&EPA
United States
Environmental Protection
Agency
Environmental Sciences Research
Laboratory
Research Triangle Park NC 27711
EPA-600- 3-79-1 10
November 1979
Research and Development
Mechanisms of
Photochemical
Reactions in
Urban Air
Final Report
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RESEARCH REPORTING SERIES
Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology. Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:
1. Environmental Health Effects Research
2. Environmental Protection Technology
3. Ecological Research
4. Environmental Monitoring
5. Socioeconomic Environmental Studies
6. Scientific and Technical Assessment Reports (STAR)
7. Interagency Energy-Environment Research and Development
8. "Special" Reports
9. Miscellaneous Reports
This report has been assigned to the ECOLOGICAL RESEARCH series. This series
describes research on the effects of pollution on humans, plant and animal spe-
cies, and materials. Problems are assessed for their long- and short-term influ-
ences. Investigations include formation, transport, and pathway studies to deter-
mine the fate of pollutants and their effects. This work provides the technical basis
for setting standards to minimize undesirable changes in living organisms in the
aquatic, terrestrial, and atmospheric environments.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.
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EPA-600/3-79-1K)
November 1979
MECHANISMS OF PHOTOCHEMICAL REACTIONS IN URBAN AIR
Final Report
by
James N. Pitts, Jr., Karen Darnail,
William P. L. Carter, Arthur M. Winer and Roger Atkinson
Statewide Air Pollution Research Center
and Department of Chemistry
University of California
Riverside, CA 92521
Grant No. R-800649
Project Officer: Marcia C. Dodge
Atmospheric Chemistry and Physics Division
Environmental Sciences Research Laboratory
Research Triangle Park, North Carolina 27711
ENVIRONMENTAL SCIENCES RESEARCH LABORATORY
OFFICE OF RESEARCH AND DEVELOPMENT
U.S. ENVIRONMENTAL PROTECTION AGENCY
RESEARCH TRIANGLE PARK, NORTH CAROLINA 27711
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DISCLAIMER
This report has been reviewed by the Environmental Sciences Research
Laboratory, U.S. Environmental Protection Agency, and approved for publica-
tion. Approval does not signify that the contents necessarily reflect the
view and policies of the U.S. Environmental Protection Agency, nor does
mention of trade names or commercial products constitute endorsement or
recommendation for use.
ii
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ABSTRACT
Results of an environmental chamber study and three basic studies
pertaining to the chemistry of air pollution are described.
Results obtained during the last four years of a long-term program
designed to provide data required for the validation of models for chemical
transformations in air pollution are presented. A 5800-liter, Teflon-
coated, evacuable, thermostatted chamber and a 25 KW xenon arc solar
simulator were used for irradiations, under simulated atmospheric condi-
tions, of various hydrocarbon-NOx-air mixtures. Detailed time-concentra-
tion profiles were obtained for a wide range of products as well as for the
reactants employed. Results from a total of 114 hydrocarbon-NOx irradia-
tions, employing representative alkanes, olefins, aromatlcs, and oxygenates
both singly and in two- or multi-hydrocarbon mixtures, are reported.
Relative and absolute concentrations of the reactants were chosen on a
factorial design basis. Several hydrocarbon-NOx systems were also studied
as a function of temperature, with added aldehydes or with added PAN.
Chamber and light source characterizations, including determinations of 03
lifetimes and of light and dark H202 decays, and measurements of the
spectral distributions of the photolyzing light, were carried out. The
experimental procedures and analytical methods employed in this study and
the limitations and uncertainties in the data are discussed.
The kinetics and mechanism of the gas phase reaction of hydroxyl
radicals with o-cresol and methoxy benzene was studied over the temperature
range 299-435 K using a flash photolysis resonance fluorescence technique.
In both cases the observed temperature dependence of the OH decays is
attributed to both H atom abstraction by OH, and to OH radical addition to
the aromatic ring, with the adduct predominately decomposing at higher
temperatures. These data were used to derive rate constants and Arrhenius
parameters for OH addition and OH H-abstraction for both systems.
The reactions of 03 with acetylene, methylglyoxal and a series
of aromatic hydrocarbons were studied at 297 + 2 K, and rate constants
and product data are reported.
The chemical ionization mass spectrum of peroxyacetylnitrate (PAN),
a major component of photochemical smog, was obtained using both methane
and isobutane as reagent gas and the results confirmed the commonly ac-
cepted structure for PAN, CH3(CO)OON02.
This report was submitted in fulfillment of Grant No. R-800649 by the
Statewide Air Pollution Research Center,' University of California, River-
side, under the sponsorship of the U.S. Environmental Protection Agency.
This report covers a period from January 1, 1974, to November 30, 1978, and
work was completed as of November 30, 1978.
iii
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CONTENTS
Abstract ill
Figures • vii
Tables viii
Acknowledgments x
1. Introduction 1
2. Experimental Facility and Procedures 2
Facility 2
Procedures for photochemical runs .. 6
Procedures for actinometry experiments 9
3. Analytical Methods and Physical Measurements ....... 9
Temperature 9
Relative humidity 10
Ozone 10
Oxides of nitrogen 11
Formaldehyde 12
Hydrogen peroxide .... 13
Carbon monoxide 15
Organic reactants and products ......15
4. Chamber and Light-Source Characterization 27
Ozone decay rates 27
H.2®2 decay rates 28
Light intensity 28
Spectral distribution 35
5. Photooxidation of Hydrocarbon-N0x Systems 36
Experimental runs performed 36
Results 40
Limitations of the data set 44
6. Kinetics and Mechanism of the Gas Phase Reaction of
OH Radicals with Methoxybenzene and o-Cresol Over
the Temperature Range 299-435 K 46
Introduction 46
Experimental 46
Results 47
Discussion 48
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7. The Gas Phase Reaction of 63 with a Series
of Aromatic Hydrocarbons 56
Experimental methods 56
Products 57
Kinetics 59
8. Chemical lonization Mass Spectrum of Peroxy-
acetylnitrate (PAN) . 63
Experimental 63
Results and discussion 65
References 68
Appendix
Detailed data sheets 73
vi
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FIGURES
Number Page
1 The SAPRC Evacuable Chamber-Solar Simulator
Facility ........................ 3
Absorbtion Spectrum of Samples from the
Method for Monitoring H202 Taken During EC-255 ..... 14
Plots of the OH Radical Decay Rate Against Aromatic
Concentration for Methoxybenzene at 299.9 and 422.0 K
and for o-Cresol at 299.4 and 423.1 K .......... 49
Arrhenius Plots of log k Against 1000/f (k) for
Methoxybenzene and o-Cresol ............... 51
Plot of Reactant and Product Concentrations Against
Time for the Reaction of 03 with 1,3,5-Trimethylbenzene . 58
Plot of the 03 Decay Rate Against Aromatic Hydrocarbon
Concentration for Benzene, Toluene, m-Xylene and
1,2,4-Trimethylbenzene ..... ............ 61
Total Ion Current Chromatogram of PAN (1000 ppm in N2) • 64
vii
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TABLES
Number Page
1 Chromatographic Systems and Compounds Monitored
by Each 16
2 Comparison of Acetaldehyde Concentrations Deter-
mined from Area Response with Those from Peak
Height Response on the 10' 10% C-600 System 22
3 Actinometry Experiments in the Evacuable Chamber .... 29
4 Experimental Data and Calculated Results for the
N0£ Photolysis Rate Constant (k^) Determined in
Five Consecutive One-Minute Photolyses 34
5 Initial Concentrations, Light Intensity and Selected
Reactivity Parameters for Single Component Hydro-
carbon-NOx Runs 37
6 Initial Concentrations, Light Intensity and Selected
Reactivity Parameters for Dual Component Hydro-
carbon-NOx Runs 41
7 Initial Concentrations, Light Intensity and Selected
Reactivity of Aromatics for Mixed Olefin-N0x Runs .... 42
8 Initial Concentrations, Light Intensity and Selected
Reactivity Parameters for Seven Hydrocarbon Mixture-
NOX Runs 43
9 Rate Constants for the Reaction of OH Radicals with
Methoxybenzene and o-Cresol 50
10 H Atom Abstraction Rate Constants, kj_, and the Ratio
kl/(kl + k2^ for the Reaction of OH Radicals
with Methoxybenzene and o-Cresol at 299 K 53
11 Arrhenius Activation Energies for Reactions (2) and
(-2) and Heats of Formation AHf for the
OH-Aromatic Adducts 55
viii
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TABLES (Continued)
Number Page
12 Products Observed for the Reaction of 63 with
Toluene, o-Xylene and 1,3,5-Trimethylbenzene 59
13 Comparison of the Present Room Temperature Rate
Constants k£ with Selected Literature Values 62
14 Chemical lonization Mass Spectra of Peroxyacetylnitrate
(PAN) 66
ix
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ACKNOWLEDGMENTS
We thank the following people for their valuable effort without which
this program would not have been possible: Mr. William D. Long for assis-
tance in conducting the chamber experiments, Mr. Frank R. Burleson and Mr.
Glen C. Vogelaar for conducting the gas chromatographic measurements, Ms.
Laurie A. Willis for the data processing and Ms. Minn P. Poe for developing
the necessary computer programs. During the latter part of the program,
valuable assistance in conducting the experiments and in data processing
was given by Ms. Sara M. Aschmann.
Other SAPRC staff members who have contributed directly or indirectly
to the work were: Dr. George Breuer, Dr. George Doyle, Dr. Alain Glangetas,
Dr. Richard Graham, Ms. Sharron Harris, Dr. John McAfee, Dr. Edgar Stephens,
and Dr. Ernesto Tuazon. The following student helpers assisted in conducting
the experiments at various times throughout this program: Richard Borders,
Richard Brown, Ken Feenstra, Steve Meinhardt and Ray Plank.
Finally, we wish to acknowledge our contract officer, Dr. Marcia
C. Dodge, for assistance in planning the experiments conducted in this
program.
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1. INTRODUCTION
In recent years there has been a growing demand for reliable and
cost-effective computer kinetic models of photochemical smog formation by
air pollution control officials, atmospheric scientists and a variety of
regulatory agencies, as well as by industry. Considerable progress has
been made in obtaining the kinetic and mechanistic information required in
the development of chemical mechanisms which adequately describe the
complex chemical transformations in the polluted troposphere QX7)•
Despite such progress and the increasingly sophisticated computer tech-
niques available to modelers, there has remained a critical need for a data
base sufficiently comprehensive and characterized to serve as a benchmark
against which computer kinetic models of various complexities may be
experimentally validated (b_-12) •
From July, 1973 through December, 1978, the Statewide Air Pollution
Research Center (SAPRC) conducted an experimental program for the EPA
involving the generation of an extensive set of environmental chamber data
which can be used for validating detailed chemical kinetic models for
photochemical smog formation. The photochemical experiments have consisted
of irradiations of a number of representative alkanes, olefins, aromatics
and oxygenates, both singly and in mixtures, in the presence of NOX in air.
In most cases, sets of experiments were done with varying initial hydro-
carbon and NOX levels; in many cases the effects of added aldehydes were
studied. In addition, for the propene-NOx system, the effects of tem-
perature, varying the initial NO/N(>2 ratio and the addition of PAN was
also studied.
For each experiment, detailed concentration-time profiles for the
reactants and all of the identifiable products, both major and minor, were
obtained. Physical parameters such as temperature, relative humidity and
light intensity were also monitored. In order that this data have maximum
utility for detailed model validation, attempts were made to control and
characterize the conditions of these experiments to the maximum extent
practical.
Results from the first 18 months of this program (July, 1973 through
November, 1974) have been reported previously (13). These included the
bulk of the chamber and light source characterization studies for this
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program. Thus, efforts to characterize surface effects and determinations
of ozone lifetimes, absolute light intensity, spatial homogeneity of light
within the chamber, mixing and equi^-jration times and sampling rates were
reported. Results from a set of preliminary experimental runs were also
reported. Data were given for the propene-NOx and n-butane-NOx photooxida-
tion systems and also for a study of the effects on these systems of
variables such as added aldehydes, temperature and initial NO/N02 ratio.
The present report provides the results of the remainder of the
experiments performed in this program. During the period covered by this
report (December, 1974 through December, 1978), in addition to 114 photo-
chemical runs and 52 associated actinometry experiments, further light-
source characterizations, mainly determinations of spectral distributions,
and several 63 and H202 decay experiments were also performed. The
experiments performed consist of the bulk of the SAPRC-EPA chamber program.
Because of improvements in light source characterization and experimental
techniques resulting from experience gained throughout this program, the
later photochemical runs reported here can be considered to be better
characterized. Thus, these supercede many of the earlier runs given in the
previous report.
2. EXPERIMENTAL FACILITY AND PROCEDURES
A. Facility
The SAPRC evacuable chamber-solar simulator facility in its
present configuration is shown schematically in Figure 1. Its design and
construction have been described in detail elsewhere (L3-J.6.). The salient
features of the evacuable chamber, the solar simulator, the pure air
system and the data collection system are summarized below.
Evacuable Thermostatted Chamber. The SAPRC evacuable chamber
is a cylindrical, aluminum alloy cell, 1.37 m in diameter and 3.96 m long
(surface-to-volume ratio 3.41 m"1), with the interior coated in FEP-
Teflon. The ends of the chamber consist of Teflon-coated grid structures,
each of which holds sixteen 33 cm x 33 cm quartz windows. Each window is
individually Viton 0-ring sealed to the grid, and the grids in turn are
bolted to the ends of the chamber through 0-ring sealed flanges. Thermal
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TRICHROIC
SPECTRAL
TEMPERATURE CONTROL MANIFOLD
( PARTIAL)
AMBIENT
AIR
INLET
MAGNETICALLY
COUPLED
STIRRING FANS
LN2
BAFFLE
10 DIFFUSION
PUMP
TO ROTARY
PUMP
QUARTZ
FOCUSING LENS
SECONDARY
MIRROR
TEFLON COATED
INNER SURFACES
in Situ MULTIPLE
REFLECTION
OPTICS
•XENON ARC LAMP
AND COLLECTOR
-FOLDING
MIRROR (FLAT)
COOLING
WATER PUMP
CRYOGENIC
SORPTION PUMPS
PRIMARY MIRROR
DISPENSER TUBE
MICHELSON
INTERFEROMETER
-CHAMBER IRRADIATION WINDOWS
ULTRAVIOLET GRADE QUARTZ
Figure 1. The SAPRC Evacuable Chamber-Solar Simulator Facility.
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fluid passages welded to the exterior of the chamber permit wall tempera-
ture control (to + 2 F) over the region 0 to 212 F by means of an ethylene
glycol-water mixture circulated thrc,.jh the passages from a remotely
located heat exchanger and refrigeration system. The exterior of the
chamber is insulated with fiberglass (1 inch) and polyurethane (2 inches)
and covered with an aluminum sheath. The volume of the chamber was exper-
imentally determined to be 5774 liters, in good agreement with the calcu-
lated volume of 5860 liters.
The chamber is equipped with a total of 23 flanged ports, with openings
ranging from 2 to 16 inches in diameter. As seen in Figure 1, two large,
diametrically-opposed parts are used to install multiple reflection optics
for in-situ IR or UV analyses. For the work reported here, such IR and UV
analyses were not used because of the low reactant and product concentra-
tions employed, though the optical mirrors were in place in the chamber
during most of these studies. Small ports were fitted with Swagelock
0-seal connectors (0.5 or 1 inch) to allow insertion of glass tubes for
injections and sampling.
The chamber is presently evacuated by means of a three-stage, hydro-
carbon-free pumping system to ~10~^ microns in four hours or less.
Through Run EC-120, the pumping system consisted of a liquid (water) ring
roughing pump and air ejector pump which evacuated the system to -10 torr,
and three cryosorption pumps, two of which, when used sequentially, further
reduced the pressure to 1-20 microns. For runs after EC-120, a 25.4 cm
diffusion pump employing a perfluorinated oil ("Fomblin" polyether) as a
working fluid was added to the system, and the chamber is now routinely
pumped to, and maintained overnight, at <10~2 microns.
Solar Simulator. The 25 KW solar simulator (15) was designed
to provide a collimated beam of light with an overall light intensity
uniform to +10% and with spectral fidelity to the deep-space solar spec-
trum, particularly in the 300-450 nm region. The output of a 25 KW xenon
arc lamp (Hanovia or Durotest) is collected and projected by a collector
mirror via a 45° flat mirror onto an optical integrator. The beam then
passes on to the collimating optics which are over-coated with magnesium
fluoride for peak reflectivity at 300 nm. A compact optical system was
obtained at the cost (due to the secondary mirror) of a "hole" in the beam
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whose diameter ranges from 25 to 11 cm over the length of the chamber.
The beam is collimated to a collimation half-angle of +1.1". Although this
collimation angle requires a larger clearance between beam and chamber
walls (beam diameter is 1.2 m) to minimize surface photochemistry, it also
reduces the effect of shadows caused by the secondary mirror and the window
grid structures. A trichroic spectral filter, designed to remove some of
the energy in the near-infrared portion of the spectrum (800-900 nm), was
placed on the input side of the optical integrator for most of the experi-
ments reported here. To achieve a good simulation of the tropospheric
spectral distribution, a 6.4 mm (0.25 inch) thick Pyrex pane is placed
between the solar simulator and the quartz end windows of the chamber.
Improved light intensity (as well as increased illumination of the shadowed
areas) is achieved by use of Alzak reflectors on the panes at the far end
of the chamber (13).
Pure Air System. Matrix air at a flow rate of 12-15 scfm is
provided by an air purification system which has been described in detail
previously (16). Ambient air is drawn through Purafil beds (to remove
NOX), compressed by a liquid (water) ring compressor to 100 psig, and
passed successively through a heatless dryer, a Hopcalite tower (to remove
CO) and a second heatless dryer packed with activated coconut charcoal. The
latter acts as a pressure-swing adsorption unit and routinely reduces the
hydrocarbon levels (as measured in the chamber) to 800 ppb methane, <5 ppb
of G£ hydrocarbons and propane and <1 ppb of all higher hydrocarbons. This
very dry, purified air stream, after filtering to remove any charcoal dust,
is heated, then divided into two metered streams, one of which passes through
a spray tower supplied with heated distilled water. The streams are re-
combined in the appropriate relative amounts to give the desired humidity.
Data System. Data collection from continuous analyzers was
accomplished by the use of a mini-computer data acquisition system based up-
on that developed by the Rockwell Science Center for the EPA-RAPS monitor-
ing stations. The system is built around a PDP-8 computer with 16 K of
core memory, and permits the continuous monitoring of up to 96 key station
readouts. Data for 03, NO, N02, NOX, CO, temperature, relative humidity
and relative light intensity (radiometer) were collected with this system
and recorded on magnetic tape. The remaining data were prepared in
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punched card form, and the two sats were processed using an IBM-360/50 or an
IBM 370/155 computer.
B. Procedures for Photochemical Runs
Preparation of the Chamber. Prior to each photochemical run the
chamber was evacuated (at ambient temperature) for at least 12 hours at
pressures of <5 x 10~2 torr (Runs £120) or <10~^ torr (Runs j>121).
Several times in this program, the chamber walls were further cleaned by an
evacuated bakeout at >200 F, followed by ozone conditioning at 10-20 ppm
(minimum of 12 hours). After Run EC-261, the chamber was further condi-
tioned by performing "dummy" propene-NOx-air irradiations (initial propene
sO.5-1 ppm, NOX sO.5 ppm) for at least four hours, following evacuated
bakeouts and actinometry experiments. This was done so that the condition
of the chamber following actinometry or evacuated bakeouts would resemble
that following a regular photochemical run. Experience has shown that this
is required to assure high reproducibility of replicate runs.
Pure Air Fill. Except as noted below or on the data sheets in
the Appendix, the chamber was filled with air prior to injection of the
reactants. To achieve the desired temperature and humidity of the matrix
air for each experiment, the pure air system was turned on at least 30
minutes prior to use and the chamber temperature controller was set to the
desired gas phase temperature. The humidified air stream was brought via a
heating wire-wrapped pipe to a manifold at one of the chamber ports, and
allowed to by-pass the chamber through a flow meter into a tube equipped
with both a Brady array humidity sensor and a wet-dry bulb thermometer set.
This arrangement allowed adjustment of both the humidity and temperature of
the air stream to the desired levels before diverting the flow into the
chamber.
The chamber was filled to a pressure of about 760 torr (about 25
torr above atmospheric pressure at Riverside) to allow installation of all
sampling probes under positive pressure. Prior to Run EC-197, the chamber
was then opened to the atmosphere via a filter cannister filled with equal
volumes of Purafil, charcoal and indicating Drierite throughout the experi-
ment. (Before each experiment, the cannister was backflushed with pure
air). Beginning with Run EC-197, the makeup air was provided from a Teflon
bag which was filled with purified air at the same temperature and humidity
6
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as used in filling the chamber. After filling the chamber but before
addition of the reactants, background levels of all species were determined
and the total nonmethane hydrocarbon level was generally ^80 ppbC.
Reactant Injections* Injections of reactants were generally made
45-60 min prior to the beginning of the irradiation, although in a number
of cases, small supplementary injections for fine-tuning were made up to 30
min prior to the irradiation. In some cases, formaldehyde, acetaldehyde or
benzaldehyde were expanded into the evacuated chamber prior to the pure air
fill. These cases are noted on the data sheets in the Appendix.
Injections and dilutions of gas phase reactants were generally done
using hypodermic glass syringes (B-D Yale 5, 10, 20 and 100 ml). Liquid
reactants were generally injected by adding the desired volume of the
liquid (using microsyringes) into a 1 liter glass bulb, whose contents
were subsequently flushed into the chamber with N£«
All reactants were obtained from commercially available samples
with the exception of N02 and formaldehyde. N02 was prepared by
reaction of NO with excess oxygen in a syringe. Formaldehyde was prepared
by heating previously dried paraformaldehyde at 373 K under vacuum, passing
the effluent through a trap at 179 K (methanol slush) to remove t^O and
other products, and collecting at 77 K (liquid N£ trap). The desired
pressures of formaldehyde were then expanded into a glass bulb of known
volume, whose contents were subsequently flushed or expanded into the
qhamber•
The injection sequence was generally as follows: the injection
tube was flushed with N£, NO was added, the tube was flushed again with
N2f the remaining reactants (hydrocarbon, N02 and, for some runs, CO)
were added, followed by a final flush with N2« For some runs, adjustment
to the desired N02 level was made by adding the necessary volume from the
previously prepared sample of NO in 02 as soon as a steady reading was
obtained for NO and N02» after injection of NO. For runs before EC-230,
reactants were flushed directly into the chamber. For Run EC-230 and those
following, the system for injection of reactants was modified to include a
1.6 cm (I.D.) Teflon disperser tube which runs the length of the chamber.
Employing this system reduced mixing times to ~10 minutes.
Irradiation Procedure. The solar simulator was brought to the
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desired power level with the douner in place at least 5 minutes prior
to the start or irradiation. The chamber wall temperature control was
switched to refrigerate at a setting of about 5 F below the desired gas
phase temperature ~5 minutes before the run was begun in order to mini-
mize the variation of the gas phase temperature due to the solar simulator
heat load. During an experiment, a radiometer (EG & G Model 550) placed at
the far end of the chamber facing the solar simulator is maintained within
+0.02 mw/cm2 of the value determined in the actinometry. Beginning with
Run EC-106, the relative spectral distribution of the photolyzing light was
determined at least once at approximately the middle of the run.
Sampling. Following the pure air fill, the continuous moni-
toring instruments for 03 and oxides of nitrogen (see Section 3) were
attached, and began to withdraw air from the chamber. The sampling rates
for these instruments were measured periodically, and are reflected in the
total sampling rates given for each run on the data sheets in the Appendix=
Sampling for formaldehyde, 1^02 and for GC or GC-MS analysis using
Tenax trapping was done prior to the irradiation (reported on the data
sheets as the T = 0 value) and, generally, at hourly intervals. Sampling
times were usually 20 min for formaldehyde, 30 min for H202 and 15 min for
Tenax trapping. Sampling rates were measured with calibrated rotometers
and are reflected in the total sampling rates given on the data sheets for
each run. For formaldehyde and 1^02, concentrations and volumes of gas
samples are reported at the midpoint of the sampling time (except at T = 0,
as noted above), while volumes and concentrations derived from Tenax
trapping are reported for the beginning of the sampling time.
Sampling for chromatographic analysis (except for those using Tenax
trapping) were done employing 100 ml syringes. The syringes were flushed
1 or 2 times (100-200 ml withdrawn) with air from the chamber before
taking 100 ml for analysis. Samples for each type of chromatographic
analysis were generally taken before reactant injections, after injections
and before irradiation, immediately before the start of the photolysis and
at regular intervals thereafter. The total number of such GC samples taken
is recorded for each run on the data sheets in the Appendix, but its
contribution to the total sampling rate was generally negligible.
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C. Procedures for Actinometry Experiments
The determination of kj for photolysis of N02 in a nitrogen
atmosphere according to the method of Holmes et al. (17) was used to
determine the absolute light intensity in the evacuable chamber. Before
Run EC-324, the solar simulator was brought up to the approximate desired
power level before filling the chamber, and then was unshuttered briefly
to allow adjustment of power to give the desired radiometer value. For Run
EC-324 and those following, the solar simulator power was held at the set
Value used for the associated photochemical runs and the radiometer value
was riot adjusted. The solar simulator was shuttered and the chamber was
filled with nitrogen of 2.99.995% stated purity level. Approximately 20 torr
of vacuum-distilled N02 (<1% NO) in a 500 ml bulb was then flushed into
the chamber with nitrogen.
After mixing was completed and constant initial values for NO and
N0£ were obtained, the solar simulator was unshuttered and a one or two
minute irradiation carried out. Radiometer readings (with a 330 nm inter-
ference filter of 80 nm full-width at half maximum) were taken every 10
seconds during the irradiation, and solar simulator power settings (product
of current and voltage panel meter readings) were recorded, at least in-
itially and at the end of the irradiation. During this brief irradiation
period, the light intensity did not vary significantly (<0.01 mw/cm^).
The final N0£ concentration was allowed to stabilize (<20 min) after the end
of irradiation. The formula of Holmes et al. (17), including the term to
correct for the initial NO concentrations, was used to calculate the k^
value (see Section IV-C).
3. ANALYTICAL METHODS AND PHYSICAL MEASUREMENTS
A. Temperature
The sample temperature was monitored with a radiation iron-constantan
thermocouple inserted via a glass probe into the dark space in the center
of the chamber, at the end remote from the solar simulator. A Doric
Model DS-350 Thermocouple Indicator Type J provided temperature readout
in degrees F with an accuracy of +2 F. Good gas phase temperature con-
trol (±2 F) was maintained during photolyses by setting the controller
9
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4-5 F below the desired temperature. There was some radiation heating
of the thermocouple probe even though it was located in the dark space in
the center of the chamber and was further shielded by a foil .cover. This
has been estimated to be about 2 F by shuttering the simulator and deter-
mining the immediate temperature change. The data presented have not been
corrected for this.
B. Relative Humidity
A Brady array (Thunder Scientific) mounted in a bulkhead fitting
was used to measure relative humidity (RH). The response in volts (V) was
converted to % RH using the calibration (at 85 F) function supplied by the
manufacturer•
Substantially more variation occured in the relative humidity than
could be accounted for by the changes in gas phase temperatures during an
experiment. Prior to Run EC-197 some increase in RH might have been
attributed to filtered makeup air which was not of the same water content.
However, Runs EC-214 and EC-216, which showed similar increases in RH, were
provided with makeup air identical to that used to fill the chamber in-
itially. The Brady arrays used for this measurement were calibrated at 85
F and at that temperature were reliable to _+5% RH. However, since the
Brady was bulkhead mounted into a flange on the wall of the chamber, it may
have been cooled to 80 F or less. Except as noted on the data sheets in
the Appendix, the water content of the matrix was very well controlled at
the time of the chamber fill, to be 50 ± 5% RH at 85 F. This was probably
the best indicator of the water concentration present in the chamber.
C. Ozone
A Dasibi Model 1003 UV absorbance analyzer was used to monitor ozone
(03). Prior to June, 1975, calibration was checked periodically using the
2% neutral buffered potassium iodide method (NBKI). However, this method
was shown to yield ozone concentrations which were ~20-25% high at 50% RH
(_18_»_19.)» and since that time, calibrations against a UV standard have been
performed. Ozone concentrations obtained with instruments calibrated by
the NBKI method have been corrected by a factor of 0.8. The overall accu-
racy of the 03 data is estimated to be +5%*
10
-------
D. Oxides of Nitrogen
A TECO Model 148 chemiluminescence analyzer was used to monitor
nitrogen oxides (NO, N02, NOx) • The instrument measures the chemilumi-
nescence from the reaction of NO with 03 which takes place in a reaction
chamber maintained at reduced pressure. The response of the instrument is
inversely proportional to this reaction chamber pressure. However, the
reaction chamber pressure is instrumentally shown as reaction chamber
vacuum relative to ambient atmospheric pressure. At a constant vacuum
reading, as carried out in practice, changes in ambient room pressure will
translate into reaction chamber pressure changes with an approximate
four-fold percentage amplification. We have provided an additional valve
and replaced the standard pump with a high capacity vacuum pump in order to
regulate the reaction chamber vacuum to within ;f0.50%.
Calibration (20) was carried out using a modified CHAMP (Continuous
Health Air Monitoring Program) calibrator, which is a flow dilution system
with calibrated mass flow meters and an NBS standard NO calibration cylin-
der. Zero readings were set with medical breathing air during calibration,
and with air passed through an MSA Type N filter between calibrations (ozone
generator off). The TECO converter efficiency was checked using N0£
generated by gas phase reaction of the NO and 03 and was always found to
be 100 + 5%.
The analysis for N0£ and NOX is complicated by the fact that the
converter converts organic nitrates (such as PAN and alkyl nitrates) and
HN03 to NO (21). Since the conversion of organic nitrates is quantitative
(21), N02 and NOX data can be corrected by subtracting off the PAN and
organic nitrate concentrations which were measured using independent
methods. (Linear interpolation was made between PAN and nitrate data
points since, in general, these data were taken less frequently than
NOx data). Unfortunately, HN03 was not routinely monitored, and the
extent of HN03 interference is uncertain. Tests with nylon filters,
which are believed to quantitatively remove HN03 (22). indicate that HN03
interference is significant in runs containing >2-5 ppm NOX, but that it is
probably negligible in runs with lower NOx levels, such as those reported
here. It appears that low levels of HN03 are removed by the walls of
the sampling tube before entering the converter.
11
-------
A comparison of the TECO 14B with the Bendix analyzer which had
been calibrated in the same way showed analyses for NOX to be generally
within 10%. The accuracy for the N02 a*id NOX measurements is primarily
limited by uncertainties in PAN and alkyl nitrate measurements used in
correcting for interferences, and the possibility of interference by
HNC>3 or by unmonitored organic nitrates.
E. Formaldehyde
The chromotropic acid method (23) was used to monitor formaldehyde
(HCHO). Samples were taken in a single bubbler containing 10 ml of
distilled water at the rate of 1 fc/min. The developed solutions were read
on a Bausch and Lomb Spectronic 20 formaldehyde (calibration #1 on the data
sheets) and a Beckman 35 Spectrometer formaldehyde (calibration #2 and #3
on the data sheets).
The chromotropic acid method for monitoring formaldehyde has shown
more unexpected and inexplicable results than any other analysis we use.
The major problem during the period reported here was a series of anomalous-
ly low data for Runs EC-177 through EC-188 (EC-179 through EC-188 were done
for another program and are not reported here). The cause is still not
known; a possible explanation is the use of a different bubbler (a new one
or one with a coarse rather than extra coarse frit). For some of the
earlier experiments, the blank and low concentration samples showed con-
siderable yellowing= It was later discovered that a residue was accumulat-
ing both in the volumetric flasks and in the cuvettes. By routinely using
concentrated ^804 to clean all glassware (beginning before Run EC-216)
this problem has been eliminated.
Recent calibration of the method, using accurately known HCHO concen-
trations in N£ prepared in a high vacuum system and diluted down to
concentration levels of ilOO ppb using a flow dilution technique, has
shown the general reliability of our procedure, as used, to be +10-15% with
2.90% of the total HCHO trapped in the first bubbler. Good agreement was
also obtained when known amounts of HCHO were injected into the EC prior to
the pure air fill, provided that the disperser tube was not used (see
data for Runs EC-336). When known amounts of HCHO were injected into
the chamber using the disperser tube (Runs EC-250 through EC-257),
12
-------
the chromotropic acid measurements were only -60% of the calculated
values. This may be due to absorption on the walls of the dispersion tube,
though problems with the chromotropic acid technique cannot be ruled out.
The overall reliability of the HCHO measurements, beginning with Run EC-216
is estimated to be +10 to -30%.
F. Hydrogen Peroxide
\
Two procedures were examined for the determination of hydrogen per-
oxide. Initially, the Ti(IV)-8-quinolinol method for H202 determination
(24) was attempted using various dilutions of a standard H202 solution.
The "450 mU" absorption maximum of the peroxy-titanium 8-hydroxquinolate
complex was found to occur anywhere from 440 to 465 my, and poor repro-
ducibility of absorbance values has prevented establishing a satisfactory
calibration. This procedure was abandoned in favor of the titanium tetra-
chloride procedure of Pilz and Johann (25) which, though less sensitive, is
manipulatively much simpler, with relatively few uncertainties being
introduced in the course of developing the solutions. This procedure was
applied for H202 determinations on Runs EC-247 through EC-257.
The TiCl^ procedure was carried out as follows: A stock solution
of TiCl4 in concentrated HC1 was prepared and was pulled through a fritted
(very fine) funnel. A 25 ml aliquot of this was diluted 1:9 by the addi-
tion of distilled water each morning prior to the experiment. An air
sample was drawn through an impinger containing 5-10 ml of the dilute TiCl^
solution, usually for 30 minutes at 1 liter per minute. The exposed
solution was transferred quantitatively to the appropriate size volumetric
flask and brought up to volume with the dilute TiCl4 solution. The visible
absorption spectrum (700 to 350 nm) of the complex of TiCl4~H202 was
recorded using 5 cm pathlength semimicro cells. Calibrations with stan-
dardized H202 gave absorption coefficients in good agreement with that of
Pilz and Johann (735 M""1 cm"1 at !\max = 410 nm).
Because of the light scattering resulting from the formation of fine
particulate in exposed samples (presumably Ti02 in samples taken from the
chamber), the use of the usual blank vs. blank reference spectrum tends to
lead to overestimates of H202 concentrations. This can be seen in Figure
2, which gives spectra (normalized at 700 nm) of (a) the unexposed
solution, (b) a sample exposed to air containing no H202 (sample #1
13
-------
0)
o
C
cd
rQ
S-l
o
en
(a) blank vs. blank
(b) #1 vs_. blank
(c) #7 vs. blank
filter
change
400
500
Wavelength (nm)
600
700
Figure 2. Absorption spectra of samples from the TiCl method for monitoring
IL,O0 taken during EC-255.
-------
is that taken prior to the start of the run) and (c) of a sample containing
the TiCl4~H202 complex at a concentration corresponding to 8 ppb H202 in
air. The absorbance at 410 nm has been calculated for each sample relative
to that in the #1 sample, each normalized to their respective values at 700
- [i.e., Abs£0 - <0-A700) - ttjjo-^)].
It can be seen from the data sheets in the Appendix that generally no
more than 13 ppb of H202 was determined by this method, the only excep-
tion to this being Run EC-247, in which 20 ppb 1^02 was observed. (This run
also formed 0.6-0.7 ppm 03, 2.5 times more than any other run in which 1^2
was monitored). The observed scatter in the data suggests a random uncer-
tainty of at least +5 ppb.
G. Carbon Monoxide
A Beckman Model 6800 Air Quality Gas Chromatograph, which was cali-
brated daily, was used to monitor carbon monoxide (CO). The stainless
steel (SS) standard CO calibration cylinder which has been used over the
course of this work has shown a gradual (~1% per month) loss of CO, and
beginning in January, 1976, the SS standard cylinder has been periodically
cross-calibrated against a new aluminum standard cylinder. The CO data
have been corrected for the decay of CO in the SS cylinder used here and
are reliable to about +10%.
H. Organic Reactants and Products
Organic reactants and products were monitored by gas chromatography
employing flame ionization (FID) or electron capture (BCD) detection.
Brief descriptions of each system used, along with lists (in order of re-
tention times) of compounds they were used to monitor, are given in Table
1. For selected compounds, approximate sensitivities obtainable during
routine monitoring and approximate calibration accuracies are also given
in the table. The techniques employed with the various systems, and the
calibration techniques and special problems associated with the analysis of
specific compounds using these systems are discussed below.
Table 1 also gives the designations for the compounds (or sum of
compounds in cases of overlapping peaks) used on the detailed data sheets.
Some compounds can be monitored by more than one system—in those cases,
the Table indicates which column was most often used to derive the data
15
-------
Table 1. Chromatographic Systems and Compounds Monitored by Each
GC System
Abbreviation Description Compound
PN 51 X 1/8" SS Porapak N; 60 C; Methane
FID Ethene
Ethane
Acetylene
QMS 36' X 1/8" SS 10% 2,4- Propane
dimethylsulfolane on C-22 Propene
Firebrick, 0 C and 2' X 1/8" Isobutane
SS 10% Carbowax 600 on C-22 n-Butane
Firebrick; 0 C; FID Neopentane
Acetylene
1-Butene
Isobutene
Cis-2-butene
Trans-2-butene
2 , 3-Dimethylbutane
10' C-600 10" X 1/8"SS10% Carbowax Acetaldehyde
600 on C-22 Firebrick; 70 C; Ethylene oxide
FID Propylene oxide
Propionaldehyde
Acetone
Butyr aldehyde
Methyl nitrate
Methyl ethyl ketone
Ethyl nitrate
Benzene
Isopropyl nitrate
n-Propyl nitrate
Toluene
2-Butyl nitrate
1-Butyl nitrate
m-Xylene
•a
Compounds Monitored
. Sensitivity0 Calibration
Abbreviation (ppb) Uncertainty Notes
METHANE 7
ETHENE 0.2 +,«
ETHANE 0.2
ACETYLEN 0 . 2
PROPANE 0.05
PROPENE
I-C4
N-C4 0.05 }
NEO-C5 , > e,f
(ACETYLEN) 0.1 ±2% )
1-C458
1-04"°
C2-C4"
T2-C4=
2,3-DMB 0.1
ACETALD 0.05 ±25%h
- ff
(ETOX)d - B
PROX ( + sy
PROPALD j
ACETONE 0.05 ±20%
BUTYRALD ±5% )
(ME-N)d - > e,i
MEK 0.05 )
(C2-N)d
BENZENE 0.02 ~
(C3-N-2)d 0.1
(C3-N-l)d 0.1
TOLUENE \
(C4-N-2)d ±10% J 6
(C4-N-l)d v
M-XYL 0.1 \ ±37.
-------
Table 1 (continued) - 2
GC System
Abbreviation Description
PANALYZER
3-PART
t
3' C-600
5' C-600
SP-1000
12" X 1/8" Teflon 5% Carbowax
400 on Chromosorb G; 28 C;
BCD
10' X 1/8" SS 5%, 1,2,3-tris-
(2-cyanoethoxy)propane and
51 X 1/8" SS 5% Bentone 34 +
5% dinonyl phthalate both on
HMDS gas chrotn W; 3' X 1/8"
SS 10% Carbowax 600 on C-22
Firebrick; 65 C; FID
3' X 1/8" SS 10% C-600 on
C-22 Firebrick; 90 C; FID
5' X 1/8" SS, 5% C-600 on
C-22 Firebrick; 90 C; FID
6'X 1/4" X 2 mm ID glass;
0.1% SP 1000 on Carbopack C;
temp. prog. 150 C •*• 250 C <§
20 C/min; FID; Tenax cart-
ridge sampling
Compounds Monitored
Compound
Methyl Nitrate
Ethyl Nitrate
2-Propyl Nitrate
2-Butyl Nitrate
1-Propyl Nitrate
Peroxyacetyl Nitrate
1-Butyl Nitrate
2,3-Dimethyl Butyl
Nitrate
Acetaldehyde
Ethylene oxide
Propionaldehyde
Acetone
Butyraldehyde
Methyl ethyl ketone
Toluene
m-Xylene
Benzaldehyde
Toluene
m-Xylene
Benzaldehyde
m-To lua 1 d ehy d e
Benzaldehyde
Benzyl nitrate
o-Cresol
m-Cresol
p-Cresol
o-Nitro toluene
m-Nitrotoluene
p-Nitrotoluene
Sensitivity0 Calibration
Abbreviation (ppb) Uncertainty Notes
Cl-N
C2-N
C3-N-2
C4-N-2
C3-N-1
PAN
C4-N-1
(DMB-N)d
(ACETALD)d
ETOX
(PROPALD)
(ACETONE )<*
(BUTYRALD)d
(MEK)d
(TOLUENE) d
(M-XYL)d
BZALD
TOLUENE
M-XYL
BZALD
M-TOLALD
BZALD
-
O-CRESOL
M-CRESOL
P-CRESOL
ONT
MNT
PNT
0.5
0.3
0.3
0.1
0.6
0.2
0.6 \
0.1 f
5.0
0.02
0.03
0.5 \
0.5 /
0.1
0.1
0.1
0.1
0.2
0.3 1
0.4 |
0.5 1
±5%j
±10%3 \
±20%k ;
±20%k \
±20%k /
±25%1
±20%
m
±25%
±15%
±15%
±20% \
f
±5Z
f
~
±100%
±5%
±10%
+
±10% \
f
±25%
±30% \
±15% /
±10%
e
n
g
g
e
-------
Table 1 (continued) - 3
oo
GC
X
Abbreviation
TENX-GC 10' X
Tenax
250 C
System
Description
1/4" X 2 mm ID glass;
GC; temp prog. 100 C •*•
@ 20 C/min; FID; Tenax
cartridge sampling
Compounds Monitored
Compound
Benzaldehyde +
Benzyl nitrate
o-Cresol
o-Nitrotoluene
m-Nitrotoluene +
2,3-Hydroxy
nitrotoluene
p-Nitrotoluene +
4,3 Hydroxy
nitrotoluene
V
Abbreviation
BZALDBZN
O-CRESOL
ONT
MNT23HNT
FNT43HNT
Sensitivity0 Calibration
(ppb)
0.1 1
0.1 ]
0.1
0.2
0.2
0.2
0.2
0.3
Uncertainty Notes
10% J g
15%
40% g
20% I
> O
50% / g
Partial list. Restricted to compounds observed in experimental runs given in this report.
Abbreviations as used on data sheets.
CSensitivity is defined as the approximate concentration which gives a signal/noise ratio of 2.
Unless stated to the contrary on the data sheets, the data given for this compound on the data sheets was obtained
using another system.
CCompounds indicated interfere significantly. The presence of large levels of one will make analysis of the other(s)
more uncertain.
fDespite overlap, n-butane and neopentane can be reliabily monitored together if present in roughly equal quantities.
g
Compounds indicated cannot be separated with this GC system.
There is significantly less uncertainty if response by peak area is used.
Because of overlap with butyraldehyde and methyl ethyl ketone, methyl nitrate is not monitored using this system.
1 k
•"Calibration valid for concentration < 10 ppb only. Calibration valid for concentration < 20 ppb only.
Nonlinear calibration curve used, wo authentic sample available for calibrations.
Interference by.^water peak prevents quantitative analysis of this compound on this system.
-------
given on the data sheets, unless stated otherwise.
Aliphatic Hydrocarbon Analysis Using the Porapak N and Dimethyl-
sulfplane Systems. The GI and €2 hydrocarbons were monitored employing
5' x 1/8" stainless steel columns packed with 100/120 mesh Porapak N held at
60 C. The N£ flow was 80 ml/min. Two separate Porapak N (PN) systems were
used throughout this program—one in each of our two chromatography labs.
Acetylene and the 03+ alkanes and olefins were monitored employing 34' x
1/8" stainless steel columns packed with 10% 2,4-dimethylsulfolane (DMS) on
C-22 firebrick held at 0 C, in series with 2' x 1/8" stainless steel "soaker"
columns containing 10% Carbowax 600 on C-22 firebrick (30/60 mesh). As
with Porapak, two separate DMS systems were used throughout the program.
With one, the DMS support was 60/80 mesh and the N£ flow was 26 ml/min;
With the other, the support was 100/120 mesh and the N2 flow was 50
ml/min. The DMS and Porapak N systems in both laboratories employed flame
ionization detection.
The DMS and Porapak systems were calibrated by sequential quantitative
dilutions of 2 ml of the pure gas (as measured by a 5 ml hypodermic syringe)
or of 1-10 yl of the pure liquid (as measured by micropipet) into two
specially designed ~2 liter flasks of accurately known volume (26^,27}.
The precisions of the calibrations measured were generally +3%.
With the exception of analysis for methane on the Porapak system,
or analyses where higher concentrations (2.0.5-1 ppm) of reactants were
monitored, 100 ml samples from the chamber were concentrated prior to
injection using a liquid argon- or liquid oxygen-cooled 12" x 1/8" stain-
less steel trap (packed with 10% DMS on 40-60 mesh C-22 firebrick). The
traps were then warmed with an ice bath (to attain a reproducible tempera-
ture) briefly, prior to the injection of their contents into the column.
For methane or high concentration reactant analysis, a 2-3 ml loop was
flushed with the 100 ml sample from the chamber, and its contents were
injected directly into the column. Separate calibrations were done for
"loop" and "trap" analyses.
The overall accuracy of these measurements is generally ±5%. This
is supported by the fact that when analyses have been carried out on the
same mixture using the two independently-maintained Porapak N or DMS
systems, the results agree to within 10%. The aliphatic hydrocarbons all
19
-------
gave a constant response per un±L concentration over the range of concen~
trations studied.
Aromatic Hydrocarbon, Oxygenate and Organic Nitrate Analysis
Using the 10" C-600 System. For most runs analysis of aromatic hydrocar-
bons, aliphatic aldehydes and ketones and C-^ organic nitrates were
monitored using a 10' x 1/8" stainless steel column of 10% Carbowax 600
on C-22 Firebrick (100/120 mesh) operated at 70-75 C. The N2 flow was
held at 50.5 ml/min, and flame ionization detection was used. Sampling
was carried out as described above, except that the trap for sample
concentration was packed with uncoated glass beads. Calibrations for
oxygenates and organic nitrates were generally done as described above.
Aromatic hydrocarbons were calibrated by micropipeting 1 yl each of
the aromatics of interest in pre-flushed ~50 liter bottles of accurately
known volume, diluting this mixture by injecting a 20 ml aliquot into a
~2 liter flask, from which calibration samples were taken.
Calibrations were generally carried out with two to five compounds
at a time, and these were chosen to avoid overlap of the GC peaks. With
the exception of acetaldehyde, which will be discussed in detail below,
the precision of the calibration measurements was generally excellent
(+3%). Peak height was assumed to be a linear function of concentration
over the range of concentrations found in these experiments, except for
oxygenates. Estimates of calibration accuracy are given in Table 1.
Estimated sample measurement accuracy could approach +2% under ideal
conditions, but most measurements were considerably more uncertain. The
major causes of sample measurement uncertainties were low yields (i.e., very
small peaks) or interferences (i.e. peak overlap) with a compound present
at a higher concentration. (Table 1 indicates which compounds suffer
significant interferences in the chromatographic analyses). For example,
for propene + n-butane runs, measurements of propionaldehyde and butyral-
dehyde were uncertain by 15-25% and measurements of propylene oxide and ethyl
nitrate were uncertain by +50%.
The acetaldehyde analysis has turned out to be particularly diffi-
cult to do accurately. The calibration is complicated by the fact that
acetaldehyde is a very low-boiling liquid (BP =21 C), making it difficult
to handle in a quantitative way using the standard procedure of transferring
20
-------
with a micropipet. In addition, it has a very assymmetrical peak shape,
and the peak height can vary significantly from sample to sample, and as a
function of concentration. The overall reliability of the acetaldehyde
measurements has been determined on the basis of calibrations carried out
recently using a flow dilution technique analogous to that used for HCHO
calibration (see Section III-E), except that in this case, the diluted
mixture of acetaldehyde in N£ was analyzed from a 5.47 liter Pyrex bulb
which had been flushed with this mixture for ~2 hours. Measurements of
both peak area response and peak height response were made. Where possi-
ble, peak areas were determined for samples taken during the runs reported
herej and estimates of accuracy based on comparison of concentrations
obtained from peak heights vs. peak areas are given in Table 2. Because of
the attenuation required to observe the propene oxide (e.g., 1,2 epoxy
propane) peak, it is not possible to determine areas for all the acetal-
dehyde peaks in all the runs, but the scatter observed in the experimental
data is generally smoothed out when areas are taken into account. Oc-
casionally, there will be an anomalous value due to a poor sampling. All
data given on the data sheets are based on peak height response.
In runs containing 2,3-dimethylbutane, an unknown peak on the C-600
column was observed which was attributed to 2,3-dimethylbutyl-2-nitrate
(DMB-N). Although no authentic sample of this compound was available, this
assignment was made based on the facts that (1) it is an expected product in
2,3-dimethylbutane runs, based on observations of alkyl nitrate yields in
other larger alkane systems (28), (2) the C-600 retention time corresponded
to what one would expect for DMB-N and (3) in the same runs, an unknown
peak appeared on the Panalyzer (which also monitors organic nitrates;
see below) , with a retention time appropriate for DMB-N. The C-600
calibration factor was estimated based on those obtained for other C,^
alkyl nitrates, and is estimated to be uncertain by at least + 50%.
PAN and Alkyl Nitrate Analysis Using the Panalyzer System. PAN
and the alkyl nitrates were monitored by GC using electron capture detec-
tion (ECD) and an 18" x 1/8" Teflon column of 5% Carbowax 400 on chromosorb
G (80/100 mesh) operated at ambient temperature (_2£,_30). All analyses on
this system were done by flushing a ~2 ml loop with a 100 ml sample, then
injecting the contents of the loop onto the column; the high sensitivity
21
-------
Table 2. Comparison of Acetaldehyde Concentrations Determined from
Area Response with Thota from Peak Height Response on the
10' 10% C-600 System
Run Number Concentration Uncertainty
95-106 20-30% highb
113-121 5-20% lowb
179-188 0-5% lowb
207-216 5-20% high
230-236° 0-10% high
256-279 5-20% low
Height response/area response. The area response is estimated to be
reliable to +10%.
Peak height data were not corrected for error in density of acetal-
dehyde used to calculate calibration factors; and the peak height
data should be higher by 6%. The numbers on this table do not take
this into account.
£
Run 230 was anomolous, 25% high.
22
-------
of the BCD to the nitrate group made sample concentration unnecessary.
Due to the limited linear range of the BCD, a calibration curve
is required for each compound. Calibrations for PAN response have been
carried out using three independent methods for obtaining dilution of
PAN to a variety of concentrations [PAN was prepared as described previous-
ly (3_D3» All methods rely on the determination of the PAN concentration
in a pressurized cylinder by infrared absorption of the 8.65 y band of
PAN (30) (e = 13.9 x 10~4 ppnT1) in a 10 cm pathlength cell using a Perkin-
Elmer Model 137 IR spectrophotometer. PAN calibrations throughout this
program showed some degree of scatter, but generally agreed to within
±20%, regardless of the method used. Because of the known instability of
PAN and its catalytic decomposition on metal surfaces (32), it would be
expected that the most correct values are those of maximum response for a
given PAN conencentration. However, the general agreement obtained using
the independent methods which provide a variety of surfaces suggests that
PAN decomposition is not a substantial factor in determining the reliabil-
ity of calibration curves. Some of the scatter in the PAN calibrations may
also have been due to the uncertainty of the infrared determination of the
PAN sample prior to dilution.
There are several other factors to be considered in evaluating
the accuracy of the PAN data. A major one is degree of control of operat-
ing parameters provided by the GC system itself* A Wilkens Instrument
& Research, Inc., Model PAN-680 GC purchased in 1963 was used for this
analysis. Although this instrument does not provide the oven temperature
control of newer instruments, it does have a standing current control.
For all of the work reported here, calibrations and experiments, the
standing current has been maintained within ±27, of a fixed value. This is
of major importance since there is an approximately 1:1 correlation between
response and standing current. The instrument was operated near ambient
temperature and the oven temperature ranged from 24-32 C, and retention
times for PAN have been 0.95-1.45 minutes. Although an increased response
for shorter retention times is expected, such a trend has not been observed.
This may be a result of changing calibration methods or there may, in fact,
be less thermal decomposition of the PAN at the lower operating temperature
(longer retention time) which compensates for the reduced peak height.
23
-------
A recent report by Holdren and Rasmussei (33_) claimed that the re-
sponse of GC-ECD systems to PAN can be dependent on the moisture content of
the PAN sample. Specifically, they found maximum GC response to PAN when
the samples were at very high (~100%) relative humidity (RH) and a much
lower response when the RH dropped below about 30%. Subsequent studies by
Watanabe and Stephens (34). however, showed that such effects were signifi-
cant only for acid-washed glassware.
The overall accuracy of the data for PAN was estimated to be ^20%;
and +50% for methyl and ethyl nitrate. For the larger organic nitrates,
the C-600 analysis was considered to be more accurate, and the BCD data was
not used when C-600 data was available.
Aromatic Hydrocarbon and Oxygenate Analysis Using the 3-Part
System. For some runs, aromatic hydrocarbons and/or oxygenates were
monitored using a 3-part column consisting of three 1/8" stainless steel
tubes in series, packed as follows: 5% 1,2,3-tris(2-cyanoethoxy)-propane on
HMDS Gas Chrom W (100/120 mesh) (10'), 5% bentone 34 + 5% dinonyl phthalate
on HMDS Gas Chrom W (100/120 mesh) (5'), and 10% Carbowax 600 on C-22
firebrick (30/60 mesh) or HMDS Gas Chrom W (100/120 mesh). The columns
were held at 65 C, N2 flow was 36 ml/min. and flame ionization detection
was used. Calibration and sampling for this system was exactly as de-
scribed for the C-600 system.
In general, this system did not separate the oxygenates as well as
did the C-600 system, so use of the C-600 system for oxygenate analysis was
preferred. However, the 3-part system gave better separation for ethy-
lene oxide (i.e., 1,2 epoxyethane) so it was used to monitor that compound.
An indication of the uncertainties in the acetaldehyde analysis can be
obtained from selected runs in which acetaldehyde was monitored using both
the three-part system and the C-600 system (only the C-600 data is reported
on the data sheets). Some of the difficulties encountered in carrying out
the acetaldehyde analysis are discussed in Section 3.
Benzaldehyde Analysis Using the 3' C-600 System. In the earliest
toluene runs (EC-82 through EC-86), benzaldehyde was monitored using a
3' x 1/8" stainless steel column packed with 10% Carbowax 600 on C-22
firebrick (100/110 mesh) held at 90 C. The N2 flow was 50.5 ml/min. and
24
-------
flame ionization detection was used. Sampling was done by flushing a ~2
ml loop whose contents were then injected into the column. Calibration was
done as described for oxygenates on the 10' C-600 or the 3-part columns.
This method has proven to be inappropriate because benzaldehyde is difficult
to quantitatively evaporate, suggesting that all of the 3' C-600 benzalde-
hyde data may be systematically high.
Interference by an unknown contaminant peak (which was not a product
of the runs, but nevertheless could not be eliminated) also made this
analysis highly uncertain. At best, this analysis is uncertain by +50%,
with the uncertainty increasing significantly as the concentration de-
creases. This analysis was superceded by the SP-1000 analysis and, later,
by the 5' 5% C-600 analysis, both described below.
Aromatic Product Analysis Using the SP-1000 System. Benzaldehyde,
cresols and nitrotoluenes were monitored using a 6' x 2 mm I. D. glass
column packed with 0.1% SP-1000 on Carbopack C. N£ flow was held at 20
ml/min. and flame ionization detection was used. Samples for analysis on
the SP-1000 column are collected by drawing a known volume of sample
(generally -10 liters) through a 60-80 mesh Tenax-filled, 3" x 4 mm I. D.
tube at ambient temperatures. The Tenax tube was placed in series with the
SP-1000 column and heated to 250 C, while the column was held at 150 C.
The carrier gas then drove the compounds of interest off the Tenax tube
and onto the column. Following the desorption process, which took 20
minutes, the column was temperature-programmed from 150 C to 250 C at 20
C/min.
Prior to Run EC-330, calibrations were done by placing known volumes
of dilute methanol solutions of the compound of interest directly into the
Tenax-filled tube, then desorbing the contents of the tube into the
column as described above. For Run EC-330 and those following, calibra-
tions were done by injecting known amounts into the evacuable chamber and
sampling from the chamber using the same procedure as for an experimental
run. The samples were introduced into the chamber using vacuum techniques
or by measuring the weight change of a glass-wool-filled tube, in which the
compound was introduced, before and after being flushed with N£ into the
chamber. The precision of the earlier "liquid" calibrations was generally
+10-50%. The precision of the "chamber" calibrations (based on both
25
-------
methods of sample injection into the chamber) was +9% for benzaldehyde
and m-nitrotoluene and +20% for o-cresol.
Several problems were inherent .o the SP-1000 analysis. The procedure
employed using this system was more difficult than any of the other GC
analyses, and caused it to be generally less precise than the others.
Temperature programming resulted in rapid baseline changes around the time
of benzaldehyde elution, which resulted in very broad and asymmetrical peak
shapes for this compound. Contaminant peaks were a problem which could not
be eliminated. In general, all analyses using this system can be considered
reliable to within +50% at best. This is consistent with the benzaldehyde
data given on the data sheet for Runs EC-335 through EC-340, which were
obtained using both this system and the considerably less uncertain 5' 5%
C-600 system (see below).
Aromatic Product Analysis Using the Tenax GC System. For several
runs, cresols, nitrotoluenes and hydroxynitrotoluenes were monitored using
a 10' x 1/8" glass column packed with 60/80 mesh Tenax GC (Altech). The
N2 flow was held at 20 ml/min. The sampling procedure employed was
similar to that used for the SP-1000 system (the same instrument was
used). The Tenax traps were heated to 250 C and its contents were desorbed
onto the 100 C column for 5 min. The column was then temperature-pro-
grammed from 100 C to 250 C at 20 C/min. Calibrations were done by micro-
syringing methanol solutions of the compounds of interest on the Tenax
traps, as done for the SP-1000 system. The uncertainty of the data ob-
tained using the Tenax GC system is probably comparable to, or greater
than, the uncertainty of the data from the SP-1000 system, since similar
problems were encountered in both systems and fewer Tenax GC calibration
injections were attempted.
Aromatic Reactant and Product Analysis Using the 5' C-600 System.
Towards the end of this program, toluene and benzaldehyde or m-xylene and
m-tolualdehyde were monitored using a 5' x 1/8" stainless steel column
packed with 5% Carbowax 600 on C-22 firebrick (100/115 mesh). The N2
flow was 50.5 ml/min and flame ionization detection was used. Sampling was
done as for the 10' 10% C-600 or the 3-Part system, except that the traps
in which the sample was concentrated were heated with boiling water instead
of an ice bath, and the GC injection valves were heated to 95-100 C.
26
-------
Calibration was done by sampling from the evacuable chamber dosed with
known amounts of the compound of interest, as described for the SP-1000
system.
The reliability of the aromatic hydrocarbon analysis on the 5' 5%
C-600 system is probably comparable to that of the 10' 10% C-600 system
except that there is a larger body of calibration data for the latter.
Compared to the 3' C-600 or the SP-1000 systems, the reliabilities of the
benzaldehyde and tolualdehyde analyses on the 5" 5% C-600 system are
excellent. Since there are no significant interferences or other difficul-
ties in the analysis, the overall uncertainty for benzaldehyde or tolu-
aldehyde data obtained from this system is primarily determined by the
calibration uncertainties (+5%).
4. CHAMBER AND LIGHT-SOURCE CHARACTERIZATION
The bulk of the chamber and light-source characterization experiments
performed in this program have been described in our previous report
(13). However, during the period covered by this report, additional 03
decay experiments, H202 decay experiments and more complete char-
acterizations of the light source were done. These are described below.
A. Ozone Decay Rates
A detailed discussion of ozone light and dark decay rates was given
in our previous report (13) and is only briefly summarized here. Both the
light and dark decay rates were found to be highly sensitive to chamber
history or pretreatment. After normal experimental conditions, ozone decay
rates of 0.0016 min""^ and 0.0027 min~* for dark and irradiated conditions,
respectively, were typical. These experiments were carried out by adding
ozone (prepared using a Welsback ozone generator) to the chamber which had
been filled with purified air at 85 F and 50% RH. In more recent experi-
ments (July 6-7, 1976), dark and light decay rates of 0.0007 min-1 and
0.0020 min~l were measured. In order to determine whether the presence of
the reaction mixture in HC/NOX systems affects the 03 dark decay rate, the
03 dark decay was monitored following a run (EC-165) in which the 03
maximum was reached, and which was allowed to stand overnight. The observed
decay rate was 0.0010 min~l, which is within the variability observed for
27
-------
the other dark decay experiments.
B. EbO? Decay Rates
Experiments were also done to determine 1^02 light and dark decay
rates. H£02 was injected into the chamber by bubbling 02 through a
98% H202 solution held at a constant and monitored temperature (21-23 C)
in a water bath. The amount of H202 injected was calculated from vapor
pressure of 1^02 at the temperature of the water bath and the volume of D£
passed through the H202 solution (flow rate = 255 ml/min). The relative
decay rates were then monitored by I. R. Two dark decay experiments were
done. In the first (April 18, 1975; intial H202 =7.1 ppm; 4 hour run),
the decay rate was 0.0014 + 0.0001 min'1, in the second (May 13, 1975;
initial ^2 = 2.8 ppm, 2.6 hour run), the rate was 0.0016 + 0.0001 min"1.
Although agreement between these runs was good, they were both done within
a one-month period, and it is unknown to what extent the H202 dark decay
rate varies with time or with the condition of the chamber.
Three light decay experiments were done, all with solar simulator
power equal to 18 KW and an assigned k^ (N02 photolysis rate) of 0.15
min"1. For the first (May 5, 1975; initial 1^02 =4.7 ppm; 3.27 hour run)
the rate was 0.0057 + 0.0001 min'1; in the second (May 13, 1975; initial
H202 = 2.1 ppm, 1.88 hour run), the rate was 0.0035 + 0.0003 min"1; and in
the third (May 13, 1975; initial H202 =1.3 ppm; 1.58 hour run) the rate
was 0.0039 + 0.003 min"1. The third light decay run was done with an extra
3/16" pyrex plate filtering the solar simulator output (in addition to the
usual 1/4" plate; see Section II-A-2), but this appears to have a minor,
if any, effect on the 1^02 light decay rate.
C. Light Intensity
A number of N02 actinometry experiments have been conducted throughout
this program; their results are summarized in Table 3. In general, repli-
cate runs gave a k^ in agreement to within +0.02 min"1. Although 02 can
be effectively removed from the chamber by evacuation (to concentrations
less than 10 ppm), as many as 50 ppm of 02 could have been present in the
nitrogen employed in the kj experiments. Since our calculations of kj were
carried out assuming 02 was absent, 02 present in concentrations greater
than -10 ppm would lead to lower values for kj than would have been observed
28
-------
Table 3. Actlnometry Experiments in the Evacuable Chamber
ho
Date
1975
May 14
Jul 16
22
28
Sep 25
Oct 17
' 19
Hov 21
1976
Feb 25
25
Mar 8
8
9
9
15
19
EC Run
No.
75
88
89
90
93
109
111
112
119
120
126
127
128
129
132
136
Concent rat ions
(NO)
0.022
0.08
0.03
0.06
0.06
0.03
0.15
0.03
0.12
0.03
0.08
0.05
0.03
0.03
0.03
0.03
(NVo
3.01
2.51
. 1.78
1.93
2.93
1.87
1.17
2.00
2.12
1.64
2.07
1.73
1.76
1.59
1.65
1.55
(ppm)
(N02)f
2.08
1.50
1.03
1.07
1.86
1.10
0.75
1.14
1.42
0.68
1.00
0.79
0.79
0.60
0.67
0.57
(min"1)
0.12
0.15
0.17
0.18
0.39e
0.30e
0.35e
0.35e
0.37e
0,26e
0.30
0.25
0.27
0.27
0.34
0.31
0.35
Radiometer
(raw/cm )
__
0.14
0.136
0.16
(0.38)f
0.308
0.34
0.332
0.33
0.32
0.299
0.401
0.392
0.408
0.435
0.506
0.505
0.515
SS Power
(KW)
17.7
19.7
21.3
21.3
12.6
12.0
12.7
13.3
13.0
11.6
13.1
12.9
13.45
15.5
15.5
15.4
15.85
Notes0
Calc for power used in
EC-77
Recoated secondary & flat
Install new lamp (Hanovia) ,
spare collector
Radiometer switch
position 3
Switch position 2
New lamp (Durotest)
Lamp adjusted
Lamp adjusted to
position of EC-119
Lamp adjusted to
position of EC-120
(continued)
-------
Table 3 (continued) - 2
Date
Mar 30
Apr 16
27
May 6
26
Jun 8
u>
0 22
Jul 13
30
Aug 4
26
1977
Feb 11
Jun 23
24
24
Aug 5
Oct 26
Nov 8
EC Run
No.
140
148
154
159
167
170
173
175
184
187
189
215
223
224
225
229
235
244
Concentrations
(NO)Q
0.04
0.02
0.05
0.03
0.065
0.01
0.044
0.049
0.122
0.049
0.039
0.029
0.083
0.58
0.029
0.083
0.0439
0.0537
(N02)o
1.56
1.29
1.31
1.57
1.35
2.05
1.69
2.13
1.36
2.150
1.45
1.32
1.65
1.71
1.82
1.70
1.77
1.67
(ppm)
(N02)f
0.53
0.475
0.42
0.58
0.490
0.646
0.927
0.83
0.454
0.714
0.489
0.39
0.507
0.781
0.644
0.654
0.761
0.668
(min"1)
0.38h
0.35
0.40h
0.35
0.355
0.41
0.36
0.20
0.33
0.38
0.391
0.388
0.382
0.435
0.422
0.2661
0.362
0.332
0.289
0.316
Radiometer
(raw/cm )
0.488
0.511
0.485
0.503
0.518
0.524
0.48
0.274
0.352
0.36
0.359
0.359
0.344
0.356
0.327
0.240
0.293
0.225
0.220
0.233
SS Power
(KW)
15.6
16.6
17.4
18.1
19.8
21.2
19.9
11.5
12.7
13.7
16.0
16.6
13.9
17.1
18.2
15.0
17.2
17.95
17.8
19.6
Notes0
•
Calc for power used in
EC-169
New lamp (Durotest)
New Pyrex filter
Calc for powerd used in
EC-176
Recoated flat & secondary
Trichroic filter removed
(continued)
-------
Table 3 (continued) - 3
Date
Dec 28
1978
Jan 18
Mar 15
28
Apr 24
Jul 10
24
Oct 9
20
20k
31
31k
31k
Nov 9
9k
27
27k
Dec 11
EC Run
No.
261
262
267
274
283
295
303
313
322
323
324
325
326
332
333
341
342
347
Concentrations
(N0)o
0.0732
0.144
0.029
0.0488
0.0976
0.0537
0.097
0.0439
0.073
0.034
0.0488
0.0292
0.062
0.039
0.0292
0.0488
0.0497
0.0537
(N02)Q
1.58
1.62
1.72
1.85
2.16
1.75
2.31
1.78
1.85
1.83
1.39
1.46
1.45
1.64
1.52
1.50
1.49
1.49
(pptn)3
(W2)f
0.483
0.584
0.700
0.639
0.708
0.532
0.695
0.483
0.407
0.717
0.454
0.576
0.353
0.532
0.522
0.498
0.497
0.495
b
kl
(win"1)
0.424
0.360
0.3091>:i
0.373
0.395
0.425
0.430
0.472
0.568
0.323
0.396
0.321
0.522
0.398
0.375
0.389
0.387
0.389
Radiometer
(raw/ cm )
0.313
0.262
0.252
0.262
0.264
0.256
0.259
0.256
0.263
0.145
0.180
0.145
0.270
0.176
0.183
0.167
0.163
0.162
SS Power Notes
(KW)
13.45
12.0
11.8
12.1
12.82
14.3
14.9
16.12
18.98
12.2
14.9 Hew lamp (Durotest)
12.76
18.16
14.9
15.1
15.2
15.1
15.1
"Monitored with TECO Model 14B.
Two mln Irradiation period unless noted otherwise. All k, values calculated using the unmodified formula of
Unlntnf? at- «1 {1 ~J \ •*-
Holmes et al. (17).
(continued)
-------
Table 3 (continued) - 4
Given conditions hold for subsequent runs until explicitly noted otherwise.
Assume k. ~ (power) .
1 min. irradiation.
Reading at 12.2 KW after completion of experiment; radiometer did not reach steady value during k. determination.
8Filter (330 ± 40 nm) installed with radiometer for this and all subsequent readings.
Anomalously high value. Believed to be due to insufficient warm-up time, and not used in assigning k. values for
experimental runs.
Anomalously low value. May be due to QI in chamber. Not used in assigning k. values for experimental runs.
N« in chamber overnight.
Immediately preceded by another actinometry experiment. Chamber was not completely pumped down.
-------
in the complete absence of 02 (17). For example, 50 ppm of 02 would result
in a value of k^ ~10% low with respect to the true N02 photolysis rate
(JJ.). An oxygen-contaminated N2 cylinder or a leak while filling the
chamber would probably accounts for the occasional, unexpectedly low k^'s
which were observed.
Wu and Niki (25) have pointed out that use of the equation of Holmes
et al. (17) is not strictly applicable unless [NO]/[N02] > 0.5, due to the
fact that N205 has not reached a steady state concentration. An experiment
(Run EC-112) was accomplished by running a series of consecutive 1 minute
photolyses starting with 2.0 ppm N02. The results are given in Table 4,
along with calculated values of k^ using the unmodified Holmes equation,
and using the Holmes equation modified to be consistent with the recom-
mended rate constants given by Hampson and Garvin (2). These data show
that reasonably consistent values of kj were obtained for the 0-1 min
irradiaton when [NO]/[N02] <^ 0.5. It can also be seen that the values
of kj calculated from the experimental data depended on the rate con-
stants used in the calculations, with the discrepancy generally increasing
as [NO] increases. The k^ values given on Table 3 were all calculated
using the unmodified equation of Holmes et al. (17), and may be 5-10% low
if the rate constants of Hampson and Garvin (2) are more appropriate.
The k^ values assigned for the individual experimental runs were
based on the observed correlations between the results of the actinometry
experiments listed in Table 3 and the average radiometer reading or
average solar simulator power. For the runs prior to EC-274, the radiome-
ter readings were found to correlate reasonably well with measured kj
values, at least for a given solar simulator lamp and condition of the
optical system; this is what was primarily used to assign the k^ values
during that period. Because of this correlation, the practice had been to
adjust the solar simulator power to maintain constant radiometer readings
in order to assure constant kj values for a given set of runs. However,
after Run EC-274, the sensitivity of the radiometer apparently began to
deteriorate, since it was observed that the k^ steadily increased with time
in runs during which the radiometer readings were held constant (see Runs
EC-275 through EC-323 on Table 3). During that period, a good corre-
lation was observed between measured kj values and average solar simulator
33
-------
Table 4. Experimental Data and Calculated Results for the NO Photolysis
Rate Constant (k,) Determined in Fi/e Consecutive One-Minute
Photolyses
Calculated k (min )
Time
(min)
0
1
2
3
4
5
NO
(ppm)
0.03
0.85
1.27
1.50
1.62
1.69
N02
(ppm)
2.00
1.14
0.70
0.45
0.33
0.25
Unmodified3*0
0.374
0.359
0.370
0.298
0.3D5
Modified1*'0
0.385
0.395
0.438
0.375
0.404
Calculated using the equation given by Holmes et al. (A), based on the
values of k . k. and k given below.c
a D c
Calculated using the equation of Holmes et al. (17), modified to be
consistent with the k , k and k values recommended by Hampson and
Garvin (2) for 85 F.c& °
Rate constants used are as shown:
Reaction
k(cm molecule sec units)
Holmes et al. (17) Garvin & Hampson (2)
(a) 0 + N0£ ->NO +
(b) 0
9.35 x 10
~12
1.24 x 10
~31
9.1 x 10
~12
1.0 x 10
~31
(c) 0 + NO + N2 -* N02 +
6.44 x 10
~32
1.07 x 10
~31
34
-------
power, so the latter quantities were used to assign the k^ values for the
experimental runs. Following Run EC-324, the kj values for the experi-
mental runs were held constant by holding the solar simulator power con-
stant.
D. Spectral Distribution
The spectral distribution of the solar simulator output after passage
through the chamber was obtained with one of two systems: (a) a McPherson
0.3 m monochromator (with a grating blazed at 200 nm) and a Hamamatsu R106
photomultiplier (through Run EC-156) or (b) a SPEX spectrometer (Model
1667) with a 1P28 photomultiplier (beginning with Run EC-156). The
differences in spectra upon changing from the McPherson to the SPEX system
were within that observed between spectra from one day to the next using
the same system. The response of these systems as a function of wavelength
was determined using an NBS standard lamp and the solar simulator spectral
data have been corrected for this response, thus providing data which is
proportional to photo flux.
The spectra were originally recorded on a strip chart and the values
read from the chart. Beginning with Run EC-177, the intensity was moni-
tored with a digital voltmeter with manual setting of each desired wave-
length. This removed some of the imprecision associated with reading
values from the chart, particularly at short wavelengths, where the inten-
sity rapidly changed.
Spectral distributions measured for the individual experiments are
given on the data sheets. Variation of hourly spectra taken during
a single run was found to be less than 5%. The intensities were normalized
to a value of 1.0 at 350 nm. This wavelength was chosen because the
maximum intensity seen by the radiometer (equipped with a 330 +_ 40 nm
filter) was calculated to be 350 nm. The spectral distributions within a
given series of runs done around the same time and employing similar
photolysis conditions were fairly constant. However, as the solar simu-
lator lamps were changed or the optics upgraded or otherwise modified, the
spectral distributions were observed to change significantly. Therefore,
no single spectral distribution can be considered to be representative of
all the experiments reported here.
35
-------
5. PHOTOOXIDATION OF HYDROCARBON-NOX SYSTEMS
A. Experimental Runs Performed
The reactivity and product formation resulting from irradiations
of single, dual and multi-hydrocarbon mixtures in N0x-air systems have
been studied in this program. In most cases, experiments were done at a
variety of initial hydrocarbon and NOX levels, using factorial design
blocks as a basis for systematically selecting the most efficient and
relevant set of concentrations of reactants, given that only a limited
number of runs could be done for each system (13). In addition to study-
ing the effects of initial reactant concentrations, the effect of varying
temperature was studied for the propene-NOx and n-butane-NOx systems.
The effects of initially-present aldehydes were studied for the propene-
NOx, n-butane-NOx and toluene-NOx systems, and the effect of initially-
present PAN was studied for the propene-NOx system. In a number of cases,
duplicate runs were done to determine the reproducibility of four experi-
mental systems. In particular, seven standard propene runs (initial
propene s initial NOX a 0.5 ppm) were done at scattered intervals through-
out the program. In all, 114 photochemical runs were done in this program
throughout the -four year period covered by this report.
Single Hydrocarbon Runs. The reactivities of 10 individual hydro-
carbons or aldehydes in N0x-air irradiations were studied, in most cases at
a variety of initial reactant concentrations. The individual hydrocarbons
studied (ordered by the number of runs performed) are (1) ethene (6 runs),
(2) propene (19 runs), (3) 1-butene (3 runs), (4) trans-2-butene (3 runs),
(5) n-butane (10 runs), (6) 2,3-dimethyl butane (3 runs), (7) toluene (24
runs), (8) m-xylene (4 runs), (9) formaldehyde (4 runs) and (10) acetal-
dehyde (3 runs). The initial concentrations and special experimental
conditions for the single hydrocarbon-NOx runs are given in Table 5. The
runs are given in the table in order of increasing hydrocarbon and NOX
levels; the run numbers give an indication of the time period in which the
run was done.
Dual Hydrocarbon Runs. The reactivities of eleven dual hydrocar-
bon mixtures were also studied, also at a variety of initial reactant con-
centrations. The systems studied were: (1) propene + n-butane (7 runs),
36
-------
Table 5.
Initial Concentrations. Light Intensities and Selected Reactivity Parameters for Single Component Hydrocarbon-NO Runs
A
00
Initial Concentration
Run
Ho.
142 Ethene
143
156
285
287
286
217 Propene
256
257
277
95
96
121
177
216
230
276
317
318
319
320
278
279
314
315
316
122 1-Butene
123
124
HC
0.949
2.027
1.995
1.949
3.995
3.758
0.099
0.109
0.112
0.564
0.504
0.500
0.483
0.493
0.503
0.546
0.540
0.493
0.509
0.502
0.536
1.016
1.144
1.062
0.967
1.070
0.217
0.404
0.424
NO
0.322
0.390
0.376
' 0.791
0.404
0.708
0.241
0.520
0.530
0.098
0.365
0.349
0.410
0.364
0.412
0.392
0.410
0.256
0.172
0.100
0.222
0.366
0.730
0.684
0.664
0.735
0.398
0.401
0.608
(ppm)
NO,
0.158
0.110
0.124
0.215
0.124
0.237
0.238
0.044
0.032
0.010
0.092
0.090
0.101
0.099
0.104
0.128
0.106
0.281
0.331
0.430
0.338
0.128
0.244
0.246
0.276
0.246
0.103
0.106
0.385
NO
0.480
0.500
0.501
1.006
0.528
0.947
0.478
0.564
0.559
0.108
0.456
0.438
0.510
0.463
0.518
0.520
0.517
0.530
0.500
0.530
0.560
0.498
0.977
0.918
0.942
0.982
0.500
0.505
0.996
kl
(rain"1)
0.33
0.33
0.32
0.39
0.39
0.39
0.43
0.30
0.30
0.35
0.35
0.35
0.30
0.33
0.43
0.30
0.35
0.53
0.53
0.55
0.55
0.35
0.35
0.48
0.49
0.51
0.29
0.28
0.27
6 Hr
°3
Special Conditions (ppm)
.782
.848
.796
.840
.552
.682
Acetaldehyde - 0.146 ppm .059
Formaldehyde - 0.042 ppma .002
Formaldehyde - 0.371 ppm8 .066
.296
.403
.412
.501
.523
.523
.298
.374
.606
PAN • 0.072 ppm .684
PAN - 0.149 ppm .747
PAN - 0.036 ppm .633
.559
.677
.728
T - 61.4 F .344
T - 102 F .953
.181
.469
.083
03 Max
(min) (ppm)
> 360
210
195
> 360
135
180
> 675
> 360
> 360
135
270
300
315
435
465
>420
> 360
>390
285-300
255
330
195
>360
>360
>360
>360
> 420
>450
>630
1.087
1.055
_
.965
1.080
_
-
-
.313
.432
.422
.506
.540
.564
-
_
-
.689
.755
.642
.625
:
-
-
_
_
_
N02 Max
(min) (ppm)
105 .303
60 .375
45 .365
165 .711
45 .449
60 .756
180 .272
> 360
195 .303
30 .085
45 .321
60 .302
45 .341
90 .314
105 .367
120 .364
135 .366
45 .392
45 .419
30 .460
45 .405
60 .385
105 .705 1
90 .666 )
135 .614
60 .724
180 .281
75 .323
210 .535
Notes
Duplicate
Standard
Propene
Runs
Duplicate
-------
Table 5 (continued) - 2
oo
Initial Concentration (ppm)
No.
146
157
147
178
162
163
168
305
304
308
309
307
306
171
169
165
78
77
273
269
327
340
270
339
272
79
271
80
84
HC
Trans-2- 0.231
0.216
butene 0 417
n- Butane 1.961
2.050
1.978
1.961
4.30
4.28
4.05
4.31
6.44
6.44
2,3 Dimethyl- 0.586
0.740
DU££1T1G i fine
Toluene 0.228
0.276
0.587
0.566
0.572
0.537
0.576
0.576
0.580
0.976
1.146
1.02
0.968
NO
0.385
0.397
0.782
0.087
0.383
0.377
0.326
0.078
0.349
0.305
0.203
0.083
0.147
0.066
0.126
0.088
0.069
0.518
0.096
0.398
0.351
0.333
0.414
0.341
0.398
0.080
0.186
0.401
0.388
HO,
0.124
0.129
0.200
0.011
0.122
0.113
0.166
0.021
0.117
0.178
0.272
0.019
0.040
0.013
0.064
0.011
0.032
0.059
0.014
0.074
0.096
0.096
0.051
0.102
0.080
0.020
0.028
0.095
0.081
HO
0.510
0.525
0.982
0.099
0.506
0.490
0.493
0.099
0.466
0.483
0.475
0.102
0.187
0.099
0.191
0.100
0.101
0.574
0.110
0.472
0.445
0.430
0.465
0.445
0.478
0.100
0.215
0.498
0.469
T.
(min"1) Special Conditions
0.33
0.34
0.34
0.33
0.35
0.34 Acetaldehyde " 0.526 ppm
Formaldehyde - 1.101 ppm
0.43
0.43
0.44 T • 59.1 F
0.45 t - 101.1 P
0.43
0.43
0.33
0.33
0.33
0.14
0.14
0.37
0.35
0.40
0.39
0.35 Formaldehyde • 0.178
0.39 Benzaldehyde - 0.187
0.35 Acetaldehyde « 0.361
0.14
0.37
0.14
0.14
6 Hr
°3
(ppm)
.239
.205
.154
.366
.112
.430
.327
.398
.269
.044
.545
.420
.520
.330
.237
.457
.086
.012
.188
.298
.376
.346
.362
.225
.410
.080
.217
.234
.233
03 Max
(min) (ppm)
> 360
> 360
> 360
> 495
> 360
> 360
>67S
> 360
>435
> 360
> 360
> 390
> 405
>630
> 720
510-570
195
>360
75-90
> 360
>360
>360
330
> 360
>360
105-120
90
255
>360
-
-
_
-
-
-
-
-
-
-
-
-
-
-
.489
.092
-
.215
-
—
.369
-
-
.096
.296
.272
N02 Max
(min) (ppm)
60
60
90
75
270
105
105
45
180
345
90
45-60
90-105
90
150
90
45
330
30
150
135
105
90
195
90-105
30
30
105
135-150
.297 )
.305 /
.556
.066
.276
.299
.302
.076
.324
.275
.363
.078
.146
.055
.124
.069
.066
.236
.064
.260
.259 \
.250 /
.274
.235
.296
.063
.142
.312 \
.273 J
Notes
Duplicate
Duplicate
Duplicate
-------
Table 5 (continued) - 3
OJ
vo
Initial Concentration
Run
No.
HC
NO
(ppm)
NO.,
NO,
kl
(min ) Special Conditions
6 Hr
°3
(ppm)
03 Max
(min) (ppm)
N02 Max
(min) (ppm)
Notes
Toluene (continued)
264
265
266
86
337
335
336
81
85
82
83
343 M-xylene
345
346
344
164 Acetaldehyde
253
254
251 Formaldehyde
250
255
252
1.156
1.070
1.196
1.090
0.971
1.005
0.993
1.96
1.920
1.88
5.63
0.491
0.480
0.478
0.486
0.340
0.546
0.472
0.193
0.328
0.330
0.359
0.420
0.435
0.432
0.407
0.322
0.352
0.342
0.408
0.431
0.679
1.334
0.214
0.220
0.204
0.520
0.388
0.011
0.085
0.080
0.011
0.006
0.392
0.056
0.048
0.059
0.080
0.124
0.092
0.097
0.094
0.093
0.377
0.674
0.066
0.059
0.059
0.154
0.118
0.009
0.037
0.033
0.012
0.010
0.103
0.470
0.482
0.494
0.485
0.448
0.443
0.439
0.502
0.523
1.016
2.003
0.279
0.278
0.261
0.671
0.506
0.020
0.112
0.113
0.023
0.016
0.493
0.35
0.35
0.35
0.14 Formaldehyde » 0.161
0.39 Benzaldehyde - 0.172
0.39 Acetaldehyde - 0.326
0.39 Formaldehyde - 0.301
0.14
0.14
0.14
0.14
0.38
0.39
0.39
0.39
0.33
0.30 a
0.30 a
0.30 a
0.30 a, no NO injected
0.30 a, no NO injected
0.30 a
-
.332
.285
.269
.344
.264
.231
.258
.365
.418
.093
.318
(.342)b
.503
.085
.134
.264
.271
.213
..203
.024
210
210
210-225
330
255
225
165
180
240
> 360
> 360
75
75
55-60
180
> 360
> 360
> 360
> 360
> 360
> 360
> 360
.419
.393
.403
.299
.325
.396
.393
.313
.293
_
-
.283
.396
.384
.586
_
-
-
_
-
—
90
90
90
120
105
75
60
270
120
180
270
30
25
35
45
210
0
60
30
> 360
> 360
165
.285 1
.295 f
.295
.336
.264
.274
.271
.342
.348
.607
1.370
.189 J
.192 }
.118 1
.454
.259
.009
.068
.077
: }
.232
Duplicate
Duplicate
Duplicate
Small amounts of n-butane and neopentane were added to allow calculation of hydroxyl radical concentrations from their relative rates of appearance.
-------
(2) propene + ethene (3 runs), (3) propene 4- trans-2-butene (1 run), (4)
n-butane + 2,3-dimethylbutane (2 runs), (5) toluene + propene (3 runs) and
(6) toluene 4- n-butane (3 runs). lr»c initial concentrations used in
the dual hydrocarbon-NOx runs are given in Table 6.
Multi-Hydrocarbon Runs* Runs were done employing two multi-
hydrocarbon systems: (1) four olefin mixtures containing ethene, propene,
1-butene and trans-2-butene (5 runs) and (2) seven hydrocarbon mixtures
containing ethene, propene, trans-2-butene, n-butane, 2,3-dimethylbutane,
toluene and m-xylene as representative alkanes, olefins and aromatics
(11 runs). Both systems were irradiated at several hydrocarbon and NOX
levels and with varied relative composition of the hydrocarbon mixtures.
The initial concentrations used in these multi-hydrocarbon runs are given
in Tables 7 and 8.
B. Results
Detailed data sheets for each of the photochemical runs performed
in this program during the period covered by this report are given in
the Appendix. The data sheets are presented in chronological order (i.e.,
in order of increasing run numbers). To allow for easier comparison
of overall reactivity results within each experimental system, Tables 5
through 8 give selected reactivity parameters observed for each experiment.
In addition to giving the results of all relevant experimental
measurements made during each run, the data sheets give the following
information: (1) the initial concentrations of reactants and observed
background species, (2) the averages of measurements of physical parameters
such as temperature, relative humidity, etc., (3) relevant calibration
data, (4) the assigned kj values, (5) the calculated total rate of gas
withdrawal from the chamber due to sample withdrawal (see Section II-B-5),
allowing for calculation of the dilution rate for each run (chamber volume
= 5774 £), (6) the calculated total PAN + organic nitrate concentrations
("TOT N03") used to obtain the corrected N02 and NOX data from the
raw values (21) (the latter being listed on the last page of each data
sheet as "N02" and "NOX"), (7) the calculated total nitrogen ("TOT N") and
carbon levels ("HCTOT") and (8) the water concentrations calculated from
the RH and the temperature data. In addition, the data sheets for each run
40
-------
Table 6.
Initial Concentrations, Light Intensities and Selected Reactivity Parameters for Dual Component Hydrocarbon-NO^ Runs
Initial Concentrations (ppm)
Run
No.
113 Propene
99
106
97
115
116
114
145 Propene
160
144
149 Propene
172 n-Butane
166
330 Toluene
329
334
328 . Toluene
338
331
HC1
0.410
0.400
0.402
0.500
0.310
0.824
0.766
0.428
0.400
0.221
0.384
0.339
1.816
0.567
0.555
0.993
0.569
0.969
1.991
HC2
n-Butane 2.04
2.00
2.00
2.04
2.94
4.00
3.66
Ethene 1.049
1.400
2.027
t-2-Butene 0.209
2.3 DMB 0.237
0.319
Propene 0.0942
0.0985
0.0954
n-Butane 2.038
2.026
2.043
NO
0.091
0.407
0.401
0.397
0.402
0.391
0.794
0.745
0.752
0.398
0.813
0.079
0.088
0.202
0.352
0.348
0.349
0.346
0.351
N02
0.020
0.090
0.102
0.088
0.104
0.104
0.204
0.246
0.241
0.111
0.176
0.017
0.012
0.090
0.102
0.100
0.100
0.100
0.112
N0x
0.111
0.497
0.500
0.500
0.506
0.493
0.996
0.994
0.994
0.509
0.989
0.097
0.100
0.290
0.455
0.448
0.449
0.447
0.464
kl
Cmin"1)
0.35
0.35
0.35
0.35
0.35
0.35
0.35
0.34
0.35
0.33
0.33
0.34
0.33
0.40
0.40
0.39.
0.40
0.39
0.40
6 Hr
°3
(ppm)
.297
.539
.590
.524
.582
.619
.733
.777
.874
.767
.276
.259
,452
.278
.384
.315
.523
.410
.352
°3
(min)
105-150
300
390-405
240
420
165-180
330
>360
>360
165-180
>360
>690
>480
180
300-315
180
360
240
120
Max
(ppm)
.348
,557
.592
.578
.590
.741
.745
_
-
1.060
_
_
-
.344
.403
.408
_
.484
.523
N02~corr.
(min)
30
60
105
60
105
60
90
120
105
45
75
135
45-75
60
90-105
60
105
75
45
max
ppm Notes
.080
'.HI } Duplicate
.355
.362
.382
.701
.635
.631
.377
.585
.054
.064
.193
.279
.289
.298
.301
.334
-------
Table 7. Initial Concentrations, Light Intensities and Selected Reactivity Paramters for Mixed Olefin-NO Runs
Run
No.
161
152
150
151
153
Propene
0.102
0.116
0.224
0.441
0.109
Initial Concentrations (ppm)
t-2-
Ethene 1-Butene Butene NO N0?
0.908
1.015
1.014
0.975
1.923
0.189
0.222
0.097
0.209
0.415
0.088
0.102
0.093
0.190
0.193
0.386
0.398
0.774
1.466
0.774
0.123
0.104
0.222
0.590
0.197
NO
X
0.510
0.504
0.998
2.056
0.969
kl
(min"1)
0.34
0.35
0.33
0.35
0.34
6 Hr< 03 Max N02
O.(ppm) (min) (ppm) (min)
210-225
.689 210-225
.799 >360
.147 >360
.801 180
.857 45
.787 45
105 •
150
1.050 45
Max
(ppm)
.369
.362
.630
1.124
.706
-P-
to
-------
Table 8. Initial Concentrations, Light Intensity and Selected Reactivity Parameters for Seven Hydrocarbon Mixture-NO Runs
Run
No.
241
246
247
233
237
238
232
231
243
U> 242
245
Ethene
0.484
0.253
1.025
0.260
0.875
0.982
0.258
1.051
1.939
2.014
2.055
Fropene
0.045
0.049
0.054
0.051
0.100
0.093
0.051
0.108
0.109
0.109
0.104
t-2-
Butene
0.024
0.026
0.053
0.025
0.050
0.047
0.026
0.055
0.110
0.108
0.102
n-Butane
0.464
1.058
0.273
1.085
1.025
0.966
1.102
1.130
0.568
0.558
0.534
2.3DMB
0.211
0.538
0.080
0.648
0.463
0.420
0.612
0.715
0.084
0.203
0.185
Toluene
0.040
0.023
0.145
0.034
0.086
0.083
0.032
0.121
0.155
0.306
0.321
m-xylene
0.044
0.023
0.145
0.033
0.091
0.084
0.029
0.108
0.154
0.306
0.317
NO
0.379
0.386
0.380
0.096
0.377
0,718
0.469
0.440
0.386
0.377
0.743
NO,
0.110
0.122
0.125
0,007
0.106
0.234
0.024
0.052
0.115
0.125
0.259
»°x
0.489
0.506
0.505
0.103
0.483
0,952
0.492
0.492
0.502
0.503
0'.992
(rain"1;
0.30
0,30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
6 Hr Oj
.408
,374
-
.322
.584
.606
.305
.540
-
.418
.635
°3
(min)
>360
>570
210-225
240-285
240
435
>360
240
135
105
180
Max
-------
include comments which describe ny special j-roblems, conditions or pro-
cedures associated with that experiment, and in some cases, give miscel-
laneous observations made during the run. Before the results of any run
are used for model validation, its associated comments should be examined.
C. Limitations of the Data Set
Although these experiments were performed using the highest reasonable
level of characterization and quality control practical at the time,
it is important to stress that the data must be examined critically before
being used for model validation. A discussion of the problems and uncer-
tainties associated with most of the different types of measurements made
during these runs have been given in Section 1. In some cases (formal-
dehyde and benzaldehyde, in particular), the quality of the data improved
significantly during the latter part of the program. In addition, experi-
mental conditions or procedures were changed from time to time throughout
the program, which may affect the quality and reproducibility of the data.
Significant changes in procedures were discussed in Section 1.
An indication of the reproducibility of experiments done at separate
times throughout the program can be obtained by examining the results
of the standard propene runs listed in Table 5. It can be seen that the
reproducibility is poor for runs separated by large time intervals. The
most obvious explanation for this is the differences in light intensity
(see the kj values given in Table 5), though chamber conditioning or the
modification of the pumping system made around the time of Run EC-121 may
also have contributed. Poor reproducibility was also observed in the earliest
set of toluene-NOx experiments (compare Runs EC-80 and 81 and EC-84 and 85,
respectively). This can be attributed to a temporary lack of temperature
control throughout that period (see comments on data sheets). On the other
hand, in the most recent toluene-NOx runs, much better reproducibility was
obtained.
Perhaps the most serious limitation of these data concerns the problem
of chamber wall effects. "Memory" or "dirty wall" effects appear to
be inherent in irradiation vessels employed in HC-NOX photooxidation
studies (36^-38) • Indeed, in our chamber runs there are a number of cases
where it is difficult to attribute non-reproducibility to changes in light
intensity alone (see Tables 5-8 and our previous report [_T3]). In addition,
44
-------
in all cases when our data has been modeled (.6».Z,.9-.12.), it has been
necessary to provide for some type of radical input from unknown sources in
order to fit the initial rates of hydrocarbon decay and NO conversion.
This is frequently attributed to nitrous acid (HONO) being initially
present (formed during the injection of NOX), which rapidly photolyzes to
form hydroxyl radicals; but results of recent experiments done in our
laboratories (39)» in which NOX was injected under conditions designed to
minimize HONO formation, indicate that this is not the case. Experiments
we have done employing clean Teflon bags indicate that the reactivity
increases significantly after the bag accumulates a history of hydrocarbon-
NOX irradiations (40). The nature and causes of this effect in our evacu-
able chamber have not yet been adequately characterized.
45
-------
6. KINETICS AND MECHANISM OF THE GAS PHASE REACTION
OF OH RADICALS WITH METHOXYBENZENE AND o-CRESOL
OVER THE TEMPER/TDkJ; RANGE 299-435 K
A. Introduction
Phenolic compounds are formed from the gas phase reaction of 0(-*P)
atoms of OH radicals with aromatic hydrocarbons (41.-46.), and are products
from the reaction of OH radicals with aromatic hydrocarbons under polluted
atmospheric conditions (47). The gas phase reactions of the hydroxyl
radical with these phenolic compounds are hence of great importance for
kinetic chemical modeling of photochemical air pollution.
B. Experimental
OH radicals were produced by the pulsed vacuum ultraviolet photolysis
of H20 at wavelengths longer than the LiF cutoff (21050A1). OH radical
concentrations were monitored as a function of time after the flash by
resonance fluorescence using a cooled EMI 9659QA photomultiplier fitted
with an interference filter transmitting the 3064 A band of OH (A2 +,Ev" =
0 ->x2n,v" = 0). The intersection of the detection system aperture and
the resonance radiation beam defined a fluorescence viewing zone at the
center of the reaction vessel whose cross-section was ~2 cm in diameter.
This region was well separated from the reaction vessel walls, thus mini-
mizing wall losses of the OH radicals. The reaction cell was enclosed in a
furnace which could be held constant to better than +1 K over the tempera-
ture range 295-475 K, and the gas temperature was measured by a Chromel/
Alumel thermocouple mounted inside the reaction vessel.
The flash lamp was typically operated at discharge energies of 25-50
joules per flash at repetition rates of one flash every three seconds.
Signals were obtained by photon counting in conjunction with multichannel
scaling. OH radical decay curves were accumulated from 30-1050 flashes,
depending on the signal strengths. OH half-lives ranged from 1.83-113
msec, and the OH radical concentrations were followed over at least three
half-lives. In all cases the flash duration (2.1 ysec) was negligible in
comparison to the OH radical half-lives encountered.
In order to avoid the accumulation of photolysis or reaction products,
all experiments were carried out under flow conditions so that the gas
46
-------
mixture in the reaction vessel was replenished every few flashes. The
partial pressure of H20 in the reaction cell was ~0.02 torr. The argon
used had a purity level of 2.99.998%, according to the manufacturer, while
the methoxybenzene and o-cresol had stated purity levels of 2:99%. In
addition, the o-cresol was distilled prior to use and stored under argon.
A known fraction of the total argon flow was saturated with the
aromatic vapor at 273 K (methoxybenzene) or 293 K (o-cresol). Aromatic
partial pressures in this fraction of the total flow were determined by
their ultraviolet absorption using a 9.0 cm pathlength cell and a Gary 15
spectrophotometer. The absorption cell was calibrated using known pressures
of the aroma tics as measured by an MKS Baratron capacitance manometer. All
flows were monitored by calibrated flowmeters, and the gases were premixed
before entering the reaction vessel. Prolonged flowing of the o-cresol and,
to a lesser extent, of methoxybenzene, was necessary in order to obtain
steady-state gas phase concentrations of these aromatics during the deter-
minations of rate data.
C. Results
OH radical decays were obtained for the reaction of OH radicals with
methoxybenzene and o-cresol over the temperature range 299-435 K at a
total pressure of ~100 torr of argon. The experimental observations were
entirely analogous to those recently reported (48) for the aromatic hydro-
carbons. Thus non-exponential OH radical decays were observed over the
temperature region -330-390 K, with the decay rates decreasing with time
after the flash. For the temperature regions 299 K < T < 330 K and 390 K <
T < 435 K the OH decays were exponential, obeying the integrated rate
expression
[OH]tQ/[OH]t - S0/St = exp[(k0 + k[aromatic]) (t-to)] (I)
where [OH]t and [OH]t are the concentrations of OH at times to and t,
respectively, S0 and St are the corresponding resonance fluorescence
intensities, ko is the first-order rate for removal of OH in the absence
of added reactant (primarily attributed to diffusion out of the viewing
zone and to reaction with impurities), and k is the rate constant for
the reaction
OH + aromatic -»• products
47
-------
The rate constants, k, obtained af 400 K were a factor of ~6 lower than
those at 299 K.
As in the previous work (48), rate constants k were determined as
a function of temperature from either (a) the dependence of the OH radical
decay rate on the aromatic concentrations, as shown in Figure 3 for o-
cresol and methoxybenzene at -299 K and ~423 K, or (b) from a single OH
decay rate, R at a known aromatic concentration, using equation (II).
R = (t-to)"1 In S0/St = k0 4- kfaromatic] (II)
This latter method obviously has a somewhat larger degree of uncertain-
ty, partially associated with the estimation of the OH decay rates in the
absence of reactant, R = kQ. However, for OH decay rates X200 sec"*, any
error associated with the estimation of kg (which was typically 10-20
sec"*) was <5%. Values of 1^ were estimated using values obtained by
method (a) for the same aromatic at similar temperatures. The error limits
given in Table 9 and shown in Figure 4 are the estimated overall limits,
which, for method (a), include the least square standard deviations (1-3%)
as well as the estimated accuracy limits of other paramters such as total
pressure and the aromatic concentrations in the reactant mixture. Using
method (a), the experimental decay rates in the range typically used for
method (b), R ^200 sec~l, were within 5% of those calculated from least
squares analysis of the data. Hence this spread is indicative of the
random errors associated with method (b), and is included in the overall
error limits for method (b) (Table 9 and Figure 4). For o-cresol the
overall error limits are estimated to be approximately +20% on account of
greater errors in the ultraviolet absorption calibration. However, the
relative rate constants for o-cresol are estimated to be accurate to
approximately _+5-10%.
Table 9 gives the rate constants obtained at the temperatures used,
and Figure 4 shows the data plotted in Arrhenius form. The solid lines
for T $ 330 K and for T > 390 K were obtained from least squares fitting
of the data in these temperature regions, while the dashed lines between
these temperature regions merely indicate the trend of the data.
D. Discussion
From the initial OH radical concentrations and the aromatic concentra-
tions used, it can be estimated that errors in the measured rate constants
48
-------
VO
500
299.4°K
$400
299.9 °K
oMETHOXYBENZENE
• o-CRESOL
1234
[AROMATIC] molecule cnT3
6x10
13
Figure 3. Plots of the OH Radical Decay Rate Against Concentration for Methoxybenzene at
299.9 and 422.0 K and for o-Cresol at 299.4 and 423.1 K.
Total pressure -100 torr of argon.
-------
Table 9. Rate Constants, k, for the Reaction of OH Radicals with Methoxybenzene and o-Cresol
Methoxybenzene
Temperature K
299.9
309.0
309.7
318.5
321.7
329.5
357.4
370.4
385.5
Oi
0 392.3
404.1
413.2
417.9
422.0
428.7
435.3
12 3 -1 -1
10 x k cm molecule sec
19.6 + 2.4aJ
17.3 ±2. 6b)
17.5 + 2.6b)
17.5 ±2. 6b)
17.8 + 2.7b)
12.7C)
6.7C>
3.0C)
3.33 + 0.50b)
3.25 + 0.50b)
3.31 + 0.50b)
3.90 + 0.56b)
2.85 + 0.43b)
3.30 + 0.40a)
2.76 + 0.41b)
2.72 + 0.41b)
o-Cresol
Temperature K
299.4
310.6
322.0
330.7
335.4
344.4
356.5
385.8
392.8
400.6
407.8
423.1
12 3 -1-1
10 x k cm molecule sec
34.1 + 6.8a)
29.3 + 5.9b)
29.8 ± 6.0b)
26.8 + 5.4b)
25.5 + 5.1b)
18.5°
15.0C)
6.4C)
6.0C)
5.6 ±l.lb)
5.4 ±l.lb)
6.2 +1.2a)
3 OH radical decays were observed to be exponential. The rate constants were obtained from the dependence of the OH
decay rates on aromatic concentration. The indicated error limits are the estimated overall error limits which in-
clude the least square standard deviations, as well as the estimated accuracy limits of other parameters such as
aromatic concentrations in the reactant mixture.
OH radical decays were observed to be exponential. The rate constants were obtained from the OH decay rate at a
single aromatic concentration. The indicated error limits are the estimated overall error limits.
OH radical decays were observed to be nonexponential. Rate constants were obtained from the initial OH decay rate
at a single aromatic concentration. No realistic error limits can be given to the nonexponential behavior of the
OH decays, and, in extreme cades, the rate constants given indicate the order of magnitude only.
-------
5xlOH
IxlO
3
O
ro
e
o
IxlO
Methoxy benzene
2.2
2.6 3.0
IOOO/T(°K)
3.4
Figure 4.
Arrhenius Plots of log k Against 1000/T(K) for Methoxy-
benzene and o-Cresol.
o Exponential OH radical decays observed.
x Non-exponential OH radical decays observed. The dashed
lines merely reflect the trend of the data in tempera-
ture regions where non-exponential decays are observed.
51
-------
due to reaction of OH radicals with reaction products would be typically
<5-10%, using an assumed rate constant of 10~10 cm3 molecule""1 sec"1
for the reaction of OH radicals wit-, all reaction products.
The experimental observations are again explained (using methoxybenzene
as an example) by a reaction scheme (48) involving both abstraction (reac-
tion I) and addition to the aromatic ring (reaction II).
OCH,
OH +
IUO
OCH,
(1)
OCR
Addition of the OH radical is shown for attack at the ortho position
by analogy with the reaction of 0(^P) atoms with aromatic hydrocarbons
(A2.».4A»-4JL)» obviously addition of the OH radicals may occur at any of the
carbon atoms of the aromatic ring, forming a variety of OH-aromatic adducts
which initially contain the excess energy due to the exothermicity of the
reaction. The initially formed OH-aromatic adduct, which contains approxi-
mately 18 kcal mole"1 of excess energy (see later), will, as discussed
previously, be readily thermalized in the presence of ~100 torr of argon;
hence reaction (-2) refers to the decomposition to the thermalized OH-
aromatic adduct back to reactants.
The experimental results are consistent with the occurrence of the
above reactions with the OH-aromatic adducts being stable within the
time frame of OH radical observations (1-30 msec) from 299 K to ~330 K,
and being unstable for temperatures >390 K. Hence, at room temperature, the
measured rate constants are those for both addition and abstraction, k = ko
+ k£, while at £390 K only k^, the rate constant for abstraction, is
measured.
52
-------
The following Arrhenius expressions for H atom abstraction (kj)
and addition to the aromatic ring (k2) can be obtained from least squares
analysis of the data in the temperature regions T - 299-325 K and T _>360
K for methoxybenzene, and T « 299-340 K and T .> 400 K for o-cresol (in
view of the appreciable error limits the Arrhenius activation energies
are quoted to the nearest 0.1 kcal mole"*):
methoxybenzene: kj « 1.7 x 10~12 e500/RT cm^ molecule'1 sec"1
k2 = 3.7 x 10~12 e800/RT ^3 molecule'* sec'1
o-cresol: kx - 5.0 x 10'11 e'1800/RT cm^ molecule'1 sec'1
fc2 - 1.6 x 10'12 eiSOO/RT cm3 molecule'1 sec'1
Because of the small temperature ranges in each region the error
limits are large and extrapolation outside of these temperature ranges will
give large uncertainties in the values obtained. Discussion of the
individual values of the pre-exponential factors and Arrhenius activation
energies has little merit in view of the large error limits, except to
point out that reaction 2 has a negative temperature dependence, as
previously observed (48) for the aromatic hydrocarbons (except benzene).
The overall uncertainties in EI and E2 are estimated to be ±2 kcal mole'1.
By extrapolation of the data above 390 K to room temperature, the values of
kj and ki/(kj + k2) at 299 K shown in Table 10 can be obtained. These
values are of a similar order of magnitude as those derived for the
aromatic hydrocarbons (48).
Table 10. H Atom Abstraction Rate Constants, kj and the Ratio kj/(ki + k2)
for the Reaction of OH Radicals with Methoxybenzene and o-Cresol
at 299 K
Aromatic 1012 x kj cm-* molecule'1 sec'1 *
methoxybenzene 3.9 0.2
o-cresol 2.6 0.08
(a)Extrapolated from T £380 K to 299 K using the Arrhenius line in Figure 2.
limits are estimated to be approximately a factor of two.
53
-------
The rate constant k-2 for the thermalized OH-aromatic adduct is given
by
k_2 = A_2 e - (HI)
As noted above, OH radicals are monitored with the present experimental
systems for -1-30 msec after the flash, and significant nonexponentiality
of the OH decay curves was observed at temperatures from ~330-390 K. Hence
the half-life of the OH-aromatic adduct must be of the order of -5-10 msec
in this temperature range, corresponding to k_£ ~100 sec"1 at 360 K. For
A_2 estimated to be 3 x lO1-^ sec""* [of the same order of magnitude as the A
factors for decomposition of the cyclohexadienyl (49) and methylcyclohex-
adienyl radicals (50)] the activation energy for reaction (-2) becomes E_2
~18 kcal mole"1- (Individual data are given in Table 11).
From equation (III) the half-lives of the OH-aromatic adducts can be
estimated to be 0.33 sec at 299 K, 19 msec at 330 K, 0.28 msec at 390 K and
0.03 msec at 435 K. These values of A_2 and E_2 thus give half-lives of
the OH-aromatic adducts which are totally consistent with both the reaction
scheme discussed above and the experimental observations.
Knowing the activation energies of reactions (2) and (-2), the heats of
formation of the OH-aromatic adducts can be obtained as (51):
Hf(OH-aromatic adduct) = Hf(aromatic) + Hf(OH) - H2
where H£ is the enthalpy of reaction (2) and
H2 = E_2 - £2 + RT
where E_2 and £2 are the activation energies for reactions (-2) and (2)
respectively.
Table 11 gives the Arrhenius activation energies E_2 and E£ used
together with the experimental and calculated heats of formation Hf of the
OH-aromatic adducts. The calculated values of Hf (OH-aromatic adduct)
were obtained as in the previous work (48), except that a stabilization
energy of 19.0 kcal mole"1 was found to give the best fit between the
experimental and calculated values of Hf (OH-aromatic adduct). This
values is similar to, though somewhat higher than, that of 16.5 kcal
mole"1 previously determined for the aromatic hydrocarbons (48). While
54
-------
Table 11. Arrhenius Activation Energies for Reactions (2) and (-2) and
Heats of Formation AHf for the OH-Aromatic Adducts
Hf kcal molecule"1
Aromatic
Methoxybenzene
o-Cresol
E2
kcal mole"1
-0.8 + 2
-1.8 + 2
E_2 (
kcal mole"1
18.1+2
19.1+2
OH-aromatic
adduct
Aromatic
-18.00(d)
-30.74(e)
Exp(b)
-28.4 + 4
-43.1 ± 4
Calc(c)
-29.5
-42.6
(a)fi_2 obtained using A_2 = 3 x lO1^ sec"1, k_2 = 100 sec"-'- at the temper-
ature corresponding to the midpoint of the dashed lines in Figure 4.
Indicated error limits are equivalent to a factor of 100 in A_2/k_2
at the temperature of midpoint of the dashed lines of Figure 4.
(b)Calculated using AHf (OH) = 9.2 + 1 kcal mole"1 (52) and AHf (OH-aromatic
adduct) = AHf (aromatic) + AHf(OH) - (E_2 - E2 + RT).
(c)Calculated from group additivity rules, using a stabilization energy for
the radicals of 19.0 kcal mole"*. The calculated values of AHf refer to
the following cyclohexadienyl radicals: for methoxybenzene, l-methoxy-2-
hydroxy and for o-cresol, l-methyl-2,3-dihydroxy. These radicals were
obtained by assuming the OH radical attack occurs ortho to the methoxy
and hydroxy groups, respectively, analogous to 0(^P) reaction.
(d)Reference 51.
(e)Reference 53.
these two stablization energies are equivalent within the error limits
(estimated at + 5 kcal mole"1), a trend to a higher stabilization energy
for the radicals produced from methoxybenzene and o-cresol may be expected
as the methoxy and hydroxyl substituents will stabilize the OH-aromatic
adducts via interaction of the electrons of the oxygen atom with the
aromatic ring (54).
55
-------
7. THE GAS PHASE REACTION OF 0? WITH A SERIES
OF AROMATIC HYDROCARBONS
Although a large amount of rate of product information exists for
the gas phase reactions of ozone with olefinic hydrocarbons, little data
are available for the reactions of 63 with the aromatic hydrocarbons. No
systematic studies have been carried out, but the aromatic hydrocarbons
appear to be relatively unreactive towards ozone with room temperature rate
constants of the order of 10~20 cm3 molecule"! sec~l (55-.5_7) • The only gas
phase product data available are indirectly derived from the NOX photo-
oxidation of a series of aromatic hydrocarbons carried out by Nojima,
Fukaya, and Kanno (58) where a-dicarbonyls (glyoxal, methylglyoxal, and
biacetyl) were observed as products.
In this work, rate constants for the gas phase reaction of 03 with a
series of aromatic hydrocarbons have been determined at 297 +_ 2 K from 03
decay rates in the presence of excess reactant. Acetylene was included in
the reactants studied since its room temperature rate constant is reason-
ably well known (5J^,.59.-J>1_) and hence could be used as a check on the
experimental technique. Product analyses were also carried out for the
reaction of 63 with selected aromatic hydrocarbons.
A. Experimental Methods
The reaction cell was a stirred 23 liter cylindrical Pyrex vessel
which could be routinely evacuated to £2 x 10~^ torr. 03-reactant mixtures
were prepared by filling calibrated volumes with reactants to known pres-
sures, and then expanding them into the evacuated reaction vessel. The
reaction vessel was then pressuized to 760 torr with synthetic air (N£/02
- 4.0) prepared from 02 (>99.99% purity) and N2(>99.998% purity). Pres-
sures were measured by a 0-10 torr MKS Baratron gauge or by a 0-800 torr
Wallace and Tiernan FA-160 absolute pressure gauge. All reactions were
carried out at 297 + 2 K.
03 concentrations were monitored by a NO-03 chemiluminesent detector
operated at ~2 torr total pressure. A sample flow rate of 3.0 cm3 sec~l
at STP and NO flow rate of 45.0 cm3 sec"1 at STP were used. The N02
emission was detected by a cooled EMI 9558A photomultiplier tube fitted with
o
a cut-off filter transmitting A2.4700 A. This instrument was calibrated by
56
-------
monitoring 03 concentrations as determined by long-path (40 meter) infrared
absorption spectroscopy at 9.48 p using a Perking-Elmer 621 infrared
spectrophotometer and the 9.48 p ozone extinction coefficient of Hanst,
Stephens, Scott, and Doerr (62), and was linear over the range (0.25-125)
x 1Q13 molecule cm~3.
Reaction products were anlyzed by gas chromatography using both a 50
cm x 0.3 cm Teflon column, packed with Carbowax 400 on 60/80 firebrick,
operated at 297 K with an electron capture detector and a 300 cm X 0.3 cm
stainless steel column, packed with Carbonwax 600 on 60/80 firebrick,
operated at 373 K with a flame ionization detector. In addition, product
analyses were carried out by using long-path (40 meter) infrared absorption
spectroscopy and by a Finnigan 3100D combined gas chromatograph-mass
spectrometer.
Gas chromatographic analysis showed that all reactants had a purity
of 2.98%. Approximately two percent 03 in Q£ was prepared by passing
°2 (j>99.99% purity) through a Welsbach T-408 ozonizer.
B. Products
Table 12 shows the results of qualitative product analyses carried
out for the reactions of 63 with toluene, o-xylene and 1,3,5-trimethyl-
benzene. The major products observed from the reaction of 03 with these
aromatic hydrocarbons were a-dicarbonyls, in agreement with the observa-
tions of Nojima, Pukaya, Fukui and Kanno (5.8) on the gas phase NOX photo-
oxidation of these compounds.
A quantitative product analysis was carried out for the reaction of
ozone with 1,3,5-trimethylbenzene using long-path infrared absorption
spectroscopy. Figure 5 shows a typical time dependence of the product
and reactant concentrations. From the data at short reaction times, it
can be calculated that A [methylglyoxal] /A[1,3,5-trimethylbenzene] =3.0
+ 0.5 and A [03]/A [1,3,5-trimethylbenzene] = 2.0 + 0.3. These results
suggest the following stoichiometry:
0 0
II II
3 CH3C-CH
57
-------
2.5 r xlO
METHYLGLYOXAL
1.3.5 TRIMETHYLBENZENE
4 6
TIME (sec)
lOxlO4
Figure 5. Plot of Reactant and Product Concentrations Against Time
for the Reaction of 0» with 1,3,5-Trimethylbenzene.
58
-------
Table 12. Products Observed for the Reaction of 03 with Toluene, o-Xylene
and 1,3,5-Trimethylbenzene
Reactant
Method A
Method B
Method C
Toluene
o-Xylene
1,3,5-Trimethyl-
benzene
methyIglyoxal
glyoxal
glyoxal
methyIglyoxal
biacetyl
methyIglyoxal
benzaldehyde
biacetyl
o-tolualdehyde
CO, C02, HC02H
CH3C02H methyl-
glyoxal, glyoxal
CO, C02, HC02H
CH3C02H, methy1-
glyoxal
CO, C02, HC02H
methyIglyoxal,
CH3C02H
Method A 50 cm X 0.3 cm Teflon column, packed with Carbowax 400 on 60/80
firebrick, operated at 297 K with an electron capture detector.
Method B 300 cm X 0.3 cm stainless steel column, packed with Carbowax 600
on 60/80 firebrick, operated at 373 K with a flame ionization
detector.
Method C Long-path infrared analysis in a 40-meter gas cell coupled to a
Perkin-Elmer 621 infrared spectrometer.
Carbon balances averaged over the three runs were (105 + 15%) with methy 1-
glyoxal accounting for >85% of the product carbon. The other minor products
(CO, C02, HCOOH and CH3COOH) observed in this reaction were also obtained
from the ozonolysis of methyIglyoxal, although their time dependence (Figure
5) indicates that they are primary products. It was also observed that
A [03]/A [aromatic] - 1.9 + 0.4 for the reactions of 03 with toluene and
o-xylene indicating that the stoichiometry was 2.0 for the reactions of 03
with all the aromatic hydrocarbons studied.
C. Kinetics
Rate constant determinations were carried out under conditions such that
the reactant concentration was always in excess of the 03 concentration
59
-------
([reactant]/[03] >. 20). Hence, <-he pseudo-first order decay of ozone is
given by the integrated rate expression
ln([03])0/[03] = (kx + nk2 [reactant]) (t-t0)
where [03Jo, [03] are the 03 concentrations at times tQ and t,
respectively, k2 is the first order decay of 03 (attributed to hetero-
geneous wall decomposition), k2 is the rate constant for the reaction
n03 4- reactant ->- products
and n is the stoichiometry factor. The decays of 03 were observed to be
exponential over 1-3 half-lives and were reproducible to within + 10%.
Values of nk2 were obtained from the slopes of plots of the 03 decay
rate, defined as (t-tQ)"1 In [03]Q/[03], against reactant concen-
tration, such as those shown in Figure 6 for benzene, toluene, m-xylene and
1,2,4-trimethylbenzene. In the absence of reactant, the 03 decay rates
kj varied from (1.7-5.9) X 10~6 sec"!. The stoichiometry factor, n,
has been shown to be 1.0 for the reaction of 03 with acetylene (9,6J)) and a
value of n = 2.0, as determined for toluene, o-xylene and 1,3,5-trimethyl-
benzene, was used for the aromatic hydrocarbons. In the case of methyl-
glyoxal, a stoichiometry factor n = 1 was assumed. The rate constants k2
so obtained are given in Table 13. The rate constant for the reaction of
03 with methylglyoxal, a typical major product from the reaction of 03
with the aromatic hydrocarbons studied, is approximately of the same order
of magnitude as those for the individual aromatic hydrocarbons. At the
low conversions of aromatic hydrocarbons used, (2-5%), secondary reactions
should be minimal and thus the rate constants k2 determined should be
close to those for the primary reaction.
