EPA-600/3-76-095
October 1976
Ecological Research Series
              BIOLOGICAL, CHEMICAL AND PHYSICAL
   RELATIONSHIPS  IN THE  STRAITS OF  MACKINAC
                                       Environmental Research Laboratory
                                       Office of Research and Development
                                      U.S. Environmental Protection Agency
                                             Duluth, Minnesota 55804

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                 RESEARCH REPORTING SERIES

 Research reports of the Office of Research and Development, U.S. Environmental
 Protection Agency,  have been grouped into  five series. These five broad
 categories were established to facilitate further development and application of
 environmental technology. Elimination of traditional grouping was consciously
 planned to foster technology transfer and a maximum interface in related fields.
 The five series are:

      1.    Environmental Health Effects Research
      2.    Environmental Protection Technology
      3.    Ecological Research
      4.    Environmental Monitoring
      5.    Socioeconomic  Environmental Studies

 This report has been assigned to the ECOLOGICAL RESEARCH series. This series
 describes research on the effects  of  pollution on humans, plant and animal
 species, and materials.  Problems are assessed for their long- and short-term
 influences. Investigations include formation, transport, and  pathway studies to
 determine the fate of pollutants and their effects. This work provides the technical
 basis for setting standards to minimize undesirable changes in living organisms
 in the aquatic, terrestrial, and atmospheric environments.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.

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                                                 EPA-600/3-76-095
                                                 October 1976
BIOLOGICAL, CHEMICAL AND PHYSICAL RELATIONSHIPS IN
             THE STRAITS OF MACKINAC
                        by
     Claire L. Schelske, Eugene F. Stoermer,
        John E. Gannon and Mila S. Simmons
          Great Lakes Research Division
              University of Michigan
            Ann Arbor, Michigan  48109
                  Grant  R802721
                 Project Officer

                  Nelson  Thomas
           Large Lakes Research Station
     Environmental Research  Laboratory-Duluth
            Grosse He, Michigan 48138
     ENVIRONMENTAL RESEARCH LABORATORY-DULUTH
        OFFICE OF RESEARCH AND DEVELOPMENT
       U.S.  ENVIRONMENTAL PROTECTION  AGENCY
               DULUTH,  MINNESOTA  55804

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                              DISCLAIMER


This report has been reviewed by the Environmental Research Laboratory-Duluth,
U.S. Environmental Protection Agency, and approved for publication.   Approval
does not signify that the contents necessarily reflect the views and policies
of the U.S. Environmental Protection Agency, nor does mention of trade names
or commercial products constitute endorsement or recommendation for use.
                                       ii

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                                  FOREWORD
     Our nation's freshwaters are vital for all animals and plants, yet our
diverse uses of water	for recreation, food, energy, transportation, and
industry	physically and chemically alter lakes, rivers, and streams.  Such
alterations threaten terrestrial organisms, as well as those living in water.
The Environmental Research Laboratory in Duluth, Minnesota develops methods,
conducts laboratory and field studies, and extrapolates research findings

     —to determine how physical and chemical pollution affects aquatic
       life

     —to assess the effects of ecosystems on pollutants

     —to predict effects of pollutants on large lakes through use of models

     —to measure bioaccumulation of pollutants in aquatic organisms that
       are consumed by other animals, including man

     This report, part of our program on large lakes, details our findings
in the Straits of Mackinac, that waterway connecting Lake Michigan and Lake
Huron.


                                       Donald I. Mount, Ph.D.
                                       Director
                                       Environmental Research Laboratory
                                       Duluth,  Minnesota
                                     111

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                                 CONTENTS
List of Figures	    ix

List of Tables	xiii

Acknowledgments	    xv

I     Introduction  	     1

        1.1  Objectives	     1
        1.2  Current Patterns in the Straits Region 	     2
        1.3  Description of the Study Area	     4
        1.4  Literature Cited 	     8

II    Conclusions	    10

III   Description of Physical-Chemical Conditions and Phyto-
        plankton Community Parameters.  C. L. Schelske,
        M. S. Simmons and L. E.  Feldt	    14

        3.1  Methods and Materials	    14
               Shipboard analyses 	    14
               Laboratory analyses  	    16
        3.2  Epilimnetic Averages and Seasonal Variation  	    17
               Water temperature	    17
               Specific conductance 	    20
               Hydrogen ion concentration 	    21
               Secchi transparency  	    21
               Chlorophyll a	    21
               Soluble reactive  silica  	    21
               Nitrate nitrogen  	    22
               Total phosphorus	    22
        3.3  Physical-Chemical Conditions in August 	    23
               Water temperature	    23
               Specific conductance 	    24
               Hydrogen ion concentration	    24
               Silica	    24
        3.4  Physical-Chemical Conditions in September  	    25
               Water temperature	    25
               Specific conductance 	    26
               Hydrogen ion concentration	    26
               Silica	    26

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        3.5  Physical-Chemical Conditions in October
               Water temperature
               Specific conductance
               Hydrogen ion concentration .............
               Silica .......................     28
        3.6  Correlation of Physical, Chemical and Phyto-
               plankton Community Parameters  ...........     ^9
               Relationships among temperature,  pH , nitrate and
                 silica ......................     29
               Relationship of nutrients and chlorophyll   .....     ^7
        3.7  Literature Citied  ..................     39

IV    Water Masses and Dilution of Surface Waters in the
        Straits Area.  T. B. Ladewski ...............     ^1
        4.1  Results  .......................     42
        4.2  Literature Cited ...................     53

V     Multivariate Statistical Analysis of Physical, Chemical
        and Phytoplankton Community Parameters.   R. A.  Moll ....     56

        5.1  Methods  .......................     56
        5.2  Results  .......................     57
               Factor analyses  ..................     57
               Cluster analyses ..................     58
        5.3  Literature Cited ...................     70

VI    Distribution and Abundance of Phytoplankton.  E.  F.
        Stoermer, R. G. Kreis, Jr., and T. B. Ladewski   ......     72
        6.1  Materials and Methods   ................     72
        6.2  Taxonomic Composition of the Phytoplankton
               Assemblage  .....................     76
        6.3  Distribution of Major Species  ............     81
        6.4  Ordination Analysis of Phytoplankton Assemblages ...     99
               Near-surface associations in October ........     99
               Hypolimnetic associations in October ........    102
               Wear-surface associations in September .......    105
               Hypolimnetic associations in September .......    109
               Near-surface associations in August  ........    109
               Hypolimnetic associations in August  ........    116
        6.5  Comparison of Temperature-Conductivity and Phyto-
               plankton Community Patterns  ............    116
               Distribution of chemical -physical parameters at
                 5 m during October  ................    125
        6.6  Literature Cited ...................    130

VII   Crustacean Zooplankton of the Straits of Mackinac and
        Northern Lake Michigan.  J. E. Gannon, K. S. Bricker and
        T. B. Ladewski  ......................    133
                                    vi

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        7.1  Introduction	   133
        7.2  Methods and Materials	   133
               Field	   133
               Laboratory	   136
               Analytical	   136
        7.3  Results and Discussion	   138
               Straits of Mackinac	   138
               Northern Lake Michigan	   172
        7.4  Summary	   188
        7.5  Literature Cited 	   189

VIII  Comparison of Phytoplankton and Nutrients in Northern
        Lake Michigan and the Straits of Mackinac	   191

        8.1  Physical-Chemical Conditions 	   191
        8.2  Phytoplankton	   195
        8.3  Summary	   200

IX    Appendices

        A.  Physical and chemical data collected in the vicinity
              of the Straits of Mackinac, 1973	   204

              A.I   Cruise 1, August 1973	   204
              A.2   Cruise 2, September 1973	   209
              A.3   Cruise 3, October 1973	   216

        B.  Primary productivity at 5 m.  Data in mgCm~3hr~1  .  .  .   224

              B.I   Cruise 1, August 1973	   224
              B.2   Cruise 2, September 1973	   225
              B.3   Cruise 3, October 1973	   227
        C.  Depth profiles of north-south transects 	   229

              C.I   Transect 01-06, Cruise 1,  August 1973 	   229
              C.2   Transect 01-06, Cruise 2,  September 1973  ...   229
              C.3   Transect 01-06, Cruise 3,  October 1973  ....   230

              C.4   Transect 07-10, Cruise 1,  August 1973 	   231
              C.5   Transect 07-10, Cruise 2,  September 1973  .  .  .   231
              C.6   Transect 07-10, Cruise 3,  October 1973  ....   231
              C.7   Transect 13-16, Cruise 1,  August 1973 	   232
              C.8   Transect 13-16, Cruise 2,  September 1973  .  .  .   232
              C.9   Transect 13-16, Cruise 3,  October 1973  ....   233

              C.10  Transect 17-23, Cruise 1,  August 1973 	   233
              C.ll  Transect 17-23, Cruise 2,  September 1973  .  .  .   234
              C.12  Transect 17-23, Cruise 3,  October 1973  ....   234

              C.13  Transect 24-31, Cruise 1,  August 1973 	   235
              C.I4  Transect 24-31, Cruise 2,  September 1973  ...   236
              C.15  Transect 24-31, Cruise 3,  October 1973  ....   237

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      C.16  Transect 32-37, Cruise 1, August 1973 	   238
      C.17  Transect 32-37, Cruise 3, October 1973  ....   238
      C.18  Transect 40-48, Cruise 2, September 1973  . . •   239
      C.19  Transect 40-48, Cruise 3, October 1973  ....   240

D.  List of species found in phytoplankton collections  . .   241

E.  Proof that a conservative parameter can be expressed
      as a linear combination of other conservative
      parameters	   250
F.  Counts of zooplankton from vertical net tows	   252

      F.I  Cruise 1, August 1973	   252
      F.2  Cruise 2, September 1973	   256
      F.3  Cruise 3, October 1973.	   260
      F.4  Northern Lake Michigan, September 1973	   265
                          vnx

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                             LIST OF FIGURES


Number                                                              Page

  1.1    Map of stations in the Straits survey area	     3

  3.1    Flow chart illustrating sample processing of 4iscrete
           depth samples, Straits of Mackinac 1973	    15

  4.1    Temperature-conductivity plot for October 5-m samples  .  .    43
  4.2    Geographic locations of regions identified in the
           temperature-conductivity plot of Figure 4.1  	    44
  4.3    Percent of Lake Michigan water at 5 m for October  ....    46
  4.4    Percent of Lake Huron water at 5 m for October	    47
  4.5    Percent of St. Marys River water at 5 m for October  ...    48
  4.6    Temperature-conductivity plot for September 5-m samples.  .    50
  4.7    Geographic locations of the regions identified on the
           basis of the T-C plot of Figure 4.6	    51
  4.8    Temperature-conductivity plot for August 5-m samples ...    54
  4.9    Geographic locations of the regions identified on the
           basis of the T-C plot of Figure 4-8 for September
           samples	    55

  5.1    Surface water distribution in August 	    60
  5.2    Five-meter water distribution in August  	    61
  5.3    Ten-meter water distribution in August 	    62
  5.4    Surface water distribution in September  	    63
  5.5    Five-meter water distribution in September 	    64
  5.6    Ten-meter water distribution in September	    65
  5.7    Surface water distribution in October  	    66
  5.8    Five-meter water distribution in October	    67
  5.9    Ten-meter water distribution in October  	    68

         Distribution of:
  6.1      total algal cell counts	    79
  6.2      blue-green algae 	    80
  6.3      green algae	    80
  6.4      diatoms	    82
  6.5      Asterionella formosa 	    83
  6.6      Cyclotella comta 	    83
  6.7      Cyclotella. ocellata	    84
  6.8      Cyclotella operculata  	    84
  6.9      Cyclotella ndchiganiana	    86
                                    IX

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Number                                                              Page

  6.10     Cyclotella stelligera  	    86
  6.11     Fragilaria crotonensis 	
  6.12     Synedra filiformis 	    87
  6.13     Rhizosolenia eriensis  	
  6.14     Tabellaria fenestrata  	    ^
  6.15     Tabellaria fenestrata var. intermedia  	    90
  6.16     Chrysococcus dokidophorus  	
  6.17     Chrysosphaerella longispina  	    91
  6.18     Phodomonas minuta var. nannoplanctica  	    93
  6.19     Cryptoncnas ovata  	    93
  6.20     Ankistrodesmus species #3  	    '
  6.21     Crucigenia guadrata  	    94
  6.22     Eutetraworus species #1	    95
  6.23     Gloeocystis planctonica  .....  	    95
  6.24     Oocystis spp	    97
  6.25     Anabaena flos-aquae  	    97
  6.26     Anacystis incerta  	    98
  6.27     Anacystis thermalis  	    98
  6.28     Gomphosphaeria lacustris  	   100
  6.29     Oscillatoria bornetii  	   100
  6.30   October 5-m sample ordination plots   	   101
  6.31   Geographic locations of 5-m October phytoplankton
           communities	103
  6.32   Ordination plots for October surface  and  subsurface
           samples	104
  6.33   September 5-m water sample  ordination plots   	   108
  6.34   Geographic locations of 5-m September phytoplankton
           communities	110
  6.35   Ordination plots for September surface and subsurface
           samples	112
  6.36   August 5-m water sample ordination plots  	   113
  6.37   Geographic locations of 5-m August phytoplankton
           communities	115
  6.38   Ordination plots for August surface and subsurface
           samples	117
  6.39   Phytoplankton trends on the T-C plane	123
         Cell densities for:
  6.40     Cyclotella michiganiana on the T-C  plane for  October  .  .   126
  6.41     Cyclotella ocellata  	   127
  6.42     Cyclotella stelligera	128
  6.43   Trends of physical and chemical parameters in the T-C
           plane	129

  7.1     Location of zooplankton sampling stations in northern
           Lake Michigan,  September  1973	135
  7.2     Distribution and abundance  (numbers of individuals  per
           m3)  of total crustacean zooplankton in  the Straits of
           Mackinac on three cruises  	   141

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Number                                                              Page

  7.3    Distribution and abundance (numbers per m3 and percent
           composition) of calanoid copepods in the Straits
           region	142
         Distribution and abundance of:
  7.4      Diaptomus oregonensis in the Straits region  	  143
  7.5      Diaptomus minutus in the Straits region	144
  7.6      Diaptomus ashlandi in the Straits region	145
  7.7      Diaptomus sicilis in the Straits region	146
  7.8      Diaptomus spp. copepodids in the Straits region  ....  147
  7.9      Limnocalanus macrurus in the Straits region  	  149
  7.10     Senecella calanoides in the Straits region 	  150
  7.11     Epischura lacustris in the Straits region  	  151
  7.12     cyclopoid copepods in the Straits region 	  152
  7.13     Cyclops bicuspidatus thomasi in the Straits region . . .  153
  7.14     Cladocera in the Straits region	154
  7.15     Daphnia galeata mendotae in the Straits region 	  155
  7.16     Daphnia retrocurva in the Straits region 	  157
  7.17     Daphnia longiremis in the Straits region 	  158
  7.18     Holopedium gibberum in the Straits region	159
  7.19     Leptodora kindtii in the Straits region  	  160
  7.20     Eubosmina coregoni in the Straits region 	  161
  7.21     Bosmina longirostris in the Straits region 	  162
  7.22     Diaphanosoma leuchtenbergianum in the Straits region . .  164
         Zones of similarity in community structure of
           crustacean zooplankton in the Straits region during:
  7.23     August 1973	165
  7.24     September 1973 as determined by principal component
             analysis	166
  7.25     October 1973 as determined by principal component
             analysis	167
         The ratio of calanoid copepods to cladocerans and
           cyclopoid copepods in the Straits region during:
  7.26     August 1973	173
  7.27     September 1973	174
  7.28     October 1973	175
  7.29   Distribution and abundance (numbers of individuals  per
           m3) of total crustacean zooplankton in northern Lake
           Michigan during September 1973 	  176
         Distribution and abundance of:
  7.30     calanoid copepods in northern Lake Michigan  	  177
  7.31     Diaptomus spp. copepodids in northern Lake Michigan  . .  178
  7.32     Diaptomus oregonensis in northern Lake Michigan  ....  179
  7.33     Diaptomus sicilis in northern Lake Michigan  	  180
  7.34     cyclopoid copepods in northern Lake Michigan 	  182
  7.35     Cladocera in northern Lake Michigan	183
  7.36     Daphnia galeata mendotae in northern Lake Michigan . . .  184
  7.37     Daphnia retrocurva in northern Lake Michigan 	  185
  7.38     Eubosmina coregoni in northern Lake Michigan 	  186
  7.39     Holopedium gibberum in northern Lake Michigan	187
                                  XI

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Number
  8.1    Location of northern Lake Michigan stations sampled
           20-23 September 1973 immediately after the sampling
           of the Straits survey area
         Distribution of:
  8.2      Anacystis incerta  ...................  198
  8.3      Anacystis thermalis  ..................  198
  8.4      Fragilaria crotonensis .................  199
  8.5      Cyclotella stelligera  .................  199
  8.6      CyclotelJa comta ....................  200
  8.7      Cyclotella michiganiana  ................  201
  8.8      Asterionella formosa  ..................  201
  8.9      Cyclotella ocellata  ..................  202
  8.10     Cyclotella operculata  .................  202
                                  XII

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                              LIST OF TABLES
Number

  1.1    Characteristics of epilimnetic waters, summer 1970 ....    6
  1.2    Samples collected on three cruises in 1973 	    6
  1.3    Approximate depths and locations of stations in and near
           the Straits of Mackinac  	    7

  3.1    Averages of environmental parameters of epilimnetic waters
           on three cruises in the Straits of Mackinac, 1973  ...   18
         Correlation of data for:
  3.2      all cruises, all depths	   30
  3.3      all cruises, 5-tn depths with no missing values	   30
  3.4      August—all stations, all depths	   31
  3.5      September—all stations, all depths	*.   31
  3.6      October—all stations, all depths  	   32
  3.7      Stations 01-06, all cruises, all depths  	   32
  3.8      Stations 07-10, all cruises, all depths  	   33
  3.9      Stations 11-12, all cruises, all depths  	   33
  3.10     Stations 13-23, all cruises, all depths  	   34
  3.11     Stations 24-31, all cruises, all depths  	   34
  3.12     Stations 32-37, all cruises, all depths  	   35
  3.13     Stations 38, 39, 49, 50, all cruises, all depths ....   35
  3.14     Stations 40-45, all cruises, all depths  	   36
  3.15     Stations 46-48, all cruises, all depths  	   36
  3.16   Correlations of rate of carbon fixation, Secchi disc
           transparency, and concentration of silica, nitrate
           and total phosphorus with chlorophyll a  	   38

  4.1    Sources of water with ranges of temperature and conduc-
           tivity for regions MJ , HI and Sj in Figure 4.2	   45
         Summary of nitrate, silica, temperature, and conduc-
           tivity values for:
  4.2      September	   52
  4.3      August	   52

  5.1    Factor analysis of Straits data	   58

  6.1    Example of tabulation of phytoplankton counts  	   74
  6.2    Species and data processing code for phytoplankton used
           in the principal component analysis  	   75
                                  xiii

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Number                                                              Page

  6.3    Results of the PCA of 5-m phytoplankton samples for the
           first three principal components 	
  6.4    Phytoplankton in the Straits of Mackinac	   78
  6.5    Cell densities at Station 29 above, in and below the
           thermocline for August, September and October cruises  .  106
  6.6    October phytoplankton cell densities	
  6.7    September phytoplankton cell densities 	
  6.8    August phytoplankton cell densities  	
  6.9    Values of R2 and related statistics from regressions
           of cell densities against temperature and conduc-
           tivity for the most abundant taxa	H9
  6.10   Values of R2 from regressions of cell densities
           against temperature and conductivity for less abun-
           dant taxa	H9
  6.11   Values of R2 and SD from regressions of physical-
           chemical parameters against temperature and conduc-
           tivity 	130

  7.1    List of crustacean zooplankton species collected in
           the Straits of Mackinac region during 1973 	  139
         Distribution of zooplankton during:
  7.2      August 1973	168
  7.3      September 1973	170
  7.4      October 1973	171

  8.1    Averages of environmental parameters of epilimnetic
           waters in Lake Michigan, September 1973	193
         Summary of relationships between T-C patterns and
           phytoplankton community patterns of:
  8.2      August samples	196
  8.3      September samples  	  196
  8.4      October samples	197
                                  xiv

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                             ACKNOWLEDGMENTS
The cooperation and assistance of many persons were essential in complet-
ing this project.  The retired U.S. Coast Guard buoy tender MAPLE was
provided, on short notice by the University of Michigan, as a research
vessel to substitute for the R/V INLAND SEAS which had been decommissioned
a few weeks earlier due to the need for extensive repairs.  Our Marine
Superintendent Clifford Tetzloff, Captain Richard Thibault and the ship's
crew provided excellent working facilities under these unusual conditions.
Among those who should be acknowledged for their capable assistance in
collecting and processing samples were Kenneth White, Beth Bowman,
Jim Kubus, Denny Berry, Jenny Wagner, Ann Stevens, Kathy Bricker,
Jill Goodell and Dave Rofritz.  Larry Horning did the drafting work on
many of the figures.  Most of the extensive tabular material was prepared
by Janine Graham.  Special credit should be given to Norah Daugherty who
typed the final text and persevered through the complexities of assembling
all the materials in final form.
                                    xv

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                                SECTION I

                              INTRODUCTION
The Straits of Mackinac, from the standpoint of physical dynamics, is a
unique area in the Laurentian Great Lakes.  It is unique in that the
Straits connect two lakes with the same water level, and although there
is a net water transport from Lake Michigan to Lake Huron the flow os-
cillates between the two lakes.  Outflows at other points in the Great
Lakes system are due to differences in water levels.

The oscillatory flow resulting from the connection of two lakes with the
same water level would be expected to produce complicated physical dynam-
ics and possibly a unique biological environment.  The physical processes
have been studied infrequently (Powers and Ayers I960; Murty and Rao
1970; FWPCA 1967) .  Saylor and Sloss (In press) measured currents and
water movements in the Straits during the time our study was conducted.

The biology and ecology of the Straits of Mackinac, northern Lake
Michigan and northern Lake Huron are poorly known.  The benthos has been
studied by Henson (1962, 1970) .  To our knowledge there have been no
investigations on the plankton—the limited data available are reviewed
in Sections VI and VII, which present our results on phytoplankton and
zooplankton.  Likewise, little is known about the phytoplankton produc-
tivity and major nutrients in the Straits of Mackinac.  Indications of
accelerated eutrophication have been reported for Lake Michigan in recent
years (Beeton 1969; Schelske and Stoermer 1971), but the impact of inputs
of Lake Michigan water on eutrophication and primary productivity in the
receiving waters of the Straits of Mackinac and Lake Huron has not been
assessed.  A review of the biological and chemical conditions in rela-
tion to the eutrophication and trophic status of Lake Michigan has been
completed recently (Schelske, In press) .

Our study was initiated in late August 1973 with data being collected on
three cruises:  30 August-1 September, 16-18 September and 6-8 October.
The purpose of this investigation was to gather baseline data on environ-
mental quality in the Straits of Mackinac and to use these data as out-
lined in the objectives.
1.1 OBJECTIVES

1)  To evaluate the effect of input of water from Lake Michigan on water

                                    1

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 quality  in  the  Straits  of Mackinac and in the northern part of Lake
 Huron.

 2)   To identify water masses  in  the  Straits of Mackinac, northern Lake
 Huron and  the  St. Marys River, by

           a) measuring  chemical  characteristics,
           b) measuring  primary productivity of phytoplankton,
           c) determining the  standing crop, species composition, and
                 diversity estimates  of phytoplankton assemblages,
           d) determining the  standing crop and species composition of
                 zooplankton,  and
           e) measuring  concentrations of phosphorus.

 3)   To  evaluate our results in relation to other studies and available
 data and to assess  whether  more  detailed studies of input from Lake
 Michigan,  including estimates of water transport, will be needed to
 determine  the  significance  of inputs of water from Lake Michigan on water
 quality  in Lake Huron.

 4)   To use our data to  assess water  quality.
 1.2 CURRENT PATTERNS IN THE STRAITS  REGION

 Although  currents in the survey  region  (Fig. 1.1) are complicated  and
 highly variable,  several generalizations  can be made about water move-
 ments. Detour Passage,  in the northeastern corner of the survey area,
 serves as one mouth  of  the St. Marys River, which empties Lake  Superior
 into northern Lake Huron.   Total net flow at Detour Passage was measured
 as  2000 m3/sec (Powers  and Ayers 1960).   It was shown from drift bottles
 and dynamic height calculations  that the  St. Marys River water  is  carried
 east or west with little tendency  to move south in the survey area and
 that generally there is  counterclockwise  surface circulation in the east-
 central part of the  survey area  (Ayers  et al.  1956).

 Currents  at Detour Passage may be  considered reasonably constant in
 comparison  to the highly variable  currents at  the Straits.  The average
 net  current in the Straits of Mackinac  was eastward and ranged  from
 1500-1900 m3/sec  (Powers and Ayers 1960;  FWPCA 1967; Saylor and Sloss,
 In press) .   Extreme  variations are due  mainly  to the 50-60 hr seiche
between Lake  Michigan and  Lake Huron.   The net flow typically changes
 from 10,000 m3/sec in one  direction  to  a  flow  of equal magnitude in the
 opposite  direction in a  period of  only  24 hr.  During only a small frac-
 tion of a month is the  instantaneous net  flow  in the Straits near  the
average 1500-1900 m3/sec.   Saylor  and Sloss (In press) and FWPCA (1967)
 found  net transport  commonly exceeding  20,000  m3/sec in either  easterly
or westerly directions.   Such a  large pulse of water traveling  .18 m/sec
for  12 hr moves about 8  km, which may be  taken to be an estimate of a
mixing  radius  near the  Straits.  Ayers  et al.  (1956) showed that surface
water,  after  passing through the Straits  from  Lake Michigan, generally

-------
u>
          46*00'
          45"50'
                LAKE   ,03
             MICHIGAN
"^U
 BOIS  ^-^
BLANC      /
ISLAND    jl_
        *»

/
                                                                         "28
                                                                         "27
                                                                         "25



                                                                         "24


                                                                    tORDWOOD
                                                                     POINT s--
                                                                        LAKE
                                                                       HURON
          45f301
                                -84*45'-
                                                      -84*30'-
                                                                           -84*15'
                                                                                                     POINT>-
                                                                                                  ' DETOUR "48

                                                                                                   DETOUR^
                                                                                                   PASSAGE —
                                                                                                         '46
                                                                                                          <45—
                                                                                                          (44-
                                                                                                 84*00-
                              Figure 1.1.  MAP  OF STATIONS IN THE STRAITS SURVEY AREA.

-------
 flows  southeastward  along  the  southern  shore, and that surface current
 speeds near  Bois Blanc  Island  were about 4 km/day.  From Figure 1.1 it
 is  clear  that  stations  are,  in general, spaced within this mixing radius
 and that  this  mixing radius  is fairly large compared with the size of
 the survey area.

 Despite the  extensive mixing,  relatively little exchange occurs in the
 Straits between the  epilimnion and hypolimnion.  Powers and Ayers (1960)
 on  6 August  1957 found  the flow below the thermocline was westerly at
 1640 m3/sec  while  the surface  flow was easterly at 3200 m3/sec.  Saylor
 and Sloss  (In  press)  found 100-day average flows (9 August 1973 to
 13  November  1973)  of  3320 m3/sec easterly above 20 m and 1400 m3/sec
 westerly below 20  m.  They also found the greatest difference when the
 thermocline  was most  strongly  developed.  Before the breakdown of the
 thermocline  on about  13 September 1973, current velocities above 20 m
 (taken to  be the location of the therroocline)  averaged about 7 cm/sec
 easterly but below 20 m were about 7 cm/sec westerly.  After 13 Septem-
 ber, the average flow of the current was easterly at 3.0 cm/sec above
 20  m and 1.5 cm/sec below 20 m.  Consequently the average currents above
 and below  the  thermocline are  not only independent,  they are opposite in
 direction  during well developed summer stratification.  After the break-
 down of the  thermocline, average currents at all depths would appear to
 be  easterly  in the Straits of  Mackinac.

 Knowledge  of subsurface currents outside the immediate vicinity of the
 Straits is limited.  Ayers et  al. (1956) conducted cruises in the survey
 area on 28 June, 27  July and 25 August 1954.  On the basis of the dynamic
 height technique (Ayers 1956),  bottom currents in the deep regions to the
 north  and  east of  Bois Blanc Island were westerly.  Ayers et al. (1956)
 predicted, on  the  basis of these currents, that upwellings would occur
 west of Detour Passage along the northern shore.  Upwelling was found in
 this area  in two out of our three 1973 cruises.  It is reasonable to
 expect that  the westward bottom currents continue along the deep channel
 north  of Mackinac  Island and then south to the Straits of Mackinac, where
 they appear  as the westward hypolimnetic currents in the Straits.  The
 absence of upwellings in October 1973 coincided with the absence of
 thermal stratification and disappearance of the westward hypolimnetic
 flow in the  Straits, suggesting that upwelling may be a regular feature
 along  the northern shore while  the Straits are thermally stratified.

 Currents of  northern Lake Michigan have been studied (e.g. Ayers et al.
 1958;  FWPCA  1967)  but very little information is available for regions
near the Straits because they  are, for the most part, relatively shallow.
 Consequently it is not possible to determine from previous studies how
 far the deep westward currents  extend into Lake Michigan.
1.3 DESCRIPTION OF STUDY AREA

The study was restricted to an area that could be sampled from a research
vessel in 3 or 4 days.  Factors that entered into consideration were

-------
logistic, i.e., the distance  that could be traversed by the vessel, and
scientific personnel which were not adequate for several days of  contin-
uous operation.  Based on these considerations  the study area extended
90 km from west to east and was 50 km north-south from Station 48 to
Station 40.  It was bounded on the west by stations running north-south
between St. Helena Island and Waugoshance Point in Lake Michigan and on
the east by stations between Point Detour and Forty Mile Point in Lake
Huron (Fig. 1.1).

Locations of stations were based on three premises:   1) that there was a
net transport of water from east to west, i.e., that water flows out of
Lake Michigan through the Straits of Mackinac into Lake Huron;  2) that
water from Lake Superior flows through the St.  Marys River into Lake
Huron, with part of the water flowing into Lake Huron through Detour
Passage near Station 48; 3) that water characteristics at various points
in the study area would result from mixtures of varying proportions of
waters from Lake Michigan, Lake Superior, and Lake Huron.

Fifty stations were laid out, mostly on north-south transects so water
characteristics could be determined for different parts of the study
area.  Stations 01-06, for example, were placed to evaluate and to assess
quality and characteristics of water flowing out of Lake Michigan.  In
actuality our results showed evidence of mixing of Lake Michigan and
Lake Huron surface waters on this transect and the presence of a subsur-
face flow from Lake Huron waters to Lake Michigan.

Stations 07-10 were located between Mackinac Island and Rabbit Back Peak
to sample water flowing through the Straits on the north side of Mackinac
Island; Stations 13-23 were located between Bois Blanc Island and the
lower peninsula of Michigan to sample water flowing through the Straits
on the south side of Bois Blanc Island; and Stations 11 and 12 were
located to sample the water flowing through the narrow channel between
Mackinac and Bois Blanc Island.  Stations were located between Forty Mile
Point and the Detour Passage to assess water quality in upper Lake Huron
and to measure the influence of water flowing out of Lake Superior through
the St. Marys River.

Chemically the waters in the three lakes are quite distinct, and a number
of parameters are indicative of water masses from the three lakes
(Table 1.1).  Lake Huron waters in the study area are largely a mixture
of waters from Lake Michigan and Lake Superior with chemical character-
istics determined by the proportion of water from the two lakes.

Water temperature and specific conductance were useful in identifying
water masses.  During the summer, water temperatures in Lake Superior are
somewhat colder than those in the surface waters of Lake Michigan.  At
other times of the year, differences in water temperature may not be as
great.  Specific conductance on the other hand is always much less in
Lake Superior than in Lake Michigan, with expected values for Lake
Superior being 100 umho @ 25°C and for Lake Michigan about 265 ymho @
25°C (Table 1.1).  Values for Lake Huron are intermediate, about  200 umho
@ 25°C in the northern part of the lake.

-------
Table  1.1.   CHARACTERISTICS OF EPILIMNETIC WATERS, SUMMER 1970.  Averages
                  from  Schelske and Roth  (1973, p. 65-67).



Specific
conductance
Lake
N. Michigan
N . Huron
Superior
pH ymho @ 25° C
8.50
8.50
8.04
261
192
95

Sulfate
(mg/1)
15.5
10
1.5

Chloride
(mg/D
7.22
4.6
1.1
. 	 _____ 	 — —
Nitrate
(mg N/l)
0.129
0.139
0.254
	 	 "••*
Silica
(mg Si02/D
0.27
1.07
2.28
 As  pointed  out  recently  (Schelske 1975), silica and nitrate nitrogen can
 be  used  to  characterize  water masses in the upper Great Lakes.  Contrast-
 ed  with  the conservative ions which are more dilute in Lake Superior,
 these nutrients are more concentrated in Lake Superior and are diluted
 when mixed  with waters from Lake Michigan  (Table 1.1).  Concentrations
 of  silica in Lake  Superior waters, in addition to being relatively large
 (>  2.0 mg/1), also vary  less seasonally than those in Lake Michigan,
 which range from less than 0.1 mg/1 during late summer to more than
 1.0 mg/1 during the period when the lake is homothermous (Schelske, In
 press).  Values for nitrate do not differ as much between the two lakes,
 but in the  summer, waters from Lake Superior contain at least twice as
 much nitrate as those in the outflow from Lake Michigan.

 Other chemical  parameters, including calcium, sodium, magnesium, potas-
 sium and alkalinity, vary greatly among the three lakes.  Concentrations
 of  phosphorus also vary  with the smallest concentrations in Lake Superior
 and the  largest concentrations in Lake Michigan.

 More  than 800 samples (Table 1.2) were collected at discrete depths as
 part  of  this  study; physical-chemical data tabulated in Appendix A were
Table 1.2.  SAMPLES COLLECTED ON THREE CRUISES IN 1973.  Each sample re-
presents data collected at one depth.  C-14 samples include dark samples.



Stations not sampled
C-14 samples at 5 m
Total samples

1
38 - 50
69
217
Cruises
2
13, 20, 21, 32-37
130
272

3
None
156
317

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obtained from these samples.  Samples for phytoplankton were also taken
at the discrete depths, but samples for zooplankton were obtained with
vertical net hauls.  Specific sampling depths for the discrete samples
are listed with the data in Appendix A.

The latitude, longitude and approximate depths for the 50 stations
sampled are listed in Table 1.3.
Table 1.3.  APPROXIMATE DEPTHS AND LOCATIONS OF STATIONS IN AND NEAR THE
                           STRAITS OF MACKINAC.

Station
number
ST-01
ST-02
ST-03
ST-04
ST-05
ST-06
ST-07
ST-08
ST-09
ST-10
ST-11
ST-12
ST-13
ST-14
ST-15
ST-16
ST-17
ST-18
ST-19
ST-20
ST-21
ST-22
ST-2'3
Depth
(meters)
14
20
33
18
14
11
12
31
41
24
24
12
14
24
24
10.5
10
13
22
13
15
18
15

Latitude
45°45.8
45°47.3
45°48.7
45°50.3
45°51.5
45°52.8
45°54.8
45°54.3
45°53.0
45°53.2
45°50.8
45°50.4
45°47.9
45°46.5
45°45.0
45°43.4
45° 41. 2
45°42.1
45°42.9
45°43.8
45°42.6
45°41.8
45°41.0
Location
Longitude
84°51.0
84°51.0
84°51.0
84°51.0
84°51.0
84°51.0
84°42.1
84°41.0
84°40.0
84°38.9
84°35.8
84°37.3
84°35.0
84°35.0
84°35.0
84°35.0
84°30.0
84°30.0
84°30.0
84°30.0
84°25.0
84° 25.0
84°25.0

-------
 Table 1.3 continued.

Station
number
ST-24
ST-25
ST-26
ST-27
ST-28
ST-29
ST-30
ST-31
ST-32
ST-33
ST-34
ST-35
ST-36
ST-37
ST-38
ST-39
ST-40
ST-41
ST-42
ST-43
ST-44
ST-45
ST-46
ST-47
ST-48
ST-49
ST-50

Depth
(meters)
16.5
24
33
51
61
69
44
23
19
19
36
45
50
49
19
38
6
46
73
73
110
76
30
22
17
57
39


Latitude
45°40.9
45°43.2
45°45.4
45°47.6
45°49.8
45°52.0
45°54.1
45°56.4
45°57.1
45°55.0
45°53.2
45°51.3
45°50.3
45°49.3
45°38.0
45°35.2
45°30.0
45°32.2
45°35.0
45°40.0
45°45.0
45°50.0
45°54.2
45°56.2
45°56.9
45°54.2
45°54.2
Location
Longitude
84°17.9
84°17.8
84°17.8
84°17.8
84°17.8
84°17.8
84°17.8
84°17.8
84°30.0
84°30.0
84°30.0
84°30.0
84°30.0
84°30.0
84°10.3
84°02.4
83°55.0
83°55.0
83°55.0
83°55.0
83°55.0
83°55.0
83°55.0
83°55.0
83°55.0
84°02.3
84°10.3
1.4 LITERATURE CITED

Ayers, J. C.  1956.  A dynamic height method for the determination of
     currents in deep lakes.  Limnol. Oceanogr.  1: 150-161.

	, D. V. Anderson, D. C. Chandler and G. H. Lauff.   1956.  Cur-
     rents and water masses of Lake Huron.  Univ. Michigan,  Great Lakes
     Res. Div. Pub. 1, 101 p.

-------
	, D. C. Chandler, G. H. Lauff, C. F. Powers and E. B. Benson.
     1958.  Currents and water masses of Lake Michigan.  Univ. Michigan,
     Great Lakes Res. Div. Pub. 3, 169 p.

Beeton, A. M.  1969.  Changes in the environment and biota of the Great
     Lakes, p. 150-187.  In: Eutrophication, causes, consequences, cor-
     rections.  Washington:  Nat. Acad. Sci.

Federal Water Pollution Control Administration.  1967.  Lake currents.
     FWPCA, Great Lakes Region, Chicago, 111.

Henson, E. B.  1962.  Notes on the distribution of the benthos in the
     Straits of Mackinac region.  Proc. 5th Conf. Great Lakes Res.,
     Univ. Michigan, Great Lakes Res. Div. Pub. 9: 174-175.

	.  1970.  Pontoporeia affinis (Crustacean, Amphipoda) in the
     Straits of Mackinac region.  Proc. 13th Conf. Great Lakes Res.:
     601-610.  Internat. Assoc. Great Lakes Res.

Murty, T. S. and D. B. Rao.  1970.  Wind-generated circulations in Lakes
     Erie, Huron, Michigan, and Superior.  Proc. 13th Conf. Great Lakes
     Res.: 927-941.  Internat. Assoc. Great Lakes Res.

Powers, C. F. and J. C. Ayers.  1960.  Water transport studies in the
     Straits of Mackinac region of Lake Huron.  Limnol. Oceanogr. 5:
     81-85.

Saylor, J. H. and P. W. Sloss.  In press.  Water volume transport and
     oscillatory current flow through the Straits of Mackinac.  J. Phys.
     Oceanogr.

Schelske, C. L.  1975.  Silica and nitrate depletion as related to rate
     of eutrophication in Lakes Michigan, Huron, and Superior, p. 277-
     298.  In:  A. D- Hasler (ed.), Coupling of land and water systems,
     Springer-Verlag New York, Inc.

	.  In press.  Trophic status and nutrient loading for Lake
     Michigan.  Report of North American Project of OECD, Study of
     Eutrophication.  U.S. Environmental Protection Agency.

     	 and J. C. Roth.  1973.  Limnological survey of Lakes Michigan,
     Superior, Huron and Erie.  Univ. Michigan, Great Lakes Res. Div.
     Pub. 17, 108 p.

     	 and E. F. Stoermer.  1971.  Eutrophication, silica depletion
     and predicted changes in algal quality in Lake Michigan.
     Science 173: 423-424.

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                                SECTION II

                               CONCLUSIONS


 The  Straits  of Mackinac  and adjacent areas studied in this report comprise
 a  complex  environmental  system.  The complexity is attributable in part
 to three physical  factors and their interaction:  1) the oscillatory flow
 of water between Lake Michigan and Lake Huron resulting from seiches be-
 tween  the  two lake basins with equal mean elevations; 2) the net transport
 of water from Lake Michigan into Lake Huron, since the outflow for Lake
 Michigan is  through  the  Straits of Mackinac into Lake Huron; 3) the west-
 erly subsurface flow of  water from Lake Huron into Lake Michigan, a
 phenomenon that is probably restricted to the period of summer -thermal
 s tratification.

 Oscillatory  and subsurface water movements confuse the simple straight-
 forward identification of water masses, as they contribute to mixing
 over a broad geographical area extending from northern Lake Michigan into
 northern Lake Huron.  Our study was too limited in the geographic sense
 to define  the boundaries of the area affected by mixing of water masses.

 Water  masses characteristic of epilimnetic waters were delineated with
 four separate techniques:

 1)   Multivariate statistical techniques showed that water masses could be
 identified with cluster  analysis.  Stations with similar values for nine
 different  environmental  variables were grouped and identified on maps of
 the  study  area (Sec. V).

 2)   Ordination analyses  of plankton assemblages also were used to group
 different  stations.  In  this case the data were counts of zooplankton and
 phytoplankton for  individual stations.  The analyses groups closely
 related stations and provided data on the plankton community associated
 with each  group of stations (Sec. VI, VII).

 3)  Temperature-conductivity plots were useful in identifying surface
water masses on one of the three cruises.  Data from the October cruise
 could be used in this analysis since three sources of water, one from
Lake Michigan, one from  Lake Huron and one from Lake Superior, were
 clearly identifiable on  the basis of temperature and conductivity.  The
 fraction of water  from each of the three sources was determined and
plotted (Sec. IV).
                                    10

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4)  Various analyses for single parameters were used for identification
of water masses.  Average values for silica, specific conductance, pH and
to a lesser extent for nitrate nitrogen and water temperature in different
areas were related to water masses.  These averages plus isopleths of the
same parameters plotted on depth profiles for the transects sampled could
be used to infer relationships among water masses.  Comparison of isopleths
on the depth profiles was the only approach that was applied extensively
to characterization of subsurface water masses (Sec. Ill).

From the standpoint of identifying water masses in this type of survey,
several physical-chemical parameters could have been applied successfully.
Our results showed that specific conductance was very valuable and that
silica, pH, alkalinity and nitrate nitrogen, although not conservative
parameters in the usual sense, had conservative properties in this study
(Sec. Ill, VI).

Although biological communities (phytoplankton and zooplankton) were
readily associated with water masses from the ordination analysis (Sec. VI,
VII), rates of carbon fixation and chlorophyll a varied little among water
masses (Sec. Ill).  The apparent cause for this lack of relationship was
that phytoplankton standing crops were so small that differences among
groups of stations could not be detected analytically.  These small dif-
ferences in values were also found for rates of carbon fixation and total
phosphorus (Sec. Ill).

Although physicochemical characteristics were only subtly different, the
community structure of crustacean zooplankton reflected water quality
conditions within the Straits region.  Species composition was nearly
identical at every station, but principal component analysis based on
percent composition data revealed patterns of community structure remark-
ably similar to water masses identified by cluster analysis (Sec. V).  In
general, cladocerans were proportionately most prevalent in waters towards
Lake Michigan and south of Bois Blanc Island while calanoid copepods were
relatively most abundant in waters towards Lake Huron and north of Bois
Blanc Island.  Cladocerans have been observed as most characteristic of
eutrophic waters and calanoid copepods most prevalent in oligotrophic
waters elsewhere in the Great Lakes.  It is significant that the relative
proportion of these two crustacean zooplankton groups to one another was
a sensitive indicator of water quality in the Straits region where physi-
cochemical conditions differed so subtly (Sec. VII).

The phytoplankton in the Straits of Mackinac region is floristically dis-
similar from the open waters of both Lake Michigan and Lake Huron
(Sec. VI).  Besides mixing of populations developed in the primary water
sources, it appears that conditions in the Straits region are favorable
for the development of certain phytoplankton populations not usually
found in offshore plankton assemblages in the upper lakes.  Examples of
this are the relatively large populations of Chrysosphaerella longispina
and Chrysococcus dokidophorus noted in our study.  The region is also
affected by the injection of normally benthic species into the plankton.
These populations are apparently derived from islands and shoal areas
and from the St. Marys River.  In most instances they constitute a
quantitatively minor part of the assemblage.

                                     11

-------
 It is clear that populations of blue-green  algae  developed in Lake
 Michigan are being transported to Lake Huron  via  surface  flow through the
 Straits  of  Mackinac.   On  the basis of  our results it appears  that  the
 populations involved  are  senescent and there  is minimal reproduction  in
 the  Straits region and Lake  Huron.  These populations are characteristic
 of moderately eutrophied  regions  in the Great Lakes, especially regions
 with sufficient  phosphorus loading to  cause silica limitation during  the
 summer.   One of  the primary  populations involved, Anacystis incerta,  is
 capable  of  forming nuisance  blooms but does not constitute a nuisance in
 quantities  noted in the present study.  During this study the area most
 affected by input from Lake  Michigan was the  region south of Bois Blanc
 Island and  the adjacent waters of open Lake Huron (Sec. VIII).

 The  net  transport of  water from Lake Michigan to Lake Huron has the fol-
 lowing effects on the nutrient enrichment of  northern Lake Huron
 (Sec. VIII):

 1)  A relatively rich but diffuse source of phosphorus is supplied.   The
 degree of enrichment  in northern  Lake  Huron is obviously small, although
 the  total input  is large  due to the large flow of water.  The flux of
 total phosphorus is approximately 10 g P sec"1 (1920 m3 sec"1 x 5.0 mg P
 m~3). Estimates could vary  greatly due to several uncertainties, includ-
 ing  errors  in measurements of total phosphorus and net transport and
 seasonal variations in either or  both  of these parameters.  A change of
 0.1  mg P m~3 changes  the  flux by  4.0%.  An error as large as 20% there-
 fore might  be associated  with the estimate of annual phosphorus trans-
 port if  the error in  mean phosphorus concentrations were 0.5 mg P m   .
 Most of  the phosphorus is transported  in the particulate form, presumably
 combined in biological materials.

 2)  Silica-depleted waters are supplied, resulting in reduction of silica
 concentrations in northern Lake Huron.  This  relationship is most severe
 during late summer and fall,  and  the reduced  supply of silica eventually
 will affect diatom standing  crops in northern Lake Huron.

 3)   Nitrate-depleted  waters  are transported from Lake Michigan, resulting
 in decreased concentrations  in northern Lake Huron.  The effect is great-
 est  in late summer and early fall when the greatest depletion of nitrate
 occurs in Lake Michigan.  This relationship is not considered as important
 as that  for silica and phosphorus since nitrate concentrations are not
 diluted  to  levels  that would limit phytoplankton growth.  It must also
 be recognized that the levels of  organic nitrogen are probably greater in
 Lake  Michigan than in Lake Huron, partly compensating for the nitrate
 reduction associated with mixing  waters from  the two lakes.

 During the  period  of  thermal stratification there is a subsurface  flow
 of water  from Lake Huron  to  Lake  Michigan.  This water flows west below
 the epilimnetic waters  of Lake Michigan and is apparently entrained and
mixed with  the epilimnetic waters of Lake Michigan in an undetermined
area west of  the  Straits  of  Mackinac.

Mixing of waters  from  Lake Michigan and Lake Huron increases  the silica
 concentration  in  the  silica-depleted waters of Lake Michigan.  Removal or

                                    12

-------
reducing the effect of silica limitation apparently allows some diatom
populations to develop in the Straits area at higher population densities
than occur either in northern Lake Michigan or northern Lake Huron
(Sec. VIII).  This relationship also suggests that some other nutrient
limitation, possibly for phosphorus, may be removed by the mixing process.
The transport of relatively high concentrations of phosphorus from Lake
Michigan and the enrichment of mixed waters with silica from Lake Huron
produced relatively large diatom crops in the study area even at times
when Lake Michigan waters were silica depleted and contained significant
populations of blue-green algae.  In effect this increased growth of
diatoms and demand for silica extends the potential for silica limitation
from Lake Michigan into Lake Huron.  It will also accelerate the rate of
silica depletion in Lake Huron.

Generally it is concluded that there is a subtle effect of water trans-
port from Lake Michigan on the water quality in northern Lake Huron.
Some effects are seasonal; for example, silica-depleted and blue-green
algae-bearing waters are transported from Lake Michigan in the severest
form only during the late summer and fall.

This investigation provides an important and unique data set on the
characterization of the area in and near the Straits of Mackinac.  Its
results are the only combined baseline data on plankton and chemistry for
this part of the upper Great Lakes.  The study is limited, since the
period of observation was restricted to 40 days, from 30 August to
8 October 1973.  Additional data obviously are needed to provide a compre-
hensive analysis of seasonal dynamics.

Future studies should be designed so the effect of short-term changes in
physical dynamics could be included in the study.  Part of the influence
of  these effects on the data could be minimized by synoptic coverage of
the study area with several ships—the sampling period for each cruise
of  our study was about 60 hr or about the same period as that for the
seiche between Lake Michigan and Lake Huron.

Data collection could be refined with a network of buoys that continuously
record data for temperature, specific conductance and currents and with
one or more ships to take additional samples.  Data collected at different
stations in the study area could then be related to the physical dynamics.

A larger study area would be needed than we sampled, as there are three
separate questions that could be addressed in future studies:

1)  What are the dynamics of transport and mixing between the two lakes?

2)  What are the influences of Lake Michigan on northern Lake Huron and
the areal extent of these influences?

3)  Is the opposite effect, the influence of Lake Huron on northern Lake
Michigan, restricted primarily to the period of thermal stratification?
                                    13

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                               SECTION III

             DESCRIPTION OF PHYSICAL-CHEMICAL CONDITIONS AND
                    PHYTOPLANKTON COMMUNITY PARAMETERS
                                    by
         Claire L.  Schelske, Mila S. Simmons, and Laurie E. Feldt


 The purpose of this section is to provide background data and to describe
 conditions in the Straits of Mackinac on the three cruises in 1973.
 3.1 METHODS AND MATERIALS

 Prior  to each cruise, several types of bottles were prepared for use in
 sample collection.  Labels containing sample numbers and other identifi-
 cation codes were placed on all bottles in which samples would be
 collected  in the field.  One or two days prior to the cruise, 5-dram
 glass  amber vials were prepared for chlorophyll samples.  The vials were
 spiked with 8-9 ml of 90% acetone (buffered with 0.1 g/liter of magnesium
 carbonate), tightly capped and stored upright in the freezer until needed
 for sample introduction on shipboard.

 Bottles for alkalinity samples (2-oz polyethylene) were spiked with 5 ml
 of 0.01N HC1, tightly capped and stored upright in boxes.

 Shipboard Analyses

 Water  samples were taken with clean 5-liter Nisken bottles, except sur-
 face samples which were taken with a clean plastic bucket; sample depths
were generally at 5-m intervals from the surface to 20 m, and at 10-m
 intervals below that.  As many as 11 depths were sampled at the deepest
 stations.  Temperature was measured with a bathythermograph and with a
mercury thermometer on shipboard.

Water samples were processed as illustrated in the flow chart (Fig. 3.1).
Samples for chemical analyses were filtered through HA Millipore filter
papers, which were previously rinsed several times and soaked in dis-
tilled deionized water.  The bottles for chemical analyses were first
rinsed once with the filtered water before sample introduction.

Specific conductance and pH were measured on board ship immediately after
the water samples were collected.  Specific conductance was measured with

                                   14

-------
                                                                Filtrate-DISCARD
300
Te
PH
Sp
Al
Raw Water
UNFIL
s
FILTER
*
TERED
1
ml 5(
nperature I
A
=cific conductance
calinity-5 m 0
4
AA Millipore
500 ml; Om, 5m, &
2 other depths
HA Millipore
250 ml


Filter-store in amber vial for gross
Filtrate
rinse 2 oz
bottles first
Filter-store in
phytoplankton
2 oz unfrozen for
chemical analyses
2 oz freeze for
chemical analyses
2 oz freeze for
contingency
amber vial containing
8 ml 90% acetone. Put in freezer
for chlorophyll analyses.
ml 900 ml 60 ml
hytoplankton C-L4 plt in 2 oz
dd 5 drops 5 n bottles &
glutaraldehyde 2 J & ID freeze for
m, 5m & 2 other Us j #1 screen total phosphorus
depths
Figure 3.1.
FLOW CHART ILLUSTRATING SAMPLE PROCESSING OF DISCRETE DEPTH  SAMPLES,  STRAITS OF MACKINAC
1973.

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a Leeds and Northrop Model 4866-60 conductivity bridge equipped with a
temperature compensator.  A Corning pH meter Model 111 equipped with a
digital readout and an automatic temperature compensator was used to
measure pH.  The  two-buffer calibration technique, usually with pH 7.0
and  10.0 buffer solutions, was employed.  The sample temperature was
read to 0.1°C with a laboratory mercury thermometer.

The  rate of  carbon fixation by phytoplankton was measured by a previ-
ously described method  (Schelske and Callender 1970).  Water samples
 (250 ml) were  collected  in glass-stoppered Pyrex bottles, injected with
2.0  pCi  C-14,  incubated  for 3-4 hr aboard ship and filtered through
47-mm HA Millipore filters.   The filters were mounted with rubber cement
on 52-mm diameter aluminum planchets and stored for counting.  A Low
Beta Beckmann  Planchet Counter was used for counting.  Efficiency of
this counter and  the absolute activity of the C-14 was determined with a
Nuclear  Chicago Liquid Scintillation Counter (Wolfe and Schelske 1967) .
Alkalinity was determined from pH measurements on 20-ml samples to which
5 ml of  0.010N HC1 was added.  Alkalinity measurements were performed
only on  samples from 5 m where C-14 productivity was measured.

Soluble  reactive  silica  and nitrate nitrogen were measured on board ship
with a TechniconCt) AutoAnalyzer.  Silica was determined by the Technicon
AutoAnalyzer Heteropoly-Blue  Method.  In the method, silica is complexed
with acidified molybdate to form a silicomolybdate complex which is
reduced  to an  intense heteropolyblue.  Oxalic acid was added prior to
the  reduction with ascorbic acid to destroy any phosphomolybdate.  The
color produced was measured at 630 mp.

Nitrate was reduced by copper-hydrazine solutions to nitrate at 54°C.
The  nitrite produced and the  nitrite initially present in the sample
were then  determined by  a diazotization-coupling reaction using
sulfanilamide and N-1-naphthyl-ethylene diamine.  This red-violet
colored complex was measured  at 520 my (Kamphake et al. 1967).  Nitrite
was  not analyzed  separately,  as quantitatively insignificant values
would be expected in non-polluted oxygenated waters.

Samples for chlorophyll  (250 ml) were filtered through a 47-mm HA
Millipore  filter.  The filters were extracted overnight at -10°C with
90%  acetone buffered with magnesium carbonate.  The samples were then
centrifuged, and  5 ml was transferred to sample cuvettes and read in a
modified Turner Model 111 Fluorometer.  The samples were subsequently
acidified  and read in the fluorometer for phaeopigment determinations
(Strickland and Parsons  1968).  Readings of extracted chlorophyll with
the  fluorometer were taken both on board ship and in our laboratories in
Ann Arbor.   Samples were maintained in the cold and dark until readings
were  taken.


Laboratory Analyses

Frozen samples were transferred from the ship's freezers to large
insulated coolers and brought back to the Ann Arbor laboratory.  The
trip was normally 6 hr.  Samples remained frozen during transit and were

                                    16

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immediately stored in laboratory freezers.  The containers used for
transport were large plywood boxes insulated with 5 cm of styrofoam.
Sometimes smaller picnic coolers were used for extra samples, and in
this case blocks of dry ice were used to maintain freezing temperatures
during transport.

Samples were brought back to the laboratory usually at the end of each
cruise, which was normally after a week.  Analyses were usually completed
within a week to a month's time depending upon the availability of per-
sonnel to do the analyses.

Chemical analyses for ammonia, total phosphorus, total soluble phosphorus,
chloride and sulfate were performed on thawed samples with the Technicon
AutoAnalyzer in the laboratory.  Most of the methods employed were
Technicon AutoAnalyzer methods or modified ones.  All analyses except the
one for total phosphorus were performed on samples of filtered water.

Ammonia was oxidized to nitrous acid by hypochlorite which reacts with
phenol to give a blue color.  The reaction was catalyzed by nitroprusside
and buffered by EDTA.  The color produced was measured at 630 mp (H. E.
Allen, U.S. Bureau Sport Fish, and Wildlife, Ann Arbor, Mich., unpublish-
ed manuscript).  A special sampling chamber wherein acid-scrubbed air
was constantly purged was used to minimize ammonia contamination from
the atmosphere.

Samples for total phosphorus and total soluble phosphorus were concen-
trated by evaporation and digested with potassium persulfate for 1.5 hr
in an oven at 110°C.  The samples were then treated with an acidic solu-
tion of ammonium molybdate to give phosphomolybdate which was then
reduced by ascorbic acid to give a blue color and measured at 630 my.

Chloride reacts with mercuric thiocyanate to form mercuric chloride.  The
released thiocyanate reacts with ferric ammonium sulfate to form a red
complex, Fe(SCN)3-  The resulting color was measured at 480 mp.

An automated turbidimetric method was used for the determination of
sulfate.  The turbidity produced by the reaction of BaCl2 in HC1 with
sulfate was measured at 420 mp.  An NH^-OH-EDTA rinse was used to pre-
vent the coating of the BASOt^ precipitate on the walls of the manifold
system and the flow cells (Santiago et al. 1975).
3.2 EPILIMNETIC AVERAGES AND SEASONAL VARIATION

Data from the averages for eight parameters indicate the range of condi-
tions observed in surface waters during the three cruises (Table 3.1).
Averages for different groups of stations represent conditions for
different parts of the study area:  Stations 01-06 for Lake Michigan,
Stations 40-45 for Lake Huron and Stations 46-48 for the St. Marys River.
                                    17

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oo
           Table 3.1.  AVERAGES OF ENVIRONMENTAL PARAMETERS OF EPILIMNETIC WATERS ON THREE CRUISES IN
                    THE STRAITS OF 1IACKINAC,  1973.  Data arc mean + one Dtandard deviation.
Stations
Cruise 1
Cruise 2
Cruise 3
Stations
Temperature (C)
1-6
7-10
13-23
24-27
28-31
32-37
40-45
46-48
21.1 ± .0.44
19.5 ± 1.44
21.3 ± 0.77
21.6 ± 0.70
20.9 ± 0.55
20.3 ± 0.83
N.S.
N.S.
15.4 ± 0.87
11.4 ± 1.10
14.4 ± 0.46
13.1 ± 1.07
10.1 ± 1.48
N.S.
13.3 ± 2.13
12.7 ± 1.35
Specific conductance (10~'*mho
1-6
7-10
13-23
24-27
28-31
32-37
40-45
46-48
2.496 ± 0.056
2.397 ± 0.062
2.445 ± 0.040
2.101 ± 0.102
2.208 ± 0.086
2.272 ± 0.064
N.S.
N.S.
2.354 ± 0.127
2.270 ± 0.059
2.348 ± 0.115
2.280 ± 0.100
2.025 ± 0.182
N.S.
2.064 ± 0.136
1.500 ± 0.194
14.4 ± 0.49
12.2 ± 0.29
13.4 ± 0.51
12.4 ± 0.28
12.4 ± 0.68
12.2 ± 0.28
11.2 ± 0.80
13.6 t 0.78
cm-')
2.462 ± 0.062
2.018 ± 0.063
2.300 ± 0.138
1.940 ± 0.085
1.768 ± 0.075
1.934 ± 0.131
2.045 ± 0.098
1.498 ± 0.226
1-6
7-10
13-23
24-27
28-31
32-37
40-45
46-48

1-6
7-10
13-23
24-27
28-31
32-37
40-45
46-48
Cruise 1
Cruise 2
Cruise 3
Chlorophyll a (mg m 3)
1.51 ± 0.14
1.25 ± 0.17
1.22 ± 0.16
1.12 ± 0.11
1.16 ± 0.23
1.22 ± 0.17
N.S.
N.S.
Silica
0.510 ± 0.090
0.696 ± 0.104
0.586 + 0.117
0.689 ± 0.082
0.679 ± 0.117
0.635 ± 0.120
N.S.
N.S.
1.73 ± 0.70
1.21 ± 0.36
1.67 ± 0.10
1.78 ± 0.12
1.26 ± 0.29
N.S.
1.71 ± 0.17
1.38 i 0.24
(mg Si02 I'1)
0.951 ± 0.162
1.235 ± 0.082
1.007 ± 0.053
1.047 ± 0.032
1.299 ± 0.172
N.S.
0.946 ± 0.160
1.754 ± 0.140
1.60 ± 0.24
1.45 ± 0.16
1.33 ± 0.28
1.56 ± 0.39
1.71 ± 0.36
1.56 ± 0.29
1.43 ± 0.40
1.26 ± 0.24

1.292 ± 0.129
1.416 ± 0.081
1.162 ± 0.213
1.144 ± 0.071
1.318 ± 0.133
1.504 ± 0.128
1.150 ± 0.111
1.674 ± 0.269

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Table 3.1 continued.
Stations

1-6
7-10
13-23
24-27
28-31
32-37
40-45
46-48

1-6
7-10
13-23
24-27
28-31
32-37
40-45
46-48
Cruise 1

8.658 ± 0.050
8.635 ± 0.050
8.657 ± 0.021
8.662 ± 0.017
8.627 ± 0.025
8.653 ± 0.016
N.S.
N.S.
Secchi
5.02 ± 0.32
6.03 ± 0.15
5.62 ± 0.43
8.08 ± 0.43
8.00 ± 0.66
6.70 ± 0.47
N.S.
N.S.
Cruise 2
pH
8.514 ± 0.063
8.372 ± 0.098
8.498 ± 0.048
8.512 ± 0.048
8.315 ± 0.099
N.S.
8.441 ± 0.093
8.123 ± 0.038
transparency (m)
3.86 ± 0.79
4.88 ± 0..48
4.63 ± 0.25
5.67 ± 0.76
6.67 ± 1.76
N.S.
6.73 ± 1.47
3.83 ± 1.44
Cruise 3

8.416 + 0.065
8.226 ± 0.063
8.401 ± 0.060
8.284 ± 0.058
8.236 ± 0.047
8.240 ± 0.065
8.335 ± 0.055
8.140 ± 0.060
Stations

1-6
7-10
13-23
24-27
28-31
32-37
40-45
46-48
Cruise 1
Nitrate
143 ± 16
159 ± 16
187 ± 37
222 ± 33
198 ± 15
180 ± 12
N.S.
N.S.
Cruise 2
(ugN I'1)
212 ± 69
276 ± 19
241 ± 51
241 ± 41
341 ± 33
N.S.
246 ± 41
293 ± 19
Cruise 3

177 ± 19
308 ± 9
246 ± 18
310 ± 16
322 ± 11
299 ± 31
285 ± 16
323 ± 5
Total phosphorus (pgP I"1)
6.82 ± 0.76
7.20 ± 0.85
6.55 ± 0.72
7.32 ± 0.54
7.10 ± 0.84
8.33 ± 0.93
9.42 ± 2.08
4.77 ± 1.97
1-6
7-10
13-23
24-27
28-31
32-37
40-45
46-48
4.63 ± 0.93
3.35 ± 1.20
3.16 ± 0.98
1.45 ± 0.47
3.02 ± 1.0.6
2.88 ± 0.73
N.S.
N.S.
4.76 ± 0.90
3.26 ± 2.12
3.96 ± 1.27
3.32 ± 0.83
4.08 ± 1.20
N.S.
3.21 ± 1.66
4.20 ± 0.72
5.10 ± 0.53
5.17 ± 1.78
4.02 ± 1.80
4.49 ± 1.14
3.93 ± 1.02
4.50 + 1.67
3.66 ± 1.12
3.66 ± 1.42

-------
 Water Temperature

 Surface water temperatures,  as would be expected,  generally decreased
 during the three cruises.   On the August cruise,  surface temperatures
 were generally greater than 20°C, but the easternmost  transect,  where
 lower temperatures  from water flowing out  of the St. Marys  River might
 have been observed,  was not  sampled.   Most of the  surface water cooling
 occurred between Cruises 1 and 2;  a much smaller amount  of  cooling  and
 in fact an increase in temperatures occurred at some stations between
 Cruises 2 and 3 (Table 3.1).

