APTD-70 NATIONAL INVENTORY OF SOURCES AND EMISSIONS: ASBESTOS - 1968 U.S. ENVIRONMENTAL PROTECTION AGENCY Office of Air and Water Programs Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 ------- APTD-70 NATIONAL INVENTORY OF SOURCES AND EMISSIONS: ASBESTOS - 1968 by W. E. Davis § Associates 9726 Sagamore Road Leawood, Kansas Contract No. CPA-22-69-131 EPA Project Officer: C. V. Spangler Prepared for ENVIRONMENTAL PROTECTION AGENCY Office of Air and Water Programs Office of Air Quality Planning and Standards Research Triangle Park, N.C. 27711 February 1970 ------- The APTD (Air Pollution Technical Data) series of reports is issued by the Office of Air Quality Planning and Standards, Office of Air and Water Programs, Environmental Protection Agency, to report technical data of interest to a limited number of readers. Copies of APTD reports are available free of charge to Federal employees, current contractors and grantees, and non-profit organizations as supplies permit from the Air Pollution Technical Information Center, Environmental Protection Agency, Research Triangle Park, North Carolina 27711 or may be obtained, for a nominal cost, from the National Technical Information Service, 5285 Port Royal Road, Springfield, Virginia 22151. This report was furnished to the Environmental Protection Agency in fulfillment of Contract No. CPA-22-69-131. The contents of this report are reproduced herein as received from the contractor. The opinions, findings and conclusions expressed are those of the author and not necessarily those of the Environmental Protection Agency. The report contains some information such as estimates of emission factors and emission inventories which by no means are representative of a high degree of accuracy. References to this report should acknowledge the fact that these values are estimates only. Publication No. APTD-70 11 ------- PREFACE This report was prepared by W. E. Davis & Associates pursuant to Contract No. CPA 22-69-131 with the U. S. Public Health Service, U. S. Department of Health, Education, and Welfare, National Air Pollution Control Administration. The inventory of atmospheric emissions has been prepared to pro- vide reliable information regarding the nature, magnitude, and extent of the emissions of asbestos in the United States for the year 1968. Background information concerning the basic characteristics of the asbestos industry has been assembled and included. Process descriptions are given, but they are brief, and are limited to the areas that are closely related to existing or potential atmospheric losses of the pollutant. Due to the limitation of time and funds allotted for the study, the plan was to personally contact about twenty percent of the companies in each major emissions source group to obtain the required infor- mation. It was known that published data concerning emissions of the pollutant was virtually non-existent. 111 ------- The asbestos emissions and emissions factors that are presented are based on information obtained from production companies that represent about fifty percent of the domestic production, and from reprocessing companies that handled about five percent of the asbestos consumed in 1968. Two of the largest reprocessing companies refused to furnish the information requested concerning their facilities. At the beginning of this study, Johns-Manville indicated that they were willing to co- operate, but after several months and two special trips to their home office, no useful information was given. The GAP Corporation also indicated they would provide certain data but have delayed and have refused to grant permission to visit their mining facility in Vermont. This response was typical of several in the asbestos industry, and accounts for the lack of data from reprocessing companies. Many stated that they knew of no way to test for asbestos emissions and therefore could provide no information. The magnitude of the asbestos emissions from production facilities is subject to many variables, including atmospheric conditions, and is very difficult to estimate accurately. The emissions during mining, blasting, loading, hauling, and unloading are virtually uncontrolled, and visual inspection indicates that emissions are substantial. IV ------- ACKNOWLEDGEMENTS This was an industry oriented study and the authors express their appreciation to the many companies and individuals in the asbestos industry for their contributions. We wish to express our gratitude for the assistance of the various societies and associations, and to many branches of the Federal and State Governments. Our express thanks to Mr. C. V. Spangler, Project Officer, National Air Pollution Control Administration, for his helpful guidance. ------- CONTENTS SUMMARY 1 SOURCES OF ASBESTOS 2 MATERIAL FLOW Material Flow Chart 4 Mining and Processing 5 Asbestos Imports & Exports 6 Reprocessing 7 Friction Materials 7 Asbestos Cement Products 8 Floor Tile 8 Textiles 9 Asbestos Paper 9 Miscellaneous 10 EMISSIONS Map of Emission Regions 11 Asbestos Emissions 12 Asbestos Emissions Factors 13 Particle Size of Emissions 14 Mining and Other Basic Processing 15 Reprocessing 19 Friction Materials 19 Asbestos Cement Products 21 Textiles 23 Asbestos Paper 25 Miscellaneous 27 Consumptive Uses 28 Road Surfacing 28 Construction 29 Brake Linings 29 Steel Fireproof ing 30 Motor Vehicle Use 31 Insulating Cement 31 VII ------- CONTENTS EMISSIONS Incineration and Other Disposal 33 APPENDIX A Asbestos Mines in the United States 34 Reprocessing Plants Producing Asbestos Friction Material 35 Reprocessing Plants Producing Asbestos Cement Products 37 Reprocessing Plants Using Asbestos in Floor Tile 40 Other Asbestos Reprocessing Plants 42 Vlll ------- -1- SUMMARY The flow of asbestos in the United States has been traced and charted for the year 1968. The apparent consumption for the year was 817,363 tons and the domestic production was only 120,690 tons. Imports, mostly from Canada, totaled 737,909 short tons. There was no recovery from scrap. Emissions to the atmosphere during the year were 6,579 tons. About 85 percent of the emissions were due to mining and mill- ing operations. Estimates of emissions are based for the great- est part on observations made during field trips,.and on the limited information provided by mining, milling, and reprocess- ing companies. Information was not available regarding the magnitude of the emissions or the particulate size. There were no emission records