EPA-600/3-78-006
January 1978
Ecological Research Series
                        THE TRANSPORT  OF  OXIDANT
                               BEYOND  URBAN AREAS
               Light Hydrocarbon and Oxidant  Data
                           New England Study,  1975
                                 Environmental Sciences Research Laboratory
                                      Office of Research and Development
                                     U.S. Environmental Protection Agency
                                Research Triangle Park, North Carolina 27711
                                                           .

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                RESEARCH REPORTING SERIES

Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology.  Elimination  of traditional grouping was  consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:

      1.   Environmental  Health Effects Research
      2.   Environmental  Protection Technology
      3.   Ecological Research
      4.   Environmental  Monitoring
      5.   Socioeconomic Environmental Studies
      6.   Scientific and Technical  Assessment Reports (STAR)
      7.   Interagency Energy-Environment Research and Development
      8.   "Special" Reports
      9.   Miscellaneous Reports

This report has been assigned to the ECOLOGICAL RESEARCH series. This series
describes research on the effects of pollution on humans, plant and animal spe-
cies, and materials. Problems are assessed  for their long- and short-term influ-
ences. Investigations include formation, transport, and pathway studies to deter-
mine the fate of pollutants and their effects. This work provides the technical basis
for setting standards to minimize undesirable changes in living organisms in the
aquatic, terrestrial, and atmospheric environments.
This document is available to the public through the National Technical Injterma-
tion Service, Springfield, Virginia 22161.                          /

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                                        EPA-600/3-78-006
                                        January  1978
 THE TRANSPORT OF OXIDANT BEYOND URBAN AREAS
     Light Hydrocarbon and Oxidant Data
           New England Study, 1975
                      by
 H. Westberg, K. J. Allwine and E. Robinson
            Air Resources Section
       Chemical Engineering Department
         Washington State University
         Pullman, Washington  99164
           Contract No. 68-02-2239
               Project Officer

             Joseph J. Bufalini
 Atmospheric Chemistry and Physics Division
 Environmental Sciences Research Laboratory
Research Triangle Park, North Carolina  27711


 ENVIRONMENTAL SCIENCES RESEARCH LABORATORY
     OFFICE OF RESEARCH AND DEVELOPMENT
    U.S. ENVIRONMENTAL PROTECTION AGENCY
RESEARCH TRIANGLE PARK, NORTH CAROLINA  27711

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                                  DISCLAIMER

     This report has been reviewed by the Environmental  Sciences Research
Laboratory, U.S. Environmental Protection Agency, and approved for publication.
Approval does not signify that the contents necessarily  reflect the views and
policies of the U.S. Environmental Protection Agency, nor does mention of
trade names or commercial products constitute endorsement or recommendation
for use.

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                                   ABSTRACT

     During the months of July and August, 1975, a comprehensive air pollution
field monitoring program was conducted in southern New England.   Participants
in the program included research groups from Washington State University,
Battelle Columbus Laboratories, EPA-Research Triangle Park,  EPA-Las  Vegas  and
EPA-Region I.  Oxidants, hydrocarbons, oxides of nitrogen and other  gaseous
pollutant species were measured at several ground stations in Connecticut
and Massachusetts.  The use of three instrumented aircraft provided  information
concerning vertical dispersion and transport of pollutants.
     This report provides a tabulation of data collected by  Washington  State
University.  It includes surface data from a field laboratory near Groton,
Connecticut, plus vertical pollutant information obtained during daily  air-
craft sampling missions.
                                     iii

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                                  CONTENTS
Abstract	      iii
Figures	       vi
Tables	    xviii
Acknowledgements 	    xxiii

     1.  Introduction  	        1
     2.  Experimental Procedure  	        3
             Site Description and Program Design 	        3
             Mobile Laboratory 	        7
             Ground Instrumentation  	        7
             Aircraft Measurements 	        8
             Meteorological Measurements 	       10
             Data Handling Procedures  	       11
             Calibration Procedures  	       14
     3.  Data Summary	       17
             Meteorology	       17
               Synoptic Weather Summary  	       17
               Upper Level  Winds	       22
             Continuously Collected Ground Data  	       28
             Light Hydrocarbon Data at Ground Level   	       68
             Aircraft Flight Data	      100
             Aircraft Collected Hydrocarbon, Halocarbon and
               NO  Data	      279
                 X

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                                    FIGURES
Number                                                                 Pagt
   1      Maps of New England  study  area  ................   4
   2      Flight paths used  in New England study  ............   5
   3      Data flow in field ......................  13
   4      Flight #1  on July  15, 1975, with ozone  concentrations (ppb)
           marked at points along the  route  .............. 101
   5      Vertical ozone and temperature  profiles over Hampton
           (point b) at 4:00  pm on  July  15,  1975   ........... 102
   6      Plot of aircraft data recorded  during flight #1 on July 15,
           1975 ............................ 103
   7      Flight #2 on July  18, 1975, with ozone  concentrations (ppb)
           marked at points along the  route  .............. 104
   8      Vertical ozone and temperature  profiles over mouth of
           Connecticut River  (point b) at 2:00 pm on July 18, 1975  .  . 105
   9      Plot of aircraft data recorded  during flight #2 on July 18,
           1975 ............................ 106
  10      Flight #3 on July  18, 1975, with ozone  concentrations (ppb)
           marked at points along the  route  .............. 107
  11      Vertical ozone and temperature  profiles near Hartford
           (point d) at 4:25  pm on  July  18,  1975   ........... 108
  12      Plot of aircraft data recorded  during flight #3 on July 18,
           1975 ............................ 109
  13      Flight #4 on July  19, 1975, with ozone  concentrations (ppb)
           marked at points along the  route  .............. HO
  14      Vertical sounding  over Long Island  Sound  (point b) at
           10:10 am on July 19, 1975   ................. m
  15      Vertical  sounding  southeast of  Kingston (point g) at
           12 noon  on July  19, 1975 .................. HI
  16      Plot of aircraft data recorded  during flight #4 on July 19,
           1975 ............................ 112
  17      Flight #5  on July  19, 1975, with ozone  concentrations (ppb)
           marked at points along the  route  .............. 113
  18     Vertical ozone and temperature profiles northeast of Boston
           (point d) at 5:00 pm on July 19, 1975  ........... 114
                                    v

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                               FIGURES (cont.)
Number                                                                 Page

  "19     Plot of aircraft data recorded during flight  #5  on  July  19,
           1975 ............................  115

  20     Flight #6 on July 20, 1975, with ozone concentrations  (ppb)
           marked at points along the route ..............  115
  21     Vertical sounding near New Haven (point b)  at 3:15  pm  on
           July 20, 1975  .......................  117

  22     Angle ascent across Sound (point c to a)  at ^4:15 pm on
           July 20, 1975  .......................  117
  23     Vertical ozone and temperature profiles near  Groton
           (point a) at 4:25 pm on July 20, 1975  ...........  118
  24     Plot of aircraft data recorded during flight  #6  on  July  20,
           1975 ............... ~ .............  HQ

  25     Flight #7 on July 20, 1975, with ozone concentrations  (ppb)
           marked at points along the route ..............  120
  26     Vertical ozone and temperature profiles south of Groton  at
           8:15 pm on July 20, 1975 ..................  121
  27     Plot of aircraft data recorded during flight  #7  on  July  20,
           1975 ............................  122
  28     Flight #8 on July 21, 1975, with ozone concentrations  (ppb)
           marked at points along the route ..............  123
  29     Vertical sounding near Putnam (point  b) at  11:40 am on
           July 21, 1975  .......................  124
  30     Vertical sounding northeast of Boston (point  d)  at  1 :00  pm
           on July 21, 1975 ......................  124
  31     Vertical ozone and temperature profiles on  descent  into
           Trumbull Airport (point a) at 2:10  pm on  July  21, 1975  .  .  .  125
  32     Plot of aircraft data recorded during flight  #8  on  July  21,
           1975 ............................  126
  33     Flight #9 on July 21, 1975, with ozone concentrations  (ppb)
           marked at points along the route ..............  127
  34     Vertical sounding over Long Island Sound  (point  b)  at
           4:10 pm on July 21, 1975 ..................  128
  35     Vertical sounding over Madison (point c)  at 4:35 pm on
           July 21, 1975  .......................  128
  36     Vertical ozone and temperature profiles southeast of
           Hartford (point d)  at 5:00 pm on July 21, 1975 .......  i
  37     Plot of aircraft data recorded during  flight #9 on July 21,
           1975 ............................ ]3n
  38     Flight #10 on July 22, 1975,  with  ozone  concentrations (ppb)
           marked at points along the  route .............. 131
                                     VI1

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                               FIGURES  (cont.)
Number                                                                  Page
  39     Vertical  sounding  over  Long  Island  (point  b) at  7:55 am
           on July 22,  1975	132
  40     Vertical  sounding  over  Madison  (point d) at 8:50 am on
           July 22, 1975	132
  41     Plot of aircraft data recorded  during flight #10 on July 22,
           1975	133
  42     Flight #11 on  July 22,  1975, with ozone concentrations (ppb)
           marked at points along  the route  	  134
  43     Vertical  sounding  over  Madison  (point c) at 1:45 pm on
           July 22, 1975	135
  44     Vertical  sounding  over  Atlantic Ocean (point e) at 2:45 pm
           on July 22,  1975	135
  45     Vertical  ozone and temperature  profiles over Atlantic
           Ocean (point d)  at  2:30 pm on July 22, 1975	136
  46     Vertical  sounding  over  Atlantic Ocean (point g) at 3:00 pm
           on July 22,  1975	137
  47     Vertical  sounding  over  Atlantic Ocean (point f) at 3:30 pm
           on July 22,  1975	137
  48     Plot of aircraft data recorded  during flight #11  on July 22,
           1975	138
  49     Flight #12 on  July 23,  1975, with ozone concentrations (ppb)
           marked at points along  the route  	  13Q
  50     Vertical  sounding  near  Putnam (point b) at 8:40 am on
           July 23, 1975	140
  51     Vertical  sounding  NE of Boston  (point e) at 10:30 am on
           July 23, 1975	140
  52     Plot of aircraft data recorded during flight #12  on July 23,
           1975	141

  53     Flight #13 on  July 23,  1975, with ozone concentrations (ppb)
           marked  at points along  the route  	  143
  54     Vertical  sounding  near  Putnam (point b) at 3:45 pm on
           July 23, 1975	144
  55     Vertical  sounding  over  Long Island  (point e) at 4:45 pm  ...  144
  56     Vertical  ozone and temperature profiles on descent to landing
           at Groton (point a) at  5:10 pm on July 23, 1975	145
  57     Plot of aircraft data recorded during flight #13  on July 23
           1975	:.  146

  58     Flight #14 on  July 24,  1975, with ozone concentrations (ppb)
           marked  at points along  the route  	  147
  59     Vertical  sounding  NE of Putnam  (point b) at 9:55  am on
           July 24, 1975	148
                                   vm

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                               FIGURES (cont.)
Mumber                                                                 page

  60     Vertical sounding north of Boston (point d)  at  11:05  am
           on July 24, 1975	148

  61     Vertical ozone and temperature profiles  on descent  to
           landing at Groton (point a) at 12:30 pm on July 24,  1975  .  .  149

  62     Plot of aircraft data recorded during flight #14 on July 24,
           1975	150

  63     Flight #15 on July 24, 1975, with ozone  concentrations (ppb)
           marked at points along the route 	  151
  64     Vertical ozone and temperature profiles  HE of Putnam
           (point b) at 3:00 pm on July 24, 1975	152

  65     Plot of aircraft data recorded during flight #15 on July 24,
           1975	153

  66     Flight #16 on July 26, 1975, with ozone  concentrations (ppb)
           marked at points along the route 	  154

  67     Vertical sounding NE of Putnam (point b) at  10:15 am  on
           July 26, 1975	155
  68     Vertical sounding SE of Boston (point d) at  11:15 am  on
           July 26, 1975	155
  69     Plot of aircraft data recorded during flight #16 on July 26,
           1975	156
  70     Flight #17 on July 26, 1975, with ozone  concentrations (ppb)
           marked at points along the route 	  157
  71     Vertical sounding NE of Putnam (point b) at  3:35 pm on
           July 26, 1975	158
  72     Vertical sounding east of Boston (point  d) at 4:45  pm on
           July 26, 1975	158
  73     Plot of aircraft data recorded during flight #17 on July 26,
           1975	159
  74     Flight #18 on July 27, 1975, with ozone  concentrations (ppb)
           marked at points along the route 	  160
  75     Vertical sounding NE of Putnam (point b) at  9:45 am on
           July 27, 1975	161
  76     Vertical sounding SW of Boston (point d) at  11:15 am on
           July 27, 1975	161
  77     Plot of aircraft data recorded during flight #18 on July 27,
           1975	162
  78     Flight #19 on July 27, 1975, with ozone  concentrations (ppb)
           marked at points along the route 	  163

  79     Vertical sounding NE of Putnam (point b) at  3:20 pm on
           July 27, 1975	164
                                     IX

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                               FIGURES (cont.)
'lumber                                                                 page
  80     Vertical  sounding  north  of Boston  (point  d)  at  4:45  pm
           on July 27,  1975	164
  81     Plot of aircraft data  recorded during  flight #19 on  July 27,
           1975	165
  82     Flight #20 on  July 28, 1975,  with  ozone concentrations  (ppb)
           marked at points along the  route 	  166
  83     Vertical  ozone and temperature profiles over Atlantic Ocean
           (point d) at .11:05 am  on July  28,  1975	167
  84     Plot of aircraft data  recorded during  flight #20 on  July 28,
           1975	168
  85     Flight #21 on  July 28, 1975,  with  ozone concentrations  (ppb)
           marked at points along the  route 	  169
  86     Vertical  sounding  near Groton (point a) at 2:45 pm on
           July 28, 1975	170
  87     Vertical  sounding  SE of  Hartford (point b) at 3:20 pm on
           July 28, 1975	170
  88     Vertical  ozone and temperature profiles south of Long Island
           (point d) at 4:35 pm on July 28, 1975	171
  89     Plot of aircraft data  recorded during  flight #21 on  July 28,
           1975	172
  90     Flight #22 on  July 29, 1975,  with  ozone concentrations(ppb)
           marked at points along the  route 	  173
  91     Vertical  sounding  NE of  Putnam (point  b)  at  9:50 am  on
           July 29, 1975	174
  92     Vertical  sounding  SE of  Boston (point  d)  at  10:50 am on
           July 29, 1975	174
  93     Plot of aircraft data  recorded during  flight #22 on  July 29,
           1975	175
  94     Flight #23 on  July 29, 1975,  with  ozone concentrations  (ppb)
           marked at points along the  route 	  176
  95     Vertical  sounding  NE of  Putnam (point  b)  at  3:15 pm  on
           July 29, 1975	177
  96     Vertical  sounding  SE of  Boston (point  d)  at  4:05 pm  on
           July 29, 1975	177
  97     Plot of aircraft data  recorded during  flight #23 on  July 29
           1975	.'  .  178
  98     Flight #24 on  July 30, 1975,  with  ozone concentrations  (ppb)
           marked at points along the  route 	  179
  99     Vertical  sounding  NE of  Putnam (point  c)  at  9:45 pm  on
           July 30, 1975	180

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                               FIGURES (cont.)          i
Number                                                                 page
 100     Vertical sounding near Groton (point f)  at  10:45 pm on
           July 30, 1975	180
 101     Plot of aircraft data recorded during flight #24 on July 20,
           1975	181
 102     Flight #25 on August 2,  1975, with  ozone concentrations (ppb)
           marked at points along the route  	  182
 103     Vertical sounding NE of  Putnam  (point c)  at 12:35 pm on
           August 2, 1975	183
 104     Vertical sounding near Cape Cod  (point e) at 2:10 pm on
           August 2, 1975	183
 105     Vertical ozone and temperature profiles  SW  of Boston (point d)
           at 1:15 pm on August 2, 1975	184
 106     Plot of aircraft data recorded during flight #25 on August 2,
           1975	185
 107     Flight #26 on August 2,  1975, with  ozone concentrations (ppb)
           marked at points along the route  	  186
 108     Vertical sounding near Cape Cod  (point b) at 9:10 pm on
           August 2, 1975	187
 109     Vertical sounding SW of  Boston  (point c)  at 10:00 pm on
           August 2, 1975	187
 110     Vertical ozone and temperature profiles  NE  of Putnam (point d)
           at 10:45 pm on August  2, 1975	188
 111     Plot of aircraft data recorded during flight #26 on August 2,
           1975	189
 112     Flight #27 on August 3,  1975, with  ozone concentrations (ppb)
           marked at points along the route  	  190
 113     Vertical sounding NE of  Putnam  (point b)  at 10:45 am on
           August 3, 1975	191
 114     Vertical sounding SW of  Boston  (point d)  at 12:15 pm on
           August 3, 1975	191
 115     Plot of aircraft data recorded during flight #27 on August 3,
           1975	192
 11-6     Flight #28 on August 5,  1975, with  ozone  concentrations (ppb)
           marked at points along the route  	  193
 117     Vertical sounding near Groton (point b)  at  1:20 pm on
           August 5, 1975	194
 118     Vertical sounding near New Haven  (point  c)  at 2:10 pm on
           August 5, 1975	194
 119     Plot of aircraft data recorded during flight #28 on August 5,
           1975	195

                                      xi

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                               FIGURES  (cont.)
Number

 120     Flight #29 on  August  6,  1975,  with ozone concentrations (ppb)
           marked  at points  along  the route
 121      Vertical  sounding  NE  of  Putnam  (point b) at 9:50 am on
           August  6,  1975  .......................  197
 122      Angle  descent  into Trumbull Airport  (Groton) at ^12 noon
           on August  6,  1975   .....................  197
 123      Vertical  ozone  and temperature  profiles NE of Providence
           (point  e)  at  11:00  am  on August 6, 1975  ..........  198

 124      Plot of aircraft data recorded  during flight #29 on August 6,
           1975 ............................  199
 125      Flight #30 on August  6,  1975, with ozone concentrations (ppb)
           marked  at  points along the route ..............  200

 126      Vertical  sounding  near Groton (point b) at 2:15 pm on
           August  6,  1975  .......................  201
 127      Vertical  sounding  NE  of  Boston  (point d) at 3:45 pm on
           August  6,  1975  .......................  201
 128      Plot of aircraft data recorded  during flight #30 on August 6,
           1975 ............................  202
 129      Flight #31 on August  9,  1975, with ozone concentrations (ppb)
           marked  at  points along the route ..............  203
 130      Vertical  sounding  over Madison  (point b) at 11:55 am on
           August  9,  1975  .......................  204
 131      Vertical  sounding  over Long Island (point c)  at 12:30 pm on
           August  9,  1975  .......................  204
 132      Vertical  ozone  and temperature  profiles over Atlantic Ocean
           (point  d)  at  1:05 pm on August 9, 1975 ...........  205
 133      Plot of aircraft data recorded  during flight #31  on August 9
           1975 .............. . .............  206
 134      Flight #32 on August  9,  1975, with ozone concentrations (ppb)
           marked  at  points along the route ..............  207

 135      Vertical  sounding  over Madison  (point b) at 3:55 pm on
           August  9,  1975  ......... . ..............  208
 136      Vertical  sounding  over Long Island (point c)  at 4:30 pm on
           August  9,  1975  .......................  208
 137      Vertical  ozone  and temperature  profiles over Atlantic Ocean
           (point  d)  at  5:10 pm on August 9, 1975 ...........  20P

 138      Plot of aircraft data recorded  during flight #32 on August 9
           1975 ........................... '.210
 139      Flight #33 on August  10, 1975,  with ozone concentrations (ppb)
           marked  at  points along the route ..............  211
                                     xn

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                               FIGURES (cont.)
Number                                                                 Page

 140     Vertical  sounding over Atlantic  (point a)  at  11:45 am on
           August 10, 1975	212

 141     Vertical  sounding over Long Island (point  b)  at  12:15 pm
           on August 10, 1975	212
 142     Vertical  sounding near Groton (point  c)  at 12:50  pm on
           August 10, 1975	213

 143     Vertical  sounding near Putnam (point  d)  at 1:25  pm on
           August 10, 1975	213

 144     Plot of aircraft data recorded during flight  #33  on August 10,
           1975	214

 145     Flight #34 on August 10, 1975, with ozone  concentrations (ppt)
           marked at points along the route 	  215
 146     Vertical  sounding over Atlantic  (point a)  at  4:45 pm on
           August 10, 1975	216
 147     Vertical  sounding over Long Island (point  b)  at  5:15 pm on
           August 10, 1975	216
 148     Vertical  sounding near Groton (point  c)  at 5:45  pm on
           August 10, 1975	217
 149     Vertical  sounding near Putnam (point  d)  at 6:15  pm on
           August 10, 1975	217
 150     Plot of aircraft data recorded during flight  #34 on August 10.
           1975	218
 151     Flight #35 on August 11, 1975, with ozone  concentrations (ppb)
           marked at points along the route 	  219
 152     Vertical  sounding over Atlantic  (point a)  at  9:55 am on
           August 11, 1975	220
 153     Vertical  sounding over Long Island (point  b)  at  10:30 am on
           August 11, 1975	  220
 154     Vertical  ozone and temperature profiles  near  Groton (point c)
           at 11:00 am on August 11, 1975	  221
 155     Vertical  ozone and temperature profiles  near  Putnam (point d)
           at 11:40 am on August 11, 1975	  222
 156     Plot of aircraft data recorded during flight  #35 on August 11,
           1975	  223
 157     Flight #36 on August 12, 1975, with ozone  concentrations (ppb)
           marked at points along the route 	  224

 158     Vertical  ozone and temperature profiles  near  Groton (point d)
           at 12:15 pm on August 12, 1975	  225

 159     Flot of aircraft data recorded during flight  #36 on August 12,
           1975	  226

                                    xiii

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                               FIGURES  (cont.)
                                                                       Page
160     Flight #37 on August 12, 1975,  with  ozone  concentrations  (ppb)
          marked at points along the route  	  227
161     Vertical sounding over Atlantic (point  b)  at  3:45  pm on
          August 12, 1975	228
162     Vertical sounding over Atlantic (point  c)  at  4:20  pm on
          August 12, 1975	228
163     Plot of aircraft data  recorded  during flight  #37 on August 12,
          1975	229
164     Flight #38 on August 13, 1975,  with  ozone  concentrations  (ppb)
          marked at points along the route  	  230
165     Vertical sounding SW of Danbury (point  b)  at  10:00 am on
          August 13, 1975	231
166     Vertical sounding SE of Hartford  (point d) at 11:10 am on
          August 13, 1975	231
167     Plot of aircraft data  recorded  during flight #38 on August 13,
          1975	232
168     Flight #39 on August 13, 1975,  with  ozone  concentrations  (ppb)
          marked at points along the route  	  234
169     Vertical ozone and temperature  profiles near Norwich (point r>)
          at 4:05 pm on August 13,  1975	235
170     Vertical sounding over Martha's Vineyard (point g) at 5:30 pm
          on August 13, 1975	236
171     Vertical sounding near Groton (point h) at 6:20 pm on
          August 12, 1975	  .  236
172     Plot of aircraft data  recorded  during flight #39 on August 13
          1975	'?37
173     Flight #40 on August 14, 1975,  with  ozone concentrations (ppb)
          marked at points along the route  	  238
174     Vertical sounding SW of Danbury (point  b) at 10:30 am on
          August 14, 1975	239
175     Vertical sounding SE of Hartford  (point d) at 11:45 am on
          August 14, 1975	239
176     Plot of aircraft data  recorded  during flight #40 on August 14
          1975	.'  240
177     Flight #41  on August 14, 1975,  with  ozone concentrations (ppb)
          marked at points along the route  	  242
178     Vertical sounding near Norwich  (point b) at 4:25 pm on
          August 14, 1975	243
179     Vertical sounding over Martha's Vineyard (point c) at 5:30 pm
          on August 14, 1975	243
                                    xiv

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                                FIGURES  (cont.)
Number                                                                 Page
 180     Plot of aircraft data recorded  during flight  #41  on August 14,
           1975	244
 181     Flight #42 on August 15, 1975,  with ozone  concentrations  (ppb)
           marked at points along the route 	  245
 182     Vertical  sounding south of Long Island (point b)  at 10:50 am
           on August 15, 1975	246
 183     Vertical  sounding south of Long Island (point c)  at 11:45 am
           on August 15, 1975	246
 184     Vertical  ozone and temperature  profiles  SE of New York City
           (point d) at 12:30 pm on August 15, 1975 ....  	  .  247
 185     Plot of aircraft data recorded  during flight  #42  on August 15,
           1975	248
 186     Flight #43 on August 15, 1975,  with ozone  concentrations  (ppb)
           marked at points along the route 	  249
 187     Plot of aircraft data recorded  during flight  #43  on August 15,
           1975	250
 188     Flight #44 on August 18, 1975,  with ozone  concentrations  (ppb)
           marked at points along the route 	  251
 189     Vertical  sounding SW of Danbury (point b)  at  11:25 am on
           August 18, 1975	252
 190     Vertical  sounding SE of Hartford (point  d)  at 12:45 pm on
           August 18, 1975	  252
 191     Plot of aircraft data recorded  during flight  #44  on August 18,
           1975	253
 192     Flight #45 on August 18, 1975,  with ozone  concentrations  (ppb)
           marked at points along the route 	  254
 193     Vertical  ozone and temperature  profiles  near  Groton (point c)
           at 8:15 pm on August 18, 1975	255
 194     Plot of aircraft data recorded  during flight  #45  on August 18,
           1975	256
 195     Flight #46 on August 19, 1975,  with ozone  concentrations  (ppb)
           marked at points along the route 	  257
 196     Vertical  sounding NE of Providence (point  c)  at 11:20 am on
           August 19, 1975	258
 197     Vertical  sounding SW of Cape Cod (point  d)  at 11:55 am on
           August 19, 1975	258
 198     Plot of aircraft data recorded  during flight  #46  on August 19,
           1975	259
 199     Flight #47 on August 19, 1975,  with ozone  concentrations  (ppb)
           marked at points along the route 	  260

                                      xv                          , --  " "

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                               FIGURES (cont.)
Number                                                                  Pa£§.
 200     Vertical  sounding  near  Long  Island  (point  b) at  2:40  pm on
           August  19,  1975	261
 201     Vertical  sounding  near  Cape  Cod  (point  d)  at 4:00  pm  on
           August  19,  1975	261
 202     Plot of aircraft data recorded during flight #47 on August  19,
           1975	262
 203     Flight #48 on August 19,  1975, with ozone  concentrations  (ppb)
           marked  at points along  the route  	  263

 204     Angle ascent  at start of  flight  («\J:30  pm) on August  19,
           1975	264
 205     Vertical  sounding  SE of New  York City (point d) at 9:30 pm  on
           August  19,  1975	264
 206     Plot of aircraft data recorded during flight #48 on August  19,
           1975	265
 207     Flight #49 on August 20,  1975, with ozone  concentrations  (ppb)
           marked  at points along  the route  	  266

 208     Vertical  ozone and temperature profiles NW of Boston  (point b)
           at 1:40 pm  on August  20, 1975	267
 209     Plot of aircraft data recorded during flight #49 on August  20,
           1975	268
 210     Flight #50 on August 20,  1975, with ozone  concentrations  (ppt>)
           marked  at points along  the route  	  269
 211     Vertical  sounding  near  Long  Island  (point  b) at 4:30  pm on
           August  20,  1975	270
 212     Vertical  sounding  near  Cape  Cod  (point  d)  at 6:00 pm  on
           August  20,  1975	270

 213     Plot of aircraft data recorded during flight #50 on August  20,
           1975	271

 214     Flight #51  on August 21, -1975, with ozone concentrations  (ppb)
           marked  at points  along  the route  	  272

 215     Vertical  ozone and  temperature profiles NW of Boston  (point b)
           at 10:40  am on August 21,  1975	273

.216     Plot of aircraft data recorded during flight #51 on August  21,
           1975	274

 217     Flight #52  on August 21,  1975, with ozone concentrations  (ppb)
           marked  at points  along  the route  	  275

 218     Vertical  sounding  over Atlantic  (point  c) at 3:45 pm  on
           August  21,  1975	276

 219     Vertical  sounding  near Martha's Vineyard (point d) at 4:05  pm
           on  August 21,  1975	276

                                     xvi

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                               FIGURES (cont.)
Number                                                                 Page

 220     Vertical ozone and temperature profiles  near  Groton  (point e)
           at 4:40 pm on August 21, 1975	277

 221     Plot of aircraft data recorded during flight  #52 on  August 21,
           1975	278
                                     xvn

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                                   TABLES
dumber                                                                 Pa
         Ground  and Aircraft Measurements
           Ground-Level Measurements
           Aircraft Measurements
   2     Low Pass  Comparison of Ground and Aircraft Ozone Instruments  .    16
   3     Upper Level Winds at Groton During July and August,  1975 ...    22
   4     Surface Data Collected at Groton, CT on July 15, 1975  ....    29
   5     Surface Data Collected at Groton, CT on July 16, 1975  ....    30
   6     Surface Data Collected at Groton, CT on July 17, 1975  ....    31
   7     Surface Data Collected at Groton, CT on July 18, 1975  ....    32
   8     Surface Data Collected at Groton, CT on July 19, 1975  ....    33
   9     Surface Data Collected at Groton, CT on July 20, 1975  ....    34
  10     Surface Data Collected at Groton, CT on July 21, 1975  ....    35
  11      Surface Data Collected at Groton, CT on July 22, 1975  ....    36
  12     Surface Data Collected at Groton, CT on July 23, 1975  ....    37
  13     Surface Data Collected at Groton, CT on July 24, 1975  ....    38
  14     Surface Data Collected at Groton, CT on July 25, 1975  ....    39
  15     Surface Data Collected at Groton, CT on July 26, 1975  ....    40
  16     Surface Data Collected at Groton, CT on July 27, 1975  ....    41
  17      Surface Data Collected at Groton, CT on July 28, 1975  ....    42
  18      Surface Data Collected at Groton, CT on July 29, 1975  ....    43
  19      Surface Data Collected at Groton, CT on July 30, 1975  ....    44
  20      Surface Data Collected at Groton, CT on July 31, 1975  ....    45
  21      Surface Data Collected at Groton, CT on August 1, 1975 ....    46
  22      Surface Data Collected at Groton, CT on August 2, 1975 ....    47
  23      Surface Data Collected at Groton, CT on August 3, 1975 ....    48
  24      Surface Data Collected at Groton, CT on August 4, 1975 ....    49
  25      Surface Data Collected at Groton, CT on August 5, 1975 ....    50
  26      Surface Data Collected at Groton, CT on August 6, 1975 ....    51

                                   xviii

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Number
                                TABLES (cont.)
                                                                       Page
  27     Surface Data Collected at Groton, CT on August  7,  1975  ....   52
  28     Surface Data Collected at Groton, CT on August  8,  1975  ....   53
  29     Surface Data Collected at Groton, CT on August  9,  1975  ....   54
  30     Surface Data Collected at Groton, CT on August  10,  1975   ...   55
  31     Surface Data Collected at Groton, CT on August  11,  1975   ...   56
  32     Surface Data Collected at Groton, CT on August  12,  1975   ...   57
  33     Surface Data Collected at Groton, CT on August.13,  1975   ...   58
  34     Surface Data Collected at Groton, CT on August  14,  1975   ...   59
  35     Surface Data Collected at Groton, CT on August  15,  1975   ...   60
  36     Surface Data Collected at Groton, CT on August  16,  1975   ...   61
  37     Surface Data Collected at Groton, CT on August  17,  1975   ...   62
  38     Surface Data Collected at Groton, CT on August  18,  1975   ...   63
  39     Surface Data Collected at Groton, CT on August  19,  1975   ...   64
  40     Surface Data Collected at Groton, CT on August  20,  1975   ...   65
  41     Surface Data Collected at Groton, CT on August  21,  1975   ...   66
  42     Surface Data Collected at Groton, CT on August  22,  1975   ...   67
  43     Hydrocarbon Concentrations in Samples Collected at  Ground
           Sites on July 15, 1975	   69
  44     Hydrocarbon Concentrations in Samples Collected at  Ground
           Sites on July 16, 1975	   70
  45     Hydrocarbon Concentrations in Samples Collected at  Ground
           Sites on July 17, 1975	   71
  46     Hydrocarbon Concentrations in Samples Collected at  Ground
           Sites on July 18, 1975	,	   72
  47     Hydrocarbon Concentrations in Samples Collected at  Ground
           Sites on July 19, 1975	   73
  48     Hydrocarbon Concentrations in Samples Collected at  Ground
           Sites on July 20, 1975	   74
  49     Hydrocarbon Concentrations in Samples Collected at  Ground
           Sites on July 21, 1975	   75
  50     Hydrocarbon Concentrations in Samples Collected at  Ground
           Sites on July 22, 1975	   76
  51     Hydrocarbon Concentrations in Samples Collected at  Ground
           Sites on July 23, 1975	   77
  52     Hydrocarbon Concentrations in Samples Collected at  Ground
           Sites on July 24, 1975	   78
                                     xix

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                               TABLES   (cent.)

.Number

  53     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on July 25,  1975	    79
  54     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on July 26,  1975	    80
  55     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on July 27,  1975	    81
  56     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on July 28,  1975	    82
  57     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on July 29,  1975	    83
  58     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on July 30,  1975	    84
  59     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on July 31,  1975	   85
  60     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on August 1  and 2,  1975	   86
  61     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on August 3, 1975	   87
  62     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on August 4, 1975	   88
  63     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on August 5, 1975	   89
  64     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on August 6, 1975	   90
  65     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on August 7, 1375	   9]

  66     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on August 8, 1975	   92

  67     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on August 9, 1975	   93

  68     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on August 10 and 11, 1975	   94

  69     Hydrocarbon Concentrations  in  Samples Collected at Ground
           -Sites on August 12 and 13, 1975	   95

  70     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on August 14, 1975	   Q5

  71      Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on August 15 and 16, 1975	   97

  72     Hydrocarbon Concentrations  in  Samples Collected at Ground
           Sites on August 17 and 18, 1975	   Q8
                                     xx

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                                 TABLES  (cont.)
Number                                                                  Page

  73     Hydrocarbon Concentrations in Samples Collected at Ground
           Sites on August 19 and 20, 1975	    99

  74     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 15, 1975	280

  75     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 18, 1975	281

  76     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 19, 1975	282

  77     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 20, 1975	   283

  78     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 21 , 1975	284

  79     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 22, 1975	285

  80     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 23, 1975	286

  81     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 24, 1975	287

  82     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 26, 1975	288
  83     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 27, 1975	289
  84     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 28, 1975	290
  85     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 29, 1975	
  86     Light Hydrocarbon, Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations in Samples Collected by Aircraft
           on July 30, 1975	292
                                      xxi

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                                TABLES (cont.)

Number                                                                  Page.

  87     Light Hydrocarbon,  Fluorocarbon-11 , Carbon Tetrachloride
           and NOX Concentrations  in  Samples Collected by Aircraft
           on August 2,  1975	293
  88     Light Hydrocarbon,  Fluorocarbon-ll , Carbon Tetrachloride
           and NOX Concentrations  in  Samples Collected by Aircraft
           on August 3,  1975	294
  89     Light Hydrocarbon,  Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations  in  Samples Collected by Aircraft
           on August 5,  1975	295
  90     Light Hydrocarbon,  Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations  in  Samples Collected by Aircraft
           on August 6,  1975	296
  91     Light Hydrocarbon,  Fluorocarbon-11 , Carbon Tetrac|loride
           and NOX Concentrations  in  Samples Collected by Aircraft
           on August 9,  1975	297
  92     Light Hydrocarbon,  Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations  in  Samples Collected by Aircraft
           on August 10, 1975	298
  93     Light Hydrocarbon,  Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations  in  Samples Collected by Aircraft
           on August 11, 1975	299
  94     Light Hydrocarbon,  Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations  in  Samples Collected by Aircraft
           on August 12, 1975	300
  95     Light Hydrocarbon,  Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations  in  Samples Collected by Aircraft
           on August 13, 1975	301

  96     Light Hydrocarbon,  Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations  in  Samples Collected by Aircraft
           on August 14, 1975	302

  97     Light Hydrocarbon,  Fluorocarbon-11 , Carbon Tetrachloride
           and NOX Concentrations  in  Samples Collected by Aircraft
           on August 15,  1975	303

  98     Light Hydrocarbon,  Fluorocarbon-11, Carbon Tetrachloride
           and NOX Concentrations  in  Samples Collected by Aircraft
           on August 18,  1975	304

  99     Light Hydrocarbon,  Fluorocarbon-11, Carbon Tetrachloride
           and NOX  Concentrations  in  Samples Collected by Aircraft
           on August 19,  1975	305

100     Light Hydrocarbon,  Fluorocarbon-11, Carbon Tetrachloride
           and NOX  Concentrations  in  Samples Collected by Aircraft
           on  August  20,  1975	306
                                    xx n

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                                ACKNOWLEDGEMENTS

     We wish to thank the Environmental Protection Agency, Environmental
Sciences Research Laboratory, Research Triangle Park, North Carolina,  for
financial support of this work.  The guidance and technical advice provided
by Dr. J. J. Bufalini was much appreciated.  Assistance by the EPA Region  I
Air Branch is also gratefully acknowledged.  We also thank the University
of Connecticut—Marine Sciences Institute for providing space and electrical
power for our laboratory trailer.
     Members of the Washington State University  Air Pollution Section that
contributed to this program include:  G. All wine, D. Eli as, S. Farwell, R. A.
Rasmussen, K. Sexton, P. Weir and M. Wiggins.
                                    xxi n

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                                  SECTION  1
                                INTRODUCTION

     A critical  question  facing EPA  personnel  in Region I is whether
 transportation  control  strategies in the  New  England area should be
 promulgated  on  a local  basis  (e.g. the  immediate Boston vicinity) or on
 a  larger  regional  scale (e.g.  portions  of New York, Connecticut and
 Massachusetts).   To  help  answer this question, an EPA coordinated study
 was conducted  in the northeastern United  States during the summer months
 of 1975.   Primary importance was placed on collection and interpretation
 of photochemical  oxidant  data.   If it could be shown that a significant
 portion of the  oxidant  burden  in a localized  area was due to oxidant and/or
 oxidant precursors transported  into  those areas from some upwind point, it
 certainly would  be most logical  to devise regional control plans.  On the
 other hand,  if  the evidence indicated that only minor amounts of oxidant
 were the  result  of transport processes, initiation of region-wide control
 strategies would  not be warranted.
     Primary objectives of the  field program  were to monitor ozone and
 ozone precursors  throughout the New  England region and determine to what
 extent the oxidant problem in the Boston  area is attributable to transport.
 Specific  areas of  interest included  (1) oxidant formation and transport
 within the Boston and New York  City  urban plumes, (2) oxidant behavior in
 relation  to  high  pressure systems, (3)  coastal Seabreeze effect on oxidant
 levels, (4)  relationships between ozone layers aloft and temperature
 inversions,  and  (5)  ozone transport  in  the Connecticut River valley.
     The  field study which began  on  July  15 involved research teams from
Washington State University (WSU), Battelle,  EPA—Research Triangle Park,
 EPA--Las  Vegas, and  EPA—Region  I.   WSU's part in the program involved
collection of air quality data  at a  ground station near Groton, Connecticut,
and from  aircraft flights over much  of  the southern New England region.

                                      1

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     The purpose of this report is to provide a tabulation of the data
collected by Washington State University during the six-week sampling
period.   Subsequent reports will  discuss in detail  various portions of
the data presented herein.

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                                  SECTION  2
                           EXPERIMENTAL  PROCEDURE

SITE DESCRIPTION AND  PROGRAM  DESIGN
     To  satisfy the sampling  objectives of the  program, a triangular
network  of monitoring base stations was set  up  in southern New England.
This is  shown on the  map  in Figure  1  .   Washington State University's
base station was located  on the  southern  Connecticut coast south of Groton.
Battelle's base of operations was near  Simsbury, Connecticut, and the two
EPA groups were in the Boston vicinity.   It  was felt a triangular design
such as  this provided optimum coverage  of the study area.  WSU had access
to air masses that originated in the New  York City area and passed out
over the Atlantic Ocean and Long Island Sound.  Battelle could monitor
air parcels coming into the region from the  northwest while the EPA groups
were positioned to provide upwind and downwind coverage of the Boston
metropolitan area.
     Our main sampling trailer was located near the tip of Avery Point
south of Groton (Figure 1  ).  We also collected bag samples for hydrocarbon
analysis at a rural inland site  northwest of Groton.  This was near the
Devil's  Hopyard State Park about halfway  between Groton and Hartford.
     Aircraft flight  paths were  designed  to  provide maximum coverage of
the southern New England  region.  During  the first half of the study period
when two airplanes were operating, WSU concentrated on the eastern portion
of the region.  As shown  in Figure  2A, we flew north from Groton to the
proximity of the Massachusetts border and then headed east toward Boston.
The section of this first  leg from Putnam to the turn-point overlapped
with Battelle's flight path and  thus allowed cross-checking of instruments
in the two aircraft.   The  remainder of our route consisted of a counter-
clockwise arc of 18 miles  radius around Boston, followed by return to

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                                            <=£>
                          ATLANTIC  OCEAN   (N)
                                       Scale:  l" - 38 mi
       + INLAND SITE
      DEVIL'S HOPYABD
Figure 1.  Maps of  New England study area.

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                 A
NEW
YORK
                             MASSACHUSETTS
         O WORCESTER
MASSACHUSETTS
                                                              ATLANTIC    OCEAN
               Figure  2.   Flight  paths  used  in New  England study.

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Groton vlr, prny-jdence.  Vertical profiles were flown at two points along
the flight p*':h.  The location of these soundings was generally in an area
upwind and downwind of Boston.
     When not flying the Boston loop, we generally covered an area south of
Groton, as shown in Figure IB.  The objective here was to monitor pollutant
behavior over water.  In early August when the EPA-Las Vegas plane arrived,
our primary routes covered the southwestern portion of the New England
region during morning hours (Figure 2C ) and the southeastern area during
afternoons (Figure 2D).  Spiral ascents were used at various points along
these flight routes to monitor the vertical distribution of pollutants.
     When over  land, the flight paths just described were usually flown
at  1500 ft MSL.  Over the ocean and Long Island Sound, the plane commonly
dropped down to 500 ft and, on occasion, to as low as 200 ft above the
water.  When weather permitted, morning and afternoon sampling flights
were employed.  The length of time in the air generally varied between 2
and 3 hours.  From July 15 to August 21 we carried out a total of 52 flights.
      In concluding this section on program design, Table  1  summarizes the
measurements we made.  All ground-level parameters were monitored continu-
ously with the  exception of individual light hydrocarbons.  Samples for
hydrocarbon analysis were generally collected over two-hour periods during
morning,  afternoon and evening hours.  Not listed in the table is the
measurement of  upper-level winds; however, this information was obtained
from pibal observations each morning and afternoon.
     Data from  aircraft instrumentation was continuously recorded on
magnetic  tape.  The bag samples for hydrocarbon analysis were collected
at  various points along the flight path.

	TABLE  1 .  GROUND AND AIRCRAFT MEASUREMENTS	

                         Ground-Level Measurements
Ozone                                     Wind Speed
Oxides of Nitrogen                        Wind Direction
Total Hydrocarbon                         Turbulence
Methane                                   Dew Point
Carbon Monoxide                          Solar Radiation
Individual C2-C6 HC                       Temperature
Halocarbons                               Vertical Temperature Discontinuity
                                             (Acoustic Radar)

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TABLE  1.  cont.

                           Aircraft Measurements
Ozone
Condensation Nuclei
Visual Range (Nephelometer)
Temperature
Relative Humidity
Navigational Parameters  (VOR, DME, Altitude, etc.)
Bag/Can Samples  (Hydrocarbons, Halocarbons, NO  , etc.)
                                              A
MOBILE LABORATORY
     A 23-ft custom-built  travel trailer served as our field headquarters.
This laboratory contained  52 ft of bench and rack space for accommodation
of our monitoring  instruments, meteorological sensors and data acquisition
and reduction  system.  Most of this equipment is permanently mounted  in  the
trailer for easy transport from site to site.  The laboratory can  be  set up
with most  instruments fully operational in one day.  Constant temperature
within the trailer is maintained by two large air conditioners mounted on
the roof.
     Outside air is  brought into the trailer through a 4-in. stainless
steel line-  The top of  the air inlet stack is about 20 ft above ground
level.  This sample  line runs the full interior length of the trailer and
serves as  a manifold for supplying outside air to the continuously monitor-
ing instruments.   An air flow rate through the line of approximately  100
cfm is maintained  by a squirrel-cage fan at the exhaust end.
     Equipment is  laid out within the trailer such that those instruments
monitoring the most  reactive gases (ozone and nitric oxide) are closest  to
the inlet  end of the manifold.
GROUND INSTRUMENTATION
     This  section  provides a brief description of the instruments  used to
make the ground measurements listed in Table 1 .
Ozone Measurements - Meloy Model OA350 Ozone Analyzer.  Operation  of  this
     instrument is based on the gas-phase chemiluminescent reaction between

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     ozone and ethylene.   It provided  dependable,  trouble-free operation
     throughout the study period.
HO, :;02 and NO  Measurements -  TECO  Model  14D  and  Monitor  Labs Model  3440.
     Both of these instruments  employ  the  chemiluminescent reaction
     between nitric oxide and ozone  as the detection  technique.   After
     some start-up problems  were  corrected, the  TECO  14D provided good
     service-   The Monitor Labs instrument was  used for the first week
     when the 14D was undergoing  repair.
Methane, Carbon Monoxide  and Total Hydrocarbon Measurements -  Beckman
     Model 6800 Air Quality  Gas Chromatograph.   This  automated gas chro-
     matograph employs a  flame  iom'7ation  detector for hydrocarbon analysis.
     Carbon monoxide is reduced to methane prior to entering the  detector.
     With the exception of the  last  week of the  study period,  this
     instrument provided  trouble-free  operation.
Halocarbon Measurements - Hewlett Packard  Model  5700A Gas  Chromatograph.
     This instrument was  equipped with a constant-current  63Ni  electron
     capture detector.  Separation of  fluorocarbon-11, chloroform, carbon
     tetrachloride and 1 ,1,1-trichloroethane was achieved  on a 10-ft x
     1/8 in. stainless steel  column  containing  10% SF-96 Chromosorb W.
     The column was maintained  at 55°C.  With a  carrier gas (95%  argon-
     5% methane) flow of  20  ml/min,  four analyses  could be run each hour.
     This instrument was  automated by  attaching  a  1-ml sample  loop, a  Carle
     microvalve (#5518),  a Carle  valve actuator  (#4201) and a  Carle valve-
     minder (#4101).  A manual  injection technique was used for aircraft-
     collected samples.
Individual Light Hydrocarbon Measurements  - Perkin-Elmer Model  900 Gas
     Chromatograph.  The  standard dual-flame instrument was used  with
     the addition of a subambient accessory.  The  normal carrier  gas
     flow system was modified to  include a freezeout  trap  for  concen-
     trating the organics in ambient air.   The column used to  separate
     light hydrocarbons was  a packed capillary  (201 x 1/16") containing
     Durapak n-octane/Porasil C.  When operated  with  a carrier flow of
     "-10 ml/min He and temperature-programmed  from -70 to  80°  at  24°/min
     this column provided excellent  resolution of  the C2-C5. hydrocarbon
     fraction.   This hydrocarbon  analysis  method was  not automated.

