U.S. Environmental Protection Agency Industrial Environmental Research EPA-600/7-78-015
Office of Research and Development Laboratory
Research Triangle Park. North Carolina 27711 February 1978
SAM/IA: A RAPID SCREENING
METHOD FOR ENVIRONMENTAL
ASSESSMENT OF FOSSIL ENERGY
PROCESS EFFLUENTS
Interagency
Energy-Environment
Research and Development
Program Report
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RESEARCH REPORTING SERIES
Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology. Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:
1. Environmental Health Effects Research
2. Environmental Protection Technology
3. Ecological Research
4. Environmental Monitoring
5. Socioeconomic Environmental Studies
6. Scientific and Technical Assessment Reports (STAR)
7. Interagency Energy-Environment Research and Development
8. "Special" Reports
9. Miscellaneous Reports
This report has been assigned to the INTERAGENCY ENERGY-ENVIRONMENT
RESEARCH AND DEVELOPMENT series. Reports in this series result from the
effort funded under the 17-agency Federal Energy/Environment Research and
Development Program. These studies relate to EPA's mission to protect the public
health and welfare from adverse effects of pollutants associated with energy sys-
tems. The goal of the Program is to assure the rapid development of domestic
energy supplies in an environmentally-compatible manner by providing the nec-
essary environmental data and control technology. Investigations include analy-
ses of the transport of energy-related pollutants and their health and ecological
effects; assessments of, and development of, control technologies for energy
systems; and integrated assessments of a wide range of energy-related environ-
mental issues.
REVIEW NOTICE
This report has been reviewed by the participating Federal Agencies, and approved
for publication. Approval does not signify that the contents necessarily reflect the
views and policies of the Government, nor does mention of trade names or commercial
products constitute endorsement or recommendation for use.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.
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EPA-600/7-78-015
February 1978
SAM/IA: A RAPID SCREENING
METHOD FOR ENVIRONMENTAL
ASSESSMENT OF FOSSIL ENERGY
PROCESS EFFLUENTS
by
L.M. Schalit and KJ. Wolfe
Acurex Corporation/Aerotherm Division
485 Clyde Avenue
Mountain View, California 94042
Contract No. 68-02-2160 (T.D. 4)
Program Element No.EHE624
EPA Project Officer: Joshua S. Bowen
Industrial Environmental Research Laboratory
Office of Energy, Minerals, and Industry
Research Triangle Park, N.C. 27711
Prepared for
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Research and Development
Washington, D.C. 20460
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ABSTRACT
The Environmental Protection Agency's Industrial Environmental Re-
search Laboratory-RTF Energy Assessment and Control Division (IERL-RTP/EACD)
conducts programs to develop control technology and perform environmental
assessments for both energy and industrial processes.
In conducting environmental assessments, it is necessary to do one or
more of the following tasks: (1) rank individual effluent streams by the
expected toxicity of their discharges, (2) establish sampling priorities,
(3) determine problem pollutants, (4) recommend best multimedia control
technology alternatives, and (5) recommend control/disposal technology de-
velopment programs. This report describes the simplest member of a sequence
of Source Analysis Models (SAMs) of increasing complexity and thoroughness
which can be used as a tool to help with these five tasks. This model,
SAM/IA, is useful for rapid screening of each effluent stream from a specific
source. It is based on a comparison of effluent concentrations with the
set of Minimum Acute Toxicity Effluent (MATE) criteria established by the
EPA. This report explains the purposes of SAM/IA and describes the model
embodied in SAM/IA, the format used and the MATE criteria against which pol-
lutants are gauged. Several examples have been included to illustrate
specific facets of the use of the model and of the format.
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TABLE OF CONTENTS
Section Page
1 INTRODUCTION 1
2 SOURCE ANALYSIS MODEL FOR RAPID SCREENING
OF CONTROL OPTIONS 5
2.1 Introduction to SAM 5
2.2 SAM/IA Calculation Procedure 7
2.3 MATEs for Use with the SAM/IA Format 10
2.4 User's Guide to the SAM/IA Format 11
2.4.1 Instructions for the Use of the
Summary Sheet (Form IA01) 11
2.4.2 Instructions for the Use of the
Worksheet (Form IA02) 20
2.4.2.1 Completion of Form IA02 -Level 1 20
2.4.2.2 Completion of Form IA02 -Level 2 23
2.4.3 Further Data to be Entered in Appendix A ... 25
SAM/IA APPLICATION EXAMPLES 27
3.1 Introduction 27
3.2 Example 1 —a Hypothetical Fluidized
Bed Combustor 28
3.3 Example 2 -Utility Boiler 28
3.4 Example 3 -Flat Glass Processing 52
3.5 Example 4 -Byproduct Coke Oven 59
REFERENCES 66
APPENDIX A. A-l
ill
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LIST OF ILLUSTRATIONS
Fi gure Page
1 Environmental assessment/control technology
development diagram 2
2(a) IA01 Summary sheet, side 1 12
2(b) IA01 Summary sheet, side 2 13
3(a) IA02 Worksheet, Level 1 14
3(b) IA02 Worksheet, notes 15
3(c) IA02 Continuation Worksheet, Level 1 16
4(a) IA02 Worksheet, Level 2 17
4(b) IA02 Continuation Worksheet, Level 2 18
5(a) Example 1 29
5(b) Example 1 (Continued) 30
5(c) Example 1 (Continued) 31
5(d) Example 1 (Concluded) 32
6(a) Example 2(a) 33
6(b) Example 2(a) (Continued) 34
6(c) Example 2(a) (Continued) 35
6(d) Example 2(a) (Continued) 36
6(e) Example 2(a) (Concluded) 37
7(a) Example 2(b) . 38
7(b) Example 2(b) (Continued) 39
7(c) Example 2(b) (Continued) 40
7(d) Example 2(b) (Continued) 41
7(e) Example 2(b) (Continued) 42
7(f) Example 2(b) (Concluded) . : 43
iv
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LIST OF ILLUSTRATIONS (Concluded)
Fi gure Page
8(a) Example 2(c) 45
8(b) Example 2(c) (Continued) 46
8(c) Example 2(c) (Continued) 47
8(d) Example 2(c) (Continued) 48
8(e) Example 2(c) (Continued) 49
8(f) Example 2(c) (Continued) 50
8(g) Example 2(c) (Concluded) 51
9(a) Example 3 53
9(b) Example 3 (Continued) 54
9(c) Example 3 (Continued) 55
9(d) Example 3 (Continued) 56
9(e) Example 3 (Continued) 57
9(f) Example 3 (Concluded) 58
10(a) Example 4 60
10(b) Example 4 (Continued) 61
10(c) Example 4 (Continued) 62
10(d) Example 4 (Continued) 63
10(e) Example 4 (Continued) 64
10(f) Example 4 (Concluded) 65
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SECTION 1
INTRODUCTION
The Environmental Protection Agency's Industrial Environmental Re-
search Laboratory-RTP Energy Assessment and Control Division (IERL-RTP/EACD)
conducts programs to develop control technology and perform environmental
assessments for both energy and industrial processes. The primary purpose
of environmental assessment activities is to provide a necessary portion
of the research base which supports standards development by EPA program
offices. Therefore, these assessments:
t Determine environmental loadings, control costs and energy impact
when existing or "best future definable" sets of control or dis-
posal options are applied to specific sources or processes
• Compare these environmental loadings with existing standards or
estimated Multimedia Environmental Goals (MEGs) to establish con-
trol need priorities
In particular, it is important to be able to determine which control options
are the most environmentally effective for each polluting source. It is
also important to establish sampling priorities, identify problem pollutants,
rank effluent streams with respect to degree of hazard in already existing
plants and compare the relative degree of hazard between plants.
If comparisons between environmental assessments are to be of maximum
benefit, the assessments need to employ a standardized methodology, insofar
as the subjects of the assessments will allow. IERL-RTP/EACD has thus
chosen to create a standardized set of Source Analysis Models (SAMs) which
will couple to multimedia environmental goals (MEGs). Figure 1 diagrams
the development of environmental assessment methodology and control tech-
nology. The box labeled Environmental Alternatives Analyses encompasses the
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CONTROL TECHNOLOGY
DEVELOPMENT
• ENGINEERING ANALYSIS
• IMC MD APPLIED PROCESSES
DEVELOPMENT
•SPECIFIC PROCESS DEVELOP-
MENT AID (VALUATION
CURRENT PROCESS TECH-
NOLOBVBACKGROUND
• PROCESS INFORMATION
• SCHEDULES
• STATUS
• PRIORITIES FOR FUR-
THER STUOV
ENVIRONMENTAL DATA ACQUISITION
• EXISTING DATA FOR EACH PROCESS
• IDENTIFY SAMPLING AND ANALYTI-
CAL TECHNIQUES INCLUDING MO-
ASSAYS
• TEST PROGRAM DEVELOPMENT
• COMPREHENSIVE WASTE STREAM
CHARACTERIZATION (LEVELS I. II.
Ill)
• INPUT-OUTPUT MATERIALS CHARAC-
TERIZATION
• CONTROL ASSAYS
ro
CURRENT ENVIRONMENTAL
BACKGROUND
• POTENTIAL POLLUTANTS
AND NWACTS IN ALL
MEDIA
• DOSE/RESPONSE DATA
• FEOJSTATE STDS. CRI-
TERIA
• TRANSPORT MODELS
•SUMMARIZE INDUSTRY-
RELATED OCCUPATIONAL
HEALTH/EFIBEMlaLOGICAL
LITERATURE
ENVIRONMENTAL ENGINEERING
ENVIRONMENTAL SCIENCES
ENVIRONMENTAL SCIENCES
TECHNOLOGY TRANSFER
ENVIRONMENTAL OUECTIVES
DEVELOPMENT
• ESTABLISH PERMISSIBLE
MEDIA CONC. FOR CONTROL
DEVELOPMENT GUIDANCE
• DEFINE DECMON CRITERIA
FOR PRIORITIZING SOURCES.
PROBLEMS
• DEFINE EMISSION GOALS
• PRIORITIZE POLLUTANTS
• NONPflUUTANT MPACT
• MOASSAV CRITERIA
YES
IS
' SETTER '
CONTROL
wNEEDED!,
CONTROL TECHNOLOGY ASSESSMENT
• CONTROL SYSTEM AND DISPOSAL
OPTION INFORMATION AND DE-
SUN PRINCIPLE
• CONTROL PROCESS POLLUTION
AND IMPACTS
• PROCESS ENGINEERING POLLUT-
ANT/COST SENSITIVITY STUDIES
• ACCIDENTAL RELEASE, MALFUNC-
TION. TRANSIENT OPERATION
STUDIES
• FIELD TESTING IN RELATED
APPLICATIONS
• DEFINE BEST CONTROL TECH-
NIQUE FOR EACH GOAL
• POLLUTANT CONTROL SYSTEMS
STUDIES
• CONTROL TECHNOLOGY R 4 D
PLANS AND GOALS
SELECT AND APPLY
ALTERNATIVE SOURCE
ANALYSBMODELB)
ENVIRONMENTAL ALTERNATIVES ANALYSES
SELECT AND APPLY
ASSESSMENT ALTERNATIVES-
ALTERNATIVE SETS OF MULTI-
MEDIA ENVIRONMENTAL GOALS
MEG'S)
• BEST TECHNOLOGY
• EXISTING AMBIENT STBS
• ESTMATEO PERMISSIBLE
CONC.
• NATURAL BACKGROUND
(ELIMINATION OF DISCHARGE)
• SIGNIFICANT DETERIORATION
•MINMUM ACUTE TOXKITY
EFFLUENT
• QUANTIFIED CONTROL MD NEEDS
• QUANTIFIED CONTROL ALTERNATIVES
• QUANTIFIED MEDIA DEGRADATION
ALTERNATIVES
• QUANTIFIED NONPOLLUTANT EFFECTS
AND SITING CRITERIA ALTERNATIVES
• DEFINED RESEARCH DATA BASE FOR
STANDARDS
ENVIRONMENTAL ENGRG
TECHNOLOGY TRANSFER
ENVIRONMENTAL SCIENCES RM
•HEALTH/ECOLOGICAL EFFECTS
RESEARCH
•TRANSPORT/TRANSFORMATION
RESEARCH
MEDIA DEGRADATION AND
HEALTH/ECOLOGICAL
•PACTS ANALYSIS
• AM. MATER. AND LAND
QUALITY
• UK REASED SICKNESS
MD DEATHS
• ECOLOGY-RELATED
EFFECTS
• MATERIAL-RELATED
imcn
• QUANTIFIED EFFECTS
ALTERNATIVES
Figure 1. Environmental assessment/control technology development diagram.
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SAM/MEG system. SAMs, as currently envisioned, address source identifica-
tion and goal comparison questions; MEGs, by definition, address goals.
SAMs do not currently include cost definitions and summations. Battelle-
Columbus and Research Triangle Institute (RTI) are currently engaged in
creating MEGs. Those RTI-created MEGs which are designed for rapid screen-
ing are the "Minimum Acute Toxicity Effluent" MEGs, abbreviated as "MATEs."
Various member of the set of SAMs will provide rapid screening, in-
termediate, or detailed approaches to relate effluent stream pollutant emis-
sion levels to the MEGs. Later members of the sequence of SAMs will couple
to techniques for effluent transport and transformation analyses (ETTAs).
Together they are intended to provide a coarse screening of effluent stream
impact for use in environmental assessments.
This document describes the rationale and framework of the simplest
SAM, designed for rapid screening with no effluent transport and transforma-
tion analysis. Rapid screening of the degree of hazard and the rate of dis-
charge of toxic pollutants may occur at any level of depth of chemical and
physical analysis. Indeed, the decision to conduct detailed effluent char-
acterization analysis (i.e., "Level 2") will ordinarily be made as a result
of a SAM analysis based on an initial screening. The SAM procedure has been
designed to provide the guidance required to go from "Level 1," in which
only the presence of broad categories of chemical compounds is determined,
to "Level 2," in which the presence or absence of specific chemical com-
pounds is established.
An introductory discussion of the rationale followed by a stepwise
description of the SAM/IA format is given below. Examples of the applica-
tion of SAM/IA follow to illustrate use of the SAM/IA model and format. The
two key application modes for SAM/IA are:
• Interpretation of Level 1 sampling and analysis results to deter-
mine maximum potential "degree of hazard" and "toxic unit dis-
charge rate"
• Interpretation of Level 2 sampling and analysis results to deter-
mine potential "degree of hazard" and "toxic unit discharge rate"
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In SAM/IA, major simplifying assumptions have been made about pollu-
tant transport and transformation in the environment prior to impact on a
receptor. The criteria against which pollutant concentrations are judged
have also been subject to simplifying assumptions. As a result, SAM/IA is
designed for use by experienced and qualified project officer and environ-
mental assessment contractor personnel who will, on a case-by-case basis,
review these assumptions to ensure the correct application of the model.
In addition, at the time of this report, many pollutants exist for which
MATEs have not yet been established. The user must, therefore, exercise
judgment in flagging these omissions and bringing them to the attention of
the EPA in terms of :
• Their importance to the particular environmental assessment being
conducted
0 Requirements for the continuing development of additional MATE
values
These user comments will prove invaluable in the further development of the
SAM/ETTA/MEG system.
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SECTION 2
SOURCE ANALYSIS MODEL FOR RAPID
SCREENING OF CONTROL OPTIONS
2.1 INTRODUCTION TO SAM
The use of a Source Analysis Model (SAM) for rapid screening of con-
trol options provides the environmental assessment community with a work-
book format which identifies input data requirements and guides the user
through a set of calculations. These calculations provide a quantitative
means of assessing the pollution potential of a source and of control options.
The SAM format focuses on each separate effluent stream which arises
during an energy production or industrial process. Such streams may exist
because of the process itself or may arise because of the application of pol-
lution control technology to a process-generated effluent. Examples of the
former are:
• Flue gas and bottom ash emissions from a utility boiler
• HpS, mercury and arsenic emissions from certain steam-dominated
geothermal wells
t Hydrocarbon emissions at petrochemical refineries
Examples of the latter are:
i
• Hopper ash from baghouses or electrostatic precipitators
• Scrubber-generated sludge
Each use of the SAM format assumes a specific set of effluent streams which
exit from the process itself or from the control technology in use. The
format then examines the extent or amount of environmental impact which
results, utilizing information on specific substances of concern determined
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from sampling data. SAM/IA includes formats for using either Level 1 or
Level 2 sampling data in keeping with EPA's phased approach to comprehensive
sampling and analysis.
In the phased approach to environmental assessment, Level 1 is the
initial emission analysis and is used to distinguish very hazardous effluent
streams from those which are less hazardous or are relatively innocuous.
Level 1 data, consisting of identified organic classes of compounds and in-
organic elements, generates the semiquantitative information which is then
used to select the detailed and specific analyses required in Level 2.
SAMs can be used to do one or more of the following:
• Rank effluent streams. In this application, the SAM is used to
compare the toxic-unit rate of discharge into each effluent
stream; these toxic-unit summations can then be ranked by magni-
tude. Examination of the relative magnitudes generated by differ-
ent streams immediately shows the relative hazard of the different
effluent streams.
t Establish specific Level 2 and additional Level 3 sampling and
analysis priorities in performing environmental assessments
t Determine problem pollutants and pollutant priorities. In this
application, use of the SAM can lead to an understanding of
which pollutants are most likely to cause major environmental
impact because they remain poorly controlled under all equipment
options currently available.
• Determine which control technology options are the most effective.
In this application, the SAM is used to examine a given process
stream with first one and then another control approach. The
impact of alternative control equipment choices can be compared
on the basis of:
— The differing reductions which can be expected to occur in
the original process stream pollutant emissions
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— The ways in which concentration of certain pollutants into
particular control equipment effluent streams will occur
• Determine the need for control/disposal technology development
Straightforward application of the proper SAM format can, therefore, be
used to accomplish a variety of goals.
In the simplest SAM, designated SAM/IA, effluent streams from any
process or applicable controls are not assumed to interact with the external
environment (i.e., transport of the components in Jhe effluent stream to the
external environment occurs without transformation of these components). No
assumption is made about pollutant-specific dispersion, but it is assumed
that such dispersion from the source to a receptor would, in almost all
cases, be equal to, or greater than, the safety factors normally applied to
acute (short-term exposure) toxicity data to convert them to estimated safe
low-level, longer-term chronic ambient exposure levels.
SAM/IA thus:
• Is on an effluent concentration basis
• Uses only one potential assessment alternative (the MATE)
• Does not include transport/transformation analysis
• Includes only degree of hazard/toxic-unit discharge calculations
2.2 SAM/IA CALCULATION PROCEDURE
The general procedure to be followed when using SAM/IA for a given
source and control-option is described and explained below. A detailed
description of how to fill out the forms (i.e., a user's handbook) appears
in Section 2.4. I
A key feature of SAM/IA is the individual comparison of process efflu-
ent stream (1) sample fractions (in Level 1), or (2) specific pollutant
species (in Level 2), to the MATE goals. MATE values have been created for
most of the 650 substances on the MEG pollutant list based upon health or
ecological effects reference data. The assumption is made that the concen-
trations of pollutants in gas, liquid or solid effluent streams should not
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exceed MATE values which are estimated to minimize acute (short-term expo-
sure) toxic effects.
The steps included in the SAM/IA approach are:
1. Identify specific sources within the overall system or process
2. Identify the various effluent streams from that source. Each gas,
liquid or solid waste discharge is included as a separate effluent
stream.
3. Determine the concentration of each sample fraction (Level 1) or
specific pollutant species (Level 2) to be considered in each
effluent stream. In Level 1 assessments, the set of species
potentially present which would lead to hazard is established at
this point for each sample fraction.
4. Each sample fraction or specific pollutant concentration in a
given effluent stream is then divided by its corresponding health-
based MATE. This quantity is, henceforth, called a "degree of
hazard" (H). A second quotient is formed using the corresponding
ecological MATE.*
5. At this point, flags (i.e., checkmarks) are noted on the form for
each pollutant entry whose health or ecological degree of hazard
(H) is greater than unity. These flags have been put on the form
specifically for later ease in spotting potential problem pollu-
tants. Their presence should be noted and assessed in any report.
6. The final calculation for each pollutant species or sample frac-
tion in each stream takes the product of its degree of hazard (H)
and the effluent stream flowrate to establish health (or ecolog-
ical) toxic unit discharge rates (TUDR).
*
Both health and ecological MATEs may be known. If so, both should be com-
pared to the pollutant concentration.
8
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7. The total stream degree of hazard is then calculated as the sum
of the H's for each pollutant. Further, the total stream TUDR
is calculated by summing the individual pollutant entry toxic
unit discharge rates.
8. Degrees of Hazard and Toxic Unit Discharge Rates are then grouped
and summed by discharge media (i.e., the H's and TUDRs for all
gaseous, water and solid effluent streams are listed and summed
for each medium)
9. Finally, if a Level 1 assessment is being performed, any addi-
tional data which can be used to rule out the presence of
chemical species is noted in the sample fraction versus species
lists in Appendix A
It should be noted that the third step requires an enumeration of all
of the components of a given effluent stream which are to be considered. If
a component is not included in the enumeration, any environmental impact
which results from its discharge will not be included in the results.
The SAM/IA format will ordinarily be used for rapid screening of the
difference between an uncontrolled process and the results of the applica-
tion of various control options. Thus, it will ordinarily be applied to
confined or ducted sources.
Such rapid screening requires understanding of the assumptions being
made. These assumptions include:
t The user assumption that the -650 substances currently in the MEG
list as potential components of an effluent stream are the only
ones which need to be included. (Unknown components may be
sources of environmental impact which are modified or modifiable
by the control technology and therefore Level 1 bioassay results
will be important as a companion data base for interpretation of
SAM/IA results.)
• The methodology assumption that dispersion of effluents will be
adequate and will also offset any transformation to more toxic
substances
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• The MATE values (or the basic data they were developed from) are
adequate
• No synergistic, or the-whole-is-greater-than-the-sum-of-its-parts,
effects occur. The bioassay results are an important aid to in-
terpretation of this point.
These assumptions are "built-in" to SAM/IA. No provision has been
made for modification of the SAM/IA calculation method for specialized cir-
cumstances which are expected to be improbable. In many cases, perhaps
most, the assumptions are conservative. However, these factors should be
kept in mind in evaluating the need for more detailed assessment.
2.3 MATES FOR USE WITH THE SAM/IA FORMAT
MATE values for organic and inorganic compounds from fossil energy
processes are being generated by Research Triangle Institute under EPA Con-
tract No. 68-02-2612 (Reference 1).
MATEs describe very approximate concentrations of components or
species in air, water or land effluents which may evoke significant damage
responses in exposed humans or the ecology from limited duration exposures
(i.e., less than 8 hours per day). MATEs are derived from TLVs, NIOSH rec-
ommendations, LD50's, LDLO's, LC50's, TD^'s, TLMs, Water Quality Criteria
and Drinking Water Regulations.
Six MATEs may be listed for a single substance:
• Air (health and ecology based)
• Water (health and ecology based)
• Land (health and ecology based)
As many as six MATEs can be listed for each pollutant species or
sample fraction in the worksheets. This allows comparisons of emissions to
MATEs for air, water or land for studies of health or ecological effects.
These MATEs are based on currently available data. They are viewed by EPA
and RTI as providing a point of departure for further work, both within this ,
topical area and as inputs to environmental assessments. With these caveats
in mind, we caution the reader that there is no substitute for continuing
10
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critical review of their applicability on a case-by-case-basis. For further
discussion of MATE values including their basis and limitation, the reader
should consult Reference 1.
2.4 USER'S GUIDE TO THE SAM/IA FORMAT
SAM/IA has two forms on which to enter and process data. On the
first, each process is analyzed into component effluent streams. Then, for
each such stream, the appropriate* second form is used to compare each pollu-
tant in each stream against an environmental goal, and to sum over all such
comparisons to determine the degree of hazard which this stream poses.
Further entries on the first form then allow summation of the degree of
hazard over all gas, liquid or solid waste streams.
Blank SAM/IA format sheets are attached as Figures 2, 3 and 4.
Figures 2(a) and 2(b) show the IA01 summary sheet. Figures 3(a), 3(b) and
3(c) show the IA02 Level 1 worksheets and Figures 4(a) and (b) show the
IA02 Level 2 worksheets required for each effluent stream specified on the
IA01 summary sheet.
2.4.1 Instructions for the Use of the Summary Sheet (Form IA01)
On the IA01 summary sheet (Figures 2(a) and 2(b)) use the first line
to identify the source and applicable control options in sufficient detail
to distinguish this case from all others considered. For example, one could
specify the specific source, type and manufacturer of control units and
their collection efficiencies, the assumed«mode of operation (e.g., standard,
nonstandard), etc.
On line 2, enter the process throughput or capacity. The units used
will ordinarily be mass consumed or produced or energy consumed per unit
time. For example, for a boiler, this would be the fuel consumed in mega-
watts (i.e., megajoules/sec) or MBtu/hr.
Use the space at line 3 to sketch a block diagram of the system under
consideration. Include the source(s) and all associated control devices.
i.e., appropriate to a Level 1 and Level 2 assessment. (A different form
is used for each level.)
11
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Figure 2(a). IA01 Summary sheet, side 1.
SAM/IA SUMMARY SHEET Form IAOI
1. SOURCE AND APPLICABLE CONTROL OPTIONS
2. PROCESS THROUGHPUT OR CAPACITY
3. USE THIS SPACE TO SKETCH A BLOCK DIAGRAM OF THE SOURCE AND CONTROL ITEMS SHOWING ALL EFFLUENT
STREAMS. INDICATE EACH STREAM WITH A CIRCLED NUMBER USING 101-199 FOR GASEOUS STREAMS,
201-299 FOR LIQUID STREAMS, AND 301-399 FOR SOLID WASTE STREAMS.
4. LIST AND DESCRIBE GASEOUS EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
101
10?
103
104
lOfi
lOfi
107
5. LIST AND DESCRIBE LIQUID EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3. "
on?
?03
?04
?0fi
6. LIST AND DESCRIBE SOLID WASTE EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP
301
3.
30?
303
304
305
30fi
7. IF YOU ARE PERFORMING A LEVEL 1 ASSESSMENT, COMPLETE THE IA02-LEVEL 1 FORM FOR EACH EFFLUENT
STREAM LISTED ABOVE. IF YOU ARE PERFORMING A LEVEL 2 ASSESSMENT. COMPLETE THE IA02-LEVEL 2 FORM
FOR EACH EFFLUENT STREAM LISTED ABOVE.
12
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Figure 2(b). IA01 Summary sheet, side 2.
8. LIST SUMS FROM LINE 7, FORMS IA02. IN TABLE BELOW
DEGREE OF HAZARD AND TOXIC UNIT DISCHARGE RATES BY EFFLUENT STREAM
GASEOUS
STREAM
CODE
A
DEGREE OF
HAZARD
HEALTH
BASED
-
B
ECOL.
BASED
—
c
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(mVsec)
D
E
LIQUID
STREAM
CODE
F
9. SUM SEPARATELY GASEOUS, LIQUID AND
(I.E., SUM COLUMNS)
HEALTH-BAJ
GASEOUS (X COL. B) <
LIQUID (I COL. G) S
SOLID WASTE (I COL L) 9
10. SUM SEPARATELY GASEO
LINE 8 (I.E., SUM COLUM
GASEOUS (mVsec)
LIQUID (I/sec)
SOLID WASTE (g/sec
11. NUMBER OF EFFL
GASEOUS
LIQUID
SOLID WASTE
US. LIQUID AND
MS)
HEALTH-BA
(X COL D)
(I COL. 1)
) (£ COL. N)
DEGREE OF
HAZARD
HEALTH
BASED
-
G
ECOL.
BASED
-
H
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(I/sec)
1
J
SOLID WASTE STREAM DEGREES
TOTAL DEGREE OF HAZARD
5ED ECO
>A fSC
JR
r.
(1C
(2C
SOLID WASTE STREAM TOXIC U
TOTAL TOXIC UNIT Dl
iSED EC(
10A n
IOR
inr.
(5;
ft
SOLID WASTE
STREAM
CODE
K
OF HA,
LOGICAL
OL. C) <
OL. H)
9L M)
NIT DISC
3CHARG
DLOGICA
COL. E)
COL. J)
COL. 0)
DEGREE OF
HAZARD
HEALTH
BASED
—
L
ECOL
BASED
—
M
TOXIC UNIT
DISCHARGE RATES
HEALTH ECOL
BASED BASED
(g/sec)
N 0
ZARD FROM TABLE AT LINE 8
.-BASED
3A'
3R'
ar-
CHARGE RATES FROM TABLE AT
E RATES
kL-BASED
Tru-
mp-
mr-
UENT STREAMS
11A
11B
11C
12. LIST POLLUTANT SPECIES
KNOWN OR SUSPECTED TO BE EMITTED FOR WHICH A MATE IS NOT AVAILABLE.
13
-------
SAM/IA WORKSHEET FOR LEVEL 1
Figure 3(a). IA02 Worksheet, Level 1
Form IA02 Level 1
1. SOURCE/CONTROL OPTION Page l /
2. EFFLUENT STREAM 3. EF
CODE # NAME (g£
FLUENT STREAM FLOW RATE
Q =
s = mVsec — liquid = I/sec — solid waste = g/sec)
4. COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF FORM FOR SCRATCH WORK)
A
SAMPLE FRACTION
UNITS
B
FRACTION
CONCEN-
TRATION
C
HEALTH
MATE
CONCEN-
TRATION
D
ECOLOGICAL
MATE
CONCEN-
TRATION
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
—
F
ORDINAL
POSITION IN
HEALTH MATE
TABLE
—
G
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
—
H
ORDINAL
POSITION IN
ECOL. MATE
TABLE
—
1
V/IF
HEALTH
MATE
EXCEEDED
—
J
X/.F
ECOL.
MATE
EXCEEDED
—
K
L
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(i x LINE 3)
(ECOLOGICAL
BASED)
(G > LINE 3)
IF MORE SPACE IS NEEDED. USE A CONTINUATION SHEET
5. EFFLUENT STREAM DEGREE C
HEALTH MATE BASED (I COL.
ECOLOGICAL. MATE BASED (I
(ENTER HERE AND AT LINE 8,
F HAZARD
n 5a
nni G\ 5b
FORM IA01)
6. NUMBEF
COM PAR
HEALTH 6c
ECOLOGIC/
? OF ENTRIES 7. T(
ED TO MATES ..
n
, E(
\\ fih (E
DXIC UNIT DISCHARGE SUM
EALTH MATE BASED (S COL K)
)OLOGICAL MATE BASED (I COL
NTER HERE AND AT LINE 8. FO
7=.
1 ) 7h
RM IA01)
-------
Figure 3(b). IA02 Worksheet, notes,
NOTES
ASSUMPTIONS
LIST ALL ASSUMPTIONS MADE REGARDING FLOW RATE, EMISSION FACTORS AND MATE VALUES.
15
-------
Figure 3(c). IA02 Continuation Worksheet, Level 1.
CONTINUATION SHEET FOR ITEM NO. 4, FORM IA02, LEVEL 1
Page
SOURCE/CONTF
A
SAMPLE FRACTION
UNITS
?OI OPTION EFFL
B
FRACTION
CONCEN-
TRATION
—
c
HEALTH
MATE
CONCEN-
TRATION
D
ECOLOGICAL
MATE
CONCEN-
TRATION
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
K- F
ORDINAL
POSITION IN
HEALTH MATE
TABLE
G
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
H -
ORDINAL
POSITIONi.lN
ECOL. MATE
TABLE
1
N/IF
HEALTH
MATE
EXCEEDED
UENT STF
J
N/IF
ECOL.
MATE
EXCEEDED
—
JFAM NO
K | L
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
(ECOLOGICAL
BASED)
(G x LINE 3)
CTl
-------
SAM/IA WORKSHEET FOR LEVEL 2
Figure 4(a). IA02 Worksheet Level 2
Form IA02 Level 2
1. SOURCE/CONTROL OPTION
2.
4.
1
EFFLUENT STREAM
CODE # NAME
-~ -_ Page 1 /
3. EFFLUENT STREAM FLOW RATE
n =
(gas = mVsec — liquid = 1
/sec — solid = g/sec
)
COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF FORM FOR SCRATCH WORK)
A
POLLUTANT
SPECIES
UNITS
f
CATEGORY
—
B
POLLUTANT
CONCEN-
TRATION
._
C
HEALTH
MATE
CONCEN-
TRATION
f MORE SPACE IS NEEDED, USE A CONTINUATION SHEET
5, EFFLUENT STREAM
HEALTH MATE BAJ
ECOLOGICAL MATE
(ENTER HERE AND
DEGREE OF HAZARD
5ED (^ P.OI F) Ra
BASED (I COL, F) 5b
AT LINE 8, FORM IAC
)1)
D
ECOLOGICAL
MATE
CONCEN-
TRATION
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
6. NUME
POLLL
PAREC
HEALTH
ECOLOGI
IER OF
ITANTS COM-
) TO MATES
rA| fih
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
G
N/IF
HEALTH
MATE
EXCEEDED
—
H
V/,F
ECOL
MATE
EXCEEDED
—
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
(ECOLOGICAL
BASED)
(F i LINE 3)
7. TOXIC UNIT DISCHARGE SUM
HEALTH MATE BASED (1 COL. 1)
ECOLOGICAL MATE BASED (i! CO
(ENTER HERE AND AT LINE 8, FC
1) 7h
RM IA01)
-------
CONTINUATION SHEET FOR ITEM NO. 4, FORM IA02, LEVEL 2
Figure 4(b). IA02 Continuation Worksheet, Level 2.
Page
SOURCE/CONTROL 0
PTIDN . EFFLU
A
POLLUTANT
SPECIES
UNITS
— — — T:-x; -'
CATEGORY
-
B
POLLUTANT
CONCEN-
TRATION
C
HEALTH
MATE
CONCEN-
TRATION
D
ECOLOGICAL
MATE
CONCEN-
TRATION
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
'
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
G
N/.F
HEALTH
MATE
EXCEEDED
—
ENT STRE
H
V.F
ECOL
MATE
EXCEEDED
"AM NO
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
(ECOLOGICAL
BASED)
(F x LINE 3)
CD
-------
An additional page may be used as an atttachment. Show all effluent streams,
and number those which discharge to the environment. Use the numbers 100 to
199 for gaseous discharges, 200 to 299 for liquid discharges and 300 to 399
for solid waste discharges.
On line 4, list gaseous effluent streams as numbered in the sketch
in line 3.
On line 5, list liquid effluent streams as numbered in the sketch in
line 3.
On line 6, list solid effluent streams as numbered in the sketch in
line 3.
Next, as stated in line 7 of Form IA01, for each effluent stream
listed in lines 4, 5, and 6, complete an appropriate IA02 form. Note that
different forms are used for Level 1 and Level 2 assessments. When these
forms are complete, return to lime 8 on Form IA01. At this point, the
degree of hazard and the toxic unit discharge rate will be known for each
pollutant identified in each stream, and overall values for each stream as
a whole will have been determined.
At line 8 of Form IA01 (see Figure 2(b)), list effluent stream code
numbers and associated ecological and health-based degrees of hazard (from
lines 5a and 5b of Form IA02) and toxic unit discharge rates (from lines 7a
and 7b of Form IA02).
For line 9, sum the health-based degrees of hazard for gaseous,
liquid and solid effluent streams separately. Enter the results on lines
9a, b and c, respectively.
Similarly, sum the ecological-based degrees of hazard for gaseous,
liquid and solid effluent streams separately and enter them on lines 9a',
9b' and 9c', respectively.
On line 10, sum the health-based toxic unit discharge rates for
gaseous, liquid and solid effluent streams separately. Enter the results
on lines lOa, b and c, respectively.
19
-------
Similarly, sum the ecological-based toxic unit discharge rates for
gaseous, liquid and solid effluent streams separately and enter them on
lines 10a', 10b' and 10c', respectively.
At line 11, enter the number of gaseous, liquid and solid effluent
streams in lines Ha, lib and lie, respectively.
Finally, at line 12, list pollutant species known or suspected to be
emitted for which a MATE is not available.
This completes the discussion of Form IA01.
2.4.2 Instructions for the Use of the Worksheet (Form IA02)
Two different versions of Form IA02 are available; the first is
appropriate for use when a Level 1 assessment is underway, the second is
appropriate for use in Level 2 assessments. Level 1 assessments require
knowledge of the process stream sample fraction concentrations. Level 2
assessments require knowledge of the concentrations of the specific pollu-
tant species which are being considered.