at any of the locations visited. ------- -2- SOURCES OF ASBESTOS Asbestos is the name applied to a group of naturally fibrous minerals that are found in irregular veins scattered throughout rock masses in various parts of the world. Only a few of the deposits are of commercial importance. There are several varieties of asbestos, differing considerably in composition and physical properties. The most important commer- cially is chrysotile, and its wide use is due to the fact that its fibers are strong and flexible. Other species of asbestos fall in the amphibole group, and the only ones used to any extent are anthopytllite, trem- olite, amosite, and crocidolite. In the United States asbestos has been found in the States of Alaska, Arizona, California, Georgia, Idaho, Maryland, Montana, North Carolina, Oregon, Vermont, Virginia, Washington, and Wyoming, but production has been negligible except in California, Vermont, Arizona, and North Carolina. Most of the asbestos mined in the world is produced by companies that also fabricate finished asbestos products. They are strong, well organized concerns that maintain a tight control throughout all phases of the business, including mining, processing, manufacturing, and ------- -3- marketing of asbestos and asbestos products. As an example, the largest producer in the world, operates asbestos mines in Canada and the United States, and manufactures asbestos products in more than forty five domestic and eight overseas plants. The products include all the important large volume items that contain asbestos. ------- MATERIAL FLOW ASBESTOS MATERIAL FLOW CHART - 1968 (Short Tons) 175000 (ASBESTOS CONTENT)' FROM MINING 5610 EMISSIONS 48700 TO TAILINGS ASBESTOS PRODUCTION DOMESTIC 120690 737909 IMPORTS 41236 EXPORTS SCRAP 817363 1 04000. 410000 200000 18000. 30000 55363 FRICTION MATERIALS ASBESTOS CEMENT PRODUCTS FLOOR TILE TEXTILES ASBESTOS PAPER MISCELLANEOUS CONSUMER .- J Figure V ------- -5- MINING AND PROCESSING There are eight asbestos mining companies in the United States that produce chrysotile fiber. Four of these mines are located in California, three in Arizona, and one in Vermont. In Arizona the mining operations are all in the Salt River Valley north of Globe, and the mills are either at the mines or in Globe. The California asbestos mines and mills are in the counties of San Benito, Fresno, and Calaveras. The largest mine and mill in the United States is in Vermont near the Canadian border. One company operating in Yancey county, North Carolina, pro- duces a small amount of amphibole asbestos fiber. Asbestos production in the United States during 1968 is reported as 120,690 short tons^_/ Mining companies are listed in Appendix A. Asbestos Production in the United States 1968 STATE SHORT TONS Arizona 1,390 California 75,592 North Carolina and Vermont 43,708 1- Bureau of Mines Minerals Yearbook - 1968 ------- -6- ASBESTOS IMPORTS During 1968, asbestos imports were 737,909 short tons. Approx- imately 94 percent of the import total was from Canada and 5 percent was from the Republic of South Africa._/ ASBESTOS EXPORTS 2 Asbestos exports, during 1968, were 41,236 short tons._/ 1-2- Bureau of Mines Minerals Yearbook - 1968 ------- -7- REPROCESSING The apparent consumption of asbestos in the United States, during 1968, has been reported at 817,363 short tons._/ FRICTION MATERIALS Asbestos is regarded as indispensable in most types of friction materials. It is used as the primary constituent in brake linings and clutch facings for motor vehicles, and other commercial and industrial equipment. Brake linings are of two principal types. In the early days of the automobile, virtually all brakebands were of woven asbestos fabrics but now the molded type is used extensively. Molded linings con- sist of asbestos fibers bonded with an organic matrix. Metallic reinforcing is commonly added, and the shaped products are thoroughly cured. Chrysotile asbestos is required, ranging in fiber length from the very short grades to those just under spinning grades. In the United States the use of asbestos in friction materials during 2 1968 was about 104,000 short tons.__/ Reprocessing plants producing friction materials are listed in Appendix A. 1- Bureau of Mines Minerals Yearbook - 1968 2- Estimate based on reports from reprocessing companies and data from the 1967 Census of Manufacturers. ------- -8- ASBESTOS CEMENT PRODUCTS Asbestos building materials, such as roofing shingles, siding, flat sheets, corrugated sheets, and wallboard consist of portland cement and approximately 15 percent shingle grade asbestos. The mix for asbestos cement pipe may contain as much as 20 percent. In the United States the use of asbestos in asbestos cement products, during 1968, is estimated at 410,000 short tons^_/ Reprocessing com- panies producing asbestos cement products are listed in Appendix A. FLOOR TILE Asbestos is used extensively in asphalt floor tile, and in vinyl asbestos floor tile as a filler and binder. The total amount of asbestos used for this purpose has not changed much during the past few years, but less is used now in asphalt products and more in the vinyl asbestos flooring. The use of asbestos in floor tile during 1968, is estimated at 2 200,000 short tons._/ Reprocessing companies using asbestos in floor tile are listed in Appendix A. 1- Estimate based on data from 1967 Census of Manufacturers and Bureau of Mines Minerals Yearbook - 1968. 2- Bureau of Mines Minerals Yearbook - 1968. ------- -9- TEXTILES Long fiber or spinning grade asbestos is required for textiles and the process involved in manufacturing asbestos fabrics is much the same as that employed in spinning or weaving cotton and wool. In fact, a small amount of cotton or some other organic fiber is normally used along with the asbestos. The asbestos content usually ranges from 75 to 99 percent. Yarns are made in various sizes and used for many purposes. Yam used for brake linings is usually reinforced with fine copper, brass or lead wire and woven into strips. Yarn for electrical insulating tape should contain not more than 7 percent carbon, and not more than 14 percent cotton. Yarn for cloth varies depending on the end use of the material. Asbestos cloth is used for safety clothes, gloves, gaskets, insulating blankets, and numerous other purposes. In the United States, asbestos used in textiles during 1968 totaled about 18,000 short tons. ASBESTOS PAPER Asbestos paper is used for many purposes such