24401-29





                    BACKGROUND  DOCUMENT
          RESOURCE CONSERVATION AND RECOVERY ACT




         SUBTITLE C - HAZARDOUS WASTE REGULATIONS









          SECTION 3004 - STANDARDS APPLICABLE TO




         OWNERS  AND OPERATORS  OF HAZARDOUS WASTE




       TREATMENT,  STORAGE, AND DISPOSAL FACILITIES









                      40 CFR  PART 265









      SUBPART  J  - INTERIM STATUS STANDARDS FOR TANKS




      SUBPART  Q  - INTERIM STATUS STANDARDS FOR CHEMICAL,




                   PHYSICAL, AND BIOLOGICAL TREATMENT
           U.S.  ENVIRONMENTAL  PROTECTION AGENCY




                   OFFICE OF SOLID  WASTE




                       APRIL 29,  1980

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                                                              Page




IV.  Continuous  Feed Operations	   27




     A.   Summary of Proposed Standard 	   27




     B.   Rationale for the Proposed Standard	   27




     C.   Summary of Comments	   27




     D.   Analysis of and Response to Comments	   28




     E.   Final Regulation Language  	   30




  V.  Freeboard	   31




     A.   Summary of Proposed Standard 	   31




      B.   Rationale for the Proposed Standard	   31




      C.   Summary of Comments	   32



      D.   Analysis of and Response to Comments	   32




      E.   Final Regulation Language  	   34




 VI.   Waste Analyses and Trial Treatment Tests 	   35




      A.   Summary of Proposed Standard	   35




      B.   Rationale for the Proposed Standard	   35




      C.   Summary of Comments	   36




      D.   Analysis of and Response to Comments	   37




      E.   Final Regulation Language  	   40




VII.   Inspections	   42



      A.   Summary of Proposed Standard 	   42




      B.   Rationale for the Proposed Standard	   42




      C.   Summary of Comments	   42



      D.   Analysis of and Response to Comments	   43




      E.   Final Regulation Language  	   47
                                111

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                                                                Page


VIII.  Closure	    49


       A.  Summary of Proposed Standard  	    49


       B.  Rationale for the Proposed Standard	    49


       C.  Summary of Comments	    51


       D.  Analysis of and Response to Comments	    52
                                                   A

       E.  Final Regulation Language  	    53


  IX.  Special Requirements for Ignitable

       and Reactive Waste	    54


       A.  Summary of Proposed Standard  	    54


       B.  Rationale for the Proposed Standard	    54


       C.  Summary of Comments	    55


       D.  Analysis of and Response to Comments	    57


       E.  Final Regulation Language  	    62


   X.  Special Requirements for Incompatible Waste 	   64


       A.  Summary of Proposed Standard  	   64


       B.  Rationale for the Proposed Standard	64


       C.  Summary of Comments	65


       D.  Analysis of and Response to Comments	65


       E.  Final Regulation Language 	   67


  XI.  NPDES Facilities  	   68


       A.  Summary of Comments	68


       B,  Analysis of and Response to Comments	68


 XII.  Miscellaneous Comments  	   70


   FINAL INTERIM STATUS REGULATION LANGUAGE  	   72


   References	81


   Appendix I  NFPA Buffer Zone Requirements for Tanks ....   83
                                  IV

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                           FOREWORD




     This is one of a series of documents providing support




and background information for regulations issued under Section




3004 of the Resource Conservation and Recovery Act (RCRA).




This background document concerns the management of hazardous




waste in tanks and in chemical, physical, and biological treat-




ment facilities other than surface impoundments and land treat-




ment facilities (40 CFR Parts 265, Subparts J and Q).  It is




divided into two parts.  The first part contains introductory




material which addresses the Congressional authority for the




regulation, key definitions used in the regulation, examples




of damage incidents which illustrate the need for the regulation,




and a description of precedents set for the regulation by State




and/or other Federal statutes.  The second part of this document




describes the regulations as originally proposed, summarizes




and responds to comments received that relate to the proposed




regulation, and indicate the Agency's rationale for the final




regulation.




     On December 18, 1978,  in §§250.44 and 250.44-1 of the




proposed RCRA Section 3004 regulations,  the Agency proposed




standards for the storage of hazardous waste in tanks.  In




§§250.45-4 and 250.45-6, the Agency proposed standards for




the treatment of hazardous waste in basins.  (The proposed




§250.45-6 standards applied also to treatment facilities other




than basins.)  As specified in §250.40(c)(2)  of the proposed




rules, certain of the proposed §§250.44,  250.45-4,  and 250.45-6




standards applied to facilities during the interim status
                              v

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period (i.e., the time  from the  effective  date  of  the  interim




status regulations until the  Agency's  final  decision on a




facility owner's or operator's permit  application).




     Several commenters asked that  the set of standards




applicable to facilities with interim  status be expanded,




pointing out that the Agency  has predicted (43  Federal Register




58984) that the ultimate permitting process  may take several




years  to complete.   In  response  to  these comments, the Agency




has  added several of the proposed permanent  status standards




to the set of final  interim  status  standards.   As  explained




in the preamble discussion entitled "Interim Status Standards",




in general, the Agency  included  permanent  status standards




in the set of final  interim  status  standards if the standard:




      (a)  can be  implemented  by  the regulated community




          within  the six-month period  between the  time the




          regulations are  promulgated  and  their effective




          date;




      (b)  does not  require large capital expenditures  for




          items which would  later require  approval as  part




          of the  permitting process; and




      (c)  can be  implemented  directly  by the regulated




          community without  the  need for consultation  with




          or interpretation by the  Agency.




     The Agency believes that some  of  the  proposed permanent




status technical  requirements for the  design and construction




of tanks, basins, and chemical,  physical,  and biological treat-




ment facilities — e.g., the  requirements  for spill confinement
                               VI

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structures, an impermeable base beneath tanks, and emergency




storage capacity — should not be implemented during the interim




status period.  The costs of upgrading these aspects of facilities




will be considerable and the designs will require Agency approval,




which is properly part of the permit issuance process.  Therefore,




these requirements are not included in the final interim status




standards.



     Some of the proposed §250.45-4 and 250.45-6 standards for




basins and other types of treatment facilities contained "Notes",




which provided alternative standards to those in the text of



the regulation, available upon making a specified showing to the




Agency.  To avoid the burden to the Agency of having to pass




on such requests during the interim status period,  the final




interim status standards have been rewritten so that, although




alternative standards may be available only under specified




conditions, no showing or Agency approval is necessary.



     In the proposed rules, the standards for tanks were somewhat




different than those for basins.  Tanks were regulated as




covered containment devices used for storing hazardous waste,




while basins were regulated as uncovered containment devices




used for treating hazardous waste.  (The proposed rules did not




address the use of tanks for treating hazardous waste.)  Both



tanks and basins,  however, were defined to be constructed out




of man-made materials.




     The comments revealed that this distinction between covered




storage devices and uncovered treatment devices did not reflect




actual practice very well. The final rules call all non-portable
                             Vll

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containment devices made of non-earthen materials  "tanks",



whether they are covered or uncovered, or  used  for  storage or



treatment. All tanks are covered  by  a  single  set of regulations



(40 CFR Part 265, Subpart J).   The Subpart J  standards  include



standards  from the proposed §$250.44-1 (Storage Tanks)  and



250.45-4  (Basins), and  also standards  applying  to tanks and



basins in  the proposed  §§250.44 (General Storage) and 250.45-6



(Chemical, Physical, and Biological  Treatment Facilities).



      Subpart Q contains requirements which pertain  to chemical,



physical,  and biological treatment conducted  in facilities



other than tanks, surface  impoundments (Subpart K),  or  land



treatment  facilities  (Subpart  M).  For example, facilities



which treat hazardous waste using distillation  columns, centri-



fuges, or  filter presses must  comply with  the Subpart Q standards



if  they do not meet the definition of  "tank"  specified  in the




final Part 260 rules.



      The  Phase I Subpart Q standards are essentially identical



to  the Phase  I standards for tanks.  Therefore, the standards



in  these  two  Subparts will be  discussed together.   References



to  tanks  in the  following  discussion are also meant to  include



the waste  containment components  of  chemical, physical, and




biological treatment equipment.
                              Vlll

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                       - 1 -



   INTRODUCTION AND RATIONALE FOR THE  REGULATION




RCRA Authority for the Regulation;




     In Section 3004 of Subtitle C of  the Solid Waste




Disposal Act, as substantially amended by the Resource




Conservation and Recovery Act (RCRA) of 1976, as amended




(42 U.S.C. §§6901 et seq.), the Congress of the United




States requires the Administrator of the U.S. Environ-




mental Protection Agency (EPA) to promulgate regulations




to establish such standards, for hazardous waste treat-




ment, storage, and disposal facilities as may be necessary




to protect human health and the environment.




     Sections 3004(3) and (4) of RCRA state that the




standards to be promulgated by the EPA must include




requirements for -




     "(3)  treatment, storage, or disposal of all such




     waste received by the facility pursuant to such




     operating methods, techniques,  and practices as




     may be satisfactory to the Administrator;




     "(4)  the location,  design, and construction of




     such hazardous waste treatment, disposal, or




     storage facilities;  [emphasis added].




     To comply with this mandate, the Agency must,  among




other things, promulgate regulations that will protect human




health and the environment from the potential adverse




effects of (l) treating or storing hazardous waste  in tanks



and (2) treating hazardous waste in facilities subject to




regulation under Subpart  Q.

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II.   Key Definitions

          The following terms, which are defined  in  Part  260,

     are key to this area of  regulation:

          "Freeboard" means the vertical distance between
          the top of a tank or surface  impoundment dike,
          and the surface of  the waste  contained  therein.

          11 Incompatible Waste" means a  hazardous  waste which
          is unsuitable for:

          (i)  Placement in a particular device or facility
               because it may cause corrosion or  decay of
               containment materials  (e.g.,  container inner
               liners or tank walls), or

          (li) Commingling with another waste or  material
               under uncontrolled  conditions because the
               commingling might produce heat or  pressure,
               fire or explosion,  violent  reaction,  toxic
               dusts, mists,  fumes, or  gases, or  flammable
               fumes or gases.
          (See Part  265, Appendix V, of  this  Chapter  for examples)

     These  definitions are further discussed in the  background

     document supporting the  final Part 260  rules.

     o    "Inner  liner" means a continuous layer  of  material
          placed  inside a tank or  container  which protects
          the construction materials of the  tank  or  container
          from the  contained  waste or the  reagents used to
          treat the waste.

     This definition was added to  the final  rules to distin-

     guish  between  continuous layers of materials used to line

     facilities constructed primarily of non-earthen materials

     (e.g.,  tanks)  and those  constructed of  earthen  materials

     (e.g.,  landfills).  The  former type of  facility is always

     lined  with man-made materials, the latter is often lined

     by earthen materials. Because the  precautions needed to

     protect these  linings depend  on the materials used to

     make them, it is appropriate  to have  different  terms to

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                       - 3 -

refer to the them in the regulations.  Accordingly, con-

tinuous layers of material used to line facilities constructed

primarily of non-earthen materials are called ''inner liners11/

and materials used to line facilities constructed of earthen

materials are called "liners".

0    "Storage" means the holding of hazardous waste
     for a temporary period, at the end of which
     the hazardous waste is treated, disposed of,
     or stored elsewhere.

     This new definition expands and clarifies the defin-

ition of "storage" in RCRA. It makes clear that the under-

lying difference between storage and disposal is one of

intent to remove the waste after a limited time, rather

than any difference in facilities and equipment.  The

need for this new definition is discussed in the background

document entitled " Containers and Piles".

0    "Surface Impoundment" or "impoundment" means a
     facility or part of a facility which is a natural
     topographic depression, man-made excavation, or dike
     area formed primarily of earthen materials (although
     it may be lined by man-made materials), which is
     designed to hold an accumulation of liquid wastes or
     wastes containing free liquids, and which is not an
     injection well.  Examples of surface impoundments
     are holding, storage, settling, and aeration pits,
     ponds, and lagoons.

     The analysis of comments received on the proposed

definition of "Surface Impoundment" and the rationale for

the modifications made to the definition in the final

rules is contained in the background document entitled

"Surface Impoundments".

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                       - 4 -
     "Tank" means a stationary device, designed to
     contain an accumulation of hazardous waste which
     is constructed primarily of non-earthen materials
     (e.g., wood, concrete, steel, plastic) which
     provide structural support.

     The analysis of comments received on the proposed

definition of "Storage Tank" and the rationale for the

medications made to the definition in the final rules

is contained on page 10 of this document.

o    "Treatment" means any method, technique, or process,
     including neutralization, designed to change the
     physical, chemical, or biological character or com-
     position of any hazardous waste so as to neutralize
     such waste, or so as to recover energy or material
     resources from the waste, or so as to render such
     waste non-hazardous; safer to transport, store, or
     dispose of; or amenable for recovery, amenable for
     storage, or reduced in volume.

     The analysis of comments received on the proposed

definition and the rationale for modifications made to

it in  the  final  rules is contained on page 16 of this

document.

o    "Totally enclosed treatment facility" means a
     facility for the treatment of hazardous waste
     which is directly connected to an industrial
     production process and which is constructed and
     operated in a manner which prevents the release
     of hazardous waste or any constituent thereof into
     the environment during treatment. An example is a
     pipe  in which waste acid is neutralized.

     The rationale for adding this definition to the final

rules  is contained on page 19 of this document.