 Temperature relationships among the groups of stations on the three
 cruises were strongly influenced  by two  factors on the September cruise.
 As pointed out below, the depth of the mixed layer increased between
 Cruises 1 and 2,  and upwelled water in September tended  to  decrease
 average surface temperatures.  The presence of upwelled  water was evident
 from average temperatures for Stations 28-31 and 07-10.  At these two
 groups of stations  epilimnetic temperatures were lowest  on  Cruise 2.

 By Cruise 3, average temperatures for Stations 46-48 were greater than
 the adjacent waters, reflecting the large  amount of thermal inertia in
 Lake Superior or  indicating  a relatively constant  temperature in the  out-
 flow from Lake Superior between the two  cruises (App. C-18, C-19).

 Specific Conductance

 From a conservative parameter such as specific conductance, inferences
 can be made about relationships and origins of water masses.  It was
 obvious,  for example,  that on all  three  cruises water sampled at Stations
 01-06 in Lake Michigan was diluted with  Lake Huron water, as the specific
 conductance (Table  3.1) was  lower  than the expected range of 260-270  ymho
 cm"1  (Table 1.1)  in  northern  Lake Michigan.  The influence  of water flow-
 ing out of  Detour Passage from Lake Superior via the St. Marys River was
 evident also in the  average  specific  conductance for Stations 46-48.
 Although  averages were much  lower  for  Stations 46-48 than for other sta-
 tions,  they were considerably greater  than the average of 95 umho cm"1
 for  Lake  Superior or  the minimum  value of  about 120 measured on Cruise 3.
 Averages  larger than  Lake Superior values  were due to dilution with
 Lake  Huron  water, with an average  specific conductance of 205 ymho  cm""1
 at  Stations 40-45 for  Cruises 2 and 3  (Table 3.1).

 It was  evident from  these data  that on each cruise water found at Stations
 01-06 had a  specific  conductance most  closely related to water found  at
 Stations 13-23.  Values at these  two  groups of stations  also were the
largest of any sampled, indicating the largest proportion of Lake Michigan
water in the  study area.

Dilution and mixing of  surface water masses originating  from Lake
Superior, Lake Huron and Lake Michigan are evident from  the data on
average specific conductance  and are  considered in greater  detail in
Section 4.0.


                                    20

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Hydrogen Ion Concentration

Obvious features of the pH data were largest values in Lake Michigan with
smallest values in the area near Detour Passage and a general decrease in
values seasonally (Table 3.1).  Larger values were found in Lake Michigan
due to a greater buffering capacity than present in either Lake Huron or
Lake Superior; in addition, waters of Lake Michigan are buffered above
the equilibrium pH of about 8.4 (Schelske and Callender 1970), leading
to the precipitation of marl or "milky water" (Ladewski and Stoermer
1973).  Photosynthetic activity and increasing water temperature during
the summer cause the pH to be greater than the equilibrium values.  The
decrease in pH during the sampling period was due to mixing surface
waters with colder subsurface waters of lower pH and to the decrease in
water temperature which increases the solubility of carbon dioxide and
reduces pH (Schelske and Callender 1970).

Secchi Transparency

There was no seasonal trend in Secchi disc transparency; lowest readings
were found on the second cruise.

Transparency was least in two areas, one in Lake Michigan waters repre-
sented by Stations 01-06 and 13-23 and the other in St. Marys River
water represented by Stations 46-48 (Table 3.1).  The smaller transpar-
encies in these areas were not entirely a reflection of relatively large
standing crops of phytoplankton, as the lowest chlorophyll concentrations
were found at Stations 46-48.  Inorganic turbidity must have contributed
to reduced transparency at Stations 46-48 and also, possibly, at Stations
01-06 and 13-23.  Ladewski and Stoermer (1973) found that minimum Secchi
disc transparency in September was caused by milky water.  Greatest
transparencies were found in the areas most remote from Lake Michigan
and Detour Passage and were at Stations 24-31 on Cruise 1, Stations 28-
31 and 40-45 on Cruise 2, and Stations 40-45 on Cruise 3.


Chlorophyll a

Concentrations of chlorophyll a varied little among the data for the
survey.  Averages for groups of stations ranged only from 1.1-1.8 during
the study (Table 3.1).  For most stations, the largest average was found
on Cruise 2 when the water transparency was lowest.  With the small dif-
ference between the averages, additional discussion of chlorophyll
averages is not warranted other than to point out that many of the stand-
ard deviations were less than 10% of the mean values.  Variance in
chlorophyll data is frequently much larger.


Soluble Reactive Silica

Silica changed seasonally, with concentrations increasing from the first
to the last cruise.  Water at Stations 01-06 and 13-23, with the great-
                                    21

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 est  proportion  of Lake Michigan water, contained the smallest concentra
 tions  of  silica; largest  concentrations were at Stations 46-48 due  to
 the  input of  St. Marys River water  (Table 3.1).

 Concentrations  of silica  in Lake Michigan water (Stations 01-06) on
 Cruise 1  averaged greater than 0.5 mg/liter, a value greater than expected
 for  Lake  Michigan water in August or September.  In late August, concen-
 trations  of silica  in surface waters of Lake Michigan would be less than
 0.2  mg/liter  and possibly less than 0.1 mg/liter.  Concentrations of
 silica on Cruises 2 and 3 also were greater than expected for Lake
 Michigan  surface waters.   Silica concentrations higher than expected
 resulted  from the mixing  of water relatively enriched with silica from
 Lake Huron with water from Lake Michigan in the Straits area.  The
 source of water for the increased concentrations was not Lake Michigan,
 as surface water concentrations remain below 1.4 mg/liter until December
 or January (Rousar  1973).  The source of silica-rich water was the
 westerly  subsurface flow  from Lake Huron.

 Nitrate Nitrogen

 On each cruise, the smallest average nitrate nitrogen concentration was
 found  at  Stations 01-06 in Lake Michigan; the largest concentrations were
 found  at  Stations 46-48 near Detour Passage and at Stations 28-31
 (Table 3.1).  These relationships are due to the input of water with
 relatively low  nitrate concentration from Lake Michigan and water with
 relatively high nitrate concentration from Lake Superior (Table 1.1).
 At Stations 28-31 the large average in September was due to upwelled
 water  (App. C-14) with high nitrate concentrations.  The data also  show
 that Lake Huron waters contained relatively large concentrations of
 nitrate in comparison to  Lake Michigan waters.

 Nitrates  generally increased during the three cruises, but the trend was
 not  as definite as found  for silica.  The large average for nitrate on
 Cruise 2  at Stations 01-06 was probably due to a smaller proportion of
 Lake Michigan water than  on Cruises 1 and 3; on Cruise 2, the average
 specific  conductance was  the lowest of the three cruises, indicating
 greater intrusion of waters from Lake Huron, Lake Superior, or both
 sources (Table  3.1).

 Total  Phosphorus

 There were no obvious seasonal trends in total phosphorus and, with the
 exception of Stations 24-27, there was very little difference in the
 average concentrations.  With the exception of the one value of 1.5 yg P/
 liter,  averages ranged from 2.9 to 5.2 pg P/liter.  For the three cruises,
 the largest averages were for Stations 01-06, ranging from 4.6 to 5.1 yg
P/liter (Table 3.1).  There is some indication that the lowest values
 for each group of stations occurred on Cruise 1; however, if there  were
 smaller concentrations during the first cruise, the differences appeared
                                    22

-------
to be too small to be detected statistically due to the relatively large
variances.

Because phosphorus limits algal growth in the upper Great Lakes, small
concentrations should be associated with small standing crops of phyto-
plankton.  The smallest average for total phosphorus, 1.5 pg P/liter was
found for Stations 24-27 on Cruise 1.  At these stations, chlorophyll
concentrations were also minimal and Secchi disc transparency was rela-
tively large, indicating that phytoplankton standing crops were smaller
than at surrounding stations  (Table 3.1).  Generally, however, there
were no obvious relationships between averages for total phosphorus and
algal standing crops.  One probably should not expect to see definite
relationships between means of total phosphorus and chlorophyll since
the range of these variables was small during the study.  For the com-
plete data set the expected relationship was obtained, i.e. that small
standing crops of chlorophyll would be associated with small concentra-
tions of phosphorus.
3.3 PHYSICAL-CHEMICAL CONDITIONS IN AUGUST

The description here and in 3.4 and 3.5 for the September and October
cruises is based on data presented in Appendix A and Appendix C.  Raw
data are tabulated in Appendix A, while isopleths of water temperature,
pH, specific conductance and  silica are plotted in Appendix C for depth
profiles of each transect sampled.  Specific references will not be made
to these appendices each time data are presented, but will be added when
data in appendices may be of  particular interest to the reader.


Water Temperature

On the August cruise, surface water temperatures were fairly uniform
over the study area (Table 3.1).  Temperature on the Lake Michigan trarii-
sect (Stations 01-06) varied  from 21.0° to 21.8°C.  South of Bois Blanc
Island temperatures ranged from 21.0° to 22.0°C.  On the transect to the
east of Bois Blanc Island (Stations 24-31), surface temperatures ranged
from 20°C at the northern end of the transect to 22°C at the southern
end.  At Station 07 near Rabbit's Back Peak, water was relatively cold;
the temperature was 17°C at the surface and the isotherms indicate that
upwelling may have occurred in this vicinity (App. C.4).  Water in the
harbor at St. Ignace at this  time was very cold, as attested by members
of the ship's scientific crew who attempted to swim after the day's work
was completed on 31 August.

Thermal stratification was pronounced on all transects sampled except the
three south of Bois Blanc Island, and even on these transects stratifi-
cation was present although not as strong as found at other sampling
sites.  The minimum isotherm  south of Bois Blanc Island was 12°C, which
was one degree warmer than the minimum isotherm for the Lake Michigan
                                    23

-------
 transect  (Stations  01-06).  At  these  stations the epilimnion extended  to
 a  depth of  about  15 m.   North and east of Bois Blanc  Island the  thermo-
 cline  was much  shallower with the epilimnion extending only to about 10 m.
 At Stations 31  and  32,  the distribution of isotherms  near the surface
 indicates intrusion of  relatively cold water along the north shore
 (App.  C.13  and  C.16).   The origin of  this cold water  may be related to
 the upwelling noted for Station 07.

 Specific Conductance

 Epilimnetic waters  on the Lake  Michigan transect (Stations 01-06) had
 values for  specific conductance >250  ymhos.  South of Bois Blanc Island
 specific conductance in the epilimnion was >240 ymhos.  On these same
 transects,  subsurface values for specific conductance were lower,
 decreasing  to 220 ymhos near the bottom (App. C.I, C.7, C.10).  These
 low values  indicate intrusion of Lake Huron water below the thermocline
 (Lake  Michigan  water would have a specific conductance of at least
 260 ymhos).

 On the transect north of Bois Blanc Island (Stations  32-37) (App. C.16)
 and on the  transect east of Bois Blanc Island (Stations 24-31), values
 for specific conductance were comparable to the minimum values found
 south  of the island or  about 220 ymhos (App. C.13).   On both of these
 transects,  however, there is a  minimum for specific conductance at 15-20 m
 that is most obvious between Stations 26-30 and Stations 34-37.  These
 relatively  low  values are indicative of a separate water mass.

 Hydrogen Ion Concentration

 Values of pH in the epilimnetic water at Stations 01-06 and for the three
 transects (Stations 13-23) on the south side of Bois  Blanc Island were
 greater than 8.6  (Table 3.1).   Maximum values were 8.70 at Stations 01,
 05 and 06.   At  the  other stations sampled on this cruise, surface values
 were also above 8.6 except Stations 07 and 31 where the values were 8.58
 and 8.57 respectively.

 In the relatively deep  waters on transects 32-37 and  24-31, values for
 pH were less than 7.8.   On the  Lake Michigan transect, Stations 01-06,
 the minimum isopleth was 8.2 at 25 m—pH values of 8.2 were also found  at
 20  m on the next  transect to the east, Stations 13-16.

Silica

Surface values  for silica were  generally lowest on the Lake Michigan
transect,  Stations 01-06, and on the three transects  south of Bois Blanc
Island, Stations  13-23,  with the range of values being about 0.1 mg/liter
or  from less than 0.5 to less than 0.6 mg/liter.  The lowest value
observed at all the stations was 0.36 mg/liter at Station 32, representing
a pocket of low silica water that probably originated in Search Bay or
                                    24

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some other nearshore area (App. C.16).

Highest values for silica in surface waters, values greater than 0.7 mg/
liter, were found at Stations 07, 33, and 31 along the north shore of the
Straits and at Stations 25 and 26 east of Bois Blanc Island.  These high
values undoubtedly represent the presence of water masses with a greater
percent composition of Lake Huron or Lake Superior water than the other
stations.

Vertical stratification of silica was very pronounced at all stations,
although to a lesser degree at the stations with the highest silica
values.  Values for bottom samples ranged from 1.4 mg/liter at 25 m on
the Lake Michigan transect (App. C.I) to 1.8 mg/liter on the transects
with deeper water, i.e., the transect north of Mackinac Island (App. C.4)
and the two transects north and east of Bois Blanc Island (App. C.13,
C.16).  On the transect north of Mackinac Island, 1.8 mg/liter was found
at depths >30 m while on the other transects this much silica was not
present at all stations and if present was restricted to water below 30 m.
3.4 PHYSICAL-CHEMICAL CONDITIONS IN SEPTEMBER

On the September cruise the distribution of environmental parameters was
more varied than on the preceding cruise due to the effects of weather
and the fact that an additional transect, Stations 40-48, was sampled.
Strong winds from the south made it impossible to sample Stations 13, 20,
and 21 located on the windward shore, and had a profound effect on the
water masses—including producing upwelling between Stations 29 and 30.


Water Temperature

Surface water temperatures varied from a maximum of 16°C in Cecil Bay at
Station 01 to less than 9°C at Station 30 in an upwelling area.  Temper-
atures west of the Straits (Stations 01-06) and south of Bois Blanc
Island (Stations 13-23) were warmer than in other areas, and greater than
14°C at all stations.  North of Mackinac Island and on transects east of
Bois Blanc Island, surface temperatures were less than 13°C except along
the south shore where they exceeded 16°C at some stations.

Thermal stratification was weak or nonexistent at stations west of the
Straits and those south of Bois Blanc Island.  Epilimnetic depths on
these transects were 15-20 m—there was evidence of stratification at
Station 19 due to the presence of 10°C at a depth of 20 m.

Two temperature distributions on this cruise were not observed on the
previous cruise.  One was the presence of upwelled water in the vicinity
of Station 29; the other was the presence of relatively warm water flow-
ing out of Detour Passage, that was sampled at Stations 46-48.  These
                                    25

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two water masses are easily identifiable also by chemical parameters,
particularly  specific  conductance and silica (App. C.13, C.18).


Specific Conductance

Patterns of specific conductance were not related to distribution  of
temperature on  the Lake Michigan transect, Stations 01-06, and on  tran-
sects  south of  Bois Blanc Island, Stations 13-23.  Water with high
specific conductance was found along the south shore at Stations 01
(App.  C.2) and  23  (App. C.ll) where water temperatures were greatest.
Highest specific conductance water was found at Stations 22 and 23,
indicating a  greater proportion of Lake Michigan water than found  at
other  stations; relatively high specific conductance water was present
as far east and south  as Stations 40, 41 and 42 (App. C.18), indicating
flow of Lake  Michigan  water to this area.  One or two lenses of low
specific conductance water were also found near the surface on transect
1-6.   These results indicate a considerable amount of mixing in an area
extending from  Lake Michigan south of Bois Blanc Island to Stations
40-42  in Lake Huron.

Water  flowing out of Detour Passage was identifiable by low specific
conductance,  less than 130 pmhos at Station 48, and by relatively  warm
temperature (App. C.18).

On transect 24-31, upwelled water had specific conductance values  of less
than 2.1 in the vicinity of Station 30.  There was also a lens of  low
specific conductance water near Government Island at Station 31—this
lens was associated with relatively low water temperature but was  not
correlated with either silica or pH (App. C.14).

Hydrogen Ion  Concentration

Largest values  for pH  were found on transect 1-6, at transects 13-23
south  of Bois Blanc Island and at the south end of the two transects east
of Bois Blanc Island.  These values ranged from >8.4 to >8.6, values
which  would be  typical of Lake Michigan water.  Highest values were
found  at Station 01 at the surface and between 10 and 15 m at Stations
18 and 19.  Since Station 20 was not sampled, it is difficult to ascer-
tain the distribution  of water masses on transect 17-20.

Minimum values for pH  ranged from 8.0-8.1 and were found in deep waters
on the two transects east of Bois Blanc Island, north of Mackinac  Island
and in the water flowing out of Detour Passage.


Silica

High silica concentrations were found at Station 04 in Lake Michigan.
Since these high values were associated with values for specific conduct-
ance of 220 ymho they presumably can be attributed to the intrusion of
                                    26

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Lake Huron water (App. C.2).  South of Bois Blanc Island, the isopleths
for silica appear to run in the vertical plane rather than horizontal;
interesting is the fact that on two transects the largest values are on
the south shore and on the other transect they are on the north shore
(App. C.8, C.ll).  The presence of isopleths in this area that extend
from the surface to the bottom, separating the water into horizontal
components, is suggested also by the data for water temperature, specific
conductance and pH.  The relationships suggest mixing of Lake Huron and
Lake Michigan waters.  It is very obvious on transect 24-31 (App. C.14)
that discrete water masses are present in the horizontal plane—partly
due to the surface water mass along the south shore and partly to the
upwelled water in the vicinity of Station 30.

Epilimnetic water with a silica concentration of 1.8 mg/liter can be
attributed to the influence of water flowing out of Detour Passage.  As
would be expected, high silica water is present in the deeper waters of
the two transects east of Bois Blanc Island (App. C.14, C.18).  These
values range from 1.8 to 2.2 mg/liter—concentrations characteristic of
Lake Superior water; however, due to the conductivities greater than
200 ymho associated with this water, the origin of high silica is not
attributable directly to the presence of Lake Superior water.  The
specific conductance indicates that a considerable portion of this water
originated in Lake Huron.
3.5 PHYSICAL-CHEMICAL CONDITIONS  IN OCTOBER


Water Temperature

In October there was no  thermal stratification on the Lake Michigan tran-
sect nor on those  south  of Bois Blanc Island  (App- C.3, C.9, C.12).
Temperature on  these transects ranged from 12° to 14°C.  On transects
north and west  of  Bois Blanc  Island, the epilimnion was 25-30 m deep,
(App. C.15, C.19)  but on the  transect northwest from Mackinac Island
(App. C.6) there was no  thermal stratification to a depth of 35 or 40 m.
Warmest temperatures were found on the transect in Lake Michigan and in
the water flowing  out of Detour Passage (Stations 46-48).


Specific Conductance

On the Lake Michigan transect, the relatively homothermous waters were
reflected by small variations in  specific conductance with values ranging
from <240 ymho  to  <250 ymhos  (App. C.3).  On two transects south of Bois
Blanc Island (App. C.12)  there was an intrusion of lower conductivity
water along the south shore of Bois Blanc Island with values ranging from
200-220 ymhos.  This low conductivity water, based on conductivities on
transect 24-31, apparently represented an intrusion of Lake Huron water
(App. C.15).  Relatively high conductivity water extended along the south
shore of the study area  from  Station 01 to Station 40.
                                   27

-------
 Water  from Detour  Passage was easily identified by low specific conduct-
 ance values,  ranging as  low as 120 pmho at Station 48 (App. C.19).


 Hydrogen  Ion  Concentration

 Values for pH were relatively uniform on the Lake Michigan transect and
 on those  south  of  Bois Blanc Island.  Like specific conductance, larger
 values were present along the south shore of the study area, but unlike
 specific  conductance, there was less variation from east to west with
 the range of  values being approximately 0.2 pH units or from >8.3 to
 >8.5.   East and north of Bois Blanc Island, surface pH values ranged from
 8.10 to <8.3  with  water  from the Detour Passage having a pH of about 8.1.
 Subsurface values  for pH ranged as low as 7.8 at Station 37 north of
 Bois Blanc Island,  but in general most values were not lower than 8.0.


 Silica

 On the Lake Michigan transect, Stations 01-06, there was evidence of
 vertical  as well as horizontal distributions of silica (App. C.3).  Ver-
 tical  stratification was present at the three stations on the south end
 of the transect, but to  the north of Station 03 the gradients were
 horizontal, increasing northward from 1.2 to >1.4 rag/liter.  The same
 range  of  values was present at Stations 01-03, but with values increasing
 with depth from the surface to the bottom.

 South  of  Bois Blanc Island the distribution of silica was relatively
 complex,  with different  patterns of distribution on each of the three
 transects sampled.  Smallest values were found on transect 13-16, values
 that were less  than or equal to those found on the Lake Michigan tran-
 sect (App.  C.9).   On the next transect to the east, 17-20, the values
 were all  equal  to  or greater than the largest values for transect 13-16.
 In addition,  on transect 17-20 the smallest values were found in the
 middle of  the transect,  which was due partly to two large values for
 silica found  at  Station  17 (App. C.12).  One of the values at Station 17
 exceeded  2.0  mg/liter (surface), but this value appeared real since the
 5-m value was 1.7 mg/liter.  The pattern of low values at mid-transect
 was repeated  on  transect 21-23, and on both transects 17-20 and 21-23
 isopleths  indicated horizontal gradients of silica.  Horizontal gradients
 of  silica concentration  were also found on the transect north of Mackinac
 Island  (App.  C.6),  along the north end on transect 32-37 (App. C.17) and
 possibly on the north end on transect 24-31 (App. C.15).  These relation-
 ships  indicate a homogeneous mass of water along the north shore which
may be a mixture of water from Detour Passage (App. C.19) and Lake Huron.
 If  this is the case, as  suggested by the distribution of specific conduct-
ance,   then it may have been produced by westerly currents along the north
shore.

Water  flowing out of Detour Passage had a silica concentration of 2.2 rag/
liter,  comparable to what would be expected from a source in Lake Superior
                                    28

-------
(Table 1.1).  Below 30 m on the three transects with deep water north
and east of Bois Blanc Island, vertical stratification of silica was also
present.

On this cruise, surface values for silica were generally higher along the
north shore of the study area and lowest on the south shore.  The one
obvious exception is Station 17 along the south shore, which had one of
the highest values for silica, the origin of which is not known.
3.6 CORRELATION OF PHYSICAL, CHEMICAL AND PHYTOPLANKTON COMMUNITY
    PARAMETERS

As a preliminary step to data analysis, 14 correlation matrices were
run, one for each of the following tables:

     Table 3.2   All cruises, all depths, with missing data
           3.3   All cruises, 5-m depths, without missing data
           3.4   August, all stations, all depths
           3.5   September, all stations, all depths
           3.6   October, all stations, all depths

                 All cruises, all depths:
           3.7   Stations 01-06
           3.8            07-10
           3.9            11-12
           3.10           13-23
           3.11           24-31
           3.12           32-37
           3.13           38, 39, 49, 50
           3.14           40-45
           3.15           46-48

The data were therefore analyzed as a total group, as groups for each
cruise, and as groups similar to those listed in Table 3.1.

Although significant correlations do not connote causal or functional
relationships between two factors, they do indicate associated variables
and how one parameter varies in relation to another parameter.  Several
associations were found by examining the correlation matrices.


Relationships Among Temperature, pH, Nitrate and Silica

Highly significant correlation coefficients were found for the six
possible correlation coefficients for temperature, pH, nitrate and silica
(Table 3.2).  These results show that high silica and nitrate concentra-
tions and low pH values are associated with cold water with the converse
being true for warm water, or that temperature was correlated negatively
with silica and nitrate and positively with pH.  Highly significant
                                   29

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Table 3.2.  CORRELATION  OF DATA FOR ALL CRUISES,  ALL DEPTHS.   N = 768,
                              R @ .99 = .10.

Secchi
Temp
pH
C14-ls
Chi
Si02
N03
P Tot
Table 3.3.
Secchi
1.00
-0.33
-0.32
-0.36
-0.24
0.23
0.33
-0.09
Temp

1.00
0.86
0.11
0.41
-0.79
-0.78
0.14
CORRELATION
MISSING
pH C14-ls Chi


1.00
0.16 1.00
0.48 0.24 1.00
-0.84 -0.16 -0.36
-0.78 -0.38 -0.36
0.10 0.16 0.23
OF DATA FOR ALL CRUISES,
VALUES. N = 98, R <§ .99
Si02 NO 3 P Tot





1.00
0.75 1.00
-0.04 -0.11 1.00
5-M DEPTHS WITH NO
= .26.


Secchi
Temp
pH
Cl4-ls
Chi
Si02
NO 3
P Tot
Secchi
1.00
-0.22
-0.17
-0.37
-0.06
-0.02
0.21
-0.16
Temp

1.00
0.78
0.13
-0.25
-0.68
-0.68
-0.02
pH Cl4-ls Chi


1.00
0.16 1.00
-0.21 0.26 1.00
-0.80 -0.15 0.29
-0.73 -0.42 0.08
-0.13 0.20 0.11
Si02 N03 P Tot





1.00
0.62 1.00
0.20 -0.10 1.00
                                   30

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Table 3.4.  CORRELATION OF DATA FOR AUGUST—ALL STATIONS, ALL DEPTHS.
                      N = 199, R @ .99 =  .19.

Secchi
Temp
pH
C14-ls
Chi
Si02
N03
P Tot
Table 3.5.
Secchi
1.00
-0.42
-0.42
-0.34
-0.35
0.47
0.49
-0.61
Temp

1.00
0.95
0.19
0.34
-0.95
-0-87
0.28
CORRELATION
N =
pH Cl4-ls Oil Si02 NO 3


1.00
0.08 1.00
0.44 0.04 1.00
-0.96 -0.20 -0.40 1.00
-0.86 -0.25 -0.34 0.87 1.00
0.28 -0.03 0.31 -0.29 -0.25
OF DATA FOR SEPTEMBER—ALL STATIONS, ALL
259, R @ .99 = .16.
P Tot







1.00
DEPTHS


Se cchi
Temp
pH
C14-ls
Chi
Si02
N03
P Tot
Secchi
1.00
-0.58
-0.39
-0-43
-0.32
0.23
0.40
-0.09
Temp

1.00
0.82
0.31
0.66
-0.70
-0.73
0.21
pH C14-ls Chi Si02 N03


1.00
0.21 1.00
0.65 0.19 1.00
-0.76 -0.40 -0.61 1.00
-0.62 -0.40 -0.50 0.74 1.00
0-07 0.12 0-15 -0.11 -0.16
P Tot







1.00
                                   31

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Table 3.6.  CORRELATION  OF DATA FOR OCTOBER—ALL  STATIONS, ALL DEPTHS.
                       N = 313,  R @ .99  =  .15.

Secchi
Temp
pK
C14-ls
Chi
Si02
NO 3
P Tot
Table 3.7.
Secchi
1.00
-0.49
-0.16
-0.12
-0.17
0.01
0.23
-0.01
Temp

1.00
0.72
0.39
0.68
-0.34
-0.62
0.26
CORRELATION OF
DEPTHS .
PH C14-ls Chi Si02 N03 P Tot


1.00
0.14 1.00
0.59 0.38 1.00
-0.60 0.05 -0.33 1.00
-0.75 -0.54 -0.40 0.39 1.00
0.17 0.36 0.27 0.01 -0.16 1.00
DATA FOR STATIONS 01-06, ALL CRUISES, ALL
N = 77, R @ .99 = .30.


Secchi
Temp
PH
C14-ls
Chi
Si02
NO 3
P Tot
Secchi
1.00
-0.23
-0.36
-0.15
-0.33
0.50
-0.15
0.15
Temp

1.00
0.87
-0.12
-0.05
-0.89
-0.55
-0.03
pH C14-ls Gil Si02 N03 P Tot


1.00
-0.65 1.00
-0.10 0.76 1.00
-0.90 0.31 0.55 1.00
-0.50 -0.23 -0.02 0.44 1.00
-0.08 0.38 0.29 0.14 -0.05 1.00
                                  32

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Table 3.8.  CORRELATION OF DATA FOR STATIONS 07-10, ALL CRUISES»  ALL
                   DEPTHS.  N - 66, R @ .99 = .32.


Secchi
Temp
pfi
C14-ls
Chi
Si02
NO 3
P Tot
Table .
Secchi
1.00
0.38
-0.04
-0.36
0-49
-0.07
0.02
0.59
Temp

1.00
0.85
-0.14
0.41
-0.91
-0.90
0.12
3.9. CORRELATION
DEPTHS
pH C14-ls Chi Si02 N03


1.00
0.02 1.00
0.29 -0.18 1.00
-0.95 -0.14 -0.27 1.00
-0.95 -0.08 -0.23 0.97 1.00
-0-08 -0.37 0.25 -0.05 0.09
OF DATA FOR STATIONS 11-12, ALL CRUISES,
. N = 27, R @ .99 = .49.
P Tot







1.00
ALL


Secchi
Teiap
PH
C14-ls
Chi
Si02
NO 2
P Tot
Secchi
1.00
0.03
-0-41
-0.55
-0.18
0.38
0.15
-0.12
Temp

1.00
0.86
0.09
-0.29
-0.84
-0.95
-0.18
pK Cl4-ls Chi SiO:. N03


1.00
0.46 1.00
-0.06 0.17 1.00
-0.93 -0.41 0.22 1.00
-0.91 -0.29 0.12 0.87 1.00
-0.12 -0.20 0.09 0.20 0.84
P Tot







1.00
                                  33

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Table-3.10,  CORRELATION  OF DATA FOR STATIONS 13-23,  ALL CRUISES, ALL
                   DEPTHS.  N = 110, R @ .99 = .25.

Secchi
Temp
pH
CU-ls
Chi
Si02
NO 5
P lot
Table 3
Secchi
1.00
-0.17
-0.35
-0.73
-0.43
0.23
0.10
0.10
Temp

1.00
0.90
0.15
-0.37
-0.82
-0.54
0.03
.11. CORRELATION
DEPTHS
pH C14-ls Chi Si02


1.00
0.32 1.00
-0.23 0.32 1.00
-0.73 -0.21 0.23 1.00
-0.59 -0.31 0.11 0.39
-0.05 -0.02 -0.12 0.01
OF DATA FOR STATIONS 24-31, ALL
. N = 207, R @ .99 = .18.
N03 P Tot






1.00
0.13 1.00
CRUISES, ALL


Secchi
Temp
pH
Cl4-ls
Chi
Si02
N03
P Tot
Secchi
1.00
0.10
-0.10
-0.50
-0.17
-0.02
-0.03
-0.17
Temp

1.00
0.85
0.26
0.36
-0.88
-0.84
-0.15
pH C14-ls Chi Si02


1.00
0.60 1.00
0.46 0.13 1.00
-0.87 -0.47 -0.39 1.00
-0.74 -0.53 -0.31 0.85
-0.05 -0.38 0.20 0.13
NO 3 P Tot






1.00
0.20 1.00
                                   34

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Table 3.12.  CORRELATION  OF DATA FOR STATIONS 32-37, ALL CRUISES,  ALL
                   DEPTHS.  N = 90, R @ .99 = .27.

Secchi
Temp
pE
C14-ls
Chi
Si02
NO 3
P Tot
Table 3
Secchi Temp
1.00
-0.19 1.00
-0.34 0.90
0.38 -0.79
0.07 0.41
0 . 39 -0 . 86
0.40 -0.88
0.57 -0.05
. 13 . CORRELATION
CRUISES, ALL
pH C14-ls Chi S102


1.00
-0.77 1.00
0.50 0.66 1.00
-0.92 0.82 -0.33 1.00
-0.84 0.68 -0.25 0.82
-0.12 0.14 0.24 0.22
OF DATA FOR STATIONS 38, 39, 49,
DEPTHS. N = 57, R @ .99 = .34.
N03 P Tot






1.00
0.32 1.00
50, ALL


Se cchi
Temp
pH
C14-ls
Chi
Si02
N03
P Tot
Secchi Temp
1.00
-0.39 1.00
-0.46 0.66
-0.67 0.78
-0.15 0.74
0-28 -0.68
0.25 -0.44
-0.02 -0.16
pH C14-1S Chi Si02


1.00
0.63 1.00
0.53 0.23 1.00
-0.69 -0.38 -0.58 1.00
-0.57 -0.49 -0.53 0.75
-0.003 0.20 0.05 -0.03
NO 3 P Tot






1.00
-0.29 1.00
                                   35

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Table 3.14.  CORRELATION OF DATA FOR STATIONS  40-45,  ALL  CRUISES,  ALL
                   DEPTHS.  N = 104, R @ .99 = .25.


Secchi
Temp
pK
Cl4-ls
Chi
Si02
NO;
P Tot
Table 3

Secchi
1.00
-0.20
-0.14
0.08
-0.09
0.13
0.28
0.09

Temp

1.00
0.83
-0.24
0.69
-0.62
-0.67
0.27
.15. CORRELATION
DEPTHS

pH C14-ls Chi Si02


1.00
-0.20 1.00
0.83 0.12 1.00
-0.58 -0.70 -0.59 1.00
-0.60 -0.62 -0.51 0.84
0.15 0.14 0.18 -0.21
OF DATA FOR STATIONS 46-48, ALL
. N = 32, R @ .99 = .45.
N03 P Tot






1.00
-0.28 1.00
CRUISES, ALL


Secchi
Temp
PH
CIA-Is
Chi
Si02
NO 3
P Tot
Secchi
1.00
-0.30
0.53
-0.37
-0.25
-0.66
0.43
-0.28
Temp

1.00
0.32
-0.58
0.35
0.43
-0.18
0.14
pH C14-1& Chi Si02


1.00
-0.04 1.00
0.13 0.71 1.00
-0.26 0.28 0.48 1.00
0.07 -0.26 -0.32 -0.42
-0.26 0.29 0.55 0.39
NO 3 P Tot






1.00
-0.16 1.00
                                   36

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correlation coefficients were found because the water column was strati-
fied thermally and chemically for most of the stations.  To a lesser
extent, these relationships were found because water from Lake Huron and
the outflow from the St. Marys River were usually colder than the surface
waters of Lake Michigan (Table 3.3).  Surface water from Lake Michigan
had higher pH and lower silica and nitrate than the other waters.

That nitrate, silica, and pH were correlated with temperature can be seen
from the correlation matrices for the three cruises.  On Cruise 1, when
water temperature differences were greatest among the stations, the six
correlation coefficients for the variables ranged from  .86 to .96
(Table 3-4) and on Cruise 2 from .62 to  .82 (Table 3.5).  By Cruise 3,
when thermal stratification was limited  to a few stations, correlation
coefficients of silica with temperature  and nitrate were -.34 and .39
and the other correlation coefficients ranged from  .60  to .75 (Table 3.6).
Only eight other correlation coefficients for silica, nitrate, temperature
and pH were less than 0.5.  Two of these were between nitrate and silica
for Stations 13-23 (Table 3.10) and between nitrate and temperature for
Stations 38, 39, 49, 50 (Table 3.13).  The remaining six were all the
coefficients for Stations 46-48 (Table 3.15).

Correlations for nitrate, silica, pH and temperature at Stations 46-48
obviously differed from the other stations.  Not only were all the cor-
relation coefficients less than -42 (Table 3.15), but some had opposite
signs in comparison to the other groups.  The correlation coefficient
for silica and nitrate was -.42 whereas  all other coefficients for this
pair of variables were positive (Tables  3.2-3.14).  Silica likewise was
positively correlated with temperature,  but the relationship was negative
at other stations.  The positive correlation of silica and temperature
is related to water originating in the St. Marys River with higher silica
and temperature than the adjacent waters in Lake Huron.  In other areas
of the lake, warm surface waters were silica-depleted in relation to the
colder and deeper waters.

Relationship of Nutrients and Chlorophyll

In nutrient-limited systems, the standing crop of phytoplankton might be
expected to be correlated with nutrients and other phytoplankton community
parameters.  These relationships can be  tested partly from correlation
coefficients between the standing crop of phytoplankton, measured as
chlorophyll a, and other parameters such as concentration of silica,
nitrate and total phosphorus, rate of carbon-14 uptake, and Secchi disc
transparency.  Although chlorophyll was  not consistently correlated with
any of these parameters, most of the correlations among these variables
were highly significant (Table 3.16).

Correlation coefficients for silica and  chlorophyll were highly signifi-
cant, excepting those for Stations 07-10, 11-12, and 13-23 (Table 3.16).
Some of the highly significant correlations, however, were positive while
others were negative.  Highly significant positive correlation coefficients
                                    37

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 Table 3.16.  CORRELATIONS OF RATE OF CARBON FIXATION, SECCHI DISC TRANS-
    PARENCY, AND CONCENTRATION OF SILICA, NITRATE AND TOTAL PHOSPHORUS
             WITH CHLOROPHYLL A.  Data from Tables 3.2-3.15.
a
r
.30
.32
.49
.25
.18
.27
.34
.25
.45
.26
.10
.19
.16
.15
Station
01-06
07-10
11-12
13-23
24-31
32-37
38, 39, 49, 50
40-45
46-48
allb
all
A
S
0
N
77
66
27
110
207
90
57
104
32
98
768
199
259
313
C-14
.76
-.18
.17
.32
.13
.66
,23
.12
.71
.26
.24
.04
.19
.38
Secchi
-.33
.49
-.18
-.43
-.17
.07
-.15
-.09
-.25
-.06
-.24
-.35
-.32
-.17
Si02
,55
-.27
.22
.23
-.39
-.33
-.58
-.59
.48
.29
-.36
-.40
-.61
-.33
NO 3
-.02
-.23
.12
.11
-.31
-.25
-.53
-.51
-.32
.08
-.36
-.34
-.50
-.40
TPOit
.29
.25
.09
-.12
.20
.24
.05
.18
.55
.11
.23
.31
.15
.27
  Approximate  critical value for r at the .01 probability level.

   Only at  5-meter depths where there were no missing data.
were obtained at Stations 01-06 with the most silica-depleted water
(Table 3.7) and with the complete set of data that included only near-
surface samples for which all data were available (Table 3.3).  Both sets
of data indicate silica was limiting, since standing crops increased with
larger concentrations of silica.  At Stations 46-48, the positive correla-
tion coefficient seems to have resulted from relatively large concentra-
tions of silica in the St. Marys River water (Table 3.15).  Correlation
coefficients for chlorophyl of .71 with carbon fixation and .55 with
total phosphorus indicate that water  from the St. Marys River was phos-
phorus-limited, as the phytoplankton community parameters increased with
phosphorus concentration.

Highly significant correlation coefficients for nitrate and chlorophyll
were all negative, indicating that in at least these groups of stations
nitrate was not limiting or that increased standing crops of chlorophyll
reflected nutrient decreases or nutrient utilization by phytoplankton
(Table 3.16).
                                    38

-------
Few highly significant correlations were obtained between chlorophyll and
total phosphorus (Table 3.16).  It is important to note, however, that
for the complete data set and for the data by cruises there were highly
significant correlations.  The correlation coefficients were small, prob-
ably reflecting the large variances in these two groups of data.

Most of the correlations between rates of carbon fixation and chlorophyll
were positive, as expected, but only about half of the coefficients were
highly significant (Table 3.16).  Since rates of carbon fixation were
measured at only 5 m, the only meaningful correlation may be the one for
the 5-m samples.  For this group of samples the correlation coefficient
and the critical value for r were equal.  Only three sets of coefficients
indicated that measurements of chlorophyll a and rates of carbon-14 were
as highly related as measurements of temperature, nitrate, silica and
pH.  These were the coefficients for Stations 01-06, 32-37 and 46-48,
but the causes for only finding a small number of these highly related
measures are not obvious.

Most of the correlations between Secchi disc transparency and chlorophyll
were negative, as expected, but only half of the coefficients were highly
significant (Table 3.16) .  One of the highly significant values, .49 for
Stations 07-10, was positive, which we cannot explain.  Like chlorophyll,
the complete data set and the samples by cruises had highly significant
correlations.  In addition, highly significant correlations were found
for Stations 01-06 and 13-23.  It was obvious that transparency measure-
ments could not have been used to estimate standing crops of chlorophyll.

Correlations by themselves are not particularly illuminating.  In
Section V, multivariate techniques are used to analyze the data set.
3.7 LITERATURE CITED

Kamphake, L. J.,  S. A. Hannah, and J. M. Cohen.  1967.  Automated analysis
     for nitrate  by hydrazine reduction.  Water Res. 1: 205-216.

Ladewski, T. B. and E. F.  Stoermer.  1973.  Water transparency in south-
     ern Lake Michigan in  1971 and 1972.  Proc. 16th Conf. Great Lakes
     Res.: 791-807.   Internat. Assoc. Great Lakes Research.

Rousar, D. C.  1973.  Seasonal and spatial changes in primary production
     and nutrients in Lake Michigan.  Water, Air, and Soil Pollution 2:
     497-514.

Santiago, M. A.,  Saundra Fielek and C- L. Schelske.  1975.  Automated
     method for sulfate determination in lake water.  Water Quality
     Parameters,  ASTM STP  573, Amer. Soc. for Testing and Materials,
     p. 35-46.
                                    39

-------
Schelske, C. L. and E. Callender.  1970.   Survey of phytoplankton produc-
     tivity and nutrients in Lake Michigan and Lake Superior.   Proc.  13th
     Conf. Great Lakes Res.: 95-105.   Internat.  Assoc.  Great Lakes
     Research.

	, L. E. Feldt, M. A. Santiago and E. F.  Stoermer.  1972.
     Nutrient enrichment and its effect on phytoplankton production and
     species composition in Lake Superior.   Proc.  15th  Conf. Great Lakes
     Res.: 149-165.  Internat. Assoc.  Great Lakes  Research.

Strickland, J. D. H. and T. R. Parsons.  1968.  A  practical handbook  of
     seawater analysis.  Bull. Fish. Res.  Bd.  Canada No.  167.   311 p-

Wolfe, D. A. and C. L. Schelske.  1967.  Liquid  scintillation and geiger
     counting efficiencies for carbon-14  incorporated by  marine phyto-
     plankton in productivity measurements.  J.  Cons. Perm. int.  Explor.
     Her. 31: 31-37.
                                   40

-------
                                SECTION IV

     WATER MASSES AND DILUTION OF SURFACE WATERS IN THE STRAITS AREA
                                    by

                           Theodore B. Ladewski
Epilimnetic water may be considered to be bounded on the top by the air-
water interface and on the bottom by the thermocline.  The degree to
which the epilimnetic water is affected by inputs across the top and
bottom boundaries is difficult to quantify, but will be a function of the
transit time of water through the Straits area, which was estimated to
be 19 days.  Inputs across the upper surface will be assumed to be unim-
portant over this transit time and will be ignored.  Except in the case
of obvious upwelling, inputs from the hypolimnion will also be ignored,
leaving three major inputs to the Straits survey area:  Lake Michigan,
the St. Marys River, and Lake Huron.  The flow from the St. Marys River
at Detour Passage was estimated to be 2000 m3 sec"1 (Powers and Ayers
1960) .  The average net flow at the Straits between 9 August and 13
November 1973 above 20 m was 3320 m3 sec"1 (Saylor and Sloss, In press) .
The next largest source of water is the Cheboygan River with an average
flow of 21 m* sec"1 between August and October 1973 (USGS 1973, 1974).
Since this source is dwarfed by comparison with the flow from Lake
Michigan and the St. Marys River, it and other rivers in the area likely
have only minor effects on the surface waters.

The purpose of this section is to describe and provide background infor-
mation on relationships among surface-water masses related to the three
major inputs during the period of our study.

To trace the water movements from Lake Michigan and the St. Marys River
into the Straits area, conservative parameters were needed.  "Conserva-
tive concentrations" are defined by Sverdrup et al. (1942) as those
"that are altered locally, except at the boundaries, by the processes of
diffusion and advection only."  An alternate definition for "conserva-
tive," used in this paper, is:  A quantity is conservative if its
measured value X in a mixture of volumes V.^ of water from N different
sources is equal to:
                   N

               X = i=l ViXi                                           (1)
                   N
                   I   V
                                     41

-------
 where Xj_ = measured  value of  the parameter at  source  1^   This  relation-
 ship may be rewritten as:
                  N
                  I FXi             where
                                                N
 A conservative parameter therefore is one which dilutes proportionately
 with  its  quantity  in  the water.  Examples of parameters not conserved
 according to  this  definition are pH, Secchi depth or any which are sub-
 ject  to biological or chemical reactions or to phase change.

 Temperature and  conductivity were chosen as conservative parameters to
 be used to trace water masses because these measurements are simple and
 subject to little  experimental error.  Conductivity is a function of
 concentrations of  all ions including bicarbonate.  However, its correla-
 tion  with chloride at 5 m is quite high (r = .96) so it may be considered
 to be relatively unaffected by the biota.  Water temperature could not
 be considered conservative if local cooling or warming rates are compara-
 ble to rates  of  temperature change due to surface-water mixing.  The size
 of the survey region  is sufficiently small on a meteorological scale so
 it is reasonable to expect air temperatures and other meteorological
 conditions to be relatively uniform over the area at any one time.  Cli-
 matic cooling will reduce the resolution of the technique of using water
 temperature to distinguish water masses but is not likely to be a factor
 during a  3-day cruise.
 4.1  RESULTS

 To identify water masses, temperature was plotted vs. conductivity.
 Clusters of stations with similar temperature and conductivity were
 circled and labeled on Figure 4.1 and the geographical locations indi-
 cated on Figure 4.2.  The difference in the locations between 24 and 24R
 or 30 and 30R, two stations which were sampled on different days, indi-
 cated the extent of daily variation and measurement error of temperature
 and  conductivity.  It is evident that there are three extreme regions:
 MI located west of the Straits in Lake Michigan at Stations 01-03, Hj
 located east of the Straits in Lake Huron at Stations 41 and 42, and Sj
 located at Station 48 at the mouth of the St. Marys River.

 Sources of water with temperature and conductivity for each of the re-
 gions in Figure 4.2 are shown in Table 4.1.  It is evident that the
 regions cannot be distinguished from temperature alone since water from
 the  St. Marys River and Lake Michigan have similar temperatures.  Resolu-
 tion of water masses, however, is possible for specific conductance
 (Table 4.1).

 Stations 01, 42, and 48 may be considered as the primary sources of
water due to their location on the triangle in Figure 4.1.  The plot of

                                    42

-------
  260
                                                            LAKE MICHIGAN
                                                             M,
                            12           13
                             TEMPERATURE *C
Figure 4.1.  TEMPERATURE-CONDUCTIVITY PLOT FOR OCTOBER 5-M SAMPLES.
    Numbers refer to  the  stations at which the samples were taken.
    The temperature and conductivity of a station (at 5 m) is indi-
    cated by the position of  its  number.  Note that all stations are
    included by a triangle  connecting Stations 01,  42, and 48.  See
    Figure 4.2 for the geographic locations of the labeled regions.
                                  43

-------
                                         -84°30'
Figure 4.2.  GEOGRAPHIC LOCATIONS OF REGIONS  IDENTIFIED IN THE TEMPERATURE-CONDUCTIVITY
    PLOT OF FIGURE 4.1.

-------
Table 4.1.  SOURCES OF WATER WITH  RANGES  OF TEMPERATURE  AND  CONDUCTIVITY
                FOR REGIONS  Mls  El AND Si IN FIGURE 4.2,


Region         Source            Temperature            Conductivity
MI
HI
Si
Lake
Lake
Lake
Michigan
Huron
Superior
High
Low
High
(14.8-15
(10.5-11
(13.8-14
.0)
.0)
.3)
High
Interned .
Low
(248-252)
(214-218)
(118-146)
 the  regions  (Fig.  4.2)  also suggests that water is diluted from the  three
 sources  into the central stations of the survey area.

 Assuming three sources of water represented by Stations 01, 42 and 48,
 it is  possible to estimate the fraction of each of the three water types
 at the surface location X, if F£ (X) is defined as the fraction of water
 at X originating from source i_, where:

                     i=l  represents the source at Station 01,
                     i=2  represents the source at Station 42,
                     i=3  represents the source at Station 48.

 Since  there are three sources assumed:

                I    F±(X) = Fj(X) + F2(X) + F3(X) = 1                (2)


 for  any  surface point X inside the survey area.  Since temperature and
 conductivity are assumed to be conserved (see Eq. 1):

                Z    F±(X) I± - T(X)              and                 (3)
                I    F±(X) C± = C(X)                                  <4>
                i-1

 where:  T- is the temperature at source l^Cj. the conductivity at
 source 1/T (X) the temperature at point  X, and C (X) the conductivity
 at point X.  Equations 2, 3 and 4 were solved simultaneously for the F±
 at each station.

 Several general conclusions may be drawn  from the distribution of calcu-
 lated fractions of water from Lake Michigan, Lake Huron and the St. Marys
 River (Figs. 4.3-4.5) during the October  cruise.  First  the contours are
 generally smooth, indicating that the assumptxons behind Eqs. 2-4 and
 the hypothesis that water types can be traced using  temperature and con-
                                     45

-------
Figure 4.3.  PERCENT OF LAKE MICHIGAN WATER AT 5 M FOR OCTOBER.   Lake Michigan water ±s assumed
    to be represented by Station 01.  Numbers written at each station give the percentage of Lake
    Michigan water as calculated using temperature and conductivity.

-------
                                                                      84-ocr-
Figure 4.4.  PERCENT  OF LAKE HURON WATER AT 5 M  FOR OCTOBER.

-------
.p-
00
                                  -84-45'


                                Figure 4.5.  PERCENT OF ST. MARYS RIVER WATER AT 5 M FOR OCTOBER.

-------
ductivity are valid.  One apparent  inconsistency  for  Station 17 may be
due to effects from the Cheboygan River which would be expected to have
a high temperature and conductivity,  thus making  it appear, on the basis
of these parameters, as a station characteristic  of Lake Michigan.

Second, little water from Lake  Michigan was  present in the northeastern
corner of the sample area.  Water from Lake  Michigan  flowed along the
southern shore and was evident  at Station 40, on  the  southeastern corner
of the survey area, where approximately 43%  of  the water was from the
source in Lake Michigan.  This  flow of water into Lake Huron from Lake
Michigan closely parallels  the  results of Ayers et al. (1956), who showed
water of high temperature and conductivity and  high concentrations of
magnesium and calcium flowing eastward through  the Straits and along the
southern shore in all three of  their  synoptic cruises.

Third, water comprised of a mixture from the St.  Marys River and Lake
Huron flowed westward along the northern shore  from Detour Passage.
Since Detour Passage is situated on the eastern edge  of the survey area,
it is not clear whether there is an additional  flow eastward.  Either an
eastward or westward current may occur at Detour  Passage, although the
westward current appears more predominant  (Ayers  et al. 1956).  In addi-
tion, the water from the area of Station 42, initially identified as
coming from Lake Huron, appears to  be moving north and west.  This appar-
ent northward current at Station 42 is consistent with observation of
similar northward currents  measured by drogues  in the summer of 1966
(Sloss and Saylor, In press) .   Apparently, mixing of  Lake Huron and
St. Marys River water occurred  in the northeastern half of the survey
area with very little inclusion of  Lake Michigan  water (Fig. 4.3).

Six regions were identified from the  plot of temperature vs. conductivity
(Fig. 4.6) for September samples, as  indicated  on the map of the study
area  (Fig. 4.7).  At this time  one  distinct  water mass, S, was identified
as originating from the St. Marys River.  The remaining five regions are
distributed along a gradient from MI, with the  highest temperature and
conductivity, to U with the coldest temperature and an intermediate
conductivity.  In contrast  with the previous cruise,  Lake Michigan water
with a specific conductance of  265  ymho was  not present at Stations 01-06;
the highest specific conductance, 250 pmho,  was found at Station 23-
These conductivity relationships indicate that  considerable mixing of
Lake Michigan and Lake Huron waters occurred in the MI and M2 regions.

Region U is cold with a high nitrate  concentration characteristic of
hypolimnetic water (Table 4.2), suggesting that upwelling occurred at
region U prior to the time  of sampling.  The conductivity is lower in
region U than in the hypolimnion, indicating that hypolimnetic water
mixed with westward flowing water from the St.  Marys  River.

Regions US and UM appear to be  derived from  a mixture of waters from U
and S and U amd M.  The location of these regions (Fig. 4.7) and their
intermediate temperature suggests they orginated  from an upwelling along
                                    49

-------
 260
  240
  220
§
  200
E
   180
o
z>
o
o
o  |60
   140-
   120
                       UM.
                  10     II      12      13

                          TEMPERATURE  °C
14
IS
16
17
Figure 4.6.  TEMPERATURE-CONDUCTIVITY PLOT FOR SEPTEMBER 5-M
    SAMPLES.  Numbers  refer  to  stations at which the samples
    were taken.   See Figure  4.7 for the geographic locations of
    the labeled regions.
                                50

-------
Figure 4.7.  GEOGRAPHIC LOCATIONS OF THE REGIONS IDENTIFIED ON THE BASIS OF THE T-C PLOT OF
    FIGURE 4.6.

-------
           Table 4.2.  SUMMARY OF NITRATE, SILICA, TEMPERATURE, AND CONDUCTIVITY VALUES FOR SEPTEMBER.
Ul
N)

Parameter
N03
Si02
Temp.
Cond.
Table
Overall range
for 5-m
samples
133 - 362
.73 - 1.89
8.5 - 16.8
126 - 253
4.3. SUMMARY OF
Range for
samples below
40 m
296 - 393
1.32 - 2.23
4.2 - 6.1
220 - 222
Range in
region U
(5 m)
274 - 362
Range in Range in
region S region MI
(5 m) (5 m)
258 - 295 133 - 252
1.26 - 1.50 1.85 - 1.89 .73 - .87
8.5 - 10.0 13.2 - 13.8 15.8 - 16.
163 - 219
NITRATE, SILICA, TEMPERATURE, AND
126 - 142 223 - 247
CONDUCTIVITY VALUES FOR
Units
MgN/1
mgSi02/l
8 °C
ymho/cm
AUGUST .

Parameter
N03
Si02
Temp.
Cond.
Overall range
for 5-m
samples
126 - 244
.43 - .96
17.0 - 22.0
196 - 225
Range for
samples below
40 m
306 - 364
1.45 - 1.96
4.5 - 7.5
215 - 222
Range in
region U
(5 m)
188 - 244
.43 - .91
17.0 - 18.
200 - 227
Value at
region H
(station 25, 5m)
214
.70
1 20.9
197
Units
ygN/1
mgSi02/l
°C
ymho/cm

-------
the northern shore some time prior to the survey or to an intrusion of
relatively cool Lake Huron water.

Unfortunately stations representative of the sources were not sampled,
as indicated by Figure 4.6, so  it is not possible to compute the fraction
of water from each source as was done for the October samples (Figs. 4.3-
4.5).  Instead of three sources, there appear to be at least four sources
for surface water in the survey area:  surface waters of Lake Michigan,
Lake Huron, and the St. Marys River, plus the hypolimnion of Lake Huron.
An additional conservative parameter would be needed to compute fractions
from each source.  Nevertheless, the stations do form a rough triangle,
suggesting that the most important sources are Lake Michigan, St. Marys
River and the hypolimnion of Lake Huron.

Five regions were identified on the plot of temperatures vs. conductivity
for the August samples, one region including only Station 25 (Fig. 4.8),
and the relationship among the  water masses is much more difficult to
interpret than the previous cruise.  A water mass characteristic of Lake
Michigan extends through the Straits and south of Bois Blanc Island
(Fig. 4.9).  Upwelled water is  present along the north shore, but the
limited sampling area makes it  difficult to determine its extent and
origin.  According to chemical  data, the upwelled water mass, U, and the
water mass at Station 25 appear to be Lake Huron water (Table 4.3) be-
cause N03-N, Si02 and conductivity are more characteristic of Lake Huron
than of the other lakes.
 4.2 LITERATURE  CITED

 Ayers, J. C., D. V. Anderson, D.  C.  Chandler and G. H. Lauff.  1956.
     Currents and water masses  of Lake Huron.  Univ. Michigan, Great
     Lakes Res. Div.  Pub.  1.  101 p.

 Powers,  C. F. and J.  C. Ayers.   1960.  Water transport studies in the
     Straits of Mackinac  region of Lake  Huron.  Limnol. Oceanogr. 5:
     81-85.

 Saylor,  J. H. and P.  W. Sloss.   In press.  Water volume transport and
     oscillatory current  flow through the  Straits of Mackinac.  J. Phys.
     Oceanogr.

 Sloss, P. W. and J. H.  Saylor.   In press.  Lake scale current measurements
     in  Lake Huron.   J. Geophys.  Res.

 Sverdrup, H. U., M. W.  Johnson  and R. H. Fleming.  1942.  The oceans:
     their physics, chemistry,  and general biology.  Englewood Cliffs:
     Prentice Hall, Inc.   1087  p.

 U.S. Geological Survey.   1973;  1974.  Water resources data for Michigan.
     Surface water records.  USGS, Okemos, Mich.
                                    53

-------
  260
  240
                         16          20          21
                        TEMPERATURE  *C
22
Figure 4.8.  TEMPERATURE-CONDUCTIVITY PLOT FOR AUGUST 5-M
    SAMPLES.  Numbers refer  to stations at which the
    samples were taken.   See Figure 4.9 for geographic
    locations.
                            54

-------
Ui
Ul
             Figure 4.9.   GEOGRAPHIC LOCATIONS OF THE REGIONS IDENTIFIED ON THE BASIS OF THE T-C PLOT OF
                 FIGURE 4.8 FOR SEPTEMBER SAMPLES.

-------
                                SECTION V

       MULTIVARIATE STATISTICAL ANALYSIS OF PHYSICAL, CHEMICAL AND
                    PHYTOPLANKTON COMMUNITY PARAMETERS
                                    by

                             Russell A. Moll
 The  Straits of Mackinac is one of the most interesting areas of the
 Laurentian Great Lakes in terms of physics, chemistry, and biology
 (Henson  1962, 1970; Powers and Ayers 1960).  The narrow juncture between
 Lake Michigan and Lake Huron is known for its unusual current conditions,
 as water is exchanged between the two lakes (Powers and Ayers 1960; Murty
 and  Rao  1970; FWPCA 1967; Mortimer 1975).  Knowledge of the distribution
 and  movement of water masses in relation to biological characteristics
 and  processes is relatively poor.  As an initial attempt to describe the
 dynamics and biology of the area, studies were conducted during the late
 summer and early fall of 1973 on the biological, chemical and physical
 characteristics, including measurement of nutrients and phytoplankton
 productivity and the distribution and abundance of phytoplankton and
 zooplankton.  Only the physical and chemical variables will be discussed
 here.  For a more extensive and comprehensive treatment of the results
 in this  section, see Moll et al. (In press).

 The  purpose of this section is to show that multivariate statistical
 techniques can be used to analyze large sets of data from the Great Lakes.
 Specifically it will be shown that water masses can be identified from
 cluster  analysis of several variables.  Data used are the same as those
 discussed in Section III, except duplicate sampling of stations were not
 used in  the analysis.  Several questions were studied:  What is the
 spatial  relationship among stations?  Was there an effect of depth on the
 parameters sampled?  Did the relationships among stations and depths vary
 from cruise to cruise?
5.1 METHODS

For factor and cluster analyses, data were normalized to mean 0.0 and
variance 1.0 which reduces units for each variable to the same numerical
range (Pielou 1969).  Computer programs used for cluster and factor
analysis are included in MIDAS (Michigan Interactive Data Analysis System),
statistical software at the University of Michigan Computing Center.
Several clustering algorithms were used, but the best results were obtained
with the unweighted pair group method (Sokal and Sneath 1963 or  Sneath
and Sokal 1973).

                                    56

-------
The relationship of each variable  to  other  variables  and  the relative
importance of each variable were investigated  with  correlation analysis;
correlations calculated between variables were also used  in a factor
analysis to show major factors affecting variability  in the data  (Van de
Geer 1971; Mulaik 1972).  Only factor loadings with eigenvalues greater
than 1.00 were used (Rummel 1970).  Values  of  the communalities for each
variable were estimated using the  iterative principal axis factor solu-
tion (Harman 1967).  Iteration was continued until  succeeding estimates
of communalities differed by less  than 1.0  x 10~3 or for  20 iterations.
An orthogonal varimax rotation was performed on the factor matrix.

Cluster analyses were run to determine the  similarities between different
stations based on nine chemical and physical parameters.  In the cluster-
ing analyses, the similarity coefficient between samples was either
Euclidean distances or correlation, with the Euclidean distances consis-
tently yielding higher cophenetic  correlations.  A  cophenetic correlation
coefficient was calculated for every  clustering analysis performed, and
only analyses with cophenetic correlations  greater  than +0.700 were
considered.  The cophenetic correlation coefficient indicates the concur-
rence between the original distance matrix  and the  end result of the
clustering analysis (Sneath and Sokal 1973) .   The only associations which
were considered of interest were those found in the lower half (based on
the number of branchings) of the phenogram.  The hierarchy of station
relationships was displayed in the phenogram by circling  clusters of
stations on a map of the sampling  area.
5.2 RESULTS


Factor Analyses

Factor analysis determined the communality or the amount of variation
unique to each variable.  A communality of 1.00 indicates the variation
was common to all variables sampled, while a value of 0.00 indicates no
variation common to the data set.  In  the Straits of Mackinac data
(Table 5.1), Secchi disc readings had  the smallest communality (0.1399);
this result implied that the measure of Secchi disc values in this area
had little intrinsic value other than  the knowledge of the Secchi disc
reading itself.  Chlorophyll values also produced a low communality of
0.2226, which could have been in part  explained by the absence of any
other phytoplankton biomass measures in the data set.  Other communali-
ties in the data set were reasonably high.

Two factors were extracted from the factor analysis with eigenvalues of
3.8676 and 1.2366 (Table 5.1).  The first factor showed an underlying
source of variation in the data composed of water temperature and pH, to
a lesser extent specific conductance and chlorophyll, and in the opposite
sign, silica and nitrate.  This could  have been considered a depth and/or
water mass factor.  Silica and nitrate generally increased with depth
while temperature, pH, and to a lesser degree specific conductance de-
creased with depth.  Likewise, water masses with high silica and nitrate


                                    57

-------
   Table 5.1.   FACTOR ANALYSIS OF STRAITS DATA.   N = 719,  number of
   factors = 2, Kaiser's statistic = .9328,  where N = number of ob-
                                servations.
    Variable
Communalities
Scaled factor loadings
  (1)           (2)
Secchi
Temp.
PH
Chlorophyll
Si02
NO 3
Total P
Sol P
Cond.

.13992
.78508
.90970
.22256
-.80841
-.78010
-.72711
.41525
.31606
Eigenvalue
% variance
-.37403
.88553
.95352
.40315
-.88669
-.88073
.06099
-.03489
.55223
3.8676
43.0
.00544
.03025
-.02228
.24500
. 14898
-.06652
.85052
.64345
-.10537
1.2366
56.7
 had low temperature,  pH,  and specific  conductance.   The  second  factor,
 apparently a phosphorus factor,  had  high  loadings for  both  total  and
 soluble phosphorus.   These results indicate  three major  factors influenced
 the data set:   depth, water  masses,  and phosphorus.

 Cluster Analyses

 Several groupings of data  were used  for clustering analyses:  1) all the
 data from Cruise 1, 2)  data  from 0,  5, 10, 15, 20, 30, and 40 m for each
 cruise,  and  3)  a reduced data set of water temperature, pH, silica,
 nitrate and  total phosphorus for 0,  5, and 10-m samples for each cruise.
 Analysis of  the entire  data  set  for  one cruise indicated that similari-
 ties among stations were related primarily to depth and that the data
 should  be analyzed by depth.

