v>EPA
United States
Environmental Protection
Agency
Industrial Environmental Research
Laboratory
Research Triangle Park NC 27711
EPA-600/7-80-097
May 1980
Environmental
Assessment: Source Test
and Evaluation Report —
Wellman-Galusha
(Ft. Snelling) Low-Btu
Gasification
Interagency
Energy/Environment
R&D Program Report
-------
RESEARCH REPORTING SERIES
Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:
1. Environmental Health Effects Research
2. Environmental Protection Technology
3. Ecological Research
4. Environmental Monitoring
5. Socioeconomic Environmental Studies
6. Scientific and Technical Assessment Reports (STAR)
7. Interagency Energy-Environment Research and Development
8. "Special" Reports
9. Miscellaneous Reports
This report has been assigned to the INTERAGENCY ENERGY-ENVIRONMENT
RESEARCH AND DEVELOPMENT series. Reports m this series result from the
effort funded under the 17-agency Federal Energy/Environment Research and
Development Program. These studies relate to EPA's mission to protect the public
health and welfare from adverse effects of pollutants associated with energy sys-
tems. The goal of the Program is to assure the rapid development of domestic
energy supplies in an environmentally-compatible manner by providing the nec-
essary environmental data and control technology. Investigations include analy-
ses of the transport of energy-related pollutants and their health and ecological
effects; assessments of, and development of, control technologies for energy
systems; and integrated assessments of a wide-range of energy-related environ-
mental issues.
EPA REVIEW NOTICE
This report has been reviewed by the participating Federal Agencies, and approved
for publication. Approval does not signify that the contents necessarily reflect
the views and policies of the Government, nor does mention of trade names or
commercial products constitute endorsement or recommendation for use.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.
-------
EPA-600/7-80-097
May 1980
Environmental Assessment:
Source Test and Evaluation Report
Wellman-Galusha (Ft. Snelling)
Low-Btu Gasification
by
M.P. Kilpatrick, R.A. Magee, I.E. Emmel,
and G.C. Page
Radian Corporation
P.O. Box 9948
Austin, Texas 78766
Contract No. 68-02-2147
Exhibit A
Program Element No. INE825
EPA Project Officer: William J. Rhodes
Industrial Environmental Research Laboratory
Office of Environmental Engineering and Technology
Research Triangle Park, NC 27711
Prepared for
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Research and Development
Washington, DC 20460
-------
ABSTRACT
This report contains the results of a Source Test and Evaluation Program
performed on a Wellman-Galusha gasification facility at the U.S. Bureau of
Mines Twin Cities Metallurgy Research Center, Fort Snelling site. The gasifier
is operated as part of a Bureau of Mines program to investigate the use of
low-Btu gas as a fuel for iron ore pelletizing. The major objectives of this
program were to provide survey data from which a preliminary assessment of
potential environmental imact could be made, and to identify potential problem
areas which would require further characterization or pollution control tech-
nology implementation. Operational difficulties with the test burner resulted
in the product gas being vented to the start-up flare, bypassing the cyclone,
during the majority of the lignite test (North Dakota, Indianhead), December
9-15, 1978. Therefore, data for the test burner is limited somewhat and the
product gas characterization does not reflect the particulate removal capabil-
ity of the process cyclone. Within these constraints, the test objectives were
met.
The Source Analysis Model/lA was used to provide a rapid screening
technique for identifying and prioritizing potentially harmful waste streams.
Specifically identified as major contributors to the overall health discharge
severity were benzopyrene and carbon monoxide in the product gas; arsenic and
chromium in the test burner flue gas. The gasifier ash sluice water exceeded
Federal drinking water standards for selenium, iron, sulfate, and total dis-
solved solids; and the cyclone dust quench water exceeded the standards for
fluoride, arsenic, lead, and iron. Leachates of the gasifier ash and cyclone
dust fall well below Resource Conservation and Recovery Act specified limits
for trace elements. The product gas and the gasifier ash sluice water
exhibited moderate in vitro cytotoxicity against WI-38 human lung fibroblast
cells.
ii
-------
TABLE OF CONTENTS
Abstract ii
List of Figures v
List of Tables vi
Acknowledgments ix
1 INTRODUCTION 1
1. 1 Test Overview 1
1.2 Results 5
1.3 Recommendations 10
2 PLANT DESCRIPTION 1A
2.1 Process Description 1A
2.2 Plant Operation 18
2.3 Process Flow Rates and Mass Balances 18
3 METHODOLOGIES 23
3.1 Sampling Methodologies 23
3.1.1 Product Gas Sampling 23
3.1.2 Electrostatic Precipitator Sampling 25
3.1.3 Trace Element Sampling . 29
3.1.A Ammonia and Cyanide Sampling 29
3.1.5 Gas Phase Sulfur Species Collection 32
3.1.6 Gas Sampling for Organics 32
3.2 Analytical Methodologies 34
3.2.1 Elemental Analysis 3A
3.2.2 Organic Screening Analysis 3A
3.3 Detailed Organic Analysis Approach AA
3.3.1 Specific Ion Monitoring GC/MS A 7
3.3.2 Halogen-Specific Gas Chromatography ... A9
3.A Quality Assurance A9
iii
-------
TABLE OF CONTENTS
(Continued)
Page
RESULTS 52
4.1 Source Analysis Model/lA Results 52
4.2 Bioassay Results Summary 71
4.2.1 Mutagenicity Test Results (Ames) . 71
4.2.2 In Vitro Cytotoxicity Test Results (WI-38, RAM) .... 72
4.2.3 Acute In Vivo Toxicity Test Results (Rodent) 72
4.2.4 Ecological Testing 72
4.3 Chemical Analysis Results .. 73
4.3.1 Gasification System Overview 73
4.3.2 Gas Streams 84
4.3.3 Liquid Streams 91
4.3.4 Solid Streams 94
References 110
iv
-------
LIST OF FIGURES
Number
1-1 Operating Schematic of the Wellman-Galusha
Gasifier 3
1-2 Data Matrix for the Ft. Snelling Gasifier STE 4
1-3 Total Stream, Weighted Discharge Severities and
Bioassay Test Results for the Fort Snelling
Wellman-Galusha Process Streams 6
1-4 Elemental Distributions in the Gasifier Ash
and Cyclone Dust Ordered by Increasing Elemental
Boiling Point (up to 2212°C) 8
1-5 Elemental Distributions in the Gasifier Ash
and Cyclone Dust Ordered by Increasing Elemental
Boiling Point (2270 to 5927°C) 9
2-1 Operating Schematic of the Wellman-Galusha
Gasifier 15
2-2 Diagram of a Wellman-Galusha Gasifier Equipped
with a Coal Bed Agitator 16
2-3 Normal Operation Schematic of the Wellman-Galusha
Gasifier 19
2-4 Operating Schematic of the Wellman-Galusha Gasifier
with Product Gas Vented 20
2-5 Summary of Fort Snelling Gasifier Operation and
Sampling Periods 21
3-1 Sampling Matrix for the Wellman-Galusha Gasifier
at the U.S. Bureau of Mines Plant 24
3-2 Product Gas Sampling System with ESP 26
3-3 Schematic of ESP Used for Aerosol and Particulate
Removal 27
3-4 Analysis Matrix for Solid Samples 35
3-5 Analysis Matrix for Liquid Samples 36
3-6 Organic Analysis Prioritization Logic Sequence 46
3-7 Specific Ion Monitoring Plot for Benzo(b)fluoranthene ... 48
4-1 Worst Case Weighted Discharge Severity Summary
Based on Screening Analysis Results Only 54
4-2 Gasifier Ash Major Component Enrichment Ratio vs.
Elemental Boiling Point 98
4-3 Gasifier Ash Trace Element Enrichment Ratio vs.
Elemental Boiling Point 99
4-4 Cyclone Dust Major Component Enrichment Ratio vs.
Elemental Boiling Point 100
4-5 Cyclone Dust Trace Element Enrichment Ratio vs.
Elemental Boiling Point 101
-------
LIST Off TABLES
Number
1-1 Comparison of Solid Waste Extracts and RCRA
Extract Limits 11
1-2 Comparison of Wastewater Streams and Drinking
Water Standards 12
2-1 Fort Snelling Process Flow Rates and Material
Balances 22
3-1 ESP Collection Efficiency 28
3-2 Ammonia Collection Efficiency 30
3-3 Cyanide Collection Efficiency 31
3-4 Total Volatile Sulfur in Gas Streams by Impinger
Collection 33
3-5 Comparison of 1CP and SSMS Data for Liquids 38
3-6 Comparison of 1CP and SSMS Data for Solids 39
3-7 Volatile Metal Comparison 40
3-8 Added Extraction Efficiency Using Ethyl Ether
for Solids 42
3-9 Added Extraction Efficiency Using Ethyl Ether
for Liquids 43
3-10 Comparison of Radian 1CP Data and Reported Values
for EPA Water Quality Control Sample #3 51
4-1 Product Gas Particulate/Tar Major Contributions to
DS and WDS for Health Effects Including Worst Case
Assumptions «... 56
4-2 Product Gas Particulate/Tar Major Contributions to
DS and WDS for Ecological Effects Including Worst
Case Assumptions • 57
4-3 Product Gas Organic Module Major Contributions to
DS and WDS for Health Effects Including Worst Case
Assumptions 58
4-4 Product Gas Organic Module Major Contributions to
DS and WDS for Ecological Effects Including Worst
Case Assumptions 59
4-5 Test Burner Flue Gas Major Contributions to DS
and WDS for Health Effects Including Worst Case
Assumptions 60
4-6 Test Burner Flue Gas Major Contributions to DS
and WDS for Ecological Effects Including Worst
Cast Assumptions 61
4-7 Gasifier Ash Major Contributions to DS and WDS
for Health Effects Including Worst Case
Assumptions •• 62
vi
-------
LIST OF TABLES
(Continued)
Number Page
4-8 Gasifier Ash Major Contributions to DS and WDS
for Ecological Effects Including Worst Case
Assumptions • 63
4-9 Gasifier Ash Sluice Water Major Contributions
to DS and WDS for Health Effects Including
Worst Case Assumptions 64
4-10 Gasifier Ash Sluice Water Major Contributions
to DS and WDS for Ecological Effects Including
Worst Case Assumptions 65
4-11 Cyclone Dust Major Contributions to DS and WDS
for Health Effects Including Worst Case
Assumptions 66
4-12 Cyclone Dust Major Contributions to DS and WDS
for Ecological Effects Including Worst Case
Assumptions 67
4-13 Cyclone Dust Quench Water Major Contributions
to DS and WDS for Health Effects Including
Worst Case Assumptions 68
4-14 Cyclone Dust Quench Water Major Contributions
to DS and WDS for Ecological Effects Including
Worst Case Assumptions 69
4-15 Discharge Severity and Weighted Discharge
Severity Summations for the Ft. Snelling
Wellman-Galusha Process Streams Including
Worst Case Assumptions 70
4-16 Bioassay Test/Results Matrix 71
4-17 Mass Flow for the Minor and Trace Elements 74
4-18 Percent Distribution of the Trace Elements
and Minor Elements with the Product Gas
Routed to the Start-Up Flare » . . 77
4-19 Relative Elemental Distribution Estimated
for Discharge Streams in Normal Operating
Configuration 80
4-20 Extractable Organic Summary 83
4-21 Gaseous Species Analysis Summary .. 85
4-22 Trace and Minor Element Compositions of
Product Gas and Test Burner Flue Gas 87
4-23 Organic Compounds Identified from the
Product Gas 90
vii
-------
LIST OF TABLES
(Continued)
Number Page
4-24 Wastewater and RCRA Leachate General
Composition Summary 92
4-25 Trace and Minor Elements in Ash Sluice
Water, Cyclone Quench Water, and
Service Water 93
4-26 Characterization Analysis Results for Solid
Streams 95
4-27 Trace and Minor Elemental Results for
Coal, Gasifier Ash, and Cyclone Dust 96
4-28 Enrichment Ratios for the Gasifier Ash
and Cyclone Dust 97
4-29 Gasifier Ash Sluice Water and RCRA Leachate
Elemental Composition 103
4-30 Cyclone Dust Quench Water and RCRA Leachate
Elemental Composition 104
4-31 Gasifier Ash Total Element and Total Soluble
Element Concentrations ................ 106
4-32 Cyclone Dust Total Element and Total Soluble
Element Concentrations 107
4-33 Comparison of Isotope Analysis and SSMS ........ 109
4-34 Abundances for Uranium Isotopes ....... 109
4-35 Gross Alpha and Beta Analysis and Specific
Isotope Analysis Comparison ......... 109
viii
-------
ACKNOWLEDGMENT
The authors would like to express their appreciation to the operators and
staff of the Bureau of Mines Twin Cities Metallurgy Research Center for
assistance and advice during the performance of this effort. Guidance and
review by W. J. Rhodes and T. K. Janes of EPA/IERL-RTP also contributed
significantly to the successful completion of this source test and evaluation
program.
In addition to the authors, the following members of the Radian staff were
major contributors to the program:
E. A. Baker
R. V. Collins
G. M. Crawford
M. J. Kowalski
D. S. Lewis
W. A. Williams
ix
-------
SECTION 1
INTRODUCTION AND SUMMARY
Radian Corporation of Austin, Texas is performing a comprehen-
sive assessment of low-Btu gasification technology under contract to the
Environmental Protection Agency. A major portion of this assessment
involves Source Test and Evaluation (STE) programs at operating low-Btu
gasification facilities.
This report describes the results of a STE performed on a
Wellman-Galusha gasification facility at the Bureau of Mines (BOM) Twin
Cities Metallurgy Research Center at the Fort Snelling site. The gasifier
is operated by BOM as part of a program to investigate the feasibility of
using low-Btu gas as fuel for an iron ore pelletizing kiln. The BOM
conducts the program and operates the facility in cooperation with the
Pellet Energy Group Steering Committee which includes:
Allis Chalmers
American Natural Gas Service Company
Bechtel Corporation
Bureau of Mines
Burlington Northern
Cleveland-Cliffs Iron Company
Department of Energy
Dravo Corporation
Eveleth Expansion Company
Hanna Mining Company
Inland Steel Company
Inter-City Gas Ltd.
Mansfield Carbon Company
McDowell-Wellman Engineering Company
Davy McKee Corporation
Peoples Natural Gas
Pickens Mather and Company
Reserve Mining Company
U.S. Steel Corporation
Western Energy Company
1.1 TEST OVERVIEW
The objective of the Source Test and Evaluation was to provide
survey data under normal operating conditions from which a preliminary
assessment of potential environmental impacts could be made. In addition,
the test was intended to identify potential problem areas which require
-------
further characterization or application of pollution control technologies.
Achievement of these objectives was limited primarily by operational diffi-
culties during the sample collection period. No significant operational
problems with the gasifier itself were experienced during the test period.
However, difficulties with the test burner resulted in the venting of the
product gas to the start-up flare upstream of the cyclone during the major-
ity of the test. Therefore, only a limited amount of data was collected
for the test burner, and the product gas results do not reflect the par-
ticulate removal capabilities of the cyclone. Product gas characterization
was performed on the start-up vent. Within these constraints, the test
objectives were achieved.
The Wellman-Galusha gasification system characterized during this
test was a commercial scale system providing fuel gas for a pilot scale
pelletizing kiln and a combustion test burner. Figure 1-1 provides a
schematic of the system indicating the streams which were characterized.
Figure 1-2 provides a summary of the data which were collected, and is pre-
sented in this report for each stream. Collection of samples and data was
conducted during a test run of the system December 9-15, 1978, using North
Dakota (Indianhead) lignite.
The major definitive findings of this source test and evaluation
may be summarized:
• The two solid wastes (gasifier ash and cyclone dust)
generated by operation with Indianhead lignite would be
classified as nonhazardous under the RCRA guidelines of
12-18-78. Even though, for most of the trace elements in the
coal, greater than 90 percent of the element mass existed in
the solids, none of the elements were soluble enough in the
RCRA leaching solution to exceed limits. In addition,
neither solid waste exhibited u detectable biological
response in any of the bioassay tests performed.
• Approximately 20 percent of the coal sulfur was retained by
the ash materials. The remainder was converted to gaseous
sulfur components in the product gas. Sulfur removal from
the gas would be required to meet the current New Source
Performance Standards for Utility Boilers.
• The wastewater streams (ash sluice and cyclone dust quench
water) exceeded the National Drinking Water Standards for
pH, TDS, and certain elemental components. Treatment of
these streams prior to discharge would be required.
-------
Coal
Jacket ^
Walor
Flare
Ash
and Sluice
Water
Dust
Quench
Water
To Pelletizer
Kiln
Natural
Gas
Scrubber
Test
Burner
o-
Sampling Points
70-1579-1
Figure 1-1. Operating Schematic of the Wellman-Galusha Gasifier
-------
,
8
2
3
4
5
1
6
Stream
Test Burner Flue Gas
7a Product Gas
Coal Bin Vent Gas
Gasifier Ash
Gasifier Ash Sluice Water
Cyclone Dust
Cyclone Dust Quench Water
Lignite
Service Water
o
01
CO
O
e
CO
TJ W
H C
O M
>*j X Hi
H. . e
X -- H
**1 ft> C3
(-• CL |-> w
O rt X)
« o H- ro
H 0> S 0
03 CO Co H-
rt ro rt ro
rt CO fD CO
• •
•
• •
•
• •
O
CO
TO
(D
O
C
CO
Z
H-
rt
t^
O
TO
fl>
3
Cfl
n>
o
H-
(D
CO
•
f^
t-1
1
n
o
ffi
^
Q.
^
O
o
CD
H
o*
o
3
cn
0 O
•^ n>
(D rt H
(D po H
3 H- pi
H- M O
3 n> ro
OQ CL
flj
0 0 M
cw oo S
(u 0> (D
333
H- H- rt
O O CO
• • •
• •
• • •
• •
•
2
ro
Co Co Co f
I-1 (X rt ro
H- ro CD
o o ^ o
p) f&) p"*
n o jg co
cr rt C o-
O I-L Co H-
3 < M M
*-< H- H- H-
I-1 rt rt rt
CO *< *< ^<
.
• •
•
• •
•
•
Figure 1-2. Data Matrix for the Ft. Snelling Gasifier STE
-------
• Suspected carcinogenic or toxic compounds were identified in
the product gas tar/oil aerosols. Bioassay results confirmed
the toxic nature of this material.
• Use of the Source Analysis Model (SAM/1A) to evaluate the*
potential impacts of the process effluents, indicates, at
this point, that organic components are the major contri-
butors to the potential environmental impacts as measured by
the estimated discharge severity ratio. Additional char-
acterization will be required to confirm or disprove the
presence of these components.
1.2 RESULTS
The results of the source test and evaluation program at the Fort
Snelling gasification facility are summarized for the bioassay tests and
the Source Analysis Model/lA evaluation of the process streams in Figure
1-3. All of the streams were found to contain constituents in potentially
harmful concentrations, however, a low potential for adverse effects is in-
dicated by the bioassay test results for all the streams except the product
gas composite. The product gas composite exhibited moderate toxicity in
the in vitro cytotoxicity test (RAM) and marked toxicity to the test cells
used in the mutagenicity test (Ames). However, no mutagenicity nor any in
vivo toxicity was reported from this sample. Over 3500 yg/SCM of poly-
nuclear aromatic hydrocarbons were identified in the product gas samples
analyzed.
The general organic character of the process streams followed a
trend to more aromaticity in the gaseous streams and cyclone dust quench
water. The cyclone dust was more aromatic than the ash and ash sluice
water which were primarily aliphatic.
One of the primary concerns associated with the use of coal
derived materials as combustion fuels is compliance with regulatory limita-
tions on emissions of oxides of sulfur and nitrogen. Although there were
significant operating problems with the test burner during the sampling
effort, some useful information relating to these components was obtained.
Analyses of the low-Btu product gas determined that 23 percent of the ni-
trogen in the coal was converted to nitrogen-containing compounds (ammonia
and hydrogen cyanide) in the product gas. During combustion, these would
be converted to oxides of nitrogen. The total NOX emission rate would be
dependent on burner design since thermally formed NOX is a major contri-
butor to the total emission.
-------
TOTAL STREAM
DISCHARGE SEVERITY
-" H1 M M I-1;-' Ml-'
"*} W M M M W M M
OMNJOJ *» Ui CT> ^J
1 1 1 1 1 1 1
i
— i
|
1
^MM
1
^HH
1
1
^•M
1
I
^
!
TEST PRODUCT PRODUCT ASH ASH* DUST DUST*
BURNER GAS • GAS SLUICE QUENCH
PARTICULATE MODULE WATER WATER
w
co
H W
BC W
O
1E8
1E7
1E6
1E5
1E4
1E3
1E2
1E1
1EO
\
TEST PRODUCT PRODUCT
BURNER GAS GAS
PARTICULATE MODULE
ASH
ASH*
SLUICE
WATER
DUST
DUST*
QUENCH
WATER
co
g HIGH
CO
pp
MOD. -
LOW/ND -
I
TEST PRODUCT
BURNER GAS
COMPOSITE
ASH
ASH*
SLUICE
WATER
DUST
DUST*
QUENCH
WATER
Health
Ecology
High: High effects
Mod.: Moderate effects
Low/ND: Low or nondetectable effects
*total sample organic loading expressed
as single maximum worst case compound.