Table 13 also shows that the rate constant determined in this study
for the reaction of 03 with acetylene is in reasonably good agreement with
the values obtained by Cadle and Schadt (59), DeMore (j>0,61_) and Stedman
and Niki (57). The rate constants k2 obtained in this work for the
xylenes and 1,3,5-trimethylbenzene are also consistent with the upper
limits determined by Hanst, Stephens, Scott and Doerr (56) and Stedman
and Niki (57) and by Bufalini and Altshuller (55) respectively.
However, the present rate constant for the reaction of 03 with
toluene is much lower than that determined by Stedman and Niki (57). No
immediate reason for this discrepancy is obvious. The rate constants k2
60
-------
20
o
j? l5
LU
h-
OC 10
>-
o
UJ
Q 5
ro
O
0
xlO'5
1.2.4 TRIMETHYLBENZENE
0
2 3
[AROMATIC] molecule crrr3
4x10
17
Figure 6. Plot of the Og Decay Rate Against Aromatic Hydrocarbon Concentration for Benzene,
Toluene, m-Xylene and 1,2,4-Trimethylbenzene,
-------
Table 13. Comparison of the Present Room Temperature Rate Constants
with Selected Literature Values
10 X k» cm molecule sec
Gas Phase
This Work (297+2°K)a Literature CCL^ Solution
Acetylene
Benzene
Toluene
o-Xylene
m-Xylene
p-Xylene
1,2,3-Trimethylbenzene
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Methylglyoxal
3.8 ± 0.6
0.007 ± 0.004
0.015 ± 0.008
0.07 ± 0.02
0.06 ± 0.02
0.04 ± 0.02
0.16 ± 0.04
0.13 ± 0.03
0.22 ± 0.06
0.11 ± 0.05
7.8 ± 2.8
5.9C
3.0 ± 0.5°
8.6 ± 0.9£
1.2 ± 0.6
< 0.5
< 20f
< 10£
0.0047 ± 0.0003
0.028 ± 0.001
0.14 ± 0.01
0.13 ± 0.01
0.16 ± 0.01
0.47 ± 0.05
0.47 ± 0.05
0.70 ± 0.07
The indicated error limits are the estimated overall error limits.
Stoichiometry factors: n = 1 for acetylene and methylglyoxal, n = 2
for the aromatic hydrocarbons.
bCadle and Schadt (59), T = 303 K.
r\
DeMore (60), derived from Arrhenius expression, T = 297 K.
^DeMore (61), T = 294 K.
6Stedman and Niki (57^), T = 298 K.
Hanst, Stephens, Scott and Doerr (56).
SBufalini and Altshuller (55).
TJakagawa, Andrews and Keefer (63), T = 298.4 K.
62
-------
for the aromatic hydrocarbons show a similar trend with the degree of
alkylation as do those for the reaction of the aromatic hydrocarbons with
0(3P) atoms (64.) and with OH radicals (65,66.), indicating the electro-
philic character of 03 in these reactions. Table 13 also includes the
rate constants obtained by Nakagawa, Andrews and Reefer (63) in CC14
solution. It can be seen that there is a close correspondence of the
rate constants obtained in CCl^ solution with those obtained in the
present work in the gas phase. Such a correspondence between solution
phase and gas phase rate constants has previously been noted (67) for
several paraffinic hydrocarbons.
The rate constants, k2, determined in this work lead to aromatic
hydrocarbon half-lives in the presence of 0.1 ppm (2.47 x 10^2 molecule
cm~3) of 63 (typical levels in a polluted urban atmosphere) ranging
from ~2 years for 1,3,5-trimethylbenzene to -90 years for benzene.
Hence, their reaction with 03 will be a negligible loss process in
polluted urban atmospheres compared to their reaction with OH radicals (65).
VIII. CHEMICAL IONIZATION MASS SPECTRUM OF PEROXYACETYLNITRATE (PAN)
Attempts (Jij5,6£) to measure the molecular weight of PAN using conventional
and time-of-flight mass spectrometers, both equipped with electron impact
(E.I.) ion sources, were unsuccessful in that no molecular ion was observed.
However, the more stable molecular ion of the homologous molecule, peroxy-
benzoylnitrate, has been detected using E.I. ionization (70). Because
chemical ionization (C.I.) leads to less fragmentation than does ionization
by electron impact (_7JL~Z4.)» C.I. mass spectra of oxygen-containing substrates
usually contain substantial [M + H ] + peaks formed by proton transfer from
the reagent gas. Therefore, we sought to determine the molecular weight of
PAN by obtaining a C.I. mass spectrum of PAN, which contained a [M + H] + ion.
A. Experimental
PAN (1000 ppm in N2) was prepared and analyzed by the method of Stephens
(15,76). It was separated from traces of CH3ONO, CH3ON02, CH3N02 and
C2H50N02 by introduction into the ion sources of a quadrupole mass spectro-
meter using an all-glass gas chromatographic inlet system. The total ion
current chromatogram presented in Figure 7 shows that all impurity peaks
were well resolved from the PAN peak. Mass spectral scans of the PAN peak
63
-------
lOO-i
h-
UJ
cr
o:
o
o
<
o
5.0
TIME (MIN)
10.0
Figure 7. Total Ion Current Chromatogram of PAN (1000 ppm in N ) ,
64
-------
taken early and late during its elution gave identical mass spectra.
Therefore, the PAN peak did not contain any unresolved contaminant.
Mass spectra were recorded using a Finnigan 3200 quadrapole mass
spectrometer equipped with a C.I. ion source, an all-glass gas chromato-
graphic inlet system and a computer data acquisition system. PAN samples
(1000 ppm in N£> were introduced into the mass spectrometer using the
gas chromatographic inlet system equipped with a 1 m x 2 mm Teflon column
packed with 5% Carbowax E-400 on 60/80 mesh, acid washed-DMCS treated
Chromosorb W (2Z >!§.)• Methane and isobutane reagent gas flow rates were
30 ml min~l. Operating temperatures and mass spectrometer settings were
as follows: g«c. injector and column, separator oven and transfer line
temperatures, all 25 C; ion source temperature, 60 C; reagent gas ion
source pressures, 0.4 and 1.0 Torr for Ctfy and 0.2 Torr for i-C^jo*
electron energy, 152 eV; electron multiplier voltage, 1.9 kV.
B. Results and Discussion
Table 14 summarizes the C.I. mass spectrum of PAN obtained using
methane and isobutane reagent gases. With both reagent gases, the ion
with the largest mass in the mass spectrum of PAN appears at m/e 122.
Two observations confirm that this ion is the [M + H] + of PAN. First,
the intensity of the ion increases dramatically when the reagent gas is
changed from CIfy to i-C^^g and, second, when the pressure of CH^
is adjusted (0.4 Torr) so as to maximize the intensity of the m/e 122
peak, a small peak at m/e 150 (M + 29) appears in the methane C.I. mass
spectrum of PAN. Therefore, the molecular weight of PAN is 121 a.m.u.
The intense fragment ions at m/e 42 [CH3CO]+ and m/e 46 [N02]+
detected using CIfy as reagent gas are most likely formed by the following
decomposition pathways.
PAN + [CH5J+—» CH4 + [PANH]
+ 0. + HN02 II
m/e 43
65
-------
Table 14. Chemical lonization Mass Spectra of PAN
m/e
122
121
120
88
77
61
57
56
55
48
46
45
44
43
42
Ion Intensity
3.5
0.5
—
1.0
0.3
1.7
2.1
0.4
0.6
0.4
100.0
12.0
1.4
45.1
5.4
(% of base peak)
100.0
15.1
1.9
1.7
4.6
13.0
t
1
n
o
t
s
c
a
n
n
e
d
J
Ion
[M + H] +
[M] +
[M - 1J +
[0 CCH2ONO] +
[CH3ON02] +
[CH3ONO]+
[CHC02] +
[N02] +
[HC02]+
[C02] +
[CH3CO]+
[CH2CO] +
aPressure, 1.0 Torr; mass range 42-300 a.m.u.
^Pressure, 0.2 Torr; mass range 60-300 a.m.u.
66
-------
The ions at m/e 61 and 77 are most probably [CH3ONO]+ and [CH3ON02] +
formed by CH3 transfer to N02 via a cyclic six-membered transition state:
—0
CHO -I- 02 +
m/e 61
[CH3ONO]
III
IV
m/e 77
Because the PAN spectrum does not contain ions at m/e 62 and 78 (the
[M + H]+ ions corresponding to CH3ONO and CH30N02) the ions at m/e
61 and 77 cannot be caused by tailing of the CH3ONO or CH30N02 impur-
ities. The following decomposition path may possibly explain the ion
at m/e 88:
PAN
0.
v.o
0—0
0 + [0 = CCH ONO] «-
m/e 88
The three fragmentation pathways depicted by paths I, III and V are
all consistent with the formulation of PAN as peroxyacetylnitrate,
CH3(CO)OON02 (68). and are not consistent with its formulation as
acetylpernitrate, CH3(CO)ON03 (79). This conclusion is also supported
by simple valence considerations (80) and a recent infrared study of 15N
labeled PAN. Thus, the C.I. mass spectral evidence reported here confirms
PAN's molecular weight, which had previously been inferred from chemical
properties (68,82_), and supports PAN's commonly accepted structure
67
-------
REFERENCES
1. J. N. Pitts, Jr. and B. J. Finl-yson, Angew. Chem., Int. Ed., _H, 1
(1975).
2- R. F. Hampson, Jr. and D. Garvin, "Reaction Rate and Photochemical
Data for Atmospheric Chemistry - 1977," NBS Spec. Pub. 513, May 1978.
3. R. Atkinson, K. R. Darnall, A. C. Lloyd, A. M. Winer and J. N.
Pitts, Jr., Adv. Photochem.. _U, 375 (1979).
4. H. Niki, E. E. Daby and B. Weinstock, Adv. Chem. Soc., 113. 116
(1972).
5. K. L. Demerjian, J. A. Kerr and J. G. Calvert, Adv. Environ. Sci.
Technol., _4» 1 (1974).
6. A. C. Baldwin, J. R. Barker, D. M. Golden and D. G. Hendry, J. Phys.
Chem. 81. 2483 (1977).
7. W. P. L. Carter, A. C. Lloyd, J. L. Sprung and J. N. Pitts, Jr.,
Int. J. Chem. Kinetics.. 11. 45 (1979).
8. T. A. Hecht, J. H. Seinfeld and M. C. Dodge, Environ. Sci. Technol.,
1, 327 (1974).
9. G. Z. Whitten and H. Hogo, "Mathematical Modeling of Simulated Photo-
chemical Smog," Systems Applications, Inc., EPA-600/3-77-011, January
1977.
10. D. G. Hendry, A. C. Baldwin, J. R. Barker and D. M. Golden, "Computer
Modeling of Simulated Photochemical Smog," EPA-600/3-78-059, June
1978.
11. A. H. Falls and J. H, Seinfeld, Environ. Sci. Technol.. 12. 1398
(1978).
12. C. Z. Whitten, H. Hogo, M. J. Meldgin, J. P. Killus and P. J.
Bekowies, "Modeling of Simulated Photochemical Smog with Kinetic
Mechanisms," EPA-600/3-79-001, January 1979.
13. J. N. Pitts, Jr., K. R. Darnall, A. M. Winer and J. M. McAfee,
"Mechanisms of Photochemical Reactions in Urban Air, Volume 2,
Chamber Studies," EPA-600/3-77-014b, 1977.
14. A. M. Winer, R. A. Graham, G. J. Doyle, P. J. Bekowies, J. M.
McAfee and J. N. Pitts, Jr., "An Evacuable Environmental Chamber-Solar
Simulator Facility for the Study of Atmospheric Photochemistry,"
Ady. Environ. Sci. Technol. 10 (1979), in press.
68
-------
15. J. H. Beauchene, P. J. Bekowies, J. M. McAfee, A. M. Winer, L. Zafonte
and J. N. Pitts, Jr., "A Novel 20 KW Solar Simulator Designed for Air
Pollution Research," Proc. Seventh Conf. on Space Simulation, Paper
No. 66, NASA Special Publication 336, pp. 811-825, 1973.
16. G. J. Doyle, P. J. Bekowies, A. M. Winer and J. N. Pitts, Jr., "Char-
coal-Adsorption Air Purification System for Chamber Studies Investiga-
ting Atmospheric Photochemistry." Environ. Sci. Technol.. 11, 45
(1977). —
17. J. R. Holmes, R. J. O'Brien, J. H. Crabtree, T. A. Hecht and J.
H. Seinfeld, "Measurement of Ultraviolet Radiation Intensity in
Photochemical Smog Studies," Environ. Sci. Technol.. _7, 519 (1973).
18. J. N. Pitts, Jr., J. M. McAfee, W. D. Long and A. M. Winer, "Long-
Path Infrared Spectroscopic Investigation at Ambient Concentrations
of the 2% Neutral Buffered Potassium Iodide Method for Determination
of Ozone," Environ. Sci. Technol.. 10. 787 (1976).
19. State of California Air Resources Board, "Comparison of Oxidant
Calibration Procedures," Final Report of the Ad Hoc Measurement Com-
mittee, February 3, 1975.
20. E. C. Ellis, "Technical Assistance Document for the Chemiluminescence
Measurement of Nitrogen Dioxide," EPA-600/4-75-003, December 1975.
21. A. M. Winer, J. W. Peters, J. P. Smith and J. N. Pitts, Jr., "Response
of Commercial Chemiluminescent NO-N02 Analyzers to Other Nitrogen-
Containing Compounds," Environ. Sci. Technol.. _8, 1118 (1974).
22. D. F. Miller and C. W. Spicer, J. Air Pollut. Control Assoc.. 25.
940 (1975).
23. R. G. Smith, R. J. Bryan, M. Feldstein, B. Levadie, F. A. Miller,
E. R. Stephens and N. G. White, "Tentative Method of Analysis for
Formaldehyde Content of the Atmosphere (Colorimetric Method)." H. L.
S.., _7, (1) Supplement, 87 (1970).
24. I. R. Cohen and T* C. Purcell, Anal. Chem.. 39. 131 (1967).
25. W. Pilz and I. Johanns Intern. J. Environ. Anal. Chem., J3, 257 (1974).
26. E. R. Stephens and F. R. Burleson, "Analysis of the Atmosphere
for Light Hydrocarbons," J. Air Pollut. Control Assoc.. 17_, 147
(1967).
27. E. R. Stephens, "Hydrocarbons in Polluted Air," Summary Report,
Coordinating Research Council, Project CAPA-5-68, June 1973; NTIS No.
PB 230 993/As.
28. K. R. Darnall, W. P. L. Carter, A. C. Lloyd, A. M. Winer and J. N.
Pitts, Jr., J. Phys. Chem., .80, 1948 (1976).
69
-------
29. E. F. Barley, K. A. Kettner and E. R. Stephens, "Analysis of Peroxy-^
acyl Nitrates by Gas Chromatngraphy with Electron Capture Detection,"
Anal. Chem.. _35, 589 (1963).
30. E. R. Stephens and M. A. Price, 'Analysis of an Important Air
Pollutant: Peroxvacetvl Nitrate." J. Chem. Educ., jQ, 351 (1973).
31. E. R. Stephens, F. R. Burleson and E. A. Cardiff, "The Production
of Pure Peroxyacyl Nitrates," J. Air Pollut. Control Assoc., 15.,
87 (1965).
32. E. R. Stephens, F. R. Burleson and K. M. Holtzclaw, "A Damaging
Explosion of Peroxyacetyl Nitrate," J. Air Pollut. Control Assoc.,
J.9., 261 (1969).
33. M. W. Holdren and R. A. Rasmussen, "Moisture Anomaly in Analysis of
Peroxyacetyl Nitrate (PAN)." Environ. Sci. Technol.. 10, 185 (1976).
34. I. Watanabe and E. R. Stephens, "Reexamination of Moisture Anomaly
in Analysis of Peroxyacetyl Nitrate," Environ. Sci. Technol.. 12,
222 (1978).
35. C. H. Wu and H. Niki, "Methods for Measuring N02 Photolysis Rate,"
Environ. Sci. Technol.. _£, 46 (1975).
36. J. J. Bufalini, S. L. Kopczynski and M. C. Dodge, Environ. Lett.,
1, 100 (1972).
37. C. H. Wu, S. M. Japar and H. Niki, J. Environ. Sci. Health. All,
191 (1976).
38. J. J. Bufalini, T. A. Walter and M. M. Bufalini, Environ. Sci.
Technol.. _11_, 1181 (1977).
39. W. P. L. Carter, A. M. Winer and J. N. Pitts, Jr., Unpublished
Results.
40. K. R. Darnall, A. M. Winer and J. N. Pitts, Jr., Unpublished
Results.
41. G. Boocock and R. J. Cvetanovic, Can. J. Chem., 39, 2436 (1961).
42. G. R. H. Jones and R. J. Cvetanovic, Can. J. Chem., 19. 2444 (1961).
43. I. Mani and M. C. Sauer, Jr., Adv. Chem. Series, No. 82. 142 (1968).
44. E. Grovenstein, Jr. and A. J. Mosher, J. Amer. Chem. Soc., 92, 3810
(1970).
45. R. A. Bonanno, P. Kim, J. H. Lee and R. B. Timmons, J. Chem. Phys.
^7, 1377 (1972). '
46. J. S. Gaffney, R. Atkinson and J. N. Pitts, Jr., J. Amer. Chem. Soc.
.98, 1828 (1976). *
70
-------
47. M. Hoshino, H. Akimoto and M. Okuda, Bull. Chem. Soc. Japan, 51,
718 (1978). —
48. R. A. Perry, R. Atkinson and J. N. Pitts, Jr., J. Phys. Chem., 81,
2196 (1977). —
49. D. G. L. James and R. D. Suart, Trans. Faraday Soc., 64. 2752 (1968).
50. A. Amano, 0. Horie and N. H. Hanh, Int. J. Chem. Kinet., 8, 321
(1976). ~
51. S. W. Benson, "Thermochemical Kinetics," 2nd Ed., Wiley, New York, (1976).
52. J. A. Kerr, M. J. Parsonage and A. F. Trotman-Dickerson, "Strengths of
Chemical Bonds," in Handbook of Chemistry and Physics, 56th Ed., The
Chemical Rubber Company, 1975-1976.
53. J. H. S. Green, Chem. Ind., 1575 (1962).
54. C. K. Ingold, "Structure and Mechanism in Organic Chemistry, Cornell
University Press, 1953.
55. J. J. Bufalini and A. P. Altshuller, Can. J. Chem., 43. 2243 (1956).
56. P. L. Hanst, E. R. Stephens, W. E Scott and R. C. Doerr, "Atmospheric
Ozone-Olefin Reactions," The Franklin Institute, Philadelphia,
Pennsylvania, 1958.
57. D. H. Stedman and H. Niki, Environ. Lett., 4., 303 (1973).
58. K. Nojima, K. Fukaya, S. Fukai and S. Kanno, Chemosphere, _5, 247 (1974).
59. R. D. Cadle and C. Schadt, J. Chem. Phys., 21, 163 (1953).
60. W. B. DeMore, Int. J. Chem. Kinet., .1, 209 (1969).
61- W. B. DeMore, Int. J. Chem. Kinet., .3, 161 (1971).
62. P. L. Hanst, E. R. Stephens, W. E. Scott and R. C. Doerr, Anal. Chem.,
33, 1113 (1961).
63. T. W. Nakagawa, L. J. Andrews and R. M. Keefer, J. Amer. Chem. Soc.,
82, 269 (1960).
64. R. Atkinson and J. N. Pitts, Jr., J. Phys. Chem., 78, 1780 (1974).
65. G. J. Doyle, A. C. Lloyd, K. R. Darnall, A. M. Winer and J. N. Pitts,
Jr., Environ. Sci. Technol., 1, 237 (1975).
66. D. A. Hansen, R. Atkinson and J. N. Pitts, Jr., J. Phys. Chem., 2i»
1763 (1975).
67. D. G. Williamson and R. J. Cvetanovic, J. Amer. Chem. Soc., 92., 2949
(1970).
71
-------
68. E. R. Stephens, Adv. Environ. Sci. Technol., _!_, 119 (1969).
69. E. R. Stephens, E. F. Darley, 0. C. Taylor and W. E. Scott, Int.
J. Air Water Pollut., ±, 79 (1961).
70. J. M. Heuss and W. A. Glasson, Environ. Sci. Technol., .2, 1109 (1978).
71. F. H. Field, Ace. Chem. Res., J., 42 (1968).
72. M. S. B. Munson and F. H. Field, J. Amer. Chem. Soc., 88. 2621 (1966).
73. E. C. Horning, D. I. Carroll, I. Dzidic and R. N. Stillwell, Adv. Biochem.
Psychopharm., _7, 15 (1973).
74. B. Munson, Anal. Chem., 28A, 43 (1971).
75. E. R. Stephens, F- R. Burleson and E. A. Cardiff, J. Air Pollut. Control
Assoc., .15_, 27 (1965).
76. E. R. Stephens, Anal. Chem., 36, 928 (1964).
i
77. E. F. Darley, K. A. Kettner and E. R. Stephens, Anal. Chem., 35, 589
(1963).
78. E. R. Stephens and M. A. Price, J. Chem. Educ., 50, 351 (1973).
79. P. L. Hanst, J. Air Pollut. Control Assoc., 21. 269 (1971).
80. R. D. Harcourt and D. P. Kelly, Environ. Sci. Technol., _8, 675 (1974).
81. E. Varetti and G. C. Pimentel, Spectrochim. Acta, _30A, 1069 (1974).
82. E. R. Stephens, Atmos. Environ., J^, 19 (1967).
72
-------
APPENDIX: DETAILED DATA SHEETS
73
-------
EC - 77
TOLUENE
MAY 20
BEGIN IRRADIATION llOOt 0.25 INCH PYfcEX FILTER
OZONE MOMTORfcD WITH OASI8I 1212 AND MONITOR LABS INSTRUMENTS
TEMPERATURE NOT MONITORED} STANDARD CONTROL PROCEDURE USED AS FOR 85 DfcG F RUNS
6U8BLER STARTED AT 1518 FOR TRAPPING OF ACIDIC PRODXTS, VOL IN HCHO VOL COLUMN
CO FACTOR 2.04/1.328; BECKMAN 6300 USED
PAN CALIB 9 (XI. 05)
1~Q AT 1100 POT
PAN
REL HUM
HCHO
CALIB*
9
2
1
REL HUM X
SSPOwER KW
RAD10M MW/CM2
NO PPM
N02-CORR PPM
CO PPM
HCHO PPM
ACETALD PPM
TOLUENE PPM
AVERAGE
AVERAGE
AVERAGE
INIT CONO
INIT COND
INIT CONO
INIT COND
INIT CONO
INIT CONO
* ASSIGNED INITIAL CONDITION
Kl=0.14 MIN-1
SAMPLING RATE * 2.399 L/MIN
64 GC SAMPLES TAKEN
39.47
19.73
0.140
0.518
0.058
1.663
0.003
0.001
0.276
-------
Ln
EC - 77
TOLUENE
1975 HAY 20
CLOCK
TIME
1100
111&
1130
1145
1200
1215
1230
1245
1300
1319
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
ELAPSED
TiMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
CASIBI
0.0
0.0
G.O
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.004
0.002
0.0
0.002
0.002
0.004
O.C06
0.004
0.004
0.008
0.010
0.010
0.012
OZONE
PPM
MONITOR
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.000
0.001
0.001
0.001
0.001
0.001
0.002
0.003
0.003
0.003
0.005
0.006
0.006
0.007
0.009
0.011
0.012
NO
PPM
0.518
0.511
0.501
0.469
0.474
0.457
0.442
0.427
0.410
0.391
0.371
0.352
0.332
0.313
0.293
0.276
0.256
0.239
0.220
0.205
0.188
0.176
0.159
0.144
0.129
N02-CORH
PPM
0.058
0.063
0.070
0.075
0.088
0.100
0.107
0.114
0.127
0.136
0.151
0.161
0.171
O.lfiO
0.187
0.195
0.204
0.211
0.216
0.224
0.226
0.228
0.236
0.233
0.235
NOA-CORR
PPM
0.574
0.571
0.569
0.566
0.559
0.557
0.549
0.544
0.537
0.527
0.520
0.513
0.503
0.493
0.461
0.471
0.461
0.448
0.438
0.426
0.414
0.402
0.392
0.377
0.367
TOLUENE
PPM
0.276
0.274
0.272
0.270
0.260
0.252
0.25U
0.244
0.240
U.236
0.230
0.224
0.220
0.216
0.208
0.204
0.196
0.196
0.190
0.185
0.1SO
0.178
0.172
0.168
0.164
CO
PPM
1.68
1.74
1.72
1.72
1.74
1.69
1.70
1.73
1.74
1.77,
1.77
1.78
1.80
1.77
1.79
1.60
1.82
1.64
1.81
1.97
1.86
1.85
1.87
1.65
1.89
PAN
PPM
0.000
******
0.000
******
o.ouo
******
0.000
******
0.000
******
0.000
******
0.000
******
******
******
0.001
******
0.001
******
******
0.001
******
******
0.002
HCHO
PPM
0.003
******
******
******
0.004
******
******
******
0.011
******
******
******
0.013
******
******
******
0.015
******
******
******
******
******
******
******
******
ACETALD
PPM
O.OOIU
******
0.0020
******
0.0020
******
0.0030
******
0.0030
******
0.0030
******
0.0040
******
0.0040
******
0.0030
******
O.JOtO
******
******
******
o.oovo
******
0.0090
ACETONE
PPM
******
******
0.0050
******
0.0070
******
0.0060
******
0.0060
******
O.C100
******
0,0110
******
0.0120
******
0.0120
******
O.OilO
*«>****
******
******
0.0110
******
O.C160
-------
EC - 77
TOLUENE
1975 MAY 20
CLOCK
TIME
1100
1115
113U
1145
UJO
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
ELAPSED
TtMlNJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
163.
160.
195.
110.
ii5.
240.
255.
270.
265.
300.
315.
330.
345.
360.
REL HUM
»
41.5
41.5
41.5
41.5
41.5
41.5
41.0
41.0
40.5
40.5
40.0
40.0
39.5
39.5
39.5
39.0
38.5
38.5
36.0
38.0
37.5
37.5
37.0
37.0
36.5
SSPOhER
KM
19.10
******
******
******
19.60
******
******
******
******
19. ao
******
******
******
******
******
******
******
19.80
******
******
20.20
******
******
******
19.90
RA01GH
HM/CM2
******
******
******
******
0.140
******
******
******
******
0.139
******
******
******
******
******
******
******
0.140
******
******
******
******
******
******
******
PO #2
VOLTS
0.457
0.442
0.440
0.442
0.442
0.442
0.442
0.440
0.440
G.440
0.442
0.442
0.442
0.442
0.442
0.445
0.445
0.440
0.442
0.442
0.442
0.442
0.442
******
0.437
HCHO VOL
L
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
27.00
******
30.00
******
30.00
******
15.00
-------
EC - 78
TOLUENE
1975 MAY 28
6EGIN IRRADIATION 1045; 0.25 INCH PYREX FILTER
OiONE MONITORED WITH CASIBI 1212 AND MONITOR LASS INSTRUMENTS
TOLUENE = 0.230 PPM AT 1025
SAMPLE 1605-1650 AT 6 L/MIN
TEMPERATURE NOT MONITORED; STANDARD CONTROL PROCEDURE USED AS FOR 85 DEC F RUNS
CO FACTOR 2.64/1.35! BECKMAN 6800 USED
PAN CALI6 9 (X1.05)
T»0 AT 1045 POT
CALIB*
PAN
REL HUM
HCHO
R£L HUM
SSPOwER
RA010M
NO
N02-CORR
CO
ACETALD
AC ETONE
TOLUENE
i
KK
HH/CMZ
PPM
PPM
PPM
PPM
PPM
PPM
9
2
I
AVERAGE
AVfcRAGE
AVERAGE
INIT CCNO
I NIT COND
1NIT CCND
INIT CONO
INIT CCNO
INIT CCNO
29.95
19.70
0.137
O.C69
0.032
2.040
O.C04
0.005
0.210
* ASSIGNED INITIAL CONDITION
Kl*0.14 MIN-1
SAMPLING RATE « 2.278 L/MIN
57 GC SAMPLES TAKEN
-------
00
EC - 78
TOLUENE
1975 MAY 28
CLOCK
TIME
1045
1100
111S
1130
1145
1200
lily
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.;
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
OASIBI
0.0
0.0
0.008
0.018
0.027
0.041
0.055
0.064
0.076
0.086
0.086
0.090
0.090
0.092
0.090
0.090
0.066
0.086
0.088
0.088
0.088
0.086
0.084
0.084
0.086
OZONE
PPM
MCNJTOR
0.000
0.004
0.009
0.019
0.031
0.042
0.056
0.066
0.074
0.080
0.083
0.086
0.088
0.086
0.086
0.084
0.084
0.083
0.083
0.082
0.080
0.079
0.079
0.078
0.077
NO
PPM
0.069
0.053
0.032
0.020
0.014
0.011
0.010
0.008
O.OC8
0.007
0.008
0.007
O.C07
O.C07
O.C07
O.OG7
0.007
O.CC7
O.OC7
O.OC7
O.OC7
0.007
O.OC7
0.007
0.006
N02-CORR
PPM
0.032
0.045
0.060
0.066
0.062
li.055
0.047
0.041
0.035
0.030
0.025
0.022
0.019
o.oia
0.017
0.016
0.015
0.015
0.015
0.015
0.015
0.015
0.015
0.015
0.015
NOX-CORR
PPM
0.100
0.097
0.092
0.086
0.076
0.066
0.057
0.050
0.043
0.037
0.033
0.030
0.027
0.025
0.024
0.023
0.022
0.022
0.021
0.021
0.022
0.021
0.022
0.022
0.021
TOLUENE
PPM
0.210
0.226
0.218
0.208
0.202
0.190
0.184
0.178
0.170
0.164
0.159
0.156
0.150
0.145
0.144
0.140
0.139
0.138
0.136
0.134
0.128
0.128
0.126
0.124
0.122
CO
PPM
2.04
2.01
2.05
2.05
2.07
2.07
2.05
2.09
2.07
2.09
2.15
2.15
2.13
2.16
2.18
2.19
2.21
2.20
2.21
2.27
2.27
2.25
2.28
2.32
2.33
PAN
PPM
0.000
******
0.001
******
0.003
******
0.006
******
0.009
******
0.012
******
0.013
******
0.012
******
0.012
******
0.010
******
0.009
******
0.008
******
0.007
HCHO
PPM
0.0
******
******
******
O.OOJ
******
******
******
0.015
******
******
******
0.024
******
******
******
0.042
******
******
******
u.051
******
******
0.055
******
ACETALO
PPM
0.0040
******
O.OU50
******
0.0060
******
0.0060
******
O.OufaO
******
0.0110
******
0.0070
****¥*
0.0110
******
0.0060
******
0.0100
******
0.0100
******
U.OlOtl
******
0.0090
ACETONE
PPM
0.0050
******
0.0070
******
0.0100
******
0.0160
******
O.OtiO
******
O.C240
******
0.0250
******
0.0370
******
O.OjGO
******
0.0340
******
0.0-siO
******
o.0j6o
******
0.0370
-------
VO
EC - 78
TOLUENE
1975 MAY 26
CLOCK
TIME
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
2o5.
300.
315.
330.
345.
360.
REL HUH
X
43.0
43.0
43.0
43.0
43.0
42.5
42.5
41.5
41.5
41.0
40.5
40.0
40.0
39.5
39.0
39.0
36.5
38.0
38.0
37.5
37.5
37.0
37.0
36.5
36.0
SS POWER
Kb
18.70
******
19.60
******
******
******
19.40
******
******
******
******
******
20.00
******
******
******
20.10
******
******
******
20.40
******
******
******
******
RAOICM
MM/CM2
0.127
0.133
0.137
******
******
******
0.135
******
******
******
******
******
0.139
******
******
******
0.138
******
******
******
0.145
******
******
******
0.143
PD «2
VOLTS
0.445
0.440
0.440
0.442
0.437
0.437
0.435
0.432
0.442
0.437
0.442
0.440
0.437
0.440
0.437
0.440
0.440
0.435
0.442
0.445
0.445
0.445
0.442
0.447
******
HCHO VOL
L
30.00
******
******
******
30.00
******
******
******
3U. 00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
30.00
******
-------
oo
o
EC - 79
TOLUENE
1975 MAY 29
6EOIN IRRADIATION 1015; 0.25 INCH PVREX FILTER
iKONc MONITORED WITH CASIBI 1212 AND MONITOR LABS INSTRUMENTS
TcMPERATURE NOT MONITORED; STANDARD PROCEDURE APPLIED FOR 85 DEG f RUNS
CO FACTOR 2.84/1.325; BECKMAN 6800 USED
PAN CALIB 9 4X1.05)
T«0 AT 1015 POT
CALIB*
PAN
REL HUM
HCHO
REL HUH
SSPOwER
RAOIOM
NO
N02-CORR
CO
HCHO
ACETALO
ACETONE
TOLUENE
3
KW
HM/CNZ
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
AVERAGE
AVERAGE
AVERAGE
INIT COND
INIT COND
INIT CCNO
INIT CCNO
INIT CCND
INIT CCNO
INIT CCNO
* ASSIGNED INITIAL CCNDITIUN
Ki*0.14 MIN-1
SAMPLING RATE = 2.278 L/HIN
57 GC SAMPLES TAKEN
44.44
19.59
0.138
C.C80
0.019
2.120
0.011
0.002
0.005
O.S76
-------
oo
EC - 79
TOLUENE
1975 MAY 29
CLOCK
TIME
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
TIMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
OASIBI
0.0
0.002
0.016
0.041
0.070
0.064
0.094
0.096
0.096
0.092
0.092
0.088
0.088
0.086
0.086
0.082
0.082
0.060
0.080
0.080
0.080
0.078
0.080
0.084
0.080
OiONE
PPM
MONITOR
0.000
0.004
0.017
0.049
0.075
0.089
0.094
0.095
0.091
0.087
0.086
0.061
0.078
0.076
0.075
0.072
0.072
0.069
0.069
C.067
0.066
0.066
0.064
0.062
0.061
NO
PPM
0.080
0.060
0.029
0.015
0.013
0.012
0.013
0.012
0.012
0.011
0.011
0.011
0.012
0.011
0.011
0.012
0.011
0.011
0.011
0.011
0.011
O.U11
0.011
0.011
0.011
N02-CORR
PPM
0.019
0.038
0.063
0.062
0.049
0.038
0.028
0.023
0.019
0.016
0.014
0.014
0.013
0.013
0.013
0.013
0.013
0.013
0.013
0.013
0.013
0.013
0.013
0.014
0.014
NOX-CORR
PPM
0.099
0.098
0.091
0.077
0.062
0.050
0.041
0.035
0.031
0.028
0.026
0.025
0.024
0.025
0.024
0.025
0.025
0.024
0.024
0.024
0.024
0.024
0.024
0.024
0.024
TOLUENE
PPM
0.976
0.960
0.920
0.888
0.848
0.824
0.800
0.792
0.776
0.768
0.754
0.744
0.740
0.728
0.720
0.704
0.696
0.688
0.680
0.672
0.664
0.660
0.656
0.652
0.648
CO
PPM
2.12
2.08
2.05
2.10
2.09
2.12
2.13
2.16
2.15
2.17
2.19
2.19
2.19
2.20
2.21
2.23
2.26
2.27
2.25
2.31
2.29
2.33
2.34
2.33
2.36
PAN
PPM
0.000
******
0.001
******
0.007
******
0.013
******
0.015
******
0.015
******
0.013
******
0.011
******
0.010
******
0.008
******
0.007
******
0.006
******
0.004
HCHO
PPM
0.011
******
******
******
0.013
******
******
******
0.024
******
******
******
0.035
******
******
******
0.042
******
******
******
0.052
******
******
O.OSo
******
ACETALO
PPM
0.0020
******
O.OOiO
******
0.0040
******
0.0050
******
0.0060
******
0.0060
******
0.0020
******
0.0060
******
0.0090
******
0.0090
******
0.0100
******
0.0100
******
0.0100
ACETONE
PPM
0.0050
******
O.OiOu
******
O.UiiU
******
0.0270
******
0.0i70
******
0.0270
******
0.0290
******
0.0290
******
0.0290
******
0.0290
******
0.0 300
******
0.0320
******
0.0340
-------
oo
EC - 79
TOLUENE
1975 HAY 29
CLOCK
TIME
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
REL HUH
S
50.5
50.5
50.5
50.0
49.5
48.5
48.0
47.0
46.5
45.5
45.0
44.5
44.0
43.5
43.0
42.5
42.5
41.5
41.0
40.5
40.0
40.0
39.5
39.0
39.0
SSPOMER
KW
18.70
18.60
******
******
19.70
******
******
******
20.00
******
******
******
19.60
******
******
******
20.10
******
******
******
20.10
******
******
******
19.90
RADICM
MW/CM2
0.135
0.133
******
******
0.138
******
******
******
0.141
******
******
******
0.138
******
******
******
0.140
******
******
******
0.140
******
******
******
0.140
PO #2
VOLTS
0.459
0.435
0.432
0.440
0.440
0.440
0.440
0.442
0.442
0.445
0.437
0.435
0.437
0.435
0.432
0.445
0.440
0.440
0.445
0.440
0.440
0.440
0.440
0.442
0.440
HCHO VOL
L
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
30.00
******
-------
00
OJ
EC - 80
TOLUENE
1975 JUN 2
BEGIN IRRADIATION 1100; 0.25 INCH PVREX FILTER
JiONE MONITORED WITH CASIBI 1070 (CASIoIl AND MONITOR LABS (MONITOR)
INSTRUMENTS. DASIBI 1212 ALSO CN CHAMBER
TEMPERATURE NOT MONITORED? STANDARD PROCEDURE APPLIED FOR 85 DEG F RUNS
CO FACTOR 2.84/1.3736; BECKMAN 6600 USED
PAN CALIB 9 (XI.05)
T«0 AT 1100 POT
CAUB*
PAN
REL HUM
HCHO
REL HUH
SSPOHEft
RADIUM
NO
N02-CGRR
CO
ACETALD
AC ETONE
TOLUENE
*
KM
MW/CM2
PPM
PPM
PPM
PPM
PPN
PPM
9
2
1
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCND
INIT CCNC
INIT CCNO
INIT CCND
INIT CCNO
47.95
20.18
0.140
0.401
O.OS5
2.234
0.001
0.003
1.020
* ASSIGNED INITIAL CONDITION
M=0.14 MIN-l
SAMPLING RATE •= 2.610 L/MIN
56 GC SAMPLES TAKEN
-------
oo
EC - 80
TOLUENE
1975 JUN 2
CLOCK
TIME
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
13*5
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
ELAPSED
T(MIN)
0.
15.
30.
45.
oO.
75.
90.
105.
120.
135.
150.
165.
1«0.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
OZONE
PPM
OAS1BI
******
******
0.010
0.010
0.016
0.021
0.039
0.055
0.078
0.106
0.137
0.168
0.188
0.215
0.238
0.258
0.266
0.272
0.270
0.268
0.258
0.252
0.244
0.238
0.234
0/QNE
PPM
MONITOR
0.000
0.001
0.002
0.004
0.007
0.009
C.C18
0.038
0.062
0.088
0.116
0.149
0.170
C. 195
0.218
0.235
0.243
0.249
0.247
0.242
0.239
0.230
0.223
0.218
0.211
NO
PPM
0.401
0.370
0.326
0.271
0.210
0.154
0.100
0.060
0.039
0.028
0.021
0.016
0.016
0.012
0.012
0.012
0.010
0.010
0.010
0.010
0.010
0.009
0.010
0.010
0.009
N02-CORR
PPM
0.095
0.122
0.157
0.197
0.241
0.273
0.301
0.312
0.298
0.273
0.241
0.201
0.171
0.142
0.116
0.093
0.075
0.059
0.048
0.041
0.032
0.030
0.029
0.030
0.029
NOX-CORR
PPM
0.498
0.493
0.483
0.469
0.452
0.425
0.403
0.372
0.336
0.302
0.259
0.220
0.166
0.155
0.128
0.1 04
0.086
0.069
0.057
0.050
0.043
0.040
0.039
0.038
0.037
TOLUENE
PPM
1.020
0.984
0.960
0.944
0.904
0.864
0.640
0.600
0.768
0.744
0.712
0.680
0.660
0.624
0.60U
0.580
0.560
0.530
0.520
0.504
0.496
0.48U
0.472
0.464
0.456
CO
PPM
2.23
2.26
2.25
2.26
2.27
2.27
2.29
2.32
2.33
2.37.
2.41
2.43
2.43
2.46
2.47
2.50
2.51
2.54
2.54
2.61
2.59
2.61
2.63
2.65
2.66
PAN
PPM
0.000
******
0.000
******
0.002
******
0.005
******
0.011
******
0.020
******
0.028
******
0.036
******
0.043
******
0.046
******
0.047
******
0.042
******
0.036
HCHO
PPM
0.0
******
******
******
0.019
******
******
******
0.035
******
******
******
0.048
*v****
******
******
0.062
******
******
******
0.062
******
******
0.07&
******
ACETALO
PPM
0.0010
******
0.0040
******
0.0040
.******
******
******
0.0060
******
0.0060
******
0.0100
******
0.0110
******
0.0110
******
0.0130
******
0.0130
******
0.0130
******
0.0140
ACETONE
PPM
O.OU30
******
0.0090
******
0.0110
******
******
******
0.0270
******
0.0390
******
0.0620
******
0.0690
******
0.0690
******
0.0750
******
0.0790
******
0.0090
******
0.0690
-------
EC - 80
TOLUENE
1975 JUN 2
oo
CLOCK
TIME
1100
1115
1130
1145
1200
1215
123u
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
ELAPSED
TIM1N)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
, 330.
345.
360.
REL HUH
*
54.0
54.0
53.0
52.5
52.0
51.5
50.5
50.0
49.5
49.0
48.5
47.5
47.0
46.5
46.5
46.0
46.0
45.5
45.5
45.0
44.5
44.0
44.0
43.5
43.5
SSPQMER
KM
18.90
******
******
******
19.90
******
******
******
******
******
******
******
20.40
******
******
******
20.60
******
******
******
20.80
******
******
******
20.50
RACIOM
MW/CM2
0.130
******
******
******
0.138
******
******
******
******
******
******
******
0.140
******
******
******
0.142
******
******
******
0.144
******
******
******
0.144
PO #2
VOLTS
0.474
0.442
0.437
0.435
0.442
0.440
0.435
0.440
0.442
0.440
0.442
0.440
0.440
0.440
0.440
0.437
0.442
0.440
0.442
0.445
0.442
0.437
0.440
0.442
0.442
HCHO VOL
L
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
30.00
******
-------
00
EC - 81
TOLUENE
1975 JUN 4
oEGIN IRRADIATION 1015; 0.25 INCH PYfccX FILTER
OZONE MONITORED WITH DASI3I 1070 AND MONITOR LASS INSTRUMENTS
H202 SAMPLES TAKEN (60 L) AT 1545 TO 1615 HOURS
TELETYPE OFF-LINE FRCM 1502 TO 1622 HOURS
TEMPERATURE NOT MONITORED; STANDARD PROCEDURE APPLIED FOR 85 DEG F RUNS
CO FACTOR 2.84/1.335; BECKMAN 6800 USED
PAN CALIB 9 (XI.051
T«0 AT 1015 POT
CALIB*
PAN
AtL HUM
HCHO
ft EL HUM
SSPQfcER
AAUOM
NO
cm
ACETALD
ACETONE
TOLUENE
S
KM
MH/CM2
PPM
PPM
PPM
PPM
PPM
9
2
1
AVERAGE
AVERAGE
AVERAGE
iNlT CGND
IIMIT CONO
JNIT CCNO
INIT CCND
1NIT CCNO
20.56
0.147
0.4C8
2.031
0.002
0.005
1.960
* ASSIGNED INITIAL CONDITION
M=0.14 MIN-1
SAMPLING RATE * 2.518 L/MIN
60 GC SAMPLES TAKEN
-------
00
EC - 81
TOLUENE
1975 JUN 4
CLOCK
TIME
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
14uO
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
TIMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
22.5.
240.
255.
270.
265.
300.
315.
330.
345.
360.
02CNE
PPM
CASIBI
0.0
0.002
0.008
0.010
0.021
0.051
0.102
0.166
0.219
0.262
0.291
0.307
0.313
0.307
0.301
0.293
0.285
0.277
0.270
0.260
0.252
0.250
0.246
0.236
0.231
OZONE
PPM
MONITOR
C.OOO
0.000
0.002
0.006
0.013
0.038
J.087
0.143
0.191
0.231
0.253
0.265
0.265
0.258
0.248
0.239
0.231
0.225
0.215
0.209
0.199
C.1S3
0.192
0.165
0.160
NO
PPM
0.408
0.368
0.302
0.214
0.122
0.054
0.032
0.022
0.016
0.012
0.011
0.011
O.C10
O.COS
O.CC9
0.010
0.010
0.009
0.010
0.010
0.010
0.010
0.010
0.010
0.009
N02-CORR
PPM
******
0.094
0.092
0.094
0.102
0.113
0.123
0.140
0.163
0.183
0.193
C.230
0.253
0.263
0.288
0.316
0.323
0.333
0.342
0.337
0.324
0.314
0.304
0.284
0.262
NQX-CORR
PPM
******
0.503
0.5 CO
0.502
0.499
U.498
0.495
0.490
0.490
0.484
0.476
0.473
0.466
0.452
0.444
0.440
0.425
0.408
0.399
0.382
0.365
0.346
0.331
0.310
0.264
TOLUENE
PPM
1.960
1.920
1.S60
1.800
1.760
1.680
1.630
1.570
1.500
1.440
1.400
1.330
1.320
1.290
1.250
1.240
1.220
1.180
1.160
1.160
1.140
1.120
1.110
1.110
1.090
CO
PPM
2.03
2.04
2.03
2.03
2.08
2.12
2.14
2.16
2.20
2.21
2.27
2.31
2.35
2.38
1.92
2.37
2.45
2.48
2.49
2.57
2.60
2.59
2.64
2.62
2.67
PAN
PPM
0.000
******
0.001
******
0.004
******
0.016
******
0.031
******
0.045
******
0.054
******
0.060
******
0.052
******
0.046
******
0.043
******
0.035
******
0.032
HCHO
PPM
0.0
******
******
******
0.0
******
******
******
0.027
******
******
******
0.047
******
******
******
0.074
******
******
******
0.081
******
******
******
******
ACETALO
PPM
O.J020
******
0.0030
******
0.0040
******
0.0050
******
0.0070
******
0.0060
******
0.0100
******
0.0120
******
O.JUO
******
0.0130
******
0.0130
******
0.0150
******
u.0170
ACETONE
PPM
0.0050
******
0.0060
******
0.0120
******
0.0250
******
******
******
0.0500
******
0.0610
******
0.0630
******
0.0590
******
0.0530
******
0.0450
******
0.0^70
******
0.0540
-------
oo
oo
EC - 81
TOLUENE
1975 JUN 4
CLOCK
TIME
1015
1030
104S
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
13t5
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
T(MIN!
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
REL HUM
S
48.5
46.0
48.0
47.5
47.0
46.5
46.0
•45.5
45.0
44.5
44.5
44.5
44.0
44.0
44.0
43.5
43.5
43.0
43.0
43.0
42.5
41.5
41.5
41.0
41.0
SSPOnER
KM
19.60
******
20.70
******
20.80
20.60
******
******
20.70
******
******
******
20.80
******
******
******
******
******
******
******
20.50
******
******
******
******
RACIOM
MH/CM2
******
******
0.151
******
0.143
0.148
******
******
0.147
******
******
******
0.146
******
******
******
******
******
******
******
0.144
******
0.148
******
0.146
PD #2
VOLTS
0.464
0.452
0.454
0.452
0.452
0.449
0.449
0.447
0.447
0.442
0.442
0.440
0.445
0.442
0.440
0.440
0.442
0.440
0.442
0.437
0.435
0.437
0.440
0.440
0.442
HCHO VOL
L
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
******
-------
00
VO
EC - 82
TOLUENE
1975 JUN 5
btGIN IRRADIATION 0945; 0.25 INCH PVREX FILTER
OZONE MONITORED WITH .CASIBI 1070 AND MONITOR LABS INSTRUMENTS
TEMPERATURE NOT MONITORED; STANDARD PROCEDURE APPLIED FOR 85 45? 6 RU5S
CO FACTOR 2.84/1.271; 8 EC KM AN 6800 USED
PAN CALIB 9 (XI.05)
T«0 AT 945 POT
CALIB#
PAN
REL HUM
HCHO
REL HUM
SS POWER
RADICM
NO
NG2-CORK
CO
HCHO
ACETALD
AC ETONE
TOLUENE
X
Kri
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
I
AVERAGE
AVERAGE
AVERAGE
INIT CbND
1N1T CCNQ
INIT CCND
INIT CCND
INIT CCND
INIT O3ND
INIT CCND
* ASSIGNED INITIAL CONDITION
Kl=0.14 MIN-1
SAMPLING RATE * 2.267 L/HIN
59 GC SAMPLES TAKEN
41.68
20.12
0.141
0.679
0.337
2.134
0.001
0.002
0. C06
1.880
-------
V£>
O
EC - 82
TOLUENE
1975 JUN 5
CLOCK
TIME
9*5
1000
1015
1030
1045
11 UO
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
TtMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
OASI6I
0.0
0.0
0.0
0.004
0.006
0.008
0.012
0.018
0.021
0.027
0.033
0.045
0.059
0.072
0.096
0.119
0.147
0.168
0.203
0.234
0.270
0.299
0.328
0.354
0.365
OZONE
PPM
MONITOR
0.000
0.002
0.002
0.002
0.002
0.003
0.005
0.007
0.009
0.013
C.019
0.028
C.037
0.052
0.076
0.092
0.124
0.142
0.175
0.211
0.243
0.276
0.306
0.332
0.345
NO
PPM
0.679
0.660
0.630
0.581
0.532
0.474
0.418
0.362
0.308
0.249
0.191
0.147
0.1C7
0.078
0.064
0.049
0.037
0.024
0.022
0.020
0.015
0.015
0.012
0.012
0.012
N02-CORR
PPH
0.337
0.344
0.371
0.392
0.424
0.457
0.486
0.517
0.538
0.566
0.591
0.604
0.607
0.594
0.552
0.524
0.483
0.443
0.395
0.348
0.301
0.254
0.208
0.174
0.141
NOX-CORR
PPM
1.016
1.004
0.994
0.976
0.954
0.929
0.901
0.876
0.846
0.817
0.782
0.753
0.712
0.670
0.616
0.570
0.515
0.467
0.412
0.367
0.313
0.267
0.218
0.186
0.151
TOLUENE
PPM
1.880
1.840
1.820
1.790
1.750
1.700
1.660
1.610
1.560
1.520
1.480
1.450
1.430
******
1.360
1.320
1.280
1.250
1.200
1.160
1.140
1.120
1.080
1.030
0.992
CO
PPM
2.13
2.08
2.06
2.12
2.12
2.12
2.14
2.18
2.23
2.23 •
2.24
2.29
2.28
2.31
2.35
2.41
2.42
2.43
2.49
2.54
2.58
2.60
2.63
2.69
2.74
PAN
PPM
0.000
******
0.000
******
0.002
******
0.003
******
0.004
******
0.007
******
0.011
******
0.017
******
0.025
******
0.032
******
0.044
******
0.053
******
0.059
HCHO
PPM
0.001
******
******
******
0.012
******
******
******
0,027
******
******
******
0.054
******
******
******
0.061
******
******
******
0.081
******
******
0.090
******
ACETALD
^PM
0.0020
******
0.0030
******
0.0040
******
0.0050
******
0.0050
******
0.0070
******
0.0070
******
0.0080
******
O. JU90
******
0.0090
******
0.0110
******
0.0120
******
0.0120
ACETONE
PPM
0.0060
******
0.0070
******
0.0090
******
0.0110
******
0.0120
******
0.0140
******
******
******
0.0290
******
O.OJ70
******
0.0450
******
******
******
0.0610
******
0.0720
-------
EC - 82
TOLUENE
1975 JUN 5
CLOCK.
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
REL HUM
«
48.0
48.5
49.0
49.0
48.5
47.5
47.0
46.5
45.5
45.0
44.5
44.0
43.5
43.0
43.0
42. 5
41.5
41.5
41.0
40.5
40.5
40.0
39.5
39.5
39.0
SSPOWER
KK
19.40
******
19.90
19.90
20.50
******
20.40
20.20
19.80
******
20.10
19.90
20.40
******
20.40
******
20.40
******
20.50
******
20.10
******
20.10
******
19.90
RADICM
HM/CM2
0.137
0.140
0.13S
0.144
0.147
0.143
0.145
0.140
0.137
******
0.137
0.139
0.144
******
0.141
******
0.138
******
0.143
******
C.140
******
0.140
******
0.139
PO #2
VOLTS
******
0.440
0.435
0.442
0.447
0.440
0.440
0.437
0.430
0.432
0.430
0.430
0.435
0.437
0.432
0.432
0.427
0.432
0.432
0.435
0.432
0.427
0.430
0.427
0.427
HCHO VOL
L
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
30.00
******
-------
v£>
EC - 83
TOLUENE
1975 JUN 23
IRRADIATION 1130; 0.25 INCH PYREX FILTER
CHUNE MONITORED WITH CASiai 1070 AND MONITOR LABS INSTRUMENTS
bcNZALDEHYOE ANALYSIS UNCERTAIN BECAUSE OF LARGE INTERFERING BACKGROUND PEAK
BENZALCEHYDE MONITORED USING 3* 10X C-600/C22 COLUMN
RELATIVE HUMIDITY APPRCX. OSt
TEMPERATURE NCT MONITORED; STANDARD PROCEDURE APPLIED FOR 85 DEG F RUNS
PHOTODIODE AT 1730 IS 1725 VALUE
SAMPLE 1715-1730 AT 3 L/MIN; 1625-1724 AT 1.2 L/MIN
CO FACTOR 2.84/1.214! BECKMAN 6800 LSED
T«0 AT 1130 PDT
CALIB#
PAN
REL HUM
HCHO
SSPOhER
RAOIOM
NO
N02-CGRR
ACETALD
ACcTCNE
BZALO
TilLUENe
Kte
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
AVERAGE
AVERAGE
INIT CCNO
INIT CCNO
INIT CCNO
INIT CONO
INIT CCNO
INIT CCNO
20.37
0.139
1.363
0.664
0.001
C.C03
0.016
5.630
* ASSIGNfO INITIAL CONDITION
M=0.14 MIN-1
SAMPLING RATE » 2.4C4 L/MIN
57 GC SAMPLES TAKEN
-------
VO
Co
EC - 83
TOLUENE
1975 JUN 23
CLOCK
TIME
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
ELAPSED
T(HIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
213.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
DASIB1
0.0
0.000
0.000
0.000
0.006
0.006
0.010
0.016
0.022
0.027
0.029
0.037
0.041
0.053
0.055
0.066
0.076
0.088
0.111
0.143
0.182
0.233
0.295
0.362
0.418
liZONE
PPM
MONITOR
0.000
0.000
0.000
0.001
0.001
0.001
0.001
0.001
0.002
0.004
0.004
0.005
0.006
0.008
0.013
0.019
0.025
0.035
0.059
0.081
0.125
0.167
0.228
0.289
0.351
NO
PPM
1.363
1.334
1.304
1.2oO
1.216
1.158
1.094
1.016
0.928
0.845
0.762
0.674
0.576
0.479
0.38o
0.30J
0.225
0.161
0.1C7
0.073
0.049
0.029
0.029
0.024
0.015
NQ2-CQRR
PPM
0.664
0.674
0.693
0.717
0.736
0.779
0.818
0.862
0.930
0.983
1.031
1.096
1.151
1.218
1.270
1.322
1.349
1.367
1.370
1.339
1.293
1.249
1.186
1.120
1.059
NOX-CORR
PPM
2.017
2.003
1.993
1.977
1.952
1.937
1.908
1.888
1.858
1.828
1.793
1.768
1.733
I.o92
1.661
1.624
1.579
1.523
1.473
1.412
1.347
1.279
1.211
1.140
1.078
TOLUENE
PPM
5.630
5.630
5.630
5.600
5.570
5.440
5.440
5.310
5.250
5.060
5.020
4.960
4.860
4.740
4.610
4.540
4.480
4.330
4.290
4.160
4.130
4.030
3.970
3.840
3.680
CO
PPM
******
0.22
0.21
0.23
0.27
0.27
0.33
0.27
0.43
0.42 .
0.45
0.31
0.51
0.59
0.59
0.61
0.69
0.70
0.75
0.80
0.66
0.95
1.01
1.11
1.18
PAN
PPM
0.000
******
0.000
******
0.002
******
0.002
******
0.003
******
0.005
******
0.007
******
0.010
******
0.014
******
0.027
******
0.041
******
0.050
******
0.065
HCHO
PPM
0.0
******
******
******
0.0
******
******
******
0.007
******
******
******
0.038
******
******
******
O.OoO
******
******
******
******
******
******
******
******
ACETALO
PPM
0.0010
******
0.0010
******
0.0010
******
0.0020
******
0.0010
******
o.oo^o
******
******
******
0.0030
******
0.0040
******
0.0040
******
0.0050
******
0.0060
******
0.0060
ACETONE
PPM
0.0030
******
0.0050
******
O.Ou7J
******
0.0070
******
O.CU70
******
0.0090
******
******
******
0.0110
******
0.0i30
******
0.0160
******
0.0200
******
0.0240
******
0.0280
ttZALD
PPM
O.Olo
******
0.022
******
0.025
******
0.04C
******
O.G36
******
0.060
******
0.060
******
0.056
******
0.062
******
O.C6O
******
0.072
******
0.083
******
0.082
-------
VD
EC - 83
TOLUENE
1975 JUN 23
CLOCK
TIME
1130
1145
1200
1215
U30
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1550
1545
1600
1615
1630
1645
1700
1715
1730
ELAPSED
TIMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
SSPOHER
Kh
20.20
20.30
******
******
******
******
******
******
20.20
******
******
******
******
******
******
******
******
******
******
******
******
******
******
20.90
******
RAOICM
MW/CM2
0.136
0.137
******
******
******
******
******
******
0.138
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.144
******
PO *2
VOLTS
0.452
0.432
0.427
0.427
0.425
0.423
0.425
0.430
0.430
0.427
0.425
0.423
0.427
0.427
0.427
0.427
0.425
0.432
0.432
0.430
0.430
0.435
0.437
0.432
0.432
HCHO VOL
L
25.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
******
******
******
******
******
-------
Ui
EC - 84
TOLUENE
1975 JUN 25
BEGIN IRRADIATION 1045; C.25 INCH PYREA FILTER
OZONE MONITORED WITH CASIBI 1070 AND MONITOR LABS INSTRUMENTS
BENZALDEHYDE ANALYSIS UNCERTAIN BECAUSE OF LARGE INTERFERING BACKGROUND PEAK
BENiALCEhYOE MONITORED USING 3' 10* C-600/C22 COLUMN
TEMPERATURE NOT MONITORED! STANDARD POOCECURE APPLIED FOR 85 DEC F RUNS
CO FACTOR 2.84/1.214; BECKMAN 6800 USED
T=0 AT 1045 POT
CALIB*
PAN
REL HUH
HCHO
REL HUH
SS POWER
RAOIOM
NO
NC2-CORR
MCHO
ACETALO
BZALD
TOLUENE
*
KM
HW/CH2
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCND
INIT CCNO
INIT CCNO
INIT CONO
INIT CCNO
74.91
19.84
0.137
0.388
o.oeo
O.C07
0.005
0.032
0.968
* ASSIGNED INITIAL CONDITION
K1-0.14 MIN-1
SAMPLING RATE = 2.459 L/MIN
57 GC SAMPLES TAKEN
-------
vo
EC - 84
TOLUENE
1975 JUN 25
CLOCK
TIME
1045
1100
1115
1130
1145
I2co
1215
1230
12H5
1300
1315
1330
1345
1400
1415
14.JO
1445
1500
1515
1530
1545
loOO
1615
1630
1645
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
CAS I BJ
0.000
0.000
0.000
0.002
0.006
0.006
O.OCB
0.016
0.022
0.029
0.041
0.053
0.068
0.082
0.102
0.113
0.129
0.147
0.162
0.174
0.190
0.201
0.215
0.227
0.233
OZONE
PPM
MONITOR
0.000
0.002
0.002
0.002
0.004
0.006
C.009
0.013
0.019
0.023
0.034
0.045
0.066
C.073
0.095
C.1C8
0.126
0.140
0.155
0.172
C.166
0.200
0.217
0.228
0.235
NO
PPM
0.388
0.371
0.344
0.310
0.271
0.234
0.195
0.149
0.110
O.C88
0.066
0.049
0.039
0.029
0.027
0.022
0.020
0.020
0.017
0.012
0.012
0.012
0.012
0.010
0.010
N02-CORR
PPM
0.060
0.097
0.119
0.143
0.169
0.195
0.222
0.250
0.263
0.273
0.273
0.261
0.251
0.239
0.218
0.2CO
0.177
0.160
0.141
0.127
0.110
0.094
0.079
0.068
0.058
NOX-CORR
PPM
0.469
0.463
0.460
0.450
0.440
0.430
0.415
0.399
0.3U1
0.359
0.337
0.312
0.290
0.266
0.245
0.222
0.196
0.180
0.156
0.139
0.122
0.109
0.088
0.075
0.067
TOLUENE
PPM
0.968
0.944
0.944
0.920
0.88J
0.672
0.832
0.808
0.784
0.760
0.740
0.720
0.696
0.672
0.656
0.640
0.608
0.600
0.576
0.552
0.528
0.520
0.496
0.480
0.460
CO
PPM
******
2.04
2.05
2.07
2.09
2.07
2.08
2.06
2.12
2.11-
2.13
2.16
2.17
2.15
2.21
2.21
2.20
2.26
2.27
2.28
2.32
2.29
2.35
2.37
2.40
PAN
PPM
0.000
******
0.001
******
0.002
******
0.003
******
0.005
******
0.010
******
0.015
******
0.019
******
0.026
******
0.030
******
0.034
******
0.041
******
0.043
HCHO
PPM
0.007
******
******
******
0.016
******
******
******
0.034
******
******
******
0.040
******
******
******
0.047
******
******
******
0.054
******
******
******
******
ACETALO
PPM
0.0050
******
0.0040
******
O.OO60
******
0.0080
******
O.OObO
******
0.0070
******
0.0060
******
0.0080
******
0.0080
******
0.0090
******
0.0090
******
0.0110
******
0.0100
ACETONE
PPM
******
******
0.0140
******
0.0160
******
O.Gilo
******
0.0170
******
0.0220
******
0.0260
******
0.0270
******
******
******
0.0340
******
0.0340
******
0.04uO
******
0.040C
8ZALO
PPM
0.032
******
0.040
******
0.022
******
0.028
******
0.025
****<••*
0.022
******
0.020
******
0.025
*****v
0.022
******
0.02C
******
0.016
******
0.010
******
0.015
-------
EC - 84
TOLUENE
1975 JUN 25
CLOCK
TIME
1045
1100
1115
1130
11*5
1200
1215
1230
1245
1300
1315
1330
1345
14GO
1415
1430
1443
1500
1515
1530
1545
loQO
1615
1630
1645
ELAPSED
TiMINI
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
1S5.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
REL HUM
*
92.5
92.0
87.5
85.0
84.0
83.5
83.0
82.5
82.0
tiO.5
79.5
79.0
78.0
77.5
75.5
75.5
74.5
73.0
72.0
68.5
64.5
60.5
57.0
54.0
51.5
SSPONER
KM
19.50
******
******
******
20.00
******
******
******
19.60
******
******
19.70
******
******
******
******
******
******
******
******
******
******
******
******
20.20
RACIOM
MM/CM2
0.135
******
******
******
0.137
******
******
******
0.136
******
*«*#**
0.137
******
******
******
******
******
******
******
******
******
******
******
******
0.138
PO #2
VOLTS
0.296
0.427
0.430
0.430
0.427
0.430
0.425
0.432
0.427
0.430
0.425
0.427
0.425
0.427
0.423
0.425
0.425
0.425
0.425
0.423
0.423
0.435
0.425
0.423
0.423
HCHO VOL
L
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
******
-------
VO
oo
EC - 85
TOLUENE
1975 JUN 26
BEGIN IRRADIATION 1000; 0.25 INCH PYRtX FILTER
OZONE MONITORED WITH CASIBI 1070 AND MCN1TOR LABS INSTRUMENTS
BENZALOEriYDE ANALYSIS UNCERTAIN bcCAUSfc OF LARGE INTERFERING BACKGROUND PEAK
BENZALDEHYOE MONITORED USING 3' 10* C-600/C22 COLUMN
TEMPERATURE NOT MONITORED; STANDARD PROCEDURE APPLIED FOR 85 OEG F RUNS
CO FACTOR 2.84/1.185! BECKMAN 6800 LSEO
T«0 AT 1000 POT
CAUB*
PAN
REL HUM
HCHO
REL HUM
SS POWER
RADIOM
NO
N02-CORR
CO
ACETALD
ACETONc
6ZALO
TOLUENE
*
KM
MK/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
I
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
1NIT CQND
INIT CCNO
INIT CCND
INIT CCNO
INIT COND
INIT CQNO
* ASSIGNED INITIAL CONDITION
K1-0.-14 MIN-1
SAMPLING RATE * 2.266 L/MIN
57 GC SAMPLES TAKEN
40.90
2C.20
0.138
C.431
0.092
2.067
0.004
0.010
0.005
1.920
-------
vO
£C - 85
TOLUENE
1975 JUN 26
CLOCK ELAPSED
TIME
1000
1015
1050
1045
1100
1115
1150
1145
1200
1215
1230
li-tS
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
DASI61
0.000
0.000
0.000
0.002
0.006
0.010
0.014
0.022
0.045
0.086
0.125
0.162
0.201
0.242
0.274
0.291
0.293
0.291
0.291
0.285
0.278
0.274
0.268
0.262
0.256
OZONE
PPN
MCNITOR
0.000
0.001
0.001
C.002
O.OQ4
0.006
0.009
0.020
0.044
0.081
0.123
0.164
0.207
0.241
0.267
C.263
0.288
0.285
0.279
0.272
0.265
0.258
0.253
0.243
0.239
NO N02-CORR NOX-CORR
PPM
0.431
0.410
0.379
0.331
0.280
0.217
0.140
0.081
0.039
0.026
0.017
0.015
0.013
0.011
0.011
0.010
0.010
0.010
0.010
C.010
0.009
0.009
0.009
C.009
0.009
PPM
0.092
C.108
0.136
0.176
0.217
0.260
0.316
0.347
0.348
0.322
0.274
0.231
0.193
0.153
0.120
0.093
0.072
0.062
0.052
0.050
0.049
0.04d
0.047
0.046
0.044
PPM
0.522
0.520
0.515
0.508
0.494
0.476
0.456
0.428
0.388
0.347
0.291
0.246
0.2G5
0.165
0.130
0.102
0.080
0.068
0.060
0.057
0.056
0.055
0.055
0.053
0.052
TOLUENE
PPM
1.920
1.910
1.900
1.860
1.790
1.770
1.700
1.640
1.610
1.560
1.510
1.450
1.390
1.340
1.310
1.280
1.230
1.200
1.160
1.150
1.120
1.110
1.090
1.060
1.040
CO
PPM
2.07
2.10
2.09
2.11
2.14
2.15
2.15
:.ie
2.20
2.24 ,
2.29
2.31
2.35
2.37
2.43
2.45
2.51
2.52
2.55
2.59
2.61
2.66
2.65
2.70
2.72
PAN
PPM
0.000
******
0.000
******
0.002
******
0.004
******
0.020
******
0.030
******
0.030
******
0.041
******
0.049
******
0.050
******
0.044
******
0.037
******
0.032
HCHO
PPM
0.0
******
******
******
O.OOb
******
******
******
0.016
******
******
******
0.034
******
******
******
0.054
******
******
******
0.074
******
******
0.081
******
ACETALD
PPM
0.0040
******
0.0050
******
o.OOjQ
******
0.0050
******
0.0060
******
0.0070
******
0.0070
******
O.OOoO
******
0.0090
******
0.0110
******
0.0120
******
0.0120
******
0.0130
ACETONE
PPM
0.0100
******
******
******
0.0090
******
0.0100
******
0.0i70
******
0.0220
*v****
0.0270
******
O.C540
******
0.0^40
******
O.OJ70
******
0.0560
******
0.0360
******
0.0350
.BZALO
PPM
0.005
******
0.007
******
0.007
******
0.010
******
0.018
******
0.016
******
0.020
******
0.023
******
0.023
******
0.020
******
c.o^o
******
0.020
******
0.020
-------
I-
o
o
EC - 85
TOLUENE
1975 JUN 26
CLOCK
HKE
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
ELAPSED
TCMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
REL HUH
I
45.0
44.5
44.0
44.0
44.0
43.5
43.5
43.0
43.0
42.5
41.5
41.5
41.0
40.5
40.0
40.0
39.5
39.0
38.5
38.0
38.0
37.5
37.0
36.5
36.5
SSPOHER
KW
19.60
******
******
******
******
******
******
******
20.00
******
******
******
******
******
******
******
20.20
******
******
******
******
20.50
******
******
20.50
RAD1CH
MH/CH2
0.140
******
******
******
******
******
******
******
0.137
******
******
******
******
******
******
******
0.136
******
******
******
******
0.138
******
******
0.138
PO *2
VOLTS
******
0.432
0.427
0.427
0.423
0.423
0.423
0.423
0.425
0.423
0.423
0.423
0.423
0.418
0.425
0.427
0.420
0.418
0.415
0.415
0.415
0.423
0.425
0.423
0.427
HCHO VOL
L
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
30.00
******
-------
EC - 86
TOLUENE * FORMALDEHYDE
1975 JUL 2
BEGIN IRRADIATION 1230; 0.25 INCH PYREX FILTER
SUPPLEMENTAL NC2 INJECTION AT 12Z8
OZONE MONITORED hlTH CASIBI 1070 AND NCNITOR LABS INSTRUMENTS
BENZALOEHYDE ANALYSIS UNCERTAIN BECAUSE Of LARGE INTERFERING BACKGROUND PEAK
6ENZALOEHYCE MCNITQREO USING 3' 10* C-600/C22 COLUMN
TEMPERATURE NCT MONITORED; STANDARD PROCEDURE APPLIED FOR 85 DEC F RUNS
CO FACTOR 2.84/1.18; BECKMAN 6800 USED
T-0 AT 1230 POT
CALIB*
PAN
REL HUM
HCHO
REL HUM
SSPQrfER
RAOIOM
NO
N02-CQRR
HCHO
ACETALO
TOLUENE
CO
%
KW
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
AVERAGE
AVERAGE
AVERAGE
INIT COND
INIT CCNO
INIT CCND
INIT CCNO
INIT COND
INIT CCNO
35.67
2C.45
C.138
0.407
0.081
0.161
0.001
1.090
2.134
* -ASSIGNED INITIAL CONDITION
KU0.14 MIN-1
SAMPLING RATE = 2.810 L/MIN
57 GC SAMPLES TAKEN
-------
EC - 86
TOLUENE * FCRHALOEHtCE
1975 JUL 2
I-1
O
to
CLOCK
TIME
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
1600
1815
1830
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
OASIBI
******
******
******
0.002
0.002
0.004
0.006
0.016
0.020
0.035
0.059
0.090
0.115
0.141
0.168
0.191
0.219
0.242
0.262
0.279
0.289
0.293
0.299
0.289
0.285
OZONE
PPM
MONITOR
******
******
******
0.003
0.004
0.005
C.008
0.012
0.024
0.044
0.067
0.095
0.126
0.152
0.181
0. 2C8
0.239
0.264
0.286
0.303
C.312
0.317
0.318
0.307
0.299
NO
PPM
******
******
******
0.303
0.255
0.200
0.143
0.096
O.C61
0.036
0.028
0.023
0.017
0.013
0.011
0.011
0.010
0.009
0.009
O.OC7
0.007
O.CQ7
0. OC7
0.006
0.006
N02-CORR
PPM
******
******
******
0.181
0.216
0.253
0.295
0.322
0.336
0.333
0.313
0.288
0.261
0.232
0.204
0.179
0.154
0.132
0.109
0.093
0.079
0.066
0.059
0.053
0.049
NOX-CORR
PPM
******
******
******
0.484
0.473
0.455
0.438
0.419
0.396
0.372
0.338
0.310
0.277
0.247
0.219
0.168
0.163
0.139
0.118
0.100
0.065
0.076
0.065
0.059
0.054
TOLUENE
PPM
1.090
1.080
1.080
1.040
1.010
0.992
0.9t>0
0.944
0.912
******
0.848
0.632
0.792
0.768
0.756
0.720
0.688
0.672
0.640
0.614
0.600
0.580
0.568
0.544
0.528
HCHO
PPM
0.161
******
******
******
0.134
******
******
******
0.114
****** .
******
******
0.110
******
******
******
0.109
******
******
******
0.096
******
******
0.105
******
CO
PPM
******
******
******
2.13
2.14
2.13
2.18
2.20
2.22
2.25
2.29
2.33
2.36
2.38
2.38
2.42
2.45
2.49
2.50
2.58
2.60
2.65
2.65
2.70
2.62
PAN
PPM
0.000
******
0.000
******
0.001
******
O.U03
******
0.005
******
0.011
******
0.015
******
0.021
******
0.028
******
0.034
******
O.U37
******
0.037
******
0.03?
ACETALD
PPM
O.U010
******
0.0030
******
0.0030
******
0.0040
******
O.OU50
******
******
******
0.0060
******
0.0100
******
0.0090
******
0.0100
******
0.0030
******
0.0060
******
U.0100
ACETONE
PPM
******
******
0.0000
******
0.0070
******
0.0100
******
******
******
******
******
0.0200
******
0.0270
******
0.0260
******
0.0290
******
0.0270
******
0.0.320
******
0.0270
6ZALD
PPM
0.0
******
0.0
******
0.002
******
0.002
******
O.J10
******
0.010
******
0.011
******
0.011
******
0.012
*****«•
0.02G
******
0.010
******
0.010
******
0.010
-------
EC - 86
TOLUENE * FORMALDEHYDE
1975 JUL 2
O
U)
CLOCK
TIME
U3d
U45
1300
U15
1330
1345
1400
1415
1430
1445
15CO
1515
1530
1545
1600
1615
1630
lt>45
1700
1715
1730
1745
1600
1815
1830
ELAPSEC
TIMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
REL HUM
*
******
******
******
38.0
38.0
38.0
38.0
37.5
37.5
37.0
36.5
36.0
36.0
3S.5
35.0
35.0
34.5
34.0
34.0
33.5
33.0
33.0
32.5
32.5
32.0
SSPOhER
KW
20.50
******
******
******
20.30
******
******
******
20.00
******
******
****#*
20.20
******
******
******
20.10
******
21.00
******
20.70
******
20.60
******
******
RACKM
MW/CM2
0.140
******
******
******
0.137
******
******
******
0.135
******
******
******
0.134
******
******
******
0.131
******
0.142
******
0.139
******
0.143
******
******
PD #2
VOLTS
******
******
******
0.430
0.425
0.423
0.423
0.415
0.413
0.420
0.415
0.418
0.418
0.420
0.418
0.418
0.415
0.430
0.430
0.425
0.427
0.427
0.430
0.432
0.430
HCHO VOL
L
20.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
30.00
******
-------
EC - 95
PROPENE
1975 SEP 29
BEGIN IRRADIATION 11155 0.25 INCH PYREX FILTER
RADIOMETER IN SNITCH POSITION 3
NJX FACTOR 0.9 TO CORRECT TECO RXN CHAMBER FROH 23.0 TO 22.0
CO FACTOR 2.64/1.21; 6ECKMAN 6800 USED
T«0 AT 1115 POT
CALIB#
PAN
REL HUM
HCHO
TS
REL HUM
SSPG*ER
RAOIOM
H20
NO
N02-CORR
CO
HCHQ
ACETALD
ACETONE
PROPENE
DEC K
1
Kh
MM/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
I NIT CONO
INIT CCNO
INIT COND
INIT CONO
INIT CCND
INIT CCNO
INIT CQND
* ASSIGNED INITIAL CONDITION
Kl*0.35 MIN-1
SAMPLING RATE * 1.820 L/MIN
54 GC SAMPLES TAKEN
303.5
60.18
11.9?
0.305
2.599E 04
0.365
0.092
2.012
0.010
O.C05
0.008
0.504
-------
o
Ul
EC - 95
PROPENE
19T5 SEP 29
CLOCK
TIME
1115
1130
11*5
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
163U
1645
1700
1715
ELAPSED
TtfUNl
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
lao.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OiGNE
PPM
0.0
0.0
0.025
0.063
0.119
0.156
0.197
0.236
0.272
0.301
0.324
0.346
0.369
0.391
0.406
0.418
0.422
0.430
0.432
0.430
0.420
0.414
0.410
0.406
0.403
NO
PPM
0.365
0.203
0.104
0.055
0.036
0.025
0.021
0.016
0.012
0.011
0.009
0.009
0.007
0.007
0.005
0.004
0.004
O.CC4
0.004
0.004
0.004
0.004
0.004
0.004
0.003
N02-CORR
PPM
0.092
0.223
0.302
0.321
0.315
0.301
0.284
0.248
0.216
0.165
0.156
0.13i
0.109
0.087
O.Oott
0.058
0.046
0.039
0.036
0.029
0.023
0.020
0.017
0.016
0.016
NOX-CORR
PPM
0.456
0.437
0.406
0.378
0.351
0.328
0.302
0.265
0.22S
0.193
0.165
0.140
0.114
0.092
0.072
0.063
0.050
0.044
0.03d
0.032
0.026
0.024
0.019
0.019
0.021
PROPENE
PPM
0.504
0.414
0.340
0.290
0.244
0.210
0.170
0.140
0.116
0.096
0.074
0.064
0.052
0.040
0.031
0.025
0.020
0.016
0.013
0.010
0.009
0.007
0.006
0.005
0.004
CO
PPM
2.01
2.01
2.06
2.06
2.10
2.17
2.27
2.37
2.40
2.42
2.53
2.53
2.64
2.75
2.76
2.77
2.79
2.92
2.94
2.99
3.05
3.03
3.05
3.25
3.18
PAN
PPM
0.000
******
0.009
******
0.029
******
0.037
******
0.074
******.
0.100
******
0.122
******
0.141
******
0.147
******
******
******
0.158
******
0.158
******
0.153
HCHO
PP«
0.010
******
******
******
0.222
******
******
******
0.282
******
******
******
0.291
******
******
******
******
0.250
******
******
0.228
******
******
0.215
******
ACETALO
PPM
0.005
******
******
******
0.141
******
0.155
******
0.165
******
0.157
******
0.139
******
0.123
******
0.127
******
0.108
******
0.098
******
0.075
******
0.077
PROPALG
PPM
0.0003
******
0.0003
.******
0.0018
******
0.0026
******
0.0030
******
0.0035
******
0.0039
******
0.0040
******
0.0047
******
0.0041
******
0.0040
******
0.0030
******
0.0039
ACETONE
PPM
0.0080
******
0.0110
******
0.0160
******
0.0210
******
0.0230
******
O.Oi&U
******
0.0t90
******
0.0320
******
0.0390
******
0.0360
******
0.0360
******
0.0470
******
0.04011
PROX
PPM
0.0
******
0.0002
******
0.0004
******
0.0006
******
******
******
0.0006
******
0.0005
******
0.0009
******
0.0010
******
0.0012
******
0.0012
******
0.0012
******
0.0012
NE-N
PPM
0.0
******
0.0
******
O.Q003
******
0.0006
******
0.0008
******
O.OJ10
******
0.0011
******
0.0011
******
0.0011
******
0.0011
******
O.uUil
******
0.0011
******
0.0011
-------
EC - 95
PROPENE
1975 SEP 29
CLOCK
TIME
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
ELAPSED
TtMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
t40.
255.
270.
265.
300.
315.
330.
345.
360.
TS
DEC F
67.2
69.2
67.2
87.4
66.5
66.7
66.5
66.5
67.0
66.2
66.0
66.7
86.7
67.0
87.2
67.2
86.7
67.0
67.2
67.0
87.2
87.9
86.7
67.2
87.7
REL HUH
*
50.0
49.5
50.5
53.0
56.5
60.0
61.5
63.0
04.0
64.0
65.0
65.5
65.5
65.5
65.0
64.5
65.5
o5.Q
64.5
64.5
64.5
64.0
63.5
64.0
63.5
SSPOWER
KW
******
11.70
11. eu
11.90
11.80
12.00
ik*****
******
******
******
******
******
11.80
******
******
******
******
12.10
******
******
12.10
******
12.20
******
12.30
RADIOM
MW/CH2
0.351
0.290
0.300
0.296
0.305
******
******
******
******
******
******
******
0.298
******
******
******
******
0.301
******
******
0.301
******
0.305
******
0.308
HCHO VOL
L
20.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
******
30.00
******
******
30.00
******
******
30.00
******
-------
EC - 96
PROPENE
1975 SEP 30
BEGIN IRK ADI AT I ON 1000; 0.25 INCH PVREX FILTER
RADIOMETER IN StalTCH POSITION 2
NUX FACTOR 0.8^ TO CORRECT TECO RXN CHAM6ER FROM 23.7 TO 22.0
CO FACTOR 2.84/1.£1; BECKHAN 6800 USED
T=0 AT 1000 POT
CALIBD
PAN
REL HUM
HCHO
TS
REL HUM
SS POWER
RADIOM
H20
NO
N02-CGRR
HCHO
ACETALD
ACeTQNE
PROPENE
DEG K
%
KM
MW/CM2
PPM
PPH
PPM
PPM
PPM
PPM
PPM
9
2
1
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CQND
1NIT CQND
INIT CCNO
JNIT CCNO
INIT CONO
INIT CONO
* ASSIGNED INITIAL CONDITION
M=0.35 MIN-1
SAMPLING RATE = 1.723 L/MIN
54 GC SAMPLES TAKEN
303.2
69.49
12.00
0.342
2.9C7E 04
0.349
0.090
0.020
0.002
0.004
0.500
-------
o
00
EC - 96
PROPENE
1975 SEP 30
CLOCK
TIME
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
loOO
ELAPSED
TIM1NJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
1BO.
±95.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.0
0.0
0.002
0.016
0.041
0.078
0.117
0.158
0.193
0.223
0.254
0.281
0.307
0.328
0.350
0.371
0.387
0.401
0.410
0.420
0.422
0.420
0.422
0.416
0.412
NO
PPM
0.349
0.279
0.194
0.122
0.071
0.049
0.034
0.026
0.021
0.017
0.013
0.012
0.010
0.009
0.008
0.007
0.006
C.006
0.005
0.005
0.005
0.005
0.004
0.004
0.066
N02-CORR
PPM
0.090
0.151
0.222
0.274
0.302
0.301
0.283
0.268
0.248
0.224
0.201
0.175
0.153
0.125
0.101
0.082
0.065
0.046
O.C26
0.016
0.005
0.0
0.0
0.0
0.0
NOX-CORR
PPM
0.438
0.429
0.415
0.396
0.373
0.350
0.322
0.295
0.268
0.242
0.214
0.187
0.163
0.134
0.109
0.069
0.071
0.051
0.030
0.021
0.009
0.003
0.0
0.0
0.0
PROPENE
PPM
0.500
0.450
0.396
0.344
0.306
0.272
0.232
0.200
0.170
0.140
0.120
0.096
0.080
0.070
0.054
0.043
0.034
0.024
0.023
0.018
0.014
0.012
0.010
0.008
0.006
CO
PPM
******
1.93
1.97
2.06
2.09
2.17
2.10
2.16
2.20
2.22
2.31
2.55
2.52
2.44
2.53
2.55
2.70
2.69
2.75
2.79
2.81
2.87
2.82
2.95
2.94
PAN
PPM
0.000
******
0.002
******
0.013
******
0.029
******
0.048
******
0.067
******
0.088
******
0.110
******
0.127
******
0.149
******
0.160
******
0.167
******
0.162
HCHd
PPM
0.020
******
******
******
0.161
******
******
******
0.211
******
******
******
0.262
******
******
******
0.222
******
******
******
0.220
******
******
0.232
******
ACETALO
PPM
0.002
******
0.05.1
******
0.107
******
0.123
******
0.150
******
0.157
******
0.130
******
0.122
******
0.136
******
0.109
******
0.106
******
0.097
******
0.066
PAOPALD
PPM
0.0002
******
0.0004
******
0.0011
******
U.0017
******
0.0022
******
0.0027
******
0.0027
******
0.0020
******
0.0036
******
0.0035
******
0.0037
******
0.0036
******
0.0035
ACETONE
PPM
0.0040
******
0.0040
******
0.0080
******
0.0100
******
0.0150
******
0.0190
******
0.0210
******
0.0360
******
0.0310
******
0.0340
******
0.0390
******
0.0320
******
0.0320
PROX
PPM
0.0
******
0.0002
******
0.0006
******
c.ooos
******
0.0007
******
0.0010
******
0.0012
******
******
******
0.0014
******
0.00 3
***».»*
******
******
0.0015
******
0.0016
KE-N
Pf-M
******
******
******
******
******
******
******
******
******
******
O.OC06
******
C.0006
******
0.0011
******
0.0011
******
O.OOOd
******
0.0011
******
0. 0003
******
0.0011
-------
EC - 96
PROPENE
1V75 SEP 30
Ci.uCK
TIME
1000
1015
1030
1045
1100
1115
1130
1145
1200
U15
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
> 330.
345.
360.
TS
OEG F
87.0
88.4
67.0
87.2
66.2
85.7
86.0
85.7
85.2
85.5
85.5
65.5
85.7
85.2
85.2
85.5
86.0
86. 0
86.5
85.5
65.5
86.2
67.0
86.7
66.0
REL HUH
X
58.5
57.5
58.5
60.5
63.0
67.0
68.5
70.0
72.0
73.0
73.5
72.5
72.5
73.5
73.0
73.5
73.5
73.0
72.0
72.0
73.0
72.0
71.0
71.0
70.0
SSPOMER
KW
12.80
******
******
******
******
******
11.60
******
11.80
******
******
******
11.80
******
******
******
****«,*
******
******
******
12.00
******
******
******
12.00
RADIOrt
MW/CM2
0.373
******
******
******
******
******
0.332
******
0.334
******
******
******
0.333
******
******
******
******
******
******
******
0.338
******
******
******
******
HCHO VOL
I
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
20.00
******
-------
EC - 97
PRDPENE » BUTANE
1975 OCT 1
BEGIN IRRADIATION 1015; 0.25 INCH PVREX FILTER
6-HOUR CONC (PPBJ; C2-Nt 1.6; C3-NI. 1.4; C4-Nli 2.5» (FROM OXYGENATE COLUMN)
OZONE FACTOR 0.8
CO FACTOR 2.84/1.21; BECKHAN 6800 USED
T«0 AT 1030 POT
CAL1Q*
PAN
REL HUH
HCHO
TS
REL HUH
SSPOWER
RADIOM
H20
NO
N02-CORR
PROPENE
N-C4
CO
HCHO
ACETALD
ACETONE
OEG K
*
KM
MW/CM2
PPM
PPM
PPH
PPH
PPM
PPM
PPM
PPM
PPM
9
2
1
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CONO
INIT COND
INIT CONO
INIT CONO
INIT CONO
INIT COND
INIT CGNO
INIT CONO
ASSIGNED INITIAL CONDITION
Kl'0.35 HIN-1
SAMPLING RATE
303.3
70.58
12.22
0.337
2.981E 04
0.397
0.088
0.500
2.040
1.820
0.004
0.001
0.002
1.562 L/MIN
54 GC SAMPLES TAKEN
-------
EC - 97
PROPENE » BUTANE
19T5 OCT 1
CLOCK
TIME
1030
1045
1.10 j
1115
1130
1145
1200
1215
1230
1245
UOO
131s
1330
1345
1400
1413
1433
1445
1500
1515
1530
1545
1600
1615
1630
ELAPSED
TtN(N)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
ISO.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC f
85.0
86.7
85.5
85.5
85.2
85.5
85.7
85.5
86.0
86.2
85.5
85.5
66.2
86.5
87.2
86.0
87.0
86.2
87.0
87.0
87.4
87.9
86.2
66.5
87.2
REL HUH
?
54.0
54.0
60.0
67.5
71.0
74.0
73.5
72.5
74. J
74.0
74.0
74.5
74.5
73.5
72.5
72.0
73.5
72.0
71.5
72.0
72.0
70.5
70.5
72.5
71.0
SSPOHER
KM
12.00
******
******
******
12.10
******
******
******
******
******
******
******
12.30
******
******
******
12.30
******
******
******
******
******
******
******
12.40
RAD1QM
MH/CM2
0.333
******
******
******
0.334
******
******
******
******
******
******
******
0.338
******
******
******
0.338
******
******
******
******
******
******
******
0.340
riCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
20.00
******
-------
EC - 97
t»ROPENE t BUTANE
1975 OCT 1
N>
CLOCK
TIME
1030
1045
1100
1115
1130
1145
1200
1215
U30
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
ELAPSED
TIMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OiONE
PPM
o.o
0.0
0.006
0.025
0.064
0.125
0.193
0.260
0.315
0.379
0.420
0.465
0.502
0.533
0.555
0.571
0.578
0.574
0.571
0.563
0.557
0.547
0.539
0.530
0.524
NO
PPM
0.397
0.319
0.216
0.118
0.067
0.044
0.031
0.023
0.020
0.017
0.015
0.015
0.012
0.012
0.011
0.011
o.an
0.011
0.010
0.010
0.010
0.010
0.010
0.009
0.009
N32-CORR
PPM
o.osa
0.157
0.242
0.325
0.355
0.348
0.325
0.290
0.252
0.224
0.193
0.155
0.117
0.088
0.062
0.041
0.024
0.018
0.015
0.007
0.000
0.002
0.003
0.002
0.000
NOX-CORR
PPM
0.483
0.474
0.460
0.444
0.424
0.391
0.354
0.312
0.272
0.240
0.207
0.168
0.129
0.099
0.073
0.052
0.035
0.028
0.024
0.017
0.009
0.011
0.012
0.011
0.008
PROPENE
PPM
0.500
0.476
0.422
0.380
0.342
0.300
0.260
0.230
0.180
0.148
0.126
0.100
0.080
0.066
0.050
0.040
0.034
0.026
0.025
0.020
0.016
0.015
0.010
******
0.010
N-C4
PPM
2.04
2.08
2.00
1.93
1.96
1.93
1.89
1.90
1.86
******
1.80
1.76
1.76
1.71
1.69
******
1.68
1.64
1.62
1.62
1.60
1.60
1.56
1.56
1.54
-------
EC - 97
PROPENE * BUTANE
1975 OCT 1
CLOCK
TIME
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
ELAPSED
TCMINI
0.
15.
30.
45.
60.
T5.
90.
105.
120.
13S.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
1.82
1.88
1.90
2.02
2.05
2.08
2.10
2.15
2.26
2.32
2.30
2.43
2.42
2.44
2.47
2.59
2.62
2.70
2.78
2.80
2.61
2.77
2.92
2.98
2.9*
PAN
PPM
0.000
******
0.003
******
0.011
******
0.034
******
0.07J
******
0.035
******
0.117
******
0.145
******
tl.ioZ
******
0.162
******
0.171
******
0.162
******
0.162
HCHO
PPM
0.004
******
******
******
0.121
******
******
******
0.242
******
******
******
0.272
******
******
******
0.250
******
******
******
0.242
******
******
0.224
******
ACETALO
PPM
0.001
******
0.056
******
0.094
******
0.077
******
0.205
******
0.214
******
0.229
******
0.227
******
0.230
******
0.217
******
0.213
******
0.211
******
0.200
PROPALO
PPM
0.0003
******
0.0007
******
0.0014
******
0.0032
******
0.0 J45
******
0. 0055
******
O.OOS7
******
0.0064
******
0.0067
******
0.0067
******
0.0066
******
0.0067
**** **
0.0066
ACETONE
PPM
0.0020
******
0.0050
******
0.0060
******
0.0240
******
0.0350
******
0.0340
******
0.0400
******
0.0430
******
0.0460
******
0.0450
******
0.0440
******
0.0420
******
0.0420
BUTVRAL
PPM
0.0
******
0.0005
******
0.0010
******
0.0021
******
0.0029
****** _
0.0032
******
0.0035
******
0.0038
******
0.0042
******
******
******
0.0042
******
0.0045
******
0.0045
MEK
PPM
0.0
******
0.0090
******
0.0170
******
0.0350
******
0.0480
******
0.0540
******
0.0620
******
0.0720
******
0.0860
******
0.0800
******
0.0850
******
0.0870
******
0.0920
PROX
PPM
0.0001
******
0.0001
******
0.0002
******
0.0011
******
0.0016
******
0.0016
******
0.0018
******
0.0021
******
0.0022
******
0.0022
******
0.0022
******
0.0024
******
0.0024
ME-N
PPM
0.0
******
0.0
******
0.0
******
0.0001
******
******
******
O.OU06
******
0.0007
******
0.0008
******
0.0011
******
0.0011
******
0.0011
******
0.0011
******
0.0011
C2-N
PPM
0.0
******
0.0
******
0.0
******
0.0001
******
0.0004
******
O.OOU6
******
0.0006
******
0.0006
******
0.0011
******
0.0011
******
0.0011
******
0.0011
******
0.0011
C4-N-2
PPM
C-600
0.0
******
0.0024
******
0.0047
******
0.0072
******
0.0094
******
0.0114
******
0.0134
******
0.0151
******
0.0166
******
0.0166
******
0.0170
******
0.0170
******
0.0170
-------
EC - 97
PROPENE » BUTANE
1975 OCT 1
CLOCK
TIME
1030
1045
110J
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1413
1430
1445
1500
1515
1530
1545
1600
1615
1630
ELAPSED
TIMINI
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC F
85. 0
86.7
85.5
85.5
85.2
65.5
85.7
85.5
86.0
86.2
85,5
85.5
66.2
86.5
87.2
86.0
87.0
86.2
87.0
87.0
87.4
87.9
86.2
86.5
87.2
REL HUH
*
54.0
54.0
60.0
67.5
71.0
74.0
73.5
72.5
74. J
74.0
74.0
74.5
74.5
73.5
72.5
72.0
73.5
72.0
71.5
72.0
72.0
70.5
70.5
72.5
71.0
SSPOMER
KM
12.00
******
******
******
12.10
******
******
******
******
******
******
******
12.30
******
******
******
12.30
******
******
******
******
******
******
******
12.40
RADIOH
HW/CM2
0.333
******
******
******
0.334
******
******
******
******
******
******
******
0.338
******
******
******
0.338
******
******
******
******
******
******
******
0.340
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
20.00
******
-------
EC - 99
PROPENE + BUTANE
1975 OCT 6
BEGIN IRRADIATION 1030; 0.25 INCH PYREX FILTER
6-HOUR CONC
-------
EC - 99
PAOPENE + BUTANE
1975 OCT 6
CLOCK
TIME
1015
1030
1045
1100
1115
1150
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
TIMINI
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
OiONE
PPM
0.0
0.0
0.0
0.016
0.045
0.064
0.135
0.180
0.227
0.274
0.313
0.352
0.391
0.424
0.453
0.481
0.510
0.528
0.545
0.551
0.557
0.551
0.551
0.547
0.539
NO
PPM
0.407
0.325
0.221
0.126
0.076
0.053
0.039
0.031
0.026
0.020
0.017
0.016
0.015
0.012
0.012
0.011
0.010
0.010
0.010
0.010
0.010
0.011
0.010
0.009
0.010
N02-CORR
PPM
0.090
0.163
0.244
0.320
0.351
0.349
0.334
0.310
0.286
0.264
0.239
0.213
0.164
0.155
0.123
0.104
0.085
0.058
0.033
0.030
0.027
0.018
0.006
0.005
0.005
NOX-CORR
PPM
0.497
0.487
0.467
0.447
0.429
0.403
0.375
0.340
0.310
0.284
0.256
0.229
0.200
0.167
0.136
0.115
0.095
0.068
0.042
0.039
0.035
&.028
0.015
0.014
0.013
PROPENE
PPM
0.400
0.368
0.324
0.294
0.270
0.234
0.206
0.176
0.150
0.130
0.120
0.098
0.080
0.066
0.056
0.042
0.036
0.030
0.020
0.020
0.018
0.016
0.012
0.010
0.008
N-C4
PPM
2.00
1.97
1.95
1.92
1.90
1.86
1.85
1.81
1.74
1.76
1.74
1.74
1.74
******
1.68
1.66
1.64
1.60
1.60
1.59
1.60
1.55
1.55
1.52
1.52
-------
EC - 99
PROPENE + BUTANE
1975 OCT 6
CLOCK
TIME
1015
1030
1045
1100
1115
1130
1145
1200
1Z15
1330
1245
1300
IMS
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
TIM1NJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
2.06
1.89
2.06
2.07
2.11
2.07
2.25
2.29
2.32
2.36
2.33
2.48
2.42
2.63
2.64
2.60
2.72
2.30
2.76
2.82
2. 83
2.91
2.9?
3.01
2.95
PAN
PPM
0.000
******
******
******
0.011
******
0.026
******
C.055
******
0.065
******
0.079
*««***
0.105
******
0.116
******
0.143
******
0.141
******
0.158
******
0.151
HCHO
PPM
******
******
******
******
0.105
******
******
******
0.159
******
******
******
0,211
******
******
******
******
******
******
******
0.218
******
******
******
0.201
ACETALD
PPM
0.001
******
0.047
******
0.104
******
0.12?
******
0.152
******
0.132
******
0.176
******
0.188
******
0.194
******
0.175
******
0.202
******
0.174
******
0.190
PROPALO
PPM
0.0003
******
0.0006
******
0.0014
******
0.0023
******
0.0033
******
0.0036
******
0.0049
******
0.0053
******
0.0057
******
0.0055
******
0.0062
******
0.0062
******
0.0067
ACETONE
PPM
0.0030
******
0.0030
******
0.0060
******
0.0090
******
0.0130
******
0.0150
******
0.0240
******
0.0220
******
0.0240
******
0.0220
******
0.02SO
******
0.0270
******
0.0310
BUTYRAL
PPM
0.0001
******
0.0008
******
0.0013
******
0.0019
******
0.0022
******.
0.0019
******
0.0032
******
0.0034
******
0.0032
******
0.0036
******
0.0044
******
0.0040
******
0.0042
MEK
PPM
0.0010
******
0.0120
******
0.0200
******
0.0340
******
0.0380
******
0.0440
******
0.0580
******
0.0640
******
0.0720
******
0.0700
******
' 0.0910
******
0.0810
******
0.0990
PROX
PPM
0.0
******
0.0
******
0.0001
******
0.0003
******
******
******
******
******
0.0010
******
0.0010
**«*#*
0.0011
******
0.0012
******
0.0015
******
0.0012
******
0.0015
ME-N
PPM
0.0
******
******
******
0.0
******
0.0
******
0.0
******
0.0006
******
O.OOOu
******
0.0006
******
0.0011
******
0.0017
******
0.0011
******
0.0006
******
0.0011
C2-N
PPM
0.0
******
******
******
0.0
******
0.0
******
0.0
******
J.0006
******
0.0006
******
0.0006
******
O.OOG6
******
0.0006
******
O.OUOB
******
0.0006
******
0.0006
C4-N-2
PPM
C-600
0.0
******
0.0027
******
0.0046
******
0.0070
******
0.0088
******
0.0109
******
0.0124
******
0.0141
******
0.0149
******
0.0181
******
0.0169
******
0.0166
******
0.0175
-------
EC - 99
PROPENE » BUTANE
1975 OCT 6
00
CLOCK
TIME
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1*00
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
TtHINI
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
OEG F
85.2
85.2
84.5
84.8
85.0
85.2
85.0
85.2
85.2
85.5
85.5
85.5
85.5
86.0
85.7
85.5
85.5
85.5
85.5
85.7
86.0
85.7
86.0
86.2
86.2
R£t HUH
*
54.5
54.5
60.0
09.5
71.5
73.0
73.5
75.5
75.5
76.0
75.5
76.0
76.5
76.0
75.5
75.0
75.0
75.0
75.0
74.5
74.5
73.5
74.5
74.0
73.5
SSPOMER
KN
12.30
******
******
******
12.50
******
******
******
12.70
******
******
12.60
12.60
******
******
******
12.50
******
******
******
******
******
******
12.40
13.00
RAOIOH
HW/CM2
0.325
******
******
******
0.332
******
******
******
0.334
******
******
0.334
0.333
******
******
******
0.333
******
******
******
******
******
******
0.345
0.330
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -106
PROPtNE * BUTANE
1975 OCT 14
BEGIN IRRADIATION 0945; 0.25 INCH PYREX FILTER
SPECTRAL DISTRIBUTION TAKEN AT X552
OZONE FACTOR 0.8
CO FACTOR 2.84/1.20; BECKMAN 6800 USED
T«0 AT 945 POT
PAN
REL HUH
HCHO
REL INT
CALIB*
9
2
1
1
TS
REL HUM
SSPOnER
RA010M
H20
NO
NC2-CORR
PROPtNE
N-C4
CO
HCHO
ACETALD
ACcTONE
DEG K
I
KM
HH/CM2
PP8
PPM
PPM
PPM
PPM
PPM
PPH
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CONO
INIT CONO
INIT CONO
INIT CCND
INIT COND
INIT CONO
INIT CCND
INIT CbND
302.8
51.90
12.4.7
0.331
2.132E
0.401
0.102
0.402
2.000
1.815
0.012
0.001
0.002
04
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTIONS
WAVELENGTH!NM»
500.
430.
403.
380.
370.
36d.
350.
340.
330.
320.
310.
300.
290.
280.
REL.
X.l-0.35 MIN-1
SAMPLING RATE = 1.5C4 L/MIN
64 GC SAMPLES TAKEN
INTENSITY
1.618
1.557
1.425
1.316
1.236
1.119
1.000
0.789
0.572
0.357
0.146
0.039
0.001
0.0
-------
EC -106
PROPENE * BUTANE
1975 OCT 14
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
OZONE
PPM
0.0
0.0
0.0
0.0
0.003
0.020
0.041
0.072
0.104
0.145
0.184
0.229
0.266
0.307
0.346
0.381
0.414
0.447
0.483
0.510
0.533
0.553
0.569
0.582
0.590
0.590
0.592
0.592
0.588
0.576
NO
PPM
0.401
0.349
0.268
0.228
0.169
0.121
0.085
0.061
0.049
0.039
0.031
0.024
0.021
0.018
0.016
0.015
0.012
0.012
0.011
0.011
0.010
0.010
0.009
0.010
C.010
0.009
C.007
0.009
0.009
0.009
N02-CORR
PPM
0.102
0.145
0.192
0.243
0.296
0.321
0.340
0.344
0.338
0.328
0.314
0.294
0.269
0.251
0.235
0.198
0.166
0.139
0.113
0.087
0.067
0.049
0.030
0.017
0.006
0.000
-0.000
0.000
-0.000
0.000
NOX-CDRR
PPM
0.500
0.494
0.482
0.472
0.459
0.441
0.426
0.406
0.386
0.367
0.345
0.317
0.290
0.268
0.251
0.213
0.179
0.150
0.124
0.097
0.075
0.057
0.039
0.025
0.012
0.001
-0.000
0.000
-0.000
0.000
PROPENE
PPM
0.402
0.380
0.352
0.325
0.304
0.290
0.262
0.240
0.222
0.200
0.170
0.150
0.136
0.112
0.094
0.080
0.076
0.060
0.042
0.038
0.028
0.026
0.018
0.016
0.014
0.012
0.010
0.006
0.006
0.004
N-C4
PPM
2.00
2.00
1.96
1.95
1.94
1.90
1.90
1.84
1.84
1.84
1.82
1.82
1.78
1.75
1.74
1.74
1.71
1.68
1.66
1.64
1.61
1.61
1.58
1.57
1.54
1.50
1.43
1.50
1.50
1.47
-------
EC -106
PR3PENE » BUTANE
1975 OCT 14
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1203
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
Io45
1700
ELAPSED
TIMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
ISO.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
CO
PPM
1.82
1.77
1.79
1.76
1.80
1.66
1.94
1.93
1.95
1.91
2.04
2.12
2.10
2.16
2.14
2.17
2.25
2.23
2.31
2.34
2.36
2.38
2.47
2.49
2.46
2.49
2.46
2.50
2.58
2.65
PAN
PPM
0.000
******
0.001
******
0.004
******
0.010
******
0.020
******
0.030
******
0.048
* ,<****
0.048
******
o.oao
******
0.102
******
0.120
******
0.137
******
0.149
******
0.162
******
0.149
0.158
HCHO
PPM
0.012
******
******
******
0.151
*<*****
******
**«*«*
0.191
******
******
******
0.207
******
******
******
0.201
******
******
******
0.199
******
******
******
0.187
******
******
******
******
******
ACETALO
PPM
0.001
******
0.032
******
0.070
******
0.109
******
0.132
******
0.149
******
0.172
******
0.138
******
0.182
******
0.199
******
0.182
******
0.185
******
0.173
******
0.196
******
0.179
******
PROPALO
PPM
0.0002
******
0.0004
******
0.0009
******
0.0016
******
0.0024
******
0.0031
******
0.0040
******
0.0046
******
0.0049
******
0.0054
******
0.0054
******
0.0061
******
0.0060
******
0.0065
******
0.0062
******
ACETONE
PPM
0.0020
******
0.0030
******
0.0040
******
0.0060
******
0.0030
******
0.0100
******
0.0120
******
0.0140
******
0.0140
******
0.0160
«#****
0.0200
******
0.0220
******
0.0190
******
0.0230
******
0.0220
******
BUTYRAL
PPM
0.0
******
0.0004
******
0.0008
******
0.0013
******
0.0017
******
0.0020
******
0.0024
******
0.0027
******
0.0032
******
0.0036
******
******
******
0.0040
******
0.0034
******
0.0040
******
0.0040
******
MEK
PPM
0.0
******
0.0060
******
0.0160
******
0.0260
******
0.0330
******
0.0400
******
0.0490
******
0.0600
******
0.0650
******
0.0770
******
0.0760
******
0.0690
******
0.0760
******
0.0980
******
0.0870
******
PROX
PPM
0.0
******
0.0001
******
0.0004
******
0.0008
******
0.0012
******
0.0016
******
0.0016
*$****
o.ooia
******
0.0020
****v*
0.0022
******
0.0024
******
0.0024
******
0.0024
******
0.0024
******
0.0022
******
ME-N
PPM
0.0
******
0.0
******
0.0
******
0.0
******
0.0003
******
0.0006
******
0.0006
******
0.0006
******
0.0008
******
0.0010
******
0.0008
******
0.0008
******
U.0011
******
o.ouil
******
0.0008
0.0011
C2-N
PPM
0.0
******
0.0
******
0.0
******
0.0
******
0.0003
******
0.0006
******
0.0006
******
0.0 J06
******
0.0006
******
0.0007
******
0.0006
******
0.0007
******
O.OuOS
******
0.0008
******
0.0008
0.0007
C4-N-Z
PPM
C-600
0.0
******
0.0019
******
0.0037
******
0.0055
******
0.0073
******
0.0090
******
0.0112
******
0.0128
******
0.0142
******
0.0159
******
0.0167
******
0.0164
******
0.0168
******
0.0175
******
0.0173
**«•***
-------
EC -106
PRDPENE + BUTANE
1975 OCT 14
CLOCK
TIME
945
1400
1015
1030
1045
1100
1115
1130
1145
1200
1215
i230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
lc>45
1700
ELAPSED
TIMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
TS
DEC F
84.8
86.5
85.2
85.2
85.2
85.0
84.8
85.2
85.2
85.2
85.2
85.2
85.0
85.0
85.2
05.2
85.2
65.2
85.5
85.2
85.5
86.0
85.5
85.7
86.0
86.0
86.2
86.2
86.2
86.0
REL HUH
*
44.0
44.0
44.5
46.5
48.5
50.5
52.0
54.0
55.0
55.5
55.5
55.5
55.5
55.0
55.0
55.0
54.5
54.5
54.5
54.0
53.5
53.0
52.0
51.5
51.5
51.0
50.5
50.0
49.5
49.0
SSPOMER
KM
12.70
******
******
******
12. OU
12.60
******
******
12.70
******
******
******
12.70
******
******
******
12.70
******
******
******
******
******
******
******
12.70
******
******
******
******
******
RADION
MW/CMZ
0.333
******
******
******
0.333
0.328
******
******
0.332
******
******
******
0.332
******
******
******
0.331
******
******
******
******
******
******
******
0.331
******
******
******
******
******
HCHO VOL
L
20.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
******
******
-------
EC -113
PROPENE * BUTANE
1975 NOV 24
dEGIN IRRADIATION 1030; 0.25 INCH PYREX FILTER
LAST HCHO SAMPLE STARTED AT 1615 HOURS; ALL HCHO SAMPLES TURNED YELLOW
PROPYLENE OXIDE NOT SEPARATED FROM HC PEAK
ALL NITRATES FROM FIO GC5 Cl-N
CALI3#
PAN
REL HUM
HCHO
TS
REL HUM
SSP3V.ER
RADIOK
H20
NO
N02-CORR
PROPENE
N-C4
CO
ACETONE
C2-N
DEC K
%
KW
MW/CM2
PPM
PPM
PPH
PPM
PPM
PPM
PPK
PPM
9
2
I
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
INIT COND
INIT COND
INIT CCND
INIT COND
INIT CCNO
INIT COND
ASSIGNED INITIAL CONDITION
Kl=0.35 MIN-1
SAMPLING RATE
302.7
49.06
12.85
0.331
2.000E
0.091
0.020
0.410
2.0<»0
1.341
0.003
0.001
1.783 L/MIN
54 GC SAMPLES TAKEN
-------
EC -113
PROPENE * BUTANE
197$ NOV 24
to
CLOCK
TIME
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
160U
1615
1630
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.0
0.006
0.078
0.160
0.233
0.281
0.317
0.338
0.348
0.348
0.348
0.340
0.336
0.330
0.324
0.319
0.315
0.311
0.309
0.305
0.305
0.301
******
0.299
0.297
NO
PPM
0.091
0.043
0.017
0.010
C.C09
0.008
0.007
0.007
0.007
0.006
0.006
0.006
0.006
0.006
0.006
0.006
C.006
0.005
0.005
0.005
0.005
0.005
******
0.005
0.005
NQ2-CORR
PPM
0.020
0.063
0.080
0.070
0.056
0.044
0.031
0.023
0.016
0.009
0.004
0.001
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
******
0.0
0.0
NOX-CORR
PPM
0.111
0.105
0.097
0.081
0.005
0.051
0.038
0.030
0.022
0.015
0.010
0.007
0.004
0.003
0.002
0.002
0.002
0.001
0.001
0.002
0.003
0.001
******
0.0
0.000
PROPENE
PPM
0.410
0.388
0.350
0.314
0.260
0.224
0.185
0.164
0.140
0.120
0.106
0.094
O.OBO
0.075
0.065
0.061
0.055
0.046
0.043
0.038
0.035
0.031
0.026
0.025
0.021
N-C4
PPM
2.04
2.05
2.02
******
1.98
1.93
1.92
******
1.86
1.87
1.86
1.84
1.84
1.82
i.ai
1.80
1.73
1.77
1.72
1.74
1.73
1.72
1.72
******
1.69
-------
EC -U3
PROPENE * BUTANE
1975 NOV 24
Un
CLOCK
TIME
1030
1043
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
U30
1345
1400
Itl5
143U
1445
1500
1515
1530
1545
1600
1015
1630
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
1.34
1.45
1.38
1.42
1.51
1.53
1.53
1.55
1.51
1.63
1.64
1.70
1.75
1.68
1.77
\. 77
1.84
1.84
1.87
1.93
1.96
1.93
******
1.99
2.02
PAN
PPM
0.000
******
0.004
******
0.020
******
0.037
******
0.047
******
0.056
******
0.059
******
0.060
: *****
0.059
******
0.060
******
0.058
******
0.059
******
0.059
HCHO
PPM
******
******
******
******
******
******
******
******
******
******
*««***
******
******
******
******
******
******
******
******
******
******
******
******
******
******
ACETALO
PPM
******
******
0.050
******
0.114
******
0.144
******
0.173
******
0.166
******
0.178
******
0.168
******
0.160
******
0.169
******
0.194
******
0.184
******
0.158
PROPALD
PPM
0.0002
******
0.0010
******
0.0025
******
0.0036
******
0.0040
******
0.0036
******
0.0036
******
0.0034
******
0.0031
******
0.0032
******
0.0038
******
0.0038
******
0.0031
ACETONE
PPM
0.0034
******
0.0049
******
0.0080
******
0.0100
******
0.0099
******
0.0099
******
0.0133
******
0.012U
******
0.0149
******
0.0163
******
O.C163
******
0.0189
******
0.0163
BUTYRAL
PPM
******
******
0.0011
******
0.0024
******
0.0030
******
0.0041
******
0.0038
******
0.0042
******
0.0046
******
0.0049
******
0.0048
******
0.0054 .
******
0.0057
******
0.0053
MEK
PPM
0.0002
******
0.0134
******
0.0281
******
0.0403
******
0.0466
******
0.0535
******
0.0562
******
0.0567
******
0,0623
******
0.0631
*******
0.0670
******
0.0705
******
0.0705
C2-N
PPM
0.0006
******
0.0006
******
0.0002
******
0.0006
******
0.0005
******
******
******
0.0006
******
0.0003
******
0.0009
******
0.0006
******
0.0013
******
0.0011
******
0.0021
C3-N-1
PPM
C-600
0.0
******
0.0
******
0.0
******
0.0003
******
0.0003
******
0.0007
******
0.0010
***«¥*
0.0007
******
0.000?
******
0.0013
******
0.0012
******
0.0012
******
0.0009
C4-N-2
PPM
C-600
0.0
******
0.0023
******
0.0057
******
0.0078
******
0.0005
******
******
******
0.0101
******
0.0098
******
0.0102
******
0.0105
******
0.0108
******
0.0114
******
0.0111
C4-N-1
PPM
C-600
******
******
0.0
******
0.0006
******
0.0010
******
0.0010
******
0.0014
******
0.0010
******
0.0019
»»**,*
0.0020
******
0.0013
******
0.0007
******
0.0015
******
0.0017
-------
K3
EC -113
PROPENE »
BUTANE
1975 NOV 24
CLOCK
TIME
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
looo
1615
Ib30
ELAPSED
TIHIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
loS.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC f
70.6
84.8
85.0
85.2
85.0
******
85.2
85.5
85.5
85.2
85.0
84.8
85.0
85.2
65.5
85.7
85.2
85.5
85.5
86.0
85.5
85.5
******
66.2
86.5
REL HUH
at
41.5
41.5
43.5
45.5
47.5
49.5
50.5
50.5
50.5
51.0
51.5
52.5
52.5
52.0
51.5
50.5
50.5
50.0
50.0
49.5
49.0
49.0
******
48.0
47.0
SSPOWER
KM
12.40
13.30
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
RADIOM
HW/CH2
0.303
0.337
0.332
******
******
0.340
******
******
0.305
******
0.322
0.327
0.332
******
0.332
0.330
0.335
0.332
0.322
0.332
0.340
******
******
0.293
0.327
HCHO VOL
L
25.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
20.00
******
-------
to
EC -11*
PROPENE + BUTANE
1975 DEC 24
BEGIN IRRADIATION 1030; 0.25 INCH PYREX FILTER
OZONE FACTOR 0.8, CO FACTOR 2.20/1.14
T»0 AT 1030 PST
PAN
REL HUH
HCHO
REL INT
TS
REL HUH
RADIOH
H20
NO
N02-CQRR
PROPEKE
N-C4
CO
HCHO
ACETONE
C4-N-1
OEG K
CALIB*
9
3
1
1
AVERAGE
302.9
% AVERAGE 63.34
HW/CH2
PPH
PPM
PPM
PPH
PPM
PPM
PPH
PPH
PPH
* ASSIGNED
SPECTRAL
AVERAGE
AVERAGE
INIT
INIT
INIT
INIT
iNIT
INIT
IMT
INIT
INITIAL
DISTRIBUTION:
COND
CONO
CONO
COND
CCNO
CCNO
CONO
COND
0.
2.
0.
0.
0.
3.
1.
0.
0.
0.
328
502E 04
794
2U4
766
660
329
008
003
001
CONDITION
hAVELENGTMNHI
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
REL.
INTENSITY
2.
1.
1.
1.
1.
1.
1.
0.
0.
0.
0.
0.
0.
0.
135
861
655
460
335
163
000
762
529
313
132
034
002
0
Kl»0.35 HIN-1
SAHPLING RATE - 1.783 L/HIN
54 GC SAMPLES TAKEN
-------
EC -114
PROPENE + BUTANE
1975 DEC 24
N)
00
CLOCK
TIME
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
143d
1445
1500
1515
1530
1545
1600
1615
1630
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
235.
300.
315.
330.
345.
360.
OZONE
PPM
0.0
0.0
0.0
0.0
0.002
0.018
0.055
0.100
0.156
0.211
0.276
0.332
0.3SI
0.444
0.494
0.549
0.596
0.643
0.678
0.711
0.729
0.741
0.745
0.741
0.733
NO
PPM
0.794
0.657
0.518
0.374
0.256
0.173
0.117
0.073
0.051
0.039
0.027
0.024
0.020
0.015
0.012
0.012
0.010
0.010
0.007
0.010
0.010
0.010
0.010
0.007
0.010
N02-CORR
PPM
0.204
0.328
0.438
0.550
0.633
0.633
0.701
0.698
0.676
0.636
0.590
0.532
0.468
0.409
0.347
0.276
0.217
0.173
0.131
0.092
0.058
0.043
0.029
0.021
0.018
NOX-CORR
PPM
0.996
0.983
0.953
0.924
0.890
0.854
0.818
0.774
0.728
0.675
0.617
0.554
0.485
0.421
0.359
0.288
0.227
0.180
0.138
0.099
0.065
0.051
0.038
0.028
0.023
PROPENE
PPM
0.766
0.710
0.664
0.600
0.548
0.504
0.452
0.404
0.356
0.310
0.2U6
0.254
0.194
0.158
U.I 20
0.088
0.080
0.064
0.044
0.038
0.030
0.026
0.016
0.014
0.014
N-C4
PPM
3.66
3.62
3.60
3.55
3.52
3.47
3.44
3.38
3.36
3.33
3.33
3.26
3.23
3.17
3.17
3.12
3.09
3.07
3.04
3.01
2.98
2.94
2.74
2.91
2.88
-------
EC -114
PfiOPENE t- BUTANE
1975 DEC 24
CLOCK
TIME
1030
1045
1100
1115
1130
U4S
1200
1215
1230
1245
130J
1315
1330
1345
1400
1415
1430
1445
I-1 1500
S m5
1530
1545
1600
1615
1630
ELAPSED
T(HIN)
0.