Choose and complete the applicable worksheet for the effluent stream
which is to be considered.
2.4.2.1 Completion of Form IA02 - Level 1
On line 1 (Figures 3(a), 3(b) and 3(c)) fill in the system descrip-
tion as in line 1, Form IA01. At line 2, enter the code number and descrip-
tion of the effluent stream to be evaluated on this page (i.e., one of the
streams listed on lines 4, 5, and 6 on Form IA01).
Next, enter the flowrate of this effluent stream in appropriate units
at line 3. The appropriate unit for gaseous streams is cubic meters per
second (m3/s); for liquid streams, liters per second (1/s); and for
solid streams, grams per second (g/s).
Line 4 requires the completion of a table of data. In column A, list
all sample fractions known to be present in this effluent stream which are
in the MEG pollutant list.
20
-------
In column B the measured concentration of each sample fraction in
the effluent stream is entered.
The "health-based MATE concentration" (for column C) and "ordinal
table position" (for column F) are determined by the following procedure:
Look up the sample fraction name in column 1 of the key to
the lists, Table A-l in Appendix A. The right half of this
key lists the health-based MATE value which is to be entered
in column C of Form IA02. (Choose the value appropriate for
the medium: gaseous, liquid or solid waste.) The left half
of the key then refers to another list in Appendix A. Go to
this list and choose, from its third column, the ordinal
number of the last species in the sample fraction of inter-
est whose MATE concentration is less than or equal to the
measured sample concentration. Enter this number in column
F of Form IA02. (For cases where all MATEs exceed the
sample concentration, enter a blank (--). Many sample
fractions contain compounds for which MATEs are not yet
available (N). To be conservative, treat N as zero and
enter the ordinal number of the last species with an N if
all known MATEs exceed the sample concentration.) If a
decision is made later to perform a Level 2 assessment,
only those species listed (from the species in the first
line to the species whose line number was just entered)
need to be considered for inclusion in the Level 2
assessment.*
Repeat this procedure for ecological MATES to provide the entries for
column D of Form IA02 and the ordinal list positions for column H.
*
Additional data, such as IR spectra, available at Level 1 may be used to
rule out the presence of some of these species. This is discussed further
in Section 2.4.3.
21
-------
Note that the ordinal positions established for Level 2 for health
and ecology-based determinations need not be identical. Further, the
chemical species in a certain sample fraction for which Level 2 must be per
formed need not be the same for health and ecological considerations.
In column E, calculate the degree of health hazard (H) due to each
pollutant as (for a given line):
u/. ,.. x Fraction concentration nvt ^«ilimn c - column B
H(health) = - - ' or column E "
health MATE - ' " column C
Similarly for column G calculate the degree of ecological hazard due
to this pollutant as:
u, rtl «„.,•„„ -i \ _ Fraction concentration nv, _ft •,.,_„ r - column B
H(ecological) -- ecological MATE - • or column G " column D
In column I, enter a checkmark if the health MATE is exceeded (i.e.,
column E > 1). Similarly, in column J, enter a checkmark if the ecological
MATE is exceeded (i.e., column F > 1).
For column K, calculate a health-based toxic unit discharge rate for
each as "degree of health hazard" (H) times "stream flowrate:"
TUDR(health) = H(health) x stream flowrate, or
column K = (column E) x (line 3)
Similarly, for column L calculate an ecological -based toxic unit discharge rate
for each pollutant as degree of ecological hazard times flowrate: i.e.,
TUDR(ecological) = H(ecological) x stream flowrate, or
column L = (column G) x (line 3)
Next, at line 5a, calculate the total effluent degree of hazard (health-
MATE based) as the sum of all the individual pollutant degree of hazard ,
values for the stream: i.e., sum column E including values on any continua-
tion sheets) and enter the sum on line 5a. Enter the total ecological -MATE
based degree of hazard (i.e., sum column G) on line 5b.
22
-------
Further enter this health-based value on line 8, Form IA01 in
column B for gaseous, G for liquid or L for solid effluent streams.
Similarly, enter the ecological-based degree of hazard sum in column C, H or
M on line 8, Form IA01.
At line 6 count the number of sample fractions, N, listed in column A,
for which MATE values exist. Enter the number of sample fractions with
health MATE values at line 6a and enter the number of sample fractions with
ecological-based MATEs at line 6b. At line 7 compute the sum of health-
based TUDR: i.e., sum column K and enter the result at line 7a. Next, sum
the ecological-based TUDR ( column L) and enter the result at line 7b.
Finally, rewrite the result at line 7a of Form IA02 on line 8, Form
IA01 in column D, I or N for the health-based sum of TUDR; also rewrite the
result at line 7b of Form IA02 on line 8, Form IA01, in column E, J, or 0.
This completes the discussion of Form IA02 as used in Level 1.
2.4.2.2 Completion of Form IA02 - Level 2
Completion of Form IA02 for a Level 2 assessment requires knowledge
of the concentrations of the specific pollutant species which are to be
considered for the stream.
On line 1 (Figure 4(a)) fill in the system description as in line 1,
Form IA01. At line 2, enter the code number and description of the effluent
stream to be evaluated on this page (i.e., one of the streams listed on
lines 4, 5, and 6 on Form IA01).
Next, enter the flowrate of this effluent stream in appropriate units
at line 3. The appropriate unit for gaseous streams is cubic meters per
second (m3/s); for liquid streams, liters per second (1/s); and for solid
streams, grams per second (g/s).
Line 4 requires the completion of a table of data. In column A, list
all pollutant species known to be present in this effluent stream which are
in the MEG pollutant list. '
In addition, in column A enter the chemical category for each pollu-
tant species to be considered. Chemical categories are listed in Appendix A
Lists 7 and 8.
23
-------
In column B the measured concentration of each pollutant in the
effluent stream is entered. If actual (measured) concentrations are not
known an alternative of lesser preference is to utilize emission factor
data to calculate the concentration.
For column C, enter a health-based MATE value for each pollutant in
column A. (If a health-based MATE is not available, flag this pollutant on
line 12 of Form IA01.)
For column D, follow the directions for column C but use ecological-
based MATE values.
In column E, calculate the degree of health hazard (H) due to each
pollutant as (for a given line):
„/. Q,,.. x pollutant concentration „ __•,,,_„ r - column B
H 1). Similarly in column H, enter a checkmark if the ecological
MATE is exceeded (i.e., column F > 1).
For column I, calculate a health-based toxic unit discharge rate for
each pollutant as "degree of health hazard" (H) times "stream flowrate:"
TUDR(health) = H(health) x stream flowrate, or
column I = (column E) x (line 3)
Similarly, for column J calculate an ecological-based toxic unit discharge rate
for each pollutant as degree of ecological hazard times flowrate: i.e.,
TUDR(ecological) = H(ecological) x stream flowrate, or
column J = (column F) x (line 3)
24
-------
Next, at line 5a, calculate the total effluent degree of hazard (health-MATE
based) as the sum of all the individual pollutant degree of hazard values
for the stream, i.e., sum column E (including values on any continuation
sheets) and enter the sum on line 5a.
And, similarly, for line 5b, calculate the total effluent degree of
hazard (ecological-MATE based) as the sum of all the individual pollutant
degree of hazard values for the stream, i.e., sum column F (including values
on any continuation sheets) and enter the sum on line 5b.
In addition, enter the health-based sum on line 8, Form IA01 in
column B, G or L for gaseous, liquid or solid effluent streams, respectively.
Similarly, enter the ecological-based degree of hazard sum in column C, H
or M.
At line 6 count the number of pollutants, N, listed in column A, for
which MATE values exist. Enter the number of species with health-based MATE
values at line 6a and enter the number of species with ecological-based MATEs
at line 6b. At line 7 compute the health-based toxic unit discharge sum by
entering the total value of the health-based TUDR: i.e., sum column I and
enter this sum on line 7a. Next, sum the ecological-based TUDR (i.e., sum
column J) and enter this sum on line 7b.
Finally, enter this sum on line 8, Form IA01 in column D, I or N for
the health-based TUDR; enter the sum from line 7b, the ecological-based sum,
in column E, J or 0.
This completes the discussion of Form IA02 as used in Level 2 assess-
ments.
2.4.3 Further Data to be Entered in Appendix A
After completing both forms in a Level 1 environmental assessment, any
additional data known about the various sample fractions should be entered in
the appropriate list in Appendix A. As an example, IR spectra determined
during a Level 1 assessment may be used together with low resolution mass
spectroscopy (LRMS) to rule out the presence of any hydroxyl-containing com-
pounds with molecular weights greater than a certain value. If such compounds
25
-------
are still potentially present, as established by the concentration-determined
ordinal number for the appropriate sample fraction tables, then the IR-LRMS
data may be used to cross out additional compounds occurring in these lists
between the first entry and the ordinal number position for that list. The
rationale for the deletion of the compound from further consideration should
be written to the right of the line for that compound.
26
-------
SECTION 3
SAM/IA APPLICATION EXAMPLES
3.1 INTRODUCTION
In this section, four sets of illustrative examples of the application
of the SAM/IA format are presented. As of the drafting of this report com-
prehensive Level 1 and Level 2 sampling and analysis results were not avail-
able for a specific source,, but will become available in the near future.
Data are available for only a few pollutants in the examples used.
The first example shows the SAM/IA technique applied to hypothetical
Level 1 samples from a fluidized bed combustor.
The second example includes:
a. An uncontrolled wet bottom utility boiler with air and water-
slurried flyash emissions
b. The addition of an ESP to case (a), with consequent removal of
particulates and addition of solid wastes from the ESP
c. The addition of combustion modifications for NOX control to
case (b)
The third and fourth examples illustrate use of the format with pro-
cess industries. The examples chosen are a glass melting furnace coupled
to an annealing lehr and coke byproduct ovens with and without the applica-
tion of control technology.
These examples are included to show how efficiently one may apply the
SAM technique. Further, they demonstrate ..that useful information may be
obtained even if only some of the effluent streams from a given process are
considered.
27
-------
In these examples, standard notation has been used whenever possible
with the exception that numbers such as "1.2 x 10s" are sometimes presented
in computer format, i.e., as 1.2E5.
3.2 EXAMPLE 1 -A HYPOTHETICAL FLUIDIZED BED COMBUSTOR
Example 1 (Figures 5(a), 5(b), 5(c), 5(d)) show the application of
the SAM/IA procedure to a hypothetical fluidized bed combustor (FBC). In
an attempt to inject realism into the example, the following combination
of data was created:
• A power generation capacity of 30 MW for the FBC (about the size
of existing units)
• An approximation to the flue gas effluent stream flowrate of
existing units
• Tentative Level 1 sampling data from a TRW study of the Battelle,
Columbus, FBC
These data were used to fill out the SAM/IA forms.
This procedure illustrates the use of Table A-l from the appendix and
the accessory lists to which Table A-l directs the user for specific sample
fractions.
3.3 EXAMPLE 2 - UTILITY BOILER
Example 2a shows the application of the SAM/IA procedure to hypothet-
ical Level 2 results from a utility boiler under three different methods of
pollution control and is shown in Figures 6(a) through (6e). A wall-fired
boiler with a capacity of 1110-MW thermal input (1.1 x 109 joules/sec) was
chosen. Example 2a is an assessment of this unit under baseline operating
conditions (i.e., no control techniques applied). The significant combustion-
generated effluent streams in a boiler were considered to be the flue gas and
the slurried bottom ash (References 2, 3, 4 and 5).
The second example (2b) adds a 99 percent efficient electrostatic
precipitator and is shown in Figures 7(a) through 7(f). This reduces the
amount of particulate in the flue gas, but results in the addition of a
28
-------
Figure 5(a). Example 1.
SAM/IA SUMMARY SHEET
Form IA01
1. SOURCE AND APPLICABLE CONTROL OPTIONS
Fluidized Bed Combustor
2. PROCESS THROUGHPUT OR CAPACITY electrical output: 30
3. USE THIS SPACE TO SKETCH A BLOCK DIAGRAM OF THE SOURCE AND CONTROL ITEMS SHOWING ALL EFFLUENT
STREAMS. INDICATE EACH STREAM WITH A CIRCLED NUMBER USING 101-199 FOR GASEOUS STREAMS,
201-299 FOR LIQUID STREAMS, AND 301-399 FOR SOLID WASTE STREAMS.
FBC
Primary
Cyclone
Secondary
Particulate
Removal
4. LIST AND DESCRIBE GASEOUS EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
Flue Gas
102
103
104
105
106
107
5. LIST AND DESCRIBE LIQUID EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
201
202
203
204
205 j :
206
6. LIST AND DESCRIBE SOLID WASTE EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
301
302
303
304
305
306
7. IF YOU ARE PERFORMING A LEVEL 1 ASSESSMENT, COMPLETE THE IA02-LEVEL 1 FORM FOR EACH EFFLUENT
STREAM LISTED ABOVE. IF YOU ARE PERFORMING A LEVEL 2 ASSESSMENT, COMPLETE THE IA02-LEVEL 2 FORM
FOR EACH EFFLUENT STREAM LISTED ABOVE.
_
-------
Figure 5(b). Example 1 (Continued).
8. LIST SUMS FROM LINE 7,
FORMS IA02, IN TABLE BELOW
DEGREE OF HAZARD AND TOXIC UNIT DISCHARGE RATES BY EFFLUENT STREAM
GASEOUS
STREAM
CODE
101
A
DEGREE OF
HAZARD
HEALTH
BASED
-
1.2E5
B
ECOL
BASED
—
13.9
C
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
fmVsec)
3.7E6
D
431
E
LIQUID
STREAM
CODE
F
9. SUM SEPARATELY GASEOUS, LIQUID AND !
(I.E., SUM COLUMNS)
HEALTH-BAS
GASEOUS (I COL. B) 9
LIQUID (2 COL G) 9
SOLID WASTE (I COL L) 9
10. SUM SEPARATELY GASEOUS. LIQUID AND
LINE 8 (I.E., SUM COLUMNS)
HEALTH-BA
GASEOUS (mVsec) (I COL D)
LIQUID (I/sec) (I COL. 1) ]
SOLID WASTE (g/sec) (I COL N)
11. NUMBER OF EFFLI
GASEOUS
LIQUID
SOLID WASTE
DEGREE OF
HAZARD
HEALTH
BASED
—
G
ECOL.
BASED
-
H
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(I/sec)
I
J
SOLID WASTE STREAM DEGREES
TOTAL DEGREE OF HAZARD
,ED ECO
A 1.2E5 (ZC.
R
r.
(£C
(SC
SOLID WASTE STREAM TOXIC U
TOTAL TOXIC UNIT DIS
SED EC(
10A 3.7E6 tf
nR
mr.
JENT STREAMS
IIA One
11B
11C
(I
C <
SOLID WASTE
STREAM
CODE
K
OF HA:
LOGICAL
OL. C) <
OL. H) <
OL. M) <
NIT DISC
5CHARG
)LOGICA
COL E)
COL. J)
COL. 0)
DEGREE OF
HAZARD
HEALTH
BASED
—
L
ECOL
BASED
—
M
TOXIC UNIT
DISCHARGE RATES
HEALTH ECOL.
BASED BASED
(g/sec)
;
N 0
?ARD FROM TABLE AT LINE 8
.-BASED
»A- 13.9
3R'
JC'
CHARGE RATES FROM TABLE AT
E RATES
L-BASED
IOA- 431
10R'
inr- , j
* ]
.* -
12. LIST POLLUTANT SPECIES KNOWN OR SUSPECTED TO BE EMITTED FOR WHICH A MATE IS NOT AVAILABLE
No health MATE for $03; no ecological MATES for Be, Ba, Pb, As, SOs, Se, Te, F",
HC1, Cd.
30
-------
SAM/IA WORKSHEET FOR LEVEL 1
Figure 5(c). Example 1 (Continued),
Form IA02 Level 1
1. SOURCE/CONTROL OPTION Page j / 2
Fluidized Bed Combustor
2. EFFLUENT STREAM 3. EFFLUENT STREAM FLOW RATE
101 Flue aas Q = __31_m!/sec
COOED NAME (gas = mVsec — liquid - I/sec — solid waste - g/sec)
4. COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF FORM FOR SCRATCH WORK)
A
SAMPLE FRACTION
UNITS
LCI
LC2
LC3
LC4
LC5
LC6
LC7
LC8
LCI 2
SGC
C1-C6
C6-C12
32/Be
Jg/Bfl
B
FRACTION
CONCEN
TRATION
4200.
605.
2400.
1900.
610.
920.
1000.
11.
11.
No Data
No Data
No Data
<0.026
<1.3
C
HEALTH
MATE
CONCEN-
TRATION
100.
no.
0.02
990.
1300.
170.
100.
6000.
16000.
»
••••
— ^_
2.
500.
D
ECOLOGICAL
MATE
CONCEN-
TRATION
—
-_
--
__
__
— _
__
__
__
m >—
^lfm
fm —
_ —
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
—
42.
5.5
1.2xl05
1.92
0.46
5.41
10.
1.8xlO~3
6.8xlO"4
«*•
« mm
— —
<0.013
<0.0026
F
ORDINAL
POSITION IN
HEALTH MATE
TABLE
—
2
8
32
10
7
22
7
2
__
_«.
mf _
« ••
__
__
G
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
—
—
__
__
„_
— -,
. ,—
— —
H_
__
^^
._
__
..
H
ORDINAL
POSITION IN
ECOL. MATE
TABLE
—
—
__
__
__
—_
_ ^
__
_w
__
^ ^
— —
^^ _
_—
__
1
N/IF
HEALTH
MATE
EXCEEDED
—
/
/
/
/
— »
/
/
__
- —
^^ ^
•• «•
^ ^
— —
._
J
\/IF
ECOL.
MATE
EXCEEDED
—
—
_—
__
_.
«—
— _
««
— _
— _
•w^
— _
^ ^
__
__
K | L
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
1.3x10-*
17
3.7xl06
59.5
14.3
168 .
310.
0.06
0.02
_ —
— _
^ ^
<0.4
7h 431
?M IA01)
-------
CONTINUATION SHEET FOR ITEM NO. 4, FORM IA02, LEVEL 1
Figure 5(d). Example 1 (Concluded).
Page 2 / 2
sniiRr.F/mNTimi OPTION Fluidized Bed Combustor EFFLUENT STRFAM NO 101
A
SAMPLE FRACTION
UNITS
46/Pb
47/NH3 ^
47/HCN
49/As
53/S03
54/Se-
55/Te
56/F-
57/HC1
82/Cd
83/Hq
B
FRACTION
CONCEN-
TRATION
<1.3
4. 87x1 Q*
200.
0.039
550
<0.039
<0.26
570
5.5xl04
<0.052
0.009
C
HEALTH
MATE
CONCEN-
TRATION
150.
l.SxlO4
l.lxlO4
2.
—
200.
100.
2.5xl03
7000.
10.
50.
D
ECOLOGICAL
MATE
CONCEN-
TRATION
__
350. .
3.4xl04
—
—
—
—
--
__
__
10.
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
<0.0087
0.27
0.018
0.02
—
<2xlO"^
<2.6xlO">:
0.23
7.9
<0.005
1.8xlO"4
F
ORDINAL
POSITION IN
HEALTH MATE
TABLE
__
—
—
—
—
—
--
__
—
—
G
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
__
13.9
0.0059
—
.
—
__
—
__
—
9x1 O"4
H
ORDINAL
POSITION IN
ECOL. MATE
TABLE
__
—
—
—
—
—
_-
—
__
—
—
1
V.F
HEALTH
MATE
EXCEEDED
—
__
—
—
—
—
—
—
_-
/
--
—
J
VlF
ECOL.
MATE
EXCEEDED
—
__
/
—
—
—
—
—
_-
__
__
—
K
L
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
<0.27
8.4
0.56
0.62
—
<0.006
<0.08
713.
245.
<0.16
0.006
(ECOLOGICAL
BASED)
(G x LINE 3)
«•»
431
0.18
—
—
__
__
__
__
0.03
co
ro
-------
Figure 6(a). Example 2(a).
SAM/IA SUMMARY SHEET Form IAOI
1. SOURCE AND APPLICABLE CONTROL OPTIONS
Wall-fired utility boiler/bit, coal fuel/uncontrolled
2. PROCESS THROUGHPUT OR CAPACITY 1.1 X 109 J/S6C fuel input (1110 MW)
3. USE THIS SPACE TO SKETCH A BLOCK DIAGRAM OF THE SOURCE AND CONTROL ITEMS SHOWING ALL EFFLUENT
STREAMS. INDICATE EACH STREAM WITH A CIRCLED NUMBER USING 101-199 FOR GASEOUS STREAMS,
201-299 FOR LIQUID STREAMS, AND 301-399 FOR SOLID WASTE STREAMS.
Flue gas
lOl)
4. LIST AND DESCRIBE GASEOUS EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
101 Flue gas
102
103
104
105
106
107
5. LIST AND DESCRIBE LIQUID EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
201 Bottom ash slurry
202
203
204
205 s
206
6. LIST AND DESCRIBE SOLID WASTE EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
301
302
303
304 -
305
306
7. IF YOU ARE PERFORMING A LEVEL 1 ASSESSMENT, COMPLETE THE IA02-LEVEL 1 FORM FOR EACH EFFLUENT
STREAM LISTED ABOVE. IF YOU ARE PERFORMING A LEVEL 2 ASSESSMENT, COMPLETE THE IA02-LEVEL 2 FORM
FOR EACH EFFLUENT STREAM LISTED ABOVE.
33
-------
Figure 6(b). Example 2(a) (Continued).
8. LIST SUMS FROM LINE 7, FORMS IA02. IN TABLE BELOW
DEGREE OF HAZARD AND TOXIC UNIT DISCHARGE RATES BY EFFLUENT STREAM
GASEOUS
STREAM
CODE
101
A
DEGREE OF
HAZARD
HEALTH
BASED
-
789
B
ECOL
BASED
—
1700
C
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(m'/sec)
4.2E5
D
9.1E5
E
LIQUID
STREAM
CODE
201
F
9. SUM SEPARATELY GASEOUS, LIQUID AND <
(I.E., SUM COLUMNS)
HEALTH-BAS
GASEOUS (i COL B) 9
LIQUID (I COL G) 9
SOLID WASTE (I COL. L) 9
10. SUM SEPARATELY GASEOUS, LIQUJD AND
LINE 8 (I.E., SUM COLUMNS)
HEALTH-BA
GASEOUS (mVsec) (X COL. D)
LIQUID (I/sec) (X COL. 1) 1
SOLID WASTE (g/sec) (X COL N)
11. NUMBER OF EFFLI
GASEOUS
LIQUID
SOLID WASTE
DEGREE OF
HAZARD
HEALTH
BASED
—
0.063
G
ECOL
BASED
-
4.1
H
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(I/sec)
4.3
1
279
J
SOLID WASTE STREAM DEGREES
TOTAL DEGREE OF HAZARD
,ED ECO
A 789 rx n
R 0.063
r.
(XC
(XC
SOLID WASTE STREAM TOXIC U
TOTAL TOXIC UNIT DIJ
SED ECC
IOA 4.2E5 ,T ,
nR 4.3
inr.
JENT STREAMS
n A one
11B
11C
one
(X (
(X <
SOLID WASTE
STREAM
CODE
K
OF HA2
LOGICAL
OL. C) «
OL H) <
9L M) <
MIT DISC
5CHARG
)LOGICA
:OL E)
:OL j)
:OL. o)
DEGREE OF
HAZARD
HEALTH
BASED
—
L
ECOL.
BASED
-
M
TOXIC UNIT
DISCHARGE RATES
HEALTH ECOL
BASED BASED
(g/sec)
N 0
!ARD FROM TABLE AT LINE 8
-BASED
JA- 1700
IR- 4.1
ifV
CHARGE RATES FROM TABLE AT
E RATES
L-BASED
10A- 9.1E5
10R- 279
ior
I !
1 I
12. LIST POLLUTANT SPECIES KNOWN OR SUSPECTED TO BE EMITTED FOR WHICH A MATE IS NOT AVAILABLE.
HC, participates, NOV, SO, Al, As, V, Zn, Zr, Pb
* X
34
-------
SAM/IA WORKSHEET FOR LEVEL 2
Figure 6(c). Example 2(a) (Continued)
Form IA02 Level 2
1. SOURCE/CONTROL OPTION Rage 1 / 2
Wall -fired utility boiler/uncontrolled
2.
4.
I
EFFLUENT STREAM 3.
101 Flue gas
CODE # NAME
EFFLUENT STREAM FLOW RATE
0 = 537 m3/S
(gas = mVsec — liquid = 1
/sec —
solid = g/sec)
COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF FORM FOR SCRATCH WORK)
A
POLLUTANT
SPECIES
UNITS
NOX
S0x
CO
HC
Parti cul ate
Al
As
Hg
V
In
CATEGORY
—
47
53
42
—
—
38
49
83
65
81
B
POLLUTANT
CONCEN-
TRATION
yg/m3
6.59xl05
2. 66x1 O6
4. 49x1 O4
l.SxlO3
3.5x106
4. 49x1 O5
817
14.7
1.7xl03
1.7x10*
c
HEALTH
MATE
CONCEN-
TRATION
ug/m°
9,000
13,000
40,000
—
—
5,200
2
50
500
4,000
D
ECOLOGICAL
MATE
CONCEN-
TRATION
ug/m3
—
—
120,000
—
—
—
—
10
1
—
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
73.2
205
1.12
—
—
86.3
409
0.29
3.4
4.3
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
0.37
—
—
—
—
1.47
1.7xl03
—
G
N/IF
HEALTH
MATE
EXCEEDED
—
V
/
/
—
—
/
/
—
/
/
H
N/IF
ECOL
MATE
EXCEEDED
—
- —
/
/
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
m3/sec
3.9xl04
1.1x10
6x1 02
—
—
4.6xl04
2.2xl05
1.6xl02
l.SxlO3
2.3xl03
(ECOLOGICAL
BASED)
(F i LINE 3)
m3/sec
—
—
2x1 02
—
—
—
—
7.9x102.
9.1xl05
—
f MORE SPACE IS NEEDED, USE A CONTINUATION SHEET
5. EFFLUENT STREAM
HEALTH MATE BAS
ECOLOGICAL MATE
: (ENTER HERE AND
DEGREE OF HAZARD
JED (X rn| F) 5a 789
BASED (I COL. F) 5b
AT LINE 8, FORM (AC
1.7xl03
)1)
6. NUMB
POLLL
PAREC
HEALTH
ECOLOGI
ER OF 7. T
ITANTS COM- .
) TO MATES
fia 10 F
r.Ai fih 3 (
OXIC UNIT DISCHARGE SUM
IEALTH MATE BASED (£ COL. 1)
COLOGICAL MATE BASED (£ CO
ENTER HERE AND AT LINE 8, FO
7a 4.2xl05
h7h 9.1x10"
RM IA01)
U1
-------
CONTINUATION SHEET FOR ITEM NO. 4. FORM IA02, LEVEL 2 Figure 6(d). Example 2(a) (Continued).
Page
2/2
SOURCE/CONTROL 0
p-nnw Wall -fired utility boiler/uncontrolled EFFLU
A
POLLUTANT
SPECIES
UNITS
Ir
Pb
CATEGORY
—
63
46
•W'
—
B
POLLUTANT
CONCEN-
TRATION
ug/m3
2.1xl03
874
c
HEALTH
MATE
CONCEN-
TRATION
yg/m
5,000
150
D
ECOLOGICAL
MATE
CONCEN-
TRATION
ug/m
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
0.42
5.8
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
G
VlF
HEALTH
MATE
EXCEEDED
—
v/
ENT STRE
H
N/IF
ECOL
MATE
EXCEEDED
—
AM NO 101
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
m3/sec
2.3xl02
3x1 03
(ECOLOGICAL
BASED)
(F x LINE 3)
m-Vsec
—
—
-------
SAM/IA WORKSHEET FOR LEVEL 2 Figure 6(e). Example 2(a) (Concluded)
Form IA02 Level 2
1. SOURCE/CONTROL OPTION Rage 1 / 1
Wall -fired utility boiler/uncontrolled
2. EFFLUENT STREAM 3.
201 Bottom ash (slurry)
4.
i
CODE # NAME
EFFLUENT STREAM FLOW RATE
n= 68.2 1/sec
(gas = mVsec — liquid = 1
/sec —
solid = g/sec)
COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF FORM FOR SCRATCH WORK)
A
POLLUTANT
SPECIES
UNITS
Al
As
Hg
V
Zn
Zr
Pb
CATEGORY
—
38
49
83
65
81
63
46
B
POLLUTANT
CONCEN-
TRATION
ug/i
3. 53x1 O3
2.14
6x1 O"3
5.75
45
25
1.21
C
HEALTH
MATE
CONCEN-
TRATION
yg/i
8x1 04
250
10
2,500
2.5xl04
7.5xl04
250
D
ECOLOGICAL
MATE
CONCEN-
TRATION
ug/i
•103
50
250
150
102
—
50
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
0.044
9x1 O"3
6x1 O"4
2.3xlO"3
l.SxlO"3
3.3xlO"4
4.8xlO"3
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
3.53
0.043
2.4xlO"5
3.8x10-2
0.45
—
2.4xlO"2
G
N/.F
HEALTH
MATE
EXCEEDED
—
H
V.F
ECOL
MATE
EXCEEDED
—
•
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E » LINE 3)
1/sec
3.0
0.6
0.04
0.16
0.12
0.02
0.33
(ECOLOGICAL
BASED)
(F i LINE 3)
1/sec
241
2.9
1.6xlO"3
2.6
30.7
—
1.65
f MORE SPACE IS NEEDED, USE A CONTINUATION SHEET
5. EFFLUENT STREAM
HEALTH MATE BAS
ECOLOGICAL MATE
(ENTER HERE AND
DEGREE OF HAZARD
JED (E COL E) 5a °-063
BASED a COL. F) 5b
AT LINE 8, FORM IAC
4.1
>D
6. NUME
POLLL
PAREC
HEALTH
ECOLOGI
ER OF 7. 1
TANTS COM- ,
) TO MATES
fia 7 E
CAI fih 6 (
'OXIC UNIT DISCHARGE SUM
1EALTH MATE BASED (I COL. 1)
COLOGICAL MATE BASED (X CO
ENTER HERE AND AT LINE 8, FC
4-3
.)7h 279
RM IA01)
co
-------
Figure 7(a). Example 2(b).
SAM/IA SUMMARY SHEET
Form IA01
1. SOURCE AND APPLICABLE CONTROL OPTIONS
Wall-fired utility boiler/bit, coal fuel/electrostatic precipitator (n = 99%)
2. PROCESS THROUGHPUT OR CAPACITY 1.1 X 10 J/S fuel input (1110 MW)
3. USE THIS SPACE TO SKETCH A BLOCK DIAGRAM OF THE SOURCE AND CONTROL ITEMS SHOWING ALL EFFLUENT
STREAMS. INDICATE EACH STREAM WITH A CIRCLED NUMBER USING 101-199 FOR GASEOUS STREAMS,
201-299 FOR LIQUID STREAMS, AND 301-399 FOR SOLID WASTE STREAMS.
ESP
— (101
Flue gas
Bottom
ash slurry
ESP
hopper ash
4. LIST
101
102
103
104
105
106
107
AND DESCRIBE GASEOUS EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
Flue gas
5. LIST
201
202
203
204
205
206
AND DESCRIBE LIQUID EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
Bottom ash slurry
6. LIST
301
302
303
304
305
306
AND DESCRIBE SOLID WASTE EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
ESP hopper ash
7. IF YOU ARE PERFORMING A LEVEL 1 ASSESSMENT, COMPLETE THE IA02-LEVEL 1 FORM FOR EACH EFFLUENT
STREAM LISTED ABOVE. IF YOU ARE PERFORMING A LEVEL 2 ASSESSMENT, COMPLETE THE IA02-LEVEL 2 FORM
FOR EACH EFFLUENT STREAM LISTED ABOVE. '
38
-------
Figure 7(b). Example 2(b) (Continued).
8. LIST SUMS FROM LINE 7, FORMS IA02, IN TABLE BELOW
DEGREE OF HAZARD AND TOXIC UNIT DISCHARGE RATES BY EFFLUENT STREAM
GASEOUS .
STREAM
CODE
101
A
DEGREE OF
HAZARD
HEALTH
BASED
-
4.6E2
B
ECOL.
BASED
-
7.3E2
C
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(mVsec)
2.5E5
D
3.9E5
E
LIQUID
STREAM
CODE
201
F
9. SUM SEPARATELY GASEOUS, LIQUID AND
(I.E.. SUM COLUMNS)
HEALTH-BAJ
GASEOUS (X COL. B) S
LIQUID (I COL. G) S
SOLID WASTE (I COL L) 9
10. SUM SEPARATELY GASEO
LINE 8 (I.E., SUM COLUM
GASEOUS (mVsec)
LIQUID (I/sec)
SOLID WASTE (g/sec
11. NUMBER OF EFFL
GASEOUS
LIQUID
SOLID WASTE
JS, LIQUID AND
NS)
HEALTH-BA
(I COL D)
(I COL. 1)
) (I COL. N)
DEGREE OF
HAZARD
HEALTH
BASED
—
0.063
G
ECOL.
BASED
-
4.1
H
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(I/sec)
4.3
1
279
J
SOLID WASTE STREAM DEGREES
TOTAL DEGREE OF HAZARD
JED ECO
IA 4.6E2 fir
1R 0.063
r 1.3E3
(S.C
(1C
SOLID WASTE STREAM TOXIC U
TOTAL TOXIC UNIT Dl
SED EC(
10A 2.5E5 K
OR 4.3
inr. 2.3E5
(T
SOLID WASTE
STREAM
CODE
301
K
, OF HA;
LOGICAL
OL C) <
OL H) <
,01. M) <
NIT DIS(
SCHARG
DLOGICA
COL E)
COL. J)
COL. 0)
DEGREE OF
HAZARD
HEALTH
BASED
—
1.3E3
L
ECOL.
BASED
—
6.0E4
M
TOXIC UNIT
DISCHARGE RATES
HEALTH ECOL
BASED BASED
(g/sec)
2.3E5 1.1E7
N 0
JARD FROM TABLE AT LINE 8
.-BASED
a*- 7.3E2
»• 4.1
srv 6.0E4
CHARGE RATES FROM TABLE AT
E RATES
L-BASED
IOA- 3.9E5
,nR- 279
inr- 1.1 E7
UENT STREAMS
HA one
11B
11C
one
one
12. LIST POLLUTANT SPECIES KNOWN OR SUSPECTED TO-BE EMITTED FOR WHICH A MATE IS NOT AVAILABLE.
HC, particulates, Zr, Al, As, Zn, NO , SO , Pb
x x
39
-------
SAM/IA WORKSHEET FOR LEVEL 2
Figure 7(c). Example 2(b) (Continued).
Form IA02 Level 2
O
1. SOURCE/CONTROL OPTION p ?
Wall-fired utility boiler/electrostatic precipitator (n = 99%) 8
2.
4.
I
EFFLUENT STREAM
101 Flue gas
CODE # NAME
3. EFFLUE
Q =
COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF
A
POLLUTANT
SPECIES
UNITS
NO,
S0x
CO
HC
Parti cul ate
Al
As
Hg
V
Zn
CATEGORY
—
47
53
42
_
38
49
83
65
81
B
POLLUTANT
CONCEN-
TRATION
ug/m
6.6X105
2. 66x1 O6
4. 49x1 04
l.SxlO3
3.5xl04
l.SxlO5
272
13,9
729
5.72xl03
C
HEALTH
MATE
CONCEN-
TRATION
ug/m
9,000
13,000
40,000
—
__
5,200
2
50
500
4,000
D
ECOLOGICAL
MATE
CONCEN-
TRATION
ug/m3
—
—
1.2xl05
—
—
—
—
10
1
—
F MORE SPACE IS:NEEDED. USE A CONTINUATION SHEET
5. EFFLUENT STREAM
HEALTH MATE BAS
ECOLOGICAL MATE
1 (ENTER HERE AND
DEGREE OF HAZARD „
rn *v rra r» Ra 4.6x10
p|i (>, VAH . r) *>a
BASED (I COL. F) 5b
AT LINE 8, FORM IAC
7.3xl02
1)
6. NUME
POLLL
PAREE
HEALTH
ECOLOG
NT STREAM FLOW RATE
537 mj/sec
(gas = mVsec — liquid = 1
/sec —
solid = g/sec)
FORM FOR SCRATCH WORK)
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
73.3
205
1.12
—
—
34.6
136
0.28
1.46
1.43
1ER OF
JTANTS COM-
) TO MATES
fia 10
CAL 6b
3
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
0.4
—
—
—
—
1.4
729
—
G
N/.F
HEALTH
MATE
EXCEEDED
—
/
/
/
'
/
/
/
H
N/IF
ECOL
MATE
EXCEEDED
—
/
J
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
nP/sec
3.9xl04
l.lxlO5
6x1 02
—
—
l.SxlO4
7.3xl04
1.5xl02
7.8xl02
7.7xl02
(ECOLOGICAL
BASED)
(F i LINE 3)
m^/sec
—
—
2x1 02
—
—
—
—
7.5xl02
3.9xl05
—
7. TOXIC UNIT DISCHARGE SUM
HEALTH MATE BASED (I COL. 1)
ECOLOGICAL MATE BASED (I CO
(ENTER HERE AND AT LINE 8, F(
2.5xl05
7a
, n7h3.9x!05
)RM IA01)
-------
CONTINUATION SHEET FOR ITEM NO. 4, FORM IA02, LEVEL 2 Figure 7(d). Example 2(b) (Continued).
