WATER POLLUTION CONTROL RESEARCH SERIES • 16060 EGS 01/71 INFILTRATION RATES AND GROUNDWATER QUALITY BENEATH CATTLE FEEDLOTS, TEXAS HIGH PLAINS ENVIRONMENTAL PROTECTION AGENCY • WATER QUALITY OFFICE ------- WATER POLLUTION CONTROL RESEARCH SERIES The Water Pollution Control Research Series describes the results and progress in the control and abatement of pollution in our Nation's waters. They provide a central source of information on the research , develop- ment, and demonstration activities in the Water Quality Office, Environmental Protection Agency, through inhouse research and grants and contracts with Federal, State, and local agencies, research institutions, and industrial organizations. Inquiries pertaining to Water Pollution Control Research Reports should be directed to the Head, Project Reports System, Office of Research and Development, Water Quality Office, Environmental Protection Agency, Room 1108, Washington, D. C. 20242. ------- INFILTRATION RATES AND GROUNDWATER QUALITY BENEATH CATTLE FEEDLOTS, TEXAS HIGH PLAINS by Texas Tech University Department of Geosciences Lubbock, Texas 79409 for the WATER QUALITY OFFICE ENVIRONMENTAL PROTECTION AGENCY Project #16060EGS Contract f 14-12-804 January, 1971 For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402 - Price 65 cents Stock Number 5501-0125 ------- EPA Review Notice This report has been reviewed by the Water Quality Office, EPA, and approved for publication. Approval does not sig- nify that the contents necessarily reflect the views and policies of the Environmental Protection Agency, nor does mention of trade names or commercial products constitute endorsement or recommendation for use. 11 ------- ABSTRACT Detailed field and laboratory studies of five feedlots were conducted to determine field seepage rates and distributive geometry of infiltrated runoff. Practical field seepage rates at these sites ranged from 2 to 20 feet/year. Disper- sal rates of ions in the groundwater zone varied from 45 to 400 feet/year. Nitrogen (N03, NC>2, NH4, Org-N) and common chemical parameters (Ca, Mg, Na, K, Cl, 804, TDS, pH, and conductance) were deter- mined in cores and groundwater samples; based on groundwater analyses from 80 Texas High Plains feedlots, rates of con- centration of NOj-N and Cl in groundwater beneath feedlots range from 0.07 to 0.4 p.p.m. per year, and average 0.17 p.p.m. per year. Laboratory determined constant head vertical permeability of cores from 22 feedlot sites revealed a range in values of lO'2 to 10-6 cm/sec for Ogallala sediments, 10~4 to iO'7 cm/sec for near-surface material of floodplains and feedpen- runoff surfaces, and values of 10~6 to 10~8 cm/sec for playa clay. Factors related to runoff-infiltration were correlated with groundwater quality, and it was determined that local surfi- cial material and regional soils patterns are closely related to quality of groundwater beneath feedlots. Direct correla- tion of water quality does not exist with feedpen-runoff slope, cattle load, and surface-area ratios of drainage basin to collection system. This report is submitted in fulfillment of Project Number 16060EGS, Contract Number 14-12-804, under the (partial) sponsorship of the Water Quality Office, Environmental Pro- tection Agency. Key Words: Nitrates, groundwater quality, Ogallala Forma- tion, core chemistry, permeability, High Plains geologic environment. 111 ------- CONTENTS Section Page I Conclusions 1 II Recommendations 3 III Introduction 5 Study Sites 5 Field Methods 9 Laboratory Methods 10 Nitrogen Cycle 11 IV Discussion of Study Area 13 Geomorphology-Geology 13 Groundwater 16 V Infiltration-Groundwater Quality Relationships 18 VI Field Infiltration Rates and Dispersal Rates in Groundwater 21 Field Site I 21 Field Site II 27 Field Site III 30 Field Site IV 39 Field Site V 42 Other Sites 42 VII Acknowledgments 53 VIII References Cited 55 ------- FIGURES NO. PAGE 1 LOCATION OF CATTLE FEEDLOTS INVESTIGATED IN STUDY, TEXAS HIGH PLAINS 6 2 AGE DISTRIBUTION OF FEEDLOTS IN STUDY 7 3 APPROXIMATE AVERAGE CATTLE LOAD ys_ YEAR FEEDLOT ESTABLISHED 8 4 GENERALIZED SOIL TEXTURE MAP, TEXAS HIGH PLAINS ... 15 5 DISTRIBUTION OF OBSERVATION WELLS, FIELD SITE I ... 22 6 GAMMA LOG PROFILES, FIELD SITE I 23 7 SUBSURFACE HYDROLOGIC PARAMETERS, FIELD SITE I 23 8 DISTRIBUTION OF NOs-N IN GROUNDWATER, FIELD SITE I. 26 9 DISTRIBUTION OF OBSERVATION WELLS, FIELD SITE II .. 28 10 GAMMA LOG PROFILES, FIELD SITE II 29 11 SUBSURFACE HYDROLOGIC PARAMETERS, FIELD SITE II ... 29 12 DISTRIBUTION OF CHLORIDE IN GROUNDWATER, FIELD "SITE II 32 13 DISTRIBUTION OF OBSERVATION WELLS, FIELD SITE III . 33 14 GAMMA LOG PROFILES, FIELD SITE III 35 15 SUBSURFACE HYDROLOGIC PARAMETERS, FIELD SITE III .. 34 16 DISTRIBUTION OF N03-N IN'GROUNDWATER, FIELD SITE III 38 17 DISTRIBUTION OF OBSERVATION WELLS, FIELD SITE IV .. 40 18 GAMMA LOG PROFILES, FIELD SITE IV 41 19 SUBSURFACE HYDROLOGIC PARAMETERS, FIELD SITE IV*... 41 20 DISTRIBUTION OF OBSERVATION WELLS, FIELD SITE V ... 44 .21 GAMMA LOG PROFILES, FIELD SITE V 45 VI ------- NO. PAGE 22 SUBSURFACE HYDROLOGIC PARAMETERS, FIELD SITE V 45 23 DISTRIBUTION OF N03-N IN GROUNDWATER, FIELD SITE V. 48 24 AGE OF FEEDLOTS INVESTIGATED vs RANGE IN MAXIMUM N03-N CONCENTRATION IN GROUNDWATER 50 25 AGE OF FEEDLOTS INVESTIGATED vs_ RANGE IN MAXIMUM CHLORIDE CONCENTRATION IN GROUNDWATER 51 26 AGE OF FEEDLOTS INVESTIGATED vs RANGE IN MAXIMUM CONDUCTANCE OF GROUNDWATER 52 VII ------- TABLES No. Page I Relation of Feedlot-Runoff Seepage Factors to Groundwater Quality, Texas High Plains 20 II Core Chemistry, Well #8, Field Site I 24 III Groundwater Chemistry, Field Site I 25 IV Core Chemistry, Well #9, Field Site II 30 V Groundwater Chemistry, Field Site II 31 VI Core Chemistry, Well #20, Field Site III 36 VII Groundwater Chemistry, Field Site III 37 VIII Core Chemistry, Well #7, Field Site IV 39 IX Groundwater Chemistry, Field Site IV 43 X Core Chemistry, Well #9, Field Site V 46 XI Groundwater Chemistry, Field Site V 47 Vlll ------- CONCLUSIONS 1. Concentration values of ammoniacal, organic and nitrite nitrogens, calcium, magnesium, sodium, potassium, and chlo- ride in collected cattle-feedlot runoff exceed "normal" val- ues for groundwater in the Ogallala Formation. Nitrate- nitrogen in collected feedlot runoff may be found to be less concentrated than in Ogallala groundwater. The occurrence of high values of nitrate-nitrogen in Ogallala groundwater in the vicinity of a feedlot is not always prima facie evi- dence of a feedlot source. 2. Nitrite-nitrogen, ammoniacal and organic nitrogen occur in high concentrations in collected feedlot runoff. These ions usually are partially removed at the surface or retained in the unsaturated subsurface environment and do not concen- trate in the saturated zone in proportion (quantitatively) to their surface occurrence. Removal of ammonia, organic and nitrite-nitrogen is a result of nitrification-denitrification reactions as well as volatilization of ammonia. Nitrogen retention is in part accountable to clay mineral adsorption and to bacterial fixation. 3. Surficial silt-clay mixtures of feedpens and/or runoff surfaces exhibit secondary cementation in the form of root fillings, vug and pore fillings, and veinlets. Below this developed hardpan, soil densities are noticeably less and permeability values are larger. 4. The ubiquitous Texas High Plains "caprock" caliche is often porous and permeable below runoff collection systems. Secondary solution of caliche is evidenced by vugs, second- ary cementation of fractures and solution vugs, and by silt- clay-fillings in the solution vugs and voids. 5. The unsaturated zone of the Ogallala Formation is slow- to-rapidly permeable. Laboratory determined constant head vertical permeability values in the unsaturated zone range' from 10~2 to 10~6 cm/second. Laboratory determined perme- ability values of playa sediments are usually less than 10~° cm/second. Permeability values of feedpen and runoff sur- face material range from 10~^ to 10"^ cm/second. Minimum permeability of the surficial mantle and minimum permeability values of the Ogallala sediments determine practical infil- tration rates. 6. Regional soils patterns and the localized surficial sedi- ments of playas are related to groundwater quality beneath cattle feedlots. Total infiltration and infiltration rates are greater in the sandy soil zones than in the hardland ------- zones of the High Plains. The "ponding" part of playas that contain the usual clay layer are an effective barrier against infiltration of feedlot runoff. 7. Concentration in groundwater of dissolved solids derived from High Plains cattle feedlots is restricted to the vicinity of the point-source (feedlot). This is accountable to the low total volume of infiltrate, plus dilution of the infil- trate in the groundwater zone. Low total volume of infil- trate is, in large part, due to (A) low rainfall, high runoff- evaporation rates, (B) low permeability factors associated with the feedlots, and (C) secondary precipitation in the unsaturated zone. Around feedlots a significant dilution factor is the usually large flow rate (natural and induced) in the Ogallala relative to permeability rates between the watertable and the surface. Groundwater dispersal rates determined under existing field conditions show average values ranging from 45 to 400 feet per year. Actual dispersal rates are greatly dependent upon distribution and pumping rate of producing wells at the site. Where a feedlot operation uses large volumes of groundwater, significant quantities of infiltrate that reach the saturated zone are recovered by pumping. 