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                            - 5 -
III.  Damage Cases


          The following damage cases illustrate the potential

     hazards associated with the improper storage or treatment

     of hazardous waste. They demonstrate the need to regulate

     any type of containment device that is used to treat or

     store hazardous waste — to guard against the damage

     that these kind of operations can entail.  The influence

     which these damage incidents had in establishing the

     final standards for tanks and chemical,  physical,  and

     biological treatment facilities is explained in the

     sections of the document where the individual standards

     are discussed.
          (1)   In 1977,  a 20,000 gallon storage tank filled
               with highly flammable waste (a solvent and
               ethyl acetate)  exploded at a chemical disposal
               site in New Jersey-   Eleven other storage
               tanks were ruptured in the blast, releasing
               heavy chemical  fumes.  Three tanks were blown
               into the air and thrown several hundred feet
               across the plant.  The tanks were intercon-
               nected by a common vapor recovery system
               which could have allowed the flame to propa-
               gate through the system to all the tanks.
               The tanks were  being renovated by a contractor
               at the time of  the fire.  The suspected cause
               of the explosion is improper welding, a
               smoldering cigarette or some other worker-
               related incident.  Six workmen were killed
               and 30 others injured.l

          (2)   Lagooned wastes from a copper reclamation
               company in Noxamixon Township, Pennsylvania,
               had been the source of ground water.-  stream,
               and soil contamination there.  The company,
               which was in operation from 1965 to 1969,

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    bought  industrial  wastes from other plants,
    extracted  copper,  and  stored the rest of the
    toxic  liquids in lagoons.   T'hree of the cement
    lagoons developed  open seans on the bottom
    and  leaked toxic fluids into an adjacent
    creek,  killing all aguatic life.   After an
    injunction was issued  requiring the wastes to
    be treated,  the company defaulted,  leaving
    3  1/2  million gallons  of toxic wastes on the
    site.   Heavy rains in  April 1970 caused the
    lagoon to  overflow and spill the hazardous
    wastes  (e.g., acids, copper, nickel, and iron
    chloride)  into the creek which is a tributary
    of the  Delaware River.  County officials then
    built  a dike around the area.  Soil contami-
    nation  persists at the site and the entire
    area is devoid of vegetation.  In 1971, the
    wastes  were finally neutralized and ocean
    dumped.2

(3)  An open gate valve in  a retention lagoon at
    a  chemical company in  Venango County, Penn-
    sylvania  released phenolic substances to
    Oil  Creek.  Some fish  and turtles were killed
    in the Creek.3

(4)  A  firm engaged in the  disposal of spent chemicals
    was  storing and disposing of toxic chemicals
    at two Louisiana locations.  At one of these
    sites,  several thousand drums of waste (some
    with and some without  lids) were in storaqe.
    Many of the drums were leaking, and visible
    vapors were emanating  from the area.  As a
    result, all of the pine trees beside the storaae
    area were killed ."4

(5)  An employee transferred two 5-gallon cans of
    waste  vinyl cyanide and water from a still to
    a  supposedly empty waste drum.  As the employee
    rolled the drum to a storage area across -the' =•
    road,  it exploded.  Waste materials sprayed
    the  employee.  The drum was thrown 'approxi-
    mately 48 feet, wrapping around a steel quard
    post.   The employee received 'thermal and
    possible chemical burns to both feet.  The
    exothermic reaction that caused the drum to
    rupture was probably a combination of
    cyanoethylation and polymerization.5

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                            - 7 -

          (6)  In 1978, the owner of a facility in Dallas,
               Texas, who had declared bankruptcv, left behind
               the following items on his property: parts of
               an incinerator which burned during a fire,
               acid and alkali recovery basins with a "home-
               made" fiberglass liner, a variety of storaae
               tanks, approximately 150 55-gallon drums, a
               landfill, and a number of other small containers
               of chemicals.  The facility owner had been in
               the business of storing and processing a
               variety of wastes, which included car-wash
               and grease-trap wastes, chromium sludge, acid
               and alkaline wastes, plating waste, cyanide,
               ketones, tannins, and aromatic solvents.
               Water samples, from monitoring wells, at a
               depth of approximately 10 feet detected metal
               comtamination.6

IV.  State Legislation

          EPA reviewed the solid waste management regulations

     and guidelines of several States to ascertain the various

     State approaches to regulating the storage and treatment

     of solid and/or hazardous waste in tanks and in other

     types of facilities used to treat wastes.  The following

     is a synopsis of those aspects of the States' regulations

     or guidelines which the Agency used as models in developing

     the RCRA interim status standards for these facilities.

          Several States'  regulations or guidelines have '

     standards which specifically address the incompatibility

     of stored and/or treated wastes with each other,  or with

     the construction materials of the containment devices

     (i.e.,  containers or tanks) in which the wastes are

     treated or stored.  For example:

     -    Texas,7 Louisiana,^ and Tennessee^ prohibit

          placing incompatible wastes together in the same

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                  - 8 -




containment device.  However, Texas' Guidelines




provide an exception to this rule where the place-




ment of incompatible wastes in the same containment




device is done for controlled neutralization of



acids and alkalies.1°




Texas11 and South Carolina12 prohibit adding




hazardous waste to an unwashed containment device




that previously held a material or waste with




which it is incompatible.




Minnesota13 requires tanks to be constructed of




materials, or protected by a liner, that will not




react chemically with the contained waste, if such




a  reaction may impair the tank's ability to contain




the waste.  Louisiana1'* has a similar requirement,




but it specifies that the construction materials




of the containment device must be resistant to the




emplaced waste for at least the estimated life of




the operation.  A bond, or warranty satisfactory




to the Secretary of Louisiana's Department of




Natural Resources  is required for construction




materials or liners for which historical perfor-




mance data is not  available.




Texas15 and Louisiana1^ require tests to be con-




ducted for determining the compatibility of the




waste to be contained with the construction




materials of the containment device, or with

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                            - 9 -

          the liner used to protect them.*

          In addition to standards which deal with incom-

     patibility, the following other State standards were

     also used as prototypes in developing the Subparts J

     and Q interim status standards:

          Texasl7 specifies that all ponds (which include

          containment devices comparable to uncovered tanks)

          should have adequate freeboard.  The suggested

          height of the freeboard varies from 1 1/2 to 2

          feet, depending upon the characteristics of the

          waste.  For example, Texas'  standards specify that

          Class IA waste (which includes those wastes which

          are classifed to be hazardous in Section 3001 of

          the RCRA rules) should be contained in ponds with

          2 feet of freeboard.

     -    Louisiana^ requires that before introducing

          any new or altered hazardous waste into an existing

          or new treatment sequence, pilot or bench scale

          tests, or reliable operating data, must be obtained

          for the waste.
    * Louisiana's regulations gives owners or operators the option
of collecting data (presumably from the literature or from other
facilities) in lieu of performing the tests themselves.

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    ANALYSIS OF STANDARDS, ORGANIZED BY SUBJECT

Subject;  The Definitions of "Basin" and "Storage Tank"

A.   Proposed Definitions:

     "Basin" means any uncovered device constructed of
artificial materials, used to retain wastes as part of
a treatment process, usually with a capacity of less
than 100,000 gallons.  Examples of basins include open
mixing tanks, clarifiers, and open settling tanks.

     "Storage Tank" means any manufactured non-portable
covered device used for containing pumpable hazardous
waste.  (As defined in §250.41.)

     "Storage Tank" means any manufactured non-portable
covered device used for containing but not treating
hazardous waste.   (As defined in §250.21.)

B.   Rationale for the Proposed Definitions

     BASIN;  The purpose  of the proposed wording of the

definition  of "basin" was to help owners or operators decide

if  the  uncovered containment devices in which they treat

hazardous waste are  "basins" or "surface impoundments".

This distinction was important because the proposed

requirements for surface  impoundments were far more

rigorous than they were for basins.

     The primary characteristic which distinguished

basins  and  surface impoundments in the proposed rules

was the type of materials used to build the containment

devices.  Basins were made out -of man-made, "artificial

materials"  (e.g.,  steel,  plastic, concrete).  Surface

impoundments, on the other hand, could be lined by "arti-

ficial  materials"  (e.g.,  PVC), but the construction

material that provided structural support for surface

impoundments was earthen  material  (e.g., natural  in-place

soil, or reworked/reconstructed soil).

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     A secondary characteristic which the Agency believed



would be helpful to distinguish between basins and surface



impoundments was size.  Because man-made materials are



typically more expensive than earth, basins tend to be



smaller than surface impoundments.  Based on the Agency's



belief that most basins hold less than 100,000 gallons,



the definition of "basin" contained a statement to this



effect.






     STORAGE TANK;  The Agency mistakenly provided two



different definitions of the term "storage tank" in the



proposed rules, one in §250.21, and the other in §250.41.



The two proposed definitions were similar in that they



defined a storage tank to be any manufactured non-portable



covered device used to store hazardous waste.  However,



the definition provided in §250.41 also stated that the



waste contained in storage tanks is pumpable. This was not



intended and has been removed from the final definition.



     The purpose of the proposed wording of the defin-



ition^) of "storage tank" was to help owners or operators



decide if their covered containment devices were "con-



tainers" or "tanks".  Again, the ability to make this-



determination was important because some- of the proposed



requirements for containers were different than those



for tanks.



     The primary characteristic which distinguished con-



tainers and tanks in the proposed rules was size.   Con-

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                       - 12 -






tainers were small enough to be portable, whereas tanks




were too large to be portable  (i.e., they are stationary)






C.   Summary of Comments:




Regarding the definition of "Basin":




1.   The word "uncovered" should be deleted.




2.   The definition should specify whether the term




     "artificial material" means man-made, manufactured,




     not natural in place, or  something else.




3.   The volume restriction of 100,000 gallons should




     be deleted, because containment devices constructed




     of man-made materials frequently have a capacity




     greater than 100,000 gallons.




4.   The public normally understands the word "basin"




     to mean a geologic or topographic depression or a




     small bathroom or kitchen bowl; therefore, the




     term should not be used to stand for a large device




     constructed of artificial materials.






Regarding the definition of "Storage Tank":




5.   The word "covered" should be deleted because:



     -    the storage of a non-volatile waste does not




          require a covered tank.




     -    the word is not part, of the commonly under-



          stood meaning of "tank".  The special need




          for "covered" devices is properly addressed




          elsewhere in the proposed regulations, with




          respect to storing volatile materials.

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                       - 13 -






          the word "covered" places an unwarranted




          limitation on facilities which would be con-




          sidered storage tanks.




          an uncovered steel tank would be designated




          as a "basin".  Consequently, it would require




          ground-water monitoring, even though the absence




          of a cover — by itself — does not signifi-




          cantly increase the potential for contaminating




          ground water-




6.   The word "pumpable" should be deleted from §250.4l(b)(84)



     because:




     -    it makes this definition inconsistent with the




          definition of the same term given in §250.2l(b)(27).




     -    the definition does not specify the circumstances




          under which the material must be "pumpable".




          In some instances, material may be liquid and




          "pumpable" going in, but may become non-pumpable




          during storage — e.g., because of evaporation,




          or reaction,  or solidification, etc.




     -    the storage of solid or semi-solid wastes should




          be permitted.






D.   Analysis of and Response to Comments.;




     The Agency's re-evaluation of its conception of




storage for regulatory purposes now permits storage to




be conducted in uncovered as well as covered devices,




and in devices such as surface impoundments. Thus basins.

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                             - 14 -








as they were defined in the  proposed regulations, are now




recognized as appropriate storage devices.   In addition, the




Agency has recognized that treatment as well as storage may




be conducted in tanks.  These changes have made the proposed




regulations' concepts of basins and storage  tanks essentially




identical, with the exception that one is uncovered and the




other is  covered.  As a result, the Agency has combined the two




concepts  into one: a tank is now defined to be "a stationary




device, designed to contain  an accumulation  of hazardous waste,




v/hich is  constructed primarily of non-earthen materials . . .




which provide structural support."  Tanks are referred to  as




covered or uncovered when appropriate. The terms "basin"




and  "storage tank" have been deleted from the final rules.




     These revisions should  satisfy most of  objections to




including "uncovered" in the definition of "basin", and




"covered" in the definition  of "storage tank"; these object-




ions appear to reflect mainly a discontent with restricting




basins  (uncovered tanks) to  treating waste,  and storage




tanks (covered tanks) to storing it.  The final rules also




contain no standards requiring the use of covered tanks. As




explained in the background  document on Storage and Containers;




the purpose of requiring tanks to be closed  was to control air




emissions. However.- air emissions are primarily a problem  fox-




volatile  waste, and the Agency has deferred  issuing any rules




concerning volatile waste.

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                            - 15 -






       The meaning of the term "artificial materials" was




unclear in the proposed definition of "basin" and has been




replaced by the words "non-earthen ... (e.g., wood, concrete,




steel, plastic)" in the final definition, to make clear the




types of construction materials which can be used to build a




tank.




       The proposed definition of "basin" stated that they




usually had a capacity of less than 100,000 gallons.  The




Agency did not intend owners or operators to interpret this




to mean that containment devices which hold more than 100,000




gallons are excluded from the definition of basin.  Rather,




the statement was included in the definition as general




guidance to help differentiate between basins and surface




impoundments.  However, since the statement seems to have




confused,  rather than helped the regulated community to




distinguish between basins (uncovered tanks)  and surface




impoundments, the Agency has deleted the reference to the




capacity of tanks from the final rules.




       The Agency also agrees that tanks need not be re-




stricted to holding "pumpable" waste,  and this requirement




has been deleted.

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                            - 16 -


II•   Subject;  The Definitions of "Treatment" and  "Treatment

     Facility"


     A.   Proposed Definitions:

          "Treatment" has the same meaning as that given in
     Section  1004 of the Act.

          "Treatment Facility" means any  facility which treats
     hazardous waste.

     B.   Summary of Comments:

        1. The definition of "treatment" should  exclude:

          (a) operations performed to meet Clean Water Act

          requirements  (i.e., it should exclude pretreatment

          of  wastewater to be discharged  to  industrial NPDES

          facilities in the same way that it excludes the

          pretreatment  of wastewater to be discharged to

          POTWs).   Otherwise, wastewater  streams would be

          subject to dual regulation — and  this is  inconsis-

          tent with Section 1006 of RCRA, which requires

          integration with other environmental  laws.