Page 2 / 2
SOURCE/CONTROL 0
PTION Wall-fired utility boiler/electrostatic precipitator (r)=992o) EFFLU
A
POLLUTANT
SPECIES
UNITS
Zr
Pb
CATEGORY
63
46
B
POLLUTANT
CONCEN-
TRATION
yg/m3
5.3xl02
360
C
HEALTH
MATE
CONCEN-
TRATION
ug/m3
5000
150
D
ECOLOGICAL
MATE
CONCEN-
TRATION
ug/m3
__
—
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
o.n
2.4
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
__
—
-
G
N/IF
HEALTH
MATE
EXCEEDED
—
__
/
ENT STRE
_H
V.F
ECOL
MATE
EXCEEDED
—
__
--
:AM NO 101
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
m /sec
56.9
1.3xl03
(ECOLOGICAL
BASED)
(F x LINE 3)
m /sec
_*.
__
-------
SAM/IA WORKSHEET FOR LEVEL 2
Figure 7(e). Example 2(b) (Continued).
Form IA02 Level 2
1. SOURCE/CONTROL OPTION Rage l / -,
Wall -fired utility boiler/electrostatic precipitator (n = 99%)
2.
4.
1
EFFLUENT STREAM 3.
201 Bottom ash (slurry)
CODE # NAME
EFFLUENT STREAM FLOW RATE
Q= 68.2 1/sec
(gas = mVsec — liquid = I/sec — solid = g/sec)
COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF FORM FOR SCRATCH WORK)
A
POLLUTANT
SPECIES
UNITS
Al
As
, -,-^._
Hg 'V-
V
Zn
Zr
Pb
CATEGORY
—
38
49
83
65
81
63
46
B
POLLUTANT
CONCEN-
TRATION
ug/i
3.53xl03
2.14
6x1 O"3
5.75
45
25
1.21
C
HEALTH
MATE
CONCEN-
TRATION
ug/i
8xl04
250
10
2,500
2.5xl04
7.5xl04
250
D
ECOLOGICAL
MATE
CONCEN-
TRATION
ug/i
. 103
50
250
150
102
—
50
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
0.044
9xlO"3
6xlO"4
2.3xlO"3
l.SxlO"3
3.3xlO"4
4.8xlO"3
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
3.53
0.043
2.4xlO"5
3.8xlO"2
0.45
—
2.4xlO"2
G
N/.F
HEALTH
MATE
EXCEEDED
—
H
N/IF
ECOL
MATE
EXCEEDED
—
/
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
1/sec
3.0
0.6
0.04
0.16
0.12
0.02
0.33
(ECOLOGICAL
BASED)
(F x LINE 3)
1/sec
241
2.9
1.6xlO"3
2.6
30.7
—
1.65
F MORE SPACE IS NEEDED, USE A CONTINUATION SHEET
5. EFFLUENT STREAM
HEALTH MATE BAS
ECOLOGICAL MATE
(ENTER HERE AND
DEGREE OF HAZARD
pn (y roi F) ** 0.063
BASED~(S COL. F) 5b
AT LINE 8, FORM IAO
4.1
1)
6. NUME
POLLL
PAREC
HEALTH
ECOLOGI
1ER OF 7. 1
ITANTS COM- ,
) TO MATES
fia 7 E
CAI fih 6 (
'OXIC UNIT DISCHARGE SUM
HEALTH MATE BASED (I COL 1)
ICOLOGICAL MATE BASED (I CO
ENTER HERE AND AT LINE 8, F(
7a 4.3
i h?h 279
)RM IA01)
-------
SAM/IA WORKSHEET FOR LEVEL 2
Figure 7(f). Example 2(b) (Concluded)
Form IA02 Level 2
1. SOURCE/CONTROL OPTION
Wall -fired utility boiler/electrostatic precipitator (n = 99%)
2.
'4.
I
EFFLUENT STREAM 3.
301 ESP hopper ash
CODE tt NAME
EFFLUE
Q =
COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF
A
POLLUTANT
SPECIES
UNITS
Al
As
Hg
V
Zn
Zr
Pb
CATEGORY
—
38
49
'-•" 83
65
81
63
46
B
POLLUTANT
CONCEN-
TRATION
vig/g
7. 74x1 O4
157
0.22
280
3.3xl03
458
148
C
HEALTH
MATE
CONCEN-
TRATION
ug/g
160
0.5
0.02
5
50
15
0.5
D
ECOLOGICAL
MATE
CONCEN-
TRATION
pg/g
.2
0.1
0.5
0.3
0.2
—
0.1
Page 1 / 1
NT STREAM FLOW RATE
186 g/$eq
(gas = mVsec — liquid = I/sec — solid = g/sec)
FORM FOR SCRATCH WORK)
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
4.8xl02
314
11
56
66
30.5
296
f MORE SPACE IS NEEDED, USE A CONTINUATION SHEET
5. EFFLUENT STREAM
HEALTH MATE BAS
ECOLOGICAL MATE
! (ENTER HERE AND
DEGREE OF HAZARD 3
;EH
-------
third effluent stream — the precipitator bottom ash. The trace element dis-
tribution used is from Reference 6.
The final example (2c) retains the precipitator and adds low-excess-
air (LEA) firing. It is shown in Figures 8(a) through 8(g). LEA reduces
NOY by about 20 percent but simultaneously results in an increase in CO
/\
emissions. The CO level, however, is below the MATE for CO. The net result
is a reduction in the rate of discharge of toxic units to the air.
The following table summarizes the three cases.
Case
Baseline
ESP
ESP and LEA
Total Health-Based TUDR
Gas
4.2 x 105
2.5 x 10s
2.4 x 105
Liquid Solid
4.3
4.3
4.3
—
2.3 x 105
2.3 x 10s
44
-------
Figure 8(a). Example 2(c).
SAM/IA SUMMARY SHEET
Form IA01
1. SOURCE AND APPLICABLE CONTROL OPTIONS
Wall-fired utility boiler/bit, coal fuel/electrostatic precipitator (n 99%)/
low excess air firing.
2. PROCESS THROUGHPUT OR CAPACITY 1.1 x 10 J/S6C fuel input (1110 MW)
3. USE THIS SPACE TO SKETCH A BLOCK DIAGRAM OF THE SOURCE AND CONTROL ITEMS SHOWING ALL EFFLUENT
STREAMS. INDICATE EACH STREAM WITH A CIRCLED NUMBER USING 101-199 FOR GASEOUS STREAMS,
201-299 FOR LIQUID STREAMS, AND 301-399 FOR SOLID WASTE STREAMS.
ESP
(tt
Flue gas
Bottom
ash slurry
ESP
hopper ash
4. LIST
101
102
103
104
105
106
107
AND DESCRIBE GASEOUS EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
Flue gas
5. LIST
201
202
203
204
205
206
AND DESCRIBE LIQUID EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
Bottom ash slurry
6. LIST
301
302
303
304
305
306
AND DESCRIBE SOLID WASTE EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
ESP hopper ash
7. IF YOU ARE PERFORMING A LEVEL 1 ASSESSMENT, COMPLETE THE IA02-LEVEL 1 FORM FOR EACH EFFLUENT
STREAM LISTED ABOVE. IF YOU ARE PERFORMING A LEVEL 2 ASSESSMENT. COMPLETE THE IA02-LEVEL 2 FORM
FOR EACH EFFLUENT STREAM LISTED ABOVE.
45
-------
Figure 8(b). Example 2(c) (Continued).
8. LIST SUMS FROM LINE 7,
FORMS IA02, IN TABLE BELOW
DEGREE OF HAZARD AND TOXIC UNIT DISCHARGE RATES BY EFFLUENT STREAM
GASEOUS
STREAM
CODE
101
A
DEGREE OF
HAZARD
HEALTH
BASED
-
450
B
ECOL
BASED
—
749
C
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(mVsec)
2.4E5
D
3.9E5
E
LIQUID
STREAM
CODE
201
F
9. SUM SEPARATELY GASEOUS, LIQUID AND «
(I.E., SUM COLUMNS)
HEALTH-BAS
GASEOUS (l COL B) 9
LIQUID (I COL G) 9
SOLID WASTE (I COL L) 9
10. SUM SEPARATELY GASEOl
LINE 8 (I.E., SUM COLUMI
GASEOUS (mVsec)
LIQUID (I/sec)
SOLID WASTE (g/sec)
11. NUMBER OF EFFLI
GASEOUS
LIQUID
SOLID WASTE
JS. LIQUJD AND
MS)
HEALTH-BA
(S COL. D)
(I. COL. 1) 1
(I COL. N)
DEGREE OF
HAZARD
HEALTH
BASED
—
0.063
G
ECOL.
BASED
—
4.1
H
TOXIC UNIT
DISCHARGE RATES
,' HEALTH
BASED
ECOL.
BASED
(I/sec)
4.3
1
279
J
50LID WASTE STREAM DEGREES
TOTAL DEGREE OF HAZARD
,ED ECO
A 450 rx r
R 0.063
r 1.3E3
ac
(zc
SOLID WASTE STREAM TOXIC U
TOTAL TOXIC UNIT DI5
SED ECC
inA 2.4E5 rr i
OR 4.3
inn 2.3E5
(T
(I
SOLID WASTE
STREAM
CODE
301
K
OF HA2
LOGICAL
OL. C) i
OL H) <
9L M) <
MIT DISC
5CHARG
)LOGICA
COL. E)
COL. J)
COL. 0)
DEGREE OF
HAZARD
HEALTH
BASED
—
1.3E3
L
ECOL
BASED
—
6.0E4
M
TOXIC UNIT
DISCHARGE RATES
HEALTH ECOL.
BASED BASED
(g/sec)
2.3E5 1.1E7.
N 0
!ARD FROM TABLE AT LINE 8
-BASED
JA- 749
m- 4.1
ir.- 6.0E4
:HARGE RATES FROM TABLE AT
E RATES
L-BASED
10A' 3.9E5
lOR' 279
inr 1.1 E7 ."
JENT STREAMS
HA one
lie
11C
one
one
12. LIST POLLUTANT SPECIES KNOWN OR SUSPECTED TO BE EMITTED FOR WHICH A MATE IS NOT AVAILABLE.
HC, participates, Zr, Al, As, Zn, Pb, NOX> SOX
46
-------
SAM/IA WORKSHEET FOR LEVEL 2
Figure 8(c). Example 2(c) (Continued)
Form IA02 Level 2
L SOURCE/CONTROL OPTION Page l /
Wall-fired utility boiler/electrostatic precipitator (n = 99%)/LEA firing
2. EFFLUENT STREAM 3.
101 Flue qas
CODE* NAME
EFFLUENT STREAM FLOW RATE
Q = 524 m3/S
(gas = rrP/sec — liquid = 1
/sec — solid = g/sec
)
4. COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF FORM FOR SCRATCH WORK)
1
A
POLLUTANT
SPECIES
UNITS
NOX
S0x
GO
HC
Parti cul ate
Al
As
Hq
V
Zn
CATEGORY
—
47
53
42
' ..
«•
38
49
83
65
81
B
POLLUTANT
CONCEN-
TRATION
/ 3
ug/m
5V2xl05
2. 73x1 O6
9.2xl04
1800
3.6xl04
l.SxlO5
279
14,3
747
5.9xl03
C
HEALTH
MATE
CONCEN-
TRATION
vig/m
9000
13000
40000
im n
««
5200
2
50
500
4000
D
ECOLOGICAL
MATE
CONCEN-
TRATION
vtg/m
— —
• —
120000
mt mm
.»••
«.«
M ^
10
1
— —
E
DEGREE OF
HAZARD
(HEALTH)
. (B/O
58
210
2.31
^mf
— —
34.6
139.5
0.286
1.49
1.48
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
„_
- —
0.77
fm „.
__
...
^^
1.43
747
_._
G
V/IF
HEALTH
MATE
EXCEEDED
—
/
/
/
MhM
*._
v/
^
__
/
/
H
ECOL
MATE
EXCEEDED
__
__
—
_^
__
—
mf^
J
it
__
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E * LINE 3)
m3/sec
3x1 04
l.lxlO5
1210.
_.
__
1.8xl04
7.3xl04
1.5xl02
783
773
(ECOLOGICAL
BASED)
(F i LINE 3)
m3/sec
—
--
4x1 02
__
—
—
__
749
3.9xl05
—
P MORE SPACE IS NEEDED, USE A CONTINUATION SHEET
5. EFFLUENT STREAM
HEALTH MATE BAJ
ECOLOGICAL MATE
((ENTER HERE AND
DEGREE OF HAZARD
5ED (I COL. E) 5a 450
BASED (I COL. F) 5t
AT LINE 8, FORM IAC
749
>D
6. NUMB
POLLL
PAREC
HEALTH
ECOLOGI
IER OF 7. T
ITANTS COM- ,
) TO MATES
fia 10 E
PJ\I fih 3' (
OXIC UNIT DISCHARGE SUM
IEALTH MATE BASED (£ COL. 1)
COLOGICAL MATE BASED (I CO
ENTER HERE AND AT LINE 8, FC
7a 2.4 x 105
h7h 3.9xl05
RM IA01)
-------
CONTINUATION SHEET FOR ITEM NO. 4. FORM IA02. LEVEL 2 Figure 8(d). Example 2(c) (Continued).
Page 2 / 2
SOURCE/CONTROL 0
p-rinw Wall-fired utility boiler/ESP (n=99%)/LEA firing FFFIII
A
POLLUTANT
SPECIES
UNITS
Zr
Pb
CATEGORY
63
46
• — .
B
POLLUTANT
CONCEN-
TRATION
yg/m3
542
369
C
HEALTH
MATE
CONCEN-
TRATION
ug/m3
5000
150
D
ECOLOGICAL
MATE
CONCEN-
TRATION
ug/m3
—
—
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
0.11
2.46
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
--
—
G
>/IF
HEALTH
MATE
EXCEEDED
—
__
•
ENT STRE
H
N/.F
ECOL
MATE
EXCEEDED
__
—
AM NO 101
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
m3/sec
57
1.3xl03
(ECOLOGICAL
BASED)
(F x LINE 3)
m3/sec
__
--
•
CD
-------
Figure 8(e). Example 2(c) (Continued),
NOTES
ASSUMPTIONS
LIST ALL ASSUMPTIONS MADE REGARDING FLOW RATE, EMISSION FACTORS AND MATE VALUES.
Assume low excess air firing operates at 117-percent theoretical air compared to
120-percent for baseline operation. The flowrate is:
(537) = 524 m3/s
(This is a 15-percent reduction in excess air.)
-------
Ul
O
SAM/IA WORKSHEET FOR LEVEL 2 Fiqure 8(f).' Example 2(c) (Continued). Form IA02 Level 2
1. SOURCE/CONTROL OPTION Page 1 / 1
Wall-fired utility boiler/ESP (n = 99%)/LEA firing
2.
4.
i
EFFLUENT STREAM 3.
201 Bottom ash (slurry)
CODE # NAME
EFFLUENT STREAM FLOW RATE
Q = 68.2 I/Sec
(gas = mVsec — liquid = I/sec — solid = g/sec)
COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF FORM
A
POLLUTANT
SPECIES
UNITS
Al
As
Hg
V
Zn
Zr
Pb
CATEGORY
—
38
49
83
65
81
63
46
B
POLLUTANT
CONCEN-
TRATION
yg/i
3.53xl03
2.14
6xlO"3
5.75
45
25
1.21
C
HEALTH
MATE
CONCEN-
TRATION
ug/i
8xl04
250
10
2,500
2.5xl04
7.5xl04
250
D
ECOLOGICAL
MATE
CONCEN-
TRATION
ug/i
. 103
50
250
150
102
—
50
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
0.044
9x1 O"3
6x1 O"4
2.3xlO"3
l.SxlO"3
3.3xlO"4
4.8xlO"3
FOR SCRATCH WORK)
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
3.53
0.043
2.4xlO"5
3.8xlO"2
0.45
—
2.4xlO"2
G
N/IF
HEALTH
MATE
EXCEEDED
—
H
N/.F
ECOL
MATE
EXCEEDED
—
V
—
—
—
—
—
—
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
1/sec
3.0
0.6
0.04
0.16
0.12
0.02
0.33
(ECOLOGICAL
BASED)
(F i LINE 3)
1/sec
241
2.9
1.6xlO"3
2.6
30.7
—
1.65
F MORE SPACE IS NEEDED. USE A CONTINUATION SHEET
5. EFFLUENT STREAM
HEALTH MATE BAS
ECOLOGICAL MATE
i (ENTER HERE AND
DEGREE OF HAZARD . ...
(J.Ubo
pn_(y r.ni F) R»
BASED (I COL F) 5b
AT LINE 8, FORM IAC
4.1
1)
6. NUME
POLLL
- PAREt
HEALTH
ECOLOG
1ER OF 7. TOXIC UNIT DISCHARGE SUM
'TAi'T?.22'1" HEALTH MATE BASED (S COL. 1)
) TO MATES
fi, 7 ECOLOGICAL MATE BASED (I CO
4.3
7a
i i)7h 279 '
rA, fih 6 (ENTER HERE AND AT LINE 8, FORM IA01)
-------
SAM/IA WORKSHEET FOR LEVEL 2 Figure 8(g). Example 2(c) (Concluded)
Form IA02 Level 2
1. SOURCE/CONTROL OPTION Rage l / 1
Wall-fired utility boiler/electrostatic precipitator (n = 9950/LEA
2.
4.
1
EFFLUENT STREAM 3.
301 ESP hopper ash
CODE* NAME
EFFLUENT STREAM FLOW RATE
n= 186 g/sec
(gas = mVsec — liquid = 1
/sec — solid - g/sec
)
COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF FORM FOR SCRATCH WORK)
A
POLLUTANT
SPECIES
UNITS
Al
As
Hg
V
Zn
Zr
Pb
CATEGORY
—
38
49
83
65
81
63
46
B
POLLUTANT
CONCEN-
TRATION
ug/g
7. 74x1 O4
157
0.22
280
3.3xl03
458
148
c
HEALTH
MATE
CONCEN-
TRATION
ug/g
160
0.5
0.02
5
50
15
0.5
D
ECOLOGICAL
MATE
CONCEN-
TRATION
ug/g
. 2
0.1
0.5
0.3
0.2
—
0.1
E
DEGREE OF
HAZARD
(HEALTH)
.(B/C)
4.8xl02
314
11
56
66
30.5
296
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
3.9xl04
1.6xl03
0.44
933
1.7xl04
—
1.5xl03
G
N/IF
HEALTH
MATE
EXCEEDED
—
/
v/
/
S
/
/
/
H
N/.F
ECOL
MATE
EXCEEDED
—
/
/
/
/
/
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E « LINE 3)
g/sec
9x1 04
5.8xl04
2x1 03
104
1.2xl04
5.7xl03
5.5xl04
(ECOLOGICAL
BASED)
(F K LINE 3)
g/sec
7.2xl06
2.9xl05
82
1.7xl05
S.lxlO6
—
2.8xl05
F MORE SPACE IS NEEDED, USE A CONTINUATION SHEET
5, EFFLUENT STREAM
HEALTH MATE BAS
ECOLOGICAL MATE
1 (ENTER HERE AND
DEGREE OF HAZARD 3
?FD {>; COI F) 5?> 1.3x10
BASED (I COL. F) 5t
AT LINE 8, FORM (AC
, 6xl04
)1)
6. NUME
POLLL
PAREC
HEALTH
ECOLOG
1ER OF 7. T
JTANTS COM- ,
) TO MATES
fia 7 E
rAi fih 6 (
OXIC UNIT DISCHARGE SUM
IEALTH MATE BASED <£ COL 1)
COLOGICAL MATE BASED (£ CO
ENTER HERE AND AT LINE 8, FC
2.3xl05
7a
l)7h 1Jxl°
RM IA01)
-------
3.4 EXAMPLE 3 - FLAT GLASS PROCESSING
The third example is a 500-tonne per day flat glass plant. The
primary emissions are to the air and are from the glass melting oven and
the annealing lehr. As in the previous example, this example is included
to clarify the use of the SAM/IA method rather than to perform an accurate
analysis of a process. Consequently, some concentrations have been
approximated where data were lacking. Results are shown in Figures 9(a)
through 9(f).
52
-------
Figure 9(a). Example 3
SAM/IA SUMMARY SHEET
Form IA01
1. SOURCE AND APPLICABLE CONTROL OPTIONS
Flat glass manufacturing process (gas-fired) air emissions
2. PROCESS THROUGHPUT OR CAPACITY (500 tonnes/day) 17 kg/s
3. USE THIS SPACE TO SKETCH A BLOCK DIAGRAM OF THE SOURCE AND CONTROL ITEMS SHOWING ALL EFFLUENT
STREAMS. INDICATE EACH STREAM WITH A CIRCLED NUMBER USING 101-199 FOR GASEOUS STREAMS,
201-299 FOR LIQUID STREAMS, AND 301-399 FOR SOLID WASTE STREAMS.
Raw
materials
Flue gas
Glass
melting
oven
Annealing
lehrs
Flue gas
••-Glass
4. LIST
101
102
103
104
105
106
107
AND DESCRIBE GASEOUS EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
Melting oven flue gas
Annealing lehr flue gas
5. LIST AND DESCRIBE LIQUID EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
201
202
203 ,
204
205
206
6. LIST AND DESCRIBE SOLID WASTE EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
301
302
303
304
305
306
7. IF YOU ARE PERFORMING A LEVEL 1 ASSESSMENT, COMPLETE THE IA02-LEVEL 1 FORM FOR EACH EFFLUENT
STREAM LISTED ABOVE. IF YOU ARE PERFORMING AlEVEL 2 ASSESSMENT, COMPLETE THE IA02-LEVEL 2 FORM
FOR EACH EFFLUENT STREAM LISTED ABOVE.
53
-------
Figure 9(b). Example 3 (Continued).
8. LIST SUMS FROM LINE 7,
FORMS IA02, IN TABLE BELOW
DEGREE OF HAZARD AND TOXIC UNIT DISCHARGE RATES BY EFFLUENT STREAM
GASEOUS .
STREAM
CODE
101
102
A
DEGREE OF
HAZARD
HEALTH
BASED
-
1.1E4
102
B
ECOL.
BASED
-
0.04
1
C
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL
BASED
(mVsec)
8.6E5
31.
D
2.9
0.3
E
LIQUID
STREAM
CODE
F
9. SUM SEPARATELY GASEOUS, LIQUID AND <
, (I.E., SUM COLUMNS)
HEALTH-BAS
GASEOUS (I COL B) 9
LIQUID (I COL. G) 9
SOLID WASTE (i COL L) 9
10. SUM SEPARATELY GASEOUS, LIQUID AND
LINE 8 (I.E., SUM COLUMNS)
HEALTH-BA
GASEOUS (mVsec) (I COL D)
LIQUID (I/sec) (I COL 1) 1
SOLID WASTE (g/sec) (I COL N)
11. NUMBER OF EFFL
GASEOUS
LIQUID
SOLID WASTE
DEGREE OF
HAZARD
HEALTH
BASED
—
G
ECOL.
BASED
—
H
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(I/sec)
1
J
JOLID WASTE STREAM DEGREES
TOTAL DEGREE OF HAZARD
>ED ECO
A 1.1E4 rsr
R
r.
(1C
(SC
SOLID WASTE STREAM TOXIC Ul
TOTAL TOXIC UNIT DIJ
SED ECC
IOA 8.6E5
np
inr.
(J (
SOLID WASTE
STREAM
CODE
K
OF HA;
LOGICAL
OL. C) <
OL H) <
9L. M) <
MIT DISC
5CHARG
)LOGICA
:OL E)
:OL j>
(I COL. 0)
DEGREE OF
HAZARD
HEALTH
BASED
—
L
ECOL.
BASED
-
M
TOXIC UNIT
DISCHARGE RATES
HEALTH ECOL
BASED BASED
(g/sec)
N 0
!ARD FROM TABLE AT LINE 8
.-BASED
JA- 1
»r(
CHARGE RATES FROM TABLE AT
E RATES
L-BASED
•3 O
IDA' & • £•
10R-
! i
IOC' i i
JENT STREAMS
11A 2
11B
11C
12. LIST POLLUTANT SPECIES KNOWN OR SUSPECTED TO BE EMITTED FOR WHICH A MATE IS NOT AVAILABLE.
HC, parti cul ate, S03, Cr, Si, Mn, Ca, F", NOX, SOX
54 - -
-------
SAM/IA WORKSHEET FOR LEVEL 2
Figure 9(c). Example 3 (Continued),
Form IA02 Level 2
1. SOURCE/CONTROL OPTION Rage l / 2
Flat glass manufacturing process/gas fired
2.
4.
1
EFFLUENT STREAM 3.
101 Melting oven flue gas
CODE* NAME
EFFLUENT STREAM FLOW RATE
o = 76 m3/sec
(gas = mVsec — liquid =
/sec — solid = g/sec
)
COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF FORM FOR SCRATCH WORK)
A
POLLUTANT
SPECIES
UNITS
NOX
S0x
CO
HC
Parti oil ate
Fluoride
Ca
Mn
Si
CATEGORY
—
47
53
42
—
—
56
34
71
43
B
POLLUTANT
CONCEN-
TRATION
ug/m3
8.9xl05
3.6xl05
4.5xl03
8.9xl03
2.2xl05
22.3
4.5xl04
6.7xl03
3.4xl04
C
HEALTH
MATE
CONCEN-
TRATION
yg/m3
9,000
13,000
40,000
—
—
2,500
16,000
5,000
10,000
D
ECOLOGICAL
MATE
CONCEN-
TRATION
ug/m3
—
—
120,000
—
—
—
—
—
—
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
99
27.7
0.11
—
—
0.009
2.8
1.34
3.4
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
0.038
—
—
—
—
—
—
G
N/IF
HEALTH
MATE
EXCEEDED
—
/
/
/
/
/
H
V/IF
ECOL
MATE
EXCEEDED
—
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
m /sec
7.5xl03
2.1xl03
8.6
—
—
0.68
214
102
2.6x10*
(ECOLOGICAL
BASED)
(F i LINE 3)
m /sec
—
—
2.9
—
—
—
—
—
—
f MORE SPACE IS NEEDED, USE A CONTINUATION SHEET
5. EFFLUENT STREAM
HEALTH MATE BAJ
ECOLOGICAL MATE
i (ENTER HERE AND
DEGREE OF HAZARD 4
5FD PL rO| F) Ra 1>lxl°
BASED (X COL. F) 5b
AT LINE 8, FORM IAC
0.04
U)
6. NUME
POLLL
PAREt
HEALTH
ECOLOG
IER OF 7. 1
JTANTS COM- ,
) TO MATES
fia 8 E
rAi fih 1 (
OXIC UNIT DISCHARGE SUM
1EALTH MATE BASED (I COL. 1)
COLOGICAL MATE BASED (X CO
ENTER HERE AND AT LINE 8, FC
8.6xl05
7a
l)7h 2.9
»RM IA01)
in
en
-------
CONTINUATION SHEET FOR ITEM NO. 4, FORM IA02, LEVEL 2 Figure 9(d). Example 3 (Continued).
Page 2
SOURCE/CONTROL 0
PTION Hat glass manufacturing process/gas fired FFFIU
A
POLLUTANT
SPECIES
UNITS
Cr
•
•*-._ .. ,'ifi
1 ... . -* ^
CATEGORY
—
68
——
•— —
B
POLLUTANT
CONCEN-
TRATION
l.lxlO4
c
HEALTH
MATE
CONCEN-
TRATION
1
D
ECOLOGICAL
MATE
CONCEN-
TRATION
••«
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
l.lxlO4
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
__
G
V.F
HEALTH
MATE
EXCEEDED
....
/
ENT STRE
H
V/IF
ECOL
MATE
EXCEEDED
„
AM NO 101
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
8.5xl05
(ECOLOGICAL
BASED)
(F x LINE 3)
•-
-------
SAM/IA WORKSHEET FOR LEVEL 2
Figure 9(e). Example 3 (Continued)
Form IA02 Level 2
1. SOURCE/CONTROL OPTION Page l / ]
Flat glass plant/gas fired
2.
4.
EFFLUENT STREAM 3.
102 Annealing lehr flue gas
EFFLUENT STREAM FLOW RATE
n _ 0.304 m3/sec
CODE # NAME (gas =
mVsec — liquid = 1
/sec —
solid = g/sec)
COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF FORM FOR SCRATCH WORK)
A
POLLUTANT
SPECIES
UNITS
NOX
CO
CATEGORY
—
47
42
B
POLLUTANT
CONCEN-
TRATION
wg/m
8.9xl05
1.2X105"
c
HEALTH
MATE
CONCEN-
TRATION
yg/m
9,000
40,000
D
ECOLOGICAL
MATE
CONCEN-
TRATION
ug/m3
—
120,000
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
98.9
3
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)_
1
G
V.F
HEALTH
MATE
EXCEEDED
—
/
/
H
N/IF
ECOL
MATE
EXCEEDED
—
/
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
m3/sec
30
0.9
(ECOLOGICAL
BASED)
(F x LINE 3)
nvVsec
—
0.3
f MORE SPACE IS NEEDED, USE A CONTINUATION SHEET
5. EFFLUENT STREAM
HEALTH MATE BA£
ECOLOGICAL MATE
(ENTER HERE AND
DEGREE OF HAZARD
JED (X COI, E) 5a 102
BASED (I COL. F) 5b
AT LINE 8, FORM IAC
1
ID
6. NUME
POLLL
PAREC
HEALTH
ECOLOGI
ER OF 7. T
TANTS COM- ,
) TO MATES
fia 2 E
r.Ai fih 1 (
OXIC UNIT DISCHARGE SUM
EALTH MATE BASED (S COL. 1)
COLOGICAL MATE BASED (X CO
ENTER HERE AND AT LINE 8, FC
31
7a
l)7h °'3
RM IA01)
U1
-------
Figure 9(f). Example 3 (Concluded).
NOTES
Calculation of flue gas flowrate:
Flowrate is unknown; theoretical heat to melt 1 kg of raw materials is 1.85
MJ. For an efficiency of 20 percent and a capacity of 500 x 103 kg/day, the oven
fuel input must be 160 MW. A 110
flowrate in the gas oven is about
fuel input must be 160 MW. A 110-MW powerplant has a flowrate of 57 m /s, so the
Q = (57) x = 76 m3/s
ASSUMPTIONS
LIST ALL ASSUMPTIONS MADE REGARDING FLOW RATE, EMISSION FACTORS AND MATE VALUES.
58
-------
3.5 EXAMPLE 4 - BYPRODUCT COKE OVEN
The fourth example shows the effect of waste water treatment on
liquid effluent from a coke oven in Figures 10(a) through 10(f). This
example is included to show the use of SAM/IA to evaluate TUDRs in a single
stream before and after treatment. Consequently, only the raw effluent
stream and the "cleaned effluent stream" are considered and other effluent
streams are neglected.
Pollutant concentrations in the effluent streams were known directly
from sampling data (Reference 7) and did not have to be calculated from
emission factors.
The result of the analysis shows that the waste water treatment re-
duces the health based TUDR sum from 3.2 x 10s to 4.8 x 10* I/sec, an 85-
percent reduction.
59
-------
Figure 10(a). Example 4.
SAM/IA SUMMARY SHEET
Form IA01
1. SOURCE AND APPLICABLE CONTROL OPTIONS
Byproduct coke oven "C"/liquid waste/untreated
2. PROCESS THROUGHPUT OR CAPACITY 5400 tonnes/day
3. USE THIS SPACE TO SKETCH A BLOCK DIAGRAM OF THE SOURCE AND CONTROL ITEMS SHOWING ALL EFFLUENT
STREAMS. INDICATE EACH STREAM WITH A CIRCLED NUMBER USING 101-199 FOR GASEOUS STREAMS,
201-299 FOR LIQUID STREAMS, AND 301-399 FOR SOLID WASTE STREAMS.
Raw waste
stream
4. LIST AND DESCRIBE GASEOUS EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
101
102
103
104
105 :
106
107
5. LIST
201
202
203
204
205
206
AND DESCRIBE LIQUID EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
Raw waste stream
6. LIST AND DESCRIBE SOLID WASTE EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
301
302
303
304
305
306
7. IF YOU ARE PERFORMING A LEVEL 1 ASSESSMENT, COMPLETE THE IA02-LEVEL 1 FORM FOR EACH EFFLUENT
STREAM LISTED ABOVE. IF YOU ARE PERFORMING A LEVEL 2 ASSESSMENT. COMPLETE THE IA02-LEVEL 2 FORM
FOR EACH EFFLUENT STREAM LISTED ABOVE.
_ .
-------
Figure 10(b). Example 4 (Continued).
8. LIST SUMS FROM LINE 7, FORMS IA02, IN TABLE BELOW
DEGREE OF HAZARD AND TOXIC UNIT DISCHARGE RATES BY EFFLUENT STREAM
GASEOUS
STREAM
CODE
A
DEGREE OF
HAZARD
HEALTH
BASED
—
B
ECOL.
BASED
-
c
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(mVsec)
D
E
LIQUID
STREAM
CODE
201
F
9. SUM SEPARATELY GASEOUS. LIQUID AND
(I.E., SUM COLUMNS)
HEALTH-BA!
GASEOUS (I COL B) S
LIQUID (I COL G) £
SOLID WASTE (I COL L) 9
10. SUM SEPARATELY GASEO
LINE 8 (I.E., SUM COLUM
GASEOUS (mVsec)
LIQUID (I/sec)
SOLID WASTE (g/sec
11. NUMBER OF EFFL
GASEOUS
LIQUID
SOLID WASTE
JS, LIQUID AND
MS)
HEALTH-B/i
(I COL D)
(I COL. 1)
) (X COL. N)
DEGREE OF
HAZARD
HEALTH
BASED
—
1.9E5
G
ECOL.
BASED
—
1.5E5
H
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(I/sec)
1.8E6
1
1.5E6
J
SOLID WASTE STREAM DEGREES
TOTAL DEGREE OF HAZARD
5ED ECO
>A (*C
>R 1.9 X 105
r.
(1C
(1C
SOLID WASTE STREAM TOXIC U
TOTAL TOXIC UNIT Dl
iSED EC(
10A rz
nR l.SxlO6
inn
(T
SOLID WASTE
STREAM
CODE
K
OF HA,
LOGICA1
OL. C)
OL. H)
OL M)
NIT DIS(
SCHARG
DLOGIC/
COL E)
COL. J)
COL. 0)
DEGREE OF
HAZARD
HEALTH
BASED
—
L
ECOL
BASED
—
M
TOXK": UNIT
DISCHARGE RATES
HEALTH ECOL
BASED BASED
(g/sec)
N 0
ZARD FROM TABLE AT LINE 8
.-BASED
aa-
3R- 1.5 x in5
or-
:HARGE RATES FROM TABLE AT
E RATES
vL-BASED
inA-
inR- 1.5X106
me1
UENT STREAMS
11A
11B
11C
12. LIST POLLUTANT SPECIES
sulfide
one
KNOWN OR SUSPECTED TO BE EMITTED FOR WHICH A MATE IS NOT AVAILABLE,
61
-------
SAM/IA WORKSHEET FOR LEVEL 2 Figure 10(c). Example 4 (Continued)
Form IA02 Level 2
1. SOURCE/CONTROL OPTION
Byproduct coke oven raw waste stream
2.
4.
I
EFFLUENT STREAM 3.
