber filter.  Ambient air is drawn
through  a  1 ym fluoropore filter to remove
all particulates,  then through  the glass
fiber filter coated with oxalic acid.  The
ammonia  gas passes through the  first filter
and is collected on the second.   The filters
are subsequently analyzed.
                       66

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TECHNICAL REPORT DATA
(Please read Inunctions on the reverse before com,
r REPORT NO. ~~~ fa"
EPA-600/2-80-023
4 TITLE AND SUBTITLE
'CROSS-COUNTRY URBAN AND RURAL MEASUREMENTS OF NO
AND so2 x
7. AUTHOR.(S) j j ,
L. Langan, M.A. Peache, and J.J. Garbarz,
R.E. Baumgardner, and R.K. Stevens
9, PERFORMING ORGANIZATION NAME AND ADPRESS
Environmental Measurements. Inc.1
San Francisco, California 94111
12. SPONSORING AGENCY NAME AND ADDRESS
Environmental Sciences Research Laboratory -- RTP, NC
Office of Research and Development
U.S. Environmental Protection Agency
Research Triangle Park, N.C. 27711
iletingj 	
3. RECIPIENT'S ACCESSIOf*NO.
5. REPORT DATE j
January 1980 1
6. PERFORMING ORGANIZATION CODE I
8. PERFORMING ORGANIZATION REPORT NO. I
10. PROGRAM ELEMENT NO. I
1AA601 CA-32 (FY-77)
11. CONTRACT/GRANT NO. 1
68-02-2484
13. TYPE OF REPORT AND PERIOD COVERED I
Final
14. SPONSORING AGENCY CODE I
EPA/600/09 I
15. SUPPLEMENTARY NOTES I
16 ABSTRACT

      Total sulfur and  oxides of nitrogen measurements,  gathered  along two long-
 distance routes across the United States, are presented.   Supportive  information
 describing the instrumentation, procedures, moving  laboratory, and  regional  meteoro-
 logical conditions  are provided.

      Over 300,000 measurements were made.  Points consisting  of  ten-measurement
 averages have been  plotted; they are also presented  in  a  graphic analysis.   This
 analysis consists of frequency distribution plots of segments of the  trip,  for
 example, through rural  areas and crossing urban developments.  These  plots  provide  a
 means of classification of the degree of pollution  present  and monitored  with  this
 moving laboratory technique.

      The data were  gathered from Denver, Colorado,  to Raleigh, North  Carolina, in
 August 1976, and from  Los  Angeles, California, to Raleigh, .North Carolina,  in  November
 1976.  In November  the laboratory stopped at six rural  locations to record  time-
 averaged data, which are also presented.
                               KEY WORDS AND DOCUMENT ANALYSIS
                 DESCRIPTORS
                                             b,IDENTIFIERS/OPEN ENDED TERMS
                                                                        c. COSATi Field/Group
 *Air pollution
 *Sulfur
 *Sulfur dioxide
 *Nitrogen  oxides
 *Measurement
 *Rural  areas
 *Urban  Areas
  United States
13B
07B
05J
8. DISTRIBUTION STATEMENT

 RELEASE  TO PUBLIC
19. SECURITY CLASS (Tl
  UNCLASSIFIED
75
20. SECURITY CLASS (TMspage/
  UNCLASSIFIED
                           22. PRICE
  Form 2220-1 (9-73)
                                           67

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