Figure 1-3. Total Stream, Weighted Discharge Severities and Bioassay
Test Results for the Fort Snelling Wellman-Galusha Process
Streams
-------
The North Dakota lignite used during the test sampling had a
sulfur content equivalent to 0.58 Ib S/IO^ Btu. Under the proposed New
Source Performance Standards (NSPS) this sulfur level in the fuel would
require a sulfur removal efficiency of 70 percent in the process. Analyses
of the product gas and test burner flue gas (prior to scrubbing) showed
that the product gas contained 71 percent of the coal sulfur during sam-
pling period two and the test burner flue gas contianed 72 percent of the
coal sulfur during sampling period one. These results indicate that the
gasification process alone is not adequate to meet the sulfur removal
requirements of the proposed NSPS for combustion sources. Additional
sulfur removal in the form of acid gas removal processes on the product gas
or flue gas desulfurization will likely be required.
The results of the SAM/1A analysis of the data indicate that the
trace and minor elemental components are secondary to the organics in
health and ecological concern. These elements enter the process in the
coal, and during the gasification reactions are distributed among the
various streams leaving the gasifier. For almost all of the elements
characterized, greater than 90 percent of the mass of the elements entering
with the coal exited with the cyclone dust and gasifier ash. During
gasification individual elements may (1) remain in the solids and be
distributed in the same proportions as the coal ash or (2) be volatilized
and exit with the product gas or (3) be volatilized and recondense as the
gases leave the zones of very high temperature. Most of the elements fall
in the first or third category.
Eight elements have significantly more than 25 percent of their
total mass in the gas and may be considered to exhibit category two
(volatile) behavior:
Antimony Lead
Arsenic Mercury
Cobalt Selenium
Iodine Sulfur
Figures 1-4 and 1-5 present the distribution of the elements in
the gasifier ash and the cyclone dust. The elements are in ascending order
of boiling point of each element. The difference between the sum of
cyclone dust and gasifier ash from 100% represents the mass of each element
which exits in the test burner flue gas.
Generally, the volatile elements are more concentrated in the test
burner flue gas and the cyclone dust. This is not strictly true since the
ordering does not consider compounds which may be more volatile than the
element. Identification of specific compounds would be required for a more
precise correlation.
-------
ex
faction of Total (%)
s s § i
u.
20-
I
i
1
i
1
"
i
1
-3
a
S
•
1
1
1
•
P
"7"
EH Cyclone Dust
Q GaslllerAsh
_
1
~
i
;
1
•
i
F Cl Br I
P Hg S As Se Rb Cs Cd K Na Zn Mg Ba Li Sb Sr Yb Eu Ca Pb Sin MM Aq
Elements
Figure 1-4. Elemental Distributions in the Gasifier Ash and Cyclone Dust
Ordered by Increasing Elemental Boiling Point (up to 2212°C)
-------
100-
80-
40-
20-
~~
m
E33 rja E2
--
^ Cyclone Dust
r~l Qaslller Ash
"
Sn Si Ga Al Cr B Cu Dy Ho Sc Nl Tb Ge Co Er Y Gd Fe V Nd Pr Ti Ce La Zr U Th Nb Mo W
Elements
Figure 1-5. Elemental Distribution in the Gasifier Ash and Cyclone Dust Ordered by
Increasing Elemental Boiling Point (2270 to 5927°C)
-------
The form in which an element occurs naturally in the coal may be
an additional determiner of its distribution. Elements associated pre-
ferentially with the organic phase of the coal are more likely to parti-
cipate in reactions and be more readily volatilized than those found in the
mineral phase. Many elements, however, have been found to be associated
with the organic phase in one coal and with the inorganic phase in another.
Variations can depend on mineral (ash) and sulfur content, which are
directly affected by coal type and conditions of formation.
The impact of the trace element content of the two solid wastes on
disposal of the material was evaluated using the extraction procedures spec-
ified by the Resource Conservation and Recovery Act (RCRA) (Ref. 1).
Leachates produced by extraction of the gasifier ash and cyclone dust were
analyzed for a number of trace elements and general water quality param-
eters. Table 1-1 presents the concentrations of those elements with RCRA
specified limits. In all cases, the elemental concentrations are at least
an order of magnitude below the RCRA limits.
The only two wastewaters in the gasification system are generated
by using plant service water to sluice or quench solids. During contact
with the solids, components may dissolve in the water which render it
unsuitable for discharge without treatment. Table 1-2 presents a compari-
son of the wastewater compositions with Federal Drinking Water Standards.
Both were more basic than allowable pH limits. The gasifier ash sluice
water exceeded the standards in total dissolved solids, sulfate, selenium,
and iron. Mercury and fluoride concentrations are 70 percent and 50 per-
cent of the standards and will require additional data to insure that they
will not exceed the limits. The cyclone dust quench water exceeded the
standards for fluoride, arsenic, lead, and iron. In addition, the levels
of total dissolved solids, selenium, and barium, appear to warrant further
study.
1.3 RECOMMENDATIONS
Specific recommendations for consideration in future assessment
activities fall into two categories:
(1) additional data needs, and
(2) methodology recommendations.
Data Needs
The source test and evaluation conducted at the Fort Snelling site
combined with the results of a similar effort at the Glen Gery Brick
Company (Ref. 2), provide environmental and process data on Wellman-Galusha
gasifiers operating on lignite and anthracite coal. Characterization of
materials from a similar gasification system operating on bituminous or
subbituminous coal would compliment the available data and vastly improve
the existing data base for Wellman-Galusha gasifiers.
10
-------
TABLE 1-1. COMPARISON OF SOLID WASTE EXTRACTS AND RCRA EXTRACT LIMITS
Element
As
Ba
Cd
Cr
Pb
Hg
Se
Ag
RCRA1
Extract Limits
(12/18/78)
(mg/a>
0.50
10
0.10
0.50
0.50
0.02
0.10
0.50
Gasifier Ash
Leachate
(mg/fc)
0.019
1.0
<0.007
0.001
0.007
<0.001
0.014
<0.001
Cyclone Dust
Leachate
(mgM)
0.033
1.0
<0.001
0.001
0.008
<0.001
0.006
<0.001
RCRA = Resource Conservation and Recovery Act
11
-------
TABLE 1-2. COMPARISON OF WASTEWATER STREAMS AND DRINKING WATER STANDARDS
Element
As
Ba
Cd
Cl"
Cr
Cu
F~
Fe
Ph
Mn
Hg
Se
Ag
Zn
SOiT
pH
TDS
NIPDWS l
(mg/A)
0.05
1.0
0.01
0.05
1.8
0.05
0.002
0.01
0.05
Gasifier Ash
PNSDWR2 Sluice Water
(mg/A) (mg/A)*
0.0033
0.13
<0.002
250. 78.
0.007
1.0 0.017
0.87
0.3 1.2
0.008
0.05 0.002
0.0014
0.020
0.001
5.0 0.044
250. 2860.
6.5-8.5 9.3
500. 4300.
Cyclone Dust
Quench Water
(mg/A)*
0.12
0.57
<0.005
34.
<0.005
0.012
2.0
4.9
0.099
<0.001
0.0004
0.006
0.002
0.035
55.
10.0
390.
NIPDWS - National Interim Primary Drinking Water Standards, Federal
Register (3/31/77)
2PNSDWR * Proposed National Secondary Drinking Water Regulations,
Federal Register (3/31/77)
*Metal results by SSMS except As, Hg, and Se which were done by
hydride AA. Non-metal species by Standard Methods.
12
-------
Operational problems during the sample collection portion of this
STE program precluded complete characterization of the test burner flue
gas. The combustion effluents which were characterized were produced
during combustion with extremely high excess air. Combustion data for
low-Btu fuel gas under more typical commercial combustion conditions is
required to adequately characterize the potential environmental impacts.
Additional analytical effort is required to confirm or disprove
the presence of the assumed "worst case" chemical forms used in the Source
Analysis Model/lA results presented in this report.
The variability of key components over long-term operation still
requires definition. This will require longer periods of stable gasifier
operation (on the order of 30 days) than have thus far been available.
Methodology
The detailed organic analysis approach based on the iterative use
of the SAM/1A results proved to be a valuable tool in the planning of
analytical activities. Computerization of the SAM/1A calculations makes
this practical by reducing the effort required. Continued use of this
approach in conjunction with the addition of generalized sample charac-
terization techniques is recommended.
A small scale electrostatic precipitator (ESP) was used in the
product gas sampling train, and was highly successful and efficient for the
collection of particulates and aerosol tars. Continued use of the ESP for
tar laden streams is recommended after modification of the equipment for
operation at higher temperatures.
Both the silver persulfate collection solution and the acid/base
collection trains were used during the Fort Snelling STE for collection of
vaporous trace elements. However, direct comparison of the two was not
possible. An evaluation of the collection efficiencies of the two
approaches is recommended.
Two specific analytical recommendations resulted from this
program. Addition of an ethyl ether extraction to the organic sample
preparation significantly increased the extraction efficiency over extrac-
tion with methylene chloride only. Elemental analysis with inductively
coupled argon plasma emission spectrometry (ICP) proved to be a comple-
mentary technique to spark source mass spectrometry and greatly extended
the range of quantitation. Both of these additions should be continued.
13
-------
SECTION 2
PLANT DESCRIPTION
A commercial size Wellman-Galusha gasifier was assembled at the
Bureau of Mines Fort Snelllng test facility to determine the feasibility
of using low-Btu gas (5.6E6 J/m3, 150 BTU/scf) to pelletize iron ore.
During the late fall of 1978, several short test runs, approximately 5 days
each, were made using coke, bituminous coal, semi-bituminous coal (ranking
slightly higher than subbituminous), and a lignite as gasifier feedstocks.
The gas produced during these tests was burned in a test burner designed to
study the low-Btu gas combustion characteristics. The following sections
provide a description of the Fort Snelling gasification facility configur-
ation and operation during the source test and evaluation program con-
ducted, by Radian.
2.1 PROCESS DESCRIPTION
The following brief process description Introduces the reader to
the program test facility shown in Figure 2-1.
Coal, Hand i "fog
At the Fort Snelling test facility, coal is stored in piles near
the gasifier. A front-end loader moves the hopper. The coal is moved by
the belt conveyor, to a vibrating screen where coal fines less than 1.9 cm
(3/4 inch) are removed for disposal. From the screen, the coal is moved to
the top of the gasification building by a bucket elevator where it falls
into a coal storage bin.
Coal from the coal bin flows by gravity into the two coal hoppers
located atop the gasifier. The coal hoppers continuously feed coal into
the gasifier by gravity flow through two vertical feed pipes. Four slide
valves are used to control the coal flow rate.
Gasification/Gas Purification
In the gasifier (shown in Figure 2-2) a water-cooled agitator dis-
tributes the coal evenly as it falls from the feed bin. As the hot product
gas rises from the bottom of the gasifier, it dries and devolatilizes the
coal as the coal moves down in the gasifier to the gasification zone. At
the bottom of the gasifier, the coal is partially combusted by moist air
forming a low-Btu product gas and ash. The ash falls through a rotating
grate, is dumped through a valve at the bottom of the gasifier, and is
disposed. Steam to the gasifier is provided by passing air over hot water
in the gasifier cooling jacket before the air enters the bottom of the
gasifier.
14
-------
Coal
Ul
Jacket
Water f
Ash
and Sluice
Water
Dust
Quench
Water
_^ ToPelletizer
Kiln
Natural
Gas
Scrubber
Test
Burner
o
Sampling Points
70-1579-1
Figure 2-1. Operating Schematic of the Wellman-Galusha Gasifier
-------
VENT
ELEVATOR
AGITATOR
COUNTERWEIGHT
COAL BIN
COAL HOPPERS
PRODUCT GAS
AGITATOR
-^. JL -
SATURATION
DEVOLATILIZATION ZONE
GASIFICATION ZONE
COMBUSTION ZONE
REVOLVING GRATE
CYCLONE AND
WATER SEAL
SHUT-OFF
VALVE
Figure 2-2. Diagram of a Wellman-Galusha Gasifier
Equipped with a Coal Bed Agitator
16
70-1428-1
-------
The hot low-Btu product gas is cooled as it passes up through the
coal in the gasifier. During start-up or banking, the gasifier product gas
is diverted to the start-up vent and flare. During normal operation, the
product gas passes through a refractory-lined cyclone before going to the
pelletizer kiln and test burner. Large particulates in the product gas
fall to the bottom of the cyclone, down the cyclone leg, and into a water
quench. The quenched particulates are scraped out of the quench trough,
passed over a dewatering screen and disposed. Water from the quench trough
flows to the process sewer.
Test Burner
Most of the low-Btu gas produced in the Wellman-Galusha gasifier
is burned in a test burner. The test burner is a combustion chamber
designed to study the burning characteristics of low-Btu gas. The
combustion gases from the test burner are contacted with a caustic water
solution which removes SC>2 before the gases are discharged to the
atmosphere through an exhaust fan. Spent caustic water solution from the
combustion gas scrubber is discharged to the process sewer from the
scrubber recycle tank.
Waste Stream Summary
The Fort Snelling gasifier/test burner facility major waste
streams are:
• Gaseous waste streams
coal feed system vent gases,
- start-up flare combustion gases, and
- test burner scrubber exhaust.
• Liquid waste streams
jacket water,
- ash sluice water,
- cyclone quench water, and
- test burner flue gas scrubber blowdown.
• Solid waste streams
- gasifier ash,
- cyclone particulates, and
- coal fines.
17
-------
2.2 PLANT OPERATION
The Fort Snelling Wellman-Galusha gasifier was started up on coke
December 8, 1978, after being shut down to repair a leak in the gasifier
water jacket. After achieving stable operation on coke, a North Dakota
lignite (Indianhead) was started to the gasifier feed system on December
10. Late on December 11, the lignite had displaced the coke, and the plant
was operating as shown in Figure 2-3. However, before gas sampling was
initiated, a sudden buildup in pressure in the gasifier test burner system
caused the test burner to flame-out at ^0200 hours on December 12. One set
of solid and liquid samples was collected just before the flame-out (2300-
2400 hours of December 11).
The gasifier was banked after the test burner flame-out and until
the test burner system was checked. Normal plant operation was reestab-
lished by noon of December 12. Sampling of solid and liquid streams
(sample points 1, 2, 3, 4, 5, 6) and the test burner and product gas
streams (points 7 and 9) was initiated. However, due to a pressure buildup
in the gasifier system, the gasifier product gas to the test burner and the
pelletizer kiln was automatically sent to the afterburner at ^2200 hours on
December 12. Sampling of the unit was suspended at this time.
Inspection of the product gas line to the test burner and pelle-
tizer kiln revealed plugging due to the accumulation of tar and conden-
sate (organic and aqueous). However, the gasifier operation was con-
tinued with the product gas being vented to the flare as shown in Figure
2-4. Sampling of the test burner exhaust gas and pelletizer kiln exhaust
gases could not be completed under this mode of operation. However,
sampling of the coal bin vent gases, the gasifier product gas, and gasifier
solid and liquid streams (sample points 1, 2, 3, 6, 7a, and 8) was
accomplished from ^1700 hours on December 13 through ^0200 hours on
December 14.
Due to the early shutdown of the test burner, only a partial
characterization of the combustion gases was made. In addition, the
gasifier operation on December 13th and 14th was hindered by channeling in
the gasifier resulting in oxidation at the top of the gasifier bed. Figure
2-5 summarizes the pertinent gasifier test burner operating conditions dur-
ing the two sampling periods.
2.3 PROCESS FLOW RATES AND MASS BALANCES
Pertinent process data were collected by the Bureau of Mines
personnel and computerized data gathering system. Flow ra'.es and material
balances provided by the Bureau of Mines were used to calculate the mater-
ial balances for the two sampling periods as summarized in Table 2-1. Data
presented for the second sampling period were averaged over two data seg-
ments provided by the Bureau. The data provided by the Bureau of Mines are
presented in Appendix A; in addition, the estimated error limits for each
of the process streams are presented.
18
-------
Coal
Jacket
Water
Ash Sluice
Water
Ash
and Sluice
Water
jQuench [
-0
Dust
Quench
Water
To Pellelizer
Kiln
Natural
Gas
Scrubber
Tesl
Burner
o-
Sampling Points
70-1579-1
Figure 2-3. Normal Operation Schematic of the Wellman-Galusha Gasifier
-------
COAL
JACKET
WATER
JACKET ^
WATER
'cb-
FLARE
o
= Sampling Points
ASH SLUICE
WATER
ASH AND SLUICE.
WATER
70-1580-1
Figure 2-4. Operating Schematic of the Wellman-Galusha Gasifier
with Product Gas Vented
20
-------
Mode Fuel
Normal - coke
Normal - coke-lignite
Normal - lignite
Vented - lignite
Banked - lignite
Sampling Periods
Product Gas and
Test Burner Exhaust
Product Gas Vent
and Coal Bin Vent
Sat. Sun. Mon. Tues. Wed. Thur. fri.
9 Dec. 10 Dec. 11 Dec. 12 Dec. 13 Dec. 14 Dec. 15 Dec.
1200
- .. 1
2200
' '0200 2200
1—1 1 ' 1400
i |
1200 1400 '
i ill
I 1 1 • 1
1430 2124
1604 0247
I • i
I 1
Figure 2-5. Summary of Fort Snelling Gasifier Operation and Sampling Periods
-------
TABLE 2-1. FORT SMELLING PROCESS FLOW RATES AND MATERIAL BALANCES
Stream Description
FLOW RATES (g/s)
Sampling Period 1 Sampling Period 2
INPUT STREAMS
Air
Water
Coal
Total
OUTPUT STREAMS
Ash
Dust
Hot Product Gas
Total
RATIO INPUT TO OUTPUT
500 ± 50
67 ± 7
320 ± 32
887 ± 60
27 ± 3
3.8 ± 2
860J± 86
891 ± 86
0.9S
440 ± 44
66 ± 7
250 ± 25
756 ± 51
21 ± 2
7002! 70
721 ± 70
1.05
Includes product gas, steam, and tar.
2Includes product gas, steam, tar, and dust.
22
-------
SECTION 3
METHODOLOGIES
The techniques cited (Ref. 3) and described in Appendix C formed
the core of the approach to the source test and evaluation of the Fort
Snelling facility. Additions to or deviations from these methods are
described in the following sampling and analytical methodology sections.
3.1 SAMPLING METHODOLOGIES
Due to the plant operational problems encountered during the
on-site sampling and analysis portion of this program, not all of the
originally scheduled sampling could be implemented. A partial charac-
terization of the test burner flue gas was completed; however, no samples
of the pelletizer kiln exhaust gas were taken. In order to determine the
fate of ammonia and cyanide in the test burner, test burner flue gas
samples were obtained simultaneously with product gas samples for the
determination of ammonia and cyanide concentration. During this sampling
period, samples for Cj^ to Cg hydrocarbons, volatile sulfur species, and
fixed gas content were also taken at both locations. A pressure build-up
in the gasifier caused by an accumulation of particulates, tar, and con-
densate in the product gas line resulted in the product gas being sent to
the start-up flare, bypassing the cyclone, test burner, and pelletizer
kiln. Therefore, the bulk of the product gas sampling was done at the
start-up vent to the flare prior to the cyclone. Samples of the coal bin
vent gases, the gasifier ash and ash sluice water were taken during this
mode of plant operation. Cyclone dust and dust quench water samples were
only obtained during the period of normal cyclone operation. An overview
of the samples taken and the sampling techniques used at the gasifier/test
burner is given in Figure 3-1.
Sampling procedures for the test burner flue gas are discussed in
Appendix B of this document. The grab samples of the liquid and solid
streams were taken periodically during the sampling effort and are
discussed also in Appendix B.
3.1.1 Product Gas Sampling
Only the ammonia and cyanide impinger samples and gas samples for
fixed gases, volatile sulfur species, and C^ to G£ hydrocarbons were
taken of the product gas at the exit of the cyclone. Due to the pressure
buildup, the product gas was then routed through the start-up vent to the
flare thus bypassing the cyclone. A 51 mm port on the start-up vent was
used for sampling; this port had no gate valve and was entered directly.
The sampling at this site was essentially a continuation of the product gas
sampling program. The product gas to the flare contained all the elements
23
-------
SAMPLES
i
CO
•d
ft)
H
rt
o
H
P>
rt
re
w
CO
"S
a
H-
n
C
H
P>
rt
re
g
T
^
ro
co
H-
3
O
O
8.
8
CO
rt
re
H
re
8?
rt
ft)
I-1
co
P*
CO
CO
H
8 8
H- re
o* re
pi rt
CO pi
re H
CO
i
r
3
K*
ft)
tr
•o
H-
3
00
i-l
CO
o
3
H-
o.
re
I
H-
3
00
re
H
CO
en
H
Hi
C
H
H-
5-
00
re
hf
CO
1
&)
o
ft)
y
M
1
H-
3
00
re
H
CO
H-
X
re
00
ft)
ca
re
co
pj
HI
H
CO
•O
re
o
H-
re
co
o
o
re
o.