201 Raw waste load
CODE # NAME
EFFLUE
Q =
COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF
A
POLLUTANT
SPECIES
UNITS
Ammoni a
Cyanide
Phenol
Sulfide
CATEGORY
—
47
47
ISA
53
B
POLLUTANT
CONCEN-
TRATION
yg/i
7,330,000
91,000
910,000
197,000
c
HEALTH
MATE
CONCEN-
TRATION
U9/1
2,500
500
5
—
D
ECOLOGICAL
MATE
CONCEN-
TRATION
yg/1
50
25
500
—
Page 1 / 1
NT STREAM FLOW RATE
9.7 1/sec
(gas = mVsec — liquid = I/sec — solid = g/sec)
FORM FOR SCRATCH WORK)
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
2,932
182
182,000
—
F MORE SPACE IS NEEDED, USE A CONTINUATION SHEET
5. EFFLUENT STREAM
HEALTH MATE BAS
ECOLOGICAL MATE
i (ENTER HERE AND
DEGREE OF HAZARD g
FO (V (XV F) 5a 1.9x10
BASED (I COL. F) 5b
AT LINE 8, FORM IAC
1.5xl05
l)
6. NUME
POLLL
PAREC
HEALTH
ECOLOG
JER OF
JTANTS COM-
) TO MATES
fia 3
rAi fih 3
F
DEGREE OF
HAZARD
(ECOLOGICAL)
(B/D)
146,600
3,640
1,820
—
G
V/IF
HEALTH
MATE
EXCEEDED
—
/
/
/
H
N/.F
ECOL
MATE
EXCEEDED
—
/
/
•
1
J
TOXIC UNIT DISCHARGE RATE
(HEALTH
BASED)
(E x LINE 3)
1/sec
2.8xl05
l.SxlO3
l.SxlO6
—
(ECOLOGICAL
BASED)
(F i LINE 3)
1/sec
1.4xl06
3.5xl04
l.SxlO4
—
7. TOXIC UNIT DISCHARGE SUM
HEALTH MATE BASED (S COL. 1)
ECOLOGICAL MATE BASED (£ CO
(ENTER HERE AND AT LINE 8, F(
l.SxlO6
7a
1 5x10^
1 l)7h '-bXIU
DRM IA01)
ro
-------
Figure 10(d). Example 4 (Continued),
SAM/IA SUMMARY SHEET
Form IA01
1. SOURCE AND APPLICABLE CONTROL OPTIONS
Byproduct coke oven "C'Vliquid waste - after treatment
2. PROCESS THROUGHPUT OR CAPACITY
5400 tonnes/day
3. USE THIS SPACE TO SKETCH A BLOCK DIAGRAM OF THE SOURCE AND CONTROL ITEMS SHOWING ALL EFFLUENT
STREAMS. INDICATE EACH STREAM WITH A CIRCLED NUMBER USING 101-199 FOR GASEOUS STREAMS,
201-299 FOR LIQUID STREAMS, AND 301-399 FOR SOLID WASTE STREAMS.
Coke „
Oven
-
Waste ^-^
treatment »- (|oj)
plant
Treated
waste
4. LIST AND DESCRIBE GASEOUS EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
101
109 '
103
104
10R
lOfi
107
5. LIST AND DESCRIBE LIQUID EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
901 Treated effluent discharge
909
904
90S
90fi
6. LIST AND DESCRIBE SOLID WASTE EFFLUENT STREAMS USING RELEVANT NUMBERS FROM STEP 3.
301
309
304
30K
7. IF YOU ARE PERFORMING A LEVEL 1 ASSESSMENT, COMPLETE THE IA02-LEVEL 1 FORM FOR EACH EFaUENT
STREAM LISTED ABOVE. IF YOU ARE PERFORMING A LEVEL 2 ASSESSMENT, COMPLETE THE IA02-LEVEL 2 FORM
FOR EACH EFFLUENT STREAM LISTED ABOVE.
63
-------
Figure 10(e). Example 4 (Continued).
8. LIST SUMS FROM LINE 7,
FORMS IA02, IN TABLE BELOW
/
DEGREE OF HAZARD AND TOXIC UNIT DISCHARGE RATES BY EFFLUENT STREAM
GASEOUS
STREAM
CODE
A
DEGREE OF
HAZARD
HEALTH
BASED
—
B
ECOL
BASED
-
c
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(mVsec)
D
E
LIQUID
STREAM
CODE
201
F
9. SUM SEPARATELY GASEOUS. LIQUID AND i
(I.E., SUM COLUMNS)
HEALTH-BAS
GASEOUS a COL B) S
LIQUID (I COL G) S
SOLID WASTE (I COL L) 9
10. SUM SEPARATELY GASEOl
LINE 8 (I.E., SUM COLUMI
GASEOUS (mVsec)
LIQUID (I/sec)
SOLID WASTE (g/sec,
11. NUMBER OF EFFLI
GASEOUS
LIQUID
SOLID WASTE
JS, LIQUID AND
>JS)
HEALTH-BA
(I COL. D)
(1 COL 1) ]
I (I COL. N)
DEGREE OF
HAZARD
HEALTH
BASED
—
3.6E4
G
ECOL.
BASED
—
1.4E4
H
TOXIC UNIT
DISCHARGE RATES
HEALTH
BASED
ECOL.
BASED
(I/sec)
3.5E5
1
1.3E5
J
SOLID WASTE STREAM DEGREES
TOTAL DEGREE OF HAZARD
!ED ECO
A fir
R 3.6E4
r.
ac
(ZC
SOLID WASTE STREAM TOXIC U
TOTAL TOXIC UNIT DIJ
SED ECC
inA tr i
OR 3.5E5
inr
(y
(I
SOLID WASTE
STREAM
CODE
K
OF HA;
LOGICAL
OL. C) <
OL. H) <
OL M) <
NIT DISC
5CHARG
)LOGICA
SOL. E)
COL. J)
COL. 0)
DEGREE OF
HAZARD
HEALTH
BASED
—
L
ECOL.
BASED
—
M
TOXIC UNIT
DISCHARGE RATES
HEALTH ECOL
BASED BASED
(g/sec)
N 0
ttRD FROM TABLE AT LINE 8
.-BASED
1A-
JR' 1.4E4
jr.-
:HARGE RATES FROM TABLE AT
E RATES
L-BASED
IDA'
10R' 1.3E5
ion'
JENT STREAMS
11A
11B
11C
12. LIST POLLUTANT SPECIES
Sulfide
one
KNOWN OR SUSPECTED TO BE EMITTED FOR WHICH A MATE IS NOT AVAILABLE.
64
-------
SAM/IA WORKSHEET FOR LEVEL 2
Figure 10(f). Example 4 (Concluded)
Form IA02 Level 2
1. SOURCE/CONTROL OPTION Rage ^ / -,
Byproduct coke oven waste water treatment effluent
2.
4.
EFFLUENT STREAM 3.
201 Treated effluent discharge
CODE # NAME
EFFLUENT STREAM FLOW RATE
n= 9.7 1/sec
(gas = mVsec — liquid =
/sec —
solid = g/sec)
COMPLETE THE FOLLOWING TABLE FOR THE EFFLUENT STREAM OF LINE 2 (USE BACK OF FORM FOR SCRATCH WORK)
A
POLLUTANT
SPECIES
UNITS
Ammonia
Cyanide
Phenol
Sulfide
CATEGORY
—
47
47
18A
53
B
POLLUTANT
CONCEN-
TRATION
yg/i
520,000
74,000
18,000
50,000
c
HEALTH
MATE
CONCEN-
TRATION
yg/i
2,500
500
5
—
D
ECOLOGICAL
MATE
CONCEN-
TRATION
yg/i
. 50
25
500
—
E
DEGREE OF
HAZARD
(HEALTH)
(B/C)
208
148
36,000
—
F MORE SPACE IS NEEDED, USE A CONTINUATION SHEET
5. EFFLUENT STREAM
HEALTH MATE BAS
ECOLOGICAL MATE
(ENTER HERE AND
DEGREE OF HAZARD
4
JED (I COL E) 5a 3.6x10
BASED (I COL. F) 5b
AT LINE 8, FORM IAC
1.4xl04
)1)
6. NUME
POLLL
PAREC
HEALTH
ECOLOGI
ER OF 7. T
ITANTS COM- ,
) TO MATES
fia 3 E
rAi fih 3 (
F
DEGREE OF
HAZARD
(ECOLOGICAL)
-------
REFERENCES
1. Cleland, J. G. and Kingsbury, G. L., "Multimedia Environmental Goals for
Environmental Assessment: Vol. 1," EPA-600/7-77-136a, November 1977.
2. Vitez, B., "Trace Elements in Flue Gases and Air Quality Criteria,"
Power Engineering, Vol. 80, No. 1, January 1976.
3. Ruch, R. R., et a!., "Occurrence and Distribution of Potentially Volatile
Trace Elements in Coal," EPA-65Q/2-74-054.
4. "Supplement No. 6 for Compilation of Air Pollutant Emission Factors
(Second Edition)," U.S. Environmental Protection Agency, Office of Air
and Waste Management, Office of Air Quality Planning and Standards,
July 1974.
5. Bartpk, W., et al., "Field Testing: Application of Combustion Modifica-
tions to Control NOX Emissions from Utility Boilers," Exxon Research and
Engineering Company, EPA-650/2-74-066.
6. Klein, David H., et al., "Pathways of 37 Trace Elements Through Coal-
Fired Power Plant," Environmental Science and Technology, Vol. 9, No. 10,
pp. 973-979, October 1975.
7. Development Document for Effluent Limitations Guidelines and New Source
Performance Standards for the Steel Making Segment of the Iron and Steel
Manufacturing Point Source Category, EPA-440/1-74^024a, PB-238 837.
66
-------
APPENDIX A
SAMPLE FRACTION CATEGORIES AND
ORDERED MATE VALUES
A-l Air-Health
A-2 Air - Ecology
A-3 Water - Health
A-4 Water — Ecology
A-5 Solid - Health
A-6 Solid - Ecology
A-7 Sample Fraction and
Chemical Categories
A-8 SSMS/AA Chemical Categories
A-l
-------
TABLE A-l. KEY TO SAMPLE FRACTION LISTS AND SMALLEST MATE VALUES
ro
Sample
Fraction
Cl
C2
C3
C4
C5
C6
C7
C8
C9
CIO
Cll
C12
GC11
LCI
LC2
LC3
LC4
LC5
LC6
LC7
LC8
LCI 2
SGC
Key
1
2
Gaseous
Health Ecology
A-1C1
A-1C2
A-1C3
A-1C4
A-1C5
A-1C6
A-1C7
A-1C8
A-1C9
A-1C10
A-l Cll
A-1C12
A-1GC11
A-l LCI
A-1LC2
A-1LC3
A-1LC4
A-1LC5
A-1LC6
A-1LC7
A-1LC8
A-l LCI 2
A-l SGC
A-2C1
A-2C2
A-2C3
A-2C4
A-2C5
A-2C6
A-2C7
A-2C8
A-2C9
A-2C10
A-2C11
A-2C12
A-2GC11
A-2LC1
A-2LC2
A-2LC3
A-2LC4
A-2LC5
A-2LC6
A-2LC7
A-2LC8
A-2LC12
A-2SGC
3 1 4
Liquid
Health Ecology
A-3C1
A-3C2
A-3C3
A-3C4
A-3C5
A-3C6
A-3C7
A-3C8
A-3C9
A-3C10
A-3C11
A-3C12
A-3GC11
A-3LC1
A-3LC2
A-3LC3
A-3LC4
A-3LC5
A-3LC6
A-3LC7
A-3LC8
A-3LC12
A-3SGC
A-4C1
A-4C2
A-4C3
A-4C4
A-4C5
A-4C6
A-4C7
A-4C8
A-4C9
A-4C10
A-4C11
A-4C12
A-4GC11
A-4LC1
A-4LC2
A-4LC3
A-4LC4
A-4LC5
A-4LC6
A-4LC7
A-4LC8
A-4LC12
A-4SGC
5
6
Solid Waste
Health Ecology
A-5C1
A-5C2
A-5C3
A-5C4
A-5C5
A-5C6
A-5C7
A-5C8
A-.5C9
A-5C10
A-5C11
A-5C12
A-5GC11
A-5LC1
A-5LC2
A-5LC3
A-5LC4
A-5LC5
A-5LC6
A-5LC7
A-5LC8
A-5LC12
A-5SGC
A-6C1
A-6C2
A-5C3
A-6C4
A-6C5
A-6C6
A-6C7
A-6C8
A-6C9
A-6C10
A-6C11
A-6C12
A-6GC12
A-6LC1
A-6LC2
A-6LC3
A-6LC4
A-6LC5
A-6LC6
A-6LC7
A-6LC8
A-6LC12
A-6SGC
Smallest Mate Values
1
2
Gaseous
Health Ecology
3.3E5*
5.3E6
330.
1.8E4
2.0E2
10.0
1.0E3
1.0E3
1.2
120.
110.
100.
3.8E4
100.
110.
0.02
990.
1.3E3
170.
100.
6.E3
1.6E4
1.E3
1.-
1.1E5
—
—
94.
«
~
—
--
—
—
—
—
—
—
—
—
—
—
—
—
--
—
3
4
Liquid
Health Ecology
4.9E7*
8.E7
5.E3
2.7E5
3.8E3
150.
1.5E4
1.5E4
18.
5.
5.
5.
5.8E5
1.5E3
1.7E3
0.3
1.5E4
1.9E4
5.
5.
9.E4
5.
1.5E4
1.E4*
1.E5
1.E3
1.E3
100.
0.02
1.E4
100.
1.E3
100.
100.
100.
~
100.
0.01
0.01
1.E3
1.E3
1.5
100.
1.E3
500.
--
5 | 6
Solid Waste
Health Ecology
9.8E4*
1.6E5
10.
540.
7.5
0.3
3.
30.
0.04
0.01
0.01
0.01
1.2E3
3.
1.4
0.003
30.
38.
0.01
0.01
180.
0.01
30.
2.2
200.
2.
2.
2.
4.E-5
20.
0.2
2.
0.2
0.2
0.2
—
0.2
l.E-5
l.E-5
2.
2.
0.003
0.2
2.
1.
—
SSMS/AA Use Table A-8 SSMS/AA
00
CM
r-.
i
Note: In this table and succeeding lists, computer notation is used.
Numbers of the form: 3.3x10$ are written in the form: 3.3E5.
-------
LIST A-l - AIR - HLALTH
SAMPLE HAIL
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MI CROC RAMS/CUBIC METER
Cl 3.3E5 1A METHANE
Cl 5.7E6 IB ElhYLENE
C2 5.3E6 1C ACETYLENE
C2 6.1E6 1A ETHANE
C2 6.6E6 IB PROPYLENE
C3 N * IB BUTYLENES * NOT YET ASSIGNtD
C3 N 1C BUTYNE
C3 3.3E2 10B ETHYLENEIM1NE
C3 1.0E2 11 01AZOHETHANE
C3 1.6E3 7A FORMALOtHVUE
C3 2.6E3 26 VINYL CHLOHIDE (CHLOROETHENEI
C3 1.8EH 10B DIMETHYLAMINE
C3 7.5EH 10B OlETHYLAMINE
C3 2.1E5 2A METHYL CHLORIDE
C3 1.7E6 1C PROPYNE
C3 2.2E6 IB BUTADIENES
C3 5.0E6 2A OICHLOROOIFLUOROMETHANE
C3 9.0E6 1A PROPANE
C«» N 10B ETHYLHETHYLAMINE
CH 1.6E4 10A ETHYLAMINE
CH 6.0EH 2A METHYL BROMIDE
C
-------
LIST A-l - AIR - HEALTH
SAMPLE
FRACTION
C5
C5
C5
C5
C5
C5
C5
C5
C5
C5
C6
C6
C6
C6
C6
C6
C6
C6
G6
C6
C6
G6
C6
C6
C6
C6
C6
C6
G6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C7
C7
MATt
VALUE:
3,7t«*
H.bEt
fa.0t4
2.0LS)
2.0ES
a.btb
7.0E&
1.8E6
a,tt6
5,QM>
N
N
N
N
l.QEl
3.2E1
1.3Ei
1.6E4
3.0Ei
1.3.EH
1.5E<*
3.6EH
«»,SiE«»
7,OE«f
1«1E5
1.2Eb
l.bEb
2.fcES
3.SE£»
3.6E.S
3.9ES
H.SE5
S.QEb
5,^tb
9,8Eb
1.PE6
1.1E6
l.lEfa
1.9E6
N
N
CATEGORY SUHjjTANCE
MATE UNITS: MICROGRAMS/CUBIC METER
2A
2A
1,B
2A
23
28
1,A
78
2A
2A
IB
IB
11
IOC
9
IS
2B
IDA
23A
5C
9
7A
2A
5B
5A
2A
1A
7A
5B
&A
76
5B
IB
2A
1A
SA
2A
H
CHLOKOMETHYL METHYL ETHEK
TRitHLOKOETHANE
CAKWON TETKACHLORIUE
CY^LOPENTAUIENES
1.2-OlCHLOKOETHANE
1,1-UICHLOKOETHENE
1,2-OICHLOKOETHENE
PENTANES
li2-QICHLOKO-lt2*OlFLUOROETHANE
BKQHOPICHLOROMETHANE
HEPTENES
HEXENES
a-CHUpKQETMYL HETHYL ETHER
AUK.IL MERCURY
N.N'-pINETHYLHyDRAZINE
H-AH|NObIPhENYL
1-CYANOETHANE
BENZENE
OICHLPRPPRPPENES
BUTYLAMIMES
P1CPLIN£§
TMTJAKY PENTANOL
qUTYRALUEHtDE
CHLOROFORM (TRICHLOROMETHANE )
HETHANOL
OICHLOROPROPANES
HEXANES
3-METHYLBU1ANAL
2-OUTANOL
1-PRPPANQL
gUTANONE
2-PROPANOL ( ISOPROPYL ALCOHOL)
CYCLQHEXENE
BROnpCHLOROMETHANE
CtCLOhEXANE
CTHANOL
BROMOBUTANES
CHLOROETHYL ETHYL ETHER
-------
LIST A-l - AIR - HEALTH
SAMPLE
FRACTION
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C8
C8
C8
C8
C8
C8
C8
C8
C8
C«
C8
C8
C8
ca
C8
C8
C8
C8
C8
C8
C8
C8
ce
ca
C9
C9
Q*
MATt
VALUE
M
N
N
N
1.0E4
3,OE«»
•UOLH
1.5E5
1.8E&
l.ttEb
-------
LIST A-l - AIR - HEALTH
SAMPLE
FRACTION
C9
C9
C9
C9
C9
C9
C9
C9
.C9
C9
C9
C9
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
ClO
CIO
Cll
Cll
Cll
Cll
Cll =*-»--
MATt
VALUE
N
1.2
f.eta
1.9EH
6.3EH
9.6E4
l.StS
2,2Eb
2.5Eb
f.ZEb
*.H£&
1.1E6
N
N ""
N
N
N
1.2E2
3.2E2
f,8E6
5.0E3
6.0E3
1.6EH
1.9E*
2.7EH
3.0t«*
3.0EH
H.5EH
5.9EH
1.2tb
l.SEb
l.&Eb
2.3Eb
3.UE9
f.56.5
N
N
N
N
N
CATEGORY SUBSTANCE
1 liiJ-OICHLOKOETHYL ETHYL ETH6.R
12 N-NITKOSO-UIMETHYLAMINE.
23A CHLOROPYRIUINE
80 AUIPATES
IS ISOPROPYL OEN/ENE
13B OIHHENYL SULFIUE
10A PKOPANOLAM1NE
15 PKOPYL BCN2ENE
16A 2-CHLOROTOLUENE
IS STYRENE
15 XtLtNES
1A NONANES
IA ALKANES ic>9)
H A-CHLOKOBUTYL ETHYL ETHER
24 bENZOFURAN
25 TRI AND TETRAMETHYL THIOPHENES
16A 1.3-DICHLOROBENZENE
12 N-MTROSO-UIETHYLAMINE
SB 3-HYDROXYPKOPANOIC ACID LACTOME
23A CHLORQPYRIOINE
2A BRONCFORH CTRIBROMOMETHANE)
IDA ETHANOLAMINE
22 OICYCLOPENTADIENE
60 ADIPATES
23A Di AND POLTSUbSTITUTEU PYRIDINES
19 2-CHLOROPHtNOL
4 2«2*-DICHLOROOIETHYL ETHER
18B 113-DIHYDROXYBENZENE
7A BEN2ALUEHYUE
15 TRIfiETHYLBENZENES
80 METHYL BEN^OATE
6B 2«3-EPOXY-l-PROPANOL
15 OIALKYL BENZENES
16A lt2-DJCHLOKOBENZENE
16A ItH-DlCHLOKOBENZENt:
1A ALKANES (C>9>
4 B1S-(1-CHLOROISOPROPYL> ETHER
7B TtTRACHLOROACETONE
15 TLTRAMETHYLBENZENES
2A 1-CHLOROOCTANE
MATE UNITS! M1CROGRAMS/CUBIC METER
-------
LIST A-l - AIR - HEALTH
SAMPLE
FRACTION
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
MATE
VALUE
1.1E2
S.OE2
B.1E2
5.0E5
1.0E4
l.OEf
1.9E.4
1.9EH
2.0E4
2.5E<*
H.5E«+
5.0E1
2.3Et>
2.3ES
3.6E5
N
N
N
1.0E2
2.UE3
5.0E3
7.0E3
2.2EH
2.HLH
5.5E4
5.6E9)
16A BHUMO AND UIBROMOBENZENES
16A BROMOCHLOROBENZENES
26A TLTRAETHYLLEAD
12 N-NITROSO-DIPROPYLAMINE
17 NITROBENZENE
19 2ft-DICHLOHOPHENOL
18A CRESOLS (METHYL PHENOLS)
16A ALKYL CRESULS
5A A-HYOROXYTULUENE (BENZYL ALCOHOL)
20 2-NITROPHENOL
15 TETRAHYOKONAPHTHALENE
15 OIALKYL BENZENES
MATE UNITS: MICROGRAMS/CUBIC METER
GC11
12
N-NITROSO-UIISOPROPYLAMINE
LCI N 1A ALrtANES (C>9)
LCI 1.0E2 26A TtTRAETHYLLEAD
-------
LIST A-l - AIR - HEALTH
SAMPLE MATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/CUB1C METER
LC2 N 16B BlS-(CHLOROMETHYL)bEMENE
LC2 N 16A BROf-0 AND OIRROMOBENZLNES
LC2 N 16A BROHOCHLOROBENZENES
LC2 N 22 CYCLOPENTAMONAPHTHALENE
LC2 N 22 FLUCRENE.
LC2 N 15 «HH»-DIPHENYLBIPHENYL
LC2 1.1E2 2B HEXACHLOROCYCLOPENTADIENE
LC2 5.0E2 16A POLYCHLORIUATED BIPHENYLS
LC2 1.0E5 15 BIPHENYL
LC2 «t.!E3 2B HtXACHLOROBUTADIENE
LC2 3.El 21 BLN^< A) ANTHRACENE
-------
LIST A-l - AIK - HEALTH
iO
SAMPLE
FRACTION
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC<»
ICH
LCH
LC«»
LCH
LCH
LC<»
LC<»
LC4
LC<»
LC»«
LC<*
LC<*
LCt*
LCH
HATE
VALUE
5.0E2
9.0E2
9.0E2
1.1E3
1.6L3
1.6EA
1.6E.3
l.QEd
2.2E3
2.5E3
3.0ti
3.7E3
6.5E3
9.0E3
9.9E3
1.3Ef
1.6E4
2.7EH
3.0E4
3.4EH
4.5EH
5.6E«»
6.9EH
6.9EH
9.0E*»
2.3E5
2.3CS
N
N
N
N
N
N
N
N
9.9E2
1.3E4
5.0E4
1.2E1
1.3E<+
1.9E<*
2t3E<+
CATEGORY SUBSTANCE
16A POLYCHLORIlMflTEO BlPHENYLS
22 BEN20(B)FLUORAUTHENE
22 BLNZOIEIFLUORANTHENE
21 OlbtNZOlA, )PYKtNE
22 BtNZO(K)FLUORANTHENE
22 INOENO(l«2t3«CO)PYKENE
21 PHtNANTHRENE
21 METHYL CHRYSENES
21 CHRYSENE
21 PICENE
21 BtN20(E)PYK£NE
21 DIBtNZO(A,H)PYRENE
22 BEN20(J)FLUORANTHENE
15 TERPHENYLS
21 DIBENZIA.OANTHRACENE
22 l«2:5,6-OIBENZOFLUOrt£NE
21 - BENZO(6)CHRYSENE
21 BENZO(C)PHENANTHRENE
21 METHYLPHENANTHRENES
16A POLYCHLORINATEO BENZENES
15 INUENE
21 ANTHRACENE
16A CHLORONAPHTHALENES
23A COLLIDINES
22 FLUORANTHENC
15 INDAN
21 PYRENE
4 BROMOPHENYL PHfNYL ETHER
7B CHLOROHYDROXY BENZOPHENONE
25 DIBENZOTHIOPHENE
7B OIHYORO(D)CARVON£
9 NAPHTHONITRILES
H 2-CHLORO-l«2-EPOXYHROPANE
25 2i2-BITHIOPHEN£
7B 5»6-BENZO-9-ANTHROlME
25 BENZONAPHTHOTHIOPHENE
17 ^-NlTROBIPHE^YL
17 NITROBENZENE
7B CAMPHOR
17 l-CHLORO-2-NITROBENZENE
17 l-CHLORO-i»-NITROBENZENE
25 BENZO(b)THIOPHENE
MATE UNITS: MICROGRAMS/CUB1C METER
-------
LIST A-l - AIR - HEALTH
SAMPLE
FRACTION
LC<»
LC<»
LCS
LC5
LCS
LCS
LC5>
LCS
LCS
LCS
LCS
LCS
LCS
LCS
LCS
LCS
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
MATt
VALUE
2. set
H.1EH
N
N
N
N
N
N
N
1.3E3
1.5E3
2.HE3
•USE 3
3.0E1
7.Ht<*
5.9E9
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
1.7E2
2.2E2
2.SE2
5.0E2
8.0E2
l.OEd
1.2L3
CATEGORY SUOSTANCE
7B ISOPHOKONE
7B ACETOPHtNONE
2t Bb.NZO(B)NAPHTHO(2t3-0)FUKAN
24 DIBfcNZOFURAN
2H HETHYLDIBENZOFUKANS
2H NAPHTHOFURANS
12 N-NITROSO-OIPENTYLAMINE
24 PHENANTHRO(9,10-B)FURAN
2H 1.9-BENZOXANTHENE
12 N-NETHrL-N-NITROSO-ANILlNE
17 OIN1TROTOLUENES
12 N-IMITROSO-OIPHOPYLAhlNE
17 METHOKYNlTKOBENZENes
17 NlTROTOLUEf*ES
12 N-NITROSO-UIPHENYLAMINE
24 TETRAHTDROFURAN
IfiC ACEMAPHTHOLS
23B BLNZO(C>QU1NOLINE
23B BENZO(F)OUINOLINE
23B BENZO(H)OUlNOLINE
238 BENZ(A)ACRIDINE
23B OIMYOROACRIOINC
23B DIHETHYLUIUNOLINES, DIMETHYLISOQUINOLINES
80 DI-2-EHTYLHEXYL PHTHALATE
ISA ETHYLPHENOLS
23B INDENO(l,2i3-IJ)ISOQUINOLINE
5C ISOBORNEOL
80 LONG CHAIN ESTERS
18C PHENANTHROLS
80 PHENYL BEN^OATE
13A 1-AMTHRACENETHIOL
18C 2-HYOROXYDIBENZOFURAN
18C 2-HYBROXYFLUORENE
IOC 2-AniNONAPHTHALENE
23B OIBENZ(A,H)ACRICINE
23B OIbENZ(A,J)ACKIOINE
IOC ANISIDIUES
13A PLRCHLOROMETHANETH.IOL
23C DIBEN?0(C.U)CARBAZOLE
IDA MLFHYLAHINt
MATE UNITS: MICROGRAMS/CUBIC METER
-------
LIST A-l - AIR - HEALTH
SAMPLE MATE
FRACTION VALUE CATEGORY SUBSTANCE HATE UNITS: MICROGRAMS/CUBIC METER
LC6 2.Ot3 IBB l^-UIHYURUXYBENZENE
LCfe 2.ltd 13A BtNZENETHlOL
LC6 2.7td 23C PYRROLE
LC6 <*.3E3 230 BENZOTHIAZULE
LC6 H.SE3 IOC lit-DIAMINOBENZENE
LC6 H.7E3 230 MtTHYL BEftUOTHIAZOLES
LC6 5.0E3 80 PHTHALATE tSTERS
LC6 6. OE13 23C DIBENZO* 23C METHYLINDOLES
LC6 S.SEH 23B 2-METHYLQUlNOLINE
LC6 7.0t4 10B MORPHOLINE
LC6 9.0E<* 23B ACRIOINE
LC6 9.0E1 SB BORNEOL
LC6 l.lEtj 18C 2-NAPHTHOL
LC6 1.2ES 18C 1-NAPHTHOL
LC6 1.5ES 18C INOANOLS
LC6 1.9E5 SC A-TERPINEOL
LC7 N 8A LONG CHAIN ACIDS
LC7 1.0E2 20 2.f«6-TRINlTROPHENOL
LC7 2.0E2 20 H.b-DINITRO-0-CKESOL
LC7 2.2E^ IOC H.1«-M£THYLENE-bIS-(2-ChLOKOANILINE)
LC7 5.0E.2 19 PfcNTHACHLOKQPHENOL
LC7 5.6E.2 IOC 1-AMINONAPHTHALENE
-------
LIST A-l - AIR - HEALTH
SAMPLE MftTL
FRACTION VALUE CATEGORY SUHST/\MCE MATE UNITS! MICR06RAMS/CUB1C METER
LC7 6.BE2 20 01NITRO-P-CRESOL
LC7 l."»EJ 20 OINITRQPHENOLS
LC7 6.0E.3 8A PHTHALlC AGIO
LC7 6.6E3 IOC 3«3»-OlCHLOROBENZIDINE
LC7 l.Ht-4 IOC BtNZlOINE U.<» '-OIAHINOfclPMENYD
LC7 l."»E.t 11 1.2-UIPHENYLHYORAZINE
LC7 2.5E«» 8A ACETIC AGIO
LC7 3. Of* BC FORMAMIOE
LC7 f.6L4 20 2-AMINO-«l,6-DINITROPHENOL
LC7 5.8EH 20 2-NlTROPHENOL
LC7 8.8EH 8B HYOROXYACETIC ACID
LC7 1.4E5 8A BENZOIC ACID
LC7 4.5E5 8C ACETAWIOE
LC8 N 8B 6-AMINOHEXANOIC ACID
LC8 N 14A 9.10-ANTHRAQUINONEDISULFONIC ACID
LC8 6.0E3 8A PHTHALlC ACID
LC8 2.5E<+ 8A ACETIC ACID
> LC8 H.OEf 11A BENZENtSULFONlC ACID
ro
LC12 1.6EH 20 <*-MTROPHENOL
LC12 2.0Lt 20 3-NITROPHE.fJOL
NYD * N 26A ALKYL STIBINES * NOT YET DETERMINED
NYD N 26C COMPLEXED IRON
NYD N 26C GOMPLEXtD NICKEL
NYD N 26C COMPLEXED TIN
NYD N 26C COMPLEXED UNC
NYD N 26B DIBENzE CHROMIUM
NYD N 2A DIHROMOCHLOROMETHANE
NYD N 21 PLRYLENE
NYD N 9 lt$-OICYANO-L-HYDROXYBUTANt
NYD N 23B 2<3-BENZ-H-AZAFLuORENE
NYD 1.0E2 26A ORGANOTIN
NYD 1.5C2 26A TETRAMETHYLLEAD
NYD 3.2E2 SB B-PROPIOLACTONE
NYD 3.5E2 11 MONOMETHYLHYDRA2INE
NYD l.OEi 11 NtN-UIMETHYLHYDRAZINE
NYD 2.0E3 11 -UIMETHYLAMINOA20B£NZENE
NYD 3.0E3 26C COMPLEXED COPPER
NYD 3.0E3 9 TE.TRAMETHYLSUCCINONITRILE
NYD 3.SEJ 26B NICKELOCENL
NYD 2.3E«f 9 BUTYRONITRlLE
NYD 3.2EH 9 BLNZONITRILE
NYD 3.2E
-------
LIST A-l - AIN - HEALTH
SAMPLE: MAIL
FRACTION VALUE CATEGORY SUUSTANCE MATE UNITS: MICROGRAMS/CUBIC METER
NYO 6.UE.H 26B FERROCENE
NtD 3.0E5 5C TERTlAHt BUTANOL
SGC N 13B 01ETHYL SULFIDE
SGC 1.0E3 13A ETHANETHIOU
S6C l.OEd 13A MLTHANETHIOL
SGC 1.5E3 13A N-UUTANETHlOL
SGC 2.UEH 13B DIMETHYL SULFIDE
SGC 6.IE* 13A PROPANETHIOLS
3>
CO
-------
LIST A-2 - AIR - ECOLOGY
SAMPLE HATE
FRACTION VALUE CATEGORY SUUSTANCE MATE UNITS: MICROGRAMS/CUBIC METER
Cl N * 1A METHANE » MOT YET ASSIGNED
Cl 1.0 IB ETHYLENE
C2 N 1A ETHANE
C2 N IB PKOPYLENE
C2 LIES 1C ACETYLENE
C3 N 18 BUTADIENES
C3 N IB BUTYLENES
C3 N 1C BUTYNE
