oEPA
         Unned Slates
         Environmental Protection
         Agency
          Industrial Environmental Research
          Laboratory
          Research Triangle Park NC 2771 1
EPA 600 7-79-049
February 1979
Technical Manual for the
Measurement and
Modeling of Non-point
Sources at an Industrial
Site on a River

Interagency
Energy/Environment
R&D Program Report

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                  RESEARCH REPORTING SERIES


Research reports of the Office of Research and Development. U.S. Environmental
Protection Agency, have been grouped into nine series These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology  Elimination of traditional  grouping was  consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:

    1.  Environmental Health Effects Research

    2.  Environmental Protection Technology

    3.  Ecological Research

    4   Environmental Monitoring

    5.  Socioeconomic Environmental Studies

    6.  Scientific and Technical Assessment Reports (STAR)

    7.  Interagency Energy-Environment Research and Development

    8.  "Special" Reports

    9.  Miscellaneous Reports

This report has been assigned to the INTERAGENCY ENERGY-ENVIRONMENT
RESEARCH AND DEVELOPMENT series. Reports m this series result from the
effort  funded  under the 17-agency  Federal Energy/Environment Research and
Development Program. These studies relate to EPA's mission to protect the public
health and welfare from adverse effects of pollutants associated with energy sys-
tems.  The goal of the Program is to assure the rapid development of domestic
energy supplies in an environmentally-compatible manner by providing the nec-
essary environmental data and control technology. Investigations include analy-
ses of the transport of energy-related pollutants  and  their health and ecological
effects; assessments  of, and development of. control technologies for  energy
systems; and integrated assessments of a wide-range of energy-related environ-
mental issues.
                        EPA REVIEW NOTICE
This report has been reviewed by the participating Federal Agencies, and approved
for  publication. Approval does not signify that the contents necessarily reflect
the views and policies of the Government, nor does mention of trade names or
commercial products constitute endorsement or recommendation for use.

This document is available to the public through the National Technical Informa-
tion Service, Springfield. Virginia 22161.

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                                    EPA-600/7-79-049

                                         February 1979
       Technical  Manual  for the
   Measurement  and Modeling of
Non-point Sources  at an Industrial
               Site on  a  River
                         by

            G.T. Brookman, J.J. Binder, P.B. Katz, and W.A. Wade,

              TRC - The Research Corporation of New England
                    125 Silas Dean Highway
                  Wethersfield, Connecticut 06109
                    Contract No. 68-02-2133
                       Task No. 2
                   Program Element No. EHE624
                 EPA Project Officer: D. Bruce Harris

               Industrial Environmental Research Laboratory
                Office of Energy, Minerals, and Industry
                 Research Triangle Park, NC 27711
                       Prepared for

               U.S. ENVIRONMENTAL PROTECTION AGENCY
                 Office of Research and Development
                    Washington, DC 20460

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                               TABLE OF CONTENTS
Section                                                               Page

1.0                 OBJECTIVE	    1

2.0                 INTRODUCTION 	    2

3.0                 DEVELOPMENT OF A FIELD SURVEY PROGRAM	
   3.1                Selection of Sampling Sites	    5
      3.1.1             Runoff Sampling Sites	    5
      3.1.2             River Sampling Sites 	    7
   3.2                Sampling Methodology 	    9
      3.2.1             Selection of Parameters to be Measured ....    9
      3.2.2             Number and Frequency of Samples	12
      3.2.3             Sample Collection Methods	15
           3.2.3.1        Overland Runoff	15
           3.2.3.2        Open Channel Flow	15
      3.2.4             Type of Sanple	20
      3.2.5             Measurement of Runoff and River Flow	21
   3.3                Sample Analysis	23
   3.4                Data Reduction and Analysis	23

4.0                 MATHEMATICAL MODELING	30
   4.1                Model Selection Criteria 	   30
   4.2                Possible Industrial Non-Point Source Models.  .  .   31
   4.3                Example Industrial Runoff and Receiving
                      Water Model - SSWMM-RECEIV II	35
      4.3.1             General Description	35
      4.3.2             Computer Requirements	35
      4.3.3             Model Utilization	35
      4.3.4             Model Input Information Requirements 	   36
      4.3.5             Model Results	   3S

5.0                 PROGRAM COSTS AND TIME CONSIDERATIONS	40
   5.1                Manpower for Measurement Survey	-*0
   5.2                Other Direct Costs for Measurement Survey. ...   ^2
   5.3                Elapsed Time Requirements	-*2
   5.4                Labor and Computer Time to Implement
                      SSWMM-RECEIV II for Case Run	^6

6.0                 SUMMARY:  HYPOTHETICAL CASE	^8
   6.1                Introduction	^8
   6.2                Background Information 	   *S
   6.3                Selection of Sampling Sites	50
   6.4                Sampling Methodology 	   50
      6.4.1             Parameters for Analysis	50
      6.4.2             Sampling Frequency 	   51
      6.4.3             Method of Sample Collection	51
      6.4.4             Flow Measurement	51
      6.4.5             Sample and Data Analysis	52
   6.5                Model Apolication to Example Case	53
   6.6                Conclusion	56
                                       111

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                               LIST OF TABLES
TABLE                                                                   PAGE

 3-1      Parameters Commonly Monitored in Water Non-Point
          Source Programs  	    10

 3-2      Minimum Volume, Preservation and Maximum Storage Time
          of Samples for Common Pollutants   	    11

 3-3      Comparison of Manual and Automatic Sampling 	    19

 3-4      Range of Pollutant  Concentrations at  the Sampling
          Locations of Coal-Fired Utility .        	    25

 3-5      Mean Pollutant Concentrations with 95TI Confidence
          Limits on River at  Coal-Fired Utility 	   ]    27

 3-6      Comparisons of Mean Values and Variances Within 957.
          Confidence Limits at Upstream and Downstream Sites
          During Dry and Wet  Sampling Periods at Coal-Fired Utility   .    29

 4-1      Possible Models for Industrial Runoff Applications    ...    32

 4-2      SSWMM-RECEIV II Model Input Requirements 	    37

 5-1      Estimated Manpower  Requirements for Runoff  Study  ....    41

 5-2      Estimated Cost of Equipment - Estimate of Other Direct
          Costs for Example Runoff Study	43

 5-3      Estimated Cost/Parameter Analyzed/Sample 	    44

 5-4      Labor and Computer  Time Based on Example Case	47

 6-1      Physical Dimensions of  Land Elements  - Coal-Fired
          Utility Station Example Case    	55

 A-l      TRC  SSWMM Selected  Model Results   	    59

 A-2      TRC  LNKPRG Selected Model Results  	    61

 A-3      TRC  RECEIV Setup/Quantity Selected Model Results  ....    63

 A-4      TRC  RECEIV II Quality Selected Model  Results   	    69
                                    IV

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                              LIST OF FIGURES



FIGURE                                                                PAGE

 3-1      Site Divided Into Drainage Basins  	     6

 3-2      Plug Collector	    16

 3-3      Weir Installation in Storm Drain	    22

 5-1      Elapsed Time Estimates for Runoff Study Which is to be
          Used in Conjunction with a Mathematical Model  ....    ^5

 6-1      Site Layout, Coal-Fired Utility Station Example Case .   .    ^9

 6-2      Land and River Model Element Schematic, Coal-Fired Utility
          Station Example Case	    5~»

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1.0  OBJECTIVE




     This Technical Manual presents a guide to planning a measurement




and modeling program for non-point sources of water pollution from an




industrial site.  The emphasis of the manual is on storawater runoff




and the impact of the runoff on stream water quality.




     The manual describes the criteria for designing a measurement program,




including factors to be considered in sampling site selection and options




for sampling methodology.  The planning to be done includes:  1)  the choice




of pollutant parameters for analysis, 2) the determination of sampling




frequency, 3) analysis of alternative techniques of sample collection, and




4) the selection of flow measurement methodology.  In addition, sample analysis




and data analysis procedures must be considered.




     The resulting measurement program is designed to be compatible for use




with a mathematical model.  A model, with a minimum amount of measured field




data as input, can be used to predict the quantity and quality of runoff




and its impact on a river for a wide variety of storm, site, and river




conditions.  This manual includes a guide to the application of one model




especially adapted for stormwater runoff.




     Data is also presented to assist in the development of estimates for




manpower and time requirements, field equipment costs, and for computer




time.




     An example of the possible application of a plan for the measurement




and modeling of stormwater runoff from a coal-fired utility plant is pre-




sented in Section 6.
                                 -1-

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 2.0   INTRODUCTION

      A precise definition of non-point source water pollution does not exist;

 however,  for the purpose of this manual the following definition applies:


      Non-point source water pollution is the accumulated pollutants
      in a receiving body of water from runoff due to snow melt and
      rain, seepage and percolation, and chemical spills and leaks,
      contributing to the degradation of the quality of surface waters
      and groundwaters.


      Non-point source water pollution can have a major influence on water

 quality.  Thus, identifying non-point source pollution and its impact on

natural water bodies is of significant concern to those developing water

management plans to maintain and improve water quality.

      To date, non-point source water pollution has been studied in some

detail for urban and agricultural environments.  However, little attention

has been paid to industrial stonnwater runoff.

     As Section 208 Areawide Waste Treatment Management Plans are enacted

by regional agencies on a nationwide scale, more emphasis can be expected

on non-point source controls in both the municipal and industrial sectors.

Also, with increasing enactment of Best Practicable Treatment (BPT) for

point sources,  more stress will be placed on BPT for non-point sources in those

areas where water quality still falls short of attainment goals.

      In addition, more regulations may be forthcoming on the quality of

stormwater outfall discharges and subsequent controls may be required.
                                                                     *

      For these reasons, more concern is being directed toward runoff from

industrial non-point sources.  Sources with the highest potential for con-

taminating runoff are generally material storage piles and fallout from

 fugitive and point source air emissions which accumulate on impervious
                                  — 9 —

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     This manual will assist the facilities engineer and agency water quality




planner to develop the framework of a program to assess the impact of storm-




water runoff on stream water quality.  This manual discusses the approach to




the measurement and modeling of stormwater runoff from most industrial sites.




The discussion of measurement and modeling of the impact on receiving waters,




however, is limited to rivers, the most likely industrial receiving body.




     This manual is the second volume in a set concerning the evaluation of




non-point pollution sources from industry.  The first volume  is a technical




report of sampling and modeling of non-point sources at coal-fired utilities.




The measurement and modeling guidelines described in this manual were developed




in conjunction with the program described in the first volume.
                                  -3-

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3.0  DEVELOPMENT OF A FIELD SURVEY PROGRAM

     The field survey procedures chosen for a runoff sampling program are

specific both to the industry and to the site.  The following considerations

are important for the development of a plan for such a runoff survey.
     1.   Purpose of Sampling Program.  What is the reason for the
          sampling program?  What is the intended use of the results?

     2.   Resource Availability.  What resources in terms of manpower,
          equipment and money are available to perform the sampling
          program?  Are they adequate to fulfill the objectives of
          the program?

     3.   Site Location.  What are the flow and mixing characteristics of the
          river likely to be?  Is flow in the river regulated by a dam?  Is
          there the likelihood of a suitable amount of rainfall during the
          sampling period?  Can plant discharges and runoff be isolated
          from other discharges, tributaries, etc.?

     4.   Runoff Sources and Characteristics.  What are the likely sources
          of runoff (i.e., material piles, from fugitive dust on parking
          lots and roads, from material-loading/unloading areas, etc.)?
          What types and quantities of materials are likely to run off?
          What are the physical properties of  the material subject to  run-
          off?  How are the runoff sources located with respect to drainage
          patterns, storm sewers, etc.?  How large .an area is drained?  Is
          there evidence of runoff patterns?   How is runoff disposed of?
          How can it be quantified?  Are local topography and drainage sys-
          tems amenable to interception?

     5.   Parameters to be Analyzed.   Is there a river flow recording
          station nearby?  What is the river water quality?  What
          chemical compounds are specific to the runoff material?  What
          pollutants are important to the program objective?
Each of these elements must be addressed in the development of specific

test plans for the sampling program.  A site visit and discussions with

plant personnel are usually adequate to answer many of these questions

and to develop the test plan.  Some preliminary samples may be necessary

to fill gaps in available information.
                                 -4-

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3.1  Selection of Sampling Sites




     One of the principal objectives of the initial on-site visit is to




gather enough information to select the runoff and river sampling locations.









     3.1.1  Runoff Sampling Sites




     From a visual survey of the industrial site and site maps, the possible




significant sources of runoff are determined.  These may include piles of




raw materials such as coal and wood, waste material disposal piles such as




bark, and areas of significant accumulated dirt and dust fall.




     The path of surface water flow from these sources to a stream is defined




by the drainage basins of the site.  The drainage basins can be determined in




a variety of ways.  Contours from existing topographic maps of the site can be




used to define the drainage area.  If these maps are not available or if there




is uncertainty as to the size and shape of a basin, visual observations of




drainage patterns snould be made during one or more storm events and during




dry conditions.  Many plants have storm sewer systems which can be located




through the use of sewer system drawings.  These sewer systems can also be




used to divide the plant into basins.  A more accurate but more costly method




of determining drainage basins is to perform a topographic survey of the site.