IS.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
1 80.
195.
210.
225.
240.
255.
^70.
285.
300.
315.
. 330.
345.
360.
CO
PPM
1.33
1.31
1.35
1.38
1.43
1.48
1.50
1.50
1.63
1.60
1.61
1.77
1.72
1.77
1.84
1.90
1.88
1.96
1.95
2.02
2.13
2.14
2.18
2.16
2.26
PAN
PPM
0.000
******
O.C03
******
0.012
******
0.025
******
0.050
******
0.073
******
0.107
******
0.137
******
C.176
******
0.196
******
0.231
******
0.231
******
0.231
HCHO
PPM
0.008
******
******
******
0.191
******
******
******
0.306
******
******
******
0.419
**$***
******
******
0.433
******
******
******
0.419
******
******
******
0.338
ACETALO
PPM
******
******
******
******
0.156
******
0.221
******
0.265
******
0.322
******
0.377
******
O.i 79
******
0.371
******
0.427
******
0.336
******
0.382
******
0.387
PROP AID
PPM
0.0002
******
0.0011
******
0.0027
******
0.0045
******
0.0063
******
0.0076
*****!)!
0.0091
******
0.0095
******
0.0099
******
0.0110
******
0.0097
******
0.0108
******
0.0112
ACETONE
PPM
0.0034
******
0.0032
******
0.0046
******
0.0103
******
0.0159
******
0.0225
******
0.0278
*##*¥*
0.0314
******
******
******
0.0427
******
0.0417
******
0.0364
******
0.0346
BUTYRAL
PPM
0.0
******
0.0010
******
0.0017
******
0.0026
******
0.0038.
******'
0.0044
******
0.0055
,;, ;:****
0.0060
******
0.0066
******
0.0075
******
P. 0075
******
O.OOS7
******
0.0088
MEK
PPM
0.000
******
0.019
******
0.018
******
0.061
******
0.079
******
0.094
******
0.108
******
0.134
******
0.144
****<:*
0.160
******
0.175
XfVttXK
0.175
**#*«*
0.182
PROX
PPM
******
******
******
******
******
******
0.0035
******
******
******
0.0078
******
0.0090
******
0.0097
***«*«
0.0063
***!<**
0.0084
*##«**
0.0089
******
0.0089
******
0.0089
ME-N
PPM
0.0
******
0.0
******
O.OOU3
******
0. OOOb
******
0.0011
*«**¥«
0.0022
******
0.0025
******
0.0028
******
0.0028
******
0. 1029
******
0.0031
******
0.0031
******
0.0031
C2-N
PPM
0.0
******
0.0
******
0.0004
******
0.0006
******
0.0008
******
0.0011
******
0.0014
******
0.0015
******
0.0017
******
0.0020
***«»*
0.0018
******
0.00/0
******
0.0020
C4-N-2
PPM
C-600
0.0
******
0.0033
******
0.0076
******
0.0113
******
0.0145
******
0.0176
******
0.0221
******
0.0216
**«•«•**
0.0269
**?**»
0.0307
******
0.030S
******
0.0339
****** .
0.0348
C4-N-1
PPM
C-600
0.0005
******
O.OOOo
******
0.0013
******
0.0016
******
0.0021
******
0.01)21
******
0.0026
******
0.0026
******
0.0032
******
0.0037
******
0.0028
******
0.0043
******
0. 0046
-------
EC -114
PROPENE + BUTANE
1975 DEC 24
U)
O
CLOCK
TIME
1030
1045
1100,
1115
1130
1145
1200
1215
12 30
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
15t5
1600
1615
1630
ELAPSED
TtHINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC f
73.8
85.2
85.2
85.5
85.0
85.2
85.7
65.2
85.7
65.7
86.0
85.7
85.5
65.5
86.0
85.7
86.2
86.0
86.0
85.7
86.2
85.7
86.5
86.7
86.7
REL HUH
«
53.5
53.5
53.5
54.0
54.0
54.0
54.5
54.5
54.5
54.5
54.5
54.5
54.5
54.5
54.5
54.5
54.5
54.5
54.5
54.5
54.5
54.5
54.5
54.0
54.5
IUD10M
MX/CH2
******
0.322
0.325
0.327
0.330
******
0.342
******
0.337
******
******
******
******
******
******
******
0.325
******
******
0.325
0.330
0.330
******
******
0.335
HCHO VOL
L
25.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -115
PRQPENE * BUTANE
1975 DEC 3
IRRADIATION 10455 0.25 INCH PYREX FILTER
OZONE FACTOR 0.8. CO FACTOR 2.20/1.11
T=0 AT 1045 PST
PAN
REI HUM
HCHO
REL INT
CALIBflf
9
3
1
1
TS
REL HUM
RAOIOK
H20
NJ
N02-CORR
PROPEME
N-C4
CO
HCHO
ACETONE
PROX
DEC, K
*
MH/CH2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
I NIT CONO
INIT CQNO
IN1T CONO
INIT CONO
INIT CONO
INIT CCI4D
INIT CCNO
INIT CONO
302. 8
53.69
0.335
2.208E
0.402
0.104
0.310
2.940
1.404
0.012
0.003
0.001
04
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: WAV£LENi,TH(NM)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
Kl»0.35 MIN-1
SAMPLING RATE - 1.664 L/MIN
54 GC SAMPLES TAKEN
REL.
INTENSITY
2.174
.976
.703
.478
.336
.169
1.000
0.750
0.535
0.317
0.124
0.033
0.002
0.0
-------
EC -115
PROPENE + BUTANE
1975 DEC 3
UJ
CLOCK
TIME
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
l4-»5
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
1800
1815
ELAPSED
TIMII-O
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
241).
255.
270.
235.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
OZONE
PPM
0.0
0.0
0.0
0.0
0.002
0.016
0.041
0.066
0.102
0.141
0.130
0.215
0.254
0.237
0.322
0.362
0.395
0.428
0.461
0.489
0.516
0.539
0.559
0.573
0.582
0.586
0.588
0.588
0.590
0.586
0.584
NO
PPM
0.402
0.349
0.287
0.227
0.165
0.118
0.083
0.060
0.045
0.035
0.028
0.024
0.020
0.017
0.015
0.013
0.012
0.011
0.011
0.010
0.010
0.009
0.009
0.007
0.007
0.007
0.007
0.007
0.007
0.007
0.007
N02-CORR
PPM
0.104
0.148
0.203
0.254
0.303
0.339
0.357
0.362
0.356
0.347
0.329
0.308
0.239
0.262
0.237
0.208
0.184
0.159
0.136
0.111
0.087
0.070
0.052
0.049
0.046
0.028
0.011
0.006
0.002
0.006
0.012
NOX-CORR
PPM
0.506
0.497
0.490
0.480
0.468
0.455
0.439
0.422
0.401
0.381
0.357
0.332
0.307
0.279
0.250
0.221
0.195
0.170
0.147
0.121
0.095
0.077
0.059
0.056
0.052
0.034
0.019
0.013
0.008
0.013
0.018
PROPENE
PPM
0.310
0.294
0.278
0.278
0.242
0.244
0.220
0.188
0.168
0.148
0.134
0.126
0.104
O.U90
0.078
0.068
0.058
0.046
0.040
0.034
0.028
0.022
0.020
0.014
0.010
0.010
0.008
0.008
0.006
0.005
0.004
N-C4
PPM
2.94
2.91
2.90
2.88
2.86
2.78
2.78
2.75
2.75
2.69
2.67
2.62
2.61
2.59
2.58
2.54
2.51
2.50
2.46
2.45
2.43
2.40
2.38
2.37
2.35
2.32
2.30
2.23
******
2.26
2.24
-------
EC -115
PROPENE * BUTANE
1975 DEC 3
CLOCK
TIME
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
1800
1815
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90,
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
CO
PPM
1.40
1.43
1.36
1.47
1.31
1.54
1.52
1.90
1.56
1.60
1.65
1.66
1.78
1.76
1.80
1.73
1.77
1.81
1.91
1.88
1.95
1.98
2.04
2.04
2.04
2.15
2.17
2.15
2.20
2.22
2.36
PAN
PPM
0.000
******
0.001
******
0.004
******
0.007
******
0.017
******
0.030
******
******
******
***»*»
******
0.071
******
0.084
******
0.102
******
0.114
******
0.107
******
C.130
******
0.134
******
0.119
HCHO
PPM
0.012
******
******
******
0.083
******
******
******
0.141
******
******
******
0.171
*««**«
******
******
******
******
******
******
0.201
******
******
******
0.183
******
******
******
******
******
******
ACETALO
PPH
******
******
0.019
******
0.056
******
0.098
******
0.116
******
0.134
******
0.164
******
0.179
****«#
0.173
******
0.196
******
******
******
0.222
******
0.179
******
0.206
******
0.205
******
0.198
PROPALD
PPM
0.0004
******
******
******
0.0008
******
0.0019
******
0.0026
******
0.0033
******
0.0045
******
0.0047
******
0.0054
******
0.0058
******
0.0059
******
0.0072
******
0.0073
******
0.0068
******
0.0072
******
0.0075
ACETONE
PPM
0.0031
******
0.0026
******
0.0040
******
0.0067
******
0.0086
******
0.0122
******
0.0153
******
0.0130
***«*»
0.0173
******
0.0200
******
0.0189
******
0.0320
******
0.0252
******
0.0214
******
0.0270
******
0.0267
BUTYRAL
PPM
0.0
******
0.0005
******
0.0011
******
0.0020
******
0.0023
*******
0.0029
******
0.0038
*?****
0.0046
******
0.00-.4
******
0.00t9
££****
0.0057
******
0.0056
******
0.0058
******
0.0066
******
0.0068
******
0.0072
MEK
PPM
0.000
******
0.009
******
0.022
******
0.040
******
0.046
******
0.060
******
0.076
******
0.078
******
0.092
******
0.108
******
0.116
******
0.132
******
0.122
******
0.130
******
0.145
******
0.145
PROX
PPM
0.0011
******
******
******
******
******
******
******
******
******
******
******
******
*«$***
******
******
******
******
******
******
******
******
0.0036
******
******
******
0.0028
******
0.0028
******
******
HE-N
PPM
0.0
******
0.0
******
0.0
******
0.0
******
0.0
*v****
0.0003
******
******
******
******
******
0.0006
******
0.0007
******
0.0007
******
0.0008
******
0.0007
******
0.0008
******
0.0006
******
0.0011
C2-N
PPM
0.0
******
0.0
******
0.0
******
0.0
******
o.o
******
0.0003
******
******
******
******
******
0.0007
******
0.0007
******
0.0008
******
0.0010
******
0.0006
******
0.0011
******
O.OU06
******
0.0011
C4-N-2
PPM
C-600
0.0005
******
0.0017
******
0.0046
******
0.0070
******
0.0097
******
0.0108
******
0.0116
******
0.0161
******
0.0132
******
0.0194
******
0.0218
******
0.0237
******
0.0246
******
0.0254
******
0.0262
******
0.0276
C4-N-1
PPM
C-600
0.0003
******
******
******
0.0005
******
O.OJ14
******
0.0012
******
0.0018
******
0.0318
******
0.0024
******
0.0027
******
0.0020
******
0.0031
******
0.0030
******
0.0028
*¥****
0.0034
******
0.0033
******
******
-------
EC -US
PROPENE + BUTANE
1975 DEC 3
OJ
CLOCK
TIME
1045
1100
1115
1130
1145
1200
1215
1230
1243
1300
1315
1330
1345
1400
1415
1430
1445
ISOJ
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
1800
1815
ELAPSED
T1HINI
0.
IS.
30.
45.
60.
75.
90.
105.
120.
13S.
ISO.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
4SO.
TS
DEG F
75.2
86.5
85.2
86.2
as. 2
85. 2
85.2
8S.O
85.0
65.2
85.5
64.8
85.5
85.7
85.2
85.2
85.5
86.2
as. 5
85.7
85.5
85.7
85.2
85.7
85.2
84.8
85.5
85.2
86.2
86.2
86.7
REL HUH
X
48.5
49.0
51. 0
S3.S
54.0
54.0
54.0
54.5
54.5
54.5
54.0
54.5
54.5
54.0
54.0
54.0
54.0
34.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
RAOIOM
MW/CM2
******
0.337
******
0.332
0.335
******
0.332
******
0.332
******
0.335
******
******
******
******
******
0.332
******
******
******
******
******
0.325
0.330
0.327
******
0.332
******
******
******
0.342
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
******
******
******
******
20.00
******
******
******
20.00
******
******
******
******
******
******
-------
Co
EC -116
PROPENE * BUTANE
1975 DEC 4
BEGIN IRRADIATION 0930; 0.25 INCH PVREX FILTER
OZONE FACTOR 0.8, CO FACTOR 2.20/1.09
T-0 AT 930 PST
PAN
REL HUH
MCHO
REL INT
TS DEG K
REL HUH *
RAUIQM MH/CH2
M20 PPH
NO PPM
N02-CQRR PPM
PHOPEME PPH
N-C4 PPh
CD PPH
HCHO PPH
ACETONE PPH
C4-N-1 PPM
* ASSIGNED
CALIB*
9
3
1
1
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT COND
INIT CONO
INIT CONO
INIT CONO
INIT CCNO
INIT CCNO
INIT CQND
INIT CONO
INITIAL CONDITION
303.0
53.71
0.332
2.231E 04
0.391
0.104
O.B24
4.000
1.335
0.005
0.003
0.001
SPECTRAL DISTRIBUTION: kAVELENGTHtNH) REL.
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
INTENSITY
2.154
1.923
1.689
1.464
1.342
1.183
1.000
0.754
'0.534
0.323
0.128
0.034
0.002
0.0
Kl-0.35 HIN-1
SAMPLING RATE * 1.727 L/MIN
64 GC SAMPLES TAKEN
-------
EC -116
PROPENE » BUTANE
1975 DEC 4
CLOCK
TIME
930
945
1000
1015
1030
1045
110U
1115
U3J
1145
1200
1215
1230
1245
1300
1315
1330
1343
1400
1415
1430
1445
1500
1515
1530
ELAPSED
T(HIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.0
0.0
0.002
0.035
0.133
0.268
0.403
0.526
0.619
0.686
0.719
0.741
0.741
0.731
0.719
0.707
0.694
0.660
0.668
0.659
0.649
0.639
0.633
0.627
0.619
NO
PPM
0.391
0.292
0.183
0.079
0.038
0.022
0.016
0.013
0.011
0.011
0.010
0.010
0.010
0.009
0.009
0.009
0.007
O.OG7
0.007
0.007
0.007
0.007
0.006
0.007
0.006
N02-CORR
PPM
0.1 04
0.196
0.2B8
0.364
0.382
0.353
0.306
0.242
0.176
0.126
0.077
0.051
0.032
0.017
0.006
-0.001
-0.009
-0.009
-0.011
-0.010
-0.010
-0.009
-0.009
-0.013
-0.015
NOX-CORR
PPM
0.493
0.487
0.471
0.446
0.420
0.375
0.321
0.254
0.187
0.136
0.085
0.061
0.039
0.026
0.013
0.006
-0.001
-0.003
-0.005
-0.004
-0.003
-0.003
-0.003
-0.007
-0.009
PROP ENE
PPM
0.824
0.780
0.720
0.672
0.600
0.544
0.408
0.328
0.250
0.192
0.152
0.118
0.088
0.072
0.056
0.046
0.038
0.032
0.020
0.016
0.014
0.014
0.010
0.006
0.010
N-C4
PPM
4.00
3.98
3.94
3.89
3.87
3.82
3.76
3.68
3.58
3.58
3.54
3.52
3.50
3.41
3.39
3.39
3.41
3.36
3.34
3.33
3.30
3.26
3.17
3.26
3.25
-------
EC -116
PROPENE * BUTANE
1975 DEC 4
CLOCK
TIME
930
945
100U
1015
1030
1045
1100
IH5
1130
1145
1200
1215
1230
1245
1300
131%
13 3 J
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
T1MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
15C,
165.
iao.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC r
85.0
85.7
85. 2
85.2
85.5
85.5
86.0
65.7
80.5
86.0
86.0
86,0
85.7
8&.0
86. C
85.2
65.2
85.2
85.2
86.0
86.0
86.2
66.5
86.2
66.2
REL HUH
*
52.0
92.0
52.0
53.0
53.5
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
RAD I OH
MW/CM2
0.335
0.335
******
******
0.330
******
******
******
0.335
******
0.330
******
0.330
******
0.327
******
0.332
******
0.330
0.327
0.332
******
******
******
0.335
HCHO VOL
L
25.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
******
-------
u>
00
EC -121
PROPENE
1976 FEB 26
BEGIN IRRADIATION lOOOi 0.25 INCH PYREX FILTER
CO FACTOR 2.2/1.22
RADIOMETER CORRECTION -0.01 HW/CM2
T=0 AT 1000 PST
PAN
REL HUM
HCHO
REL INT
TS DEC K
REL HUM *
SSPOnER Kh
RAOIOM MW/CM2
H20 PPM
NO PPM
N02-CORR PPM
CO PPM
ACETALD PPM
ACETONE PPM
PRiiPENE PPM
* ASSIGNED
CALIBrf
9
2
I
2
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CONO
INIT COND
IMT CCND
INIT CCND
INIT CCNO
INIT CCNO
INITIAL CONDITION
304.2
56.82
13.23
0.413
2.548E 04
0.410
0.101
Z.193
O.COS
0.005
0.483
SPECTRAL DISTRIBUTION: hAVELENGTH(NM) REL.
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
INTENSITY
1.993
1.874
1.623
1.435
1.310
I.id2
1.000
0.760
0.513
0.255
0.067
0.016
O.C
Kl«=0.30 MIN-1
SAMPLING RATE * 1.768 L/MIN
54 GC SAMPLES TAKEN
-------
EC -121
PROPENE
1976 FE8 26
CLOCK
TIME
1000
1015
1030
1045
1100
1115
1130
1145
120J
1215
1230
1245
1300
1315
1330
13*5
-i> J TF^
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
P 5 R
£, JL J &
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
OZONE
PPM
0.0
0.0
0.020
0.046
0.100
0.122
0.169
0.213
0.249
0.269
0.310
0.344
0.364
0.391
0.415
04, -a n
« *r 3 v
0.452
0.471
0.484
0.493
0.501
0.506
C.501
0.503
0.501
0.498
NO
PPM
0.410
C.2«>0
0.143
0.082
0.060
0.040
0.029
0.024
0.021
0.016
0.015
0.013
0.011
0.011
0.010
Onl rt
« UiO
0.007
0.009
0.007
0.007
0.007
0.007
C.007
0.007
0.007
0.007
N02-CORR
PPM
0.101
0.230
0.320
0.341
0.323
0.311
0.286
0.263
0.227
0.213
0.191
0.165
0.139
0.114
O.OS3
Of 7^t
* U / 3
0.054
0.042
0.036
0.021
0.022
0.014
O.C08
0.0
• o.o
0.0
NOX-CORR
PPM
0.510
0.491
0.464
0.419
0.384
0.352
0.317
0.238
0.257
0.227
0.205
0.179
0.148
0.125
0.102
On ft 1
• Qoi
0.061
0.050
0.043
0.030
0.029
0.021
0.016
0.006
0.0
0.0
PROPENE
PPM
0.463
0.410
0.335
0.275
0.231
0.191
0.162
0.133
0.111
0.087
0.071
0.058
0.043
0.032
0.028
o!oi6
0.013
0.009
0.007
0.006
0.004
0.003
0.003
0.002
0.002
CO
PPM
2.19
2.37
2.38
2.37
2.45
2.45
2.57
2.58
2.59
2.70
2.72
2.74
2.78
2.83
2.86
2r f
. 66
2.92
2.9ti
3.02
2.99
3.09
3.09
3.15
3.18
3.19
3.20
PAN
PPM
0.000
******
0.008
******
0.027
******
0.050
******
0.067
*******
0.084
******
0.105
******
******
0.141
******
******
0.153
0.149
******
0.158
******
0.167
******
HCHO
PPM
0.0
******
******
******
0.201
******
******
******
0.278
******
******
******
0.262
******
******
0,228
******
******
******
0.197
******
******
******
0.171
******
ACETALO
PPM
0.005
******
0.076
******
0.141
******
0.148
******
0.148
******
f% 162
******
0.143
******
0.1^5
0.109
******
0.110
******
0.079
******
0.076
******
0.066
******
PROPALO
PPM
0.0004
******
0.0010
******
0.0020
*****•?
0.0028
******
0.0032
******
0.0036
******
0,0040
******
0.0041
0.0041
******
0.0047
******
0.0036
******
0.0040
******
U.0037
******
ACETONE
PPM
0.0055
******
0.0069
******
0.0101
******
0.0115
******
0.0174
******
tl. O.i54
******
0.0200
******
0.0<:37
0.0188
******
0.0272
******
0.0253
******
0.0197
******
0.0271
******
PROX
PPM
0.0001
******
******
******
O.OQ07
******
0.0007
******
0.0010
******
0.0019
******
0.0018
******
O.OC19
0.0017
******
0.0022
******
0.0013
******
0.0014
******
0.0017
******
ME-N
PFM
0.0
******
0.0
******
0.0006
******
0. JOJ6
******
0.0011
******
O.uOl*.
****««
0.0014
******
******
O.OOi 7
**»***,
******
0.0013
0.0015
******
0.0015
******
u.0017
******
-------
EC -121
PROPENE
1976 FEB 26
CLOCK
TIME
1000
1015
1030
1045
1100
1115
1130
1145
12oO
1215
1230
12*5
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
Iol5
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
TS
PEG F
87.0
90.1
90.4
69.4
88. 7
89.2
89.6
90.1
88.9
88.2
88.9
£9.2
87.7
87.9
87.2
67.2
87.2
87.9
87.0
67.4
87.9
86.5
67.0
87.0
67.4
67.9
REL HUM
*
49.0
46.5
50.0
52.0
54.0
56.5
59.0
59.0
59.5
60.5
61.0
61.0
61.0
61.5
61.5
62.0
62.0
62.0
61.5
62.0
61.5
61.0
61.5
62.0
61.5
61.0
SSPOrtER
KW
13.20
******
13.20
******
******
******
******
13.60
******
******
******
******
13.20
******
******
******
******
******
******
******
******
13.10
******
******
13.10
******
RAC10M
Mh/C«2
******
0.410
******
******
0.398
******
******
0.413
0.395
******
******
0.403
0.400
******
******
******
0.400
******
0.405
0.410
0.400
******
******
0.417
0.403
0.395
HCHO VOL
L
25.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20. CO
******
-------
EC -122
BUTENE-l
1976 FEB 27
BEGIN IRRADIATION 0930, 0.25 INCH PVREX FILTER
CORRECTION FOR DECAY IN Kl
Cl-N ESTIMATED 0.3 PP6 AT 1530
CO FACTOR 2.2/1.25
RADIOMETER CORRECTICN -0.02 MM/CM2
T=0 AT 930 PST
PAN
REL HUM
HCHO
REL INT
CALIB*
9
2
1
2
Ti
REL HUM
SSPurtER
RAOICM
H20
NO
N02-CORR
CO
ACETALD
ACETONE
1-C4=
OEG K
4
KW
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CGNO
INST COND
INIT CCND
INIT CCND
INIT CGND
INIT CGNO
303.0
£2.46
13.22
0.126
2.L80E 04
0.398
0.103
1.674
0.002
O.C02
0.217
ASSIGNED INITIAL CCNDIT10N
SPECTRAL DISTRIBUTION: kAVELENGTH(MM)
5UO.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
Kl=0.29 MIN-1
SAMPLING RATE » 1.730 L/MIN
54 GC SAMPLES TAKEN
REL. INTENSITY
1.973
1.888
1.632
1.457
1.312
1.174
1.000
0.753
0.514
0.270
0.096
0.021
0.0
-------
(O
EC -122
BUTENE-1
1576 FEB 27
CLOCK
TIME
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
14t5
1500
1515
1530
1545
1600
1615
1630
ELAPSED
TiHINl
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
OZONE
PPM
0.0
0.0
0.0
0.0
0.002
0.005
0.010
0.017
0.027
0.029
0.039
0.051
0.059
0.061
0.076
0.085
O.C98
0.107
0.117
0.127
0.137
0.147
0.156
0.169
0.161
0.188
0.200
0.213
0.220
NO
PPM
0.398
0.369
0.330
0.293
0.252
0.215
C.186
C. 161
0.137
0.117
0.103
0.089
0.076
C.068
0.061
0.055
0.045
0.044
0.039
0.034
0.031
0.026
0.024
0.022
0.021
C.020
C.018
C.017
0.016
N02-CORR
PPM
0.103
0.126
0.162
0.183
0.215
0.240
0.252
0.264
0.276
0.280
0.281
0.280
0.281
0.273
0.268
0.261
0.258
0.246
0.239
0.230
C.226
0.216
0.214
0.1*7
0.187
0.178
0.171
0.165
0.157
NOX-CORR
PPM
0.5CO
0.495
0.492
0.477
0.466
0.455
0.437
0.425
0.413
0.397
0.383
0.367
0.356
0.344
0.329
0.316
0.303
0.290
0.273
0.265
0.255
0.242
0.238
0.219
0.208
0.198
0.190
0.181
0.173
1-C4=
PPM
0.217
0.205
0.178
0.161
0.143
0.127
0.115
0.101
0.090
0.078
0.066
0.062
0.056
0.051
0.046
0.039
0.036
0.031
0.027
0.024
0.022
0.018
0.016
0.014
0.012
0.010
******
O.OC8
0.006
-------
-e-
co
EC -122
BUTENE-1
1976 FEB 27
CLOCK
TIME
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
375.
390.
405.
420.
TS
DEG F
83.8
65. 0
£4.5
04.5
64.8
85.0
85.0
65.2
85.5
85.2
85.7
85.5
65.2
«5.0
85.5
86.0
85.2
66.0
66.2
86.5
86.2
8o.7
86.5
86.0
86.2
66.2
86.5
87.0
87.2
REL HUM
*
46.0
45.5
47.0
49.5
52.0
54.0
55.0
56.0
56.5
56.0
56.5
56.5
56.5
57.0
57.5
57.0
56.0
55.5
54.5
53.5
52.5
52.0
51.0
51.0
51.5
51.0
50.5
50.5
49.5
SSPOwER
KN
13.10
******
******
******
13.10
******
******
******
******
*****.*
******
******
13.20
******
******
******
13.10
******
******
******
******
******
******
******
13.60
******
******
******
******
RAOIOM
MW/CM2
0.405
******
******
******
0.400
******
******
0.403
0.407
0.412
******
******
0.425
******
******
******
0.403
******
******
******
0.403
******
******
******
0.407
0.400
0.412
0.410
0.412
HCHO VOL
L
25.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
******
-------
EC -123
BUTENE-1
1976 MAR 1
BEGIN 1RRA01ATICN 1000, 0.25 INCH PYREX FILTER
CORRECTION FOR DECAY IN Kl
HNC3 MONITORED USING MODIFIED MAST, SAMPLING RATE ISO ML/HIN
BECKMAN 6800 OFF CHAMBER 1022-1407
Cl-N ESTIMATED 0.6 PPB AT 1730
CO FACTOR 2.2/1.26, HN03 EST. 2 PPB/DIV
RADIOMETER CORRECTION -0.02 MW/CM2
T«0 AT 1000 PST
PAN
REL HUM
hCHO
REL INT
CALIB*
9
2
1
2
TS
REL HUM
SSPOWER
RAD10M
H20
NO
N02-CORR
CO
HN03
ACETALD
ACETONE
1-C4=
DEC K
X
Kb
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PFM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
INIT CCND
INIT CCNO
INIT CCND
INIT CCND
INIT CCND
INIT CCND
303.2
66.03
13.28
0.502
2.666E 04
0.401
0.106
1.861
0.004
0.001
0.002
0.404
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: hAVELENGTH(NM)
500.
430.
403.
386.
370.
360.
350.
340.
330.
320.
310.
300.
290.
Kl=0.28 MIN-1
SAMPLING RATE * 1.876 L/MIN
66 GC SAMPLES TAKEN
REL.
INTENSITY
1.786
1.684
.1.510
1.397
1.281
1.156
1.000
0.760
0.535
0.291
0.118
0.042
0.0
-------
6C -123
BUTENE-1
1976 MAR 1
CLOCK
TIME
1000
1015
1030
1045
1100
UlS
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
150J
1515
1530
1545
loGo
1615
1630
1645
1700
1715
1730
ELAPSED
T(MIM)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
130.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
OZONE
PPM
0.0
0.0
0.002
0.015
0.02C
0.044
0.064
O.OS5
0.125
0.149
0.178
0.198
0.227
0.247
0.269
0.291
0.215
0.335
0.352
0.379
0.393
0.415
0.435
0.452
0.469
C.4S1
0.491
0.501
0.503
0.506
0.506
NO
PPM
0.401
0.324
0.247
0.188
C.13S
0.094
C.072
0.057
0.045
0.038
C.031
0.027
0.024
c.oia
0.016
0.015
C.013
0.012
0.011
0.011
C.010
0.009
0.009
O.OC7
C.007
0.007
0.006
0.006
0.006
0.006
0.006
N02-CQRR
PPM
0.106
0.17S
0.232
0.271
0.313
0.323
0.322
0.315
0.307
0.292
0.277
0.259
0.242
0.225
0.207
0.188
0.170
0.154
0.136
O.J117
0.1C7
O.C88
O.C76
0.065
0.052
0.041
0.030
C.029
0.028
0.028
0.026
NOX-CORR
PPM
0.505
0.499
0.477
0.459
0.443
0.413
0.395
0.374
0.351
0.330
0.306
0.285
0.265
0.243
0.224
0.202
0.183
0.166
0.147
0.126
0.115
0.095
0.084
0.073
0.059
0.047
0.037
0.035
0.034
0.032
0.032
1-C4-
PPM
0.404
0.356
0.320
0.281
0.246
0.218
0.191
0.164
0.147
0.127
0.111
0.092
0.080
0.066
0.057
0.047
0.039
0.032
0.026
0.021
0.017
0.013
0.011
O.OC8
0.006
O.JOS
0.003
0.003
0.002
******
0.002
-------
EC -123
6UTENE-1
1976 MAR 1
CLOCK
TIME
1000
1015
1030
1045
1100
1115
1130
1145
uoo
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
loOO
1615
Io30
1645
1700
1715
1730
ELAPSED
TCMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
CO
PPM
1.88
1.90
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
2.29
2.31
2.35
2.37
2.38
2.48
2.46
2.51
2.54
2.50
2.64
2.58
2.67
HN03
PPM
0.004
0.005
0.006
O.C06
******
0.002
0.006
0.005
0.003
0.004
0.007
c.ooa
0.010
******
0.008
0.008
0.008
0.008
0.008
******
******
******
******
******
******
0.004
0.004
C.OOS
0.005
******
******
PAN
PPM
0.000
******
0.001
******
0.002
******
O.C05
******
0.007
******
0.012
******
0.017
******
0.021
******
0.026
******
******
******
0.040
******
0.047
******
0.055
******
0.060
******
******
******
0.065
PPN
PPM
0.000
******
0.002
******
0.010
******
0.020
******
0.031
******
0.042
******
0.052
******
0.058
******
C.064
******
******
******
0.076
******
0.077
******
0.079
******
0.085
******
******
******
0.076
HCHO
PPM
0.0
******
******
******
0.127
******
******
******
0.149
******
******
******
0.171
******
******
******
0.171
******
******
******
o.iai
******
******
******
0.147
******
******
******
0.119
******
******
ACETALO
PPM
0.0015
******
0.0058
******
0.0133
******
0.0288
******
0.0273
******
0.0351
******
0.0407
******
0.0421
******
0.0495
******
0.0534
******
0.0525
******
******
******
0.0587
******
******
******
0.0554
******
0.0539
PROPALO
PPM
0.0002
******
0.0613
******
0.0975
******
0.1230
******
0.1250
******
0.1310
******
0.1290
******
0.1110
******
0.1140
******
0.0998
******
0.0790
******
0.0852
******
0.0687
******
0.0502
******
0.0464
******
0.0382
ACETONE
PPM
0.0019
******
0.0044
******
0.0068
******
0.0095
******
0.0106
******
0.0108
******
0.0144
******
0.0168
******
0.0201
******
0.0188
******
' 0.0202
******
0.0263
******
0.0260
******
0.0185
******
0.0267
******
0.0289
BUTYRAL
PPM
0.0002
******
******
******
0.0011
******
0.0016
******
0.0018
******
0.0022
******
0.0022
******
0.0022
******
0.0023
******
0.0022
******
0.0018
******
0.0023
******
0.0023
******
0.0020
******
0.0023
******
0.0023
BUOX
PPM
0.0000
******
0.0006
******
0.0012
******
0.0020
******
0.0023
******
0.0026
******
0.0030
******
0.0027
******
0.0031
******
O.U030
******
0.0025
******
0.0035
******
0.0035
******
0.0030
******
0.0031
******
O.OOjO
C2-N
PPM
0.0
******
0.0
******
0.0
******
0.0003
******
O.C004
******
C.0004
******
0.0006
******
0.0007
******
0.0006
******
******
******
0.0011
******
0.0011
******
0.0011
******
0.0014
******
0.0014
******
0.0014
-------
EC -123
flUTENE-l
1976 MAR 1
CLOCK ELAPSED
TINE T(HIN)
1000 0.
1015 15.
1030 30.
10*5 45.
1100 60.
1115 75.
1130 90.
1145 105.
1200 120.
1315 155.
1230 150.
1245 165.
1300 160.
IMS 195.
1330 210.
1345 225.
1400 240.
1415 255.
1430 270.
1445 285.
1500 300.
1515 315.
1530 330.
1545 345.
1600 360.
1615 375.
1630 390.
1645 405.
1700 420.
1715 435.
1730 450.
TS
CEG F
84.3
84.3
83.3
83.5
83.3
84.0
84. 6
84.5
84.5
85.0
65.7
84.8
85.5
85.0
84.3
84.3
84.3
85.2
84.3
84.5
85.0
85.0
35.7
85.2
85.5
86.0
85.5
85.0
85.5
86.2
86.2
REL HUM
61.5
60.5
62.0
65.0
67. C
69.0
70.0
71.0
71.0
72.0
71.0
70.0
69.5
69.0
69.5
69.0
69.0
69.0
69.0
69.0
69.0
67.5
67.5
67.0
66.0
65.5
65.5
65.0
65.0
65.0
64.5
SSPCfcER
Kh
13.10
******
******
******
******
******
******
******
******
******
13.30
******
******
******
13.30
******
******
13.60
******
******
******
13.10
******
******
******
******
******
******
RAOICM
MK/CM2
0.395
0.383
0.390
******
0.398
0.405
******
******
******
******
******
******
0.410
******
******
******
0.415
******
******
******
0.412
******
******
******
0.429
0.412
******
******
0.410
0.400
0.412
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
-------
EC -124
BUTENE-1
1976 MA« Z
BEGIN IRRADIATION 0945t 0.25 INCH PVREX FILTER
CORRECTION FOR DECAY IN Kl
HN03 MONITORED USING MODIFIED MAST i SAMPLING RATE 150 ML/M1N
(JECKMAN 6600 OFF CHAMBER C956-1038
GC-MS SAMPLES TAKEN AFTER RUN
CO FACTOR 2.2/1.24, HN03 EST. 2 PPB/CIV
RADIOMETER CORRECTION -0.017 MKI/CM2
T«0 AT 945 PST
PAN
REL HUM
HCHQ
REL INT
CALIB*
9
2
1
2
00
TS
REL HUM
SSPOWER
RAOIOM
H20
NO
N02-CORR
CO
HN03
ACETALD
ACETONE
1-C4»
DEC K
X
KM
KW/CM2
PPM
PPM
PPM
PPK
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
INIT COND
INIT CGNO
INIT CCND
INIT CCND
INIT CCND
INIT COND
302.6
J9.S6
13.37
0.401
2.442E 04
C.608
0.385
1.872
O.C04
0.001
0.002
C.424
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: fcAVELENGTHCNMJ
500.
430.
403.
360.
370.
360.
350.
340.
330.
320.
310.
300.
290.
Kl=0.27 MIN-1
SAMPLING RATE - 1.9C6 L/MIN
68 GC SAMPLES TAKEN
REL,
INTENSITY
1.705
1.721
1.555
1.403
1.288
1.166
l.COO
0.772
0.519
0.304
0.129
0.045
0.0
-------
EC -124
SUT6NE-1
1976 MAR 2
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1443
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
160J
1815
1330
1845
1900
1915
1930
1945
2000
2015
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
510.
525.
540.
555.
570.
585.
600.
615.
630.
OZONE
PPM
0.0
0.0
0.0
0.002
O.Q02
0.005
0,007
0.007
0.010
0.012
0.015
0.015
0.020
0.022
0.024
0.032
0.037
0.039
U.044
0.054
0.056
0.061
0.068
0.076
0.083
0.090
0.103
0.103
0.117
0.125
0.129
0.142
0.149
0.15S
0.166
0.178
0.188
0.193
0.208
0.217
0.227
0.237
0.247
NO
PPM
0.608
0.572
G.540
0.503
0.479
0.442
C.413
0.38'
0.362
0.327
C.303
0.278
0.259
C.237
0.715
0.200
0.188
0.166
C.154
0.139
0.129
C.120
0.103
C.100
0.090
0.083
0.078
C.066
0.064
0.059
0.051
0.049
0.042
0.042
C.Q34
0.034
0.032
0.029
0.029
0.024
0.022
C.022
0.022
N02-CORR
FPM
0.365
0.402
0.426
0.439
0.458
0.476
0.466
0.497
0.5C7
0.515
0.525
0.528
0.532
0.534
0.535
0.530
0.523
0.523
0.519
0.514
0.5C7
0.500
0.5C1
0.424
0.475
0.465
0.447
0.447
0.430
0.413
0.409
0.398
0.386
0.370
0.365
0.352
0.336
0.324
0.310
O.i99
0.268
0.270
0.259
NOX-CORR
PPM
0.996
0.976
0.968
0.945
0.937
0.918
0.899
0.880
0.664
0.842
0.828
0.807
0.791
0.770
0.748
0.728
0.711
0.685
0.673
0.656
0.637
0.618
0.604
0.564
0.565
0.545
0.527
0.513
0.493
0.474
0.460
0.446
0.428
0.414
0.399
0.384
0.368
0.351
0.337
0.323
0.310
0.294
0.276
1-C4«
PPM
0.424
0.369
0.355
0.332
0.306
0.276
0.258
0.237
0.213
0.203
0.161
0.165
0.156
0.143
0.112
0.117
0.108
0.095
0.086
0.080
0.071
0.065
0.062
0.056
0.050
0.044
0.040
0.036
0.033
0.026
0.026
0.023
0.019
0.017
0.015
0.014
0.012
0.010
0.009
0.008
0.007
0.006
0.005
-------
Ui
o
EC -124
BUTENE-i
1976 MAR 2
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
14*5
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
1600
1815
1830
1845
1900
1915
1930
1945
2000
2015
ELAPSED
T(HIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
510.
525.
540.
555.
570.
585.
600.
615.
630.
CO
PPM
1.67
1.88
****** ,
******
1.94
1.94
1.93
1.98
2.01
1.98
2.03
2.05
2.04
2.09
2.11
2.16
2.15
2.16
2.18
2.24
2.26
2.26
2.30
2.30
2.34
2.36
2.37
2.42
2.45
2.46
2.50
2.53
2.57
2.49
2.58
2.67
2.58
2.67
2.67
2.73
2.70
2.76
2.73
HN03
PPM
0.004
0.003
0.001
6.001
0.003
0.003
0.003
0.003
0.003
0.002
C.O
0.002
0.004
0.003
O.U06
0.006
C.004
0.003
0.003
0.002
0.002
0.005
0.004
C.004
O.OCd
0. 006
0.004
0.007
C.008
0.008
******
0.010
0.011
C.010
0.009
0.009
C.010
0.011
0.010
C.011
0.013
0.010
C.008
PAN
PPM
0.000
******
0.001
******
0.001
******
O.OC1
******
0.002
******
0.003
******
0.004
******
0.005
******
O.OC7
******
O.OC9
******
0.011
******
0.013
******
0.015
******
0.018
******
0.020
******
******
******
0.025
******
0.028
******
0.030
******
0.033
******
0.036
******
0.038
PPN
PPM
0.000
******
0.001
******
0.003
******
0.006
******
0.008
******
0.012
******
0.013
******
0.018
******
0.021
******
0.023
******
0.025
******
0.026
******
0.028
******
0.031
******
0.033
******
0.034
******
0.035
******
0.036
******
0.036
******
0.036
******
0.036
******
0.036
HCHO
PPM
0.0
******
******
******
0.068
******
******
******
0.079
******
******
******
0.125
******
******
******
0.161
******
******
******
0.127
******
******
******
0.157
******
******
******
0.145
******
******
******
0.131
******
******
******
0.123
******
******
******
0.115
******
******
ACETALO
PPM
0.0010
******
0.0037
******
0.0085
******
0.0141
******
0.0214
******
0.0295
******
0.0349
******
0.0415
******
0.0466
******
0.0499
******
0.0565
******
0.0613
******
0.0645
******
0.0669
******
0.0680
******
0.0704
******
a. 0731
******
0.0653
******
0.0720
******
0.0699
******
0.0700
******
******
PROPALD
PPM
0.0002
******
0.0417
******
0.0698
******
0.0893
******
0.1070
******
0.1110
******
0.1190
******
0.1190
******
0.1170
******
0.1130
******
0.1110
******
0.1080
******
0.1030
******
0.0968
******
0.0913
******
0.0819
******
0.0773
******
0.064C
******
0.0645
******
0.0576
******
0.0516
******
******
ACETONE
PPM
0.0023
******
0.0050
******
0.0045
******
0.0069
******
0.0097
******
0.0096
******
0.0128
******
0.0116
******
0.0122
******
0.0160
******
0.0192
******
0.0229
******
0.0270
******
0.0305
******
0.0318
******
0.0281
******
0.0322
******
0.0348
******
0.0428
******
0.0417
******
0.0607
******
******
BUTYRAL
PPM
0.0002
******
0.0013
******
0.0020
******
0.0029
******
0.0035
******
0.0037
******
0.0041
******
0.0041
******
0.0041
******
0.0038
******
0.0038
******
0.0035
******
0.0034
******
0.0031
******
0.0029
******
0.0027
******
0.0025
******
0.0021
******
0.0021
******
0.0019
******
0.0017
******
******
BUOX
PPM
0.0
0.0000
******
0.0014
******
0.0026
******
0.0038
******
0.0049
******
0.0055
0.0064
******
0.0070
******
0.0073
******
O.OJ77
******
O.U077
******
0.0082
******
0.0064
******
0.0065
******
0.0067
******
0.0084
******
0.0064
******
0.0077
******
0.0084
******
0.0079
******
0.0079
******
******
ME-N
PPM
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0001
******
0.0003
******
0.0003
******
0.0003
******
0.0006
******
0.0006
******
0.0008
******
0.0010
******
0.0011
******
0.0013
******
0.0013
******
0.0014
******
0.0014
******
0.0015
******
0.0017
******
0.0017
C2-N
PPM
0.0
******
0.0
******
0.0
******
0.0004
******
0.0003
******
0.0006
******
0.0006
******
0.0008
******
O.C/Olu
******
o.ooir
****«:,.
0.0014
******
0.0014
******
0.0018
******
0.0020
******
0.0020
******
0.1,021
******
0.0021
******
0.0022
******
0.0022
******
0.0022
******
0.0024
******
0.0025
-------
EC -124
dUTENE-1
1976 MAR 2
CLOCK
TIME
9*5
1000
1015
1030
1045
1100
Ilia
1130
1145
UOO
1215
1230
1245
1300
1315
1330
1345
14uO
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
1800
IblS
1830
1645
1900
1915
1930
1945
2000
2015
ELAPSED
T(HIN>
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
510.
525.
540.
555.
570.
585.
600.
615.
630.
TS
DEC F
******
84.8
83.3
84.3
83.3
84.3
84.3
84.8
83.6
83.5
64.0
84.5
84.5
83.5
83.5
64.3
85.2
84.8
84.5
84.8
85.0
85.7
85.5
86.0
85.2
85.7
86.0
85.7
85.7
86.2
86.0
86.7
86.2
86.2
66.0
66.2
66.0
86.2
66.0
66.5
87.0
86.7
85.7
REL HUH
%
45.0
45.0
47.5
52.5
56.5
60.5
62.0
63.5
63.5
63. C
63.0
63.0
63.0
62.5
63.5
63.0
62.5
62.5
62.0
61.5
61.0
61.0
60.5
61.0
60.5
60.5
60.5
60.5
61.0
60.5
60.0
60.0
60.0
60.5
60.5
60.5
60.0
60.5
60.5
60.0
60.0
59.5
59.5
SSPOhER
KM
13.20
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
13.20
******
******
******
******
******
******
13.50
******
******
******
******
******
13.40
******
13.30
13.40
******
******
12.50
******
******
******
13.50
******
******
RACIOM
MW/CM2
******
******
******
******
0.406
******
******
******
0.398
******
******
******
0.406
******
******
******
******
******
******
******
0.408
0.391
0.393
0.401
0.403
******
******
******
0.415
0.396
0.396
0.406
0.396
******
******
******
0.403
******
******
******
0.418
0.396
0.396
HCHO VOt
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
-------
N?
cC -142
cTHENE
1976 APR 1
BEGIN IRRADIATION 0915f 0.25 INCH PVREX FILTER
PROPALD.ACETCNEtETOX.&ACETALD MCNITORED 8V 3-PART COLUMN
CO FACTOR 2.2/1.24,
RADIOMETER CORRECTION -0.013 Nh/CM2
T=0 AT 915 PST
CALI6*
PAN
REL HUM
HCHO
REL INT
TS
REL HUM
SSPowER
RADIOM
HiO
NO
N02-CCRR
CO
hCMu
ACcTALO
ACETONE
ETHENE
OEG K
X
Kl»
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
3
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCND
INIT CCND
INIT COND
INIT CCND
INIT CCND
INIT CCND
303.0
63.37
15.89
0.486
2.434E 04
0.222
0.158
2.262
0.050
C.005
0.005
C.S49
ASSIGNED INITIAL CCNDITIQN
SPECTRAL DISTRIBUTION:
hAVELENGTHJNM)
500.
430.
403.
360.
370.
360.
350.
340.
330.
320.
310.
300.
290.
REL.
Kl=0.34 MIN-1
SAMPLING RATE = 1.715 L/MIN
42 tC SAMPLES TAKEN
INTENSITY
2.195
1.942
1.785
1.553
1.396
1.196
1.000
0.722
0.474
0.251
O.CS9
O.C19
0.0
-------
Ui
GJ
EC -142
ETHENE
1976 APR 1
CLOCK
TIME
915
930
945
1000
1015
1030
1045
uoo
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.0
0.0
0.010
0.020
0.034
0.054
0.078
0.100
0.132
0.166
0.203
0.239
0.288
0.327
0.376
0.427
0.489
0.542
0.598
0.652
0.699
0.733
0.760
0.772
0.782
NO
PPM
0.322
C.280
0.227
0.177
0.143
0.111
0.092
0.070
C.C60
0.050
0.042
0.034
0.027
0.022
C.020
C.C16
0.012
C.011
0.013
0.009
0.009
0.007
0.007
0.010
C.010
N02-CORR
PPM
0.158
0.191
0.222
0.260
0.279
0.2S5
0.2So
0.303
0.298
0.288
0.276
0.264
0.250
0.232
0.210
0.190
0.166
0.116
0.113
0.102
0.083
0.067
0.055
0.044
0.038
NOX-CORR
PPM
0.480
0.471
0.450
0.438
0.422
0.406
0.390
0.374
0.357
0.338
0.318
0.299
0.277
0.255
0.229
0.206
0.182
0.157
0.131
0.109
0.093
0.076
0.063
0.056
0.047
ETHENE
PPM
0.949
0.914
0.870
0.839
0.807
0.775
0.748
0.717
0.689
0.6SS
0.628
0.593
0,566
0.534
0.500
0.469
0.430
0.395
0.357
0.328
0.298
0.267
0.245
0.223
0.203
CO
PPM
2.26
2.23
2.23
2.24
2.29
2.30
2.33
2.38
2.47
2.49
2.54
2.53
2.57
2.66
2.67
2.72
2.80
2.63
2.89
2.93
2.99
3.04
3.11
3.18
3.20
PAN
PPM
0.000
0.000
******
0.001
******
0.001
******
0.002
******
0.002
******
0.003
******
0.004
******
0.005
******
0.007
******
0.009
******
0.010
******
0.012
HCHO
PPM
0.050
******
******
******
0.068
******
******
******
0.111
******
******
******
0.161
******
******
******
0.191
******
******
******
0.207
******
******
******
0.177
ACETALO PROPALO ACETONE BUTVRAL
PPM PPM PPM PPM
0.0049
******
0.0049
******
0.0056
******
0.0066
******
0.0071
******
0.0086
******
0.0094
******
0.0110
******
0.0113
******
0.012o
******
0.0130
******
0.0134
******
0.0137
0.0004
******
0.0005
******
0.0008
******
0.0012
******
0.0017
******
0.0027
******
0.0036
******
0.0047
******
0.0056
******
0.0069
******
0.0077
******
0.0062
******
0.0083
0.0053
******
0.0079
******
0.0085
******
0.0114
******
0.0140
******
0.0194
******
0.0225
******
0.0259
******
0.0283
******
0.0323
******
0.0373
******
0.0394
******
C.C432
0.0002
******
0.0003
******
******
******
******
******
0.0004
******
******
******
******
******
******
******
0,0011
******
******
******
******
******
******
******
0.0037
ETOX
PPM
0.0
******
0.0
******
0.0002
******
0.0002
******
0.0002
******
0.0003
******
0.0003
******
0.0004
******
0.0004
******
0.0004
******
******
******
******
******
0.0006
-------
Ul
EC -142
ETHENE
1976 APR 1
CLOCK
TIME
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
123J
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1315
ELAPSED
TiMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC F
83.0
86.4
85.0
65.2
85.5
85.5
84.8
85.5
85.5
86.0
85.7
86.0
86.2
86.2
86.0
86.5
86.2
86.0
85.2
85.5
85.5
66.0
85.2
85.2
85.7
REL HUH
*
61.5
61.0
62.5
64.0
65.0
65.0
65.5
65.5
66.0
65.5
65.5
65.5
66.0
65.0
64.5
64.5
64.0
64.0
64.0
63.5
63.5
63.0
63.0
63.0
63.0
SSPOMER
KM
******
******
15.90
******
16.00
******
******
******
15.80
******
******
******
16.00
******
******
******
15.90
******
******
******
15.70
******
******
******
15.90
RAOIOM
MU/CM2
******
0.490
0.485
0.480
0.502
******
******
******
0.480
0.490
******
******
0.471
******
******
******
0.485
******
******
0.433
0.473
0.478
0.488
0.473
0.478
HCHO VOL
L
20.00
******
**** **
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
Ui
EC -143
ETHENE
1976 APR12
BEGIN IRRADIATION 0915, 0.25 INCH PVREX FILTER
PROPALDfACETGNEiETOXiSACETALD MCNITOREO BY 3-PART COLUMN
CO FACTOR 2.2/1.20
RADIOMETER CORRECTION -0.012 M1./CH2
T=0 AT 915 PST
CALIB*
PAN
fiEL HUM
HCHO
REL INT
TS
REL HUM
SS POKER
RAOIOM
H20
NO
N02-OORR
CC
ACETALD
ACETONc
ETHENE
DEC K
*
KW
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
3
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
IMF CCNO
JNIT CCNO
IN1T CCNO
INIT CCNO
INIT CCNO
INIT CCNO
302.1
57. 94
15.83
0.481
Z.285E 04
0.390
C.110
2.123
0.002
O.C03
2.027
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION:
hAVELENGTH(NH)
SCO.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
REL.
Kl«0.33 MIN-1
SAMPLING RATE » 1.763 L/MIN
54 GC SAMPLES TAKEN
INTENSITY
2.167
1.936
1.787
1.539
1.373
1.202
1.000
0.720
0.477
0.251
C.090
0.021
0.0
-------
Ui
EC -143
ETHENE
1976 APA12
CLOCK
TIME
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.0
0.002
0.024
0.031
0.151
0.261
0.396
0.547
0.7C6
0.843
0.953
1.021
1.065
1.062
1.087
1.082
1.065
1.036
1.016
0.992
0.962
0.933
0.904
0.877
0.648
NO
PPM
0.390
C.291
0.172
C.092
0.046
0.028
0.017
0.012
0.010
0.009
O.OC9
0.007
0.007
C.C07
0.007
O.OC7
0.007
C.007
0.007
0.007
O.OC7
0.007
0.007
0.007
0.007
N02-CORR
PPM
0.110
0.1S5
0.295
0.351
0.375
0.360
0.333
0.291
0.243
0.193
0.155
0.122
0.092
0.074
0.062
0.053
0.045
0.038
O.OJ5
0.032
0.032
0.027
0.028
0.026
0.026
NOX-CORR
PPM
0.500
0.487
0.469
0.444
0.423
0.387
0.352
0.305
0.252
0.202
0.163
0.128
0.099
0.082
0.069
0.059
0.052
0.047
0.041
0.040
0.038
0.036
0.036
0.033
0.033
ETHENE
PPM
2.027
1.915
1.833
1.751
1.654
1.570
1.469
1.365
1.262
1.139
1.046
0.945
0.864
0.803
0.739
0.690
0.645
0.602
0.564
0.531
0.50o
0.471
0.444
0.420
0.402
CO
PPM
2.18
2.14
2.12
2.25
2.26
2.36
2.43
2.56
2.63
2.78
2.84
3.01
3.09
3.24
3.30
3.41
3.52
3.60
3.72
3.73
3.76
3.86
3.95
4.05
PAN
PPM
0.000
******
0.000
******
0.001
******
0.001
******
0.003
******
0.004
******
0.006
******
0.007
******
0.008
******
0.009
******
0.009
******
0.010
******
0.009
HCHO
PPM
0.0
******
******
******
0.298
******
******
******
0.705
******
******
******
0.937
******
******
0.967
******
******
******
******
0.765
******
******
******
0.695
ACETALD
PPM
0.0020
******
0.0040
******
0.0055
******
O.OOSJ
******
0.0113
******
0.0137
******
0.0129
******
0.0171
******
0.0167
******
0.0160
******
0.0161
******
0.0187
******
0.0192
PftOPALO
PPM
0.0003
******
0.0007
******
0.0019
******
0.0047
******
0.0073
******
0.0095
******
0.0091
******
0.0107
******
0.0103
******
U.0099
******
0.0067
******
0.0093
******
0.0093
ACETONE
PPM
0.0031
******
0.0063
******
0.0146
******
0.0285
******
0.0338
******
0.0400
******
O.CJ25
******
0.0419
******
0.0386
******
0.0423
******
0.0361
******
0.0400
******
0.0423
6UTVRAL
PPM
******
******
******
******
******
******
******
******
0.0026
******
******
******
******
******
******
******
0.0045
****:
******
******
******
******
******
0.0044
ETOX
f PH
0.
******
0.0002
******
******
0.0003
******
0.0005
******
O.OOCd
******
O.uCilu
******
0.0014
»*^*»*
0.0016
»**»**
0. 00 1 6
******
0.0017
******
0.0021
******
0.0022
-------
Ul
EC -143
ETHENE
1976 APR12
CLOCK
TIME
915
930
945
1003
101S
1030
104S
1100
1115
1130
1145
1ZOO
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
ELAPSED
TtMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
iao.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
OEG F
64.3
85.2
84.3
83.8
83.0
84.3
84.0
84.3
83.5
63.3
83.5
83.5
83.5
64.0
84.0
84.5
84.5
64.3
84.5
84.5
84.8
84.8
84.8
85.0
85.0
REL HUH
a
40.5
41.0
43.5
47.5
53.0
58.5
61.0
61.0
61.5
62.0
61.5
61.5
61. 5
61.0
61.0
61.0
61.0
61.0
61.0
60.5
60.5
60.5
60.5
60.5
60.5
SSPOMER
Kh
******
******
15. SO
******
15.60
******
******
******
16.10
******
******
******
******
******
******
******
16.20
******
******
******
15.60
******
******
******
15.60
RADIOM
MM/CH2
******
0.477
0.486
0.484
0.479
0.479
******
******
0.496
0.459
******
******
0.464
0.469
******
******
0.511
******
******
******
0.479
******
******
******
0.481
HCHO VOL
I,
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
20.00
******
******
******
******
20.00
******
******
******
20.00
-------
EC -144
ETHENE + PROPENE
1976 APR15
BEGIN IRRADIATION 0915! 0.25 INCH PYREX FILTER
AT 1515 HOURS ESTIMATE Cl-N « 0.5 PP6
ETOX MONITORED EY 3-PART COLUMN
CO FACTOR 2.2/1.24
RADIOMETER CORRECTION -0.005 MW/CW2
T=0 AT 915 PST
PAN
REL HUM
HCHO
REL INT
CALIB#
9
2
1
3
Ln
co
TS
REL HUM
SSPOwErt
SADIGM
H20
NO
N02-CORR
CO
HCrlO
ACcTALD
ACETONE
ETHENE
PfvOPENE
DEG K
X
KW
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCNO
INIT CCND
INIT CCND
INIT CCND
INIT CCND
INIT CCND
INIT CCND
302.6
60.55
15.S4
C.485
2.468c 04
C.398
0.111
2.271
C.020
C.C05
O.C03
2.027
0.221
ASSIGNED INITIAL CCNCITION
SPECTRAL DISTRIBUTIONS KAVEL£\GTH(NMJ
5CC.
430.
403.
360.
370.
360.
350.
340.
330.
320.
310.
300.
290.
Kl»0.33 MIN-1
SAMPLING RATc * 1.762 L/MIN
55 C.C SAMPLES TAKEN
REL.
INTENSITY
2.245
982
812
560
39b
202
000
717
476
250
088
0.021
0.0
-------
ec -144
ETHENE + PRCPENE
1976 APR15
CLOCK
TIME
915
930
945
1000
Iul5
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
13-«5
1400
»415
1430
1445
1500
1515
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
10?.
120.
135.
150.
Io5.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.0
0.007
0.046
0.142
0.266
0.430
0.576
0.755
0.9C9
0.992
1.043
1.060
1.060
1.036
1.016
0.999
C.970
0.936
0.909
0.882
0.852
0.630
0.806
0.787
0.767
NO
PPM
0.398
0.259
C.120
C.060
C.029
0.016
0.012
C.010
0.007
C.007
C.006
0.007
C.007
C.OC7
0.006,
0.006
C.006
0.007
O.C06
O.OC6
C.OC6
O.C06
0.006
C.C06
0.006
N02-CQRR
PPM
0.111
0.231
0.346
0.377
0.367
0.331
0.277
0.216
0.159
0.118
0.065
0.065
0.045
0.033
0.026
0.023
0.019
0.016
0.014
0.015
0.014
O.C13
0.013
O.C11
0.012
NOX-CORR
PPM
0.509
0.4SO
C.468
0.435
0.398
0.343
0.288
0.225
0.163
0.125
0.091
0.073
0.053
0.041
0.034
0.030
0.025
0.023
0.021
0.021
0.021
0.020
0.019
0.017
0.019
ETHENE
PPM
2.027
1.939
1.652
1.770
1.682
1.594
1.464
1.356
1.249
1.141
1.044
0.970
0.866
0.829
0.776
0.736
0.692
0.657
0.623
a. 5 86
0.552
0.529
0.5C1
0.477
0.453
PROPENE
PPM
0.221
0.199
0.170
0.146
0.115
0.092
0.061
0.049
0.032
0.025
0.014
0.010
0.007
0.005
0.003
0.002
0.002
0.001
0.001
0.001
0.001
O.OOl)
0.000
0.000
0.000
-------
EC -144
ETHENE * PROPENE
1976 APR15
ON
O
CLOCK
TIME
915
930
945
10UO
1015
1030
1045
UCv>
1115
1130
1145
1200
1215
1230
1245
UOO
1315
1330
1345
14UO
1415
1430
1445
1500
I5i5
ELAPSED
TIMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
2.27
2. 28
2.29
2.28
2.34
2.41
2.48
2.63
2.73
2.60
2.95
3.04
3.11
3.30
3.31
3.44
3.42
3.61
3.66
3.72
3.77
3.92
3.94
3.97
4.03
PAN
PPM
c.ooo
******
C.002
******
C.010
******
C.027
******
0.048
******
0.062
******
0.071
******
C.075
******
0.075
******
C.074
******
C.071
******
0.069
******
0.067
HChO
PPM
0.020
******
******
******
0.363
******
******
******
0.765
******
******
******
0.646
******
******
******
0.705
******
******
******
0.715
******
******
******
0.624
ACETALO
PPM
0.0047
******
******
******
0.0868
******
0.1050
******
0.1080
******
******
******
0.0944
******
******
******
0.0824
******
******
******
0.0733
******
******
******
0.0660
PROPALO
PPM
0.0002
******
0.0009
******
0.0035
******
0.0060
******
0.0083
******
******
******
0.0072
******
******
******
0.0082
******
******
******
0.0068
******
******
******
0.0063
ACETLNE
PPM
0.0033
******
0.0071
******
0.0304
******
0.0369
******
0.0401
******
******
******
0.0464
******
******
******
0.0394
******
******
******
0.0355
******
******
******
0.0335
BUTYRAL
PPM
0.0003
******
0.0001
******
0.0013
******
0.0027
******
0.0039
******"
******
******
0.0042
******
******
******
0.0041
******
******
******
0.0034
******
******
******
0.0031
ETOX
PPM
******
******
0.0
******
******
******
0.0005
******
******
******
0.0012
******
******
******
0.0017
******
******
******
0.0020
******
******
******
0.0021
******
******
PftOX
PPM
0.0
******
0.0004
******
0.0009
******
0.0013
******
O.OOli
******
******
******
0.0015
******
******
******
0.0012
******
******
******
0.0013
******
******
******
0.0014
-------
EC -144
ETHENE +• PROPENE
1976 APR15
CLOCK
TIME
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
;soo
1515
ELAPSED
T
-------
10
EC -145
ETHENE * PRCPENE
1976 APR16
6EG1N IRRADIATION 0900, 0.25 INCH PYREX FILTER
ETOX MONITORED BY 3-PART COLUMN
CO FACTOR 2.2/1.22
RADIOMETER CORRECTICN -0.005 MK/CC2
T=0 AT 900 PST
CALIB«
PAN
REL HUM
HCHQ
REL INT
TS
REL HUM
SSPOHEh
RADIOM
H20
NU
N 02 -CORK
CO
HCMO
ACETALO
PROPALO
ACETONE
ETriENE
PROPENE
DEC K
4
Kh
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
3
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCND
INIT CCND
INIT CCND
INIT CCND
INIT COND
IMT CCND
INIT CCNO
INIT CCND
202.8
60.01
16.03
0.467
2.456E 04
0.745
0.246
2.123
0.004
0.003
0.000
0.003
1.S49
0.428
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: hAVELENGTH
-------
EC -145
ETHENE * PROPENE
1976 APR16
ON
CLOCK
TJME
900
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
14GJ
1415
1430
1445
1500
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
130.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
3oO.
OZCNE
PPM
0.0
0.0
0.0
0.0
0.005
0.012
0.022
0.042
0.061
0.088
0.117
0.151
0.183
0.225
0.266
0.3C5
0.349
0.396
0.445
0.498
0.550
0.606
0.667
0.725
0.777
NO
PPM
0.745
C.660
C.559
0.459
C.379
0.305
C.247
0.195
C.156
0.122
0.098
0.031
0.059
0.051
0.042
C.034
0.027
0.022
0.020
0.015
0.012
C.012
C.010
O.C07
C.C10
N02-CORR
PPN
0.246
0.322
0.392
0.469
0.521
0.569
0.6C1
0.629
0.635
0.625
0.617
0.6C8
0.589
C.557
0.529
C.493
0.461
0.415
0.371
0.329
0.267
O.«i46
0.198
0.159
0.122
NOX-CORR
PPM
0.994
0.981
0.957
0.930
0.9C9
0.875
0.848
0.819
0.791
0.747
0.715
0.66o
0.653
0.6C8
0.56S
0.527
0.485
0.437
0.391
0.346
0.301
0.258
0.207
0.168
0.132
ETHENE
PPM
1.049
1.005
0.973
0.933
0.906
0.867
0.845
0.813
0.788
0.759
0.739
0.708
0.688
0.657
0.633
0.604
0.570
0.546
0.518
0.466
0.458
0.427
0.396
0.361
0.330
PROPENE
PPM
0.428
0.402
0.361
0.311
0.283
0.257
0.237
0.208
0.190
0.169
0.145
0.131
0.112
0.093
0.076
0.064
0.054
0.043
0.035
0.026
0.021
0.015
0.011
0.007
0.005
-------
EC -U5
ETHcNE * PRCPENE
1976 APR16
0\
CLOCK
TIME
900
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
IjOO
1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
KMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
2.42
2.33
2.40
2.36
2.36
2.35
2.50
2.44
2.54
2.64
2.63
2.68
2.73
2.75
2.90
2.91
2.95
3.06
3.06
3.18
3.17
3.27
3.34
3.44
3.51
PAN
PPM
C.OOO
******
0.001
******
C.004
******
0.009
******
C.017
******
0.026
******
0.029
******
0.046
******
0.055
******
0.063
******
0.079
******
C.098
******
0.112
HCHO
FPM
0.004
******
******
******
0.161
******
******
******
0.264
******
******
******
0.369
******
******
******
0.516
******
******
******
0.453
******
******
******
0.499
ACETALO
PPM
0.003
******
******
******
O.OS7
******
******
******
0.160
******
******
******
0.174
******
******
******
0.165
******
******
******
0.149
******
******
******
0.103
PROPALD
PPM
0.0005
******
******
******
0.0020
******
******
******
0.0036
******
******
******
0.0047
******
******
******
0.0055
******
******
******
0.0064
******
******
******
0.0068
ACETONE
PPM
0.0027
******
******
******
0.0045
******
******
******
0.0075
******
******
******
0.0113
******
******
******
0.0122
******
******
******
0.0154
******
******
******
0.0197
ETOX
PPM
0.0
******
0.0
******
******
******
0.0
******
******
******"
0.0
******
******
******
0.0
******
******
******
0.0
******
******
******
0.0008
******
0.001G
PROX
PPM
0.0000
******
******
******
0.0024
******
******
******
0.0045
******
******
******
0.0056
******
******
******
0.0060
******
******
******
0.0070
******
******
******
O.OC61
ME-N
PPM
0.0
******
0.0
******
0.0
******
0.0007
******
0.0009
******
0.0012
******
O.OOlo
******
0.0018
******
0.0020
******
0.0022
******
0.0026
******
0.0028
******
0.0030
-------
EC -145
ETHENE * PHOPENE
1976 APR16
Ul
CLOCK
TIME
900
915
930
9*5
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
KMINI
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC F
SO.S
68.9
67.2
65.2
65.0
65.0
65.0
65. i
85.7
85.2
B5.Z
85.2
85.5
65.0
85.7
85.0
65.2
65.0
65.2
b5.5
85.7
65.0
65.2
85.0
85.5
REL HUH
*
49.0
49.0
50.0
53.0
57.0
60.5
62.0
62.5
62.5
62.5
62.5
62.0
62.5
62.0
62.0
62.0
62.0
62.0
62.0
61.5
61.5
61.5
61.5
61.5
61.5
SSPOHER
Kh
******
******
16.20
******
******
******
******
***«.**
16.10
******
******
******
16.10
******
******
******
15.90
******
******
******
15.90
******
******
******
16.00
RAOIOM
MW/CM2
******
0.476
0.496
0.506
0.498
0.484
******
******
0.498
0.484
0.468
0.484
0.486
0.486
******
******
0.4S4
0.479
******
******
0.486
0.488
******
******
0.493
HCHO VOL
L
20.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
tC -146
TRANS-2-BUTtNE
1976 APR 12
IRRAOIATICN 0915t 0.25 INCH PVRcX FILTER
CO FACTjR 2.2/1.27
RADIOMETER COhficCTlCN -0.02i) «*/CM2
T*0 AT 915 PST
PAN
RcL HUM
HCrtQ
REL INT
CALIB*
9
2
1
3
TS
REL HUM
SbPJncK
RAOIOM
H2u
NO
*J2-CCRR
Ti-C4=
CO
ACETALO
AC£TON£
OcG K
t
KM
MX/CM2
PPM
PPM
PPM
PHM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGc
AVERAGE
INIT CLNO
INIT CCNO
IMT CCND
INIT CCNO
IMT CCNU
IMT CCNO
302.9
ts.36
U.bfl
O.'tdo
0
-------
EC -146
TRANi-2-OUTENE
1976 APR 12
CLOCK
UMt
915
930
945
1000
1015
1030
1045
11JO
1115
1130
1145
1200
1213
1230
12-.3
1300
1315
1330
1345
ItOO
1415
lt3J
1445
1500
1515
ELAPScO
TtHlNI
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ItiC.
195.
210.
225.
240.
255.
270.
2o5.
300.
315.
330.
345.
360.
OZQNfc
PPK
0.0
0.005
0.024
0.042
0.051
0.071
0.07o
G.09u
0.096
O.O'.B
0.12C
0.125
0.137
0.147
0.161
0.166
0.173
0.183
0.193
0.196
******
0.217
0.227
0.232
0.239
NO
PPM
0.385
C.267
C.U7
C.143
C.lll
C. ICO
0.081
0.063
0.074
C.067
C.064
u.055
C.033
0.04-i
0.045
J.C'iZ
C.04C
J.035
0.034
C.031
0.031
0.029
C.026
0.024
0.024
N02-COKR f
PPM
0.124
0.223
0,273
0.2ti9
0.2S7
0.291
0.20H
0.271
0.266
0.^5-)
0.240
0.2^i>
G.239
C.230
0.223
0.217
0.2C7
0.198
0.190
0.1U3
0.174
0.163
0.156
0.151
0.141
«W-CO*R
PPM
0.510
0.4U5
0.460
0.433
0.409
0.3ad
0.370
0.355
0.341
0.327
u.314
0.303
0.293
0.260
0.2oB
0.259
0.247
0.234
0.226
0.215
0.205
0.194
0.104
0.177
0,166
T2-C4»
PPM
0.231
0.14o
0.087
u.046
0.025
0.014
O.OC7
0.0 04
0.002
0.001
0.001
O.OG1
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0.001
0.000
-------
oo
EC -Ut>
TRANS-2-bUTENE
I97o APR 12
LCCK
TIME
915
930
945
1000
1015
1030
1045
1100
1115
1130
11-.5
1200
1215
1230
1243
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
ELAPSEC
TlrtlMI
0.
15.
30.
45.
60.
7s.
90.
105.
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165.
160.
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PPP
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2.10
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2.09
2.15
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2.22
2.20
2.25
2.20
2.28
2.24
2.31
2.32
2.44
2.45
2.42
2.40
2.44
2.49
2.43
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2.53
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PPM
0.000
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ON
ec -146
TRANS-2-BUTENfc
1976 APR 12
CLOCK
TIMe
915
930
9*5
IOOG
1015
1030
1045
UOJ
1115
113J
1145
UOO
1215
1230
124S
13UO
1315
1330
1345
1400
I4i5
1430
1445
1500
1515
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T(MIN)
0.
15.
30.
45.
bO.
75.
90.
105.
120.
135.
150.
105.
18U.
195.
210.
225.
240.
255.
270.
265.
300.
315.
•330.
345.
360.
TS
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81.3
64.3
63.5
64.3
84.5
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65.2
85.5
85.7
66.2
66.2
86.0
66.2
06.5
86.2
66.0
bb.O
66.0
65.5
65.5
65.5
65.7
66.0
86.0
85.7
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*
62.5
61.5
63. 0
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65.5
66.0
66.5
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66.5
66.5
60 .0
66.0
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66.0
66.5
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65.5
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65.0
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65.0
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16.50
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16.60
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0.481
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0.454
0.471
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******
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0.493
******
******
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0.495
0.491
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0.495
0.463
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0.486
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20.00
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20.00
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20.00
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******
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20.00
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20.00
-------
EC -147
TRANS-2-tlUTcNE
1976 APR U
ociilN IRRADIATION J830, 0.25 INCH PYREA FILTER
LO FACTOR 2.*/1.23
RAuIOMfcTcR CORRECTICN -0.017 MH/CM2
T=0 AT t)30 PbT
CALld*
PAN
RcL HUM
HCHO
SEL INT
TS
HEL HUM
SSPUnER
RADIO*
H20
NO
N02-CORR
T2-C4=
CO
HCHU
ACcTALD
ACETCNc
DEU K
X
KW
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PHM
9
3
1
3
AVERAGE
AVE-^Abt
AVErlAGE
AVERAGE
AVERAGE
INIT CC^O
INIT CCNO
INIT UNO
IMT COSO
INIT CliNO
IMT CCNO
INIT CCNO
302.2
t3.30
16.43
C.-.92
C.7ti2
C.iOO
0.^17
2.030
C.013
O.CC2
0.002
ASSIGNED INITIAL CONDITION
SPECTRAL OISTRI6UTICN:
500.
430.
403.
360.
370.
360.
350.
340.
330.
320.
310.
300.
290.
Kl«0.34 MIN-1
SAMPLING RATE » 1.784 L/MIN
56 GC SAMPLES TAKEN
REL<
INTENSITY
2.524
2.122
1.916
1.601
1.426
1.20U
.1. 000
0.707
0.456
0.230
O.C76
0.014
0.0
-------
EC -147
TKANS-2-dUTENE
1976 APR 13
CLOCK
TIMt
63J
845
900
915
930
945
looo
1U15
1030
1045
Uud
1115
1130
U45
1200
1215
1230
I2t5
13.JO
1315
133J
13*5
I4oo
1415
1430
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
Io5.
130.
195.
210.
225.
240.
255.
270.
2H5.
300.
315.
330.
345.
360.
OZGNE
PPP
0.0
0.0
0.005
0.012
O.u20
0.027
0.034
O.O42
0.0-.2
******
******
0.0u4
0.071
U.U01
0.083
O.C90
0.100
0.105
0.107
0.105
0.125
0.127
******
0.139
0. 154
NO
PPM
0.782
C.596
0.452
0.352
C.266
0.244
J.215
0. 193
C. 176
0. 161
0.149
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0.132
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0.117
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-------
EC -147
THANi-2-dUTENE
1976 APR 13
CLOCK
TIME
830
845
900
915
93J
945
1000
1015
i030
1043
1100
1115
1130
1145
1200
U15
12JO
1245
1300
1315
1330
U45
1400
1415
1430
ELAPSED
T(M1N)
0.
13.
30.
45.
bO.
75.
90.
105.
120.
135.
150.
165.
1UO.
195.
210.
225.
240.
255.
270.
i o5.
300.
315.
330.
345.
36U.
TS
OEG F
82.8
85.0
84.8
83.5
84.0
65.7
86.2
b5.7
66.0
66.0
65.7
85.5
86.0
67.0
87.9
85.7
86.5
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87.4
66.0
66.2
67.0
******
65.7
86.2
RfcL HUH
*
******
49.5
51.5
53.3
54. C
54.0
54.0
54.0
54.0
34. C
34.0
34.0
54.0
34.0
54. C
54.0
54.0
34.0
34.0
54.0
54.0
34.0
******
53.5
53.5
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******
16.30
******
******
16.60
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******
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16.60
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******
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16.50
******
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16.50
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16.20
******
******
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RADIO*
Mh/CM2
0.479
0.491
0.47o
0.491
0.466
******
******
******
0.3J1
******
******
0.303
0.496
******
******
******
0.501
******
******
0.484
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0.481
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0.49d
0.496
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20.00
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20.00
-------
EC -149
PROPENE * TRANS-2-BUTENE
1976 APR 16
oEGIN IRRADIATICN 0945, 0.25 INCH PYREX FILTER
CO FACTOR 2.2/1.21
RADIOMETER CORRECTION -0.009 Mh/CM2
T»0 AT 945 PST
PAN
REL HUM
HCHO
REL INT
CALIB*
9
2
1
3
TS
REL HUM
SSPOWER
RAD10M
H20
NO
N02-CORR
CO
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ACETONE
PROPENE
T2-C4*
DEC, K
!S
KW
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCND
INIT CCND
IMT CCND
INIT CCND
INIT CCND
INIT CCND
303.1
£3.62
16.35
0.475
2.450E 04
0.813
0.176
2.096
0.002
0.004
0.384
0.209
(ASSIGNED INITIAL CCNCITION
SPECTRAL DISTRIBUTION:
WWELENGTH(NM)
500.
430.
403.
360.
370.
360.
350.
340.
330.
320.
310.
300.
£90.
REL.
Kl=0.33 MIN-1
SAMPLING RATE = 1.779 L/KIN
49 GC SAMPLES TAKEN
INTENSITY
2.532
2.104
1.928
1.618
1.411
1.216
l.COO
0.698
0.453
0.236
0.083
0.019
0.0
-------
EC -1*9
PROPENE * TRANS-2-BUTENE
1976 APR 16
CLOCK
TIME
945
IOOJ
1015
1030
1045
UuO
1115
1130
1145
1200
1215
1230
1245
1500
1315
133u
1345
I4v0
1*15
1430
1445
1500
1515
1530
1545
ELAPSED
TCMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
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PPM
0.0
0.0
0.005
0.015
0.029
0.039
0.05o
0.066
0.076
O.C93
0.103
0.115
0.129
0.132
0.145
0.161
0.169
0.166
0.198
0.213
0.225
0.237
0.249
0.266
0.276
NO
PPM
0.813
C.596
C.440
C.320
0.249
C.1S3
0.169
0.139
C.127
0.112
C.098
C.090
0.083
0.066
0.064
0.059
0.054
C.049
C.046
C.044
0.039
C.037
0.032
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PPM
0.176
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0.542
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0.284
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PPM
0.989
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0.665
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0.562
0.560
0.537
0.514
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0.464
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0.420
0.396
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PROPENE
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0.384
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0.217
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0.133
0.115
0.100
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0.073
0.068
0.060
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0.037
0.032
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PPM
0.209
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0.001
0.001
0.001
0.000
0.001
0.001
-------
EC -149
PROPENE * TRANS-2-BUTENE
1976 APR 16
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
150J
1515
1530
1545
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
2.10
2.05
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2.22
2.29
2.31
2.34
2.42
2.40
2.43
2.46
2.45
2.50
2.53
2.47
2.59
2.63
2.58
2.68
2.67
2.74
PAN
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******
0.0006
******
0.0028
******
O.J030
******
0.0028
******
0.0029
******
0.0033
******
O.OU29
******
0.0029
******
0.0028
******
0.0029
******
0.0027
******
0.0026
PKOX
PPM
0.0001
******
******
******
0.0014
******
******
******
******
******
0.0032
******
O.C042
******
0.0042
******
0.0045
******
0.0047
******
O.GuSl
******
0.0050
******
0.0052
ME-N
PPM
0.0
******
0.0
******
0.0013
******
0.0020
******
O.ou2a
******
0.0026
******
0.0036
******
0.0039
******
0.0042
******
0.0045
******
0.0045
******
0.0050
******
0.0050
-------
fcC -1*9
PROPENE + TRAMS-2-BUTENE
1976 APR 16
OLLCK,
TIME
945
1000
1015
1030
1045
1100
1115
113J
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
TIHIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC F
64.5
67.7
66.0
65.5
86. C
86.0
66. 7
36.2
67.0
66.0
65.1
66.2
66.0
86.0
85.2
85.2
85.5
85.5
85.7
65.5
85.5
65.2
85.7
86.5
65.5
REL HUH
*
61.5
62.0
63.0
64.5
65.0
65.0
65.0
64.5
65.0
65.0
64.0
65.0
64.0
64.0
64.0
63.0
63.5
63.0
6J.O
63.0
63.0
62.5
62.5
o2.0
62.5
SSPOhER
Kb
******
******
******
******
16.50
******
******
******
16.60
******
******
******
16.40
******
******
******
15.80
******
******
******
16.90
******
******
******
15.90
RAC1QM
Mh/CH2
******
0.499
0.499
0.477
0.487
******
******
0.514
0.489
******
******
******
0.482
0.475
0.467
0.462
0.462
0.465
0.465
0.472
0.470
C.470
******
0.477
0.475
HCHO VOL
L
20.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20. 00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
-------
EC -150
FOUR ALKENES
1976 APR 19
BEGIN IRRADIATION lOCOt 0.25 INCH PYREX FILTER
NO SPEC OISTRIB DUE TO RECORDER MALFUNCTION
AT UOO HOURS ESTIMATE C2-N = 0.3 PPa
CO FACTOR 2.2/1.24
RADIOMETER CORRECTION -0.008 Mh/CM2
T=0 AT 1000 PST
CAL1B*
PAN
REL HUM
HCHO
TS
REL HUM
SSPQwER
RALIOM
H20
NO
NG2-CORR
CO
HCHO
ACETALD
ACETONE
ETHcME.-
PhCPENE
PROPENE
PROPENE
DEC K
*
Krt
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
IMT CCND
INIT CCND
INIT CCNO
INIT CCND
INIT CCND
IMT CCNO
INIT CCNO
INIT CCND
INIT CCND
* ASSIGNED INITIAL CCNDITION
Kl=0.33 MIN-1
SAMPLING RATE = 1.777 L/MIN
46 GC SAMPLES TAKEN
3C3.3
63.36
16.45
0.466
2.67UE 04
0.774
0.^22
£.149
0.050
O.OC1
0.002
1.014
0.224
0.224
0.224
-------
00
EC -150
FOUR ALKENES
1976 APR 19
CLOCK
TIME
1000
1015
1030
1045
lluO
1115
1130
1145
1200
1215
123U
1245
uoa
1313
1330
1343
14CJ
1415
It30
1445
1500
1515
1530
1545
1600
EtAPSEO
T(MINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPK
0.0
0.0
0.002
0.010
0.020
0.039
0.054
0.076
0.105
0.132
0.166
0.195
0.232
0.271
0.3C6
0.352
0.398
0.440
0.491
0.540
0.601
0.652
0.703
0.752
0.799
NO
PPM
0.774
0.642
0.511
C.393
C.3C5
0.225
0.176
0.137
0.110
0.065
0.071
C.C59
0.054
0.039
0.034
0.029
0.024
0.022
C.020
0.015
0.015
0.012
0.010
C.010
C.010
NU2-OWR
PPM
0.222
0.333
0.437
0.5C9
0.561
0.6C6
C.627
0.430
0.615
0.6C7
0.562
0.562
0.525
0.495
0.456
0.421
0.377
0.333
0.291
0.243
C.2CO
0.157
0.118
0.076
0.042
NOX-CORR
PPM
0.998
0.976
0.948
0.902
0.866
0.833
0.803
0.769
0.725
0.692
0.655
0.621
0.576
0.537
0.492
0.450
0.404
0.357
0.311
0.261
0.215
0.172
0.131
0.092
0.052
ETHENE
PPM
1.014
0.969
0.937
0.907
0.869
0.838
0.8C9
0.787
0.760
0.733
0.712
0.688
0.658
0.626
0.604
0.580
0.552
0.526
0.497
0.464
0.442
0.404
0.377
0.349
0.323
PROPENE
PPM
0.224
0.212
0.187
0.165
0.148
0.133
0.123
0.109
0.097
0.061
0.073
0.065
0.057
0.046
0.039
0.031
0.026
0.020
0.016
0.012
0.009
0.007
0.005
0.003
0.002
1-C4 =
PPM
0.097
0.090
0.078
0.068
0.059
0.052
0.046
0.042
0.037
0.03T
0.027
0.023
0.020
0.016
0.013
0.011
O.U09
0.007
0.005
0.004
0.003
0.002
0.002
0.001
0.001
T2-C4=
PPM
0.093
0.073
0.052
0.034
0.021
0.013
0.007
0.004
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
******
0.000
0.000
0.000
-------
EC -150
FOUR ALKENES
1976 APR 19
CLOCIV
TlMc
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1350
1345
1400
M 1415
--J 1430
MD 1445
1500
1515
1530
1545
160U
ELAPSED
T(MIN)
0.
15.
3J.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
2.15
2.13
2.C8
2.14
2.20
2.20
2.23
2.33
2.47
2.42
2.43
2.54
2.54
2.62
2.76
2.73
2.81
2.83
2.89
3.00
3.04
3.13
3.18
3.23
3.35
PAN
PPM
C.OOO
******
0.002
******
0.012
******
C.020
******
C. 030
******
0.042
******
0.053
******
0.064
******
0.077
******
o.oaa
******
0.1C9
******
C.124
******
0.145
PPN
FPM
0.000
******
o.cco
******
0.003
******
O.CC7
******
0.011
******
0.015
******
0.018
******
0.023
******
0.029
******
0.033
******
0.034
******
0.038
******
0.045
HCHO
PPM
O.JbJ
******
******
******
0.161
******
******
******
0.201
******
******
******
0.433
******
******
******
0.282
******
******
******
0.356
******
******
******
0.363
ACETALD
PPM
0.001
******
******
******
0.103
******
******
******
0.139
******
******
******
0.139
******
******
******
0.130
******
******
******
0.102
******
******
******
0.066
PROPALO
PPM
0.0002
******
******
******
0.0227
******
******
******
0.0341
******
******
******
0.0364
******
******
******
0.0341
******
******
******
0.0272
******
******
******
******
ACETONE
PPM
0.0017
******
******
******
******
******
******
******
****v*
******
******
******
******
******
******
******
0.0120
******
******
******
0.0118
******
******
******
0.0122
BUTYRAL
PPM
0.0003
******
******
******
0.0006
******
******
******
0.0014
******
******
******
0.0021
******
******
******
0.0027
******
******
******
0.0033
******
******
******
0.0040
PROX
PPM
******
******
******
******
******
******
******
******
******
******
******
******
0.0024
******
******
******
0.0028
******
******
******
0.0029
******
******
******
0.0030
BUG*
PPM
0.0
******
******
******
******
******
******
******
u.0012
******
******
******
0.0016
******
******
******
O.U017
******
******
******
0.0014
******
******
******
0.0016
ME-N
PPM
0.0
******
0.0
******
U. 01/06
******
O.OuOb
******
O.CIU12
******
0.0016
******
0.00^2
******
0.00^5
******
0.0027
******
0.0030
******
0.0034
******
0.0036
******
0.0026
-------
CO
o
EC -150
FOUR ALKENES
1976 APR 19
CLOCK ELAPSEC
TIME TiMIN)
1000 0.
1015 15.
Io30 30.
1045 45.
1100 60.
1115 75.
1130 90.
1145 105.
iiOO 120.
1215 135.
1230 150.
1245 165.
1300 180.
1315 195.
1330 210.
1345 225.
1400 240.
1415 255.
1430 270.
1445 285.
1500 300.
15i5 315.
1530 330.
1545 345.
1600 360.
TS
DEC F
86.7
87.0
d5.5
85.2
85.7
b5.7
86.2
86.5
86.2
86.2
86.5
86.2
65.7
86.0
87.0
86.5
86. C
86.2
86.7
67.2
86.5
87.0
86.5
86.2
86.2
REL HUM
46.0
48.5
56.5
63.0
65.0
66.0
66.0
66.5
66.5
66.5
66.0
65.5
65.0
65.0
64.5
bS.C
64.5
64.5
63.5
64.5
65.0
64. C
63.5
64.0
64.0
SSPCWER
Kh
16.40
***#**
******
16.50
******
******
******
******
*******
******
******
16.40
******
*******
******
16.40
******
******
******
16.oO
******
******
******
16.40
RACIOM
MH/CM2
0.483
0.495
0.485
0.485
0.481
0.483
******
******
0.483
******
******
******
0.483
******
******
******
0.488
******
******
******
0.493
0.483
0.481
0.478
0.483
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20. CO
-------
00
EC -151
FOUR ALKENES
1976 APR 20
6EGIN IRRADIATION 0945, 0.25 INCH PYREX FILTER
AT 1545 HOURS ESTIMATE C2-N - 0.3 PPB
CO FACTOR 2.2/1.24
RADIOMETER CORRECTION -0.005 MW/CN2
T=0 AT 945 PST
CALIBtf
PAN
REL HUM
HCHO
REL INT
TS
REL HUM
SSPGhER
RA010M
H2G
NO
NG2-COR*
CO
ACETuNE.
ETri:;)E
PROP ENS
PRCPENE
PROPENE
OEG K
%
KM
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPH
PPM
PPH
PPM
9
2
1
3
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
I NIT CONO
INIT CCND
INIT CCND
INIT CCNO
INIT CCNO
INIT CCND
INIT COND
INIT CCND
303.1
65.00
15.12
0.496
2.713E 04
1.466
C.590
2.288
0.002
C.S75
0.441
0.441
C.441
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION:
kAVELENGTH(NM)
SCO.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
REL.
Kl=0.35 MIN-1
SAMPLING RATE •= 1.791 L/MIN
66 GC SAMPLES TAKEN
INTENSITY
2.489
2.C83
1.913
1.59d
1.416
1.208
l.COO
0.707
0.462
0.239
0.085
O.C19
O.C
-------
oo
to
EC -151
FOUR ALKENES
1976 APR 20
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
T4MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
iao.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
OZONE
PPP
0.0
0.0
0.0
0.0
0.0
0.002
0.002
0.002
0.005
0.005
0.005
0.015
0.015
0.024
0.029
0.032
0.044
0.051
0.054
0.054
0.081
0.033
0.103
0.127
0.147
NO
PPM
1.466
1.280
1.128
0.982
0.865
0.791
0.713
0.650
0.572
C.526
0.484
0.440
0.396
C.352
0.318
0.288
0.244
0.225
0.205
0.176
0.161
0.142
0.132
0.117
0.107
N02-CORR
PPM
0.590
Q.739
o.esd
0.960
1.027
1.055
1.C82
1.105
1.122
1.123
1.124
1.111
1.109
1.CS6
1.093
1.077
1.G66
1.036
1.016
1.0C7
C.974
0.950
0.917
0.889
O.E57
NOX-CORR
PPM
2.056
2.024
1.992
1.947
1.897
i.asi
1.795
1.749
1.704
1.651
1.607
1.551
1.509
1.447
1.410
1.355
1.320
1.261
1.221
1.178
1.135
1.092
1.053
1.007
0.960
ETHENE
PPM
0.975
0.936
0.905
0.672
0.844
0.822
0.798
0.774
0.752
0.727
0.701
0.684
0.666
0.639
0.618
0.597
0.588
0.563
0.547
0.527
0.510
0.492
0.477
0.460
0.439
PROPENE
PPM
0.441
0.406
******
0.345
0.308
0.2U1
0.255
0.237
0.2C8
0.188
0.165
0.153
0.130
0.120
0.106
0.096
0.087
0.074
0.068
0.061
0.053
0.048
0.042
0.036
0.031
1-C4«
PPM
0.209
0.193
0.176
0.156
0.137
0.123
0.111
0.100
0.087
0.07T
0.067
0.060
0.051
0.046
0.041
0.056
0.032
0.027
0.025
0.022
0.019
0.016
0.014
0.012
0.010
T2-C4«
PPM
0.190
0.144
0.104
0.073
0.049
0.032
0.021
0.013
0.008
0.005
0.003
0.001
0.001
0.001
0.001
0.001
0.001
0.000
0.001
0.001
0.000
0.001
0.001
0.001
0.001
-------
OQ
EC -151
FOUR ALKENES
1976 APR 20
CLOCK
TIME
945
1000
1015
lOaO
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
Itl5
1430
U45
1500
1515
1530
1545
ELAPSED
T
-------
00
-p-
cC -151
FOUR ALKENES
1976 APR 20
CLOCK ELAPSED
TIME T(MINI
945 0.
1000 15.
1015 30.
1030 45.
1045 60.
1100 75.
1115 90.
1130 105.
1145 120.
1200 135.
1215 150.
1230 165.
1245 180.
1300 195.
1315 210.
1330 225.
1345 240.
1400 255.
1415 270.
1430 285.
1445 300.
liOO 315.
1515 330.
1530 345.
1545 360.
TS
DEO F
77.2
82.1
62.3
83.0
63.5
84.3
65.2
85.2
65.7
86.5
86.7
86.5
86.5
86.7
86.7
87.2
87.2
87.0
87.0
87.2
87.4
87.4
87.9
88.4
88.4
REL HUM
64.0
64.5
65.5
65.5
66.0
66.5
66.5
66.5
66.5
66.0
65.5
65.0
65.5
65.0
65.5
65.0
64.5
64.5
64.0
64.0
64.0
63.5
63.5
63.0
63.5
SSPOWER
Kh
******
******
******
******
******
******
******
******
16.40
******
******
******
******
******
******
******
16.10
******
******
******
16.30
******
******
******
11.70
RADICM
MW/CM2
0.501
0.501
0.501
******
0.493
0.488
******
******
0.496
******
******
******
0.501
******
******
******
******
******
******
******
0.479
0.474
0.503
0.506
0.525
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
oo
Ul
EC -152
FOUR ALKENES
1976 APR 21
bEGIN IRRADIATION lOCOi 0.25 INCH PYREX FILTER
AEROSPACE PfcFM ON CHAMBER, 0.6 L/MIN
AT IfcOO HOURS: Cl-N = 0.5 PPB, C2-N « 0.3 PPB
CO FACTOR 2.2/1.21
RADIOMETER CORRECTION -0.002 MW/CM2
T=0 AT 1000 PST
CALIB»
PAN
REL HUM
HCHO
REL INT
TS
REL HUM
SSPOHER
RAOIOM
H£U
NO
N02-CORR
CO
ACETALD
ACETONE
ETHtNE
PROPEN6
PfcQPENE
PROPENE
DEG K
%
KM
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
3
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
IN1T COND
INIT CCND
1N1T CCND
INIT CCND
INIT CCND
INIT CCND
INIT CCNO
INIT CCND
INIT CCNO
303.2
42.96
16.73
0.497
2.443E 04
0.398
C.104
2.189
C.002
0.003
1.015
0.116
0.116
0.116
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION:
hAVtLENGTWMM)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
REL.
Kl'0.35 MIN-1
SAMPLING RATE « 2.396 L/MIN
73 GC SAMPLES TAKEN
INTENSITV
2.579
2.216
1.991
'1.639
1.428
1.228
l.COO
0.693
0.458
0.225
0.072
0.014
0.0
-------
oo
EC -152
FOUR ALKENES
1976 APR 21
CLOCK
TIME
1000
1015
1030
1045
1100
1115
H3o
11*5
12uu
1215
1230
12*5
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.0
0.010
0.051
0.149
0.249
0.332
0.4C5
0.481
0.542
0.6C8
0.667
0.716
0.755
0.777
0.787
0.787
0.777
0.767
0.735
0.743
C.728
0.716
0.708
0.699
0.689
NO
PPM
0.398
0.250
0.125
0.055
C.033
0.026
0.022
C.017
0.016
0.013
0.012
0.016
0.012
0.011
0.011
0.011
0.012
0.011
C.011
0.011
0.011
0.011
0.011
U.011
C.011
N02-CORR
PPM
0.104
0.237
0.336
0.362
0.348
0.314
0.272
0.229
0.186
0.153
0.122
o.cat
0.062
0.044
0.031
0.023
0.019
0.015
0.010
0.003
O.CC4
0.003
0.000
0.0
0.0
NOX-CORR
PPM
0.5C4
0.489
0.461
0.418
0.382
0.340
0.292
0.246
0.201
0.167
0.133
0.100
0.074
0.055
0.042
0.034
0.032
0.024
0.021
0.014
G.014
0.014
0.011
0.010
0.008
ETHENE
PPM
1.015
0.962
0.918
0.872
0.829
0.784
0.743
0.701
0.663
0.623
0.563
0.542
0.508
0.470
0.449
0.416
0.396
0.371
0.357
0.341
0.322
0.306
0.293
0.276
0.263
PROPENE
PPM
0.116
0.102
0.089
0.072
0.061
0.050
0.041
0.031
0.024
0.019
0.014
0.009
0.007
0.005
0.004
0.003
0.002
0.002
0.001
0.001
0.001
0.001
0.001
0.000
0.000
1-C4=
PPM
0.222
0.191
0.162
0.127
0.114
0.085
0.068
0.051
0.040
0.029
0.021
0.015
0.011
0.008
0.006
0.004
0.003
0.002
0.002
0.002
0.001
0.001
0.001
0.001
0.000
T2-C4=
PPM
0.102
0.071
0.042
0.016
0.004
0.001
0.000
0.000
******
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
******
******
0.000
0.000
0.000
0.000
0.000
0.000
-------
00
-J
EC -152
FOUR ALKENES
197o APR 21
CLOCK
TIME
1000
lOli
1030
1045
1100
1115
1130
1145
1200
12i5
1230
1245
liOO
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
ELAPSED
TtMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
i35.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
2.19
2.21
2.28
2.30
2.34
2.43
2.46
2.49
2.51
2.60
2.61
2.74
2.BO
2.87
2.86
2.97
3.00
3.02
3.14
3.10
3.18
3.21
3.27
3.27
3.33
PAN
PPM
C.OOO
v*****
0.007
******
0.027
******
C.046
******
0.062
******
0.076
******
0.097
******
0.109
******
0.111
******
0.115
******
C.113
******
0.111
******
0.1C8
PPN
PPM
0.000
******
0.002
******
O.CC8
******
0.016
******
0.034
******
0.034
******
0.035
******
0.041
******
0.038
**>,.***
O.C41
******
0.045
******
0.046
******
0.050
HCHO
PPM
0.0
******
******
******
0.127
******
******
******
0.242
******
******
******
0.246
******
******
******
0.242
******
******
******
0.262
******
******
******
0.260
ACETALO
PPM
0.002
******
0.081
******
0.120
******
0.124
******
0.118
******
• 0.111
******
0.105
******
0.091
******
O.J87
******
0.078
******
0.081
******
0.075
******
0.071
PRQPALO
PPM
0.0004
******
0.0417
******
0.0642
******
0.0716
******
0.0741
******
0.0708
******
0.0642
******
0.0519
******
0.0469
******
0.0388
******
0.0388
******
0.0337
******
0.0292
ACETONE
PPM
0.0032
******
******
******
******
******
******
******
******_
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
BUTYRAL
PPM
0.0002
******
0.0007
******
0.0018
******
0.0027
******
0.0032
******
0.0037
******
0.0039
******
0.0037
******
0.0038
******
0.0033
******
0.0033
******
0.0032
******
0.0031
BUOX
PPM
0.0
******
0.0004
******
0.0008
******
0.0012
******
0.0012
******
0.0013
******
0.0014
******
******
******
0.0013
******
0.0010
******
0.0013
******
0.0013
******
******
-------
oo
oo
EC -152
FOUR ALKENES
1976 APR 21
CLOCK
TIME
1000
1015
10jO
1045
1100
1115
1130
1145
1200
1215
1230
Ii45
1300
1315
1330
1345
IfOO
1415
1430
1445
1500
1515
1530
1545
1600
ELAPSED
T(HIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
TS
DEC F
87.0
90.1
87.2
87.2
87.2
86.2
86.2
86.2
85.5
86.0
85.7
85.2
85.2
65.5
85.7
i>5.7
85.5
85.2
b5.2
85.7
85.7
86.0
86.2
85.2
85.5
REL HUM
*
50.0
50.0
54.0
61.0
64.0
65.0
65.0
66.0
65.5
65.0
65.0
64.5
64.5
64.5
64.5
64.0
64.0
64.0
64.0
04.0
64.0
64.0
64.0
64.0
64.0
SSPOWER
Kk
******
******
******
******
16.90
******
******
******
16. 7C
******
******
******
16.60
******
******
******
16.60
******
******
******
16.80
******
******
******
16.80
RADICM
Mh/CM2
0.491
0.511
0.496
0.491
0.504
******
******
******
0.494
C.501
******
******
0.487
******
******
******
******
0.494
0.489
0.489
0.511
0.496
0.499
0.489
0.496
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
co
EC -1S3
FOUR ALKENES
1976 APR 22
ocGIN IKnAOIATlCN 09JO, 0.25 INCH PYKcX FILTER
MeRQSPACE PNFM ON CHAMBeR, 0.6 L/MIN
INCREASED FLUW TO 4.34 L/MIN, 1439-1511 HOURS
,>,0 FACTOR 2.2/1.21
RADIOMETER CORRECTION -0.004 M*/C«2
T=0 AT 930 PST
CALIBrf
PAN
REL HUM
HCHO
REL INT
TS
REL HUM
SSPu»ER
KADI OH 1
H20
NO
io2-CuRR
cTHENE
PRJPHNc
1-C4=
T2-C<.=
to
ACETALO
ACETC-NE
OEli K
*
KM
Kd/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
3
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVtRAGE
IMT CCNO
INIT CCNO
IMT CGNO
INIT CCNO
INIT CCKG
INIT CCND
IMT CCND
INIT CCNO
IMT CCNO
302.*
63.48
17.29
C.fab
3.5^26
C.ITt
O.li?
1.923
0.109
C.llS
0.193
2.030
O.C.03
U.C03
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION:
k£L
500.
430.
4C3.
JdO.
370.
360.
350.
340.
330.
320.
310.
300.
290.
MIN-l
SAMPLING RATc » 2.339 L/MIN
fl GC SAMPLES TAKEN
INTENSITY
2.652
2.253
2.038
1.650
1.46-t
1.2*4
1.000
C.704
0.466
0.231
0.072
0.009
0.0
-------
EC -153
FOUR ALKENES
1976 APR 22
CLOCK
TIME
930
943
iOuO
1015
1030
10*3
1100
1113
1130
1143
UOJ
1215
1230
12*5
130J
131?
1330
13.
240.
255.
270.
263.
300.
313.
330.
345.
360.
OZONE
PPM
0.0
O.OC2
0.03:*
0.176
0.327
0.445
0.357
0.664
0.7o2
O.do2
0.960
1.021
1.050
1.043
1.023
1.CC4
0.972
0.943
0.916
0.8S4
O.bf4
0.657
0.835
O.olb
O.dJl
NO
PPM
C.774
C.4B9
C.222
0.07d
C.012
0.02-)
0.022
0.017
C. ul 5
G.012
0.012
C.012
0.012
C.012
C.012
C.010
0.012
0.010
C.010
O.ulO
C.015
C.010
C.01Q
C.010
0.010
N02-CJRR
PPM
J.197
0.446
0.654
0.7C6
G.C50
J.57-,
0.48b
C.390
0.2S8
O.ZC4
0.125
0.075
0.03i>
0.017
O.C03
-0.023
-0.02o
-0.023
-0.019
-O.Oli
-0.019
-O.OU
-0.013
-U.CO&
O.CC2
NOX-COKR
PP«
0.969
0.937
0.876
0.7o6
0.694
0.605
0.512
0.409
0.313
0.217
0.137
O.Odd
0.043
0.029
0,012
-C.C13
-0.014
-0.014
-0.009
-0.005
-0.004
-0.001
-O.C04
0.0 J"t
0.014
ETHENE
PPK
1.923
1.031
1.729
I.o30
1.541
******
1.360
1.2bi>
1.212
1.053
1.022
0.933
0.880
0.619
0.765
0.722
0.090
0.051
0.615
0.568
0.557
0.326
0.496
0.466
0.446
PROPENE
PPM
0.109
0.09d
\J. JdO
O.Ood
J.052
******
0.035
0.025
O. J19
0.011
O.OG9
O.OOo
0.004
0.003
0.002
0.0o2
O.dJl
O.OC1
0.001
0.000
0.000
0.000
0.000
0.000
O.OJO
1-C4*
PPM
0.415
0.4U6
o.<:J9
0.243
0.185
»«****
0.117
O.UJ2
O.J61 .
0. J37
0.02o
0.019
0.01 3
0. J09
0.005
0.0 J4
J.OJ3
0.002
0.001
0.001
0.001
0.001
0.001
O.OJO
J. uOO
I2-C4»
PPM
0.193
0.140
U.074
0.003
0.004
******
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
U.O
0.0
0.0
0.0
0.0
0.0
0.0
o.o
-------
EC -153
FVJK ALKEt»ES
1976 APR 22
LOCK.
riMc
930
9*5
iOOO
1015
103u
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
UJO
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
T(MIN»
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
15C.
165.
180.
195.
210.
225.
240.
255.
270.
235.
300.
315.
330.
3t5.
360.
CO
PPM
2.03
2.CC
2.08
2. 11
2.23
2.34
2.39
2.49
2.57
2.61
2.77
2.90
2.94
3.10
3.10
3.24
3.30
3.32
3.33
3.46
3.51
3.64
3.66
3.70
3.70
PA.M
PPM
0.000
******
U010
******
0.0
-------
NO
EC -15J
FOUR ALKENES
1976 APR ii
CLOCK
fJME
930
9f5
1000
10 15
1030
1045
1100
U15
113d
U45
UOO
1215
1230
1245
13UO
131S
133U
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
TIMING
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
105.
160.
195.
210.
225.
240.
255.
270.
2o5.
300.
315.
330.
345.
369.
TS
CtG F
67.2
69.2
d7.0
86.7
87.2
87.2
67.0
67.0
87.0
67.7
37.9
67.9
67. *>
87.2
87.0
87.0
U7.2
67.0
66.5
bo. 5
67.0
67.0
67.2
87.2
87.7
REL HUh
*
60.5
60.3
60.5
63.5
o4.0
64.5
o5.0
65.0
65.0
64.5
64.5
64.5
64.0
64.0
04.0
63.5
6J.5
63.0
OJ.5
63. C
63.0
63.0
63.0
62.5
62.5
SSPCMLR
KM
******
******
17.30
******
16.90
******
******
******
lo.90
******
******
******
17.80
***(.«*
******
******
17. CC
******
******
******
17.40
******
******
******
17.70
RAC10M
MH/CM2
0.477
0.199
0.497
0.489
0.405
0.487
0.492
******
0.48^
******
******
******
0.514
******
******
******
0.494
0.480
0.462
0.482
0.497
0.497
0.516
0.511
0.504
HCHO VOL
L
20.00
******
******
******
20. UO
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
******
******
******
20. 00
******
-------
VO
Co
EC -156
ETHENE
1976 MA* 4
IRRADIATION 0930; 0.25 INCH PYREX FILTER
AEROSPACE PNFM ON CHAMBERi 0.6 L/MIN
ACETALDiPRGPALC ANC ETOX MONITORED WITH 3-PART COLUMN
PPN POSSIBLY DUE TO CON T AC I NAT I CN FRCM PREVIOUS RUM
CO FACTOR 2.2/1.23
RADIOMETER CORRECTICN -0.014 MW/CM2
F=0 AT 930 POT
CALIB*
PAN
REL HUM
HCHO
REL INT
TS
REL HUM
SSPOHER
RADIOM
H20
NO
N02-CORR
CO
HCriO
ACETALO
ACETONE
ETHENE
DEG K
t
KK
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
\
3
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
INIT CCND
INIT CCNO
INIT CCNO
INIT CCNO
INIT CCND
INIT CCND
303.1
61.57
17.47
0.474
Z.J99E 04
0.276
0.124
2.C23
0.027
O.OC1
0.003
1.995
ASSIGNED INITIAL CCNOITION
SPECTRAL DISTRIBUTION:
hAVELENGTH(NWJ
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
REL.
K1=0.3Z MIN-1
SAMPLING RATE = 2.377 L/MIN
45 GC SAMPLES TAKEN
INTENSITY
3.288
2.469
2.198
.1.699
1.442
1.295
l.COO
0.658
0.415
0.200
0.064
0.012
0.0
-------
EC -156
ETHENE
1976 MAY 4
CLOCK
TIME
930
945
ludO
1015
Iu3u
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1*30
1445
1500
1515
1530
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
Io5.
180.
195.
2iO.
225.
240.
255.
270.
235.
300.
315.
330.
345.
360.
OZONE
PPM
0.0
0.012
0.044
0.110
0.203
0.308
0.437
0.579
0.728
0.838
0.945
1.&09
1.045
1.055
1.050
1.038
1.009
0.992
0.970
0.938
******
0.879
0.852
******
0.796
NO
PPM
0.376
0.231
C.127
0.065
C.037
0.020
0.012
0.006
C.QC5
0.002
O.U02
0.001
0.001
C.002
0.002
0.002
O.C02
0.002
0.002
O.G02
O.OG1
0.002
0.002
C.002
0.002
N02-CORR
PPM
0.124
C.250
0.534
0.365
0.3fct
0.348
0.318
0.272
0.222
0.176
0.137
0.1G6
O.C83
0.064
0.050
0.041
0.034
0.030
0.030
0.023
0.021
0.018
0.019
0.018
0.018
NOX-CORR
PPM
0.501
0.483
0.461
0.430
0.402
0.369
0.330
0.282
0.227
0.178
0.139
0.107
0.085
0.066
0.052
0.043
0.03o
0.032
0.032
0.024
0.023
0.021
0.022
0.020
0.021
ETHENE
PPM
1.995
1.885
1.796
1.7C8
1.615
1.516
1.436
1.324
1.210
1.119
1.016
0.925
0.847
0.776
0.720
0.670
0.632
0.583
0.551
0.519
0.487
0.462
0.436
0.412
0.392
-------
Ln
EC -156
ETHENE
1976 MAY 4
CLOCK
TIME
930
9*5
lOOu
1015
11>JO
ij*5
1100
1115
11 JO
11*5
UOO
1213
1230
12*5
1300
1315
1330
1345
1*00
1*15
1*30
1**5
1500
1515
1530
ELAPSED
TiMIN)
0.
15.
30.
*5.
bO.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
2*0.
255.
270.
265.
300.
315.
330.
3*5.
360.
CO
PPM
2.02
2. 08
2.09
2.15
2.18
2.28
2.30
2.40
2.*7
2.52
2.63
2. SI
2.85
2.93
3.05
3.16
3.25
3.29
3.*1
3.4*
3.*5
3.57
3.59
3.67
3.69
PAN
PPM
0.000
******
C.OOO
******
C.001
******
C. 003
******
0.005
******
0.007
******
C.010
******
0.012
******
0.013
******
0.01*
******
0.014
******
0.015
******
0.015
PPN
PPM
O.UOu
******
O.CLC
******
0.001
******
O.OC2
******
O.GOi
******
O.L03
******
0.003
******
O.OG4
******
O.OC4
******
0.004
******
O.OC4
******
O.CC*
******
0.003
HCHO
PPM
0.027
******
******
******
0.262
******
******
******
0.50*
******
******
******
0.655
******
******
******
0.735
******
******
******
0.63*
******
******
******
0.572
ACETALO
PPM
0.0009
******
0.0017
******
0.0023
******
0.0025
******
0.0042
******
0.0050
******
******
******
0.0102
******
******
******
0.0096
******
0.005*
******
0.004*
******
0.0076
PROPALO
PPM
0.000*
******
0.001*
******
0.0029
******
0.0052
******
0.0078
******
0.0102
******
******
******
0.0156
******
0.0125
******
0.009*
******
0.0076
******
0.0068
******
0.0065
ACETONE
PPM
0.0034
******
******
******
******
******
******
******
0.028*
*******
******
******
******
******
******
******
0.03*9
******
******
******
******
******
******
******
0.0307
BUTYRAL
PPM
0.000*
******
******
******
******
******
******
******
0.0037
******
******
******
******
******
******
******
0.0051
******
******
******
******
******
******
******
0.00*3
ETOX
PPM
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0009
******
0.0012
******
0.0010
******
0.0010
******
0.0013
-------
EC -156
ETHENE
1976 MAY 4
CLOCK
TIME
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
IbOO
1515
1530
ELAPSED
TCMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
iao.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
TS
DEG F
63.8
85.5
65.2
65.2
85.5
66.2
86.5
86.5
86.0
86.2
66. 2
86.5
86.2
86.5
66.5
86.7
86.5
86.5
66.7
86.5
86.7
66.7
87.2
86.5
86.7
REu HUM
*
60.5
60.5
61.5
63.0
64.0
64.0
64.5
64.5
64.0
64.0
64.0
64.0
64.0
63.5
63.5
63.5
63.5
63.5
63.5
63.0
63.0
63.0
63.5
63.0
63.0
SSPOWER
Kk
******
17.60
******
******
17.70
******
******
******
17.40
******
******
******
17.50
******
******
******
17.00
******
******
******
17.70
******
******
******
17.40
RA010M
MW/CM2
0.435
0.489
0.477
0.506
0.464
******
******
******
0.472
******
******
0.484
0.472
******
******
******
0.455
******
******
0.477
0.472
0.467
0.479
0.460
0.467
HCHO VOL
L
15.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -157
TRANS-2-BUTENE
1976 MAY 5
BEGIN IRRADIATION 0930! 0.25 INCH PYREX FILTER
AEROSPACE PNFM CN CHAMBER, 0.6 L/MIN
PPN POSSIBLY DUE TO CONTAMINATION FROM PREVIOUS RUN
CO FACTOR 2.2/1.22
RADIOMETER CORRECTICN -0.014 MW/CM2
T=0 AT 945 POT
PAN
REL HUM
HCHO
REL INT
CALIBtf
9
2
1
4
TS
REL HUM
SSPO«ER
RADIOM
H20
NO
N02-CORR
HCHQ
ACETALD
ACETONE
T2-C4=
DEG K
i
KM
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCND
INIT CCND
INIT CCND
INIT CCND
INIT CCND
302.5
63.99
17.41
0.466
2.747E 04
0.397
C.129
O.C10
0.001
0.003
0.216
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION:
hiAVELENGTHCNNI
SCO.
430.
403.
360.
370.
360.
350.
340.
330.
320.
310.
300.
290.
M=0.34 MIN-1
SAMPLING RATE « 2.378 L/MIN
47 GC SAMPLES TAKEN
REL. INTENSITY
2.406
2.116
1.724
1.634
1.398
1.171
1.000
0.697
0.462
0.236
0.062
0.014
0.0
-------
00
EC -157
TRANS-2-BUTENE
1976 MAY 5
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
liOO
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSEC
T4MIN)
0.
15.
30.
45.
t>0.
75.
90.
105.
120.
135.
150.
165.
ISO.
1S5.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.0
0.002
0.015
0.034
C.044
0.054
0.054
0.073
0.083
0.093
0.085
0.107
0.112
0.122
0.129
0.132
0.144
0.147
0.159
0.166
0.176
0.176
0.183
******
0.205
NO
PPM
0.397
0.283
0.206
C.154
C.125
0.104
C.092
C.067
0.074
0.066
0.062
C.C57
0.054
C.C5C
0.053
0.048
C.043
C.040
0.036
0.037
0.033
0.032
0.029
0.029
0.027
N02-CORR
PPM
0.129
0.223
0.273
0.299
0.305
0.303
C.2S8
0.288
0.287
0.263
0.275
0.271
0.261
0.255
0.241
0.237
0.235
0.22a
0.219
0.210
0.2C5
0.198
0.192
Q.180
0.171
NOX-CORR
PPM
C.525
0.510
0.486
0.455
0.429
0.406
0.391
0.375
0.363
0.349
0.337
0.328
0.316
0.305
0.295
0.286
0.279
0.268
0.257
0.247
0.239
0.230
0.221
0.210
0.200
T2-C4=
PPM
0.216
0.142
0.091
0.054
0.031
0.017
0.009
0.005
0.002
0.001
0.001
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
-------
VO
EC -157
TRANS-2-BUTENE
1976 MAY 5
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
TCMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165;
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
******
2.08
2.10
2.10
2.12
2.22
2.11
2.16
2.21
2.21
2.22
2.27
2.27
2.28
2.28
2.37
2.31
2.36
2.40
2.38
2.40
2.44
2.50
2.46
2.53
PAN
PPM
0.000
******
0.007
******
C.023
******
C. 034
******
0.039
******
0.042
******
0.045
******
C.047
******
0.047
******
0.049
******
C.050
******
0.050
******
0.052
HCHQ
PPM
0.010
******
******
******
0.012
******
******
******
0.020
******
******
******
0.024
******
******
******
0.020
******
******
******
0.028
******
******
******
0.022
ACETAUO
PPM
0.001
******
0.161
******
0.220
******
0.214
******
0.205
******
0.166
******
0.171
******
0.145
******
0.127
******
0.127
******
0.112
******
0.104
******
0.090
PROPALD
PPM
0.0002
******
******
******
0.0006
******
0.0007
******
0.0010
******
0.0010
******
0.0014
******
0.0014
******
0.0014
******
0.0019
******
0.0021
******
0.0024
******
0.0025
ACETONE
PPM
0.0023
******
0.0044
******
o.ooao
******
0.0076
******
0.01G5
******
0.0060
******
0.0104
******
0.0102
******
0.0062
******
0.0128
******
0.0176
******
0.0158
******
0.0147
BUTYRAL
PPM
0.0002
******
0.0002
******
0.0003
******
0.0004
******
0.0005.