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     All  the ground instruments, with the exception of the Perkin-Elmer
900 gas chromatograph, obtained air samples on a continuous basis from
the trailer manifold described under MOBILE LABORATORY.  Samples for light
hydrocarbon analysis were taken from the trailer manifold, plastic bags
or stainless steel cans.  The latter two collection devices provided the
means for collecting samples at remote ground sites and in the aircraft.
     All  bags used for ambient air collection were fabricated of Teflon
Type A (2 mil.) and sealed with a bandsealer marketed by Packaging Aids
Corporation.  The sample bags varied from 5 to 30 liters capacity.  Teflon
Swagelok-type fittings capped with Teflon-faced silicone septa were u;;ed
as sampling ports.  These bags were cleaned by flushing with hydrocarbon-
free air.  Contamination-free Kohmyr all Teflon pumps were used to fi ri
bags in the field.
     Canisters were used in addition to Teflon bags in the aircraft.  These
canisters were constructed of stainless steel with all the inner surfaces
polished using the "Summa" process.  The cans were filled with air using
a metal bellows pump and sealed by closing two bellows valves.  By pres-
surizing these containers to 10 psig, about 5 liters of air could be
obtained for sampling purposes.  Use of thes-e canisters provides several
advantages over plastic bags.  Foremost among these advantages is that
samples collected for halocarbon analysis are not subject to contamination
by fluorinated materials emitted from Tedlar and Teflon bag surfaces.
METEOROLOGICAL MEASUREMENTS
     Instrumentation used to measure the various meteorological parameters
included three separate systems:
     1)  Climet CI-60 Data System - This instrument package contains
         sensors for measuring wind speed, wind direction, dew point,
         temperature and solar radiation.  Turbulence was also determined
         from wind speed and wind direction perturbations.  Output from
         the various sensors is channeled into a translator which conditions
         the signals and provides an output voltage compatible with a
         multi-pen recorder or other data-logging device.
     2)  Aerovironment Model 300 Monostatic Radar - This acoustic sounder
         measures the turbulent fluctuation of atmospheric temperature on

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         electrosensitive chart paper.  A continuous record of the
         intensity of echo return as a function of height and time
         is obtained.  The instrument has a maximum vertical  range
         of 1000 meters.
     3}  Warren-Knight Model  84 Double Center Theodolite - Pilot
         balloons were used in conjunction with this theodolite for
         monitoring upper-level wind speed and direction.  The balloons
         were of the 30g type and the standard rise rate table was used
         for computations.
AIRCRAFT MEASUREMENTS
     The WSU Air Pollution Section's Cessna 336 Skytnaster was used in
this study.  The 336 is a twin-engine, centerline thrust, high-wing aircraft,
This airplane is capable of carrying the pilot, instrument operator, about
400  Ibs. of instrumentation and enough fuel for 4 hours of survey work.  Air
for  sampling instruments is brought in through a 4-in.  diameter air scoop
extending out approximately 10-in. from the fuselage.   The air scoop and
connecting 3-in. Plexiglas pipe inside the airplane cabin were designed
to bring a large flow of sample air into the plane.
     The plane was equipped with two 60-amp alternators.  A Topaz solid-
state inverter was used to convert the 28-VDC alternator output to 120
VAC  for operating the air pollutant analyzers.  This inverter provided
about 1500 watts of usable power, which was more than  sufficient for our
needs.
     The most commonly employed flight paths were described in an earlier
section (see Fig. 2 ).  When flying at 1500 ft MSL, airspeed  generally was
in the 120- to 140-mph range.  Spiral ascents were carried out at 500 ft/min
using half-standard rate turns (4 min).  Standard 2-min turns were used to
achieve a 500-ft/min descent rate.
     Aircraft measurements were listed in Table  1.  In succeeding para-
graphs appropriate comments will  be made concerning sampling  instrumentation
and techniques.
Ozone Measurements - A Bendix Model 8002 chemiluminescent analyzer was used
     to monitor ozone levels aloft.  The response time (<10 sec) of this
     instrument is sufficiently rapid for meaningful aircraft measurements.
                                    10

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     The only problem encountered with this analyzer was zero shifts
     accompanying cabin temperature changes.  This problem could be
     alleviated somewhat by keeping the instrument running while the
     aircraft was on the ground; however, on very warm days it was
     necessary to include a spiral climb immediately after take-off
     to cool the interior of the aircraft.
Condensation Nuclei - An Environment One Rich 100 analyzer was used to
     measure very small particulate material in the atmosphere.
Visual Range - A MRI Integrating Nephelometer modified to increase its
     sensitivity was used to monitor light scattering and visual range.
     Air was not dried before entering the analyzer tube so changes in
     atmospheric humidity must be taken into account when examining
     these data.
Temperature, Relative Humidity and Navigational Parameters - A Metro-
     data M8 Airborne Meteorological and Navigational System was used to
     measure temperature, humidity, airspeed, altitude, bearings from
     two points (VOR) and distance from one point (DME).  The temperati ,e
     and humidity data are derived from sensors mounted under the aircr "t
     wing.  The airspeed and altitude systems use potentiometric trans-
     ducers which are connected to the aircraft pitot-static system.
     VOR/DME data are acquired from navigational receivers installed  in
     the aircraft.  Mapping of flight paths was accomplished through  the
     use of continuously collected VOR and DME signals plus a visual
     record kept by the pilot and instrument operator aboard the aircraft.
Bag/Can Samples for Hydrocarbon and Halocarbon Analysis - A manifold  was
     constructed in the rear portion of the aircraft cabin that permitted
     rapid collection of bag samples for subsequent analysis in the ground
     laboratory.  Five-liter bags could be filled in about 15 sec by  ram
     air from the sample line, while bags of 30-liter capacity took about
     one minute to fill.  Stainless steel canisters (see GROUND INSTRUMEN-
     TATION) were filled using a metal bellows pump.
DATA HANDLING PROCEDURES
     All data collected in the aircraft and from most continuously
monitoring ground instruments was recorded on 4-track magnetic tape using
                                     11

-------
Metrodata Model  DL620A data  logging  systems.  Data from the Beckman air
quality  gas chromatograph and the Hewlett Packard electron capture gas
chromatograph was  recorded on strip  chart recorders.  Thus, final reduc-
tion  of  THC, CO, CH^ and halocarbon  data was performed manually.  Output
from  the Perkin-Elmer 900 gas chromatographs was channeled directly into
a  Hewlett Packard  3352 data  system.  This system provides individual hydro-
carbon  identification and quantisation information immediately following
each  gc  run.  Figure 3  summarizes the general data flow for all our field
collected data.
      We  have developed the software  necessary to allow our HP 2100 mini-
computer (basic  component of HP 3352 data system) to process 4-track
magnetic tape data in the field.  This permits field personnel to look at
nearly a complete  data set each day, which is very advantageous from the
standpoint  of recognizing instrumental malfunctions as well as short term
pollutant relationships that warrant further study.  The hardware involved
in this  operation  includes a Metrodata Model TR625  tape reader, the Hewlett
Packard  2100 computer, a Printec 100 high speed printer and a teletype for
communicating with the system.  The  data processing operation involves con-
verting  raw voltages to scientific units, plus time averaging and tabulating
for easy review.
      The frequency of data recording in the field was dependent on the
sampling technique.  In the  aircraft where considerable distance was
covered  in  a short time, instrument  and sensor responses were recorded
five  times  every two seconds.  Under normal flying conditions, this cor-
responds to a data  point approximately every 70 ft.  On the ground where
pollutant and meteorological  parameters were monitored at a fixed point,
data  recording times varied  from one minute for ozone, oxides of nitrogen
and the  meteorological sensors to fifteen minutes for halocarbo.n
measurements.
      Field data collected on 4-track magnetic tape was transferred to 9-
track tape in our  home laboratory.  This provides a permanent storage
mechanism plus a data format that is compatible with Washington State
University's IBM-360 computer.  Often the IBM-360 is used for additional
data analysis.
                                     12

-------
                      DATA  FLOW
                                    THE   FIELD
        o
        z
a
z
3
O

-------
CALIBRATION PROCEDURES
     A comprehensive data quality control  program is an essential  part of
all field studies.  Instrument calibration and zero checks must be
documented so that any questions concerning data quality can be resolved.
We kept daily records of these events and  have used this information in
arriving at the numbers provided in this report.  Any data that appeared
questionable was not included.  A summary  of precautions taken to  insure
data integrity for the various measurements is provided below.
Ozone -  The ground based and airborne ozone analyzers were calibrated at
         least once a week using a McMillan Model  1000 ozone generator.
         This ozone source was specially designed  to provide outputs
         in the 20 to 200 ppb range.   Absolute calibration of the  McMillan
         generator was based on the standard KI  method plus spectral
         measurements using a Dasibi  Model  1003-AH ultraviolet ozone
         photometer.  In addition, EPA-Region I  made three calibration
         comparisons with our instruments  during the field study period.
         The results of these comparisons  will  be  reported by EPA-Region  I.
         From a qualitative standpoint it  was obvious  that our instrument
         readings agreed closely with EPA's.  Cross-checks between our
         ground and aircraft ozone monitors were made  nearly every day by
         flying low passes near the trailer laboratory.   Table 2  lists
         the days and results of these cross comparisons.   It is obvious
         from this table that differences  were very small.
         A zero check was made once a day  on the ground  ozone instrument.
         However, in the aircraft numerous  checks  were made during each
         flight.   The airborne ozone  data  has been adjusted for zero
         drift whenever necessary.
         Ozone analyzers of the type  used  in this  study  respond to changes
         in atmospheric pressure.   Ground  level  pressure changes are minor
         and need not be of concern;  however, when an  instrument is
         carried  aloft by aircraft, pressure factors must  be considered.
         All  of our aircraft collected ozone data  has  been corrected for
         altitude using equations  developed from pressure  chamber  studies.
         This work has been reported  in detail  elsewhere (Monthly  Technical
                                   14

-------
     Report, April 1974; EPA Contract No. 68-02-1232, Dr. J. J. Bufalini,
     Project Officer).
Oxides of Nitrogen - Our calibration source for the Teco and Monitor
     Labs instruments was a tank containing 5.8 pptn NO.  Linearity checks
     were made by diluting the 5.8 ppm standard in Teflon bags.  A cali-
     bration check was performed once a week and zero checks daily.
Total Hydrocarbon, Methane and Carbon Monoxide - The Beckman 6800AQGC was
     calibrated using a tank containing 7.9 ppmC (THC), 2.19 ppm methane
     and 3.00 ppm carbon monoxide.   Calibration checks were made about
     every other day.  Toward the end of the study we received a standard
     from EPA-RTP that was reported to contain 0.44 ppm CO.  We ran this
     standard and determined a concentration of 0.47 ppm, which is ce^t-inly
     in good agreement.
Fluorocarbon-11 and Carbon Tetrachloride - The electron capture gas
     chromatograph was calibrated by making up standards in ambient air.
     At the present time we feel this is the best method since the moist"re
     and oxygen content of the standard will be nearly the same as in
     samples collected during routine analysis periods.  The calibratio.
     was based on a Freon-11 standard that had been certified by mass
     spectrometry.  At the beginning of the field study, measured volumes
     of the 11 ppm standard were added to a 45 1 carboy filled with ambient
     air.  From this a peak height versus concentration curve was obtained
     for the concentration region of interest (100-400 ppt).  During this
     initial calibration period a stainless steel canister was filled with
     ambient air and the fluorocarbon-11 concentration was determined
     based on the calibration described above.  Samples from this canister
     were run daily throughout the study period in order to monitor
     stability of the electron capture detector.  Carbon tetrachloride
     calibration was carried out in a similar manner.
Individual Light Hydrocarbons - Identification of the light hydrocarbons
     was based on retention time comparisons.  Resolution of light hydro-
     carbons on the Durapak n-Octane/Porasil C column was excellent and
     retention times were extremely reporducible.  Thus, little difficulty
     existed in making unambiguous peak identifications.  Calibration of the
     Perkin-Elmer gas chromatographs was achieved by measuring instrument

                                    15

-------
     response of known concentrations of hexane in air.   Three different
     hexane sources were used to prepare standards in the ppb range.
     In the field, an internal  standard (neo-Hexane, .209 ppm) was
     included in each air analysis  in order to insure calibration
     reliability.
Meteorological  Parameters - Calibration curves supplied  by the
     manufacturer were used to  convert the Climet CI-60  sensor output
     signals to the appropriate temperature, wind speed, etc. readings.
     While in the field, sensor signals were checked  routinely to
     insure correct operation.
Particulate Measurements - The  condensation nuclei counter and nephelo-
     meter were calibrated in the home laboratory prior  to going into
     the field.  No calibration checks were made in the  field since
     their primary function was not to provide absolute  numbers but
     rather to determine gross  horizontal  and vertical CN and/or light
     scattering inhomogenities  within an air mass.  We were concerned
     only with relative differences.

TABLE  2 .  LOW PASS COMPARISON  OF GROUND AND AIRCRAFT OZONE INSTRUMENTS
Date (Fit #) 03 Concentration (ppb)   Date (Fit #)  Q3  Concentration (ppb)
                 AIR       GND                        AIR       GND
7/15
7/18
7/19
7/19
7/20
7/20
7/21
7/21
7/22
7/22
7/23
7/23
7/24
7/24
7/26
( 1)
( 2)
( 4)
( 5)
( 6)
( 7)
( 8)
( 9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
19
151
58
54
43
23
84
114
43
111
53
99
84
69
33
20
155
53
55
39
28
92
119
44
113
59
100
86
63
35
7/26
7/27
7/28
7/30
8/5
8/6
8/9
8/10
8/11
8/14
8/19
8/19
8/20
8/20
8/21
(17)
(19)
(20)
(24)
(28)
(29)
(32)
(33)
(35)
(40)
(46)
(47)
(49)
(50)
(51)
49
60
69
51
107
66
90
98
65
77
60
81
63
44
52
50
65
70
54
105
62
96
113
66
73
56
76
59
47
50
                                16

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                                   SECTION 3

                                 DATA SUMMARY
METEOROLOGY

     This section contains a brief description of synoptic weather patterns

and a daily summary of upper winds (5001 to 5000') at Groton during Jul;

and August, 1975.  All times in this section refer to Eastern Daily Ti -e

     Surface meteorological observations made at the ground trailer in

Groton are reported as hourly averages in the subsection entitled LIGHT

HYDROCARBON DATA AT GROUND LEVEL.  Included there are averages for wind

speed, wind direction, turbulence, temperature, dew point and solar radio'ion.

     Aircraft flights provided upper level temperature profiles for trw „

days during the sampling period.  These are plotted in the subsection AIK«JRAFT

FLIGHT DATA.

Synoptic Heather Summary for the New England Area; July 14-August 21, 1975
Monday 7/14 -
Tuesday 7/15 -
Wednesday 7/16 -
Weather maps showed a strong high pressure system centered
approximately 500 miles to the east of Boston.  Another
less dominant high existed to the west of the region
in Ohio.  Between these two systems, a weak stationary
front extended from Canada through western Pennsylvania
and on into the mid-Atlantic states.  General wind flow
to 5000' in southern Connecticut was from the southwest.

The Atlantic high weakened slightly and moved more to the
east.  The weak instability line also moved eastward
into eastern New York and down through central Pennsylvania,
This disturbance contributed to early morning showers
throughout much of the New England region.  Wind flow
below 5000' continued from the southwest.

The high to the west of the region began to merge with
the larger Atlantic system.  As a result, the instability
line rapidly decayed.  An upper level low over the midwest
gained strength.  Winds from the surface to 2000' were
from the south with higher level winds more from the
southwest.
                                     17

-------
  h'jrsday 7/17  -
 "riday 7/18  -
 Saturday 7/19 -
 Sunday  7/20  -
Monday  7/21  -
Tuesday 7/22 -
Wednesday 7/23 -
Thursday 7/24 -
Friday 7/-I
         1C
         ~
The upper  level  low over  Indiana  started  retrenching.
Consequently, the Atlantic high spread southwestward
and weakened.  Upper  level wind flow was  primarily
from the west while surface flow  was somewhat more  from
the southwest.

A ridge began to build over New England as the off-
coast high continued  to weaken and move to the east.
A weak upper level subsidence set in.  Wind flow
below 5000' was  from  the  southwest zone.

A front moving down from  Canada began to  influence
the region, causing the upper ridge to flatten.  Wind
speeds increase with  flow more from the west.

Instability built-up  throughout the day.  A small surface
trough extended across the New England region.  Surface
to 2000' winds were from  the southwest during morning
hours, shifting more  to southerly in the  afternoon.

The instability line  passed through Groton during early
morning hours as evidenced by thunderstorms.  By daytime,
the skies  had cleared.  Surface winds were from the west
while upper level winds were more from the northwest in
the morning shifting  to westerly by afternoon.

High pressure now entrenched in New England region.
Surface winds were light from the west with 1500' winds
from the northwest in morning, becoming more westerly
in the afternoon.  Seabreeze evident during afternoon
hours (1-7 PM).

High pressure system  continued to move eastward.   A
new cold front began moving down from Canada.  A low
pressure area centered in Minnesota also  appeared on
the weather maps.  Wind flow to 2000'  was from the
west throughout the day.

The high pressure system weakened and began to diffuse.
The advancing cold front extended across  northern New
England.   The low occluded with its center north of
Lake Superior.   The surface to 2000'  winds were from
the west-southwest.   Haze built throughout the day at
Groton.

The front in northern N-GW England retreated to the north
as a new cold front moved into New York and Pennsylvania
from the west.   The Groton area experienced rain showers
during early morning  hours.  Surface to 2000' winds were
from the southwest.  A high over Iowa moved eastward.
                                    18

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Saturday 7/26  -
Sunday 7/27  -
Monday 7/28  -
Tuesday 7/29  -
Wednesday 7/30  -
Thursday 7/31  -
Friday 8/1  -
Saturday 8/2 -
Sunday 8/3 -
Monday 8/4 -
The easterly moving  front  passed  Groton  at approximately
2:00 AM.  A high  pressure  system  is  now  centered  over
northwestern Pennsylvania.   Northwesterly  winds prevailed
from the surface  to  2000'.

High pressure weakened  as  the  system moved to  the north-
east.  A new front approached  Connecticut  from the west.
Tropical storm  Blanche  passed  about  450  miles  off the
coast as it moved north.   Winds to 2000' were  from the
southeast in the  morning,  becoming more  southerly by
evening.

The front to the  west continued its  rapid  approach and
by evening was  close to Groton.   Tropical  storm Blanche
approached Nova Scotia.  Surface  to  2000'  winds were
from the west-southwest.

Frontal passage occurred about 4:00  AM.  The high
pressure area following the  front was centered over
Pennsylvania.   Surface  to  4000' winds were  from the
west-northwest.

The high pressure system was centered over  western
New York.  Subsidence occurred throughout  the  region.
Surface to 2000'  winds were  from  the west-northwest.

High pressure existed over the entire east  coast.
Subsidence continued.  Winds to 3000' were  from the
west-northwest.

High pressure remained with  centers  in southwest
Pennsylvania and  Wisconsin.  Some weak frontal  activity
formed in Maine ahead of a slow moving east-west aligned
front across central Canada.  Winds were from the
northwest below 3000'.

High pressure weakened and moved southward  as frontal
activity increased.  A low pressure system was  located
to the north in Canada.  The weak frontal activity
persisted off the Maine coast.  Winds at lowest altitudes
were from the north-northwest.

The barometric  pressure continued to fall as the high
moved farther south.  A weak front originating  from the
north passed through Groton at approximately 6:00  PM.
Before the frontal passage, surface to 2000' winds were
mainly weak and disorganized.  After passage air flow
was predominantly from the northeast.

Frontal activity weakened but existed over most of the
eastern United  States.  A new high pressure system began
moving southeastward out of Canada.   Winds were easterly at
the surface, swinging to the south with increasing altitude.
                                     19

-------
 ruesday 8/5  -
Wednesday 8/6  -
Thursday 8/7  -
 Friday 8/8  -
 Saturday 8/9  -
Sunday 8/10 -
Monday 8/1
Tuesday 8/12 -
Wednesday 8/13 -
Some frontal activity remained  in the Groton area.  The
high pressure system in Canada  strengthened as  it con-
tinued to move to the southeast.  Surface flow  was  light
and from the west with winds shifting to the north  with
altitude in the morning.  Wind  strength increased from
the northwesterly direction in  the afternoon.

Main frontal activity existed along coast through Rhode
Island and Cape Cod.  Advancing high now centered over
Lake Superior.  Surface to 2000' winds were light and
from the northeast - becoming more northerly in the
western part of the region.

A weak low pressure center developed south of Nantucket.
Light rain fell throughout the day.  Eastward movement
of high over Great Lakes slowed somewhat.  Wind flow in
the Groton area was from the northeast.
Nantucket low strengthened a little and moved to the
north.  An upper level low over New England added to
unsettled weather conditions.  Winds to 3000' were
generally from the north.
                                                                       the
Some instability still persisted over Cape Cod; however,
most of the western part of New England was clear.  The
center of the advancing high pressure system was now over
West Virginia.  A quick moving frontal system associated
with a low in central Canada moved to the east.  Surface
to 2000' winds were from the northwest.
The high continued its southern movement.
associated with the Canadian low extended in
west direction along the U.S.-Canada border.
trough existed along much of the east coast.
3000' were from the northwest.
A front
  an east-
   A surface
   Winds to
The low pressure center moved eastward across Canada and
weakened.  The front remained stalled along the U.S.-
Canada border.  The trough along the east coast
strengthened.  Winds to 3000' were from the west-
southwest.

The front to the north showed little movement.  The
trough moved eastward causing air flow from the west-
northwest during afternoon hours.

The frontal  system combined with a new low in central
Canada and began to orient northeast-southwest through the
central U.S.   The main trough weakened but another minor
trough set up in southern New England.  Winds below 3000'
varied considerably over the region but were generally
from the western quadrants.
                                    20

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Thursday 8/14 -
Friday 8/15 -
Saturday 8/16  -
Sunday 8/17  -
Monday 8/18  -
Tuesday 8/19  -
 Wednesday  8/20  -
Thursday  8/21  -
The frontal system finally moved through the Groton area
about 10:00 PM.  A high pressure system located in
Minnesota appeared to be moving northeastward.  Winds
to 3000' were from the west.

The frontal system that passed Groton on the 14th stalled
in southern Pennsylvania.  A weak high pressure system
built off the coast of New England.  In addition a weak
trough developed over the region.  Winds to 3000' were
from the north-northwest in the morning followed by a
shift to southwesterly in the afternoon.

The front stalled in Pennsylvania began to weaken.  The
trough continued to build over New England.  Winds to
3000' were from the southeast over most of the region.

The front to the south decayed rapidly.  A small lo>s »,'S
centered about 200 miles east of New Jersey.  Surfa^ •>  :o
2000' winds were from the east while air flow in the
3000-6000' region was from the southwest.

A new frontal system approaching rapidly from the west
passed through Groton during the late evening hours.
Winds below 3000' were from the west.

High pressure began to build over the region as a new
system moved southeastward out of Canada.  Surface tc
3000' winds were from the northwest.

High pressure continued to build with center of high now
over Lake Superior.  Winds at lowest altitudes remained
from the northwest.

High pressure was strongly entrenched over the region.
Morning winds below 2000' were from the northwest.  Air
flow came from the southwest during afternoon hours.
                                    21

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                          TABLE 3.  UPPER LEVEL WINDS AT GROTON DURING JULY  AND  AUGUST,  1975
ro
PO

DATE
TIME
ALTITUDE
(FEET)
500
1000
1500
2000
2500
3000
3500
4000
4500
5000

7/14 7/15 7/15
1000 0900 1600

178/26 207/24 220/20
189/33 218/21 227/18
193/34 238/17
193/31 246/16
193/28 247/20
258/20
265/19
263/18
256/15
249/17

7/16
1500

223/12
236/12
244/12
245/15
250/16
253/16
261/15
263/16
270/20
271/21

7/17
1615

270/17
276/18
281/17
287/18
287/20
286/19
290/16
295/15
313/13
320/15

7/18
1530

225/13
232/16
231/15
241/15
253/18
260/19
268/18
271/16
274/18
267/18

7/19
1000

215/24
219/24
225/25
218/24
213/27
213/28
213/29
212/30
228/31
211/33

7/19
1805

214/32
219/31
229/28
228/26
230/28
238/28
245/25
247/25
245/24
241/31

7/20 7/21
1200 0935

230/18 269/1
229/19 277/1
225/19 301/1
223/19 311/1

3
2
3
8
316/24
317/20








                x/y   x  =  direction  in  degrees; y  =  speed  in mph

-------
                                  TABLE 3.  Continued
DATE
TIME
ALTITUDE
(FEET)
500
1000
1500
2000
2500
3000
3500
4000
4500
5000
7/21
1415

250/22
243/21
246/19
251/18
261/20
272/20
281/19
286/21
288/20
290/18
7/22
0910

335/16
331/16
320/17
310/18
277/12
281/16
286/20
278/20
260/18
258/21
7/22
1515

242/22
243/16
254/10
280/07
300/10
317/11
336/11
329/11
322/10
320/12
7/23
0930

270/13
277/15
280/14
276/14
263/14
269/14
281/13
294/12
320/17
311/16
7/23
1455

230/15
234/16
244/16
253/16
260/20
274/18
278/19
285/15
290/18
286/18
7/24
0930

240/18
243/18
247/17
243/20
237/25
233/26
230/28
231/27
233/29
230/31
7/24
1440

208/23
212/15
215/20
220/21
230/25
233/27
234/27
235/25
235/26
234/28
7/26
1040

330/1 7
326/23
328/24
332/17
335/19
339/16
352/12
360/09
300/08
289/16
7/27
0858

062/05
089/07
111/07
102/08
095/08
100/07
101/07
099/07
103/07
038/05
7/27
1510

190/04
192/03
109/01
047/05
028/06
018/03
090/03
1 72/02
185/05
166/07
x/y  x = direction in degrees;  y =  speed  in mph

-------
                                                   TABLE 3.   Continued
INi
DATE
TIME
ALTITUDE
(FEET)
500
1000
1500
2000
2500
3000
3500
4000
4500
5000
7/28 7/28
0858 1450

224/25 214/18
229/24 218/18
239/21 230/19
245/31 244/19
248/38 260/16
265/16
276/17
276/18
277/20

7/29
0913

330/14
325/19
320/19
316/18
312/17
296/15
284/13
274/13
271/14
271/16
7/29
1515

302/09
302/09
299/10
297/13
298/14
299/13
306/11
310/13
308/13
299/16
7/30
0925

310/05
298/07
275/10
256/11
265/10
295/06
309/03
323/03
320/05
321/05
7/30
1515

249/21
248/18
251/16
265/13
286/11
292/10
296/10
313/09
340/09
020/10
7/31
0925

288/10
291/12
304/10
326/14
330/16
312/14
303/15
264/20
295/13
303/14
7/31
1520



250/23
257/1
271/1
287/1
295/1
292/1
294/1
9
•5
*S
2
4
6
5
299/16
301/1
295/1
7
9
                  x/y  x = direction  in  degrees; y  =  speed  in  mph

-------
                                                   TABLE 3.   Continued
ro
en
DATE
TIME
ALTITUDE
(FEET)
500
1000
1500
2000
2500
3000
3500
4000
4500
5000
8/3
0900

345/08
355/13
348/11
346/07
349/05
337/06
320/06
295/07
288/08

8/3
1450

233/10
256/05
306/06
310/06
315/06
319/07
326/07
326/08
305/10
299/09
8/5
1000

343/04
342/07
357/11
357/13
351/12
355/12
350/09
342/12
350/11
353/12
8/5
1455

243/14
256/06
321/06
329/08
340/11
351/13
360/13
354/13
356/13
351/14
8/6
0930

031/15
052/12
066/20
099/18
105/10
131/04
085/04
051/03
355/02
021/03
8/6 8/8
1502 0920

084/13 330/15
061/08 331/19
038/10 334/21
022/21
016/10
001/10




8/8
1450

341/16
358/24
016/22
029/21
028/19
028/21




8/9
0930

334/11
346/15
346/19
342/19
340/20
338/19
326/18
311/21
310/23
318/21
8/9
1510

251/21
275/10
314/07
328/08
325/11
330/11
336/12
005/12
352/16
344/19
                  x/y  x = direction in degrees; y = speed in mph

-------
                                TABLE 3.  Continued
DATE
TIME
ALTITUDE
(FEET)
500
1000
1500
2000
2500
3000
3500
4000
4500
5000
8/10
0915

285/18
292/22
293/24
300/21
320/13
350/14
350/12
340/09
305/10
290/14
8/10
1210

257/18
266/12
286/11
308/11
326/09
308/08
295/08
296/09
297/12
315/14
8/10
1525

253/23
261/21
278/18
298/15
300/15
310/14
316/18
308/18
301/18
309/20
8/11
0915

308/10
319/14
326/15
320/15
301/13
298/13
297/16
314/21
309/22
295/22
8/11
1505

231/1


5
230/14
232/1
234/1
239/1
231/1
270/1
285/1
284/1

3
3
3
3
0
1
3

8/12
0920

345/10
353/15
358/15
348/16
343/15
333/15
325/11
325/11
325/13
329/14
8/12
1450

275/09
307/09
319/10
313/14
309/14
311/15
312/16
311/16
318/16
320/17
8/13
0920

058/05
065/07
061/04
020/03
330/02
307/03
323/05
350/06
352/05
350/03
8/13
1505

209/10
233/10
246/13
247/12
247/10
246/10
250/10
256/10
256/10
256/11
8/14
0915

270/18
281/18
294/17
290/18
278/23
262/26
264/27
273/30


x/y  x = direction in degrees; y = speed in mph

-------
                                                  TABLE  3.  Continued
ro
DATE
TIME
8/14
1430
8/15
0905
8/15
1500
8/18
1010
8/18
1450
8/19
0855
8/19 8/20
1645 0915
8/20
1525
8/21
0930
ALTITUDE
(FEET)
500
1000
1500
2000
2500
3000
3500
4000
4500
5000
248/22
252/18
265/13
273/12
280/13
280/15
276/17
296/17
293/18
292/19
012/18
014/17
355/13
346/08
339/06
340/06
343/06
348/07
347/06
325/06
213/10
230/09
245/07
260/05
280/05
286/05
320/05
318/06
318/08
319/09
260/09
297/09
310/14
314/15
295/16
286/18
278/20
281/21
289/19
296/16
246/20
251/16
265/14
280/12
289/11
295/11
297/12
300/14
296/14
291/15
331/1
340/1
335/1
1
2
1
325/12
321/1
318/1
315/1
308/1
2
1
1
1
325/09
319/09
256/19 358/1
5
265/17 357/16
275/14 353/1
350/1
350/1
349/1
345/1
5
5
6
5
3
338/09
328/10
320/1
1
292/16
294/12
300/15
301/18
301/20
302/22
302/22
302/21
303/19
305/18
330/01
248/07
250/10
253/09
256/09
264/08
269/08
272/08
270/09
264/10

                  x/y  x = direction in degrees; y = speed in mph

-------
CONTINUOUSLY COLLECTED GROUND DATA
     Data in this section is tabulated on a daily basis.   For each day
of the sampling period, average hourly concentrations  of  ozone,  oxides
of nitrogen, methane, non-methane total  hydrocarbon, carbon monoxide,
fluorocarbon-11 and carbon tetrachloride are reported.   In addition,
meteorological  parameters including wind speed,  wind direction,  turbulence,
solar radiation, temperature and dew point are reported  in the daily
summaries.
     Hourly averages refer to the period from 30 minutes  before  the
hour to 30 minutes after the hour.  Times correspond to Eastern  Daylight
Time.
                                   28

-------
                             TABLE  4    SURFACE DATA COLLECTED AT GROTON, CT ON JULY 15, 1975
ro
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3 N0
ppb ppb
15
14
19
18
17
17
16
13
15
19
23
33
35
22
22
21
20
18
16
13
13
16
16
16
GAS DATA MET. DATA
N02 NMTHC CO CH4 CFCI3 CCI4 WS WD Q^ ^D TMP DP
ppb ppmC ppm ppm ppt ppt mph deg deg ml_y °F °F
<.l .2 1.4 150 128 5 180 8 0 70 66
<.l .2 1.4 150 128 8 190 9 0 69 66
<.l .2 1.4 150 128 6 190 8 0 69 66
<.l .2 1.4 150 128 7 175 7 0 68 65
<.l .2 1.4 145 128 6 190 7 0 69 66
<.l .2 1.4 145 128 9 200 6 30 70 67
<.l .2 1.4 140 128 8 195 7 200 70 67
<.l .2 1.4 145 128 8 200 6 360 71 67
<.l .2 1.4 150 128 9 195 8 675 73 68
<.l .2 1.4 150 128 7 220 8 920 76 69
<.l .3 1.4 160 128 8 215 8 1300 76 70
<.l .3 1.4 160 128 6 200 7 700 74 67
<.l .3 1.4 155 128 4 190 8 950 79 69
<.l .3 1.4 155 128 5 200 7 800 78 69
<.l .3 1.4 150 128 7 200 4 1125 78 69
<.l .3 1.4 155 128 7 200 7 875 76 67
<.l .3 1.4 155 128 5 210 9 750 76 68
<.l .2 1.4 150 128 8 215 7 500 76 68
<.l .2 1.4 150 128 10 230 7 175 74 68
<.l .2 1.4 150 128 8 220 6 35 72 68
<.l .3 1.4 150 128 9 220 6 0 71 67
<.! .3 1.4 150 128 8 215 6 0 72 68
<.l .3 1.4 150 128 8 215 7 0 71 68
<.l .3 1.4 150 128 7 210 7 0 71 67

-------
                             TABLE 5-   SURFACE DATA  COLLECTED  AT  GROTON, CT ON JULY  16,  1975
CO
o
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
14
13
13
14
13
14
12
14
15
16
17
20
22
24
24
23
23
20
19
15
15
17
18
20
NO
ppb
—
—
—
—
—
—
—
—
—
—
—
—
8
10
7
7
7
6
6
6
6
6
7
7
N02
ppb
__
—
—
—
—
—
—
—
—
—
—
—
10
11
8
7
9
9
11
8
5
7
8
8
GAS DATA
NMTHC CO CH4
ppmC ppm ppm
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<-l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .4 1.4
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .3 1.4
<.l .2 1.4
<.l .2 1.4
<.l .3 1.4
CFCI3
PPt
150
150
150
150
150
150
150
150
150
155
155
160
160
160
160
155
155
155
155
160
160
160
160
160
cci4
ppt
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
WS
mph
3
3
2
4
5
6
4
7
6
4
5
6
5
6
7
8
10
9
7
6
5
6
9
7
MET.
WD 
-------
TABLE 6.   SURFACE DATA COLLECTED AT  6ROTON,  CT ON JULY  17, 1975

Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
20
21
21
20
19
20
20
19
20
23
23
29
35
33
30
31
28
27
25
32
25
23
23
23
NO
ppb
7
7
6
6
6
6
6
7
6
6
8
8
7
8
6
6
7
6
6
6
6
6
6
5
GAS DATA MET. DATA
N02 NMTHC CO CH4 CFCI3 CCI4 WS WD (^ RAD TMP DP
ppb ppmC ppm ppm ppt ppt mph deg deg mLy °F °F
8 <.l .3 1.4 155 128 4 215 7 0 71 68
8 <.l .3 1.4 155 128 2 225 7 0 71 68
8 <.l .3 1.4 155 128 4 230 9 0 70 67
9 <.l .3 1.4 155 128 4 230 9 0 70 68
9 <.l .3 1.4 155 128 2 220 9 0 70 68
8 <.l .3 1.4 155 128 7 230 10 50 71 68
9 <.l .3 1.4 155 128 8 240 7 125 72 69
9 <.l .3 1.4 155 128 7 250 6 225 73 69
10 <.l .3 1.4 155 128 8 240 5 350 75 70
10 <.l .3 1.4 155 128 7 220 6 790 76 70
14 <.l .3 1.4 155 128 8 220 6 1000 78 71
14 <.l .3 1.4 155 128 8 230 6 1400 82 73
14 <.l .3 1.5 155 128 6 210 7 1500 84 73
15 <.l .3 1.5 155 128 6 195 7 1375 84 72
10 <.l .3 1.5 155 128 5 200 8 800 81 70
9 <.l .3 1.5 155 128 6 200 6 1050 80 70
12 <.l .3 1.5 150 128 8 210 6 750 78 68
10 <.l .3 1.5 150 128 9 210 6 425 74 68
10 <.l .3 1.5 150 128 11 220 6 200 73 68
10 <.l .3 1.5 155 128 13 240 6 25 73 68
12 <.l .3 1.5 155 128 10 250 7 0 72 69
10 <.l .3 1.5 155 128 13 250 8 0 74 70
10 <.l .3 1.5 155 128 12 250 8 0 74 70
10 <.l .3 1.5 155 128 5 235 11 0 72 69

-------
                              TABLE 7.   SURFACE DATA COLLECTED AT GROTON, CT ON JULY 18, 1975
OJ
ro
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
21
21
23
23
21
20
19
20
19
24
62
97
113
155
165
108
68
70
73
63
46
52
52
46
NO
ppb
5
5
6
6
6
6
6
6
7
8
7
6
6
6
8
7
7
7
6
6
6
6
7
7
N02
ppb
10
10
11
10
11
11
13
13
15
16
19
20
21
23
23
23
16
13
11
11
12
7
10
10
GAS
NMTHC
ppmC
<.l
<.l
<.l
<.l
<.l
<.!
<.l
<.l
<.l
<.l
.2
.5
.4
.4
.4
.7
.3
.2
.3
.3
.3
.3
.3
.3
DATA
CO CH4
ppm ppm
.3 1.5
.3 1.5
.3 1.5
.3 1.5
.3 1.5
.3 1.5
.4 1.5
.4 1.5
.5 1.6
.6 1.6
.6 1.6
.8 1.7
.9 1.8
1.1 1.8
1.2 1.8
.8 1.6
.5 1.5
.5 1.5
.5 1.4
.4 1.4
.4 1.4
.4 1.4
.4 1.4
.4 1.4
CFCI3
PPt
155
155
155
155
160
170
200
215
220
250
325
470
475
575
500
350
230
225
210
200
195
180
180
180
CCI4
PPt
218
128
128
128
128
128
134
140
140
153
174
186
220
220
198
183
140
128
128
128
128
128
128
128
WS
mph
3
3
5
7
12
12
11
11
8
13
14
12
11
11
8
7
11
8
13
11
9
8
10
11
MET.
WD 0^
deg deg
220 8
245 10
260 7
260 6
250 7
250 8
260 7
260 6
250 8
245 8
250 8
250 8
230 8
230 7
220 7
220 7
220 6
230 5
230 7
250 7
245 8
250 8
250 10
260 7
DATA
RAD TMP
mLy °F
0 71
0 72
0 74
0 74
0 73
20 73
115 73
170 74
390 74
920 76
1100 78
1300 81
1370 80
1350 81
1200 82
950 82
700 78
300 75
125 74
35 73
0 73
0 73
0 74
0 74
DP
°F
69
69
70
71
70
70
71
71
70
71
71
72
71
72
72
72
70
68
67
68
68
68
69
69

-------
                            TABLE 8.  SURFACE DATA COLLECTED AT GROTON,  CT ON JULY 19, 1975
GO
GO
Time
hr
01 dO
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
38
35
35
33
32
28
20
12
13
14
38
50
55
53
58
59
62
55
48
42
39
39
40
39
NO
ppb
7
7
7
7
7
7.
8
7
7
7
8
8
8
7
7
7
7
6
11
14
12
12
9
7
GAS
N02 NMTHC
ppb ppmC
10 .3
10 .3
10 .3
10 .3
10 .2
10 .2
11 .2
8 .3
11 .3
12 .3
11 .3
11 .3
12 .2
8 .3
11 .3
9 .3
10 .2
11 .2
10 .2
8 .2
8 .2
9 .2
9 .2
8 .2
DATA
CO
ppm
.4
.4
.4
.4
.3
.3
.3
.3
.4
.5
.5
.5
.5
.4
.4
.4
.4
.4
.3
.3
.3
.3
.3
.3
CH4
ppm
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
CFCI3
ppt
170
165
165
165
165
165
165
165
165
170
175
180
170
165
165
165
165
165
165
160
165
165
165
165
cci4
ppt
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
. 128
128
128
128
128
'128
WS
mph
11
10
10
7
8
10
11
9
10
11
10
8
12
15
18
15
19
19
17
17
12
16
18
17
MET.
WD 0^
deg deg
260 7
260 6
250 8
240 7
235 9
240 9
240 8
250 7
245 7
240 8
230 7
225 7
230 7
230 7
225 6
220 6
225 6
225 6
225 6
230 7
235 7
240 8
230 7
235 7
DATA
RAD TMP
mLy °F
0 74
0 74
0 74
0 72
0 73
45 73
250 73
540 75
800 76
1050 77
997 78
1350 79
1400 81
1360 81
1250 80
875 78
725 78
500 77
175 75
50 75
0 73
0 73
0 73
0 72
DP
°F
69
69
69
68
69
69
69
69
69
69
70
70
71
70
70
69
69
69
69
69
68
69
69
68

-------
                               TABLE 9.  SURFACE  DATA COLLECTED AT GRDTDN. CT ON .1111 Y 20,  1975
CO
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
34
27
26
23
26
25
24
22
20
25
22
37
44
58
50
40
33
33
28
26
23
25
25
27
NO
ppb
10
13
14
12
12
16
16
13
13
13
13
12
12
12
11
12
12
11
11
12
15
16
15
12
N02
ppb
5
10
10
13
10
10
12
12
15
12
12
14
14
16
19
16
13
13
11
12
12
11
11
11
GAS
NMTHC
ppmC
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
<.l
<.l
<.l
<.l
<.l
<.l
DATA
CO
ppm
.3
.3
.3
.3
.3
.3
.4
.4
.4
.5
.5
.5
.6
.5
.5
.5
.5
.4
.3
.3
.3
.3
.3
.3
CH4
ppm
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
CFCI3
ppt
165
160
155
155
155
155
155
155
160
160
165
175
170
165
160
150
150
150
150
150
150
150
150
150
CCI4
PPt
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
128
MET. DATA
WS WD O^ RAD TMP
mph deg deg rnLy °F
18 240
18 240
18 250
18 244
12 255
14 254
13 335
16 244
12 260
12 260
9 249
7 226
10 236
13 220
14 226
11 225
10 225
13 226
13 240
11 240
9 255
11 235
13 230
12 220
7 0 74
7 0 74
7 0 75
7 0 74
6 0 73
7 47 74
7 1 00 74
7 225 74
5 550 75
5 800 77
6 1250 79
7 420 80
7 875 79
7 1300 81
6 975 80
7 950 79
7 725 79
7 225 76
7 60 75
8 28 74
8 0 74
7 0 74
8 0 74
7 0 74
DP
°F
69
70
70
69
69
70
70
69
70
70
71
71
72
72
71
71
71
70
70
69
70
70
70
70

-------
                             TABLE 10.   SURFACE DATA COLLECTED AT GROTON.  CT  ON JULY 2K 1975
OJ
en

Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
ppb
28
30
32
34
36
25
37
35
31
39
52
53
76
92
no
119
120
123
152
93
81
84
80
66
NO
ppb
12
12
13
13
12
13
12
13
13
13
13
14
14
17
15
15
16
17
17
16
16
16
17
14
N02
ppb
11
11
10
10
11
13
13
13
17
15
16
24
18
17
15
15
17
17
18
14
16
14
15
18
GAS
NMTHC
ppmC
<.l
<.l
<.l
<.l
<.l
<.l
<.l
.2
.2
.3
.3
.3
.3
.2
.3
.3
.3
.3
.4
.3
.3
.3
.2
.2
DATA
CO
ppm
.3
.3
.3
.3
.3
.4
.4
.4
.5
.5
.5
.6
.7
.7
.7
.7
.7
.7
.8
.6
.6
.7
.8
.8
CH4 CFCI3
ppm ppt
1.4 145
1.4 145
1.4 145
1.4 145
1.5 145
1.5 155
1.5 165
1.5 180
1.5 190
1.7 230
1.7 250
1.7 320
1.7 280
1.7 285
1.5 275
1.5 220
1.5 220
1.5 250
1.5 340
1.5 240
1.5 220
1.5 220
1.6 260
1.6 255
cci4
PPt
122
122
128
128
128
128
128
128
134
^40
146
146
153
153
153
134
128
128
153
140
134
134
153
153
WS
mph
17
20
19
17
17
19
17
13
11
12
14
15
16
15
15
16
17
15
13
12
12
8
5
CALM
MET.
WD O^
deg deg
225 7
225 7
225 7
220 8
240 7
250 7
260 7
260 7
255 6
252 7
251 7
250 6
260 6
260 6
255 6
260 6
265 5
265 6
260 6
245 7
260 7
265 7
280 11
14
DATA
RAD TMP
mLy °F
0 74
0 74
0 73
0 73
0 72
30 72
50 72
275 73
690 74
1050 76
1275 77
1425 78
1450 78
1408 81
1250 82
1050 82
800 82
525 82
200 80
50 76
0 75
0 75
0 76
0 74
DP
°F
70
69
69
70
69
69
69
70
70
70
70
70
71
72
72
70
69
69
70
69
69
70
70
70

-------
                              TABLE 11.  SURFACE DATA COLLECTED AT GROTON, CT ON JULY 22, 1975
CO
Time 0^
hr ppb
0100 67
0200 48
0300 33
0400 29
0500 24
0600 27
0700 30
0800 32
0900 44
1000 46
1100 55
1200 59
1300 78
1400 118
1500 121
1600 111
1700 112
1800 105
1900 104
2000 90
2100 72
2200 54
2300 48
2400 33
NO
ppb
12
12
12
12
12
12
12
14
17
10
10
11
11
12
12
11
9
7
10
11
11
11
11
12
N02
ppb
15
17
22
19
21
21
17
21
18
14
13
12
15
18
14
15
15
15
15
14
18
22
15
24
GAS
NMTHC
ppmC
.2
.2
.3
.5
.5
.3
.3
.2
.2
.2
.2
.2
.2
.3
.3
.2
.2
.3
.3
.3
.3
.5
.5
.5
DATA MET. DATA
CO CH4 CFCI3 CCI4 WS WD Q^ RAD IMP DP
ppm ppm . ppt ppt mph deg deg mLy °F °F
.8 1.6 255 140 4 235 12 0 73 70
.9 1.6 315 146 CALM 15 0 73 69
.9 1.6 355 153 CALM 13 0 72 69
.8 1.6 350 153 CALM 15 0 71 68
.8 1.6 310 153 CALM 14 0 70 66
.7 1.6 265 140 CALM 10 50 71 65
.8 1.6 290 146 5 270 7 500 72 68
.5 1.6 330 153 CALM 6 750 78 65
.5 1.6 280 140 CALM 7 900 82 65
.5 1.6 210 140 CALM 10 1100 85 65
.5 1.6 185 134 5 260 20 1275 86 65
.5 1.5 185 134 6 265 13 1300 86 66
.7 1.6 350 146 15 250 8 1075 80 68
.8 1.6 500 153 17 250 6 1375 80 70
.8 1.6 390 146 17 255 5 1250 81 69
.7 1.6 310 128 16 255 6 970 82 68
.7 1.6 260 128 13 250 6 700 80 68
.7 1.6 210 128 13 255 6 430 80 67
.7 1.6 195 128 11 260 5 175 77 68
.7 1.6 255 128 9 260 5 45 76 68
.9 1.6 310 128 CALM 10 0 75 67
.5 1.6 285 128 CALM 23 0 73 66
.5 1.6 385 128 CALM 14 0 72 67
.5 1.6 360 128 CALM 8 0 72 67

-------
TARIF 1?   SURFACE DATA COLLECTED AT GROTON.  CT ON  JULY  23.  1975
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
33
12
<5
<5
<5
<5
19
30
36
44
53
63
71
83
93
100
104
128
120
116
99
82
78
74
GAS DATA MET. DATA
NO N02 NMTHC CO CH4 CFCIj CCI4 WS WD Q^ RAD TMP DP
ppb ppb ppmC ppm ppm ppt ppt mph deg deg mLy °F °F
13 19 .4 1.2 1.7 360 128 3 355 11 31 71 68
15 20 .6 1.2 1.7 380 128 2 040 11 32 70 67
18 19 .4 1.5 1.7 430 299 3 030 13 39 69 67
16 24 .3 1.0 1.6 310 421 3 030 10 38 68 64
14 19 .3 .8 1.6 250 268 2 045 8 27 66 62
13 20 .4 .7 1.6 260 329 2 270 10 75 67 63
16 24 .5 .8 1.6 270 472 5 265 5 350 71 63
17 16 .2 .6 1.6 220 134 9 265 6 500 74 64
17 19 .3 .7 1.6 235 122 9 270 7 850 79 66
16 19 .3 .7 1.6 230 122 13 260 6 1100 79 67
15 18 .3 .7 1.6 255 122 14 250 6 1250 78 66
7 14 .3 .6 1.6 220 122 13 245 5 1375 79 66
6 17 <.l .6 1.6 175 122 10 240 6 1380 80 65
6 15 <.l .6 1.6 170 122 6 210 12 1325 82 65
6 15 <.l .6 1.6 170 128 6 230 8 1150 83 66
7 15 <.l .6 1.6 175 140 9 240 6 975 82 67
7 17 <.l .7 1.6 185 134 5 235 6 1000 83 67
7 17 .2 .7 1.6 255 140 4 210 8 425 81 68
6 18 .2 .6 1.6 245 140 5 230 11 175 78 68
7 14 .2 .6 1.6 225 140 5 225 11 35 76 68
7 15 <.l .6 1.6 205 140 4 220 12 1 74 68
6 14 <.l .6 1.6 185 134 3 225 13 0 72 67
6 14 <.l .6 1.6 180 134 3 220 20 0 72 67
7 12 <.l .5 1.6 170 122 * 210 13 2 72 67