           (b) processing methods and techniques which are

          designed  to reduce  the volume or quantity  of a

          waste  being generated.

           (c) processing operations which'separate  oil and

          water  by  gravity, because the reporting  requirements

          for these facilities  would be staggering.

        2. The definition of  "treatment  facility" should

          exclude,  or differentiate these facilities, from

          resource  recovery  facilities.

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                            - 17 -






     3.   The proposed rules are inequitable because they




         regulate differently two facilities which treat




         waste in an identical manner.  Where waste is rendered




         non-hazardous by being piped directly to a processing




         facility, the facility is not subject .to control




         under Subtitle C.  However, a facility which renders




         its waste non-hazardous with an identical process,




         but after the waste has passed through a surface




         impoundment, is subject to control under Subtitle C.




         In order to eliminate this inequity, the definition




         of "treatment facility" should exclude any facility




         where the waste flows, on a substantially continuous




         basis,  directly from the point of generation, or




         through a storage facility or surface impoundment,




         to a processing facility.




     4.   Facilities which treat their waste on-site (e.g.,




         universities or hospitals which treat waste before




         it leaves the premises) should be exempt from the




         requirements of Sections 3004 and 3005.   Otherwise,




         in a chemistry lab,  every chemical on the shelf




         that has been used once might be considered to be




         a waste, and every successive experiment might be




         considered to be a treatment facility.




C.    Analysis of and Response to Comments;




     la.   The regulations promulgated under the Clean Water



     Act  (CWA) are designed to prevent the discharge of pol-




     lutants to surface waters.  The regulations  promulgated

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                     - 18 -








under Subtitle C of RCRA, on the other hand, are




designed to prevent the discharge of hazardous waste




to ground water, as well as surface waters.  In those




cases where treatment facilities regulated under the




CWA contain hazardous waste, this waste may seep through




the bottom of the  facility to  the ground water, as well




as flow over the rim of the facility to surface waters.




For this reason, the Agency believes that these facil-




ities must be subject to the regulations precribed




under Subtitle C of RCRA, as well as the regulations




prescribed under Section 402 of the Clean Water Act.



     The final rules do not exclude the pretreatment of




all wastewater discharged to POTWs from regulation under




RCRA. The exclusion only applies to domestic sewage or




mixtures of domestic sewage with other wastes that pass




through a sewer  system to a POTW. The rationale for




this is contained  in the Part  261 background document




supporting the exclusions under §261.4(a).






Ib. Processing operations which reduce the volume of a




waste already generated cannot be'excluded'from the




definition of "treatment" because RCRA expressly defines




"treatment11 of hazardous waste, to include any method,




or process, ...  designed  ...  to render such waste  ...




reduced in volume" (emphasis added).  However,- neither




RCRA nor these regulations are intended to govern changes

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                      - 19 -




to production processes made to reduce the volume or




quantity of wastes generated.






lc. & 2. For this same reason, the Agency is also unable




to modify the definition of  "treatment" to exclude gravity




oil/water separation processes.  However/ if the purpose




of the separation process is to extract the waste oil




for reuse, rather than for disposal, the waste oil separa-




tion process would be a resource recovery facility,  and




would be exempt from regulation under the final Phase I




Section 3004 regulations. (See the Part 261 background




document supporting the exclusions under §261.4(b)).






3. The final rules do not exclude all processing facil-




ities in which hazardous waste is received directly from a




production process. Only those which meet the definition




of a "totally enclosed treatment facility" are exempted




from these rules. The key characteristics of such a




facility are that it:




  - does not release any hazardous waste or constituent




    of hazardous waste into the environment during




    treatment, and




  - it is directly connected to. an industrial production




    process.




    The Agency has exempted these facilities from regula-




tion under Subtitle C because they do not release wastes




or waste constituents into the environment,  and therefore



stringent controls are not "necessary to protect human

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health and the environment".   Such  controls might also



discourage the use of  such  facilities, which  in many ways



represent the optimum  in  good  waste management practices.



It may also be very difficult,  as a practical matter, to



permit or otherwise regulate these  types of facilities



— many are indoors, are  part  of complicated  plumbing



systems which do not fall within RCRA's jurisdiction, and



do not have clearly defined starting  and end  points.



    After treatment in a  totally enclosed  treatment



facility, the resulting discharge,  treatment  residue,



etc., may be a hazardous  waste and  subject to regulation



under Subtitle C.  Owners and  operators of such facilities



should consult §261.3  of  the Part 261 rules to determine



whether that is the case.



    Hazardous v/aste treatment  facilities which receive



wastes from a surface  impoundment do  not pose any of the



practical problems mentioned above. They are  not hard to



distinguish from the production processes, and have dis-



crete beginning and end points. They  are thus more prac-



tical to examine in the permitting  process. In addition,



a generator with a totally  enclosed treatment process



would need 'no facility permit  at all,  and  requiring him



to obtain a facility permit would create a substantial



burden for both the Agency  and the  owner or operator



with little corresponding gain. On  the other  hand, a fac-



ility with a surface impoundment will require a facility

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                      - 20A -






permit in any event, and it should be practical and




relatively simple to obtain a treatment permit for an




otherwise totally enclosed treatment process at the




same time.  These factors indicate a sensible regulatory




distinction between a "totally enclosed treatment




facility" at the end of a generator's production process




and a similar facility which draws its wastes from a




surface impoundment.






4. The Agency disagrees with the comment suggesting that




the Section 3004 and 3005 standards should only apply to




off-site treatment facilities.  These regulations are de-




signed to ensure that hazardous waste facilities do not



pose a threat to human health and the environment.




Potential hazards are certainly not posed uniquely by




off-site treatment facilities.  Because on-site treat-




ment facilities pose a potential threat to human health




and the environment equal to that posed by off-site




treatment facilities, the final rules apply to both




types of facilities.




     However, the Agency does not expect that many  uni-




versity chemistry labs will be treatment facilities.




The reason is that the chemicals used for the purpose of




experimentation are not deemed to be wastes until the




experiment is over and the resulting residue needs  to be



stored, treated, or disposed.   That is,  the experiments

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                            - 21 -


      performed in labs are not considered to be treatment

      processes because the substances used to run the experi-

      ments are hazardous chemicals, not hazardous waste.

D.    Final Definitions;

          "Treatment":  (see page 4 above)

          "Totally enclosed treatment facility": (see page 4
          above)

          The definition of "treatment" in the final Part 260

      rules is substantively the same as that which was proposed

      The Agency has rearranged the order of certain phrases in

      the proposed definition in order to maXe it easier to

      understand.

           The proposed definition of "treatment facility" has

      been deleted from the final rules because its meaning was

      obvious and, therefore, defining the term was unnecessary-

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                            - 22 -




III.  Subject:   Compatability of the Waste with the




     Containment Device and/or its liner




     A.    Summary of Proposed Standards 250.44(h),




          250.45-4(b)(l),  (d),  and (e), and 250.45-6(a)




          and  (b)(2);




          The  proposed standards required that the materials



     used to build containment devices  (i.e.,  tanks,  basins,




     and other types of treatment facilities), or the liners




     used to protect them,  must be compatible  both with  the




     hazardous waste to be  stored or treated,  and with the




     treatment reagents that are expected to be used:




          -    under expected operating conditions (250.45-4(e)



               and 250.45-6(a));




          -    so that the  ability of the containment device to




               contain the  waste is not impaired (250.44(h)).



          The  proposed standards further required that the




     waste to  be treated  in containment devices must  be  tested




     to  determine if the waste, or the  reagents to be used




     to  treat  the waste, will have any  detrimental effect on




     the containment device (250.45-4(d)  and 250.45-6(b)(2)).




          Wastes which would damage the construction  materials




     of  a basin were not allowed to be  placed  in the  basin




     (250.45-4(b)(l)).




     3.    Rationale for the Proposed Standards;



          The  service  life  of a containment  device can be




     prematurely shortened  because of harmful  interactions




     between its construction materials and  the waste or reagents

-------
                        - 23 -


it contains.  This interation may include one or more of

the following:

(l)  Corrosion;  Corrosion of containment devices may be
accelerated by the properties of the hazardous waste
itself, or by the chemical reagents used to treat the
waste.  For example, chromic acid (an oxidizing agent)
generally corrodes all metals.  Therefore, it would be
inappropriate to treat hazardous waste with chromic acid
in a steel tank unless the tank is lined with a material
which is relatively inert to chromic acid (e.g., glass,
polyethylene, or PVC).

(2)  Salting and scaling;  Salting and scaling is the
formation of an insulating layer at heat transfer sur-
faces, which could contribute to the failure of evapora-
tion tanks and the subsequent escape of hazardous waste
to the environment.  Salting and scaling may be reduced
or prevented by the preliminary treatment of the influent
waste stream or by other operational controls.

(3)  Pressure:  High pressure (caused, for example, by
mixing wastes which collectively generate large amounts
of gaseous emissions) may cause covered containment
devices to explode, unless the device has been designed
to withstand high pressure.

(4)  Liquid flow rate and mechanical abrasion;  Mechanical
abrasion from materials contained in the waste or high
liquid flow rates may damage the construction materials
of a containment device.  In order to prevent this, it is
important to match the construction material of the device
with the abrasion characteristics of the wastes expected
to be treated, and the anticipated liquid flow rate of
the treatment process.

     The purpose of the proposed standards was to prevent

these sorts of adverse interactions.  This was necessary

in order to prevent the premature deterioration of con-

tainment devices and the subsequent discharge of the

waste they contain to ground water or surface water.

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                       - 24 -






C.    Summary of Comments Received;




     1.   It is unrealistic to try to protect basins from




     "any detrimental effect" which may result from con-




     taining a waste which is incompatible with the basin's




     construction materials because all construction
                                           .:



     materials have an intended useful life (i.e.,  a




     design corrosion rate).   Owners or operators should




     be allowed to choose between a construction material




     with a relatively short  intended life (e.g., carbon




     steel, with an intended  life of five years), which




     requires frequent replacement of the basin,  vs. a




     construction material with a relatively long intended




     life (e.g., stainless steel,  with an intended life




     of ten to thirty years), which allows less frequent




     replacement of the basin.   Therefore, the phrase




     "any detrimental effect" should be replaced  by the




     phrase "any effect which would cause the basin to




     fail prior to closure, or prior to the end of  the




     basin's intended life".



     2.   The restriction on  placing waste in a basin,




     where the waste is detrimental to the basin's  con-




     struction materials,  will preclude the presently




     desirable waste management practice of mixing  spent




     alkaline with spent acid for  the purpose of  neutral-




     ization — because these wastes will cause corrosion




     when tested on the construction materials of the




     basin.  The standard should be revised to allow

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                       - 25 -






     wastes, which by themselves would corrode a basin,




     to be placed in the basin for the purpose of chemical




     reaction under controlled conditions.




D.   Analysis of and Response to Comments;




  1 & 2.  The Agency agrees with the commenter's general




     argument that containment devices need not be designed




     to last forever.  Although the Agency would prefer




     that hazardous waste be treated or stored in devices




     which will not be detrimentally affected by these




     operations, the Agency recognizes that, inevitably,




     the construction materials of most containment




     devices will be somewhat impaired by the physical




     or chemical properties of the waste they contain.



          The Agency's concern is not so much with the




     gradual deterioration of a containment device — as




     long as this deterioration is monitored, and the




     device is repaired or replaced as needed (see the




     §265.15 inspection requirements) — as with the




     rapid impairment of a device's containment capabilities




     due to adverse interactions between the device's




     construction materials and the wastes it contains.




          In response to the comments, the final rules




     have been modified to prohibit placing wastes in




     containment devices if so doing would impair the




     ability of the device to contain the waste during its




     intended life.  Unlike the proposed rules, the focus

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                       - 26 -

     of the final standard is solely on placing wastes

     into devices.  The proposed approach, which regu-

     lated both the types of materials used to build

     devices and the kinds of wastes that could go in

     them, was redundant.  As long as the waste that is

     placed into the devices is controlled, the purpose

     of the proposed standards (i.e., to prevent the

     rapid deterioration of these devices) will be

     achieved.


E.    Final Regulation Language;

§265.192  General operating requirement*

     (b)  Hazardous wastes or treatment reagents must not
be placed in a tank if they could cause the tank or its
inner liner to rupture, leak, corrode, or otherwise fail
before the end of its intended life.



§265.401  General operating requirement*

     (b)  Hazardous wastes or treatment reagents must not
be placed in the treatment process or equipment if they
could cause the treatment process or equipment to rupture,
leak, corrode, or otherwise fail before the end of its
intended life.

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                            - 27 -




IV.  Subject:  Continuous Feed Operations




     A.   Summary of Proposed Standard  250.45-6(g);




          The proposed standard required that facilities which




     continuously feed hazardous waste  into containment devices




     used to treat hazardous waste must have a waste feed




     cutoff or a by-pass system which turns on automatically




     when the treatment process breaks  down.




     B.   Rationale for the Proposed Standard;




          The Agency believed that it makes little sense to




     add hazardous waste to a containment device  in which the




     waste already contained therein is not being treated




     effectively.  In addition, where the breakdown of the




     treatment process poses a threat to human health and the




     environment  (e.g., when an unanticipated reaction between




     a  reagent and a waste generates excessive heat), the




     inflow  of additional waste into the device may exacerbate




     the problem  and thereby increase the dangers associated




     with the malfunction of the treatment process.




          Therefore, the Agency believed that facilities with




     continuous feed operations should  be equipped with fail-safe




     mechanisms (i.e./ waste feed cutoff or by-pass systems)




     capable of stopping the flow of waste into a containment




     device  in which the treatment process is not working.




