Edison Water Quality Laboratory April 1971 Oil Spill Dispersants Product Data \ ENVIRONMENTAL PROTECTION AGENCY 0 WATER QUALITY OFFICE ------- FOREWORD The purpose of this manual is to furnish a ready access to currently available oil spill dispersant information. It was specifically prepared for the Division of Oil and Haz- ardous Materials, which expressed a need for such a com- pilation. The manual summarizes oil spill dispersant product data available to the Oil Pollution Research Section staff at the time of preparation. As such, it comprises data sum- marized from the library, reprint, product and administra- tive files of the Edison Water Quality Laboratory. This report contains reference to some preliminary unpub- lished toxicity data from EPA and other Federal Agencies, state agencies and private industry, and as such, dissem- ination of such information should be handled with discretion. Acknowledgment is given to the many interested parties who have contributed information which aided in the preparation of this manual. ------- INTRODUCTION This manual is separated into four sections which include two product sections, a manufacturer's product section and a ref- erence section. The products listed in Section A have the most information at this time, whereas only limited data ware available for those products listed in Section B. For convenience in updating the manual as new products and new information on existing products become available, the sections are not paginated. In Section C manufacturers are listed alphabetically with the products of each manufacturer cross-referenced .to the section listings. Section D lists references cited in the product sections. ------- SECTION A ------- SECTION A The following dispersant products are listed in Section A: ALKEN O.S.D. AMEROID AQUANEX MC BACTO-ZYME B&B 2021-S B&B 2023 BESCO B-51-DT BESCO D-EMULSION NO. 100 BESCO SLICK - 4UO BLITZ BP - 1002 BP - 1100 CASOL COLLOID - 88 COREXIT 7664 COREXIT 8666 DI-CHEM 320 DISPERSE-OIL DISPERSOL OS P.O. 300-B P.O. 300-H FOILZOIL (GAMLEN) D SOLVENT GAMOSOL GOLD CREW HEMCO NO. 2 HOLL-CHEM #622 IGEPAL CO-430 IGEPAL CO-530 ISOMAL 265 JANSOLV-60 & 60W LLCP-12 MAGIC POWER MAGNUS MET AQUACLENE 100 OD - 2 OIL SPILL ERADICATOR X-l-11 (PETROLITE) W-U39 (PETROLITE) WF-30 POLYCLENS (MOLTOKLAR) POLYCOMPLEX A-11 & A-11 D RIDZLIK SEAMULSO E SKANEX S-102 SLIX SPILL- X SURFLO RD 282 TALENT TEOC UU4 TEOC 777 TYFOSOL 80 (WYANDOTTE) SPILL REMOVER ------- ALKEN O.S.D. MANUFACTURER COST AVAILABILITY Alken-Murray Corporation 111 Fifth Avenue New York, New York 10003 $2.99/gal. (55 gal. drum) F.O.B. Cleveland, Ohio PRODUCT DESCRIPTION Nonionic/anionic mixture of emulsifiers in 507o aromatic solvent SPECIFIC GRAVITY FLASH POINT SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 0.904 @ 60° F 180° F (C.O.C.) Miscible in water > 18 months Store @ U0° F to 110° F pH 9.2 - 9.6 Maximum allowable concentration for inhalation >1,000 ppm MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted. Agitate. Reacts immediately. Dosage Use Limitations REMARKS Dispersant to oil ratio 1:10 to 1:15 by volume Use above 35° F on light and heavy distillate residual and crude oils. Do not use below -5° F. Not for use in potable water supplies. Manufacturer reports 99 (-*•) % effectiveness in laboratory tests. Maximum allowable concentration for marine life reported by manufacturer to be > 100 ppm. ------- AMEROID OIL SPILL EMULSIFIER #1 MANUFACTURER COST AVAILABILITY Drew Chemical Corp. 522 Fifth Avenue New York, New York 10036 $2.60 - $3.20/gal. Worldwide @ 121 points. PRODUCT DESCRIPTION Nonionic ethylene dioxide condensate with petro- leum solvent. SPECIFIC GRAVITY FLASH POINT SOLUBILITY SHELF LIFE 0..960 @ 68° F 168° F (C.O.C.) Emulsifies in water Unlimited Store @ 10-150° F OTHER MANUFACTURER'S USE RECOMMENDATIONS Application Method Educt @ 3 to 57o concentration using pressurized sprayer. Reaction time is immediate. Dosage Use Limitations Dispersant to oil ratio 1:20 to 1:33 by volume. Use on light and heavy distillate, residual and crude oils. Increase dosage on weathered crudes. NOTE: Other Drew Chemical Corp. products that may be promoted for cleaning up oil spills: Drew Oil and Grease Remover, Ameroid HDE-777, Ameroid Oil & Grease Remover, Ameroid L.A.C. ------- EFFECTIVENESS; Manufacturer reports 75% oil dispersed in lab tests. Other: Dispersant to oil ratio" of 1:10 to .1:20 required to dispef'se seven crude and three fuel oils.".'. Least effective on Devonian Spill Experience: Inc ident Anne Mildred Brtfvig, February 1966 Effectiveness unknown Torrey Canyon, March 1967 Effectiveness unknown General Colocotronis (Bahamas) Effect ivehess 'unknown Toxicity Tests: Spec ie s Reference Fathead minnow (Pimephales promelas) 96 hr TLj, - 6.1 ppm (17) Zebra fish (Brae hy dan io rerio) no survival 24 hrs @ 20 ppm C']!"2) Marine fish (Gambusia) 21 of 21 dead in" 24 hrs-@'; 15 - ppm-' ------- AOUANEX MC MANUFACTURER Montgomery Chemical Company P. 0.. Box 187 Jenkinto'wn, Pennsylvania 19046 COST $1.30 - $l.Wgal. AVAILABILITY F.O.B. Gloucester, New Jersey SPECIFIC GRAVITY 0.830 @ 60° F FLASH POINT 180° F Tag Open Cup SHELF LIFE Unlimited OTHER Store @ ambient to 120° F HUMAN HAZARD Minimal toxicity. MAC-500 ppm for inhalation MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted. Agitate. Reacts immediately. Dosage Dispersant to oil ratio estimated @ 1:10 by volume Use Limitations Recommended for use on light and heavy distillate, residual and crude oil. ------- BACTO-ZYME MANUFACTURER Nevada Enzymes, Inc. ~~ 3049 Rie-gel, Building C Las Vegas, Nevada 89012 COST $3.95/g.al. (1-55 gal. drum) AVAILABILITY F.O.B. Las Vegas, Nevada PRODUCT DESCRIPTION Ferment of organic materials - 927o; polyglycols - 2%; amines - 4%; esters - 2% (Liquid Corn Steep) SOLUBILITY Completely soluble in water SHELF LIFE Unlimited OTHER Store under 120° F HUMAN HAZARD Non-toxic MANUFACTURER'S USE RECOMMENDATIONS Application Method Apply in fine spray diluted four times with water. Contact time 0 to 4 hours. Use Limitations Recommended for use on distillate and crude oils at' temperatures above 50° F. REMARKS Ford Motor Company, Central Testing Lab., Dear- born, Michigan, found product to be very effec- tive. Used by City of Denver, Colorado on July 1969 to clean up an asphalt paving residue on lake. Reportedly used by Dept. of Interior, Willow Beach Fish Hatchery at Lake Mead and found safe at a dilu- tion of 25,000 to 1 when used to clean algae from raceways. REFERENCE ------- B&B 2021-S MANUFACTURER COST AVAILABILITY B&B ChemicaJ Co., Inc. Box 796 Miami, Florida 33166 $2.20/gal. (55 gal. drum) Available in bulk on East Coast PRODUCT DESCRIPTION Soaps 30-50%; aromatic solvents US-65%; i.nhibi- ' tors 2-5% SPECIFIC GRAVITY FLASH POINT SHELF LIFE HUMAN HAZARD 0.91 > 150° F (C.O.C.) One. Year 200 ppm threshold limit value (inhalation) MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted with high pressure hoses. Agitate. Dosage Use Limitations REMARKS 1 gal. to 50-100 £t2 on a thin slick Recommended for use on light and heavy distillate, residual and crude oils Manufacturer reports 100% effectiveness on thin slicks in Florida waters. Exceeds requirements of MIL-S-2286'4 (Ships). Spill Experience: Inc ident Bahamas Agricultural Ltd. of Owens-Illinois used product on oil spill in Bahamas. Belcher Oil Co., Port Everglades, Florida used product to disperse Bunker C oil spill. Port Everglades Authority reports oil was effectively dis- persed and no toxicity effects were observed. REFERENCE ------- B&B 2023 MANUFACTURER COST AVAILABILITY B&B Chemical Co., Inc. Box 796 Miami, Florida 33166 $2.85/gal. (55 gal. drums) Available in bulk on East Coast PRODUCT DESCRIPTION Nonionic detergents - 70%; water - 30% SPECIFIC GRAVITY 1.01 FLASH POINT None SHELF LIFE Unlimited HUMAN HAZARD 1000 ppm threshold limit value (inhalation) MANUFACTURER'S USE RECOMMENDATIONS Application Method Dilute to as much as 25 times with water and spray. Agitate. Reacts immediately. Dosage Use Limit.at ions REMARKS REFERENCE (14) 1 gaL. to 50-100 ft2 on a thin slick More effective at warm temperatures Manufacturer reports 100% effectiveness on thin slicks. Used at U.S.N. Shipyards at Philadelphia (1969) and Charleston (1970). ------- BESCO B-51-DT MANUFACTURER COST AVAILABILITY The Besco Corporation 200 N. Myrtle Street Metairie, Louisiana 70004 $1.80/gal. (1-20 55 gal. drums) F.O.B. New Orleans, Louisiana PRODUCT DESCRIPTION Detergent type with surfactants, coupling agents. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE HUMAN HAZARD 1.007 Non-flammable 3l4 cps @ 20° C Soluble in water Indefinite above freezing Non-toxic MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted with low pressure. Agitate after one to three minutes contact time. Dosage REMARKS Dispersant to oil ratio 1:2 to by volume. Manufacturer reports very satisfactory effec- tiveness in treating oil spills over a fourteen month period. REFERENCE ( ------- BESCO D-EMULSION NO. 100 MANUFACTURER COST AVAILABILITY PRODUCT DESCRIPTION SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE HUMAN HAZARD The Besco Corporation 200 N. Myrtle Street Met airie, Louisiana 70004 $1.60/gal. (1-20 55 gal. drums) F.O.B. New Orleans, Louisiana Aliphatic petroleum hydrocarbons, nonionic synthetic penetrating surface active agents and coupling agents. 0.815 120° to 140° F 1.65 cps @ 25° C Emulsifies in water Unlimited Non-toxic MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted with low pressure. Agitate after one to three minutes contact time. Dosage REMARKS Dispersant to oil ratio 1:2 to 1:4 by volume Manufacturer reports very good effectiveness in treating oil spills over eight year period. Product is presently being replaced by Besco- Slick-440. REFERENCE ------- BESCO SLICK - 440 MANUFACTURER The Besco Corporation 200 N. Myrtle Street Metairie, Louisiana 70004 COST $1.90/gal. (1-20 55 gal. drums) AVAILABILITY F.O.B. New Orleans, Louisiana SPECIFIC GRAVITY 1. 06 1 FLASH POINT 100° to 120° F (C.C.) VISCOSITY 1.85 cps @ 25° C SOLUBILITY Emulsifies in water SHELF LIFE Unlimited HUMAN HAZARD Non-toxic MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted with low pressure. Agitate after one to three minutes contact time. Dosage Dispersant to oil ratio 1:2 to 1:4 by volume REMARKS Manufacturer reports very good effectiveness and im- provement over Besco D Emulsion No. 100. Has been used to treat spills over 3 1/2 year period. REFERENCE (14) ------- BLITZ MANUFACTURER COST AVAILABILITY SPECIFIC GRAVITY FLASH POINT SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD The "Clarkson Laboratories, Inc. 1450 Ferry Avenue Camden, New Jersey 08104 also 107 Fourth Avenue New York, New York 10003 $1.95/gal. F.O.B. Camden, New Jersey or San Francisco, California 1.020 Non-flammable Soluble in water Unlimited Store @ 32° F to 100° F If desired, add 257o ethylene glycol to prevent freezing. Non-toxic MANUFACTURER'S USE RECOMMENDATIONS Application Method Dosage Use Limitations REMARKS Spray diluted 2:1 with water Dispersant to oil ratio 1:15 by volume Recommended for use on distillate fuel oil or fresh crude. Manufacturer reports product disperses 100% of the oil that it emulsifies. Used in New York Harbor by Texaco Oil Company and in Camden, New Jersey to disperse gasoline spill on land (1967). Effectiveness not reported. ------- BP-1002 MANUFACTURER COST AVAILABILITY PRODUCT DESCRIPTION SPEC IF 1C-GRAVITY FLASH POINT VISCOSITY SOLUBILITY HUMAN HAZARD BP North America, Inc. 620 'Fifth -Avenue-, New York, New .York 10020 $1.08/gal. • F.O.B. United Kingdom Nohionic emulsifiers in aromatic petroleum solvent (kerosene) (60-70% aromatic), 3% coconut oil, 12% sulfonated dodecyl benzene. .. 0.88 @.15.5° C • 115° F (P.M.C.C.) > 10 cp @ 20° C Emulsifies in water Non-toxic but prevent eye contact MANUFACTURER'S USE RECOMMENDATIONS Application Method- Spray undiluted. -Contact time - none Dosage Use Limitations REMARKS Other Dispersant to oil ratio 1:5 to 1:10 by volume Recommended for use on all oils both on water and shore. Manufacturer reports product effective for sea and shore use. Dispersant to oil ratio of 1:10 emulsifies 82% of HD-SAE 20 motor oil.(D Gulf Oil reports 1:10 ratio effective for black oils. ------- Spill Experience: Inc ident Anne Mildred Br^vig, February 1966, North Sea - Amount of oil treated unknown. Torrey Canyon, March 1967, Cornwall, England - 540,000 gallons at sea 1,200,000 gallons on shore It was estimated that use at sea prevented 14,000 tons of "Torrey Canyon" oil from reaching shore. Effectiveness reports are conflicting. Toxic ity Tests: Spec ies Reference Mummichog (Fundulus heteroclitus) 24 hr TI^ 10 mg/1 (13) 96 hr TI^ 10 mg/1 Pink Shrimp (Pandalus montagui) 48 hr TL^, 5.8 ppm ( 3) Brown Shrimp (Crangon crangon) 48 hr TL^, 5.8 ppm (3) Shore Crabs (Carcinus maenas) 48 hr TLm 15. ppm ( 3) Cockles (Cardium edule) 48 hr TI^ 81. ppm ( 3) Marine Fish (Gambusia) .6 of 21 dead in 24 hr @ 1 ppm (23) 12 of 22 dead in 24 hr @ 15 ppm (23) 21 of 21 dead in 24 hr @ 30 ppm (23) ------- Bp-noo MANUFACTURER COST AVAILABILITY BP North America, Inc. 620 Fifth Avenue New York, New York 10020 $1.00 - $1.50/gal. In U. S. - B.P. Corp., Marcus Hook, Pennsylvania PRODUCT DESCRIPTION Oil-soluble nonionic emulsifiers in petroleum- based solvents (non-aromatic) SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY HUMAN HAZARD 0.82 - 0.83 @ 20° C 80° F (PMCC) Flammable > 10 cp @ 20° C Emulsifies in water Non-toxic. Avoid inhalation or eye contact. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted. Agitate. Dosage Use Limitations Toxic ity Tests: Spec ies Dispersant to oil ratio 1:10 by volume. Recommended for use on all oils on water and shores. On sandy beaches spray one hour before tide comes in after exposing oily sand. Reference Brown shrimp (Crangon crangon) 48 hr TLtn> 3300 ppm ------- CASOL MANUFACTURER COST AVAILABILITY PRODUCT DESCRIPTION SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD Wyandotte Chemicals Corp. J. B. Ford Division Wyandotte, Michigan 48192 $2.00/gal. (55 gal. drum) Five manufacturing plants: Los Angeles, Cali- fornia; Stroudsburg, Pennsylvania; Atlanta, Georgia; Wyandotte, Michigan; and Venezuela Polyglycols - 20%; aliphatic solvents - 80% 0.82 - 0.88 > 190° F (T.C.C.) 100% volatile. Product will burn. ca 5 cs. Emulsifies with water - mixes with oil type solvents Unlimited Store at 0° F to 140° F 5-day BOD @ 20° C 600,000 mg/1 (15) Ingestion toxicity and toxic effects, as well as therapeutic treatment, same as for kerosene or fuel oil. Maximum allowable concentration 500 ppm 8 hour exposure. MANUFACTURER'S USE RECOMMENDATIONS Application Method Dosage Use Limitations Toxicity Tests: Spec ies Spray undiluted. Agitate. Dispersant to oil ratio 1:5 by volume Recommended for use on light and heavy distillate, residual, and crude oils. Works best in fresh water, but has been successful in sea water. Reference Fathead minnow (Pitnephales promelas) 96 hr TI^ 32.0 ppm (15) Goldfish 24 to 96 hr LD5Q 15 ppm (25) ------- COLLOID-88 OIL SLICK DISPERSANT MANUFACTURER COST AVAILABILITY PRODUCT DESCRIPTION SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD Colloid Chemical Co. 31 Perkins Street Brockton, Massachusetts 02402 $2.50 - &3.75/gal. FoO.B. Brockton, Massachusetts An aqueous based suspension of microscopically sized particles of an inert mineral with emul- sion stabilizers and penetrants in small amounts. 