M
8
S
CT-
o
3
co
re
H
re
co
H-
3
g
H
00
P)
3
H-
O
1
C
*
^j
00
o
1
cr
H
w
H.
o
P)
CO
CO
p>
1
£
^
to
JS
Test Burner
Product Gas
Product Gas (vent)
Coal Bin Vent Gas
Gasifier Ash
Gasifier Ash Sluice Water
Cyclone Dust
Cyclone Dust Quench Water
Lignite
Service Water
Figure 3-1.
Sampling Matrix for the Wellman-Galusha Gasifier
at the U. S. Bureau of Mines Plant
-------
of the product gas plus particulates and high molecular weight aerosol tars
normally removed by the process cyclone.
The sampling train used at both product gas sampling locations is
shown schematically in Figure 3-2. This system contained sample taps for
gas chromatography grab samples and for sampling with two independent
impinger trains behind an electrostatic precipitator.
3.1.2 Electrostatic Precipitator Sampling
Due to the high oils and tars concentration in the product gas, an
electrostatic precipitator (ESP) was used instead of the SASS cyclones and
filter for particulate removal during the product gas sampling. The ESP
removes particulates and aerosol tars from the gas stream by creating an
electron wind between the negatively-charged central electrode and the
positively-charged outer wall. This electron wind imparts a negative
charge to the aerosolized particles. These particles are then attracted to
the outer wall of the ESP. As the gas stream passes through the collection
zone, the particles migrate to the outer wall, discharge, and fall down to
the collection cup at the bottom of the ESP. A schematic of the ESP used
is shown in Figure 3-3.
The particulates collected by the ESP and filter would be common
to any train used. However, the ESP was operated at 140°C (285°F), there-
fore, the vapor phase material collected in the organic module was that
material which passed through the ESP at 140°C (285°F), not 200°C (400°F)
as for other SASS runs. Due to this lower operating temperature of the
ESP, some vapor phase material which would normally be collected in the
organic module was collected in the ESP as tarry condensables in addition
to the aerosol tars removed from the gas stream by electrostatic
precipitation.
The material recovered from the ESP, the ESP rinse, and filter
remained separate through a portion of the analytical matrix to enable the
calculation of ESP efficiency. The quantity of methylene chloride insol-
uble material was also determined to distinguish between particulates and
tars. The ESP efficiency in removing particulates and aerosol tars from the
product gas was calculated to be 99.2% as shown in Table 3-1. Of the
material collected, 32% was methylene chloride insoluble.
The SASS organic module was operated in the standard manner except
the XAD-2 canister was separated from the condenser to reduce contact
between resin and condensate. Due to the size of the ESP, the flow rate
through the entire system was limited to 280 ml/sec. Also, due to the high
organic loading of the product gas, the total gas volume of the sample was
reduced from the recommended 30 SCM in order not to overload the organic
module.
25
-------
to
HEATER
CONTROLLER
STACK T.C.
ss PROBE
S-TYPE PITOT
ESP AND FILTER
IN OVENS
0AS COOLER
XAD-2 CARTRIDGE
GAS TEMPERATURE T.C.
IMPINGERT.C
DRY GAS METER
ORIFICEMETER
CENTRALIZED TEMPERATURE
AND PRESSURE READOUT
CONTROL MODULE
VACUUM PUMP
r- TRACE ELEMENT
\ IMPINGERS
\ (COOLED)
1
Figure 3-2. Product Gas Sampling System with ESP
701999 I
-------
ELECTRODE
STANDOFF
0.010" DIA.S.S.
ELECTRODE
INLET
OUTLET
DC
POWER SUPPLY
ELECTRODE
STANDOFF
GROUND
Figure 3-3. Schematic of ESP Used for Aerosol and Particulate Removal
27
-------
TABLE 3-1. ESP COLLECTION EFFICIENCY
Material Collected by the ESP: 39.754g
Material Collected by the Filter: 0.306g
TOTAL MATERIAL COLLECTED: 40.060
Material collected by the ESP
ESP Collection Efficiency (%) « x 100
Total material collected
- 99.2%
Gas Volume Sampled: - 8.5 SCM1
Average Sampling Rate: - 0.28 Vs
:SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
28
-------
Gas samples were taken for GC analysis at the inlet of the ESP and
at the exit of the ESP to ascertain the effects of the ESP on gas composi-
tion. No measurable effects or discernible trends were seen. The results
of these gas analyses are given in Appendix D.
3.1.3 Trace Element Sampling
Trace metals in the gas streams were collected using two different
sampling systems. Two ammonium persulfate impingers were used to collect
vaporous trace metals in the test burner flue gas upstream of the caustic
scrubber. However, vaporous trace elements in the product gas exiting the
ESP and organic module were collected by a series of impingers: two
10 percent nitric acid impingers and two 10 percent sodium hydroxide
impingers.
The planned comparison of the two collection systems was not done
because of operational problems with the gasifier. An evaluation of the
collection efficiencies of the two trace element collection systems still
needs to be made.
3.1.4 Ammonia and Cyanide Sampling
Each ammonia or hydrogen cyanide sampling train consisted of two
absorbing impingers. Collection efficiencies of the absorbing solutions
were calculated by analyzing both impingers in each sample run. Collection
efficiency of the first impinger was defined as:
x 100
where: ygj = total yg of analyte in first impinger, and
Ugu " total yg of analyte in second impinger.
Ammonia was collected totally in the first impinger even at the
high concentration of the product gas. Some carryover at high concentra-
tions was detected in the cyanide impingers. Assuming the collection
efficiency of the second impinger is the same as the first, the overall
collection efficiency for the ammonia and cyanide absorbing systems was
greater than 99 percent. The collection efficiency data for ammonia are
summarized in Table 3-2 and for cyanide in Table 3-3.
29
-------
TABLE 3-2. AMMONIA COLLECTION EFFICIENCY
Stream
Product Gas
Coal Bin Vent
i
Test Burner
Flue Gas
Run f
1
1
2
2
3
3
1
1
2
2
3
3
Ammonia
Impinger #
1
2
1
2
1
2
1
2
1
2
1
2
not detected
Total
yg/ Impinger
20,400
ND
18,000
ND
8,000
ND
193
ND
ND
ND
KD
ND
Collection
Efficiency
> 99%
> 99%
> 99%
> 88%
— „
•••••••
ND = not detected at less than 25 yg ammonia per impinger.
30
-------
TABLE 3-3. CYANIDE COLLECTION EFFICIENCY
Stream Run #
Product Gas 1
1
2
2
3
3
Test Burner 1
1
2
2
3
3
Coal Bin Vent 1
1
2
2
3
3
Impinger #
1
2
1
2
1
2
1
2
1
2
1
2
1
2
1
2
1
2
Total Ug/
Impinger
36,600
760
26,000
1,800
23,000
760
ND
ND
325
7
457
2
27
ND
17
ND
20
ND
Collection
Efficiency
987.
94%
97%
98%
99%
>87%
>81%
>83%
ND
not detected at less than 4 yg cyanide per impinger.
31
-------
3.1.5 Gas Phase Sulfur Species Collection
Two methods were employed to determine the concentration of the
gaseous sulfur species present in the product gas and the coal bin vent
gas. An impinger collection method using six percent hydrogen peroxide for
the sulfur oxides, 2N zinc acetate to trap sulfide, and 0.2N potassium
hydroxide in ethanol to collect carbon disulfide and carbonyl sulfide, was
compared to the flame photometric GC (FPD-GC) determination which is
discussed in detail in Appendix C. The results from the impinger methods
are given in Table 3-4.
At the product gas start-up vent to the flare, the total volatile
sulfur concentration by FPD-GC was 1280 vppm + 200 (2 a) the average of six
duplicate analyses performed over a six hour period, while the impinger
collection method gave a total volatile sulfur concentration of 990 vppm.
Although further evaluation of the selective speciation and trapping
efficiency of the impinger method is called for, the total volatile sulfur
concentration is In general agreement with the flame photometric-GC method.
Gas chromatography samples from the coal bin vent were not
sufficiently pressurized to provide an analysis without the possibility of
dilution occurring. The two impinger runs at this location yielded 1.5 and
2.1 vppm total volatile sulfur species, respectively.
3.1.6 Gas Sampling for Organics
Sampling for organics in the product gas and the test burner flue gas
deviated from recommendations (Ref. 3) only by the arrangement of the
condensate trap and the resin canister. At both of these locations, as
previously stated, the condensate trap was prior to the XAD-2 resin
canister.
To characterize the volatile organics present, a sorbent trap filled
with Tenax GC/sillca gel was used for the product gas prior to the cyclone.
A 100 ml sample of the product gas was pumped through the tube for sub-
sequent thermal desorption GC-MS analysis. Tenax trap samples of the coal
bin vent gas were also taken; however, these samples were not analyzed due
to the possibility of an unknown volume of diluent air entering the
sampling system.
32
-------
TABLE 3-4. TOTAL VOLATILE SULFUR IN GAS STREAMS BY IMPINGER COLLECTION
u>
u>
STREAM RUN
Product Gas* 1
Coal Bin Vent 2
Gas
Coal Bin Vent 3
Gas
IMPINGER
2N ZnOAc
0.1N KOH in EtOH
6% H202
2N ZnOAc
0.1N KOH in EtOH
6% H202
2N ZnOAc
0.1N KOH in EtOH
6% H202
IMPINGER
WEIGHT, g
282.06
159.49
233.48
198.95
147.47
218.60
186.90
147.47
209.15
TOTAL
TTIJ-L ^ /
mg b/
IMPINGER mg S SCM
452
4.67 459.7 0.3549
3.0
1.08
<.005 1.31 0.6875
0.23
0.20
<.005 1.59 0.5675
1.39
SULFUR
mg S/SCM vppm
1295 990
1.9 1.5
2.8 2.1
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
*at the vent to the flare.
-------
3.2 ANALYTICAL METHODOLOGIES
Laboratory analyses of the solid and liquid samples followed the
analysis matrices shown in Figures 3-4 and 3-5, respectively. The samples
joined by brackets in the analyses diagrams were composited prior to the
analyses. Descriptions of the analytical procedures used are given in
Appendix C of this document.
3.2.1 Elemental Analysis
Analysis for 22 elements by inductively coupled argon plasma
emission spectrophotometry (ICP) in addition to spark, source mass spec-
trometry (SSMS) analysis was performed on the following samples:
cyclone dust,
gasifier ash,
product gas particulates,
gasifier ash sluice water, and
cyclone dust quench water.
This comparison was done to determine the feasibility of using ICP
for the screening of low-fitu gasification samples. The ICP requires the
sample be in a liquid form for analysis, i.e., solids must be dissolved.
Spark source can be run on either solid or liquid samples with little or no
preparation. ICP has a greater analytical dynamic range (10^) than SSMS,
thus enabling quantification of the higher concentration components not
possible with SSMS. The lower detection limits of ICP however can be
limited because of dilution in the digestion process. Detection for the
lanthanides and actinides using SSMS are far superior to those of ICP.
Tables 3-5 and 3-6 present a comparison of available ICP and SSMS data. For
the volatile elements, mercury, arsenic, antimony and selenium, the com-
parison is extended to ICP, SSMS, and atomic absorption spectrophotometry
(AA) in Table 3-7. No clear trends toward a single analytical technique
are apparent in these data.
3.2.2 Organic Screening Analysis
The organic screening analysis followed the procedures given in
Appendix C. One significant deviation from the previously used procedures
was the addition of ethyl ether as an extraction solvent. The ether was
used after the regular methylene chloride extraction in order to recover
the highly polar organics which are not as efficiently extracted by methy-
lene chloride. All of the extracts were kept separate for preliminary
total chromatographable organics (TCO) and gravimetric (GRAV) determina-
tions to evaluate the added efficiency of the ether extractant.
34
-------
Analyses
Log
Number
Sample
Description
a
M
rt
H-
a
BJ
rt
fD
Proximate
Mineral
Analysis
W
H-
N
H-
00
Morphology
w
s
VI
*
O
1-1
o
CO
CO
P
*<
TO
Specific
Isotopes
Leaching
Organic
Bioassay
M
n
^
(jj
Ln
FS- 9 Lignite
FS- 11 Lignite
FS- 21 Lignite
FS- 24 Lignite
FS- 50 Lignite
FS- 72 Lignite
FS- 15 Gasifier Ash
FS- 47 Gasifier Ash
FS- 61 Gasifier Ash
FS- 70 Gasifier Ash
FS- 20 Cyclone Dust
FS- 28 Cyclone Dust
FS- 33 TB SASS XAD Resin
FS- 34 TB SASS Cyclone)
FS-145 TB SASS Filter )
FS-170 PG Filter )
FS-171 PG Filter I
Extract with CH2C12 and
composite with solids from
FS-75, FS-144, FS-168
* Includes Hg, As, Sb, Se by AA.
TB: Test Burner.
PG: Product Gas.
Log numbers correspond to the sample log given in Appendix B.
Figure 3-4. Analysis Matrix for Solid Samples
-------
Analyses
Log
Number
Sample
Description
•» 3 (0 B PJ co
H- 3 O 3 co
OHH O O 3 H- 3 M
OCOO 3MM-D.COO
Own cn cn to n> * *d
FS- 5 Gasifier Ash Sluice Water
FS- 5 Cyclone Quench Water
FS-26 Cyclone Quench Water
FS-12 Gasifier Ash Sluice Water
FS-43 Gasifier Ash Sluice Water
FS-51 Gasifier Ash Sluice Water
FS-66 Gasifier Ash Sluice Water
u>
FS-13 Gasifier Ash Sluice Water
FS-45 Gasifier Ash Sluice Water
FS-52 Gasifier Ash Sluice Water
FS-68 Gasifier Ash Sluice Water
FS-14 Gasifier Ash Sluice Water
FS-46 Gasifier Ash Sluice Water
FS-53 Gasifier Ash Sluice Water
FS-67 Gasifier Ash Sluice Water
FS-17 Cyclone Quench Water i
FS-25 Cyclone Quench Water }
FS-18 Cyclone Quench Water
FS-19 Cyclone Quench Water
FS-27 Cyclone Quench Water
FS-16 Service Water
Figure 3-5. Analysis Matrix for Liquid Samples
-------
Analyses
Log
Number
Sample
w
o
T)
BC
o
Q
T)
3*
(B
O
H
CO
H
O
O
O
3
Description
S
CO
*
O
Ash Leachate
Cyclone Dust Leachate
FS-38
FS-39
FS-40
FS-77
FS-78
FS-79
FS-80
FS-81
82-84
85-88
89-93
94-99
100-120
121-139
FS-167
FS-168
FS-144
FS-75
TB SASS Impingers
TB SASS Impingers
TB SASS Impingers
PG TM Impingers
PG TM Impingers
PG TM Impingers
PG TM Impingers
PG TM Impingers
Metal Carbonyl Impingers
Total Sulfur Impinger-KOH
Total Sulfur Impinger-H202
Total Sulfur Impinger-Zn Acetate
Ammonia Impinger-H2SOi«
Cyanide Impinger-NaOH
Ag2S208 Blank
PG Probe Rinse
PG ESP Tar ) CH2C12 Composite
PG ESP Rinse J Extracts
•
•
•
•
Fe, Ni
Total S
Total S
Total S
NH3
HCN
.
•
*Includes Hg, As, Sb and Se by AA.
TB: Test Burner.
PG: Product Gas.
Log numbers correspond to the sample log given in Appendix B.
Figure 3-5. Analysis Matrix for Liquid Samples (Continued)
-------
TABLE 3-5. COMPARISON OF ICP1 AND SSMS2 DATA FOR LIQUIDS
00
Gasifier Ash Sluice Water
Element
Lead
Barium
Tin
Cadmium
Silver
Molybdenum
Strontium
Arsenic
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
Vanadium
Titanium
Calcium
Aluminum
Magnesium
Sodium
Boron
SSMS
0.008
0.1
<.001
<.002
0.001
0.1
4.0
0.009
0.05
0.01
0.02
<.002
0.5
0.005
0.009
0.02
0.05
>10
> 1
5
> 3
0.2
ICP
<.07
0.14
3.0
<.005
<.005
0.31
4.6
0.080
0.044
0.017
<.02
<.15
1.2
0.002
0.007
0.077
0.044
220
11
11
1720
4.6
Cyclone Dust
SSMS
0.02
0.002
<.001
<.001
<.002
<.004
2.0
0.05
0.06
0.02
0.08
0.009
2.0
0.005
0.01
0.02
0.06
>10
> 1
1
> 3
0.09
Quench Water
0.10
0.57
2.9
<.005
<.005
<.04
1.1
<.08
0.035
0.012
<.02
<.15
4.9
<.001
<.005
0.045
0.18
54
11
11
220
0.99
All values in ug/ml.
2SSMS: Spark Source Mass
Spectrometry.
Inductively Coupled Argon Plasma Emission
Spectrometry.
-------
TABLE 3-6. COMPARISON OF ICP1 AND SSMS2 DATA FOR SOLIDS
VD
Cyclone Dust
Lead
Barium
Tin
Cadmium
•>..*•
Silver
Molybdenum
Strontium
Arsenic
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
Vanadium
Titanium
Calcium
Aluminum
Magnesium
Sodium
Boron
SSMS
8
>1000
2
2
2
2
>1000
46
160
30
4
5
>1000
20
11
19
470
>1000
>1000
>1000
>1000
75
ICP
<87
2290 ± 25
<50
<6
<6
<50
1180 ± 10
<6
40 ± 6
<6
<25
<180
7730 ± 100
18 ± 4
<6
<12
310 ± 10
44000 ± 350
7100 ± 100
12200 ± 100
<6200
110 ± 5
Gasifier Ash
SSMS
5
>1000
0.5
0.8
0.6
15
>1000
9
20
81
75
23
>1000
170
100
410
>1000
>1000
>1000
>1000
>1000
320
ICP
<87
210 ± 10
1200 ± 20
<6
<6
50 ± 1
1290 ± 10
98 ± 1
15 ± 10
25 ± 8
67 ± 4
<180
30300 ± 200
64 ± 1
21 ± 1
<12
310 ± 7
48500 ± 400
19000 ± 100
12300 ± 100
<6200
210 ± 10
Product
SSMS
39
>1000
4
3
30
3
>1000
89
70
110
35
4
>1000
13
27
11
550
>1000
>1000
>1000
>1000
200
Gas Particulates
ICP
<87
2320 ± 10
<50
85± 3
NA
<50
1200 ± 10
<100
140 ± 6
76 ± 6
<33
<180
10300 ± 200
35 ± 2
40 ± 11
<13
290 ± 10
44900 ± 300
8370 ± 40
12200 ± 200
6350 ± 150
170 ± 5
All values in yg/g ± 2a
NA = Not Analyzed.
(where available)
SSMS: Spark Source Mass Spectrometry.
1ICP: Inductively Coupled Argon Plasma Emisssion
Spectrometry.
-------
TABLE 3-7. VOLATILE METAL COMPARISON
Stream
Cyclone Dust
Gasifier Ash
Product Gas
Particulates
Gasifier Ash
Sluice Water
Cyclone Dust
Quench Water
Method
AA
SSMS
ICP
AA
SSMS
ICP
AA
SSMS
ICP
AA
SSMS
ICP
AA
SSMS
ICP
Arsenic
64
46
<6
<6.5
9
98
77
89
<100
0.33
0.009
0.08
0.12
0.05
<0.08
Ant imony
<0.4
3
NA
2
<0.1
NA
<0.4
2
NA
<0.06
0.002
NA
<0.06
<0.001
NA
Selenium
13
5
NA
0.01
4
NA
15
3
NA
0.02
0.005
NA
0.03
0.006
NA
Mercury
2.1
NA
NA
0.39
NA
NA
2.6
NA
NA
0.0014
NA
NA
0.0004
NA
NA
As ppm, solids yg/g; liquids ug/ml.
NA: Not analyzed.
SSMS: Spark Source Mass Spectrometry.
ICP: Inductively Coupled Argon Plasma Emission Spectrometry.
AA: Atomic Absorption Spectrometry.
-------
For solids, the added extraction efficiency of ether is somewhat
variable as shown in Table 3-8. The greater percentages of added effi-
ciency correspond to TCO increases and, with the exception of the product
gas particulates, none of the solids would be expected to retain TCO
material. Since the product gas particulates were collected with an ESP at
140°C (285°F) instead of 200°C (400°F), some additional TCO material would
be anticipated. The added extraction efficiency on the GRAV portions
indicates that the particulates may have contained tarry material that was
more soluble in the ether.
Liquid samples show the widest range of variability for the added
extraction efficiency of ether. From the data in Table 3-9, there is no
real advantage to the ether extractions for TCO material. It is clear
though that the GRAV material recovery was enhanced by the ether extrac-
tion. From these data, following the methylene chloride extraction with
ether extraction is recommended for added recovery efficiency for both
solids and liquids.
Addition of an ether extraction step does not pose a problem for
the liquid chromatography solvent exchanges due to the high volatility of
ethyl ether. However, ether is often difficult to obtain at adequate
purity for extraction and greater than 100-fold concentrations. Distilled-
in-glass quality ether sometimes requires additional clean-up prior to use
due to the presence of ethyl acetate.
