EPA R2-73-198
MAY 1973                Environmental Protection Technology Series
Low  Water Volume Enzyme  Deactivation
of Vegetables Before  Preservation
                                 Office of Research and Monitoring

                                 U.S. Environmental Protection Agency

                                 Washington, D.C. 20460

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            RESEARCH REPORTING SERIES
Research reports of the  Office  of  Research  and
Monitoring,  Environmental Protection Agency, have
been grouped into five series.  These  five  broad
categories  were established to facilitate further
development  and  application   of   environmental
technology.   Elimination  of traditional grouping
was  consciously  planned  to  foster   technology
transfer   and  a  maximum  interface  in  related
fields.  The five series are:

   1.  Environmental Health Effects Research
   2.  Environmental Protection Technology
   3.  Ecological Research
   4.  Environmental Monitoring
   5.  Socioeconomic Environmental Studies

This report has been assigned to the ENVIRONMENTAL
PROTECTION   TECHNOLOGY   series.    This   series
describes   research   performed  to  develop  and
demonstrate   instrumentation,    equipment    and
methodology  -to  repair  or  prevent environmental
degradation from point and  non-point  sources  of
pollution.  This work provides the new or improved
technology  required for the control and treatment
of pollution sources to meet environmental quality
standards.

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                                                     EPA-R2-73-198
                                                     May 1973
   LOW WATER VOLUME ENZYME  DEACTIVATION
     OF VEGETABLES BEFORE PRESERVATION
                            by

                  Dr. Jack W. Rails
                 Mr. Walter A. Mercer

                   Project 12060  PAV
                     Project Officer
               Mr. Harold W. Thompson
Pacific Northwest Environmental Research Laboratory
                Corvallis, Oregon  97330
                      Prepared for

      OFFICE OF RESEARCH AND MONITORING
    U.S. ENVIRONMENTAL PROTECTION AGENCY
            -   WASHINGTON,  D.C.  20460
    For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402
               Price 90 cents domestic postpaid or 66 cents QPO Bookstore

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                             EPA Review Notice
This report has been reviewed by the Environmental Protection Agency
and approved for publication.  Approval does not signify that the con-
tents necessarily reflect the views and policies of the Environmental
Protection Agency, nor  does mention of trade names or commercial
products constitute endorsement or" recommendation for use.
                            -11-

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                         ABSTRACT
Four pilot-plant units were operated with asparagus, peas, corn,
beans, beets, pumpkin,  and spinach to establish the potential for
new blanching systems with low wastewater generation,  The
systems investigated were microwave, hot-gas, steam and hot-
water.

Single  runs of about one  hour duration were made for each commodity
with each blanching system.  Wastewater volume was measured  and
samples were analyzed for COD,  SS, and pH.   The most striking
result  obtained was the small volume of steam condensate  formed
during hot-gas blanching.

Canned samples of vegetable material from each blancher  were prepared
for quality evaluation after storage.  Taste panels showed  no  significant
flavor  preference for samples from any individual blanching system.  The
system used had no significant effect on the vitamin and mineral retention
of blanched or canned samples.  The oxygen content of  canned samples
was lowest for hot-gas blanching compared to the other three  systems.

Estimates of the cost of blanching using commercial-scale units  gave
(do liars/ton blanched):  microwave,  18. 47; hot-gas, 3.39; steam, 2.21;
and hot-water, 2. 36.

This report was submitted in fulfillment  of Project Number 12060 PAV
under the sponsorship of the Office of Research and Monitoring,  U.S.
Environmental Protection Agency and the National Canners Association,
Western Research Laboratory,  Berkeley, California.
                              -111-

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                          CONTENTS


Section                                                  Page

   I        Conclusions                                    1

  n        Recommendations                              3

  III       Introduction                                    5

  IV       Experimental Plan                             7
                Blanching                                 7
                Product Evaluation                       12
                Statistical Evaluation                     14
                Economics                               14

  V        Experimental Results                         17
                Blanching                                17
                Product Evaluation                       28
                Economics                               38

  VI       Discussion                                    41

  VII       Acknowledgements                            47

  VIII      Literature Cited                              49

  IX       Publications  and Patents                       5]

   X       Glossary                                     53

  XI       Appendices                                    57
                              -v-

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                        FIGURES







No.                                                     Page







  1     Percent of Total BOD Due to Blanching              5





  2     Microwave Blancher                                7




  3     Hot-Gas Blancher                                  8





  4     Hot-Water and/or Steam Blancher                  10





  5     Pilot Blancher Installation                         11
                              -vi-

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                        TABLES
No.                                                     Page
  1     Schedule of Analysis for Vitamins                  14
       and Minerals

  2     Long Term Blanching Runs for Green Asparagus     17

  3     Wastewater Volume and Characteristics             18
       for Green Asparagus Blanching

  4     Long Term Blanching Runs for Green Peas          19

  5     Wastewater Volume and Characteristics for         20
       Green Pea Blanching

  6     Long Term Blanching Runs for Cut Green Beans     21

  7     Wastewater Volume and Characteristics  for         21
       Cut Green Bean Blanching

  8     Long Term Blanching Runs for Corn-on-Cob        23

  9     Wastewater Volume and Characteristics for         23
       Corn-on-Cob Blanching

 10     Long Term Blanching Runs for Red Beets           24

 11     Wastewater Volume and Characteristics for         24
       Red Beet Blanching

 12     Long Term Blanching Runs for Pumpkin Pieces      25
                            -Vll-

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No.                                                    Page


13     Wastewater Volume and Characteristics for        26
       Pumpkin Piece Blanching

14     Long Term Blanching Huns for Spinach             27

15     Wastewater Volume and Characteristics for        27
       Spinach Blanching

16     Taste Panel Evaluation of Canned Samples After    28
       Storage for Six Months

17     Quality Scores for USDA Grading of Canned        30
       Vegetables

18     Headspace Gas Analysis  of Canned Vegetables      31
       Stored Six Months

19     Estimation of Extent of Internal Corrosion of       33
       Cans Used to Store Vegetables for Six Months
       at 65-85  °F

20     Vitamin Content of Raw,  Blanched, and Canned     36
       Vegetables

21     Mineral Content of Haw and Blanched Vegetables    37

22     Summary of Cost Estimates for Four Commercial   38
       Scale Blanching Systems

23     Comparison of Peroxidase Inactivation and          42
       Residence Times for Blanching of Vegetables

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No.                                                  Page
 24    Wastewater Generation During Vegetable         44
       Blanching

 25    Pounds of COD and SS Produced During           45
       Vegetable Blanching
                            -iX-

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                            SECTION I

                         CONCLUSIONS
1.  Two relatively new blanching systems, microwave and
    hot-gas, show promise for reducing enzymatic activity
    and removing occluded gases in asparagus,  peas,  beans,
    corn, beets, pumpkin and spinach.

2.  The use of microwave blanching of vegetables reduces the
    volume of wastewater formed substantially, but the capital
    costs are too high for a seasonal operation.

3.  A new method of blanching, now called "hot-gas blanching"
    shows exceptional promise in reducing wastewater volume
    to very low levels while providing commercially acceptable
    blanching.

4.  The flavor of hot-gas blanched vegetables, preserved by
    canning, was not significantly different from the flavor of
    samples prepared by microwave, steam and hot-water
    blanching.
                           -1-

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                               SECTION II
                           RECOMMENDATIONS
1.  Hot-gas blanching of major-use vegetables  should be investi-
    gated on an in-plant, continuous basis.

2.  The hot-gas blanched vegetables investigated on an in-plant,
    continuous basis should be returned to commercial production
    either mixed or unmixed with conventionally blanched material.

3.  The commercial product containing all or partially hot-gas
    blanched vegetable should be marketed in such a way that
    consumer reaction to the quality can be evaluated.

4.  The interest of all potential equipment suppliers should be
    encouraged so the design and production of  commercial-scale
    hot-gas blanchers will  move forward rapidly if in-plant trials
    are successful.
                             -3-

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                         SECTION

                       INTRODUCTION
 The heating of vegetables prior to terminal preservation by freez-
 ing, canning, or dehydration is an essential operation for satisfac-
 tory final product quality (1).  This  blanching treatment produces
 several desirable changes in the raw vegetables.  Primarily, en-
 zymes are thermally inactivated to stabilize the food components
 against rapid chemical changes.  Gases,  most importantly oxygen,
 are displaced from the food during blanching.  For several veg-
 tables,  the blanching step results in physical changes in the veg-
 table which improves subsequent operations  such as washing,
 peeling,  or filling into containers.  The blanching step may provide
 a useful removal of certain contaminants  on, or in,  the raw food.

 The disadvantages in vegetable blanching  using steam or hot-water
are loss  of nutrients and the formation of large  volumes of high-
 strength liquid wastes.  Surveys (2) of canneries have indicated
that an average of 40 percent of the total BOD in the liquid waste
from vegetable processing results from hot-water or steam blanch-
ing (Figure 1).
      ASPARAGUS
      BEANS,  SNAP
      BEETS  (&  PEELING)
      CORN
      PEAS
      PUMPKIN
      SPINACH
33
                      80
        50
             Figure 1.  Percent of Total BOD Due to Blanching
                            -5-

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New methods of blanching which generate lower volumes of liquid
wastes during vegetable processing would have obvious advantages
for environmental protection.

Blanching methods that minimize generation of liquid waste require
heat transfer media of controlled low water content.  Since vegeta-
bles are 70-92 percent water, the key to low wastewater blanching
is adequate heat transfer with minimal condensate from the water
in the vegetable or from injected steam,

The present practice of the vegetable preservation industry is to
use hot-water or steam blanching.  Relatively little research and
development effort has been devoted to new or modified blanching
systems which would reduce the volume of liquid waste generated.
Two recent innovations in vegetable blanching methods have promise
of substantial reductions  in wastewater volume.  However, neither
of these systems {jfluidized bed blanching (3) or IQB (4) ~]  appear to
have the potential for  almost complete elimination of wastewater.

Two methods of blanching which have potential for low wastewater
volume generation were chosen for a comparative study along with
hot-water and steam blanching.  One method, microwave blanching,
has had prior investigation with several vegetables:  corn-on-cob
(5, 6),  brussel sprouts (7) and potatoes (8).  None of these earlier
studies were as comprehensive as those planned in this current
study.  The  second blanching system proposed for this study was a
completely new method called hot-gas blanching which is based on
the direct use of hot natural gas combustion products as the major
heat source  for increasing the temperature of the vegetables being
blanched.

Therefore,  the objectives of this study were to compare the traditional
methods of vegetable blanching (hot-water or steam)  with a partially
evaluated (microwave) method and a new (hot-gas) method with the
expectation of demonstrating feasibility of a low waste-water volume
blanching system which gave adequate product quality and retention
of nutrients.  The four blanching systems studied were compared by
measuring operational factors, pollutional potential,  product quality,
and cost estimates.
                               -6-

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                               SECTION IV
                         EXPERIMENTAL PLAN
BLANCHING

To evaluate the potential usefulness of microwave and hot-gas
blanching of seven major vegetable commodities,  simulators of
possible commercial-scale units were operated in conjunction
with simulators of commercial hot-water and steam blanching
equipment.

The microwave unit used in this study was a Varian Model COS 5A
Microwave Conveyor shown schematically in Figure 2.  The specifi-
cations for the microwave blanching unit are tabulated in Appendix A.
   PRODUCT IN
PRODUCT OUT
                  Figure 2.  Microwave Blancher
                              -7-

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The hot-gas blanching unit was designed, at the request of the
National Canners Association,  by Magnuson Engineers, Inc. , and
fabricated by Heat and Control, Inc.  Outline  drawings .of the hot-gas
blancher are shown in Figure 3.
  PRODUCT OUT
                                           PRODUCT IN
 4"VENT

 ACCESS OPENINGS

 1" STEAM INLET
 7VzHP. 230/450 3PH. 60 Hz
        1755 RPM
                                  COMBUSTION AIR BLOWER
                               230/460 V. 3PH. SO Hz 500 WATTS
                                   193 Vz"
 V4 HP. O.C. CONVEYOR DRIVE.
 1ZOV. 60Hz A.C.ISKVAPOWER
 SUPPLY AT OPERATOR'S CONTROL/
 POWER UNIT.
7VzHR 330/460 3 PH. 60 Hz
    1755 RPM   /   	
            ^_.«	J J..,— -.,__
                                              1* STEAM INLET
COMBUSTION AIR BLOWER
Z30/460V.  3PH. 60Hz
   500 WATTS
                     Figure 3.   Hot-Gas Blancher
                                   -8-

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The specifications of the hot-gas blancher are shown in Appendix B.
The hot-gas blancher generates a mixture of hot nitrogen,  carbon
dioxide and water ( supplemented on occasion by injected steam )
which is blown past the vegetable pieces as they are conveyed through
the high temperature zone.  The temperature of the vegetable pieces
is raised by transfer of heat from the hot-gas mixture until a tem-
perature is achieved which will thermally inactivate enzymes and
drive off occluded gases.  At this point, the heated vegetables are
discharged to an ambient temperature zone and are conveyed to a
filling line for canning or to  a cooling line for frozen products.  If
sanitary conditions are maintained in the hot-gas blancher, no fur-
ther washing of the blanched product before  canning is required.

The steam and hot-water blanching was simulated in a single unit
which was the third stage of  the pilot washer provided to the National
Canners Association under U.S.  Atomic Energy Commission Contract
AT ( 04-3  ) -  536.  Line drawings for the steam and hot-water blancher
are shown in Figure 4.   The specifications for the steam and hot-
water blancher are listed in  Appendix C.   The commercial practice
of the vegetable preservation industry is to use hot-water or steam
for blanching.  Hot-water is an effective blanching medium due to
its exceptional heat transfer properties, its cleansing action on soiled
vegetables and its ease of temperature control.  Steam blanching is
used less frequently than hot-water  blanching, usually in those cases
where a quality factor ( taste, color, texture ) is  improved by the use
of steam.