     C.   Summary of Comments Received:



          1.   It is unnecessary to require that  automatic waste




          feed cutoff or by-pass systems be installed in all




          treatment facilities.  Instead, the standard should:

-------
                       - 28 -




               allow a facility to use other mechanisms




               (e.g., dikes or collection ponds) which




               will contain waste discharges if a mal-




               function occurs 7




          -    require that a facility have adequate




               instrumentation and controls to ensure




               safe operating conditions.




     2.   The standard should be recast to acknowledge




     that not all malfunctions are severe enough to



     cause hazardous waste to be discharged to the




     environment.  Automatic cutoffs or by-passes,  if




     required at all, should only have to be triggered



     by malfunctions which might cause discharges.




     3.   EPA should clarify whether the the use of the




     word "by-pass" in the proposed standard is meant




     to be interpreted in the way the chemical industry




     uses the term, i.e., "shunt,  to the downstream




     side of a process or piece of equipment".




D.    Analysis of and Response to Comments;




     1.   The Agency still believes that the best way to




     minimize the potential dangers associated with a



     system failure (e.g., a-malfunction in the treatment




     process, or a crack in the tank) is to prevent addi-




     tional waste from flowing into a tank.   The Agency



     disagrees that facilities should be allowed to con-




     tain the overflow from a tank — with dikes or




     collection ponds — instead of preventing the  inflow

-------
                  - 29 -




of a waste to a tank.  The Agency believes that




every reasonable effort should be made to confine




waste to the interior of a tank, and only after




these efforts have failed, should waste be allowed




to flow into secondary containment devices (e.g.,




dikes or collection ponds).




     However, the Agency agrees that mechanisms




other than those specified in the proposed standard




should be allowed to prevent the inflow of waste to




tanks.  For example, a manual waste feed cutoff




system may be just as effective as an automatic




waste feed cutoff system to prevent the inflow of




waste to a tank.  For this reason, the Agency has




revised the standard in terms of a performance stan-




dard.  The final standard requires that facilities




at which hazardous waste is continuously fed into




tanks be equipped with a means to prevent the inflow




of waste to the tank, but it does not require that




any particular method(s) be used to accomplish this




objective.




2.   The Agency recognizes that there may be situa-




tions where the malfunction of a treatment process




does not pose a threat to human health and the environ-




ment (e.g., where an aerator is not aerating an




industrial wastewater with 100% efficiency).  In




such situations, the addition of more waste to the




treatment facility may not significantly exacerbate

-------
                       - 30 -

     the situation.  The Agency agrees that under such

     circumstances, an owner or operator should not be

     required to prevent waste from flowing into a tank.

     Therefore, the final standard indicates that the

     equipment used to prevent inflow to a tank need

     only be activated in the event of a leak or over-

     flow from the tank due to a system failure (e.g.,

     a malfunction in the treatment process, a crack

     in the tank, etc.).

     3.   Because the Agency's use of the term "by-pass"

     is consistent with the way it is used in the chemical

     industry, and the way it is defined in the dictionary,

     the Agency believes that further clarification of

     the term in these regulations is unnecessary.

E.   Final Regulation Language:

§265.192  General operating requirement*

     (d)  Where hazardous waste is continuously fed into
a tank, the tank must be equipped with a means to stop
this inflow (e.g.f a waste feed cutoff system of by-pass
system to a stand-by tank).

[Comment:  These systems are intended to be used in the
event of a leak or overflow from the tank due to a system
failure (e.g., a malfunction in the treatment process,
a crack in the tank, etc.)]


§265.401  General operating requirement*

     (c)  Where hazardous waste is continuously fed into a
treatment process or equipment, the process or equipment
must be equipped with a means to stop this inflow (e.g.,
a waste feed cut-off system or by-pass system to a standby
containment device).

[Comment;  These systems are intended to be used in the
event of a malfunction in the treatment process or
equipment.]

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V.   Subject;  Freeboard




     A.   Summary of Proposed  Standard  250.45-6(e):




          The proposed  standard  required  that  at  least two




     feet of freeboard  be provided  for  each  containment device




     used for treating  hazardous waste.




     B.   Rationale  for the  Proposed  Standard;




          Hazardous  waste may  spill or  splash  over  the rim  of




     an  open-topped  containment  device  (i.e.,  uncovered tank




     or  surface  impoundment)  for a  number of reasons, which




     include:



          -    the  acceleration  of  a  treatment facility's




                liquid  flow  rate  past  that for  which the facility




                is  designed;



          -    careless pouring  of  additional  waste into  a




                partially full containment device;




          -    an  unanticipated  reaction between two incom-




                patible wastes which causes them to boil-over;




           -    wave-action on a  windy day in containment




                devices with large surface areas;  and




           -    major precipitation.



           The  purpose of the required two feet of freeboard



      was to prevent such spilling or splashing and thus  reduce




      the potential for spilled or splashed waste to contaminate




      ground water or surface water.



           The  Agency's choice of two feet as the required




      height of the freeboard was based on the State of Texas'




      guidelines for ponds,  which specify that a minimum of

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                       - 32 -






two feet of freeboard should be maintained for ponds




containing hazardous waste.




     Additional support for requiring owners or operators




to maintain at least two feet of freeboard in large,




uncovered containment devices is contained in several




technical documents (e.g., in the proceedings from a




symposium on upgrading wastewater stabilization ponds-^,




an EPA design manual for upgrading wastewater treatment




plants^O, and an environmental engineers' handbook on




water pollution21).




C.   Summary of Comments Received:




     In many cases, a freeboard of less than two feet




will be sufficient to prevent hazardous waste from splashing




or spilling during treatment.   Therefore, a "note" should




be added to the standard which allows using less than two




feet of freeboard where:




     -    there is a collection and drainage area surrounding




          the reaction vessel which has restricted access




          during operation (the commenter did not explain




          exactly what he meant by the phrase "which has




          restricted access during operation");




     -    an equivalent degree of protection is  provided.




D.   Analysis of and Response to Comments;




     The Agency agrees that secondary containment




systems — dikes, trenches, drainage to another  treatment




system, diversion to a stand-by tank, etc. — may provide

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                       - 33 -
a degree of protection from splashing and spillage equal




to that provided by two feet of freeboard.  The interim




status standards for tanks do not require secondary




containment systems (see the Foreword of this document).




However, the Agency believes that facilities with interim




status should be allowed to use existing containment




systems to prevent hazardous waste from spilling or




splashing from tanks to the ground water or surface




water.  Therefore, the final interim status standard for




tanks require that facilities have either (1) two feet




of freeboard, or (2) a containment structure (e.g., dike




or trench), drainage control system, or diversion structure




(e.g., standby tank) which has a capacity that equals




or exceeds the volume of the top two feet of the tank.




     The Agency has not included a freeboard requirement




in the final Subpart Q standards. Unlike tanks,  which can




be uncovered, to the Agency's knowledge the treatment




processes regulated under Subpart Q are conducted in




covered containment devices and maintaining freeboard




in these devices is thus unnecessary.

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                       - 34 -


E.   Final Regulation Language;

$265.192  General operating requirement*

     (c)  Uncovered tanks must be operated to ensure at
least 60 centimeters (2 feet) of freeboard, unless the
tank is equipped with a containment structure (e.g., dike
or trench), a drainage control system, or a diversion
structure (e.g., standby tank) with a capacity that equals
or exceeds the volume of the top 60 centimeters (2 feet)
of the tank.

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                            - 35 -






VI.   Subject;  Waste Analyses and Trial Treatment Tests




     A.   Summary of Proposed Standards 250.45-6(b) and  (c)




          The proposed  standards required  that waste analyses




     and trial tests be conducted in part  in order to:




          -    identify the proper  treatment technique for




               each type of hazardous  waste treated at the




               facility;



               determine if the waste  is contaminated with




               substances which might  interfere  with the




               treatment of the waste  or damage  the contain-




               ment device; and



               ensure  that each new or significantly different




               waste accepted at the facility  can be treated




               effectively with the process  used at the  facility.




      B.    Rationale  for the Proposed Standard




           Carelessness and haphazard experimentation with




      different treatment techniques on large quantities  of




      hazardous waste  (e.g.,  the quantity which is contained in




      a tank) can adversely affect  human health and  the environment




      if the waste is  incompatible  with the treatment process




      or the chemical  reagents  used to treat the waste.   For




      example, adding a strong oxidizing agent  (e.g.,  chromic




      acid) to a  steel  tank full  of an unknown  waste may  generate




      toxic fumes, excessive heat,  fires,  explosions,  or  may




      cause the tank to corrode rapidly.

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                       - 36 -






     The purpose of the proposed standard was to dis-




courage the large scale "hit or miss" approach to hazardous




waste treatment by requiring that an owner or operator




conduct bench scale (or pilot scale) tests to determine




the effectiveness and safety of the treatment technique




intended to be used at the facility.




C.   Summary of Comments Received:




     1.   Requiring that a hazardous waste be tested




     before placing it in a basin (§250.45-4(d))  is inappro-




     priate when applied to the continuous flow of an




     industrial wastewater through a treatment process




     unit.




     2.   Requiring trial treatment tests for each new or




     significantly different waste accepted at a treatment




     facility may result in needless duplicative testing




     where the waste has already been shown to be compatible




     with the process in question at similar facilities.




     3.    A treatment facility should have to submit to



     the permit authority the type of information described




     in §250.45-6(b) and (c) before a significant new




     waste can be handled at the facility.



     4.    A list of analytical tests should be developed




     to help the owner or operator determine which processes




     are appropriate for the treatment of his waste.   This




     list should include such tests as:   total quantitative




     analysis, leach test,  explosives testing, flammability

-------
                   - 37 -






tests, corrosivity tests, oxidative tests, and




toxicity determinations.




5.   The word "proper" in §250.45-6(b)(1) should be




replaced with the word "appropriate" because the




word "proper" suggests that there is only one treat-




ment technique, feed rate, operating condition,  etc.




for a particular hazardous waste.




Analysis of and Response to Comments;



1.   It was the Agency's intent, in the proposed




rules, to require the testing of industrial waste-



water flowing through a treatment process unit only




(a) when the process is initially started up,




(b) when the influent waste stream changes signifi-




cantly, or (c) when the process used to treat the




wastewater is changed or is significantly modified.




The final rules have been redrafted along these




lines.




2.   The Agency agrees that an owner or operator




should not have to perform waste analyses or trial




tests where the information needed to ensure that




the regulations will be complied with has been




obtained at, and is available from other facilities




which have performed similar storage or treatment of




similar waste under similar operating conditions.




Therefore, the regulations have been revised to



exempt owners or operators from the waste analyses

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and trial test requirements where such information




is available from other sources.  However, reliance




on information from other facilities does not relieve




the owner or operator of primary responsibility




should the information he has obtained from other




sources prove to be incorrect, and damage to human




health or the environment occurs.



3.   It might be desirable for EPA to review the




results of each waste analysis and trial test before




a new or significantly different waste could be




handled at a facility-  This review would enable EPA




to prevent the storage/treatment of waste where the




Agency believes the owner or operator has misinter-



preted the results of the tests with respect to a



planned course of action.  However, the number of




reviews which EPA would have to conduct if it required



owners or operators to obtain EPA review of their test




results before a new or significantly different waste




could be managed, makes such a requirement impractical



because EPA lacks sufficient manpower to provide a




timely turn-around of the test results.  In addition,




it is unclear whether the added increment of safety is



enough to be worth the added burden to the Agency and




to owners and operators.  Furthermore, the results of




these waste analyses and trial tests will be available



to the Regional Administrator.  Because these results

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                  - 39 -








will be reviewed when the facility's application for




a permit is evaluated, the Agency believes that this




review process will encourage owners or operators to




conduct thorough analyses/tests and to take the




course of action which the test results indicate




should be taken.




     It should be noted that the final interim status




standards do not include a revision of paragraph (iv)




and  (v) of proposed §250.45-6(b).  These parts of




the proposed standard dealt with issues (i.e., volatile




and highly toxic substances) for which EPA is deferring




action.  Therefore, although prior review of test




results is not required for the final interim status




standards corresponding to proposed §250.45-6(b)(i),(ii




and  (iii), the Agency is deferring its decision as




to whether Agency review of the test results will be




required before the waste can be managed, where the




tests indicate that highly toxic substances or toxic




air  emissions will be generated during the intended




storage or treatment process.




4.   The Agency agrees that owners or operators should




be given guidance to help them select an appropriate




process to treat their waste.  The Agency is in the




process of developing a guidance manual which will




describe the types of analytical tests requested by




the  commenter.

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                       - 40 -



     5.  The Agency agrees that there may be a number of

     treatment techniques, chemical reagents, operating

     conditions, etc. that are appropriate for the treatment

     of a particular waste.  Any implication that there

     is only one "proper" treatment process for each type

     of waste has been eliminated from the final rules.


E.   Final Regulation Language:

§265.193  Waste analysis and trial tests*

     In addition to the waste analysis required by §265.13,
whenever a tank is to be used to:

     (l)  Chemically treat or store a hazardous waste
     which is substantially different from waste previously
     treated or stored in that tank; or

     (2)  Chemically treat hazardous waste with a substan-
     tially different process than any previously used
     in that tank;

the owner or operator must, before treating or storing
the different waste or using the different process:
     (l)  Conduct waste analyses and trial treatment or
     storage tests (e.g., bench scale or pilot plant
     scale tests); or

     (2)  Obtain written, documented information on
     similar storage or treatment of similar waste under
     similar operating conditions;

to show that this proposed treatment or storage will meet
all applicable requirements of §265.l92(a) and (b).