C3 N 11 DIAZOMETHANE
C3 N 2A DICHLOROOIFLUOROMETHANE
C3 N 10B DIETHYLAMINE
C3 N 10B UlMtTHYLAMINE
C5 N 10B ETHYLENEIM1NL
C3 N 7A FORMALDEHYDE
C3 iM 2A MLTHYL CHLORIDE
C3 N 1A PROPANE
C3 N 1C PROPYNE
C3 rt 28 VINYL CHLORIDE (CHLOROETHENE)
C«t N 7A ACETALUtHYUE
C
-------
LIST A-2 - AIR - ECOLOGY
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/CUB1C METER
C5 N 1A PLNTANES
C5 N IB PENTENES
CS N 7A PROPIONALDEHYDE
CS N 25 THIOPHENE
C5 N 2A TRICHLOROETHANE
CS N 26A TRIHETHYLANSINE
CS N 2B 1,1-DICHLOROETHENE
CS N 2A 1,2-DICHLONOETHANE
C5 N 28 1»2-UICHLOKOETHENE
CS N 2A 1.2-DICHLO«0-1,2-DIFLUOROETHAME
CS N IDA 3-AhINOPROPANE
CS 9.HEX 7A ACROLEIN
C6 N 9 ACETONITRILE
C6 N 26A ALKYL MERCURY
C6 N 15 BENZENE
C6 N 2A BHOhOCHLOROMFTHANE
C6 N 2A BKOhODICHLOROhETHANE
C6 N 7B BUTANONE
C6 N IDA BUTYLAMINES
Cb N 7A BUTYRALOEHYOE
C6 N 2A CHLOKOFORM
Cb N 1A CtCLOHtXANL
C6 N IB CYCLOHEXENL
C6 N 2A OICHLOROPROPANES
C6 N 2B D1CHLOROPROPENES
Cb N 5A ETHANOL
C6 N IB HEPTENES
C6 N 1A HLHANES
C6 N IB HtXENES
C6 N bA MtThANOL
C6 N 11 N«N*-Dlt1£THYLHYORA2INE
C6 N 23A P1COLINES
C6 N 5C 1EK1IAMY PfcNTANOL
C6 N 9 1-CYANOETHANE
C6 N bA 1-PHOPANOL
C6 N 58 2-BUTANOL
Cb N H 2-CMLOROETHYL METhYL ETHEK
C6 N 5B 2-PHOPANOL (ISOPROPYL ALCOHOL)
C6 N SB 2.6-DTMETHYL-H-HEPTANOL
C& N 7A 3-METHYLBU1ANAL
Cb N IOC H-AMINOBIPHENYL
-------
LIST A-2 - AIK - ECOLOGY
SAMPLE MAIL
FRACTION VALUE CATEGORY SUdSTAwCE MATE UNITS! MICROGRAMS/CUBIC METER
C7 N 2A BROMOBUTANtS
C7 N i* CHLOROETHYL ETHYL ETHER
C7 N H CHUOROMETHYL ETHYL ETHER
C7 N 1A HEPTANES
C7 N 6B HYUROXYbENZOIC ACID
C7 N 5A ISOBUTYLALCOHOL
C7 N 3 ISOPROPYL ETHER
C7 N 8D METHYL METHACRYLATE
C7 N H l-CHLORO-lt2-OXETANE
C7 N H 1«1«-DICHL0RODIETHYL ETHER
C7 N <» itl»-DlCHLOROMETHYL ETHER
C7 N 3 l.i-OIOXANE
C7 N 3 lt«»-DlOXANE
. C7 N 3 2-NETHOKY BlPHENYL
C7 N 8C 6-HEXANELACTAM (E-CAPROLACTAM)
> £6 N 80 ADIPATES
1, C8 N 8A BENZOIC ACID
CD cd N 16A CHLOKOBENZtNE
C8 N 23A COLLIDINES
CB N 10A CYCLOHEXYLAMINE
Cd N 2A D1BROHOOICHLOKOMETHANE
Cd N 15 ETHYL BENZLNE
€8 N 8A FORMIC ACID
C8 N 8A LON6 CHAIN ACIDS
€8 N 8A HALEIC ACIU
CB N 136 METHYL UISULFIDE
C8 N 2A MLTHYLLNE CHLOR10L (UICHLOKOMETHANE)
C8 N 25 WETHYLTHIOHHENES
C8 N 5A N-BUTANOL
Cfl N 1A OCTANES
C8 N SA PtNTANOLS (PRIMARY)
C8 N 5B PtNTANOLS (SECONDARY)
C8 N 23A PHENYL PYRIDINES
C8 < N 23A PYRIOINE
C8 N 2B TETRACHLOROETHENE
C8 N IS TOLUENE
08 N 6B l-ChLORO-2.3-EPOXYPROPANE (A-EPICHLOROHYDRIN)
CB N IDA 1»2-DIAMINOETHANE
C8 N 3 2-ETHYL-H-METHYL-li 3-OIOXOLANES
-------
LIST A-2 - AIR - ECOLOGY
SAMPLE MATE
FRACTION VALUE: CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/CUBIC METER
C9 N 60 AOIPATES
C9 N 16A BHOMO AND UIBHOMOBENZENES
C9 N 23A CHLOKOPYRIUINE
C9 N 25 DINETHYLTHIOPHENES
C9 N 13B DIPHENYL SULFIOE
C9 N 15 ISOPROPYL BENZENE
C9 N 1A NONANES
C9 N 12 N-NITROSO-UIMETHYLAMINE
C9 N 10A PKOPANOLAMINE
C9 N 15 PROPYL BENZENE
C9 N 15 STYRENE
C9 N 15 XYLENES
C9 N tf lf2-OICHLOKODIISOPROPYL ETHER
C9 N (f 1,2-OICHLOKOETHYL ETHYL ETHER
C9 N 16A 2-CHLOROTOLUENE
CIO N 60 ADIPATtS
CIO N 1A ALKANES (C>9>
CIO N f A-CHLOKOBUTYL ETHYL ETHER
CIO N 7A BLNZALUtHYUE
CIO N 2t ULNZOFURAN
CIO N 2A BROHOFORM (TRIBROMOMETHANE)
CIO N 23A CHLOROPYRIOINE
CIO N 23A 01 ANO POLYSUBSTITUTEO PYR10INES
CIO N 15 OIALKYL BENZENES
CIO N 22 D1CYCLOPENTADIENE
CIO N 10A ETHANOLAMINE
CIO N 60 METHYL BENIOATE
cio N 12 N-NITROSO-OIETHYLAMINE
CIO N 25 TRI AND TETRAMETHYL THIOPHENES
CIO N 15 TRIMETHYLBLNZENES
CIO N 16A 1«2-OICHLOKQBENZENE
CIO N 16A lid-OICHLOKOBENZENE
CIO N 16B 1<4-UIHYDROXYBENZENE
CIO N 16A lif-UICHLOKOBENZENE
CIO N 19 2-CHLOROPHtNOL
CIO N
-------
LIST A-2 - AIK - ECOLOGY
SAMPLE MATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS! MICROGRAMS/CUBIC METER
Cll N 9 ACRYLONITRILE
Cll N 1A ALKANES (C>9)
Cll N IOC AMINOTOLUENES (METHYL ANILINES)
Cll N IOC ANILINE
Cll N <* BlS-(l-CHLUROISOPROPYL) ETHER
Cll N 15 BUTYLBtNZENE
Cll N 15 01ALKYL BENZENES
Cll N 1 Cll N IS TtTRAHETHYLBENZENES
J_, Cll N 16B -CHLOROTOLUENE
CO Cll N 2A 1-CHLOKOOClANE
Cll N 20 3-NITROPHENOL
C12 N 1A ALKANES (C>9)
C12 N 16A ALKYL CRESOLS
C12 N 5A A-HYOROXYTOLUENE (BENZYL ALCOHOL)
C12 N 16A BROHO AND DIBROMOBENZENES
C12 N 16A BROMOCHLQROBENZENES
C12 N 18A CRESOLS (METHYL PHENOLS)
C12 N 15 OIALKYL BENZENES
C12 N 17 NITROBENZENE
C12 N 12 N-NITROSO-UIPROPYLAMINE
C12 N 26A TETRAETHYLLEAD
C12 N 15 TETRAHYQRONAPHTHALENE
C12 N 20 2-NITROPHENOL
C12 N 19 2,1-DlCHLOKOPHENOL
ecu N 12 N-NITROSO-DIISOPROPYLAMINE
LCI N 1A ALKANES 9)
LCI N 26A TE1RAETHYLLEAO
-------
LIST A-2 - AIR - ECOLOGY
SAMPLE HATE
, FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/CUBIC METER
LC2 N IS bIPHENYL
LC2 N 16B BlS-(CHLORUMETHYL)bENZCNE
LC2 N 16A BRUMU AND UIBROHOBENZtNES
LC2 N 16A BROHOCHLOROBENZKNES
LC2 N 16A CHLORONAPHTHALENES
LC2 N 22 CYCLOPENTANONAPHTHALENE
LC2 N 15 DlHYORONAPHTHALtNE
LC2 N 21 DIMETHYL NAPHTHALENES
LC2 N 22 FLUORENE
LC2 N 2B HEXACHLOROBUTA01ENE
LC2 N 2B HEXACHLOROCYCLOPENTAOIENE
LC2 N 15 INUAN
LC2 N IS INOENE
LC2 N 21 MONOALKYL NAPHTHALENES
LC2 N 21 NAPHTHALENE
LC2 N 16A POLYCHLORINATEO BENZENES
LC2 N 16A POLYCHLORINATEO BIPHENYLS
3» LC2 N IS TETRAHYDRONAPHTHALENE
j_, LC2 N 15 «fi«*«-DIPHENYLbIPHENYL
<£>
LC3 N 21 ACENAPHTHENE
LC3 N 21 ACENAPHTHYLENE
LC3 N 21 ANTHRACENE
LC3 N 21 BENZO(A)PYKENE
LC3 N 22 B£NZO(B)FLUORANTHENE
LC3 N 21 BENZO(C)PHENANTHRENE
LC3 N 22 BLNZOCEJFLUORANTHENE
LC3 N 21 BEN20(E)PYKENE
LC3 N 21 BENZOCGICHKYSENE
LC3 N 21 BLNZO(6iHtI)PERYLENE
LC3 N 22 BENZOtJIFLUOHANTHENE
LC3 N 22 BENZO(K)FLUORANTHENE
LC3 N 21 BENZtAIANTHRACENE
LC3 N 16A CHLORONAPHTHALENES
LC3 N 21 CHRYSCNE
LC3 N 23A COLLIDINES
LC3 M 21 CORONENE
LC3 N 22 CYCLOPENTA(OEF)HHENANTHRENE
LC3 N 21 Dlbfc.NZO(A< )PYRENE
LC3 N 21 DIBENZO(AtH)PYRLNE
LC3 ' N 21 DlBENZO(A,l)PYKLNt
LC3 N 21 OlBLNZ(AfC)ANTHRACENE
LC3 N 21 Ulb(.NZ(AiH>ANTHNACENE
-------
LIST A-2 - AIR - LCOLUbY
SAMPLE MATE
FRACTION VALUE CATEGORY SUBSTANCE NATE UNITS: MICROGRAMS/CUBIC METER
LC3 N 21 DIMETHYL PYRENE8
LG3 N 22 FLUORANTHENE
LC3 N 15 INOAN
LC3 N 15 INUENE
LC3 N 22 INqEMO(1.2t3iCD)FYKENE
LC3 N 21 METHYL CHRYSENES
LC3 N 21 hETHYLPHENANTHRENES
LC3 N 23A MONOSUBSTITUTEP ALKYL PYRIUINES
LC3 N * 21 NAPHThACENL
LC3 N 21 PHENANTHRENE
LC3 N 21 PHENYL NAPHTHALENES
LC3 N 21 PICENE
LC3 N 16A PQLYCHLQRINATED BENZENES
LC3 N 16A POLYCHLQB|NAT£p BIPHENYLS
LC3 N 21 PYRENE
LC3 N 15 TtRPHENYLS
LC3 N 22 TRIBENZYi.EN[EBEN2ENe (TRUXENE)
LC3 N 21 TRIPHENYLEHE
LC3 N 21 1-METHYLPYRENE
LC3 N 22 1«2-BENZOFLUORENE
LC3 N 21 1.2-BEN2QNAPHTHACENE
LC3 N 22 l*i»:5t6-pIBENZOFLUORENE
LC3 N 22 2i3-BENZOFLUOKENE
LC3 N 21 2i7-Din£THVL>NTHRACENE
LC3 N 22 3-METHYL-CHOLANTHRENE
LC3 N 15 I.^'-OIPHENYLBIPHENYL
LC3 N 21 7tl2^pIMETHYLBEN2
-------
LIST A-2 - AIR - ECOLOGY
SAMPLE HATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS! MICROGRAMS/CUBIC METER
LC4 N 17 4-NITftOBIPHENYL
LC4 N 7B 5*b-BENZO-9-AMThRONE
LCS N 24 BENZO(B)NAPHTHO(2i3-l»FURAN
LCS N 24 D1BE.NZOFURAN
LCS N 17 D1N1TROTOLUENES
LCS N 17 HETHOXYNITR08ENZENES
LCS N 24 MLTHYLOIBENZOFURANS
LCS N 24 NAPHTHOFUKANS
LCS N 17 NITROTOLUENES
LCS N 12 N-METHYL-N-NITROSO-ANILINE
LCS N 12 N-NITROSO-OIPENTYLAMINE
LCS N 12 N-NITROSO-UIPHENYLAMINE
LCS N 12 N-NITROSO-DIPROPYLAHINE
LCS N 24 PHENANTHRO<9.10-B)FURAN
LCS N 24 TETRAHYDROUJRAN
LCS N 24 lt9-BENZOXANTHENE
LC6 N 16C ACENApHTHOLS
LCb N 23B ACRIDINE
LCb N 18A ALKYL CRESOLS
LCb N IOC ANISlDlNEs
LCb N SC A-TERPINEOL
LCb N ISA BLNZENETHIOL
LCb N 230 BENZOTHIAZOLE
LCb H 23C BEMZO)CARbAZULE
LCb N 23C OIBENZO(A«I)CAKBAZOLE
LCb N 23C OIBENZO(CtO)CARbAZOLE
LCb N 23B DIBENZACRIDINE
-------
LIST A-2 - AIR - ECOLOGY
SAMPLE MATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/CUBIC METER
LC6 N 23B OIHYOROACRIDINE
LC6 N 23B OIKETHVLQUINOLINES. OIMETHYLISOQU1NOL1NES
LC6 N 60 Di-2-EHTYLHEXYL PHTHALATE
LC6 N 18A ETHYLPHENOLS
LC6 N IfiC INUANOLS
LC6 N 23B INOLNOUt2»3-IJ)ISOQUINOLlNE
LC6 N 23C INUOLE
LC6 N 5C ISOBORNEOL
LC6 N 80 LONG CHAIN ESTERS
LC6 N 23D METHYL BENZOTHIAZOLES
LC6 N IOA HE.THYLAMINL
LC6 N 23C HETHYLINDOLES
LC6 N 10B HORPHOLINE
LC6 N 100 N.N-DIflETHYLANILINE
LC6 N 13A PERCHLOROMtTHANETHlOL
LC6 N 18C PHENANTHROLS
LC6 N 60 PhtKYL BENZOATE
LC6 N 16A PHENYLPHENOLS
> LC6 N 80 PHTHALATE ESTERS
ro LC6 N 18A POLYALKYL PHENOLS
1X3 LC6 N 23C PYRROLE
LC6 N 23B QUINOLINEI ISOQUINOLINE
LC6 N 16A XYLENOLS (UIMETHYL PHENOLS)
LC6 N ISA 1-ANTHRACENETHIOL
LC6 N 18C 1-NAPHTHOL
LC6 N SB 1-PHENYLETHANOL
LC6 N 16B 1«2«3-TRIHYDROXYBENZENES
LC6 N IOC 1.«»-DIAHINOBENZENE
LC6 N 16B 1,«*-DIHVOROXYBENZENE
LG6 N IOC 2-AHINONAPHTHALENE
LC6 N 16C 2-HYDROXY01BENZOFURAN
LC6 N 16C 2-HYOROXYFLUOREME
LC6 N 18A 2-METHOXYPMENOL
LC6 N 23B 2-METHYLQUINOLINE
LC6 N 16C 2-NAPHTHOL
LC6 N 16A 2i2*-OIHYOKOXYOIPHENYLS
LC7 N 8C ACETAMIDE
LC7 N 8A ACETIC ACIU
LC7 N IOC BLNZIOINE <4,
-------
LIST A-2 - AIK - ECOLOGY
ro
SAMPLE
FRACTION
LC7
LC7
UC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC8
Lea
Lea
Lee
L.C6
LC12
LCI*
NYD *
NYD
NYO
NYO
NYO
NYD
NYO
NYD
NVD
NYD
NYO
NYO
NYD
NYO
NYO
NYU
f'YO
NYD
mo
WYD
NYD
NYU
MATE
VALUE
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
CATEGORY SUdSTANCE
8C FORMAMiDE
8B HYUROXYACEUC ACIU
6A LONb CHAIN ACIDS
19 PtNTHACHLOKOPHENOL
8A PHTHALIC ACID
IOC 1-AMINONAPHTHALENE
11 1.2-DIPHENYLHYDRAZINE
20 2-AMINO-«t,6-DlNlTROPHENOL
20 2-NITROPHENOL
20 2«H»6-TRINITROPHENOL
IOC 3.3«-DICHLOROBENZIDINE
IOC Ht«*«-METHYLENE-BIS-<2-CHLOROANlLINE»
20 "M6-OINITRO-0-CRESOL
6A ACETIC ACIO
1HA BEN2ENESULFONIC ACID
6A PHTHALIC ACID
6B 6-AHINOHEXANOIC ACIO
1<*A 9«10-ANTHRAQUINONEOISULFONIC ACID
20 3-N1TROPHENOL
20 «4-NlTROPHENOL
26A ALKYL STIB1NES
9 BLN20NITRILE
9 BUTYRONITRILE
6B B-PROPIOLACTONE
26C COrtPLEXED COPPER
26C COMPLEXED IRON
26C COHPLEXEO NICKEL
26C COflPLEXEO TIN
26C COnPLEXED /INC
26B OldENZE CHKOMIUM
2A OIBKOMOCHLOROMETHANE
26B FERROCENE
11 HONONETHYLHYDRAZINE
26B NICKLLOCENE
11 N«N-OIhETHTLhYDRA2lNL
26A OKbANOCERMANES
26A OKtiANOTIN
21 PtKYLENE
SC TERTIARY BUTANOL
26A TETRAHETHYLLEAD
-------
LIST A-2 - AIR - ECOLOGY
SAMPLE HATE
FRACTION VALUt CATEGORY SUbSTANCE MATE UNITS: MICROGRAMS/CUBIC METER
NYD N 9 1.3-DICYANU-L-HYUROXYBUTANE
NYD N 23B 2.3-BEN2-t-AZAFLUORENE
S6C N 13B OIETHYL SUUFIDE
S6C N 13B DIMETHYL SULFIOE
SGC N 13A ETHANETHIOL
SGC N ISA HtTHANETHIOL
SGC N ISA N-BUTANETHIOL
SGC N ISA PROPANETHIOLS
ro
-------
LIST A-3 - UATER - HEALTH
SAMPLE
FRACTION
MATE
VALUE
CATEGORY SUBSTANCE
MATE UNITS! MICROGRAMS/LITER
Cl
Cl
«».9E7
8.6E7
1A
IB
MLTHANE
ETHTLENL
C2
C2
C2
8.0E.7
9.2E7
1.3E8
1C
1A
IB
ACETYLENE
ETHANE
PROPYLENE
ro
01
C3 N * IB BUTYLENES
C3 N 1C BUTYNE
C3 5.0E3 10B E1HYLENEIMINE
C3 6.0E3 11 ' DIAZOMETHANE
C3 2.HEH 7A FORhALOEHYUE
C3 3.6E4 28 VINYL CHLOKIUE (CHLOROETHENE)
C3 2.7ES 10B OIMLTHYLAMINE
C3 l.lEfa 10B DIETHYLAMINE
C3 3.2E6 2A MLTHYL CHLORIDE
C3 2.SE7 1C PROPYNE
C3 3.3E.7 IB BUTADIENES
C3 7.4E7 2A OlCHLOROQIFLUOROMETHANE
C3 l.HEb 1A PHUPANE
* NOT YET ASSIGNED
-------
LIST A-* - W/JltR - HEALTH
SAMPLE MATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/LITER
C«» N 10B ETHYLMtTHYUMlNE
C«» 2.7ES IDA ETHYLAMINE
C» 9.0ES 2A METHYL BROMIDE
C«» \ 2.7E6 7A ACETALUtHYUE
CH 7 2.1E7 1A BUTANES
CH 6.0E7 2A TRICHLOROFLUOROHETHANt
CS N IB CYCLOHEXAD1ENE
CS N 1A CYCLOPENTANE
CS N 2*» FURAN
C5 N IB PENTENES
CS N 26A TRIHETHYLANSINE
CS N 10A 3-AMINOPROPANE
CS 3.8E3 7A ACROLEIN
CS 1.3E4 2A METHYL IODIDE
CS 6.8Et 25 THIOPHENE
> CS 5«» 9 1-CYANOETHANF.
C6 H.5f4 IS REN2ENE
C6 1.7E3 2B OlCHLOHOPROPENfS
C6 2.3t3 IDA HUTYLAMINES
Cft 5.3K3 23rt P1COL1NLS
C6 fe.UFtj 2A CHLUHOFORM (THICHLOHO^E
C.f> fe.BfS 5C TLMTIAKY PLMTANOL
-------
List A-3 - WATER - HEALTH
ro
SAMPLE
FRACTION
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
ce
ce
CB
ce
ce
Cfl
en
ce
r*
NATE
VALUE
1.1E6
1.7E6
2.«»Eb
3.9E6
5.3E6
5."»E.b
5.8E6
6.8Eb
7.5£6
8.9E6
1.5E7
1.5E7
1.6C7
1.7E7
2.9E7
N
N
N
N
N
N
l*5E
-------
1.1ST A-3 - WATER - HEALTH
SAMPLE MUTE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/LITER
C8 3."»ES 3 fc-ETHYL-4-METHYL-lt 3-OIOXULANES
C8 3.8ES IDA 1.2-DIAMNOFTHANE
C8 fe.OttJ IDA CYCLOHEXYLAKINE
C6 1.0E6 23A COLLI01NES
C8 2.1E6 8A BENZOIC ACID
C8 2.3E6 5A N-BUTANOL
C8 3.9E6 2A f«E.THYLENE CHLORlDt IUICHLOKOMETHANE)
C8 5.3C6 16A CHLOROBE.NZt.NE
C8 5.HE6 5A PENTANOLS
-------
LIST A-3 - WATER - HEALTH
SAMPLE
FRACTION
MATE
VALU£
CATEGORY SUBSTANCE
MATE UNITS1. MICROGRAMS/LITER
ro
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
cio
CIO
CIO
CIO
CIO
CIO
CIO
cio
CIO
CIO
CIO
CIO
CIO
CIO
N
N
N
N
N
5.0
5.0
1.6E3
4.8E3
7.2E4
7.5E4
9.0E4
2.4Eb
2.8E5
4.1E5
4.5ES
8.6E5
1.8E6
2.3E6
2.3E6
3.4E6
4.5E6
6.8Efa
1A
4
24
25
16A
18B
19
12
8B
23A
2A
10A
22
8D
23A
4
7A
15
80
6B
15
16A
16A
ALKANES (C>9)
A-CHLOROBUTYL ETHYL ETHER
BENZOFURAN
TRI AND TElRAMETHYL THIORHENES
1«3-OICHLOROBENZENE
lt3-OlHYOROXYBENZENE
2-CHLOROPHt.NOL
N-NITROSO-UIETHYLAHINE
3-HYOROXYPKOPANOIC ACID LACTONE
CHLOROPYRIOINE
BROhOFORM (TRIBROMOMETHANE)
ETHANOLAMINE
OICYCLOPENTADIENE
ADIPAJES
01 AND POLYSUBSTITUTEO PYRIDINES
2.2'-OICHLOROOIETHYL ETHER
BLNZALOEHYUE
TRIhETHYLBENZENES
METHYL BENZOATE
2i3-EPOXY-l-PROPANOL
D1ALKYL BENZENES
1%2-OICHLOKOBENZENE
1«4-OICHLOROBENZENE
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
en
N
N
N
N
N
5.0
5.0
1.2E4
1.7E3
7.5E3
7.5E«»
1.5Et»
l.&E!)
1A
4
7B
15
2A
ISA
20
14B
IOC
2A
16B
6A
2A
ALKANES (C>9)
BlS-d-CHLOROISOPROPYLl ETHER
TLTRACHLOROACETONE
TETRAMETHYLBENZENES
1-CHLOROOCTANE
PHENOL
3>N1TROPHENOL
DIMETHYL SULFOXIDE
AMINOTOLUENES (METHYL ANILINES*
HEXACHLOROCYCLOHEXANE (LINOANE)
-CHLOROTOLUENE
ETHYLENE 6LYCOL (1«2-ETHANtOIOL)
HEXACHLOROETHANE
-------
LIST A-3 - UATLR - HEALTH
CO
o
SArtHLE
FRACTION
Cll
Cll
Cll
Cll
Cll
Cll
Cll
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
MATE
VALUk.
3.0Eb
3.BES
6.8Eb
7.5ES
S.tEb
3.HE6
5.HE6
N
N
N
S.O
5,0
5.0
5.0
1.5E3
3.6E4
7.5E«*
8.3E3
2.0E6
3.4E6
CATEGORY SUBSTANCE
IOC ANILINE
IOC DIMETHYLAN1LINE (XYLIDINESJ
9 ACHYLONITR1LE
21 NAPHTHALENb
15 BUTYLBENZENE
15 OIALKYL BENZENES
6A PROPYLENE bLYCOL (1«2-PROPANEOIOL)
1A ALKANES (C>9)
16A BROMO AND UIBROHOBCNZENES
16A BROMOCHLORUBENZENES
18A ALKYL CRESOLS
IttA CRESOLS (METHYL PHENOLS)
20 2-NITROPHENOL
19 2t*t-OICHLOROPHENOL
26A TETRAETHYLLEAO
12 N-NITROSO-DIPROPYLAMINE
17 NITROBENZENE
5A A-HYDROXYTOLUENE (BENZYL ALCOHOL)
15 TETRAHYDRONAPHTHALENE
15 OIALKYL BENZENES
MATE UNITS: MICROGRAMS/LITER
GCll
5,8Eb
N-N1TROSO-OIISOPROPYLAMINE
LCI N 1A ALKANES (C>9)
LCI 1.5E3 26A TLTRAETHYLLFAO
-------
LIST A-3 - WATER - HEALTH
SAMPLE NATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/LITER
LC2 N 16B B1S-ICHLOROMETHYDBENZENE
LC2 N 16A BROPO AND DIBROMOBENZENES
LC2 N 16A BROPOCHLOROBENZENES
LC2 N 22 CYCLOPENTANONAPHTHALENE
LC2 N 22 FLUORENE
LC2 N 15 ».«»»-DIPHENYLBIPHENYL
LC2 1.7E3 2B HEXACHLOROCYCLOPENTADIENE
LC2 7.SEA 16A POLYCHLORINATEO BIPHENYLS
LC2 l.SEt 15 B1PHENYL
LC2 6.1C4 2B HEXACHLOROBUTADIENE
LC2 5.1ES 16A POLYCHLORINATEO BENZENES
LC2 6.8ES 15 INOENE
LC2 7.5E5 21 NAPHTHALENE
LC2 1.0E6 16A CHLORONAPHTHALENES
LC2 2.0E6 15 OIHYDRONAPHTHALENE
LC2 2.0E6 15 TETRAHYDRONAPHTHALENE
LC2 3.HE6 21 DIMETHYL NAPHTHALENES
LC2 3.4E6 15 INDAN
LC2 3.«»E6 21 MONOALKYL NAPHTHALENES
LC3 N 21 ACENAPHTHENE
LC3 N 21 ACENAPHTHYLENE
LC3 N 21 BEN20|6«H,I)PERYLENE
LC3 N 21 CORONENE
LC3 N 22 CYCLOPENTA
-------
LIST A-3 - WATtH • HEALTH
SAMPLE HATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICR06RAMS/LITER
LC3 7.3E3 16A PQLYCHLORINATED BIPHENYLS
LC3 1.3EH 22 BE.N20(B)FLUORANTH£NE
LC3 1. «»£.•» 22 BLNZO(E>FLUOKANTHENE
LC3 1.6E.4 21 DIBtNZOCA, JPYRENE
LC3 2.*»Et 22 INDENO(l«2»3tCD)PYRENE
LC3 £.<*£<» 21 PHENANTHRENE
LC3 2.5m 22 BENZO(K)FLU.ORANTH£NE
LC3 2.7E4 21 METHYL CHRtSENES
LC3 3.3EH 21 CHRYSENE
LC3 3.6Et 21 PICENE
LC3 H.6EH 21 BCM20(E)PYKENE
LC3 5.6E* 21 OIBENZO(A,H»PYRENE
LC3 9,8Ef 22 BE.NZOI JfFLUORANTHENE
LC3 1.UE5 15 TtRpHENYLS
LC3 1.SE5 21 D1BENZIA,C»ANTHRACENE
LCS 2.0E5 22 1»2:5»6"DIBENZOFLUORENE
LC3 2.«*E5 21 BENZ9(6)CHHYSENE
LC3 «f.lE5 21 BENZO«C)PHENANTHRENE
LCS «».6E5 21 METHYLPHENANTHRENES
LC3 S.1E9 16A p>PLY,CHLORINATED BENZENES
LC3 6.6E9 IS INDENE
LCS 8,«»E3 21 ANTHRACENE
LCS -1.0E6 IfiA CHLORONAPHTHALENES
LC3 1.0E6 23A CQLLIQINES
LC3 1.HE6 22 FLUORANTHENE
LC3 3.«E6 15 INOAN
LCS 3.5E6 21 PYRENE
LC4 N 4 BROflOPHENYL PHENYL ETHER
LC*» N 7B CHLORDHYDROXY BENZOPHLNCNE
LC4 N 25 QJBENZOTHIOPHENE
I.CH N 7B UIHYURO(D)CARVONE
LCH N 9 NAPHTHONITPILES
LCH N if 2-CHLORQ-l»2-EPOXYPROPANE
LCM N 25 2i2-BITHlQPHENE
LCH N 7B 5»6-BENZO-9-ANTHRONE
LCI 1.5E4 25 BENZONAPHTHOTHIOPHENE
LC«» 2.0EH 17 «»-NITROBIPHENYL
LCH 7.5EH 17 N1TROBENZENF
LCH 1.8E5 7B CAMPHOR
LC«» 2.0ES 17 l-CHLORO-2-NITRORF.NZt^'E
LCI 2.9ES 17 1-CHLORO-H-NITROHENZENr
LCH 3.5ES 25 BENZO (B ITHlOPHf.NE
-------
LIST A-3 - WATtR - HEALTH
SAMPLE HATE.
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/LITER
LCI 3.BC3 7B ISOPHORONE
LC«» 6.1Eb 7B ACETOPHtNONE
LC5 N 2i» BENZO(B)NAPHTHO(2t3-0)FURAN
LCS N 21 01BENZOFURAN
LCS N 2«» METHYLOIRENZOFURANS
LCS N 2t NAPHTHOFURANS
LCS N 12 N-N1TROSO-UIPENTYLAHINE
LCS N 24 PHENANTHRO<9«10-B»FURAN
LCS N 2H 1.9-BENZOXANTHENE
LCS 1.9EH 12 N-HETHYL-N-NITROSO-ANIUNE
LCS 2.3E1 17 OINITROTOLUENES
LCS 3.6EH 12 N-NITROSO-OIPROPYLAMINE
LCS 6.8Et 17 METHOXYNITKOBENZENES
LCS ».5t5 17 NITROTOtUENES
LCS 1.1E6 12 N-NITROSO-OIPHENYLAniNE
LCS 9.0E.6 2«* TETRAHYDROHURAN
LC6 N 23B BENZOfOQUlNOLINE
LC6 N 23B BENZOIFIQUINOLINE
LC6 N 23B BENZO(H)QU1NOLINE
LC6 N 23B BEN2(A)ACR1DINE
LC6 N 23B DIHYDROACRtDINE
LC6 N 23B OlNLTHYLQUlNOLINESt DINETHVLISOQUINOLINES
LCS N 60 OI-2-EHTYLHEXYL PHTHALATE
LC6 N 23B lNDENO(li2«3-IJ)ISOQUlNOLINE
LC6 N 5C ISOBORNEOL
LC6 N 80 LONG CHAIN ESTERS
LC6 N BO PHE.NYL BENZQATE
LC6 N 13A 1-ANTHRACENETHIOL
LC6 5.0 18C ACENAPHTHOLS
LC6 S.O ISA ALKYL CRESOLS
LC6 5.0 IBB CATECHOL U.2-DIHYDROXYBENZENL)
LC6 S.O 19 CHLORINATED CRESOLS
LC6 S.O 16A CRESOLS (MtTHYL PHENOLS)
LC6 5.0 16A ETHYLPHENOLS
LC6 5.0 1AC INUANOLS
LC6 5.0 18C PHENANTHROLS
LC6 5.0 18A PHLNYLPHENOLS
LC6 5.0 18A POLVALKYL HHENOLS
I.C6 5.0 18A XVLtMOLS (UIMETHYL PHLNOI.S>
LC6 5.0 18C l-N/\PHTHOL
-------
LIST A-s - WATER - HEALTH
SAMPLE
FRACTION
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC7
LC7
LC7
LC7
LC7.
LC7
MATE
VALUE
5.0
5.0
5.0
5.0
5.0
5.0
,5«°
'1.5E3
2.5E3
3. IE A
'3.7E3
7.5E3
1.2E ACRIDINE
IOC ANISIDINES
ISA PERCHLOROMETHANETHIOL
10A HETHYLAHINE
13A BtNZENETHIUL
23C PYRROLE
250 BENZOTHIAZOLE
IOC l,"»-OIAf1INOBENZENE
230 METHYL BENZOTHIAZOLES
80 PMTHALATE ESTERS
23C DIBENZOt A, G)CARBAZOLE
23B BENZIC ) ACRIDINE
23C INOOLE
23C OlBENZOf A.I JCARBAZOLE
238 CUINOLINEI ISOOUINOLINE
SB J-PHENYLE7HANOL
23C BENZO( A )CA«BAZOLE
23C CARBAZOLE
238 DlBtNZ 1C, H) ACRIDINE
100 NiN-DIMETHTLANILINE
23C METHYLINOOLES
23B 2-METHYLQUlNOLINE
10B MORPHOL1NE
23B ACR10INE
SB BORNEOL
5C A-TERPINEOL
6A LONG CHAIN ACIPS
20 DINITROPHENOLS
20 DINITPO-P-CHESOL
19 PENTHACHLOHOf'HENOL
?0 2"A^•I^lO-^,6-DIMITHOPH^MC.I.