as; roofing felt, a paper or tape for covering hot ductwork, in the manufacture of air- cell pipe covering. Millboard is used in the manufacture of mill- ------- -10- board gaskets. It is estimated that the quantity of asbestos used in paper in the United States during 1968 totaled 30,000 short tons. MISCELLANEOUS In addition to the above mentioned uses, asbestos is used in filters, insulating materials, auto undercoating, roofing compound, boiler cement, plastics, rubber, wall joint tape, wall joint cement, gas mask filters, welding rod coating, fire proof ing materials, com- pounded packings, fire walls, oil well drilling mud, etc. About 15,000 to 17,000 tons of asbestos is used each year in in- sulation materials that are for insulating pipes, ducts, boilers, and other hot equipment. The asbestos content of the insulation is about 15 percent. About 3,000 tons of asbestos is used each year in material that is sprayed-on steel columns and other structures for fire protection. The miscellaneous uses of asbestos, during 1968, are estimated at 55,363 short tons. ------- EMISSIONS MAP OF EMISSION REGIONS •J- Asbestos Mines • Asbestos Reprocessing Figure VI ------- -12- ASBESTOS EMISSIONS 1968 SOURCE CATEGORY SOURCE GROUP SHORT TONS MINING AND OTHER BASIC PROCESSING REPROCESSING CONSUMPTIVE USES INCINERATION OR OTHER DISPOSAL Mining and Milling Friction Materials 312 Asbestos Cement Products 205 Textiles 18 Paper 15 Floor Tile 100 Miscellaneous 28 Construction 61 Brake Linings 190 Steel Fireproof ing 15 Insulating Cement 25 5,610 678 291 NA TOTAL 6,579 NA - Data not available, Region No. 1 Region No. 2 Region No. 3 Region No. 4 EMISSIONS BY REGION PLANTS SHORT TONS 3570 20 2020 Regional distribution includes the source groups - Mining and Milling (representing 85 percent of total emissions) Undistributed 15 percent 969 ------- -13- ASBESTOS EMISSIONS FACTORS MINING AND OTHER PROCESSING REPROCESSING Friction Materials Asbestos Cement Products Textiles Paper Floor Tile CONSUMPTIVE USES Brake Linings Steel Fireproofing Insulating Cement C 93 Ib/ton of asbestos produced C 6 Ib/ton of asbestos processed C 1 Ib/ton of asbestos processed C 2 Ib/ton of asbestos processed C 1 Ib/ton of asbestos processed C 1 Ib/ton of asbestos processed NC 10 Ib/ton of asbestos processed NC 10 Ib/ton of asbestos applied C 25 Ib/ton of asbestos applied Asbestos emissions factors are based on particulate control indicated as follows: Mining and Other Processing Friction Materials Asbestos Cement Products Textiles Paper Floor Tile Insulating Cement - Eighty percent. - Ninety five percent. - Seventy five percent. - Ninety five percent. - Seventy five percent. - Seventy five percent. - Eighty nine percent. C - Controlled NC - Not Controlled ------- -14- PARTICLE SIZE OF EMISSIONS Field sampling and lab testing were not a part of this study, and throughout this report there are numerous statements to the effect that information concerning the particle size of asbestos emissions is not available from mining processing, and reprocessing companies. All these companies stated they were not aware of any accurate method for testing asbestos emissions. Even though there is a lack of data concerning the particle size of asbestos emissions, there is considerable information available re- garding the dimensions of asbestos fibers. The diameter of chrysotile fiber ranges from about 0.018 to 0.03 microns, and the length varies from a fraction of a micron to 30,000 microns and longer. It is reasonable to assume the size of some asbestos emission particles would be about the same as that of a single fiber, (0.018 to 0.03 micron) and others may consist of a cluster of fibers several microns in diameter and more than a thousand microns in length. The dust observed in some of the mine offices appeared to consist of very fine particles, possibly ranging in size from 1 to 40 microns. The particle size of most emissions from bag filters at reprocessing facilities is probably in the range of 1 to 10 microns. ------- -15- MINING and OTHER BASIC PROCESSING In the United States most of the asbestos mining operations are of the open-pit type and the milling facilities are located reasonably close to the mines. At some locations the rock is easily removed without blasting, but at others, it is necessary to blast in order to i loosen the material. From the standpoint of atmospheric emissions, it is unfortunate that blasting is necessary. At many locations the rock containing the asbestos is moved from the mine to a storage pile near the mill where it remains until it is again moved into the mill for processing. During the loading, un- loading, and moving operations, there are emissions, and the mag- nitude of those emissions depends on the atmospheric conditions. Chrysotile asbestos is a fibrous form of serpentine, and is usually associated with massive fractured serpentine. The concentration process is unusual in that it involves the separation of a fibrous mineral from a massive form of the same mineral. Neither chemical composition, nor specific gravity can be used as a basis for sepa- ration; however, mechanical separation is possible. Due to its fibrous structure, it can be divided into filaments that are amenable ------- -16- to separation by air suction and screening. Since the long fibers of chrysotile asbestos are worth several times as much as the short ones, it is important to accomplish separation of fiber from rock with a minimum of fiber breakage. Asbestos mill- ing consists essentially of course crushing, drying, and recrushing in stages, each step being followed by screening, and air separation of the fiber from rock. In Arizona the mining is underground and the fiber is found in veins that occur in bands from a few inches to a few feet in thickness. The fiber is mined in drifts and stopes, using modified room-and-pillar methods, and mining costs are relatively high. Since mining is under- ground, the atmospheric emissions are considered as negligible. In Vermont, the fiber-bearing rock is removed from an open pit, which is worked on three benches, each 125 feet high. About 50,000 tons of rock is broken with each multiple blast._/ Operations in California are well organized and efforts are made to control emissions, but the very nature of the operation makes emission control difficult. During one field trip, it was observed that trucks transporting rock were covered with tarpaulins; however, the tarpaulins were loose and the dust