[Comment;  As required by §265.13, the waste analysis plan
must include analyses needed to comply with §§2.65.198 and
265.199.  As required by §265.73,- the owner or operator
must place the results from each waste analysis and  trial
test, or the documented information, in the operating
record of the facility-]

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                        - 41 -
§265.402  Waste analysis and trial tests*

     In addxtion to the waste analysis required by §265.13,
whenever:

     (l)  A hazardous waste which is substantially different
     from waste previously treated in a treatment process
     or equipment at the facility is to be treated in that
     process or equipment, or

     (2)  A substantially different process than any pre-
     viously used at the facility is to be used to chemi-
     cally treat hazardous waste;

the owner or operator must, before treating the different
waste or using the different process or equipment:

     (1)  Conduct waste analyses and trial treatment tests
     (e.g., bench scale or pilot plant scale tests); or

     (2)  Obtain written, documented information on similar
     treatment of similar waste under similar operating
     conditions;

to show that this proposed treatment will meet all applicable
requirements of §265.401 (a) and (b).

[Comment;  As required by §265.13, the waste analysis
plan must include analyses needed to comply with §§265.405
and 265.406.  As required by §265.73, the owner or operator
must place the results from each waste analysis and trial
test, or the documented information, in the operating
record of the facility=J

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                             - 42 -






VII.  Subject;  Inspections




      A.   Summary of Proposed Standard 250.45-4(h):




           The proposed standard required that basins be visually




      inspected in accordance with §250.43-6, and that any damage




      detected during the inspection be repaired immediately.




           §250.43-6 called for the daily visual inspection of




      several specific components of hazardous waste facilities,



      plus the recording of these inspections in the facility's




      daily operating log.   The daily inspection requirement




      could be relaxed for certain aspects of the facility's




      operation if the owner or operator could demonstrate




      that lesser requirements would still adequately protect




      human health and the environment.




      B.   Rationale for the Proposed Standard;




           The purpose of the proposed §250.43-6 standards is




      discussed in the background document entitled "Inspections".




           The purpose of the requirement that any damage detected




      during the visual inspection be repaired immediately,




      was to assure not only that damage to basins is detected,




      but that corrective measures are speedily taken to repair




      the damage.




      C.   Summary of Comments Received;




           1.   The requirement that basins be repaired "imme-




           diately" , should be revised to require that damage




           be repaired:




                     as soon as practicable

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                        - 43 -






               in time to prevent a substantial present




               or potential hazard to human health and



               the environment




     because using the word "immediately" might subject




     owners/operators to penalties, even though they took




     prompt action in good faith.  In addition, under




     certain circumstances (e.g., strikes, inclement




     weather, the need to remove the waste before repairing




     the basin),  it may be impossible to carry out repairs




     immediately.




     2.   Daily inspection is unnecessary because dike




     failure is a long term event with early warning




     signs such as wet spots or dead or unusually lush




     vegetation in a limited area of the dike.  Further-




     more, the daily inspection aspect of the standard




     could be counterproductive because it could lead to




     superficial inspections.




     3.   The inspections required in items 1 through 7




     of §250.43-6(a) are redundant for facilities regulated




     under OSHA's safe employment regulations, the Clean



     Water Act, the Clean Air Act, as well as state and




     local regulations.




D.   Analysis of and Response to Comments;



     1.   The Agency agrees that it may not always be




     possible to "immediately" repair damage noted during




     the inspection of a facility.  In some cases, immediate



     repair, although desirable, may not be necessary.  For

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                  - 44 -






example, the presence of rust in the wall of a tank




should be remedied, but human health and the environ-




ment will not be placed in serious jeopardy, under




most circumstances, if the tank is not repaired for




a week or two.  Therefore, the final inspection




standards require that any damage or adverse con-




dition detected during the inspection must be




corrected before it can result in a pollution




incident.  Where an incident is imminent or has




already occurred, the final standards require that




repair be made as soon as possible.




2.   The response to comments concerning the daily




inspection aspect of the proposed §250.43-6 standards




is contained in the background document entitled




"Inspections".  The final general inspection stan-




dards (§265.15) require owners or operators to develop



their own inspection schedule.  The inspection




schedule is to be based on the owner's or operator's




knowledge of the facility's critical processes,



equipment, and structures, and on his perception




of the potential for failure and the rate of any




deterioration processes (corrosion, erosion, etc.)




which may lead to failure.




     In addition, owners or operators of tanks must




comply with certain minimum inspection requirements




specified in the final standards for tanks.  The




rationale for including minimum inspection require-

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                  - 45 -




ments in each of the technical sections of the final




regulations, is contained in the background document




entitled "Inspections".




     The minimum inspection requirements for tanks




and chemical, physical, and biological treatment




facilities are divided into two categories:  those




aspects of the facility which require inspection




each operating day, and those which require inspection




each week.




     Damage  incident #3 on page 6 of this document




illustrates  that the spill control equipment of




storage/treatment facilities (e.g., a tank's valves)




needs to be  inspected each operating day because of




the vital role (i.e., preventing the inflow to, or




containing the overflow from containment devices)




that such equipment plays at these facilities in




preventing a malfunction which could quickly threaten




human health or the environment.  Similarly, the




Agency believes that the data gathered from monitoring




equipment (e.g., pressure and temperature gauges)




must be checked each operating day because of the




important role that this data plays in ensuring that




the facility is running according to plan".




     On the  other hand, because deterioration




resulting from corrosion or erosion normally occurs




relatively slowly, the Agency believes that the




construction materials of tanks and spill confinement

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                            - 46 -


          structures (e.g., dikes) should only have to be

          inspected once a week.  Weekly inspection should be

          adequate to detect corrosion or erosion long before

          the tanks or spill confinement structures are likely

          to fail-*  The final standards also require weekly

          inspection of the grounds surrounding the tanks and

          spill confinement structures for obvious signs of

          leakage.   Damage incident #4 illustrates the type

          of obvious signs of trouble (e.g.,  dead vegetation,

          visible air emissions) which signal the failure of a

          containment device.

          3.   Response to comments concerning the alleged

          overlap of the proposed §250.43-6 standards with

          the inspection requirements of other Acts,  is

          contained in the background document entitled

          "Inspections."
     *    Support for a weekly inspection requirement for
these aspects of facilities is contained in several of the
comments received on the proposed §250.43-6 standards.

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                        - 47 -
E.   Final Regulation Language;

§265.194  Inspections

     The owner or operator of a tank must xnspect, where
present:

     (1)  Discharge control equipment  (e.g., waste feed
     cut-off systems, by-pass systems, and drainage systems),
     at least once each operating day, to ensure that it
     is in good working order;

     (2)  Data gathered from monitoring equipment (e.g.,
     pressure and temperature gauges), at least once
     each operating day, to ensure that the tank is being
     operated according to its design;

     (3)  The level of waste in the tank, at least once
     each operating day, to ensure compliance with
     §265.l92(c)7

     (4)  The construction materials of the tank, at
     least weekly, to detect corrosion or leaking of
     fixtures or seams; and

     (5)  The construction materials of, and the area
     immediately surrounding, discharge confinement struc-
     tures (e.g., dikes), at least weekly, to detect
     erosion or obvious signs of leakage (e.g., wet spots
     or dead vegetation).

[Comment:  As required by §265.l5(c), the owner or operator
must remedy any deterioration or malfunction he finds.]
§265.403   Inspections

     The owner or operator of a treatment facility must
inspect, where present:

     (l)   Discharge control and "safety equipment (e.g.,
     waste feed cut-off systems, by-pass systems, drainage
     systems, and pressure relief systems) at least once
     each  operating day, to ensure that it is in good
     working order;

     (2)   Data gathered from monitoring equipment (e.g.,
     pressure and temperature gauges), at least once
     each  operating day, to ensure that the treatment
     process or equipment is being operated according
     to its design;

-------
                       - 48 -
     (3)  The construction materials of the treatment
     process or equipment, at least weekly, to detect
     corrosion or leaking of fixtures or seams;  and

     (4)  The construction materials of, and the area
     immediately surrounding, discharge confinement
     structures (e.g., dikes), at least weekly,  to
     detect erosion or obvious signs of leakage (e.g.,
     wet spots or dead vegetation).

[Comment:  As required by §265.l5(c), the owner or
operator must remedy any deterioration or malfunction
he finds . "]

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                              _ 49 -






VIII.  Subject;  Closure




       A..   Summary of Proposed Standards  250.45-4Ch) and




            250.45-6(h) and  (i);




            The proposed standards required that when a basin




       closes, all hazardous waste and hazardous waste residues




       contained in the facility must be removed from it and




       disposed of  (250.45—4(h)), or treated  or disposed of




       (250.45-6(h) and (i)), as a hazardous  waste.




            In addition, when removing residues from a treatment




       facility  (either when the facility  closes,  or when  simply




       cleaning the facility),  the proposed standards required




       that the residues must be assumed to be hazardous unless




       they are analyzed and found not to  be  hazardous, within




       the meaning  of  the  proposed Section 3001 regulations.




       However, testing to prove that a residue is non-hazardous




       was not required where the owner or operator could  demon-




       strate that  the residue  is similar  to  a non-hazardous




       residue that was previously generated  at the facility.




       B.   Rationale  for  the Proposed Standards;




            Although  it may  be  obvious that because basins and




       treatment  facilities  are.temporary  containment^devices,




       the hazardous  waste contained  in them  must-be removed




       when the  facility closes,  it may not be as  obvious  that




       the hazardous  waste residues that  settle to the bottom of




       basins or  treatment facilities must also be removed before




       closure.   The  Agency  believed  that  hazardous waste  residues




       must be removed from the facility because the structural

-------
                             - 50 -


     material of the facility is eventually going to fail*

     (i.e., crack or corrode), and the subsequent discharge of

     the residue from the damaged facility may contaminate

     ground water or surface water.  Damage incidents #2 and

     #6 on pages 5-6 of this document illustrate the type of

     damage which may result when hazardous waste is left in

     containment devices after the facility has closed.

          Although some of the residues generated in treatment

     facilities (e.g.,  sludges which settle to the bottom of

     the containment device, or by-products generated during

     the treatment process itself) may have been rendered

     non-hazardous during the process of treating the waste,

     the Agency believed that most of the residues generated

     in treatment facilities are hazardous.  Therefore, to

     discourage owners  or operators from making hasty and

     perhaps erroneous  assumptions about the nature of the

     residues which they generate, the Agency wrote the proposed

     standard to require that residues be treated or disposed

     of as hazardous waste unless they are proven to be non-

     hazardous .
     * In fact, prolonged contact of the residue with the
insides of the basin may even accelerate its deterioration
if the residue is corrosive or incompatible with basin's
structural materials.

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                        - 51




C.    Summary of Comments Received:




     1.   The requirement to remove all hazardous waste and




     hazardous waste residues from treatment facilities is




     inconsistent with §250.45-3(e)(l), which does not require




     removing the waste or residues of a surface impoundment




     which meets the landfill requirements of §250.45-2.




     2.   Residues should only have to be analyzed to




     determine whether they are hazardous if owners or




     operators have reason to believe that their residues




     are hazardous.  This suggestion is consistent with




     page 58951 of the proposed  Preamble, which states




     that such testing is only required when the generator




     has reason to believe that his waste is hazardous.




     3.   The requirement that the residue be analyzed to




     determine whether it is hazardous "within the meaning




     of Subpart A" is too broad, because Subpart A includes




     "the broad criteria of the  statutory standard in




     §250.12 and the bases for listing in §250.14." The




     requirement for residue analysis  should be consistent




     with the analysis required  of generators of solid




     waste who know or who have  reason to believe that




     their waste is hazardous.   That is, the waste should




     be evaluated  in accordance  with the characteristics




     set forth in  §250.13.




     4.   The 100  kg exemption for generators should apply




     to facility operators who generate residues through




     treatment.

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                        - 52 -




D.   Analysis of and Response to Comments;




     1.    The Agency did not intend that proposed




     §250.45-6(h) apply to surface impoundments closed in




     accordance with the landfill closure requirements.




     However, this intention was not reflected in the



     proposed standard.  The final rules have been written




     to reflect the Agency's original intent.




     2.    The Agency believes that most residues resulting




     from treatment processes are hazardous wastes.  For



     this reason, the final Part 261 rules specify that




     all such residues are hazardous unless the owner or




     operator can demonstrate otherwise.  A more detailed




     explanation for this provision is contained in the




     Part 261 background document supporting the definition




     of hazardous waste in §261.3.



     3.    The Agency agrees that the proposed requirement




     to analyze the residue "within the meaning of Subpart A"



     was somewhat broad.  The final rules specify that all




     residues generated from treatment processes are hazard-




     ous waste unless the owner or operator can demonstrate,




     in accordance with §261.3(f) of Part 261, that the



     residue is not a hazardous waste.  As is further ex-




     plained in the background document for Part 261, this



     means that the residue need not be tested against a




     particular characteristic if no incoming waste was




     found hazardous under that characteristic, and that




     the residue need not be measured against the criteria



     for delisting a listed waste unless some incoming waste

-------
  was a listed waste. The Agency does not agree that the

  residue should not be measured against the criteria for

  listing wastes so long as one of the incoming wastes

  was listed.

  4.    The final rules specify that, by removing a residue

  from a tank or treatment facility, the owner or operator

  becomes a generator of hazardous waste and must manage it

  in accordance with all applicable requirements of Parts

  262, 263, and 265 of the final Subtitle C rules.  Any

  special exemptions pertaining to generators in these rules

  also apply to owners and operators generating residues.


E.   Final Regulation Language;

§265.197  Closure

     At closure, all hazardous waste and hazardous waste
residues must be removed from tanks, discharge control
equipment, and discharge confinement structures.

[Comment;  At closure, as throughout the operating period,
unless the owner or operator can demonstrate, in accordance
with §261.3(f) of this Chapter, that the residue removed
from his tank is not a hazardous waste, the owner or
operator becomes a generator of hazardous waste and must
manage it in accordance with all applicable requirements
of Parts 262, 263, and 265 of this Chapter.]


