&EPA
United States
Environmental Protection
Agency
Environmental Research
Laboratory
Athens GA 30605
EPA-600 4-79-017
March 1979
Research and Development
Inductively Coupled
Plasma-Atomic
Emission
Spectroscopy
Prominent Lines
-------
RESEARCH REPORTING SERIES
Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology. Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:
1 Environmental Health Effects Research
2. Environmental Protection Technology
3. Ecological Research
4. Environmental Monitoring
5. Socioeconomic Environmental Studies
6. Scientific and Technical Assessment Reports (STAR)
7 Interagency Energy-Environment Research and Development
8. "Special" Reports
9. Miscellaneous Reports
This report has been assigned to the ENVIRONMENTAL MONITORING series.
This series describes research conducted to develop new or improved methods
and instrumentation for the identification and quantification of environmental
pollutants at the lowest conceivably significant concentrations. It also includes
studies to determine the ambient concentrations of pollutants in the environment
and/or the variance of pollutants as a function of time or meteorological factors.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.
-------
EPA-600/4-79-017
March 1979
INDUCTIVELY COUPLED PLASMA - ATOMIC
EMISSION SPECTROSCOPY: PROMINENT LINES
by
R. K. Winge, V. J. Peterson, and V. A. Fassel
Ames Laboratory, USDOE
Iowa State University
Ames, Iowa 50011
Interagency Agreement No. EPA-IAG-78-D-X0146
Project Officer
Charles E. Taylor
Analytical Chemistry Branch
Environmental Research Laboratory
Athens, Georgia 30605
ENVIRONMENTAL RESEARCH LABORATORY
OFFICE OF RESEARCH AND DEVELOPMENT
U.S. ENVIRONMENTAL PROTECTION AGENCY
ATHENS, GEORGIA 30605
-------
DISCLAIMER
This report has been reviewed by the Environmental Research
Laboratory, U.S. Environmental Protection Agency, Athens, Ga.,
and approved for publication. Approval does not signify that
the contents necessarily reflect the views and polices of the
U.S. Environmental Protection Agency, nor does mention of trade
names or commercial products constitute endorsement or recommen-
dation for use.
-------
FOREWORD
Nearly every phase of environmental protection depends
on a capability to identify and measure specific pollutants
in the environment. As part of this Laboratory's research on
the occurrence, movement, transformation, impact, and control
of environmental contaminants, the Analytical Chemistry Branch
develops and assesses new techniques for identifying and
measuring chemical constituents of water and soil.
The use of inductively coupled plasma (ICP)-atomic emission
spectroscopy is expected to increase rapidly as analytical
chemists confront new problems in elemental characterization.
This report records the prominent lines of the ICP emission
spectra of some 70 elements as the first step in the development
of a spectral atlas that would serve as a useful tool in the
selection of analytical lines for this spectroscopic technique.
David W. Duttweiler
Director
Environmental Research Laboratory
Athens, Georgia
111
-------
PREFACE
An analytical facility, employing inductively coupled
plasma, atomic emission spectroscopy (ICP-AES), is being
developed for the rapid and comprehensive qualitative and
quantitative survey of the chemical elements in water. Because
many of the elements of interest in water are present at trace
or ultratrace levels we needed tc know the "ultimate" line
(yielding the lowest detection limit) for each element as well
as alternate lines in the event the ultimate line proved to
be unsuitable for a particular analytical problem. When this
project was undertaken, little information was available on
the relative intensities of spectral lines emitted by the ICP.
With the available time and resources we could not produce the
ICP equivalent of the MIT or NBS wavelength tables. We did,
however, develop a relatively simple and rapid method for
estimating the analytical capabilities of the prominent lines
emitted by 70 metallic and metalloid elements. The resulting
data, contained in this report, are therefore a necessary pre-
requisite for the development of an elemental survey instrument
based on ICP-AES.
IV
-------
ABSTRACT
The prominent lines of 70 elements as emitted in an
inductively coupled plasma excitation source have been
identified. The lines are listed alphabetically by element
and numerically by wavelength. Detection limit capabilities
are estimated for each spectral line.
This report was submitted in fulfillment of Interagency
Agreement IAG-EPA-78-D-X0146 by the Ames Laboratory under the
sponsorship of the U.S. Environmental Protection Agency. This
report covers the period from March 1, 1977, to February 28,
1978, and work was completed as of August 17, 1978.
v
-------
CONTENTS
Foreword iii
Preface iv
Abstract v
Figures and Tables viii
Abbreviations and Symbols ix
Acknowledgment ix
1. Introduction 1
2. Conclusions and Recommendations 3
3. Experimental Facilities and Procedures 4
4. Results and Discussion 8
References 11
Preface to Appendices A and B 12
Appendices
A. Prominent Lines of the Elements Emitted by
the Inductively Coupled Plasma. Alphabetical
list with the lines of each element listed
in order of decreasing In/I, ratio 14
B. Prominent Lines of the Elements Emitted by
the Inductively Coupled Plasma in Order of
Wavelength 39
VII
-------
FIGURES
Number
Signal-to-background ratios (In/Ib) of spectral
lines can be read directly from log-scaled
intensities with appropriately numbered scales.
The scales in this figure are superimposed on a
portion of the Zn spectrum. Please see text for
an explanation of the scales ,
Comparison of detection limits calculated in
the conventional manner (analyte concentration
equivalent to three times the standard
deviation of 1^) with those calculated from
the assumption that the standard deviation
of I|j can be approximated by 0.01 1
TABLES
Number Pag<
I Comparison of relative intensities of spectral
lines of Mg obtained from arc, spark, and
inductively coupled plasma excitation sources.
The relative intensities have all been normalized
with respect to those of the Mg I 383.83 nm
line 2
II Experimental facilities and operating conditions... 5
vzn
-------
LIST OF ABBREVIATIONS AND SYMBOLS
AES
AMPS
C
DL
*b
ICP
Xg
In
L/min
m
mg/L
mL/min
mm
run
W
atomic emission spectroscopy
amperes
concentration
detection limit
background intensity
inductively coupled plasma
gross intensity
net intensity
liters per minute
meter
milligram per liter
milliliter per minute
millimeter
nanometer
watt
ACKNOWLEDGMENT
The authors gratefully acknowledge the help of M. A. Floyd
in the computer listing of the spectral lines and the related
numerical data.
IX
-------
SECTION 1
INTRODUCTION
A comprehensive listing of spectral lines with appropriate
intensity information is an invaluable aid in the development
of spectroscopic analytical methods. The existing wavelength
tables (1-6) have been excellent sources for the identification
of spectral lines and for interpretation of spectra in arc,
spark and flame atomic spectroscopy. For many elements, the
relative intensities exhibited by the spectra excited in the
inductively coupled plasma (ICP) do not correspond to the
information available in the published wavelength tables. A
typical example is shown in Table I. These data show that the
Mg II line intensities are much stronger, relative to the Mg I
line intensities, in the ICP than in arc and spark excitation
sources. Because of these relative intensity disparities, an
atlas of the spectra of all elements as observed in the emissions
from ICPs would serve as a useful guide in the selection of
analytical lines for ICP-atomic emission spectroscopy (AES).
As an initial step in the preparation of such an atlas, we have
recorded the ICP emission spectra of some 70 elements over a
wavelength range of '^320 nm that covers the prominent lines.
Publication of an atlas of these recordings is the eventual
goal, but in view of the rapid anticipated growth of ICP-atomic
emission spectroscopy to new analytical problems (7), the rapid
publication of a definitive list of the prominent lines compiled
from these records is highly desirable. We use the term
prominent* line because we have chosen to express the line
strengths in terms of net signal-to-background ratios and
estimated detection limits. For analytical purposes these
quantities are far more useful than relative intensities.
Also the use of net signal-to-background ratios eliminates
the need for consideration of photomultiplier sensitivity and
grating efficiency as functions of wavelength. When possible,
ten or more of the prominent lines of each element are listed.
Some elements, e.g. boron and carbon, emit fewer than ten
lines of measurable intensity in the ICP under the operating
conditions used in this study.
* Prominent denotes "standing out so as to be easily seen,"
standing out beyond the adjacent surface or line" (8).
-------
Table I. Comparison of relative intensities of spectral lines
of Mg obtained from arc, spark, and inductively
coupled plasma excitation sources. The relative
intensities have all been normalized with respect
to those of the Mg I 383.83 nm line.
lonization State and Wavelengths (nm)
NBS (1) Cu-arc
MIT (2) arc
MIT (2) spark
AL* ICP
(II) 279.55
2
0.5
1.5
80
(II) 280.27
1.2
0.5
1.5
42
(I) 285.21
12
1
0.5
8
(I) 383.83
1
1
1
1
*Ames Laboratory
-------
SECTION 2
CONCLUSIONS AND RECOMMENDATIONS
Relative intensities of spectral lines excited in the
ICP may differ considerably from those obtained from other types
of excitation sources.
Trace element analytical capabilities of spectral lines
can be compared rapidly and in a simple manner from signal/
background ratios which may be read directly from wavelength
scans made with a logarithmic intensity scale.
A comprehensive listing of observed spectral line
interferences would be a useful complement to the prominent
line information listed in this report.
-------
SECTION 3
EXPERIMENTAL FACILITIES AND PROCEDURES
The experimental facilities and operating conditions are
shown in Table II. The wavelength scans for all elements were
obtained under a single set of operating conditions. The
information generated from these scans is therefore applicable
to simultaneous multielement ICP methods.
A four decade recording range, made possible by a
logarithmic current/voltage converter, allowed the intensity
from the full 189-516 nm range (189-590 nm for sodium) to be
recorded without changes in recorder or amplifier settings,
thus considerably simplifying the collection of the data and
its interpretation. For example, the logarithmic intensity
scale allows a simple method to be used for the estimation of
detection limits directly from the wavelength recordings.
On a logarithmic scale the separation of two
values corresponds to the log of the ratio of the
values rather than the absolute difference as would
be indicated on a linear scale. The difference,
therefore, between a peak intensity (gross intensity
Ip-) and its background intensity Ib on a log scale
may be written:
log Ig - log Ib = log jf- (1)
r*^> *^ JL, r^
The gross intensity ! is the sum of Ib and the net
analyte intensity In, therefore Equation 1 may be
rewritten:
log I - log Ib = log
= log
In + Ib
nT. b (2)
4- 1
(3)
Now, if a log scale (scaled the same as the recording
scale) is laid beside a spectral line, with unity
corresponding to the background level, the antilog
values on the scale will correspond to the quantity
(I /Ib + 1) as shown at the left of the Zn 213.86 nm
-------
Table II. Experimental facilities and operating conditions.
Mono chromator
Jarrell-Ash Model No. 78-466
1 m focal length; 1180 grooves/
mm grating; blazed for 250 nm;
20 micrometer entrance and
exit slits
Plasma
HF generator
power
plasma Ar flowrate*
auxiliary plasma Ar
flowrate*
vertical observation zone
Plasma-Therm
Model HFS-2500D
1100 W
20 L/min
flow is turned off for normal
operation, ^1 L/min is used
for starting plasma
12-18 mm above load coil
Nebulizer
sample uptake rate
aerosol carrier Ar
flowrate*
Pneumatic cross-flow type
1.9 mL/min
1 L/min
Data acquisition system
Logarithmic
current/voltage
converter to
Hewlett-Packard
7001AM X-Y recorder
* Nomenclature for the ICP gas flows has been defined in
references 9 and 10.
peak in Figure 1. The In/lb ratio can be read
directly if the antilog values on the log scale are
adjusted by the factor of one as shown at the right
of the Zn 213.86 nm peak in Figure 1. With such a
"reading scale", the In/Ib ratio can be read directly
and rapidly for any spectral line on the recording.
The detection limit (DL), in its conventional sense, is
defined as the analyte concentration required to yield a net
signal equivalent to three times the standard deviation of the
background beneath the spectral line (11). Under normal
operating conditions, with all components in the signal
processing system operating properly, the uncertainty (standard
deviation) in the spectral background usually lies within the
range of 0.3 - 1.070 of the background signal level. This agrees
-------
ICT6-j
CO
CL
LU
a:
o:
o
o
h-
o
X
Q_
10
ID
CVJ
O
CVJ
O
CM
to
O
CJ
iO
-9
({M
i~*rV\
d(JU =
100 =
RH
«JvJ
on
£U
IO -
?
£.
!
«-r TTii w»
1
Uo
00
2
CVJ
1
1
In
'b
1QQ
= iyy
p.99
-49
IQ
\;y
- 9
1
1
0 J
Figure 1. Signal-to-background ratios (In/Ib) of spectral lines
can be read directly from log-scaled intensities with
appropriately numbered scales. The scales in this
figure are superimposed on a portion of the Zn
spectrum. Please see text for an explanation of the
scales.
-------
essentially with the findings of Boumans and DeBoer (10,12), and
for our polychromator system (13) applies generally to all
analytical lines regardless of wavelength. Therefore, the
standard deviation of the background can be approximated by
0.01 Ib and the detection limits can be estimated from
DL % - (4)
in
* °-93 C (5)
*' ()
in which C is the analyte concentration which yielded I
The analyte concentrations used for the wavelength scans were
chosen so that the maximum In/Ib ratio for each element fell
within the approximate range of 20-200. The In/Ib ratios of the
most prominent lines of each element were measured with the log
scale described above. These ratios, the elemental concentra-
tions, and the appropriate spectral line information were
transferred to computer memory from which the information was
retrieved alphabetically by element and serially in order of
wavelength. The estimated detection limits were computed from
Equation 5 and were printed with the alphabetical and serial
line listings.
-------
SECTION 4
RESULTS AND DISCUSSION
The prominent lines for each element are listed in
Appendix A alphabetically by element and in order of decreasing
In/1]-) ratio for each element group. These same spectral lines
are listed in order of wavelength in Appendix B. Information on
all lines of argon and hydrogen which appeared in the background
and elemental scans with measurable In/Ib ratios is also
included in the tables.
Because the detection limits listed in Appendices A and B
were estimated from In/Ib ratios, an inquiry is appropirate into
how these detection limits compare with those obtained in the
conventional manner (11) . The comparison provided in Figure 2
shows that the two methods agree moderately well, especially
when the uncertainties in the detection limits determined by
either method are considered. Detection limits are inherently
rather imprecise numbers.
The data in Figure 2 suggests that the In/lb based
detection limits are conservative estimates. The scatter of the
points would not change but the correlation of the two methods
would be closer to 1:1 if 0.7% rather than 1.0% had been used
for the estimated relative standard deviation of the background
signals. The significance of the comparison of detection limits
is, however, that the trace element analytical capabilities of
spectral lines can be compared rapidly and in a simple manner,
as described in this paper, from wavelength scans made with a
logarithmic intensity scale.
Our emphasis on line strength, line-to-background ratios,
and detection limits is that these criteria are primary figures
of merit for trace and ultratrace analytical applications. Once
the sensitive lines are identified, then other important criteria
must be considered. These criteria include: 1) freedom from
spectral line interferences arising from sample concomitants or
from the supporting atmosphere of the discharge, 2) linearity of
response of the spectral lines with concentrations, 3) low stray
light contributions at the analytical line wavelengths, and 4)
spatial accessibility in polychromators. With reference to the
latter, the wavelength distribution of the lines listed in
Appendices A and B confirm our earlier findings that many of the
prominent lines emitted in the ICP are located in the region
8
-------
O.I
o>
a.
en
to
<
CD
z
UJ
o
co
I
o
UJ
UJ
o
0.01 -
0001 -
00001-
00001 0.001 0.01
DETECTION LIMITS, In/lb BASIS
Figure 2. Comparison of detection limits calculated in the
conventional manner (analyte concentration equivalent
to three times the standard deviation of 1^) with
those calculated from the assumption that the
standard deviation of Iv can be approximated by
0.01 Ib.
-------
near 200 nm. For example, 35% of all the metallic and metalloid
element lines in Appendices A and B are located below 250 nm.