was blowing. A fine dry dust was noticed at 1- Bowles, Oliver; Asbestos - A Materials Survey; Bureau of Mines Information Circular 7880- 1959. ------- -17- all locations - inside and outside. A fine dust haze was observed at a distance of several miles from some of the mining and milling operations. In general, emission control equipment is used to some extent at all milling facilities. At one location visited, mechanical type collectors were used, and the operator estimated a two percent fiber loss to the atmosphere, based on the total asbestos fiber processed. At the second location, there were four mechanical dust collectors, and one was equipped with a bag filter. At the third location all of the cyclone collectors were equipped with bag filters, but there was a light fog of asbestos inside the mill building. At the fourth mill, there were bag filters, but there was no collector on the dryer. There was a light haze over the plant due to rock unloading. At the fifth mill, bag filters were used except for the cyclone collector on the dryer. At the sixth mill, which was not in operation at the time the field trip was made, there was a baghouse, but dust was everywhere - in the office, and in the conference room. At the seventh mill, no visitors were allowed beyond the office without permission from the home office in New York. Without exception, there was no data regarding emissions. There were no records or tests showing the asbestos content or the asbestos particle size of the emissions. ------- -18- Even though emissions data was not available, an emissions factor of 93 pounds per ton of asbestos produced has been estimated for mining and milling operations. This factor is based on the type of emissions control equipment used and its collection efficiency. ASBESTOS EMISSIONS FACTORS FOR MINING AND MILLING* (pounds per ton of asbestos produced) Emission Uncontrolled Cyclone Bag house Factor Mining X 3 Loading X 2 Hauling X 2 Unloading X 2 Crushing & Drying X 10 Milling XX 64 Tailings X 10 93 * Based on baghouse efficiency @ 99.5% and cyclone efficiency @ 80%. For the year 1968, the asbestos emissions to the atmosphere from sources of mining and milling are estimated at 5,610 short tons, based on an average emissions factor of 93 pounds per ton of asbestos produced. ------- -19- REPROCESSING An outstanding characteristic of the asbestos industry is that a very large proportion of the fiber is mined, imported, processed, and re- processed by a relatively few companies. Very little of the finished product is sold to the consumer trade. The original use of asbestos was based on its heat resistance properties, but the current use is more often as a binder; such as in asbestos cement products. The asbestos fibers are usually sold in 100 pound bags which are paper bags or jute bags which sometimes have a plastic liner. The disposal of these bags seems to present a problem to the industry. A few are able to use the paper bags in the product being produced, but many more are still seeking a satisfactory solution. FRICTION MATERIALS One of the largest uses of the friction material is in brake linings of the molded type. The molded linings, consisting of asbestos fibers bonded with an organic matrix, contain approximately fifty percent asbestos. As a part of the manufacturing process, the linings must be shaped and finished by grinding after they are formed. This ------- -20- creates a substantial loss of asbestos, as much as thirty percent. With such a grinding procedure an adequate exhaust and collection system is essential. A large manufacturer of brake linings reported 4000 tons of asbestos collected in bag filters at one plant during 1968 and described his collection system. He estimated overall atmospheric emissions of asbestos to be 0.25 to 0.50 percent, based on the efficiency of his collection equipment. Other manufacturers provided some information regarding the type of collection equipment in operation, but not data or estimates of asbestos emissions. On the basis of information obtained an emissions factor of 6 pounds per ton of asbestos processed is estimated, and asbestos emissions to the atmosphere during 1968 are 312 short tons. ------- -21- ASBESTOS CEMENT PRODUCTS Asbestos cement products contain 15 to 20 percent asbestos, cement, and minor amounts of other ingredients. In one method of pipe manufacture, a slurry of asbestos, cement, and water is collected on a felt-covered belt and the water is removed by suction. The sheet is then wound on a rotating metal cylinder to form the pipe. After the pipe wall is built to the desired thickness, the pipe is steam cured. Asbestos shingles and siding products, manufactured by the dry process, have a dry mix which is spread evenly on a conveyor belt before water is added. When produced by the wet method, the water is added before the forming is initiated. From the standpoint of air pollution during manufacture of asbestos cement products, the principal emissions occur when unloading the asbestos and while handling it in a dry condition. Data regarding the magnitude and nature of asbestos emissions to the atmosphere was not available at any asbestos cement plant that was visited during this study; therefore, an emissions factor based on visual inspection is estimated as 1 pound per ton of asbestos processed. ------- -22- Asbestos emissions to the atmosphere due to the manufacture of asbestos cement products, during 1968, are estimated at 205 short tons, based on an average emissions factor of one pound per ton of asbestos processed. ------- -23- TEXTILES During the manufacture of most asbestos textiles, a small amount of cotton or some other suitable organic fiber is mixed with the asbestos to help bind the asbestos fibers together during the spin- ning process. After all the fibers are thoroughly mixed, they are combed into a parallel position as they pass a succession of carding rolls. The loose blanket that has emerged from carding is separated into rovings and spun into yarn. The spinning of the yarns and the subsequent weaving of the fabrics accumulates a considerable amount of lint and dust. To control this accumulation and cleanse the air inside the factory, it is the usual practice to exhaust the air from the building through a bag filter, and sometimes return the air from the filter to the factory. In asbestos textile mills, the amount of asbestos collected in bag filters is about 8 to 10 percent of the asbestos processed. The