§265.404  Closure

     At closure, all hazardous waste and hazardous waste
residues must be removed- from treatment processes -or"   -
equipment, discharge control equipment, and discharge
confinement structures.

[Comment;  At closure, as throughout the operating period,
unless the owner or operator can demonstrate, in accor-
dance with §261.3(f) of this Chapter, that the residue
removed from his treatment process or equipment is not a
hazardous waste, the owner or operator becomes a generator
of hazardous waste and must manage it in accordance with
all applicable requirements of Parts 262, 263, and 265 of
this Chapter.1

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                             - 54  -



[X.   Subject;   Special  Requirements  for  Ignitable and




     Reactive  Waste




     A.     Summary of Proposed Standard  250.45-4(b)(2)  and (3):




          The  proposed  standard prohibited owners or  operators




     from  placing  ignitable  or reactive  waste  in  basins unless




     he  could  demonstrate  that doing so  would  not:




          -    produce  more  air contaminants than the permissible




               exposure levels promulgated by  OSHA, or




               damage the  structural integrity of the basin




               through  fires,  explosive  reactions, or the




               generation  of heat.




     B.    Rationale  for the  Proposed Standard;




          The  Agency was concerned about owners or operators




     placing ignitable  and reactive  waste in containment devices




     because the waste  may come in contact with materials  with



     which it  will ignite  or react and thereby cause  a  fire




     or  explosion, or generate excessive heat.  Damage  incident




     #1  on page 5  of this  document exemplifies  the types of




     dangers which can  result  from placing ignitatale  waste in




     containment devices.



          Generating excessive heat  or causing  a  fire or explo-




     sion  in a containment device  in which hazardous  waste is




     treated or stored,  poses  a serious  threat  to human health




     and the environment because:



               it  could generate hazardous air  emissions which




               may endanger  the health and lives  of the facility's




               personnel and neighbors ;

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                        - 55 -






          it could damage the structural integrity of




          the basxn through heat, fires, or explosive




          reactions, and allow hazardous waste to be




          discharged from the device to ground water or




          surface water;




     -    it could ignite nearby flammable waste.




     To prevent this type of damage, the proposed stan-




dard restricted but did not prohibit the placement of




ignitable or reactive waste in basins, since the Agency




wished to encourage facilities to treat rather than




dispose of hazardous waste.  Conditions for a variance




from the proposed standard were included in the proposed




rules, allowing owners or operators to place ignitable




or reactive waste in basins if so doing would not (l) damage




the structural integrity of the basin as a result of heat




generation, fires, or explosive reactions; or (2) contribute




air contaminants in excess of the permissible exposure




levels promulgated by OSHA.




C.   Summary of Comments Received:




     1.   The provision of the "Note" to the standard




     which required that owners or operators demonstrate




     that their treatment operations do not contribute




     air contaminants in excess of the permissible exposure




     levels promulgated.by OSHA is objectionable because




     this would:



               use RCRA to regulate air contaminants




               within the regulatory authority of the

-------
                   - 56 -








          Clean Air Act and OSHA and, thus, would




          conflict With RCRA's Section 1006 mandate




          regarding the application and integration




          of RCRA with other environmental laws.




          misuse the OSHA exposure limits which were




          derived from Threshhold Limit Values  (TLVs)




          developed by the American Conference of




          Governmental Industrial Hygienists (ACGIH),




          because the ACGIH has placed the following




          restrictions on the use of the TLVs:  the




          limits "are not intended for use, or for




          modification for use, (l) as a relative




          index of hazard or toxicity.- (2) in the




          evaluation or control of community air




          pollution nuisances, (3) in estimating the




          toxic potential of continuous, uninterrupted




          exposures ..." .




               Furthermore,  the proposed use of OSHA




          limits is technically more stringent than



          the compliance requirements under OSHA




          itself.  OSHA applies these limits to human




          exposure, and allows administrative controls



          and protective equipment for compliance.




Therefore, the restriction on placing ignitable and




reactive waste in basins should be modified to allow



placing such waste in basins for the purpose of




treatment if such treatment will not:

-------
               violate any applicable standard promulgated



               under the Clean Air Act; or



               damage the structural integrity of the



               basin through heat generation, fires, or



               explosive reactions.



     2.   The restriction on placing ignitable and reactive



     waste in basins should be deleted because basins com-



     prise major elements of treatment systems and, there-



     fore, must contain such wastes in order to treat them.



D.   Analysis of and Response to Comments;



     1.   The Agency agrees that the OSHA air contaminant



     exposure figures are not generally appropriate for the



     circumstances of waste treatment, storage, and disposal



     facilities, and they have been deleted from the regu-



     lations.  In addition, the Agency is deferring promul-



     gation of regulations dealing with volatile wastes



     under Section 3004, as explained in the preamble dis-



     cussion entitled "Volatile Waste."  Other standards for



     the treatment of ignitable, reactive, and incompatible



     wastes are discussed in the preamble.



     2.   The Agency still believes that certain restrict-



     ions are needed on placing ignitable or reactive



     waste in tanks and in chemical, physical, and



     biological treatment facilities.  The final rules



     permit alternative approaches.  An owner or operator



     may treat ignitable or reactive waste so as to render



     the waste non-ignitable or nonreactive.  This



     provision minimizes the potential for such waste

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                   - 53 -






to come into contact with sources of ignition, or




with substances with which it may react, during the




time the waste is contained in these facilities.




     Alternatively, some owners or operators treat




ignitable or reactive waste for a purpose other than



rendering the waste non-ignitable or non-reactive,




respectively — e.g., to reduce the water content




of the waste before incinerating it.  Because the




Agency wishes to encourage the treatment of hazardous




waste, the final rules allow owners or operators to




treat or store ignitable or reactive waste without



rendering the waste non-ignitable or non-reactive,




respectively, if the waste is treated or stored in




such a manner that it is protected from any sources



of ignition or from any material or condition which




may cause it to react.




     Finally, the final rules permit placement of



ignitable or reactive wastes in tanks which are used




solely for emergencies. Petroleum refiners requested




such an exemption for surface impoundments which



collect petroleum and related materials in emergencies.




The Agency has made such a provision in the surface




impoundment regulations, and believes that a parallel.




exemption for tanks is warranted.




     The Agency has included in §265.l7(b)  of Subpart B




of the final rules, general requirements for ignitable,

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                   - 59 -






reactive, and incompatible wastes.  The final Subparts




J and Q requirements specify that treatment or storage




of ignitable and reactive waste in tanks and in chemica




physical, and biological treatment facilities must be




done in accordance with §265.l7(b).  The rationale




for the §265.17(b) requirements is contained in the




preamble discussion entitled "Ignitable, Reactive,




and Incompatible Wastes".




     The Agency believes that the potential for a




violent explosion or fire from a tank containing




ignitable or reactive waste is more likely to occur




if the tank is covered because of the tendency for




vapors to pressurize in enclosed devices.  For this




reason, the Agency believes that minimum setbacks




from the facility's property line should be required




for tanks which contain ignitable or reactive waste.




This would minimize the potential for injury to the




neighboring public from the flying debris or toxic




air emissions which often result from explosions




involving hazardous materials.  For example, the




explosion which occured in 1977 at the chemical




disposal site in New Jersey (see damage incident #1




on page 5 of this document) resulted in the ejection




of several large tanks and the death and injury of




several people at the site.



     Not a great deal of data is available on which




the Agency can base minimum setback requirements

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                   - 60 -






for these types of waste.  The only data on this




subject of which EPA is aware is that gathered by




the National Fire Protection Association (NFPA).




This data was codified in the NFPA's Flammable and




Combustible Code of 1977.




     The purpose of the standards in the NFPA code




is "to reduce the hazard to a degree consistent with




reasonable public safety, without undue interference




with public convenience and necessity which requires



the use of flammable and combustible liquids"22




(emphasis added).  Because protection of human health




from fires or explosions resulting from the storage



of ignitable and reactive waste is also a goal of




the Section 3004 RCRA rules, it is appropriate to




use the NFPA's minimum setback requirements as the




basis for establishing EPA's regulations for ignitable




and reactive waste.   Although EPA's categories of




ignitable and reactive waste are only roughly compar-




able to NFPA's category of flammable and combustible




liquids, the setback requirements in the NFPA rules




would appear to represent a minimum fo-r -all igni-table




and reactive wastes,  since the -great majority of these




wastes pose similar hazards from ignition o.r reaction.




Therefore, the final rules require that the treatment




or storage of ignitable or reactive waste must be in




accordance with the NFPA's buffer zone requirements




for tanks, contained in Tables 2-1 of the "Flammable

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                   -Gl-






and Combustible Code of 1977".  These tables are




contained in Appendix I of this document.




     These NFPA standards already apply to most




covered tanks containing ignitable and reactive




materials under the Occupational Safety and Health




Administration's  (OSHA) regulations.  The Agency,




therefore, does not expect these regulations to




necessitate substantial capital expenditures for




covered tanks.




     The NFPA standards do not by their terms apply




to uncovered tanks and, thus, requiring these existing




tanks to comply with the NFPA standards might require




substantial capital expenditures.  Because such a




requirement does  not meet the general criteria for




interim status standards (see the Foreword to this




document), it has not been included in the Part 265




rules.  For this  same reason, the requirement to




comply with the NFPA standards has also not been




included  in the Subpart Q standards for chemical,




physical, and biological treatment facilities.

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                                - 62 -


       E.   Final Regulation Language;

       §265.192  General operating requirements*

            (a)  Treatment or storage of hazardous waste in
       tanks must comply with §265.i7(b).*

       §256.198  Special requirements for ignitable or reactive
                 waste[Interim Final]

            (a)  Ignitable or reactive waste must not be placed in
       a tank, unless:

                 (l)  The waste is treated, rendered, or mixed
                 before or immediately after placement in the
                 tank so that (i) the resulting waste, mixture,
                 or dissolution of material no longer meets
                 the definition of ignitable or reactive waste
                 under §§261.21 or 261.23 of this Chapter,  and
                 (11) §265.17(b) is complied with; or

                 (2)  The waste is stored or treated in such
                 a way that it is protected from any material
                 or conditions which may cause the waste to
                 ignite or react; or

                 (3)  The tank is used solely for emergencies.
* §265.17   General requirements for ignitable,  reactive,  or
            incompatible wastes [Interim Final]

       (b)  Where specifically required by other Sections  of this
  Part, the treatment, storage, or disposal of ignitable or
  reactive waste, and the mixture or commingling of incompatible
  wastes, or incompatible wastes and materials,  must be conducted
  so that it does not:

       (l)  Generate extreme heat or pressure, fire or explosion,
       or violent reaction;

       (2)  Produce uncontrolled toxic mists,  fumes, dusts, or
       gases in sufficient quantities to threaten human health;

       (3)  Produce uncontrolled flammable fumes or gases  in
       sufficient quantities to pose a risk of fire or explosions;

       (4)  Damage the structural integrity of the device  or
       facility containing the waste; or

       (5)  Through other like means threaten human health or the
       environment.

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                        - 63 -f
     (b)  The owner or operator of a facility which treats
or stores ignitable or reactive waste in covered tanks
must comply with the National Fire Protection Association's
(NFPA's) buffer zone requirements for tanks, contained in
Tables 2-1 through 2-6 of the "Flammable and Combustible
Code - 1977".

[Comment: See §265.l7(a) for additional requirements.]


§265.401  General operating requirements*

     (a)  Chemical, physical or biological treatment of
hazardous waste must comply with §265.l7(b).
§265.405  Special requirements  for  ignitable or reactive
          waste[Interim Final]

      (a)  Ignitable or  reactive waste must not be placed
in a  treatment process  or equipment unless:

      (l)  The waste is  treated, rendered, or mixed before
      or immediately after placement in the treatment
      process or  equipment so that  (i) the resulting waste,
      mixture, or dissolution of material no longer meets
      the definition of  ignitable or reactive waste under
      §§261.21 or 261.23 of this Chapter, and (ii) §265.l7(b)
      is complied with;  or

      (2)  The waste is  treated  in  such a way that it is
      protected from any material or conditions which may
      cause the waste  to ignite  or  react.

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                              - 64 -






X.   Subject:  Specxal Requirements for Incompatible Waste




     A.   Summary of Proposed Standards 250.45-4(c) and 250.44(3.)




          The proposed standards prohibited placing hazardous




     wastes which are incompatible with each other in basins.




          The standards also prohibited placing hazardous waste




     in an unwashed storage tank that previously held an incom-




     patible material.




     B.   Rationale for the Proposed Standards:




          The Agency was concerned about owners or operators




     placing wastes which are incompatible in the same con-




     tainment device because the commingling of incompatible




     waste may:




     (l)  generate hazardous air emissions which may endanger




          the health and lives of the facility's personnel and




          neighbors.  For example, mixing cyanide and sulfide-




          containing alkaline wastes may release toxic HCN and




          H2S vapors into the environment.




     (2)  generate excessive heat, fire, or explosions, which




          may damage the structural integrity of the containment




          device and, thus, possibly cause hazardous waste to be




          discharged from the basin to ground water or surface




          water.  For example, mixing hazardous waste containing




          highly reactive components- (e.g.-, oxrdation-reduction




          agents and organics) may generate excessive heat which




          could adversely affect the impermeability of some




          construction materials or liners.

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                        - 65 -




C.   Summary of Comments Received;




     1.   The prohibition on mixing incompatible waste




     precludes the presently desirable waste management




     practice of controlled neutralization of spent




     acids and caustics.  The standard should be revised




     to allow wastes which are incompatible to be mixed,




     if such mixing is:




          -    for the purpose of treatment




               in accordance with the provisions of




               the note to §250.45(c)




     2.   The requirement that hazardous waste must not




     be placed in a storage tank or container which pre-




     viously held an incompatible waste is unnecessary,




     particularly when:




          -    the tank is empty, or



               the tank is suitable for both caustic




               and acidic substances.