41
-------
TABLE 3-8. ADDED EXTRACTION EFFICIENCY USING ETHYL ETHER FOR SOLIDS
TCO
CH2C12
Gasifier Ash 18.5
(mg/kg)
Cyclone Dust 163
(mg/kg)
Test Burner Particulates 24.3
(yg/SCM)
Product Gas Particulates 1.13
(mg/SCM)
Product Gas Resin 2050
(mg/SCM)
SCM at 25°C (77°F) and 101 kPa (1 atm),
A MO* pf«^n«n« <"M ™ Ether Extractable
GRAY
Et20 CH2C12 Et20
2.57 526 38
60.2 1110 820
8.43 647 333
0.31 182 57.5
24 290 13
dry basis.
Mass ,^
Added
TCO
12%
28%
26%
21%
1%
Efficiency
GRAY
7%
7%
34%
24%
4%
Total Extractable Mass
-------
TABLE 3-9. ADDED EXTRACTION EFFICIENCY USING ETHYL ETHER FOR LIQUIDS
pH=2 pH=12
CH2C12 Et20 CH2C12 Et20
TCO. (in mg/1)
Gaslfier Ash 4.16 ND 9. 38 0.17
Sluice Water
Cyclone Dust ND ND 3.31 ND
Quench Water
GRAV (in mg/1)
Gasifier Ash 63.2 44.5 ND 4.3
Sluice Water
Cyclone Dust 23.2 14.6 12.2 2.6
Quench Water
Added Efficiency
pH=2 pH=12
0% 2%
0%
41% 100%
39% 18%
ND - less than 0.001 mg/£ detected.
LAA*A vff^i^^r ti\ - Ether Extractable Mass _ 100
Total Extractable Mass
-------
3.3 DETAILED ORGANIC ANALYSIS APPROACH
The fundamental objective of the detailed organic analysis
approach followed on this project was the generation of data for process
and effluent streams which would allow an assessment of the potential
environmental and health effects of a stream by comparison to the dis-
charge multimedia environmental goals (DMEG) for specific compounds (Ref.
4,5, and 6). To achieve this objective In the most comprehensive manner
for specific organic compounds would be extremely expensive. Therefore a
phased logic sequence was followed to provide a means of prioritizing
streams, fractions within each stream, and classes of compounds and spec-
ific compounds within each fraction. The logic sequence was intended to
utilize techniques to eliminate as many compounds as possible from consid-
eration in the compound-specific detailed analysis by insuring that they
are not present at concentrations greater than their respective DMEG
values.
The data from the preliminary screening analysis were used to
eliminate from consideration as many classes of compounds or specific
compounds for which DMEG values were available prior to the detailed
analysis. This step simultaneously reduced the scope of the detailed
analysis and prioritized the samples on the basis of weighted discharge
severity (WDS) for further analysis. The decision criteria were based on
worst case DMEG values for specific compounds which were potentially
present.
The logic sequence implemented contained these decision elements:
1. With all available information about the stream such as
process data, on-site analysis results, ultimate and
proximate analyses, can any possible reduction in DMEG
compounds or classes of compounds be made?
2a. With the determination of extractable organic content by
total chromatographable organics (TCO) and gravimetric (GRAV)
content, can any reduction be made on the basis of a
Discharge Severity <1?
2b. With the infrared analysis data, can a reduction of compound
classes be made on the basis of key functional group absence?
3. After fractionation of a sample by a separation scheme for
which there are established relationships between compound
classes and individual fraction, do the TCO and GRAV deter-
minations in conjunction with the predicted compound class/
fraction relationship reduce the number of compounds of
concern?
44
-------
4. On the basis of the infrared analysis for each LC fraction,
can an elimination of compound classes be made? Must other
compound classes not predicted by the LC relationship be
introduced into consideration?
5. If the preceding decision criteria eliminate the possibility
of hazardous materials, do the bioassay results indicate that
a hazard not covered by the DMEG listings is present?
This phased logic sequence is presented graphically in Figure 3-6.
The detailed organic analysis approach implemented here was
compound specific only for those compounds in the DMEG listings.
Prioritization was done on the worst case basis which meant that the
calculated total organic loading for a sample or an LC fraction was all
assumed to be the specific compound having the lowest DMEG value in each
predicted category. The specific analysis focused on:
• quantification of the first priority compound,
• calculating a new prioritization in case the second worst
compound in that category might have a higher priority than
the first priority compound from the next compound category
of interest, and
• quantification of the next priority compound.
The necessary ranking between samples was done on a flow rate
weighing, so the actual analysis prioritization was based on weighted
discharge severity, where:
dctot
- DS
DMEG
and,
DS x mr - WDS.
where:
dctot • discharge concentration of the measured total
organic loading as the sum of ICO and GRAV
45
-------
'PROCESS
STREAM
SAMPLE,
PROCESS DATA ON-SITE
ANALYSIS, PROXIMATE,
ULTIMATE
STEP 1
STEP 2
ELIMINATE COMPOUNDS
IDS
-------
DMEG • discharge multimedia environmental goal, used here
as the appropriate worst case value for each classs of
compounds
DS = discharge severity
mr - mass flow rate of the stream analyzed
WDS = weighted discharge severity for each stream analyzed
3.3.1 Specific Ion Monitoring GC/MS
The method chosen for the detailed analysis was specific ion
monitoring (SIM) gas chromatography/mass spectrometry (GC/MS). With this
technique, the appearance of characteristic compound specific ions is
monitored within known retention time windows for the compound of interest.
In order to get confirmation for the designate compound:
• the primary ion must be present,
• the secondary ion must be present,
• both ions must be maximized at the correct retention
time for the designated compound.
In as many cases as possible, standards of the designated com-
pounds were obtained and their mass spectra and retention times were veri-
fied prior to analysis. Compounds for which no standards were available
were monitored on the basis of characteristic ions from the literature
during the entire mass spectrometer run time. An example of the specific
ion monitoring technique is given in Figure 3-7, which shows a SIM GC/MS
analysis for benzo(b)fluoranthene. The figure shows both the more intense
primary ion, m/e - 252, and the secondary ion, m/e » 250, maximized at 35.0
minutes which was the established retention time for benzo(b)fluoranthene.
Since all three confirmation criteria were met, the probability of correct
identification was enhanced. The instrumental parameters for this analysis
are given in Appendix C.
Specific ion monitoring GC/MS was chosen as the primary detailed
analysis technique because it generates compound specific information which
is required to implement the analysis approach concept. To obtain the same
degree of compound specific information from a scanning GC/MS analysis,
every peak in the total ion plot would have to be identified. The effort
required for the identification of all the compounds eluting from the GC
column would be prohibitive in this source test and evaluation program.
47
-------
258*0
350.0
TI
TOTAL ION PLOT
PRIMARY ION
SECONDARY ION
i — i — r n — i — r -r
30 35
(minutes)
T- i—r
40
Retention
Time:
25
Figure 3-7 . Specific Ion Monitoring Plot for Benzo(b)fluoranthene
-------
To identify the major components of a GC/MS scan gives a better overall
view of the process stream components, but does not address the problems of
extremely hazardous compounds present at very low concentrations as does
SIM GC/MS. Low resolution mass spectrometry using the direct probe for
sample injection also gives a better overall view of the process stream
than SIM GC/MS, but has specificity deficiencies.
3.3.2 Halogen Specific Gas Chromatography
As an adjunct to the detailed analysis technique, a halogen-
specific analysis was done prior to SIM GC/MS. This analysis was designed
to give quantitative information about the compounds and classes of com-
pounds that contain halogen moieties, since halogenated organic compounds
are among the most hazardous in the DMEG listings. Aliquots of the unfrac-
tionated samples were analyzed by gas chromatography using a Hall electro-
lytic conductivity detector in the halogen-specific mode according to the
procedure given in Appendix C.
3.4 QUALITY ASSURANCE
To provide quality assurance for the on-site analyses, certified
gas standards and standard solutions were analyzed during the sampling
effort. Also, GC samples were analyzed in duplicate on-site. During the
on-site sampling, an evaluation of the affect the electrostatic precipi-
tator had on the gas stream composition was made. No trends or indications
of sample degradation were observed. The planned evaluation of trace
element train collection efficiencies was not conducted due to process
operational difficulties.
The samples which were not analyzed on-site were preserved
according to the recommended procedures (Ref. 3). Liquid samples that had
short lifetimes were returned for laboratory analysis within the preserva-
tion time limits. All samples were logged on-site and the log data entries
were cross-verified upon receipt in the laboratory. The on-site log is
presented in Appendix B of this document.
Solvent blanks, impinger solution blanks, and blank XAD-2 resin
were analyzed in the laboratory and included in the appropriate subcon-
tracted analyses. LC columns were run using a blank XAD-2 resin extract
and solvent blanks from designated solvent lots. The same solvent lots
were used throughout the organic analysis, and blanks were analyzed by IR
as well as TCO and GRAV. TCO blanks were analyzed within each set of TCO
determinations. An infrared spectrum of the blank XAD-2 resin extract is
given in Appendix D for purposes of comparison with the infrared spectrum
of XAD-2 sample extracts.
49
-------
The EPA Water Quality control sample #3 was analyzed by ICP to
provide the accuracy data for the method. Table 3-10 presents the com-
parison of the reported value and the Radian ICP value. Most values were
within experimental errors. Arsenic and lead were above the prescribed
level. This is due to the misalignment of the analytical lines of these
elements on the present instrument.
Prior to the thermal desorption GC/MS analysis of the Tenax trap,
a blank run was made to assure that no instrument contamination was pre-
sent. Hexadeuterobenzene was used as an internal standard for the thermal
desorption GC/MS analysis, and diQ-anthracene was used as the internal
standard for the SIM GC/MS quantification.
50
-------
TABLE 3-10. COMPARISON OF RADIAN ICP DATA AND REPORTED VALUES
FOR EPA WATER QUALITY CONTROL SAMPLE #3
Element
Aluminum
Arsenic
Cadmium
Cobalt
Chromium
Copper
Iron
Manganese
Lead
Vanadium
Zinc
Reported yg/ml
0.904
0.154
0.073
0.396
0.209
0.102
0.678
0.397
0.352
0.157
0.174
Radian yg/ml
1.15
0.301
0.083
0.547
0.238
0.114
0.760
0.425
0.546
0.186
0.206
51
-------
SECTION 4
RESULTS
An overview of the Source Analysis Model/lA results, the bioassay
results, and the analytical results is contained in the following sections.
Detailed tabulations of all data produced are provided in the appendices.
4.1 Source Analysis Model/lA Results
The Source Analysis Model/lA (Ref. 7) was used to provide a rapid
screening technique for identifying and prioritizing potentially harmful
waste streams. Major simplifying assumptions implicit in the use of the
Source Analysis Model/lA (SAM/1A) methodology are:
• The substances currently in the Multimedia Environmental
Goals (MEG) lists (Ref. 4, 5 and 6) are the only ones that
must be addressed at this time (the MEG's are currently being
updated to include new data, account for new or revised
standards, and add new compounds).
• Transport of the components in the waste streams to the
external environment occurs without chemical or physical
transformation of those components.
• Actual dispersion of a pollutant from a source to a receptor
will be equal to, or greater than the safety factors normally
applied to acute toxiclty data to convert these data to
estimated safe chronic exposure levels.
• Discharge Multimedia Environmental Goals (DMEG) values (Ref.
4, 5, and 6) developed for each substance are adequate for
estimating acute toxlcity. A DMEG is a concentration of a
substance estimated to cause an adverse effect in a
health receptor exposed once or intermittently for short
periods. It relates either to human health or ecological
effects.
• The waste stream components cause no synergistic effects.
These assumptions, along with the accuracy of the test data and assumptions
used in developing DMEG values, must be considered when interpreting test
results using a SAM/1A analysis scheme.
In addition to the assumptions inherent in the SAM/1A, the
summarized SAM/1A results given are based on these postulates:
• All streams are treated as if they were emission streams, and
the flow rates are used for weighted discharge severity (WDS)
calculations.
52
-------
• The compounds or elements identified by a specific method
preempt any screening results such as SSMS or LC.
• The maximum potential concentration of an organic compound
not specifically identified is taken as the sum of the TCO
and GRAV concentration of the established LC fraction.
The SAM/1A results calculated at the end of the organic screening
analysis were used to prioritize LC fractions for specific ion monitoring
(SIM) GC-MS. Using the established correlation between LC fractions and
organic categories in the MEG listings (Ref. 8), the categories that could
be present in each fraction were determined. Potential worst case weighted
discharge severity (WDS) factors were then calculated for each LC fraction
by assuming that the total organic loading (TCO + GRAV) is present as the
worst case compound (smallest DMEG value) in the categories potentially
present. These worst case weighted discharge severity factors were as
shown in Figure 4-1. The detailed analysis then focused on those organic
compounds potentially present which would generate WDS factors from 10*0
to 10^. Utilizing this approach exerted a leveling effect on the
resulting WDS factors.
The actual concentrations of specific organic compounds, as
determined by SIM/GC-MS during the detailed analysis, were significantly
less than the maximum potential concentration. The highest specific WDS
for any stream, calculated from measured concentrations of specific com-
pounds, is less than 108. The SAM/1A results given in the Tables (4-1 to
4-14) are for the highest WDS factors from each stream and include both
experimentally verified compounds and remaining worst case assumptions.
The summations of these WDS factors to give total WDS for each stream are
given in Table 4-15 for both the health and ecological effects. The
analogous discharge severity (DS) summations are also given in the table.
Further expenditure of effort to eliminate the remaining worst case
assumptions could lower these WDS and DS factors even more.
53
-------
10
It—
It
10 -
io»-
CO
60
~ 10'-
to
Id
of ios—
to
Q 10s-
ios-
io2-
10°
LC 1234567
FRACTION
Product Gas
Particulate
1234567
1234567
Product Gas Organic Tes;t Burner Composite
Module
1234567
Gasifier Ash
123456
Cyclone Dust
FIGURE 4-1. Worst Case Weighted Discharge Severity Summary
Based on Screening Analysis Results Only
-------
NOTES FOR THE FOLLOWING TABLES: 4-1 to 4-14
P = compound is on Priority Pollutant List
V = compound is the worst case within the appropriate
matrix for that category/subcategory
T = concentration is total organic loading (TCO + GRAV)
for the LC fraction
S = concentration is from SSMS
D = concentration is determined experimentally; from
on-site analysis, SIM-GC/MS, Anion/Cation analysis
ICP or AAS
Cone = concentration in yg/SCM at 25°C (77°F) and 101 kPa
(1 atm) dry basis, for gases; yg/1 (ppb) for liquids;
and yg/g (ppm) for solids
WDS = units are g/s for all streams
LCCAT = established LC fraction if applicable
* = indicates that the compound appears more than once
in the listing, i.e. in more than one LC fraction
55
-------
TABLE 4-1. PRODUCT GAS PARTICULATE/TAR MAJOR CONTRIBUTIONS TO DS AND
WDS FOR HEALTH EFFECTS INCLUDING WORST CASE ASSUMPTIONS
Ul
ON
OMEC
oa
04
10
to
to
10
12
10
20
20
20
21
02
10
10
10
10
19
13
10
23
10
13
10
10
10
23
12
Ot)
10
08
06
06
06
B
B
C
C
C
C
A
C
B
B
B
C
B
C
C
C
C
A
A
C
C
C
A
C
C
C
C
A
A
C
A
A
A
C
NO.
020* P H
020* P H
100*
043*
Oil*
042*
040* P
220*
04|*
020* P M
042*
100* P H
140* P M
062*
063*
060*
OBI*
060* P H
100* H
200*
160* H
100*
140*
042*
043*
041*
160* H
040* P
122*
140* P
121*
123*
120* w
060* w
PHOOUCT CAS PARTICIPATE, HEALTH IMPACT
COMPOUND NAME 1VPE CONC
E-6 G/SCM
1,1'-D1CHLOROME,THYL ETHER
Itl'-DICHLOROMETHYL ETHER
1,4-UIAHINOBENZENE
4-AMINOTOLUENE
2-AMINOTOLUENE
3-AMINOTOLUENE
N-NITR030DIETHVLAMINE
2-AMINONAPHTHALENE
3.5-D1NIT80-P-CRESOL
4,6-DINITHO-O-CRESOL
2.b-DINITKO-P-CRESOL
BENZO(A)PYRENE
HEXACHLOKOCYCLOPENTADIENE
M-ANISIDINE
P-ANISIDINE
ANISIDINES
0-ANISIDINE
PENTACHLOROPHENOL
BENZENETHIOL
1-AMINONAPHTHALENE
OlbENZO(CiG)CARBA20LE
1,4-DIAMIHOBENZENE
PERCHLGROMETHANETHIUL
3-AMINOTOLUENE .
4-AMINOTOLUENE
2-AMINOTOLUENE
DIb£NZO(C,GKARBAZOLE
N-NITROSOD1ETHYLAMINE
PALMITIC ACID
BENZIOINE
MYRISTIC ACID
STEAHIC ACID
SATURATED LONG CHAIN ACIDS (MN|226-26S)
b-HEXANELACTAM
T
T
T
T
0
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
4.9UE
4.10E
3.60E
3.60E
3.60E
3.60E
3.bOE
3.60E
3.bOE
3.bOE
i.bOE
1.90E
B.70E
3.60E
3.bOE
3.60E
3.bOE
3.60E
3,b«E
3.60E
4.90E
4.90E
3.buE
4.90E
4.90E
4.90E
4. 10E
4.90E
3.60E
3.bOE
3.60E
1.60E
3.60E
3.60E
Ob
OS
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
02
05
Ob
Ob
Ob
Ob
Ob
Ob
Ob
OS
OS
Ob
05
OS
OS
05
05
Ob
Ob
Ob
Ob
Ob
Ob
DS
9.BOE
B.20E
3.bOE
3.30E
3.30E
3.30E
3.00E
2.11E
I.BOE
I.BOE
I.60E
9.50E
7.90E
7.20E
7.20E
7.20E
7.20E
7.20E
7.20E
b.42E
4.90E
4.90E
4.50E
4.50E
4.50E
4.50E
4.10E
4.10E
3.60E
J.60E
3.60E
3.60E
3.60E
3.60E
04
04
04
04
04
04
04
04
04
04
04
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
HD3
G/S
S.BOE
4.B3E
2. 12E
1.93E
1 .93E
1.V3E
t.BOE
1.24E
1.10E
l.lOt
1.10E
5. tot
4.70E
4.24E
4.24E
4.24t
4.24E
4.24E
4.24E
3.BOE
2.90E
2.90E
2.70E
2.b2E
2.b2E
2.b2E
2.41E
2.40E
2.12E
2.12E
2.12E
2.12E
2. 12E
2.12E
07
07
07
07
07
07
07
07
07
07
07
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
Ob
06
Ob
Ob
LCCAT
S
-------
TABLE 4-2. PRODUCT GAS PARTICULATE/TAR MAJOR CONTRIBUTIONS TO DS AND
WDS FOR ECOLOGICAL EFFECTS INCLUDING WORST CASE ASSUMPTIONS
OMEG
83
IS
IS
IS
65
15
01
01
16
22
21
16
21
22
21
21
21
21
21
17
21
21
03
09
25
09
12
10
oa
20
20
23
23
23
A
A
A
A
A
A
B
B
A
C
c
A
B
C
B
B
C
0
C
B
B
C
B
A
B
B
A
C
B
A
B
B
B
B
NO.
010
120*
040*
120*
010
040*
080
060
220*
080*
too*
220*
060*
oao*
too*
060*
100*
040*
000*
040
000*
oao*
060
120
040
020
020*
040*
060*
120*
040*
too*
220*
240*
PRODUCT CAS PARTICULAR, ECOLOGY IMPACT
COMPOUND NAME TYPE CONC
E-6 G/SCM
P
P
P
P
P
P
P
P
P
P
MERCURY
ISOPROPYL BENZENE
TOLUENE
ISOPROPYL BENZENE
VANADIUM
TOLUENE
BUTADIENES
BUTYLENES
POLYCHLOR1NATED BIPHENYLS
BENZO(B)FLUORANTHENE
BENZO(A)PYRENE
POLYCHLORINATED BIPHENYLS
1, 12-DIMETHYLBEN2UJANTHRACENE
BENZO(B)FLUORANTHENE
BENZO(C)PHENANTHRENE It ALKYL DERIVATIVES
7, 12-OIMETHYLBENZ(A)ANTHRACEN£
BENZO(A)PYRENE
DIBENZO(A,I)PYHENE
DIBENZ(A,H)ANTHRAC£N£
l-CHLORO-2-NITROBENZENE
3-METHYLCHOLANTHHENE
DIBENZ( A, H) ANTHRACENE
2-£THYL-4-METHYL-l,3-OIOXOLANE
TETRAMETHYLSUCCINONITMILE
B£NZO(B)THIOPHENE
BENZONITRILE
N-NITKOSODIMETHYLAMINE
AMINOTOLUENES
B-PROPIOLACTONE
2,4,6-TRlNITROPHENOL
OINITRO-P-CRESOLS
DIHYDROACRIOINE
DIBENZ(A,J)ACKIDINE
UIBENZ(A,H)ACRIDINE
0
T
T
T
S
T
T
T
0
0
0
0
D
0
0
0
0
0
0
0
0
D
0
0
D
0
0
0
D
D
0
D
D
D
6
6
6
a
3
a
8
a
< 7
1
0
0
1
3
0
0
1
0
6
0
0
0
0
0
0
0
0
0
0
0
a
2
0
0
.50E 03
.aoE 05
.BOE 05
.90E 04
.60E 01
.90E 04
.70E 05
.70E 05
.60E 00<
.OOE 01
.OOE-01
.OOE-01
.60E 02
.70E 02
.OOE-01
.OOE-01
.90E 02
.OOE-01
.10E 00
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.40E 02
.30E 01
.OOE-01
.OOE-01
6.