8. Practical seepage rates determined under existing field environments range from 2 to 20 feet/year. Rates of concen- tration of NOj-N in the Ogallala Formation of the High Plains approximate 0.07 to 0.3 p.p.m. NC^-N/year. Approximate values for rate of concentration of chloride are 0.07 to 0.4 p.p.m. Cl/year. Average values for rates of concentration of chlo- ride and nitrate-nitrogen are about 0.17 p.p.m. per year. Average rates of increase in conductance values for ground- water beneath High Plains feedlots are 40-100 micromhos/cm per year. 9. There are several feedlots in this study that have con- tributed N03-N to levels approaching or exceeding recommended limits (10 p.p.m. NC^-N). Some of the lots that have degraded water quality approaching recommended limits are expected to exceed such limits in the future. On the other hand, some sites in the High Plains will probably never signifi- cantly degrade groundwater quality, the reasons being slow infiltration rates relative to groundwater dispersal rates, recycling of infiltrated runoff, subsurface impermeability at the site, and rapid dispersal of surface runoff^ No re- gional degradation of the Ogallala groundwater is expected in the foreseeable future, only degradation in specific localized areas. ------- RECOMMENDATIONS 1. Ion-balance studies are needed of nitrogen and other com- mon ions associated with feedlot runoff. As already known, the concentration of some ions, for example Ca, K, N0£, NH^, Org-N, are not quantitatively correlative from ponded runoff to the unsaturated zone to the groundwater zone. Imbalances of nitrogen are in part attributable to nitrification- denitrification reactions and volatilization of ammonia; Ca and K reductions are attributable to cation exchange reactions between plants-soils-bacteria and to chemical precipitation by oxidation reactions and evaporation. Natural processes operate to cause such desirable imbalances; thus, techniques need to be investigated to enhance these desirable results. 2. An investigation is required to determine optimal rela- tionships of seepage to return flow (pumping) under field conditions. Some feedlots for all practical purposes should show buildup of runoff in the groundwater zone yet the buildup does not occur; quantitative relationships of seepage to re- turn flow need to be evaluated. Slow seepage rates may be acceptable for feedlots that use large volumes of groundwater. 3. Shallow-hole exploration (20-40 feet) of playas is needed to better determine the geology and its relation to control of seepage. New (pre-feedlot) and old playas should be in- cluded to evaluate the effects of colloid-filtrate plugging. 4. Periodic evaluation of groundwater quality beneath selected sites used in this study should be made on an annual basis. It is recommended that water supply wells in the vicinity of all feedlots be sampled annually for specific ion content in groundwater. 5. In selecting future feedlot sites to minimize degradation of groundwater it seems significant to pay attention to the geographic location, type of "runoff system" and liquid-waste handling procedures, composition and structure of near-surface earth materials at the site, and pre-existing water quality beneath the site. Ideally, it would seem preferable to locate sites outside areas with very sandy soil zones. This in fact has been the trend in feedlot location, though probably unintentional. The "migration" of feedlots has been northward on the Plains to areas with less sandy soil than exists in the south, south- west part of the Plains. ------- The best "runoff system" should be a situation where long- term' ponding does not occur. Water that is ponded should be in an essentially impermeably bottomed reservoir. Many High Plains playas serve this purpose if_ the natural clay liner is not breached and the storage capacity of the imper- meable (clay) part .of the playa is not exceeded. If the natural clay liner of a playa is breached, the side-slopes of the excavation as well as the bottom should be restored to its original density. Clay layers in playas are lense- shaped bodies that are thin toward the edges of the "ponding" part of the playa; therefore, the "ponding" area of a playa adjoins what can be relatively permeable material. Long- term induced head due to "ponding", even in poorly permeable zones, may eventually cause movement of liquid-waste to the groundwater zone. Handling procedures for liquid waste may be of considerable significance in reducing potential pollu- tion hazards. Spreading of liquid waste increases the ulti- mate destruction and rate of conversion of nitrogens to tol- erable levels as well as serving to decrease concentrations in localized areas. Permeability data taken from cores of the subsurface unsatu- rated zone (Ogallala Formation) and from near-surface soil zones of feedlots indicate that the least permeable zones are consistently at or near the surface. This is a result of several factors some of which are inherently due to the geologic development of the Ogallala and some due to second- ary precipitation of dissolved solids in soil zones of feed- lot runoff surfaces. Runoff slopes in time usually decrease in permeability. There are places in the High Plains where naturally .occurring nitrate-nitrogen and other ions are in high concentration. Obviously, in these geographic areas small additions of un- desirable chemical compounds to the groundwater zone can degrade water quality to an intolerable limit for household or municipal use. The intolerable limit one speaks of is dependent upon the intended usage of the water. Certainly many industrial and agricultural applications of water have much higher tolerable limits in terms of nitrate-nitrogen and other ionic concentrations than water for household usage ------- INTRODUCTION Increasing concern within the last decade over possible con- centration of nitrate and other ions in the saturated zone beneath commercial cattle feedlots has warranted numerous studies where feedlots proliferate. Fortuitously interrela- ted factors of climate, soil, and groundwater, resulting in high-yield feedgrain production, have led to development of over one hundred major cattle feeding operations in the High Plains of Texas. Commercial cattle feedlots have been in existence in the Texas High Plains for 35 years, but increas- ing concern due to asymtotic development within the 1960's led to initiation of this and other studies. The initial objectives of this study included (1) quantita- tive estimates and distributive geometry of nitrogen (N03, N02, NH4,- Org-N) and other chemiqal parameters (Ca, Mg, Na, K, Cl, §64, pH, conductance) in groundwater below some major feedlot operations, and (2) determination of relative rates of movement of infiltrates from surface to the groundwater zone under field conditions existing in the High Plains. Initiation of the original project by the EPA led to incor- poration of additional objectives supported by the Texas Water Development Board, Texas Cattle Feeders Association, North Plains Water District (Texas), and Texas Tech University. The principal objectives incorporated into the total project, by support of the aforementioned agencies, were to (3) deter- mine the significance of subsurface distribution of dissolved solids from feedlot runoff to the groundwater zone (Ogallala aquifer), and to (4) evaluate what total geologic environment(s) in the High Plains is (are) least conducive to infiltration of feedlot runoff to the groundwater zone. Discussion, pres- entation of data, and conclusions relative to objectives 1 and 2 are, primarily, herein reported. A separate publica- tion-'- relative to objectives 3 and 4 is in preparation. Study Sites Eighty commercial cattle feedlots (locations, Figure 1) were investigated to varying degrees for the total research pro- gram. The 80 feedlots ranged from new to 35 years in estab- lished age (distribution, Figure 2) with a one-time cattle capacity of over one million head (load vs years established, Figure 3). be published by International Center for Arid and Semi-Arid Land Studies, Texas Tech University, Lubbock, Texas. ------- OKLAHOMA ^v HUTCHINSON^1* FIGURE 1—LOCATION OF CATTLE FEEDLOTS INVESTIGATED IN STUDY, TEXAS HIGH PLAINS ------- 41950 51 52 53 54 55 56 57 58 59 I960 61 62 63 64 65 66 67 68 69 1970 YEAR FEEDLOTS ESTABLISHED FIGURE 2--AGE DISTRIBUTION OF FEEDLOTS IN STUDY ------- o o o .iH X! E-" a oo pq I w H PH ISO 165 150 135 120 105 90 75 60 45 30 15 0 10.3 10.0 t L ! 