If only the line of highest In/Ib is considered for each element
then approximately 45% occur in the region below 250 nm. This
high number density of potentially useful analytical lines in
the low wavelength region may therefore present problems in the
selection of lines for polychromator systems. The problem
arises because each analytical wavelength requires a fixed
space for the slit assembly, mirror, and photomultiplier.
Compromises have to be made when two desired analytical
wavelengths compete for the same component space. Because most
elements possess alternative lines with approximately equivalent
detection limits, these compromises can usually be accommodated
without serious loss of powers of detection.
10
-------
REFERENCES
1. W. F. Meggers, C. H. Corliss, and B. F. Scribner. Tables
of Spectral-Line Intensities, Part IArranged by Elements.
NBS Monograph 145, U.S. Department of Commerce, 1975.
2. Massachusetts Institute of Technology Wavelength Tables.
The MIT Press, Cambridge, Massachusetts, 1969.
3. A. N. Zaidel;, V. K. Prokof'ev, S. M. Raiskii, V. A.
Slavnyi, and E. Ya. Shreider. Tables of Spectral Lines.
3rd Ed. Plenum Press, 1970.
4. R. L. Kelly and L. J. Palumbo. Atomic and Ionic Emission
Lines Below 2000 Angstroms--Hydrogen Through Krypton.
NRL Report 7599, Naval Research Laboratory, Washington,
DC, 1973.
5. R. L. Kelly. A table of emission lines in the vacuum
ultraviolet for all elements (6 angstroms to 2000 angstroms).
UCRL 5612, University of California Lawrence Radiation
Laboratory, Livermore, California, 1959.
6. M. L. Parsons, B. W. Smith, and G. E. Bentley. Handbook
of Flame Spectroscopy. Plenum Press, New York, 1975.
7. Elemental Analysis: Plasmas Revive Emission Spectroscopy.
Science, 199, 1324 (1978).
8. The Random House Dictionary of the English Language, The
Unabridged Edition. Random House, New York, 1966.
9. A. Montaser and V. A. Fassel. Anal. Chem., 48, 1490 (1978).
10. P. W. J. M. Boumans and F. J. DeBoer. Spectrochim. Acta,
32B, 365 (1977).
11. H. Kaiser. Anal. Chem., 42, 26A (1970).
12. P. W. J. M. Boumans and F. J. DeBoer. Spectrochim. Acta,
30B. 309 (1975).
13. R. K. Winge, V. A. Fassel, R. N. Kniseley, E. DeKalb, and
W. J. Haas, Jr. Spectrochim. Acta, 32B, 327 (1977).
11
-------
PREFACE TO APPENDICES A AND B,
EXPLANATION OF SYMBOLS AND ABBREVIATIONS
S of I
CONG
EST'D DET LIM
NM
COMMENTS
NR
State of lonization. The symbols I, 'II, and III
indicate that the spectral lines originate
respectively from the neutral atom, single
ionized and doubly ionized states.
Ratio of net analyte intensity to background
intensity.
Concentration of the single element analyte
solution used for the wavelength scans from
which the prominent lines were determined.
Estimated Detection Limit. Detection limits
estimated from the In/Ib ratios as explained
in this paper.
Not Measurable because of interfering line
listed in COMMENTS column.
All wavelengths listed in Appendices A and B
were taken from the NBS tables (1) unless
otherwise designated in the comments column.
Either air or vacuum wavelengths are listed
depending on the source.
Air Wavelengths
NBS (1)
MIT (2)
Zaidel, 200 nm
and above (3)
Vacuum Wavelengths
NRL (4)
UCRL (5)
Zaidel, below
200 nm (3)
Not Resolved. This description indicates
components of an unresolved pair of lines.
For convenience in the computer listing of the
data, In/Ib, CONG, and EST'D DET LIM values are
listed for each wavelength although only a
single In/It> measurement was obtained from each
unresolved pair.
12
-------
GROUP NR This description indicates components of an
unresolved group (3 or more lines). Only the
wavelength of the strongest line (NBS tables
(1)) is listed.
APPROX WAVE Approximate Wavelength. This description
applies to spectral lines (Os, Pt) which have
not been positively identified as belonging to
the elemental scans in which they were found.
These approximate wavelengths may be previously
unreported lines of Os and Pt or they may be
due to impurities. The impurities, if present,
have not been positively identified.
Additional remarks
Significant figures. Although the number of digits shown
in the EST'D DET LIM column may be greater than the precision
of the determination justifies, no convenient means of limiting
the number of significant digits in the computer printout was
available. Normally, only one significant figure is appropriate
for detection limit data (11).
Interferences. The comments column includes interference
information when a component of the background spectrum overlaps
an analyte line (e.g., the Dy 396.839 nm line is located on
the broad H 397.007 nm line) or when an analyte line is located
in a complex molecular band system (e.g., the OH 306.36 nm
system) where band components may cause spectral interferences.
The notation of molecular bands does not preclude the use of
analyte wavelengths within the band region; e.g. with our
experimental facilities the Al 308.22, Be 313.04, Ca 315.89 and
Cu 324.75 nm lines are analytically useful even though they are
located in the OH band region.
Argon lines. Most of the argon lines above 475 nm in
Appendices A and B exhibit considerable broadening which may be
due to broadened upper energy levels of the associated transi-
tions. The upper energy levels of these broad lines lie near
the ionization energy of the argon atom.
13
-------
APPENDIX A
Prominent Lines of the Elements Emitted
by the Inductively Coupled Plasma
Alphabetical list with the lines of each
element listed in order of decreasing In/Ib ratio
Ag
Ag
Ag
Ag
Ag
Ag
Ag
Ay
Ag
s
OF
I
I
T
II
II
II
II
II
II
II
WAVE-
LENGTH
(nm)
328.
338.
243.
224.
241.
211.
232.
224.
233.
I
n
T
CONC
(mg/L)
EST'D
DET LIM
b (mg/L)
068
239
779
641
318
383
505
874
137
38.
23.
2.
2.
1.
0.
0.
0.
0.
0
0
5
3
5
9
7
6
5
10.
10.
10.
10.
10.
10.
10.
10.
10.
0
0
0
0
0
0
0
0
0
0.
0.
0.
0.
0.
0.
0.
0.
0.
007
013
120
130
200
333
428
500
600
COMMENTS
Zaidel
Zaidel
Zaidel
Zaidel
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
I
I
I
I
I
I
I
I
I
I
I
I
I
309. 271
309.284
396. 152
237. 335
237. 312
226. 922
226.910
308.215
394.401
236, 705
226. 346
221.006
257.510
13.0
13.0
10. 5
10.0
10.0
9.0
9.0
6.6
6.3
5.8
5.0
4.8
4.0
10.0
10.0
10.0
10. 0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
0.023
0.023
0.028
0.030
0.030
0.033
0.033
0.045
0.047
0.051
0.060
0.062
0.075
OH Band
OH Band
NE
NR
NE
NE
OH Band
Zaidel
Zaidel
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
T
j_
I
I
I
I
I
I
I
I
i
I
I
I
I
X
415.859
419.832
420.068
425. 936
427.217
430.010
433. 356
560.673
555. 870
426.629
419. 103
419.071
404. 442
549.587
418. 188
>50.0
50.0
50.0
50.0
43.0
40.0
38.0
36.0
33.0
32.0
32.0
32.0
31.0
31.0
28. 0
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel,NR
Zaidel,NF
Zaidel
Zaidel
Zaidel
14
-------
Appendix A cont'd
S WAVE- In CONG EST'D COMMENTS
OF LENGTH (mg/L) DET LIM
I (nm) Xb (mg/L)
Ar I 394.898 27.0 Zaidel
Ar I 588,859 25.0 Zaidel
Ar I 518.775 24.0 Zaidel
Ar I 451.074 21.0 Zaidel
Ar I 565.070 21.0 Zaidel
Ar I 557.255 21.0 Zaidel
Ar I 591.200 19.0 Zaidel
Ar I 355.431 18.0 Zaidel
Ar I 516.228 18.0 Zaidel
Ar I 416.418 17,0 Zaidel
Ar I 545.165 15.0 Zaidel
Ar I 573.952 15.0 Zaidel
Ar I 433.534 11.0 Zaidel
Ar I 592.881 10.0 Zaidel
Ar I 434.517 9.0 Zaidel
Ar I 522.127 9.0 Zaidel
Ar I 360.652 8.7 Zaidel
Ar I 356.766 8.6 Zaidel
Ar I 394.750 8.0 Zaidel
Ar I 425.119 7.5 Zaidel
Ar I 470.232 7,2 Zaidel
Ar I 588.263 7,1 Zaidel
Ar I 364.983 7,0 Zaidel
Ar I 542.135 6.6 Zaidel
Ar I 452.232 6.2 Zaidel
Ar I 533.426 6.0 Zaidel
Ar I 383.468 6.0 Zaidel
Ar I 515.140 6.0 Zaidel
Ar I 550.611 6.0 Zaidel
Ar I 459.610 6.0 Zaidel
Ar I 552.496 5.0 Zaidel
Ar 1 555.962 4.9 Zaidel
Ar I 586.032 4.3 Zaidel
Ar I 462.844 4.0 Zaidel
Ar I 577.212 4.0 Zaidel
Ar I 363.446 3.9 Zaidel
Ar I 559.748 3,9 Zaidel
Ar I 525.279 3.8 Zaidel
Ar I 339.375 3.6 Zaidel
Ar I 558.872 3,5 Zaidel
Ar I 363.268 3.5 Zaidel
Ar I 346.108 3.5 Zaidel
Ar I 356.329 3.2 Zaidel
Ar I 487.626 3.2 Zaidel
Ar I 488.795 3.2 Zaidel
Ar 436.836 3,2 HIT
15
-------
Appendix A cont'd.
Ar
Ar
AT
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
AE
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
S
OF
I
I
I
I
I
I
I
I
I
I
I
I
I
I
T
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
WAVE-
LENGTH
(nm)
525.148
331. 935
545.742
580. 208
568. 190
511. 820
506.008
594. 267
504. 881
544. 222
404.597
565. 913
367.067
357.229
547. 346
543.999
356. 434
369. ,090
377. 037
350. 649
568.964
568.991
517. 754
339.278
337.348
355. 601
505. 418
564.866
340.618
405. 453
364.312
489.469
541.047
561. 797
365.953
389.466
317.296
537. 349
378.136
367. 524
332.550
389.986
436.379
562.089
564. 134
475.294
I
n
T
Lb
3.2
3. 1
2.8
2.8
2.8
2.8
2.7
2.7
2.6
2.5
2. 5
2.4
2.4
2.3
2.3
2.2
2. 1
2.0
2.0
2.0
2.0
2.0
1.9
1.8
1.8
1.7
1.7
1.7
1.6
1.5
1.5
1.5
1.4
1. 4
1.4
1.4
1.4
1.4
1.3
1. 1
1.1
1.0
1.0
1.0
1.0
1.0
CONG EST'D COMMENTS
(mg/L) DET LIM
(mg/L.)
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
OH Baad, Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
16
-------
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
S
OF
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
WAVE-
LENGTH
(nm)
476. 867
560. 108
563.558
349.327
558. 183
320.039
528. 608
495.675
323. 449
553.445
570. 086
325.758
539. 397
483.669
507. 308
508. 709
521. 049
531.773
553.911
503.203
524. 110
512.780
442.399
562. 378
521,477
534, 741
498.995
458. 929
I
n
Ib
0. 9
0.9
0.9
0.9
0. 8
0.8
0.8
0.8
0.8
0.7
0.7
0.7
0.7
0.6
0.6
0.6
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.4
0.3
0. 3
0.2
0. 2
CONG
(mg/L)
EST'D
DET LIM
(mg/L)
Appendix A cont'd.
COMMENTS
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
OH Band,Zaidel
Zaidel
Zaidel
OH Band,Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
As
AS
As
As
AS
As
As
AS
As
As
I
I
I
I
I
I
I
I
I
I
193,696
197.197
228.812
200.334
189.042
234.984
198,970
200.919
278.022
199.048
56.0
39.0
36. 0
25.0
22.0
21.0
16.0
6. 1
5.7
5.5
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
0,053
0.076
0,083
0.120
0,136
0.142
0,187
0.491
0.526
0,545
NEL
Au I 242.795
Au I 267.595
Au I 197.819
Au II 208,209
170.0
96.0
77.0
70.0
100.0
100.0
100.0
100.0
0.017
0.031
0.038
0.042
Zaidel
Zaidel
17
-------
Appendix A cont'd.
S WAVE-
OF LENGTH
Au
Au
Au
HU
Au
Au
B
B
B
B
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Ba
Be
Be
3e
Be
Be
le
Be
Be
Be
Be
Bi
Bi
Bi
Bi
Bi
3i
Bi
Bi
I
I
II
I
II
II
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
I
II
I
I
I
.1
I
I
I
I
T
I
I
I
I
II
I
(nm)
201.
211.
191.
200.
198.
195.
249.
2U9.
208.
208.
455.
493.
233.
230.
413.
234.
389.
489.
225.
452.
313.
234.
313.
249.
265.
217.
217.
332.
205.
205.
223.
306.
222.
206.
195.
227.
190.
213.
200
068
893
081
963
193
773
678
959
893
403
409
527
424
066
758
178
997
473
493
042
861
107
473
045
510
499
134
590
601
061
772
825
170
389
658
241
363
n
54.0
47.0
35.0
32.0
20.0
18.0
63.0
53.0
30.0
25.0
230,0
130.0
75.0
73.0
9.1
7.8
5.2
3. 7
2.0
1.9
110.0
96.0
41.0
8. 0
6.4
2.5
2.5
1.4
0.7
0.7
87.0
40.0
36.0
35. 0
14.0
12.0
10.0
10.0
CONG
(mg/L)
100.0
100.0
100.0
100.0
100.0
100.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
1.0
1,0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
EST'D
DET LIM
(mg/L)
0.055
0.063
0.085
0.093
0. 150
0.166
0.0048
0.0057
0.010
0.012
0.0013
0.0023
0.0040
0.0041
0.032
0.038
0.057
0.081
0.150
0.157
0.00027
0.00031
0.00073
0.0038
0.0047
0.012
0.012
0.021
0.042
0.042
0.034
0.075
0.083
0.085
0.214
0.250
0.300
0.300
"COMMENTS
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
H 388.905
Zaidel
OH Band
OH Band
Group NR
Group NB
NB
NR
Group NB
Zaidel, NB
Zaidel, NB
OH Baud
Zaidel
18
-------
Appendix A cont'd.
Bi
Bi
C
C
C
Ca
Ca
Ca
Ca
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Cd
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Ce
Co
Co
Co
Co
Co
Co
S
OF
I
I
I
I
I
I
II
II
II
I
II
I
II
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
WAVE-
LENGTH
(ran)
289.
211.
193.
247.
199.
393.
396.
317.
422.
214.
228.
226.
361.
326,
346.
231.
479.
413.
413.
418.
393.
446.
394.
429.
407.
407.
456.
404.
380,
401.
238.
228.
237.
230.
236.
231.