20 2-N1TPOPHENOL
MATE UNITS: MICR06RAMS/LITER
-------
LIST A-3 - UATtK - HtALTH
CO
en
SAMPLE
FRACTION
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC8
Lea
LC8
LC6
LC8
LC12
LC12
NYD *
NYO
NTO
NYO
NYO
NYD
NYO
NYD
NYD
NYD
NYO
NYD
NYO
NYO
NYO
NYO
NYO
NYO
NYO
NYO
NYD
MVP
MATE
VALUE
5.0
5.0
3. SEA
8.5E5
9. Of*
9.9E«*
2.0ES
2.1E5
3.8E5
»».5E5
1.3E6
2.1E6
6.8E6
N
N
9.0EH
3.8t5
6.0E5
5.0
5.0
N
N
N
N
N
N
N
N
N
N
1.9E5
1.6E3
2. SLA
S.3t3
1.5EH
3.0E4
«».5E«*
"».5f»
5.2EH
a.ttti
<».7t5
«».9E5
CATEGORY SUBSTANCE
MATE UNITS: MICROGRAMS/LITER
20
20
IOC
IOC
8A
IOC
11
IOC
8A
8C
8B
8A
8C
8B
14A
8A
8A
14A
20
20
26A
26C
26C
26C
26C
268
2A
21
9
23B
26A
8B
26A
11
11
11
26C
9
26R
9
2.^,6-TRIMITROPHENOL
Hi6rUINITRO-0-CRESOL
-------
LIST A-3 • WATER - HEALTH
SAMPLE
FRACTION
WYO
NYD
Sec
see
see
see
sec
see
MATE
VALUE
9.0E3
«U5£fe
N
1»5E^
l*$E*f
2.3m
3.6E9
1.2E6
CATEGORY
26B
5G
136
13A
13A
ISA
138
ISA
SUBSTANCE
FEHROCENf
TERTIARY MUTANOL
DlETHYL SlILflDE
EfHANETHIOL
PlETHANETHlOt
N-HUTANETH10L
DIMETHYL SULFlDt
PHOPAWEfHlOLS
MATE UNITS: MICROGRAMS/LITER
CO
CT>
-------
LIST A-t - WATLR - ECOLOGY
SAMPLE MAIL
FRACTION VALUE CATEGORY SUBSTANCE HATE UNITS: MICROGRAMS/LITER
Cl l.OEH IB ETHYLENE
Cl l.OEb 1A METHANE
C2 N * 1C ACETYLENE * MOT YET ASSIGNED
C2 N 1A ETHANE
C2 l.OES IB PROPYLtNE
C3 N IB BUTYLENES
C3 N 1C BUTYNE
C3 N 11 01AZOMETHANE
C'6 N 10B ETHYLENEIH1NE
C3 N 1C PROPYNE
C3 l.OEd IB BUTADIENES
> C3 1.0E3 10B UlETHYLAHINE
' C3 1.0E4 10B OlntTHYLAMiNE
vj C3 , 1.0L3 7A FO^MALOEHYUE
C6 1.0L5 2A OlChLOROOIFLUOROMEfHAWE
C3 l.OEb 2A METHYL CHLUKIDE
C3 l.OEb 1A PROPANE
C3 l.OEb 2B VINYL CHLORIDE (CHLOROETHf.NE I
-------
LIST A-H - UATLK - LCOLOGY
SAMPLE MATE
FRACTION VALUE CATEGORY SUUSTANCE MATE UNITS: MICROGRAMS/LITER
CH N 7A ACETALUtHYUE
C4 N 10B ETHYLMETHYLAHINE
CH N 2A TfUCHLOROFLlJOROMETHANt
CH 1.0E5 10A ETHYLAMINE
C<* l.OtS 1A BUTANES
C*» 1.0E5 2A METHYL BROMIDE
CS N IB CYCLOHiXADAFNE
CS N IB CtCLOPENTAUIENES
CS N 2t FUHAN
CS N 2A METHYL IODIDE
C5 N IB PtNTENES
CS N 25 THIOHHtNE
C5 N 26A TRIMETHYLAKSINE
CS N 2A 1.2-DI-CHLOKO-1,2-DIFLUOROETHANE
> CS N IDA 3-AfilNOPR.OHANE
(^ CS 1.0E2 7A ACKOLEIN
00 CS l.OEd 2A CARbON TETKACHLORIDE
CS 1.0E3 1A PENTAMES
CS 1.0E3 2A TRICHLOROETHANE
CS ^.5Ed «* CHLOROMEfHYL METHYL ETHER
CS l.OEt 7A PROPIONALDEHYDE
CS 1«OE4 2B 1,1-DICHLOKOETHENE
CS l.OEH 2A lt2-OICHLOROETHANE
CS l.OEH 2B 1.2-OICHLOKOETHENE
CS l.OES 7B ACETONE
CS l.OEij 1A CYCLOPENTANE
C6 N 2A BKOr.OCHLOROMETHANE
Cb N 2A BROhODlCHLUROMETHAiME
C6 N 2A CHLOROFORM (TRICHLOROMETHANE)
C6 N IB CVCLOHEXENt
C6 N IB HtXENES
C6 N 11 N»N«-D1METHYLHYORA2INE
Cfe N 23A P1COLINES
C6 N 9 1-CYANOETHANE
C6 .W •* 2-CHLOROETHYL METHYL tTHER
Cb N Sri 2»6-DIMETHYL-«i-HEPTANOL
C6 N IOC M-AMlNOBIPHFNrL
C6 ~~ .02 26A ALr\YL MEKCURY
C6 1.0L2 7A bbTYKALUEHYDE
Cb —— I.OLA Ib BEl\i^ENt
-------
LIST A-4 - WATER - ECOLOGY
•T
CO
SAMPLE
FRACTION
C6
Cb
C6
C6
C6
C6
C6
Cfa
C6
C6
C6
C6
C6
C6
C6
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
ca
C6
ca
CB
C6
ca
ce
ce
c«
C8
MATE
VALUE:
1.UE4
1.0E3
1.0E4
i. at A
l.Ott
1.0E<*
1.0E.3
1.0Et>
l.OLb
1.0E3
i.oet)
l.OEb
l.OEb
1.0E5
l.OEb
N
N
N
IM
N
N
N
N
N
N
1.0E1
l.OEt
l.OtH
l.OEH
l.OES
N
N
N
N
N
N
N
N
N
N
CATEGORY SUbSTANCE
1A CtCLOHtXANL
2A DICHLOKOPKUPANES
2B OICHLOKOPHUPEUES
7A 3-HETHYLBUlANAL
5A 1-HROPANOL
5B 2-PHOPAMOL (ISOPROPYL ALCOHOL)
9 ACLTONITRILE
7B DUTANONE
10A BUTYLAMINES
5A ETHANOL
IB HEPTENES
1A HLXANES
SA HETHANOL
5C TERTIARY PLNTANOL
58 2-BUTANOL
2A BROnOBUTANES
f CHLOROETHYL ETHYL ETHER
if CHLOROHETHYL ETHYL ETHER
6B HYOKOXYBEMOIC ACID
H 1-CHLORO-H2-OXETANE
H lil'-OICHLURODIETHYL ETHER
H ltl»-DlCHLOROHETHYL ETHER
9 lt3-OlOXANE
3 2-METHOXY BIPHENYL
8C 6-HLXANELACTAM (E-CAPKOLACTAH)
5A ISOBUTYLALCOHOL
3 ISOPROPYL ETHER
80 METHYL METHACRYLATE
3 l.H-DIOXANt
1A HEPTANES
00 AUIPATES
6A BENZOIC AC 10
23A COLLIOINES
2A DiriROMOUICHLOROMETHANE
6A FORMIC ACIU
6A LUNG CHAIN ACIDS
6A MALLIC ACIU
13B MtTHYL UISULFIDE
2b MEFHYLTHIOHHEWES
1A OCTANES
MATE UNITS: MICROGRAMS/LITER
-------
LIST A-"+ - WATtR - ECOLOGY
SAMPLE rtAlt
FRACTION VALUE CATEGORY SUBSTANCL MATE UNITS: MICR06RAMS/LITER
CB N bB PtNTANOLS (SECONDARY)
C8 N 23A PHtNYL PYHlOINES
C8 N 3 2-t:THYL-<»-1CTHYL-l« 3-D10XOLANES
Ctt ltOL2 IbA CHLOKO«tNZt.l\/E
Cd 1.0t3 15 ETHYL btNZtNE
CB l.Of-4 2B TtTKAChLOHUETHLNE
C8 i.Qt-A 15 TOLUENE
C8 l.Otd 68 l-ehLOKO-2»3-EPOXYHHOMANE (A-tPICHLOROHYOrtIM
C6 l.OE-5 IDA 1«2-OIAMINUETHAME
C8 l.OtH IDA CVCLOHEXYLAMINE
C8 1.OEt 2A METHYLENE CHLORIDE (UICHLOKONETHANE)
. C6 l.OEH SA PLNTANOLS (PRIMARY)
CB l.OEt 23A PYHIOINE
C8 l.OEb 5A N-BUTANOL.
C9 N 80 ADIPATES
> C9 N IbA BROMO AND UIBROMOBENZENES
L C9 N 23A CHLORCPYRIUINE
O C9 N 25 OlMETHYLTHtOPHENES
C9 N 13B OIPHENYL SULFIDE
C9 N 1A NONANES
C9 N 12 N-^MTROSO-UIMETHYLAMINE
C9 N 10A PHOPANOLAMlNE
C9 N H 1,2-DICHLOHODIISOPROPYL ETHER
C9 N * 1»2-D1CHLONOETHYL ETHYL ETHEK
C» N 16A 2-GHLOROTOLUFNE
C9 1-.OE.3 15 rSOPROPYL BENZENE
C9 1.0E3 15 PROPYL BENZENE
C9 1.0E5 15 STYRENE
C9 1.0E3 15 X-YLENES
-------
LIST A-f - VJATEK - ECOLOGY
SAMPLE
FRACTION
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
CIO
cio
CIO
CIO
CIO
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
MATE
VALUE
N
N
N
N
N
N
N
N
N
N
N
N
N
N
1.0E2
1.0E2
1.0E2
5.0E2
5.0E2
1.0E3
l.OEt
l.OEt
1.0E1
N
N
N
N
N
N
N
N
N
1.0E2
1.0t2
1.UE2
5.0E2
CATEGORY SUBSTANCE
BO AUIPATES
1A ALKANES 9»
H A-CHLOKOBU1YL ETHYL ETHER
7A BENZALOEHYUE
2«» BENZOFUKAN
2A BKOhOFOrtM (TRIBROMOMETHANE)
23A CHLOKOPYRIUINE
23A [Jl AND POLYSU8ST1TUTEO PYFUDINES
60 Mt-THYL BEN^OATE
12 N-NITROSO-UIETHYLAttINE
25 TRI AND TETRArtETHYU THIOPHtNES
15 TRIMETHYLBLNZENES
16A ItJ-DIChLOKOBENZENE
6B, 2.3-EPOXY-l-PROPANOL
22 DICYCLOPENTADIENE
16A 1«2-OICHLOKOBENZENE
16A 1«H>DICHLOROBENZEN£
16B 1.4-UIMYDRUXYBEN2ENE
19 2-CHLOKOPHENOL
15 D1ALKYL BENZENES
10A ETHANOLAMINE
H 2»2«-DlCHLOROOIETHYL ETHER
6B 3-HYDROXYPKOPANOIC ACID LACTONE
1A ALKANES (C>9)
IOC AMINOTOLUENES
-------
LIST A-«» - WATLR - ECOLOGY
ro
SAMPLE
FRACTION
Cll
Cll
Cll
Cll
Cll
Cll
Cll
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
MA1E
VALUE
5.0E2
1.0E4
1.0E3
1.0E5
1.0E1
l.OE*
l.OEb
N
N
N
N
1.0E2
5.0E2
5.0E2
5.0E2
5.0E2
1.0E3
l.OEA
1.0L3
1.0E1
CATEGORY SUBSTANCE
20 3*NlTROfHEUOL
9 ACKYLONITR1LE
IOC ANILINE
15 D1ALKYL BENZENES
6A ETHYLENE GUYCOL (1 .2-ETHANEDIOL)
IS TETRAHETHYLBEN2ENES
6A PROPYLENE liLYCOL (1,2-PROPANEDIOL>
1A ALKANES (C>9)
16A BKOnO AND DIBROMOBENZENES
16A BROMOCHLOROBENZENES
12 N-NITROSO-OIPROPYLAHINE
26A TETRAETHYLLEAD
ISA ALKYL CRESOLS
16A CRESOLS JHLTHYL PHENOLS)
20 2-NITROPHENOL
19 2i<*-DlCHLOROPHENOL
15 OIALKYL BENZENES
17 NITROBENZENE
15 TETRAHYORONAPHTHALENE
5A A-HYDROXYTULUENE (BENZYL ALCOHOL)
MATE UNITS: MICROGRAMS/LITER
GCll
12
N-NITROSO-OIISOPROPYLAMINE
LCI N 1A ALKANES (C>9)
LCI 1.0E2 26A TtTRAETHYLLEAD
-------
LIST A-4 - hATLH - ECOLOGY
SAMPLE MATL
FRACTION VALUt CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/LITER
LC2 N IS B1PHENYL
LC2 N 16B BIS- (CHLOROpiETHYL) BENZENE
LC2 N 16A SKOHO AND 01BKOH08ENZENES
LC2 N 16A BKUMOChLOROBENZENES
LC2 N 16A CMLORONAPHTHALENES
LC2 N 22 CYCLOPENTANONAPHTHALENE
LC2 N 15 D1HYORONAPHTHALENE
LC2 N 21 DIMETHYL NAPHTHALENES
LC2 N 22 FLUORENE
LC2 N 2B HEXACHLOROBUTADIENE
LC2 N 2B HtXACHLOROCYCLOPENTADIENE
LC2 N 15 INUAN
LC2 N 15 1NOENE
LC2 N 21 HCJNOALKYL NAPHTHALENES
LC2 N 15 H."»'-OIPHENYLBIPHENYL
LC2 .01 16A POLYCHLORINATEO BIPHEMYLS
LC2 1.0E2 21 NAPHTHALENE
> LC2 1.0E2 16A POLYCHLORINATED BENZENES
*. LC2 ItOEd 15 TETRAHYOROIMAPHTHALENE
LC3 N 21 ACENAPHTHENE
LC3 N 21 ACENAPHTHYLENE
LC3 N 21 ANTHRACENE
LC3 N 21 BENZO(A)PYKENE
LC3 N 22 BENZO(B)FLUORANTH£NE
LC3 N 21 BtNZO(C)PHtNANTHRENE
LC3 N 22 BENZO(E)FLUORANTH£NE
LC3 N 21 BENZO(E)PYK£NE
LC3 N 21 BLNZO(G)CHKYSENE
LC3 N 21 BLNZO(C«H«JL)PERYL£NE
LC3 N 22 8£N20(J>FLUORANTHENE
LC3 N 22 BENZO(K)FLUORANTHENE
LC3 N 21 BLNZ(A>ANTHRACENE
LC3 N 16A CHLORONAPHTHALENES
LC3 N 21 ChRYSENE
LC3 N 23A COLLIDINES
LCi N 21 CORONENt.
LC3 N 22 CYCLOPENTA(DEF)PH£NANTHPENt
LC3 N 21 OlfaENZOlA, )PYRENE
LC3 N 21 OlBLNZO(AtH)PYRENE
LC3 N 21 01BENZO(A<1)PYKENE
LC3 N 21 UlBLNZ(A,C)ANTHKACt.NE
LC3 N 21 DIBENZ(AiH)ANTHRACEN'E
-------
LIST A-H - WttTfcR - ECOLOGY
SAMPLE MATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS! MICROGRAMS/LITER
LC3 N 21 DIMETHYL PYRENES
LG3 N 22 FLUOHANTHENE
LC3 N 15 INOAN
LC3 N lb INOtNE
LC3 N 22 INUENO(li2»3«CU)PYKLNE
LC3 N 21 METHYL CHRYSENES
LC3 N 21 MtTHYLPHLNANTHRENES
LC3 N 23A MONOSUBSTITUTED ALKYL PYRIDINES
LC3 N 21 NAPHTNACENL
LC3 N 21 PHtlNANTHKFNE
LC3 N 21 PHENYL NAPHTHALENES
LC3 N 21 PlCtNE
LC3 N 21 PYRtNE
LC3 N 15 TtRPHEIMYLS
LC3 N 22 TRiBENZYLENEBENZENE (TKUXENE)
LC3 N 21 TRIPNENYLENE
LC3 N 21 1-METHYLPYRENE
LC3 N 22 1.2-bENZOFLUORENE
LC3 N 21 lt2-BENZONAPHTHACENE
LG3 N 22 l«2:5i6-DIBENZOFLUOR£NE
LC3 IM 22 2t3-BENZOFLUOHBNE
LC3 N 21 2«7-OIMLTHYLANTHRACENE
LC3 N 22 3-nETHYL-CHOLANTHRE.ME
LC3 N 15 «f»H«-DIPHENYLBlPHENYL
LC3 N 21 7«12-CIMETHYLBEN2
-------
LIST A-4 - WA1fc.K - ECOLOGY
SAMPLE MATE
FRACTION VALUL CATEGORY subsr/\uct MATE UNITS; MICROGRAMS/LITER
LC4 1.0E3 17 NITROBENZENE
LC4 1.0E4 17 l-CHLORO-2-NITROBENZE.NE
LCS N 24 BENZO(B»NAPHTHO«2.3-D)FURAN
LCS N 24 DIBEMZOFUKAN
LCS N 17 MtTHOXtNITKOBENZENES
LCS N 24 MtTHYLOlBENZOFURANS
LCS N 24 NAPHTHOFURANS
LCS N 12 N-METHYL-N-NITROSO-ANIL1NE
LCS N 12 N-NITROSO-UIPENTYLAhlNE
LCS N 12 N-NITROSO-OIPhENYLAMINE
LCS N 12 N-N1TROSO-UIPKOPYLAMINE
LCS N 24 PHENANTHRO(9tlO-B)FURAN
LCS N 24 TETRAHYDROFURAN
LCS N 24 1<9-BENZOXANTHENE
LCS 1.0E5 17 OINITROTOLUENES
> LCS 1.0E3 17 NITROTOLUENES
4*.
LC6 N 23B ACRIDINE
LC6 N IOC ANISIDINES
LC6 N 5C A-TERPINEOL
LC6 N ISA BENZENETHIOL
LC6 N 230 BENZOTHIAZOLE
LC6 N 23C BENZO|A)CAKBAZOLE
LC6 N 23B BENZO(C)QU1NOLINE
LC6 N 23B BENZO(F)OU1^IOLI^E
LC6 N 23B BENZO(H)QUINOLII»E
LC6 N 23B BE.NZ(A>ACR1DINE
LC6 N 23B BENZtCIACRlOINE
LC6 N SB BCJRNEOL
LC6 N 23C CAKBAZOLE
LC6 N 23C OlbtNZOU.MCARBAZOLE-
LC6 N 23C DIBtNZO(A.l>CARBAZULE
LCb N 23C DlbtNZO(C,U»CARBA20LE
LC6 N 23B DlbtNZ
-------
LIST A-H - WATER - ECOLOGY
•ft.
CTl
SAMPLE
FRACTION
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC*
LC6
LC6
LC6
LCfe
LC6
LC6
LC6
LC6
LC7
LC7
LC7
LC7
LC7- .
LC7
MATE
VALUE
i\l
N
N
N
N
N
N
N
N
N
N
N
N
1.5
1.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
S.OC2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
S.OE2
5.0&2
i.ota
l.OEt
N
N
N
to
N
N
CATEGORY SUBSTANCE
5C
60
230
23C
100
13A
60
23C
23B
13A
58
IOC
238
60
IOC
16C
16A
168
19
16A
16A
16C
18C
16A
16A
18A
16C
168
188
18C
16C
16A
16C
16A
10A
108
8C
6A
8C
SB
6A
6A
MATE UNITS: MICROGRAMS/LITER
LONG CHAIN ESTERS
MLTHVL BEN^OTHIAZOLES
HETHYLINOOLES
N.N-DIHETHYLANILINE
PLRCHLOROMtThANETHIOL
PHENYL BENZOATE
PYRROLE
QUINOLINEJ ISOQUINOLINE
1-ANThRACENETHIOL
1-^PHENYtETHANOL
lr«*-OIAMINOBENZEN£
2-METHYLQUINOL1NE
PHTHALATE ESTERS
2-AftINONAPHTHALENE
ACENApHTHOLS
ALKYL CRESOLS
CATECHOL (1,2-OIHYDROXYBENZENE )
CHLORINATED CRESOLS
CRESOLS (METHYL PHENOLS)
ETHYLPHENOLS
INOANOLS
PHENANTHROLS
PHENYLPHENOuS
POLYALKYL PHENOLS
XYLENOLS (OjHETHYL PHENOLS)
l-NAPHTHOL
1,2.3.TRZHYOROXYBENZENES
1.«»-DIHYOROXYBENZENE
2-HYOROXYDlBENZOFUKAN
2-HYDROXYFLUORENE
2-METHOXYPHENOL
2*NAPHTHOL
2«2*-OIHYDKOXYOIPHENYLS
HETHYLAHINt
HURPHOL1NE
ACETAHIOE
BEN20IC AClO
FORhAMIDE
HYOROXYACETIC ACID
LONG CHAlfv ACIDS
PHTHALIC ACID
-------
LIST A-«t - V.'ATLR - ECOLOGY
•>
JS>
SAMPLE
FRACTION
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC8
LC6
LC6
tea
tee
LC12
LC12
MATt
VALUE
N
N
N
1.0E2
1.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
1.0E5
N
N
N
N
1.0E3
5.0E2
5.0E2
CATEGORY SUBSTANCE
11 1.2-DJPHENYLHYDRAZlNE
IOC 3.3«-DICHLOROaEN2IOINE
IOC ** I*' -METHVLENE-bIS- ( 2-CHLOROAWILINE )
IOC BEN2ID1NE (t, 1* •-DIAMINOBIPHENYL )
IOC 1-AMINONAPHTHALENE
20 DINITROPHENOLS
20 DINITRO-P-CRESOL
19 PENTHACHLOKOPHENOL
20 2-AhINO-«t,fa-DINITROPHENOL
20 2-NITROPHENOL
20 2<<*«6-TKINlTROPHENOL
20 H.6-OINITRO-0-CRESOL
6A ACETIC ACIU
1HA BENZENESULFONIC ACID
8A PHTHALIC ACID
8B 6-AHINOHEXANOIC ACIO
1<»A 9.10-ANTHRAQUINONEOISULFONIC ACIO
8A ACETIC ACID
20 5-NITROPHCMOL
20 <»-NITROPHENOL
MATE UNITS: MICROSRAMS/LITER
-------
LIST A-4 - WATtR - ECOLOGY
SAMPLE NATE
FRACTION VALUE CATEGORY SUbSTA'lCE MATE UNITS: MICR06RAMS/LITER
NYD * N 26A ALKYL STIB1NES * NOT YET DETERMINED
NYO N 9 BEN20NITRILE
NYD N 9 BUTYRONITRILE
\YD N 6B B-PKOPIOLACTONE
NYD N 26C COhPLEXEO COPPER
MYD N 26C COMPLEXEO IRON
NYD N 26C COMPLEXED NICKEL
NYO N 26C COrtPLEXED UN
NYO N 26C COMPLEXEO £INC
NYD N 266 DIBEN2E CHHOMIUM
NYO N 2A DlHROHOCHLOROhETHANE
NYD N 26B FLRROCENE
MYD N 11 MONOHETHYLHYURAZINE
NYD N 26B NICKLLOCENE
NYO N 11 N.N-DIMETHTLHYORA2INE
NYD N 26A ORGAN06ERMANES
> NYO N 26A OKGANOTIN
i NYD N 21 PLRYLENE
C» wVD N 26A TETRAMUHYtLEAD
NYO N 9 TETRAMETHYLSUCCINONITRILE
NYD N 11 -UlhETHYLAMINOAZOBENZENE
NYD N 9 1«3-DICYANO-L-HYOKOXYBU1ANE
NYD N 23b 2.4-BENZ-H-AZAFLUOHEMt.
NYD l.OEb 5C TLRTIAKY BUTANOL
SGC N 13B D1ETHYL SULFIDE
SGC N 13B DIMETHYL SULFIOE
SGC N 13A ETHANETHIOL
SGC N 13A MLTHANtTHIOL
SGC N 13A N-BUTANETHIOL
SGC N 13A PROPANETHIOLS
-------
LIST A-b - SOLID - HtALTH
SAMPLE MATE
FRACTION VALUE CATEGORY SUbSTAIMCE MATE UNITS: MICR06RAMS/GRAM
Cl 9.6E«t 1A METHANE
Cl 1.7E& 18 ETHYLENE
C2 1.6E5 1C ACETYLENE
C2 1.8E5 1A ETHANE
C2 2.6E5 IB PKOPYLENE
N o * NOT YET ASSIGNED
c3 1.0E1 10B ETHYLENEIMINE
C3 1.2E1 11 OIAZONETHANE
C3 «t.6El 7A FORMALOtHYUE
> C3 7.6E1 2B VINYL CHLOKIDE (CHLOROETHENE)
ja, C3 5.HE2 10B D1MLTHYLAMINE
*> C3 2.2E3 10B 01ETHYLAMINE
C3 6,«tEd 2A METHYL CHLORIDE
C3 - 5.0EY 1C PROPYNE
C3 6.6E«» IB BUTADIENES
C3 1.5E& 2A DICHLORODIFLUOROMETHANE
C3 2.Bt.5 1A PROPANE
-------
LIST A-5 - SOLID - HEALTH
SAMPLE MATE.
FRACTION VALUE CATEGORY SUBSTAfcCL MATE UNITS: MICROGRAMS/GRAM
CH N 10B ETHYLMETHYLAMINE
C C5 1.HE2 25 THIOPHtNE
^, C5 1.1E3 «t CHLOROMETHtL METHYL ETHER
O C5 1.1E3 7A PROPIONALOE.HYUE
C5 1.4E9 2A TRICHLOKOE1HANE
C5 1.8E4 2A CARBON TETRACHLORIDE
C5 6.0E4 IB CYCLOPENTADIENES
CS 6.0EA 2A 1.2-DICHLOKOETHANE
C5 7.8E9 2B lil-OICHLOKOETHENE.
C5 2.2EH 2B 1.2-DICHLOKOETHENE
CS 5,*tE 2B UICHLOROPROPENES
"C6 H.5E^ 10A BUTYLAMINES
C6 — -1.16.3 23A PICOLINLS
C6 1.2E3 2A CHLOROFORM (TKICHLOROMETHANE)
C6'^- 1,<*E3 5C TERTIARY PtNTANOL
-------
LIST A-b - SOLiU - HEALTH
SAMPLE
FRACTION
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
G6
C6
C7
C7
C7
C7
G7
C7
C7
C7
C7
C7
G7
C7
C7
C7
C7
ce
ca
C8
ca
ca
C8
C8
Cfl
C8
ca
MATE
VALUE
2.1E3
3.3EA
H.8E3
7.6E3
LIE*
1.1E1
1.2E1
1.1E1*
1.5E4
1.8E4
s.om
3.0E1
3.2E
-------
LIST A-b - SOLID - HEALTH
SAMPLE
FRACTION
CB
C8
C6
ca
C8
ca
ca
CB
C8
C8
C8
ca
ca
ca
C9
C9
C9
C9
C9
C9
C9
C9
C9
C9
C9
C9
C9
C9
C9
HATE
VALUE
7.0E2
7.6E2
1.2E3
2.1E3
4.2E3
<».&E3
7. BE 3
1.1EH
l.ltt
1.1EH
1.1EH
1.3E«»
2.0EH
<* . HEH
N
N
N
N
.OH
1.H.E2
5.6E2
1.9Ea
2.9E3
3.8E5
6.6EA
7.5E4
1.3E4
1.3E4
3.2E1
CATEGORY SUBSTANCE
MATE UNITS: MICROGRAMS/GRAM
25
IDA
IDA
23A
8 A
5A
2A
16A
5A
SB
15
15
2B
1A
16 A
12
23A
8D
is
13B
10A
15
16A
15
15
1A
METHYLTHIOHHFNES
li2-OIAhINOETHANE
CYCLOHEXYLAMINE
CULLIOINES
BLNZOIC ACID
N-BUTANQL
METHYLENE CHLORIDE (OICHLOROMETHANE)
PENTAN01.S I PRIMARY)
PENTANOLS < SECONDARY)
TOLUENfc
ETHYL BENZLNE
TETRACKUOROETHENE
OCTANES
BROMO AND UIBROMOBENZENES
DI1ETHYI.THIOPHENES
1.2-DICHLORODIISOPROPYL ETHER
ii2-DICHLOROETHYL ETHYL ETHETR
N-NITROSO-DIMETHYLAMINE
CHLOBOPYRIDINE
ADIPATES
ISOPROPY.L BENZENE
DIP.HENYL SULFIOE
P^OPANOLAMINE
PROHY.L BENZENE
2-CHLOKOTOLUENE
STY.RENL
XYLENES
NONANES
-------
LIST A-5 - SOLID - HEALTH
in
CO
SAMPLE
FRACTION
CIO
CIO
CIO
cio
CIO
CIO
CIO
cio
CIO
CIO
CIO
CIO
cio
cio
CIO
CIO
CIO
CIO
CIO
cio
CIO
CIO
CIO
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
Cll
MATE
VALUE
N *
N
N
N
N
.01
.01
3,6
9.6
1.4E2
1.5E2
1.8E2
4.8E2
5.6E2
8.2E2
9.0E2
1.8E3
3.6EA
4.6E3
5.2E3
6.8E3
9.0E3
1.4E4
N
N
N
N
N
.01
.01
1.5
2.4
3.0
1.5E1
3.0E2
3.0E2
CATEGORY SUBSTANCE
1A ALKANES (C>9)
4 A-CHLOROBUTYL ETHYL ETHER
24 BtNZOFURAN
25 TRI AND TETRAMETHYL THIOPHLNES
16A ItS-DlCHLOKOBENZENE
18B li3-OIHYDROXYBENZENE
19 2-CHLOROPHENOL
12 N-NITROSO-UIETHYLAMINE
8B 3-HYDROXYPKOPANOIC ACID LACTONE
23A CHLOROPYRIOINE
2A BROMOFORM (TRIBROMOMETHANE)
10A ETHANOLAMINE
22 DICYCLOPENTADIENE
80 AUIPATES
23A 01 AND POLYSUBSTITUTED PYRIDINES
-OICHLOROOIETHYL ETHER
7A BENZALOEHYUE
15 TRIMETHYLBENZENES
80 METHYL bENZOATE
6B 2.3-EPOXY-l-PROPANOL
15 DIALKYL BENZENES
16A 1,2-DICHLOKOBENZENE
16A 1<4-OICHLOKOBENZENE
1A ALKANES (C>9>
4 BIS-(I-CHLOROISOPROPYL) ETHER
7B TETRACHLOROACETONE
15 TETRAMETHYLBENZENES
2A 1-CHLOROOCTANE
18A PHENOL
20 3-NITROPHENOL
16B -CHLOROTOLUENE
14B DIMETHYL SULFOXIDE
IOC AMINOTOLUENES (METHYL ANILINES)
2A HEXACHLOROCYCLOHLXANE
-------
LIST A-5 - SOLID - HEALTH
>
in
SAMPLE
FRACTION
Cll
Cll
Cll
cii
Cll
Cll
Cll
C12
C12
C12
C12
era
C12
C12
C12
C12
C12
C12
C12
C12
MATE
VALUE
6.0E.2
7.5E2
1.HE3
1.5EA
6.6E3
6. 6E A
1.1E4
N
N
N
.01
.01
.01
.01
9.0
7.2E1
1.5E2
1.7E3
4.0E4
6.8E3
CATEGORY SUBSTANCE
MATE UNITS: MICROSRAMS/GRAM
IOC
IOC
9
21
IS
15
6A
1A
16A
16A
ISA
ISA
20
19
26A
12
17
5A
15
15
ANILINE
01 METHYL AN 1-LINE (XYLIUINES)
ACRYLONITRiLE
NAPHTHALENE
BUTYLBENZENE
D1ALKYL BENZENES
PROPYLENE liLYCOL (1,2-PROPANEOIOL)
ALKANES (C>9)
BROhO AND DIBROMOBENZENES
BROnOCHUOROBENZENES
ALKYL GRESOLS
CRESOLS (METHYL PHENOLS)
2-Nl'TROPHENOL
Tt.T'R»AET'HYLLEAD
N^riUTROSO-DXPHbPYLAMINE
NITROBENZENE
A-HfDROXYTOLUENE (BENZYL ALCOHOL)
tETRAHYORONAPHTHALENE
DIALKYL BENZENES
6C11
1.2E5
12
N-NITROSO-OIISOPROPYLAMINE
LCI N 1A ALKANES (C>9)
LCI 3.0 26A TtTRAETHYLLEAO
-------
LIST A-5 - SOLID - HEALTH
SAMPLE HATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROG RAMS /GRAM
LC2 N 16A POLYCHLORINATED B1PHENYLS
LC2 N 16B BIS-CCHLOROMETHYDBENZENE
LC2 N 16A BROMO AND UIBROMOBENZENES
LC2 N 16A BROHOCHLOROBENZENES
LC2 N 22 CYCLOPENTANONAPHTHALENE
LC2 N 22 FLUORENE
LC2 N 15 »f.H'-OIPHENYLBIPHENYL
LC2 1.4 IS INDENE
LC2 3.H 2B HEXACHLOROCYCLOPENTAOIENE
LC2 1.5E1 16A CHLORONAPHTHALENES
LC2 3.0E1 15 B1PHENYL
LC2 1.2E2 2B HEXACHLOROBUTADIENE
LC2 1.0t3 16A POLYCHLORINATEO BtNZENES
LC2 1.5E3 21 NAPHTHALENE
LC2 H.OE3 15 OIHYDRONAPHTHALENE
LC2 "t.OEa 15 TETRAHYDRONAPHTHALENE
LC2 6.6E3 21 DIMETHYL NAPHTHALENES
> LC2 6.6E5 15 INUAN
01 LC2 6.8E3 21 MONOALKYL NAPHTHALENES
cn
LC3 N 16A POLYCHLORINATED BIPHENYLS
LC3 N 21 ACLNAPHTHENE
LC3 N 21 ACENAPHTKYLENE
LC3 N 21 BENZO(6,H,I)PERYLENE
LC3 N 21 cOrtONENt
LC3 N 22 CYCLOPENTA(DEF)PHENANTHRENE
LC3 N 21 DIMETHYL PTRENES
LC3 N 23A MONOSUBSTITUTEO ALKYL PYRIUINES
LC3 N 21 NAPHTHACENL
LC3 N 21 PHENYL NAPHTHALENES
LC3 N 22 TRIBENZYLENEBENZENE (THUxENE)
LC3 N 21 TRIPHENYLENE
LC3 N 21 1-METHYLPYKENE
LC3 N 22 1«2-BENZOFLUORENE
LC3 N 21 1»2-BENZONAPHTHAC£NE
LC3 N 22 2t3>BENZOFLUORENE
LC3 N 21 2.7-UIMETHYLANTHRACENE
LC3 N 15 U.H'-DIPHENYLBIPHENYL
LC3 .003 21 DlBENZ
-------
LIST A-b - SOLID - HEALTH
un
CT>
SAMPLE
FRACTION
LC3
LC3
LG3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
UC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LCI
LCH
LCH
LCH
LC«*
LCH
LCH
LC«»
LC<»
LC«»
LCf
v LC<«
LC«* — ,_
LC<«
LC«»
HATL
VALUE
1.3
l.H
1.5E1
2.7E1
2.8EI
3.2E1
H.8E1
H.flEl
U.9E1
5.1E1
6.6E1
7.5E1
9.1E1
1.1E2
2.0E2
2.6E2
3.0L2
-------
LIST A-5 - SOLID - HEALTH
SAMPLE MATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/GRAM
LC4 7.5L2 7B ISORHORONE
LC4 1.2E3 7B ACE10PHENONE
LCS N 24 BENZO(B)NAPHTHO(2t3-0)FURAN
LCS N 24 OIBENZOFURAN
LCS N 24 MtTHYLOIBENZOFURANS
LCS N 24 NAPHTHOFURANS
LCS N 12 N-N1TROSO-UIPENTYLAHINE
LCS N 24 PHENANTHKO<9,10-B)FURAN
LCS N 24 1»9-BENZOXANTHENE
LCS 3.8E1 12 N-METHYL-N-NITROSO-ANILINE
LCS 4.SE1 17 DINITROTOLUENES
LCS 7.2E1 12 N-NITROSO-OIPROPYLAMINE
LCS 1.4E2 17 METHOXYNITKOBENZENES
LCS 9.0E2 17 N1TROTOLUENES
LCS 2.2E3 12 N-NITROSO-UIPHENYLAMINE
^ LCS 1.8E4 24 TETKAHYOROFURAN
cn
LC6 N 23B BENZOCOQUINOLINE
LC6 N 23B BENZO(F)QIUNOLINE
LC6 N 23B BENZO
-------
LIST A-5 - SOLID - HEALTH
SAMPLE HATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/GRAM
l_C6 .01 18B 1«2,3-THIHYDROXYBENZENES
LC6 .01 16B l."»-UIHYORUXYBENZ£NE
LC6 .01 16C 2-HYOKOXYUlBENZOFUKAN
LC6 .01 1BC 2-HYOROXYFLUORENE
LC6 .01 16A 2-METHOXYPHENOL
LCfa ,01 18C 2-NAPHTHOL
LC6 .01 ISA 2t2«-OIHYDKOXYDIPHENYLS
LC6 3.0 23C D1BENZO(C,U)CARBAZOLE
LC6 5.0 IOC 2-AMINONAPHTHALENC
LC6 6.7 23B DIBENZACKIOINE
LC6 7.4 23B DIBtNZ(AiJ)ACRIDINE
LC6 1.5E1 IOC ANISIDINES
LC6 2.4E1 13A PERCHLOROMETHANETHIOL
LC6 3.6E1 10A METHYLAHINt
LC6 6.2E1 ISA BENZENETHIOL
LC6 B.1E1 23C PYRROLE
> LC6 1.3E2 23D BLNZOTHIAZOLE
i, LC6 1.1E2 230 METHYL BENIOTHIA20LES
00 LC6 1.HE2 IOC 1»H-DIAMIN08ENZENE
LC6 1.5E2 60 PHTHALATE LSTERS
LC6 1.6E2 23C OIBENZOIA.S)CARBAZOLE
LC6 3.2E2 23B BENZ(C)ACRlDINE
LC6 3.3E2 23C INOOLE
LC6 3.6E2 23C OlbENZOIAt 1JCARBAZOLE
LC6 f.7E2 238 QUINOLINEl ISOQUINOLINE
LC6 5.*fE2 SB 1-PhENYLETHANOL
LC6 S.6E2 23C BENZO(AICAKBAZOLE
LC6 6.8E2 23C CARBAZOLE
LC6 6.9E2 23B OIBtNZ(C,H)ACRIDINE
LC6 7.5E2 100 NtN-DlMETHYLANILINE
LC6 1.HE4 23C METHYLINDOLES
LC6 1.7E3 23B 2-METHYLQUlNOLINE
LC6 2.1E3 108 MORPHOLINE
LC6 2.7E3 23B ACRIDINE
LC6 2.6E.3 SB BOKNEOL
LC6 5.8EJ 5C A-TERPINEOL
LC7 N 6A LONG CHAIN ACIDS
LC7 .01 20 DINITROPHENOLS
LC7 .01 20 D1N1TRO-P-CRESOL
LC7 .01 19 PENTHACHLOKOPHENOL
LC7 .01 20 2-AMINO-«*,b-OINITROPHENOL
LC7 .01 20 2-N1TROPHENOL
-------
LIST A-5 - SOL10 - HEALTH
SAMPLE MATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/GRAM
LC7 .01 20 2i«»i6-TRINlTKOPHENOL
LC7 .01 20 t.b-OINITRO-0-CHESOL
LC7 6.6 IOC «H«*«-METHVLENE-BIS-(2-CHLOKOANILINE)
LC7 1.7E1 IOC 1-AMNONAPHTHALENE
LC7 1.BE2 8A PHTHALIC ACID
LC7 2.0E2 IOC 3t3»-DICHLOROBENZIOINE
LC7 4.0E2 11 lt2-OIPHENtLHYDRAZINE
LC7 H.2E2 IOC BENZIOINE U,<*'-OIAMINOBlPHENtD
LC7 7.6E2 8A ACETIC ACID
LC7 9.0E2 8C FORMAMIOE
LC7 2.6E3 6B HYUKOXYACETIC ACID
LC7 t.2£3 8A BLNZOIC AC10
LC7 l.HEH 8C ACETAHIOE
LC8 N 8B 6-AMINOHEXANOIC ACID
LC8 N 1HA 9tlO-ANTHRAQUINONEOISULFONIC ACID
> LC8 1.8E2 6A PHTHALIC ACID
^ LC8 7.6E2 6A ACETIC ACIU
10 LC6 1.2t3 1«»A BLNZENtSULFONIC ACID
LC12 .01 20 3-NITROPHENOL
LC12 .01 20 (f-NITROPHENOL
-------
LIST A-5 - SOL10 - HEALTH
SAMPLE MATE
FRACTION VALUE. CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/6RAM
NYO * N 26A ALKYL STIBINES * NOT YET DETERMINED
NYO N 26C COMPLETED IRON
NYO N 26C COMPLEXEO NICKEL
NYO N 26C COMPLEXEO TIN
NYO N 26C COMPLEXED ZINC
NYD N 268 OIBE.NZE CHKOMIUM
NYO N 2A DIBROMOCHLOROMETHANE
NYO N 21 PERYLENE
NYO N 9 l,4-DICYANO-|_-HYDROXYBUTANt
NYO N 23B 2i3-B£NZ-H-AZAFLUORLNE
NYO 3.0 26A ORGANOTIN
NYO 3.2 68 B-PROPIOLACTONE
NYO H.5 26A TETRAMETHYLLEAO
NYO 1.1EI 11 MONOMETHYLHYORAZINE
NYO 3.0E1 11 NtN-DIMETHYLHYDRAZINE
NYO 6.0E1 11 -UIMETHYLAMINOAZOBENZENE
NYO 9.0E1 26C COMPLEXED COPPER
> NYO 9.0E1 9 TLTRAMETHYLSUCC1NONITRILE
CT, NYO 1.0E2 26B NICKELOCENt
O NYD 6.8E2 9 BUTYRONITKILE
NYO 9.4E2 26A ORGANOGERMANES
NYO 9.BE2 9 BENZONITRILE
NYD l.SEi 2bB FtRHOCLNE
NYD 9.0EA 5C TLKTIAHY BUTANOL
SGC N 13B D1ETHYL SULFIDE
SGC 3.0E1 13A ETHANETHIOL
SGC 3.0L1 13A MbTHANLTHIUL
SGC H.5E1 13A N-BUTANETHlOL
SGC 7.2E2 13B DIMETHYL SULFIDE
SGC 2.1E4 13A PROPANETHIULS
-------
LIST A-6 - SOLID - ECOLOGY
SAMPLE HATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/GRAM
Cl 2.0E1 IB ETHYLENE
Cl 2.0E2 1A METHANE
C2 N * 1C ACETYLENE * NOT YET ASSIGNED
C2 N 1A ETHANE
C2 2.0E2 IB PROPYLENE
C3 N IB BUTYLENES
C3 N 1C BUTYNE
C3 N XI DIAZOHETHANE
C3 N 10B ETHYLENEIMINE
C3 N 1C PROPYNE
C3 2.0 IB BUTADIENES
> C3 2.0 10B DIETHYLAMINE
Oi C3 2.0 10B D1HETHYLAM1NE
-1 C3 2.0 7A FORMALDEHYDE
C3 2.0E2 2A DICHLORODIFLUOROMETHANE
C3 2.0E2 2A METHYL CHLORIDE
C3 2.0E2 1A PROPANE
C3 2.0E2 2B VINYL CHLORIDE (CHLOROETHENE>
-------
LIST A-6 - SOLID - ECOLOGY
er>
ro
SAMPLE
FRACTION
CH
CH
CH
C«*
CH
C«»
CS
C5
CS
CS
CS
CS
CS
CS
CS
CS
CS
CS
CS
CS
CS
CS
CS
CS
CS
CS
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
HATE.