Raw vegetables were donated by member canners and were transported
by refrigerated truck to the Berkeley Laboratory where the blanching
simulators were installed.  A series of short duration experiments
were conducted over  a range of operating conditions for each blanch-
ing-unit to determine good operating conditions.   The conditions selec-
ted for longer duration experiments were  based on weight changes,
product appearance and residual peroxidase levels.  The peroxidase
measurement involved measuring color generation over a period of
ten minutes.   The plot of time versus optical density gave a line whose
slope corresponded to residual peroxidase content (5).
                            -9-

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      DRIVE UNIT SUPPORTED
      FROM CONVEYOR CHASSIS.
      SEPARATE REMOVABLE
      COVERS.
                       VENT
                                                                      CO
PRODUCT IN
   2 HEADERS, SIDE BY SIDE, WATER,  STEAM
   PIVOT POINT FOR       \
    ONVtVOR CHASSIS        \
WHITE NEOPRENE
  CURTAINS
      v jjj	-   v .....       ><..e.k...r  I ^

          :     :    :    :    :    :     :    :    :   " :  V ..••'"  «  \ ,;*  "4   ..''5  +     ^
      ':•"••'	'	'	"	••-•     •  ,,...  »»....• . ^     m
                               PRODUCT OUT
                                                   ADJUSTABLE LEGS
                                                   THIS UNIT ONLY
                                        99'
                 Figure 4.   Hot-Water and/or Steam  Blancher
                                 -10-

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The unit indicated in Figure 4 was operated as a steam blancher by
passing steam into a spray h'ead manifold above the conveyor belt.
The unit was operated as a hot-water blancher by circulating a fixed
volume  of water held in the blancher tank through an automatically
controlled (  steam heated ) tubular heat exchanger.  A photograph of
the blanching units as they appeared during the pilot plant studies is
shown in Fi gure  5.
                MICROWAVE UNIT
STEAM/HOT-WATER UNIT
                                                             .
                                                  -GAS  UNIT
                                               *~

           Figure 5.  Pilot Blanching Installation
                           -11-

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During the long duration runs, wastewater samples were collected
from each of the  four blanchers.  The total effluent from the micro-
wave, hot-gas and steam blancher was mea'sured for volume and a
portion analyzed.  Four one quart samples of the total volume of
mixed liquid and  suspended solids were taken from the hot-water
blancher at 15 min intervals.  A final wastewater sample was taken
from the hot-water blancher tank at the end of each long duration
run for each of the vegetables studied.  All of the wastewater samples
collected were analyzed for COD,  SS and pH (9).
PRODUCT EVALUATION
Samples of blanched vegetables were prepared ( for example :
corn cutting,  beet peeling, pumpkin blending and screening) and
canned for later quality evaluation.  A total of five quality evalua-
tions ( taste,  grading, headspace gases, internal can corrosion,
and vitamin and mineral content) were made on each set of canned
vegetable samples.  Details  of these evaluations are presented below.

Taste  - Sets of samples of each  commodity ( except peas and spinach)
were presented to a laboratory taste panel consisting of about 16
tasters.   The presentation of samples in a random order was repeated
four times to obtain approximately 60 judgements.  The sets of four
different samples were presented in paper cups marked L, M,  N,
and O.  Each panelist was asked to rank the four samples after
tasting, with "4" denoting the worst flavor,  and  "1" the best flavor.
It was  requested that each sample be a given different ranking number
even if two or more samples tasted the same.  Therefore,  if four
identical samples were judged,  the cumulative average  score for a
large number of judgements  would be "2. 5. " A  scoring sheet used
to record the ranking of samples is  shown in Appendix D.

Grading  - A second evaluation of the canned samples was made by
experienced quality graders  from the U. S.  Department of Agriculture
Processed Fruit and Vegetable Inspection Division.  The samples
were shipped to Stockton, California from where they were distributed
by the  USDA to individual inspectors. This  quality grading developed
a number reflecting primarily the appearance of the  sample.
                             -12-

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Headspace Gases - Limitation of time did not permit a direct measure
of gas content of vegetables immediately after blanching.  An analysis
was made of headspace gas in cans representing each blanching var-
iable for each commodity.  The method used was^essentially that des-
cribed in the NCA Laboratory Manual for Food Canners and Processors
(10) with the modifications  listed in Appendix E.

Internal Can Corrosion - The fourth quality evaluation was made by
visual examination of 7-14  washed and dried empty cans from each
blanching variable for extent of internal corrosion.  The cans were
scored "411 if badly corroded, "3" if moderately corroded,  "2"  if
slightly corroded and "1" if without visible corrosion.

Vitamin and Mineral Content - The fifth quality measurement was  the
determination of the  level of vitamins and minerals in raw  and blanched
samples of each vegetable studied,  restricting the analysis to the nu-
tritionally significant components.  These determinations were made
according to the Eleventh Edition of the "Official Methods of Analysis
of the Association of Official Analytical Chemists" (11:).

The selection of vitamins and minerals for analysis was based on three
sources of data:

          a) Tabulations of vitamin and mineral content of raw
              and processed  vegetables (12,  13)
          b) Official tabulations of Recommended Daily Dietary
              Allowances (14)
          c) Per capita consumption of processed vegetables (15)

In general, a vitamin or mineral was included in the analytical  schedule
if a 100 g portion of  a specified  vegetable contained 10% or more of the
maximum recommended daily dietary allowance,  (MRDA).  In those cases
where all vitamins and minerals were below the 10% figure, a combination
of the percentage contribution to the MRDA  and the per capita consumption
were used to make the selection.

The vitamin and mineral testing schedule used in  this  study is tabulated
in Table 1.  Due to loss of samples or misunderstandings on the part of
analysts, this schedule was not followed rigorously.
                               -13-

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Table 1    Schedule of Analysis for Vitamins and Minerals
                       Vitamins
                Minerals
Commodity
Niacin   Ca   Mg   P  ' Fe
Asparagus
Green Beans
Beets
Corn
Peas
Pumpkin
Spinach
No
No
No
No
.No
Yes
Yes
Yes
Yes
No
Yes
Yes
No
No
Yes
Yes
Y3S
Yes
Yes
No
Yes
No
Yes
No
Yes
Yes
No
No
Yes
No
Yes
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
No
Yes
Yes
No
No
Yes
Yes
Yes
Yes
Yes
No
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
No
No
No
No
Yes
No
Yes
 STATISTICAL EVALUATION
 The results of product evaluations were subjected to analysis of
 variance to determine if there was a significant effect due to the
 the blanching condition used in the preparation of samples on which
 the measurement was made.  The analysis of variance was made
 using a randomized complete block design ( 16 ) with the vegetables
 involved in the analysis as blocks*and the blanching conditions as treat-
 ments.   When the variance ratio (F value) calculated exceeded the
 tabular F values at the 1 or 5 percent level of significance,  multiple
 range tests could be used to determine  significance due to individual
 blanching conditions for specific vegetables.
 ECONOMICS
 The cost of blanching using a new system such as microwave or
 hot-gas is a critical factor in any decision to replace currently used
 equipment.  Therefore, a serious attempt was made in this study to
 gather information on which to base cost estimates of commercial
 scale equipment for microwave, hot-gas, steam and hot-water blanch-
                              -14-

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ing.  The information on capital costs,  cooling water usage, make-up
water volumes, power consumption and space requirement were ob-
tained by suppliers or potential suppliers of commercial scale equip-
ment.  The operating  costs were estimated from power usage and
public utility fee schedules as well as general estimates of cost of
wastewater treatment.  The cost estimate was designed to represent
an unspecified commodity being blanched in a unit of approximately
5 tons/hr capacity.  The uncertainties of estimation made  the cost
estimate useful only as a rough screening of economic practicability
of a new blanching system before more extensive testing and collection
of cost factors were considered.
                             -15-

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                            SECTION V

                      EXPERIMENTAL RESULTS
 BLANCHING

 Asparagus - The green asparagms used in 1971 studies was obtained
 from Washington State in two spaced deliveries.  The stalks were
 trimmed by hand to five-in. lengths ( cutting off the butt ends ).  This
 asparagus was blanched in three of the four units; the hot-gas blanche r
 was not completely installed while fresh canning asparagus was available
 in 1971.  The  results of the short duration blanching experiments with
 asparagus are tabulated in Appendix F and include the results of ex-
 periments with hot-gas blanching conducted in Stockton, California in
 1972.   The results of long  duration blanching  of asparagus are tab-
 ulated in Table 2.
 Table 2  Long Term Blanching Runs for Green Asparagus

Run
No.
Blan-
ching
Unit
Feed
Rate,
Lb/Hr
Feed
Time,
Min
Resi-
dence
Time, Sec

Temp,
°F
Prod
Yield, %
Perox
Inact
Slope
Raw       -                     -         -               0. 17
ASP-38  5 kw   110    45       145      144   91        0.055
         Microwave  +
         Steam Injection
ASP-36  Steam  180    60       100      200   94        0.00
ASP-37  Hot-   120    60        90      180  104         .016
         Water
TLF-4   Hot-   500    60       131      265   91        0.00*
         Gas

*  The peroxidase inactivation slope for 1972 raw asparagus was 0.40.
                               17-

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Table 3 lists the wastewater volume and characteristics for green
asparagus blanching in the four experimental units.  The results of
analysis of grab samples taken from the hot-water blancher are tab-
ulated in Appendix G.
Table 3    Wastewater Volume and Characteristics for Green Asparagus
           Blanching
Run
No.
ASP-38


Blan-
ching
Unit
5 kw
Micro-
wave +
Waste
Water
Vol , Gal.
1.3



COD,
mg/1
3500



SS,
mg/1
44



PH
6. 8


Steam Injection
ASP-36
ASP -37
Steam
Hot -Water
4.3
100
2500
100
40
1
6.7
7.7
TL.F-4    Hot-Gas          0     No wastewater formed
Green Peas -  The green peas used for the blanching studies were Alaska
variety freezer peas taken from the flume between the third stage washer
and the hot water blancher at a commercial freezing plant.  The peas had
a temperature of 70 °F as they were loaded into a refrigerated truck for
transport to the NCA Berkeley Laboratory.  The peas in the lug boxes
located in the center of a stack of boxes in the truck did not lose heat
rapidly enough to avoid souring.  The bulk of the soured peas were sorted
out on receipt and only the better quality material used in the blanching
experiments.   The peas  used were of sufficient quality to provide useful
measurement of blanching effects except for organoleptic evaluation.

The results of the short duration experiments on blanching of green peas
are tabulated  in Appendix F.
                              -18-

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 The long term blanching experiments with green peas are summarized
 in Table 4.
 Table 4    Long Term Blanching Runs for Green Peas

Run
No.
Raw
P-17


P-13
P-3
P-6

Blan- Feed
ching Rate,
Unit Lb/Hr
— —
5 kw 220
Microwave +
Steam Injection
Hot-Gas 710
Steam 180
Hot- 210
Water
Feed
Time,
Min
.
54


46
55
58

Resi-
dence
Time, Sec

160(15)*
206(39)*

120
90
90


Temp
o
F

150


255
180
185

Prod
Yield, %

98


99
100
99

Perox
Inact
Slope
1.8
0.60


0. 14
0. 013
0. 043

*   Numbers in parentheses indicate feed time in minute's at listed
    residence time
The wastewater volume and characteristics for blanching of green peas
in four experimental units is tabulated in Table 5.
                             -19-

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Table 5     Wastewater Volume and Characteristics for Green Pea
            Blanching

Run
No.
P-17
Blan-
ching
Unit
5 kw
Waste -
Water
Vol , Gal.
4.25

COD,
mg/1
54,300

SS,
mg/1
630


PH
4.2
            Microwave +
            Steam
            Injection
P-13

P-3
P-6
Hot -Gas +
Steam
Injection
Steam
Hot -Water
0.005

4.0
100
™

41,000
3,920
*"

3,700
170
™

4.6
4.4
Green Beans - The green beans used in the short-duration blanching
runs were obtained at a cannery in Eugene, Oregon and transported to
Berkeley in an air conditioned station wagon.  The beans were pole
beans which had been snipped and size-graded.  The results of the short-
duration blanching runs for green beans are tabulated in Appendix F.

The green beans used for the longer-duration runs were obtained in
Junction City, Oregon and transported to Berkeley in two air-condi-
tion station wagons. The beans were cut bush beans of Number 3
sieve size.  The results for the long-term blanching experiments  with
green beans are tabulated in Table 6.
                              -20-

-------
Table 6    Long Term Blanching Runs  for  Cut Green Beans
Run
No.
Raw
BN-26

Blan-
ching
Unit
.
5kw
Microwave
Feed
Rate,
Lb/Hr


+ 120
Feed
Time,
Min


50
Resi-
dence
Time, Sec


206
Temp
F


130
,Prod
Perox
Inact
Yield,% Slope


92
4.8

0.53
Steam Injection
BN-25
Hot -Gas +
340
60
333
250
82
0.06
Steam Injection
BN-27
BN-28
Steam
Hot Water
190
120
56
60
217
291
190
190
94
98
0.07
0.06
The wastewater volumes and characteristics from long-term blanching
of green beans are tabulated in Table 7.
 Table 7    Wastewater Volume and Characteristics for Cut Green
            Bean Blanching
 Run
 No.
 BN-26
 BN-25

 BN-27
 BN-28
Blan-
ching
Unit
5 kw
Microwave +
Steam Injection

Hot-Gas +
Steam Injection
Steam
Hot Water
Waste-
water
Vol , Gal.
   2.4


   0.043

   4.25
    100
COD,
mg/1
1,500


  900

5,400
  330
SS,
mg/1
 46


 88

 100
   8
PH
6.5


7.7

6.1
7.3
                              -21-

-------
Corn -   The corn used in the blanching experiments was obtained
in Eugene, Oregon on September 8,  1971.  The corn was shipped to
Berkeley in the husks.  Commercial-scale corn husking and cutting
equipment was loaned to NCA by the Green Giant Company from their
plant in Belvidere, Illinois.

Corn was husked and a portion cut for blanching as cut kernels. In
the initial run of unwashed cut kernels through the hot-gas blancher,
about one fifth of the feed weight ( 95 Ib ) stuck on the wire mesh con-
veyor belt and caramelization of the starchy liquid adhering to the
corn kernels took place.   The product recovered from the belt weighted
77 Ib (  80% recover ).  The conveyor  belt was cleaned by hand brush-
ing of the moving belt ( at maximum speed setting ) with steam injec-
tion into the unit and a continuous water  spray on the belt at the product
discharge end.  The cleaning took 27 minutes  and used 34 gal of fresh
water.  The cleaning wastewater composite had a COD of 18, 000 mg/1
and a SS of 3,200 mg/1.