     Figure 3-1 shows a plant site which has been divided into drainage




basins through visual observation and storm sewer network maps.  The four




drainage basins are numbered 1 through 4.  Basin 1 discharges to the river




via overland flow at discharge point No. 1.  Basins 2, 3 and 4 discharge to




the river via a storm sewer system at discharge point No. 2.
                                 -5-

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          -  s
                          Storm sewer system
                      i
     Coal
     pile

                                                            /    N
                                                        Cooling water
                                                     ^\,  discharge

                                                   i.*,'
                                       LEGEND

                             Q   BASIN NUMBER

                            	BASIN BOUNDARY

                                   DISCHARGE POINT
                                   STORM SEWER
                                   SAMPLING POINT
Figure 3-1:  Site divided into drainage  basins.
                          -6-

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     To isolate the runoff from these drainage basins, stormwater runoff




should be intercepted as close to the source as possible.  For example, in




Figure 3-1, sampling should occur in the storm sewer as close as possible




to the location where Basin 3 drains into Basin 4 and the combined drainage




from Basins 3 and 4 discharge into Basin 2.  These locations are marked with




asterisks in Figure 3-1.  Sampling must also be performed at all major dis-




charges to the river to get a total quantity of runoff to the receiving




water.  In Figure 3-1, points Nos. 1 and 2 indicate the discharge locations




of Basin 1 and Basins 2-4, respectively.




     The access to the sampling sites of both manpower and equipment must




also be considered.  Related considerations for storm sewers include:




1) Location of the manholes; 2) for accurate flow measurement, the change




of slope of the sewer lines influent to and exiting from the manhole; 3)




possible drop manholes; 4) possible bends in the manhole channels; and 5)




effect changes in river depth and flow rate after heavy rains will have on




storm sewer outfall access.









     3.1.2  River Sampling Sites




     Once the drainage basins and the runoff sampling points have been de-




fined, river sampling stations can be selected upstream and downstream of




the basin discharges from the plant.  Several factors must be considered to




assure that these sites produce representative river samples.  For example,




river mixing patterns relative to the discharge points and runoff areas




must be adequately defined.  All stations must be positioned at locations




which are well-mixed; i.e., having uniform chemical and physical properties.
                                   -7-

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   The upstream sampling station should be located above any influence




 from  the discharges of the plant site in a well-mixed reach to obtain




 samples truly representative of background pollutant levels in the stream.




      The downstream station should be placed at a location where the runoff




 plume (portion of river influenced by runoff) has fully dispersed across the




 river to ensure that the samples collected are representative of time average




 pollutant loadings.  To determine discharge plume dispersion, various tests




 can supplement visual observation.   These include tracking floating tags and




 fluorometry which measures optically the concentration of fluorescent dyes




 in waterways.




     For both upstream and downstream sampling sites, consideration must also




be given to the effect of heavy rain on the runoff plume flow rate and conse-




quently on the plume dispersion behavior.   Also the sampling equipment must




be sited well above the expected high water level caused by heavy rainfall.




     One sampling location upstream and one downstream will usually provide




sufficient data,  although increasing the number of sampling stations to two




or three per location will insure more representative sampling in situations




where less than ideal conditions exist such as rivers with poor mixing or




wide, deep rivers which have a low velocity.   Any point discharges (such as




the cooling water discharge shown in Figure 3-1), tributaries, etc., between




the upstream and downstream sites must also be sampled to account for their




effects on the river.
                                    -8-

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     During dry conditions the upstream and downstream data should be approxi-




mately the same, excluding any point source discharges.  (If there are major




point source effluents, these should be reflected in the downstream data.)




If unaccountable major differences in data exist, the downstream and possibly




the upstream station(s) should be moved until agreement is attained.









3.2  Sampling Methodology




     3.2.1  Selection of Parameters to be Measured




     Table 3-1 shows a list of typical parameters associated with non-point




sources.  The objectives of the field survey may allow deletion of some con-




stituents or require the addition of others.  The water quality of the




receiving body, the likelihood of detecting the various contaminants in the




river, and the type of source being analyzed will affect the choice of




parameters.  For example, coal pile runoff dictates different parameters




than agricultural runoff.  Contaminants previously present in high concen-




trations in the receiving body may mask similar contaminants discharged in




the runoff.




     Sample preservation and analysis requirements may also affect the




choice of parameters to be studied.  Table 3-2 shows the minimum sample




volume, method of sample preservation, and recommended maximum storage time




requirements for commonly-sampled pollutants.  Review of these recommended




storage times indicates that parameters such as BOD, phosphate, kjeldahl




nitrogen, ammonia, phenol, cyanide, and TOG, which require rapid analyses,




should be determined in a field laboratory or immediately shipped to a




nearby home laboratory.  On the other hand, metals samples can be acidified




and stored for analysis at the end of the sampling program.   In addition,
                                  -9-

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                            TABLE 3-1

PARAMETERS COMMONLY MONITORED IN WATER NON-POINT SOURCE PROGRAMS


            1.   Solids

                 Total Suspended
                 Total Dissolved
                 Turbidity


            2.   Organic Materials

                 Oil & Grease
                 Total Organic Carbon (TOC)
                 Biochemical Oxygen Demand (BOD)
                 Chemical Oxygen Demand (COD)
                 Dissolved Oxygen (DO)


            3.   Metals

                 Iron
                 Cadmium
                 Copper
                 Manganese
                 Lead


            4.   Nutrients

                 Phosphate (Ortho, total)
                 Total Kjeldahl Nitrogen (TKN)
                 Ammonia Nitrogen
                 Nitrate-Nitrite


            5.   Others

                 Sulfate
                 Cyanide
                 PH
                 Phenol
                                 -10-

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                        TABLE  3-22

MINIMUM VOLUME, PRESERVATION AND MAXIMUM STORAGE TIME OF
              SAMPLES FOR COMMON POLLUTANTS
Minimum
Pollutant Volume (mi)
Total Suspended Solids
Total Dissolved Solids
Turbidity
Oil & Grease
Total Organic Carbon
Biochemical Oxygen Demand
Chemical Oxygen Demand
Metals
Phosphate
Kjeldahl Nitrogen
Ammonia
Sulfate
Cyanide
pH
Dissolved Oxygen (Winkler)
Dissolved Oxygen (Probe)
Phenol
100
100
100
1000
25
1000
50
100
50
500
400
50
500
25
300
300
500
Sample
Preservation
Cool, 4°C
Cool, 4°C
Cool, 4°C
Cool, 4°C
HjSOi^ to pH<2
Cool, 4°C
H2SOit to pH<2
Cool, 4°C
H2SO^ to pH<2
HN03 to pH<2
Cool, 4°C
Cool, 4°C
H2S01+ to pH<2
Cool, 4°C
H2S01+ to pH<2
Cool, 4°C
Cool, 4°C
NaOH to pH 12
Cool, 4°C
-
-
Cool, 4°C
Maximum Storage
Period
7 Days
7 Days
7 Days
24 Hrs in glass
container only
24 Hrs
6 Hrs
7 Days
6 Mos
24 Hrs
24 Hrs
24 Hrs
7 Days
24 Hrs
6 Hrs
No Holding, glass
No Holding, glass














only
only
24 Hrs, glass only
                                       H3POU  to  pH<4
                                       l.OgCuSOu/Jl
                              -11-

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as  a  screening process, some laboratories only analyze for oil and grease




on  samples with a visible oil sheen or floating grease matter.  This proce-




dure  thus reduces the number of samples to be transported for analysis.




Reference should be made to Methods for Chemical Analysis of Water and Wastes




(EPA-625-/6-74-003) and to Standard Methods for the Analysis of Water and Waste-




water,  14th ed., 1975, APHA-AWWA-WPCF, for specific details concerning pre-




servation and storage times.




      Some parameters such as pH, turbidity, and dissolved oxygen can be




measured using continuously recording monitors.  Measuring these parameters




continuously can reduce the load on the analytical laboratory and provide a




real  time indication of changes in water quality.  For example, during dry




weather, these parameters (pH, etc.) should be very similar upstream and




downstream in the river when point source dry weather flows are subtracted




from  the downstream data.  If they are not similar, it is highly probable that




the sites are located in non-representative sections of the river and should




be moved, if possible, and re-sampled.




      It should also be noted that frequent (weekly during sampling) calibration




of dissolved oxygen and pH probes is advisable for accurate readings.  In addi-




tion, dissolved oxygen values determined using a DO probe can be compared to




dissolved oxygen values determined by the Winkler Method (Section 218, Standard




Methods) from random samples fixed on-site.









      3.2.2  Number and Frequency of Samples




     Timing of sample collection is one of the problems associated with sampl-




ing runoff.   Because runoff is diffuse and it is usually not feasible to




collect all of it,  total quantification must be estimated from a limited




number of samples.   Even if it were possible to collect all runoff from a
                                   -12-

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particular basin as it discharges to the river, the data generated from sum-




ming all the basins in a test area could still have significant errors.  These




errors could be caused by some of the basin runoff draining to or from an ad-




joining basin outside the test area.  The measured data would not, therefore,




quantify and qualify the runoff generated by the test area.  Instead, many




factors are used in the timing of sampling periods and the number and frequency




of samples within those periods and fewer samples need to be collected and ana-




lyzed in dry weather than in wet weather.  River conditions are more stable in




dry weather than they are during and after a rainfall event when short-term




and dynamic changes in pollutant values occur  in the river.  It is important




to initiate sampling at the first instance of  rainfall and then take samples




often because a large quantity of materials may wash off the surface almost




immediately, especially in paved areas.  This  effect is called "first flush."




For longer-duration storms, the sampling rate  can be reduced.




     The number of samples deemed adequate is  also dependent upon the pro-




gram objective and the available resources.  A data base constructed from many




samples can allow greater confidence in deriving conclusions from the program




and in calibrating the model.  Cost savings can be obtained by analyzing




fewer than the total number of collected samples (e.g., analyze every third




or fourth sample initially).  If the reduced number of analyses show a trend,




then additional analyses can be performed on selected samples to fill in the




missing data.  If no trend is indicated, additional analyses are not cost-




effective.
                                   -13-

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      A determination  of  sampling  frequency  can be  made  by  the  relationship



 between variation  in  runoff  character  and the acceptable error in  the  average



 result.   It  can be assumed that the greater the variability, the greater  the



 number  of samples that must  be integrated to yield a composite sample  with  a



 reasonable value.



      For example, the SSWMM-RECEIV-H  model divides a storm into rainfall



 intervals, with the intensity of  the rainfall and  the length of the interval



 as input data.  How many discrete samples must be  integrated in that interval



 period  to obtain an average  sample that will vary  no more  than 5 Ib/day



 suspended solids from the true average based on 95% confidence limits?



 From previous sampling and analysis, 10 samples taken over the interval show



a standard deviation of 10 Ib/day suspended solids.



     The Student 't1  distribution can be utilized  to estimate  n, the number



of samples.   This relationship is defined as:




                             t2 2

                         n = ±£-                           (3-1)





where :



     s is the sample standard distribution,



     d is allowable margin of error,



     t is the percentile of the 't1  distribution at v

       degrees of freedom and (1-a)  confidence limits.



 In this case,



     s = 10 Ib/day



     d =  5 Ib/day




     C = Va/.Z = C.975 = 2'262


     v = (10-1) degrees of freedom = 9
     n _
     n
       _ (2.262)2 (10)2   _     fi
       --    -   - 20.46
                                     -14-

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Approximately 21 discrete samples should be integrated over the designated rain-
fall interval so that the value of suspended solids in the composite will vary
no more than ±5 Ib/day with 95% confidence limits.
     However, it should be noted that this methodology can be used only for
estimation purposes, as the value of the sample standard deviation, determined
by preliminary sampling, is based on factors not necessarily reproducible in
each storm.  For example, the number of dry days between storms will affect the
dust and dirt accumulation and the subsequent variability of the runoff samples.
Wide variations in storm intensity and duration can also affect sample vari-
ability.
     Sampling frequency methods must be taken into account so that project
objectives are not compromised by too few samples or analyses.


     3.2.3  Sample Collection Methods
          3.2.3.1  Overland Runoff
     Where runoff from an industrial site follows a storm sewer or natural or
earth channel, open channel methods of sample collection can be utilized.  How-
ever, where runoff is likely to follow a poorly-defined path overland, plug
collectors can be placed in the ground to trap water flowing over them.  These
plugs (see Figure 3-2) should have a screen cover to prevent "pushalong" solids
from collecting in them.  Plug collectors can be used with a system of dikes
and berms to channel flow in an impervious area to a discharge point where the
flow can then be sampled.


          3.2.3.2  Open Channel Flow
     Runoff and river samples in sewers and channels are collected with manual
and automatic samplers.   The sampling equipment is selected based on the parame-
ters chosen, the number and frequency of samples to be taken, and location of
the sampling stations.
                                     -15-

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 Plug collector
  /



 /MI
'
Figure 3-2: Plug Collector
      -16-

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          3.2.3.2.1  Manual Samplers




     Manual sampling of runoff and rivers is best suited to those areas where




a small drainage area must be surveyed or where significant manpower resources




are readily available during storm activity.  Manual sampling should not be




considered if the manpower available is less than one person/sampling site.




A "honey dipper" or bucket-type container with a rod or rope is one of the




oldest types of manual samplers.  It is used to obtain grab samples from shallow




runoff channels or storm sewers.




     In addition, samplers have been developed to take dissolved oxygen (DO)




and BOD samples without significant sample aeration.  A BOD bottle(s) is placed




in a bucket-type device and lowered into the stream flow.  Water enters the




inlet and flows through a tube to the bottom of the BOD bottle.  When the




chamber and bottle are full, the device is raised and the bottle is removed




for BOD and/or DO analysis.3  These samplers are not suited to shallow areas.




     Similarly, Van Dorn bottles are manual samplers for deep channel areas.




These samplers consist of an open-ended cylinder which is lowered into the




stream.  When there is a representative sample within the cylinder, a




triggering mechanism is activated to seal the chamber.