following seems to be typical of asbestos textile manufacturing plants: At one plant where asbestos cloth, rope, tape, etc. is manufactured the air in the building is filtered through bag filters and returned to the factory. During 1968, 8 1/2 percent of the asbestos used was collected in the bag filters. Based on this in- ------- -24- formation, an emissions factor is estimated at 2 pounds per ton of asbestos processed. Asbestos emissions to the atmosphere from textile mills during 1968 are estimated at 18 short tons. ------- -25- ASBESTOS PAPER The methods used to make asbestos paper are similar to those employed in the manufacture of paper from wood pulp. Asbestos of paper-stock grade, sodium silicate, size, and starch are mixed with water to make a thin slurry. The material is conveyed to a paper machine, and as the sheet is formed, it passes between rollers and through driers to remove the water and dry the paper. If a two-ply paper is desired, one side of a sheet is coated with sodium silicate, and the two sheets are run together over several hot rolls. Crimped paper is made by passing the sheets over cor- rugated rolls. During the manufacture of asbestos paper and asbestos paper products, emissions to the atmosphere occur at the beginning of the process when the asbestos fiber is dry, and also again after the paper is formed. The magnitude of the emission? due to dusting depends, to a large extent, on the number of times the paper is handled as the products are manufactured. Since manufacturer's data was not available regarding asbestos emissions during the manufacture of paper, the emissions factor ------- -26- was estimated at one pound per ton of asbestos processed. Asbestos emissions to the atmosphere due to the manufacture of asbestos paper during 1968 are estimated at 15 short tons, based on an emissions factor of one pound per ton of asbestos processed, ------- -27- MISCELLANEOUS A light fluffy form of magnesium carbonate combined with asbestos fiber makes an effective heat insulation for steam pipes. Such products are commonly referred to as "85 percent magnesia", and they are manufactured by mixing magnesium carbonate and asbestos in water, collecting the solids on a filter press and cast- ing the mix in the form of pipe insulation. The manufacture of molded articles for electrical fittings and household appliances is similar to many other manufacturing procedures regarding the manner in which asbestos fiber is handled. Asbestos is mixed with other ingredients, ground, compressed in molds, baked and polished. The asbestos be- comes "locked-in" during the process and thereafter presents a minimum hazard with respect to air pollution. Asbestos emissions to the atmosphere, during 1968, due to the manufacture of miscellaneous products that contain asbestos i are estimated at 28 short tons, based on an emissions factor of 1 pound per ton of asbestos processed. ------- -28- CONSUMPTIVE USES When asbestos material is used, most is applied by the building trades 01 some specialty group. In these cases most of the emissions to the atmosphere occur during the cutting, handling, or spraying of the asbestos products. There are exceptions, one of the outstanding being the replace- ment of motor vehicle brake linings. The abrasion of brake and clutch facings during use may be another source of atmospheric emissions of asbestos. Rock from asbestos mines, used as a road surfacing agent, would also result in an emission to the atmosphere from use. Road Surfacing There have been several reports that tailings from asbestos milling operations are used for surfacing roads. Sometimes the rock is mixed with oil or asphalt, and at other times, it is used as it comes from the mill. At one location visited during a field trip, it was reported that 150,000 tons of mill tailings, containing about 2 tons of asbestos ------- -29- fiber, were sold to a contractor during 1968 for use on roads. It is reported that an appreciable amount is used in Vermont for roads. _/ This could not be confirmed, since permission to visit the mine and mill was denied. Construction Workmen in all trades in the construction industry come in con- tact with asbestos. Heating ducts are often insulated with asbestos, and steam piping is nearly always covered with a material contain- ing asbestos. Electricians strip asbestos insulation from wires, and the carpenter saws asbestos siding, wallboard, and shingles. As a result, there is asbestos released to the air around the con- struction sites. Asbestos emissions to the atmosphere at construction sites are estimated at 61 short tons for 1968. Brake Linings Motor vehicle travel during 1968 totaled one trillion miles, and replacement brake linings were required for about 25 to 30 million vehicles. It is the usual practice, when installing new brake linings, 1- May-Timothy C.; Asbestos; Mineral Facts and Problems; Bureau of Mines Bulletin 630 - 1965 ------- -30- to fit the linings to the drums by grinding, and the amount of grinding required varies depending on the condition of the brake drum. Data concerning motor vehicle brake linings: Vehicle miles during 1968 1,010,000,000,000 Mileage life of brake linings 27,500 Brake lining sets on new vehicles 10,718,000 Pounds of asbestos per set of brake linings 3 Assumed loss to atmosphere during grinding and fitting - percent 0.5 Based on the above, the emissions factor is 10 pounds per ton of asbestos processed, and the asbestos emissions to the atmos- phere during 1968 were 190 tons. Steel Fireproofinq Several spray-on materials that contain asbestos are used ex- tensively on steel columns and other structures as a fire pro- tection measure. The application of such materials is often required by code. Even though the building frame may be covered by a temporary enclosure when the material is sprayed/ the work- men are exposed to an atmosphere that is virtually saturated with asbestos fiber. Asbestos emissions to the atmosphere, due to the use of spray- on fireproofing during 1968, are estimated at 15 short tons, ------- -31- based on an emissions factor of 10 pounds per ton of asbestos applied. Motor Vehicle Use It is obvious that there are substantial particulate emissions from the wear of motor vehicle brake linings and clutch facings. This has been reported as a primary source of asbestos emissions to the atmosphere; however, there are conflicting reports indicating that the asbestos fiber has been destroyed by the heat of friction. In this report the estimate of emissions does not include an amount for the wear of motor vehicle brake linings and clutch facings. Insulating Cement Insulating cement that contains asbestos is used extensively in all types of boilers. It is used for pointing up joints and cracks in stack and breeching linings, and for surfacing block insulation that is installed inside breechings, ducts and economizers. During the boiler operation, as the flue gas passes through the boiler some of the insulating cement is worn away and carried along through the dust collector, up the stack, and into the atmosphere. Based on the following assumptions, an emissions factor of 33 ------- -32- pounds per ton of asbestos applied is calculated for the use of insulating cement. 