OS
50E 02
5.70E 02
1.50E 02
7.
3.
1.
4.
3.
0.
0.
0.
0.
0.
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
41E 01
60E 01
V3E 01
OOE-01
bOE-02
OOE-01<
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
NDS
G/S
3.83t 05
3.34E 05
8.72t 04
4.40E 04
2.12E 04
I.l4t 04
2.33E 02
2.23t 01
o.oot-oi
O.OOE-01
O.OOt-01
O.OOt-01
0. OOE-01
O.OOt-01
O.OOt-01
O.OOt-01
o.oot-oi
O.OOE-01
O.OOt-01
O.OOt-01
o.oot-oi
O.OOt-01
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
O.OOt-01
O.OOE-01
O.OOt-01
O.ooE-oi
o.oot-oi
O.OOE-01
o.oot-oi
O.OOt-01
LCCAT
3
3
2
2
1
1
2
2
2
3
3
3
2
2
3
2
3
4
2
2
4
4
4
4
5
5
5
5
5
S
5
S
-------
TABLE 4-3. PRODUCT GAS ORGANIC MODULE MAJOR CONTRIBUTIONS TO DS AND WDS FOR HEALTH
EFFECTS INCLUDING WORST CASE ASSUMPTIONS
OMEG NO.
PRODUCT «A3 ORGANIC NODULE COMPOCITt* HEALTH IHPACT
COMPOUND NAME
TYPE CONC OS
E-fc WSCH
H03
G/3
LCCAT
ui
00
04 B
04 B
02 B
12 A
08 B
42 A
20 A
10 C
10 C
10 C
10 C
10 C
12 A
10 C
23 C
10 C
10 C
10 C
12 A
23 B
10 C
20 B
20 B
20 B
20 B
10 C
23 B
02 A
14 B
21 B
21 B
21 B
21 B
21 B
020*
020*
140*
020*
060*
070
120*
too*
040*
043*
042*
041*
040*
100*
160*
041*
043*
042*
040*
100*
220*
042*
041*
020*
040*
220*
240*
3t»0*
020
106*
102*
103*
106*
107*
P H
P M
P N
P H
N
M
P
M
P
H
P H
H
H
H
1,1'-DICHLOROM£THYL ETHfcR
Itl'-DICHLOROMETHVL ETHER
HEXACHLOROCYCLOPENTADlEHE
N-NltROSODlMETHYLAHlNE
B-PROPIOLACTONE
CARBON MONOXIDE
2,4,6-TRINITROPHENOL
1,4-DIAHINOBENZENE
AMINOTOLUENES
4-AMINOTOLUENE
3-AMINOTOLUENE
2-AMINOTOLUENE
N-NITROSODIETHYLAHINE
1,4-DIAHINOBENZENE
OIBENZO(C,G)CARBAZOLE
2-AMINOTOLUENE
4-AMINOTOLUENE
3-AMINOTOLUtNE
N-NITKOSODIETHYLAMINE
01HYDROACRIOINE
2-AMINONAPHTHALENE
2,6-OlNlTRO-P-CRESOL
3»5-DINITRO-P-CRESOL
4r6-DINITRO-0-CR£SOL
OINITRO-P-CKESOLS
2-AMINONAPHTHALENE
DIBENZ(A,H)ACRI01NE
HEXACHLOROCYCLOHEXANE
DIMETHYL SULFOXIOE
7-METHYL BENZO(C)PHENANTHHENE
1-METHYL B£NZO(C)PHENANTHKENE
2-HETHYL BENZOCOPHENANTHRENE
2-ETHYL BENZOCOPHENANTHRENE
8-HETHYL BENZOCOPHENANTHRENE
T
T
T
T
T
0
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
5.7»E
1.30E
1.60E
7.10E
2
3
7
7
7
7
7
7
7
5
S
5
S
5
S
7
7
7
7
7
7
5
7
1
2
6
6
6
6
6
.SOE
.OOE
. 10E
.10E
. 1UE
.10E
.10E
.10E
. 10E
.70E
.70E
.70E
.70E
.70E
.70E
.10£
.10E
.10E
.10E
. 10E
.JOE
.70E
.10E
.60E
.SOE
.60E
.60E
.6UE
.60E
.60E
Ob
OS
06
05
06
08
OS
OS
OS
OS
05
OS
05
05
05
OS
05
OS
OS
05
OS
OS
OS
OS
OS
OS
OS
06
06
05
05
OS
05
OS
1.14E
2.60E
1.50E
1.10E
7.81E
7. SOE
7.
7.
6.
6.
6.
6.
S.
S.
5.
5.
S.
5.
4.
4.
4.
10E
10E
SOE
SOE
SOE
SOE
91E
70E
70E
20E
20E
20E
BOE
43E
2UE
3.60E
3.60E
3.60E
3.60E
3.
3.
3.
3.
3.
3.
3.
3.
3.
40E
22E
20E
10E
OOE
OOE
OOE
OOE
OOE
OS
04
04
04
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
6.72E
1.S3E
8.60E
6.44E
4
4
4
4
3
3
3
3
3
3
3
3
3
3
2
2
2
2
2
2
2
2
•
•
•
*
•
•
•
•
•
•
•
•
•
•
60E
42E
20E
20E
BOE
dot
BOE
80E
sot
40E
40£
lot
10E
IOC
.aoE
9
ME
.SOE
•
•
•
•
*
•
•
.
•
•
•
•
•
10E
10E
10E
10E
OOE
90E
VOE
B2E
aot
aoE
BOE
ao£
aoE
07
07
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
S
4
1
6
7
6
6
6
6
6
6
6
5
5
5
5
5
5
6
6
6
6
6
6
5
6
1
7
3
3
3
3
3
-------
TABLE 4-4. PRODUCT GAS ORGANIC MODULE MAJOR CONTRIBUTIONS TO DS AND WDS
FOR ECOLOGICAL EFFECTS INCLUDING WORST CASE ASSUMPTIONS
vo
OMEG
01
17
42
15
IS
15
47
01
65
01
ai
01
01
IS
01
01
15
S3
25
Hi
53
S3
21
21
21
21
IS
21
21
22
Ib
IS
21
16
B
A
A
A
A
A
A
A
A
B
A
b
A
A
A
A
B
A
A
A
A
A
B
B
D
B
A
B
C
C
A
A
B
A
NO.
020 H
060 P
070
120*
120*
020 P
oao P
020 H
010
otto
010 P
060
040
040 P
060
oao
060
060
020
oao
060
100
040* P
060*
040*
too*
060 P
oao*
oao* P
080* P
220*
160
040* P
220*
PRODUC1 GAS ORGANIC MODULE COMPOSITE* ECOLOGY IMPACT
COMPOUND NAME TYPE CONC
E-6 G/SCM
EWLENE
AMMONIA
CARBON MONOXIDE
I80PROPYL BENZENE
I30PROPYL BENZENE
BENZENE
HYDROGEN CYANIDE
METHANE
VANADIUM
BUTADIENES
MERCURY
BUTVLENES
ETHANE
TOLUENE
PROPANE
BUTANES
XYLENES
CARBONYL SULFIDE
THIUPHENE
CARBON DIOXIDE
SULFUR DIOXIDE
CARBON DISULFIDE
BENZ(A)ANTHRACENE
7, 12-OIMETHVLBENZU) ANTHRACENE
DI8ENZO(A,I)PYHENE
BENZO(C)PHENANTHHENE I ALKYL DERIVATIVES
ETHYL BENZENE
3-METHYLCHOLANTHHENE
OIBENZ(A,H)ANTHRACENE
BENZO(B)FLUORANTHEN£
POLYCHLOHINATED UIPHENYLS
BIPHENYL
BENZ(A)ANTHRACENE
POLYCHLOR1NATED BIPH£NYLS
D
0
D
T
T
D
D
D
S
t
L>
T
D
D
D
D
D
D
D
0
D
D
D
0
D
D
0
D
D
D
D
0
D
D
3.6UE OS
1
.10E 07
3. DUE 06
6
2
> 1
2
b
9
1
3
1
7
2
a
4
4
3
1
t
4
3
8
0
0
0
3
0
0
0
0
S
1
< 7
.60E OS
.3UE 05
.30E 04>
.22E OS
.30E 06
.20E-01
.60E 06
.3UE 00
.60E 06
.90E OS
.60E 02
.ODE OS
.60E 05
.80E 01
.51E OS
.90E 03
.71E Ott
.20E 04
.73E 04
.10E 00
.OOE-01
.OOE-01
.OOE-01
.90E 01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE 03
.40E 02
.20E 00<
DS
3.60E OS
3.03E 04
2.SOE 03
S.
1.
1.
6.
9.
9.
7.
3.
7.
6.
5.
4.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
SOE 02
91E 02
eoE oi>
S2E 00
64E-OI
20E-01
30E-01
JOE-01
OOE-02
60E-02
70E-02
44E-02
90E-02
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-OK
NDS
li/S
LCCAT
2. HE 08
l.BOE 07
I.SOE 06
3.
1.
1.
3.
5.
S.
4.
1.
4.
3.
3.
2.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
24E 05
13E OS
10E 04
90E 03
70t 02
42E 02
30E 02
94E 02
10E 01
90E 01
33E 01
62E 01
12E 01
OOfc-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOt-01
OOE-01
OOE-01
OOE-01
3
2
1
1
2
-------
TABLE 4-5. TEST BURNER FLUE GAS MAJOR CONTRIBUTIONS TO DS AND
WDS FOR HEALTH EFFECTS INCLUDING WORST CASE ASSUMPTIONS
TEST BURNER FLUE CAS COMPOSITE* HEALTH IMPACT
OMEG NO.
COMPOUND NAME
TYPE CONC US
E-6 G/SCM
HDS
LCCAT
21 C
21 C
04 B
16 A
49 A
68 A
21 B
12 A
04 B
20 A
10 C
S3 A
10 C
10 C
10 C
10 C
12 A
23 B
10 C
21 B
20 B
20 B
20 B
20 B
42 A
21 B
23 B
23 B
02 B
12 A
08 B
20 A
10 C
23 C
100*
oao*
020*
220*
010
010
oao*
020*
020*
120*
too*
060
0(10*
0'43*
041*
042*
040*
100*
220*
oeo*
042*
041*
020*
040*
oeo
040*
240*
220*
140*
020*
060*
120*
too*
160*
P
P
P
P
P
P
P
P
P
P
P
P
M
M
M
M
M
M
H
M
M
H
H
W
M
N
B£NZOlA)PYRtNE
DIBENZC A, H) ANTHRACENE
1,1«-OICHLORONETHYL ETHER
POLYCMLORINATED BIPHENYLS
ARSENIC
CHROMIUM
3-METHYLCHOLANTHRENE ,
N-NITROSODIHETHYLAMINE
Ir I'-OICHLOROMETHTL ETHER
2» 4 , 6-TR IN I TROPHENOL
1,4-DIAMINObENZENE
SULFUR DIOXIDE
AMINOTOLUENES
4-AMINOTOLUENE
2-AHINOTOLUENE
3-AMINOTOLUENE
N-NITROSOOIETHYLAHINE
DIHVDROACfUOINE
2-AMINONAPHTHALENE
3-METHYLCHOLANTHRENE
2»6-DlNITHO-P-CR£SOL
3r5-OINITRO-P-CR£SOL
4,6-DlNITRO-O-CRESOL
DINITRO-P-CRESOLS
CARBON DIOXIDE
B£NZ(A)ANTHMACEN£
DIBENZ(A,H)ACRIDIN£
DIBENZ(A,J)ACRIOINE
HEXACHLOROCYCLOPENTADIENE
N-NITR030UI METHYL AMINE
8-PROPIOLACTONE
2, 4 f *-TR IN I TROPHENOL
1 , 4-01 AMINOBENZENE
DIBENZO(C»G)CARBAZOLE
T
T
T
T
D
S
T
T
T
T
T
0
T
T
T
T
T
T
T
T
T
T
T
T
D
D
T
T
T
T
T
T
T
T
4.40E
4.40E
4. TOE
4.40E
B.60E
3. TOE
1.30E
2.20E
1.30E
2.20E
2.20E
2. TOE
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
4.40E
2.20E
2.20E
2.20E
2.20E
9.80E
4.SOE
2.20E
2.20E
a.eoE
4. TOE
2.20E
4. TOE
4. TOE
4. TOE
01
01
02
01
01
01
02
03
02
03
03
05
03
03
03
03
03
03
03
01
03
03
03
03
OT
02
03
03
02
02
03
02
02
02
2.20E 03
4.T3E 02
9.40E 01
4.40E 01
4.30E 01
3. TOE 01
3.42E 01
3.40E 01
2.60E 01
2.20E 01
2.20E 01
2.10E 01
2.00E 01
2.00E 01
2.00E 01
2.00E 01
1.83E 01
1.40£ 01
1.30E 01
1.20E 01
l.iOE 01
1.1 OE 01
1.1 OE 01
1.10E 01
1.1 OE 01
l.OOE 01
l.OOE 01
8.80E 00
8.00E 00
T.23E 00
6.90E 00
4. TOE 00
4. TOE 00
4. TOE 00
1.80E
3.B2C
T.60E
3.60E
3. SOt
3.00E
2.80E
2.T3E
2. lot
l.BOE
l.BOt
1.70E
1.61E
1.61E
1.61E-
1.61E
1.SOE
l.llt
1.04E
9.40E
B.90E
B.90E
B.90t
8.90t
e.eoE
B.10E
a. lot
T.ue
6. SOt
5.04E
5.60E
3.80E
3.80E
s.eot
OT
06
05
OS
05
OS
OS
05
OS
OS
OS
OS
05
05
OS
OS
05
OS
05
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
3
3
5
3
2
6
4
6
6
6
6
6
6
6
6
6
3
6
6
6
6
2
6
6
1
S
6
S
5
S
-------
TABLE 4-6. TEST BURNER FLUE GAS HAJOR CONTRIBUTIONS TO DS AND WDS FOR
ECOLOGICAL EFFECTS INCLUDING WORST CASE ASSUMPTIONS
DMEG
65
• 1
IS
IS
47
47
IS
15
42
S3
16
01
01
01
01
21
21
21
21
54
01
01
37
56
62
34
• 4
31
57
68
74
76
56
39
A
A
A
A
A
A
A
A
A
A
B
B
C
C
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
NO.
010
010
120*
120*
000
060
040*
040*
060
060
220
060
060
100
140
040*
060
080*
too*
010
020
040
010
010
010
010
010
010
010
010
010
010
010
010
TE8I HUWR FlUf 9*1 COMPOSITE* ECOLOGY IMPACT
COMPOUND NAME TYPE CONC
E-6 G/3CM
p
p
p
p
p
p
p
p
p
H
p
p
p
VANADIUM
MERCURY
ISOPROPYL BENZENE
IS0PROPYL BENZENE
HYDROGEN CYANIDE
AMMONIA
TOLUENE
TOLUENE
CARBON DIOXIDE
SULFUR DIOXIDE
POLYCHLORINATED BIPHENVL8
PROPANE
BUTANES
PENTANES
HEXANES
BENZ(A)ANTHRACENE
7> 12-OIMETHYLBENZUJANTHRACENE
DIBENZt A, H) ANTHRACENE
BENZO(A)PYRENE
SELENIUM
METHANE
ETHANE
BORON
BROMINE
CADMIUM
CALCIUM (A3 CA+2)
CERIUM
CESIUM
CHLORINE (AS CL-)
CHROMIUM
COBALT
COPPER
FLUORINE (AS F-)
GALLIUM
8
D
T
T
D
D
T
T
0
D
D
D
D
D
0
D
D
D
0
D
D
0
8
8
8
a
8
8
8
8
8
8
8
8
3
1
1
4
1.
< 1
1,
4,
9,
2.
0,
0,
0,
0
0
4
0
0,
0
< 1.
0,
0,
4,
4,
> 2,
> 7,
6,
1.
3.
3,
t.
9.
1.
« t.
,60E 00
,60E 01
.30E 02
,40E 01
,02E 03
,OOE OK
,30E 02
,40E 01
60E 07
70E 05
OOE-01
OOE-01
OOE-01
.OOE-01
•OOE-01
.50E 02
.OOE-01
.OOE-01
.OOE-01
,30E 02<
OOE-01
OOE-01
OOE 00
40E-OI
OOE-01>
60E 02>
20E-01
IDE oo
30E 01
70E 01
30E 02
30E 00
OOE 02
30E 00<
3
1
1
3
3
2
2
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
08
.60E 00
.60E 00
.10E-01
.70E-02
.02E-02
.90E-02<
.«2E-02
.60E-03
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-OK
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01>
.00£-OI>
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-OK
ND8 LCCAT
G/S
2.VOE 04
1.30E 04
B.eoE 02
3. OOE 02
2.44E 02
2.30E 02
2.30E 02
7.72E 0|
O.OOt-01
O.OOt-01
O.OOt-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOt-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOt-01
O.OOt-01
O.OOt-01
O.OOE-01
o.oot-oi
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOfc-01
O.OOE-01
2
3
2
3
2
2
2
2
2
-------
TABLE 4-7. GASIFIER ASH MAJOR CONTRIBUTIONS TO DS AND WDS FOR HEALTH EFFECTS
INCLUDING WORST CASE ASSUMPTIONS
to
DHEG NO.
It. A 220* M
72 A 010
16 A 220* M
21 C 100* P M
38 A 010
36 A 010
43 A 010
71 A 010 P
21 C 100* P M
68 A 010 P
76 A 010 P
32 A 010 P
54 A 010 P
21 C OHO* P
34 A 010
IB B 020* M
18 A 100* H
18 A 140* N
18 A 101*
18 C 040* H
18 A 102*
18 C 081*
18 A 082*
18 A 144*
18 A 003*
18 A 145*
19 A 060* P H
18 A 146*
19 B 020* H
18 A 160* W
19 B 021*
18 A 103*
19 B 022* P
18 A 162*
6AS1F1ER A»N,
COMPOUND NAME
POLYCHLORINATEO BIPHENYLS
IRON (AS FE+2)
POLYCHLORINATEO BIPHENYLS
BENZO(A)PYRENE
ALUMINUM
BARIUM
SILICON
MANGANESE
BENZO(A)PYRENE
CHROMIUM
NICKEL
BERYLLIUM
SELENIUM
OIBENZ( A, H) ANTHRACENE
CALCIUM (AS CA + 2)
CATECHOL
PHENYLPHENOLS
XYLENOLS
0-PHENYLPHENOL
2-NAPHTHOL
P-PHENYLPHENOL
1-INDANOL
M-ETHYLPHENOL
2,6-XYLENOL
P-ETHYLPHENOL
3f 5-XYLENOL
PENTACHLOROPHENOL
3,4-XYLENOL
CHLORINATED CRESULS
ETHYL CRESOLS
CHLORINATED-0-CRESOL3
M-PHENYLPHENOL
CHLOHINATED-M-CRESOL3
4-ETHYL-O-CRESOL
HEALTH IMPACT
TYPE CONC DS
E-b G/C
T 3.98E 01 3.90E 04
D 9.00E 04 3. OOE 04
T 1.50E 01 l.SOE 04
T 3.90E 01 6. SOE 02
D 8.BOE 04 S.SOE 02
D S.SOE 03 S.SOE 02
D 1.40E 05 4.70E 02
D 2.20E 02 4.40E 02
T
S
s
S
D
•j
o
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
.50E 01 2. SOE 02
.OOE 02 2.00E 02
.SOE 01 1.70E 02
.OOE 00 l.SOE 02
.SOE 01
.90E 01
.80E 04
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.SOE 02
.40E 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
NDS LCCAT
G/S
9.43E OS 3
7.30E OS
3.62E 05 2
1.60E 04 3
1.33E 04
1.331 04
1.12E 04
1.10E 04
6.04E 03 2
4.83E 03
4.03E 03
3.63E 03
3.62E 03
3. 40E 03 3
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03
2.42E 03 6
-------
TABLE 4-8. GASIFIER ASH MAJOR CONTRIBUTIONS TO DS AND WDS FOR ECOLOGICAL
EFFECTS INCLUDING WORST CASE ASSUMPTIONS
u>
OMEG
02
16
48
16
02
72
38
08
06
08
08
76
08
06
08
08
62
19
01
34
65
36
71
78
19
20
20
10
20
20
10
10
20
82
A
A
A
A
A
A
A
0
0
D
0
A
D
D
D
0
A
A
B
A
A
A
A
A
A
A
A
C
A
A
C
C
A
A
NO.