******
0.0006
******
0.0006
******
O.C007
******
0.0007
******
0.0009
******
0.0010
******
0.0009
******
0.0011
MEK
PPM
0.0001
******
0.0011
******
0.0017
******
0.0020
******
0.0021
******
0.0019
******
0.0019
******
0.0019
******
0.0016
******
0.0020
******
O.OC19
******
0.0017
******
0.0017
M£-N
PPM
0.0
******
0.0
******
0.0005
******
0.0011
******
0.0ul5
******
0.0015
******
0.0019
******
0.0019
******
0.0016
******
0.0016
******
0.0022
******
0.0022
******
0.0022
-------
EC -157
TRANS-2-6UTENE
1976 MAY 5
O
O
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
U15
1330
1345
i400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC F
81.6
65.5
85.7
85.5
65.7
86.5
87.0
87.4
87.2
67.2
87.0
87.0
86.7
66.5
67.0
87.0
67.0
87.2
87.2
87.4
87.2
87.2
87.4
87.2
87.4
REL HUM
*
51.5
60.0
64.5
66.0
66.0
66.5
66.5
66.5
66.5
66.5
66.0
66.0
66.0
65.5
65.5
65.5
65.5
65.0
64.5
64.5
64.5
64.5
64.5
64.5
64.0
SSPCMER
KW
******
******
17.20
******
17.40
******
******
******
17.40
******
******
******
17.30
******
17.30
******
17.60
******
17.50
******
17.50
******
******
******
17.50
RAOIOM
MH/CM2
******
0.484
0.480
0.472
0.484
******
******
0.511
0.480
0.484
0.492
******
0.470
0.484
0.489
0.484
0.484
0.484
0.480
0.489
0.482
0.482"
0.484
0.487
0.484
HCHO VO
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.CO
******
******
******
20.00
-------
to
O
EC -160
ETHENE * PRGPENE
1976 MAY 10
6EGIN IftRAOIATICN 0930; 0.25 INCH PYREX FILTER
ESTIMATE ETOX = 1 PPB AT 1530 HOURS
CO FACTOR 2.2/1.23
RADIOMETER CORRECTION -0.004
T=0 AT 930 POT
CALIB*
PAN
REu HUM
HCHO
REL INT
TS
REL HUH
SS POWER
RADIOM
HtO
NO
N02-CCRR
CO
HCHO
ACETALD
ACETONE
PROX
ETHEN'E
PROPENE
DEG K
%
KK
MW/CM2
PPM
PPM
PPM
PPM
PPK
PPM
PPM
PPM
PPM
PPM
9
2
1
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CGNO
INIT CCNO
IMT CCNO
INIT CCNO
INIT CCND
INIT CCND
INIT CCND
INIT CCNJ
INIT CCNO
20Z.7
C.520
2.439E 04
C.152
i!l36
O.OC4
C.OC2
0.003
O.C01
1.C14
0.400
ASSIGNED INITIAL CCNOITION
SPECTRAL DISTRIBUTION:
hAVELENGTH(Nf)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
29C.
REL.
Kl«=0.35 MIN-i
SAMPLING RATE = 1.736 L/MIN
66 GC SAMPLES TAKEN
INTENSITY
2.514
2.228
2.004
1.674
1.448
1.193
l.COO
C.703
0.467
0.230
0.086
0.022
0.0
-------
EC -160
ETHENE + PRCPENE
1976 MAY 10
NJ
O
CLOCK
TIME
530
9*5
1000
1015
1030
1045
1100
1115
1130
11*5
1200
1215
1230
12*5
liOO
1315
1330
13*5
ItOO
1*15
1*30
1**5
1500
1515
1530
ELAPSED
T(M1N>
0.
15.
30.
*5.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
2*0.
255.
(.10.
285.
300.
315.
330.
3*5.
360.
CUCNE
PPM
0.0
0.0
O.OG5
0.010
0.015
0.032
0.0*6
0.073
0.1C5
0.132
0.171
0.215
0.256
0.300
0.3**
0.386
0.*32
0.489
0.5*7
0.601
0.002
0.723
0.782
0.633
0.67*
NO
PPM
0.752
0.613
0.501
O.J98
0.305
0.237
0.136
C.l*7
C. 120
C.C65
C.073
0.059
0.0*9
0.039
0.032
C.C27
0.02*
C.020
C.020
0.015
0.015
C.012
C.010
C.010
C.010
N02-CORR
PFK
0.2*1
C.350
0.4*0
C.510
0.5o7
0.607
0.627
0.631
0.623
0.620
0.5S7
0.572
0.535
0.497
o.*sa
O.*lb
0.378
0.32*
0.280
0.232
o.ie*
0.1*6
0.1C7
0.070
0.038
NOX-CORR
PPM
0.99*
0.963
0.9*0
0.9C8
0.875
0.8*6
0.815
0.780
0.7*3
0.705
0.672
0.633
0.586
0.533
0.490
0.**7
0.395
0.3*6
0.297
0.2*7
0.199
0.155
0.119
0.080
0.0*8
ETHENE
PPM
1.01*
0.960
0.920
O.d88
0.858
0.82*
0.796
0.766
0.735
0.712
0.685
0.655
0.625
0.598
0.570
0.5*2
0.510
0.*78
0.**8
0.419
0.395
0.361
0.329
0.306
0.278
PROPENE
PPM
0.400
0.362
0.312
0.271
0.253
0.227
0.189
0.168
0.1*7
0.128
0.112
0.095
0.079
0.063
0.053
0.0*2
0.03*
0.026
0.019
0.01*
0.009
0.006
0.005
0.003
0.002
-------
EC -160
ETHENE » PROPENE
1V76 MAY 10
CLOCK.
TIME
930
945
100U
1015
1030
1045
1100
1115
1130
1145
1200
1215
li.30
1245
1300
1313
1330
13/*3
g 1400
LO 1415
1430
1445
1500
1515
1530
EtAPSEO
TIHIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
1S5.
210.
225.
240.
i55.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
2.14
2.19
2.18
2.21
2.21
2.39
2.47
2.54
2.62
2.70
2.77
2.63
2.68
2.92
2.98
3.03
3.15
3.20
3.27
3.36
3.43
3.50
3.58
3.73
3.73
PAN
PPM
C.OOO
******
0.002
******
0.014
******
0.017
******
C.02S
******
C.039
******
0.054
******
C.066
******
C.078
******
C.098
******
C.120
******
C.134
******
C.158
HCHO
PPM
O.CC4
******
******
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0.187
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0.381
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0.282
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0.0007
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0.0036
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0.0032
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0.0036
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0.0043
-------
EC -160
ETHENE + PRCPENE
1976 MAY 10
O
-P-
CLOCK
TIME
930
945
1000
1015
1030
1045
1100
1115
1130
1145
i200
U15
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
TS
D£G F
60.1
63.3
63.5
64.3
64.5
64.3
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85.2
65.0
65.2
66.0
66.2
66.2
65.5
85.5
65.2
85.5
86.0
86.5
65.5
65.2
85.7
85.7
85.7
86.2
REL HUM
*
51.0
54.5
61.0
65.0
65.5
07.5
66.0
68.5
68.5
67.5
67.5
67.0
67.0
66.5
66.5
67.0
66.5
66.0
66.0
65.5
65.0
65.0
65.0
65.0
64.5
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KM
17.90
******
******
******
18.40
******
******
******
16.00
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17.90
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17.90
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18.10
******
******
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13.80
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MH/CM2
******
0.494
0.497
0.507
0.507
0.497
0.499
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0.485
******
******
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0.480
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******
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0.430
0.494
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0.492
0.469
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0.502
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20.00
******
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20.00
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20.00
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20.00
-------
CC -161
FOUR ALKENES
1976 MAY 11
BEGIN IRRADIATION 0900; 0.25 INCH PYREX FILTER
CO FACTOR 2.2/1.32
RADIOMETER CORRECTION -0.004 MW/CH2
T»0 AT 900 PDT
CALia*
PAN
REL HUM
HCHO
REL INT
TS
REL HOI
SSPOWER
RADIuM *
H20
NJ
SJ2-CQRR
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%
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PPM
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AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT COND
IMT CCNO
INIT CONO
INIT CONO
INIT CCNO
INIT CONO
INIT CCND
INIT CCNO
I MIT CONO
303.3
77.46
17.97
0.469
3.257E 04
0.386
0,123
0.908
0.102
C.1B4
0.068
2.158
O.C02
0.002
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION:
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500.
430.
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380.
370.
360.
350.
340.
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320.
310.
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Kl»0.34 MIN-1
SAMPLING RATE « 1.742 L/MIN
75 GC SAMPLES TAKEN
INTENSITY
2.434
2.162
1.911
1.706
1.422
1.173
1.000
0.727
0.485
0.266
0.047
0.017
0.0
-------
to
o
ON
£C -161
FOUR ALKENES
1976 MAC 11
CLOCK
TIME
900
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
123^
1245
1300
1315
1330
1345
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1415
1430
1445
1500
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TIMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
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0.846
0.857
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0.850
0.833
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0.809
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0.102
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0.000
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-------
EC -161
FOUR ALKENES
1976 MAY 11
CLOCK
TIME
900
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1250
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
TIMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
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2.92
3.07
3.07
3.13
3.15
3.26
3.23
3.32
3.36
3.43
3.45
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C.C47
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N3
O
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EC -161
FOUK ALKENES
1976 MAY 11
CLOCK
TIME
900
915
930
S45
1000
1015
1030
1045
1100
1115
1130
11-.5
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
T(MIN)
0.
IS.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
TS
OEG F
84.5
69.2
86.5
86.5
86.2
67.2
67.4
67.2
87.2
67.0
86.5
66.5
66.0
66.2
66.2
86.0
86.0
85.2
85.2
84.5
64.5
85.0
84.5
84.3
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REL HUM
*
50.0
48.5
51.5
56.5
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65.5
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75.5
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65.5
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86.5
85.5
86.0
87.0
86.5
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66.5
66.0
86.5
86.5
88.5
86.0
86.0
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18.10
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16.00
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17.90
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17.90
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17.60
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18.00
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0.504
0.487
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O
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EC -Io2
,\-ooTA,NE
1976 MAY 12
CLOCK
TIME
930
94?
1000
1013
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1043
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1115
1130
1145
1200
1213
1230
1245
1300
U15
1330
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1415
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1445
1500
1515
1330
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0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
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165.
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195.
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223.
240.
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0.489
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tC -162
N-dUTftNE
1976 HA*
CLOCK ELAPSED
TlMc T«HIN»
930 0.
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1000 30.
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EC -162
tN-BUTAN£
1976 MAY 12
CLuCK
TIME
930
943
1000
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EC -162
N-BUTANE
197o MAy 12
CLOCK
IIMc
930
945
1000
1015
1030
1045
1100
1115
1130
1145
120u
Itl5
1230
1245
1300
1315
1330
1343
140J
141 5
1430
lf»5
1500
1515
1530
ELAfSSO
TiMIN)
0.
19.
30.
45.
60.
75.
90.
105.
120.
135.
150.
lc>5.
IdO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPP
0.0
0. wC2
0.002
0.007
O.Olu
0.012
0.015
O.Oli.
0.017
0.022
0.024
0.029
******
******
******
******
vw*v*»
******
0.066
0.073
0.031
0.086
O.CSd
0.103
0.112
NO
PHM
C.383
C.347
C.319
0.2d9
C.266
C.245
C.223
C.208
C. 193
C.177
C.166
C.15&
******
******
******
******
******
******
C.G94
C.067
0.079
0.072
0.070
C. JO2
0.065
NU2-COKR
PPM
0.122
0.146
0. Io9
0.18V
0.205
O.i;15
0.22'J
0.240
C.242
0.250
0.25S
J.tSy
******
******
******
**«**«
******
****<.*
0.27^
0.275
0.273
0.2t>9
0.259
0.261
0.25d
NOX-COAR
PPM
0.5Gb
0.490
0.487
0.480
0.472
0.462
0.454
U.447
0.435
0.426
0.425
0.415
******
******
******
******
******
******
0.3/4
0.363
C.354
u.341
0.334
0.327
0.323
N-C4
PPf
2.05
2.CO
1.97
1.S3
1.S2
l.SO
1.89
l.bl
l.b
-------
N)
I-1
OJ
EC -162
N-BUTANE
I97o MAY 12
dEGIN IRRADIATION 0930; 0.25 INCH PYReX FILTER
C4-N DATA FROM C-600 CCNSICEREO MORE RELIABLE THAN FRUM PANALYiER
CJ FACTOR 2.2/1.32
kAOIOMETEh CORRECTION -u.004 M»/CM2
T«0 AT 930 PUT
CALIBff '
PAN
REL HUM
HCHQ
REL 1ST
TS
KiL HUM
SSPunEK
RA010M
hti)
NO
N02-COAR
iS-C4
CO
hCHu
AC IcT ONE
OEG K
S
Kri
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
3
AVtRAbL
AVERACE
AVE^AGt
AVERAGE
AVERAGE
IMT CCNO
INiT CCiNO
IMT CCNJ
INIT CCNC
IN IT CCN3
IMT CCNO
303.0
77.od
IB.57
C.Sli
•4.9C1E
0.333
U. 122
2.C50
2.092
C.C20
O.OU2
ASSIGNED INITIAL CCND1TICN
iPECTRAL DISTRIBUTION! mAVELENuTHiNCI
SCC.
430.
403.
38d.
370.
360.
3iO.
340.
330.
320.
31C.
300.
290.
Kl»0.35 HIK-l
SAMPLING RATE = 1.763 L/MIN
>4 (iC SAMPLES TAKEN
KEL
INTENSITY
3.666
2.679
2.34a
1.795
1.504
1.213
1.000
0.658
0.3^7
0.202
O.Ct>7
0.011
0.0
-------
EC -163
N-BUTANE * ACETALOEHYOE
1976 MA* 13
BEGIN IRRADIATION 1030; 0-.25 INCH PVREX FILTER
CO FACTOR 2.2/1.33
RADIOMETER CORRECTION -0.004 MW/CH2
T«0 AT 1030 PDT
PAN
REL HUM
HCHO
REL INT
CALIB*
9
a
1
3
ho
TS
REL MUM
SSPO-ER
RAOIOM
H20
NJ
N02-CORR
N-C4
ACETALO
CO
PAN
ACETONE
DEG K
%
KM
MH/CM2
PPM
PPH
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT COND
IMT COND
INIT CCMD
INIT COND
INIT CCND
INIT CONO
IMT CCNO
301.7
74.94
18.09
0.547
2.914E 04
0.377
0.113
1.S70
0.526
2.166
0.001
0.002
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION! hAVELENGTHtNM)
500.
430.
403.
380.
370.
360.
330.
340.
330.
320.
310.
300.
290.
Kl-0.34 MIN-l
SAMPLING RATE - 1.782 L/MIN
53 GC SAMPLES TAKEN
REL.
INTENSITY
3.753
2.62o
2.315
1.794
1.473
1.187
l.UOO
0.687
0.421
0.199
0.065
0.010
0.0
-------
EC -163
N-BUTANE » ACETALOEhfOE
1976 HAY 13
CLOCK
T1HE
1030
10*5
1100
Ills
1130
114S
i2uo
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
153J
1545
1600
1615
1630
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.0
0.007
0.012
0.020
0.032
0.049
0.064
O.OS3
0.093
******
******
******
0.178
0.195
0.217
0.234
0.256
0.278
0.298
0.318
0.340
0.362
0.386
0.405
0.430
NO
PPM
0.377
0.280
0.219
0.170
0.137
0.113
0.098
0.073
0.076
******
******
******
0.046
0.039
0.034
0.033
0.031
0.028
0.027
0.024
0.022
0.021
0.018
0.017
0.016
N02-CORR
PPM
0.113
0.188
0.230
0.262
0.281
0.286
0.294
0.299
0.234
******
******
******
0.262
0.259
0.244
0.233
0.224
0.209
0.192
0.179
0.164
0.151
0.137
0.125
0.115
NOX-CORR
PPM
0.490
0.469
0.448
0.434
0.419
0.403
0.391
0.378
0.365
******
******
******
0.310
0.297
0.282
0.267
0.255
0.237
0.219
0.203
0.187
0.171
0.153
0.143
0.131
N-C4
PPM
1.98
1.93
1.89
1.88
1.87
1.83
1.82
1.80
1.79
1.78
1.76
1.75
1.73
1.70
1.70
1.68
1.07
1.66
1.65
1.62
1.60
1.60
1.57
1.55
1.56
ACETALO
PPM
0.526
******
0.384
******
0.371
******
0.370
******
0.295
******
0.299
******
0.309
******
0.307
******
0.281
******
0.316
******
0.260
******
0.229
******
0.255
-------
EC -163
N-6UTANE * ACETALDEHYDE
1976 MAY 13
N>
H1
a*.
CLOCK
TIME
103J
Iu45
1100
1115
1130
1145
1200
121!)
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
IbOO
1615
1630
ELAPSED
TIMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
2.19
2.21
2.15
2.20
2.21
2.20
2.28
2.26
2.25
******
******
******
2.34
2.46
2.39
2.51
2.45
2.44
2.52
2.47
2.49
2.59
2.57
2.57
2.62
PAN
PPM
0.001
******
0.016
' ******
0.02S
******
0.035
******
0.045
******
0.054
******
C.062
******
0.071
******
0.077
******
0.087
******
0.097
******
0.106
******
******
HCHO
PPM
0.0
******
******
******
0.010
******
******
******
O.C06
******
******
******
******
******
******
******
0.014
******
******
******
0.022
******
******
******
0.0
PROPALD
PPM
******
******
******
******
******
******
0.0009
******
0.0010
******
0.0015
******
0.0020
******
0.0022
******
0.0028
******
0.0033
******
0.0036
******
0.0038
******
0.0044
ACETONE
PPM
0.0021
******
0.0019
******
0.0024
******
0.0030
******
0.0026
******
0.0042
******
0.0049
******
0.0057
******
0.0061
******
0.0107
******
0.0076
******
0.0075
******
0.0141
BUTYRAL
PPM
******
******
0.0009
******
0.0013
******
0.0016
******
0.0017
******
0.0025
******
0.0028
******
0.0031
******
0.0034
******
0.0038
******
0.0039
******
0.0041
******
0.0045
HEK
PPM
******
******
0.0038
******
0.0224
******
0.03J9
******
0.0300
******
0.0429
******
0.0493
******
0.0517
******
0.0567
******
0.0773
******
0.0658
******
0.0682
******
******
ME-N
PPM
0.0
******
0.0
******
0.0005
******
0.0008
******
0.0011
******
0.0014
******
0.0016
******
0.0019
******
0.0019
******
0.0022
******
0.0024
******
0.0023
******
******
C4-N-2
PPM
C-600
0.0
******
O.OU32
******
0.0042
******
0.0052
******
0.0068
******
0.0077
******
0.009J
******
0.0089
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0.0102
******
0.0115
******
0.0119
******
0.0140
******
0.0135
C4-N-1
PPM
C-600
0.0
******
******
******
0.0004
******
0.0007
******
0.0006
******
0.0007
******
0.0007
******
O.OJ11
******
0.0013
******
0.0011
******
0.0016
******
0.0014
******
0.0013
-------
EC -163
N-BUTANE * ACETALDEHrOE
1976 MAV 13
N3
CLOCK
TIME
1030
1045
1100
1115
1130
1145
1200
1215
1230
12t5
1300
1315
1330
13
-------
fO
EC -164
ACETALOEHYDE
1976 MAY 17
otlilN IRKADIATICN 1015; 0.25 INCH PYKEX FILTER
TEMPtRATURE CONTROL FAILURES TEMPERATURE INCREASED THROUGHOUT RUN
CU FACTOR 2.2/1.32
KACIOMETEd CORRECTION -0.004 MH/CM2
T*0 AT 1015 POT
C«LI6#
PAN
REL HUM
HCHO
REL INT
TS
REL HUM
SSPCrfEK
KAUiLAM
HtU
HJ
NJ2-CCRR
ACcTALO
CO
ACETCNL
DcG K
'4
Kh
Mh/CM2
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
3
AVERAGE
AVtRAGe
AVErtAOE
AVEKACE
AVtRAGE
IMT CCNO
IMT CCNU
IMT CCNO
INIT CMC
I NIT CCH0
307.1
tt>,t>7
Id. 57
5t 04
C. 3d«
c.ua
0.340
2.109
C.CCl
ASSIGNED INITIAL CCNC1TION
SPECTRAL DISTRIBUTION: tiAVELENGTHINH) REL.
430.
403.
38C.
370.
360.
340.
330.
320.
310.
300.
290.
Kl=0.3i MIN-1
SAMPLING RATE « 1.762 L/MIN
24 OC SAMPLES TAKEN
INTENSITY
3.670
2.575
2.2V5
1.770
1.-.65
1.191
1.000
C.699
0.427
0.192
C.062
0.011
0.0
-------
EC -164
ACETALOEhrOE
1976 MAY 17
CLOCK
TIMu
1015
1030
10l3
1100
1U5
1130
1145
1200
1215
12JO
1245
1300
1313
1330
1345
1400
1415
1430
l-»45
1500
1515
1530
1545
1600
1613
ELAPSED
T(MINi
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
i.03.
IbO.
195.
210.
225.
2tO.
255.
270.
285.
300.
315.
330.
345.
360.
CUCNE
PPf
0.0
0.002
O.C02
O.OC5
0.007
0.010
0.012
0.020
0.022
0.024
0.027
0.032
0.037
0.039
0.042
0.049
0.054
0.05b
0.061
0.064
0.066
0.071
0.081
0.078
0.085
NO
PPM
0.388
C.360
0.321
C. 26o
C.261
0.237
0.216
0.198
C. Iu2
C.164
C. 154
0.144
0.134
*.. 125
C. lib
C.110
C. 100
C.1C7
C.090
0.085
Q.078
0.079
0.073
C.071
C.068
N02-CORR
PPM
O.lld
0.137
0.165
0.191
0.204
0.221
0.233
0.240
0.245
0.252
0.234
0.255
0.255
0.255
0.25S
0.253
0.255
0.242
0.251
0.248
0.252
0.242
0.236
0.233
O.Z25
NOX-CORR
PPM
0.506
0.497
0.467
0.477
0.467
O.H58
0.449
0.438
li.427
0.410
0.406
0.399
O.J90
0.3ol
0.375
0.363
0.355
0.350
0.342
0.334
0.330
0.321
0.310
0.305
C.296
ACETALO
PPM
0.340
******
0.243
******
0.216
******
0.162
******
o.loa
******
0.138
******
0.132
******
0.127
******
0.110
******
0.104
******
0.093
******
O.OS1
******
0.078
CO
PPM
2.11
2.09
2.11
2.11
2.12
2.15
2.18
******
******
******
******
******
******
******
******
2.38
2.39
2.40
2.45
2.45
2.32
2.31
2.51
2.58
2.53
PAN
PPM
0.000
******
O.UOu
******
0.011
******
0.011
******
0.017
******
0.019
******
0.021
******
0.021
******
0.026
******
******
0.023
0.024
******
0.024
******
0.025
HCHO
PPM
******
******
******
******
0.030
******
******
******
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******
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0.272
******
******
******
******
******
******
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0.050
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******
******
0.004
PKUPALU
PPM
******
******
******
******
******
******
******
******
O.OOOo
******
0 . OOOo
******
li.OuOf
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U.OO08
******
U.0009
******
0.0010
******
0.0011
******
0.0012
ACETONE
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0.0013
******
******
v*****
0.0022
*** ***
0.0030
******
O.o03o
******
U .0041
******
0.0037
******
O.OO46
******
0.0051
******
0.0053
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0.0060
******
0.0073
******
0.00o3
BJTVRAL
PPM
******
******
O.OuOl
******
o.oool
******
o.oooi
******
O.0u02
******
0.0uu2
******
O.OU03
******
O.u003
******
J.0004
******
O.UOG4
******
0.0004
******
O.0u05
******
0.0005
KE-N
PPM
0.0
******
ti.C
******
0 .uv/04
******
0.0005
******
C.OOub
******
u.Ool 1
******
0.0013
******
0. ool 1
******
0 . Co 1 5
******
******
O.Oulb
0.0019
*B**«*
O.OU19
******
0.0016
-------
O
EC -164
ACETALCEHYOE
1976 MAY 17
LOv*
TIMc
1015
1030
1045
110J
ll 13
1130
Ui5
1200
1215
123u
i243
1300
1315
133o
LJ45
14JO
lllD
1430
1445
1500
1515
1530
1545
IbOO
1615
ELAPSED
T(MIN)
0.
15.
30.
45.
o 0.
75.
90.
105.
liO.
135.
150.
lob.
loG.
195.
210.
225.
<.40.
255.
270.
265.
300.
315.
330.
345.
360.
TS
CEG F
dO.l
83.8
b4.3
64.0
64. a
65.2
90.4
90.6
a9.9
69.4
69.6
90.9
90.9
90.9
91 .1)
94.3
95.3
97.2
97.9
99.2
99.7
100.1
100.6
101.4
101.9
REL HUM
*
46.0
49.0
5/.0
67.5
73.0
75.5
75.5
75.5
75.5
75.5
75.5
73.5
75.5
75.0
/5.0
75.0
74.0
74.0
74.0
73.5
73.5
73.5
73.5
73.0
73.0
SSPUrtER
KK
******
***« **
16. oJ
******
ID . oj
******
Iti.dO
******
1J.5J
******
******
****¥*
18. od
******
******
******
16. 50
******
******
******
18.20
*»*»*»
******
***] **
Id. 60
RAD10M
M«/CM2
******
******
C.4dO
******
0.4d9
******
0.4D5
J.-»b7
0.543
0.465
0.475
O.io3
O.i77
0.470
0.4dO
******
0.51V
******
******
******
0.519
0.467
0.494
0.45B
0.465
HCHU VOL
L
20.00
******
******
******
20.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
l-o
N3
EC -165
2,3-tJlMETHYLBUTANE
MAY la
IRRADIATION 10CO, J.25 INCH PYKE* FILTfc*
ALKYc NITRATE UATA FROM C-oOO CONSICE^EU M0*e RfcLlAbLt THAN FROM PANALYiER
1,6-N-O ATTRloUTEO TJ UNKNCrfN PEAK CN BUTH C-6JO COLUMN AND PANALYitK.
C-OU3 DATA USED. CALIBRATION FACTUX ESTIrtATcO
CuRRtCTICN -li.COS MK/CM2
AT 1000 POT
CALIB*
PAN
REL HUM
tiCHO
REL INT
Ti
SiPChER
KADIUM
.NJ
iMGi-CuRK
2,3-L«d
ACcTONE
OEli K
Kh
MH/CM2
PPM
PPM
PPM
PPM
9
2
1
*
AVERACE
OVERAGE
AVERAGE
IMT CCND
IMT CCNO
JMT CCNO
INIT CCNO
301.7
Ib.Ji
C.tdO
0.086
O.C11
l.oiJS
C.002
AS.SIGNEO INITIAL CCNOITION
SPECTRAL DISTRIBUTION: hAVELENGTh(NC) REL.
-------
cC -165
2,3-OIMcTHVLBUTANE
1976 HAY 16
CLULK
TIME
13JO
1015
1030
1043
1100
1130
1145
1200
1215
1230
let?
1300
1315
1330
1345
140j
1415
1430
1445
1500
ID 15
1530
1545
1600
1615
1630
1645
1730
1715
1730
1745
loOO
1615
Ib30
1845
1900
1915
19 3u
1945
2000
ELAPSED
UMIN)
0.
15.
30.
43.
60.
•7 L
f 5.
90.
105.
120.
135.
150.
Io5.
loO.
195.
210.
225.
240.
255.
270.
i«5.
JOO.
315.
330.
345.
3t>0.
375.
390.
405.
420.
435.
450.
463.
4oJ.
495.
510.
525.
540.
555.
570.
535.
600.
CULNE
PP*
0.0
0.010
0.024
0.039
0.064
0.078
0.105
0.129
0.149
0.173
0.195
0.217
0.237
0.259
0.273
0.303
0.325
0.344
0.364
0. 3bo
0.403
0.413
0.432
0.445
0.457
0.462
0.
******
O.o016
******
O.UOJU
**** * *
0.0o3o
*lt**V«
O.OU45
******
0.0054
******
0. Ouol
******
O.QO&6
******
O.uo71
******
O.OU71
******
0.0079
******
0.0082
******
0 «00o6
******
O.OJ91
******
U.0092
******
O.U092
******
O.Oi/92
******
0.0u94
******
******
Co-N-U
FPM
C-bOC
0.0
******
O.oCl?
******
O.OUJ7
0.0045
******
u . Oco4
******
0.0073
******
O.OOJ7
******
******
******
0.0111
*«.****
0. Jl 16
******
O.J123
*¥«* **
O.ul i
-------
EC -165
2,3-OIMETKVLaUTANe
1976 HAy la
CLOCK
TIME
1000
1015
1030
1045
11UO
1115
1130
1145
1^00
121 5
1230
1245
1300
1313
133u
1345
1400
.. 1415
K 1*30
Ui 1443
1500
1515
1530
1545
ioOO
lolj
1630
Ib45
170o
1715
1730
1745
IbOO
18 la
1830
1045
1900
1915
1930
19-.5
2000
ELAPSED
T(KlN)
0.
15.
30.
45.
60.
75.
90.
105.
12U.
135.
ISO.
Io5.
180.
195.
210.
225.
2tO.
255.
27J.
2oO.
495.
310.
525.
340.
555.
570.
565.
600.
TS
CEO F
85.0
86.5
85.5
85.0
67.2
88.4
90.9
92.6
94.3
95.5
96.5
97.5
97.7
97.0
96.2
96.0
96.0
95.7
95.7
95.7
96.0
85.7
86.5
86.2
66.2
85.7
85. 5
85.5
85.2
8b.C
oo.2
86.7
86.5
67.0
87.2
87.2
87.7
66.0
86.2
86.5
86.2
SSPOwER
KB
******
Id. 50
18.10
******
Id. 20
******
******
******
18.30
******
******
******
17.90
******
16.10
18. 10
18.50
******
******
******
18.50
******
******
***«.**
16.20
******
******
******
18.30
******
******
******
18.80
******
******
******
18.90
******
******
******
18.50
RADICM
Mh/CM2
0.454
0.486
0.4bl
0.47b
U.4E4
******
******
0.431
0.479
******
******
******
0.4u9
0.476
0.474
0.469
U.461
0.476
0.481
G.469
0.476
0.481
0.498
0.484
u.466
0.466
0.474
0.466
C.474
0.471
O.t7o
C.491
0.486
0.491
0.496
0.5C8
0.5C3
0.474
0.466
0.461
0.479
MCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
V*****
20.00
******
******
******
20.00
******
******
******
20. OJ
******
******
******
20.00
******
******
******
20.00
******
******
******
2C.OO
******
******
******
20. CO
******
******
******
******
-------
EC -166
N-DUTANE » 2,3-OIMETHYL8UTANE
1976 MAY 24
BEGIN IRRADIATION 1030J 0.25 INCH PYREX FILTER
ALKYL NITRATE DATA FROM c-600 CONSIDERED MORE RELIABLE THAN FROM PANALYZER
C6-N-D ATTR10UTEO TO UNKNOnN PEAK ON BOTH C-600 COLUMN AND PANALYZER.
ONLY C-600 DATA USED. CALIBRATION FACTOR ESTIMATED
ACETALOEHYOE HONITOHEO WITH 3-PART COLUMN
CO FACTOR 2.2/1.34
RADIOMETER CORRECTION -0.004 MM/CM2
T-0 AT 1030 PDT
PAN
REL HUM
HCHO
REL INT
CALIB*
9
2
1
4
to
TS
REL HUM
SSPOriER
RAOIOM
H«!0
NO
N02-CORR
N-C4
2,3-OMB
CO
ACETALD
ACETONE
MtK
DEC K
1
Kw
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CONO
INIT COND
INIT CONO
INIT CONO
INIT COhO
INIT CONO
INIT CONO
I NIT CONO
303.4
65.04
18.86
0.505
3.7656 04
0.0d8
0.012
1.816
0.319
2.149
0.001
0.004
0.001
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION! WAVELENGTH!NMJ
500.
430.
403.
36U.
370.
360.
350.
340.
330.
320.
310.
300.
290.
Kl-0.33 MIN-1
SAMPLING RATE • 1.777 L/MIH
bo cc SAMPLES TAKEN
KEL. INTENSITY
2.459
2.206
2.005
1.673
1.435
1.204
1.000
0.7U
0.476
0.234
0.093
0.029
0.0
-------
EC -166
N-BUTANE + 2,3-OIM£TMVLBUTAN6
1976 MAY 24
N3
t-0
CLOCK
TIME
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
1800
1615
1830
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
IbO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
: 330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
02ONE
PPM
0.0
0.012
0.032
0.056
0.088
0.112
0.134
0.159
0.186
0.208
0.230
0.254
0.278
0.298
0.322
0.344
0.364
0.383
0.401
0.415
0.425
0.435
0.442
0.447
0.452
0.454
0.457
0.459
0.459
0.459
0.459
0.462
0.462
NO
PPM
0.068
0.058
0.041
0.026
0.023
0.020
C.018
0.017
0.016
0.015
0.013
0.013
0.013
0.012
0.012
0.011
0.011
0.011
0.010
0.010
0.009
0.010
0.009
O.U09
0.009
0.009
0.009
0.009
0.008
0.009
0.008
0.009
0.003
N02-CORR
PPM
0.012
0.039
0.054
0.064
0.064
0.064
0.062
O.Gib
0.054
0.052
0.051
0.048
0.045
0.041
0.035
0.032
0.028
0.025
0.022
0.020
O.C19
0.015
0.012
0.011
0.010
0.009
0.009
0.009
0.007
0.007
0.007
0.007
0.007
NOX-CORR
PPM
0.100
0.097
0.095
0.090
0.087
0.084
0.080
0.076
0.070
0.068
0.065
0.062
0.058
U.053
0.047
0.043
0.039
0.035
0.032
0.030
0.028
0.025
0.022
0.021
0.019
0.017
0.017
0.017
0.015
0.016
0.015
0.015
0.015
N-C4
PPM
1.82
******
1.53
******
1.76
******
1.71
******
1.69
***v«*
1.66
******
1.63
******
1.61
***v**
1.51
******
1.53
******
1.51
******
1.48
******
1.46
******
i.44
******
1.42
******
1.40
******
1.38
2t3-OMB
PPM
0.319
******
0.282
******
0.302
******
0.308
******
0.289
******
0.282
******
0.269
******
0.264
******
0.245
******
0.250
******
0.247
******
0.234
******
0.227
******
0.222
******
0.219
******
0.207
******
0.210
-------
EC -166
N-BUTANE * 2,3-DIMtTHVLBUTANE
1976 MAY 24
CLOCK
TIME
1030
1045
1100
1115
1130
1145
1200
1215
1230
12t5
1300
1315
1330
1345
1400
1415
1433
1445
1500
1515
1530
1545
1600
1615
1630
1643
1700
1715
1730
1745
1800
1815
1830
ELAPSED
T(MIri)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
lt>5.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
CO
PPM
2.15
2.12
2.17
2.12
2.22
2.20
2.18
2.24
2.25
2.28
2.26
2.30
2.31
2.35
2.38
2.40
2.40
2.44
2.48
2.50
2.47
2.48
2.51
2.49
2.60
2.63
2.65
2.59
2.01
2.65
2.65
2.73
2.68
PAN
PPM
0.000
******
0.001
*******
0.003
******
0.006
******
0.011
******
0.012
******
0.016
******
0.021
******
0.025
******
0.029
******
0.031
******
0.035
******
0.037
******
0.038
******
0.039
******
0.040
******
0.039
HCHO
PPM
0.0
******
******
******
0.004
******
******
******
0.010
******
******
******
C.010
******
******
******
0.002
******
******
******
0.004
******
******
******
0.002
* *****
******
******
0.002
******
******
******
0.002
ACETALD
PPM
0.0014
******
******
******
0.0029
******
******
******
0.0190
******
******
******
0.0271
******
******
******
0.0353
******
******
******
0.038J
******
******
******
0.0391
******
******
******
0.0429
******
******
******
0.0429
PROPALO
PPM
******
******
0.0003
******
0.0009
******
0.0010
******
0.0019
******
0.0019
******
0.0024
******
0.0029
******
0.0032
******
0.0032
******
0.0038
******
0.0041
******
0.0038
******
0.0044
******
0.0046
******
******
******
0.0044
ACETONE
PPM
0.004
******
0.020
******
0.034
******
0.051
******
0.058
******
0.046
******
0.058
******
0.063
******
0.081
******
0.082
******
0.109
******
0.071
******
0.123
******
0.089
******
0.128
******
******
******
0.114
MEK
PPM
0.0008
******
0.0174
******
0.0232
******
0.0308
******
0.041)6
******'
0.0333
******
0.0475
******
0.0526
******
0.063S
******
0.0678
******
0.0757
******
******
******
0.0867
******
0.0785
******
0.0932
******
******
******
0.0912
C3-N-2
PPM
C-600
******
******
******
******
0.0008
******
o.ooott
******
******
******
0.0015
******
0.0016
******
******
******
0.0020
******
0.0021
******
******
******
0.0023
******
0.0023
******
0.0025
******
0.0024
******
******
******
0.0024
C3-N-2
PPM
PANAIY2R
0.0
******
0.0003
******
0.0007
******
0.0010
******
0.0014
******
0.0016
******
0.0023
******
0.6024
******
0.0026
******
0.0027
******
0.0029
******
0.0031
******
0.0034
******
0.0032
******
0.0033
******
0.0031
******
0.0032
C4-N-2
PPM
C-600
0.0
******
0.0015
******
U.0034
******
0.0044
******
0.0060
******
0.0063
******
0.0070
******
0.0089
******
0.0108
******
0.0101
******
******
******
0.0112
******
O.OltS
******
0.0125
******
0.0132
******
******
******
0.0139
C6-N-0
PPM
C-600
0.0
******
******
******
0.0010
******
0.0013
******
0.0017
******
0.0022
******
0.0025
******
0.0028
******
0.0030
******
0.0033
******
0.0035
******
0.0034
******
0.0034
******
0.0037
******
0.0035
******
******
******
0.0037
-------
EC -166
N-BUTANE * 2,3-DIHETHltL8UTANE
1976 MAY 24
N3
CLOCK
TIME
1030
1045
1100
1115
1130
IMS
1200
1215
1230
1245
1300
1315
1330
1345
14JO
1415
1430
1445
1500
1515
1530
15*5
loOO
1615
1630
1645
1700
1715
1730
1745
1800
1615
1830
ELAPSED
T4MINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
ISO.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
TS
DEC F
83.3
87.2
85.5
65.5
85.5
85.0
86.0
86.0
85.7
86.5
86.5
86.7
87.2
87.7
87.4
87.9
87.9
87.9
87.2
87.0
86.5
86.5
86.2
86.0
85.7
86.5
87.0
86.5
86.0
86.2
86.5
86.7
87.2
REL HUM
*
47.5
47.5
51.5
57.5
63.0
69.0
71.0
70.5
69.0
70.5
70.0
70.5
70.0
70.0
67.5
68.5
68.0
67.0
66.5
67.0
67.5
67.5
68.0
68.0
67.5
67.5
67.5
67.5
67.0
67.0
o7.5
67.5
67.5
SSPOMER
KW
******
******
18.90
******
19.10
******
******
******
18.90
******
******
******
18.90
******
******
******
******
******
******
******
18.70
******
******
******
19.00
******
******
******
******
******
******
******
18.50
RAOIOM
MW/CM2
******
0.465
0.482
0.480
0.482
******
******
0.470
0.480
******
******
0.487
0.482
U.480
0.475
******
******
0.480
******
0.489
0.480
0.475
******
******
0.482
0.475
******
******
0.489
0.487
0.507
0.489
0.492
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -Io8
N-BUTANE + FORMALDEHYDE
1976 MAY 28
8EGIN IRRADIATION 0930; 0.25 INCH PYREX FILTER
0755: 2 TORR HCHO IN 500 ML BULB FLUSHED INTO EC
CO FACTOR 2.2/1.3
RADIOMETER CORRECTION -0.004 MW/CM2
T«0 AT 930 POT
PAN
REL HUM
HCHO
REL INT
CALIB*
9
2
1
4
fo
M
00
TS
REL HUM
SSPOwER
RADIOM
H20
NO
N02-CQRR
N-C4
HCHO
CO
ACETONc
DEC K
t
KW
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCND
INIT CGND
INIT CONO
INIT CCND
INIT CCNO
303.2
65.81
19.70
0.486
2.777E
0.327
0.166
1.9bl
0.101
2.067
0.002
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: MAVELENGTHCNM)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
Kl-0.33 MIN-1
SAMPLING RATE « 1.758 L/MIN
88 GC SAMPLES TAKEN
REL
INTENSITY
2.461
1.966
1.980
1.661
1.439
1.180
1.000
•0.729
0.467
0.229
O.OU2
0.012
0.0
-------
EC -168
N-BUTANE * FORMALCEHVOE
1976 MAY 28
to
to
CLOCK
TJMc
930
945
1000
1015
1030
1045
1100
1115
113U
1145
1200
1215
1230
1245
1300
i315
1330
1345
14'JU
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
1600
1815
1630
1845
1900
1915
1930
1945
2000
2015
2030
2045
2100
ELAPSED
TIHINI
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
iao.
195.
210.
225.
240.
255.
270.
285.
300.
315.
' 330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
430.
495.
510.
525.
540.
555.
570.
565.
600.
615.
630.
645.
060.
675.
690.
OZONE
PPM
0.0
0.010
0.015 .
0.022
0.034
0.044
0.056
0.066
0.063
0.096
0.110
0.127
0.142
0.156
0.171
0.163
0.195
0.213
0.230
0.244
0.256
0.274
0.291
0.308
0.327
0.347
0.362
0.381
0.405
0.420
0.442
0.462
0.4U4
0.511
0.532
0.554
0.576
0.596
0.616
0.633
0.640
0.647
0.652
0.655
0.655
0.655
0.655
NO
PPM
0.327
0.2b7
0.217
0.172
0.142
0.120
0.103
0.064
U. 062
0.071
0.064
0.057
0.053
0.049
0.044
0.042
0.035
0,034
0.033
0.027
0.027
0.024
C.024
0.021
0.021
0.020
0.017
0.016
0.016
C.015
0.013
0.013
0.013
0.012
0.012
0.012
0.011
0.012
0.011
0.010
0.010
0.011
0.010
0.010
0.010
0.010.
0.011
N02-CORR
PPM
0.166
0.204
0.239
0.271
0.285
0.293
0.297
0.302
0.293
0.291
0.28U
0.279
0.274
0.268
0.258
0.247
0.242
0.231
0.222
0.217
0.204
0.193
0.185
0.175
0.164
0.149
0.139
0.123
0.119
0.103
0.092
0.061
0.067
0.056
0.046
0.039
0.030
0.021
0.014
0.007
0.0
0.0
0.0
0.0
0.0
0.0
0.0
NOX-CORR
PPM
0.493
0.472
0.457
0.446
0.428
0.414
0.400
0.386
0.376
0.363
0.351
0.33d
0.328
0.317
0.302
0.289
0.279
0.267
0.256
0.244
0.231
0.218
0.208
0.193
0.185
0.169
0.158
0.145
0.134
0.118
0.106
0.094
0.061
0.069
0.060
0.052
0.041
0.032
0.025
0.018
0.011
0.010
0.007
0.005
0.004
0.002
0.002
N-C4
PPM
1.961
1.918
1.882
1.862
1.813
1.791
1.775
1.755
1.750
1.722
1.709
1.694
1.671
1.661
1.646
1.623
1.616
1.595
1.567
1.562
1.552
1.534
1.519
1.493
1.493
1.476
1.460
1.427
1.422
1.412
1.410
1.377
1.354
1.354
1.323
1.321
1.023
1.286
1.227
******
1.237
******
1.227
******
1.204
******
1.178
HCHO
PPM
0.101
******
******
******
0.040
******
******
******
0.036
******
******
******
0.044
******
******
******
0.048
******
******
******
0.050
******
******
******
0.042
******
******
******
0.050
******
******
******
0.040
******
******
******
0.040
******
******
******
0.040
******
******
******
0.044
******
******
-------
EC -168
N-BUTANE * FORMALDEHYDE
1976 MAY 28
Co
O
CLOCK
TIMt
930
945
1000
1015
1030
1045
1100
1115
1130
1145
I2ou
1215
1230
1245
1300
1315
133J
1345
140J
1415
14JO
1445
1500
1315
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
ibOu
1815
1830
1045
1900
1915
1930
1945
2000
2015
2030
2045
2100
ELAPSED
T(HIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
423.
435.
450.
465.
480.
495.
510.
525.
540.
555.
570.
585.
600.
otS.
630.
645.
660.
675.
690.
CO
PPM
2.07
2.07
2.14
2.13
2.22
2.27
2.20
2.30
2.35
2.37
2.39
2.41
2.46
2.47
2.47
2.50
2.56
2.59
2.58
2.60
2.62
2.62
2.66
2.68
2.77
2.76
2.U1
2.82
2.83
2.84
2.88
2.93
2.92
2.93
2.96
2.94
3.03
3.09
3.08
3.11
3.09
3.13
3.21
3.17
3.21
3.25
3.21
PAN
PPM
0.000
******
0.003
******
0.005
******
0.007
******
0.012
******
0.015
******
0.019
******
0.022
******
0.025
******
0.029
******
0.033
******
0.037
******
0.041
******
0.046
******
0.049
******
0.056
******
0.064
******
C.070
******
0.076
******
0.083
******
0.092
******
0.091
******
0.092
******
O.O92
ACETALD
PPM
******
******
0.029
******
0.036
******
0.042
******
0.054
******
0.060
******
O.C62
******
O.J70
******
0.077
******
O.Odl
******
0.080
******
0.093
******
U.087
******
0.096
******
0.093
******
0.105
******
0.099
******
0.114
******
0.114
******
******
******
J.114
******
******
******
0.089
******
0.113
PROPALD
PPM
0.0001
******
0.0005
******
0.0009
******
0.0013
******
0.0016
******
0.0020
******
0.0022
******
0.0026
******
0.0029
******
0.0034
******
0.0037
******
0.0043
******
0.0043
******
0.0047
******
0.0048
******
0.0059
******
0.0060
******
0.0070
******
******
******
******
******
0.0081
******
******
******
0.0070
******
0.0076
ACETONE
PPM
0.0024
******
0.0029
******
0.0045
******
0.0056
******
0.0047
******
0.0077
******
U.OJ86
******
0.0069
******
0.0084
******
0.0097
******
0.0107
******
O.OOB4
******
0.0108
******
0.0085
******
0.0092
******
0.0151
******
0.0139
******
0.0213
******
0.0249
******
******
******
0.0385
******
******
******
0.0259
******
0.0368
BUTYRAL
PPM
0.0002
******
0.0013
******
0.0021
******
0.0025
******
0.0029
******
0.0033
******
0.0034
******
0.0035
******
0.0038
******
0.0042
******
0.0043
******
0.0044
******
0.0046
******
0.0049
******
0.0048
******
0.0052
******
0.0053
******
0.0055
******
0.0056
******
******
******
0.0058
******
******
******
0.0061
******
0.0052
MEK
PPM
0.0002
******
0.0258
******
0.0450
******
0.0576
******
0.0582
******
0.0789
******
0.0882
******
0.0835
******
0.0973
******
0.1080
******
O.lloO
******
0.1020
******
0.1250
******
0.1130
******
0.1200
******
0.1500
******
0.1450
******
0.1700
******
0.1710
******
******
******
0.1930
******
******
******
0.1770
******
0.1810
ME-N
PPM
0.0
******
0.0
******
0.0
******
0.0
******
0.0002
******
0.0003
******
0.0003
******
0.0004
******
0.0005
******
0.0006
******
0.0006
******
0.0006
******
0.0006
******
0.0010
******
0.0010
******
0.0011
******
0.0009
******
0.0008
******
0.0009
******
0.0009
******
0.0008
******
0.0003
******
0.0009
******
0.0010
C2-N
HPM
0.0
******
0.0002
******
0.0003
******
0.0003
******
0.0004
*v****
0.0005
******
0.0007
******
04 JU08
******
0.0008
******
0.0008
******
0.0009
******
0.0008
******
0.0009
******
0.0008
******
0.0011
******
0.0012
******
0.0012
******
0.0011
******
0.0011
******
0.0011
******
0.0011
******
0.0011
******
0.0012
******
0.0011
C4-N-2
PPM
C-600
0.0
******
O.OU37
******
0.0063
******
0.0063
******
0.0103
******
0.0117
******
0.0132
******
0.0149
******
0.0153
******
O.OiSl
******
0.0179
******
o.oibtt
******
0.0193
******
0.0202
******
0.0216
******
0.0229
******
0.0240
******
0.0252
******
0.0258
******
******
******
0.0283
******
******
******
0.0289
******
0.027U
C4-N-1
PPM
C-600
0.0
******
0.0011
******
0.0010
******
0.0013
******
0.0016
******
O.OU17
******
0.0020
******
O.Oui.3
******
0.0020
******
0.0022
******
0.0025
******
0.0023
******
0.0022
******
0.0025
******
0.0026
******
0.0029
******
0.0034
******
O.OU31
******
0.0030
******
******
******
0.0029
******
******
******
0.0035
******
0.0032
-------
EC -168
N-BUTANE + FORMALOEHYCE
1976 MAY 28
to
CLOCK
TIME
930
945
1000
1015
1030
1045
UOU
1115
1130
1145
1200
1215
1230
12*5
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
IbOO
1615
1630
1645
1700
1715
1730
1745
1800
1815
1830
1845
1900
1915
1930
1V45
2000
2015
2030
2045
2100
ELAPSED
T(HIN)
0.
IS.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
510.
525.
540.
555.
570.
585.
600.
615.
630.
645.
660.
675.
690.
TS
DEC F
84.0
85.7
84.8
65.2
86.0
86.0
8t>.2
86.2
66.2
66.5
86.2
86.5
86.5
86.5
86.2
86.2
86.0
86.0
85.7
86.0
86.0
86.2
86.0
86.2
86.2
86.5
85.7
85.7
86.0
85.5
86.0
86.2
86.2
86.2
86.5
87.2
87.0
87.0
87.0
87.2
87.2
86.5
67.0
66.5
86.7
80.2
86.5
REL HUH
*
50.5
52.5
57.5
65.5
67.5
68.5
63.5
68.5
69.0
68.5
69.0
69.0
68.5
69.0
68.5
63.5
6S.5
68.5
68.0
68.5
67.5
67.5
67.5
67.5
67.0
67.0
66.5
66.5
66.5
66.5
66.0
66.5
66.0
66.0
66.0
66.0
65.5
65.5
65.5
65.5
65.5
65.5
65.0
65.5
65.5
65.5
65.0
SSPOWER
KM
******
19.50
19.50
******
19.50
******
******
******
19.40
******
******
******
19.80
******
******
******
19.40
******
******
******
19.40
******
******
******
19.60
******
******
******
19.60
******
******
******
20.20
******
******
******
20.20
******
******
******
20.20'
******
******
******
19.30
******
******
RADIDM
MW/CM2
******
0.477
0.475
0.480
0.499
0.480
0.485
0.499
0.480
0.487
0.487
0.489
0.489
0.480
******
******
0.485
0.485
0.477
******
0.494
0.482
******
******
0.504
0.494
0.477
0.472
0.480
******
0.492
******
0.494
0.499
******
******
0.511
******
******
******
0.502
0.480
0.494
******
0.472
0.487
0.487
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
-------
ro
u>
ec -it>9
2t3-DIMETHYLBUTANE
1976 JUN 2
BcGIN IRRA01ATIUN 093C; C.25 INCH PVFEX FILTER
ALKYL MTRATE CATA FROM C-600 COHSlCcREO MORE RELIABLE THAN FROM PANiLYiER
C6-N-D ATTi*iboTEt) TO UNKNCrtN PtAK CN BOTH C-600 COLUMN ANJ PANALY^EK.
ONLY C-oOO DATA USEC. CALIoRATIdM FACTCR ESTIMATED
HCHO DATA JUESTIOMACILE, CCLOR i<4 DLANK, NEN BLANK AT luoo
ACETALD MONITbREO ON 3-PAHT COLUMN
co FACT:)* 2.2/1.28
T«0 AT 930 POT
CALIb*
PAN
REL HUM
HCHO
REL INT
TS
HEL HUM
SSPu»cK
KAtiOM
H20
NO
CUi-Ci-RR
2t3-i/rtfa
CO
HCriU
ACETONE
MEK
0£G K
4
Krt
M<(/CK2
PHM
PPH
PPM
PPM
PPM
PPM
PPM
PPM
9
2
1
4
AVERAGE
AVERAGE
AVERACf.
AVERAGE
AVERAGE
INIT CCNO
UIT CCNO
INIT CCNO
IMT CCNO
IMT CCNO
INIT CCNO
INIT CCNJ
JCfc.b
tS.l'i
19.97
C.U7
C.Co4
C.740
3.6UZ
O.CiC
0.1/03
O.COO
AiblGNED INITIAL CCNOITION
SPECTRAL DISThlfaOTIUN:
5CC.
430.
403.
3UO.
370.
360.
350.
J40.
330.
320.
31C.
300.
Kl-0.33 MIN-1
SAHPLINii RATE * 1.714 L/MIN
69 GC SAMPLES TAKEN
REL. INTENSITY
2.bOu
2.313
2.092
I.o95
1.449
l.ltio
l.CUJ
0.716
0.440
0.203
O.Cti
0.010
O.C
-------
6C -169
2,3-OlrtEThirLBUTANE
1976 JUN 2
ro
CLOCK
TIME
930
945
1000
iOl5
1030
10*5
1100
1115
1130
11*5
120J
1215
1230
12*5
1300
1315
1330
13*5
1*00
1*15
1*30
14*5
1500
1515
1530
15*5
160J
Ibl5
1630
lb*5
1700
1715
1730
174i
1600
idl 5
loJO
18*5
1900
1915
1930
I9*j
2000
201S>
203J
20*5
2100
2115
21 3 J
ELAPSED
TIMIN)
0.
15.
30.
*5.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
2*0.
255.
270.
205.
3 JO.
315.
J30.
3*5.
360.
375.
390.
*05.
420.
435.
450.
465.
*dO.
*95.
510.
525.
5*0.
555.
570.
5d5.
bOO.
615.
630.
6*5.
660.
675.
o90.
705.
720.
OZONE
PPM
0.0
0.015
0.02*
0.03*
O.U39
0.0*9
0.061
O.Obd
0.078
O.Odd
0.098
0.103
0.112
0.125
0.132
0.142
0.151
U. 161
0.169
O.ldl
0.191
0.203
0.213
0.225
0.237
0.2-19
0.264
0.276
0.288
0.3UO
u.320
0.335
0.354
0.369
0.333
0.4J1
0,415
0.432
0.4*2
0.*52
O.H64
O.*71
0.*79
O.*d*
0.486
O.*d9
0.491
0.491
0.493
NO
PPM
0.127
O.lOd
C.Od*
0.072
C. 062
0.053
C.04d
C.044
0.041
C.040
C.034
C.034
0.030
C.C2d
C.028
0.0l5
a. 023
C.022
C.022
C.020
C.GIB
0.016
C.Old
U.016
0.015
C.016
C.014
C.012
C.012
0,013
0.012
C.012
C.012
0.012
O.J09
C.010
C.010
C.U09
u.008
c.ota
0.009
C.003
C.OU9
C.OOd
C.G09
C.C08
C.CCd
O.OOd
0.009
NJ2-CORR
PPM
0.064
C.CdO
C.C9d
O.lCd
0.113
0.117
C.119
0. 121
0.121
C.12J
0.124
0.120
0.121
C.120
0.11J
C.119
C.U7
0.114
0.111
0.109
0.1 Co
0.104
0.101
C.CS8
0.094
C.OSC
o.cea
O.CB6
o.oao
O.C77
O.G73
J.066
0.064
0.060
O.C57
0.052
O.u*b
0.0*5
0.0*1
C.C39
0.036
0.033
0.032
0.030
0.029
0.027
u.027
0.026
0.02!>
NOA-CCM*
PPM
0.191
O.liJd
0.182
0.180
0.175
0.171
0.163
0.166
O.U3
0.15J
0.15d
0. 15t
U.151
0.149
0.147
0.144
0.141
0.136
0.133
0.129
0.124
0.121
0.119
0.114
0.11J
0.103
0.101.
0.098
0.092
0.091
o.OdS
0.080
0.076
0.073
0.063
0.062
0.058
0.054
0.049
0.047
0.04*
0.041
0.040
0.039
0.037
0.035
0.036
0.035
0.034
2 1 3- EMU
PPM
0.740
******
0.7 Id
******
0,&9d
******
0.061
******
0.631
******
0.620
******
0.5S1
******
0.578
******
0.554
******
0.335
******
0.510
******
0.4S1
******
0.470
******
0.470
******
0.4*9
******
0.*27
******
0.413
******
0.397
******
0.395
******
0.363
******
0.346
******
0.335
******
0.324
******
******
******
******
-------
EC -169
1976 JUN 2
CLUCK
TIME
930
945
1000
1015
10JO
1045
1100
1115
1130
1145
120J
1215
12^0
12t3
13oO
1315
1330
13<»5
CO 140J
•P- )415
143J
1445
1500
1513
1330
1545
160 j
1615
1630
1645
1700
1713
17->0
1745
IttOO
1815
1830
1645
1900
1915
1930
19-.5
2000
2015
2030
2043
2100
2115
2130
tLAPSEC
TtMltU
0.
15.
30.
45.
63.
75.
90.
105.
120.
135.
150.
165.
loO.
193.
210.
225.
240.
255.
270.
2d3.
300.
315.
330.
345.
360.
375.
390.
4O5.
420.
435.
450.
4o5.
480.
495.
3lO.
525.
540.
555.
570.
5e5.
oOO.
615.
630.
645.
6bO.
675.
690.
70i>.
720.
CO
PPM
3.68
3.64
3.67
3.71
3.o9
3.76
3.68
3.73
3.78
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
4.01
4.07
4.05
4.05
4.10
******
******
******
******
4.09
4.19
4.18
4.18
4.18
4.17
4.21
4.25
4.25
4. 28
4.24
4.29
4.29
******
PAN
PPM
C.vCJ
******
O.OOJ
******
C.001
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EC -169
<£, 3-01 KETHH. BUTANE
1976 JUN 2
N3
Co
t_n
CLOCK
tine
930
945
1UOJ
1015
1030
1045
1100
1115
1130
11*5
1200
1215
12 3 0
1245
1300
1315
1330
1345
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1415
1430
1445
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1515
1530
1545
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1730
1745
1800
181 j
1830
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1900
1915
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2000
2015
2030
2045
2100
2115
2130
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0.
15.
30.
45.
60.
75.
90.
105.
12J.
135.
150.
Iu5.
180.
195.
210.
225.
240.
255.
270.
265.
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315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
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510.
525.
540.
555.
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585.
600.
615.
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645.
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720.
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DEC f
35.2
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84.5
84.0
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93.6
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94.8
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Lo
EC -171
2,3-JIHcTHYL8UTANE
1976 JUN 9
IP.RAOIATICN O900» 0.25 INCH PYP.EX FILTER
ACfcULOEHIOc MCMTOREU CN 3-PART COLUMN
C6-N-D ATlRlauTEt; TO UNnNChN PEAK C.M BOTH C-600 COLUMN AND
CALIBRATION FACTOR ESTIMATED
ALlUL NITRATE CAT A f(-CH C-600 CONSICERED MORE RELIABLE THAN FROM PANALYIER
jPEC OISTRld DATA FRCM STRIP CHART (£5 NM/INCHI
CO FACTOR 2.
-------
eC -171
2 ,3-UIWeTHVLUUTANE
1970 JUN 9
LLuCK
IIME
900
915
930
94a
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
143J
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
17"»5
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1830
1645
1900
1915
1930
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0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
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255.
270.
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315.
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cC -171
2,3-DlMcThYLeuTAflE
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CLOCK
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EC -171
2.3-DIMETHYL6UTANE
19 tt> JUN 9
CLOCN
TIME
900
915
930
9S£C
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15.
30.
45.
60.
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300.
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85.0
60.0
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20.00
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20.00
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20.00
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-------
O
EC -172
N-bUTANE «• 2,3-DlMETI-YLfaUTANE
1976 JUN 10
IKKAOIATICN 0915; 0.25 INCH pvaex FILTER
ACETALlitHYOE fCMTGkEC CN 3-PART COLUMN
ALKVL NITRATE DATA PhCM C-600 CGNSIOEREO MORE RELIABLE THAN FROM PANALYZER
L.6-N-D ATTRIduTED TU UNKNCwN PEAK CN BCTH C-600 COLUMN AND PANALVidR.
CAL16RATICN FACTCR ESTIMATED
CO FACTOR 2.2/1.25
RADIOMETER CORRECTION -C.002 MH/CM2
T»0 AT 915 POT
CALIB»
PAN
REL HUM
HChC
ScL INT
TS
REL HUM
SSHU-E*
KAOIOM
H20
NO
N02-CURR
N-C4
2.3-OM8
C'J
ACETALD
ACfcTONe
OEli K
*
KM
MH/CM2
PPM
PPM
PPM
PPM
PPh
PPM
PPM
PPM
9
2
1
4
AVERAGE
AVERAGE
AVErtAGc
AVERAGE
AVESttGE
IMT CCNO
INIT CCNO
IMT CLND
INIT CCNd
IMT CCND
INIT CtNO
INIT CCNO
303.3
C.-ifco
1.303E 05
O.C79
O.C17
C.339
C.
-------
EC -172
197o JUN 10
2,3-CIMET>Yl_euTANE
CLOCK
TIMc
915
930
9*>5
1000
1015
1C30
1045
1100
1115
1130
1145
1200
12 15
1230
12-.5
1300
1315
1330
1345
1400
1415
ItiO
1443
1500
1515
1530
1545
1600
1615
1630
1045
1700
1715
1730
1745
IbOJ
1613
I(i30
1845
1900
1915
1930
1945
20uO
2015
2030
2O45
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0.
15.
30.
45.
oj.
75.
90.
105.
120.
135.
130.
165.
IdO.
195.
210.
225.
240.
255.
270.
235.
JOO.
315.
330.
345.
560.
375.
3SO.
405.
420.
435.
450.
4b5.
4dO.
495.
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525.
540.
555.
570.
5d5.
600.
615.
630.
c»45.
660.
675.
690.
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PPM
0.0
0.012
0.022
0.032
0.03
0.095
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0.188
0.203
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0.225
0.237
0.247
0.239
0.269
0.278
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0.298
0.303
0.31b
0.327
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0.342
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PPM
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-------
EC -172
N-bUTANE + 2,3-DIMEThYLBUTANE
1976 JUN 10
.LUCN
TIMc
915
930
9*5
1000
1015
1030
10*5
1100
1115
1130
11*5
1200
1*15
1230
U45
1300
1313
1330
1345
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1*30
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1300
1515
1530
1545
1600
1613
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1645
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1715
1730
17*5
180u
1813
Id30
16*5
1900
1915
193o
19*5
2000
2015
2O3u
20*5
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TIMINJ
0.
15.
30.
45.
oO.
75.
90.
105.
1^0,
135.
150.
165.
180.
195.
210.
225.
2*0.
255.
270.
2t5.
300.
315.
330.
345.
3oO.
375.
390.
405.
420.
433.
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465.
480.
495.
510.
525.
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555.
570.
365.
600.
615.
630.
645.
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690.
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2.46
2.51
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2.54
2.53
2.57
2.55
2.61
2.59
2.35
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2.68
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w
EC -172
N-BUTANE *
2 . 3-01 ME T(-»(. BUTANE
1976 JUN 10
CLOCK
TIME
915
930
y*5
1000
1015
1030
10*5
1100
1115
113J
11*5
UOO
1215
1230
12*5
1300
1315
1330
1.1*5
1*00
1*15
1*30
1**5
1500
1515
1530
15*5
1600
1615
1630
16<0
1700
1715
1730
17*5
1800
1815
1630
18*5
1900
1913
1930
19*5
2000
2015
2030
20*5
ELAPSEC
T(MIN)
0.
15.
30.
*5.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
2*0.
255.
270.
285.
300.
315.
330.
3*5.
360.
375.
390.
*05.
*20.
*35.
*50.
*05.
*30.
*95.
510.
525.
5*0.
555.
570.
565.
600.
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630.
u*5.
660.
675.
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TS
UtO F
St*5
87.9
86.5
87.0
07. C
S7.0
86.5
66.5
86.2
86.5
85.0
86.0
B5.7
85.7
66.0
86.0
86.0
65.5
85.7
65.5
85.5
86. C
65.7
66.2
8*. 8
85.0
85.0
85.2
65.5
85.2
86.0
86.2
06.5
86.5
86.5
86.7
86.5
86.5
86.2
66.2
86.2
86.2
86.2
86.2
66.0
85.7
66.2
REL HUM
*
*6.5
*6.5
50.5
52.5
55.0
58.5
61.0
61.5
62.0
62.5
63.0
62.5
62.0
62.0
62. 0
62.5
62.0
62.0
ol.5
61.5
61.5
61.5
61.5
61.5
61.0
61.5
61.5
61.5
61.5
61.5
61.0
61.0
******
******
******
******
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SSPOwER
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******
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19.70
20.00
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20.10
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20.00
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-------
EC -177
PKOPeNE
l-ilo JUL 9
6EGIU Ih^AOIATICN 09455 C.25 INCH P^KEX FILTER
BRADY USs USED; CALI8 JUL 16t 1976; VOLTAGE EXCEEUtO CAPACITY OF UACS AT 1015J
VOLTAGE CIVIGEft ACCEC 1638.
CO FACTOR 2.2/1.21
RADIOMETER CORRECTICN -0.002 MK/CM2
T*0 AT 945 POT
PAN
HCriO
«EL INT
TS
«EL HUM
SSPJ»:R
KAi>IUM
HZu
NO
i02-CCRR
PKuPENE
PAN
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ACcTALU
ACcTCut
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K*
MH/LM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
1
4
AVErtAGE
AVEWACt
AvtRAtc
AVErtACt
AVERALt
INIT CCNO
IMT Ctt\C
INIT CCND
INIT Ci-NO
IMT CCNO
IMT CCND
INIT CCNO
307.0
t3.40
13. 71
0.357
3.3^3E
C.364
C.CS9
0.493
0.001
C.C10
0.001
0.001
04
ASSIGNED INITIAL CCNCITIUN
SPECTRAL DISTRIBUTIONS KAVELENGTH4NMJ
5.00.
430.
403.
38G.
370.
36J.
350.
330.
31o!
300.
280.
M«0.33 MIN-1
SAMPLING KATE « 1.7C9 L/MIN
35 GC SAMPLES TAKEN
INTENSITY
2.072
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C36
000
637
0.377
0.166
O.C30
C.C01
0.0
-------
EC -177
PRdPENE
1976 JUL 9
CLOCK.
TIMc
945
1000
1013
U3J
10-45
11 JO
1113
1130
1145
12uJ
1213
K30
12t5
1300
1315
1330
13*3
140J
1415
1410
14*3
15GO
1515
1530
1545
1600
1615
1630
1645
1700
1715
ELAPSED
TIM1N)
0.
15.
30.
45.
60.
7S.
90.
105.
120.
135.
150.
165.
loO.
195.
210.
223.
240.
255.
270.
265.
30J.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
CZCME
PPM
U.(J
0.0
0.0
0.007
0.022
O.u
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to
EC -177
PROPENE
197o JUL 9
CLUCK
rue
9*5
luoo
1015
1030
1045
UUO
1115
1130
1145
1<00
1215
123J
1245
13 OJ
1315
1330
1345
ItOO
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
Io45
17JO
1715
ELAPSEC
T1MINI
0.
15.
JO.
45.
60.
?5.
90.
105.
120.
135.
150.
165.
130.
195.
210.
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C. C6*<
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0.091
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0.040
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0.040
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ACETALO
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0.001
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0.065
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0.119
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0.145
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0. 161
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0.164
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0.172
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0. 186
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0. 168
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0.157
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0.139
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0.120
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PKOPALO
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0.0031
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0.0039
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0.0042
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O.OJ40
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0.0044
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0.0036
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ACETLNE
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0.0011
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0.0026
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0.0033
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0.0041
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C.0046
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0.0060
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0.0037
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O.CJdO
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U.0079
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0.014d
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BUTVRAL
PPM
0.0001
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O.OOJ2
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0.0003
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O.U005
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0.0007
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0. J009
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0.0011
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O.OOL5
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0.0016
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O.OOld
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0.0019
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0.002U
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0.0019
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MEK
PPM
0.0001
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0.0002
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0.0001
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O.OOJ2
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0. J002
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0.0002
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0.0002
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0.0003
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0.0004
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0.0005
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0.01*05
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0.0006
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O.U004
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PRUX
PPM
0.0
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******
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o.oooi
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o.oou/
******
0.0010
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0 . JU 1 5
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li.0014
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O.OOlo
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0.0ul7
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O.JUlV
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0.0012
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******
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0.0
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0.0
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0.0002
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U.OJ05
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0. Jjlu
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0.0011
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O.OO12
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******
******
0.0012
******
******
******
0.0011
-------
£C -1/7
PkJPENE
197o JUL 9
CLOCK
TI.MH
945
1000
iO!5
1030
1045
1100
1115
1130
Ilt5
1200
1215
1*30
1245
1300
1315
1330
134a
1400
1415
1430
1445
1500
1»15
1530
1545
16uO
1615
I63u
1645
1700
1715
ELAPSED
TIMINJ
0.
15.
30.
45.
60.
75.
90.
Iu5.
120.
135.
150.
165.
160.
1-95.
210.
225.
240.
2^3.
270.
2t)5.
300.
315.
330.
345.
360.
J75.
390.
405.
4£0.
V35.
450.
TS
OEU f
75.2
B4.5
03.0
63.0
63.5
76.7
ao.a
86.5
69.6
91 . b
93.1
9f .3
95.5
96.0
96.5
97.2
97.5
96.5
9u.2
9d.4
99.2
99.2
99.2
99.4
96.9
99.2
99.2
99.2
99.7
99.4
99.2
R6L HUM
X
54.0
56.5
******
******
******
******
******
******
******
******
**«#«*
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
&b.5
69. 0
69.0
SSFdWtR
Kh
14.40
13.60
13.50
******
13.40
******
******
***?**
13.50
******
******
******
13.40
******
******
******
******
******
******
******
13.50
******
******
******
14.10
******
******
******
14. CO
******
******
RAOtCM
MW/CM2
******
0.369
0.3o2
0.350
0.350
C.350
******
0.355
0.352
0.347
******
******
******
******
******
******
******
******
0.350
0.352
0.342
0.345
0.342
0.372
0.36'-)
0.369
0.372
0.364
O.ioO
G.364
0.374
HCH0 VOL
L
20.00
******
******
******
20. CO
******
******
******
20. CO
******
******
******
******
20. CO
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
******
******
******
******
******
******
-------
EC -178
N-8UTANE
1976 JUL 13
BEGIN IRRADIATION 0915; 0.25 INCH PYREX FILTER
C4-N-2 JATA FROM C-600 COLUMN CONSIDERED MORE RELIABLE THAN FROM PANALYZER
6RAOY 1296 USED! CALI8 JUL 16, 1976
CO FACTOR 2.2/1.21
RADIOMETER CORRECTION -0.001 MW/CM2
T*0 AT 915 PDT
PAN
HCHO
REL INT
CALIBtf
9
1
it
oo
TS DEC K
REL HUM *
SSPOkiER KM
RADIUM MW/CM2
H20 PPM
NJ PPM
N02-CORR PPM
N-C4 PPM
ACETALD PPM
ACETONE PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
IN IT CONO
INIT COND
INIT CCNO
INIT CCNO
302.2
56.96
14.46
0.362
2.bG5E 04
0.087
0.011
1.961
0.001
0.001
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: hAVELENGTH(NM)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
Ki«0.33 MIN-1
SAMPLING RATE * 1.771 L/HIN
71 GC SAMPLES TAKEN
REL.
INTENSITY
2.196
.812
.598
.400
.273
.100
.000
0.836
0.617
0.381
0.167
0.032
0.0
-------
N3
EC -178
N-8UTANE
1976 JUL 13
CLOCK
TIMe
915
930
9f5
1000
1015
1030
1043
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
134*
1400
1415
1430
1445
150J
1515
1530
1545
1600
1615
1630
1645
1700
1715
173U
ELAPSED
TIHIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
OZONE
PPM
0.0
0.0
0.012
0.020
0.042
0.061
0.088
0.103
0.127
0. 142
0.166
0.188
0.208
0.225
0.247
0.259
0.278
0.291
0.305
0.325
0.337
0.347
0.352
0.362
0.366
0.371
0.374
0.376
0.379
0.379
0.381
0.381
0.381
0.383
NO
PPM
0.087
0.067
0.042
0.030
0.023
0.018
0.018
0.017
0.016
0.017
0.015
0.013
0.011
0.014
0.011
0.011
0.011
0.010
0.010
0.013
0.010
0.010
0.010
0.010
0.009
0.009
0.009
0.010
0.010
0.010
0.013
0.010
0.009
0.009
N02-CORR
PPM
0.011
0.030
0.050
0.062
0.064
0.066
0.062
0.059
0.055
0.050
0.048
0.046
0.048
0.035
0.034
0.029
0.026
0.020
0.015
0.010
0.011
0.009
0.006
0.004
0.032
0.002
0.001
0.0
0.0
0.0
0.0
0.0
0.0
0.0
NOX-CORR
PPM
0.099
0.097
0.095
0.092
0.088
0. 083
0.080
0.076
0.071
0.066
0.063
0.053
0.059
0.049
0.045
0.040
0.036
0.031
0.025
0.024
0.021
0.019
0.016
0.014
0.012
0.012
0.010
0.009
o.ooa
0.006
0.005
0.005
0.005
0.006
N-C4
PPM
1.96
1.94
1.92
1.90
1.86
1.85
1.84
1.81
1.80
1.7d
1.77
******
1.73
1.71
1.70
1.67
1.66
1.64
1.62
1.61
1.60
1.56
1.57
1.55
1.55
1.52
1.51
1.50
1.50
1.48
1.47
1.47
1.45
1.44
-------
EC -178
N-BUTANE
1976 JUL 13
CLOCK
TIME
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
153J
1545
1600
1615
1630
1645
1700
1715
1T30
ELAPSED
TIM1NJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
CO
PPM
******
2.15
2.19
2.15
2.20
2.22
2.16
2.17
2.19
2.25
2.25
2.24
2.26
2.30
2.31
2.36
2.38
2.39
2.38
2.43
2.38
2.41
2.44
2.42
2.50
2.46
'2.50
2.53
2.57
2.53
2.54
2.58
2.66
2.65
PAN
PPM
0.000
******
0.001
******
0.003
******
0.005
******
0.009
******
0.013
******
0.017
******
0.021
******
0.026
******
0.031
******
0.034
******
0.037
******
0.039
******
0.040
******
0.043
******
0.045
******
0.045
******
HCHO
PPM
0.0
******
******
******
0.024
******
******
******
0.010
******
******
******
0.010
******
******
******
0.016
******
******
******
0.010
******
******
******
0.018
******
******
******
******
******
******
0.0
******
******
ACETALO
PPM
0.0010
******
******
******
0.0376
******
0.0378
******
0.0455
******
0.0543
******
0.0582
******
0.0686
******
0.0673
******
0.0781
******
0.0792
******
0.0855
******
0.0887
******
0.0871
******
0.0831
******
0.0916
******
0.0857
******
PKOPALO
PPM
0.0001
******
0.0003
******
0.0007
******
0.0011
******
0.0015
******
0.0019
******
0.0020
******
0.0027
******
0.0026
******
0.0031
******
0.0030
******
0.0037
******
0.0038
******
0.0039
******
0.0039
******
0.0041
******
0.0037
******
ACETONE
PPM
0.0009
******
0.0025
******
0.0028
******
0.0041
******
0.0048
******
******
******
0.0056
******
0.0055
******
0.0046
******
0.0065
******
0.0061
******
0.0079
******
0.0078
******
0.0087
******
0.0066
******
0.0090
******
0.0074
******
BUTYRAL
PPM
0.0001
******
0.0007
******
0.0015
******
0.0020
******
0.0024.
******
0.0028
******
0.0030
******
0.0035
******
0.0035
******
0.0039
******
0.0041
******
0.0043
******
0.0045
******
0.0046
******
0.0043
******
0.0048
******
0.0047
******
MEK
PPM
0.0000
******
0.0105
******
0.0237
******
0.0354
******
0.0391
******
0.0435
******
0.0495
******
0.0577
******
0.0546
******
0.0690
******
0.0687
******
0.0810
******
0.0827
******
0.0863
******
0.0739
******
0.0907
******
0.0786
******
C2-N
PPM
0.0
******
0.0
******
0.0010
******
0.0010
******
0.0010
******
0.0010
******
0.0010
******
0.0015
******
0.0015
******
0.0020
******
0.0020
******
0.0015
******
0.0020
******
0.0020
******
0.0015
******
0.0020
******
0.0020
******
C4-N-2
PPM
C-600
0.0
******
0.0019
******
0.0043
******
0.0051
******
0.0065
******
0.0078
******
0.0092
******
0.0103
******
******
******
0.0124
******
0.0132
******
0.0146
******
0.0148
******
0.0151
******
0.0157
******
0.0157
******
0.0159
******
C4-N-2
PPM
PANALYiR
0.0
******
0.0021
******
0.0042
******
Ll.OJbb
******
0.0u73
******
0.008b
******
0.0o9b
******
0.0114
******
0.0122
******
0.0135
******
0.0144
******
0.0152
******
0.0159
******
0.0161
******
0.0164
******
0.0168
******
0.0170
******
C4-N-1
PPM
PANALYiR
0.0
******
0.0008
******
0.0009
******
0.0007
******
0.0010
******
0.0010
******
O.OulZ
******
0.0014
******
******
******
0.0019
******
0.0014
******
0.0016
******
0.0015
******
0.0016
******
0.0015
******
0.0021
******
0.0020
******
-------
fO
l-n
EC -178
N-BUTANE
1976 JUL 13
CLOCK
TIME
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
13*5
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
ELAPSED
T(MIN»
0.
IS.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ido.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
TS
DEG F
62.8
65.0
64.8
85.2
65.7
85.0
85.5
89. 2
89.2
89.2
89.9
90.6
90.9
91.4
92.1
92.3
92.8
92.8
92.8
92.8
92.8
92.8
93.1
93.1
93.3
93.3
93.8
94.0
94.0
94.8
94.8
95.0
95.0
89.6
REL HUM
*
45.0
46.0
48.5
51.0
54.0
55.0
57.0
53.5
59.5
60.0
61.0
61.0
60.5
60.5
60.0
60.0
60.5
60.5
61.0
61.0
61.5
61.0
61.0
61.0
60.5
60.5
60.0
60.0
51.0
52.0
52.5
52.0
52.0
51.0
SSPOrfER
KM
******
16.00
******
******
14.00
******
******
******
******
******
******
******
14.20
******
******
******
14.10
******
******
******
14.20
******
******
******
14.20
******
******
******
14.50
******
******
******
14.50
******
RADIQM
MH/CM2
******
0.358
0.361
0.353
0.351
0.348
0.351
0.375
0.356
******
******
0.363
0.356
******
******
******
0.348
0.368
0.3t>3
0.358
0.346
0.361
0.361
0.368
0.361
0.373
0.365
0.370
0.373
0.365
0.373
0.370
0.387
0.368
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
20.00
******
******
-------
EC -216
PROPENE
1977 FEB 1*
BEGIN IRRADIATION 09*5} 0.25 INCH PYREX FILTER
HCHO ABSORBANCE CORRECTED FOR 15 ML H20 USED IN BUBBLERS
BRADY I6t>3
CO FACTOR 1.8/0.35; CH4 1.120/0.955; THC 1.120/2.41
T*0 AT 945 PST
PAN
REL HUM
HCHO
REL INT
CALIBtf
10
2
1
4
to
Ln
TS
REL HUM
SSPOWcP
RAOIOH
H20
NO
N02-CORR
PROPENE
CO
HCHO
ACETALO
ACETONE
METHANE
OEG K.
4
KW
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT COND
I NIT CONU
INIT CCND
INIT COND
INIT COND
INIT COND
INIT CONO
INIT COND
302.7
55.24
17.44
0.361
2.274E
0.412
0.103
0.503
2.186
0.030
0.002
0.002
0.920
04
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: WAVELENGTH!NM)
500.
430.
403.
380.
370.
360.
350,
340.
330.
320.
310.
300.
290.
280.
Kl-0.43 MIN-l
SAMPLING RATE « 1.830 L/MIN
68 GC SAMPLES TAKEN
REL.
INTENSITY
1.589
.638
.532
.350
.228
.087
.000
.823
0.609
0.349
0.137
0.023
0.000
0.0
-------
NO
EC -216
PROPENE
1977 FEB 14
CLOCK
TIME
9*5
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1313
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
170J
1715
1730
1745
1800
ELAPSED
TCMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
OZONE
PPM
0.0
0.0
0.0
0.007
0.015
0.032
0.056
0.085
0.115
0.159
0.186
0.217
0.249
0.286
0.308
0.337
******
0.381
******
0.427
0.452
0.476
0.493
0.508
0.523
0.535
0.545
0.550
0.557
0.559
0.562
0.564
0.562
0.559
NO
PPM
0.412
0.338
0.266
C. 194
0. 136
O.C93
0.062
0.042
0.031
0.027
0.023
0.018
0.015
0.012
0.011
O.OC7
0.009
C.007
0.007
C.007
0.004
0.006
0.004
0.-005
0.005
0.005
0.004
0.006
0.004
0.006
0.006
C.004
0.005
0.005
N02-CORR
PPM
0.103
0.173
0.231
0.266
0.326
0.351
0.365
0.367
0.351
0.334
0.311
0.292
0.273
0.25U
0.228
0.204
0.176
0.158
0.137
0.112
0.086
3.079
0.071
0.055
0.039
0.036
0.034
0.030
0.032
0.022
0.019
0.012
0.012
0.011
NOX-CORR
PPM
0.51S
0.504
0.498
0.481
0.465
0.442
0.426
0.407
0.384
0.357
0.333
0.311
0.286
0.261
0.239
0.211
0.183
0.164
0.144
0.118
0.091
0.085
0.076
0.057
0.044
0.039
0.031
0.031
0.034
0.026
0.023
0.018
0.016
0.013
PROPENE
PPM
0.503
0.460
0.392
0.370
0.339
0.3C6
0.273
0.252
0.216
0.195
0.159
0.142
0.123
0.098
0.084
0.068
0.054
0.045
0.036
0.029
0.023
0.01?
0.014
0.010
0.008
0.006
0.004
0.003
0.003
0.002
0.002
0.001
0.001
******
-------
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1115
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1615
1700
1715
1730
1715
1800
ELAPSED
TCMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
133.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
CO
PPM
2.19
2.02
2.26
2.14
2.47
2.21
2.22
2.27
2.24
2.32
2.36
2.49
2.40
2.41
2.46
2.45
2.89
2.59
2.64
2.61
2.60
2.60
2.66
2.86
2.75
2.83
2.86
2.98
2.85
2.84
2.89
2.88
2.79
2.89
THC
PPMC
2.18
2.08
2.02
1.96
1.86
l.fil
1.78
1.74
1.66
1.60
1.59
1.62
1.51
1.53
1.49
1.46
1.51
1.47
1.49
1.45
1.47
1.46
1.45
1.44
1.46
1.43
1.50
1.47
1.49
1.47
1.48
1.48
1.49
1.53
PAN
PPM
0.000
******
0.001
******
0.006
******
0.016
******
0.026
******
0.043
******
0.057
******
0.069
******
0.090
******
0.102
******
0.129
******
0.131
******
0.146
******
0.151
******
0.145
******
0.154
******
0.154
******
HCHO
PPM
0.030
******
******
******
0.062
******
******
******
0.142
******
******
******
0.173
******
******
******
0.177
******
******
******
0.181
******
******
******
0.160
******
******
******
0.133
******
******
******
0.148
******
ACETALD
PPM
0.002
******
0.060
******
0.102
******
0.147
******
0.15B
******
0.202
******
0.183
******
0.174
******
0.177
******
0.161
******
0.141
******
0.134
******
0.113
******
0.109
******
0.105
******
0.080
******
0.077
******
PROPALO
PPM
0.0002
******
0.0005
******
0.0010
******
o.ooia
******
0.0023
******
0.0031
******
0.0033
******
0.0033
******
0.0037
******
0.0042
******
0.0035
******
0.0036
******
0.0037
******
0.0041
******
0.0042
******
0.0038
******
0.0039
******
ACETONE
PPM
0.0016
******
0. 01)30
******
0.0046
******
0.0069
******
0.0108
******
0.0117
******
0.0143
******
0.0168
******
0.0142
******
0.0135
******
o.uiaa
******
0.0146
******
0.0194
******
0.0211
******
0.0181
******
0.0228
******
0.01S1
******
BUTYRAL
PPM
0.000 1
******
0.0001
******
0.0002
******
0.0003
******
0.0005
******
0.0007
******
O.OQ10
******
0.0011
******
0.0013
******
0.0016
******
0.0016
******
0.0017
******
0.0019
******
0.0022
******
0.0021
******
0.0021
******
0.0020
******
MEK
PPM
0.0001
******
0.0001
******
0.0001
******
0.0001
******
O.UU01
******
******
******
O.OOU2
******
0.1*003
******
0.0003
******
0.0003
******
0.0004
******
0.0004
******
0.0004
******
0.0005
******
0.0004
******
O.OOOo
******
0.0004
******
PROA
PPM
******
******
******
******
******
******
0.0006
******
0.0010
******
0.0016
******
0.0020
******
0.0021
******
0. J123
******
0.0020
******
0.0025
******
0.0021
******
0.0021
******
0. OU27
******
O.OOc.4
******
0.0031
******
0.0023
******
ME-N
PPM
0.0
******
0.0
******
0.0
******
0.0001
******
O.OU05
******
0.0007
******
0.0008
******
0.0011
******
0.0011
******
0.0011
******
0.0012
******
0.0013
******
0.0012
******
0.0013
******
0.0013
******
0.0014
******
******
******
METHANE
PPM
0.92
0.93
1.09
0.97
0.99
0.93
1.22
1.01
1.03
0.92
0.93
1.13
0.91
l.Oc
1.00
1.12
0.65
1.05
1.00
0.93
0.93
1.03
1.10
1.17
0.98
1.02
1.01
1.07
1.25
1.10
1. 11
1.00
1.05
1.09
-------
10
Ul
Ol
EC -216
PROPENE
1977 FEB 14
CLOCK
TIME
9*5
1000
1015
1030
10*5
1100
1115
1130
1145
1200
1215
1220
12*5
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
1800
ELAPSED
UMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
TS
DEC F
83.5
85.5
85.2
85.5
85.7
86.0
85.7
85.7
65.2
85.5
85.7
85.7
85.5
85.5
84.5
84.8
85.2
64.8
85.2
85.2
85.5
85.7
85.2
85.5
85.5
86.2
86.0
86.5
86.5
86.0
86.0
85.7
85.5
85.0
REL HUM
*
43.5
45.0
48.0
52.0
56.0
58.5
59.5
60.0
60.0
60.5
60.5
60.5
60.5
60.5
60.0
60.0
60.5
60.0
60.0
60.0
60.0
60.5
60.5
60.5
60.5
60.0
60.0
60.0
59.5
59.5
59.5
60.0
60.0
60.5
SSPOMER
KM
17.47
17.51
17.60
******
17.56
******
******
******
17.55
******
******
******
17.22
******
******
******
17.34
******
******
******
17.43
******
******
******
17.51
******
******
******
17.43
******
******
******
17.22
******
RA010M
HW/CM2
******
0.364
0.362
0.362
0.359
******
******
******
0.364
******
******
******
0.357
******
******
******
0.366
******
******
******
0.369
******
******
******
0.366
******
******
******
0.366
******
0.359
******
0.352
0.354
HCHQ VOL
L
15.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
30.00
******
******
******
20.00
******
******
******
30.00
******
-------
Ul
EC -217
PROPENE * ACETALDEHYDE
1977 FEB 15
BEGIN IRRADIATION 0930; C.25 INCH PYREX FILTER
HCHO SAMPLE AT 0745 GAVE 0.00 ABSOR3ANCE
BRADY 1663 £ 1193
CO FACTOR 1.8/0.34; CH4 1.120/0.955; THC 1.120/2.41
T*0 AT 930 PST
CALIB*
REL HUM
REL HUM
HCHO
TS
REL HUM
REL HUM
SSPGrfER
RAD10M
H20
NO
N02-CORR
PROPENE
ACETALD
CO
HCHO
ACETONE
8UTYRAL
METHANE
DEC K
X
Z
KM
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
2
5
1
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CQNO
INIT CONO
INIT CCNO
INIT CCNO
INIT CCNO
INIT CONO
INIT CONO
INIT COND
INIT CONO
303.3
51.51
51.51
17.60
0.362
2.179E 04
0.241
0.238
0.099
0.146
1.759
0.003
0.004
0.001
1.120
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: hAVELENGTHlNMJ
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
M-0.43 MIN-l
SAMPLING RATE » X.6C8 L/MIN
77 GC SAMPLES TAKEN
REL i
INTENSITY
1.584
1.628
1.536
1.338
1.228
1.091
1.000
0.832
0.607
0.345
0.137
0.023
0.000
0.0
-------
EC -217
PROPENE » ACETALDEHVDE
1977 FEB 15
S3
CLOCK
TIME
930
945
1000
1015
1030
1045
1100
1115
1130
11*5
1200
1315
1230
12*5
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
1800
1815
1630
1845
1900
1915
1930
1945
2000
2015
2030
2045
2100
2115
2130
ELAPSED
T(HIN)
0.
15.
30.
45.
60.
75.
90.
105.
tzo.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
2d5.
300.
315.
. 330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
510.
525.
540.
555.
570.
585.
600.
615.
630.
645.
660.
675.
690.
705.
720.
OZCNE
PPM
0.0
0.002
0.007
0.005
0.007
0.007
0.007
0.007
0.012
0.012
0.017
0.022
0.022
0.020
0.022
0.022
******
0.029
0.037
0.042
0.044
0.051
0.054
0.054
0.059
0.059
0.068
0.066
0.076
0.078
0.081
0.090
0.088
0.095
******
0.100
0.098
0.107
0.107
0.112
0.120
0.122
0.122
0.129
0.137
0.134
0.144
0.144
0.149
NO
PPM
0.241
0.227
0.209
C.197
0.182
0.167
0.155
0.145
0.136
0.128
c.na
0.114
C. ICO
0.09S
0.089
0.083
0.071
C.066
0.067
0.056
0.061
0.050
0.049
0.050
0.045
0.043
0.044
0.033
0.038
0.029
0.034
0.031
0.026
0.028
0.026
0.022
0.022
0.023
0.018
0.016
0.016
0.015
0.012
0.015
0.015
0.011
0.015
0.011
0.009
N02-CORR
PPM
0.238
0.233
0.236
0.243
0.24S
0.256
0.263
0.262
0.263
0.266
0.269
0.265
0.272
0.265
0.268
0.263
0.271
0.267
0.257
0.263
0.253
0.255
0.247
0.242
0.238
0.235
0.227
0.231
0.221
0.222
0.213
0.208
0.209
0.198
0.190
0.188
0.184
0.179
0.171
0.170
0.165
0.160
0.157
0.150
0.144
0.140
0.137
0.133
0.127
NOX-CORR
PPM
0.478
0.460
0.450
0.438
0.431
0.425
0.418
0.407
0.399
0.394
0.388
0.378
0.371
0.362
0.355
0.346
0.340
0.333
0.322
0.318
0.311
0.304
0.296
0.289
0.283
0.276
0.271
0.265
0.257
0.250
0.243
0.237
0.233
0.225
0.217
0.213
0.205
0.200
0.191
0.184
O.ltil
0.175
0.170
0.164
0.158
0.151
0.150
0.144
0.135
PROPENE
PPM
0.099
******
0.077
******
0.065
******
0.059
******
0.048
******
0.042
******
0.035
******
0.030
******
0.025
******
0.021
******
0.018
******
0.015
******
0.013
******
0.011
******
0.009
******
0.008
******
0.006
******
0.005
******
0.004
******
0.003
******
0.003
******
0.002
******
0.002
******
0.001
******
0.001
ACETALO
PPM
0.146
******
0.149
******
0.151
******
0.135
******
0.151
******
0.143
******
0.141
******
0.133
******
0.128
******
0.126
******
0.116
******
0.108
******
0.106
******
0.104
******
0.095
******
0.090
******
0.084
******
0.078
******
0.076
******
0.070
******
0.068
******
0.062
******
0.060
******
0.056
******
0.053
-------
EC -217
PROPENE » ACETALDEHVDE
1977 FEB 15
CLOCK
TIME
930
9*5
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
12JO
1245
1300
1315
1330
1345
K> 1400
oS l415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
leoo
1815
1830
1845
1900
1915
1930
1945
2000
2015
2030
2045
2100
2115
2130
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
460.
495.
510.
525.
540.
555.
570.
585.
600.
615.
630.
645.
660.
675.
690.
705.
7ZO.
CO
PPM
1.76
1.66
1.66
1.71
1.84
1.68
1.82
1.73
1.85
1.76
1.94
1.76
1.82
2.09
1.77
1.93
1.88
1.73
1.97
2.02
1.69
2.04
2.13
******
1.94
1.97
2.08
1.90
2.20
1.98
2.12
2.02
1.94
2.04
2.13
2.13
2.20
2.19
2.39
2.13
2.15
2.11
2.26
2.20
2.38
2.34
2.30
2.41
2.38
THC
PPMC
1.18
1.24
1.17
1.24
1.21
1.19
1.19
1.14
1.15
1.13
1.14
l.ll
1.15
1.12
1.10
1.15
1.08
1.17
1.10
1.11
1.11
1.08
1.08
1.53
l.ll
1.08
1.14
1.09
1.13
1.11
1.11
1.12
1.09
1.08
1.11
1.08
1.07
1.10
1.08
1.07
1.13
1.09
1.11
1.04
1.04
i.oa
1.C9
1.04
1.05
PAN
PPM
0.0
******
O.C03
******
0.005
******
0.006
******
O.CC7
******
0.008
******
0.009
******
0.010
******
0.010
******
0.011
******
0.011
******
0.012
******
0.014
******
0.014
******
0.015
******
0.016
******
0.015
******
0.017
******
0.017
******
0.017
******
O.Old
******
******
******
******
******
******
******
o.ois
HCHO
PPM
0.003
******
******
******
0.016
******
******
******
0.027
******
******
******
0.024
******
******
******
0.040
******
******
******
0.027
******
******
******
0.027
******
******
******
0.027
******
******
******
0.032
******
******
******
0.030
******
******
******
0.040
******
******
******
0.027
******
******
******
0.027
PRGPALO
PPM
******
******
0.0005
******
0.0007
******
0.0008
******
0.0010
******
0.0014
******
0.0013
******
0.0016
******
0.0014
******
0.0018
******
0.0017
******
0.0019
******
0.0021
******
0.0020
******
0.0021
******
0.0023
******
0.0023
******
0.0022
******
0.0026
******
0.0026
******
0.0027
******
0.0029
******
0.0029
******
0.0030
******
0.0034
ACETONE
PPM
0.0044
******
0.0074
******
0.0090
******
0.0136
******
0.0140
******
0.0138
******
0.0110
******
0.0145
******
0.0165
******
0.0201
******
0.0201
******
0.0178
******
0.0205
******
0.0180
******
0.0228
******
0.0205
******
0.0253
******
0.0191
******
0.0257
******
0.0289
******
0.0261
******
0.0337
******
0.0243
******
0.0266
******
0.0403
BUTYRAL
PPM
0.0008
******
0.0009
******
0.0005
******
0.0004
******
O.U006
******
0.0005
******
0.0005
******
0.0006
******
0.0005
******
0.0006
******
0.0005 '
******
0.0001
******
0.0007
******
0.0007
******
0.0008
******
0.0007
******
0.0009
******
0.0007
******
0.0009
******
0.0011
******
0.0010
******
0.0011
******
0.0009
******
O.0009
******
0.0013
MEK
PPM
0.0
******
0.0
******
O.I)
******
0.0001
******
0.0
******
0.0001
******
0.0
******
0.0
******
0.0
******
u.o
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
PROX
PPM
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0007
******
0.0010
******
0.0008
******
0.0007
******
O.OOOd
******
0.0007
******
0.0009
******
******
******
0.0007
******
******
******
0.0008
******
0.0008
******
O.O01O
ME-N
PPM
0.0
******
0.0
******
0.0
******
0.0003
******
G.OOU4
******
O.OJU5
******
0.0006
******
******
******
0.0007
******
0.0008
******
0.0008
******
0.0008
******
0.0009
******
0.0010
******
0. 01)11
******
0.0011
******
0.0011
******
0.0012
******
0.0013
******
0.0013
******
0.0013
******
******
******
******
******
******
******
O.0014
METHANE
PHM
1.12
1.09
0.98
1.08
1.03
1.02
1.01
1.13
0.97
1.12
1.06
1.02
1.02
0.95
1.09
1.06
0.99
1.01
1.01
0.97
0.98
0.98
1.05
0.31
1.18
0.06
1.13
1.08
1.07
1.00
1.15
1.02
0.99
1.03
1.08
1.03
0.96
1.13
0.95
0.99
1.16
1.00
1.08
0.94
1.03
1.00
1.08
0.97
0.95
-------
EC -217
PROPENE * ACETALDEHYDE
1977 FEB 15
Ui
VD
CLOCK
TIME
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
1800
1815
1830
1345
1900
1915
1930
1945
2000
2015
2030
2045
2100
2115
2130
ELAPSED
T(MIN»
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
510.
525.
540.
555.
570.
585.
600.
615.
630.
645.
660.
675.
690.
705.
720.
TS
DEC F
84.5
85.7
86.0
86.0
85.7
85.7
86.0
86.0
86.2
86.5
86.5
87.0
86.2
86.2
86.2
86.2
86.2
86.2
86.2
86.5
86.5
87.0
86.5
87.2
87.4
87.0
86.5
86.5
86.2
86.5
87.2
86.5
87.0
86.0
86.2
86.7
86.5
86.5
86.5
86.2
86.7
86.0
66.2
86.0
86.2
86.5
86.5
86.5
86.0
REL HUM
%
» 1663
50.0
50.0
50.0
51.0
51.0
51.0
51.0
52.0
52.0
52.0
52.0
52.0
52.0
52.0
52.0
52.0
52.0
52.0
52.0
51.0
52.0
51.0
51.0
52.0
51.0
52.0
52.0
52.0
52.0
52.0
51.0
52.0
52.0
51.0
51.0
51.0
51.0
52.0
52.0
51.0
52.0
51.0
52.0
52.0
52.0
51.0
52.0
51.0
51.0
REL HUH
X
* 1193
41.0
45.0
46.0
46.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
SSPOWER
KM
17.56
******
17.56
******
17.64
******
******
******
17.60
******
******
******
17.64
******
******
******
17.39
******
******
******
17.43
******
******
******
17.89
******
******
******
17.51
******
18.06
17.17
18.06
17.64
******
******
18.02
17.39
******
******
17.93
17.30
******
17.22
17.22
17. 72
******
******
17.60
RADIDM
MW/CM2
******
0.364
0.359
0.364
0.364
******
******
******
0.364
******
******
******
0.366
******
******
******
0.357
0.354
******
******
0.364
******
******
******
0.369
0.366
******
******
0.369
******
******
0.354
0.371
0.357
0.366
******
0.366
0.352
0.357
******
0.371
0.362
0.359
0.354
0.366
0.362
******
0.359
0.357
HCHO VOL
L
15.00
******
******
******
15.00
******
******
******
15.00
******
******
******
15.00
******
******
******
15.00
******
******
******
15.00
******
******
******
15.00
******
******
******
15.00
******
******
******
15.00
******
******
******
15.00
******
******
******
15.00
******
******
******
15.00
******
******
******
15.00
-------
N>
O>
O
EC -230
PROPcNE
1977 AUG 9
IhRAOIATICN 0945i C.2b INCH PtKEX FILTER
UiuJJfc rtuNlTORED BV BOTH CASIdl 1212 IC-1212J ANO OASIDI 1070 10-1070)
bRAUY 1663 (1977 AUG 2o CALloJi TECO 14b; BECKMAN 6800
co FACTOR 1.6/3.25
T«0 AT 945 POT
PAN
HCHQ
REL INT
TS OEG K
KEL HUM *
SSPJnER KM
RAOIOM MH/CH2
H20 PPM
NO PPM
C.02-CCRR PPM
PKOPENE PPM
CO PPM
HCHO PPM
ACETALD PPM
ACtTONE PPM
» ASSIGNED
CALIB*
9
I
4
AVERAGE
AVERAGE
AVEMAOc
AVERAGE
AVERAGE
IN IT CCNO
INIT CCNO
INtT CCM)
INIT CCNO
INIT CCNO
INIT CCNO
INIT CCNO
INITIAL CCNCITIGM
302. B
51. 2i
16. Id
C.229
i.lC^c 04
0.392
0.128
C.^46
1.943
C.2S2
0.002
C.002
SPECTRAL DISTRIBUTION: I
-------
K3
tc -230
PRJP6NE
1977 AUG 9
CLOCK
TIME
945
1000
1015
1030
10*5
1100
1115
1130
1145
UOO
1215
1230
1243
1300
131S
1JJO
1343
1400
1413
1430
1445
1500
1515
1530
1545
1600
1615
16JO
1645
ELAPSED
TIMINI
0.
15.
30.
43.
60.
75.
90.
105.
110.
135.
150.
165.
Ibu.
1*3.
210.
225.
240.
255.
270.
2d5.
300.
315.
J^O.
345.
360.
375.
390.
405.
420.
CuONE
PPM
0-1212
0.0
0.0
0.0
0.0
0.0
O.U02
0.010
0.022
0.037
0.051
0.071
0.093
0.112
0. 132
0. 1-.9
0.171
O.lfi6
J.21.5
0.220
0.234
0.252
0.261
0.274
0.286
0.298
0.313
0.325
0.335
0.342
ClONE
PPM
C-1070
C.O
0.0
0.0
0.0
C.005
C.010
C.ulO
C.022
C.049
Ll.Oio
0.083
I*. 103
C.125
C.137
C.159
0.176
C.193
C.210
C.225
C.247
C.254
C.2o6
0.2d6
0.2b6
0.305
C.315
C.327
C.337
C.344
NO
PPM
0.342
0.34J
C.jCO
C.251*
C.20V
0.162
O.U3
C.OS5
0.073
O.Ubl
0.049
C.03B
O.OJ2
C.k2o
0.024
0.022
0.018
0.017
0.016
0.015
C.013
0.012
C.L12
O.C12
0.011
0.011
0.010
C.C1C
C.010
N02-CORS
|>PM
0.12d
0.167
0.207
0.244
0.2B2
0.31d
0.342
0.351
0.364
0.360
0.354
0.349
0.340
0. J2o
0.310
0.292
0.277
0.260
0.239
0.225
0.208
0. ISl
0.173
C.157
0.141
0.12B
0.114
0.101
O.OdV
MOX-CUf R
PPM
0.520
0.514
0.507
0.5C3
U.4S2
0.479
0.467
0.446
0.435
O.t20
0.401
J.3d5
0.371
0.353
0.333
0.312
0.294
0.275
0.255
0.237
0.219
0.202
0.185
0.168
0.150
0.138
0.122
0.109
0.097
PROPENE
PPM
0.546
0.522
*«*««*
0.436
0.421
0.391
0.351
0.333
0.3C9
0.279
0.252
0.230
0.204
o.iai
0.162
0.143
0.123
0.109
0.094
0.060
0.071
0.061
0.051
0.044
0.037
U.031
0.027
0.022
0.016
-------
fcC -230
PHJPtNE
1977 AUG 9
CLOCiv
TIME
V45
loOO
1015
1030
10t5
1100
1113
1130
1145
1200
Ul3
123J
12tS
13JJ
Lily
1330
iJ45
1400
141 5
It30
1445
1500
1515
1530
1545
loOO
1613
1630
1645
ELAPSED
T1MIN)
0.
15.
30.
45.
oO.
75.
90.
105.
120.
133.
150.
Io5.
ISO.
195.
210.
225.
240.
255.
270.
2o5.
300.
315.
33v>.
345.
360.
375.
390.
405.
420.
CO
PPM
1.94
******
1.94
******
1.97
******
1.9B
******
2.03
******
2.03
******
2.C9
******
2.14
******
2.20
******
2.17
******
2.25
******
2.31
******
2.34
******
2.37
******
2.41
PAN
PPM
C.OOJ
******
O.uOl
******
0 .003
******
O.G07
****¥*
0.013
******
O.Oil
4**v *»
O.Oji
******
0.042
******
C.052
******
G.064
******
0.072
******
C.uol
******
C.095
******
C.103
******
C.110
HCHO
PPM
0.262
******
******
******
0.123
******
******
***«.**
0.171
******
******
******
0.240
******
* *** ««
******
C.i2d
******
***< **
******
0.2co
«***.**
******
******
0.252
******
******
******
0.232
ACcTALD
PPM
u.002
******
0.048
******
u.09t)
******
0.13S
******
o. 1 7a
******
0.1W
******
0.22o
******
0.23J
******
0.2oO
******
0.230
******
0.223
******
0.217
******
0.206
******
0.195
******
0.172
PKOPALD
PPM
o.oool
******
0.0004
******
C.0009
******
0.0013
******
0.0018
******
0.0022
******
0.0029
******
0.0034
******
0.0036
******
0.0040
******
O.OJ30
******
0.0035
******
0.0040
******
0.0040
******
0.0036
ACETONE
PPM
0.0015
******
0.0022
******
0.0031
******
0.00t2
******
0.0071
******
O.OOod
******
0.01.55
******
0.0130
******
0.01B4
******
0.0193
******
0.0195
******
0.0150
******
0.0216
******
0.0208
******
0.01o4
atmRAL
PPM
o.oool
******
0.0001
******
0.0001
******
0.0002
******
0.0003
*******
O.OOJ4
******
u.0006
******
O.OuJ7
******
0.0010
******
******
******
0.0011
******
0.0012
******
0.0014
******
O.U015
******
0.0014
M£K
PPM
0.0001
******
0.0001
******
0.0002
******
O.OuOl
******
******
******
******
******
0.0002
******
******
******
******
******
******
******
• ******
******
******
******
******
******
******
******
******
|>RUX
PPM
0.0
******
O.OJuZ
******
0.0003
******
0.0011
******
0.0013
******
O.Ool •
******
0.0023
******
O.JU23
******
0.0029
******
0.0032
******
0. vvil
******
0.0027
******
0.0031
******
0.0026
******
0.0027
Mc-N
PPM
0.0
******
0.0
******
0.0
******
U.OOU2
******
0.0002
*** ***
O.OOU2
**** **
0.0004
******
u.0uo7
******
U. U Juti
******
U.OOU'J
******
u. 0009
******
0.0011
******
0.0011
******
0.0013
******
u.uOlS
-------
EC -230
PRUPtNE
1977 AUG 9
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
UJO
1215
U3C
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1345
1600
1615
1630
1045
tLAPStO
T(HIN)
0.
15.
30.
45.
60.
75.
90.
105.
ItO.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
2b5.
JOO.
315.
330.
345.
360.
375.
390.
405.
420.
IS
CEG F
84.8
05.5
85.5
85.7
84. C
64.3
85.0
85.2
85.5
66.2
65.0
65.0
b5.2
85.7
b4.5
b5.2
8o.O
36.5
85.2
85.5
85.7
84.0
04. a
b5.2
85.5
66.2
87.0
85.5
85.5
REL HUM
*
47.0
47.5
49.0
49.5
50.5
52.0
53.0
53.0
5c.5
52.0
52.0
52.5
53.0
52.5
52.5
53.0
53.0
52.5
52.5
53.0
52.5
53.5
53.5
53.5
53.0
52.5
51.5
51.0
52.0
SSPUrftR
Kk
15.88
16. Od
16. CO
15. S9
15.99
16.42
**vs»v
******
1 0 . 1 -i
******
******
******
15.99
16.39
******
******
16. S3
16.20
******
******
16. C7
******
******
**»*»*
16.20
******
******
******
16,20
RACIOM
M«/CH2
0.225
0.232
0.230
0.225
0.227
C.230
******
******
0.227
******
******
******
0.222
0.232
******
******
0.239
0.232
0.227
******
0.22i
******
******
******
******
0.227
******
******
******
HCHO VOL
L
10.00
******
******
******
2C.OO
******
******
******
20.00
******
******
******
20. CO
******
******
******
-------
=C -231
7-HYDROCARbGN MIX *4
1977 AUG 10
BEOIN IRRADIATION 1030; 0.25 INCH PYfcEX FILTER
PEAKS ATRRIBUTED TO C&-N-D OBSSRVED ON PANALYZER. DATA NOT QUANTIFIABLE.
C3-N-2 INCLUDES SMALL AMCUNTS OF C2-N
NZ ACCIDENTLY FLUSHED INTO CHAMBER AT 4 L/MIN THROUGHOUT RUN
QiONE MONITORED BY BOTH DASIiJl 1212 (0-1212) AND OASI3I 1070 (0-10701
6*ADY 1663 (1977 AUG 26 CALIBJ; TECU 148; 8ECKM4N 6800
CO FACTOR 1.6/0.335
T=0 AT 1030 POT
HCHO
PAN
REL INT
CALIB*
1
9
4
TS 06G K
REL HUM %
SSP'.lnEfl KW
RAOIOM MW/CM2
H20
NU
N02-CORR
ETHCNE
PROPENE
N-C4
T2-C4=
2,3-DMB
TCLJENE
h-XYL
cr
HCHO
ACETONE
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT
INIT
INIT
INIT
INIT
INIT
INIT
INIT
INIT
INIT
INIT
INIT
CCND
CCND
CCND
COND
COND
CONO
CCND
CCNO
COND
CCND
COND
CCND
302.8
A3.33
16.24
0.229
1.621E
0.440
0.052
1.051
0.1U8
1. 130
0.055
0.715
0.121
0.108
1.630
0.020
0.001
ASSIGNED INITIAL CONDITION
-------
EC -231
7-HYORQCARBON MIX *4
1977 AUG 10
SPECTRAL DISTRIBUTION: hAVELENGTHlNH) REL. INTENSITY
500. 2.1^2
430. 1.911
403. l.72i
380. 1.421
370. 1.202
360. 1.132
350. 1.000
340. 0.789
330. 0.571
320. 0.314
310. 0.126
300. 0.023
290. 0.001
280. 0.0
Kl=0.33 HIN-1
SAMPLING RATE * 4.000 L/HIN
^ 54 GC SAMPLES TAKEN
O\
Cn
-------
EC -231
7-HYOROCAR80N MIX #4
1977 AUG 10
to
OS
CLOCK
TIMF
1030
10*5
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
ELAPSED
TIMIN>
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
OZONE
PPM
D-1212
0.000
0.000
0.000
0.002
0.032
0.117
0.205
0.291
0.362
0.427
0.493
0.525
0.562
0.591
0.60S
0.620
O.o23
0.616
0.613
0.603
0.589
0.579
0.564
0.552
0.540
OZONE
PPM
D-1C70
0.0
0.0
0.0
0.007
0.039
0.120
C.215
0.296
C. 371
0.432
0.469
0.528
0.567
0.591
0.611
C.620
0.620
0.618
0.611
0.601
0.589
0.576
0.562
0.550
0.537
NO
PP*
0.440
0.377
0.291
0.132
0.073
0.035
0.021
0.021
0.012
0.011
0.010
0.009
0.007
0.007
0.007
0.012
0.013
0.011
0.005
0.006
O.C36
0.011
O.OC6
0.005
O.OJ6
N02-CORR
PPM
0.052
0.103
0.180
0.272
0.360
0.365
0.344
0.307
0.275
0.244
0.211
0.1 79
0.150
0.124
0.101
G.0d6
0.071
0.057
0.053
0.050
0.345
0.037
0.045
0.039
0.039
NUA-CORR
PPM
0.492
0.483
0.472
0.453
0.433
0.400
0.364
0.325
0.286
0.252
0.218
0.185
0.158
0.130
0.107
0.098
0.083
0.067
0.060
0.055
0.048
0.04S
0.048
0.044
0.042
ETHENE
PPM
1.051
******
0.987
******
0.922
******
0.831
******
0.757
******
0.676
******
0.610
******
0.542
******
0.492
******
0.450
******
0.415
******
0.378
******
0.348
PROPENE
PPM
0. 108
******
0.097
******
0.081
******
0.060
******
0.042
******
0.027
******
0.017
******
0.011
******
0.007
******
******
******
0.003
******
0.002
******
0.001
N-C4
PPM
1.130
******
1.083
******
1.051
******
0.991
******
0.963
******
0.924
******
0.884
******
0.856
******
0.824
******
0.805
******
0.775
******
0.756
******
0.734
T2-C4=
PPM
0.055
******
0.042
******
0.022
******
0.003
******
0.0
******
0.0
******
0.0
******
O'vO
******
0.0
******
0.0
******
u.o
******
0.0
******
0.0
2i3-0«S
PPM
0.715
******
3.667
******
0.644
******
0.598
******
0.565
******
0.531
******
0.500
******
0.475
******
0.453
******
0.432
******
0.415
******
0.4U1
******
0.384
TOLUENE
PPM
0.121
******
0.115
******
0.109
******
0.099
******
0.096
******
0.091
******
0.086
******
0.0ti2
******
0.077
******
0.075
******
0.071
******
0.069
******
0.067
M-XYL
PPM
0.108
******
0.097
******
0.084
******
0.069
******
0.058
******
0.050
******
0.043
******
0.036
******
0.033
******
0.031
*****4r
0.028
******
0.026
******
0.024
-------
EC -231
7-HVOROCARBON MIX
1977 AUG 10
ON
CLCCK
TIKE
1030
10*5
1100
1115
1133
1145
1200
1215
1230
1245
1300
1315
1330
13*5
1400
1415
1430
144S
1500
1515
1530
15-.5
1600
1615
1639
ELAPSED
TIMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
130.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
3oO.
CD
PPM
1.63
******
1.61
******
1.61
******
1.63
******
1.65
******
1.71
******
1.76
******
1.78
******
1.84
******
1.36
******
1.89
******
1.90
******
1.93
PAN
PPM
0.000
******
0.001
******
0.006
******
0.023
******
0.039
******
0.047
******
0.062
******
0.079
******
o.osa
******
0.092
******
0.095
******
0.094
******
0.092
HCHQ
PPM
0.020
******
******
******
0.077
******
******
******
0.296
******
******
******
0.371
******
******
******
0.4Z3
******
******
******
0.453
******
******
******
0.381
ACETALD
PPM
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.029
******
******
******
0. 166
******
******
******
0.141
PrtGPALO
PPM
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0044
******
******
******
0.0092
******
******
******
0.0385
ACETONE
PPM
0.001
******
0.012
******
0.045
******
0.053
******
0.110
******
0.142
******
0.142
******
0.176
******
o.iao
******
0.179
******
0.174
******
0.175
******
******
MEK
PPM
******
******
0.0035
******
0.0102
******
0.0089
******
0.0225
*******
0.0283
******
0.0251
******
0.0364
******
0.0361
******
0.0385
******
0.0357
******
0.0399
*v****
0.0419
C3-N-2
PPM
C*600
0.0
******
0.0003
******
0.0010
******
0.0021
******
0.0023
******
0.0033
******
0.0036
******
0.0040
******
0.0043
******
0.0040
******
0.0040
******
0.0040
******
0.0040
C3-N-2
PPM
PANALViR
******
******
0.0004
******
0.0010
******
0.0013
******
0.0023
******
O.JU30
******
0.0032
******
0.6034
******
0.0034
******
0.0038
******
0.0034
******
0.0034
******
0.0036
C4-N-2
PPH
PANALYZR
0.0
******
0.0005
******
0.0011
******
0.0016
******
0.0025
******
0.0036
******
0.0042
******
0.0045
******
0.0051
******
0.0051
******
0.0053
******
0.0054
******
0.0054
-------
EC -231
7-HYOROCARSON MIX «4
19T7 AUG 10
NJ
CLOCK
TIME
1030
1045
1100
1115
1130
1145
1200
1215
1230
12*5
1300
1315
1330
13-.5
1400
1415
1430
1445
1530
1515
153J
1545
1600
1615
162J
ELAPSEO
T(HIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEG F
86.5
84.3
34.3
85.0
85.2
86.0
86.5
87.0
87.2
64.3
84.3
35.0
85.5
86.0
87.0
87.4
84.0
84.0
84.5
85.2
65.5
86.2
85.5
83.5
83.8
REL HUM
*
44.5
44.5
46.5
47.0
46.5
46.0
45.5
44.5
43.5
43.5
44.0
44.0
43.5
42.5
41.5
41.0
40.5
41.0
40.5
40.0
39.5
38.5
38.0
38.0
38.0
SSPOK6R
KM
16. *t»
15.77
16.17
16.06
16.19
******
******
******
16.34
******
******
******
16.46
******
******
******
16. 19
******
******
******
16.39
******
******
******
16.39
RADICM
MM/CM2
******
0.239
0.237
0.225
0.220
0.225
******
0.232
0.227
******
******
******
0.225
******
******
******
0.230
******
******
0.230
0.227
******
******
******
0.232
HCHO VOL
L
30.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -2J2
7-HYDRQCAPBON MIX *1
1977 AUG 11
BEGIN IRRADIATION 1000; 0.25 INCH PYREX FILTER
PEAKS ATRRIBUTED TO C6-N-0 OBSERVED ON PANALfZER. DATA NOT QUANTIFIABLE.
C3-N-2 INCLUDES SMALL AMOUNTS OF C2-N
JZONE MONITORED BY BOTH OASIBI 1212 JO-1212) AND DASIBI 1070 40-1070)
BRADY 1663 I 1977 AUG 26 CALIBI; TECO 14B; BECKMAN 6800
FACTORS: co 1.6/0.339
T»0 AT 1000 POT
vo
CALIQ*
HCHO
PAN
RcL INT
TS
KEL HU*
SS POWER
RADIO*
H20
NO
N02-CCRR
ETHfcNE
PROPER
N-C*
T2-C*=
2.3-DM3
TOLUENE
H-XYL
CO
HCHO
ACETALD
AC ETON?