-------
                               TABLE 13.   SURFACE DATA COLLECTED AT GROTON,  CT  ON  JULY  24,  1975
CO
00
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
73
68
56
46
42
40
54
50
62
74
80
86
86
90
82
80
66
56
48
40
37
29
30
29
NO
ppb
7
7
7
6
7
8
7
7
7
7
7
7
7
7
7
7
7
8
7
7
7
7
7
7
N02
ppb
13
13
12
12
12
12
13
17
15
15
17
16
14
14
13
13
13
14
12
12
10
11
10
10
GAS
NMTHC
ppmC
<.l
<.l
<.l
<.l
..2
.2
.2
.2
.2
.2
.2
.2
.2
.2
<.l
<.l
<.l
<.l
<.l
<.l
<.l
<.l
<.l
<.l
DATA
CO CH4
ppm ppm
.5 1.6
.4 1.5
.4 1.5
.3 1.5
.4 1.5
.4 1.5
.4 1.5
.5 1.5
.6 1.5
.6 1.5
.6 1.5
.7 1.5
.7 1.5
.6 1.5
.6 1.5
.6 1.5
.5 1.5
.4 1.5
.4 1.5
.3 1.5
.3 1.5
.3 1.5
.3 1.5
.3 1.5
CFCI3
ppt
160
160
160
145
150
165
160
165
180
175
175
175
185
180
180
185
165
160
155
140
140
135
135
130
CCI4
PPt
122
122
134
122
122
122
122
128
134
122
122
128
122
122
122
122
122
128
116
116
116
116
116
no
WS
mph
4
3
9
11
13
9
6
6
10
4
5
4
7
6
7
7
8
12
12
16
16
18
18
16
MET.
WD 0^
deg deg
215 11
255 9
250 5
255 5
255 5
245 6
230 8
240 6
245 5
210 6
200 6
200 10
195 7
210 10
190 8
200 7
215 9
220 7
220 7
220 6
220 6
220 6
225 6
225 6
DATA
RAD TMP
ml_y °F
3 72
3 72
4 72
1 73
1 73
38 72
300 74
600 76
850 77
1050 80
1225 82
1320 82
1300 82
800 80
900 80
750 79
800 80
400 77
100 75
20 75
0 74
0 74
0 73
0 73
DP
°F
67
67
67
65
65
65
65
67
68
69
69
69
70
69
69
70
70
70
69
69
69
69
69
69

-------
                            TABLE 14.  SURFACE DATA COLLECTED AT GROTON , CT ON JULY 25,  1975
CO
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
31
34
42
47
48
51
46
41
41
28
27
34
30
33
36
43
36
34
33
48
46
46
40
34
NO
Ppb
7
13
7
7
7
7
7
8
8
7
9
14
12
11
11
12
12
12
11
11
11
12
11
11
GAS
N02 NMTHC
ppb ppmC
10 <.1
10 <.l
11 <.l
11 <.l
11 <.l
11 <.l
12 <.l
13 <.l
12 <.l
12 <.l
15 <.l
10 <.l
8 <.l
10 <.1
9 
-------
TABLE 15.  SURFACE DATA COLLECTED AT GROTON,  CT  ON  JULY  26.  1975
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
27
23
27
27
29
26
21
18
24
27
29
35
37
41
44
47
50
50
49
45
36
<5
<5
<5
NO
ppb
11
11
11
10
10
10
10
n
n
n
n
9
9
10
9
7
6
7
6
6
6
>50
>50
>50
GAS
N02 NMTHC
ppb ppmC
8 .2
8 .2
5 .2
5 .2
3 .2
3 .2
3 .2
4 .2
3 .2
3 .2
4 <.l
3 <.l
3 <.l
3 <.l
3 <.l
2 <.l
2 <.l
2 <.l
3 <.l
7 <.l
14 <.l
NOx .2
NOx .4
NOx .4
DATA
CO
ppm
.7
.6
.5
.4
.3
.3
.3
.3
.3
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.4
.5
1.0
1.8
1.5
CH4
ppm
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
CFCI3
ppt
i 230
170
170
170
155
150
160
165
160
165
155
155
155
155
150
155
155
160
170
180
230
395
515
455
cci4
ppt
131
128
128
128
128
122
128
128
128
128
116
116
116
122
128
128
128
128
128
128
131
137
137
171
WS
mph
2
3
2
2
1
2
2
4
4
2
2
2
3
4
2
3
4
4
1
2
1
3
2
2
MET.
WD Cfe
deg deg
250 2
020 8
040 7
040 8
030 7
200 7
220 7
230 7
235 13
245 13
225 8
010 7
010 9
020 12
005 7
020 10
020 8
025 11
360 7
030 10
010 10
020 14
035 12
030 10
DATA
RAD TMP
mLy °F
0 70
0 68
0 66
0 65
0 63
20 62
200 63
550 67
900 71
1150 73
1300 75
1425 75
1460 77
1450 78
1370 80
11 50 81
900 80
650 79
325 77
25 72
2 68
0 66
0 62
0 60
DP
°F
68
62
58
56
53
52
51
53
53
52
53
53
54
54
54
54
53
52
52
50
50
51
52
53

-------
TABLE 16.  SURFACE DATA COLLECTED AT GROTON, CT ON JULY 27, 1975

Time Oj
hr ppb
0100 <5
0200 <5
0300 <5
0400 < 5
0500 <5
0600 < 5
0700 10
0800 19
0900 27
1000 43
1100 60
1200 69
1300 71
1400 73
1500 64
1600 64
1700 67
1800 65
1900 63
2000 62
2100 60
2200 54
2300 53
2400 54
NO
ppb
26
14
8
8
6
8
12
10
9
8
7
7
6
7
6
6
6
7
5
6
5
6
5
5
GAS DATA MET. DATA
N02 NMTHC CO CH4 CFCI3 CCI4 WS WD C% RAD TMP DP
ppb ppmC ppm ppm ppt ppt mph deg deg mLy °F °F
42 .3 1.3 1.6 355 622 3 020 12 0 60 53
36 <.l 1.1 1.6 270 592 2 040 18 0 58 52
30 .2 .9 1.6 255 253 2 020 15 0 56 52
28 .2 .8 1.6 245 189 2 025 20 0 55 51
18 .2 .7 1.6 220 146 3 020 15 5 55 51
18 .2 .6 1.6 220 137 3 020 16 200 57 52
14 .2 .6 1.7 205 128 4 020 13 525 65 54
8 .2 .5 1.6 195 128 4 010 18 800 70 55
8 <.l .5 1.6 190 128 3 030 18 1050 75 57
8 <.l .6 1.6 195 128 3 140 19 1275 75, 59
8 <.l .8 1.6 200 128 4 135 20 1400 76 61
11 <-l .9 1.5 185 128 4 130 7 1325 79 58
5 <.l .6 1.5 170 128 4 195 8 1440 79 61
5 <.l .6 1.5 155 128 6 195 7 1450 79 61
5 <.l .5 1.5 145 131 6 195 7 1350 79 58
3 <.l .5 1.5 145 131 5 285 5 1150 77 57
3 <.l .6 1.5 155 131 7 190 6 850 76 56
4 <.l .5 1.5 150 131 7 185 6 625 75 57
3 <.l .5 1.5 145 128 6 170 14 325 73 58
3 <.l .5 1.5 140 128 3 190 9 2068 56
2 <.l .5 1.5 145 128 4 150 11 064 57
1 <.l .5 1.5 145 128 7 210 18 0 65 58
2 <.l .4 1.5 140 128 8 230 8 0 66 57
3 <.l .4 1.5 140 128 e 265 8 0 66 59

-------
                                TABLE 17.   SURFACE  DATA f.OI I Ff.TFD  AT GROTON. f.T ON  ,1111 Y ?R  1Q7S
ro
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
49
48
59
64
64
66
75
71
70
70
68
72
108
123
138
—
123
118
98
96
90
79
—
68
NO
ppb
5
5
5
5
6
6
6
6
7
6
6
7
7
7
7
—
6
5
5
5
5
5
__
6
GAS
N02 NMTHC
ppb ppmC
4 <.l
7 <.l
2 <.l
2 <.l
2 <.l
2 <.l
6 <.l
8 <.l
7 <.!
7 <.l
12 .3
24 .2
24 .2
26 .2
20 .2
<.l
10 <.l
13 <.l
14 <.l
9 <.l
7 <.l
8 <.l
<.l
7 <.l
DATA
CO
ppm
.4
.4
.4
.4
.4
.4
.5
.5
.5
.6
.9
1.1
1.2
1.3
1.2
.9
.9
.8
.8
.8
.8
.7
.6
.8
CH4
ppm
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.6
1.8
1.8
1.8
1.8
1.8
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.6
1.6
CFCI3
ppt
145
145
140
135
135
140
155
155
185
220
290
365
375
415
380
260
270
260
225
215
225
200
210
210
cci4
ppt
122
116
116
116
116
122
122
122
128
128
174
198
186
186
174
140
134
128
128
116
122
122
122
122
MET.
WS WD Ck
mph deg deg
6 270
11 270
13 260
12 260
17 240
15 240
16 235
14 230
17 235
17 240
16 250
12 250
11 230
10 230
9 225
__
10 225
13 235
10 245
9 250
10 260
10 255
— —
3 270
6
7
7
8
6
6
6
7
7
6
5
5
7
6
6
—
6
7
7
6
5
4
__
9
DATA
RAD TMP
mLy °F
0 65
0 65
0 67
0 68
0 68
10 69
90 70
290 71
400 72
425 73
700 74
730 75
1350 78
1320 78
1175 78
__
675 77
415 76
160 74
30 73
0 73
0 73
— — _ _
0 71
DP
°F
59
59
59
58
60
62
62
64
64
65
65
65
66
67
67
—
68
67
67
67
67
67
__
68

-------
                              TABLE 18.   SURFACE DATA COLLECTED AT GROTON, CT ON JULY 29, 1975
-pa
CO
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
63
60
53
38
24
24
,18
17
26-
35
36
—
54
51
50
56
53
51
46
33
30
24
13
<5
GAS DATA MET. DATA
NO N02 NMTHC CO CH4 CFCI3 CCI4 WS WD (^ RAD TMP DP
ppb ppb ppmC ppm ppm ppt ppt mph deg deg mLy °F °F
6 5 <.l .8 1.6 210 116 3 265 11 0 71 68
7 5 <.l .8 1.6 219 116 5 270 8 0 71 68
6 5 <.l .7 1.6 220 116 2 255 12 0 71 68
7 15 .2 .7 1.7 280 122 2 270 12 0 70 67
6 18 .2 1.0 1.7 270 162 2 030 10 2 67 64
7 19 .2 1.0 1.7 300 290 2 015 13 45 66 *€4
10 25 .2 1.0 1.7 355 464 2 250 11 225 68 63
16 30 .3 1.1 1.8 416 509 3 250 7 520 72 64
10 19 .2 1.3 1.6 230 134 2 240 7 850 78 62
7 9 <.l .4 1.6 180 140 1 230 7 1090 83 60
6 8 <.; .4 1.6 170 128 3 240 7 1200 84 58
5 7 <.l .4 1.6 165 116 5 245 15 1300 84 54
5 6 <.l .4 1.6 165 116 6 245 17 1425 .' 86 55
5 5 <.l .4 1.6 160 116 7 260 14 1375 "85 54
5 3 <.l .4 1.6 150 122 7 260 15 1300 86 53
6 10 <.l .4 1.6 155 128 5 255 20 1075 86 53
6 12 <.l .4 1.6 155 122 6 245 11 775 83 60
5 6 <.l .4 1.6 155 116 2 290 12 525 85 55
5 9 <.l .4 1.6 175 128 2 015 7 175 80 54
5 18 <.l .8 1.6 210 128 2 040 9 23 76 56
5 14 <.l .6 1.6 190 128 2 030 9 0 73 54
5 20 <.l .6 1.6 240 128 3 015 15 0 71 53
10 30 .2 .9 1.6 260 207 3 040 13 0 68 54
13 34 .2 .9 1.6 '45 207 " 035 16 =0 65 57

-------
TABLE 19.  SURFACE DATA COLLECTED AT  GROTON,  CT  ON  JULY  30,  1975
Time Oj
hr ppb
0100 <5
0200 <5
0300 <5
0400 <5
0500 < 5
0600 <5
0700 <5
0800 <5
0900 20
1000 25
1100 38
1200 46
1300 55
1400 78
1500 105
1600 87
1700 85
1800 83
1900 78
2000 73
2100 68
2200 58
2300 61
2400 71
NO
ppb
10
15
19
22
22
26
28
34
29
31
20
11
11
10
9
7
7
7
7
6
6
6
6
7
GAS DATA MET DATA
N02 NMTHC CO CH4 CFCI3 CCI4 WS WD (^ RAD TMP DP
ppb ppmC ppm ppm ppt ppt mph deg deg mLy °F °F
31 .4 1.0 1.7 295 207 2 270 13 0 66 58
37 .2 .8 1.9 330 232 2 245 19 0 67 57
36 .2 .7 1.7 255 336 3 020 10 0 66 57
30 .2 .7 1.7 255 393 3 040 8 0 63 56
32 .2 .7 1.7 240 927 3 025 8 0 62 56
32 .3 .7 1.7 245 1275 2 040 15 50 62 56
31 .2 .9 1.8 415 741 2 040 13 350 66 59
44 .3 1.5 1.8 500 336 3 210 14 600 72 60
42 .4 1.5 1.8 435 476 3 255 12 875 77 61
50 .3 1.4 1.8 395 534 5 230 8 1050 77 62
34 <.'! .8 1.8 265 278 7 220 7 1275 75 63
18 <.l .7 1.6 175 128 9 225 7 1390 76 65
17 <.l .6 1.6 165 116 8 230 7 1410 78 66
20 <.l .7 1.7 185 122 11 240 5 1375 79 67
21 <.l .9 1.7 265 122 14 250 5 1290 79 66
12 <.l .7 1.7 235 122 13 250 5 1050 79 65
14 <.l .6 1.6 180 116 12 250 6 800 78 65
14 <.l .6 1.6 170 122 11 250 6 480 78 64
13 <.l .6 1.6 175 122 10 260 6 175 76 64
11 <.l .6 1.6 230 122 9 260 5 40 76 63
12 <.l .7 1.6 220 128 6 270 6 0 75 63
18 <.l .8 1.6 225 128 3 270 15 0 74 63
11 <.l .8 1.6 240 128 6 240 8 0 72 65
12 <.l .7 1.6 230 128 9 255 5 0 72 65

-------
                              TABLE 20.  SURFACE DATA COLLECTED AT GROTON, CT ON JULY 31, 1975
in
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
66
58
51
49
38
28
22
25
28
38
75
101
128
168
178
176
178
133
128
123
138
126
98
90
NO
ppb
8
7
7
7
7
8
10
18
20
20
15
10
10
9
8
8
9
9
8
9
9
9
9
9
N02
ppb
8
7
7
7
14
24
33
50
60
65
47
32
32
34
26
24
19
23
28
40
25
22
27
28
GAS
NMTHC
ppmC
<.l
<.l
<.l
<.l
<.l
<.l
<.l
.3
.5
.4
.2
.2
.2
.2
<.l
<.l
<. 1
<.l
<.l
.2
<.l
<.l
.2
.2
DATA
CO CH4
ppm ppm
.6 1.6
.4 1.6
.4 1.6
.4 1.6
.6 1.6
.8 1.8
1.0 1.9
1.5 2.0
1.7 2.1
1.6 2.2
1.4 2.2
1.3 2.1
1.4 2.1
1.4 2.1
1.4 2.0
1.2 1.9
1.1 1.8
1.0 1.8
1.3 1.7
1.6 1.7
1.3 1.7
1.3 1.7
1.5 1.8
1.6 1.8
CFC!3
ppt
190
175
175
175
215
270
345
420
440
555
445
300
435
455
410
330
295
245
250
290
275
265
375
385
CCI4
PPt
128
122
122
122
128
128
134
198
360
207
162
134
131
162
149
122
116
116
116
122
128
116
131
134
WS
mph
11
13
11
14
11
8
8
10
8
13
15
14
12
18
16
14
15
7
3
4
7
7
6
4
MET.
WD Ck
deg deg
260 6
265 6
260 6
255 5
270 7
270 8
270 8
270 7
255 7
250 7
255 6
255 7
240 7
260 6
260 7
260 6
260 6
270 8
270 10
270 13
260 11
270 14
270 10
275 7
DATA
RAD TMP
mLy °F
0 72
0 73
0 72
0 71
0 72
49 71
225 71
450 75
750 77
1000 76
1250 77
1 360 78
1350 79
1250 79
1050 81
640 81
570 80
360 83
150 83
50 80
3 78
0 78
0 80
0 79
DP
°F
66
64
64
65
64
64
64
65
66
66
67
68
69
69
69
69
69
70
70
70
70
70
70
70

-------
                        TABLE 21.  SURFACE DATA COLLECTED AT GROTON, CT ON AUGUST  1, 1975
01
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
Ppb
83
76
55
37
24
5
21
38
46
52
73
96
108
126
118
133
97
108
102
93
78
87
58
41
NO
ppb
9
9
8
8
8
10
10
11
10
13
12
11
12
11
11
9
10
9
8
7
7
6
7
6
N02
ppb
25
26
27
35
36
38
31
27
18
40
32
30
42
35
34
24
17
22
25
26
40
30
34
32
GAS
NMTHC
ppmC
.3
.2
.4
.4
.4
.4
.3
<. l
<.l
.2
.2
<. 1
<.l
<.l
<.l
<.l
<.l
< . 1
<.l
< . 1
.2
<. 1
.2
.2
DATA
CO CH4
ppm ppm
1.6 1.8
1.6 1.9
1.7 1.9
1.9 2.0
1.8 2.0
1.3 2.0
1.5 2.0
1.1 1.8
.8 1.8
1.2 1.8
1.6 1.8
1.7 1.9
1.7 1.8
1.3 1.8
1.3 1.8
1.3 1.8
.9 1.8
.9 1.7
1.2 1.7
1.5 1.7
1.8 1.8
1.5 1.8
1.9 1.8
1.8 1.8
CFCI3
PPt
385
360
410
510
490
370 >
410 >
350
275
280
290
365
325
280
260
280
220
210
320
325
375
355
355
425
cci4
PPt
137
140
162
162
162
1800
1800
302
140
220
162
152
152
134
140
140
128
128
128
140
128
128
134
140
WS
mph
2
3
2
1
1
2
1
2
3
4
5
7
6
8
9
11
10
9
10
6
2
2
3
£
MET.
WD Q^
deg deg
260 11
270 14
260 13
270 8
230 12
260 9
050 14
010 12
030 21
240 10
245 9
250 8
255 9
255 9
250 8
260 7
260 8
270 7
270 6
270 12
270 13
260 14
265 8
265 7
DATA
RAD TMP
mLy °F
0 78
0 75
0 75
0 75
0 73
60 74
200 76
450 82
800 87
1000 89
1150 84
1300 84
1325 86
1300 86
1175 85
1000 84
700 85
400 85
73 84
25 84
0 82
0 81
0 80
0 77
DP
°F
70
70
70
70
70
71
72
73
74
74
73
73
74
74
74
74
73
72
72
72
73
73
72
72

-------
TABLE 22.  SURFACE DATA COLLECTED AT GROTON, CT ON AUGUST 2, 1975
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
33
23
21
23
28
19
21
20
22
36
63
98
108
123
133
133
133
121
96
76
54
51
43
--
NO
ppb
7
7
7
7
7
8
9
11
12
14
8
11
10
12
8
9
9
8
7
7
6
8
8
9
GAS
N02 NMTHC
ppb ppmC
27 .2
28 .3
25 .3
23 .3
21 .3
22 .3
23 .3
30 .3
31 .3
35 .2
18 .2
30 .2
31 .2
30 .2
22 .2
17 .2
16 .2
22 .2
25 .2
38 .4
40 .4
26 .4
38 .4
30 .4
DATA
CO
ppm
1.5
1.1
.9
.9
.9
.9
.9
.8
.7
.7
.6
1.6
1.3
1.1
1.1
1.1
1.1
1.1
1.2
1.6
1.7
1.6
1.4
1.2
CH4
ppm
1.8
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.6
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.8
1.8
1.7
CFCI3
ppt
425
335
310
285
265
275
295
280
255
240
245
205
230
260
255
265
235
245
235
320
290
355
400
?75
cci4
PPt
140
140
131
125
131
131
131
342
451
262
232
153
131
131
131
131
131
131
128
134
128
140
134
122
WS
mph
4
3
3
3
3
4
5
3
3
4
2
5
9
12
13
14
12
10
7
3
2
3
3
3
MET.
WD Cfc
deg deg
270 7
270 9
265 13
250 12
260 8
260 8
260 7
250 12
250 14
260 13
260 9
240 14
250 10
260 8
255 8
260 7
260 7
260 8
265 11
265 7
240 13
250 12
245 20
260 14
DATA
RAD TMP
mLy °F
0 76
0 76
0 76
0 76
0 76
45 74
225 76
430 82
750 87
1025 92
1200 96
1300 90
1350 85
1300 84
1175 85
1000 86
725 86
400 83
200 81
25 81
0 78
0 80
0 83
0 82
DP
°F
72
71
72
72
71
70
71
72
71
74
76
75
73
73
74
74
74
73
72
73
72
75
77
75

-------
                        TABLE 23.  SURFACE DATA COLLECTED AT GROTON, CT ON AUGUST 3, 1975
co
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
ppb
32
28
26
18
20
36
29
37
41
48
62
88
110
121
126
129
131
126
120
93
73
66
56
53
NO
ppb
8
9
9
8
8
8
8
10
12
14
10
10
9
10
8
7
7
7
8
9
9
10
7
7
N02
ppb
28
26
19
25
21
17
23
24
22
26
21
30
18
18
17
19
18
27
15
10
12
10
13
12
GAS
NMTHC
ppmC
.3
.4
.3
.3
.3
.2
.4
.4
.4
.3
.3
.4
.3
.3
.2
.2
.2
.2
.2
.2
< . 1
< .1
< .1
.2
DATA
CO
ppm
1.2
1.2
1.0
1.0
.9
.7
.7
.7
1.1
1.0
1.0
1.3
1.2
1.2
1.2
1.3
1.5
1.6
1.1
.7
.5
.5
.7
.7
CH4
ppm
1.8
1.8
1.7
1.8
1.8
1.8
1.7
1.7
1.7
1.7
1.8
1.8
1.7
1.7
1.7,
1.7
1.7
1.7
1.7
1.6
1.6
1.6
1.6
1.6
CFCI3
ppt
265
295
260
270
295
245
355
310
265
240
260
295
275
275
275
270
260
245
245
215
190
195
245
245
CCI4
ppt
128
140
153
153
168
140
201
476
180
137
143
146
143
131
128
128
128
128
131
125
125
128
128
128
MET. DATA
WS WD Ck f^0 ™p
mph deg deg ml_y °F
CALM
CALM
CALM
CALM
CALM
CALM
CALM
3 255
5 255
6 250
5 250
7 255
9 250
12 250
10 255
7 235
4 215
3 140
9 095
10 090
10 075
7 070
6 040
6 030
11 0 81
10 0 78
16 0 76
16 0 75
18 0 75
13 39 76
15 167 77
15 513 84
11 821 83
12 757 82
13 955 83
11 1155 84
11 1273 84
8 1298 83
7 1091 85
9 628 84
8 338 84
12 318 84
18 158 81
16 55 82
26 0 78
20 0 76
18 0 77
16 0 75
DP
°F
73
73
72
71
72
71
71
73
73
72
73
74
74
74
74
73
72
72
72
69
71
71
71
68

-------
TABLE 24.  SURFACE DATA COLLECTED AT GROTON,  CT  ON  AUGUST  4,  1975
Time
to-
Ol 00
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
58
57
51
40
37
35
33
31
32
38
40
41
41
42
41
41
38
37
37
34
32
28
28
25
NO
ppb
7
7
7
7
7
7
7
7
8
9
9
9
9
9
9
8
6
8
7
7
7
7
6
7
N02
ppb
9
8
7
4
3
2
3
4
4
5
3
5
5
6
5
5
2
2
1
3
3
5
6
7
GAS
NMTHC
ppmC
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
<.l
<.l
<.l
<.l
<.l
<.l
<.l
<.l
<.!
<.l
<.l
<.l
<.l
<.l
DATA
CO
ppm
.5
.5
.5
.3
.2
.2
.2
.2
.2
.2
.2
.3
.3
.3
.3
.3
.3
.3
.3
,3
.3
.3
.3
.3
CH4
ppm
1.6
1.6
1.6
1.5
1.5*
1.5
1.5
1.5
1.5
1.5
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
CFCI3
ppt
210
200
200
155
140
140
145
145
155
150
145
145
141
136
132
132
132
132
136
136
141
141
154
150
cci4
ppt
128
128
125
116
116
116
116
116
122
116
116
116
116
116
116
116
116
116
116
116
127
116
127
116
WS
mph
6
6
4
7
5
4
6
5
7
9
9
7
7
7
9
9
8
8
7
4
MET. DATA
WD Q^ RAD TMP
deg deg mLy °F
035 15 0 74
035 17 0 74
035 17 0 73
060 23 0 72
055 21 0 72
045 14 16 72
055 14 51 72
050 19 72 72
080 12 90 73
080 11 145 73
080 9 255 72
085 7 422 74
075 16 268 74
080 14 270 74
085 10 239 74
080 17 244 74
085 22 295 73
075 24 75 72
065 24 49 72
055 19 0 72
CALM 19 0 72
5
4
4
050 19 0 72
035 15 0 72
055 18 0 72
DP
°F
68
68
68
68
68
68
67
67
66
67
67
68
67
67
67
66
65
66
66
66
67
67
67
68

-------
                           TABLE 25.   SURFACE DATA COLLECTED AT  GROTON,  CT ON AUGUST 5, 1975
o
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
21
23
23
21
20
9
12
7
18
24
25
65
80
89
105
112
105
97
77
73
64
43
30
28
NO
ppb
7
7
7
7
7
7
7
12
10
10
16
9
8
9
8
9
9
9
7
6
7
7
6
7
GAS DATA MET. DATA
N02 NMTHC CO CH4 CFCI3 CCI4 WS WD (^ RAD TMP DP
ppb ppmC ppm ppm ppt ppt mph deg deg ml_y °F °F
5 <.l .2 1.6 145 116 4 045 24 0 72 68
2 <.l .2 1.7 136 116 CALM 17 0 72 68
1 <.l .2 1.7 136 116 CALM 21 0 72 69
1 <.l .2 1.8 145 116 CALM 6 0 73 70
4 .2 .2 1.8 150 116 CALM 2 0 73 70
10 .2 .3 1.8 172 127 4 270 5 21 73 69
11 .2 .4 1.9 180 116 4 265 10 72 73 70
15 .2 .5 1.8 167 127 5 245 6 180 73 69
13 .2 .7 1.8 264 127 CALM 20 716 80 72
15 .3 .7 1.7 216 137 CALM 9 950 86 72
22 .2 .7 1.7 205 137 6 225 8 1147 80 70
20 <.l .7 1.8 221 137 11 250 7 1068 80 70
13 <.l .8 1.8 234 137 13 250 7 1377 71 71
15 .2 .8 1.7 238 137 13 255 6 1240 71 71
14 .2 .7 1.7 250 137 14 255 6 1200 82 71
10 .2 .7 1.7 254 127 15 260 7 1026 82 72
12 <.1 .5 1.7 213 127 14 260 6 850 83 70
17 <.1 .6 1.7 176 127 12 255 7 490 80 70
15 <.1 .6 1.7 160 127 10 255 8 159 77 69
10 <.1 .5 1.7 152 116 6 265 11 39 75 69
12 .2 .7 1.7 187 127 5 270 10 0 77 70
25 .4 1.3 1.8 262 127 CALM 16 0 77 69
35 .3 1.2 1.9 295 127 CALM 14 0 76 67
23 .2 .9 1.7 250 127 CALM 9 0 76 66

-------
TABLE.26.  SURFACE DATA COLLECTED AT GROTON,  CT  ON AUGUST 6,  1975
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
ppb
30
28
30
26
22
21
20
19
20
39
51
61
70
70
71
68
62
27
25
24
30
27
22
18
NO
ppb
6
6
7
6
6
6
7
7
8
8
9
9
9
8
8
8
9
8
8
8
8
7
6
6
GAS
N02 NMTHC
ppb ppmC
20 .2
22 <.l
14 <.l
14 <.l
11 <.l
9 <.l
11 <.l
12 <.l
11 <.l
10 <.l
19 <.l
22 <.!
12 <.l
10 <.l
9 <.l
8 <.l
12 .2
32 .2
28 <.l
20 <.l
14 <.l
9 <.l
8 <.l
10 <.l
DATA
CO
ppm
.8
.6
.5
.5
.5
.5
.5
.5
.5
.7
1.1
.9
.7
.7
.6
.7
.9
.9
.7
.5
.4
.3
.3
.3
CH4
ppm
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.8
1.8
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
CFCI3
ppt
221
213
217
201
180
180
185
197
189
197
316
369
282
221
205
201
221
299
271
234
187
152
148
148
cci4
ppt
338
422
159
137
127
127
127
127
127
127
127
127
127
127
127
127
127
137
127
127
116
127
127
127
WS
mph
4
4
5
7
7
7
5
5
6
5
5
7
8
6
8
6
5
9
11
12
11
12
9
9
MET.
WD O^
deg deg
038 17
025 14
010 22
015 14
015 15
023 16
030 16
025 19
020 17
050 20
130 18
085 20
085 17
080 18
087 18
090 13
060 23
035 17
033 17
028 18
042 16
039 13
045 13
030 17
DATA
RAD TMP
mLy °F
0 76
0 75
0 75
0 74
0 73
24 72
99 73
304 74
450 76
813 80
702 83
351 77
526 77
380 76
280 76
134 75
108 75
80 76
39 74
13 73
0 72
0 71
0 69
0 67
DP
°F
65
64
64
64
64
63
62
61
63
66
68
68
69
69
69
69
69
66
65
65
63
63
62
63

-------
                        TABLE  27.   SURFACE DATA COLLECTED AT GROTON, CT ON AUGUST 7, 1975
en
ro
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300'
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
ppb
17
17
16
17
18
16
15
13
13
12
13
14
13
15
13
14
8
11
12
12
15
15
13
12
NO
ppb
6
6
6
6
6
6
6
6
10
8
8
9
8
9
8
9
10
7
7
6
6
6
8
8
N02
ppb
9
8
7
5
4
5
6
6
8
8
8
8
12
11
13
13
20
16
12
11
8
8
10
13
GAS DATA
NMTHC CO
ppmC ppm
<.l .3
<.l .2
<.l .2
<.l .2
<.l .2
<.l .2
<.l .2
<.l .3
.2 .3
.2 .3
<.l .5
<.l .5
<.l .4
<.l .4
<.l .5
.2 1.0
<.l .5
<.l .4
<.l .3
<.l .3
<.l .3
< . 1- .3
<.l .3
<.l .3
CH4
ppm
1.7
1.7
1.7
1.7
1.7
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
CFCI3
ppt
140
140
137
133
140
144
148
152
152
125
203
187
195
183
179
183
223
179
179
156
144
144
144
144
cci4
ppt
127
127
127
127
127
127
127
127
127
127
127
127
137
127
127
127
148
127
127
127
137
137
137
MET.
WS WD (JQ
mph deg deg
10 025
10 025
12 025
10 020
11 020
10 020
11 020
11 020
12 020
13 020
12 025
14 020
9 020
7 020
4 015
6 020
CALM
CALM
3 025
CALM
CALM
4 030
CALM
127 CALM
17
18
14
16
14
16
17
16
18
18
15
17
18
19
26
22
7
7
7
7
7
7
3
7
DATA
RAD TMP
mLy °F
0 67
0 67
0 67
0 67
0 66
0 66
40 66
80 66
90 66
167 65
307 65
318 66
175 65
231 64
168 65
135 65
112 64
84 64
50 63
19 63
0 62
0 63
0 64
0 63
DP
°F
62
63
63
62
62
62
62
61
61
61
60
59
59
59
60
59
59
59
59
58
58
57
57
57

-------
                        TABLE  28.   SURFACE  DATA  COLLECTED AT GROTON, CT ON AUGUST 8, 1975
CO
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
ppb
11
13
16
11
13
10
10
8
11
11
10
8
14
13
12
8
<5
8
<5
5
<5
<5
<5
<5
NO
ppb
8
6
6
8
6
8
8
10
9
9
10
10
13
16
11
10
12
10
7
7
8
6
9
9
N02
ppb
14
9
6
13
7
13
10
11
9
11
8
13
15
17
14
16
20
15
18
16
22
18
20
19
GAS
NMTHC
ppmC
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< . 1
< . 1
< .1
.2
.2
.2
.2
< .1
<.l
DATA
CO
ppm
.3
.2
.2
.2
.2
.2
.4
.4
.4
.4
.5
.7
.5
.5
.7
.7
.6
.5
.5
.5
.6
.6
.7
.5
CH4
ppm
1.7
1.7
1.7
1.7
1.7
1.7
IH
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.6
1.6
1.6
1.6
1.7
1.7
CFCI3
ppt
148
140
140
140
140
140
156
164
168
176
183
176
168
179
191
168
160
167
167
179
182
186
209
186
cci4
ppt
127
127
127
137
137
137
127
137
127
127
127
127
127
127
127
127
116
116
116
395
125
135
125
116
MET. DATA
WS WD Q^ RAD TMP
mph deg deg mLy °F
CALM
3 250
3 220
3 230
3 240
CALM
3 220
CALM
CALM
3 220
4 240
3 230
CALM
CALM
5 025
3 240
CALM
CALM
CALM
3 030
CALM
CALM
CALM
3 265
7 0 63
8 0 64
7 0 64
7 0 63
10 0 63
7 19 64
7 248 67
7 370 67
7 458 70
12 272 70
23 742 68
15 321 70
7 476 73
7 500 70
7 385 69
7 280 71
7 200 69
7 160 71
7 30 70
13 12 69
9 0 69
7 0 69
20 0 69
10 0 69
DP
°F
57
58
58
58
58
59
59
59
61
61
61
62
63
63
62
64
64
64
64
63
63
63
62
62

-------
                        TABLE 29.   SURFACE  DATA COLLECTED AT GROTON, CT ON AUGUST 9, 1975
tn
.pa
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
°3
Ppb
<5
<5
<5
< 5
< 5
< 5
< 5
11
20
35
45
50
70
81
82
82
94
96
88
72
50
25
16
2400 40
NO
ppb
8
8
9
8
8
8
9
9
8
8
8
9
10
8
6
6
6
8
8
7
6
8
6
	 L_
GAS
N02 NMTHC
ppb ppmC
14 <.l
14 <.l
17 <.l
15 <.l
17 <.l
18 <.l
16 <.l
17 <.l
14 <.l
14 <.l
19 <.l
18 <.-!
20 < .1
15 <.l
11 <.l
10 <.l
11 < .1
12 < .1
13 < .1
16 <.l
24 .2
30 .3
33
22 -
DATA
CO
ppm
,5
.6
.6
.6
.6
.7
.6
.6
.5
.5
.7
.7
.6
.6
.6
.5
.5
.5
.6
.9
1.0
1.4
--
—
CH4
ppm
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.6
1.6
1.7
1.7
1.7
--
—
CFCI3
Ppt
167
175
171
175
190
190
194
205
201
190
175
160
182
186
179
175
175
163
243
300
285
270
292
248
cci4
PPt
116
125
125
116
116
125
299
289
164
125
125
116
116
116
125
125
125
125
125
125
125
116
108
MET.
WS WD O^
mph deg deg
5 265
3 vrb
3 260
4 270
5 275
CALM
CALM
CALM
CALM
3 030
4 240
7 230
15 240
14 250
17 260
18 260
18 268
17 270
12 275
7 280
6 285
6 290
3 280
108 6 285
8
15
11
7
11
12
10
10
7
10
18
9
9
9
6
6
6
6
7
6
11
11
16
8
DATA
RAD TMP
mLy °F
0 68
0 68
0 67
0 67
0 67
21 65
97 65
497 67
836 76
1063 78
1268 80
1405 77
1442 76
1410 76
1251 77
1023 78
745 77
522 77
219 76
10 74
0 73
0 72
0 70
0 70
DP
°F
62
62
62
62
62
61
62
63
64
63
63
65
65
64
64
63
63
63
65
62
62
62
61
63

-------
                        TABLE 30.  SURFACE DATA COLLECTED  AT  6ROTON,  CT ON  AUGUST 10, 1975
en
en
Time 0^
hr ppb
0100 40
0200 13
0300 13
0400 16
0500 18
0600 16
0700 18
0800 29
0900 36
1000 52
1100 68
1200 93
1300 110
1400 113
1500 103
1600 100
1700 108
1800 130
1900 115
2000 150
2100 150
2200 130
2300 116
2400 90
NO
ppb
6
6
6
6
6
6
7
6
7
7
9
8
9
8
7
7
7
7
7
6
6
6
6
8
GAS DATA MET. DATA
N02 NMTHC CO CH4 CFCI3 CCI4 WS WD Q^ RAD TMP DP
ppb ppmC ppm ppm ppt ppt mph deg deg mLy °F °F
20 	 259 116 4 290 12 0 69 63
30 — -- -- 256 108 5 275 10 0 67 62
27 	 256 108 6 278 10 0 66 60
20 — -- -- 241 108 5 283 10 0 66 58
18 -- -- — 220 116 4 290 11 9 65 58
15 -- - — 216 108 4 285 7 30 66 59
16 	 202 116 7 278 6 206 67 59
13 	 202 116 6 270 5 508 70 60
13 <.l .5 1.7 191 108 8 270 6 803 73 63
20 <.l .7 1.7 212 116 9 260 7 1023 74 64
18 <.l .7 1.7 230 116 13 262 7 1117 74 65
16 <.l .7 .17 216 116 17 270 7 1285 76 65
17 <.l .7 1.7 202 108 16 270 6 1200 76 65
19 <.l .7 1.7 223 108 15 266 7 1276 78 66
15 .2 .8 1.7 205 116 16 270 6 698 80 62
15 <.l .7 1.7 187 116 13 267 6 850 80 64
20 <.l .8 1.7 194 116 12 265 8 500 79 64
17 <.l .8 1.7 230 116 10 270 6 180 77 66
29 <.l .9 1.7 274 116 7 275 6 74 78 64
22 <.l .9 1.7 281 124 9 280 7 24 76 66
23 .2 1.0 1.8 277 116 4 275 9 0 74 67
22 .3 1.0 1.8 302 116 3 280 14 0 77 66
24 .3 1.0 1.8 310 116 6 275 17 0 78 66
25 — -- — 320 124 CALM 12 0 77 68

-------
                         TABLE  31.   SURFACE DATA COLLECTED AT 6ROTON, CT ON AUGUST 11, 1975
en
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
°3
ppb
97
75
62
50
42
18
<5
15
25
33
60
73
100
103
94
91
86
73
83
80
79
71
60
2400 55
GAS DATA MET. DATA
NO N02 NMTHC CO CH4 CFCI3 CCI4 WS WD (JQ RAD TMP DP
ppb ppb ppmC ppm ppm ppt ppt mph deg deg mLy °F °F
8 22 - 	 324 124 4 280 14 0 74 67
8 19 — -- -- 331 124 3 280 10 0 73 67
7 21 	 346 124 4 270 10 0 73 67
7 18 	 324 124 4 283 5 0 71 67
7 21 -- -- — 342 249 CALM 11 0 70 67
•7 27 — — — 382 240 CALM 10 27 69 66
13 34 	 367 >1300 CALM 9 189 71 67
18 38 	 400 >1300 CALM 14 406 74 69
13 28 -- — -- 281 257 5 275 9 422 75 68
11 19 	 284 116 8 265 9 641 75 68
10 20 .2 .9 1.8 304 135 11 265 7 1004 77 69
9 30 .2 1.1 1.9 334 135 10 262 7 857 77 69
9 26 .2 1.1 1.9 365 135 10 264 6 1400 79 70
7 25 <.l .9 1.8 327 135 10 262 6 1200 79 69
7 25 <.l .8 1.8 274 145 8 264 9 887 78 69
8 20 <.l .7 1.8 251 135 8 265 6 598 77 69
7 26 <.l .6 1.8 213 154 8 268 6 243 79 69
7 40 <.l .8 1.8 228 145 5 263 7 250 76 68
7 28 <.l .8 1.8 228 145 CALM 15 142 77 69
7 30 <.l .7 1.8 228 145 5 280 6 35 76 68
7 30 <.l .7 1.7 228 154 5 273 7 0 74 68
8 15 <.l .5 1.7 201 125 10 275 6 0 74 68
9 14 <.l .3 1.7 175 125 10 276 6 0 75 67
9 10 <.l .3 1.7 179 125 4 285 11 0 74 67

-------
                        TABLE 32.   SURFACE DATA COLLECTED AT GROTON, CT ON AUGUST 12, 1975
en

Time 0^
hr ppb
0100 40
0200 40
0300 37
0400 33
0500 28
0600 20
0700 14
0800 19
0900 35
1000 48
1100 54
1200 62
1300 84
1400 106
1500 110
1600 111
1700 110
1800 116
1900 98
2000 58
2100 37
2200 29
2300 20
2400 15
NO
ppb
8
6
7
6
6
6
9
13
10
11
9
12
11
9
8
7
7
7
6
6
7
6
7
7
GAS DATA MET. DATA
N02 NMTHC CO CH4 CFCI3 CCI4 WS WD Q^ ^D TMP DP
ppb ppmC ppm ppm ppt ppt mph deg deg mLy °F °F
15 <.l .3 1.7 182 125 5 285 9 0 72 67
11 <.l .4 1.7 217 135 5 285 7 0 72 67
12 <.l .4 1.7 220 125 3 280 8 0 72 65
15 <.l .4 1.7 194 231 CALM 10 0 69 62
15 <.l .3 1.7 190 145 CALM 11 0 68 62
24 <.l .3 1.7 209 443 CALM 18 0 67 61
32 <.l .5 1.7 243 896 CALM 8 162 68 62
33 <.l .8 1.7 350 569 CALM 22 439 74 63
25 <.l .7 1.7 255 251 CALM 12 714 80 65
21 <.l .4 1.7 217 193 CALM 8 1003 85 67
16 <.l .3 1.7 182 145 7 260 11 1173 83 66
20 <.l .4 1.7 175 125 9 255 9 1224 79 66
18 <.l .4 1.7 186 135 9 245 6 1368 79 68
20 <.l .6 1.7 346 135 14 262 7 1242 78 69
15 <.l .7 1.7 289 135 15 262 8 1218 78 68
15 <.l .5 1.6 319 145 18 266 6 785 80 78
17 <.l .5 1.6 232 145 14 263 6 674 79 68
20 <.l .6 1.6 217 145 11 264 7 366 77 68
20 <.l .7 1.7 247 145 5 275 11 137 76 68
40 <.l .9 1.7 308 145 3 250 12 23 75 69
30 <.l 1.2 1.7 315 135 3 260 11 0 75 64
25 <.l .6 1.7 251 540 3 260 13 0 76 64
31 <.l .8 1.8 243 260 CALM 10 0 74 64
36 <.l .9 1.8 274 520 CALM 13 0 73 64

-------
                         TABLE 33.  SURFACE DATA COLLECTED AT GROTON, CT ON AUGUST 13, 1975
en
oo
Time 0-a
hr ppb
0100 19
0200 <5
0300 <5
0400 <5
0500 14
0600 23
0700 16
0800 14
0900 25
1000 35
1100 42
1200 66
1300 87
1400 80
1500 89
1600 76
1700 81
1800 73
1900 74
2000 82
2100 114
2200 117
2300 120
2400 116
NO
ppb
8
9
11
10
9
10
11
12
10
15
14
12
12
10
10
10
8
8
7
7
7
8
6
7
GAS DATA MET DATA
N02 NMTHC CO CH4 CFCI3 CCI4 WS WD 0^ RAD IMP DP
ppb ppmC ppm ppm ppt ppt mph deg deg mLy °F °F
31 .2 .7 1.8 259 550 CALM 8 0 73 65
36 .2 .7 1.8 274 462 CALM 11 0 71 64
38 <.l .7 1.8 266 752 CALM 12 0 70 65
33 <.l .5 1.8 252 790 ,GALM 11 0 70 65
27 <.l .5 1.8 229 925 5 035 12 0 70 64
18 <.l .5 1.8 241 434 CALM 11 35 69 63
23 <.l .7 1.8 348 366 CALM 12 202 70 64
28 <.l .7 1.8 303 145 3 035 17 473 73 65
13 <.l .4 1.7 233 135 CALM 11 752 78 65
23 <.l .6 1.7 211 135 3 200 14 1014 79 66
33 <.l .9 1.8 233 151 5 240 5 1191 78 67
29 <.l .7 1.8 255 241 7 250 7 1335 78 68
23 <.l .7 1.7 218 183 6 248 4 1388 78 68
20 <.l .8 1.7 185 145 6 240 7 1353 80 67
16 <.l .6 1.7 174 155 7 233 8 1195 80 68
12 <.l .4 1.7 159 155 9 230 8 699 79 68
10 <.l .4 1.7 167 164 7 230 8 431 77 67
12 <.l .5 1.7 178 135 6 260 10 285 75 67
14 <.l .5 1.7 170 135 6 240 8 156 75 66
10 <.l .5 1.7 178 125 8 242 4 24 74 67
12 <.l .5 1.6 229 135 12 230 6 0 73 67
8 <.l .5 1.8 237 135 12 225 7 0 74 68
8 <.l .5 1.8 237 154 7 265 8 0 74 67
6 <.l .4 1.8 248 173 7 270 6 0 75 68

-------
                       TABLE 34.   SURFACE DATA COLLECTED AT GROTON, CT ON AUGUST 14, 1975
en
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
°3
Ppb
80
16
13
19
25
16
23
28
30
30
38
60
73
90
116
110
87
76
51
32
26
32
31
2400 31
NO
ppb
7
6
6
6
8
7
7
7
10
12
14
10
11
9
9
9
9
9
10
8
8
7
6
7
GAS
N02 NMTHC
ppb ppmC
8 <-l
40 .2
45 .2
27 <.l
24 <.l
26 <.l
20 <.l
20 <.l
20 <.l
26 <.l
29 <.l
18 <.l
22 <.l
23 <.l
16 <.l
14 <.l
11 <.l
13 <.l
19 <.l
27 <.l
26 <.l
17 <.l
14 <.l
10 <.l
DATA
CO
ppm
.3
.8
.6
.5
.4
.4
.3
.6
.9
.Q
1.0
1.1
1.2
1.2
1.2
1.0
.9
.8
1.0
1.2
1.1
.7
.7
.7
CH4
ppm
1.8
1.8
1.8
1.8
1.7
1.7
1.7
1.7
1.7
1.9
1.9
1.8
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.6
1.6
1.6
1.6
CFCI3
ppt
270
418
392
281
248
241
233

211
237
263
248
289
307
237
200
167
159
181
222
207
178
174
163
cci4
PPt
124
154
145
135
135
135
135
—
145
145
145
145
145
145
145
135
135
135
135
173
154
145
135
MET. DATA
WS WD Q^ RAD
mph deg deg ml_y
10 265
10 270
16 270
13 275
7 285
3 280
9 274
11 280
14 272
12 275
13 268
9 270
17 264
16 265
18 270
17 273
16 273
13 273
5 275
CALM
CALM
CALM
CALM
145 CALM
5 0
5 0
6 0
6 0
10 0
16 0
9 34
9 119
6 364
7 778
6 1139
12 1163
9 1283
7 1267
6 1209
6 857
6 708
8 469
16 268
10 36
Q 0
7 0
13 0
7 .0
TMP
°F
73
72
73
73
74
72
73
74
75
78
79
83
80
79
79
80
80
78
81
80
78
76
74
73
DP
°F
68
67
66
66
66
66
66
65
66
67
68
70
69
70
70
69
69
68
67
61
61
59
57
56

-------
                        TABLE 35.  SURFACE DATA COLLECTED AT GROTON, CT ON AUGUST  15,  1975
cr>
o
Time 0^
hr ppb
0100 27
0200 24
0300 11
0400 16
0500 20
i
0600 15
0700 13
0800 16
0900 28
1000 36
1100 41
1200 59
1300 66
1400 64
1500 63
1600 80
1700 77
1800 57
1900 56
2000 46
2100 50
2200 53
2300 45
2400 45
NO
ppb
6
6
6
6
6

6
7
10
10
9
7
8
10
9
10
10
10
9
8
6
7
6
7
6
GAS
N02 NMTHC
ppb ppmC
12 <.l
12 <.l
24 <.l
15 <.l
11 <.l