1.15 @ 77° F Non-flammable 88 cp @ 68° F Insoluble in water Unlimited Fluid to 20° F Avoid eye or skin contact. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray diluted 49 to 99 times with sea water at high pressure. Immediate reaction. Dosage Use Limitations REMARKS Dispersant to oil ratio 1:2 to 1:50 by volume. Use on light and heavy distillate, residual and crude oils. Does not sink or permanently emulsify oil, only disperses it into minute floating globules. Do not use over shellfish beds. Manufacturer reports one part of agent disperses 10 parts Bunker C or 50 parts No. 2 fuel oil. Product may be called S-l, or Coastal Services ------- Spill Experience: Incident "Ocean Eagle", San Juan, Puerto Rico (March 1968) Over 1000 spills treated in last two years in New England, Fort Lauder- dale and Tampa, Florida. " City Service spill, Braintree, Massachusetts (June 1969) Buzzards Bay, Massachusetts (September 1969) Effectiveness not reported for above incidents. Toxic ity Tests: Species Ref_. Snails (Litorina littorea) - Safe @ 1000 ppm with or without oil (14) Sea urchins - Safe @ 1000 ppm with or without oil " Other fish - Safe @ 1000 ppm with or without oil Clams (Mercenaria mercenaria) - Not safe for use over shellfish beds Softshell clam (Mya arenia) - 96 hr TI^ 45 ppm (33) Mummichog (Fundulus heteroclitus) 96 hr TL^, 70 ppm " Winter flounder (Psuedo pluronectes) 96 hr Tl^, 10 ppm* " Lobster (Homorus americana) 96 hr TL^, 46 ppm " Edible mussel (Mytilus edulis) 96 hr TI^, 54 ppm* ." Atlantic silverside 96 hr Tl^ 32 ppm *tentative subject to revision ------- COREXIT 7664 AND COREXIT 7664* (Star on Drum) MANUFACTURER COST AVAILABILITY Enjay Chemical Co. 60 West 49 Street New, York, ,New York. .10020 $3.50 to $3.90/gal. ..Major ports and cities, in U. S. .PRODUCT DESCRIPTION Water-based nonionic-polyhydric alcohol ester, of fatty acid with isopropyl alcohol and water solvents. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD Original 7664 1.004 @ 60° F 90° F (T.O.C.) 30 Cs @ 100° F 500 Cs @ 32° F Soluble in water Unlimited Pour Point - 5° F 5-day BOD - 380,000 mg/1 Modified 7664* 1.02 @ 60° F > 175° F (T.O.C.) 160 SSU @ 100° F 115 Cs @ 32° F Soluble in water (15) Pour Point + 25° F Store above 30° F Avoid eye contact. For inhalation threshold limit is 400 pprn. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray diluted 16 to 24 times with water. Reac- tion time -'immediate on agitation. Dosage Use Limitations Dispersant to oil ratio 1:10 to 1:50 by volume. For use on light and heavy liquid oils (distill- ates, residuals and crude oils). Marginal effec- tiveness on oils with viscosit ies > 1000 Cs or under calm conditions without external agitation. Not effective below 25° F. ------- .REMARKS Manufacturer reports 100% effectiveness in lab tests. Dispersant to oil ratio of 1:2 ,to 1:5 was required to dis- perse seven crude oils and three fuel oils. Most effective on fuel oils and Cambrian crude. Least effective on Leduc Crude. On a 1 (high) to 4 (low) scale, Corexit rated 2. Spill Experience: Incident General Colocotronis off Bahamas - 50 drums used. Amount of oil treated - unknown. Esso Essen off Africa - 100 drums used. Amount of oil treated - unknown. Esso Andron off Africa - 168 drums used. Amount of oil treated - unknown. Santa Barbara, California - ? drums used. Amount of oil treated - unknown. Polycommander, Aruba N8W.I. - 35 drums used. Amount of oil treated - unknown. Toxic ity Tests: Spec ies See attached table,, ------- SUMMARY OF TOXICITY TESTS ON COREXIT 7664 Test Organism Steelhead Fingerling Pacific oyster larva (Crassotrea gigas) Shrimp (Penaeu s sp.) Shrimp (Palaemonetes sp.) With 10X So. La. Crude Oil, depending on Mumm.ichog (Fundulus heteroc litus) Fathead minnow (Pimephales promelas) With 2X Mich. Crude Fundulus parvipinnis Fathead minnow (Pimephales promelas) Shrimp (Penaeu s duorarum) Fish (Gambusia) Zebra fish (Brachydanio rerio) Rockfish (Clinidae) Whelk (Burnupena sp.) Limpet (Patella granularis) Oil None None None None None oil None None Oil None None None None None None None None None Reported As 96 hr Tl^ Non-toxic Toxic 48 hr TLn - 48 hr TLm 48 hr T-LB, 24 hr TLn, 96 hr TLj, 96 hr TL™ 24 hr Tit,, 24 hr TV 96 hr TL,,, 96 hr TLm No Kill, 24 hrs No Kill, 48 hrs No Kill, 24 hrs No Kill, 24 hrs No Kill, 12 hrs No Kill, 24 hrs Kill, 24 hrs Concentration 15.8 mg/1 10 mg/1 40 . mg/1. 5,000 ppm 10,000 ppm 50-50.0 p.pm > 10,000 mg/1 2,300 mg/1 >. 3,;20Q ppm 1 ,-800 ppm > 15,900 ppm 7,200 ppm > 10,000 ppm 10,000 ppm 10,000 ppm 15,000 ppm 500-1,000 ppm 10,000 ppm 10,000 ppm 1-10,000 ppm Reference (6) " tr . (34) tt 1 1 > (13) (15), 1 1 (18) t r (1:7) (23) 1 1 (12) (32) " Tl I I ------- SUMMARY OF TOXICITY TESTS ON COREXIT 7664 (Cont'd) Test Organism Starfish (Asterina exigua) Abalone (Haliotis midae) Rock Lobster (Fasus lalandii) Periwinkles (Oxystele variegata) Pacific northern onchovy (Engraulis mordax) Sailfin Molly (Poecilla latipinna) . With 10X So. La. Crude Oysters Atlantic salmon parr Herring Bluegill Yellow Peach Oil None None None None None Oil None None None None None Reported As No Kill, Behavioral Stress , No Kill, No Kill, AH alive, All dead, No effects, No Kill , 24 hrs 6 hrs 24 hrs 24 hrs 118 hrs TI^, 24 hrs 24 hrs 8 days 96 hrs 142 hrs Tl^ 96 hrs Tl^ 96 hrs TL^ Concentration Reference 500- 1,000 ppm 500 ppm 500 ppm 10,000 ppm > 10- 500 ppm 500 ppm 10 ppm 1,000 ppm 10,000 ppm 8,000 ppm 500 ppm 500 ppm 398 ppm 398 'ppm (32) (35) (23) (33) ------- COREXIT 8666 MANUFACTURER COST AVAILABILITY En jay Chemical Co. 60 West 49 Street New York, New York 10020 $3.50 to $3.90/gal. Major ports and cities in U. S. PRODUCT DESCRIPTION Same, as Corexit 7664 except contains aliphatic hydrocarbon solvent. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 0.840 @ 60° F 185° F (T.O.C.) 25 Cs @ 32° F 57 Cs @ 0° F 50 SSU @ 100° F Disperses in water Unlimited Pour point: 80° F Avoid eye and skin contact MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray full strength as a thin film. Agitate. Reacts immediately. Dosage Use Limitations REMARKS Dispersant to oil ratio 1:10 to 1:100 by volume. Use on light and heavy liquid distillate, residual and crude oils. Not for use in potable water supplies. Manufacturer reports product particularly effec- tive for heavy viscous fuel and crude oils. Product will disperse 10 to 25 its own volume of oil. ------- Spill Experience: Incident Tanker "Arrow", Nova Scotia, Canada - Very limited use with unknown results. "Delian Appollon", Tampa Bay, Florida - Used on shore. Effectiveness not reported. Toxic ity Tests: Spec ie s Reference Sailfin molly (Poecilla latipinna) 24 hr, No Kill 10,000 ppm (24) Zebra fish (Brachydanio rerio) 24 hr, No Kill 20,000 ppm (12) 96 hr, Non-toxic 10,000 ppm (14) ------- TOXICITY. DATA ON, COREXIT 8666 BY MARINE BIOLOGICAL ASSOCIATION OF THE U.K., PLYMOUTH Control 10,000 ppm 5,000 ppm Number of Gob'ies '(Gobius minu'tus) dead Number .of Gobies .tested Corexit 8666 after 24 hrs. 0/10 .0/10 0/10 .hrs. 0/10 0/10 , 1/10 . 72 hrs. 1/10. 0/10.. 1/10 96 hrs., 1/10. 0/10 2/10 ' Corexit 8666 + Oil 2000 + 8000 (4000) 1000 + 4000 (1700) 500 + 2000 (.930) 2000 -i- 8000 (2000) 0/10 0/10 0/20 0/10 2/10 0/10 .0/20, 2/1,0 1000 + 4000 (1000) 0/10 500 + 2000 (500-1000)0/10 1/10 ..0/16 '. 2/10 3/10 (5 survivors poor) 2/10 5/10 0/10 0/10 Number,of .. Shrimp . (Crangon • c rangon) dead . . ..Number of .Shrimp tested 0/10 7/10 (3 survivors poor) 1000 + 4000 500 -i- 2000 200 -i- 800 100 + 400 (200) NOTES; 1. Number in .parenthesis represents actual oil measured in suspension. Note comparison to concentration of oil added. 1/10 0/10 0/15 4/10 . 2/10 1/15 7/10 3/10 5/15 7/10 4/10 6/15 2. Oil used was Kuwait crude residue after topping at 250° C. ------- TOXICITY DATA ON COREXIT 8666 From Sprague, J. B., "Progress Report on Toxicity of Corexit and/or Bunker C Oil". Fisheries Board of Canada (March 2, 1970). Extensive tests on. Corexit 8666 alone and with oil were initiated as a. result of its proposed use following the, ARROW spill in Nova Scotia. These tests included: Pollack in sea water at about 3-5° C. . Tilapia (a tropical fish) in half sea water at 23° C. . * Salmon in fresh water at 4° C and 15° C. Shore crab in sea water at 4° C. . Winter flounders at 4° C. . Lobsters at 4° C. Some typical results included: . 1000 ppm Corexit 8666 did not kill Pollack or Tilapia after two days. 1000 ppm Gorexit 8666 did not kill salmon or shore crab after six days. . 50,000 ppm Corexit 8666 + Bunker C was lethal threshold to beach-living marine crustacean (Gammarus oceanicus). j . 1000 ppm Corexit 8666 + 1000 ppm Bunker C was slowly lethal to small salmon and killed same in 2-4 days; one of two shore crabs died after 4 days, the other survived 6 days. ------- DI-CHEM 320 MANUFACTURER COST AVAILABILITY Diversified Chemicals Corp. 8100 Electric Avenue Stanton, California 90680 $2.15/gal. (55 gal. drum) F.O.B. Stanton, California PRODUCT DESCRIPTION Anionic - 26%; water diluent 50% SPECIFIC GRAVITY 1.035 @ 60° F Non-flammable Soluble in water More than two years Storage @ 30° F to 120° F Avoid prolonged skin contact FLASH POINT SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD MANUFACTURER'S USE RECOMMENDATIONS Application Method Apply by high pressure spray (500-2000 psi) with positive displacement pump and eductor diluting 50 times with water. Agitate. Reacts immediately. Dosage Use Limitations REMARKS Oil to dispersant ratio 1:5 to 1:50 by volume Recommended for use on light and heavy distillate, residual and crude oils. Manufacturer reports 100% of oil dispersed. One ppm disperses five ppm oil. No separation of oil when 5 cc of oil and 50 to 5000 ppm dispersant were mixed with 95 cc of water. REFERENCE Toxic ity Tests: Species Reference No effects with tropical fish @ 50. ppm (25) ------- DISPERSE-OIL MANUFACTURER COST AVAILABILITY PRODUCT DESCRIPTION SPECIFIC GRAVITY FLASH POINT SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD Pepper: Tank Cleaning Co. 2000 M: Kin ley. Avenue National City, California 92050 $1.20 to $1.25/gal. F.O.B, National City, California A concentrated mixture of water-rbased synthetic detergents and surface active agents fortified with highly active phosphates. 1.030 @ 60° F Non-flammable Soluble in water. Compatible with petroleum so {L vent s. One year (at least) Store above 32° F Freezes at> 32° F without separation Non-toxic MANUFACTURER'S USE RECOMMENDATIONS - Application Method Apply by high pressure (300 psi) sprayer, with eductor, diluting 4 to 6 times with sea water for Bunker C, and diluting 2 times with sea water for diesel oil. May also be applied as foam, although effectiveness is decreased. Agitate. Reacts im- mediately. Dispersant to oil ratio 1:1 to 1:4 by volume for Bunker C. 1:6 to 1:10 by volume for diesel and JP-4, Recommended for use on light and heavy distillate, residual and crude oils. Not effective on heavy asphalt residuals. Not for use in potable water supplies. Use Limitations ------- Spill Experience: Incident November 1968 - 86,000 gallons of Bunker C in San Diego Bay dispersed with 21,000 gallons of product. Numerous spills (80-100/yr) of dis- tillate and Navy special in San Diego Bayd^O. Effectiveness not determined. Toxicity Tests: Spec ie s Reference Mummichog (Fundulus heteroclitus) 2k hr TI^ 42 ppm (25) 48 hr Tl^n 42 ppm -96 hr Tim 40 ppm ------- DISPERSOL OS MANUFACTURER COST 1C I America, Ihc . 151 South Street Stamford, Connecticut 0690U $2.76/gal. PRODUCT DESCRIPTION Nonionic polyethanoxy compound approximately 10%; isopropanol diluent approximately 90%. 0.796 @ 68° F 53° F (Abel C.C.) Highly inflammable 1 cp @ 68° F Active agent insoluble in water. Completely solu- ble in oil. Unlimited Store between 23° F - 140° F Boiling point: 179.6° F Pour point - free flowing down to -5° C Harmful to eye tissue. Concentrations of isopro- panol greater than 400 ppm by volume are unsatis- factory for working conditions. Explosive limits by volume in air: Lower 2% Upper 12% Vapor is heavier than air. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted. Spraying equipment must be grounded. During use there should be no smoking, sparks or open flames. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD Dosage Use Limitations 1 gallon per 20/yd2 of slick, 250 gallons/acre. Dispersant to oil ratio 1:2 to 1:10 by volume. Recommended for use on light and heavy distillate, residual and crude oils. ------- Toxicity Tests: Spec ies Reference Brown Shrimp LD5Q 3000/10,000 ppm (14) Sea Shrimp LD50 1% (25) Gobies (Gobius minutus) No survival 2k hrs 1,000 ppm (24) 6 of 10 dead 48 hrs 500 ppm 5 of 10 dead 72 hrs 200 ppm ------- F.O, 300-B P.O. 300-H* MANUFACTURER COST AVAILABILITY Fine Organics, Inc. 205 Main Street Lodi, New Jersey 07644 $1.80/gal. F.O.B. Lodi, New Jersey PRODUCT DESCRIPTION Synthetic emulsion degreasers. Nonionics, 107o; aromatic hydrocarbons, 41%; aliphatic hydrocar- bon, 497o. Also contains couplers and inhibitors, SPECIFIC GRAVITY FLASH POINT 0.875 180° F (C.O.C.) for 300-B 210° F (C.O.C.) for 300-H VISCOSITY OTHER > 0.5 poises Storage @ 0° F to 140° F for 300-B @ 0° F to 180° F for 300-H MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted. Agitate. May be diluted with fuel oil, fresh or salt water. Dosage Use Limitations REMARKS Dispersant to oil ratio 1:2 by volume. Recommended for light and heavy distillate, residual and crude oils. Used on local harbor spills, Newark Bay, Passaic River, Delaware River, 1966-1968^^). Effective- ness not determined. ^Formula identical except for a higher boiling aliphatic hydrocarbon which results in higher flash point. Results will be equal to 300-B. Toxicity Tests: Spec ies Steelhead minnow fingerlings Pacific oyster larvae Crassotrea gigas 96 hrs Toxic Non-toxic 65.0 ppm 4.0 ppm 1 . 