1 - Fifteen percent of the insulating cement worn away during use, .: - Dust collector efficiency - 89 percent (average) Asbestos emissions to the atmosphere during 1968 due to the use of insulating cement are estimated at 25 short tons. ------- -33- INCINERATION OR OTHER DISPOSAL The recovery of scrap is an important factor in some industries, but asbestos, once used, is rarely recovered for reuse. In most products, asbestos is combined with other materials in such a manner that it is difficult to separate into a usable form. Most of the discarded products that contain asbestos become part of the solid waste. The greatest percentage of the asbestos is used in building materials; therefore, the debris from the demolition of buildings, and from new construction, contains most of the asbestos scrap. In the process of destroying a building, some of the asbestos fibers would be released; and if the asbestos fiber is not destroyed by burning, there would be some asbestos released by incineration. ------- -34- APPENDIX A ASBESTOS MINES IN THE UNITED STATES ARIZONA Asbestos Manufacturing Company Jaquays Mining Corporation Metate Asbestos Corporation LOCATION Gila County Gila County Gila County CALIFORNIA Atlas Minerals Corporation Coalinga Asbestos Company (1) Pacific Asbestos Corporation (2) Union Carbide Corporation Fresno County Fresno County Calaveras County San Benito County NORTH CAROLINA Powhatan Mining Company Yancey County VERMONT GAF Corporation Orleans County (1) - Owned by Johns-Manville Corporation (2) - Acquired by H. K. Porter Company, Inc. during 1968. ------- -35- REPROCESSING PLANTS PRODUCING ASBESTOS FRICTION MATERIALS CALIFORNIA H. Krasne Manufacturing Company Silver Line Brake Lining Corporation Lasco Brake Products Corporation, Ltd. LOCATION Los Angeles Los Angeles Oakland CONNECTICUT H. K. Porter Company, Inc. Raybestos-Manhattan, Inc. Middletown Stratford ILLINOIS Gatke Corporation Grizzly Brake Division of Mar Pro Inc. The L. S. Miley Company Johns-Manville Corporation Chicago Chicago Chicago Waukegan INDIANA Raybestos-Manhattan, Inc. H. K. Porter Company, Inc. World Bestos Company (sub. of Firestone Tire & Rubber Co.) Crawfordsville Huntington New Castle KENTUCKY H. K. Porter Company, Inc. Richmond MASSACHUSETTS Auto Friction Lawrence MICHIGAN American Brakeblock - Division Ambes Corp. Birmingham American Brake Shoe Company Troy ------- -36- NEW JERSEY Johns-Manville Corporation Reddaway Manufacturing Company, Inc. Raybestos-Manhattan, Inc. H. K. Porter Company, Inc. Manville Newark Passaic Trenton NEW YORK Bendix Corporation Troy NORTH CAROLINA Southern Friction Materials Company Charlotte OHIO American Brake Shoe General Motors Corporation Maremont Corporation Cleveland Dayton Paulding PENNSYLVANIA Raybestos-Manhattan, Inc. H. K. Porter Company, Inc. Manheim Pittsburgh TEXAS Standee Brake Lining Company Houston TENNESSEE Bendix Corporation Cleveland VIRGINIA American Brake Shoe Winchester (Thomas Register, Dec., 1968 Ed., Fortune-1966 Plant & Product Directory of the 1000 Largest U.S. Industrial Corporations; U.S. Department of Commerce.) ------- -37- REPROCESSING PLANTS PRODUCING ASBESTOS CEMENT PRODUCTS ALABAMA U.S. Cast Iron Pipe Company GAP Corporation Cement Asbestos Products Company LOCATION Anniston Mobile Woodward CALIFORNIA Southern Pipe & Casing Company Johns-Manville Corporation Johns-Manville Corporation Certain-Teed Products Corporation Certain-Teed Products Corporation Johns-Manville Corporation Azuza Long Beach Pittsburgh Riverside Santa Clara Stockton CONNECTICUT Tile Roofing Company Stratford GEORGIA Uniroyal, Inc. GAP Corporation Hogansville Port Wentworth ILLINOIS Acme Asbestos Covering & Flooring Company Chicago Asbestos & Magnesia Materials Company Chicago Flintkote Company Chicago Western Slate Company Elmhurst Pel-Pro, Inc. Skokie Johns-Manville Corporation Waukegan INDIANA U. S. Gypsum Company East Chicago ------- -38- LOUISIANA Johns-Manville Corporation National Gypsum Company Marraro New Orleans MASSACHUSETTS Johns-Manville Corporation No. Billerica MICHIGAN American Asbestos Products Company Detroit MINNESOTA Mac Arthur Company St. Paul MISSOURI Certain-Teed Products Corporation GAP Corporation National Gypsum Company St. Louis St. Louis St. Louis NEW HAMPSHIRE Johns-Manville Corporation Nashua NEW JERSEY Johns-Manville Corporation National Gypsum Company Philip Carey Manufacturing Company GAP Corporation U. S. Plywood-Champion Papers, Inc. Manville Millington Perth Amboy So. Bound Brook South River NEW YORK Asbeka Fabricators Corporation National Gypsum Company, Inc. Flintkote Company Brooklyn Buffalo White Plains ------- -39- NORTH CAROLINA H. K. Porter Company, Inc. Johns-Manville Corporation Charlotte Marshville OHIO Philip Carey Manufacturing Company Seagrave Flintkote Company Cincinnati Columbus Ravenna PENNSYLVANIA Certain-Teed Products Corporation Nicolet Industries, Inc. Supradur Manufacturing Company (sub. of Seagrave) Ambler Ambler Windgap TEXAS Johns-Manville Corporation Certain-Teed Products Corporation Philip Carey Manufacturing Company Dennison Hillsboro Houston WISCONSIN Wisconsin Gasket & Manufacturing Company Milwaukee (Thomas Register, Dec.,! 