17 <.l
20 <.l
19 
-------
                        TABLE  36.   SURFACE  DATA COLLECTED AT GROTON,  CT ON AUGUST 16, 1975
CTl
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
Ppb
42
33
12
18
34
27
22
25
30
37
40
44
54
60
54
51
48
47
45
46
49
58
63
60
NO
Ppb
6
6
6
6
6
6
7
7
7
7
9
9
7
7
8
8
8
8
7
7
7
6
7
6
N02
ppb
8
9
35
30
16
19
21
23
15
20
19
17
8
5
4
4
6
9
4
5
2
4
3
3
GAS
NMTHC
ppmC
<.l
< .1
< .1
< .1
< . 1.
< .1
.2
.2
.2
< .1
< .1
< . 1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
< .1
DATA
CO
ppm
.8
1.0
1.2
1.0
.9
1.0
1.2
1.6
1.2
1.2
1.2
1.2
.7
.7
.7
.8
.8
.8
.8
.8
.8
.7
.6
.7
CH4
ppm
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.7
1.7
1.7
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
CFCI3
PPt
166
180
194
184
173
173
191
234
169
166
169
176
144
140
137
140
140
140
144
144
137
137
144
144
cci4
PPt
116
116
134
116
116
116
116
124
124
134
124
124
124
124
124
124
124
124
124
124
124
124
124
124
MET. DATA
WS WD Q^ K*D ™P
mph deg deg mLy °F
CALM
CALM
3 070
3 060
3 068
3 090
3 040
3 045
3 050
CALM
7 245
10 272
14 245
8 210
5 120
4 070
4 067
3 060
3 045
4 115
5 153
11 153
7 155
8 150
16 0 72
13 0 72
20 0 72
18 0 71
15 0 71
13 0 70
9 42 71
8 126 71
15 193 72
10 138 73
4 317 73
7 259 70
4 190 68
10 256 67
9 237 68
21 222 69
21 181 69
23 138 69
22 50 67
17 0 68
9 0 68
14 0 68
17 0 67
16 0 67
DP
°F
66
66
66
66
65
66
66
67
68
67
68
63
62
62
62
62
62
63
61
62
63
62
60
60

-------
                         TABLE 37.  SURFACE DATA COLLECTED  AT GROTON, CT ON AUGUST 17, 1975
CTi
(V)
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
°3
ppb
52
44
38
36
40
39
35
32
38
38
51
55
53
50
50
42
41
42
37
35
18
5
20
2400 18
NO
ppb
6
7
6
6
6
5
6
6
7
8
8
8
8
7
7
7
7
7
6
6
6
9
6
6
N02
ppb
2
4
3
4
5
4
5
7
5
8
5
3
6
5
9
8
12
10
10
18
24
40
27
25
GAS DATA
NMTHC CO
ppmC ppm
.3 .6
.3 .6
.3 .6
.3 .6
<.l .6
.3 .6
<.l .6
<.l .7
<.l .7
<.l .7
<.l .7
.2 .7
.2 .7
.2 .8
.2 .9
.2 1.0
.2 .9
<.l .9
<.l 1.0
<.l 1.3
<.l 1.6
<.l 1.6
.2 1.4
.2 1.4
CH4
ppm
1.6
1.6
1.6
1.6
1.-6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
l.fi
CFCI3
PPt
140
140
137
140
140
140
140
148
144
155
144
140
140
137
140
144
144
144
151
182
193
193
231
231
cci4
ppt
124
124
124
124
124
124
124
124
124
124
135
135
135
135
135
135
135
135
135
135
135
135
145
WS
mph
5
5
4
5
6
5
5
5
4
4
6
4
3
7

5
9
8
6
3
6
4
3
135
MET.
WD (^
deg deg
080 9
038 15
045 15
036 15
045 15
053 14
042 15
030 14
040 19
070 22
087 7
088 13
145 10
155 14
CALM 9
240 5
260 6
265 6
270 6
270 6
285 12
282 10
268 17
CALM 16
DATA
RAD TMP
mLy °F
0 66
0 66
0 66
0 65
0 65
0 65
65 65
134 66
267 68
295 69
289 70
309 70
259 71
593 72
295 72
531 73
142 71
186 71
95 71
0 71
0 70
0 71
0 70
0 70
DP
°F
60
61
61
61
60
59
59
60
61
62
63
63
63
63
63
63
63
64
64
65
65
65
64
64

-------
                         TABLE 38.   SURFACE DATA COLLECTED AT GROTON, CT ON AUGUST 18,  1975
01
CO
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
°3
ppb
20
31
34
34
32
25
19
23
31
43
57
80
100
124
136
138
141
132
118
68
40
35
33
2400 34
NO
ppb
6
6
6
6
7
6
7
7
8
8
6
7
7
7
6
6
6
6
6
6
6
5
5
5
N02
ppb
19
13
9
8
8
15
31
23
14
12
15
17
15
17
20
17
15
16
11
21
25
20
21
20
GAS
NMTHC
ppmC
<.l
<.l
<.l
<.l
—
-_
--
—
—
.2
.2
.2
.2
.2
.2
.2
.2
<.l
<.l
<.l
< .1
—
--
--
DATA
CO
ppm
1.2
1.0
.9
.9
—
—
-_
—
--
1.0
1.2
1.4
1.6
1.6
1.7
1.6
1.4
1.2
1.2
1.0
.9
—
—
—
CH4
ppm
1.6
1.7
1.6
1.6
—
—
--
—
--
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1;6
1.6
—
--
—
CFCI3
ppt
207
193
186
186
189
238
340
350
298
270
270
280
378
417
368
340
291
280
228
224
210
175
172
179
cci4
PPt
135
145
135
135
164
145
145
164
145
154
154
164
164
164
173
164
154
154
154
145
279
299
501
MET. DATA
WS WD (JQ RAD
mph deg deg ml_y
4 275 20 0
8 284 8 0
6 280 10 0
6 286 10 0
3 265 20 0
5 278 13 0
6 285 9 36
3 265 20 80
4 270 18 470
8 265 8 839
13 264 7 844
16 260 7 1198
16 262 7 1198
19 260 6 1270
17 265 5 785
16 275 7 650
15 270 5 540
12 268 5 373
12 270 6 126
8 280 12 0
CALM 14 0
CALM 7 0
CALM 7 0
492 CALM 7 0
TMP
0F
70
70
70
70
68
69
70
70
72
75
74
75
75
76
76
78
77
77
75
76
75
73
71
69
DP
°F
63
63
63
62
62
63
64
65
65
65
66
66
67
67
68
68
68
68
67
65
63
57
53
52

-------
                        TABLE 39.  SURFACE  DATA  COLLECTED AT  6ROTON,  CT ON AUGUST  19,  1975
en
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
°3
ppb
40
34
30
35
24
29
31
31
27
30
37
45
56
67
68
73
76
80
68
35
19
<5
<5
2400 15
NO
ppb
5
5
5
5
5
6
7
10
11
9
7
6
6
8
7
6
7
10
14
5
5
28
32
6
GAS DATA
N02 NMTHC CO CH4
ppb ppmC ppm ppm
12
15
17
11
21
13
13
16
19
14
10
8
9
13
8
8 	
14
8
9
27 	
38 	 -
60
60
32 	 -
CFCI3
PPt
172
165
161
165
165
168
189
238
231
231
228
151
166
157
147
157
160
160
160
192
250
301
266
182
cci4
PPt
347
318
501
241
501
386
145
251
164
231
193
145
145
133
124
149
124
116
116
124
182
149
174
MET.
WS WD Ck
mph deg deg
3 275
CALM
CALM
3 265
CALM
CALM
4 275
3 265
3 249
3 250
3 270
6 269
5 270
13 260
23 269
22 267
22 269
16 260
8 290
3 270
CALM
3 050
3 060
224 3 040
12
10
10
18
9
21
16
15
12
12
7
20
24
8
6
6
6
7
5
19
14
6
4
17
DATA
RAD
mLy
0
0
0
0
0
0
218
519
802
1049
1243
1372
1419
1361
1221
1000
749
420
120
0
0
0
0
0
TMP
°F
68
66
64
63
62
60
62
65
69
73
76
77
78
77
75
74
74
74
73
70
69
66
65
66
DP
°F
49
46
47
49
48
48
51
51
52
52
52
47
48
54
55
56
57
57
57
53
51
54
53
51

-------
                        TABLE 40.  SURFACE DATA COLLECTED AT GROTON,  CT ON  AUGUST 20,  1975
CTl
cn
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
°3
ppb
16
<5
<5
<5
5
12
10
24
23
28
42
51
54
50
59
64
59
57
47
38
27
23
<5
2400 <5
NO
ppb
6
45
52
36
7
6
12
10
16
14
7
7
7
6
7
7
6
6
6
6
5
5
35
45
GAS DATA
N02 NMTHC CO CH4
ppb ppmC ppm ppm
30
58
60
49
30
31
33
28 	
32
26
16
11 	
10 	
9
9 	 -
10
9
11
13
27
37
36
68
65 	
CFCI3
ppt
259
163
173
141
112
106
131
125
118
131
195
166
157
154
157
147
157
160
173
195
221
227
304
358
cci4
ppt
199
182
362
506
240
141
149
133
149
124
158
141
133
141
141
124
166
224
149
124
348
572
249
MET.
WS WD Ck
mph deg deg
3
4
3
3
3

4
5
4
3

7

3
4
6
3
3
4
3



224 ?
030
030
030
035
036
CALM
035
035
030
036
CALM
265
CALM
300
270
270
280
265
270
270
CALM
CALM
CALM
052
6
6
9
14
12
14
11
7
12
14
7
17
8
8
10
19
8
11
20
14
10
12
15
10
DATA
RAD
mLy
0
0
0
0
0
0
198
432
912
1047
1224
1375
1465
1155
1145
595
757
478
170
0
0
0
0
0
TMP
0F
65
64
64
63
61
63
63
67
70
73
77
79
77
79
79
79
80
78
75
70
67
67
63
61
DP
°F
51
54
54
54
52
51
52
52
52
50
51
53
53
48
48
49
48
47
47
49
49
48
52
52

-------
                         TABLE 41.   SURFACE DATA COLLECTED AT GROTON, CT ON AUGUST 21, 1975
01
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
°3
Ppb
<5
<5
<5
15
<5
5
<5
<5
13
27
36
52
54
80
105
77
67
75
90
L05
96
95
91
75
NO
ppb
50
19
20
7
18
6
20
31
28
18
16
10
1
6
6
6
6
5
7
6
5
5
3
3
GAS DATA
N02 NMTHC CO CH4
ppb ppmC ppm ppni
63
46
44 	
28 	 -
38 	
27
32 	
38
45
36 	 -
41 	
24
12 	 -
13
13
8 v-__
16
20 	
25 	
6 	
5 	
5
5
3 	
CFCI3
ppt
336
243
234
202
221
224
237
282
339
275
131
198
154
182
179
154
144
163
218
192
179
176
176
176
cci4
ppt
157
>500
>900
539
672
299
639
>900
473
282
265
149
124
124
124
124
124
124
141
141
133
133
124
WS
mph
CALM
3
CALM
4
3
CALM
CALM
3
CALM
3
5
8
8
10
12
14
12
12
9
19
20
20
22
133 22
MET.
WD O^
cleg deg

050

042
030


270

220
235
242
248
245
255
263
245
250
245
245
245
243
247
252
12
11
9
13
13
7
13
15
10
19
7
5
6
4
6
6
3
6
5
3
4
3
6
6
DATA
RAD
mLy
0
0
0
0
0
0
176
442
761
1021
1200
1292
1361
997
974
640
271
170
62
0
0
0
0
0
TMP
°F
61
60
61
61
57
56
59
62
66
73
73
73
74
75
75
74
73
73
73
72
72
72
71
72
DP
°F
53
49
51
49
48
47
49
51
51
53
55
56
54
58
58
54
57
57
61
62
62
62
62
63

-------
                        TABLE 42.   SURFACE DATA COLLECTED AT GROTON, CT ON AUGUST 22, 1975
en
Time
hr
0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
°3
ppb
69
63
56
45
40
36
25
23
20
20
32
NO
ppb
4
3
3
3
4
3
5
5
6
6
8
GAS DATA
N02 NMTHC CO CH4
ppb ppmC ppm ppm
3
3
2
5
4 	
5
12
15
20
20
22
CFCI3
ppt
173
166
160
154
150
160
182
198
253
291
342
cci4
ppt
124
124
124
124
124
133
141
158
158
141
141
WS
mph
19
22
23
23
20
18
16
16
18
13
11
MET.
WD (J&
deg deg
252
251
254
255
260
270
266
264
260
266
275
6
5
7
6
6
7
5
5
6
5
8
DATA
RAD
mLy
0
0
0
0
0
0
0
190
109
621
669
TMP
°F
72
72
72
73
73
73
73
72
73
74
78
DP
°F
64
64
65
67
67
68
68
68
68
69
70

-------
LIGHT HYDROCARBON DATA AT GROUND LEVEL
     This section provides a listing of individual  light hydrocarbon
concentrations measured at the two ground sites.   The trailer site refers
to samples collected near our mobile laboratory at Avery Point, while the
inland site was to the northwest of Groton near the Devils  Hopyard State
Park (see Figure 1).
NOTES ON TABLES:
     All light hydrocarbon concentrations  are  reported  as  iag/m3.
     * = less than 0.5 pg/m3 (0.8 ppb C)
     Blank space = no data, either because the value  obtained  was
                   questionable or the measurement was  not made.
     Times are Eastern Daylight Time.
                                   68

-------
        TABLE  43.  HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
                    AT GROUND SITES ON JULY 15, 1975.


Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
6-1
3.5

1.0
2.0
3.0
1.0
1.0

.5
.5
*
*
*
1.0
.5
*
*
*
.5
*
*
15
G-2
4.0

2.0
2.0
3.5
*
2.0

1.0
1.0
*
*
*
3.0
2.0
1.0
.5
1.5
1.0
1.0
*
26
G-3
4.0

*
1.5
1.5
1.0
2.0

.5
*
*
*
*
5.0
3.0
*
*
2.0
*
*
*
21
G-4
3.0

*
1.5
1.5
*
1.0

*
*
*
*
*
*
*
*
*
*
1.0
*
*
8
G-l     Trailer Site    6:00-8:00 a.m.
G-2      Trailer Site  12:00-1:00 p.m.
G-3      Trailer Site   3:20 p.m.
G-4      Trailer Site  10:30 p.m.
                                     69

-------
TABLE  44.  HYDROCARBON CONCENTRATIONS  IN  SAMPLES  COLLECTED
            AT GROUND SITES ON JULY 16,  1975.

Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
G-l
2.0
7.5
*
1.5
*
1.0
1.0
*
*
*
*
*
*
1.0
.5
*
*
*
*
*
*
15
G-2
3.0
7.0
.5
1.0
*
1.0
1.0
*
*
*
*
*
*
1.5
1.0
*
*
*
*
*
*
16
G-3
3.0
7.5
*
1.0
*
.5
1.5
.5
*
*
*
*
*
2.0
1.0
*
*
.5
.5
.5
*
19
G-4 G-5
3.5 4.0

* *
1.5 1.5
1.5 1.5
.5 2.0
1.0 6.0
*
* *
* *
* *
* *
* *
1.0 4.0
* 2.0
* 1.0
* *
* *
1.0 *
* *
* *
10 22

G-l Trailer Site
G-2 Trailer Site
G-3 Trailer Site
G-4 Trailer Site
G-5 Inland Site
6
n
2
10
6
:00-8:00 a.m.
:00 a.m.
:00 p.m.
:30 p.m.
:00-8:00 a.m.










                           70

-------
TABLE  45.  HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
            AT GROUND SITES ON JULY 17, 1975.
            6-1         G-2        G-3
Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
..„.,.....,...—.,- .ii.i ... - — '•- —
G-l Trailer Site
G-2 Trailer Site
G-3 Inland Site
4.5
*
*
1.5
.5
.5
1.0
1.0
*
*
*
*
*
1.5
1.0
*
*
.5 -
*
*
*
12
6
12
3
2.5
6.0
*
1.5
*
.5
1.0
*
*
*
*
*
*
1.5
1.0
*
*
*
*
*
*
14
z. • -- • '— '
:00-8:00 a.m.
:00 noon
:00-5:00 p.m.
2.5
6.0
2.0
3.0
4.5
1.0
2.5
.5

.5
*
*
*
2.5
2.0
.5
*
*
*
*
*
28



                             71

-------
TABLE  46.  HYDROCARBON CONCENTRATIONS  IN  SAMPLES  COLLECTED
            AT GROUND SITES ON JULY  18,  1975.
G-l
Ethane 3.5
Ethylene 4.5
Acetylene *
Propane 2.5
Propene *
i -Butane 1 .0
n-Butane 1.5
neo-Pentane *
1-Butene *
i-Butene *
t-2-Butene *
Propyne *
c-2-Butene *
i-Pentane 1 .0
n-Pentane l .0
Cyclopentane *
1-Pentene *
i-Hexane .5
3-Methylpentane 1 .0
n-Hexane *
Cyclohexane *
3
Total yg/m 16
G-2
4.0
7.5
1.0
4.0
3.0
2.0
3.5
*
*
1.0
*
*
*
4.0
3.0
*
*
1.5
1.0
1.0
*
37
G-3
6.5
3.0
2.0
9.0
2.0
8.0
11.0
*
*
*
*
*
*
10.0
6.0
.5
*
2.5
2.0
2.5
*
55
G-4
7.0
3.5
3.0
7.5
1.0
7.0
11.5
1.0
.5
*
*
*
*
11.0
5.5
.5
*
3.0
2.0
*
2.5
67
G-5
9.5
4.5
4.0
10.5
1.5
10.5
17.0
*
*
.5
*
*
*
16.5
9.0
1.0
*
*
*
*
*
85
G-6
4.0
1.5
1.0
2.0
.5
1.0
3.0
*
*
*
*
*
*
4.0
2.5
*
*
*
2.0
*
*
22
G-7
2.0
3.0
2.0
3.0
2.0
3.0
5.5
*
*
1.0
*
*
*
5.5
3.0
*
*
1.5
*
*
*
32
G-8
5.5
7.0
2.5
6.0
6.5
5.0
9.5
2.5
1.0
*
.5
*
*
10.0
4.5
1.0
.5
3.0
3.0
1.5
*
70
G-9
4.0
3.0
2.0
3.5
1.5
2.5
5.0
*
*
*
*
*
*
4.5
2.5
*
*
1.5
3.5
*
*
34

G-l Trailer Site
G-2 Trailer Site
G-3 Trailer Site
G-4 Trailer Site
G-5 Trailer Site
G-6 Trailer Site
G-7 Inland Site
G-8 Inland Site
G-9 Inland Site
12:45 a
6:00-8
11:00 a
.m.
:00 a.m.
.m.


















12:00 noon
1:00 p
9:30 p
1:00-3
6:00-8
2:00-5
.IT).
.m.
:00 a.m.
:00 a.m.
:00 p.m.






























                           72

-------
TABLE  47 .  HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
            AT GROUND SITES ON JULY 19, 1975.


Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
G-l
3.5
1.5
1.0
2.0
1.0
1.0
3.0
*
*
*
*
*
*
4.0
2.5
*
*
*
3-Methylpentane *
n-Hexane
Cyclohexane
3
Total yg/m
G-l Trailer
G-2 Trailer
G-3 Trailer
G-4 Trailer
G-5 Inland
G-6 Inland
1.0
*
21
Site
Site
Site
Site
Site
Site
G-2
4.0
2.5
1.5
2.0
1.0
2.0
4.0
.5
*
*
*
*
*
5.5
3.0
*
*
2.0
1.5
2.0
*
32
6:00-9:00 a.m.
11:00-2:00 p.m.
4:00-7:00 p.m.
10:00-12:00 midni
1:00-4:00 a.m.
2:00-5:00 a.m.
G-3 G-4
4.0 4.0
2.0 .5
1.0 *
2.0 2.0
1.0 *
1.0 .5
2.5 2.0
* .5
* *
* *
* *
* *
* *
3.0 1.0
2.0 .5
* *
* *
1.5 *
* *
* *
* *
20 11



ght


G-5
3.0
3.5
2.0
3.5
2.0
2.5
4.5
*
*
.5
*
*
*
5.0
3.0
*
*
1.5
1.0
*
*
32






G-6
4.5
4.5
1.5
3.5
3.5
2.0
4.0
*
*
2.5
*
*
*
4.0
2.5
*
*
1.0
*
*
*
34






                             73

-------
TABLE  48.  HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
            AT GROUND SITES ON JULY 20, 1975.


Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
G-l
4.5
1.5
*
2.5
3.0
1.5
1.5
*
*
*
*
*
*
2.0
1.5
*
*
1.0
*
*
*
19
G-2
4.0
2.0
1.5
2.5
.5
1.5
3.0
*
*
*
*
*
*
4,0
2.5
*
*
1.5
1.0
1.0
*
25
G-3
3.5
1.0
.5
1.5
*
*
1.0
*
*
*
*
*
*
1.5
1.5
*
*
*
*
*
*
11
6-4
4.0
2.0
1.0
3.0
1.0
2.0
3.5
*
*
1.0
*
*
*
3.5
2.0
*
*
1.0
*
*
*
24
G-5
4.0
2.5
1.0
3.5
2.5
2.5
4.0
*
*
1.0
*
*
*
4.0
2.5
*
*
1.0
2.5
*
*
31

G-l Trailer Site
G-2 Trailer Site
G-3 Trailer Site
G-4 Inland Site
G-5 Inland Site
6
11
5
1
6
:00-9:00 a.m.
:00-2:00 p.m.
:00-8:00 p.m.
:00-4:00 a.m.
:00-9:00 a.m.















                           74

-------
         TABLE 49 .   HYDROCARBON CONCENTRATIONS IN SAMPLES  COLLECTED
                     AT GROUND SITES ON JULY 21, 1975.

Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
6-1
3.0
1.0
*
2.5
*
1.0
2.0
*
*
*
*
*
*
2.0
1.5
*
*
*
*
*
*
13
- - i i
G-2
3.5
2.5
2.0
4.0
1.0
3.0
5.0
*
*
*
*
*
*
5.5
3.5
*
*
1.0
*
*
*
31
•- - i » , , , ,. , ,.
G-3
.6.0
1.5
*
3.0
*
*
5.5
1.0
*
*
*
*
*
6.0
3.0
*
*
2.0
.5
*
*
29
-•—'—- 	 -• • . - -.. 	 _.._.-
6-4
4.5
1.5
2.0
3.0
*
2.0
4.0
*
*
*
*
*
*
4.0
2.5
*
*
*
*
*
*
24
G-l     Trailer Site    6:00-8:00 a.m.
G-2     Trailer Site   11:00-2:00 p.m.
G-3     Trailer Site    5:00-8:00 p.m.
G-4     Inland Site     2:00-5:00 p.m.
                                      75

-------
         TABLE  50 .  HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
                     AT GROUND SITES ON JULY 22, 1975.


Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
Total yg/m
G-l
5.5
5.0
3.0
5.5
1.5
4.5
8.5
*
*
1.0
*
*
*
10.0
6.5
.5
*
1.5
2.5
*
*
56
G-2
4.5
3.0
1.5
4.0
2.0
2.0
5.5
*
*
*
*
*
*
9.0
5.0
*
*
3.0
3.0
2.5
*
45
G-3
3.0
5.0
7.5
5.0
2.5
3.5
7.0


1.0
*
*
*
7.0
4.5
*
*
*
1.0
*
*
48
G-4
4.5
2.0
1.0
3.0
1.0
1.5
3.0


*
*
*
*
3.0
1.5
*
*
1.0
*
*
*
22

G-l    Trailer Site    6:00-9:00 a.m.
G-2    Trailer Site    5:00-8:00 p.m.
G-3    Inland Site     1:00-4:00 a.m.
G-4    Inland Site     6:00-9:00 a.m.
                                        76

-------
TABLE  51  .  HYDROCARBON  CONCENTRATIONS  IN SAMPLES COLLECTED
            AT GROUND SITES  ON  JULY  23,  1975.

G-l
Ethane 5.5
Ethyl ene 4.0
Acetylene 1.5
Propane 6.0
Propene 2.5
i-Butane 3.0
n-Butane 7.0
neo-Pentane *
1-Butene *
i-Butene *
t-2-Butene *
Propyne *
c-2-Butene *
i-Pentane 9.0
n-Pentane 5.0
Cyclopentane *
1-Pentene *
i-Hexane 3.0
3-Methylpentane 3.0
n-Hexane 2.5
Cyclohexane *
3
Total yg/m 52
G-l Trailer Site
6-2 Trailer Site
G-3 Trailer Site
G-4 Inland Site
G-5 Inland Site
G-2
5.0
2.5
1.5
3.5
.5
2.5
6.5
1.0
*
*
*
*
*
7.5
4.0
*
*
2.5
2.0
*
*
39
6:00-9:00 a.m.
11:00-2:00 p.m.
5:00-8:00 p.m.
1:00-4:00 a.m.
6:00-9:00 a.m.
G-3
7.5

2.0
5.5
1.0
*
6.5
1.0
*
*
*
*
*
6.5
3.5
*
*
2.0
*
*
*
36
. 	 	 - -




G-4
5.0
5.0
*
6.0
3.5
*
5.0
2.0
*
*
1.0
*
*
4.0
4.5
1.0
*
1.5
*
*
*
39





G-5
4.5
3.0
1.5
3.5
1.0
2.0
4.0
*
*
*
*
*
*
5.0
4.0
*
*
2.0
6.0
*
*
37





                                 77

-------
TABLE  52.  HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
            AT GROUND SITES ON JULY 24, 1975.


Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total pg/m
G-l
4.0
4.0
1.0
3.0
2.5
1.5
3.5
*
*
*
*
*
*
2.5
2.0
*
*
*
*
.5
*
25
G-2 G-3
5.5 5.0

1.5 .5
3.0 2.0
1.0 *
2.0 .5
4.0 1.5
* *
* *
* .5
* *
* *
* *
4.5 1.5
2.5 1.5
* *
* *
2.5 *
1.5 1.5
1.5 *
* *
30 15
G-4
5.5
1.5
1.0
3.0
*
1.0
2.0
*
*
*
*
*
*
2.0
1.0
*
*
*

*
*
17

G-l Trailer Site
G-2 Trailer Site
G-3 Trailer Site
G-4 Inland Site
6
11
5
5
:00-9:00 a.m.
:00-2:00 p.m.
:00-8:00 p.m.
:00-8:00 p.m.




                              78

-------
TABLE  53 .  HYDROCARBON CONCENTRATIONS  IN SAMPLES COLLECTED
            AT GROUND SITES ON JULY 25,  1975.


Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
G-l
6.5
5.0
*
4.0
2.5
1.0
2.0
*
*
*
*
*
*
2.0
2.5
*
*
*
*
*
*
3
Total yg/m 26
,..._._.,», _,_.._, . „,-- ,_ I,., n. i- 	 ' "
6-1 Trailer Site
G-2 Trailer Site
G-3 Trailer Site
G-4 Inland Site
G-5 Inland Site
• • 1 • !•
1



G-2
4.5
2.0
1.0
3.0
*
1.0
3.0
*
*
*
*
*
*
3.0
2.0
*
*
1 .5
*
*
*
21
-.-., . i... ... • 	 	 	 	 - 	 • 	 — -
6:00-9:00 a.m.
1:00-2:00 p.m.
5:00-8:00 p.m.
1:00-4:00 a.m.
6:00-9:00 a.m.
G-3
5.0
4.5
1.5
4.0
1.0
2.0
4.0
*
*
1.0
*
*
*
4.0
2.5
*
*
*
*
*
*
30
i - - - —




G-4
4.0
4.0
2.5
3.0
2.0
1.5
2.5
*
*
*
*
*
*
3.0
2.0
*
*
*
*
*
*
25





G-5
4.5
2.0
*
2.5
1.0
1.0
2.0
*
*
*
*
*
*
2.0
1.5
*
*
*
*
*
*
17





                                79

-------
TABLE  54 .  HYDROCARBON CONCENTRATIONS IN SAMPLES  COLLECTED
            AT GROUND SITES ON JULY 26, 1975.


Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
G-l
5.0
2.0
.5
3.5
1.0
1.0
2.0
*
*
*
*
*
*
2.5
1.5
*
*
1.0
.5
*
*
21
G-2
4.0
1.5
*
2.5
*
1.0
2.0
*
*
*
*
*
*
2.5
2.0
*
*
*
*
*
*
16
G-3
5.0
1.5
1.0
3.0
*
1.0
2.5
*
*
*
*
*
*
3.0
2.0
*
*
*
*
*
*
19

G-l Trailer
G-2 Trailer
G-3 Trailer
Site 6
Site 11
Site 5
: 00-9: 00 a.m.
:00-2:00 p.m.
:00-8:00 p.m.



                              80

-------
TABLE  55 .   HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
             AT GROUND SITES ON JULY 27, 1975.

Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
Total yg/m
.y -_|||_||||| 	 _ .- - 	 "• — —
6-1 Trailer Site
G-2 Inland Site
6-3 Inland Site
6-4 Trailer Site
6-1
4.5
4.0
2.5
9.5
2.5
2.5
5.0
*
*
.5
*
*
*
6.0
3.5
1.5
*
*
*
*
*
42
,1, i •• —
6
11
2
5
G-2
4.0
1.5
*
1.5
*
*
1.5
1.0
*
*
*
*
*
1.5
1.0
*
*
*
2.5
*
*
15
i 	 	
:00-9:00 a.m.
:30 a.m.
:00-5:00 p.m.
:00-8:00 p.m.
6-3
4.0
2.0
1.0
3.0
1.5
1.5
3.0
*
*
1.5
*
*
*
3.0
2.0
*
*
*
*
1.0
*
24
-



6-4
4.5
1.5
1.0
2.5
1.0
1.0
2.0
*
*
*
*
*
*
3.0
2.0
*
*
*
*
*
*
19




                                  81

-------
           TABLE  56  .  HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
                       AT GROUND SITES ON JULY  28, 1975.


Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
Total yg/m
G-l
4.0
4.0
3.5
4.0
3.5
1.5
3.0
*
*
1.5
*
*
*
3.5
3.5
*
*
*
.5
1.0
*
34
G-2
4.5
1.5
3.0
2.0
1.0
1.5
3.0
*
*
.5
*
*
*
3.0
1.5
*
*
1.0
1.5
*
*
24
G-3
5.5
2.0
1.5
3.5
*
*
4.0
*
*
1.0
*
*
*
3.5
2.0
*
*
1.0
*
*
*
24
G-4
8.0
3.5
3.5
7.5
1.0
*
12.5
*
*
1.0
*
*
*
11.0
5.0
*
*
3.0
1.5
*
*
58
G-5
7.0
1.5
2.0
5.5
*
3.0
6.0
*
*
1.0
*
*
*
5.0
2.5
*
*
1.5
1.0
*
1.0
37

G-l    Inland Site
G-2    Inland Site
G-3    Trailer Site
1:00-4:00 a.m.
6:00-9:00 a.m.
6:00-9:00-a.m.
G-4    Trailer Site  12:00-3:00 p.m.
G-5    Trailer Site   5:00-8:00 p.m.
                                     82

-------
         TABLE  57 .  HYDROCARBON  CONCENTRATIONS  IN SAMPLES COLLECTED
                     AT  GROUND  SITES  ON  JULY  29,  1975.


Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
6-1
6.0
5.5
3.5
10.0
2.0
5.5
12.0
.5
*
.5
*
*
*
13.0
7.5
*
*
4.5
2.5
*
*
G-2
4.0
1.5
1.5
3.0
*
1.0
3.0
*
*
.5
*
*
*
3.0
1.5
*
*
1.0
1.5
*
*
Total  yg/nf
73
22
 G-l    Trailer Site

 G-2    Trailer Site
    6:00-9:00 a.m.

   12:00-3:00 p.m.
                                      83

-------
TABLE  58 .   HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
            AT GROUND SITES ON JULY 30,  1975.

Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
G-l
5.5
6.0
1.0
4.5
2.0
2.0
4.5
*
*
2.0
*
*
*
4.5
3.5
*
*
1.5
1.0
2.0
*
40
G-2
5.0
3.0
2.0
4.0
1.5
2.0
4.5
*
*
.5
*
*
*
5.0
3.5
*
*
*
*
*
*
31
G-3
6.5
9.5
6.5
13.0
4.0
9.0
19.0
*
1.5
2.0
2.0
*
*
21.0
11.0
1.5
*
6.5
3.5
*
*
117
G-4
5.0
6.5
2.0
4.5
1.5
2.5
6.0
*
*
1.0
*
*
*
6.5
4.0
*
*
1.5
*
2.0
*
43
G-5
4.0
3.0
1.5
3.0
1.0
3.0
3.5
*
*
.5
*
*
*
4.5
2.5
*
*
*
*
*
*
27
G-6
4.0
4.0
1.5
3.0
2.0
2.0
7.5
*
*
*
*
*
*
5.0
2.0
*
*
1.0
*
2.0
*
34

G-l Inland Site
G-2 Inland Site
G-3 Trailer Site
G-4 Trailer Site
G-5 Trailer Site
G-6 Inland Site
1
6
8
12
5
5
:00-4:00 a.m.
:00-9:00 a.m.
:00-10:00 a.m.
:00-2:00 p.m.
:00-7:00 p.m.
:00-8:00 p.m.
























                          84

-------
TABLE  59.  HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
            AT GROUND SITES ON JULY 31, 1975      LULLECTED

Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
G-l
/.O
8.0
6.5
8.0
3.0
7.5
16.0
*
*
*
*
*
*
19.0
9.0
1.0
*
5.0
2.5
*
*
93
G-2
8.0
4.0
4.5
7.5
1.0
7.0
13.5
*
*
*
*
*
*
13.0
7.0
*
*
.5
3.5
2.5
*
72
— i .... I, i .__.„,
G-3
4.5
5.0
2.5
5.0
3.5
3.0
5.5
*
*
*
*
*
*
6.5
3.5
*
*
1.5
4.0
1.5
*
46
• 	 — 	
G-4
6 0
V • \J
7.0
* • ^y
5.0
5.5
3.0
7.5
14.5
*
*
*
*
*
*
17.0
8.0
1.0
*
5.0
2.5
4.0
.5
87

G-l Trailer Site
G-2 Trailer Site
G-3 Inland Site
G-4 Inland Site
6
n
1
6
:00-9:00 a.m.
:30-2:30 p.m.
:00-4:00 a.m.
:00-9:00 a.m.








                           85

-------
TABLE  60.   HYDROCARBON CONCENTRATIONS  IN  SAMPLES  COLLECTED
            AT GROUND SITES ON AUGUST 1  AND  2,  1975.



Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total ug/m
August
G-l
5.5
3.0
2.5
5.5
1.0
3.0
7.5
*
*
*
*
*
*
8.5
4.5
*
*
3.0
2.0
2.5
*
49
1
G-2
5.5
3.0
2.0
4.5
1.5
3.0
6.5
*
*
1.0
*
*
*
5.5
3.5
*
*
3.5
1.5
*
41

G-l
4.5
4.5
3.5
9.5
2.0
5.5
11.5
*
*
*
*
*
*
12.5
7.0
*
*
3.5
2.0
2.0
.5
69
August
G-2
6.0
5.0
3.0
4.5
1.5
4.0
10.0
*
.5
1.0
*
*
*
13.5
8.5
4.0
*
6.5
4.5
5.0
*
78
2
G-3
6.5
4.5
4.5
5.5
1.0
4.0
11.5
*
*
1.5
*
*
*
14.0
7.5
1.0
*
5.5
3.5
vy • %*
3.0
*
73

G-4
6.0
5.0
3.0
6.0
3.0
3.5
8.5
2.0
*
*
*
*
*
8.5
4.5
t^ 9 W
1.0
1 • w
*
2.0
7 0
/ • \j
2.0
*
62

August 1
G-l Trailer
G-2 Inland
August 2
G-l Trailer
G-2 Trailer
G-3 Trailer
G-4 Trailer

Site 3:30-6
Site 4:00-7

Site 6:00-9
Site 11:00-2
Site 5:00-8
Site 6:00-9

:30 p.m.
:00 p.m.

:00 a.m.
:00 p.m.
:00 p.m.
:00 a.m.
































                         86

-------
TABLE  61 .  HYDROCARBON  CONCENTRATIONS  IN SAMPLES COLLECTED
            AT GROUND  SITES ON AUGUST 3, 1975.


Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
Total yg/m
.•^^.^^^H m ^P» • 	 •!• w^^^-^- ""
	 " 	 	 —
G-l Trailer
G-2 Trailer
G-3 Trailer
G-4 Trailer
G-l
6.5
7.5
5.5
9.5
3.0
5.5
15.5
*
1.0
1.0
*
*
*
17.0
9.5
*
*
5.0
*
.*
*
87
	 _ r~ ~ ' 	
Site
Site
Site 1
Site
G-5 Inland Site
G-2
6.5
5.0
3.5
15.0
2.5
5.5
11.5
*
1.0
2.0
*
*
*
14.0
8.0
*
*
*
*
*
*
75
	 • •• -
	 , • "•
1 :00-4:00 a.m.
6:00-9:00 a.m.
1:00-2:00 p.m.
2:00-5:00 p.m.
2:00-5:00 p.m.
G-3
6.5
5.5
4.5
6.5
1.0
5.0
13.5
*
*
*
*
*
*
15.5
9.5
*
*
6.5
5.0
*
*
79
L I -T
	 -: ...... r -




G-4
7.0
6.0
4.0
5.5
1.0
3.0
7.5
*
*
1.5
*
*
*
11.0
6.5
*
*
5.0
3.0
4.5
*
66
__
.




G-5
6.0
3.5
2.0
4.5
1.5
2.5
5.0
*
*
2.0
*
*
*
4.5
2.5
*
*
1.0
1JH»
.5
*
37
	 	 	 •""- 	 • 	 •-
	 M - | IB - 	 	 11





                            87

-------
TABLE  62 .   HYDROCARBON CONCENTRATIONS IN  SAMPLES  COLLECTED
            AT GROUND SITES ON AUGUST 4,  1975.


Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
G-l
6.0
12.5
11.0
7.0
5.0
3.5
7.5
*
1.5
*
2.5
*
*
3.0
8.5
*
*
*
*
*
*
68
6-2
5.0
3.5
2.0
4.0
1.5
2.0
4.5
*
*
2.0
*
*
*
4.5
2.5
*
*
1.0
.5
*
*
33
G-3
3.5
2.5
2.5
3.5
1.0
9.0
3.5
*
*
*
1.0
*
*
4.5
3.0
*
*
*
1.5
*
*
36
G-4
3.5
2.0
*
3.0
*
1.0
2.0
*
*
*
*
*
*
2.5
2.0
*
*
*
1.0
*
*
17
G-5
3.5
1.5
*
2.0
.5
.5
1.0
*
*
1.5
*
*
*
2.0
1.0
*
*
*
*
*
*
14

G-l Inland Site
6-2 Inland Site
G-3 Trailer Site
G-4 Trailer Site
G-5 Trailer Site
1
6
6
11
5
:00-4:00 a.m.
:00-9:00 a.m.
:00-9:00 a.m.
:00-2:00 p.m.
:00-8:00 p.m.















                          88

-------
TABLE  63.
        T
GROUND SITES
                                        N  SAMPLES
                               AUGUST 5, 1975.
          6-1
      G-2
                                G-3
Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
4.0
3.5
3.0
4.0
2.5
1.5
3.0
*
*
*
1.0
*
*
3.5
4.0
*
*
*
1.0
*
*
31
3.0
1.5
1.5
2.5
.5
1.5
3.0
*
*
*
*
*
*
4.0
5.5
*
*
*
*
*
*
23
4.0
1.5
1.0
5.0
1.0
2.0
4.0
*
*
1 5
I . sj
*
*
*
5.5
3.0
*
*
2.0
1.0
1.5
*
33
5.0
3.5
2.0
4.5
1.0
3.5
9.0
*
*
*
*
*
*
8.5
5.5
*
*
*
2.0
1.5
2.0
48
vj — u
5.0
1.5
4.0
1.5
2.0
4.5
i?
•jf
•k
*
*
5.5
4.0
*
*
*
2 0
b » V
*
*
30

G-l Inland Site
G-2 Inland Site
G-3 Trailer Site
G-4 Trailer Site
G-5 Trailer Site
1
6
6
11
5
:00-4:00 a.m.
:00-9:00 a.m.
:00-9:00 a.m.
:00-2:00 p.m.
:00-8:00 p.m.















                          89

-------
TABLE  64.  HYDROCARBON CONCENTRATIONS  IN  SAMPLES  COLLECTED
            AT GROUND SITES ON AUGUST 6, 1975.

Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
G-1
4.5
2.0
1.0
5.0
1.0
2.0
4.0
*
*
*
1.5
*
*
4.5
3.0
*
*
1.5
.5
1.0
*
32
G-2
5.0
4.0
3.5
5.5
*
3.5
9.0
*
*
1.5
*
*
*
10.0
5.5
*
*
3.5
1.5
2.5
*
55
G-3
5.0
5.5
3.5
5.5
2.5
4.0
10.0
*
*
1.0
*
*
*
10.5
6.0
*
*
3.0
*
*
*
57
G-4
3.0
1.5
1.0
2.5
.5
1.5
4.0
*
*
2.0
*
*
*
4.5
2.5
*
*
1.5
.5
*
*
25

G-1 Trailer Site
G-2 Trailer Site
G-3 Trailer Site
G-4 Rural Site
6:00-9
11:00-2
5:00-8
2:00-5
:00 a.m.
:00 p.m.
:00 p.m.
:00 p.m.








                           90

-------
TABLE  65.  HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
            AT GROUND SITES ON AUGUST 7, 1975.


Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
Total yg/m
6-1
4.0
3.0
3.0
3.0
1.5
1.5
3.0
*
*
*
*
*
*
2.5
2.0
*
*
* *
*
*
*
24
G-2
3.5
1.5
*
2.0
*
1.0
1.5
*
*
1.5
*
*
*
2.0
1.0
*
*
*
1.0
*
*
15
G-3
4.0
2.0
*
3.5
*
1.0
2.0
*
*
*
*
*
*
2.0
1.5
*
*
*
1.5
*
*
18
6-4
5.0
3.5
1.5
3.5
1.5
1.5
3.5
*
*
2.5
*
*
*
4.5
2.5
*
*
1.5
.5
1.0
*
33

6-1 Inland Site
G-2 Inland Site
G-3 Trailer Site
6-4 Trailer Site
1
6
6
11
:00-4:00 a.m.
:00-9:00 a.m.
:00-9:00 a.m.
:00-2:00 p.m.








                           91

-------
TABLE  66.   HYDROCARBON CONCENTRATIONS IN SAMPLES  COLLECTED
            AT GROUND SITES ON AUGUST 8,  1975.


Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
G-l
5.0
2.5
2.0
5.0
1.5
3.5
*
*
*
2.0
*
*
*
4.0
2.5
*
*
1.5
1.0
1.5
*
32
G-2
4.5
4.5
2.0
4.5
1.5
2.0
3.5
*
*
*
*
*
*
5.0
3.5
1.0
*
1.0
1.5
*
*
35
G-3
5.0
3.5
2.0
4.5
1.5
2.0
4.0
*
*
1.0
*
*
*
5.5
5.0
*
*
*
*
*
*
34
6-4
5.5
3.0
2.0
4.5
1.5
2.0
4.0
*
*
*
1.5
*
*
4.5
2.5
*
*
1.5
*
*
*
33

6-1 Trailer Site
6-2 Trailer Site
G-3 Trailer Site
6-4 Inland Site
6
11
5
2
:00-9:00 a.m.
:00-2:00 p.m.
:00-8:00 p.m.
:00-5:00 p.m.








                          92

-------
TABLE  67.  HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
            AT GROUND SITES ON AUGUST 9, 1975.


Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total pg/m
6-1
8.0
6.5
4.5
7.5
2.5
2.5
6.5
*
1.0
2.0
*
*
1.0
7.0
5.0
*
*
2.5
*
*
*
57
G-2
4.5
4.0
3.0
5.0
2.0
2.5
5.5
*
1.0
1.0
*
*
*
6.0
4.0
*
*
*
*
*
*
39
G-3
6.0
5.5
2.5
9.0
2.5
2.5
6.5
*
1.0
2.0
*
*
.5
8.0
4.5
*
*
2.5
*
*
*
53
G-4
5.5
7.0
3.0
5.0
1.5
3.5
8.0
*
1.0
*
*
*
*
10.0
6.5
*
*
2.5
2.0
4.0
*
60
G-5
6.0
4.5
2.5
4.5
1.0
2.5
6.5
*
1.0
1.0
*
*
*
8.0
5.0
*
*
*
*
*
*
43

6-1 Inland Site
G-2 Inland Site
G-3 Trailer Site
G-4 Trailer Site
G-5 Trailer Site
1
6
6
11
5
:00-4:00 a.m.
:00-9:00 a.m.
:00-9:00 a.m.
: 00-2: 00 p.m.
:00-8:00 p.m.















                           93

-------
TABLE  68.  HYDROCARBON CONCENTRATIONS  IN SAMPLES COLLECTED
            AT GROUND SITES  ON AUGUST 10 AND 11, 1975.



Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
Total yg/m
August 1
G-l
8.0
8.0
3.0
7.0
2.5
3.5
7.5
*
*
3.0
*
*
*
10.0
6.0
*
*
3.5
1.5
*
*
0
6-2
7.5
3.5
3.0
6.0
1.0
3.0
6.5
*
*
2.0
*
*
*
8.0
4.5
*
*
2.5
*
*
*
64 48

G-l
10.0
9.0
7.0
25.5
4.5
8.0
18.5
*
2.5
1.0
4.5
*
*
22.0
12.5
1.5
*
8.5
5.5
7.5
*
148
August 11
6-2
7.0
6.0
6.0
8.0
1.5
6.0
15.5
*
*
*
*
*
*
18.5
10.0
1.0
*
5.5
4.0
*
*
89

6-3
9.5
4.0
3.5
7.5
1.0
3.0
7.0
*
*
*
*
*
*
8.5
5.0
*
*
3.0
2.0
2.5
*
57

August 10
G-l Trailer
6-2 Trailer
August 11
G-l Trailer
6-2 Trailer
6-3 Trailer

Site 6:00-9
Site 11:00-2

Site 6:00-9
Site 11:00-2
Site 5:00-8

:00 a.m.
:00 p.m.

:00 a.m.
:00 p.m.
:00 p.m.





















                          94

-------
TABLE  69.  HYDROCARBON CONCENTRATIONS  IN  SAMPLES COLLECTED
            AT GROUND SITES ON AUGUST  12 AND  13, 1975.



Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total pg/m

G-l
5.0
6.5
4.5
10.5
3.0
5.0
11.5
*
1.0
*
2.5
*
*
14.5
9.0
1.0
*
4.0
3.0
4.5
*
86
August 12
G-2
7.0
3.5
2.5
5.5
1.0
3.0
6.0
*
*
*
*
*
*
7.0
4.5
*
*
2.5
1.5
2.5
*
47

G-3
9.0
5.5
5.0
8.0
1.5
4.0
9.0
*
*
*
1.5
*
*
11.0
6.0
*
*
4.5
2.5
3.5
*
71

G-l
4.5
6.5
4.5
11.5
2.5
6.5
13.5
*
1.0
1.0
1.5
*
*
16.5
9.5
*
*
4.5
3.0
*
*
87
August 13
G-2
5.0
3.0
3.0
4.0
1.0
2.5
5.5
*
*
1.0
*
*
*
7.5
4.0
*
*
3.0
1.5
4.0
*
45

G-3
5.0
3.0
1.5
4.5
1.5
2.0
4.5
*
*
*
*
*
*
5.5
4.0
*
*
2.0
.5
*
*
34

August 12
G-l Trailer
G-2 Trailer
G-3 Trailer
August 13
G-l Trailer
G-2 Trailer
G-3 Trailer

Site 6
Site 11
Site 5

Site 6
Site 2
Site 5

:00-9:00 a.m.
:00-2:00 p.m.
:00-8:00 p.m.

:00-9:00 a.m.
:30 p.m.
:00-8:00 p.m.
































                          95

-------
TABLE  70.   HYDROCARBON CONCENTRATIONS  IN  SAMPLES  COLLECTED
            AT GROUND SITES ON AUGUST 14,  1975.


Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
G-l
7.0
4.5
1.5
7.0
1.0
3.0
6.0
*
*
1.5
*
*
*
7.0
4.0
*
*
1.5
1.0
*
*
45
G-2
7.5
2.5
1.5
5.0
1.0
2.5
5.0
*
*
*
1.0
*
*
6.0
3.0
*
*
2.0
1.0
1.5
*
40
G-3
7.0
3.5
2.5
6.5
1.5
3.5
7.5
*
*
*
*
*
*
8.0
4.0
*
*
2.0
1.0
*
*
47
6-4
7.0
3.0
2.0
6.0
3.0
2.5
5.5
*
2.5
*
1.0
*
*
6.0
3.5
*
*
*
2.5
*
*
45

G-l Trailer
G-2 Trailer
G-3 Trailer
6-4 Trailer
Site 6
Site 7
Site 11
Site 5
:00-9:00 a.m.
:00-9:00 a.m.
:00-2:00 p.m.
:00-8:00 p.m.