The lack of successful blanching of unwashed  cut kernel corn with the
hot-gas blancher made it necessary ( for comparative purposes ) to
run all four blanching units using corn-on-cob.  The blanched corn-on-
cob was cut for preparation of canned whole kernel corn samples.

The results of short-duration blanching runs on corn-on-cob in the
four experimental units are tabulated in Appendix F.

The results of longer-term blanching of  corn-on-cob in the four exper-
imental blanchers are tabulated in Table 8.
                             -22-

-------
Table 8
Long Term Blanching Runs for Corn-on-Cob
Run
No.
Raw
CN-14

CN-10
CN-15
CN-12
Blan- Feed
ching Rate ,
Unit Lb/Hr
mm mm
5 kw
Microwave + 160
Steam Injection
Hot -Gas + 360
Steam Injection
Steam 220
Hot-Water 230
Feed Resi-
Time f dence
Min Time, Sec
—

60
60
60
47
.

224
330
435
437
^
Perox
Temp,Prod Inact
F Yield, % Slope
—

130
260
195
190
.

95
98
98
96
0.

0.
0.
0.
0.
110

067
022
040
067
The wastewater volumes and characteristics for longer-term blanching
of corn-on-cob are tabulated in Table 9.
Table 9    Wastewater Volume and Characteristics for Corn-on-Cob
            Blanching
       Blan-
Run    ching
No.    Unit
                      Waste-
                      water
	Vol , Gal.

CN-14  5 kw            0.75
        Microwave +
        Steam Injection
CN-10  Hot-Gas +       0.0024
        Steam Injection
CN-15  Steam           3.12
CN-12  Hot-Water        110
                        COD,     SS,
                        mg/ 1    mg/ 1
                                     4,300
                                       500

                                     9.400
                                       460
                                   73
                                   90
                                    4
 PH
6.3


6.8

6.4
7.7
                             -23-

-------
Red Beets  -  A mixture of small and medium sized, washed, red beets
were obtained in Eugene, Oregon on September 15,  1971 and brought to
Berkeley.  The results of short-duration blanching runs with beets in
the four experimental units are tabulated in Appendix F.  The results of
long term blanching of beets  are  tabulated in Table 10.
Table 10    Long Term Blanching Runs for Red Beets
Run
No.
Blan-
ching
Unit
Feed    Feed   Resi-
Rate,    Time,  dence
                         Perox
                         Inact
Raw
BT-10
BT-7
                            Temp, Prod
Lb/Hr  Min    Time,  Sec    F     Yield, %  Slope
5 kw     240
Microwave +
Steam Injection
Hot-Gas +157
Steam Injection
          30
          60
 93
625
                              130
                              250
100
 94
1. 14
0. 105
0.045
BT-8
BT-11
Steam 142
Hot- Water 150
53
60
660
510
195
198
96
99
0.
0.
038
075
The wastewater volumes and characteristics for longer-term blanching
of beets are tabulated in Table 11.
Table 11   Wastewater Volume and Characteristics for Red Beet
           Blanching
        Blan-
Run    ching
No.     Unit
BT-10  5 kw
        Microwave +
        Steam Injection
BT-7  Hot Gas +
        Steam Injection
                 Waste-
                 water
                   0. 50
                   0.007
                       COD,
                        320
                      1,500
             SS
                 Vol., Gal.     mg/1    mg/1
              47
              10
                                          5.3
                                          7.0
                              -24-

-------
 Table 11
ContTd

Run
No.
BT-8
BT-H
Blan-
ching
Unit
Steam
Hot-Water
Waste -
water COD,
Vol , Gal. mg/1
4.75 7,200
100 370

SS,
mg/1
420
14


PH
5. 0
7. 10
 Pumpkin - The pumpkins used in the blanching experiments were obtained
 near Gridley, California on October  19, 1971 and transported whole to
 the Berkeley Laboratory.  The pumpkin was cut by hand into random-
 sized pieces ( 1 in.  square up to 3 in. square )  and the seeds removed.

 The results of short-duration blanching runs for  pumpkin are tabulated
 in Appendix F.  The results from the longer-term blanching experiments
 with pumpkin pieces are tabulated in Table  12.
 Table  12    Long Term Blanching Runs for Pumpkin Pieces
        Blan-
Run    ching
No.     Unit
      Feed
Feed   Residence
                                                   Prod   Perox
                   Rate,   Time,   Time,   Temp, yield  Inact
                   Lb/Hr  Min	Sec      °F      %    Slope
Raw      -          ...
PM-13   5 kw        130      60     390
         Microwave +
         Steam Injection
PM-14   Hot-Gas +   130      60     625
         Steam Injection
PM-15   Steam       140      60     600
PM-16   Hot-Water   120      60     510
                                              140
                                             250

                                             196
                                             210
                                        86

                                        93
                                        94
                                              7.43
                                        94    1.22
                               0.079

                               0. 0057
                               0. 013
The wastewater volumes and characteristics for longer-term blanching
of pumpkin are tabulated in Table 13.
                              -25-

-------
Table 13    Wastewater Volume and Characteristics for Pumpkin
            Piece Blanching

Run
No.
PM-13
Blan-
ching
Unit
5 kw
Waste
water
Vol, Gal.
2.5

COD,
mg/1
6,600

SS,
mg/1
84

pH
6.2
          Microwave +
          Steam Injection
PM-14   Hot-Gas +         0.005          140       1        6.0
          Steam Injection
PM-15
PM-16
Steam
Hot -Water
4.5
110
10,400
640
48
10
6. 1
7.2
Spinach  - The spinach used in blanching experiments was obtained from
Walla Walla, Washington.  The spinach received at the cannery on
October 27, 1971 was destoned and washed.  The washed spinach was
packed in plastic-lined  lug boxes.  Crushed ice was added to keep the
product cool during the transport period.  The spinach arrived in Berk-
eley in excellent condition on the evening of October 29, 1971.

The results of short-duration runs for microwave and hot-gas blanching
of spinach are tabulated in Appendix F. No short-duration runs were
made for  steam and hot-water blanching because bench scale work, done
earlier on samples of fresh market spinach, had established that ad-
equate peroxidase inactivation for canning could be accomplished with a
residence time of one minute at 180  F.

The results for the long-term blanching experiments with whole leaf
spinach are tabulated in Table 14.
                              -26-

-------
Table 14     Long Term Blanching Runs for Spinach

Run
No.
Raw
SP-1

SP-2
SP-3
SP-4
Blan- Feed
ching Rate,
Unit Lb/Hr

5 kw 38
Microwave +
Steam Injection
Hot -Gas + 140
Steam Injection
Steam 230
Hot-Water 140
Feed
Time,
Min

60

60
26
30
Resi-
dence
Time, Sec

93

164
79
66

Temp,
°F

140

250
180
180
Prod
Yield, %

63

69
91
104
Perox
Inact
Slope
0.72
0. 034

0. 004
0. 0008
0. 065
The wastewater volumes and characteristics for longer-term blanching
of spinach with the four experimental units are tabulated in Table 15.
Table

Run
No.
SP-1

SP-2
SP-3
SP-4
15 Wastewater
Blanching
Blan-
ching
Unit
5 kw
Microwave + j
Steam Injection
Hot-Gas +
Steam Injection
Steam
Hot Water
Volume and Characteristics
Waste -
Water
Vol , Gal.
0.63

0. 003
6.4
100

COD,
mg/l
280

990
4700
220
for Spinach

SS,
mg/l
37

1
210
35

PH
5.6

6.9
6. 1
6.6
                              -27-

-------
PRODUCT EVALUATION

The samples of canned vegetables prepared from the blanched material
from  each of the four units were stored at ambient temperature in the
NCA Berkeley Laboratory for six months before any quality examin-
ation  was made.  The  storage period was used to allow any slow chem-
ical reactions due to inadequate blanching to show up as deteriorated
product quality.  Also, the storage period would allow time for any
internal corrosion to occur due to inadequate blanching.

Taste - The canned  samples  of  green asparagus,  green beans, corn,
beets and pumpkin (  as pies ) were presented to a laboratory taste panel.
The results of the taste panel evaluation are tabulated in Table 16.  It
was not possible to get a taste panel results for green peas ( raw prod-
uct souring ) or spinach ( low vacuum due to excessive holding time of
hot brine  filled cans before closing and retorting  ).
Table 16    Taste Panel Evaluation of Canned Samples After Storage
            for Six Months
                            Ranking Totals */Number of Judgements
    Commodity

 Asparagus
    Microwave
    Steam
    Hot-Water
    Commercial**
Panel
32/11
26/11
20/11
31/11
46/16
34/16
49/16
31/16
55/16
38/16
41/16
26/16
51/16
31/16
39/16
39/16
 Green Beans
    Microwave
    Hot-Gas
    Steam
    Hot-Water
49/16
40/16
37/16
34/16
44/16
39/16
37/16
34/16
43/16
42/16
43/16
32/16
48/16
35/16
40/16
37/16
                            -28^

-------
Table 16   Cont'd
                           Ranking Totals */Number of Judgements
   Commodity

Corn
   Microwave
   Hot-Gas
   Steam
   Hot-Water
Panel
26/16
51/16
38/16
44/16
24/15
41/15
31/15
55/15
28/16
40/16
34/16
52/16
28/16
42/16
39/16
50/16
Beets
  Microwave
  Hot-Gas
  Steam
  Hot-Water
31/14
42/14
37/14
30/14
28/16
41/16
47/16
44/16
44/16
31/16
39/16
40/16
40/16
36/16
44/16
40/16
Pumpkin ( As Pies )
  Microwave
  Hot-Gas
  Steam
  Hot-Water
41/15
28/15
28/15
43/15
48/16
37/16
39/16
38/16
35/13
29/13
28/13
38/13
41/15
31/15
43/15
34/15
         The ranking totals are sums of individual rankings with
         the best flavor given the lowest number.

         Sample purchased at a store to complete the set of four
         samples since hot-gas blanching of asparagus was not
         done at the  time of the preparation of the other  three
         samples.
                            -29-

-------
Grading -  Canned samples of green beans, whole kernel corn, whole
beets, pumpkin and spinach prepared with microwave, hot-gas, steam
and hot-water blanching were quality graded by inspectors from the
USDA.  The total scores from the grading are tabulated in Table 17
and the copies of the actual scoring sheets are in Appendix H.  The
higher the score number the higher the quality of the sample being
scored.
Table 17     Quality Scores for USDA Grading of Canned Vegetables
Commodity                                    Total Score *

Green Beans
   Microwave                                      76
   Hot-Gas                                         64
   Steam                                           62
   Hot-Water                                      72

Whole Kernel Corn
   Microwave                                      71
   Hot-Gas                                         75
   Steam                                           68
   Hot-Water                                      82

Whole Beets
   Microwave                                      83
   Hot-Gas                                         79
   Steam                                           80
   Hot-Water                                      80

Pumpkin
   Microwave                                      78
   Hot-Gas                                         78
   Steam                                           85
   Hot-Water                                      84
                            -30-

-------
Table 17    Cont'd
Commodity                                    Total Score *

Spinach
   Microwave                                       0**
   Hot-Gas                                         n**
   Steam                                           0**
   Hot-Water                                       0**

   *      Higher the score the better the product quality
  **      All spinach samples scored 0 due to excessive stem  material
Headspace Gases -  The results of analysis of headspace gases in
canned samples of vegetables are tabulated in  Table 18.
Table 18    Headspace Gas Analysis of Canned Vegetables Stored
            Six Months
                                                Percent
              Blanching  Headspace                       Argon
Commodity    Unit      Volume, ml   N2    CO2    HZ*  +02
Asparagus   Microwave      15.4       84   7.2    6.2   2.6

             Steam          10.8       94   3.5    0.0   2.5

             Hot-Water       8.6       86   3.7    6.3   4.0

Green Beans Microwave      28. 8       93   4. 8    0.2   2. 0

             Hot-Gas        29.1       89   5.5    3.6   1.9

             Steam          28. 7       93   4. 6    0. 3   2. 1

             Hot-Water      24.4       91   5.0    2.0   2.0

                             -31-

-------
Table 15   Cont'd
Percent
Commodity
Spinach



Beets



Pumpkin



Green Peas



Blanching Headspace
Unit Volume, ml N2
Microwave
Hot-Gas
Steam
Hot-Water
Microwave 21.0
Hot-Gas 24. 8
Steam 17.8
Hot-Water 26. 5
Microwave 21.4
Hot-Gas 27. 0
Steam 15.3
Hot -Water 21.1
Microwave 30. 1
Hot-Gas 28. 8
Steam 31.9
Hot- Water 29. 2
89
87
92
86
74
91
93
88
90
86
90
91
93
88
90
92
CO 2
10.4
10.5
6.4
11.2
5.7
7.3
3.9
5.2
6.6
8.6
7.9
6.6
4.4
4.0
3.6
3.7
r
H2*
0.0
0.3
0. 0
0.6
18.3
0.4
0. 0
4.6
1.4
4. 1
0. 0
0.3
0. 0
0.9
2.9
0.3
Argon
+02
0.6
2.2
1.6
2.2
2.0
1.3
3. 1
2.2
2.0
1.3
2.1
2. 1
2.6
7.1
,3.5
4.0
                              -32-

-------
Table 18    Cont'd
                                                Percent
              Blanching   Headspace                       Argon
 Commodity     Unit      Volume, ml    N2    CO2   H2»   +02	

 Corn         Microwave      42.9       91    3.9   0. 0   5. 1

              Hot-Gas        36.0       88    7.3   0.3   4.4

              Steam          38.5       92    5.8   0.3  . 1. 9

              Hot-Water      37.5       92    5. 9   0. 0   2. 1

*  Determined by difference



Internal Can Corrosion -  The results of estimation of the extent of
internal corrosion of cans used to store thermally processed vegetables
are tabulated in Table 19.
Table 19   Estimation of Extent of Internal Corrosion of Cans Used to
           Store Vegetables for Six Months at 65 - 85 F
Commodity                            Average Extent of Corrosion*