798
026
091
856
362
366
847
933
673
438
802
502
051
106
620
284
992
765
380
660
109
021
275
667
585
571
236
076
152
239
892
616
862
786
379
160
I
n
Zb
9.0
7.8
67.0
17.0
3.4
89,0
30.0
1,5
1.5
120.0
110.0
89.0
1.3
0.9
0.7
0.5
0.5
6.2
6.0
5.7
5. 0
4.8
4.4
4.3
4.2
4.2
4. 1
4.0
4.0
4.0
50.0
43.0
31.0
31.0
27.0
23.0
CONC
(mg/L)
100.0
100.0
100.0
100.0
1000,0
0.5
0.5
0.5
0.5
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10,0
10.0
10,0
10.0
10.0
10.0
10,0
10.0
10.0
10.0
10.0
EST'D COMMENTS
DET LIM
(mg/L)
0.333
0.384
0.044 NEL
0. 176
8.823 NEL
0.00019
0.00050 H 397.007
0.010 OH Band
0.010
0.0025
0.0027
0.0034
0.230
0.333
0.428
0.600
0.600
0.048
0.050
0.052
0.060
0.062
0.068
0.069
0.071 NE
0.071 NE
0.073
0.075
0.075
0.075
0.0060
0.0070
0.0097
0.0097
0.011
0.013
19
-------
S WAVE-
OF LENGTH
Co
Co
Co
Co
Co
Co
Co
cr
cr
cr
Cr
cr
Cr
cr
cr
Cr
cr
cr
cr
Cr
Cr
Cr
Cs
Cs
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Cu
Dy
Dy
Dy
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
II
I
I
II
I
I
II
II
I
I
II
II
II
(nm)
238.
231.
235.
238.
234.
231.
234.
205.
206.
267.
283.
284.
206.
276.
284.
285.
276.
286.
266.
286.
286.
357.
452.
455,
324.
224.
219.
327.
213.
223.
222.
221.
219-
217.
221.
353.
364.
340.
346
405
342
636
426
498
739
552
149
716
563
325
542
654
984
568
259
257
602
511
674
869
673
531
754
700
958
396
598
008
778
810
226
894
458
170
540
780
Appendix A cont'd.
COMMENTS
49
42
42
42
35
31
22
21
16
15
15
14
14
13.0
13.0
56,
39,
31,
31.
25,
23.
19,
17,
17,
17,
0.7
0.3
13.0
30.0
13.0
11.0
10,
10.
10.
10,
10,
10,
10,
10,
10.
10,
10,
10.
10,
10.0
10.0
0061
0071
0071
0071
0086
0097
013
014
018
0.020
0.020
0.021
0.021
0.023
0.023
1000.0 42.857
1000.0 100.000
10.
10.
10,
10,
10.
10.
10,
10.
10.
10,
0,
0.
0,
0.
0,
0,
0,
0,
0,
0,
0054
0077
0097
0097
012
013
015
017
017
017
10.0 0.023
10.0 0.010
10.0 0.023
10.0 0.027
Zaidel
OH Band
Zaidel
20
-------
S WAVE-
OF LENGTH
Dy
Dy
Dy
Dy
oy
Dy
Dy
Dy
Dy
Dy
By
Dy
I
II
II
II
II
II
II
II
II
II
II
II
II
(nm)
353.
394.
396.
338.
400.
387.
407.
352.
353.
357.
389.
238.
602
468
839
502
045
211
796
398
862
624
853
736
n
T
CONC
(mg/L)
Jb
10.
9.
9.
9.
8.
8.
7.
7.
6.
6.
6.
5.
0
5
5
0
4
2
5
4
6
4
0
8
10
10
10
10
10
10
10
10
10
10
10
10
*
*
*
«
*
*
0
0
0
0
0
0
0
0
0
0
0
0
EST'D
DET LIM
(mg/L)
0
0
0
0
0
0
0
0
0
0
0
0
*
*
*
*
*
*
*
*
030
031
031
033
035
036
040
040
045
046
050
051
Appendix A cont'd.
COMMENTS
Ca 396.847,H 397,007
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
Er
II
II
II
II
II
II
II
II
II
II
II
II
337.
349.
323.
326.
369.
390.
291.
296.
331.
339.
338.
389.
271
910
058
478
265
631
036
452
242
200
508
623
2
1
1
1
1
1
1
1
1
9.
7.
6.
6,
6,
4.
1.
1.
0.
9.
8.
7.
0
0
0
0
0
0
0
0
0
4
8
0
10
10
10
10
10
10
10
10
10
10
10
10
»
*
*
*
*
*
*
*
*
*
0
0
0
0
0
0
0
0
0
0
0
0
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
010
017
018
018
018
021
027
027
030
031
034
042
OH Band
H 388.905
Eu
EU
EU
Eu
Eu
Eu
EU
Eu
EU
EU
II
II
II
II
II
II
II
II
II
II
381
412
420
393
390
272
372
397
443
281
*
*
*
*
*
*
»
967
970
505
048
710
778
494
196
556
394
110.
70.
70.
53.
39.
37.
34.
32.
24.
22.
0
0
0
0
0
0
0
0
0
0
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
*
»
*
*
»
*
*
0027
0043
0043
0057
0077
0081
0088
0094
012
013
H 397.007
Fe II 238.204
Fe II 239.562
Fe II 259.940
Fe II 234. 349
Fe II 240.488
Fe II 259.837
65.0
59.0
48.0
29.0
27.0
24.0
10.0
10.0
10.0
10.0
10.0
10.0
0.0046
0.0051
0.0062
0.010
0.011
0.012
21
-------
Appendix A cont'd.
S WAVE-
OF LENGTH
?e
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
Fe
I
II
II
II
II
II
II
II
II
II
II
II
(nm)
261.
234.
234.
258.
238.
263.
263.
274.
275.
233.
273.
187
310
830
586
863
105
132
932
574
280
955
n
T
CONC
(mg/L)
*b
24
23
23
20
20
19
19
19
16
15
15
*
*
*
*
*
*
«
«
0
0
0
0
0
0
0
0
0
0
0
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
0
0
0
0
0
0
0
0
0
0
0
EST'D COM
DET LIM
(mg/L)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
012
013
013
015
015
015
015
015
018
020
020
N8
NR
NE
NR
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
Ga
I
I
I
I
I
I
I
I
I
I
294.364
417. 206
287.424
403. 298
250.070
209.050
245. 007
294. 418
271.965
233. 826
265.987
64.0
45.0
38.0
27.0
16.0
11.0
10.0
9.4
5.7
3.9
3.6
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
0.046
0.066
0.078
0. 111
0.187
0.272
0.300
0.319
0.526
0.769
0.833
MIT
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
Gd
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
342
336
335
335
310
376
303
343
358
364
301
354
354
308
303
*
*
*
247
223
047
862
050
839
284
999
496
619
013
580
936
199
405
2
1
1
1
1
1
1
1
1
1
1
1.
5.
4.
4.
3.
2.
1.
0.
0.
0.
0.
9.
9.
9.
8.
0
0
0
0
0
0
0
0
0
0
0
5
0
0
8
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
014
020
021
021
023
025
027
030
030
030
030
031
033
033
034
OH Band
OH Band
Ge
Ge
Ge
I
I
I
209. 426
265. 118
206. 866
75.0
62.0
50.0
100.0
100.0
100.0
0.040
0.048
0.060
22
-------
Appendix A cont'd.
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
Ge
S
OF
I
I
I
I
I
I
I
I
I
I
WAVE-
LENGTH
(nm)
219.871
265. 158
204.377
199. 824
204.171
259. 254
303.906
275. 459
270.963
I
n
T
Xb
47.0
36.0
35.0
34.0
34.0
29.0
29.0
28.0
27.0
CONG
(mg/L)
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
EST'D
DET LIM
(mg/L)
0.063
0.083
0.085
0.088
0.088
0.103
0.103
0. 107
0.111
COMMENTS
H
H
H
H
H
H
H
I
I
I
I
I
I
I
486. 133
434.047
410.174
397.007
388.905
383. 539
379.790
17.0
5.0
1.5
0.6
0.3
0. 1
0.1
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
Hf
II
II
II
II
II
II
II
II
II
II
II
II
II
II
277
273
264
232
263
282
251
251
257
196
239
239
235
246
*
*
*
*
*
*
«
*
*
336
876
141
247
871
022
269
303
167
382
336
383
122
419
190.
180.
160.
160.
160.
160.
150.
150.
150.
150.
140.
140.
130.
130.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
100
100
100
100
100
100
100
100
100
100
100
100
100
100
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
015
016
018
018
018
018
020
020
020
020
021
021
023
023
KR
NR
Zd
Hg
Hg
Hg
Hg
Hg
Hg
Hg
II
I
I
I
I
I
I
194
253
296
435
265
302
365
*
*
*
*
*
*
.
227
652
728
835
204
150
483
120.
49.
1.
1.
0.
0.
0.
0
0
7
1
7
6
3
100
100
100
100
100
100
100
*
*
*
*
*
*
0
0
0
0
0
0
0
0.
0.
1.
2.
4.
5.
10
025
061
764
727
285
000
.000
Zaidel
Zaidel
Ho II 345.600
53. 0
10.0 0.0057
23
-------
Appendix A cont'd,
S WAVE-
OF LENGTH
Ho
:iO
Ho
Ho
Ho
Ho
Ho
Ho
Ho
I
II
II
II
II
II
II
II
II
II
n
T
CONG
(mg/L)
(nm) b
339.
389.
347.
341.
381.
348.
379.
351.
345.
898
102
426
646
073
484
675
559
314
2
1
1
1
1
1
1
1
1
3.
8.
6.
6.
5.
5.
2.
1.
0.
0
0
0
0
0
0
0
0
0
1
1
0.
0.
10.
1
1
1
1
1
1
0.
0.
0.
0.
0.
0.
0
0
0
0
0
0
0
0
0
EST'D
DET LIM
(mg/L)
0.
0.
0.
0.
0.
0.
0.
0.
0.
013
016
018
018
020
020
025
027
030
COMMENTS
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
Ir
II
II
I
II
I
I
II
I
I
I
II
I
I
I
I
I
I
224.
212.
205.
215.
204.
209.
208.
236.
254.
215.
263.
216.
266.
237.
238.
250.
269.
28-4.
268
681
222
268
419
263
882
804
397
805
971
942
479
277
162
298
423
972
110.
100.
49.
44.
30.
28.
28.
24.
19.
17.
17.
13.
13.
12.
12.
12.
11.
10.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
*
*
*
*
*
*
*
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
*
.
*
*
*
*
*
*
«
*
«
»
*
027
030
061
068
100
107
107
125
157
176
176
230
230
250
250
250
272
300
404.721 0.7 1000.0 42.857
24
H 388.905
H 379.790
In
In
In
In
In
In
In
In
In
In
In
In
II
I
I
I
I
I
I
II
I
I
II
I
230. 606
325. 609
303.936
451. 131
410. 176
271.026
325. 856
207. 926
256.015
293. 263
197.745
275. 388
47.0
25.0
20.0
16.0
6.4
5.4
5.0
4.2
4.2
2.0
1.7
1.6
100.0
100,0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
0.063
0. 120
0.150
0.187
0.468 H 410.174
0.555
0.600
0.714 Zaidel
0.714
1.500
1.764 Zaidel
1.875
Zaidel
-------
S WAVE-
OF LENGTH
K
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
La
Li
Li
Li
Li
Li
Li
Li
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
Lu
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
(nm)
404
333
379
408
412
398
379
399
407
387
375
404
403
338
442
384
392
492
492
394
460
323
274
497
256
413
413
261
291
219
307
289
339
350
270
290
275
302
347
.414
.749
.478
.672
. 323
. 852
. 083
.575
.735
. 164
. 908
. 291
. 169
.091
.990
.902
.922
.098
.179
.910
. 286
.263
. 118
.170
.254
.262
.256
.542
. 139
.554
.760
. 484
.707
.739
. 171
.030
.417
.054
. 248
n
0.0
30.0
30.0
30.0
29.0
27.0
26,0
22.0
21,0
20.0
20.0
19,0
19.0
17.0
13.0
12.0
12.0
12,0
12.0
NM
3.5
2.8
1.9
1.4
0.7
0.4
0.4
150.0
24.0
18.0
17.0
15. 0
14.0
13.0
12. 0
12.0
12.0
11.0
10.0
CONC
(mg/L)
1 nnn n
1 U U U U
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
EST'D
DET LIM
(mg/L)
0.010
0.010
0.010
0.010
0.011
0.011
0.013
0.014
0.015
0.015
0.015
0.015
0.017
0.023
0.025
0.025
0.025
0.025
««"«»
0.857
1.071
1.578
2. 142
4.285
7.500
7.500
0.0010
0.0062
0.0083
0.0088
0.010
0.010
0.011
0.012
0.012
0.012
0.013
0.015
Appendix A cont'd.
COMMENTS
Ar 404.442
Ar 394.898
OH Band
Zaidel
Zaidel,SR
Zaidel,NE
OH Band
25
-------
S WAVE-
OF LENGTH
sg
Mg
Mg
Mg
Mg
Mg
Mg
Mg
Ng
Mg
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mn
Mo
Mo
Mo
Mo
Mo
MO
MO
Mo
Mo
Mo
Mo
Na
Na
Na
Na
I
II
II
I
II
I
II
I
I
I
II
II
II
II
II
II
I
II
I
I
I
II
I
II
II
II
II
II
II
II
II
II
II
II
I
I
I
I
(nm)
279.
280.
285.
279.
202.
279.
383.
383.
277.
293.
257.
259.
260.
294.
293.
279.
293.
279.
280.
403.
344.
403.
191.
202.
203.
204.
281.
201.
284.
277.
287.
268.
263.
292.
588.
589.
330.
330.
553
270
213
806
582
079
826
231
983
654
610
373
569
920
930
482
306
827
106
076
199
307
510
030
844
598
615
511
823
540
151
414
876
339
995
592
237
298
195.0
100.0
19.0
2.0
1.3
1.0
0.9
0.7
0.6
0.5
220.0
190.0.
145.0
39.0
29.0
24.0
22.0
18.0
14.0
6.8
6.6
6. 3
5.8
38,
24.
24,
21,
16.
15.
12.
11.
10.
8.
8.
Na I 285.301
101.0
43.0
1.6
0.7
1. 1
CONC
(mg/L)
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10,
10,
10,
10.
10.
10,
10,
10,
10,
10.
10,
10.
10,
10,
10.
10,
10.
10.
10.
10,
10.
10.
100,
100.
100,
100,
10.0
10,0
0
0
0
0
EST'D
DET LIM
(mg/L)
0,
0,
0,
0.
0,
0.
0,
0,
0,
00015
00030
0016
015
023
030
.033
042
050
0.060
0014
0016
0021
0077
010
012
013
016
0.021
0.044
0.045
0.047
0.051
0.0079
0.012
0.012
0.014
0.018
0.020
0.025
0,027
0.030
0.037
0.037
0,
0,
1.
4.
029
069
875
285
Appendix A cont'd.
COMMENTS
Zaidel
NEL
1000.0 27.272
Ar 588.859
Zaidel,KE
26
-------
S WAVE-
OF LENGTH
I (nm)
Na
Na
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nb
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Sd
Nd
Nd
Nd
Nd
Nd
Nd
Nd
Sd
Ni
Ni
Ni
Ni
Ni
Ni
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
II
II
285.
288.
309.
316.
313.
269.
322.
319.
295.
292.
271.
288.
210.
272.
287.
401.
430.
406.
415.
410.
386,
386.
404.
417.
385.
385.
394.
445.
424.
395.
396.
384.
384.
380.
221.
232.
231.
216,
217.
230.