0 ppm Reference (6) (6) ------- FOILZOIL MANUFACTURER COST AVAILABILITY Sea-Air Chemical Corp. 32-00 Borden Avenue Long Island City, New York 11106 $2.05/gal. F.O.B. Long Island City, New York FLASH POINT VISCOSITY PRODUCT DESCRIPTION Tank cleaner. Polyglycols (non-solvent) SPECIFIC GRAVITY 1.02 @ 68° F Non-flammable Slightly more than water SOLUBILITY Soluble in water SHELF LIFE Unlimited Keep from freezing Non-toxic OTHER HUMAN HAZARD MANUFACTURER'S USE RECOMMENDATIONS Application Method Coarse spray - contact time varies. Can be sprayed diluted with equal quantity of water. Dosage Use Limitations REMARKS Dispersant to oil ratio 1:5 by volume or 10 gals/1000 ft2 of oil slick. Use on petroleum oils and distillate fuels. Manufacturer reports 96% of oil dispersed in field tests. Toxicity Tests: Species Reference Mummichog (Fundulus heteroclitus) 24 hr TL^ 42 mg/1 • (13) v 96 hr Tim 31 mg/1 (13) ------- MANUFACTURER COST PRODUCT DESCRIPTION SPECIFIC GRAVITY FLASH POINT OTHER HUMAN HAZARD APPLICATION METHOD REMARKS (GAMLEN) D SOLVENT Gamlen Chemical Co. 321 Victory Avenue South San Francisco, California 94080 $2.10/gal. Tank and bilge cleaning solvent. Highly con- centrated detergent containing kerosene. 0.870 @ 70° F > 150° F (C.O.C.) Fire Pt.: 165° F (min.) B.O.D. 864,000 mg/l(19) Avoid eye and skin contact Spray In lab tests 1:1 ratio emulsified 16.1% of Navy Special grade fuel oil'9). Toxic ity Tests: Spec ies Pink shrimp (Pandalus montagui) Brown shrimp (Crangon crangon) Cockles (Cardium edule) Daphnids (Daphnia magna) 48 hr TLfo 11.5 tng/1 48 hr Tl^ 9.6 mg/1 48 hr Tlfl, 38.8 mg/1 24 hr TLj, 13.7 ppm 48 hr TLfl, 2.9 ppm 72 hr TL^ 1.5 ppm Reference (3) (19) w/crude oil 24 hr TI^, 24.4 ppm " 48 hr TI^ 10.7 ppm " 72 hr Tl^ 9.1 ppm Bluegills - Kills within 5 minutes @ 10.0 ppm ------- GAMOSOL OIL SPILL REMOVER MANUFACTURER. . Garnien.Chemical Co. 321 Victory Avenue South San Francisco, California 94080 also 11 Broadway New York, New York 10017 $3.25/gal. (1-55 gal. drum) South San Francisco, California' East Paterson,..New Jersey" Mobile, Alabama PRODUCT DESCRIPTION Tanker and bilge cleaning solvent. Polyglycols, 9%;-.polyethanol, 18%; aromatic hydrocarbons,. 7.3%. COST AVAILABILITY SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 0.92 @ 60°,F > 1,50° F (CoO.C.) 43 SoS.U. @ 100° F Emulsifies in water Un1im it ed Fire point: 155° F Store @ 0° to 125° F Avoid eye or skin"contact MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray as a solid jet, undiluted, through a small jet nozzle under pressure or dilute 5 to 10 times with water. Immediate reaction. Dosage Use Limitations: REMARKS Dispersant to oil ratio 1:6 to 1:10 by volume. For use on light and heavy distillate, residual and crude oils. Minimal effects @ 28° F. Manufacturer reports 95% of oil dispersed. Product meets specification of MIL-S-A22864 (ships). In lab tests at 1:1 ratio emulsified 20. 8%9) and 26.7%d6) Of NaVy Special grade fuel oil (referred to as Gamosol at time of tests). Principal oil spill emu Is if ier stocked by Royal Navy at time of Torrey Canyon incident. Used by Royal Navy in England and Australia. ------- Spill Experience: Inc ident Anne Mildred Br^vig, February 1966 - Effectiveness undetermined Torrey Canyon, March 1967 - Effectiveness undetermined Toxicity Tests: Species Reference Mummichog (Fundulus heteroclitus) 24 hr TL^ 6.4 mg/1 (13) 96 hr T^ 6.4 mg/1 (13) Zebra fish (Brachydanio rerio) No survival. ........ ^ 24 hr @ 15 ppm (12) Pink shrimp (Pandalus montagui) 48 hr TLm I205ppm ( 3) Brown shrimp (Crangon crangon) 48 hr TL^ 8.8ppm ( 3) Shore crabs (Care inus maenas) 48 hr TLm 20.4ppm ( 3) Cockles (Cardium edule) 48 hr TL^ 15.8ppm ( 3) ------- GOLD CREW DISPERSANT MANUFACTURER COST AVAILABILITY Ara Chem, Inc. P. 0. Box 5031 San Diego, California 92105 $2.50 - $2.75/gal. F.O.B. San Diego ,'California PRODUCT DESCRIPTION Concentrated water-based nonionics and lesser quantity of arly-sulfonates. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 1.035 @ 68° F i Non-flammable 300 cp @ 68° F Soluble in water Unlimited Store @ 0° F to 180° F Avoid eye or open-cut contacts. Non-irritating to skin. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray in a hard coarse spray, diluted 80 times with water @ 150 to 175 psi pressure using Ara- Chem System *which includes injector pump, 200- 300 gpm spray pump and two 1 1/2" spray nozzles. No other agitation required. Dosage Use Limitations REMARKS Dispersant to oil ratio 1:5 to 1:15 by volume. Use on light and heavy distillate, residual and crude oils up to semi-solid weathered state at any temperature. Not recommended for beach cleaning although product is claimed quite effective for this purpose. Manufacturer reports 100% of oil dispersed. One part product to 30 parts oil in lab tests. • *The Ara Chem System cuts a 60-foot swath through the oil slick at boat speeds of 3 to 6 mph with dispersant usage of 1/2 to 3 bblsAr. The system is continuous, requiring no prior mixing of dispersant. ------- (9) At 1:1 ratio emulsified 27.1% Navy Special fuel oil , Spill Experience: Incident San Diego Bay, California - 8 years experience on U. S. Navy Oil Spills. Santa Barbara, California (Feb. 1969). Effectiveness not reported. Toxic ity Tests: Species Reference Fundulus parvipinnis 24 hr Tl^ 128 ppra (18) 96 hr TI^ 128 ppm ------- HEMCO NO. 2 MANUFACTURER Hemisphere Marine Chemicals Co., Inc. 300 Main Street Orange, New Jersey 07050 COST $2.75/gal. AVAILABILITY F.O.B. Orange, New Jersey also Halifax, N.S.; Portland, Maine; and Gulf Coast; Caribbean Islands and Canal Zone PRODUCT DESCRIPTION Aromatic solvent type emulsifier SPECIFIC GRAVITY 0.895 @ 60° F FLASH POINT 160° F (C.O.C.) OTHER Solvent is not biodegradable MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted. Contact time, 15 to 20 minutes before agitation. Educted - dilute 24 to 49 times with water for cleaning beaches and rocks. Dosage Varies Use Limitations For use on oil polluted beaches and harbor waters from -70° F to 140° F. Spill Experience: Incident Ocean Eagle, San Juan, Puerto Rico (March 1968). Halifax, Nova Scotia by Atlantic Salvage and Dredging Co. Palm Beach, Florida by Spencers Boatyard. West Palm Beach, Florida by Florida Diesel Co. (1966-1969). New York Harbor by William J. Shee Co. (1970). Effectiveness not reported on above. Toxicity Tests: Spec ies . Reference Silversides (Atherinomorus stipes) 6 hrs TL-^QQ 100 ppm Moharra (Eucinostomus argent eus) 6 hrs TL^QQ 27 ppm (14) 24 hrs all survived .............. , ..... 10 ppm (14) ------- HOLL-CHEM #622 OIL SPILL DISPERSANT MANUFACTURER COST AVAILABILITY Holl-Chem, Inc. 502-A Maritime Building Seattle, Washington 98104 $3.15 - $3.30/gal. F.O.B. Seattle, Washington 98104 PRODUCT DESCRIPTION Polyglycols, 23%; alkyl-aryl sulphonates, 14.5%; aromatic petroleum solvent, 62.57o. SPECIFIC GRAVITY FLASH POINT SOLUBILITY SHELF LIFE 0.958 @ 60° F 205° F (C.O.C.) Soluble in water Unlimited Store @ 0-140° F OTHER MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray. Agitate immediately. Dosage 'Use Limitations REMARKS Dispersant to oil ratio 1:10 by volume but varies. Use @ 40° F or above on light and heavy distillate residual and crude oil. Not effective on weathered crudes. Not for beach cleaning. Manufacturer reports 99% effectiveness and 10 years experience of product use in Puget Sound and coastal waters from Alaska to Oregon. Lab tests rated product as 2 on a scale 1 (low) to 4 (high) tested visually on medium weight crude oil (API Gravity 29.9)(l7). Toxic ity Tests: Spec ies Steelhead minnow Pacific oyster larvae - Toxic Crassotrea eigas - Non-toxic 96 hr TI^ 3.2 mg/1 0.1 ppm 0.01 ppm Reference (6) (6) (6) ------- IGEPAL CO-430 MANUFACTURER COST AVAILABILITY GAP Corporation 140 West 51 Street New York, New York 10020 $1.28 to $1.78/gal. Linden, New Jersey and Calvert City, Kentucky PRODUCT DESCRIPTION Nonionic. Ethoxylated nonyphenal (Wo ethylene oxide), no solvent. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE 1.02 @ 77° F 500 - 600° F (O.C.) 175-250 cp @ 77° F Insoluble but dispersible in water. Unlimited No limit on storage temperatures. OTHER MANUFACTURER'S USE RECOMMENDATIONS Application Method Eduction @ 2 to 5% concentration. Dispersant to oil ratio 1:33 to 1:100 by volume, Dosage Use Limitations Use on light and heavy distillate, residual and crude oils. REFERENCE ------- IGEPAL CO-530 MANUFACTURER GAP Corporation 140 West 51 Street New York, New York 10020 COST $1.30 to $1.82/gal. AVAILABILITY Linden, New Jersey and Calvert City, Kentucky PRODUCT DESCRIPTION Nonionic. Ethoxylated nonyphenal (54%, ethylene oxide), no solvent. SPECIFIC GRAVITY 1.04 @ 77° F FLASH POINT 480-510° F (O.C.) VISCOSITY 175-250 cp @ 75° F SOLUBILITY Insoluble but dispersible in water. SHELF LIFE Unlimited OTHER No limit on storage temperatures. MANUFACTURER'S USE RECOMMENDATIONS Application Method Eduction @ 2 to 5% concentration. Dosage Dispersant to oil ratio 1:33 to 1:100 by volume Use Limitations Use on light and heavy distillate, residual and crude oils. REFERENCE (5) (14) ------- ISOMAL 265 MANUFACTURER COST AVAILABILITY Johnson-March Corp. 3rd and Berks Street Philadelphia, Pennsylvania 19122 $2.Wgal. (0,28/lb. in 500 Ib. drum) F.O.B.. Philadelphia, Pennsylvania 19122 PRODUCT DESCRIPTION Sulfonated ester, 65%; water, 20%. SPECIFIC GRAVITY 8.7 Ibs/gal @ 78° F FLASH POINT SHELF LIFE OTHER ca 400° F (C.O.C.) Unlimited Store @ ambient temperatures. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted or diluted three times with sea water, mineral spirits or kerosene. Agi- tate immediately. Dosage Use Limitations Dispersant to oil ratio 1:1000 to 1:5000 by volume. Light oils and fresh crudes. REFERENCE ------- JANSOLV-60 JANSOLV-60 W* MANUFACTURER COST AVAILABILITY Sunshine Chemical Corp. P. 0. Box 2041 West Hartford, Connecticut 06117 also P. 0. Box 5534 Jacksonville, Florida 32207 $2.00/gal. F.O.B. Jacksonville, Florida; West Hartford, Connecticut; and Highland Park, Illinois. PRODUCT DESCRIPTION Nonionic water-based surfactants and petroleum- based solvent. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 0.95 @ 75° F 154° F (T.O.C.) 35 sec. @ 75° F, Ford No. 4 Cup Soluble in water Four years Store Jansolv 60 @ 32° F to 250° F Store Jansolv 60 W .@ -10° F to 250° F 5-day BOD - 350,000 mg/l(15) Non-toxic. Threshold limit 500 ppm in air. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray or educt by fire hose diluted 33 to 100 times with water. Reacts immediately. Dosage Use Limitations REMARKS Varies, depending on oil spilled. Use on light and heavy distillate, residual and crude oils,, Not effective on sandy beaches. At 1:1 ratio emulsifies 91.4% of Navy Special grade fuel o *Same as Jansolv 60 except for additive to allow use to -10° C. ------- Spill Experience: Inc ident Ocean Eagle, San Juan, Puerto Rico. Effectiveness unknown. Toxic ity Tests: Spec ies Reference Steelhead minnow fingerlings 96 hr TT^, 35.5 mg/1 ( 6) Mummichog (Fundulus heteroclitus) 24 hr TL 60 mg/1 (13) 96 hr TI^ 27 mg/1 (13) . Fathead minnow (Pimephales promelas) 96 hr TI^, 9.5 mg/1 (17) Pacific oyster larvae (Crassotrea gigas)Toxic 0.8 ppm ( 6) Non-toxic 0.4 ppm Silversides (Atherinomorus stipes) 6 hr TL100 50 ppm (20) 18 hr Tl^ 10 ppm .(20) Moharra (Euc inostomus argentus) 6 hr TL^QQ 27 ppm (20) ------- LCP-12 OIL SLICK DISPERSER MANUFACTURER COST AVAILABILITY Grain Industrial Products Corp. P. 0. Box 34233 Farmers Branch, Texas 75234 also P. 0. Box 1062 2411 Swiss Avenue Dallas, Texas 75221 $2.30 - $2.80/gal. F.O.B. Farmers Branch, Texas PRODUCT DESCRIPTION Octyl-phenoxy-polyethoxy-ethanol, blended with other ingredients SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY OTHER HUMAN HAZARD 8.3 Ibs/gal. Non-flammable Slightly viscous Soluble in water Freezing point, approximately 0° C Non-toxic MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray diluted 3 times with water on light oil slicks. Spray undiluted on thick slicks or heavy oils. Agitate. Reacts immediately. Dosage Toxicity Tests: Spe c ie s For use on light and heavy oils and sludges. Mummichog (Fundulus heteroc litus) 24 hr Tl^, 140 mg/1 96 hr Tiro 140 mg/1 Daphnids (Daphnia magna) 24 hr TL^ 694 mg/1 48 hr TL^ 290 mg/1 96 hr TI^ 204 mg/1 ReEerenc e (13) 11 (19) " w/crude oil 24 hr TLj, 370 mg/1 " 48 hr T^ 275 mg/1 " 96 hr TLjn 102 mg/1 ------- MAGIC POWER OIL DISPERSENT QD #1 MANUFACTURER COST AVAILABILITY Lawton Specialty Co., Inc. P. 0. Box 44 Lawton, Oklahoma 73501 $3.35/gal. F.O.B. Lawton, Oklahoma or Dallas, Texas PRODUCT DESCRIPTION Nonionic. Contains wetting agents and emulsi- fiers in a naptha solvent. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 0.84 @ 75° F 176° F (C.O.C.) 1-6 cp @ 75° F Emulsifies in water 1 year (possibly longer) 5-day BOD @ 20° C - 880 mg/l(15). Store @ 20° F to 140° F. None when used diluted. Estimated threshold limit for inhalation 300 to 350 ppm at 60 to 80° F. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray diluted 1 to 5 times with water. Agitate. Reacts immediately. Dosage Use Limitations Toxic ity Tests: Spec ies Dispersant to oil ratio 1:10 to 1:2000 by volume. Use on light and heavy distillate, residual and crude oils. Reference Fathead minnow (Pimephales promelas) 96 hr 14.0 ppm (15) ------- MAGNUS OIL SPILL DISPERSER MANUFACTURER COST AVAILABILITY Magnus Chemical 400 South Avenue Garwood, New Jersey 07027 $2.85/gal. Inventory at thirteen locations. PRODUCT DESCRIPTION Alkyl-aryl-benzene, nonionic wetting agents, petroleum diluent and odor masking (3%), sta- bilizing and combining agents. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 0.892 @ 60° F 170° F 30.8 seconds Zahn cup No. 1 @ 60° F Emulsifies in water Unlimited pH 8.0. Store at 0° to 130° F. Freezing point 0° C. Avoid eye or skin contact. 500 ppm maximum for inhalation. MANUFACTURER'S USE RECOMMENDATIONS Application Method Use Limitations Apply undiluted as a heavy droplet spray. Do not fog or mist chemicals as it reduces efficien- cy,, The product can be applied by low volume (0-3 gpm), low pressure (10-30 psi) pump, or by air driven drum pump; a lube pump, or pressure- pot top sprayer. May also be educted at 3 to 5% by volume^ Dispersant oil ratio at 50° F. 1: 8 to 1:10 by volume for Bunker C. 1: 3 to 1: 5 by volume for weathered crude. 