Asparagus
   Microwave                                       2
   Steam                                            2
   Hot-Water                                       2
   Commercial                                      3

Green Beans
   Microwave                                       1
   Hot-Gas                                         1
   Steam                                            1
   Hot-Water                                       1
                             -33-

-------
Table 19      Cont'd*
Commodity                            Average Extent of Corrosion*

Beets
   Microwave                                       1
   Hot-Gas                                         1
   Steam                                            1
   Hot-Water                                       1

Green Peas
   Microwave                                       2
   Hot-Gas                                         2
   Steam                                            2
   Hot-Water                                       2

Corn
   Microwave                                       2
   Hot-Gas                                         1
   Steam                                            1
   Hot-Water                                       1

Spinach
   Microwave                                       1
   Hot-Gas                                         3
   Steam                                            2
   Hot-Water                                       2

Pumpkin
   Microwave                                       3
   Hot-Gas                                         2
   Steam                                            2
   Hot-Water                                       2

#4 =  severe; 3 = moderate; 2 =  slight;  1 = no corrosion
                            -34-

-------
Vitamin and Mineral Content  -  The average values for vitamin content
of raw, blanched and canned samples of vegetables are tabulated in
Table 20.  Individual results for vitamin content and related standard
deviations  are tabulated in Appendix I.  The average values for mineral
content of raw and blanched samples of vegetables are tabulated in
                                                4
Table 21.  Individual results for mineral content and standard  deviations
are tabulated in Appendix J.
                             -35-

-------
Table 20       Vitamin Content of Raw,  Blanched,  and Canned Vegetables
                           Average Values in mg/lOOg
                      Blanched Samples
Canned and Stored ( Six Months ) Samples
Commodity
Asparagus



Green Peas




Green Beans



Corn



Beets


Pumpkin

Spinach




Vitamin
B,
BZ
C
Niacin
B,
B2
B6
C
Niacin
B,
B2
B6
Niacin
B,
B2
B6
Niacin
BZ
C
Niacin
A
Niacin
A
B2 	
C
*
**
Raw Microwave
.22
.22
19.
1. 55
.07
. 17
#
*#
*
*
. 13
.056
.49
*
. 12
*
1.41
. 061
6.9
.24
5.78
.49
2.30
. 072
**
Enzyme
Samples
*
. 19
14.
1.82
. 10
. 17
. 24
#*
1.93
*
. 13
.058
.64
*
. 11
#
2.23
. 054
6.8
.21
5.05
. 38
4. 02
. 15
**
used gave
lost durin
Hot-Gas
. 18
. 19
11.
. 73
. 14
. 17
.27
#*
2. 03
*
. 12
.037
.73
#
. 12
*
2. 06
. 068
7. 5
.26
4. 06
. 57
4.21
. 13
**
poor results.
g storage peri
Steam
*
. 20
22.
1.46
.07
. 13
. 32
*#
1.95
#
. 12
. 053
.56
*
. 11
*
2. 18
. 045
5.6
. 20
7.91
.26
3.63
. 10
#*
sample used
.od
Hot-Water
*
.20
18.
1.65
.06
. 15
.22
#*
1.72
*
. 12
.057
.57
*
. 11
*
1.91
. 041
7.9
.20
4.66
. 32
3.74
.073
**
up in other

Microwave
. 053
. 096
3. 8
.64
. 10
. 075
. 14
2.6
1. 1
.29
.054
. 051
.36
. 025
. 079
. 070
1. 08
. 016
4. 1
. 08
3. 74
.41
1. 57
. 11

analyses

Hot-Gas
_
-
-
-
. 11
. 082
. 15
4.7
1.2
.40
.066
. 054
. 38
.026
. 079
. 077
1. 12
. 013
5. 0
. 09
3. 09
.44
2. 25
. 096



Steam
. 051
. 090
3.6
.76
. 10
.067
. 10
3.9
.92
.30
.060
.048
.35
. 026
.077
. 072
1. 07
.014
4. 1
. 11
2. 98
. 33
3.26
. 081



Hot-Water
. 057
. 11
3.6
. 72
. 089
. 068
. 11
3. 1
.91
.29
.056
. 059
. 32
. 023
. 071
. 073
.95
. 023
4. 8
. 09
5. 22
.28
4. 46
. 089




-------
                     Table 21     Mineral Content of Raw and Blanched Vegetables

                                        Average Values in mg/lOOg

                                                                     Blanched Sample
       Commodity



       Asparagus






       Green' Peas
       Green Beans
-j
i
       Corn



       Beets



       Pumpkin







       Spinach
Mineral
Ca
Mg
P
Ca
Mg
P
Fe
Ca
Mg
P
Fe
P
P
Ca
Mg
P
Ca
Mg
P
Fe
Raw
21.2
15.7
67.0
*
*
#
*
40.0
27.0
36.0
1.25
83.0
22.7
9.2
6.7
11.6
62.2
63.5
20.0
3.1
Microwave
22. 1
15.5
77.0
14.2
28.5
104.
1.03
45. 8
29.3
40.0
1.32
91.3
26. 0
8.8
12.9
21.5
86. 0
89.5
50.2
3.4
Hot -Gas
19.3
15.2
61.5
14.-*
29.1
114.
1.06
52.0
33.1
48.0
1.54
79.0
26.6
13.5
10.9
13.9
68.0
65.0
42. 5
3.2
Steam
22.0
14.4
70.0
13.0
27.6
101.
.99
39.2
26.5
36.0
1.24
90.0
23.4
10.7
9.6
14.2
65.0
65.5
42. 5
3.3
Hot -Water
20.2
16.4
69. 5
14.2
28.3
98.
1. 04
40.6
27. 1
38.4
1. 19
*
21.2
9.2
7.2
9.7
50. 5
49. 0
31.4
3. 1
                            * Sample lost

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ECONOMICS

The detailed cost estimate for vegetable blanching with the four
systems used in this  study are tabulated in Appendix K.  A summary
of the cost estimates is tabulated in Table 22.
Table 22      Summary of Cost Estimates for Four Commercial
              Scale Blanching Systems*



Hot-Gas
Microwave
Hot -Water
Steam
Cost/Ton

Fixed Cost**
2. 19
14.72
1.26
1. 11
Blanched, Dollars

Operating***
1.20
3.72
0.87
0.95
Waste
Management
. 00
. 03
.23
. 15

Total
3.39
18.47
2.36
2.21
*      Based on 5 tons/hr, 1800 hr season

**     Capital costs include: amortization, interest,  space rent,
       taxes, insurance, maintenance

***    Operating cost-4 include:  electric power,  steam consumption,
       gas consumption, water use,  part replacement when applicable,
       and labor.
The assu^pt-ons used in making the cost estimates were the following:

Blancher capacity --  Five tons/hr.
                            -38-

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Annual operating period -- Five week season for each of three commod-
ities.  Six day work week with blanchers operating 20 hr. day.  Therefore,
the total operating period annually would be 3 x 5 x 6 x 20 or 1800 hr.

First cost -- The purchase price of commercial scale blanchers
supplied by manufacturers of food processing equipment.  The purchase
price of the  microwave blancher included the cost of a cooling tower
for removing heat from the water used to cool the power tubes.

Amortization -- Defined as the capital recovery factor (erf) and assum-
ing 7 percent interest,  5 year amortization period and no  salvage value.

Space rent -- This was set at $12. 00/sq ft/year.  One thousand sq ft was
provided for the microwave unit due to the space required for the wave
generating unit in addition to the blancher space requirement.  Five
hundred  sq ft was provided for the other three blanching units.  Boiler
space requirements were ignored since all four units  require steam.

Taxes  -- These were set at $5. 00/$100. 00 of assessed  value based on
25 percent of market  value.

Insurance_-- This was set at 0.2 percent of assessed  value/year.

Maintenance -- This can only be roughly estimated since this factor
varies with the complexity of the equipment and with the care in which
it is operated.  The estimates used ranged from 1 to 2.  5 percent of
first cost/year.

Electrical power -- A rate of $. 035/kwh was used for the hot-gas,
steam and hot-water blanchers and a rate of $. 0125 lor  the microwave
blancher due to its much larger power requirements.  All rates were
obtained from Pacific Gas and Electric Company General Service
Schedule No. A-l.

Steam consumption -- The steam required by the microwave blancher
was the figure provided by the Varian Corporation and that required
for the hot-gas blancher roughly estimated since no steam flow me^er
was used with the experimental unit.

For the hot-water and steam blanchers, steam consumption was
calculated from the following formula (17);
                              -39-

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                   S   =   5.5  C  ( T2 - Tl )
                                 E
      where:

                   S   =  steam requirement ( brake horse power )

                   C  =  process rate  ( tons/hr )
                   T2  =  steam temperature (  F )
                                                           o
                   Tj  =  temperature of incoming product (  F )

                   E =   efficiency

It should be noted that the above  formula yields only a estimated
steam consumption.  The blancher efficiencies were arbitrarily
selected to represent mean efficiencies  over a range of 30-90 percent
with the consideration that hot-water blanchers are more efficient
than steam blancher s.  Blancher efficiency is dependent on  character-
istics such as wall insulation and venting and thus is difficult to
estimate.

Natural gas - -  The cost was taken from the Pacific Gas and Electric
Company Schedule referred to above.

Water --  The figure of $ . 10/100 cu ft was  obtained from the Varian
Corporation as the cost of make-up water for the cooling tower losses.
The estimate of 10 gpm of make-up water for the hot-water blancher
was provided by the FMC Corporation.

Waste disposal --  The figure of $. 05/lb for BOD and SS removal was
obtained from a report prepared by NCA for the U.S.  Environmental
Protection Agency (2).  Amounts of waste were determined from the
studies described above and represent averages of runs involving seven
vegetables.  The values used only approximate those  expected from
commercial blanching operations.

Labor --  Figures of $ 4/hr plus $ .40/hr benefits were used to cal-
culate costs.  Due to the complexity of the microwave and hot-gas
units ( primarily the control requirements ) it was estimated that each
unit would require one worker.   For the steam and hot-water blanchers
provision was made for a half-time worker.
                             -40-

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                          SECTION VI

                          DISCUSSION
The objectives of this study were to test the feasibility-of one new (hot-
gas) and one partially investigated (microwave) blanching system as
replacements for the currently used hot-water and steam blanching
systems.  The overall feasibility was determined  by examining, in
sequence,  the factors of peroxidase inactivation,  blanched product
appearance and texture, wastewater generation and characteristics,
product quality and cost estimates. The feasibility of the proposed
replacement systems could have been eliminated at any of the stages
of the testing program.  For example., at the start of the  study there
was no assurance that hot-gas blanching would reduce peroxidase levels
in a given vegetable using practical residence times  and operating
temperatures.

The fact that the  blanching units  used  in this study were simulators of
possible commercial scale  equipment must be emphasized.   While  every
effort was  made to  operate  the simulators as closely as possible to
commercial conditions,  it should be obvious that the results obtained
are only approximations of  an actual commercial result.  Also, after
a few initial experiments with microwave and hot-gas blanching it was
apparent that steam injection was required to get the most effective
use of energy inputs and to  avoid dehydration of the raw vegetable.
Therefore,  the microwave and hot-gas blanching systems were not
"pure" systems but operationally were "mixed" systems more properly
termed microwave-steam or hot-gas-steam,  respectively.  For purposes
of brevity, the simple designations of microwave and hot-gas are used
in this report but it should be understood that steam  was injected in
the majority of experimental runs.

The first consideration in the text of feasibility of microwave and hot-
gas blanching was the degree of peroxidase inactivation which could be
achieved at reasonable residence times.  The  extent of peroxidase in-
activation found in samples  collected near the  mid-point of the long
duration runs are tabulated in Table 23 with the residence times shown
in parentheses.
                               -41-

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Table 23      Comparison of Peroxidase Inactivation and Residence Times
              for Blanching of Vegetables
                 Percent Peroxidase Inactivation at
                 (Minutes of Residence Time)
Commodity
Asparagus
Peas
Beans
Corn
Beets
Pumpkin
Spinach
Microwave
67
66
89
39
91
84
95
(2.
(3.
(3.
(3.
(1.
(6.
(1.
4)
0)
4)
7)
5)
5)
5)
Hot-Gas
100
92
99
80
96
99
99
(2
(2
(5
(5
(1
(1
(
•2)
.0)
.6)
.5)
0.4)
0.4)
2.7)
Steam
100 (
99 (
99 (
1.7)
1.5)
3.6)
64 (7.2)
97 .(
100 (
100 (
11. 0)
10.0)
1.3)
Hot-Water
90
98
99
39
93
100
91
(1.
(1.
(4.
(7.
(8.
(8.
(1.
5)
5)
8)
3)
5)
5)
1)
The target peroxidase inactivation value selected for this study was 90
percent.  This value, which represents a residual peroxidase content of
10 percent, was chosen since such as extent of inactivation would be
satisfactory for a canned final product.   Essentially complete peroxidase
inactivation would be required for frozen preservation. r Many of the short
duration runs tabulated in Appendix F lists blanching conditions which
produce 100 percent peroxidase inactivation and would be useful for blan-
ching of vegetables  to be preserved by freezing.

The extent of peroxidase inactivation resulting from microwave blanching
showed the  greatest variability from vegetable to vegetable.  The average
extent of peroxidase inactivation was lower for microwave blanching than
for the other three blanching methods.  This observation of variability of
extent of peroxidase inactivation suggests that the energy produced fluc-
uates during different periods  of operation at the same settings of the
                              -42-

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dials on the control panel of the microwave blancher.  The microwave
blancher appeared to be more effective with the large piece size veg-
etables such as beets and pumpkin than with smaller  sized vegetables
such as peas.

The hot-gas  blancher was the most reliable of the two newer blanching
systems in reducing peroxidase levels at residence times  similar to
those used for steam and hot-water blanching.  The only low value found
for hot-gas blanching ( 80 percent for corn-on-cob ) was still consider-
ably higher than the value found for steam  and hot-water at somewhat
longe:r residence times. It can be concluded that hot-gas blanching has
the potential of reducing peroxidase levels to useful degrees at practical
residence times.