                          96

-------
          TABLE  71 .   HYDROCARBON CONCENTRATIONS IN SAMPLES  COLLECTED
                      AT GROUND SITES ON AUGUST 15 AND 16,  1975.



Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m

6-1
4.5
2.5
2.0
5.5
1.0
2.5
6.0
*
*
*
*
*
*
7.5
4.5
*
*
*

*
*
36
August 15
G-2
3.5
2.5
1.5
3.5
1.0
2.0
4.5
*
*
.5
*
*
*
5.5
3.5
*
*
2.0
1.5
1.5
*
33
August 16
6-3
6.5
2.0
1.0
5.5
*
1.5
2.5
*
*
*
1.5
*
*
3.5
2.0
*
*
1.5
*
*
*
28
G-l
5.5
9.5
3.0
13.0
2.5
6.0
12.0
*
1.0
1.0
*
*
*
15.5
8.0
*
*
4.5
*
*
*
82
G-2
4.5
4.5
1.0
4.5
*
2.0
3.5
*
*
*
*
*
*
4.5
2.5
*
*
*
*
*
**
27

August 15
 G-l     Trailer Site
 G-2     Trailer Site
 6-3     Trailer Site
August 16
 G-l     Trailer Site
 G-2
Trailer Site
 8:30-10:30 a.m.
11:00-2:00 p.m.
 5:00-8:00 p.m.

 6:00-9:00 a.m.
 5:00-8:00 p.m.
                                    97

-------
TABLE  72.  HYDROCARBON CONCENTRATIONS  IN SAMPLES COLLECTED
            AT GROUND SITES ON  AUGUST 17 AND  18, 1975.



Ethane
Ethylene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
]-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
3
Total yg/m
August 17
G-l G-2
6.5 4.5
2.5 2.5
1.0 1.0
6.0 4.0
* 1.0
2.5 1.5
3.0 3.0
* *
* *
* *
* *
* *
* *
4.5 4.0
2.5 3.0
* *
* *
* *
* *
* *
* *
29 25

G-l
12.5
9.5
5.0
10.5
1.5
6.0
11.5
*
*
3.5
*
*
*
12.0
6.5
*
*
3.5
1.0
*
*
83
August 18
G-2
4.0
3.5
4.0
6.5
1.0
5.5
9.5
*
*
*
*
*
*
10.5
6.0
1.0
*
2.0
2.0
2.5
*
58

G-3
10.0
12.0
3.0
8.0
4.5
3.5
7.0
*
*
*
3.5
*
*
8.0
4.5
*
*
2.5
1.5
*
*
68

August 17
G-l Trailer
G-2 Trailer
August 18
G-l Trailer
G-2 Trailer
G-3 Trailer

Site 6:00-9:00 a.m.
Site 11 :00-2:00 p.m.

Site 6:00-9:00 a.m.
Site 11 :00-2:00 p.m.
Site 5:00-8:00 p.m.





















                          98

-------
TABLE  73.  HYDROCARBON CONCENTRATIONS IN SAMPLES COLLECTED
            AT GROUND SITES ON AUGUST 19 AND 20, 1975.


Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
neo-Pentane
1-Butene
i-Butene
t-2-Butene
Propyne
c-2-Butene
i-Pentane
n-Pentane
Cyclopentane
1-Pentene
i-Hexane
3-Methylpentane
n-Hexane
Cyclohexane
Total yg/m
August 19
G-l G-2
6.0 5.0
5.0 3.5
2.0 1.5
5.5 4.5
* 1.0
1.5 2.0
2.0 3.5
* *
* *
* *
* *
* *
* *
5.0 4.0
3.0 2.5
* *
* *
* 1.5
* *
* *
* *
30 29

G-3
5.5
6.5
1.5
5.0
3.0
2.0
5.5
*
*
*
*
*
*
4.5
3.5
*
*
*
*
*
*
37
August 20
G-l
6.0
5.0
3.5
6.5
1.5
4.0
9.0
*
1.0
*
2.0
*
6.5
12.0
8.0
*
*
.5
*
*
*
66

August 19
G-l Trailer
6-2 Trailer
G-3 Trailer
August 20
G-l Trailer

.Site 6:00-9:00 a.m.
Site 11 :00-2:00 p.m.
Site 5:00-8:00 p.m.

Site 6:00-9:00 a.m.












                           99

-------
AIRCRAFT FLIGHT DATA
     Three basic types of information are contained in this section.
     1)  A map for each flight showing the route followed, ozone
         concentrations (ppb) at selected points along the route,
         vertical sounding locations, and bag and can sample
         collection points.
     2)  Plot of ozone concentration and temperature vs.  altitude
         for all aircraft vertical  soundings.
     3)  Composite plots showing changes in altitude, CN  counts, visual
         range, relative humidity and ozone concentration vs.  time (and
         distance) along the flight path.
     The data is arranged by flight with flights numbered consecutively
beginning on July 15.  All times reported refer to Eastern Daylight Time.
                                   100

-------
    KINGSTON O
                                             L.7~.
                                                      MASSACHUSET TS
CONNECTICUT
                                                 o '
PUTNAM O  •'
 NEW
 JERSEY
NEW YORK CITY,
                                               ATLANTIC

                                                    OCEAN
                                                               Scale;  l' = 21 mi.
   Figure 4.  Flight #1 on July 15,  1975, with ozone concentrations  (ppb) marked
             at points along the route.

              TIME:  3:50 to 5:06  PM
               Leg
ab:
b:
be:
cd:
de:
ea:
3:50 -
4:05 -
4:21 -
4:41 -
4:48 -
4:55 -
4:04
4:20
4:40
4:47
4:54
5:06
      climb to 6500'  MSL
      spiral descent  to 500'
      at  1000'
      at  1000'
      slant ascent to 3000'
- 5:06 slant descent to landing
              WIND:  210° at 15 mph (Groton)

              WEATHER:   Sunny and hot
                                  101

-------
             8
 ALTITUDE

(xlO3 ftMSL)
             3


             2
                                                  T
                  T
                                                                    T
                          20
                                                   i—|—|—i—i—i—i  i  r  i  I  I   i  i
                                                    50   55   60  65   70   75   80

                                                            TEMP  (°F)
                                                             \
30
  40
ppb  0,
                                                              »

                                                               \
                          \
                           \
                                                                       \
                                   \
                                                                              *
                                                                              \
                                        6


                                        5


                                        4


                                        3


                                        2
                 Figure 5.  Vertical  ozone and temperature profiles over Hampton
                           (point b) at  4:00 pm on July 15,  1975.
                                          102

-------
                Figure 6.  Plot of aircraft data recorded during flight #1 on July  15, 1975.
o
co
   OZONE


    (ppb)
40




30



20




 10



 0




 8
  ALTITUDE


  (xlO3 ftMSL)   4



              2
                                1550     1610     1630     1650


                                                 FLIGHT   TIME
                                                       1710
                                                                                                 90
                                                                                                 80
70
                                                                                                 60
     RELATIVE


     HUMIDITY

-------
                                                     MASSACHUSET TS
    KINGSTON O
CONNECTICUT
PUTNAM O
 NEW

 YORK
               (T
 NEW
 JERSEY
NEW YORK  CITY/
                                              ATLANTIC

                                                   OCEAN
                                                              Scale;  l" = 2lmi.
   Figure 7.  Flight #2 on July 18,  1975, with ozone concentrations (ppb) marked
            at points along the route.

              TIME:  1:25 to 2:32 PM

               Leg   ab:  1:25-1:56 climb to 7000' MSL
                     b:  1:57-2-15 spiral descent to 500'
                    ba:  2:16 - 2:32 at ^  1500'

              WIND:  230° at 15 mph (Groton)

              WEATHER: Sunny and warm with haze
                                 104

-------
            8


            7
ALTITUDE

|xl03 ftMSL)
            3


            2



            I


            0
                                                  T
                        T
                          T
                          50
70
                                                   i  i  i   i  i—i—i—i—i—\—i—i—i—i
                                                    55   60  65   70   75   80  85

                                                            TEMP  (°F)
  90
ppb 03
110
130
                                                  8
                                                  6


                                                  5
                                                  3


                                                  2
               Figure 8.   Vertical ozone and temperature profiles  over mouth of
                          Connecticut River (point b) at 2:00 pm on  July  18, 1975.
                                         105

-------
                     Figure  9.  Plot of aircraft data recorded during flight #2 on  July 18, 1975.
             200 -
     COND.
    NUCLEI
  (xlO3 part/ml)
o
CTl
    OZONE
     (ppb)
                                          1350     I4IO      I43O
                                                   FLIGHT  TIME
  VISUAL
DISTANCE
   (km)
RELATIVE
HUMIDITY

-------
                                                       MASSACHUSET TS
                             CONNECTICUT
 NEW

 JERSEY
NEW YORK
                                          RIVERHEADO'
                         LONG   ISLAND
                                               ATLANTIC

                                                     OCEAN
                                                                Scale:  I  = 21 mi.
   Figure 10.  Flight #3 on July 18, 1975, with ozone concentrations  (ppb)  marked
             at points along the route.

               TIME:  3:50 to 5:08 PM

                Leg   ab:  3:50 - 4:05 at ^2500' MSL
                     be:  4:06 - 4:17 at ^2500'
                     cd:  4:18 - 4:20 at ^2500'
                      d:  4:20 - 4:28 spiral  to 5000'
                     de:  4:29 - 4:43 slant  descent  5000'
                     ea:  4:44 •• 5:08 at ^2500'
to 2500'
              WIND:   230° at  10 mph (Groton)

              WEATHER:  Sunny and hot
                                  107

-------
             8
 ALTITUDE

(XIO3 ftMSL)
             3


             2
                     80
90
                                                   i—i—i
                          	,	-,	T—-r-


                        60   65   70  75   80  85

                            TEMP  (°F)
100         110
   ppb  0,
120
130
                                                       6


                                                       5


                                                       4


                                                       3


                                                       2
                 Figure 11.  Vertical  ozone and temperature profiles  near Hartford
                            (point d)  at 4:25 pm on July 18,  1975.
                                          108

-------
                  Figure 12.   Plot of aircraft data recorded during flight #3 on  July 18, 1975.
   COND.
  NUCLEI
(xlO3 part/ml)
  OZONE
   (ppb)
  ALTITUDE
 (xlO3  ftMSL)
                               1550     1610      1630      1650
                                                FLIGHT  TIME
1710
                                    VISUAL
                                   DISTANCE
                             80     (km)
                                  RELATIVE
                                  HUMIDITY

-------
KINGSTON O \  64
 NEW

 YORK
                         64
                              CONNECTICUT
                                                   o
                                                        MASSACHUSETTS
                                      PUTNAM O •'
                      o,
               A-4
               A-5
              •J (Spiral)

                V
                68
                              62
                         HARTFORD
      68
           69
                68
                -ETOWN
72

O
                                      108
 NEW
 JERSEY
NEW YORK CITY
                                         A-3
                                         78
                                          68
              62
                                             76
                                                  98
                                               A-2
                                £x
                                                            60  H^GROTON


                                                              (Spiral) A'.


                                                                       44
                                                                S)
                                                                         44
                          LONG   ISLAND
                                            56-
                                                                42
                                                                   48
                                                                     48
                                                             52
                           55
                                                   56
                                               56
                                                 ATLANTIC

                                                       OCEAN
                                                                   Scale;  I = 21 mi.
     Figure 13.  Flight #4 on July 19,  1975, with ozone concentrations (ppb)
               marked at points along the route,

                TIME:  9:35 AM to 1:15 PM

                 Leg   ab:   9:35 - 10:00 climb to 8000' MSL
                       b:   10:01 - 10:22 spiral descent to 1000'
                      be:   10:23 - 10:39 at  1000'
                      cd:   10:40 - 11:15 angle ascent to 5000' and back down to  1000'
                      de:   11:16 - 11:36 at  1000'
                     efg:   11:37 - 12:08 at  ^2000'
                       g:   12:08 - 12:34 spiral to  8000' and  back down to 1500'
                      gh:   12:35 - 12:58 at  ^1800'
                      ha:   12:59 - 1:15 between 1000' and 2000'

                WIND:  240° at 20 mph (Groton)

                WEATHER:   Partly cloudy and warm

                                    110

-------
           8


           7
ALTITUDE

'XIO3 ftMSL)
            3


            2
                                                  I      '      I     '      I      '

                                                  I  I   I  I  I   I  I—I—I—1—I—I—I—I
                                                            TEMP  (°F)
                                                                       8
                                                 Figure 14

                                          Vertical sounding over
                                        Long Island Sound (point b)
                                        at 10:10 am on July 19, 1975,
                                        6


                                        5


                                        4


                                        3


                                        2


                                        I


                                        0
                          40
                      50
  60
ppb  0,
            7


            6
 ALTITUDE
     ftMSL)
            I


            0
       Figure 15

   Vertical sounding
.southeast of Kingston
 (point g) at 12 noon
 on July  19, 1975.
                                                        I      I      I     I      I

                                                   —I—I—I—I—I—I—I—I—I—I—I—I—I
                                                    50  55   60  65  70   75  80
             TEMP  (°F)
              7


              6


              5


              4


              3


              2
                                  J
                                      50
                                  60
                               ppb  03
               70
80
                                          111

-------
                    Figure 16.   Plot of aircraft data recorded during flight #4  on July 19, 1975.
   COND.
  NUCLEI
(*I03 part/ml)
            40

            30

            20

            10

             0
_          100

  OZONE    8°
   (ppb)     60

            40

            20

            8

 ALTITUDE  6
 (xlO3 ftMSL)  4
            2
                    160
                    I20     VISUAL
                         DISTANCE
                    80      (km)
                    40

                    0
                                                                                                90
                    80
                                                                                                70
                                                                                                60
                                                                                                50
                                                                                                     RELATIVE
                                                                                                     HUMIDITY
             IO2O     I04O     1100     1120      1140      1200
                                                FLIGHT  TIME
                                                                   1220
1240
I30O

-------
NEW  HAMPSHIRE
MASSACHU3,
        112
    WORCHESVER O
                 PROVIDENCEO L

                  RHODE \ -» « 64
                  ISLAND
            98
CONNECTICU
                                             WINEYARDis
                              ATLANTIC    OCEAN
 Figure 17.  Flight #5 on July 19, 1975, with ozone concentrations (ppb)
           marked at points along the route.

           TIME:  3:45 to 6:42  PM

            Leg   ab:   3:45 - 4:00 at ^1500' MSL
                 be:   4:01  - 4:21 at ^2000'
                 cd:   4:22-4:50 between 1500' and 2000'
                  d:   4:51  - 5:22 spiral ascent to 7500' and descent to 2000'
                 da:   5:23 - 6:42 varying altitudes between 1000' and 4000'

           WIND:  240° at 15 mph (Groton)

           WEATHER:  Sunny and  hot
                               113

-------
             8


             7
 ALTITUDE

(XIO3 ftMSL)
                     i-—~r
            T—'—r
                    -i	T
                           60
                                                     i—i—i—i—i—i—i—i   i  i  ''  '
                                                    55   60   65  70   75   80  85

                                                            TEMP  (°F)
                   \
70
   80
ppb  0,
                                                            »
                                                            \
                                                               \
                          *

                          \
                                                                   \
                                                                      \
                                                                         b

                                                                         \
                                                                             \
                                        6


                                        5


                                        4


                                        3


                                        2
90
                Figure  18.  Vertical ozone and  temperature profiles northeast of
                           Boston (point d)  at 5:00 pm on July 19, 1975.
                                          114

-------
                  Figure 19.   Plot of aircraft data recorded during flight #5 on July  19, 1975.
   COND.
  NUCLEI
(xlO3 part/ml)
  OZONE
   (ppb)
                             ,20     VISUAL
                                  DISTANCE
                             8°      (km)
             1540      1600     1620     1640      1700     1720
                                                FLIGHT  TIME
1740
1800
1820
1840
                                  RELATIVE
                                  HUMIDITY

-------
                                                      MASSACHUSEJ TS
                             CONNECTICUT
KINGSTON O
NEW

YORK
                           O DANBURY
                                           60-l(Spiral)
NEW
JERSEY
                                         RIVERHEADO
                                               ATLANTIC

                                                    OCEAN
   Figure 20.  Flight #6 on July 20, 1975, with ozone concentrations  (ppb)
             marked at points along the route.

               TIME:   2:35 to 4:32 PM

                Leg   ab:  2:35 - 2:55 at VIOOO1  MSL
                      b:  2:56 - 3:44 spiral ascent to 10000'  and descent to 1000'
                     be:  3:45 - 4:32 at 1000'
                     ca:  4:00-4:32 slant ascent to 5000' and spiral down over Groton

               WIND:   220° at 15 mph (Groton)

               WEATHER:  Sunny, hot and humid
                                  116

-------
            9  -
            8


            7
ALTITUDE

(XIO3 ftMSL)
            3


            2
                                                       T
                                                              I
                       Figure 21
Vertical  sounding near
  New Haven (point
at 3:15 pm on July
20, 1975.
                   o
    ~~i  i  i   i  i—i—i—i—i—i—i
     50  55   60   65   70   75

             TEMP  (°F)
                                                               80  _
                                        8
                                                                \
                                                                 ^

                                                                 \
                                                                  \
                                                      \
                                                          \
                                                                             *
                                        6


                                        5


                                        4


                                        3


                                        2


                                        I


                                        0
                          50
                     60
  70
                                               ppb
            7


            6
 ALTITUDE

(XIO3 ftMSL)
            3



            2


            I
      Figure 22

 Angle ascent across
 Sound (point c to a)
 at 'x4:15 pm on July
 20, 1975.
     55  60   65   70  75   80  85


             TEMP  (°F)
                                                                 \
                                                   \
                                                    \
                                                      \
                                                        \
7


6


5


4


3


2
                                                           \
                                                  _L
                          50
                      60
   70
ppb  03
                                          117

-------
             8
 ALTITUDE

(XIO3 ftMSL)
             3


             2
                          50
60
  70
ppb 03
                                                              T
                                   T
                                                              60  65   70  75   80

                                                             TEMP  (°F)
                              \
                                                                       \
                                                                        \
                                                                          \
                                    \
                                       \
                                                 9


                                                 8
                                        6


                                        5


                                        4


                                        3


                                        2
                                                                               •

                                                                               \    -
                Figure 23.  Vertical  ozone  and temperature profiles  near Groton
                           (point a)' at 4:25 pm on July 20, 1975.
                                          118

-------
                  Figure 24.   Plot of aircraft data recorded during  flight #6 on July 20, 1975.
   COND.
  NUCLEI
(xlO3 part/mi)
  OZONE
 ALTITUDE
 (xlO3  ftMSL)
                      1420     1440     1500     1520      1540
                                               FLIGHT  TIME
1600
1620
1640
                                    VISUAL
                                  DISTANCE
                             80      (km)
                                  RELATIVE
                                  HUMIDITY

-------
    KINGSTON O
I  MASSACHUSETTS
             PUTNAM O  :
CONNECT CUT
 NEW
 JERSEY
NEW YORK  CITY
                                              ATLANTIC
                                                    OCEAN
                                                               Scale;  I = 21 mi.
    Figure 25.  Flight #7 on July 20,  1975, with ozone concentrations (ppb)
              marked at points along the route.
               TIME:  7:30 to 8:30 PM
                 Flight consisted of spiral climb to 9000'  followed by spiral
                descent and landing
               WIND:  220° at 10 mph
               WEATHER:  Partly cloudy and warm
                                  120

-------
            8

            7
 ALTITUDE
(XIO3 ftMSL)
            3

            2

            I

            0
                                                        T
                          30
                                                              T
                              T
                                    T
                                                o
                                                     i  i   i  i  \—i—i—i—i—i—i—i—i
                                                    50   55  60   65   70  75   80

                                                            TEMP  (°F)
40
50
                                               ppb
                                                                \
                                                                  \
                              \
                                \
                                 \
                                   •
                                   \
                                     ^
                                      \
                                        \
                                        /
                Figure  26.   Vertical ozone and temperature profiles south of
                            Groton at 8:15 pm on July 20, 1975.
                                                  8
                                      6

                                      5

                                      4

                                      3

                                      2
                                          121

-------
                     Figure 27.  Plot  of aircraft data recorded during flight #7 on July 20,  1975.
    COND.
   NUCLEI
 UK)3 part/ml)
ro
   OZONE
    (ppb)
                                        I94O     2OOO    2O20
                                                 FLIGHT  TIME
2040
                                    VISUAL
                                   DISTANCE
                              80     (km)
                                   RELATIVE
                                   HUMIDITY

-------
   NEW  HAMPSHIRE
                                              (Spiral }d
                                              f*m^t
   MASSACH'kvE^
            48

        WORCHES^ER O
              51
                                BROCKTONO
                     PROVIDENCEO I.
CONNECTION
                      ISLAND
                                                  MARTHA1^
                                  ATLANTIC    OCEAN
   Figure 28.  Flight #8 on  July 21., 1975, with ozone concentrations (ppb)
             marked at points along the route,

              TIME:  11:00 AM to 2:15 PM

               Leg   ab:   11:00 - 11:30 at ^1500'  MSL
                     b:   11:31 - 11:51 spiral ascent to 6000' and descent to 2000'
                    be:   11:52 - 12:11 at 2000'
                    cd:   12:12 - 12:43 at 2000'
                     d:   12:44 - 1:11 spiral ascent to 6000' and descent to 1500'
                    de:   1:11 - 1:58 at 1500'
                    ea:   1:59 - 2:15 between 1000' and 3000'

              WIND:  230°  at 15 mph (Groton)

              WEATHER:  Sunny and warm

                                  123

-------
 ALTITUDE

(xlO3 ftMSL)

9
8

7
6

5
4

3

2

1
0
i | I | i , , , i 1
( — i — i — i — i — i — i i i i ' ' ' i
Figure 29 55 60 65 70 75 80 _
Vertical sounding near TEMP (°F)
Putnam (point b)
"at 11 :40 am on July 21 ,
1975.
•••
1 \
1? \
0\
o

™*
0
—
c
f /
\
\
\
\
\
\

- -
• 1 1 1 1 1 1 1 1 1 1

9
8

7
6

5
4

3

2

1
0
                          40
                   50
  60
ppb 03
             7


             6
 ALTITUDE

(XlO3 ftMSL)
             2


             I


             0
                                                              l
    Figure  30

Vertical  sounding
    northeast
  jof Boston (point d)
      at  1 :00 pm on July
         21, 1975.
                                                  i   i  i  i   i  i  i  i   i  i  i   r  i  i
                                                        55   60  65   70   75   80
             T^MP  (°F)
                                                               \
                                                                 •*
                                                                 \
                                               \
                                                                    *
                                                                     \
                                                                       «
                                                                       \
                                                       i
                                                       \
7


6


5


4


3


2
                           40
                   50
   60
ppb  03

-------
            4
ALTITUDE

xlO3 ftMSL)
                          50
                                   o
60
                                                        T
                                                              T
                                   T
                                                                  n—i—i—i—i—i—i

                                                    70   72   74  76   78  80  82  _

                                                             TEMP  (°F)
                                                      \
                                                        %

                                                         \
                      \
                        »

                         \
                                                                  \
                                                                     \
                                                                        \
                                                    .0
                                                                           *


                                                                        /
                                                                           \
70
80
90
                                               ppb
                Figure  31.   Vertical ozone and temperature profiles  on  descent
                            into Trumbull Airport (point a) at 2:10  pm  on July
                            21, 1975.
                                          125

-------
                      Figure  32.  Plot of aircraft data recorded  during flight #8  on July 21, 1975.
    COND.
   NUCLEI
 (x!03 part/ml)
en
           40

           30

           20

            10

            0

           100

  OZONE   80
   (Ppb)     60

           40

           20

            8

 ALTITUDE   6
(xlO3  ftMSL) , 4
            2

            O
               II2O
II4O
                               I2OO
1220
I24O
I3OO
I32O
I34O
I4OO
                                                                          160
                                                                          I20    VISUAL
                                                                               DISTANCE
                                                                          80      (km)

                                                                          40
                                                                          90

                                                                          80

                                                                          70

                                                                          60

                                                                          50
I42O
                                                                                                       RELATIVE
                                                                                                       HUMIDITY
                                                  FLIGHT   TIME

-------
Figure 33.   Flight #9 on  July 21,  1975,  with  ozone concentrations (ppb)
            marked at points  along  the route.
TIME:
Leg








3:
ab
b
be
c
cd
d
de
ef
fa
45
•
"
;
:
:
;
:
;
;
to
3:
4:
4:
4:
4:
4:
5:
5:
6:
6:
45
06
20
31
44
55
06
48
01
:14 PM
- 4
- 4
- 4
- 4
- 4
_ 5
- 5
- 6
- 6
*
•
;
^
*
*
;
:
:
05
19
30
43
54
05
47
00
14
angle ascent to 6000'
spiral descent
to
between 500' and
spiral ascent
.at 5000'
spiral descent
between 1000'
between 1000'
at ^1000'
to

to
and
and

500'
2000'
5000'

500'
1500
2000

MSL





i
i

            WIND:  230° at 15 mph

            WEATHER:  Sunny and hot
                                    127

-------
             8
 ALTITUDE

(XIO3 ftMSL)
             3


             2
                                                  T
                                                        '
                                             T
        Figure 34

Vertical sounding over
  Long Island Sound
  (point b) at 4:10  pm
 > on July 21, 1975.
                           70
             7


             6
 ALTITUDE

(XIO3 flMSL)
             I


             0
      Figure 35
•

Vertical sounding over
.  Madison (point c}
at 4:35 pm on July 21,
1975.
                                                   i — i — i — i — i — i — i — i — i  i   i  i  '   i
                                                    55   60   65   70  75   80   85

                                                            TEMP   (°F)
                                                        \
                                                         \
                                         \
                                           \
                                                               \
                                                                  \
                                       6


                                       5


                                       4
                                                   \
                                                      \
                                 no
                         150
                                               ppb
    60   65   70  75   80   85  90

             TEMP  (°F)
                                                       \
                                         \
                                                               t
                                                                     ^

                                                                     \
                                                                       »
                                                                        \
                                                                          >
                                                                      2


                                                                      I


                                                                      0
                           50
                     60
   70
ppb  03
80
                                          128

-------
            8


            7
ALTITUDE

(XIO3 ftMSL)
            3


            2
                          60
                                                              T
                              T
                                   T
                                                   i—i—r
                                                           ~i   i  i—i—i—i—i—i—i—i
                                                    60   65  70  75   80  85   90


                                                            TEMP  (°F)
                 \
                                                          \
                                                           *
                                                              %

                                                              \
                          \
                              \
                                                                       \
                                                                        \
                                                                          >
70
  80
ppb 0,
90
                                        9



                                        8


                                        7



                                        6


                                        5


                                        4
               Figure  36.   Vertical ozone and temperature profiles  southeast of
                           Hartford (point d) at 5:00 pm on July 21,  1975.
                                          129

-------
                       Figure 37.  Plot of aircraft data  recorded during flight #9 on July 21,  1975.
    COND.
    NUCLEI
  OcK)3 part/ml)
CO
o
    OZONE
     (ppb)
                        1600     I62O      I64O     1700      1720
                                                  FLIGHT  TIME
I74O
1800
1820
                                    VISUAL
                                  DISTANCE
                             80      (km)
                                  RELATIVE
                                  HUMIDITY

-------
    KINGSTON O
CONNECTICUT
 NEW

 YORK
                                                          "•^^^•"•^^^^^^^^•^•a™^-tt'*''fl^*'^i*i^ffp^te^\'ffiFaniiEtiig'jtni5'*fc*1Kflf^:fflff^
                                                          MASSACHUSET TS
                                                                    PUTNAM
                                                       HARTFORD
                                         MIDDLETOWN O^\
 NEW

 JERSEY
NEW YORK  CITY/
                                                  ATLANTIC

                                                       OCEAN
                                                                   Scale; I  = 21 mi.
   Figure 38.  Flight #10 on  July 22, 1975, with ozone concentrations  (ppb)
              marked at points along the route.

              TIME:   7:35 AM to 9:15 AM

               Leg   ab:   7:35 -   7:47 angle  ascent to 6000'  MSL
                      b:   7:48 -   8:02 spiral descent to 500'
                     be:   8:03 -   8:30 at ^ 1000'
                     cd:   8:31  -   8:43 between 500' and 1000'
                      d:   8:44 -   8:55 spiral ascent to 6500'
                     da:   8:56 -   9:15 angle  descent from 6500' to  landing

              WIND:  330° at 5 mph  (Groton)

              WEATHER:  Sunny and warm
                                    131

-------
             8
 ALTITUDE

(XIO3 ftMSL)
             3


             2
         Figure 39

~ Vertical sounding over
   Long Island (point b)
  at  7:55 am on July 22,
- 1975.
                           50
                      60
                                                             T
                                                                   -r
                                                        T
                                                  i—i—i—i—i—i—i—i—i—i—i   i  i  i
                                                    50  55   60  65   70   75  80

                                                            TEMP  (°F)
                                                            \
   70
ppb  0,
                                             \

                                             \
                                               \
                                                \
                                                                   \
                                                                      \
                                                       \
                                                          \
                                                           ^

                                                           \
                                                                             \
                                        9


                                        8
                                        6


                                        5


                                        4
                                       2


                                       I


                                       0
             7


             6
 ALTITUDE

(XIO3 ftMSL)
              I


             0
                Figure 40

         Vertical  sounding over
           Madison (point d) at
       01   8:50 am on  July 22,
           1975.
                       o
                        o
                           50
                      60
     50  55   60  65   70   75  80
       \
         \
             TEMP  (°F)
                                                          \
                                                            \
                                               \
                                                  \
                                                                     \
                                               ppb  03
                                                                           \
                                                            «
                                                            \

-------
                    Figure 41.  Plot of aircraft data recorded during flight #10 on July 22, 1975.
      COND.
     NUCLEI
   UK)3 part/ml)
oo
oo
          80

          60

          40

          20

            0

          70

 OZONE   6°
  (ppb)    50

          40

          30

            8

ALTITUDE
(xiO3 ftMSL)   4
            2

            0
                                    VISUAL
                                   DISTANCE
                              80     (km)
                                                                                                      RELATIVE
                                                                                                      HUMIDITY
                                 0740     0800    0820     0840
                                                  FLIGHT   TIME
0900
                                                                        0920

-------
    KINGSTON O
CONNECTICUT
 NEW

 YORK
                                       MIDDLETOWN


                                             "O
                                                      MASSACHUSETTS
PUTNAM
                                                    HARTFORD
 NEW

 JERSEY
NEW YORK
                                                       108

                                               ATLANTIC

                                                    OCEAN
                                                                Scale;  I =21 mi.
   Figure 42.  Flight #11 on July 22,  1975, with ozone concentrations (ppb)
             marked at points along  the route.
              TIME:   1:15 PM to 3:55 PM

               Leg   ab:  1:15 - 1:21 at ^1000' MSL
                     be:  1:21 - 1:37 angle ascent to 7000'
                     c:  1:38-1:57 spiral descent to 500'
                     cd:  1:58 - 2:29 at 1000'
              d,e,f  & g:  2:30 - 3:29 series of spiral ascents and descents (5001 - 5000
                     ga:  3:30 - 3:55 at 1000'

              WIND:   240° at 10 mph  (Groton)

              WEATHER:  Sunny and hot

                                  134

-------
                                                  T	r
            8


            7
      Figure 43

Vertical  sounding  over
   Madison (point  c)
at 1:45 pm on July 22,
1975.
ALTITUDE

(XIO3 ftMSL)
            3


            2


            I


            0
                                                     i  i  i   i—i—i—i—i—i—i—i—i—i
                                                    50  55   60   65   70   75  80

                                                            TEMP  (°F)
                          60
                                   \
                                                        \
                                                           i
                    70
  80
ppb 03
                                           \
90
100
                                        8


                                        7


                                        6


                                        5


                                        4


                                        3


                                        2
            7


            6
      Figure 44

Vertical sounding over
Atlantic Ocean (point e)
at 2:45 pm on July 22,
1975.
 ALTITUDE

 (XIO3 ftMSL)
                                                              I  i   I
     50  55   60   65   70   75   80

             TEMP  (°F)
                                        6


                                        5


                                        4
             I


            0
                          80
                    90
   100
ppb  03
 no
120
                                          135

-------
             1.5
 ALTITUDE

(xio3 ftMSL)
              .5
             0
                                                           i—i—i—i—i—i—i—i  r  i   i
                                                          72   74   76   78   80   82  _


                                                              TEMP  (°F)
                                         •EMP
                                                                  \
                                                                    \
                                                 \
                                                    \
                     1.5
                                                                    .5
70          80
                                             90          100
                                                ppb  0,
110          120
                Figure 45.  Vertical  ozone  and  temperature profiles over Atlantic
                            Ocean (point d)  at  2:30 pm on July 22, 1975.
                                            136

-------
                                                              T
                                                             T
            8


            7
     Figure 46

Vertical sounding over
Atlantic Ocean (point g)
at 3:00 pm on July 22,
1975.
                                                            i  i—i—i—i—i—i—i—i—i
                                                             60   65   70  75   80

                                                            TEMP  (°F)
                                        8
ALTITUDE

(XIO3 ftMSL)
            3


            2
                                                                     6


                                                                     5


                                                                     4


                                                                     3


                                                                     2
                          60
                    80
   100
                                               ppb
120
140
            7


            6
       Figure 47

Vertical sounding over
Atlantic Ocean (point f)
at  3:30 pm on July 22,
1975.
 ALTITUDE

(XIO3 ft MSL)
                         Q
                          100
                    120
                                                   I  I  [   T  I  T  I  T  T  I   I  I  I   I

                                                    70   72  74   76  78   80   82
  140
ppb  03
                                          137
             TEMP  (°F)
160
 180
                                        6


                                        5


                                        4

-------
                    Figure 48.   Plot of aircraft data recorded during flight #11  on July 22, 1975.
      COND.
     NUCLEI
   (*I03 part/ml)
00
     OZONE
      (ppb)
    ALTITUDE
    (xlO3  ftMSL)   4
                 I32O      I34O      1400     I42O     I44O     I5OO
                                                    FLIGHT  TIME
1520
1540
I6OO
                             160
                             ,20    VISUAL
                                   DISTANCE
                             80     (km)
                             40

                             0
                                                                                                   90
                             80

                             70

                             60

                             50
                         RELATIVE
                         HUMIDITY

-------
   NEW  HAMPSHIRE
   MASSACH(
             45
        WORCHEST
              46
CONNECTION
                                                   4.1  A-4
                                                        e (Spiral)
                                                        OUCHESTER
         PUTNAM
                ~m  H-I

              43-7   PROVIDENCE
                                   ATLANTIC    OCEAN
                                                                Scale:
                                          = 21 mi.
  Figure 49.   Flight #12  on July 23, 1975, with ozone concentrations  (ppb)
             marked at points along the route.
             TIME:  8:05 AM to 11:45 AM
              Leg
ab:
b:
be:
cd:
de:
e:
ef:
fa:
8:05 -
8:28 -
8:59 -
9:30 -
10:08 -
10:21 -
10:38 -
11:30 -
8
8
9
10
10
10
11
11
    :27 at ^ 1500' MSL
    :58 spiral ascent to 8000'  and descent to 1500'
    :29 at * 2000'
    :07 at ^ 2000'
    :20 angle ascent to 6000'
    37 spiral descent to 500'
    29 at ^ 1500'
- 11:45 angle ascent to 3000'  and descent to landing
             WIND:   250° at 6 mph (Groton)
             WEATHER:  Sunny and warm
                                    139

-------
             8


             7


             6
 ALTITUDE
     ftMSL)
             3


             2


             I


             0
                           LJ-J- *rmr*atfH*^i
                              -•-r- '- "-' -I"---
                                                    i — i — i
                                                                           T
                                                                       i  i
                 Figure 50       ^   5J-   gQ  6g   TO   75

            Vertical sounding near
                                                                                  80  _
              Putnam (point b) at.
              8:40 am on July 23,V
              1975.
                                                              TEMP  (°F)
        \
                                      ^

                                       \
                                         \
                                                               \
                                             \
                                               \
                                                                    \
                                                 B

                                                  \
                                                     \
                                                       \
                                         9


                                         8
                                         6


                                         5


                                         4
                           50
                   60
  70
ppb
              7


              6
 ALTITUDE

(XIO3  ftMSL)
             3


             2


              I
        Figure  51

Vertical sounding  NE of
Boston (point e) at 10:30 am
on July 23,  1975.
                                                          55   60  65   70   75  80  _
             TEMP  (°F)
                                                                \
                                                                   \
                                                 \
                                                  i

                                                  \
                                                    \
                                                       \
                                                          \
                                                             \
                                         5


                                         4


                                         3


                                         2


                                         I
                                       40
                               50
                            ppb  03

-------
 OZONE
  (ppb)
ALTITUDE
(xlO3 ftMSL)  4
                    Figure 52.  Plot of  aircraft data  recorded during  flight #12 on July 23, 1975.
                                                                          Flight  continued next page
                              0800     0820    0840     0900
                                               FLIGHT  TIME
0920     0940
1000
                                                                                                      VISUAL
                                                                                                    DISTANCE
                                                                                               80      (km)
                                   RELATIVE
                                   HUMIDITY

-------
                                               Figure 52.  Continued
ro
   OZONE
    (ppb)
  ALTITUDE
 (xlO3 ftMSL)  4
             2
                                1000     IO2O     IO4O     HOO
                                                 FLIGHT  TIME
II2O
1140
I2OO
                                                                                               160
                                                                                               ,20    VISUAL
                                                                                                    DISTANCE
                                                                                               80     (km)
                                                                                               40
                            90

                            80

                            70

                            60

                            50
                        RELATIVE
                        HUMIDITY

-------
                 O WORCHESTER

MASSACHUSETTS
       PUTNUM
CONNECTICU
                         ATLANTIC
            OCEAN
 Figure 53.  Flight #13 on July 23, 1975, with ozone concentrations  (ppb)
           marked at points along the route.
           TIME:  3:20 PM to 5:10 PM
            Leg
ab:
b:
be:
Cd:
de:
e:
ea:
3:20
3:40
3:52
4:08
4:21
4:32
4:50
- 3:39
- 3:51
- 4:07
- 4:20
- 4:31
- 4:49
- 5:10
angle ascent to 5000' MSL
spiral descent to 500'
at ^ 1500'
at -b 1500'
between 500' and 2000'
                                spiral ascent  from 500'
                                across sound at 2500'
                     to 3500' and down to 2500'
           WIND:  220° at 12 mph (Groton)

           WEATHER:  Sunny and hot

                                143

-------
             9  -
             8
 ALTITUDE

(xio3 ft MSL)
             3


             2


             I


             0
                                                             T
      Figure 54

Vertical  sounding near
Putnam (point b) at 3:45 pm
on July 23, 1975.
        ,—,—|—|—,—i—i  i  i   r—i  i
         60  65   70   75   80  85

             TEMP  (°F)
                          9


                          8

                                                                  \
                                                                   »
                                                                   \
                                                 i
                                                  \
                                                     \
                                                        \
                                       6


                                       5


                                       4


                                       3


                                       2
                          60
                   70
  80
ppb 03
             7


             6
 ALTITUDE

(XIO3 ft MSL)
             2


             I


             0
       Figure 55

Vertical  sounding over
 Long Island (point e)
 at 4:45  pm.
              65   70  75   80  85  -

             TEMP  (°F)
                                                                   2


                                                                   I


                                                                   0
                          60
                   80
   100
ppb  03
120
                                                                        140
                                           144

-------
            9  h



            8


            7
ALTITUDE

(XIO3  ftMSL)
            4



            3


            2


            I


            0
                          140
                        78   80   82  84   86

                      TEMP  (°F)
160
   180
ppb  03
200
220
                Figure 56.   Vertical  ozone  and  temperature profiles on descent
                            to landing  at Groton  (point a) at 5:10 pm on  July
                            23, 1975.
                                        9


                                        8
                                                  6


                                                  5


                                                  4


                                                  3


                                                  2
                                           145

-------
                     Figure 57.   Plot of aircraft  data recorded during flight #13 on July 23, 1975.
CTl
     OZONE
      (ppb)
    ALTITUDE
   (xlO3 ftMSL)   4
                                   I53O      I55O      I6IO      1630
                                                    FLIGHT   TIME
f65O
I7IO
                                                                                                 — 160
                                                                                                          VISUAL
                                                                                                         DISTANCE
                                                                                                            (km)
                                   RELATIVE
                                   HUMIDITY

-------
   NEW  HAMPSHIRE
   MASSACHUSETTS
       WORCHESTER O
              73
         PUTNAM
CONNECTICU
             65
                                     O LAWRENCE
                                     90    104
                                                  MARTHA'S j
                                                  (VINEYARD^
                                   ATLANTIC   OCEAN
                                                               Scale;  I  - 21 mi.
  Figure 58.  Flight #14 on July 24, 1975, with ozone concentrations (ppb)
            marked at points  along the route.
             TIME:  9:15 AM to 12:30 PM
              Leg
             WIND;
ab:
b:
be:
cd:
d:
de:
ef:
fa:
9:15
9:46
10:06
10:13
10:57
11:13
11:47
12:14
             9:45 at ^ 1500' MSL
            10:05 spiral ascent to 5000' and descent to  2000'
            10:12 at 2000'
            10:56 counterclockwise arc at ^ 2000'
            11:12 spiral ascent to 5000' and descent to  2000'
            11:46 counterclockwise arc at 2000'
            12:13 at 1500'
            12:30 ascent to 4000' and spiral descent to  landing
240° at 6 mph (Groton)
220° at 12 mph (Boston)
             WEATHER:  Sunny and warm
                                     147

-------
 ALTITUDE

(xlO3 ftMSL)
                                                         i—r~i
                         Figure 59

                   Vertical sounding NE of
                   Putnam (point b)  at 9:55 am
                   on July 24, 1975.
                                         TEMP  (°F)
                           o
                                                                    o
                                                                    6


                                                                    5


                                                                    4


                                                                    3


                                                                    2
                          40
                   60
  80
ppb  0,
100
120
             7


             6
 ALTITUDE

(XlO3 ftMSL)
             2


             I


             0
   1      i      '     r

      Figure 60

Vertical  sounding north
  of  Boston (point d)
  at  11:05 am on July
  24, 1975.
     70  72   74   76  78   80  82

             TEMP  (°F)
                                       6


                                       5


                                       4


                                       3


                                       2


                                       I


                                       0
                          60
                   80
                                          148
   100
ppb  03
120
140

-------
            8


            7
 ALTITUDE

(xlO3 ftMSL)
            3


            2


            I


            0
                          50
60
                                                          i   i  i  i—i—i—i—i—i—i—i

                                                         72   74   76  78   80   82

                                                             TEMP  (°F)
  70
ppb 03
80
90
                                                  8
                                                  6


                                                  5


                                                  4


                                                  3


                                                  2


                                                  I


                                                  0
               Figure 61.  Vertical  ozone and temperature profiles on descent
                           to landing at Groton (point a) at 12:30 pm on July
                           24, 1975.
                                          149

-------
                       Figure 62.  Plot of aircraft data recorded during flight #14 on July  24, 1975.
LJl
   OZONE
     (ppb)
                                                                                                          VISUAL
                                                                                                         DISTANCE
                                                                                                           (km)
                                                      RELATIVE
                                                      HUMIDITY
              O93O      O95O     IOIO       IO30
 I05O      1110
FLIGHT  TIME
1130      I ISO       1210      I23O

-------
   NEW  HAMPSHIRE
                                   O LAWRENCE
                                   90    103
   MASSACHUSETTS
       WORCHESTER O
                                    85  81  8I
                    PROVIDENCE

                     RHOa
CONNECTICU
            89
                                                MARTHA1^

                                                VINEYARDk!
                                 ATLANTIC    OCEAN
  Figure 63.  Flight #15 on July 24, 1975, with ozone concentrations (ppb)
            marked at points along the route.
             TIME:  2:20 PM to 5:20 PM

              Leg   ab:  2:20 - 2:41  at 1500' MSL
                    b:  2:42 - 3:07  spiral  ascent to 7000' and descent to 1500'
                   be:  3:08 - 3:17  at 1500'
                   cd:  3:18 - 4:41  counterclockwise arc  at -\, 1500'
                   da:  4:42 - 5:20  at 1500'

             WIND:  210° at 10 mph (Groton)
                   220° at 18 mph (Boston)

             WEATHER:  Partly cloudy  and hot

                                 151

-------
             8
 ALTITUDE

'xlO3 ftMSL)
                           50
60
                                                       ~1	1	1	1	1	1	1	1	:	1  1	1

                                                         60  65   70   75   80  85


                                                            TEMP  (°F)
                                                              \
                                                                 \
                              \
                                %

                                \
                                                                           \
   70
ppb  0,
80
                Figure 64.  Vertical ozone and  temperature profiles NE of Putnam
                           (point b) at 3:00 pm  on July 24, 1975.
                                                 3


                                                 2
                                          152

-------
                   Figure 65.  Plot of aircraft data recorded during flight #15 on July  24, 1975.
en
oo
          130

OZONE    "°
 (ppb)     90

          70

          50

           8
   ALTITUDE
  (xlO3 ftMSL)  4
              6 -
              2 	
               1420
                                                                                                        VISUAL
                                                                                                      DISTANCE
                                                                                                 80      (km)
                    1440     1500      1520      1540      1600
                                              FLIGHT   TIME
1620
1640
1700
1720
                                                                                                      RELATIVE
                                                                                                      HUMIDITY

-------
 NEW   HAMPSHIRE
                                O  LAWRENCE
                                                GLOUCHESTER
 MASSACHUSETTS
     WORCESTER O
                                    (Spiral) d
                                 29  30 .JF 3
                           >

                  ISLAN
CONNECTICU
            26
                                ATLANTIC
                                             OCEAN
Figure 66.  Flight #16 on July 26, 1975, with ozone concentrations  (ppb)
          marked at points along the route.
           TIME:  9:40 AM to 12:50 PM
            Leg
ab:
b:
be:
cd:
d:
de:
ef:
fa:
340°
320°
9:40 - 10:10 at 1500' MSL
10:11 - 10:30 spiral ascent to
10:31 - 10:40 at 1500'
10:41 - 11:00 counterclockwise
11:01 - 11:29 spiral ascent to
11:30 - 11:50 at 1500'
11:51 - 12:13 at 1500'
12:14 - 12:50 at 1500'
at 12 mph (Groton)
at 12 mph (Boston)
                                               5000' and descent to 1500'

                                               arc at 1500'
                                               5500' and descent to 1500'
           WIND:
           HEATHER:  Sunny and warm
                                154

-------

9
8

7
6

ALTITUDE
3 5
(XIO ftMSL)
4
3
2
1
O
	 	 1 	 1 	 1 	 1 	 • 	 1 	 -, 	 , -. 	 r 	 -p. 	 r 	 ,
"""i i i i i i r— i — i — i — i — i — i
Fi9Ure 67 50 55 60 65 70
Vertical sounding NE of TEMP /oF\
- Putnam (point b) at 10:15 am
on July 26, 1975.
••
mm


of \
i )
\ \
i \
-
iiiiiiiiiii

9


7



5
4
3
2
1
n
30 40 50
ppb 03

7

6

5
ALTITUDE
4
', XIO3 ft MSL )
3
*ij
2
1


ii 'I'l'i'i*
Fi'qiirp fifi
3 i i i i i i i i i i i i i i
.. .. , j- ec * 50 55 60 65 70 _
Vertical sounding SE of
Boston (point d) at 11:15 am
on July 26, 1975. TEMP ( F}
-
/ 1
o / I
J \
— /o ~
/ \
— ^ \
f \
\ x\
«•••
,.1,1.1, i

7

6

5

4

3

2
1
O
40 50
155
     ppb 03

-------
                     Figure  69.   Plot of aircraft data  recorded during flight  #16 on July 26, 1975.
      COND.
     NUCLEI
   (x(03 part/ml)
en
en
     OZONE
      (ppb)
    ALTITUDE
   (xlO3  ftMSL)   4
                2
                095O
                                                                                  VISUAL
                                                                                 DISTANCE
                                                                           80      (km)
IOIO
I03O
IO5O
1110
1130
I ISO
1210
1230
                                                                         I25O
                                                                                 RELATIVE
                                                                                 HUMIDITY
                                                     FLIGHT   TIME

-------
   NEW  HAMPSHIRE
                                    —^

                                     O LAWRENCE^
                                    35  	3f

                                36  Jr~   ^>v>38  CXGLOUCHESTER
   MASSACHUSETTS    35,

                            34.
                      fl!
                               •42
                                 BOSTON
        WORCHESTER O     34

                      34

                     *A-5,6
                            34-
                                             (Spiral)^
              33'

         PUTNAM
              *

             35

CONNECTION
            37-
                                    39
                                           r •
                                            43
                                     CAPE  COD
PROVIDENCE