6.7 3.3 15 10 5 0 AGE IN YEARS t!950 51 52 53 54 55 56 57 58 59 I960 61 62 63 64 65 €6 67 68 69 1970 YEAR FEEDLOTS ESTABLISHED FIGURE 3--APPROXIMATE AVERAGE CATTLE LOAD vs. YEAR FEEDLOT ESTABLISHED ------- Twenty-two feedlots were drilled and/or cored to investigate subsurface geology and chemistry of part of the unsaturated zone. Five representative feedlots, each of which lies south of the Canadian River, are herein described in detail. Socio-economic implications inherent in such a volatile topic as feedlots and potential groundwater pollution prohibit detailed locations. The specific site locations are of but academic interest; geologic environments and their relation to the Texas High Plains geologic framework are the signifi- cant factors. Accordingly, we have designated the sites under the generality of field sites I thru V. Field Methods Holes were drilled with a commercially-owned mud-rotary rig and with a mud-rotary rig of the Texas Water Development Board. All coring was completed with the TWDB rig. Drilled holes were reamed 12 3/4 inches in diameter to a depth of 50 feet and then completed to TD with an 8 3/4-inch bit. All drilled holes were.set with slotted, 6-inch plastic casing and cemented -to a depth of 50 feet. One-foot extensions of casing above ground level were capped with a commercial well seal. • Holes drilled and cored with the Water Develop- ment Board rig were completed to TD with an 8 3/4-inch bit, and set with slotted, 5-inch plastic casing, cemented to a depth of 20-40 feet, and capped with.a commercial well seal. Holes were completed below the watertable but not necessarily to the base of the Ogallala Formation. Gamma and spontaneous potential-resistivity logs were run by the U. S. Geological Survey, Lubbock, Texas, on all drilled holes reported in this phase of the project. Four-inch diameter, two-foot long rotary cores of the Ogal- lala Formation were taken with a double-walled core barrel with a custom-designed sheet-metal liner to retain the core upon removal from the barrel. Four-inch diameter push barrels were used for cores of soil zones. Core samples collected in the field for chemical analysis were retained below ground- water temperatures with dry ice. The metal liners were sealed with paraffin, the push cores sealed with plastic wrapping and paraffin, and then shipped to the TWDB Materials Testing Laboratory, Austin, Texas, for determination of plasticity index, void ratio, porosity, permeability, size analysis, and moisture content. Field and laboratory descriptions of lithology were made according to the Unified Soil Classi- fication System. ------- Laboratory'Methods Laboratory core analyses included determination of (1) in situ unit weight and moisture content, (2) Atterberg Limits, (3) shrinkage factors, (4) grain size analysis by sieving and hydrometer, (5) specific gravity, and (6) vertical con- stant head permeability. In addition to the above labora- tory tests, void ratio, porosity, and degree of saturation were calculated. Details of techniques used to determine each of the afore- mentioned parameters are available from the following sources The in situ unit weight and moisture content test procedure used is "Suspended Weight in Air and Water", as described in U. S. Bureau of Reclamation Earth Manual, Designation E-10, Part E, page 454. The test procedure for determining Atterberg Limits was the one-point hand method for liquid limit (LL), as described in the Texas Highway Department Soil Manual, Test Method Tex-104-E. The plastic limit (PL) and plasticity index (PI) were measured according to ASTM Test Specification D-424; shrinkage factors are described in ASTM Test Specification D-427. The grain-size analysis procedure used is described in ASTM Test Specification D-422. Al-1 soils samples in which 5% or more of the material passed the No.. 200 sieve were graded by both sieving and hydrometer analysis. The procedure used to determine the specific gravity of soil is described in ASTM Test Specification D-854. Fifty-gram samples were treated in a 500 ml flask; a vacuum pump was used to remove entrapped air. Constant head permeability tests were run on an undisturbed core, trimmed to obtain parallel ends and uniform diameter. The sample was then placed in a permeameter and saturated under constant head. When uniform flow was obtained, the quantity of water flow during a measured time was determined. Permeability was calculated as shown. thA K = coefficient of permeability Q = quantity of flow L = core length t = time elapsed h = total head loss A = core cross-sectional area 10 ------- Water-quality parameters determined include the nitrogen family (NO,, N0£, Ntfy, Org-N), common ions (Cl, Ca, Mg, Na, K, 504), pH and conductance. Water-quality determinations were made using Orion specific ion probes, a Technicon nitrogen autoanalyzer, and wet chem- istry techniques; conductivity and pH values were measured by meters. The wet chemistry analyses were performed in accordance with procedures specified in Standard Methods for Examination of Water and Wastewater. Duplication of analytical techniques was employed in the examination of many samples in order to provide a basis for correlation of results obtained by different techniques. Aliquots for core chemistry were taken by soaking and mechani- cally mixing equal weights of sediment and distilled water. The core extracts were analyzed in the same manner as the water samples. Nitrogen Cycle A review of the nitrogen cycle is presented as prelude to the discussion of feedlots and water quality. Nitrogen in nature occurs as molecular nitrogen (N?); as organic nitro- gen in urea, proteins, amino acids, and protein derivatives; inorganic nitrite (N02), nitrate (N03), ammonia (Nt^), and ammonium (NH^) ions; and as other less (quantitatively) im- portant intermediate products. All animals and plants contain nitrogen, and nitrogen also exists in the earth's atmosphere, lithosphere", and hydrosphere Inorganic physico-chemical reactions and inorganic-organic reactions associated with plant-animal metabolic activity serve as the "catalyst" whereby nitrogen in various forms is cycled in nature. As a generality, the biological (in- organic-organic) phase of the nitrogen cycle is graphically represented. \ ORG. M FIXATION j « i ATTER-* »-ORG t Kl — I \ i 1 1 - r A * N2,02 ~ NITRIFICATION > — »!*% ^«. ^REDUCTION ,J N2 j — »-N J ,02 t ^FICATION r RECYCLE 11 ------- In the cycle, organic nitrogen is converted into inorganic ammonia, nitrite, nitrate and to molecular nitrogen. Decom- position of organic matter results in formation of organic nitrogen and other products. Subsequently, organic nitrogen is used as an energy source by bacteria and is converted to ammonia. Large quantities of ammonia escape to the atmosphere as a gas; other molecules of ammonia are oxidized under aerobic conditions, as a bacterial energy source, to nitrite and ni- trate. Nitrite and nitrate may further be converted to nitro- gen gas. Shortcuts and reversals exist in the aforementioned oxidative process (See diagram). Under anaerobic conditions, nitrate may be converted to nitrite and to nitrogen gas. To close the cycle, some organisms are capable of assimilating nitro- gen into cellular matter. Significant differences in factors affecting the nitrogen cycle exist between the environment of feedlots and that of many freshwater systems. These factors are the organic-inor- ganic load, predominance of bacterial activity over the ac- tivity of algae, changing aerobic-anaerobic environments, and the removal of runoff to the subsurface environment. A Texas High Plains feedlot surface is an environment of al- ternate wetting-drying, the organic and inorganic load exceeds the capacity for degradation, the surface is aerobic (some- times anaerobic at depth), and bacterial activity is high. The runoff collection-system is heavily laden with organic- inorganic matter, oxygen-deficient conditions often exist at depth, and bacterial activity is high. In the unsaturated subsurface, seepage results in removal of liquid from the anaerobic conditions. The denitrification and reduction of nitrate by bacteria account for relatively low concentrations of nitrate in feedlot-runoff collection ponds. On the con- trary, nitrification (oxidation) of organic nitrogen, nitrite and ammonia to nitrate account in part for the accumulation of nitrate in the unsaturated zone and groundwater zone be- neath feedlots. 12 ------- DISCUSSION OF STUDY AREA Observations on the relationships of cattle feedlot sites to geomorphological-geological features and groundwater quality in the Southern High Plains are presented, followed by descriptions of representative field sites. Outlining the geologic setting of High Plains cattle feedlots provides the framework for evaluating relative rates of movement of nitrate and other ions from the surface to the watertable, and natural rates of dispersal in the groundwater zone under existing field conditions. Geomorphology-Geology The High Plains is in the "Panhandle" of Texas and is the southernmost extension of the Great Plains which borders the east side of the Rocky Mountains. The High Plains is bounded on the east and west by an erosional escarpment and merges southward into the Edwards Plateau. Only one major stream, the Canadian River, transgresses the southern High Plains, but tributary drainage to the Red, Colo- rado, and Brazos rivers originates in the region. Drainage relative to cattle feedlots is localized principally within the stream systems and in the ubiquitous closed-drainage pla- yas that occur in the region. Semiarid climatic conditions of low rainfall (±20 inches), large daily fluctuations in temperature (±40°) , and high-wind conditions (5-35 mph) re- sult in low values for long-term runoff and in periods of rapid drying. Most feedlots in the High Plains are located on stream drain- age systems or playa systems. Approximately 40% of the feed- lots considered in this study are located on streams, 45% on playas, and 15% have no relation to the aforementioned geomorphic features. These statistics are applicable to all feedlots in the Texas High Plains. Of course, good drainage is an economic asset and in most instances such benefits are readily obtainable by proper geographic location. High Plains streams have gradients ranging from about 10 feet/ mile to less than 5 feet/mile. Feedlot playas considered in this study have a relief of from 5 to 45 feet of closed con- tours. Feedpens located adjacent to stream channels and pla- yas in Armstrong, Bailey, Castro, Lamb, Lubbock, Farmer and parts of Deaf Smith counties (Figure 1) have drainage slopes ranging from 2% to 5%; feedpens in Floyd, Hale, Gray, Potter, Oldham and Moore counties have slopes ranging between 0.2% and 2%. Few feedpen slopes of the High Plains exceed 5% in value. 