 Clusters of data for depths  greater  than 10 m were not reliable, as
 cophenetic correlations were less than 0.700 and were therefore difficult
 to interpret.   Relatively  few stations were deeper than 15 m, and data
 from  20, 30 and 40 m were more homogeneous than surface waters  so the
analysis had little value.   Definite geographical patterns of stations
were obtained from clusters  of data for 0, 5, and 10 m so these results
are discussed in the greatest detail.  Clusters from the 15-m depth
showed a transition between  the  definite patterns found at 10 m and the
lack of obvious patterns at  20 m.
                                   58

-------
Maps for Cruise 1 suggested a pattern of  surface water  flow from Lake
Michigan through the Straits, then south  of  Bois Blanc  Island  into Lake
Huron (Figs. 5.1-5.3).  This flow  pattern is indicated  by the  distribu-
tion of water masses.  At the surface,  one water mass extended from the
western edge of Mackinac Island  to the southeastern edge of  Bois Blanc
Island (Fig. 5.1).  There were two additional large water masses of sur-
face water, one directly north of  Bois Blanc Island and a second in the
northwest part of the study area.   At 5 m, stations south of Bois Blanc
Island were joined with those west of the Straits, indicating  a flow of
water south of Bois Blanc Island (Fig.  5.2).  There was no  indication
that the water mass north and northeast of Bois  Blanc Island (Stations
27-37) was related to the water  located south of the island  and west of
the Straits.  Winds during the cruise period were low in velocity and
from the southwest.  Current meters set by the Great Lakes  Environmental
Research Laboratory, NOAA, showed  that water above 10 m flowed from Lake
Michigan south of Bois Blanc Island into  Lake Huron (Saylor  and Sloss,
In press).

On Cruise 2, Stations 38-50 were added to the sampling  grid, but the
pattern of water masses was similar to  Cruise 1. It was obvious that a
distinct water mass was found to the south and southeast of  Bois Blanc
Island (Figs. 5-4-5.6); this water mass was  also related to  stations west
of the Straits.  These data indicate that a  related water mass extended
from stations west of the Straits  in Lake Michigan to stations north of
Forty Mile Point in Lake Huron.  Data for water  temperature, specific
conductance, and nitrate-nitrogen  (Table  3.1)  indicated that this area
contained a mixture of Lake Michigan and  Lake Huron water, with greater
proportions of Lake Michigan water on the west and of Lake Huron water on
the east.  Current meters set by NOAA also showed that  water flowed south
of Bois Blanc Island from Lake Michigan into Lake Huron.

Other areas of related stations  were identified: First was  the cluster
of Stations 47 and 48 (Figs. 5.4-5.6),  obviously different  from the other
stations in specific conductance,  pH, silica,  and nitrate (Table 3.1).
The chemical differences are due to the discharge of Lake Superior water
through Detour Passage.  Second  are the clusters of stations in the
northern part of the area.  These  east-west  clusters were related to
upwelling along the northern shore that is evident at Stations 29-31
(App. C.14); this upwelled water can be traced along the northern shore,
as shown in Section IV.

The final cruise occurred during a period of east winds rather than the
prevailing westerly winds.  More distinct patches or clusters of water
were identified during this cruise than from the previous cruises.  A
distinct water mass was again present south  of Bois Blanc Island, but it
was not connected to stations west of the Straits and appeared as a large
homogeneous area south of the island, extending  southeast to Forty Mile
Point (Figs. 5.7-5.9).  Two other  water masses were evident, one com-
posed of stations surrounding Mackinac  Island, the other of  stations east
of Bois Blanc Island.  Current meter data from the Straits  showed little
surface flow of water into Lake  Huron from Lake  Michigan and a transport
from Lake Huron exceeding 30,000 m3 sec'1  on 6 October  (Saylor and Sloss,


                                    59

-------
               AUGUST
           SURFACE  SAMPLES
Figure 5.1.  SURFACE WATER DISTRIBUTION IN AUGUST.   Only  the  strongest cluster associations are
    shown.

-------
              AUGUST
          5 METER SAMPLES
Figure 5.2.  FIVE-METER WATER DISTRIBUTION IN AUGUST.  Only the strongest cluster associations
    are shown.

-------
ho
                           AUGUST
                      \0 METER SAMPLES
                                                                                                 84'OCT-
            Figure  5.3.   TEN-METER WATER DISTRIBUTION IN AUGUST.   Only the strongest cluster associations
                 are shown.

-------
             SEPTEMBER
         SURFACE SAMPLES
                     -84'45'-
                                          - 84-30'
Figure 5.4.  SURFACE WATER DISTRIBUTION IN SEPTEMBER.  Only  the  strongest cluster associations
    are shown.

-------
              SEPTEMBER
          5 METER SAMPLES
                                         -64'30'
Figure 5.5.  FIVE-METER WATER DISTRIBUTION IN SEPTEMBER.  Only the strongest cluster associations
    are shown.

-------
Ln
                            SEPTEMBER
                        10 METER SAMPLES
                                   -84-451-
                                                         -84-30'
                                                                                84*15'-
                                                                                                     -04'OCT-
              Figure 5.6.  TEN-METER WATER DISTRIBUTION  IN  SEPTEMBER.  Only the  strongest cluster associations
                  are shown.

-------
   OCTOBER
SURFACE  SAMPLES
           -84*45'-
Figure 5.7.
    shown .
    SURFACE  WATER DISTRIBUTION IN OCTOBER.  Only the strongest cluster associations are

-------
    LAKE     ,.03

  MICHIGAN   |
             I ** 1
              02
            OCTOBER

         5 METER SAMPLES
I        •     	    84*45'	'	64*30'	84*15'	 '——	81'OCT	'-	'


Figure 5.8.  FIVE-METER WATER DISTRIBUTIONS IN OCTOBER.   Only the strongest cluster  associations

    are shown.

-------
00
             AfSff
                 LAKE
               MICHIGAN
                         OCTOBER
                     10 METER SAMPLES
            Figure 5.9.  TEN-METER WATER DISTRIBUTION IN OCTOBER.  Only the strongest cluster  associations
                are shown.

-------
In press) .  This 3-day period  was unusual in that  the  flow  from Lake
Michigan was small; however, on the day preceding  the  cruise  (5 Oct.) the
transport from Lake Michigan to Lake Huron exceeded  50,000  m3 sec"1!
Thermal stratification was  no  longer present at  Stations  01-06 and 13-23
on this cruise, as surface  water temperature had decreased  (Table 3.1).

A final series of clustering analyses was performed  with  a  reduced data
set to determine the  importance of certain key variables  in the relation-
ships obtained from the  complete data set.  Clustering analyses from each
cruise for 0, 5, and  10-m samples were rerun using only water temperature,
pH, silica, nitrate,  and total phosphorus—the variables  identified as
major factors from the factor  analysis (Table 5.1).  Clusters produced
from the analysis of  the reduced data set were generally  comparable with
clusters from the full data set.  For instance,  surface samples from
Cruise 1 with a reduced  data set showed clusters south and  north of Bois
Blanc Island as well  as  a water mass west of Mackinac  Island, just as
did the analysis using the  full data set (Fig. 5.2).  The results dif-
fered in that the cluster north of Bois Blanc Island was  a  little larger
in the reduced data set  than for the full data set.  Likewise, the full
data set showed the water mass west of Mackinac  Island was  related to
the mass south of Bois Blanc Island while the reduced  data  set did not
show this association.   These  differences between  the  full  and reduced
data sets for the surface samples of Cruise 1 were typical  of most compar-
isons between the full and  reduced data sets. Results from the two data
sets were most similar on Cruise 3 and least similar on Cruise 1.

Comparison of all variables with variables identified  as  major factors
pointed out the pitfalls of sampling only a small  number  of parameters
to describe water masses.  Under certain conditions  (e.g.,  as the calm
winds during Cruise 3) both the full and reduced data  sets  gave the same
results.  Under other conditions, different conclusions would have
resulted from analysis of the  full data set than from  analysis of the
reduced set.  Certain variables can be considered  "key" or  major variables
all of the time with  a good degree of reliability, but the  interaction
between those major variables  and other variables  can  rarely be predicted.
Due to unpredictable  interactions, it is necessary to  sample many varia-
bles to adequately describe water masses in unknown  regions.

From results of all the  clustering analyses, some  general conclusions
about the Straits area could be made.  A large,  homogeneous area of water
extended from Lake Michigan into Lake Huron, although  this  area was
disrupted by winds from  the east and southeast during  the cruise.  The
water mass extended generally  from Lake Michigan through  the Straits, past
the western shore of  Mackinac  Island and south of  Bois Blanc Island.
Water characteristics were  not greatly changed as  the  water mass passed
near the shore and over  shallow areas south of Bois  Blanc Island, although
there was evidence of greater  proportions of Lake  Huron water to the east-
ward.  Water from Lake Huron was frequently identified at the extreme
central-eastern part  of  the sampling area (Stations  43, 44, 45)  yet was
never associated with any water in the rest of the area.  Water from the
                                    69

-------
 St. Marys  River,  identified  by  several  chemical parameters, was  released
 into  Lake  Huron through Detour  Passage.  This water was  identifiable only
 at Stations 47  and  48  in the immediate  vicinity of the passage.  Most
 water-mass associations were found only in  the upper 10  m of  the water
 column,  with the deeper water remaining unmixed with the surface waters,
 except in  areas of  upwelling.
 5.3 LITERATURE CITED

 Federal Water  Pollution Control Administration.  1967.  Lake currents.
      FWPCA,  Great  Lakes Region, Chicago.

 Harman, H. H.   1967.  Modern  factor analysis.  University of Chicago
      Press.   474 p.

 Henson, E. B.   1962.  Notes on the distribution of the benthos in  the
      Straits of Mackinac region.  Proc. 5th Conf. Great Lakes Res.,
      Univ. Michigan, Great Lakes Research Div. Pub. 9: 174-175.

 	.   1970.   Pontoporeia affinis (Crustacean, Amphipoda) in the
      Straits  of Mackinac region.  Proc. 13th Conf. Great Lakes Res.:
      601-610.  Internat. Assoc. Great Lakes Res.

 Moll,  R.  A.,  C. L.  Schelske and M. S. Simmons.  In press.  Distribution
      of water masses  in and near the Straits of Mackinac.  J. of Great
      Lakes Res.

 Mortimer, C. H.  1975.  Physical characteristics of Lake Michigan and its
      response to applied forces, p. 1-102.  In Environmental status of
      Lake Michigan  region, Vol. 2.  Argonne Nat. Lab., Argonne, 111.
      ANL/ES-40.

 Mulaik, S. A.  1972.  Foundations of factor analysis.  New York: McGraw-
      Hill.  453 p.

 Murty, T. S. and D. B. Rao.  1970.  Wind-generated circulations in Lakes
     Erie, Huron, Michigan, and Superior.  Proc. 13th Conf. Great Lakes
     Res.: 927-941.   Internat. Assoc. Great Lakes Res.

 Pielou, E. C.  1969.  An introduction to mathematical ecology.  New York:
     Wiley-Interscience.  286 p.

Powers, C. F. and J. C. Ayers.  1960.  Water transport studies in the
     Straits of Mackinac region of Lake Huron.  Limnol. Oceanogr. 5:
     81-85.

Rummel, R. J.  1970.  Applied factor analysis.  Evanston: Northwestern
     University Press.  617 p.
                                   70

-------
Saylor, J. H. and P. W. Sloss.  In press.  Water volume transport and
     oscillatory current flow through the Straits of Mackinac.  J. Phys.
     Oceanogr.

Sneath, P. H. A. and R. R. Sokal.  1973.  Numerical taxonomy:  The princi-
     ples and practices of numerical classification.  San Francisco:
     W. H. Freeman and Co.  359 p.

Sokal, R. R. and P. H. A. Sneath.  1963.  Principles of numerical
     taxonomy.  San Francisco: W. H. Freeman and Co.  359 p.

Van de Geer, J. P.  1971.  Introduction  to multivariate analysis for  the
     social  sciences.  San Francisco: W. H. Freeman and Co.  293 p.
                                     71

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                                SECTION VI

               DISTRIBUTION AND ABUNDANCE OF PHYTOPLANKTON
                                    by
               Eugene F.  Stoermer, Russell G. Kreis, Jr. and
                           Theodore B. Ladewski
 The major  objective of  this phase of the investigation was to determine
 if there were  consistent differences in the quantitative and qualitative
 aspects of phytoplankton assemblages in Lake Michigan and Lake Huron and,
 if so, to  what extent populations developed in Lake Michigan were trans-
 ported to  Lake Huron.   Available information (Schelske and Roth 1973;
 Schelske 1975;  Vollenweider et al. 1974) suggests that Lake Michigan is
 more  eutrophied than Lake Huron.  It appears that eutrophication of Lake
 Michigan has proceeded  to the point where silica is becoming secondarily
 limiting during summer  stratification  (Schelske and Stoermer 1971), re-
 sulting in a shift of dominance in the phytoplankton assemblage from
 organisms  requiring silica to those which do not (Schelske and Stoermer
 1972; Stoermer 1972).   Possibly also secondarily related to eutrophica-
 tion, Ladewski and Stoermer (1973) show that some areas of Lake Michigan
 now have a midsummer transparency minimum similar to that observed in
 Lake  Ontario (Dobson et al. 1974).  Satellite altitude images of Lake
 Michigan (Strong et al. 1974) indicate that this phenomenon is probably
 most  highly developed in the southern and eastern portions of the lake.
 Unfortunately,  the area of our study is not included in the imagery
 reported by the above authors.

 Although comprehensive  studies are lacking, those available (Stoermer and
 Yang  1969;  Schelske and Roth 1973; Schelske et al. 1974) indicate that
 the phytoplankton assemblages of both northern Lake Michigan and northern
 Lake Huron still retain elements of the oligotrophic Cyclotella flora
 characteristic  of large boreal and alpine lakes, including relatively
 undisturbed portions of the Laurentian Great Lakes (Hutchinson 1967).

 Due to the  limited area covered by this investigation and the high prob-
 ability of  exchange and mixing between the two systems, effects in the
 Straits of  Mackinac region might be expected to be subtle and highly
 time dependent.  The evidence presented in this section, therefore,
 should be viewed as representative of specific situations.  While the
data presented may be representative of the general or average case, it
would be desirable to investigate other seasons of the year and specific
meteorological  conditions.
                                    72

-------
6.1 MATERIALS AND METHODS

The material utilized in this  phase of the investigation was obtained
from the same stations and  depths  sampled for other  parameters.  At
stations where a thermocline was present,  samples were taken from 0 and
5 m and from depths just above and just below the thermocline.  At shal-
low stations, samples were  taken from the first  four depths sampled.  In
addition to the stations sampled,  a limited number of additional collec-
tions from the same time interval  were inspected to  confirm identity of
questionable taxa or to attempt to further determine occurrence patterns
of rare species.  Immediately  after collection in Niskin bottles, 50 nil
of water were fixed with 4% glutaraldehyde,  stored at 4.0°C in the dark
for 1-4 hr toensure complete  fixation and then  filtered onto 0.8 ym
AA Millipore®, membrane filters  (25 mm  diameter).  The filtered prep-
arations were subsequently  partially dehydrated  in an ethanol series,
cleared with beechwood creosote, and mounted on  glass slides (Stoermer
et al. 1974).

All identifications and enumerations reported were made using a Leitz
Ortholux microscope fitted  with an oil immersion objective and condenser
system furnishing 1.32 numerical aperture and approximately 1200 X magni-
fication.  Population estimates were based on counting two 150-nm width,
transects 10 mm in length.  Reference samples have been retained in our
laboratory.

Raw counts were coded and prepared so all data could be reduced by
computer.  Initial data reduction  furnished population estimates in the
form given in Table 6.1.  Raw  data in this form  have been transmitted to
the project officer and are available upon request.

Principal component analysis  (PCA)  was chosen as a parametric multivari-
ate technique for analysis  of  phytoplankton cell concentrations.  Untrans-
formed cell densities were  used in the correlation matrix.  Taxa for PCA
analysis were selected using  three criteria.   First, each taxon should
be well defined taxonomically—composite  categories were avoided.  Second,
each taxon should be counted with  reasonable accuracy.  Consequently it
was required that each taxon exceed 5 colonies or individuals in at least
one sample.  Third, each taxon should be  observed in at least 30% of all
samples, eliminating locally or erratically distributed taxa; it was
never applied directly since all taxa satisfying the second criterion
also satisfied this one.  Fourteen taxa fulfilled these criteria for the
August and September cruises  and 13 for the  October cruise (Table 6.2).

Principal component analysis is a  technique  which reduces the number of
dimensions in multidimensional data and at the same time retains a maxi-
mum amount of information in  the original  multidimensional data set.
PCA performs the following  operations on  the data set.  First, each
parameter (taxon abundance) is scaled to  its standard deviation.  This
allows taxa found in low abundances to be weighted equivalently to the
more abundant taxa.  Second, each  taxon is,  in effect, assigned an axis
in a multidimensional Cartesian coordinate system, and each station is
assigned a location in the  coordinate system relative to the abundances


                                    73

-------
        Table  6.1.   EXAMPLE  OF TABULATION  OF PHYTOPLANKTON COUNTS.
                     EPJl  Straits  of  Rackinac October  1973
                project:    EPA
                   year:   1973
                station:     49
               latitude:     45°  54.1'
nonber of cells counted:    367

              diversity:      1.856
             survey number:    3
                Julian day:  280 ( 7 Oct)
                     depth:    5.0 m
                 longitude:   84° 02.6'
   volume of water scanned:    0.477 ml

                  evenness:    0.557
             division

   Cyanophyta (blue-green algae)
   Chlorophyta  (green algae)  .  .
   Bacillaciophy ta (diatoms)  .  .
   Chrysophyta  (chrysophytes).  .
   Cryptopbyta  (cryptoraonads).  .
   Pyrrophyta (dinoflagellates).
   other 	
   undetermined.
   total
number of
 species  cells/ml
     0
     2
    19
     3
     2
     1
     0
    _1_
   "28
                                                           SE
CV   X pop.
             species name

   Chrysosphaerella  longispina  	
   Fragilaria crotonensis.  .  	
   Asterionella  formosa	  .
   Cyclotella ocellata  	
   Cyclotella stelligera  ........
   Dinobryon questionable sp.  *1  .  .  .  .
   Rhodomonas minuta var. nannoplanctica
   Undetermined  cyst ..........
   Helosira distans  vars  alpiqena.  ...
   Tabellaria fenastrata  	
   Stephanodiscus ninut.us	
   Cyclotella nichiqaniana  	  .
   Ankistrodesnus sp.  *3	
   Cryptomonas ovata ....  	
   Rhizosolenia  eriensis  	
   Bitzschia acicularis	
   Oocystis questionable  spp..  .  .  «  .  .
   Jkchnanthes clevei var. rostrata  ...
   Knonoeoneis vitrea	
   Ceratiua hirundinella  	  .
   Cyclotella conta	
   Cyclotella meneghir.iana  var.  plana.  .
   Cyclotella operculata  	  .  .
   Diploceis eliiptica  var.  pygnaea.  .  .
   Diploneis cculata 	  ....
   tucocconeis lapponica  ........
   Hallononas pseudocoronata  	
   Rhizosolenia  gracilis  	
0.0
10.5
282.7
437.7
23.0
2.1
0.0
12.6
768.6
cells/ml
414.7
100.5
62.8
25. 1
20.9
20.9
16.8
12.6
12.6
12.6
10.5
8.4
6.3
6.3
6.3
4.2
ft. 2
2.1
2.1
2.1
2.1
2.1
2.1
2.1
2. 1
2.1
2.1
2.1
0.0
2.1
85.9
123.6
2.1
2. 1
0.0
4.2
39.8
SE
104.7
92.2
12.6
8.4
4.2
20.9
4.2
4.2
12.6
12.6
2.1
0.0
2.1
6.3
2.1
4.2
4.2
2. 1
2.1
2. 1
2.1
2.1
2.1
2.1
2.1
2.1
2.1
2.1
****
0.20
0.30
0.28
O.C9
1.00
****
0.33
0.05
CV
0.25
0.92
0.20
0.33
0.20
1.00
C.25
0.33
1.00
1.01
0.20
0.0
C.33
1.00
0.33
1.00
1.CO
'.CO
1.CO
1.00
1.00
1.0Q
1.00
1.00
l.CO
1.00
1.00
1.00
o.o
1.362
36.785
56.948
2.997
0.272
0.0
100.000
* pop.
53.951
13.079
8.17U
3.270
2.7.T5
2.725
2.180
1.635
1.635
1.635
1.362
1.090
0.917
0.817
0.817
0.545
0.545
0.272
0.272
0.272
0.272
0.272
0.272
0.272
0.272
0.272
0.272
0.272
                                      74

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Table 6.2.
SPECIES AND DATA PROCESSING CODE FOR PHYTOPLANKTON USED IN THE
           PRINCIPAL COMPONENT ANALYSIS.
 Code
       Taxon name
                                                  Type
 Used in the
   PCA for
Aug  Sep  Oct
ANINCE
ANTHER
ASFORM
CHDOKI
CNOVAT
CRQUAD
CYCOMT
CYMICH
CYSTEL
CYOCEL
CYOPER
ETSPEQ
GLPLAN
GMLACU
OOSPP
RDMINU
RHERIE
SYFILI
Anaoysti-s -Lnoerta
Anaeystis thermal'is
Asterionel~La foxmosa
ChicysoooQcus dokidophorus
Cryptomonas ovata
Grucigenia quadrata
Cyclotella oomta
Cyolotella miohiganiana
Cyelotella stell-lgeva
Cyolotella ooetlata
Cyclote'Lla apeveulata
Eutetramorus species #1
Gloeoeystis planktoniea
Gomphosphaeria lacustris
Oocystis spp.
Rhodomonas mlnuta v. nannoplanetica
Rh-Lzosolenia eirLensis
Synedra filiformis
Blue-green
Blue-green
Diatom
Chrysophyte
Cryptomonad
Green
Diatom
Diatom
Diatom
Diatom
Diatom
Green
Green
Blue-green
Green
Cryptomonad
Diatom
Diatom
X
X


X
X
X
X
X
X
X
X
X
X
X
X


X
X

X
X

X
X
X
X
X


X
X
X
X
X
x
x
X
X
X

X
X
X
X




X
X
X
X
 of  the  taxa at that station.  Stations with similar phytoplankton compo-
 sitions,  after the previously performed standardization,  will in a
 Euclidean sense be closer to each other in the multidimensional  space than
 stations  dissimilar in composition.  PCA projects the location of each
 station in multidimensional space to a new set of mutually orthogonal axes
 called  principal components.

 Associated with each taxon and principal component is a loading  factor
 which may be interpreted as the cosine of the angle the taxon's  axis makes
 with the  principal component.  The loading factor indicates how  important
 that taxon is in determining the principal component (PC) .  The  first axis
 (the first PC)  is chosen to contain the maximum possible  variance and
 thus will provide the best discrimination between stations of any of the
 PCs.  The second axis (second PC) contains the greatest variance possible
 under the constraint of orthogonality with the first.  The data  set can be
 completely described only by determining all principal components.  If the
 data set  contains more stations than taxa, that number of PCs will be
 equal to  the number of taxa.  However, if the first few PCs contain a.
 large percentage of the variance, they will contain enough information to
 justify ignoring all the rest for the sake of simplicity  of interpretation.
 Since the PCs are chosen to be orthogonal, scores of stations relative to
 the principal components may be used as coordinates in a  plot to show the
 location  of  stations relative to one another.  Relative locations of
                                    75

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 stations on  the plot will roughly approximate relative locations of
 stations in  the multidimensional space.  Stations very dissimilar  in
 composition  may be  identified and, to a somewhat lower degree of certain-
 ty, very similar  stations may be identified also on the basis of proxim-
 ity on  the plot.  If only the first two PCs are retained, PCA reduces
 the multidimensional data set to two dimensions.  More complete descrip-
 tions of the technique are given by Orloci (1966) and Morrison (1967) .

 Additional information about the application of PCA to phytoplankton
 cell densities is found  in the discussion of results from October
 (Sec. 6.4).   Information on the cumulative percent variance, eigenvalue,
 and statistical significance of each principal component derived from
 the analysis of the August, September and October phytoplankton data is
 presented in Table  6.3.
 6.2  TAXONOMIC  COMPOSITION OF THE PHYTOPLANKTON ASSEMBLAGE

 A list of  taxa encountered in this, study is given in Appendix D.  Many of
 the  289  taxa recorded are primarily benthic in habitat preference, and
 their occurrence in plankton collections is probably accidental.  As
 would be expected, numbers of pseudoplankton were greatest at stations
 nearest  shore  although some occurrences were noted in most samples
 examined.  Pseudoplankton was most common in the Detour Passage region
 (Stations  46,  47, 48) where a large number of species apparently were
 derived  from the St. Marys River.  Abundance estimates for most of these
 taxa were  small and subject to large errors, so primary emphasis has been
 given to euplanktonic taxa in the analysis of data.

 Bacillariophyta were the dominant organisms in the taxonomic listing,
 comprising 222 of the 289 species and 34 of the 67 genera (Table 6.4).
 Eight common genera accounted for 160 of the species of diatoms; only 62
 species  occurred in the other 26 genera of diatoms.  Most species that
 were not diatoms were Chlorophyta or green algae.  Only five species of
 blue-green algae were recorded.

 Abundance  of phytoplankton was greatest during the August cruise and
 least during the October cruise, with relatively small variations in
 total counts among stations during each cruise (Fig. 6.1).  In September,
 total counts were smaller at stations in the northeastern sector of the
 sampling area  than those on the most westerly transect and along the
 southern shore.  This difference in abundance was present in October, but
 the  range  in total cell counts was smaller than in September.

The  taxonomic  composition of the phytoplankton also changed during the
study;  the abundance of blue-green and green algae decreased during suc-
cessive sampling periods (Figs. 6.2 and 6.3).  In both cases highest
numbers were found on the August cruise.  Blue-greens and greens were
less abundant  in September when the abundance of greens was very small.
                                    76

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Table 6.3.  RESULTS OF THE PCA OF  5-M PHYTOPLANKTON SAMPLES FOR THE
                    FIRST THREE PRINCIPAL  COMPONENTS.
    August
         Number of samples:  39
         Number of taxa:     14

                                       PCI        PC2        PC3
         Cumulative % variance       29%        43%        55%
         Eigenvalue                   4.0        2.1        1.6
         Significance21                 .002       .025       .084
    September
         Number of samples:  32
         Number of taxa:     14

                                       PCI        PC2        PC3
         Cumulative % variance       34%        48%        60%
         Eigenvalue                   4.8        2.0        1.7
         Significance                  .000       .002       .011
    October
         Number of  samples:   40
         Number of  taxa:      13

Cumulative % variance
Eigenvalue
Significance
PCI
35%
4.5
.000
PC2
50%
2.0
.001
PC3
61%
1.4
.005
aThe significance values result from Bartlett's test of the hypothe-
 sis that the determinant of  the residual matrix is zero (eg.  Cooley
 and Lohnes 1971).
                                  77

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Table 6.4.  PHYTOPLANKTON IN THE STRAITS OF MACKINAC.
Species
Bacillariophyta                         222
Chlorophyta                              44
Chrysophyta                              12
Cryptophyta                               3
Cyanophyta                                5
Pyrrophyta                                3
                           Total        289
Genera
Bacillariophyta                          34
Chlorophyta                              21
Chrysophyta                               4
Cryptophyta                               2
Cyanophyta                                4
Pyrrophyta                                2
                           Total         67
Species of Common Bacillariophyta
Navicula                                 26
Nitzschia                                26
Achnanthes                               23
Fragilaria                               22
Cyclotella                               19
Synedra                                  18
Cymballa                                 16
Stephanodiscus                           10

                           Total        160
                          78

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        TOTBL flLGflL CaLS/HL
    30 BUG - 1 SEPT 1973    -
        TOTfll fiLCH. CELLS/H
    17-19 SEPTEMBER 1973
        TOTflL aCflL CELLS/M.
     6-6 OCTOBER 1973
Figure  6.1.   DISTRIBUTION OF  TOTAL
     ALGAL CELL  COUNTS.
                      79

-------
       BLUE-GREEN RLGRE CELLS/H.
     17-19 SEPTEMBER 1973   *-*•
                                                         GREEN HLGflE CELLS/HL
                                                     30 BUG - 1 SEPT 1973    fl '  '  'ofo
       BLUE-GREEN ALGAE CELLS/HL
      6-8 OaOBER 1973     •,  .  .  >
        GREEN flLCBE CELLS/ML
    17-19 SEPTEMBER 1973
         GREEN FUME CELJLS/ML
      6-6 aTOBtR 1973
Figure  6.2.   DISTRIBUTION  OF BLUE-
     GREEN ALGAE.
Figure  6.3.   DISTRIBUTION OF  GREEN
     ALGAE.
                                               80

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Blue-greens and greens tended to be more abundant at western stations
and those along the southern shore than at other locations.  The abundance
of diatoms (Fig. 6.4) fluctuated much less drastically, and no clear pat-
terns were apparent in their occurrence.
6.3 DISTRIBUTION OF MAJOR SPECIES

Asterionella formosa is apparently an extremely eurytopic diatom, occur-
ring in a wide variety of habitats (Huber-Pestalozzi 1942) and thriving
under most conditions found in the Great Lakes.  According to Hohn (1969)
it is one of the species whose absolute abundance did not change appreci-
ably in Lake Erie between 1938 and 1965.  Scattered populations were
found in our August samples (Fig. 6.5) and no discernible pattern of
occurrence was apparent.  Some increase in average abundance was noted in
September with an apparent tendency for highest population levels to occur
at stations nearest shore.  In October, A. formosa was abundant at most
stations sampled but population levels remained low at offshore stations
in Lake Huron.

Cyclotella comta is a species widely reported from mesotrophic to oligo-
trophic habitats.  It is common in the upper lakes but apparently absent
from Lake Erie (Hohn 1969) and exceedingly rare in Lake Ontario (Stoermer
et al. 1974).  Populations were noted at all stations sampled during
August (Fig. 6.6), with highest abundance being found at stations on the
most easterly transect sampled.  In September, relatively high population
levels were found at Stations 40-45 on the most easterly transect, not
sampled the previous month; but abundance was substantially lower at
stations west of this transect.  Although still present at most stations
sampled during October, C. comta had declined to a relatively minor
element of the assemblage by this time and no marked trends in distribu-
tion were evident.

Cyclotella ocellata appears to be characteristic of relatively undisturbed
habitats in the Great Lakes (Stoermer and Yang 1970).  Only a few isolated
populations were noted in August (Fig. 6.7), but it was quite abundant in
September at some stations in the northeastern sector of the area sampled.
Abundance of C. ocellata was more uniform in October than on the two
previous cruises.  Our evidence suggests that this species maintains
metalimnetic populations during the summer, and population increases in
September and October are at least partially the result of upwelling and
metalimnetic entrainment.

Cyclotella operculata (Fig. 6.8) appears to have similar ecological
affinities to C. ocellata (Stoermer and Yang 1970).  In our samples, it
is consistently less abundant than that species and, partially because of
the low population levels, its distribution pattern is not as clear.  In
all months sampled, highest population levels were found at stations in
the eastern section of the sampling area.
                                    81

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          DIRTOM CELLS/ML
    J7-19 SEPTEMBER 1973
          DIATOM CELLS/ML
     6-6 OCTOBER 1973
Figure  6.4.   DISTRIBUTION OF  DIATOMS,
                      82

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    BSTEHIONELLfl FORMOSfl CELLS/ML
    30 flUG - 1 SEPT 1973
     ftSTERIONEU-fl FORMOSfl CELLS/ML
    17-19 SEPTEMBER 1973   fr •
      CTaOTELLfl COMTO CELLS/ML
    30 flUG - 1 SEPT 1973
     RSTERIONEOfl FORMOSfl CELLS/N.
      6-8 OCTOBER 1973
      CTOOTELLfi CBHTB CH.LS/HL
    17-19 SEPTEMBER 1973     	•
      CTCLOTELLfl COHTfl CELLS/H.
     6-8 OCTOBER 1973
Figure  6.5.   DISTRIBUTION OF
     ASTERIONELLA  FORMOSA.
Figure 6.6.   DISTRIBUTION  OF
     CYCLOTELLA COMTA .
                                                83

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      CYCLOTEtLfl OCELLflTfl CELLS/ML
     30 HUG - 1 SEPT 1973
      CtCLOTELLB OCELLflTfl CELLS/ML
     17-19 SEPTEMBER 1973
      CYCLOTELLR OCELLBTB CELLS/ML
       6-8 XTOBER 1973     t
    CTCLOTELLB OPBRCULBTfl CEUS/HL
    30 BUG - 1 SEPT 1973    j
    CTOOTaUB OPERCULflTfi CELLS/ML
    17-19 SEPTEMBER 1973
    craoraifl OPERCULBTB CELLS/ML     \    •
      B-8 OCTOBER 1973
Figure  6.7.   DISTRIBUTION OF
     CYCLOTELLA OCELLATA.
Figure 6.8.   DISTRIBUTION  OF
     CYCLOTELLA OPERCULATA.
                                                  84

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Cyclotella michiganiana (Fig. 6.9) is very widely distributed in the
phytoplankton of the upper Great Lakes.  Available evidence suggests that
it is tolerant of low levels of eutrophication but is eliminated from
habitats which have been grossly modified (Schelske et al. 1974).  It was
fairly abundant and evenly distributed in August with an apparent trend
toward higher population levels at offshore stations in Lake Huron.  This
pattern was reversed in September; population levels increased at stations
along the southern shore and on the Lake Michigan side of the Straits but
remained static or declined in the northeastern sector.  The trend toward
higher populations in Lake Michigan was accentuated in the results from
the October cruise.

Cyclotella stelligera (Fig. 6.10) is a common component of the offshore
phytoplankton flora of the upper Great Lakes.  Similar to C. michiganiana,
it appears to be favored by low levels of eutrophication and responds
strongly to experimental nutrient enrichment (Schelske and Stoermer 1972;
Schelske et al. 1972).  Apparently, however, it is not tolerant of high
levels of pollution.  Hohn (1969) lists it as one of the species that
decreased markedly in abundance in Lake Erie between 1938 and 1965.  Its
abundance in Saginaw Bay (Schelske et al. 1974) and the nearshore waters
of Lake Michigan is reduced relative to less eutrophic open waters.
During August this species was present in remarkably uniform numbers at
most stations sampled.  There was some tendency for higher values to
occur nearer the northern Lake Huron shore and the lowest values near the
southern shore.  Abundance was greatest in September at all stations
sampled.  By October, abundance decreased at stations in the northeastern
sector of the sampling area, but C. stelligera remained relatively abun-
dant at stations along the southern shore and on the Lake Michigan side
of the Straits.

Fragilaria crotonensis (Fig. 6.11) is one of the eurytopic plankton
dominants which apparently can tolerate the extreme range of environmental
conditions presently found in the Great Lakes.  Similar to Asterionella
formosa, it did not show strong trends in regional or seasonal abundance
during the study.  Interpretation of its distribution is complicated by
large uncertainties in population estimates resulting from patterns of
indeterminate colonial growth.

Synedra filiformis (Fig. 6.12) has not been widely reported from the
Great Lakes, and its distribution and ecological affinities are relatively
poorly known.  It is apparently abundant in the offshore waters of Lake
Michigan (Stoermer and Yang 1970) and during the spring phytoplankton
maximum in Grand Traverse Bay (Stoermer et al. 1972).  Published reports,
however, indicate that it is abundant only at stations near the mouth of
Saginaw Bay in Lake Huron (Schelske et al. 1974).  In the present study,
its distribution was remarkable in that populations were largely restrict-
ed to stations along the southern coast and on the Lake Michigan side of
the Straits.  Small populations were noted in the Detour Passage region
during September and October.  This species was present in low densities,
but showed a general trend towards increased abundance during the period
studied.
                                    85

-------
 r
    CYCLOTEUfi HICHIGRNIfWR CELLS/ML
     30 BUG - I SEPT 1973    Q"  '  ' IJQ
     craoraLo NICHIGRNIM«I CELLS/ML
     17-19 SEPTEMBER 1973
    CTCLOTELLfl MICHIGfiNIflNB CELLS/ML
       6-6 OCTOBER 1973      j—'—^-Jg0
Figure 6.9.   DISTRIBUTION OF
     CYCLOTELLA  MICHIGANIANA.
     CTCL07EU.fi STELLIGQV) CELLS^L
     30 HUG - 1 SEPT  1973
     CTCLOTELLfi STELLIGERfl CELLS/ML
     17-19 SEPTEMBER 1973
     CTCLOTELLfl STELLIGERR CELLS/ML
      6-6 OCTOBER 1973     6"~*~~*~l3o
Figure 6.10.   DISTRIBUTION  OF
     CYCLOTELLA  STELLIGERA.
                                                86

-------
   FfWGILflfUR CRQTONENSIS CELLS/HL
   30 RUG - 1 SEPT 1973
    FROGIUWIfi OttJTONENSIS CELLS/ML
    17-19 SEPTEMBER 1973
    FIWGILPRIfl CROTONENSIS CELLS/ML
      6-8 OCTOBER 1973     ft  ' ' ',^Q
      STNEOm FILIFORMIS CELLS/ML
    30 flUO - 1 SEPT 1973      •  i  i
     STNEORfl FILIFORHIS CELLS/ML
    17-19 SEPTEMBER 1973
     STNEORfl FILIFORMIS CELLS/ML
     6-8 OCTOBER 1973     j—i—'—H-^
Figure  6.11.   DISTRIBUTION  OF
     FRAGILARIA CROTONENSIS.
Figure 6.12.   DISTRIBUTION OF
     SYNEDRA  FILIFORMIS.
                                                87

-------
Rhizosolenia  eriensis  (Fig.  6.13)  is one of  the characteristic  species
of  phytoplankton assemblages in  the upper Great Lakes.   In recent  decades
its abundance has been reduced in  Lake Erie  (Hohn 1969)  and  Lake Ontario
 (Stoermer  et  al. 1974), but  it continues to  be a fairly  important  compo-
nent of  assemblages  in the upper lakes.  The known distribution of R.
eriensis suggests that it is a summer ephemeral, developing  transient
population maxima rapidly in regions where favorable conditions exist.

Only a few scattered occurrences of this species were noted  in  our August
samples.  Population densities increased generally at stations  sampled
during the September cruise,  with  largest increases noted in the north-
eastern  and eastern  segment  of the region sampled.  During the  October
cruise,  population densities remained relatively high with a more  uniform
distribution  than had been observed previously.

The genus  TajbeJlaria is common throughout the Great Lakes system.   A
number of  growth forms are present (Koppen 1975), and at the present time
the precise taxonomic affinities of the populations which occur in the
Straits  of Mackinac  area are uncertain.  In  the present  study we have
adopted  the taxonomic criteria and nomenclature of Hustedt (1930) .  Popu-
lations  identified as T. fenestrata (Fig. 6.14) on this basis were rare
in  samples from the August cruise, and the three occurrences, noted were
at  stations north of Bois Blanc  Island.  Scattered populations  were noted
in  September  samples and there was no readily discernible pattern  of
occurrence.   In October this entity had high levels of abundance at sta-
tions in the  northern sector of  the study area in Lake Huron, and  it was
either present in very low densities or absent in the southeastern sector.

Scattered  populations of Tabellaria fenestrata var. intermedia  (Fig. 6.15)
were found at stations sampled during the August cruise, with no obvious
pattern  of greatest abundance.   During September it was  noted only in
samples  from  the Detour Passage  vicinity and at a few stations  south of
Bois Blanc Island.  A similar pattern of occurrence was  noted in October,
but T. fenestrata var. intermedia  was also present at stations  west of
the Straits where it had not occurred the previous month.

Chrysococcus  (dokidophorus Pasch.?), a species of questionable  taxonomic
status,  had an unusual temporal  and areal distribution.  It  was not noted
during August (Fig. 6.16), but was present in most samples and  locally
abundant in September.  Largest  populations  in September were found in
open-water Lake Huron stations east and northeast of Bois Blanc Island,
but  in October it was relatively abundant at most stations sampled, with
no  obvious trend in its distribution.  This  species has  not  been reported
previously from the Great Lakes  and its ecological affinities are  very
poorly known.

Chrysophaerella longispina (Fig. 6.17) has rarely been reported from the
Great Lakes,  but large populations were found at certain stations  in
Lake Huron during October.   Isolated populations were noted  in  August but
not in September.  Its distribution is unusual in that occurrences were
restricted to stations east  and  north of Bois Blanc and Mackinac Islands.
                                    88

-------
    RHIZOSOLENlfl ERIENSIS CELLS/ML
    30 HUG -  1 SEPT 1973   g—>-
    RHIZOSOLENIR ERIENSIS CELLS/ML
    17-19 SEPTEMBER 1973
    RHIZOSOLENIR ERIENSIS CELLS/HL
      6-8 OCTOBER 1973
Figure 6.13.   DISTRIBUTION OF
     RHIZOSOLENIA ERIENSIS.
                       89

-------
     TflBELLflRlH FENESTRflTfl CELLS/ML
     30. HUG - 1 SEPT  1973
     TflBELLflRIfl FENESTRBTfl CELLS/ML
     17-19 SEPTEMBER 1973
     TOBELLRRIA FENESTRflTH CELLS/ML
      6-6 OCTOBER 1973
           FENESTOflTfl V. INTERMEDIflm.
     30 HUG - 1 SEPT 1973
  TflBELLflRlfl FENESTRflTfl V. INTEHMEOIfVML
     17-19 SEPTEMBER 1973    fl  '
  TfiBELLflRIfi FENESTRfiTfl V. INTEBHEDIIVML
       6-8 OCTOBER 1973
Figure 6.14.    DISTRIBUTION OF
     TABELLARIA  FENESTRATA.
Figure 6.15.   DISTRIBUTION OF
     TABELLARIA FENESTRATA  var.
     INTERMEDIA.
                                                 90

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   CHRYSOCOCCUS DOKIDOPHORUS / MLN
   30 HUG - 1 SEPT 1973    0 '  * 30
    CHRYSOCOCCUS DOKIDOPHORUS / MLN
    17-19 SEPTEMBER 1973   g—«—'-^
     CHRYSOCOCCUS DOKIDOPHORUS / ML\
     6-6 OCTOBER 1973     ^  '  « ^
  CHRTSOSPHREnaU) LONGISPINfl CELLS/ML
    30 HUG - 1 SffT 1973   fl •< » ^
  CHRTSOSPHRERELLB LONGISPINfl CaLS/HL
    17-19 SEPTEMBER 1973   ^  » ' i^
  CHRrSOSPHRERELLfl LONGISPINfl CaLS/ML
      6-8 oaOBER 1973     fr '  ' i^
Figure 6.16.   DISTRIBUTION OF
    CHRYSOCOCCUS  DOKIDOPHORUS.
Figure  6.17.   DISTRIBUTION OF
     CHRYSOSPHAERELLA LONGISPINA.
                                              91

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Rhodomonas minuta var. nannoplanktonica  (Fig. 6.18)  is a  common  element
of phytoplankton assemblages in the Great Lakes.  Its ecological affini-
ties  are relatively poorly known, but it appears to  be tolerant  of
conditions in  the offshore waters of Lake Ontario. (Munawar and Nauwerck
1971)  as well  as the upper lakes.  During August, relatively large  popu-
lations were found at stations north and east of Bois Blanc Island, with
smaller populations noted at many other stations.  In September  this
species was present at most stations sampled; highest populations were
found offshore in Lake Huron, and it was notably rare on  the Lake Michigan
side  of the Straits.  Measurable populations were also found at  most
stations sampled during October, however abundance appeared to be least
at stations in Lake Michigan and along both the northern  and southern
shores.

Cryptomonas ovata (Fig. 6.19) seems to be a ubiquitous member of phyto-
plankton assemblages from all regions of the Great Lakes.  It was present
in nearly all  samples taken during this study and exhibited no pronounced
patterns in either seasonal or areal distribution.

Species of Ankistrodesmus (Fig. 6.20) are common elements of phytoplankton
assemblages in the Great Lakes.  Several species are apparently  present
in all the lakes and some, such as A. falcatus, reach relatively high
population levels in eutrophied areas (Stoermer et al. 1974).  The  iden-^
tity  and ecological affinities of the particular species most abundant
in the study area are unknown.  It was present at most stations  sampled
throughout the study and was particularly abundant along  the southeastern
shore in September and October.

Crucigenia quadrata (Fig. 6.21) is a common minor element of the offshore
phytoplankton  of many areas of the Great Lakes during the summer.   In our
experience, population levels as high as those found in the present study
are unusual.   Populations generally declined during  the three months
sampled, and there was a slight trend toward higher population levels at
stations near  Bois Blanc and Mackinac Islands.

Eutetramorus sp. (Fig. 6.22) was a numerically important member  of  assem-
blages collected in August, when it was quite abundant and very  evenly
distributed over the sampling area.  By September these populations had
disappeared, with only isolated minor populations remaining at stations
in the southwestern sector.  Only a few isolated populations were noted
in the October  samples.  The ecological affinities of this organism are
unknown and it  has not been reported from the Great  Lakes previously.

Gloeocystis planctonica (Fig. 6.23) was present at most stations sampled
in August, and  there was a trend toward higher population levels on the
Lake Michigan  side of the Straits and near Mackinac  and Bois Blanc  Is-
lands.  Abundance of this species was reduced considerably in September
and October.   Our observations indicate that it is a characteristic
member of summer phytoplankton associations in southern Lake Michigan
that develop when diatoms are silica-limited.
                                    92

-------
 RHOOOMONRS HINUTfl V. NBNNOPUWCTICfl/ML
    30 RUG - 1 SEPT 1973    0  '   '
 RHOOOHONflS MINUTfl V.  NfiKHOPLflNCTICfl/ML
    17-19 SEPTEMBER 1973
 RHODOHONRS NINUTB V. NflNNOPUtCTICfl/ML
      6-6 OCTOBER 1973
      CRYPTOMONflS OVHTfl CELLS/ML
    30 flUG - I SEPT 1973       '  <  '
       CflTPTOMONBS OVBTfl
     17-19 SEPTENBER 1973
       CRTPTOMONRS OVPTH CELLS/ML
      6-8 OCTOBER 1973
Figure  6.18-   DISTRIBUTION  OF
     KHODOMONAS MINUTA  var.  NANNO-
     PLANCTICA.
Figure 6.19.    DISTRIBUTION  OF
     CRYPTOMONAS OVATA .

-------
   RNKISTRODESMUS SPECIES *3 CELLS/ML
     17-19 SEPTEMBER 1973
                                                       CRUCIGENIA QUfiOHflTfl CELLS/ML
                                                      30 BUG - 1 SEPT 1973     '  '
     CRUCIGENIH OUflORflTfl CELLS/ML
    17-19 SEPTEMBER 1973   ft • •
   flNKISTPOOESMUS SPECIES «3 CaLS/ML
      6-8 OCTOBER 1973
     CRUCIGENIH QUHORflTR COLS/ML
      6-e ocToeen 1973
Figure  6.20.   DISTRIBUTION OF
     ANKISTRODESMUS species #3.
Figure  6.21.   DISTRIBUTION  OF
     CRUCIGENIA QUADRATA.
                                               94

-------
   EUTEWBHOBUS SPECIES »1 CELLS/Ml
    30 BUG - 1 SEPT 1973    t	•—
    GLOEOCTST1S PtfllCTONICfi CELLS/ML
    30 RUG - 1 SEPT 1973   0  •  •
              SPECIES «i CELLS/HI
    17-19 SEPTEMBER 1973   t
    GLOEOCTSTIS PLflNCTONICfl CEILS/ML
    17-19 SEPTEMBER 1973    '  •  '
    GLOEOCTSTIS PLflNCTONICfl CELLS/ML
      6-8 OCTOBER 1973
    EUTETFttMORUS SPECIES «1 CELLS/HL
      6-8 OCTOBER 1973
Figure  6.22.   DISTRIBUTION  OF
     EUTETRAMORUS  species #1.
Figure  6.23.   DISTRIBUTION  OF
     GLOEOCYSTIS  PLANCTONICA.

-------
 Although  somewhat less abundant  than Gloeocystis, species of Oocystis
 (Fig.  6.24)  had  a similar pattern of distribution.  Measurable popula-
 tions  were  found at all  stations sampled during August, and there was a
 definite  trend toward higher population levels in the southwestern
 sector of the sampling area.  Average population abundance was reduced
 in September, and there  was a weak trend toward higher population levels
 at stations  in Lake Michigan and along the southern shore.  Population
 levels were further reduced in October but the same trend in distribution
 was apparent.  Members of this genus are widely distributed in summer
 phytoplankton assemblages from the upper Great Lakes but, like
 Gloeocystis, it  appears  to be favored when diatoms are silica-limited
 and it has  become more abundant  in southern Lake Michigan in recent years.

 Anabaena  flos-aquae (Fig. 6.25)  is a common minor constituent of summer
 phytoplankton assemblages in the Great Lakes.  It is one of the eurytopic
 species favored  by eutrophication and has the potential for forming nui-
 sance  blooms under nutrient-rich conditions.  Its pattern of indetermi-
 nate colonial growth leads to rather large uncertainties in abundance
 estimates.   Isolated populations were noted in August, and it was most
 consistently present at  stations in the southwestern sector of the
 sampling  area.   Reduced  population levels were noted in September at
 stations  on the  Lake Michigan side of the Straits and along the southern
 shore. A similar situation was  found in October, except several sizable
 populations were also found at offshore stations in Lake Huron.

 Anacystis incerta (Fig.  6.26) is a common element of summer and fall
 phytoplankton assemblages throughout the Great Lakes.  It is usually not
 abundant  in the  upper lakes but has the potential for forming nuisance
 blooms because of its large colonies and the presence of gas vacuoles in
 the cells (Drouet and Daily 1956).  It was the most abundant member of
 assemblages collected in August and tended to be especially abundant at
 stations  in the  southwestern sector of the sampling area.  In September
 it remained  abundant at  stations on the Lake Michigan side of the Straits
 and along the southern shore, but only relatively minor populations were
 found  in  the rest of the area sampled.  In October small populations
 were restricted  to stations on the Lake Michigan side of the Straits and
 along  the southern shore.

 Anacystis thermalis (Fig. 6.27), like the previous species, is a common
 element of  summer phytoplankton assemblages in the Great Lakes.  It does
 not, however, have the potential to produce nuisance blooms since the
 colonies  are small and the cells lack gas vacuoles.  Our observations
 indicate  that it also has a different ecologic range than A. incerta.
 It  apparently is favored by low levels of eutrophication and has become
much more abundant in southern Lake Michigan in recent years.  It appar-
 ently  cannot tolerate gross perturbation.  Anacystis thermalis is either
present in very low numbers or absent from areas such as Saginaw Bay and
western Lake Erie and is much less abundant than A. incerta in Lake
Ontario (Stoermer et al. 1974).  It was present at all stations during
August and tended to be most abundant in the southwestern sector of the
                                    96

-------
       OOCTSTIS SPP. CELLS/ML
    30 HUG - 1 SEPT 1973   ft  •   • ^
     flNflBflENfl FLOS-flQUHE CELLS/ML
    30 MJG - 1 SEPT 1973   g-
     RNflBflENfl FIOS-flQUflE CELLS/ML
    17-19 SEPTEHBEfl 1973      • «
        OOCTSTIS SPP. CELLS/ML
    17-19 SEPTEMBER 1973    g—'—•-fa
     WRBflENR aOS-BQUBE CELLS/ML
     6-8 OCTOBER 1973
        OOCTSTIS SPP. CELLS/ML
      6-8 OCTOBER 1973
Figure  6.24-   DISTRIBUTION  OF
     OOCYSTIS  SPP.
Figure 6.25.   DISTRIBUTION OF
     ANABAENA  FLOS-AQUAE.
                                               97

-------
      HNRCtSTIS INCERTfl CELLS/ML
    30 flUG - 1 SEPT 1973
      flNRCTSTIS INCERTB CELLS/ML
     17-J9 SEPTEMBER 1973   g—•—Hg^
      flNflCTSTIS INCERTfl CELLS/ML
      6-8 OCTOBER 1973
                                                    7
     flNflCTSTIS THERMflLIS CELLS/ML
    30 HUG - 1 SEPT 1973    Q  '  * 300
     flNflCTSTIS THERMBUIS CaLS/ML
    17-19 SEPTEMBER 1973    ^  •  •  3fo
     flNflCTSTIS THERMflLIS CatS/HL
      6-8 OCTOBER 1973
Figure 6.26.   DISTRIBUTION OF
     ANACYSTIS  INCERTA.
Figure 6.27.    DISTRIBUTION OF
     ANACYSTIS  THERMALIS.
                                                98

-------
sampling area.  In September, population levels were low at offshore
stations in Lake Huron but remained abundant on the Lake Michigan side of
the Straits and along the southern shore.  In October, population levels
comparable to those found previously occurred only at stations on the
Lake Michigan side of the Straits, and only relatively small populations
were found in Lake  Huron with greatest abundance along the southern
shore.

Gomphosphaeria lacustris (Fig. 6.28) is a common element of phytoplankton
communities in the Great Lakes.  It is apparently eurytopic and tolerates
the range of conditions between Lake Superior and Lake Ontario.  Its
abundance is reduced in grossly perturbed areas such as the inner reaches
of Saginaw Bay.  It was most abundant in August but no obvious trends in
distribution were apparent.  In September it was most abundant on the
Lake Michigan side of the Straits and along the southern shore.  Some
indication of the same distribution pattern as September was evident in
October although occurrences were more scattered with smaller ranges in
populations.

Scattered populations of Oscillatoria bornetii (Fig. 6.29) were noted in
the samples from all three cruises.  This species tended to increase in
abundance, especially in October, but no strong trends in areal distri-
bution were apparent.
6.4 ORDINATION ANALYSIS OF PHYTOPLANKTON ASSEMBLAGES

Data on ordination analysis of phytoplankton are presented in the reverse
order of collection, as the October cruise comprises the most complete
data set.  In October all 50 stations were sampled, whereas Stations
38-50 were not sampled in August and Stations 32-37 were not sampled in
September.


Wear-surface Associations in October

The ordination analysis of October samples revealed an east-west or
Lake Huron-Lake Michigan axis for the first principal component (PC).
Stations in region Ax found on the extreme right end of the first PC
were generally located west of the Straits, and stations in regions B,
BC, and C on the opposite end of the first PC were located generally
northeast of the Straits (Fig. 6.30a).  Region A2 was composed of sta-
tions located between the two extremes.  Since the first PC removes the
greatest variance from the data, it may be concluded that the greatest
difference in surface phytoplankton communities was between the communi-
ties found in Lake Michigan and those found east of the Straits.

A plot (Fig. 6.30b) of the 13 taxa used in the principal component
analysis (PCA) relative to the loading factors of the first two PCs il-
lustrates the composition of the communities for various regions
                                   99

-------
    GOHPHOSPHfiERIft LflCUSTFUS CELLS/HL
     30 BUG - 1 SEPT 1973   ^  '   ' tgbo
    GOMPHOSPHflERIR LflCUSTRlS CEULS/HL
     17-19 SEPTEMBER 1973    ^  •   • ^
                                                       OSCILLBTOR1B BORNETII CELLS/HL
                                                   OSCILLfiTORIR BORNETII CELLS^IL
                                                   17-19 SEPTEMBER 1973
                                                       OSCILLflTORIR BOmETII CELLS/HL
                                                        6-8 OCTOBER 1973      ., .  . .  .
GOMPHOSPHREftlfi LfiCUSTRIS CELLS/ML
   6-6 OCTOBER 1973
Figure 6.28.   DISTRIBUTION  OF
     GOMPHOSPHAERIA  LACUSTRIS.
                                              Figure 6.29.   DISTRIBUTION  OF
                                                   OSCILLATORIA BORNETII.
                                              100

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(a)
                                                                                   (WEB1E-*

                                                                                   CTCOHIJ
                                                         (b)
Figure 6.30.  OCTOBER 5-M SAMPLE ORDINATION PLOTS.  The first principal component is represented  on  the
    horizontal axis and the second on the vertical axis.  The cross indicates the location of  the ori-
    gin.  The exact location of the station or taxon is at the lower left-hand corner of its label.

    (a) Station ordination plot.  Stations are located relative to the first two principal component
    scores.  See Figure 2.1 or Figure 6.31 for station locations.

    (b) Phytoplankton taxa ordination.  Taxa are located relative to the loading factors of the first
    two principal components.  See Table 6.2 for the taxa abbreviations.  The small letters following
    the taxon abbreviation indicates the division:  diatom, chrysophyte, j»reen, b_lue-j»reen, cryptomonad.

-------
 depicted  in Figure 6.31.  A station with relatively high densities of
 taxa  located on  the right side of Figure 6.30b will be located on the
 right side of Figure 6.30a, or any station with relatively low densities
 of  these  taxa on the right side of Figure 6.30b will be situated on the
 left  side of Figure 6.30a.  Similarly, any station with high densities
 of  species at the top of Figure 6.30b will appear toward the top of
 Figure 6.30a, but if it has low densities of these taxa it will appear
 toward the bottom of Figure 6.30a.  The cluster labeled "Z" (Fig. 6.30b)
 defines a community of four species with similar patterns of distribution
 corresponding to region C (Fig. 6.31).  These species tend to be abundant
 in  the same places, and where these species are abundant the taxa of
 community X and  community Y (Fig. 6.30b) are relatively rare.  Conversely,
 where the taxa of community X are abundant, those of Z and Y are rare.
 Likewise  stations of region AI would tend to have high concentrations of
 the taxa of community X.

 Two species, Rhizosolenia eriensis and Cyclotella comta, have relatively
 small loading factors for both the first and second component, i.e.,
 they  appear close to the origin (Fig. 6.30b).  These species apparently
 show  no clear distribution patterns relative to the others or occur in
 equally high abundances in more than one of the regions Aj , B and C.  It
 might also be expected that, although Chrysococcus dokidophorus appears
 to  belong to community Z, its relatively high loading factor for PCj
 indicates that it may also be found in region Aj as well as in region C.
 Community Y is represented by only one species, Asterionella forwosa and
 it  would be found primarily in region B.

 Regions containing characteristic phytoplankton communities as identified
 on  the basis of  the ordination plots (Fig. 6.30a) have been plotted in
 Figure 6.31.  This map suggests a close geographical proximity between
 stations with similar phytoplankton communities.  The similarity between
 Figures 6.31 and 4.2 suggests that the grouping is determined primarily
 by  water currents.

 Hypolimnetic Associations in October

 A PCA was performed for all samples collected in October, including the
 5-m as well as a small number of hypolimnetic samples (Fig. 6.32a).
 Regions Aj, A2,  EI and C are based on the results of the PCA for the 5-m
 samples as shown in Figure 6.30a; relative positions of these regions
 have been changed little by including hypolimnetic samples in the analy-
 sis.   A new group of stations, region D (Fig. 6.32a) corresponds to
 hypolimnetic samples collected east and north of Bois Blanc Island in
Lake Huron.  Associated with region D is a phytoplankton assemblage, W,
 consisting of Cyclotella ocellata and Rhizosolenia eriensis.  This hypo-
limnetic association can be distinguished from assemblage Z found in the
 surface water which is characterized by Rhodomonas winuta v.
nannoplanctica,  Cryptomonas ovata and Chrysococcus dokidophorus.
                                   102

-------
                     -84°45'-
                                           -84°30'
                                                                 84°I5'-
                                                                                      -84-OCT-
Figure 6.31.  GEOGRAPHIC LOCATIONS  OF  5-M OCTOBER PHYTOPLANKTON COMMUNITIES.  Regions  are deter-
    mined on the basis of  the  ordination plot of Figure 6.30.  Phytoplankton data  are  not avail-
    able for stations not  included  in  one of the four regions.

-------
(a)
                                                                               CYCOMT
Figure 6.32.  ORDINATION PLOTS FOR OCTOBER SURFACE AND SUBSURFACE SAMPLES.

    (a) Station ordination plot.  The number preceding the hyphen refers to the station,  and the number
    following the hyphen refers to the depth in meters at which the sample  was taken.   Unhyphenated num-
    bers refer to samples collected at 5 m.  Samples are located relative to the first two  principal
    components.

    (b) Phytoplankton taxa ordination.  Taxa are located relative to their  loading factors.  The first
    principal component is represented on the horizontal axis and the second on the vertical axis.   See
    caption for Figure 6.30a and b for further explanation.

-------
The assemblages in surface and hypolimnetic samples from stations in
Lake Michigan were similar.  Subsurface samples taken at Stations 03 and
15 appeared to have the same phytoplankton community as the 5-m samples
(Fig. 6.32a).

Total cell densities are highest at the surface and lowest in the hypo-
limnion, but diatom densities are highest below the thermocline at
Station 29 (Table 6.5).  Diatoms constitute 15% of the assemblage at 0 m
for Station 29 but 93% of the assemblage below the thermocline at 50 m.

Results of the ordination analyses are qualitative and may be considered
ambiguous; the differences, however, between standing crops of different
species of phytoplankton in each region also can be evaluated from the
average standing crops.  It can be seen that the six species identified
as community X in region Aj (Fig. 6.32b) by ordination analysis are those
that were more abundant in region X than in the other regions (Table 6.6).
Cyclotella ocellata and Rhizosolenia eriensis, the hypolimnetic assem-
blage W, from Lake Huron had the greatest cell densities in region D
(Table 6.6).

Stations with unusual or extreme communities on the basis of the ordina-
tion plot are 06, 42 and 31 (Fig. 6.30a).  Station 06, located NW of the
Straits, had near-surface cell densities for Cyclotella stelligera,
C. michiganiana, and Synedra filiformis that were at least three times
more abundant than at any other station (Table 6.6).  It also had
extremely high densities of Fragilaria crotonensis, a species not used
in the PCA, and Rhizosolenia eriensis.  Station 06 had the highest near-
surface cell densities for total algae, total blue-greens, and total
diatoms of all stations sampled in October.  Station 42, SE of the
Straits, had the highest 5-m cell density for Cyclotella operculata but
also had extremely high densities of Cryptomonas ovata, Chrysococcus
dokidophorusf Rhodomonas minuta var. nannoplanctica and Cyclotella
stelligera.  Station 31, located in the northcentral part of the survey
area, had the highest 5-m density of all stations for Asterionella
forwosa and high density of Fragilaria crotonensis but also, by contrast,
had extremely low concentrations for a number of species including
Chrysococcus dokidophorus, Cyclotella stelligera, Rhodomonas minuta var.
nannoplanctica, Anacystis incerta, and Anacystis thermal is.


Near-surface Associations in September

The ordination plots for September (Fig. 6.33) were analyzed from a
smaller set of samples and are therefore more difficult to interpret than
those for October (Figs. 6.30 and 6.32).  Plots for September do not show
the well segregated clusters found in October.  Station 39 had a particu-
larly unusual phytoplankton assemblage which included very high densities
of Anacystis incerta, A. thermal is, Cyclotella michiganiana, characteris-
tic of region Aj (Fig. 6.33a), and Rhodomonas minuta var.  nannoplanctica,
and Chrysococcus dokidophorus which were more abundant in the northeastern
corner of the survey area.  Inclusion of Station 39 with region A2 is
therefore somewhat arbitrary.
                                   105

-------
Table 6.5.  CELL DENSITIES AT STATION 29 ABOVE,  IN,  AND  BELOW  THE THERMOCLINE FOR THE AUGUST, SEPTEMBER AND OCTOBER CRUISES.
Letters "E," "T" and "H" refer to epilimnion,  thernocllne,  and hypolinmion.  Under "apparent trend" Is indicated  the regions  in
which a taxon attains highest densities.   Under  "dep"  is indicated  the depth which, at Station 29, the taxon appears to  be
concentrated.  This determination is made subjectively on the  basis of  the cell densities at  Station  29.   Under "epi" is the
surface region where the taxon is most abundant  as  indicated on Tables 6.6, 6.7 and 6.8.  For each taxon,  cell  densities (in
cells/ml) are given above the standard error of  the mean, which is  determined on the basis of a replicate  cell  count of  the
sample.
August

Anacystis incerta

Anacystis thermal is

Synedra filiformis

Cyclotella michiganiana


Cyclotella stelligera

Oocystis spp.