 /?//0,

 ISL
                       41
                 )N /
                                  ATLANTIC   OCEAN
                                                               Scale;
                                                  = 21 mi.
  Figure 70.  Flight #17 on July 26, 1975, with ozone concentrations (ppb)
            marked at points along the route.
             TIME:  -3;00 PNT to 6:05 PM
              Leg
ab:
b:
be:
cd:
d:
de:
ea:
3:00 -
3:26 -
3:53 -
4:05 -
4:32 -
4:56 -
5:37 -
3:25
3:52
4:04
4:31
4:55
5:36
6:05
              at 1500'  MSL
              spiral ascent to 7000' and descent to 1500'
              at 1500'
              counterclockwise
              spiral ascent to
              counterclockwise
              at 1500'
                                                 arc at  1500'
                                                 7000' and descent to 1500'
                                                 arc at  1500'
             WIND:  350°  at 10 mph  (Groton)
                   340°  at 10 mph  (Boston)
             WEATHER:  Sunny and  warm
                                    157

-------
 ALTITUDE

(XIO3 ft MSL)
             3


             2
                          Figure 71

                   Vertical sounding NE of
                   Putnam  (point b) at 3:35 pm
                   on July 26, 1975.
            i—i—i—i—T—i—i—i—i—r—i  i  i  i
                  50   55   60  65   70   75

                      TEMP  (°F)
             7


             6
 ALTITUDE

(XIO3 ft MSL)
                           40
                          40
50
                                                            \
                                                             \
                                                                \
                            \
                              \
                                 \
                                                                         \
                                       6


                                       5


                                       4


                                       3


                                       2
                                                  I
  60
ppb 0,
                                                       I  I   I  T  I   I  I  I  I   I  I  1

                                                             50  55   60   65  70
                           f
                      TEMP/ (°F)
                          \
                           \
                              \
                               \
                                                                      v
                                                                      \
                                                Figure 72

                                         Vertical sounding  east
                                            of Boston (point  d)
                                            at 4:45 pm on July
                                            26, 1975.
                                                                        \
                                       6


                                       5


                                       4


                                       3
                                     \
                                       \
50
  60
ppb

-------
                 Figure 73.  Plot of aircraft data  recorded during flight #17  on July 26, 1975.
           60

 OZONE    50
  (ppb)     40

           30

           20

            8

ALTITUDE
(xlO3 ftMSL)   4
            2
            0
             1500     1520      1540     1600     1620     1640
                                               FLIGHT  TIME
1700
1720
1740
                                                                                                    VISUAL
                                                                                                   DISTANCE
                                                                                              80     (km)
1800
                                  RELATIVE
                                  HUMIDITY

-------
   NEW  HAMPSHIRE
   MASSACHUSETTS   39
        WORCHESTER O
              38
         PUTNAM

             38


CONNECTICU

           38
                                                   RTHA1
                                                  flNEYARD.
              36
                                  ATLANTIC    OCEAN
  Figure 74.  Flight #18 on July 27, 1975, with ozone concentrations (ppb)
             marked at points along the route.
             TIME:   9:10 AM to 12:15 PM
              Leg
             WIND:
ab:
b:
be:
cd:
d:
de:
ea:
9:10 -
9:35 -
9:55 -
10:04 -
11:01 -
11:30 -
11:36 -
9:34
9:54
10:03
11:00
11:29
11:35
12:15
                at 1500'  MSL
                 piral ascent to 5000' and descent to 1000'
                 at 1500'
                 counterclockwise
                 spiral ascent to
                 counterclockwise
                 at 1500'
                                                   arc at 1500'
                                                   6000' and descent to
                                                   arc at 1500'
1500'
040° at 5 mph (Groton)
100° at 5 mph (Boston)
             WEATHER:  Sunny and warm
                                    160

-------
9   -



8


7
ALTITUDE

(xlO3 ftMSL)
 3


 2



 I


 0
               30
            7


            6
 ALTITUDE
    ft MSL )
            2


            I


            0
               30
      Figure 75

Vertical sounding NE of
Putnam (point b)  at 9:45  am
on July 27, 1975.
                                                          ~i  i   i  r—i—i—i—i—i—i
                                                   50   54  58   62  66  70   74

                                                           TEMP  (°F)
               40
              40
                50
                                                                                       8
                                               *




                                              \

                                                           \
                                                                   -^
                                                                     \
                                                                      \
                                                                 6


                                                                 5


                                                                 4


                                                                 3


                                                                 2


                                                                 I


                                                                 0
                                               ppb
                                        48   52  56   60  64   68   72

                                                TEMP  (°F)
                                                            r
                                                            /
                                                                           6


                                                                           5


                                                                           4
                                 Figure 76

                           Vertical sounding SW
                            of Boston (point d)
                            at 11:15 am on  July
                            27, 1975.
                                                                           V
                                                        »
2


I


0
                                     50
                                              ppb  0,
                                          161

-------
                      Fic.ure 77.   Plot of aircraft  data recorded  during flight #18 on July 27, 1975.
     COND.
    NUCLEI
     part/ml)
ai
no
    OZONE
     (ppb)
  ALTITUDE
  (xlO3 ftMSL)  4

              2
              0920    0940      IOOO     IO2O      I04O      HOO
                                                  FLIGHT  TIME
1120
II4O
1200
                                   VISUAL
                                  DISTANCE
                             80     (km)
1220
                                  RELATIVE
                                  HUMIDITY

-------
   NEW  HAMPSHIRE
   MASSACHUSETTS
CONNECTICU
            61
                                  ATLANTIC    OCEAN
                                                              Scale;  l" = 21 mi.
 Figure 78.   Flight #19 on July 27, 1975, with ozone concentrations  (ppb)
            marked at points along the route.
             TIME:  2:50 PM to 5:55 PM

              Leg   ab:   2:50 - 3:09 at 1500' MSL
                    b:   3:10-3:39 spiral ascent to 8000' and descent to 1500'
                   be:   3:40 - 3:48 at 1500'
                   cd:   3:49 - 4:29 counterclockwise arc at 1500'
                    d:   4:30 - 5:00 spiral ascent to 7000' and descent to 1500'
                   de:   5:01  - 5:22 counterclockwise arc at 1500'
                   ea:   5:23 - 5:55 at 1500'

             WIND:  180°  at 10 mph (Groton)
                   120°  at 12 mph (Boston)
            WEATHER:  Sunny and warm
                                  163

-------
 ALTITUDE

(xio3 ft MSL)
             0
                       rj.v»r---;^.*ia«w-J,fci rm

                                                      i—i—i—i—i—i—i—i  i   i  i   i  i
                                                    54   58  62   66   70  74   78
                                                             TEMP (°F)
                                                         \
                                                           *

                              ^
                                                           \
                                                              \
                                                                %
                                                                 \
                         Figure 79

                   Vertical sounding NE of
                   Putnam (point b) at 3:20  pm
                   on July 27, 1975.
                                         \
                                            \
                                              \
                                                  t
                                                  8


                                                  7


                                                  6


                                                  5


                                                  4


                                                  3


                                                  2


                                                  I


                                                  0
                30
40
50
  60
ppb 03
 ALTITUDE

(XIO3 ft MSL)
             3


             2
                                                         52   56,  60   64  68   72
       Figure 80

Vertical sounding north of
Boston (point d) at 4:45 pm
on July 27, 1975.
                                                                               \
                                                 6


                                                 5


                                                 4


                                                 3


                                                 2
                                                                                 \
                40
50
60
   70
ppb  03
80

-------
                     Figure 81.   Plot of aircraft  data recorded during flight #19 on July 27, 1975.
CJ1
   OZONE
     (ppb)
                                                                                                 160
                                                                                                 ,2o    VISUAL
                                                                                                      DISTANCE
                                                                                                 80     (km)
RELATIVE
HUMIDITY
               4500     1520      1540      1600     1620     1640     1700      1720      1740    1800
                                                  FLIGHT  TIME

-------
                                                       MASSACHUSETTS
                             CONNECTICUT
                                         PUTNAMO
KINGSTON O
                           O DANBURY
NEW
JERSEY
                                                               71 (3000')
                                                               67 (4000')
                                                              47 (6000')

                                                             55 (7000')

                                                            54  (80001)
                                                ATLANTIC
                                                 *k

                                                     OCEAN
                                                                 Scale;  I  =21 mi
   Figure 82.   Flight #20 on July 28, 1975, with ozone  concentrations (ppb)
              marked at points along the route,


              TIME:  10:05 AM to 11:45 AM
               Leg
              WIND:
                ab:
                be:
                cd:
                 d:
                da:

                230°
                260°
10:05 - 10:18 at 1500' MSL
10:19 - 10:43 between 1000'  and 2000'
10:44-10:58 between 500' and 2000'
10:59 - 11:15 spiral ascent to 8000'
11:16-11:45 slant descent from 8000'

at 20 mph (Groton)
at  8 mph (New York)
              WEATHER:  Cloudy and warm
                                  166

-------
            8


            7
 ALTITUDE

(xlO3  ftMSL)
3


2


I


0
                           50
60
                                                   T
                                                                          T
                                                      |  ii   r  i  i—i—i—i—i—i—,—|
                                                    50  55   60  65   70   75   80

                                                             TEMP  (°F)
                   \
                                                           \
                                                             \
                                                               ^
                           \
                                                                  \
                                                                    \
                                                                      \
                                                                        \
                                                                          \
                                                                           \
                                      70
                                                ppb
               Figure 83.  Vertical ozone and temperature  profiles over Atlantic
                           Ocean (point d) at 11:05 am on  July 28, 1975.
                                                  9


                                                  8
                                                  6


                                                  5
                                                  3


                                                  2
                                         167

-------
                       Figure 84.  Plot of aircraft data recorded during flight #20 on July 28,  1975,
en
oo
             160

     COND.   120
    NUCLEI
      part/ml)
    OZONE
80

40

 0

100

80

60

40

20

 8
   ALTITUDE
   (x!03 ftMSL)   4

               2

               O
                             160
                             ,20    VISUAL
                                  DISTANCE
                             80      (km)

                             40
                                  RELATIVE
                                  HUMIDITY
                        IOOO     IO2O     IO4O       1100     1120
                                                  FLIGHT  TIME
II4O
                                                                I20O

-------
                                                       MAbbAUHUSEI
KINGSTON O
                              CONNECTICUT
                            O DANBURY
NEW

JERSEY
                                                ATLANTIC

                                                     OCEAN
   Figure 85.  Flight #21 on July 28, 1975, with ozone concentrations (ppb)
             marked at points along the route.
              TIME:  2:30 PM to  5:20 PM
Leg
a:
ab:
b:
be:
cd:
d:
de:
ef:
fa:
2:30 -
3:01 -
3:11 -
3:36 -
4:17 -
4:28 -
4:46 -
5:01 -
5:11 -
3:00
3:10
3:35
4:16
4:27
4:45
5:00
5:10
5:20
                                   spiral ascent
                                   between 1500'
                                   spiral ascent
                                   at 1500'
                                   at 1500'
                                   spiral ascent
                                   at  1500'
                                   at -v 1500'
                                           to 8000'
                                           and 2000
                                           to 7000'
and descent to 500' MSL

and descent to 1500'
                                           to 5000' and descent to 1500'
             WIND:  225° at 10 mph (Groton)

             WEATHER:  Partly cloudy and warm

                                     169

-------
             8
 ALTITUDE

(xlO3 ftMSL)
             7


             6
 ALTITUDE

(XlO3 ft MSL)
                             Figure 86

                        Vertical sounding  near
                        Groton (point a) at  2:45 pm
                        on July 28, 1975.
                ^     I
             —I—I—I—I—I—1—I—I—1—I—I—I—I
              50  55   60   65  70  75   80
                      TEMP (°F)
                          60
80
              \
                                                      i
                                                      \
                                                        \
                                                           \
                       \
                         i
                                                                  \
                                                                    \
                                                                     ^

                                                                      \
                                                                        \
                                                                         \
                                                                          \
                                                                            \

                                                                            \
                                                 8


                                                 7


                                                 6


                                                 5
                                                3


                                                2
            100
         ppb  0,
120
140
              50\ 55   60   65  70   75  80  _

                   \ TEMP  (°F)
                     \
                       \
                        \
                           \
                             \
                                                                     \
                         Figure 87

                   Vertical sounding SE of
                     Hartford (point b) at
                     3:20 pm on July 28, 1975
                                  \
                                     \
                                        \
                                                6


                                                5
                          60
80
            100
120
140
                                          ,70

-------
            8
 ALTITUDE
(xlO3  ftMSL)
            3

            2
                                                                                T
                          60
                                                             i  i  \	1	r—i—i—i	1—i
                                                              60   65  70   75   80
                                                             TEMP  (°F)
80
  100
ppb 03
                          \
                           v
                            \
                                                                    •
                                                                       •\
                                   *
                                    \
                                       \
                                                                              ^
                                                                               \
120
               Figure 88.  Vertical ozone and temperature profiles  south of
                           Long Island (point d) at 4:35 pm on  July 28, 1975
                                                  9

                                                  8
                                          171

-------
                     Figure 89.   Plot of aircraft data recorded during flight #21  on July 28, 1975.
   COND.
  NUCLEI
    part/ml)   80
ro
  OZONE
    (ppb)
 ALTITUDE
 (xlO3  ftMSL)   4
             2
              142O      I44O      I5OO      I52O     I54O     I6OO
                                                 FLIGHT   TIME
1620
1640
1700
                             160
                             ,20    VISUAL
                                  DISTANCE
                             80     (km)
1720
                                  RELATIVE
                                  HUMIDITY

-------
 NEW  HAMPSHIRE
                                  O  LAWRENCE"
                                  34       33
                                                    GLOUCHESTER
 MASSACHUSETTS
                              rA-4
                          31-
                               BOSTON
     WQRCHESTER O        32" \c
                      ol
                  30
                             35
                   b (Spiral)     BRO/K
                                                    .4!
                                                    •42


                                                    41
                                                   A-2,3
                                                    rf (Spiral)
         PUTNAM

              31 •


CONNECTION
            30.
                                       38
                                 '38
                                •38
                  PROVIDENCE<
                    ISLAND?
                     38
                 '39
                                                 XT
                                                1  MARTHA'S^

                                ATLANTIC    OCEAN
                                                             Scale; I   =  21 mi.
Figure 90.   Flight #22 on July 29, 1975, with ozone concentrations (ppb)
           marked at points along the  route.
           TIME:  9:20 AM to 12:20 PM
            Leg
ab:
b:
be:
cd:
d:
de:
ea:
9:20
9:43
10:09
10:16
10:35
11:00
11:48
                                9:42 at 1500' MSL
                               10:08 spiral ascent to 7000' and descent to 1000'
                              ,10:15 at 1500'
                               10:34 counterclockwise arc at 1500'
                               10:59 spiral ascent to 6000' and descent to 1500'
                               11:47 counterclockwise arc at 1500'
                               12:20 at 1500'
          WIND:  330° at  8 mph (Groton)
                 330° at 11 mph (Boston)
          WEATHER:  Sunny and warm
                                 173

-------
             9  -
             8
 ALTITUDE

(XIO3 ftMSL)
        Figure 91

Vertical  sounding NE of
Putnam (point b) at 9:50 am
on July 29, 1975.
                                                             T
                                                                              '  '
          ~i — i — i — r — i — i — i  T  i
       45   50  55   60  65   70   75


               TEMP  (°F)
             7


             6
 ALTITUDE

(XIO3 ftMSL)
             0
                           o

                           o
 o
io
                           30
                                                         9


                                                         8
                                    \
                                     ^
                                      \
                                                           \
                                           \
                                              \
                                                                 *
                                                                   \
                                                                    ^
                                                                       ^
                                                                          •

                                                                          \
                                                                           \
                                          6


                                          5


                                          4


                                          3


                                          2


                                          I


                                          0
                   40
                                               ppb 0,
                                                  I
                                           T
                             I
                                                  1   I  Til  i  i  1   1  1  I   I  I  I

                                                        50   55  60  65   70  75
                                         TEMP (°F)
                                         \

                                             \
                                               \
                                                 \
                                          5


                                          4
                                                                     \
                                                  Figure 92
                                      o
Vertical  sounding SE of
Boston (point d) at 10:50 am
on July 29,  1975.
                                                                           \
                                                                            \
                                                                              \
                                                                    2


                                                                    I
                           30
                   40
                                          174
                                               ppb  03

-------
                    Figure 93.   Plot of aircraft  data recorded during flight #22 on  July 29, 1975.
     COND.
    NUCLEI
   (*K)3 part/ml)
-4
en
     OZONE
      (ppb)     40
                                      A.i|20     VISUAL
                                       ^v    I      DISTANCE
                                                80      (km)
                0920
0940     1000      1020
 1040     1100
FLIGHT   TIME
1120
1140
1200      1220
                                                     RELATIVE
                                                     HUMIDITY

-------
   NEW  HAMPSHIRE
                                    O LAWRENCE
   MASSACHUSETTS    32

                            38
        WORCHESTER O      37
                      38
                     PROVIDENCEQ

                      RHODE
CONNECTICU
            46
                                                 MARTHA'
                                                 (VINEYARD
                                  ATLANTIC    OCEAN
  Figure 94.  Flight #23 on July 29, 1975, with ozone concentrations (ppb)
             marked at points along the route.
             TIME:   2:35 PM to 5:35  PM
              Leg
ab:
 b:
be:
cd:
 d:
de:
ea:
2:
3:
3:
3:
3:51
4:16
5:02
:35
:02
:26
:35
- 3
at
       1500' MSL
3:25 spiral  ascent to 7000'  and descent to 1500'
3:34 at 1500'
3:50 counterclockwise arc at 1500'
    spiral  ascent to 7000'  and descent to 500'
    counterclockwise arc at 1500'
  4:
  5:
  5:35 at
                                       1500'
             WIND:   320° at 8 mph (Groton)
                    330° at 10 mph (Boston)
             WEATHER:  Sunny and hot
                                  176

-------
           8
       Figure 95

Vertical  sounding NE  of
Putnam (point b)  at 3:15 pm
on July 29, 1975.
                                                   50   55  60   65   70  75  80

                                                           TEMP (°F)
ALTITUDE

(XIO3 ftMSL)
            3


            2


            I


            0
 ALTITUDE

(XIO3 ftMSL)
            2


            I


            0
                          30
                                 10
                                  /
                                  \
                                        9


                                        8


                                        7
                                                     \
                                      \
                                        \
                                                           \
                                 ol
                                                             ^
                                                                \
                                                  \
                                                    \
                                                      V
                                                       \
                                       5


                                       4


                                       3


                                       2
                    40
                                              ppb  03
                                                  i
                                            i
                                                       i
                                                  i—i—i—i—i—i—i—i—i—r—i—i—i—i
                                                        55   60  65   70   75   80
                                  f
                                  \      TEMP  (°F)
                                   \
                                      \
                                         \
                                           \
                                              \
                                                \
                                       6


                                       5


                                       4
                                                                    \
       Figure 96

Vertical sounding SE  of
Boston (point d) at 4:05 pm
on July 29, 1975.
                                                                      «*
                          \
                            \
                             \
                          50
                    60
                                         177
   70
ppb  03

-------
                     Figure 97.  Plot of aircraft data recorded  during flight #23  on July 29, 1975.
      COND.
     NUCLEI
   (xlO3 part/ml)
00
     OZONE
      (ppb)
              160
    ALTITUDE
   (xlO3 ftMSL)
                 I44O     15OO      I52O      I54O      I6OO      I62O
                                                    FLIGHT  TIME
I64O
1700
I72O
f74O
                                   RELATIVE
                                   HUMIDITY

-------
   NEW  HAMPSHIRE
                                    —f          i
                                     O LAWRENCE
   MASSACHUSETTS
                                 BOSTON
        WORCHESTER O
              47

         PUTNAM
             40
CONNECTICU
                     (
-------
             9  -
             8
 ALTITUDE

(XIO3 ftMSL)
             3


             2
           - 0
                          T"
                        Figure 99
                               T
Vertical  sounding NE of
Putnam (point c) at 9:45 pm
on July 30,  1975.
I—I—1—I—I—1  I  I
      60   65   70

         TEMP  (°F)
                                                    i—i  i  i   i
                                                   75   80   85
             7


             6
 ALTITUDE

(XIO3 ftMSL)
             2


             I


             0
                                           9


                                           8


                                           7
                                                               \
                                              \
                                                \
                       ol
                                                                    \
                                                                      \
                                                      \
                                                                          \
                          40
                   50
                                               ppb
           Figure 100            '

     Vertical sounding near
     Groton (point f) at 10:45 pm
     on July 30, 1975.
         I  i   I  I  I  T   I  T  I   I  1  t  1

                 65   70  75   80  85


                TEMP  (°F)
                                                                  \
                                                                   \
                           •^

                           \
                                                                   5


                                                                   4
                                                                        \
                                                       \
                                                        \
                    40
              60
                                         180
80          100
   ppb  03
                120

-------
                  Figure 101.  Plot of aircraft  data recorded during flight #24 on July 30, 1975.
            160

    COND.   120
   NUCLEI
    3         80
  OcO part/ml)
             40
00
    OZONE
     (ppb)
          100

           80

           60

           40

           20

            8

ALTITUDE   6
(xlO3 ftMSL)   4

            2

            0
                       2100     2120     2140     2200    2220
                                                 FLIGHT  TIME
2240
                                                                        2300
                                    VISUAL
                                   DISTANCE
                              80     (km)
                                  RELATIVE
                                  HUMIDITY

-------
  NEW  HAMPSHIRE
                             / O LAWRENCE
                                               GLOUCHESTER
  MASSACHUSETTS
       (2000') 64
       PUTNAM
      (6000") 30
                 PROVIDENCEO '.
                  RHODE
                  ISLAND
       (40001 30
CONNECTICU
  34 (5000)
       ~
37001)
                                         -VINEYARD
                              ATLANTIC    OCEAN
Figure 102.  Flight #25 on August 2, 1975, with ozone concentrations (ppb)
          marked at points along the route.
TIME: 12:00 to 2:40 PM
Leg ab:
be:
c:
cd:
d:
de:
e:
ef:
12:00 -
12:18 -
12:28 -
12:41 -
12:57 -
1:41 -
2:06 -
2:16 -
12:17 angle ascent to 5000' MSL
12:27 angle descent to 1000'
12:40 spiral ascent to 7000'
12:56 angle descent to 1500'
1:40 spiral ascent to 9000' and descent
2:05 at * 1000'
2:15 spiral ascent to 5000'
2:40 angle descent to landing




to 1500



           WIND: Calm
           WEATHER:  Hazy and hot
                                182

-------
            9  h



            8


            7
      Figure 103

Vertical  sounding  NE of
Putnam (point c) at 12:35 pm
on August 2, 1975.
            70   75  80  85   90  95

                TEMP  (°F)
                                           8
                                                          \
ALTITUDE

(XIO3  ftMSL)
                                           \
                                              \
            3


            2


            I


            0
                                                                   \
                                           6


                                           5


                                           4


                                           3


                                           2
                                I
                    30
              40
50         60
   ppb  0,
70
                                                                         I
             7


             6
      Figure 104

Vertical sounding  near
Cape Cod (point e) at
2:10 pm on August  2,
1975.
                                                    I   I  I  I   I  I  I  I   I  I  I   !  1

                                                             75  80   85  90   95
                TEMP  (°F)
                                                                  \
 ALTmiDE

 (XIO3 ftMSL)
                                                  \
                                                   \
                                                                       \
                                                                         \
                                                                           \
                                                                    3


                                                                    2
                                                                             \

                                                             60

-------
            8
ALTITUDE
     ftMSL)
            3


            2
                         30
                                            \
                                                   65  70   75   80  85   90  95
                                              >
                                                           TEMP  (°F)
           ^
           \
                                                   \
                                                     \
                                                       \
40
  50
ppb
60
70
               Figure 105.  Vertical ozone  and temperature profiles SW of Boston
                           (point d) at 1:15 pm on August 2,  1975.
                                                6


                                                5
                                        184

-------
                   Figure 106.   Plot of aircraft data recorded during flight  #25 on August 2,  1975.
     COND.
    NUCLEI
     •*
  (xK) part/mi)
00
en
     OZONE
      (ppb)
    ALTITUDE
    (xlO3 ftMSL)  4
                1200      S220      i240     1300     1320     1340
                                                  FLIGHT  TIME
1400
1420
1440
                                    VISUAL
                                   DISTANCE
                                     (km)
                                  RELATIVE
                                  HUMIDITY

-------
                                                   GLOUCHESTER
   NEW   HAMPSHIRE
                                  O LAWRENCE
   MASSACHUSETTS
       WORCHESTER O
                   PROVIDENCEO

                    RHODE^

                     ISLAND
             53

CONNECTICU
            49
32 (70001
                                               VINEYARD
                                 ATLANTC    OCEAN
Figure 107.
           Flight #26 on August 2,  1975, with ozone concentrations (ppb)
           marked at points along the route.
             TIME:  8:35 PM to 11:20 PM
              Leg
ab:
b:
be:
c:
cd:
d:
de:
8:35
9:03
9:21
9:48
10:15
10:39
10:57
                               9:02 angle ascent to 7000' MSL
                               9:20 spiral descent to 500'
                               9:47 at 1500'
                              10:14 spiral ascent to 6000' and descent to 1500'
                              10:38 at 1500'
                              10:56 spiral ascent to 5000' and descent to 1500'
                              11:20 at 1500'
             WIND:  310° at 5 mph (Boston)

             WEATHER:   Clear and hot

                                186

-------
           9  h



           8


           7
ALTITUDE

(XIO3 ftMSL)
            3


            2



            I


            0
 ALTITUDE

(XIO3 ftMSL)
            I


            0
     Figure 108

Vertical sounding  near
  Cape Cod (point  b)
  at 9:10 pm on  August
  2, 1975.
                              '  I   I  I  I - 1 - 1 - T - 1 - 1 - 1 - 1— 1

                             70   75   80   85   90  95   100
                                     TEMP (°F)
                                                                8
                          50
                          \
                                                   \
                                                      \
                                  \
                                                              \
                                                                 \
                                            \
                                              \
                                                \
                                                  \
                                                    \
                                                      ^

                                                      \
                                                                5


                                                                4


                                                                3


                                                                2


                                                                I


                                                                0
              70
                           90
                        ppb  0,
110
                                                  I
                                      I
                                                  I   I  I  I  I   I  T  11  i  1  I   I  1

                                                   65   70   75  80   85   90   95
                                 T
                                                          \TEMP  (°F)
                                                              \
                                                                \
                                                                  \
                                             \
                                               \
                                                                5


                                                                4
                                                                       \
      Figure 109

Vertical sounding SW  of
Boston (point c) at 10:00 pm
on August 2, 1975.
                                                                          \
                                                                             \
                                                               2


                                                                I


                                                                0
                          40
              50
                                         187
                           60
                        ppb  03
                                                             70

-------
             7
 ALTITUDE

[xlO3 ftMSL)
             0
                          40
50
                                                              T
                                                         T	1	1	1	1	r—i	r—i—i—i

                                                             75   80  85  90   95


                                                            TEMP  (°F)
   60
ppb  0,
                             \
                                                                     \
                                                                        \
                                                                          \
                                                                            \
                                                                              \
                                                                               1
                                                                               \
                Figure 110.   Vertical ozone and temperature  profiles NE of Putnam
                             (point  d) at 10:45 pm on August 2, 1975.
                                                6


                                                5
                                                3


                                                2
                                         188

-------
                     Figure 111.  Plot of aircraft data recorded during flight #26 on August 2, 1975.
       COND.
      NUCLEI
    (xlO3 part/ml)
00
10
      OZONE
        (ppb)
                60
                 2020     204O
                                                                       VISUAL
                                                                     DISTANCE
                                                                80      (km)
                                                                     RELATIVE
                                                                     HUMIDITY
2100     2120     2140     2200    2220     2240    2300     2320
                 FLIGHT  TIME

-------
 ,«•<_; v   ' ' .-1 A -ff >f^f- 11 DC"
 ! ^(. W   11/-4 Iv/ron/nt
                              J O  LAWRENCE
MASSACHUSETTS  69
                  (Spiral)^ I..
     WORCHESTER O
                  PROVIQENCEO '.
CONNECTICU
             54
                   'ISLAND
                                             r-JVINEYARD^J
                                             \I/^-        ^^
                                ATLANTIC    OCEAN
Figure 112.
               Flight #27 on August 3, 1975, with ozone concentrations  (ppb)
               marked at points along the route.
           TIME:   10:05 AM to 1:20 PM
            Leg
           WIND:
ab:
b:
be:
cd:
d:
de:
ea:
10:05 -
10:34 -
10:57 -
11:07 -
12:05 -
12:34 -
12:45 -
10:33
10:56
11:06
12:04
12:33
12:44
1:20
                                      at 1500'  MSL
                                      spiral ascent to 6000' and descent to 1000
                                      at 1500'
                                      counterclockwise
                                      spiral ascent to
                                      counterclockwise
                                      at 1500'
                                                  arc between 500' and
                                                  6000' and descent to
                                                  arc at 1500'
1500'
1500'
                     200° at 4 mph  (Groton)
                     080° at 7 mph  (Boston)
           WEATHER:  Hazy and hot
                                 190

-------
           9  h


           8


           7
ALTITUDE

(xlO3 ftMSL)
            3


            2


            I


            0
                          T
      Figure 113

Vertical  sounding  NE of
Putnam (point b) at 10:45 am
on August 3, 1975.
      i  i  i  i   i—i—i—i—|—i—|—|—|
         65   70  75   80  85   90  _

            TEMP  (°F)
 ALTITUDE
     ft MSL )
            I


            0
                          40
                    50
                                                           \
                                           \
                                             \
                                                                 \
                                                                   \
                                                                     \
                                                      \
                                                       r

                                                       \
                         9


                         8
                                       6


                                       5


                                       4


                                       3


                                       2
  60
ppb 03
                                                  r  i  i   i  r  i  i   r  i  i  T  i  \  i
                                                        65   70   75  80   85  90
                                          TEMP  (°F)

                                          \

                                            \

                                              \

                                                \
                                                                    \
                                                                     \
                                                                      \
      Figure 114

Vertical sounding  SW of
Boston (point d) at 12:15 pm
on August 3, 1975.
                                                                        \
                                                                          \
                                       5


                                       4
                                        2


                                        I


                                        0
                          40
                    50
                                          191
  60
ppb  03
70
                                                                        80

-------
                 Figure 115.  Plot of aircraft  data recorded during  flight #27 on August 3, 1°75.
 COND.
NUCLEI
 «•
  part/ml)
            KD2O     IO4O      1IOO      H2O      II4O     I2OO
                                                FLIGHT   TIMP
I22O
1240
I30O
I32O
                                                                                                      RELATIVE
                                                                                                      HUMIDITY

-------
    KINGSTON O
                    o
CONNECTICUT    f
                                                        MASSACHUSET TS
                                                                 PUTNAM O  :
 NEW

 YORK
                                                     HARTFORD
               o:
                            O DANBURY
 NEW

 JERSEY
NEW YORK
                                       Ml DOLE TOWN
                                         §Q  ~
                                         54/LJ*
                                           kj* A-3?
                                         98   (Spiral)
                     84   75
VGROTON
  —"^/
  H,2^
  ' (Spiral)
                                                ATLANTIC

                                                     OCEAN
                                                                 Scale; I  = 21 mi.
   Figure 116.  Flight #28 on August 5, 1975, with ozone concentrations  (ppb)
              marked at points along the route.

              TIME:  12:50 PM to 2:55 PM

              Leg   ab:  12:50 - 1:10 angle ascent to 6000' MSL
                     b:   1:11 - 1:25 spiral  descent to 500'
                    be:   1:26-1:59 between 500' and 6000'
                     c:   2:00 - 2:14 spiral  descent to 500'
                    cd:   2:15 - 2:27 at 10001
                    da:   2:28 - 2:55 at 1000'

              WIND:  230° at  10 mph (Groton)

              WEATHER:  Partly cloudy and warm
                                   193

-------
 ALTITUDE

(xio3 ftMSL)
 ALTITUDE

(XIO3 ftMSL:
             3


             2
                         Figure  117

                   Vertical  sounding near
                   Groton (point b) at 1:20 pm
                   on August 5,  1975.
                         60  64   68   72  76   80   84

                                 TEMP (°F)
                30
50
70
                         Figure  118

                   Vertical  sounding near
                     New Haven (point c)
                     at 2:10 pm  on August
                     5, 1975.
                                                      \
                                                       \
                              \
                                \
                                                             \
                                                              \
                                                                \
                                                                  \
                                         \
                                           \
                                             \
                                                6


                                                5


                                                4


                                                3


                                                2
                                                                         \
                                                                           \
  90
ppb
                                                  I
                                   i
                                                  i—i—i—i—i—i—i—i—i—i—i—i—i—i
                                                    64  68   72  76   80   84  88
                                                            TEMP  (°F)
                                                     \
                                                      \
                                                       \
                                                        \
                               \
                                 \
                                                6


                                                5


                                                4
                                                            \
                                                             \
                                                               \

                                              \
                                                \
                                                  \

                                                     I
                50
60
70
                                           194
   80
ppb  03
90

-------
                    Figure 119.  Plot  of aircraft  data recorded during, flight #28 on August  5, 1975.
cn
     COND.

    NUCLEI
    i
     part/ml)
         200


          150



          100



           50


            0


           120



 OZONE    I0°

  (ppb)     80



           60


           40



            8



ALTITUDE   6

(xlO3 ftMSL)   4


            2
                           VISUAL

                          DISTANCE

                     80     (km)
                                                                                                     RELATIVE

                                                                                                     HUMIDITY
                        1300     S320     1340     1400     1420

                                                 FLIGHT  TIME
                                                                1440
1500

-------
            HAMPSHIRE
   MASSACHUSETTS
        WORCHESTER O
         PUTNAM
CONNECTIPU
       (2500) T
       (1500') 40

     (2000') 80
                                                   VINEYARD
                                   ATLANTIC   OCEAN
                                                                 Scale: I   = 21 mi.
  Figure 120.  Flight #29 on August 6, 1975, with  ozone concentrations  (ppb)
              marked at points along the route.
              TIME:   9:05 AM to 12:05 PM

               Leg   ab:   9:05 -  9:42 between 1500' and 2500' MSL
                     b:   9:43 - 10:00 spiral ascent to 5000' and descent to 1500'
                     be:  10:01 - 10:12 at 1500'
                     cd:  10:13 - 10:29 at 1500'
                     de:  10:30 - 10:43 at 1500'
                     e:  10:44 - 11:17 spiral ascent to 6000' and descent to 1500'
                     ef:  11:18 - 11:42 at 1500'
                     fa:  11:43 - 12:05 between 1500' and 3000'

              WIND:   040° at 15 mph (Groton)
                     050° at  8 mph (Boston)
              WEATHER:  Partly cloudy and warm
                                    196

-------
            8


            7
      Figure 121

Vertical  sounding  NE  of
Putnam (point b) at 9:50 am
on August 6, 1975.
                                                    i   i  i  i—i—i—i—i—i—i—i—i—i
                                                             58  62   66  70   74

                                                           TEMP  (°F)
                                                 8
ALTITUDE

(xlO3 ftMSL)
            3


            2
                                                 \
                                                                     \
                                                                      \
                                                                       V
                                                                       \
                                                                         \
                                                         \
                                                                           \
                                                                             \
                                                 6


                                                 5


                                                 4


                                                 3


                                                 2
               20
        30
40
  50
ppb 0,
60
                                                             T
                                                       I
            7


            6
        Figure 122

 Angle descent into Trumbull
 Airport (Groton) at ^12 noon
 on August 6, 1975.
                                                  I  I   I  I  I   I  I  I   1  I  I  I   I  I

                                                             64  68   72   76   80
 ALTITUDE

 (XlO3 ftMSL)
            3
                      TEMP  (°F)
                                                 6


                                                 5


                                                 4
               70
        80
90
   100
ppb  03
                                                             110
                                           197

-------
 ALTITUDE

(XIO3 ftMSL]
             8
                                                   T
                                                I
                20
40
60
                                                   i—i—i—i—T—i—i—i—r—r~~i   i—i—i
                                                         54   58  62   66   70   74


                                                             TEMP  (°F)
                                                   i
   80
ppb  0,
                                                              \
                                                                 \

                                                                         \
                                                                           \
                                                                            \
                                                                             \
                                                                           \
                                                                             \
                                                                              \
                                                             6


                                                             5


                                                             4


                                                             3


                                                             2


                                                             I
                 Figure  123.  Vertical  ozone and  temperature profiles NE of Providence
                             (point e) at 11:00  am on August 6, 1975.
                                           198

-------
                  Figure 124.  Plot of aircraft data recorded during flight #29 on August 6,  1975.
   COND.
  NUCLEI
(*K)3 part/ml)
  OZONE
    (ppb)
,20     VISUAL
     DISTANCE
80      (km)
     RELATIVE
     HUMIDITY
             0910     0930     0950     1010      1030     1050      1110      1130      1150     1210
                                                FLIGHT  TIME

-------
                                                          a

                                                         50 (4500*)
                                                      22  (I0001)
NEW   HAi\,PSHiKL
                             (35001 4
                               27

   MASSACHUSETTS    28
        WORCHESTER O
                      (3000) 39
         PUTNAM O  !<2500')36

                     PROVIDENCrfO
CONNECTICUT
                                   ATLANTIC    OCEAN
  Figure  125.  Flight #30 on August 6, 1975, with ozone concentrations  (ppb)
              marked at points along the route.
                             ) 4:45 PM

                             - 2:19 spiral ascent to 7500'  MSL
                             - 2:58 angle descent to 1500'  and climb to 3500'
                             -3:32 between 1500' and 3500'
                             - 3:56 spiral ascent to 6500'  and descent to 1000'
                             - 4:05 at 1500'
                             - 4:45 at 1500'
              WIND:  090°  at 7 mph  (Boston)

              WEATHER:  Cloudy with intermittent rain  showers
TIME:
Leg





2:00
b:
be:
cd:
d:
de:
ef:
PM t
2:05
2:20
2:59
3:33
3:57
4:06
                                   200

-------
           8


           7
           Figure 126

     Vertical sounding near
     Groton  (point b) at 2:15 pm
     on August 6, 1975.
ALTITUDE

(XIO3 ftMSL)
                o
            3


            2


            I


            0
               40
            7


            6
 ALTITUDE

(XIO3 ftMSL)
4
              60
     52  56   60   64  68   72  76

             TEMP  (°F)


       \
                                                      \
                                                         >
                                                            \
                                                    \
                                                                 ^
                                                                   \
                                                 9


                                                 8


                                                 7


                                                 6


                                                 5


                                                 4
                                                                     \
                                                            \
                                                              \
                                                                \
80
  100
ppb 0
                                                             r
                                                            T
                                                    ii  i   i  i  i   i  i  r  i  i  )  i

                                                       52   56   60  64   68   72
                                               TEMP (°F)
                                                                 \
                                                                   \
                                \
                                        6


                                        5


                                        4
                                                            \
                                          Figure  127

                                    Vertical  sounding ME of
                                    Boston (point d) at 3:45 pm
                                    on August 6,  1975.
                                                                         \
                                                                        /
                                                             •
                                                               ^
              20
             30
40
                                         201
   50
ppb  03
60

-------
                    Figure  128.  Plot of aircraft data recorded during flight #30 on August  6,  1975.
             200

     COND.   150
    NUCLEI
  (xlO3 part/ml)  '°°
ro
o
ro
    OZONE
     (ppb)
                I4OO      I42O      144O     I5OO     I52O     I54O
                                                   FLIGHT  TIME
I6OO
I62O
I64O
                                    VISUAL
                                  DISTANCE
                             80      (km)
I7OO
                                  RELATIVE
                                  HUMIDITY

-------
                                                       MASSAUHUSLt
KINGSTON O
                              CONNECT/CUT
         PUTNAM O
NEW

YORK
                                       MIDDLETOWN.—   -
                            O DANBURY
NEW

JERSEY
                                    (Spiral)
                                ISLAND
                                                     OCEAN
   Figure 129.  Flight #31 on August 9, 1975, with ozone concentrations (ppb)
              marked at points along the route.
              TIME:  11:40 AM to 2:00 PM
               Leg
ab:
b:
be:
c:
cd:
d:
de:
ea:
11:40
11:52
12:07
12:21
12:41
1:01
1:15
1:31
                            11:51 angle ascent to 6000'
                            12:06 spiral  descent to 500'
                            12:20 at 1000'
                            12:40 spiral  ascent to 6000'
                             1:00 between 500' and 1500'
                             1:14 spiral  ascent to 6000'
                             1:30 angle descent to 1000'
                             2:00 between 500' and 1500'
MSL
                                                         and descent to 1000'
              WIND:  310° at 10 mph  (Groton)

              WEATHER:  Sunny and warm
                                  203

-------
             8
 ALTITUDE

(xlO3 ftMSL)
             3


             2


             I


             0
                                                   "i
                                                        *->IMS»
        40
50
                                                ppb 0,
          Figure 131
    Vertical sounding over
      Long Island (point c)
      at  12:30 pm on August
      9,  1975.  0
                                                        I  I   I  i  I   I  1  I   I  I  I  I

                                                       60  64   68   72  76   80
                                      \
                      TEMP  (°F)
                                                               \
                                                                  \
                                                                    \
                                                                       \
                                                                        i

                                                                        \
        30
40
            50
                                          204
                                                 8


                                                 7


                                                 6


                                                 5


                                                 4


                                                 3


                                                 2
                                                 6


                                                 5


                                                 4
                                                                     2


                                                                     I


                                                                     0

-------
            8

            7
 ALTITUDE
(xlO3 ftMSL)
            3

            2
            0
                                                        T
                                                              T
                              T
                                    T
                                          T
                                                   i	1—i	r
                                                               i  r—i—i—i—r—i—i—
                                                      60   64   68   72   76   80

                                                             TEMP  (°F)
                                                   I
                          30
40
  50
ppb 0,
60
70
               Figure 132.  Vertical  ozone  and  temperature profiles over Atlantic
                            Ocean (point d)  at  1:05  pm on August 9, 1975.
                                                  8

                                                  7

                                                  6

                                                  5
                                                  3

                                                  2
                                         205

-------
                    Figure 133.   Plot  of aircraft data recorded during flight 131 on August 9, 1975.
ro
o
CTl
     COND.
    NUCLEI
      part/ml)
           160

           120

           80

           40

            0

           100

 OZONE   8°
   (ppb)     60

           40

           20

            8

ALTITUDE  6
(x!03 ftMSL)  4
            2
                              160
                              ,20     VISUAL
                                   DISTANCE
                              80      (km)
                              40
                          II4O      I2OO      I22O      I24O     I3OO
                                                    FLIGHT   TIME
I32O
                                                                             I34O
WOO

-------
                                                         MASSACHUSET TS
KINGSTON O
                              CONNECTICUT
PUTNAM O
                                        MIDDLETOWN rP^s -—
                            O DANBURY
NEW

JERSEY
                                          100 (4000')
                                         A'8'9    ATLANTIC
                                       d (Spiral)

                                                      OCEAN
   Figure 134.  Flight #32 on August 9, 1975, with ozone concentrations (ppb)
              marked at points along the route.