          3.2.3.2.2  Automatic Samplers




     Automatic samplers have advanced in reliability and sophistication in




recent years.  These samplers, which are manufactured by a number of firms,




are either the scoop type or the pumping type.  A majority of present-




day samplers are pumping systems.
                                    -17-

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     Scoop samplers utilize a ladle-type dipper activated by a time clock or

electrical impulse.  Periodically, at a prescribed interval, the scoop is

lowered into the runoff stream and a sample is extracted and emptied into a

composite receiver.

     Scoop type samples operate best in sewers and shallow manholes and are

not suited for river sampling.

     Automatic samplers utilizing pumps are suited to both runoff and river

sampling, as the sampling hose can be extended to sites in channels, manholes,

sewers and mid-stream,  while the main unit with the pump and sample bottles

remains in an accessible location.

     Automatic samplers have several advantages in runoff sampling:


     1.   Automatic samplers can assure that the beginning of the storm
          is not missed.   Rising water level in the channel can activate
          a mercury switch on the sampler and the sample pump automatically
          starts.   In  this manner the "first flush" of the storm where the
          highest pollutant loads can occur is accurately measured.

     2.   Sequential samplers containing many small bottles can take inte-
          grated samples (composite of individual samples with time) at
          predetermined intervals within each bottle and still offer the
          discrete-sample advantage of separate bottles.  In this manner,
          individual samples can be taken of the "first flush" of the storm
          while composite samples can be generated for the latter portions
          of the storm event as runoff and loadings decrease.

     3.   Most automatic samplers can be coupled with compatible flow
          measurement  equipment to generate flow proportional samples.

     4.   Refrigerator containers in the samplers are available to maintain
          sample integrity for many parameters,  although they may not be
          necessary for short storm events.


     Table 3-3 presents a comparison of manual and automatic sampling techniques
                                -18-

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                                 TABLE 3-3

                COMPARISON OF MANUAL AND AUTOMATIC SAMPLING
               Manual
         Automatic
    Manpower requirement is quite
    large; therefore, manual samp-
    ling is an advantage only when
    sampling small drainage areas.

    Sample collection equipment
    expenditures are not excessive.
    Simple submersible pumps and/
    or weighted water samplers will
    suffice.
3.  Field measurements can be made
    by individual or combined
    meters.
4.  The beginning of the storm
    event can be missed if mobili-
    zation of manpower is not
    immediate.
5.  Samples will be non-representa-
    tive if untrained collectors
    are used.
6.  If samples need to be collected
    at close time intervals, exten-
    sive manpower may be required
    at each station or the inter-
    vals may be missed altogether.
Manpower requirement is mini-
mal; only maintenance and
removal of samples require
manpower.

Sample collection equipment
becomes a capital expenditure
because it is automated and
must be sheltered from weather
and vandalism and often must
be specially designed.

Field measurements can be made
by meters used in conjunction
with the automatic collection
system, or they may be designed
into the system.

Since automatic collectors can
be activated by precipitation
or an increase in flow or water
level, the initial influence of
the storm will not be missed.

Samples will be lost or non-
representative only if equipment
malfunctions or power source is
interrupted or depleted.

Automatic samplers make collec-
tion easier at close time
intervals.
                                    -19-

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           3.2.4  Type of Sample




      In a runoff sampling program both discrete and composite samples can be




 generated.   Individual discrete samples require more resources and time  for




 analysis  but  better  reflect  rapid changes  in water  quality  and "slugs" of




 pollutants.   Composite samples  are suited  for  river sampling  upstream of




 the  runoff sampling  site and downstream of the site when waste characteristics




 do not  vary significantly over  the sample  interval.




      Samples  for  parameters such  as bacteria counts,  dissolved oxygen, chlorine,




 and  sulfide need  to  be  analyzed quickly  and are, therefore, best taken as




 grab  samples.   Sampling  programs  with an emphasis on  oil and  grease should




 utilize a sampling technique which requires no  transfer of  the  sample  to




 another container, i.e., requires  discrete  samples.




     Most runoff  sampling programs will require a combination  of discrete and




 composite samples.  Discrete samples will  be generated by automatic samplers




with some of the discrete samples  integrated to reflect steady  state conditions




 in the runoff and river during that interval.   For  example, samples of runoff




remaining after the main  storm event can easily be  combined into a composite




sample.  Discrete or "grab" samples are then taken  for parameters such as




fecal and total coliform, dissolved oxygen, temperature, and pH.




     Acceptable storage containers for the pollutants being sampled should




be used.  Specific parameters such as phenols,  oil and grease, and dissolved




oxygen must be collected  in glass bottles.   Reference should be made to




Methods for Chemical Analysis of Water and Wastes and Standard Methods for




Examination of Water and Wastewater
                                   -20-

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     3.2.5  Measurement of Runoff and River Flow




     A weir or  flume  installed across the discharge or storm drain intake is




an excellent means of measuring  the runoff flow rate.  Flumes, which are




specially shaped open channel flow sections providing a restriction in




area, are compatible  with runoff flow measurement since they are self-clean-




ing.  The high  velocity through  the flume can eliminate the deposition of




solids and sediments.  In addition, the accuracy of the flume is less affected




by varying approach velocities than is the weir.5




     Figure 3-3 illustrates  the  application of a weir to measure runoff through




a storm drain in an industrial site.  Weirs, which are obstructions to the flow,




can cause deposition  of materials behind the weir which affect the accuracy




of the flow measurement.  In addition, time delays behind the weir can effect




problems in highly variable  flow conditions.  In these cases, water quality




samples taken at the  weir cannot be correlated with simultaneous flow measure-




ments taken behind the weir, causing difficulty in data interpretation.  There-




fore, weirs should be designed with consideration to the expected flow rates




and should be maintained between storms to prevent interference from solids




deposition.




     In areas where neither  a storm drain nor a defined drainage pattern (to




use plugs) exist, ditches can be dug to collect and channel the runoff flow




for sampling and flow measurement.  Ditches must be constructed carefully




because alteration of the soil porosity will affect runoff quantity and quality.




Ideally, ditches should be lined with impervious material, such as polyethylene




sheeting, to reduce the risk of  pollutants reacting with or leaching into




freshly exposed soil.
                                    -21-

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                ^^S^^^^^ir^^^T^'j^^--1-,-; v^-T^^^s^rT" ~
                •,f£r<> <-. -££.'..r**'-~*-i~e?'-'~>*"~±. —'-^33^ T^..:T'..vs5i:»»mr-^rr.-.—.Tr-—r-^._—
                ^-^^^"i^^'i^l^-^^'^^-'i-^-"^"-^^"-"/ —«ie"*f-. %V-V^:&;»<-J-i.-> !L""*^:-,
                ^MJ-JTC-^I datt .-..JJCi —'BE;. JiTMja»i".-> -l--*^ ^.A*»»j. i  «• •\!»T. ..«.^T.T.-Q**».^.<^. ....r.v->..
                  Figure 3-3:  WEIR INSTALLATION  IN STORM DRAIN


                                       -22-

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      River  flow  can  be  determined  in  several ways.   If  there are U.S. Geolo-




 gical Survey  (USGS)  continuous  recording  gaging  stations nearby upstream and




 downstream  of  the  site,  their flow data will usually be satisfactory.  If




 gaging stations  do not  exist, local flow  rates can be estimated as  the pro-




 duct  of the cross-sectional  area of the river  and measured  velocity.




      In addition,  if  the river  is  dammed, a measurement of  the water level




 behind the  spillway  can be used to provide a suitable estimate of flow, when




 taken at a  distance  behind the  dam equal  to at least four times the water level.









 3.3   Sample Analysis




      Analytical  procedures for  pollutants of interest can be found  in the




 previously  mentioned  Methods of Chemical Analysis of Water  and Wastes and




 Standard Methods for  the Analysis  of  Water & Wastewater.  It is important to




 use these accepted methods to ensure  the data's  comparability with other studies




 and acceptability  to  regulatory agencies.  Analysis  time and cost can be reduced




 by analyzing only  a portion of  the samples (e.g., analyze every third or fourth




 sample) and investigating further  only if important  trends  appear.




      The laboratory  should follow  accepted quality assurance procedures to




 ensure  the validity of  the data.   These procedures should include an inventory




 file  of all instrumentation, standards, chemicals and samples, a file for instru-




 ment  calibration,  and a  semi-annual State or EPA analytical audit.  Additionally,




 it is  recommended  that  the laboratory repeat analyses of a  specified portion of




 the samples (e.g., 10 percent)  and  include an audit  sample  (split sample or




known standard) as a further check on the results.









 3.4  Data Reduction and Analysis




     The data used to evaluate  the  runoff and its impact on the river should be




compiled to present time-dependent  changes in:
                                   -23-

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               river flow
               rainfall
               runoff rates
               pollutant concentrations in runoff, river, and rain


     Hyetographs (plots of rainfall versus time), hydrographs (river flow

versus time) and plots of pollutant concentrations versus time can together

provide a graphic indication of the relationship between runoff and the receivi:

body water quality.

     In addition, flow and concentration data can be related by plotting the

mass loadings of pollutants versus time for both runoff and receiving water

bodies.

     There are a number of ways to present and analyze runoff and receiving

water data to ascertain any trends.  Table 3-4 shows the range of pollutant

concentrations measured at runoff sources and upstream and downstream river

locations in a coal-fired utility non-point source program.1  Alternatively,

only the mean values of each range could have been given.  However, data can be

presented to show its variability.  Giving the standard deviation and the

coefficient of variation of data values is one method of expressing the vari-

ability of sampling measurement.  The sample standard deviation,  S, is the
                                     2
square root of the sample variance, S , which is defined as
                     i
                    S~   =  Z(X-X)

                             n-1                       (3-2)

and the coefficient of  variation, CV  = S
where:    X  = value in sample

          X  = mean value of sample

          n  = number of values in samples.

                                  -24-

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                                                     TABLE 3-4
                            RANGE OF POLLUTANT CONCENTRATION AT THE SAMPLING  LOCATIONS



                                               OF COAL-PIItEl) UTILITY
Pollutant
Total Suspended
Solids
Total Dissolved
Solids
Iron
Aluminum
Manganese
Sulfate
Total Alkalinity
@ CaC03
Total Acidity
(? CaCOa
PH
RANGE OF POLLUTANT CONCENTRATIONS, mg/1
Upstream
Dry
1-21
100 - 170
.14 - .40
N.D.1
.013 - .090
11 - 20
38 - 48
-
6.77 - 7.80
Wet
2-5
60 - 130
.09 - .17
N.D.1
.025 - .040
12 - 17
38 - 42
-
6.60 - 6.76
Downstream
Dry
1-11
80 - 180
.06 - .34
N.D.1
N.D.2- .040
11 - 22
36 - 45
-
6.77 - 7.60
Wet
2-12
-
.09 - 1.03
N.D.1 - 26.6
.030 - .060
12 - 24
40-41
-
6.36 - 6.87
Coal Pile Discharge I'ipe
Dry
12 - 19000
2300 - 21700
160 - 23500
20 - 1800
2 - 100
90 - 57000
-
200 - 38000
1.48 - 3.37
Wet
1700 - 13000
2300 - 115000
700 - 1400
70 - 100
9-15
1600 - 2700
-
1900 - 2900
2.35 - 3. 36
in
           lNone detected,  < Q.2 mg/1




           2Hone detected,  < 0.012 mg/1

-------
     Another method is to state the level of confidence that a measured value

will fall within a certain interval.  Table 3-5 illustrates the 95% confidence

limits of pollutant concentrations for upstream and downstreams sites of an

example sampling program.   In this case, the observed values of the confidence

interval will bracket the mean value 95 out of 100 times.

     If the data is plotted and the magnitude of the parameter versus the

frequency of occurrence demonstrates a normal distribution, then the confidence

limits can be defined by use of Student's 't1 distribution.  The confidence

limits are:

               L  =  X  + t,   ,,   JS2           (3-4)
where:    L  * the limits of the confidence interval

          X  = arithmetic mean of data set with 'n1 elements

          t  = percentile of the 't1 distribution at v degrees of
               freedom and (1-a) confidence limits

          S2 = best estimate of sample variance of 'n' elements in data set


     In the analysis of runoff data, it is sometimes desirable to determine if

there are statistically different pollutant values in the receiving stream

upstream and downstream of the runoff discharges.   While the 't' test can be

utilized to determine if mean values of parameters differ upstream and down-

stream within certain confidence limits, the 'F1 test is used in a similar

manner to derive a confidence interval for the variances of the sample.  The

'F1 ratio is a ratio of variances of the upstream and downstream samples.  The

critical 'F', like the 't1 test, is the percentile of the  'F1 distribution

at v upstream and v downstream degrees of freedom and (1-a) confidence limits.
                                     -26-

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                                TABLE 3-5

                 MEAN POLLUTANT CONCENTRATIONS  WITH 95%
           CONFIDENCE LIMITS ON RIVER AT COAL-FIRED UTILITY


Pollutant
TSS
SOu
Fe
Mn
Alk
POLLUTANT CONCENTRATION, mg/1
Upstream
Dry
8.11 ± 2.26
13.89 ± 0.84
0.23 ± 0.02
0.028 ± 0.005
41.65 ± 0.85
Wet
7.25 ± 3.13
15.09 ± 0.94
0.12 ± 0.03
0.032 ± 0.003
40.33 ± 0.94
Downstream
Dry
4.13 ± 2.04
13.83 ± 1.45
0.21 ± 0.09
0.023 ± 0.005
39.33 ± 0.89
Wet
5.50 ± 2.71
16.65 ± 2.25
0.39 ± 0.27
0.043 ± 0.012
40.30 ± 0.34
95Z confidence limits - x ±
                                   -27-

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Table 3-6 illustrates how the  'tf test and  'F' test were used to determine




if the pollutant values varied to a statistically significant degree upstream




and downstream of runoff sites at a coal-fired utility.1




     If the pollutant values prove to be statistically different upstream and




downstream during a rain event, then further investigation and data evaluation




of the runoff would be made.  The presence of point discharges, tributaries,




etc. between the upstream and downstream sites will complicate the statistical




calculations.  These data must be subtracted from the downstream data before




a statistical analysis can be performed comparing upstream and downstream




conditions.