1968 Ed.; Fortune-1966 Plant & Product Directory of the 1000 Largest U. S. Industrial Corporations; U.S. Department of Commerce.) ------- -40- REPROCESSING PLANTS USING ASBESTOS IN FLOOR TILE CALIFORNIA GAF Corporation Armstrong Cork Company Flintkote Company LOCATION Long Beach South Gate Vernon ILLINOIS Flintkote Company GAF Corporation Armstrong Cork Company Johns-Manville Corporation Chicago Joliet Kankakee Waukegan LOUISIANA Johns-Manville Corporation Flintkote Company Marraro New Orleans MASACHUSETTS Flintkote Company Watertown MISSISSIPPI Armstrong Cork Company Jackson NEW JERSEY Congoleum-Nairn, Inc. Johns-Manville Corporation American Builtrote Rubber Company, Inc. Kearny Manville Trenton NEW YORK GAF Corporation Vails Gate ------- -41- OHIO Johns-Manville Corporation Chillicothe PENNSYLVANIA Armstrong Cork Company Lancaster TEXAS GAF Corporation Houston (Thomas Register, Dec. , 1968 Ed.; Fortune-1966 Plant & Product Directory of the 1000 Largest U.S. Industrial Corporations; U.S. Department of Commerce.) ------- -42- OTHER ASBESTOS REPROCESSING PLANTS ALABAMA GAP Corporation LOCATION Mobile CALIFORNIA Hill Brothers Chemical Company Fibreboard Paper Products Corporation Jbhns-Manville Corporation Fibreboard Paper Products Corporation Scott Labs, Inc. Sacomo Manufacturing Company George Short Company City of Industry Emeryville C Pitts burg B C Redwood City B Richmond C San Francisco ABC San Francisco C COLORADO The Verticel Company Englewood CONNECTICUT Brosites Industries, Inc. Standard Washer & Material, Inc. Auburn Manufacturing Company Greenwich Manchester Middletown C C DELAWARE Haveg Industries, Inc. Wilmington GEORGIA Terri-Cord Mills Roberta ILLINOIS Unarco Industries, Inc. Accurate Felt & Gasket Manufacturing Co. Acme Asbestos Covering & Flooring Co. Bloomington Chicago Chicago C C B ------- -43- Asbestos & Magnesia Materials Company Asbestos Textile Company Chambers Gasket & Manufacturing Company Colonial Kolonite Company A. Daigger & Company Filpaco Industries, Inc. Geraghty Gasket & Manufacturing Company L. E. Harnisch & Company John Herman Manufacturing Corporation Industrial Hermetic Materials, Inc. Kopel Filter Paper Company Sail Mountain Company Singer Safety Products, Inc. Grant Wilson, Inc. United Gasket Corporation Industrial Gloves Company GAP Corporation F. D. Farnam Company Luse-Stevenson Company Blackhawk Gasket Corporation Excelsior Leather Washer Mfg. Co. Nicolet Industries, Inc. Johns-Manville Corporation Chicago Chicago Chicago Chicago Chicago Chicago Chicago Chicago Chicago Chicago Chicago Chicago Chicago Chicago Cicero Danville Joliet Lyons Melrose Park Rockford Rockford Union Waukegan A B A C C C C B C A C C C A A B C A B ABC C C C B C LOUISIANA Johns-Manville Corporation New Orleans MARYLAND Congoleum-Nairn, Inc. Cedarhurst MASSACHUSETTS Armstrong Cork Company Pepperell Braiding Company Barwood Manufacturing Corporation Asbestos Textile Company, Inc. Braintree C East Pepperell A Everett C No. Brookfield A MICHIGAN Detroit Gasket & Manufacturing Company Detroit Great Lakes Filter Media Company Detroit Walker Manufacturing Company Jackson B C ------- -44- MISSOURI GAP Corporation Standard Asbestos Mfg. & Insulating Co. General Gasket Corporation Tallman-McCluskey Fabrics Company (sub. of H. K. Porter Co. Inc.) Kansas City Kansas City St. Louis St. Louis B BC C A NEW HAMPSHIRE American Asbestos Textile Corporation Johns-Manville Corporation NEW JERSEY Howard Industries, Inc. Asbesto Corporation Kavon Filter Products Company Janos Asbestos Company GAP Corporation Columbia Filter Company Cellulo Company Imperial Products Company Ladden Asbestos Corp. of New Jersey Smyth Rubbar & Packing Company Smith & Kanzler Corporation Johns-Manville Corporation Flaherty-Kennedy Filter Fabrics Asbestos Products Mfg. Corp. Asbestospray Corporation Johns-Manville Corporation . Electrical Insulation Sales Company Brassbestos Manufacturing Corporation La Favorite Rubber Manufacturing Co. J. T. Baker Chemical Company Minerals & Insulation Company, Inc. Baldwin-Ehret-Hill, Inc. NEW YORK Atlantic Asbestos Corporation Able-Val Canvas & Rope Mfg. Co. Acme Canvas & Rope Company Eureka Packing Company Smith Chemical & Color Company Meredith Tilton Berkley Heights Bloomfield Cranford East Rutherford Gloucester City Hawthorne Hoboken Hoboken Irvington Jersey City Linden Manville Maplewood Newark Newark New Brunswick North Bergen Patterson Patterson Phillips burg Rochelle Park Trenton Bronx Brooklyn Brooklyn Brooklyn Brooklyn A B C A C ABC B C C A B C B C B C C C C C C C C C B C A A A ------- -45- U. S. Indestructible Gasket Company Armstrong Cork Company National Filter Corporation Asbestos Ltd. Atlantic Asbestos Corporation Scientific Filter & Machinery Company Whittaker, Clark & Daniels, Inc. Pam Narrow Fabrics Corporation Garlock, Inc. Gaddis Engineering Company Brooklyn A C Fulton B Mt. Vernon C New York City New York City New York City New York City Oceanside A Palmyra A C Port Washington B C NORTH CAROLINA Carolina Asbestos Company Tar Heel Mica Company Davidson Plumtree OHIO G. P. Hall Company Johns-Manville Corporation The Blemker Company Cincinnati Gasket Packing, & Mfg. Co. Russel Gasket Company Zimmerman Packing Company Asbestos Products Company Bodwell-Lemmon Company Foseco Inc. Russell Gasket Company Nicolet Industries, Inc. The Cellulo Company Asbeka Fabricators Corporation Akron Avery Cincinnati Cincinnati Cincinnati Cincinnati Cleveland Cleveland Cleveland Cleveland Hamilton Sandusky Willoughby B C C C C C C C PENNSYLVANIA Keasbey & Mattison Company Nicolet Industries, Inc. GAF Corporation Debco Products Raybestos-Manhattan, Inc. American Asbestos Textile Corporation Nicolet Industries, Inc. Atlas Asbestos Company Greene Tweed & Company Aljay Manufacturing Company Ambler Ambler Erie Herminie Manheim Norristown Norristown North Wales North Wales Philadelphia AC C AC B AC A A C A ------- -46- Anchor Packing Company Austen Hill Manufacturing Company Burnswick Asbestos Company Collins Packing Company Delaware Asbestos & Rubber Company Manufactured Rubber Products Company Mercer Rubber Company, Inc. Philadelphia Asbestos Corporation George A. Rowley & Company, Inc. Charles A. Wagner Company, Inc. Armstrong Cork Company Pittsburgh Corning Corporation Westinghouse Electric Corporation Refractory and Insulation Corporation Quaker Safety Products & Mfg. Co. Carlisle Corporation Philadelphia Philadelphia Philadelphia Philadelphia Philadelphia Philadelphia Philadelphia Philadelphia Philadelphia Philadelphia Pittsburgh Pittsburgh Pittsburgh Port Kennedy Quakerstown Ridgway A A C C C SOUTH CAROLINA H. K. Porter Company, Inc. Raybestos-Manhattan, Inc. Bennettsville A North Charleston A C TEXAS GAP Corporation Johns-Manville Corporation Philip Carey Manufacturing Company Standee Asbestos Textile Company Dallas Fort Worth Houston Houston B B A A C VIRGINIA Capitol Asbestos Fabricators Corporation Forcee Manufacturing Corporation Alexandria Tappahannock WISCONSIN Ametek/Plymouth Plastics Division Sheboygan CODE - A - Textiles B - Paper C - Miscellaneous (Thomas Register, Dec., 1968 Ed.; Fortune-1966 Plant & Product Directory of the 1000 Largest U.S. Industrial Corporations; U.S. Department of Commerce.) if U. S. COVERNMENT PRINTING OFFICE: 1973 74B77I/41B4 ------- BIBLIOGRAPHIC DATA SHEET 1. Report No. APTD-70 3. Recipient's Accession No. PB 192-252 4. Title and Subtitle National Inventory of Sources and Emissions: Asbestos 1968 5. Report Date February 1970- 6. 