1:20 by volume for distillate fuels. Contact time 10-20 minutes for penetration. For use on gasoline, kerosene, heating oil, jet fuel, Bunker C, other distillate fuels and crude oil. Not a beach cleaner. Best results at 50° F and above» Not effective on heavy asphalt residues,, ------- REMARKS Manufacturer reports product passes all tests of MIL-Spec C 22864A (Ships). At 1:1 ratio 36.6% of Navy Special Fuel oil was At i:l ratio 3b.6% ot Navy emulsified in lab tests^). Spill Experience: Inc ident (General Colocotronis) Eleuthera Island, Bahamas - 150 drums used. Effectiveness not determined. Ocean Eagle, San Juan, and Ensenada Harbors, Puerto Rico - Ineffective. Albany, New York - 50,000 gallon heavy oil spill. Effectiveness unknown. Norfolk, Virginia - used by Industrial Marine Service, Inc. after physi- cal removal of most of the oil - Effectiveness unknown. Toxic ity Tests: Species Reference Pinfish (Lagadon rhomboides) 48 hr TI^, 26.9 ppm (25) Mummichog (Fundulus heteroc litus) 48 hr TI^ 10 ppm 24 hr TI^ 175 ppm (13) 96 hr Tiro 43 ppm Zebra fish (Brachydanio rerio) 1 of 5 survived 24 hrs @ 40 ppm (12) Marine f ish (Gambusia) 4 of 21 dead 24 hrs @ 1 ppm (23) 6 of 21 dead 24 hrs @ 15 ppm 16 of 21 dead 24 hrs @ 30 ppm NOTE; Two other Magnus products not recommended by manufacturer for dispersing oil spills on water are two degreasers - Magsol 3 and 701. ------- MET AOUACLENE 100 MANUFACTURER COST AVAILABILITY Metropolitan Petroleum Petrochemicals Co., Inc. 24 Caven Point Road Jersey City, New Jersey 07304 $3.75/gal. F.O.B. Jersey City, New Jersey (> 50 miles) PRODUCT DESCRIPTION Nonionic - Blend of alkanolamides - 100% SPECIFIC GRAVITY 1.004 @ 60° F FLASH POINT 350° F (P.M.C.C.) VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 135 SSF @ 70° F 185 SSF @> 40° F Completely soluble in water Unlimited pH 9.8. Freezing point 25° F. Store @ 15° to 200° P. 5-day BOD @ 20° C - 840,000 mg/l(15). Non-toxic MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray full strength or dilute with water, down to 4% solution. Agitate. Reacts immediately. Dosage Use Limitations REMARKS Dispersant to oil ratio 1:1 to 1:12 by volume. Use on light and heavy distillate, residual and crude oils at all temperatures. Manufacturer reports 100% oil dispersion, at 1:1 ratio with No. 6 oil (20 mis) in 400 ml water, 30 sec. agitation, 1-12 hours standing time. ------- Spill. Experience: Inc ident Used on several small spills in New England. It is the prescribed and inventoried chemical along the St. Lawrence Seaway. Approved for use in reservoir for potable water supply by Dept. of Health in Massachusetts in 1967. Used on Bunker C oil spill at Gulf Oil Co., Philadelphia, Pennsylvania in January 1970. Product was not effec- tive after trying three times to disperse oil. Air temperature was 20° F, water temperature approximately 35° F. The dispersant seemed to remain on top of oil slick with no emulsif icat ion after fire hose agitation. Dispersant had to be warmed prior to use Toxic ity Tests: Spec ies Ref . Fathead minnow (Pimephales promelas) 96 hr 11^ 25.0 ppm (15) w/oil 96 hr Tl^ 42.0 ppm Mummichog (Fundulus heteroc litus) 24 hr TL^, 110 mg/1 (13) 96 hr TLjj, 32 mg/1 Fathead minnow (Pimephales promelas) 96 hr TLm 50 ppm Sof.tshell clam (Mya arenia) 96 hr TL^ 50 ppm (33) Mummichog (Fundulus heteroc litus) 96 hr TI^ 44 ppm " Winter flounder (Psuedo pluronectus)* 96 hr Tl^ 20 ppm " Lobster (Homarus americana) 96 hr TL^, 46 ppm " Edible mussel (Mytilus edulis)* 96 hr TI^ 40 ppm Atlantic Silversides 96 hr TL^ 25 ppm *tentative subject to revision ------- OD-2 MANUFACTURER COST AVAILABILITY Grain Industrial Products Corp. P. 0. Box 34223 Farmers Branch, Texas $2.45 - $2.95/gal. F.O.B. Fanners Branch, Texas PRODUCT DESCRIPTION Anionic SPECIFIC GRAVITY Density 8.5 Ibs/gal. Non-flammable Soluble in water Non-toxic FLASH POINT SOLUBILITY HUMAN HAZARD MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray under pressure through small nozzle diluted 3 times with water. Contact time 20-30 minutes. For heavy oils apply undiluted. Dosage REMARKS Toxic ity Tests: Spec ies Fundulus parvipinnis Dispersant to oil ratio 1:6 by volume Union Oil Co. reported 1:3 or 1:4 dispersant to oil rati 48 hours oil ratio produced light emulsion which was stable (14) 96 hr TLj, 118 ppm Mummichog (Fundulus heteroc'litus) 24 hr TLj, 55 mg/1 96 hr TLj, 54 mg/1 Re£. (18) (13) ------- OIL SPILL ERADICATOR X-l-11 MANUFACTURER Xz it Chemical Company 56 Newark Street Hoboken, New Jersey 07030 COST $3.30 - $3.81/gal. AVAILABILITY F.O.B. Hoboken, New Jersey SPECIFIC GRAVITY 0.980 @ 68° F FLASH POINT None (C.O.C.) VISCOSITY 150 cp (Room Temp.) SOLUBILITY Insoluble in water SHELF LIFE Unlimited OTHER Store @ 50° F to 122° F MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted 10 to 50 times with water. Contact time - 30 minutes. Dosage Dispersant to oil ratio 1:10 to 1:50 by volume. Use Limitations Minimum temperature for use 50° F. Use on light and heavy distillate residual and crude oils. Recommended for beach cleaning. Spill Experience: Inc ident No. 5 Fuel Oil cleaned from Bermuda Beach near Princess Hotel. Manu- facturer reported all oil was dispersed and the beach sand completely cleaned. Toxicity Tests: Spec ies Referencg Salmon 40% dead 96 hrs 20 ppm (23) Herring 10% dead 120 hrs 5 ppm 6C% dead 120 hrs 10 ppm NOTE; In this study conducted by Fisheries Research Board of Canada the above toxic ity data is for XZIT which may be Oil Spill Eradicator X-l-11. REFERENCE ------- (PETROLITE) W-1439 (TRET-O-LITE) MANUFACTURER COST AVAILABILITY Petrol it e Corporation Tretolite Division 369 Marshall Avenue St. Louis, Missouri 63119 also 2 West 4th Street New York, New York 10017 $2.90/gal. F.O.B. St. Louis, Missouri and Brea, California. Distribution points: New Orleans, Louisiana; Houston, Texas; and Philadelphia, Pennsylvania. PRODUCT DESCRIPTION Tank cleaner. Contains acylamide, 44%; water, 26%; 'dipropylene alcohol, 10%; isop.ropanol, 20%. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 0.976 @ 21° C 94° F (open cup) 77 SSU @ 100° F Soluble in water Unlimited Pour point > 10° F Non-toxic MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray diluted 1 to 4 times with water by volume. May also be used undiluted. Agitate. Reacts immediately. Dosage Use Limitations REMARKS Dispersant to oil ratio 1:5 to 1:10 by volume. Primarily for tank cleaning(10). Recommended for light and heavy distillate, residual and crude oils. Manufacturer reports approximately 100% of oil dispersed by laboratory tests. Laboratory tests rated W-1439 as 2 on a scale of 1 (high) to 4. (low). Visual observations used for ------- comparison with 10 other dispersants. Tested against medium weight crude oil (A.P.I, Gravity 29.9°)(1U). .Toxicity Tests: Spec ies Ref. Steelhead minnow fingerlings 96 TI^ 35.5 mg/1 ( 6) Zebra fish (Brachydanio rerio) 0 of 4 survived 2k hrs @ 10 ppm (12) Pacific oyster larvae Toxic cone. 1.5 mg/1 (6) (Crassotrea gigas) Non-toxic cone. 0.8 mg/1 " ------- (PETROLITE) WF-30 MANUFACTURER Petrolite Corporation Tretolite Division 369 Marshall Avenue St. Louis, Missouri 63119 COST $2.00/gal. .- 55 gal. drum F.O.B. St. Lou;'is, Missouri and Brea, California. PRODUCT DESCRIPTION 50% Aryl sulfonate - 50% aromatic solvent 0.94 @ 75° F 136° F (open cup) 74.7 SSU @ 100° F Dispersible in water Unlimited Store @ 40° to 120° F Avoid skin contact AVAILABILITY SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray - followed by .ag it at ion. Contact time - variable, depending on age of oil. Dosage Use Limitations Dispersant to oil ratio 1:5 to 1:20 by volume. Recommended for use on light and heavy distill- ates, residuals and crude oils. ------- POLYCLENS (MOLTOKLAR)* MANUFACTURER COST AVAILABILITY Polycell Products, Ltd. Broadwater Road Welwyn Garden City Hertfordshire, United Kingdom also Cadix, Great Britain Ltd. and Cadix-Natre of Antwerp $0.67 to $1.09/gal. England PRODUCT DESCRIPTION ' Paint brush cleaner. Contains polyglycols, 10%; petroleum naptha, 90%. SPECIFIC GRAVITY FLASH POINT SOLUBILITY 0.87 @ 50° F 116° F to 120° F (A.C.C.) Emulsifies in water Store below 104° F OTHER MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted Dosage Dispersant to oil ratio 1:2 to 1:4 by volume. Use Limitations Effective on oils with viscosity <6000 sees. REMARKS Manufacturer reports 100% emu Is if ic at ion of oil. At 1:10 ratio emulsified 54% HD-SAE 20 motor *In Germany, Polyclens is known as Moltoklar (Marine Engineer, p. January 1961 (U.K.) ------- Spill Experience: Inc ident "Esso Portsmouth" - Milford Haven, U. K. (1961) Anne Mildred BreCvig, North Sea (February 1966)^ Effectiveness not reported on the two above incidents. Toxic ity Tests: Spec ies Reference Pink shrimp (Pandalus montagui) 48 hr Tin, 8-5 PPm (3) . Brown shrimp (Crangon crangon) 48 hr TLm 15.7 ppm " Shore crabs (Carcinus maenas) 48 hr TI^ 23.2 ppm " Cockles (Gardium edule) 48 hr TLm 70.0 ppm " ------- POLYCOMPLEX A-ll AND A 11 D* MANUFACTURER Guardian Chemical Corp. 41-45 .Crescent Street: Long Island City, New York 11101 COST AVAILABILITY Sole International Distributor; Ocean-Wide Marine Supply'Co. Box 827 Huntingdon, New York 11743' $3.75/gal. $3.80/gal. plus $!4.00/dr. on west coast F.O.B. Long Island City, New York. Inventory at Santa Barbara, Gulf Coast, Boston,. Chicago and Miami. PRODUCT DESCRIPTION A water-based nonionic oil complexing, blend of alkanolamides. Also described as amino-amido complex with 52% water. SPECIFIC GRAVITY FLASH POINT VISCOSITVx SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 1.005 370° F (OoCo) Auto-ignition temp. 400° F 150-160 cp at room temp. Soluble in water Unlimited May freeze below 32° F. pH 9.5 - 9.8. Boiling point: 370° F. None to operators. Threshold limit 500 ppm plus. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray diluted 4 times with sea water at 60-100 psi. Agitate after 3 to 5 minutes reaction time. Dosage Use Limitations Dispersant to oil ratio 1:7 to 1:12 by volume. More required for heavy oils,, Most effective with #2 to #5 fuel oils, but is not effective for Bunker C. *Polycomplex A-ll is a water solution of Polycomplex A. A-ll contains 47-49% of active agents - 51-53% water. A-ll D contains 33% of active agents - 67% water. ------- REMARKS Manufacturer reports all visible oil dispersed. Sun Oil Co., Philadelphia, reports 1:8 ratio effective for crude and fuel oils. Gulf Oil Co. reports 1:10 ratio effective. Spill Experience: Inc ident Ocean Eagle, San Juan, Puerto Rico, March 1968 - Ineffective Santa Barbara, Union Oil Co. (247 bbls. used) February-March 1969 - Not determined. Toxicity Tests: Spec ies See attached sheets ------- SUMMARY OF TOXICITY TESTS ON POLYCOMPLEX A-ll Test Organism Mummichog (Fundulus heteroc litus) Fathead minnow (Pimephales promelas) Steelhead minnow (Fingerling) Fundulus parvipinnis Zebra fish (Brachydanio rerio) Moharra (Euc inostomus argenteus) Silversides (Artherinomorus stipes) Herring (Harengula c lupeola) Sergeant major (Abudefduf saxatilis) Brine shrimp (Artemia salina) With Navy #4 fuel (diesel) oil Reported As Concentration 24 hr TI^ 96 hr TLn, 96 hr TLm 96 hr TLm 24 hr TLm 96 hr TLm 24 hr (none of 5 survived) 18 hr TLo 6 hr TL33 12 hr TL100 6 hr TL10Q 18 hr TL10Q 12 hr TL33 6 hr TL1Q0 75% showed loss of balance @ 18 hr TLo 72 hr TL10Q 8 hr TL10Q 40 40 13.0 13.0 225 . 134 30 5 10 27 100 5 10 100 5 5 100 500 mg/1 mg/1 ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm Reference (13) (17) (6) (18). (17) (20) tt ft Tt tt tt tt tt tt (21) 1 T ------- SUMMARY OF TOXICITY TESTS ON POLYGQMPLEX A-ll (Cont'd) Test; Organism. Reference Killifish (Fundulus diaphanus) Killifish (Fundulus. heteroclitus) Marine f ish (Gambusia) Clams (Mercinaria mercinaria) Commercial oyster All affected in None of 5 survived 12 of 22 dead in None of 21 surved 20 hrs @ 100 ppm 18 hrs @ 33 mg/1 24 hrs @ 15 ppm 24 hrs @ 30 ppm When tested at 0, 83, 107, 335, 670 and 1005 mg/1, the following was observed: At the 0.0 control concentration, various numbers of clams were ob- served pumping and no deaths occurred. Only once at the lowest concentration (83 mg/1) was one clam observed not pumping. At 48 hours, deaths started to occur; with several clams dying at the three highest concentrations. This is meaningful as clams can or are supposed to stay alive in a bactile environment for weeks at a time. The oysters were exposed to Polycomplex and Navy #4 Fuel Oil at 1:9 ratios in a flowing seawater system for 96 hours with the following results: @ 400 ppm - shell growth decreased 99% (approx.) @ 200 ppm " . " " 65% @ 100 ppm - " " " 65% @ 50 ppm - " " " 50% When placed in clean flowing seawater after testing, all oysters, at all concentrations tested, recovered. (21) (22) (23) . M (22) (21) ------- RIDZLIK MANUFACTURER COST AVAILABILITY Ashland Chemicals Industrial Chemicals & Solvents Division 8 East Long Street Box 2219 Columbus, Ohio 43216 $1.50/gal. - 55 gal. drum F.O.B. 50 locations in U. S. PRODUCT DESCRIPTION Contains a highly concentrated water-based surfactant. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 0.9799 @ 60° F 95° F (T.O.C.) 3.99 cs @ 100° F 39.1 SUS @ 100° F Stable for long periods in proper containers. Pour point 0° F Freeze point 0° F Store above 0° F Very low MANUFACTURER'S USE RECOMMENDATIONS Application Method Sprayed or sprinkled. Educted at rate of 1 quart per 100 gals, of water for large slicks. Can be used with fire fighting foam eductors. Use Limitations Toxicity Tests: Species Opal eyed perch Recommended' for distillate and crude oils. Not specifically recommended for use on Bunker C. Minimum water temperature of 10° F. 72 hr 34.4 ppm Reference (25) (Girella nigracans) Average 24-72 hr TL^ 36.4 ppm ------- SEAMULSO E MANUFACTURER COST Turco Chemische Producten N.V. Verl. Blokkenweg 12 Ede, Holland $2.17/gal. in Holland PRODUCT DESCRIPTION Aromatic diluent - 70% SPECIFIC GRAVITY 0.94 151° F P.M. 5 cp @ 25° C Emulsif iable in water Unlimited Threshold limit of 250 ppm -FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE HUMAN HAZARD MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted. Contact time 15 to 30 minutes before agitation. Dosage Use Limitations REMARKS About 2.5 to 12.5 gal/100 ft2 of surface. For use on light and heavy distillate, residual and crude oil. Manufacturer reports product will completely emulsify in time all oil and tar. REFERENCE ------- SKANEX S-102 MANUFACTURER Scandinavian Oil Service Stora Badhusgatan 20 S-41121 Gothenburg, Sweden COST AVAILABILITY Domestic Representative: Surface Separator Systems, Inc. 103 Mellor Avenue Baltimore, Maryland 21228 $3.6Vgal. (1-55 gal. drum) F.O.B. Gothenburg, Sweden PRODUCT DESCRIPTION Polyglycolethers (3), 107<>; naptha diluent, 90% (includes aromatics (maximum), 207o) SPECIFIC GRAVITY FLASH POINT SOLUBILITY SHELF LIFE HUMAN HAZARD 0.79 153° F (P.M.) Emulsifies in water Unlimited Avoid eye and skin contact. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray. Agitate. Reacts immediately. Dosage Dispersant to oil ratio 1:2 to 1:10 by volume. Use Limitations For use on light and heavy distillate, residual and crude oils at temperatures greater than 38° F in sea water (not fresh water). REMARKS Used by Swedish Coast Guard to control several spills. Effectiveness not reported. ------- SLIX MANUFACTURER COST AVAILABILITY Amerace-Esna Corp. Chemical Specialties Division 7>4 Hudson Avenue Tenafly, New Jersey 07670 $2.85 - $3.07/gal. (1-55 gal. drum) F.O.B. Tenafly, New Jersey and Los Angeles, Gal if ornia PRODUCT DESCRIPTION Blend of nonionic and anionic surfactants, 33.8%; alkaline silicate, 3%(25); 10-15% silicates and hydrotropes(5) _ Also, nonionic alkyl-phenoxy ethoxy-ethano1, U57o with water SPECIFIC GRAVITY FLASH POINT SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD MANUFACTURER'S USE RECOMMENDATIONS 1.046 @ 68° F Does not burn Soluble in water Unlimited pH 11.5. Keep from freezing. Possible dermatitis from prolonged contact Application Method Spray diluted 1 to 4 times with sea water. For eduction dilute 19 to 32 times. Dosage Use Limitations REMARKS NOTE Dispersant to oil ratio 1:20 by volume, with greater ratio for thin slicks. Use 1 gal/100 ft2, For use on light and heavy distillate, residual and crude oils at temperatures between 50° to 80°. F. Not for use on shores. Manufacturer reports 1007o of oil emulsified - most efficient conditions. Dispersant to oil ratio 1:10 gave 70% emu Is ifi- cation of HD-SAE 20 motor oil(l7). Available in England from: Safety Cleaning Solvents Ltd. P. 0. Box 10 Egham, Surrey, England(ll) ------- Spill Experience: Inc ident Anne Mildred Br^vig, Feb. 1966 North Sea - crude oil Albacape, 1966, New York Harbor - 2,000 gallons used Effectiveness not determined on the two above incidents. Toxic ity Tests: Species Reference Pink shrimp (Pandulus montagui) 48 hrs TLn, 12.1 ppm (3) Brown shrimp (Crangon crangon) 48 hrs Tl^, 114.5 ppm " Shore crabs (Carcinus maenas) 48 hrs Tl > 150 ppm " Cockles (Cardium edu.le) 48 hrs Tl^ 12.7 ppm (13) Mummichog (Fundulus heteroclitus) 24 hrs TI^ 16 mg/1 Zebra fish (Brachydanio rerio) No survival @ 10 ppm (12) Bluegill 96 hrs TI^ 10.5 ppm (33) Yellow Peach 96 hrs TI^ 3.2 ppm ------- SPILL-X MANUFACTURER COST AVAILABILITY Pacific Chemical 4501 Shilshole N.W. Seattle, Washington 98107 $3.45/gal. (1-55 gal. drum) F.O.B. Seattle, Washington PRODUCT DESCRIPTION Primarily a degreaser SPECIFIC GRAVITY FLASH POINT SHELF LIFE OTHER 0.914 - 0.92 @ 68° F 220° F (C.O.C.) Two years Store @ 0° - 120° F MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted. Agitate. Dosage Use Limitations REMARKS OTHER Varies with conditions For use on light and heavy distillate, residual, and crude oil at any temperature. Rated 2 on lab test and 1 on field tests on a scale of 1 (low) to 4 (high). Tested visually against 10 other dispersants. Medium weight crude oil used (A.P.I. Gravity 29.9°~)^17\ At 1:1 ratio 41.1% of Navy Special Fuel oil emulsified^ '. ------- SURFLO RD 282 MANUFACTURER COST AVAILABILITY National Lead Company Baroid Division P. 0. Box 1675 Houston, Texas 77002 $3.25/gal. F.O.B. Houston, Texas PRODUCT DESCRIPTION Oxyalkylated ester, 40%; oxyalkylated alcohol, 10%; esters, 2.5%; water diluent, 37.5%; alcohol dilutent, 10%. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 0.997 A 65° F 168° F (T.O.C. ) 275 SSU @ 70° F Soluble in water Unlimited Store @ -10° F to 150° F Contact is not hazardous unless specific aller- gies develop. Contains no known chemicals known to be particularly toxic by inhalation. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted. Dilute 19 to 400 times with water for larger slicks. Dosage Use Limitations REMARKS Toxic ity Tests: Spec ies Dispersant to oil ratio 1:10 to 1:100 by volume. Recommended for light and heavy distillate, residual and crude oils. Not recommended for use in potable water supplies. Manufacturer reports 1 ml keeps 10 mis of oil dis- persed in 90 mis of sea water for 24 hours. Reference Black mollies No Kill, 24 hrs @ 100 ppm (14) ------- Spill Experience: Inc ident Lake Union, Seattle, Washington - spill by Washington Natural Gas Co. Willamette River, Portland, Oregon - several spills cleaned up by Shaver Transportation, Portland, Sitka Harbor, Alaska - used on spill on harbor and on Puget Sound, Bremerton, Washington - several spills by Puget Sound Navy YardCl4) 'Toxic ity Tests: Species Reference Steelhead minnow f ingerlings 96 hr TLj, 35.5 ppm (6) Pacific oyster larvae Toxic 1.5 ppm. (Crassotrea gig as) Non-toxic 0.4 ppm ------- TALENT MANUFACTURER COST AVAILABILITY Wyandotte Chemicals Corp. J. B. Ford Division Wyandotte, Michigan 48192 $3.15/gal. Manufactured at five plants in the United States and Canada PRODUCT DESCRIPTION Heavy duty liquid syndet for use with sea water. Contains nonionic detergents and water diluent. SPECIFIC GRAVITY FLASH POINT VISCOSITY SOLUBILITY SHELF LIFE OTHER HUMAN HAZARD 1.03 200° F (P.M.C.C.) 5.0 cp @ 68° F Miscible with water Unlimited Store @ 0° to 140° F Non-toxic to operators MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted. Agitate. Reacts immediately. Dosage Use Limitations REMARKS Toxicity Tests: Species Dispersant to oil ratio 1:1 to 1:40 by volume, depending on viscosity of oil. Recommended for small spills of distillate fuel or other light oils. In lab test at a 1:1 ratio, emulsified 16.3% of Navy special fuel Reference Goldfish 45 (14) ------- TEOC 444 MANUFACTURER COST AVAILABILITY Teoc, Inc. P. 0. Box 513 1100 Victory Drive Westwago, Louisiana 70094 $3.30/gal. in ten drum lots F.O.B. Westwago, Louisiana PRODUCT DESCRIPTION Nonionic surfactants and aliphatic solvent. SPECIFIC GRAVITY 0.846 @ 75° F FLASH POINT 104° F (T.C.C.) SOLUBILITY Complete dispersion in water OTHER Store @ less than 212° F HUMAN HAZARD Threshold limit value of 500 ppm for inhalation. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted. Dilute 3 times with water for plane spraying or in strong winds. Dosage Use Limitations REMARKS Dispersant to oil ratio of 1:10 for average light crudes found in South Louisiana. Contact time varies. The finer the spray, the more effective will be application. Recommended for use on Bunker C and fresh crude oil. Manufacturer reports 100% effectiveness. The heavier the oil the poorer is the effectiveness. "Dead" oil or old pit oil may not be dispersed. REFERENCE ------- TEOC 777 MANUFACTURER COST AVAILABILITY Teoc, Inc. P. 0. Box 513 1100 Victory Drive Westwago, Louisiana 70094 $3.30/gal. in ten drum lots F.O.B. Westwago, Louisiana PRODUCT DESCRIPTION Nonionic 37.3% aliphatic diluent - 62.7% SPECIFIC GRAVITY 0.837 @ 75° F 104° F (T.C.C.) Complete dispersion in water Store @ less than 212° F Threshold limit value 500 ppm for inhalation FLASH POINT SOLUBILITY OTHER HUMAN HAZARD MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted. For plane spraying or appli- cation in strong winds dilute 1:3 by volume with water. Dosage Use Limitations REMARKS Dispersant to oil ratio 1:20 by volume, but var- ies with changing conditions. Contact time varies. The finer the spray the more effective will be the application. Recom- mended for use on Bunker C and fresh crude oil. Manufacturer reports 100% effectiveness.' The heavier the oil, the poorer is the effective- ness. "Dead" oil or old pit oil may not be dispersed. REFERENCE ------- TYFOSOL 80 MANUFACTURER COST National Research and Chemical Company 1250 Cerise Avenue Hawthorne, California 90250 also 30 East 42nd Street New York, New York 10001 $5.00/gal. in five drum lots PRODUCT DESCRIPTION Polyglycols, 6%; amines, 11%; nonionics, 40%. Also described as a blend of amineamido sul- phonates and alkanolamide-type detergents. SPECIFIC GRAVITY FLASH POINT SOLUBILITY SHELF LIFE HUMAN HAZARD 0.945 @ 20° F 150° F (C.O.C.) Emulsifies in water One year or more Non-toxic to personnel. MANUFACTURER'S USE RECOMMENDATIONS Application Method Spray undiluted Dosage Use Limitations REMARKS Dispersant to oil ratio of 1:33 to 1:50 by volume should emulsify Bunker C. Recommended for use on light and heavy distill- ate, residual, and crude oils. Passes MIL-C-22230 tests Toxic ity Tests: Spec ies Reference Mummichog (Fundulus heteroc litus) 24 hr TI^ 13.5 mg/1 (13) 96 hr TLn 13.5 mg/1 ------- (WYANDOTTE) SPILL REMOVER1 MANUFACTURER COST AVAILABILITY Wyandotte Chemicals Corporation J. B. Ford Division Wyandotte, Michigan 48192 $2.55/gal. (1-55 gal. drum) FoO.B, Los Angeles, California; Stroudsburg, Pennsylvania; Atlanta, Georgia; Wyandotte, Michigan; and Venezuela PRODUCT DESCRIPTION Polyglycols, 33%; and aromatic solvents SPECIFIC GRAVITY 0.9 FLASH POINT 160° F (T.C.C.) VISCOSITY 5.5 cps @ 68° F SOLUBILITY Emulsifies in water SHELF LIFE Unlimited OTHER HUMAN HAZARD Store @ 0° F to 140° F. 5-day BOD @ 20° C 630,000 mg/l(15) Relatively non-toxic MANUFACTURER'S USE RECOMMENDATIONS Application Msthod Sprinkle or spray undiluted in a solid stream using a low pressure nozzle. Agitate. Contact time, 3 to 20 minutes for heavy fuel oils and crude. Atomizing or fogging nozzles not recom- mended. Dosage Use Limitations REMARKS Dispersant to oil ratio 1:5 by volume. For Bunker C or Navy Special 1:3 by volume. Use on light and heavy distillate, residual and crude oils in both fresh and sea water. Manufacturer reports product passes requirements of MIL-S-22864-A (Ships). Disperses approximate- ly 5 times its weight in oil. Dispersant to oil ratio of 1:10 emulsified 70% of HD-SAE 20 motor *Same or similar to Casol except flash ------- Toxic ity Tests: Species Reference Fathead minnow (Pimephales promelas) 96 hr Tl^, 5.6 ppm (15) Goldfish (Estimated) Tl^ 15 ppm ------- SECTION B ------- SECTION B The following dispersant products are listed in Section B: ACTUSOL ACTUSOL T-776 AFCO #5350 ACTEMUL ACTEMUL U.C. AMEROID DREWCLEAN 522 AMWAY INDUSTROCLEAN ANTI-OIL TS 3 ANTI-OIL TS 5 AQUANIX AQUATREAT ASCAL SUPER 7-11 ATLAS 1901 AUTOMATIC TANK WASH BAROID SLIX-5 BASIC-H BASAL AD 6 BD-30 BERGEN BIG RED CESCO CEJER APC CIRRASOL CHEVRON NI-0 CLEANOSOL CLEANER - 8671 CLOCK 06:39 COB COLDCLEAN COMPOUND RICHONAGE YLA CONGO EMULSIFIER 700 CON-0-1571 C-REINIGER CRONAX (OIL SPILL) CW SOLVENT DART DBG PLUS DECK GLO DEGREASER 80 G DEGRECO DERMOL D.G. Ok DI-CHEM 322 DI-CHEM 325 DI-CHEM 400 DISPERSITE 110 DISPERSAL DISOLVOL DISSOLVO DREW SC 96 DREW TANK CLEANER NO. DUNHAM D-166 ELIMAX ------- EMSOL ESSO F-6155 EMULSIFIER K E-147 (SHANNON) E-314 FASOLV FINA SOL FINA TAR SOLVENT FINA TAR SOLVENT E.S. FINA-UNISOL P.O. 399 GREESKILLA 3 GULF AGENT 822 GULFSIL DE-GREASER HAMCX) HEPACOLITH HOUGHTOSAFE 112 HOUGHTOSOLV HOUGHTON-DETERGENT HYDRO-GAMOSOL H-4000 ICI SURFACTANT IMC-SWS IGEPAL RC 520 JAY KLEARFAC AA040 KLEARFAC AA270 KLEARFAC AA420 KLEARFAC AB270 KELITE A-108-1 KILL-SPILL-D-166 KOR-14 K-RITE 300 KURI-CLEAN "SD" LIX 336 LIQUID CONCENTRATE LISSAPOL N.X. MABEC-PP5 MABEC-21T MAGNA MAGNUS MARINE DISPERSER MARINE CLEANER 8551 MARINE CLEANER 8555 MARITEC OIL SPILL REMOVER METCLENE SPECIAL METCLENE METSPERE MIGHTY MATE MILCHEN MIL-EMULSIFIER MILCHEN PPS MURCO-OSE #2 NAVEE 42 ------- NAVITONE NEOS AB NORSEMEN 67 NORSEMEN 69 NYSTOL O.S.E. #79 OIL & GREASE REMOVER OIL & GREASE REMOVER OIL AND SPILL ERADICATOR OIL EX OIL GO OIL MEGA OIL SLICK EMULSIFIER #5189 OIL SPILL OIL SPILL DISPERSER OIL SPILL REMOVER #1 OIL SPILL REMOVER #2 OSR-7348 OXANE OXANEEZ PARDAG HEAVY DUTY PENTRON-D PENTRON TC-30 PERMAG #41 PERO-KLEAN No. 801 PERO-KLEAN No. 805 PERO-KLEAN No. 818 PETRO-BAN PILOT OIL SPILL ERADICATOR P.O. 576 POLY-ZYME PRODUCT 20215 RETZLOFF 1-4016-P S-l S-5 SANTOMERSE ME-B SLURRY SEA CLEAN 70 SEA GREEN 50 A SEA GREEN 70 SEA SWEEP SELF RINSE SEPTEX SHIP CLEAN SILLARIT SKANEX QUICK SLICKAWAY SLIPCLEAN SLICKGONE I SLICKGONE #2 SNOWDRIFT SP 162 STREP 33 ------- STRUKTOL SURFACTANT 8851 SURFEMUL #5 SWABY TANK-GLO TCC-569 (Grain) TEEPOL ,TERGITOL 15-S-5 TERGITOL 15-S-9 TIP TOP CLEANER TRACER-TECK TRET-0-LITE TRICON TURCO (TWELVE) 12 N DEGREASER UNICO CONCENTRATE UNISOL-FE VECOM B-24 VISCO C-16-F WEN-DON FORMULA 203 WHITTAKERS G.P. DEGREASANT WYANDOTTE 20 ZIF ------- ACTEMUL MANUFACTURER PRODUCT DESCRIPTION COST SPECIFIC GRAVITY FLASH POINT FIRE POINT SOLUBILITY OTHER POUR POINT APPLICATION METHOD Aetna Chemical Corp. Power Division East Paterson, New Jersey 07407 Heavy-duty degreaser. Emulsifiers, wetting agents and solvents which are 99% aromatic. $2.25/gal. 0.9639 @ 60° F 195° F (C.O.C.) 210° F (C.O.C.) Soluble in water pH 8.0 -30° F Spray full strength or dilute 1 to 10 times with water. ACTEMUL U.C. MANUFACTURER PRODUCT DESCRIPTION COST SPECIFIC GRAVITY FLASH POINT POUR POINT FIRE POINT BOILING POINT HUMAN HAZARD Aetna Chemical Corp. All-purpose degreaser. Nonionic - petroleum solvent and detergents. $2.25/gal. 0.9639 @ 60° F None (C.O.C.) 5° F None (C.O.C. ) 95° C Avoid prolonged contact ------- MANUFACTURER PRODUCT DESCRIPTION SPECIFIC GRAVITY FLASH POINT REFERENCE (25) ACTUSOL W. R. Grace & Co. Du Bois Chemical Division Union Avenue & Du Bois East Rutherford, New Jersey 07070 Contains vegetable oil soap, alkali and ali- phatic solvent. 0.895 - 0.905 135° F (C.O.C.) ACTUSOL T-776 MANUFACTURER COST W. R. Grace & Co. $2.50/gal.(10) PRODUCT DESCRIPTION Nonionic surfactant, petroleum sulfonate, pine oil, cyclohexanol, and aliphatic solvent. SPECIFIC GRAVITY FLASH POINT Toxic ity Tests: Spec ies (Bulk density) 8.25 Ib/gal. 135° F Ref. Steelhead minnow f ingerling 96 hr TLj, 24.0 ppm (6) AFCO #5350* MANUFACTURER Alex C. Ferguson Co., Inc. Philadelphia, Pennsylvania 19104 COST \ $2.40/gal. 1 REFERENCE (5)(26)(28) *Also called AFCO OIL SPILL ERADICATOR ------- AMEROID DREWCLEAN 522 MANUFACTURER Drew Chemical Corp. PRODUCT DESCRIPTION Degreaser. Contains emulsifiers, wetting agent . and solvent with weak aromatic odor. SPECIFIC GRAVITY 0.920 @ 20° C FLASH POINT 168° F CLOUD POINT 10° F REFERENCE (25) AWAY INDUSTROCLEAN MANUFACTURER Amway Corp. Ada, Michigan 49301 PRODUCT DESCRIPTION Non ionic with trace of an ionic REFERENCE (29) ANTI-OIL TS 3 MANUFACTURER German Reference (1) ANTI-OIL TS 5 MANUFACTURER German Reference (1) EFFECTIVENESS- At D/0 ratio of 1:10 emulsified 68% of HD-SAE 20 motor oil. AQUANIX MANUFACTURER . Milehen, Inc. Box 2211 Houston, Texas 77001 ------- . AQUATREAT MANUFACTURER Carter Chemical Co. 250 Fulton Avenue Hempstead, New York 11550 PRODUCT DESCRIPTION Physical and chemical characteristics identical to Polycomplex. REFERENCE (25) ASCAL SUPER 7-11 MANUFACTURER German Reference SPILL EXPERIENCE Used during Anne Mildred Br^vig Tanker incident in North Sea. REFERENCE (1)(8)(26) ATLAS 1901 MANUFACTURER Atlas Preservative Co., Ltd. Fraser Road Erith, Kent, England COST $1.60/gal. PRODUCT DESCRIPTION Solvent based DOSAGE Dispersant to oil ratio 1:4 by volume Toxicity Tests: Species Ref, Pink shrimp (Pandalus montagui) 48 hr TL^ 87 ppm (3) Brown shrimp (Crangon crangon) 48 hr TLj, 120 ppm " Shore crabs (Carcinus maenas) 48 hr TLm > 150 ppm " Cockles (Cardium edule) 48 hr TI^ 48 ppm " REFERENCE (3)(26) AUTOMATIC TANK WASH MANUFACTURER Magnus Chemical Co. EFFECTIVENESS In lab test @ D/0 ratio 1:1 emulsified 14% of Navy Special grade fuel oil. REFERENCE (16)" ------- BAROID SLIX-5 DEGREASER MANUFACTURER National ,Lead Co> PRODUCT DESCRIPTION Contains glycol-ether, solvents REFERENCE (26) BASIC-H MANUFACTURER Shaklee Products - Hayward, California 94544 PRODUCT DESCRIPTION Nonionic concentrated water-based cleaning com- pound (not a detergent or soap) SPECIFIC GRAVITY 1.03 FLASH POINT None £H 6.5 REFERENCE (25) BASAL AD 6 REFERENCE (4)(25).