13 ------- The Ogallala Formation, the principal aquifer, surfaces the Texas High Plains, along with a thin intermittent veneer of unconsolidated Pleistocene sediments. The Ogallala is breached to the-underlying Cretaceous System in some large playas (non feedlot) and to the Triassic and Permian systems along the Canadian River. Soils distribution in the High Plains (Figure 4) (1, 2, 3) has a significant relation to infiltration of surface water, thus a relationship to infiltration of cattle feedlot runoff. Rates of infiltration and total accumulation of dissolved solids in groundwater are, in general, higher in "sandy soils" and areas of "sand dunes" than in the tighter soil zones. Total dissolved solids (TDS) and specific-ion maps^ (chloride, nitrate) of areas in the southern High Plains where no feedlots are located, indicate this relationship. A contributing factor for the sandy soils, groundwater quality relationship is the relatively rapid entrapment of surface water by loose surficial material (sand) which prevents ready runoff, evaporation, and even evapotranspiration due to low plant density. One should add"that the significance of soils distribution in terms of potential degradation of large volumes of groundwater is di- minished when one considers the low total number of feedlots (±20 in 1970) in the sandy soil zones of the High Plains. Most surface materials on stream and playa feedlot slopes consist of dense, fine-grained, semi-consolidated soils under- lain by caliche. Feedlots located on Texas High Plains streams have feedpens situated on slopes consisting of caliche and thin soils, but in many the stream bottoms have breached the caliche. Feedlots in headwater areas and tributaries of streams have the usual caliche zone beneath the stream channel. Poorly permeable, thin zones of clayey silt were found in stream channels that breach the caliche; at most sites these zones were underlain by thin layers of fine- to coarse-grained sand and/or gravel. The clayey silt and sand-gravel valley fill overlies the Ogallala Formation. Vertical constant head permeability values determined for the clay-silt sediments of channels are 10"^ to 10"^ cm/second.3 The underlying sand zones usually have vertical permeability values of 10"' cm/sec, or larger. Most sediments that occupy the floodplain of the channel consist of a near-surface zone 2 Derived from published and unpublished data of Texas Water Development Board and High Plains Water District, and by chemical analyses in Geoscience Department Water Quality Lab, Texas Tech University. In preparation for publication. 31 X 10"6 cm/sec equals 1.034 ft/year. 14 ------- OKLAHOMA LEGEND | | FINE TEXTURED SOILS SANDY SOILS SAND DUNES FIGURE 4--GENERALIZED SOIL TEXTURE MAP, TEXAS HIGH PLAINS (After Carter, 1931; Lotspeich § Coover, 1962; Lehman, Stewart § Mathers, 1970) 15 ------- of clay and clay-silt that is slowly permeable to impervious. Vertical constant head permeability values determined for floodplain sediments in this study range from 10~? cm/sec to larger permeability values. The "pond" of playas is surfaced by layers of clay, which is underlain by layers of "lake-fill" sand and/or lenses of clay-silt-sand. Playa "fills" up to 40 feet in thickness were measured, and all are underlain by the Ogallala Forma- tion. Vertical permeability values of playa lake clay are 10~6 to 10~8 cm/sec or lower in value (impermeable). Lithi- fication of medium and coarse-grained clastic zones is notice- ably absent beneath the "standing water area" in all types of collection systems. Surficial silt-clay mixtures surfacing feedpens and/or run- off slopes exhibit secondary cementation in the form of root fillings, vug and pore fillings, and veinlets. Below this developed hardpan, soil densities are noticeably less. Per- meability values typical of the hardpan surface of feedpens and drainage slopes range from 10~4 to 10~? cm/second. Caliche below playa and stream channel collection systems is porous and permeable. Secondary solution of caliche is evidenced by vugs, secondary cementation of fractures and solution vugs, and by silt-clay filling in solution vugs and voids. The Ogallala Formation underlies the surficial material at all feedlots considered in this study. In terms of infiltra- tion, most laboratory determined permeability values in the unsaturated zone range from 10"^ cm/sec to 10~6 cm/sec; the larger permeability values of Ogallala sediments will permit rapid percolation of water. However, minimum permeability of near-surface material and minimum permeability values of Ogallala sediments determine actual vertical transmissibility rates. Groundwater Groundwater in the study area is ubiquitous within the Ogal- lala Formation. Depth-to-water ranges from a minimum of 10 feet (parts of Tierra Blanca Draw) to depths of 250-300 feet. Saturated thicknesses range from 30 feet to 300 feet in areas investigated. Concentration of water-quality parameters in this study varies significantly in the Ogallala aquifer within short distances (few hundred feet), regionally from north to south, and in some geographic localities from west to east. 16 ------- In the High Plains, nitrite, ammoniacal and organic nitrogen, sodium, potassium, calcium, chloride, and total-dissolved- sojids (IDS) are definitive parameters for collected feed- lot runoff. Most feedlot runoff (ponded) ranges from less than one hundred to several hundred p.p.m. of ammoniacal and organic nitrogen, chloride, sodium, calcium, potassium, and up to several thousand p.p.m. of IDS. These chemical parame- ters invariably are more concentrated in collected runoff than in Ogallala groundwater. Nitrite and nitrate-nitrogen concentrations in feedlot runoff (ponded) range from less than 10 p.p.m. to several tens-of-parts-per-million. Nitrite- nitrogen is -consistently more concentrated in feedlot runoff than in groundwater, but this relation is not always true for nitrate-nitrogen. There are areas in the southern High Plains, particularly in sandy soil zones, where naturally occurring N03-N is higher in "normal" Ogallala groundwater than in water beneath feed- lots that show evidence of "seeping" to the watertable. Thus, in order to relate groundwater quality to cattle feed- lot runoff one must first establish the quality of water in the Ogallala aquifer in the vicinity of a feedlot site prior to time of establishment of the site in question. Ionic concentrations in feedlot runoff are often difficult to correlate with concentrations of specific ions in ground- water derived from feedlot runoff. This is particularly true for potassium. Rarely is there correlation of high potassium concentrations in feedlot runoff with low potas- sium concentrations consistent in Ogallala groundwater. This is in part accountable by plant use of potassium, ad- sorption by clay minerals, and use of potassium by organisms. Nitrite-nitrogen, ammoniacal nitrogen and organic nitrogen infiltrated from feedlot runoff also are not easily corre- lated with the occurrence of these ions in groundwater. Such imbalances are attributable to inorganic oxidation- reduction reactions and/or to metabolic processes of organisms, Chloride and conductivity values, and sometimes NOj-N, show the most consistent correlation. As noted previously, secon'dary precipitation of dissolved solids is readily noticeable in the few feet of near-surface material of feedlots and in parts of the unsaturated zone of the Ogallala Formation. This is another cause of the often observed common cation-anion imbalance between the chemistry of cattle feedlot runoff and groundwater. 17 ------- INFILTRATION - GROUNDWATER QUALITY RELATIONSHIPS Theoretical consideration aside, particular attention was given to field evaluation of factors that control seepage and seepage rates. Cattle loading history in terms of years and number of cattle was developed for 80 feedlot sites. Other data for the sites include determining thickness of the saturated and the unsaturated zones; feedpen slopes; drainage basin, feedpen, collection system area-volume re- lations; and type of collection system. Other practical mat- ters of rainfall rates and periodicity, and balance studies of amount and rate of runoff-evaporation-infiltration were not determined directly. Distribution of nitrogen (N03, N02, NH,, Org-N) and common chemical parameters (Ca, Mg, Na, K, Cl, 804, pH, conductance) in groundwater beneath the 80 feedlots and their vicinity were determined. Also, near- surface cores were taken from 22 feedlot sites (feedpens and collection ponds) in the High Plains. From a regional viewpoint, concentration of nitrate and other dissolved solids in groundwater as a result of runoff from feedlots is related to soils patterns. The southern part of the southern High Plains and the western part of the North Plains has a sandy soil cover (Figure 4, page 15), and the feedlot water-quality data developed for this study Show higher infiltrate concentrations in groundwater beneath the sandy soil zones than in the hardland region. As noted pre- viously, this observation concerning soil-infiltration re- lationships .is confirmed, independent of this study, by Texas Water Development Board annual observation well records and by specific ion (N03, Cl) distribution maps of the southern High Plains. Local sediment distribution is significant also. Surface sediments in High Plains playas are, almost invariably, es- sentially impermeable (<10~6 cm/sec). Also, secondary depo- sition in feedpens and on runoff slopes develops a near- surface hardpan that retards infiltration. The unsaturated portion of the Ogallala at few sites considered in this study is sufficiently impervious t.o prevent some seepage of ponded feedlot runoff if it penetrates the surfacing mantle; there- fore, permeability of near-surface material is often the essential controlling factor in infiltration. No direct correlation between drainage slopes and groundwater quality in the High Plains is apparent. As indicated pre- viously, few slopes exceed about 5 percent, and within these limits other overriding factors evidently are more signifi- cant. The prime significance of feedlot slopes is to pre- vent ponding which increases the probability of seepage. 