281
114
418
340
079
706
548
498
088
781
662
318
942
198
539
225
358
109
608
946
333
340
080
732
166
174
151
157
738
116
312
824
852
536
647
003
604
556
467
300
I
n
T
ib
1.1
0.6
83.0
75.0
60.0
43.0
42,0
4i.o
40.0
40.0
34.0
31.0
31.0
30.0
28.0
59.0
40.0
31.0
28.0
26.0
23.0
23.0
23.0
22. 0
19.0
19.0
19.0
19.0
17.0
17.0
17. 0
16.0
16.0
16.0
29.0
20.0
19.0
17.0
13.0
CONG
(mg/L)
1000.0
1000.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100,0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
10.0
10.0
10.0
10.0
10.0
EST'D
DET LIM
(mg/L)
27.272
50.000
0.036
0.040
0.050
0.069
0.071
0,073
0.075
0.075
0.088
0.096
0.096
0.100
0,107
0.050
0.075
0.096
0.107
0.115
0.130
0.130
0.130
0.136
0.157
0,157
0.157
0.157
0.176
0. 176
0.1.76
0.137
0. 187
0. 187
0.010
0.015
0.015
0.017
0.023
Appendix A cont'd.
COMMENTS
Zaidel,NR
Zaidel
OH Band
OH Band
OH Band
OH Band
OH Band
NE
NB
NE
NR
13.0
10.0 0.023
NE
NR
Zaidel
Zaidel
MIT
MIT
27
-------
S WAVE-
OF LENGTH
Ni
Ni
Ni
Ni
Ni
Ni
os
os
Os
Os
Os
Os
OS
OS
OS
Os
p
p
p
p
p
p
p
p
p
p
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
Pb
I
II
II
I
II
I
I
II
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
T
I
I
I
I
I
I
I
(nm)
227.
225.
234.
239.
352.
341.
225.
228.
189.
233.
206.
219.
236.
207.
248.
222.
213.
214,
253.
213.
203.
215.
255.
202.
215.
253.
220.
216.
261.
283.
280.
405.
224.
368.
266.
239.
363.
247.
021
386
554
452
454
476
585
226
900
680
721
439
735
067
624
798
618
914
565
547
349
408
328
347
294
401
353
999
418
306
199
783
688
348
316
379
958
638
83.0
48,0
25.0
24.0
22. 0
18.0
16.0
14.0
13.0
11.0
39.0
39.0
11.0
8.5
7.4
7.2
5.2
3.8
3.4
3.0
70.0
33.0
23.0
21.0
19.0
11. 0
9.0
8.6
7.7
6.3
5.2
5. 1
CONG
(mg/L)
10.0
10.0
10.0
10.0
10.0
10.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
100.0
100.0
100.0
100.0
100.0
100.0
100,0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
EST'D
DET LIM
(mg/L)
0.025
0.025
0.03 1
0.038
0.045
0.048
0.00036
0.00063
0.0012
0.0012
0.0014
0.0017
0.0019
0.0021
0.0023
0.0027
0.076
0.076
0.272
0.352
0.405
0.416
0.576
0.789
0.882
1.000
0.042
0.090
0.130
0.142
0.157
0.272
0.333
0.348
0. 389
0,476
0.576
0.568
Appendix A cont'd.
COMMENTS
Zaidel
Zaidel
APP50X. WAVE
WIT
MIT
28
-------
S WAVE-
OF LENGTH
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
Pd
I
I
I
II
I
I
I
II
II
I
I
I
I
I
II
II
I
II
(rim)
340.
363.
229.
324.
360.
342.
248.
223.
244.
351.
355.
247.
348.
244.
235.
346.
236.
248.
458
470
651
270
955
124
892
159
791
694
308
642
115
618
134
077
796
653
I
n
T
CONG
(mg/L)
1b
68.
55.
44.
39.
35.
30.
29.
25.
23.
22.
22.
18.
18.
18.
17.
16.
15.
15.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
100.
100.
100.
100,
100.
100.
100.
100.
100.
100.
100.
100,
100.
100.
100.
100.
100.
100.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
EST'D
DET LIM
(mg/L)
»
*
B
0,
0
0
0
0
0
0
0
0
0
0
0
0
*
*
*
*
»
*
*
*
044
054
068
076
085
100
103
120
130
136
136
166
166
166
176
187
200
200
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
Pr
II
II
II
II
II
II
II
II
II
II
390.
414.
417,
422.
422.
406.
411.
418.
440.
400.
844
311
939
535
293
281
846
948
882
869
8
8
7
7
6
6
6
5
4
4
*
*
*
,
*
.
*
*
*
m
1
0
2
0
3
3
0
0
9
6
10
10
10
10
10
10
10
10
10
10
*
*
«
*
*
*
*
*
*
0
0
0
0
0
0
0
0
0
0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
037
037
041
042
047
047
050
060
061
065
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
Pt
II
II
I
I
II
I
I
I
I
I
I
214. 423
203.646
204.937
265.945
224.552
217.467
306. 471
212.861
193.700
210.333
273. 396
248.717
100.0
54.0
42.0
37.0
36.0
36.0
25.0
24.0
22.0
20.0
20,0
20.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
0.030
0.055
0.071
0.081
0.083
0.083
0.120
0.125
0. 136
0.150
0. 150
0.150
Appendix A cont'd.
COMMENTS
Zaidel
OH Band
MIT
Zaidel
Zaidel
Zaidel
MIT
MIT
OH Band
APPEOX. WAVE
29
-------
Appendix A cont'd,
S WAVE-
OF LENGTH
Rb
Ft
E e
Fe
P.e.
Fe
fce
F e
ae
fc e
Be
F e
F.e
Sh
Fh
f,h
f-h
Rh
Rh
Eh
sh
Fh
Rh
Ph
Rh
Rh
Sh
Ru
Ru
Ru
Fu
RU
Fu
Ru
Fu
Ru
Ru
Fu
Ru
Fu
I
I
I
II
II
II
II
T
*.
I
I
II
II
I
I
II
II
I
II
I
II
I
II
I
II
II
I
I
I
II
II
II
II
II
II
II
I
II
II
II
1
II
(rim)
420.
421.
197.
221.
227.
189.
20U.
228.
229.
202.
209.
346.
208.
233.
249.
343.
252.
369.
246.
339.
251.
352.
242.
241,
228.
365.
350.
240.
245.
267.
269.
266.
249.
249.
349.
273.
245.
271.
372.
235.
185
556
313
426
525
836
908
751
449
364
241
046
559
477
077
4B9
053
236
104
682
103
802
711
584
857
799
252
272
657
876
206
161
842
857
894
435
644
241
803
791
I
n
T
Lb
0.8
NM
49.0
47.0
44.0
8.0
3. 8
3.8
3.6
3.2
3.2
2.6
2.4
67.0
52.0
50.0
39,0
35.0
28. 0
24.0
24.0
24.0
24, 0
23.0
21.0
20.0
20.0
100.0
100.0
83.0
33.0
31.0
31.0
31.0
27.0
26.0
25.0
25.0
25.0
21.0
CONC
(mg/L)
1000.0
1000.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10,0
10.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100,0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
EST'D
DET LIM
(mg/L)
37.500
« W * « M
0.006
0.006
0.006
0.037
0.078
0.078
0.083
0.093
. 0.093
0. 115
0.125
0.044
0.057
0.060
0.076
0.085
0. 107
0.125
0. 125
0.125
0. 125
0.130
0. 142
0.150
0.150
0.030
0.030
0.036
0.090
0.096
0.096
0.096
0.111
0.115
0.120
0.120
0. 120
0. 142
COMMENTS
Sr 421.552
Zaidel
Zaidel
Zaidel
NR
NR
30
-------
S WAVE-
OF LENGTH
Ru
RU
EU
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
Sb
3b
Sb
Sb
Sb
Sb
Sc
sc
SC
sc
Sc
SC
SC
SC
SC
SC
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
Sc
sc
Sc
Sc
SC
I
II
II
I
I
I
I
T
I
I
I
I
I
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
(nm)
247,
250.
279.
206.
217.
231.
252.
259.
259.
217.
195.
213.
204.
214.
209.
203.
220.
237.
361.
357.
363.
364.
424.
357.
335.
337.
358.
255.
431.
256.
356.
364.
355.
336.
365.
432.
358.
353.
256.
359.
432.
336.
893
701
535
833
581
147
852
805
809
919
039
969
957
486
841
977
845
792
384
253
075
279
683
635
373
215
094
237
409
025
770
531
855
895
180
074
964
573
321
048
501
127
n
20.0
19.0
19.0
91.0
68.0
49.0
28.0
28.0
28.
19
18
16.0
15.0
12.0
8.7
6.6
6.5
4.7
200,
150,
140,
110.
110,
82.
80.
68.
67,
65,
38,
37.
35.
34.
32.
31.
31,
26.
24.
22.
20,
19.
0
0
0
37.0
17.0
CONC
(mg/L)
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
10.0
10,0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10,0
10.0
10.0
10.0
10.0
10.0
10.0
EST'D
DET LIM
(mg/L)
0.150
0.157
0.157
0.032
0.044
0.061
0. 107
0. 107
0.107
0.157
0. 166
0.187
0.200
0.250
0,344
0.454
0.461
0.638
0.0015
0.0020
0.0021
0.0027
0.0027
0.0037
0.0038
0.0044
0.0045
0.0046
0.0079
0.0081
0.0081
0,0086
0.0088
0.0094
0.0097
0.0097
0.011
0.012
0.013
0.015
0.015
0.017
Appendix A cont'd,
COMMENTS
MIT
NE
NB
Zaidel
Ar 356.766
31
-------
S WAVE-
OF LENGTH
Sc
Sc
Se
Se
56
3e
Se
Si
Si
.~i
Si
Si
Si
Si
Si
Si
si
Si
Si
Si
Si
Si
Stn
Sm
Sm
Sm
SHI
Sm
Sra
Sm
S in
Sm
Sm
Sm
sn
Sn
Sn
Sn
I
II
II
I
T
X
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
I
I
I
(nm)
254
437
196
203
206
207
199
251
212
288
250
252
251
252
221
251
198
221
243
190
220
205
359
442
360
363
428
446
367
356
373
443
388
. 522
.446
.026
.985
. 279
.479
.511
.611
.412
. 158
.690
.851
.432
.41 1
.667
.920
.899
. 039
. 515
. 134
.798
.813
.260
. 434
.949
. 429
.079
.734
.084
.827
. 126
.432
.529
330. 639
189.980
235. 484
242.949
283, 999
40.0
26.0
10. 0
1.9
0.6
250.0
180.0
110.0
100.0
95.0
79.0
75.0
72.0
61.0
50.0
47.0
36.0
23.0
23.0
23.0
69.0
55.0
52.0
45.0
43.0
41.0
40.0
39.0
38.0
36.0
36.0
J3. 0
120.0
31.0
31.0
27.0
CONG
(mg/L).
10.0
10.0
100.0
100,0
100.0
100.0
100.0
100,0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100. 0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100,0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
EST'D
DET LIM
(mg/L)
0.017
0.017
0.075
0. 115
0. 300
1.578
5.000
0.012
0.016
0.027
0.030
0.031
0.037
0.040
0.041
0.049
0.060
0.063
0.083
0.130
0.130
0.130
0.043
0.054
0.057
0.066
0.069
0.073
0.075
0.076
0.078
0.083
0,083
0,090
0.025
0.096
0.096
0.111
Appendix A cont'd,
COMMENTS
NfiL
NEL
NEL
Zaidel
Zaidei
32
-------
Sfl
Sn
sn
Sn
Sn
Sn
Sn
S
OF
I
I
I
I
I
I
I
I
WAVE-
LENGTH
(run)
226.891
224.605
242. 170
270.651
220.965
286.333
317.505
I
T
xb
25.0
25.0
19.0
18.0
16.0
14.0
14.0
CONC
(mg/L)
100.0
100.0
100.0
100.0
100.0
100.0
100.0
EST'D
DET LIM
(tng/L)
0.120
0.120
0. 157
0.166
0.137
0.214
0.214
Sr
sr
Sr
Sr
Sr
Sr
Sr
Sr
Sr
sr
II
II
II
II
II
II
II
I
II
II
407
421
216
215
346
338
430
460
232
416
*
«
*
*
*
*
*
*
*
771
552
596
284
446
071
545
733
235
180
72
39
36
29
13
8
4
4
2
2
*
»
*
*
*
*
*
«
*
0
0
0
0
0
8
8
4
9
4
1
1
10
10
10
10
10
10
10
10
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
00042
00077
0083
010
023
034
062
068
103
125
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta
Ta'
Ta
Ta
Ta
Ta
Ta
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
226
240
268
233
228
263
238
223
267
205
219
260
248
284
269
296
«
*
.
.
*
*
*
*
*
*
*
*
*
*
.
^
230
063
517
198
916
558
706
948
590
908
603
349
870
446
452
513
120.
105.
100.
96.
95.
88.
80.
69.
68.
68.
58.
54.
54.
52.
50.
50.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
«
*
*
*
*
a
*
*
*
*
*
*
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
025
028
030
031
031
034
037
043
044
044
051
055
055
057
060
060
Tb
Tb
Tb
Tb
Tb
Tb
Tb
II
II
II
II
II
II
II
350
384
367
387
356
356
370
»
*
»
»
*
917
873
635
417
174
852
286
130.
54.
50.
48.
47.
46.
46.
0
0
0
0
0
0
0
100
100
100
100
100
100
100
*
0
0
0
0
0
0
0
0.
0.
0.
0.
0.
0.
0.
023
055
060
062
063
065
065
Appendix A cont'd.
COMMENTS
OH Band
MIT
MIT
33
-------
Appendix A cont'd,
S WAVE-
OP LENGTH
Tfc
Th
Tb
Tb
Tb
Tb
Tb
Te
Te
Te
Te
Te
Te
Te
Te
Te
Te
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Th
Ti
Ti
Ti
Ti
Ti
I
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
(nm)
332.
389.
374.
374.
370.
329.
345.
214.
225.
233.
214.
200.
238.
208.
199.
225.
226.
283.
283.
274.
401.
318.
318.
374.
294.
353.
269.
339.
332.
360.
311.
284.
287.
'256.
275.
334.
336.
323.
337.
334.
440
920
734
717
392
307
406
281
902
578
725
202
326
116
418
548
555
730
231
716
913
020
823
118
286
959
242
204
512
944
953
281
041
559
217
941
121
452
280
904
73.0
17.0
17.0
14.0
12.0
11.0
11.0
6. 3
2.7
2.6
46.0
42.0
36.0
36.0
34.0
32.0
31.0
31.0
30.0
30.0
30.0
28.0
27.0
26.0
23.0
23.0
23.0
23.0
79.0
57.0
56.0
45.0
40.0
CONG
(mg/L)
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
10.0
10.0
10.0
10.0
10.0
EST'D
DET LIM
(mg/L)
0.085
0.096
0.100
0. 100
0. 103
0.103
0. 111
0.041
0.176
0. 176
0.214
0.250
0.272
0.272
0.476
1. 111
1.153
0.065
0.071
0..083
0.083
0.088
0,093
0.096
0.096
0.100
0.100
0. 100
0. 107
0.111
0.115
0. 130
0. 130
0.130
0.130
0.0038
0.0053
0 . 00 54
0.0067
0.0075
OH Band
OH Band
OH Band
OH Band
34
-------
Appendix A cont'd.
S WAVE-
OF LENGTH
Ti
Ti
Ti
Ti
Ti
Ti
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tl
Tm
Tm
TIB
Tm
TIB
Tm
Tm
Tm
TIB
Tm
Tm
Tro
TB
Tm
Tm
Tin
Tm
TIB
0
U
0
0
u
u
u
I
II
II
II
II
II
II
II
I
I
I
I
I
I
I
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
(nm)
308.
307.
338.
323.
323.
368.
190.
276.
351.
377.
237.
291.
223.
352.
258.
313.
346.
384.
342.
376.
379.
336.
317.
376.
313.
345.
329.
344.
324.
370.
370.
250.
286.
385.
367.
263.
409.
393.
424.
294.