     In general, increasing the number of samples will increase the confidence




with which conclusions can be drawn.   However, it may take several rainfall




events over several months to get a set of data to properly define whether a




problem exists and, if it exists, to  gather enough data to design a cost-




effective control system.  This procedure is impractical from cost and time




standpoints.   Therefore,  in an attempt to define non-point sources from industry




more cost effectively, the use of a mathematical model as a replacement for




most of the sampling is recommended.   Applicable models are discussed in




Section 4.
                                    -28-

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                             TABLE 3-6

COMPARISONS OF MEAN VALUES & VARIANCES WITHIN 95% CONFIDENCE LIMITS
 AT UPSTREAM & DOWNSTREAM SITES DURING DRY & WET SAMPLING PERIODS
                      AT  COAL-FIRED UTILITY
Pollutant

TSS
SOi,
Ft!
Hn
Alk
1
1-0
f TSS
SOM
Fe
Hn
Alk

TSS
s Downstream




Wet < Dry
Wet < Dry



W*t > Dry

Wet < Dry

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4.0  MATHEMATICAL MODELING




4.1  Model Selection Criteria




     Mathematical models properly applied provide a cost-effective means of




quantifying impacts on water quality resulting from stormwater runoff and




of evaluating alternatives for the control of polluted runoff.  In recent




years many mathematical models have been developed to simulate the quantity




and quality of stormwater runoff and the impact of such runoff on the quality




of water bodies.  These models were developed to satisfy different needs,




ranging from the design of municipal storm sewer systems to the assessment of




land use as it influences flooding and water quality.  Although none of the




models were developed specifically for industrial runoff, some models can be




adapted to such use.  There are many criteria that can be used when selecting




a model, but in general the simplest model which satisfies project needs should




be selected for use since such a model is normally the most economical choice.




     Once a model has been selected, it must be adapted to the specific site




or area being studied.   A model is adapted through the process of calibration




and verification. Calibration is achieved by adjusting the model to reflect




site specific field data.  After the model has been calibrated, it should be




tested against a second set of field data.  If the second set of field data




and the modeled results compare favorably, the model is considered to be




verified and ready for application.




     To be adaptable to industrial applications a model must predict the




quantity and quality of stormwater runoff, the transport of such runoff to




a receiving body of water, and the impact of such runoff on the quantity and




quality of the receiving water.  In addition, since storm events are dynamic,




a model must also be capable of simulating functions in a dynamic (time-




dependent) fashion.
                                    -30-

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     To predict the quantity and quality of stonnwater runoff, a model must




be able to simulate the effects of such items as the intensity and the dura-




tion of the storm event,  infiltration and drainage characteristics, the




accumulation of pollutants between storms, and the washoff of such pollutants




during storms.  For continuous simulation of multiple storms, a model must be




able to simulate dry weather flows as well as storm flows.




     To predict the transport of stonnwater runoff for industrial land use,




a model must be able to simulate overland flow and routing in man-made systems




(channels, sewers, etc.).  To describe the impact of the stormwater runoff on




a receiving body of water, a model must be capable of simulating the quantity




and quality responses of  the receiving water to the runoff.  For increased




flexibility, a model should simulate various types of receiving waters including




rivers, lakes, and estuaries.








4.2  Possible Industrial  Non-Point Source Models




     Table 4-1 lists ten  (10) mathematical models for runoff and/or receiving




waters with possible adaptability to an industrial site.




     The EPA Stormwater Management Model (SWMM), Water Resource Engineers




Stormwater Management Model, Short Stormwater Management Model - RECEIV II




(SSWMM-RECEIV II), Hydrocomp Simulation Program (HSP), and Dorsch Consult




Hydrograph Volume Method  are capable of dynamically simulating the quantity




and quality of stormwater runoff and its impact on the quantity and quality




of receiving waters.  These models can best be described as runoff and receiving




water models.  The quality simulation portion of each of these models must be




modified for industrial application.  The quality relationships are based on




land utilization with all types of industry lumped into one land use category -
                                    -31-

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                               TABLE 4-1




          POSSIBLE MODELS FOR INDUSTRIAL RUNOFF APPLICATIONS






EPA Stonnwater Management Model - Release II  (SWMM)




Water Resource Engineers Stonnwater Management Model




Short Stormwater Management Model - RECEIV II  (SSWMM - RECEIV II)




Hydrocomp Simulation Program (HSP)




Dorsch Consult Hydrograph Volume Method




Corps of Engineers Storage, Treatment, Overflow, and Runoff Model  (STORM)




Battelle Wastewater Management Model (BWMM)




Metcalf and Eddy Simplified Stormwater Management Model




EPA - Hydrocomp Agricultural Runoff Management Model (ARM)




Pyritic Systems:  A Mathematical Model
                                    -32-

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industrial.  No attempt is made to specify the particular type of industry.




If industry-specific data is available on pollutant accumulation, washoff




characteristics, and pollutant characteristics of dirt and dustfall, then




these models can be utilized.




     The Corps of Engineers Storage, Treatment, Overflow, and Runoff Model




(STORM), Battelle Wastewater Management Model  (BWMM), and Metcalf and Eddy




Simplified Stormwater Management Model are capable of dynamically simulating




the quantity and quality of stornwater runoff, but not its impact on receiving




waters.  Consequently, these models are designated as runoff models.  As with




the preceding model group (runoff and receiving water models), the quality




portion of the runoff models is not adequate to meet the program objectives.




Again, the quality relationships for runoff are based on general land utiliza-




tion categories that do not specify the type of industry; hence, quality




relationships addressing pollutant accumulation and washoff must be supplied




for the industry.  In addition to this limitation, the runoff models were not




designed to simulate the impact of stonnwater runoff on receiving waters.  To




simulate this impact, it is necessary to interface the runoff models with a




receiving water model.  RECEIV - II,' developed by Raytheon Company for EPA, is




a Water Quantity and Quality receiving water model that can be used in conjunc-




tion with such runoff models.




     The EPA - Hydrocomp Agricultural Runoff Management Model (ARM) and Pyritic




Systems:  A Mathematical Model are designed to quantify and qualify stonnwater




runoff for the agricultural and mining industries, respectively.  These models
                                   -33-

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are described as specific industry models.  As with the runoff models, the




specific industry models cannot simulate the impact of stormwater flows on




receiving waters.  They must be interfaced with a receiving water model to




simulate such impact.  Since ARM was developed specifically for the agri-




cultural industry, it is not necessary to modify the program quality relation-




ships but only to calibrate and verify existing quality relationships with




field data.  On the other hand, Pyritic Systems:  A Mathematical Model is




designed for a drift (subsurface) mine.  Extension of this model to surface




mining (strip mining) requires both quantity and quality program modifications,




     One combined runoff and receiving water model found very suitable for




industrial application is the Short Stormwater Management Model (SSWMM) -




RECEIV II.   SSWMM, developed by the University City Science Center, Philadelphi|




Pennsylvania in 1976, is a simplified version of the runoff and transport por-




tions of the EPA-SWMM model; RECEIV II, developed by the Raytheon Company and




the EPA in 1974, is a modified version of the receiving water portion of the




EPA-SWMM model.8




     A brief description of SSWMM-RECEIV II, as linked for industrial appli-




cations,1 will follow as an example on  (1) how such models are utilized,




(2) the necessary input data, and  (3) what model results are presented.
                                    -34-

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A.3  Example Industrial Runoff and Receiving Water Model - SSWMM-RECEIV II

     4.3.1  General Description

     SSWMM-RECEIV II is capable of dynamically simulating both the quantity

and the quality of industrial stonnwater runoff and the impact of such runoff

on the quantity and the quality of receiving waters including rivers, lakes,

and estuaries.  The user can define, with certain restrictions, the quality

parameters which he chooses to simulate.  Pollutant transport can be modeled

by both overland flow and sewer routing.  Dry weather flows can also be simu-

lated.  The model is primarily designed to simulate individual storm events

but can be used to model multiple storm periods.

     The linked SSWMM-RECEIV II model1 consists of the following four

programs:


     SSWMM (Short Stonnwater Management Model Program)
     LNKPRG (Link Program)
     SETUP/QUANTITY (RECEIV II Quantity Program)
     QUALITY (RECEIV II Quality Program)


     4.3.2  Computer Requirements

     SSWMM-RECEIV II is written in Fortran IV and was developed for installa-

tion on a Univac 90/30 digital computer with a basic compiler (equivalent to

an IBM 370 Level G compiler).  The program requires 100K bytes of core storage.



     4.3.3  Model Utilization

     Without performing a detailed field measurement program, SSWMM-RECEIV II

can be used to simulate industrial non-point source pollution associated with

stonnwater runoff from material storage piles and from areas of dust and dirt

accumulation.  It also simulates the subsequent impact on receiving waters

(rivers, lakes, or estuaries).  Pollutants that can be modeled are user-selected

and include items such as solids, nutrients, and metals.
                                     -35-

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     Typical model applications for new or existing plants might include:
          Defining industrial stormwater runoff flow and pollutant
          concentrations.  The quantity and quality of stormwater
          runoff at user selected storm intensities can be affected.

          Identifying if an impact results from stormwater runoff
          and if so, defining its significance and frequency of
          occurrence.

          Defining design criteria for stormwater treatment.  The
          volume flow rate and total volume of stormwater runoff
          and the pollutant mass loads caused by the stormwater
          runoff for user selected design storms can be predicted.

          Evaluating stormwater treatment alternatives.  The impact
          of various wastewater treatment efficiencies on water
          quality in the receiving waters can be described.  The
          relative merits (cost vs. improved water quality) of
          different treatment alternatives can be weighed.
     As with any mathematical model, SSWMM-RECEIV II must be applied

correctly.  The user must understand model limitations and use the model

within these limitations.  At this time SSWMM-RECEIV II:
          Cannot simulate stormwater percolation through or the erosion
          of material storage piles, but can only simulate stormwater
          runoff from material storage piles.
                                                                       •

          Has not been tested to simulate dynamic background source
          flows and loadings in the receiving water.

          Must be used within temporal and spatial limits defined in
          the model.
     More detailed descriptions of SSWMM-RECEIV II user restrictions can be

found in the technical report prepared for this program on the sampling and

modeling of non-point sources at a coal-fired utility.1



     4.3.4  Model Input Information Requirements

     Table 4-2 summarizes the model input information requirements for SSWMM-

RECEIV II, as categorized by the individual programs.  SSWMM input includes

information such as physical descriptions of user selected discretization


                                 -36-

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                                                    TABLE 4-2
                             SSWMM -  RECEIV  II  MODEL  INPUT  REQUIREMENTS
     INPUT DATA
                                                                          PROBABLE  DATA  SOURCE
SSVIHM Program
     1)   drainage basins
     2)   land use characterise lea
     3)   spatial  framework  of storm sewers, sub-
         cacchments,  drainage ditches on site
     4)   rainfall intensity
     5)   storm duration and dry days between storm
     6)   dust and dirt accumulation rate
     7)   pollutant characteristics of dust and dirt

LMKFRC Program
     1)    background  receiving flows and
          pollutant mass  loads
     2)    industrial  flows  and pollutant mass loads

Setup/Quantity Program
     1)    spatial segmentation of receiving water Into
          nodes and channels of uniform hydraulic and
          water quality properties
     2)    rates of rainfall and evaporation (optional)

Quality Program
     1)    initial pollutant concentrations in
          receiving water
     2)    reaction rates

     3)    water temperatures and temperature
          compensation coefficients
plant site maps and engineering drawings
National Weacher Service or installation of
on-site rain gage
field measurement and laboratory analysis
USCS. NOAA, and state pollution  control agencies
USGS, 7.5' topographic maps,  US Army Corps of
Engineers flood studies.  National Ocean
Survey bathymetric maps
National Weather Service
plant data, USGS data,  or  state pollution control
agencies
literature values or results of field
measurement program
USCS or state pollution control Field data
with literature values  for coefficients
                                                         -37-

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elements, storm activity, and pollutant generation and washoff data.  LNKPRG

input includes the information output files from SSWMM and an input deck.

The card input consists of user-determined program interface instructions to

link SSWMM and RECEIV II and instructions for non-storm input to or withdrawals

from the receiving waters.  Input requirements for the Setup/Quantity portion

of RECEIV II include' the information output file from LNKPRG and input card

decks, including geographical, hydraulic, and meteorological data describing

the receiving waters.   The QUALITY program requires input data describing the

initial pollutant concentrations in the receiving water and pollutant reaction

kinetics.



     4.3.5  Model Results

     Model results are printed for each of the programs (SSWMM, LNKPRG,

SETUP/QUANTITY, QUALITY) in the SSWMM-RECEIV II model.  SSWMM-RECEIV II model

utilizes a mixed system of English/metric units.

     Results from SSWMM include:


     •    Initial pollutant loads (mg) on each subcatchment prior to
          the storm.

     •    Stormwater flow (cfs) and associated pollutant mass loads
          (Ibs/min) for each timestep.

     •    Total amount of rainfall (cu. ft.), total infiltration (cu.
          ft.), total runoff (cu. ft.), total surface storage (cu. ft.),
          and the percentage error computed for unaccounted water.

     •    Total pollutant mass (Ibs) washed from the land surface
          during the storm.