               TIME:  3:30 PM to 6:00 PM
                Leg
ab:
b:
be:
c:
cd:
d:
de:
ea:
3:30
3:47
4:03
4:19
4:43
5:01
5:14
5:36
                             3:46 angle ascent to 6000' MSL
                             4:02 spiral descent to  500'
                             4:18 at 1000'
                             4:42 spiral ascent to 6000' and  descent to  1000'
                             5:00 between 500' and 1500'
                             5:13 spiral ascent to 6000'
                             5:35 angle descent to 2000'
                             6:00 between 1000' and  2000'
               WIND:  250° at 13 mph (Groton)

               WEATHER:  Sunny and hot

                                   207

-------
             8
         Figure 135

   Vertical sounding over
   Madison  (point b) at
'   3:55  pm  on August 9, 1975,
 ALTITUDE

(XIO3  ftMSL)
             3


             2
                                                             T
                                              T
                                                     i—i—i—i—i—i—i—i—i   i  i  i   i
                                                    60  64   68   72  76   80   84

                                                            TEMP   (°F)
                                                            9


                                                            8
                40
             7


             6
 ALTITUDE

(XIO3 ftMSL)
50
                             /
                           /
                           \
                                                        \
                                                           \
                                                             \
                                                                \
                                                                  -*
                                          \
                                             \
                                                                          \
                                                                      6


                                                                      5


                                                                      4


                                                                      3


                                                                      2
                                                                            t
                      60
  70
ppb 0,
                                                     I  I  i   I  I  I
                                                                       I  I   I
                         60   64  68   72   76  80   84

                                 TEMP (°F)
                                                            6


                                                            5
                        Figure 136

                   Vertical sounding over
                   Long Island (point c)
                -  at 4:30 pm on August 9,
                   1975.
                                                            2


                                                            I


                                                            0
               30
40
                      50
                                          208
   60
ppb  03
70

-------
            8


            7
ALTITUDE

(xlO3 ftMSL)
               40
60
80
                                                              T
                                                T	r
                                                       60  64   68   72   76  80

                                                             TEMP  (°F)
  100
ppb
120
140
               Figure 137.   Vertical  ozone  and  temperature profiles over Atlantic
                            Ocean (point d)  at  5:10  pm on August 9, 1975.
                                                              9


                                                              8
                                                                                         I


                                                                                         0
                                          209

-------
                  Figure 138.  Plot of aircraft data recorded during flight  #32 on August 9, 1975.
   COND.
  NUCLEI
0
-------
    KINGSTON O
CONNECTICUT
                                                     o ,
         rf (Spiral
PUTNAM Cf A-2
      71
 NEW

 YORK
                                                       HARTFORD
                                          MIDDLETOWN
                cr
                             O DANBURY
                                                NEW HAVEN
 NEW

 JERSEY
NEW YORK CITY
                                       88* A-3
                                       /' f c (Spiral)
                                      8HGROTON
                                                                       '79
                           (Spiral) b
                                             RIVERHEADO'
                           LONG   ISLAND
                                  •112

                                 •100
                                                           A-l
                                                        (Spiral) a'


                                                   ATLANTIC

                                                        OCEAN
                                                                    Scale;  i = 21 mi.
   Figure  139.  Flight #33 on August 10, 1975,  with ozone concentrations (ppb)
               marked at points along the route.
               TIME:  11:10 AM to 2:00 PM

                Leg    a:  11:36 - 11:57 spiral descent from 7500'  to 500' MSL
                     ab:  11:58 - 12:07 at 1000'
                      b:  12:08 - 12:31 spiral ascent to 7500' and descent to  1000'
                     be:  12:32 - 12:43 between 500' and 1500'
                      c:  12:44 - 12:57 spiral ascent to 8000'
                      d:   1:15 -  1:32 spiral descent to 1500'
                     dc:   1:33 -  2:00 at 1500'

               WIND:  240° at 12 mph (Groton)

               WEATHER:  Sunny and hot

                                    211

-------
             8


             7
 ALTITUDE

(XIO3 ft MSL)
             3


             2
                                                  attwrCiv ,<
-------
           8


           7
ALTITUDE

(XIO3 ftMSL)
            3


            2
                                                             I     ••     I	«—
                                                    I   I  I—I—I—I—I—I—1—I—I—I—I
                                                   60   64   68  72   76  80   84
                                   \
                                                            TEMP  (°F)
                                     \

                                                       \
                                                         \
                                                            \
                                            \
                                              \
                                                                \
                                                                  \
                                                                   \
      Figure 142

Vertical sounding  near
Groton (point c) at  12:50
pm on August 10, 1975.
                                                                    i
                                \
                                   \
                                                                          \
                                        9


                                        8


                                        7


                                        6


                                        5


                                        4


                                        3


                                        2


                                        I


                                        0
              30
        50
70
  90
ppb 0,
            7


            6
 ALTITUDE
    ftMSL)
            3


            2
                                  >n  i   i  i  i  i   i  r i   i  i  i  T
                                 60\ 64   68   72   76   80  84


                                     \   TEMP  (°F)


                                         \


                                              \
                                                                \
                                                                  \
                                                  *

                                                  \
                                                                     4
                                                                    \

                                                                    \
                                Figure 143

                          Vertical sounding  near
                          Putnam (point d) at  1:25
                          pm on August 10, 1975.
                                                     \
                                    x
                                                                            \
                                                                             %
                                                                                %
               30
        50
70
                                          213
                                              ppb  03

-------
                  Figure 144.  Plot of  aircraft data recorded during flight  #33 on August 10,  1975.
  COND.
 NUCLEI
   part/ml)
 OZONE
   (ppb)
ALTITUDE
(xlO3 ftMSL)  4
            2
              II2O     II4O     I2OO     I22O      1240     1300
                                                FLIGHT  TIME
I32O
I34O
WOO
                              160
                              ,20    VISUAL
                                   DISTANCE
                              80      (km)
                              40

-------
                                    (Spiral) d

                                 PUTNAM
                                     A-6  9-72
                              CONNECTICUT
KINGSTON O
NEW

YORK
                                        MIDDLETOWN
                            O DANBURY
NEW

JERSEY
                                           RIVERHEADO
                                                ATLANTIC

                                                      OCEAN
   Figure 145.  Flight #34 on August 10, 1975, with ozone concentrations  (ppb)
              marked at points along  the route.
              TIME:  4:00 PM to 7:00 PM
               Leg
a:
ab:
b:
be:
c:
d:
dc:
4:32 -
4:55 -
5:07 -
5:25 -
5:41 -
6:07 -
6:23 -
4:54
5:06
5:24
5:40
5:53
6:22
7:00
54 spiral descent from 8500'  to 250'  MSL
                                   at 1000'
                                   spiral  ascent
               to
                                               5000'
                                between 500' and 1500'
                                spiral ascent to 9000'
                                spiral descent to 1500'
                                at 1500'
and  descent  to 100'
              WIND:  280°  at 5 mph  (Hampton)

              WEATHER:  Clear and warm
                                   215

-------
             8
 ALTITUDE

(XIO3 ftMSL)
             3


             2

                              T
                                                                  —,
                                                                          I
       Figure 146

Vertical  sounding over
 Atlantic (point a)
 at 4:45  pm on August
  10,  1975.
                                                  i—i—\—\—i—i—i—i—i—i—i—ii   i
                                                    60  64   68   72  76   80  84

                                                            TEMP   (°F)
                                              \
                                                 \
                                                   \
                                                      \
                                                        \
                                                           \
                                         \
                                           \
                                             \
                                                 9


                                                 8
                                                                   \
                                                                    \
                                                                      \
                                                 6


                                                 5


                                                 4


                                                 3


                                                 2


                                                 I


                                                 0
                50
      70
90
  no
130
150
                                               ppb
             7


             6
 ALTITUDE

(XIO3 ftMSL)
                                                              I
       Figure 147

Vertical  sounding over
Long Island  (point b)
at 5:15 pm on August 10,
1975.
                                                         I   I  I  T  1  I  I  I   1  I  1

                                                        64   68   72  76   80  84
                      TEMP  (°F)
                                                               \
                                                                \
                                             \
                                               \
                                                                    \
                                                6


                                                5
                                                                                      2


                                                                                      I
                50
       70
90
   110
ppb  03
130
150
                                            216

-------
           9  H


           8


           7
ALTITUDE

(XIO3 ftMSL)
            3


            2
            0
                                 I   I  I  I  1—I—I—I—I—I—1—I—I
                                60   64  68   72   76  80   84

                                        TEMP  (°F)
                             \
                               \
                                                    \
                                                      \
                                                        \
                                                          \
                                         \
                                           \
                                             \
                                                                \

                                                  \
      Figure 148

Vertical  sounding  near
Groton (point c) at  5:45
pm on August 10, 1975.
                                                    \
                                    \
                                     \
                                                                            \
                                                                              \
                                        8


                                        7


                                        6


                                        5


                                        4


                                        3


                                        2


                                        I
              50
       70
90
   110
ppb  0,
130
            7


            6
 ALTITUDE
    ftMSL)
                                60v  64   68  72   76  80   84

                                   \   TEMP (°F)
                                                       \
                                                          \
                                                            \
                                                              \
                                              \
                                                                   6


                                                                   5


                                                                   4
                                                                   \
                         Figure  149

                   Verticil sounding near
                   Putnam (point d) at
                   6:15  pm on August 10,
                   1975.
                                                       \
                                                          \    -
                                                            \
                                                              \
              30
       50
70
  90
ppb  03
                                           217

-------
                    Figure 150.  Plot of  aircraft data recorded during flight #34 on August  10,  1975.
INJ
CO
     COND.
    NUCLEI
      port/ml)
    OZONE
   ALTITUDE
   (xlO3 ftMSL)  4
                »6OO     I62O     I64O     I7OO      I72O      1740
                                                   FLIGHT  TIME
I80O
1820
1840
1900
                                    VISUAL
                                   DISTANCE
                                     (km)

-------
                                             MIDDLETOWN
                                                    NEW HAVEN
NEW YORK  CITY/
                             LONG    ISLAND
                                                                         Scale;  I  = 21 mi.
    Figure 151.
Flight #35 on August 11, 1975, with ozone  concentrations (ppb)
marked at points along the route.
                TIME:  9:20 AM to 12:15 PM
                 Leg
a:
ab:
b:
be:
c:
d:
dc:
9:47
10:05
10:19
10:43
11:01
11:28
11:51
                    10:04 spiral  descent from 8500'  to 500' MSL
                    10:18 at 1000'
                    10:42 spiral  ascent to  6000' and descent to 1000'
                    11:00 between 500'  and  1500'
                    11:14 spiral  ascent to  8000'
                    11:50 spiral  descent to 1500'
                    12:15 at 1500'
                WIND:  Calm (Groton)

                WEATHER:   Hazy and warm
                                         219

-------
             8


             7


             6
 ALTITUDE

(xIO3 ftMSL)
                                                  T
                                                                          r
            i—i—i—i—i—i—i—i  r-
           50   55   60  65   70
                                                                          i—i—i  i
                                                                         75  80
                                                    \
                      TEMP (°F)
                                                 9


                                                 8
                \
                 \
                   \
                    i

                    \
                                                            \
                       \
                         \
                           ^
                         Figure 152

                    Vertical sounding over
                      Atlantic (point a)
                      at  9:55 am on August
                      IT,  1975.
                                                                    \
                                                 6


                                                 5


                                                 4
                                \
                                 \
                                    \
                                      \
                                                                              \
                                                 2


                                                 I


                                                 0
                          45
55
           65
         ppb 0,
             7


             6
 ALTITUDE

(XIO3 ftMSL)
                                                                 j  i  I  I   r
              55  60   65   70  75   80   85

                      TEMP  (°F)
                                                         \
                                                           \
                                                             \
                                                               \
                           \
                             \
                                                 Figure 153
                                                                     \
                                 \
                                            Vertical sounding over
                                            Long Island  (point b)
                                            at 10:30 am  on August 11,
                                            1975.
                                   \
                                     \
                                       \
                                                 6


                                                 5


                                                 4


                                                 3


                                                 2


                                                 I
                           60
70
            80
                                         220
                                                    °

-------
           9  —
           8
ALTITUDE

(XIO3 ftMSL)
            3


            2
            0
                          40
                                                  T
                              -r
                                   T
                                T
             I  I  I   I  I	1	1	1	1	1	1	1	1

            55  59   63   67   71   75   79


                      TEMP  (°F)
                         \
                                                                •w
                                                                   \
                                                                     \
                                                                      •v
                                                                        V
                                    *
                                      \
                                                                             \
                                        9



                                        8


                                        7
                                        4



                                        3


                                        2
                                                                               \   _
60
  80
ppb  03
               Figure 154.  Vertical  ozone and temperature profiles near Groton
                            (point c) at 11:00 am  on August 115 1975.
                                                  0
                                         221

-------
 ALTITUDE

(xlO3 ftMSL)
6


5
             3


             2
             0
                                                  T
                                                 T
                          40
                                                   I  I   I  I  I   I  I  1   I  I  I   I  I  I

                                                    55   60  65   70   75   80  85
                                                             TEMP  (°F)
                         50
  60
ppb
                Figure 155.  Vertical ozone and  temperature profiles near  Putnam
                            (point d) at 11:40  am on August 11, 1975.
                                        8


                                        7


                                        6


                                        5


                                        4
                                        222

-------
                    Figure  156.  Plot of aircraft data recorded during flight #35 on August  11, 1975.
PO
ro
CO
      COND.

     NUCLEI
     •»
      part/ml)
          80



          60



          40



          20



           0



          100




OZONE    8°


 (ppb)     60



          40



          20



           8
    ALTITUDE

    (x!03  ftMSL)   4


                2
               \0
0920
                        0940
                             1000
1020
 1040      1100


FLIGHT   TIME
120
1140
1200
                                                        160


                                                        I20     VISUAL

                                                             DISTANCE

                                                        80      (km)


                                                        40
1220

-------
    NEW   HAMPSHIRE
                                    _          «\\    70
                                    O  LAWRENCE?^
                                     60    ~~ _
                                                      'GLOUC HESTER
                                                      75
   MASSACHUSETTS
CONNECTICUT
                                   ATLANTIC    OCEAN
                                                                Scale;  l" =21 mi.
  Figure 157.  Flight #36 on August 12, 1975, with ozone concentrations  (ppb)
              marked at points along the route.
              TIME:  9:25 AM to 12:35 PM

               Leg   ab:   9:25-10:21 between 1500' and 2500' MSL
                    be:  10:22 - 10:25 at 1500'
                    cc:  10:26 - 11:34 counterclockwise arc around Boston at 1500'
                    cd:  11:35 - 12:05 at 1500'
                     d:  12:06 - 12:24 spiral ascent to 10,000'
                    da:  12:25 - 12:35 angle descent to landing

              WIND:  010° at 5 mph (Groton)
                    120° at 5 mph (Boston)
              WEATHER:  Sunny and hot
                                     224

-------
ALTITUDE

xlO3 ftMSL)
           9   -
           8   -
           7   -
           6   -
5   -
           4   -
           3


           2
                  I  I  I   I  T  1  I	1	1	1	1	1

            45  \50  55   60   65  70   75
                                                                                    -  9
                                                  8


                                                  7


                                                  6


                                                  5


                                                  4


                                                  3


                                                  2
                                                                                    -   I
                         60
70
                                      80
                                    ppb  03
90
               Figure  158.  Vertical ozone and temperature profiles  near  Groton
                           (point d) at 12:15 pm on August 12, 1975.
                                          225

-------
                    Figure 159.  Plot of aircraft data  recorded during flight #36 on  August  12, 1975.
     COND.
    NUCLEI
      part/ml)
INJ
ro
cr>
    OZONE
     (ppb)
   ALTITUDE
  (xlO3 ftMSL)
               O93O    O95O     IOIO       I03O     IO5O      1110
                                                    FLIGHT  TIME
1130
1150
I2IO
1230

-------
                                                        MASSACHUSET TS
                                                                       GROTON
                                                                       (1500')
                              CONNECTICUT
NEW

JERSEY
(25001)
                                                                    (1500*)
                                                                130  (I0001)

                                                                A-2,3
                                                     185
                                                         170
                                                ATLANTIC

                                                      OCEAN
                                                                  Scale;  I = 21 mi.
   Figure 160.  Flight #37 on August 12, 1975, with ozone concentrations  (ppb)
              marked at points along the route.
              TIME:   3:15 PM to 5:05 PM

               Leg   ab:  3:15 - 3:32 between 1000' and 2500' MSL
                     b:  3:33-4:02 spiral ascent to 7500' and descent to 500'
                     be:  4:03 - 4:14 at 500'
                     c:  4:15-4:26 spiral ascent to 7000'
                     ca:  4:27 - 5:05 angle descent to landing

              WIND:   260° at 5 mph (Groton)

              WEATHER:  Sunny and warm
                                   227

-------
             8
 ALTITUDE

(xlO3 ftMSL)
             3


             2


             I


             0
                   o
     Figure  161

Vertical  sounding over
  Atlantic (point b)
  at 3:45 pm on August
  12, 1975.
                                                    55   60  65   70   75  80   85

                                                            TEMP  (°F)
                                                      \
                                                        \
                                                          \
                70
 ALTITUDE

(XlO3 ft MSL)
             0
               70
                                   \
                                      \
                                                                 \
                                                                  \
                                           \
                                               \
                                                 \
                                                   \
                                                 5


                                                 4


                                                 3


                                                 2
                                                     \    _
                                                JL
  90
no
  130
ppb 0,
150
  200 ppb
  at  250*
                             Figure  162

                        Vertical  sounding over
                          Atlantic (point c)
                          at 4:20 pm on August
                          12, 1975.
                                I     J     T     |      1

                                —r—i	1—i	1	1—r—i	1	1—i

                                60  65   70   75   80  85
                \    TEMP  (°F)
                  \
                    \
                      \
                        \
                          \
                             \
                                                              6


                                                              5


                                                              4
                                                                      »
                                                                       \
                                                                         \
                                                                            \
                                                                             \
                                                                              \
  110
150
                                          228
  190
ppb  03
230
270

-------
                      Figure 163.  Plot of aircraft data recorded during flight #37 on August  12, 1975.
ro
vo
                80
       COND.
      NUCLEI
    0
-------
     KINGSTON O
 NEW

 YORK
               CONNECTICUT
                                                        MASSACHUSETTS
PUTNAM O  :
                                                     HARTFORD
55
*r ' "
55
f
60

62

65

60
/i
58\60
LJuL
rn\\ flX"
 NEW
 JERSEY
NEW YORK CITY,
                                                ATLANTIC

                                                      OCEAN
                                                                  Scale; I1 = 21 mi.
   Figure 164.
Flight #38 on August 13, 1975, with ozone concentrations (ppb)
marked at points along the route.
                                                          and descent to 1000'
TIME:  9:00 AM to 12:20  PM

 Leg   ab:  9:00 -  9:40 .at 1500' MSL
        b:  9:41 - 10:12 spiral  ascent to 6000' and descent to 1000'
       be: 10:13 - 10:24 between 1500' and 2000'
       cd:  10:25 - 10:54 at 2000'
        d:  10:55 - 11:25 spiral ascent to 7000'
       de:  11:26 - 11:50 between 500' and 1500'
       ef:  11:51 - 12:02 at 1500'
       fa:  12:03 - 12:20 between 500' and 1500'

WIND:  020° at 5 mph (Groton)

WEATHER:  Sunny and warm

                    230

-------
                                                 T
                                          T
           8


           7
     Figure 165

Vertical  sounding SW  of
  Danbury (point b) at
  10:00 am on  August  13,
  1975.
                                                    I   I  I  I   I	1	1	1	1	1	1	1	]

                                                   54   58  62   66   70  74   78

                                                           TEMP  (°F)
                                        8


                                        7
ALTITUDE

(XlO3 ftMSL)
                                                                                      3


                                                                                      2
            7


            6
 ALTITUDE

(XIO3 ftMSL)
            3


            2


            I


            0
                         50
                   60
   70
ppb 0,
                                            80
                 o
      Figure 166
m
Vertical sounding SE of
   Hartford (point d) at
.   11:10 am on August 13,
   1975.
                   JL
                          iO
                         50
                   60
                                                             I
                                                  I—I—I	1—I—I—I	1—I—I	1—I—I—I
                                                   54   58  62   66  70   74   78
                                      \
           \TEMP  (°F)


             \
                                                              \
                                                                    6


                                                                    5
                                              \
                                                 \
                                                                      \
                                                      \
                                                         \
                                                           \
                                        3


                                        2
   70
ppb  03
                                         231

-------
                     Figure 167.  Plot of aircraft data recorded during flight  #38 on August 13,  1975.
      COND.

     NUCLEI

   (xK)3 port/ml)
ro
CO
ro
           80



           60


           40



           20


            0



           100



 OZONE   8°


   (ppb)     60



           40


           20



            8




ALTITUDE  6

(xlO3 ftMSL)  4


            2



            O
                    160


                    I20    VISUAL

                          DISTANCE

                    80     (km)


                    40
                                  O900     O92O     094O     IOOO


                                                    FLIGHT   TIME
                                                                   I02O
IO4O
IIOO

-------
                                              Figure 167.  Continued
ro
OJ
GO
     COND.
    NUCLEI
      port/ml)
     OZONE
      (ppb)    60
    ALTITUDE
    (xlO3 ftMSL)   4
                          1100      1120      1140     1200     1220
                                                   FLIGHT  TIME
I24O
                                    VISUAL
                                   DISTANCE
                              80      (km)

-------
^_ ^ sp L, i^-|^ra«fta^-' ^^. _JkHWKMKA-JlL  ^   4- .-_ . — «_- • -._-• ^ __^^_.	 ^! -Et'-i^,
                   (3 VORCHESTER

 MASSACHUSETTS
                                 BROCKTON O
        PUTNUM O   '
 CONNECTICUT
                                                 (1500')
                                                    (500")
                                                   65  (I!   .  ,
                                                      65  (2500)
                                        70 68 66  67 66
                                                         ,66  &500')
                              77  75 70
ATLANTIC
                                               OCEAN
                                       Scale
                                                                          = 21ml.
  Figure 168.  Flight #39 on August  13, 1975, with ozone concentrations  (ppb)
             marked at points along the route.
             TIME:  3:40 PM to 6:30 PM
              Leg
ab:
b:
be:
cd:
de:
ef:
fg;
g-
gh:
h:
3:40
4:01
4:16
4:31
4:42
4:49
5:05
5:21
5:41
6:11
- 4:00
- 4:15
- 4:30
- 4:41
- 4:48
- 5:04
- 5:20
- 5:40
- 6:10
- 6:30
        angle ascent to 8000' MSL
        spiral descent to  500'
        between 1500'  and  2500'
        at 1500'
        at 1500'
        between 300' and 1500'
        angle ascent to 6000'
        spiral descent to  1000'
        between 300' and 4000'
        spiral descent from 4000' to landing
             WIND:   220° at 10 mph  (Groton)
             WEATHER:  Sunny and  hot

-------
            8


            7



            6
ALTITUDE

(XIO3 ftMSL)
            3


            2
                    70
                                                             TEMP  (°F)
                   \
                     \
                      \
                        \
                          \
                                                            \
                                                                             \
                                                                               \
                                                                                \
80
90
100
110
120
                                                ppb
               Figure 169.  Vertical ozone and temperature profiles near Norwich
                            (point b) at 4:05 pm on August 13, 1975.
                                8


                                7


                                6


                                5


                                4


                                3


                                2


                                I


                                0
                                               235

-------
             9  -
 ALTITUDE

(XIO3 ftMSL)
                                                             T
                                                     T
                         Figure  170
                    Vertical  sounding over
                 Martha's  Vineyard (point g)
                 "at 5:30 pm on August 13, 1975.
                 —i	1—i—i	1	1	1—i  i   r  i
                  58  62   66   70   74  78


                     TEMP  (°F)
                                                                   9


                                                                   8
                                                               \
                                                                \
                                              \
                                                \
                                                                      \
                                                                        \
                                                                         ^
                                                                            \
                                                                              \
                                                                                \   .
                                                                                 1
                                                                                /
                                                6


                                                5


                                                4


                                                3


                                                2


                                                I


                                                0
                     60
            80
     100         120
         ppb  03
                    140
             7


             6
 ALTITUDE

(XIO3 ftMSL)
     Figure  171

Vertical  sounding near
Groton  (point  h) at 6:20
pm on August 13, 1975.
                                                   ii  i   i  i  i   i  i  i   i  i  i   i  i
                                                         64  68   72   76   80   84
                     TEMP  (°F)
                                                6


                                                5
                                                                   \
                                                                     N
                                                                       \
                                                                          \
                                                                            \
                                                                              \
                                                                                \
                60
       80
100
   120
ppb  03
236
140
160

-------
                    Figure 172.  Plot of aircraft data recorded during flight #39  on August 13, 1975.
tvs
CO
     COND.
    NUCLEI
      part/ml)
              80
                 1540     1600     1620     1640     1700     1720
                                                    FLIGHT  TIME
1740
1800
1820
                                    VISUAL
                                   DISTANCE
                              80      (km)
1840

-------
                                                       MASSACHUSET TS
               CONNECTICUT
    KINGSTON O
                   60   67  71   70   70   72   75  79
NEW
JERSEY
                                                ATLANTIC

                                                     OCEAN
   Figure 173.
Flight #40 on August  14, 1975, with  ozone concentrations (ppb)
marked at points along the route.
              TIME:  9:35 AM to 1:00 PM

               Leg   ab:   9:35 - 10:14 between 1000' and 2000'  MSL
                               10:50 spiral  ascent to 9000'  and descent to 1000'
                               11:03 at 1500'
                               11:28 at 2000'
                               12:02 spiral  ascent to 9000'  and descent to 1000'
                               12:27 between 500' and 1500'
                               12:40 at 1500'
                    fa:  12:41  -  1:00 between 500' and 1500'

              WIND:  260° at 15 mph (Groton)

              WEATHER:  Partly cloudy and warm
ab:
b:
be:
cd:
d:
de:
ef:
9:35
10:15
10:51
11:04
11:29
12:03
12:28

-------
                 "! ••aavEv&frv*-*;
                                     KSBM T
           8
ALTITUDE
(XIO3 ftMSL)
            3

            2

            I

            O
               60
 ALTITUDE
 (XIO3 ftMSL)
70
                                                   ~~lI   !  l—I—I—i—i—I—i—i	1—i
                                                    56   60  64   68   72   76  80
                          \
                                                             TEMP  (°F)
                                                     \
                                                  9

                                                  8
                                                       \
                                                        \
                                                          \
                                                           \
                                                             \
                                     \
                                      \
                                        \
                                                  6

                                                  5
                                                                   \
                                                                     \
                  Figure 174
             Vertical sounding SW of
               Danbury (point b)  at
               10:30 am on August 14,
               1975.
                                 \
                                 /
                                 \
                                    \
                                      \
3

2
                                       \
                                         \    -
80
                                               ppb  03
                                                   i\
                                                     \
                                                    56 \  60  64   68   72   76   80  _

                                                            TEMP  (°F)
                                                            \
                                                              \
                                                               \
                                                                *
                                                                 \
                                         \
                                           \
                                            Figure  175
                                       Vertical  sounding SE of
                                         Hartford (point d) at
                                         11:45 am on August 14,
                                         1975.
                                             \
                                                        \_
                                                  6

                                                  5

                                                  4

                                                  3

                                                  2

                                                   I
              50
60
70
                                               ppb  0,
                                          239

-------
                      Figure 176.  Plot of aircraft data  recorded during flight #40  on August 14, 1975.
       COND.

      NUCLEI

    OctO3 part/ml)
IN)
JS»
O
 VISUAL

DISTANCE

   (km)
                                   094O      IOOO      I02O      IO40      IIOO      1120

-------
                                              Figure 176.  Continued
     COND.
    NUCLEI
  OcKD3 part/ml)
ro
-F*
           80

           60

           40

           2Q

            0

           \20

 OZONE    I0°
   (ppb)     80

           60

           40

            8

ALTITUDE
(xlO3 ftMSL)  4
            2
160
12Q    VISUAL
     DISTANCE
80      (km)
40
                         \\20      1140      \200     \220     1240
                                                   FLIGHT  TIME
                                                                 1300

-------
                  O WORCHESTER

MASSACHUSETTS
       PUTNUM O
CONNECTICUT
                         86
                              95
                                   as  «io:   «
    a
                          ATLANTIC
OCEAN
                                                                     I  = 2! ml.
 Figure 177.  Flight #41 on August 14, 1975, with  ozone concentrations (ppb)
             marked at points along the  route.

            TIME:  3:45  PM to 6:45  PM

             Leg   ab:   3:45 - 4:15 angle ascent to 9000' MSL
                   b:   4:16 - 4:32 spiral  descent to  1000'
                  be:   4:33 - 5:12 at 1500'
                   c:   5:13-5:50 spiral  ascent to 7000' and descent  to 300'
                  cd:   5:51-6:20 between 300'  and 1500'
                  da:   6:21 - 6:45 at * 1000'

            WIND:  240°  at 12 mph  (Groton)

            WEATHER:  Sunny and hot
                                 242

-------
            8


            7
 ALTITUDE

(XIO3  ftMSL)
            3


            2
            Figure 178

       Vertical  sounding  near
         Norwich (point b)  at
         4:25 pm on August  14,
         1975.
                                                            TEMP  (°F)
                50
 ALTITUDE

' (XIO3 ftMSL)
             7


             6
             5   -
4  -
            3


            2


            I


            0
               50
             \
               \
                                                       \
                                                    \
                                           \
                                        8


                                        7


                                        6


                                        5


                                        4


                                        3


                                        2
             60
70
  80
ppb  03
90
                  Figure 179

             Vertical  sounding over
          Martha's Vi'neyard (point c)
          at 5:30 pm on  August 14, 1975.
                                                    60 \64  68   72  76   80   84  _
                 \(
                      TEMP  (°F)
                                                            \
                                                              \
                                                   \
                                                     \
                                                                    \
                                                          \
                                                            \
                                                 6


                                                 5


                                                 4


                                                 3
                                                                         150

-------
                  Figure 180.  Plot of aircraft data recorded during  flight #41 on August 14,  1975.
              80
     COND.
    NUCLEI
      part/ml)
ro
                16OO     I62O     I64O     I7OO

-------
                                                         MASSACHUSET TS
    KINGSTON O
         CONNECTICUT
                              5
                                                                   PUTNAM
 NEW

 YORK
                                                      HARTFORD
                                         MIDDLETOWN
                             O DANBURY
                                                 VGROTON
                                               NEW HAVEN
 NEW

 JERSEY
                                            RIVERHEADO(
                                                                 •47
NEW YORK  CITY/

     e

     78*'
                          LONG   ISLAND
                                         •45
                                         c (Spiral)
                               (Spiral)
       -67
           45'
            c>

          (90CO

            (50°)
            58
(Spiral^ 56
.{/
OCEAN
                                             Scale: I  = 21 mi.
   Figure 181.   Flight #42  on August  15, 1975, with ozone concentrations (ppb)
               marked at points along the route.
               TIME:  10:15 AM to 1:20 PM
                Leg
ab:
b:
be:
c:
cd:
d:
de:
10:15
10:43
11:18
11:35
11:59
12:15
12:44
           10:42 at 1500' MSL
           11:17 spiral ascent  to 9500' and descent to  2000'
           11:34 at 2000'
           11:58 spiral ascent  to 7500' and descent to  500'
           12:14 at ^ 1000'
           12:43 spiral ascent  to 8000' and descent to  1000'
            1:20 at 1000'
              WIND:  140° at 8 mph (JFK)

              WEATHER:  Sunny and warm

                                   245

-------
 ALTITUDE

(xio3 ft MSL;
             8
             7
             3


             2
                                                                             :4JUG*r«w
     Figure 182

Vertical  sounding south of
 Long Island (point b)  at
 10:50 am on August 15, 1975
             7


             6
 ALTITUDE

(XIO3 ft MSL)
                                                  i—rp—i—i—i—i—ii    '  '
                                                 50  64  58   62  66   70   74
                          40
                  60
  80
ppb  0,
                          30
                   50
   70
ppb  03
                                        9


                                        8


                                        7


                                        6


                                        5


                                        4


                                        3


                                        2


                                        I


                                        0
i ! , j 1— — y— | j

ft V
Q , , , \ ,
1 I '

1 	 ' '
y 54 58A 62 66 70 74
.X^ TEMP (°F)
o^X^ ^
^
I
c


~

- C

S~
1

—

\


1
^ Figure 183
Vertical sounding south of
» Long Island (point c) at
11:45 am on August 15, 1975.
, . 	 L 	 ^ 	 , , ,
\
\
\
\
\
\
-



7

6
5

4


3

2

1
0

-------
           8
ALTITUDE

(XIO3 ftMSL)
            3


            2
                          40
                                                        I  I  I   (	1	1	T	,	,	,	1	

                                                       54  58   62   66  70   74
                                                  _L
                                                             TEMP  (°F)
                                                           \
                                                            \
50          60
         ppb  0,
                                                              \
                                                               \
                                                                \
                            \
                                                                      \
                                   \
                                     \
                                                                             \
                                                  9


                                                  8
6


5


4


3


2
               Figure 184-  Vertical ozone and temperature  profiles SE of New York City
                            (point d) at 12:30 pm on August 15,  1975.
                                           247

-------
                     Figure 185.  Plot of aircraft data recorded during  flight #42 on August 15,  1975.
ro
•e*
oo
    OZONE


      (ppb)
    ALTITUDE


   (xlO3 ftMSL)
                IO2O      IO4O      IIOO      1120      II4O     I2OO


                                                    FLIGHT  THVIE
1220
1240
I3OO
I32O
                                                                                                            VISUAL


                                                                                                          DISTANCE

                                                                                                             (km)

-------
    KINGSTON O
 NEW

 YORK
 NEW*

 JERSEY



[NEW YORK  CITY/
    (I0001) 4(

      (400d) 47T
         (eooo1)
           (7500") 60
    CONNECTICUT    f(
                                                    .1   MASSACHUSETTS
                                                 /— **— IS     - - —
                                                     HARTFORD
                                        MIDDLETOWN
                                              NEW HAVEN
LONG    ISLAND
              "55
                                    58
RIVERHEADOV,

          "80 (3500')

       "69 (5000')

   "70 (700O')


'57  «&LANTIC


          OCEAN
     68
                   70
                           76
                                                                 PUTNAM
                                                                     .GROTON
                                              = 2! mi.
   Figure 186.  Flight #43 on August 15, 1975, with ozone concentrations
              marked at points along the route.
              TIME:  5:00 PM to 6:30 PM

               Leg  ab:  5:00 - 5:48 angle ascent to 9000' MSL
                    be:  5:49 - 5:59 at 9000'
                    cd:  6:00-6:30 descent to landing at Groton

              WIND:  250° at 7 mph (Groton)

              WEATHER:  Clear and warm
                                   249

-------
                   Figure 187.  Plot-of aircraft data recorded during flight #43 on August  15, 1975.
ro
ui
o
    OZONE

     (ppb)
   ALTITUDE

  (xlO3 ftMSL)  4


              2
                                 172O      I74O     I8OO     I82O


                                                   FLIGHT  TIME
I84O
                                                                                                   160


                                                                                                   ,20    VISUAL

                                                                                                        DISTANCE

                                                                                                   80     (km)



                                                                                                   40

-------
                                                         MASSACHUSET TS
    KINGSTON O
CONNECTICUT
                                                    ^ HARTFORD
                                                  59A  62
                                                 (Spiral) d
                                                   A-3,4
                                        MIDDLETOWN
                     60\A~'t2O DAN BURY
                          b (Spiral)
                              T
                              74  85  90
NEW

JERSEY
                                            RIVERHEAOO
                          LONG    ISLAND
                                                 ATLANTIC

                                                      OCEAN
                                                                  Scale;  I' = 21 mi.
  Figure 188.  Flight #44 on August 18, 1975,  with ozone concentrations  (ppb)
              marked at points along  the route.


              TIME:   10:35 AM to  1:30 PM

               Leg   ab:  10:35 - 11:09 at 3500' MSL
                     b:  11:10 - 11:45 spiral  ascent to  10,000' and descent to 2000'
                     be:  11:46 - 12:03 at 2000'
                     cd:  12:04 - 12:28 at 2000'
                     d:  12:29 -  1:02 spiral  ascent to  8000'  and descent to 1000'
                     de:   1:03 -  1:13 at 1500'
                     ea:   1:14 -  1:30

              WIND:   230° at  10 mph (Groton)

              WEATHER:  Partly cloudy and warm

                                   251

-------
 ALTITUDE

(XIO3 ftMSL)
           ^	|_nr_ir_--I	-r

            r^Vi—i	1	1	1—i	1	1	'—i	1  '
           46 ^ 50  54  58   62  66    70

                  I    TEMP  (°F)

                  \
                        Figure 189

                   Vertical  sounding SW of
                   Danbury (point b) at 11:25
                   am on August 18, 1975.
                                                          \
                                                           *

                                                            \
                          40
50
  60
ppb 0,
                                                              \
                          \
                            *
                                                                    \
                                                                       \
                                                                          \
                                       \
                                                                                      9


                                                                                      8


                                                                                      7
                                       5


                                       4
                                         \
                                            \
 ALTITUDE

(XIO3 ftMSL;
             0
                                                  \
                                                 50 \  54   58   62  66   70  74
                                             o
                        Figure  190

                   Vertical  sounding SE of
                   Hartford  (point d) at
                   12:45 pm  on  August 18,
                   1975.
                                                    \
                                                      \
                                                           TEMP (°F)
                                                         \
                                                           \
                          50
60
                                         252
   70
ppb  03
                                                             \
                          A
                          \
                            \
                               \
                                  \
                                     \
                                        \
                                           \.

-------
                   Figure 191.   Plot  of aircraft data recorded during flight #44  on August 18, 1975.
              160



      COND.   120

     NUCLEI
   0(10 part/ml)
               80
ro
en
oo
      OZONE


       (ppb)
     ALTITUDE


    (xlO3 ftMSL)   4
                                                                 160


                                                                 ,20    VISUAL

                                                                       DISTANCE

                                                                 80     (km)


                                                                 40
                 1040      1100
1120      1140     1200     1220


                 FLIGHT   TIME
1240
1300     1320
1340

-------
                                                      MASSACHUSETTS
                                                               PUTNAM O  ;
               CONNECTICUT
KINGSTON O
                                                                  aGROTON

                                                                     e (Spiral)
             O DANBURY
NEW
JERSEY
                                         RIVERHEADQ
                         LONG   ISLAND
                                              ATLANTIC

                                                    OCEAN
   Figure 192.
Flight #45 on August 18, 1975, with ozone concentrations (ppb)
marked at points along the route.
             TIME:  7:40 PM to 8:30 PM

              Leg  ab:  7:40 - 7:52 at 1500' MSL
                   be:  7:53-8:05 angle ascent to 7000'
                    c:  8:06 - 8:30 spiral descent to landing at Groton

             WIND:  260° at 8 mph (Groton)

             WEATHER:  Hazy and warm
                                  254

-------
           8   I-
ALTITUDE

|XI03 ftMSL)
            3


            2
           0
                          50
                                                             TEMP  (°F)
                                                   \
                                                    \
                                                     \
                                                      \
                  \
                   \
                                                           %


                                                           \
                                                             \
                                                                \
                            \
                               \
                                  \
                                                                           \
                                                  9



                                                  8
                                         6


                                         5


                                         4



                                         3



                                         2
                                                                             \
                                                                               \
60
   70
ppb  0,
               Figure 193.  Vertical ozone and temperature  profiles near Groton
                            (point c) at 8:15 pm on August  18, 1975.
                                          255

-------
                     Figure 194.   Plot of aircraft data recorded  during flight #45 on August 18,  1975.
    COND.

   NUCLEI

  6d03 part/ml)
ro
en
cr>
160



120



80



40



 0



80



60



40



20



 0



 8
  ALTITUDE

  (xlO3  ftMSL)   4


              2
   OZONE

     (ppb)
1940    2OOO     2O20


        FLIGHT  TIME
                                                                   204O
                                                        160


                                                        I20    VISUAL

                                                             DISTANCE

                                                        80     (km)



                                                        40

-------
                  O WORCHESTER

MASSACHUSETTS
        PUTNUM O
CONNECTICUT
         RHODE 44
                     ISLAND^
                             46
                                                51 (1500')

                                                37 (500')

                                                38 (I50d)
               43  (5001)

              WLANTIC

             37 {1500')
                                             OCEA
 Figure 195.
Flight #46 on August 19, 1975,  with ozone concentrations (ppb)
marked at points along the route.
            TIME:

             Leg
      10:00 AM to 1:20 PM
      ab:
      be:
       c:
      cd:
       d:
      de:
      ea:
10:00 - 10:20 between 500'  and 2500' MSL
10:21 - 11:08 between 500'  and 1500'
11-09 - 11:31 spiral ascent to 6000' and descent to 1000'
n!32 - 11:46 at 1500'
11-47 - 12:14 spiral ascent to 7000' and descent to 1500'
12:15 - 12:29 between 500'  and 1500'
12:30 -  1:20 between 500'  and 3000'
            WIND:
      330° at 15 mph (Groton)
            WEATHER:   Sunny and warm
                                  257

-------
9
8
7
6
ALTITUDE
3 5
(XIO ftMSL)
4

3

2
I
0
7
5
ALTITUDE
, 4
(XIO3 ft MSL)
3
2

1
0
-j- i f / , , -™---j— j-
i i i • i i i i i i i i i i i
Figure 196 46 50 54 58 62 66 70 _
Vertical sounding. NE of TEMP (°F)
- Providence (point c)
at 11 :20 am on August
19, 1975.
- -
S* \
S^ \
r \
of \
1° \
b \
\ \
V \
i 1 i 1 i L t. I _ L ™_J__™, •
30 40 50
ppb 03
I j 1 J i | T J r- ^ J
i i i i i i i i 1 I 1 1 I 1
Figure 197 y£ 46 50 54 58 62 66 70 _
Vertical sounding SW oC . TEMP (°F)
of Cape Cod (point d) V> \
at 11:55 am on August \ \
19, 1975. .SQ \
7 NXX
7° ^x
of X,
ol \^
o\
1 t • 1 1 1 , 1 , 1
40 50 60
                                                     9






                                                     8






                                                 -   7






                                                     6






                                                     5






                                                     4






                                                     3






                                                     2
                                                 _  -i







                                                    6






                                                    5






                                                 -  4
                                                 -  2
258
            °

-------
                 Figure 198.   Plot of aircraft data recorded during flight #46 on August  19,  1975.
   COND.
  NUCLEI
(xiO3 part/ml)
              80

              60

              40

              20

                0

en             100

     OZONE   80
      (ppb)     60

              40

              20

                3

    ALTITUDE   6
   (xlO3 ftMSL)   4

                2
              1010      1030      1050      1110       1130      1150
                                                  FLIGHT  TIME
                                                                       1210
1230
1250
1310

-------
                  O WORCHESTER

MASSACHUSETTS
        PUTNUM O   '

                    PROVIDENCE

CONNECTICUT     RHODE
                           •65 (1500')

                          -70 (5001)

                         48
                          ATLANTIC
                                OCEAN
                                                               Scale> i  = 21 mi
 Figure 199.
Flight #47 on August 19, 1975, with ozone concentrations  (ppb)
marked at points along the route.
TIME:
Leg






2:30
ab:
b:
be:
cd:
d:
de:
ea:
PM
2:
2:
2:
3:
3:
4:
4:
to '
30 -
37 -
47 -
33 -
50 -
14 -
27 -
5:15
2:36
2:46
3:32
3:49
4:13
4:26
5:15
                                  angle ascent to 5000' MSL
                                  spiral descent to  500'
                                  between 500' and 1500'
                                  at 1500'
                                  spiral ascent to 7000'
                                  between 500' and 1500'
                                  between 500' and 1500'
                                          and descent to 500'
            WIND:   250° at 15 mph (Groton)
                   320° at  8 mph (Boston)
            WEATHER:  Sunny and hot
                                   260

-------
           8


           7
ALTITUDE

(XIO3 ftMSL)
            3


            2
     Figure 200

Vertical sounding  near
Long Island (point b)
at 2:40 pm on August 19,
1975.
                                                  i  I  I	1—I	1—i	1	r
                                                           TEMP  (°F)
                                                                             i—i
7


6
 ALTITUDE

(XIO3 ftMSL)
                         65
                    O
                    o
                                       D
                   75
                                     85
                                   ppb  03
                                                 \
                                                    \
                                                       \
                                                  i      •     i      •      i
                                                  i—i	1	1	1	1—i	1	i—i—i  i  i   i
                                                 46 . 50  54  58   62   66   70
                                                           TEMP  (°F)
                                        \
                                          \
                        Figure 201

                   Vertical sounding near
                    Cape Cod  (point d) at
                    4:00 pm on August 19,
                    1975.
                                                    t
                                                    \
               50
        60
                          70
                                         261
   80
ppb  03
                                                                          8
                                                                          6


                                                                          5


                                                                          4


                                                                          3


                                                                          2
                                                                                      0
                                                                    6


                                                                    5

-------
                    Figure 202.  Plot of aircraft data recorded during  flight #47 on August 19,  1975,
             200

     COND.    150
    NUCLEI
  (xlO3 part/ml)   I0°
en
ro
    OZONE
      (ppb)
   ALTITUDE
   (xlO3  ftMSL)  4 -—
                         I44O     I5OO     I52O     I54O      I6OO      I62O      f64O      I7OO     I72O
                                                    FLIGHT  TIME

-------
                                                       MASSACHUSET TS
KINGSTON O
                             CONNECTICUT
                                                                PUTNAM
                                                 o.
NEW

YORK
                                                    HARTFORD
                                       MIDDLETOWN
                        O DANBURY
                                                                    .GROTON
                                             NE
                 *\
                        38
                                        \
                                                41
JERSEY    ' a 2000') 40"

                (3500')
NEW YORK  CITY
                               \
                                        42
                                -%9
                                              44
                                          ?HEADO
                    A-7
                     LONG\  ISC

                 (3500') 48
                                                    \
                      (3500') 50'
                 (300') 74-

             (2500')  45 ,jfA-8,9,IO,ll

        [35°0)'fi^^V (Spiral)
                                        \
                                                ATLANTIC

                                                     OCEAN
                                                                Scale;  I  = 21 mi.
   Figure 203.  Flight #48 on August 19, 1975, with ozone concentrations (ppb)
              marked at points along the route.

       TIME:   7:05 AM to 10:20 PM

        Leg    ab:  7:05-8:00 between  1500 and 5000' MSL
              be:  8:01  - 8:52 between  300 and 5000'
              cd:  8:53  - 9:20 at 1500'
               d:  9:21  - 9:39 spiral ascent to 4500'
              da:  9:40  -JO:20 between 500 and 3500'

       WIND:   300° at 10 mph (JFK)

       WEATHER:   Sunny and Warm
                                  263

-------
             8
 ALTITUDE

(XIO3 ftMSL)
             3


             2
    Figure  204

Angle ascent at start
of flight  (^7:30 pm)
on August  19, 1975.
                                                         i—i—i—i—i—i—i—i—i   i  i
                                                        50   54  58   62  66   70

                                                            TEMP  (°F)
                                                9


                                                8
                                                             \
                                           \
                                            \
                                                                   t
                                                                     \
                                                6


                                                5


                                                4
                                                                       *
                                                                       \
                                                      •
                                                       \
                                                         «
                                                          \   .
                                                  I
                 30
       40
50
  60
ppb 0,
             7


             6
 ALTITUDE

(XIO3 ftMSL)
  1      I     '     I
     Figure 205

Vertical sounding SE of
New York City (point d)
at 9:30 pm on August 19,
1975,
                                                  i — i — i — i — i — i — \
             56   60   64

                      TEMP  (°F)
                                                                  i   i—i—i—i—i—i
                                                                 68   72   76  80
                                                6


                                                5
                30
       40
                                          264

-------
                   Figure 206.  Plot of aircraft data recorded during flight #48 on August  19, 1975.
             160



     COND.   120

    NUCLEI
     -,         on
      part/ml)


              40
no
a>
on
    OZONE

      (ppb)
    ALTITUDE

   (xlO3 ftMSL)
 VISUAL

DISTANCE

   (km)
                1920     1940     2000    2020    2040      2100      2120     2140     2200    2220

                                                  FLIGHT  TIME

-------
   NEW  HAMPSHIRE
                                  -i
                                    40
J          &\
O LAWRENCE\L_
Jt*\           *
   MASSACHUSETTS
                              35
                 GLOUCHESTER

               54 (50d)

                 56 (1500*)

                 66
        WORCHESTER O
         PUTNAM
CONNECTICUT
          (IQPO1) 64V!
                                  ATLANTIC   OCEAN
                                                              Scale:  I  = 21 mi.
  Figure 207.  Flight #49 on August 20, 1975, with ozone concentrations (ppb)
              marked at points along  the route.
              TIME:  12:00 to 2:45 PM

               Leg   ab:  12:00 - 1:27 at 1500' MSL
                     b:   1:28 - 1:54 spiral  ascent to 7500'  and descent to 1500'
                    ba:   1:55 - 2:45 at 1500'

              WIND:  010° at 8 mph (Groton)
                    310° at 8 mph (Boston)

              WEATHER:  Sunny and warm
                                  266

-------

9

8
7
6
ALTITUDE
5
(XIO ftMSL)
4
3
2

I
n
\j


i •'.',-,.
36 42 48 54 60 66 72
TEMP (°F)
~
/ \
°C \
\o \
I \
/ x\
ol \
1° ^
i i | 1 i _i F I. A I *
30 40 50
ppb 03
Figure 208. Vertical ozone and temperature profiles NW of Boston
(point b) at 1:40 pm on August 20, 1975.

9

8
7
6
5
4
3
2

I
n
\f


267

-------
                    Figure 209.  Plot of  aircraft data recorded  during flight #49 on August  20/1975.
      COND.
     NUCLEI
   (xK)3 part/ml)
ro
cr>
oo
     OZONE
      (ppb)
    ALTITUDE
   (xlO3 ftMSL)   4
                2
                 I2OO      I22O      I24O      I3OO     I32O      1340
                                                    FLIGHT  TIME
1400
I42O
I44O
I5OO

-------
                 O WORCHESTER
MASSACHUSETTS
                              BROCKTON O
       PUTNUM O
                   PROVIDENCE O
                              ~
CONNECTICUT
RHODE
                    ISLAND^
                            40
                                           ,- 53
                                       %  \\
                                           OCEAN
 Figure 210.  Flight #50 on August 20, 1975, with ozone concentrations  (ppb)
            marked at points along the route.

    TIME:   4:15 to 7:05 PM

     Leg    ab:  4:15 - 4:25 angle ascent to 5000'  MSL
            b:  4:26-4:35 spiral descent to  500'
           be:  4:36-5:20 between 500 and 2000'
           cd:  5:21 - 5:38 at 1500'
            d:  5:39 - 6:13 spiral ascent to 7500' and descent to 500'
           da:  6:14 - 7:05 between 500 and 2500'

    WIND:   300° at 15 mph (Groton)

    WEATHER:  Sunny and warm
                                269

-------
             8


             7
 ALTITUDE

(XIO3 ftMSL)
             3


             2
             0
     Figure  211

Vertical  sounding  near
Long Island  (point b)
at 4:30 pm on  August 20,
1975.
                           55
                                                              T
                                                                         I •W'M'MUltKiXU*-' -- J
                                                      1	1	1	1	T	1	1	1  1   I  1  ~l  I

                                                    46   50   54  58   62   66   70


                                                             TEMP  (°F)
                   65
                                      \
                                                             \
                                                               \
                                                                  \
                                                 \
                                                    \
                                                       \
                                                                             \
   75
ppb 0,
                                        5


                                        4


                                        3


                                        2


                                        I


                                        0
 ALTITUDE

(XIO3 flMSL)
             0
                                                               I
                                                                           I
                                o
                                   o
                                                   i   i  i  i   i  i  i   i  i  i   ir  i  i
                                                    48   52   56   60  64   68  72
                                               \
                                                 \
                                         TEMP  (°F)
                                                   \
                                                     ^

                                                     \
                                                        \
                                           \
                                                                s.

                                                                 \
                              Figure 212        \

                         Vertical sounding near
                         Cape Cod (point d) at
                         6:00 pm on August 20,
                         1975.
                                                                    5


                                                                    4
                                                                             \
                                                                                \
                                                                          1"2S3T,'
                           40
                   50
                                          270
   60
ppb  03

-------
                   Figure 213.   Plot of aircraft data recorded during  flight #50 on August 20,  1975.
             160
     COND.   (20
    NUCLEI
      part/ml)
CO
    OZONE
      (ppb)
1600    1620
                                 !640     1700     1720      1740     1800     1820      1840      1900
                                                   FLIGHT  TIME

-------
   NEW  HAMPSHIRE
                                                     GLOUCHESTER
                                    O  LAWRENCE
                                    40      40
   MASSACHUSETTS
        WORCHESTER O
         PUTNAMO
                    PROVIDJ&CEO I
CONNECTICUT
                      'ISLAND
                                                 MARTHA'S,^
                                               ^VINEYARDS!
ATLANTIC
                                                 OCEAN
  Figure 214.  Flight #51 on August 21, 1975, with ozone concentrations (ppb)
              marked at points along the route.

      TIME:   9:10 to 11:50 AM

       Leg    ab:  9:10 - 9:39 at 1500' MSL
             be:  9:40 - 10:22 counterclockwise arc  at 1500  '
              c:  10:23 - 10:48 spiral ascent  to 6500' and descent  to 1000'
             cd:  10:49 - 11:24 at 1500'
             da:  11:25 - 11:50 at 1500'

      WIND:   Light and variable (Groton)
             300° at 5 mph (Boston)

      WEATHER:  Sunny and Warm
                                  272

-------

9

8
7
6
ALTITUDE
5
XIO ftMSL)
4

3

2
1
0

T- "-• I 	
46 50 54 58 62 66 70 _
TEMP (°F)
~ -
-
r '\
o
c
- (

0
o
-
—
\
\
\
o \^
x. _
\
\ -
\ -


9

8
7
6


4

3

2
1
O
30 40 50
ppb (X
Figure 215.  Vertical ozone and temperature profiles  NW of  Boston
             (point b) at 10:40 am on August 21, 1975.
                             273

-------
                   Figure 216.  Plot  of aircraft data recorded during flight #51 on August 21,  1975.
     COND.
    NUCLEI
   (x(03 part/ml)
ro
80

60

40

20

 0

80

60

40

20

 0

 8
   ALTITUDE
   (xlO3 ftMSL)  4

               2
    OZONE
      (ppb)
                O900    O920
094O      1000      1020      IO4O
                  FLIGHT  TIME
IIOO
1120
                                                                          II4O
                                                                                                 I20O

-------
                  O WORCHESTER

MASSACHUSETTS
CONNECTICUT
 Figure 217.  Flight #52 on August  21, 1975, with ozone concentrations (ppb)
             marked at points along the route.