D.   Analysis of and Response to Comments;



     1.   The Agency agrees that incompatible wastes  should




     be allowed to be mixed together  in containment de-




     vices  for the purpose of treatment if the §265.17(b)




     regulations are complied with  (see previous Section




     of this document).



          As mentioned  earlier, the Agency is deferring




     regulation of volatile wastes, which may cause air




     emissions to be generated  from treatment facilities.




     The  only restriction included  in the final interim

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                   - 66 -






status standards on the treatment of incompatible




wastes in facilities subject to control under Subparts




J and Q, is that this treatment comply with §265.l7(b)



2.   The Agency believes that placing hazardous




waste in containment devices which previously held




an incompatible waste should be restricted even when



the device is "empty", because the residues that are




left in the device may react adversely with the




"new" waste to be stored or treated in the device.



Damage incident #5 on page 6 of this document exem-




plifies the type of potential hazards associated




with placing waste in an unwashed containment device



which previously held an incompatible waste.   This




hazard exists even if the tank itself is compatible




with both the previous waste and the "new" waste.




     The Agency believes that, unless devices are




cleaned (washed), they are seldom empty because the




pumps and drain valves used for this purpose are



seldom capable of removing the last drops of waste




which settle to the bottom, or adhere to the sides




of the tank.  Therefore, the requirement to wash a




tank before emplacing a "new" waste in it, — if the




"new" waste is incompatible with the "original"




waste -- has been retained in the final standards.




However, the standard has been reworded to allow




waste to be placed in an unwashed device which pre-




viously held an incompatible waste, if it is done




in accordance with §265.l7(b).

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                        - 67 -
E.   Final Regulation Language:

§265.199  Special requirements for incompatible waste

     (a)  Incompatible wastes or incompatible wastes and
materials, (see Appendix V for examples) must not be
placed in the same tank unless §265. 17 (b) is complied
with .

     (b)  Hazardous waste must not be placed in an
unwashed tank which previously held an  incompatible
waste or material, unless §265. 17 (b) is complied with.
§265.406  Special requirements for incompatible wastes

      (a)  Incompatible wastes, or incompatible wastes and
materials,  (see Appendix V  for examples) must not be
placed in the same treatment process or equipment, unless
§265.17(b)  is complied with.

      (b)  Hazardous waste must not be placed in unwashed
treatment equipment which previously held an incompatible
waste or material, unless §265.17(b) is complied with.

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                             - 68 -






XI.   Subject:  NPDES Facilities




     A.   Summary of Comments:




          NPDES-permitted treatment facilities should be exempt




     from the §250.45-6 standards, because:




          1.    these facilities are regulated under Section




          402 of the Clean Water Act, and Section 1006 of RCRA




          specifically excludes activities or substances subject




          to the Clean Water Act from regulation under RCRA.




          2.    the terms of the NPDES permit overlap and are




          inconsistent with the provisions of §250.45-6.  For




          example, §250.45-6(g), which requires by-passing, is




          incompatible with certain industry NPDES require-




          ments which prohibit by-passing.




          3.    the standards dictate design and operating




          procedures which are outside of the RCRA mandate for




          such facilities.




     B.   Analysis of and Response to Comments;




        1-2.    Section 1006 of RCRA excludes activities or




          substances subject to the Clean Water Act (CWA)




          "except to the extent that such application (or




          regulation) is not inconsistent with the require-




          ments" of the CWA.  As stated earlier, the Agency




          believes it has authority under RCRA to regulate




          NPDES facilities.  The Agency is also unaware of




          any regulations promulgated under the CWA which are




          inconsistent with the proposed §250.45-6 standards.




          With regard to the example cited by the commenters




          concerning by-pass systems, proposed §250.45-6(g)

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                   - 69 -






gave, and present §265.192(d) gives, owners or opera-




tors the option of either equipping their treatment




systems with an automatic waste feed cut-off or a




by-pass system.  Thus, in those instances where the




provisions of a facility's NPDES permit prohibit




by-passing, owners or operators are able to comply




with the proposed standard by installing an automatic




waste feed cut-off system at their facilities.




3.   As explained on pages 17-18 of this document,




the Agency believes that the standards it has proposed




for treatment facilities are in accordance with the




authority given to the Agency in Section 3004 of




RCRA.  Thus, where NPDES-permitted facilities contain




hazardous waste, the Agency believes that these




facilities should comply with the standards promul-




gated under Section 3004 of RCRA, as well as those




promulgated under the CWA.  Response to this comment




is also contained in the preamble to the Section 3001




standards.  In addition, the proposed and present




interim status standards contain few of the design




standards proposed for the general status standards.




Comments directed toward the general standard design




requirements will be discussed when general design




standards are promulgated.

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                             - 70 -

XII.   Subject;  Miscellaneous Comments

 Comment;  It is unreasonable to require facilities which change

 the pH of their wastes, so as to render them less hazardous

 before disposal,  to comply with the requirements for treatment

 facilities.   This points out the need for separate standards

 for on-site treatment and storage facilities.

 Response;  The definition of "treatment", in Section 1004 of

 RCRA, specifically includes neutralization processes.  Because

 the regulation of pH is a "neutralization process", the Agency's

 regulations which pertain to treatment facilities must apply

 to all facilities which change the pH of their waste.

      Because facilities which neutralize their waste on-site

 pose an equal potential threat to human health and the environ-

 ment as do off-site neutralization processes,* the Agency

 disagrees with the commenter's suggestion that separate sets

 of standards should be written for on-site facilities at

 which hazardous waste is neutralized.



 Comment;  The standards for treatment facilities (§250.45-6)

 are too detailed because they impose requirements on semi-

 hazardous materials which will have little or no effect upon

 water quality or public health.  The standards for treatment

 facilities should be related to the degree of hazard of the

 waste being treated.
 * Except for totally enclosed treatment facilities, which have
   been exempted from the Subtitle C rules (see page 19 of this
   document).

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                            - 71 -






Response:  The Agency disagrees with the commenter's suggestion




that the proposed standards for treatment facilities are too




detailed.  On the contrary, the Agency recognized that it is




difficult to write specific design and operating standards




which would be appropriate for all treatment systems and,




therefore, wrote performance-oriented standards in the proposed




§250.45-6 rules for chemical, physical, and biological treat-




ment facilities.  The Agency believes that all of these proposed




standards are appropriate  for all hazardous waste treatment




facilities, regardless of  the hazard of the waste being treated.




(See the background document entitled "Degree of Hazard" for




the Agency's rationale for not establishing regulations based




on the degree of hazard of the waste.)

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            FINAL INTERIM STATUS REGULATION LANGUAGE





                      Subpart J - Tanks




§265.190  Applicability




     The regulations in this Subpart apply to owners and




operators of facilities that use tanks to treat or store




hazardous waste, except as §265.1 provides otherwise.




[§265.191  Reserved]




§265.192 General operating requirements*




     (a)  Treatment or storage of hazardous waste in tanks must




comply with §265.17(b).




     (b)  Hazardous wastes or treatment reagents must not be




placed in a tank if they could cause the tank or its inner




liner to rupture, leak, corrode, or otherwise fail before




the end of its intended life.




     (c)  Uncovered tanks must be operated to ensure at least




60 centimeters (2 feet) of freeboard, unless the tank is




equipped with a containment structure (e.g., dike or trench),




a drainage control system, or a diversion structure (e.g.,




standby tank) with a capacity that equals or exceeds the




volume of the top 60 centimeters (2 feet) of the tank.




     (d)  Where hazardous waste is continuously fed into a




tank, the tank must-be equipped with a means to stop this




inflow  (e.g., a waste feed' cutoff system or~by-pass system to




a stand-by tank).




[Comment:  These systems are intended to be used in the event




of a leak or overflow from the tank due to a system failure




(e.g., a malfunction in the treatment process, a crack in the




tank, etc.).1

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                             -  7,3 -






§265.193  Waste analysis and trial tests*




     In addition to the waste  analysis required by §265.13,



whenever a tank is to be used  to:




     (1)  Chemically treat or  store a hazardous waste which is



     substantially different from waste previously treated or



     stored in that tank; or




     (2)  Chemically treat hazardous waste with a substantially



     different process than  any  previously used in that tank?



the owner or operator must, before treating or storing the dif-



ferent waste or using the different process:



     (1)  Conduct waste analyses and trial treatment or storage




     tests  (e.g., bench scale  or pilot plant scale tests); or



     (2)  Obtain written, documented information on similar



     storage or treatment of similar waste under similar operating




     conditions;



to  show that this proposed treatment or storage will meet all



applicable  requirements of §265.192(a) and  (b).




[Comment:   As  required by  §265.13, the waste analysis plan must



include analyses  needed to comply with §§265.198 and 265.199.



As  required by §265.73, the  owner or operator must place the



results from each waste analysis and trial  test, or the documented



information, in the  operating  record of the  facility.]




§265.194   Inspections



       The  owner or  operator  of a tank must  inspect, where present:



      (1)   Discharge control  equipment  (e.g., waste feed cut-off



     systems,  by-pass  systems, and drainage  systems), at least

-------
     once each operating day, to ensure that it is in good working



     order;




     (2)  Data gathered from monitoring equipment (e.g./ pressure



     and temperature gauges), at least once each operating day,



     to ensure that the tank is being operated according to its



     design;




     (3)  The level of waste in the tank, at least once each



     operating day.- to ensure compliance with §265.192(c);



     (4)  The construction materials of the tank, at least



     weekly, to detect corrosion or leaking of fixtures or



     seams; and



     (5)  The construction materials of, and the area immediately



     surrounding, discharge confinement structures (e.g.,  dikes),



     at least weekly, to detect erosion or obvious signs of



     leakage (e.g., wet spots or dead vegetation).



[Comment;  As required by §265.15(c), the owner or operator must



remedy any deterioration or malfunction he finds.]



[§§265.195 - 265.196 Reserved]




§265.197  Closure



     At closure, all hazardous waste and hazardous waste residues



must be removed from tanks, discharge control equipment, and dis-




charge confinement structures.



[Comment;  At closure, as throughout the operating period, unless



the owner or operator can demonstrate, in accordance with §261.3(f)



of this Chapter, that the residue removed from his tank is not a



hazardous waste, the owner or operator becomes a generator of

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                             - 75 -
hazardous waste and must manage  it  in  accordance with all applicable



requirements of Parts  262,  263,  and 265  of  this Chapter.]



§265.199  Special  requirements for  ignitable  or reactive waste



          [Interim Final]




      (a)  Ignitable or reactive  waste  must  not be placed in a tank,



unless:




      (1)  The waste is treated,  rendered, or  mixed before or



      immediately after placement in the  tank  so that  (i) the



      resulting waste,  mixture, or dissolution of material no



      longer meets  the  definition of ignitable or reactive waste



      under  §§261.21 or 261.23 of this  Chapter, and  (ii) §265.17(b)



      is  complied with; or



      (2)  The waste is stored or treated in such a way that



      it  is protected  from  any material or conditions which




      may cause  the waste to ignite  or  react;  or



      (3)  The tank is  used solely for  emergencies.



      (b)  The owner or operator  of  a facility which treats or stores



ignitable or  reactive  waste in covered tanks  must comply with the



National Fire Protection Association's (NFPA's) buffer zone



requirements  for  tanks, contained in Tables 2-1 through 2-6 of



the  "Flammable  and Combustible Code -  .1977".



CComment;  See  §265»17(a)  for additional requirements.]



§265>199  Special  requirements for  incompatible wastes



      (a)  Incompatible wastes, or incompatible wastes and materials,



 (see Appendix V for  examples) must  not be placed  in the same



tank, unless  §265.17(b) is complied with.

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                             - 76 -
     (b)  Hazardous waste must not be placed in an unwashed tank



which previously held an incompatible waste or material, unless




§265.17(b) is complied with.



[§§265.200 - 265.219 Reserved]

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                            - 77 -
                 Subpart Q - Chemical, Physical,



                     and Biological Treatment



§265.400  Applicability




     The regulations in this Subpart apply to owners and opera-



tors of facilities which treat hazardous wastes by chemical,




physical, or biological methods in other than tanks, surface



impoundments, and land treatment facilities, except as §265.1



provides otherwise.  Chemical, physical, and biological treatment




of hazardous waste in tanks, surface impoundments, and land




treatment facilities must be conducted in accordance with



Subparts J, K, and M, respectively.




§265.401  General operating requirements*




     (a)  Chemical, physical, or biological treatment of hazardous



waste must comply with §265.17(b).



     (b)  Hazardous wastes or treatment reagents must not be



placed in the treatment process or equipment if they could



cause the treatment process or equipment to rupture, leak,



corrode, or otherwise fail before the end of its intended life.




     (c)  Where hazardous waste is continuously fed into a



treatment process or equipment-, the process or equipment must be




equipped with a means to stop this inflow (e.g., a waste feed



cut-off system or by-pass system to a standby containment device).



[Comment;  These systems are intended to be used in the event




of a malfunction in the treatment process or equipment.]

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§265.402  Waste analysis and trial tests*



     In addition to the waste analysis required by §265.13,



whenever:




     (1)  A hazardous waste which is substantially different



     from waste previously treated in a treatment process or




     equipment at the facility is to be treated in that process



     or equipment, or



     (2)  A substantially different process than any previously




     used at the facility is to be used to chemically treat



     hazardous waste;



the owner or operator must, before treating the different waste



or using the different process or equipment:



     (1)  Conduct waste analyses and trial, treatment tests



     (e.g., bench scale or pilot plant scale tests); or



     (2)  Obtain written, documented information on simi-



     lar treatment of similar waste under similar operating



     conditions;



to show that this proposed treatment will meet all applicable



requirements of §265.401 (a) and (b).



[Comment;  As required by §265.13, the waste analysis plan must




include analyses needed to comply with §§265.405 and 265.406.