DEC K
%
KM
HH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
1
9
4
AVERAGE
AVERAGE
AVERAGE,
AVERAGE
AVERAGE
IMT CONO
IN IT COND
INIT COND
INIT CONO
INIT CCND
INIT CONO
INIT COND
INIT COND
INIT COND
INIT CCND
INIT CCNO
INIT CCND
INIT CCNO
302.5
16.53
0.230
1.B71E
0.469
0.024
0.258
0.051
1.102
0.026
0.612
0.032
0.029
1.742
0.009
0.002
0.001
ASSIGNED INITIAL CONDITION
-------
— I
O
EC -232
T-HYOROCARBON MIX #1
1977 AUG 11
SPECTRAL DISTRIBUTION: hAVELENGTHi NMJ RtL. INTENSITY
500. 2.208
430, 2.000
403. 1.819
380. 1.515
370. 1.3*9
360. 1.208
350. I. 000
340. 0.850
330. 3.623
320. 0.345
310. 0.140
300. 0.025
290. 0.000
230. 0.0
Kl»0.30 MIN-1
SAMPLING RATE » 2.264 L/MIN
59 GC SAMPLES TAKEN
-------
EC -232
7-HYDROCARBON MIX #1
1977 AUG 11
to
CLOCK
TIHE
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1345
130J
nib
1330
1343
1400
1415
1430
1445
1500
1515
1530
1545
1600
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
D-1212
0.0
0.0
0.0
0.0
0.0
0.0
0.005
0.012
0.022
0.037
0.049
0.068
0.093
0.110
0.127
0. 144
0.166
0.178
0.195
0.217
0.234
0.249
0.269
0.283
0.305
OZON6
PPM
0-1070
0.0
0.0
0.0
0.0
0.0
0.002
0.005
0.015
0.024
0.039
0.056
0.073
0.093
0.112
0. 129
0.147
0. 166
0. 183
0.198
0.217
0.234
0.254
0.271
0. 288
0.305
NO
PPrt
0.469
0.431
0.394
0.343
0.292
0.238
0.1 dd
0.151
0.115
0.090
0.066
0.053
0.051
0.040
0.035
0.031
0.02S
0.026
0.0?2
0.021
0.022
0.017
0.017
0.015
0.016
N02-CORR
PPM
0.024
0.05J
0.039
0.136
0.180
0.224
0.264
0.289
0.317
0.330
0.340
0.344
0.332
0.330
0.319
0.315
0.313
0.291
0.279
0.268
0.251
0.233
0.221
0.212
0.197
NOX-CORR
PPM
0.492
0.483
0.485
0.481
0.473
0.462
0.452
0.441
0.431
0.419
0.406
0.396
0.383
0.369
0.354
0.343
0.339
0.315
0.299
0.286
0.2/3
0.254
0.237
0.226
0.212
ETHENE
PPM
0.253
******
0.254
******
0.240
******
0.228
******
0.214
******
0.205
******
0.194
******
O.IB5
******
0.172
******
0.168
******
0.156
******
0.145
******
0.139
PROPENE
PPM
0.051
******
0.047
******
0.042
******
0.036
*„ »*#*
0...31
******
0.027
******
0.023
******
0.019
******
0.015
******
0.013
******
0.010
******
0.003
******
0.006
N-C4
PPM
1.102
******
1.087
******
1.070
******
1.040
******
1.012
******
1.002
******
0.976
******
0.948
******
0.901
******
******
******
0.884
******
0.871
******
0.842
T2-C4=
PPM
0.026
******
0.021
******
0.016
******
0.010
******
o.OOa
******
0.003
******
0.001
******
ihooo
******
u.o
******
0.0
******
0.0
******
0.0
******
0.0
2,3-DMB
PPM
0.612
******
0.592
******
0.576
******
0.551
******
0.529
******
0.514
******
0.493
******
0.476
******
0.458
******
0.446
******
0.430
******
0.415
******
0.401
TOLUENE
PPM
0.032
******
0.031
******
0.030
******
0.029
******
Q.u28
******
0.028
******
0.026
******
0.026
******
0.024
******
0.024
******
0.023
******
0.023
******
0.022
M-XVL
PPM
0.029
******
0.027
******
0.024
******
0.022
******
0.019
******
0.018
******
0.016
******
O.C14
******
0.013
******
0.012
******
o.ou
******
0.010
******
0.009
-------
EC -232
7-HYDROCARBON MIX 91
1977 AIJG 11
10
CLOCK
TIME
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
12*5
130U
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
mo.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
1.74
******
1.69
******
1.74
******
1.75
******
1.75
******
1.79
******
1.80
******
1.86
******
1.87
******
1,94
******
1.95
******
2.17
******
2.01
PAN
PPM
0.000
******
0.001
******
0.001
******
0.002
******
0.005
******
******
******
0.013
******
O.Old
******
0.322
******
0.027
******
0.032
******
0.033
******
C.040
HCHQ
PPM
O.C09
******
******
******
0.052
******
******
******
0.032
* *****
******
******
******
******
******
***v«*
0.110
******
******
******
0.157
******
******
******
0.136
ACETALD
PPM
3-PART
0.002
******
******
******
0.030
******
0.055
******
0.069
******
******
******
0.036
******
0. J85
******
******
******
0.094
******
0.102
******
0.100
******
0.095
PROPALO
PPM
3-PART
0.0
******
******
******
0.0015
******
0.0012
******
0.0016
******
******
******
0.0021
******
0.0023
******
******
******
0.0030
******
0.0035
******
0.0040
******
0,0052
ACETONE
PPM
0.001
******
0.013
******
0.018
******
******
******
0.053
******
0.069
******
0.072
******
0.113
******
0.090
******
0.142
******
0.126
******
0.153
******
0.161
MEK
PPM
0.0
******
0.0034
******
0.0056
******
3.0141
******
0.0135
******'
0.0205
******
0.3199
******
0.0295
******
0.0164
******
0.0374
******
0.0252
******
0.0417
******
0.0368
C3-N-2
PPM
C-600
0.0
******
0.0003
******
0.0005
******
0.0008
******
******
******
******
******
0.0018
******
0.0021
******
0.0025
******
0.0028
******
0.0030
******
0.0032
******
0.0033
C3-N-2
PPM
PANALYZR
0.0
******
0.0003
******
0.0007
******
0.0011
******
0.0016
******
0.0020
******
0.0023
#*«***
0.&025
******
0.0028
******
0.0029
******
0.0035
******
0.0035
******
0.0039
C4-N-2
PPM
PAMALYZR
0.0
******
O.J003
******
O.OOuS
******
0.0012
******
0.0022
****¥*
******
******
0.0030
******
0.0034
******
O.OJ38
******
0.0048
******
0.0051
******
0.0059
******
o.oa54
-------
EC -23Z
7-HYDRQCARBON MIX
1977 AUG 11
CLOCK
TIME
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
14JO
1415
1430
1445
1500
1515
1530
1545
1600
ELAPSED
T«MIN»
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEG F
82.6
85.2
65.7
86.0
85.7
65.5
86.0
86.0
85.5
85.5
66.0
85.5
85.7
86.2
85.0
85.5
84.8
85.2
84.8
85.2
85.2
85.0
85.5
84.8
85.2
REL HUM
*
49.5
50.5
51.5
52.0
52.0
53.0
54.0
54.0
54.0
54.5
54.5
54.5
55.0
54.5
55.0
55.5
55.5
55.5
55.5
56.0
55.5
56.0
56.0
56.0
56.0
SSPCrtER
KM
15.88
15.99
15.71
16.20
15.99
******
******
******
16.46
******
16.34
******
16.38
******
******
******
20.25
******
******
******
16.07
******
******
******
******
RADIOM
MH/CM2
******
0.230
0.225
0.227
0.227
******
******
******
0.239
0.227
0.23J
0.227
0.230
******
******
******
0.227
******
******
******
0.232
******
******
0.237
0.234
HCHO VDL
L
30.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
15.00
******
******
******
20.00
******
******
******
20.00
-------
N5
EC -233
7-HYOROCARBON MIX «2
1977 AUG 12
BEGIN IRRADIATION lOlai 0.25 INCH PYREX FILTER
PEAKS ATRRIBUTED TO C6-N-0 OBSERVED ON PANALYZER. DATA NOT QUANTIFIABLE.
C3-N-2 INCLUDES SMALL AMCUNTS OF C2-N
ACETALDtHYOE AND PROP1CNALOEHYDE MONITORED ON 3-PART COLUMN
OZONE MONITORED BY BOTH OASIBI 1212 (0-1212) AND OASIBI 1070 (0-1070)
BRAOY 1663 11977 AUG 26 CALIBIi TECO 148; BECKMAN 6800
FACTORS: CO 1.6/0.336
T«0 AT 1015 POT
CALIB*
HCHO
PAN
REL INT
TS
REL HUM
SSPO*ER
RADIOM
H20
N3
N02-CORR
cTHENE
PKOPcMt
N-C4
T2-C4*
2,3-DMB
TOLUENE
M-XYL
CO
HCHO
ACETALO
ACETONE
DEC K
t
Kd
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
1
9
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
I NIT CONO
irm CCNO
INIT CGNO
INIT CCND
IMT CONO
INIT CONO
INIT COND
INIT CCNO
INIT CONO
INIT CCND
INIT COND
INIT CGNO
INIT CCND
302.7
52.70
16.56
0.232
2.USE
0.096
0.007
0.260
0.051
1.035
0.025
0.648
0.034
0.033
1.299
0.004
0.001
0.001
04
ASSIGNED INITIAL CONDITION
-------
EC -333
7-HYDROCARdQN MIX «2
1977 AUG 12
SPECTRAL DISTRIBUTION: WAVELENGTH!NMI REL. INTENSITY
500. 2.096
430. 1.905
403. 1.716
380. 1.440
370. 1.316
360. 1.165
350. 1.000
340. 0.791
330. 0.564
320. 0.323
310. 0.127
300. 0.024
290. 0.000
280. 0.0
Kl=0.30 MIN-1
SAMPLING RATE « 2.267 L/MIN
t-o 42 GC SAMPLES TAKEN
-------
EC -233
7-HYDROCAR80N MIX #2
1977 AUG 12
CLOCK
TIME
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
140J
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
T(M1N)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0-1212
0.0
0.002
0.034
0.095
0.156
0.198
0.230
0.252
0.271
0.266
0.300
0.310
0.318
0.320
0.325
0.325
0.327
0.327
0.327
0.327
0.325
0.325
0.325
0.325
0.322
OZONE
PPM
D-1070
0.0
0.002
0.039
0.093
0.159
0.203
0.232
0.256
C.278
0.291
0.303
0.313
0.313
C.322
0.325
C. 327
0.330
0.327
0.327
C.330
C.327
0.325
0.325
0.325
0.325
NO
PPM
0.096
0.056
0.022
O.OU
0.011
0.009
O.C09
0.008
O.OOB
0.007
O.OC7
0.007
0.007
0.007
0.006
0.007
0.007
0.007
0.007
0.007
0.006
0.007
O.OOS
0.007
0.006
N02-CORR
PPM
0.007
0.043
0.074
0.0 7o
0.071
0.063
0.054
0.051
0.047
0.043
0.040
0.037
0.035
0.033
0.030
0.029
0.029
0.029
0.029
0.027
0.027
0.029
0.028
0.029
0.030
NOX-CORR
PPM
0.103
0.099
0.096
0.089
0.081
0.072
0.062
0.059
0.055
0.051
0.047
0.044
0.042
0.039
0.036
0.036
0.036
0.036
0.036
0.034
O.J34
0.035
0.036
0.035
0.036
ETHENE
PPM
0.260
******
0.242
******
0.225
******
0.194
******
0.201
******
0.189
******
0.177
******
0.166
******
0.158
******
0.152
******
0.142
******
0.136
******
0.129
PROPENE
PPM
0.051
******
0.044
******
0.035
******
0.027
******
0.020
******
0.016
******
0.012
******
0.010
******
0.007
******
0.006
******
0.005
******
0.004
******
0.003
N-C4
PPM
1.085
******
1.062
******
1.032
******
1.008
******
0.973
******
******
******
0.931
******
0.913
******
0.899
******
0.830
******
0.687
******
0.864
******
0.849
T2-C4=
PPM
0.025
******
0.017
******
0.003
******
0.0
******
0.0
******
0.0
******
0.0
******
0"»0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
2,3-DMB
PPM
0.648
******
0.623
******
0.594
******
0.509
******
0.548
******
0.531
******
0.514
******
0.501
******
0.493
******
0.477
******
0.472
******
0.452
******
0.446
TOLUENE
PPM
0.034
******
0.033
******
0.031
******
0.030
******
0.029
******
0.026
******
0.026
******
0.027
******
O.U26
******
0.024
******
0.025
******
******
******
0.024
M-XYL
PPM
U.033
******
O.C31
******
0.02o
******
**** **
******
0.021
**** * *
0.019
******
0.018
******
0.016
******
0.016
******
0.014
****«..
o.oi.
******
0.013
******
0.012
-------
£C -233
7-HrDROCARBON MIX »2
1977 AUG 12
N3
CLOCK
TIME
1015
1030
1045
1100
1115
1130
1146
120J
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
15«0
1515
1530
1545
1600
1615
ELAPSED
T(MIM)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
1.30
******
1.31
******
1.13
******
1.37
******
1.36
******
1.39
******
1.45
******
1.52
******
1.56
******
1.57
******
1.55
******
1.62
******
1.55
PAN
PPM
******
******
0.001
******
0.006
******
o.oia
******
0.022
******
0.026
******
0.029
******
0.033
******
0.033
******
0.034
******
0.037
******
0.035
******
0.036
HCHO
PPM
0.104
******
******
******
0.0i9
******
******
******
0.105
******
******
******
0.121
******
******
******
0.125
******
******
******
0.145
******
******
******
0.145
ACETALO
PPM
3-PART
0.001
******
******
******
0.071
******
0.077
******
******
******
O.OS3
******
******
******
0.078
******
******
******
0.079
******
******
******
O.OB3
******
0.116
PROPALD
PPM
3-PART
0.0003
******
******
******
0.0022
******
0.0033
******
******
******
0.0040
******
******
******
0.0044
******
******
******
0.0043
******
******
******
0.0049
******
0.0056
ACETONE
PPM
0.001
******
0.023
******
0.054
******
0.079
******
0.080
******
0.106
******
0.094
******
0.123
******
0.127
******
0.102
******
0.151
******
0.125
******
0.174
MEK
PPM
0.0
******
0.0054
******
0.0134
******
0.0191
******
0.0210
******
0.0257
******
0.0212
******
0.0306
******
0.0310
******
0.0193
******
0.0377
******
0.0293
******
0.0428
C3-N-2
PPM
C-600
******
******
0.0002
******
0.0009
******
0.0014
******
0.0016
******
0.0016
******
0.0022
******
0.0023
******
0.0024
******
0.0025
******
0.0025
******
0.0024
******
0.0025
C3-N-2
PPM
PANALYZR
0.0
******
0.0006
******
O.OJ12
******
0.0016
******
0.0020
******
0.0021
******
0.0023
******
O.<0024
******
0.0025
******
0.0024
******
0.0027
******
0.0027
******
0.0029
C4-N-2
PPM
PANALVZR
0.0
******
0.0004
******
0.0015
******
0.0022
******
0.0026
******
0.0029
******
0.0036
******
0.0037
******
0.0037
******
0.0037
******
0.0038
******
0.0039
******
0.0039
-------
EC -233
7-HYOROCAR80N MIX *2
1977 AUG 12
CLOCK
TIME
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
NJ 1445
*-* 1500
00 1515
1530
1545
1600
1615
ELAPSED
TIMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEG F
84.5
86.0
85.0
85.5
85.7
86.0
86.2
86.0
86.0
84.8
85.5
84.3
64.5
85.0
84.3
84.0
84.3
64.5
84.3
84.5
84.5
85.0
64.8
85.2
84.8
R6L HUH
S
51.0
50.5
51.0
52.0
52.0
52.5
52.5
52.5
52.5
53.0
53.5
53.5
54.5
54.5
54.5
55.0
55.0
54.5
54.0
54.0
54.0
53.5
53.5
53.5
53.5
SSPOWER
KM
16.52
******
16.52
******
16.60
******
16.51
******
16.46
******
16.55
16.59
16.23
******
16.72
******
16.47
******
******
******
16.72
******
******
******
16.80
RAOIOM
HW/CH2
0.227
0.232
0.232
******
0.232
******
******
******
0.227
******
******
0.232
0.225
******
******
******
0.227
******
******
******
0.230
******
******
******
0.239
HCHQ VOL
L
30.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
K)
EC -237
7-HYDROCARBON MIX *4
1977 OCT 28
BEGIN IRRADIATION 0930; 0.25 INCH PYREX FILTERS TR1CHROIC FILTER OUT
PEAKS ATTRIBUTED TO C6-N-0 OBSERVED ON PANALYZER, BUT DATA NOT QUANTIFIABLE
C3-N-2 INCLUDES SMALL AMOUNTS OF C2-N
PRUPIONALDeHYDE FACTOR ESTIMATED
AROMATICS AND OXYGENATES MONITORED WITH 3-PART COLUMN
OASIBl 1212, TECO 148, BECKMAN 6800 USED
6RADY 291 USED
CO FACTOR 1.6/2.93
T»0 AT 930 PDT
CAUB«
HCHO
PAN
REL INT
TS
REL HUH
SSPOwER
RAD10M
H20
NO
N02-CORR
ETHtNE
PROPENE
N-C4
T2-C4=
2,3-OMB
TOLUENE
M-XVL
CO
ACETALO
ACETONE
PEG K
*
KM
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
2
9
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT COND
INIT CCNO
INIT CONO
INIT COND
INIT COND
INIT COND
INIT CCNO
INIT CCND
INIT CONO
INIT CONO
INIT CCNO
INIT CCND
303.1
56.04
18.32
0.228
2.348E
0.377
0.106
0.875
0.100
1.025
0.050
0.463
0.086
0.091
0.956
0.001
0.003
ASSIGNED INITIAL CONDITION
-------
EC -Z37
7-HYOROCARBON MIX
1977 OCT 16
SPECTRAL DISTRIBUTION: hAVELENGTHCNMI REL. INTENSITY
500. 2.879
430. 2.240
403. 1.686
380. 1.581
370. 1.384
360. 1.156
350. 1.000
340. 0.781
330. 0.538
320. 0.300
310. 0.116
300. 0.018
290. 0.001
280. 0.001
270. 0.0
Kl-0.30 HIN-l
SAMPLING RATE » 1.692 L/MIN
Ni
00 49 GC SAMPLES TAKEN
-------
EC -237
7-HVOROCAR80N MIX #4
1977 OCT 28
00
CLOCK
TIME
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
13JO
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
T1MIN!
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.000
0.000
0.007
0.039
0.108
0.186
0.261
0.332
0.388
0.449
0.50B
0.555
0.591
0.616
0.638
0.647
0.652
0.647
0.642
0.633
0.625
0.611
0.601
0.591
0.581
NO
PPM
0.377
0.272
0.169
0.083
0.040
0.024
C.018
0.013
0.011
0.010
0.007
0.007
O.OC6
O.OC6
0.006
0.020
0.006
0.006
0.005
O.C05
0.005
0.005
0.005
0.005
0.005
N02-C3RR
PPM
0.106
0.199
0.293
0.356
0.373
0.357
0.331
0.3C5
0.277
0.244
0.216
0.183
0.154
0.130
0.110
0.083
0.086
0.082
0.078
0.065
0.055
0.054
0.052
0.052
0.050
NOX-CORR
PPM
0.483
0.470
0.462
0.437
0.413
0.380
0.347
0.318
0.286
0.251
0.223
0.187
0.159
0.135
0.115
0.103
0.091
O.OB6
0.083
0.069
0.059
0.057
0.057
0.054
0.054
ETHENE
PPM
0.875
******
0.928
******
0.874
******
0.786
******
0.732
******
0.659
******
0.609
******
0.542
******
0.490
******
0.449
******
0.418
******
0.380
******
0.352
PROPENE
PPM
0.100
******
o.oai
******
0.066
******
0.047
******
0.034
******
0.021
******
0.015
******
0.009
******
0.005
******
0.003
******
0.002
******
0.002
******
0.001
N-C4
PPM
1.02S
******
0.975
******
0.936
******
0.916
******
0.915
******
0.872
******
0.903
******
0.854
******
0.837
******
0.824
******
0.812
******
0.797
******
0.779
T2-C4"
PPM
0.050
******
0.031
******
0.011
******
0.001
******
0.000
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
2,3-QMB
PPM
0.463
******
0.441
******
0.422
******
0.399
******
0.3S1
******
0.365
******
0.359
******
0<*34l
******
0.322
******
0.314
******
0.307
******
0.300
******
0.292
TOLUENE
PPM
0.006
******
0.081
******
0.078
******
0.073
******
0.071
******
O.Oofl
******
0.065
******
0.062
******
0.061
******
0.058
******
0.057
******
0.055
******
0.053
M-XVL
PPM
0.091
******
0.076
******
O.U66
******
0.055
******
0.049
******
0.042
******
0.036
******
0.031
******
0.029
******
0.026
******
0.024
******
0.022
******
0.021
-------
EC -237
7-HVOROCARBDN MIX **
1977 OCT 38
oo
CLOCK
TIME
930
9*5
1004
1015
1030
10*5
1100
1115
IUO
11*5
1200
1215
1230
12*5
1300
1315
1330
13*5
1*00
1*15
1*30
1*45
1500
1515
1530
ELAPSED
T(MINJ
0.
15.
30.
*5.
60.
75.
90.
105.
120.
135.
153.
165.
180.
195.
210.
225.
2*0.
255.
270.
285.
300.
315.
330.
3*5.
360.
CO
PPM
0.96
0.96
0.98
0.99
1.01
1.0*
1.10
1.09
1.15
1.20
1.21
1.27
1.31
1.3*
1.39
l.*2
1.46
l.*7
1.53
1.55
1.58
1.62
1.66
1.69
1.73
PAN
PPM
0.000
******
0.001
******
0.012
******
0.027
******
0.0*2
******
0.055
******
0.068
******
0.079
******
0.036
******
0.083
******
0. 100
******
C.098
******
0.098
HCHO
PPM
0.0
******
******
******
0.107
******
******
******
0.228
******
******
******
0.335
******
******
******
0.38*
******
******
******
0.387
******
******
******
0.282
ACETALD
PPM
0.001
******
0.0*3
******
0.08*
******
0.086
******
0.097
******
0.10*
******
0.115
******
0.108
******
0.11*
******
0.100
******
0.110
******
0.098
******
0.10*
PROPALD
PPM
0.0002
******
0.0001
******
0.0009
******
0.0016
******
0.0026
******
0.003*
******
0.00*1
******
0.00**
******
0.00**
******
0.00*2
******
0.00*7
******
0.0042
******
0. 00**
ACETONE
PPM
0.003
******
0.02*
******
0.056
******
0.071
******
******
******
0.1*9
******
0.193
******
0.199
******
0.197
******
0.198
******
0.221
******
0.195
******
0.197
MEK
PPM
******
******
0.0061
******
0.013*
******
0.0163
******
0.0272
*******
0.033*
******
0.0*0*
******
0.0*00
******
0.0*68
******
0.0485
******
0.0526
******
0.0*91
******
0.0507
C3-N-2
PPM
PANALV/H
0.0
******
0.0006
******
0.0013
******
0.0016
******
0.0021
******
0.002*
******
0.0025
******
0.0027
******
0.0028
******
0.0029
******
0.0030
******
0.0032
******
0.0033
C*-N-2
PPM
PANALY/R
0.0
******
0.0005
******
0.0016
******
0.002*
******
0.0032
******
0.0033
******
0.00*3
******
0.52
******
0.005*
******
0.005*
******
0.005*
******
0.0055
******
0. 0059
-------
EC -237
7-HYDROCARBON MIX #4
1977 OCT 28
oo
CLOCK
TIME
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
TtHINI
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
TS
DEG F
84.0
84.5
84.5
84.6
85.7
86.2
86.5
86.5
87.0
66.5
87.0
86.5
86.5
87.0
86.7
86.2
66.2
86.7
66.5
66.5
36.5
86.5
86.2
66.5
£6.5
REL HUH
*
49.0
51.0
53.5
55.5
56.5
57.0
57.5
58.0
58.0
58.0
58.0
58.0
59.0
59.0
59.0
59.0
59.0
59.0
59.0
59.0
59.0
59.0
59.0
59.0
59.0
SSPOMER
KM
18.10
******
******
******
18.30
******
******
******
Id. 30
******
******
******
18.60
******
******
******
18.30
******
******
******
******
******
******
******
18.30
RAOIQH
MH/CM2
******
0.225
******
******
0.227
******
******
******
0.232
0.225
******
******
0.230
******
******
******
0.225
******
******
******
******
0.225
******
******
0.225
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
15.00
-------
EC -237
T-HYOROCARBON MIX «4
1977 OCT 28
to
oo
CLOCK
TIME
930
945
1000
1015
1030
I04i
1100
1115
1130
1145
1200
1215
1230
1245
130J
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
N02
PPM
0.106
0.200
0.296
0.365
0.388
0.380
0.363
0.344
0.325
0.298
0.276
0.250
0.230
0.211
0.197
0.173
0.181
0.175
0.169
0.165
0.164
0.161
0.159
0.159
0.158
NOX
PPM
0.484
0.471
0.464
0.446
0.427
0.403
0.379
0.358
0.333
0.305
0.283
0.255
0.234
0.216
0.202
0.193
0.186
0.178
0.173
0.169
0.167
0.165
0. 164
0.161
0.161
TOT N03
PPM
0.000
0.001
0.002
0.009
0.015
0.023
0.031
0.039
0.048
0.054
0.060
0.068
0.075
0.081
0.086
0.090
0.094
0.093
0.091
0.100
0.1 C9
0.103
0.107
0.107
0.107
TOT N
PPM
0.484
0.473
0.464
0.448
0.429
0.404
0.381
0.358
0.336
0.308
0.283
0.258
0.236
0.217
0.203
0.193
0.187
0.181
0.173
0.170
0.169
0.166
0.164
0.164
0.162
H20
PPM
19250.
20352.
21350.
22322.
23445.
24024.
24423.
24636.
25021.
24636.
25021.
24636.
25060.
25433.
25256.
24867.
24867.
25256.
2506C.
25060.
25060.
25060.
24867.
25060.
25060.
HCTOT
PPMC
10.472
10.332
10.192
10.035
9.877
9.646
9.415
9.397
9.378
9.231
9.0ti4
9.166
9.248
9.020
8.792
8.665
8.539
8.414
8.289
8.269
8.249
8.057
7.864
7.753
7.641
-------
EC -238
7-HYOROCARBON MIX *3
1977 OCT 31
BEGIN IRRADIATION 0900; 0.25 INCH PYREX FILTER; TRICHRQIC FILTER OUT
PgAKS ATTRIBUTED TO C6-N-0 03SERVEO ON PANALYZERt BUT DATA NOT QUANTIFIABLE
C3-N-2 INCLUDES SMALL AMOUNTS OF C2-N
PROPIONALDEHYDE FACTOR ESTIMATED
AHOM4TICS AND OXYGENATES MONITORED WITH 3-PART COLUMN
DASIdl 1212; TECO KB; BECKMAN 6800 USED
8RAOY 291 USED
FACTORS: CO 1.6/3.21
T«0 AT 900 PST
CO
CALIB*
HCHO
PAN
REL INT
TS
REL HUH
SSPJWER
RAOIOM
H20
NO
N02-CORR
ETHENE
PROPENE
N-C4,
T2-C4=
2i3-DM8
TOLUENE
M-XYL
CO
HCriO
ACETALD
ACETONE
DEC K
%
KW
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
2
9
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CONO
INIT COND
INIT CONO
INIT CONO
INIT CCNO
INIT CCND
INIT CONO
INIT CONO
INIT CCNO
INIT CONO
INIT CONO
INIT CONO
INIT COND
303.6
59.69
U.SO
0.233
2.547E
0.716
0.234
0.9S2
0.093
0.966
0.047
0.420
0.063
0.084
0.677
0.026
0.001
0.004
04
ASSIGNED INITIAL CONDITION
-------
EC -238
/-HYDROCARBON MIX #3
1977 OCT 31
SPECTRAL DISTRIBUTION: WAVELENGTH(NM) REL. INTENSITY
500. 3.267
430. 2.380
403. 1.970
380. 1.646
370. 1.428
360. 1.172
350. 1.000
340. 0.775
330. 0.527
320. 0.293
310. 0.111
300. 0.017
290. 0.000
230. 0.0
Kl=0.30 MIN-1
SAMPLING RATE * 1.621 L/MIN
79 GC SAMPLES TAKEN
ON
-------
EC -238
7-HVOROCAR80N MIX
1977 OCT 31
#3
CLOCK
TIME
900
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
N3 1330
00 1345
"^ 1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
ELAPSED
TtMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
OZONE
PPM
0.000
0.000
0.000
0.000
0.000
0.007
0.015
0.024
0.042
0.076
0.103
0.132
0.169
0.205
0.239
0.269
0.305
0.342
0.379
0.415
0.457
0.493
0.530
0.569
0.603
0.635
0.660
0.677
0.686
0.691
0.639
0.636
0.682
0.672
NO
PPM
0.718
0.633
0.545
0.440
0.357
0.231
0.217
0.166
0.122
0.093
0.073
0.061
0.046
0.037
0.034
0.024
0.024
0.022
0.02J
0.015
G.015
0.01.2
0.010
0.012
0.010
0.010
0.010
C.01Q
0.010
0.010
0.010
0.007
0.007
0.010
N02-CORR
PPM
0.234
0.297
0.379
0.465
0.534
0.585
0.627
0.654
0.669
0.663
0.664
0.649
0.637
0.609
0.532
0.556
0.518
0.430
0.441
0.402
0.362
0.320
0.284
0.243
0.210
0.177
0.147
0.127
o.ioa
0.095
0.086
0.081
O.C75
0.069
NOX-CORR
PPM
0.952
0.927
0.921
0.907
0.833
0.864
0.842
0.818
0.792
0.763
0.735
0.706
0.679
0.645
0.61'.
0.573
0.543
0.499
0.453
0.416
0.372
0.330
0.291
0.250
0.217
0.185
0.154
0.132
0.115
0.102
0.094
0.086
0.083
0:073
ETHENE
PPI«
0.982
******
0.949
******
0.911
******
0.852
******
J.814
******
0.774
******
0.725
******
0.665
******
0.627
******
0.576
******
0.542
******
0.436
******
0.433
******
0.389
******
0.354
******
0.321
******
0.298
******
PROPENE
PPM
0.093
******
0.082
******
0.070
******
0.060
******
0.053
******
0.044
******
0.035
******
0.027
******
0.020
******
0.015
******
0.010
******
0.006
******
0.004
******
0.002
******
0.002
******
******
******
0.001
******
N-C4
PPM
0.966
******
0.954
******
0.935
******
0.921
******
J.927
******
0.900
******
0.675
******
0.863
******
0.843
******
0.835
******
0.798
******
0.764
******
0.769
******
0.736
******
0.725
******
******
******
0.683
******
T2-C4*
PPM
0.047
******
0.033
******
0.020
******
0.011
******
0.005
******
0.001
******
0.000
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
0.0
******
******
******
0.0
******
2t3-OMB
PPM
0.420
******
0.401
******
0.392
******
0.383
******
0.369
******
0.355
******
0.341
******
9.331
******
0.318
******
0.31J
******
0.293
******
0.277
******
0.269
******
0.257
******
0.243
******
******
******
0.229
******
TOLUENE
PPM
0.083
******
0.078
******
0.075
******
0.073
******
0.070
******
0.069
******
0.067
******
0.064
******
0.062
******
0.058
******
0.057
******
0.054
******
0.053
******
0.050
******
0.048
******
******
******
0.045
******
M-XYL
PPM
0.0b4
******
0.074
******
0.065
******
0.059
******
0.052
******
0.047
******
0.043
******
******
******
0.035
******
0.030
******
0.027
******
0.023
******
0.020
******
0.017
******
0.016
******
******
******
0.013
******
-------
EC -238
7-HYDROCARBON MIX »3
1977 OCT 31
N>
CLOCK
TIME
900
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
ELAPSED
TIMINI
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
CO
PPM
0.66
1.53
1.56
1.59
1.61
1.60
1.62
1.66
1.67
1.67
1.72
1.71
1.78
1.79
1.83
1.86
1.90
1.91
1.97
1.99
2.02
2.05
2.07
2.14
2.15
2.20
2.25
2.27
2.33
2.35
2.35
2.42
2.43
2.43
PAN
PPM
0.000
******
0.001
******
0.004
******
o. oca
******
0.014
******
0.022
******
0.030
******
0.038
******
0.045
******
0.058
******
0.063
******
0.073
******
O.OB4
******
0.1UO
******
0.109
******
0.110
******
0.112
0.113
HCHO
PPM
0.026
******
******
******
0.054
******
******
******
******
******
******
******
0.209
******
******
******
0.292
******
******
******
0.3B2
******
******
******
0.404
******
******
******
******
******
******
******
U.302
******
ACETALD
PPM
0.001
******
0.038
******
0.075
******
0.099
******
0.107
******
0.111
******
0.128
******
0.118
******
0.128
******
0.101
******
0.110
******
0.114
******
0.114
******
0.106
******
0.108
******
******
******
0.086
******
PROPALO
PPM
0.0002
******
0.0002
******
0.0004
******
0.0005
******
C. OJ06
******
0.0014
******
0.0021
******
0.0025
******
0.0030
******
0.0033
******
0.0038
******
0.0042
******
0.0049
******
0.0055
******
0.0056
******
******
******
0.0051
******
ACETONE
PPM
0.004
******
0.018
******
0.035
******
0.054
******
0.071
******
0.095
******
0.120
******
0.132
******
0.156
******
0.170
******
0.192
******
0.194
******
0.233
******
0.263
******
0.258
******
******
******
0.254
******
MEK
PPM
0.0002
******
0.0047
******
0.0104
******
0.0160
******
0.0204
*******
O.OZoS
******
0.0324
******
0.0344
******
0.0412
******
0.0414
******
0.0515
******
0.0500
******
0.0610
******
0.0595
******
0.0696
******
******
******
0.0709
******
ME-N
PPM
0.0
******
0.0
******
0.0003
******
0.0003
******
0.0009
******
0.0009
******
0.0012
******
0.0015
******
0.0018
******
0.0015
******
0.0013
******
0.0013
******
0.0014
******
0.0013
******
0.0014
******
0.0015
******
0.0014
0.0016
C3-N-2
PPM
PANALYIR
0.0
******
0.0004
******
0.0010
******
0.0009
******
0.0017
******
0.0019
******
0.0023
******
0.9026
******
0.0028
******
0.0030
******
0.0032
******
0.0033
******
0.0035
******
0.0039
******
0.0040
******
0.0042
******
0.0040
0.0043
C4-N-2
PPM
PANAIYZR
0.0
******
0.0005
******
0.0013
******
0.0016
******
0.0024
******
0.0028
******
0.0037
******
0.0037
******
0.0042
******
0.0050
******
0.0055
******
0.0055
******
0.0065
******
0.0067
******
0.0076
******
0.0076
******
0.0075
0.0076
-------
EC -238
7-HYDROCARBON MIX «3
1977 OCT 31
OO
VO
CLOCK
TIME
900
915
930
945
1000
1015
1030
10*5
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
ELAPSED
TtMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
TS
OEG F
86.0
85.0
84.8
86.2
86.7
86.5
87.0
66.7
87.2
87.9
87.9
88.2
88.2
88.2
87.9
67.9
87.4
87.2
86.7
86.5
86.7
86.7
87.0
86.7
66.5
87.0
86.5
86.5
86.5
86.5
86.2
86.5
87.0
86.5
REL HUN
*
50.0
51.5
54.5
56.5
57.0
57.5
58.0
58.5
59.0
59.0
59.0
59.0
59.0
59.5
59.5
59.5
59.5
60.0
60.5
61.0
61.5
62.0
62.0
62.0
62.0
62.0
62.0
62.0
62.0
62.0
62.0
62.0
62.0
62.0
SSPOMER
KW
18.70
18.40
******
******
******
******
******
******
Id. 10
******
******
******
19.10
******
******
******
18.90
******
******
******
19.20
******
******
******
19.10
******
******
******
******
19.20
******
******
19.40
******
RADIOM
MW/CM2
0.234
******
******
******
******
******
******
******
0.215
0.237
******
******
0.234
******
******
******
0.230
******
******
******
0.230
******
******
0.230
0.234
******
******
******
0.234
0.234
******
******
0.239
******
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
******
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
******
******
******
******
20.00
******
-------
EC -238
7-HVDROCARBON MIX #3
19T7 QCT 31
fo
«3
O
CLOCK
TIME
900
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
12*5
1300
1315
133J
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
ELAPSED
TIMINI
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
N02
PPH
0.234
U.298
0.381
0.469
0.540
0.594
0.638
0.669
0.689
0.691
0.691
0.681
0.674
0.650
0.628
0.606
0.572
0.540
0.508
0.474
0.440
0.401
0.366
0.332
0.305
0.281
0.259
0.244
0.230
0.217
0.210
0.205
0.200
0.195
NOX
PPM
0.953
0.928
0.923
0.911
0.894
0.872
0.852
0.833
C.811
0.787
0.762
0.738
0.716
0.686
0.660
C.628
0.596
0.559
0.520
0.439
0.449
0.410
0.374
0.340
0.313
0.238
0.266
0.249
0.237
0.225
0.217
0.210
0.208
0.200
TOT N03
PPM
0.000
0.001
0.002
0.004
0.006
o.coa
0.011
0.015
0.019
0.023
0.027
0.032
0.037
0.041
0.045
0.049
0.053
0.060
0.067
0.072
0.078
0.080
0.083
0.089
0.095
0.104
0.112
0.117
0.122
0.123
0.124
0.124
0.125
0.127
TJT fo
PPM
0.953
0.931
0.926
0.909
0.896
0.874
0.855
0.835
0.811
0.789
0.765
0.743
0.721
0.686
0.662
0.630
0.596
0.562
0.528
0.489
0.454
0.413
0.376
0.344
0.315
0.291
0.269
0.254
0.239
0.227
0.220
0.213
0.208
0.205
H20
PPM
20910.
20876.
21920.
23813.
24400.
24423.
25021.
25042.
25651.
26253.
26253.
26457.
26457.
26681.
26476.
26476.
26069.
26086.
25898.
25910.
2t>326.
26540.
26747.
26540.
2633 5.
26747.
26335.
26335.
26335.
26335.
26131.
26335.
26747.
26335.
HCTOT
PPMC
10.112
9.971
9.830
9.722
9.614
9.522
9.429
9.374
9.319
9.22i
9.127
9.045
8.962
8.845
8.729
8.671
8.613
8.515
8.418
8.329
8.241
8.054
7.867
7.880
7.894
7.764
7.633
7.533
7.432
7.299
7.167
7.044
6.922
6.925
-------
EC -241
7-HYDROCARBON MIX #5
1977 NOV 4
dEGIM IRRADIATION 0845} 0.25 INCH PYR5X FILTER} TRICHROIC FILTER OUT
PcAKS ATTRIBUTED TO C6-N-D OBSERVED ON PANALYZER. BUT DATA NOT QUANTIFIABLE
C3-N-2 INCLUDES SMALL AMOUNTS OF C2-N
AROM4TICS AND OXYGENATES MONITORED WITH 3-PART COLUMN
DASI8I 1212, TECO 148, BECKMAN 6BOO, BRADY 291 USED
FACTORS: co 1.6/0.264
T=0 AT 845 PST
to
CALIB*
PAN
HCHO
REL INT
TS
RcL HUM
SSPOrtER
RAOIOM
H£D
NO
N02-CORR
ETHENE
PROPENE
N-C4
T2-C4=
2i3-DMQ
TOLUJNE
M-XYL
CO
HCHO
ACETALD
ACETONE
OEG K
%
KW
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
2
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
I NIT OND
INIT CCND
INIT COND
INIT CONO
INIT COND
INIT COND
INIT CQND
INIT CONO
INIT CQND
I NIT COND
INIT CONO
INIT CCND
INIT COND
303.3
49.18
18.91
0.226
2.070? 04
0.379
0. 110
0.484
0.045
0.404
0.024
0.2L1
0.040
0.044
1.296
0.018
0.001
0.002
ASSIGNED INITIAL CONDITION
-------
EC -241
7-HYOROCARBON MIX #5
1977 NOV 4
SPECTRAL DISTRIBUTION: hAVELENGTril NMI REL. INTENSITY
500. 2.969
430. 2.297
403. 1.932
330. 1.633
370. 1.396
360. 1.164
350, 1.000
340. 0,773
330. 0.524
320. 0,266
310. 0.103
300. 0.017
290. 0.001
230. 0.0
Kl*0.30 MIN-l
SAMPLING RATE = 1.7C6 L/MIN
49 GO SAMPLES TAKEN
to
-------
EC -241
7-HVDROCARBON MIX #5
1977 NOV 4
N>
CLOCK
TIME
645
900
915
930
945
1003
1015
1030
10*5
1100
1115
1130
11*5
1200
1215
123)
1245
1303
1315
1330
1345
1400
1415
1430
1445
ELAPSED
T(HIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
13*.
150.
165.
183.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.000
0.000
0.000
0.000
0.002
0.010
0.017
0.029
0.044
0.064
0.086
0.103
0.125
0.147
0.173
0.195
0.217
0.239
0.264
0.291
0.310
0.335
0.362
0.386
0.408
NO
PPM
0.379
0.333
0.292
0.247
0. 200
0.161
0. 120
0.093
0.072
0.055
0.046
0.040
0.034
C. 031
0.023
0.022
0.017
0.018
0.015
0.013
0.011
0.012
0.011
0.010
0.010
N02-CORR
PPM
0.110
0.147
0.182
0.222
0.257
0.263
0.318
0.335
0.341
0.346
0.340
0.334
0.332
0.325
0.314
0.302
0.292
0.274
0.259
0.249
0.234
0.228
0.211
0.191
0.171
NQX-CORR
PPM
0.489
0.401
0.473
0.467
0.456
0.446
0.436
0.427
0.412
0.400
0.387
0.373
0.365
0.355
0.337
0.322
0.309
0.291
0.273
0.263
U.245
0.236
0.220
0.197
0.178
ETHENE
PPM
0.484
******
0.455
******
0.433
******
0.391
******
0.396
******
0.362
******
0.349
******
0.327
******
0.309
******
0.294
******
0.269
******
0.249
******
0.230
• PHOPcNE
PPM
0.045
******
0.042
******
0.035
******
0.030
******
0.027
******
0.021
******
0.019
******
0.013
******
0.012
******
o.ooa
******
0.007
******
0.004
******
0.003
N-C4
PPM
0.464
******
0.472
******
0.448
******
0.435
******
0.45?
******
0.423
******
0.432
******
0.400
******
0.412
******
0.389
******
0.398
******
0.369
******
0.364
T2-C4-
PPM
0.024
******
0.017
******
0.011
******
0.006
******
0.003
******
0.001
******
0.000
******
0.0
******
0.0
******
0.0
******
' 0.0
******
0.0
******
0.0
2t3-OMB
PPM
0.211
******
0.203
******
0.197
******
0.188
******
0.184
******
0.177
******
0.173
******
OV166
******
0.160
******
0.154
******
0.149
******
0.142
******
0.133
TJLUENE
PPM
0.040
******
0.039
******
0.037
******
0.035
******
0.035
******
J.033
******
0.032
******
0.031
******
0.030
******
0.027
******
0.028
******
3.027
******
0.025
H-XVL
PPH
0.044
******
0.039
******
0.034
******
0.030
******
0.027
******
0.024
******
0.022
******
0.019
******
0.018
******
0.014
******
0.014
******
0.012
******
o.uio
-------
EC -2*1
7-HYDROCARBON MIX *5
1977 NOV 4
N>
CLOCK
TIM£
845
900
915
930
945
1030
1015
1030
1045
1100
1113
1130
1145
1200
1215
123J
1245
13dO
1315
133J
1345
1400
1415
1430
1445
ELAPSED
TIMIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
1.30
1.28
1.31
1.27
1.33
1.36
1.36
1.38
1.40
1.41
1.43
1.49
1.49
1.52
1.55
1.56
1.59
1.62
1.70
1.67
1.70
1.73
1.78
1.78
1.89
PAN
PPM
0.000
******
0.000
******
0.002
******
0.004
******
0.008
******
0.012
******
0.016
******
0.020
***&«*
0.024
******
O.J31
******
0.034
******
0.037
******
0.047
HCHO
PPM
0.018
******
******
******
0.034
******
******
******
0.046
******
******
******
0.097
******
******
*«.-***#
O.C66
******
******
******
0.101
******
******
******
0.137
ACETfcLD
PPM
0.3010
******
0.0155
******
0.0305
******
0.0429
******
0.0505
******
0.0451
******
0.0552
******
3.0565
******
0.0586
******
0.0486
******
0.0603
******
0.0623
******
0.0542
PROPALO
PPM
0.0002
******
0.0002
******
0.0003
******
0.0005
******
0.0007
******
0.0009
******
0.0014
******
0.0019
******
0.0022
******
0.0022
******
0.0029
******
0.0033
******
0.0036
ACETONE
PPM
0.0023
******
0.0095
******
0.0173
******
0.0277
******
0.0374
******
0.0368
******
******
******
0.0609
******
0.0698
******
0.0591
******
0.0837
******
J.0878
******
0.0910
MEK
PPM
0.0003
******
0.0028
******
0.0055
******
0.0091
******
0.0120
******
0.0121
******
0.0165
******
0.0ld5
******
0.0214
******
0.0168
******
0.0253
******
0.0262
******
0.0272
C3-N-2
PPM
PANALYZR
0.0
******
0.0001
******
0.0005
******
0.0007
******
0.0007
******
O.oOOS
******
0.0009
******
0.0010
******
0.0013
******
0.0016
******
0.3016
******
0.0015
******
0.0016
C4-N-2
PPM
PANALViR
0.0
******
0.0
******
0.0009
******
0.0011
******
0.0011
******
0.0013
******
0.0015
******
O.X3013
******
0.0016
******
0.0016
******
0.0016
******
0.0017
******
0.0013
-------
EC -2*1
7-HVDROCAR80N MIX «5
1977 NOV 4
to
VD
CLOCK
TIMc
845
900
915
930
945
1000
1015
1030
104a
11 JO
1115
1130
1145
12JO
1315
1230
124b
1300
1313
1330
1345
1400
1415
143J
1445
ELAPSED
TIMINt
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
163.
195.
210.
225.
240.
255.
270.
265.
300.
315.
. 330.
345.
360.
TS
DEC F
85.2
85.5
84. B
85.0
85.5
85.7
86.0
85.7
86.2
86.2
66.2
86.2
87.0
Bb.7
86.5
87.2
b7.0
87.0
86.7
86. 5
87.2
87.2
86.7
87.0
87.0
REL HUM
*
42.0
43.0
46.0
48.0
49.0
49.5
50.0
50.5
50.5
50.5
51.0
51.0
51.0
51.0
51.0
51.0
51.0
51.0
50.5
51.0
51.0
51.0
51.0
51.0
51.0
SSPOWER
Kh
ia.40
******
******
******
18.80
******
******
******
19.00
******
**««**
******
19.10
******
******
******
18.90
******
******
******
19.10
******
******
******
19.10
RADIDM
MW/CM2
0.225
0.227
0.225
0.220
0.220
******
******
******
0.232
0.225
0.225
******
0.222
******
******
******
0.227
0.227
******
******
0.227
******
******
******
0.230
HCHO VCL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20. 00
******
******
******
20.00
******
******
******
20.00
-------
VD
EC -242
7-HYDRGCARBON MIX #7
1977 NOV 7
BEGIN IRRADIATION 0945; 0.25 INCH PYKEX FILTER; TR1CHROIC FILTER OUT
PEAKi ATTRIBUTED TO C6-N-D OBSERVED ON PANALYZER, BUT DATA NOT QUANTIFIABLE
C3-N-2 INCLUDES SMALL AMOUNTS OF C2-N
AR01ATICS AND OXYGENATES MONITORED WITH 3-PART COLUMN
DASI8I 1212, TECO 14B, BECKMAN 6800. BRADY 291 USED
FACTORS: co 1.6/0.231
T-0 AT 945 PST
CALIB»
HCHO
PAN
REL INT
TS
REL HUM
SSPOWER
RAOIOM
H20
NO
N02-CCRR
ETH=NE
PRQPENE
N-C4
T2-C4 =
2.3-OMB
TOL'JENS
M-XYL
CO
HCHC
ACETALO
AC = TON=
DEG K
X
KW
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
2
9
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCNO
INIT COND
INIT COND
INIT CJND
INIT CCNO
INIT CCND
INIT COND
INIT CCND
INIT COND
INIT CCNO
INIT CCND
INIT CCND
303.1
59.09
19.40
0.231
2.»75= 04
0.377
0.125
2.014
0.109
0.558
0.108
0.203
0.306
0.306
1.021
0.028
0.002
0.004
ASSIGNED INITIAL CONDITION
-------
EC -242
7-HYOROCARBON MIX #7
1977 NOV 7
SPECTRAL DISTRIBUTION: hAVELENGTHI MM) REL. INTENSITY
500. 2.965
430. 2.251
403. 1.869
330. 1.617
370. 1.401
360. 1.163
350. 1.000
340. 0.771
330. 0.530
320. 0.289
310. 0.111
300. 0.017
290. 0.001
230. 0.0
M=0.30 MIN-l
SAMPLING RATE « 1.761 L/M1N
4d GO SAMPLES TAKEN
-------
EC -242
7-HYDROCARBON MIX »7
1977 N3V 7
CLOCK
TIME
945
1000
1015
1030
1045
110J
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
fS 1
-------
EC -242
7-HYOROCAR80N MIX » 7
1977 NOV 7
N3
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
i430
1445
1500
1515
1530
1545
ELAPSED
T(MIN)
0.
15.
30.
45.
uO.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
1.02
1.09
1.12
1.22
1.33
1.41
1.49
1.61
1.66
1.73
1.80
1.88
1.95
2.02
2.10
2.14
2.24
2.29
2.36
2.44
2.51
2.54
2.63
2.68
2.78
PAN
PPM
0.0
******
0.016
******
******
******
0.110
******
0.125
******
0.128
******
0.140
******
0.128
******
0.132
******
0.128
******
0.114
******
0.138
******
0.111
HCHO
PPM
0.028
******
******
******
0.443
******
******
******
0.646
******
******
******
0.575
******
******
******
0.580
******
******
******
0.620
******
******
******
0.673
ACETALD
PPM
0.002
******
0.132
******
0.164
******
0.172
******
0.166
******
0.159
******
0.134
******
0.147
******
0.127
******
0.135
******
0.123
******
0.127
******
0.115
PRQPALD
PPM
0.0003
******
0.0016
******
0.0047
******
0.0061
******
0.0061
******
0.0061
******
0.0045
******
0.0049
******
0.0041
******
0.0043
******
0.0038
******
0.0043
******
0.0039
ACETONE
PPM
0.0039
******
0.0276
******
******
******
0.0736
******
0.0700
******
0.0773
******
0.0541
******
0.0700
******
0.0595
******
0.0684
******
0.0603
******
0.0706
******
0.0644
MEK
PPM
0.0002
******
0.0065
******
0.0122
******
0.0182
******
0.01J8
******
0.0211
******
0.0177
******
0.0230
******
0.0191
******
0.0239
******
0.0201
******
0.0254
******
0.0221
ME-N
PPM
0.0
******
0.0002
******
O.uUOl
******
******
******
0.0005
******
0.0004
******
******
******
******
******
0.0004
******
0.0005
******
0.0006
******
0.0004
******
0.0006
C3-N-2
PPM
PANALY^R
0.0
******
O.OOG3
******
0.0004
******
******
******
0.0007
******
0.0009
******
0.0011
******
O.OOOd
******
0.0011
******
0.0007
******
0.0013
******
0.0007
******
0.0011
C4-N-2
PPM
PANALYIR
0.0
******
0.0002
******
0.0002
******
******
******
******
******
0.0019
******
0.0019
******
0.0019
******
0.0017
******
0.0022
******
0.0022
******
0.0015
******
0.0019
-------
EC -242
7-HyDROCARBON MIX #7
1977 NOV 7
Lo
O
O
CLOCK
TIME
943
1000
1015
1030
1045
1100
1113
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
141?
1430
1445
1500
1515
1530
1545
ELAPSED
TIMIN)
0.
15.
30.
45.
63.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC F
66.0
85.7
84.3
d4.3
85.2
85.5
85.7
86.0
85.7
85.7
86.2
86.2
86.0
86.2
86.2
86.0
86.5
86.0
8o.2
87.0
87.0
86.5
87.2
66.5
87.0
REL HUM
Z
50.0
51.0
54.0
56.5
58.0
59.5
60.0
60.5
61.0
61.5
62.0
62.0
62.5
62.0
62.5
62.5
62.5
63.3
63.0
62.5
62.5
62.5
62.5
62.5
63.3
SSPOrffR
KM
******
18.80
******
******
19.40
******
******
******
19.20
******
******
******
19.50
******
******
******
19.40
******
19.60
******
19.90
******
******
******
19.40
RADIOM
MM/CH2
0.220
0.232
0.227
0.222
0.230
******
******
******
0.232
******
******
******
0.234
******
******
******
******
0.227
0.227
******
0.24f
******
******
******
0.222
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
OJ
o
EC -Z43
7-HVOROCAR60N MIX *7A
1977 NOV 6
6EGIN IRRADIATION 0945! 0.25 INCH PYKEX FILTER: TRICHROIC FILTER OUT
PSAKS ATTRIBUTED TO C6-N-C OBSERVED ON PANALV^ERt BUT DATA NOT QUANTIFIABLE
C3-N-i INCLUDES SMALL AMOUNTS OF C2-N
ARQMATICS AND OXYGENATES MONITORED KITH 3-PART COLUMN
DASIUI 1212, TcCO 14Bt BECKMAN 6600, cJRADY 291 USED
FACTORS: CO 1.6/0.263
T«0 AT 945 PST
CALIB*
HCHO
REL INT
TS
REL HUM
JSPOWER
At-DlOM
H20
NJ
NtiH-cORR
cTHcNE
PR OPE HE
N-C4
T2-C4 =
2,3-DMb
TOLUcNe
M-XYL
CO
ACETALD
ACETONE
DEG K
X
KW
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
2
4
AVERAGE
AVERAGE
AVcAAGE
AVERAGE
AVERAGE
INIT CCNO
1N1T CGND
IMT CONO
INIT CCND
IMT CCNO
1MT CCNO
INIT CCNO
INIT CONO
JNIT CONO
INIT CCNO
INIT CCNO
INIT CCNO
301.8
42.12
11.40
0.229
1.710E
0.366
0.115
1.939
0.109
O.Soti
0.110
0.084
0.155
0.1S4
0.608
0.001
O.C02
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: hAVELENGTHI NKI
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
M«=0.30 MIN-1
SAMPLING RATE « 1.639 L/MIN
20 GC SAMPLES TAKEN
REL.
INTENSITY
3.100
2.343
1.S54
1.616
1.414
1.172
1.000
0.775
0.531
0.293
0.110
0.017
0.000
0.0
-------
EC -243
7-HirOROCARBQN MIX #7A
1977 NOV 6
CLOCK
TIME
9t5
1000
1015
10JO
1045
1100
1115
1130
11-.5
1200
1215
ELAPSED
T(HIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
OZONE
PPM
0.000
0.000
0.076
0.303
0.459
0.367
0.635
0.686
0.711
0.716
0.711
NO
PPM
0.386
0.223
0.055
C.018
0.012
0.010
0.010
0.011
O.OC9
0.010
0.009
NJ2-CJRR
PPM
0.115
0.257
0.394
0.364
0.3C4
0.260
0.197
0.151
0.113
0.096
0.086
N02-CORR
PPM
******
******
0.0
0.0
c.o
0.0
0.0
0.0
0.0
0.0
0.0
NOX-CORR
PPM
0.502
0.461
0.447
0.380
0.315
0.269
0.204
0.160
0.119
0.103
0.092
NOX-CORR
PPM
0.502
0.481
0.447
0.380
0.315
0.269
0.204
O.loO
0.119
0.103
0.092
ETHENE
PPM
1.94
******
1.79
******
1.58
******
1.42
******
1.27
******
1.14
PRGPENE
PPM
0.109
******
0.087
******
0.055
******
0.034
******
0.019
******
0.011
N-C4
PPM
U.5o&
******
0.553
******
0.53s
******
0.523
******
0.506
******
0.495
T2-C4=
PPM
0.110
******
0.052
******
O.G01
******
O.uGO
******
0.000
******
o.coo
2i3-OMB
PPM
O.U84
******
0.060
******
0.073
**««**
0.071
******
O.Oob
******
0.063
TOLUENE
PPM
0. 155
**v* *v
u. 1-.1
******
0.136
******
0. 136
******
O.U5
******
0.116
M-xrt
PPM
0.15".
******
O.l^i
******
0.099
******
0. Os 3
***»*»
D.073
**»»*»
O.Gol
-------
Co
O
U)
EC -243
7-HYDROCARBON MIX #7A
1977 NOV 8
CLOCK
TIME
945
1000
1015
1030
1045
110U
1119
1130
1145
UOO
1215
ELAPSED
TJMIN1
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
CO
PPM
0.61
0.70
0.67
0.73
0.79
0.85
0.92
1.01
1.10
1.17
1.23
PAN
PPM
0.0
******
0.009
******
C.045
******
C.072
******
C. 100
******
0.100
HCHO
PPM
0.0
******
******
******
0.223
******
******
******
0.571
******
******
ACETALD
PPM
0.001
******
0.105
******
0.192
******
0.181
******
0.172
******
0.145
PROPALD
PPM
O.OJ01
******
0.0004
******
0.0037
******
0.0049
******
0. 0061
******
0.0055
ACETONE
PPM
0.0019
******
0.0084
******
0.0286
******
0.0336
******
0.0407
******
0.0352
HEK
PPM
0.0002
******
0.0054
******
0.0144
******
0.0176
******
0.0222
******
0.0215
ME-N
PPM
0.0
******
0.0002
******
0.0004
******
******
******
0.0005
******
0.0007
C3-N-2
PPM
PANAIUR
0.0
******
O.OOOa
******
0.0004
******
******
******
0.0005
******
0.0009
C4-N-2
PPM
PANALYiR
0.0
******
0.0004
******
0.0005
******
******
******
0.0019
******
0.0012
C6-N-D
PFh
0.0
******
0.0006
******
0.0009
******
0.0027
******
0.0040
******
******
-------
EC -243
7-HYDROCARBON Mix *7A
1977 NOV 6
CLOCK
TIME
945
1000
1015
1030
1045
1100
111?
1130
1145
1200
1215
ELAPSED
TIMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
TS
DEC F
61.3
84.0
83.8
84.5
85.2
65.5
86.0
86.0
86.0
86.2
86.5
REL HUM
i
48.0
50.5
53.0
54.0
55.5
55.5
56.0
56.5
56.5
56.5
56.5
SSPOhER
Kb
18.70
******
******
******
19.27
******
******
******
19.32
******
******
RADIOM
HM/CH2
******
0.232
0.227
0.230
0.225
******
******
******
0.232
0.230
******
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
o
-c-
-------
EC -24S
7-HYDfcOCARBCN MIX #6
1977 NOV 9
CO
o
Ln
IRRADIATION 0945; C.25 INCH PYREX FILTER! TRICHROIC FILTER OUT
1356: CHAMBER BRIEFLY OPENED TO PUMPING SYSTEM: EST. LESS THAN 2? DILUTION
PEAKS ATTRIBUTED TO CG-N-D OBSERVED ON PANALYZEK, BUT DATA NOT gUANTIFIABLE
C3-N-2 INCLUDES SMALL AMOUNTS OF C2-N
AROMATICS AND OXYGENATES MONITORED hITH 3-PART COLUMN
0945: 3-PART SAMPLE DILUTED} PRE T=0 VALUE USED
BRADY 291 NOT CCNNECTEC TC CHAMBER UNTIL 1532
uASIBI 1212, TECO 146, 8ECKMAN 6600, BRADY 291 USED
FACTORS: co 1.6/0.247
T=0 AT 945 PST
CALIB«
HCHO
REL INT
PAN
TS
REL HUM
SSPCnffR
RADIOM
H20
NO
NG2-CGRR
ETHENE
PtvOPENE
N-C4 "
T2-C4=
2,3-OMB
TOLUENE
M-XYL
Cj
hCHO
ACETONE
DEC K
*
KM
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
2
4
9
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CONG
INIT CJMJ
INIT CCND
INIT CCMO
IMT CCND
IMT CONG
INIT CCNO
INIT CCND
INIT CONC
INIT CCND
INIT CCNO
INIT CCND
302.6
50.25
19.51
C.232
9.217E 05
C.743
0.259
Z.055
0.104
C.534
0.102
0.165
0.321
O.il7
2.5C2
O.C16
0.002
ASSIGNED INITIAL CCNDITION
-------
EC -245
7-HfDROCAKBCN MIX #£
1977 NCV 9
SPECTRAL DISTRIBUTION: V.AVELENGTHINM REL. INTENSITY
500. 2.047
430. 2.323
403. I. 546
380. 1.619
370. 1.407
36C. 1.168
350. l.COO
340. 0.779
330. 0.532
320. 0.293
ilO. 0.110
300. 0.016
290. 0.000
260. 0.0
M = 0.30 MIN-i
SAMPLING RATE = 1.7C7 L/MIN
Co 50 GC SAMPLES TAKEN
O
-------
EC -245
7-HYDROCARBON MIX *6
1977 NOV 9
o
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1243
1300
1315
1.130
1345
1400
1415
1430
It45
1500
1515
1530
1545
ELAPSED
TIMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
clCl.
ti5»
240.
2a3.
£70.
2fc5.
300.
315.
330.
345.
360.
UZCNE
PPM
0.000
0.000
0.000
0.027
0.130
0.283
0.423
0.547
0.669
0.774
0.843
0.884
0.892
0.887
0.870
0.845
0.916
0.774
0.745
0.721
0.699
0.679
0.664
0.647
0.635
WO
PPM
0.743
0.591
0.391
•0.181
0.068
0.032
0.022
C.015
0.012
0.012
0.012
0.010
0.012
C.020
3.010
0.010
0.010
0.010
0.012
0.010
C.010
C.010
0.010
0.010
0.010
t»Q2-CQRft
PPM
0.259
0.391
0.560
0.711
C.755
0.703
C.630
0.536
0.443
0.351
0.258
0.206
0.175
0.145
0.112
0.095
O.C78
0.083
0.091
0.090
0.090
0.099
o.ua
0.109
0.118
NOX-CORR
PPM
0.992
0.970
0.943
0.889
0.818
0.732
0.644
0.548
0.453
0.358
0.266
0.213
0.180
0.157
0.117
0.100
0.085
o.oaa
0.098
0.095
0.095
0.106
0.115
0.117
0.123
ETHENE
PPM
2.055
******
1.947
******
1.801
******
1.634
******
1.462
******
1.279
******
1.121
******
1.007
******
0.915
******
0.8C5
******
0.739
******
0.686
******
0.628
PROPENE
PPM
0.104
******
0.090
******
0.069
******
0.047
*.*****
0.028
******
.0.014
******
0.008
******
0.004
******
0.002
******
0.001
******
0.001
******
0.001
******
0.001
N-C4
PPM
0.534
******
0.527
******
0.512
******
0.500
**.***
0.4B5
******
0.469
******
0.462
******
0.445
******
0.444
******
0.427
******
0.421
******
0.41C
******
0.405
T2-C4-
PPM
0.102
******
0.065
******
0.019
******
0.001
******
0.000
******
0.000
******
0.000
******
0.000
******
0.000
******
0.000
******
0.000
******
0.000
******
c.ooo
2 i 3- OMB
PPM
0.185
******
0.179
******
0.170
******
0.161
******
0.152
******
0.143
******
0.138
******
0.131
******
0.129
******
0.123
******
0.121
******
U.116
******
0.114
TOLUENE
PPH
0.321
******
0.300
******
0.269
******
0.263
******
0.249
******
0.245
******
0.229
******
0.223
******
0.220
******
0.191
******
0.199
******
0.18o
******
0.187
M-AYl
PPM
0.317
******
0.272
******
0.202
******
0.177
******
0.146
******
0.129
******
0.106
******
0.097
******
0.091
******
0.070
******
0.075
******
0.066
******
O.uoS
-------
EC -245
7-HVORGCAKBON Ml* ttk
1977 NOV 9
LO
o
oo
CLOCK
TIME
9fb
1000
1015
103d
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
If Ou
1415
14 JO
1445
1500
1515
1530
1545
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
IbO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
Soil.
CO
PPM
2.5u
2.39
2.5J
2.5d
2.60
2.69
2.77
2.85
2.93
3.02
3.13
3.28
J.36
3.45
3.51
3.59
3.66
3.78
3.75
3.66
3.89
3.97
4.02
4.12
4.16
PAN
PPM
0.0
******
C.004
******
0.027
******
0.061
******
C.1JO
******
C.13U
******
0.150
******
0.176
******
0.194
******
0.176
******
C.183
******
0.164
******
C.162
HCHO
PPM
0.016
******
******
******
0.277
******
******
******
0.574
******
******
******
0.639
******
******
******
0.776
******
******
******
0.bS5
******
******
******
0.712
ACETALD
PPM
C. JUG
******
0.06
-------
EC -245
7-HYDRCCARBON MIX
1977 NOV 9
to
o
VD
CLOCK
TIME
945
iooo
1015
103d
i.045
1100
1115
1130
1145
I20u
Ui3
123u
1245
1300
1315
1330
1345
1400
1415
1430
1445
*5uO
1515
1530
1545
ELAPSEC
TiMINl
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
TS
DEC F
84. 3
84. 6
64.5
65.0
66.2
86.2
do. 5
66.7
67.0
66.7
86.5
86.5
66.0
bo. 2
86.5
bo. 5
6o.7
37.0
86.7
86.5
66.5
66.5
67.2
66.7
87.0
KEL HUM
I
******
******
******
******
******
******
******
******
******
XI*****
******
******
******
******
******
******
******
******
******
******
******
******
***v**
50.5
50.0
SSPOWER
KM
19.40
******
******
******
19.40
*«v***
******
******
19.80
******
******
******
19.30
******
******
******
19.50
******
******
******
19.60
******
******
******
19.60
RACIOM
MW/CM2
0.225
0.232
0.230
0.227
0.230
******
******
******
0.242
0.2i2
0.225
0.227
0.230
******
******
iii*****
0.234
******
******
**¥***
0.234
******
******
******
0.239
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
*#****
20.00
-------
u>
M
o
EC -246
7-HYDROCARBGN MIX «1
1977 NUV 10
BEGIN IRRADIATION 0930; 0.25 INCH PtREA FILTERi TRICHROIC FILTER OUT
PEAKS ATTRIBUTED TO C6-N-0 OBSERVED UN PANALYiER, BUT DATA NOT QUANTIFIABLE
C3-N-2 INCLUDES SHALL AMOUNTS OF C2-N
ARCiMATICS AND OXYGENATES MONITORED hITH j-PART COLUMN
OASI6I 1212, TECO 14B, BECKHAN 6800, BRADY 291 CScO
FACTORS: CO 1.6/0.227
T«0 AT 930 PST
CALIB#
HCHO
PAN
REL INT
TS
REL HUM
SSPOWER
RAOIOM
H20
NO
N02-CORR
ETHENE
PftuPENE
N-C4
T2-C4=
2,3-DMB
TOLUENE
M-XYL
ACETONE
MEK
DEC K
%
KM
MH/CM2
PPM
PPh
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
2
9
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
1MT CCNO
INIT CCNO
INIT CCNO
IMT CCNO
INIT CCND
INIT CCNO
INIT CCNO
INIT CCNO
INIT CCNO
INIT CCNO
303.3
52.57
19.25
C.232
2.22SE 04
C.386
0.122
C.253
0.049
1.C56
0.326
0.538
C.023
0.023
C.C02
0.001
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: hAVELENGTHlNMJ
500.
430.
40 3.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
Kl-0.30 MIN-1
SAMPLING RATE - 1.617 L/MIN
74; GC SAMPLES TAKEN
REL. INTENSITY
.3.046
2.332
1.950
1.609
1.402
1.159
1.000
0.776
0.526
0.268
0.111
O.C16
0.001
0.0
-------
EC -246
7-HYDRCCAR80N MIX
1977 NOV 10
U)
CLOCK
TIME
930
945
1000
Iul5
1030
1045
ilOO
111?
1UO
1145
12uO
1215
12:>0
1245
1300
1315
1330
1345
14 JO
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
1745
1800
1615
1830
1845
1900
ELAPSED
TIMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ibO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
510.
525.
540.
555.
570.
OZONE
PPM
0.000
0.000
0.000
0.000
O.OC2
0.012
0.022
0.032
0.051
0.066
0.0&8
0.105
0.127
0.144
0.169
0.1S6
0.205
0.<.
-------
6C -246
7-HYDROCARBON HIX HI
1977 NOV 10
CLOCK
TJMC
930
945
1000
101?
Iu30
Iu45
1100
1115
1130
1145
UOO
121 5
1230
U45
1300
1315
1330
1345
i4oo
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
1700
1715
173o
1745
1600
Idl5
1630
1845
190J
ELAPSED
TtMINl
0.
15.
30.
45.
60.
75.
90.
10*.
120.
135.
150.
IbS.
180.
195.
210.
t25.
240.
2i5.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
450.
465.
460.
495.
510.
525.
540.
555.
570.
CO
PPM
0.0
0.0
0.0
0.0
0.0
0.0
O.C3
0.05
o.ca
C.08
0.12
0.15
0.17
0.17
0.24
C.25
0.29
0.32
0.34
0.39
0.37
0.43
0.46
0.49
C.4b
0.51
0.55
0.56
0.62
0.63
0.67
0.70
0.70
0.72
Ci.75
0.79
0.84
0.62
0.89
PAN
PPM
0.000
U.OOO
c.ooo
******
0.003
******
C.OC5
******
C.007
******
0.011
******
0.015
******
0.019
******
0.022
******
C.028
******
C.030
******
C.036
******
0.041
******
C.048
******
0.053
******
0.057
******
0.060
******
0.067
******
0.068
******
0.070
HCHO
FPM
0.0
******
******
******
0.012
******
******
******
0.121
******
******
******
C.030
******
******
******
0.033
******
******
******
0.039
******
******
******
0.121
******
******
******
******
******
******
******
******
******
******
******
0.078
******
******
ACETALD
PPM
******
******
******
******
0.0337
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0.0424
******
O.C626
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0.0654
******
0.0703
******
0.0729
******
0.0619
******
0.0797
******
0.0816
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0.0777
******
O.C772
******
0.0875
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******
******
0.0715
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0.0857
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0.0829
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O.C893
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0.0762
PROPALO
PPM
0.0002
******
0.0002
******
O.OOC4
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0.0005
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O.GOC9
******
O.OOC9
******
0.0014
******
0.0017
******
0.0017
******
0.0023
******
0.0023
******
0.0026
******
0.0028
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0.0034
******
******
******
0.0034
******
0.0040
******
0.0037
******
0.0047
******
0. 0037
ACETONE
PPM
J.002
******
0.017
******
0.038
******
0.052
******
0.073
******
0.084
******
0.104
******
0.117
******
0.096
******
0.1-.5
******
0.127
******
0.175
******
0.161
******
0.207
******
******
******
0.214
******
0.254
******
0.232
******
0.270
******
0.217
McK
PPM
0.0006
******
0.0050
******
0.0116
******
0.0160
******
0.0224
******
0.0240
******
0.0299
******
0.0337
******
0.0232
******
0.0418
******
0.0330
******
0.0496
******
0.0386
******
******
******
******
******
0.0556
******
0.0716
******
0.0576
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0.0756
******
0.0422
ME-N
PPM
0.0
0.0
0.0001
******
0.0002
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0.0002
******
******
******
******
******
0.0002
******
0.0002
******
0.0003
******
0.0003
******
0.0004
******
0.0003
******
0.0003
******
0.0003
******
0.0003
******
0.0005
******
0.0005
******
0.0005
******
0.0005
******
0.0005
C3-N-2
PPM
PANALYiR
0.0
0.0
0.0004
******
0,0010
******
0.0013
******
0.0016
******
O.OOlb
******
0.0022
******
0.0021
******
0.0023
******
0.0030
******
0.0032
******
0.0033
******
0.0035
******
0.0036
******
0.0040
******
0.0043
******
0.0046
******
0.0046
******
0.0048
******
0. 0046
C4-N-2
PPM
PANALYZR
0.0
0.0
0.0
******
O.OOU
******
0.0016
******
0.0022
******
0.0029
******
G.0029
******
0.0029
******
0.0028
******
0.0037
******
0.0038
******
0.0038
******
0.0038
******
0.0044
******
0.0046
******
0.0048
******
0.0063
******
0.0075
******
0.0069
******
0.0069
-------
EC -246
7-HYDROCAR60N MIX »1
1977 NOV 10
U>
M
LO
CLOCK
TIME
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
15 3u
1545
1600
1615
1630
1645
1700
1715
1730
1745
1800
Iol5
1830
1845
1900
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
1S5.
210.
225.
240.
255.
270.
285.
300.
315.
330.
' 345.
360.
375.
390.
405.
420.
435.
450.
465.
480.
495.
510.
525.
540.
555.
570.
TS
OEG F
64.8
«4.5
84. 8
65.0
85.7
66.0
66.5
66.5
86.7
86.5
87.2
86.7
67.0
86.7
87. U
86.7
86.7
36.5
86.7
87.0
87.0
87.0
87.2
66.7
37.0
86.7
87.2
66.7
87.2
87.0
67.0
66.2
86.7
86.5
86.0
86.2
86.7
86.2
86.2
REL HUM
X
44.5
46.5
49.5
51.0
52.0
52.5
53.0
53.0
53.0
53.0
53.0
53.0
53.5
53.5
53.5
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
54.0
53.5
53.5
53.5
53.5
53.5
53.5
53.5
53.5
53.5
53.5
53.5
53.5
53.5
SSFOwER
KM
16.70
******
18.70
******
******
******
******
******
19.10
******
******
******
19.40
******
******
******
19.50
******
******
*******
19.40
******
******
******
19.70
******
******
******
19.70
******
******
******
19.40
******
******
******
19. CO
******
19.10
RACIOM
Mh/CM2
0.2*5
0.227
0.227
******
C.234
******
******
******
0.227
******
******
******
0.232
0.230
0.227
******
0.239
0.232
0.230
0.227
0.230
******
******
******
0.239
******
******
******
0.239
******
******
******
0.220
******
******
******
0.239
0.234
0.237
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
******
******
******
******
******
******
******
******
******
******
******
20.00
******
******
-------
EC -247
7-HYOROCARBCN MIX #8
1977 NCV U
dEGIN IRRADIATION 0845; 0.25 INCH PYKEX FILTER, TRICHROIC FILTER OUT
PcAc-S ATTRIBUTED TO Co-N-0 uBScRVEC UN PANALY/ER, bUT DATA NOT QUANTIFIABLE
CJ-N-2 INCLUDES SMALL- AKCLNTS OF C2-N
GC-KS DATA INDICATE ThAT C2-N IS LESS THAN C3-N-1 OR C3-N-2
ARCMATICS ANO OXYGENATES MCNITGRtO hITH 3-PART COLUMN
H2C2 MONITORED BY TITANIUM TETRACHLORIDE PROCEDURE
D«SIoI 1212., TECO lit, 3EU.MAN ooOO, BRADY 291 USED
FACTORS: CO 1.6/0.235
T=o AT
PST
HCl-lO
PAN
REL INT
CALIbB
2
9
4
TS DEC K
RE.. HUM t
SSPO^ER Kw
RAUIUM MW/CM2
H20
NO
NJ2-CORR
eTHENE
PRUPENE
N-C4
T2-Ct=
2,3-DMb
TOLUENE
M-XYL
CO
HCMO
ACETALD
ACETCNE
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
IMT
INIT
INIT
INIT
INIT
INIT
INIT
INIT
IMT
IMT
INIT
INIT
INIT
CCND
CLND
CCND
CCND
CLND
CCND
CCND
CCND
CCNC
CCND
CCNC
CCND
CCND
3C3.3
54.30
19.30
C.230
J.275E 04
C. 380
0.12b
1.025
O.C54
C.27J
0.053
o.cao
C.145
0.145
0.4J6
O.C03
O.C01
0.002
ASSIGNtJ INITIAL CCNCITIC-N
-------
EC -247
7-HYDRCCARBGN MIX *8
1977 NCV il
SPECTRAL DISTRIBUTION: hAVELENGTHtNP) REL. INTENSITV
500. 3.024
430. 2.J1S
403. 1.S41
380. 1.610
370. 1.431
360. 1.170
350. l.COO
340. C.7S1
330. 0.531
320. O.Z93
310. O.lli.
300. 0.017
290. 0.001
230. C.C
M=0.30 MIN-1
SAMPLING RATE * 1.6SO L/MIN
41 GC SAMPLES TAKEN
-------
EC -247
7-HYDROCARBON MIX «6
i977 NOV 11
us
CLOCK
TIME
645
900
V 1 5
^ jO
945
1000
1015
1030
1045
1UO
1115
1130
Ht3
1200
1215
12iO
12t5
13 Oj
1315
1330
I34i>
ELAPSED
TCMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
193.
210.
i.f.5*
240.
<:P5.
270.
2 on.
300.
co
PPM
0.44
0.45
0.47
0.47
0.50
0.57
0.62
0.64
C.69
C.74
0.67
0.85
0.92
0.99
1.04
1.10
1.13
1.18
1.25
i.27
1.35
h202
PPM
******
******
O.OOt
******
******
******
******
******
******
******
******
******
******
******
C.020
******
******
******
******
******
******
PAN
PPM
0.000
******
0.002
******
0.016
******
0.036
**#¥**
0.053
******
******
*******
O.CG3
******
0.095
******
J.102
******
0.104
******
0.1J6
HCHO
PPM
0.003
******
******
******
0.141
******
******
******
0.230
******
******
******
0.377
******
******
******
0.276
******
******
******
0.177
ACETALD
PPM
0.001
******
0.031
******
0.054
******
0.072
******
0.070
******
0.068
******
0.063
******
0.064
******
0.066
******
0.057
******
O.OSt
PROPALO
PPM
0.0001
******
0.0000
******
0.0002
******
0.0005
******
0.0007
******
0.0010
******
0.0012
******
0.0011
******
0.0011
******
0.0011
******
0.0011
ACETONE
PPM
0.0021
******
0.0076
******
0.0178
******
0.0484
******
0.0586
******
0.0746
******
0.0o83
******
0.0688
******
0.0836
******
0.0671
******
0.0771
MEK
PPM
0.0001
******
0.0023
******
0.0036
******
0.0080
******
0.0092
******
0.0120
******
O.J130
******
0.0141
******
0.0172
******
0.0156
******
'0.0167
ME-N
PPM
0.0
******
0.0
******
0.0002
******
0.0006
******
0.0006
******
******
******
0.0009
******
0.0009
******
0.0009
******
O.OuOS
******
0.0008
C3-N-2
PPM
PAUALYiR
0.0
******
0.0
******
O.uOOl
******
0.0003
******
O.OOU4
******
******
******
0.0009
******
0.0007
******
O.OOOo
******
0.0009
******
0.0009
C4-N-2
PPM
PANALViR
O.C
******
0.0
******
0.0006
******
O.OOOo
******
C.OuJ9
******
******
******
O.OOil
******
0.0011
******
******
******
******
******
0.0011
-------
tC -247
7-HVDROCARBON MIX #8
1977 NOV 11
U>
1 1
1 — '
•vj
CLCCK
TlMc
645
900
915
930
943
1000
iOl5
1030
1045
11JO
1115
1130
1145
UOO
1215
1230
1243
130u
1313
1330
1345
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
130.
195.
210.
225.
240.
255.
270.
265.
300.
TS
DEC F
83.6
64.5
85.0
85.2
65.7
86.0
86.2
86.5
87.2
87.2
87.0
86.5
87.0
86.7
87.2
b7.2
87.2
87.4
87.0
87.3
87.0
REl HUM
S
46.5
48.0
51.0
53.0
53.5
54.0
34.5
55.0
55.0
55.5
55.5
55.5
55.5
55.3
55.5
55.5
53.5
55.5
55.5
53.5
55.5
SSFOtiER
KM
18.70
******
18.90
******
IV. 20
******
******
******
19.50
******
******
******
19.90
******
******
******
19.50
******
******
******
19.40
RADIOM
Mh/CM2
******
0.232
0.227
0.225
C.230
******
******
******
0.234
******
******
******
0.237
******
******
******
0.244
******
******
******
0.230
HCHQ VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
15.00
H2Q2 VO
PPM
******
******
30.0
******
******
******
******
******
******
******
******
******
******
******
30.0
******
******
******
******
******
******
-------
00
EC -250
FORMALDEHYDE
1977 NOV 16
BEGIN IRRADIATION 1000J 0.25 INCH PYREX FILTERt TRICHROIC FILTER OUT
0842-0652: FLUSH 0.411 TQRR HCHO IN 5.467 L 8UL9 INTO EC THROUGH OtSPERSER TUBE
CALCULATED HCHO INJECTED = 0.540 PPM IN EC.
HCHO WAS FLUSHED INTC THE CHAMBER AFTER THE PURE-AIR FILL.
SOME HCHO PROBABLY TRANSFERRED T3 MAKEUP-AIR BAG
N-C4 AND NEO-C5 ADDED AS TRACERS FOR OH
H202 MONITORED 8Y TITANIUM TETRACHLORIDE PROCEDURE
DASIBI 1212, TECO 14B, BECKMAN 6aOOt 3RAOY 291 USED
FACTORS: CO 1.6/.256
T»0 AT 1000 PST
CALI8*
PAN
HCHO
REL INT
TS
REL HUM
SSPOi»ER
RAD1QM
H20
NO
NQ2-CORR
HCHO
N-C4
NEO-C5
CO
ACETALO
ACETONE
METHANE
ETHANE
6THENE
ACETYLEN
ACETYLtN
PROPANE
OEG K
%
KM
HW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
1
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
INIT CCND
INIT CGND
INIT CONO
INIT CONO
INIT CONO
INIT CCNO
INIT CONO
INIT COND
IMT COND
INIT CQNO
INIT CCNO
INIT CCNO
INIT COND
303.5
51.82
19.60
0.231
2.220E
0.011
0.012
0.328
0.007
O.C08
2.105
0.001
0.002
1.043
0.005
0.003
0.006
0.006
0.007
ASSIGNED INITIAL CONDITION
-------
EC -250
FORMALDEHYDE
19/7 NOV 16
SPECTRAL DISTRIBUTION: WAVELENGTH(NM) REL. INTENSITY
500. 3.177
430. 2.341
403. 2.037
360. 1.630
370. 1.421
360. 1.167
350. 1.000
340. 0.773
330. 0.527
320. 0.238
310. 0.110
300. 0.016
290. 0.001
2SO. 0.0
Kl*0.30 MIN-1
SAMPLING RATE » 1.693 L/MIN
to 30 GC SAMPLES TAKEN
-------
UJ
M
o
EC -Z50
FORMALDEHYDE
1977 NOV 16
CLOCK
TIME
828
935
1000
1015
1030
10*5
1100
1115
1130
11*5
1200
1215
1230
12*5
1300
1315
1330
13*5
1*00
1*15
1*30
1**5
1500
1515
1530
15*5
1600
ELAPSED
TCHIN1
-92.
-25.
0.
15.
30.
*5.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
2*0.
255.
270.
235.
300.
315.
330.
345.
360.
OZONE
PPM
******
******
o.ouo
0.015
0.03*
0.05*
0.071
0.090
0.103
0.117
0.127
0.139
0.1*7
0.156
0.16*
0.169
0.178
0.183
0.183
0.193
0.198
0.198
0.203
0.208
0.208
0.213
0.213
NO
PPM
******
******
o.ou
0.008
o.oo8
0.008
0.008
0.008
O.OL8
C.009
0.008
0.008
0.007
O.OC8
0.007
0.007
C. 009
0.008
O.OC8
O.OC8
0.009
C.008
0.009
0.008
0.008
0.003
0.012
N02-CORR
PPM
******
******
0.012
0.01*
0.015
0.016
0.016
0.017
0.017
0.017
0.018
0.020
0.019
0.021
0.020
0.021
0.019
0.020
0.021
O.U22
0.021
0.021
0.021
0.021
0.022
0.022
0.018
NOX-CORR
PPM
******
******
0.023
0.023
0.023
0.02*
0.02*
0.025
0.025
0.026
0.026
0.028
0.026
0.029
0.027
0.028
0.02
-------
<_J
EC -250
FORMALDEHYDE
1977 NOV 16
CLOCK
TIME
828
935
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
143ii
1445
1500
1515
1530
1545
1600
ELAPSED
TiMINJ
-92.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
130.
195.
210.
225.
240.
255.
270.
285.
, 300.
315.
330.
345.
360.
CO
PPM
******
******
2.11
2.17
2.15
2.20
2.27
2.27
2.35
2. 3d
2.40
2.43
2.47
2.50
2.50
2.52
2.58
2.56
2.58
2.61
2.62
2.69
2.69
2.67.
2.70
2.73
2.73
H202
PPM
******
******
0.0
******
0.0
******
******
******
0.022
******
******
******
0.0
******
******
******
******
0.0
******
******
0.0
******
******
******
c.o
******
******
PAN
PPM
******
******
0.000
******
0.000
******
0.001
******
O.UJ2
******
0.003
******
0.004
******
0.003
******
0.005
******
******
******
0.005
******
0.007
******
0.007
******
0.007
ACETALO
PPM
0.0007
******
0.0010
******
******
******
******
******
******
******
******
******
******
******
0.0045
******
******
******
******
******
******
******
******
******
******
******
0.0060
PROPALD
PPM
0.0001
******
0.0005
******
******
******
******
******
******
******
******
******
******
******
0.0014
******
******
******
******
******
******
******
******
******
******
******
0.0020
ACETONE
PPM
0.0010
******
0.0016
******
******
******
******
******
******
******
******
******
******
******
0.0288
******
******
******
******
******
******
******
******
******
******
******
0.0384
BUTYRAL
PPM
0.0
******
0.0001
******
******
******
******
******
******
*******
******
******
******
******
0.0014
******
******
******
******
******
******
******
******
******
******
******
******
MEK
PPM
0.0001
******
0.0004
******
******
******
******
******
******
******
******
******
******
******
0.0045
******
******
******
******
******
******
******
******
******
******
******
******
PROX
PPM
0.0000
******
0.0
******
******
******
******
******
******
******
******
******
******
******
0.0
******
******
******
******
******
******
******
******
******
******
******
0.0001
METHANE
PPM
1.06
******
1.04
******
******
******
******
******
******
******
******-
******
******
******
1.06
******
******
******
******
******
******
******
******
******
******
******
1.06
ETHANE
PPM
0.0049
******
0.0040
******
******
******
******
******
******
******
******
******
******
******
0.0047
******
******
******
******
******
******
******
******
******
******
******
0.0047
ETHENE
PPM
0.0033
******
0.0032
******
******
******
******
******
******
******
******
******
******
******
0.0021
******
******
******
******
******
******
******
******
******
******
******
0.0015
-------
u>
EC -250
FORMALDEHYDE
1977 NOV 16
CLOCK
TIME
828
935
1000
1015
1030
1045
1103
1115
1130
1145
1204
1215
1230
12<»b
1300
1315
1330
1345
1400
1415
1430
1445
1500
1513
1530
1545
1600
ELAPSEC
T(MIN)
-92.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
ACETYLEN
PPM
(PN>
0.0067
******
0.0064
******
******
******
******
******
******
******
******
******
******
******
0.0059
******
******
******
******
******
******
******
******
******
******
******
0.0058
ACETYLEN
PPM
(OMS)
0.0067
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
PROPANE
PPM
0.0072
******
0.0070
******
******
******
******
******
******
******
******
******
******
******
0.0066
******
******
******
******
******
******
******
******
******
******
******
0.0060
PR3PENE
PPM
0.000
******
0.000
******
******
******
******
******
******
******
******
******
******
******
0.000
******
******
******
******
******
******
******
******
******
******
******
0.000
I-C4
PPM
0.0001
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
0.0001
-------
U)
to
EC -250
FORMALDEHYDE
19TT NOV 16
CLOCK
TIH£
828
935
1000
1015
1030
10 45
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1530
1515
1530
1545
1600
ELAPSED
T(HIN)
-92.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEO F
******
******
84.5
84.5
85.0
85.2
85.7
86.5
66.5
86.7
87.0
86.7
87.0
87.2
87.2
87.7
87.4
87.2
87.4
»7.7
87.4
87.7
87.4
87.4
87.7
87.2
87.9
REL HUM
*
******
******
45.5
47.5
50. 0
51.5
52.5
53.0
53.0
53.0
53.5
53.5
53.0
53.5
53.5
53.5
53.0
53.5
53.0
53.0
53.0
53.0
53.0
53.0
53.0
53.0
53.0
SSPQWER
KM
******
******
19.14
******
******
******
19.23
******
******
******
20.02
******
******
******
19.54
******
******
******
19.49
******
******
******
19.54
******
******
******
20.25
RAOIQM
HW/CM2
******
******
0.230
0.230
0.232
0.227
0.225
******
******
******
0.234
******
******
******
0.227
******
******
******
0.230
******
******
******
0.232
0.232
******
******
0.232
HCHO VOL
L
******
******
10.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
H202 VOL
PPH
******
******
30.0
******
30.0
******
******
****v*
30.0
******
******
******
30.0
******
******
******
******
20.0
******
******
30.0
******
******
******
30.0
******
******
-------
EC -250
FORMALDEHYDE
1977 NOV 16
CLOCK
TIME
828
935
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
ELAPSED
T(MIN)
-92.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
N02
PPM
******
******
0.012
0.014
0.015
0.017
0.018
0.019
0.019
0.020
0.021
0.024
0.023
0.025
0.023
0.024
0.023
0.025
0.026
0.027
0.026
0.027
0.026
0.026
0.029
0.029
0.026
NOX
PPM
******
******
0.023
0.023
0.024
0.025
0.026
C. 027
0.027
0.028
0.029
0.031
0.330
0.033
0.031
0.032
0.032
0.033
0.033
0.034
0.034
0.036
0.037
0.036
0.037
0.037
0.038
TOT N03
PPM
******
******
0.000
0.000
0.000
0.001
0.001
0.002
0.002
0.002
0.003
0.003
O.C04
O.U03
0.003
O.C04
0.005
0.005
0.005
0.005
0.005
0.006
0.007
O.C07
0.007
0.007
0.007
TOT N
PPM
******
******
0.023
0.023
0.024
0.025
0.026
0.027
0.027
0.028
0.029
0.032
0.030
0.033
0.031
0.032
0.032
0.033
0.034
0.034
0.034
0.036
0.037
0.036
0.037
0.037
0.038
H20
PPM
******
******
18157.
18955.
20266.
21039.
21785.
22512.
22512.
22687.
23080.
22901.
22864.
23260.
23260.
23623.
23222.
23260.
23222.
23402.
23222.
23402.
23222.
23222.
23402.
23042.
23534.
HCTOT
PPMC
0.378
0.419
0.420
******
******
******
******
******
******
******
******
******
******
******
C.260
******
******
******
******
******
******
******
******
******
******
******
0.259
-------
EC -251
FORMALDEHVOE * NOX
1977-NOV 17
BEGIN IRRADIATION 1000; 0.25 INCH PYREX FILTER, TRICHROIC FILTER OUT
0620-0835: FLUSH 0.417 TORR HCHO IN 5.467 L BULB INTO EC THROUGH OISPERSER TUBE
CALCULATED HCHO INJECTED * 0.550 PPM IN EC
HCHO WAS FLUSHED INTO THE CHAMBER AFTER THE PURE AIR FILL.
ABOUT 130 PPB HCHO OBSERVED IN MAKEUP-AIR BAG
N-C4 AND NEQ-C5 ADDED AS TRACERS FOR OH
H202 MONITORED BY TITANIUM TETRACHLORIDE PROCEDURE
DAS If) I 1212, TECO 14B, BECKMAN 6800, 3RADV 291 USED
FACTORS: CO 1.6/.277
T*0 AT 1000 PST
fO
t_n
CALI8*
PAN
HCHO
REL INT
TS
REL HUM
SSPJhER
RAOIOM
H2Q
NO
N02-CCRR
HCHO
N-C4..
NEO-C5
CO
ACETALO
ACETONE
MEK
METHANE
ETHANE
ETHENE
PROPANE
OEG K
*
KV.
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
1
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CONO
INIT COND
INIT CCND
INIT CONO
INIT CCND
INIT CQNO
INIT CCND
INIT CCND
INIT COND
INIT CCND
INIT COND
INIT COND
INIT CGND
303.4
52.07
19.79
0.229
2.230E
0.080
0.033
0.193
0.006
O.C.08
1.491
0.001
0.002
0.001
1.C75
0.004
0.003
0.007
04
ASSIGNED INITIAL CONDITION
-------
GJ
EC -251
FORMALDEHYDE + NOX
1977 NOV 17
CLOCK
TIME
930
looo
1015
1030
1045
UOO
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
13*5
14JO
1415
1430
1445
1500
1515
1530
1545
1600
ELAPSED
T(HIN)
-30.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC ^
******
85.7
86.0
85.2
85.2
85.7
86.2
87.0
87.2
87.7
87.7
87.4
87.2
87.4
87.4
37.2
87.2
87.4
87.4
«7.2
87.4
67.2
87.2
87.9
87.2
87.7
REL HUH
*
******
44.0
45.5
48.5
50.5
52.0
53.0
53.5
53.5
54.0
54.0
54.0
54.0
54.0
54.5
54.5
54.5
54.5
54.5
54.0
54.0
54.0
54.0
54.0
54.0
54.0
SSPONER
KM
******
19.35
******
******
******
19.71
******
******
******
19.76
******
******
******
20.02
******
******
******
19.98
******
******
******
19.58
******
******
******
20.11
RAOIOH
MW/CM2
******
0.203
0.230
0.225
0.225
0.230
******
******
******
0.230
******
******
******
0.232
******
******
******
0.232
******
******
******
0.227
******
******
******
0.237
HCHQ VOL
L
******
10.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
H202 VOL
PPM
******
30.0
******
30.0
******
*.$****
******
30.0
******
******
******
30.0
******
******
**««**
30.0
******
******
******
30.0
******
******
******
30.0
******
******
-------
EC -251
FORMALDEHYDE » NOX
1977 NOV 17
OJ
CLOCK
TIME
930
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
12 30
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
ELAPSED
TCMINJ
-30.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
235.
300.
315.
330.
345.
360.
PROPANE
PPM
******
0.0065
******
******
******
******
******
******
******
******
******
******
******
0.0058
******
******
******
******
******
******
******
******
******
******
******
******
PHOPENE
PPM
******
0.000
******
******
******
******
******
******
******
******
******
******
******
c.ooo
******
******
******
******
******
******
******
******
******
******
******
******
I-C4
PPM
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
O.OC01
******
******
******
******
******
******
******
******
******
******
******
******
-------
EC -251
FORMALDEHYDE + NOX
1977 NOV 17
CLOCK
TIME
930
1000
1015
1030
1045
110J
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
U> 1415
?« 1430
1445
1500
1515
1530
1545
1600
ELAPSED
T(MIN)
-30.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
CO
PPM
******
1.49
1.50
1.60
1.66
1.70
1.72
1.76
1.80
1.83
t.d7
1.87
1.90
1.91
1.94
1.98
1.97
2.01
2.04
2.04
2.04
2.04
2.07
2.10
2.13
2.13
H202
PPM
******
0.0
******
0.003
******
******
******
0.013
******
******
******
0.012
******
******
******
0.007
******
******
******
0.012
******
******
******
0.010
******
******
PAN
PPM
******
0.000
******
0.001
******
0.002
******
0.002
******
0.004
******
******
******
O.OC6
******
0.006
******
O.OC7
******
0.008
******
0.008
******
0.009
******
0.009
ACETALD
PPM
******
0.0012
******
******
******
******
******
******
******
******
******
******
******
0.0049
******
******
******
******
******
******
******
******
******
******
******
0.0053
PROPALD
PPM
******
0.0004
******
******
******
******
******
******
******
******
******
******
******
0.0023
******
******
******
******
******
******
******
******
******
******
******
0.0020
ACETONE
PPM
******
0.0023
******
******
******
******
******
******
******
******
******
******
******
0.0367
******
******
******
******
******
******
******
******
******
******
******
0.0375
BUTYRAL
PPM
******
O.OOJ1
******
******.
******
******
******
******
******
*******
******
******
******
0.0011
******
******
******
******
******
******
******
******
******
******
******
0.0011
MEK
PPM
******
0.0005
******
******
******
******
******
******
******
******
******
******
******
0.0011
******
******
******
******
******
******
******
******
******
******
******
0.0016
PROX
PPM
******
0.0
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
METHANE
PPM
******
1.07
******
******
******
******
******
******
******
******
******
******
******
1.08
******
******
******
******
******
******
******
******
******
******
******
1.06
ETHANE
PPM
******
0.0045
******
******
******
******
******
******
******
******
******
******
******
0.0043
******
******
******
******
******
******
******
******
******
******
******
0.0044
ETHENE
PPM
******
0.0030
******
******
******
******
******
******
******
******
******
******
******
0.0015
******
**** **
******
******
******
******
******
******
******
******
***** V
0.0011
ACtTYLEN
^PH
I OH SI
******
******
******
******
******
******
******
******
******
*** * **
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
-------
ec -zsi
FORMAL OEHVOE » NOX
1977 NOV 17
CLOCK
TIME
930
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
14
-------
OJ
O
EC -251
FORMALDEHYDE » NOX
1977 NOV 17
SPECTRAL DISTRIBUTION: hAVELENGTHt NH) REL. INTENSITY
500. 3.240
430. 2.372
403. 1.989
380. 1.648
370. 1.417
360. 1.171
350. 1.000
340. 0.772
330. 0.530
320. 0.288
310. 0.110
300. 0.016
290. 0.001
200. 0.0
K 1-0. 30 MIN-1
SAMPLING RATE = 1.694 L/MJN
31 GC SAMPLES TAKEN
-------
EC -251
FORMAL DEHYDE + NOX
1977 NOV 17
CLOCK
TIME
930
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
OJ 1415
OJ 1430
I-1 1445
1500
1515
1530
1545
1600
ELAPSED
T(MIN)
-30.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
N02
PPM
******
0.033
0.068
0.078
0.074
0.071
0.067
0.061
0.060
0.056
0.053
0.050
0.048
0.045
0.043
0.042
0.042
0.040
0.038
0.038
0.038
0.038
0.037
0.036
0.034
0.035
NOX
PPM
******
0.113
0.104
0.098
C.089
C.084
0.079
0.072
0.069
0.066
0.062
C.058
0.056
C.053
0.051
0.050
0.048
0.048
C.046
0.045
0.045
0.046
0.045
0.044
0.043
C.043
TOT N03
PPM
******
0.000
0.001
0.001
0.001
0.002
0.002
0.002
0.003
0.004
0.004
0.005
0.005
0.006
0.006
o.ooa
0.006
0.007
0.007
0.008
0.008
0.008
0.009
0.009
J.009
0.009
TOT N
PPM
******
0.113
0.104
0.098
0.090
0.084
0.079
0.073
0.069
0.066
0.062
0.059
0.056
0.053
0.051
0.050
0.050
0.048
0.046
0.046
0.046
0.046
0.045
0.044
0.044
0.043
H20
PPM
******
18258.
19028.
19813.
20631.
21577.
22338.
23080.
23260.
23844.
23844.
23660.
23477.
2366C.
23879.
23694.
23694.
23879.
23879.
23477.
23660.
23477.
23477.
24029.
23477.
23844.
HCTOT
PPMC
0.2BJ
0.283
******
******
******
******
******
******
******
******
******
******
******
0.244
******
******
******
******
******
******
******
******
******
******
******
0.231
-------
Co
CO
EC -252
FORMALDEHYDE +
1977 NOV 18
NOX
BEGIN IRRADIATION 0945, 0.25 INCH PYREX FILTER, TRICHROIC FILTER OUT
0817: 0.428 TORR HCHO IN 5.467 L BULB EXPANDED INTO EC THROUGH DISPERSES TUBE
CALCULATED HCHO INJECTED = 0.564 PPM IN EC
N-C4 AND NEO-C5 ADDED AS TRACERS FOR OH
H202 MONITORED BY TITANIUM TETRACHLORIDE PROCEDURE
PAN LESS THAN 1 PPB AT 1545
DASidI 1212, TECO 14B, 6ECKMAN 6800, BRADY 291 USED
FACTOR: co 1.6/.277
T«0 AT 945 PST
CALI8*
PAN
HCHO
REL INT
TS
REL HUH
SSPOWER
RAD10M
H20
NO
N02-CORR
HCHO
N-C4
NEO-C5
CO
ACETALO
ACETONE
METHANE
ETHANE
ETHENE
ACETYLEN
ACETYLEN
PROPANE
DEG K
*
KM
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
1
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CONO
INIT CCNO
INIT COSO
INIT CCNO
INIT CCND
INIT CCND
INIT CCND
INIT CONO
INIT CCND
INIT CONO
INIT CCND
INIT CCND
INIT CCNO
INIT CCND
303.6
50.24
20.18
0.229
2.181E 04
0.392
0.103
0.359
0.006
0.008
0.756
0.001
0.002
1.190
0.005
0.003
0.005
0.005
0.006
ASSIGNED INITIAL CONDITION
-------
U)
u>
u>
EC -252
FORMALDEHYDE + NOX
1977 NOV 18
SPECTRAL DISTRIBUTION: HAVELENGTHCNM) REL. INTENSITY
500. 3.209
430. 2.379
403. 1.983
380. 1.6*7
370. 1.413
360. 1.170
350. 1.000
340. 0.779
330. 0.527
320. 0.290
310. 0.111
300. 0.016
290. 0.001
280. 0.0
KU0.30 HIN-1
SAKPUNG RATE = 1.693 L/MIN
30 GC SAMPLES TAKEN
-------
UO
OJ
EC -252
FORMAL DEHyoe + NOX
1977 NOV 18
CLOCK
TIME
845
935
9*5
1000
1015
1030
104*
lioo
1115
1130
1145
12JO
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
T(HIN)
-60.
-10.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
******
******
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.000
0.002
0.002
0.007
0.010
0.010
0.010
0.012
0.015
0.015
0.020
0.017
0.020
0.017
0.022
0.022
0.020
0.024
NO
PPM
******
******
C.392
0.352
0.327
0.292
0.265
0.238
0.221
C.205
0.188
0.178
0.167
0.158
0.149
0.142
C.133
0.127
0.122
0.117
0.110
C.107
0.103
0.099
0.096
0.093
C.090
N02-CORR
PPM
******
******
0.103
0.133
0.150
0.176
0.192
0.209
0.213
0.219
0.225
0.228
0.231
0.232
0.231
0.230
0.231
0.232
0.230
0.226
0.227
0.222
0.221
0.220
0.216
0.215
0.213
NOX-CORR
PPM
******
******
0.493
0.485
0.479
0.468
0.456
0.445
0.432
0.423
0.413
0.405
0.39d
0.388
0.360
0.370
0.364
0.358
0.349
0.342
0.336
0.330
0.322
0.318
0.313
0.305
0.302
HCHO
PPM
******
******
0.359
******
******
******
0.286
******
******
******
0.121
******
******
******
0.141
******
******
******
0.103
******
******
******
0.099
******
******
******
0.084
N-C4
PPM
.00004
.00585
.00615
******
******
******
******
******
******
******
******
******
******
******
.00499
******
******
******
******
******
******
******
******
******
******
******
.00443
NEO-C5
PPM
******
.00718
.00753
******
******
******
******
******
******
******
******
******
******
******
.00669
******
******
******
******
******
******
******
******
******
******
******
.00616
-------
EC -252
FORMALDEHYDE * NOX
1977 NOV 18
CLOCK
TIME
845
935
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
133J
W 1345
LO 1400
01 1415
1430
1445
1500
1515
1530
1545
ELAPSED
TIMIN)
-60.
-10.
0,
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
255.
300.
315.
330.
345.
360.
CO
PPM
******
******
0.76
0.80
0.81
0.87
0.8B
0.94
0.97
1.00
1.04
1.07
1.11
1.12
1.14
1.17
1.19
1.22
1.21
1.22
1.29
1.29
1.29
1.31
1.35
1.38
1.38
H202
PPM
******
******
0.0
******
0.0
******
******
******
0.0
******
******
******
0.0
******
******
******
0.0
******
******
******
0.0
******
******
******
0.0
******
******
ACETALD
PPM
0.0007
******
O.C012
******
******
******
******
******
******
******
******
******
******
******
0.0u30
******
******
******
******
******
******
******
******
******
******
******
0.0050
PROPALO
PPM
0.0001
******
0.0003
******
******
******
******
******
******
******
******
******
******
******
0.0006
******
******
******
******
******
******
******
******
******
******
******
0.0009
ACETONE
PPM
0.0008
******
0.0015
******
******
******
******
******
******
******
******
******
******
******
0.0056
******
******
******
******
******
******
******
******
******
******
******
0.0098
BUTYRAL
PPM
0.0000
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
0.0002
******
******
******
******
******
******
******
******
******
******
******
0.0004
ME ft
PPM
0.0002
******
0.0002
******
******
******
******
******
******
******
******
******
******
******
0.0020
******
******
******
******
******
******
******
******
******
******
******
0.0018
PROX
PPM
******
******
0.0000
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0001
METHANE
PPM
1.21
******
1.19
******
******
******
******
******
******
******
******
******
******
******
1.21
******
******
******
******
******
******
******
******
******
******
******
1.19
ETHANE
PPM
0.0048
******
0.0050
******
******
******
******
******
******
******
******
******
******
******
0.0048
******
******
******
******
******
******
******
******
******
******
******
0.0049
ETHENE
PPM
0.0030
******
0.0029
******
******
******
******
******
******
******
******
******
******
******
0.0020
******
******
******
******
******
******
******
******
******
******
******
0.0020
ACETYLEN
PPM
IPNI
0.0050
******
0.0046
******
******
******
******
******
******
******
******
******
******
******
0.0046
******
******
******
******
******
******
******
******
******
******
******
0.0047
ACETYLEN
PPM
(OMSI
0.0043
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
**¥***
******
******
******
******
-------
EC -252
FORMALOEHYDE + NOX
197/ NOV 18
u>
CLOCK
TIME
84*5
935
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
14uO
1415
1430
1445
1500
1515
1530
1545
ELAPSED
TCHIN)
-60.
-10.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
130.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
PROPANE
PPM
0.0060
******
0.0060
******
******
******
******
******
******
******
******
******
******
******
0.0054
******
******
******
******
******
******
******
******
******
******
******
0.0055
PROPENE
PPM
C.OCO
******
0.000
******
******
******
******
******
******
******
******
******
******
******
0.000
******
******
******
******
******
******
******
******
******
******
******
c.ooo
I-C4
PPM
0.0001
******
0.0000
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
0.0000
-------
u>
EC -252
FORMALDEHYDE * NOX
1977 NOV 18
CLOCK
TIME
845
935
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
T(MIN)
-60.
-10.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC F
******
******
84.3
85.2
85.2
85.5
86.2
86.5
87.0
86.7
87.2
87.2
87.4
87.9
87.7
87.4
87.9
87.4
87.7
88.4
87.9
87.9
87.7
87.9
88.2
88.2
88.2
REL HUM
%
******
******
45.0
47.0
49.5
51.0
52.0
52.5
52.5
52.5
52.5
52.5
52.5
52.5
52.5
52.5
52.0
52.5
52.5
52.5
52.0
52.5
52.0
52.0
52.0
52.0
52.0
SSPOMER
KM
******
******
20.23
******
******
******
IS. 84
******
******
******
19. ao
******
******
******
20.16
******
******
******
20.02
******
******
******
20.48
******
******
******
20.70
RAOIOM
MH/CM2
******
******
0.217
0.234
0.232
0.227
0.225
******
******
******
0.227
******
******
******
0.234
0.227
******
******
0.227
******
******
******
0.237
0.227
******
******
******
HCHO VOL
L
******
******
10.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
H202 VOL
PPM
******
******
30.0
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
-------
Oo
00
EC -252
FORMALDEHYDE * NOX
1977 NOV 18
CLOCK
TIME
B*5
935
9*5
1000
1015
1030
10*5
1100
1115
1130
11*5
1200
1215
1230
12*5
130J
1315
1330
13*5
1*00
1*15
1*30
1**5
1500
1515
1530
15*5
ELAPSED
T(MiNI
-60.
-10.
0.
15.
30.
*5.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
2*0.
255.
270.
285.
300.
315.
330.
3*5.
360.
N02
PPM
******
******
0.103
0.133
0.150
0.176
0.192
0.209
0.213
0.219
0.225
0.228
0.231
0.232
0.231
0.230
0.231
0.232
0.230
0.226
0.227
0.222
0.221
0.220
0.216
0.215
0.213
NOX
PPM
******
******
0.*93
0.485
0.*79
0.
-------
U)
EC -253
ACETALOEHYDE
1977 NOV 21
BEGIN IRRADIATION 0930; 0.25 INCH PYREX FILTER, TRICHROIC FILTER OUT
0800: 0.392 TORR ACETALCEHYDE IN 5.467 L BULB EXPANDED INTO EC
THROUGH DISPERSER TUBE
CALCULATED ACETALDEHYDE INJECTED « 0.517 PPM IN EC
N-C4 AND NEO-C5 ADDED AS TRACERS FOR CH
H202 MONITORED BY TITANIUM TETRACHLORIDE PROCEDURE
DAStdl 1212, TECO 14B, BECKMAN 6800, BRADY 291 USED
FACTORS: CO 1.6/.277
T*0 AT 930 PST
PAN
HCHO
REL INT
TS DEG K
REL HUN *
SSPOJ.5R KM
RAUIOM MM/CM2
H20 PPM
NO PPM
N02-CCRR PPM
ACETALD PPM
N-C4 PPM
NEO-C5 PPM
CO PPM
* ASSIGNED
CALIB*
9
1
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT COND
INIT CCND
INIT CQND
INIT CCND
INIT CONO
INITIAL CONDITION
303.4
52.68
20.52
0.230
2.253E 04
0.011
0.009
0.546
0.006
0.008
2.110
SPECTRAL DISTRIBUTION: hAVELENGTH(NW) REL.
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
INTENSITY
3.200
2.387
1.993
1.650
1.429
1.165
1.000
0.776
0.527
0.285
0.109
0.016
0.000
0.0
Kl'0.30 MIN-1
SAMPLING RATE »
40 GC SAMPLES TAKEN
1.839 L/MIN
-------
EC -253
ACETALDEhYDE
1977 NOV 21
CLOCK
TIME
930
945
1001)
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
IttO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.000
0. J02
0.007
0.012
0.020
0.022
0.029
0.037
0.042
0.049
0.054
0.061
0.066
0.071
0.078
0.083
0.088
0.095
0.100
0.105
0.110
0.117
0.122
0.130
0.134
NO
PPM
0.011
O.OC9
0.009
C.009
0.012
O.OC9
0.011
0.009
0.009
0.009
0.008
0.008
C.OC8
0.008
0.008
0.013
0.003
0.008
0.007
O.OC7
0.007
0.007
0.007
0.008
0.007
N02-CORR
PPM
0.009
0.009
0.008
0.006
0.003
0.006
0.003
0.005
0.003
0.004
0.005
0.004
0.003
0.002
0.003
0.003
O.OJ4
0.004
0.006
O.OC5
0.004
O.G05
0.006
0.004
0.004
NOX-CORR
PPM
0.020
0.019
0.017
0.015
0.015
0.014
0.014
0.013
O.J13
0.013
0.013
0.012
0.011
0.012
0.011
0.016
0.012
0.012
0.013
0.012
0.012
0.012
0.013
0.012
0.012
ACETALO
PPM
0.546
******
******
******
0.535
******
0.530
******
0.449
******
******
******
0.363
******
0.478
******
0.415
******
0.333
******
0.334
******
0.307
******
0.299
N-C4
PPM
.00638
******
.00624
******
.00603
******
.00602
******
.00602
******
.00592
******
.00579
******
.00567
******
.00569
******
.00547
******
.00550
******
.00537
******
.00531
NEO-C5
PPM
.00766
******
.00747
******
.00724
******
.00729
******
.00721
******
.00715
******
.00704
******
.00696
******
.00696
******
.00670
******
.00677
******
.00668
******
.00642
CO
PPM
2.11
2.11
2.14
2.14
2.14
2.15
2.17
2.18
2.19
2.19
2.21
2.24
2.24
2.26
2.28
2.28
2.31
2.34
2.32
2.34
2.36
2.39
2.39
2.39
2.39
H202
PPM
******
0.0
******
******
******
******
******
******
******
******
0.003
******
******
******
0.007
******
******
******
0.007
******
******
******
0.004
******
******
PAN
PPM
0.000
******
0.006
******
0.011
******
0.015
******
0.018
******
0.021
******
0.026
******
0.028
******
0.030
******
0.031
******
0.035
******
0.036
******
0.040
HCHO
PPM
0.0
******
******
******
0.020
******
******
******
0.025
******
******
******
0.036
******
******
******
0.040
******
******
******
0.043
******
******
******
0.052
-------
EC -253
ACETALCEHYOE
1977 NOV 21
CLOCK ELAPSED
TINE T(HIN)
930 0.
945 15.
1000 30.
1015 45.
1030 60.
1045 75.
1100 90.
1115 105.
1130 120.
1145 135.
1200 150.
1215 165.
123J 180.
1245 195.
1300 210.
1315 225.
1330 240.
1345 255.
1400 270.
1415 285.
1430 300.
1445 315.
1500 330.
1515 345.
1530 360.
TS
DEC F
84.0
84.5
S4.5
85.0
85.7
86.0
86.5
66.5
87.0
87.0
87.2
87.2
87.2
87.4
87.2
87.2
87.4
87.4
87.4
87.2
87.7
88.2
87.9
87.9
88.2
REL HUH
45.5
47.5
50.0
52.0
53.0
53.5
53.5
54.0
54.0
54.0
54.0
54.0
54.0
54.5
54.5
54.0
54.5
54.5
54.5
54.5
54.5
54.0
54.0
54.0
54.0
SSPOWER
KW
20.18
******
******
19.71
******
******
20.70
******
******
******
20.48
******
******
******
20.34
******
******
20.55
20.98
******
******
******
21.25
RAOIOM
0.225
0.234
0.227
******
0.222
******
******
******
0.230
******
******
******
0.230
******
******
******
0.230
0.227
0.227
0.220
0.234
******
******
******
0.242
HCHO VOL H202 VOL
L PPM
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
30.0
******
******
******
******
******
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
-------
OJ
EC -253
ACETALDEHYDE
1977 NOV 21
CLOCK
TIME
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
TtHIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
N02
PPH
0.009
0.012
0.014
0.015
0.014
0.018
0.018
0.021
0.021
0.024
0.026
0.027
0.028
0.028
0.031
0.032
0.034
0.035
0.037
0.038
0.040
0.041
0.042
0.042
0.044
NOX
PPM
0.021
0.022
0.023
• 0.024
0.026
0.027
0.029
0.030
0.031
0.033
0.034
0.035
0.037
0.039
C. 039
0.045
0.042
C.043
0.044
0.045
0.047
0.048
0.048
0.050
0.051
TOT N03
PPM
0.000
0.003
O.C06
0.008
0.011
0.013
0.015
0.017
0.018
0.020
0.021
0.024
0.026
0.027
0.028
0.029
0.030
0.031
0.031
0.033
O.OJ5
0.035
0.036
0.038
0.040
TOT N
PPM
0.021
0.022
0.023
0.024
0.026
0.027
0.029
0.030
0.030
0.033
0.034
0.035
0.037
0.037
0.039
0.045
0.042
0.043
0.044
0.045
0.046
0.048
0.048
0.050
0.051
H20
PPM
17875.
18955.
19953.
21076.
21992.
22374.
22724.
22937.
23296.
23296.
23477.
23477.
23477.
23879.
23694.
23477.
23879.
23879.
23879.
23694.
24065.
24215.
24029.
24029.
2421 5.
HCTOT
PPMC
1.156
******
1.166
******
1.173
******
1.174
******
1.022
******
0.947
******
0.875
******
1.110
******
0.989
******
0.827
******
0.840
******
0.789
******
0.783
-------
EC -254
ACET4LOEHYOE
1977 NOV 22
NOX
BEGIN IRRADIATION 09305 0.25 INCH PYRE* FILTER, TRICHROIC FILTER OUT
OdOO: 0.385 TORR ACETALCEHYDE IN 5.467 L BULB EXPANDED INTO THE EC
CALCULATED ACETALDEHYOE INJECTHO = 0.508 PPM.
ASSUMED TO BE INITIAL CONCENTRATION
N-C4 AND MEQ-C5 ADDED AS TRACERS f 3* 3H
H202 MONITORED BY TITANIUM TETRACHLO*IDE PROCEDURE
DASIiil 1212. TECO 14B, BECKMAN 6300 BRADY 291 USED
FACTORS: co 1.6/.277
T*0 AT 930 PST
PAN
HCHC
REL INT
CALIB*
9
1
4
TS
REL HUM
SSP?dEK
RADIUM
H20
NO
I02-COR3
ACETALO
N-C4
NEO-C5
C3
HCHC
DEG K
I
KM
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVFRAGE
AVERAGE
AVERAGE
INIT CCNO
INIT CCNO
INIT CCNO
INIT CCNO
INIT COND
INIT CONO
INIT CCND
303.7
47.93
20.28
0.230
2.C82E
0.085
0.027
0.506
0.007
0.007
2.701
0.012
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: WAVELENGTHt NMI
500.
430.
403.
330.
370.
360.
350.
340.
330.
320.
310.
300.
290.
260.
Kl'0.30 MIN-1
SAMPLING RATE - 1.839 L/MIN
40 GC SAMPLES TAKEN
REL.
INTENSITY
3.239
2.363
990
645
430
162
000
768
0.519
0.286
0.108
0.016
0.001
0.0
-------
U>
*~
.p-
EC -254
ACETALDEHYDE » NOX
1977 NOV 22
CLOCK
TIME
93J
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1330
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
TIMINI
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
2S5.
300.
315.
330.
345.
360.
OZONE
PPM
0.000
0.005
0.020
0.029
0.039
0.051
0.066
0.08L
0.093
0.105
0.120
0.130
0.144
0.156
0.166
0.178
0.191
0.200
0.210
0.220
0.232
0.239
0.247
0.254
0.264
NO
PPM
O.OB5
0.054
0.041
0.030
0.024
0.021
0.013
0.016
0.014
0.013
0.012
0.010
0.011
O.OU9
J.009
0.003
0.008
0.008
0.008
0. 008
O.OOS
0.007
0.007
0.006
0.006
N02-CORR
PPM
0.027
0.053
0.058
0.064
O.C6U
0.066
0.065
0.065
0.065
0.061
0.059
0.053
0.047
0.045
0.041
O.C38
0.034
0.032
0.028
0.025
0.023
0.022
0.020
0.021
0.021
NOX-CORR
PPM
0.112
0.104
0.098
0.093
0.092
0.087
0.082
0.079
0.078
0.073
0.070
0.062
0.058
0.054
0.050
0.046
0.042
0.039
0.035
0.032
0.030
0.028
0.026
0.027
0.027
ACETALD
PPM
0.472
******
0.504
******
0.407
******
0.46S
******
0.346
******
0.388
******
0.290
******
0.322
******
0.263
******
0.245
******
0.235
******
0.215
******
0.233
N-C4
PPM
.00668
******
.00658
******
.00644
******
.00649
******
.00632
******
.00632
******
.00615
******
.00609
******
.00599
******
.00579
******
.00570
******
.00559
******
.00547
NEO-C5
PPM
.00733
******
.00744
******
.00730
******
.00719
******
.00719.