380* H
220* W
010
220* W
380* W
010
010
281*
282*
280* P H
2«3*
010 P
260* P M
283*
282*
281*
010
060* P M
220 W
010
010
010
010 P
010 P
060* P W
102*
100* W
140* P M
101* P
080* M
220* H
200* W
103*
010 P
GASIFIER ASH, ECOLOGY IMPACT
COMPOUND NAME TYPE CONC
E-6 G/G
HEXACHLOROCYCLOHEXANE
POLYCHLORINATED BIPHENYLS
PHOSPHORUS
POLXCHLORJNATED BIPH£NYLS
HEXACHLOROCYCLOHEXANE
IRON (AS FE + 2)
ALUMINUM
DIMETHYL PHTHALATE
OIETHYL PHTHALATE
PHTHALATE ESTERS (MM j 194-279)
DI-N-BUTYL PHTHALATE
NICKEL
PHTHALATE ESTERS (MW;194-279)
0I-N-BUTVL PHTHALATt
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
TITANIUM
PENTACHLOROPHENOL
OICYCLOPENTAOIENE
CALCIUM (AS CAf2)
VANADIUM
BARIUM
MANGANESE
COPPER
PENTACHLOROPHENOL
2,5-DINITROPHENOL
DINITROPHENOLS
BENZIDINE
2,4-DINITROPHENOL
2-AMINO-4,b-DINlTROPHtNOL
2-AMINONAPHTHALENE
1-AMINONAPHTHALENE
2,6-DINJTROPHENOL
CADMIUM
T
T
D
T
T
D
U
T
T
T
T
S
T
T
T
T
D
T
T
D
S
D
D
S
T
T
T
T
T
T
T
T
T
S
3.30E
3.90E
2.00E
1.50E
1.50E
9.00E
B.BOE
l.OOE
l.OOE
l.OOE
1 .OOE
7.50E
2.60E
2.6UE
2.60E
2.60E
4.50E
l.OOE
3.30E
4.80E
4.10E
5.50E
2.20E
8.10E
2.60E
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
02
01
03
01
01
04
04
02
02
02
02
01
01
01
01
01
03
02
02
04
02
03
02
01
01
02
02
02
02
02
02
02
02
8.00E-01
US
B.24E
3.90E
2. OOE
l.SOE
3.74E
1.80E
4.40E
1.30E
I.JOE
I.JOE
1.30E
3.UOE
3.24E
3.24E
3.24E
3.24E
2.B1E
2. OOE
.70E
.50E
.40E
.10E
. 10E
B.10E
5.20E
5. OOE
5. OOE
5. OOE
5. OOE
5. OOE
S.OOE
5. OOE
S.OOE
4. OOE
04
04
04
04
03
03
02
02
02
02
02
01
01
01
01
01
01
01
01
01
01
01
01
00
00
00
00
00
00
00
00
00
00
00
WDS
G/S
2. OOE
9.43t
4.83E
3.62t
9. lOfc
4.40E
1.10E
3.02E
3.02t
3.02E
3.02E
9. lOt
7.90E
7.VOt
7.90E
7.90E
6.BOE
4.B3E
4.00t
3.62E
3.30L
2.70E
2.70E
2.00t
1.30L
1.21E
1.21t
1.21E
1.21E
1.21E
1.21E
1.21E
1.21E
9.70E
06
05
05
05
04
04
04
03
03
03
03
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
01
LCCAT
1
3
2
2
6
6
b
6
5
5
5
5
6
t
5
6
6
6
6
6
b
b
b
-------
TABLE 4-9. GASIFIER ASH SLUICE WATER MAJOR CONTRIBUTIONS TO DS AND WDS FOR
HEALTH EFFECTS INCLUDING WORST CASE ASSUMPTIONS
OHEG NO.
16 A 220
21 C 100*
21 C 000*
16 C 020
18 A 142*
!« A 145
16 C 040
U A 160
ia A 104
18 A 162
18 A 163
18 A 180
16 A 181
16 A 182
18 A 183
18 B 020
18 B 040
IB B 060
16 B 080
20 B 020*
16 A 083
18 C 080
18 C 081
16 C 082
18 C 083
19 A 020*
18 A 161
18 A 081
19 A 040*
20 A 000
16 A 100
19 A 060*
16 A 102
16 A 103
H
P M
P
M
P
M
M
H
H
H
M
N
P H
W
P W
P W
H
H
P H
GA8IFIER ASH
COHPOUNO NAME
POLYCHLORINATED BIPHENYLS
BENZO(A)PVRENE
OIBENZC A, H) ANTHRACENE
I-NAPHTHOL
2,4-XVLENOL
3,5-XYLENOL
2-NAPHTHOL
ETHYL CRE30L3
2,6-XYLENOL
4-ETHVL-0-CRE30L
2-ETHYL-P-CRESOL
POLYALKYLPHENOLS (MN>13S)
2,4,6-TRIMETHYL HETHYL PHENOL
4,6-DI-TERT-BUTYL-M-CR£SuL
2.6-OIMETHYL-4-HEPTYL PHENOL
CATECHOL
1, J-DlHYDROXYbENZENE
1,4-01HYOROXYBENZENE
1,2, J-THIHYDROXYBENZENE
4,6-DlNITRO-O-CRESOL
P-ETHYLPHENOL
INUANOLS
1-INDANOL
4-INOANOL
5-1NOANOL
2-CHLOROPHENOL
6-ETHYL-M-CRESOL
0-ETHYLPHENOL
2»
-------
TABLE 4-10.
GASIFIER ASH SLUICE WATER MAJOR CONTRIBUTIONS TO DS AND WDS FOR
ECOLOGICAL EFFECTS INCLUDING WORST CASE ASSUMPTIONS
OHEG
16
02
08
06
06
08
19
16
26
16
16
16
16
16
16
10
16
16
20
10
16
16
20
16
16
21
16
01
20
10
20
16
16
16
A
A
0
0
0
D
A
A
B
A
A
A
A
A
A
C
A
A
A
C
A
A
A
A
B
A
A
B
A
C
A
A
B
B
NO.
220 H
360 N
283
282
281
280* P W
060* P W
040
040 H
020* P
162
061
062
083
100* P
200 M
080
120* P
101* P
140* P W
062
063
080 N
160* P
043
020* P
161
220 M
103
220 M
100 W
061
020 H
040
GA3IFIER ASH SLUICE HATER, ECOLOGY IMPACT
COMPOUND NAME TYPE CONC
E-6 G/L
POLYCHLORINATEO BIPHENYLS
HEXACHLOROCYCLOHEXANE
DI-N-BUTYL PHTHALATE
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
PHTHALATE ESTERS (MW:194-279)
PENTACHLOROPHENOL
BROMOBENZENE
TRITOTYL PHOSPHATES
CHLOROBENZENE
HEXACHLOROBENZENE
l-BROMO-2-CHLOROBENZENE
l-BROMO-3-CHLOROBENZENE
l-BROMO-4-CHLOROBENZENE
1,2-D I CHLOROBENZENE
1-AMINONAPHTHALENE
BROMOCHLOROBENZENES
1 , J-0 1 CHLOROBENZENE
2,4-OINlTROPHENOL
BENZIDINE
1, J-DIBROMOBENZENE
1,4-DIBROMOBENZENE
2-AMINO-4,6-DINITHOPHENOL
POLYCHLORINATED BENZENES
1,4-B I S(CHLOROMETHYL) BENZENE
NAPHTHALENE
1,2,4-TRICHLOROBENZENE
DICYCLOPENTAOIENE
2,6-OINlTROPHENOL >
2-AM1NONAPHTHALENE
DINITROPHENOLS
1,2-DIBROMOBENZENE
A-CHLOROTOLUENE
BIS(CHLOROMETH YD BENZENES
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
.JOE
.30E
.JOE
.JOE
.30E
.30E
.30E
.30E
.30E
.30E
.30E
.30E
.JOE
.30E
.30E
.JOE
.30E
.JOE
.30E
.JOE
.JOE
.30E
.30E
.JOE
.30E
.JOE
.30E
.30E
.30E
.JOE
.JOE
.JOE
.30E
.30E
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
US
2.51E
6. JOE
8.
8.
8.
-------
TABLE 4-11.
CYCLONE DUST MAJOR CONTRIBUTIONS TO DS AND WDS FOR HEALTH
EFFECTS INCLUDING WORST CASE ASSUMPTIONS
CYCLONE OUST. HEALTH I HP AC I
OHEC NO.
ib A 220*
16 A 220*
21 C 100* P
21 c oeo* P
19 A 020* P
19 A 040* P
20 0 041*
19 A 060* P
16 A 042*
19 B 020*
Id C 083*
ta A 020* P
IB A 060*
Id A 040*
18 A 080*
Id A 041*
IB A oai*
20 A 020* P
IB A 082*
20 A 040*
18 A 083*
20 A 060* P
18 A 100*
20 A 080*
18 A 101*
20 A 100*
18 A 102*
20 A 101* P
18 A 103*
20 A 102*
IB A 120*
20 A 103*
18 A 140*
20 A 120*
M
M
M
N
W
M
N
H
H
M
M
N
M
M
M
M
H
H
H
M
COMPOUND NAME
POLYCHLOR1NATED BIPHENYL8
POLVCHLORINATED BIPHENYLS
BENZO(A)PYRENC
OI6£NZ( A, H) ANTHRACENE
2-CHLOROPHENOL
2,4-DICHLOROPHENOL
3,S-DINITHO-P-CR£SOL
PtNTACHLOROPHENOL
0-CRE30L
CHLORINATED CRESOLS
S-INDANOL
PHENOL
2-METHOXYPHENOL
CRE30L3
ETHYLPHENOLS
M-CRESOL
0-ETHYLPHENOL
2-NITROPHENOL
M-ETHYLPHENOL
3-NITROPHENOL
P-tTHYLPHENOL
(I-NITROPHENOL
PHENYLPHENOLS
2-AMlNO-4,6-DINITKOPHENOL
0-PHENYLPHENOL
DINITROPHENOLS
P-PHENYLPHENOL
3,4-DINITROPHENOL
M-PHENYLPHENOL
2,5-DINITROPHENOL
2,2'-OIHYDROXYOIPHENYL
2,6-OINITROPHENOL
XYLENOLS
2,4,6-TRlNITROPHENOL
ITPE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
r
T
T
CONC
E-6 6/C
I.30E 03
1.40E 02
I.JOE 03
I.JOE 03
3.40E 03
3.40E 03
3.40E 03
S.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E OS
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
US NDS LCCAT
6/8
1.30E 06 4.94E 06 3
1.40E OS 5.32E OS 2
2.20E 04 0.23E 04
4.64E 03 1.80E 04
3.40E 03 1.30L 04
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
.30E 04
.30E 04
,30t 04
.30E 04
.30E 04
.30£ 04
.30E 04
.30E 04
.lot 04
.30£ 04
.30E 04
.30E 04
,30E 04
.30E 04
.30E 04
.30E 04
.3ot 04
.30E 04
.30E 04
.Sot 04
.30b 04
.JOE 04
.JOE 04
.JOE 04
.JOE 04
.30E 04
.30E 04
.JOE 04
.SOE 04
-------
TABLE A-12.
CYCLONE DUST MAJOR CONTRIBUTIONS TO DS AND WDS FOR ECOLOGICAL
EFFECTS INCLUDING WORST CASE ASSUMPTIONS
DMEG
16 A
02 A
16 A
02 A
46 A
06 D
06 D
08 D
06 D
08 D
08 D
06 D
08 0
19 A
72 A
20 A
20 A
20 A
20 A
20 A
10 C
10 C
10 C
19 A
01 B
16 A
16 A
Ib A
Ib A
16 A
16 B
16 A
16 B
16 A
NO.
220*
380*
220*
380*
010
281*
283*
282*
280*
283*
282*
261*
280*
060*
010
102*
101*
100*
060*
103*
220*
200*
140*
060*
220
063*
162*
Obi*
060*
160*
020*
161*
043*
080*
CYCLONE OUST, ECOLOGY IMPACT
COMPOUND NAME TYPE CONC
E-6 G/G
W
W
M
H
P H
P W
P W
P
H
W
H
W
P M
P W
H
P
H
POLYCHLORINATEP BIPHENYLS
HEXACHLOROCYCLOHEXANE
POLYCHLORINATEO BIPHENYLS
HEXACHLOROCYCLOHEXANE
PHOSPHORUS
DIMETHYL PHTHALATE
DI-N-BUTYL PHTHALATE
DIETHYL PHTHALATE
PHTHALATE ESTERS (MN| 194-279)
DI-N-BUTYL PHTHALATE
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
PHTHALATE ESTERS (MH| 194-279)
PENTACHLOROPHENOL
IKON (AS FE + 2)
2,5-DIHlTROPHENOL
2,0-DINITROPHENOL
OINITROPHENULS
2-AMINO-4,6-DlNlTROPHENOL
2,6-DINITROPHENOl.
2-AMINONAPHTHALENE
1-AMINONAPHTHALENE
BENZIDINE
PENTACHLOROPHENOL
DICYCLOPENTAOIENE
1,4-DIBROMOBENZENE
HEXACHLOROBENZENE
1,2-DlBROMOBENZENE
OIBROMOBENZENES
POLYCHLORINATED BENZENES
A-CHLOROTOLUENE
1,2,4-TRICHLOROBENZENE
1,4-8IS(CHLOROMETHYL)BENZENE
BROMOCHLOROBENZENES
T
T
T
T
0
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1
2
1
1
5
3
3
3
3
7
7
7
7
3
9
3
3.
3
3.
3,
3,
3
3
7.
2,
•
•
4
t
t
4
t
4
.30E 03
.60E 03
,40E 02
.40E 02
,90E 02
.40E 03
,40E 03
,40E 03
.40E 03
.7UE 02
,70E 02
.70E 02
.70E 02
,40E 03
20E 03
,40E 03
.40E 03
,40E 03
40E 03
40E 03
40E 03
40E 03
40E 03
70E 02
60E 03
3UE 03
30E 03
30E 03
30E 03
30E 03
30E 03
30E 03
30E 03
30E 03
DS
1.30E
b.SOE
1.40E
3. SOE
S.90E
4.24E
4.24E
4.24E
4.24E
9.62E
9.62E
9.62E
9.62E
6.80E
.64E
.70E
.70E
.70E
.70E
.TOE
.70E
.70E
.70E
.S4E
.3UE
6. SOE
6. Sot
b.SOE
6. SOE
b.SOE
b.SOE
b.SOE
b.SOE
b.SOE
06
OS
OS
04
03
03
03
03
03
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
01
01
01
01
01
01
01
01
01
HD3
U/S
4.94E
2. SOt
S.32t
1.32t
2.24t
i.blt
l.blt
I.blt
l.blt
3.70E
3.70E
3.70t
3.70E
2.60E
7.00t
6. SOt
6. SOt
b.SOt
b.SOt
b.SOt
6. SOt
6. SOt
b.SOE
5.90t
4.94E
2. SOt
2. SOt
2. SOt
2. SOt
2. SOt
2. SOt
2./SOt
f, sot
2. SOt
LCCAT
06 3
06 1
OS 2
OS 2
04
04 6
04 b
04 b
04 b
03 S
03 S
03 S
03 5
03 b
02
02 b
02 b
02 b
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
-------
TABLE 4-13.
CYCLONE DUST QUENCH WATER MAJOR CONTRIBUTIONS TO DS AND WDS
FOR HEALTH EFFECTS INCLUDING WORST CASE ASSUMPTIONS
00
OHEG
1ft
21
21
10
10
10
10
10
10
10
10
10
19
10
10
19
10
10
19
10
10
19
19
19
10
10
19
20
10
10
10
20
10
ia
A
C
c
B
B
A
B
C
A
C
C
C
A
B
A
A
C
A
A
A
A
B
B
B
A
A
B
A
A
A
A
A
A
A
NO.
220
100*
000*
040
060
103
020
040
102
001
002
003
020*
000
003
040*
060
102
060*
120
140
020
021
022*
041
143
023
020*
146
160
002
060*
163
101
M
P M
P
M
M
M
M
P M
M
P W
M
P H
M
W
M
P
P N
W
P H
CYCLONE DUST flUENCH NAUR,
COMPOUND NAME
POLYCHLORINATEO BIPHENYL3
BENZO(A)PVREHE
OIBENZ (A, H) ANTHRACENE
1 , 3-0IHYDROXVBENZENE
t r 4-DIHYDROX YBENZENE
2,b-DIM£THYL-«-HEPTYL PHENOL
CATECHOL
2-NAPHTHOL
4,6-DI-TERT-BUTYL-M-CHESQL
1-INDANOL
4-INDANOL
S-INDANOL
2-CHLOROPMENOL
1,2,3-TRIHYDROXYHENZENE
P-ETHYtPHENOL
2,4-DICHLORUPHCNOL
INUA'NOLS
P-PHENYLPHENOL
PENTACHLOROPHENOL
2, 2 ' -DIHYOROXYDIPHENYL
XYLENOLS
CHLORINATED CRESOLS
CHLOHINATEO-0-CRESOLS
CHLORINATED-M-CRE30US
M-CRESOL
2,5-XYLENOL
CHLORINATED-P-CRESOL8
2-NITROPHENOL
3f 4-XYUENOL
ETHYL CRESOLS
M-ETHYLPHENOL
4-NITROPHENOL
2-ETHYL-P-CRESOL
0-PHENYLPHENOL
HEALTH IMPACT
TYPE CONC DS
E-6 6/L
T 6.00E
T 6.00E
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
f
I
T
T
T
T
T
T
f
y
T
T
T
T
T
.OOE
.OOE
.OOE
.OttE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.out
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.ooe
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OUE
.OOE
.OOE
.OOE
.OOE
04 1.20E
04 2. OOE
04 4.30E
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
,20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
.20E
07
OS
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
NDS
G/3
0.33E
1.40E
J. OOE
0.33E
0.33E
0.33E
0.33C
0.33E
0.33E
0.33E
0.33E
6.33E
0.33E
0.33E
0.33E
B.33E
e.sjt
0.33E
0.33E
0.33E
0.33E
0.33E
8. Jit
0.33E
0.33E
0.33E
0.33E
0.33E
0.33E
0.33t
8.J3t
0.33E
0.33E
0.33E
LCCAT
07
Ob
OS
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
-------
TABLE 4-14.
CYCLONE DUST QUENCH WATER MAJOR CONTRIBUTIONS TO DS AND WDS FOR
ECOLOGICAL EFFECTS INCLUDING WORST CASE ASSUMPTIONS
CYCLONE OUST OUCNCH MAUR, 'CCOLO&V IMPACT
vo
OHEG
NO.
COMPOUND
NAME
TYPE
CONC
E-6 G/L
DS
H08
U/S
LCCAT
16
02
08
oa
08
08
19
48
16
16
21
16
16
16
16
16
16
16
01
16
16
16
20
16
16
26
16
20
20
16
16
16
10
10
A
A
D
D
0
D
A
A
A
A
A
A
A
A
A
6
B
A
B
A
A
A
A
A
A
B
B
A
A
B
B
A
C
C
220
380
282
283
281
280*
060*
010
082
063
020*
081
060
OK3
0<>2
000
04|
160*
220
061
140*
162
101*
120*
040
040
020
103
100
042
043
161
220
140*
H
W
P H
P H
P
P
H
P
P
P
H
H
H
N
P H
P
H
D
D
D
P
P
P
1
1
N
1
D
1
1
B
1
P
0
1
1
Hi
2
1
B!
Ti
A
2
D
1
1
1
2
B
POLYCHLORINATED B1PHENVLS
HEXACHLOROCYCLOHEXANE
DIETHYL PHTHALATE
OI-N-BUTYt PHTHALATE
DIMETHYL PHTHALATE
PHTHALATE ESTERS (MHi194-279}
PENTACHLOROPHENOL
PHOSPHORUS
l-BROMO-3-CHLOROBENZENE
4»DIBROMOBENZENE
NAPHTHALENE
l-BROMO-2-CHLOROBENZENE
DIBROHOBENZENE3
l-BROMO-4-CHLOROBENZENE
1,3-DIBROMOBENZENE
BIS(CHLOROMfcTHYL)BENZENES
1,2-BIS(CHLOROM£THYBENZENE
POLYCHLORINATEO BENZENES
OICVCLOPENTADIENE
1,2-OIBROMOBENZENE
1,4-OICHLOROBENZENE
HEXACHLOROBENZENE
2»4-DINITROPHENOL
1,3-OICHLOROBENZENE
BROMOBEN2ENE
TRITOTYL PHOSPHATES
A-CHLOROTULUENE
2»6-OINITROPH£NOL
DINITROPHENOLS
1,3-BIS(CHLOROMETHYL)BENZENE
1,4-BI3(CHLOROMETHYL)BENZENE
1,2,4-TRICHLOROBENZENE
2-AH1NONAPHTHALENE
BENZIDINE
T
T
T
T
T
T
T
s
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
.ODE 04
.ODE 04 .
.OOE 04 '
.ODE 04 <
.OOE 04 '
.OOE 04 «
.OOE 04 <
.OOE 02 (
.OOE 04 <
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
1.20E 07
i.OOE 06
4. OOE 04
I.OOE 04
4. OOE 04
I.OOE 04
J.40E 03
i.OOE 02
i.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
8.33E 07
2. io£ 07
2.BOE 05
2.BOE 05
2.BOE 05
2.80E 05
1.701 04
5.60E 03
4.20E 03
4.20E 03
4.20E 03
4.20E 03
4.20E 03
4.20E 03
4.20E 03
4.20E 03
4.20E 03
4.20E 03
4.20C 03
4.20E 03
4.20E U3
4.20E 03
.20E 03
.20E 03
.20E 03
.20t 03
.20E 03
.20E 03
.20E 03
.20E 03
.20E 03
.20E 03
4.20E 03
4.20£ 03
-------
TABLE 4-15.