As required by §265.73, the owner or operator must place the



results from each waste analysis and trial test, or the documented



information, in the operating record of the facility-]



§265.403  Inspections



     The owner or operator of a treatment facility must inspect,




where present:

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                            - 79 -









     (1)   Discharge control and safety equipment (e.g.,  waste



     feed cut-off systems, by-pass systems,  draingage systems,



     and  pressure relief systems) at least once each operating



     day, to ensure that it is in good working order;



     (2)   Data gathered from monitoring equipment (e.g., pressure



     and  temperature gauges), at least once each operating day,



     to ensure that the treatment process or equipment is being



     operated according to its design;



     (3)   The construction materials of the treatment process or



     equipment, at least weekly, to detect corrosion or leaking



     of fixtures or seams; and



     (4)   The construction materials of, and the area immediately



     surrounding, discharge confinement structures (e.g., dikes),



     at least weekly, to detect erosion or obvious signs of



     leakage (e.g., wet spots or dead vegetation).



[Comment:  As required by §265.15(c), the owner or operator must



remedy any deterioration or malfunction he finds.]



§265.404  Closure



     At closure, all hazardous waste and hazardous waste residues



must be removed from treatment processes or equipment, -discharge




control equipment, and discharge confinement structures.



[Comment:  At closure, as throughout the operating period, unless



the owner or operator can demonstrate, in accordance with §261.3(f)



of this Chapter, that the residue removed from his treatment



process or equipment is. not a hazardous waste, the owner or



operator becomes a generator of hazardous waste and must manage

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                             - 80 -
it in accordance with all applicable requirements of Parts



262, 263, and 265 of this Chapter.]




§265.405  Special requirements for ignitable or reactive waste



          [Interim Final]



     (a)  Ignitable or reactive waste must not be placed in a



treatment process or equipment unless:



     (1)  The waste is treated, rendered, or mixed before or



     immediately after placement in the treatment process or



     equipment so that (i) the resulting waste, mixture, or



     dissolution of material no longer meets the definition of



     ignitable or reactive waste under §§261.21 or 261.23 of



     this Chapter, and (ii) §265.17(b) is complied with; or



     (2)  The waste is treated in such a way that it is protected



     from any material or conditions which may cause the waste to



     ignite or react.



§265.406  Special requirements for incompatible wastes



     (a)  Incompatible wastes, or incompatible wastes and materials,




(see Appendix V for examples) must not be placed in the same



treatment process or equipment, unless §265.17(b) is complied with.



     (b)  Hazardous waste must not be placed in unwashed treat-



ment equipment which previously held an incompatible waste or



material, unless §265.17(b) is complied with.



[§§265.407 - 265.429  Reserved]

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                              -  81  -
                           References

1.   Trip Report.  John Schaum and  Gene  Grumpier,  Technology
     Program, Hazardous Waste Management Division  -  January 24,
     1979.   (A brief description of the  damage  incident  was
     published in Solid Waste Management,  "News  Briefs",
     December 3, 1977.)

2.   Confirmed by telephone by Cindy Giansante,  Environmental
     Scientist, EPA, Washington, D.C., on October  30,  1979,
     with Joseph A. Feola, Water Quality Specialist;  Pennsylvania
     Department of Environmental Resources;  Norristown,
     Pennsylvania.

3.   Confirmed by telephone by Cindy Giansante,  Environmental
     Scientist, EPA, Washington, D.C., on October  30,  1979, with
     Kenneth Young, Chief of Operations; Pennsylvania  Department
     of Environmental  Resources; Meadville,  Pennsylvania.

4.   Letter  from Jerry T. Thornhill, Chief Emergency Response
     Branch, EPA, Region VI to Arsen Darnay,  Jr.,  Director
     Resource Recovery Division, EPA, Washington,  D.C.   October 27
     1972:   "Hazardous Waste Study".

5.   Hatayama, H.K., J.J. Chan, E.R. de  Vera, R.D. Stephens, and
     D.L. Storm.  "A Method for Determining Hazardous  Wastes
     Compatibility." Grant No. R804692.   Prepared  for  the
     Municipal Environmental Research Laboratory,  Office of
     Research and Development, U.S. EPA, Cincinnati,  Ohio, 1980.

6.   Confirmed by telephone by Cindy Giansante,  Environmental
     Scientist, EPA, Washington, D.C., on November 15, 1979,
     with Ron Kimbro,  Texas Department of Water  Resources,
     Austin, Texas.

7.   Texas Department  of Water Resources,  Industrial  Solid
     Waste Management.  Technical Guideline #9,  "Noncompatible
     Wastes".  Revised March 1, 1978.

8.   State of Louisiana Department  of Natural Resources, Rules
     and Regulations,  Hazardous Waste Management Plan, Mandated
     by:  Act 334 of 1978.  Section 8.4.9. Chemical,  Physical,
     and Biological Treatment Facilities.

9.   Tennessee Department of Public Health,  Division  of  Solid
     Waste Management, Draft Hazardous Waste Management  Regula-
     tions,  Rule  8, Requirements Pertaining to  Hazardous Waste
     Storage Facilities.  August, 1978.

10.  Op. cit.  Texas Guideline #4,  "Ponds and Lagoons".

11.  Op. cit.  Texas Guideline #9,  "Noncompatible  Wastes".

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                             - 82 -
12.  South Carolina Department of Health and Environmental
     Control, Draft Hazardous Waste Management Regulations.
     R. 61-79.4, Standards for Treatment, Storage, and  Disposal
     Facilities.

13.  Minnesota Code of Agency Rules.  Pollution Control Agency
     (PCA) - Hazardous Waste.  6 MCAR §4.9004, "Location,
     operation and closure of a hazardous waste facility: C.
     Hazardous Facility Operation, 3. Storage of hazardous
     waste in containers and tanks.

14.  Op. cit.  State of Louisiana Rules and Regulations,
     Section 8.4.3.  Impoundments and Basins.

15.  Op. cit.  Texas Guideline #4, "Ponds and Lagoons".

16.  Op. cit.  State of Louisiana Rules and Regulations,
     Section 8.4.9 Chemical, Physical and Biological Treatment
     Facilities.

17.  Op. cit.  Texas Guideline #4, "Ponds and Lagoons".

18.  Op. cit.  State of Louisiana Rules and Regulations,
     Section 8.4.9  Chemical, Physical and Biological  Treatment
     Facilities.

19.  Middlebrook,  E. Joe et al.   Upgrading Wastewater  Stabili-
     zation Ponds to Meet New Discharge Standards.  Symposium
     Proceedings sponsored by Utah Water Research Laboratory,
     Utah State University and U.S.  Environmental Protection
     Agency, ORD,  November,  1974.

20.  U.S. Environmental Protection Agency.  Process Design
     Manual for Upgrading Existing Wastewater Treatment Plants.
     U.S. EPA Technology Transfer, October, 1974, pg.  3-14.

21.  Liptalc, Bela G., ed. Environmental Engineers' Handbook,
     Volume 1,  Water Pollution,  pg.  815.

22.  National Fire Protection Association, NFPA 30 Flammable
     and Combustible Code 1977,  pg.  3.

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                                                              APPENDIX  I

                                    NPPA  Buffer  Zone  Requirements  for  Tanks
                             Table 2-1

         Stable Liquids (Operating Pressure 2.5 psig or Less)
                       Table 2-2

Stable Liquids (Operating Pressure Greater Thau 2.5 psig)


Type of
'rank.


Floating
Roof
[Sec
2-2.1.1 (a)]



Vertical
with
Weak
Roof
to
Shell
Seam
(Sec
2-2.1.1)



Horizontal
and
Vertical
with
Emer-
gency
Relief
Venting
To Limit
Pressures
to 2.5 psig



I'rotecllon

Protection
lor
Exposures*
None
Approved
foam or
inerling
system on
tanks not
exceeding
150 feel in
diameter**
Protection
for
Exposures*
None

Approved
inerting
system on
(he tank
or approved
foam system
on vertical
tanks
Protection
for
Exposures*
None
Minimum Distance In
Feet from Property Line
Which U or Gun lie Unlit
Upon, Including the
Opposite Side of a Public
Way ami Sliull lie Nat
Less Than 5 Keel
Yi times diameter of
tank
Diameter of tank but
need not exceed 175
feet



J-2 times diameter of
tank



Diameter of tank
2 times diameter of tank
but need not exceed 350
feet



\i times Table 2-6


Table 2-6
2 times Table 2-6
Minimum Distance In
Keet front Neuron I Side of
Any Public Wuy or from
Nearest Important
Building on tbe Same
Property und Shall lie
Not Less Thau 5 Feet
]/e, times diameter of
tank
Y& times diameter of
tank



H times diameter of
tank



Y± times diameter of
tank
H times diameter
of tank

''

Vi times Table 2-6


Table 2-6
Table 2-6
                                                                             Type of
                                                                              Tunk
       Protect Ion
 Minimum Distance In
Keel from Property Line
Which Is at C»n lie Ilullt
  Upon, Including the
Opposite Side of u Public
        Way
 Minimum Distance In
I'eet from Nearest Side of
 Any Public Way or from
   Nearest Important
 Dulldlnii on the Same
       Property
                                                                           Any Type
       Protection   1Yi times Table 2-6 but
          for       shall not be less  than
      Exposures*         25 feet
                                                                                                                          Yi times Table 2-6 but
                                                                                                                          shall not be less than
                                                                                                                                 25 feet
                                                                                                    3 times Table 2-6 but
                                                                                          None      shall riot be less thun
                                                                                                           50 feet
                                        \Yi limes Table 2-6 but
                                         shall not be less than
                                                25 feet
                                                                            *See Definition for "Protection for Exposures."
                                                                                                        Table 2-3

                                                                                                     Boil-over Liquid*
  *Sec definition for "Protection for Exposures."

  **For tanks over 150 ft. in diameter use  "Protection  for Exposures" or
"None" as applicable.


Type of
Tank

Floating
Roof
2-2.1.1 (a)]




Fixed
Roof
[Sec
2-2.1. 4(a)J



Protection

Protection
for
Exposures*
None
Approved

or
inerting
system
Proteciion
for
Exposures*
None
Minimum Distance In
Feet from Properly Line
Which In or Can Ue Uullt
Upon, Including the
Opposite Side of u Public
Wuy und Shall Re Not
Loss Than 5 Feet
Yi times diameter of
tank
Diameter of tank


Diameter of tank


2 times diameter of tank
4 times diameter of tank
but need not exceed 350
feet
Minimum Distance la
Feet from Nearest Side of
Any Public Wuy or from
Nearest Importune
Building on the Same
Property and Shall Ue
Not Lena Thau 5 Feet
Yl times diameter of
tank
Y& times diameter of
tank


Y± times diameter of
tank


% limes diameter of
tank
% times diameter of
tank
                                                                         I

                                                                         00
                                                                            *Scc definition for "Protection for Exposures."

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                       Table 2-4 Unatablc Liquids
                                                                                                       Table 2-5  Clas* HIB Liquid*


Type of
Tank





Horizon-
tal and
Vertical
Tanks
with
Emer-
«ency
Lelief
Venting
to Permit
Pressure
Not iu
Excess of
2.5 paig






Horizon-
tal and -
Vertical
Tanki
with
Emer-
gency
Relief
Venting
to Permit
Pressure
Over
2.5 psig



Protection

Tank
protected
with
any one
of the
following:
Approved
water spray,
Approved
incrting,
Approved
insulation
and
refrigeration,
Approved
barricade
Protection
for
Exposures*
None
Tank
protected
with
any one
of the
following :
Approved
water spray,
Approved
inerting,
Approved
inaulation
and
refrigeration,
Approved
barricade

Protection
for
Exposures*
None
Minimum Distance In
Feet from Property Line
Which Is or Cuu lie Built
Upon, Including the
Opposite Side of a Public
Wuy







Table 2-6 but not less
than 25 feet





2\4 times Table 2-6 but
not less than SO feet
5 times Table 2-6 but
not less than 100 feet





2 times Table 2-6 but
not less than 50 feet





4 times Table 2-6 but
not less than 100 feet
8 times Table 2-6 but
not less than ISO feet
Minimum UUtance In
Keel from Nearest Side of
Any Public Wuy or from
Nearest Important
Building on die Same
Property







f
Not less than 25 feet

.



Not lesa than 50 feet
Not less than 100 feet





Not less than SO feet





Not less than 100 feet
Not less than 150 feet
                                                                                      Capacity Giitlona
                                                                                      12,000 or less
                                                                                      12,001 to 30,000
                                                                                      30,001 to 50,000
                                                                                      50,001 to 100,000
                                                                                     100,001 or more
 Minimum Distance lit
 Feet from Property Line
Which Is or Can Be Built
  Upon, Including the
Opposite Side of a Public
         Way
 Minimum Distance in
Feet from Nearest Side of
 Any Public Way or from
   Nearest Important
 Building oil the Same
        Property
5
10
10
15
15
5
5
10
10
15
                                                                                                                 Table 2-C

                                                                                                Reference Table for Use in Tables 2-1 to 2-4
Capacity Tunk
Gallons
275 or less
276 to 750
751 to 12,000
12,001 to 30,000
30,001 to 50,000
50,001 to 100,000
100,001 to 500,000
500,001 to 1,000,000
t, 000,001 to 2,000,000
2,000,001 to 3,000,000
3,000,001 or more
Minimum Distance In Minimum Distance In
Feet from Property Line Feet from Nearest Side ol
Which Is 01- Can Be Built Any Pul.llc Way or from
Upon, Including the Nearest Important
Opposite Side of a Public Building on the Same
Way Property
5
10
15
20
30
50
80
100
135
165
175
5
5
5
5
10
15
25
35
45
55
60
                                                                                                                                                                          I

                                                                                                                                                                          CD
*Sce definition for "Protection for Exposures."
                                                                                                                                              GPO B(i8-066

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