Gloeocystis planctonica

Cruc-igenia guadrata

Cyclotella comta

Chrysococcus dokidophorus

Kh-izosolenia eriensis

Eutetraoorus species #1

Anabaena flos-aquae

Fragilaria crotonensis

Tabellaria fenestrata

Cyclotella operculata

Asterionella foroasa

Cryptononas ovata

Chrysosphaerella longispina

Rhodomonas minuta v.
nannoplanctica
Cyclotella ocellata

Total cells/ml
Total blue-green cells/ml
% blue-green
Total green cells/ml
% green
Total diatoms/ml
% diatoms
Temperature (°C)
Conductivity (umho/cn)
E
Om
1697
691
0

0

65
6
607
398
23
19
80
34
40
23
92
92
23
11
0

0

260
38
354
138
136
2
6
6
0

0

0

0

2
2
0

3424
2656
78
499
15
264
8
21.5
226
Sample depth
ETH
5m
3288
649
111
52
2
2
52
11
880
335
31
2
55

78
2
0

50
13
0

6
6
335
21
262
262
6
6
0

6
2
0

11
2
0

23
2
4
4
5408
4616
85
519
10
205
4
21.0
228
20m
147
147
0

0

69
2
607
189
73
6
21
8
38
21
0

82
19
0

19
6
34
34
0

293
75
4
4
8
4
0

0

0

8
4
82
6
1539
754
49
96
6
679
44
9.0
202
50m
105
105
0

19
2
17
8
0
0
44
15
0

0

0

13
4
0

0

0

0

0

4

4

0

0

0

0
27
11
300
105
35
0
0
195
65
4.5
218
Apparent
trend E
dep epi Om
E A 712

E A 67

H I 4
4
E BC 21
13
E C? 335
335
T C 130
4
E A 15
2
E A 0

? A 0

IB 13

1 1 17
4
T ? 0

E A 0

E A? 0

1 C 159
113
? ? 0

? B 0

? C 0

E ? 4

? ? 0

E BC 19
6
T C 124
36
1711
1114
65
23
1
532
31
10.6
216
September
Sample depth
ETH
5m
838
545
63
4
0

50
21
147
147
128
27
65
6
36
36
0

27
2
27
11
4

0

0

90
69
13
8
0

0

8
4
0

13
4
115
10
1690
1047
62
111
7
482
29
10.6
216
20m
168
168
34
34
0

61
19
0
128
2
13
4
8
8
0

61
6
6
2
19
15
19
2
0

82
82
2
2
0

0

6
2
0

8
8
245
44
1273
545
43
48
4
658
52
8.0
207
50m
314
63
0

6
2
2
2
0
140
2
13
13
17

0

21

0

52
6
0

0

191
48
2
2
0

0

2
2
0

2
2
352
38
1357
404
30
107
8
840
62
5.8
214
Apparent Sample
trend E E
dep epi Om
E A 0

E A 272
272
? ? 0

ET A 4

E A 0
ETH AB? 23
6
E A 13
13
? A 25
25
? ? 0

T C 2
2
E ? 8
4
H C 0

T A 0

? ? 0

? ? 48
19
11 2
2
1 C 2
2
? A 0

? ? 6
2
? ? 484
182
E ? 17
H C 61
15
984
272
28
48
5
149
15
10.6
216
5m
21
21
0

0

8
4
168
168
23
2
4

0

0

8
4
21
4
2
2
0

46
46
124
40
0

2
2
29
29
15
2
375
358
25
17
88
21
1066
331
31
6
.6
293
28
10.6
216
October
depth
T H
20m
105
63
8

0

15
2
0
17
4
6
6
25
25
0

2
2
15
2
4
4
0

0

147
96
6
6
2
2
57
31
8
8
0

4
4
124
44
771
251
33
52
7
400
52
6.0
71?
50m
21
21
0

4

11
6
0
36
15
0

0

0

13
4
4

13
13
0

0

191
191
4

2
2
0

6
6
0

2
2
157
27
522
21
4
0
0
486
93
4.6
719
Apparent
trend
dep epi
T A

1 A

? A

TH A

? A
ETH A

? A

? A

? A?

H AC

E AC

H ?

7 ,

? ?

? ?

? ?

? ?

T B

E C

E C?

E C
H C






                                                           106

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Table 6.6.  OCTOBER PHYTOPLANKTON CELL DENSITIES.   Average densities (in cells/ml) for each
region (Figs. 6.30a and 6.31) are given over the standard error of  the mean.  Standard errors are
omitted when values used in the average are identical.   Columns titled "apparent trend" indicate
regions of maximum and minimum abundance.  Taxa are grouped according to apparent trend.  Taxa
most abundant in region AI are listed first, those showing no pattern relative to the regions are
listed second, and those taxa most abundant in regions B or C are listed last.  Taxa identified
with an (*) were used in the PCA.
Region label and Number of stations ADDarent trpnri

Anacystis incerta*

Anacystis tbermalis*

Synedra filiformis*

Cyclotella michiganiana*

Gomphosphaeria lacustris

Cyclotella stelligera*

Oocystis spp.*

Gloeocystis planctonica

Crucigenia quadrata

Cyclotella comta*

Chrysococcus dokidophorus*

Rhizosolenia eriensis*

Eutetramorus species #1

Anabaena flos-aquae

Fragilaria crotonensis

Tabellaria fenestrata

Cyclotella operculata

Asterionella formosa*

Cryptoinonas ovata*

Chryaosphaerella longispina

Rhodomonas minuta v. nannoplanctica*

Cyclotella ocellata*
AI
5
1114
88
126
13
24
11
95
14
394
82
85
21
21
6
12
8
19
12
11
2
17
2
10
4
3
3
37
23
103
74
8
3
2.1
.9
28
4
5.4
.5
0

5
2
43
7
A?.
10
494
107
30
6
10
2
48
7
276
51
58
5
16
2
5
3
23
8
11
2
16
2
8
2
6
3
16
8
49
18
3.8
.8
1.7
.8
27
5
5
1
34
24
5
2
47
6
B
10
31
31
8
3
.8
.6
12
3
134
38
24
6
5
1
.8
.8
0

6
1
8
1
6
2
0

21
18
168
49
6
2
3
1
41
7
5.4
.7
100
48
11
2
38
5
BC
10
170
63
16
4
.6
.3
12
2
300
78
25
4
7
2
.6
.6
16
16
5
1
16
1
8
2
7
3
11
9
67
15
6
2
1.5
.9
28
7
5.9
.8
67
38
18
4
75
7
C
5
256
110
18
9
2
2
14
2
67
34
54
21
5
2
2
2
0

12
2
21
3
7
2
3
3
62
52
65
19
4
4
5
3
21
6
10
2
245
150
33
7
121
16
D
8 High Low
20 A B,D
15
27 A B
20
9 A B,C
2
14 A
1
168 A C
89
42 A B
7
10 A
3
16 A B
15
4 A?
4
10 A,C,D
1
5.5 A,C B,D
.8
17 D
4
5
3
0 D

86
22
9
3
1.6
.5
18 B
7
4 C
1
0 C? A,D

3 D A.D
1
142 C,D
19
                                              107

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o
oo
      (a)
                                                             (b)

     Figure 6.33.   SEPTEMBER 5-M WATER SAMPLE ORDINATION PLOTS.  See Figures 6.30a and 6.31 for further dis-
         cussion.   Station locations are  given on Figure 6.34.  Communities shown are chosen with the help of
         Table 6.5.

         (a) Station ordination plot.

         (b) Phytoplankton ordination plot.

-------
Comparison of the phytoplankton distribution  in  September  (Fig. 6.34)
with that of October shows that the general orientation and locations of
regions A, B, and C were similar in the  two months.  The species composi-
tion of community X for September  (Fig.  6.33b) is similar  to community X
in October; both are characteristic of region AX and A2 (Lake Michigan
water) and have several species in common:  Anacystis incerta,
A. thermalis, Cyclotella michiganiana, Oocystis  spp., and  Gomphosphaeria
lacustris (Tables 6-6 and 6.7).

Community Z for September, consisting of two  diatoms, Cyclotella comta
and C. operculata, is quite different from community Z for October which
includes a diatom, chrysophyte, and two  cryptomonads.  These Z communities
are found in region C which is located in approximately the same area for
the two cruises.  Community Y in September consists of Cyclotella ocellata
and Rhizosolenia eriensis, which corresponds  with the hypolimnetic
community W of October.


Hypolimnetic Associations in September

Ordination plots for stations and  taxa of all 5-m samples  plus some
selected hypolimnetic samples show an overlap of samples in regions B
and D  (Fig. 6.35).  Community Y, consisting of Cyclotella  ocellata and
Rhizosolenia eriensis, is found in both  regions, indicating that upwelled
water  is present at the surface in region B.  In this deep water region
(Table 6.7), C. ocellata and R. eriensis attain extremely  high densities
and are the only taxa more abundant below the thermocline  than above it.

Near-surface Associations in August

In August, region Aj in Lake Michigan combined with region A2 has a phyto-
plankton assemblage, X, that is similar  to that found in September and
October except that it contains no diatoms (Fig. 6.36).  Two blue-green
algal  taxa (Anacystis incerta and  A. thermalis) and four green algal taxa
(Gloeocystis planctonica, Crucigenia guadrata, Oocystis spp- and a
Eutetramorus species) dominate the assemblage.

A second region, C, consists of a  single station (25) which has a unique
community for this cruise.  The densities of  Anacystis incerta and
A. thermalis were the lowest at this station at 5 m, while  densities of
two diatoms, Cyclotella operculata and C. comta, were highest (Table 6.8).
The community includes Phodomonas  minuta var. nannoplanctica, a species
found  in the Lake Huron community  of October, and Cyclotella michiganiana,
found  in the Lake Michigan community for September and October.

Region B is located along the northern coast  of  the survey area (Fig. 6.37)
and is characterized by a community, Y,  of two diatoms:  Cyclotella
ocellata and C. stelligera (Fig. 6.36).
                                    109

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Figure 6.34.  GEOGRAPHIC LOCATIONS OF 5-M SEPTEMBER PHYTOPLANKTON COMMUNITIES.  Regions are de-
    termined on the basis of the ordination plot  of Figure 6.33a.  Phytoplankton data are not
    available for stations not included in one  of the  four regions.

-------
Table 6.7.   SEPTEMBER PHYTOPLANKTON CELL DENSITIES.  Averages (cells/ml) are given over  standard error of the mean.
Format same as Table 6.6.  Region D Is discussed under "Hypolimnetic associations In September."  Last 3 columns
show average densities for epilimnion of northern Lake Michigan (NLM) Stations 52-54 (11 samples). epillmnion of
Stations 20-23 (16 samples), and hypolimnion of Stations 20-23 (14 samples).  Stations were  sampled on 20-23 Sept.
1973, immediately after sampling of the Straits survey area.  See Figure 8.1 for NLM station locations.  The
epilimnion is taken to be represented by samples above 20 m and the hypolimnion by those below 30 m.

Gomphosphaeria lacustris*

Anacystis incerta*

Anacystis thermalis*

Oocystis spp . *

Cyclotella michiganiana*

Gloeocystis planctonica

Eutetraoorus species #1

Asteripnella fornosa

Crucigenia guadrata

Cyclotella stelligera*

Fragilaria crotonensis

Tabellaria fenestrata

Synedra filifornds*

Anabaena flos-aquae

Chrysococcus dokidophorus*

Cryptooonas ovata*

Chrysosphaerella longispina
Rhodomonas minuta v. nannoplanctica*

Cyclotella comta*

Cyclotella operculata*

Khizosolenia eriensis*

Cyclotella ocellata*
Region
1
933
99
2951
196
197
23
52
8
73
6
44
9
16
4
24
7
19
9
113
9
84
26
6
2
2.8
.9
37
20
7
2
7
1
0
20
7
27
3
.9
.5
2.1
.8
20
4
label and number of
10
279
34
1629
155
98
16
24
6
55
3
32
9
7
3
9
5
34
12
97
8
81
20
5
2
6
3
10
7
12
3
6
1
0
17
4
24
1
2.3
.7
5
1
58
10
B
7
30
19
200
86
8
6
5
2
15
2
10
4
4
3
14
5
12
7
102
19
61
19
3
1
4
1
0

8
3
6
2
0
17
6
14
3
4
1
11
3
108
24
C
6
231
102
681
238
46
16
31
5
31
5
13
11
9
4
6
4
14
10
75
10
89
22
5
2
2
1
62
58
7
1
6
2
0
27
8
57
6
10
2
14
4
141
38
stations Apparent
D High
4
0 A

84 A
77
5 A
4
7 A
3
10 A
4
4 A
4
0 A

7 A
4
0

92 A,B?
16
73
43
4
2
3
1
0

.5
.5
.5
.5
0
2.6
.5
19 C
3
0 C

26 D,C,B
9
317 D,C,B
84
trend NLM NLM NLM
Low 52-54 20-23 20-23
epi epi hypo
B,D

B,D 2712 2093 49
222 213 22
B,D 218 227 12
28 18 5
B,D

B,D 54 8.5 2.4
4 1.5 .7
D

B,D

C,D 27 2.2 3.9
7 1.5 1.1
D

C? 87 29 26
854
55 10 3.7
14 6 1.2











D

B,D 19 3.4 1.5
3 .9 .5
A,D 1.1 0 0
.4


15 1.2 15
2 .61
                                                         111

-------
(a)
                                                                                      RDMINU
                                                                                     CHOOKI

                                                                                       CNOVflT
                                                                                     CYSTEL
                                                          (b)
                                                                                STFILI
Figure 6.35.   ORDINATION PLOTS FOR SEPTEMBER SURFACE AND SUBSURFACE SAMPLES.   See caption for Figure  6.32
    for further  information.

    (a) Station  ordination plot.

    (b) Phytoplankton ordination plot.

-------
(a)
(b)
Figure 6.36.  AUGUST 5-M WATER SAMPLE ORDINATION PLOTS.
    Station locations are given on Figure 6.37.

    (a) Station ordination plot.

    (b) Phytoplankton ordination plot.
   See Figures 6.30 and 6.37 for further discussion.

-------
Table 6.8.   AUGUST PHYTOPLANKTON  CELL DENSITIES.  Average densities (in cells/ml) for each region
(Figs. 6.36 and 6.37)  are given over the  standard error of the mean.  Format is the same as for Table
phytoplankton counts from the 5-m sample at that station. Region D is discussed under "Hypolimnetic
associations in August." Standard errors for region C are based on two replicate counts on one slide.
Taxa identified with an (*) were used in the PCA.
Reuion label and Number


Anacystis incerta*

Anacystis thermalis*

Crucigenia quadrata*

Gloeocystis Dlanctonica*

Oocystis spp.*

Eutetramorus species #1*

Anabaena flos-aquae

Synedra fj.lifortnis

Chrysococcus dokidophorus

Tabellaria fenestrata

Cryptomonas ovata*

Rhizosolenia eriensis

ChrysosphaereJ la longispina

Cyclotella operculata*

Cyclotella comta*

Cyclotella michiganiana*

Rhodomonas minuta v.
nannoplanctica *

Fragilaria crotonensis

Cyclotella stelligera*

Cvclotella ocellata*

Asterionella formosa

AI
5
4348
448
208
25
80
22
165'
29
98
5
308
32
46
38
0

0

0

7
2
0

0

3
1
19
2
20
3
7
1
C7 /
J/ 4
225
87
42
25
4
3
1
3
3
A2
19
3171
231
150
13
55
15
99
17
75
6
204
14
32
17
1.0
.5
0

0

8
1
.8
.4
9
9
3.3
.8
28
2
32
2
3
1
501
79
54
13
28
2
2.5
.5
2
1
BC
11
2363
184
109
13
29
11
70
9
50
3
192
22
38
24
1.0
.4
0

3
2
7
2
1.1
.7
10
10
6.3
.9
46
4
54
4
14
6
535
114
82
18
31
4
3.0
.7
7
4
C
1
2032
453
68
15
17
9
50
25
61
17
230
9
0

0

0

0

11
3
3
1
45
45
6
1
64
9
52
8
10
5
817
84
194
32
83
17
17
6
13
3
of stations
B
3
607
398
29
29
0

90
6
38
13
145
b
0

0

0

0

8
4
0

0

27
6
101
4
61
6
14
2
440
440
90
6
34
8
0

0

DI
3
35
35
0

0

0

3
3
0

0

10
5


13
6
2
1
17
8
0

1
1
17
3
17
2
3
2
28
28
22
22
78
17
48
14
2
2
D2
4
1079
360
54
41
8
8
53
9
25
2
92
30
23
23
4
2
7 .5
7 .5
9
4
7
3
6
4
0

6
2
50
12
47
16
8
2
508
123
163
52
53
9
39
15
8
6
Apparent trend

High Low
A C,D

A C,D

A C,D

A D

A D

A D

A?

D?



D?



D?



C

C A,D

B,C

B,C

B D
B

B,D A

B,D

B

                                               114

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                     - 84-45'-
                                           - 84°30'
Figure 6.37.  GEOGRAPHIC LOCATIONS OF 5-M AUGUST PHYTOPLANKTON COMMUNITIES.   Regions are deter-
    mined on the basis of the ordination plot of Figure  6.36.   Stations  east of a line from
    Station 24 to Station 31 were not sampled.

-------
Hypolimnetic Associations in August

Including  seven deep  samples with the 5-m samples in the PCA analysis
gave an orientation similar to that for the 5-m samples  (Fig. 6.38).  The
deep samples added to  the analysis are in regions D} and D2, which  show
closest proximity to  region B and some samples in region BC.  This  is
evidence that the community in region B is related to the hypolimnetic
community  and that region B is upwelled, but also suggests  that some
additional stations (11R, 37, 34, 30 and 35) might be upwelled.  These
additional stations are located north and east of Bois Blanc Island near
region B (Fig. 6.37).

The hypolimnetic community found at Stations 27, 29 and 35  is character-
ized by two species of Cyclotella, C. ocellata and C. stelligera
(Fig. 6.38).  These two taxa also constitute community Z, identified as
the community at region B from the 5-m samples (Fig. 6.36).  These con-
clusions that C. ocellata and C. stelligera are favored in region B and
in the hypolimnion is  supported by the absolute abundance of these
species (Table 6.8).

Region D2,  intermediate between region DI and the surface sample regions
(Fig. 6.38), consists  of subsurface samples at stations located for the
most part  in the southwestern side of the survey area.  For example, the
5-m sample at Station  03 (in the western side of Lake Michigan) belongs
with region A\, which  contains community X (green and blue-green algae).
The 25-m sample at the same station, on the basis of Figure 6.38a appears
to have a  community intermediate between community X at 5 m and communi-
ty Z of the hypolimnion of the northwestern section.  This implies that
deep-water samples do  not all have the same phytoplankton community.  The
hypolimnion in the northeastern part of the survey area has a phytoplankton
community  consisting mainly of Cyclotella ocellata and C. stelligera
(Table 6.8, Figs. 6.38a and b).  The hypolimnion of the southwestern side
(identified as having  Lake Michigan water at its surface) has a communi-
ty somewhat intermediate between those of surface Lake Michigan and the
hypolimnion of the more northern stations.  One possible explanation is
that deep  westward currents are carrying the C. ocellata and C. stelligera
(and any other deep-water taxa east of the Straits) into the hypolimnion
of Lake Michigan.
6.5 COMPARISON OF TEMPERATURE-CONDUCTIVITY AND PHYTOPLANKTON COMMUNITY
    PATTERNS

If certain phytoplankton communities are associated with specific water
masses, then individual taxa in these water masses should be diluted with
the mixing of water masses.  It should, therefore, be possible  to deter-
mine how much of the distribution pattern of a given taxa is due to
dilution of water masses and how much is due to other factors.
                                   116

-------
                                                                                  CNOVfCMlflCU
                                                       (b)
Figure 6.38.  ORDINATION PLOTS FOR AUGUST  SURFACE AND SUBSURFACE SAMPLES.
    for further information.

    (a) Station ordination  plot.

    (b) Phytoplankton ordination plot.
See caption for Figure  6.32

-------
 If a parameter  follows water movement and is conservative,  then  its
 value at any  surface point x should follow the same rules set  forth  above
 for temperature and conductivity  (Sec. IV).  If V  (x)  is the value of
 this conservative parameter at x  then


                V  (x) =   £ V± F, (x)
                       1-1

 where 7^ (x)  is, as before, the fraction of water  at x originating from
 JL and V.^ is the value of the parameter at source _i.  It is  shown in
 Appendix E that in a system consisting of three water  sources  it is  pos-
 sible to express any conservative parameter as a linear combination  of
 any other two conservative parameters (but only if neither  of  these  two
 has equal values at all  sources and only if they are linearly  independent).
 It then follows that:

                The value of the conserved parameter V(x) at
                surface point x in the Straits survey area
                is expressible as a linear combination  of
                temperature, T(x), and conductivity, C(x),
                at that point.

 If the density  of a phytoplankton taxon is conservative (that  is, if it
 can be viewed as a passive tracer of water masses  and  does  not grow, die,
 sink or get eaten), then it should be possible to obtain a  large value
 of R2 from a linear regression of the plankton's density against temper-
 ature and conductivity.  (It should be understood  that this regression
 is not meant  to predict  phytoplankton density from temperature and
 conductivity in the usual sense, but rather to examine the  relationship
 of phytoplankton density with water dilution.)  The value of R2  is
 interpretable as the fraction of variance removed by the regression.
 Consequently, the larger R2 is, the better the dilution model  explains
 the distribution of the  plankton.  Conversely, a low value  of  R2 suggests
 that water-mass dilution is not the major factor determining the density
 estimates of  the plankton in the  surface samples.

 Measurement errors also  contribute to the unexplained  fraction of the
 variance.  Since the number of colonies of any one species  observed  on a
 slide did not exceed 50  and was usually very much  less than this (Tables
 6.9, 6.10), it  is apparent that statistical variability in  species counts
 will be an important contributor to the unexplained variance.  Water-mass
 dilution accounts for 21 to 74% of the observed densities for  the most
 abundant taxa, whereas it can account for less than 10% for the  least
 abundant ones.  These results indicate that the values of R2 are at  least
partly dependent on counting error, i.e., that the largest values for R2
are associated with the most abundant species.

 It is possible  to estimate the contribution to the statistical variability
due to the counting procedure.  The regression model for R2 may  be written
                                    118

-------
Table 6.9.  VALUES OF R2 AND RELATED  STATISTICS FROM REGRESSIONS OF CELL
DENSITIES AGAINST TEMPERATURE AND CONDUCTIVITY FOR THE MOST ABUNDANT TAXA.
 Taxon name
 Estimated maximum
 number of colonies
observed on a slide
R2   R2
                                                     est
                                                            R2
                                                            est
Standard error
of the angle
    (SD)
Anacystis incerta
Anacystis therraalis
Synedra filiformis
Cyclotella michiganiana
Cyclotella stelligera
Cyclotella comta
Chrysococcus dokidophorus
Rfcodomonas minuta v.
nannoplanctica
Cyclotella ocellata
8
n
22
42
29
14
14
16
35
.521
.543
.307
.743
.344
.206
.210
.354
.515
.628
.718
.867
.895
.803
.484
.265
.703
.729
.83
.76
.35
.83
.43
.43
.79
.50
.71
10.3°
10.1
16.7
6.6
13.8
20.7
15.0
14.2
8.3
Table 6.10.   VALUES OF R2  FROM REGRESSIONS  OF CELL DENSITIES AGAINST TEM-
              PERATURE AND  CONDUCTIVITY FOR  LESS ABUNDANT TAXA.
 Taxon name
       Estimated maximum
       number of colonies
       observed on a slide
                    Standard error
                    of  the angle
                        (SD)
P.stsrionalla formosa
Oocystis spp.
Gloeocgstis planctonj.es
Ar.a'oaeria flos-aquae
Rhizosolenia eriensis
Sutetramorus species //I
Cyclotella operculata
Ctyptornonas ovata
Chrysosphaerel la longi spina
Fragllaria crotonensis
Tabellaria fenestrata
Crueigrenia quadrata
Gomphasphaeria lacustrJ.s
6
7
2
3
7
2
5
6
5
5
3
4
4
.126
.326
.241
.013
.020
.059
.148
.099
.092
.056
.085
.062
.111
20.2°
15.9
19.5
68.8
55.2
30.9
20.5
31.3
34.3
34.8
26.4
43.3
31.4
                                       119

-------
as:
                 2 =  SST-SSE
                       SST
                                    N
where SST = total sum of squares =  Z
                                   1=1


                                    N          9
      SSE = total sum of squares =  Z   (y^-y^)
                                   1=1

        N = number of samples  (or stations or  slides)

       yi = measured value of  dependent variable  (number of colonies)
            for  sample 1^

       y^ = predicted value of the dependent variable based on  the
            regression
                                                    N
        y = average number of  colonies per slide =  Z  y.j
                                                   1=1
                                                      N

Since we have verified that the colonies are distributed randomly on the
slides, it may be assumed that colony counts follow a Poisson distribu-
tion.  Let Ai be the Poisson parameter for the colony counts made of the
species in question over a fixed area A of slide i_.  (Ai may be thought
of as the average number of colonies counted in a very large number of
non-overlapping  scans each covering an area A of this slide.)  From the
properties of the Poisson distribution, Ai equals the variance and the
mean.  Each slide count is a sample of size one from a Poisson distribu-
tion with parameter Ai, and thus Ai may be estimated as either:

               Ai = y±

or

               Ai = MSB = (3

Consequently:
                      N
               SSE =  Z  (y_.
                     1=1   3

                      N
                   =  Z  Ai
                     1=1

                      N
                   ~  V  "\7
                   -  L  yi
                     1=1
                                   120

-------
This permits an estimate for R2 which is based on the number of colonies
counted on a slide:

                2    _ SST-SSEes<-
                 est ~   SST

                        N
where         SSEest =  I,  yi
                       i=l

The R2est can be calculated before the regression is performed and pro-
vides a means of evaluating the R2 resulting from the regression analysis.
If R2 nearly equals R2est» it ™ay be concluded that the fraction of the
variance not explained by the regression can be accounted for mainly by
counting error.

The ratio of R2/R2est may be interpreted as the fraction of the variance
of cell density accounted for by dilution.  The unexplained fraction
includes contributions due to sample preparation (believed to be much
smaller than the contribution due to counting, which was considered above
and is included in R2est) and other factors including patchiness, growth,
death, sinking, and predation.  Very large fractions (over 70%) of the
variance of the densities for Anacystis incerta, Anacystis thermalis,
Cyclotella michiganiana, Chrysococcus dokidophorus, and Cyclotella
ocellata are apparently explained by water mixing, whereas other taxa have
between 35% and 50% of the variance explained by dilution (Table 6.9).
The species with the lowest fraction explainable by dilution is Synedra
filifornds.  The unaccounted fraction is almost entirely the result of
the extremely high density at Station 06.  For the other taxa, the dif-
ference between R2 and R2est is not explained as simply.

An examination of the residuals of the regression might help identify
additional factors determining cell density.  If, for example, the resid-
uals (residual is defined as the value predicted on the basis of the
regression minus the measured value: [y^-y^]) for a species most abundant
in Lake Michigan increase toward the southeast, then this species is
probably sinking or being preyed upon faster than it is reproducing as
water moves from Lake Michigan to Lake Huron.  Another explanation might
be that cell densities at the source are increasing but that net produc-
tion is not equal to the rate of dilution with Lake Huron or St. Marys
River water.  Examination of residuals of these species (Table 6.9),
however, do not show any simple patterns.  Instead, the factors affecting
the residuals appear for the most part to be local and erratic.  For
example, the extremely high cell density of Synedra filiformis at
Station 06 is inconsistent with the dilution patterns as defined by^tem-
perature and conductivity.  Cyclotella stelligera attains high densities
at Stations 04 and 05 as well as at 06.  The densities of C. stelligera
between Stations 02 and 06 are not consistent with dilution patterns.  The
very high density at Station 42 is also highly inconsistent with dilution
patterns.
                                   121

-------
The general conclusion to be drawn from the analysis of phytoplankton
densities relative to the water-mass dilution is that, for most  species,
simple dilution seems to be a very important factor determining  distribu-
tion patterns and that for some it may be the only significant factor.
Most phytoplankton species therefore appear to be semi-conservative  in
the sense that at least half of the density variance is explainable  by
water dilution.

The regressions of plankton densities vs. temperature and conductivity
can also be used to indicate diagrammatically where the plankton are
found (Fig. 6.39).  Multiple linear regression with two independent  vari-
ables is usually viewed as a technique of finding the least squares  plane
passing through points in three-dimensional space.  It can also  be viewed,
however, as a two-dimensional problem.  The regression of cell density D
on temperature and conductivity determines statistical parameters a, 3
and y for the regression model
               D± = 3T± + yCi + a + ei
where          D-^ = density at station i^
               T£ = temperature at station i^
               C^ = conductivity at station i^
               e^ = error

such that  the canonical variable (3T + yC + a) maximally correlates with
D.  In this sense it is very similar to canonical correlation.  If the
regression coefficients 3 and y are normalized:
                        3                   Y
               g' = /gz + Yz  and  y' = /3Z + yz

then g' and y' may be interpreted as direction cosine for the axis of
the canonical variable (3T + yC + a) in the T-C plane.

It is also possible to estimate the angular error associated with the
direction  of each arrow.  Using a Taylor expansion, it is possible to
show that  (derivation is omitted) :

               SD2 = Var[arctan(y/x) ] &

   (n-3)2  [xy(Varx-Vary)+(y2-x2)Covxy]2 + (n-3) (y2Varx-xyCovxy+x2Vary)

              n(n-l) (x2+y2) *                     (n-1) (x2+y2) 2

Here,  y is the regression coefficient associated with conductivity and x
is the regression coefficient associated with temperature.  Simulations
to test the accuracy of this approximation show that, for n > 30, it is
accurate to about 2% for SD in the range 2° to 10° and accurate to about
15% for SD in the range 50° to 70°.  The approximation shows a tendency
to underestimate that is especially noticeable when SD is greater than
                                   122

-------
  260
   240
  220
   200
H
>
P
O
3
   160
   160
   140
   120
       LAKE
      HURON
A Oocystlj app.

B Gloeocystls plonetonlca

C Anabatna floe-aquae

D Rhizoeolenia erlensfe

E Euletramorus species rt I
P Cyclotella operculata

8 Cryptomonas ovota

H Chrysosphaerella longlsplno

I  Frogilorio crotonenais
J Tabellaria fenestrata
K Crucigenla  quadrota

L Qomphoephoeria lacustris
                                                                \
                                                                     ST. MARYS
                                                                      RIVER
                   H
                                 12             13

                                  TEMPERATURE °C
                                                             14
Figure 6.39.   PHYTOPLANKTON  TRENDS ON THE T-C  PLANE.  Numbers refer  to  sta-
    tions  and are plotted in the T-C  plane.  Only 5-m samples are considered,
    and only stations for which phytoplankton  data exist  are shown.   Each
    arrow  shows the direction in the  T-C plane in which the corresponding
    phytoplankton taxon tends to be most abundant; length  of arrow indicates
    strength of tendency.  Directions for arrows are taken from multiple
    linear regressions of cell density against temperature and conductivity;
    length of arrow represents value  of R2 for that regression.  Arcs at ar-
    row tips  represent standard error of the angle as estimated from the
    variance-covariance matrix of the regression coefficients.  Dashed  line
    indicates value of R2est-
                                        123

-------
30°.  As might be expected, SD increases as R2 and the number of colonies
counted decreases (Tables 6.9, 6.10).  The values of SD shown are,  for
the most part, relatively small and indicate that the directions on the
arrows shown in Figure 6.39 are reasonably accurate..

The plot in Figure 6.39 may be seen as an ordination of stations and
phytoplankton, but of a different nature than the ones shown in
Figure 6.30 where each station and phytoplankton taxon is ordinated rela-
tive  to the phytoplankton community.  In Figure 6.39 the relationships
of both stations and phytoplankton are shown relative to water-mass dilu-
tion  as revealed by temperature and conductivity.  Figure 6.30 displays
results of a single multivariate ordination; the use of the term
"multivariate" means that the ordination examines community relationships.
In Figure 6.39, the results of univariate analyses for temperature and
specific conductance and 22 phytoplankton taxa are shown.  If Figure 6.39
is rotated 45° clockwise relative to Figure 6.30, rather striking simi-
larities are revealed between station locations as well as taxa locations.
This  again supports the conclusion that the distribution of communities
illustrated in Figure 6.31 is due mainly to the dilution of the individual
taxa  found in the communities of Lake Michigan, Lake Huron and the
St. Marys River.

The direction of an arrow in Figure 6.39 indicates direction of highest
occurrences, and the length of the arrow the strength of the trend.  The
arrow for Cyclotella wichiganiana, for example, points in the direction
of the Lake Michigan stations.  It therefore appears to show a tendency
toward high densities in Lake Michigan and low densities in Lake Huron
and the St. Marys River.  The length of the arrow or the R2 indicates
that  this tendency is very strong.  Arrows for Anacystis incerta and
A. thermalis are shifted more toward the Lake Huron stations than the
arrow for C. michiganiana.  It would be concluded that these species,
though most abundant in Lake Michigan, are more abundant at Lake Huron
stations than at stations of the St. Marys River.  The arrow of
Cyclotella stelligera points almost straight up.  It is abundant both at
Lake  Huron and Lake Michigan stations but relatively rare at the
St. Marys River.  Cyclotella ocellata is most abundant toward Lake Huron
stations, whereas Rhodomonas minuta var. nannoplanctica, though very
abundant at Lake Huron stations, is more abundant at St. Marys River than
in Lake Michigan since its arrow points generally toward Lake Huron
stations but also somewhat toward St. Marys River stations and away from
Lake  Michigan stations.  Only three species, Asterionella fornosa,
Tabellaria fenestrata, and Fragilaria crotonensis, appear to be most
abundant at the St. Marys River—all have relatively small values of R2.

It is apparent that most arrows in Figure 6.39 tend to be oriented  toward
Lake Michigan, Lake Huron or the St. Marys River, implying that most of
the 22 taxa are abundant in only one of the three water types.  Few taxa
appear to be equally abundant in two water types simultaneously.  A taxon
occurring equally at all three water types would have a nondirected
arrow—that is one of very short length.
                                   124

-------
The actual cell densities of Cyclotella ndchiganiana, C. ocellata, and
C. stelligera at stations in the survey area are shown in Figures'e.40,
6.41 and 6.42, and can be compared with the results shown in Figure 6.39.
Cyclotella michiganiana is most abundant at Lake Michigan stations and
becomes less abundant as Lake Michigan water dilutes with Lake Huron or
St. Marys River water (Fig. 6.40).  Highest densities of C. ocellata are
toward Lake Huron and lower densities toward Lake Michigan and the
St. Marys River (Fig. 6.41).  These conclusions are consistent with the
results shown in Figure 6.39 and Table 6.2.

As suggested by Figure 6.39, C. stelligera appears to be most abundant
in Lakes Michigan and Huron, although it is also found at the St. Marys
River.  Its densities, however, are low at stations in the center of
Figure 6.42, being higher at the sources than at stations where the
waters from these sources mix.  This pattern is quite inconsistent with
the dilution model which results in the large difference between R2 and
R2est given in Table 6.9, and was not evident in the distribution of any
other taxa, although it is possible that counting the algae samples more
fully would uncover such patterns for other phytoplankton.  One possible
cause for the odd distribution of C. stelligera would be the occurrence
of very rapidly developing blooms simultaneously at each of the sources
(but not in the mixed water) immediately before or during the time the
samples were collected.


Distribution of Chemical-Physical Parameters at 5 m During October

Regressions of several physical-chemical parameters and rates of phyto-
plankton carbon fixation vs. temperature and specific conductance were
calculated for the data from 5 m in October.  Results are listed in
Table 6.11 and plotted in Figure 6.43.

The R2 for chloride is nearly 1.0, indicating chloride behaves as a
conservative parameter (Table 6.11).  Since the arrow for chloride is
parallel to the conductivity axis, it appears that conductivity and
chloride analyses measure the same thing in these samples or are, at
least, redundant.  That the R2 value is not 1.0 may be explained by
measurement errors.  Since the arrow for chloride points away from the
vertex for the St. Marys River, chloride values are very low there rela-
tive to the other sources.  Chloride is higher in Lake Michigan than in
Lake Huron, since the arrow points more nearly in the direction of the
Lake Michigan source.

Alkalinity, surprisingly, based on the R2 from the regression, acts as
a nearly conserved property (Table 6.11).  The changes induced by the
biota through photosynthesis and respiration may be too slow relative to
the transit time of the water through the survey area to affect the
results attributed to dilution.  Alkalinity is very large in Lake Michigan
compared to values in the St. Marys River, which also may account for the
apparent conservative behavior.
                                   125

-------
        260r
        320
        200
                                                       •rs"®/
                                             /"V-" \_A_J V-X'ii'h/ml/
                                      LAKE MICHIGAN

                                        ?
                                            o
             LAK£ HURON--
              JiK£ HUF
                    O
         CD
O
                                   O
X o
                                ©
                               o
         120
                              sO
                                        \
                                          \
                                             \
                                                  o
                                                \
               CYCLOTELLR MICHIGRNIflNfl CELLS/HL
                                                    X  I
                                                         ST. MARYS
                                                          RIVER
                               12          13

                               TEMPERATURE *C
      Figure 6.40.  CELL DENSITIES FOR CYCLOTELLA MICHIGANIANA ON
          THE T-C PLANE FOR OCTOBER.  Each 5-m sample is located on
          the T-C plane.  At the location of the sample in this
          plane, a circle is drawn which has an area proportional  to
          the cell density.  These plots may be used to help inter-
          pret Figure 6.39.  Use Figure 6.39 as a key to determine
          with which station a circle corresponds.
The pH data  are  not,  strictly speaking,  conserved mainly due to strong
buffering capacity of the  Great Lakes and to the fact that pH relation-
ships are not linear, i.e.,  pH is not conserved because it does not follow
the definition of  equation 1 of Section IV.  Nonetheless, pH shows a
surprisingly high  value  of R2.  Its distribution is virtually identical
with that of alkalinity  but  is less nearly conservative.

Sulfate is generally  considered to be a conservative parameter.  Its
relatively low value  of  R2 may be explained by the analytical technique
which, at the time of this project, was still being developed at this
laboratory (Santiago  et  al.  1975).  Sulfate concentrations are largest in
Lake Michigan.

Nitrate nitrogen has  a surprisingly high R2 for a nutrient required by
phytoplankton.   Since it is  not limiting in the upper Great Lakes
                                    126

-------
         260 r
         240
         220
         200
         180
         140 -
         120-
                                                           -"
                                                    -oo "6     /
                CYCLOTELLR OCELLHTfi CELLS/ML
                                12          13

                                TEMPERATURE °C
       Figure 6.41.  CELL DENSITIES FOR CYCLOTELLA  OCELLATA.   See
           caption for Figure "6.40.
 (Schelske 1975)  and is found in relatively high concentrations, apparently
 it  is changed  slowly by the biota and acts like a nearly conservative
 parameter.  Nitrate was highest at the St. Marys River and very low in
 Lake Michigan.

 Rates of carbon  fixation,  soluble reactive silica and total phosphorus
 were not conservative,  as  expected and shown by the relatively low R2
 (Table 6.11).  Carbon fixation was about equal in Lake Huron and the
 St. Marys River  but was larger in Lake Michigan.  Silica is limiting for
 diatoms in the Great Lakes (Schelske 1975), and its small value for R2
 indicates silica concentration was not conservative.  Silica concentra-
 tions were much  larger  in  the St. Marys River than in Lake Michigan or
 Lake Huron.  R2  for total  phosphorus and soluble phosphorus was very low,
 indicating that  dilution was not a large factor relative to explaining
 concentrations in the study area.

The relatively large variance in total phosphorus results (Table 3.1)
suggests that analytical or sampling methods are not precise.  The vari-
ance is large not only  relative to the mean but also to the range of
                                   127

-------
         260
         340
         220
       o  ISO
         160
                                                  -GOO-'87
                                                   V_A_X x—' a
                                                             LAKC MICHIMH
                           IJ6 I
                           cells/ml'
                                           o
                  ^  o
GD°
  o

                                       Oo|
                                    \
                                         O
                                        \
                                                  O
                                                \
                                                 \
               CYCLOTELLfl STELLIGERfl CELLS/ML
                                                         T. MARYS
                                                         RIVER
                               12          13

                               TEMPERATURE °C
       Figure 6.42.   CELL DENSITIES FOR CYCLOTELLA STELLIGERA.  See
           caption for Figure 6.40.
averages for different groups of stations.  If it were not  for  the  prob-
lem of variable results with phosphorus, one would have  to  conclude that
biological and other environmental processes, not dilution,  control the
concentrations of silica and phosphorus.  Nitrate is probably an excep-
tion due to the fact that it is not limiting, that the soluble  component
is measured (instead of the particulate and soluble in the  case of  total
phosphorus) and that the concentration difference is large  between  Lake
Michigan and the St. Marys River.

Although the Secchi depth transparency is not conserved  (i.e. does  not
obey eq. 1 of Sec. IV), its reciprocal, which may be associated with
extinction coefficient (e.g. Ladewski and Stoermer 1973), can be taken
as an estimate of suspended particulate material, which  may in  turn be
conserved if biological activity and sinking can be neglected.   The
reciprocal Secchi depth is highest at the St. Marys River where the water
is quite turbid, due probably to inorganic materials, and lowest in Lake
Huron where the water is relatively clear.  The  moderate value  of R2
suggests that particulate loading might be semi-conservative if measured
with a more accurate instrument.
                                   128

-------
   260
   240
   220-
 o  200-
 •x
 o
   180-
U

§
8  '60-
   140-
   120
                                                                      LAKE
                                                                      MICHIGAN
                                                           / ST. MARYS
                                                           u  RIVER
                             12            13



                              TEMPERATURE  °C
Figure  6.43.   TRENDS OF PHYSICAL AND CHEMICAL PARAMETERS IN  THE T-C

    PLANE.  Concept and format  same as  Figure 6.39.
                                     129

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      Table 6.11.  VALUES OF R2 AND SD FROM REGRESSIONS OF PHYSICAL-
        CHEMICAL PARAMETERS AGAINST TEMPERATURE AND CONDUCTIVITY.

Parameter
Cl
Alkalinity
PH
SO^
Carbon fixation
Total soluble POi,
Total P04
Secchi""*
Si02
NO 3
R2
.933
.868
.609
.433
.247
.135
.179
.494
.363
.836
Standard deviation
(SD) of the angle
in degrees
2.3
3.7
7.5
11.8
19-3
24.4
15.4
6.3
8.9
4.8
 6.6  LITERATURE CITED

 Cooley, W.  W. and  P. R. Lohnes.  1971.  Multivariate data analysis.
      New York: John Wiley & Sons, Inc.  364 p.

 Dobson, H.  F. H.,  M. Gilbertson and P. G. Sly.  1974.  A summary and
      comparison of nutrients and related water quality in Lakes Erie,
      Ontario, Huron, and Superior.  J. Fish. Res. Board Canada 31:
      731-738.

 Drouet, F.  and W.  A. Daily.  1956.  Revision of the Coccoid Myxophyceae.
      Butler Univ.  Botanical Studies, Vol. 12.  218 p.

Hohn, M. H.  1969.  Qualitative and quantitative analyses of plankton
      diatoms, Bass Island area, Lake Erie, 1938-1965, including synoptic
      surveys of 1960-1963.  Ohio Biol. Survey, N.S., Vol. 3, No  1
      211 p.

Huber-Pestalozzi, G.  1942.  Das Phytoplankton des Susswassers.  Die
     Binnengewasser 16, Teil 2, 2.  Halfte, Diatomeen.  Stuttgart.  549 p.
                                   130

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Hustedt, F.(  1930.  Bacillariophyta  (Diatomeae).  m A. Pascher (ed.)
     Die Susswasser-Flora Mitteleuropas.  Heft  10.  Jena: Gustav Fischer
     Verlag.  466 p.

Hutchinson, G. E.  1967.  A treatise on limnology.  II.  Introduction to
     lake biology and the limnop lank ton.  New York: Wiley.  1115 p.

Koppen, J. D.  1975.  A morphological and taxonomic consideration of
     Tabellaria (Bacillariophyceae)  from the northcentral United States
     J. Phycol. 11: 236-244.

Ladewski, T. B. and E. F. Stoermer.  1973.  Water transparency in southern
     Lake Michigan in 1971 and 1972.  Proc. 16th Conf. Great Lakes Res.:
     791-807, Internat. Assoc. Great Lakes Res.

Morrison, D.  1967.  Multivariate statistical methods.  New York: McGraw-
     Hill.  338 p.

Munawar, M. and A. Nauwerck.  1971.  The composition and horizontal
     distribution of phytoplankton in Lake Ontario during the year 1970.
     Proc. 14th Conf. Great Lakes Res.: 69-78,  Internat. Assoc. Great
     Lakes Res.

Orloci, L.  1966.  Geometric models in ecology.  I.  The theory and appli-
     cation of some ordination methods.  J. Ecol. 54: 193-215.

Santiago, M. A., Saundra Fielek and C. L. Schelske.  1975.  Automated
     method for sulfate determination in lake water.  Water Quality
     Parameters, ASTM STP 573: 35-46.  Amer. Soc. for Testing and
     Materials.

Schelske, C. L.  1975.  Silica and nitrate depletion as related to rate
     of eutrophication in Lakes Michigan, Huron and Superior, p. 277-298.
     In A. D. Hasler (ed.), Coupling of land and water systems.  New York:
     Springer-Verlag New York Inc.

	, L. E. Feldt, M. A. Santiago and E. F. Stoermer.  1972.
     Nutrient enrichment and its effect on phytoplankton production and
     species composition in Lake Superior.  Proc. 15th Conf. Great Lakes
     Res.: 149-165, Internat. Assoc. Great Lakes Res.

	, 	, M. S. Simmons and 	.  1974.  Storm
     induced relationships among chemical conditions and phytoplankton in
     Saginaw Bay and western Lake Huron.  Proc. 17th Conf. Great Lakes
     Res.: 78-91, Internat. Assoc. Great Lakes Res.

	and J. C. Roth.  1973.  Limnological survey of Lakes Michigan,
     Superior, Huron and Erie.  Univ. Mich.,  Great Lakes Res. Div.
     Pub. 17.  108 p.
                                    131

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	 and E. F. Stoermer.  1971.  Eutrophication, silica depletion
     and predicted changes in algal quality in Lake Michigan.
     Science 173: 423-424.

	 and 	.  1972.  Phosphorus, silica and eutrophication
     of Lake Michigan, p. 157-171.  In G. E. Likens (ed.), Nutrients and
     eutrophication.  Amer. Soc. Limnol. Oceanogr., Spec. Symp.  1.

Stoermer, E. F.  1972.  Statement, p. 217-254.  In Conf.  Pollution of
     Lake Michigan and its tributary basin, Illinois, Indiana, Michigan,
     and Wisconsin - 4th session, Sept. 19-21, 1972,  Chicago, 111.  U.S.
     Environmental Protection Agency.  Vol. I.

	, M. M. Bowman, J. C. Kingston and A. L. Schaedel.   1974.
     Phytoplankton composition and abundance during IFYGL.  Univ.  Mich.,
     Great Lakes Res. Div., Spec. Rep. No. 53.  373 p.

	, C. L. Schelske, M. A. Santiago and L.  E.  Feldt.   1972.
     Spring phytoplankton abundance and productivity in Grand Traverse
     Bay, Lake Michigan, 1970.  Proc. 15th Conf. Great Lakes  Res.:
     181-191, Internat. Assoc. Great Lakes Res.

	 and J. J. Yang.  1969.  Plankton diatom assemblages in  Lake
     Michigan.  Univ. Mich., Great Lakes Res.  Div.,  Spec.  Rep.  47.
     268 p.

	 and 	.   1970.  Distribution and  relative  abundance
     of dominant plankton diatoms in Lake Michigan.   Univ. Mich., Great
     Lakes Res. Div. Pub. 16.  64 p.

Strong, A. E., H. G. Stumpf, J. L. Hart and J.  A.  Pritchard.  1974.
     Extensive summer upwelling on Lake Michigan during 1973  observed by
     NOAA-2 and ERTS-1 satellites.  Proc. 9th  Internat. Symp. Remote
     Sensing of Environment, 15-19 April 1974.   Environmental Res.  Inst.
     of Mich., Ann Arbor, p. 923-932.

Vollenweider, R. A., M. Munawar and P.  Stadelmann.  1974.   A  comparative
     review of phytoplankton and primary production  in the Laurentian
     Great Lakes.  J. Fish. Res. Board  Canada  31:  739-762.
                                   132

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                                SECTION VII

          CRUSTACEAN ZOOPLANKTON  OF THE STRAITS  OF MACKINAC AND
                          NORTHERN LAKE MICHIGAN
                                     by

       John E. Gannon, Kathryn  S.  Bricker  and  Theodore B. Ladewski


7.1 INTRODUCTION

Zooplankton samples were  first  procured from the Laurentian Great Lakes
nearly 100 years ago.  However, due to the difficulty and high cost of
sampling such large water bodies,  our  knowledge  of zooplankton ecology
in the Great Lakes has accrued  slowly.   Relatively few studies have been
conducted, and knowledge  of  zooplankton has barely advanced beyond de-
scriptive ecology (Gannon 1969) .   Our  current  understanding of zooplankton
species composition, abundance, and distribution in  the open waters of
the Great Lakes is fairly complete and has recently  been reviewed by
Davis (1966), Patalas (1972), and  Watson and Carpenter (1974).  However,
many ecologically and economically strategic regions such as embayments,
inshore areas, and interconnecting waterways remain  to be investigated.
One of these important areas is the Straits of Mackinac, the zone of
water exchange between Lakes Michigan  and  Huron.

As part of a physicochemical and biological investigation of this limno-
logically dynamic region, we studied crustacean  zooplankton in the
Straits of Mackinac during 1973.   Since this was  the first investigation
of zooplankton in tliis region,  our primary objective was to provide
benchmark data on species composition,  distribution, and abundance.  Our
second objective was to analyze zooplankton community structure in rela-
tion to the interactions  of Lake Michigan  and  Lake Huron waters.  A
third objective was to provide  information on  crustacean zooplankton in
northern Lake Michigan, as most prior  zooplankton investigations in Lake
Michigan have focused only on the  southern third of  the lake (Gannon
1974a).  These data are included primarily to  contrast and compare zoo-
plankton community structure between northern  Lake Michigan and the
Straits of Mackinac.
7.2 METHODS AND MATERIALS

Field

Samples were obtained with a 0.5-m diameter cylinder-cone net towed


                                   133

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 vertically  from  near bottom to  the  surface  at  approximately 0.5 m/sec.
 The net material consisted  of nylon monofilament  screen  cloth  of 250 p
 mesh  apertures with a  porosity  of 44%.   This mesh size closely corre-
 sponds to the No.  6 mesh  (239 y) of the  old silk  bolting cloth rating
 system (Welch 1948).   Since  the net was  2 m long,  vertical  tows were from
 2  m off bottom to the  surface.  Extra care  was  taken  to  insure that  the
 cod end of  the net hit bottom before beginning  the vertical  ascent.
 Single samples were procured at most stations.  However,  several stations
 were  sampled  twice during a  cruise  in order to  investigate variations in
 species composition and abundance over a short  time span.

 The tow net was  fitted with  a Nansen throttling mechanism and  split  tows
 were  obtained at deep  stations  where a distinct thermocline  was present.
 Two vertical  tows, one from  the bottom to the  top  of  the hypolimnion and
 the other from the bottom of the thermocline to the surface, were made
 at approximately one-third of the stations  during  each cruise.   The
 Nansen closing net was employed primarily to reduce effects  of  net clog-
 ging  during long vertical tows.

 Another plankton tow from near  bottom to the surface was  made  at each
 station using a  0.5-m  diameter  No.  20 (76 y mesh size) conical  net.  This
 net was employed to qualitatively collect smaller  plankters  such as  roti-
 fers.  These  samples have not been  analyzed to  date.

 In order to aid  in the interpretation of zooplankton data in the Straits
 region, samples  were also taken in northern Lake Michigan at 18  stations
 during 20-23  September 1973  (Fig. 7.1).  Vertical  tows from near bottom
 to the surface were obtained with both the  No.  6 and No.   20 mesh nets.

 Upon  completion  of each vertical haul, the  net was washed thoroughly and
 the contents  of  the cod end bucket were  carefully  transferred  to an  8-oz
 screw cap jar.   Carbonated water (club soda) was immediately added as a
 narcotizing agent  (Gannon and Gannon 1975).  After approximately 5 min,
 most  locomotor activity had  ceased, and  the sample was preserved in  5%
 buffered formalin.

 The mesh size used in  any study should be sufficiently small to  capture
 the desired organisms  but large enough to avoid clogging by phytoplankton.
 The mesh size of  250 p was chosen for its good  filtration characteristics
 and to catch  all adult crustacean zooplankters.  Net filtration efficiency
 tests were  not conducted in  the Straits  region.  However, such  tests were
made using  flowmeters  in the offshore waters of Lake Michigan where  fil-
 tration efficiency ranged from  86.7-99.7% (Gannon  1972a).  In  order  to
 test the efficiency of the net  to capture crustacean zooplankton, compari-
sons of the catch of the net and a  7-liter  capacity transparent Van  Dorn
bottle were made at a  station in Lake Huron near the mouth of  Saginaw Bay
on 15 August 1974.  Quantitative analyses of these samples revealed  that
numbers of  the smallest zooplankters (Chydorus  sphaericus, Bosmina
longirostris, Eubosmina coregoni, Ceriodaphnia  lacustris, C. guadrangula,
Tropocyclops prasinus  mexicanus, and cyclopoid  copepodids) were relatively
lower in the net tow than in the water bottle.  Consequently,  these
species appear to be somewhat under-sampled by  the No. 6 mesh  net.
                                   134

-------
                                                       STRAITS OF
                                                      L MACKINAC
                                        BEAVER   0
                                        ISLAND
                                               X 2T X 20
                                                       AREA
                                                      ^ENLARGED
                              46  X
                       -aX v   X  47
                       28 45
                                          NORTHERN LAKE
                                               MICHIGAN
                                               Ml.
                                         0   10 20  30  40 50
        Figure 7.1.  LOCATION OF ZOOPLANKTON SAMPLING STATIONS
            IN NORTHERN LAKE MICHIGAN, SEPTEMBER 1973.
A test was conducted  on 25  July 1974 at a 27-m deep station  in  the
Straits of Mackinac to  compare the efficiency of the Nansen  closing net
in capturing crustacean zooplankton.  A vertical tow was  made from near
bottom to surface and then  two tows, one in the hypolimnion  and  the
other in the thermocline and epilimnion, were conducted using the Nansen
closing mechanism.  Numbers of Crustacea were somewhat higher in the
split tows than in the  tow  of the entire water column.  Consequently some
clogging in long tows through the entire water column is  suspected.

Species composition and abundance of zooplankton were similar at those
stations sampled twice  within a few hours.   In those  instances where a
station sampling was  repeated after many hours,  zooplankton  abundance
varied considerably.  However,  even though  abundance  was  decidely dif-
ferent,  percent composition of species  remained closely similar.  For
                                   135

-------
example, Station 24 was sampled on 7 and 8 October 1973.  The abundance
of calanoid copepods was 3,086 individuals/m3 on the first day and
7,533/m3 on the second, but percent composition increased only from 64.1
to 69.4%.  Consequently, interpretation of data based upon percent compo-
sition rather than abundances may be more valid.


Laboratory

All  adult crustacean zooplankton were identified to species.  Copepodids
were identified to species except those of Diaptomus and Cyclops, which
were identified to genus only.  Identifications were made according to
Yeatman  (1959) for cyclopoid copepods, Wilson (1959) for calanoid cope-
pods, Brooks  (1957) for Daphnia, Deevey and Deevey (1971) for Eubosmina,
and  Brooks  (1959) for remaining Cladocera.

Each sample was adjusted to a standard volume in a graduated cylinder.
The  sample was mixed thoroughly by random movements of a Hensen-Stemp el
pipette; then a subsample was quickly drawn from the middle of the
cylinder with the pipette.  Aliquots of 0.5, 1.0, or 5.0 ml were obtained
with properly calibrated pipettes depending upon concentration of organ-
isms.  The subsample was transferred to a chambered counting cell
(Gannon 1971).  The entire contents of the cell, usually 150-300 individ-
uals, were enumerated at 30-60 X under a Bausch and Lomb stereozoom
microscope.  Those organisms requiring higher magnification for identifi-
cation were transferred to an American Optical compound microscope and
observed at 100 or 430 X.  Two subsamples were counted from each sample
and  the results averaged.  If the counts varied more than 30%, a third
subsample was enumerated and only the two counts in closest agreement
were retained.  Data were calculated in numbers of individuals per m3
assuming 100% filtration efficiency.  These data appear in Appendix F.1-.3
for  the Straits of Mackinac and Appendix F.4 for northern Lake Michigan.
Percent relative abundance was also calculated for each species.

The  subsampling and counting procedure was tested for accuracy and repro-
ducibility.  Errors in the procedure were random, indicating that the meth-
ods  employed were reliable (Gannon 1972a).  Further statistical tests using
least squares regression analysis were performed on the subsampling and
counting procedure.  It was found that when an error estimate of 25% at the
95%  confidence level is desired, a minimum of 12 individuals per species
must be counted.  Numerical estimates of those rarer species in which there
were less than 12 individuals per subsample, i.e., roughly less than 150
individuals/m3, were considered as statistically unreliable.

Analytical

Principal component analysis (PCA) as described in Section 6.1 was used
as the analytical technique.  Three criteria were used to select the taxa
for the principal component analysis (PCA) of a particular month.  First,
it was required that each taxon be well enough defined taxonomically that
its contribution to the results of the analysis is interpretable.  With
                                   136

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the exception of Diaptomus spp.  copepodids,  composite  categories were
avoided.  Diaptomus spp. copepodite  stages are believed  to have similar
ecological requirements and  thus were  expected to  show interpretable
distributional patterns relative to  the  other taxa.  The second criterion
was that each taxon must be  observed at  more than  30%  of the stations of
the particular cruise in question.   Taxa which are not widely distributed
tend to dominate PCA by making the few stations  at which they do occur
look particularly unusual.   This is  a  problem common among parametric
multivariate techniques, which in general perform  poorly on data which
are badly skewed or include  a large  number of tied cases.  The non-inclu-
sion of locally distributed  taxa is  further  justified  on the basis that
the distributions of such taxa are generally easy  to describe without the
use of multivariate analysis.  The choice of 30% as a  cutoff point is
based largely on past experience with  PCA and represents the compromise
of including as many taxa as possible  without including  ones which are
locally or erratically distributed.  The third criterion for inclusion
of a taxa was that it be counted with  reasonable accuracy.  It was conse-
quently required that each taxon exceed  10 individuals in at least one
sample.  This criterion was  never directly imposed, however, because all
taxa which satisfied the second  criterion also easily  satisfied this
third one.

Using these criteria, 19 taxa were chosen for analysis of the August data
and 17 for the September and October data.   Initial principal component
analyses were performed on each  month's  data.  One rare  species,
Diaphanosoma leuchtenbergianum,  which  was included in  the original analy-
ses of each cruise, showed no distributional patterns  consistent with
the regions determined by the PCAs.  Consequently  it was decided not to
include this species in the  final analyses but instead to discuss its
distribution independently.

Separate PCAs were performed for each  cruise, using the  correlation matrix
of the percent composition of the selected taxa.  The  percent composition,
Pij, for taxon ± at station  j_ was computed as:   P-H =  (NIJ/NXJ) x 100%,
where N^ is the number of individuals of taxon  i_  found  at station j_ and
and NTJ  is the total zooplankton count  at station j_.  Station 40 was not
used in determining the principal components for the October data since
the zooplankton community at that station was particularly unusual and
did not correspond with the  community  of any other station in the survey
area.  The cumulative percentages of the total variance  contributed by
each of the first four principal components  for  the analyses are:

             Cruise          Number of
             number          stations    PCI.   PC2   PCS   PC4
          1 (August)            37        35%    46%   55%   63%
          2 (September)         40        42     52    62    71
          3 (October)           49        26     43    55    63
                                   137

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Plots were drawn showing the location of each of the stations relative  to
the  first two PCs.  The stations belonging to different regions on  these
PCA  plots are identified on maps of the survey area, and simple averages
for  each taxon in each region are tabulated to determine the distribution
pattern of each taxon relative to those regions.  We consider the maps
and  tables of averages and not the original PC plots to be of most  impor-
tance.  The choice of Euclidean distance as a measure of similarity
(rather than, for example, coefficient of community or percent similarity)
and  the decision not to use a non-linear data transformation (for example,
arcsine /P-H ) were made for this reason.

For  each cruise, the first PC was interpretable as a Lake Michigan-Lake
Huron axis.  Consequently, the largest share of the variance in the data
may  be interpreted as being due to an east-west or Lake Michigan-Lake
Huron effect.  The first PC of Cruise 2 by itself accounted for a large
percentage of the total variance.  Third and higher PCs were not used in
interpreting any of the analyses.
 7.3  RESULTS AND DISCUSSION


 Straits of Mackinac

 Twenty-nine taxa of crustacean zooplankton were recorded in the Straits
 region  (Table 7.1).  Twenty-three species of Cladocera and Copepoda were
 characteristic of limnetic waters, while six cladocerans were considered
 as benthic and littoral forms that sporadically appeared in the plankton.
 Seven calanoid and three cyclopoid copepods were represented.  Diaptomis
 oregonensis, D. minutus, and Epischura lacustris were the numerically
 predominant calanoid copepods.  Cyclops bicuspidatus thomasi was by far
 the  most abundant cyclopoid copepod.  Cladocera were represented by 13
 limnetic and six littoral and benthic species.  Daphnia galeata mendotae,
 D. retrocurva, Holopedium gibberum and Eubosndna coregoni were the pre-
 dominant limnetic cladocerans.  Ceriodaphnia reticulata was represented
 only by a single individual at Station 20 during Cruise 1.  Single
 specimens of Drepanothrix dentata were observed at Station 23 during
 Cruise 2 and Station 03 during Cruise 3.  These two species are apparently
 new  records for Lakes Michigan and Huron.

 The  opposum shrimp, Afysis relicta Loven, and the deepwater amphipod,
Pontoporeia affinis Lindstrom, were occasionally collected in plankton
samples.  Afysis was observed at Stations 08, 44, and 50 on Cruise 2 and
at Station 47 on Cruise 3.  Pontoporeia was observed at Station 35 during
Cruise 3.  Since these organisms are predominantly benthic during the
daytime, they were undoubtedly inadequately sampled by the plankton net
and  these data by no means reflect their abundance or distribution in the
Straits region.
                                   138

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Table 7.1.  LIST OF CRUSTACEAN ZOOPLANKTON SPECIES COL-
LECTED IN THE STRAITS OF MACKINAC REGION DURING 1973.
The symbol (*) denotes those species that are predomi-
nantly benthic and appear adventitiously in the plankton,
Calanoid Copepoda

     Diaptomus ashlandi Marsh
     Diaptomus minutus Lilljeborg
     Diaptomus oregonensis Lilljeborg
     Diaptomus sicilis Lilljeborg
     Epischura lacustris Forbes
     Limnocalanus macrurus Sars
     Senecella calanoides Juday

Cyclopoid Copepoda

     Cyclops bicuspidatus thomasi Forbes
     Mesocyclops edax Forbes
     Tropocyclops prasinus mexicanus Kiefer

Cladocera
  Family Leptodoridae
     Leptodora kindtii (Focke)
  Family Polyphemidae
     Polyphemus pediculus (L.)

  Family Sididae
     Diaphanosoma leuchtenbergianum Fischer
    *Sida crystal!ina (Muller)
  Family Holopedidae
     Holopedium gibberum Zaddach

  Family Daphnidae
     Ceriodaphnia lacustris Birge
     Ceriodaphnia quadrangula Muller
     Ceriodaphnia reticulata (Jurine)
     Daphnia galeata mendotae Birge
     Daphnia longiremis Sars
     Daphnia retrocurva Forbes

  Family Bosminidae
     Bosmina longirostris  (Muller)
     Eubosmina coregoni (Baird)

  Family Chydoridae
    *Acroperus harpae Baird
    *Alona affinis (Leydig) f|
    *Alona guadrangularis  (Muller)
     Chydorus sphaericus Muller
    *Drepanothrix dentata  (Euren)
    *Eurycercus lamellatus (Muller)
                           139

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Abundance of total Crustacea at various stations ranged from nearly
1,000 individuals/m3 to almost 28,000/m3 during the study period
(Fig. 7.2).  Average standing crops for Cruises 1, 2, and 3 were 8,642,
5,014, and 11,975/m3, respectively.  Higher numbers in October mainly
reflect recruitment of young instars, especially of Diaptomus spp., into
the population.  Concentrations of organisms were often higher at  inshore
stations and near Bois Blanc and Mackinac Islands.