7. Author(s) W. E. Davis 8. Performing Organization Rept. No. 9. Performing Organization Name and Address W. E. Davis § Associates 9726 Sagamore Road Leawood, Kansas 10. Project/Task/Work Unit No. 11. Contract/Grant No. CPA-22-69-131 12. Sponsoring Organization Name and Address Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, N.C. 27711 13. Type of Report & Period Covered Final 1968 14. 15. Supplementary Notes 16. Abstracts The inventory of atmospheric emissions has been prepared to provide reliable informatioi regarding the nature, magnitude, and extent of the emissions of asbestos in the United States for the year 1968. Background information concerning the basic characteristics of the asbestos industry has been assembled and included. Process descriptions are given, but they are brief, and are limited to the areas that are closely related to existing or potential atmospheric losses of the pollutant. The asbestos emissions and emissions factors that are presented are based on information obtained from production companies that represent about fifty percent of the domestic production, and from reprocessing companies that handled about five percent of the asbestos consumed in 1968 The magnitude of the asbestos emissions from production facilities is subject to many variables, including atmospheric conditions, and is very difficult to estimate accurately. The emissions during mining, blasting, loading, hauling, and unloading are virtually uncontrolled, and visual inspection indicates that emit; si DTK; 17. Key Words and Document Analysis. 17a. Descriptors Inventory Atmospheric emissions Asbestos Asbestos industry Pollutant Asbestos emissions Asbestos emission factors 17b. Identifiers/Open-Ended Terms 17c. COSATI Field/Group 13B 18. Availability Statement Unlimited 19.. Security Class (This Report) UNC L ASS1FIED^ Uiy 20. Security Class (This P"1jMCLASSIFIED 21. Ko. of Pages 52 22. Price $3.00 FORM NTIS-35 tREV. 3-72) U3COMM-DC 14M3-P72 ------- INSTRUCTIONS FOR COMPLETING FORM NTIS-35 (10-70) (Bibliographic Data Sheet based on COSATI Guidelines to Format Standards for Scientific and Technical Reports Prepared by or for die Federal Government, PB-180 600). 1. Report Number. Each individually bound report shall carry a unique alphanumeric designation selected by the performing organization or provided by the sponsoring organization. Use uppercase letters and Arabic numerals only. Examples FASEB-NS-87 and FAA-RD-68-09. 2. Leave blank. 3- Recipient's Accession Number. Reserved for use by each report recipient. 4. Title and Subtitle. Title should indicate clearly and briefly the subject coverage of the report, and be displayed promi- nently. Set subtitle, if used, in smaller type or otherwise subordinate it to main title. When a report is prepared in more than one volume, repeat the primary title, add volume number and include subtitle for the specific volume. 5- Report Date. Each report shall carry a date indicating at least month and year. Indicate the basis on which it was selected (e.g., date of issue, date of approval, date of preparation. 6- Performing Organization Code. Leave blank. 7. Author(i). Give name(s) in conventional order (e.g., John R. Doe, or J.Robert Doe). List author's affiliation if it differs from the performing organization. 8- Performing Organization Report Number. Insert if performing organization wishes to assign this number. 9. Performing Organization Name and Address. Give name, street, city, state, and zip code. List no more than two levels of an organizational hierarchy. Display the name of the organization exactly as it should appear in Government indexes such as USGRDR-I. 10. Project/Task/Work Unit Number. Use the project, task and work unit numbers under which the report was prepared. 11. Contract/Grant Number. Insert contract or grant number under which report was prepared. 12- Sponsoring Agency Name and Address. Include zip code. 13. Type of Report and Period Covered. Indicate interim, final, etc., and, if applicable, dates covered. 14. Sponsoring Agency Code. Leave blank. 15. Supplementary Notes. Enter information not included elsewhere but useful, such as: Prepared in cooperation with . . . Translation of ... Presented at conference of ... To be published in ... Supersedes . . . Supplements . . . 16. Abstract. Include a brief (200 words or less) factual summary of the most significant information contained in the report. If the report contains a significant bibliography or literature survey, mention it here. 17. Key Words and Document Analysis, (a). Descriptors. Select from the Thesaurus of Engineering and Scientific Terms the proper authorized terms that identify the major concept of the research and are sufficiently specific and precise to be used as index entries for cataloging. (b). Identifiers and Open-Ended Terms. Use identifiers for project names, code names, equipment designators, etc. Use open-ended terms written in descriptor form for those subjects for which no descriptor exists. (c). COSATI Field/Group. Field and Group assignments are to be taken from the 1965 COSATI Subject Category List. Since the majority of documents are multidisciplinary in nature, the primary Field/Group assignment(s) will be the specific discipline, area of human endeavor, or type of physical object. The application(s) will be cross-referenced with secondary Field/Group assignments that will follow the primary posting(s). 18. Distribution Statement. Denote releasability to the public or limitation for reasons other than security for example "Re- lease unlimited". Cite any availability to the public, with address and price. 19 & 20. Security Classification. Do not submit classified reports to the National Technical 21. Number of Pages. Insert the total number of pages, including this one and unnumbered pages, but excluding distribution list, if any. 22. Price. Insert the price set by the National Technical Information Service or the Government Printing Office, if known. (REV. 3-72) USCOMM-OC 148S2-P72 ------- |