VALUE
N
N
N
2.0
2.0E2
2.0E2
N
N
N
N
N
N
N
N
N
.20
2.0
2.0
2.0
9.0
2.0E1
2.0E1
2.0E1
2.0E1
2.0E2
2.0E2
N
N
N
N
N
N
N
N
N
N
N
4.E-5
.20
2.0
CATEGORY SUBSTANCE
7A ACKTALDEHYUE
10B ETHYLnETHYLAMlNE
2A TKICHLOROFLUOROHETHANE
IDA ETHYLAMNE
1A BUTANES
2A METHYL BROMIDE
IB CYCLOHEXADIENE
IB CYCLOPENTAUIENES
2<* FUKAN
2A METHYL IODIDE
IB PENTENES
25 THIOPHENE
26A TRIhETHYLAHSINE
2A 1.2-DICHLOKO-1,2-DIFLUOROETHANE
10A 3-AMINOPROPANE
7A ACROLEIN
2A CARBON TETKACHLORIDE
1A PENTANES
2A TRICHLOROETHANE
<* CHLOROMETHtL METHYL ETHER
7A PROPlONAuDtHYDE
2B 1,1-DICHLOHOETHENE
2A li2-OICHLOKOETHANE
2B li2-DICHLOROETHENE
7B ACETONE
1A CVCLOPENTANE
2A BROnOCHLOROHETHANE
2A BROMODICHLOROMETHANE
2A CHLOROFORM (TRICHLOROMETHANE)
IB CYCLOHEXENL
IB HLXENES
11 NiN*-DIMETHYLHYDRAZINE
23A PICOLINES
9 1-CYANOETHANE
«» 2-CHLOROETHYL METHYL ETHER
SB 2.6-DIMETHtL-H-HEPTANOL
IOC 4-ANINOBIPHENYL
26A ALKYL MERCURY
7A BUTYRALUEHVDE
15 BENZENE
MATE UNITS: MICROGRAMS/GRAM
-------
LIST A-fc - SOLID - ECOLOGY
CO
SAMPLE
FRACTION
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C6
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
C7
ca
C8
ca
ca
ca
ca
ca
ca
ca
ca
MATE
VALUE
2.0
2.0
2.0.
2.0
2.0E1
2.0E1
2.0E2
2.0E2
2.0E2
2.0E2
2.0E2
2.0E2
2.0E2
2.0E.2
2.0E2
N
N
N
N
N
N
N
N
N
N
2.0E1
2.0E1
2.0E1
2.0E1
2.0C2
N
N
N
N
N
N
N
N
1*
N
CATEGORY SUBSTANCE
1A CYCLOHEXANt
2A D1CHLOROPROPANES
28 01CHLOROPROPEMES
7A 3-Hfc.THYLBUTAMAL
5A 1-PKOPANOL
SB 2-PROPANOL (ISOPROPYL ALCOHOL I
9 ACE10NITRILE
7B BUTANONE
10A BUTYLAHINES
5A ETHANOL
IB HEPTENES
1A HLXANES
5A HLTHANOL
5C TLRTIAKY PENTANOL
SB 2-BUTANOL
2A BROftOBUTANES
it CHLOROETHYL ETHYL ETHER
H CHLOROHETHYL ETHYL ETHER
8B HYDROXYBENZOIC ACIO
H 1-CHLORO-H2-OXETANE
H Itl'-DlCHLOROOIETHYL ETHER
H l«l'-DlCHLOROnETHYL ETHER
3 li3-DIOXAN£
3 2-METHOXY 8IPHENYL
6C 6-HLXANELACTAM (E-CAPROLACTAM)
SA ISObUTYLALCOHOL
3 ISOPROPYL tTHER
BO HtTHYL METHACRYLATE
3 lt«*-DIOXANt
1A HEPTANES
80 AOIPATES
6A BENZOIC ACID
23A COLLIDINES
2A 018ROMODICHLOROMETHANE
8A FORMIC ACIU
6A LONG CHAIN ACIDS
6A MALEIC ACIU
13B METHYL DISULFIDE
25 METHYLTHIOHHENES
1A OCTANES
MATE UNITS: MICROGRAMS/GRAM
-------
LIST A-6 - SOLID - ECOLOGY
SAMPLE MATE
FRACTION VALUE CATEGORY SUUMANCE MATE UNITS! MICROGRAMS/GRAM
C8 N SB PENTANOLS (SECONDARY)
C8 N 23A PHENYL PYRIDINES
C8 N 3 2-tTHYL-l-hETMYL-li 3-DIOXOLANtS
C8 .20 16A CHLOROBfcNZLNE
OB 2.0 15 ETHYL BENZENE
C8 2.0 2B TETRACHLOROETHENE
C8 2.0 IS TOLUENE
Cd 2.0 6B l-CHLOKO-2«3-EPOXYPROPANE (A-EPICHLOROHYDRIN)
C8 2.0 10A li2-DIAMINOETHANE
C8 2.0E1 10A CYCLOHEXYLAMINE
C8 2.0E1 2A METHYLENE CHLORIDE (DICHLOKOMETHANE)
C8 2.0E1 5A PENTANOLS (PRIMARY)
C8 2.0E1 23A PYR10INE
Ca 2.0E2 5A N-BUTANOL
C9 N 80 ADIPATES
_ C9 N 16A BROMO AND DIBROMOBENZENES
I C9 N 23A CHLOROPYRIOINE
g C9 N 25 D1HETHYLTHIOPHENES
C9 N 13B OIPHENYL SULFIDE
C9 N 1A NONANES
C9 N 12 N-NITROSO-UIMETHYLAMINE
C9 N 10A PROPANOLAMINE
C9 N 1 1.2-DICHLOKODIISOPHOPYL ETHER
C9 N 1 lt2-DICHLOKOETHYL ETHYL ETHER
C9 N 16A 2-CHLOROTOLUENE
C9 2.0 15 ISOPROPYL BENZENE
C9 2.0 15 PROPYL BENZENE
C9 2.0 15 STYRENE
C9 2.0 15 XYLENES
CIO N 8D ADIPATES
CIO N 1A ALKANES (C>9)
CIO N H A-CHLOROBUTYL ETHYL ETHER
CIO N 7A BENZALULHYUE
CIO N 21 BENZOFURAN
CIO N 2A BROMOFORM (TRIBROMOMETHANE)
CIO N 23A CHLOROPYRIOINE
CIO N 23A DI AND POLYSUBSTITUTED PYRIOINES
CIO N 8D METHYL BENZOATE
CIO N 12 N-NITROSO-OIETHYLAMINE
CIO ~~ N 25 TRI AND TETRAHETHYL THIOPHENES
CIO N 15 TKIMETHYLBtNZENES
-------
LIST A-6 - SOLID - ECOLOGY
SAMPLE HATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS! MICROGRAMS/GRAM
CIO N 16A 1.3-DICHLOKOBENZENE
CIO N 6B 2«i-EPOXY-l-PROPANOL
CIO .20 22 DICYCLOPENTADIENE
CIO .20 16A 1.2-DICHLOROBENZENE
CIO .20 16A 1,«»-OICHLOKOBENZENE
ClO 1.0 IBB 1.3-DIHYDROXYBEN2ENE
CIO 1.0 19 2-CHLOROPHk.NOL
CIO 2.0 15 OIALKYL BENZENES
CIO 2.0E1 10A ETHANOLAMINE
CIO 2.0E1 H 2«2«-DlCHLORODIETHYL ETHER
CIO 2.0£1 BB 3-HYOROXYPKOPANOIC ACID LACTONE
Cll N 1A ALKANES (C>9)
CH N IOC AMINOTOLUENES (METHYL ANILINES)
Cll N
-------
LIST A-6 - SOLID • ECOLOGY
SAMPLE
FRACTION
MATE.
VALUE
CATEGORY SUBSTANCE
MATE UNITS: MICROGRAMS/GRAM
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
C12
N
N
N
N
.20
1.0
1.0
1.0
1.0
2.0
2.0
2.0
2.0E1
1A
16A
16A
12
26A
16A
ISA
20
19
15
17
IS
SA
ALKANES (C>9)
BROHO AND OIBHOMOBENZENES
BROMOCHLORUBENZENES
N-NITROSO-UIPROPVLAMINE
TETRAETHYLLEAD
ALKYL CRESOLS
CRESOLS (METHYL PHENOLS)
2-NITROPHENOL
2ft-OICHLOKOPH£NOL
OIALKYL BENZENES
NITROBENZENE
TLTRAHYORONAPHTHALENE
A-HYDROXYTOLUENE (BENZYL ALCOHOL)
GC11
12
N-NITROSO-DIISOPROPYLAMINE
LCI
LCI
.20
1A ALKANES (C>9)
26A TtTRAETHYLLEAD
-------
LIST A-6 - SOLID - ECOLOGY
SAMPLE MATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/GRAM
LC2 N 16A POLYCHLORINATEO BIPHENYLS
LC2 N 15 B1PHENYL
LC2 N 16B BIS-(CHLOROMETHYL)BENZENE
LC2 N 16A BROMO AND OIBROMOBENZENES
LC2 N 16A BROHOCHLOROBENZENES
LC2 N 22 CYCLOPENTANONAPHTHALENE
LC2 N 15 OIHYORONAPHTHALENE
LC2 N 21 DIMETHYL NAPHTHALENES
LC2 N 22 FLUORENE
LC2 N 2B HEXACHLOROBUTADIENE
LC2 N 2B HE.XACHLOROCYCLOPENTADIENE
LC2 N 15 INDAN
LC2 N 15 INUENE
LC2 N 21 MONOALKYL NAPHTHALENES
LC2 N 15 LC2 .20 16A POLYCHLORINATEO BENZENES
CD LC2 2.0 15 TLTRAHYDRONAPHTHALENE
•«J
LC3 N 16A POLYCHLORINATED BIPHENYLS
LC3 N 21 ACENAPHTHENE
LC3 N 21 ACENAPHTHYLENE
LC3 N 21 ANTHRACENE
LC3 N 21 BENZOUIPYRENE
LC3 N 22 BENZO(B>FLUORANTH£NE
LC3 N 21 BENZO(C)PHE.NANTHRENE
LC3 N 22 BENZO(E)FLUORANTHENE
LC3 N 21 BENZO(E)PYR£NE
LC3 N 21 BENZO(ti)CHKYSENE
LC3 N 21 BEN20(G,H,I)PERYLENE
LC3 N 22 BENZO(
-------
LIST A-6 - SOLID - ECOLOGY
en
oo
SAMPLE
FRACTION
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
UC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
LG3
LC3
LC3
LC3
LC3
LC3
LC3
LC3
ICH
LC«*
LCt
LC"»
LCI
LC<»
LCH
LCt
LCH
LC*»
LCH
LC«»
LCH
LCt
LCH
MATE
VALUE
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
l.E-5
.20
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
CATEGORY SUBSTANCE
21 DIMETHYL PYRENES
22 FLUORANTHENE
15 INOAN
15 INDENE
22 INOENO(1«2«3»CO)PYRENE
21 METHYL CHRYSENES
21 HLTHYLPHENANTHKtNES
23A MONOSUBSTITUTED ALKTL PYRIUINES
21 NAPHTHACENL
21 PHENANTHRENE
21 PHEMYL NAPHTHALENES
21 P1CLNE
21 PYHLNE
15 TLRPHENYLS
22 TRIBEN2YLENEBENZENE (TRUXENE)
21 TRIPHENYLENE
21 1-HETHVLPYKENE
22 lt2-BENZOFLuORENE
21 1.2-BEN20NAPHTHACENE
22 lt2I5,6»DlBENZOFLUORENE
22 2.3-BENZOFLUORENE
21 2«7-DIMETHYLANTHRACENE
22 3-«fcTHYL-CHOLANTHRENE
15 *»«*»-OlPHENYLBlPHENYL
21 7»12-DIMETMYLBENZ(A)ANTHRACENE
16A CHLORONAPHTHALENES
16A POLYCHLORINATED BENZENES
76 ACETOPHE.NONE
25 BENZONAPHTHOTHIOPHENE
25 BENZO(B)THIOPHENE
•f BKOhOPHENYL PHENYL ETHER
7B CAMPHOR
7B CHLOROHYDROxY BENZOPHENONE
25 DIBENZOTHIOPHENE
7B DIHYORO(D)CARVONE
7B ISOPHORONE
9 NAPHTHONITRILES
17 l-CHLORO-4-NITROBENZENE
H 2-CHLORO-l«2-EPOXYPROPANE
25 2«2-BlTHIOHHENE
17 H-NITROBIPHENYL
7B 5»6-BENZO-V-ANTHRONE
MATE UNITS: MICROGRAMS/GRAM
-------
LIST A-6 - SOLID - ECOLOGY
:>
10
SAMPLE
FRACTION
LCH
LC<»
LC5
LC5
LC5
LC5
LC5
LCS
LC5
LCS
LCS
LCS
LCS
LCS
LCS
LCS
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
LC6
HATE
VALUE
2.0
2.0E1
N
N
N
N
N
N
N
N
N
N
N
N
2.0
2.0
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
CATEGORY SUBSTANCE
17 NITROBENZENE
17 l-CHLORO-2-NITROBENZENE
21 BENZOACRIOINE
23B OIBENZCAtJIACRIDINE
23B DIBENZ(C,H>ACRIOINE
23B OIHYDROACR1DINE
23B DIMETHYLQUlNOLlNESi OIMETHYLISOQUINOLINES
8D DI-2-EHTYLHEXYL PHTHALATE
23B INUtNO(li2»3-U)ISOQUlNOLINE
23C INOOLE
MATE UNITS! MICROGRAMS/GRAM
-------
LIST A-6 - SOL1U - ECOLOGY
SAMPLE
FRACTION
LCfe
LCfe
LC6
LC6
LCfe
LCfe
LC6
LC6
LCfc
LC6
LC6
LC6
LC6
LCfe
LC6
LC6
LCfe
LC6
LC6
LC6
LC6
LCfc
LC6
LC6
LC6
LC6
i_C6
LC6
LC6
LC6
LCfe
LC6
LCfe
LCfe
LCfe
LCfe
LC7
LC7
LC7
LC7
LC7
LC7
MATE
VALUE
N
N
N
N
N
N
N
N
N
N
N
N
N
.003
.20
1.0
1.0
1.0
1.0
1.0
1*0
1.0
1.0
1.0
1.0
1.0
1.0
1*0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
2.0E1
N
N
N
N
N
N
CATEGORY SUBSTANCE
5C « ISOBORKE.OL
80 LONG CHAIN ESTERS
23D METHYL BEfUOThlAZOLES
23C NETHYLINDOLES
100 N»N-DIMETHYLAMILINE
13A PLRCHLOROMETHANETHIOL
80 PHENYL BEN-fOATE
23C PYRKOLE
23B QUINOLINE! ISOQUINULINE
13A 1-ANTHRACENETHIOL
SB 1-PhENYLETHAWOL
IOC l.t-DIAMINOBENZENE
23B 2-METHYLQUINOLINE
60 PHThALATE ESTERS
.IOC 2-AMINONAPHTHALENE
18C ACENAPHTHOLS
ISA ALKYL CRESULS
18B CATECHOL (1,2-DIHYDROXYBENZENE)
19 CHLORINATEU CRESOLS
18A CKESOLS (METHYL PHENOLS)
18A ETHYLPHENOLS
18C INOANOLS
18C PHENANTHROLS
18A PHCNYLPHENOLS
ISA POLYALKYL PHENOLS
18A XYLENOLS JUIMETHYL PHENOLS*
18C 1-NAPHTHOL
18B 1,2.3-TRIHYDROXYBENZENES
18B l.H-OIHYOROXYBENZENE
18C 2-HYOROXYOlBENZOFURAN
18C 2rHYDROXYFLUOKENE
16A 2-METHOXYPHENOL
18C 2-NAPHTHOL
18A 2.2'-OIHYDKOXYOIPHENYLS
10A METHYLAMINt
10B MORPHOLINE
8C ACETAMIOE
8A BLNZOIC ACID
8C FOKMAHIUE
8B HYOROXYACE1IC ACID
8A LONG CHAIN ACIOS
8A PHTHALIC ACID
MATE UNITS: HICROGRAMS/GRAM
-------
LIST A-6 - SOLID - ECOLOGY
SAMPLE
FRACTION
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC7
LC8
LC8
LC6
LC8
Lea
LC12
LC12
NYD *
NYO
NYD
NYD
NYO
NYD
NYD
NYD
NYO
NYO
NYO
NYO
NYO
NYO
NYO
NYO
NYD
NYO
HATE
VALUE
N
N
N
.20
.20
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
N
N
N
N
2.0
1.0
1.0
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
CATEGORY SUHSTANCE
11 1»2-DIPHENYLHYORAZINE
IOC 3t3»-DICHLOROBENZIDINE
IOC 1i«M-METHYLENE-BIS-C2-CHLOROANILINE)
IOC BENZIDINE Utt'-DlAMINOBlPHENYL)
IOC 1-AniNONAPHTHALENE
20 Q1NITROPHENOLS
20 DINITRO-P-CRESOL
19 PENTHACHLOKOPHENOL
20 2-AhINO--DINlTKOPHENOL
20 2-NITROPHENOL
20 2t«*»6-TRINlTROPHENOL
20 H.6-DINITRO-0-CRESOL
8A ACETIC AGIO
14A BENZENESULFONIC ACID
8A PHTHALIC ACID
6B 6-AHINOHEXANOIC ACID
14A 9«10-ANTHRAQUINONEDISULFONIC ACID
8A ACETIC ACID
20 3-NITROPHENQL
20 «t-NITROPHENOL
26A ALKYL STIBINES
9 BENZONITRILE
9 BUTYRONlTRlLE
8B B-HROPIOLACTONE
26C COHPLEXED COPPER
26C COriPLEXED IRON
26C COHPLEXEO NICKEL
26C COMPLCXED TIN
26C COMPLEXEO ZINC
26B DIdENZE CHKOMIUM
2A DIBROHOCHLOROnETHANE
26B FERROCENE
11 HONOMETHYLHYDRAZINE
26B NICKELOCENE
11 NfN-DIHETHYLHYDRAZINE
26A ORQANOGERMANES
26A ORGANOTIN
21 PERYLENE
MATE UNITS: MICROGRAMS/GRAM
* NOT YET DETERMINED
-------
LIST A-6 • SOLID - ECOLOGY
SAMPLE MATE
FRACTION VALUE CATEGORY SUBSTANCE MATE UNITS: MICROGRAMS/GRAM
NYO N 26A TETKAMETHYLLEAD
NYO N 9 TtTRAMETHYLSUCCINONITRILE
NYD N 11 -D1METHYLAMINOAZOBENZENE
NYO N 9 l»3-DICYANO-L-HYDROXYBUTANt
NYO N 23B 2»3-BENZ-«»-AZAFLUORENE
NYO 2.0E2 5C TERTIARY BUTANOL
SGC N 13B 01ETHYL SULFIOE
S6C N 13B DIMETHYL SULFIOE
SGC N ISA ETHANETHIOL
SGC N 13A HETHANETHIOL
SGC N 13A N-BUTANETH10L
SGC N 13A PROPANETHIOLS
ro
-------
LIST A-7
N = NUT YET ASSIGNED
CHEMICAL CATEGORY
NYD = NOT YET DETERMINED
GASEOUS
HEALTH ECOLOGY
(MICROGM/CU M)
LIQUID
HEALTH ECOLOGY
IMICKOGM/L)
SOLID WASTE SAMPLE
HEALTH ECOLOGY FRACTION
(MICROGM/GRAM)
>
CO
1A METHANE
1A ETHANE
1A PROPANE
1A BUTANES
1A PENTANES
1A HEXANES
1A CYCLOPENTANE
1A CYCLOHEXANE
1A HEPTANES
1A OCTANES
1A NONANES
IA ALKANES 9>
1A ALKANES (C>9)
1A ALKANES (C>9)
1A ALKANES (C>9)
IB ETHYLENE
IB PROPYLENE
IB BUTYLENES
IB BUTADIENES
IB PENTENES
IB CYCLOPENTADIENES
IB HEXENES
IB CYCLOHEXENE
IB CYCLOHEXADIENE
IB HEPTENES
1C ACETYLENE
1C PROPYNE
1C BUTYNE
2A METHYL BROMIDE
2A METHYL CHLORIDE
2A METHYL IODIDE
2A METHYLENE CHLORIDE (DICHLOROMETHANE)
2A bROMOCHLOROMETHANE
2A CHLOROFOKM (TRICHLOROMETHANE)
2A BROMODICHLOROMETHANE
3.3E5
6.1E6
9.0E6
1.1E6
1.8E6
3.6E5
N
1.1E6
1.6E6
1.5E6,
1.1E6
N
N
N
N
5.7E6
8.6E6
N
2.2E6
N
2.0E5
N
1.0E6
N
N
5.3E6
1.7E6
N
S.OLt
2.1ES
B.J>E2
2. fat5
l.lLfc
1.2E5
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
1.0
N
N
N
N
N
ti
N
N
N
LIES
N
N
N
N
N
N
N
N
N
H.9E7
9.2E7
l.«»E8
2.1E7
2.7E7
5.HE6
N
1.6E7
2.1E7
2.2E7
1.6E7
N
N
N
N
8.6E7
1.3E8
N
3.3E7
N
3.0E6
N
1.5E7
N
N
8.0E7
2.5E7
N
9.0E5
3.2Efa
1.3E1
3.9Eb
1.7E7
6.0E5
N
1.0E5
N
1.0E5
1.0E5
1.0E3
1.0E5
1.0E5
1.0E3
1.0E5
N
N
N
N
N
N
1.0E4
1.0E5
N
1.0E3
N
N
N
N
N
1.0E5
N
N
N
1.0E5
l.OES
N
1.0E4
N
N
N
9.8E
-------
LIST A-7
N = NOT YtT ASSIGNED
CHEMICAL CATEGORY
NYD a NOT YtT DtTERMINED
GASEOUS
HEALTH ECOLOGY
(HICROGM/CU M)
LIQUID
HEALTH ECOLOGY
(M1CKOGM/L)
SOLID WASTE SAlPLE
HEALTH ECOLOGY FRACTION
(MICHOGh/GRAM)
2A DI8ROMOCHLOROMETHANE
2A BKOHOFORN (TRIBROMOHETHANt)
2A DIBROMOOICHLOROMETHANE
2A DICHLOROOIFLUOROMETHANE
2A TRICHLOROFLUOROHETHANE
2A CARBON TETRACHLORIDE
2A 1.2-DICHLOROETHANE
2A TRICHLOROETHANE
2A lt2-DICHLORO-l,2-OIFLUOROETHANE
2A HEXACHLOROETHANE
2A DICHLOROPROPANES
2A BROMOBUTANES
2A HEXACHLOROCYCLOHEXANE
2A I-CHLOROOCTANE
2B VINYL CHLORIDE (CHLOROETHENE)
2B li2-OICHLOROETHENE
2B 1»1-DICHLOROETHENE
2B TETRACHLOROETHENE
2B OICHLOROPROPENES
2B HEXACHLOROBUTADIENE
2B HEXACHLOROCYCLOPENTADIENE
3 ISOPROPYL ETHER
3 2-METHOXY BIPHENYL
3 2-ETHYL-"»-METHYL-lt 3-DIOXOLANES
3 1»3-DIOXANE
3 1,4-DIOXANE
H CHLOROMETHYL METHYL ETHER
4 l.l'-DICHLOROMETHYL ETHER
* 2-CHLORO-1.2-EPOXYPROPANE
H 2-CHLOROETHYL METHYL ETHER
-------
LIST A-7
N = NOT YET ASSIGNED
CHEMICAL CATLGORY
NYU = NOT YET DETERMINED
GASEOUS
HEALTH ECOLOGf
(MICROGH/CU M)
UlUUIt)
HEALTH ECOLOGY
•MICROGM/L)
SOLID WASTE SAMPLE
HEALTH ECOLOGY FRACTION
(MICROGM/GRAM)
* BIS-(l-CHLOROISOPROPYL) ETHER
-------
LIST A-7
N = NOT YET ASSIGNED
CHEMICAL CATEGOKY
NYD = NOT YLT Ofc-TERMINED
GASEOUS
HEALTH ECOLOGY
(hlCROGM/CU M)
LIUUID
HEALTH ECOLOGY
(HICROGM/L)
SOLID WASTE SA.1PLE
HEALTH ECOLOGY FRACTION
(MICROGM/GRAH)
78 ACETONE
76 TETRACHLOROACETONE
7B BUTANONE
7B ISOPHOKONE
7B CAMPHOR
78 ACETOPhENONE
7B CHLOROHYOROXY BENZOPHENONE
7B 5i6-BENZO-9-ANTHRON£
7B OIHYDROCOICARVONE
8A FORMIC ACID
6A ACETIC ACID
8A ACETIC ACID
8A MALEIC ACID
8A BENZOIC ACID
8A BENZOIC ACID
8A PHTHALIC ACID
8A PHTHALIC ACID
8A LONG CHAIN ACIDS
8A LONG CHAIN ACIDS
8B HYDROXYACETIC ACID
8B HYOROXYBENZOIC ACID
8B 3-HYDROXYPROPANOIC ACID LACTONE
6B 6-AMINOHEXANOIC ACID
8B B-PROPIOLACTONE
8C FORMAMIOE
8C ACETAMIDE
8C 6-HEXANELACTAM (E-CAPROLACTAM)
8D METHYL METHACRYLATE
80 PHTHALATE ESTERS
80 ADIPATES
80 ADIPATES
80 ADIPATES
80 LONG CHA-IN ESTERS
2.1E6
N
5.9E5
2.5E.1
1.2Et
«*.1EH
N
N
N
9.0E3
2.5E4
2.5E<*
1.0E3
l.fES
1.4E5
6.0E3
6.0E3
N
N
8.8E
-------
N =
LIST A-7
NOT YET ASSIGNED
CHEMICAL CATEGORY
NYD = NOT YET DETERMINED
GASEOUS
HEALTH ECOLOGY
(MICKOGM/CU M)
LIQUID
HEALTH ECOLOGY
IMICROGM/L)
SULIO WASTE SAMPLE
HEALTH ECOLOGY FRACTION
(MICROGM/GRAM)
3>
•-J
60 METHYL BENZOATE
60 PHENYL BENZOATE
80 OI-2-EHTYLHEXYL PHTHALATE
9 ACETONITRILE
9 ACRYLONITRILE
9 1-CYANOETHANE
9 BUTYRONITRILE
9 1,3-DICYANO-L-HYDROXYBUTANE
9 BENZONITRILE
9 NAPHTHONITRILES
9 TETRAMETHYLSUCCINONITRILE
10A METHYLAMINE
IDA CTHYLAMINE
10A ETHANOLAMINE
1QA 1.2-OIAMINOETHANE
10A 3-AMINOPROPANE
IDA PROPANOLANINE
IDA BUTYLAMINES
10A CYCLOHEXYLAMINE
10B ETHYLENEIMINE
10B DIMETHYLAMINE
10B ETHYLMETHYLAMINE
10B OIETHYLAMINE
10B HORPHOLINE
IOC ANILINE
IOC AHINOTOLUENES (METHYL ANILINES)
IOC OIMETHYLANILINE (XYLIOINES)
IOC ANISIOINES
IOC Itt-DIAMINQBENZENE
IOC t-AMINOBIPHENYL
IOC BENZIOINE (f.t'-DIAMINOBIPHENYL)
IOC 3t3»-OICMLOROBENZIDIN£
IOC tt4»-METHYLENE-BlS-(2-CHLOROANlLlNE)
IOC 1-AM1NONAPHTHALENE
IOC 2-AMINONAPHTHALENE
1.5E5
N
N
7.0EH
4.5EH
1.8E3
2.3EH
N
3.2E4
N
3.0E3
1.2E3
1.8E4
6.0E3
2.5E«*
N
1.3ES
l.SEt
H.OEt
3.3E2
1.8E4
N
7.5Ef
7.0EH
1.9EH
1.1E2
2.5EH
5.0E2
H.SE3
1.3E3
mE«t
6.6E3
2.2E2
5.6E2
1.7E2
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
2.3E6
N
N
1.1E6
6.8E3
2. TEH
3.*E5
N
«f.9E5
N
-------
LIST A-7
N = NOT YET ASSIGNED
CHEMICAL CATEGORY
NYD z NOT YET DETERMINED
GASEOUS
HEALTH ECOLOGY
(MICROGM/CU H)
LIQUID
HEALTH ECOLOGY
(MICKOGM/L1
SOLID WASTE SAMPLE
HEALTH ECOLOGY FRACTION
(MICROGM/GRAM)
10D
N.N-OIMETHYLANILINE
2.5E4
3.8E5
7.5E2
LC6
-J
00
11 OIA20METMANE
11 nONONCTHYLHYORAZINE
11 N«N-OIMETHYLHYDRAZINE
11 N.N'-DIHETHYLHYDRAZINE
11 Ita-OIPHETNYLHYDRAZlNE
11 -OIMETHYLAMINOAZOBENZENE
12 N-NITROSO-DIMETHYLAMINE
12 N-NITROSO-DIETHYLAMINE
12 N-NITROSO-OIPROPYLAMINE
12 N-NITROSO-OIPROPYLAMINE
12 N-NITROSO-OIISOPROPYLAMINE
12 N-NITROSO-OIPENTYLAMINE
12 N-METHYL-N-NITROSO-ANILINE
12 N-NITROSO-OIPHENYLAMINE
ISA METHANETHIOL
ISA ETHANETHIOL
13A PROPANETHIOLS
ISA N-BUTANETHIOL
ISA BENZENETHIOL
ISA 1-ANTHRACENETHIOL
ISA PERCHLOROMETHANETHIOL
13B DIMETHYL SULFIDE
13B OIETHYL SULFIDE
138 OIPHENYL SULFIDE
13B METHYL OISULFIOE
l
-------
LIST A-7
s NOT YET ASSIGNED
CHEMICAL CATEGORY
NYD = NOT YET DETERMINED
GASEOUS
HEALTH ECOLOGY
(hlCKOGM/CU M»
LIQUIU
HEALTH ECOLOGY
(MICROGM/L)
SOLID WASTE
HEALTH ECOLOGY FRACTION
(MICROGM/GRAM)
•vj
<£>
15 BENZENE
15 TOLUENE
15 ETHYL BENZENE
15 STYRENE
15 PROPYL BENZENE
15 ISOPROPYL BENZENE
15 INOAN
15 INDAN
15 INOENE
15 INOENE
15 BUTYLBENZENE
15 BIPHENYL
15 tt4«-OXPHENYLBIPHENYL
15 «f.H«-DIPHENYLBIPHENYL
15 XYLENES
15 OIALKYL BENZENES
15 OZALKYL BENZENES
15 OIALKYL BENZENES
15 TETRAHYORONAPHTHALENE
15 TETRAHYORONAPHTHALENE
15 OIHYDRONAPHTHALENE
15 TERPHENYLS
15 TRIMETHYLBENZENES
15 TETRANETHYLBENZENES
16A CHLOROBENZENE
16A BROMO AND DIBROMOBENZENES
16A BROMO AND OIBROMOBENZENES
16A BROMO ANO OIBROMOBENZENtS
16A BROMOCHLOROBENZENES
16A BROMOCHLOROBENZENES
16A 1*2-OICHLOROBENZENE
16A lt3-OICHLOROBENZENE
16A li«f-OICHLOROBEN2ENE
16A POLYCHLOKINATEO BENZENES
16A POLYCHLOHINATED BENZENES
16A 2-CHLOHOTOLUENE
16A CHLORONAPHTHALENES
16A CHLORONAPHTHALENES
16A POLYCHLOHINATED BIPHENYLS
3.0E3
3.8E5
f.tEb
<».2E5
2.2E&
6.3E4
2.3Eb
2.3E5
«».5E<*
«t.5E1
2.3E5
1.0E3
N
N
if.HES
2.3E5
2.3E5
2.3E5
1.3E5
1.3E5
1.3ES
9.0C3
1.2E5
N
3.5E5
N
N
N
N
N
3.0E&
N
H.5E5
3.1EH
3.1EH
2.5E5
6.9EH
6.9EH
S.OC2
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
t.5Et
5.6E6
b.bEb
6.3E6
3.3Eo
9.5E3
3.«f£6
3. HE*
6.6E5
6.8E5
3 .IE*
1.5E<+
N
N
6.5E6
3.fEb
3.UE6
3.<»Eb
2.0E6
2.0E6
2.0E6
1.HE5
1.8E6
N
S.SEb
N
N
N
N
N
4.5E6
N
b.SEb
5.1EJ)
5.1E&
3.8E6
1.0E6
1.0E6
7.5E3
1.0E3
1.0E3
1.0E3
1.0E3
1.0E3
1.0E3
N
N
N
N
N
N
N
N
1.0E3
1.0E3
1.0E3
1.0E3
1.0E3
1.0E3
N
N
N
1.0E
-------
LIST A-7
N = NUT YET ASSIGNED
CHEMICAL CATEGORY
NYU = NOT YET DETERMINED
GASEOUS
HEALTH ECOLOGY
(-MICKOGM/CU M)
LIQUID
HEALTH ECOLOGY
(HICROGM/L)
SOLID WASTE SAMPLE
HEALTH ECOLOGY FRACTION
CMICROGM/GRAM)
16A
POLYCHLORINATED BIPHENYLS
5. Of 2
7.5E3
.01
LC3
16B -CHLORQTQLUENE
16B BIS-(CHLORQMETHYL)BENZENE
17 NITROBENZENE
17 NITROBENZENE
17 <»-NITROHJ,PHENYL
17 l-CHLORO-2-NITROBENZENE
17 1-CHLORO-H-NITROBENZENE
17 METHOXY.NITROBENZENES
17 NITROTOLUENES
17 DINITROTQLUENES
ISA PHENOL
18A CRESOLS (METHYL PHENOLS)
ISA CRESOLS (METHYL PHENOLS)
ISA 2-METHOXYPHENOL
16A ETHYLPHENOLS
ISA PHENYLPHENOLS
18A 2t2»-OIHYDROXYDIPHENYLS
ISA XYLENOLS |DIMETHYL PHENOLS)
18A ALKYL CRESOLS
1BA ALKYL CRESOLS
ISA POLYALKYL PHENOLS
16B CATECHOL U,2-DIHYOROXYB£NZENE)
18B li3-OIHYUROXYBENZENE
18B liOlHYDROXYBENZENE
18B l«2i3-TRIHYOROXYBENZENES
18C 1-NAPHTHOL
18C 2-NAPHTHOL
16C PHENANTHROLS
18C INDANOLS
18C ACENABHTHOLS
18C 2-HYDKO«YFLUORENE
1BC 2-HYURQXYOIBENZOFURAN
5.0E3
N
5.0E3
5.0E3
1.3E3
T.5E3
l!5E3
1.9E1
2l2Et
N
2.3E
-------
LIST A-7
N = NOT YET ASSIGNED
CHEMICAL CATEGORY
NYD = NOT YET DETERMINED
GASEOUS
HEALTH ECOLOGY
(MICROGM/CU M)
LIQUID
HEALTH ECOLOGY
(MICROGH/L)
SOLID WASTE SAMPLE
HEALTH ECOLOGY FRACTION
(HICROGh/GRAM)
CO
19 2-CHLOROPHENOL
19 2«H-DICHLOROPHENOL
19 PENTHACHLOROPHENOL
19 CHLORINATED CRESOLS
20 2-NITROPHENOL
20 2-NITROPHENOL
20 3-NITROPHENOL
20 3-NITROPHENOL
20 «-NITROPHENOL
20 OINITROPHENOLS
20 U.6-DINITRO-0-CRESOL
20 OINITRO-P-CRESOL
20 2-AHINO-H.6-OINITROPHENOL
20 2tt<6-TRINlTROPHENOL
7.0E3
5.0E2
2.3Ef
5.&E4
5.8EH
2.0E4
2.0EH
1.6E1
2.0E2
6.8E2
1.0E2
N
N
N
N
N
N
N
N
N
N
N
N
N
N
5.0
5.0
b.O
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0L2
.01
.01
.01
.01
.01
.01
.01
.01
.01
.01
.01
.01
.01
.01
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
CIO
C12
LC7
LC6
C12
LC7
Cll
LC12
LC12
LC7
LC7
LC7
LC7
LC7
21 NAPHTHALENE
21 NAPHTHALENE
21 MONOALKTL NAPHTHALENES
21 PHENYL NAPHTHALENES
21 DIMETHYL NAPHTHALENES
21 ACENAPHTHENE
21 ACENAPHTHYLENE
21 ANTHRACENE
21 2t7-OIMETHYLANTHRACENE
21 PHENANTHRENE
21 METHYLPHENANTHRENES
21 NAPHTHACENE
21 B£N2(A)ANTHRACENE
21 7i12-OIMETHYLBENZ(A)ANTHRACENE
21 BENZOCUPHENANTHRENE
21 CHRYSENE
21 METHYL CHRYSENES
21 TRIPHENYLENE
21 PYRENE
21 l-METHYLPYRENE
21 DIMETHYL PYRFNFS
21 li2»BEN/ONAPHTHACEN£
21 BEN20(G)CHRYSENE
5.0E«»
5.0E<*
2.3E5
N
2.3E5
N
N
5.6E1
N
1.6E3
3.UE4
N
.26
2.7Et
2.2E3
1.6E3
N
2.3E5
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
7.5E5
7.5E5
3.HE6
N
3,<»E6
N
N
S.HE5
N
2,tEH
H.6E5
N
6.7E2
3.9
H.lEb
3.3E1*
2.7E4
N
3.5E6
N
N
N
2.