******
.00694
******
.00683
******
.00703
******
.00673
******
.00661
******
.00657
******
.00658
******
.00630
CO
PPM
2.70
2.66
2.64
2.47
2.69
2.67
2.70
2.70
2.71
2.74
2.76
2.76
2.77
2.79
2.80
2.83
2.83
2.86
2.87
2.88
2. 87
2.90
2.90
2.91
2.95
H202
PPM
******
0.0
******
******
******
******
0.003
******
******
******
0.001
******
******
******
O.OOt
******
******
******
0.008
******
******
******
0.004
******
******
PAN
PPM
0.000
******
0.008
******
0.015
******
0.023
******
0.026
******
0.035
**v*v*
0.045
****¥*
0.051
******
0.053
******
0.004
******
0.068
******
0.071
******
0.070
HCHO
PPM
0.012
******
******
******
0.006
******
******
******
0.008
******
******
******
0.022
******
******
******
0.019
******
******
******
0.026
******
******
******
0.037
-------
CO
.p-
EC -254
ACETALDEHVDE + NOX
1977 NOV 22
CLOCK
TIME
930
94i>
1000
1015
1030
1045
HOO
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
T(HIM)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
; 330.
345.
360.
TS
DEC F
83.0
85.2
85.5
85.5
67.0
87.2
87.7
87.9
88.2
88.2
B8.4
83.2
88.7
88.4
88.7
88. 7
88.7
88.4
88.4
88.2
88.7
87.9
88. 4
88.2
B6.2
«EL HUM
%
42.0
43.5
45.5
47.0
40.0
48.0
48.5
46.5
48.5
48.5
48.5
48.5
48.5
48.5
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.5
SSP0WER
KV
19.57
******
19.81)
******
20.02
20,33
******
******
20.66
******
******
******
20.98
******
******
******
20.20
******
******
******
20.48
******
******
******
20.48
RAQIOM
Mh/CM2
0.234
0.227
0.227
******
0.230
0.232
******
******
0.239
******
******
******
0.230
******
******
******
0.232
******
0.234
******
0.230
******
******
******
0.230
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
H202 VOL
PPM
******
30.0
******
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
-------
U>
-t-
EC -255
FORMALDEHYDE
1977 NOV 23
BEGIN IRRADIATION 09CO; 0.25 INCH PVREX FILTER, TRICHROIC FILTER OUT
0731: 0.387 TORR HCHO IN 5.467 L BUL8 EXPANDED INTO THE EC
CALCULATED FORMALDEHYDE INJECTED = C.510 PPM IN EC
N-C4 ANO NEO-C5 ADDED AS TRACERS FOR OH
H202 MONITORED BY TITANIUM TETRACHLORIDfc PROCEDURE
OAS1BI 1212, TECO 14B, BECKHAN 6800, BRADY 291 USED
CO FACTORS: 1.6/.273
T«0 AT 900 PST
CALIB*
PAN
HCHO
REL INT
TS
REL HJM
SSPOWER
RAOICM
H20
NO
N02-CORR
HCHO
N-C4
NEQ-C5
CO
ACETALD
ACETONE
MEK
METHANE
ETHANE
ETHENS
ACETYLEN
ACETYLEN
PROPANE
DEC K
%
KM
MU/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
1
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CGND
INIT CCNO
INIT COND
INIT CCNO
INIT CCND
INIT CCNO
INIT COND
INIT CCND
INIT CCNO
INIT COND
INIT COND
INIT CCNO
INIT CCNO
INIT CCNO
303. 5
44.61
20.55
0.229
1.955E 04
C.006
0.010
0.330
0.007
C.C07
2.202
0.001
0.001
0.001
1.223
0.005
O.OOS
0.008
0.008
0.005
ASSIGNED INITIAL CONDITION
-------
EC -255
FORMALDEHYDE
1977 NOV 23
SPECTRAL DISTRIBUTION! NAVELENGTH»N»» REL. INTENSITY
500. 3.284
430. 2.421
403. 2.012
380. 1.666
370. 1.445
360. 1.190
350. 1.000
340. 0.7T3
330. 0.525
320. 0.286
310. 0.109
300. 0.016
290. 0.001
280. 0.0
K.U0.30 MIN-l
SAMPLING RATE * 1.693 L/HIN
30 GC SAMPLES TAKEN
-------
oo
EC -255
FORMALDEHYDE
1977 NOV 23
CLOCK
TIME
752
840
900
915
930
9*5
1000
1015
1030
10t5
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
T(HIN)
-68.
-20.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
iao.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
******
******
0.000
0.010
0.022
0.039
0.056
0.071
0.086
0.095
0.108
0.120
0.130
0.137
0.147
0. 156
O.lt>4
0.169
0.176
0.178
0.183
0.186
0.193
0.193
0.195
0.200
0.203
NO
PPM
******
******
0.006
0.006
O.OC6
0.006
0.006
0.006
0.006
0.006
0.006
0.006
O.OC6
0.006
0.006
0.006
0.006
0.005
0.005
0.005
0.005
0.006
0.005
0.005
0.005
0.006
0.006
N02-CORR
PPM
******
******
0.010
0.014
0.011
0.013
0.013
0.014
0.013
0.015
0.015
0.015
0.015
0.016
0.016
0.016
0.016
0.017
0.016
0.016
0.017
0.016
0.017
0.017
o.oia
0.017
0.018
NOX-CORR
PPM
******
******
0.016
0.020
0.017
0.019
0.019
0.020
0.020
0.020
0.021
0.021
0.021
0.021
0.022
0.022
0.022
0.022
0.022
0.022
0.022
0.023
0.023
0.022
0.023
0.023
0.024
HCHO
PPM
******
******
0.330
******
******
******
0.262
******
******
******
0.171
******
******
******
0.111
******
******
******
0.053
******
******
******
0.038
******
******
******
0.038
N-C4
PPM
.00012
.00700
.00694
******
******
******
******
******
******
******
******
******
******
******
.00575
******
******
******
******
******
******
******
******
******
******
******
.00463
NEO-C5
PPM
******
.00752
.00748
******
******
******
******
******
******
******
******
******
******
******
.00678
******
******
******
******
******
******
******
******
******
******
******
.00603
-------
u>
EC -255
FORMALDEHYDE
1977 NOV 23
CLOCK
TIME
752
840
900
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
TIMIN)
-68.
-20.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
'315.
330.
345.
360.
CO
PPM
******
******
2.20
2.23
2.23
2.29
2.34
2.33
2.34
2.37
2.45
2.43
2.50
2.47
2.55
2.53
2.53
2.59
2.60
2.63
2.65
2.66
2.69
2.70
2.69
2.72
2.73
H202
PPM
******
******
0.0
******
0.008
******
******
******
0.010
******
******
******
0.009
******
******
******
0.010
******
******
******
0.011
******
******
******
0.008
******
******
PAN
PPM
******
******
c.ooo
******
O.JOO
******
0.000
******
O.OJ1
******
0.002
******
0.002
******
0.002
******
0.003
******
******
0.004
0.004
******
J.005
******
0.005
******
0.006
ACETALO
PPM
0.0005
******
0.0011
******
******
******
******
******
******
******
******
******
******
******
0.0040
******
******
******
******
******
******
******
******
******
******
******
0.0047
PROPALO
PPM
0.0001
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
0.0014
******
******
******
******
******
******
******
******
******
******
******
0.0016
ACETONE
PPM
0.0005
******
0.0011
******
******
******
******
******
******
******
******
******
******
******
0.0116
******
******
******
******
******
******
******
******
******
******
******
0.0283
BUTYSAL
PPM
0.0000
******
0.0001
******
******
******
******
******
******
*******
******
******
******
******
O.OOOo
******
******
******
******
******
******
******
******
******
******
******
0.0007
HEK
PPM
0.0001
******
O.OOOb
******
******
******
******
******
******
******
******
******
******
******
0.0022
******
******
******
******
******
******
******
******
******
******
******
0.0019
PROX
PPM
0.0000
******
0.0000
******
******
******
******
******
******
******
******
******
******
******
0.0000
******
******
******
******
******
******
******
******
******
******
******
0.0001
METHANE
PPM
1.22
******
1.22
******
******
******
******
******
******
******
******
******
******
******
1.24
******
******
******
******
******
******
******
******
******
******
******
1.26
ETHANt
PPM
0.0051
******
0.0051
******
******
******
******
******
******
******
******
******
******
******
0.0052
******
******
******
******
******
******
******
******
******
******
******
0.0053
ETHENE
PPM
0.0047
******
0.0048
******
******
******
******
******
******
******
******
******
******
******
0.0032
******
******
******
******
******
******
******
******
******
******
******
0.0022
-------
EC -255
FORMALDEHYDE
1977 NOV 23
CLOCK
TIME
752
840
900
915
93U
945
1030
1015
1030
1045
1100
1115
1130
1145
120J
1215
1230
1245
W 1300
g 1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
TiMIN)
-68.
-20.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
Ib5.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
ACETYLEN
PPM
-------
Ul
EC -255
FORMALDEHYDE
1977 NOV 23
CLOCK
TIME
752
8 40
900
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
T(MIN)
-68.
-20.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC F
******
******
84.3
65.2
85.0
85.2
86.2
86.2
86.7
S7.0
87.2
87.2
87.2
87.4
87.9
87.9
87.9
87.2
87.2
87.4
87.9
87.7
87.4
87.4
87.4
87.7
87.9
REL HUM
*
******
******
40.5
42.5
44.5
46.5
47.5
48.0
48.0
48.5
48.5
48.5
48.5
48.5
49.0
48.5
48.5
48.5
49.0
49.0
49.0
49.0
48.5
48.5
48.5
48.5
49.0
SSPOWER
KW
******
******
19.96
******
******
20.46
20.46
******
******
******
20.48
******
******
******
21.16
******
******
******
20.52
******
******
******
20.79
******
******
******
20.56
RADIOM
Mh/CM2
******
******
0.225
0.227
0.225
0.220
0.232
******
******
******
0.227
0.230
0.230
******
0.239
******
******
******
0.234
0.230
0.227
******
0.232
******
******
******
0.232
HCHO VOL
L
******
******
10.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
H202 VOL
PPM
******
******
30.0
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
-------
Ui
to
EC -255
FORMALDEHYDE
1977 NOV 23
CLOCK
TIME
Til
840
900
915
930
9*5
1000
1015
1030
1045
1100
1115
lisa
1145
120J
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
T1MIN)
-68.
-20.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
N02
PPM
******
******
0.010
0.014
0.012
0.013
0.014
0.014
0.014
0.016
0.016
0.017
0.017
o.oie
0.019
0.019
0.019
0.020
0.020
0.020
0.021
0.021
0.022
0.022
0.023
0.023
0.024
NOX
PPM
******
******
0.016
C.020
0.018
0.019
0.020
0.021
0.021
0.022
0.022
0.023
0.023
0.023
0.024
0.025
0.025
0.026
0.025
C.U26
0.026
0.027
0.027
0.027
0.029
0.029
C. 029
TOT N03
PPM
******
******
0.000
0.000
0.000
0.000
0.000
0.001
0.001
0.001
0.002
0.002
a. 002
0.002
0.002
0.003
0.003
0.004
0.004
O.CC4
O.C04
0.004
0.005
0.005
0.005
0.006
O.C06
TOT N
PPM
******
******
0.017
0.021
o.oia
0.019
0.020
0.021
0.020
0.022
0.022
0.023
0.023
0.024
0.024
0.025
0.025
0.026
0.026
0.026
0.026
0.027
0.027
0.028
0.029
0.029
0.030
H20
PPM
******
******
16036.
17362.
18038.
18996.
20020.
20230.
20547.
20923.
21086.
21086.
21036.
21250.
21804.
21581.
21581.
21086.
21303.
21469.
21804.
21636.
21250.
21250.
21250.
21415.
21804.
HCTOT
PPMC
0.414
0.418
0.419
******
******
******
******
******
******
******
******
******
******
******
0.245
******
******
******
******
******
******
******
******
******
******
******
0.223
-------
Ul
CO
EC -256
PROPENE
1977 NOV 29
BEGIN IRRADIATION 0945; 0.25 INCH PYREX FILTER, TRICHROIC FILTER OUT
N-C4 AND NE3-C5 ADDED AS TRACERS FOR OH
H202 MONITORED BY TITANIUM TETSACHLORIDE PROCEDURE
DAStai 1212, TECQ 14B, 8ECKMAN 6600. HRAOY 291 USED
CO FACTORS: CO 1.6/.320
T=0 AT 945 PST
PAN
HCH3
REL INT
TS
REL HUM
SSPCKHR
RADIUM
H20
NO
M02-CORR
PKOPcNE
N-C4
NEO-C5
C3
HCHQ
AC?TALD
ACETONE
CALIB*
9
1
4
OEG K AVERAGE
% AVERAGE
Kh AVERAGE
HW/CM2 AVfAiiE
PPM AVERAGE
PPM INIT COND
PPM INIT CQNO
PPM
PPM
PPM
PPM
PPM
PPM
PPM
INIT
INIT
INIT
INIT
INIT
INIT
INIT
* ASSIGNED INITIAL
SPECTRAL
DISTR
IBUTIQN!
CONO
COND
CCNO
CCND
CCND
CONO
CCNO
303.0
49.32
20.72
0.232
2.044E 0
0.5ZO
0. 344
0.109
0.007
0.008
2.616
0.042
0.001
0.001
4
*
CONDITION
WAVELENGTH(NM) REL
500.
430.
403.
330.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
. INTENSITY
3.227
2.379
1.998
1.651
1.437
1.1U2
1.000
0.7S5
0.535
0.293
0.111
0.016
0.001
0.0
Kl*0.30 MIN-1
SAMPLING RATE » 1.697 L/MIN
35 GC SAMPLES TAKEN
-------
U)
U1
EC -256
PR3PENE
1977 NOV 29
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1233
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
f LAPSED
TIMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.030
0.002
0.000
0.002
0.002
NO
PPM
0.520
J.506
0.493
'0.481
0.467
0.452
0.435
0.41S
0.401
0.366
0.374
0.359
0.347
0.332
0.322
0.313
0.300
0.291
0.278
0.269
0.264
0. 249
0.244
0.237
0.227
N02-CORR
PPM
0.044
0.049
0.061
0.071
0.033
0.095
0.105
0.117
0.124
0.131
0.141
0.161
0.160
J.170
0.172
0.180
0. I 8t
0.187
J.194
0.199
0.204
0.206
0.209
0.209
0.209
NOX-CORR
PPM
0.564
0.552
0.552
0.552
0.549
0.544
0.537
0.530
0.522
0.517
0.512
0.510
0.505
J.50J
0.495
0.492
0.482
0.478
0.473
0.465
0.461
0.456
0.451
0.443
0.436
PRCPENE
PPM
0.109
0.103
0.100
0.095
0.090
0.064
0.080
0.074
0.071
0.065
0.062
0.058
0.055
0.051
0.048
0.045
0.042
0.040
0.037
******
0.033
******
0.030
******
0.026
N-C4
PPM
******
.00683
.00687
.00687
.00677
.00665
.00665
.00636
******
******
.00636
.00635
.00631
******
.00618
.00615
.00603
.00589
.00579
******
.00589
******
******
******
.00560
NEO-C5
PPM
.00766
.00751
.00751
.00751
.00745
.00737
.00736
.00684
.00733
******
.00703
.00715
.00713
******
.00696
.00695
.00091
.00673
.00669
******
.00673
******
.00666
******
.00662
-------
EC -256
PROPENE
1977 NOV 29
CLOCK
TIME
9*5
1000
1015
1030
10*5
1100
1115
1130
11*5
1200
1215
1230
12*5
1300
1315
133J
13 *i.
1*00
1*15
1*30
1**5
1500
1515
1530
15*5
ELAPSED
T(M[N)
0.
15.
30.
*5.
60.
75.
90.
105.
120.
135.
150.
165.
mo.
195.
210.
225.
2*0.
255.
270.
285.
300.
315.
330.
3*5.
360.
CO
PPM
2.62
2.60
2.62
2.60
2.65
2.63
2.65
2.66
2.68
2.68
2.68
2.69
2.7*
2.73
2.71
2.73
2.75
2.75
2.76
2.77
2.30
2.60
2.82
2.82
2.35
H202
PPM
0.0
******
******
' ******
0.002
******
******
******
0.00*
******
******
******
0.009
******
******
******
0.00*
******
******
******
0.002
******
******
******
******
PAN
PP1
******
******
******
.******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.001
******
0.001
******
0.001
******
9.001
HCHQ
PPM
0.0*2
******
******
******
0.0
******
******
******
0.00*
******
******
******
0.012
******
******
******
0.0
******
******
******
0.002
******
******
******
0.00*
ACETALO
PPM
0.001
******
0.006
******
0.012
******
0.018
******
0.023
******
0.027
******
******
******
0.03*
******
0.036
******
0.0*0
******
0.036
******
0.037
******
0.037
PROPALO
PPM
0.0002
******
0.0001
******
0.0002
******
0.0002
******
0.0001
******
O.OOJ3
******
0.0003
******
0.0002
******
0.0002
******
******
******
3.0003
******
0.000*
******
0.000*
ACETONE
PPM
0.001*
******
0.001*
******
0.0011
******
0.0016
******
0.0016
******
0.0026
******
0.0026
******
0.0025
******
0.0025
******
0.00*7
******
0.0036
******
0.00*9
******
0.00*7
-------
OJ
EC -256
PROPANE
1977 NOV 29
CLOCK ELAPSED
TIME TIMINJ
945 0.
1000 15.
1015 30.
1030 45.
1045 60.
1103 75.
1115 90.
1130 105.
114ti 120.
1200 135.
1215 150.
1230 165.
1245 180.
1300 195.
1315 210.
1333 225.
1345 240.
1400 255.
1415 270.
1430 2d5.
1445 300.
1500 315.
1515 330.
1530 345.
1545 360.
TS
DEC F
84.0
84.3
85.0
85.2
66.2
86.5
87.0
87.0
87.2
87.4
87.2
87.2
87.0
86.7
87.2
87.2
87.0
67.2
87.2
87.2
87.4
87.4
87.7
87.4
87.2
REL HUM
I
44.0
45.5
48.0
' 50.0
51.0
52.0
52.0
52.5
52.5
52.5
53.0
53.0
53.0
53.0
53.0
53.0
53.0
53.0
53.0
53.0
53.0
52.5
52.5
52.5
52.5
SSPChER
KH
20.09
******
******
******
20.46
******
******
******
20.57
******
******
******
20.84
******
* *****
******
2C.79
******
******
******
21.16
***«-**
******
******
21.15
RADIOM
MH/CM2
0.200
0.227
0.230
0.234
0.234
0.232
0.227
0.227
0.230
******
******
******
0.234
******
******
******
0.232
******
******
0.234
0.242
******
******
******
0.237
HCHO VOL H202 VOL
I PPM
20.00
******
******
****_**.
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
******
-------
Ul
CC -257
FORMALDEHYDE * PROPENE
1977 NOV 30
BEGIN IRHAOIATION 09455 0.25 INCH PYREX FILTER! TRICHROIC FILTER OUT
0759: 0.415 TORR HCHO IN 5.467 L BULB EXPANDED INTO EC
CALCULATED HCHO INJECTED " 0.547 PPM IN EC
N-C4 AND NEO-C5 ADDED AS TRACERS FOR OH
H202 MONITORED BY TITANIUM TETRACHLOR1UE PROCEDURE
OASIBI 1212, TECO 14B, BECKMAN 6800, BRADY 291 USED
CO FACTOR: 1.6/.265
T-0 AT 945 PST
CALIB*
PAN
HCMO
REL INT
TS
REL HUM
SSPOW5R
RADIOM
H20
NO
NG2-CORR
HCHO
PROPtNE
N-C4
NEO-C5
CO
ACETACO
ACETONE
DEC K
X
KH
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
1
4
AVERAGE
AVERAGE
AVERAGt
AVERAGE
AVERAGE
INIT CONO
INIT CCNO
INIT CCND
INIT CCNO
INIT CCNO
INIT CCNO
IWlT CCND
INIT CCNO
INIT CCNO
303.9
50.37
20.91
0.230
2.199E 04
O.S30
0.032
0.371
0.112
0.007
0.006
0.849
0.001
0.001
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION:
kAVELENGTH(NM)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
Kl-0.30 MIN-1
SAMPLING RATE « 1.692 L/MIN
48 GC SAMPLES TAKEN
REL. INTENSITY
3.204
2.366
1.991
1.633
1.431
1.174
1.000
0.765
0.522
0.288
0.108
0.016
0.001
0.0
-------
LJ
t_n
00
EC -257
FORMALDEHYDE + PROPENE
1977 NOV 30
CLOCK
TIME
945
100J
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.002
0.005
O.OLQ
0.012
0.015
0.022
0.022
0.027
0.032
0.037
0.037
0.044
0.046
0.049
0.051
0.059
0.061
0.066
NO
PPM
C.530
0.471
0.415
C.362
0.308
0.269
0.237
0.210
0.136
0.169
0.151
0.137
C. 125
0.110
0.105
0.098
0.090
0.083
0.076
0.073
0.068
0.064
0.061
0.056
0.056
N02-CORR
PPM
0.032
0.083
0.129
0.167
0.209
0.238
0.257
0.269
0.280
0.285
0.292
0.297
0.301
0.303
0.298
0.300
0.297
0.295
0.294
0.289
0.282
0.284
0.282
0.271
0.269
NOX-CORR
PPM
0.559
0.554
0.544
0.531
0.516
0.506
0.494
0.479
0.469
0.454
0.443
0.433
0.423
0.413
0.403
0.395
0.382
0.375
0.368
0.360
0.350
0.350
0.340
0.330
0.322
HCHQ
PPM
0.371
******
******
******
0.282
******
******
******
0.250
******
******
******
0.230
******
******
******
0.126
******
******
******
0.121
******
******
******
0.098
PROPENE
PPM
0.112
0.093
0.087
0.077
0.067
******
0.051
******
0.043
******
0.035
******
0.029
******
0.025
******
0.021
******
0.018
******
0.015
******
0.013
******
0.011
N-C4
PPM
.00704
.00681
.00675
.00665
.00648
******
.00608
******
.00625
******'
.00605
******
.00590
******
.00575
******
.00573
******
.00559
******
.00539
****** •
.00539
******
.00531
NEO-C5
PPM
.00766
.00748
.00738
.00737
.00730
******
.00684
******
.00702
******
.00698
******
.00687
******
.00673
******
.00661
******
******
******
.00646
******
.00656
******
.00636
-------
EC -257
FORMALDEHYDE + PROPENE
1977 NOV 30
CLOCK
TIME
9*5
1000
1015
1030
10*5
1100
1115
1130
11*5
1200
1215
1230
12*5
1300
1315
1330
13*5
1*00
OJ 1*15
Ui 1^30
^ 1**5
1500
1515
1530
15*5
ELAPSED
T(MIN)
0.
15.
30.
*5.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
2*0.
255.
270.
285.
300.
315.
330.
3*5.
360.
CO
PPM
0.85
0.86
0.91
0.9*
0.98
1.03
1.06
1.10
1.13
1.1*
1.17
1.22
1.25
1.28
1.29
1.32
1.35
1.35
1.39
1«*1
1.41
l.*2
l.*8
l.*8
1.51
H202
PPM
0.0
******
0.0
******
******
******
0.0
******
******
******
C. 002
******
******
******
******
******
******
******
******
******
******
******
0.001
******
******
PAN
PPM
******
******
******
******
0.001
******
0.002
******
O.G03
******
0.00*
******
0.00*
******
0.005
******
O.G06
******
O.C06
******
O.C07
******
O.C07
******
0.007
ACETALO
PPM
0.0010
******
0.0156
******
0.0268
******
0.0339
******
0.0353
******
0.0368
******
0.0368
******
0.0366
******
0.0361
******
0.0316
******
0.032*
******
0.03U
******
0.0318
PROPALO
PPM
0.0002
******
0.0002
******
0.0002
******
0.0002
******
0.0003
******
0.0002
******
0.0003
******
0.0003
******
0.0003
******
0.0003
******
0.0003
******
0.0003
******
0.000*
ACETONE
PPM
0.0013
******
0.0012
******
0.0018
******
0.0017
******
0.0020
******
0.0021
******
0.0030
******
0.003*
******
0.0036
******
0.00*3
******
0.0036
******
******
******
0.00*4
-------
EC -257
FORMALDEHYDE «• PROPENE
1977 NOV 30
CLOCK
TIME
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
T(MIN»
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEG F
84.5
85.5
85.2
86.2
86.7
87.0
87.7
87.2
87.9
as. 2
88.2
87.9
87.7
87.7
88.2
37.4
87.7
87.9
87.4
87.4
87.7
87.7
87.9
87.4
87.4
REL HUM
*
42.5
44.0
46.5
48.5
49.5
50.0
50.5
50.5
50.5
51.0
51.0
51.0
51.0
51.0
51.5
51.5
51.5
52.0
51.5
52.0
52.0
52.0
52.0
52.0
52.0
SSPOHER
KW
20.55
******
******
******
20.55
******
******
******
20.61
******
******
******
20,79
******
******
******
21.34
******
******
******
21. 16
******
******
******
21.34
RAOIOM
MW/CM2
0.227
0.227
0.220
0.232
0.227
******
******
******
0.227
******
******
0.232
0.230
0.227
0.232
0.237
0.227
0.230
0.232
0.232
0.230
0.230
0.234
0.234
0.230
HCHQ VOL
L
10.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
15.00
******
******
******
20.00
******
******
******
20.00
H202 VOL
PPM
30.0
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
30.0
******
******
******
******
******
******
******
30.0
******
******
-------
OJ
EC -257
FORMALDEHYDE * PR OP EN E
1977 HQV 30
CLOCK
TIME
945
1000
1015
1030
lots
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
T(HIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
N02
PPM
0.032
0.083
0.129
0.169
0.210
0.239
0.259
0.271
0.233
0.288
0.296
0.300
0.305
0.308
0.303
0.305
0.303
0.300
0.300
0.296
0.288
0.291
0.288
0.278
0.276
NOX
PPM
0.559
0.554
0.545
0.532
0.518
0.508
C.496
0.481
0.471
0.457
0.447
0.437
0.427
0.418
0.408
0.401
0.388
0.381
0.374
0.366
0.357
C.357
C.347
0.337
0.330
TCT N03
PPM
0.0
0.000
0.001
0.001
0.001
0.002
0.002
0.002
O.OC3
0.003
0.004
0.004
0.004
0.004
0.005
0.005
0.006
0.006
0.006
0.006
0.007
0.007
0.007
0.007
0.007
TOT H
PPM
0.562
0.554
0.545
0.530
0.518
0.508
0.496
0.481
0.469
0.457
0.447
0.437
0.430
0.416
0.408
0.403
0.393
0.383
0.376
0.369
0.357
0.354
0.349
0.335
0.332
H20
PPM
16960.
18116.
18996.
20441.
21189.
21570.
22290.
21955.
22471.
22870.
22870.
22694.
22519.
22519.
23094.
22564.
22740.
23139.
22564.
22783.
22961.
22961.
23139.
22783.
22783.
HCTOT
PPMC
0.778
0.730
0.689
0.647
0.607
******
0.554
******
0.522
******
0.493
******
0.469
******
0.405
******
0.343
******
0.323
******
0.311
******
0.294
******
0.277
-------
OO
EC -264
TOLUcNE
1978 JAN 23
BEGIN IKRAiil^TION 124SJ 0.25 INCH PYRE* FILTER; TRICHROIC FILTER OUT
TOLUENE MU'NITURtO BY 3-FART COLUMN
TcNAX GC SAMPLES BEGINNING AT 1£15, 1330, 1430, 153C, 1605
(10.8 L EACH EXCEPT 21.6 AT Io05)
TENAA GC-MS SAMPLES BEGINNING AT 1230,1345,1445,1545 (EACH 10.8 LJ
NO SPECTRAL DISTRIBUTION TAKEN
OASItJI 1212, TECO 14B-1, B«AOY 291 USED
T=0 AT 1245 PST
CALIB*
PAN
hCHO
RtL INT
TS
REL HUM
SSPLftER
KAUIOM
ruO
NJ
NG2-COKR
TOLUENE
HCriC
DEC K
S
Kh
MW/CM2
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNU
IMT CCND
INIT CCND
IMT CCNO
304. 0
41.30
11. 61
C.262
1.839E
C.420
O.C56
1.156
C.008
* ASSIGNED INITIAL CCNDITION
Kl=0.35 MIN-1
SAMPLING RATE = 1.535 L/MIN
16 GC SAMPLES TAKEN
-------
ON
Co
EC -264
TOLUENE
1978 JAN 23
CLOCK
TIME
1245
1500
1315
1330
1345
1350
1400
1415
1430
144P
1500
1515
1530
l34p
1550
loOO
1615
1630
1645
cLAPSED
TIM1N)
0.
15.
30.
45.
60.
65.
75.
90.
105.
120.
135.
150.
165.
180.
185.
195.
210.
225.
240.
QZCNE
PPM
0.0
0.0
0.0
o.oia
0.018
******
0.021
0.053
0.100
0.154
0.218
0.280
0.342
0.395
******
0.418
0.419
0.413
0.400
NO
PPM
C.420
0.391
0.340
0.269
0.191
C.164
C.118
0.073
0.046
0.0*8
C.022
C.015
C.015
0.016
C.013
0.012
0.012
C.012
C.011
N02-CQRR
PPM
O.C56
0.076
0. lil
0.183
0.241
0.263
0.264
C.290
0.279
0.255
0.2C5
0.157
0.115
0.072
O.C67
0.05C
0.035
0.029
0.027
NOX-CORR
PPM
0.470
0.468
0.461
0.450
0.432
0.426
0.401
0.362
0.324
0.277
0.228
0.173
0.130
0.088
o.oao
0.064
0.046
0.039
0.037
TOLUENE
PPM
1.156
******
******
******
******
0.989
******
******
******
0.358
******
******
******
******
0.650
******
******
******
******
PAN
PPM
0.000
******
******
******
0.004
******
******
0.013
******
0.024
******
0.044
******
0.056
******
******
0.067
******
0.071
HCHO
PPM
0.008
******
******
******
0.002
******
******
******
******
0.017 '
******
******
***#**
0.032
******
******
******
******
0.029
ME-N
PPM
0.0
******
0.0
******
0.0
******
******
0.0
******
0.0004
******
0.0007
******
O.OOli
******
******
0.0011
******
0.0011
-------
EC -264
TOLUENE
1976 JAN 23
CLOCK
TIME
1245
1300
1315
13-sO
13*5
1350
1400
1415
1430
14-0
1500
1515
1530
1»45
1550
1600
1615
1630
1645
ELAPSEC
T
-------
EC -265
TOLUcNE
1W8 FEB 2
fl£(,IN IKRAOIATIQN 1245; 0.25 INCH PVREX FILTER} TRICHROIC FILTER OUT
OAilBI 1212 CN STANDBY LHT.IL 1450
TOLOENE AND OXYGENATES CCMTUREO BY 3-PART COLUMN
TENAX GC SAMPLES BEGINNING AT 0925t12CO ,1330,1435,1530,1630! EACH 10.8 L
TENAX GC-MS SAMPLES BEGINNING AT 0925i1215,1345,1445i1545i£1645: EACH 10.8 L
NC SPECTRAL DISTRIBUTION TAK.EN
TECO 14o-l, 6RACY 291, 6 CASI6I 1212 USED
T=0 AT 1245 PST
oo
O\
Ln
CALI&*
PAN
HChu
RtL INT
TS
RCL HUM
SSPOMER
RADIOM
Hid
NO
N02-CORR
TOLUENc
HCMO
ACeTALD
ACETONE
OfcG K
91
KH
M»'/CM2
PPM
PPM
PPM
PPM
PFM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCNC
INIT CCNO
JNIT CCNC
INIT CCNO
INIT CCNO
ASSIGNED INITIAL CONDITION
Kl=0.35 MIN-1
SAMPLING RATE
3U.6
54.39
Il.o9
O.itl
i.iQ
0.435
C.G47
1.C70
C.012
O.OC1
0.003
1.535 L/MIN
16 GC SAMPLES TAKEN
-------
cC -2t>5
TOLUENE
197tt FEB 2
CLOCK
TIME
1245
1300
1313
l.»3u
1345
1400
1415
14JO
1443
1500
Iil3
1530
1543
lt>*JG
16 IS
1630
1045
ELAPSED
TiMINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
133.
150.
165.
100.
195.
210.
225.
240.
CUONE
PPM
******
******
******
******
******
******
******
******
******
0.215
0.264
0.320
0.344
0.383
0.393
0.391
0.379
NO
PPM
0.435
0.363
C.321
C.243
0.162
0.098
0.053
0.035
0.024
0.020
C.Olb
C.013
C.010
0.010
O.OC9
C.01U
Q.OC7
N02-CJRR
PPM
0.047
0.086
0.146
0.2C7
0.263
0.291
0.300
0.276
0.244
0.194
0.155
0.111
O.C79
0.055
O.U36
0.032
0.028
NOX-CORR
PPM
0.482
0.472
0.4o8
0.-.47
0.422
0.388
0.352
0.312
0.2o4
0.212
0.171
0.123
0.088
0.065
0.044
0.03d
0.035
TOLUENE
PPM
1.070
******
******
******
1.029
******
******
******
0.873
******
******
******
0.729
******
******
******
0.631
PAN
PPM
0.000
******
0.001
******
0.004
******
0.014
******
0.031
******
0.043
******
0.059
******
0.072
******
0.070
HCHO
PPM
0.012
******
******
******
******
0.011
******
******
0.019
******
******
******
0.036
******
******
******
0.039
ACETALO
PPM
0.0010
******
******
******
******
******
******
******
0.0037
******
******
******
0. OC56
******
******
******
0.0049
PKOPALO
PPM
0.0004
******
******
******
0.0004
******
******
******
0.0011
******
******
******
0.0020
******
******
******
0.0030
ACETC/NL
PPM
0.0025
******
******
******
0.0092
******
******
******
******
******
******
******
0.0i93
******
******
******
o.02o9
ME-N
PPM
0.0
******
0.0
******
0.0
******
0.0
******
O.OuOl
******
0.0001
******
U.0002
******
0.0u02
******
0.0003
CO
-------
EC -265
TOLUENE
1978 FEB 2
CLOCK
TIHc
U45
1300
1315
1-sjO
1345
14uJ
i415
1*30
1445
1500
1515
1550
1545
1600
Iol5
1630
loti
ELAPSED
TIMIN)
0.
15.
30.
45.
bC.
75.
va.
105.
120.
135.
150.
165.
iao.
1S5.
210.
225.
240.
TS
DEC F
65.0
85.5
Bo.O
63.3
84. C
a<».5
65.0
d5.0
65.0
65.2
as. 2
65.0
£5.2
85.2
65.2
85.2
65.2
REL HUM
*
49.5
50.5
51.5
52.5
54.5
55.0
55.5
55.5
55.5
55.5
55.5
55.5
55.5
55.0
55.0
55.0
55.0
SSPOhcR
KM
11.86
******
******
******
11.50
******
******
******
11.66
******
******
******
11.66
******
******
******
11.77
RACIOM
MH/CM2
0.271
0.266
0.256
0.259
0.261
******
******
******
0.256
******
******
0.261
0.256
******
******
******
0.261
HCHO VQL
L
20.00
******
******
******
******
20.00
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
-------
UJ
0>
00
EC -266
TOLUENE
1978 FEB 7
IRRADIATION 1C15; 0.25 INCH PYREX FILTER; TRICHROIC FILTER OUT
TOLUENE AND OXYGENATES fONITORED 8Y 3-PART COLUMN
TENAX GC SAMPLES TANcN AT BEGINNING OF EACH HR, HOO-loOO (10.8 L EACH)
TENAX GC-MS SAMPLES TAKEN BEGINNING AT 0945t 1016,13l6itlo20
(EACH 15.3 L SAMPLES EXCEPT 19.4 AT 1316)
oRADY 291,OAS18I U12t6 TECC 14B-1 LSEO
CO FACTOR 1.6/47.0; BcCKMAN 6800 MANUAL OPERATION: SAMPLES PULLED 42 MIN TOTAL
T=0 AT 101s PST
CALIB*
PAN
HCHG
REL INT
TS
REL MJM
SSPonrR
RAL1CM
H<:L
NJ
N02-C.CRR
TCLUcNE
Cu
HCHO
ACETAtD
ACETGNE
M-CKESOL
OEG K
%
KW
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNJ
INIT CCKD
IMT CCNO
INIT CJNC
INIT CCNO
INIT CCNO
INIT CCNC
INIT CCNO
302.6
47.13
11.85
C.263
l.S2«E 04
0.122
C.059
1.196
C.230
C.C1C
0.001
0.002
O.C01
ASSIGNED INITIAL CCNDITION
SPECTRAL DISTRIBUTION:
kAVELENGTHIMN)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
210.
300.
290.
REL.
Kl=0.35 MIN-1
SAMPLING RATE « 1.611 L/MIN
12 GC SAMPLES TAKEN
INTENSITY
1.538
1.543
1.442
1.361
1.248
1.093
1.000
0.609
0.573
0.324
0.129
0.021
0.0
-------
ON
EC -266
TQLUcNE
1978 FEB 7
CLOCK
TIME
*G15
1030
10*5
11JO
1X15
1130
11*5
1200
1215
li.30
12<»5
130J
131a
1330
13*5
1400
1*15
1*30
14*5
1500
1515
1530
15*5
1600
1615
ELAPSED
TCMINJ
0.
15.
30.
*5.
60.
75.
90.
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100.
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2*0.
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270.
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0.362
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0.029
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PPM
1.196
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0.505
-------
EC -266
TOLUENE
1978 f=EB 7
CLOCK
TIME
1015s
i n *•! ii
iU -Jw
1045
1100
1115
1130
1145
1215
1230
U45
t300
1315
1330
1345
1400
1415
1430
1445
1500
1513
1545
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16 15
ELAPSED
T(MIN)
0.
1 K
1 3.
30.
45.
60.
75.
90.
i n i*
1 U >•
120.
135.
150.
165.
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195.
210.
225.
240.
255.
270.
285.
300.
330.
345.
360.
CO
PPM
0.33
0.39
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******
******
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0.48
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******
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******
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0.68
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0.83
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0.004
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0.075
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0.039
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u>
EC -266
TOLUENE
1978 r£B 7
CLOCK ELAPSED
TIME T4MINJ
10 li C.
10JO 15.
1045 30.
U«JO 45.
1115 60.
1130 75.
1145 90.
1200 105.
1215 120.
1230 135.
1245 150.
1300 165.
U15 180.
1330 195.
1345 210.
1400 225.
1415 240.
1430 255.
1445 2?0.
1500 285.
1315 300.
1530 315.
1545 330.
1600 345.
1615 360.
PNT
PPM
GC-MS
C.O
******
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******
C.GQ10
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******
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0.0020
******
******
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******
******
******
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0.0040
******
******
******
0.0030
******
******
******
G.CC30
-------
u>
•vl
EC -266
TOLUENE
1978 FEB 7
CLOCK
TIME
1015
1030
1043
1100
1115
1130
1145
1200
1215
123U
1245
13JO
1315
1330
13*5
1400
1415
1430
1445
1500
1515
1530
1545
1600
Ibl5
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ioO.
195.
210.
225.
£40.
255.
270.
265.
300.
315.
330.
345.
360.
TS
DEC F
84.8
63.5
85.5
83.8
84.0
84.8
85.0
85.2
85.5
65.2
85.2
85.5
65.2
85.5
85.5
85.7
85.5
86.0
86.0
65.7
66.2
65.5
85.7
86.0
86.0
REL HUM
*
43.5
44.0
45.0
46.0
47. C
48.0
48.0
48.5
48.5
48.5
46.5
48.5
48.5
46.5
48.5
4d.5
46.5
48.5
48.5
48.0
48.0
48.0
43.0
48.0
48.0
SSPdwER
Kh
11.68
******
11.78
******
11.64
******
******
******
11.73
******
******
******
11.73
******
******
11.83
11.91
******
******
******
11.95
******
******
******
12.15
RAO I DM
Mh/CM2
0.264
0.206
0.264
0.259
0.264
******
0.261
******
0.261
0.261
******
******
******
0.261
0.259
0.259
0.261
******
0.260
0.264
0.264
******
******
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0.271
HCHO VOt
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20.00
******
******
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20. CO
******
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20.00
******
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20.00
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20.00
-------
EC -269
TOLUENE »3
1978 MAR 16
ocC,IN IRRADIATION 1045s 0.25 INCH PYREX FILTER, TRICHROIC FILTER OUT
TOLUENE ANO OXYGENATES MONITORED BY 3-PART COLUMN
HChO MAY 8E LCw BY FACTOR OF 2.2 DUE TO INCORRECT ROTOMETER SETTING.
SETTING FOR THIS RUN NCT KNOhN
TENAX GC SAMPLES TAKEN BEGINNING AT C845,C945,1130,1230,1330,143061530
GC ANALYSIS USING 10FT X iMM GLASS COLUMN CONTAINING TENAX GC (60-80 MESH)
TcNAX GC-MS SAMPLES TAKEN BEGINNING 09CC, 1000, U45,U45 .1345 ,1445615'H>
GC-MS ANALYSIS USING 25K X 0.2MM WALL-CCATEO GLASS CAPILLARY COLUMM
CONTAINING UCCN t-B
EACH TENAX GC £ TENAX GC-MS SAMPLE 10.8 L
dR«UY 291, OASIBI 1212, £ TECQ 148-1 USED;
CO FACTOR 1.45/17.0! 3ECKMAN 6800 MANUAL OPERATION
T=0 AT 1045 PST
--J
OJ
CALIB#
PAN
hCHO
RcL INT
TS
REL HUM
SSPOntR
RAOIOM
H20
NO
N02-CC-RR
TOLUENE
hCHO
ACETONE
6/ALU
btALDBtN
OEG K
Si
K'W
MM/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
INIT CCNO
IMT CCND
INIT CCNO
INIT CCNO
INIT COND
INIT CCND
302.7
46.16
11.95
C.263
I.3S3E
0.398
O.C74
0.566
0.003
C.C05
0.001
0.003
04
ASSIGNED INITIAL CCNOITION
-------
cC -269
TOLUENE #3
1976 MAR 16
SPECTRAL DISTRIBUTION: kAVcLENGTH(Nf} REL. INTENSITY
SCO. 1.667
<<30. 1.584
403. 1.473
360. 1.382
370. 1.265
3oC. 1.112
350. l.GOO
340. O.E07
330. 0.575
320. 0.322
310. 0.126
300. 0.019
290. C.001
28C. 0.0
Kl=0.35 MIN-1
SAMPLING RATE = l.£56 L/HIN
24 GC SAMPLES TAKEN
-------
OJ
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Ln
cC -269
TOLUENE *3
1976 MAR 16
CLOCK
TIME
1045
1100
1115
1130
1143
1200
1215
U30
1245
liOu
1315
1330
1345
1400
1415
1430
14t5
1500
1515
1530
15t5
1600
1615
lojj
1645
ELAPSED
T(MIN)
0.
^.5.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
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0.086
0.100
0.117
0.134
0.149
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0.1S3
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0.230
0.254
0.274
0.298
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PPM
C.3S8
0.368
C.332
C.291
C.249
0.206
C.165
0.134
0.1C9
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0.048
C.C39
C.034
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HC -24,9
TOLUENE *3
1978 MAK JO
CLOC*.
TIMS
Io45
1100
1115
U30
11 <.:>
121 •;
1230
ii'«5
130 J
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******
******
O.OOlo
******
******
******
o.oolo
******
******
******
******
8ENZ-N02
PPM
GC-MS
0.0
******
******
******
0.0001
******
******
»**•*•»*
O.UOO?
******
******
******
O.OvJOb
******
**** **
******
0.0008
******
******
**** *c
******
******
******
0.0006
BZALDBZN
PPh
T6NX GC
0.003J
******
******
0.0055
******
******
******
0.0070
**** **
******
**«* **
******
0.0075
******
******
U. 00(17
******
******
******
0.0085
******
******
******
******
-------
00
EC -269
TGLUENE »3
1976 MAR 16
CLOCK ELAPSED
TIME TtMJNl
10*5 0.
1100 15.
1115 30.
1130 45.
1145 60.
1200 75.
1215 9C.
1230 105.
1245 120.
13ud 135.
1315 150.
i330 165.
1345 180.
1400 195.
1415 210.
1430 225.
1445 240.
1500 255.
1515 270.
1530 285.
1545 300.
1600 315.
1615 330.
1630 345.
Io45 360.
TS
DEC F
84. 8
84. a
64. a
85.2
65.2
85.5
85.5
85.7
65.5
65.5
65.5
85.2
as. s
85.2
85.2
85.2
85.5
85.5
85.5
85.5
85. .2
65.7
85.5
85.5
65.5
H EL HUM
37.0
40.0
43.0
44.5
46.0
46. S
47.0
47.0
47.5
47.5
47.5
47.5
47.5
46.0
46.0
4b.O
4b.O
4c.O
48.0
46.0
43.0
46.0
4o.O
46.0
48.0
SSPQUcR
Kh
11.74
******
**'•**#
******
11.91
******
******
******
11.68
******
******
******
11. d4
******
******
******
11.91
******
******
******
12.04
******
******
******
12.31
RADIOM
MW/CM2
******
0.260
0.259
0.260
0.261
******
******
******
0.259
******
******
******
0.261
0.261
******
******
0.261
0.261
******
******
0.261
0.266
0.266
0.264
0.269
HCHO VOL
L
20.00
******
******
***-!**
20.60
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20. 00
******
******
******
20.00
-------
EC -270
TOLUENE #5
197U MAR £0
JKKADIATJON 1000,- 0925 IMCH PVREX FILTER; TRJCHROJC FILTER OUT
TOLUENE AND OXVGENATES FCNITOREO BY 3-PART COLUMN
HCHO MAY BE LCw BY FACTCR OF 2.2 DUE TO INCORRECT ROTOMETER SETTING.
SETTING FOR THIS RUN NOT KNCWN
TcNAX GC SAMPLES TAKEN BEGINNING AT C613, HOC, 1200, UOO 1 1400 , 1500U600
EACH SAMPLE 10.8 L
GC ANALYSES USING 10 FT * 2 KM GLASS COLUMN CONTAINING TENAX GC (60/80 MESH)
OAS16I 1212, TECO 146-1, ERALY 291 USED
CO FACTOR 1.45/.16; BECKMAN 6600 MANUAL OPERATION
T«0 AT 1000 PST
PAN
HCHO
REL INT
CALIB*
9
3
4
TS
REL HUM
SSPUKER
RAulCH
H20
NO
NC2-CORR
TOLUENE
HCHO
ACETALO
ACETCNc
OlALOtiiH
DEC K°
I
KM
WW/CM2
PPM
PPK
PPM
PPM
PPM
PPI-,
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
IMT CCMO
INIT CCNO
INIT CCNO
IMT CCNO
INIT CCNO
INIT CCND
302.t
45.56
12.02
C.264
1.852E 04
0.414
O.OS1
0.576
0.171
0.001
0.004
0.003
ASSIGNED INITIAL CONDITION
SPECTRAL OISTR IbUTlCN:
ViAVELENGTH(NM)
5CC.
430.
40J.
380.
370.
36C.
350.
340.
330.
320.
310.
300.
290.
280.
Kl=0.35 MIN-1
SAMPLING RATE - 1.954 L/MIN
26 GC SAMPLES TAKEN
REL. INTENSITY
1.665
1.603
1.515
1.395
1.288
1.112
1.000
0.818
0.570
0.320
0.131
O.C19
0.001
0.0
-------
UJ
GO
o
cC -270
TOLUENE #5
1976 MAR 20
CLOCK
TIME
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
12<*5
130J
1315
Ia30
1J45
1400
1415
1430
1445
1500
1S15
1530
1545
1600
ELAPSED
T(M1N)
0.
15.
30.
45.
60.
75.
90.
105.
1*0.
135.
150.
165.
IbO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
0.000
0.000
0.000
0.005
C.010
0.020
0.034
0.046
0.071
0.090
0.112
0.139
0.164
0.136
0.2C8
0.232
0.261
0.286
0.313
0.337
0.357
0.366
0.369
0.366
0.362
NO
PPM
0.414
0.365
.0.304
0.242
0.162
0.133
C.C95
0.071
0.053
0.039
C.032
C.C26
0.021
C.013
C.018
C.012
C.G1Q
O.OC9
C.007
O.OC6
C.CC7
0.006
0.006
C.C06
C.005
N02-CORR
PPM
0.051
0.091
C.142
0.191
0.233
0.260
0.274
0.273
0.269
0.255
0.241
0.221
0.200
0.179
0.156
0.143
0.124
0.104
O.C32
0.064
0.053
0.038
0.038
0.027
0.024
NOA-CORR
PPM
0.465
0.455
0.446
0.432
0.415
0.392
0.368
0.343
0.319
0.293
0.271
0.244
0.220
0.196
0.175
0.154
0.132
0.111
o.osa
O.C69
O.C59
0.043
0.041
0.032
0.027
TOLUENE
PPM
0.576
******
0.542
******
0.497
******
0.466
******
0.430
******
0.403
******
0.378
******
0.345
******
0.321
******
0.289
******
0.262
******
0.232
******
0..217
-------
00
EC -270
TOLUENE *5
1976 MAR 20
CLOCK
TIME
100J
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
i430
1445
1500
1515
1530
1545
1600
ELAPSED
T(MJN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
Io5.
IfaO.
1S5.
210.
225.
2tO.
255.
270.
265.
300.
315.
330.
34i.
360.
CO
PPM
******
******
******
******
1.30
******
******
******
1.38
******
******
******
1.45
******
******
**v*»*
1.52
******
******
******
1.64
******
******
******
1.69
PAN
PPM
0.000
******
ti.OOl
******
0.003
******
C. (JC7
******
******
******
0.019
******
O.C25
******
C.030
******
0.034
******
0.041
******
C.C50
******
C.054
******
0.057
HCHQ
PPM
0.171
******
******
******
0.066
******
******
******
0.113
******
******
******
O.C86
***«•**
******
******
O.C77
******
******
******
O.Qo3
******
******
******
0.051
ACtlALD
PPM
0.0013
******
0.0016
******
0.0027
******
O.C026
******
0.0035
******
0.0039
******
0.0041
******
0.0051
******
0.0056
******
0.0050
******
0.0051
******
0.0053
******
0.0059
PftOPALD
PPM
O.OOC3
******
0.0004
******
C.0007
******
0.0009
******
0.0013
******
0.0015
******
0.0020
******
0.0023
******
0.0027
******
0.0030
******
0.0033
******
0.0032
******
0.0037
ACETbNE
PPM
J.0038
******
0.0029
******
0.0046
******
J.0059
******
0.0100
******
0.0112
******
0.0121
******
0.0146
******
0.0161
******
0.0179
******
0.0215
******
0.0171
******
0.0227
0-CRESCL
PPM
0.0
******
******
******
0.0071
******
******
******
******
******
******
******
0.0017
******
******
******
0.0009
******
******
******
0.0010
******
******
******
0.0007
ONT
PPM
TENX GC
0.0
******
******
******
O.OOOo
******
******
******
******
******
******
******
0.0020
******
******
******
0.0001
******
******
******
0.0
******
******
******
0.0
PNT-.3HNT
PPM
TcNiA GC
o.u
******
******
******
0.0010
******
******
******
******
******
******
******
0.0026
******
******
******
0.002V
******
******
******
U.0036
******
******
******
0.0035
MNT23HNT
PPM
TtNA GC
0.0
******
******
******
U.0006
******
******
******
******
******
******
******
0.0011
******
******
******
O.U020
******
******
******
0.0024
******
******
******
0.0017
32ALDBIN
PPM
TENX GC
0.0020
******
******
******
0.0072
******
******
******
******
******
******
******
0.0009
******
******
******
O.OOV6
******
******
******
0.0113
******
******
******
0.0101
-------
OJ
oo
[S3
EC -270
TOLUENE »5
1978 MAR 20
CLOCK ELAPSED
TlMc TIMINJ
lOuO 0.
1015 15.
1030 30.
1045 45.
lluO 60.
1115 75.
lljO 90.
i*45 105.
UOo 120.
1215 135.
1230 150.
12t5 165.
liOO 160.
1^15 195.
1330 210.
13*0 225.
14UO 240.
itia 255.
14^0 270.
1445 265.
1500 300.
1515 315.
1530 330.
15*5 3*5.
1600 360.
TS
DEG F
61.1
64.3
64.3
85.0
65.7
6&.0
€6.0
86.0
66.2
86.0
66.0
86. C
66.0
6o.O
66.2
66.2
66.5
oo. 2
66.2
86.0
86.2
65.5
05.7
85.7
85.7
REL HUH
42.0
44.5
46.0
47.5
4b.C
48.5
46.5
49.0
49.0
49.0
49.5
49.5
49.5
49.5
49.5
49.5
49.5
49.5
49.5
49.5
49.5
49.5
50.0
50.0
49.5
SSPOrfER
Kta
11.92
******
******
U.10
******
******
12.09
******
******
******
12.02
******
******
******
11.99
******
******
******
12.02
******
******
******
12.02
RACIOM
0.256
0.266
0.261
0.2e>t>
0.2c9
0.266
******
******
0.264
0.266
******
******
0.2o6
******
******
******
0.269
******
******
******
0.266
0.259
******
******
0.264
HCHO VOL
L
20.00
******
******
******
30.30
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
u>
00
ec -..71
TOLUENE »2
1978 MAR 21
8EGIN IRRADIATION 0945! 0.25 INCH PYREX FILTERS TRICHROIC FILTER OUT
TuLOENc AND OAV6ENATES MONITORED BY 3-PART COLUMN
nCHO MAV Be LOx df FACTCR OF 2.2 DUE TJ ^CORRECT ROTOMETER SETTING.
ScTTING FOR THIS RUN NCT KNCttN
TtNAX GC SAMPLES TAKEN EEGINNING AT C6C5,1045,1145,1345•I445tl545
GC ANALYSES USING ii( FT A i MM GLASS COLUPN CONTAINING TENAX OC (60/80 MESH)
TENAX GC-MS SAMPLES TAKEN BEGINNING C82G, 4,915. 0930,1030 ,1215 .1230C1430
EACH TENAX GC L TENAX GC-MS SAMPLE 10.8 L
OAS16I 1212, TcCD 146-1, ERACV 291 UStO
CO FACTUA 1.45/.163; BECKMAN 6800 MANUAL OPERATION
T«0 AT 945 PST
PAN
HCHO
RdL INT
TS
RE I. HUM
SSPOwER
RA010H
H20
NO
NOE-CORk
TOLUENE
hCHO
ACETALD
ACETONE
BZAL084N
DcG K
I
KM
MW/CH2
PPM
PPM
PPH
PPM
PPM
PPM
PPM
PPM
* ASSIGNED
SPECTRAL
CALI8#
9
3
4
AVERAGE
AVERACE
AVERAGE
AVERAGE
AVERAGE
JNIT CLNO
INIT CCNO
INIT CCNO
IMT CCND
1MT CCNO
1N1T CCNO
1NIT CGND
302.5
49
li
C.
2 .
0.
0.
1.
0.
C.
0.
0.
.32
.12
269
CC7E 04
166
028
146
004
OC1
003
002
INITIAL CCNOITION
DISTRIBUTION: hAVELENGTHCNMI
500.
430.
403.
360.
370.
360.
350.
340.
330.
320.
310.
300.
290.
260.
REL.
*
INTENSITY
1.
1.
1.
1.
1.
1.
1.
0.
0.
0.
0.
0.
C.
0.
660
591
466
375
272
125
COO
822
570
318
125
019
C01
0
Kl-0.36 MIN-1
SAMPLING RATE • 2.1C5 1./MIN
27 OC SAMPLES TAKEN
-------
LO
00
-C-
EC -271
TOLUENE #2
1978 MAR 21
CLOCK
TIME
945
luOO
IU15
1030
lots
1100
1115
1*3^
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
TCMIN1
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
Io5.
lao.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
GZCNE
PPM
0.000
O.OC7
0.046
0.130
0.222
0.278
0.296
0.2S3
0.286
0.274
0.269
0.261
0.257
0.252
0.247
0.242
0.239
0.237
0.232
0.230
0.227
0.225
0.222
0.222
0.217
NO
PPM
0.186
0.125
C.043
0.014
C.01C
C.006
C.005
C.C04
0.004
C.005
C.004
C.004
0.004
C.004
0.004
C.004
0.004
C.004
C.004
0.004
C.CC4
0.004
C.004
0.004
0.004
N02-CORR
PFM
0.028
O.C82
0.142
0.129
O.C85
O.OSu
0.025
0.019
0.014
0.011
0.012
0.013
0.011
0.012
0.014
0.015
0.015
0.0 lo
0.013
0.016
0.018
0.017
C.Ola
0.019
0.023
NOA-CCRR
PPM
0.215
0.2C6
0.165
0.143
0.095
0.054
O.C29
0.023
0.018
0.016
0.017
0.017
0.015
O.C17
0.016
0.019
0.019
0.020
C.017
0.020
0.021
0.021
0.021
0.023
0.027
TOLUENE
PPM
1.146
******
0.995
******
0.882
******
0.819
******
0.770
******
0.745
******
0.706
******
0.695
******
0.676
******
0.625
******
0.622
******
0.604
******
0.585
-------
00
EC -271
TOLUENE t^^
197* -MAR 21
CLUCK
TIME
945
100U
1015
1030
1045
1100
1115
1130
1145
12Ju
1215
U30
1243
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
1.50.
165.
ibO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
******
******
******
******
0.64
******
******
******
0.76
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******
******
0.85
******
******
******
******
******
******
******
C.99
******
******
******
1.04
PAN
PPM
C.OOO
******
0.005
******
0.028
******
C.047
******
0.052
******
0.053
******
0.052
******
O.C49
******
0.046
******
C.046
******
0.041
******
C.040
******
0.039
HCHO
PPM
0.004
******
******
******
0.011
******
******
******
0.033
***«.**
******
******
0.03b
*****$
******
******
0.042
******
******
******
0.042
******
******
******
0.028
ACETALO
PPM
0.0011
******
0.0013
******
0.0022
******
0.0033
******
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0.005J
******
0.0078
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0.0070
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0.0085
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0.0075
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0.0075
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0.0106
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0.0161
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0.0021
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0.0026
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0.0025
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0.0026
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0.0027
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0.0027
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0.0024
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0.0024
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0.0025
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0.0026
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0.0032
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0.0023
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0.0072
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0.0114
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0.0143
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0.0138
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0.0133
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0.0138
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0.0158
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0.0148
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0.0170
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0.0180
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0.0143
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0.0246
0-CRESOL
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0.0
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0.0128
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0.0
******
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0.0001
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0.0
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0.0
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6.0
******
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PPM
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0.0
******
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******
0.0024
******
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******
******
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0.0025
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PPM
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0.0
******
******
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******
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******
0.0012
******
******
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******
******
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0.0010
******
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******
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PPM
TENA GC
Ci.0o24
******
******
******
0.0151
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******
******
0.0172
******
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******
0.0149
******
******
******
0.0159
******
******
******
0.0139
******
******
******
******
-------
U)
00
6C -271
TOLUENE »2
1976 MAR 21
TiM£
9*5
1000
1015
1030
10*5
1100
1115
1130
1145
1200
1215
12->0
12*5
1300
1315
1330
1345
1*00
1*15
1*30
14*5
1500
1515
1530
15*5
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T(MIN)
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
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Io5.
180.
195.
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255.
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2fa5.
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315.
330.
3t5.
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CEG F
£4.3
64.3
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85.2
65.2
65.7
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66.0
85.7
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80.5
86.2
86.2
66.2
66.2
66.5
86.2
86.2
REL HUM
t
*2.0
43.5
47.0
46.5
*9.5
50.0
50.0
50.5
50.5
50.5
50.5
50.5
50.5
SO. 5
50.5
50.5
50.5
50.0
50.5
50.0
50.0
50.0
50.0
50.0
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11. S3
******
******
******
11.95
******
******
******
12.1*
******
******
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11.95
******
•***»**
******
******
******
12.50
******
12.47
******
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11.68
RAQIOM
Mvi/CM2
0.27*
0.26*
0.26*
0.26*
0.26*
******
******
0.2t>6
0.266
******
******
******
0.2o6
0.25*
0.256
0.276
0.271
0.276
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0.266
0.283
0.278
0.276
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0.266
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L
20. CO
******
******
******
20. CO
******
******
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20.00
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20.00
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20.00
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20.00
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20.00
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00
tC ~t.TZ
TOLUENE #6
1978 MAR 22
oEGJN IRRADIATION 09155 0.25 INCH PYREX FILTER; TRiCHROIC FILTER OUT
TOLUENE AND OXYGENATES fCNITOREC 8Y 3-PART COLUMN
07*3: EXPAND 0.223 TORR ACETALOEHYDb IN 3.467 L bULB INTO EC
CALCULATED ACtTALCEhYDE INJECTED = 0.292 PPM IN EC
TENAA GC SAMPLES TAKEN BEGINNING AT C955,1015,1115,1215,1312il415£1515
EACH TENAX GC SAKPLE 10.8 L
6RADY 291t DASI6I 1212 £ TECO 14fa-l USED
CO FACTOR 1.W.166; BECKMAN 68CO MANUAL CPcRATIQN
T=0 AT 915 PST
PAN
MCHO
REL INT
TS
REL HUM
SSPQWER
SADiOM
H^O
h4U
N02-CORR
TOLUENE
HCHO
ACETALO
DEC K
*
KM
MW/CM2
PFM
PPM
PPM
PPM
PPM
PPM
* ASSIGNED
SPECTRAL
CAHB#
9
3
*
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCND
INIT CCND
INIT CCND
INIT CCND
3C2.C
45.84
11.93
G.2&2
1.625E 04
C.396
c.ceo
C.580
0.016
C.3&1
INITIAL CONDITION
DISTRIBUTION: WAVELENGTH* MJ REL.
5CO.
430.
403.
38C.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
INTENSITY
1.700
1.629
1.499
1.387
1.. 276
1.114
1.000
0.813
0.563
0.316
0.124
Q.C19
0.001
c.c
Kl=0.35 MIN-i
SAMPLING RATE = 1.927 L/MIN
26 GC SAMPLES TAKEN
-------
QO
oo
EC -272
TOLUENE rib
1978 MAR 22
CLOCK
TIME
915
930
945
looo
lOli
1030
1045
1100
1115
113o
1145
1200
1215
U3d
1245
1300
1315
1330
1345
1403
1415
143J
1445
1500
1515
ELAPSED
T1MINJ
0.
15.
30.
45.
6U.
75.
90.
105.
1*0.
135.
150.
165.
iao.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
(UONE
PPM
0.000
0.000
0.002
0.007
0.017
0.027
0.039
0.059
0.076
0.09b
0.120
0.139
0.161
0.166
0.2C6
0.230
0.257
0.281
0.3C5
0.332
0.354
0.376
0.393
0.403
0.410
NO
PPM
0.396
0.327
0.260
'C.197
C.156
C.1C9
C.084
0.064
0.049
C.045
0.031
C.C2o
0.022
G.022
C.015
0.012
0.011
C.011
C.CC9
0.007
0.006
C.006
0.006
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O.C60
C.139
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0.293
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0.189
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0.147
0.124
0.103
0.084
0.065
0.017
0.032
0.020
0.010
NOX-CORR
PPM
0.478
0.468
0.455
0.436
0.420
0.399
0.379
0.360
0.338
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0.292
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0.252
0.227
0.203
0.181
0.157
0.133
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0.051
0.037
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PPM
0.580
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0.569
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0.538
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0.3o5
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0.347
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0.278
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0.285
-------
EC -ZTi
TOLUENE #6
1978 MAR 22
CLOCK
TIME
915
930
945
1000
luli
10^0
10-0
1100
Ills
1130
1145
UOO
1215
Ii30
U45
1300
1315
IjJO
OJ 134a
« 1400
1415
14 JO
1445
1500
IMS
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0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
2i5.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
******
******
******
******
u.19
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******
******
******
******
******
******
******
******
******
0.37
******
******
******
******
0.45
******
******
******
0.51
PAN
PPM
C.UOO
******
0.007
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O.U19
******
C.029
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C.OtJ
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0.052
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C.059
******
0.073
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0.067
******
C.1CO
******
******
******
C.123
******
0.132
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0.016
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******
******
0.037
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******
******
0.073
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0.065
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O.C77
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0.361
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-------
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-------
ec -272
TOLUENE #6
i978 MAR 22
CLOCK
TIMc
515
930
945
looo
1015
1030
1045
1100
i!15
1130
1145
1200
1215
U30
1245
1JGO
1313
1330
AJ4 j
1400
1415
1430
1445
1500
1513
ELAPSED
T4MINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
153.
165.
ifaO.
195.
213.
225.
240.
255.
270.
ib3.
300.
315.
330.
345.
360.
TS
OEG F
83.5
84.3
84.3
84.5
85.2
85.2
65.5
85.7
65.7
86.0
86.0
86.0
66.2
86.0
86.0
86.2
06.2
66.2
86.0
86.0
66.0
85.7
06.0
85.7
86.0
ft EL HUM
*
41.0
42.5
44.5
• 46.0
47.0
47.5
47.5
47.5
47.5
47.5
48.0
48.0
47.5
47.?
47.5
47.5
47.5
47.5
47.5
47.5
47.5
47.5
47.5
46.0
48.0
SSPOrfER
KM
11.84
******
******
11.91
*¥¥***
******
******
******
******
******
*¥****
**<.***
11.84
******
******
******
11.91
******
******
******
11.97
******
******
******
12.09
RADIOM
MW/CM2
0.274
0.26o
0.261
0.261
0.261
0.256
0.259
0.259
0.261
0.264
0.264
0.264
0.259
0.261
0.25V
0.259
0.264
0.261
0.259
0.261
0.261
0.266
0.264
0.264
0.266
HCHJ VOL
L
20. CO
******
******
******
20.00
******
******
******
20.00
******
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******
20.00
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******
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20.00
******
******
******
20.00
******
******
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20.00
-------
N5
EC -273
TOLUENE »1
1976 MAR 23
BEGIN IRRADIATION 0945; 0.25 INCH PYREX FILTER iTRICHROIC FILTER OUT
TcNAX GC SAMPLES TAKEN CEG1NNING AT 0825,0925,1045r1145,1245,1345tl445tl545
EACH TENAX GC SAMPLE 10.6L
TOLUENE AND OXYGENATES HCMTOREO BY 3-PAR7 COLUMN
BRADY 291, DASlBl 1212, C TECO 14B-1 USED
CO FACTOR 1.45/.164; BECKMAN 6800 MANUAL OPERATION
T=0 AT 945 PST
CALIB*
PAN
HCHO
REL INT
TS
REL HUM
SSPOKER
AADiOM
H20
NO
N02-CORR
TOLUENE
CO
HChO
ACETALO
ACETONE
0-CivESOL
P-CRESOL
BZALdbZN
D£G K
*
KM
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INiT CCNO
JNIT CCND
IMT CCNO
INIT CCNO
1NU CCND
INIT CCNO
IMT CCNO
INIT CCNO
INIT CCNO
INIT CCNO
303.5
13.17
0.2o9
2.C92E
0.096
O.C14
O.J67
O.iif,
O.CC2
0.001
C.C03
O.C01
O.C05
O.CC1
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION:
hAVELENGTH(NM)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
29C.
260.
REL.
Kl*0.35 MIN-1
SAMPLING RATE - i.S54 L/MIN
26 GO SAMPLES TAKEN
INTENSITY
1.735
.655
.530
.404
.280
.114
.COO
0.807
0.564
0.315
0.120
O.C18
O.C01
0.0
-------
UJ
EC -273
TOLUENE *i
1978 MAR 23
CLOCK
TIME
945
1000
1015
1030
10*5
1100
1113
1130
1145
1200
1215
1230
Ii45
1300
1315
1330
1345
1400
1415
1430
1443
1500
151S
1530
1545
ELAPSED
T4MINJ
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
105.
160.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
OZONE
PPM
0.000
0.022
O.OS5
0.166
0.20C
0.215
0.215
0.213
0.210
0.210
0.206
0.2C3
0.2C3
0.195
0.200
C.200
O.lSfa
0.19b
0.195
0.195
0.198
0.193
0.193
0.191
o.iee
NC
PPM
0.096
0.046
0.014
C.OOB
C.C07
0.006
C.CC6
0.006
C.007
C.OC6
C.OC6
C.C06
0.006
C.£C6
0.006
C.006
O.CC6
O.C06
C.C05
0.005
C.OC5
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0.255
-------
VO
EC -273
TGLUeNE #1
1978 MAR Za
CLOCK
TIME
9t3
1000
1015
\ 0 jO
i^j*t 5
1100
1115
1 i 50
1145
12UO
1215
1230
i245
13oO
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
TJMIN)
0.
15.
30.
45.
60.
75.
90.
120.
135.
150.
165.
ISO.
195.
Zl 0.
225.
240.
255.
270.
235.
300.
315.
330.
345.
360.
CO
PPM
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0.36
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0.37
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******
******
******
******
******
******
0.57
******
******
******
0.63
******
******
******
0.67
PAN
PPM
******
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0.008
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C.024
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C.030
O.C32
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0.030
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0.031
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0.031
******
0.0^9
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C.028
******
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0.028
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******
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0.0116
-------
EC -273
TOLUENE HI
1978 MAR 23
CLOCK
TIME
943
1000
1015
1030
1J45
110J
1115
1130
1145
i^Od
1215
1230
1245
1300
1315
1330
1345
1400
^ 1415
5 1430
1445
15^0
1515
1530
1545
ELAPSED
T(MIN1
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
24C.
255.
270.
265.
300.
315.
330.
345.
360.
TS
CEG f
65.0
68.4
87.7
87.4
87.0
66.2
87.7
66.2
69.2
87.7
86.5
86.5
86.5
87.0
66.7
66.7
87.0
U6.7
86.0
66.0
8o.O
64.8
64.8
65.0
84.8
REL HUM
*
41.5
42.5
44.0
45.0
46.5
47.0
48.0
48.5
48.0
46.0
49.0
50.5
51.0
51.5
51.5
51.5
52.0
52.0
52.0
52.0
52.0
52.0
52.0
52.0
52.0
SSFCWER
Kta
13.30
******
13.17
******
13.19
******
******
13.55
13.48
******
******
******
13.34
******
******
******
13.56
******
******
******
13.84
12.02
******
******
12.24
RAOIOM
MWCM2
******
0.271
0.261
0.256
0.256
0.269
0.2&9
0.266
0.264
0.261
0.264
0.261
0.259
0.269
0.269
0.269
0.266
U.266
0.313
C.310
0.315
0.261
0.264
0.266
0.266
HCHO VOL
L
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20. CO
******
******
******
20. CO
******
******
******
20.00
-------
U)
EC -27o
PROPENE #6
1978 MAR 29
BEGIN IRRADIATION 0915; 0.25 INCH PYkEX FILTER; TRICHR01C FILTER QdT
oRAOY 291t tASIBI 1212 t TECO 148-1 USEC
CJ FACTOR: 1.45/.086
T=0 AT 930 PST
CAUB#
PAN
hCHO
REL INT
TS
REL HUM
SiPGwER
RAOIOM
M20
NO
N02-COKR
PKOPcNc
CO
hCHO
ACETALO
ACETONE
D£G K
*
KM
MW/CM2
PPh
PPM
PPM
PPM
PPH
PPH
PPM
PPH
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
IMT CCNu
IN1T CCNC
IMT CCNO
IMT CCND
IMT CCND
INIT CCNO
IMT CCNO
302.7
12.il
C.262
1.837E 04
0.410
0.106
0.540
C.260
C.C15
0.001
C.C01
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION:
hAVELENGTH(NM)
500.
430.
403.
360.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
REL.
Kl=0.35 MIN-1
SAMPLING RATE « 1.732 L/MIN
50 GC SAMPLES TAKEN
INTENSITY
1.703
1.617
1.4d7
1.389
1.274
1.106
1.000
0.802
'0.555
0.311
0.119
0.017
0.001
0.0
-------
EC -276
PROPENE «6
1973 MAR 29
CLOCK
TIME
907
930
9*3
1000
1015
1U30
10*5
1100
1115
1130
11*5
IcOO
1215
U30
1245
13JJ
1315
1330
13*5
i*UO
1*15
1*30
i**5
1500
1515
1530
ELAPSED
TtMlNJ
-23.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
i35.
300.
315.
330.
3*5.
360.
OICNE
PPM
******
0.000
0.000
0.000
0.002
0.007
0.015
0.022
0.032
0.05*
0.073
0.095
0.120
0.1*2
0.169
0.193
0.213
0.232
0.25*
0.271
0.293
0.310
0.325
0.3*2
0.359
0.374
NO
PPM
******
C.*10
C.3*8
C.299
0.2*9
0.202
C.162
C.125
C.OS8
C.073
0.056
C.C51
O.C35
C.031
C.027
0.022
C.020
0.016
C.016
0.012
C.C11
C.010
C.013
C.007
0.009
0.009
N02-C3RR
PPM
******
0.1C6
0.158
0.205
C.250
0.2c7
0.313
0.236
0.35*
0.36*
0.366
0.353
0.353
C.339
0.322
0.3C5
0.2S1
0.275
0.255
0.235
C.217
0.2C2
0.1E4
0.166
0.150
0.136
NOA-CORfc
PPM
******
0.517
0.506
0.503
0.*S9
0.*87
0.*73
0.*62
C.*50
0.438
O.*20
0.40*
C.3B9
0.368
0.3*8
0.326
0.3Cd
0.2o9
0.268
0.2*7
0.228
0.210
0.196
0.173
0.157
0.1*1
PROPENE
PPM
0.535
0.5*0
0,*98
0.467
******
0.400
0.365
0.336
0.310
0.284
0.257
0.232
0.208
0.183
0.161
0.1*0
0.124
0.106
0.091
0.077
0.065
0.055
0.0*6
0.038
0.031
0.026
-------
EC -£76
PROPENE #6
1978 MAR 29
us
*£>
CO
CLOCK
TIME
907
9JO
945
iuOJ
1015
Iu30
10*5
1100
1115
1130
11*5
uoo
U15
U30
U45
1300
1315
1330
1345
itOO
If la
1*30
14-o
1500
1515
1530
ELAPSED
TIMIN)
-23.
0.
15.
30.
45.
bO.
75.
90.
105.
120.
135.
15C.
165.
160.
195.
210.
225.
240.
255.
270.
2d5.
300.
315.
330.
345.
360.
CO
PPM
******
0.26
******
******
******
0.27
******
******
******
0.27
******
******
******
0.37
******
******
******
0.45
******
******
******
******
0.45
******
******
0.66
PAN
PPM
******
0.000
******
O.OGO
******
0.002
******
C.007
******
0.013
******
0.021
******
C.030
******
0.044
******
******
******
0.067
******
0.078
******
******
******
C.100
HCHQ
PPM
***«.**
0.015
******
******
******
0.062
******
******
******
0.115
******
******
******
0.1&3
******
******
******
0.159
******
******
******
0.146
******
******
******
0.192
ACETALO
PPM
******
0.001
******
0.042
******
0.087
******
0.120
******
0.151
******
C.161
******
0.182
******
0.153
******
0.1S2
******
0.160
******
O.lbi
******
0.167
******
0.156
PROPALD
PPM
******
******
******
0.0001
******
O.OOOo
******
0.0008
******
0.0012
******
0.0012
******
0.0017
******
0.0016
******
0.0020
******
0.0014
******
0.0025
******
0.0025
******
0.0025
ACETONE
PPM
******
0.0009
******
0.0006
******
0.0016
******
0.0021
******
0.0028
******
0.0029
******
0.0052
******
0.0024
******
0.0063
******
0.0029
******
0.0072
******
0.0080
******
0.0061
8UTYRAL
PPM
******
0.0001
******
******
******
0.0001
******
0.0002
******
0.0003'
******
0.0004
******
0.0007
******
0.0006
******
0.0010
******
0.0008
******
0.0013
******
0.0014
******
0.0014
MEK
PPM
******
0.0001
******
O.J001
******
0.0001
******
0.0001
******
0.0001
******
0.0001
******
0.0002
******
0.0002
******
0.0002
******
0.0002
> ******
0.0003
******
0.0004
******
0.0004
PROX
PPM
******
0.0000
******
******
******
******
******
******
******
******
******
******
******
O.OOU7
******
******
******
0.0011
******
******
******
0.0010
******
0.0016
******
0.0013
ME-N
PPM
******
0.0
******
0.0
******
0.0
******
0.0001
******
O.u004
******
0.0005
******
u.OOui
******
0.0009
******
0.0009
******
O.OOil
******
0.0011
******
0.0013
******
0.0013
-------
OJ
EC -276
PROPcNE #6
1978 MAR 29
CLOCK
TIMc
907
930
945
IGuu
1015
1030
1045
UOO
1115
1120
1145
UOO
1215
1230
1245
1300
1315
1330
1345
1400
1*15
1430
1445
15JO
15*5
1530
ELAPSED
T(MIN)
-23.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
15C.
165.
IdO.
195.
21C.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
TS
OEG F
******
85.0
63.8
83.8
84.5
85.0
85.5
65.7
85.7
e>5.7
C6.0
03.7
60.0
a'j. 7
8o.O
66.0
-------
o
o
EC -277
PROPENE #1
1978 MAR 30
6E61N IRRADIATION 0915; 0.25 INCH PYREX FILTER i TRICHRCIC FILTER OUT
6RAOY 2S1, DASIiU 12U 6 TECO 14B-1 USED;
CO FACTOR: 1.4s/.087
T=0 AT 915 PST
PAN
HCriO
REL INT
TS
REL MUM
SSPJhER
RAJIOM
H20
NO
NG2-CGRK
PKOPENc
CO
hCrtO
ACETALO
riCETCNE
OEG K
*
Kh
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
* ASSIGNED
SPECTRAL
CAL1B*
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CQNO
INIT CCNO
INIT CCND
INIT CCfvD
INIT CCNtl
INIV CCNO
2C2.6
47
12
C.
1.
0.
C.
0.
C.
C.
0.
0.
.14
.21
262
939E 04
098
010
5
-------
EC -277
PROPENE *1
197S MAR 30
CLOCK
TIME
903
915
930
945
1000
1015
1030
1045
1100
Ilia
1130
1145
1200
±215
1230
lk<>5
1300
1315
133J
13*5
1400
1415
1430
1445
1500
1515
ELAPSED
TtMINJ
-12.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
15C.
165.
IttO.
195.
210.
225.
240.
255.
270.
2e5.
300.
• 315.
330.
345.
360.
OZONE
PPM
******
O.COC
0.012
0.056
0.125
0.193
0.239
0.278
0.298
0.306
0.313
0.31U
0.310
0.305
0.300
0.300
C.296
0.296
0.293
0.293
0.293
0.293
0.293
0.291
0.293
0.296
NO
PPM
******
0.098
C.046
' C.018
C.011
O.OC8
C.C07
0.007
0.006
G.006
G.006
0.005
0.006
C.OC5
0.005
G.005
C.l<05
O.OC5
0.005
0.004
C.004
C.004
0.004
C.004
C.004
0.004
N02-CORR
PPM
******
0.010
0.058
0.065
O.C77
O.C67
O.C55
0.045
0.036
0.028
0.019
0.013
0.013
0.012
0.012
0.012
0.014
0.016
0.015
0.012
0.016
0.014
0.014
0.014
0.013
0.014
NOX-CORR
PPM
******
0.108
0.104
0.103
0.087
0.075
0.063
0.052
0.042
0.033
0.026
0.018
0.018
0.017
0.018
0.017
0.019
0.020
0.018
0.016
0.020
0.018
0.018
0.018
0.017
O.Olb
PROPENE
PPM
0.559
0.564
0.457
0.453
0.388
0.336
0.278
0.232
0.195
0.166
0.142
0.123
0.106
0.093
0.081
0.071
0.062
0.055
0.048
0.042
0.036
0.032
0.028
0.024
0.021
0.019
-------
O
to
EC -277
PROPfcNE #1
197B MAR 30
CLOCK
TiME
903
915
930
y<*5
1000
iuls
lOiJ
*o45
ilLIU
1115
1130
Ht5
1200
Ul3
1230
1*45
1300
lJi5
1330
1345
1400
1415
1430
1445
1500
1515
ELAPSED
TIMiNJ
-iZ.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
IBO.
195.
210.
225.
240.
255.
270.
235.
300.
315.
330.
345.
360.
CO
PPM
******
0.23
******
******
******
0.32
******
******
******
C.3S
******
******
******
0.48
******
******
******
0.60
******
******
******
0.66
******
******
******
0.60
PAN
PPM
******
0.000
******
0.003
******
0.021
******
******
******
0.052
******
0.067
******
C.069
******
0.070
******
0.069
******
0.074
******
0.074
******
0.075
******
0.077
HCHO
PFM
******
O.CC5
******
******
******
0.127
******
******
******
0.212
******
******
******
0.212
******
******
******
******
******
******
******
0.195
******
******
******
0.169
ACETALO
PPM
******
0.001
******
0.068
******
0.135
******
0.172
******
0.166
******
0.191
******
0.192
******
0.189
******
0.190
******
0.176
******
0.168
******
0.170
******
0.131
PROPALD
PPM
******
******
******
0.0002
******
0.0012
******
0.0014
******
0.0012
******
0.0014
******
0.0015
******
0.0016
******
0.0015
******
0.0017
******
0.0016
******
0.0017
******
0.0016
ACETCNE
PPM
******
o.oooa
******
0.0023
******
0.0062
******
0.0065
******
0.0041
******
0.0043
******
0.0066
******
O.OOU3
******
0.0080
******
0.0072
******
0.0040
******
0.0065
******
0.0033
OUTYkAL
PPM
******
C.OOJ1
******
G.U003
******
0.0007
******
0.0010
******
0.0010
******
0.0011
******
0.0012
******
O.OU13
******
0.0012
******
0.0012
******
0.0012
******
0.0013
******
0.0009
MEK
PPM
******
0.0001
******
0.0001
******
0.0001
******
0.0002
******
0.0002
******
0.0002
******
U.0003
******
0.0003
******
0.0003
******
0.0003
******
0.0004
******
0.0004
******
0.0003
PROX
PPM
******
0.0000
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
-------
-p-
o
u>
cC -277
PROPcfME »1
1978 MAR 30
CLOCK
TIME
903
915
930
9*5
1000
1015
Iu30
1043
110J
1115
1130
11 45
UOO
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
ELAPSED
TIMINJ
-12.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
Io5.
180.
195.
210.
225.
240.
c55.
27C.
265.
300.
315.
330.
345.
3oO.
TS
CEG F
******
64.5
U4.0
64.8
65.0
66.0
86.2
66.0
85.7
65.7
86.2
86.2
B6.2
oo.O
66.5
66.0
86.2
d6.2
86.5
86.7
b6.5
66.2
66.5
86.2
66.7
86.2
REL HUM
*
******
42.0
43.0
45.5
46.5
47.5
46.0
46.5
49.0
49.0
49.0
49.0
49.0
49.5
49.5
49.5
49.5
49.5
49. S
49.0
-9.0
49.0
49.0
49.0
49.0
49. C
SSPOwER
KM
******
12.10
12.17
******
******
li.02
******
******
******
12.41
******
******
******
12. 14
******
******
******
12.26
******
******
******
12.38
******
******
******
12.30
RAD13M
MH/CM2
******
0.259
0.2o9
******
******
0.256
0.271
0.264
0.261
0.264
0.261
0.259
0. 2t>4
0.264
******
******
******
0.261
0.269
******
******
0.264
0.250
******
******
0.261
HCHO VOL
L
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
******
******
******
******
20.00
******
******
******
20.00
-------
-p-
o
EC -278
PHOPENE #2
1978 MAR 31
BeOlN IRRADIATION 0915! O.25 INCH PYREA FILTERS TRICHR01C FILTER OUT
oRAOY 291, DASIBI 1212 £ TECO 14B-1 USED
CO FACTOR: 1.45/.066; 6ECKMAN 6800 ON MANUAL OPERATION
T«0 AT 915 PST
PAN
HCHO
R'cL iNT
TS
REL HUM
SSPOhER
RADIQM
H20
NO
NJ2-CGRR
PKOPENE
HCHO
DEC K
*
KM
CALIB*
9
3
4
AVERAGE 302.7
AVERAGE 46.30
AVERAGE 12.35
Mrf/CM2 AVERAGE C.263
PPM
PPM
PPM
PPM
PPM
* ASSIGNED
SPECTRAL
AVERAGE 1.9uuE 04
INIT
IMT
INIT
INIT
INITIAL
DISTRIBUTION:
CCND 0.366
CCND 0.126
CCND 1.016
CCND 0.008
CONDITION
hAVELENGTHlNMJ REL.
SCO.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
INTENSITY
1.707
1.642
1.511
1.406
1.271
1.115
l.COO
0.607
0.556
0.316
0.120
0.017
0.0
Kl=0.35 MIN-1
SAMPLING RATE » 1.733 L/MIN
52 GC SAMPLES TAKEN
-------
o
Ui
EC -278
PROPENE *2
1978 MAR 31
CLOCK
TIME
900
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1330
1245
1300
1315
133J
1345
1400
1415
1430
1445
1500
1515
ELAPSED
TiMINI
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
clO.
£15.
240.
255.
^70.
205.
300.
315.
330.
345.
360.
OICNE
PPM
******
0.000
0.000
0.015
0.056
0.134
0.225
0.330
0.420
0.493
0.542
0.586
0.611
0.623
0.625
0.620
0.611
0.601
0.594
0.586
0.581
0.574
0.569
0.564
0.564
0.559
NO
PPM
******
C.366
0.248
•0.151
0.077
0.037
0.022
0.015
C.011
0.010
0.007
0.006
0.010
C.006
O.OC6
C.C06
0.006
0.006
0.006
0.005
0.005
0.005
0.005
0.005
0.005
0.004
N02-CORR
PPM
******
0.123
0.234
0.320
0.371
0.363
0.356
0.315
0.259
0.201
0.140
0.064
0.047
0.020
0.010
-O.C01
-O.C15
-0.021
-0.025
-0.019
-0.015
-O.C09
-0.018
-0.024
-0.020
-0.017
NOX-CORR
PPM
******
0.498
0.482
0.473
0.448
0.419
0.377
0.329
0.268
0.209
0.145
0.089
0.057
0.024
0.015
0.004
-0.011
-0.018
-0.020
-0.018
-0.012
-0.007
-0.013
-0.019
-0.016
-0.015
PROPENE
PPM
LOOP
0.999
1.016
0.929
0.848
0.773
0.683
0.582
******
******
0.296
0.226
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
PROPENE
PPM
TRAP
******
******
******
******
******
******
******
******
******
******
******
0.181
******
0.107
0.084
O.C61
0.052
0.041
0.034
0.027
0.023
0.018
0.015
0.012
0.010
0.008
-------
o
ON
EC -278
PROPENE *2
1978 MAR 31
CLOCK
TIME
900
913
930
945
1000
1015
1030
1045
11UO
1115
1130
1145
1200
1215
1230
1245
13uO
1315
Ii30
1345
1400
1415
1430
1445
1500
1515
ELAPSED
T(HIN)
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
0.03
******
******
******
******
0.12
******
******
******
0.27
******
******
******
0.49
******
******
******
0.66
******
******
******
0.79
******
******
******
0.86
PAN
PPM
******
0.000
******
0.003
******
0.021
******
0.056
******
0.109
******
0.185
******
0.225
******
0.235
******
0.260
******
******
******
0.235
******
0.245
******
0.240
HCHO
PPM
******
J.OQB
******
******
******
0.261
******
******
******
0.417
******
******
******
0.438
******
******
******
0.423
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******
******
0.395
******
******
******
0.373
ACETALD
PPM
******
0.000
******
0.113
******
O.lbd
******
0.275
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0.336
******
0.378
******
0.323
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0.317
******
0.348
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0.258
******
0.277
******
0.300
******
0.234
PROPALO
PPM
******
0. OJC1
******
0.0006
******
0.0010
******
0.0023
******
0.0018
******
0.0024
******
0. OU13
******
0.0018
******
0.0037
******
0.0012
******
0.0018
******
0.0029
******
0.0028
ACETONE
PPM
******
0.0003
******
0.00-11
******
O.OOld
******
0.0033
******
0.0056
******
0.0077
******
0.0053
******
0.0049
******
0.0087
******
0.0053
******
0.0046
******
0.0123
******
0.0132
BUTYRAL
PPM
******
0.0000
******
0.0001
******
0.0003
******
0.0007
******
0.0011 '
******
0.0015
******
0.0013
******
0.0014
******
0.0020
******
0.0014
******
0.0014
******
0.0021
******
0.0021
MEK
PPM
******
0.0000
******
0.0000
******
0.0001
******
0.0001
******
0.0001
******
0.0001
******
O.OuOl
******
******
******
0.0003
******
0.0002
******
0.0003
******
0.0003
******
0.0005
PROX
PPM
******
0.0
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0018
ME-N
PPM
******
0.0
******
0.0
******
0.0004
******
0.0009
******
0.0011
******
0.0006
******
0. JOi/9
******
O.OOOo
******
0.0012
******
******
******
0.0012
******
0.0009
******
0.0009
-------
o
-J
EC -278
PROPENE #£
1978 HAK 31
CLOCK
TIME
900
915
930
945
10 JO
1015
iu->0
10*5
1100
1115
1130
1145
1200
1215
1330
1243
1300
1315
1330
1345
1400
1415
1440
1445
1500
1515
ELAPSED
T(MIN)
-15.
0.
15.
30.
45.
60.
75.
90.
105.
UO.
135.
150.
165.
160.
1S5.
210.
225.
240.
255.
270.
,285.
300.
315.
330.
345.
360.
TS
DEG F
******
85.5
84.0
84.0
84.3
85.0
85.5
85.7
85.2
85.7
85.7
fi5.2
85.5
85.7
85.7
85.7
85.7
85.7
86.0
66.2
85.7
8<>.0
85.5
85.7
86.0
86.0
REt HUM
X
******
41.0
42.5
45.0
46.5
47.5
48.0
48.5
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.5
49.5
45.5
49.0
49.5
49.0
49.0
49.0
49.0
49.0
SSPGfrER
Kh
******
12.21
******
******
******
12.19
12.41
******
******
12.34
******
******
******
12.38
******
******
******
12.46
******
******
******
12.38
******
******
******
12.41
RADIQM
MW/CM2
******
0.261
0.201
0.261
0.256
0.261
******
******
******
0.266
******
******
******
0.264
0.261
0.261
0.261
0.266
0.266
0.261
0.261
0.261
0.264
******
******
0.266
HCHO VOL
L
******
cO. CO
******
******
******
2o.OO
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20. 00
******
******
******
20.00
-------
EC -27V
PROPENE »3
1978 APR 3
o£GIN IRRADIATION 0930; 0.25 INCH PYREA FILTER; TRICHROIC FILTER OUT
BRADY 291, BAS1BI 1212 £ TECO 148-1 USED
CO FACTOR 1.45/.101
T«0 AT 930 PST
PAN
HCHO
REL INT
CALIB*
9
3
4
O
00
TS
REL HUH
SSPOrtER
RADIOS
H20
NO
N02-CORR
PROPENE
HCriO
ACETALD
ACETONE
DEG K
*
KM
HW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
1NIT COND
INIT CCNO
INIT CQNO
INJT CCND
IMT COND
INIT CCNO
302.5
48.11
12. Jo
0.262
l.'j'.ot
C.730
0.244
1.144
0.016
C.OC1
0.002
04
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: hAV£LEN6TH(NM)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
Kl=0.35 M1N-1
SAMPLING RATE « 1.732 L/MIN
50 GC SAMPLES TAKEN
REL.
INTENSITY
1.748
1.666
1.524
1.417
1.295
1.125
1.000
0.501
0.562
0.315
0.120
0.018
0.001
0.0
-------
EC -279
PROPENE #3
197o APR 3
CLOCK
TIME
915
930
945
1000
1015
10-)0
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
T(MIN)
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
OZONE
PPM
******
0.000
0.000
0.000
0.000
0.002
0.012
0.034
0.068
0.110
0.164
0.225
0.276
0.330
0.381
0.425
0.467
0.506
0.540
0.569
0.598
0.628
0.645
0.662
0.674
0.677
HO
PPM
******
0.730
0.613
0.498
0.396
0.303
C.222
0.154
0.100
0.078
0.049
Q.C44
0.044
C.C32
0.020
0.017
0.012
0.012
0.010
0.007
C.CC7
0.007
0.007
O.OC7
0.007
0.007
N02-CORR
PPM
******
0.244
0.343
0.448
0.530
0.595
0.655
0.653
0.7C5
J.69o
0.671
0.621
0.569'
0.512
0.4o7
0.4C6
0.339
0.274
0.259
0.251
0.183
0.116
0.056
-O.U02
-0.009
-0.011
NOA-CORR
PPM
******
0.977
0.957
0.946
0.924
0.898
0.875
0.842
0.805
0.771
0.722
0.672
0.611
0.547
0.479
0.416
0.349
0.283
0.268
0.256
0.191
0.123
0.061
0.003
-0.004
-0.006
PROPENE
PPM
LOOP
1.152
1.144
1.058
0.983
0.923
0.855
0.788
0.728
0.657
0.588
0.519
0.455
0.379
0.324
0.262
******
******
******
******
******
******
******
******
******
******
******
PROPENE
PPM
TRAP
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.225
0.179
0.141
0.111
0.087
0.068
0.052
0.040
0.030
0.024
0.018
-------
EC -279
PROPcNE *3
1978 APR 3
CLOCK
TIME
915
9 JO
9*5
lOuO
1015
1030
1045
1100
1115
1130
1145
UOO
1215
1230
1245
1300
1315
1330
1345
1400
14i5
1450
1445
1500
1515
1530
ELAPSED
TiMIN)
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345,
360.
CO
PPM
0.14
******
******
******
******
0.32
******
******
******
******
******
******
******
0.79
******
******
******
0.95
******
******
******
1.25
******
******
******
1.48
PAN
PPM
******
0.000
******
0.001
******
O.OCa
******
0.019
******
i-.u38
******
O.Obd
******
C.1C7
******
0.150
******
C.202
******
0.160
******
******
******
0.340
******
0.335
HChtJ
PPM
******
0.016
******
******
******
0.192
******
******
******
0.348
******
******
******
0.465
******
******
******
0.522
******
******
******
0.471
******
******
******
0.436
ACETALD
PPM
******
0.001
******
0.095
******
0.175
******
0.250
******
0.306
******
0.370
******
0.425
******
0.434
******
0.470
******
0.369
******
0.325
******
0.308
******
0.284
PRQPALO
PPM
******
0.0004
******
0.0007
******
0.0015
******
0.0023
******
0.0029
******
0.0030
******
0.0052
******
0.0035
******
0.0048
******
0.0018
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0.0045
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0.0020
******
0.0024
ACETONE
PPM
******
0.0017
******
0.0007
******
0.0010
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0.0017
******
0.0021
******
0.0051
******
0.0079
******
0.0071
******
0.0163
******
0.0065
******
0.0067
******
0.0078
******
0.0093
BUTVRAL
PPM
******
0.0004
******
0.0001
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0.0001
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0.0002
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******
0.0006
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0.0004
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0.0011
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******
0.0009
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0.0012
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0.0013
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0.0016
MEK
PPM
******
0.0001
******
0.0001
******
0.0001
******
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******
0.0001
******
******
******
0.0001
******
0.0002
******
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******
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0.0002
******
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******
0.0003
PROX
PPM
******
******
******
******
******
******
******
******
******
0.0017
******
J.0033
******
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******
******
******
0.0068
******
0.0034
******
0.0015
******
0.0029
******
0.0034
ME-N
PPM
******
0.0
******
0.0
******
U.U004
******
0.0009
******
0.0016
******
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******
0.0031
******
0.0031
******
0.0032
******
0.0019
******
0.0033
******
0.0036
******
0.0036
-------
EC -279
PROPENE *3
1978 APR 3
CLOCK
TIME
915
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1..15
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSEC
TJMIN)
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DE6 F
******
04.3
84.3
83. 8
84.3
84.5
85.0
85.2
65.5
85. 5
d5.7
86.0
85.5
86.0
85.7
86.0
65.7
85.5
85.7
86.0
65.7
85.7
66.2
85.7
86.0
85.7
REL HUH
*
******
41.0
42.5
45.0
46.5
47.5
48.0
48.5
49.0
49.0
49.5
49.5
49.5
49.5
49.5
49.5
49.5
50.0
50.0
50.0
50.0
49.5
50.0
50.0
49.5
49.5
SS POWER
Kto
******
12.26
******
******
******
12.30
******
******
******
12.34
******
******
******
12.45
******
******
******
12.34
******
******
******
12.41
******
******
******
12.52
RAOIOH
MW/CM2
******
0.254
0.261
0.266
0.256
0.259
0.259
0.266
0.261
0.256
0.269
0.261
******
0.264
******
******
******
0.266
******
******
0.234
0.264
******
******
******
0.269
HCHO VOL
L
******
20. CO
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -285
ETHfcNE
1976 APR 25
IRRADIATION 0945; 0.25 INCH PYREX FILTER; TRICHROIC FILTER OUT
BRAD* 291. DAI SSI 1212 £ TECO 14B-1 USED
CO FACTOR 1.45/14.7
T«0 AT 945 FST
CALIB*
PAN
HCHO
REL INT
TS
AEL HUM
SSPDhER
RA01CM
H20
NJ
NQ2-CORR
cTHENE
HChO
ACcTALD
ACtTCNE
DEG K
%
KM
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
INIT CCNO
1N1T CCNO
INIT C2NO
IMT CCISO
INIT CCNO
303.2
li.70
1.851E
0.7S1
0.215
C.C15
O.C01
0.001
N>
ASSIGNED INITIAL CCMC1TION
SPECTRAL DISTRIBUTION:
kAVELENGTh(NK)
sec.
430.
403.
380.
370. .
36C.
350.
340.
330.
320.
31C.
300.
i90.
260.
REL. INTENSITY
1.616
1.589
1.493
1.400
1.282
1.114
1.000
0.807
0.559
'0.312
0.119
0.017
0.001
0.0
Kl«0.39 MIN-1
SAMPLING RATE « 1.730 L/MIN
47 aC SAMPLES TAKEN
-------
-C-
H"
U>
EC -id5
ETHENE
1978 APR 25
CLOCK
TIME
930
545
iouO
li>15
1030
1045
1100
1115
UaO
1145
1200
1215
1230
1245
1300
1315
IjjO
1345
1100
1*15
1430
1445
15UJ
1515
1530
1545
ELAPSED
TiMIN)
-15.
0.
15.
30.
45.
oC.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
(ULNE
PPM
******
0.000
o.oco
0.000
o.oco
o.uoo
0.002
0.01C
0.017
0.029
0.051
0.076
0.1C8
0.149
0. 1S3
0.242
0.28o
0.349
0.403
0.469
0.537
0.606
0.677
0.738
0.799
0.840
NO
PPM
******
0.791
0.706
• C.625
C.542
0.447
0.371
C.332
C.237
0.181
C.134
0.098
0.071
C.051
C.042
C.032
0.022
C.020
0.015
C.015
C.010
C.GC7
C.005
C. OC5
C.CC2
0.007
N02-CQRR
PPM
***¥**
o.iis
0.285
€.356
0.412
C.500
0.556
0.576
0.646
0.680
0.697
0.709
0.711
0.6
-------
EC -285
ETHENE
1978 APR 25
CLOCK
TIME
930
943
1000
1015
1030
1045
1100
1113
1130
1145
1200
1215
1230
1243
1300
1315
1330
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1400
1415
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1500
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T(HIN)
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135.
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165.
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0.0007
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0.0101
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0.0006
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0.0008
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0.0006
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0.0033
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******
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0.0011
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0.0011
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0.0017
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0.0017
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0.0038
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0.0031
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0.0061
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0.0120
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0.0086
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0.0178
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0.0146
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0.0140
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******
0.0001
******
0.0001
******
0.0002
******
0.0002
******
0.0003 '
******
0.0003
******
0.0007
******
0.0009
******
0.0016
******
0.0014
******
0.0023
******
0.0021
******
0.0028
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PPM
******
0.0002
******
0.0001
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0.0001
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0.0000
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******
******
0.0000
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0.0000
******
******
******
0.0001
******
******
******
******
******
******
******
******
ME-N
PPM
******
0.0
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0.0
******
0.0
******
0.0
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6.0003
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******
0.0007
******
0.0007
******
0.0009
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0.0009
******
0.0009
-------
Ul
EC -285
ETHENE
1970 APR 25
CLOCK
TIME
930
945
1000
1015
1030
1045
1100
1115
1130
llfi>
1200
1215
1230
1243
1300
1315
1330
1345
1400
1415
1430
14*5
1500
1515
1530
1545
EcAPScC
TIMINJ
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEG F
**-;***
b4.5
85.2
65.2
65.2
86.0
86.2
66.7
66.7
8c.7
66.7
87.0
66.7
86.7
66.7
86.7
87.0
67.0
87.2
87.0
87.0
87.0
86.7
67.0
67.0
87.2
ft EL HUM
S
******
41.0
42.5
45.0
47.0
48.0
46.5
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
48.5
48.5
SSPOWER
Kh
******
12.75
12.64
******
******
12. 5o
******
******
******
12.64
******
******
******
12.63
******
******
******
12.64
******
******
******
12.75
******
******
******
13.00
RADICM
Mh/CM2
******
0.274
0.271
0.261
0.261
0.259
******
******
******
0.266
******
******
******
0.261
0.261
0.261
0.261
0.259
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******
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0.264
0.261
0.261
0.266
0.266
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******
20.00
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20.00
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20. CO
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20.00
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20. 00
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******
20. CO
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******
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20.00
-------
EC -286
ETHENE
1976 APR 26
BEGIN IRRADIATION 0915; 0.25 INCH PYREX FILTER; TRICHR01C FILTER OUT
BRADY 291. OAIS6I 1212 £ TECO 146-1 USED
Cu FACTOR 1.45/15.3
T=0 AT 915 PST
CALIB*
PAN
HCHO
REL INT
TS
REL HUM
SSPonEK
MlJlCH
H2J
NJ
NQ2-CORR
ETwcNc
HCriC
ACETALO
ACETONc
DEG K
S
KM
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
IMT CCND
INIT CCND
INIT CCND
INIT CCND
INIT CCNO
302.9
43.05
12.69
0.263
1.843E 04
C.708
0.237
3.756
0.014
C.C01
0.001
ASSIGNED INITIAL CCNCIT10N
SPECTRAL DISTRIBUTION: hAVELENGTWNMJ
500.
430.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
K.l-0.39 MIN-1
SAMPLING RATE - 1.731 L/MIN
48 GC SAMPLES TAKEN
REL.
INTENSITY
1.738
701
538
393
241
139
000
0.818
0.566
0.316
0.119
0.017
0.0
-------
EC -2*16
ETHENE
1978 APR 26
CLOCK
TIME
900
915
930
5*5
1000
1015
1030
10*5
1100
1115
1130
11*5
1200
U15
1230
12*5
1300
1315
1330
13*5
l*Ju
1*15
1*30
i**5
1500
1515
ELAPSED
TJMINJ
-15.
0.
15.
30.
*5.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
2*0.
255.
270.
265.
300.
. 315.
330.
3*5.
360.
OZCNE
PPM
******
0.000
0.000
0.005
0.027
0.100
0.415
0.366
0.537
0.716
0.870
0.99*
1.065
1.080
1.067
1.0*1
1.00*
0.962
0.916
0.875
0.838
0.80*
0.767
0.735
0.706
0.682
NO
PPM
******
C.708
C.520
' 0.320
0.171
0.076
C.0*2
0.020
C.012
C.01Q
0.002
0.005
0.002
0.005
0.002
C.005
C.CC2
0.002
0.007
0.002
C.002
C.UO2
C.C02
C.002
0.002
0.002
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PPM
******
O.i.37
O.*05
0.579
0.7C3
0.75o
0.7*3
0.6S6
C.620
0.516
0.410
0.31*
0.237
0.177
0.1*7
0.12*
0.11,6
0.1C8
0.106
0.100
C.100
O.OS9
O.C59
0.096
O.C96
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PPM
******
0.9*7
0.923
0.899
0.871
0.832
0.782
0.713
O.o27
0.521
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0.31*
0.2*0
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0.1*7
0.127
0.116
0.108
0.110
0.103
0.100
0.059
0.099
0.096
0.096
0.095
ETHENE
PPM
3.812
3.758
3.651
3.511
3.338
3.2*7
3.07*
2.908
2.76*
2.56*
2.382
2.167
1.972
1.819
1.685
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1.350
1.322
1.239
1.189
1.129
1.058
1.019
0.972
0.927
-------
-O
I-1
oo
EC -286
ETHENE
1978 APR 26
CLOCK
TIME
900
915
930
945
lOuO
1015
1030
1045
1100
1115
1130
1145
1200
U15
1230
1245
13JO
1315
1330
1345
1400
Ifl5
1430
1445
1500
1515
ELAPSED
TIM1NJ
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
15J.
163.
IfaO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
0.18
******
******
******
******
0.24
******
******
******
0.48
******
******
******
1.02
******
******
******
1.47
******
******
******
1.84
******
******
******
2.15
PAN
PPM
******
0.000
******
0.000
******
0.001
******
C.002
******
0.003
******
0.005
******
C.OC8
******
C.009
******
0.011
******
0.011
******
0.012
******
0.013
******
G.014
HCHO
PPM
******
0.014
******
******
******
0.571
******
******
******
l.llo
******
******
******
1.425
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******
******
1.423
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******
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1.350
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1.227
ACcTALD
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******
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******
0.0014
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0.00<:2
******
O.C041
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O.OC68
******
O.C093
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0.0107
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0.0127
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0.0147
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0.0161
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0.0150
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0.0175
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0.0174
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PPM
******
o.ooco
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******
******
u.OOOl
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0.0029
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******
0.0022
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0.0041
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0.0027
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0.0048
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0.0056
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0.0028
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O.OOOB
******
0.0015
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0.0026
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0.0117
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0.0145
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0.0206
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0.0169
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0.0227
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0.0161
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0.0242
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0.0126
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0.0208
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0.0111
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PPM
******
0.0001
******
0.0001
******
0.0003
******
0.0013
******
0.0021 '
******
0.0033
******
0.0031
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0.0036
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0.0032
******
0.0037
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0.0027
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0.0030
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0.0024
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PPM-
******
0.0000
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0.0000
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0.0001
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0.0001
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ME-N
PPM
******
0.0
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0.0
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0.0001
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0.0004
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0.0006
******
0.0007
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0.0007
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0.0007
******
0.0007
******
0.0009
******
0.0009
******
0.0009
******
0.0009
-------
VD
EC -286
ETntNE
1978 APR 26
CLOCK
TIME
900
915
930
945
1000
1015
1030
lOtS
1100
1115
1130
1145
UOO
1215
1230
1245
1300
1315
1330
1315
1400
1415
1430
1445
1500
1515
ELAPSED
TiMINI
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
iao.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
OEG F
******
85.0
65.5
05.2
85.5
85.7
86.0
86.5
66.5
86.7
67.0
67.0
87.0
66.7
87.0
87.0
87. C
87.0
87. C
87.0
87.2
87.2
87.2
87.2
87.2
87.0
REL HUM
*
******
40.5
41.5
44.0
46.0
47.5
48.0
48.5
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49.0
49. C
49.0
49.0
48.5
49.0
49.0
48.5
48.5
SSPCIWER
KW
******
12.66
******
******
******
12.49
******
******
******
1Z.92
******
******
******
12.40
******
******
******
12.73
******
******
******
12.92
******
******
******
12.70
RACIOM
MH/CM2
******
******
0.264
0.259
******
0.254
******
******
******
G.t66
******
******
******
0.254
0.266
******
******
0.264
0.266
******
******
0.271
******
******
******
0.259
hCHQ VOL
L
******
20. CO
******
******
******
20.00
******
******
******
20.00
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20. 00
******
******
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20. CO
******
******
******
20.00
******
******
******
20.00
-------
EC -287
ETHENE
i978 APR 27
bE&IN IRRADIATION C9CO; 0.25 INCH PVREX FILTEHJ TRICHROIC FILTER OUT
6RADV 291, DAIS8I 1212 t TECO 148-1 USED
CO FACTOR: i.45/15.2; BECKMAN 6803 ON MANUAL OPERATION
T=0 AT 900 PST
N3
O
CAL1B#
PAN
HCHO
Rt-L INT
TS
REL HUM
SSPJ«SR
RADIUM
HiO
N3
N02-CORR
cTHENE
HCHQ
ACETALO
ACETONE
DEC K
X
KM
MM/CM2
PPM
PPM
PPh
PPM
PPM
PFM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
IMT CONO
1NIT CCNO
INIT CCNO
INIT CCNO
INIT CCNO
INIT CCNO
303.0
45.24
12.67
0.260
1.9C4E 04
0.404
0.124
3.995
0.014
O.C01
0.001
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION:
hAVELENGTH(NM)
SCO.
430.
403.
380.
370.
360.
350.
340.
33J.
320.
310.
300.
290.
REL.
Ki«0.39 MIN-X
SAMPLING RATE • 1.711 L/MIN
20 GC SAMPLES TAKEN
INTENSITY
1.704
1.655
1.526
1.427
1.300
1.128
1.000
0.805
0.561
0.310
0.117
0.017
0.0
-------
to
SC -287
ETHENE
1978 APR 27
CLOCK
TIME
64o
900
915
930
945
luod
1015
1030
1045
1100
1115
1130
1145
1200
1213
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
TIH1N)
-14.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
285.
300.
" 315.
330.
345.
360.
OZONE
PP«
******
0.000
0.007
0.073
0.237
0.447
0.645
0.813
0.911
0.955
0.965
0.948
0.921
0.887
0.350
0.811
0.782
0.743
0.711
0.682
0.652
0.628
0.603
0.536
0.567
0.552
NO
PPM
******
C.404
0.215
0.060
0.020
0.010
0.005
0.004
C.002
0.002
0.002
0.002
0.002
0.002
0.002
C.Q02
C.002
0.002
0.001
0.002
0.002
0.002
C.CC1
0.001
O.LC5
0.002
N02-CORR
PPM
******
0.124
0.301
0.439
0.449
0.405
0.345
0.2E2
0.228
0.164
0.153
0.129
0.114
0.1C4
0.097
O.CS3
0.091
C.090
0.089
0.090
0.090
0.09C
0.090
0.092
0.088
0.091
NOX-CORR
PPM
******
0.528
0.516
0.493
0.467
0.413
0.350
0.283
0.223
0.184
0.153
0.130
0.114
0.105
0.097
0.094
0.091
0.091
0.089
0.090
0.091
0.090
0.090
0.092
0.092
0.092
ETHENE
PPM
4.000
3.995
3.3o6
3.661
3.531
3.289
3.081
2.354
2.651
2.451
2.298
2.150
2.043
1.922
1.841
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1.645
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1.513
1.446
1.376
1.317
1.277
1.227
1.175
1.126
CO
PPM
0.54
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******
******
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0.66
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1.93
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2.29
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******
0.0010
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0.0113
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0.0125
******
0.0192
******
0.0211
******
0.0121
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0.0116
******
0.0175
******
0.0098
******
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******
0.0068
******
0.0146
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******
0.0001
******
0.0003
******
0.0014
******
0.0022
******
U.0030
******
O.Cu32
******
0.0027
******
C.^O^o
******
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******
l/.COi3
******
0.0019
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0.0020
******
0.0023
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PPM
******
0.0001
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0.0016
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******
******
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******
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0.0002
-------
N)
NJ
EC -287
ETHENE
1978 APR 27
CLOCK
TIME
846
900
915
930
945
1000
1015
1030
1045
1100
1115
1130
1149
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
TJMINJ
-14.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
3UO.
315.
330.
345.
360.
TS
DEC F
******
85.5
85.0
85.0
85.0
86.0
86.0
86.5
66.5
86.2
86.2
86.5
86.2
86.5
86.2
86.5
86.5
86.2
8b.5
86.5
86.2
86.5
86.2
86.5
86.2
66.5
REL HUH
*
******
40.0
42.0
44.0
46.0
47.0
47.5
48.0
48.0
48.0
48.0
48.5
48.5
48.5
48.5
48.0
48.0
48.0
48.0
48.0
48.0
48.0
48.0
47.5
47.5
47.5
SSPOtaER
KU
******
12.57
******
******
12.68
12.68
******
******
******
12.56
******
******
******
12.68
******
******
******
12.82
******
******
******
12.60
******
******
******
12.75
RACIOM
HM/CM2
******
0.259
0.264
0.259
0.256
0.264
******
******
******
0.259
******
******
******
0.261
0.256
0.261
0.264
0.261
0.256
0.259
******
0.259
******
******
******
0.266
HCHO VOL
L
******
20.00
******
******
******
20.00
******
******
******
2C.OC
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
N>
OJ
EC -30*
N-BJTANE
1978 JUL 25
IRRADIATION 0930; 0.25 IrtCH PYREX FILTER, TRICHROIC FILTER OUT
NEGATIVE PEAK (APPROX -1 DIVISIONS! AT T=0 ON PAN CHART AT 1.22 MIN RT
UNKNOWN PEAK ON PAN CHART AT APPROX 2.16 MIN RT
C*-N-2 DATA FROM C-600 CONSIDERED M3P6 RELIABLE THAN DATA FROM PANALYZER
BRADY 1193X, DASIBI 1212 (550 ML/MIN), TECO 14B-1 (570 ML/MINI,
OECKMAN 6300 (125 *"L/MIN)
CO FiCT-R: 1.^5/12.6; BECMAN 6800 ON MANUAL OPERATION
T«0 AT 930 POT
CALIB#
PAN
HCHC
REL INT
TS
REL HUM
SSPOHs*
RADIO-1'!
H20
NO
N02-CCR*
N-C*
c?
HCHC
DEC K
X
KM
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
JNIT CCND
INIT CCNO
INIT CCND
INIT CCND
INIT CCNO
303.1
6
-------
N>
•P-
tC -304
N-BUTANE
I97d JUL 25
CLOCK
TIME
835
9lo
9JO
945
1000
1015
1033
1045
HOJ
111S
1130
U4S
1200
1215
1230
12**
1300
131.5
1330
I34i
1400
1415
1*30
1445
1500
1515
1530
15
-------
-P-
NJ
EC -304
N-6UTANE
197b JUL 25
CLOCK
TIME
83S
918
930
945
1000
1015
103J
1345
HUG
1115
1130
1145
1203
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
1645
HLAPSEO
T(MIN)
-55.
-12.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
1BD.
195.
210.
225.
240.
255.
2TO.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
CO
PPM
******
******
1.30
******
******
******
1.40
******
******
******
1.50
******
******
******
1.61
******
******
******
1.67
******
******
******
1.77
******
******
******
1.92
******
******
******
******
******
PAN
PPM
******
******
0.000
******
0.000
******
0.001
******
0.002
******
0.004
******
0.006
******
0.003
******
0.011
******
0.014
******
0.017
******
0.020
******
0.023
******
0.027
******
******
******
******
******
HCHO
PPM
******
******
0.002
******
******
******
U.004
******
******
******
0.006
******
******
******
0.009
******
0.020
******
0.031
******
******
******
0.025
******
******
******
0.0
******
******
******
******
******
ACETALD
PPM
0.001
******
******
*****.*.
******
******
0.030
******
0.045
******
0.063
******
0.074
******
0.085
******
0.091
******
0.108
******
0.112
******
0.117
******
0.143
******
0.149
******
******
******
******
******
PROPALD
PPM
0.0001
******
******
******
******
******
******
******
0.0003
******
O.OOOt)
******
0.0006
******
0.00 10
******
0.0007
******
0.0010
******
0.0012
******
0.0013
******
0.0022
******
0.0021
******
******
******
******
******
ACETONE
PPM
0.0005
******
0.0004
******
0.0022
******
0.0005
******
0.0012
******
U.0035
******
0.0016
******
0.0019
******
0.0016
******
0.0010
******
0.0027
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0.0034
******
0.0048
******
0.0043
******
******
******
******
******
BUTYRAL
PPM
0.0001
******
******
******
0.0013
******
0.0009
******
******
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0.0022
******
0.0021
******
0.0036
******
******
******
0.0043
******
******
******
******
******
0.0055
******
0.0050
******
******
******
******
******
MEK
PPM
0.0001
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0.0001
****v*
0.0180
******
0.0212
******
0.0332
******
0.0587
******
0.0453
******
0.0518
******
0.0551
******
0.0634
******
0.0695
******
0.0790
******
0.0919
******
0.0921
******
******
******
******
******
C2-N
PPM
PAUALViR
******
******
0.0
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0.0
******
0.0001
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0.0002
******
0.0002
******
0.0003
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0.0003
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0.0003
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0. JOOJ
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0.0004
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0.003'f
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0.0004
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0.0004
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******
******
******
******
C4-N-2
PPM
C-600
0.0
******
0.0
******
0.0042
******
0.0069
******
0.0097
******
0.0119
******
0.0143
******
0.01o7
******
0.0188
******
0.0211
******
0.0227
******
0.0242
******
0.0263
******
0.0291
******
******
******
******
******
C4-N-2
PPM
PANAtYZR
******
******
0.0
******
0.0027
******
0.0042
******
0.0059
******
O.OJ75
******
0.0093
******
O.OlOb
******
0.0118
******
0.0129
******
0.0142
******
0.0158
******
0.0162
******
0.0171
******
******
******
******
******
C4-N-1
PPM
PANAL W
******
******
0.0
******
0.0
******
0.0005
******
0.0004
******
0.0004
******
0.0007
******
0.0010
******
0.0011
******
0.0011
******
0.0018
******
0.0017
******
0.0018
******
0.0018
******
******
******
******
******
-------
S3
EC -304
N-SUTANE
1976 JUL 25
CLOCK
TIME
835
918
930
9*5
1000
1015
1030
1045
1100
1115
1130
1145
1230
1215
1233
1245
1300
1315
1330
1345
1400
1415
1430
1445
15JO
1515
1530
1545
1600
1615
1630
1645
ELAPSED
T(MIN»
-55.