     LNKPRG results include the stormwater flows and pollutant mass loads

from SSWMM converted to a format acceptable to RECEIV II (SETUP/QUANTITY,

QUALITY).
                                   -38-

-------
     Results from SETUP/QUANTITY include:


     •    Hydraulic head (m) or water level in the receiving water
          at each node for each timestep.

     •    Water flow (m3/sec) and velocity (m/sec) in the receiving
          water in each channel for each timestep.
     Results from QUALITY include:


     •    Pollutant concentrations (mg/1) in the receiving water at
          each node for each timestep.

     •    Daily maximum, minimum, and average pollutant concentra-
          tions (mg/1) in the receiving water at each node.


     The complete set of results, then, quantifies and qualifies stormwater

runoff and its impact on the quantity and quality of the receiving water.
                                    -39-

-------
 5.0   PROGRAM COSTS AND TIME CONSIDERATIONS

      The  cost and time requirements of a runoff study will vary with the

 number of sampling sites, parameters to be measured, number of samples to

 be taken,  as  well as other complicating factors.  These factors may include

 the interference of other sources or tributaries in the test area and the

 variability of river flows.  This section outlines the considerations necessary

 for planning  the resources to conduct an industrial runoff measurement and

modeling  study.



5.1  Manpower for Measurement Survey

     In order to outline manpower requirements, a typical runoff study, includ-

ing modeling, was developed.   This runoff study was based on several assump-

tions:


     (1)   site was 300 miles from contractor's base
     (2)   most runoff collected by storm sewers
     (3)   regulated flow stream at 60 m3/s
     (4)   2 receiving body and 4 runoff sampling sites
     (5)   4 week sampling program  (16 weeks without modeling)
     (6)   960 samples collected  (3840 samples without modeling)
     (7)   6 parameters analyzed
     (8)   500 samples analyzed (2000 samples without modeling)


     Table 5-1 shows an estimate of the manpower requirements for the assumed

4-week sampling program using modeling (and the assumed 16-week program with-

out modeling).  The Senior Engineer/Scientist would serve as project coordi-

nator and review the conclusions of the field program.  The Engineer/Scientist

would develop the test plan,  supervise the field work and analyze the data.

Preparation and field support and analyses would be handled by-the Junior

Engineer/Technician.
                                    -40-

-------
                               TABLE 5-1

           ESTIMATED MANPOWER REQUIREMENTS FOR RUNOFF STUDY
        Task

1.   Pretest Survey
     & Site Selection

2.   Test Plan

3.   Preparation For Field

4.   Field Study

5.   Sample Analysis

6.   Data Evaluation


     Total Hours
    Senior
Eng./Scientist
    (Hours)
     20

      8
     36
  Eng./
Scientist
 (Hours)
   40

  120  (100)

   40  (80)

  320  (1280)

  240  (480)

   40  (240)


  800  (2220)
  Junior
Eng./Tech
 (Hours)
     40

    180 (360)

    320 (1280)

    240 (1400)

     40 (100)


    820 (3180)
( ) without modeling
                                    -41-

-------
     Using  this sampling program as a guideline, the manpower costs for




individualized programs can be estimated.








5.2  Other Direct Costs For Measurement Survey




     Table 5-2 presents estimated costs for equipment purchases and other major




expenditures excluding travel and subsistence for a program including model-




ing.  The vehicle rentals and on-site communication are estimated to be $2200




and $850 respectively for a program which does not include modeling.  The




estimate for equipment assumes a laboratory is available for use in the program




without additional equipment expense.   The equipment costs can be mitigated




by taking advantage of rental or lease arrangements offered by many vendors.




These costs will vary proportionally with the complexity of the source rather




than the duration of the study.




     In addition,  Table 5-3 outlines the cost per sample of some parameters




for analysis in an industrial runoff study.  These costs are from one com-




mercial laboratory which was found to be in the median range for such analysis




and are quoted for 6 or more samples.   Some laboratories offer a volume rate




for large numbers of samples and these costs can be adjusted accordingly.








5.3  Elapsed Time Requirements




     Figure 5-1 shows an estimate of the elapsed time requirements for con-




ducting a field survey program.   The entire survey using modeling can be com-




pleted in 3-6 months.  Equipment preparation and acquisition take the longest




amount of time to complete.  If  a model is not used, the program will take from




9 to 12 months to complete.
                                    -42-

-------
                               TABLE 5-2

                      ESTIMATED COST OF EQUIPMENT-
        ESTIMATE OF OTHER DIRECT COSTS FOR EXAMPLE RUNOFF STUDY
1.   Equipment

     Sequential Samplers (6)                           $  9,050

     Flow Measuring Device & Recorder (4)                 8,500

     Rainfall Measuring Device & Recorder (2)             2,130

     pH Monitor (2)                                       2,200-3,200

     DO Monitor (2)                                       4,900

     Dual Pen Recorder (2)                                1,100-3,200

     Boat with Outboard Motor                             1,100

     Misc.                                                1,100


2.   Shipping                                               850


3.   Vehicle Rentals                                        650


4.   On-Site Communication                                  220


     TOTAL (12/77) DOLLARS                             $31,800-34,900
                                   -43-

-------
                          TABLE 5-3
          ESTIMATED COST/PARAMETER ANALYZED/SAMPLE
Parameter
acidity
alkalinity
BOD 5
COD
color
cyanide
dissolved oxygen*
hardness
ammonia nitrogen
total Kjeldahl nitrogen
organic nitrogen
nitrite nitrogen
nitrate nitrogen
oil and grease
     soxhlet extraction
     infra-red
TOC
pH*
phenol
total phosphate
total solids
sulfate
turbidity
common metals (each)
              Cost/Sample
(based on 6 or more samples,  1978 dollar;
               S 2.00
                 2.00
                 7.25
                 6.25
                 2.00
                 5.00
                 2.00
                 3.25
                 3.50
                 5.50
                 5.50
                 2.00
                 3.50

                 7.25
                15.75
                 7.50
                 2.00
                 5.00
                 7.50
                 3.25
                 6.50
                 2.00
                 5.00
 *can be determined in the field with continuous monitors
                               -44-

-------
       ELAPSED WEEKS
10          15
                                          20
25

                                            J	i	I	I	L 1  L_ II
I	I	I
             _i	i	I	i  i   i  i
                  10           15           20
                        ELAPSED WEEKS  -
25
30

Pretest Survey
& Site Selection

TocF Plan



Preparation &
Equip. Acquisition

*-Field Study
i
Sample
Analysis

Evaluation

1

*



'<%%,

wtm

^^^^^
i
!
' , . , . j ......
i mzz%t
30
                                                                           PROGRAM ELEMENT
                                                                           IF ALL EQUIPMENT IS
                                                                           IMMEDIATELY AVAILABLE
                                                                           PROGRAM ELEMENT IF
                                                                           EQUIPMENT MUST BE
                                                                           PURCHASED
Figure 5-1:  Elapsed time estimates for runoff study which is to be used
             in conjunction with a mathematical model

-------
5.4  Labor and Computer Time to Implement SSWMM-RECEIV II for Case Run




     The labor and computer time necessary to utilize SSWMM-RECEIV II are




directly related to the complexity of the plant site to be modeled and are




site specific.  To provide comparative information to the potential user,




a program run was designed and executed for a coal-fired utility plant on




a river system and the labor and computer time requirements for this




exercise are listed.   Labor includes the time to define the problem, gather,




reduce, code, and keypunch the input information, run the model, and analyze




the results.  Estimates are based on using a Univac 90/30 computer.  Operational




costs may differ for other computers.




     The labor and computer time for the sample program is listed  in Table  5-4.




To define the problems, gather, reduce, code and keypunch the input informa-




tion, run the model, and analyze the results require 12 hours of a Senior




Engineer/Scientist, 48 hours of an Engineer/Scientist, and 88 hours of a Junior




Engineer/Scientist.  Computer time requirements based on a Univac  90/30 rate of




speed were 14 minutes and 14 seconds.
                                   -46-

-------
                                             TABLE 5-4
                           LABOR AND COMPUTER TIME BASED ON EXAMPLE CASE
Task
1. Problem- Definition

2. Input Data Acquisition

3. Input Data Reduction


4. Input Coding/
Keypunching


5. Run Model (including
ilobup.jjiny)
6. Analyze Results
TOTAL
Sr Engr/Sci
8







.




4
12
Labor (Man-Hours)*
Engr/Sci
8

8

20







4
8
48
Junior Engr/Sci


16

40



16



8
8
88
Computer Time**

SSWMM - 44 sec.

LNKPRG - 17 sec

SETUP/QUANTITY-
9 min. , 34 sec


QUALITY - 3 min. ,
39 sec.



14 min. , 14 sec.
 * Based on using a Univac 90/30 computer.
** Based on Univac 90/30 rule of speed.

-------
6.0  SUMMARY;  HYPOTHETICAL CASE




     Application of Che Measurement and Modeling Techniques to Stonnwater




Runoff from a Coal-Fired Utility on a River.








6.1  Introduction




     This section provides an example of the application of the measurement




and modeling techniques to a coal-fired electric utility plant.




     The example is an uncomplicated case applied to an average-sized




plant on a small river.








6.2  Background Information




     The objective of the sampling program was to provide data to evaluate the




effects of runoff on the river.   The following information was obtained




from an initial site visit and interviews with plant personnel.




     Figure 6-1 shows a plant layout of a coal-fired electric utility station.




With a typical 100-day supply of coal on hand, the 200,000 tons of coal cover




11 1/2 acres.   The ash-handling area covers 23 acres on the opposite side of




the plant.  The coal pile runoff drains into a branched storm sewer, while the




ash pile runoff is discharged from a collection pipe into the river.




     The site is located on a fast-moving, very clean river.  Other than the




cooling water intake and discharge, there are no other normal discharges into




the river.  Runoff patterns and drainage areas are visible in the texture and




type of soil,  rock, and vegetation.  These drainage areas are practically




flat, making runoff flow measurements difficult.
                                   -48-

-------
                   ^'ii^i^ j.
                   ^vv^y^'4
                                        E
                                         LESEND
                                 5fC AUTOMATIC SAMPLERS
                                 • PLUS COLLETTORS
                                 	 APPROXIMATE BOUNDARIES OF
                                   DRAINAGE BASINS
Figure 6-1:  Site layout, coal-fired utility station
           example case.
                     -49-

-------
6.3  Selection of Sampling Sites

     Figure 6-1 also shows the delineation of drainage basins and the

locations of sampling sites.  As runoff from the coal pile, fly ash

pile and roof of the plant were of major interest, sampling stations were

placed in these areas.  The river background sampling site was located upstream

of the ash pile runoff's entry into the river.  It was placed approximately

one third of the distance across the river and the sampler intake was adjusted

to 1/3 the river depth.  The downstream site was placed approximately 150

meters (500 feet) downstream of the storm sewer entry into the river, where

the discharge plume was dispersed.



6.4  Sampling Methodology

     6.4.1  Parameters for Analysis

     For evaluation of coal and ash pile runoff, the following constituents

were of interest in both the river and runoff:


          Total suspended solids
          Total dissolved solids
          Iron
          Aluminum
          Sulfate
          PH
          Manganese
          Alkalinity


     Of the above parameters, only sulfate and alkalinity requires cooling of

the samples and analysis within a short period.  Analysis of samples for these

parameters was performed in a field laboratory to guard against sample degrada-

tion.  The samples of metals were acidified and shipped to the home laboratory

with solids samples for analysis.  Values of pH for the river stations were

determined in the field with pH probes.
                                    -50-

-------
     6.4.2   Sampling  Frequency




     In order  to sample  the  first  flush of runoff at the initiation of the




 rainfall,  automatic samplers were used which were  activated with the  rising water



 level.   In order to collect  representative  samples  at  this  stage of the  storn,




 the automatic  samplers drew  samples every 2 minutes and these were integrated




 to represent 10 minute intervals.  The sample plugs were also emptied every




 10 minutes.  If the storm duration was greater than 90 minutes, pollutant




 concentrations leveled out and the sampling  frequency was consequently reduced




 to half-hourly integrated samples.  This rate was continued after the storm




 until noticeable effects had  diminished.




     River  samplers were set  to integrate hourly composites of 15-minutes




 discrete samples during dry weather for background flow data.









     6.4.3  Method of Sample  Collection




     As shown  by Figure 6-1,  automatic samplers were utilized in the storm




 drains and  at  the river stations.  Samples of runoff around coal and ash piles




were collected in sampling plugs.




     The automatic samplers were pump-type sequential samplers.  The river




 samplers were  set in inflatable rafts since the sample line could not reach




 far enough  into the river and still maintain proper purge and backflush cycles.




 These rafts also supported the pH  probe while the monitors were sheltered on




 land.









     6.4.4  Flow Measurement



     For the storm sewer, flow data were obtained by a combination rectangular




 and V-notch weir located at the discharge end of the pipe.   The V-notch is used




 to measure  the lesser dry weather  flows and the rectangular weir measures the




 wet weather flows.  The water level sensor must be calibrated to a combination







                                  -51-

-------
weir.  Flow data from the ash pile area were obtained by applying standard




hydraulic formulas to the depth, slope, and diameter of the collection pipe.




Dry weather flow from this pipe and the cooling water discharge flow and




quality were also measured.




     River flow data were obtained from USGS gaging stations located approxi-




mately 0.5 miles upstream and 1.5 miles downstream.  The upstream gaging




station was located downstream of the nearest tributary and there were no major




point source discharges between the gaging station and the sampling site.




Rainfall data were obtained from a rain gage installed at the plant.









     6.4.5  Sample and Data Analysis




     Samples taken at the coal-fired utility site were analyzed in accordance




with procedures described in Standard Methods for the Examination of Water




and Wastewater.  After trends in the analysis results were established, every




fourth sample was analyzed.