802
864
376
657
904
520
864
787
924
572
969
832
782
943
01 4
126
220
802
508
133
575
261
283
191
389
366
100
150
154
136
026
908
923
958
007
553
014
203
167
192
I
n
T
£b
39,0
37.0
37.0
30.0
29.0
26. 0
CONG
(mg/L)
10.0
10.0
10.0
10.0
10.0
10.0
EST'D
DET LIM
(mg/L)
0.0077
0.0081
0.0081
0.010
0.010
0.011
74.0
25.0
15. 0
13.0
7.0
2.9
2.2
1.7
1.7
,0
0
0
0
0
0
0
0
0
0
58,
37.
31.
30.
26.
26,
26.
23.
23.
22,
19.0
19,0
18.0
16.0
15,0
14.0
14.0
14,0
12.0
10,0
9.0
8.9
8.2
6.5
6.2
100.
100.
100.
100,
100,
100.
100,
100,
100.0
10.0
10.0
10.0
10,
10,
10,
10,
10,
10.
10,
10,
10.
10.
10,
10,
10.
10,
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10.0
100
100
100
100
100,
100
0
,0
0
,0
0
,0
0,
0,
0,
0,
0.
1,
1,
1,
040
120
200
230
428
034
363
764
1.764
100.0
.0052
,0081
,0097
.010
,011
,011
,011
,013
,013
,013
,015
,015
,016
,018
,020
0.021
0.021
0.021
0.250
0.300
0,333
0.337
0.365
0.461
0.483
0,
0.
0,
0,
0,
0,
0.
0,
0,
0,
0,
0,
0,
0,
0.
COMMENTS
OH Band
OH Band
OH Batid
OH Band
OCHL
OH Band
OH Band
OH Band
OH Band
35
-------
u
n
I!
u
u
u
u
u
V
V
V
V
V
V
V
V
V
V
V
V
V
w
*
w
w
w
w
rf
V
w
H
w
w
w
w
w
H
Y
Y
Y
S WAVE-
OF LENGTH
I (ran)
II 385.466
II 290.828
II 258.963
II 288.274
II 256.541
II 279.394
II 311.935
II 330.590
II 309.311
II 310. 230
II 292.402
II 290.882
II 311.071
II 289. 332
II 268.796
II 311.838
II 214.009
II 312. 528
II 327,612
II 292.464
II 270.094
II 207.911
II 224.875
218. 935
II 209.475
II 209.860
II 239.709
II 222.589
II 220. 448
II 200.807
II 208. 819
II 248.923
II 202.998
II 205.468
II 216.632
II 232. 609
II 203. 503
II 371.030
II 324.228
II 360.073
Appendix A cont'd,
COMMENTS
60.0
47.0
40.0
34.0
30.0
29. 0
29.0
25.0
20.0
20.0
19.0
18.0
17.0
100.0
67.0
65.0
64.0
55.0
54.0
50.0
49.0
42.0
41.0
41.0
40.0
40.0
40.0
39.0
38.0
36.0
67.0
63.0
10.
10.
10,
10.
10.
10.
10.
10.
10,
10.
10.
10,
,0
,0
,0
,0
0
,0
0
100
100
100
100
100
100
100
100.0
100.0
100
100
100
100
100
100
0,
0
0
0
0
0
o,
0
0
0
0,
0,
,0050
,0064
,0075
,0088
,010
,010
,010
,012
,015
,015
015
,016
10.0 0.017
0.030
0.044
0.046
0.046
0,054
,055
,060
,061
,071
0.073
0.073
,075
,075
,075
076
0.
0,
0.
0.
0,
0,
0,
0,
100.0 0.078
10.0 0.0035
10.0 0.0045
10.0 0.0048
OH Band
OH Band
OH Band
OH Band
OH Band
MIT
OH Band
MIT
Zaidel
Zaidel
OH Band
36
-------
S WAVE-
OF LENGTH
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Yb
Zn
Zn
zn
Zn
Zn
Zn
Zn
Zn
zn
Zfl
Zn
Zr
Zr
zr
zr
Zr
zr
Zr
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
l
I
I
I
I
I
~L
I
II
II
II
II
II
II
II
(nm)
377.
437.
378.
361.
321.
363.
224.
332.
360,
417.
354.
320.
328.
369.
289.
222.
211.
212.
218.
275.
297,
265,
213.
202.
206.
334.
330.
481.
472.
328.
334.
280.
280.
343,
339.
257.
349.
357.
327.
256.
433
494
870
105
669
312
306
789
192
754
901
332
937
419
138
446
667
674
571
048
056
375
856
548
200
502
259
053
216
233
557
106
087
823
198
139
621
247
305
887
n
57.0
46. 0
40.0
40.0
38.0
36.0
33.0
32.0
30. 0
26.0
23.0
20.0
170.0
100.0
35.0
34.0
32.0
32.0
22.0
17.0
17.0
14,0
170.0
75.0
51.0
2.2
1.3
1.3
0.7
0.6
0.4
0.4
0.4
42. 0
39..0
31.0
30.0
30.0
25.0
22.0
CONC
(mg/L)
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10,0
10.0
10.0
10.0
10.0
10.0
10.0
10,0
10.0
10.0
10.0
10.0
10.0
10.0
EST'D
DET LIM
(mg/L)
0.0053
0.0065
0.0075
0.0075
0.0079
0.0083
0.0091
0.0094
0.010
0.011
0.013
0.015
0.0018
0.0030
0.0086
0.0088
0.0094
0.0094
0.013
0.017
0.017
0.021
0.0018
0,0040
0.0059
0. 136
0.230
0.230
0.428
0.500
0.750
0.750
0.750
0.0071
0.0077
0,0097
0.010
0.010
0.012
0.013
Appendix A cont'd.
COMMENTS
OH Band
OH Band
NF
NE
37
-------
S WAVE-
OF LENGTH
zr
zr
Zr
Zr
Zr
Zr
Zr
zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
Zr
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
n
T
CONG
(mg/L)
(rim) b
327.
267.
272.
273.
274.
270.
350.
355.
348.
256.
272.
330.
316.
318.
328.
274.
275.
357.
926
363
261
486
256
013
567
660
115
764
649
628
597
286
471
586
221
685
2
1.
20.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6.
4.
4.
2.
2.
2.
2.
1.
1.
1.
1.
1.
0.
0.
0.
0.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
*
*
«
*
*
*
*
*
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
EST'D
DET LIM
(mg/L)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
014
015
018
021
021
025
025
025
025
027
027
027
027
027
030
030
030
030
Appendix A cont'd,
COMMENTS
OH Band
OH Band
38
-------
APPENDIX B
Prominent Lines of the Elements Emitted by the
Inductively Coupled Plasma in Order of Wavelength.
As
Be
Sn
Os
Si
Ei
11
Mil
Au
C
As
Pt
Hg
Sb
Au
Bi
Se
Ef
A3
He
Au
In
Si
As
Au
As
Se
C
fe
Ge
AU
Te
As
W
AS
Au
Mo
Mo
P
Be
Zn
s
OF
I
I
II
II
I
II
II
II
I
I
I
II
I
I
T
I
II
I
II
I
II
I
I
II
I
I
I
T
I
II
T
I
II
I
I
II
II
I
II
II
WAVE-
LENGTH
(nm)
189.042
189.836
189.980
189.900
190.134
190. 241
190.864
191.510
191.893
193,091
193.696
193.700
194.227
195.039
195.193
195. 389
196.026
196.382
197. 197
197.313
197.819
197.745
198.899
198.970
198.963
199.048
199,511
199.362
199.418
199.824
200.081
200. 202
200.334
200.807
200.919
201. 200
201.511
202.030
202. 347
202.364
202.548
i
n
Xb
22.0
8.0
120.0
25.0
23.0
10.0
74.0
5.8
35.0
67.0
56.0
22.0
120.0
18.0
18.0
14.0
40.0
150.0
39.0
49.0
77.0
1.7
50.0
16.0
20.0
5.5
0.6
3.4
6.3
34.0
32.0
12.0
25.0
42.0
6. 1
54.0
16.0
38.0
3.8
3.2
75.0
CONG
(mg/L)
100.0
10.0
100.0
1.0
100.0
100.0
100.0
10.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
10.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
1000.0
100.0
100.0
100,0
100.0
100.0
100.0
100.0
100.0
10.0
10.0
100.0
10.0
10.0
EST'D
DET LIM
(mg/L)
0.136
0.037
0.025
0.0012
0. 130
0.300
0.040
0.051
0.085
0,044
0.053
0.136
0.025
0. 166
0.166
0.214
0.075
0.020
0.076
0.006
0.038
1.764
0.060
0. 187
0.150
0.545
5.000
8.823
0.476
0.088
0.093
0.250
0.120
0.071
0.491
0,055
0.018
0.0079
0.789
0.093
0.0040
COMMENTS
NRL
Zaidel
Zaidel
APPROX. WAVE
NRL
Zaidel
UCBL
NfiL
Zaidel
NRL
APPfiOX. WAVE
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
NHL
Zaidel
NRL
NRL
Zaidel
MIT
Zaidel
39
-------
Appendix B cont'd,
MI
w
p
H
Ft
Ko
Sb
Se
Ge
Ge
Ir,
Mo
Fe
Ft
Sb
Ir
W
cr
Be
Be
Si
Ta
Cr
Bi
Zn
Se
Cr
OS
Sb
Ge
Cs
Se
W
In
Au
Te
Re
W
Ir
B
B
Ga
Ee
Ir
Ge
W
S WAVE-
OF LENGTH
I (nm)
I 202.582
II 202.998
I 203. 349
II 203.503
II 203.646
II 203. 344
I 203.977
I 203.985
I 204.171
I 204.377
204.419
II 204.593
I 204.908
I 204.937
I 204.957
I 205.222
II 205.468
II 205.552
I 205.590
I 205.601
I 205.813
205.908
II 206. 149
I 206.170
II 206.200
I 206.279
II 206.542
II 206.721
I 206.833
I 206.866
II 207.067
I 207.479
II 207.911
II 207.926
II 208.209
I 208.116
I 208.559
II 208.819
I 208.882
I 208.893
I 208.959
209.050
II 209.241
I 209.263
I 209.426
II 209.475
I
n
T
Lb
1.3
40.0
7.4
38.0
54.0
24.0
6.6
26.0
34.0
35.0
30.0
24.0
3.8
42.0
15.0
49.0
40.0
49.0
0.7
0.7
23.0
68.0
42.0
35.0
51.0
10.0
31,0
22.0
91.0
50.0
14.0
1.9
100.0
4.2
70.0
11.0
2.4
41.0
28.0
25.0
30.0
11.0
3.2
28.0
75.0
64.0
CONG
(mg/L)
1.0
100.0
100.0
100. 0
100.0
10.0
100.0
100.0
100.0
100.0
100.0
10. 0
10.0
100.0
100.0
100.0
100.0
10.0
1.0
1.0
100.0
100.0
10.0
100.0
10. 0
100.0
10.0
1.0
100.0
100.0
1.0
100.0
100,0
100.0
100.0
100. U
10.0
100.0
100.0
10.0
10.0
100.0
10.0
100.0
100.0
100.0
EST'D
DET LIM
(mg/L)
0.023
0.075
0.405
0.078
0.055
0.012
0.454
0.115
0..088
0..085
0. 100
0.012
0.078
0.071
0.200
0.061
0.075
0.0061
0.042
0.042
0.130
0,044
0.0071
0.085
0.0059
0.300
0.0097
0.0014
0.032
0.060
0.0021
1.578
0.030
0.714
0.042
0.272
0. 125
0.073
0.107
0..012
0.010
0.272
0.093
0.107
0.040
0.046
COMMENTS
Zaidel
MIT
MIT
Zaidel
Zaidel
Zaidel, NS
Zaidel, NE
Zaidel
MIT
Zaidel
Zaidel
MIT
40
-------
Appendix B cont'd.
s
OF
Sb
W
Pt
Nb
Bi
Au
Ag
Yb
Si
Yb
Ir
Pt
Ei
F
Cu
F
Zn
Sb
V
Te
Pt
Cd
Sb
Te
E
Ir
Sr
P
P
Ir
Ni
Sr
₯
Ir
Fb
Ni
Pt
Be
Be
Sb
Cu
Sb
Yb
W
Cu
Cs
I
I
II
I
II
I
II
II
II
I
II
II
I
I
I
II
I
I
I
II
I
II
II
T
I
T
4*
II
II
T
-L
I
I
II
II
II
II
I
II
I
I
I
I
I
I
II
II
II
WAVE-
LENGTH
n
T
CONG
(mg/L)
(nm) b
2
09.
209.
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
10.
10.
11 .
11.
11.
11.
12.
12.
12.
12.
13.
13.
13.
13,
13.
13.
14.
14.
14.
14.
14.
14.
14.
15.
15.
15.
15.
15.
16.
16.
16.
16.
16.
17.
17.
17.
17.
17.
17.
17.
1-8.
18.
19.
19.
841
860
333
942
026
068
383
667
412
674
681
861
363
547
598
618
856
969
009
281
423
438
486
725
914
268
284
294
408
805
556
596
632
942
999
467
467
499
510
581
894
919
571
935
226
439
8
55
20
31
7
.7
.0
.0
.0
.8
47.0
0
32
180
32
100
24
10
8
25
39
170
16
20
73
100
120
12
14
39
44
29
3
7
17
17
36
40
13
33
13
36
2
2
68
17
19
22
65
17
18
.9
.0
.0
.0
.0
.0
.0
.5
.0
.0
.0
.0
.0
.0
. 0
.0
.0
.0
.0
.0
.0
.4
.2
.0
.0
.0
,0
.0
.0
.0
.0
.5
.5
.0
.0
.0
.0
.0
.0
.0
100
100
100
100
100
100
10
10
100
10
100
100
100
100
10
100
10
100
10
100
100
10
100
100
100
100
10
100
100
100
10
10
100
100
100
10
100
1
1
100
10
100
10
100
10
1
,0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
,0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0*
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
EST'D
DET LIM
COMMENTS
(mg/L)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0.
344
054
150
096
384
063
333
0094
016
0094
030
125
300
352
012
076
0018
.187
015
041
030
0025
250
214
076
068
010
882
416
176
017
0083
075
230
090
023
083
012
012
044
017
157
013
046
017
0017
Zaidel
Zaidel
MIT
Zaidel
WIT
NB
NE
MIT
41
-------
Appendix B cont'd,
S WAVE-
OF LENGTH
Lu
Ta
Ge
Cu
Pb
W
Si
Sb
Sn
Al
Si
Ee
Cu
Ni
Si
Cu
Yb
W
Cu
Cs
Bi
Cu
Bi
Pd
Tl
Ta
ir
Y
Pt
Sn
Ag
Fb
Cu
Ag
W
Ni
Ba
Te
Os
Te
Ta
Al
Cd
Te
Sn
Al
I
II
II
I
I
II
II
I
I
I
I
I
II
I
II
I
II
II
II
I
I
I
I
I
II
I
II
II
II
II
I
II
I
II
II
II
II
II
I
II
1
II
I
II
I
I
I
n
T
CONG
(mg/L)
(nm) b
219.
219.
219.
219.
220.
220.
220.
220.
220.
221.
221.
221.
221.
221.
221.
221,
222.
222.
222.
222.
222.
223.
223.
223.
223.
223.
224.
224.
224.
224.
224.
224.
224.
224.
224.
225.
225.
225.
225.
225.
226.
226.
226.
226.
226.
226.