(26) BD'-30 MANUFACTURER Rohm & Haas Co. Independence Mall West Philadelphia, Pennsylvania 19105 PRODUCT DESCRIPTION Anionic surfactant BERGEN OIL ON WATER REMOVER MANUFACTURER Bergen Chemical Corp. Back Bay P. 0. Box 371 Boston, Massachusetts 02117 REFERENCE (28) ------- MANUFACTURER REFERENCE (25) MANUFACTURER REFERENCE (25) BIG RED Texas Refinery Corp. Fort Worth, Texas 76101 Suggested for use at Santa Barbara, California CESCO SPILL EXPERIENCE Reportedly used in Lake Charles, Louisiana area REFERENCE (25) CEJER APC Cejer Co. 2545 Treedy Blvd. South Gate, California 90280 Suggested for use at Santa Barbara, California MANUFACTURER CIRRASOL Imperial Chemical Industries Toxicity Tests: Species Shr imp 2000 ppm Ref. (25) ------- CHEVRON NI-0 MANUFACTURER Chevron Chemical Co. 200 Bush Street San Francisco, California 94101 REFERENCE (6)(26) Toxicity Tests: Spec ies Steelhead minnow fingerling 96 hr Ref . 3.2 mg/1 (6) REFERENCE (3)(12) Toxicity Tests: Species Pink shrimp (Pandulus montagui) 48 hr Brown shrimp (Crahgon crangon) 48 hr Shore crabs (Care inus m'aenas) 48 hr Cockles (Cardium edule) 48 hr Zebra fish (Brachydanio rerio) No survival 24 hr CLEANOSOL Ref. (3) 32 ppm 44 ppm 102 ppm 19 ppm 15 ppm (12) MANUFACTURER CLEANER-86 71 Enjay Chemical Co. 60 West 49 Street New York, New York 10020 REFERENCE (12) Toxic ity Tests: Spec ie s Ref. Zebra fish (Brachydanio rerio) None survived 24 hr @ 20 ppm (12) CLOCK 06:39 MANUFACTURER Cleaning Compounds Corp. 999 Commercial Street Palo Alto, California 94302 Suggested for use at Santa Barbara, California REFERENCE (25) ------- MAN UF ACT USER REFERENCE (25) COB En jay Chemical Co. Houston Chemical Plant Stedman Street Houston, Texas 77002 Suggested for use at Santa Barbara, California MANUFACTURER COLD CLEAN Adair Equipment Co. 405 Century Building Houston, Texas 77002 Distributor; Rapid Supply Co. (same address) PRODUCT DESCRIPTION Cold water cleaner and oil emulsifier. Low level phosphate emulsifier which contains trisodium nitrilostriacetate. FLASH POINT BOD Does not flash (C.O.C.) 20-day BOD @ 20° C, 3,200 to 3,600 APPLICATION METHOD Dilute 100 times with water Product was used on the Chevron Platform "C" blow- out as a safety precaution to reduce the flamability of the crude after the fire was extinguished. Toxic ity Tests: Spec ies Fathead minnow (Pimephales promelas) 96 hr TL^ 138 ppm Non-toxic (No Kill) Minnow (Fundulus simulus) Non-toxic (No Kill) Blue crab (Callinectes sapidus) Non-toxic (No Kill) RHTRENCE (25) 96 hr TLO 96 hr TL^ 96 hr TLo 96 hr TL^ 120 ppm 220 ppm 180 ppm 500 ppm ^ 96 hr TLO 450 ppm ------- COMPOUND RICHONAGE YLA MANUFACTURER Richardson Co. 100 New Street. Patersbn, New; Jersey , 07510 REFERENCE (26) CONGO EMULSIFIER 700 MANUFACTURER Continental Chemical Co. 270 Clifton Blvd. Clifton, New Jersey 07015 PRODUCT DESCRIPTION Nonionic. 100% blend of surfactants for use in emulsifying low viscosity oils. SP. GR. 1.02 REFERENCE (26) CONGO EMULSIFIER K . MANUFACTURER Continental Chemical Co. PRODUCT DESCRIPTION Basically nonionic with traces anionic, blend of surfactants. CON-0-1571* MANUFACTURER Continental Chemical Co. EFFECTIVENESS At 1:1 ratio emulsified 11.2% of Navy Special Grade Fuel Oil. REFERENCE (26) *Product no longer available C-REINIGER MANUFACTURER German Reference (1) EFFECTIVENESS At D/0 ratio 1:10 .emulsified 92% HD-SAE 20 motor oil. ------- CRONAX (OIL SPILL) MANUFACTURER Atlas Chemical Industries, Inc. 1270 Avenue of the Americas New York, New York 10020 REFERENCE (28) CW SOLVENT MANUFACTURER Gamlen Chemical Co. COST $1.80/gal. PRODUCT DESCRIPTION Tank and bilge cleaning solvent. EFFECTIVENESS In lab tests at 1:1 ratio emulsified 15.2% of Navy Special Grade Fuel Oil^9\ Toxicity Tests: Spec ies Ref. Pink shrimp (Pandalus montagui) 48 hr TL^ 14.6 mg/1 (3) Cockles (Cardium edule) 48 hr TLm 69.5 mg/1 NOTE; Other company products listed as tank and bilge cleaning solvents are Sea Clean and Sea Clean #2. ------- DART MANUFACTURER Sea-Air Chemical Corp. 3200 Borden Avenue. Long Island City,"New York 11101 COST $1.45/gal. (1-55 gal. drum) AVAILABILITY F.O.B/Long Island City, New York PRODUCT DESCRIPTION Solvent emulsion degreaser for tank cleaning. Polyglycols and solvents. This product is Sea Air Chemical Corp. primary oil spill dispersant. SPECIFIC GRAVITY 0.89 FLASH POINT 170° F (C.O.C.) SOLUBILITY Emulsifies in water SHELF LIFE Unlimited Toxicity Tests: Species Ref. Mummichog (Fundulus heteroclitus) 2H hr Tl^ 44 mg/1 (13) 96 hr Tim 18 mg/1 DEC PLUS MANUFACTURER Cultured Chemical Division 1139 West Struck Avenue Orange, California 92667 Suggested for use at Santa Barbara, California REFERENCE (25) DECK GLO MANUFACTURER Sea Air Chemical Corp. PRODUCT DESCRIPTION Nonionic, 65% water. A tank wash. EFFECTIVENESS In lab test @ D/0 ratio 1:1 emulsified 39.2% of Navy Special Grade Fuel Oil. SPECIFIC GRAVITY 1.017 @ 80° F POUR POINT 30° F REFERENCE (16) ------- DEGREASER 80 G MANUFACTURER The Chemlan Co. 2k Smith Street Biddleford, Maine 04005 PRODUCT DESCRIPTION Solvent/emu Isifier. No. 2 fuel oil as solvent, REFERENCE (25) DEGRECO MANUFACTURER Hampton Roads Chemical Corp. P. 0. Box 1848 Newport News, Virginia 23607 PRODUCT DESCRIPTION Contains emulsifiers in No. 2 fuel oil solvent. REFERENCE (25) DERMOL REFERENCE (3) Toxic ity Tests: Spec ies Pink shrimp (Pandalus montagui) Brown shrimp (Crangon crangon) Shore crabs (Carcinus maenas) Cockles (Cardium edule) 48 hr Tlfn 148 ppm 48 hr Tim 156 ppm 48 hr TI^ 435 ppm 48 hr TLnr 148 ppm Ref. (3) D. G. 04 MANUFACTURER REFERENCE (26)(28) Banner Chemical Products Corp. 46 Great Jones New York, New York 10001 ------- MANUFACTURER REFERENCE (26) DI-CHEM 322 DI-CHEM 325 DI-CHEM 400 Diversified Chemicals Corp. 8100 Electric Avenue Stanton, California 90680 MANUFACTURER REFERENCE (25) DISPERITE 110 O'Brien Industries, Inc. 1040 Bushwick Avenue Brooklyn, New York 11201 MANUFACTURER REFERENCE (28) DISPERSAL Sea Air Chemical Co. DISOLVOL MANUFACTURER Sea Air Chemical Co. PRODUCT DESCRIPTION Non-solvent emulsifier SPECIFIC GRAVITY 1.068 @ 80° F REFERENCE (25) ------- DISSOLVO MANUFACTURER Sea Air Chemical Co. PRODUCT DESCRIPTION Nonionic - 72% water SPECIFIC GRAVITY 1.068 @ 80° F EFFECTIVENESS REFERENCE (16) In lab test @ D/0 ratio 1:1 emulsified 19% of Navy Special. MANUFACTURER EFFECTIVENESS REFERENCE (1) DREW SC 96* Drew Chemical Corp. At D/0 ratio 1:10 emulsified 66% HD-SAE 20 motor oil. *Product no longer available DREW TANK CLEANER NO. MANUFACTURER REFERENCE Drew Chemical Corp. DUNHAM D-166 MANUFACTURER Dunham Chemical Co. 20 Versey Street New York, New York 10001 REFERENCE (25) Toxicity Tests: Spec ies Mummichog (Fundulus heteroc litus) 24 hr TLj, 16 mg/1, 96 hr TLm 16 rag/l'" Ref. (13) ------- ELIMAX MANUFACTURER German Reference (1) EFFECTIVENESS At D/0 ratio of 1:10 emulsified 80% of HD-SAE. 20 motor oil. EMSOL MANUFACTURER Du Bois Chemical Division PRODUCT DESCRIPTION Nonionic mineral oil sulfonate SPECIFIC GRAVITY 0.84 FLASH POINT ' 135° F (C.O.C.) REFERENCE (16) ESSO F-6155 MANUFACTURER Esso Research & Engineering Linden', New" Jersey 07036 Toxic ity Tests: Species Ref. Pink shrimp (Pandalus montagui) 48 hr TI^ 8.6 ppm (3) Brown shrimp (Crangon cjangon) 48 hr TL 9.6 ppm " Shore crabs (Carcinus maenas) 48 hr TI^, 17.5 ppm " Cockles (Cardium edule) . 48 hr TL 63 ppm " EMULSIFIER K MANUFACTURER Continental Chemical Co. PRODUCT DESCRIPTION Refer to Conco Emulsifier K E-147 (SHANNON) MANUFACTURER Unknown Suggested for use at Santa Barbara, California REFERENCE (25) ------- E-314 MANUFACTURER Du Bois Chemical Division PRODUCT DESCRIPTION Rust preventer, oil-based emulsifier SPECIFIC GRAVITY 0.91 FLASH POINT 310° F REFERENCE (6) Toxicity Tests: Species Re£. Steelhead minnow fingerling 96 hr TLj, 22.5 mg/1 (6) FASOLV MANUFACTURER National Laboratories 225 Summit Avenue Montvale, New Jersey 07645 Suggested for use at Santa Barbara, California REFERENCE (25) FINA SOL MANUFACTURER Petrofina (Great Britain, Ltd.) 50 Rockefeller Plaza New York, New York 10001 PRODUCT DESCRIPTION Nonionic ------- MANUFACTURER FINA TAR SOLVENT Petrofina (Great Britain, Ltd.) REFERENCE (4)(25)(26) MANUFACTURER SPILL EXPERIENCE REFERENCE (25)(30) FINA TAR SOLVENT E.S. Petrofina (Great Britain, Ltd.) Used off,;Bizerta, Italy after tanker spill MANUFACTURER FINA-UNISOL Petrofina (Great Britain, Ltd.) PRODUCT DESCRIPTION Nonionic SPILL EXPERIENCE Used during Torrey Canyon incident REFERENCE (25)(26)(30) F. 0. 399 MANUFACTURER Fine Organics, Inc. 205 Main Street Lodi, New Jersey 07644 PRODUCT DESCRIPTION Concentrated dispersant. A combination of surface active agents, solvents, emulsifiers, couplers and inhibitors. APPLICATION METHOD REFERENCE (25) Spray, holding end of nozzle close to the surface of the water, and at a tangent to get a good chopping action. MANUFACTURER REFERENCE (25)(26) GREESKILLA 3 Atlas Preservative Co., Ltd. ------- MANUFACTURER REFERENCE (26) GULF AGENT 822 Gulf Research & Development Co. P. 0. Drawer 2038 Pittsburgh, Pennsylvania 15230 MANUFACTURER REFERENCE (11) GULFSIL DE-GREASER Gulf Oil (Great Britain, Ltd.) 6 Grosvenor Place London, S.W.I., England MANUFACTURER REFERENCE (25) HAMCO Hampton Road Chemical Corp. MANUFACTURER REFERENCE (1) HEPACOLITH German Reference HOUGHTOSAFE 112 MANUFACTURER REFERENCE (4)(26) Edgar Vaughan and Co., Ltd. Legge Street Birmingham 4, England MANUFACTURER REFERENCE (11) HOUGHTOSOLV Edgar Vaughan and Co., Ltd. ------- HOUGHTON-DETERGENT MANUFACTURER Edgar Vaughan and Co., Ltd. REFERENCE (30) HYDRO-GAMOSOL MANUFACTURER Gamlen Chemical Co. REFERENCE (12) Toxicity Tests: Species Re£. Zebra fish (Brachydanio rerio) no survival 24 hrs @ 80 ppm (12) H-4000 MANUFACTURER Graphco, Inc. Alamo, California 94507 PRODUCT DESCRIPTION Contains emulsifiers, detergents, wetting agents, naptha solvent, chlorinated hydrocarbons. FLASH POINT 175° F (C.O.C. ) FIRE POINT 202° F (C.O.C.). REFERENCE (25) 1CI SURFACTANT MANUFACTURER I.C.I. America, Inc. REFERENCE (26) IMC-SWS, MANUFACTURER I.M.C. Drilling Mud, Inc. P. 0. Box 22605 Houston, Texas 77027 Suggested for use at Santa Barbara, California REFERENCE (25)(26) ------- IGEPAL RC 520 MANUFACTURER G.A.F. Corporation PRODUCT DESCRIPTION Nonionic REFERENCE (5) JAY PRODUCT DESCRIPTION Anionic REFERENCE (25) KLEARFAC AA040 MANUFACTURER Wyandotte Chemicals Corp. Wyandotte, Michigan 48192 PRODUCT DESCRIPTION Anionic - mono substituted ortho^ phosphate ester surfactant active agent, % by weight (rain.) 60%. COST 30 - 40cYlb. depending on quantity and grade^5) SPECIFIC GRAVITY 1.112 @ 25° C/25" C VISCOSITY 240 cps @ 25° C (Brookfield) SOLUBILITY Disperses in water POUR POINT " 55° F USE LIMITATIONS Dispersant to oil ratio 1:6 to 1:100 for crude ------- KLEARFAC AA270 MANUFACTURER Wyandotte Chemicals Corporation PRODUCT DESCRIPTION Anionic - mono, substituted ortho phosphate ester surfactant active agent, % by weight (min.) 90%. SPECIFIC GRAVITY 1.165 @ 25° G/25° C VISCOSITY 5900 cps @ 25° C (Brookfield) POUR POINT 25° F KLEARFAC AAU20 MANUFACTURER Wyandotte Chemicals Corporation PRODUCT DESCRIPTION Anionic - mono substituted ortho phosphate ester surfactant agent, % by weight (min.) 90%. SPECIFIC GRAVITY 1.118 @ 25° C/25° C VISCOSITY 2950 cps @ 25° C (Brookf ield) POUR POINT 20° F KLEARFAC AB 270 MANUFACTURER Wyandotte Chemicals Corporation PRODUCT DESCRIPTION Anionic - mono substituted ortho phosphate ester surfactant active agent, % by weight (min.) 95%. SPECIFIC GRAVITY 1.088 @ 25° C/25° C VISCOSITY 800 cps @25°C (Brookfield) POUR POINT 5° F KELITE A-108-1 MANUFACTURER Kelite Chemical Corp. 1250 North Main Street Los Angeles, California 90052 Suggested' for use at Santa Barbara, California REFERENCE (25) ------- KILL-SPILL-D-166 MANUFACTURER Dunham Chemical Co. PRODUCT DESCRIPTION Refer to Dunham D-166 KOR-14 MANUFACTURER Amalgamated Chemicals Corp. P. 0. Drawer 153 Orlando, Florida 32802 REFERENCE (25) K-RITE 300 MANUFACTURER Winnie Engineering Corp. Winnie, Texas 77665 PRODUCT DESCRIPTION A highly concentrated cold water emulsifier which will dissolve asphalt. Suggested for use at Santa Barbara, California. REFERENCE (25) KURI-CLEAN "SD' Toxicity Tests: Spec ies Ref. Zebra fish (Brachydanio rerio) None of 5 survived 24 hr @ 15 ppm (12) ------- LIX 336 MANUFACTURER COST AVAILABILITY The Lix Corporation 300 West 80 Street Kansas City, Missouri $0.80/gal (1-55 gal drum) F.O.B. Kansas City, Missouri PRODUCT DESCRIPTION A water-based cleaning compound. Contains tetra potassium pyro-phosphate, water, solvents, coupling and wetting agents. SPECIFIC GRAVITY FLASH POINT SHELF LIFE OTHER 1.02 @ 70° F Does not burn Unlimited Store @ 32° F to 120° F MANUFACTURER'S USE RECOMMENDATIONS: Application Method No experience Dosage Not known for oil spills Use Limitations Recommended for cleaning shore surfaces coated with Bunker C or distillate fuels. Applied diluted 4 times with water. REFERENCE LIQUID CONCENTRATE SWABY ZIF Best line Products, Inc. 1095 North Fifth Street San Jose, California 95112 Suggested for use at Santa Barbara, California MANUFACTURER REFERENCE (25) ------- LISSAPOL N. X. MANUFACTURER I.C.I. America, Inc. PRODUCT DESCRIPTION Nonionic, ethoxylated alkylphenol with 90% kerosene-naptha. Also referred to as anhydrous nonylphenol ethylenoide condensate. REFERENCE Time, 90, P. 68, July 1967. REFERENCE (25) MABEC-PP5 and MABEC-21T MANUFACTURER REFERENCE (25) MAGNA Magna Corp. 1808 S. Bloomfield Avenue Santa Fe Springs, California 90670 MANUFACTURER MAGNUS MARINE DISPERSER Magnus Chemical Co. PRODUCT DESCRIPTION Nonionic EFFECTIVENESS SPECIFIC GRAVITY POUR POINT FLASH POINT REFERENCE (16) In lab test @ D/0 ratio 1:1 emulsified 63.3% Navy Special Grade fuel oil. 0.905 @ 80° F 6° F 168° F (P.M.) ------- MARINE CLEANER 8551 MANUFACTURER En jay .Chemical Co. 60 West 49 Street New York, New York 10020 PRODUCT DESCRIPTION Water-based 'concentrate. SPECIFIC GRAVITY 1.05 @ 60° F FLASH POINT > 175*F (T.O.C.) VISCOSITY 45 SSU @ 100° F 10 CS @ 32° F Spill Experience: • Inc ident "Esso Guildford", Casco Bay, Maine, August 9, 1969 Environmental Effects: Considerable quantities of seaweed were found dead or dying. . Hard shell clams, mussels and barnacles were also found dead or dying. A kerosene odor'was apparent in tidal pools and sand. Sand removed from a depth of 12" in a test pit had a strong kerosene odor. Tidal pools in and around the rocks on the shoreface were sterile and in some cases contained partially dispersed floating oil. Most of these had a detectable- kerosene odor seven days after dispersant application. . MARINE CLEANER 8555 MANUFACTURER En jay Chemical Co. PRODUCT DESCRIPTION 'Blend of emulsifiers in a high-flash solvent SPECIFIC GRAVITY 0.93 @ 6'0° F- ' FLASH POINT > 175* F. (T.O.C.) VISCOSITY 33.1 SSU @ 100° F 6.2 CS @ 32° F 14.3 CS @ 0° F For spill experience refer to Marine Cleaner 8551 REFERENCE (25) ------- MARITEC OIL SPILL REMOVER MANUFACTURER Maritec Corp. PRODUCT DESCRIPTION In lab test at D/D ratio of 1:1 emulsified 33.6% of Navy Special Grade fuel oil. Non.ionic. SPECIFIC GRAVITY POUR POINT FLASH POINT REFERENCE (16) 0.955 @ 80* F - 44° F 190° F (C.O.C.) METCLENE SPECIAL METCLENE HEAVY DUTY DEGREASER METSPERE HEAVY DUTY CLEANER MANUFACTURER Metropolitan Petroleum Petrochemicals, Inc. Jersey City, New-Jersey 07303 REFERENCE (25)(26) MIGHTY MATE Sea Air Chemical Co. MANUFACTURER Toxic ity Tests: Species Mummichog (Fundulus heteroc litus) 24 hr TI^ 320 mg/1 96 hr TLj, 300 mg/1 Ref. (13) ------- MANUFACTURER REFERENCE (26) MILCHEN MIL-EMULSIFIER MILCHEN PPS Milchen, Inc. MANUFACTURER MURCO-OSE #2 Murray Chemical Co., Inc. The Whiteclean Corp. 235 East 31st Street New York, New York 10001 PRODUCT DESCRIPTION Liquid emulsifier REFERENCE (31) MURATTI PRODUCT Toxic ity Tests: Spec ies Moharra (Eucinostomus argenteus) 6 hr TLjQQ 50 ppm 18 hr TL 43 27 ppm 24 hr TL 85 27 ppm 24 hr TL 25 10 ppm Tested in Puerto Rico at time of "Ocean Eagle" incident. Ref . (20) ------- NAVEE 42 MANUFACTURER Amerace-Esna Corp. PRODUCT DESCRIPTION A blend of solvents, soap, water and alkaline salts. The principal solvent is a high KB " aromatic petroleum hydrocarbon; the soap is of the rosin tall oil type. COSTS $1.80 - $2.55/gal SPILL EXPERIENCE Anne Mildred Brjzfvig (Feb. 1966) in North Sea Toxicity Tests: Spec ies Ref. Mummichog (Fundulus heteroclitus) 24 hr TI^ 175 mg/1 (13) , 96 hr Tlfn 175 mg/1 NAVITONE MANUFACTURER Amerace-Esna Corp. PRODUCT DESCRIPTION Contains emulsifiers, detergents and solvents. REFERENCE (25) NEOS AB Toxic ity Tests: Species . Ref. Zebra fish (Brachydanio rerio) 2 of 5 survived 24 hr @ 20 ppm (12) ------- NORSEMEN 67 MANUFACTURER ' Norsemen Chemic'al's 68, Store -Kongerisgade D.K. 1264, Copenhagen Denmark PRODUCT DESCRIPTION A heavy duty oil degreaser. Nonionic'in aromatic solvent. SPECIFIC GRAVITY FLASH POINT VISCOSITY REFERENCE (25) 0.89 63° C (PMCC) 1.60 cs @ 100° F MANUFACTURER NORSEMEN 69 Norsemen Chemicals PRODUCT DESCRIPTION Sea cleaner. Nonionic solvent emulsifier SPECIFIC GRAVITY 0.84 3.43 cs @ 100° F D/0 ratio 1:5.5 FLASH POINT DOSAGE REFERENCE (25) NYSTOL OIL SPILL EMULSIFIER #79 MANUFACTURER Nystol Chemicals Conforms MIL-S-22864 (Amend. 