     As shown in Tables 3-4, 3-5, and 3-6, analytical results were arranged in




dry and wet weather categories,  by pollutant, to facilitate the comparative data




analysis.  Sample variance, standard deviations, etc. were calculated and analys




of the variance and means were performed to establish the comparability of the




site data.




     The upstream and downstream dry weather data should vary in a similar




fashion and their means should be essentially the same.  Conclusions concerning




wet weather data were more subjective.  If the runoff affects the river, then




the downstream values should be greater than the upstream on a statistically




significant basis.




     Comparison of the hydrographs and graphs of pollutant concentration versus




time and interpretation of statistical analyses provided the basis for




conclusions on the runoff's effect on the river.
                                   -52-

-------
6.5  Model Application  to  Example Case




     The SSWMM-RECEIV II model was selected for the case of the coal-fired




utility station on a river.  This model, as previously discussed, simulates the




conveyance of the runoff to  the river and the impact of the runoff on the down-




stream water quality.




     In addition to the water sampling described in Section 6.4, dust and




dirt accumulation at the plant site was measured and analyzed  to determine




its constituents.  The  stormwater runoff from the coal and ash piles as well




as the runoff from the dust  and dirt  constituted the sources of non-point




source pollution input  to  the model.  The pollutants modeled included total




suspended solids, dissolved  solids, sulfates, total iron, manganese, and




aluminum.




     Land and river areas  wera divided into discrete elements for modeling pur-




poses, as depicted in Figure 6-2.  Input data required for the river elements




are, for the nodes:  (1) water surface elevation, (2) surface area,  (3) depth




of bottom, and (4) Manning coefficient, and for the channels:  (1) channel




length, (2) width, (3) depth, (4) Manning coefficient, and (5) initial velocity.




Input data for the land elements include the physical dimensions of the runoff




collection system as outlined in Table 6-1.




     Timesteps were chosen for the model, with 60 seconds for the hydraulic




river model, 720 seconds for the RECEIV II Quality model, and 900 seconds for




the SSWMM stormwater model.  In addition, storm activity was recorded and rainfall




intensity was input to SSWMM, as well as background river and non-storm-related




source flows.
                                   -53-

-------
        1000'
       1000
                                               i   .,   BACKGROUND RIVER FLOW =
                                                  1/141.6 mVsec (5000 ftVsec)
                                                 /
                          STORMWATER DISCHARGE FROM
                          ASH HANDLING AREA;COOLING
                             WATER WITHDRAWAL =
                          5.7 mVsec  (200 ftVsec)
                                                 STORMWATER DISCHARGE FROM
                                                 COAL PILE AND PLANT AREA;
                                                 COOLING WATER DISCHARGE =
                                                 5.7 m3/sec  (200 ftVsec)
	SUBCATCHMENT  BOUNDARY
---STORM SEWER SYSTEM
©  LAND ELEMENT  NUMBER
 1   RIVER NODE  (JUNCTION)NUMBER
 i   RIVER CHANNEL NUMBER
                                                 ARTIFICIAL CAM
            Figure 6-2:
Land and river model element schematic,
coal-fired utility station example case
                                      -54-

-------
                                        TABLE 6-1

                          PHYSICAL DIMENSIONS OF LAND ELEMENTS

                         COAL-FIRED UTILITY STATION EXAMPLE CASE
Element
Number
Description
 Type*  Area (Acres) or   Slope    Width Overland
        Pipe Diam. (ft)  (ft/ft)     Flow (ft) or
	Pipe Length (ft)
6


7


8
Ash Handling Area
(Dust & Dirt
Accumulation)

Inlet to River for
Ash Handling Area

Coal Pile Area
(Pile & Dust.& Dirt
Accumulation)

Storm Sewer Draining
Coal Pile Area

Plant Area (Dust fie
Dirt Accumulation)

Storm Sewer Draining
Coal Pile Area

Storm Sewer Draining
Plant Area

Storm Sewer Draining
Coal Pile & Plant
Areas

Inlet to River for
Coal Pile & Plant
Areas
            23.0
                                           .01
                                                                   1000.
                                                                                50
            11.5



             1.5


            11.5


             1.5


             1.5


             3.0
                                           .01
                                            .01
                                           .01
                                           .01
                                            .01
                                            .01
                                                                    500.



                                                                    335.


                                                                   2000.


                                                                    250.


                                                                    667.


                                                                    250.
                                                                               100,
                                                                               100.
  1 = Subcatchment
  2 = Gutter (Pipe or Inlet)
NOTE:   For a subcatchment,  use  area, slope, width of overland flow, and
       percent imperviousness.   For a gutter (pipe), use pipe diameter,
       slope,  and  pipe length.   For a gutter (inlet), just identify type,
                                          -55-

-------
      Selected results  from the case run are presented for each program  in  SSWMM-




 RECEIV  II  (SSWMM, LNKPRG, SETUP/QUANTITY, and QUALITY)  in Tables A-l, A-2, A-3,




 and A-4  in the Appendix.  Selected SSWMM results  (Table A-l)  include  the pol-




 lutant mass  loads on each subcatchment prior to the  storm,  flow and pollutant  mass




 loading  information for each inlet to the river at time 50,400 seconds  of  Day  2,




 total rainfall, total  infiltration, total runoff, total surface storage, per-




 centage  error for unaccounted water during the storm period, and the  total




 storm-induced pollutant loads for each inlet to the river.  Selected  LNKPRG




 results  (Table A-2) include background river and power  plant cooling  water




 loadings.  Other selected LNKPRG results include flows  and stormwater pollut-




 ant concentrations from SSUMM.   The selected results from SETUP/QUANTITY




 (Table A-3) include the head or water level at each node and the river  flow




 and velocity in each channel.  Selected QUALITY results (Table A-4) include




 the pollutant concentrations at each node (junction) in the river and the




maximum, minimum, and average pollutant concentrations  for each node  in the




 river for Day 2.









 6.6  Conclusion




     This hypothetical case of an industrial runoff study demonstrates how such




a study  is planned and enacted.  The costs incurred in  the project can be




developed from the cost data presented in Section 5.




     The case of the coal-fired utility plant is based  on TRC's collective




 efforts  in this field.  It has been outlined to show in an uncomplicated manner




 a diverse number of runoff sources and the measurement  and modeling that can




 be used  to address the impact of industrial runoff.
                                   -56-

-------
REFERENCES
                   Sampling and Modeling of Non-Point Sources at a Coal-Fired
Utility by TRC - THE RESEARCH CORPORATION of New England for the Industrial
Environmental Research Laboratory, Research Laboratory,  Research Triangle
Park, N.C.

 2EPA-625-16-74-003 Methods for Chemical Analysis of Water and Wastes,  U.S.
Environmental Protection Agency, Washington, D.C. (1974).

 technical Bulletin No. 183, National Council of the Paper Industry for Air
and Stream Improvement, June 1965.

 ^EPA-600/4-77-031 Sampling of Water and Wastewater. Shelley, P., Office of
Research and Development, U.S. EPA.

 5Stevens Water Resources Data Book, Leupold & Stevens,  Inc., June 1975.

 6Experimental Statistics, Handbook 91, U.S. Dept. of Commerce, 1966.

 7New England River Basins Modeling Project Final Report,  Volume Ill-
Documentation Report, Part I-RECEIV II Water Quantity and  Quality Model,
Raytheon Company (Washington, D.C.:  U.S. Environmental  Protection Agency),
EPA Contract No. 68-01-1890, December 1974.

 8Stormwater Management Model, Metcalf & Eddy, University  of Florida and Water
Resources Engineers, Inc., 4 Volumes, U.S. EPA Report Nos. 11024 DOC 7/71,
8/71, 9/71, and 10/71.
                                    -57-

-------
                APPENDIX
 SELECTED RESULTS - SSWMM-RECEIV II MODEL
          CASE RUN FOR EXAMPLE
INDUSTRIAL NON-POINT SOURCE RUNOFF STUDY
                   -58-

-------
                                                                  TABLE A-l


                                                   TRC SSWMM SELECTED MODEL  RESULTS
                                                 COAL-FIRED UTILITY STATION  EXAMPLE CASE



            POLLUTANT  CONCENTRATIONS  AND  INITIAL HASS LOADS AREPfllNTEO OUT FOR  6 CONSTITUENTS.
           THESE  CONSTITUENTS,  IN  ORQER.  AUC	
                          2	TOTAL  SUSPENDED  SOLIDS
                          j	SULFATES
                          »	TOTAL  IRON
                          S	MANGANESE
                          t	ALUMINUM
                          7	TOTAL  DISSOLVED  SOLIDS


           ON WATERSHED  I THERE  ARE  1.I110E  07  GRAMS OF DUST  AND DIRT.

                     THE  KG  CONTENT OF EACH CONSTITUENT ONTHIS UATEIISHLD IS
                     O.OOOOE-Ol  I.I227E  10  l.l3i|GE  0?  2.26BOE OS  S.67UUE  06  5.6700E  0?  1.1340E 08   O.OOOOE-OI

                     THE  HG  CONTENT OF EACH CONSTITUENT IN THE CATCHBASINS FOR  THIS WATERSHED IS
I                     O.OOOOE-01  O.OOOOE-01  O.OOObE-01  U.OOOOE-01  O.UOOOE-OI  O.OOOOE-01  O.OOOOE-01   O.OOOOE-01
Ln
vo

           ON WATERSHED  3 THERE  ARE &.6700E  06  GRAMS OF DUST  AND DIRT.

                     THE  KG  CONTENT OF EACH CONSTITUENT ONTHIS WATERSHED IS
                     O.OOoOE-01  S.6I33E  09  S.6700E  06  L1340E OB  2.BJ50E  06  2.83SOE  07  S.6700E 07   O.OOOOE-OI

                     THE  HG  CONTENT OF EACH CONSTITUENT IN THE CAICHBASINS FOR  THIS WATERSHED IS
                     O.OOOOE-01  O.OOOOE-01  O.OOOOE-OI  O.OOOOE-01  O.OOOOE-Ol  O.OOOOE-Ql  O.OOOOE-01   O.OOOOE-01


           ON WATERSHED  S THERE ARE S.6700C 06  GHAHS OF OUST  AND CIRT.

                     THE HG CONTENT OF EACH CONSTITUENT ONTHIS WATERSHED IS
                     O.OOOOC-01  S.613JE  09  S.670CE  06  1.13HOE OB  2.83SOE  06  2.B3SOC  07  S.6700E 07   O.OOOOE-01

                     THE HC CONTENT OF EACH CONSTITUENT IN THE CATCHBASINS FOR  THIS WATERSHED IS
                     O.OOoOc-01  O.OOOOE-01  O.OOOOE-01  O.OOOOE-01  O.OOOOE-Ol  O.OOOOE-01  O.OOoO£-01   O.OOOOE-01

-------
                                                                 TABLE A-l
                                                                 (Cont'd)
               COAL  riRCU  UTILITY  SlAllON  EXAHPLC  CASt


             SUMHiRY OF  QUANTITY AMD  OUALllV  RESULTS  FOR  1IMC     SUMOO.
             QUANTITY -  FLOW  IN CD FT/SEC
I             QUALITY - POLLUTANT LOADINGS  IN  LB/HIN;  COLIFORHS  (IF  HOOCLCOI  IN  HPN/HIN
ON
I               ELEMENT    FLOW                    TSS      SULFATES    TOTAL  FE    MANGANESE     ALUMINUM        TOS


                  ?        2.83       0.00(1      Jb.J13        0.1611        3.282        0.082       0.821        1.641
                  9        5.SU       O.OUa      <|6.MU1        0.1223        2.446        0.061       fl.612        1.223

-------
                                                          TABLE A-2

                                             TRC LNKPRG SELECTED MODEL RESULTS
                                          COAL-FIRED UTILITY  STATION EXAMPLE CASE
BACKGROUND |«iFONHAI10N  41  tlHC  =       0.   IS AS FOLLOWS
       now in cu M/stc
       POLLUTANT  LOADINGS  IN  HG/SCCj  COLIFORHS  IIF MODELED) IN MPNE«06/SEC.