     TIME:   2:40 to 4:55 PM

      Leg    ab:   2:40-3:03 between 300 and 2500'  MSL
             b:   3:04-3:09 spiral descent from 2500  to 500'
            be:   3:10 - 3:38 at 500'
             c:   3:39 - 3:53 spiral ascent  to 3500'  and descent to 300'
            cd:   3:54 - 4:03 at 500'
             d:   4:04 - 4:18 spiral ascent  to 4500'  and descent to 1500'
            de:   4:19 - 4:31  at 1500'
             e:   4:32 - 4:55 spiral ascent  to 4000'  and descent to landing

    WINDS:  220°  at  10 mph (Groton)

    WEATHER:  Partly cloudy and hot

                                  275

-------
             8


             7
 ALTITUDE

(XIO3 ftMSL)
             3


             2
             0
        Figure 218

   Vertical  sounding  over
     Atlantic (point  c)
     at 3:45 pm on August
     21, 1975.
                                                  T

                                                   r—i—i—\—i—i—i—i—i—i  i   i  '
                                                  58   60  62   64   66  68   70


                                                             TEMP  (°F)
                           100
                      120
  140
ppb  0,
                                        9


                                        8
                                                                       6


                                                                       5


                                                                       4
 ALTITUDE

(XIO3  ftMSL)
             0
                                                               T
                                                          l
        Figure 219

   Vertical sounding  near
Martha's Vineyard (point d)
•at 4:05 pm on August  21 , 1975.
                                                                   1	T	1	1	1	1	1

                                                    52   56   60  64   68   72  76


                                                             TEMP  (°F)
                           60
                      80
                                          \
                                           \
                                          276
   100
ppb  03
120
                                        5


                                        4
                                                                       2


                                                                       i


                                                                       0

-------
                                                 T
                                                             T
ALTITUDE

XIO3  ftMSL)
5  h
            3


            2
            0
              50
              60
70
                                                  r~3iiiiiiifii~i

                                                 60   62  64   66   68  70   72


                                                            TEMP  (°F)
  80
ppb
               Figure 220.   Vertical  ozone  and  temperature profiles near Groton
                              oint e) at 4:40 pm  on August 21, 1975.
                                                                                       8
                                           277

-------
                    Figure  221.  Plot of aircraft data recorded during flight #52 on August 21,  1975.
OO
         200

 COND.    150
NUCLEI
  part/ml)   '°°
          50

           0

         200

OZONE    I6°
  (ppb)     120

          80

          40

           8
   ALTITUDE
   (xlO  ftMSL)  4
               2
                                 1440      I50O     I52O
                                                        I54O     I6OO     I62O     1640
               6 -

-------
AIRCRAFT COLLECTED HYDROCARBON, HALOCARBON AND NO  DATA
                                                 /\
     Light hydrocarbon, halocarbon and NO  concentrations in aircraft
                                         /\
collected samples are listed in this section.  The data is reported  on
a daily basis beginning with the first flight—July 15.  Reference should
be made to the flight maps in the previous section for the exact sample
collection point.
NOTES ON TABLES:
     Light  hydrocarbon concentrations are reported as yg/m3.
     * = less  than  0.5 yg/m3  (0.8 ppb C).
     Blank  space  =  no data, either because the value obtained was
                    questionable or the measurement was not made.
     Times  are Eastern Daylight Time.
                                    279

-------
TABLE 74. LIGHT HYDROCARBON, FLUOROCARBON-11, CARBON TETRACHLORIDE
          AND NOX CONCENTRATIONS IN SAMPLES  COLLECTED BY AIRCRAFT
          ON JULY 15, 1975.
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane

Total yg/m3

CFC13  (ppt)
CCl^   (ppt)
NO     (ppb)
A-l
3.5
1.0
*
1.5
*
*
*
*
*
6
150
128
A-2
3.0
1.0
*
1.5
*
*
1.0
.5
*
7
160
116
A-3
3.0

*
1.5
1.0
1.0
4.0
1.5
1.0
13


KEY (see flight map)


A-I  Over Long Island at 6500'  (Point b - 4:04)
A-2  Over Long Island at 2300'  (4:27)
A-3  Over Long Island at 1000'  (4:37)
                                     280

-------
TABLE  75.  LIGHT HYDROCARBON, FLUOROCARBON-11, CARBON TETRACHLORIDE
            AND NOX CONCENTRATIONS IN SAMPLES COLLECTED BY AIRCRAFT
            ON JULY 18, 1975.


Ethane
Ethyl ene
Acetyl ene
Propane
Propene
i -Butane
n-Butane
i-Pentane
n-Pentane
Total yg/m










,3
CFC13 (ppt)
CC1,, (ppt)
A-l
4.0
2.0
*
2.0
*
1.0
1.5
1.5
1.0
13
155
128
NOX (ppb)
A-2
7.

7.
7.
2.
5.
11.
9.
5.
55


21
0

0
5
0
5
5
5
0
A-3
5.5
5.5
3.5
5.0
*
5.0
11.0 1
8.0
4.0
A-4
6.0

4.5
6.5
1.5
5.5
0.0
9.5
4.5
48 48



540
140

A-5
5

2
4
3
5
8
6
3
39
.0

.5
.5
.5
.0
.5
.5
.5

A-6
6.0

2.5
4.5
1.0
3.5
6.5
6.5
3.0
34
A-7 A-8
6.0 7.
5.
3.0 4.
4.5 6.
1.0 *
4.0 5.
7.5 10.
7.5 9.
4.0 3.
38 50
5
0
0
0

0
0
0
5

455

18

1

5

19
128
20

KEY (see flight map)
A-l Over
A-2 Over
A-3 Along
A-4 Along
A-5 Along
A-6 Along
A-7 Along
A-8 Over
Connecticut River
Connecticut River
Coast at
South Leg
West Leg
North Leg
East Leg
Groton at
500' (2:
at 2500
at 2500'
at 2500
at 2500'
1000' (5
at 7000'
at 500'
24)
1 (3:
(4:1
1 (4:

58)
1)
36)
(point
(point




b -
b -




1:
2:1




55)
7)






















(4:55)
:05)








                                      281

-------
TABLE  76.    LIGHT HYDROCARBON,  FLUOROCARBON-11 ,  CARBON TETRACHLORIDE
             AND NOX CONCENTRATIONS  IN  SAMPLES  COLLECTED  BY AIRCRAFT
             ON JULY 19,  1975.

A-l A-2 A-3
Ethane 3.5 3.5 4.5
Ethylene 1-0 3.0
Acetylene 1.0 1.5 2.0
Propane 2.0 3.5 4.5
Propene .5 1.5 *
i-Butane 1.0 2.5 4.0
n-Butane 2.0 5.0 8.0
i-Pentane 2.0 5.5 7.0
n-Pentane 1.5 2.5 3.5
Total yg/m3 15 26 37
CFC13 (ppt) 185 270
CCl^ (ppt) 128 128
NOX (ppb) 15
A-4
4.0
6.0
2.5
2.0
1.0
1.0
1.0
1.0
1,0
20


11
A-5
4.0

2.0
3.5
2.0
2.0
5.5
4.5
2.0
26


20
A-6 A-7
4.5 4.0
1.0 1.5
* 1.0
2.0 2.5
* *
* 1.5
.5 3.0
* 2.5
* 2.0
8 18
165 230
128 128

A-8 A-9
4.0 3.0
4.5
1.0 *
1.5 1.5
* *
1.0 *
2.0 1.0
3.0 1.0
1.0 .5
14 12


15

KEY (see flight map)
A-l Over Long Island at 1000' (point d -
A-2 Over Long, Island Sound at 1000' (11:
A-3 East of New Haven at 1500' (11:33)
A-4 Over Kingston at 8000' (point g - 12
A-5 Over Kingston at 1500' (12:33)
A-6 Northeast of Boston at 7500' (point
A-7 Northeast of Boston at 2000' (5:22)
A-8 Over Groton at 2000' (6:31)

11:1
28)

:19)

d - 5



6)




:06)




















A-9 Low Pass over Trumbull Airport (6:40)
                                     282

-------
 TABLE 77.  LIGHT  HYDROCARBON,  FLUOROCARBON-11, CARBON TETRACHLORIDE
            AND  NOX CONCENTRATIONS  IN SAMPLES  COLLECTED BY AIRCRAFT
            ON JULY 20,  1975.

Ethane
Ethyl ene
Acetyl ene
Propane
Propene
i -Butane
n-Butane
i-Pentane
n-Pentane
Total yg/m3
CFC13 (ppt)
CCl^ (ppt)
NO (ppb)
A-l
4.0

*
2.0
*
-.5
1.0
.5
*
8
160
128

A-2
3.0
.5
*
1.5
*
*
1.5
1.5
*
8
180
128

A-3
3.0
2.5
*
1.5
*
1.0
1.0
1.0
*
10

13
A-4
3.0
2.0
*
1.5
*
*
.5
*
*
7
150
116

A-5
4.5
1.0
*
2.5
*
*
1.0
.5
1.0
11
155
128

KEY (see flight map)

A-l  East of New Haven at 6000'  (point b - 3:29)
A-2  East of New Haven at 1000'  (3:44)
A-3  Over Groton at 5000' (4:20)
A-4  South of Groton at 9000' (7:59)
A-5  South of Groton at 2000' (8:25)
                                     283

-------
TABLE 78.  LIGHT HYDROCARBON, FLUOROCARBON-11 ,  CARBON TETRACHLORIDE
           AND NOX CONCENTRATIONS IN SAMPLES  COLLECTED BY AIRCRAFT
           ON JULY 21, 1975.
                       A-1    A-2   A-3   A-4    A-5    A-6    A-7    A-8   A-9
Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
i-Pentane
n-Pentane
Total yg/m3 1
CFC13 (ppt)
CCl^ (ppt)
N0x (ppb) 1
4.0 3
2.0 4
*
2.0 2
*
1 .0 1
1.0 1
1.0 1
* 1
1 15


5 17
.0
.0
*
.5
*
.0
.5
.5
.0

1
1

4.0
*
*
1.0
*
*
*
*
*
5 1
50 21
4.0
1.5
1.5
2.5
*
1.5
3.0
3.0
1.5
9
5
5.5
4.0
4.5
7.0
1.0
8.0
13.5
13.0
6.5
63

28 140


21
3
2
1
3
1
1
3
2
1
19


17
.0
.5
.0
.0
.0
.5
.0
.5
.5




5.0
3.0
1.5
3.0
1.0
2.0
4.5
4.0
2.5
27


16
5.0
1.0
1.0
3.0
*
2.0
4.0
3.5
2.0
22
230
150

5.
2.
4.
4.
*
4.
9.
8.
4.
41
435
140

0
0
0
5

5
0
0
0





KEY (see flight map)
A-1 Over Putnam at 6000'
A-2 Over Putnam at 2000'
A-3 Northeast of Boston
A-4 Northeast of Boston
A-5 Over Long Island at

(point
(11:52
at 6000
at 2000

b -
)
1 (1
1 (1

11:40)

2:55)
:08)
1000' (point b - 4
A-6 Over Long Island Sound at 1
000'
A-7 Southeast of Hartford at 1500'
A-8 Over Atlantic Ocean
A-9 Over Atlantic Ocean
at 1000
at 2000
(4:25)
(point
1 (point e
1 (5
:56)





:20)

d -
- 5:








5:09)
46)





























































                                    284

-------
 TABLE  79.   LIGHT  HYDROCARBON,  FLUOROCARBON-11 ,  CARBON TETRACHLORIDE
             AND  NOx  CONCENTRATIONS IN  SAMPLES  COLLECTED BY AIRCRAFT
             ON JULY  22,  1975.
                         A-l    A-2   A-3   A-4   A-5   A-6   A-7
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
i -Butane
n-Butane
i-Pentane
n-Pentane
Total yg/m3
CFC13 (ppt)
CC1H (ppt)
N0x (ppb)
KEY (see flight
A-l East of New
A-2 East of New
A-3 Over Groton
A-4 East of New
A-5 East of New
3.5 3.5
2.0 *
* *
2.0 1.5
* *
1.0 *
1.5 1.0
1.5 .5
1.0 *
13 7
185 155
140 128

map)
3.
5.
1.
3.
1.
3.
6.
5.
3.
32




Haven at 1000' (point
Haven at 6500' (9
at 1000' (9:13)
:00)

Haven at 7000' (point
Haven at 1200' (1
A-6 Over Atlantic Ocean at 1000'
:54)
0
5
5
0
0
0
0
5
0





d


c

4.
,
*
2.
*
*
1.
1.
•
10
145
128


- 8:


- 1:

0
5

0


5
5
5

1
1


44)


37)

4.
1.
1.
3.
*
1.
3.
3.
1.
18
95
28







0
0
5
0

5
0
0
5










5
5
2
3

3
5
5
2
33









.0
.5
.5
.0
.5
.0
.5
.0
.5










3
5
1
3
2
1
3
2
1
24









.5
.0
.5
.5
.0
.5
.0
.5
.5










(3:29)
__ • » — m ••• \
A-7  Over Long Island Sound at 1000' (3:45)
                                      285

-------
TABLE 80-   LIGHT HYDROCARBON, FLUOROCARBON-11 ,  CARBON  TETRACHLORIDE
           AND NOX CONCENTRATIONS  IN  SAMPLES  COLLECTED BY  AIRCRAFT
           ON JULY 23, 1975.
                       A-l    A-2    A-3    A-4   A-5   A-6   A-7   A-8
Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
i-Pentane
n-Pentane
Total ug/m3
CFC13 (ppt)
CClt, (ppt)
NOX (ppb)









1


1
3.5
5.0
*
1.0
*
*
*
*
*
0 1


6 1
3.

1.
2.
,
1.
2.
2.
1.
5


6
0

5
0
5
5
5
5
5




3


2
.0 4.
2.
.5 1.
.0 3.
0
0
0
0
.5 *
2
4
8
2
24



.5 2.
.5 4.
.5 4.
.5 3.
24
290
116

0
0
5
0




5.5
2.5
1.0
3.0
1.5
2.0
4.5
5.0
3.0
28


17
4.5

1.0
3.0
2.0
1.5
3.0
3.0
2.0
20


19
3.5 7
1.5 2
* 3
* 6
*
* 6
i.o n
* 10
* 4
6 51
138 419
116 243

.0
.5
.0
.0
*
.0
.5
.0
.5





KEY (see flight map)
A-l At top of
A-2 At bottom
A-3 At top of
A-4 At bottom
A-5 At top of
A-6 At bottom
A-7 Eastern ti
A-8 Eastern ti
Putnam spi
of Putnam
spiral NE
of spiral
Putnam spi
of Putnam
p of Long
p of Long
ral -
spiral
8000'
(point b -
- 2000
of Boston (
NE of
ral -
spiral
Island
Island
1 (point
point 3 -
Boston
5000'
(point
1
e
(point b -
- 500'
- 3500
- 2500
(point
b
' (point
1 (point
8:40)
b - 8:
0:17)

57)







- 10:35)
3:38)



- 3:51)
e - 4:
e - 4:
42)
51)




                                    286

-------
TABLE 81.  LIGHT HYDROCARBON, FLUOROCARBON-11 , CARBON TETRACHLORIDE
           AND NOX CONCENTRATIONS IN SAMPLES COLLECTED BY AIRCRAFT
           ON JULY 24, 1975.
                       A-l   A-2   A-3   A-4   A-5   A-6   A-7
Ethane
Ethyl ene
Acetyl ene
Propane
Propene
i- Butane
n-Butane
i-Pentane
n-Pentane
Total yg/m3
CFC13 (ppt)
CC1,, (ppt)
NOX (ppb)
KEY (see flight
A-l At bottom













map)
5.5
3.0
2.0
3.5
*
*
6.0
5.0
2.0
27
221
127


of spiral NE
A-2 At 055° radial on
7.0

5.5
6.5
1.5
7.5
18.0
16.5
9.5
72


18

3.5
8.5
*
2.0
*
*
1.5
*
1.0
17


13

of Putnam -
Boston arc
A-3 Over Groton at 4000' (1
A-4 At top of spiral NE of
A-5 At bottom of spiral NE
A-6 At 150° radial on
A-7 At 360° radial on
- 2000
4.
8.
*
2.
1.
*
1.
1.
1.
20


13

2000
1 (1
5
0

5
0

5
0
0





1
0
4.0
3.0
1.0
2.5
*
*
2,5
2.0
1.0
16
166
127


(point
:55)
2:20)
Putnam - 7000' (point b
of Putnam - 1500' (point
Boston arc
Boston arc
- 1500
- 1500
1 (3
1 (4
*
*
36)
_ ^ \
09)
4

1
4
5
1
2
2
2
23




b

- 2
b


.0

.0
.5
.0
.0
.5
.5
.0





- 10

:53)
- 3:


5.
6.
1.
4.
1.
1.
3.
3.
2.
28


16

0
0
5
5
0
5
0
0
0





:07)

11)






                                     287

-------
 TABLE 82.  LIGHT HYDROCARBON, FLUOROCARBON-11 , CARBON TETRACHLORIDE
            AND NOX CONCENTRATIONS IN SAMPLES COLLECTED BY AIRCRAFT
            ON JULY 26, 1975.
                       _A-1   A-2   A-3   A-4   A-5   A-6   A-7

Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane

Total yg/m3            10    11      7    21      8    19     10

CFC13  (ppt)                      146   185    151
CCl^   (ppt)                      127   127    127
NOY    (ppb)           10     9                        67
  A
4.0
3.5
*
1.5
*
*
.5
*
*
4.0
3.5
*
1.5
*
*
1.0
1.0
*
4.0
*
*
1.5
1.0
*
*
*
*
4.5
4.5
1.0
2.0
*
1.5
3.0
3.0
1.5
4.0
1.0
*
1.5
*
*
*
1.0
*
4.0
3.5
1.0
2.5
1.5
1.0
2.0
2.0
1.5
4.0
2.0
*
2.0
*
*
1.0
1.0
*
KEY (see flight map)

A-l  At top of spiral NE of Putnam - 5000'  (point b  -  10:18)
A-2  At bottom of spiral NE of Putnam -  1500'  (point b -  10:29)
A-3  At top of spiral SE of Boston - 5500'  (point d  -  11:10)
A-4  At 090° radial  on Boston arc - 1500'  (point  e - 11:48)
A-5  At top of spiral NE of Putnam - 7000'  (point b  -  3:38)
A-6  At bottom of spiral NE of Putnam -  1500'  (point b -  3:53)
A-7  At top of spiral East of Boston - 7000'  (point  d  - 4:44)
                                     288

-------
 TABLE 83.  LIGHT HYDROCARBON, FLUOROCARBON-11 , CARBON  TETRACHLORIDE
            AND NOX CONCENTRATIONS IN SAMPLES COLLECTED BY AIRCRAFT
            ON JULY 27, 1975.
                        A-l   A-2   A-3   A-4   A-5
                       wt

Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane

Total yg/m3            13     5    12    11    26

CFC13  (ppt)                138   148
ccv  (ppt)                116   104
NOV    (ppb)            6
3.5
4.0
*
2.0
1.5
*
1.0
.5
*
3.5
*
*
1.0
*
*
*
*
*
5.0
1.0
2.5
*
*
1.0
*
1.5
1.0
3.5
3.5
*
2.0
*
*
*
1.0
.5
9.0
6.0
1.5
2.0
.5
2.5
1.5
2.0
1.0
KEY (see flight map)

A-l  At top of spiral NE of Putnam - 5000' (point b -  9:41)
A-2  At top of spiral West of Boston - 6000'  (point d  -  11:11)
A-3  At bottom of spiral West of Boston - 1500'  (point d  - 11:27)
A-4  At top of spiral NE of Putnam - 8000' (point b -  3:20)
A-5  At 090° radial on Boston arc - 1500' (4:16)
                                     289

-------
 TABLE 84.  LIGHT HYDROCARBON, FLUOROCARBON-11 ,  CARBON TETRACHLORIDE
            AND NOX CONCENTRATIONS IN SAMPLES COLLECTED BY AIRCRAFT
            ON JULY 28, 1975.
                        A-1    A-2   A-3   A-4

 Ethane                 6.5   6.0   3.0   7.5
 Ethylene               4.5   3.0    *    2.5
 Acetylene               3.0   3.0    *    4.0
 Propane                6.0   6.5   2.5   7.0
 Propene                1.5   1.0    *     *
 i-Butane               4.5   5.0    *     *
 n-Butane               8.5   9.0   1.5  12.0
 i-Pentane               8-5   7.5   1.0  10.0
 n-Pentane               3-5   4.0   1.0   5.0

 Total  yg/m3            47    45     9    48

 CFClo   (ppt)                      146   400
 CC1,3   (ppt)                      127   185
 NOV     (ppb)           11     'I
 KEY  (see  flight map)

A-l  Near Groton at 1500'  (3:04)
A-2  At bottom of spiral  SE of Hartford  -  1500'  (point  b  -  3:34)
A-3  At top of spiral  over Atlantic  Ocean  -  5000'  (point  d  -  4:36)
A-4  Over Long Island  at  ^2000'  (4:50)
                                     290

-------
 TABLE 85.  LIGHT HYDROCARBON, FLUOROCARBON-11 , CARBON TETRACHLORIDE
            AND NOx CONCENTRATIONS IN SAMPLES COLLECTED BY AIRCRAFT
            ON JULY 29, 1975.
                        A-l   A-2   A-3   A-4   A-5   A-6   A-7
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane
Total yg/m3

CFC13

NO..
        (ppt)
        (ppt)
        (ppb)
4.5
3.0
1.0
3.0
1.5
1.0
2.5
2.5
1.5
2


3.
2.
*
2.
*
*
1.
1.
1.
10


0
0

0


0
0
0



4
3
3
2
1
2
6
7
3
34
359
127
.5
.5
.0
.0
.0
.5
.5
.5
.5



3
1
2
1

1
1
1
1
13


.0
.5
.0
.0
*
.0
.5
.5
.0



3.5
*
*
1.5
*
*
1.0
1.5
1.0
9
135
116
4.
1.
1.
2.
*
1.
3.
2.
1.
17
187
116
0
5
0
0

5
5
0
5



4
2

1
1

1
1
2
14


.0
.5
*
.5
.0
.5
.5
.0
.0



10
11
KEY  (see flight map)

A-l  At bottom of spiral NE of Putnam - 1000' (point b -  10:06)
A-2  At top of spiral SE of Boston - 6000' (point d - 10:47)
A-3  At bottom of spiral SE of Boston - 1500' (point d -  11:00)
A-4  At 310° radial on Boston arc - 1500'  (11:35)
A-5  At top of spiral SE of Boston - 7000' (point d - 3:59)
A-6  At bottom of spiral SE of Boston - 500'  (point d - 4:15)
A-7  At 045° radial on Boston arc - 1500'  (4:31)
                                      291

-------
 TABLE 86.  LIGHT HYDROCARBON, FLUOROCARBON-11 , CARBON TETRACHLORIDE
            AND NOX CONCENTRATIONS IN SAMPLES COLLECTED BY AIRCRAFT
            ON JULY 30, 1975.
                        A-l    A-2   A-3
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane

Total yg/m3

CFC13  (ppt)
CC14   (ppt)
NO     (ppb)
4.5
*
*
2.0
*
.5
1.5
1.0
1.0
11
132
no
3.5
8
*
16.5
*
*
1.5
1.0
.5
23
142
110
3.5
.5
*
1.5
*
1.0
1.5
1.5
*
10
147
no
KEY (see flight map)

A-l  At top of spiral  NE of Putnam - 6000'  (point c  -  9:40)
A-2  At bottom of spiral NE of Putnam - 1500'  (point c -  9:50)
A-3  Southwest of Providence at 1500'  (10:20)
                                    292

-------
 TABLE  87.   LIGHT HYDROCARBON, FLUOROCARBON-11 , CARBON TETRACHLORIDE
            AND NOX CONCENTRATIONS IN SAMPLES COLLECTED BY  AIRCRAFT
            ON AUGUST 2, 1975.
                        A-l   A-2   A-3   A-4
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane
Total yg/m3

CFC13

NO..1*
        (ppt)
        (ppt)
        (ppb)
4.5
1.0
*
2.0
*
*
.5
*
*
5.0
1.5
1.0
3.5
*
3.0
4.5
14.5
1.5
4.0
*
*
1.5
*
*
1.0
*
*
*
*
2.5
7.5
2.0
3.5
8.5
12.0
5.5
                   8

                 138
                 106
 35

175
116
143
116
                                         42
KEY  (see flight map)
A-l  At top of spiral SW of Boston - 9000' (point d - 1:10)   (
A-2  At bottom of spiral SW of Boston - 1500' (point d - 1:40,
A_Q  A4- 4-r.n nf cnivai <;w nf Ro-ston - 7000' (point c - 10:00)
A-
A-4
At top of spiral SW of Boston - 7000' (point
At bottom of spiral SW of Boston - 1500' (point c - 10:18)
                                      293

-------
 TABLE 88.  LIGHT HYDROCARBON, FLUOROCARBON-11 ,  CARBON TETRACHLORIDE
            AND NOX CONCENTRATIONS IN SAMPLES  COLLECTED BY AIRCRAFT
            ON AUGUST 3, 1975.
                        A-l    A-2   A-3   A-4
 Ethane
 Ethylene
 Acetylene
 Propane
 Propene
 i-Butane
 n-Butane
 i-Pentane
 n-Pentane
Total yg/m3

CFC13

NO..
        (ppt)
        (ppt)
        (ppb)
4.
9.
1.
4.
5.
5.
4.
4.
2.
41


5
5
5
5
0
5
0
5
0



4
5
1
2
1
1
3
4
1
25


.5
.0
.0
.5
.5
.0
.5
.0
.5



4.
*
*
1.
*
1.
1.
1.
•
9
147
116
0


5

0
0
0
5



6
4
3
5

5
12
12
6
56
534
127
.5
.0
.5
.0
.5
.0
.5
.5
.5



KEY (see flight map)

A-l  At bottom of spiral  NE of Putnam - 1500'  (point b - 10:55)
A-2  At 080° radial  on Boston arc - 1500'  (11:40)
A-3  At top of spiral West of Boston - 6000'  (point d - 12:16)
A-4  Southwest of Boston at 1500' (12:48)
                                     294

-------
 TABLE  89.   LIGHT  HYDROCARBON, FLUOROCARBON-11,  CARBON TETRACHLORIDE
            AND  NOX CONCENTRATIONS IN SAMPLES COLLECTED  BY AIRCRAFT
            ON AUGUST 5, 1975.
                        A-l    A-2   A-3   A-4
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane

Total yg/m3
CFC1,
CC1,/
NO
(ppt)
(ppt)
(ppb)
4.5

1.0
2.5
1.0
1.0
2.5
6.0
1.0
20
5.0

2.0
4.0
1.5
2.5
5.5
5.5
3.0
29
3.5
2.5
*
2.0
*
*
1.0
*
1.0
10
4.5
3.5
1.5
2.5
*
1.5
3.5
3.0
2.0
22
135
127
213
127
KEY (see flight map)

A-l  At top of spiral near Groton - 6000' (point b -
A-2  At bottom of spiral near Groton - 500'  (point b - 1:26)
A-3  At top of spiral near New Haven - 6000' (point c - 2:00)
A-4  At bottom of spiral near New Haven - 500'  (point c - 2:lb)
                                      295

-------
TABLE 90.   LIGHT HYDROCARBON,  FLUOROCARBON-11,  CARBON TETRACHLORIDE
           AND NOX CONCENTRATIONS  IN  SAMPLES  COLLECTED  BY AIRCRAFT
           ON AUGUST 6, 1975.
                      A-l    A-2    A-3    A-4   A-5   A-6   A-7
Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
i-Pentane
n-Pentane
Total yg/m3
CFC13 (ppt)
CCH (ppt)
NOX (ppb)













5.0
4.5
1.0
4.5
4.5
2.0
4.5
4.5
2.5
33


8
2.5
1.0
*
1.5
*
*
1.5
*
1.0
8
140 1
127 1

3.5
1.0
1.5
2.5
*
1.5
3.5
3.5
1.5
19
40
27

5
5
2
4
2
3
7
7
4
43



.0
.0
.5
.5
.5
.5
.5
.5
.5




4.0
*
*
1.5
*
i *
1.0
1.0
*
8



4.
2.
1.
2.
*
1.
2.
2.
1.
16


6
0
0
0
5

0
5
0
0




4
2
1
3

1
2
2
1
17



.0
.0
.0
.0
.5
.0
.0
.0
.0





KEY (see fli
A-l At 170°
A-2 At 240°
A-3 At 240°
*"V
A-4 At 240
ght map)
radial on
radial on
radial on
radial on

inner
outer
outer
outer
A-5 Over Connecticut-Rhode

Boston
Boston
Boston
Boston
Island

arc -
arc -
arc -
arc -
border

1

500
6000
3300
1
500

1 (10:
1 (poi
1 (poi
1 (poi
- 5500' (2
A-6 Over Massachusetts-Rhode Island border -
A-7 Northeast of Boston at
3500'

20)
nt e
nt e
nt e
:25)


-
-
-



10
11
11



:57)
:10)
:15)

(2:48)
4300' (3:47)
                                   296

-------
 TABLE 91.  LIGHT HYDROCARBON,  FLUOROCARBON-11 , CARBON TETRACHLORIDE
            AND NOX CONCENTRATIONS  IN SAMPLES  COLLECTED BY AIRCRAFT
            ON AUGUST  9,  1975.
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane
Total pg/m3

CFC1

NO..^
        (PPt)
        (ppt)
        (ppb)
                        A-l   A-2   A-3   A-4   A-5   A-6   A-7   A-8   A-9
6.0
n.o
1.5
3.5
2.0
2.0
4.5
6.5
3.0
40
5.0
5.0
1.5
4.0
1.5
2.0
5.0
5.0
3.0
32
4.0
2.0
2.5
3.0
*
2.5
5.5
5.0
3.0
28
3.5
*
*
2.5
*
*
1.0
*
*
7
3.0
1.5
1.0
2.0
*
1.5
3.5
3.5
1.5
18
4.0
2.5
1.5
2.5
1.0
1.5
3.5
4.0
2.0
23
4.0
2.0
2.0
3.0
1.5
2.5
5.0
5.0
3.0
28
5.5
2.5
3.0
3.0
«.
4.0
8.5
8.5
4.0
39
3.5
*
*
1.5
*
8
*
*
*
5
220
116
122
108
173
108
349   122
116    99
KEY (see flight map)

A-l  At bottom of spiral Southeast of New Haven - 1000'  (point  b  - 12:03)
A-2  At bottom of spiral over Long Island - 1000' (point c  -  12:40)
A-3  At bottom of spiral over Atlantic Ocean - 1000'  (point d - 1:00)
A-4  At top of spiral over Atlantic Ocean - 6000' (point d  -  1:13)
A-5  Over Long Island at 1000'  (1:30)
A-6  At bottom of spiral Southeast of New Haven - 1000'  (point  o  - 4:03)
A-7  At bottom of spiral over Long Island - 1000' (point c  -  4:39)
A-8  At bottom of spiral over Atlantic Ocean - 1000'  (point d -5:00)
A-9  At top of spiral over Atlantic Ocean - 6000' (point d  -  5:13)
                                     297

-------
TABLE 92.   LIGHT HYDROCARBON,  FLUOROCARBON-11 ,  CARBON TETRACHLORIDE
           AND NOX CONCENTRATIONS  IN  SAMPLES  COLLECTED BY AIRCRAFT
           ON AUGUST 10,  1975.
                            A-2   A-3   A-4   A-5   A-6
Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
i-Pentane
n-Pentane
Total yg/m3
CFC13 (ppt)
CC14 (ppt)
NOX (ppb)









6
5
1
4
2
3
8
6
4
.5
.5
.5
.0
.0
.0
.0
.0
.0
41


1


1



5.5
3.5
1.5
4.5
1.5
2.5
5.0
4.0
2.0
6.0
2.0
1.0
3.5
*
2.0
4.0
3.5
2.0
30 24


8



11.
3.
7.
8.
2.
10.
19.
18.
7.
88
532
183

0
5
5
5
0
0
5
0
5




6.0
1.5
2.5
4.0

2.5
5.0
5.0
8.0
35
220
135

6.
3.
1.
4.
*
2.
4.
4.
2.
28



5
0
5
0

0
0
0
5


















KEY (see flight
A-l At bottom
A-2 At bottom
map)
of spiral
of spiral



A-3 Over Norwich at 1500
A-4 At bottom
A-5 At bottom
A-6 At bottom
of spiral
of spiral
of spiral




over
near


Atlantic
Putnam
' (point c
over
near
near
-
- 1
Atlantic
Groton
Putnam
-
-

Ocean
1500'
:52)
Ocean
1500'
1500'








- 1000
(point

- 1500
(point
(point


' (point a
d -

1:30)

' (point a
c -
d -
5:36)
6:25)

- 11:53)


- 4:55)


                                    298

-------
 TABLE  93.   LIGHT HYDROCARBON, FLUOROCARBON-11,  CARBON TETRACHLORIDE
            AND  NOX CONCENTRATIONS IN SAMPLES COLLECTED BY AIRCRAFT
            ON AUGUST 11, 1975.
                        A-l    A-2   A-3   A-4
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane
Total yg/m3

CFC13

NO.**
        ppt
       (ppt)
       (ppb)
5.0
3.0
1.5
4.5
1.5
2.0
4.5
3.5
2.5
7.5
4.5
2.5
5.5
1.5
3.5
8.0
8.5
4.0
4.5
*
1.0
2.5
*
1.5
*
2.5
1.5
5.5
1.5
1.5
4.0
*
2.5
4.0
3.5
2.0
                       28
46
 14

156
135
 25

190
135
KEY (see flight map)

A-1  At bottom of spiral over Atlantic Ocean - 1000'  (point  a  - 10:05)
A-2  At bottom of spiral over Long Island - 1000'  (point  b -10:40)
A-3  At bottom of spiral near Putnam - 1500'  point d -   1:48
A-4  At bottom of spiral near Groton - 1500' (point c -  I^:UJJ
                                      299

-------
 TABLE 94.  LIGHT HYDROCARBON, FLUOROCARBON-11 ,  CARBON TETRACHLORIDE
            AND NOX CONCENTRATIONS IN SAMPLES  COLLECTED BY AIRCRAFT
            ON AUGUST 12, 1975.
                        A-l    A-2   A-3
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane
Total yg/m3

CFC1

NO,."
       (ppt)
       (ppt)
       (ppb)
7.0
6.0
2.5
6.0
5.0
3.5
6.5
7.5
4.0
48
5.5
7.0
1.0
5.0
5.0
1.5
2.5
3.0
2.0
33
8.0
4.0
3.0
7.5
1.5
3.5
8.0
9.0
5.0
50
16    10
KEY (see flight map)

A-l  At 190° radial  on Boston arc - 1500'  (11:28)
A-2  Near top of spiral  over Atlantic Ocean - 6000'
A-3  At bottom of spiral over Atlantic Ocean - 500'
                             (point
                             (point
                                                               3:52)
                                                               4:03)
                                     300

-------
  TABLE  95.   LIGHT HYDROCARBON, FLUOROCARBON-11 , CARBON  TETRACHLORIDE
             AND NOX CONCENTRATIONS IN SAMPLES COLLECTED BY AIRCRAFT
             ON AUGUST 13, 1975.
                        A-l   A-2   A-3   A-4   A-5   A-6   A-7   A-8
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane
Total yg/m3

CFC13

NO..1*
       (ppt)
       (PPt)
       (ppb)
2.5
*
1.0
1.5
1.0
1.0
1.0
*
1.0
9
4.5
*
1.0
2.5
*
1.0
2.0
1.5
*
13
5
4
1
6
1
2
6
1
9
37
.5
.0
.5
.0
.0
.5
.0
.5
.0

5
2
1
3

1
2
3
1
20
.0
.0
.0
.0
.5
.5
.5
.0
.5

3.5
*
*
1.5
1.0
*
*
*
*
6
5
3
1
4
1
2
4
9
2
35
.5
.0
.5
.5
.5
.0
.5
.5
.5

4
6
1
2
2
1
2
5
2
28
.5
.0
.5
.5
.0
.5
.5
.0
.0

5.0
1.0
1.5
3.0
*
1.5
3.0
3.0
1.5
20
                 130
                 125
             144
             135
133
135
248
154
KEY (see flight map)
A-l
A-2
A-3
A-4
A-5
A-6
A-7
A-8
At top of
At bottom
At top of
At bottom
At top of
At bottom
At top of
At bottom
spiral Southwest of Danbury - 6000'  (point  b  - 9:53)
of spiral Southwest of Danbury - 1500'  (point b -  10:10)
spiral near Hartford - 7000'  (point  d -  11:05)
of spiral near Hartford - 1500'  (point d -  11:21)
spiral near Norwich - 8000' (point b - 3:57)
of spiral near Norwich - 1500' (point b  - 4:17)
spiral over Martha's Vineyard -  6000' (pomt_g - 5:20)
of spiral over Martha's Vineyard - 1000' (point g  -  5:40)
                                      301

-------
 TABLE 96.  LIGHT HYDROCARBON, FLUOROCARBON-11, CARBON TETRACHLORIDE
            AND NOX CONCENTRATIONS IN SAMPLES COLLECTED BY AIRCRAFT
            ON AUGUST 14, 1975.
                        A-l   A-2   A-3   A-4   A-5   A-6
 Ethane
 Ethylene
 Acetylene
 Propane
 Propene
 1-Butane
 n-Butane
 i-Pentane
 n-Pentane
Total yg/m3

CFC1

NO..1*
        (ppt)
        (ppt)
        (ppb)
6.
5.
1.
4.
1.
2.
4.
4.
2.
32
5
5
5
0
5
0
0
5
0

5
3
1
6
1
2
4
3
1
27
.0
.0
.0
.0
.0
.0
.0
.0
.5

4.
*
*
2.
*
*
*
*
1.
7
0


0




0

5.
1.
2.
5.
*
2.
5.
4.
3.
30
0
5
0
5

5
5
5
0

3
4

2
1
1
3
3
2
21
.5
.0
*
.5
.0
.5
.0
.5
.0

5
3
1
4
1
2
5
5
3
33
.5
.5
.0
.5
.5
.5
.0
.5
.5

133
124
191
124
KEY (see flight map)

A-l  At top of spiral  Southwest of Danbury - 9000'  (point b - 10:32)
A-2  At bottom of spiral  Southwest of Danbury -  1500'  (point b -  10:51)
A-3  At top of spiral  near Hartford - 9000'  (point  d  -  11:45)
A-4  At bottom of spiral  near Hartford - 1500'  (point d - 12:06)
A-5  At top of spiral  near Norwich - 9000' (point b - 4:15)
A-6  At bottom of spiral  near Norwich - 1500'  (point  b  - 4:38)
                                     302

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 TABLE  97.   LIGHT  HYDROCARBON, FLUOROCARBON-11,  CARBON TETRACHLORIDE
            AND  NOX  CONCENTRATIONS IN SAMPLES  COLLECTED BY AIRCRAFT
            ON AUGUST 15, 1975.
                        A-l   A-2   A-3   A-4
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane
Total  yg/m3

CFC1

NO..4
       (ppt)
       (ppt)
       (ppb)
3.5 4.0
* *
* *
1.5 2.0
* 2.5
* *
* *
.5 *
* *
6 9
133 137
116 124
3.0
*
*
1.5
*
*
1.0
1.0
*
7
133
124
3.5
1.5
1.5
2.5
*
1.5
4.0
3.5
2.0
20
205
134
KEY (see flight map)
A-l
A-2
A-3
A-4
     At bottom of spiral over Atlantic Ocean - 1500  (point  b  -  10:42)
     At top of spiral over Atlantic Ocean - 7000'   point  b - 11:05)
     Over Atlantic Ocean at 1000' (point c - 11:58
     Over Atlantic Ocean at 1000' (point d - 12:43)
                                      303

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 TABLE  98.   LIGHT  HYDROCARBON, CLUOROCARBON-11, CARBON TETRACHLORIDE
            AND  NOX CONCENTRA~IONS  IN SAMPLES COLLECTED BY AIRCRAFT
            ON AUGUST  18, 1975.
                       A-l   A-2   A-3   A-4   A-5   A-6
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane

Total yg/m3

CFC1
CC1
NO..
(ppt)
(ppt)
(ppb)
4.0
*
*
2.0
*
1.0
1 .0
1.0
*
5.0
1 .5
2.0
3.5
*
3.5
*
3.5
2.0
4.0
*
1.0
2.5
*
1.0
2.0
1.5
1.0
6.0
1.5
2.0
3.5
*
*
4.5
4.0
2.5
3.0
*
*
1.5
*
1.0
*
*
*
5.0
1.0
1.0
2.5
*
1.5
3.0
2.5
1.5
                 133
                 135
                             21

                            207
                            145
 13

168
135
 24

200
145
137
135
 18

165
135
KEY (see flight map)
A-l
A-2
A-3
A-4
A-5
A-6
    At top of spiral Southwest of Danbury - 10,000' (point b - 11:27)
    At bottom of spiral Southwest of Danbury - 2000' (point b - 11:49)
    At top of spiral near Hartford - 8000' (point d - 12:43)
       bottom of spiral near Hartford - 1500' (point d - 1:00)
At
At
At
top of spiral near Groton -
3500' in spiral near Groton
                                   7000' (point c - 8:04)
                                   (point c - 8:16)
                                     304

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 TABLE 99.  LIGHT HYDROCARBON, FLUOROCARBON-11, CARBON TETRACHLORIDE
            AND NOX CONCENTRATIONS IN SAMPLES COLLECTED BY  AIRCRAFT
            ON AUGUST 19, 1975.
                        A-1..A-2  A-3  A-4  A-5  A-6  A-7   A-8  A-9  A-10  A-ll
Ethane
Ethyl ene
Acetylene
Propane
Propene
i -Butane
n-Butane
i-Pentane
n-Pentane
Total ug/m3
CFC1, (ppt)
ccv (ppt)
NO (ppb)
3.0
1.0
*
2.0
*
1.5
*
2.0
1.0
11
141 1
124 1

3.5
1.0
*
2.0
*
1.0
2.0
1.5
1.0
12
38
i24

4.5
2.0
2.5
2.5
*
3.0
6.5
6.0
2.5
30
224
199

4.5
3.0
1.0
3.0
1.0
1.0
2.0
2.5
1.5
20


4.0
2.5
1.5
2.5
1.0
1.0
2.5
2.5
2.0
20
1
1

4.0
1.5
1.0
2.0
*
1.0
2.0
2.5
1.5
16
44 1
16 1

2.5
*
*
1.5
*
*
1,5
1.0
*
7
34 1
16 1

4
1
1
2

2
3
3
1
19
54
41

.0 3.0
.5 4.0
.0 2.5
.5 3.0
* 1.5
.0 7.0
.5 8.0
.0 9.0
.5 4.5
43
269
149

5.5
4.0
3.5
3.5
2.5
4.5
9.5
11.0
6.0
50
285
141

3.0
1.0
1.0
1.5
*
1.0
2.5
3.0
1.0
14
166
116
-

KEY (see flight map)

A-l  At bottom of spiral Northeast of Providence - 2000'  (point c - 11:29)
A-2  At bottom of spiral Southeast of Boston - 1500'  (point d - 12:14)
A-3  Over Ocean South of Martha's Vineyard - 500'  (12:36)
A-4  Northeast of Providence at 1500' (point c - 3:35)
A-5  At bottom of Cape Cod spiral - 1000' (point d -  4:11)
A-6  Over Long Island at 2000' (power plant plume - 7:40)
A-7  Over Long Island at 3500' (8:39)
A-8  Southeast of New York City at 500'  (9:23)
A-9  Southeast of New York City at 2000' (9:29
A-10 Southeast of New York City at 3000'  9:33
A-ll Southeast of New York City at 4500' (9:39)
                                     305

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 :-5.E 100.  LIGHT HYDROCARBON, FLUOROCARBON-11 ,  CARBON  TETRACHLORIDE
            AND NOX CONCENTRATIONS IN SAMPLES  COLLECTED BY  AIRCRAFT
            ON AUGUST 20, 1975.
                        A-l    A-2   A-3   A-4    A-5
Ethane
Ethylene
Acetylene
Propane
Propene
i-Butane
n-Butane
i-Pentane
n-Pentane

Total  ug/m3
ec
NO
(ppt)
(ppt)
(ppb)
3.0
1.5
2.0
3.5
*
4.5
8.0
7.0
4.5
4.0
1.5
1.0
2.0
1.0
1.0
1.0
1.5
1.0
3.5
1.5
*
1.5
*
*
1.0
1.0
1.0
5.0
3.5
*
3.0
3.0
1.0
1.5
2.0
1.0
1.5
2.5
1.5
3.0
1.5
1.5
2.5
4.0
2.5
 34

192
124
                      14
10
20
21
KEY (see flight map)

A-l  At 130° radial  on Boston arc - 1500'  (12:51)
A-2  At top of spiral  Northwest of Boston  -  7500'  (point  b  -  1:38)
A-3  At bottom of spiral  Northwest of Boston -  1500'  (point b -  1:52)
A-4  At top of spiral  North of Martha's  Vineyard  -  7500'  (point  d  - 5:50)
A-5  At bottom of spiral  North of Martha's Vineyard -  1000' (point d  - 6:12)
                                     306

-------
 1. REPORT NO.
   EPA-600/3-78-006
       TECHNICAL REPORT DATA
(Pease read Instructions on the reverse before completing)
 \2          ——	    I	
                               3. RECIPIENT'S ACCESSION NO.
      THE TRANSPORT  OF OXIDANT BEYOND URBAN  AREAS
      Light Hydrocarbon and Oxidanf Data
      New England Study,  1975
                               5. REPORT DATE
                                January 1978
                               6. PERFORMING ORGANIZATION CODE
      H.  Westberg, K.J.  Allwine and E.  Robinson
                                                            8. PERFORMING ORGANIZATION REPORT NO.
                          VIE AND ADDRESS
      Air Resources  Section
      Chemical Engineering Department
      Washington State  University
      Pullman, Washington  99164
                               10. PROGRAM ELEMENT NO.
                                 1AA603 AJ-05  (FY-77)
                               11. CONTRACT/GRANT NO.
                                 68-02-2239
 12. SPONSORING AGENCY NAME AND ADDRESS
      Environmental Sciences Research Laboratory - RTF, NC
      Office of Research and Development
      U.S. Environmental Protection Agency
      Research Triangle  Park, NC  27711
                               13. TYPE OF REPORT AND PERIOD COVERED
                                  Final
                               14. SPONSORING AGENCY CODE
                                  EPA/600/09
 15. SUPPLEMENTARY NOTES
 16. ABSTRACT
           During  the months of July and August,  1975, a comprehensive air pollution
      field monitoring program was conducted in southern New England.  Participants
      in the program included research  groups from Washington State University,
      Battelle Columbus Laboratories, EPA-Research Triangle Park, EPA-Las Vegas and
      EPA-Region I.   Oxidants, hydrocarbons, oxides of nitrogen and other gaseous
      pollutant species were measured at several  ground stations in Connecticut
      and Massachusetts.  The use of three  instrumented aircraft provided information
      concerning vertical dispersion and transport of pollutants.

           This report provides a tabulation of data collected by Washington State
      University.   It includes surface  data from  a field laboratory near Groton,
      Connecticut,  plus vertical pollutant  information obtained during daily aircraft
      sampling missions.
  7.
                                 KEY WORDS AND DOCUMENT ANALYSIS
                   DESCRIPTORS •
      *Air pollution
      *Ozone
      *Transport properties
       Chemical analysis
       Field tests
       Airplanes
 3. DISTRIBUTION STATEMENT


      RELEASE TO PUBLIC


 iiiiiiinjii] i   H*l "••J""?-VTjf^TrTSVtfl&yBZt^&^&XB
i EPA Form 3220-1 (9-73)
                                               b.lDENTIFIERS/OPEN ENDED TERMS
                      New England
                  19. SECURITY CLASS (This Report)
                     UNCLASSIFIED
                  20. SECURITY CLASS (Thispage)
                     UNCLASSIFIED
:. COSATI I-'icW/Croup

    13B
    07B
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21. NO. OF PAGES
    331
                                             22. i RICE

                                             307

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