2) DOSAGE 1 gal/bbl-oil REFERENCE (31) ------- OIL & GREASE REMOVER MANUFACTURER EFFECTIVENESS REFERENCE (l) EFFECTIVENESS SPECIFIC GRAVITY POUR POINT FLASH POINT REFERENCE (16) German Reference In lab test @ D/0 ratio 1:10 emulsified 82% of HD-SAE 20 motor oil. OIL & GREASE REMOVER MANUFACTURER E. F. Drew & Co. (now Drew Chemical Corp.) In lab test @ D/0 ratio 1:1 emulsified 35.8% of Navy Special. 0.901 @ 80° F -26° F 164° F (P.M.) MANUFACTURER OIL AND SPILL ERADICATOR New Process Chemical Co. 350 Fifth Avenue New York, New York 10001 PRODUCT DESCRIPTION Anionic . EFFECTIVENESS. SPECIFIC GRAVITY FLASH POINT POUR POINT REFERENCE (16) In lab test @ D/0 ratio 1:1 emulsified 56% Navy Special. 0.891 @ 80° F 140° F (C.O.C.. ) -12° F ------- MANUFACTURER EFFECTIVENESS OIL EX German Reference (1) At D/0 ratio of 1:10 emulsified 52% of HD-SAE 20 motor oil. MANUFACTURER REFERENCE (26) OIL GO Casco Chemical Co. R-88 High Street Danvers, Massachusetts 01923 MANUFACTURER REFERENCE (25) OIL MEGA Clarkson Laboratories OIL SLICK EMULSIFIER #5189 EFFECTIVENESS In lab test @ D/0 ratio 1:1 emulsified 19.4% Navy Special grade fuel oil. REFERENCE (9) MANUFACTURER REFERENCE (26) OIL SPILL Atlas Chemical Co. ------- MANUFACTURER EFFECTIVENESS REFERENCE (9) OIL SPILL DISPERSER May be Magnus Product In lab test @ D/0 ratio 1:1 emulsified 8.2% of Navy Special grade fuel oil. OIL SPILL REMOVER #1 MANUFACTURER May be Gamlen Product EFFECTIVENESS In lab test @ D/0 ratio 1:1 emulsified 41.1% of Navy Special grade fuel oil. REFERENCE (9) OIL SPILL REMOVER #2 MANUFACTURER May be Gamlen Product EFFECTIVENESS In lab test @ D/0 ratio 1:1 emulsified 16.6% of Navy Special grade fuel oil. REFERENCE (9) OSR-7348 Grain Industrial Products Co. Non-flammable. MANUFACTURER FLASH POINT Toxic ity Tests: Species Mummichog (Fundulus heteroclitus) 24 hr TL^ 100 mg/1 . 96 hr Tic, 57 mg/1 Ref. (13) ------- PENETONE X 138 MANUFACTURER Toxici'ty Tests: Spec ie s Amerace-Esna Corp. Mummichog (Fundulus heteroclitus) 24 hr TI^, 26 mg/1 96 hr TLm 24.5 mg/1 Ref . - (13) MANUFACTURER REFERENCE (26) PENTRON-D *PENTRON TC-30 Technical Division Apollo Chemical Co. 250 Delaware Avenue Clifton, New Jersey 07014 *A marine tank cleaner MANUFACTURER REFERENCE (16) PERMAG #41 Magnuson Products Corp. 50 Court Street Brooklyn, New York 11201 In lab test @ D/0 ratio 1:1 - fair to poor results with Navy Special grade fuel oil. MANUFACTURER PERO-KLEAN No. 801 The Perolin Co., Inc. Empire State Building New York, New York 10001 PRODUCT DESCRIPTION Marine cleaner. Heavy duty alkaline-solvent type product. FLASH POINT 200° F (C.O.C.) REFERENCE (16) ------- OXANE MANUFACTURER REFERENCE (4)(26) Foreign Reference OXANEEZ MANUFACTURER REFERENCE (5)(26) Nopco Chemical Co. 60 Park Place Newark, New Jersey 07102 PARDAG HEAVY DUTY REFERENCE (25)(26) *PC-65 SUPERSLICK PC-5 PC-6 PC-17 PC-50 MANUFACTURER White Chemicals Division White Manufacturing Co. 1140 Lockwood Drive Houston, Texas 77020 REFERENCE (26) *PC-65 Superslick. Nonsolvent. $2.75/gal. Diluted 1 to 10 times with water. Reference (25)(26). MANUFACTURER EFFECTIVENESS PENETONE 867 (16) Amerace-Esna Corp. Contains 68% water. In lab test @ D/0 ratio 1:1 emulsified 11.5% Navy Special Grade fuel oil. ------- MANUFACTURER EFFECTIVENESS REFERENCE (16) PERO-KLEAN No. 805 The Perolin Co., Inc. In lab test @ D/0 ratio 1:1, emulsified 14.3% of Navy Special grade fuel oil. NOTE; Other Perolin Products: No. 802, Powder surfactant No. 842, Liquid Alkaline Cleaner PERO-Klean No. 818 MANUFACTURER The Perolin Co., Inc. PRODUCT DESCRIPTION Nonionic - aromatic solvent emulsifier COST $3.10 - $3.50/gal. AVAILABILITY Worldwide FLASH POINT 200° F VISCOSITY ca 180° F p_H 7 APPLICATION METHOD Spray undiluted HUMAN HAZARD EFFECTIVENESS Toxic ity Tests: Spec ies Avoid'eye or skin contact One of the most effective of 5 products .tested at dispersant to oil ratio 1:5 to 1:10 — most effective on fuel oils, Saskatchewan and Silur- ian crudes and least effective on Alberta, Leduc and Cambrion Crudes^-^) 4 At 1:10 D/0 ratio Pero-Klean No. 818 emulsified 58% of HD-SAE 20 motor oil(D. Ref. Fathead minnow (Pimephales promelas) (Most toxic of 5 dispersants tested) 96 hr Tl^. 53 ppm (17) Imparts very intense odor to water. Threshold odor number at 1 ppm is > 200. ?' 11IRENCE (17) ------- MANUFACTURER PETRO-BAN Napasco Chemical Co. P. 0. Box 10532 New Orleans, Louisiana 70113 PRODUCT DESCRIPTION Oil spill remover. Solvent detergent emulsi- fier. Forms milky emulsion in water. SPECIFIC GRAVITY FLASH POINT VISCOSITY FIRE POINT REFERENCE (25) 0.92 @ 60° F 155° F (C.O.C.) 43 SSU @ 100° F 160° F (C.O.C.) PILOT OIL SPILL ERADICATOR MANUFACTURER Pilot Chemical Co. P. 0. Box 12292 Norfolk, Virginia 23502 In lab test @ D/0 ratio 1:1 emulsified 78.9% of Navy Special grade fuel o REFERENCE (9)(26) MANUFACTURER EFFECTIVENESS REFERENCE (16) P.O. 576 Clarkson Laboratories In lab test @ D/0 ratio 1:1 emulsified 16.7% of Navy Special grade fuel oil. MANUFACTURER REFERENGl- (25 POLY-ZYME Zurn Industries, Inc. 1801 Pittsburg Avenue Erie, Pennsylvania 16512 ------- PRODUCT 20215 MANUFACTURER Unknown Toxic ity Tests: Spec ies Ref. Moharra (Euc inostomus argenteus) 6-12 hr TL^g 20 ppm (20) 18-24 hr TL57 20 ppm Remarks; Tested in Puerto Rico at time of "Ocean Eagle" incident RETZLOFF 1-4016-P MANUFACTURER Retzloff Chemical Co. Houston, Texas 77002 PRODUCT DESCRIPTION Contains diesel fuel solvent FLASH POINT 150° F (min.) REFERENCE (25)(26) S-l MANUFACTURER Coastal Services, Inc. 343 Washington Square Braintree, Massachusetts 02184 PRODUCT DESCRIPTION Same as Colloid 88. Also called Coastal Services 88. REFERENCE (25) S-5 MANUFACTURER Coastal Services, Inc. PRODUCT DESCRIPTION A solvent based Colloid product. REFERENCE (25) ------- SEA CLEAN 70 MANUFACTURER REFERENCE (12) Toxic ity Tests: Species The Perolin Co., Inc. Ref.. Zebra fish (Brachydan-io rerio) No survival 24 hrs @ 20 ppm (12) SEA GREEN 50 A SEA GREEN 70 MANUFACTURER Sea Light Mfg. Co., Ltd. 6th Floor, Kyoda. Bldg. No. 1 Chrome Hancho Nihon Basli Chou Ku Tokyo, Japan REFERENCE (10)(26) SEA SWEEP MANUFACTURER EFFECTIVENESS Eureka Chemical Co. P. 0. Box 1608 Olympia, Washington 98501 On a scale of 1 (high) to 4 (low) was given a rating of 1. Was one of most effective of 11 products tested^6). Toxic ity Tests: Spec ies Pacific oyster larvae (Crassotrea gigas) Toxic Non-toxic 1.5 ppm (6) 0.8 ppm (") ------- MANUFACTURER REFERENCE (26) SANTOMERSE ME-B SLURRY Monsanto Inorganic Chemicals Division 800 North Lindbergh Boulevard St. Louis, Missouri 63166 MANUFACTURER FLASH POINT REFERENCE (16) SELF-RINSE New Process Chemical Co. In lab test @ D/0 ratio 1:1 emulsified 7, Navy Special grade fuel oil. 198° F (P.M.) of SEPT EX MANUFACTURER The Chemlan Co. PRODUCT DESCRIPTION Contains emulsifiers, penetrants and deodorizers Primarily for opening clogged septic tank and cesspool lines. REFERENCE (25)(26) MANUFACTURER REFERENCE (25) Amerace-Esna Corp. SHIP CLEAN MANUFACTURER German Reference (1) SILLARIT At D/0 ratio of 1:10 emulsified 52% of HD-SAE motor oil. ------- MANUFACTURER REFERENCE (26) SKANEX QUICK SKANEX S EMULSIFIER Scandinavian Oil Service MANUFACTURER REFERENCE (26) SLICKAWAY Mankana Chemical Co. 2324 Boston Street Baltimore, Maryland .21224 SLIPCLEAN MANUFACTURER Slip Trading Go. 34 Great St. Helen's Street London, E.G. 3, England . PRODUCT DESCRIPTION Referred to as a rigwash detergent REFERENCE (4) (11) (26) ------- (Dasic) SLICKGONE I MANUFACTURER Dasic Chemicals Ltd. Winchester Road Romsey, Hampshire, England PRODUCT DESCRIPTION Nonionic detergent REFERENCE (4) Spill Experience: Inc ident Torrey Canyon, March 1967. Effectiveness not determined. Toxic ity Tests: Spec ies Pink shrimp (Pandalus montagui) 48 hr TL Brown shrimp (Crangon crangon) Shore crab (Care inus maenas) Cockles (Cardium edule) 5.2 ppm 48 hr TL^" 6.6 ppm 48 hr TLffl 35 ppm 48 hr TLn, 32.4 ppm Ref. (3) SLICKGONE #2 MANUFACTURER Dasic Chemicals Ltd. PRODUCT DESCRIPTION Nonionic detergent (26) COST DOSAGE Toxic ity Tests: Spec ies solvent based f i£ i $2.30/gal. Dispersant to oil ratio 1:10 by volume Pink shrimp (Pandalus montagui) 48 hr TLj, Brown shrimp (Crangon crangon) 48 hr TLj, Shore crabs (Care inus maenas) Cockles (Cardium edule) Zebra fish (Brachydanio rerio) No survival 48 hr 48 hr 24 hr 4.5 3.5 21.3 30.5 ppm ppm ppm ppm Ref. (3) 25 ppm ------- MANUFACTURER PRODUCT DESCRIPTION REFERENCE SNOWDRIFT Monsanto Inorganic Chemical Div. Referred to as .a beach cleaner MANUFACTURER REFERENCE (26) B. P. Ltd. SP 162 MANUFACTURER W. and F. Walker Ltd. Kirby, Liverpool England STREP 33 MANUFACTURER German Reference (1) STRUKTOL At D/6 ratio of 1:10 emulsified 86% of HD-SAE 20 Motor Oil. SURFACTANT 8651 Enjay Chemical Company MANUFACTURER Toxicity Tests: Spec ies Zebra fish (Brachydanio rerio) None 'Survived 24 hrs.@ 10 pprrr Ref . (12) ------- SURFEMUL #5 MANUFACTURER 3 C Chemical Corp. REFERENCE (18) (26) Toxic ity Tests: Spec ies Fundulus parvepinnis 24 hr TI^, 350 ppm 96 hr Tl^j 350 ppm Ref. (18) MANUFACTURER Sea Air Chemical Co. PRODUCT DESCRIPTION Nonionic -70% water. TANK-GLO EFFECTIVENESS SPECIFIC GRAVITY REFERENCE (16) In lab test @ D/0 ratio 1:1 emulsified. 25.2% of Navy Special Grade fuel oil. 1.075 @ 80° F MANUFACTURER TCC-569 (Grain) Grain Industrial Products Corp. TEEPOL PRODUCT DESCRIPTION Referred to as an ionic detergent REFERENCE (4)(30) 1 ------- TERGITOL 15-S-5 MANUFACTURER Union Carbide Chemical Corp. PRODUCT DESCRIPTION Nonionic Toxicity Tests: Species Ref. Mummichog (Fundulus heteroclitus) 24 hr TI^, 3.8 mg/1 (13) 96 hr Tiro 3.8 mg/1 TERGITOL 15-S-9 MANUFACTURER Union Carbide Chemical Corp. PRODUCT DESCRIPTION Nonionic Toxic ity Tests: Species Ref. Mummichog (Fundulus heteroclitus) 24 hr TI^ 9.0 mg/1 (13) 96 hr TLm 7.8 mg/1 TIP TOP CLEANER MANUFACTURER Dutch Pride Products San Jose, California 95125 Suggested for use at Santa Barbara, California REFERENCE (25) TRACER-TECK PRODUCT DESCRIPTION Nonionic REFERENCE (25) ------- TRET-0-LITE E3453 MANUFACTURER REFERENCE (26) Petrolite Corp. MANUFACTURER TRICON / New Process Chemical Co. PRODUCT DESCRIPTION Oil and spill eradicator (no longer available). Anionic. 10% polyethylene glycol ether; 5% fatty acids; 2% alcohol; 63% petroleum solvents; 20% petroleum sulfonate. SPECIFIC GRAVITY FLASH POINT- OTHER ' EFFECTIVENESS Toxicity Tests: Species Striped bass 0.891 @ 80°F 140°F (C.O.C.) Pour Point - 12°F At 1:1 ratio emulsified 66.6% of Navy Special .Grade fuel oil(10). Toxic at low concentrations Ref. (7) REFERENCE (25) TURCO ------- (TWELVE) 12 N DEGREASER MANUFACTURER APPLICATION SPECIFIC GRAVITY FLASH POINT pH REFERENCE (25) Timmons and Charles 110 Academy Street Jersey City, New Jersey 07303 Spray @ D/0 ratio 1:1 0.925 190°F 6.6-6.8 MANUFACTURER UNICO CONCENTRATE Universal Supply Co. PRODUCT DESCRIPTION Concentrate. Nonionic, traces cationic. REFERENCE (25)(26)(29) Toxicity Tests: Species Fundulus parvipinnis Ref . 