18 ------- Ratios of collection-system area to area of drainage-basin are in general unrelated directly to groundwater quality- Possible exceptions to this observation are large ratios of drainage-basin area to runoff-collection area of feedlots located on stream channels, and small ratios of drainage basin to runoff-collection area of feedlots located on playa sys- tems. In many large drainage basins with through-flowing streams into which feedlots empty, there has not been any significant buildup of infiltrates beneath the feedlots. Perhaps other unknown factors affect this relationship. According to Lehman, Stewart and Mathers (3), playa collec- tion systems that are small (volume) in relation to drainage basin areas influence infiltration of impounded water. Com- putation of drainage-basin area to playa-area ratios and their correlation to groundwater quality do not confirm this. How- ever, a study by Hauser (4) and permeability determinations in this current study leads the writer to agree with Lehman and others. One must conclude that small ratios of drainage basin to playa volume are of some importance in preventing collection and infiltration of runoff in the "overflow" parts of the playas bordered by sandy soils. Hence, the pumping of excess water out of playa collection systems is a justi- fiable practice. Cattle load and surface-area of feedpens may have some sig- nificance to seepage and seepage rates, but they do not appear to be independently related, to groundwater quality beneath Texas High Plains cattle feedlots. Perhaps the interaction with other factors may mask their correlation with ground- water quality. A summary of the relationship of this and other factors to quality of groundwater are enumerated in Table I." 19 ------- TABLE I RELATION OP FEEDLOT RUNOFF SEEPAGE FACTORS TO GROUNDWATER QUALITY, TEXAS HIGH PLAINS NJ O Factors Geographic Location Age of lot Feedlot cattle load Feedpen surface Feedpen gradient Stream gradient Drainage area vs Feedpen area Type o£ collection system System capacity vs Drainage area Collection-pond surficial material Subsurface *lithology Caliche "caprock" Depth to water Saturated thickness beneath lot Relation Significant; related to soils distribution, geomor- phic and geologic control. Significance interdependent on other factors. Related, but old feedlots do not mean pollution. Not considered significant for commercial feedlots . Surficial material of most feedpens is poorly permea- ble due to compaction and cementation. Not correlative with groundwater quality. No relation to groundwater quality. Rarely significant; Only with very large ratios in streams and small ratios in playas. Significant; playa and non-ponding system away from stream most desirable. Not always significant. Local geology important. Important; playa clay impermeable. Minimum permeability significant in Ogallala. Significance is questionable due to unpredictable permeability. Significant in some geographic locations. Importance dependent in part on transmissibility of Ogallala Formation. ------- FIELD INFILTRATION RATES AND DISPERSAL RATES IN GROUNDWATER Infiltration and groundwater dispersal rates of feedlot run- off are evaluated within the detailed geologic framework of five selected field sites. In addition, concentration of NOj-N, chloride, and conductance values in groundwater are correlated with the ages of 80 feedlots (Locations, Figure 1, p. 6) to further determine field rates of infil- tration that exist in the Texas High Plains. The field sites, designated I through V, are located in the central part of the southern High Plains. Field Site I. Distribution of observation wells at Site I is shown in Figure 5. This feedlot is eleven years old and has a one-time capacity of 7,000 head of cattle. Runoff from this feedlot collects in a large shallow playa that contains an open borehole which has been in existence for two years; surface runoff moves by gravity flow into the groundwater zone. The Ogallala Formation crops out at the surface in the feed- pens. The playa contains 20-25 feet of sediment consisting of a near-surface clay and, underlying this, alternating lenses of clay-silt and nodular caliche; a profile of sub- surface' lithology of the Ogallala Formation at Field Site I is shown in Figure 6, page 23. Thirteen cores were taken for permeability determinations, but most of the section is so loosely consolidated and fria- ble that in situ permeability determinations were not always possible. Constant head permeability values determined at this site in the Ogallala range from 1.45 X 10"5 cm/sec to 5.5 X 10"3 cm/second. Certainly 10~5 cm/sec is near the minimum permeability of the Ogallala at this site. The clay layer of the playa is very slowly permeable to impermeable (10"' cm/sec). Various hydrologic parameters of subsurface material are shown in Figure 7, page 23. Core chemistry (Table II) beneath the collection pond indi- cates runoff has not infiltrated to the groundwater zone. Water-quality data (Table III, p. 25) from well installations (Well #5, #6, Figure 5) also indicate that seepage has not occurred beneath the feedpens to the groundwater zone. Laboratory determined minimum permeability values for the Ogallala at this site are about 15 feet/year. Depth-to-water beneath the feedpens is 120-130 feet, which theoretically would permit seepage to the watertable within about 8-9 years. Since runoff has not reached the watertable due to seepage, 21 ------- •~ WELL -„,__ TOPOGRAPHIC ~34iS— CONTOUR ROAD CONTOUR INTERVAL s FEET FIGURE 5--DISTRIBUTION OF OBSERVATION WELLS, FIELD SITE I 22 ------- WELL 16 el. 3430 Elev. 3400- 3375- 3350- 3325- 3300- 3275- FIGURE 6--GAMMA LOG PROFILES, FIELD SITE I FEET GAMMA LOG BELOW WELL 8 L.S.D. 0- .25 RELATIVE GRAIN SIZE DISTRIBUTION (mm.) p% K-cm. sect1 .005 .45 70 90 30 40 45 K>~2 IO~S Kf4 IO"6 —i ii ti i I i u_ ii ii k k 80- 100- i iii RADIATION - INCREASING ^GRAIN SIZE INCREASING VOID RATIO POROSITY ^PERMEABILITY INCREASING FIGURE 7--SUBSURFACE HYDROLOGIC PARAMETERS, FIELD SITE I 23 ------- TABLE II--CORE CHEMISTRY, WELL #8, FIELD SITE I FEET BELOW L.S.D. N03-N N02-N An-N ORG-N CA MG CL SO/, IDS pH I MOIST 0 6.64 0.003 0 0.84 38 6 20 28 211 8.03 13 9 1.33 0.003 0 0.84 44 H 20 20 78 8.10 15 17 1.33 0.003 0 0.56 42 8 20 16 448 8.13 13 44 0.44 0.003 0 0.56 38 8 20 12 68 8.22 17 67 0.88 0.003 0 0.56 45 6 26 13 192 8.01 17 90 0.81 0.003 0 0.56 30 9 12 11 120 8.30 13 ALL CHEMICAL CONCENTRATION VALUES REPORTED AS DRY WEIGHT; ALL IONS IN P.P.M. at Field Site I during its 11 years of existence, the con- clusion is that near-surface permeabilities are the control- ling factor in the extended seepage time. The saturated zone of the Ogallala Formation is 180 feet in thickness. The Triassic immediately underlying the Ogallala is an aquiclude, as is usual in the High Plains. Flow direc- tion in the Ogallala is normally toward the east but the presence of the open borehole has resulted in a mound on the watertable. The mound is recognizable for a radius of approximately 800 feet in a southeast direction from Well #9. The present -difference in head from epicenter to the south- east edge of the mound is on the order of 10 feet. This well is pumped intermittently; therefore, the geometry of the mound varies with time. Groundwater chemistry (Table III, page 25) was determined from sampling of 19 observation wells. The real indicators of runoff reaching the groundwater zone at this site are the high N02-N and NH4-N values of Well #9. Distribution of "above-normal" N03-N in groundwater (Figure 8) corresponds to the geometry of the groundwater mound described previously. Rate of dispersal of runoff-derived groundwater has averaged 400 feet/year. This field rate is reported under conditions of periodic rainfall-injection and on a recovery-as-needed basis. Scalf, Hauser, McMillion, Dunlap and Keeley (5), and Schneider, Jones and Wiese (6) report from short-term induced injection- recovery studies of NOj movement in the Ogallala Formation that rates of movement under injection exceed the 400 feet/ year value. Also, these investigators revealed that recovery 24 ------- TABLE III--GROUNDWATER CHEMISTRY, FIELD SITE I WELL No. 1 2 3 1 5 6 7 8 9 10 11 12 13 11 15 16 17 18 19 N03-N 1,3 1,1 1,4 1.0 2.1 1.3 1.0 0.9 7.9 1.1 2.1 0.8 0.8 0.8 0.6 0.5 0.7 0.5 3.5 N02-N 0.000 0.009 0.001 0.003 0.000 0.100 0.003 0.600 6.300 0.006 * 0.006 0.003 0.003 0.015 * * * 0.003 AM-N 0.00 * * * * 0.00 * 0.00 11.77 0.28 m » * * * * * * * * ORG-N 0.00 * 0.22 0,12 * 0.00 * 3.60 7.00 0.00 * * 0.11 0.28 * * * * 0.28 CA 12 18 53 83 56 11 12 18 58 68 10 10 .78 /7 11 36 10 11 80 He 11 18 29 30 52 15 63 17 11 78 79 39 30 26 71 17 11 15 27 NA 31 33 31 29 