  PTSRC      FLOU      SOU    TOTFt        HN                                  AL                        TOS      TSS



     3   1H1.6000  0.1C OT  12480.0    4250.0      0.0      0.0      0.0 141600.0      0.0      0.0   0.7E 07  0.1E 07

     4    -5.7000  S7000.0   1710.0     170*0      0.0      0.0    '  0.0   5700.0      0.0      0.0  2SSOOO.O  57000.0

     5     5.7000  57000.0   1710.0     170.0      0.0      0.0      0.0   5700.0      0.0      0.0  285000.0  57000*0

-------
                                                                 TABLE A-2
                                                                 (Cont'd)
          INPUt INTO KCCCIV II AT HUE  SOUOO.  SCC  ARC AS FOLLOWS
          FLOW IN CU MXSCC
,          POLLUTANT LOADINGS IK MG/SEC; COLIFOHHS  IIF HODELEOI IN Hf>NC«06/SEC.
ON
V    INLET      FLOU      so*    TOTFC       HN                                  AL                        TOS      TSS



        1     O.C80Z   1210.6  21812.1    620.3      0.0      0.0      0.0   6203.0      0.0      0.0  12406.0 289644.*

        2     0.1SS9    924.6  18*91.7    
-------
                                                                TABLE  A-3
                                          TRC  RECEIV II SETUP/QUANTITY SELECTED MODEL RESULTS
                                                 COAL-FIRED UTILITY STATION EXAMPLE CASE
 EXANPLC RUN 1
 ILL LOADINGS TREATED AS FINITE SOURCES
  »ASIN CONTAINS 3 SUBCAKHHENTS,1 PIPES,AND 2 INLETS

  BAY IS   2
                  TOTAL  AREA=16  ACRES
U)

HOUR
0.00
0.20
0.10
0.60
0.80
1.00
1.20
1.10
1.60
1.60
2.0Q
2.20
2.40
2.60
2.bO
3.00
3.20
J.lO
J.60
3.80
1.UO
1.20
1.10
1.60
1.80
5.00
5.20
5.10
5.60
•,.81)
6.00
6.20
6.40
6.60
6.80
7.00
7.20
7.40
7.60
JUNCTION 1
HEAD (HI
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.S2
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.'i2
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
                                             TIME  HISTORY  OF  STAGE
JUNCTION    2
    HCADIH)

      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.2*
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.2«
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
      2.29
JUNCTION    3
    HCAD(H)

      2.05
      2. 35
      2.35
      2.05
      2.35
      2.05
      2.05
      2.35
      2.35
      2.05
      2.)S
      2.35
      2.05
      2.05
      2. 05
      2. 05
      2.35
      2.05
      2.35
      2.95
      2.05
      2.05
      2.05
      2.05
      2.35
      2.05
      2.05
      2.05
      2.05
      2.05
      2.05
      2.05
      2.05
      2.35
      2.05
      2.05
      2.05
      2.05
      2.05
JUNCTION 4
HEADIHt







































.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
JUNCTION S
HEAOCH1
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.93
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
JUNCTION
HEAOCHl
255.55
257.59
259.62
261.66
263. 70
265.73
267.77
269.60
271.84
27j. aa
275.91
277.95
279.98
282.02
284.06
286.09
288.13
290.16
292.20
291.24
296.27
298.31
300.35
302.36
33
-------
                                                                  TABLE  A-3
                                                                  (Cont'd)
.c-
I
         .•0
         .00
 uto
  .to
 '.GO
  .20
  .40
 9.60
 9.80
10.00
10.20
10.10
10.60
10.80
11.00
11.20
11.40
11.60
11.60
12.00
12.20
12.HO
12.60
12.60
13.00
13.20
13.00
13.60
13.80
14.00
11.20
1N.HO
11.60
In. 80
IS. 00
IS. 20
15.10
IS-fcO
IS. 80
16. CO
16.20
16.10
16.60
16. bO
17.00
17.20
I7.*0
17.60
17.80
18.00
l». 20
\m."»a
2.52
2.S2
 .52
 .52
 .52
 .52
 .52
 .52
 .52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.S2
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.S2
2.52
2.52
2.53
2.53
2.53
2.52
2-52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.S2
2.29
2.29
2.2*
2.7V
2.29
2>29
2.29
2.2'
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2-29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.2«
2.05
2.')5
2.05
2.15
2.US
^.15
2.35
2.05
2.05
2.US
2.35
2.05
2.U*.
2.35
2.05
2.05
2.05
2.OS
2.05
2.05
2.05
2.05
2.OS
2.35
2.05
2.05
2.05
2.05
2.05
2.05
2.05
2.05
2.35
2.35
2.35
2.05
2.05
2.05
2.05
2.05
2.05
2.05
2.05
2.05
2.05
2.05
2.OS
2.05
2.05
2.05
2.05
2.05
2.05
2.05
.76
.76
.76
.76
.76
.76
.76
.76
.76
.74,
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
0.90
n.9o
0.90
0.90
0.90
0.90
0>90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
O.yQ
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
331.96
337.00
339.01
311.07
313. 10
315.14
347.18
319.21
3S1.2S
353.28
355.32
357.36
359.39
361.13
363.17
365.50
367.51
369.57
371.61
373.65
375.68
377.72
379.75
381.79
383.83
385.86
387.90
389.94
391.98
394.02
396.06
39B.1Q
400.14
402. 18
434.22
406.26
404.30
410.34
412.37
414.41
416.45
418.49
420.53
422.57
424.61
126.65
428.69
430.73
432.77
434.80
436.84
438.88
440.92
442.95

-------
                                                          TABLE  A-3
                                                          (Cont'd)
K.60
18.10
iv.ro
19.20
19.HO
19.60
19. 80
20.00
20.20
2U.«tO
20.60
20.ED
21.00
21.20
21.-40
21.60
21.60
22.00
22.20
22. 00
22.60
22.60
23.00
23.20
2J.<|0
21.60
23.BO
2«.00
2.52
2.52
2.S2
2.52
2.52
2.S2
2.S2
2.52
2.52
2-52
2.52
2.52
2.52
2*52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.52
2.S2
2.52
2. 52
2.S?
2.52
2.29
2.29
2.29
2.29
2.21
2.29
2.29
2.2V
2.2*
2.29
2.29
2.29
2.29
2.29
2.29
2.29
2.2?
2.29
2.29
2.29
2-29
2.29
2.29
2.29
2.29
2.29
2.OS
2.OS
2.OS
2.05
2.35
2.05
2.05
2.35
2.05
2.05
2-05
2.35
2.OS
2.05
2.05
2.05
2.35
2.05
2.115
2.OS
2.TS
2.05
2.05
2.05
2.05
2.05
2.05
2.OS
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
400.99
4*7.03
409.06
051.10

-------
        RUN 1
ALL LOADINGS TRCATlb AS FINIlt  SOURCES
                                                              TABLE A-3
                                                              (Cont'd)
BASIN CON1AINS 3 SUBCATCHMENTS ,4 PIPES,AND 2 INLETS

DAY IS   2
TOTAL AREA=46 ACRES

HOUR

D.OO
0.20
O.qC
O.bC
o.so
.Ot
.20
.10
.60
.ao
2.0U
2.20
2. HO
2.60
2.60
1.00
3.20
1.40
1.60
i.ac
4.30
1.20
4. 40
4.60
«t.ac
5.00
S.2C
s.40
5. GO
.80
.00
.20
.10
.60
.80
7.00
1.20
1.<»0
CHANNEL
FLOW
CU M/S
111.60
I1* 1.60
1H. 40
11*1.60
1"|.60
141.60
141.40
111. bO
1*11.60
It 1.60
141.60
111.60
111.60
111.60
111.60
lH.bO
141.60
111.60
1«1.60
111.60
1*1. hO
H1.60
lll.hO
141.60
141.60
III. 60
111. CO
141.60
141.60
141.60
141.i>0
141. bC
141.60
141.60
141.60
141.60
111. 60
V*t .bO
1 2
VCL.
H/S
O.BB2
0.882
0.862
0.382
0.06?
0.882
3.482
3.182
0. 862
0.882
3.882
0.882
0.882
0.88?
o.aa?
O.UB2
0.882
0.1B2
o.na?
0.862
O.B&2
0.88?
0.882
0.8hZ
o.abz •
0.982
0.3*2
0.802
U.«32
0.862
U.3B2
0.382
U.OB2
0.882
O.OB2
0.862
O.U82
O.uaj
HE II I
CHANNEL
FLCU
CU H/S
135.93
Hb.VO
135.9Q
m.su
US. 90
135. VO
1 35.93
135. *0
MS. 93
135. SO
US. SO
US. 93
135.91)
115.90
135.90
135.90
135. SU
135. SO
1 35. SO
115.90
135. VO
115.90
135.9i)
135.90
135.90
135.90
135.90
135. VQ
135.9(1
135. S3
135.90
155.90
135.90
lib. 90
115.90
131. VO
135.90
11S.«0
S T 0 1
2 3
yEL.
N/S
0.865
0.865
0.865
O.A6S
0.865.
0.865
0.865
U.865
0.865
U.C6S
O.U65
(..065
U.865
0.865
0.665
0.865
0.865
O.E65
0.665
0.865
0.665
O.E65
0.865
U.B6S
U.66S
u.665
b.865
0.665
O.P65
C.B65
U.B65
0.065
0.8d5
O.U6S
0.865
0.865
0.865
G.86S
                                                                       A  K  0   VELOCITY
HANNEL 3 4
FLOW VEL.
CU H/S M/S
14 .60 0.911
14 .60 0.9M
1^ .tU 0.941
11 .60 0.941
14 .60 0.911
11 .60 0.941
14 .60 0.941
11 .60 0.941
11 .60 0.941
11 .60 0.941
14 .60 0.911
14 .60 0.941
11 .60 0.941
11 .63 0.941
11 .60 0.941
11 .60 U.941
m .bO 0.941
14 .63 0.941
14 .60 0.941
14 .60 O.V41
14 .60 0.941
14 .60 0.941
14 .60 0.941
14 .60 0.941
14 .60 0.941
14 .60 0.941
14 .60 0.941
14 .63 0.941
14 .60 0.941
14 .60 0.941
14 .60 0.941
14 .60 0.941
14 .60 0.941
141.63 0.941
141.60 0.941
141.60 0.941
141.60 0.941
141. bU 0.941
CHANNEL 1
FLOU \
CU M/S
141 .60
111 .60
141.60
141 .63
141 .60
111 .60
141.60
141.60
141.60
141.60
141.60
141 .60
141.60
141 .60
141 .60
141 .60
141.60
141 .60
141.60
141.63
141.60
141.60
111 .60
141.60
141.60
141.60
141.60
141.60
141.60
I'll. 60
141.60
111 .60
141 .60
141.60
141.60
141.60
141.60
141.60
5
'EL.
H/S
.258
.258
.258
.?58
.258
.258
.258
.258
.258
.25B
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.256
.258
.258
.258
.258
.258
                                                                                        CHANNEL  4   S
                                                                                            FLOU  VEL.
                                                                                           CU  H/S  H/S
                                              CHANNEL  4   S
                                                 FLOU  VEL.
                                                CU H/S  H/S

-------
 7.60
 7.8U
 8.00
 6.2"
 8.40
 8.60
 8.80
 9.JU
 9.20
 V.lO
 9.60
 9.80
10.00
10.20
10.10
10.bO
10.00
 1.1)0
 1.20
 l.lO
 1.60
 1.80
12. 30
12.20
12.10
12.60
12.ao
13.00
13.20
13.10
13.60
13.80
J 1.00
14.20
11.10
14.bO
11.bO
IS.JO
IS.20
IS.10
IS.60
IS.80
16.00
16.20
16.10
16.60
ib.ao
17.00
17.20
17.10
17.60
17.80
Ifl.OO
ia.20
TABLE A-3
(Cont'd)
1*1.60
HJ.hO
HI. 1.0
HI . oO
Hl.t.0
Hl.fiO
HI. 60
HI. 60
HI. 60
HI. 1.0
HI. 60
Hl.bO
HI .60
Hl.oO
I'll. 60
141.60
HI. 60
Hl.oO
I'M. 60
111.60
m.6o
HI. 60
111.60
1H. 60
111.60
lil.oO
111.60
HI. 60
HI. 60
H1.39
111.5'
HI. 59
111.5V
H1.S9
Hi.i>0
HI. 61
111.61
111.60
Hl.(.0
INI .60
111.60
Hl.f.O
Hi .60
HI. 60
HI. 60
HI. 60
HI. 60
Hi. 60
HI. 60
HI. 60
HI. 60
HI. 60
HI. 60
HI. 60
U.HA2
O.BB2
U.H82
.).ft6;r
O.M02
0.0&2
U.8S2
•J.8B2
O.HB2
O.H62
o.«82
0.882
0.882
3.802
0.682
0.082
o.Bfl2
J.9U2
0.862
J.Sb2
0.862
i).B82
0.482
0.882
0.882
0.882
0.682
0.8«2
0.882
0.801
0.881
,1.061
0.08|
n.eei
0.881
0.361
0.081
J.381
0.88 |
n.aei
0.382
9.082
0.382
O.a«2
O.A62
0.882
0.86?
0.88;
0.882
3.082
0.862
0.832
0.882
0.862
US. 90
MS. 10
135.90
U5.VO
US. 90
us. to
Mb. 91)
MS. 90
135.90
1 JS . 90
1 IS. 90
MS. S3
MS. 90
US. til
US. til
MS. 90
US. 90
US. 90
135.90
US. V.I
US. 90
us.vu
US.9J
1J5.SO
us.vo
U5.9'J
US.VO
US. 90
US. 91
US. 92
US. 93
135.95
US.V6
US. 97
US. 97
US. 97
US. 95
US.9S
135. SI
U5.V3
US.V2
US. 91
135.91
135.91
135.90
US. 9(1
135.90
US.VO
135.90
135 .90
US. 90
US. 9Q
US. 90
US. 90
0.665
U«8*>S
0.16S
0.865
C.865
0.865
U.06S
0.865
0.665
0.865
O.B6S
0.065
0.865
C.665
O.B6S
0.865
0.365
C.66S
0.86S
U.B65
U.865
0.865
U.865
U.86S
0.665
U.D65
0.865
U.66S
U.floS
0.665
0.66S
0.665
O.B65
O.H65
C.B6S
0.665
0.065
0.065
0.065
0.66S
Ci.865
C.865
0.86S
O.B6S
0.865
U.865
0.865
O.f 65
0.865
0.665
U.B6S
U.66S
0.665
C.865
11
11
11
11
11
11
11
11
H
11
11
H
11
11
11
11
11
11
11
H
H
It
11
11
H
11
11
11
H
H
H
H
11
11
H
H
H
11
11
H
H
H
H
11
11
H
H
H
H
H
11
H
11
H
.60
.bO
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.6U
.60
.60
.60
.60
.61
.62
.66
.71
.75
.79
.62
.61
.79
.76
.73
.69
.67
.65
.63
.62
.62
.61
.61
.61
.61
.60
.60
.60
.60
.60
.60
0.911
G.911
0.9M1
0.911
0.911
0.911
0. VII
0. VII
O.V1I
0.911
0.911
0.911
0.911
0.911
0.91 1
0.911
0. 911
0.911
0.911
0.911
0.911
0.911
0.911
0.911
0.911
0.911
0.91 1
0.911
0.911
0. V12
0.912
0.912
0.912
0.912
0.912
0.9M2
0.912
0.912
0.912
0.912
0.912
0.911
0.941
0.911
0.911
0.911
0.911
0.911
0.911
0.911
0.911
0.911
0.911
0.911
111.60 .258
H1.60
111.60
111.60
111.60
141 .60
111.60
111.60
111 .60
HI .60
1 11 .60
111 .60
HI .60
HI .60
111.60
HI .60
111.60
HI .60
111.60
HI .60
111 .60
111.60
111 .60
111.60
111.60
111 .60
111 .60
HI .60
111.62
111.65
1 11 .69
111.73
mi. 78
111 .81
111.81
1 1 1 . a o
111 .78
111.71
11 .70
11 .68
11.66
11.61
11 .63
. 41.62
11.61
11.61
11.61
111.60
111 .60
111 .60
111.60
HI .60
111.60
111.60
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.256
.258
.258
.250
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.259
.259
.259
.259
.259
.259
.259
.258
.258
.258
.256
.258
.258
.258
.256
.258
.253
.258
.258
.256
.258
.258
.256