Calanoid copepods were an important fraction of the plankton in the
Straits region.  They increased from an average of 3,862/m3 (42% of total
Crustacea) in August to 6,417/m3 (57% of total Crustacea) in October
(Fig. 7.3).  A pronounced east-west difference in abundance of calanoid
copepods was observed during August and September.  Numbers of calanoid
copepods were approximately 2-10 times lower west of the Mackinac Bridge
and in the South Channel (south of Bois Blanc Island) than towards the
Lake Huron portion of the Straits.  This pattern was less pronounced in
October as distribution of calanoids was more uniform throughout the
study area.

Four species of Diaptomus were observed in the Straits region.  Diaptomus
oregonensis was most abundant (4% of total Crustacea) and was decidedly
more prevalent west of the Mackinac Bridge and in the South Channel during
August and September (Fig. 7.4).  This species was considerably less
abundant in October and its distribution was more uniform.  Adults of
D. minutus were also most prevalent west of the Mackinac Bridge and in
the South Channel in August (Fig. 7.5) .  In September and October,  it was
low in abundance and more evenly distributed throughout the Straits area.
Adults of D. ashlandi and D. sicilis were relatively low in abundance
throughout the study period and comprised near 1% and 0.5%, respectively,
of total Crustacea during each cruise.  Numbers of D. ashlandi decreased
while numbers of D. sicilis increased throughout the study period.   No
distinct pattern of distribution was observed for D. ashlandi, but D.
sicilis was somewhat more abundant towards Lake Huron (Figs. 7.6 and 7.7).

Whereas adults of most diaptomids, especially D. oregonensis and D.
minutus, were most prevalent towards Lake Michigan and in the South Chan-
nel, copepodids of Diaptomus spp. were distinctly most abundant,
especially during August and September, towards Lake Huron and north of
Bois Blanc Island (Fig. 7.8).  Recruitment of young copepods into the
population is indicated throughout the study period as numbers of
Diaptomus copepodids increased from an average of 2,893/m3 in August to
5,968/m3 in October.  They comprised an average of about 30% of total
Crustacea in August and September and 53% in October.  Since Diaptomus spp.
copepodids were so abundant, the distribution pattern noted for total
calanoids (Fig. 7.3) largely reflects the distribution of Diaptomus spp.
copepodids (Fig.  7.8).

The other calanoid copepods, Limnocalanus, Senecella, and Epischura, were
low in relative abundance throughout the study period but exhibited dis-
tinct patterns of distribution.   Limnocalanus was decidedly more abundant
                                   140

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         TOTflL CRUSTflCEfl/M3
    17-19 SEPTEMBER 1973
        TOTflL CRUSTflCEfl/M»
     6-8 OCTOBER 1973     t-
Flgure  7.2.  DISTRIBUTION AND ABUNDANCE
     (NUMBERS OF INDIVIDUALS PER M3)  OF TO-
    TAL CRUSTACEAN  ZOOPLANKTON IN  THE
    STRAITS OF MACKINAC ON THREE CRUISES,
    1973.
                    141

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        CflLflNOIOS/M*
30 flUG - 1 SEPT 1973    5—TsSoO
            CflLHNOIOS/M»
    17-19 SEPTEMBER 1973    J
           CflLflNOIDS/M*
     $-8 XTOBER 1973
                                                          Z CflLflNOIOS
                                                  30 HUG - 1 SEPT 1973
                                                      Z CRLfWOIDS
                                                   SEPTEMBER 1973
                                                      Z CflLflNOIDS
                                                6-6 OCTOBER 1S73     6
Figure  7.3.   DISTRIBUTION AND ABUNDANCE (NUMBERS  PER  M3 AND PERCENT  COMPOSI-
     TION)  OF  CALANOID COPEPODS IN THE  STRAITS REGION.
                                            142

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      DIRPTOHUS OFEGONENSIS/M3
   30 flUG - 1 SEPT 1973    ,   •   •
             OREGONENSIS
30 flUG - 1 SEPT 1973
      DIflPTOMUS OREGQNENSIS/tf
   17-19 SEPTEMBER 1973
   % OlftPTOMUS OREGONENSIS
17-19 SEPTEMBER 1973
   7. DIflPTOMUS OREGONENSIS
  6-8 OCTOBER 1973
      DlfiPTOMUS OREGONENSIS/M3
     6-8 OCTOBER 1973
Figure  7.4.   DISTRIBUTION AND  ABUNDANCE  OF  DIAPTOMUS  OREGONENSIS IN THE
     STRAITS  REGION.
                                              143

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        DIfiPTOMUS NINUTUS/N*
    30 flUG - I SEPT 1973    & '   ' t5bo
         DIflPTOMUS MINUTUS/M*
    J7-I9 SEPTEMBER 1973    >—>—'-T&Q
        DIflPTOMUS MINUTUS/H1
     6-8 OCTOBER 1973      t—'—>~i3nn
     Z DIflPTOMUS HINUTUS
30 HUG -  I SEPT 1973
       OlflPTOMUS HINUTUS
  6-6 OCTOBER 1973      ft  •
Figure  7.5.   DISTRIBUTION AND ABUNDANCE OF DIAPTOMUS  MINUTUS IN THE
     STRAITS REGION.
                                             144

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       DIflPTOMUS RSONDI/M"
    30 BUG - 1 SEPT 1973
        DlfVTOHUS fiSHLWOI/H5
    17-19 SEPTQBER 1973
        DlflPTOMUS BSHLflNDl/H'
      6-8 OCTOBER 1973
    Z OlflPTQMUS flSHLflNDI
30 HUG - 1 SEPT  1973
    X OlflPTOMUS flSHLfWDI
17-19 SEPTEMBER 1973    t

    Z DIflPTOMUS RSHLflNDI
 6-6 OCTOBER 1973
Figure  7.6.   DISTRIBUTION AND  ABUNDANCE  OF  DIAPTOMUS ASHLANDI  IN  THE
     STRAITS  REGION.
                                              145

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         DlflPTOMUS SICILIS/M*
    30 RUG - 1  SEPT 1973
     DlflPTOMUS SICILIS/M*
17-19 SEPTEMBER 1973    g-
                                                       X DlflPTOMUS SICILIS
                                                  30 HUG - 1 SEPT 1973    *
                                                            X DlflPTOMUS SICILIS
                                                       17-19 SEPTEMBER 1973
         DIRPTOMUS SICILIS/M8
      6-8 OCTOBER 1973
                                                       X DIRPTOMUS SICILIS
                                                    6-8 OCTOBER 1973
Figure  7.7.   DISTRIBUTION  AND  ABUNDANCE  OF  DIAPTOMUS  SICILIS IN THE  STRAITS
     REGION.
                                               146

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     OlflPTOMUS SPP. COPEPOOIOS/M*
   30 flUG - 1 SEPT 1373    0
     DlflPTOMUS SPP.  COPEPOOIDS/M8
    17-19 SEPTEMBER 1973
     DlflPTOMUS SPP.  COPEPODIOS/M*
     6-8 OCTMER 1973     t—•-
 Z DlflPTOMUS SPP. COPEPOOIDS
30 BUG - 1 SEPT 1973    H-H
 2 DlflPTOMUS SPP. COPEPODIOS
17-19 SEPTEMBER 1973    *-*-
 Z DlflPTOMUS SPP.  COPEPOOIDS
 6-8 OCTOBER 1973
Figure  7.8.   DISTRIBUTION  AND ABUNDANCE OF DIAPTOMUS SPP.  COPEPODIDS  IN THE
     STRAITS  REGION.
                                                147

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 in open waters towards Lake Huron (Fig. 7.9).  For example, the average
 abundance of Limnocalanus during all cruises at stations west of the
 Mackinac Bridge was 2.3 individuals/m3 (0.04% of total Crustacea), where-
 as abundance of this species (86.3/m3 or 0.6% of total Crustacea) was
 distinctly greater along the transect of stations from Cordwood Point to
 Government Island toward Lake Huron.  As to be expected from this cold-
 water stenothermic species, Limnocalanus was most prevalent at offshore
 stations (Fig. 7.9).  The other cold-water stenotherm, Senecella, exhibited
 a pattern of distribution similar to Limnocalanus.  Senecella was absent
 from stations toward Lake Michigan and in the South Channel and was most
 abundant at offshore stations toward Lake Huron (Fig. 7.10).  In contrast,
 Epischura was more abundant toward Lake Michigan and in the South Channel
 than in the Lake Huron portion of the Straits region.  It was somewhat
 more abundant at nearshore stations, especially in South Channel
 (Fig. 7.11).

 Cyclopoid copepods were considerably less prevalent in the Straits region
 than either calanoid copepods or cladocerans.  Average abundance of
 cyclopoid copepods ranged from 232-1,018/m3 during the study period.
 During Cruises 1, 2, and 3, they comprised 5, 4, and 9%, respectively, of
 total crustacean plankton.  The cyclopoid copepods did not exhibit any
 striking distribution patterns within the Straits region (Fig. 7.12).

 The cyclopoid copepods were composed almost entirely of one species,
 Cyclops bicuspidatus thomasi, which comprised over 97% of total cyclopoids
 during the study period.  Obviously, the relatively uniform distribution
 of total cyclopoids (Fig. 7.12) is due to the distribution of Cyclops
 bicuspidatus thomasi (Fig. 7.13).  Mesocyclops edax, although low in
 numbers, was slightly more prevalent towards Lake Huron in August and
 September but was more evenly distributed throughout the study area in
 October (App. F.l-3).  Tropocyclops prasinus mexicanus was likely under-
 sampled by the mesh size of the net utilized in this investigation.  It
 was collected sporadically at stations throughout the study area during
 August and September (App. F.l-2).

 The Cladocera constituted a significant portion of crustacean plankton,
 particularly in August when they averaged 53% of total Crustacea.  Actual
 numbers were highest in October (average 4,541/m3), but Cladocera com-
 prised only 35% of total Crustacea due to increased abundance of copepods
 at this time.  The Cladocera were distinctly more abundant towards Lake
Michigan and in the South Channel than towards Lake Huron (Fig. 7.14).
 This trend was most prominent in August and September.  There was also a
 trend for Cladocera to be more prevalent at stations near shore (Fig. 7.14).

Daphnia galeata wendotae was the most abundant cladoceran throughout the
 study period.  It averaged 1,401 individuals/m3 in August and comprised
17% of total Crustacea.  This species exhibited a distinct pattern of
greatest abundance towards Lake Michigan and in the South Channel
 (Fig.  7.15).   A similar pattern was observed in September, but patchier
distribution was noted in October.  It was most abundant in nearshore
                                    148

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      L1MNOCHLRNUS MRCRURUS/KP
   30 (WG - 1  SEPT 1973
      UMNOCflLRNUS MBCRURUS/M9
   17-19 SEPTEMBER 1973    *—i
      LIMNOCfiLflNUS MBCBURUS/H*
     6-8 OCTOBER 1973     i—•
     LIMNOCflLflNUS MflCHJRUS
30 RUG - 1 SEPT 1973
   X LINNOCflLflNUS MfCTUflUS
  6-8 OCTOBER 1973
Figure 7.9.   DISTRIBUTION  AND ABUNDANCE  OF LIMNOCALANUS MACRURUS IN THE
     STRAITS  REGION.
                                              149

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         SENECELLR CFLFWOIDES/H*
     30 flUG -  1 SEPT 1973
        SENECELLfl CfWJ*IOIDES/M»
     17-19 SEPTEMBER 1973
    X SENECELLFI CN.RN01DES
30 HUG - 1 SEPT 1973      '  '  '
        SENECELLH tflLflNOIOES/M*
      6-8 OCTOBER 1973     t—"—•—"-51.
    X SENECELLR CHLWOIDES
17-19 SEPTEMecn 1973      '  •  '
    X SENECELLFI CflLRNOIOES
  6-8 OCTOBER 1973      t—'—•-
Figure  7.10.   DISTRIBUTION AND ABUNDANCE OF SENECELLA CALANOIDES  IN  THE
     STRAITS REGION.
                                               150

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        EPISCHURfl LflCUSTRIS/M8
    30 HUG - 1 SEPT  1973    ft •  •  i^fa
                                                     Z EPISCHURfl LfiCUSTRIS
                                                 30 flUG - 1 SEPT 1973    g-
        EPISCHURft LflCUSTHIS/M*
    17-19 SEPTEMBER 1973    ft i  i  -^
                                                     % EPISCHUm LflCUSTRIS
                                                 17-19 SEPTEMBER 1973
                                                           Z EPISCHURfl LflCUSTRIS
                                                         8-8 OCTOBER 1973
  EPISCHURfl LBCUSTRIS/M»
6-8 OCTOBER 1973      fl •  •  '^
Figure  7.11.   DISTRIBUTION AND ABUNDANCE OF EPISCHVRA LACUSTRIS IN  THE
     STRAITS REGION.
                                                 151

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                                                           X CYCLOPOIOS
                                                    30 RUG - 1  SEPT 1973
       CTCLOPOIDS/M*
30 BUG - 1 SEPT 1973    g
           CTCLOPOIDS/M'
    17-19 SEPTEMBER 1973    *
                                                        V. CTCLOPOJOS
                                                17-19 SEPTEMBER 1973    t
                                                            7. CYCLOPOIOS
                                                      6-8 OCTOBER 1973
        CYODPOIDS/M'
  6-8 OCTOBER 1973     fr
Figure  7.12.  DISTRIBUTION AND  ABUNDANCE OF CYCLOPOID  COPEPODS  IN  THE
     STRAITS REGION.
                                             152

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                                                       X CYCLOPS BICUSPIDflTUS THOMRSI
                                                       30 RUG - 1 SEPT 1973
CYCLOPS BICUSPIDRTUS THOMBSI/M8
30 flUG - I SEPT 1973    ..
CYCLOPS BICUSPIORTUS THOMflSJ/H*
17-19 SEPTEMBER 1973
                                                       Z CYCLOPS BICUSPIOHTUS THOMfiSI
                                                       17^19 SEPTEMBER 1973
                                                       Z CYCLOPS BICUSPIDfiTUS THOMHSI
    CYCLOPS BICUSPJDflTUS THOMflSI/M'
     B-8 OCTOBER 1973      ±—•
Figure  7.13.   DISTRIBUTION AND  ABUNDANCE  OF  CYCLOPS  BICUSPIDATUS  THOMASI
     IN  THE  STRAITS  REGION.
                                               153

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            CLftDOCERfl/M»
    30 «JG - 1 SEPT 1973
        % CLHXKERfl
30 BUG - 1 SEPT 1973    Q ' '  '  ' too
            CLflDOCERH/M5
    17-19 SEPTEMBER 1973
     6-8 OCTOBER 1973
         CLROOCEHR
17-19 SEPTEMBER 1973
        X CLFOOCERfl
 6-6 OCTOBER 1973
Figure  7.14.   DISTRIBUTION  AND  ABUNDANCE OF  CLADOCERA  IN THE STRAITS
     REGION.
                                            154

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     ORPHNIR GRLERTR MENOOTRE/H*
   30 BUG - 1 SEPT 1973    .  .  .
     OflPHNIH GflLEflTR MENDOTflE/M'
    17-19 SEPTEMBER 1973
      DflPHNIfl GflLERTfl MENDOTRE/M8
      6-8 OCTOBER 1973
  Z ORPHNIR GflLERTA HENDOTflE
30 BUG - 1 SEPT 1973   g—»-
  Z DRPHNIft GHLERTA HENOOTRE
17-19 SEPTEWER 1973     —«-
  X ORPHNlfl GflLERTft MENOOTRE
  6-B OCTOBER 1973      j
Figure  7.15.   DISTRIBUTION AND ABUNDANCE  OF  DAPHNIA  GALEATA MENDOTAE  IN THE
     STRAITS REGION.
                                               155

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 areas,  especially  off  the  islands  and  the north  shore of  the  study  area
 during  October  (Fig. 7.15).

 Daphnia retrocurva was  also an abundant cladoceran in the Straits region
 where it comprised an  average of near  10% of total Crustacea  during
 August  and  September.   Its contribution (4%) to  total Crustacea was
 considerably less  during October.  This species was predominantly distrib-
 uted in waters  toward  Lake Michigan and in the South Channel  during all
 three cruises (Fig.  7.16).  It was also more abundant at  nearshore
 stations.

 In contrast to  D.  galeata  mendotae and D. retrocurva, D.  longiremis was
 less abundant and  its  patterns of  distribution were not as distinctive.
 Daphnia longiremis comprised an average of 4, 3, and 1% of total
 Crustacea during August, September, and October, respectively.  It  was
 most abundant north  of the islands in August; no decisive pattern was
 evident in  September and October (Fig. 7.17).

 Holopedium  gibberum was an important constituent of the plankton community
 in the  Straits  region.  It was most abundant during August when an  average
 of 905/m3 or 5% of total Crustacea was observed.  Holopedium  exhibited
 greatest abundance in  waters toward Lake Michigan and in  the  South  Chan-
 nel, especially during August and September (Fig. 7.18).  Its distribu-
 tion in October was  less distinct, with some tendencies to be more
 prevalent near  shore.

 The carnivorous species Leptodora kindtii was never sufficiently abundant
 to comprise 1%  of  total Crustacea.  However, it was distributed through-
 out the study area and was considerably more abundant toward Lake Michigan
 and in  the  South Channel (Fig. 7.19).  The other carnivorous  cladoceran,
 Polyphemus  pediculus, was  less abundant than L. kindtii,  but  its distri-
 bution  pattern  was strikingly similar, especially in August and September
 (App. F.l-3).

 Eubosmina coregoni was approximately two to three times more  abundant in
 the Straits region than Bosmina longirostris.  The relative abundance of
 E.  coregoni decreased  from 7% of total Crustacea in August to 3% in
 October while B. longirostris increased slightly from 1%  in August  to 2%
 in October.   The distribution patterns of the two species were notably
 different;  E. coregoni was most characteristic of waters  towards Lake
 Michigan and  in the South  Channel  (Fig. 7.20), B. longirostris was  most
 prevalent near  the north shore especially at the mouth of the St. Marys
 River as well as shallow stations elsewhere (Fig. 7.21).

 The remaining Cladocera were present in low levels of abundance, consid-
 erably  less  than 1% of total Crustacea.  Diaphanosoma leuchtenbergianum
was distributed throughout the Straits region during the  study period.
 Its distribution was exceedingly irregular in August and  September.  In
 October, it was most prevalent along the north shore and  another patch
 of relative abundance was noted at Station 16 in the South Channel
                                   156

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      DRPM41R RETROCURVR
30 RUG - 1 SEPT J973
        OflPHNIfi RETROCURVR/M»
   30 flUG - 1 SEPT 1973
        DfiPHNIfi RETHOCUHVB/N9
    17-19 SEPTEMBER 1973    *
        OflPHNIfl RETROCURVfl/M9
     6-8 OCTOBER 1973     t-
      OflPWJIfl RETROORVR
17-19 SEPTEMBER 1973    t
     Z DflPHNIH RETROCURVR
  6-6 OCTOBER 1973
Figure  7.16.   DISTRIBUTION AND ABUNDANCE  OF  DAPHNIA  RETROCURVA  IN  THE
     STRAITS REGION.
                                               157

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    DflPHNIfl LONGIREHIS/M*
30 HUG - I SEPT 1973
         DflPHNIfl LONGIREMIS/M*
     17-19 SEPTEMBER 1973
         DflPHNIfl LONGIFEMIS/M5
      6-8 OCTOBER 1973
                                                            Z DOPHNIfl LOMGIREHIS
                                                       30 flUG - 1 SEPT 1973
                                                       % DflPHNlfl LONGIBEMIS
                                                   17-19 SEPTEHBER 1973
                                                       Z DRPHNIR LONGIREMIS
                                                    6-6 OCTOBER 1973
Figure 7.17.   DISTRIBUTION AND ABUNDANCE OF DAPHNIA LONGIREMIS  IN  THE
     STRAITS REGION.
                                               158

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       HOLOPEDIUN GI8BERUM/M8
   30 BUG - 1 SEPT 1973
                                                     % HOLOPEOIUM GIBBERUM
                                                 30 BUG - 1 SEPT 1973    K
       HOLOPEOIUM GIBBERUM/M8
    17-19 SEPTEMBER 1973
                                                     7. HOLOPEOIUM GIBBERUM
                                                  17-19 SEPTEMBER 1973
                                                          Z HOLOPEOTUH GIBBEBUM
                                                        6-6 OCTOBER 1973
  HQLOPEDIUM GIBBEflUM/K5
6-8 OCTOBER 1973
Figure  7.18.   DISTRIBUTION AND  ABUNDANCE  OF  HOLOPEDIUM GIBBERUM IN THE
     STRAITS REGION.
                                               159

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         LEPTODORR KINDTII/M8
    30 BUG - I SEPT 1973
         LEPTODOflfl KINDTII/M8
     17-19 SEPTEMBER 1973
         LEPTODORfl KINOTII/M8
      6-6 OCTOBER 1973      t
     % LEPTOOOfW KINDTII
30 RUG - 1 SEPT 1973
     '/. LEPTOOOFW KINDTII
17-19 SEPTEMBER 1973
     2 LEPTODORR KINDTII
  6-8 OCTOBER 1973
Figure  7.19.   DISTRIBUTION  AND  ABUNDANCE  OF  LEPTODORA KINDTII  IN  THE
     STRAITS REGION.
                                               160

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       EUBOSMINfi COREGONI/tP
   30 flUG - 1 SEPT 1973
        EUBOSMINfl COREGON1/M3
   17-19 SEPTEMBER 1973
        EUBOSMINR COREGONI/M5
     6-6 OCTOBER 1973      Jt—
                              Tsbo
      EUBOSHINfl COFEGQNI
30 flUG - 1 SEPT 1973
    '/. EUBOSMINf) COREGONI
17-19 SEPTEMBEfl 1973
    X EUBOSHINfl COHEGONI
 6-6 OCTOBER 1973
Figure  7.20.   DISTRIBUTION AND ABUNDANCE OF EUBOSMINA COREGONI  IN THE
     STRAITS REGION.
                                               161

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       BOSMINfl LONGIROSTHIS/MS
    30 HUG -  1 SEPT 1973
                                                     Z BOSMINB LONGIROSTfUS
                                                 30 flUG - 1 SEPT 1973    £—•
       BOSHJNR UMGIROSTRIS/M9
    17-19 SEPTQ^R 1973
                                                     % BOSHlNfi LONGIFOSTRIS
                                                 17-19 SEPTEMBER 1973
                                                          Z BOSMINR LONGIROSTFirS
                                                        e-6 OCTOBER 1973
  BOSMINfi LONGIHOSTBIS/M5
6-8 OCTOBER 1973
Figure  7.21.   DISTRIBUTION AND ABUNDANCE OF BOSMINA  LONGIROSTRIS  IN THE
     STRAITS REGION.
                                                162

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(Fig. 7.22).  Ceriodaphnia lacustris,  C.  guadrangula,  and Chydorus
sphaericus were observed  throughout  the Straits region but exhibited no
noteworthy patterns of distribution,   sida  crystallina, a littoral species
was observed only in September  near  the mouth of the St. Marys River      '
Other species were predominantly littoral forms that occasionally appeared
as one or two individuals at nearshore stations (App.  P.1-3) .

In summary, the preceding simple inspection of data reveals  that there
were differences in the community structure of crustacean zooplankton
within the Straits of Mackinac.  Although the species  composition was
practically identical at  every  station, prominent and  consistent patterns
were evident in the relative proportions  of species to one another in
specific subregions within the  Straits.   The relative  abundance of zoo-
plank ters towards Lake Michigan (west  of  the Mackinac  Bridge) and in the
South Channel (south of Bois Blanc Island)  shared many resemblances.
This region was characterized by a distinct preponderance of cladocerans,
especially Daphnia retrocurva and D. galeata mendotae.  Other cladocerans,
such as Holopedium gibberum, Eubosmina coregoni, Leptodora kindtii, and
Polyphemus pediculus, were also most prevalent in this region.  In addi-
tion, the calanoid copepods Epischura  lacustris, Diaptomus oregonensis,
and D. minutus were generally characteristic of this region.  In contrast,
calanoid copepods as a group were relatively most abundant in waters
towards Lake Huron, i.e., north and east  of Bois Blanc Island.  The pre-
ponderance of calanoid copepods in this region was mainly due to
copepodids of Diaptomus spp., D. sicilis  adults, Limnocalanus macrurus
and Senecella calanoides. Cyclopoid copepods,  predominantly Cyclops
bicuspidatus thomasi, did  not show any  distinctive trends but appeared
somewhat more prevalent toward  Lake Huron.   Cladocerans, such as Bosmina
longirostris, were mainly characteristic  of inshore stations in this
region.

Principal component analysis (PCA) allowed  us to more  clearly observe
some of these trends and  defined other trends not discernible simply by
inspection.  Two major regions, here arbitrarily termed L and M, were
deliniated by PCA based upon similarities in relative  abundance of zoo-
plankters at various stations.   The L  region lies toward Lake Michigan
and in the South Channel  while  the M region consists of waters towards
Lake Huron and north of Bois Blanc Island.   On August  and October cruises,
the M region was divided  into two subregions,  M east of Bois Blanc Island
and N north of the island.  The N subregion was not sampled due to inclem-
ent weather during the September cruise.  These major  regions were
remarkably consistent both in areal coverage and in species associations
throughout the study (Figs. 7.23-7.25).

During the August cruise, the waters toward Lake Michigan and in the
South Channel (L2) were characterized  by  a  greater relative abundance of
Daphnia retrocurva, D. galeata  mendotae,  Holopedium gibberum, Eubosmzna
coregoni, Epischura lacustris,  Diaptomus  oregonensis,  and D. nunutus
(Fig. 7.23).  Stations within the Lj subregion  showed  the greatest affin-
ities due to a preponderance of Daphnia galeata mendotae  D. retrocurva,
and Diaptomus minutus (Table 7.2).  L3 was  characterized by greater
                                    163

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    DlfiPHflNOSOHfl LEUCHTENBERGIflNUM/lP
     30 RUG - 1 SEPT 1973    £
    DIflPHflNOSOMH LEUCKTENBEBGIflNUM/M*
     17-19 SEPTEMBEft 1973    (j—i
    DIflFHflNOSOMfi LEUCHTENBEHGIflNUH/Ma
      6-8 OCTOBER 1973      g—'—i
Z OlflPHflNOSOMB LEUCHTENBERGIfNJM
 30 flUG - 1 SEPT 1973    g
Z OlflPmNOSOMft LEUCKIENBERGIFHJH
 17-19 SEPTEMBER 1973
Z OlftPHFWOSOMfl LBJCHTENBERCIflNUH
   B-6 OCTOBER 1973     i—«
Figure 7.22.   DISTRIBUTION AND ABUNDANCE  OF  DIAPHANOSOMA LEUCHTENBERGIANUM
     IN THE  STRAITS REGION.
                                                 164

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Figure 7.23.  ZONES OF SIMILARITY IN COMMUNITY STRUCTURE OF CRUSTACEAN ZOOPLANKTON IN THE STRAITS
    REGION DURING AUGUST 1973.  These zones,  arbitrarily labeled L,  M,  and  N,  were determined  by
    principal component analysis using percent composition of  16 species.

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                                                                                   DETOUR
                                                                                  PASSAGE
                     -84M5'
Figure 7.24.  ZONES OF SIMILARITY IN COMMUNITY STRUCTURE OF CRUSTACEAN ZOOPLANKTON  IN  THE
    STRAITS REGION DURING SEPTEMBER  1973 AS DETERMINED BY PRINCIPAL COMPONENT ANALYSIS.

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ON
•-J
                                                     		two	=	84«OCT	

           Figure 7.25.  ZONES OF SIMILARITY IN COMMUNITY STRUCTURE OF  CRUSTACEAN ZOOPLANKTON IN THE

               STRAITS REGION DURING OCTOBER  1973 AS DETERMINED BY PRINCIPAL  COMPONENT  ANALYSIS.

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Table 7.2.  DISTRIBUTION OF ZOOPLANKTON DURING AUGUST 1973.  Relative abun-
dances (in percent composition)  for each region (Fig. 7.23) are given over
the standard error of the mean.   Standard errors are omitted when values
used in the average are identical.   Taxa are grouped according to apparent
trend.  Taxa most abundant in Lj  are listed first, and those most prevalent
in MI appear last.
Region and number of stations

Daphnia retrocurva

Epischura lacustris

Diaptomus minutus

Holopedium qibberum

Eubosmina coregoni

Daphnia galeata mendotae

Diaptomus oregonensis

Leptddora kindtii

Polyphemus pediculus

Mesocyclops edax

Daphnia longiremis

Ceriodaphnia lacustris

Bosmina longirostris

Diaptomus ashj.andi

Cyclops bicuspidatus thomasi

Diaptomus sicilis

Diaptomus spp. copepodids

Limnocalanus macrurus

Li
4
17.2
4.4
1.4
.1
10
3
16
3
11
1
28
3
4.1
1.3
.56
.04
.14
.09
.11
.07
1.6
.9
.09
.05
.38
.13
.54
.02
1.7
-4
.02
.02
6.1
.5
0

L2
10
15
3
1.3
.2
7.9
1.3
14
1
8.5
1.1
23
1
6.2
1.1
.91
.16
.41
.13
.21
.14
2.7
.5
.08
.03
.46
.14
1.1
.1
3.5
.4
.02
.02
13
2
.02
.02
L3
8
11
2
1.2
.2
4.4
.7
15
1
7.8
.5
18
1
5.6
.8
.73
.14
.19
.08
.15
.06
3.4
1.0
.13
.03
.84
.31
1.69
.08
6.0
.5
.01
.01
22
3
.07
.03
NI N2
1 3
8.5 5.4
.4
.59 .55
.17
.77 1.4
.5
6.8 6.2
1.7
3.2 2.8
.3
8.1 8.7
.5
4.2 3.1
.6
.47 .66
.50
.09 .02
.02
.09 -09
.03
13 11.1
.6
.26 .10
-05
1.7 1.8
.4
3.9 1.8
.2
6.1 6.8
.6
0 .05
.04
41 48
3
0 .15
.14
M2
9
5.7
.7
.63
.12
2.1
.5
7.0
.7
3.7
.3
10.5
.7
2.1
.4
.28
.06
.15
.06
.13
.06
4.8
.7
.05
.01
1.1
.2
1.51
.07
5.9
.5
.16
.05
52
2
.46
.20
MI
1
1.0

.31

1.2

3.4

1.3

3.2

.57

.11

.05

.02

.87

0

.30

.48

2.1

.05

84

.38

                                   168

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relative abundance of Diaptomus  oregonensis.   Stations  in  the M region
northeast of Bois Blanc  Island  showed affinities based  upon greater
relative abundance of Diaptomus  sicilis,  Diaptomus  spp.  copepodids and
Limnocalanus macrurus.   These species also comprised a  major constituent
in the N region northwest of Bois  Blanc Island,  but this region was more
characterized by the relative abundance of Diaptomus ashlandi, Daphnia
longiremis, Bosmina longirostris,  and Cyclops bicuspidatus thomasi
(Fig. 7.23).  Only one (Mesocyclops edax)  of  the 16 species analyzed did
not show any strong trends  in distribution during August (Table 7.2).

Trends in species associations were strongest during the September cruise,
a period characterized by strong westerly winds  (Fig. 7.24).  The L
region was characterized by the  same species  predominance  as observed in
August.  Daphnia retrocurva, D.  galeata mendotae, and Diaptomus
oregonensis were most prevalent  in the Lj  subregion, while Holopedium
gibberum and Epischura lacustris most characterized the 1,3 subregion.
The M region was also characterized by the same  predominant species as in
August.  Stations in the MI subregion had  a relatively  greater abundance
of Diaptomus spp. copepodids, D. sicilis,  Limnocalanus  macrurus, and
Bosmina longirostris, while the  MS subregion  had more Cyclops bicuspidatus
thomasi (Fig. 7.24).  Only Mesocyclops edax,  Daphnia longiremis. and
Diaptomus ashlandi did not  show  any strong trends in distribution during
this cruise (Table 7.3).

Trends in relative abundance of  zooplankters  were least  distinct during
the October cruise, when weak easterly winds  were blowing  (Fig. 7.25).
The L region included the same  species predominance as  the previous
cruise with the addition of Mesocyclops edax  and Eubosmina coregoni and
the exclusion of Holopedium gibberum and Daphnia galeata mendotae.  The
LI subregion was predominated by Daphnia retrocurva, Diaptomus ashlandi,
D. oregonensis, Epischura lacustris,  and Leptodora  kindtii while 1*2 was
characterized by a greater preponderance of Eubosmina coregoni and
Diaptomus minutus.  The  M and N  subregions were  more distinct from one
another than on previous cruises.   Daphnia longiremis, D. galeata mendotae,
and Holopedium gibberum  were most  prevalent in the  N subregion while, as
in previous cruises, Diaptomus spp. copepodids,  D.  sicilis and Limnocalanus
macrurus characterized the M subregion (Fig.  7.25).  Station 40, inshore
in the extreme southeastern corner of the  study  area, was an entity in
itself during this cruise.  It contained strong  characteristics of both
L and N regions with a preponderance of Epischura lacustris,  Leptodora
kindtii, Daphnia longiremis, D.  galeata mendotae, and Holopedium gibberum
(Fig. 7.25).  Only Cyclops bicuspidatus thomasi  and Bosmina longirostris
were not characteristic  of  any particular  portion of the Straits region
during this cruise (Table 7.4).

The distribution and abundance of  crustacean  zooplankton is related to
temperature, food requirements,  and competitive  interactions among
species.  Our understanding of the interrelationships between physico-
chemical and biological  factors  expressed  in  different growth and repro-
duction rates of various species is indeed meager.  Nevertheless, the
                                    169

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Table 7.3.  DISTRIBUTION OF ZOOPLANKTON DURING SEPTEMBER 1973.  Relative
abundances (in percent composition) for each region (Fig. 7.24) are
given over the standard error of the mean.  Taxa are grouped according
to apparent trend.  Taxa most abundant in Lj are listed first, and those
most prevalent in M^ appear last.

Region and number of stations

Leptodora kindtii

Diaptomus oregonensis

Daphnia retrocurva

Diaptomus minutus

Eubosmina coregoni

Daphnia, galeata mendotae

Epischura lacustris

Holopedium gibberum

Diaptomus ashlandi

Daphnia longiremis

Mesocyclops edax

Bosmina longirostris

Cyclops bicuspidatus thomasi

Diaptomus sicilis

Diaptomus spp. copepodids

Limnocalanus macrurus

Ll
4
1.3
.2
9.0
1.9
19
3
2.4
.5
2.6
.3
42
5
2.9
.9
4.2
.9
1.1
.3
2.8
1.3
.04
.04
0

2.1
.6
0

8.7
2.5
0

L2
7
1.14
.08
5.9
3.2
17
2
1.9
.5
3.1
.5
38
4
3.8
.9
5.6
1.2
.60
.13
3.4
.7
.20
.09
.27
.21
1.8
.4
.11
-04
15
4
.09
.06
L3
6
.74
.31
7.1
1.1
14.1
.5
.81
.18
1.4
.3
35
3
2.3
.6
4.0
1.3
1.6
.6
4.2
1.1
.13
.09
.13
.10
3.9
1.1
.02
.02
22
2
.05
.03
M3
11
.35
.05
2.6
.6
7.6
1.3
1.1
.2
2.0
.3
15
2
1.5
.2
2.2
.3
.85
.15
3.2
.6
.22
.07
-63
.22
6.0
1.3
.21
.08
55
3
.90
.31
M2
6
.16
.06
1.1
.2
4.1
.8
.18
.10
.65
.23
9.2
1.5
.65
.23
1.3
.3
.35
.05
2.1
.3
.10
.03
1.4
.2
3.9
.4
.18
.04
73
2
.77
.26
MI
6
.07
.01
.62
.16
1.9
.4
.15
.08
.33
.08
6.5
1.4
.50
.16
1.2
.2
.33
.07
1.8
.3
.09
.02
2.1
.7
4.3
.5
.31
.04
78
3
1.5
.6
                                  170

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Table 7-4.  DISTRIBUTION OF ZOOPLANKTON DURING  OCTOBER 1973.  Relative
abundances (in percent composition)  for each region  (Fig. 7.25) are given
over the standard error of the mean.   Standard  errors are omitted when
values used in the average are identical.   Taxa are  grouped according to
apparent trend.  Taxa most abundant  in Lj  are listed first, and those most
prevalent in M^ appear last.
Region and Number

Epischura lacustris

Daphnia retrocurva

Diaptomus minutus

Diaptomus ashlandi

Leptodora kindtii

Mesocyclops edax

Diaptomus oregonensis

Eubosmina coregoni

Cyclops bicuspidatus thomasi

Bosmina longirostris

Daphnia longiremis

Holopedium gibberum
Daphnia galeata mendotae

Diaptomus spp. copepodids
Diaptomus sicilis
Limnocalanus macrurus
Li
3
4.2
.9
9.5
1.1
.75
.24
1.5
-4
.45
-04
.34
.10
1.5
.2
2.6
1.0
8.0
.8
1.7
.9
.10
.02
1.8
.4
15.4
.6
49
2
.15
.11
0
L2
10
2.5
.4
5.8
.7
.90
.14
.92
.15
.15
.03
.30
.06
1.0
.2
4.4
.5
9.3
2.1
1.0
.2
.33
.13
3.2
.7
18-
2
48
3
.27
.08
.01
.01
LN NI
1 9
12 .64
.21
4.9 4.0
.7
.61 .24
-05
0 -47
.09
.46 .06
.03
.15 .09
-05
.15 .88
.16
.61 2.1
.2
10 7.3
.5
2.8 1.9
.3
.76 1.4
.4
20 8.5
1.1
38 30
2
10 40
2
0 .32
.07
0 -02
-01
of stations
N2
8
.57
.12
2.7
.5
.17
.08
.34
.08
.09
.03
.14
.04
.52
.10
2.7
.2
9.6
1.5
3-6
1.4
.53
.09
5.8
1.3
17

53
1
-43
.09
.21
.09
M2
12
.90
.29
2.0
.3
.32
.06
.32
.04
.08
.02
.11
.03
.78
.10
2.4
.3
8.9
.5
1.4
.2
.71
.12
3.6
.4
14

62
1
.63
.09
.31
.18
MI
7
.43
.17
1.7
.3
.12
.04
.15
.02
.16
.04
.09
.03
1.0
.1
1.9
.3
7.3
.9
1.9
.6
.35
.08
3.0
.7
11

68
2
.71
.08
1.3
.6
                                      171

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 distribution and abundance of crustacean zooplankton observed in  the
 Straits of Mackinac region are interpretable in light of our knowledge
 of  responses of zooplankton communities to different trophic conditions.

 Calanoid  copepods generally appear best adapted^ for oligotrophic  condi-
 tions  in  the Great Lakes.  In more eutrophic waters, cladocerans,
 cyclopoid copepods, and rotifers are relatively more abundant than
 calanoid  copepods.  This trend has been observed in Lakes Superior,
 Huron, Erie, and Ontario by Patalas (1972) and in Lake Michigan by
 Gannon (1972a; 1972b; 1974b; 1975).  In the Straits of Mackinac,  the
 simple ratio of calanoid copepods to cyclopoid copepods and cladocerans
 appeared  to be an indicator of trophic conditions (Figs. 7.26-7.28).
 Higher values were generally obtained towards Lake Huron and lower values
 towards Lake Michigan during each cruise.  The actual numbers obtained
 in  this simple ratio do not seem important but relative differences from
 station to station are revealing.  Monitoring changes in the ratio of
 calanoid  copepods to cladocerans and cyclopoid copepods during summer
 stratification may be a useful indicator of eutrophication trends in the
 Great  Lakes.

 In  summer, even though physicochemical characteristics of water at various
 stations  in the Straits region differed only subtly, distinct water masses
 were identified.  Similarities between water masses discerned by cluster
 analyses  (see Sec. V) and regions of homogeneity in zooplankton community
 structure (Figs. 7.23-7.25) were remarkable.  Cladocerans were relatively
 most abundant in the slightly more eutrophic waters towards Lake Michigan
 and in the South Channel, while calanoid copepods prevailed in the
 slightly  more oligotrophic waters towards Lake Huron;  Although the species
 of  crustacean zooplankton were nearly identical throughout the study area,
 the community structure appeared to be a sensitive indicator of water
 quality even in the waters of the Straits region where nutrient conditions
 differ so subtly.

 Northern  Lake Michigan

 All of the eulimnetic crustacean zooplankton noted in the Straits region
 were observed in northern Lake Michigan during September except
 Tropocyclops prasinus wexicanus and Polyphemus pediculus (App. F.4).
 Littoral  and benthic species were absent iti the plankton except for a few
 individuals of Acroperus harpae at the shallowest station (10 m) off the
 Sturgeon  Bay Ship Canal.  Mysis relicta was observed in the plankton at
 most stations greater than 120 m deep.  Pontoporeia affinis was observed
 in the plankton only at Station 24, 164 m deep (App. F.4).

Average numbers of crustacean zooplankton were considerably lower at
 stations  in northern Lake Michigan (1,537/m3) than in the Straits region
 (5,014/m3) in September (Fig. 7.29).  Highest numbers (>3,000/m3) were
noted at an inshore station near Sturgeon Bay and stations nearest the
Straits region.   The lowest numbers (
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     CLADOCERA + CYCLOPOIDA
          AUGUST, 1973
Figure 7.26.   THE RATIO  OF CALANOID COPEPODS TO CLADOCERANS AND CYCLOPOID COPEPODS
    IN THE STRAITS REGION DURING AUGUST 1973.

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   CLADOCERA + CYCLOPOIDA
       SEPTEMBER .1973
Figure 7.27.   THE RATIO OF CALANOID COPEPODS TO CLADOCERANS AND CYCLOPOID COPEPODS
    IN THE STRAITS REGION DURING  SEPTEMBER 1973.

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  CLADOCERA + CYCLOPOIDA
      OCTOBER,1973
Figure 7.28.   THE  RATIO OF CALANOID COPEPODS TO CLADOCERANS AND CYCLOPOID COPEPODS
    IN THE STRAITS REGION DURING OCTOBER 1973.

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                                         TOTflL CRUSTRCEfl/M3

                                               6  '  ' '  10000
    Figure 7.29.  DISTRIBUTION AND ABUNDANCE (NUMBERS OF INDIVID-
        UALS PER M3) OF TOTAL CRUSTACEAN ZOOPLANKTON IN NORTHERN
        LAKE MICHIGAN DURING SEPTEMBER 1973.
deepest offshore stations.  Calanoid copepods and cladocerans each com-
posed about half of the crustacean zooplankton.  Cyclopoid copepods
represented a minor component in the fauna.  Predominant species were
Daphnia galeata roendotae and D. retrocurva followed by Limnocalanus
macrurus, Diaptomus oregonensis, Eubosmina coregoni, and Diaptomus
sicilis.

Calanoid copepods comprised an average of 51% of total Crustacea
(Fig. 7.30).  Approximately half of the calanoids were Diaptomus spp.
copepodids.  These immature copepods did not exhibit any appreciable
pattern of distribution in northern Lake Michigan (Fig. 7.31)).  Adult
Diaptomus oregonensis (Fig. 7.32) and D. ashlandi (App. F.4) were
slightly more abundant at stations nearest the Straits of Mackinac than
elsewhere in northern Lake Michigan.  In contrast, D. sicilis was gener-
ally more prevalent at deep stations southwest of Beaver Island
(Fig. 7.33).  Limnocalanus macrurus was found at all stations but was
generally most abundant at deeper offshore stations (App. F.4) .  An
exception was a relatively large number (191/m3) at shallow Station 44.
Senecella calanoides was not observed at stations less than 120 m deep.
Diaptomus minutus and Epischura lacustris were both low in abundance and
did not exhibit any noteworthy patterns of distribution (App. F.4).
                                  176

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                                       0      8000
Figure 7.30.  DISTRIBUTION AND ABUNDANCE OF CALANOID
    COPEPODS IN NORTHERN LAKE MICHIGAN.

    (a) Numbers per m^.

    (b) Percent composition.
                          177

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                                XDIflPTOMUS SPP. COPEPODIDS
                              DIflPTOMUS SPP. COPEPODIDS/M3
                                               8000
Figure 7.31.  DISTRIBUTION AND ABUNDANCE OF DIAPTOMUS  spp.
    COPEPODIDS IN NORTHERN LAKE MICHIGAN.

    (a) Numbers per m3.

    (b) Percent composition.
                            178

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                                  XDIflPTOMUS OREGONENSIS

                                         0       15
                                DlflPTOMUS OREGONENSIVM3
                                        0
600
Figure 7.32.  DISTRIBUTION AND ABUNDANCE OF DIAPTOMUS
    OREGONENSIS IN NORTHERN LAKE MICHIGAN.

    (a) Numbers per m^.

    (b) Percent composition.
                             179

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                                   XDIflPTOMUS SICILIS
                                 DIRPTOMUS SJCILIS/M3
                                       0
150
Figure 7.33.  DISTRIBUTION AND ABUNDANCE OF DIAPTOMUS
    SICILIS IN NORTHERN LAKE MICHIGAN.

    (a) Numbers per m3.

    (b) Percent composition.
                            180

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Cyclopoid copepods represented  only  a small fraction  (average 3 4%) of
total Crustacea (Fig. 7.34).  Cyclops bicuspidatus  thomasi was more
abundant than Mesocyclops edax  at  shallow stations  (<30 m deep)  but the
reverse was true at deep stations  (App.  F.4).                  '

Cladocera comprised an average  of  46.4%  of total Crustacea (Fig. 7.35).
Predominant species were Daphnia galeata mendotae and D. retrocurva,
which both represented an average  of about 17% of Crustacea at all sta-
tions.  These species were most prevalent at the shallowest stations
near the Straits of Mackinac  and off Frankfort,  Mich., and the Sturgeon
Bay Shipping Canal (Figs. 7.36  and 7.37).  Eubosmina  coregoni comprised
an average of 6.5% of the crustacean zooplankton and  was most abundant
off the Sturgeon Bay Shipping Canal  (Fig. 7.38).  Likewise, Holopedium
gibberum, comprising an average of 2.9%  of total Crustacea, was most
prevalent at Station 44 off of  Sturgeon  Bay.   Otherwise, this species
did not exhibit any discernible pattern  of distribution in northern Lake
Michigan (Fig. 7.39).  The remaining cladocerans represented considerably
less than 1% of total Crustacea at all stations.  Most species, such as
Leptodora kindtii, exhibited  greatest abundance  at  Station 44 (App. F.4).
Chydorus sphaericus was represented  by only a  few individuals at
Station 28 (App. F.4).

As would be expected, species composition of crustacean zooplankton in
northern Lake Michigan was nearly  identical to that observed in the
Straits region.  The larger number of Mysis relicta collected in northern
Lake Michigan is undoubtedly  due to  the  greater  depths of these waters.
It is well known that a large portion of the Afysis  population spends the
day off bottom in deep waters (Beeton 1960;  Robertson et al. 1968)  and
therefore are more readily obtainable by plankton nets.

By first inspection of these  zooplankton data, it appears that the biomass
of zooplankton is higher in the Straits  region than in northern Lake
Michigan.  However, there may be an  apparent but  false reduction of num-
bers of individuals per unit  volume  at deeper  stations simply because a
longer water column was sampled.   Consequently,  data  calculated in terms
of percent composition of various  species may  be  more useful for compara-
tive purposes than abundance  per unit volume.  An indication that this
supposition is true can be obtained  by comparing  two  stations of similar
depth.  Stations 03 in the Straits region and  26  in northern Lake Michigan
are 53 and 55 m deep, respectively.   Abundance of total crustacean zoo-
plankton in the Straits (1,883/m3) was slightly higher than in northern
Lake Michigan (1,591/m3).  In contrast,  biomass of  zooplankton was
considerably higher (6,491/m3)  at  a  station 60 m  deep in southern Lake
Michigan during September 1969  using identical methods (Gannon 1972a;.
Although these data are limited, they do suggest  that there may be
substantial differences in numbers of  zooplankters per unit volume  in
southern and northern Lake Michigan.

Although depth-adjusted volumes of zooplankton may be comparable in
northern Lake Michigan and the  Straits of Mackinac, some interesting dif-
                                    181

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                                                    	1- ^•T.inuiiiuyr
                                               800
Figure 7.34.  DISTRIBUTION AND ABUNDANCE OF CYCLOPOID
    COPEPODS IN NORTHERN LAKE MICHIGAN.

    (a) Numbers per m3.

    (b) Percent composition.
                             182

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                                                  00
                                                       \
                                      Jr	1	1	1	1
                                      0        4000
Figure 7.35.  DISTRIBUTION AND ABUNDANCE OF CLADOCERA IN
    NORTHERN LAKE MICHIGAN.

    (a) Numbers per m^.

    (b) Percent composition.
                           183

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                                XDflPHNIfl GflLEflTfl MENDOTflE

                                        0   '   '   60
                               DflPHNIfl GflLEflTfl MENOOTflE/M3
                                              2000
Figure 7.36.  DISTRIBUTION AND ABUNDANCE OF DAPHNIA GALEATA
    MENDOTAE IN NORTHERN LAKE MICHIGAN.

    (a) Numbers per m3.

    (b) Percent composition.
                             184

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                                   XDflPHNIfl  RFTROCURVfl

                                        o"1" """"lib
                                  DflPHNIfl RETROCURVfl/M3
                                                1500
Figure 7.37.   DISTRIBUTION A^TD ABUNDANCE OF DAPHNIA
    RETROCURVA IN NORTHERN LAKE MICHIGAN.

    (a) Numbers per m3.

    (b) Percent composition.
                             185

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                                   XEUBOSMINR  COREGONI

                                        6        15
                                  EUBOSMINfl COREGONI/H3
                                                 400
Figure 7.38.  DISTRIBUTION AND ABUOT>ANCE OF EUBOSMINA
    COREGONI IN NORTHERN LAKE MICHIGAN.

    (a) Numbers per m3.

    (b) Percent composition.
                             186

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                                   XHOLOPEDIUM GIBBERUM
                                 HOLOPEDIUM GIBBERUM/M-
Figure 7.39.   DISTRIBUTION AND ABUNDANCE OF HOLOPEDTUM
    GIBBERUM  IN NORTHERN LAKE MICHIGAN.

    (a) Numbers per m3.

    (b) Percent composition.
                             187

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ferences in relative abundance did exist in September 1973.  The percent
composition of calanoid copepods was slightly higher in northern Lake
Michigan, predominantly due to greater abundance of Diaptomas sicilis.
The relative abundance of cladocerans was substantially higher in the
Straits region and in the most southerly tier of stations in Lake Michigan
than at stations in between.  This pattern of distribution was due mostly
to Daphnia retrocurva, Eubosmina coregoni, and Holopedium gibberum.

It is apparent that water in the Straits of Mackinac is sufficiently
modified by the proximity of shallow, nearshore waters and by mixing with
Lake Huron water to have different physicochemical and biological
characteristics than water in northern Lake Michigan.  Further data are
needed to better understand the community structure of zooplankton in
northern Lake Michigan as related to differences in water quality between
this region and the Straits of Mackinac as well as the southern portion
of Lake Michigan.
 7.4  SUMMARY

 Crustacean zooplankton were investigated in the Straits of Mackinac
 region  to:  1) provide benchmark data on species composition, distribu-
 tion, and abundance; 2) analyze zooplankton community structure in rela-
 tion to the interactions of Lake Michigan and Lake Huron waters; and 3)
 contrast and compare zooplankton community structure between northern
 Lake Michigan and the Straits of Mackinac.  Fifty stations were set up
 along eight transects.  Samples were collected on three cruises in
 August, September, and October 1973 using vertical tows of a 0.5-m diam-
 eter cylinder-cone net (250 y mesh size) fitted with a Nansen throttling
 mechanism.

 The  community of crustacean zooplankton in the Straits of Mackinac was
 comprised of 29 species.  Twenty-three species of Cladocera and Copepoda
 were characteristic of limnetic waters, while six cladocerans were ben-
 thic and littoral forms that sporadically appear in the plankton.  Abun-
 dance of total Crustacea at various stations during the study period
 ranged from near 1,000 individuals per m3 to almost 28,000 per m3.

 Distinct differences in community structure of zooplankton were readily
 apparent within the Straits of Mackinac.  Although species composition
was  nearly identical at every station, prominent and consistent patterns
were  evident in the relative proportions of species to one another in
 specific sub-regions within the Straits.  The relative abundance of zoo-
plankters towards Lake Michigan (west of the Straits of Mackinac) and in
 the  South Channel (south of Bois Blanc Island) shared many resemblances.
This region was characterized by a distinct preponderance of cladocerans,
especially Daphnia retrocurva and D. galeata mendotae.  Other cladocerans,
such as Holopedium gibberumf Eubosmina coregoni, Leptodora kindtii, and
Polyphemus pediculus were also most prevalent in this region.  The cala-
                                   188

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noid copepods Epischura lacustris, Diaptomus oregonensis, and D. minutus
generally were characteristic of  the  region.   In contrast, calanoid
copepods as a group were relatively most abundant in waters toward Lake
Huron, i.e., north and east of Bois Blanc  Island, mainly due to copepo-
dids of Diaptomus spp., Diaptomus sicilis  adults, Limnocalanus macrurus,
and Senecella calanoides.  Cyclopoid  copepods, predominately Cyclops
bicuspidatus thomasi, did not show any  distinctive trends but appeared
somewhat more prevalent toward Lake Huron.  Cladocerans, such as Bosmina
longirostris, were mainly characteristic of inshore stations in this
region.

Regions of homogeneity of  zooplankton community  structure, as determined
by principal component analysis,  were remarkably similar to water masses
identified by cluster analysis  (Sec.  V).   Cladocerans were relatively
most  abundant in the slightly more  eutrophic waters toward Lake Michigan
and in the  South Channel, while  calanoid  copepods prevailed in the
slightly more oligotrophic waters toward  Lake  Huron.  The community struc-
ture  of crustacean  zooplankton  appears  to be a sensitive indicator of
water quality in the Straits  of  Mackinac  where nutrient conditions are
only  subtly different.
 7.5 LITERATURE CITED

 Beeton, A. M.  1960.   The  vertical migration of Mysis relicta in Lakes
     Huron and Michigan.   J.  Fish. Res. Board  Canada 17: 517-539.

 Brooks, J. L.  1957.   The  systematics of North American Daphnia.  Mem.
     Connecticut Acad. Arts and Sci., Vol.  13. 180 p.

 	    	.  1959.  Cladocera,  p. 587-656.  In W. T. Edmondson (ed.),
     Fresh-water biology,  2nd   ed.   New York: Wiley.

Davis, C. C.  1966.   Plankton  studies  in  the largest Great Lakes of the
     world, with special reference  to  the St. Lawrence Great Lakes of
     North America.   Univ.  Michigan, Great Lakes Res. Div., Pub. 14: 1-36.

Deevey, E. S., Jr. and  G.  B. Deevey.   1971.  The American species of
     Eubosmina Seligo (Crustacea, Cladocera).  Limnol. Oceanogr. 16:
     201-218.

Gannon, J. E.  1969.   Great Lakes plankton investigations: a bibliography.
     Univ. Wisconsin-Milwaukee,  Center for Great Lakes Stud., Spec. Rept.
     No. 7.  65 p.

             1971   Two counting cells for the enumeration of zooplankton
	micTo~-Crustacea.   Trans.  Amer.  Microsc. Soc. 90: 486-490.
                                    189

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             1972a.  A contribution to the ecology of zooplankton
     Crustacea of Lake Michigan and Green Bay.  Unpubl. Ph.D. Diss.,
     Univ. Wisconsin.  257 p.

	.  1972b.  Effects of eutrophication and fish predation on
     recent changes in zooplankton Crustacea species composition in Lake
     Michigan.  Trans. Amer. Microsc. Soc. 91: 82-84.

	.  1974a.  The ecology of Lake Michigan zooplankton—A review
     with special emphasis on the Calumet Area, Appendix B, 56 p.  In
     R. H. Snow, Water pollution investigation:  Calumet Area of Lake
     Michigan.  U.S. Environmental Protection Agency Rep. No. 905/9-74-
     011-B, Vol. 2.

	.  1974b.  The crustacean zooplankton of Green Bay, Lake
     Michigan.  Proc. 17th Conf. Great Lakes Res., p. 28-51.  Internat.
     Assoc. Great Lakes Res.

	.  1975.  Horizontal distribution of crustacean zooplankton
     along a cross-lake transect in Lake Michigan.  J. Great Lakes Res. 1:
     79-91.

	 and S. A. Gannon.  1975.  Observations on the narcotization of
     crustacean1 zooplankton.  Crustaceana 28: 220-224.

Patalas, K.  1972.  Crustacean plankton and the eutrophication of the
     St. Lawrence Great Lakes.  J. Fish. Res. Board Canada 29: 1451-1462.

Robertson, A., C. F. Powers, and R. F. Anderson.  1968.  Direct observa-
     tions on Mysis relicta from a submarine.  Limnol. Oceanogr. 13:
     700-702.

Watson, N. H. F. and G. F. Carpenter.  1974.  Seasonal abundance of
     crustacean zooplankton and net plankton biomass of Lakes Huron,
     Erie, and Ontario.  J. Fish. Res. Board Canada 31: 309-317.

Welch, P. S.  1948.  Limnological methods.  Philadelphia: Blakiston.
     381 p.

Wilson, M. S.  1959-  Calanoida, p. 738-794.  In W. T. Edmondson (ed.),
     Fresh-water biology, 2nd ed.  New York: Wiley.

Yeatman,  H.  C.   1959.  Cyclopoida, p. 795-814.  in W. T. Edmondson, (ed.),
     Fresh-water biology, 2nd ed.  New York: Wiley.
                                   190

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                                SECTION VIII

              COMPARISON OF PHYTOPLANKTON AND NUTRIENTS  IN
           NORTHERN LAKE MICHIGAN  AND THE STRAITS  OF  MACKINAC
In September, after the regular  sampling survey of  the  study area, 18
stations were sampled in northern Lake  Michigan (Fig. 8.1).  At these
stations, sampling procedures  and methodology were  the  same as those that
were used on the three cruises of the Straits survey area.  Comparing
data obtained in September enabled us to conclude that  certain biological
conditions were unique to the  Straits area.   In addition, data for
September provide the basis  for  verification of environmental conditions
in Lake Michigan at stations removed from the influence of mixing between
Lake Michigan and Lake Huron waters.  It is  obvious from the data pre-
sented below that the Straits  survey area did not include stations with
characteristic Lake Michigan conditions,  i.e. water samples collected at
Stations 01-06, the westernmost  transect,  contained a mixture of Lake
Michigan and Lake Huron or Lake  Superior water.
8.1 PHYSICAL-CHEMICAL CONDITIONS

Mixing apparently occurred over a broad  geographic area west of the
Straits and was not uniform in one area  for  the three cruises.  For exam-
ple, the average specific conductance at Stations 01-06 ranged from 235
to 250 ymho cm"1 on the  three cruises (Table 3.1).  These data also there-
fore indicate that some  fraction of Lake Huron water was present at this
westernmost transect on  all of the cruises.

In September the water flowing out of Lake Michigan was cooled in the
Straits of Mackinac due  to the mixing with colder waters from Lake Huron.
Epilimnetic water temperatures in the main part of Lake Michigan averaged
about 17°C (Table 8.1),  but in the Straits area decreased to 15°C at
Stations LM 52-54 (Table 8.1) and to temperatures as low as 14°C as the
water flowed eastward to the south of Bois Blanc Island (Table 3.1,
App. C.10 and C.ll).  Evidence for mixing of colder Lake Huron water with
Lake Michigan water can  also be found for data on specific conductance,
pH, silica and nitrate;  there is no question therefore that mixing occurred
at least in the area extending east from Stations LM 52-54 in Lake Michigan
(Fig. 8.1) to at least Stations 24-26 in Lake Huron (Fig. 1.1).

In Lake Michigan, specific conductance at Stations LM 20-22, LM 23-25 and
LM 45-47 that are outside the area influenced by mixing in the Straits of


                                    191

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                                                                    STRAITS SURVEY
                                                                    AREA-
Figure 8.1.  LOCATION OF NORTHERN LAKE MICHIGAN STATIONS SAMPLED 20-23 SEPTEMBER 1973
    IMMEDIATELY AFTER THE SAMPLING OF THE STRAITS SURVEY AREA.  In the text stations
    shown in Figure 8.1 are designated LM to distinguish them from the stations in the
    Straits survey area shown in Figure 1.1.

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Table 8.1.  AVERAGES OF ENVIRONMENTAL PARAMETERS  OF EPILIMNETIC WATERS  IN
    LAKE MICHIGAN, SEPTEMBER 1973.   Data  are mean + one  standard  deviation.

Stations1   Temperature   Specific conductance        pH         Secchi disc
                (C)          (ItrVho  cm'1)                          (m)
 LM20-222   16.8+0.93      2.676+0.038       8.578+0.029   5.00+0.50

 LM23-253   17.4 + 0.22      2.673 + 0.064       8.587 + 0.081   5.00 + 0.50

 1^45-47^   16.6+0.54      2.668+0.056       8.625+0.051   4.83+0.35

 LM52-545   15.0 + 0.45      2.489 + 0.020       8.539 + 0.055   5.17 + 0.58

    1-66    15.4 + 0.87      2.354 + 0.127       8.514 + 0.063   3.86 + 0.79
Chlorophyll a
(mg m~3)
Silica
(mg SiO;,!-1)
Nitrate
(ugN I'1)
Total
phosphorus
(pgP I"1)
 LM20-222   1.50+0.22      0.343+0.082        74.0+  42.0   5.62+0.66

 LM23-253   1.29+0.37      0.222+0.046        77.0+  19.0   5.10+1.21

 IM45-47*   1.44 + 0.35      0.217 + 0.075        50.0+  33.0   5.07 + 0.67

 LM52-545   1.45 + 0.15      0.895 + 0.109       161   + 101     5.79 + 0.58

    1-66    1.73+0.70      0.951+0.162       212   +  69     4.76+0.90

Stations excepting 1-6 were sampled only in September.  See Fig. 8.1.
2Average of 12 samples, depths ranging from 0-20 m.
3Average of 15 samples, depths ranging from 0-30 m.
^Average of 15 samples, depths ranging from 0-30 m.
5Average of 11 samples, depths ranging from 0-20 m.
6Data from Table 3.1.
                                     193

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Mackinac averaged about 267 ymho cm"1 (Table 8.1).  Lake Michigan waters
were diluted to the extent that at stations LM 52-54 in Lake Michigan
specific conductance averaged 249 and at Stations 01-06 in the Straits
area averaged 235 ymho cm"* (Table 3.1).  It can be seen from data in
Table 3.1 that dilution of Lake Michigan water was greater in September
than during the other two months since specific conductance was least
during this month.

In  the Straits area, the pH of Lake Michigan water was reduced, but only
slightly, as the result of mixing with waters from Lake Huron or Lake
Superior.  In Lake Michigan at Stations LM 45-47, pH averaged greater
than 8.6 which was reduced to 8.54 at Stations LM 52-54 (Table 8.1) and
to  8.51 and 8.50 at Stations 01-06 and 13-23 in the Straits area
(Table 3.1).  These differences in pH were probably real, as the measure-
ments for pH were very precise.

South of Beaver Island, the epilimnetic waters of Lake Michigan were
nearly silica-depleted, with average concentrations being as low as 0.2 mg
Si02 liter"1 (Table 8.1).  In the Straits area, average concentrations
ranged from 0.9-1.0 mg Si02 liter"1 for Stations LM 52-54 in Lake Michigan
and Stations 13-23 south of Bois Blanc Island (Table 3.1).  It is obvious
in  comparing epilimnetic averages for the survey area (Table 3.1) that
the water needed to enrich the silica concentrations in the Straits area
was not epilimnetic water from Lake Huron, so the source of silica must
be  attributable to sources in the thermocline or hypolimnion.

The waters of Lake Michigan also were depleted in nitrate nitrogen rela-
tive to waters in the Straits survey area.  In Lake Michigan south of
Beaver Island, nitrate concentrations averaged less than 80 yg N03 liter"1
and as low as 50 yg NOs liter"1 at Stations LM 45-47 (Table 8.1), whereas
in  the Straits survey area concentrations averaged 210 at Stations 01-06
and 240 at Stations 13-23 (Table 3.1).  At Stations LM 52-54, located
west of Stations 01-06, nitrate concentrations averaged 160 yg N03 liter"1.