24 hr T^ 220 ppm (18) 96 hr TLm 220 ppm MANUFACTURER UNISOL-FE May be Universal Supply Co. REFERENCE (12) Toxicity Tests: Species Ref. Zebra fish (Brachydanio rerio) No survival 24 hr @ 20 ppm (12) ------- MANUFACTURER EFFECTIVENESS VECOM B-24 German Referenced) At D/0 ratio 1:10 emulsivied 50% of HD-SAE motor oil. MANUFACTURER REFERENCE (26) VISCO C-16-F Nalco Chemical Co. Box 87 Sugar Land, Texas 77478 MANUFACTURER REFERENCE (25) WEN-DON FORMULA 203 Wen-Don Chemical Co. MANUFACTURER REFERENCE (4)(26) WHITTAKERS G.P. DEGREASANT English Reference WYANDOTTE 20 MANUFACTURER Wyandotte Chemical Corp. Discontinued product used during "Ocean Eagle" incident, San Juan, Puerto Rico. REFERENCE (25) ------- SECTION C ------- MANUFACTURER "AND PRODUCT INDEX Manufacturer Adair Equipment Co. 405 Century Building Houston, Texas 77002 Aetna Chemical Corp. Power Division East Paterson, New Jersey.07407 Alex C. Ferguson Co., Inc. Philadelphia, Pennsylvania 19104 Alken-Murray Corporation 111 Fifth Avenue New York, New York 10003 Amalgamated Chemicals Corp. P.O. Drawer 153 Orlando, Florida 32802 Amerace-Esna Corp. Chemical Specialties Division 74 Hudson Avenue Tenafly, New Jersey 07670 Amway Corporation Ada, Michigan 49301 Apollo Chemical Co. Technical Division 250 Delaware Avenue Clifton, New Jersey 07014 Ara Chem, Inc. P.O. Box 5031 San Diego, California 92105 Ashland Chemicals 8 East Long Street 'Columbus, Ohio 43216 Atlas Chemical Industries, Inc. J1270 Avenue of the Americas New York, New York 10020 Atlas Preservative Co., Ltd. Fraser Road Products Section Cold Clean B Actemul B Actemul U.C. B AFCO #5350 B Alken O.S.D. Kor-14 B Slix A Navee 42 B Navitone B Penetone 867 B Penetone XI38 B Ship Clean B Amway Industroclean B Pentron-D B Pentron TC-30 B Gold Crew Dispersant Ridzlik Cronax (Oil Spill) B Oil Spill B Atlas 1901 P Greeskilla 3 » ------- Manufacturer Products Section Banner Chemical Products Corp. 46 Great Jones New York, New York 10001 B&B Chemical Co., Inc. Box 796 Miami, Florida 33166 Bergen Chemical Corp. Back Bay P.O. Box 371 Boston, Massachusetts 02117 The Besco Corporation 200 N. Myrtle Street Metairie, Louisiana 70004 Bestline Products, Inc. 1095 North Fifth Street San Jose, California 95112 BP North America, Inc. 620 Fifth Avenue New York, New York 10020 Carter Chemical Co. 250 Fulton Avenue Hempstead, New York 11550 Casco Chemical Co. R-88 High Street Danvers, Massachusetts 01923 Cejer Co. 2545 Treedy Boulevard South Gate, California 90280 The Chemlan Co. 24 Smith Street Biddleford, Maine 04005 Chevron Chemical Co. 200 Bush Street San Francisco, California 94101 The Clarkson Laboratories 1450 Ferry Avenue Camden, New Jersey 08104 D. G. 04 B B&B 2021-S A B&B 2023 A Bergen Oil on B Water Remover Besco B-51 DT A Besco D-Emulsion No. 100 A Besco Slick - 440 A Liquid Concentrate B Swaby B Zif B BP-1002 A BP-1100 A SP-162 B Aquatreat B Oil Go B Cejer APC B Degreaser 80 G B Septex B Chevron NI-0 B Blitz A Oil Mega B P.O. 576 B ------- Manufacturer Products Section Cleaning Compounds Corp. 999 Commercial Street Palo Alto, California 94302 Coastal Services, Inc. 343 Washington Square Braintree, Massachusetts 02184 Colloid Chemical Co. 31 Perkins Street Brockton, Massachusetts 02402 Continental Chemical Co. 270 Clifton Boulevard Clifton, New Jersey 07015 Grain Inudstrial Products Corp. P.O. Box 34233 Farmers Branch, Texas 75234 also P.O. Box 1062 2411 Swiss Avenue Dallas, Texas 75221 Cultured Chemical Division 1139 West Struck Avenue Orange, California 92667 Dasic Chemicals Ltd. Winchester Road Romsey, Hampshire, England Diversified Chemicals Corp. 8100 Electric Avenue Stanton, California 90680 Drew Chemical Corp. 522 Fifth Avenue New York, New York 10036 Clock 06:39 S-l S-5 Colloid-88 Conco Emulsifier 700 Conco Emulsifier K Con-0-1571 LCP-12 OD-2 OSR-7348 TCC-569 DBG Plus Slickgone #1 Slickgone #2 Di-Chem 320 Di-Chem 322 Di-Chem 325 Di-Chem 400 Ameroid Oil .Spill Emulsifier #1 Ameroid Drewclean 522 Drew SL 96 Drew Tank Cleaner #4 Oil and Grease Remover B B B B B A A B B B B A B B B A B B B B Dunham Chemical Co. 20 Versey Street New York, New York 10001 Dunham D-166 B ------- Manufacturer Products Sect ion Dutch Pride Products San Jose, California 95125 Edgar Vaughan and Co., Ltd. Legge Street Birmingham 4, England Enjay Chemical Co. 60 West 49th Street New York, New York 10020 Esso Research & Engineering Linden, New Jersey 07036 Eureka Chemical Co. P.O. Box '.1-608 Olympia, Washington 98501 Fine Organics, Inc. 205 Main Street Lodi, New Jersey 07644 GAP Corporation 140 West 51st Street New York, New York 10020 Gamlen Chemical Co. 321 Victory Avenue So. San Francisco, California 94080. Graphco, Inc. Alamo, California 94507 Guardian Chemical Corp. 41-45 Crescent Street Long Island City, New,York 11101 Gulf Oil (Great Britain, Ltd.) 6 Grosvenor Place London, S.W.Io, England Gulf Research & Development Co. P.O. Drawer 2038 Pittsburgh, Pennsylvania 15230 Tip Top Cleaner Houghtosafe 112 Houghtosolv Houghton-Detergent Corexit 7664 Corexit 8666 Cleaner 8671 COE Marine Cleaner 8551 Marine Cleaner 8555 Surfactant 8651 Esso F-6155 Sea Sweep P.O. 300-B P.O. 300-H P.O. 399 Igepal Co-430; Igepal Co-530 Igepal Rc-520 Gamlen D Solvent Gamosol Oil Spill Remover CW Solvent Hydro-Gamosol H-4000 Polycomplex A-ll Polycomplex A-ll D Gulfsil De-Greaser Gulf Agent 822 B B B A •A B B B B B B B A A B A A B A B B B A A ------- Manufacturer Products Section Hampton Roads Chemical-Corp. P.O. Box 1848 Newport News, Virginia 23607 Hemisphere Marine Chemicals Co., Inc. 300 Main'Street Orange, New Jersey 07050 Holl-Chem, Inc. 502-A Maritime Building Seattle, Washington 98104 Id America, Inc . 151 South Street Stamford, Connecticut 06904 I.M.C. Drilling Mud, Inc. P.O. Box 22605 Houston, Texas 77027 Johnson-March Corporation 3rd and Berks Street Philadelphia, Pennsylvania 19122 Kelite Chemical Corp. 1250 North Main Street Los Angeles, California 90052 Lawton Specialty Co., Inc. P.O. Box 44 Lawton, Oklahoma 73501 The Lix Corporation 300 West 80th Street Kansas City, Missouri 64114 Magna Corporation 1808 S. Bloomfield Avenue Santa Fe Springs, California 90670 Magnus Chemical Co. 400 South Avenue Garwood, New Jersey 07627 Magnuson Products Corp. 50 Court Street Brooklyn, New York 11201 Degreeo B Hemco No. 2 Holl-Chem #622 Dispersol OS A Cirrasol B ICI Surfactant B Lissapol N.X. B .IMC-SWS B Isomal 265 Kelite A-108-1 B Magic Power Oil Dispersent OD #1 Lix 336 Magna B Magnus Oil Spill Disperser A Automatic Tank Wash B Magnus Marine Disperser B Permag #41 B ------- Manufacturer Products Section Mankana Chemical Co. 2324 Boston Street Baltimore, Maryland 21224 Maritec Corp. Metropolitan Petroleum Petrochemicals, Inc. 24 Caven Point Road Jersey City, New Jersey 07304 Milchen, :Inc. .Box 2211 Houston, Texas 77001 Monsanto Inorganic Chemicals Division 800 North Lindbergh Boulevard St. Louis, Missouri 63166 Montgomery Chemical Company P.O. Box 187 Jenkintown, Pennsylvania 19046 Murray Chemical Co., Inc. The Whiteclean Corp. 235 East 31st Street New York, New York 10001 Nalco Chemical Co. Box 87 Sugar Land, Texas 77478 Napasco Chemical Co. P.O. Box 10532 New Orleans, Louisiana 70113 Norsemen Chemicals 68, Store Kongensgade O.K. 1264, Copenhagen Denmark National Laboratories 225 Summit Avenue Montvale, New Jersey 07645 Slickaway Maritec Oil Spill Remover Met Aquaclene 100 Metclene Special Metclene Heavy Duty . Degreaser Metspere Heavy Duty Cleaner Aquanix Milchen Mil-Emulsifier Milchen PPS Santomerse ME-B Slurry Snowdrift Aquanex MC Murco-Ose #2 Visco C-16-F Petro-Ban Norsemen 67 Norsemen 69 Fasolv A B B B B B B B B B B B B B ------- Manufacturer Products Section National Lead Company Baroid Division P.O. Box 1675 Houston, Texas 77002 National Research and Chemical Company 1250 Cerise Avenue Hawthorne, California 90250 also 30 East 42nd Street New York, New York 10001 Navada Enzymes, Inc. 3049 Riegel, Building C Las Vegas, Nevada 89012 New Process Chemical Co. 350 Fifth Avenue New York, New York 10001 Nopco Chemical Co. 60 Park Place Newark, New Jersey 07102 Nystol Chemicals O'Brien Industries, Inc. 1040 Bushwick Avenue Brooklyn, New York 11201 Pacific Chemical 4501 Shilshole N.W. Seattle, Washington 98107 Pepper Tank Cleaning Co. 2000 McKinley Avenue National City, California 92050 The Perolin Co., Inc. Empire State Building New York, New York 10001 Petrofina (Great Britain, Ltd.) 50 Rockefeller Plaza New York, New York 10001 Surflo RD 282 Baroid Slix-5 Degreaser Tyfosol 80 A B Bacto-Zyme Oil & Spill Eradicator Self Rinse Tricon Oxaneez Nystol Oil Spill Emulsifier #79 Disperite 110 Spill-X Disperse-Oil Pero-Klean No. 801 Pero-Klean No. 805 Pero-Klean No. 818 Sea Clean 70 Fina Sol Fina Tar Solvent Fina Tar Solvent E.S. Fina-Unisol B B B B B B B B B B B B B ------- Manufacturer Products [Section Petrolite Corporation Tretolite -Division 369 Marshall Avenue St. Louis, Missouri 63119 also 2 West 4th Street New York, New York 10017 Pilot Chemical Co. P.O. Box 12292 Norfolk, Virginia 23502 Polycell Products, Ltd. Broadwater Road Welwyn Garden City Hertsfordshire, United Kingdom Retzloff Chemical Co. Houston, Texas 77002 Richardson Company 100 New Street Paterson, New Jersey 07510 Rohm & Haas Company Independence Mall West Philadelphia, Pennsylvania 19105 Scandinavian Oil Service Stora Badhusgatan 20 8-41121 Gothenburg, Sweden Domestic Representative: Surface Separator Systems, Inc. 103 Mellor Avenue Baltimore, Maryland 21228 Sea-Air Chemical Corp. 32-00 Borden Avenue Long Island City, New York 11106 Petrolite W-1439 Petrolite WF-30 Tret-0-Lite Pilot Oil Spill Eradicator Polyclens (Moltoklar) BD-30 Skanex S-102 Skanex Qucik Foilzoil Dact Deck Glo Dispersal Dissolvol Dissolve Mighty Mate Tank Glo :A A B B Retzloff 1-4016-P Compound Richonage YLA B B A B A B B B B B B B ------- Manufacturer Products Section Sea Light: Mfg. Co., Ltd. 6th Floor, Kyoda Bldg. No. 1 1 Chrome Hancho Nihon Basli Chou Ku jTokyo , Japan Shaklee Products Hayward, California Slip Trading Company ,34 Great St. Helen's Street London, E.G. 3, England Sunshine Chemical Corp. ;P.O. Box 2041 ;West Hartford, Connecticut 06117 .also ;P.O. Box 5534 Jacksonville, Florida 32207 'Teoc , Inc . P.O. Box 513 1100 Victory Drive Westwago, Louisiana 70094 'Texas Refinery Corp. 'Fort Worth, Texas 76101 3 C Chemical Corp. Timmons and Charles 110 Academy. Street Jersey City, New Jersey 07303 Turco Chemische Producten N.V. Verl. Blokkenweg 12 Ede, Holland Union Carbide Chemical Corp. 270 Park Avenue New York, New York 10001 Universal Supply Company W. and F. Walker Ltd. Kir by, Liverpool England Sea Green 50 A Sea Green 70 B B Basic-H Slipclean Jansolv-60 Jansolv-60 W Teoc 444 Teoc 777 Big Red Tergitol 15-S-5 Tergitol 15-S-9 Unico Concentrate Strep 33 B B A A A A B Surfemul #5 B (Twelve) 12 N Degreaser B Seamulso E A B B B B Wen-Don Chemical Co. Wen-Don Formula 203 B ------- Manufacturer Products Sect ion White Chemicals Division White Manufacturing Company 1140 Lockwood Drive Houston, Texas 77020 Winnie Engineering Corp. Winnie, Texas 77665 W. Ro Grace & Co. Du Bois Chemical Division Union Avenue & Du Bois East Rutherford, New Jersey 07070 Wyandotte Chemicals Corp. J. Bo Ford Division Wyandotte, Michigan 48192 Xzit Chemical Company 56 Newark Street Hoboken, New Jersey 07030 Zurn Industries, Inc. 1801 Pittsburg Avenue Erie, Pennsylvania 16512 PC-65 Superslick B PC-5 B PC-6 B PC-17 B PC-50 B K-Rite 300 B Actusol B Actusol T-776 B Emsol B E-314 B Casol A Talent A Spill Remover A Klearfac AA040 B Klearfac AA270 B Klearfac AA420 B Klearfac AB270 B Wyandotte 20 B Oil Spill Eradicator X-l-11 A Poly-Zyme ------- SECTION D ------- REFERENCES 1. Hellman, H. and Knopp, H., Further investigation into the suitability of EMULSIFIERS FOR THE ELIMINATION OF OIL FROM SURFACE WATERS, Deutsche Gewasserkunkl Mitteilung, 11, 4, 91 2. Poliakoff, M. Z. (1969) OIL DISPERSING CHEMICALS, EPA, WQO, Edison Water Quality Laboratory, Edison, New Jersey. 3. Portmann, J. E. and Connor, P. M. (1968), THE TOXICITY OF SEVERAL OIL-SPILL REMOVERS TO SOME SPECIES OF FISH AND SHELL- . FISH, Marine Biology, International Journal on Life in Oceans and Coastal Waters, 1_, 4, p. 322-329. 4. Smith, J. E. (Edit.) (1968), TORREY CANYON POLLUTION AND MARINE LIFE, Cambridge University Press, New York City. 5. COMBATING POLLUTION CREATED BY OIL SPILLS, VOLUME 1, METHODS (1970), A. D. Little, Inc. (Report to Dept. of Transportation, U. S. Coast Guard). 6. Tracy, H. B., Lee, R. A., Woelke, C. E., and Sanborn, K. (1969) A REPORT ON THE RELATIVE TOXICITIES AND DISPERSING-EVALUATIONS OF ELEVEN OIL-DISPERSING PRODUCTS, State of Washington, Water Pollution Control Commission and Department of Fisheries. 7. Chadwick, H. K. (1969), TOXICITY OF TRICON OIL SPILL ERADICATOR TO STRIPED BASS, California Fish and Game, 46_, 3, 371 8. REPORT OF EXPERIENCE OF THE GERMAN MARITIME TRAFFIC ADMINI- STRATION on the sea accident of the Norwegian tanker "Anne Mildred Brizfvig" occurred on February 20, 1966 in the North Sea. 9. Culbertson, T. L., and Scott, A. L. (1968), CHEMICAL TREATMENT OF OIL SPILLED ON HARBOR WATERS, Technical Note N-983, Naval Civil Engineering Laboratory, Port Hueneme, California. 10. STUDY OF EQUIPMENT AND METHODS FOR REMOVING OIL FROM HARBOR WATERS (1969), Battelle Memorial Institute, Pacific Northwest Laboratories, Appendix B, II. Chemical Agents (Report for Department of Navy, Naval Civil Engineering Laboratory). 11. Taylor, J. C. (1962), THE RECOVERY AND CONTAINING OF OIL SPILLS, Journal of the Institute of Petroleum, 18, 467, 355. 12. Unpublished results, Humble Oil Company (1969). 13. Unpublished results, FWQA (1969) 14. OIL SPILL TREATING AGENTS - A COMPENDIUM (1970), Battelle Memorial Institute, Pacific Northwest Laboratories (Report -for American Petroleum Institute). ------- 15. Zillich, J. (1969), A BIOLOGICAL EVALUATION OF SIX CHEMICALS USED TO DISPERSE OIL SPILLS, State of Michigan, Dept. of Natural Resources. 16. Rozene, B. B., Zaccaria, L. V. (1961), DEVELOPMENT OF PROPOSED SPECIFICATION FOR OIL SLICK SOLVENT EMULSIFIER, Report No. 951-61, Boston Naval Shipyard, U. S. Navy. 17. Oda, A. (1968), A REPORT ON THE LABORATORY EVALUATION OF FIVE CHEMICAL ADDITIVES USED FOR THE REMOVAL OF OIL SLICKS ON WATER, Ontario Water Resources Commission, Toronto. 18. RESULTS OF A BIOASSAY FOR UNION OIL CO. (1969), Agri Science Laboratories, Inc., Hawthorne, California. 19. Dowden, B. F., (1962), TOXICITY OF COMMERICAL WASTE-OIL EMUL- SIFIERS TO DAPHNIA MAGNA, Jour. WPCF, 3^, 10, 1010. 20. Eger, W. F. (1968), RESUME OF ACTIVITIES REGARDING OCEAN EAGLE, University of Puerto Rico, Department of Marine Sciences, Mayaguez, P. R. 21. Johnson, R. F. (1967), Final report on A BIOLOGICAL ASSAY FOR POSSIBLE EFFECTS OF POLYCOMPLEX A ON MARINE FISH AND SHELLFISH to Guardian Chemical Corporation, William F. Clapp Laboratories, Inc. of Battelle Memorial Institute Report #13757. 22. Unpublished New York State Conservation Department (1968). 23. Canevari, G. P. (1970) Corexit 7664 OIL DISPERSANT STATUS OF TOXICITY EVALUATIONS, Esso Research and Engineering Company, Florham Park, New Jersey. 24. Canevari, G. P. (1970) Corexi 8666 OIL DISPERSANT STATUS OF TOXICITY EVALUATIONS, Esso Research and Engineering Company, Florham Park, New Jersey. 25. Oil Spill Product Files FWQA, Edison, New Jersey. 26. SYSTEMS STUDY' OF OIL SPILL CLEANING PROCEDURES VOLUME 1: ANALYSIS OF OIL SPILLS AND CONTROL MATERIALS (1970), Dillingham Corp., LaJolla, California (Final report to American .Petroleum Institute). 27. Tobin, P. M. (1970), USE OF DISPERSANT, AQUACLENE 100, AT THE GULF OIL COMPANY OIL SPILL IN PHILADELPHIA, PENNSYLVANIA, Un^. . published trip report, FWQA, Edison, New Jersey. 28. .CONTINGENCY .PLANS FOR SPILLS OF OIL AND OTHER HAZARDOUS MATERIALS IN NEW ENGLAND (1969), U.S. Dept. of the Interior, FWPCA, New , England Basins Office, Needham Heights, Massachusetts. ------- 29. Merrell, J. C. (1969), PRELIMINARY DISPERSANT EVALUATIONS, Unpublished Memo, Santa Barbara Sub-Office, FWQA. 30. Carthy, J. P. and Arthur, D. R. (Editors) (1968), THE BIOLOGICAL EFFECTS OF OIL POLLUTION ON LITTORAL COMMUNITIES, Supplement to Volume 2 of Field Studies, Field Studies Council, London. 31. LITERATURE ON OIL SPILL CONTROL, Marine West, Sept. - Oct. (1968), p. 15. 32. Stander, G. H., THE ESSO ESSEN INCIDENT, South African Shipping News and Fishing Industry Review, August 1968, p. Ul. 33. USE OF CHEMICALS, MATERIALS OR TECHNIQUES TO TREAT OIL SPILLS (1970) Publication No. 539U, Commonwealth of Massachusetts, Division of Water Pollution Control, Boston, Massachusetts. 34. Mills, E. R., Jr. (1970), THE ACUTE TOXICITY OF VARIOUS CRUDE OILS AND OIL SPILL REMOVERS ON TWO GENERA OF MARINE SHRIMP, M. S. Thesis, Louisiana State University- 35. Unpublished (1968), Dept. of the Interior, Bureau of Commerical Fisheries, La Jolla, California. ------- |