DISCHARGE SEVERITY & WEIGHTED DISCHARGE
SEVERITY SUMMATIONS FOR THE FT. SNELLING
WELLMAN-GALUSHA PROCESS STREAMS INCLUDING
WORST CASE ASSUMPTIONS
Health
Stream
Product Gas Particulate
P. G. Organic Module
Test Burner Flue Gas
Gasifler Ash
Gaaifier Ash Sluice H20
Cyclone Dust
Dust Quench Water
EDS
2.4E5
1 . 9E5
2.5E3
8.7E4
2.5E7*
1.4E6
1.2E7*
EWDS
(g/s)
1.4E8
1.1E8
2.0E7
2.1E6
1.8E8*
5.5E6
8.3E7*
Ecology
IDS
2.3E3
3.9E5
5.4
1.6E5
2.5E7*
2.1E6
1.2E7*
ZWDS
(g/s)
1.4E6
2.3E8
4.4E4
3.8E6
1.8E8*
8.0E6
8.3E7*
aEb - a x 10
* Total sample organic loading expressed as the single worst case
organic compound for maximum DS and WDS.
70
-------
4.2
BIOASSAY RESULTS SUMMARY
The bioassay tests conducted and a summary of the results obtained
are shown in Table 4-16. The detailed results are given in Appendix F as
received from the subcontractor, A. D. Little Inc.
TABLE 4-16. BIOASSAY TEST/RESULTS MATRIX
BIOASSAY TEST
SAMPLE
AMES
WI-38
RAM
RODENT
Product Gas Composite
Test Burner Composite
Gasifier Ash
Gasifier Ash Sluice Water
Cyclone Dust
Cyclone Dust Quench Water
Neg.* Mod.
Neg . None
Neg.
Neg. Mod.
Neg.
Neg. None
None
None None
None
None None
None
Neg. - no mutagenicity detected.
None - no in vitro or in vivo toxicity.
Mod. - moderate in vitro cytotoxicity.
* - toxic to test cells.
4.2.1 Mutagenicity Test Results (Ames)
The Ames test was performed on Salmonella typhimurium with and
without metabolic activation in a histidine insufficient culture medium
such that tester strains were not allowed to colonize. After incubation,
the histidine-positive revertant colonies were counted as an indicator of
mutagenicity. No sample appeared to be mutagenic in the presence or
absence of metabolic activation. The product gas composite was extremely
71
-------
toxic to the test cells and could only be tested at 0.08, 0.4, 2.0, and 10
yl/plate instead of the 100, 150, 200, and 250 yl/plate as was done for th*
test burner flue gas composite and liquid stream samples.
4.2.2 In Vitro Cytotoxicity Test Results (Wl-38. RAM)
In vitro cytotoxicity was assayed using Wl-38 human lung
fibroblast cells and rabbit alveolar macrophages (RAM). For the Wl-38
assay, the cultured cells were incubated on media containing the sample
extracts. After incubation, the cells were removed by trypsinization,
diluted with culture medium and assayed for cell viability, protein, and
adenosine triphosphate (ATP) levels. No detectable toxicity was found at
the highest concentrations Of cyclone dust quench water or test burner flu*
gas composite tested. The product gas composite and the gasifier ash
sluice water caused moderate toxicity.
The cyclone dust and gasifier ash were tested for in vitro
cytotoxicity using the RAM assay. Alveolar macrophages collected by lung
lavage from specific pathogen-free albino rabbits were incubated in media
containing finely ground particles of the dust and ash for 20 hours. The
cells were subsequently trypsinized, and aliquots of the cell suspensions
were assayed for viability and protein and ATP levels. There was no
detectable toxicity for either solid tested.
4.2.3 Acute In Vivo Toxicity Test Results (Rodent)
Acute in vivo toxicity was evaluated by oral administration of th*
samples to fasted, adult albino Sprague-Dawley rats. No signs of toxicity
or pharmacological effects were detected. No mortality was recorded and
upon autopsy, after a two week observation period, no gross lesions or
abnormalities were noted. The gasifier ash and cyclone dust were adminis-
tered as suspensions in physiological saline; the product gas composite
extract, the cyclone dust quench water, and the gasifier ash sluice water
were administered by oral intubation without saline. The mortality data
suggests that the oral LD$Q for each test substance is greater than 10.0
g/kg or 10.0 ml/kg.
4.2.4 Ecological Testing
Ecological testing was not conducted on these streams due to th
uncertainties in the results interpretation. A ranking of high, medium
low potential for hazard cannot be made from results of ecological tests *
Previous ecological testing of Wellman-Galusha discharge streams with an*
anthracite coal indicated ecological toxicity from the gasifier ash and
lesser degree from the cyclone dust (Ref. 2). The SAM/1A results for
lignite feed discharge stream samples point to the product gas conde
and the ash sluice water as having the highest ecological WDS values.
72
-------
4.3 CHEMICAL ANALYSIS RESULTS
The results of the inorganic analysis and both the organic
screening and detailed analyses are summarized in this section. The data
from these chemical analyses are presented in detail in Appendix D.
The inorganic analysis results describe the elemental composition
of each stream and the distribution of these elemental species throughout
the process streams. In addition, those results which address specific
pollution problems such as water quality and solids leachability are
provided here.
The organic analytical approach implemented during this project
provided a general characterization of the streams and the distribution of
organic classes throughout the process. The detailed organic analysis was
prioritized on the basis of the weighted discharge severity (WDS) for each
stream determined from the organic screening results. This imposes a
limitation on the range of compound specific information that can be
applied to the entire process, since some streams had low WDS values and
were therefore not included in the detailed analysis.
4.3.1 Gasification System Overview
The mass flows of the minor and trace elements in the process and
discharge streams are given in Table 4-17. These mass flows were calcu-
lated from analysis of samples and flow rate data collected during opera-
tion of the gasifier in two different configurations, as discussed in
Section 2.0. Samples from the product gas, gasifier ash, and gasifier ash
sluice water were collected during operation with the product gas vented.
The distribution, of elements among these three streams during product gas
venting is presented in Table 4-18. Normal operation of the system in-
cludes passage of the product gas through the cyclone for removal of par-
ticulates and heavy tar aerosols. The distribution of elements among the
test burner flue gas, gasifier ash, gasifier ash sluice water, cyclone
dust, and cyclone dust quench water was estimated from the elemental flows
for these five streams. This estimated elemental distribution during
normal operation is given in Table 4-19. The total for normal operation is
the sum of the mass flows in the five streams normally exiting the system.
The organic screening of the samples indicates that the gaseous
streams and the cyclone dust quench water were higher in aromatics than the
solid streams and the gasifier ash sluice water,which were primarily ali-
phatic. The product gas and the cyclone dust contained high concentrations
of extractable organics compared to the test burner flue gas, the liquid
streams, and tae gasifier ash. A summary of the extractable organic con-
tent of the streams is given in Table 4-20.
73
-------
TABLE 4-17. MASS FLOW FOR THE MINOR AND TRACE ELEMENTS
Aluminum
Antimony
Arsenic
Barium
Beryllium
Bi smuth
Boron
Bromine
Cadmium
Calcium
Cerium
Cesium
Chlorine
Chromium
Cobalt
Copper
Dysprosium
Erbium
Europium
Fluorine
Gadolinium
Gallium
Germanium
Gold
Hafnium
Holmium
Iodine
Iridium
Iron
Lanthanum
Test Burner
Flue Gas
g/h
3.9E-1
<2.7E-1
2.1
>2.9
9.7E-2
1.1E-2
>4.9E-3
>1.9E1
1.5E-2
2.7E-2
8. OE-1
9.0E-1
3.2
2.3E-1
2.4
<3.2E-2
4.9E-3
1.6E-2
>7.6
2.0E-2
Product Gas
Participate
g/h
5.5E1
<7.8E1
7.6E-1
1.6E1
5.3E-3
5.3E-3
1.1
2.7E-1
5.5E-1
3.1E2
l.OE-1
4.7E-3
>6.6
1.8E-1
2.9E-2
5.5E 1
3.5E-3
1.3E-3
2.0E-3
2.7
3.9E-3
4.7E-2
1.5E-2
5.9E-3
2.0E-3
<8.2E-3
<6.8E1
7.4E-2
Product Gae
Org. Module
g/h
8.6E-4
<3.3B-2
>3.7E-2
4.3E-2
>2.7E-2
1.8E-3
9. 4E-1
1.8E-3
3. 3E-2
3.1E-2
>1.6E-3
2.3E-2
1.9E-2
2.7E-2
9.4E-1
2.7E-3
Ash Sluice
Water
g/h
2.8E-1
5.0E-5
8.3E-5
3.3E-3
1.2E-1
5.0E-4
<5.0E-5
5.5
5.0E-5
2.0
1.8E-4
<5.0E-5
4.3E-4
2.2E-2
2.0E-4
3.0E-2
<2.5E-5
Cyclone
Quench
Water
g/h
2.8E-1
3.0E-3
1.4E-2
2.5E-2
l.OE-3
<1.3E-4
1.4
5.0E-5
l.OE-4
8.6E-1
<1.3E-4
2.3E-4
3.0E-4
5.0E-2
5.0E-4
1.8E-4
1.5E-4
1.2E-1
Gasifier
Ash
g/h
8.5E3
O.9E-2
2.9
5.3E2
8.6E-1
2.0E1
1.9E-1
7.8E-2
4.7E3
1.1E1
7.8E-1
1.4E1
9.7
2.2
7.8
6.8E-1
2.9E-1
2.9E-1
1.8E1
3.9E-1
8.6E-1
8.7E-2
9.7E-2
3.9E-1
1.9E-2
8.6E3
1.1E1
Cyclone
Dust
g/h
1.6E2
<5.5E-3
8.6E-1
1.8E1
5.5E-3
4.1E-3
1.5
1.2E-1
2.7E-2
4.0E2
2. OE-1
9.6E-3
7.8E-1
1.5E-1
6.8E-2
4.1E-1
8.2E-3
4.1E-3
5.5E-3
3.8
5.5E-3
4.5E-1
8.2E-2
5.5E-3
5.5E-3
1.2E2
1.1E-1
-------
TABLE 4-17. MASS FLOW FOR THE MINOR AND TRACE ELEMENTS (Cont'd)
Lead
Lithium
Lutetium
Magnesium
Manganese
Mercury
Molybdenum
Neodymium
Nickel
Niobium
Osmium
Palladium
Phosphorus
Platinum
Potassium
Pr aseodymium
Rhenium
Rubidium
Ruthenium
Samarium
Scandium
Selenium
Silicon
Silver
Sodium
Strontium
Sulfur
Tantalum
Tellurium
Terbium
Test Burner
Flue Gas
g/h
3.7E-1
O.4E-2
>3.2
4.1E-1
3.9E-1
4.4E-1
6.1E-4
1.1
>2.4E-3
4.1
3.2E-2
>1.2E1
3.2E-4
<8.5E-3
<1.2E-3
<3.2
>7.1
2.2E-2
>3.4
1.3E-1
2.9
Product Gas
Participate
g/h
2.7E-1
2.5E-1
8.0E2
2.5E-1
1.3E1
2.0E-2
2.0E-2
2.3E-1
2.7E-2
>6.6
<6.6
1.3E-2
<6.2E-2
<1.4E-2
1 . 3E-2
3.9E-2
3.1E1
XL.4E1
2.3E-1
4.3E1
8.0
>7.2
2.0E-3
1.3E-3
Product Gas
Org. Module
g/h
5.9E-2
1.3E-2
5.1E-2
1.5E-2
6.8E-3
2.0E-2
1.9E-1
1.4E-1
4.1E-3
>6.2E-3
6.8E-1
6.2E-2
6.4E-2
8. 6E-3
8.8
Ash Sluice
Water
g/h
2.0E-4
l.OE-2
2.8E-1
5.0E-5
3.5E-5
7.8E-3
5.0E-4
5.0E-5
l.OE-2
>2.5
2.5E-5
l.OE-3
5.0E-4
7.6E-3
2.5E-5
4.3E1
l.OE-1
2.4E1
Cyclone
Quench
Water
g/h
2.5E-3
l.OE-3
2.8E-1
<2.5E-5
l.OE-5
l.OE-4
O.OE-4
l.OE-2
>2.5
5.0E-4
1.5E-4
5.0E-2
5.0E-5
5.5
2.8E-2
5.8E-1
Gasifier
Ash
g/h
4.9E-1
4.7
2.9E-2
1.2E3
2.1E1
1.7E-1
1.4
2.9
7.2
3.0
1.9E2
8.3E2
1.6
4.6
1.2
1.9
1.4
1.3E4
5.8E-2
1.8E3
1.8E2
8.5E2
<7 . 8E-2
9.6E-2
Cyclone
Dust
g/h
1.1E-1
8.2E-2
1.0E2
2.6E-1
3.1E-2
2.7E-2
4.1E-2
5.5E-2
6.8E-2
8.1
1.7E1
2.7E-2
4.1E-2
2.7E-2
6.8E-2
1.9E-1
2.5E2
2.7E-2
1.5E2
1.9E1
1.5E2
2.7E-3
1.4E-3
-------
TABLE 4-17. MASS FLOW FOR THE MINOR AND TRACE ELEMENTS (Cont'd)
Thallium
Thorium
Thulium
Tin
Titanium
Tungsten
Uranium
Vanadium
Ytterbium
Yttrium
Zinc
Zirconium
Ash*
Test Burner
Flue Gas
g/h
3.7E-2
5.1E-1
<9.7E-4
8.8E-2
<4.9E-4
3.2E-1
2.9E-1
Product Gas
Participate
g/h
6.6E-3
1.3E-2
<6.2E-4
2.7E-2
1.9
6.6E-3
6.6E-3
7.4E-2
6.2E-2
9.8E-1
1.8E-1
Product Gas
Org. Module
g/h
1.8E-3
4.9E-2
9.4E-3
1.9E-3
6.4E-2
5.1E-4
Ash Sluice
Water
g/h
7.6E-2
1.1E-3
5.0E-4
1.9E-3
1.1E-3
5.0E-5
Cyclone
Quench
Water
g/h
7.3E-2
4.5E-3
3.8E-4
5.0E-5
8.8E-4
1.3E-4
Gasifier
Ash
g/h
2.2
3.9E-2
4.9E-2
4.3E2
9.6E-2
1.6
4.0E1
2.9E-1
5.7
1.9
1.8E1
74.41%
Cyclone
Dust
g/h
1.2E-2
2.7E-2
2.7E-2
5.5
<9.6E-3
1.2E-2
2.6E-1
8.2E-3
1.8E-1
2.2
4.0E-1
18.97%
aEb
a x
10b
*Ash (mineral content) from proximate analysis, dry basis.
-------
TABLE 4-18.
PERCENT DISTRIBUTION OF THE TRACE ELEMENTS AND MINOR ELEMENTS
WITH THE PRODUCT GAS ROUTED TO THE START-UP FLARE
ELEMENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Bismuth
Boron
Bromine
Cadmium
Calcium
Cerium
Cesium
Chlorine
Chromium
Cobalt
Copper
Dysprosium
Erbium
Europium
Fluorine
Gadolinium
Gallium
Germanium
Gold
Hafnium
Holmium
Iodine
Iridium
Iron
Lanthanum
Lead
Lithium
Lutetium
TOTAL g/hr
6.8E3
8.4E-1
3.1
4.4E2
6.9E-1
5.3E-3
1.7E1
4.2E-1
6.1E-1
3.9E3
8.4
6.1E-1
2.0E1
7.7
1.7
6.7
5.3E-1
2.3E-1
2.3E-1
1.7E1
3.0E-1
7.5E-1
9.0E-2
8.1E-2
3.0E-1
2.3E-2
7.5E3
8.4
7.1E-1
3.9
2.3E-2
PRODUCT GAS
PARTICULATE
0.8
92.5
24.5
3.7
0.8
100.
6.4
63.9
90.0
7.9
1.2
0.8
33.6
2.3
1.7
8.2
0.7
0.6
0.9
16.1
1.3
6.2
16.7
7.3
0.7
35.3
9.1
0.9
38.1
6.5
% of Total
PRODUCT GAS ORGANIC ASH SLUICE
MODULE COMPOSITE WATER
<0.1 <0.1
3.9 <0.1
1.2 <0.1
<0.1 <0.1
0.2 0.7
0.4 0.1
<0.1
<0.1 0.1
<0.1 <0.1
0.2 10.2
0.4 <0.1
0.1 <0.1
0.3 <0.1
0.1 0.1
3.6 <0.1
<0.1 <0.1
<0.1 <0.1
8.3 <0.1
0.3 0.3
ASH*
99.2
3.6
74.3
96.3
99.2
92.8
35.5
10.0
91.9
98.8
99.2
56.0
97.3
98.2
91.4
99.3
99.4
99.1
83.6
98.7
90.2
83.3
92.7
99.3
64.7
90.9
99.1
53.6
93.0
100.
-------
TABLE 4-18.
PERCENT DISTRIBUTION OF THE TRACE ELEMENTS AND MINOR ELEMENTS
VJITH THE PRODUCT GAS ROUTED TO THE START-UP FLARE (Cont'd)
00
ELEMENT
Magnesium
Manganese
Mercury
Molybdenum
Neodymium
Nickel
Niobium
Osmium
Palladium
Phosphor urn
Platinum
Potassium
Praseodymium
Rhenium
Rubidium
Ruthenium
Samarium
Scandium
Selenium
Silicon
Silver
Sodium
Strontium
Sulfur
Tantalum
Tellurium
Terbium
Thallium
Thorium
Thulium
TOTAL g/hr
1.0E3
1.6E1
1.3E1
1.1
2.3
5.9
2.3
1.6E2
6.6E2
1.2
6. 3E-2
3.6
9.6E-1
1.5
3.2E1
1.0E4
3.4E-1
1.5E3
1.5E2
7.1E2
6.1E-2
2.0E-3
7.6E-2
6.6E-3
1.7
3.1E-2
Z of Total
PRODUCT GAS PRODUCT GAS ORGANIC ASH SLUICE
PARTICULATE MODULE COMPOSITE WATER
7.8 <0.1 <0.1
1.5 0.1 <0.1
99.0 <0.1 <0.1
1.8 0.7
0.9
3.9 0.3 <0.1
1.2 <0.1
4.2 0.1 <0.1
1.0 <0.1 0.4
1.1 <0.1
98.4 1.6
0.4 0.1
1.3
2.5
96.6 <0.1 <0.1
0.1 <0.1 <0.1
68.2 18.4 <0.1
2.9 <0.1 2.9
5.4 <0.1 0.1
1.0 1.2 3.4
100.
1.7
100.
0.8
2.0
ASH*
92.2
98.4
1.0
97.5
99.1
95.7
98.8
95.7
98.6
98.9
99.5
98.7
97.5
3.4
99.9
13.4
94.2
94.5
94.4
100.
98.3
99.2
98.0
-------
TABLE 4-18.
PERCENT DISTRIBUTION.OF THE TRACE ELEMENTS AND MINOR ELEMENTS
WITH THE PRODUCT GAS ROUTED TO THE START-UP FLARE (Cont'd)
ELEMENT
Tin
Titanium
Tungsten
Uranium
Vanadium
Ytterbium
Yttrium
Zinc
Zirconium
TOTAL g/hr
1.4E-1
3.4E2
8.2E-2
1.2
3.1E1
2.3E-1
4.5
2.5
1.4E1
PRODUCT GAS
PARTICULATE
18.9
0.6
8.0
0.5
0.2
1.4
38.5
1.3
% of Total
PRODUCT GAS ORGANIC ASH SLUICE
MODULE COMPOSITE WATER
1.3 53.2
<0.1 <0.1
0.6
0.8
0.1 0.1
2.5 <0.1
<0.1 <0.1
ASH*
26.6
99.4
91.4
98.7
99.7
100.
98.6
58.9
98.7
aEb = a x 10b
*Sampling period two, 1600 to 0300 on 12/13-14/78, ash mass flow = 21g/s
-------
TABLE 4-19.
RELATIVE ELEMENTAL DISTRIBUTION ESTIMATED FOR DISCHARGE
STREAMS IN NORMAL OPERATING CONFIGURATION
oo
o
ELEMENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Bismuth
Boron
Bromine
Cadmium
Calcium
Cerium
Cesium
Chlorine
Chromium
Cobalt
Copper
Dysprosium
Erbium
Eur opium
Fluorine
Gadolinium
Gallium
Germanium
Gold
Hafnium
Holmlum
Iodine
Iridlum
Iron
TOTAL g/hr
8.7E3
3.1E-1
5.9
5.5E2
8.7E-1
4.1E-3
2.2E1
3.2E-1
l.OE-1
5.1E3
1.1 El
8.2E-1
1.8E1
1.1 El
5.5
8.4
6.9E-1
2.9E-1
3.0E-1
2.4E1
4.0E-1
1.3
1.8E-1
9.7E-2
4.0E-1
4.1E-2
8.7E3
TEST BURNER
FLUE GAS
<.l
ssie
35.8
0.5
0.4
3.4
4.5
0.4
0.1
3.3
4.3
8.4
58.5
2.7
9.9
2.5
2.7
39.4
0.1
X of Total
ASH SLUICE
ASH* WATER
98.1 <,1
12.4 <.l
49.5 <.l
96.2 <.l
100.