The large standard deviations of the mean for Stations LM 52-54 and
Stations 01-06 compared to other means for silica and nitrate provide
additional evidence that mixing occurred west of the Straits of Mackinac.
The enrichment of waters with nitrate in the Straits, as was the case with
silica, has to be attributed to mixing with metalimnetic or hypolimnetic
waters.  Concentrations of nitrate and silica were greater at Stations 28-31
and Stations 07-10 (Table 3.1), where there was evidence of upwelling,
than were found at stations characterized by epilimnetic waters.

Total phosphorus concentrations in the Straits survey area seemed to be
affected least by the mixing of Lake Huron and Lake Michigan waters.
Since Lake Michigan concentrations (Table 8.1) were larger than those for
Lake Huron (Stations 24-31 and 40-45, Table 3.1), the result expected from
mixing would be lower concentrations in the Straits survey area than in
Lake Michigan.   A slightly lower concentration was found at Stations 01-06,
but the concentration at Stations LM 52-54 averaged greater than the Lake
Michigan stations.  Since the variance in the averages was large, these
differences in the averages may not be significant.  The data do suggest
that there may be an enrichment of phosphorus in the Straits area; if such

                                    194

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an enrichment process existed,  it might be attributable to biological
factors or possibly  to morphometric effects.

In September, Secchi disc  transparency seemed to be greater in Lake
Michigan (Table 8.1) than  in the Straits area at Stations  01-06 and Sta-
tions 13-23 (Table 3.1); however, the differences were small.   In Lake
Huron, Secchi disc transparency was obviously greater than in  Lake
Michigan.  These data and  the data for chlorophyll suggest that standing
crops in the Straits area  were  greater than either in Lake Michigan or
Lake Huron.  These differences, if real, were small since  average chloro-
phyll concentrations ranged  from 1.21 to 1.78 mg chlorophyll a liter~1
(Tables 3.1 and 8.1).
8.2 PHYTOPLANKTON

Data on the distribution of  phytoplankton for the  three  cruises have been
summarized in relation  to temperature-specific conductance regions and in
relation to results of  ordination analysis.   Other data  are presented in
Section VI, summarizing abundance and distribution of  the 289 phytoplank-
ton species collected as part of the study.

It is obvious that the  phytoplankton community associated with Lake
Michigan water in August and September (Tables 8.2 and 8.3) was primarily
green and blue-green algae.   In these two months,  the  communities unique
to Lake Michigan waters did  not contain diatoms due to the effects of
silica limitation.  Stations 40-48 were not  sampled in August, so the
community associated with regions typical of Lake  Huron were not sampled;
however, one station, 25, with a community of three diatoms and one
cryptomonad, was identified  from ordination  analysis.  Cyclotella comta
and C. operculata were  the two diatoms in the community identified in
Lake Huron samples from September.

Hypolimnetic samples from August and September were characterized with
ordination analysis as  diatom communities.   The August community consisted
of Cyclotella ocellata  and C.  stelligera,  and C. ocellata was also pres-
ent in the September community with Shizosolenia eriensis replacing
C. stelligera.  These hypolimnetic communities were also identified for
both months from cold regions along the northern shore, which is evidence
of upwelling (Tables 8.2 and 8.3).

In October, diatoms as  well  as blue-green and green algae were identified
in the phytoplankton community found in the  waters  of  Lake Michigan
(Table 8.4).  Water flowing  from the St.  Marys River was characterized
by a community in which Asterionella fornosa was dominant while the com-
munity in Lake Huron was primarily diatoms and cryptomonads.  As is
September, the hypolimnetic  community consisted of  C. ocellata and R.
eriensis.

The influence of water  transport from Lake Michigan and mixing of Lake
Michigan and Lake Huron water  in the Straits area on the distribution and
abundance of phytoplankton can be  inferred from data collected in

                                    195

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Table  8.2.   SUMMARY  OF  RELATIONSHIPS  BETWEEN T-C  PATTERNS  AND PHYTO-
                PLANKTON COMMUNITY  PATTERNS  OF  AUGUST SAMPLES.
Region based
on T-C
Location and
description
Region based on
phytoplankton
communities
Associated
community
(Figs. 6.36b
and 6.38b)
Community
description
              Lake Michigan and south
              of Bols Blanc Island;
              5-m depth; warm; high
              conductivity

              Surface along northern
              shore;  cold; apparently
              upwelled

              Single  station (#25) in
              southeastern corner;
              low conductivity; water
              probably from Lake Huron
              but possibly from the
              St. Marys River

              Hypolimnion of
              northeastern stations
                                                                  Green and blue-green algae
Two diatoms:
Cyclotella ocellata and
Cyclotella stelligera

Three diatoms, one cryptomonad
Two diatoms:
Cyclotella .ocellata and
Cyclotella stelligera
Table  8.3.   SUMMARY  OF  RELATIONSHIPS BETWEEN T-C PATTERNS  AND PHYTO-
             PLANKTON COMMUNITY  PATTERNS OF  SEPTEMBER SAMPLES.
Region based
on T-C
Location and
description
Region based on
phytoplankton
communities
Associated
community
(Figs. 6.36b
and 6.38b)
Community
description
              Lake Michigan and south
              of Bois Blanc Island;
              5-m depth; warm, high
              conductivity

              Surface along northern
              shore; cold
      US      Southeastern section of
             survey area
             Mouth of St.  Marys River;
             5-m depth; warm, low
             conductivity

             Hypolimnion of
             northeastern  section
mainly green and blue-green
algae
Two diatoms:
Cyclotella ocellata  and
Rhizosolenia eriensis

Two diatoms:
Cyclotella coirtta and
Cyclotella operculata
Two diatoms:
Cyclotella ocellata  and
Rhizosolenia eriensis
                                           196

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  Table  8.4.  SUMMARY OF RELATIONSHIPS BETWEEN TEMPERATURE-CONDUCTIVI-
  TY PATTERNS AND  PHYTOPLANKTON COMMUNITY  PATTERNS OF OCTOBER SAMPLES.
   Region based
    on T-C
                           Associated
              Region based on  community
Location and       phytoplankton   (Figs. 6.36b
description        communities    and 6.38b)
             Lake Michigan and south
             of Bois Blanc Island;
             5-m depth; warm; high
             conductivity

             Mouth of St. Marys
             River; 5-m depth;
             warm; very low
             conductivity

             Eastern section of
             survey area; 5-m; cold,
             moderate conductivity
             Hypolimnion of
             northeastern section
 Community
description
                                     mixture of blue-greens,
                                     greens, and diatoms
                                     Asterionella formosa
                                     relatively abundant; very low
                                     total cell density
                                     Primarily diatoms and
                                     cryptomonads ;  very low
                                     densities of greens and
                                     blue-greens

                                     Two diatoms:
                                     Cyclotella ocellata and
                                     Rhizosolenia eriensis
 September.  The  distribution  and abundance  of nine species were investi-
 gated from samples collected  in the Straits survey area plus  the stations
 sampled in Lake  Michigan  (Fig.  8.1).  Data  for the comparisons among
 these phytoplankton were  plotted as averages.  For the Straits survey
 area,  5-m samples  were averaged for the regions plotted; for  Lake Michigan
 (Fig.  8.1), samples from  0, 5,  10 and 20 m  were averaged for  each station
 since there was  no evidence of  thermal stratification.

 Two  species of blue-green algae were found  in fairly uniform  abundances
 at all stations  sampled in Lake Michigan.   Both species, Anacystis incerta
 and  A. thermalis,  seemed  to be  transported  through the Straits south of
 Bois Blanc Island  into Lake Huron (Figs. 8.2 and 8.3), a pattern identi-
 fied previously  in the Straits  survey area  (Table 8.3, Fig. 6.34).  These
 species were not abundant outside of region A (Fig. 6.34), indicating
 that transport was the main mechanism that  could be used to explain the
 distribution.  None of the remaining seven  species had distributions of
 this type.

 Five species of  diatoms were  found in the Straits survey area and at sta-
 tions  LM 52-54 in  Lake Michigan.  In general,  these species were found in
 only limited abundance at other stations in Lake Michigan, and therefore
 seemed to be favored by conditions in the Straits area or in  the area
where  waters from  the two lakes mixed.  Three  of the species,  Fragilaria
 crotonensis, Cyclotella stelligera and C. comta, seemed to be  equally
 abundant at all  stations  including those in Lake Michigan, Lake  Huron and
 at the mouth of  the St. Marys River (Figs.  8-4-8.6), although  C.  comta
and  F.  crotonensis seemed to be more abundant  in Lake Huron.   Reasons for
 the  ubiquitous distribution are not apparent.   The other two  species of
diatoms,  Cyclotella ndchiganiana and Asterionella formosa, were  most
                                      197

-------
                                  RNRCYSTIS INCERTR CELLS/ML

                                            i	1	1	1
                                           0          6000
 Figure 8.2.   DISTRIBUTION  OF ANACYSTIS INCERTA.
                                 RNflCYSTIS THERMRLIS CELLS/ML
                                              ^	\-
                                           0       300
Figure 8.3.   DISTRIBUTION OF ANACYSTIS THERMALIS.
                                198

-------
                               FRflGILRRIR CROTONENSIS CELLS/ML

                                            i	1	1	1
                                           0        150
Figure 8.4.  DISTRIBUTION OF FRAGILARIA CROTONENSIS.
                               CYCLOTELLfl STELLIGERfl CELLS/ML
                                          0        150
Figure 8.5.  DISTRIBUTION OF CYCLOTELLA STELLIGERA.



                               199

-------
                                      CYCLOTELLF) COMTfl  CELLS/ML
                                                          80
     Figure 8.6.  DISTRIBUTION OF CYCLOTELLA COMTA.
 abundant  in Lake Michigan and south and east of Bois Blanc Island
 (Figs.  8.7 and 8.8) or in region M (Table 8.3).

 Finally,  the distribution of two species of Cyclotella, C. ocellata and
 C. operculata (Figs. 8.9 and 8.10), seemed to be restricted mainly to the
 stations  east of Bois Blanc Island.  C. ocellata was characteristic of the
 hypolimnetic community (Table 8.3)—the fact that this species was not
 found west of the Straits in relatively large abundances indicates either
 that hypolimnetic water was not transported to the west or that this
 species did not thrive in the mixed water.
8.3 SUMMARY

Many of the results obtained as part of the study of the Straits area and
northern Lake Michigan can be explained as being due either to mixing of
water transported from Lake Michigan into Lake Huron or as the result of
transport of Lake Huron water westward into Lake Michigan.

The general pattern of surface water transport from Lake Michigan, as
delineated by our results, was from Lake Michigan through the Straits of
Mackinac and then south of Bois Blanc Island to Lake Huron.  This trans-
port appeared to be similar when the water was stratified thermally in
August, as well as in October when there was no thermal stratification
                                    200

-------
                               CTCLOTELLfl  MICHIGflNIflNfl CELLS/ML
                                            0        80
 Figure 8.7.  DISTRIBUTION OF CYCLOTELLA MICHIGANIANA.
                                flSTERIONELLfl  FORMOSR CELLS/ML
                                           0        80
Figure 8.8.  DISTRIBUTION OF ASTERIONELLA FORMOSA.







                               201

-------

                                CTCLOTELLfl OCELLflTfl CELLS/ML
                                          0       200
Figure 8.9.  DISTRIBUTION OF CYCLOTELLA OCELLATA.
                               CTCLOTELLR  OPERCULflTfi CELLS/ML
                                           i	1	1-
                                           0       15
Figure 8.10.  DISTRIBUTION OF CYCLOTELLA OPERCULATA.






                               202

-------
south of Bois Blanc Island.

Transport of Lake Huron water to Lake Michigan when the lakes were not
stratified thermally appeared to be complex, being controlled by the
oscillatory flow between the two lakes.  Under thermally stratified condi-
tions, Lake Huron water flowed west under  the epilimnion, eventually being
entrained and mixed with Lake Michigan water west of the Straits.  Based
on morphometry, the subsurface flow was north of Bois Blanc Island along
the northeast side of Mackinac Island, then south between Mackinac Island
and Rabbit's Back Peak and finally west through the Straits into Lake
Michigan; water can be transported in this pattern in a well-defined chan-
nel at depths of 40 m.
                                    203

-------
    APPENDIX A.  Physical and chemical data collected in the vicinity of  the  Straits  of Mackinac,  1973
Appendix A.I  Cruise 1, August 1973
STA

1
1
1
2
2
2
2
2
3
3
3
3
3
3
3
4
0 »
° 4
4
4
5
5
5
6
6
6
7
7
7
8
8
8
8
8
9
9
9
9
9
9
9
DEP
1
0
5
10
0
5
10
15
20
0
c
10
15
20
25
30
0
5
10
15
20
C
5
10
0
5
10
0
5
10
0
5
10
15
20
0
5
10
15
20
25
30
SAMP

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
39
40
41
42
43
44
45
SEC
m
4.5
4.5
4.5
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.1
5. 1
5.1
5. 1
5.1
5.0
5.0
5.0
5.5
5.5
5.5
6.2
6.2
6.2
6.0
6.0
6.0
6.0
6.0
5.9
r>.9
5.9
5.9
5.9
5.9
5.9
TEMP
°C
21.8
21.8
21.5
21.1
21.1
21. 1
21.1
18.0
21.0
21.0
21.0
21.0
15.8
12.0
10.8
21.0
21.0
21.0
20.0
13.0
21.0
21.0
21.0
21 .4
21.4
20.0
17.0
17.0
15.0
20.2
20.2
16.0
12.2
11.0
21.0
20.2
19.5
1 3.5
9.0
7.5
7. 5
pn

8.70
8.68
8.68
8.62
8.60
8.60
9.52
8.52
8.67
8.68
8.66
8.66
8.53
8.42
8.14
8.69
8.69
8.67
8.62
8.32
8.70
8.69
8.58
8.70
8.71
8.70
8.58
8.52
8.43
8.66
8.66
8.40
8.11
8.10
8.67
8.67
8.68
8.52
3.22
8.02
7.96
COND
~*mho/cni
2.29
2.55
2.53
2.50
2.55
2.55
2.55
2.55
2.50
2.50
2.50
2.50
2.40
2.35
2.16
2.52
2.49
2.51
2.46
2.24
2.50
2.50
2.43
2.50
2.50
2.49
2.32
2.27
2. 19
2. «4
2.45
2. 07
2.05
2.05
2.47
2."^
2.Uu

2.14
2.2C
2.16
CHL
mg/n:
1.63
1.60
1.64
1.55
1.52
1.49
1.55
1.52
1.58
1.74
1.56
1.74
1.54
1.31
1.46
1.57
1.42
1.30
1.39
1.60
1.29
1.34
1.56
1.41
1.32
1.39
1.31
1.35
1.40
1.18
1.22
1.87
1.60
1.73
1.10
1.29
1.41
1.79
l.tiO
.97
.89
PHAE
fraction
.09
.11
.09
.08
.11
.11
. 13
.14
.03
.10
.07
.07
.19
.18
.24
.06
.13
.15
.18
.15
.10
.11
.18
.13
.15
.15
.11
. 11
.10
.15
.20
.11
.21
.13
. 10
.10
. 11
. 13
. 18
.27
.35
SI02
«gSi02/l
. 44
.45
.45
.44
.65
.44
.45
.50
.43
.43
.43
.44
.80
1.14
1.42
.49
.48
.50
.60
1.22
.52
.53
.76
.58
.59
.60
.84
.91
.99
.63
.63
1. 14
1.31
1.39
.69
.59
.64
.97
1.38
1.71
1.79
H03
«gN/n3
117.4
125.9
125.9
145.9
151.6
157.3
157.3
147.3
1H4.5
145.9
138.8
158.7
200.1
224.3
265.7
146.2
132.7
135.4
150.3
246.4
134.1
131.3
171.9
130.0
127.3
130.0
165.9
197.6
221.6
144.3
146.8
246.9
278.5
289.9
161.9
145.4
149.2
218.8
279.6
298.5
321.3
TP04
•gP/«*
6.17
5.10
5.86
6.57
5.07
4.55
4.46
5.05
4.26
4.61
3.83
5.40
5.30
4.57
3.39
4.47
5.60
4.45
6.11
3.69
3.77
4.16
4.28
3.14
3.46
3.48
3.68
6.35
4.61
2.93
2.89
3.88
5.55
4.52
2.92
2.92
3.49

3.61
4.02
4.07
SP04
•9P/»3
2.49
3.52
5.24
2.69
2.67
2.69
2.65
3.65
2. 14
2.36
2.97
2.61
2.20
2.98
1.86
4.49
2.42
2.16
3.33
5.23
3.38
3.53
3.16
1.95
1.98
1.74
2.03
2.44
1.70
1.67
1.60
1.27
1.63
1.68
1.90
1.40
1.77
2.22
2.04
2.11
2.45
S04
•gSO4/l
15.94
16.71
17.75
17.81
18.29
15.80
17.97
17.18
16.11
16.02
16.22
15.43
15.20
14.69
12.91
16.21
16.69
16.89
15.96
13.19
16.35
16.55
15. t9
16.52
16.72
16.35
14.85
13.91
13.41
15.86
14.79
12.30
12.07
11.99
15.44
15.49
15.83
12.92
12.13
11.90
11.95
Cl
•gCl/1
7.7.9
7.71
7.78
7,59
7.66
6.78
7 ..6.8
7.68
7.48
7.36
7.51
6,78
6.97
6.58
S.64
7.40
7.51
7 .51
7.23
5,83
7,»5
7.41
6.80
7. ,32
7.43
7.38
6.39
6.12
5.78
7,17
7.13
5.43
5.23
5.19
7.30
7.25
7.09
5.62
5.35
5.23
5.22

-------
App. A.I cont.
STi DIP SAMP
M
10
10
10
10
10
11
11
11
11
11
11
12
12
12
13
13
13
14
0 1"
S 14
14
m
15
15
15
15
15
16
16
16
17
17
17
18
18
0
5
10
15
20
0
5
10
15
20
25
0
c
10
0
ft
10
0
K
1 0
15
20
0
5
1C
15
20
0
5
15
0
4
8
C
c
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
SEC
m





6.5
6.5
6.5
6.5
6.5
6.5
6.0
6.0
6.0
5.4
5.4
5.4.
6.0
6.0
6.0
6.0
6.0
5.8
5.8
5.8
.5.8
5.8
4.7
4.7
4.7
5.2
5.2
5.2
6.C
6.0
TEKP
°C
21.1
19.5
19.4
18.0
8.0
21.5
20.6
18.0
13.2
10.8
10.0
21.0
20.6
19.2
22.0
22.0
22.0
21.5
21.5
21.5
20.0
12.0
21.5
21.5
20.0
17.5
12.0
21.5
21.5
19.0
21.8
21.8
20.9
22. r-
21.8
PH
8.62
8.65
8.64
8.59
8.26
8.70
8.70
8.60
8.43
8.24
8. 10
8.67
8.68
8.67
8.65
8.65
8.64
8.64
8.66
8.65
8.59
8.17
8.64
8.65
8.63
8.51
8.26
8.65
8.66
8.60
8.67
8.67
8.67
8.67
8.67
CCND
— * mho/cm
2.39
2.39
2.39
2.31
2.15
2.30
2.?0
2.31
2.07
2.10
2.06
2.36
2.3.8
2.37
2.46
2.46
2.46
2.45
2.46
2.47
2.43
2.24
2.46
2.46
2.45
2.40
2.25
2.U9
2.49
2.44
2.47
2.48
2.49
2.45
2.44
CHi
ag/rn3
.94
1.19
1.54
1.54
1.10
1.00
1.13
1.45
1.83
1.75
1.53
1.12
1.35
1.37
1.39
1.20
1.43
1.01
1.13
1.32
1.52
1.08
1.03
1.07
1.34
.99
1.41
1.28
1.25
1.38
.98
1.26
1.39
.88
1.04
PHAE
fraction
.19
.23
.06
.21
.25
.21
. 17
.18
.14
.06
.18
.12
.12
.15
.10
. 19
.15
.15
. 14
-.06
.21
.25
.16
.18
.23
.25
.24
.18
. 18
.12
.12
. 15
.23
.14
.21
5102
mgSi02/l
.74
.65
.64
.75
1.54
.61
.59
.67
1.02
1.34
1.48
.59
.58
.62
.56
.57
.49
.57
.57
.53
.62
1.21
.53
.54
.58
.76
1.15
.51
.51
.64
.55
.54
.57
.53
.53
N03
ngU/n*
169.3
156.6
157.8
176.8
279.4
162.8
155.1
170.3
237.4
276.6
288.0
146.9
144.0
149.2
192.7
148.0
177.3"
218.8
191.6
153.6
158.7
378.8
159.4
169.8
190.9
203.5
304.6
170.2
171.6
178.4
164.3
157.6
194.1
159.0
149.6
TPO4
«gP/«3
2.99
2.57
4.09
3.67
3.89
2.69
3.03
3.77
3.59
3.59
3.08
2.48
2.71
5.01
4.42
4.38
5.28
4.52
4.70
4.68
4.39
5.32
5.46
4.76
4.63
4.47
4.63
6.93
4.21
5.18
4.10
3.37
3.64
3.50
4.38
SP04
agP/n*
1.78
2.43
1.85
1.97
1.70
1.64
1.44
2.29
1.80
2.27
1.63
1.74
1.65
3.36
4.17

3.45
3.59
3.46
3.57
3.38
3.49
5.32
4.01
3.14
3.64
2.83
3.24
3.46
3.74
2.77
2.56
2.59
2.99
2.89
S04
»gS04/l
13.56
15.17
15.37
13.73
12.37
14.13
14.18
13.81
12.46
11.66
12.28
14.60
15.36
14.85
15.48
15.^5
16.15
15.50
15.70
15.47
15.24
13.18
15.61
15.55
13.32
15.01
12.65
15.96
16.16
15.29
15.76
15.97
14.82
15.97
15.77
Cl
•gci/i
6.54
6.98
7..02
6.10
5.35
6.64
6.64
6.60
5,79
5.4.0
5.»29
7.04
7.11
7,07
7.29
7.44
7.«t4
7.17
7.36
7.31
6,37
6»07
7.4.2
7.34
6.06
6.85
5.35
7.48
7.33
7.10
7.32
7.35
6.67
7.23
7.12

-------
App. A.I cont.
;TA

19
19
19
19
19
20
20
20
21
21
21
22
22
22
22
23
23
23
24
24
24
24
25
25
25
25
25
26
26
26
26
26
26
26
27
27
27
27
27
27
27
27
27
27
DEP
M
0
5
10
15
20
0
5
10
0
c
10
0
5
10
15
0
C
10
0
c
10
15
0
5
10
15
25
0
5
10
15
20
25
30
0
R
10
15
20
25
30
35
HO
49
SAMP

8U
35
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
1C3
105
104
106
107
108
109
110
111
112
113
114
115
H6
117
118
110
120
121
12'
123
124
125
126
127
SEC
tn
5.6
5.6
5.6
5.6
5.6
6.0
6.0
6.0
6. 1
6.1
6.1
5.3
5.3
5.3
5.3
5.7
5.7
5.7
7.6
7.6
7.6
7.6
8.2
8.2
3.2
8.2
8.2
8.6
8.fi
8.6
8.6
8.6
8.6
8.6
7.9
7.9
7.9
7.9
7. "
7.9
7.9
7.9
7.9
7.9
TEMP
°C
22.0
21.4
20.8
17.5
13.8
22.0
22.0
21.5
21.5
20.0
18. C
21.5
21.0
20.0
16.0
22.0
21.0
20.5
22,1
22.0
21.2
15.0
22.0
20.9
2.1.0
13.0
8.5
22.5
21. *
20.8
13.0
10.0
8.5
7.5
23.0
21.5
21.0
17.0
1 1.5
9.5
8.5
7.5
6.5
5.9
PH

8.67
8.68
8.65
8.56
8.31
8.66
8.65
8.66
8.67
8.68
8.57
8.68
8.69
8.65
8.45
8.67
8.58
8.66
8.67
8.68
8.69
8.50
8.65
8.65
8.64
8.42
7.95
3. 6H
a. 63
8.66
8. 41
8. 11
7.'J2
7.83
3.64
8.67
8.&7
8.43
8.21
8.05
7.93
7.89
7.81
7.82
COHD
-»mhc/cm
2.45
2.48
2.34
2.34
2.2*
2.40
2.40
2.44
2.41
2.39
2.23
2.44
2.44
2.32
2.20
2,50
2,47
2.46
2.22
2.14
2.01
2.17
2.00
1 .96
1.96
2.10
2.11
2.12
2.16
2.03
2.02
2.C'3
2.13
2.18
2.19
2.20
2.22
2.08
2.07
2.06
2.11
2.13
2.16
2.20
CHL
mg/m3
1. 11
1.46
1.60
1.54
1.51
1.15
.97
1. 19
1.00
1.13
1.58
1. 10
1.19
1,45
1.92
1.11
1.21
1.52
1.04
1.11
1.12
1.68
1.06
1.22
1.33
1.79
1.39
.98
.96
1.22
1.47
1.60
1.61
1.25
1.12
1.07
1.17
1.69
1.57
1.24
.°6
.77
.75
.64
PHA~
fraction
. 18
.22
.19
...19
.23
.18
.20
.20
.17
.17
. 19
. 19
.19
.21
.19
.21
. 17
.20
.14
.17
. 10
.19
.15
. 10
.16
.16
.24
.37
.16
. 21
.13
.15
. 19
.28
-.03
.09
.21
.18
.21
.26
.35
. 30
.41
.48
SI02
mgSi02/l
.53
.55
.60
.40
1.12
.58
.57
.55
.57
.55
.75
.54
.53
.62
.94
1.09
.96
.61
.69
.65
.65
.93
.89
.70
.67
.93
1.69
.73
.79
.64
.96
1.44
1.72
1.87
.65
.61
.60
.98
1.21
1.44
1 .54
1.59
1.64
1.78
N03
•gN/ffl3
156.4
164.5
180.8
184.9
186.3
176.8
175.5
162.0
191.3
161,5
196.8
146.9
163.4
169.6
230.5
108.6
152.6
181.5
212.4
212.4
227.4
249.4
305.9
214.0
253.7
255.0
341.4

204.7
212.9
249.9
303.3
334.8
354.0
200.4
187.1
207.0
234,8
285.1
309.0
319.6
326. 1
324.8
306.2
TP04
aqp/ns
4.23
3.73
4.54
3.68
4. 19
3.95
3.43
3.62
3.76
3.67
4.12
*
4.00
5.38
3.90
3.94
3.83
3.49
3.46
1.48
1.15
.87
2.31
.96
1.03
1.60
1.56
1.56
1.61
1.15
1.44
1.37
1.38
1.68
2.58
1.84
1.70
2.57
2.81
9.44
4.85
3. 16
3.04
2.30
3.91
SP04
•gp/«3
2.70
2.87
2.64
2.82
3.19
3.20
2.70
3.10
3.11
2.90
2.85
2.77
2.70
3.20
2.75
3.00
2.76
2.61

.68
.43
.60
.65
.65
.50
.16
.48
.72
.42

.06
.30
.45
3.50
1.06
1.16
1.06
1.25
1.74

2.07
1.90
1.31

son
•gS04/l
15.71
16.18
14.90
14.56
13.96
15.38
15.04
15.52
15.18
14.85
13.64
15.39
15.73
15.12
13.57
14.05
15.20
16.08
13.85
13.52
12.71
12.91
12.51
11.91
12.11
12.18
11.98
12.05
10.50
10.30
11.72
10.98
11.99
11.93
13.21
11.12
13.48
12.20
11.73
11.13
11.87
11.67
11.74
11.81
Cl
• gd/1
7.23
7.30
6.81
6.5.8
6.24
7..1P
6.99
7.17
6,. 98
6.68
6,07
7. Q.I
7,08
6.66
5«a«
6.17
6.96
7.10
6.19
5.90
5.54
5.76
5., 4 7
5.37
5.23
5*46
5.20
5.25
3.19
3^21
5.35
4,39
5. ,4 3.
S...3.7
6*27
6.5U
6,,47
5^62
5,. 33
<»»78
5.. 31
5.*3
5-51
5.70

-------
App. A.I cont.
STA DEP SAMP
H
28 0 128
28 5 129
28 10 130
28 15 131
28 20 132
28 25 133
28 30 134
28 40 135
28 50 136
28 60 137
29 0 138
29 5 139
29 10 140
29 15 141
29 20 142
29 25 143
29 30 144
29 40 145
29 50 146
29 60 147
30 0 148
30 5 149
30 10 150
30 IE 151
30 20 152
30 25 153
30 30 154
30 35 155
30 40 155
31 0 157
31 5 150
31 10 159
31 15 16C
31 ?0 161
32 0 162
32 5 163
32 10 164
32 20 165
33 0 166
33 5 167
33 10 169
33 TO 169
SEC
01
7. 1
7.1
7.1
7.1
7.1
7.1
7.1
7. 1
7.1
7. 1
7.9
7.9
7.9
7.9
7.9
7.9
7.9
7.9
7.9
7.9
8.5
8.5
8.5
8.5
8.5
8.5
8.5
8.5
8.5
6.5
3.5
3.5
Q.5
9.5
K.O
6.0
6 . C
'..I
6.2
6.2
6.2
6.2
TEKP
•c
21.3
21.2
20.0
16.8
1 1.5
9.5
8.5
7.5
6.4
5.9
21.5
21.0
2C.5
15.5
9.0
7.0
6.0
5.0
4.5
4.5
21.2
21.2
17.0
13.0
13.'4
8.0
7.8
7.0
6.5
2 v.1
1-3.0
13.6
11.*
1 1.0
1 9 . '•>
1^.1
1 5.0
10.4
20. 3
20.3
15.0
10.2
PH
8.62
8.64
8.64
8.49
8.25
8. 11
8.01
7.93
7.78
7.30
8.61
8.66
8.64
8.51
8.23
8.15
8.03
7.95
7.84
7.77
8.53
8.63
8. 54
8.37
8.22
8.06
3.02
8.00
7.97
8.57
8.55
8.43
8.25
8. 19
3 . f. -6
a. 66
fi.sri
8. 30
8.67
8.65
3.56
8.36
COND
2.22
2.25
2.20
2.06
2.05
2.06
2.10
2.15
2.22
2.22
2.26
2.23
2.24
2.11
2.02
2.09
2.13
2.17
2.1S
2.20
2.23
2.2 )
2.04
1 .9u
1.97
2. 10
2.m
1. 16
2.1 s
1 .99
2.0)
1 .94
1.96
2. CO
2.23
2 . 2 ')
2.0"
1.96
2.25
2.2 i
2.15
2.06
CHL
1.04
1.17
1.34
1.74
1.28
1.27
1.05
.66
.53
.45
1.45
1.31
1.37
1.87
1.26
1.02
.82
.57
.39
.33
.84
1.06
1.61
1. 42
1.23
1.00
.79
.83
.76
.82
1. 1.6
1.19
1.40
1. 39
.78
1.2b
1.78
1.61
1.2.9
1.47
1 . ">3
1.52
PHAE
fraction
.11
.04
.13
.14
.21
.20
.28
.41
.41
.53
.06
.13
. 15
.19
.20
.22
.33
.44
. 54
.69
.16
. 14
.09
.13
. 19
.31
. 40
.38
.42
.11
. 11
.13
. 16
.20
.13
.1 ?
.06
.18
.17
. 16
.10
.21
SIO2
mgSi.02/1
.66
.60
.62
.81

1.28
1.37
1.58
1.45
1.56
.66
.59
.61
.83
1.15
1.25
1.35
1.51
1.70
1.96
.69
.71
.86
1.09
1. 35
1.55
1.61
1.67
1.70
.97
.86
1.06
1.27
1.31
.36
.43
1.05
1.59
.74
.76
.85
1.40
NO3
agN/»3
183.5
194.1
228.6
229.9
280.2
292.1
321.3
323.9
326.5
333.1
190.3
177.1
194.2
225.8
285.2
323.4
315.5
329.9
331.2
364.2
205. 1
199.8
240.7
282.9
304.0
338.2
346. 1
332.9
344.7
211.9
244.9
275.2
301.5
313.4
161.3
188.4
259.7
316.8
186.8
185.3
228.0
313.7
TPO«
ngP/B3
2.70
3.98
2.60
2.93
3.64
2.95
2.22
1.28
2.59
2.65
2.29
2.79
1.70
2.71
2.62
1.53
1.39
1.43
2.86
2. 18
4.99
2.18
2.06
1.78
2.80
2.64
2.35
2.24
2.69
3.94
2.51
3.44
4.82
3.11
2.60
4.85
3.84
cj. 34
2.87
3.08
4.68
5.42
SPO4
ngP/m*
2.44
2.32
2.01
1.52
1.16
1.49
1.16
1.84
.48
.54
1.08
1.00
.57
1.90
.80
.67
.38
.69
1.23
.49
.69
1.14
.25
1.01
.63
.86
1 .36
1 .52
.89
2.70
1.40
1.19
1.50
2.34
2.45
1.62
1.49
1.74
2.27
1.44
2.28
1.59
S04
•gS04/l
13.36
14.11
13.10
11.47
10.68
11.50
11.44
11.53
11.62
11.85
13.55
14.07
13.58
12.50
11.27
11.79
12.17
11,53
11.91
10.83
13.11
12.76
11.83
11.18
11.42
11.80
10.72
11.83
11.77
12.15
11.51
11.01
11.39
11.19
12.89
12.24
10.43
11.39
12.21
12.74
11.66
11.31
C*.
•gci/l
6.64.
6.76
6. HI
5.73
4.54
5.J3
5. .13
5,21
5*32
5,32
£.55
6.48
6.37
5.51
4.88
5,00
5.01
5.09
5.25
4.29
6.Q4
5.94
5,34

5.00
5.. 15
4.45
5.38
5.27
5.27
5.12
4.60
4. .79
4.83
5.98
5.68
3.98
4.83
5.72
6.13
5.57
4.98

-------
     App. A.I cont.
NJ
O
oo
STA

34
34
34
34
34
34
34
34
35
35
35
35
35
35
35
35
36
36
36
36
36
36
36
36
36
36
37
37
37
37
37
37
37
37
37
37
111
111
111
111
111
111
112
112
112
DEP
M
0
5
10
15
20
25
30
35
0
5
10
15
20
25
30
35
0
5
10
15
20
25
30
•3 c
40
45
0
5
1C
15
20
25
3C
35
40
45
0
5
10
15
20
25
0
5
10
SAMP

170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
185
188
189
190
191
193
194
195
196
197
198
199
200
201
202
203
204
205
206
207
2C8
2,12
213
214
215
216
217
209
210
211
SEC
n
7-.0
7.0
7.0.
7.0
7.0
7.0
7.C
7.0
7.0
7.0
7.C
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.C
7.0
7.C
7.0
7.0
7.T
5.7
5.7
5.7
5.7
5.7
5.7
5.8
5.8
5*8
TEMP
•c
21.2
21.0
13.6
1 1.2
1C.O
9.0
8.0
7.5
20. 9
20.0
14.0
1 1.0
9.5
8.6
8.2
7.5
20.6
20.6
16.0
10.9
9.8
9.0
8.4
7.8
7.0
6.5
20.0
20.0
13.0
10.fi
9.8
9.0
8.1
7.5
7.0
6.5
21. n
20.5
20.0
13.0
9.9
8.4
22.0
21.9
2V.O
PH

8.66
8.67
8.54
8. 36
8.28
8. 22
8.21
8.15
8.64
8.62
8.41
8.34
8.25
8.16
8.08
8.07
8.63
8.67
8.60
8.39
8.25
8.15
8.08
8.01
7.99
7.93
8.65
8.65
8.61
8.34
8.13
8.05
7.94
7.89
7.84
7.82
8.65
8. £ 4
8. 6^
8.45
8.11
7.97
8.64
8.66
8.56
com
-*raho/cm
2.2S
2.15
2.15
2.05
2.10
2.12
2.14
2.00
2.36
2.30
2.04
2.03
2.10
2.10
2.16
2.20
2.33
2.35
2.25
2.06
2.10
2.12
2.16
2.16
2.16
2.21
2.26
2.32
2.25
2.06
2.12
2 ". 1 6
2.17
2.16
2.17
2.16
2.46
2.45
2.39
2.24
2.08
2.13
2.50
2.50
2.47
C!U
mg/a
.25
.08
.81
.58
.30
.38
.86
.81
1.14
1.39
1.81
1.61
1.54
1.05
.77
.75
1.22
1.20
1.72
1.65
1.35
1.17
.86
.74
.62
.64
1.24
1.33
1.31
1.51
1. 13
1.00
.70
.87
.76
.62
1. 12
1.36
1.37
1.71
1.52
1.34
1.20
1.35
.41
PHAE
fraction
.08
.07
. 14
.15
.21
. 17
.33
.34
.14
.11
.11
.11
.13
.25
.35
.37
.13
.12
.09
.16
.16
.25
.35
.36
.37
.42
.14
. 14
.13
.20
.19
.30
.43
.25
.41
.45
.21
.14
.15
.18
.18
.24
.07
.19
.19
SI02
agSi02/l
.69
. 68
.90
1.26
1.37
1.43
1.57
1.60
.66
.69
1.00
1.19
1.34
1.47
1.59
1.60
.70
.63
.76
1.09
1.32
1,49
1.51
1.47
1.55
1.82
.65
.63
.75
1.20
1.44
1.53
1.65
1.83
118J3
1.93
.53
.54
.62
.89
1.40
1.53
.50
.50
.52
N03
ng N/B a
187.9
18C.7
250.6
313.4
343.3
346.1
354.6
364.4
194.4
187.2
271.4
309.8
335.5
349.6
353.8
355.1
162.5
163.8
198.9
281.4
344.9
327.3
334.0
335.3
335.3
342.0
187.8
174.2
201.2
289.1
321.5
328.2
337.7
353.8
355.2
351.1
132.0
141.4
136.4
207.6
274.9
294.8
122.1
144.7
135.7
TP04
BgP/»3
2.61
3.49
3.32
4.78
3.00
2.52
2.66
2.88
2.61
2.68
2.94
3.18
2.79
Z.07
4.70
1.95
2.33
2.13
2.01
2.39
2.01
1.98
2.15
3.00
2.62
2.45
2.28
3.09
2.17
2.59
2.62
2.26
2.09
2.64
2.71
2.57
2.40
2.80
3.18

2.05
2.22
2.23
2.49
2.59
SP04
ngP/B*
1.69
1.99
1.86
1.65
2.57
1.57
1.83
1.52
1.92
1.80
1.51
1.39
1.32
2.07
1. 19
1.50
1.05
1.05
1.02
1.11
1.20
.61
.77
1.01
.89
1.74
1.74
1.45
1.14
1.82
.81
1.47
1.04
1.25
1. 18
1.16
1.30
1.C1
1.34
.99
1.19
.79
1.27
1.06
1.60
S04
•gSO4/l
12.86
13.83
12.01
9.90
11.16
11.11
11.78
11.14
14.15
13.95
12.28
11.05
11.14
11.08
11.17
11.26
12.81
14.07
12.98
11.17
11.11
11.77
11.57
11.79
11.88
11.96
14.15
13.82
13.90
12.29
11.96
11.90
11.84
11.93
11.87
11.95
15.24
15.46
14.42
13.38
11.78
11.86
14.15
15.07
12.76
Cl
BgCl/1
6.10
6.44
5.13
3.6.2
4.91
4.95
5.17
4.91
6,.4tt
6.44
5*47
5.03
5.03
4.99
5.14
5.18
6.22
6.75
6.19
5.11
5.18
5*1.1
4 .92
5- 07
5.15
5.22
fi.53
e'^42
6.23
5.12
5.12
5.04
5.08
5.16
5.19
5.23
6.95
7.14
6.77
5.95
5.09
4.94
6.80
7.10
5.79

-------
Appendix A. 2  Cruise 2, September 1973
STR t>EP SAMP
1
1 0 C47
1 5 448
1 10 1*49
2 0 442
2 5 443
2 10 444
2 15 445
2 20 41*6
3 0 435
3 5 436
3 10 437
3 15 l»38
3 20 i»39
3 25 440
3 30 1*41
4 0 430
4 5 431
4 10 432
4 1E 433
4 20 434
5 0 427
5 5 428
5 10 429
6 0 424
(• 5 425
6 10 426
7 0 328
7 5 330
7 10 329
8 0 331
8 5 332
8 10 333
6 15 334
8 20 315
8 25 336
o 0 3 40
9 5 ^41
9 10 342
9 15 343
9 20 34U
9 25 345
9 30 '46
9 35 347
9 40 348
ST.C
a
4.0
4.0
4.0
4.3
4.3
4.3
4.3
4.3







4.5
4.5
4.5
4.5
4.5
4.0
4.0
4.0
2.5
2.5
2.5
5.5
5.5
5.5
5.0
5.0
5.C
5.0
5.0
5.0
4.5
4. 5
4.5
4. 5
4.5
4. r;
4.5
4.5
4.5
TSWP
•C
16.8
16.8
16.8
15.9
15.9
15.9
15.9
15.9
15.8
15.8
15.8
15.8
15.6
14.0
11.5
14.8
14.8
14.5
13.0
11.5
14.4
14.4
14.2
14.4
14. 4
14."
11.2
11.4
7.2
1 3.2
12.5
10.4
7.0
6,5
6.4
1 1.0
1 1 . •'•:
•J.6
e.r
7.h
f>.<3
6.-6
6:6
<>.*
PH
8.65
8.63
8.57
8.58
8.53
8.55
S..54
8.55
8.49
8.52
8.54
8.53
8.55
8.49
8.29
8.46
8.49
8.48
8.47
8.28
8.43
8.44
8.45
8.42
8.45
8.U6
3.34
8. 19
8.18
8.48
8.48
8.39
8.27
8. 13
8.04
8.39
fi. U2
B.^6
8.18
8. 16
8. 13
8. 11
8.1*
3.06
CC1SD
-*Bho/CBi
2.46
2.47
2.48
2.18
2.45
2.19
2.45
2.46
2.46
2.23
2.46
2.46
2.39
2.36
2.22
2.40
2.15
2.15
2.31
2.17
2.40
2.14
2.37
2.21
2.42
2.41
2.23
2.20
2.06
2.35
2.33
2.32
2.19
2.15
2.1=)
2.27
2.30
2.19
2.17
2.21
2.22
2.21
2.23
2.21
CHL
mg/m3
1.57
1.69
1.60
1.58
1.54
1.57
1.53
1.46

1.47
1.42
1.49
1.47
1.38
1.19
1.74
1.64
.45
.40

1.74
1.51

4. 16
2.32
2.69
1.07
1.21
.92
1.21
1.67
1.76
'.14
.B6
.72
1.30
1.6i>
1.12
.93
.83
.77
.71
.62
.f 6
PH&B
fraction
.10
.03
.01
.06
.04
.09
.09
.11

.11
.17
.22
.13
.13
.19
.00
.19
.20
.17

.17
.21

.17
.27
.25
. 12
.06
.31
.1U
.06
.34
.15
.23
.34
.11
.04
.23
.26
.32
.34
.37
.42
.44
SIO2
mgSi02/l
.74
.73
.75
.87
.87
.87
.87
.87
.87
.84
.84
.84
.88
.84
1.35
1.09
1.08
1.08
1.15
1.34
1.16
1.17
1.20

1.17
1.13
.26
.24
.53
. 12
.16
.29
1.38
1.58
1.66
1.28
1.20
1.42
1.54
1.58
1.64
1.71
1.73
1.75
N03
«g«/"3
194.5
133.0
133.6
191.9
207.8
243.1
235.8
233.2
267.1
252.6
161.0
148.1
126.9
120.1
199.1
192.7
178.3
162.3
207.7
251.6
206.1
357.1
334.8

203.5
207.9
292.6
299.8
351.4
254.0
255.4
278.0
288.4
348.7
366.8
277.5
260.8
313.6
336. 1
336.0
351.0
360.0
356.9
359.8
TPO4
•gp/m'
4.61
4.27
4.16
4.90
5.09
5.20
3.95
3.92
5.13
5.14
4.60
4.26
5.90
4.54
4.68
4.74
4.07
3.76
3.67
4.04
5.69
3.49
7.58

4.91
4.60
4.49
2.90
3.26
1.78
2.54
3.80
2.94
1.98
1. 16
2.44
.93
1.79
2.13
2.00
1.90
2. 62
1.40
4.95
SP04
»gP/«3
2.95
2.5<»
3.23
2.58
4.01
3.29
3.35
3.27
2.89
U.7H
2.97
4.16
2.89
3.96
3.60
2.70
2.40
3.55
4.18
2.58
2.44
1.60
2.98

2.42
3.21
3.14
1.56
1.45
.79
.60
1.33
.92
1.95


2.16




1.45

.12
504
•gS04/l
15.37
15.16
15.22
15.16
14.71
15.15
15.33
14.17
14,95
15.46
15.39
15.70
15.25
15.94
14.09
14.23
12.32
13.59
13.76
12.83
13.84
14.26
14.0-6

14.00
14.04
13.75
9.36
12.87
13.59
14.96
14.67
9.38
8.97
8.91
8.86
8.92
8.87
8.69
9.23
8.70
8.89
8.71
11.39
Cl
•gci/i
7.02
7.00
6.95
6.72
6.59
6,68
6.78
6.48
6.77
6.84
6,76
6.76
6.69
6*12
6.00
6.50
5.74
6.. 1*6
6.48
5.85
6..4 1
6.33
6-43

6.32
6,39



















-------
     App. A.2 cont.
N>
!T»

10
10
10
10
If)
11
11
11
11
11
11
12
12
12
14
14
14
14
14
15
15
15
15
15
16
16
16
17
17
17
18
18
18
19
19
19
19
19
OEP
H
0
C
10
15
20
0
5
10
15
20
25
0
C
10
0
c
10
15
20
0
c
10
15
20
0
5
10
0
5
10
0
c;
10
0
5
10
15
20
S&flP

349
350
351
352
353
354
355
356
357
358
359
360
361
362
450
454
455
456
457
458
459
460
461
462
463
464
465
477
478
479
475
474
476
469
470
471
472
473
SEC
D
4.5
4.5
4.5
4.5
4.5
4.5
4.5
4.5
4.5
4.5
4.5
4.0
4.0
4.0
4.5
4.5
4.. 5
4.5
4.5
5.2
5.2
5.2
5.2
5.2
4.8
4.8
4.8
4.5
4.5
4.5
4.5
4.5
4.5
4.5
4.5
4.5
4.5
4.5
TERP
«C
11.5
9.0
9.5
8.9
a. 9
14.0
13.9
12.2
1 1.4
1 1.0
9.0
15.1
14.2
12.9
15.0
15.0
15.0
14.0
13.2
14.4
1 4.4
14.4
14.4
14.2
14.5
14.5
14.5
14.5
14.4
14.4
14.4
14.4
14.0
14. fl
14.8
14.6
1 4.5
10.5
PH

8.39
8.2°
8.29
b. 30
8.25
8.46
6.53
8.46
8.40
8.34
8. 18
8.52
8.56
8.48
8.49
8.54
8.54
8.52
8.46
8.46
8.48
8.52
8.53
3.47
8.43
8.48
8.47
8.45
8.48
8.58
8.50
8.50
8.52
8.46
8.56
8.58
8.62
3.27
COND
~* mho/cm
2.29
2.19
2.20
2.2i
2.18
2.32
2.32
2.17
2.14
2.08
2.C5
2.39
2.39
2.29
2.42
2.35
2.35
2.35
2.35
2.35
2.35
2.24
2.40
2.10
2.35
2.27
2.37
2.18
2.3 j
2.50
2.20
2.11
2.35
2.37
2.37
2.17
2.38
2.18
CHL
ng/B3
.54
1.01
1.36
1.36
1.25
1.74
1.76
2.12
1.44
1. 15
.94
1.38
1.49
1.45
1.71
1.72
1.66
1.47
1.U5
1.62
1.60
1.66
1.69
1.60
1.78
1 .74
1.78
1.66
1.74
1.64
1.73
1.71
1.73
1.78
1.67
1.66
1.81
1.78
PHAE
fraction
.31
.18
.18
.13
.17
. 15
.07
.05
.04
.14
.27
.14
. 16
.15
.06
.10
.08
. 15
.10
.09
.07
.12
.09
. 13
.12
.06
.10
.17
. 17
.13
.11
.06
.17
.10
.15
.05
.07
-.01
3102
mgSi02/l
1.23
1.39
1.35
1.34
1.42
1.14
1.02
1.12
1.19
1.27

.98
.98
1. 12

.95
.96
1.05
1.04
1.03
1.02
1.03
1.02
1.04
1.01
1.02
1.03
1.02
1.02
1.02
1.02
1.04
1.07
.95
.97
.97
.98
.97
N03

268. 9
299.0
291.4
324.5
307.8
241.1
233.4
283.2
305.7
316.2
356.9
222.4
210.2
250.9
212.8
233.6
228.4
348.2
339.7
431.9
306.7
218.8
200.7
315.5
277.9
219.2
201.1
210.4
249.6
307.4
211.5
229,8
213.5
211.3
284.3
267.7
251.1
237.9
TP04
•gP/«3
7.84
3. 15
2.23
2.62
2.82
5.78
3.52
3.27
3.05
2.01
5.77
3.19
4.. 71
3.34
4.78
4.31
3.75
3.89
3.20
3.56
3.02
3.67
4.39
3.44
4.84
3.35
2.68
4.26
3.73
3. 19
3.94
2.94
3.52
3.78
2.74
9.88
3.52
2.63
SPO4
«gP/«*
6.06
.82
.66
.35
.40
.56
1.48
1.90
.95
1.26
3.01
1.82
.84
1.24
3.80
2.46
2.20
1.81
1.80
1.99
2.33
1.32
1.98
2.25
2.16
2.00
1.47
2.27
1.93
1.80
1.52
1.68
1.75
2.03
2.67
2.18
2.65
2.78
S04
•gS04/l
9.43
8.78
8.85
13.43
9.10
8.80
9.10
13.69
8.76
8.58
8.88
15.25
8.89
12.29
14.51
14.31
14.23
14.03
13.83
14.01
13.81
10.43
13.53
13.21
12.50
13.69
13.87
14.10
14.41
14.71
14.37
11.02
12.90
13.42
111. 11
14.03
13.96
14.27
Cl
•gcl/1














6.58
6.56
6.«9
6.41
6.31
6.43
6.39
3.55
6.37
6.14.
5.93
6.4.0
6.50
6.43
6.39
6.39
6.42
4.68
5,94
6.44
6.50
6.57
6.51
6.45

-------
App. A.2 cont.
TJ DEP S4HP
22
22
22
22
23
23
23
24
24
24
24
25
25
25
25
25
25
26
26
26
26
26
26
26
27
27
27
27
27
27
27
27
27
27
28
28
28
28
28
28
26
28
28
28
0 483
5 484
10 485
15 486
0 487
5 488
10 489
0 363
5 364
10 365
15 366
0 367
5 368
1C 369
15 370
20 371
25 372
0 373
5 374
*IO 375
15 376
20 377
25 378
30 379
0 380
5 381
10 382
15 383
20 384
25 385
30 386
35 387
40 388
50 389
C 3-90
5 391
10 392
15 393
20 394
25 395
30 396
40 397
50 398
60 399
SEC
n
4,5
4.5
4.5
4.5
4.5
4.5
4.5
5.0
5.0
5.0
5.0
5.5
5.5
5.5
5.5
5.5
5.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5




















TEHP
•C
14.2
14. -2
14.0
13.2
15.1
15.0
14.9
14.5
14.5
13.2
12.5
14.0
14.0
13.1
11.9
10.0
8.0
12.9
12.8
12.4
10.0
7.0
6.5
6.0
12.1
12.1
11.0
10.4
9.9
7.4
6.8
5.5
5.3
5.2
12.9
12.9
10.8
10.0
8.0
6.8
6.4
5.8
5.5
5.2
PH
8.45
8.46
8.46
8.41
8.47
8.53
8.51
8.56
8.61
8.51
3.43
8.55
8.54
8.50
8.38
8.33
8.25
8.48
3.48
8.52
8.40
8.18
8.09
8.05
8.48
8.48
8.43
8.35
8.32
8.21
8. 11
8.05
8.07
8.06
8.49
8.49
8.40
8.30
8.37
8. 11
8.11
8.16
8.15
3.14
COND
-*Bho/cm
2.55
2.40
2.35
2.32
2.52
2.53
2.51
2.42
2.43
2.34
2.26
2.38
2.35
2.24
2.10
2.07
2.09
2.20
2.21
2.20
2.09
2.10
2.16
2.18
2.23.
2.24
2.12
2.05
2.04
2.13
2.15
2.20
2.22
2.22
2.26'
2.24
2.09
2.09
2.C6
2.13
2.1b
2.1S
2.19
2'.22
CHL
mg/B3
1.72
1.47
1.75
1.46
1.77
1.58
1.72
1.79
1.88
1.85
1.85
1.56
1.73
1.54

1.47
1.47
1.84
1.89
1.87
1.45
1.39
.91
.71
1.85
1.77

1.51
1.30
1.08
1.15
.56
.52
.58
1.74
1.71
1.80
1.44
1.41
1.22
.95
.89
.70
.51
PHAE
fraction
-.08
.20
.08
.17
.07
.09
.10
.11
.12
.10
.13
.10
.11
.08

.11
.12
-.01
.04
-.08
.08
.14
.30
.39
.08
.01

.02
.07
.18
.20
.44
.50
.46
.06
.02
.03
.04
.08
.20
.23
.22
.41
.50
SI02
•gSi02/l
1.02
1.04
1.06
1.13
.89
.89
.92
1.05
1.05
1.05
1.15
1.00
1.00
1.03
1.10
1.24
1.31
1.05
1.04
1.03
1.13
1.50
1.73
1.96
1.11
1.06
1.09
1.11
1.18
1.61
1.60
1.95
2.01
2.03
1.02
1.05
1.07
1.26
1.06
1.33
1.45
1.32
1.36
1.56
H03
246.9
181.3
230.6
251.2
224.5
191.0
169.3
220.6
207.2
189.0
222.0
195.0
188.0
221.0
266.3
299.3
315.4
266.9
260.0
274.5
299.8
348.2
444.2
388.1
278.1
294.1
294.9
314.0
322.4
357.0
363.8
384.5
389.8
389..0
268.9
336.7
334.9
358.4
348.6
369.0
397.2
369.0
380.9
368.0
TP04
3.28
3.99
3.98
4.15
5.14
3.87
3.94
5.30
3.22
2.95
6.39
1».2«
2.91
2.57
3.20
2.37
2.59
4.02
3.23
2.91
3.54
2.38
2.95
2.88
3.19
2.27
3.08
3.10
2.83
3.15
4.57
1.88
4.07
3.20
3.88
2.94
4. 12
2.76
3.35
3.47
3.09
4.24
6.66
2.75
SPO4
2.11
2.47
2.74
2.30
2.44
2.68
2.44
2.54
1.65
1.63
2-06
2.10
1.51
1.00
2.83
2.23
1.36
1.41
1.38
1.57
.89
1.23
1.06
1.58
1.92
1.33
1.48
1.55
1.02
1.55
.99
1.71
3.66
1.51
1.97
1.56
1.87
2.49
1.89
1.87
1.71
2.69
1.92
2.90
S04
»gSO4/l
15.02
14.44
14.62
14.29
14.60
14.78
14.45
14.85
15.27
14.26
11.35
14.63
14.33
13.21
13.87
12.03
8.15
10.05
9.00
8.94
7.40
6.72
6.16
6.84-
7.63
3.64
5.54
3.02
1.97
10.24
9.56
12.16
9.90
11.04
9.50
13.81
9.96
12.32
12.49
9.73
11.85
11.04
12.19
9.31
Cl.
•gci/i
6.53
6.37
6.33
6,. 20
6*64
6,60
6.54
6 .43
6.59
£.33
4.72
6.4.7
6.47
5.94
5.48
5.38
5.15
6.Q3
5.96
5.88
5.40
5.20
5.D1
5.29
5.91
3.85
5.0.0
3.73
.69
4,09
3,28
5,26
3.28
4.63
2.63
6.05
3.. 70
5.39
5.27
3.37
5.23
4.69
5.37
2.26

-------
App. A.2 cont.
ITA

29
29
29
29
29
29
29
29
29
29
30
30
30
30
30
30
30
30
30
31
31
31
31
31
38
38
38
38
39
39
39
39
39
39
39
39
40
40
DEP
«
0
5
10
15
20
2E
30
40
50
6G
0
c
10
15
20
25
30
35
40
0
5
10
15
20
0
5
10
15
0
C
10
15
20
25
30
35
0
5
SAMP

400
401
402
403
404
405
406
407
408
409
410
411
U12
413
414
415
416
4 17
418
419
420
421
422
423
320
321
322
323
312
313
314
315
316
317
318
319
310
311
SEC
a
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
8.5
8.5
8.5
8.5
8.5
8.5
8.5
8.5
8.5
5.0
5.0
5.0
5.0
5.0
4.5
4.5
4.5
4.5
5.5
5.5
5.5
5.5
5.5
5.5
5.5
5.5
4.5
4.5
TE«P
°C
10.6
10.6
10.5
8.0
6.9
6.0
5.8
5.0
«.S
4.5
8.8
8.9
8.5
8.2
7.2
6.8
6.5
6. '5
6.4
10.0
9.9
9.8
9.5
8.0
14.9
14.9
14.9
14.0
15.7
15.5
14. 1
13.5
12.2
8.0
8.0
6.2
16.5
16.5
PH

8.35
8.41
8.37
8.34
8.26
3.2*
8.20
8.09
8.05
8.05
8.22
S.29
8.22
8.21
8.13
8.10
8.11
8.10
8.12
8.26
8.26
8.24
8.28
8.18
8.52
8.53
8.50
8.48
8.54
8.53
8.53
8.46
8.47
8.17
8.04
8.02
8.58
8.56
COHD
-*mho/cm
2.16
2.16
2.13
2.C7
2.12
2.12
2.14
2. IP
2.19
2.20
2.05
2.05
2.04
2.04
2.10
2.15
2.14
2.24
2.01
1.83
1.63
1.87
1.86
2.03
2.35
2.35
2.37
2.28
2.06
2.27
2.20
2.10
2.03
2.05
2. 00
2.15
2.17
2.19
CHL
«g/B3
1.32

1.61
2.75
1.37
1.46
1.26
.67
.59
.57
.96
.97
1.09
1.05
.92
.99
.87
.87
.88
1.15
1.37
1.33
1.27
1.07
2.02
1.76
1.80
1.68
1.60
1.63
1.94
1.47
1.37
1.08
.85
.97
1.60
1.53
PHAE
fraction
. 13

-.01
-.02
.06
.26
.22
.36
.34
.44
.07
.08
.17
.18
.24
.21
.28
.31
.30
.12
.10
.05
.10
.18
.06
.07
.03
.09
.08
.08
.03
.03
.07
.28
.31
.25
.03
.05
SI02
jngSi.02/1
1.16
1.18
1.18
1. 12
1.27
1.15
1.31
1.54
1.61
1.65
1.28
1.26
1.40
1.40
1.52
1.51
1.51
1.53
1.51
1.49
1.50
1.49
1.48
1.53
.94
.93
.93
.98
,76
.84
.86
.89
-.97
1.40
1.78
1.81
.72
.75
S03

304.5
313.8
311.9
327.5
343.1
350.8
358.5
415.2
386.5
392.6
352.8
363.6
357.1
386.9
396.2
367.4
383.0
379.6
376.2
353.8
345.7
370.8
362.6
375.1
226.6
211.3
214.0
236.2
193.6
221.3
247.7
261.5
287.9
350.4
386.4
390.6
158.4
187.3
TP04
•gP/«*
3.59
3. 13
7.59
4.54
3.82
3.35
3.47
3.56
3.79
5.03
3.53
4.18
4.22
5. 12
5.18
4.52
3.83
4.59
5.44
3.83
4.08
3. 18
3.82
3.46
3.37
7.04
4.07
3.58
3.17
3.47
3.98
5.19
2.83
2.88
4.49
3.29
2.39
2.41
SP04
BgP/«»
2.27
1.53
2.62
3.21
3. 13
2.06
2.12
2.30
4.00
3.06
3.32
2.30
2.97
2.65
2.82
2.42
2.12
2.65
4.75
2.67
2.04
1.80
2.03
2.78
2.62
1.45
2.31
2.83
.90
1.23
1.11
2.03
3.39
1.38
3.85
1.48
1.15
1.18
SOU
•gS04/l
12.64
12.69
12.98
12.78
5,29
12...Q2
9.14
11.75
9.24
11.96
11.28
9.13
9.18
11.17
11.58
9.07
9.00
11.48
8.97
9.50
9.18
9.71
10.13
9.08
16.45
16.52
15.63
14.39
14.75
14.70
14.64
14.23
15.25
12.22
13.11
12.23
14.39
13.26
CL
•gci/i
























*»Si
6.49
6.56
&«.17
6.30
6.28
5,93
S..67
6.29
5 14
i.47
5 .,1ft
6-»17
5/70

-------
    App.  A.2 cont.
bo
(—>
00
:T» DEP SAHP
K
41 0 300
41 5 309
41 10 308
41 15 307
i»1 20 306
41 25 305
41 30 304
U1 35 303
41 4C 302
41 45 301
1*2 C 290
42 5 291
42 10 292
42 15 293
42 20 294
42 3C 295
42 40 296
42 50 297
42 60 298
42 70 299
43 0 280
43 5 281
43 10 282
43 15 283
43 20 284
43 30 285
43 40 286
43 50 287
43 60 288
43 70 289
44 C 270
44 5 271
44 10 272
44 20 273
44 30 27U
44 50 275
44 70 276
44 90 277
44 100 278
44 110 279
SEC
*
5.5
S.5
5.5
5.5
5.5
5.5
5.5
5.5
5.5
5.5
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6. 9
6.9
6.9
3.5
8.5
8.5
8.5
8.5
8.5
8.5
8.5
8.5
8.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
TEMP
«C
16.1
16.1
15.5
11.0
8.5
7.6
7.0
S.«
6.1
6.0
15.0
14.5
14.0
12.0
11.0
5.5
4.9
a. 5
4.5
4.4
12.5
12.5
12.5
12.4
6.0
4.6
4.4
4.4
4.4
4.4
12.0
12.0
11.5
5.9
4.5
4.4
4.4
4.2
4.2
4.2
PH
8.51
8.58
8.53
8. 39
8.20
8. 10
3.04
8.00
3.00
8.02
8.48
8.U9
8.48
8.40
8.34
8.06
8.04
8.00
7.96
7.96
8.37
8.43
8.46
8.42
8.32
8. 18
8.12
8.11
8.12
8.11
8.46
8.42
8.41
8.65
8.40
8.12
8. 17
8.08
8.07
8.03
CCND
-*a'ao/cm
2.27
2.23
2.24
2.05
2.00
2.11
2.03
1.89
2.15
2.17
2.20
2.1H
2.21
2.04
1.99
2.11
2.15
2.17
2.11
2.16
2.03
2.00
2.00
2.00
2.20
2.16
2.17
2.19
2.21
2.22
1.96
1.95
1.95
1 .74
2.10
2.12
2.1.2
2.11
2,07
2.16
CHL
mg/B*
1.81
1.85
1.60
1.34
1. 12
.87
.67
.45
.31
.36
1.47
1.54

1.25
1.41
.83
.54
.46
.39
.37
1.92
1.81
1.78
1.73
2.19
1.23
.73
.55
.33
.22
1.94
1.87
1.94
1.98
2.83
.83
.59
.23
.24
.20
PHAt!
fraction
.05
.03
.07
.17
.25
.23
.31
.44
.60
.52
. 15
.11

.21
.12
.20
.38
.47
.50
.53
.01
.05
.04
.09
.09
.23
.27
.30
.47
.67
.03
-.06
-.06
-.03
.08
.20
.22
.57
.63
.70
SI02
ngSi.02/1
.78
.75
.83
.96
1.13
1.29
1.43
1.79
2.00
1.97
.79
.80
.92
.96
1.04
1.40
1.71
1.84
1.90
1.97
1.02
.99
1.00
.99
1. 20
1.38
1.44
1.46
1.55
2.05
.98
.95
.98
1.01
1.23
1.43
1.50
1.61
2.09
2.23
N03
agH/»3
211. 1
179.4
201.7
267.5
306.4
319.7
329.2
348.9
368.7
347.4
222.8
244.0
272.9
292.8
315.3
353.2
314.3
379.0
387.4
381.8
261.7
259.0
252.6
254.7
293.0
326.4
335.7
323.4
325.4
345.6
274.7
264.7
266.8
306.3
325.2
330.9
329.4
335. 1
354.1
361.0
IPO 4
agp/m»
8.72
3.29
3.32
2.80
3.65
2.18
3. 11
1.59
2. 14
3.20
4.04
5.36
4.48
3.57
2.91
3.37
2.76
3.27
2.12
2.88
2.41