The appearance, softening, wilting and wrinkling of vegetables blanched
by the hot-gas unit, with the exception of cut kernel corn,  were satisfac-
tory and no different from the changes caused by steam or hot-water blan-
ching.  There were no  observations made on hot-gas  blanched samples
which indicated a potential difficulty in a subsequent operation such as
peeling, cutting, blending or filling into containers.

One of the most important parts of this study was the measurement of
wastewater volume and characteristics.  The primary motivation for
examining the feasibility of potential replacement blanching systems was
the need for  reduction of wastewater generation during vegetable blanching .
The volume  of wastewater generated for each of the seven vegetables
during blanching with the four units are tabulated in Table 24.  Inspection
of the data in Table 24  leads to the conclusions that wastewater volume is
about the same for microwave and steam blanching and both of these are
significantly smaller than the volume  from hot-water blanching.  The most
striking conclusion is the very large reduction in wastewater volume from
hot-gas blanching compared even to the volume  from  steam blanching.  It
can be concluded that hot-gas blanching is truly a low volume liquid efflu-
ent blanching system.
                              -43-

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Table 24
               Waste-water Generation During Vegetable Blanching
                            Waste-water Volume, Gal/Ton
                  Microwave     Hot-Gas    Steam    Hot-Water
Vegetable

Asparagus

Peas

Beans

Corn

Beets

Pumpkin

Spinach
                      32

                      43

                      48

                    9.4

                    8.3

                      84

                      33
    0

0.018

0.25

0.013

0.087

0.076

0.043
 48

 48

 48

 28

 77

 64

130
1700

1000

1700

1200

1300

1800

2900
The low volume of liquid effluent product by hot-gas blanching results
in high concentrations of COD and SS in the wastewater.  Therefore,
it is important to compare the pounds of COD and SS produced during
blanching since these values are related to the treatment required to
avoid potential water pollution.  Table 25 tabulates the pounds of COD
and SS produced per ton of vegetable blanched with each of the four units,
It can be seen from the data in Table 25 that for all practical purposes
the hot-gas blancher produces insignificant amounts of COD and SS.
This result was the most  significant finding in the study.
                             -44-

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 Table 25
Pounds of CCD and SS  Produced During Vegetable
Blanching
Microwave
Commodity COD SS
Asparagus . 9 . 012
Peas 20 . 22
Beans . 60 . 018
Corn . 34 . 0057
Beets . 02 . 0033
Pumpkin 2. 1 . 027
Spinach . 077 .010
* Any value less than 0. 001 was
Lb/Ton Blanched

Hot-Gas- Steam Hot-Water
COD SS COD SS COD SS
00 10 .016 1.4
16 1. 5 32
.002 0 2.2 .04 4.7
0 0 2.2 .021 4.6
.001 0 4. 6 .27 4.0
0 0 5. 6 .026 9.6
0 0 5.1 .23 5.3
considered equivalent to zero
.014
1.4
. 11
. 04
. 15
. 15
.85

The above discussion has concluded that hot-gas blanching is effective in
reducing enzyme activity of vegetables without significant generation of
liquid waste. "The next factor to consider in determining overall feasibility
was product quality.  The results for taste, grading, headspace gases,
internal can corrosion and vitamin and mineral content were subjected to
analysis of variance.  In none of the  five product quality categories was
there a statistically significant difference due to the blanching treatment
received.   This result means that hot-gas blanching produces a final prod-
uct at least equivalent in quality to products produced using microwave,
steam  and hot-water blanching.

-------
The final stage of determination of overall feasibility is cost estimation.
The cost estimation is  based on a  summation of individual estimates and
its usefulness is related to the validity of the individual estimates.  The
major source of possible error in the cost estimates occurs in the estimate
of first cost for the hot-gas blancher.  The figure of $50, 000 which was
used in the  cost estimate was obtained from  a potential supplier of hot-gas
blanching equipment and was based on a limited engineering design  con-
sideration.  The experimental hot-gas blancher used in this study,  which
had an average capacity of 500 Ib/hr, cost $20, 500.  It did not seem real-
istic to use a  simple scale-up factor of 20 to estimate the cost of a  5 ton/hr
hot-gas blancher ( $410, 000 ) since much of the cost was due to custom
design and fabrication.  In-plant studies with the hot-gas blancher,  after
completing  the pilot-plant study, have suggested that the large blower
does not accomplish movement of  the vegetable pieces.  It is possible that
a simplified hot-gas blancher, which depends on convection currents to
expose  the vegetable pieces to hot combustion products, would be less
costly.   Therefore, this amount of $50, 000 was used as the first cost for
a commercial scale hot-gas blancher.

The amounts tabulated in Table 22 for cost of blanching show hot-gas blan-
ching, while more costly, is not prohibitively expensive.  In view of the
uncertainty of the cost estimate, further investigation of hot-gas blanching
is desirable to develop more accurate cost factors.

The most significantly different cost factor is comparing hot-gas blanching
with steam  and hot-water  blanching is in waste management. Hot-gas
blanching may be more attractive  economically in the next few years as
waste treatment costs increase as the national goal of zero discharge of
pollutants by  1985 is approached.  The very small volume of liquid  effluent
produced during hot-gas blanching make it an excellent choice  as part of
closed loop technology.

The cost of waste treatment is going to increase as the percent removal
of BOD and SS increases.   For those processors discharging into municipal
treatment systems, an increase in treatment level will increase the sur-
charges paid by the industrial discharger.  It is likely that waste manage-
ment  costs  will increase substantially;  this  will make hot-gas blanching
economically  more competitive with steam or hot-water blanching.
                               -46-

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                            SECTION VII

                       ACKNOWLEDGEMENTS


A number of individuals and government agencies and companies were
very generous in support  of this project by supplying equipment, raw
vegetables, containers, information or editorial advice.  The agencies,
companies and individuals whose contribution made this project possible
are:

U. S. Environmental Protection Agency, Kenneth A. Dostal, Harold W.
Thompson,  Corvallis, Oregon.

Green Giant Company, Willard R. Brosz,  John L. Welch, Le Sueur,
Minnesota and Robert L.  Shaffer, Belvidere, Illinois.

Diamond Fruit Growers,  Charles L.  Beadsley, Hood River, Oregon,
Howard Blackley, Vancouver, Washington, and Logan Cavanaugh,  Grand-
view, Washington.

Tillie Lewis Foods, Inc. , Harry Rosen, Ed Harmon,  Stockton, California.

Lamb Weston, Inc. ,  Bruce H.  Morgan,  Portland, Oregon and Howard
Rice, John Hendricks, Weston, Oregon.

Agripac, Inc.  E. E. Pitkin, Alton C. McCully, Eugene, Oregon.

Libby, McNeill & Libby,  James J. Albrecht, Randy Johnson, Donald T.
Stevens, Chicago, Illinois, James M. Smethers, Gridley, California and
Robert Wapple, Yuba City, ^California.

Rogers  Walla Walla,  Inc. , William Lawr, Bud Arnold, Richard Volman,
Irene Blake, Walla Walla, Washington.

U. S. Department of Agriculture, Robert P. Graham, Charles Huxsoll,
Douglas Homnick, Albany, California, Raymond D. McHenry, San Fran-
cisco, California, Raymond Hartwig, B. P. Eisner,  Leo Boire,  Stockton,
California.
                             -47-

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                           SECTION VIII

                        LITERATURE CITED
1.  Potter, N.N.,  Food Science,  The AVI Publishing Company,
    Westport, Connecticut  ( 1968 ).

2.  Anon. ,  "Liquid Wastes from Canning and Freezing Fruits
    and Vegetables, "  U. S. Environmental Protection Agency
    Water Pollution Control Research Series 12060 EDK 08/71
    (  1971 ).

3.  Mitchell, R. S.  , Board, P. W. , and Lynch,  L. J. , " Fluid -
    ized Bed Blanching of Green Peas for Processing," Food
    Technology, 22, No. 6, pp 717-718 ( 1968 ).

4.  Lazar, M. E. ,  Lund, D. B., and Dietrich,  W. C. , "A New
    Concept in Blanching ( IQB ), "  Food Technology, 25,
    No. 7, pp 684-686 ( 1971 ).

5.  Huxsoll, C. C. , Dietrich, W. C., and Morgan,  A.I. , Jr.,
    "Comparison of Microwave with Steam or Water Blanching
    of Corn-on-the-Cob.   1.  Characteristics of Equipment
    and Heat Penetration, " Food Technology, 24, No. 3,  pp
    290-292 ( 1970  ).

6.  Dietrich, W. C. , Huxsoll, C. C., Wagner, J. R. , and
    Guadagni, D. G. , "Comparison of Microwave with Steam
    or Water Blanching of Corn-on-the-Cob.  2. Peroxidase
    Inactivation and Flavor Retention, "  Food Technology,
    24, No.  3, pp  293-296 ( 1970 ).

7.  Dietrich, W. C. , Huxsoll, C. C. , and Guadagni, D. G. ,
    "Comparison of Microwave,  Conventional and Combination
    Blanching of Brussel Sprouts for Frozen Storage, " Food
    Technology, 24, No. 5, pp 613-617  ( 1970 ).

8.  Chen,  S. C. , Cpllins, J. L. , McCarty, I. E., and Johnson,
    M. R.  , "Blanching of White Potatoes by Microwave Energy
    Followed by Boiling Water,  " Journal of Food Science, 36,
                          -49-

-------
     No.  5, pp 742-745 ( 1971 ).

 9.   Anon. ,  "FWPCA Methods for Chemical Analysis of
     Water and Wastes, "  Analytical Quality Control Lab-
     oratory, Division of Water Quality Research, Federal
     Water Pollution Control Administration, Department
     of the Interior,  Cincinnati, Ohio  ( 1967).

10.   Anon. ,  Laboratory Manual for  Food Canners and Proces
     sors, The AVI Publishing Company, Westport,  Connecti
     cut ( 1968 ).

11.   Anon.,  Official Methods of Analysis of the Association
     of Official Analytical Chemists, Eleventh Edition,
     Association of Official Analytical Chemists,  Washington,
     D. C. (1970).

12.   Watt, B.K. , and Merrill, A. L. ,  Composition of Foods.
     Agriculture Handbook No. 8, Agricultural Research
     Service, U.S. Department of Agriculture,  Washington,
     D. C. (1963).
13.   Orr,  M. L. ,  Pantothenic Acid,  Vitamin BA, . and Vitamin
     B12 in Foods.  Home Economics Research Report No.  36,
     Agricultural Research Service, U. S. Department of
     Agriculture, Washington, D. C.   (1969).

14.   Anon. ,  "Recommended Daily Dietary Allowances, "
     Food and Nutrition News ,40, No. 2 (1968).

15.   Anon. ,  The Almanac of the Canning,  Freezing, Preser-
     ving Industries, Edward E.  Judge & Sons, Inc. ,  West-
     minster,  Maryland (1972).

16.   Amerine, M.A., Pangborn, R.M. , and Roessler, E. B. ,
     Principles of Sensory Evaluation of Food,  Academic
     Press,  New York (1965).

 17.  Copley,  M.J., and Van Arsdel, W. B. , Food Dehydration,
     The AVI Publishing  Company,  Westport,  Connecticut
     (1964).
                      -50-

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                       SECTION IX
                PUBLICATIONS AND PATENTS


Rails,  J. W. , Maagdenberg,  H. J. , Yacoub, N.L.,  and Mercer, W.A.,
"Reduced Waste Generation by Alternate Vegetable Blanching Systems"
U. S. Environmental Protection Agency Series EPA-R2 -72-018
(1972).

U.S. Patent Pending,  Hot Gas Blanching

Process, Case No. WQO - 43 - 72 (G),

February 22, 1973.
                            -51-

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                              SECTION X

                              GLOSSARY


Acceptance --  (1) An experience or feature of experience,  character-
ized by a positive ( approach in a pleasant )  attitude.  (2) Actual utili-
zation ( purchase, eating ).  May be measured by preferences or liking
for specific food item.

Analysis of Variance -- A method of determining the significance of
differences in a group of averages of experimental observations  by
partitioning of the total sum  of squares and degrees of freedom,  and esti-
mation of the standard deviation  of the population by two or  more methods
and a comparison of these estimates.

Amortization -- (1) Gradual  reduction, redemption,  or liquidation of the
balance of an account according to a specified schedule of times  and amounts.
(2) Provision for the extinguishment of a debt by means of a sinking fund.

Appearance --  The visual  properties of a food, including size, shape,
color, and conformation.

BOD --    Abbreviation for  biochemical oxygen demand. The quantity of
oxygen used in  the biochemical oxidation of organic matter in a specified
time, at a specified temperature, and under  specified conditions.

COD -- Abbreviation for chemical oxygen demand.  A measure of the  oxygen
consuming capacity of inorganic  and organic  matter present in water or
wastewater.

Blanching  -- Heating a food to a  temperature high enough to inactivate en-
zymes present  and to remove undesirable occluded gases and contaminants .

Coding -- Assignment of symbols, usually letters and/or numbers,  to test
samples so that they may be presented to a subject without identification.

Consumer -- An individual who obtains or uses a commodity.
                                  -53-

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Cooling tower -- A vertical structure with internal baffles to break
up flowing water so that it is cooled by upward-flowing air and by
evaporation of water.

Enzyme  -- A catalyst produced by living cells which is protein in
nature.

Flavor --  An attribute of foods, beverages,  and seasonings resulting
from stimulation of the sense ends that are grouped together at the
entrance of the alimentary  and respiratory tracts - especially odor and
taste.

Fixed  charge -- A charge that cannot be  escaped, shifted, or altered,
such as interest,  rent, taxes and amortization.

Make-up water -- Water added to circulating water in a system to
replace water lost by  evaporation, leakage, or blowdown.

Panel  -- A group of people  ( observers,  subjects, judges ) comprising
a test  population which has  been specially selected or designated in
some manner.

Peroxidase -- A class of enzymes which catalyze the reaction of molec-
ular oxygen with a substrate to produce a peroxide, link in the altered
molecule.

Protein -- Any of the  complex nitrogeneous compounds formed in living
organisms which consist of amino acids bound together by peptide link-
ages.

Quality -- The composite of the characteristics  that differentiate among
individual units of the product and have significance in determining the
degree of acceptability of the unit by the  user.