-12.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
105.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
420.
435.
TS
DEC F
******
******
63.8
84.5
84.0
84.3
04.8
85.0
85.2
86.0
86.0
67.0
87.0
87.4
86.7
87.2
67.4
87.2
87.4
36.5
86.0
85.7
65.5
85.5
85.7
85.5
85.5
85.2
85.5
85.5
85.5
85.7
RcL HUM
*
******
******
51.5
• 54.0
53.5
61.5
63.5
64.0
64.5
64.5
64.5
64.5
64.5
64.5
64.5
64.5
64.5
64.5
64.5
65.0
66.5
67.5
68.0
6d.5
68.5
68.0
66.0
68.0
68.0
68.0
68.0
68.0
SSPOMER
KW
******
******
14.47
******
******
******
14.43
******
******
******
14.31
******
******
******
14.54
******
******
******
14.82
******
******
******
14.80
******
******
******
15.19
******
******
******
******
******
RADIOM
MH/CM2
******
******
******
0.259
0.254
******
0.259
******
******
******
******
0.269
******
******
0.256
******
******
******
0.271
******
******
******
0.266
0.269
0.269
0.269
0.266
0.264
0.261
0.266
0.264
0.269
HCHO VOL
L
******
******
38.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
******
******
-------
EC -305
N-BUTANE
1978 JUL 26
BEGIN IRRADIATION 0930! 0.25 INCH PYREX FILTER! TRICHROIC FILTER OUT
NEGATIVE PEAK JAPPROX.-l CIVISIONSJ AT T=C CN PAN CHART AT ROUGHLY 1.22 MIN RT
C4-N-2 DATA FROM C-600 CCNSIOEREO MORE RELIABLE THAN DATA FROM PANALYiER
SRAOV 1193XrDASIBI 1212 (550 ML/MIN), TECO 14B-1 (570 ML/MINJ ,
BECKMAN 68CO (125 ML/MINI
CO FACTOR- 1.45/U.6! BECKMAN 6600 ON MANUAL OPERATION
T=0 AT 930 PDT
CALIB*
PAN
HCHO
REL INT
TS
REL HUM
SSPQhER
fiAOIGM
H20
NO
N02-CQRR
N-C4
CO
HCHQ
AC ET ONE
DEC K
%
KW
MW/CM2
PPH
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERACE
AVERAGE
INIT CCNO
INJT CCND
INIT CCNO
INIT CCNC
INIT CCNO
INIT CCND
303.0
O.30
14. 7a
0.261
Z.735E
C.C76
O.OiO
4.296
1.222
O.CC2
0.001
ASSIGNED INITIAL CONDITION
SPECTRAL OISTKJ6UTIQN:
hAVELENGTH(NM)
50C.
A30.
403.
360.
370.
360.
350.
340.
330.
320.
3iO.
300.
290.
2BC.
REL.
Kl=0.43 MIN-i
SAMPLING RATE - 1.5SS L/MIN
29 GC SAMPLES TAKEN
INTENSITY
1.919
1.751
1.605
1.433
1.315
1.126
1.600
0.798
.556
.314
,125
.020
.001
.0
0.
0.
0.
0.
0.
0.
-------
to
00
EC -305
N-BuTANE
1976 JUL 26
CLOCK
TIME
830
918
930
945
11/00
1015
1030
1049
1100
1115
1130
1145
12 Ju
U15
1230
12*5
1300
1315
1330
1543
1400
1415
1430
1445
1500
1515
1530
ELAPSEC
TIMINJ
-60.
-12.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
300.
OZONE
PP>>
******
******
O.COO
0.020
0.042
0.071
0.098
C.130
0.159
0.176
0.205
0.227
0.237
0.271
0.281
0.310
0.325
0.340
0.352
0.362
0.371
0.379
0.366
0.388
0.393
0.398
0.398
NO
PPM
******
******
0.07d
0.040
0.025
C.019
0.017
0.014
C.014
C.012
C.011
0.010
C.CC9
0.009
0.009
O.OC8
C.010
c.ooa
O.OC7
C.CC8
O.OC8
0.007
0.009
0.007
O.OC7
0.007
C.007
N02-CORR
FPM
******
******
0.020
0.055
0.069
O.C76
0.073
0.072
0.077
0.072
0.066
0.063
O.C6C
0.057
0.053
0.04.9
0.043
0.040
0.038
0.035
0.033
0.032
0.030
0.029
0.026
0.026
0.024
NOX-CORR
PPM
******
******
0.099
0.095
0.095
0.095
0.069
0.08o
0.091
0.084
0.076
0.073
O.C69
0.066
0.062
0.057
0.052
0.048
0.044
0.043
0.040
O.C39
0.038
0.036
0.033
0.033
0.030
N-C4
PPM
RM 121
0.0
4.32
4.30
******
******
******
4.13
******
**v***
******
3.94
******
******
******
3.65
******
******
******
3.72
******
******
******
3.64
******
******
******
3.53
N-C4
PPM
RM 103
******
******
******
******
3.93
******
******
******
3.91
******
******
******
3.82
******
******
******
******
******
3.67
******
3.57
******
******
******
******
******
******
-------
-p-
K>
VO
eC -305
1976 JUL 26
CLOCK
TIME
830
918
V30
945
1000
1015
1030
1045
lloo
1115
1130
1145
liOO
U15
1230
1245
1300
1315
1330
13-.5
;40u
1415
1430
1445
1500
1515
1530
ELAPSED
T(MINJ
-60.
-12.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
c55.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
******
1.22
1.23
******
******
r.*****
1.27
******
******
******
1.37
******
******
******
1.46
******
******
******
1.54
******
******
******
1.60
******
******
******
1.73
PAN
PPM
******
******
0.000
******
0.001
******
0.002
******
0.005
******
C.CC7
******
0.010
******
0.013
******
0.018
******
0.021
******
0.023
******
0.025
******
0.029
******
C.031
HCHO
PPM
******
******
0.002
******
******
******
0.001
******
******
******
O.CC8
******
******
******
0.012
******
******
******
0.017
******
******
******
0.016
******
******
******
0.023
ACETALD
PPM
0.001
******
******
******
******
******
0.030
******
******
******
0.061
******
******
******
0.083
******
******
******
0.097
******
******
******
0.122
******
******
******
0.131
PROPALO
PPM
0.0001
******
0.0001
******
******
******
0.0004
******
******
******
0.0012
******
******
******
0.0012
******
******
******
0.0019
******
******
******
0.0025
******
******
******
0.0030
ACETONE
PPM
0.0005
******
0.0005
******
******
******
0.0017
******
******
******
0.0025
******
******
******
0.0101
******
******
******
0.0071
******
******
******
0.0085
******
******
******
0.0062
BUTYRAL
PPM
0.0000
******
0.0001
******
******
******
******
******
******
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******
******
******
******
******
******
******
******
0.0025
******
******
******
0.0050
******
******
******
0.0057
MEK
PPM
0.0001
******
0.0002
******
******
******
0.0202
******
******
******
0.0372
******
******
******
0.0587
******
******
******
0.0o24
******
******
******
0.0750
******
******
******
0.0847
C2-N
PPM
PANALY/ft
******
******
0.0
******
0.0
******
0.0001
******
o.oooi
******
0.0002
******
0.0002
******
0.0003
******
0.0003
******
0.0003
******
0.0003
******
0.0003
******
0.0003
******
0.0003
C4-N-2
PPM
C-600
0.0
******
0.0
******
******
******
0.0071
******
******
******
0.0120
******
******
******
O.OloO
******
******
******
0.0196
******
******
******
0.0224
******
******
******
0.0237
C4-N-2
PPM
PAN&LtiS
******
******
0.0
******
O.Outb
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O.0u
-------
£C -305
N-8UTANE
1978 JUL 26
CLOCK
TIME
G3C
91B
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1249
1-iOO
1315
•P- 1330
i^ 1345
0 140J
1415
1430
1445
1500
1515
1530
ELAPSED
TIMIN)
-60.
-12.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
loS.
ISO.
195..
210.
225.
240.
255.
270.
483.
300.
315.
330.
345.
360.
TS
DEC F
******
******
65.5
85.7
85.0
85.0
85.2
66.2
86.5
67.0
87.0
67.4
86.7
66.7
66.2
66.5
86.0
8(5.0
66.0
66.5
85.7
bo.O
85.5
66.0
86.2
66.2
85.7
REL HUM
X
******
******
51.5
' 54.5
oO.O
64.5
67.0
68.0
66.5
68.5
66.5
68.5
69.0
69.0
69.0
69.0
69.5
69.5
69.5
69.5
69.5
69.5
69.5
69.5
69.5
69.5
69.5
SSPOriER
Kn
******
******
14.62
******
******
******
14.82
******
******
******
14.74
******
******
******
14.74
******
******
******
14.93
******
******
******
14.43
******
******
******
15.20
RAD10M
MW/CM2
******
******
******
******
******
******
0.266
******
******
******
0.266
******
******
******
******
******
******
******
0.266
******
******
******
0.256
C.259
0.264
******
0.271
HCHO VOL
L
******
******
^0.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -306
N-SUTAN? 85 OEG F
1973 JUL 27
BEGIN IKSAOIATICN 100J; 0.25 INCH PVREX FILTER; TRICHROIC FILTER OUT
NEGATIVE PEAK (APPROX -1.0 0!V) AT T=0 ON PAH CHART AT 1.25 MIN RT
UNKNOWN PEAK AT RT 2.19 3N PAN CHART; MAX PEAK HEIGHT: 1.2
C4-N-2 DATA FROM C-600 CONSIDERED MORE RELIABLE THAN DATA FROM PANALYZER
BRAOY IISJX.DASIBI 1212 (550 ML/MINJ. TECO 148-1 1570 ML/rtlNI,
6ECKMAN 6800 (125 M./MIN)
CO FACTOR: 1.^5/12.6; BECKMAN 6800 ON MANUAL OPERATION
T=0 AT 1000 POT
HCHO
REL INT
CALIB*
9
3
LO
TS
REL HU,1
5SP3WER
RAO'.JM
H2Q
N'J
^402-CORR
N-C4
CO
HCHO
DEG K
X
KW
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CONO
INIT CCNO
INIT C3NO
INIT CONO
303.3
59.37
14.62
0.260
z.'.asi
0.147
0.040
6.435
2.392
O.C07
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTIONS k.AVEL=NGTH(NMI
500.
430.
403.
330.
370.
360.
350.
340.
330.
320.
310.
300.
290.
Kl-0.44 MIN-1
SAMPLING RATE = 1,563 L/MIN
36 GC SAMPLES TAKEN
REL. INTENSITY
1.340
1.675
1.534
1.405
1.279
1.126
1.000
0.799
0.562
0.314
0.122
0.019
0.0
-------
(-0
EC -306
M-BUTANE 85 DEG F
1978 JUL 27
CLOCK
TIME
900
9*5
10JJ
10 1 5
1030
10*:>
1100
1115
1130
11*5
UOO
1215
12 3U
12*5
uoo
1315
1330
13*5
1*00
1*15
1*30
1**5
1500
1515
1530
15*5
1600
1615
1630
1645
ELAPSED
TtMIN)
-60.
-15.
0.
15.
30.
*5.
60.
75.
90.
105.
120.
135.
ISO.
165.
ISO.
195.
210.
225.
2*0.
255.
270.
2d5.
300.
315.
330.
3*5.
360.
375.
390.
405.
OZONE
PPM
******
******
0.000
0.007
0.020
0.037
0.059
0.031
0.183
0.139
0.166
0.193
0.220
0.2**
0.281
0.300
0.327
0.352
0.379
O.*03
0.423
0.4*5
0.464
0.481
0.*98
0.508
0.520
0.528
0.535
0.535
NO
PPM
******
******
0.147
0.100
J. 069
0.051
0.033
0.034
0.023
0.019
0.017
0.015
0.013
0. Oil
0.009
0.010
0.009
0.009
o. oor
0.007
a. oas
0.007
0.007
0.006
0.006
0.006
0.006
0.005
0.013
0.005
N02-CORR
PPM
******
******
0.0*0
0.383
0.111
0.127
0.1 3d
0.139
0.1*6
0.146
0.1*2
0.139
0.135
0.130
0.121
0.118
0.110
0.105
O.C97
0.090
O.C3*
0.076
J.068
0.063
0.058
0.051
0.0*6
0.045
0.0*1
9.0*2
NOX-CORR
PPM
******
******
0.167
0.183
0.181
0.177
0.175
0.174
0.168
0.163
0.153
0.153
0.147
0.141
0.134
0.127
0.118
0.112
0.104
0.097
0.091
0.083
0.075
0.068
0.063
0.056
0.051
0.050
0.053
0.047
N-C4
PPM
0.0
6.42
6.44
******
6.25
******
6.17
******
6.08
******
6.02
******
5.93
******
5.65
******
5.74
******
5.71
******
5.60
******
5.56
******
5.46
******
5.40
******
******
******
-------
EC -306
N-BUTANE 85 DEC F
1978 JUL 27
CLOCK
TIMt
900
9*5
1000
1015
1030
1045
110J
1113
1130
1145
1200
1215
1233
1245
1300
1315
133J
1345
1430
1415
1430
1445
150U
1515
1530
1545
1600
1615
1630
1643
ELAPSED
T(MIN)
-60.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
• 300.
315.
330.
345.
360.
375.
390.
405.
CO
PPM
******
******
2.39
******
******
******
2.45
******
******
***¥*«
2.52
******
******
******
2.60
******
******
******
******
******
******
******
******
******
******
******
2.90
******
******
******
PAN
PPM
******
******
O.COO
' ******
0.001
******
0.002
******
J. 003
******
0.005
******
0.007
******
0.011
******
3.015
******
0.019
******
0.019
******
0.026
******
0.029
******
0.035
******
******
******
HCHJ
PPM
******
******
0.007
******
******
******
0.003
******
V*****
******
0.004
******
******
******
0.013
******
******
******
0.009
******
******
******
0.001
******
******
******
0.002
******
******
******
ACETALD
PPM
0.001
******
******
******
0.015
******
0.032
******
0.055
******
0.071
******
0.080
******
0.085
******
0.107
******
0.117
******
0.139
******
0.138
******
0.166
******
0.153
******
******
******
PROPALD
PPM
0.0001
******
0.0001
******
******
******
0.0001
******
******
******
0.0008
******
0.0307
******
0.0010
******
0.0014
******
******
******
O.OJ21
******
0.0035
******
0.0031
******
0.0022
******
******
******
ACETONE
PPM
0.0003
******
0.0001
******
0.0004
******
O.OOOd
******
0.0038
******
0.0025
******
0.0027
******
0.0034
******
0.0036
******
0.0039
******
0.0047
******
0.0040
******
0.0061
******
0.0055
******
******
******
BUTYRAL
PPM
0.0000
******
0.0000
******
0.0009
******
0.0012
******
0.0020
******
0.3023
******
0.0023
******
******
******
0.0038
******
******
******
0.0051
******
******
******
0.0149
******
******
******
******
******
MEK
PPM
0.0002
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0.0001
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0.0119
******
0.0214
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0.0440
******
0.0398
******
0.0466
******
0.0545
******
0.0571
******
O.J658
******
0.0746
******
0.0832
******
0.0962
******
0.0980
******
******
******
C2-N
PPM
PAMALVIR
******
******
0.0
******
0.0
******
0.0001
******
0.0002
******
0.0002
******
0.0003
******
0.0003
******
0.3003
******
0.0033
******
0.0004
******
O.OU04
******
0.0004
******
0.0004
******
******
******
C4-N-2
PPM
C-600
0.0
******
0.0
******
0.0043
******
G.0071
******
o.ouv?
******
O.OU4
******
U.0154
******
0.0171
******
0.0204
******
0.0217
******
0.0243
******
0.0260
******
0.02o8
******
0. Oio9
******
******
******
C4-N-2
PPM
PANALVZR
******
******
0.0
******
0.0027
******
0.0045
******
0.0065
******
0.0060
******
0.0093
******
0.0110
******
0.0124
******
0.0146
******
0.0153
******
0.0173
******
0.0173
******
0.0191
******
******
******
C4-N-1
PPM
PANALVZR
******
******
0.0
******
0.0
******
0.0003
******
0.0004
******
******
******
0.0005
******
0.0011
******
0.0011
******
0.0013
******
0.0015
******
0.0018
******
0.0018
******
O.OU20
******
******
******
-------
EC -306
N-BUTANE 85 OEG F
1978 JUL 27
CLOCK
TIME
90J
945
10JJ
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
UJu
1315
1330
1345
1400
1415
1430
1*45
1503
1515
1530
1545
1600
1615
1630
1645
ELAPSED
T(MIN)
-60.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
100.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
405.
TS
DEC F
******
******
85.0
84.5
84.0
85.0
86.2
85.5
86.5
86.0
86.5
66.2
87.2
87.2
87.2
86.7
87.2
87.0
87.2
87.2
87.2
87.4
87.2
86.2
86.0
85.7
85.5
85.2
85.2
85.5
REL HUH
Z
******
******
49.0
51.5
55.5
57.5
59.0
59.5
60.0
60.0
60.0
60.0
60.0
60.0
60.0
59.5
59.5
59.5
59.5
59.5
59.5
59.5
59.0
59.5
61.0
62.0
62.5
62.5
62.5
63.0
SSPOWER
KM
******
******
14.62
******
14.82
******
14.43
******
******
******
14.62
******
******
******
14. 60
******
******
******
14.62
******
******
******
14.62
******
******
******
14.43
******
******
******
RAOIOM
MW/CM2
******
******
0.259
0.266
0.261
0.259
0.254
******
******
******
0.266
******
0.256
0.264
0.261
******
******
******
0.259
******
******
******
0.25?
******
******
******
******
0.261
0.252
0.256
HCHO VOL
L
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
-------
EC -307
S-BUTANE
1978 JUL Z8
3EGIM IRRADIATION} 0930 0.25 INCH PYREX FILTEK5 TRICHROIC FILTER OUT
NEGATIVE PEAK (APPROX -1.0 OIV1 AT T*0 ON PAN CHART AT 1.25 MIN RT
UNKNOWN PEAK AT RT 2.19 ON PAN CHART; MAXPEAK HEIGHT: 1.2
C4-N-2 DATA FROM C-600 CONSIDERED MOPE RELIABLE THAN DATA FROM PANftLVZER
BRADY 1193XtDASIBI 1212 (550 ML/MINI, TECO 14B-1 1570 ML/MINI,
BECKMAN 6800 (125 ML/MINI
CO FACTOR: 1.45/12.6 8ECK.MAN 6800 ON MANUAL OPERATION
T=0 AT 930 POT
HCHO
PAN
REL IMT
CALIB*
3
9
TS
REL HUM
SSPOV.ER
RADIOM
H29
OZGNE
NO
N02-CORR
N-C4
CO
HCHO
DEG K
J
KM
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVE.RAGE
AVERAGE
AVERAGE
AVERAGE
INIT CQND
INIT CCND
INIT COW
INIT CQND
INIT CGND
INIT COND
303.0
69.37
0.261
4.C79S
0.002
0.083
0.019
6.435
2.739
0.052
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: nAVELENGTHINM)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
Kl=0.44 MIN-1
SAMPLING RATE « 1.577 L/MIN
37 GC SAMPLES TAKEN
REL.
INTENSITY
1.904
1.737
1.600
1.460
1.305
1.129
1.000
0.601
0.555
0.312
0.124
0.021
0.0
-------
iC -307
N-ttUTANE
1976 JUL 28
CLOCK
TJ1E
825
920
930
945
1000
1015
1030
10*5
1100
1115
1130
11*5
I2JO
1215
1230
12*5
1300
1315
133J
13*5
1*00
1415
1430
14*5
1500
1515
1530
15*5
1600
ELAPSED
T(MIN)
-65.
-10.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
IdO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
3*5.
360.
375.
390.
020NE
PPM
******
0.0
0.002
0.020
0.044
0.081
0.107
0.139
0.169
0.198
0.222
0.2*9
0.271
0.291
0.313
0.332
0.3*7
0.36*
0.376
0.386
0.396
0.403
0.410
0.413
0.415
0.420
0.420
0.420
0.420
NO
PPrt
******
0.082
0.033
0.047
0.028
0.020
0.016
0.014
0.012
0.024
O.Oll
0.010
0.010
C.009
0.008
0.015
o.ooa
0.003
C.008
0.008
0.007
0.008
0.007
0.006
0.005
0. OC7
0.007
0.007
******
N02-CORR
PPM
******
0.019
0.019
0.052
O.C69
0.076
o.ota
0.077
0.076
O.C60
0.069
0.066
0.062
0.053
0.055
0.0*6
0.048
0.04*
0.043
0.036
0.034
0.0*2
0.032
0.031
0.030
0.029
0.02)
0.028
******
NOX-CORR
PPM
******
0.101
0.102
0.099
0.097
0.098
0.094
0.090
0.087
0.084
0.080
0.075
0.072
0.066
0.06*
0.060
0.055
0.052
0.051
0.044
0.041
0.050
0.039
0.037
0.035
0.036
0.035
0.034
******
N-C*
PPM
0.0
6.51
6.44
******
6.29
******
6.18
******
6. 11
******
5.98
******
5.88
******
5.83
*v****
5. 76
******
5.66
******
5.58
******
5.61
******
5.44
******
5.39
******
******
-------
EC -307
N-BUTANE
1978 JUL 28
CLQC*
TIP?
825
920
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
12*5
13JJ
1315
1330
1345
1400
1415
1430
1*45
1500
1515
1530
1545
1600
ELAPSED
T(MIN»
-65.
-10.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ieo.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
3T5.
390.
CO
PPM
******
******
2.74
******
******
******
2.79
******
******
******
2.89
******
******
******
2.95
******
******
******
3.03
******
******
******
3.12
******
******
******
3.15
******
******
PAN
PPM
******
******
O.OOJ
******
0.001
******
0.002
******
0.004
****«!*
0.007
******
0.009
******
0.011
******
J.014
******
0.017
******
0.020
******
0.020
******
0.024
******
0.023
******
0.026
HCH3
PPM
******
******
0.052
******
******
******
0.013
******
******
******
0.010
******
******
******
0.019
******
******
******
a. 066
******
******
******
0.021
******
******
******
0.02'J
******
******
ACETALD
PPM
0.002
******
******
******
0.022
******
0.041
******
0.062
******
0.080
******
0.089
******
0.107
******
0.097
******
0.104
******
0.14T
******
0.150
******
0.142
******
0.161
******
******
PROPALD
PPM
0.0001
******
******
******
0.0002
******
0.0003
******
0.0007
******
******
******
0.0012
******
0.0012
******
******
******
0.0010
******
0.0024
******
0.002T
******
0.0020
******
0.0016
******
******
ACETONE
PPM
0.0004
******
0.0003
******
0.0023
******
0.0025
******
0.0072
******
******
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0.0058
******
0.0112
******
******
******
0.0113
******
0.0174
******
0.0210
******
0.0137
******
******
******
******
BUTY
-------
co
cC -307
N-BUTANE
1978 JUL 28
CLOCK
Tine
825
920
S30
94i
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
123J
1245
1300
1315
U33
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
EL4PSED
T(MIN)
-65.
-10.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
1
-------
U)
ec -308
N-BUTANE 60 DEC F
1978 JUL 31
6EGIS IRRADIATION 0945; 0.25 INCH PYPSX FILTER; TRICHROIC FILTER OUT
BAD 2-C43N02 BASELINE ON C-600 CHART; C-600 02 UP SLIGHTLY
NEGATIVE PFAK UPPRQX -1 DIVISIONS) AT T = 0 ON PW CHART AT 1.13 MIN RT
C4-S-2 DATA FROM C-600 CONSIDERED MO*E RELIABLE THAN DATA FROM PANALY/ER
68ADV 1193XtOASIBI 1212 1550 ML/MINI, TECO 14B-1 (570 ML/MINI,
CO FACTOR:1.45/12.2
T«0 AT 945 POT
CALlBtf
PAN
HCHQ
REL INT
TS
AEL HUM
SSPOWSR
RADIOS
H2'J
NO
N02-CORR
N-C4
CD
DEC K
£
KM
MX/CM2
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
IN IT CGNO
INIT CCND
INIT CCND
2b8.9
50.6S
15.11
0.362
8.901t 03
0.305
0.178
4.054
1.190
ASSIGNED INITIAL CCNOITION
SPECTRAL DISTRIBUTION:
WAVtLENGTHtNMI
500.
430.
403.
3BO.
370.
360.
350.
340.
330.
320.
310.
300.
290.
REL.
Kl*0.45 MIN-1
SAMPLING RATE » 1.603 L/MIN
36 GC SAMPLES TAKEN
INTENSITY
1.919
,738
,595
,464
,317
,140
,000
,784
.558
,316
,126
0.020
0.0
-------
PC -308
N-BUTANE 60 DEG
1978 JUL 31
CLUCK
TIME
840
930
9*5
1000
1015
1030
1045
1100
111*
1133
1145
120J
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
T(M1N)
-65.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
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195.
210.
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255.
270.
285.
300.
315.
330.
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0.007
0.010
0.010
0.010
0.012
0.015
0.017
0.017
0.020
0.020
0.022
0.022
0.027
0.027
0.029
0.032
0.034
0.037
0.039
0.044
0.044
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******
******
0.305
0.2B1
0.267
0.244
0.231
0.220
0.211
0.203
0.193
0.183
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0.170
0.162
0.154
0.149
0.144
0.133
0.129
0.122
0.121
0.112
0.10*
0.103
0.098
0.095
N02-C3RR
PPM
******
******
0.178
0.190
0.197
0.216
0.222
0.229
0.233
0.239
0.243
0.248
0.253
0.253
0.256
0.261
0.262
0.263
0.273
0.269
0.270
0.273
0.274
0.271
0.274
0.275
0.272
NOX-CORR
PPM
******
******
0.483
0.471
0.464
0.459
0.453
0.443
0.442
0.440
0.434
0.431
0.426
0.421
0.418
0.414
0.409
0.405
0.402
0.398
0.392
0.390
0.383
0.3T8
0.375
0.371
0.366
N-C4
PPM
0.0
4.06
4.05
******
3.96
******
3.91
******
3.87
******
3.81
******
3.77
******
3. 74
******
3.69
******
3. 65
******
3.61
******
3.58
******
3.53
******
3.47
-------
EC -308
H-6UTANE 60 DEC F
1978 JUL 31
CLOCK
TIM =
840
930
945
1000
1015
1030
1045
1100
1115
1130
1145
1230
1215
1230
I24a
1300
1315
13JU
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
TCM1NI
-65.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
lil).
135.
150.
165.
130.
195.
210.
225.
240.
255.
270.
205.
300.
315.
330.
345.
360.
CO
PPM
******
1.18
1.19
******
******
******
1.24
******
******
******
1.62
******
******
******
1.68
******
******
******
1.75
******
******
******
1.80
******
******
******
1.81
PAN
PPM
******
******
0.000
******
O.U01
******
0.001
******
0.001
*#*<.**
0.001
******
0.002
******
0.002
******
0.002
******
0.003
******
0.004
******
C.004
******
0.005
******
0.004
HCHO
PPM
******
******
0.0
******
******
******
0.0
******
******
******
0.0
******
******
******
0.000
******
******
******
0.004
******
******
******
0.005
******
******
******
0.010
ACETALO
PPM
0.003
******
******
******
0.006
******
0.012
******
0.013
******
0.015
******
0.020
******
0.024
******
0.025
******
******
******
0.023
******
0.034
******
0.027
******
0.037
PROPALO
PPM
0.0004
******
******
******
******
******
0.0002
******
******
******
0.0002
******
0.0001
******
0.000?
******
******
******
0.0005
******
0.0004
******
******
******
0.0008
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0.0005
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0.0004
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0.0011
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0.0016
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0.0011
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0.0018
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0.0031
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0.0041
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0.0046
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0.0014
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0.0039
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0.0014
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0.0015
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0.0001
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0.0010
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0.0015
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0.0016
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0.0017
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0.0032
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0.0001
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0.0002
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0.0193
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0.0292
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0.0305
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0.0282
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0.0464
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0.0589
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0.0554
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0.0760
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0.0494
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0.0763
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0.0551
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0.0585
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PANALYZR
******
******
0.0
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0.0
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0.0
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0.0
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******
0.0001
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0.0001
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0.0001
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0.0001
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0.0001
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0.0001
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0.0002
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0.0001
C4-N-2
PPM
C-600
0.0
******
0.0
******
0.0043
******
0.0054
******
G.0056
******
0.0069
******
O.OOuO
******
0.0096
******
0.0097
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0.0109
******
0.0116
******
0.0126
******
0.0132
******
0.0139
C4-N-2
PPM
PANALYiR
******
******
0.0
******
0.0023
******
0.0029
******
0.0036
******
0.0044
******
0.0053
******
0.0059
******
0.0067
******
0.0075
******
0.0079
******
0.0085
******
O.OJ92
******
0.0095
C4-N-1
PPM
PANALYZR
******
******
0.0
******
0.0
******
0.0
******
0.0003
******
0.0004
******
0.0003
******
0.0006
******
0.0005
******
0.0005
******
0.0005
******
0.0009
******
0.0007
******
0.0008
-------
EC -308
N-3UTANE 60 OEG F
1978 JUL 31
CLCCK
TIME
840
S30
941>
IOQO
1015
1030
1045
1100
1115
113J
1145
12UJ
1215
123J
124!>
13JO
1315
133J
13t3
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
TIMIN)
-65.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
1 95.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
TS
OEG F
******
******
59.1
60.1
59.6
59.6
60.3
60.3
60.6
60.3
60.3
60.1
63.1
60.3
60.1
60.1
60.3
60.3
60.1
60.3
60.3
60.6
60. 6
60.6
60.6
60.6
60.6
REU HUM
3E
******
******
42.0
44.5
43.0
50.5
51.5
52.3
52.0
52.0
52.0
52.3
52.0
51.5
51.5
51.5
51.5
51.5
51.0
51.0
51.0
51.0
51.0
51.0
51.0
51.0
50.5
SSPQWER
Kh
******
******
15.40
******
******
**«•***
15.29
******
******
******
15.20
******
******
******
14.96
******
******
******
14.69
******
******
******
15.01
******
******
******
15.24
RA01QM
MK/CM2
******
******
0.254
0.274
0.256
0.261
0.266
******
******
******
0.264
******
******
******
0.259
******
******
******
0.249
******
******
******
0.266
******
******
******
0.269
HCHO VOL
L
******
******
20.00
******
******
******
20.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -309
N-SUTANE 100 OEG F
1978 AUG 1
BEGIN IRRADIATION 1000; 0.25 INCH PVREX FILTER; TRICHROIC FILTER OUT
UNKNOWN PEAK ON PAN CH/RT AT RT 2.24! MAX HEIGHT APPROX 1.2
C4-S-2 DATA FROM C-6CO CONSIDERED MORE RELIABLE THAN DATA FROM PANALY4ER
BRADY 1193X, CASIBI 1212 (550 ML/MINI, TECO 14-1B 1570 ML/HINIt
dECKMAN 6800 (125 HL/MIN)
CO FACTOR: 1.45/12.1; BECKMAN 6800 ON MANUAL OPERATION
T=0 AT 1000 POT
PAN
HCH3
REL INT
CALIB*
9
3
4
TS
REL HUM
SSPJWER
RADICM
H20
NC;
N02-C3<"»
N-C4
CO
HCHC
ACETONE
OEG K
I
KM
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVE'AGE
INIT CONO
INIT CCND
INIT COND
INIT CCND
INIT CCND
INIT CCND
311.5
34.77
15.33
0.261
2.3J9E
0.203
0.272
4.306
0.864
0.002
0.001
ASSIGNED INITIAL CONDITION
SPECTPAL DISTRIBUTION: WWELENGTHINM)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
REL.
Kl*0.45 MIN-1
SAMPLING RATE =
INTENSITY
1.917
1.760
1.456
1.319
1.126
1.000
0.800
0.557
0.313
0.124
0.019
0.0
1.563 L/M1N
36 GC SAMPLES TAKEN
-------
EC -309
M-BUTANE 100 DEC F
1978 AUG 1
CLOCK
TIME
830
930
100J
1015
1030
1345
1100
U15
H3D
1145
1200
1215
123u
124i
1300
1315
1330
134b
1400
1415
1430
1445
liUJ
IMS
1530
1345
1600
ELAPSED
TIM1N)
-90.
-30.
0.
15.
30.
45.
60.
T5.
90.
105.
120.
135.
150.
le>5.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
******
******
0.000
0.020
0.027
0.032
0.0t9
0.059
0.071
O.OdS
0.105
0.125
0.147
O.lo6
0.183
0.210
0.230
0.257
0.283
0.313
0.340
0.371
0.401
0.437
0.475
0.510
0.545
NO
PPM
******
******
0.203
0.149
0.121
0.100
0.084
0.072
O.ObO
0.053
0.045
0.040
0.035
0.031
0.027
0.022
0.020
0.018
0.016
0.015
0.016
0.011
0.011
0.014
0.013
C.012
0.011
N02-CQRR
PPM
******
******
0.272
0.309
0.329
0.340
0.353
0.357
0.363
0.362
0.361
0.360
0.356
C.354
0.352
0.346
0.242
0.347
0.333
0.327
C.320
0.317
0.314
0.281
0.230
0.272
0.259
NOA-CORR
PPM
******
******
0.475
0.458
0.449
0.439
0.436
0.427
0.421
0.413
0.405
0.399
0.390
0.383
0.378
0.368
0.360
0.364
0.348
0.340
0.333
0.328
0.322
0.295
0.293
0.284
0.270
N-C4
PPM
0.0
4.36
4.31
******
4. 18
******
4. 10
******
4.03
******
3.98
******
3.98
******
3.80
******
3.78
******
3.73
******
3.67
******
3.59
******
3.52
******
3.44
-------
EC -309
N-BUTANE 100 OEG F
197d AUG 1
CLOCK
TIME
830
930
1000
1015
1U30
1045
UvU
1115
1130
1145
1200
1215
123'J
1245
UdO
1315
1330
1345
1400
1415
1433
1445
1503
1515
153U
1545
1600
ELAPSED
T(MIN»
-90.
-30.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
******
0.86
0.86
******
******
******
1.00
******
******
******
1.12
******
******
**AUV*
1.25
******
******
******
1.38
******
******
******
1.46
******
******
******
1.70
PAN
PPM
******
******
0.000
******
0.002
******
0.002
******
0.003
******
0.005
******
0.006
******
0.008
******
0.011
******
0.014
******
0.018
******
J.023
******
0.027
******
0.034
HCHO
PPM
******
******
0.002
******
******
******
0.0
******
******
v**u*v
0.010
******
******
******
0.019
******
******
******
0.021
******
******
******
0.025
******
******
******
0.031
ACETALD
PPM
0.001
******
******
******
0.041
******
0.062
******
0.068
******
0.083
******
0.097
******
0.116
******
0.12J
******
0.15V
******
0.176
******
0.185
******
0.197
******
0.226
PROPALD
PPM
0.0001
******
******
******
******
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O.OOU3
******
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0.0003
******
0.0003
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0.0006
******
0.0007
******
0.0008
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0.0022
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0.0010
******
0.0023
******
0.0026
ACETONE
PPM
0.0005
******
0.0010
******
0.0030
******
0.0046
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0.0021
******
0.0031
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0.0037
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0.0047
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0.0077
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0.0077
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0.0170
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0.0071
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0.0096
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BUTYRAL
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0.0001
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0.0045
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0.0050
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0.0047
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0.0001
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0.0003
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0.0304
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0.0255
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O.OJ17
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0.0356
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0.0405
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0.0450
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0.0597
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0.0849
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0.0650
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0.0752
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0.1146
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0.0
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0.0003
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0.0005
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0.0005
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0.0005
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0.0005
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0.0006
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PPM
C-600
0.0
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0.0
******
0.0046
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0.0066
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O.OOdl
******
0.0098
******
0.0113
******
O.Ol^B
******
0.0142
******
O.OloO
******
0.0176
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0.0197
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0.0218
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0.0236
C4-N-2
PPM
PANALYZR
******
******
0.0
******
0.0029
******
0.0042
******
0.0057
******
0.0070
******
0.0061
******
0.0089
******
0.0104
******
0.0115
******
0.0130
******
0.0143
******
0.0155
******
0.0168
C4-N-1
PPM
PANALYZ*
******
******
0.0
******
0.0008
******
0.0015
******
0.0045
******
0.0053
******
0.0075
******
0.0075
******
0.0098
******
0.0090
******
J.0113
******
0.0135
******
0.0150
******
0.0158
-------
EC -309
N-BUTANE 100 DEC f
1976 AUG 1
CLOCK
TIME
830
933
1000
1015
1030
1045
1103
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1*15
1430
1445
1500
1515
1530
1545
1600
ELAPSED
T(MIN)
-90.
-30.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
3*5.
360.
TS
OEG F
******
******
101.1
99.4
98.9
100.4
101.1
100.9
101.1
101.1
101.1
101.1
100.9
100.9
101.1
101.1
101.1
101.4
101.4
101.6
101.6
100.9
101.6
******
******
******
******
REL HUM
*
******
******
30.0
32.0
34.5
35.5
35.5
35.5
35.5
35.5
35.5
35.0
35.5
35.0
35.0
35.0
35.0
35.0
35.0
34.5
34.5
34.5
34.5
******
******
******
******
SSPOrfER
KK
******
******
15.40
******
******
******
15.40
******
******
******
15.00
******
******
******
15.20
******
******
******
15.20
******
******
******
15.52
******
******
******
15.60
RADIOM
MW/CM2
******
******
0.261
0.269
0.264
0.269
0.261
0.261
******
******
0.259
******
******
******
0.261
******
******
******
******
0.254
0.252
0.254
0.26*
******
******
******
******
HCHO VCL
L
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -314
PKOPENE
1978 OCT
10
BEGIN IRRADIATION 0945! C.25 INCH PYRcX FILTER! TRICHROIC FILTER OUT
NEoMTIVc PEAK 4APPROX -2 CIVIS10NS) AT T=C CN PAN CHART AT 1.25 MIN RT
6iUUY 1193X, OASIBI 1212 (555 ML/MIN), TECO 14B-1 (585 ML/MIN)
T=U AT 945 POT
CALIB*
PAN
hCnO
REL INT
TS
REL HUM
SSPUhER
RADIOM
ri
-------
-p-
4>
oo
EC -314
PROPENE
1978 OCT 10
CLOCK
UME
845
930
•»45
1000
10i5
1030
1045
lluU
1115
1130
1145
1200
4.215
1230
1245
1300
iJl5
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
r
-------
EC -314
PKOPENE
1976 OCT 10
CLOCK
TIME
645
930
945
1000
1015
1030
1U45
1100
1115
1130
1145
UOO
1215
1230
1245
Ijl/O
1315
1330
1345
1400
1415
1430
1445
1500
1515
153i»
1545
ELAPSED
T(MIN)
-60.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
PAN
PPM
******
******
0.000
******
0.002
******
0.009
******
0.022
******
0.046
******
******
******
0.120
*!**¥**
0.133
******
0.157
******
0.190
******
0.160
******
0.226
******
0.215
hCHO
PPM
******
******
C.045
******
******
******
0.222
******
******
******
C.381
******
******
******
******
******
C.519
******
0.523
******
******
******
0.450
******
******
******
C.363
ACETALO
PPM
O.C01
******
0.002
******
0.123
******
0.225
******
0.255
******
0.357
******
0.441
******
0.430
******
0.4CU
******
0.355
******
0.317
******
0.2S7
******
0.267
******
0.264
PROPALO
PPM
0.0001
******
0.0001
******
0.0014
******
0.0029
******
O.C031
******
0.0037
******
0. 0048
******
O.OOoO
******
0.0056
******
0.0049
******
0.0022
******
0.0021
******
0.0034
******
0.0032
ACETONE
PPM
0.0002
******
0.0005
******
O.OOC6
******
0.0018
******
0.002U
******
0.0033
******
0.0045
******
0.0057
******
0.0061
******
0.0115
******
0.0050
******
0.0044
******
0.0073
******
0.0077
BUTYRAL
PPM
0.0001
******
0.0001
******
******
******
0.0001
******
0.0002
******
0.0004
******
0.0004
******
0.0003
******
******
******
******
******
******
******
******
******
******
******
******
MEK
PPM
0.0001
******
0.0001
******
0.0002
******
0.0003
******
0.0003
******
O.OOJ5
******
U.OOQ6
******
0.0007
******
0.0008
******
0.0008
******
O.U008
******
0.0009
******
0.0011
******
0.0010
PROX
PPM
0.0
******
0.0
******
******
******
0.0014
******
0.0015
******
0.0022
******
0.0034
******
0.0064
******
0.0054
******
0.0069
******
0.0025
******
0.0033
******
0.0051
******
0.0069
ME-N
PPM
******
******
U.O
******
O.OOOJ
******
U. 01)05
******
0.0009
******
0.0014
******
******
******
O.OU30
******
0.0026
******
0.0029
******
O.OCI31
******
0.0026
******
0.0031
******
0.0031
McTHANE
PPM
1.46
******
1.46
******
******
******
******
******
******
******
******
******
******
******
1.44
******
******
******
******
******
******
******
******
******
******
******
1.46
ETHANE
PfH
0.0103
******
0.0099
******
******
******
******
******
******
******
******
******
******
******
0.0101
******
******
******
******
******
******
******
******
******
******
******
O.OU99
EThcNE
PPM
0.0042
******
0.0041
******
******
******
******
******
******
******
*»«.***
******
******
******
O.ULiS
******
******
**** **
******
******
******
******
******
******
******
******
0.0025
ACETVLcN
t>PM
O.ov53
******
0.0046
******
******
******
******
******
******
******
******
******
******
******
O.OO47
******
******
******
******
******
******
******
******
******
******
******
O.OJ47
-------
Ui
o
ec -3i«
PROPENE
1978 OCT 10
CLOCK
TirtE
845
930
945
1000
1U15
1030
1045
UUO
1115
11JU
1145
UOO
1215
12 JO
1245
1300
1315
1330
13 -.5
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
TIMINI
-60.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC F
******
******
84.6
84.6
b4.6
64.6
85.4
66.1
66.4
66.1
66.4
£6.6
86.6
86.6
66.8
06.8
86.6
66.1
86.1
65.9
66.1
65.9
65.9
86.1
66.4
66.6
66.6
REL HUM
SE
******
******
******
4t,5
50.5
53.5
5s. 0
55.5
56.0
56.5
57.0
57.0
57.0
57.0
57.0
57.0
56.0
59.5
60.0
60.5
60.5
60.5
60.5
60.5
60.5
60.5
61.0
SSPOriER
KM
******
****.**
16.14
******
******
******
16. CU
******
******
******
16.24
******
******
******
16. CO
******
******
******
16.40
******
******
******
16.36
******
******
******
16.44
RACIOM
MW/CM2
******
******
******
0.261
******
******
0.256
******
******
******
0.261
******
******
******
******
0.256
0.256
0.261
0.261
0.261
******
******
0.264
0.261
0.261
0.261
0.261
HCHO VDL
L
******
******
20.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
******
******
20. CO
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
•ft-
Ul
EC -315
PROPENE 60 DEC f
1978 QCT 11
BEGIN IRRADIATION 0930; 0.25 INCH PYREX FILTER; TRICHROIC FILTER OUT
NEGATIVE PEAK JAPPROX -1.5 OIVISIONSJ AT T»0 ON PAN CHART AT 1.22 MIN RT
BRADY 1193X, DASIBI 1212 (555 ML/HIN), TECO 14B-1 (585 ML/MINI
T*0 AT 930 POT
CALIB*
PAN
HCHO
REL INT
TS
REL HUM
SSPGKER
RADIQM
M20
NO
N02-CC3R
PROPSNE
HCHC
ACETAUD
METHANE
ETHANE
eTHENE
ACETYLEN
DEG K
*
Krf
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
IN1T CCND
IN!T CONO
INIT CONO
IN1T CONO
INIT CQND
IMT COND
INIT CCNO
INIT CCNO
INIT CCND
289.5
57.18
16.43
0.260
1.040E
0.664
0.276
0.967
0.018
0.001
1.505
0.009
0.003
0.004
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: hAVELENGTHlNMi
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
Kl»0.49 MIN-1
SAMPLING PATE = 1.5CO L/MIN
50 GC SAMPLES TAKEN
REL.
INTENSITV
1.552
1.584
1.501
1.423
1.307
1.133
1.000
0.807
0.567
0.316
0.119
0.017
0.001
0.0
-------
EC -315
PROPENS 60 PEG F
197H ocr 11
U1
(0
LOCK
TIME
835
84U
921
930
9*5
1COO
1015
103J
1045
1100
1115
1130
1145
120C
1215
1230
1245
1300
1315
1330
13*5
uoo
1415
1430
1445
1500
1515
1530
ELAPSED
T(MIN)
-55.
-50.
-9.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
iao.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZCNE
PPM
******
******
******
0.000
0.000
0.000
0.000
0.002
0.010
0.015
0.024
0.039
0.049
0.066
0.086
0.103
0.125
0.142
0.164
0.166
0.208
0.230
0.247
0.271
0.208
0.305
0.330
0.344
NO
PPM
******
******
******
C.664
0.5<)f>
0.523
0.469
0.3U3
0.332
0.271
0.234
0.181
0.151
0.122
0.110
0.038
0.078
C.064
0.051
0.046
0.042
0.034
0.034
0.024
C.022
0.020
C.017
0.012
N02-CORR
PPM
******
******
******
0.275
0.332
0.398
0.431
0.488
0.527
0.573
0.5'86
0.609
0.614
0.612
0.612
0.594
0.578
0.559
0.533
0.5C4
0.475
0.452
0.419
0.393
0.361
0.331
0.302
0.277
NOX-CORR
PPM
******
******
******
0.942
0.92S
0.908
0.892
0.879
0.859
0.840
0.816
0.790
0.766
0.737
0.710
0.680
0.651
0.618
0.584
0.551
0.512
0.486
0.448
0.415
0.378
0.345
0.314
0.290
PROPEME
PPM
******
******
0.969
O.V67
0.917
0.869
0.841
0.768
0.724
0.678
0.629
0.560
0.544
0.504
0.470
0.428
0.312
0.355
0.322
0.293
0.261
0.234
0.211
0.185
0.165
0.145
0.123
0.112
-------
EC -315
PROPENE 60 DEC F
1978 OCT 11
OJ
CLOCK
TIME
835
840
921
930
945
1000
1014
1030
1045
1103
1115
1130
1145
1230
1215
1230
1245
13GU
1315
1330
1345
1400
1415
1430
1445
1503
1515
1530
ELAPSED
T(MIN»
-55.
-50.
-9.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
PAN
PPM
******
******
******
0.000
******
O.C01
******
0.003
******
0.008
******
0.015
******
0.024
******
0.035
******
0.047
******
0.061
******
0.074
******
0.091
******
0.107
******
0.116
HCHO
PPM
******
******
******
0.013
******
******
******
C. 146
******
******
******
J.259
******
******
******
0.343
******
******
******
0.372
******
******
******
0.3U3
******
******
******
0.372
ACETALD
PPM
******
0.001
******
0.001
***
-------
EC -315
PP.OPENE 60 DEC F
1978 OCT 11
Ln
CLOCK
TIME
635
8*0
921
930
9*5
1000
1015
1030
10*5
1100
1115
1130
11*5
1200
1215
1230
12*5
1300
1315
1330
13*5
1*OQ
HIS
1*30
1**5
1500
1515
1530
ELAPSED
TIMINI
-55.
-50.
-9.
0.
15.
30.
*S.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
2*0.
255.
270.
285.
300.
315.
330.
3*5.
360.
TS
DEC f
******
******
******
58.9
bl.3
61.1
61.3
61.3
61.6
61.6
61.6
61.3
61.6
61.3
61.3
61.3
61.6
61.8
61.6
61.3
61.6
61.6
61.6
61.6
61.3
61.6
61.1
61.6
REL HUM
*
******
******
******
• 38.5
*3.5
*9.5
53.5
56.0
56.5
57.0
57.5
59.0
60.3
60.3
60.0
60.0
60.0
60.0
59.5
59.5
59.5
59.5
59.5
59.0
59.0
59.0
59.5
59.0
SSPOMER
KM
******
******
******
16.60
******
******
******
******
******
******
******
16.36
******
******
******
16. *0
**»*«*
******
******
16. *0
******
******
******
16.32
******
******
******
16.52
PAOIQM
Mirf/CM2
******
******
******
******
0.256
0.261
0.256
0.25*
0.261
0.259
0.259
0.259
0.261
0.261
0.25*
0.26*
0.266
0.261
0.259
0.259
******
******
******
0.26o
******
******
******
0.266
HCHO VOL
L
******
******
******
15.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -316
PRDPENE UOZ DEG F)
1978 OCT 12
BEGIN IRRADIATION 1000; 0.25 INCH PYF.EX FILTER; TRICHROIC FILTER OUT
NEGATIVE PEAK (APPROX -1.5 DIVISI3NSJ AT T»0 ON PAN SHART AT 1.18 HIM RT
BRAOY 1193X, DASIBI 1212 (555 ML/MINI, TECO 14B-1 (585 ML/MINI
T*0 AT 1000 POT
CALIB*
PAN
HCHO
REL INT
TS
REL HUM
SSP.WER
RAOIOM
H20
N?
N02-COPR
PROPENE
HCH7
ACcTALD
AC6TCNS
METHANE
ETHANE
ETHiNc
ACETrLEM
DEC K
*
KW
MW/CM2
PPM
PPM
PPH
PPM
PPM
PPW
PPM
PPM
PPM
PPK
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CONO
IN1T CONO
INIT CCND
INIT CCNO
INIT CCND
INIT CONO
INIT CCNO
INIT CONO
INIT CCND
INIT CCNO
312.1
67.46
0.262
4.612E 04
Oi735
0.246
1.070
0.017
O.C04
0.002
1.552
0.008
0.003
G.C03
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION:
VtAVELENGTH(NN)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
290.
280.
REL. INTENSITY
Kl=0.51 MIN-1
SAMPLING RATE « 1.5C8 L/MIN
48 GC SAMPLES TAKEN
.469
.549
.481
.390
.2d3
.119
.000
0.807
0.565
0.313
0.118
0.017
0.001
0.0
-------
EC -316
PROPENE (102 DEC Fl
1978 OCT 12
CLOCK
TIME
905
951
10UJ
1015
1030
1045
1100
1115
1130
11*5
1200
1213
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1&15
1530
1545
1600
ELAPSED
T(MINI
-55.
-9.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
2TO.
285.
300.
315.
330.
345.
360.
OZONE
PPM
******
******
0.000
0.000
0.002
0.020
0.068
0.144
0.235
0.325
0.406
0.481
0.555
0.613
0.674
0.730
0.7B9
0.828
0.865
0.894
0.914
0.923
0.936
0.940
0.945
0.950
0.953
NO
PPM
******
******
0.735
G.520
0.349
C.208
0.125
0.071
0.054
0.051
0.027
0.022
0.027
0.022
0.015
0.020
0.020
0.020
0.017
0.020
0.015
C.OZO
0.010
C.017
0.015
0.010
0.017
N02-C3RR
PPM
******
******
0.246
0.440
0.577
0.631
0.724
0.717
O.fr76
0.056
0.572
0.514
0.4i5
0.394
0.338
0.279
0.232
0.180
0.151
0.134
0.120
0.091
0.009
0.055
0.058
0.060
0.069
NOX-CORR
PPM
******
******
0.982
0.957
0.921
0.884
0.344
0.785
0.725
0.699
0.601
0.544
0.477
0.413
0.355
0.298
0.247
0.208
0.171
0.151
0.130
o.m
0.082
0.068
0.071
0.077
0.083
PROPENE
PPM
******
1.070
1.070
0.933
0.818
0.712
0.603
0.497
0.412
0.320
0.247
0.183
0.131
0.092
0.065
0.043
0.027
0.017
0.011
0.006
0.004
0.004
******
0.003
******
0.002
0.002
-------
EC -316
PROPENE 1102 DEC F)
1978 OCT 12
CLOCK
TIME
905
951
1000
1015
1030
1045
n ao
1115
1130
1145
1200
1215
123J
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
ELAPSED
T(MIN)
-55.
-9.
a.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
PAN
PPM
******
******
0.000
******
0.004
******
0.020
******
0.047
******
0.082
******
0.109
******
0.156
******
0.196
******
0.220
******
0.230
******
0.270
******
0.264
******
0.247
HCHO
PPM
******
******
a. 017
• ******
******
******
0.318
******
******
******
0.560
******
******
******
J.586
******
******
******
0.526
******
******
******
0.452
******
******
******
0.372
ACETALD
PPM
0.002
******
O.C04
******
0.171
******
0.2&1
******
0.423
******
0.439
******
0.454
******
0.3U1
******
0.380
******
0.340
******
0.262
******
0.130
******
0.149
******
0.115
PRUPALO
PPM
0.0002
******
0.0002
******
0.0013
******
0.3025
******
0.0052
******
0. 005B
******
0.0051
******
0.0334
******
O.OU63
******
0.0034
******
0.0069
******
0.3035
******
0.0046
******
0.0066
ACETONE
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0.0009
******
0.0022
******
0.0036
******
0.0038
******
0.0133
******
0.0173
******
0.0216
******
0.0079
******
0.0307
******
0.0137
******
0.0303
******
0.0133
******
0.0142
******
0. 01 09
MEK
PPM
0.0001
******
0.0001
******
0.0002
******
0.0002
******
0.0004
******
0.0006
******
0.0008
******
0.0003
******
0.0014
******
0.0007
******
o.oou
******
0.0009
******
0.0009
******
0.0007
PROX
PPM
0.0
******
0.0
******
******
******
******
******
0.0048
******
0.0062
******
0.0055
******
0.0028
******
0.0071
******
0.0035
******
0.0072
******
0.0032
******
0.0051
******
0.0034
ME-N
PPM
******
******
0.0
******
0.0007
******
0.0010
******
0.0023
******
0.0030
******
0. 0036
******
0.0042
******
0.0038
******
0.0048
******
0.0047
******
0.0022
******
0.0020
******
0.0018
METHANE
PPM
1.S6
******
1.55
******
******
******
******
******
******
******
******
******
******
******
1.57
******
******
******
******
******
******
******
******
******
******
******
1.55
ETHANE
PPM
0.0087
******
0.0081
******
******
******
******
******
******
******
******
******
******
******
0.0068
******
******
******
******
******
******
******
******
******
******
******
0.0087
ETHENE
PPM
0.0031
******
0.0030
******
******
******
******
******
******
******
******
******
******
******
0.0024
******
******
******
******
******
******
******
******
******
******
******
0.0017
ACETVLEN
PPM
0.0034
******
0.0032
******
******
******
******
******
******
******
******
******
******
******
0.0033
******
******
******
******
******
******
******
******
******
******
******
0.0032
-------
EC -316
PROPENE 1102 DEC F»
1978 OCT 12
U1
oo
CLUCK
TIME
905
951
1000
101S
1030
10*5
1100
1115
11 30
11*5
12 JO
1215
1230
12*5
130J
1315
1330
13*5
1*00
U15
1*30
1**S
1530
1515
1530
15*5
1600
ELAPSED
TtMINi
-55.
-9.
0.
15.
30.
45.
60.
T5.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
2*0.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC F
******
******
102.6
100.6
100.1
100.*
101.1
101.*
102.1
102.1
102.1
102.1
101.9
101.9
102.8
102.6
103.8
102.8
102.3
102.1
101.9
102.1
102.3
101.9
102.3
101.9
102.8
REL HUM
S
******
******
59.5
61.5
6*.0
65.5
66.5
66.5
66.5
66.5
66.5
67.0
67.5
57.5
67.5
67.5
67.5
68.0
69.0
69.5
70.0
70.0
70.0
70.0
70.0
70.0
70.0
SSPDWEft
Kh
******
******
16.**
******
******
******
16.93
******
******
******
16.93
******
******
******
17.18
******
******
******
17.68
******
******
******
18.27
******
******
******
18.53
R» 310M
Mk«/CM2
******
******
0.2*9
0.26*
0.256
0.25*
0.266
0.259
0.266
0.25?
0.261
******
******
0.266
0.266
0.266
0.26*
0.26*
0.26*
0.261
0.2 36
0.25*
0.266
******
******
0.269
0.271
HCHO VOL
L
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -317
PRQPENE
1976 OCT 16
BEGIN IRRADIATION 0945J 0.25 INCH PYREX FILTER! TRICHROIC FILTER OUT
BRAOf 1193X, OASIBI 1212 (555 ML/MINI. TECO 14B-1 1585 ML/MINI
T«0 AT 945 POT
CALIB*
PAN
HCHO
REL INT
TS
REL HUM
SSPuHER
RAOIOM
H20
MO
N02-CGRR
PROPENE
HChO
ACETALO
ACETONE
ETHiKE
ETHENE
4CETVLEN
DEC K
J
KM
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
I NIT CQNO
INIT CCNO
1NIT CCNO
INIT CONO
INIT CCNO
INIT CCNO
INIT CONO
INIT CONO
INIT CONO
303.8
58.80
17.99
0.261
2.540E
0.256
0.281
0.493
0.007
0.002
0.001
0.009
0.003
0.004
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION:
Kl=0.53 MIN-1
SAMPLING RATE
WAVELENGTH!NM)
500.
430.
403.
3dO.
370.
360.
350.
340.
330.
320.
310. •
300.
290.
230.
270.
1.500 L/MIN
REL.
INTENSITY
1.470
1.516
.452
.373
.269
,110
.000
.810
.562
,310
,117
0.017
0.001
0.000
0.0
49 GC SAMPLES TAKEN
-------
ON
o
EC -317
PAOPENE
1978 OCT 16
CLOCK
TIME
855
930
9*5
1000
1015
1030
10*5
1100
1115
1130
1145
1200
1215
UJ3
12*5
1300
1315
1330
13*5
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
T11IN1
-50.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
303.
315.
330.
345.
360.
375.
390.
OZONE
PPM
******
******
0.0
0.012
0.027
0.051
0.085
0.125
0.166
0.203
0.244
0.276
0.315
0.344
0.374
0.401
0.427
0.452
0.479
0.503
0.523
0.542
0.557
0.576
O.S89
0.596
0.606
0.606
0.613
NO
PPM
******
******
0.256
' 0.206
0. 150
0.103
0.074
0.054
0.042
C.033
C.029
O.G27
0.022
0.016
0.016
0.013
C.015
0.015
0.011
0.013
0.011
C.OC7
0.007
0.004
0.006
0.012
0.012
0.013
0.005
N02-CORR
PPM
******
******
0.281
0.315
0.355
0.392
0.391
0.397
0.3<93
C.370
0.351
0.322
0.305
0.232
0.262
0.240
0.219
0.195
0.173
0.160
0.145
0.134
0.123
0.107
0.101
0.096
0.091
0.094
0.094
NOX-CQRR
PPM
******
******
0.530
0.516
0.502
0.488
0.467
0.449
0.426
0.401
0.377
0.346
0.323
0.297
0.277
0.251
0.227
0.205
0.188
0.163
0.151
0.143
0.136
0.116
0.109
0.104
0.104
0.104
0.103
PROPENE
PPM
******
0.485
0.493
0.432
0.396
0.351
0.306
0.266
0.236
0.191
0.161
0.134
0.108
0.090
0.071
0.058
U.045
0.036
0.028
0.021
0.016
0.013
0.009
0.007
0.005
O.OC4
0.003
******
******
-------
ON
EC -317
PPOPENE
1978 OCT 16
CLOCK
TIME
855
930
945
1000
lu!5
1030
1045
1100
111S
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
T(MIN)
-50.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
213.
225.
240.
255.
270.
285.
300.
315.
3?0.
345.
360.
375.
390.
PAN
PPM
******
******
0.000
******
0.003
******
0.310
******
0.022
******
0.035
******
0.050
******
0.065
******
0.076
******
******
******
0.107
******
0.114
******
0.126
******
0.130
******
******
HCHO
PPM
******
******
0.007
******
******
******
0.159
******
******
******
0.222
******
******
******
0.263
******
******
******
0.254
******
******
******
0.218
******
******
******
0.190
******
******
ACETALD
PPM
0.0 02
******
0.002
**«**«
0.072
*****>*
0.114
******
0.163
******
0.193
******
0.202
******
0.205
******
O.VS8
******
0,170
******
0.164
******
0.116
******
O.llt)
******
0.039
******
******
PROPALD
PPM
0.0002
******
0.0002
******
0.0007
******
0.0009
******
0.0014
******
0.0025
******
0.0022
******
0.0028
******
0.0029
******
0.0027
******
0.0037
******
0.0021
******
0.0032
******
0.0026
******
******
ACETONE
PPM
0.0002
******
0.0005
******
0.0019
******
0.0012
******
0.0043
******
0.0071
******
O.OU27
******
0.0088
******
O.OOSb
******
0.0099
******
0.0112
******
0.0041
******
0.0066
******
0.0043
******
******
MEK
PPM
0.0001
******
0.0001
******
0.0001
******
0.0003
******
0.0005
******
0.0005
******
0.0006
******
0.0009
******
0.0010
******
0.0011
******
0.0011
******
0.0010
******
0.0012
******
0.0010
******
******
PROX
PPM
0.0
******
0.0
******
******
******
******
******
******
******
******
******
******
******
0.0010
******
0.0014
******
0.0011
******
0.0317 .
******
******
******
0.0013
******
0.0005
******
******
ME-N
PPM
******
******
0.0
******
0.0
******
0.0004
******
0.0007
******
0.0007
******
0.0010
******
0.0013
******
0. OOV3
******
******
******
0.0014
******
0.0014
******
0.0014
******
0.0014
******
******
METHANE
PPM
1.57
******
******
******
******
******
******
******
******
******
******
******
******
******
1.58
******
******
******
*¥****
******
******
******
******
******
******
******
1.56
******
******
ETHANE
PPM
0.0091
******
0.0090
******
******
******
******
******
******
******
******
******
******
******
0.00b7
******
******
******
******
******
******
******
******
******
******
******
0.0085
******
******
ETHENE
PPM
0.0035
******
0.0033
******
******
******
******
******
******
******
******
******
******
******
0.0026
******
******
******
******
******
******
******
******
******
******
******
o.ooia
******
******
ACETlfLEN
PPM
0.0042
******
0.0041
******
******
******
******
******
******
******
******
******
******
******
0.0039
******
******
******
******
******
******
******
******
******
******
******
0.0036
******
******
-------
EC -317
PROPENE
197d OCT 16
CLOCK
TIME
855
930
945
1000
lOlb
1030
1045
1100
1115
1130
llt!>
12JO
1215
1230
1245
UOO
I31i
1330
1345
1400
1415
1<»30
1443
1500
1515
1530
1545
1600
1615
ELAPSED
T(HIN)
-50.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
375.
390.
TS
DEC F
******
******
82.8
65.2
85.2
66.2
87.0
U7.2
87.9
87.9
87. 4
87.7
87.4
87.2
86.7
87.2
87.0
87.0
87.2
87.2
87.2
87.2
87.2
67.2
87.4
87.7
87.7
87.7
67.4
REL HUM
%
******
******
44.5
48.0
52.0
55.0
56.0
56.5
56.5
56.5
57.5
58.5
59.5
60.0
61.0
61.5
62.0
62.0
62.0
62.0
62.0
61.5
62.0
61.5
61.5
61.5
61.0
61.5
61.3
SSPCWER
Kfc
******
******
******
******
18.05
******
17.89
******
******
******
17. dO
******
******
******
17.81
******
******
******
******
******
******
******
17.93
******
******
******
18.49
******
******
R40IO.M
MH/CM2
******
******
O.Z47
0.259
0.254
0.269
0.259
******
******
******
0.261
0.259
******
******
0.261
******
******
******
******
******
******
******
0.259
0.252
0.264
0.269
0.266
0.264
0.269
HCHO VOL
L
******
******
15.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
-------
U)
EC -310
PROPENE * PAN
1978 OCT 17
t
fiEGI-4 IRRADIATION 0930; 0.25 INCH PYREX FILTER; TRICHROIC FILTER OUT
2-C30N02 IS SUM OF 2-C30N32 C C23M02
BRAD* 1193X, DASIBI 1212 J555 ML/MIN)t TECO 148-1 (505 ML/MINI
OdSOJ PROPENE AND 1.047 LITERS PAN FROM TANK #10 ADDED. 0857-0859: FANS ON.
0903-J920: N02-UNCORR (TEC3 143-1) = 0.138 PPM
0920: N02 ADDED. 0924: NO ADDED. 0923-0925S FANS ON.
0925: NO * 0.210 PPM. NC2-UNCORR (TECO 148-11 * 0.358 PPM.
T=0 AT 930 POT
CAL1DK
riCHO
PAN
REL INT
TS
REL HUM
SSPJh=R
RADIDW
H2D
l«li
N02-CORR
PROPEME
PtM
HCHO
ACETONE
HE-N
C3-N-1
C3-N-2
C4-N-2
METHANE
ETH&Ht
ETHENE
ACE1VLEN
DEC K
%
K*
MW/CM2
PPH
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
3
9
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
IN IT CCND
INIT CONO
INIT CCND
INIT CONO
INIT CCND
INIT CCND
U4IT CCMO
INIT CCNO
INIT COND
INIT CCND
INIT CONO
INIT CCNO
INIT CONO
INIT CCND
303.3
60.
-------
EC -313
PPOPENE » PAN
1973 OCT 17
SPECTRAL DISTRIBUTION: hAVELENGTHINM) REL. INTENSITY
500. 1.485
430. 1.57Z
'.OS. 1.513
330. 1.413
370. 1.278
360. 1.117
350. 1.000
340. C.610
330. 0.555
320. 0.304
310. 0.115
300. 0.017
290. 0.000
280. 0.0
Kl»0.53 NlN-1
SAMPLING RATE » 1.489 L/HIN
62 GC SAMPLES TAKEN
-------
-p-
ON
Ln
EC -318
PP.GPENE +
PAN
1978 OCT IT
CLOCK
TIM"
830
905
915
933
9*5
1000
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
ELAPSED
TtMINI
-60.
-25.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
IdO.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
OiGNE
PPM
******
******
******
0.0
0.031
0.159
0.232
0.291
0.349
0.396
0.435
0.471
0.506
0.535
0.564
0.591
0.616
0.638
0.652
0.664
0.679
0.6S6
0.689
0.669
0.669
0.684
0.684
0.684
NO
PPM
******
******
******
• 0.172
0.033
0.049
0.046
0.029
0.023
0.017
0.017
0.016
0.010
0.013
0.01J
0.010
O.OJ9
0.012
0.010
C.013
0.007
0.007
0.009
C.012
0.010
0.016
0.006
0.009
N02-CORR
Pf>*
******
******
******
0.276
0.303
0.348
0.378
0.394
0.388
0.390
0.369
0.355
0.336
0.310
0.290
0.267
0.248
0.224
0.245
0.293
0.162
C.150
0.136
0.129
0.114
0.106
0.102
0.095
NOX-CORR
PPM
******
******
******
0.918
O.d74
0.791
0.706
0.596
0.496
0.413
0.374
0.354
0.0
0.0
0.0
0.0
0.0
0.0
0.119
0.108
0.106
0.101
0.102
0.094
0.094
0.092
0.092
0.094
PROPENE
PPM
0.000
0.535
******
0.509
0.397
0.345
0.276
0.232
0.176
0.137
0.109
0.083
0.062
0.046
0.035
0.026
0.019
0.014
0.010
0.007
0.005
0.003
0.002
0.002
0.001
0.001
0.001
0.000
PAN
PPM
******
******
0.125
0.072
0.062
0.063
O.OoS
0.073
0.076
0.084
0.093
0.102
0.110
0.119
0.126
0.131
0.142
0.149
0.155
0.153
0.155
0.157
0.166
0.162
0.161
0.162
0.158
0.153
-------
EC -318
PROPENE » PAN
1978 OCT 17
CtCJCK
TIME
630
90b
915
930
9*5
10JJ
1015
1030
1045
1100
UlS
1130
11*5
12JO
1215
1230
12 VJ
13JO
*• 1315
<£ 133U
1345
1*00
1415
143J
14*5
15JJ
1515
1530
ELAPSED
TIMIS)
-60.
-25.
-15.
0.
15.
30.
*5.
63.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
HCHO
PPM
******
******
******
0.019
******
******
******
******
0.019
******
******
******
0.297
******
******
******
0.266
******
******
******
0.236
******
******
******
0.182
******
******
******
ACETALO
PPM
0.001
0.002
******
*******
******
0.130
******
0.163
******
0.19J
******
0.216
******
0.198
******
0.182
******
0.146
******
0.123
******
0.101
******
0.066
******
0.056
******
0.065
PROPALD
PPM
0.0001
0.00 Jl
******
******
******
0.0014
******
0.0013
*****A
O.CJ22
******
0.0034
**<**•**
0.0033
******
0.0036
******
0.00)6
******
0.0039
******
0.0037
******
0.0059
******
0.0053
******
0.0045
ACETONE
PPM
0.0003
0.0006
******
0.0009
******
0.0047
******
0.0033
******
0.0063
******
o.oin
******
0.0087
******
0.0103
******
0.0138
******
0.0109
******
0.3132
******
0.0040
******
0.0109
******
0.0164
MEK
PPM
0.0
******
******
******
******
******
******
0.0002
******
0.0005
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0.0007
******
0.0007
******
0.0008
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0.0009
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0.0006
******
0.0012
******
0.0005
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0.0003
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0.0006
PROX
PPM
0.0
******
******
******
******
******
******
******
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******
******
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******
******
******
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******
******
******
******
0.0006
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0.0004
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0.0011
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PPM
PANALYZR
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******
0.0154
0.0140
0.01*5
0.0145
0.0148
0.0149
0.0144
0.0150-
0.0145
0.0146
0.0146
0.0145
0.01*4
0.0144
0.0143
0.0141
0.0141
0.0140
0.0138
0.0140
0.0140
0.0137
0.0135
0.0135
0.0134
0.0137
C3-N-1
PPM
C-600
0.0009
0.0038
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0.0037
******
0.0037
******
0.0037
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0.0036
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******
******
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******
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0.0031
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0.0034
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PPM
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******
******
0.0013
O.O012
0.0014
0.0012
0.0013
0.0011
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0. J015
0.0011
C.0011
O.OUii
0.0010
0.0011
0.0013
0.0011
0.0011
O.U011
0.0008
0.0011
0.0011
0.0011
0.0011
0.0014
0.0011
0.0011
0.0011
C4-N-2
PPM
C-600
0.0003
0.0046
******
0.0046
******
O.0043
******
0.0033
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0.0038
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0.0045
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0.0036
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0.0035
******
0.0035
******
******
******
******
******
******
******
******
******
0.0031
METHANE
PPM
1.35
1.34
******
1.34
******
******
******
******
******
******
******
******
******
******
******
1.34
******
******
******
******
******
******
******
1.34
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******
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ETHANE
PPM
0.0076
0.0078
******
0.0078
******
******
******
******
******
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******
******
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0.0077
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0.0074
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ETHENE
PPM
0.0v)
-------
EC -318
PROPENE * PAN
IS78 OCT 17
CLOiK
TIKE
830
905
915
930
9*5
1000
1015
1030
10*5
1100
1115
1130
11*5
1200
U15
1230
12*5
1300
1315
1330
13*5
1*00
1*15
1*30
l**5
1500
1515
1530
ELAPS5D
KMINI
-60.
-25.
-15.
0.
15.
30.
*5.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
2*0.
255.
270.
285.
300.
315.
330.
3*5.
360.
ACETYIEN
PPH
0.0033
0.0034
******
G.0034
******
******
******
******
******
******
******
******
******
******
******
0.0031
******
******
******
******
******
******
******
0.0028
******
******
******
******
PROPANE
PPM
0.0010
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
I-C*
PPM
0.0001
******
******
******
******
******
******
******
******
******
******
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******
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******
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******
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******
******
******
******
******
******
******
******
******
******
-------
oo
CC -318
PROPENE »
PAN
1978 OCT 17
CLOCK
TIME
830
903
915
930
945
IOOJ
1015
1030
1045
1100
1115
1130
1145
1200
1215
I.I3J
1245
1300
1315
133J
1345
1400
1415
143J
1445
1500
1515
1530
ELAPSED
TCMINI
-60.
-25.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
ISO.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
OEG F
******
******
******
85.7
86.0
87.7
88.4
87.7
88.2
88.7
87.4
87.4
87.4
87.7
87.9
87.9
88.2
88.4
88.2
88.2
88.9
90.4
89.6
88.2
87.7
87.2
87.4
87.4
REL HUM
S
******
******
******
******
63.0
64.0
64.5
64.5
65.5
65.5
66.5
67.5
67.5
68.0
68.0
68.0
68.0
68.0
68.0
68.0
67.5
66.5
66.0
67.0
67.5
68.5
68.5
68.5
SSPCMER
KM
******
******
17.40
18.17
******
******
******
******
17.93
******
******
******
18.27
******
******
******
18.19
******
******
******
18.14
******
******
******
18.14
******
******
******
RAO I OS
MW/CH2
******
******
******
0.256
0.269
0.264
0.259
0.256
0.259
0.261
0.261
0.256
0.259
0.264
0.259
0.261
0.256
0.261
0.261
0.259
0.256
0.261
0.256
0.254
0.259
0.256
0.264
0.269
HCHO VOL
L
******
******
******
20.00
******
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
-------
EC -319
PRGPENE * PAN
197d OCT 18
BEGIN IRRADIATION 1130; 0.25 INCH PYREX FILTER; TRICHROIC FILTER OUT
2-C3UNP2 IS SUM OF 2-C3CN02 £ C20N02
BRADY 1193X, DASIBI 1212 (555 ML/MIN), TECO 146-1 (565 ML/MIN)
1044: PROPENE AND 1.047 LITERS PAN FROM TANK #10 ADDED.
1100: ADDITIONAL 1.047 LITERS PAN FRCM TANK #10 ADDED. 1053-lllOs FANS ON.
1123: N32 AND NO ADDED. 1123-1129.5: FANS ON.
T=0 AT 1130 PDT
PAN
HCHO
REL INT
CALIB*
9
3
4
TS
REL HUM
SSP?V«ER
RADIOM
H<;G
'10
N02-CCPR
PRUPENE
PAN
HCHU
ACETUD
ACETONE
ME-N
C2-N
C3-M-2
C4-D-2
METHANE
ETHANE
ETHENE
ACETYLEN
DEG K
J
K.H
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT COND
INIT COND
INIT COND
INIT CONO
INIT CCNO
INIT CCND
INIT CCND
INIT CCND
INIT COND
INIT CCND
INIT CCND
INIT CCND
INIT CONO
INIT COND
INIT CCND
302.9
5^.02
18.79
0.260
2.410E 04
0.100
0.430
0.502
0.149
0.029
0.030
O.OU1
0.029
0.007
0.003
0.010
1.419
O.iHO
0.003
0.005
ASSIGNED INITIAL CONDITION
-------
tC -319
PROPENE » PAN
1978 OCT 18
SPECTRAL DISTRIBUTION: V.AVELENGTH(NMI REL. INTENSITY
500. 1.672
430. 1.653
403. 1.605
380. 1.435
370. 1.306
360. 1.129
350. 1.000
340. 0.790
330. 0.542
320. 0.291
310. 0.100
300. 0.003
290. 0.0
Kl«0.55 MIN-1
SAMPLING RATE » 1.513 L/MIN
58 GC SAMPLES TAKEN
-J
O
-------
EC -319
PROPENE + PAN
1978 OCT la
CLOCK ELAPSED OZCNE
TtME TtMINI
1025
1110
1115
1130
11*5
1200
1215
1230
12*5
1300
1315
1330
13*5
1-.00
l*la
1*30
1**5
15JJ
1515
1530
15*5
1600
1615 .
1630
16*5
1700
1715
1730
-65.
-20.
-15.
0.
15.
30.
*5.
60.
75.
90.
105.
120.
135.
150.
165.
iao.
195.
210.
225.
2*0.
255.
270.
285.
300.
315.
330.
3*5.
360.
PPM
******
0.000
0.000
0.0
0.1*7
0.2**
0.320
0.396
0.**7
0.498
0.5*2
0.579
0.613
0.6*5
0.672
0.699
0.716
0.733
0.7*5
0.750
0.755
0.752
0.750
0.752
0.7*7
0.7*7
0.750
0.7*7
NO
PPM
******
0.007
0.010
0.100
0.059
0.039
0.02*
C.02*
0.015
0.023
0.012
0.015
0.012
0.015
0.012
C.007
0.012
0.010
0.010
0.012
0.010
0.010
0.012
0.010
0.012
0.007
0.007
0.010
PPM
******
0.051
0.051
0.430
0.*56
0.*6J
0.426
0.392
0.360
0.319
0.292
0.26*
0.236
0.193
0.178
0.1**
0.132
0.122
0.119
0.118
0.113
0.120
0.105
0.117
0.111
0.135
0.105
0.102
NOX-CO*R
PPM
******
0.056
0.056
0.530
0.51*
0.432
0.*52
0.41*
0.369
0.332
0.305
0.269
0.2**
0.200
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0.156
0.1**
0.125
0.113
0.123
0.120
0.125
0.120
0.115
0.102
0.103
0.110
0.105
PROPENE
PPM
0.000
0.545
******
0.502
0.391
0.325
0.26*
0.198
0.150
0.117
0.087
0.066
0.0*8
0.03*
0.025
0.01B
0.013
O.JC9
0.006
O.OC5
0.003
0.002
0.002
0.001
0.001
0.001
0.000
0.000
PAN
PPM
******
******
0.157
0.1*9
0.13*
0.123
0.129
0.1*0
0.1*6
0.152
0.158
0.169
0.173
0.192
0.196
0.207
0.203
0.213
0.219
0.212
******
0.208
******
0.213
******
0.213
******
0.207
-------
EC -319
PP3PENE »
PAN
1978 OCT 18
CLOCK
TIME
1025
1110
1115
113J
1145
1200
1215
1230
1245
1300
1315
1330
1345
It 00
1415
143J
1445
1500
1515
1530
15*5
1600
1615
1630
1645
1700
1715
1730
ELAPSED
TIHINI
-65.
-20.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
183.
195.
-------
EC -319
P^OPENE * PAN
1976 OCT IB
CLOCK
TIME
1025
1110
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1433
1445
1500
1515
1530
I54i
1600
1615
163J
1645
1700
1715
1730
ELAPSED
TIM1M)
-65.
-20.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
iao.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
ACETVLEN
PPM
0.0046
0.0046
******
0.0045
******
******
******
******
******
******
******
******
******
******
******
0.0046
******
******
******
******
******
******
******
******
******
******
******
0.0039
PROPANE
PPM
0.0012
******
******
*******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
1-C4
PPM
0.0001
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
-------
EC -319
PRCJPENE *
PAN
19T8 OCT 18
CLOCK,
TI«=
1034
mo
1115
1130
1145
120J
1215
1230
1245
1300
1315
133J
1345
1403
1415
1430
1443
1SOO
1515
1530
1545
1600
1615
1630
1645
1700
1715
1730
ELAPSED
TtMIN»
-65.
-20.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
iao.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC F
******
84.0
84.3
84.3
65.7
85.2
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87.0
85.5
85.5
65.7
85.7
86.7
86.7
86.7
66.7
86.0
65.7
87.0
86.2
86.5
86.7
85.7
65.5
86.0
85.7
85.7
65.2
REL MU,1
t
******
44.0
44.0
43.0
46.0
50.5
53.0
54.5
56.0
59.0
60.5
61.0
61.0
61.3
62. C
63.5
64.5
65.5
65.5
65.5
65.5
65.5
65.5
65.5
65.5
65.5
66.0
66.0
SSPQrfER
KH
******
******
******
16.43
******
******
******
18.48
******
******
******
******
******
******
******
16.92
******
******
******
18.92
******
******
******
18.79
******
******
******
19.18
RADIO*
MH/CM2
******
******
******
0.261
0.264
0.259
0.254
J.261
0.271
******
******
0.261
0.261
0.259
0.259
0.259
0.256
0.259
0.261
0.264
0.261
0.259
0.252
0.256
0.261
0.264
0.266
0.264
HCHO VOL
L
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -320
PRGPcNt + PAN
1978 OCT 19
BEGIN IRRADIATION 0945; C.25 INCH PYREX FILTEKj TRICHRQIC FILTER OUT
2-C30N02 IS THE SUM OF 2-C30N02 t C2CN02
6RAOV U9iX, DAS18I 1212 1555 ML/MIN), TECO 14B-1 1585 ML/HIN)
0903: PROPENE ADCEC. REFILL AIR BAG, FOUND ACCIDENTLY LEFT CPENt IS CLOSED
J9U6: APPROX 500 ML PAN FROM TANK *10 ADDED. 0904-0911: FANS CN.
1402 AND NO ADDED. C9JV-0956: FANS CN.
T=0 AT 945 POT
PAN
HCHO
HcL INT
CALIB#
9
3
4
TS
REL HUM
SSPuncR
RADIuM
H2C
t,J
Nui-C~SR
PKOPENc
PAiN
ACETALD
ME-N
C2-N
C-.-N-2
METHANE
ETnANE
ETriENE
ACtTVLEN
UEG K
-------
EC -320
PROPENE + PAN
197B OCT 19
SPECTRAL OISTMBUTICNS hAVELENGTHCNMJ REL. INTENSITY
500. 1.579
430. 1.673
403. 1.512
380. 1.408
370. 1.345
360. 1.135
350. l.COO
34C. 0.812
330. 0.5&5
320. 0.299
310. 0.103
300. 0.014
29C. 0.0
Kl*0.55 MJN-1
SAMPLING RATE = 1.510 L/M1N
53 GC SAMPLES TAKEN
-------
-p-
ec -320
PRQPENE +
PAN
1978 OCT 19
CLOCK
TIME
&40
900
920
945
1000
10 li
1030
1045
liOO
1115
1130
11<*5
1200
1215
U30
U4S
1300
1315
1330
13t5
1400
1415
1<*30
1445
1500
1515
1=30
1545
ELAPSED
TCMINJ
-65.
-45.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
3*5.
360.
OZONE
PPM
******
******
******
0.4)00
0.034
0.078
0.120
0.173
0.222
0.266
0.3 1C
0.3
-------
oo
EC -320
PROPENE *
PAN
iS78 OCT 19
CLOCK
TIME.
840
900
920
945
1COO
1015
1030
1043
1100
1115
112,0
1145
1200
1215
1230
1245
1300
1315
mo
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
T(MIN)
-65.
-45.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
HCHO
PPM
******
******
******
******
0.067
******
******
0.168
******
******
******
0.268
******
******
******
0.266
******
******
******
0.241
******
******
******
0.199
******
******
******
0.172
ACETALD
PPM
C.001
******
0.002
0.011
******
C.104
******
C.158
******
c.iai
******
0.213
******
0.228
******
0.202
******
C.187
******
0.142
******
C.137
******
C.104
******
0.104
******
0.077
PROPALO
PPM
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******
0.0001
******-
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0.0014
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0.0025
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0.0034
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0.0026
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0.0029
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0.0044
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0.0054
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0.0017
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O.JC84
O.OOU2
******
O.OOoO
******
0.0078
******
0.0080
******
0.0078
C2-N
PPM
C-600
0.0009
******
0.0023
0.0022
******
0.0023
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0015
******
0.0014
******
0.0011
C3-N-2
PPM
PANALYiR
******
0.0
******
0.0003
0.0003
0,0003
0.0005
O.OOuS
O.uu05
cuuOCS
0.0u04
0.0005
******
0.0005
0.0005
0.0007
******
******
0.0003
0.0005
******
0.0005
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0.0007
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0.0003
******
0.0005
C4-N-2
PPM
C-6UO
0.0008
******
u.Olue
O.OOlfa
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******
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******
******
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C.0ul4
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0.0u22
******
0.0015
METHANE
PPM
1.46
******
1.47
1.-.7
***** *
******
******
»w**»*
******
»»»«.<-«
******
******
******
******
******
1.47
******
******
******
******
******
******
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1.47
ETHANE
PPM
O.OOoO
******
0.0076
O.OJ76
******
******
******
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******
******
******
******
******
******
L.GOoO
******
******
******
******
******
******
******
******
******
******
******
0.0076
-------
-J
VD
eC -320
PRGPtNE +
PAN
1978 OCT 19
CLOCK
TIME
840
900
920
945
10JJ
lOli
1030
1^45
iluO
ilia
11 iJ
1145
1200
1213
ii3t)
U45
1300
i315
1330
1345
l4uO
1415
1430
1445
1500
1513
1S30
1545
ELAPSED
T1M1NI
-65.
-45.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
ETHENE
PPM
O.OOJ1
******
0.0030
Q~u031
******
******
******
******
******
******
******
******
******
******
******
0.0024
******
******
******
******
******
******
******
******
******
******
******
0.0017
ACETYLEN
PPM
0.0045
******
0.0044
0.0043
******
******
******
******
******
******
******
******
******
******
******
0.0041
******
******
******
******
******
******
******
******
******
******
******
C.0041
ACETYLEN
PPM
0.0044
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
PrtOPANE
PPM
0.0010
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
I-C4
PPM
0.0001
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
-------
CO
o
EC -320
PROPENE »
PAN
1978 OCT 19
CLOCK
TJMc
640
900
920
9t3
1000
1015
1030
lOtS
lluO
llii
1130
1145
1200
1£G F
******
******
******
64.0
64.0
67.0
66.5
66.7
67.0
66.5
67.0
66.5
86.5
66.2
06.5
66.7
86.2
86.7
87.0
87.7
88.4
87.9
66.4
86.2
87.7
88.7
86.2
65.5
A EL HUM
*
******
******
******
47.5
52. C
57.0
60.0
62.0
64.0
66.0
67.0
67.0
67.5
67.5
67.5
o7.5
67.5
67.5
68.0
67.5
67.5
67.5
67.5
68.0
69.0
68.0
68.5
70.0
SSPOMER
KM
******
******
*4****
18.67
******
******
******
16.52
******
******
******
la. 82
******
******
******
18.66
******
******
******
18.92
******
******
******
18.83
******
******
******
18.91
RACIOM
MW/CM2
******
******
*¥****
0.251
0.266
0.264
0.259
0.259
******
******
******
******
******
******
******
0.261
C.257
0.259
0.256
0.259
0.256
0.261
0.259
0.256
0.264
0.261
0.261
0.264
HCHO VOL
L
******
******
******
******
15.00
******
******
20. CO
******
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
•e-
co
EC -327
TOLUENE
1973 NOV 2
BEGIN IRRADIATION 0930! 0.25 INCH PYREX FILTER! TRICHROIC FILTER OUT
TENAX bC SAMPLES COLLECTED, BUT NJ RELIABLE DATA OBTAINED
TENAX VOLUME ESTIMATED AT 40 LITERS TOTAL
BRADY 1193X, DASIbl Itli (SoO ML/MIM, TECO 14B-1 (560 ML/MINJ USED
T=0 AT 930 PST
CALIB#
PAN
hCHO
REL INT
TS
SSPGwER
RADIOM
NO
N02-CORK
TC4.UEN6
HCHO
ACETALD
METHANE
ETHANE
ETHENE
ACeTKLEN
PROPANE
OEG K
KH
Mw/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERACE
inn CCND
INIT CCNC
IMT CCNU
INIT CCND
INIT CCND
IMT CCND
INIT CCND
INIT CCNC
INIT CCND
INIT CCNO
303.4
15.16
C.192
0.357
0.096
C.573
0.013
C.Co2
1.264
O.CC6
0.003
0.003
O.C01
ASSIGNED INITIAL CONDITION
SPECTRAL DISTRIBUTION: hAVELENGTH(NM)
5CO.
430.
403.
380.
370.
B6C.
350.
340.
.330.
320.
310.
300.
290.
Kl-0.40 MIN-1
SAMPLING RATE « 1.6C3 L/MIN
28 GC SAMPLES TAKEN
REL.
INTENSITY
2.377
1.95S
1.722
1.484
1.354
1.147
'l.COO
0.733
0.429
0.277
0.104
0.006
0.0
-------
.p-
00
EC -327
TOLUENE
1978 NQV 2
CLOCK
TIME
825
915
V30
945
1000
1015
1030
1045
1100
1115
113J
1145
1200
1215
U30
1«!45
1300
1315
1330
1345
1400
1415
1430
1445
15UG
1515
1530
ELAPSEC
T(MIN)
-o5.
-15.
0.
15.
30.
43.
60.
75.
90.
105.
UO.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
OZuNE
PPM
******
0.000
0.000
0.000
0.000
0.000
O.OC5
0.007
0.017
0.029
0.039
0.056
0.013
0. C93
0.115
0.132
0.156
0.176
0.200
0.225
0.249
0.276
0.303
0.332
0.354
0.369
0.376
NO
PPM
******
0.351
0.357
0. jJ5
O.J04
c.iia
C.iio
C.168
0.1*15
0.117
C.094
C.071
C.057
C.046
0.044
0.034
0.028
0.024
C.021
C.Q20
C.C17
C.01B
0.013
0.012
0.013
C.013
0.012
N02-CJRR
PPM
******
O.C9o
0.096
o.ica
0.138
0.164
0.195
0.219
0.242
0.251
0.256
0.259
0.249
0.238
0.224
0.204
0.190
0.175
0.158
0.142
0.127
0.102
0. 066
0.070
0.052
0.046
0.036
NOX-CQRR
PPM
******
0.445
0.448
0.443
0.439
U.430
0.421
0.406
0.385
0.367
0.349
0.327
0.302
0.261
0.265
0.237
0.217
0.197
0.17o
0.153
0.142
0.116
0.097
0.060
0.064
O.C56
0.050
TOLUENE
PPM
0.000
0.572
0.573
******
0.540
******
0.511
******
0.462
******
0.439
******
0.4C7
******
0.383
******
0.355
******
0.329
******
0.3C4
******
0.276
******
0.248
******
0.226
-------
EC -327
TOLUENE
1970 NOV 2
CC.CCK
TIME
625
915
930
943
1000
10i3
1030
1045
1100
I 1 i a
1115
1130
1145
1200
1213
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
150J
1515
1530
ELAPStO
T(MIN)
-65.
-15.
0.
15.
30.
45.
60.
75.
90.
\ r\ e
1 05.
120.
135.
150.
165.
IdO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
PAN
PPM
******
******
c.occ
******
0.000
******
0.001
******
0.004
0.007
******
0.011
******
0.016
******
0.020
******
0.025
******
0.023
******
0.033
******
0.040
******
0.041
I-CHO
PPM
******
******
0.013
******
******
******
0.019
******
******
******
0.03d
******
******
******
0.042
******
******
******
0.052
******
******
******
0.051
******
******
******
0.059
ACETALD
PPM
O.CLC8
0.0012
0.0016
******
0.0026
******
0.0031
******
0.0042
******
0.0045
******
0.0057
******
0.0058
******
0.0071
******
O.OC68
******
0.0081
******
O.OC72
******
O.OOS5
******
O.CC76
PROPALO
PPM
******
******
0.0001
******
0.0001
******
******
******
0.0004
******
******
******
0.0010
******
******
******
0.0018
******
******
******
O.OOz?
******
******
******
0.0036
******
0.0017
ACETONE
PPM
0.0003
0.0003
0.0005
******
0.0012
******
0.0011
******
0.0026
******
0.0024
******
0.0050
******
0.0035
******
0.0076
******
0.0047
******
0.0095
******
0.0057
******
******
******
0.0066
8UTYRAL
PPM
******
******
0.0000
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
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MEK
PPM
0.0001
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0.0000
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0.0001
******
******
******
0.0000
*******
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******
0.0000
******
******
******
***¥«*
******
******
******
******
******
******
******
0.0001
******
******
ME-N
PPM
******
******
0.0
******
0.0
******
0.0002
******
0.0004
******
O.OU06
******
0.0007
******
0.0606
******
O.J009
******
0.0007
******
0.0007
******
0.0009
******
0.0007
******
0.0007
METHANE
PPM
1.36
******
1.36
******
******
******
******
******
******
******
******
******
******
******
1.33
******
*¥****
******
******
******
******
******
******
******
******
******
1.36
ETHANE
PPM
0.0062
******
O.u060
******
******
******
******
******
******
******
******
******
******
******
0.0058
******
******
******
******
******
******
******
******
******
******
******
0.0065
EThfcNt
PPM
0.0027
******
0.0026
******
******
******
******
******
******
******
******
******
******
******
O.Ouiu
**«¥**
***v**
***7V*
******
******
******
******
******
******
******
******
0.0014
ACETYLEN
PPM
(PN|
0.0032
******
U.C032
»*»***
******
******
******
7*****
******
******
******
*»*#**
******
'******
0.0034
******
******
******
******
******
******
******
******
******
******
******
0.0051
ACETYLEN
PPM
(DMSJ
0.0028
******
0. t>030
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
-------
CXI
EC -327
TOLUENE
1976 NOV 2
CLOCK
TIME
825
9X5
930
945
1000
i«Jl5
1030
1045
1100
1115
1130
1145
Ul/0
1215
1230
1245
1300
1315
1330
134a
i400
1415
1430
1445
1500
1515
153>>
ELAPSED
T(MIN»
-65.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ieo.
195.
210.
229.
240,
255.
2TO.
285.
300.
315.
330.
345.
360.
FRCPANE
PPM
C.0009
******
O.OOC9
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
FROPENE
PPM
Q.OOQ
******
C.OCO
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
1-C4
PPM
0.0000
******
O.COC1
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
-------
-p-
oo
EC -327
TOLUENE
1976 NOV 2
CLOCK
TIME
ti25
915
930
945
100J
loii
IGjO
1G45
1100
U15
1130
11*5
UOO
1215
12^0
1243
1300
1315
1330
1345
ItOO
1*15
1430
1445
1500
1515
1530
ELAPSED
T1MINJ
-65.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
25a.
270.
265.
300.
315.
3iO.
345.
360.
TS
DEC F
******
63.8
83.5
85.5
86.0
86. 7
86.2
87. C
87.7
87.0
87.0
67.2
67.0
86.2
86. 0
86.2
86.0
65.7
86.0
86.2
66.5
86.2
86.2
86.5
66.7
&6.7
87.0
SSPOwER
KM
******
******
15.16
******
******
******
14.76
******
******
******
15.30
******
******
******
15.33
****7*
******
******
15.06
******
******
******
15.02
******
******
******
15.50
RACICH
MM/CM2
******
******
0.195
0.168
0.166
C.186
0.1E6
0.193
0.163
0.188
0.193
0.195
******
******
0.195
******
***« **
*«*v**
0.190
0.193
******
******
0.188
0.193
0.195
0.195
0.193
hCHO VOL
L
******
******
20.00
***•***..-
******
******
20.00
******
******
******
20.00
******
******
******
20. OC
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
00
ON
EC -328
TOLUENE * N-BUTANE
1976 NOV 3
IRRADIATION 0900i 0.25 INCH PYREX FILTER, TRICHROIC FUTER OUT
PURE Alh REFILL BAG CPEN DURING INJECTIONS
NO TcNAX GC SAMPLES TAKEN
bRAL/l 1193X. DASIBI 1212 (560 ML/MINI, TECO 14B-1 (580 ML/KIN) USED
T-0 AT 900 PST
CALIBIH
PAN
HCMC
REi. INT
TS
REL HUM
SSPO-ER
AAiHOM
HiO
NO
N02-CORR
TOLUENE
N-C4
hCHO
ACcTCNE
METHANE
ETHANE
ETHbNE
ACETYLEN
DEG K
*
Krf
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPH
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
IMT CCNO
IMT CCND
INIT CCNO
INIT CCNC
INIT CCNO
INIT CCNO
IMT CCNO
INIT CCNO
INIT CCfcO
303.3
t5.54
15.37
0.193
2.77SC 04
0.349
C.100
0. 569
2.038
O.Olb
0.001
1.134
0.007
C.003
C.C04
ASSIGNED INITIAL CONDITION
SPECTRAL UISTftlBUTICN: hAVELENGTH(NM)
500.
43C.
403.
38C.
370.
36C.
350.
34U.
330.
320.
ilO.
300.
290.
Kl°0.40 MIN-1
SAMPLING RATE « 1.5C1 L/MIN
40 GC SAMPLES TAKEN
REL.
INTENSITY
2. 099
1.853
1.640
1.494
"l.335
1.141
1.000
0.78S
0.531
C.2o3
O.C9<.
O.OOJ
O.C
-------
EC -328
TOLUtNE + N-BUTANE
1976 NOV 3
00
-J
CLOCK
TIMe
750
637
900
9i5
930
945
1000
1015
1030
10*5
1100
llli
1130
ll-»5
1200
U15
123u
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
T(MIN)
-70.
-23.
0.
15.
30.
45.
60.
75.
90.
1C5.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
2TO.
285.
300.
315.
330.
345.
360.
OZONE
PPM
******
******
0.000
o.ooc
0.002
0.012
0.024
0.044
0.066
0.095
0.120
0.149
0.183
0.213
0.242
0.274
0.315
0.340
0.369
0.401
0.430
0.459
0.434
0.301
0.515
0.52C
0.523
NO
PPM
******
******
0.349
' C.302
0.237
0.177
C.132
0.098
0.074
0.056
C.046
C.038
0.033
C.029
0.026
0.022
c.o2i
c.oia
0.017
0.015
C.C15
0.018
0.015
C.015
0.012
C.012
C.013
N02-CQRR
PPM
******
******
C.100
0.141
0.195
0.244
0.277
0.292
0.295
C.298
0.286
C.272
0.257
0.242
0.2.28
0.2C9
0.194
0.170
0.150
0.125
C.1C4
0.094
0.083
0.069
0.059
0.051
0.048
NOX-CORR
PPM
******
******
0.449
0.440
0.429
0.419
0.407
0.386
0.368
0.349
0.330
0.306
0.289
0.268
0.250
0.230
0.211
0.185
0.165
0.145
0.127
0.109
0.094
0.030
0.070
0.061
0.059
TOLUENE
PPM
0.000
O.S67
0.569
******
0.520
******
C.alO
******
0.469
******
0.471
******
0.449
******
0.432
******
0.413
******
0.396
******
0.37S
******
0.362
******
0.349
******
0.333
N-C4
PPM
******
2.026
2.038
******
l.V7tt
******
1.929
******
1.8bO
******
1.632
******
1.800
******
1.759
******
1.719
******
1.686
******
1.639
******
1.613
******
1.5o4
******
1.540
-------
EC -328
TOLUENE + N-6UTANE
1976 NOV 3
CLOCK.
TIME
750
t)37
900
915
930
945
lOuO
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
•P- 1300
S l315
1330
1345
14uo
1415
I43u
1445
1500
ELAPSED
TiMIM
-70.
-23.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
loS.
180.
1 v5.
210.
225.
240.
255.
270.
2ba.
300.
i!5.
330.
345.
joO.
PAN
PPM
******
******
o.cco
******
0.001
******
0.004
******
0.010
******
0.016
******
0.024
******
0.030
******
0.037
******
0.047
******
0.056
******
0.063
******
0.071
******
0.074
hCHO
PPM
******
******
.C.015
******
******
******
0.069
******
******
******
0.052
******
******
******
C.063
******
******
******
C.083
******
******
******
0.069
******
******
******
0.086
ACETALD
PPM
0.001
******
******
******
0.017
******
0.036
******
0.048
******
0.067
******
0.075
******
O.C85
******
O.C99
******
0.104
******
0.104
******
0.106
******
0.114
******
0.117
PROPALD
PPM
0.0001
o.uooo
******
******
0.0001
******
0. 0003
******
O.OC05
******
0.0011
******
O.C021
******
0.0019
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0.0035
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0.0038
******
0.0032
******
0.0047
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0.0046
******
0.0048
ACETONE
PPM
O.OU03
0.0006
0.0007
******
O.OUll
******
0.0020
******
0.0028
******
0.0039
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0.0069
******
0.0078
******
0.0111
******
0.0128
******
0.0128
******
0.0156
******
0.0152
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0.0152
BUTYRAL
PPM
0.0
******
O.OOUl
******
0.0004
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0.0009
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0.0011
******
******
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0.0029
******
******
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0.0039
******
0.0038
******
******
******
0.0029
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0.0020
MEK
PPM
0.000
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0.000
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0.010
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0.024
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0.047 .
******
0.046
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0.061
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0.066
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0.081
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0.088
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0.091
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U.098
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0.114
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0.105
C2-N
PPM
******
******
0.0
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0.0
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0. 0001
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0.0001
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0.0002
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0.0003
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0.0003
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0.0002
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0.0004
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0.0003
******
0.0004
******
0.0004
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0.0004
C4-N-2
PPM
PANALYZR
******
******
0.0
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O.OJ17
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0.0032
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0.0059
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U.U071
******
0.0091
******
O.OU99
******
0.0109
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0.0127
******
0.0130
******
0.0142
******
0.0147
******
0.0157
METHANE
PPM
1.14
******
1.13
******
******
******
******
******
******
******
******
******
******
******
1.13
******
******
c*****
******
******
******
******
******
******
******
******
l.li
ETHANE
PPM
0.00&5
******
0.0065
******
******
******
******
******
******
******
******
******
******
******
0.00o5
******
******
******
******
******
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******
******
******
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0.0065
ETHENE
PrK
0.00£9
******
0.0u20
******
******
******
******
******
******
******
******
******
******
******
O.CU24
******
******
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******
******
******
******
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******
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O.CU21
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0.003J
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0. 003 o
******
******
******
******
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******
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O.GlinO
******
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**** * V
******
******
******
******
******
******
******
0.00-.9
-------
EC -326
TCLUeNE » N-BOTANE
1*76 NOV 3
-P-
oo
CLOCK
TJM£
75u
637
903
915
930.
945
1GCJ
1015
1030
1045
1100
Ilia
1130
Ilt5
1200
1215
1230
li4S
1300
1315
1330
1345
1400
1415
1430
1445
1500
ELAPSED
KMINJ
-70.
-23.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
TS
DEG F
******
******
85.5
66.2
66.2
65.2
65.5
85.7
86.2
Bo. 5
67. C
67.4
67.2
87.4
87.7
87.9
87.7
87.9
87.0
87.2
87.0
87.0
87.0
66.5
66.5
86.5
86.7
REL HUM
X
******
******
58.5
• 61.0
63.5
65.5
66.5
67.0
67.5
67.5
67.5
67.5
67.5
67. C
o7.0
67.0
b7.0
67. 0
67.5
66.0
66.0
68.5
68.5
66.5
68.5
68.5
69.0
SSPOirfER
KM
******
******
15.05
******
******
******
15. C6
******
*¥V***
***> **
15.23
******
******
******
15.31
******
******
******
15.62
******
******
******
15.75
******
******
******
15.54
RADICM
Mh/CM2
******
******
0.193
0.195
0.193
0.186
0.166
0.190
O.lBd
0.188
0.193
0.18d
0.183
0.168
0.193
0.190
0.183
0.188
0.195
0.198
******
******
0.205
0.193
0.195
0.193
0.195
HCHO VOL
L
******
******
20. CO
******
******
******
20.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
-------
EC -329
TOLUENE + PROPENE
197ti NOV 6
BEGIN IRRADIATION 09451 C.iy INCH PYREX FILTER; TMCHROIC FILTER OUT
SIX 100 ML SAMPLES TAKEN FOR RESEARCH AND DEVELOPMENT
BRAPV U93X, OASIBI 1212 (560 ML/MJM.TECC 14B-li(580 ML/MINI
T«0 AT 945 PST
PAN
HCMO
REL INT
CALIB0
9
3
4
VJD
O
TS
REt. MUM
SSPuWER
RADICM
H20
NO
NG2-£uRR
TQLuENe
PRuPENE
HCHO
ACcTALD
ACcTCNE
METHANE
cTHANE
ETHENE
ACETVLEN
OEG K
i
KM
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCND
INIT CCND
INIT CCNO
INIT CCNO
INIT CCND
INIT CCND
INIT CCNO
INIT CCNO
INIT CCNO
INIT CQNO
303.3
O.IS9
2.777E 04
0.352
0.102
0.555
C.098
O.C07
0.002
0.001
1.208
0.006
C.OU3
0.003
ASSIGNED INITIAL CCNDITION
SPECTRAL DISTRIBUTION: MVELENGTHCNM)
soo.
430.
403.
380.
370.
36C.
350.
340.
330.
.220.
310.
300.
290.
Kl«0.40 M1N-1
SAMPLING RATE - 1.510 L/MIN
S3 GC SAMPLES TAKEN
REL. INTENSITY
2.C67
l.«59
1.683
1.498
1.345
1.137
1.000
0.796
0.536
0.263
O.C96
0.003
0.0
-------
EC -329
TOLUENE * PRQPENE
1976 NOV 6
CLOCK
TIME
816
926
945
1000
10i5
103i>
1045
1100
1115
1130
1145
1200
1215
1230
Ii45
1300
1315
13*0
1345
1400
1415
1430
1445
1500
1315
153J
1545
ELAPSED
TtMINJ
-87.
-17.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
3oO.
315.
330.
345.
360.
OZONE
PPM
******
******
0.000
0.000
0.000
O.OQ2
0.012
0.027
0.044
0.006
0.068
0.120
0.142
0.171
0.198
0.232
0.261
0.291
0.322
0.349
0.376
0.393
0.403
0.403
0.398
0.391
0.384
NO
PPM
******
******
C.352
0.322
0.265
C.214
C.161
0.1ZO
C.089
C.070
0.056
C.044
C.040
C. 031
0.026
C.023
0.024
0.020
C.017
0.017
C.015
0.013
C.013
0.013
0.013
0.013
C.012
N02-CORR
PPM
******
******
0.102
0.126
0.171
0.213
0.250
0.270
C.279
0.^79
0.267
0.252
0.243
0.216
0.195
0.172
0.151
0.129
o.ica
0.086
0.071
O.C54
0.052
0.044
O.C43
0.039
0.038
NOX-CORR
PPM
******
******
0.453
0.448
0.43'6
0.427
0.411
0.390
0.36d
0.349
0.322
0.297
0.283
0.246
0.220
0.195
0.175
0.249
0.125
0.103
0.086
0.066
0.065
0.058
0.056
0.053
0.050
TOLUENE
PPP
0.000
0.560
0.555
******
0.526
******
0.490
******
0.460
******
0.420
******
0.4C9
******
0.389
******
0.356
******
0.313
******
0.291
******
******
******
0.258
******
0.246
PROPENE
PPM
0.0002
0.0966
0.0985
******
0.0800
******
0.0555
******
0.0415
******
0.0310
******
0.0221
******
0.0150
******
0.0105
******
0.0062
******
0.0035
******
0.0021
******
0.0014
******
0.0010
-------
EC -329
TO..UENE + PROPENE
1976 NuV 6
CLOCK
TIMc
616
923
945
1000
1015
lu Ji/
1043
IluC
1115
1130
1149
120u
1215
1230
1245
1300
1315
liiO
1345
I4u0
1415
1430
1443
1500
Iai5
1530
1545
ELAPSfcO
TIM1N)
-87.
-17.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
i ju.
345.
3oO.
PAN
PPM
******
******
O.OCO
******
0.001
******
0.004
******
0.010
******
0.016
******
0.026
******
0.033
******
0.042
******
0.051
******
JO. 061
******
0.067
******
0.064
******
0.064
hCHO
PPM
******
******
C.OC7
*******
******
******
C.043
******
******
******
0.072
******
******
******
O.OSd
******
******
******
0.066
******
******
******
0.006
******
******
******
C.067
ACETALO
PPM
0.0014
0.0017
0.0020
******
0.0151
******
O.C279
******
0.0j7i
******
O.OJ67
******
0.0420
******
0.0407
******
0.0404
******
0.0300
******
0.0306
******
******
******
0.0265
******
0.0254
PFOPALO
PPM
0.0002
0.0001
C.0002
******
0.0002
******
0.0002
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O.COOJ
******
0.0003
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******
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0.0015
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0.0021
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0.0022
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0.0031
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0.0036
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PPM
0.0005
O.OOC9
0.0009
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0.0014
******
0.0021
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0.0036
******
0.0048
******
0.0059
******
0.0087
******
0.0116
******
0.0093
******
0.0114
******
******
******
0.0132
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0.0156
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PPM
0.0001
0.0001
0.0001
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0.0001
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0.0002
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0.0003
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******
******
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******
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MEK
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0.0001
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0.0001
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0.0001
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0.0001
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******
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0.0
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0.0
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0.0
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0.0004
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0.0005
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0.0006
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u.0005
******
0.0006
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O.OGuo
******
0.00o7
******
O.J007
******
0.0005
******
0.0007
METHANE
PPM
l.tO
******
1.21
******
******
******
******
******
******
******
******
******
******
******
1.20
******
******
******
******
******
******
******
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******
******
******
1.20
tThANE
PPM
O.0062
*¥****
0.0059
******
******
******
******
******
******
******
******
******
******
******
0.0062
******
******
******
******
******
******
******
******
******
******
******
0.0059
ETHiNc
PPM
0.0029
******
0.0026
******
******
******
******
******
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******
******
******
******
******
0.0021
******
******
******
******
******
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******
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******
******
0.0014
ACETVLEI4
PPM
(PMJ
O.Ow/31
******
O.OC27
******
******
******
******
******
******
******
******
******
******
******
u.0032
******
******
******
******
******
******
******
******
******
******
******
O.C041
ACETYlEN
PPM
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0.00*5
******
******
******
**** * *
******
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******
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******
******
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******
**««**
******
******
******
-------
EC -329
TOLUENE + PROPENE
1978 NOV 6
VO
OJ
CLOCK
TIME
816
926
545
1000
1015
1030
1045
1130
1115
1130
1145
UOO
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
KMINJ
-67.
-17.
0.
IS.
30.
45.
60.
75.
90.
105.
uo.
135.
150.
165.
lt>0.
195.
210.
225.
240.
255.
270.
2U5.
300.
315.
330.
345.
360.
PROPANE
PPM
C.001C
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
1-C4
PPM
0.0001
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
-------
eC -329
TOLUENE + PkOPENE
1978 NCV 6
CLCCi-.
TIME
61o
9*6
Vf 3
lOOu
10i5
1050
1045
HOu
1115
1130
H4i
1200
1213
lijj
U45
1300
ii!5
1330
1345
1400
1415
ItJO
1445
isoo
1515
1530
1545
fcLAPiiC
TtMIN)
-67.
-17.
0.
15.
30.
45.
60.
75.
90.
105.
i.20.
135.
150.
165.
160.
1S5.
i 10.
225.
240.
255.
470.
265.
300.
315.
330.
345.
360.
TS
OEG F
******
******
05.5
66.2
66. 0
85.7
84.5
65.0
65.5
66.0
£6.2
£6.5
87.0
87.0
87.0
87.0
87.0
67.0
66.7
86.5
87.0
87.0
87.0
8o.7
86.7
87.0
67.0
REL HUM
*
******
******
56.5
61.0
63.5
65.5
67.0
67.5
68.0
68.5
68.5
68.5
68. 5
08. 0
68.0
68.0
o3.0
68.0
68.0
68.0
68.0
68.0
68.0
68.0
66.0
66.0
68.0
SSPOhch
KW
******
******
14.65
******
******
******
15.38
******
******
******
15.58
******
******
******
15.46
******
******
******
15.37
******
******
******
15.77
******
******
******
15.60
RAC10M
Mrt/CM2
******
******
0.141
0.188
0.193
0.186
0.190
******
******
******
0.198
******
******
******
0.193
0.193
0.190
******
0.193
0.168
0.188
******
0.198
******
******
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0.190
HCHO VOL
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******
******
20. CO
******
******
******
20. CO
******
******
******
20.00
******
******
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20. CO
******
******
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20. CO
******
******
******
20.00
******
******
******
20.00
-------
Ln
EC -330
TOLUENE + PRDPENE
197a NOV 7
6EGIU IRRADIATION 0945; 0.25 INCH PVREX FILTER! TRICHROIC FILTER OUT
*-ESi THAN 0.5 PP6 METHYL NITRATE AT T=6
10-LITER TENAA GC SAMPLES TAKEN FOR RESEARCH AND DEVELOPMENT
AT APPRO* 11UO AND 1200 (2 SAMPLES TCTAL)
oRADY 1193X,DASIBI 1212 (560 ML/MIN), TECC 14o-l (580 ML/MINJ USEO
T=0 AT 945 PST
CALI8*
PAN
hCnO
REL INT
TS
REL HUM
SSPOrtER
RADiOM
HiO
NO
N02-C0RR
TCLuENE
PRCPENE
MCHO
ACfcTALD
ETHANE
ETHEN£
ACETYLEN
DEC K
X
KM
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
INIT CCND
INIT CCND
INIT CCND
INIT CCND
INIT CCND
INIT CCND
INIT CCND
IMT CCNO
302.9
42.S8
15.39
C.193
2.424E
0.202
O.CSO
C.567
C.CS4
O.C09
0.002
0.005
0.002
0.002
ASSIGNcD INITIAL CONDITION
SPECTRAL OISTRIbUTICN: kAVELENGTH(NK)
500.
430.
403.
380.
37C.
360.
350.
340.
330.
320.
310.
300.
290.
Kl=0.40 MIN-1
SAMPLING RATc « 1.591 t/MIN
46 bC SAMPLES TAKEN
REL. INTENSITY
2.154
1.849
1.731
1.488
1.343
1.146
l.COO
0.780
0.537
0.289
O.C91
0.003
0.0
-------
EC -330
TOLUENE * PROPENE
1978 NOV 7
CLOCK.
TIME
b35
930
945
1000
1015
1030
1045
1100
ills
1130
1145
1200
1215
U30
U45
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
cLAPSEO
T(MIN)
-70.
-15.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
3oO.
OZONE
PPM
******
O.JOO
0.000
0.005
0.020
0.046
0.0&3
0.122
0.166
0.205
0.244
0.261
0.320
0.337
0.344
0.342
0.335
0.330
0.322
0.315
0.3C8
0.303
0.298
0.293
0.2B6
0.2b3
0.274
NO
PPM
******
0.199
C.20Z
C.160
C.103
0.065
C.044
C.OJ5
0.024
0.020
C.018
0.016
C.013
C.012
0.012
C.013
0.012
0.012
C.011
0.012
C.012
0.012
0.016
0.012
0.012
C.012
0.012
N02-CORR
PPM
******
0.091
0.090
0.123
0.169
0.190
0.193
0.175
0.153
0.132
0.105
0.0£5
0.064
0.049
0.041
0.033
0.032
0.035
0.036
0.0.37
0.036
0.036
0.029
0.032
0.033
0.034
0.034
NOA-CORft
PPM
******
0.291
0.290
0.283
0.269
0.254
0.233
0.207
0.175
0.149
0.122
0.097
0.075
0.060
0.051
0.046
0.042
0.043
0.044
0.046
0.046
0.046
0.042
0.042
0.043
0.044
0.044
TOLUENE
PPM
0.000
0.566
0.567
******
0.526
******
0.485
******
0.447
******
0.415
******
0.374
******
0.349
******
0.333
******
0.317
******
0.304
*******
0.291
******
0.272
******
0.260
PROPENE
PPM
0.0002
0.0955
0.0942
******
0.0736
******
0.04o4
******
0.0314
******
0.0201
******
0.0118
******
0.0073
******
0.0050
******
0.0035
******
0.0025
******
0.0019
******
0.0014
******
0.0010
-------
EC -330
TQLUcNE * PRCPENE
1973 NOV 7
CLOCK
11 Me
835
S30
V45
itijo
UU5
lioU
1045
1100
UiS
1130
iit5
1200
U15
lijO
Ut;>
1300
1315
133u
1345
1400
1*15
14-sO
1443
1500
1515
153G
1545
ELAPScD
TCM1N)
-70.
-15.
0.
15.
3U.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
155.
-------
EC -330
TOLUENE + PROPENe
1978 NOV 7
00
CLOCK
TIMi
«>35
930
S45
iuuO
1015
luid
1045
1100
1115
1130
1145
1200
1215
1130
1245
1300
1315
1330
1343
1400
1415
1430
1445
150J
1515
1S30
1545
ELAPSEC
T
-------
EC -331
TOLUENE * N-BUTANE
1978 NOV 8
6EGIN IRRADIATION 0915; 0.25 INCH PVREX FILTER; TRICHROIC FILTER OUT
TENAX GC SAMPLES CQLLECTECi BUT NO RELIABLE DATA OBTAINED
C-oOO OXYGENATE DATA FOR 1145t1245.1345C1445 REJECTED DUE TO
ABNORMAL PEAK SHAPES
BRADY 1193X, OASIBI 1211 (560 ML/MINI. TECO 146-1 (580 ML/MIN)
1=0 AT 515 PST
CALIB*
PAN
HCHO
REL INT
TS
REL hoM
SSPOHER
• RADIOK
H2G
NJ
N02-CQRR
TOLUENE
N-C4
HCHO
METHANE
ETHANE
ETHENE
ACETYLEN
OEG K
%
Kh
MW/CM2
PPK
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
IN1T CCND
IMT CCNO
INIT CCNO
IMT CCND
INIT CCND
INIT CCNO
INIT CCNO
INIT CONC
3C3.1
65.36
15.55
C.191
0.35«i
C.112
1.551
2.043
C.006
1.158
0.005
0.002
O.OC2
ASSIGNED INITIAL CCNDiTION
SPECTRAL DISTRIBUTION:
kAVELENGTH(NM)
500.
430.
403.
380.
370.
360.
350.
340.
330.
320.
310.
300.
REL.
Kl*0.40 MIN-1
SAMPLING RATE = 1.615 L/MIN
si GC SAMPLES TAKEN
INTENSITY
2.138
1.672
1.681
1.468
1.333
1.141
1.000
0.794
0.533
0.265
0.094
0.0
-------
EC -331
TOLUENE + N-BUTANE
1978 NOV B
Ul
o
o
CLUCK
TIME
615
905
915
930
945
1COO
1015
1030
1045
11JO
1115
11JO
1145
UuG
12i5
1230
1245
1300
1315
133J
13 -»5
14CJU
1415
1430
1445
1500
1515
ELAPSED
TiMINJ
-60.
-10.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
£10.
225.