2.45
3.08
4.45
3.32
3. 18
3.45
2.41
3.55
2.69
2.33
2.53
2.03
1.94
1.78
1.59

2.46
3.70
SP04
•gP/«*
1.37
1.29
1.40
1.11
.84
.76
.46
.95
1.01
2.34
2.77
2.99
1.92
2.63
1.70
1.45
2.15
1.01
1.08
1.29
.88
.87

2.06
1.24
1.48
1.53
3.00
1.66
2.10
1.39
1.70
1.14
.95
1.24
1.05
.32
.39
1.35
1.70
S04
•gS04/l
13.04
12.64
14.30
11.65
11.27
10.43
10.95
10.91
11.77
11.38
12.60
13.55
12.69
10.69
10.39
11.01
1d.82
10.53
11.25
10.62
11.25
10.95
11.00
10.59-
11.65
10.79
11.29
11.56
12.96
11.31
10.92
10.85
11.92
11.05
11.55
12.05
11.19
12.14
11.27
11.89
CI
•gCl/1
6.15
6.15
6. .13
5.40
4.91
.4.41
5.11
5.17
5,40
5.23
5.89
6.03
5.52
4.84
5. .01
5.14
5,., 28
5.20
5.24
tt..88
-5..09
5.13
5,13
S..93
5.36
J5ufle
5.35
5.16
5.72
5- 19
5 .01
4.88
5. A3
5 ^18
5.30
5*37
4.92
5*39
5.21
5. ,43

-------
App. A.2 cont.
;TA

45
45
45
45
45
45
45
45
45
45
46
46
46
46
46
46
46
47
47
47
47
47
48
48
48
48
49
49
49
49
49
49
49
49
49
50
50
50
50
50
50
50
50
DEP
.1
0
C
10
15
20
30
40
50
60
70
0
c
10
15
20
25
30
0
5
10
15
20
0
c
10
15
0
5
10
15
20
23
30
40
50
0
5
10
15
20
25
10
35
SAHP

260
261
262
263
264
265
266
267
268
269
253
254
255
256
257
258
259
248
249
250
251
252
244
245
246
247
235
236
237
238
239
240
241
242
243
227
228
229
230
231
232
233
234
SEC
m
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
5.5
5.5
5.5
5.5
5.5
5.5
5.5
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
9.0
9.0
9.0
S.O
9.0
9.0
9.0
9.0
9.0
6.0
6.0
6.0
fi.O
6.0
6.C
6.C
6.0
TEHP
°C
11.0
11.0
10.5
10.5
8.2
4.5
4.5
'4 ,U
4.4
4.4
11.8
11.1
10.5
3.5
7.2
6.8
6.5
14.0
13.2
12.6
8.5
8.0
14.5
13.8
12.8
9.0
9.8
9.8
9.8
9.0
8.5
7.4
6.5
5.8
5.8
10.2
10.0
9.2
8.0
7.5
7.0
6.3
6.b
PH

8.28
8.33
8.32
8.28
8.26
8.14
8.13
8.13
8.13
8.07
8.18
8.18
8.11
8.14
8.12
8. 10
8.10
8.12
8.08
8.07
8.03
8.05
8.13
8.12
8.12
3.06
8.24
8.24
8.26
8.30
a. 21
8.19
8.19
8.02
7. 98
8.19
8. 16
8.15
8.12
8.11
8. 10
8.05
8.06
COHD
~* mho/en
1.88
1.93
1.92
1.90
1 .82
1.76
2.00
2.14
2.15
2.15
1.68
1.72
1.80
1 .84
2. 04
2.12
2.17
1.30
1.42
1.42
1.96
1.95
1.36
1.26
1.54
1.94
1 .94
1 .96
1.95
1.96
2.03
2.14
2.16
2.00
1.99
1.83
1.82
1.84
1.94
2.02
2.12
2.15
2.12
CHL
•g/»3
1.69
1.56
1.69
1.43
1.58
1.67
.78
.54
.39
.36
1.80
1.66
1.34
1.19
1.21
1.12
.95
1.34
1.43
1.35
1.12
1.11
1.24
1.28
.98
.53
1.20
1.60
1.62
1.39
1.33
1.32
1.09
.77
.69
1.21
1.41
1.26
1.22
1.04
1.02
1.17
1.00
PHAE
fraction
.06
.07
.00
.08
.09
.23
.24
.33
.39
.50
.04
.08
.11
.22
.18
.21
.26
.17
-.01
.08
.17
.11
.17
.19
.10
.61
.10
-.01
.05
.01
.12
.24
.28
.32
.33
.25
.06
.13
.17
.27
.27
.27
.32
SI02
•gSi02/l
1. 14
1.14
1.27
1.17
1.23
1.37
1.45
1.49
1.60
1.77
1.61
1.58
1.54
1.56
1.51
1.51
1.60
1.88
1.85
1.83
1.66
1.61
1.84
1.90
1.76
1.61
1.36
1.25
1.24
1.27
1.24
1.27
1.38
1.69
1.80
1.45
1.45
1.46
1.46
1.48
1.49
1.56
1.63
NO 3

290.0
280.0
302.6
291.5
311.6
320.9
327.9
332.3
330.8
337.7
324.9
308.9
306.1
315.5
322.4
329.3
327.7
283.1
294.9
294.5
335.2
334.9
280.8
257.6
286.2
316.0
289.8
273.8
269.9
276.8
284.9
293.0
298.7
322.5
324.6
274.3
274.0
279.7
296.3
295.9
306.5
301.3
307.0
TPO4
•gP/«3
1.62
2.07
2.55
3.97
2.69
2.13
2.08
2.18
1.55
3.65
5.36
4.31
3.74
2.68
1.78
1.64
2.77
3.75
3.86
4.48
4.72
6.32
4.94
4.46
2.94
2.85
5.67
3.78
4.66
4.45
5.90
5.26
2.99
3.82
3.04
5.60
4.36
8.09
4.52
6.22
5.12
7.02
4. 14
SP04
•gP/»»
.89
.78
1.32
1.04
1.44
1.26
1.24
1.24
1.27
2.63
2.00
1.89
.81
3.71
.39
.67
2.1B
2.03
3.38
2.60
2.57
1.51
3.17
2.13
1.91
1.51
3.48
2.82
2.42
4.15
3.89
3.03
3.17
1.94
2.70
3.73
2.80
2.94
3.87
3.56
3.37
4.49
3.68
son
•gS04/l
11.27
11.77
11.25
10.72
11.79
11.04
11.42
11.58
12.76
12.69
9.15
9.19
9.69
9.62
12.16
11.52
13.15
8.36
8.29
8.22
10.76
10.92
8.64
8.23
8.50
10.58
10.51
11.00
11.73
10.87
11.48
12.09
12.70
12.40
11.31
10.38
10.76
10.81
11.99
10.22
11.73
11.78
12.28
CL
•gci/i
4.91
4.85
4.97
4.91
5.24
4.96
5.33
5.33
5.41
5.42
3.52
3.97
4.18
4.08
4.98
5.23
5.. 66
2.QS
2.58
2.11
4.64
4.87
2*33
1.73
3 ^^3
4..7J)
4.57
4.94
4.A2
4.8J6
5.09
5.2JS
5.32
5.39
4.75
1*37
4.4.8
4.64
5.01
4.40
5.16
S.2J
5.35

-------
App. A.2 cont.
STA

124
124
120
124
130
130
130
130
130
130
130
130
130
DEP
H
0
c
10
15
0
5
10
15
20
25
30
35
40
SiP!P

324
325
326
327
218
219
220
221
222
223
224
225
226
SEC
m
5.0
5.0
5.0
5.0
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
TEH?
°C
1 4.4
14.4
12.0
10.3
8.5
8.5
7.5
6.9
6.5
6.5
6.4
6.0
6.0
PH

8.47
8. 46
8.45
8.28
8. 11
6.18
8. 15
8. 15
8.09
8.06
8.03
8.04
8.05
CCHD
— * mho/cm
2.33
2.34
2.30
1.87
1.99
2.04
2.05
2.13
2.08
2.19
2.08
2.19
2.13
CHL
•g/n*
1.72
1.66
1.68
1.59
.90
.94
1.12
1.32
1.29
.88
1.09
.81
1.12
PHAE SI02
fraction ngSio2/l
.06 .98
.07 .96
.08 1.07
.14 1.20
.14 1.30
.14 1.34
.14
.06
.11
.33
.24
.41
.14
.41
.42
.47
.48
.52
.55
.55
NO 3
mgN/B*
211. 1
219.4
260.9
277.6
332.8
327.6
324.9
316.1
321.8
307.0
306.7
301.5
296.4
TPOtt
»gP/»a
4.01
4.69
3.08
7.94
4.08
3.94
5.95
4.37
6.67
4.39
4.43
5.08
5.75
SPO4
»gP/»3
1.60
4.46
1.19
1.22

3.66
2.62
5.07
3.71
3.14
3.68
4.11
3.56
S04
•gS04/l
16.23
16.18
14.10
13.10
12.25
12.18
12.11
13.63
12.43
12.24
9.57
13.13
12.49
Cl
•gCl/1
6.J60
6.63
6.17
5.44
5.30
5.28
5.24
6.19
5.54
5.3.7
3.79
5 ..46
5^62

-------
Appendix A,3  Cruise 3, October 1973
STA

1
1
1
2
2
2
2
2
3
3
3
3
3
3
3
4
4
4
4
4
5
5
5
6
6
6
7
7
7
8
8
8
8
8
9
9
9
9
9
9
9
9
9
DSP
H
0
5
10
0
5
10
15
20
0
5
10
15
20
25
30
0
5
10
15
20
0
5
10
0
5
10
0
5
10
0
5
10
15
20
0
5
10
15
20
25
30
35
40
SAMP

513
514
515
508
509
510
511
512
501
502
503
504
505
506
507
496
497
498
499
500
493
494
495
490
491
492
571
572
573
574
575
576
577
578
583
584
585
586
587
588
589
590
591
SEC
a
6.5
6.5
6.5
6.0
6.0
6.0
6.0
6.0
7.3
7.3
7.3
7.3
7.3
7.3
7.3
7.3
7.3
7.3
7.3
7.3
7.8
7.8
7.3
6.0
•5.0
6.0
6.0
6.0
6.0
7.3
7.3
7.3
7.3
7.3
•7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
TEMP
°C
15.1
15.1
15. 1
15.0
14.9
14.6
14.6
14.5
14.9
14.9
14.9
14.8
14.0
13.5
13.5
14.2
14.2
14.2
14.0
14.0
14.0
14.0
13.8
14.5
14.5
14.4
12.5
12.5
12.2
12.4
12.2
12.1
12.1
12. 1
12.4
12. 3
12.2
12.2
12.2
12.2
12.2
12.0
12.0
PH

8.51
8.51
8.49
8.45
8.46
8.46
8.46
8.44
8.U3
8.46
8.43
8.41
8.37
8.33
8. 31
8.42
8.44
8.44
8.41
8.41
8.35
8.37
8.43
8.44
8.21
8.UO
8.11
8.24
8.28
8.23
8.24
8.29
8.25
S.20
8. 11
8.11
8.22
8.25
8.29
8.34
8.24
8.17
8. 13
COND
-*«ho/cm
2.59
2.54
2.51
2.51
2.H9
2.46
2.48
2.42
2.48
2.52
2.52
2.47
2.44
2.38
2.33
2.45
2.44
2.47
2.46
2.45
2.29
2.44
2.49
2.47
2.45
2.94
2.00
2.00
2.01
2.10
1 .96
1.96
1 .89
1.92
2.13
2.13
2.09
2.02
2.02
2.00
2.04
2.05
2.07
CHi
mg/«3
1.51
1.67
1.65
1.81
1.63
1.65
1.65
1.55
1.67
1.73
1.74
1.61
1.59
1.27
1.28
1.41
1.35
1.47
1.39
1.27
1.59
1.49
1.40
1.84
2.24
2. 14
1.58
1.49
1.56
1.32
1.56
1.62
1.65
1.60
1.44
1. 51
1.56
1.57
1.51
1.58
1.43
1.13
1.22
PHAE
fraction
. 13
.19
.21
-.07
. 15
.13
.13
. 11
.17
.14
.13
.14
.15
.24
.26
.19
.23
.19
.23
.27
.14
.16
.17
.16
.12
.14
.05
.06
.07
.10
.12
.16
. 17
.19
.16
.15
.15
.08
.12
. 11
.11
.23
.19
SI02
mgSi02/l
1.03
1.33
1.03
1.13
1. 15

1.19
1.27
1. 17
1.20
1. 14
1.25
1.36
1.41
1.47
1.35
1. 32
1.32
1.32
1.39
1.43
1.38
1.40
1.43
1.40
1.44
1.55
1.51
1.49
1.46
1.45
1.53
1.50
1.52
1.34
1.44
1.44
1.43
1.37
1.34
1.31
1.39
1.30
N03

158.6
158.4
162.6
182.4
175.0
176.3
180.5
193.2
170.6
167.5
163.1
175.8
194.3
215.7
221.3
171.4
176.9
215.6
185.2
190.8
171.8
177.4
178.7
140.7
153.5
154.8
324.9
311.0
303.2
302.8
307.0
314.2
315.4
325.6
305.7
297.8
286.9
307.7
304.4
302.5
303.7
301.9
301.6
TPO4
•gP/n*
4.64
5.46
4.50
4.47
5.43
4.56
5.12
5.51
4.66
4.44
5.09
4.92
4.91
4.39
4.43
5.41
5.93
5.10
5.36
4.58
5.33
5.85
4.89
5.47
6.07
6.03
4.69
4. 69
5.15
4.27
3.70
4.16
3.36
4.53
3.51
3.50
7.84
10.40
4.19
4.64
4.06
4.06
5.40
SP04
•gP/«»
3.66
3.87
3.79
3.28
4.49
4.58
3.53
4.23
3.99
4.46
3.55
4.20
3.29
3.41
3.33
4.39
4.78
4.30
4.56
3.86
4.70
5.22
4.87
5.84
5.27
4.88
3.75
3.06
3.06
3.37
2.53
2.03
2.34
1.56
1.76
2.08
2.16
2.65
2.81
2.08
2.52
2.03
3.00
S04
•gS04/l
13.99
14.04
14.30
14,09
13.93
14.09
13.50
13.30
14.34
14.40
14.24
13.71
13.55
12.97
12.92
14.39
14.45
14.08
14.56
13.81
14.55
15.1*
14.34
15.29
15.66
15.03
10.83
11.12
11.22
11.72
11.42
10.80
10.77
10.73
11.76
11.66
10.84
11.33
10.90
11.27
11.50
11.53
11.50
CJ.
•9C1/1
6.67
6.50
6.63
6.52
6.55
6.28
6^25
6.21
6*64
6.81
6^54
6.34
6.14
6. .00
5.83
6,^73
6.49
4.A9
£i*32
fc*35
6.»«
6.34
6,40
6 .58
6.58
6.41
4. .89
5.15
5.38
5.32
5.11
4.81
H.7.8
4^36
5*55
5.67
4.97
5.58
5^13
5-29
5.51
5.34
3.53

-------
App.  A. 3 cont.
STA DEP  3A«P  SFC
     H          g
                                PH
                                         CONO
                                        »n ho/cm
                                                  CHL
10 0 59?
10 5 593
10 10 594
10 15 595
10 20 596
11 0 519
11 5 520
11 10 521
11 15 522
11 20 523
11 25 524
12 0 516
12 5 517
12 10 518
13 0 707
13 5 7 08
13 10 709
14 0 710
14 5 711
14 10 712
14 15 713
14 20 714
15 0 715
15 5 716
15 10 717
15 15 718
15 20 719
16 0 720
16 5 721
16 11 722
17 0 723
17 5 724
17 10 725
18 0 72f)
1S 5 727
18 1C 728
e.o
8.0
8.0
P.O
8.0
7.5
7.5
7.5
7.5
7.5
7.5
7.0
7.0
7.0
7.0
7.0
7.0
6.5
6.5
6.5
6.5
6.5
6.5
f .5
6.5
6.5
6.5
5.5
5.5
5.5
6.0
6.0
*>•"'
6.E
6.5
6.5
12.5
12.5
12.4
11.8
11.2
12.1
12.1
12. 1
12.1
12.0
12.0
12.0
12.0
12.0
14.0
1 4.0
14.0
13.9
1.3.9
13.8
13.0
13.0
13.5
1-3.5
13.5
13.4
13.0
13.5
13.5
13.5
14.5
14.4
1 3.5
1 3.S
1 1. 8
13.3
8.28
8.26
8.29
8.22
8.17
8.22
8.23
8.29
8.21
8; 20
8.11
8.22
8.21
8.21
8. 42
3.48
8.49
8.41
3.39
8.42
8.40
8.38
8.34
8.37
3.44
8.42
8.36
a. 44
8.42
8.41
8.52
8.50
8.44
«. 37
8.47
8. 37
2.02
2.02
2.04
1.96
1.96
2.00
1.99
2.00
2.00
1.99
1.97
1.96
1 .94
1.94
2.37
2.37
2.37
2.40
2.37
2.35
2.32
2.30
2.43
2.41
2.32
2.32
2.3U
2.37
2.34
2.34
2.5ii
2.4B
2.33
2.3?
2. 3<;
2.34
1.09
1.46
.24
.52
.27
.06
.35
1.35
1.53
1.60
1.24
1.37
1.51
1.38
1.40
1 .44
1.46
1.41
1. 54
1.70
1 .44
1.27
1.03
1.26
1.05
1.48
1.33
1.25
1. 17
1. 16
1.22
1.47
1.51
1.24
1.19
1.20
PHAE
fraction
.13
.10
.25
.13
.22
.17
.10
.08
.09
.09
.15
.10
.07
.17
.12
.16
.17
.15
.13
.15
.21
.31
. 14
.17
.22
.14
.11
.24
.27
.07
. 18
.17
. 13
. 13
.22
.18
SI02
»g Si 02/1
1.33
1.33
1.35
1.32
1.46
1.65
1.58
1.58
1.58
1.59
1.58
1.64
1.64
1.59
1.01
.96
.95
i96
.96
1.03
1.04
1.17
1.08
1.07
1.06
1.09
1. 12
1.08
1.05
1. 11
2.12
1.73
1. 17
1.02
1.13
1.08
HO 3
ngB/a*
308.8
314.5
308.1
310.8
325.5
298.4
295.4
309.6
293.6
299.2
303.4
263.0
288.7
300.0
248.0
234.1
229.2
243.6
254.6
246.7
250.7
259.2
246.8
247.8
245.8
249.8
259.8
247.4
236.5
244.9
193.7
200.7
228.6
235.6
238. 1
236. 1
TP04
•gP/»3
5.77
5.44
8.79
6.25
5.43
5.37
3.32
2.16
2.08
5.28
2.17
3.89
4.24
3.67
2.84
3.23
2.96
2.54
2.69
3.15
2.88
3.58
3.42
3.62
3.04
3.50
3.50
3.31
2.96
3.43
4.10
3.95
3.45
3.65
4.35
3.93
SPO4
3.82
4.38
4.75
5.15
3.81
2.78
3.25
.95
1.43
1.50
1.61
2.87
2,96
2.69
2.33
2.75
2.14
1.91
2.33
2.29
2.14
1.83
2.06
2.37
2.45
2.26
2.26
1.50
1.89
2.60
2.33
2.61
2.22
2.69
2.97
2.47
SO4
mgSOH/1
11.01
10.98
11.08
11.31
11.15
9.75
10.01
9.75
9.80
9.86
9.70
10.22
9.74
9.80
12.66
12.68
12.76
12.62
12.59
12.51
11.48
11.67
12.47
12.27
11.91
12.05
11.52
12.10
11.46
11.76
9.47
10.82
11.51
19.88
20.19
17.21
Cl
•gci/i
5.05
5.20
5.J11
5.15
5..09
5.13
5.36
5.36
5 ..19
5.22
5.08
4.2u
5.11
5.«10
6.60
6.68
6.62
6.63
6.55
5 .55
6.3.0
6.31
6.46
6.117
6.65
6.56
6 .JO
6.44
6.35
6 .70
6.10
6.39
6.50
6 ..88
6.69
6.23

-------
    App.  A.3 cont.
K>
I—i
oo
ST»

1 9
19
19
19
19
20
20
20
21
21
21
22
22
22
22
23
23
23
24
24
24
24
25
25
25
25
25
26
26
26
26
26
26
26
27
27
27
27
27
27
27
27
27
27
DEP
H
0
5
10
15
20
0
5
10
0
5
10
0
5
10
15
0
5
10
0
5
10
15
C
C
10
15
20
0
5
10
1 5
20
25
30
0
c
10
15
20
25
30
35
40
50
SAUt

729
730
731
732
733
734
735
736
737
738
739
740
741
742
743
744
745
746
747
748
749
750
751
752
753
754
755
756
757
758
759
760
761
762
76?
764
765
766
767
768
769
770
771
772
SEC
m
7.0
7.0
7.0
7.0
7.0
5.5
5.5
5.5
8.0
8.0
e.n
6.5
6.5
6.5
6.5
7.0
7.0
7.0
6. .8
6.8
6.8
6.8
8.0
8.0
9.0
8.0
8.0
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.0
7.0
7.0
7. 1
7.0
7.0
7.0
7.0
7.0
7.0
TSMP
•c
13.5
13.5
13.4
12.9
12-. 8
13.5
13.0
13.0
12.6
12.15
12.5
13.5
13.3
12.8
12.5
13.6
13.5
12.5
12.6
12.5
12.0
11.8
12.5
12.5
12.4
12.4
12.3
12.8
12.6
12.5
12.5
12.4
11.5
11.0
12.8
12.6
12.5
12.14
12.0
1 1.9
1 1.6
10.5
7.5
7.2
PH

8.41
8.45
8.47
8.37
8.24
8.43
8.44
8.41
8.35
8.34
8.29
8.41
8.41
8.28
8.29
8.37
8.40
8.41
8.32
8. 34
3.37
8.27
8.28
8.30
8.34
8.37
8.28
8.25
8. 32
8.25
8.29
8.25
8.12
7.98
8.29
8.32
8.28
8. 2U
8.16
3. 15
8.19
8.21
8.09
7.94
COND
-» mho/cm
2.38
2.41
2.34
2.26
2.25
2.27
2.13
2.07
2.03
1.98
1.93
2.36
2.30
2.09
2.00
2.39
2.34
2.34
2.17
2.15
2.05
1.89
1.94
1 .92
1 .90
1.90
1.93
1 .95
1.93
1 .90
1.91
1.91
1.91
1.92
1.90
1 .87
1.85
1 .90
1 .90
1.92
1.93
1 .95
2.00
2.12
CHL
ng/rn*
1.18
1. 10
.59
1.64
2.03
1.23
1.16
1.79
.54
1.72
1.06
1.59
1.17
1.60
1.43
1.36
1.36
1.45
1.35
.91
1.63
1.40
2.19
1.89
2.08
1.51
1.03
1.83
1.78
1.81
1.77
1.38
.89
.72
1.81
1.81
1.81
1.52
.91
.85
.86
.70
.71
.61
PHAE
fraction
.24
.21
.20
.22
. 19
.14
.25
.08
.24
.03
.20
.09
.15
.05
.16
. 16
.15
. 16
.12
.38
.15
.23
.04
.01
.06
.13
.21
.01
.11
.06
.07
.13
.25
.30
.00
.01
.02
.13
.29
.27
.28
.33
.24
.43
SI02
ngSi02/l
1.02
1.03
1.07
1.28
1.25
1.15
1.31
1.29
1.37
1.32
1.22
1. 11
1. 11
1.05
1.12
1.25
1.27
1.27
1.30
1.21
1.13
1.16
1.11
1.10
1. 10
1.13
1.10
1. 12
1.20
1.00
1.12
1.08
1.18
1.37
1.28
1.08
1. 19
1.11
1.17
1.20
1.16
1.22
1.30
1.65
H03

238.6
245.6
236.2
255.1
242.7
245.2
256.3
253.3
270.7
268.7
298.1
258.8
259.8
256.4
223.1
245.0
240.0
247.0
283.9
284.9
278.5
312.3
310.4
296.4
301.9
319.4
310.0
314.0
323.9
314.5
309.6
307.6
316.1
321.6
321.1
310.2
347.0
321.2
305.8
320.2
316.8
317.8
330.8
360.1
TP04
•gP/»3
3.04
3.43
3.48
4.38
4.42
3.45
6.38
3.73
4.36
3.94

4.49
5.51
3.96
4.55
3.85
3.93
3.98
3.17
3.60
5.39
4.70
4.59
3.85
4.63
3.86
3.13
3.37
3.61
3.88
5.01
3.85
3.09
2.98
4.76
3.76
6.09
7.11
6.84
4.69
4.49
3.61
3.65
3.87
SP04
•gP/.'
2.75
3.14
2.99
3.58
2.34
2.66
2.70
3.05
4.03
2.52
2.80
3.81
2.61
3.01
2.43
2.47
2.29
2.64
2.92
2.26
2.31
2.31
2.47
2.32
2.02
3.03
2.18
2.27
2.62
2.20
2.32
2.60
2.02
1.76
2.23
2.00
2.47
3.02

4.12
2.55
2.93
2.09
2.32
S04
•gS04/l
20.45
20.65
20.72
18.80
14.31
16.02
15.39
9.49
9.22
8.36
10.18
17.63
16.89
9.23
6.26
16.41
17..42
16.68
14.40
14.01
13.03
9.94
9.90
8.10
8.41
10.24
9.84
9.79
9.99
8.54
9.66
10.22
10.29
10.48
8.32
6.53
7.54
8.89
9.56
9.99
12.07
12.15
13.05
14.89
CL
•gcl/l
6.58
6.82
6.60
6.34
5.50
5uJB2
5.66
ft.J»0
4.31
3.99

-------
App. A. 3 cont.
ST» DEP SASP SEC
n
28 0 773
28 5 774
28 10 775
28 15 776
28 20 777
28 25 778
28 30 779
28 40 780
28 50 781
28 60 782
29 0 783
29 5 784
29 10 785
29 15 786
29 20 787
29 25 788
29 30 789
29 40 790
29 50 791
29 60 792

3C 0 793
30 5 794
30 10 795
30 15 796
30 20 797
30 25 798
30 30 799
30 35 800
3C 40 801
3' 0 802
31 5 803
31 10 804
31 15 805
31 20 806
32 0 567
32 5 568
32 10 569
32 15 570
33 0 563
3? £ 564
33 10 565
33 15 566
n
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.4
7.4
7.4
7.4
7.4
7.4
7.4
7.4
7.4
7.4

6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
8.0
8.0
8.0
8.0
8.0
7.5
7.5
7.5
7.5
9.5
9.5
9.5
9.5
TESP
•c
12.2
12.1
12.0
11.6
11.4
11.0
10.5
8.8
6.9
6.9
12.1
12.0
11.9
11.8
11.5
10.8
10.0
5.8
5.0
4.8

13.0
13.0
13.0
1 3.0
12.8
12.0
10.5
10.0
9.9
13.1
13.1
13. 1
13.1
13. 1
12.8
12.8
12.6
12.5
12.5
12.4
12.2
12. 1
PH

8.24
8.24
8.29
8.31
8.29
8.24
8.17
8. 14
7.94
7.96
8.22
8.20
8.21
8.20
8.29
8.24
8.20
8.11
8.08
8.02

8.22
8.25
8.19
8.18
8.14
8. 16
8.05
8.04
7.99
8.24
8.30
8.29
8.24
8.25
8.22
8.21
3.21
8. 17
8.24
8.21
8.27
8.2*
C08D
-» mho/cm
1 .83
1.77
1.79
1.86
1.91
1.92
1.97
2.00
2.11
2.13
1.78
1.81
1.81
1.81
1.83
1.90
1.8f
2.00
1.98
2.11

1.71
1 .73
1.65
1.67
1.71
1.77
1.87
1.92
1.95
1.72
1.70
1.70
1.70
1 .71
1.80
1.74
1 .77
1.73
1.87
1 .84
1 .87
1.81
CHL
rng/B'
1.92
1.92
1.88
1.54
.95
.81
.76
.74
.71
.49
1.94
2.01
1.77
2.12
1.67
1.21
.83
.57
.63
.45

1.87
1.96
1.81
1.94
1.30
1.08
.76
.65
.96
1.77
1.70
1.89
2.00
1.86
1.79
2.01
1.88
1.33
1.79
1.81
2.01
1.89
PHAE
fraction
.00
.01
-.00
.08
.25
.36
.34
.34
.40
.53
-.02
.05
.05
.03
.13
.25
.24
.40
.44
.47

.08
.02
.06
.04
.31
.16
.30
.40
.34
.07
.02
.04
.04
.00
.05
-.10
-.00
.15
.08
-.01
-.02
-.02
SI02
•gSiO2/l
1.22
1.32
1.16
1.30
1.18
1.20
1.12
1.32
1.61
1.53
1.19
1.19
1.15
1.16
1.13
1.18
1.20
1.37
1.42
1.50

1.41
1.48
1.40
1.45
1.31
1.45
1.49
1.49
1.55
1.46
1.53
1.42
1.46
1.43
1.60
1.53
1.57
1.59
1.28
1.36
1.30
1.36
H03
•gH/B3
323.8
333.8
321.4
319.4
310.0
315.5
316.5
331.0
351.4
364.4
317.6
321.6
318.2
311.7
312.7
303.3
313.3
344.2
354.7
397.6

349.3
330.6
341.6
313.7
322.4
312.9
333.0
325.7
350.4
318.0
310.7
312.6
341.8
330.0
330.8
322.9
348.2
329.8
332. 1
328.7
319.4
328.1
TPO4
•gP/m*
3.60
3.60
2.87
3.17
3.02
2.98
4.72
3.50
3.00
3.23
5.70
3.71
3.37
3.74
3.70
3.17
3.01
2.66
2.81
3.04

6.05
3.94
3.48
2.95
3.66
2.90
3.16
3.31
3.31
3.34
4.14
5.82
5.01
5.62
5.52
5.22
5.49
4.65
5.71
5.63
5.21
4.91
SP04
•gP/»*
2.54
2.31
2.49
1.77
1.96
2.10
2.37
2.86
2.02
2.28
2.20
2.80
2.42
2.19
2.26
2.45
2.02
1.94
1.90
2.20

1.93
3.75
1.77
1.73
1.58
2.18
2.33
1.98
2.40
2.09
2.35
2.84
2.61
2.76
4.24
4.09
3.97
3.44
5.00
4.62
4.58
4.32
SOU
•gS04/l
10.20
9.83
10.14
11.28
11.95
12.28
12.13
13.61
14.75
15.43
10.03
10.35
10.32
10.53
11.20
11.53
11.96
13.68
15.4'6
15.02

8.93
8.56
8.17
8.50
9.17
9.60
11.68
12.35
13.37
9.37
8.89
8.97
8.94
8.92
10.42
10.06
10.03
10.00
10.55
10.52
10.49
10.86
Cl
•gCl/1
4.17
4.08
4.25
S .53
4*77
4.92
4.^76
5*0.7
5.32
5.33
lull
4.29
4.43
4^27
4.45
4.53
4.67
5.22
5.23
5.3.1.
r
3.58-
3.66
3.90
3^65
.3.86
4..20
4.58
4.73
4MT
3.85
3.79
3.84
3.82
3.96
«.C4
4.01
4.03
4.J07
4. J7
4.50
4.4.7
4.45

-------
App. A.3 cont.
STA

34
34
34
34
34
34
34
34
35
35
35
35
35
35
35
35
35
35
. , 36
to ,,
ho 36
0 36
36
36
36
36
36
36
36
37
37
37
37
37
37
37
37
37
37
38
38
38
38
DEP
H
0
5
10
15
20
25
30
35
C
5
10
15
20
25
30
35
40
45
0
5
10
15
20
25
30
35
40
4E
0
5
10
15
20
25
30
35
40
45
0
5
10
15
SAHP

555
556
557
558
559
560
561
562
545
546
547
548
549
550
551
552
553
554
535
536
537
538
539
540
541
542
543
544
525
526
527
528
529
530
531
532
533
534
699
700
701
702
SEC
n
9.5
9.5
9.5
9.5
9.5
9.5
9.5
9.5
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
7.5
6.5
6.5
6.5
6.5
TEKP
oc
12.4
12.4
12.2
12.0
11.9
11.3
10.7
9.0
12.2
12.1
12.0
12.0
11.8
11.3
10.8
10.0
8.C
7.2
12.2
12.2
12.2
12.. 0
11.9
11.5
11.0
10.5
9.8
7.0
12.8
12. 2
12.2
12.0
12.0
12.0
12.0
1 1. 5
tt.O
7.5
13.9
13.8
12.2
12.1
pa

8.10
3.29
8.25
8.22
8.14
8. 10
8. 15
7.98
8.24
8.27
8.28
8.45
8.28
8.25
8.17
8.21
7.9'4
7.98
8. 15
8.18
8.24
8. 17
8.22
8. 15
8.09
8.10
8. 11
7.92
8.28
8. 30
8.29
8.27
8.29
8.29
8. 19
8. 18
8.00
7.77
8.38
8.44
8.47
8.37
COND
-«nho/cm
1.84
1.84
1 .79
1.87
1.89
1 .87
1.96
2.00
1.95
1.91
1.91
1 .88
1.84
1.92
1.91
2.00
2.01
2.01
2.07
1.96
1.96
2.06
2.04
1.85
1.93
1 .94
2.01
2.08
2.22
2.13
2.09
2.06
2.07
2.07
2.13
2.13
2.09
2.19
2.31
2.32
2.17
1.85
CHL
mg/m3
1.68
1.84
1.87
1.34
1.20
.84
.80
.89
1.80
1.71
1.69
1.42
.93
.79
.63
.52
.57
.54
1.32
1.72
1.82
1.34
1.14
.94
.65
.66
.53
.78
1.31
1.52
1.56
1.54
1.33
1.17
1.17
.84
.83
.68
1.68
1.86
1.88
1.73
PHAE
fraction
.08
.09
-.03
. 12
.15
.31
.31
.22
.00
.05
.03
.14
.29
.35
.39
.57
.41
.47
.11
.04
.06
.'19
.23
.26
.36
.37
.45
.30
.13
.12
.10
.10
.15
. 13
.21
.29
.37
.47
.03
.06
.11
.11
SI02
»gsio2/l
1.51
1.41
1.46
1.59
1.56
1.50
1.67
1.57
1.69
1.40
1.82
1.41
1.42
1.57
.42
.51
.75
.93
.45
.47
1.53
1.85
1.48
1.55
1.52
1.75
1.60
1.90
1.41
1.48
1.52
1.52
1.52
1.52
i. 52
1.58
1.85
1.99
1.17
1.13
1.22
1.16
N03

322.6
311.8
317.5
318.6
J16.8
322.5
328.2
336.9
297.3
294.0
289.1
306.9
305.0
292.6
313.4
322.1
339.9
357.7
294.4
278.5
285.5

254.0
276.3
294.1
302.8
322.1
344.4
242.9
277.2
284.2
285.5
283.9
280.9
285.0
286.3
322.0
334.8
261.8
247.9
266.8
314.1
TPO4
mgf/t*
6.35
6.55
7.23
7.85
5.78
5.44
6.09
5.25
3.88
3.38
5.09
3.69
2.75
2.54
1.96
S. 14
6.16
7.35
2.74
2.12
7.22
3.53
4.05
2.70
2.41
4.03
2.35
3.48
2.08
2.69
2.48
2.80
3.03
2.98
1.92
2.56
2.96
3.73
3.38
4.15
5.03
4.42
SP04
•gP/«'
6.68
5.46
5.69
9.79
5.99
5.46
5.80
5.15
8.89
2.05
9.41
1.87
1.98
3.56
1.32
4.59
4.97
5.88
1.81
1.68
2.12
10.81
2.63
2. 10
2.45
6.44
2.44
1.78
1.75
1.93
1.23
1.75
1.78
1.73
1.76
1.88
1.75
1.86
2.09
2.05
2.67
2.36
S04
•gSO4/l
10.94
10.78
10.74
11.70
11.54
10.78
11.01
11.12
12.78
11.36
12.58
11.03
10.87
11.23
11.20
11.17
11.73
12.49
9.«1
9l23
9.39
11.94
9.71
9.66
9.50
10.51
11.46
11.82
9.65
10.18
10.13
9.96
10.23
9.86
9.12
9.87
10.02
10.02
11.51
11.65
9.96
7.56
ct
•gci/l
«.9Z
4.37
4.84
5-99
5,. 2 5
1»j66
5 .03
4.7,6
6..8A
4.79
7.19
5. .13
4.7,2
5..19
5.3ft
S.17
5.29
5«,9«
4.98
4.51
5.20
8.47
s..te
5.57
5.51
7 ..06
5.53
5.51
9.65
sis*
5»17
5.36
5.33
5.23
5.39
5*25
5.25
.5 .2.8
6.18
6.16
5.63
4.60

-------
   App. A.3  cont.
N>
STA DEP SBNP
H
39 0 691
39 5 692
39 10 693
39 15 694
39 20 695
39 25 696
39 30 697
39 35 698
40 0 689
40 5 690
41 0 679
41 5 680
41 10 681
41 15 682
41 20 683
41 25 684
41 30 685
41 35 6 86
41 40 687
41 45 688
42 0 669
42 5 670
42 10 671
42 15 672
42 20 673
42 30 674
42 40 675
42 50 676
42 60 677
42 70 678
43 C 659
43 5 660
43 10 661
43 15 662
43 20 663
43 30 664
43 40 665
43 50 666
l>3 60 667
43 70 669
SEC

7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
6.5
6.5
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.C
9.5
9.5
9.5
9.5
9.5
9.5
'•*.5
9.5
9.5
9.5
TEHP
•C
12.5
12.4
1 1.8
11:5
11.2
11.2
11.0
10.0
13.0
13.0
12.0
11.0
10.6
10.5
10.4
10.4
8.0
7.6
6.9
6.6
11.0
10.5
10.4
10.0
9.0
6.6
5.0
5.0
a. 9
4.9
1Z.O
1 1.6
1 1.4
1 1.0
10.0
6. 5
4.9
4.5
4.5
4.4
PH

8.30
8.30
8.31
8.28
8.24
8. -18
8.17
8.13
8.34
8;34
8.32
8.31
8.38
8.37
8.32
8.18
8.17
8.06
7.96
7.87
8.28
8.37
8.33
8.30
8.28
8.10
8.01
7.84
7.92
7.83
8.34
3.37
8.43
8.29
rf.28
8. 18
3.22
3.04
8.05
7.<53
COND

2.07
2.06
2.01
1.94
1 .98
2.11
2.05
2.05
2.26
2.20
2.16
2.14
2.09
2.07
2.14
2.07
2.15
2.10
2.17
2.1(1
2.15
2.17
2.08
2.09
2.09
2.16
2.09
2.03
2.09
Z. 13
2.00
2.00
1 .96
2.00
1.03
2.16
2.06
2.22
2.12
2.21
CHL

1.27
1.29
1.41
1.65
1.45
1.06
1.16
1.01
1.02
1.21
.81
.89
1.85
1.72
1.36
1.27
1.04
.91
.71
.49
.95
1.39
1.49
1.31
1.32
.81
.96
.54
.45
.53
1.73
2.21
1.83
1.90
1 . 32.
1 . 33
1. 12
.51
.41
.40
PHAE
fraction
.07
.10
.06
.06
. 11
.27
.21
.28
.24
.14
.29
.31
.01
.07
.20
.16
.17
.34
.41
.47
.05
.19
.17
.13
.13
.33
.23
.42
.55
.46
-.02
-.01
.03
.11
.17
.23
.26
.44
.43
.51
SI02
mgSi.02/1
1.15
1.08
1. 11
1.13
1.17
1.19
1.25
1.34
1.17
1.14
1.05
1.05
1.06
1.00
1.05
1.07
1.13
1.36
1.49
1.63
1.29
1.32
1.34
1.38
1.28
1.28
1.20
1.49
1.45
1.46
1.10
1.09
1.09
1.11
1.23
1'.32
1.36
1.66
1.76
1.74
NO 3
•g N/B3
285.0
295.0
312.4
320.9
317.4
318.4
292.4
319.5
290.4
260.1
290.-3
278.6
281.2
285.3
283.7
289.2
300.4

321.2
338.6
302.6
282.3
286.4
284.7
288.8
321.6
311.3
332.7
336.7
337.9
299.1
287.4
298.7
279.8
295.4
312.4
315.0
336.3
340.4
337.3
IP04
•gP/»'
2.26
2.41
3.22
3.72
2.88
3.72
3.53
2.76
3.10
2. 80
2.94
2.75
3.79
3.56
2.91
2.75
2.87
5. 15
2.79
2.49
3.79
3.15
7.09
4.46
3.55
3.14
3. 17
3.17
3.14
3. 10
3.02
3.19
3.78
5.16
3.50
3.56
3.30
2.55
2.64
3.12
SP04
«gP/»»
1.86
1.59
1.67
1.59
1.78
1.90
2.59
2.13
1.70
2.05
2.27
2.27
2.23
2.16
2.04
2.08
2.85
1.81
2.28
1.62
2.20
2.18
2.58
3.17
2.77
2.23
2.38
3.00
2.46
2.08
2.16
2.02
2.23
2.09
2.38
2.31
3.37
2.27
2.05
2.84
S04
•gS04/l
8.55
8.47
8.16
8.30
8.5«
9.07
9.42
9.39
10.49
10.73
10.57
11.03
10.23
10.20
10.17
10.26
9.34
9,69
9.50
9.31
11.81
12.22
11.75
10.50
11.41
10.56
10.19
10.71
10.52
9.83
11.43
11.72
11.38
11.80
11.65
12.08
11.73
11.46
11.43
11.39
Cl
•gCl/1
5.05
ft. 96
4.97
JUS 5,
5 ..13
5*34
5.62
5.52
5.34
5.92
5.82
5.87
5.85
5.86
5.84
5.32
5.79
5uJ»3
5.38
.5.. 35.
&J.7
5.75
5.76
5*7,41
5-75
5.69
5.71
5..JM
5.63
5.61
5*14
5.05

5.41
5.36
5.47
5.48
5..3A
£..57.
5,. 66

-------
    App.  A.3 cont.
NJ
M
NJ
TA

00
00
04
00
00
00
00
00
44
00
05
05
45
05
05
45
45
05
05
05
06
06
06
06
06
06
06
07
07
07
07
07
08
08
08
48
49
09
09
49
09
09
09
09
09
DBF
r
0
5
10
20
30
50
70
90
100
1 10
0
5
10
15
20
30
00
50
60
7C
0
5
10
15
20
25
30
0
5
10
15
20
0
5
10
15
0
5
10
1 5
20
25
30
00
50
SAMP

609
650
651
652
653
650
655
656
657
658
639
640
641
642
603
600
605
606
607
608
632
633
630
635
636
637
638
627
628
629
630
631
623
62"
625
626
610
615
616
6.17
618
619
620
621
622
SEC
ID
11.5
11.5
11.5
11.5
11.5
11.5
11.5
11.5
11.5
11.5
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
4.0
0.0
U.O
0.0
0.0
3.3
3. 3
3. 3
3.3
6.0
6.0
6.0
6.0
6.0
6.0
6. C
6.0
6.0
TEMP
°C
11.5
11.5
11.5
11.0
9.0
0.5
0.4
4.2
0.2
0. 2
11.5
11.5
11.0
11.0
10.0
6. 0
5.0
0.9
0.6
0.5
13.5
13.0
12.5
12.2
1 1.2
9.8
8.6
10.2
13.9
12.5
12.0
11.1
10.6
1 0.0
13.5
12.5
13.0
13.0
13.0
12.5
1 1.8
10.5
9.5
9.0
6.fi
PH

3.37
8.39
8.02
8.00
8.25
d. 16
8.11
8. 11
8.03
3.03
8.25
8.30
8.33
8.37
8.30
8.16
8.06
8.01
7.99
7.98
8.27
3.17
8.16
8.19
8.10
8.09
8.08
8.09
8.09
8.08
8. 15
8. 11
8.10
8.16
8. 14
8.09
3.21
8.22
3.24
8.22
8. 19
8. 20
8.10
8.04
8.01
COND
-*fflho/Cin
1 .95
1.96
1.92
2.02
2.00
2.17
2.11
2.21
2.10
2.23
1 .91
1.93
1.93
1.93
2.00
2.08
2.15
2.12
2.20
2.11
1.67
1.71
1.71
1 .76
1.87
1.95
2.00
1.32
1.05
1 .70
1.82
1.83
1.21
1.16
1.51
1 .73
1.58
1 .66
1.60
1.66
1.84
1.96
1.96
2.07
2.12
CHL
mg/mJ
1.22
1.93
2.17
.93
1.22
.50
. 32
.23
. 19
. 15
1.03
1.68
1.03
1.01
1. 11
1.14
.69
.56
.53
.00
.82
1.31
1.30
.97
.90
.60
.70
1.05
1.50
1.29
.97
.91
1.38
1.60
1. 12
.97
1.60
1.71
1.76
1.28
1.02
.83
.91
.77
.61
PHAE
fraction
.05
-.01
.01
.35
.26
.08
.53
.65
.70
.71
. 11
.03
.18
.07
.12
.18
.33
. 38
.05
.53
i10
.07
.13
.29
.22
.02
.05
.18
.08
.09
.23
.30
.10
.13
.26
. 15
.00
.01
.02
. 15
.22
.32
.33
.37
.03
SI02
•gSi02/l
1. 30
1. 15
1.12
1.30
1. 13
1.42
1.45
1.82
1.81
1.82
1.25
1.21
1. 10
1.14
1.05
1.31
1.61
1.70
1.73
1.78
1.00
1.05
1.08
1.00
1.35
1.01
1.55
1.76
1.71
1.06
1.06
1.45
2.25
1.89
1.63
1.05
1.53
1.63
1.54
.07
.39
.36
.57
.39
.63
N03
»gH/B»
285.6
278.2
288.0
230.3
296.2
331.9
321.6
337.2
351.3
345.3
257.7
283.3
308.9
295.8
302.7
295.3
339.6
302.3
339.2
359.1
326.8
319.4
314.8
317,5
323.0
328.5
338.0
327.0
322.5
331.2
338.5
256.6
318.2
319.3
325.0
333.7
322.6
300.2
328.0
327.7
336.0
330.5
319.1
336.9
356.2
TPOO
•gP/«3
3.28
0.07
3.28
3.18
3.06
3.01
2.37
2.93
3.22
3.15
6.90
3.37
3.20
2.98
3.27
2.70
2.99
2.69
2.67
3.07
2.33
3.65
2.77
3.25
3.31
2.59
3.65
3.23
7.16
3.10
2.38
2.05
0.05
3.85
2.78
2.81
3.31
3.18
3.17
2.77
3.55
2.76
0.00
3.09
2.61
SPOO
mgp/m*
6.35
3.33
3.07
2.20
3.07
2.12
2.02
1.73
2.07
2.95
2.61
2.82
2.10
1.81
1.71
1.96
2.55
1.72
2.05
3.30
1.22
1.05
1.88
1.39
2.06
1.58
2.29
1.85
2.07
2.06
.93
1.15

3.87
2.57
1.23
2.79
1.92
1.60
1.36
1.19
1.80
6.78
1.09
1.04
S04
•gS04/l
12.50
11.19
11.36
10.16
11.31
11.55
11.27
11.63
11.67
11.90
10.20
11.11
11.54
11.26
11.81
11.14
11.89
11.74
1 1.-84
11.88
10.41
10.38
10.49
10.59
11.21
11.31
11.67
9.89
9.86
10.35
10.90
10.88
10.62
9.82
9.93
10.68
10.32
10.17
10.01
10.25
11.38
11.61
13.44
11.88
11.99
CJ.
•gcl/i
6.<15
5.06
5.45
3.34
5,^07
5.32
0.89
5.41
5^62
5.70
2.94
4.40
0.99
5^20
5.05
•U31
5.34
5.39
5*71
5.^62
3.76
3.78
0-.16
4, ..31
4.69
&~&3.
5.67
2.55
2.70
3.99
4.88
4..50
5.65
2.51
2 .,90

-------
App. A.3 cont.
ST4 DEP SJHP

50
50
50
50
50
50
50
50
124
124
12U
12U
130
130
130
130
130
130
1 30
N3 130
IS 13°
?"
0
5
1 0
15
20
2 c
30
35
0
5
10
15
P
5
10
1 5
20
TC
30
35
no

606
607
608
609
510
611
612
613
703
704
705
706
597
598
599
600
601
602
603
60U
605
SEC
ffl
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
•" 2R?
•C
13.0
13.0
13.0
13.0
12.5
10.1
9.0
9.0
13.0
13.0
12.5
12.0
12.9
12.9
12.9
12.6
12.5
1 1.5
10.0
3.9
8.0
PH

3.15
a. 12
8. 16
8.2"8
8.21
8.05
8.07
8.02
8.35
8.34
8. 34
8. 28
8.22
8.22
8.21
8.27
8.21
8.23
8.02
7.96
7.98
COVD
— 'who/cm
1 .73
1 .74
1.67
1.70
1.69
1.95
1.80
1.98
2.25
2.19
2.21
2.11*
1.76
1 .73
1.77
1.72
1.78
1.83
1.95
2.01
2 .no
CHL
mg/m3
1.98
2.04
2.09
1.9U
1.24
.74
.75
.81
1 .41*
1.42
1.74
1.98
1.45
1.79
1.78
1.78
1.37
.64
.74
.71
.73
PHAE
fraction
.05
.06
.03
.05
.15
.30
.28
.28
.07
.08
.06
.08
.11
.07
.04
.06
.15
.37
.30
.32
.32
SI02
mgSiO2/l
1.36
1.39
1.39
1.44
1.45
1.45
1.51
1.71
1.16
1.14
1. 19
1.23
1.27
1.31
1.30
1. 32
1.31
1.30
1.38
1.54
1.45
N03
ag S/«3
329.8
331.0
329.1
321.3
319.4
340.2
333.8
332.0
288.3
280.3
281.3
310.0
322.2
296.2
315.5
324.2
305.8
323.6
335.3
345.5
342.2
TP04
•gP/«*
3. 15
2.99
3.67
4.57
3.85
4.47
6.19
4.00
2.99
3.46
2.84
3. 15
4.66
4.94
4.53
4.82
3.32
2.15
3.19
2.27
1.42
SP04
•gP/«3
.42
1.34
1.9
-------
        APPENDIX B.   Primary Productivity at 5 m.   Data in mgCm 3hr l
App. B.I  Cruise 1,  August 1973

STA
7
8
10
11
12
13
15
16
17
19
20
21
22
23
25
27
29
31
32
33
34
35
36
DEP
M
5
5
5
5
5
5
5
5
4
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SAMP
28
31
49
54
60
63
71
76
79
85
9Q
93
96
100
107
119
139
158
163
167
171
179
189
C14S
SCREENS
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
C14A
PPB-C/HR
1.8
1.9
2.0
1.7
1.7
1.9
2.0
2.2
2.9
2.9
2.5
2.0
2.4
2.1
1.4
1.9
2.2
2.6
1.8
2.1
1.7
1.8
1.7
C14T
SCREENS
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
C14B
PPB-C/HR
1.7
2.7
2.0
1.7
1.5
1.8
2.1
2.1
3.3
2.6
1.8
2.6
2.2
2.3
1.3
1.8
2.5
2.4
1.7
2.0
1.6
1.8
1.5
C14D
PPB-C/HR
.15
.22
.22
.18
.31
.18
.31
.19
.32
.26
.19
.18
.17
.17
.25
.20
.24
.19
.12
.16
.09
.14
.21
ALK
PPM-C
25.2
25.2
25.8
25.4
25.7
25.5
25.4
25.9
25.8
25.8
25.9
25.2
25.6
25.9
22.6
24.2
24.6
22.9
24.2
24.2
24.6
24.6
25.2
                                     224

-------
App. B.2   Cruise 2, September 1973
STA
1
2
3
4
5
6
7
8
9
10
11
12
14
15
16
17
18
19
22
23
24
25
26
27
28
29
30
31
38
39
40
DEP
M
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SAMP
448
443
436
431
428
425
330
332
341
350
355
361
454
459
464
478
474
470
484
488
364
368
374
381
391
401
411
420
321
313
311
C14S
SCREENS
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
C14A
PPB-C/HR
3.1
3.0
3.1
2.9
3.0
4.2
4.5
3.9
1.7
2.6
2.1
1.8
3.0
2.6
3.2
2.5
2.3
2.8
3.8
3.6
3.0
2.4
2.5
2.2
1.7
1.6
1.6
1.5
2.2
2.7
2.2
C14T
SCREENS.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

1
1
1
1
1
1
1
C14B
PPB-C/HR
3.2
3.2
2.9
1.8
2.8
3.9
5.4
4.3
1.8
2.5
2.4
2.1
3.5
3.0
3.0
2.2
2.1
2.6
3.2
2.4
2.9
2.4
2.8

2.0
1.9
1.7
2.0
2.3
3.0
2.6
C14D
PPB-C/HR
.24
.43
.25
.22
.36
.34
.34
.95
.18
.15
.17
.25
.29
.33
.23
.18
.38
.36
.40
.21
.17
.16
.17
.13
.14
.27
.41
.14
.17
.21
.18
ALK
PPM-C
24.6
24.0
24.1
23.7
21.3
26.6
22.9
22.4
20.5
23.7
25.3
22.1
26.5
23.3
21.5
22.9
22.9
23.1
22.9
23.8
26.3
22.6
24.1
20.9
18.8
20.3
22.1
17.5
20.7
25.0
24.0
                                     225

-------
App. B.2  cont .
STA
41
41
42
43
44
45
46
47
48
49
50
124
130
DEP
M
5
45
5
5
5
5
5
5
5
5
5
5
5
SAMP
309
301
291
281
271
261
254
249
245
236
228
325
219
C14S
SCREENS
1
1
1
1
1
1
1
1
1
1
1
1
1
C14A
PPB-C/HR
2.2
-6
2.3
1.7
1.8
1.6
2.5
2.0
2.0
1.4
1.5
2.4
1.2
C14T
SCREENS
1
1
1
1
1
1
1
1
1
1
1
1
C14B
PPB-C/HR
-0
1.9
1.7
1.7
1.8
2.4
2.0
2.0
1.3
1.5
2.7
1.2
C14D
PPB-C/HR
.40
.34
.10
.10
.13
.16
.29
.11
.08
.09
.14
.16
ALK
PPM-C
22.1
22.1
19.1
17.2
21.5
20.9
21.9
17.5
16.6
17.5
20.3
21.1
21.1
                                    226

-------
App. B.3   Cruise 3, October 1973
STA
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
DEP
M
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SAMP C14S
SCREENS
514
509
502
497
494
491
572
575
584
593
520
517
708
711
716
721
724
727
730
735
738
741
745
748
752
757
764
774
784
794
803
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
C14A
PPB-C/HR
4.5
4.9
4.2
4.2
4.3
4.5
2.4
2.9
2.9
2.6
2.7
3.4
2.9
2.1
1.7
2.2
2.7
2.0
2.4
2.6
2.3
1.9
2.3
1.9
2.3
2.6
1.8
1.8
1.9
1.9
1.7
C14T
SCREENS
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
C14B
PPB-C/HR
3.6
3.4
2.9
2.9
2.5
6.5
.4
2.1
1.8
1.7
2.0
.4
1.8
1.9
1.5
1.9
2.1
2.5
1.5
2.7
1.6
1.9
1.7
2.0
1.7
1.6
2.4
1.7
1.7
1.3
1.4
C14D
PPB-C/HR
.46
.49
.51
.36
-45
.54






.37
.30
.18
.20
.23
.34
1.32
.37
.17
.17
.16
.27
.15
.15
.10
.12
.18
.14
.14
ALK
PPM-C
25.9
25.1
25.2
24.6
24.4
24.6
20.7
20.7
21.3
19.8
20.0
19.8
22.6
23.7
22.8
22.6
25.3
22.4
22.3
20.3
20.3
22.8
24.0
20.5
19.1
19.1
18.6
17.2
17.8
17.2
17.5
                                      227

-------
App. B.3   cont.

STA
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
124
130
DEP
M
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
SAMP
568
564
556
546
536
526
700
692
690
680
670
660
650
640
633
628
624
615
607
704
598
C14S
SCREENS
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
C14A
PPB-C/HR
3.4
3.7
3.2
3.7
3.3
3.4
3.8
2.3
2.1
1.5
1.8
2.2
2.6
3.0
1.9
2.6
2.6
2.1
2.1
3.1
2.0
C14T
SCREENS
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
C14B
PPB-C/HR
2.4
2.5
2.2
2.1
2.6
3.0
1.7
1.5
1.6
.5
1.9
2.7
1.7
2.2
1.4
2.1
2.0
2.4
1.6
1.6
1.3
C14D
PPB-C/HR






.44
.33
.35
.26
.27
.36
.21
.29
1.00
.30
.50
.27
.29
.19
.14
ALK
PPM-C
18.8
19.1
18.8
19.8
20.0
21.3
21.9
19.1
22.1
19.6
20.3
18.8
19.3
24.5
17.5
16.0
14.2
16.9
18.0
21.1
18.0
                                     228

-------
 APPENDIX  C.   Depth profiles of north-south  transects

Appendix C.I   Transect 01-06,  Cruise 1, August  1973
                                             02   01
                                                    CECIL BAY
                                                Silica
 Appendix  C.2  Transect 01-06,  Cruise  2,  September 1973
 WEST OF
 GROS CAP
CECIL BAY
06
05
04
03
'
02 01
i *
--\ ' \
/"
                                              16
                                                Temp.
                                                 Silica
         KILOMETERS
                            229

-------
Appendix  C.3  Transect 01-06,  Cruise 3, October 1973
                                                    CECIL DAY
                                                Silica
        KILOMETERS
                           230

-------
S3
OJ
    App. C.4
    Transect  07-10,  Cruise 1
    August  1973
     RABBIT'S BACK PEAK

              07
                             MACKINAC ISLAND
                                  Temp .
App.  C.5
Transect  07-10,  Cruise 2
September 1973
                                                 RABBIT'S BACK PEAK
                                                                         MACKINAC ISLAND
                                                                              Temp.
                                   KILOMETERS
App.  C.6
Transect  07-10,  Cruise 3
October 1973
                                            RABB'T'S BACK PEAK

                                                      07    OjB
                                                                     MACKINAC ISLAND
                                                                                                                           Temp.
                                                                              KILOMETERS
                                                                                                                          KILOMETERS

-------
App.  C.7   Transect 13-16,  Cruise  1, Aug.  1973
SOUTH OF LIME KILN POINT
BOIS  BLANC ISLAND
rO
                                               WEST OF
                                               POINT AU SABLE
                                                  Temp.
                                                 KILOMETERS
App.  C.8   Transect 13-16, Cruise  2,  Sept.  1973
SOUTH OF LIME KILN POINT
BOIS  BLANC ISLAND
 r°

 -10

 -zo

 -0

 i-to

 -20

 -0

 -10

L-zo

 0

 10

L-20
                                              WEST OF
                                              POINT AU SABLE
                                                  Temp.
                                                  KILOMETERS
                           232

-------
             App.  C.9   Transect 13-16,  Cruise 3,  Oct.  1973
              SOUTH OF LIME KILN POINT
              BOIS BLANC ISLAND
                         WEST OF
                         POINT AU SABLE
                                                               Temp.
                                                               KILOMETERS
App.  C.10  Transect 17-23,  Cruise  1, August  1973
MIDWAY BETWEEN ZELA POINT
AND PT. AUX PINS, BOIS BLANC ISLAND
         20      19      18
-0

-10

-20
-o

-10

-20
-0

-10

-20

-0

-10

-20
EAST OF
CHEBOYGAN
   Temp.
PACKARD POINT
BOIS BLANC ISLAND
         21    22
  Spec.
Conduct.
  Silica
EAST OF
CHEBOYGAN POINT
                           Temp.
                           Spec.
                         Conduct.
                                        Silica
                                                  KILOMETERS
                                         233

-------
 App.  C.ll  Transect  17-23,  Cruise 2,  September 1973
MIDWAY B!
AND PT AUX PINS, BOIS BLANC ISLAND
         20     19     18      17
              __.J	1	L
 ho

 L-ZO

 rO

 -10

 -20
 -0

 -10

 -20

 -0

 -10

 -20
                                  EAS- IF
                                               PACKARD  POINT
                                  CHEBOYGAN     &0|S SLANG ISLAND
                                                        21    22
                                      J         rO        '
  Temp.
  Spec.
Conduct.
  Silica
                                  23
                                      CHEBOYGAN POINT
                                                                         Temp.
                                               U20
                                                                         Spec.
                                                                      Conduct.
                                                                         Silica
                                                  KILOMETERS
App.  C.12   Transect 17-23,  Cruise  3, October  1973
MIDWAY BETWEEN ZELA POINT
AND PT. AUX PINS, BOIS BLANC ISLAND
         2O     19     18
                                 EAST OF
                                 CHEBOYGAN
                                   Temp.
                                   Spec.
                                 Conduct.
                                   Silica
            PACKARD POINT
            BOIS BLANC ISLAND
                     21    22
                                                                       EAST OF
                                                                       CHEBOYGAN POINT
                                        Temp.
                                        Spec.
                                     Conduct.
                                        Silica
                                                  KILOMETERS
                                         234

-------
App.  C.13  Transect 24-31, Crutse 1, August 1973
GOVERNMENT
  ISLAND
     EAST OF
CORDWOOD POiNT
                                                                 Temp.
                                                                 Spec.
                                                              Conduct.
                                                               Silica
                                                    KILOMETERS
                                  235

-------
App.  C.14  Transect 24-31, Cruise 2, September  1973
 GOVERNMENT
  ISLAND
     EAST OF
CORDWOOO POINT
                                                              Silica
                                                  KILOMETERS
                                 236

-------
App.  C.15  Transect 24-31, Cruise 3, October 1973
 GOVERNMENT
  ISLAND
     EAST OF
CORDWOOD POINT
                                                                Spec.
                                                              Conduct.
                                                               Silica
                                                  KILOMETERS
                                  237

-------
ho
LO
CO
         App.  C.16
         Transect  32-37,  Cruise  1, August 1973
         SEARCH BAY
  POINT DETACHEE
BOIS BLANC ISLAND
         IO

         20

         30   Spec.
         «« Conduct.
                        App. C.17
                        Transect  32-37,  Cruise  3, October  1973
                                                                          SEARCH SAY
  POINT DETACMEE
BOIS BLANC ISLAND
                              Spec.
                        ;40  Conduct.
                        i. SO

-------
                                     App. C.18  Transect 40-48,  Cruise  2, September 1973
       POINT DETOUR
                                                 FORTY MILE
OJ
                                                   Temp.
                                                                    POINT DETOUR
                                                                                                               FORTY  MILE  POINT

                                                                                                                42   41   401
  Spec.
Conduct.
                                                pH
                                                                                                          Silica

-------
                                        App.  C.19  Transect 40-48, Cruise 3, October 1973
KJ
*-
o
                                         43
                                                  FORTY  MILE POINT


                                                   4Z   41   40
POINT DETOUR
                                          FORTY  MILE  POINT
                                                   Temp.
                                           Spec.
                                         Conduct.
                                                                                                             Silica

-------
                       APPENDIX D
List of species found in phytoplankton collections
BACILLARIOPHYTA

Achnanthes affinis Grun.
A. biasolettiana (Kutz.) Grun.
A. clevei Grun.
A. clevei var. rostrata Hust.
A. exiqua Grun.
A. exigua var. constricta (Grun.) Hust.
A. exigua var. heterovalva Krasske
A. lanceolata (Breb.) Grun.
A. lanceolata var. dubia Grun.
A. lanceolata var. omissa Reim.
A. laterostrata Hust.
A. linearis  (Wm. Smith) Grun.
A. linearis  fo. curta H. L. Smith
A. microcephala (Kutz.) Grun.
A. minutissima Kutz.
A. minutissima var. cryptocephala Grun.
A. peragalli Brun
A. pinnata Hust.
A. subsaloides Hust.