-------
                                                           TABLE  A-3
                                                           (Cont'd)
00
                         18.40
                         18.60
                         lb.au
                         1-J..IO
IV.bU
I9.au
2J.OU
10. 20
2U.4U
20. bO
20. 80
21.30
21.20
21.40
21.60
21. ac
22. OU
22.20
22.40
22.60
22.80
21. JO
23.20
23.40
23.60
23. »0
24.00
141.60
141. hO
1*1. bO
|4|.bO
1*1.60
1*1. (.0
1*1 .bU
|4|.M)
|41.hO
1*1. hO
141.60
111. fcO
iM.dO
1*1.60
1 11.60
I'M. 60
1H 1.60
141. GO
1*1. bo
l*l.bll
1*1. bO
1*1.00
111. CO
111.60
1*1. bO
141.60
1*1.60
101.60
141.60
O.BB2
o.a*2
O.Uo?
U.HH2
O.IIU2
0.4(2
U..J8?
o.*«2
0.6*2
0.3H2
O.BB*
U.8B2
Q.I1R2
U.OB?
U.H62
0.8B2
O.b62
U.OB2
n.flB?
II.HU2
0.882
U.0b2
0.882
0.882
0.8B2
U.8B2
0.882
0.882
0.882
1 IS.VO
liS.«U
1 J'j.90
lli.VD
M'j.Vl)
llb.VU
Mb.VU
Mb.MU
M'j.VO
U'j.MO
US. SO
Ub.vn
lib. fO
M5.SIO
1J&.VO
13S.«0
13&.90
1JS.VJ
IIS .90
1 J5. 50
13S.90
US.fU
)35.«J
13S.«0
135.90
13S.90
US. 90
135.90
135.90
U.flfcS
0.861
o.6t:
(J.B6S
li.8hL
U.P6h
U.86S
(J.A6S
U.«b<
U.B6S
U.86S
U.8(.b
U.flbS
U.8f.S
L.865
U.f 6S
U.865.
0.86$
0.865
0.865
0.665
0.665
O.P6S
0.865
0.865
0.865
0.865
0.86S
0.865
14 .60
14 .60 '
14 .bU
14 .60
14 .60
14 .60
14 .60
14 .60
14 .60
14 .60
14 .60
14 .60
14 .611
14 .60
14 .60
14 .60
14 .bO
14 .60
14 .60
14 .60
141.60
141.60
141.bO
141.60
141.60
141.60
141.60
141.60
141.60
0.941
0.941
0.941
0.9'll
0.941
0.9<4l
0.941
U.94I
0.941
U.941
o.9m
0.9'll
0.941
0.941
0.941
0.941
U.941
U.941
0.941
0.9<;1
0.941
0.941
0.941
O.V41
0.941
0.941
0.941
0.941
0.941
141.60
141.60
14] .60
141 .60
141 .60
141.60
141. bO
141.60
141.60
141.60
141. tO
14] .60
141.60
141 .60
141.60
141.60
141. 60
14] .60
141 .60
141.60
141. bO
141.60
141.60
141 .60
141.60
141.60
141.60
141.60
141.60
.?S8
.258
.2S8
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258
.258

-------
                                                         TABLE  A-4

                                       TRC RECEIV  II QUALITY SELECTED MODEL  RESULTS
                                          COAL-FIRED UTILITY STATION EXAMPLE CASE
                 HUN 1
         ALL LOADINGS TREATED AS FINITE SOURCCS
         BASIN CONTAINS 3 SUbCATCHHCNTS .4 PIPES,AND 2 INLETS         TOTAL AREA=16  ACRES

         JUNCTION CONCENTRATIONS. DURING TIHC CYCLE   2 .QUALITY CYCLE  70. UNITS ARE  MG/L,  EXCEPT  I0**6 HPN/L COLIFORHS*



I         JUNCTION  SULFATCS  TOTAL ft  MANGANES  ALUHINUH  TDS       TSS
OS                                      E
I              1      10.COO     D.3UO     0.030     1.000    SO.000    10.000
              2      10.003     0.471     0-03*     1.0M2    50.058    11.638
              3       9.V99     t.566     0.037     1.365    So.060    12.819
              •       9.999     0.528     0.036     1.0SC    Sfl-OSI    12.001
              $       9.998     0-1*5     0.03S     l.OtS    So.035    11.393
              6       9.000     C.200     0.020     0.900    HS.QOO     9.0flO

-------
                                                         TABLE  A-4
                                                           (Cont'd)
         EXAMPLE RUN I
         ALL LOADINGS TREATED AS HHHt SOURCES
                   AVERAGE JUMC110N CONCENTRATIONS DURING TIDAL OR MHE CYCLE    2. CONSTITUENT NUMBER   1     SULFATES

                          123KS6789IO
            JUNCTIONS.

         BASIN CONTAINS 3 SUBC* TCHHCNTS ,"» PIPES.AND 2 INLETS         TOT»L AREA=<(6 ACRES
I          1  TO   6 O.lQOOE aZO.IOOOE 020.1000E 020.1000E 020.IOOOE 020.9000C 01
^4
°                                                          HAXIHUHS
           JUNCTION
           1  TO   6 O.I030E J20.I01DE 02U.1000E 020.10QOE 020.100DE 020.9000E 01

                                                           MINI HUMS
           JUNCTION
           1  TO   * 0.1000C 020.10QOE 020.9«9IE 010.7998E 01Q.999SE Q10.9000E 01

-------
                                                       TABLE A-4
                                                         (Cont'd)
        EIAHPLE RUN I
        ALL LOADINGS TREATED AS MNITE SOURCES
                  AVERAGE JUNCTION CONCENTRAI10NS  DURING  TIDAL  OR  TIME  CVCLE     2.  CONSTITUENT  NUMBER    2      TOTAL  Ft

                         123*56769         10
           JUNCTIONS.

,        BASIN CONTAINS  3 SU6CATCHHENTS•* PIPES,AND 2  INLETS          TOTAL  AflEA=46  AtRES
-J          1  TO   6 O.jQOQt J00.31D7C  OOa.SlTBE  OOO.JUbE OCO.JJ7BC  000.2000E  00
I
                                                           HAXIHUHS
           JUNCTION
           1  TO   6 0.30DOE OOO.H7b|E  003.60JME  OOO.bl29E OUO.blBBE  000.20QQE  00

                                                           MJNIMUHS
           JUNCTION
           1  TO   4 O.JOOOE OOQ.IOOOE  QOa.SOOOE  000.3000E 000.2S1SE  OOQ.200QE  00

-------
                                                         TABLE  A-4
                                                          (Cont'd)
          EXAMPLE
          •LI IOM)IN6$ .1REATED AS FiNiTE SOURCCS
                    AVCRA6E JUNCTION CONCENTRATIONS DURING TIDAL OR TIME CYCLE    2. CONSTITUENT NUMBER   6     TSS

                           1234S678910
             JUNCTIONS.

          BASIN CONTAINS 3 SUBCA TCMMf NTS t* PIPES,AND 2 INLETS         TOTAL AREA=«6 ACRES
            1  TO   b O.lQOoE 020.1010E 020.1023E 020.1023C 02Q.1023C 020.9000C 01
I                                                            HAXIHUHS
^           JUNCTION
I            1  TO   6 O.lOnOE 020.121SE 020.H7TE 020.1SQ7E 020.1602E 020.9000E 01
            JUNCTION
            1  10   * 0.1000E 020.1000E 020.1000E 020.1000E 020.99B9E 010.9000E 01

-------
         E*AMPLE RUN I
         ALL LOADINGS TREATED AS UNITf  SOURCCS
                   AVERAGE JUNCTION  CONCENTRATIONS DURING TIDAL OR TIME CYCLE    2, CONSTITUENT NUMBER    3      MANGANESE

                          1231S678910
            JUNCTIONS.
BASIN CONTAINS 3 SUBCATCHMENTS tt PlPtS.ANO  2 INLETS         TOTAL AREA=tt ACRES
                                                   010.JO'»Si

                                                   HAXIHUHS
I           1  TO   6 0. JoOIE-010.J028f-010. JOMSC-010.JUHSE-010.JO'»Si:-Ll»U.2000t:-Ol
           JUNCTION
           I   TO   6 0.3001t-al0.3'mOE-ai0.375SE-U10.J779E-010.37Vi»E-010.2000E-01

                                                            MINIMUM*
           JUNCTION
           I   10   4 0.300lE-UlO.JQOJE-OI0.3001E-010.i301E-Oi0.2»50E-OI0.2000E-01

-------
                                                        TABLE A-4
                                                          (Cont'd)
         EXAMPLE MUN I
         ALL LOADING* TREATED AS TINHC SOURCES
                   AVERAGE JUNCTION CONCENTRATIONS DURING TIDAL OR TIME CYCLE    2. CONSTITUENT NUMBER   %     ALUH1NUH

                          123*»S67B91Q
            JUNCTIONS.

         BASIN CONTAINS 5 SUbCATCHHENTS«4 PIPES.AND 2 INLETS         TOTAL AREA=M6 ACRES
           1  TO   6 O.ioUoL J1U.1003E 013.10QHE U10.10Q
-------
                                                         TABLE  A-4
                                                          (Cont'd)
            EXAMPLE RUN 1
            ALL LOADINGS TREATED AS FINITE SOURCES
                      AVERAGE JUNCTION CONCENTRATIONS DURING TIDAL OR TINE CYCLE    2, CONSTITUENT NUMBER   5     TDS

                             123456789        10
               JUNCTIONS.

            BASIN CONTAINS 3 SUBCATCHHENTS,4 PIPEStAND 2 INLETS         TOTAL AHEA=46 ACRES
I              1  TO   & O.SnOot 020.5000E 020.SOOOE 020.50UOE 0?0.5000E 020.4SOOE 02
•»j
I                                                              HAXIHUHS
              JUNCTION
              1  TO   6 O.SCOOE 020.SOQ6E 020.SC07E 020.S007E 020.S007E 020.HSOOE 02

                                                              MJNIMUMS
              JUNCTION
              1  10   6 Q.SUOOE U20.500UE UZ0.50UOE 020.SOOOE 020.499BE 020.H500C 02

-------
                                TECHNICAL REPORT DATA
                         (Please read Instructions on the reverse before completing)
 1 REPORT NO.
  EPA-600/7-79-049
                           2.
                                                      3. RECIPIENT'S ACCESSION NO.
 4. TITLE AND SUBTITLE
Technical Manual for the Measurement and Modeling
of Non-point Sources at an Industrial Site on a River
                                6. REPORT DATE
                                  February 1979
                                6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
G.T.Brookman, J.J. Binder, P. B.Katz, and
W.A.Wade,  m              	
                                                      8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
TRC - The Research Corporation of New England
125 Silas Dean Highway
Wethersfield, Connecticut  06109
                                10. PROGRAM ELEMENT NO.
                                EHE624
                                11. CONTRACT/GRANT NO.

                                68-02-2133, Task 2
 12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC  27711
                                13. TYPE OF REPORT AND PERIOD COVERED
                                Final;  1/77 - 5/78	
                                14. SPONSORING AGENCY CODE
                                  EPA/600/13
is SUPPLEMENTARY NOTEST£RL-RTP project officer is D.  Bruce Harris, MD-62, 919/541-
2557.
16 ABSTRACT rpne manuai provides 2i guide for the implementation of a measurement and
modeling program for non-point sources at an industrial site on a river. Criteria
for developing a field survey program and model selection are provided, along with
program costs and manpower requirements. A sample list of equipment and compu-
ter costs is also provided. The development of a field survey includes sample site
selection, selection of parameters to be measured, number and frequency of sam-
ples, collection methods , analytical methods, and data reduction and analysis.
Included in the modeling section is a description of the SSWMM-RECETV-TI model
which has been adapted to a coal-fired utility site. Application of the outlined pro-
cedures  to the measurement of non-point sources from a coal-fired  utility is also
presented.
 7.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                          b.IDENTIFIERS/OPEN ENDED TERMS
                                            c.  COSATI Field/Group
Pollution
Utilities
Measurement
Mathematical Models
Runoff
Stream Pollution
Leaching
Dust
Pollution Control
Stationary Sources
Non-Point Sources
13 B

14B
12A
08H
07D,07A
    11G
 8. DISTRIBUTION STATEMENT
 Unlimited
                                          19. SECURITY CLASS (This Report)
                                          Unclassified
                                             21. NO. OF PAGES

                                                81
                    20. SECURITY CLASS (Thispage)
                    Unclassified
                                                                  22. PRICE
EPA Form 2220-1 (••?»)
                                           -76-

-------