2fO.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
******
0.0
0.000
0.000
0.022
0.095
0.203
0.313
0.41S
0.496
0.523
0.51B
0.511
0.496
0.461
0.4o7
0.449
0.437
0.427
0.413
0.406
0.393
0.3B4
0.374
0.364
0.359
0.352
NO
PPM
******
0.351
0.354
0.261
0.156
0.054
0.029
C.020
0.015
C.012
0.012
0.012
C.011
0.012
C.015
C.011
0.013
0.011
0.011
0.012
0.012
C.012
C.011
C.012
0.012
0.012
0.012
N02-C3RR
PPM
******
0.112
0.112
0.174
0.276
0.334
O.k99
0.234
U.lco
0.112
C.C77
0.065
C.C57
0.058
0.053
0.053
0.051
0.052
0.054
0.055
0.055
0.054
0.053
O.C52
0.052
0.050
C.C50
NOX-CORR
PPM
******
0.464
0.465
0.453
0.432
0.366
0.325
0.250
0.17d
0.121
O.OBB
0.074
0.067
0.067
C.065
0.063
O.Cc2
0.060
0.064
0.065
0.065
0.063
0.062
O.OoO
0.061
0.060
0.060
TOLUENE
PPM
O.OCO
1.966
1.991
******
1.880
******
1.752
******
1.621
******
1.527
******
1.507
******
1.463
******
1.459
******
1.425
******
1.396
******
1.359
******
1.354
******
1.296
N-C4
PPM
******
2.019
2.043
******
1.970
******
1.902
******
1.853
******
1.795
******
1.756
******
1.737
******
1.7C7
******
1.693
******
1.664
******
1.642
******
1.622
******
1.613
-------
tC -351
TOLUENE + N-BUTANE
1976 NOV 6
CLOCK
TIME
615
905
915
930
945
l&OJ
1015
10jJ
1045
1100
Ilia
iliO
1145
1200
1215
±250
1245
1300
Ui 1315
2 1S30
1345
1400
1415
1430
1445
1500
1515
ELAPSED
TtMlNI
-60.
-10.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
PAN
PPM
******
******
c.ooc
******
0.004
******
0.023
******
0.051
******
0.069
******
0.076
******
0.074
******
0.074
******
0.071
******
0.067
******
0.067
******
0.065
******
0.062
fcCHO
PPM
******
******
C.OC6
******
******
******
0.035
******
******
******
C.048
******
******
******
0.008
******
******
******
0.084
******
******
******
0.1C9
******
******
******
C. Ill
ACETALO
PPM
0.0011
**v***
******
******
O.C199
******
0.0436
******
O.C625
******
O.C78C
******
******
******
0.0757
******
******
******
0.0675
******
******
******
0.0925
******
******
******
0.0668
PRCPALC
PPM
0.0001
******
******
******
0. CCC3
******
O.C016
******
0.0031
******
0.0045
******
******
******
0.0024
******
******
******
0.0039
******
******
******
0.0033
******
******
******
0.0036
ACETONE
PPM
0.0004
0.0005
0.0002
******
0.0022
******
0.0095
******
0.0156
******
0.0204
******
******
******
0.0171
******
******
******
0.0176
******
******
******
0.0182
******
******
******
0.0154
BUTYRAL
PPM
0.0001
******
******
******
0.0005
******
0.0022
******
0.0035
******
0.0041
******
******
******
0.0045
******
******
******
0.0054
******
******
******
0.0048
******
******
******
******
MEK
PPM
0.0000
******
0.0000
******
0.0158
******
0.0370
******
0.0537
****** •
0.0672
******
******
******
0.0788
******
******
******
0.0905
******
******
******
0.0965
******
******
******
0.0927
C2-N
PPM
******
******
0.0
******
0.0
******
0.0001
******
0.0002
******
0.0002
******
******
******
0.0002
******
0.0002
******
0.0003
******
O.OG02
******
0.0003
******
0.0003
******
0.0003
C4-N-2
PPM
PAHALYiR
******
******
0.0
******
0.0020
******
C.0041
******
0.0052
******
0.0052
******
G.UU4o
******
u.0070
******
0.0063
******
0.0052
******
0.0046
******
0.0064
******
0.0046
******
0.0052
METHANc
PPM
1.16
******
1.16
******
******
******
******
******
******
******
******
******
******
******
1.14
******
******
******
******
******
******
******
******
******
******
******
1.15
6TH«NE
PPM
0.0u54
******
O.cu55
******
******
******
******
******
******
******
******
******
******
******
0.0055
******
******
******
******
******
******
******
******
******
******
******
0.0u55
6 THEME
PPH
O.CC21
******
0.0020
******
******
******
******
******
******
******
******
******
******
******
O.GC2C
******
******
******
******
******
******
******
******
******
******
******
0.0023
ACETYIEN
PPM
(PN)
0. JJ17
******
0.0017
******
******
******
******
******
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******
******
******
******
******
0.0033
******
******
******
******
******
******
******
******
******
******
******
0.005t
-------
EC --i3l
TOLUENE * N-BUTANE
1978 NOV 8
Ui
O
CLUCK
TIME
«15
905
915
930
94b
1000
1015
1030
1049
1100
1115
1130
11-0
1200
1215
12JO
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
ELAPSE C
T(H1N)
-60.
-10.
0.
15.
30.
45.
60.
75.
90.
105.
1^0.
135.
150.
165.
130.
195.
210.
225.
240.
255.
27C.
285.
300.
315.
330.
345.
360.
BENZENE
PPM
0.0001
O.C012
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
-------
EC -331
TOLUENE + N-BUTANE
1978 NGV 8
CLOCK
TIME
815
505
915
930
S45
1000
1015
1030
1045
1100
1115
1130
1145
12JO
1215
12JO
1245
1300
1315
1330
1345
Itoo
1415
14oO
1443
1500
1515
ELAPSEC
T
-------
EC -334
TOLUENE + PROPENE
1976 NOV 13
Ui
o
.p-
IRRADIATION lOISi 0.25 INCH PVR6X FILTiRi TRICHRQIC FILTER OUT
SP 1000 IS 6' 0.1* SP 10CO/CARBOPAK C
j' C-oOJ IS 3' 1CX C-eCC/C-22 COLUMN
10' C-60J IS 1C' 10* C-60C/C-22 COLUMN
faENiALCtHYDc VALUES FOR SP/1COO UNCERTAIN DUE TO UNSYMMEThlCAL PEAK SHAPE
UEIUALDEHVOc VALUES FOR 3' C-600 MORE UNCERTAIN CUE TO INTERFERENCE nilTH
UNKNOWN bACKGrtCUND PEAK.
TOLUENE VALUES FROM 10' C-600 MORE RELIABLE THAN FROM 3' C-600
BECAUSE CALIBRATION IS BETTER CHARACTERIZED
TIME INDICATED FOR TENAA SAMPLc IS START OF IS MINUTE COLLECTION
&RADV U93X, DASI8I 12U 1565 ML/MIM, TECO 14B-1 (540 ML/MINJ USED
T=0 AT 1015 PST
CALIB*
PAN
HChO
REL INT
TS
REL HUM
SSPO-ER
AAOiOM
H2C
NO
N02-CORR
TCLUENfc
PROPcNE
hCHO
ACETALO
METHANE
ETHANE
ETHENE
ACETYLEN
OfcG K
$
KW
MK/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PP«
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
INIT CCNO
INIT CCND
INIT CCND
IMT CCND
INIT CCNO
INIT CCNO
INIT CCNO
INIT CCNO
INIT CCNO
303.5
65.65
15.31
C.182
2.775E
C.348
C.100
C.993
C.095
0.015
0.001
1.669
0.004
C.002
O.CC2
ASSIGNED INITIAL CONDITION
-------
EC -334
TOLUENE * PROPENE
197U NQV 13
SPECTRAL DISTRIBUTION: fcAVE«.ENGTH(NH REL. INTENSITY
500. 2.57-s
430. £.027
403. 1.792
380. 1.549
370. 1.360
3t>0. 1.164
350. 1.000
340. 0.7B4
330. 0.517
320. 0.272
310. 0.086
300. 0.0
K 1=0.39 MIN-i
SAMPLING RATE * 1.557 L/MIN
50 GC SAMPLES TAKEN
Ui
o
-------
tC -334
TOLUENE * PRQPENE
197to NOV 13
Ln
O-
CLCCK
TIME
625
940
S45
1015
1C30
1045
Uuu
1115
11.JO
1145
1200
1215
i^O
12JO
U45
1300
1315
1325
ijiu
13-.5
14UO
1415
14 30
1*37
1445
1500
1515
1530
1545
155i
1600
1615
ELAPSED
TIMIN)
-110.
-35.
-30.
0.
15.
30.
45.
oO.
75.
90.
105.
120.
125.
135.
150.
165.
160.
190.
195.
210.
225.
240.
255.
262.
270.
265.
300.
315.
330.
340.
345.
460.
OiONE
PPM
******
******
0.000
O.JOO
O.i/OO
O.uOT
0.022
O.Ool
0.112
0.161
0.210
0. i64
o.<:8i
0.316
0.364
0.398
C.4C8
O.t Co
0.401
0.391
0.381
0.374
0.364
******
0.357
0.349
0.342
0.335
0.330
C.325
0.322
0.315
NO
fPM
******
******
C.348
C.J48
C.265
0.208
C.129
0.073
O.U46
0.034
C.026
0.020
C.020
0.018
C.015
0.015
0.013
C.013
0.011
0.013
0.012
0.012
C.012
******
C.C11
c.on
0.011
0.012
C.012
C.011
0.012
0.011
NU2-CORR
PPM
******
******
0.101
C.1CC
0.152
0.211
0.260
0.^89
0.261
0.^54
O.clb
0.175
0.166
0.138
0.100
0.061
0.065
0.059
0.059
0.052
C.05C
0.050
0.04S
******
0.044
0.044
0.039
0.039
0.037
0.037
0.037
0.035
NOX-CORR
PPM
******
******
0.448
0.448
0.436
0.416
0.387
0.3ol
0.325
0.286
0.241
0.195
0.184
O.i55
0.115
0.0*4
0.076
0.07C
0.070
0.0o4
0.061
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0.058
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u. 054
0.053
0.049
0.050
0.048
0.046
0.047
0.045
TOLUENE
PPM
10'C-600
0.000
******
0.997
0.993
******
U.916
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O.b54
*¥V?**
0.7£0
******
0.7J1
******
******
0.671
******
0.620
******
******
0.5S9
******
0.576
******
******
******
******
******
******
0.551
******
******
******
TOLUENE
PPM
3< C-600
******
******
******
l.UO
******
1.040
******
O.S95
**¥¥**
0.918
******
0.918
******
******
0.820
******
******
******
******
0.671
******
0.669
******
******
0.652
******
0.628
******
******
******
******
0.6UU
PROPfcNE
PPM
0.0002
******
0.0949
0.0954
******
0.0725
******
0.0492
******
O.U343 '
******
0.0221
******
******
0.01Z9
******
0.0121
******
******
0.0055
******
0.0040
******
******
0.0029
******
0.0022
******
0.0018
******
******
0.0012
-------
cC -33*
TOLUENE » PKOPENE
1976 NOV 13
Lu'-K
TIME
8-,V¥«
O.C-.39
##****
0.037i
******
******
0.0365
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0.0354
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******
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0.0354
******
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0.0001
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O.OOC1
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0.0013
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O.C039
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0.0034
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0.0303
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O.OJOB
0.0005
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0.0013
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0.0041
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0.0134
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0.0163
0.0183
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******
0.0118
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0.01C9
******
******
******
******
******
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0.0173
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******
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O.U001
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******
******
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0.0
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0.0
******
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0.0003°
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0.0005
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******
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0.0u06
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0.0003
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0.0005
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0.0006
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0.0004
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0.0006
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0.0
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0.0
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0.0045
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0.0204
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0.0266
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0.0375
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0.0502
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0.0277
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0.0277
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0.0424
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0.0418
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0.0
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0.0149
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0.0180
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******
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0.0
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0.0172
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0.0034
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0.0636
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0.0u32
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0.0u34
******
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PPM
1.67
******
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1.67
******
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******
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1 .67
******
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PPM
0. OufO
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0.004 j
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******
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0.0044
-------
cC -334
TulUENe + PROPEN6
1976 NOV 13
Ci-LlCK
TlCic
Oca
S4U
943
Iui5
lUiU
lut;»
liJj
llli
1130
1145
1200
1215
U20
123d
1*45
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1315
1323
Ui 1330
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14HJ
1413
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1437
1445
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15i5
1530
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1555
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1615
EuAPSEC
TJM1NJ
-ilO.
-35.
-30.
0.
15.
30.
45.
60.
75.
90.
Iu5.
120.
125.
135.
150.
165.
160.
190.
195.
210.
225.
240.
255.
£62.
270.
2B5.
300.
315.
330.
340.
345.
360.
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PPM
O.OC19
******
******
0.0020
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0.0015
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******
******
******
******
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0.0014
ACETVLEN
PPM
(PNt
O.OC27
******
******
0.0025
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******
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0.0035
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0.0055
ACETYltN
PPM
(QMS*
O.C125
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PPM
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PPM
0.0001
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O.OC07
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-------
tC -334
TOLUENE * PROPENE
197U NOV 13
Ui
o
CLOCK.
TIME
625
940
9<»5
1015
1030
1045
1100
ma
11JO
1145
12^0
1215
1220
1230
1245
13oi)
1315
Ii25
1330
1345
1400
1415
1430
1437
1445
i500
1515
1530
1545
1555
1600
1615
ELAPSED
T(MINI
-110.
-35.
-30.
0.
15.
30.
45.
60.
75.
90.
105.
120.
125.
135.
15C.
165.
180.
ISO.
195.
210.
225.
240.
,255.
262.
270.
235.
300.
315.
330.
340.
345.
360.
TS
CEG F
******
******
85.5
66.2
85.7
85.2
85.5
85.5
85.7
85.5
86.0
8.0. C
86.5
66.5
80.7
86.7
86.5
87.0
87.0
86.7
87.2
67.0
87.2
******
87.2
87.2
87.2
87.4
87.7
87.9
87.9
87.9
PEL HUH
%
******
******
57.5
57.5
60.0
63.0
64.5
65.5
66.0
66.5
67.0
67. C
67.0
67.0
67.0
67.0
66.5
66.5
66.5
06.5
66.5
66.5
66.5
******
66.0
66.0
66.0
66.0
66.0
66.0
66.0
66.0
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Kh
******
******
******
IE. 16
15.16
******
******
15.15
******
******
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15.23
******
******
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15.27
******
******
******
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15.27
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15.54
******
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15.67
RACIOM
MW/CM2
******
******
******
O.lb3
0.188
******
******
0.166
******
******
******
0.183
******
******
******
******
0.183
0.181
0.178
0.171
0.170
0.178
******
******
******
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0.183
0.181
******
******
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0.183
HCHO VOL
L
******
******
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20. CO
******
******
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20. CO
******
******
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20. CO
******
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20. CO
******
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20. CO
TENX VO
L
******
******
******
10.00
******
******
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10.00
******
******
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10.00
******
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10.00
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10.00
******
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10.00
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-------
£C -33i
TOLUENd + ACcTALCEHYCE
1973 NGV 15
BEGIN IRKADlATlCN 1015; 0.25 INCH PYREX FILTER, TRiOHROIC FILTER OUT
SP 1000 IS fa1 0.11 SP 1000/CAR60PAK C
5' C-6UO iS p' 5* C-t>CC/C-^2 COLUMN
10' C-oOO IS 10' 10* C-6CC/C-22 COLUMN
oENiAi-OEHYDE VALUES FOR SP-1000 UNCERTAIN. 5' C-oOO DATA PREFERRED
ACEfALDEHYDE ADDED BY FLUSHING IN 0.2396 TOfcR IN A 5.467 LITER BULB.
CALCULATED INITIAL ACETALDEHYDE = .2965 PPM.
lu1 C-oOO ACETALCEhYOE VALUES MAY BE ?4 HIGH
1115: 0-CRESOL PEAK OFF SCALE. CONCENTRATION PROBABLY GREATER THAN IS PPB
TiMt INDICATED FOh TENA> SAMPLE IS START OF 15 MINUTE COLLECTION
BRADY 1193Xt DASIBI 1212 (565 ML/MINI. TECO 14B-1 (540 ML/MIN) USED
T=0 AT 1015 PST
PAN
HCHO
REL INT
CALIB0
9
3
TS
REL HUM
SSPurfER
RADiOM
H20
NO
N02-CCRR
TOLUcNE
ACETALD
HCHO
6ZALQ
METHANE
ETHANE
ETHcNt
ACtTYLcN
PRQPAi'it
DEC K
t
KM
MW/CM2
PPM
PPM
PPM
PPrt
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCI\D
IMT CCNO
INIT CCNO
IMT CCND
INIT CCNO
INIT CCND
INIT CCNO
INIT CCNC
INIT CCND
INIT COND
303.0
60. Co
15.04
C.177
04
0.352
C.C92
L.VSd
O.-it
O.C10
0.002
1.231
0.004
0.002
O.OC2
0.001
ASSIGNED INITIAL CONDITION
-------
£C -335
TOLUENE + /CETALOEHVCE
1978 NOV 15
SPECTRAL DISTRIBUTION: WAVELENGTH! NM) REL. INTENSITY
5CQ. 2.530
430. 2.032
403. 1.796
380. l.SSU
370. 1.391
360. 1.170
350. 1.000
340. 0.787
330. 0.520
320. 0.276
310. O.C90
3CO. 0.0
Kl=0.39 MIN-l
SAMPLING RATE = 1.6C6 L/MIN
42 GC SAMPLES TAKEN
Ui
-------
TOLucNE * *CETALCEHYCt
IWo NCV 15
Ui
CLUCK
TIME
840
943
9aO
lOia
1030
lOnS
110J
Ilia
1130
1145
uoo
U15
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
15 Ou
15i5
1530
1545
1600
1615
t^APSEC
TIMIN)
-95.
-30.
-25.
0.
IS.
30.
43.
60.
75.
90.
105.
120.
US.
150.
165.
ItiO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
******
******
******
0.000
0.000
0.005
0.017
0.037
0.068
0.100
0.139
0.173
0.215
0.254
0.296
0.340
0.369
C.391
0.396
0.393
0.388
0.384
0.376
0.371
0.364
0.359
0.352
0.344
NO
PPM
******
******
******
C.352
C.2u9
C.214
C.148
0.098
C.07C
C.048
C.C37
0.029
0.024
0.021
0.018
0.016
0.015
C.C15
C.013
C.C13
0.013
0.012
C.012
0.012
C.012
0.013
0.012
C.012
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PPM
******
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O.C92
0.141
0.202
O.t4i
0.271
0.274
0.262
0.24«t
0.221
0.187
0.151
0.117
O.C89
0.064
0.043
U.035
0.027
0.026
0.026
0.026
0.029
0.031
0.031
0.028
0.017
NOX-CORR
PPM
******
******
******
0.443
0.429
0.415
0.391
0,363
0.342
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0.279
0.248
0.209
C.lo9
0.132
0.102
0.076
0.055
0.045
0.038
0.038
0.036
0.037
0.039
0.042
0.045
0.038
0.029
TOLUENE
PPM
lO'C-600
0.000
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0.993
0.998
******
0.942
******
O.b93
******
O.B36
******
0.798
******
0.739
******
0.684
******
0.631
******
O.ol9
******
0.601
******
0.582
******
0.557
******
0.544
TOLUENE
PPM
51 C-600
******
0.000
0.985
1.011
******
0.925
******
0.881
******
0.823
******
0.780
******
0.737
******
0.675
******
0.65J
******
0.618
******
0.602
******
0.588
******
0.564
******
0.558
ACETALO
PPM
0.001
******
0.323
0.326
******
0.227
******
0.247
******
0.199 •
******
0.184
******
0.150
******
0.124
******
0.090
******
0.095
******
0.092
******
0.091
******
0.077
******
0.074
-------
£C -335
TOLUENE * ACETALCEHVCE
1978 NOV 15
t-n
M
to
CLOCK
TIME
8*0
9f5
950
1015
1030
Iof5
1100
IliS
1130
1145
UOO
1215
12->0
lita
1300
1315
1330
13*5
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
T(MIN)
-95.
-30.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
PAN
PPK
******
******
******
0.000
******
0.006
******
0.024
******
0.042
******
0.053
******
0.079
******
0.096
******
0.111
******
0.115
******
u.lll
******
0.102
******
0.091
******
0.098
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PPM
******
******
******
C.010
******
******
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C.055
******
******
******
0.073
******
******
******
C.092
******
******
******
C.100
******
******
******
0.105
******
******
******
0.117
PSOPALO
PPM
******
******
******
******
******
******
******
******
******
******
******
O.COC8
******
0.0012
******
O.OOlti
******
0.0041
******
0.0018
******
0.0025
******
O.OC27
******
0.0024
******
0.002o
ACETONE
PPH
0.0002
******
******
******
******
******
******
0.0026
******
0.0054
******
0.0081
******
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******
0.0126
******
0.0107
******
0.0137
******
0.0190
******
0.0144
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0.0134
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0.0131
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PPM
******
******
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0.0006
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0.0010
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0.0012
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0.0012
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0.0011
******
0.0011
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0.0011
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0.0011
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0.0011
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0.0042
0.0016
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0.0060
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0.0059
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0.0090
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0.0120
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0.0125
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0.0112
******
0.0125
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0.0129
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0.0136
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0.0142
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0.0139
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PPM
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******
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0.0007
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0.0065
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0.0095
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0.0116
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PPM
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0.0
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******
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0.0022
******
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******
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PPM
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******
0.0
0.0
******
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******
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0.0017
******
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******
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0.0021
******
******
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0.0017
******
******
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******
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PPM
1.26
******
******
1.23
******
******
******
******
******
******
******
******
******
******
******
1.23
******
******
******
******
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******
******
******
******
******
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1.23
ETHANE
PPM
0.0041
******
******
0.0041
******
******
******
******
******
******
******
******
******
******
******
0.0037
******
******
******
******
******
******
******
******
******
******
******
0.0038
ETHtNE
FPM
0.0019
******
******
0.0020
******
******
******
******
******
******
******
******
******
******
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0.0615
******
******
******
******
******
******
******
******
******
******
******
0.0013
-------
EC -335
TOLUENE + ACETALCEHYCS
1976 NOV 15
Ui
CLOCK
Tirtc
640
945
950
1015
1^3u
10*5
lluO
U15
Hiu
1145
1200
1215
iiJU
U43
1-avO
1J15
lj JO
13t5
14UU
141?
ItJJ
l-«t5
1; Jj
i3i3
liJU
1543
lo vJO
Ifcl3
ELAPSEC
T(MIN)
-95.
-30.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
163.
180.
195.
tlO.
225.
2iO.
255.
270.
io5.
300.
315.
350.
343.
3oO.
ACETVLEN
PPM
(PN)
0.0023
******
******
U.0024
******
******
******
******
******
******
******
******
******
******
******
O.U027
******
******
******
******
******
******
******
******
******
******
******
C.0042
ACETYLEN
PPM
-------
EC -335
TCLUENE * 4CETALD6HYCE
197d NUV 15
Ln
CLOCK
TJMt
biO
9*5
950
1015
1030
1045
11 JO
1115
1130
11 15
1200
1215
i<;30
1245
1300
1315
1330
1343
1400
1415
1430
1445
isou
1515
1530
1545
IbOO
1615
ELAPSED
T(M1N)
-95.
-30.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
Io5.
160.
195.
210.
£25.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEC F
******
******
******
65. A
84.3
84.5
84.8
84.5
65.2
85.5
85.5
85.7
86.0
bo. 2
66.5
Bo. 5
6o.5
bO.7
07.0
07.0
86.7
86.5
85.5
85.7
85.5
85.5
85.2
85.5
«£U HUM
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******
******
******
47.0
49.5
53.5
56.5
38.5
59.5
60.5
61.0
61.0
61.0
61.0
61.0
6i.O
61.0
61.0
61.5
61.0
ol.O
ol.O
62.0
63.5
64.0
64.5
64.5
64.5
SSFOrtER
KW
******
******
******
15.01
******
******
******
15.01
******
***$**
******
15.03
******
******
******
14. 9C
******
******
******
14.93
******
******
******
15.27
*v***«
******
******
15.15
RAGIOrt HCHO VOL
MW/CM2
******
******
******
0.190
0.181
0.178
******
0.176
******
******
******
0.181
******
******
0.1 7d
0.173 .
0.171
0.173
0.176
0.170
0.176
0.176
0.168
0.173
0.178
0.176
0.176
0.176
L
******
******
******
20.00
******
******
******
20. CO
******
******
******
20. CO
******
******
******
20.00
******
******
******
*:o.oo
******
******
******
20. 00
******
******
******
cO.CO
TENX VO
L
******
10.00
10.00
******
******
******
******
10.00
******
******
******
10.00
******
******
******
10.00
******
******
******
10.00
******
******
******
10.00
******
******
******
******
-------
On
M
ON
EC -336
TOLUENE + F08MALCEHYCE
1978 NQV 16
BEG-IN IRRADIATION 1015; 0.25 INCH PVREX FILTERt TRICHR01C FILTER OUT
SP 1000 IS 6' 0.141 SP 1000/CARBOPAK C
5' C-600 IS 5' 5* C-6CO/C-22 COLUMN
10' L-£>00 IS 10' 10* C-4CC/C-22 COLUMN
oENtALucHYOE VALUES FOR SP-1GOO UNCEKTA1N. 5' C-tOO DATA PREFEKHEO
TIME. If.L-ICATEO FCR TENAX SAMPLE IS START OF 13 MinluTE COLLECTIuN
HChO AQDED BY FLUSHING IN 0.243 TORR IN A 5.4o7 LITER BULB.
CALC INIT HCHO » .30'3 PPMJ IN GOOD AGREEMENT W/ CHROMATROPIC ACID VALUE
bRAJV 1193X» DASIBI 1212 (565 ML/HIM, TECO 146-1 (540 ML/MINJ USED
T=0 AT 1015 PST
CALIBtf
PAN
hCriO
REL INT
TS
RCL HUM
SSP:,*ER
RAJIOM
H2Q
NJ
NC2-CCRR
TOLUENE
HCHO
ACcTALD
ACETCNS
aiALD
ETHANE
ETHENE
ACeTYLEN
PkOPANE
DEu K
*
KH
MW/CM2
PPM
PPM
PPM
PPM
PPrt
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGfc
AVERAGE
AVERAGE
AVERAGE
1NIT COND
IN1T CCND
INIT CCND
1NIT CQND
INIT CuND
INIT CCND
INIT COND
INIT cerso
INIT CCNO
IMT CCND
INIT CCNO
303.0
67.88
15.12
o.m
2.76
-------
EC -336
TOLUENE * FORMALCEHVCE
1978 NOV 16
SPECTRAL DISTRIBUTION: hAVELENGTHCNMJ REL. INTENSITY
SCO. 2.562
430. 1.974
403. 1.7*1
380. 1.562
370. 1.394
360. 1.164
350. 1.000
340. 0.783
330. C.Slo
320. C.281
310. 0.091
300. O.C
Kl=0.39 MIN-1
SAMPLING RATE - 1.650 L/MIN
f2 GC SAMPLES TAKEN
Ul
M
-J
-------
EC -336
TOLUENE + FCRC.ALCEHYCc
1978 NOV lt>
Ul
M
oo
CLUCK
TIME
900
9w5
950
1015
1030
1045
1100
1115
1130
1145
1200
1215
U30
12t5
1300
1315
1330
1345
1400
1415
1430
1445
1500
li.15
1530
1545
1600
1615
ELAPSEO
TIMING
-75.
-70.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZCNE
PPM
******
******
V*****
0.000
0.000
0.010
0.032
0.081
0.142
0.195
0.254
0.310
0.362
0.391
0.3S3
0.388
0.371
0.359
0.349
0.335
0.325
0.315
0.303
0.293
0.286
0.278
0.271
0.264
NO
PPM
******
******
******
C.342
I/. 269
C.181
C.106
C.060
0.040
0.029
0.024
C.022
0.021
0.018
0.017
0.015
0.017
C.015
C.018
C.C16
0.013
C.C17
0.017
0.016
0.015
0.017
C.018
0.016
N02-CORR
PPM
#**><**
******
******
O.C97
0.150
C.219
0.262
0.271
0.251
0.216
0.175
0.132
C.C90
O.C57
0.042
0.035
0.032
O.G2d
0.027
0.029
0.028
0.027
0.026
0.025
O.U19
0.027
O.U21
0.023
NOX-CORR
PHM
******
******
******
0.439
0.419
0.3S7
0.364
0.333
0.290
0.245
0.198
0.150
0.1C7
0.074
0.058
0.049
0.047
0.045
0.040
0.040
0.042
O.C42
0.039
0.038
0.033
0.042
0.036
0.034
TOLUENE
PPM
lO'C-600
0.000
******
1.021
1.008
******
0.874
******
0.810
******
0.738
******
0.673
******
0.592
******
0.574
******
0.549
******
0.535
******
0.514
******
0.490
******
0.474
******
0.452
TOLUENE
PPM
5' C-600
******
0.001
******
0.978
******
0.686
******
0.838
******
0.763
******
0.710
******
O.o34
******
0.599
******
0.568
******
0.547
******
0.526
******
0.510
******
0.498
******
0.481
HCHO
CPM
******
******
******
0.301
**«-.***
******
******
0.197
******
*******
******
0.165
******
******
******
J.145
******
******
******
u.li9
******
******
******
0.130
******
******
******
0.129
-------
EC -336
TOLUENE + FCSMALCEHYCc
1978 NOV Ib
CLGC*
TIMt
900
905
950
1015
1030
1045
1100
1115
1130
1145
1200
1215
123J
1245
1300
1315
1330
1345
1400
1415
1430
1445
150l>
1515
1530
1543
loOO
1615
ELAPSED
TCMIN)
-75.
-70.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
21C.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
PAN
PPM
******
******
******
0.090
******
0.002
******
0.012
******
0.026
******
0.039
******
0.054
******
0.059
******
0.059
******
0.057
******
0.053
******
0.053
******
0.050
******
0.048
ACETALD
PPM
0.0008
******
6.0023
0.0024
******
0.0065
******
0.0051
******
0.0065
******
0.00£7
******
C.OC84
******
C.0038
******
0.0039
******
G.0090
******
0.0097
******
0.0089
******
0.0098
******
C.0102
PHCPALC
PPM
0.0001
******
O.OC03
******
******
O.COC4
******
O.OC03
******
******
******
0.0017
******
******
******
******
******
******
******
******
******
0.0015
******
0.0008
******
******
******
0.0012
ACETONE
PPM
0.0002
******
O.OOC8
O.G008
******
0.0029
******
0.0048
******
0.0089
******
0.0108
******
0.0099
******
0.0107
******
0.0101
******
O.G073
******
0.0110
******
0.0071
******
0.0111
******
0.0118
BUTYRAL
PPM
******
******
0.0002
0.0001
******
O.OOC2
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
MEK
PPM
0.0001
******
0.0000
O.OOOJ
******
O.OOG1
******
0.0000
******
0.0001
******
0.0001
******
******
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
0.0001
ME-N
PPM
******
******
******
0.0
******
0.0
******
0.0
******
0.0003
******
O.OU03
******
0.0003
******
0.0001
******
0.0004
******
0.0005
******
0.0005
******
0.0004
******
0.0003
******
0.0005
oiALO
PPM
5' C-600
******
0.0016
******
0.0009
******
0.0049
******
0.0095
******
' U.0122
******
0.0139
******
0.0123
******
0.0135
******
0.0142
******
0.0158
******
0.0126
******
0.0153
******
0.0139
******
0.0155
bMLD
PPM
SP 1000
******
0.0010
******
******
******
******
******
0.0121
******
******
******
0.0173
******
******
******
0.0143
******
******
******
O.U124
******
******
******
O.Olbd
******
******
******
0.0189
0-CREiOL
PPM
SP 1000
******
0.0002
******
******
******
******
******
O.OltS
******
******
******
0.0031
******
******
******
0.0021
******
******
******
0.0025
******
******
******
0.0042
******
******
******
0.0057
MNT
PPM
SP luuw
******
0.0
******
******
******
***vv*
******
O.Oi/15
******
******
******
0.0017
******
******
******
O.OJ15
******
******
******
0.0012
******
******
******
0.0014
******
******
******
0.0010
METHANE
FPM
1.14
******
******
******
******
******
******
******
******
******
******
******
******
******
******
1.14
******
******
******
******
******
******
******
******
******
******
******
1.15
cTHANE
PPN
G.uiHG
******
******
0.0040
******
******
******
******
******
******
******
******
******
******
******
0. JC33
******
******
******
******
******
******
******
******
******
******
******
C.0036
-------
EC -33o
TOLUENE + FURMALCEHYCe
1978 NOV 16
CLOCK
TIME
900
9C5
950
1015
1030
1045
1100
1*15
1130
1145
UOO
1215
1230
Ut5
1300
1315
13JO
1345
Ui 1400
N3 1415
O 1430
1445
1500
1515
1530
1545
1600
1615
ELAPSEC
TIM1N)
-75.
-70.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
le>5.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
ETHENE
PPM
C.0019
******
******
O.C020
******
******
******
******
******
******
******
******
******
******
******
0.0012
******
******
******
******
******
******
******
******
******
******
******
0.0011
AC6TYLEN
PPM
(PNJ
0.0023
******
******
•0.0024
******
******
******
******
******
******
******
******
******
******
******
0.0033
******
******
******
******
******
**$«**
******
******
******
******
******
C.OC43
ACETYLEN
PPM
-------
EC -336
TOLUENE * FQRWALCEHYCe
1970 NOV 16
Oi
to
CLOCK
TIMc
900
9u5
950
1015
1030
1045
1100
1115
1130
1145
UJJ
1215
123u
1245
1300
1313
1330
1345
14UU
1415
1430
1445
1500
1515
15jO
1545
1600
1615
ELAPSED
T(M1N)
-75.
-70.
-25.
0.
15.
30.
43.
60.
75.
90.
105.
120.
135.
IsQ.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEG F
******
******
******
84.8
83.3
64.0
84.3
64.8
65.2
85.5
66.0
86.5
87.0
66.5
85.7
85.5
85.7
85.7
85.7
66.0
85.7
85.7
6o.O
66.0
66.2
86.0
86.0
66.5
RcL HUH
%
******
******
******
58.5
62.5
65.5
o7.Q
68.0
68. 0
66.0
66.0
68.0
68.0
63. C
66.0
6D.5
69.0
o9.0
69.0
69.0
69.0
69.0
69.0
69.0
69.0
69.0
69.0
69.0
SSPOWER
KM
******
******
******
15.17
******
******
******
15.05
******
******
******
15.04
******
******
******
14.9o
******
******
******
15.26
******
******
******
15.09
******
******
******
15.28
RADIOM
Mh/CM2
******
******
******
0.181
******
******
******
0.173
0.176
0.173
0.178
0.171
0.16o
0.171
O.l6d
0.164
******
0.17o
0.166
C.173
0.176
******
******
0.173
0.176
0.171
0.161
0.181
HCHQ VOL
L
******
******
******
20.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20. CO
******
******
******
20.00
TEN* VO
L
******
10.00
******
******
******
******
******
10.00
******
******
******
10. 00
******
******
******
13.00
******
******
******
10.00
******
******
******
11.70
******
******
******
10. JO
-------
EC -337
TOLUENE «• BENZALDEHYCE
197d NOV 17
BEGIN IRRADIATION 1045! 0.25 INCH PYRtX FILTER; TR1CHRQIC FILTER OUT
SP lOuO IS 6' O.I* SP 1000/CARBOPAK C
5' C-oOO IS 5' 5* C-6CC/C-22 COLUMN
1J« C-60J IS 10' 10* C-6GC/C-22 COLUMN
0*20: EXPAND 0.165 TORR BENZALCEHYDE IN 5.467 L BULb INTO EC
CALCULATED BcNZALCEHYDE INJECTED « C.206 FPM IN EC
BENZALOEHYOE VALUES FOR SP-IOOO UNCERTAIN. s< c-60o DATA PREFERRED
TIME INDICATED FOR TENAX 'SAMPLE IS START OF 15 MINUTE COLLECTION
6RADY 1193X, OASIBI 1212 (565ML/MIN), TEC0148-1 (540ML/MIN) USED
T=0 AT 1045 PST
un
CALIB*
PAN
HCMO
REL INT
TS
REL HUM
SSPOwER
ftAuiOM
H20
NO
N02-CORR
TCLUENi
BZALD
hCriO
ACETALO
ACETCNc
METHANE
ETHANE
tTMcNE
ACETYLEN
PROPANE
8ENZENE
OEG K
*
Kb
MH/CM2
PPM
PPM
PP«
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVfcftACE
AVERAGE
AVERAGE
INIT CCNO
inn CCNO
IMT CGND
INIT CCNO
INIT CCNO
INIT CCNO
IMT CCNC
IMT CCND
INIT CCNO
JNIT CCNO
IMT COND
INIT COND
IMT CCND
3C3.C
65.57
14.94
0.173
2.7C0E 04
0.322
0.124
C.959
0.172
C.C09
0.002
0.001
1.278
C.OC4
0.002
0.002
O.C01
O.C01
ASSIGNED INITIAL CONDITION
-------
EC -337
TOLUENE + BtN/ALCEHYDE
197S NOV 17
SPECTRAL DISTRIBUTION: hAVELENGTHiNfJ REL. INTENSITY
500. 2.469
430. 2.C24
4C3. 1.766
380. 1.559
37C. 1.395
360. 1.160
350. 1.000
340. 0.785
330. 0.533
320. 0.285
310. 0.090
300. 0.0
Kl=0.39 MIN-1
SAMPLING RATE = 1.634 C/M1N
tZ GC SAMPLES TAKEN
Ui
N3
to
-------
EC -337
TOLUENE » BENiALOEHVDE
1978 NCW 17
Ln
to
CLOCK
TIMe
945
1025
1045
UUO
1115
1130
1145
12JO
1215
1230
1245
1300
13i3
1330
1 its
14JO
1415
I43u
1-t-O
IsOO
i51j
15jo
15*5
1600
1615
1630
1645
ELAPSED
T4M1NJ
-60.
-20.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
i70.
265.
3UO.
315.
330.
345.
360.
CUGNE
PPH
******
******
0.0
O.JCO
0.000
0.002
0.005
0.010
0.017
0.032
0.054
0.07B
0.1C5
0.134
0.169
0. 2C8
0.244
0.278
0.313
0.525
0.320
C.310
0.300
0.291
0.283
0.278
0.269
NO
PPM
******
******
0.322
0.300
0.275
C. 231
0.194
0.162
C.126
C.092
0.071
0.054
C.043
C.033
O.OJ1
C.027
0.020
0.017
C.016
C.OlS
O.U15
0.015
0.017
0.017
0.015
0.017
C.016
N02-CORR
PPM
******
******
0.124
0.141
C.160
0.190
C.213
0.233
0.251
0.264
0.263
0.255
0.241
0.215
0.187
0.162
0.136
0.108
O.GB2
O.C66
0.057
0.052
0.047
0.046
0.046
O.C45
O.C42
NOX-CDRR
PPH
******
******
0.448
0.439
0.433
0.41ti
0.410
0.388
0.370
0.353
0.331
0.308
0.281
0.240
0.21o
O.ld4
0.1S6
0.125
0.093
0.070
0.070
0.065
0.063
0.061
0.058
0.058
0.062
TOLUENE
PPM
lO'C-600
0.000
0.932
0.959
******
0.903
******
0.877
******
O.U35
******
0.798
******
0.764
******
0.714
******
0.657
******
0.623
******
0.592
******
0.561
******
0.544
******
0.531
TOLUENE
PPM
5' C-600
******
******
0.932
******
0.947
******
0.916
******
0.872
******
0.817
******
******
******
0.720
******
0.687
******
0.638
******
0.630
******
0.595
******
0.583
******
0.562
bZALO
PPM
51 C-600
******
******
0.172
******
0.161
******
0.149
******
******
****** •
0.113
******
0.102
******
0.085
******
0.073
******
0.066
******
0.059
******
0.054
******
0.051
******
0.048
BZALO
PPM
SP 1000
******
******
******
******
0.143
******
******
******
0.118
******
******
******
0.072
******
******
******
0.071
******
******
******
******
******
******
******
0.041
******
******
-------
EC -337
TOLUENE + BENZALDEHVCE
1976 NOV 17
Ul
CLOCK
TIM£
945
1025
1045
1100
1115
1130
1145
uoo
1215
1230
1245
13 OU
1315
1330
1J45
1400
1415
1430
1445
1500
1515
1530
1545
loOu
1615
1630
1645
ELAPSEd
TIMIN)
-60.
-20.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
i95.
210.
225.
240.
255.
270.
2&5.
300.
315.
330.
345.
360.
PAN
PPM
******
******
C.OOO
******
0.001
******
0.002
******
O.C05
******
0.009
******
0.015
******
0.022
******
0.031
******
0.041
******
0.046
******
0.047
******
0.044
******
0.039
HCHO
PPM
******
******
0.009
******
******
******
0.018
******
******
******
0.027
******
******
******
0.041
******
******
******
0.048
******
******
******
0.061
******
******
******
0.065
ACETALO
PPM
0.0010
O.OU13
O.C015
******
0.0020
******
O.OC23
******
0.0030
******
O.GC34
******
O.C051
******
0.0054
******
O.GG64
******
O.CC71
******
0.0070
******
0.0073
******
O.C086
******
O.OC96
PROPALD
PPM
0.0001
0.0001
******
******
0.0001
******
0.0001
******
******
******
******
******
O.OOOd
******
o.ooca
******
0.0008
******
******
******
******
******
******
******
******
******
0.0017
ACETONE
PPM
0.0003
0.0005
0.0007
******
0.0014
******
0.0018
******
0.0036
******
0.0039
******
0.0105
******
G.01t>9
******
0.01 SI
******
0.0172
******
0.0112
******
0.0190
******
0.0148
******
0.0150
MEK
PPM
0.0001
******
0.0000
******
0.0000
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0001
ME-N
PPM
******
******
0.0
******
0.0
******
0.0
******
0.0
****** •
0.0003
******
0.0002
******
0.0003
******
0.0003
******
0.0004
******
0.0005
******
0.0004
******
0.0005
******
0.0006
0-CRESOL
PPM
SP 1000
******
******
******
******
0.0050
******
******
******
0.0111
******
******
******
0.0077
******
******
******
0.0028
******
******
******
******
******
******
******
0.0038
******
******
MNT
PPM
SP 1000
******
******
******
******
0.0003
******
******
******
0.0009
******
******
******
O.uulb
******
******
******
0.0017
******
******
******
******
******
******
******
0.0011
******
******
METHANE
HPM
1.29
******
1.28
******
******
******
******
******
******
******
******
******
******
******
1.27
******
******
******
******
******
******
******
******
******
******
******
1.26
ETHANE
PPM
0.0043
******
0.0042
******
******
******
******
******
******
******
******
******
******
******
0.0043
******
******
******
******
******
******
******
******
******
******
******
0.0042
EThENE
PPM
0.0019
******
O.UGl
-------
cC -337
TOLUENE * BENZALDEHYCE
1978 NOV 17
Ui
K5
CLOCK
TIME
945
1025
1045
liOO
1115
1130
1145
1200
1215
12jo
1245
1300
Ijii
1330
1345
140J
1415
1430
14*5
I5u0
1515
1530
1545
1600
1615
163U
1645
ELAPSED
T(MIN)
-60.
-20.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
loO.
195.
110.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
ACETYLEN
PPM
(PN)
0.0032
******
0.0024
******
******
******
******
******
******
******
******
******
******
******
0.0033
******
******
******
******
******
******
******
******
******
******
******
0.0046
ACETYLEN
PPM
(CMS)
0.0023
******
0.0023
******
******
******
******
******
******
******
******
******
******
******
0.0031
******
******
*******
******
******
******
******
******
******
******
******
0.0047
PROPANE
PPM
O.OCC9
******
O.CC09
******
******
******
******
******
******
******
******
******
******
******
O.OCC9
******
******
******
******
******
fc*****
******
******
******
******
******
O.OC09
PROPENE
PPM
0.0002
******
0.0002
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
O.C001
I-C4
PPI*
0. OOC1
******
O.OOC1
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
******
BENZENE
PPM
0.0002
0.0007
O.OOC7
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0014
-------
EC -337
TOLUENE * BENZALDEHYCE
1976 NOV 17
Ln
CLOCK
TIME
945
1025
1045
1100
Ili5
LI 3d
Ut5
1200
12lP
1230
1245
1300
1313
1330
1343
I40u
1415
1430
1445
1500
15i5
1530
1545
1600
Iol5
1630
1645
ELAPSED
T4.8
85.2
65.?
65.7
85.7
60.0
86.0
86.2
86.2
85.7
86.2
66.2
86.2
£6.2
86.5
b6.7
86.5
66.2
66.2
REL HUM
S
******
******
56.0
59.0
62. C
64.0
65.0
66.0
66.5
66.5
66.5
66.5
66.5
66.5
66.5
66.5
66. 0
66.5
66.5
66.5
66.5
67. C
66.5
67.0
66.5
66.5
66.5
SSPOfcER
Kn
******
******
15.ua
******
******
******
14.83
******
******
******
14.88
******
******
******
14.93
******
******
******
14.36
******
******
******
15.40
******
******
******
15.08
RADICW
HM/CM2
******
******
0.178
0.176
0.168
0.168
0.173
0.173
0.171
0.166
0.173
0.171
******
******
0.173
******
******
******
0.178
0.173
0.176
0.176
0.173
******
******
0.173
******
HCHO VOL
L
******
******
20. CO
******
******
******
20. CO
******
******
******
20. CO
******
******
******
20. CO
******
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
TENX VO
L
******
******
10.00
******
10.00
******
******
******
10.00
******
******
******
11.05
******
******
******
10.00
******
******
******
10.00
******
******
******
10.00
******
******
-------
Ui
NJ
00
EC -338
TOLUENE •» N-BUTANE
1478 NOV 20
bEGIN IRRADIATION 1015; O.i5 INCH PYREX FILTER; TKICHROIC FILTER OUT
SP 1000 IS 6' 0.IX SP 1000/CARQOPAK C
5' C-600 IS 5' 5* C-6CC/C-22 COLUMN
10' C-600 IS 10' 10* C-6CC/C-22 COLUMN
6ENZALDEHYGE VALUES FOR SP-1COO UNCERTAIN. i>> C-oOO DATA PREFERRED
TIME INDICATED FOR TENAX SAMPLE IS START OF 15 MINUTE COLLECTION
BRADY U95A; OASISI 1212 <56S ML/MINJ; TECO 14B-1 4540 ML/MIN) USED
&ECKMAN obOO CN MANUAL OPERATION (FLOW 120 ML/MIN); CO FACTOR: 1.6/8.9
T=u AT 1015 PST
CALIB*
PAH
HCHO
REL INT
TS
REL HUM
SSPOrtER
RADJOM
H20
NO
N02-CORR
TOLUENE
N-C4
HCHO
ACETONE
b^ALO
METHANE
ETHANE
ETH6NE
ACETYLEN
BENZENE
DtG K
*
KK
MH/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPrt
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCND
INIT CCND
INIT CCND
INIT CCN'D
INIT CCNO
INIT CCND
INIT CCND
INIT CCNO
INIT CCND
INIT CCND
INIT CCND
INIT CCNC
303.3
66.00
15.09
0.171
2.771E 04
0.346
C.100
C.955
2.026
c.cca
0.001
0.001
1.377
0.004
O.CC2
0.003
0.001
ASSIGNED INITIAL CONDITION
-------
EC -338
TOLUENE + N-BUTANE
1978 NOV 20
SPECTRAL DISTRIBUTION: hAVELENGTHINM) RcL. INTENSITY
500. 2.006
430. 1.766
403. 1.643
380. 1.469
370. 1.339
360. 1.141
350. l.COO
340. 0.791
330. 0.538
320. C.290
310. 0.101
300. 0.0
fU=0.39 MIN-1
SAMPLING RATE - 1.751 L/MIN
32 GC SAMPLES TAKEN
Ul
NJ
-------
cC -338
TOLUENE + N-BUTANE
1978 NQV ZO
Ul
CO
o
COCK
TIME
850
950
1015
1030
1045
1100
1115
1130
1145
1200
U15
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
16JO
1615
ELAPSED
T(MIN)
-65.
-25.
0.
15.
30.
45.
60.
75.
*0.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OiGNE
PPM
******
******
0.0
O.OC2
O.COS
0.020
0.051
0.100
0.147
0.191
0.247
0.288
0.340
0.375
0.418
0.449
0.474
0.4dl
0.484
0.479
0.467
0.459
0.449
0.437
0.430
0.420
0.410
NO
PPM
******
******
0.346
C.2d8
0.216
0.142
C.002
C.053
0.035
0.031
C.024
C.018
0.018
C.018
0.016
0.016
C.012
0.015
0.015
0.012
0.015
0.012
C.013
0.016
C.C13
0.011
C.013
N02-CQRR
PPM
******
******
C.10U
0.143
0.2C5
0.263
0.299
0.3C1
0.285
0.256
C.2*l
0.189
0.157
0.128
0.1C1
0.081
0.061
C.050
0.038
0.036
0.035
0.034
0.033
0.028
0.029
0.029
0.029
NOX-CORR
PPM
******
******
0.447
0.433
0.421
0.400
0.379
0.351
0.315
0.283
0.244
0.212
0.173
0.142
0.115
0.090
0.074
0.062
0.051
0.047
0.045
0.044
0.044
0.039
0.043
0.040
0.040
TOLUENE
PPM
10'C-600
0.000
0.943
0.955
******
0.906
******
0.832
******
0.801
******
0.757
******
0.736
******
0.683
******
0.670
******
0.652
******
0.620
******
0.617
******
0.591
******
0.590
TOLUENE
PPM
5' C-600
0.000
******
0.9U3
******
0.925
******
0.870
******
0.835
******
0.804
******
0.765
******
0.722
******
0.690
******
0.672
******
0.657
******
0.639
******
0.622
******
0.622
N-C4
PPM
******
2.023
2.026
******
1.958
******
1.902
******
1.848
******
1.804
******
1.749
******
1.710
******
1.6ol
******
1.642
******
1.615
******
1.591
******
1.564
******
1.540
-------
EC -338
TOLUtNE «• N-BUTANE
1978 NJV 20
Ui
CLOCK
TIME
850
950
1015
1030
1045
1100
1115
1130
1145
12uo
1215
123u
1245
130J
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
T(MIN)
-85.
-25.
0.
15.
30.
45.
oO.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
1.06
******
1.15
******
1.39
******
******
******
1.66
PAN
PPM
******
******
0.000
******
0.002
******
C.010
******
0.020
******
0.033
******
0.046
******
0.060
******
0.070
******
0.075
******
C.076
******
C.075
******
0.071
******
C.071
HCHO
PPM
******
******
0.008
******
******
******
0.025
******
******
******
0.042
******
******
******
0.055
******
******
******
0.06C
******
******
******
O.C73
******
******
******
0.091
ACETALO
PPM
0.0007
******
******
******
0.0158
******
0.0333
******
0.0499
******
0.0599
******
0.0767
******
0.0615
******
0.0785
******
0.0968
******
0.094i>
******
0.0922
******
0.0833
******
0.0930
PROPALD
PPM
0.0001
O.OJ01
0.0001
******
0.0001
******
0.0003
******
0.0004
******
O.OOC8
******
0.0018
******
O.ool7
******
0.0021
******
0.0028
******
0.0025
******
0.0023
******
0.0024
******
0.0024
ACETONE
PPM
0.0002
0.0004
O.OOOu
******
0.0017
******
0.0041
******
0.0099
******
0.0157
******
0.0185
******
0.0154
******
0.0098
******
O.Ol&a
******
0.0153
******
0.0113
******
0.0134
******
0.0147
BUTYRAL
PPM
******
0.0001
0.0000
******
0.0004
******
******
******
******
****** '
0.0018
******
0.0024
******
0.0022
******
0.0024
******
0.0030
******
******
******
******
******
******
******
0.0048
MEK
PPM
0.0001
0.0000
0.0000
******
0.0123
******
0.0201
******
0.0324
******
U.0545
******
0.0642
******
0.0u42
******
0.0529
******
0.0«17
******
0.0798
******
0.0760
******
0.0925
******
0.1096
C2-N
PPM
******
******
0.0
******
0.0
******
0.0
******
0.0002
******
0.0002
******
0.0002
******
******
******
0.0003
******
0.0003
******
0.0003
******
0.0003
******
0. 0003
******
0.0003
C4-N-2
PPh
******
******
0.0
******
0.0020
******
0.0049
******
0.0054
******
C«ooo3
******
0.010*
******
0.0116
******
0.0125
******
0.0132
******
O.OU2
******
0.01O9
******
0.0136
******
0.0126
62A4.D
F»-M
5' C-600
0.0u26
0.0013
0.0009
******
0.0057
******
O.Ot-57
******
U.0077
******
0.0093
******
0.0103
******
0.1)104
******
0.0103
******
0.0116
******
0.0119
******
0.0124
******
0.0107
******
0.0117
B<.ALt
PPM
SP 1000
******
0.0012
******
******
******
******
0.0093
******
******
******
******
******
******
******
0.01.P7
******
******
******
******
******
******
******
U.U124
******
******
******
0.014o
0-CRESoL
PP'1
SP 1000
******
0.0012
******
******
******
******
-------
EC -338
TOLUENE * N-BUTANE
1978 NOV 20
Ui
U>
NJ
CLOCK
TIME
850
950
10X5
1030
1045
1100
1115
1130
1145
1200
U15
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
ELAPSED
T(M1N)
-85.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
MNT
PPM
SP 1CCO
******
0,0
******
******
******
******
0.0011
******
******
******
******
******
******
******
C.C015
******
******
******
******
******
******
******
O.oOll
******
******
******
0.0011
METHANE
PPM
1.39
******
1.38
******
******
******
******
******
******
******
******
******
******
******
1.36
******
******
******
******
******
******
******
******
******
******
******
1.38
ETHANE
PPM
0.0043
******
0.0044
******
*ȴ***
******
******
******
******
* *** * *
******
******
******
******
O.OC45
******
******
******
******
******
******
******
******
******
******
******
O.OC45
EThENS
PPM
0.0021
******
0.0020
******
******
******
******
******
******
******
******
******
******
******
0.0019
******
******
******
******
******
******
******
******
******
******
******
0.0022
ACETYLEN
PPM
0.0032
******
0.0032
******
******
******
******
******
******
******
******
******
******
******
0.0041
******
******
******
******
******
******
******
******
******
******
******
0.0051
BENZfcNE
PPM
0.0001
0.0006
0.0007
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0006
******
0.0007
-------
EC -338
TOLUENE + N-SUTANE
1978 NOV 20
Ui
w
u>
CLOCK
TIME
850
950
1015
1030
1C45
1100
1115
1130
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
IfciS
ELAPSED
TIMIN)
-85.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
TS
DEG F
******
******
86.0
85.2
85.2
85.5
85.5
65.7
65.2
85.5
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66.2
86.2
66.5
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86.5
86.7
87.0
87.2
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86.7
86.7
66.5
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*
******
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56.0
59.0
62.5
64.0
65.5
66. C
66.5
67.0
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67.5
67.5
67.5
67.0
67.0
67.0
67.0
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67.0
67.0
66.5
66.5
67.0
67.5
67.5
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KM
******
******
15.18
******
15.17
******
15.17
******
******
******
15.01
******
******
******
14.96
******
******
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14.60
******
******
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15.24
******
******
******
15.17
RADIUM
HW/CH2
******
******
U.178
0.176
0.173
0.171
0.171
0.16d
0.171
0.171
0.168
******
******
******
0.171
0.168
0.166
******
0.166
0.171
0.171
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0.173
******
******
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0.176
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******
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******
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20. CO
******
******
******
20.00
******
******
******
20.00
******
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20.00
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******
******
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20. CO
TENX VOL
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11.70
10.00
******
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10.00
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10.00
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10.00
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10.00
******
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10.00
-------
EC -J39
TOLUENc + BENZALDEHYLE
1978 NOV 21
ISKAOIATICN 0945; c.is INCH PYREX FILTER; TRKHROIC FILTER OUT
oASELINi CN PA,* CHART NCI SV
Mc-N Pi\cj£NT AFTER T=5( BUT C3ES NOT cXCEEO 1 PPB
SP UOJ IS t>< O.U SP 1COO/CARBOPAK C
5' C-oOO IS 5' 5* C-6CO/C-22 COLUMN
10' C-tOO IS 10' 10* C-6CC/C-22 COLUMN
Oo50: 0.165 TCRR BENZALCEFYDc IN 5.467 L BULB FLUSHED INTO EO
CALCULATED BENZALCEhrOE INJECTED « 0.20o PPM IN EC
UENZALOEHYOE VALUES FOR SP-1000 UNCERTAIN. 5' C-600 DATA PREFERRED
TI^E INDICATED FDR TENAX SAMPLE IS START OF 15 MINUTE COLLECTION
dRADV 1193X! DASI6I 12U «565 ML/MIM ; TECO 14B-1 (540 ML/MIN) USED
otCKMAN 6600 CH MANUAL OPERATION (FLO* 120 ML/MINI i CO FACTOR: 1.6/B.35
T-0 AT 945 PST
PAN
HCHO
REL INT
CALI6*
9
3
Ln
CO
TS
REL HUM
SSPOwER
RADIOM
HiO
MO
N02-Cu^K
TOi-OctjE
dt-^J
HCriL
ACc'ALO
METhANt
ETHANE
ETHENE
tCETYLEN
PROPANE
DEG K
*
KH
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
1N1T CCNO
INIT CCND
IN1T CCND
INIT COND
INIT CCND
INIT CCNC
JNIT CCND
IMT CCND
ZN1T CCND
INIT CCND
INIT CCND
303.4
43.97
15.20
C.169
2.689E 04
0.341
0.102
0.536
0.167
C.CC2
0.001
1.369
O.C05
0.002
0.004
0.001
ASSIGNED INITIAL CONDITION
-------
cC -339
TOLUENE «• BENZALCEHYCE
1976 NOV 21
iPECTRAL DJSTRI6UTION: bAVetEMGThl UK) REL. INTENSITY
500. 2.579
4JO. 2.066
403. 1.815
380. 1.569
370. 1.362
360. 1.152
350. 1.000
340. 0.769
330. 0.523
320. 0.27&
310. 0.096
300. O.C
M=0.39 MIN-l
SAMPLING RATE * 1.676 L/HIN
42 GC SAMPLES TAKEN
Ul
UJ
Ul
-------
EC -339
TOLUENE + BENZALDEHYDE
1978 NOV 21
Ul
US
CLOCK
TIME
925
920
945
1000
1015
1030
1045
1100
1115
113U
1145
1200
1215
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
ELAPSED
TIMIN)
-20.
-17.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
******
******
0.0
o.oco
0.000
0.0
0.000
0.000
0.000
0.002
O.OC5
0.010
0.017
0.022
0.029
0.039
0.049
0.061
0.073
0.088
0.105
0.122
0.137
0.159
0.178
0.2CO
0.225
NO
PPM
******
******
0.341
•C.529
0.3C9
0.293
0.274
0.2**9
0.223
0.202
C.177
0.155
0.133
0.111
0.094
0.078
0.067
C.C55
0.044
0.040
0.034
0.033
0.026
0.022
C.C18
0.020
C.016
N02-CORR
PPM
******
******
0.102
0.112
0.122
0.134
0.153
0.164
0.176
0.189
0.2C5
0.216
0.222
0.231
0.234
0.235
0.231
0.227
C.22G
0.2C6
0.200
0.163
0.169
0.155
0.139
0.126
0.110
NOX-CORR
PPM
******
******
0.445
0.439
0.434
0.426
0.421
0.410
0.401
0.391
0.378
0.365
0.351
0.338
0.323
0.308
0.294
0.273
0.264
0.247
0.226
0.209
0.191
0.176
0.160
0.142
0.119
TOLUENE
PPM
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0.533
0.536
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0.519
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J.511
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0.460
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0.468
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0.450
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0.416
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0.401
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0.582
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0.356
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0.345
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0.322
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0.3C1
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PPM
5' C-6UO
0.571
******
0.57o
******
0.532
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0.517
******
0.479
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0.493
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0.469
******
0.444
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0.417
******
0.391
******
0.379
******
0.357
******
0.340
******
0.318
BZALD
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5' C-600
0.173
******
0..187
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0.173
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0.163
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0.147
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0.134
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0.1*5
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0.106
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0.091
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0.083
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0.074
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0.065 V
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0.056
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0.046
BZALD
PPM
SP 1000
0.141
******
******
******
******
******
0.155
******
******
******
0.115
******
******
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0.084
******
******
******
0.070
******
******
******
0.062
******
******
******
******
-------
£C -339
TOLUENE + BENZALCEHYDE
1976 NGV 21
CLOCK
TIKE
925
923
945
1000
1015
iOjO
1045
1100
1115
1130
1145
1200
1215
1 5 "3 i '»
JLc JU
1245
1300
1315
1^30
1345
1400
1415
1430
1445
15JO
1515
1530
1545
CLMPScO
TIMINJ
-20.
-17.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
\ f C
165.
180.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
CO
PPM
******
******
******
******
******
******
0.42
******
******
******
******
0.44
******
0.53
******
******
******
0.7u
******
******
******
0.68
******
******
******
C.80
PAN
PPM
******
******
0.000
******
0.000
******
0.001
******
0.001
******
0.001
******
0.003
0.005
******
0.007
******
0.009
******
0.012
******
0.015
******
0.019
******
C.024
HChQ
PPM
******
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0.002
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0.002
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0.013
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0.021
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0.025
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0.0010
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0.0022
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0.0025
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0.0035
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0.0038
0.0039
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O.OJ43
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0.0054
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0.0062
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0.0063
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0.0065
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0.0001
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O.OJ02
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0.0005
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0.0009
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O.U003
0.0004
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0.0007
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0.0007
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0.0016
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0.0022
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0.0023
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0.0032
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0.0070
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0.0045
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0.0099
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0.0114
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0.0098
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0.0001
0.0001
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0.0001
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0.0001
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0.0001
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0.0001
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0.0001
0-CRESOL
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SP 1000
0.0
******
******
******
******
******
0.0027
******
******
******
J. JU47
******
******
******
0.0036
******
******
******
******
******
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0.0022
******
******
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MM
PPM
SP 1000
0.0
******
******
******
******
******
0.0001
******
******
******
O.OOU4
******
******
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0.0007
******
******
******
0.0004
******
******
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0.0011
******
******
******
******
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Pf-M
******
******
1.07
******
******
******
******
******
******
******
******
******
******
******
1.07
******
******
******
******
******
******
******
******
******
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l.OU
cThANc
PPM
******
******
0.0047
******
******
******
******
******
******
******
******
******
******
0.004b
******
******
******
******
******
******
******
******
******
******
******
0.0045
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******
******
0.0025
******
******
******
******
******
******
******
******
******
******
0.0021
******
******
******
******
******
******
******
******
******
******
******
0.0017
-------
EC -339
TOLUENE «• BENZALCEHYCE
1976 NOV 21
Ln
W
oo
CLOCK
TIME
925
92b
945
lOuO
1015
1030
1U45
1100
1115
1130
1145
1ZOO
lili
1230
1245
1300
1513
1330
1345
1400
1415
1430
1445
li>ou
1515
1530
1545
ELAPSED
T(HIN)
-20.
-IT.
0.
15.
30.
45.
60.
T5.
90.
105.
120.
135.
150.
165.
160.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
ACETVLEN
PPM
iPNJ
******
******
0.0041
******
******
******
******
******
******
******
******
******
******
******
O.CX041
******
******
******
******
******
******
******
******
******
******
******
0.0051
ACETVLEN
PPM
(QMS)
******
******
0.0037
******
******
******
******
******
******
******
******
******
******
******
0.0040
******
******
******
******
******
******
******
******
******
******
******
0.0049
PROPANE
PPM
******
******
0.0011
******
******
******
******
******
*v****
*«¥«**
******
******
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0.0011
******
******
******
******
******
******
******
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******
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0.001C
PROP EN E
PPM
******
******
0.0002
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
0.0001
1-C4
PPM
******
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
0.0001
N-C4
PPM
******
******
0.0
******
******
******
******
******
******
******
******
******
******
******
O.JOOi
******
*v****
******
******
******
******
******
******
******
******
******
0.0001
BENZENE
PPM
******
0.0004
0.0005
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0007
******
0.0007
-------
EC -339
TOLUENE * BEN2ALDEHVDE
1978 NOV 21
Ul
CLOCK
TIMe
925
926
945
1COO
1015
1030
1045
1100
1115
1130
1145
1200
1215
1230
1245
I3v>0
1313
1330
1345
14uO
1415
1430
1445
15vjO
1513
1530
1545
ELAPSED
T(MIN)
-20.
-17.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
iOO.
315.
330.
345.
360.
TS
DEC F
******
******
66. 0
84.5
84. 8
65.0
85.2
85.5
86.0
86.0
86.2
86.5
£6.7
86.7
87.0
87.0
86.5
86.5
86.7
67.0
87.0
86.7
87.0
67.0
86.7
67.0
87.0
REL HUM
*
******
******
47.0
52.5
60.0
64.0
64.5
65.0
65.5
65.5
65.5
66.0
65.5
65.5
65.5
65.5
65.5
65.5
65.5
65.0
65. C
65.0
65.0
65.0
65.0
65.0
65.0
SSPCricR
Kh
******
******
15.21
******
******
******
15.09
******
******
******
15.01
******
******
******
15.17
******
******
*<.****
15.2?
******
******
******
15.33
******
******
******
15.33
RAD10M
MV./CM2
******
******
0.173
0.176
0.171
0.166
0.168
0.168
0.171
0.173
0.166
O.i71
0.171
0.168
O.lo6
0.173
0.163
0.168
0.164
0.166
0.164
0.168
0.171
0.171
******
******
0.171
HCHO VOL
L
******
******
20. CO
******
******
******
20.00
******
******
******
20. CO
******
******
******
20.00
******
******
******
20. CO
****.**
******
******
******
******
******
******
20. CO
TENX VO
L
10.00
******
******
******
******
******
10.00
******
******
******
10.00
******
******
******
10.00
******
******
******
12.35
******
******
******
10.00
******
******
******
******
-------
EC -340
TuLUENE
1978 NOV 22
8EG1N IRKAOIATICN 0930; 0.25 INCH PVREX fILTER; TRICHROIC FILTER OUT
SP 1000 IS 6' 0.1* SP 1000/CAR80PAK C
5< C-oOO IS 5' 5* C-6CC/C-22 COLUMN
10' C-600 IS 10' 10* C-tCO/C-22 COLUMN
dENcALDtriyOE VALUES FOR SP-1COO UNCEhlAIN. 5' C-600 DATA fKEFERREO
TIME INDICATED FOR TENAX SAMPLE IS START OF IS MINUTE COLLECTION
URADY 1193X! OASIbl 1212 (565 ML/MINI; TECC -.46-1 (540 fL/MINi USED
BECKMAN 6800 ON MANUAL OPERATION (FLOri 120 i-.L/MlNJ; CO FACTOR: 1.6/19.0
T«0 AT 930 PST
CALIB*
PAN
hCHO
REL INT
TS
REL HUM
SSPOwER
RAuiOM
h20
NO
(<0<:-C3RR
TGLoENE
CO
hCHO
ACETAtO
BtALD
METHANE
eTn4Nc
ETHsNE
ACETYcEN
PROPANE
OEG K
4
Kh
Mh/Ch2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
INIT CCNO
INIT CCND
INIT CCNO
INIT CCND
INIT CCNO
INIT CCNO
INIT CCNO
INIT CGNO
INIT CCND
INIT CCNO
INIT CCND
303.i
63.20
15.18
0.167
2.59GE 04
0.333
0.056
O.J37
i.593
C.CC5
0.001
C.Q02
1.205
0.005
O.C03
0.004
O.C01
ASSIGNED INITIAL CCNDITION
-------
EC -340
TOLUENE
1978 NOV 22
SPECTRAL DISTRiaUTICN: hAVELENGTW NMI REL. INTENSITY
500. 2.596
430. 2.074
403. 1.624
380. 1.578
370. 1.391
360. 1.173
350. 1.000
340. 0.777
330. 0.523
320. 0.277
310. 0.094
300. O.C
Kl=0.40 MIN-1
SAMPLING RATE = 1.759 L/MIN
42 GC SAMPLES TAKEN
-------
Ul
J>
to
ec -340
TOLUENE
1976 NOV 22
CLOCK
TIME
630
905
930
943
1000
1015
1030
1045
1100
1115
1130
1145
ItoJ
1215
1230
12t5
13JO
13X5
1330
1345
ItJO
1415
143J
144J
1500
1515
1530
ELAPSED
T(MIN)
-60.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
360.
OZONE
PPM
******
0.0
0.0
o.oco
0.000
0.002
O.doS
0.012
0.017
0.029
0.049
0.064
0.081
0.100
0.125
0.142
0.164
0.191
0.210
0.239
0.266
0.293
0.318
0.335
0.344
******
******
NO
PPM
******
0.352
0.333
C.304
C.274
0.232
0.186
0.148
0.123
0.098
C.C74
C.060
0.049
C.040
0.033
C.031
0.026
c.02i
C.U20
0.017
0.016
0.015
0.015
0.012
C.011
******
******
N02-CORR
PPM
******
Q.C66
0.096
0.128
0.148
o.iso
0.2C9
u.^33
0.239
0.250
0.244
0.246
0.233
0.223
0.211
0.191
0.169
0.152
0.134
0.119
0.099
0.082
0.065
0.050
0.042
******
******
NOX-CORR
PPM
^
******
******
0.430
0.428
0.421
0.409
0.395
0.378
U.363
C.344
0.320
0.308
0.281
0.259
0.242
0.218
0.193
0.173
0.151
0.131
0.114
0.096
0.076
0.062
0.05J
******
******
TOLUENE
PPM
lO'C-600
0.000
******
0.537
******
0.504
******
0.481
******
0.437
******
0.422
******
0.388
******
G. 362
******
0.342
******
0.313
******
0.289
******
0.260
******
0.238
******
0.214
TOLUENE
PPM
5> C-600
0.000
0.570
0.579
******
0.543
******
0.507
******
0.463
******
0.436
******
0.404
******
d.Jfc?
******
0.3oO
******
0.341
******
0.308
******
0.282
******
0.251
******
0.230
-------
EC -340
TOLUENE
1976 NOV 22
CLOCK
TIME
830
905
930
94i
1000
1015
1030
1045
i i fin
* 1 UU
1115
1130
1145
1230
1215
1230
1245
130U
1315
1330
1345
1400
1415
143.J
1445
1500
1515
1530
ELAPSED
TIMIN)
-60.
-25.
0.
15.
30.
45.
60.
75.
105.
120.
135.
150.
165.
180.
i**«
******
O.OOC2
******
******
******
******
******
******
******
******
******
0.0017
******
0.0023
******
******
******
0.0021
ACETONE
PPM
O.OOul
******
0.0005
******
0.0010
******
0.0015
******
0.0020
******
0.0043
******
0.0042
******
0.0084
******
0.0064
******
0.0120
******
0.0142
******
0.0159
******
0.0148
******
0.0164
MEK
PPM
0.0000
******
0.0000
******
u.OouU
******
LI. 0000
******
******
******.
0.0000
******
******
******
0.0000
******
******
******
******
******
******
******
******
******
******
******
0.0001
ME-N
PPM
******
******
0.0
******
0.0
******
0.0
******
0.0
******
o.u
******
0.0003
******
0.0003
******
0.0004
******
0.0003
******
0.0003
******
0.0005
******
0.0005
******
0.0004
BZALD
PPM
10'c-oJO
0.0023
0.0019
0.0020
******
O.OC33
******
O.OOtJ
******
******
0.0071
******
0.0074
******
0.0034
******
0.0081
******
0.0082
******
0.0074
******
0.0070
******
0.0066
******
0.0071
82ALD
PPM
SP 1000
******
0.0033
******
******
******
If If * * V *
O.OOtl
******
******
u.dluO
******
******
******
0.01U5
******
******
******
0.0069
******
******
******
U.0122
******
******
******
0.0086
0-CR£SJL
PPM
SP 1000
******
0.0006
******
******
******
******
0.0034
******
******
O.OU1
******
******
******
0. 01/40
***«¥*
******
******
0.0013
******
******
******
0.0012
******
******
******
0.0uu5
MNT
PPM
SP 1000
******
0.0
******
**v***
******
******
0.0003
******
******
O.uOlO
******
******
******
0.0007
******
******
******
0.0011
******
******
******
0.0011
******
******
******
0.0010
METHANE
PPM
1.20
******
1.20
******
******
******
*»**=*
*«»***
******
******
******
*?ev**
******
i • i 9
******
******
******
******
******
******
******
******
******
**** **
******
1.20
-------
EC -340
TOLUENE
1976 NOV 22
CLQCK
TIME
830
S.05
930
S45
1000
1015
1030
1045
1100
1115
1130
11
-------
Ul
J>
Ln
EC -3*0
TOLUENE
1978 NOV 22
CLOCK
T1HE
630
9Ji,
9jJ
9t5
ICoO
1015
103ii
1045
1100
1115
1130
1143
1200
1215
12JO
1245
13JO
1315
1330
1345
1400
14i5
1430
1445
1500
1515
1530
ELAPSED
T(MIN)
-60.
-25.
0.
15.
30.
45.
60.
75.
90.
105.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
285.
303.
315.
330.
345.
360.
TS
DEC F
******
83.3
t4.0
64.3
84.5
64.5
04.5
63.0
65.0
85.2
65.7
85.7
86.2
86.5
86.5
B6.7
87.0
86.7
87.2
87.0
87.0
86.7
87.0
86.7
86.2
******
******
REL HUM
91
******
47.0
50.5
55.5
59.0
61.5
63.5
64.0
64.5
64.5
64.5
64.5
64.5
64.5
64.5
64.5
64.5
64.0
64.0
64.0
64.0
64.5
64.5
64.5
64.5
******
******
SSPOnER
Kh
******
******
14.98
******
******
******
15.17
******
******
******
14.93
******
******
******
15.56
******
15.21
******
15.17
******
******
******
15.25
******
******
******
15.21
RACICM
Mft/CM2
******
******
0.173
0.166
0.166
0.168
******
******
******
******
0.164
0.171
******
******
0.173
0.168
0.166
0.164
0.166
******
******
******
0.168
0.166
0.164
******
******
HCHQ VOL
L
******
******
20. CO
******
******
******
20. CO
******
******
******
20.00
******
******
******
20. CO
******
******
******
20. CO
******
******
******
20.00
******
******
******
20.00
TENX VOL
L
******
10.00
******
******
******
******
10.00
******
******
******
10. UO
******
******
******
10.00
******
******
******
10.00
******
******
******
12.35
******
******
******
10.00
-------
Ul
EC -343
M-XYLENE
1978 NOV 29
oEUN I&RAOJATiGN IC30; 0.25 INCH PYREX FILTER; TRICHROIC FILTER OUT
Me-N PRESENT BUT LESS THAN 0.5 PPB
C2-N PRESENT BUT LESS THAN 0.5 PPB
SP 1000 IS 6' 0.1* SP 1000/CARoJPAK C
5' C-600 IS 5* 5* C-6CO/C-22 COLUMN
10' C-600 IS 10' 10S C-60C/C-22 COLUMN
SJLAR SIMULATOR POWER SET 10* TOO LOM FOR FIRST 105 MINUTES.
INCREASED FROM 13.46 TO 15.58 KM AT 1133
POOR TEMPERATURE CCNTRCL FOR FIRST 2 HOURS OUE TO SYSTEM MALFUNCTION
1030-1200: ANOMALOUSLY LC*i 10' C-600 M-XYLENE VALUES REJECTED
3ENZALDEHYGE VALUES FOR SP-1000 UNCERTAIN. 5' C-tOO DATA PREFERRED
TJLUALD MEASUREMENT CN SP-1000 NOT REPORTED BECAUSE OF INTERFERING PEAK
M-XYLENE VALUES FROM 5' 6 10' C-600 COLUMNS PREFERRED OVER THOSE F«OM SP-1000
M-XYLENE ADDED BY FLUSHING IN .4011 TORR IN 5.467 LITER BULB
CALCULATED INITIAL M-XYLENE = .5CC3 PPM
TIME INDICATED FOR TENAX SAMPLE IS START OF 15 MINUTE COLLECTION
BRADY H9JX; DASIBI 1212 (530 ML/KIN) t TECO 146-1 (540 ML/MM) USED
T=0 AT 1030 PST
CALIBrf
PAN
HChO
REL INT
TS
REL HUM
SSPOWER
RAuIOM
H20
NO
N02-CORR
M-XYL
HCriO
ACETALD
B^ALD
M-TOLALi)
METHANE
ETHANE
ETHcNc
ACETYLEN
PROPANE
DEC K
«
KH
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PFM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
1NIT CJND
INIT CCND
INIT CCND
INIT COND
INIT CCNO
INIT CCND
IMT CCNO
INIT CCNO
INIT COND
INIT COND
INIT CuNO
INIT CCNC
3C3.3
71.13
13.01
0.161
2.94UE 04
0.214
0.06 to
0.3c2
O.C09
O.C01
0.001
0.002
2.344
O.C09
O.CC5
0.005
0.001
ASSIGNED INITIAL CONDITION
-------
EC -343
M-XYLENE
1976 NflV 29
SPECTRAL DISTRIBUTION: ^AVELENGTHINM) REL. INTENSITY
SCO. 2.420
430. 2.046
403. 1.758
380. 1.552
370. 1.380
3oO. 1.153
350. 1.000
340. 0.773
330. 0.528
320. 0.287
310. 0.131
300. O.C10
290. O.G
Kl=0.38 M1N-1
SAMPLING RATE = 1.570 L/MIN
40 GO SAMPLES TAKEN
Ln
-------
-p-
oo
EC -J43
M-XYLENE
1978 NOV 29
CLOCK
TIMt
930
940
1030
1035
10 tO
1045
105u
1055
1100
1103
1110
1115
1120
1K5
1130
1135
1140
1145
1150
1155
1200
1£05
U10
1215
1220
1225
1230
1245
1300
1315
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
ELAPSED
T(MIN)
-60.
-50.
0.
5.
10.
15.
20.
23.
30.
35.
40.
45.
50.
55.
60.
65.
70.
75.
80.
65.
90.
95.
100.
105.
110.
115.
120.
135.
150.
165.
ISO.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
OZONE
PPM
******
******
0.000
0.0
0.000
0.005
0.015
0.039
0.071
0.110
0.151
0.176
0.200
0.227
0.252
0.269
0.281
0.283
0.281
0.276
0.274
0.264
0.254
0.244
0.235
0.227
0.220
0.198
0.176
0.164
0.151
0.139
0.130
0.122
0.115
0.110
0.105
C.10J
0.100
0.095
0.095
0.095
0.093
NO
PPM
******
******
0.214
C.210
0.182
0.133
0.106
0.059
C.Q38
C.028
C.026
0.022
0.021
0.018
0.017
0.016
0.016
0.015
0.013
0.012
0.012
0.015
0.011
0.012
0.012
C. 012
0.013
0.011
0.013
0.012
0.013
0.011
C.013
0.012
0.011
C.012
0.012
0.012
0.011
C.011
0.011
0.010
0.009
N02-CORR
PPM
******
******
0.066
O.C67
0.092
0.130
0.143
0.17b
0.189
0.175
0.155
0.136
0.121
0.101
0.061
0.075
O.OoT
0.056
0.041
0.035
0.030
0.031
0.026
0.028
0.026
0.025
0.024
0.022
0.016
0.018
0.014
0.016
0.015
0.018
0.017
0.015
0.016
0.013
0.013
0.014
0.015
0.016
0.014
NOX-CORR
PPM
******
******
0.279
0.276
0.271
0.259
0.248
0.234
0.223
0.202
0.177
0.158
0.139
0.117
0.097
o.asa
0.079
0.071
0.053
0.048
O.C41
0.043
0.040
0.041
0.037
0.036
0.034
0.032
0.026
0.026
0.027
0.028
0.026
0.029
0.027
0.025
0.025
0.023
0.022
0.023
0.021
0.023
0.020
M-XYL
PPM
lO'C-600
******
0.498
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.179
******
0.162
******
0.150
******
0.137
******
0.125
******
0.114
******
0.105
******
0.095
******
******
M-XYL
PPM
5' C-600
0.522
******
0.491
******
******
******
******
******
0.378
******
******
******
******
******
0.267
******
******
******
******
******
******
******
******
******
******
******
0.174
******
******
******
0.148
******
0.128
******
0.125
******
0.116
******
0.105
******
0.094
******
0.082
M-XYL
PPM
SP 1000
0.520
******
******
******
******
******
******
******
***¥#*
****** •
******
******
******
******
0.299
******
******
******
******
******
******
******
******
******
******
******
0.197
******
******
******
0.193
******
******
******
******
******
******
******
0.121
******
******
******
******
-------
EC -343
M-XITLENE
1978 NOV 29
CLOCK
TIME
930
940
1030
1055
1040
1045
1050
1033
1100
1103
1110
1115
1120
1125
1130
1135
1140
1145
1150
1155
UOO
1205
1210
121a
1220
1225
12JO
1243
1300
1315
1330
13«t5
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
cLAPSED
TIMINJ
-60.
-50.
0.
5.
10.
15.
20.
25.
30.
35.
40.
45.
50.
55.
60.
65.
70.
75.
80.
85.
90.
95.
100.
105.
110.
115.
120.
135.
150.
165.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
PAN
PPM
******
******
0.000
******
******
******
******
******
0.014
******
******
******
******
******
0.059
******
******
******
******
******
0.076
******
******
******
******
******
0.080
******
0.079
******
O.OS1
******
0.078
******
0.074
******
0.076
******
0.076
******
0.074
******
0.072
HCHO
PPM
******
******
C.OC9
******
******
******
******
******
******
******
******
******
******
******
0.050
******
******
******
******
******
******
******
******
******
******
******
0.050
******
******
******
0.067
******
******
******
0.074
******
******
******
0.088
******
******
******
0.077
ACETALO
PPM
******
0.0010
0.0010
******
******
******
******
******
0.0027
******
******
******
******
******
O.CC50
******
******
******
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******
0.0064
******
******
******
******
******
0.0061
******
0.0057
******
0.0066
******
O.C071
******
0.0065
******
0.0076
******
0.0071
******
0.0081
******
0.0086
PROPALO
PPM
******
0.0
0.0
******
******
******
******
******
******
******
**vv**
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0014
******
0.0009
******
******
******
******
******
******
******
******
******
******
******
0.0008
ACETONE
PPM
******
0.0004
O.OJC5
******
******
******
******
******
0.0069
******
******
******
******
******
0.0199
******
******
******
******
******
0.0158
******
******
******
******
******
0.0076
******
0.0066
******
0.0099
******
0.0094
******
0. 0044
******
0.0049
******
0.0040
******
0.0064
******
0.0073
BZALO
PPM
5« C-600
0.0013
******
0.0007
******
******
******
******
******
0.0003
******
******
******
******
******
0.0008
******
******
******
******
******
******
******
******
******
******
******
0.0004
******
******
******
0.0006
******
0.0018
******
0.0011
******
0.0015
******
0.0002
******
0.0019
******
0.0004
M-TOLALD
PPM
5' C-600
0.0046
******
0.0023
******
******
******
******
******
0.0071 .
******
******
******
******
******
0.0102
******
******
******
******
******
******
******
******
******
******
******
0.0092
******
******
******
0.0097
******
0.0090
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0.0086
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0.0083
******
0.0068
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0.0068
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0.0063
METHANe
PPM
******
******
2.34
******
******
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1.91
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1.93
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PPM
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0.00o6
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0.0071
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0.0067
ETHENE
PPM
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0.0040
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0.0029
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0.0026
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PPM
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******
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0.0022
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0.0026
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0.0027
PROPANE
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******
******
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0.0003
******
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0.0006
-------
EC -343
M-XYLENE
1976 NOV 29
CLOCK
TIME
930
940
1030
1035
1040
1045
1050
1055
1100
1105
1110
1115
1120
1125
1130
1135
1140
1145
in 115J
a "55
O 1200
1205
1210
1215
It .20
1225
U30
1245
1300
1315
1330
1345
14JO
1415
1430
1445
15-uJ
1515
1530
1545
1600
1615
1630
ELAPSED
TIMIN)
-60.
-50.
0.
5.
10.
15.
20.
25.
30.
35.
40.
45.
50.
55.
60.
65.
70.
75.
60.
65.
VO.
95.
100.
105.
110.
115.
120.
135.
150.
105.
180.
195.
210.
225.
240.
255.
270.
265.
300.
315.
330.
345.
360.
PRGPENE
PPM
******
******
0.000
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.000
******
******
******
******
******
******
******
******
******
******
******
0.000
I-C4
PPM
******
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
0.0001
N-C4
PPM
******
******
0.0000
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
o.ccci
******
******
****>**
******
******
******
******
******
******
******
******
0.0000
BENZENE
PPM
******
0.0002
0.0002
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
*v**v*
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
0.0001
TOLUENE
PPM
******
O.J01
0.001
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
O.OC1
******
0.001
-------
tC -343
W-XYLENe
197b NOV 29
CLOCK
TIME
930
940
1030
1035
lutu
10*5
Iu3u
1055
lidO
1105
1110
1115
1120
1125
1130
1135
1140
1145
Ln U50
Ui 1155
I-1 1200
1205
1210
1215
1220
i<.25
123ii
1245
1300
1313
1330
1345
1400
1415
1430
1445
1500
1515
1530
1545
1600
1615
1630
ELAPSED
T(MIN)
-60.
-50.
0.
5.
10.
15.
20.
25.
30.
35.
40.
45.
50.
55.
60.
65.
70.
75.
80.
65.
90.
95.
100.
105.
110.
115.
120.
135.
150.
165.
ieo.
195,
210.
225.
240.
255.
270.
285.
300.
315.
330.
345.
3oO.
TS
DEC F
******
******
86.5
91.6
90.6
69.4
69.2
69.4
69.9
90.1
67.9
66.7
66.0
67.9
67.2
87.0
85.0
85.0
67.9
69.9
89.6
87.7
86.7
86.2
65.7
85.5
65.5
85.7
85.5
85.0
85.2
85.5
85.5
85.7
65.0
85.0
85.0
66.0
85.5
85.2
86.0
85.7
86.2
REL HUM
S
******
******
46.5
49.0
52.5
57.5
62.0
65.0
6t>.0
67.0
68.0
69.0
70.0
71.5
72.0
72.5
71.5
71.5
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
73.0
SSPOAER
KM
******
******
13.46
******
******
******
******
******
******
******
******
******
******
******
15.56
******
******
******
******
******
******
******
******
******
******
******
15.17
******
******
******
15.17
******
******
******
15.09
******
******
******
15.21
******
******
******
15.38
KADI3M
MW/CM2
******
******
0.134
0.139
0.139
0.139
0.139
C.137
0.134
******
******
******
******
0.137
0.137
0.171
0.169
0.166
0.171
0.173
0.166
0.169
O.le9
0.1 06
0.169
O.lo6
6.166
******
******
0.166
0.164
******
******
******
0.166
0.164
0.166
0.169
0.164
******
******
4*4***
0.171
HCHO VOL
L
******
******
20.00
******
******
******
******
******
******
******
******
******
******
******
20. CO
******
******
******
******
******
******
******
******
******
******
******
20.00
******
******
******
20.00
******
******
******
20.00
******
******
******
20. CO
******
******
******
20. CO
TENX VOL
L
9.92
******
******
******
******
******
******
******
******
******
******
******
******
******
9.76
******
******
******
******
******
******
******
******
******
******
******
10.06
******
******
******
9.76
******
******
******
10.61
******
******
******
10.40
******
******
******
******
-------
EC -344
M-XYLENE
197« NOV 30
BEGIN IRRADIATION OV30; 0.25 iNCH PYREX FILTER; TRICMROIC FILTER OUT
C2-N PRESENT BUT DOES NOT EXCEED 1 PP8
SP 1000 IS 6' O.I* SP 1000/CARBJPAK C
3' C-oOO IS 5' SJt C-oCC/C-22 CtLUM
10' C-OOU IS 10' 103! C-60C/C-22 COLUMN
BENZALDEHYDE VALUEi FOR SP-1COO UNCERTAIN. 5' C-eOO DATA PREFERRED
TQLJALD MEASUREMENT CN SP-1000 NOT REPORTED d£CAOSE OF INTERFERING PEAK
M-XYLeNE VALUES FROM 5' i 10» C-600 COLUMNS PREFERRED OVER THOSE FROM SP-1000
M-XYLENE ADDEC BY FLUSHING IN .4001 TORR IN 5.4b7 LITER BUL8.
CALCULATED INITIAL M-XYLCNE « .4950 PFM
TIMc INDICATED FOR TENAX SAMPLE IS START OF 15 MINUTE COLLECTION
BRADY U93X; OASI6I 1212 (530 ML/MINJ; T£CO 148-1 (540 ML/MINI USED
BcCKMAN 6tOJ ON MANUAL CPERATIUN (FLOM 120 ML/MIN); CO FACTOR: 1.6/13.4
T»0 AT 930 PST
Ui
Ui
N5
CAL18*
PAN
hCHQ
REL INT
TS
REL HUM
SsPOhER
RADIOM
H20
NO
N02-CORR
M-XYL
CO
ACETALD
ACETONE
METHANE
ETHANc
ETrtcNE
ACETrLEN
PROPANE
66NZENE
DEG K
$
KM
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
FPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT C^NO
INIT CCND
INIT CCND
INIT CCNO
INIT CCND
INIT CCNO
INIT CCNO
INIT CQNO
INIT CCNC
INIT CCND
INIT CCND
INIT CCND
303.2
69.12
15.26
0.166
i.899E 04
C.JiO
0.154
0.494 *
1.858
O.COl
0.001
2.142
O.C08
0.004
0.006
O.COl
0.001
ASSIGNED INITIAL CCNDIT10N
-------
EC -344
M-XYLcNE
1978 NOV 30
SPECTRAL DISTRIBUTION: J«AVELENGTH.40 MIN-1
SAMPLING RATE - 1.7C1 L/MIN
42 CiC SAMPLES TAKEN
Ul
-------
Ui
EC -344
M-XYLENE
1978 NQV 30
CLOCK
TIME
850
912
930
935
$40
945
950
955
1000
1005
1010
1015
1020
1025
1030
1035
1040
1045
1050
1055
1100
1105
1110
1115
1120
1125
1130
1200
U30
13JO
1330
I4u0
1430
1500
1530
ELAPSED
TtMIN)
-40.
-18.
0.
5.
10.
15.
20.
25.
30.
35.
40.
45.
50.
55.
60.
65.
70.
75.
60.
85.
90.
95.
100.
105.
110.
115.
120.
150.
180.
210.
240.
270.
300.
330.
360.
OZONE
PPM
******
******
0.000
0.000
0.000
u.o
0.000
0.005
0.010
0.022
0.042
0.061
0.095
0.120
0.154
0.195
0.222
0.244
0.278
0.310
0.335
0.359
0.338
0.403
0.425
0.452
0.469
0.569
0.586
0.567
0.550
0.533
0.520
0.511
0.503
NO
PPM
******
******
0.520
C.5C8
0.471
0.440
0.386
0.318
C.247
0.208
0.139
0.100
0.076
0.061
0.049
C.037
0.034
0.029
C.C24
0.022
C.C.-2
0.0£0
O.J^Q
0.017
0.017
6.017
0.015
0.012
0.012
0.012
0.015
0.012
C.010
0.012
G.012
N02-CGR8
PPM
******
******
0.154
0.164
0.192
0.213
0.256
0.323
0.375
0.391
0.441
0.454
0.452
0.441
0.439
0.416
0.394
0.373
0.351
0.330
0.3C8
0.288
O.iOd
0.249
0.224
J.ilZ
0.1S2
0.1C9
0.039
0.059
0.044
0.040
0.048
0.043
0.043
NOA-CORR
PPM
******
******
0.671
0.663
0.661
0.645
0.637
0.631
0.615
0.589
0.568
0.546
0.518
0.492
0.473
C.448
0.421
0.393
0.368
0.343
0.317
0.300
0.276
0.253
0.234
0.214
0.1S7
0.109
0.070
0.061
0.044
0.042
0.053
0.043
0.048
M-XVL
PPM
lO'C-600
******
0.478
0.486
******
******
******
******
******
0.371
******
******
******
******
******
0.269
******
******
******
******
******
0.168
******
******
******
******
******
0.139
0.098
0.074
0.061
0.049
0.043
0.035
0.029
0.022
M-AYL
PPM
SP 1000
0.514
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
****** •
******
******
******
******
0.177
******
0.082
******
0.052
******
******
******
******
M-XYL
PPM
5« C-600
0.507
******
0.499
******
******
******
******
******
0.4UO
******
******
******
******
******
O.i68
******
******
******
******
******
0.183
******
******
******
******
******
0.137
0.095
0.073
0.060
0.049
0.041
0.034
0.028
0.020
-------
EC -344
M-XlrLENE
1978 NOV 30
CLOCK
TIME
050
912
930
935
S>4i>
945
950
955
1000
i005
IciO
1015
1020
1025
1030
1035
10
-------
ec -344
M-AYLENE
1978 NOV 30
CLOCK
TIME
850
SU
V30
935
940
945
950
955
ic/oo
1005
1010
1015
1020
1025
1030
liijS
1040
1.J45
Ul 1050
Ui 1055
ON 1100
1105
1110
1115
1120
1125
.1130
ItOO
1230
1300
1330
1400
1430
1500
1530
ELAPSED
T(MIN)
-40.
-18.
0.
5.
10.
15.
20.
25.
30.
35.
40.
45.
50.
55.
60.
65.
70.
75.
80.
85.
90.
95.
100.
105.
110.
115.
120.
150.
IdO.
£10.
240.
270.
300.
330.
360.
ETHENE
PPM
******
******
O.U041
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0028
******
******
******
******
******
0.0021
ACETVLEN
PPM
(PNJ
******
******
0.0063
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0068
******
******
******
******
******
w.0063
ACETVLEN
PPM
(QMS)
******
******
0.002i
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0041
******
******
******
******
******
0.0050
PROPANE
PPM
******
******
0.0009
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
O.OOC8
******
******
******
******
******
0.0007
PROPENE
PPM
******
******
0.000
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.000
******
******
******
******
******
0.000
I-C4
PPM
******
******
0.0001
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
0.0001
N-C4
PPM
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
0.0001
1-C4*
PPM
******
******
0.0
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
, ******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
0.0001
BENZENE
PPM
******
0.0002
0.0009
******
******
******
******
******
O.OU65
******
******
******
******
******
0.0065
******
******
******
******
******
0.0065
******
******
******
******
******
0.0065
0.0065
0.0085
0.0085
0.0
******
******
******
******
TOLUENE
PPM
******
O.uuO
0.000
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
-------
Ln
EC -344
M-AYLENE
1976 NOV 30
CLOCK.
TIME
650
91i
930
935
943
945
950
955
1000
1CCJ5
101U
1015
1020
1025
1030
1035
1040
1045
1050
1055
iluu
11 u5
1110
1113
1120
1125
1130
120C
1230
1300
1330
1400
1430
1500
1530
ELAPSED
T(MIN)
-40.
-18.
0.
5.
10.
15.
20.
25.
30.
35.
40.
45.
50.
55.
60.
65.
70.
75.
80.
85.
90.
95.
100.
105.
110.
115.
120.
150.
ISO.
210.
240.
270.
300.
330.
360.
TS
DEG F
******
******
63.3
85.0
84.5
84.8
85.0
34.8
85.2
65.0
65.5
85.2
65.2
85.0
85.0
35.5
86.0
86.0
86.2
86.7
66,0
86.2
66.5
87.4
£6.7
87.7
6o.7
87.9
66.7
85.7
85.5
65.5
86.0
86. C
86.2
REL HUM
X
******
******
57.0
57.5
59.0
61.0
62.5
64.0
65.5
6t>.5
67.5
68.5
69.0
69.0
69.5
69.5
69.5
69.5
69.5
69.5
69.5
69.5
69.5
69.5
69.5
69.5
69.5
69.5
70.5
70.5
70.5
70.5
70.5
70.5
70.0
SSPOrfER
Kh
******
******
15.19
******
******
******
******
******
******
******
******
******
******
******
15.42
******
******
******
******
******
******
******
******
******
******
******
15.25
******
15.17
******
14.86
******
15.25
******
15.66
RAOiOM
MW/CM2
******
******
0.171
0.176
0.171
0.109
O.lo9
0.166
0.166
0.169
0.166
0.106
0.164
O.lo9
0.169
******
******
******
******
******
******
******
******
******
******
******
0.169
******
0.166
0.161
0.159
******
0.166
******
0.176
HCHO VOL
L
******
******
20.00
******
******
******
******
******
******
******
******
******
******
******
20. CO
******
******
******
******
******
******
******
******
******
******
******
20. CO
******
20. CO
******
20.00
******
20. CO
******
20.00
TENX VOL
L
9.75
******
******
******
******
******
******
******
******
******
******
******
******
******
11.55
******
******
******
******
******
******
******
******
******
******
******
10.50
******
12.06
******
10.05
******
10.04
******
******
-------
Ul
Ui
oo
EC -3*5
M-XYLENE
1978 DEC I
6EGIN IRRADIATION 0930; 0.25 INCH PYREX FILTER! TRICHROIC FILTER OUT
C.Z-H PRESENT BUT DOES NCT EXCEED 1 PP8
SP lOuJ IS 6* 0.1* SP 1000/CAftBOPAK C
a' C-600 IS 5' 51 C-6CC/C-22 COLUMN
10' C-600 IS 10' 10* C-6CC/C-22 COLUMN
6ENiAt.OEHYDE VALUES FOR SP-iQOO UNCERTAIN. 5' C-600 DATA PREFERRED
TJLUALD MEASUREMENT CN SP-iOOO NOT REPORTED BECAUSE OF INTERFERING PEAK
POROPAK-N (PNJ INSTRUMENT PROBLEMS. VALUES PROBABLY ARE 4US HIOH
M-XVLCNE VALUES FROM 5' G 10' C-600 COLUMNS PREFERRED OVER THOSE FROM SP-1000
ri-XYLENc INJECTED BY FLUSHING IN .4020 TQRR IN 5.467 LITER BULB
CALCULATED INITIAL M-XYLENE = .5014 PPM
TIME INDICATED FOR TENAX SAMPLE IS STAKT OF 15 MINUTE COLLECTION
BRADY 1193X. DASIBI 1212 (53C ML/MIN), TECO 146-1 (540 ML/MIN) USED
bECKMAN 6800 ON MANUAL OPERATION (120 ML/MINI; CO FACTOR 1.6/14.8
T*0 AT 930 PST
CALIB*
PAN
HCHO
REL INT
TS
ft£L HUM
SSPJnER
RA010M
H20
NO
ND2-CORR
M-XYL
cc
HCHD
ETHAN E
ETHENE
ACETYLEN
PROPANE
DEG K
*
KM
MW/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
IMT CCNO
INIT CCNO
INIT CCNO
INIT CCND
INIT CCND
INIT COND
INIT CCNO
INIT CCNO
INIT CCND
303.1
60.76
14.97
0.161
2.521E 04
0.220
0.059
C.480
5.206
O.C02
O.OC7
O.OG4
0.006
0.001
ASSIGNED INITIAL CONDITION
-------
EC -3*5
M-XfLENE
1978 DEC 1
SPECTRAL DISTRIBUTION: k>AVcLENGTH(NMI REL. INTENSITY
5CO. 2.257
430. 1.924
403. 1.743
330. 1.528
370. 1.354
360. 1.14o
350. l.COO
340. 0.772
330. 0.528
320. 0.280
310. 0.096
300. 0.007
290. 0.0
Ki=0.39 MIN-1
SAMPLING RATE = 1.664 L/NIN
42 GC SAMPLES TAKEN
-------
Ui
<^
o
EC -3*5
M-XYLENE
1970 DEC 1
CLOCK
TIHc
650
905
933
935
940
945
95J
955
1000
1003
1010
1015
Iu20
1025
1030
1045
1100
1115
1130
1200
1230
1300
1330
1400
1430
1500
1530
ELAPSED
TJMIN)
-40.
-25.
0.
5.
10.
15.
20.
25.
30.
35.
40.
45.
50.
55.
60.
75.
90.
105.
120.
150.
180.
210.
£40.
270.
300.
330.
360.
OZONE
PPN
******
******
0.0
0.002
0.005
0.017
0.042
0.093
0.149
0.203
0.256
0.303
0.342
0.364
0.361
0.396
0.366
0.376
0.366
0.354
0.342
0.332
0.327
0.322
0.320
0.31S
0.318
Nu
PPH
******
******
0.220
C.205
0.164
0.123
0.062
0.032
C.023
0.016
0.012
C.011
0.009
0.007
0.007
C.007
0.007
O.OOo
0.007
0.007
O.C06
0.007
0.007
0.007
C.006
C.005
0.006
N02-CO&R
PPP
******
******
O.C59
0.069
0.103
0.131
0.161
0.192
0.179
O.lbO
0.143
0.124
0.103
O.C37
O.b76
0.046
0.026
0.022
0.021
O.Q2o
0.023
0.026
0.026
0.024
0.025
0.025
0.027
NOX-CCRR
PPK
******
******
0.278
0.273
0.266
0.253
0.241
0.2<4
0.201
0.173
0.152
0.132
0.110
0.095
0.081
0.053
0.031
0.026
0.025
0.031
0.027
0.031
O.C32
0.029
0.02S
0.031
0.031
M-XYL
PPM
iO'C-600
******
******
0.480
******
******
******
******
******
0.338
******
******
******
******
******
0.22d
******
0.1 54
******
0.175
0.161
0.146
0.126
0.116
0.102
O.OS4
******
0.073
M-XYL
PPM
5* C-600
******
0.478
******
******
******
******
******
******
0.350
******
******
******
******
******
0.237
******
0.199
******
0.177
0.162
0.142
0.132
0.111
0.101
0.091
0.082
0.072
M-XYL
PPM
SP 1000
******
0.465
******
******
******
******
******
******
******
*******
******
******
******
******
0.209
******
******
******
0.177
******
0.156
******
0.115
******
******
******
u.osa
-------
EC -345
M-XVLENE
1978 DEC 1
CLOCK
TIME
850
903
930
935
940
945
950
955
iOOO
1005
1C10
1015
1C 20
1025
1030
1045
1100
1115
1130
1200
1230
1300
133o
1400
1430
1500
1530
ELAPSED
T(MIN)
-40.
-25.
0.
5.
10.
15.
20.
25.
30.
35.
40.
45.
50.
55.
60.
75.
90.
105.
120.
150.
180.
210.
240.
270.
300.
330.
360.
CO
PPM
******
******
5.21
******
******
******
******
******
******
******
******
******
******
******
5.^7
******
******
******
5.40
******
5.56
******
5.72
******
5.78
******
5.99
PAN
PPM
******
******
0.000
******
******
******
******
******
0.023
******
******
******
******
******
******
******
0.103
******
0.107
0.098
0.102
0.095
C.090
0.092
0.087
0.084
0.081
HCHO
PPM
******
******
0.002
******
******
******
******
******
******
******
******
******
******
******
0.030
******
******
******
O.C6C
******
******
******
0.124
******
0.12C
******
0.136
ACETALO
PPM
******
******
******
******
******
******
******
******
0.0u26
******
*»-****
******
******
******
0.0050
******
0.0063
******
0.0080
0.0089
0.0096
0.0105
0.0117
0.0127
0.0129
0.0138
0.0144
PROPALO
PPM
******
******
******
******
******
******
******
******
O.OJll
******
******
******
******
******
0.0017
******
0.0017
******
0.0022
******
******
******
0.0021
0.0022
0.0022
0.0023
******
ACETONE
PPM
******
******
******
******
******
******
******
******
0.0075
******
******
******
******
******
0.0132
******
0.0118
******
0.0116
0.0208
0.0223
0.0169
0.0166
0.0159
0.0183
0.0185
0.0181
Mt-N
PPM
******
******
0.0
******
******
******
******
******
0. Juu2
****** •
******
******
******
******
0.0004
******
******
******
******
0.0002
0.0005
0.0005
0.0005
0.0005
0.0005
0.0006
0.0006
BZALO
PPM
5' C-600
******
0.0011
******
******
******
******
******
******
0.0007
******
******
******
******
******
0.0002
******
0.0004
******
0.0012
0.0010
0.0013
0.0009
0.0015
0.0002
0.0014
0.0009
0.0002
K-TOLALO
PPM
5' C-600
******
0.0002
******
******
******
******
******
******
U. UUbO
******
******
******
******
******
0.0087
******
0.0109
******
0.0115
0.0090
C.0092
0.0128
G.0083
0.0090
0.0077
0.0067
0.0060
METHANE
PPM
-------
Ui
<^
NJ
cC -345
M-XYLENE
1978 DEC ]
CLOCK
TIME
65J
9d:>
930
935
940
945
950
955
1000
1005
lv,10
1C/15
1020
1025
1030
1045
1100
1115
1130
1200
U30
1300
1330
1400
143d
1500
1530
ELAPSED
T(MIN)
-40.
-25.
0.
5.
10.
15.
20.
25.
30.
35.
40.
45.
50.
55.
60.
75.
90.
105.
120.
150.
180.
210.
240.
270.
300.
330.
360.
I
ACETYLEN
PPM
(PN)
******
******
0.0063
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0074
******
******
******
******
******
0.0089
ACETYLEN
PPM
(CMS)
******
******
0.0038
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0047
******
******
******
******
******
0.0056
PROPANE
PPM
******
******
0.0009
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
O.OOC9
******
******
******
******
******
O.OOC8
PROPENE
PPM
******
******
0.0002
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
C.0001
1-C4
PPM
******
******
0.0000
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
0.0001
N-C4
PPM
******
******.
0.0000
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
0.0001
******
******
******
******
******
0.0001
I-C5
PPM
******
******
0.0
******
******
******
******
******
******
******
******
******
******
******
******
******
*******
******
******
******
0.0002
******
******
******
******
******
0.0
BENZENE
PPM
******
******
0.0002
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
******
T3LUENE
PPM
lO'C-600
******
******
0.000
******
******
******
******
******
******
******
******
******
******
«*«***
*¥****
******
******
******
******
******
******
******
******
******
******
******
******
-------
Ui
EC -345
M-XVLENE
1978 DEC 1
CLOCK
TIME
650
905
930
9ia
940
945
950
955
1000
1005
1010
1015
1020
10 i 5
1030
10f5
110U
1115
1130
liOO
12->0
1300
1330
1400
1430
1500
1530
ELAPSED
T(MIN)
-40.
-25.
0.
5.
10.
15.
iO.
25.
30.
35.
40.
45.
50.
55.
60.
75.
90.
105.
120.
150.
180.
210.
240.
270.
300.
330.
360.
TS
DEC F
******
******
84.0
84.8
64.3
£4.5
84.3
84.0
84. C
85.0
84.3
85.0
65.2
85.2
84.3
64.8
65.5
85.2
85.7
86.2
86.2
86.0
86.5
86.7
87.0
87.0
86.7
REL HUM
X
******
******
50.5
51.0
52.5
53.5
55.0
56.0
57.0
58.0
59.0
59.5
60.0
60.5
61.0
61.5
62.0
62.0
61.5
61.5
62.0
62.0
62.0
62.0
61.5
61.5
. 61.0
SSPOWER
Kh
******
******
14.98
******
******
******
******
******
******
******
******
******
******
******
14.83
******
******
******
14.58
******
15.05
******
15.17
******
15. Cl
******
15.17
RADIOM
HH/CM2
******
******
0.1&6
0.169
0.166
0.166
0.161
0.161
0.164
0.161
0.161
0.164
0.161
0.161
0.156
******
******
******
0.159
******
0.159
0.164
0.159
******
0.159
0.161
0.164
HCHO VOL
L
******
******
20.00
******
******
******
******
******
******
******
******
******
******
******
20.00
******
******
******
20. CO
******
******
******
20.00
******
20.00
******
20.00
TENX VOL
L
******
10.05
******
******
******
******
******
******
******
******
******
******
******
******
10.57
******
******
******
10.50
******
11.93
******
10.50
******
11.39
******
10.05
-------
Ln
EC -346
M-XYLENE
197o DEC 6
aEGIN IRRADIATION lC30i 0.25 INCH PYKEX FILTER! TRICHROIC FILTER OUT
TMJ HOUR RUN
NO 03 DATA KECCRCED UNTIL llil
SP 1000 IS 6" 0.1* SP 1000/CAKBJPAK. C
5' C-600 IS 5« 3% C-6CO/C-22 COLUMN
10* C-600 IS 10' 10* C-eOC/C-22 COLUMN
BENZALDEHYOE VALUES FOR SP-1COO UNCERTAIN. 5" C-600 DATA PREFERRED
TOLUALu MEASUREMENT CN SP-1UOO NOT REPCRTEO BECAUSE OF INTERFERING PEAK
M-XYLENE VALUES FKQM 5' t 10' C-600 COLUMNS PREFERRED OVER THOSE FROH SP-1000
M-XYLENc INJECTED BY FLUSHING IN .4010 TORR IN S.4t>7 LITER BULB.
CALCULATED INITIAL H-XYLENE = .5002 PPM
TIME INDICATED FOR TENAX SAMPuE IS START 3F 15 MINUTE COLLECTION
bRADY 1193X; OASIbJ 1212 <53C ML/MINJj TECO 14B-1 (540 ML/KINJ USEO
o600 CN MANUAL OPeRATIUN (FLOta 120 ML/M1N); CO FACTOR: 1.6/14.0
T«0 AT 1030 PST
PAN
hCHO
RcL INT
TS
REL HUM
SSPDxER
RAD1CM
H20
NO
NCk-CORR
M-XYL
Co
HCHO
ACETALO
BtALD
METHANE
ETHANE
ETHcNE
ACETYLEN
PROPANE
OEG K
i
Kh
Mpl/CM2
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
CALIB*
9
3
4
AVERAGE
AVERAGE
AVERAGE
AVERAGE
AVERAGE
INIT CCNO
INIT CCND
INIT CCNO
INIT CCNO
INIT CCNO
INIT CCNO
INIT CCND
INIT CCND
INIT CONO
INIT CCNO
INIT CCND
INIT CONO
304.2
S9.57
15.44
C.170
2.t52E 04
0.204
0.059
0.494 *
C.79S
0.006
0.001
O.OG1
1.306
0.004
O.C04
0.006
0.001
ASSIGNED INITIAL CONDITION
-------
Ui
ON
Ln
EC -346
M-XUtNE
1978 DEC 6
SPECTRAL DISTRIBUTION:
hAVELENGTH(NK)
500.
430.
403.
380.
370.
360.
350.
340.
330.
220.
310.
300.
290.
REL. INTENSITY
2.193
1.891
1.699
1.518
1.346
1.147
l.COO
0.774
0.539
0.2S1
0.097
0. C07
0.0
Kl*0.39 MIN-i
SAMPLING RATE » 1.754 L/HIN
15 GC SAMPLES TAKEN
-------
EC -346
M-XVLENE
1978 DEC 6
CLOCK
TIME
1005
X030
1035
1100
1105
1110
1115
1120
1125
1130
1145
1200
1215
1230
ELAPSED
T(M1N)
-25.
0.
5.
30.
35.
to.
45.
50.
55.
6 Li.
75.
90.
105.
120.
OZONE
PPM
******
******
******
******
******
******
0.340
0.366
0.384
0.384
0.3dl
0.362
0.352
0.342
NO
PPM
******
0.204
0.193
******
0.022
C.021
0.020
0.017
0.017
0.016
O.U20
0.015
C.013
0.012
N02-C3RR
PPM
******
O.U59
O.C66
******
0.118
C.CS?
0.061
0.069
0.053
0.043
0.031
0.018
0.017
0.015
NOX-CQRR
PPM
******
0.261
0.257
******
0.139
0.117
0.098
0.0d5
0.067
0.056
0.049
0.032
0.028
0.026
M-X>L
PPK
lO'C-600
0.493
0.486
******
0.321
******
, ******
******
******
******
0.^17
******
0.161
******
0.158
M-XVL
PPM
5< C-600
0.482
0.507
******
0.32J
******
******
******
******
******
0.221
******
0.179
******
0.157
M-XVL
PPM
SP 1000
******
******
******
******
******
******
******
******
******
0.219'
******
******
******
0.177
t_n
-------
EC -3*6
M-XVLENE
197o DEC to
CLOCK
TIME
1005
1030
103a
1100
1105
1UO
1115
IliO
1125
1130
1145
uoo
1215
1230
ELAPSED
TIMIN)
-*5.
0.
5.
30.
35.
40.
45.
50.
55.
60.
75.
90.
105.
120.
CO
PPM
******
0.30
******
******
******
******
******
******
******
1.01
******
1.07
******
1.14
PAN
PPM
******
C.CCO
******
0.036
******
******
******
******
******
O.OS1
******
0.101
******
0.102
HCHO
PPM
******
O.C06
******
******
******
******
******
******
.******
0.051
******
******
0.074
******
ACETALD
PPM
o.ooca
0. C007
******
0.0029
******
******
******
******
******
0.0051
******
0.0066
******
O.C087
PKOPALD
PPM
O.OOC1
******
******
0.0015
******
******
******
******
******
******
******
******
******
0.0026
ACETLNE
PPM
0.0006
0.0005
******
0.0177
******
******
******
******
******
0.0260
******
0.0237
******
0.0161
MEK
PPM
0.0002
******
******
******
******
******
******
******
******
******
******
******
******
******
ME-N
PPM
******
0.0
******
0. 0004
******
******
******
******
******
O.J006
******
0.0003
******
0.0007
C2-N
PPM
******
(1.0
******
0.0001
******
******
******
******
******
0.0002
******
0.0002
******
0.0002
oiALD
PPM
0.0031
0.0009
******
0.0008
******
******
******
******
******
0.0008
******
U.0015
******
0.0016
»-TOiAi.C
PPM
5' C-600
0.0007
0.0
******
0.0u72
******
******
******
******
******
0.0u94
******
0.0104
******
0.0057
METHANE
PPM
******
1.31
******
******
******
******
******
******
******
******
******
******
******
1.30
ETHANE
PPM
******
0.0040
******
******
******
******
******
******
******
******
******
******
******
0.0034
Ui
o\
sj
-------
EC -346
M-XYLENE
1978 DEC 6
CLOCK
TIME
1005
1030
lu.i
11CO
llua
lllu
lliS
1120
1K5
1150
1145
1200
1215
1230
ELAPSED
TtHINJ
-25.
0.
5.
30.
35.
40.
45.
50.
55.
60.
75.
90.
105.
120.
ETHENE
PPM
******
0.0041
******
******
******
******
******
******
******
******
******
******
******
0.0029
ACETYLEN
PPM
PN
******
0.0055
******
******
******
******
******
******
******
******
******
******
******
0.0059
ACETYLeN
PPM
QMS
******
O.C071
******
******
******
******
******
******
******
******
******
******
******
O.CC76
PROPANE
PPM
******
o.oooa
******
******
******
******
******
******
******
******
******
******
******
0.0007
PROPENE
PPM
******
0.000
******
******
******
******
******
******
******
******
******
**** **
******
0.000
I-C4
PPM
******
0.0
******
******
******
******
******
******
******
******
******
******
******
0.0001
BENZENE
PPM
0.0002
0.0002
******
******
******
******
******
******
******
******.
******
******
******
******
Ui
o>
oo
-------
tC -346
M-XVLENE
1976 DEC 8
CLCCK.
TJMc
1005
1030
1035
11 00
1105
1110
U15
1120
1125
UjJ
11*5
U JO
Uli
U30
ELAPSED
T(MIN)
-25.
0.
5.
30.
35.
40.
*5.
50.
55.
60.
75.
90.
105.
120.
TS
OEG F
******
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TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1 -EPOHT NO.
EPA-600/3-79-110
3. RECIPIENT'S ACCESSIOWNO.
4. TITLE AMD SUBTITLE
MECHANISMS OF PHOTOCHEMICAL REACTIONS IN URBAN AIR
Final Report
5. REPORT DATE
November 1979
6. PERFORMING ORGANIZATION CODE
7 AUTHOR(S)
8. PERFORMING ORGANIZATION REPORT NO
James N. Pitts, Jr., Karen Darnall, William P. L. Cartel
Arthur M. Winer, and Roger Atkinson
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Statewide Air Pollution Research Center and
Department of Chemistry
University of California
Riverside, California 92521
10. PROGRAM ELEMENT NO.
1AA6Q3 AC-20. FY-78,
—'— — *-** ir •" 1 ~• n I
11. CONTRACT/GRANT NO.
Grant No. 800649
12. SPONSORING AGENCY NAME AND ADDRESS
Environmental Sciences Research Laboratory- RTF, NC
Office of Research and Development
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final 12/1/74-11/30/7
14. SPONSORING AGENCY CODE
EPA/600/09
15. SUPPLEMENTARY NOTES
Previous Report: EPA-600/3-77-014a and EPA-600/3-77-014b
16. ABSTRACT
Results of an environmental chamber study and three basic studies pertaining to the
chemistry of air pollution.; are described. Results obtained during the last four years
of a long-term program designed to provide data required for the validation of models
for chemical transformations in air pollution are presented. A 5800-liter, Teflon-
coated, evacuable, thermostatted chamber and a 25 KW xenon arc solar simulator were
used for irradiations, under simulated atmospheric conditions, of various hydrocarbon-
NO -air mixtures. Results from a total of 114 irradiations, employing representative
alkanes, olefins, aromatics, and oxygenates, both singly and in two or multi-hydro-
carbon mixtures, are reported. The experimental procedures and analytical methods
employed in this study and the limitations and uncertainties in the data are discussed
The kinetics and mechanism of the gas phase reaction of hydroxyl radicals with o-creso
and methoxy benzene were studied over the temperature range 299-435 K using a flash
photolysis resonance fluorescence technique. The reactions of 0- with acetylene,
methylglyoxal and a series of aromatic hydrocarbons were studied at 297 + 2 K, and
rate constants and product data are reported. The chemical ionization mass spectrum
of peroxyacetylnitrate (PAN), a major component of photochemical smog, was obtained
using both methane and isobutane as reagent gas and the results confirmed the commonly
accepted structure for PAN, CH-(CO)OONO?.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.IDENTIFIERS/OPEN ENDED TERMS
COSATI Field/Group
Air pollution
Photochemical reactions
Reaction kinetics
Hydrocarbons
Ozone
Nitrogen oxides
13B
07E
07D
07C
07B
3. DISTRIBUTION STATEMENT
RELEASE TO PUBLIC
19. SECURITY CLASS (ThisReport)
UNCLASSIFIED
21. NO. OF PAGES
580
20. SECURITY CLASS (Thispage)
UNCLASSIFIED
22. PRICE
EPA Form 2220-1 (9-73)
570
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