Ranking  -- A procedure of  arranging food products in order according
to some  criterion and assigning consecutive integers (ranks) correspond
ing to  the order.

Sample -- A specimen or aliquot presented for inspection.
                            -54-

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Score -- A value assigned to a specific response made to a test item.

Suspended Solids (SS) -- Solids that either float on the surface  of, or
are in suspension in, water, wastewater or other liquids.

Taste -- One of the senses usually limited to four qualities:  saline,
sweet, sour and bitter.

Vapor pressure -- The  pressure exerted by a material in the gaseous
state when confined in a space  of fixed volume.
                           -55-

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                        SECTION X
                       APPENDICES
                                             Page
Appendix A

Appendix B

Appendix C


Appendix D

Appendix E

Appendix F

Appendix G


Appendix H


Appendix I


Appendix J


Appendix K
Microwave Blanching Unit Specifications       58

Hot-Gas Blanching Unit Specifications         59

Steam and Hot-Water Blanching Unit           60
Specifications

Taste Panel Scoring Sheet                    61

Headspace Gas Analysis Method               62

Short Duration Blanching Runs                65

Characteristics of Grab Samples from         73
Hot Water Blancher

USDA Scoring Sheets for Quality Grading       74
of Canned Vegetables

Vitamin Content in Raw, Blanched, and        81
Canned Vegetables

Mineral Content of Raw and Blanched          84
Vegetables

Cost Estimates for Commercial Scale         85
Blanching
                             -57-

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Appendix A
MICROWAVE BLANCHING UNIT SPECIFICATIONS
Length

Width

Microwave frequency

Microwave power (2-2. 5 kw
power packs)

Entrance and exit port size

Belt
Belt speed

Cavity material

Finish

Power requirements:

         Conveyor only
         Air heaters only
         Each power pack

Air supply
                                   o
Air temperature controllable to 250 -F
Water requirements (-each power pack)
 Steam
20 ft
 2 ft
2450 t  50  MHz
5 kw

4 in. high x 12 in. wide

1/4 in. mesh, coated
fiberglass

0-20' per min, reversible

Stainless steel

28 exterior; 4B

220V:  3-phase;  60 Hz

1 kVA
30 kVA
5 kVA

Adjustable 200-600 cfm

1. 5 gpm @ 20 psig/min
40 psi g
                            -58-

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Appendix B
HOT-GAS BLANCHING UNIT SPECIFICATIONS
Length:

Width:

Conveyor:
Conveyor width:

Conveyor drive:
Heater:
Blower:
Air Temperature:

Product Capacity:
16.5 ft

6.5 ft

Stainless steel belt in two
levels each with flights,
3 in. high and 12 in. apart

12 in.

Variable speed motor with
10 fold speed range

Natural gas fired burners
Rated at 12. 5, 000 Btu/hr

3800 standard cu ft/min

250 F  Maximum

500 Ib/hr
                             -59-

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Appendix C
STEAM AND HOT-WATER BLANCHING UNIT SPECIFICATIONS
Length:

Width:

Belt Width:

Material of Construction:

•Bearings:


Conveyor ( chain )

Shaft diameter:

Drapes:
 Drive:
 Belt speed:

 Steam coil test pressure:
8. 5 ft.

18.5 in.

15.25 in.

18 - 8 (304) stainless steel

Bronze brushed with grease
fittings

No. 40, extended pitch

1 in .

B-N standard type,  16 GA.
mesh 3/16 in. openings with
2. 5 in. high flights at 6 in.
spacing

4. 9 - 49 rpm, U. S.  Varidrive
RT. angle, 0. 5 hp,  3 phase,
60 cycle

4-40 fpm

225 psig
                             -60-

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Appendix D
TASTE PANEL SCORING SHEET
Please taste and rank samples in order of flavor preference.  Take
completed scoring sheets and used sample tray to cutting room.
       CODE                      FLAVOR RANKING

                                 1 = Best;          4 Worst
       M
       N
       O
Date                             Tasters' Initials
                          -61-

-------
Appendix E   HEADSPACE GAS ANALYSIS METHOD

Cans are opened under water, beneath a funnel connected to either a
50 or 100 ml burette to collect and read the volume of headspace gas.

The burette can be modified by a glass  blower by cutting off stop cock
and placing it on top, above the zero mark. A small .side arm is made
to take the sampling septum ( Kontes  silicone rubber stopper No.  K77-
4200 ).   The space between the stop cock and  the zero mark, including
the side  arm should be as small as practically possible  ( measure the
volume ).  Now,  below the 50 ml graduation mark, put a side arm,
which will be connected to the leveling bulb by means of rubber tubing.
The large funnel is also connected to  the burette through rubber tubing.

The procedure is as follows:

1.   Clamp tubing.

2.   Open burette at stop-cock and draw water into the burette through
     funnel, with the help of vacuum.

3.   When full, close stop cock and clamp tubing.

4.   Remove clamp and fill leveling bulb and tubing with water, squeeze
     tubing with fingers to make  absolutely certain that no air bubbles
     are  trapped in it.

5.   Place can to  be sampled into the  water and remove  all  visible air
     droplets clinging to its surface.

6.   Place can underneath the funnel and punch a hole in it with a church
     key. Usually the can is put on its side and the hole punched so that
     the  gas will not escape immediately,  but  will do  so  when the can is
     rotated under the funnel.

7.   Once all of the gas in the can has been collected, adjust the liquid
     level in the burette to that of the  leveling bulb and read the volume
     of gas ( add the volume above  the zero mark ).
                                -62-

-------
 Appendix E      Cont'd

 9.   Raise the leveling bulb above the level of the gas in the burette;
     this will give a slight positive pressure inside the burette.  Insert
     the syringe through the septum, pump it two or three times,  and
     withdraw the sample.

10.   Inject into  the chromatograph.
 Standards
 For N2 and 02, air is used and figure on a proportion of eight parts N2
 to two parts 02.

 For CO2 and H2, buy a mixture of 50:50 from Mathieson.  Close off the
 valve on the CO2 + H2 tank and apply vacuum.  Close off vacuum and
 open up tank valve, repeat this two or three times and then take the
 sample through the septum.

 Chromatographic conditions are as follows:

 Column 1:   Fourteen inches x 1/4" O.D. , Cu; Silica Gel 30/60 mesh.

 Column 2:   Transfer column, 20 ft x 1/8",  Cu; This column connects
             the outlet of column 1 to the inlet of column 3,

 Column 3:   12 ft x 1/4" molecular sieve 5A, 30/60 mesh.

 Oven temperature - This will vary according to the  condition of the columns.
 Start at around 100 C, and increase gradually,  if analysis takes too  long.

 Detector temperature - 200 C

 Injector temperature  -  150 C

 Carrier gas -  He; It will be necessary to experiment with the  flow rate
 until the best rate according to conditions is found.
                               -63-

-------
Appendix E      Cont'd

The first peak to show up is made up of all the gases except CO2,
which appears very shortly after that.  Once the CO2 peak has com-
pletely gone through, as indicated by the recording pen coming back
to the base line,  switch polarity and H2, O2 and N2 will appear in that
order.

Using He as a carrier, a plot of concentration vs  peak height should
give a straight line for each of CO2, N2 and O2.  This is not usually
true of H2, which as its concentration relative to He  increases will
give a peak with  an inverted tip. Usually H2 is determined by differ-
ence.  Add up the percentage of the three remaining  gases  and compute
the difference.

It seems that  what has been called O2 in the headspace gas  for several
years is probably argon.   The conditions used cannot separate argon
and oxygen.   To  detect O2,  it would be necessary to  use argon as a
carrier gas  ( in which case a peak  shows up ) it would indicate the
presence of oxygen, as argon would not respond.
                                -64-

-------
Appendix F
SHORT DURATION BLANCHING RUNS
Green Asparagus

Run
No.
Raw-1971
ASP -7

ASP -8
ASP -9
ASP-10
ASP- 11
ASP-12

ASP-13
ASP -14

ASP-15
ASP- 16
ASP-17
ASP-32


Blanch-
ing Unit
_
5 kw
Microwave
it
ti
ii
it
4 kw
Microwave
ii
3 kw
Microwave
ii
it
ii
5 kw
Microwave
Feed
Rate,
Lb/Hr
_
49

240
300
160
105
100

225
225

66
86
113
257
+

Residence
Time, Sec
_
673

84
84
160
281
398

130
130

281
206
160
84


Temp,
°F
_
183

183
151
151
151
210

210
210

210
210
210
144

Peroxidase
Inactivation
Slope
0. 192
Over blanched

0. 193
0.210
0. 160
0.033
0. 010

0. 285*
0.300*

0. 135
0. 175
0. 175
0.233

Steam Injection
ASP-33
ASP -34
ASP -35
ASP-1
ASP-2
ASP-18
ASP-19
ASP-20
ASP -3
ASP -5
ASP -21
ti
n
ii
Steam
it
it
ti
u
Hot Water
n
n
168
168
N.R.
323
331
400
267
268
120
172
278
160
104
130
135
100
79
100
134
227
147
90
144
144
144
212
212
200
200
200
180
190
180
0.055
0. 165
0. 080
Over blanched
0.008
0. 005
0.003
0.00
0.007
0.004
0.04
                            -65-

-------
Appendix F
Cont'd
Green Asparagus    Cont'd

Run
No.
ASP-22
ASP -23
ASP-27
Raw-1972
ASPS-1
ASPS -2
ASPS -3
ASPS -4
ASPS -5
ASPS -6
Feed
Blanch- Rate,
ing Unit Lb/Hr
" 288
" 343
267
_ _
Hot-Gas + 400
Steam Injection
" 600
" 600
" 450
11 500
11 430

Residence
Time, Sec
66
52
90
_
165
106
105
145
131
150

Temp,
°F
180
180
190
_
240
260
200
240
250
250
Peroxidase
Inactivation
Slope
0-04
0.10
0.007
0.4
0.0002
0.0002
0.0002
0. 0002
0. 0002
0.0002
 N.R.   Not Recorded
 *  Higher values due to lower moisture content of sample.
                               -66-

-------
Appendix F
Cont'd
Green Peas

Run
No.
Raw
P-14


P-16
P-15
P-7
P-8

P-9
P-10
P-ll
P-12
P-l
P-2
P-4
P-5
Feed
Blanch- Rate,
ing Unit Lb/Hr

5 kw 138
Microwave +
Steam Injection
11 139
0 kw 167
Hot-Gas 133
Hot -Gas + 300
Steam Injection
11 300
" 343
" 369
11 1200
Steam N. R.
11 150
Hot-Water 274
Hot-Water 192

Residence
Time, Sec

160


130
160
720
120

120
120
120
120
62
90
62
90

Temp
o
F

150


150
150
225
220

205
226
237
250
180
180
180
185
Peroxidase
Inactivation
Slope
1. 75
0. 58


0.51
1.80
0. 01
0.03

0. 08
0. 18
Over blanched
0. 14
0.85
0.02
0.93
0. 07
                              -67-

-------
Appendix F
Cont'd
Green Beans
Run
No.
Raw
3 Sieve


BN-6



BN-7

BN-8

BN-9

BN-10

BN-1

BN-2

BN-3

BN-4

BN-5

BN-11

BN-12
Feed
Blanch- Rate, Residence
ing Unit L.b/Hr Time, Sec
— —
Size


5 kw 85
3 Sieve Size
Microwave +
Steam Injection
" 111
3 Sieve Size
" 108
2 Sieve Size
" 129
2 Sieve Size
" 120
1 Sieve Size
Hot-Gas + 170
Steam Injection 3 Sieve
" 200
3 Sieve Size
'• 109
3 Sieve Size
" 150
3 Sieve Size
" 200
3 Sieve Size
" 203
2 Sieve Size
" 300
..



281



206

206

180

130

183

183

303

233

183

136

103
Temp,
°F
—



146



130

130

112

98

220

250

250

250

250

250

250
Peroxidase
Inactivation
Slope
Optical
Density
Greater
than 2
0.41



0.44

0.42

0.53

0.81

1.0

0.19

0.03

0.03

0.06

0.12

0.38
                       1 Sieve Size
                              -68-

-------
Appendix F
Cont'd
Green Beans

Run
No.
BN-13

BN-14

BN-15

BN-16

BN-17

BN-18

BN-19

BN-20

BN-21

BN-22

BN-23

BN-24

Feed

Blanch- Rate, Residence
ing Unit Lb/Hr Time, Sec
Steam 180
3 Sieve Size
11 172
3 Sieve Size
11 172
3 Sieve Size
" 124
2 Sieve Size
Steam 138
1 Sieve Size
11 129
1 Sieve Size
Hot-Water 146
3 Sieve Size
it 154
3 Sieve Size
" 142
2 Sieve Size
" 120
2 Sieve Size
112
1 Sieve Size
100
1 Sieve Size
217

217

90

217

90

217

291

182

182

227

182

227

Peroxidase
Temp Inactivation
°F Slope
180 0.25

190 0. 10

190 0. 12

190 0. 18

190 0. 20

190 0. 16

190 0. 04

" 0. 05

" 0. 08

" 0. 09

11 0. 08

" 0.11

                               -69-

-------
APPENDIX F
Cont'd
Corn-on-Cob

Run
No.
Raw
CN-4

Blanch-
ing Unit
..
5 kw
Feed
Rate,
Lb/Hr
«•

Microwave + 82

Residence
Time, Sec
—

422

Temp,
°F
—

142
Peroxidase
Inactivation
Slope
0. 110

O ve r blanched
Steam Injection
CN-5
CN-6
CN-1
ti
K
Hot-Gas +
100
194
400
224
133
240
140
140
255
0. 008
0.008
0.028
Steam Injection
CN-2
CN-3
CN-7
CN-8
CN-9
CN-11
ti
H
Steam
H
M
Hot -Water
320
202
201
172
266
187
330
390
561
658
435
373
255
260
195
195
195
190
0. 034
0.005
O ve r blanched
Over blanched
0.020
0.04
Red Beets

Run
No.
Raw
BT-4

BT-5
BT-6
BT-1

Blanch-
ing Unit

5 kw
Microwave +
Feed
Rate,
Lb/Hr

85

Steam Injection
239
M
Hot -Gas +
305
69

Residence
Time, Sec

224

93
53
1100

Temp,
°F
.
130

130
130
258
Peroxidase
Inactivation
Slope
1.140
Over blanched

0. 145
0.210
Over blanched
         Steam Injection
                               -70-