-------
LIST A-7
N = NOT YET ASSIGNED
CHEMICAL CATEGORY
NYO = NOT YET DETERMINED
GASEOUS
HEALTH ECOLOGY
(hlCROGM/CU h)
LIUDIU
HEALTH ECOLOGY
ANTHRACENE
BENZO(A»PYRENE
BEN?0(E»PYRENE
PERYLENE
PICENE
OIBENZO(A,H)PYRENE
DIBENZO ( A * I »PYRENE
OIBENZOtAt )PYRENE
BENZO(G,H«IJPERYLENE
CORONENt
DICYCLPPENTADIENE
FLUORENE
CYCLOPENTANONAPHTHALENE
2,3-BENZOFLUORENE
FLUORANTHENE
lt2-8ENZOFl_UORENE
CYCLOPENTACOEFJPHENANTHRENE
BENZO(K)FLUORANTHENE
BENZO(E)FLUORANTHENE
BENZO(J»FLUORANTHENE
l,2:5i6-OIBENZOFLUORENE
BENZO«b)FLUORANTHENE
3-BETHYL-»CHOl,ANTHRENE
INOENQt 1,2,3* GO )PYRENE
TRIBENZYLENEBENZENE (TRUXENE)
PYRIOINE.
PICOLINES
HONOSUBSTITUTED ALKYL PYRIOINES
PHENVL PYRIDINES
CHLOROPVKIOINE
CHLOROPYRIOINE
COLLXDINES
COLLIOINES
DI AND POLYSUBSTITUTED PYRIDINES
9.9E3
.09
.02
3.0E3
N
2.SE3
3.7L3
1.163
N
N
QUINOLINEJ ISOQUINOLINE
2-METHYLQUINOLINE
N
N
H.8E3
4.6E3
6.9E«+
6.9E4
2.7E«»
1.6EH
5.5EH
N
N
N
N
N
N
N
N
N
N
N
1.6E1
N
N
N
9.0Et
N
N
1.6E3
9.0E2
6.5E3
1.3EH
9.0E2
3. a
1.6E3
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
1.5E5
l.H
.30
1.6Ef
N
3.6Et
S.6E4
6.5E2
1.6E
-------
LIST A-7
N = NOT YLT ASSIGNED
CHEHICAL CATEGORY
NYO = roOT YET lit TERMINEu
GASEOUS
HEALTH ECOLOGY
(MlCKOfan/CU Ml
L1UUIU
HEALTH ECOLOGY
(M1CKOGM/L)
SOLID WASTE SAMPLE
HEALTH ECOLOGY FRACTION
(MICROGfi/GRAM)
00
CO
23B OIHETHYLQUINOLINES, DINLTHYLISOQUINOL1NES
23B ACRIDINE
238 DIHYOROACRIDINE
23B BENZOtClflUINOLINE
238 BENZOtFIQUXNOLINE
23B BENZO(H)QUINOLINE
23B BENZ(A)ACR10INE
23B BEMZtOACRIDINE
238 OIBENZ(AtJ)ACRIDINE
23B OI8£NZ(AtH)ACRIDINE
23B DIBENZ(C.H)ACRIDINE
23B 2t3-B£NZ-*-AZAFLUORENE
23B INOENO(l,2f3-IJ)ISOQUlNOLINE
23C PYRROLE
23C XNDOLC
23C HETHYLINOOLES
23C CARBAZOLE
23C BENZO(A)CARBAZOLE
23C PIBENZOtAtDCARBAzOLE
23C DI8ENZO(CtO)CARBAZOLC
23C OlBENZO(AiG>CARBAZOLE
230 BENZOTHIAZOLE
230 HETHYL BENZOTHIAZOLES
2<» FURAN
24 BENZOFURAN
2J
2
<4.bt3
2.AEH
N
N
N
N
to
to
to
N
N
N
N
N
N
N
N
N
N
N
N
N
to
to
N
to
N
N
N
N
M
IM
N
N
1.1E6
M
N
N
N
N
1.6E5
3.7E3
3.HE4
3.5ES
N
N
-------
LIST A-7
N = NOT YET ASSIGNED
CHEMICAL CATEGORY
NYO = NOT YET DETERMINED
GASEOUS
HEALTH ECOLOGY
(MICROGM/CU M)
LIQUID
HEALTH ECOLOGY
(MICHOGM/L)
SOLID WASTE SAMPLE
HEALTH ECOLOGY FRACTION
(MICROGP/liRAM)
25 TKI AND TETRAMETHYL THIOPhENES
25 2t2-BITHIOPHENE
25 BENZO(B»THIOPHENE
25 DIBEN20THIOPHENE
25 BENZONAPHTHOTHJQPHENE
N
N
2.3EH
N
9.9E2
N
N
N
N
N
N
N
3.5E5
N
1.5EH
N
N
N
N
N
N
N
7.0L2
N
3.Oil
r\
M
M
N
N
CIO
LCI
LCH
LCI
LC
-------
LIST A-8
N = NOT YET ASSIGNED
SSMS/AA CATEGOKY
NYO = NOT YET DETERMINED
GASEOUS
HEALTH ECOLOGY
(MICKOGM/CU M)
LIQUID
HEALTH ECOLOGY
(MICKOGM/L)
SOLID WASTE SAMPLE
HEALTH ECOLOGY FRACTION
(MICROGM/GRAH)
27 LITHIUM, LI
27 LITHIUM ION, LI+
27 LITHIUM FLUORIDE, LlF (AS LD
27 LITHIUM CARBONATE, LI2CO3
27 LITHIUM HYDRIDE, LIH
2.2E1
2.2E1
2.2E1
2.2E1
2.SE1
N
N
N
N
N
3.3E2
3.3E2
3.3E2
3.3E2
3.8E2
3.8E2
3.8E2
3.BE2
3.8E2
N
.70
.70
.70
.70
.75
.75
.75
.75
.75
N
SSMS
SSHS
SSMS
SSMS
SSMS
26 SODIUM, NA
28 SODIUrl ION,
26 SODIUM HYDROXIDE, NAOH
5.3E1
5.3E4
2.0E3
N
N
N
a.oEb
8.0E5
3.0Et
N
N
N
1.6E3
1.6L3
6.0E1
N
N
N
SSMS
SSMS
SSMS
CO
Ul
29 POTASSIUM, K
29 POTASSIUM ION, K+ (AS K)
29 POTASSIUM HYDROXIDE, KOH
30 RUBIDIUM ION, RB+
31 CESIUM ION, CE+
N
N
2.0E3
1.2E5
8.2E4
N
N
N
N
N
S.OEf
1.8E&
1.2E6
N
2.3E
-------
LIST A-fl
N = NOT YET ASSIGNED
SSMS/AA CATEGORY
NYD = iJOT YtT DETERMINED
GASEOUS
HEALTH ECOLOGY
(MICKOGiVCU H>
LIUUIO
HEALTH ECOLOGY
(M1CROGM/L)
SOLID WASTE SAMPLE
HEALTH ECOLOGY FRACTION
(MICROGM/GRAM)
3<+ CALCIUM CARBONATE* CA004
3«t CALCIUM SULFATE, CASOH
34 OOLOMITt* MGC03 CAC03
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
SSNS
SSMS
SSMS
35 STRONTIUM
35 STRONTIUM ION* SK + + I AS SK)
35 STRONTIUM FLUOK1DE. SRF2 (AS SR)
35 STRONTIUM SULPATEt SRSOf (AS SR)
3.1E3
3.1E3
3.1E3
3.1E3
N
N
N
N
H . 6E4
-------
LIST A-8
U = MOT YET ASSIGNED
SSMS/AA CATKGOKY
NYO = NOT YET 011ERHINED
GASEOUS
HEALTH ECOLOGY
(MICROGN/CU M>
LlUUIl)
HEALTH ECtfLOGY
(MICROGM/L)
SIJLIU WASTE SA1PLE
HEALTH ECOLOGY FRACTION
(MICROGM/GRAM)
00
41 THALLIUM* TL
HI THALLOUSi TL+1
41 THALLIC* TL+3
42 ELEMENTAL CARBON
42 COAL
42 CARBIDE* C-
42 CARBONATE* C03-2
42 BICARBONATE* HC03-
42 CARBONYL* COs
42 CARBON MONOXIDE
42 CARBON DIOXIDE
43 SILICON* SI
43 ORTHOSILICATE* SI04-2
43 METASILICATE, SI03-2
H3 SILANE* SIH4
43 SILICON DIOXIDE* SI02
43 SILICON DISULFIDE* SIS2
43 SILICON CARBIDE* SIC
44 GERMANIUM. GE
44 GERMANOUS* GE+2 (AS GE)
44 GERMANIC* GE+4 (AS GE»
44 GERMANOUS SULFIOE* GES (AS GE)
HH GERMANIC SULFIDE, GES2 (AS GE)
ft GERMANE* GEH<* (AS GE)
HE2
6E2
6E2
OEH
SL2
bE2
N
N
N
N
N
N
N
N
N
1.2E5
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
M
M
M
N
N
N
1
1
1
5
N
N
N
N
N
6
N
1
N
N
1
1
N
1
8
8
8
8
8
8
6
N
N
N
1
2
2
.5E3
.5E3
.5E3
,3E4
.OE5
,5E5
.IE1*
,5E5
.5E5
.4E4
.4E3
• 4E3
.4E3
.4E3
.4EA
.4E3
.ats
.5E2
.5E2
N
N
N
N
N
N
N
N
N
6.
N
N
N
N
N
N
N
N
N
M
N
N
N
N
N
IM
N
N
N
b.
si
OEl
OL1
OL1
3.0
3.0
3.0
I.bt2
N
N
N
N
N
N
N
3.0C2
N
N
2.1E1
3.0E2
N
3.0E2
1.7L1
1.7L1
1.7L1
1.7E1
1.7E1
1.7£1
1.7tl
N
N
N
i.O
,bU
.50
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
IM
.ID
.10
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSHS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
-------
LIST A-b
N = NOT YET ASSIGNED
SSHS/AA CATEGORY
MYO = NOT YET DETERMINED
GASEOUS
HEALTH ECOLOGY
(MICROGM/CU M)
LIQUID
HEALTH FCOLOGY
SOLID WASTE
HEALTH ECOLOGY FRACTION
(MICROGM/GRAM)
00
00
46 PLUHBOUSi PB+2
46 PLUMBIC, PB+4 IAS PB)
46 LEAD MONOXIDE. PBO (AS PB>
46 LEAD SULFATE, PBS04 IAS PB)
46 LEAD SULFIDE, PBS IAS PB)
46 LEAD CARBONATEf PBC03 IAS PB)
46 LEAD PHOSPHATE* PB3(P04)2 IAS PB)
46 LEAD CHROMATE. PBCR04 I AS PB)
46 LEAD MOLYBDATE, PBN004 I AS PB)
46 LEAD ARSENATE, PBHAS04 IAS PB)
47 NITRIDE, N«-
47 NITRATE* N03-
47 NITRITE, N02-
47 AMMONIUM, NH4+
47 NITROGEN OXIDES,N20,N02»N204«N203,N205,NO
47 AMMONIA, NH3
47 HYDRA2INE
47 HYDROGEN CYANIDEi HCN
47 ALKALI CYANIDES, NACN, KCN
47 CYANOGEN, C2N2
47 NITRIC ACID* HN03
46 PHOSPHORUS, P
46 PHOSPHATE, P04-3
46 PHOSPHITE* P03-3 IAS P)
48 BIPHOSPHATE, H2P04- {AS P)
46 PHOSPHINE, PH3
46 PHOSPHORIC ACID, H3P04
48 PHOSPHORUS PENTASULFIDE
49 ARSENIC, AS
49 METALLIC ARSENIC
49 ARSENOUS, AS 4-3
49 ARSENIC, AS +5
49 ARSENATE, AS04-3 (AS AS)
49 ARSENITE, AS03-3 (AS AS)
49 ARSENIDt, AS -3 (AS AS)
49 ARSINE, ASH3
49 ARSENIC TRIOXIDE, AS203
1.5E2
1.5E2
1.5E2
1.5E2
1.5E2
1.5E2
1.&E2
1.SE2
1.5E2
1.5E2
N
N
N
N
9.0E3
1.8E4
1.5E2
1.1E4
5.0E3
2.0E4
5.0E3
1.0E2
N
1.0E2
1.0E2
4.0E2
1.0E3
1.0E3
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
3.5E2
N
3.4E4
N
1.0E3
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
2.5E2
2.5E2
2.SE2
2.SE2
2.SE2
2.5E2
2.5E2
2.SE2
2.SE2
2.bE2
N
N
N
N
1.4E5
2.5E3
2.3
5.0E2
5.0E2
l.OE*
7.5E4
l.SEt
N
1.5E4
1.5E4
6.0E4
1.5E4
1.5E4
2.5E*
2.5E2
2.5E2
2.SE*
2.5E2
2.5E12
2.SE2
2.5E2
2.5E2
S.OE1
5.0E1
5.0E1
5.0E1
5.0E1
5.0E1
5.0E1
5.0E1
5.0E1
5.0E1
N
N
N
N
N
S.OE1
N
2.5E1
2.5E1
2.5E1
4.bE2
.bO
N
.50
.50
N
4.5E3
N
5.0E1
5.0E1
5.0E1
5.0E1
5.0E1
5.0E1
5.0E1
b.OEl
5.0E1
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
N
N
N
N
N
5.0
4.5
1.0
1.0
2.0
1.5E3
3.0E1
N
3.0E.1
3.0E.1
N
3.0E1
3.0E1
.50
.50
.50
.50
.50
.50
.50
.50
.50
.10
.10
.10
.10
.10
.10
.10
.10
.10
.10
N
N
N
N
N
.10
N
.05
.05
.05
.90
.001
N
.001
.001
N
9.0
N
.10
.10
.10
.10
.10
.10
.10
.10
.10
SSHS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
AA
AA
AA
AA
AA
AA
AA
AA
AA
-------
LIST A-8
N = NO! YLT ASSIGNED
SSHS/AA CATEGOKY
NYO = NOT YtT Dt.TEKMINLU
GASEOUS
HEALTH ECOLOGY
(MICROGM/CU M)
LIQUID
HEALTH ECOLOGY
(MICROGM/L)
SOLID WASTE SfllPLE
HEALTH ECOLOGY FRACTION
(MICROGM/GRAH)
SO ANTIMONYi SB
50 ANTIMONY METAL, SB
50 ANTIMONOUS, (STIBNOUS) S8+3
50 ANTIMONIC (STIBNIC) SB+b
50 STZBINEt SBHS (AS SB)
50 ANTIMONOUS SULFIDE, SB2S3
50 ANTIMONY TRIOXIDE, SB203
51 "BISMUTH, BI
51 ELEMENTAL BISMUTH, BI
51 BISMUTHOUS, Bl+3 (AS BI)
51 BISMUTHIC, BI+5 (AS BI)
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E1
4.1E2
4.1E2
4.1E2
4.1E2
N
N
N
N
N
N
N
N
N
N
N
7.5E3
7.5E3
7.5E4
7.5E3
7.5E3
7.5E3
7.5E2
6.1E3
6.1E3
6. IE*
6.1E3
2.0E2
2.0E2
2.0E2
2.0E2
2.0E2
2.0E2
2.0E2
N
N
N
N
1.5E1
1.5L1
1.SE1
1.5L1
1.5E1
1.5E1
1.5
1.2tl
1.2L1
1.2L1
1.2E1
.40
.40
.40
.40
.40
.40
.40
N
N
N
N
AA
AA
AA
AA
AA
AA
AA
SSI
SSI
SSI
SSI
00
vo
52 OZONEi 03
53 RHOMBIC SULFUR, S6
53 SULFIOE, S-2
53 SULFATE, S04-2
53 SULFITE, S03-2
53 THIOCYANATE. SCN-
53 SULFUR DIOXIDES, S02
53 SULFUR TRIOXIDE, S03
53 CARBONYL SULFIDE, COS
53 HYDROGEN SULFIDE, H2S
53 CARBON DISULFIDE, CS2
53 SULFURIC ACID, H2S04
2.0E2
N
N
N
N
N
1.3E4
N
4.4E5
1.5E4
6.0E4
1.0E3
1.0E1
N
N
N
N
N
N
N
N
N
N
N
SSMS
N
N
N
N
N
2.0E5
N
N
2.3E4
9.0E5
1.5E4
N
N
N
N
N
N
N
N
1.0E1
1.0E4
4.5E2
N
N
N
l\l
N
4.0L2
N
N
N
N
3.0L1
N
N
N
M
N
N
N
N
N
N
9.0E2
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
54 SELENIUM, SE
54 ELEMENTAL SELENIUM, SE
54 SELENIDt, SE-2
54 SELENITES, SE03-2 (AS SE)
54 SELENATES, SE04-2 (AS SE)
54 HYDROGEN SELENIDE, H2SE
54 CARBON DISELENIDE, CSE2 (AS SE)
54 SELENIUM DIOXIDE, SE02 (AS SE)
2.0E2
2.0E2
2.0E2
2.0E2
2.0E2
2.0E2
2.0E2
2.0E2
N
N
N
N
N
N
N
N
5.0E1
5.0E1
5.0E1
5.0E1
5.0E1
S.OE1
5.0E1
b.OEl
2.5E1
2.5E1
2.bEl
2.5E1
2.5E1
2.5E1
2.bEl
2.SE1
.10
.10
.10
.10
.10
.10
.10
.10
.05
.05
.05
.05
.05
.05
.05
.05
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
-------
LIST A-d
N = NOT Yt-T ASSIGNED
SSMS/AA CATEGORY
NYO = MOT YET DLIERMINEO
GASEOUS
HEALTH ECOLOGY
M)
LIUUIt)
HtALTH ECOLOGY
(M1CKOGM/D
SOLID WASTE SAMPLE
HEALTH ECOLOGY FRACTION
(MICkOGM/GRAM)
55 TELLURIUM, TE
55 TELLURIOE, TE-2
55 TELLURITE, TE03-2 (AS TE)
55 TELLURAIt, TE04 (AS TE)
1.0E2
l.OEi!
1.0E2
1.0E2
N
N
N
N
1.5E3
1.5EA
1.5E3
1.5E3
N
N
3.0
3,0
3,0
3.0
N
N
N
SSMS
SSMS
SSMS
SSHS
56 FLUORIDE ION, F-
56 HYDROGEN FLUORIDE, HF
2.5E3
2.0E3
N
N
3.0E*
N
N
7.5E1
N
SSMS
SSMS
VO
o
57 CHLORIDE ION, CL-
57 HYPOCHLORITE* CLO-
57 CHLORITE« CL02-
57 CHLORATE* CL03
57 HYDROGEN CHLORIDE• HCL
57 CHLORINE DIOXIDE, CL02
57 CARBONYL CHLORIDE (PHOSGENE), COCL2
56 BROMIDE ION, BR-
58 BROMIDE ION, BR-
58 HYDROGEN BROMIDE«
N
N
N
N
7.0E3
N
t.OE2
N
N
1.0E
62 TITANIC, TI+«» (AS TI)
62 TITANIUM DIOXIDE, TI02 (AS TI)
63 ZIHCONIUM ION, ZR+t
63 ZIRCONIUM DIOXIDE, ZR02 (AS ZR)
6.0E3
6.0E3
6.0E3
6.0E3
5.0E3
5.0E3
N
N
N
N
N
N
9.0E4
9.0EH
9.0E1
9.0EU
7.5EU
7.5EH
8.2E2
8.2E2
8.2E2
8.2E2
N
N
1.8E2
1.8C2
1.8E2
1.BE2
1.5E1
l.Stl
1.6
1.6
1.6
1.6
N
N
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
-------
LIST A-8
N = NOT YET ASSIGNED
SSMS/AA CATEGORY
NYO = NOT YET DETERMINED
GASEOUS
HEALTH ECOLOGY
(MIChOGH/CU M)
LIQUID
HEALTH ECOLOGY
(MICROGH/L)
SOLID WASTE SAMPLE
HEALTH ECOLOGY FRACTION
(MICROGM/GRAM)
HAFNIUM IQNt HF+f
5.0E2
7.5EH
1.5
SSMS
(O
65 VANADIUMf V
65 ELEMENTAL VANADIUM, V
65 VANADlCt V*3 (AS V)
65 VANAOYLi VO+2 (AS V)
65 ORTHOVANADATE, V04-4 (AS V)
65 NETAVANAOATEt V03- (AS V)
65 VANADYLICt VO+3 (AS V)
65 VANADIUM MONOXIDE. VO (AS V)
65 VANADIUM TRIOXIDE, V209 (AS V)
65 VANADIUM TETRAOXIDE, V20f (AS V)
65 VANADIUM PENTOXIDE, V205 (AS V)
65 VANADIUM CARBIDE, VC (AS V)
65 VANADIUM MONOSULFIOE, VS (AS V)
65 VANADIUM NITRIDE, VN (AS V)
65 VANADYL SULFATE, VOSOH bHgO (AS V)
5.0E2
5.0E2
5.0L2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
5.0E2
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.5E3
2.5E3
2.5E3
2.5E3
2.5E3
2.5E3
2.5E3
2.5E3
2.5E3
2.5E3
2.5E3
2.5E3
2.5E3
2.5E3
2.SE3
1.5E.2
1.SE2
1.5E2
1.5E2
1.5E2
1.5E2
1.5E2
1.5E2
1.5E2
1.5E2
1.5E2
1.5E2
1.SE2
1.5E2
1.5E2
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5*0
.30
.30
.30
.30
.30
.30
.30
.30
.30
.30
.30
.30
.30
.30
.30
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
66 NIOBUS, NB+3
66 NIOBIC, NB+5
66 NIOBIUM OXIDESt NBO, NB20& (AS NB)
2.2E4
2.2E1
2.2E<*
N
N
N
3.3E5
3.3E5
3.3E5
N
N
N
6.5E2
6.5t2
6.5t2
N
N
N
SSMS
SSMS
SSMS
67
TANTALUM ION, TA+5
5.0E3
7.5E4
1.5E2
SSMS
66 CHROMIUM, CR
68 CHROMOUS, CR+2 (AS CR)
68 CHROMIC* CR+3 (AS CR)
68 CHROMATES, CROt-2 (AS CR)
68 CHROMITES, CR20»+-2 (AS CR I
68 OICHROMATES, CR207-2 (AS CR)
68 CHROMIUM CARBONYL, CR
-------
LIST A-H
N = HOT YLT ASSIGNED
SSf.S/AA CATKGOKY
NYU = hOf YLT DLTt.KMI.4Ll3
bftSKUUii
HEALTH ECOLOGY
(i"iiCKOG"l/CU n)
LlUMu
HEALTH ECOLOGY
(HI(.HOf,l>/L)
•5/f
SOL in
HEALTH ECOLOGY FHnCTIOr>;
(MKRlKif./faKAM)
vo
PO
69 MOLYBDENUM, MO b.OE3 N
69 MOLYBDENOUS, MO+2 5.0E3 N
69 MOLY8DIC, MO+3 S.OEi N
69 MOLYBOATE, MOOt-2 (AS MO) 5.0E3 N
69 MOLYBDENUM SULFIOE, MOS2 (AS MO) 5.0E3 N
69 MOLYBDENUM TRIOXIDE, MOU3 (AS MO) 5.0E3 N
70 TUNGSTEN, W 1.0E3 N
70 TUNGSTEN IONS, W+2, W+4, W+5» W+6, W04-2 N N
70 TUNGSTEN DISULFIDE, WS2 (AS W) 1.0E3 N
70 WOLFRAMITE MINERAL, FEWOf MNU04 (AS W) 1.0E3 N
71 MANGANESE, MN
71 MANGANOUS, HN+2
71 MANGANIC, MN+3
71 PERMANGANATE, MNQi*. (AS MN)
71 MANGANOUS OXIDE, MNO (AS MN>
71 MANGANESE DIOXIDE, MN02 (AS MN)
71 MANGANESE CARBONATE, MNC03 (AS
71 MANGANOUS SULFATE, MNSOt (AS MN)
71 MANGANESE SULFlDE, MNS2 (AS MN)
72 FERROUS, FE+2 1.0E3 N
72 FERRIC, FE+3 1.0E3 N
72 FERROCVANIOE, FE(CN)6-t N N
72 FERRICYANIDE, FE(CN)6-3 N N
72 FERROUS OXIDE, FEO 5.0E3 N
72 FERRIC OXIDE, FE203 N N
72 FERRIC HYDROXIDE (HYDRATEO) FE203 XH20 N N
72 IRON SULFIDES, FES, FE2S3 IM N
72 PYRITE, FES2 N N
72 MAGNETITE, FEO FE203 9.3E3 N
72 POTASSIUM IRON SILICATE, KFESI20b N N
72 IRON CARBONYLS, FE(CO)5, FE(CO>9« FE3(CO)12 7.0E2 N
5.0E3
5.0E3
5.0E3
5.0E3
5.0E3
5.0E3
5.0E3
5.0E3
5.0E3
N
N
N
N
N
N
N
N
N
7.5E1*
7.5E4
7.5EH
7.SEH
7.5E1
7.5E1
1.5E-+
N
l.SEf
1.5E*
2.5E2
2.5E2
2.5E2
2.5E2
2.5E2
2.5E2
2.5E2
2.5E2
2.5E2
1.5E3
1.5E3
N
N
7.5EH
N
N
IM
N
6.2E3
7.UEJ
7.0E3
7.0E3
7.0E3
7.0E3
7.0E3
N
N
N
N
1.0E2
1.0E2
1.0E2
1.0E2
1.0E2
1.0E2
1.0E2
1.0E2
1.0E2
2.5E2
2.5E2
N
N
N
1.0E5
N
N
1.0E5
N
1.1E4
3.0tl
N
3.0E1
3.0tl
.50
.50
.50
.50
.50
.50
.50
.50
.50
3.0
3.0
N
N
1.5E2
N
N
N
3.8E1
N
2.1E1
N
N
M
N
.20
.20
.20
.20
.20
.20
.20
.20
.20
.50
.50
N
N
2.0E2
N
N
2.0E2
N
N
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
RUTHENIUM ION, RU+3
SSMS
-------
LIST A-fl
N = NOT YLT ASS1GNLO
SSMS/AA CATEGORY
NYU = NOT YLT DETERMINED
GASEOUS
HEALTH ECOLOGY
(hlCRUGIVCU M)
LIQUID
HEALTH ECOLOGY
(MICKOGM/L)
SOLID WASTE SfllPLE
HEALTH ECOLOGY FRACTION
(MICROGM/GRArtl
72 (AS CO) 5.0E1 N
7.5E2
7.5E2
7.5E2
7.5E2
7.5E2
7.5E2
7.SE2
7.5E2
7.5E2
7.5E2
7.5E2
2.5E2
2.5E2
2.5E2
2.5E2
2.5E2
2.5E2
2.5E2
2.5E2
2.SE2
2.5E2
2.5E2
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
.50
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
SSMS
vo
CO
75 RHODIUM ION, RH+3
76 NICKEL, NI
76 NICKELOUS* NI+2
76 NICKELIC, NI+3
76 NICKEL CARBONYL, NI(CO)4
76 NICKELOUS SULFIDE* NIS (AS NI)
76 NICKEL ARSENIDE, NIAS
-------
LIST A-8
N = NOT YET ASSIGNED
SSMS/AA CATEGORY
NYO = MOT YET DETERMINED
GASEOUS
HEALTH ECOLOGY
(hICROGM/CU M)
L1QUIO
HEALTH ECOLOGY
(MICROGM/L)
SOLID WASTE SA.IPLE
HEALTH ECOLOGY FRACTION
(MICROGM/GPAH)
79 SILVERi AG
79 SILVER ION, AG+ (AS AG)
79 SILVER CHLORIDE, AGCL (AS AG)
79 SILVER CYANIDE, AGCN (AS AG)
79 SILVER SULFIDE, AG2S (AS AG)
1.0E1
1.0E1
l.OEl
1.0E1
1.0E1
N
N
N
N
N
2.5E2
2.5E2
2.5E2
2.5E2
2.5E2
5,0
5.0
5.0
5.0
5.0
.50
.50
.50
.50
.50
.1
.1
.1
.1
.1
SSHS
SSMS
SSMS
SSMS
SSMS
80
ELEMENTAL GOLD
SSMS
vo
61 ZINC, ZN
81 ELEMENTAL ZINC, ZN
81 ZINC ION, ZN+2
81 ZINC OXIDE, ZNO (AS ZN)
81 ZINC SULFATE, ZNSOf (AS ZN)
81 ZINC SULFIDE, ZNS (AS ZN)
82 CADMIUM, CD
82 ELEMENTAL CADMIUM, CO
82 CADMIUM ION, CD+2
82 CADMIUM SULFIDE» CDS (AS CD)
82 CADMIUM OXIDE, CDO (AS CD)
-------
TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1. REPORT NO.
EPA-600/7-78-015
2.
3. RECIPIENT'S ACCESSION-NO.
4. TIT
AND SUBTITLE SAM/jA: A Rapid Screening Method
for Environmental Assessment of Fossil Energy
Process Effluents
5. REPORT DATE
February 1978
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
L.M. Schalit and K.J. Wolfe
8. PERFORMING ORGANIZATION REPORT NO.
TR-77-50
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Acurex Corporation/Aerotherm Division
485 Clyde Avenue
Mountain View, California 94042
10. PROGRAM ELEMENT NO.
EHE624
11. CONTRACT/GRANT NO.
68-02-2160 (T.D. 4)
12. SPONSORING AGENCY NAME AND ADDRESS
EPA, Office of Research and Development
Industrial Environmental Research Laboratory
Research Triangle Park, NC 27711
13. TYPE OF REPORT AND PERIOD COVERED
Task Final; 2-12/77
14. SPONSORING AGENCY CODE
EPA/600/13
15.SUPPLEMENTARY NOTES IERL-RTP project officer is Joshua S. Bowen, Mail Drop 65, 919/
541-2470.
16. ABSTRACT
repOrt describes the simplest member of a sequence of Source Analy-
sis Models (SAMs) of increasing complexity and thoroughness which can be used as
tools to help with one or more of five tasks involved in the environmental assessment
of energy and industrial processes. The tasks are: (1) ranking individual effluent
streams by the expected toxicity of their discharges; (2) establishing sampling prio-
rities; (3) determining problem pollutants; (4) recommending best multimedia control
technology alternatives; and (5) recommending control/disposal technology develop-
ment programs. This model, SAM/TA, is useful for rapidly screening each effluent
stream from a specific source: it is based on comparing effluent concentrations with
the set of Minimum Acute Toxicity Effluent (MATE) criteria established by the EPA.
The report explains the purposes of SAM/IA, the format used, and the MATE cri-
teria against which pollutants are gauged. Several examples are included to illus-
trate specific facets of the model and of the format.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS
c. COSATI Field/Group
Pollution
Combustion Control
Assessments
Selection
Fossil Fuels
Energy Conversion
Techniques
Effluents
Properties
Toxicity
Pollution Control
Stationary Sources
Environmental Assess-
ment
SAM/IA
Source Analysis Models
Rapid Screening Format
13B
21B
14B 06T
21D
10A
18. DISTRIBUTION STATEMENT
Unlimited
19. SECURITY CLASS (ThisReport)
Unclassified
21. NO. OF PAGES
166
20. SECURITY CLASS (Thispage)
Unclassified
22. PRICE
EPA Form 2220-1 (9-73)
A-95
------- |