78 20 28 16 15 20 29 27 36 * 25 31 11 25 * K 8 10 9 9 7 8 8 8 12 11 11 7 10 • 11 10 10 10 * CL 70 31 22 61 110 16 23 51 71 170 61 25 52 10 28 23 25 32 52 SO/, 60 110 7 26 100 10 * 10 10 10 * 10 21 20 * * * * 25 COND. 735 617 855 685 765 680 660 600 735 1010 660 690 680 610 610 190 610 615 558 PH 7.3 7.5 7.3 7.8 7.3 7.2 7.1 7.5 7.3 7.1 7.3 7.3 7.8 7.8 7.3 7.1 7.3 7.3 7.9 ALL VALUES IN P.P.M. EXCEPT CONDUCTANCE AND pH, CONDUCTANCE IN MICROMHOS 25 ------- LEGEND •3 WELL —6— RRM. HOf-H :^= ROAD FIGURE 8--DISTRIBUTION OF NOs-N IN GROUNDWATER, FIELD SITE I 26 ------- of injected NC>3 is related closely to volume of water recov- ered during pumping. Even though very high concentrations of dissolved solids in runoff have flowed to the groundwater zone at this site, high concentrates do not exist at great distances from the borehole. This relationship is due es- sentially to volume recovery of high IDS concentrates near the bore hole, and due to dilution away from the point source of injection. Field Site II. Location of observation wells of Field Site II are shown in Figure 9. Site II is a 19-year feedlot with a one-time cattle capacity of 8,000 head. A playa collects runoff from the feedlot and, in periods of high rainfall, runoff flows southwestward down an intermittent drainage channel. Water stands in the playa except for relatively long dry periods. Drainage slope of the feedpen is approxi- mately one percent. The Ogallala Formation crops out at the surface. The feed- pen surface is soil covered, and below this lies a caliche "caprock." The caliche is breached in the deepest part of the playa. The playa fill consists of 5 feet of dense, im- permeable clay below which lies 15 feet of clay-silt and secondary nodular caliche. The lake fill overlies fine-grain, clean sand of the Ogallala Formation that typically under- lies the small playas in the High Plains (Figure 10). Con- stant head permeability values of the unsaturated zone range between 1.0 X 10"4 cm/sec to 4.7 X 10~3 cm/sec (Figure H). Playa lake clay permeability is 10'~7 cm/sec, or less. Surface material is the only impediment to seepage of feed- lot runoff at this locality. Seepage occurs at this site as indicated by core chemistry (Table IV) and degreee of saturation (66-87%) above the watertable. Field Site II has been in existence for 19 years; depth to the watertable at this location averages 115 feet. Theoreti- cally, average rates of seepage have exceeded 6.0 feet/year. As stated, the minimum permeability of the Ogallala is 1.0 X 10'4 to 4.7 X 10~3 cm/sec (exceeds 100 ft/yr). In prac- tical terms, average field seepage rates are controlled by near-surface seepage rates; the actual rate is indeterminable. An average 200 foot saturated zone occurs within the Ogallala Formation in this area; the underlying Triassic serves as an aquiclude. As is typical in the High Plains, groundwater flow is to the southeast. Groundwater-quality parameters (Table V) for this site were established from 14 observation wells. Nitrate-nitrogen values in groundwater range from 0.8 to 7.9 parts per million. 27 ------- FIGURE 9--DISTRIBUTION OF OBSERVATION WELLS, FIELD SITE II 28 ------- Elev. 3325 3300- "- 3275- 3250- 3225- FIGURE 10--GAMMA LOG PROFILES, FIELD SITE II FEET BELOW L.S.D. 0- 20- 40- 60- 80- 100- 120- GAMMA LOG WELL 9 RELATIVE GRAIN SIZE DISTRIBUTION V8 (mm.) .25 .005 .45 .60 .75 p% K-cm. secT1 31 35 40 I0~2 IO"3 I0~* IO"5 ill iii t" h- RADIATION . INCREASING J3RAIN SIZE .,-.,,. INCREASING V01D III III POROSITY -.PERMEABILITY POROSITY INCREASING FIGURE 11--SUBSURFACE HYDROLOGIC PARAMETERS, FIELD SITE II 29 ------- TABLE IV--CORE CHEMISTRY, WELL #9, FIELD SITE II FEET BELOW L.S.D. N03-N N02-N An-N ORG-N CA KG NA K CL SO/j TDS pH % MOIST 0.0 4.5 6.5 9.5 12.0 18.0 25.0 46.0 61.0 73.0 83.0 94.0 114.0 374.20 1 co on 152.80 76.20 67.72 65.69 43.54 72.57 14.64 26.68 0 0 13.94 13.36 0 5.39 3 TO .32 2.40 0.95 * 2.44 1.69 1.49 1.88 0.69 •1.07 1.23 1.51 1.06 114.60 9.40 37.54 20.23 8.94 8.94 0 0 0 0 0 0 0 10556.80 3476.00 531.50 227.60 123.70 301.40 130.30 1.29 184.27 128.50 15.74 35.58 149.41 32.65 * 108 68 44 72 84 60 120 84 64 60 128 68 * 41 29 34 22 46 34 46 39 32 36 46 68 * * 42 30 38 30 28 30 12 32 32 14 12 * * 86 71 78 43 38 36 28 26 26 32 34 * 383 220 170 220. 188 142 262 167 156 149 230 230 * * 25 25 25 25 25 75 25 75 25 25 25 14700 It 1764 1176 1000 1176 1118 942 647 559 471 529 647 588 * * 7.3 7.4 7.3 7.3 7.4 7.3 7.4 7.2 7.3 7.2 7.3 8.4 25.7 25.5 16.1 13.5 21.7 21.7 22.4 14.8 13.6 17.4 18.5 15.0 17.3 ALL CHEMICAL CONCENTRATION VALUES REPORTED AS DRY WEIGHT: ALL IONS IN P.P.M. Nitrate-nitrogen values beneath this site are below the maxi- mum value for the immediate area; therefore, NOg-N indepen- dently is not .prima facie evidence of seepage. However, Ca, Mg, Cl, and conductance values (Well #10, Table V) show that seepage is detectable in groundwater below the feedlot site. The relatively high chloride (Well #10) is not detectable for more than 800-900 feet away from the epicenter of the playa collection system (Figure 12). Assuming that runoff could have reached the groundwater zone within the first year the site was in operation, the minimum rate of dispersal in groundwater has been approximately 45 feet/year. Permeability values of the Ogallala indicate that minimum seepage time would be 2-3 years; therefore, minimum dispersal rates would be on the order of 55 feet/year. Field Site III. Location of observation wells of Field Site III are shown in Figure 13. This site is four years old with a one-time cattle capacity of 4,000 head. The operation is located on a stream, the stream channel serving as the col- lection system for runoff. Runoff collects in a low, dredged- out area of the channel, with the system overflowing during periods of high rainfall. Drainage slope in the feedpens is 3-4$, and the stream channel has a gradient of less than ten degrees. 30 ------- TABLE V--GROUNDWATER CHEMISTRY, FIELD SITE II WELL No. 1 2 3 1 5 6 7 8 9 10 11 12 13 11 15 N03-N 1,2 1.2 7.9 7.1 5.0 3.3 2.8 1.7 5.0 2.5 2.5 1.3 1.8 0.8 N02-N * * * 0.060 0.009 0.006 0.015 0.031 0.020 0.100 0.009 0.006 * 0.000 AM-N 0.00 * 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 * 0.00 * 0.00 ORG-N 0.00 * 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 * 0.00 * 0.70 CA 16 16 16 16 16 51 15 51 71 10 10 51 22 10 MG 16 15 15 11 16 16 51 35 85 11 51 28 11 55 NA 21 37 10 21 21 28 32 33 21 11 22 80 10 82 K 10 10 11 10 10 13 9 11 10 10 10 11 10 8 CL 53 52 53 61 15 59 52 50 89 53 53 60 26 37 SOj, 10 10 10 10 10 10 10 10 50 10 10 10 * 100 COND. 6.17 650 588 617 676 618 627 599 1029 620 735 559 620 791 pH 7.1 7.1 7.1 7.3 7.1 7.3 7.2 7.3 7.3 7.3 7.1 7.2 7.7 7.2 ALL VALUES IN P.P.M. EXCEPT CONDUCTANCE AND pH. CONDUCTANCE IN MICROMHOS 9CoRE HOLE 31 ------- WELL — 70—RRM. CHLORIDE ROAD 0 20O 400600 BOO FEET FIGURE 12--DISTRIBUTION OF CHLORIDE IN GROUNDWATER, FIELD SITE II 32 ------- WELL TOPOGRAPHIC CONTOUR ROAD — STREAM CONTOUR INTERVAL 10 FEET 0 200. 400600 FEET FIGURE 13--DISTRIBUTION OF OBSERVATION WELLS, FIELD SITE III 33 ------- The Ogallala Formation crops out at the surface, with less than 10' of Pleistocene "cover sand" and soil overlying the Ogallala caliche "caprock." The caliche is within the feed- pens but is breached in the low part of the stream channel. Subsurface lithology (Figure 14) consists of zones of clay, silt, clay-silt mixtures, and zones of fine to medium-grain sand typical of the upper part of the Ogallala Formation. Constant head permeability values in the unsaturated zone of the Ogallala at the site range from 1.9 X 10~5 cm/sec to 1.39 X 10~2 cm/sec (Figure 14). There are no essentially impervious stratigraphic units detectable between the surface and wat.ertable. FIGURE 15--SUBSURFACE HYDROLOGIC PARAMETERS, FIELD SITE III GAMMA LOG t&ft" WELL 20 0- 20- 40- 60- 8O- RELATIVE GRAIN SIZE DISTRIBUTION (mm.) r Vs p% K-cm. see?' 005 .56 .70 .80 35 40 45 Iff2 IO"3 IO"4 KJ5 ^RADIATION INCREASING GRAIN SIZE INCREASING VOID RATIO POROSITY ^.PERMEABILITY. INCREASING Percentage saturation values of effective pore space of 75-85% in several cores indicate that seepage does take place. Also, core chemistry (Table VI) indicates a N03-N profile of 170 p.p.m. near the surface to 11 p.p.m. at a depth of 80 feet. The rate of initial seepage probably is less than horizontal flow rates in the saturated zone, as evidenced by the lack of a groundwater mound beneath the collection pond. The depth of water at this 4-year-old site ranges from 60-90 feet. Seepage has reached the groundwater zone; therefore, the mini- mum average field seepage rate is on the order of 15-23 feet/ year. Minimum permeability values determined in the laboratory are 20 feet/year. 34 ------- Elev. 3225-. 