-------
APPENDIX  F    Cont'd
Red Beets Cont'd

Run
No.
BT-2
BT-3
BT-9

^Earlier
Pumpkin

Run
No.
Raw
PM-1


Blanch-
ing Unit
ti
ii
Steam
Hot -Water*
Feed
Rate,
Lb/Hr
131
170
155
-
runs with fresh market
Pieces

Blanch-
ing Unit

5 kw
Microwave +

Feed
Rate,
Lb/Hr

50


Residence
Time, Sec
625
390
330
480
beets


Residence
Time, Sec

680


Temp,
°F
258
250
198
200



Temp.
°F

80

Peroxidase
Inactivation
Slope
0.073
0. 100
0. 04
0.04


Peroxidase
Inactivation
Slope
7.43
0.64

Steam Injection
PM-2
PM-3
PM-10
M
it
Hot -Gas +
50
150
200
680
390
330
Steam Injection
PM-11

PM-12

PM-4
PM-5
PM-6
M

140

Steam Injection 65

Steam
it
11
PM-7 Hot -Water
PM-8.
PMr9
M
n

150
224
256
400
200
200
390

1100

766
560
340
227
510
510
140
140
235-
250
250-
265
250-
265
193
194
196
190
192
209
0. 13
0. 10
1.8

0. 10

0.33

0.002
0.047
0.11
7.0
1.7
0.033
                             -71-

-------
APPENDIX F
Cont'd
Spinach
Run Blanch -
No. ing Unit
Feed
Rate,
Lb/Hr
Peroxidase
Residence Temp, Inactivation
Time, Sec °F Slope
Raw
SP-1A  5 kw         17
        Microwave +
        Steam Injection
SP-1B     "         16
SP-2A  Hot-Gas +    N. R.
        Steam Injection
SP-2B     "         N. R.
                                 224
                                  133
                                  330

                                  183
                            140
                            140    Overblanched
                            250    Dried
                            250
O ve r blan che d
                             -72-

-------
APPENDIX G

CHARACTERISTICS OF GRAB SAMPLES FROM HOT-WATER
                       BLANCHER
Commodity
Asparagus
Green Peas
Green Beans
Beets
Pumpkin
Spinach
Sampling Time,
Min
15
30
45
60
15
30
45
15
30
45
60
15
30
45
60
15
30
45
60
15
30
COD,
mg/1
51
72
100
130
1,760
3,900
4,550
150
200
370
490
160
250
400
620
220
450
780
910
190
260
ss,
mg/1
1
0
0
0
113
176
180
1
4
3
10




5
15
15
16
22
29

PH
7.7
7.7
8. 1
7.4
4.6
4.6
4.7
7.5
7.3
7.1
6.9




7.4
7.2
7.0
7.0
6.4
6.4
                           -73-

-------
APPENDIX H
    USDA SCORING SHEETS FOR QUALITY GRADING



              OF CANNED VEGETABLES
                           -74-

-------
                                                                                                                          SHtET  / OF  / SHEETS
rom FV-M*«
                   \JM. DEPARTMENT Of AGRICULTURE
                     CONMJMKR AND MANKKTIPM ••MVICB

                  SCORE  SHEET FOR

                CANNED  ASPARAGUS
                (EFFECTIVE MAY 7. 1963)
                                                      CONT. NO.
                                      r.o.NO.
                                                    CERT.  FORM
                                      mr.no.
                                                    CERT. NO.
                                                                                      HAM AND ADDRESS Of APPLICANT
 NO. .SIZE AN» KIND Of CONTAINEII
 LABEL
  CONTAINER MARK
        OR
  IDENTIFICATION
 NET VEI6HT (OUNCES)
 VACUUM (INCHES)
 DRAINED WEICHT  (OUNCES)
 TYPE
 STVLE
    CUTStfttf,
 SIZE  (SPEARS. TIPS. POINTS)
 COUNT  (SPEARS. TIPS. POINTS)
          7^
    PACTORS
I.   IIQDTJI
II.  COLOB
III. DBPBCT8
IT.  CHillCIU
  1DTM. 300RE
                   SCORE POINTS
 ..
 *°
                     (C)
                     (SStd) 0-<
(A)   17-10
(C)   14-11
(SStd) 0-U*
     1C)   ll-«4*
     (SStd)
                  y •?
  FLAVOR (A, C* OR ISM*)
100
                              It
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   CHAM6C ON CERTIFICATE
                                PBINCIPAL REASONS ron DIM AD INS  PRODUCT
                                                                                                              OFFICIAL INSPECT01
 FEE
 IXPtNSEI
                                                                                                              DATE-"
      lM  Ml*.

-------
      FV-BS4* (7-IS-St)
                                                                                                                                                   SHEET    OF    SMB«T»
U. «. BBPAJCTMBHT Of AOmCULTUMB
CONSUMER AND MARKET** SERVICE
SOME SHEET POt
CANNED GREEN AND WAX BEANS
(Effective Jwly 23, 1961)
CONT. NO.
P.O. NO.
R«F. NO.

CERT. FORM
CERT. NO.
NAME AM* AMREM OF APPLICANT .
I1S£> Si'tft Sf**fT'
Bfr«,lfi fi, /,/„», 4 r^'*
NO.» MSK AND KIND OF CONTAINKH

-------
                                                                                                                         SHEET/ or y SHEETS
ronu FV-364 -18
  (6-I4-5T) •
               U. S. DEPAITTMCNT OF AOmCULTUR*
                 AGRICULTURAL MAKKKTINO MtMVICK
                 SCORE SHEET  FOR
   CANNED WHOLE  KERNEL  (WHOLE GRAIN) CORN
             (EFFECTIVE JULY 30, 1952)
                                                     CONT. NO.
                                                     P.O. NO.
                                                                   CUT.  FORM
                                                      •If .NO.
                                                                    CENT. NO.
                                                                                     NAM AND AODRtt* Of APPLICANT
NO..HJE AMD KIND  Of CONTAIN*
             * Linltiif rilo.
                               i F«rtt»l limitii| r«l«

-------
SHEET/ OF / SHEETS
r«NI FVO44.10 u. S. DEPARTMENT Of AGRICULTURE
l*tM!rl' AGRICULTURAL MARKETING SERVICE
SCORE SHEET FOR
CANNED BEETS
(EFFECTIVE FEBRUARY *, 1955)
tma. INK
'•*•"*'
mr .NO.
CCMT. FOB*
CERT. NO.
NAME AMD
r?-Cl
A»OMM Of AMLICAMT
7ov.«c^ ^"AWWCH
i'«Uy UL.^
„ A^,.
 •0. .(Ill AM HMD Or CONTAINED
 LABEL
                      rtl«.  x P»rti«l
»«tl.i4ii

-------
• &NW PV-M4-SS (10-e-M)
                                                                                                                                           SHEET / Of
• U.S. DEPARTMENT OF AGRICULTURE
CONSUMER AND MARKETING SERVICE
SCORE SHEET FOR
CANNED PUMPKIN and CANNED SQUASH
(EFFECTIVE MARCH 9, 1956)
NO. .SIZE AM RIND OF CONTAINER
CONT. NO.
P.O. NO. CERT. FORM
• IF. NO. CERT. NO.
NAME AND ADDRESS OF APPLICANT
"1 3?£&kJ£l'£ y ^sJi.//o4.*>f*t
/

LAI EL
u/c.
CONTAINER MM
OR
IDENTIFICATI
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°" CASES
SAMPLE NO.
NET •EI6HT (OUNCES)
VACUUM (INCHES)
. FACTORS
COLOR
NO
1
CONSISTENCY
FINISH
DBP1CTS
TOTAL SCORE
SCORE POINTS
20
SO
20
so
100
(Al 18-20
(C) 14-17"
(SStdl 0-lS*
(Al 26-10
(Cl 21-24*
(SStdl 0-20*
(A) 17-20
(C) 14-16
(BStdl 0-11*
(Al 26-10
(C) 21-24*
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NORMAL aAVOR
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APPENDIX
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DATE . /
-2A2/72-
           * Linltlif RuU.

-------
FORM rv-3B*-1M
   (S-90-70)'
U. S. DEPARTMENT OF AGRICULTURE
 CONSUMER AND MARKETING SERVICE
 DEFECT TALLY SHEET FOR CANNED SPINACH
         (EFFECTIVE MARCH 30. 1970)
NAME AND ADDRESS OF APPLICANT
                                                                                GRADE
                                                              DATE

 '. I * t. F

  1 WHOLE LE AT

j '] CUT LEAF OR SL.  f O
                                                                                                     .X -"O
NO., SIZE, AND KINO OP CONTAINER
CUMULATIVI TOTAL (ALL CLASSES)
STBN MATERIAL  29% (A)  JO* <•)

-------
                                       Apoendix I       Vitamin Content of Raw, Blanched, and Canned Vegetables,

                                                       Values in mg/100 g wet weight ( Standard Deviation )
                                                                Blanched Samples
Canned and Stored (Six Months) Samples
            Commodity



            Asparagus
oo
»••
i
            Green Peas
Vitamin Raw Microwave Hot -Gas
B, .22
( -0)

B2 .218
.230
( . 008)

C 18.7
19. n
18. 3
19.2
18. 1
( -5)
Niacin 1.56
1.58
1.52
(.03)

B, . 07
(-0)

Bz . 168
. 173
( . 004)
B6 *



*

. 162
.202
.212
(.03)
13.4
13.4
14.2
14. 9
14. 1
( -6)
1. 80
1.85
1.80
(.03)

. 10
(.0)

. 177
. 170
{ . 005)
.24



. 178
. 177
( .001)
. 183
. 189
( . 004)

11. 1
10.4
10.4
10.6
( • 4)

.70
.75
.71
.76
( .03)
. 14
( .0)

. 176
. 170
.004
.27



Steam
*

.226
. 190
. 172
(.027)
22. 5
22. 0
22. 2
21.4
( -5)

1.40
1. 53
1.40
(.08)

.07
( -0)

. 129
. 125
. 003
. 32



Hot-Water
*

. 198
.208

( . 007)
16.7
19.8
16.7
17. 1
(1.5)

1.60
1.70
1.60
1.68
( .05)
.06
(.0)

. 157
. 143
. 010
.22



Microwave Hot-Gas
.049
.057
(.01)
.104
.087
(.012)

3.79
3.79
(.0 )



.70
.60
.62
.65
( .04)
. 099 . 110
. 100 . 108
(.001) (.001)
.075 .083
.075 .081
(.0) (.001)
.109 .154
. 1 54 . \ 54
. 142 140
( . 025) ( . 008)
Steam Hot-Water
.059
.043
(.011)
. 092
.087
( . 004)

3.69
3. 55
( • 10)



.80
.76
.80
.73
( -03)
. 102
. 103
( .001)
.064
.070
(.005)
.096
. 1'?
. 096
(.015)
.057
. 056
(.001)
. 110
. 104
{ . 004)

3. 55
3.69
( • 10)



.71
.75
.70
.70
( -02)
.089
.089
( -0)
.065
.072
(.005)
.098
114
. 109
( . 008)

-------
                                  Appendix I  Cont'd
          Commodity



          Green Beans
 B,
                                  B,
8
i
Niacih
           Corn
 B,
                         Vitamin Content of Raw, Blanched, and Canned Vegetables,

                         Values in mg/100 g wet weight ( Standard Deviation )
                                                            Blanched Samples
                                                             Canned and Stored (Six Months) Samples
Raw
#


. 12
. 12
.14
. 13
(.01)
.051
.053
.064
( . 007)

.43
.55
.48
.50
(.06)

#


. 120
.109
( .008)



. 18

Microwave
#


.14
. 12
.14
(.01)
.077
.064
.046
(.016)

.59
.65
.70
(.06)


*


. 102
. 115
( . 009)



.23

Hot -Gas
*


. 12
.12
. 12
(.00)
.038
.036
.036
.039
( . 002)
.80
.79
.60
(.11)


#


.112
.120
.006



.16

Steam
*


. 12
. 12
. 12
(.00)
.069
.055
.046
.041
(.012)
.70
.55
.52
.47
(.10)

*


. 106
. 105
(.001)



. 19

Hot -Water
#


. 11
.12
.12
(.01)
.077
.062
.050
.040
(.016)
.65
.61
.51
.50
(.07)

#


.119
.107
( . 008)



. 19

Microwave
.290
.280
( . 007)
.055
.053
(.001)

.049
.051
.053
( . 002)

.35
.36
.38
.33
(.02)

.025
.024
(.001)

.078
.080
( . 001)
.064
.082
.965.
(.008)
Hot-Gas
.386
.411
(.02)
.069
.062
(.005)

.049
.051
.063
( . 008)

.43
.36
.38
.39
.32
(.04)
.026
.025
{ .001)

.077
.082
( . 004)
.082
.078
.071
(.006)
Steam
.290
.300
(.007)
.058
.061
(.002)

.046
.054
.044
( . 005)

.40
.35
.35
.33
.33
(.03)
.025
.026
(.001)

.079
.074
( . 004)
.079
.061
. 076
(.003)
Hot -Water
.295
.290
( . 004)
.053
.058
(.004)

.063
.050
.064
( . 008)

.35
.33
.33
.30
.31
(.02)
.022
.021
(.001)

.071
.070
v (.001)
v ;6«
.076
( . 005)


-------
                                     Appendix I   Cont'd
Vitamin Content of Raw, Blanched, and Canned Vegetables,
Values in mg/100 g  wet weight ( Standard Deviation )
                                                             Blanched Samples
            Commodity

             Corn
             Beets
i
oo
             Pumpkin
             Spinach
Vitamin
Niacin




B2


C
Niacin



A

Niacin




A
B2


C
Raw Microwave
1.42
1.35
1.50
1.36
(.07)
.048
. 074
(.013)
6.9

.250
.231
(.013)
5.78
(.0)
.44
. 53
. 52
.47
(.04)
2. 30
. 065
.079
(.01)
#
2.25
2.25
2. 18
(.04)