554
603
871
958
353
448
798
845
965
006
089
426
458
647
667
810
446
589
778
798
825
008
061
159
782
948
268
306
552
605
641
688
700
874
875
386
473
548
585
902
230
346
502
555
891
910
18
58
47
31
70
49
23
6
16
4
47
47
13
29
72
17
34
50
19
11
36
23
87
25
2
69
110
33
36
25
2
9
39
0
67
12
2
2
83
17
120
5
89
2
25
9
.0
.0
.0
.U
.0
.0
.0
.5
.0
.8
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.2
.0
.0
.0
.0
.0
.3
.0
.0
.6
.0
.0
.0
.7
.0
.0
.0
.0
.0
,6
.0
.0
5
100
100
10
100
100
100
100
100
10
100
10
10
10
100
10
10
100
10
1
100
10
100
100
100
100
100
10
100
100
10
100
10
10
100
10
10
100
1
100
100
10
10
100
100
10
.
*
.
*
»
*
*
*
m
.
*
*
,
*
*
,
*
*
*
*
*
*
*
.
.
*
»
*
*
t
*
.
,
*
.
*
%
*
a
*
*
*
9
*
*
*
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0»
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
EST'D COMMENTS
DET LIM
(mg/L)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0,
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1.
0.
0.
0083
051
063
.0097
042
061
130
461
187
062
063
006
023
010
041
017
0088
060
015
0027
083
013
034
120
363
043
027
0091
083
120
130
333
0077
500
044
025
150
111
00036
176
.025
060
0034
153
120
033
Zaidel
Zaidel
Zaidel
Zaidel
MIT
MIT
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
.,
ME
42
-------
Appendix B cont'd
S
WAVE-
OF LENGTH
Al
Ni
Re
Ei
03
Co
Fe
Cd
As
Eh
Ta
fie
Pd
Ni
Ba
In
Co
Sb
Co
Cd
Co
Co
Ni
Ni
Sr
Hf
Ag
H
Ag
Ta
Fe
Eh
Ea
Os
Ga
Fe
Co
Ni
Co
Ba
Fe
Fe
Be
As
Hf
Pd
I
I
II
II
I
II
II
I
I
I
I
II
I
II
11
II
II
II
I
II
I
II
II
II
I
II
II
II
II
II
II
II
II
II
II
I
II
II
I
II
II
II
II
I
I
II
II
(nm)
226.922
227.021
227.525
227.658
228.226
228.616
228.751
228.802
228.812
228.857
228.916
229.449
229.651
230.300
230.424
230,606
230.786
231.147
231.160
231. 284
231.405
231.498
231.604
232.003
232.235
232.247
232.505
232.609
233.137
233.198
233.280
233.477
233.527
233.680
233.828
234.349
234.426
234.554
234.739
234.758
234.810
234.830
234.861
234.984
235.122
235. 134
I
n
b
9.0
12.0
44.0
12.0
48.0
43.0
3.8
110.0
36.0
21.0
95.0
3.b
44.0
13.0
73,0
47.0
31.0
49.0
23.0
0.5
18.0
13.0
19.0
20.0
2.9
160.0
0.7
39.0
0.5
96.0
15.0
67.0
75.0
24.0
3.9
29,0
14.0
9.5
13.0
7.8
23.0
23.0
96.0
21.0
130.0
17.0
CONC
(mg/L)
10.0
10.0
10.0
100.0
1.0
10,0
10,0
10.0
100.0
100.0
100.0
10.0
100.0
10.0
10.0
100.0
10.0
100.0
10.0
10.0
10.0
10.0
10.0
10,0
10.0
100.0
10.0
100.0
10.0
100.0
10.0
100.0
10.0
1.0
100.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
1.0
100.0
100.0
100.0
EST'D
DET LIM
(mg/L)
0.033
0,025
0.006
0.250
0.00063
0,0070
0.078
0.0027
0.083
0. 142
0.031
0.083
0.068
0.023
0.0041
0*063
0.0097
0.061
0.013
0..600
0.016
0.023
0.015
0.015
0.103
0.018
0.428
0.076
0.600
0,031
0.020
0.044
0.0040
0.0012
0.769
0.010
0.021
0.031
0.023
0.038
0.013
0.013
0.00031
0.142
0.023
0. 176
COMMENTS
NB
Zaidel
Zaidel
MIT
«
MIT
Zaidel
NR
NE
Zaidel
43
-------
Appendix B cont'd,
S WAVE-
OF LENGTH
Co
sn
Fu
Co
Al
Cs
Pd
Ir
Ir
Al
Al
Co
Tl
Ir
Fe
Te
Co
Te
Co
Ta
Dy
Fe
Co
Hf
Pb
Hf
Ni
Fe
W
Ta
Fu
Fe
Ag
Hh
Sn
Rh
Au
Sn
Si
Ag
Pd
Pd
Ga
Eu
Eu
Ph
I
II
I
II
II
I
II
II
I
I
I
II
I
I
II
I
II
I
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
II
I
II
I
I
I
II
II
I
I
II
II
II
n
T
CONG
(mg/L)
(nm) b
235.
235.
235.
236.
236.
236.
236.
236.
237.
237.
237.
237.
237.
238.
238.
238.
238.
238.
238.
238.
238.
238.
238.
239.
239.
239.
239.
239.
239.
240.
240.
240.
241.
241.
242.
242.
242.
242.
243.
243.
244.
244.
245.
245.
245.
246.
342
484
791
379
705
735
796
804
277
312
335
862
969
162
204
326
346
578
636
706
736
863
392
336
379
383
452
562
709
063
272
488
318
584
170
711
795
949
515
779
618
791
007
644
657
104
17
31
21
27
5
16
15
24
12
10
10
31
7
12
65
11
21
17
14
80
5
20
50
140
6
140
7
59
54
105
100
27
1
23
19
24
170
31
36
2
18
23
10
25
100
28
.0
.0
.0
.0
.8
.0
,0
.0
.0
.0
.0
,0
.0
.0
.0
.0
.0
.0
.0
.0
.8
.0
.0
.0
.3
.0
.8
.0
.0
.0
.0
.0
.5
.0
.0
.0
.0
.0
.0
.5
.0
.0
.0
.0
.0
.0
10
100
100
10
10
1
100
100
100
10
10
10
100
100
10
100
10
100
10
100
10
10
10
100
100
100
10
10
100
100
100
10
10
100
100
100
100
100
100
TO
100
100
100
100
100
100
*
*
*
.
*
m
9
,
*
*
*
*
ft
*
»
*
,
*
*
*
*
*
*
*
*
.
*
*
,
4
.
*
«
^
m
9
*
*
*
*
.
*
*
*
9
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
EST'D
DET LIM
COMMENTS
(mg/L)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
017
096
142
011
051
0019
200
125
250
030
030
0097
428
250
0046
272
014
176
021
037
051
015
0060
021
476
021
038
0051
055
.028
030
011
200
130
157
125
017
096
083
120
166
130
300
120
030
107
Zaidel
NE
ME
Zaidel
44
-------
Appendix B cont'd.
S WAVE-
OF LENGTH
Hf
Pb
Pd
C
Bu
Os
Pd
Pt
Ta
Pd
'rf
Bh
Be
B
B
Hu
Ru
Ga
Ir
Si
Bu
Tm
Bh
Hf
Hf
Si
Si
Si
Eh
Si
Si
Sb
P
P
Hg
Ir
Sc
Sc
P
In
Sc
Li
Sc
U
Th
zr
I
II
I
I
I
II
II
II
I
II
II
II
II
I
I
I
II
II
I
T
JL
I
II
II
II
II
II
I
I
I
II
T
-i.
I
I
I
I
I
I
II
II
I
I
II
I
II
II
II
II
(nm)
21*6,419
247.638
247.642
247.856
247.893
248.624
248.653
248.717
248.870
248.892
248.923
249.077
249.473
249.678
2 49 , 7 7 3
249.842
249.857
250.070
250.298
250.690
250,701
250.908
251.103
251.269
251.303
251.432
251.611
251.920
252.053
252.411
252.851
252.852
253.401
253.565
253.652
254.397
254.522
255.237
255. 328
256.015
256.025
256.254
256.321
256.541
256.559
256.764
I
n
T
Xb
130.0
5.1
18.0
17.0
20.0
13.0
15,0
20.0
54.0
29.0
41.0
52.0
8.0
53.0
63,0
31.0
31.0
16.0
12.0
100.0
19.0
14.0
24.0
150.0
150.0
79.0
250.0
61.0
39.0
75.0
95.0
28.0
3.0
11.0
49.0
19.0
17.0
65.0
5.2
4.2
37.0
0.7
22.0
5.7
23.0
11.0
CONG
(mg/L)
100.0
100.0
100.0
100.0
100.0
1.0
100.0
100.0
100.0
100.0
100.0
100.0
1,0
10.0
1 0 . 0
100,0
100.0
100.0
100.0
100.0
100.0
10.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100.0
100,0
100.0
100.0
100.0
100.0
100.0
10.0
10.0
100.0
100.0
10.0
100.0
10.0
100.0
100.0
10.0
EST'D COMMENTS
DET LIM
(mg/L)
0.023
0.588
0.166
0.176
0.150
0..0023
0.200
0.150
0.055
0. 103
0.073
0.057
0.0038 Group NE
0.0057
0.0048
0.096 NE
0.096 NR
0. 187
0,250
0.030
0.157
0.021
0.125
0.020 NR
0.020 NB
0.037
0.012
0.049
0.076
0.040
0.031
0. 107
1.000
0..272
0.061
0,157
0.017
0.0046
0.576
0.714
0.0081
4,285 Zaidel
0.013
0.526
0. 130
0.027
45
-------
Appendix B cont'd,
S WAVE- Ifl
OF LENGTH
zr
zr
Hf
Al
Mn
Tl
Fe
Ge
Mn
Sb
Sb
Fe
Fe
la
Mn
Fe
Pb
Lu
Fe
Fe:
0
Ta
Hf
Mo
Ir
Hf
Be
Ge
Ge
Hg
Yb
Pt
Ga
Hu
Pb
Ir
Cr
Ta
Au
Cr
Zr
Ru
Mo
la
V
EU
I
II
II
II
I
II
I
II
I
II
I
I
II
II
II
II
II
T
II
II
II
II
II
II
II
I
II
I
I
I
I
II
I
I
II
I
I
Hf
II
I
II
II
II
II
II
II
II
CONC
(mg/L)
EST'D COMMENTS
DET LIM
(run) *b
256.
257.
257.
257.
257.
258.
253.
259.
259.
259.
259.
259.
259.
260.
260.
261.
261.
261.
263.
263.
263.
263.
263.
263.
263.
264.
265.
265.
265.
265.
265.
265.
265.
266.
266.
266.
266.
267.
267.
267.
267.
267.
268.
268.
268.
269.
387
139
167
510
610
014
588
254
373
805
809
837
940
349
569
187
418
542
105
132
553
558
871
876
971
141
045
118
158
204
375
945
987
161
316
479
602
590
595
716
863
876
414
517
796
206
22
31
150
4
220
1
20
29
190
28
28
24
48
54
145
24
23
150
19
19
9
88
160
8
17
160
6
62
36
0
14
37
3
31
7
13
14
68
96
42
20
83
10
100
29
33
V
4
*
*
*
0
0
0
0
.0
7
0
0
0
0
0
0
0
0
0
0
0
0
."0
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
0
0
0
0
0
0
0
4
0
0
7
0
0
6
0
7
0
0
0
0
0
0
0
0
0
0
0
10.
10.
100.
10.
10.
100.
10.
100.
10.
100.
100.
10.
10.
100.
10.
10.
100.
5.
10.
10.
100.
100.
100.
10.
100.
100.
1.
100.
100.
100.
10.
100.
100.
100.
100.
100.
10.
100.
100.
10.
10.
100.
10.
100.
10.
100.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
(mg/L)
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
013
0097
020
075
0014
764
015
103
0016
107 NE
107 NE
012
0062
055
0021
012
130
0010
015 NP
015 N8
333
034
018
037
176
018
0047 Group NF
048
083
285 Zaidel
021
081
833
096
389
230
021
044
031
0071
015
036
030
030
010
090
46
-------
Th
Ir
Ta
Nb
Zr
V
Lu
5a
Ge
In
Eu
Nb
Ga
Nb
zr
Zr
Eu
Ft
Eu
zr
Hf
Fe
Li
Zr
Zr
Tii
Fe
Yb
Th
Zr
In
LU
Ge
Fe
Cr
Cr
Tl
Hf
MO
Hg
As
Mg
U
Mn
BU
Hg
s
OF
I
II
I
II
II
II
II
II
I
I
I
II
II
I
II
II
II
II
I
II
II
II
II
I
II
II
II
II
II
11
II
I
II
T
U-
II
II
II
I
II
II
I
I
II
II
I
II
WAVE- I
LENGTH ~
CONC
(mg/L)
(run) b
269.
269.
269.
269.
270.
270.
270.
270.
270.
271.
271.
271.
271.
272.
272.
272.
272.
273.
273.
273.
273.
273.
274.
274.
274.
274.
274.
275.
275.
275.
275.
275.
275.
275.
276,
276.
276.
277.
277.
277.
278.
279.
279.
279.
279.
279.
242
423
452
706
013
094
171
651
963
026
241
662
965
198
261
649
778
396
435
486
876
955
118
256
586
716
932
048
217
221
388
417
459
574
259
654
787
336
540
983
022
079
394
482
535
553
30.
11.
50.
43.
12.
17.
12.
18,
27.
5.
25.
34.
5.
30.
16.
11.
37.
20.
26.
14.
180.
15.
1.
14.
10.
36.
19.
17.
23.
10,
1.
12.
28.
16.
15.
22.
25.
190.
12.
0.
5.
1.
5.
24.
19.
195.
0
0
0
0
0
0
0
0
0
4
0
0
7
0
0
0
0
0
0
0
0
0
9
0
0
0
0
0
0
0
6
0
0
0
0
0
0
0
0
6
7
0
6
0
0
0
100
100
100
100
10
10
5
100
100
100
100
100
100
100
10
10
10
100
100
10
100
10
100
10
10
100
10
10
100
10
100
5
100
10
10
10
100
100
10
1
100
1
100
10
100
1
*
*
*
*
*
*
*
*
«
*
*
*
*
*
*
*
»
*
*
«
*
*
*
«
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 ;
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
EST'D
DET LIM
(mg/L)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
6
0
0
0
0
0
1
0
*
*
*
*
*
*
*
*
*
*
»
*
*
*
*
*
*
*
m
«
*
*
»
«
*
0-
0,
0
0
0
0
0
0
0
0
0
0
0
0
»
*
*
*
*
*
*
100
272
060
069
.025
017
012
166
111
555
120
088
526
100
018
027
0031
150
115
021
016
020
578
021
030
083
015
017
130
030
875
012
107
018
020
013
120
015
025
050
526
030
535
012
157
00015
Appendix B cont'd.
COMMENTS
MIT
47
-------
Appendix B cont'd.
S WAVE-
OF LENGTH
Mg
Mn
Zn
Mn
Zn
Eb
Mg
Eu
Ho
Hf
Th
Fb
Cr
Th
Sn
Th
Cr
Ta
Mo
Ir
cr
Mg
Na
Na
Cr
Cr
Sn
Cr
Cr
Tffl
Th
MO
Ga
Nb
Sb
Na
Si
U
Nb
0
Yb
V
Lu
Bi
Lu
U
I
II
I
I
I
I
I
II
II
II
II
II
I
II
II
I
II
II
II
II
I
II
I
I
I
II
II
I
II
II
II
II
II
I
II
T
-4.
II
I
II
II
II
II
II
II
I
II
II
n
T
CONG
(mg/L)
(nm) b
279.
279.
280.
280.
280.
280.
280.
281.
281.
282.
283.
283.
283.
283.
283.
284.
284.
284,
284.
284.
284.
285.
285,
285.
285.
286.
286.
286.
286.
286.
287.
287.
287.
287.
287.