Species incertae sedis
Achnanthes questionable sp. #1
Achnanthes sp. #1
Achnanthes sp. #15
Achnanthes sp. #28

Amphipleura pellucida Kutz.

Amphiprora ornata Baily

Amphora hemicycla Stoerm.  and Yang
A. ovalis var. libyca (Ehr.^( Cleve
A. ovalis var. pediculus (Kutz.)  V.  H.
A. ovalis Kutz.
A. veneta var. capitata Haworth

Species incertae sedis
Amphora questionable sp. #1
                         241

-------
App. D cont.
Anowoeoneis vitrea (Grun.) Ross

Species incertae sedis
Anomoeoneis vitrea var. #1 (abnormal)
Anomoeoneis sp. #3

Asterionella formosa Mass.

Caloneis alpestris (Grun.) Cleve

Species incertae sedis
Caloneis ventricosa var. #2

Cocconeis diminuta Pant.
C. pediculus Ehr.
C. placentula Ehr.
C. placentula var. euglypta (Ehr.) Cleve
C. placentula var. lineata (Ehr.) V. H.

Species incertae sedis
Cocconeis questionable sp. #1
Cocconeis sp. #4

Cyclotella antiqua Wm. Smith
C. atomus Hust.
C. comensis Grun.
C. comta (Ehr.) Kutz.
C. cryptica Reimann, Lewin, and Guillard
C. kuetzingiana Thwaites
C. kuetzingiana var. planetophora Fricke
C. kuetzingiana var. radiosa Fricke
C. weneghiniana Kutz.
C. meneghiniana var. plana Fricke
C. michiganiana Skv.
C. ocellata Pant.
C. opercu-Zata (Agardh) Kutz.
C. stelligera (Cleve and Grun.) V. H.

Species incertae sedis
Cyclotella comta auxospore
Cyclotella stelligera auxospore
Cyclotella sp. auxospore
Cyclotella sp. #5
Cyclotella sp. #7

Cymatopleura solea (Breb. and Godey) Wm. Smith
                         242

-------
 App.  D cont.
Cymbella  cesatii  Grun.
C. cistula  (Ehr.)  Kirchn.
C. cistula  var. gibbosa  J.  Brim
C. delicatula  Kutz.
C. hustedtii Krasske
C. leptoceros  var. rostrata Hust.
C. microcephala Grun.
C. minuta Kutz.
                  ii
C. obtusiuscula Kutz.
C. parvula  Krasske
C. prostrata (Berk.) Cleve
C. subventricosa  Cholnoky
C. triangulata (Ehr.) Cleve

Species incertae  sedis
Cymbella  questionable sp. #1
Cymbella  sp. #15
Cymbella  sp. #21

Denticula tenuis  var. crassula  (Naeg.) Hust.

Diatoma tenue  var. elongatum Lyngb.

Diploneis boldtiana Cleve
D. elliptica var. pygmaea A. Cl.
D. oculata  (Breb-) Cleve
D. parma  Cleve

Species incertae  sedis
Diploneis sp.  #2

Epithenda smithii Carruthers

Eucocconeis flexella (Kutz.) Hust.
E. flexella var:. alpestris  (Brun) Hust.
E- lapponica Hust.

Eunotia exigua (Breb.) Rabh.
E. incisa Win.  Smith
E. praerupta var. inflata Grun.

Fragularia  brevistriata  Grun.
F. brevistriata var. inflata (Pant.) Hust.
F. capucina Desm.
F. construens  (Ehr.) Grun.
F. construens  var. minuta Temp, and Per.
F. construens  var. pumila Grun.
F. construens  var. venter (Ehr.) Grun.
                          243

-------
App. D cont.
Fragilaria crotonensis Kitton
F. crotonensis var. oregona Sov-
F. intermedia Grun.
F. intermedia var. fallax Grun.
F. lapponica Grun.
F. leptostauron (Ehr.) Hust.
F. leptostauron var. dubia (Grun.) Hust.
F. pinnata Ehr.
F. pinnata var. intercedens (Grun.) Hust.
F. pinnata var. lancettula (Schum.) Hust.
F. vaucheriae (Kutz.) Peters
F. vaucheriae var. capitellata (Grun.) Patr.
F. vaucheriae var. lanceolata A. Mayer

Species incertae sedis
Fragilaria questionable sp. #1
Fragilaria crotonensis Kitton (abnormal)

Frustulia rhomboides var. amphipleuroides (Grun.) Cleve

Gomphonema intricatum Kutz.
G. intricatum var. pumila Grun.
G. lanceolatum Ehr.

Species incertae sedis
Gomphonema questionable sp. #1

Gyrosigma attenuatum (Kutz.) Rabh.
G. spencerii (Quek.) Griff, and Henfr.

Hannaea arcus (Ehr.) Patr.

Mastogloia grevillei Win. Smith

Melosira distans var. alpigena Grun.
Af. granulata (Ehr.) Ralf s.
Af. granulata var. angustissima 0. Mull.
Af. islandica 0. Mull.
Af. italica subsp. subartica 0. Mull.

Navicula anglica var. subsalsa (Grun.) Cleve
N- aurora Sov.
N- capitata Ehr.
N. capsa Hohn
N. cryptocephala Kutz.
N. cryptocephala var. veneta (Kutz.) Rabh.
N. decussis 0str.
N. exigua Greg. ex. Grun.
                         244

-------
 App. D cont.
 Navicula  lacustris  Greg.
 N.  lanceolata  (Agardh)  Kutz.
 N.  minima Grim.
 N.  nyassensis  0.  Mull.
 N.  placentula  var.  rostrata A.  Mayer
 N.  pseudoscutiformis  Bust.
 N.  pupula Kiitz.
 N.  radiosa Kutz.
 N.  radiosa var. parva Wallace
 N.  radiosa var. tenella (Breb.)  Grun.
 N.  rhunchocephala Kutz.
 ff-  stroesei A. Cl.
 N-  tuscula fo. obtusa Hust.
 N.  vulpina Kutz.

 Species incertae  sedis
 Navicula  questionable sp. #1
 Navicula  sp. #1
 Navicula  sp. #12
 Navicula  sp. #35

 Neidium dubium fo.  constrictum Hust.

 Nitzschia acicularis  (Kutz.) Win. Smith
 N.  acuta  Hantz.
 N.  amphibia Grun.
 N.  angustata var. acuta Grun.
 N.  bacata Hust.
 N.  capitellata Hust.
 N.  con finis Hust.
 N.  denticula Grun.
 N.  dissipata (Kutz.)  Grun.
 N.  dissipata var. media (Hantz.) Grun.
 N.  fonticola Grun.
 IV.  insecta Hust.
 N.  luzonensis Hust.
 N.  palea  (Kutz.) Wm.  Smith
 N.  recta  Hantz.
 N.  sigma  (Kutz.) Wm.  Smith
N.  sigmoidea (Nitz.) Wm. Smith
 N.  spiculoides Hust.
N.  sublinearis Hust.

 Species incertae sedis
Nitzschia questionable sp. #1
 Nitzschia  sp. #2
Nitzschia sp. #6
                         245

-------
App. D  cont.
Nitzschia sp. #8
Nitzschia sp. #9
Nitzschia sp. #10
Nitzschia sp. #12

Opephora martyi Herib.

Rhizosolenia eriensis H. L. Smith
R. gracilis H. L. Smith

Rhoicosphenia curvata (Kutz.) Grun.

Stephanodiscus alpinus Hust. ex Huber-Pestalozzi
S. astraea (Ehr.) Grun.
5. hantzschii Grun.
S. minutus Grun. ex Cleve and Moll.
S. niagarae Ehr.
S. niagarae var. magnifies Fricke
S. subtilis  (Van Goor) A. Cl.
S. tenuis Hust.

Species incertae sedis
Stephanodiscus sp. #5
Stephanodiscus sp. auxospore

Surirella biseriata Breb. and Godey
S. ovata Kutz.

Species incertae sedis
Surirella sp. #4

Synedra acus Kutz.
S. cyclopum Brutschy
S. delicatissima var. angustissima Grun.
S. demerarae Grun.
S. filiformis Grun.
S. minuscula Grun.
S. wontana Krasske
5. ostenfeldii (Krieger) A. Cl.
S. parasitica (Wm. Smith) Hust.
5. parasitica var. subconstricta (Grun.) Hust.
S. tenera Wm. Smith
5. ulna (Nitz.) Ehr.
S. ulna var. chaseana Thomas
5. ulna var. danica (Kutz.) V. H.
S. ulna var. longissima  (Wm. Smith) Brun
                         246

-------
 App .  D cont.
 Species incertae sedis
 Synedra questionable sp.  #1
 Synedra sp.  #7
 Synedra sp.  #17

 Tabellaria fenestrata (Lyngb.)  Kutz.
 T.  fenestrata var.  geniculata A.  Cl.
 T.  fenestrata var.  intermedia Grun.
 T.  flocculosa (Roth)  Kutz.
 CHLOROPHYTA

 Ankistrodesmus  gelifactum (Chod.)  Bourr.
 Botryococcus braunii  Kutz.
 Coelastrum microporum Naeg.
 Cosmarium botrytis  Menegh.
 Crucigenia irregularis Wille
 C. guadrata Morren
 Eudorina  elegans  Ehr.
 Franceia  droescheri (Lemm.) G. M.  Smith
 Gloeocystis planctonica (W. and W.) Lemm.
 Golenkinia radiata  (Chod.) Wille
 Lagerheimia ciliata (Lag.) Chod.
 Nephrocytium agardhianum Naeg.
 Pediastrum boryanum (Turp.) Menegh.
 Quadrigula chodatii (Tan.-Ful.) G. M. Smith
 Q. lacustris (Chod.)  G.  M. Smith
 Scenedesmus arcuatus Lemm.
 S. armatus (Chod.)  G.  M.  Smith
 S. bijuga  (Turp.) Lag.
 5. bijuga  var.  alternans  (Reinsch) Hansg.
 S. helveticus Chod.
 S. guadricauda  (Turp.) Breb.
 S. serratus (Chod.) Bohl.
 Sphaerocystis schroeteri  Chod.
 Spondylosium planum (Wolle) W. and W.
 Staurastrum paradoxum  Meyen
 S. paradoxum var. biradiatum (W.  and W.)  Griffiths
 S. longipes (Nordst.)((Teiling
 Tetraedron regulare Kutz.
 Ulothrix subconstricta G. S. West

 Species incertae sedis
Ankistrodesmus  sp.  #1
Ankistrodesmus  sp.  #2
Ankistrodesmus  sp.  #3
                         247

-------
App. D cont.
                                           #1
Ankistrodesmus sp. #4
Cosmarium sp. #1
Cosmarium sp. #2
Eutetrairorus questionable sp. #1
Gloeocystis questionable sp. #1
Oocystis spp.
Staurastrum sp. #2
Undetermined green colony
Undetermined green colony questionable sp.
Undetermined green filament #2
Undetermined green filament #3
Undetermined green individual
CHRYSOPHYTA

Chrysococcus (dokidophorus Pasch.?)
Chrysosphaerella longispina Lautb.
Dinobryon bavaricum Imhof
D. cylindricum Imhof
D. divergens Imhof
D. sociale Imhof
Mallomonas pseudocoronata Presc.
M. tonsurata var. alpina (Pasch. and Ruttn.) Krieger

Species incertae sedis
Chrysophyte cyst
Dinobryon cysts
Dinobryon questionable sp. #1
Mallomonas questionable sp. #1
CRYPTOPHYTA

Cryptomonas ovata Ehr.
Rhodomonas minuta var. nannoplanctica Skuja

Species incertae sedis
Cryptowonas cyst
                          248

-------
App. D cont.
CYANOPHYTA

Anabaena flos-aquae (Lyngb.) Breb .
Anacystis incerta (Lemm.) Dr. and Daily
A. thermal is (Menegh.) Dr. and Daily
Gomphosphaeria lacustris Chod.
Oscillatoria bornetii Zukal
PYRROPHYTA

Ceratium hirundinella  (0. F. Mull.) Shrank
Peridinium cinctum  (0. F. Mull.) Ehr.

Species incertae sedis
Peridinium questionable sp. #1
                          249

-------
                                APPENDIX E
           Proof that a conservative parameter can be expressed
         as a linear combination of other conservative parameters
Definition:  A conservative parameter is defined as one which has a
measured value y in a mixture of volumes V± from N different sources,
such that:
               N                 N
     i)   y =  E  V± Y±     =    I  F± Y±
              1=1               i=l
                 N
                AVJ
and where Y^ = measured value of the conservative parameter at source  i_
                 Vn-
                  i
and       F,- = —-	    =   the fraction of water in the final mixture
                N                              ,
                v                              from source i
                L  \/ •                                      —
               3=1  J
To show:  If Y is a conservative parameter, then it is expressable  as a
linear combination of any two other conservative parameters T and C in
a mixture of water from three water sources.
Proof:  For convenience, rewrite eq. i using vector notation:*
     ii)   y = F • Y
where      F = (Fj, F2, ... , FJJ) = the vector of fractions
           Y = (Yls Y2, ... , YN) = the vector of values of Y at the
                                               sources
           N = the number of sources = 3,  for this case.
Write eq. ii for each of the three conservative parameters:
     iii)  t = F • T
     iv)   c = F • C
     v)    y = F • f
* This proof uses terminology from linear algebra.  Refer to any standard
  text on that subject.
                                  250

-------
                         N
                         E  Vi
             N          1=1
Note that:   I  F^  =   —	  = 1,  or:
            1=1          Z  V-i
                        3=1   J

     vi)   F • G =  1  where G = (1,1,1)

We must now^make two requirements on f and C.   First,  it  is necessary
that T and C are independent of each other.  This  is a logical require-
ment, since if they are not independent,  then  they are proportional and
consequently redundant.  Examples of non-independent variables are the
concentrations of dissolved nitrate  in ppm and yg  at/1 or, in most cases,
the concentrations  of Na+ and Cl .  Second, it is  necessary that T and C
both be independent of  G.  This is also a logical  requirement.  Any
parameter not fulfilling this requirement will have the same value at all
the sources, thus^will  be useless as a tracer.  If these  two requirements
are met, then T, C, and G are mutually independent and are thus a basis
for all three-dimensional^yectors.  Consequently,  Y is expressable as a
linear combination  of T,  C, and G:

     vii)  Y = BT + yC  + aG

Combining eq. v with eq.  vii:

     v)    y = Y  • F
             = (gf +  yC  + aG)  •  F

             = BT-F" + yC-F" + a£-?

     viii) y=8t+yc+a

Equation viii shows that any conservative  parameter y can be expressed
as a linear combination  of any  two  other independent, non-uniform conser-
vative parameters if  there are  exactly  three sources.  By a simple exten-
sion of this argument, it can be shown  that:

     If there are N sources, then any conservative parameter (as
     defined in eq. i or ii) can be expressed as a linear combina-
     tion of N-l other conservative parameters which are neither
     uniform at all the  sources  nor proportional to each other
     (dependent).

Implicit in this discussion is  the  assumption that the values of the
parameters at the sources do not change with time.
                                   251

-------
                                 APPENDIX F.   Counts  of  zooplankton  from vertical net  tows
       Appendix  F.I
       Cruise:  1
ho
Ui
NJ
Srat ion :
Date:
Tow length
in meters:
Species:
Calanoid Copepoda
D ash
D min
D oreg
D siclis
D cops
E lac
L raai
S cal
Cyc 1 opoid Copepoda
C bi th
M edax
r pr mex
Cladocera
L kind
P ped
D leuch
S cryst
H gib
D gal me
D long
D retro
C lac
L quad
Cer ret
B long
E coreg
D dent
A harp
A affin
A quad
C sphaer
E lamell
Clad imm.
Calan Tot (#/m '')
Calan Tot (%)
Cyclo Tot (#/m'l
Cyclo Tot (Z)
Clad Tot (0/tn1)
Clad Tot (%)
Grand Total
1A*
AUK 30

I4«S


60
318
286

481
127



74



71

25

923
3325
11
2638

14

67
608






156
1272
13.9
74
0.8
7838
85.3
9184
'B
Aug 30

14 -S


42
111
481
14
523
141



„ )



W

28

905
3282

2900



28
1047






141
iil2
15.2
43
0.4
8388
84.4
9943
?A
Aug 3D

21 -S


27
1626
661

509
116



259



71
9


956
2127

1653
9


27
688







29)9
33 .h
759
).()
5540
6J.4
8738
2B
Aug 30

21 -S


67
1282
482

661
107



183



2/
18
13

916
1805

1372
18


58
634







2599
34.0
183
2.4
4861
(Vt.6
7643
i
Aug fn

40*20


7S


76
908
700

437
149



233



4?
8


1146
1732

1439




620






•140
2270
29.fi
233
3.1
5127
67.2
7630
4A
Aug 30

2j-s


49
752
352
18
879
JO



206
6


11 >
42


740
1316
424
576
6
6

6
418






127
2080
34.3
212
3.5
3776
62.2
6068
4B
Aug 30

23-S


89
857
364

1496
40



243



89
89


1059
1655
32
558
24
8

8
493






121
2846
39.4
243
3.4
4136
57.2
7225
5A
Aug 30

]fr*s


194
800
715

1225
97



800



109



1395
2583
133
2365
24


24
667






182
3031
26.8
800
7.1
7482
66.1
11313
5B
Aug JO

16>S


155
543
791

858
39



673



100
12


897
1804
21
1831
9


9
491






340
2386
27.8
673
7.9
5514
64.3
8573
h
Aug 10

12-S


12
38
22

79
13



40



32



103
374
37
684



23
93






9
164
10.5
40
2.6
1355
86.9
1559
i
Aug id

14 -s


369
72
396

3824
S ')



572
8


44
8


641
760
1221
796
24


158
303






127
4716
50.3
580
6.2
4082
43.5
9378
8
AUK 20

23-5


1.84

57
4
6] 64
10
M


950
4


(,



30
313
1251
170

12

99
89







6427
68.7
954
10.2
1970
21.1
9351
8
Aug (U

21-11


32h
41
35/
10
12844
31



1 /X 4
Id


TO



41
509
2210
275



102
132






295
13609
71 . /
1793
9.4
3584
18.9
18986
        *Stations 1  2, 4, and 5 were samplf) rwic*' during the same day.  These samples are designated as "A" and  "B".

-------
App .  F.I con t.



Cru tse:  1
Station:
Date-
Tow length
in meters:
Species'
r-alarxoiu t.opepacU.
i> ,sh
1) min
l) oreg
D siclis
D cops
E lac
L mac
S cal
Cyclopoid Copepoda
C bi th
M edax
T pr mex
Cl adorers
L Hi u.i
1* ped
1) leuch
S rrysl
H g«,
D gal rot
D long
B retro
'.: lac-
L quad
Cer ret
B long
E coreg
D dent
A harp
A affin
A quad
r .sphaur
E lamell
Clad turn.
. !an I'm 1 tf !m "j
i.alan Tol C/.}
oyrlo Col (*/m
C.yrlo CM 1 Z>
Clad Tot (ff/m')
Clad Tot (%)
Grand Total
8
Aug 30

11 >s


241
311
990

1103
85



140



5?

4i

1825
2660
1500
1740
28


170
806






523
2710
22. (j
)40
f . i
9351
75.3
12421
9
VuK SI

JVIb


:t
23
23
20
4510
3
91
3

659







17
111
1)9
45



37
40






14
,MH
81 .
659
11
385
6.
5740
9
Aug !0

I6>-S


21,'
212
424

1380
42



255



i,;
It


817
2165
64
1 Ml
1 1


74
363






26',

J - .
' S >
1
5051
.7 66.
7576
10
Aug 111

23-S


IT'
2S9
441

1164
101
12


719
8


H'i
hi


1091
1 90'.
53
1382
8


97
812






174
•1 1 1 0
a 24 «
. J >
.It 8. i
5667
.7 66.6
8504
H
AuS 10

>9>L '


315
12
I7b

8106




1667
12


1?

18

29;
>553
509
1140



49
103






491
88HV
56.3
1679
10. '
5172
33.0
15660
11
Aug 30

1 )>S


85
116
224

416
54



54



17
39


4244
903
15
370



77
1215






?31
895
11.0
•)H
'J . "'
7191
88.3
8140
11
Sep 1

29, If


90
M
1 74

5929

3


722
9


9
i


79
422
45V
321

9

15
78






106
h279
'3
'3i
8.b
1505
17.7
8515
11
Sep 1

Ib-t,


l ><'
HOO
703

1091
267



145



55
24


1589
2534
321
.1116
30


103
1801






327
nu i
'6.3
34^
l.ii
8100
70.7
11458
12
Aug 10

13-»S


79
771
220

557
50



205



61
.)/
8

1685
1951
174
835
16
5

71
1050




6

19
167/
?] .
205
2.6
5920
75.9
7802
13
Sep 1

19->S


110
1388
679

479
130



260
10


70
60
40

979
2317
260
769
II)


40
379






200
27S6
34.1
,,/D
3. 1
5124
62.6
8180
14
Sep 1

25-M9


534
80
1670

7639
46
45


1577
12


43
1 1


410
2081
2254
1227
11


67
694






666
10014
52.5
1589
83
7464
39.1
19067
14
Sep 1

|9>S


27
627
2 ft*

236
32



134

5

70
21
1 1

1238
777
80
306
1 1


16
343






118
1 1 90
2/.5
139
3.2
2991
69.2
4320
15
Sep 1

25-S


199
347
694

L535
81
7


421



66

15

1107
201(1
760
827
7


66
893






362
28b3
30.4
421
4 . 1
6133
65.1
9417
16
Sep i

22-»S


95
47J
484
8
1286
115



225
8


47
13
21

1536
2220
225
1197
8


21
581






140
2457
28.2
233
2. /
6009
69.1
8699
17
Sep 1

IU-S


)2
435
12

350
64



106
11


)2

i i

1517
21 3J
223
573
11


32
828






3?
91*
14.?
1
'. .1
539.'
84.0
6422
18
Sep !

l'v>S


1>9
1166
500

686
176



196
29


'4.!
• ; c,
i . >
74'!..'
72.7
10)04

-------
App.  F.I cent.
Cruise: 1
Station:
Date:
Tow length
in meters'
Species:
Oalanoid Copepoda
D ash
D min
P oreg
D slclis
0 cops
t lac
1 mac
S cal
Cvclopoid Copepoda
C bi th
M edax
T pr tnex
f'tadorera
1 kind
r ped
.' leuch
S cryst
H gib
\i gal me
D long
n ret rn
C !*<•.
C quad
Cer ret
B long
E coreg
D dent
A harp
A affin
A quad
(' sphaci
E lanell
Clad imm.
ualan lot (H/m ,
Calan T<-t CZ)
i.yclo Tot (#/-.': ;
Cyc].) Tot (%>
Clad Tot (#/m3)
Clad Tot (%)
Grand Total
19
Sep 1

24>S


54
532
652

660
139



448



58
39
8

tfhK
195V
166
> 192
8


23
799






185
203 /
26.2
448
s.s
5298
68.1
7783
20
Sep 1

20>S


127
434
1306

1151
184



307
9


33
9
28

1523
2268
585
12SH


14
9
707






373
320/
31.0
316
>. i
6799
65.9
10317
21
Sep 1

16 .-i


182
543
800

2665
115



543
33


18
18
30

1379
1807
382
882
9
12

52
825






179
4305
41 1
576
5.5
5593
53.4
10474
22
Sep 1

19. s


1H
22-
136

701
108



264
72


54
6
6

917
1101
240
491



24
515






6
1385
27 j
Mb
h.6
3361
66.1
5082
23
Sep 1

16>S


i6
73
119
3
671
83



169
13


4'!
^


562
625
13
311
10


13
268






40
i DOS
32.7
IR2
.5. *)
1885
61.4
3072
24
Aug 31

17 >S


124
498
141

1228
62



130
17


4 j
62


97)
979
45
549



28
843






79
2053
35 4
147
;..>
3603
62.1
5803
25
Aug 31

i* 15


193
45
1.57
8
8172
12
61


1022
17


'.
S


Z47
1105
376
26f>



27
171






139
8648
'1.9
1039
8.6
2343
19.5
12030
25
Aug 31

L5>S


to
145
79

781
116



116
65


54
65
25

?02
L171

399
6


82
487






68
1361
29 6
181
3.9
3059
66.5
4601
26
Aug 31

32. -15


16]
37
123
22
9155
6
67


726
10


37
D


141
605
83
176
4


23
116






96
957J
«2.5
736
6. j
1295
11.2
11602
26
Aug 31

15-S


51
1019
306

611
102



136
17


25
59
25

1757
1528
17
331
17


34
197






161
208 1
i: .;
153
. •<*
4151
64.9
6393
27
Aug 11

51 -1


91
4
102

4035

182
14

511
8


'~_,

1

12 )
335
306
140



19
52






22
=4428
'4.4
a 9
3 ,
1003
16.9
5950
27
Aug )l

17-»S


157
397
315

906
82



502
7


' L



1378
936
225
472.



52
502






/: 7
1857
10 .
i09
rf.V
3804
61.7
6170
28
Aug 31

58 '1 '.


34
9
16
10
15706
1
74
9

171




I


2f>
130
118
48



20
65






4;
ljb',9
96.2
1 71
1 ,0
452
2.7
16482
28
Aug »l

IV'S


15H
622
260

1063
158



622
11


:>/
'3
. i

1709
1347
136
396



102
521






373
2261
29.8
633
8. i
4687
61.8
7581
29
Aug II

6HM5


44
9
24
9
3017
1
28


185



1
;
1

34
254
183
93



51
63






16
313*
77.6
1K5
'• 1:
718
17.8
4035
29
Aug 11

1 5->S


167
419
21)9

1647
139
42


100



2.1



•JLH)
IJ 32
4?4
">K')



110
928






21P
2623
34. /
300
4.0
4641
61.4
7564

-------
App.  F.I cont.
Cruise:  1
Station.
Date:
Tow length
in meters:
Species:
Calanoid Copepoda
D ash
D min
D oreg
D siclis
D cops
E lac
L mac
S cal
Cvclopoid Copepoda
C bi th
M edax
T pr mex
Cladoi'era
I- Kind
S 'P*
(_n D leuch
S cryst
H gib
D gal me
D long
D retro
C lac
C quad
Cer ret
B long
E coreg
D dent
A narp
A affin
A quad
sphaer
F 1 ame i 1
Clad imm.
Calan Tot (///m1)
CaJan Tot (%)
Cyclo Tol ("/m1 )
Cyclo Tol (%)
Clad T'.| (II /a' I
Clml Tot (/)
(irand Total
31'
Aug 31

44->ll


115
25
99
21
6863
21
41


748
8


2.1

12

288
661
567
329



181
90






107
7185
70.
756
7.
2256
22
10197
30
Aug 31

11 »S


194
167
417
6=5
85.'
130



370
9


2H

56

1982
1769
556
1157
28


278
1028






1 76
1825
.5 19.
)79
.4 4.
7f)'i«
. 1 /h.
92hP
51
Aug VI

26*11


509
39
470
39
17068




1946
39


13

39

457
2377
2338
1450



24K
26]






,f>
18125
7 65.2
1985
.1 7.1
7705
.2 27.
/HI',
H
Aug 31

ll+S


142
574
336

1535
37
15


732
9


28
77
52

1858
2337
151
1602



404
J44"i






?62
2639
22.8
741
6.4
821(,
70.9
, 1 596
32
Aug 31

23^11


511

196
38
21413
17



995



/



15
836
1238
283



20
•nt






.-'81
22175
85. 7
995
J.K
'700
10.4
^'lX''(:
32
Aug U

1] 'S


93
247
302
9
1803
117



787
15


34
15
56

1324
1843
710
1688
15


41;
1219






33b
2571
23.3
802
7.1
'657
69.4
1 lino
33
Aug 31

23>11


560
51
373

14854




1511
1.7






340
1630
2801
662



323
I5.i






106
15838
67.2
1528
b.5
f.21')
26.4
- i:)8i
3J
Aug 31

11*S


93
240
266

942
245



256
18


23

30

1397
974
359
873
55


336
642






159
1786
25.9
274
4.0
4848
70.2
6908
34
Aug 31

38*27


2
8
4

1934
2
19


300



2

3

23
67
43
22



J2
33






10
1969
86.2
100
4.4
215
9.4
2284
it,
Aug 31

11->S


102
325
174

718
108
5


301
20


24

28

1420
896
314
725
5


216
517






76
1432
24.0
J21
5.4
4221
70.7
5974
3b
Aug 31

29


5
12
28

2573
5
39


219





4

48
40
52
18



26
31






5
2662
85.7
219
7.]
224
7.2
1105
35
Aug 31

11>S


147
249
411
12
2211
46
12


515
12


23
h
12

955
961
1065
642
6


197
336






104
3088
39.0
527
6.7
4307
54.4
7922
36
Aug 3J

49*11


120
59
212
35
3299
73
21


321



J5

2

252
495
457
354
5


35
125






87
3819
63.8
321
5.4
1847
30.9
5987
3o
Aug 31

1 1 >S


51
370
597
42
1273
162



185
9


3/

79

991
1792
607
1699
9
9

181
634






185
2495
28.0
194
2.2
h223
69.8
89J2
37
Aug 31

47->13


134
14
65
1]
5211
8
29
3

562
3


S

1

100
326
485
261
8
3

40
67






89
4475
69.6
565
8.8
1390
21 .6
6430
37
Aug 31

n>s


47
235
118

466
161



262



1 , ,

V<

1826
1626
423
1105



98
846






208
1027
13.6
262
3.5
6285
S3. (I
7574

-------
Appendix F.2




Cruise:  2
Slat ion .
Datt- :
Tow length
in meters:
Spec i e s :
Calnnoid Copepoda
D ash
D min
D oreg
D siclis
D cops
E lac
L mac.
S cal
Cyclopoid Copepoda
C bi th
M edax
T pr mex
Cladoi era
1, kind
I' pi'd
D leuch
S t-ryst
H gib
D gal me
D long
D re t ro
C lac
C quad
Cer ret
B long
E coreg
D dent
A harp
A affin
A quad
C sphaer
E lamell
Clad imm.
Calan Tot (#/mf)
Calan Tot (Z)
Cyclo Tot (tf/m3)
Cyclo Tot ('/.)
Clad Tot (#/m3)
Clad Tot (%)
Grand Total
I
Sep 19

16-S


2 j
113
651

221
138



80



98



258
3660
15
1262




182






95
1148
16.9
80
1.2
5570
81.9
6798
-i
Sep 19

22 >S


34
76
433

187
25



34



51



204
1485
59
416




59






17
755
24.8
34
1.1
2291
75.2
3046
3
Sep 19

53-S


10

206
3
250
50
7



3


27



63
786
30
353
3
3

3
23






63
5?6
27.9
3
0.2
1354
71.9
1883
4
Sep 19

19-i-S


35
20
205

649
50



75







75
114)
72
379




40






80
2842
60.4
75
1.6
1787
38.0
4704
5
Sep 19

U-S


43
19
272

693
39



69



14

8

79
949
191
461




43






114
1066
35.6
69
2.3
1859
62.1
2994
6
Spp 19

12->S


,j
5
389

556
9
5


185
19
5

6r>

19

56
1181
301
509
5


5
28


14


14
51
1015
29.2
209
6.0
2248
64.7
3472
7
Sep 18

14-^S


19
19
40
2
1384
21
32


89
4


17
?


45
359
125
229
2


4
13






2
1517
63.0
93
3.9
798
33.1
2408
8
Sep 18

28>S


13
14
56

390
46



23



22
9


145
447
23
212



9
15






44
519
35.4
23
1.6
926
63.1
1468
9
Sep 18

41 *S


b
10
87
11
439
29
17


10



1
1
1

34
310
94
174



4
30






25
599
46. /
to
0.8
674
52.5
1283
11
Sep 18

il >S


36
164
187
9
2477
70
6


899



2l»



138
702
252
395
6


59
59






135
2969
52.7
899
16.0
1766
31.3
5634
12
Sep 18

15>S


274
86
313
8
1661
251
8


533



2/i



133
1598
157
721




47






78
2601
40.5
533
8.3
2758
42.9
6425
14
Sep 19

25^5


31
85
168

402
57



30
13


33

6

271
1628
207
664




98






164
743
19.3
43
1.1
3071
79.6
3857
15
Sep 19

26 >S


7
42
99
1
184
92



67



1?



276
1206
78
393




110






78
431
16. i
67
2.5
2173
81.4
2671
1 b
Sop 19

21 -S


7
47
214

107
65



87
18


21
l>


152
1342
56
480




107






83
440
15.7
105
3.7
2258
80.6
2803

-------
    App. F.2  cont.



    Cruise:  2
NJ
Station:
Date:
Tow length
in meters:
Spei les:
Calano i >, f.opepoda
D ash
D min
1) oreg
D siclis
D cops
E lac
L mac
S cal
Cyclopoid Copepoda
C bi th
M edax
T pr mex
Ciadocera
1 kind
peil
n leuch
S cryst
H gib
D gal me
D long
D retro
'.' lac
C quad
Cer ret
B long
E coreg
D dent
A harp
A affin
A quad
' sphaer
F lamell
Clad imm.
Calan Tot (#/tn''l
Calau TOL (7,)
Cyclo Tot (#/m ')
Cvc lo Tot (%)
Clad Tot (0/m')
Clad Tot (%)
Grand Total
17
Sep 19

9>S


23
26
153
4
428
167



57



31

8

46
757
125
728



7
80






80
HOI
29.
57
?
1862
68.
2720
18
Sep 19

15-+S


44
94
120

344
109



87



33



65
H3H
159
470
1



65






48
71 I
n /$.
8;
1 1.
1679
.5 67.
2477
19
Sep 19

24->S


6
46
140
3
334
50
4


31



25

4

46
631
106
28h




34






19
583
7 3J.O
31
1 .8
1151
,8 65.2
1765
22
Sep 19

18*S



32
199

477
103



88
8


H

8

167
1464
111
493




103






103
8H
""<•. j
96
4
2457
73.0
3364
23
Sep 19

17»S


34
47
195

297
115



64
4


17
4


93
806
64
675




85
4





30
088
n i
68
'* 7
J778
70.2
2534
24
Sep 18

18 >S


62
131
304
6
2712
92



296
14


33

14

119
855
215
562
8


13
169






45
1307
58
31H
5 j
•-•03)
36.0
5650
24
Sep 17

18>8


108
49
517
3
5253
167
34


221
27


38
11


27
699
186
569



10
70






128
6131
75. :>
.'48
3.1
1738
21.4
8117
24
Sep 17

8->-S


191
60
180
7
1956
131



166




11


110
1171
53
488



21
233






32
2525
32. S
166
3.5
2119
44.1
4810
25
Sep 18

2^S


54
73
218

4853
174
3


522
13


25
3


130
623
196
547
3


41
158






54
5375
69.9
535
7.0
1780
23.1
7690
26
Sep 18

33^17


13

35
25
4038
15
164
16

115
22


4

2

31
138
107
82



16
51






11
4306
88.1
137
7.8
442
9.0
4885
26
Sep 18

17 *S


147
12
96

8613
189



581
21


6"!

60

231
1099
389
407



63
201






174
9057
73-4
602
4.9
2687
21.8
12346
27
Sep 18

5CH-15


4
3
27
12
3279
28
149
24

144
4


7



62
322
83
150



33
29






10
3526
80.;
148
3.4
696
15.9
4370
27
Sep 18

15->S


31
20
87
17
6286
117
7


615
37


27

49

219
1455
312
497



107
229






95
656S
64 . H
652
6.4
2985
29. J
10202
28
Sep 18

61 -S


9
29
36
1
3322
25
49
1

211
i


1.

10

55
204
1?6
120

1

49
46




1

14
347?
80. i
2)3
4.9
6 \~>
I4./
4322

-------
    App. F.2 cont.
    Cruise:   2
oo
Station:
Date:
Tow length
In meters:
Species:
Calanoid Copepoda
D ash
D min
D oreg
D siclis
D cops
E lac
L mac
S cal
Cyclopod Copepoda
C bi th
M edax
T pr mex
Cladocera
L kind
P peel
D leuch
S cryst
H gib
D gal me
D long
D retro
C lac
C quad
Cer ret
B long
E coreg
D dent
A harp
A affin
A quad
C sphaer
E lame 11
Clad imn.
Calan Tot (#/m:')
Calan Tot (%)
Cyclo Tot (#/m3)
Cyclo Tot (%)
Clad Tot (#/m3)
Clad Tot (%)
Grand Total
29
Sep 18

/O»20


3
2
3
17
3307
2
131
10

57
3






9
17
19
8



20
12






1
3475
96.0
60
1.7
86
2.4
3621
29
Sep 18

2O*S


9
4
99
9
4646
39
57
8

764
8


9

13

197
803
279
302



113
69






22
4871
63.4
772
10.4
1807
24.3
7450
JO
Sep 17

44>13


27
2
15
29
8728
14
61
4

222
2


5



42
83
61
36

1

29
7






5
8880
94.7
224
2.4
269
2.9
9373
30
Sep 17

13->S


106
4
137
20
7534
27
35


584



12
8
4

353
893
615
278



204
74






51
7863
71.9
584
5.3
2492
22.8
10939
11
St-p 18

25-S


4
4
116
11
3779
22



851
17


1 7

4

177
15V
435
989



225
50






74
<936
47.2
868
10.4
3528
42.3
8332
)«
riep 1 /

21 -S


41
98
98

3191
112
7


324
11


15

15

50
648
123
818



14
236






0 1
ISA/
60.5
335
5.7
1982
33.8
5864
19
Sep 17

43-»S


28
60
92

5103
101
32


224
11


14

14

267
515
89
261



8
234






7j
-.416
"6.0
235
3.3
1475
20.7
7126
40
Sep 17

11+S


73
252
75

2129
488



132
L7


">/
9
9

531
1353
64
469



92
323






/8
3017
49.0
149
2.4
2985
48.5
6151
41
Sep i;

53 '15


5
5
15
20
1917
25
193
14

52
15


1



7
105
7
17



3
20






i
2194
90.5
67
2.8
163
6.7
2424
41
Sep 1 7

15»s


22J
204
289
51
3599
119



509
10?


51

17

526
3480
68
458



17
306






68
4483
44.5
611
6.1
4991
49.5
10085
42
Sep 17

7S./5


1
1
2
12
622
1
157
8

41
3


2



2
46
9
5



11
11






2
804
85.9
44
4.7
88
9.4
936
42
Sep 17

2S-S


132
112
214
10
5132
204
10


856
20


61
10
20

224
2282
122
153



92
214






51
5814
58.6
876
8.8
3229
32.6
9919
43
Sep 17

83-20


1
2
13
9
2151
7
70
5

101
1


1 /

5

41
217
25
32



13
21






17
-'258
82.2
102
3.7
388
14.1
2748
43
Sep 1 /

:o-s


1 1 ^
2')
140
1 3
9983
51
51


M'>
13


1H

38

407
3069
216
280



153
140






204
I037H
66.6
658
4.2
4545
29.2
15581

-------
App. F.2  cont.
Cru1SP•  J
Station: 4o
Date: Sep 17
Tow length
in meters: 122-20
Species:
Calanoid Copepoda
D ash 1
D min
D oreg
D siclis 8
T) cops 1053
E lac 1
L mac 119
S cal 12
Cyclopoid Copepoda
C bi th 12
M edax 1
T pr mex
Cladocera
L kind
P ped
D leuch
S cryst
H gtb 1
!) g^l me 1
D long 2
n retro ?
C lac
C quad
Cer rei
B long 3
F. roreg 2
D dent
A harp
A affin
A quad
C sphaer
E lamell
Clad imm.
Calan Tot (*/V) 1194
Calan Tot (%) 97
Cyclo Tot (ff/tn'1 13
Cyclo Tot (7) 1 .
Clad Tot H//ro') 1 •
i:lad Tot (/.) i.
Grand lotat '-'22
•4*4
Sep 17

20-S


42
95
lj
38
8242
45
62


469
13


13

15

250
1441
93
•14



85
23






89
8539
7 75 9
48/
.1 4. <
222'i
. t 19 <<
ll.>44
45
Sep 17

84-25


2

6
16
1315
I
159
4

50
6


1

1

12
22
17
13



13
5




1

2
1503
9L.3
5b
J.4
H1
j. i
164h
45
Sep I/

25-S


73
17
166
17
6478
36
5


620
12


12

27

2bl
1723
200
462



536
63






68
6792
63.0
632
5.9
•152
11. J
11)776
46
Sep 17

34>13


49
5
283
38
8423
29
4:3


343
19


3

11

22
547
136
509



82
11






35
8872
81 P
)bx
3.4
1 Cih
12 -
10S9<.
46
Sep 17

13->S


28
7
65

2511
30
11


460
4




51

86
758
217
759



J64
45






14
?652
49."
464
J* h
j;;q-
'2.4
•«.!
47
Sep 17

26-12


22
9
124
32
10924
24
5


223
12




13
3

347
313
181



65
3






35
11140
90 1
235
1 . v
Qfcn
.P
| ' | is
4/
Sep 17

12 -S


21
/
H

1914
149
11


357
4


1 1

35

2->
294
110
272



683
25






18
2111
'"•I. ')
361
9. 1
14.' '
i • '
39«,
4h
Sep 17

20->10


45
6
166
34
7920
130
3


170





H

7
699
246
337
3
4

31
)






39
8104
84.1
I 70
1 . '
\ '• 1
14 .0
W>\
48
Sep 17

10->S


13

53
3
4258
125



171
3





5
18
<•< '36
9,"
423



229
23




5

23
4452
'5.4
174
2.9
1? '9
_' |
590".
49
Sep 17

59-25


1

7
16
2664
132

8

40
4






3
178
4
11



17
4






19
2828
9J .0
6',
| £J

14541
50
Sep 17

32-10


24

55
17
10544
3
43


446
3


16

4

197
481
119
17J



86
.?3




4

103
10684
86 h
4^9
3.6
1 704
9. •<
1 'It/
50
Sep 17

10>S


71

173
2U
4329
?0
10


1039
10


.'(i

20

295
2017
'/S
91 '



1/b
10







462»
4H.4
lO/i 9
1 1 .(i
IKpn
't): t>
')')•

-------
Appendix F.3



Cruise:  3
Station :
Date:
Tow length
in meters:
Species:
Calanoitl Copopml.i
D ash
D min
D oreg
D siclis
D cops
E lac
L mac
S cal
Cyclopoid Copepoda
C bi th
M edax
T pr mex
Cladocera
L kind
P ped
D leuch
S cryst
H gib
D gal me
D long
D retro
C lac
C quad
Cer ret
B long
E coreg
D dent
A harp
A affin
A quad
C sphaer
E lamell
Clad imm.
Calan Tot (#/m3)
Calan Tot (%)
Cyclo Tot (#/mJ)
Cyclo Tot (%)
Clad Tot (#/m')
Clad Tot (%)
Grand Total
1
Oct 6

15--S


444
235
J66
13
9272
457



1854
104


91

39

392
2847
26
2089



692
131




26

379
10787
55.4
1958
10.1
6712
34.5
19457
2
Oct 6

23-+S


97
29
73
24
3124
354



500
19


34

15

160
1106
5
490



68
267




5

330
3701
5'>. 2
519
7.7
2480
37.0
6700
3
Oct 6

38^15


26
17
28
1
2008
100



181
12


8

h

36
216
6
163



19
79
1





47
2180
73.8
193
6.5
581
19.7
2954
3
Oct 6

15-+S


88
78
204

5826
689



940
17


48

27

136
2200
7
1508



71
407



14
17

336
6885
54.6
957
7.6
4771
37.8
12613
4
Oct 6

25->S


16S
146
142
18
4698
120



744



13



337
2458
4
607



44
248






208
5292
53.2
744
7.5
3919
39.4
9955
5
Oct 6

16 >S


7'-)
36
46
20
3142
142



496
30


13

10

116
1042

443



36
136






53
3465
59. <
526
9.0
1849
18.6
5840
6
Oct 6

12+S


'2
7
41

1962
26



1493
21


14

15

63
651
n
>47



95
186






107
2058
)8.6
1514
28.4
1750
33.0
5322
7
On 6

12>S


10
20
41
20
5724
153

20

1569




20


448
2047
61
346



1721
285






479
5988
49.1
1569
15.5
2571
25.4
10128
8
Of ( 6

23 >S




h

4693
55



1686
6




30

109
1728
18
164



176
273






73
4754
52.;
1692
18.8
2571
28.5
9017
9
Od h

41>S


104
26
287

5173
131



1254







2089
6216
78
H62



575
366






496
5719
32.4
1254
7.1
10682
60.5
17655
10
Or 1 h

23*14


25
1 1
40
15
4667
40
29


357







113
327
113
62



44
55






15
4827
81.6
357
6.0
729
12.3
5913
10
<)( t 6

14 >S


2J1
47
1 SJ
152
10702
156
7


1833
18



15


1855
8345
189
557



211
422






819
11406
44.4
1851
7.2
12413
48.4
25670
1 1
Oct t>

iJI >S


88
53
53
70
6375
73



896




Irt
53

1633
4373
105
246



351
263






316
6712
44.8
896
6.0
7358
49.2
14966
1 '
MI i (,

14 -S


170

191
64
846/
170



95S



21

1\

231 J
4987
424
2J3
21


509
297






1231
9062
45
955
4
10057
50
20074

-------
App.  F.3 cont.



'•ruise:  >
Station:
Date:
Tow length
in meters:
Species:
Calanoid Copepoda
1) ash
D min
D oreg
D siclis
D cops
E lac
L mac
S cal
Cyclopoid Copepoda
C bi th
M edax
T pr mex
Cladocera
i, kind
P ped
D leuc.h
S cryst
H gib
D gal me
D long
D retro
C lac
C quad
Cer ret
B long
E coreg
D dent
A harp
A affin
A quad
C sphaer
E lamol 1
Clad 1mm.
Calan Tot (ff/m')
Calan Tot (%)
Cyclo Tot (it /at'')
Cycle Tot (%)
Clad Tot (#/niM
Clad Tot (%)
Grand Total
13
Oct 8

22->S


204
166
178

5157
509



1502
38


13

25

993
4100
38
980



153
815






586
6214
40.
1540
10.
7?03
49.
15457
1.4
Oct 8

24*S


35
100
93
54
3715
305



583
46


1 <>

8

606
1848
27
278



46
46''






390
4302
, 2 50 .
629
.0 7.
JbKl
,« 42.
861 '.'
15
Oct 8

25>S


50
66
28
39
3997
149
6


576
11


6

11

161
1268

454



72
637






316
4335
.0 55.2
587
3 7.5
2925
. v (7 . t
7847
16
Oct 8

i7>S


92
75
59
70
6227
324



779
32


14

20

284
1429
63
837



68
J62






390
6847
61.5
811
7.3
3467
31.2
11125
17
Oct 8

14-8


46
24
81
18
2527
209
2


142
7


4

i

156
532
14
137



68
163






58
2907
69.4
149
3.b
11 (4
n \
4J"0
ib
Oct 8

!5->S


131
176
52
52
5158
340



803
20




33

307
2638
26
516



104
620






24*
5909
52.6
823
7.3
4492
40.0
1 1 n-'t
19
Oct 8

24 >S


21
63
99
52
3423
94



496
37


21

21

271
1085
16
230



125
287






292
3752
58.4
533
8.3
2141
33.3
b42f>
20
Oct 8

I 7->S


68
91
68
79
8451
136



849
11


23

68

1720
2422
136
181



306
487






160
8893
58.3
860
5.6
5503
36.1
L5256
?1
Oct 8

13+S


93
46
139
69
7209
46



1313





46

995
5024
278
995



324
278






162
7602
44.7
1313
7.7
81(12
47. b
17017
22
Oct 8

20*S


57
66
12.5
172
9682
7



1294
42


7

59

974
2568
113
262



184
865






309
10109
60.2
]33ft
8.0
5 '341
31 .8
16786
23
Oct 8

17'K


59
34
140
64
8153
306
4


938
2S


25

2J

$61
896
136
488



119
301






144
876U
71.7
963
7.9
2491
20.4
12J14
24
Oct 7

17-S


25
25
45
14
2795
182



595
Jl>


y
}
6

73
446
45
219



126
140




3

51
3086
64.1
615
12.8
1115
23.2
4816
?4
O( t 8

1"? -S


10
13
159
73
7169
109



932
30


H

8

394
925
111
361



136
371






45
7533
69.4
962
8.9
2359
21.7
10854
2'j
Oct 8

25-»S


66
133
421
133
9632
576
22


2081



22

66

2059
8171
244
.1.528



266
509






288
109H)
41.9
20M1
7.9
1 H 5 '<
'>(). /
2M\ 1

-------
   App.  F.3 cont.
    Cruise:  3
NJ
Station:
Date:
Tow length
tn meters:
Species:
Calanoid Copepoda
D ash
D min
D oreg
D siclis
D cops
E lac
L mac
S cal
Cyclopod Copepoda
C bi th
M edax
T pr mex
Cladocera
t kind
P ped
D leuch
S cryst
H gib
D gal me
D long
D retro
C lac
C quad
Cer ret
B long
E coreg
D dent
A harp
A affin
A quad
C sphaer
E lame 11
Clad imm.
Calan Tot (#/m3)
Calan Tot (%)
Cyclo Tot (#/m3)
Cyclo Tot (%)
Clad Tot (#/m3)
Clad Tot (%)
Grand Total
26
Oct 8

33->S


33
82
246
66
12387
49



2530
99




164

854
3779
1068
789



378
756






411
12863
54.3
2629
11.1
8199
34.6
23691
27
Oct 8

49>33


5

78
112
5968
5
332
39

509
15


--,



107
87
5
15



61
24






7
6539
88.7
524
7.1
311
4.2
7374
27
Oct 8

33->S


39

177
170
12608
31



1968



15

39

486
1999
147
224



231
556






170
13025
69.1
1968
10.4
3867
20.5
18860
28
Oct 8

63->44


11

41
112
3666
3
384
37

233
10


4

7

72
172
3
16



27
23






20
4254
87.9
243
5.0
344
7.1
4841
28
Oct 8

44 »S


58
46
58
116
7060
382



1030





23

625
2558
35
231



278
208






162
7720
60.0
1030
8.0
4120
32.0
12870
29
Oct 8

71>40


4

18
65
2456
2
160
10

196
4


1

4

29
27
2
1



6
10






1
2715
90.6
200
6. /
81
2. '
2996
29
Oct 8

40+S


19
19
153
57
8206
25
6


1127
19


6

64

236
1986
64
376



191
363






32
8485
65.5
1146
8.9
ms
25.6
12949
30
Oct 7

41 *30




10
10
1384

23


57





5

3
26
5




21
3







1427
92.2
57
3.7
63
4.1
1547
30
Oct 7

30->S


8
59
68
34
6221
59



1282
17


M
68
42

696
1961
42
297



416
272






263
6449
54. h
1299
11.0
4065
34.4
L1813
30
Oct 8

40->2h


17

29
25
4477
15
2


341



4

31

44
114
10
42



75
42






25
4565
86.2
341
6.4
387
7.3
5293
30
Oot 8

26> S


98
59
235
118
11008
118



1743
59


20

98

627
3761
78
627



392
1097






39
11636
57.7
1802
8.9
6739
33.4
20177
31
Oct 8

25.=;


44
44
177
89
7396
66



1506
44


66

13)

2901
7883
199
1395



531
841






664
7816
32.6
1550
6.5
14613
60.9
23979
32
Oct 6

19 -S


/")
45
60

8434
30



1932
45


IS

90

1393
7879
240
1348



240
360






584
8644
38.0
1977
8.7
12149
53.4
22770
3:)
Or t 6

Ik >K


46
46
116
116
9213
35



1377





162

683
2616
93
208



289
313






185
9572
61.8
1377
8.9
4549
29.4
15498

-------
   App.  F.3 con t.
   Cruise:   3
u>
Station:
Date:
Tow length
in meters:
Species:
Calanoid Copepoda
D ash
D min
D oreg
S siclis
D cops
E lac
I, mar
S ral
Cyclopoid Copepoda
C bi th
M edax
T pr mex
Cladocera
L kind
P ped
D leuch
S cryst
H gib
D gal me
D long
D retro
C lac
C quad
Cer ret
B long
E coreg
D dent
A harp
A affln
A quad
C sphaer
E lamell
Clad iiran.
Calan Tot (#/m3)
Calan Tot (%)
Cyclo Tot (#/m3)
Cyclo Tot (%)
Clad Tot (#/m')
Clad Tot (%)
Grand Total
34
Oct 6

38*25



2
J6
13
2077
6
2


189
2


4

2

46
40
8




2
11







2136
87.5
191
7.8
113
4.6
2440
34
Oct h

25*S


92
20
102
102
H865
31



2078





194

591
3392
9?
285



173
479






418
13212
63.
2078
9.
5624
26.
20914
35
Oct 6

48*38




I
32
897
6
214


90
9






17
35
6
3




9







1152
.2 87 . 2
99
,9 7.5
70
.9 5.3
1321
35
Oct 6

38*S


47
7
47
34
6976
74



IO"/40


3



279

253
6

12







J
4

I



1








541
96.3
12
> .]
9
1.6
562

-------
App .  F.3  cont.



Cruise:  3
Station:
Date:
Tow length
in meters;
Species:
Caianoid Copepods
D ash
D min
D oreg
D siclis
D cops
E lac
L mac
S cal
Cyclopoid Copepoda
C bi th
M edax
T pr mex
<;ladcc.era
I, kind
P pcd
D leuch
S cryst
H gib
D gal me
D long
D retro
C lac
C quad
Cer ret
B long
E coreg
D dent
A harp
A affin
\ quad
'' sphaei
E lame 11
Clad imm.
Calan Tot (#/nr)
Calan Tot (%)
Cyclo Tot (#/m3)
Cyclo Tot (%)
Clad Tot (#/m3)
Clad Tot (%)
Grand Total
42
Oct 7

40-S


6
13
41
19
2820
67



245



10



236
694
16
67



38
131






159
2966
65.0
245
5.4
1351
29.6
4562
43
Oct 7

81 • 15





11
141

257
20

12
1




1

13
2

1




3






1
429
92.7
1 i
2.8
21
4.5
463
43
Oct /

35-S


7
22
87
65
7770
58



822



16

22

742
2168
7
29



160
226






175
8009
64. 6
822
0.7
3565
28.8
12396
44
Oct 7

120-50





6
89

129
11

6
1






5
3






1







235
93.6
7
2.8
9
3.6
251
,,
Oct 7

50-b


20
61

41
4828
20



611





31

306
1813
10
163



71
173






51
4970
60 6
611
7.5
2618
31.9
8199
45
Ocl .'

85>LS


1
1
6
22
1487
2
16
1

154
8


2

1

10
54
7
8



11
10






1
1536
85 _'
162
9.0
104
5.8
1802
4'>
Oct 7

15-S


42
127
102
136
5467
34



1664



17

34

679
4015
119
382



212
323






289
5908
4 >.. i
Lbbt
12.2
6070
44.5
1J642
46
Ocr 7

34-18


10

63
78
5738
2
5


413
12




2

12
218
21
17



61
17






26
5896
88.1
425
6.3
374
5.6
6695
46
Oct 7

18-S


7
28
134
5
7894
71



1344
7


1.4
7
113

325
1938
57
297



531
467






226
8139
60.4
1351
10.0
3975
29.5
13465
47
Oct 7

25-S


19

123
78
6873
13
4


590
15




46

194
454
45
172



340
95






51
7110
78.0
605
6.6
1397
15.3
9112
48
Oct 7

20-S


6
1
72
42
3379
5
1


490
5


12
3
37

44
224
14
120



228
28






28
3506
74.0
495
10.4
738
15.6
4739
49
v
-------
Appendix  F.4

Cruise:   2  Lake Michigan

      Station:
      Date:
      Tow length
      in  meters:
                     13
                   Sep 23

                    185
                                            20
                                          Sep 21

                                           110
  21
Sep 21

  90
  22
Sep 21

 117
  23
Sep 21

 162
  24
Sep 21

 164
  25
Sep 21

 151
  26
Sep 21

  55
  27
Sep 23

  84
 Species:
 Calanoida  Copepoda
      D ash
      D min
      D oreg
      D siclis
      D cops
      E lac
      L mac
      S cal
2
2
9
37
76
1
97
2
5
6
80
144
780
24
38
2
8
3
55
79
424
17
29

18
3'
87
67
244
24
64

11
1
64
34
191
52
60
1
7
2
58
28
136
4
60
1
J

41
37
96
2
66
1
40
10
172
8
301
3
14

23
11
90
45
415
3
70

 Cyclopoid Copepoda
      C bi th
      M edax
                                 17
                                 24
                                                        14
                                                        28
               7
              21
              13
              17
               7
              20
               2
              10
              25
              29
              28
              25
Cladocera
     L kind
     D leuch
     H gib
     D gal me
     D long
     D retro
     C la<
     C quad
     B long
     E coreg
     A harpae
     C sphaer
     Clad  imm.


4
15

15
1

i
5
6

68
295

189

2
2
35
8
2
20
199

109
2


4 !
6
1
8
104
1
120



M
                                                                                  6
                                                                                  1

                                                                                 95

                                                                                 89



                                                                                 22
                                                                                  3
                                                                                  2
                                                                                  7
                                                                                 82

                                                                                 86
                                                                                             40
5
1
10
32
28

2

29
298
427
2
5
2
42
171
399
5
                                                                                                         13
                                                                                                                    223
                                                                                                                                101
  Calan Tot
  Calan Tot
  Cyclo Tot
  Cyclo Tot
  Clad Tot
  Clad Tot
 (#/m1)
 (%)
 (#/n>3)
 (%)
(0/ml)
(%)
  Grand Total

  Amphipoda
       P. aff. (# in sample)
226
81
10
4
43
15
279
1079
63
41
2
599
)5
1719
615
59
42
4
385
37
1042
507
62
28
3
283
35
818
414
63
30
5
213
32
657
296
54
27
5
223
41
546
246
71
12
3
89
26
347
548
34
54
3
989
62
1591
657
46
53
4
725
51
143r>
  Mysidace«
       M.rel.  (/'  in sample)
                                 156
                                                                                 96
                                                                                             32
                                                                                                        105

-------
App.  F.4  cont.

Cruise:  2 lake Michigan

     Station:
     Date:
     Tow length
     in meters:
  28
Sep 23

 166
  44
Sep 23

  10
                                                        45
                                                      Sep 23

                                                       274
  46
Sep 23

 272
  47
Sep 23

 123
  48
Sep 23

  12
  52
Sep 20

  33
  53
Sep 20

  24
  54
Sep 20

  17
Species:
Calanoida Copepoda
     D ash
     D min
     D oreg
     D siclis
     D cops
     E lac
     L mac
     S cal
  12
   3
  43
  25
 130
   9
  72
   2
  60
  11
  64
  64
 718
  67
 191
8

30
•21
68
1
73

3
1
17
17
46
3
70
2
11
3
81
37
137
9
89

31
22
91
31
149
98
40

30
5
241
3
386
27
14

93
8
305
4
880
127
12

145
17
490

1254
25
6

Cyclopoid Copepoda
     C bi th
     M edax
  13
  17
 110
   7
                                                                                6
                                                                               21
                          40
                          11
                          14
                          14
                          96
                          12
                         149
                          25
Cladocera
     L kind
     D leuch
     H gib
     D gal me
     D long
     D retro
     C lac
     C quad
     B long
     E coreg
     A harpae
     C sphaer
     Clad imm.

Calan Tot  (#/m3)
Calan Tot  (%)
Cyclo Tot  (#/m3)
Cycle Tot  (%)
Clad Tot (#/m3)
Clad Tot (%)
Grand Total
                              2
                              1
                             21
                            120

                            169
                              2
                             73

                              1
                            296
                             41
                             30
                              4
                            389
                             54
                            715
                 28
                  7
                258
                672

               1337
                 18
                343
                  7
               6
              39

              55
               1
2

19
37

78


14
4
1
21
103

62
3

46
14
7
48
424

213
3

170
19

49
496

249


99
46

147
945
15
455
8

93
19
6
45
870
64
687
4
4
89
1175
30
117
3
2670
67
3962
201
58
9
3
136
39
346
159
50
7
2
150
47
316
367
58
27
4
240
38
634
462
33
51
4
879
63
1392
706
43
28
2
912
55
1646
1429
44
108
3
1709
53
3246
1937
50
174
4
1788
46
3899
Amphipoda
     P. aff.  (If in sample)
Mysidacea
     M. rel.  (#  in sample)
  26
                            L67
                                        201

-------
                                   TECHNICAL REPORT DATA
                           (Please read Instructions on the reverse before completing)
   EPA-600/3-76-095
                                                           !. RECIPIENT'S ACCESSION-NO.
 TITLE AND SUBTITLE

BIOLOGICAL,  CHEMICAL AND  PHYSICAL RELATIONSHIPS IN THE
   STRAITS OF MACKINAC
              5. REPORT DATE
               September 1976 (Issuing
              6. PERFORMING ORGANIZATION CODE
 AUTHOR(S)
. Mw I nwn\o/

C. L.  Schelske, E. F. Stoermer, J. E. Gannon  and
   \g   C>   O J	
              8. PERFORMING ORGANIZATION REPORT NO.
   M.  S.  Simmons
i. PERFORMING ORGANIZATION NAME AND ADDRESS
 Great Lakes Research  Division
 University of Michigan
 Institute  of Science  &  Technology Bldg.
 Ann Arbor,  Michigan   48109
              10. PROGRAM ELEMENT NO.
                  1BA608
              11. CONTRACT/GRANT NO.

                R 802721
12. SPONSORING AGENCY NAME AND ADDRESS
  Environmental Research  Laboratory-Duluth
  Office of Research  and  Development
  U.S.  Environmental  Protection Agency
  Duluth, Minnesota   55804
              13. TYPE OF REPORT AND PERIOD COVERED
                Final Report-7/1/73-9/30/74
              14. SPONSORING AGENCY CODE

                 EPA-ORD
15. SUPPLEMENTARY NOTES
16. ABSTRACT
     Three cruises were  conducted from August  to October 1973 in the vicinity of the
 Straits  of Mackinac.  Environmental conditions were  influenced  by the net transport of
 water  from Lake Michigan  to Lake Huron, the oscillatory flow of water produced by
 seiches  between the two lakes and the hypolimnetic transport of water from Lake Huron
 to Lake  Michigan during periods of thermal stratification.   Different water masses  re-
 sulted from the mixing of waters from Lake Huron, Lake  Michigan and Lake Superior and
 were identified from single parameters, particularly silica, nitrate, pH,  temperature
 and  specific conductance,  from cluster analysis of chemical  and physical parameters
 and  from ordination analyses of phytoplankton and zooplankton assemblages.
     Lake Michigan waters  transported through  the Straits  represent a diffuse and rela-
 tively small phosphorus enrichment for Lake Huron, but  were  depleted in silica and
 nitrate  compared to Lake  Huron.  In August and September  phytoplankton in the silica
 depleted waters from Lake Michigan were dominated by blue-green algae.  The phytoplank-
 ton  assemblages in the Straits were distinct  from those in the  open waters  of Lake
 Michigan and Lake Huron.   Zooplankton species composition was similar at the 50 sta-
 tions  sampled, but cladocerans were proportionately  more  prevalent in the more eutro-
 phic waters of Lake Michigan than were calanoid copepods  in  Lake Huron.   It was con-
 cluded that water from Lake Michigan had a subtle deleterious effect on water quality
 in Lake  Huron.                 _^____	.	•	
                                KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
                                              b. IDENTIFIERS/OPEN ENDED TERf
  Nutrients, phosphorus,  silica,
  chlorophyll, phytoplankton,  zooplankton.
13. DISTRIBUTION STATEMENT

       RELEASE TO PUBLIC
  Straits of Mackinac
  Lake Michigan
  Lake Huron
  Ordination Analyses
  'Cluster Analyses
  Eutrophication
  Communities
  19. SECURITY CLASS (ThisReport)
    Unclassified
  20. SECURITY CLASS (This page)
    Unclassified
 06C
 08H
21. NO. OF PAGES

   285
                            22. PRICE
EPA Form 2220-1 (9-73)
267   # U.S. GOVERNMENT PRINTING OFFICE: 1976-757-056/5Jti<3 Region No. 5-11

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