3200- 3175- 3150 3125 WELL 18 el. 3233 WELL 25 el. 3235 Elev. 3225- 3200- 3175- 3150- 3HAUE. SHALE, SAND, SANDY SHALE FIGURE 14--GAMMA LOG PROFILES, FIELD SITE III 35 ------- TABLE VI--CORE CHEMISTRY, WELL #20, FIELD SITE III FEET BELOW L.S.D. N03-N N02-M ORG-N K Ci_ % MOIST 2 6 18 21 28 36 37 45 54 68 80 170 68 22 22 22 45 45 50 11 44 11 0,80 0,92 0,44 0,92 0,96 0,52 0,48 0,52 0.76 0,88 0,96 585 85 102 94 23 46 95 51 16 45 212 400 60 40 40 40 40 120 40 40 60 120 567 549 461 461 372 390 355 390 319 337 408 14,3 15,2 14.7 18,3 19,8 16.8 18,1 14,9 16,3 17,0 10.1 ALL CHEMICAL CONCENTRATION VALUES REPORTED AS DRY WEIGHT; ALL IONS IN P.P.M, The saturated zone in the vicinity of Site III is within the Ogallala Formation and the underlying Cretaceous limestone. Saturated thickness is 100 feet and, within this zone, flow direction is to the east. Water-quality parameters determined from samples from 28 ob- servation wells in the area are shown in Table VII. N03-N values in the vicinity range from 0.7 to 16.7 parts per million, "Normal" background N03-N values approximate a range of 0.7 to 7.1 parts per million. This is the range in values in the area west of the feedlot and up-dip on the watertable. Abnormally high N03-N values (distribution, Figure 16) exist near the feedlot and below the floodplain that exists north of the feedlot. The floodplain has been under cultivation and fertilization for many years and some of the N03-N in the groundwater is attributed to this practice. With ground- water flow to the east, if the feedlot were the principal source of N03-N, the influent nitrogen would be expected to have reached Well #23 (Location, Figure 13) before or by the time water was degraded in wells numbered 22, 24, and 25. Wells #23 and #24 are more apt to represent distance of move- ment, which is on the order of a few hundred feet, with an average rate of 100 feet/year. 36 ------- TABLE VII--GROUNDWATER CHEMISTRY, FIELD SITE III WELL No. 1 2 3 1 5 6 7 8 9 10 11 12 13 11 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 N03-N 1.1 7.1 2.6 1.2 5.5 1.1 15.7 15.7 15.1 7.9 5.6 1.0 5.8 5.0 3.9 6.7 11.9 16.7 13.5 * 11.7 11.7 0.9 5.0 10.8 5.0 0.7 3.9 3.1 N02-N * 0.160 0.009 0.100 0.020 0.006 0.600 0.530 0.030 0.130 0.009 0.003 * * 0.010 0.009 0.020 0.060 0.210 • 0.009 0.009 0.000 0.070 0.012 0,010 0.003 0.010 0.001 AM-N * 0.28 * 0.28 0.00 0.81 0.00 0.00 0.56 * 0.00 0.00 0.00 0.00 0.81 0.00 0.00 * 0.56 • 0.00 0.00 0.00 * 0.00 0.00 0.28 0.81 0.00 ORG-H * 2.23 0.81 1.02 0.83 0.00 0.10 0.10 2.11 1.52 0.00 0.10 * 0.00 1.51 0.00 0.18 0.10 0.00 * 0.10 0.10 * 0.81 0.10 0.11 * * 0.00 CA 65 91 88 50 60 70 58 50 50 50 51 58 60 82 51 51 50 51 61 * 53 50 18 50 18 58 76 90 11 Me 27 77 H 50 50 58 39 36 51 57 25 26 51 22 51 25 52 55 62 * 28 52 35 69 11 56 60 77 19 NA 51 78 * 59 62 67 59 56 65 57 61 57 78 72 56 59 65 65 57 * 60 63 60 62 58 61 71 78 61 K CL SO,, COND. pH 9 15 * 705 7.1 16 25 75 1323 7.2 150 86 692 7.6 13 85 100 882 7.1 13 113 50 911 7.3 17 117 150 1058 7.3 11 16 10 765 7.1 13 32 10 617 7.2 12 50 52 882 7.3 21 61 80 613 7.3 17 60 10 1058 7.2 16 67 10 735 7.3 18 121 10 911 7.3 22 112 80 853 7.1 13 103 50 882 7.1 17 82 10 821 7.2 13 71 100 1100 7.1 12 58 * 1010 7.3 15 57 10 617 7.1 * * * * * 17 50 821 7.1 16 59 75 821 7.3 15 69 «5 618 7.1 21 92 80 658 7.2 12 57 100 706 7.3 11 30 100 1069 7,1 17 138 100 1058 7.2 15 138 125 1176 7.2 12 59 280 730 7.1 ALL VALUES IN P.P.M. EXCEPT CONDUCTANCE AND pH. CONDUCTANCE IN MICROMHOS 20CoRE HOLE 37 ------- \ \ \ \ FIGURE 16--DISTRIBUTION OF N03-N IN GROUNDWATER, FIELD SITE III 38 ------- Field Site IV. Field Site IV observation wells are shown in Figure 17. This location has been in use for 16 years with a one-time capacity of 4,500 cattle. Runoff from this site collects in a playa. The Ogallala Formation crops out at the surface. Playa sediments are 10 feet in thickne.ss, including a 4-foot upper clay layer. The clay layer of the playa is relatively im- permeable at the cored location (Well #7). Typical subsur- face lithologies of the Ogallala are depicted in Figure 18. Nine cores were taken in the Ogallala Formation beneath the pond, and representative analyses indicate a constant head permeability range in value of 5.27 X 10"^ cm/sec to 1.03 X 10-3 cm/sec (Figure 19). Core chemistry (Table VIII) indicates that N03 has penetrated to a depth of at least 46 feet, and other ions show a decreas- ing trend to the watertable. Calcium, potassium, and conduc- tivity values decrease sharply below 11 feet. Based on N03-N, the field seepage rate has been no more than 3-4 feet/year. TABLE VIII--CORE CHEMISTRY, WELL #7, FIELD SITE IV FEET BELOW L.S.D.' 2.5 6 11 30 16 57 68 88 110 N03-N 0.00 12.15 13.01 * 13.33 0.00 0.00 0.00 0.00 N02-N 1.10 1.59 1.25 * 1.18 1.68 1.29 1.13 1.01 AM-N 0.00 0.00 0.00 * 0.00 0.00 0.00 0.00 0.00 ORG-N 113 33 67 * 0 171 32 65 32 CA * 81 88 31 32 28 21 16 21 MG * 26 26 13 31 36 18 16 16 NA * 68 38 60 8 11 18 33 32 K * 30 11 27 22 17 11 10 10 CL * 230 212 117 78 78 69 53 62 S01 * 80 10 10 80 10 10 10 80 TDS * 1058 1000 617 588 529 112 617 382 pH * 7.3 7.1 7.1 7.1 7.3 7.1 7.1 7.5 % MOIST 11.2 9.3 13.1 * 15.3 18.9 15.0 15.2 15.2 ALL CHEMICAL CONCENTRATION VALUES REPORTED AS DRY WEIGHT; ALL IONS IN P.P.M. 39 ------- FIGURE 17--DISTRIBUTION OF OBSERVATION WELLS, FIELD SITE IV 40 ------- WELL 7 el. 3392 Elev. 3375- 3350- 3325- 3300- 3325- FIGUKE 18--GAMMA LOG PROFILES, FIELD SITE IV FEET GAMMA LOG BELOW WELL 7 L.S.D. 0- ao- 40- 60- 80- RADIATION^ INCREASING RELATIVE GRAIN SIZE DISTRIBUTION (mm.) .25 .005 JS ^GRAIN SIZE v vs 0 75 1.0 3 1 i 1 1 1 010 RATIO F p% K-cm. sec 5 45 50 I0~s I0~4 1C ii ii m^^m •^••^B ii ii npneiTV PERMEABILI1 I r5 •y INCREASING INCREASING FIGURE 19--SUBSURFACE HYDROLOGIC PARAMETERS, FIELD SITE IV 41 ------- The saturated zone of the Ogallala Formation is 200 feet in thickness. Within this zone, 21 wells were used to col- lect water samples for chemical analyses (Table IX). In terms of NC^-N, the range in normal background N03-N is 0.7 p.p.m. to 4.7 parts per million. Seepage has not reached the groundwater at this site. Field Site V. The surface layout of Site V is shown in Fig- ure 20. This site has been in operation for 3-5 years and has a one-time capacity of 17,000 head of cattle. The ca- pacity was 4,000 cattle in the 1940 Ts, 7-10,000. head in the 1950's, and 15-17,000 head of cattle in the 1960's. Runoff collects in a playa, and the playa water in turn is pumped outside the basin for purposes of irrigation. Feedpen drain- age slopes average 1-2 percent. The Ogallala Formation crops out in the feedpens. A caliche layer exists near the surface, and below this is a typical Ogallala section (Figure 21). The playa is filled with sedi- ment to a depth of about 20 feet. Constant head permeability values within the Ogallala range from essentially non-pervious to 3.2 X 10~3 cm/sec (Figure 22). The geologic section at this site is less permeable than any of the other sites described in the report. Core chemistry (Well #9, Table X, p. 46) indicates that per- haps NO 3 has not reached the water table beneath the pond; however, groundwater chemistry (Table XI, Wells 4, 5, 9, 11, 13) indicates some seepage of N03 has occurred. The depth to water is 110-115 feet; thus, the 35-year-old-site exhibits an average minimum field rate of infiltration of about 3 feet/year. This falls within the range of laboratory determined permeability values for the site. The saturated zone at the site is within the Ogallala Forma- tion, and groundwater chemistry was determined from 16 obs.er- vation wells penetrating this zone. N03-N values (distribu- tion, Figure 23) range from 0.8 to 8.4 parts per million; N03-N values exceeding 5 p.p.m. are above normal at the site. Rate of dispersal of NOs-N in groundwater has been less than 100 ft/year. Other Sites A minimum of five and a maximum of 25 groundwater samples from beneath each of 75 additional feedlots were chemically ana- lyzed. Distributive groundwater geometry of NO-j-N (and other ions) derived from feedlot runoff was determinable from about 15 to 20 of these sites. The maximum detectable distance of 42 ------- TABLE IX--GROUNDWATER CHEMISTRY, FIELD SITE IV WELL No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 20 21 22 NOj-N 0.8 1.4 2.3 2.5 2.8 1,7 1.60 2.1 1.9 0.7 3.5 1.4 3.6 1.43 2.1 4.1 2.5 4.7 4.2 2.1 1.7 N02-N * * * 0.120 0.300 0.006 0.030 0.006 * * 0.200 » 0.060 0.010 0.006 0.006 0.560 0.240 0.160 0.760 * AM-N * * * 0 0 0 0 0 * * 1.96 » 0 0 * * 0.28 0 0 0 1.96 ORG-N * * * 0 0 0 2.0 0 * * 0 # 0 4.87 * * 0 0 0 0 0 CA 44 34 45 44 48 50 54 46 43 38 56 45 40 64 50 43 46 42 40 44 48 KG 39 55 48 39 38 55 57 34 37 57 38 35 36 52 55 47 40 45 43 35 34 NA 32 31 37 31 33 29 11 36 35 35 41 54 50 21 30 35 41 31 34 33 40 K 10 11 9 9 9 11 11 9 11 10 8 9 8 8 10 11 9 9 7 9 8 CL 27 44 34 57 46 39 43 41 39 21 39 64 50 41 43 47 53 50 57 43 43 SO,, * 140 * 40 40 40 20 40 * * 40 * 40 20 * * 40 40 40 40 40 COND. 720 - 700 550 647 588 647 663 647 740 540 588 640 588 595 676 650 559 559 588 588 559 pH 7.3 7.4 7.6 7.2 7.4 7.2 7.6 7.2 7.8 7.5 7.2 7.3 7.4 7.5 * 7.5 7.4 7.4 7.4 7.4 7.3 ALL VALUES IN P.P.M. EXCEPT CONDUCTANCE AND pH, CONDUCTANCE IN MICROMHOS X 43 ------- WELL ~irm— TOPOGRAPHIC 3710 CONTOUR ROAD CONTOUR INTERVAL 10 FEET FIGURE 20--DISTRIBUTION OF OBSERVATION WELLS, FIELD SITE V 44 ------- Elev. 3725- 3700- 3675- 3650- 3625- 3600- S":TLSHALE CLAYEY SAND SAND FEET BELOW L.S.D. 0- 20- 40- 60- 80- 120- 140- FIGURE 21--GAMMA LOG PROFILES, FIELD SITE V 6AMMA LOG WELL 9 RADIATION INCREASING .25 RELATIVE GRAIN SIZE DISTRIBUTION (mm.) p% ^GRAIN SIZE INCREASING I I i VOID RATIO POROSITY K-cm. secT1 Iff4 iff5 Iff6 iff7 PERMEABILITY INCREASING FIGURE 22--SUBSURFACE HYDROLOGIC PARAMETERS, FIELD SITE V 45 __ ------- TABLE X--CORE CHEMISTRY, WELL #9, FIELD SITE V FEET BELOW N03-N N02-N AM-N ORG-N CA MG NA K CL S0a IDS pH % MOIST L.S.D. 4 3.5 9 17 22 29 35 13 58 72 84 98 110 21.16 11.97 0.00 0.00 0.00 25.31 0.00 12.49 73.62 12.59 12. SI 0.00 0.99 1.15 0.80 1.00 1.04 0.98 1.03 1.06 0.61 1.16 1.09 1.13 0.00 0.00 7.80 0.00 0.00 0.00 0.00 0.31 0.00 0.00 0.00 0.33 13.98 46.30 22.68 78.41 65.00 5.35 46.12 17.11 0.00 17.47 97.33 47.84 54 52 40 40 34 36 36 50 38 48 30 26 26 16 24 27 21 22 18 23 19 19 10 13 25 13 38 50 48 50 31 24 12 18 13 15 11 7 9 18 9 10 11 13 9 10 6 7 106 96 71 115 124 113 99 82 64 64 57 60 40 40 80 40 60 60 40 160 80 120 60 60 412 588 529 529 588 588 529 559 441 471 324 353 7.4 7.4 7.4 7.5 7.2 7.1 7.2 7.2 7.3 7.2 7.3 7.3 6.6 5.7 * 11.8 15.2 14.2 11.1 9.6 8.0 10 3 11.9 14.8 ALL CHEMICAL CONCENTRATION VALUES REPORTED AS DRY WEIGHT; ALL IONS IN P.P.M. travel of NOj-N in the groundwater zone was on the order of 1500 feet. It is concluded, dissolved solids concentrated in Ogallala groundwater from point-sources such as cattle feedlots usually are restricted to the vicinity of the site. To determine relative field rates of seepage on a regional basis, several chemical parameters were evaluated in terms of ages of feedlots. The values used to derive the graph shown in Figure 24 represent maximum values of N03-N in ground- water beneath each of 80 feedlots. Each feedlot used repre- sents 5 to 25 groundwater analyses, and the high and low maxima for each year represent 5 to 70 determinations of N03-N. The dashed line shows the base level for"NC>3-N be- neath Texas High Plains feedlots. This base level has not been corrected for "normal" background levels in the Ogal lala before establishment of the feedlots; therefore, the base level for feedlot N03-N contribution is less than shown. The base line shows a general increasing trend in N03-N con- centration with age. The upper (solid) line of Figure 24 46 ------- TABLE XI--GROUNDWATER CHEMISTRY, FIELD SITE V WELL No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 NOrN 1.1 2.3 2.4 5.7 5.0 3.6 1,4 1.0 6.4 1.0 8.4 1.0 5.2 2.7 0.8 4.17 N02-N * * * * » 0.000 * 0.003 0.003 0.003 0.012 * 0.099 * * * AM-N * * * * * 0 * 0 0 0 0 0 0 0 0 0 CA 56 64 80 54 64 67 65 64 65 56 65 60 74 68 92 68 MG 52 37 36 60 61 59 37 62 60 52 52 33 80 29 47 40 NA 59 39 72 60 60 64 65 57 59 58 57 44 52 85 52 52 K 9 12 13 15 10 12 14 15 16 8 11 10 15 11 16 10 CL 78 195 124 72 85 85 125 85 95 85 50 82 174 124 195 103 so/, 145 40 40 140 150 * * * * 40 * 40 134 40 40 40 COND. 880 1150 882 890 790 706 995 706 805 735 794 706 1215 1000 941 735 PH 7.3 7.2 7.2 7.3 7.5 7.6 7.4 * 7.3 7.4 7.5 7.2 7.4 7.2 7.2 7.2 ALL VALUES IN P.P.M. EXCEPT CONDUCTANCE AND pH. CONDUCTANCE IN MICROMHOS 47 ------- \ \ 2 \ LEGEND —s— RPM. NO,-N ROAD FIGURE 23--DISTRIBUTION OF N03-N IN GROUNDWATER, FIELD SITE V 48 ------- represents the highest maximum level of N03-N found in all lots for each year shown. As with the base line, it has not been corrected for "normal" background N03-N. The upper line tends toward considerable variation in age concentration re- lationships and indicates that, disregarding age, some lots contribute N03-N to the groundwater zone of the High Plains. The average slope of the N03-N base line (dashed) is about 0.17 p.p.m. NC>3-N per year. The maximum slope value is 0.3 p.p.m. N03-N per year. These approximated rates represent point-sources beneath all feedlots in the study and have no significance for a specific geographic location. In conclu- sion, these values approximate a regional rate of concentra- tion of NC>3-N in Ogallala groundwater from cattle feedlots . Additional profiles are shown for chloride (Figure 25) and conductivity values (Figure 26) beneath the 80 feedlots . The profiles show slopes of 0.07-0.40 p.p.m. Cl/year and an increase in conductivity of 40-100 micromhos/cm/year, respectively. These data also reflect field infiltration rates as described for NO^-N. 49 ------- en o LOWEST MAXIMUM NO,-N £1950 1955 I960 YEAR FEEDLOT ESTABLISHED 1965 1970 FIGURE 24--AGE OF FEEDLOTS INVESTIGATED vs. RANGE IN MAXIMUM NO,-N -CONCENTRATION IN GROUNDWATER 3 ------- Cn 2SI3 \2 II O x 10 5 Q. £ 9 d z p o 8 o ai _ Q 7 o: o -J c x 6 o E 4 LJ 1 3 DC 2 I HIGHEST MAX. Cl LOWEST MAX. Cl J I «I950 J I I I I I I I I I 1955 I960 YEAR FEEDLOT ESTABLISHED 1965 1970 FIGURE 25--AGE OF FEEDLOTS INVESTIGATED ZS. RANGE Ifl MAXIMUM CHLORIDE CONCENTRATION OF GROUNDWATER ------- in (x|00) 28 HIGHEST MAX. COND. LOWEST MAX. COND. a I960 1955 I960 YEAR FEEDLOT ESTABLISHED 1965 1970 •FIGURE 26--AGE OF FEEDLOTS INVESTIGATED ys. RANGE IN MAXIMUM CONDUCTANCE OF GROUNDWATER ------- ACKNOWLEDGMENTS William D. Miller, Professor and Chairman, Geosciences Department, Texas Tech University, served as principal investigator and assumes sole responsibility for the scien- tific accuracy of the results herein reported. Special acknowledgment is due the feedlot owners and managers of the Texas High Plains who generously allowed us full use of their facilities, often for many days at a time. Their generosity is especially gratifying due to the public outcry over potential pollution by feedlots. The Projects Division and Materials Testing Laboratory of the Texas Water Development Board were major contributors to the total project. The core-drill crew from the Projects Division, TWDB, included James W. Sansom, Jr., Geologists and Crew Chief; Keith Keppel and Leon Byrd, Geologists; Lewis Barnes, Chief Driller, Hugo Walker and Lynn Jorgensen, Assis- tant Drillers. Materials Testing Laboratory personnel who contributed to the field work and who performed laboratory investigations of cores are Messrs. Paul Pasemann, Ronnie Weddell, Joe Gates, Steve Gifford, all Engineering Techni- cians, and Mike Howard, Technician, Structure Section. Messrs. G. S. Sawyer, Projects Division Director, J. E. Hunt, Chief, Materials Testing Lab, and James 0. Rodgers, Engineer, were instrumental in the planning phase of the project. Appreciation is also extended to Mr. C. R. Baskin, Chief Engineer, Mr. Seth Burnitt, Water Quality, and Mr. R. C. Peckham, Head, Ground Water division, Texas Water Develop- ment Board, for their assistance with planning and implemen- tation of portions of the project. Recognition is given for financial support of the project to the Texas Cattle Feeders Association, Mr. Lloyd Bergsma, Executive Director, and the TCFA Board of Directors, Mr. Bob Carter, President. The North Plains Water Di-strict (Texas), J. W. Buchanan, Manager, contributed financial support, and SP-logging equip- ment for logging in the North Plains. Messrs. Dennis Bell, Chief Research Assistant, and John Buchanan, David Normand and Bill Watson, Student Research Assistants, Geoscience Department, Texas Tech University, contributed to the field and laboratory investigations. 53 ------- Mr. Clyde Wilson, Acting Project Chief, Bill Sandeen-, Physi- cal Science Technologist, and Jim Smith, Hydrologist, U. S. Geological Survey, Lubbock, Texas, performed the well logging reported in this study. The initiation and major support of the project by the En- vironmental Protection Agency, Ada, Oklahoma, and the sup- port by the Project Director, Mr. Marion R. Scalf, are grate- fully appreciated. 54 ------- REFERENCES CITED 1. Carter, W. T., "The Soils of Texas," Texas Agricultural Experiment Station, Bull 431, (1931). 2. Lotspeich, F. B., and Coover, J. R., "Soil Forming Fac- tors on the Llano Estacado: Parent Material, Time and Topography," Texas Journal Science, Vol. XIV, No. 1, (1962) . 3. Lehman, 0. R., Steward, B. A., and Mathers, A. C., "Seep- age of Feedyard Runoff Water Impounded in Playas," Texas A§M - Texas Agricultural Experiment Station, MP-944, pp 1-7 (1970) . 4. Hauser, V. L., "Hydrology, Conservation, and Management of Runoff Water in Playas on the Southern High Plains," USDA Conservation Res. Report, No. 8 (1966). 5. Scalf, M. R,, Hauser, V. L., McMillion, L. G., Dunlap, W. J., and Keeley, J. W., "Fate of DDT and Nitrate in Groundwater," USDI, FWPCA, R. S. Kerr Water Research Center, (1968). 6. Schneider, A. D., Jones, 0. R., and Wiese, A. F-, "Pollu- tion Research in Recharging the Ogallala Aquifer Through Well.s," Ogallala Aquifer Symposium, ICASALS, Texas Tech University, (1970). 55 ------- 1 5 Accession Number 2 Organization Geosciences Stibjet-t Field St. Group SELECTED WATER RESOURCES ABSTRACTS INPUT TRANSACTION FORM Department Texas Tech University Title INFILTRATION RATES AND GROUNDWATER QUALITY BENEATH CATTLE FEEDLOTS, TEXAS HIGH PLAINS 10 Authors) William D. Miller Geoscience Department Texas Tech University Lubbock, Texas 79410 16 Project Designation EPA Project #16060EGS 21 Note 22 Citation 23 Descriptors (Starred First) Groundwater, nitrates*, feedlot runoff*, infiltration* 25 Identifiers (Starred First) nitrates*, feedlot runoff, infiltration field and laboratory studies o± tive teediots were conducted to determine field seepage rates and distributive geometry of infiltrated runoff. Practical field seepage rates at these sites ranged from 2 to 20 feet/ year. Nitrogen (NO,, N02, NH4, Org-N) and common chemical parameters (Ca, Mg, Na, K, Cl, 804, TDS, pH, and conductance) were determined in cores and groundwater samples; based on groundwater analyses from 80 Texas High Plains feedlots, rates of concentration of N03-N and Cl in groundwater beneath feedlots range from 0.07 to 0.4 p.p.m. per year, and average 0.17 p.p.m. per year. Laboratory determined constant head vertical permeability of cores from 22 feedlot sites revealed a range in values of 10"2 to 10~" cm/sec for Ogallala sediments, 10~4 .to 10'7 cm/sec for near-surface material of floodplains and feedpen-runoff surfaces, and values of 10'6 to-10'8 cm/sec for playa clay. Factors related to runoff-infiltration were correlated with groundwater quality, and it was determined that local surficial material and regional soils patterns are closely related to quality of groundwater beneath feedlots. Direct correlation of water quality does not exist with feedpen-runoff slope, cattle load, and surface-area ratios of drainage basin to collection system. 27 Abstre wTlliam D. Miller I Institution Texas Tech University WR: 102 (REV. JULY 19S9I WRSIC SEND TO: WATER RESOURCES SCIENTIFIC INFORMATION CENTER U.S. DEPARTMENT OF THE INTERIOR WASHINGTON. D. C. 20240 « OPO: 1969-359 ------- |