288.
288.
288.
288.
288,
289.
289.
289.
289.
290.
290.
806
827
087
106
106
199
270
394
615
022
231
306
563
730
999
281
325
446
823
972
984
213
281
301
568
257
333
511
674
923
041
151
424
539
792
114
158
274
318
963
138
332
484
798
030
828
2
18
0
14
0
19
100
22
21
160
42
21
42
46
27
m
*
.
*
»
*
*
*
*
.
*
*
»
*
.
23,
35
52
15
10
21
19
1
1
16
15
14
14
13
14
23
11
38
28
4
0
110
5
31
6
35
29
15
9
12
6
*
,.
*
.
*
*
*
*
.
*
*
*
*
*
.
.
*
.
,
«
.
*
*
*
.
*
*
*
*
*
0
0
4
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
0
0
0
0
0
0
0
0
0
0
7
6
0
8
0
0
0
0
0
0
0
0
1
10
10
10
10
100
1
10
10
100
100
100
10
100
100
100
10
100
10
100
10
1
1000
1000
10
10
100
10
10
10
100
10
100
100
100
1000
100
100
100
100
10
10
5
100
5
100
*
*
%
«
«
*
*
.
.
*
.
*
*
.
*
.
*
*
*
*
.
.
*
*
*
,
»
*
,
*
*
*
*
*
.
^
»
»
*
*
*
*
*
%
*
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
EST'D COMMENTS
DET LIM
(mg/L)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
27.
27.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
50.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
015
016
750 NE
021
750 NE
157
00030
013
014
018
071
142
0071
065
111
130
0086
057
020
300
014
0016
272 Zaidel,NE
272 Zaidel,NP
018
020
214
021
023
021
130
027
078
107
638
000 Zaidel
027
517
096
500
0086
010
010
333
012
500
48
-------
S WAVE-
OF LENGTH
V
Er
Lu
Tl
Mo
V
V
Nb
In
Mn
Kg
fin
U
Th
Ga
Ga
Mn
Nb
Er
Ta
Hg
Yb
Gd
Lu
Hg
Gd
Gd
Ge
In
Pt
Bi
Lu
Ti
Gd
Al
Ti
ai
ai
V
Nb
Gd
V
V
V
D
Th
I
II
II
II
I
II
II
II
I
II
II
II
II
II
I
I
II
II
II
II
I
II
II
II
I
II
II
I
I
I
I
II
II
II
I
II
I
I
II
II
II
II
II
II
II
II
(nm)
290.
291.
291.
291.
292.
292.
292.
292.
293.
293.
293.
293.
294.
294,
294.
294,
294.
295.
296.
296.
296.
297.
301.
302.
302.
303,
303.
303,
303.
306,
306.
307.
307.
308.
308.
308,
309.
309.
309.
309.
310.
310.
311.
311.
311.
311.
882
036
139
832
339
402
464
781
263
306
654
930
192
286
364
418
920
088
452
513
728
056
013
054
150
284
405
906
936
471
772
760
864
199
215
802
271
284
311
418
050
230
071
838
935
953
n
34.0
11.0
24.0
2.9
8.0
40.0
18.0
40.0
2.0
22.0
0.5
29.0
6.2
31.0
64.0
9.4
39.0
40.0
11.0
50.0
1.7
17.0
10.0
11.0
0.6
11.0
8.8
29.0
20.0
25.0
40.0
17.0
37.0
9.0
6.6
39.0
13.0
13.0
60.0
83,0
13.0
47.0
30.0
25.0
5.6
26.0
CONG
(mg/L)
10.0
10.0
5.0
100.0
10.0
10.0
10.0
100.0
100.0
10.0
1.0
10.0
100.0
100.0
100.0
100.0
10.0
100.0
10.0
100.0
100.0
10.0
10.0
5.0
100.0
10.0
10.0
100.0
100.0
100.0
100.0
5.0
10.0
10.0
10.0
10,0
10,0
10.0
10.0
100.0
10.0
10.0
10.0
10.0
100.0
100.0
EST'D
DET LIM
(mg/L)
0.0088
0.027
0.0062
1.034
0.037
0.0075
0.016
0.075
1.500
0.013
0.060
0.010
0.483
0.096
0.046
0.319
0.0077
0.075
0.027
0.060
1.764
0.017
0.030
0.013
5.000
0,027
0.034
0.103
0,150
0.120
0.075
0.0088
0.0081
0.033
0.045
0.0077
0.023
0.023
0.0050
0.036
0.023
0.0064
0.010
0.012
0.535
0.115
Appendix B cont'd.
COMMENTS
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
49
-------
S WAVE-
OF LENGTH
₯
Be
Nb
Be
Tm
Tra
Nb
Zr
Tin
Ar
Sn
Ca
Th
Zr
Th
Nb
Ar
₯
Y
Nb
Er
Li
ar
li
Ti
Ti
Tin
Y
Pd
Cu
In
Ar
In
Cd
Er
Zr
Cu
V
Zr
A 9
Zn
Zr
Yb
Tffl
Tb
Na
I
II
II
II
II
II
II
II
II
II
I
I
II
II
II
II
II
T
II
II
II
II
T
-i.
I
II
II
II
II
II
I
I
I
I
I
T
II
II
I
II
II
I
I
II
II
II
II
I
n
T
CONC
(mg/L)
(nm) b
312.
313.
313.
313.
313.
313.
316.
316.
317.
317.
317.
317.
318.
318.
318.
319.
320.
320,
321.
322.
323.
323.
323.
323.
323.
323.
324.
324.
324.
324.
325.
325.
325.
326.
326.
327.
327.
327.
327.
328.
328.
328.
328.
329.
329.
330.
528
042
079
107
126
389
340
597
283
296
505
933
020
286
823
498
039
332
669
548
058
263
449
452
657
904
154
228
270
754
609
758
856
106
478
305
396
612
926
068
233
471
937
100
307
237
20
110
60
41
58
22
75
11
23
1
14
1
34
11
32
41
0
20
38
42
16
2
0
56
30
29
16
67
39
56
25
0
5
0
16
25
31
19
21
38
0
10
170
19
29
1
*
*
«
*
*
«
*
*
*
*
*
*
«
*
*
*
*
»
*
9
*
»
*
*
*
0
0
0
0
0
0
0
0
0
4
0
5
0
0
0
0
8
0
0
0
0
8
8
0
0
0
0
0
0
0
0
7
0
9
0
0
0
0
0
0
6
0
0
0
0
b
1
1
1
10.
1.
00.
1.
10.
10.
00.
10.
10.
00.
0.
100.
1
1
1
1
1
1
1
1
1
10.
00.
00.
10.
10.
00.
10.
00.
10.
10.
10.
10.
10.
00.
10.
00.
00.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
00.
00.
0
0
0
0
0
0
0
0
0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
EST'D
DET LIM
(mg/L)
0.
015
0.00027
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
o..
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
050
00073
0052
013
040
027
013
214
010
088
027
093
073
015
0079
071
018
071
0054
010
010
018
0045
076
0054
120
600
333
018
012
0097
015
014
007
500
030
0018
015
.103
875
Appendix B cont'd.
COMMENTS
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Eaad
OH Band,Zaidel
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band,Zaidel
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band,Zaidel
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
OH Band
Zaidel
50
-------
S WAVE-
OF LENGTH
Zn
Na
0
Zr
Sffl
Er
Ar
Ee
Tb
Th
Ar
Y
La
Za
Zn
Ti
Ii
Gd
Sc
Gd
Ti
Sc
Gd
Tm
Sc
Sc
Er
Ti
Ar
Sr
la
Ag
Ti
cy
Er
Zr
Er
Th
Ar
Ar
Eh
Lu
Ho
Pd
Ar
Dy
I
I
I
II
II
II
II
I
I
II
II
I
II
II
I
I
II
II
II
II
II
II
II
II
ii
ii
ii
ii
ii
i
ii
ii
i
ii
ii
ii
ii
ii
ii
i
i
i
ii
ii
i
i
ii
I
n
T
CONG
(mg/L)
(run) b
330
330
330
330
330
331
331
332
332
332
332
332
333
334
334
334
334
335
335
335
336
336
336
336
336
337
337
337
337
338
338
338
338
338
338
339
339
339
339
339
339
339
339
340
340
340
m
*
*
*
.
.
*
*
*
*
*
*
*
*
*
*
*
^
*
*
*
*
,
*
.
*
9
*
*
.
%
.
.
*
*
*
*
*
%
^
*
*
*
259
298
590
628
639
242
935
134
440
512
550
789
749
502
557
904
941
047
373
862
121
127
223
261
895
215
271
280
348
071
091
289
376
502
508
198
200
204
278
375
682
707
898
458
618
780
1
0
5
11
33
10
3
1
35
28
1
32
30
2
0
40
79
14
80
14
57
17
15
26
32
68
29
45
1
3
17
23
37
9
8
39
9
30
1
3
24
14
23
68
1
11
«
*
*
*
*
*
*
«
«
*
«
»
*
*
*
*
*
*
*
*
«
*
*
*
»
*
*
*
*
*
*
*
»
*
*
*
»
*
3
7
6
0
0
0
1
4
0
0
1
0
0
2
4
0
0
0
0
0
0
0
0
0
0
0
0
0
8
8
0
0
0
0
8
0
4
0
8
6
0
0
0
0
6
0
10.
100.
100.
10.
100.
10.
1.
100.
100.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
100.
100.
5.
10.
100.
10.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
EST'D
DET LIM
(mg/L)
0.
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
230
285
535
027
090
030
021
085
107
0094
010
136
750
0075
0038
021
0038
021
0053
017
020
011
0094
0044
010
0067
034
017
013
0081
033
034
0077
031
100
125
010
013
044
027
Appendix B cont'd.
COMMENTS
Zaidel
Group NB
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
51
-------
S WAVE-
OF LENGTH
Ni
Ho
Fd
Gd
Tm
Eh.
Zr
Gd
Tm
Mn
Ho
Tin
Th
Ho
Ee
Pd
Ar
Tm
Sr
Cd
LU
Eo
Zr
Pd
Ho
Ar
Zr
Eu
Er
Eh
Zr
Ar
Lu
Tb
Ho
Pd
Tl
Cy
Ni
Eh
Tl
Dy
Sc
Dy
£y
Th
I
T
II
I
II
II
I
II
II
II
II
II
II
II
II
I
I
I
II
II
I
II
II
II
I
II
T
II
I
II
I
II
I
II
II
II
I
I
II
I
I
I
II
II
II
II
II
n
T
CONC
(mg/L)
(nm) b
341.
341.
342.
342.
342.
343.
343.
343.
344.
344.
345.
345.
345.
345.
346.
346.
346.
346,
346.
346.
347.
347.
348.
348.
348.
349.
349.
349.
349.
350.
350.
350.
350.
350.
351.
351.
351.
352.
352.
352.
352.
353.
353.
353.
353.
353.
476
646
124
247
508
489
823
999
150
199
314
366
406
600
046
077
108
220
446
620
248
426
115
115
484
327
621
894
910
252
567
649
739
917
559
694
924
398
454
802
943
170
573
602
862
959
6
16
30
21
30
50
42
10
18
6
10
19
27
53
2
16
3
37
13
0
10
16
12
18
15
0
30
27
17
20
12
2
13
130
11
22
15
7
6
24
1
30
24
10
6
30
*
»
*
»
*
*
*
*
*
«
«
«
*
*
*
*
*
*
*
*
*
*
*
*
»
«
i
*
«
2
0
0
0
0
0
0
0
0
6
0
0
0
0
6
0
5
0
0
7
0
0
0
0
0
9
0
0
0
0
0
0
0
0
0
0
0
4
6
,0
7
0
0
0
6
0
10.
10.
100.
10.
10.
100.
10.
10.
10.
10.
10.
10.
100,
10.
10.
100.
10.
10.
10.
5.
10.
10.
100.
10.
10.
100.
10.
100.
10.
5.
100.
10.
100.
100.
10.
10.
100.
100.
10.
10.
10.
10.
100.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
EST'D
DET LIM
(mg/L)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
1.
0.
0.
0.
0.
0.
048
018
100
014
010
060
0071
030
016
045
030
015
111
0057
115
187
008
023
428
015
018
025
166
.020
010
1 11
017
150
025
011
023
027
136
200
040
045
125
764
010
012
030
045
100
1
Appendix B cont'd,
COMMENTS
Zaidel
Zaidel
Zaidel
52
-------
Appendix B cont'd.
S WAVE-
OF LENGTH
Gd
Y
Gd
Pd
Ar
Ar
Zr
Sc
Tb
Ar
Ar
Ar
Sc
Sm
Tb
Ar
Zr
Sc
Ey
Sc
Zr
Cr
Sc
Gd
Sc
Sc
Sm
Y
Y
Ar
Th
Sffl
Fd
Cd
Y
Sc
Sc
Ar
Y
Sm
Ar
Fd
Pb
Sc
Ar
Sc
I
II
II
II
I
I
I
II
II
II
I
I
I
II
II
II
I
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
I
I
II
II
II
I
II
II
I
I
I
II
I
II
I
n
T
CONG
(mg/L)
(nm) b
354.
354.
354.
355.
355.
355.
355.
355.
356.
356.
356.
356.
356.
356.
356.
357.
357.
357.
357.
357.
357.
357.
358.
358.
358.
359.
359.
360.
360.
360.
360.
360.
360.
361.
361.
361.
363.
363.
363.
363.
363.
363.
363.
364.
364.
364.
580
901
936
308
431
601
660
855
174
329
434
766
770
827
852
229
247
253
624
635
685
869
094
496
964
048
260
073
192
652
944
949
955
051
105
384
075
268
312
429
446
470
958
279
312
531
9
23
9
22
18
1
12
34
47
3
2
8
37
39
46
2
30
150
6
82
10
13
67
10
26
20
69
63
30
8
27
52
35
1
40
200
140
3
36
45
3
55
5
110
1
35
*
*
*
*
*
*
*
*
*
*
*
»
*
»
*
*
*
*
*
*
»
*
»
*
*
*
*
*
»
*
*
*
*
5
0
0
0
0
7
0
0
0
2
1
6
0
0
0
3
0
0
4
0
0
0
0
0
0
0
0
0
0
7
0
0
0
3
0
0
0
5
0
0
9
0
2
0
5
0
10.
10,
10.
100.
10.
10.
100.
10.
100.
100.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
100.
10.
10.
100.
100.
100.
10.
10.
10.
10.
10.
100.
100.
100.
10.
10.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
EST'D
DET LIM
COMMENTS
(mg/L)
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
o..
0.
0.
0.
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
031
013
033
136
025
0088
063
0081
076
065
010
0020
046
0037
030
023
0045
030
011
015
043
0048
010
111
057
085
230
0075
0015
0021
0083
Ofa6
054
576
0027
0086
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Ar 356.766
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
53
-------
Appendix B cont'd.
S WAVE-
OF LENGTH
Dy
Gd
Ar
Sc
Hg
Eh
Ar
U
Ar
Sm
Ar
Tb
Pb
Ti
Ar
Eh
Er
Yb
Tm
Tm
Tb
Tb
Y
Eu
Eu
Sro
Th
Tb
Ib
La
Ira
Tm
Gd
Ar
Y
Tl
Ar
Y
La
La
Tm
Ho
H
Ce
Nd
Ho
I
II
II
I
II
I
I
T
j.
II
I
II
I
II
T
II
I
I
II
II
II
II
II
II
II
II
I
II
II
II
II
II
II
II
II
T
j.