.049
.059
(.007)
6.8

.213
. 213
(.00)
5. 05
(.0)
. 38
. 34
.42
. 37
( .03)
4.02
. 156
. 133
(.015)
*
Hot-Gas Steam Hot-Water
2.20
2.00
2. 12
1.93
(• 12)
.062
.074
(.008)
7.5

.263
.256
( .005)
4. 06
(.0)
.66
. 57
. 53
. 53
(.06)
4.21
. 130
. 138
(. 006)
*
2.25
2. 13
2.22
2. 13
(.06)
.035
.054
(.013)
5.6

. 200
. 194
( . 004)
7.91
(.0)
. 32
. 25
.24
. 25
( .04)
3.63
. 094
. 101
(.005)
*
1.97
1.70
2.00
1.98
(.14)
.036
.046
(.007)
7.9

.200
.200
(.0)
4.66
( .0)
. 30
.31
.33
.35
(.02)
3.74
.067
.078
( . 008)
*
                                  Canned and Stored (Six Months) Samples
                               Microwave  Hot-Gas   Steam   Hot-Water
                                                                                                 .94
                                                                                                1.19
                                                                                                1. 10
                                                                                                (.13)
                                   .015
                                   .016
                                  (.001)

                                  4. 1

                                  .075
                                  .078
                                  .088
                                  .075
                                  .006)

                                  3.74
                                  ( .0)

                                   .37
                                    40
                                   .38
                                   .47
                                  (.05)

                                  1.Z8
                                  1.87
                                  ( .14)

                                   . 107
                                   . 109
                                  (.001)
                                             1.00
                                             1.07
                                             1.22
                                             1.20
                                             (.11)
 .014
 .011
(.002)

5.0


 .093
 .094
 .092
 .083
 .005)

3.09
(.0)

 .40
 .45
 .42
 .49
( .04)

1.94
2.57
(.14)

 .095
 .096
 (.001)
          1. 04
          1.00
          1.03
          1. 19
          (.09)
 4. 1

 . 118
 . 102
 . 110
 . 109
( . 008)

 2.98
( .0)

  .28
  .33
  . 32
  .39
 (.05)

 2.90
 3.62
 (.11)

  . 07$
  . 084
( . 004)
           .90
          1.00
           .94
          1.00
          (.05)
  .015     .023
  . 013     . 022
 (.001)   ( .001)
 4. 8


 . 093
 . 088
 . 092
 . 083
(.005)

 5.22
 (.0)

  .23
 . 29
  .27
 -. 32
 ( ". 04)

 4. 06
 4.87
 ( • 13)

  . 088
  .090
 (.001)
             *  Sample Lost

-------
Corn

Beets

Pumpkin



Spinach
Ca
Mg
P

Ca
Mg
P
                             Appendix J    Mineral Content of Raw and Blanched Vegetables,
                                           Values in mg/100 g    wet weight  ( Standard Deviation )
                                                  	Blanched Samples
Commodity
Asparagus


Peas



Beans


Mineral
Ca
Mg
P
Ca
Mg
P
Fe
Ca
Mg
P
Raw
20.9,21.4
15.8, 15.6
68.0,66.0
*
*
*
*
40.0,40.0
28.0,26. 0
36.0,36.0

(.4)
M)
(1.4)




(.0)
(1.4)
(.0)
87.0,79.0 (5.7)

21,6,23.8 (1.6)

9.9,8.5(1.0)
7. 1,6.3(.6)
11.7, 11.4 (.2)

63.5,66.4 (2. 1)
67.3,59.8 (5.3)
17.2,22.7 (3.9)
 Microwave

 22. 1,22. 1 (.0)
 15.4, 15.6 (. 1)
 77.0,77.0 (.0)

 14. 3, 14. 0(.2)
 28.3,28.6 (.2)
106, 102 (3)
1.00, 1.06 (.04)

46.4,45.2 (. 8)
28.2, 30. 4 (1.6)
40.0,40. 0 (. 0)

92.5,90.0(1.8)

25.6,26.4 (.6)

11. 3,6.3 (3. 5)
13. 5, 12. 3 (.8)
22.7,20.2 (1.8)

84.0,88.0(2.8)
91. 5,87. 3 (2.8)
54.2,46.2 (5.7)
                                                                        Hot-Gas
19.2, 19.4 (. 1)
15.2, 15. 2 (.0)
62.0,61. 0 (.7)

14.2, 14. 6 (. 3)
28.4,29.8 (1.0)
114, 114 (.0)
1.05, 1.07 (. 01)

51.2, 52.8 (1. 1)
33.0,33.2 (. 1)
48. 5,47. 5 (.7)

82.0,75.0(4.9)

28. 8,24.4 (3. 1)

13. 5, 13. 5 (. 0)
10.9, 10.9 (. 0)
14.2, 13.6 (.4)

68. 0, 68. O(.O)
65.5,64.5 (.7)
42.7,42.2 (.4)
                                                                          jteam

                                                                            21.9,22. 1  (. 1)
                                                                            14.4, 14.4  (. 0)
                                                                            70.0,70.0  (. 0)

                                                                            13.0, 13.0  (.0)
                                                                            27.2,28.0  (.6)
                                                                            102, 100(1)
                                                                           .97, 1.00 (.02)

                                                                            40. 0,38.4  (1. 1)
                                                                            26. 6,26.4  (. 1)
                                                                            36.4,35.6  (.6)
                                                                            95.0,85.0  (7. 1)
                                                                                   Hot-Water

                                                                                   19.8,20. 5 (.5)
                                                                                   16.3, 16.4 (. 1)
                                                                                   69.0,70.0 (.7)

                                                                                   14.2, 14. 1 (. 1)
                                                                                   28.0,28.6 (.4)
                                                                                   96, 100(3)
                                                                                   1. 04, 1. 03 (.01)

                                                                                   40.4,40.8 (. 3)
                                                                                   26.6,27.6 (. 1)
                                                                                   39.6,37.2 (1.7)
                                                                           22.0,24.8(2.0)    22.0,20.4(1.2)
10.9, 10.5 (. 3)
9.5,9.7 (. 1)
15. 2, 13. 2 (1.4)

63.0,67.0(2.8)
67. 5,63. 5 (2.8)
42.2,42.7 (.4)
10.7,7. 7 (2. 1)
8. 1,6. 3 (1.3)
8.2, 11.2 (2. 1)

45.5,55.5 (7. 1)
49.5,48. 5 (.7)
33.7,29.2 (3.2)
*  Sample Lost

-------
Aooendix K
      COST ESTIMATES FOR COMMERCIAL SCALE BLANCHING


First Cost  -  5 ton/hr Microwave blancher  = $425, 000

Annual Fixed Costs

       Amortization = FC x erf (7%, 5yrs  = .24389)   =    $103,655.
       Space rent                                     =      12, 000.
       Taxes                                          =       5,310.
       Insurance                                      =         850.
       Maintenance   (2.5% of FC/yr)                  =      10, 625.
                                        Total          =    $132,440."
       Hourly fixed cost (1800 hr  yr )                 =          73. 58

Hourly Operating Costs

       Electric power ($.0125/kwh) (210 kw)           =           2.63
       Steam consumption ($1. 00/1000  Ib )             =            .80
       Water consumption ($. 10/100 cu ft  )            =            .05
       Klystron replacement (7  tubes @$9200, 6000
       hr life)                                         =          10.73
       Waste disposal ($.05 /Ib  for BOD&SS)          =            .17
       Labor (1 worker @ $4.40/hr  )                   =           4.40
                                        Total          =          18.78
Total Hourly Cost
                                            Fixed  Cost=          73. 58
                                        Operating  Cost=          18. 78
                                                 Total =          92.36

Cost/lb vegetable blanched (10, 000 Ib/hr)               =            . 00924
Cost/ton vegetable blanched                            =          18.47
                             -85-

-------
Appendix K   Cont'd



First Cost  -  5 ton/hr  Hot-gas blancher  =  $50, 000. 00

Annual Fixed Costs

    Amortization FC x erf  (7%, 5 yrs = .24389)  =  $  12,195.
    Space  rent                                     =      6, 000.
    Taxes                                         =        625.
    Insurance                                     =        100.
    Maintenance  (1. 5% of FC/yr)                  =   	750.

                                         Total     =  $  19,670.

    Hourly fixed cost  (1800 hr yr)                  =         10. 93


Hourly Operating  Costs

    Electric power ( $. 035/kw  )                  =           .61

    Steam consumption ( $  1. 00/1000 Ib )           =           .10

    Water consumption ( $  . 10/100 cu ft )          =           .00

    Gas consumption  ( $. 076/therm  )              =           .89

    Waste disposal ( $ . 05/lb for BOD & SS )       =          .00

     Labor ( 1 worker @ $ 4. 40/hr )                =         4. 40
                                         Total     =  $      6. 00

 Total Hourly Cost
                                     Fixed Cost    =        10. 93
                                 Operating Cost    =         6. 00
                                         Total     =        16.93

 Cost/lb vegetable blanched (  10, 000 Ib/hr )          =          .00169

 Cost/ton vegetable blanched                        =  $      3. 39
                              -86-

-------
Appendex K    Cont'd
First Cost    5 ton/hr Steam blancher    =  $15.000.00
Annual Fixed Costs

   Amortization FC x  erf  (7%,  5 yrs =  . 24389)
   Space rent
   Taxes
   Insurance
   Maintenance  (  1% of FC/yr )
                                            Total
   Hourly fixed cost (1800 hr yr)
=  $  3,660.
      6, 000.
        190.
         30.
   	150.
=  $ 10,030.
          5.57
Hourly Operating Costs

   Electric power { $ . 035/kw  )
   Steam consumption ( $1. 00/1000 Ib )
   Water consumption ( $  . 10/100 cu ft )
   Waste disposal ( $ 0. 05/Ib for BOD & SS )
   Labor  ( 1 Half-time worker @ $4. 40/hr)
           . 13
          2.41
           .00
           .76
          2.20
                                            Total  =  $
          5.50
Total Hourly Cost
                                        Fixed Cost
                                  Operating   Cost
                                             Total
 Cost/lb vegetable blanched  ( 10,000 Ib/hr )

 Cost/ton vegetable  blanched
          5.57
          5.50
         11.07

           .00111
          2.21
                               -87-

-------
Appendix K     Cont'd


First Cost     5 ton/hr  Hot-water blancher  =    $20,000.

Annual Fixed Costs
     Amortization = FC x erf  (7%,  5 yrs  = .24389)   =    $  4,880.
     Space rent                                       =      6, 000.
     Taxes                                           =        250.
     Insurance                                       =         40.
     Maintenance  ( 1% of FC/yr )                     =        200.
                                            Total      =    $  11,370.
     Hourly fixed cost  { 1800 hr yr )                   =           6. 32

Hourly Operating Costs

     Electric power ($. 035/kw)                                   .13
     Steam consumption ($1. 00/1000 Ib)                           1.92
     Water consumption  ( $ . 10/100 cu ft )                       . 08
     Waste disposal ( $ 0. 05/lb for BOD & SS )                    1. 17
     Labor ( 1 Half-time worker @ $4. 40/hr )                      2.20
                                            Total      =    $       5.50

Total Hourly Cost
                                         Fixed Cost   =           6.32
                                    Operating  Cost   =           5. 50
                                              Total   =         11.82
Cost/lb vegetable blanched { 10,000 Ib/hr )            =           .00113
Cost/ton vegetable blanched                            =          2. 36
                            -88-

-------
   SELECTED WATER
   RESOURCES ABSTRACTS
   INPUT TRANSACTION FORM
1. Report No.
2.
3. Accession No.
                   W
  4.  Title LOW Water Volume Enzyme
         Deactivation of Vegetables
  	Before
   7.  Author(s)
          Rails, Jack W.  and Mercer, Walter A.
                   5. Report Date 3-15-73
                   6.
                   8. Performing Organization
                     Re port No.  D-2615
  9.  Organization
          Research Foundation
          National Canners Association
          1950 Sixth Street
  ,,  0     Berkeley.. California   94710
  /-.  SponsoringUrgan.-zafjon
                     U. S. Enviornmental Protection Agency
  15.  Supplementary Notes
          Environmental Protection Agency report
          number, EPA-R2-73-198, May 1973.
                   10.  Project No.
                                                                            5653
                   //.  Contract I Grant No.
                       12060 PAV
                   1J.  Type of Report and
                      Period Covered
                       Final
                       5-1-71 to 11-30-72
  16. Abstract  Four pilot-plant units were operated with asparagus, peas, corn, beans,
     be.ets,  pumpkin and spinach to establish the potential for new blanching systems
     with low wastewater generation.  The systems investigated were microwave,  hot-gas,
     steam,  and hot-water.   Single runs of about one hour duration were made for each
     commodity with each blanching system.   Wastewater volume was measured and
     samples were analyzed for COD, SS, and pH.  The most striking result obtained was
     the  small volume of steam condensate formed during hot-gas blanching. Canned
     samples of vegetable material from each blancher were prepared for quality eval-
     uation after storage. Taste panels showed no significant flavor preference for  sam-
     ples from any individual blanching system.  The system used had no significant
     effect on the vitamin and mineral retention of blanched or canned samples.  The
     oxygen content of canned samples was lowest for hot-gas blanching compared to the
     other three systems.  Estimates of the cost of blanching using commercial-scale
     units gave (dollars/ton blanched):  microwave,  18.47; hot-gas, 3.39; steam, 2.21;
     and hot-water, 2. 36.
  17a. Descriptors
             Blanching,  vegetables, food processing, wastewater, reduced waste
     generation,  microwave blanching, hot-gas blanching, steam blanching, hot-water
     blanching*
  17'b. Identifiers
              Canning  ( food processing }
1 7c. CO WRR Field & Group Q 5D
18. Availability
General
Abstractor
Jack W.
19.
20.
Rails
Security Class.
(Report)
Security Class.
(P'ge)
\ Insti
21. No. of
Pages 88
22. Price
Send To:


WATER RESOURCES SCII-NTIFlC INFORMATION CE!" T ET.
U.S. DEPARTMENT OF THE INTERIOR
WASHINGTON. D C 20240
tution National Canners
Association
WRSIC 102 (REV JUNE 1971)
                                                          MJ.S. GOVERNMENT PRINTING OFFI
-------