II
I
I
II
II
II
II
II
I
II
II
II
I
n
T
CONG
(mg/L)
(nm) b
364
364
364
365
365
365
365
367
367
367
367
367
368
368
369
369
369
369
370
370
370
370
371
372
372
373
374
374
374
375
376
376
376
377
377
377
378
378
379
379
379
379
379
380
380
381
*
*
*
»
*
*
*
*
9
*
*
*
*
*
*
*
*
*
*
*
*
*
*
540
619
983
180
483
799
953
007
067
084
524
635
348
520
090
236
265
419
026
136
286
392
030
494
803
126
118
717
734
908
133
191
839
037
433
572
136
870
083
478
575
675
790
152
536
073
13.
10.
7.
31.
0.
20.
1.
10.
2.
40.
1.
50.
8.
26.
2.
35.
16.
100.
14.
15.
46.
29.
86.
34.
25.
38,
31.
30.
30.
20.
26.
23.
12.
2.
57.
13.
1.
40.
26.
30.
26.
12.
0.
4.
16.
15.
0
0
0
0
3
0
4
0
4
0
1
0
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
0
0
0
0
0
1
0
0
0
10.
10.
10.
100.
100.
100.
100.
100.
100.
10.
100.
10.
10.
10.
10.
100.
100.
10.
10.
100.
100.
100.
100.
100.
10.
10.
10.
10.
10.
100.
10.
10.
10.
10.
10.
10.
100.
10.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
EST'D COMMENTS
DET LIM
(mg/L)
»
*
*
023
030
Zaidel
0097
10.000
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
*
*
*
*
»
*
*
«
*
*
*
«
*
*
*
*
*
*
«
*
*
150
Zaidel
300
Zaidel
075
Zaidel
060
348
011
Zaidel
085
018
0030
021
020
065
103
.0035
0088
120
078
096
100 NR
100 NB
015
011
013
025
Zaidel
0053
230
Zaidel
0075
011
010
011
025 H 379.790
Zaidel
075
187
020
54
-------
S WAVE-
OF LENGTH
Ea
Hg
Ar
H
Mg
Tm
Nd
Nd
Tb
La
Nd
Nd
U
U
Nd
Nd
La
Dy
Tb
Sm
H
Ho
Ba
Ar
Er
Dy
Tb
Ar
Er
Eu
Pr
La
lu
Ce
U
Ca
Nd
Ce
Al
Dy
Ar
Ar
La
Nd
Al
Nd
I
II
I
I
T
j.
I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
I
II
II
I
II
II
II
I
II
II
II
II
II
II
II
II
II
II
I
II
I
I
II
II
I
II
(nm)
381
383
383
383
383
384
384
384
384
384
385
385
385
385
386
386
387
387
387
388
388
389
389
389
389
389
389
389
390
390
390
392
393
393
393
393
394
394
394
394
394
394
394
395
396
396
*
*
*
*
*
*
*
*
*
*
*
*
*
«
*
*
*
*
*
*
*
*
*
«
*
*
»
*
*
*
*
*
*
*
*
967
231
468
539
826
802
624
852
873
902
166
174
466
958
333
340
164
211
417
529
905
102
178
466
623
853
920
986
631
710
844
922
048
109
203
366
151
275
401
468
750
898
910
116
152
312
110.0
0.7
6,0
0.1
0.9
31,0
16.0
16.0
54.0
12.0
19.0
19.0
6.2
12.0
23,0
23.0
20.0
8.2
48.0
36.0
0.3
18.0
5.2
1.4
7.0
6.0
31.0
1,0
14.0
39.0
8. 1
12.0
53,0
5.0
8,2
89.0
19.0
4.4
6.3
9.5
8.0
27.0
17.0
10.5
17.0
CONG
(mg/L)
10.0
1.0
1.0
10.0
100.0
100.0
100.0
10.0
100.0
100.0
100.0
100.0
100.0
100.0
10.0
10.0
100.0
100.0
10.0
10.0
10.0
10.0
100.0
10.0
10.0
10.0
10.0
10.0
10.0
100.0
0.5
100.0
10.0
10.0
10.0
10.0
100.0
10.0
100.0
EST'D
DET LIM
(mg/L)
0.0027
0.042
0.033
0.0097
0. 187
0.187
0.055
0.025
0.157
0.157
0.483
0.250
0. 130
0.130
0.015
0.036
0.062
0.083
0.016
0.057
0.042
0.050
0.096
0.021
0.0077
0.037
0.025
0.0057
0.060
0.365
0.00019
0.157
0.068
0.047
0.031
«»^ » »
0.176
0.028
0.176
Appendix B cont'd.
COMMENTS
Zaidel
Zaidel
NR
MB
NB
NF
MB
NB
Zaidel
H 388.905
H 388.905
Zaidel
H 388.905
Zaidel
Zaidel
Zaidel
Ar 394.898
55
-------
Appendix B cont'd.
Dy
Ca
H
EU
La
La
Dy
Fr
Nd
Ce
Th
Hn
La
Ga
Hn
Ce
Nd
La
Ar
Ar
K
Ar
Eb
Nd
Fr
Ce
Ce
La
Sr
Dy
La
U
H
In
Nd
Pr
La
Eu
Ba
Li
Li
Ce
Ce
Pr
Nd
S WAVE-
OF LENGTH
I (nm)
II 396.839
II 396.847
I 397.007
II 397. 196
II 398.852
II 399.575
II 400.045
II 400.869
II 401.225
II 401.239
II 401.913
I 403.076
II 403.169
I 403.298
I 403.307
II 404.076
II 404.080
II 404.291
I/i n ti a 1 /i
*r U M1 H 1 H
I 404.442
I 404.597
I 404.721
I 405.453
I 405.783
II 406,109
II 406.281
II 407.571
II 407.585
II 407.735
II 407.771
II 407.796
II 408.672
II 409.014
I 410.174
I 410.176
II 410.946
II 411.846
II 412.323
II 412.970
II 413.066
I 413.262
I 413.256
II 413.380
II 413.765
II 414.311
II 415.608
I
n
T
*b
9.5
30.0
0.6
32.0
27.0
22.0
8.4
4.6
59.0
4.0
36.0
6.8
19.0
27.0
6. 3
4.0
23.0
19.0
On
* u
31 .0
2.5
0.7
1.5
11.0
31.0
6.3
4.2
4.2
21.0
72,0
7.5
30.0
8. 9
1.5
6.4
26.0
6.0
29.0
70.0
9.1
0.4
0.4
6.0
6.2
8.0
28.0
CONC
(mg/L:
10.0
0.5
10.0
10.0
10.0
10.0
10.0
100.0
10.0
100.0
10.0
10.0
100.0
10.0
10.0
100.0
10.0
IA A A A
UUU» U
1000.0
100.0
100.0
10.0
10.0
10.0
10.0
1.0
10.0
10.0
100.0
100.0
100.0
10.0
10.0
10.0
10.0
100.0
100.0
10.0
10.0
10.0
100.0
EST'D COMMENTS
) DET LIM
(mg/L)
0.031 Ca 396. 847, H 397.007
0.00050 H 397.007
Zaidel
0.0094 H 397.007
0.011
0.013
0.035
0,065
0.050
0.075
0.083
0.044
0.015
0. 111
0.047
0.075
0.130
0.015
Zaidel
Zaidel
42.857
Zaidel
0.272
0.096
0.047
0.071 NF
0.071 NB
0.014
0.00042
0.040
0.010
0.337
Zaidel
0.468 H 410.174
0,1 15
0.050
0.010
0,0043
0.032
7.500 Zaidel, NE
7.500 Zaidel, NR
0.050
0.048
0.037
0.107
56
-------
Appendix B cont'd,
Ar
Sr
Ar
Ga
Nd
Y
Pr
Ar
Ce
Pr
Ar
Ar
Ar
Ar
F.b
lu
Sr
Rh
£*- k*
Pr
Pr
Ca
U
Sc
Nd
Ar
Ar
Ar
Ar
Sm
Ce
Ar
Nd
Sr
Sc
Sc
Sc
Ar
Ar
H
Ar
Hg
Ar
Ar
Sc
S WAVE-
OF LENGTH
I' (nm)
I 415.859
II 416. 180
I 416.418
I 417.206
II 417.732
II 417.754
II 417.939
I 418.188
II 418.660
II 418.948
I 419.071
I 419.103
I 419.832
I 420.068
I 420.185
II 420,505
II 421.552
T ti 71 S^ft
-L H £, I . J JO
II 422.293
II 422.535
I 422.673
II 424.167
II 424.683
II 424.738
I 425.119
I 425.936
I 426.629
I 427.217
II 428.079
II 429.667
I 430.010
II 430. 358
II 430.545
II 431.409
II 432.074
II 432.501
I 433.356
I 433,531
I 434.047
I 434,517
I 435.835
I 436.379
436.836
II 437.446
n
>50.0
2.4
17.0
45.0
22.0
26.0
7.2
28,0
5.7
5.0
32.0
32.0
50.0
50.0
0.8
70.0
39.0
NM
1
6.3
7.0
1.5
6.5
110,0
17.0
7.5
50.0
32.0
43.0
43.0
4.3
40.0
40.0
4.8
38.0
31 .0
19,0
38.0
11.0
5.0
9.0
1. 1
1.0
3.2
17.0
CONG
(mg/L
10.0
100.0
100.0
10,0
10.0
10,0
10.0
1000.0
10.0
1.0
1 r\nr\ n
I UUU . U
10.0
10.0
0,5
100.0
10.0
100.0
100,0
10.0
100.0
10,0
10.0
10.0
10.0
100.0
10.0
EST'D
) DET LIM
(mg/L)
0.125
0.066
0.136
0.011
0.041
0.052
0.060
37.500
0,0043
0.00077
0.047
0.042
0.010
0.461
0.0027
0.. 176
0.069
0.069
0.075
0.062
0.0079
0.0097
0.015
2.727
0.017
COMMENTS
Zaidel
Zaidel
Zaidel
Zaidel, NB
Zaidel, NB
Zaidel
Zaidel
c »» hoi C C
sr **/ 1 _>:>
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
MIT
57
-------
Appendix B cont'd.
S WAVE-
OF LENGTH
Y
Pr
Ar
Sin
La
Sm
Eu
Nd
Ce
Sm
Ar
In
Ar
Ea
Cs
Ba
Cs
Ce
Ar
Ar
Li
Sr
Ar
Ar
Zn
Ar
Ar
Cd
Zn
Ar
H
Ar
Ar
Ar
Ba
La
La
Ea
Ar
Li
Ar
Ar
Ar
Ar
Ar
Ar
I
II
II
I
II
II
I.I
II
II
II
II
I
I
T
4.
II
II
II
I
II
I
I
I
I
T
Ju
I
I
I
I
I
I
I
I
T
j.
I
I
II
II
II
II
I
I
I
I
T
JL.
I
I
T
.k.
(nm)
437.
440.
442.
442.
442.
443.
443.
445.
446.
446.
451.
451.
452.
452.
452.
455.
455.
456.
458.
459.
460.
460.
462.
470.
472.
475.
476.
479.
481.
483.
486.
487.
488.
489.
489.
492.
492.
493.
495.
497.
498.
503,
504.
505.
506.
507.
494
882
399
434
990
432
556
157
021
734
074
131
232
493
673
403
531
236
929
610
286
733
844
232
216
294
867
992
053
669
133
626
795
469
997
098
179
409
675
170
995
203
881
418
008
308
n
T
CONC EST'D
(mg/L) DET LIM
Zb
46
4
0
55
13
36
24
19
4
41
21
16
6
1
0
230
0
4
0
6
3
4
4
7
0
1
0
0
1
0
17
3
3
1
3
12
12
130
0
1
0
0
2
1
2
0
.0
.9
.5
.0
.0
.0
.0
.0
.8
.0
.0
.0
.2
.9
.7
.0
.3
.1
.2
.0
.5
.4
.0
.2
.7
.0
,9
,5
.3
.6
.0
,2
.2
.5
.7
.0
.0
.0
.8
.4
.2
.5
.6
.7
.7
.6
10
10
100
10
100
10
100
10
100
100
10
1000
10
1000
10
100
10
10
10
10
10
10
10
10
100
*
*
«
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
COMMENTS
(mg/L)
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
42.
0.
100.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2.
0065
061
054
023
083
012
157
062
073
187
157
857
0013
000
073
857
068
428
600
230
081
025
025
0023
142
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
58
-------
Appendix B cont'd,
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
S
OF
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
,1
I
I
I
I
'I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
WAVE-
LENGTH
(nm)
508.709
511.820
512.780
515.140
516.228
517.754
518.775
521,049
521,477
522.127
524. 110
525.279
525.448
528.608
531.773
534.741
537.349
539.397
541,047
542.135
543.999
544.222
545.165
545.742
547.346
549.587
550.611
552.496
553.445
555.870
5 55 i 962
557.255
558.183
558.872
559.748
560.108
560.673
561.797
562.089
562,378
563.558
563.911
564. 134
564.866
565.070
565.913
I
V
xb
0,6
2.8
0.5
6.0
18.0
1 .9
24.0
0.5
0,3
9.0
0,5
3.8
3,2
0.8
0.5
0.3
1.4
0.7
1,4
6.6
2.2
2.5
15.0
2.8
2.3
31.0
6.0
5.0
0.7
33.0
4.9
21.0
0.8
3.5
3.9
0.9
36.0
1.4
1.0
0.4
0.9
0.5
1.0
1.7
21.0
2.4
CONG EST'D COMMENTS
(mg/L) DET LIM
(mg/L)
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel.
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
59
-------
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Ar
Na
Ka
Ar
Ar
Ar
S
OF
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
WAVE-
LENGTH
(nm)
568. 190
568.964
568.991
570.086
573.952
577.212
580.208
583.426
586.032
588.263
588.859
588.995
589.592
591.200
592.881
594.267
n
2.8
2.0
2.0
0.7
15.0
4.0
2,8
6.0
4.3
7.1
25.0
101.0
43.0
19.0
10.0
2.7
CONC
(mg/L)
EST'D
DET LIM
(mg/L)
100.0
100.0
0.029
0.069
Appendix B cont'd.
COMMENTS
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Zaidel
Ar 588.859
Zaidel
Zaidel
Zaidel
60
-------
TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
. REPORT NO.
EPA-600/4-79-Q17
3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
Inductively Coupled Plasma-Atomic Emission
Spectroscopy: Prominent Lines
5. REPORT DATE
March 1979 issuing date
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
R. K. Winge, V. J. Peterson, and V. A. Fassel
8. PERFORMING ORGANIZATION REPORT NO,
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Ames Laboratory, USDOE
Iowa State University
Ames, Iowa 50011
10. PROGRAM ELEMENT NO.
1CC824
11. CONTRACT/GRANT NO.
EPA-IAG-78-D-X0146
12. SPONSORING AGENCY NAME AND ADDRESS
Environmental Research LaboratoryAthens
Office of Research and Development
U.S. Environmental Protection Agency
Athens, Georgia 30605
GA
13. TYPE OF REPORT AND PERIOD COVERED
Final, 3/77-2/78
14. SPONSORING AGENCY CODE
EPA/600/01
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The prominent lines of 70 elements as emitted in an inductively
coupled plasma excitation source have been identified. The lines are
listed alphabetically by element and numerically by wavelength.
Detection limit capabilities are estimated for each spectral line.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.IDENTIFIERS/OPEN ENDED TERMS
COS AT I Field/Group
Chemical analysis
Spectroscopy
Chemical elements
07B
68D
3. DISTRIBUTION STATEMENT
RELEASE TO PUBLIC
19. SECURITY CLASS (This Report)
UNCLASSIFIED
21. NO. OF PAGES
71
20. SECURITY CLASS (Thispage)
UNCLASSIFIED
22. PRICE
EPA Form 2220-1 (9-73)
61
U.S. GOVERNMENT PRINTING OFFICE: 1979-6 57-060/1608
------- |