92.0 <.6
58.9 .2
70.9 <.l
91.7 .1
98.1 <.l
95.5
75.9 10.8
90.2 <.l
40.2 <.l
92.4 <.l
98.8
98.6
98.1
74.2 <.l
98.6
61.8 <.l
52.7
100.
98.6
46.7
. 98.5 <.l
CYCLONE
DUST
1.8
1.7
14.7
3.3
<.l
100.
6.9
37.2
24.5
7.8
1.8
1.2
4.2
1.4
1.2
4.9
1.2
1.4
1.9
15.7
1.4
35.6
44.5
1.4
13.5
1.4
CYCLONE
QUENCH
WATER
<.l
<.l
<.l
.1
.3
.1
<.l
<.l
<.l
4.7
<.l
<•!
<.l
.2
<.l
.1
.4
<•!
-------
TABLE 4-19.
RELATIVE ELEMENTAL DISTRIBUTION ESTIMATED FOR DISCHARGE
STREAMS IN NORMAL OPERATING CONFIGURATION (Cont'd)
oo
ELEMENT
Lanthanum
Lead
Lithium
Lutetium
Magnesium
Manganese
Mercury
Molybdenum
Neodymium
Nickel
Niobium
Osmium
Palladium
Phosphorus
Platinum
Potassium
Praseodymium
Rhenium
Rubidium
Ruthenium
Samarium
Scandium
Selenium
Silicon
Silver
Sodium
Strontium
Sulfur
TOTAL g/hr
1.1E1
9.7E-1
4.8
2.9E-2
1.3E3
2.2E1
5.9E-1
1.9
2.9
8.4
3.1
2.0E2
3.2E-2
7.8E2
1.6
1.5E-3
4.7
1.2
2.0
4.8
1.3E4
1.1E-1
2.0E3
2.0E2
3.9E3
TEST BURNER
FLUE GAS
.2
38.0
.7
.2
1.9
66.0
23.5
<.l
13.2
.1
2.0
100.
1.5
<.l
.2
<.l
66.8
<.l
20.5
.2
<.l
74.0
ASH*
98.8
50.4
97.4
100.
92.0
96.9
28.8
74.7
98.6
86.2
97.7
94.0
96.1
98.3
66.7
98.9
97.8
96.5
29.2
98.1
54.2
89.9
90.3
21.7
% of Total
ASH SLUICE CYCLONE
WATER DUST
<.l 1.0
<.l 11.3
.2 1.7
<.l 7.7
<.l 1.2
<.l 5.2
.4 1.4
1.4
<.l 0.7
<.l 2.2
<.l 4.0
.3 2.2
<.l 1.7
.9
2.2
3.5
<.l 4.0
<.l 1.9
<.l 25.2
2.2 7.5
<.l 9.5
.6 3.8
CYCLONE
QUENCH
WATER
.3
<.l
<.l
<.l
<.l
<.l
<.l
<.l
.3
33.3
<.l
<.l
<.l
.3
<.l
-------
TABLE 4-19.
RELATIVE ELEMENTAL DISTRIBUTION ESTIMATED FOR DISCHARGE
STREAMS IN NORMAL OPERATING CONFIGURATION (Cont'd)
oo
10
ELEMENT
Tantalum
Tellurium
Terbium
Thallium
Thorium
Thulium
Tin
Titanium
Tungsten
Uranium
Vanadium
Ytterbium
Yttrium
Zinc
Zirconium
TOTAL g/hr
<7.8E-2
2.7E-3
9.7E-2
1.2E-2
2.2
3.5E-2
2.6E-1
4.4E2
1.1E-1
1.6
4.0E1
3.0E-1
5.9
4.4
1.9E1
I of Total
TEST BURNER ASH SLUICE
FLUE GAS ASH* WATER
100.
98.6
98.8
100.
14.1 18.7 29.0
.1 98.6 <.l
90.5 .5
<.l 99.2
.2 99.1 <.l
97.3
<.l 96.9
7.2 43.0 <.l
1.6 96.3 <.l
CYCLONE
DUST
100.
1.4
100.
1.2
10.3
1.3
9.0
0.7
0.6
2.7
3.1
49.8
2.1
CYCLONE
QUENCH
WATER
27.9
<.l
<.l
<•!
<.l
<.l
aEb - a x 10b
^Sampling period one, 1430 to 2130 on 12/12/78, ash mass flow
27 g/s
-------
TABLE 4-20. EXTRACTABLE ORGANIC SUMMARY
STREAM
EXTRACTABLE ORGANICS
Concentration
Mass Flow
Product Gas Composite
Test Burner Composite
Gasifier Ash
Gasifier Ash Sluice Water
Cyclone Dust
Cyclone Dust Quench Water
1.57E7 yg/SCM
5.4E3 yg/SCM
6.4E2 yg/g
1.3E5 yg/1
1.3E4 yg/g
6.0E4 yg/1
8.6 g/sec (68 Ib/hr)
3.6E-2 g/sec (0.29 Ib/hr)
1.5E-2 g/sec (0.12 Ib/hr)
<9E-4 g/sec (<7E-3 Ib/hr)
4.9E-2 g/sec(0.4 Ib/hr)
<4E-4 g/sec (<3E-3 Ib/hr)
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
aEb = a x 10b
83
-------
The detailed organic analysis was prioritized on the basis of the weighted
discharge severity (WDS) for each stream from the organic screening
results. Neither the gasifier ash nor the cyclone dust had sufficiently
high WDS factors to be included in the detailed analyses. The specific
compounds that were quantified in the detailed organic analysis were
primarily polynuclear aromatic hydrocarbons (PNA). A total of 3500 yg
PNA/SCM was identified in the product gas and 450 yg PNA/SCM in the test
burner flue gas. The tabulation of compounds specifically identified is
given in Section 4.3.2, while the detailed information concerning the
compounds of interest for which analyses were conducted but for which
identifications were not made, is given in Appendix D, Section 4.0.
4.3.2 Gas Streams
The average gas compositions for the product gas, the test burner
flue gas and the coal bin vent gas are given in Table 4-21. Values are
presented along with the 95% confidence interval (2o) for:
• Fixed gases (H2, 02+ Ar, N2, CO, C02, and CH4)
• Volatile sulfur species (H2S, COS, S02, and CS2)
• Light hydrocarbons (City, C2H4, C2Hg, and €3 to
C$ isomers),
• Volatile nitrogenous species (NH3 and HCN), and
• Metal carbonyls.
The values represent an average of the available data, taken
during the sampling period. Therefore, the calculated confidence intervals
Include not only sampling and analytical variance but also a major contri-
bution from process variability. Gas chromatography samples from the coal
bin vent were not available due to problems encountered in pressurizing the
sample bombs. Ammonia, cyanide, and total volatile sulfur concentrations
were quite low, however, and it may be assumed that the vent gas is
primarily dilution air.
During sampling period one, the sulfur exiting the process in the
test burner flue gas, predominantly S02, was 72% of the sulfur in the
lignite feed, or 0.94 g/s (7.4 Ib/hr). During the secnd sampling period
the product gas contained 71% of the feed sulfur as volatile sulfur '
species, mainly H2S. This corresponded to a sulfur mass flow of 0.74 g/s
(5.8 Ib/hr). The average sulfur mass flow exiting the system was 1 2 g/s
(9.5 Ib/hr).
Nitrogen in the product gas, calculated from the sum of ammonia and
cyanide, Is the equivalent of 0.34 g/sec (2.7 Ib/hr) nitrogen. Based on
the coal nitrogen of 0.91% and a coal feed rate to the gasifier of 170
g/sec (1360 Ib/hr), nitrogen enters the system with the coal at a rate of
1.5 g/sec (11.9 Ib/hr). From these data, the gasifier converts 23% of coal
nitrogen to gaseous components that may contribute to emissions of nitrogen
oxides from combustion.
84
-------
TABLE 4-21. GASEOUS SPECIES ANALYSIS SUMMARY
ANALYSIS
PRODUCT GAS
TEST BURNER
COAL BIN VENT GAS
CO
Major Components (% ± 2o)
C02
H2
02 + Ar
N2
CO
CH,,
Sulfur Species (Vppm ± 2a)
H2S
COS
S02
CS2
Total volatile sulfur
Ci-C6 Hydrocarbons (Vppm ± 2a)
CH*
C2H6
C2H^
Cs + isomers
Ci» + isomers
Cs + isomers
Ce + isomers
Nitrogen Species (Vppm ± 2a)
NH3
HCN
Metal Carbonyls (Vppm)
Fe(CO)5
Ni(CO)i»
9.5 ±
15.4 ±
0.7 ±
46.8 ±
26.3 ±
1.3 ±
1110 ±
143 ±
16 ±
12 ±
990
9590 ±
643 ±
314 ±
445 ±
193 ±
202 ±
197 ±
842 ±
200 ±
NR
1.8f
2.4
0.4
4.1
4.6
0.3
130
16
50
4
15101"
132
68
68
42
392
100
943
90
NR
5.4 ± 2.2
ND*
16.0 ± 4.8
77.8 ± 5.2
ND
ND
NR
ND*
ND*
103 ± 122
2.8 ± 5.1
NR 1.8 ± 0.4
ND
ND
ND
ND*
ND*
ND*
<0.005 °-16 ± °'56
1.0 ± 1.0 0.039 ± 0.031
NR
0.033
<0.001
ND = not detected.
*0ne detectable measurement out of four analyses.
tSamples at the product gas start-up vent; 12/13/78, 1715 hours-2320 hours.
NR = no results.
-------
Partlculates and liquid aerosols were collected from the product
gas start-up vent with a small electrostatic precipitator (ESP) operated at
140°C (285°P). At this temperature, which was^20°C (36°F) lower than the
product gas temperature, 9.2 g/SCM (4.0 gr/SCF) of solids and liquid aero-
sols were collected. Extraction of the collected material indicated that
68Z was methylene chloride soluble. The product gas particulates and
aerosol tars produced a partlculate loading of 16.4 mg/SCM (0.007 gr/SCF)
in the test burner flue gas prior to the scrubber.
The methylene chloride soluble material in the product gas partic-
ulates and tar aerosol represents 5% of the volatile material in the feed
lignite, that is, 3.6 g/s (28 Ib/hr) in the gas from 71 g/s (560 Ib/hr) in
the coal. The extractable organics from the XAD-2 resin catch and conden-
sate of the product gas amount to an additional 6% of the lignite volatile
matter (4.6 g/s, 36 Ib/hr).
The results of analyses for trace and minor elements in samples
from the product gas start up vent and the test burner flue gas are pre-
sented in Table 4-22. The particulate portion of each gas stream includes
all material collected in the ESP at 140°C for the product gas and in the
particulate collection components of ths SASS train at 120°C for the test
burner flue gas. The vapor portions include material collected in the
remaining components of each sampling system (see Appendix B for details).
The gas streams were characterized for a wide range of organic
components, in addition to the Ci-Cg hydrocarbons presented in Table
4-21. Infrared spectra and the distribution in the LC fractions indicate
that the organic species present in the test burner flue gas were more
highly carboxylated than those in the tmcombusted product gas. The aro-
matlcs present were relatively simple ring systems, and the fractions
contained fewer Indications of nitrogenous compounds than the product gas.
Ben*o(a)anthracene was specifically identlfieo in the test burner flue gas
at 450 yg/SCM. Benzo(a)pyrene, dlbenzo(a,h)anthracene, and 7,12 dimethyl-
beoto(a)anthracene were present in the product gas but did not appear in
the fraction of the test burner flue gas that was analyzed.
The specific compounds of environmental concern which were Iden-
tified In the product gas are listed In Table 4-23. Polynuclear aromatics
which have a high potential for causing adverse environmental effects, were
identified and quantified at a combined concentration of over 3500 yg/SCM.
The organic character of the product gas particulate extract is
quite similar to the product gas organic module composite of the condensate
and XAD-2 resin extracts. This is consistent with the tarr> nature of the
particulate catch which included aerosol tars removed from the gas stream
by the ESP and organics condensing in the ESP at 140°C (285°F). The
unfractionated samples of the ESP particuates and the organic module conden-
sables are heavily aliphatic, but contain phenolics and nitrogenous
86
-------
TABLE 4-22. TRACE AND MINOR ELEMENT COMPOSITIONS OF PRODUCT GAS AND TEST BURNER FLUE GAS
00
ELEMENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Bismuth
Boron
Bromine
Cadmium
Calcium
Cerium
Cesium
Chlorine
Chromium
Cobalt
Copper
Dysprosium
Erbium
Europium
Fluorine
Gadolinium
Gallium
Germanium
Gold
Hafnium
Holmium
Iodine
Iridium
Iron
PRODUCT
PARTICULATE
Ug/SCM
27,000
<380
370
7,600
2.6
2.6
550
130
270
150,000
51
2.3
>3,200
88
14
270
1.7
0.64
0.97
1,300
1.9
23
7.2
2.9
0.97
<4
< 33, 000
GAS
VAPOR
Ug/SCM
0.42
<16
>18
21
>13
0.88
460
0.88
16
15
>0.8
11
9.2
13
460
TEST BURNER FLUE GAS
TOTAL
Ug/SCM
27,000
<400
>390
7,600
2.6
2.6
>560
130
270
150,000
53
2.3
>3,200
100
>15
280
1.7
0.64
0.97
1,300
1.9
36
7.2
2.9
0.97
<4
<33,000
PARTICULATE
ug/scM
1.9
<0.3
0.40
>120
0.16
0.096
0.024
>120
0.34
0.0066
0.99
0.59
0.14
1.2
1.0
0.29
0.20
>120
VAPOR
Ug/SCM
14
<11
86
4.6
3.8
0.34
>0.2
660
0.28
1.1
32
36
130
8.1
99
<1
0.66
190
TOTAL
Ug/SCM
16
<11
86
>120
4.0
0.44
>0.2
>780
0.62
1.1
33
37
130
9.3
100
<1.3
0.20
0.66
>310
-------
TABLE 4-22. TRACE AMD MINOR ELEMENT COMPOSITIONS OF PRODUCT GAS AND TEST BURNER FLUE GAS (Cont'd)
00
oa
ELEMENT
Lanthanum
Lead
Lithium
Lutetium
Magnesium
Manganese
Mercury
Molybdenum
Neodymium
Nickel
Niobium
Osmium
Palladium
Phosphorus
Platinum
Potassium
Praseodymium
Rhenium
Rubidium
Ruthenium
Samarium
Scandium
Selenium
Silicon
Silver
Sodium
Strontium
Sulfur
PRODUCT
P ARTICULATE
yg/SCM
36
130
120
. 39,000
120
6,500
9.7
9.7
110
13
>3,200
>3,200
6.4
<0.3
<7
6.4
19
15,000
>6,700
110
21,000
3,900
>3,500
GAS
VAPOR
yg/SCM
1.3
29
6.3
25
7.1
3.3
9.6
94
69
2.0
>3
330
30
31
4.2
860
TEST BURNER FLUE GAS
TOTAL
yg/SCM
37
160
130
39,000
130
6,500
9.7
9.7
120
13
>3,300
>3,300
6.4
<0.3
<9
6.4
19
15,000
>7,000
140
21,000
3,900
>4,300
P ARTICULATE
Ug/SCM
0.40
3.2
1.3
>120
0.44
0.0011
<0.2
0.025
1.4
0.037
6.8
>120
0.013
0.15
<0.01
<0.3
>120
0.92
>120
3.5
>120
VAPOR
yg/SCM
0.44
12
<0.07
16
17
16
18
44
>0.07
160
1.3
370
<0.2
<0.04
<130
170
*
23
2.0
*
TOTAL
yg/SCM
0.84
15
<1.4
>130
17
16
18
0.025
45
>.10
170
1.3
>490
0.013
<.35
<.05
<130
>290
0.92*
>140
5.5
>120*
-------
TABLE 4-22. TRACE AND MINOR ELEMENT COMPOSITIONS OF PRODUCT GAS AND TEST BURNER FLUE GAS (Cont'd)
oo
v£>
ELEMENT
Tantalum
Tellurium
Terbium
Thallium
Thorium
Thulium
Tin
Titanium
Tungsten
Uranium
Vanadium
Ytterbium
Yttrium
Zinc
Zirconium
PRODUCT
PARTICULATE
yg/SCM
0.97
0.64
3.2
6.4
<0.3
13
940
3.2
3.2
36
30
480
87
GAS
VAPOR
yg/scM
0.88
24
4.6
0.92
31
0.25
TOTAL
yg/SCM
0.97
0.64
3.2
6.4
<0.3
14
960
3.2
7.8
37
30
510
87
TEST BURNER
PARTICULATE
yg/SCM
0.074
2.7
<-04
0.15
<0.02
0.99
0.25
FLUE GAS
VAPOR
yg/SCM
1.4
18
3.4
12
12
TOTAL
yg/SCM
1.5
21
<.04
3.6
<0.02
13
12
impinger solution.
Not listed: product gas <.l yg/SCM
test burner flue gas <.01 yg/SCM
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
-------
TABLE 4-23. ORGANIC COMPOUNDS IDENTIFIED FROM THE PRODUCT GAS BY SIM GC/MS
COMPOUND IDENTIFIED
CONCENTRATION
yg/SCM
SAMPLE-
LC FRACTION
Polychlorlnated blphenyls
Benzo(a)anthracene
Benzo(b)fluoranthene
Biphenyl
7,12-Dimethylbenzo(a)anthracene
Benzo(c)phenanthrene
Benzo(a)pyrene
3-Methyl chloanthrene
Dlbenzo(a,h)anthracene
Dinitrotoluenes
Dlnitrocresol
DlhydroacridineO
£15.0
1.8E3*
3.8E2*
5.1E3
1.6E2*
1.0E3*
1.9E2
4.7
6.1
2.2E3
1.8E3
1.1E2
PGP-2; PGC-2
PGP-2,3; PGC-2,3
PGP-2,3; PGC-3
PGP-3; PGC-3
PGP-3
PGP-3; PGC-3
PGP-3
PGP-3
PGP-3
PGP-4
PGP-5; PGC-5
PGP-5,6
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
PGP - Product Gas Partlculate
PGC • Product Gas Organic Module Composite
A a£b - a x 10
* includes possible coelutlng isomers
t based on PCB-3 Cl
0 standard unavailable, based on dihydrophenanthridine
90
-------
material. They have the same infrared profiles and the fractionations are
quite similar. The ESP catch contains more material in LC-2 than does the
organic module composite, which indicates more light aromatics, and rela-
tively non-polar polynuclear aromatics. The mass distributions in LC-6 and
LC-7 are reversed between the two samples, the module composite having
significantly stronger absorbances in the most polar fraction (LC-7) than
in LC-6.
4.3.3 Liquid Streams
Two wastewater streams from the Fort Snelling gasifier were
characterized: gasifier ash sluice water and cyclone dust quench water.
Both were comprised of plant service water that had been in contact with
solids from the process. The suspended solids (i.e. , ash and cyclone dust)
were removed by filtration during sampling, so the water samples contained
only dissolved components. Table 4-24 presents the results of a general-
ized characterization of the two wastewaters for many of the parameters
associated with water quality. Leachate solutions from the associated
gasifier solid wastes obtained by the RCRA procedures (Ref. 1) were
analyzed for most of these parameters and are included here for comparison.
Trace and minor elemental concentrations for the plant service
water, ash sluice water, and cyclone dust quench water are provided in
Table 4-25. Generally, elements which appeared at higher concentration in
the solids are found to have dissolved in the associated sluice or quench
water. Solubilities of various elements in the solids are discussed further
in conjunction with the results of the RCRA leaching tests in Section
3.A.A.
The gasifier ash sluice water was not fractionated by liquid
chromatography during the organic screening. Comparison of the infrared
spectra of the sluice water and the ash extracts indicates that the extrac-
table organics in the two samples are quite similar. The extractable
organics in both are approximately 90% GRAV material having boiling points
greater than 250°C. The organics present in the ash sluice water at 125
mg/1 are probably heterocyclic sulfur compounds, carboxylates, and some
phenolates. A colorimetric phenol value of 0.4 mg/l phenols was also
obtained on the ash sluice water.
The cyclone dust quench water was not taken through the column
chromatography step of the organic screening. Due to the uncertainty in
the flow rate data for this stream, a weighted discharge severity priori-
tization could be in error. The cyclone dust quench water contained 59
mg/1 extractable organics, approximately half the total organic loading
found in the gasifier ash sluice water. These organics, from the infrared
analysis of the unfractionated sample, are primarily carboxylic acids and
phenols. This is borne out by the colorimetric phenol determination of 9.6
mg/l phenols.
91
-------
TABLE 4-24. WASTEWATER AND RCRA LEACHATE
GENERAL COMPOSITION SUMMARY
pH
TDS
TSS
Sulfate
Sulfite
Nitrate
Nitrite
Phosphate
Cyanide
Ammonia
COD
BOD
Phenol
Chloride
Fluoride
TOG
GASIFIER ASH
SLUICE WATER
9.3
4300
NA
2860
47
3
< 0.01
< 0.1*
< 0.02
5.4
76
28-64f
0.36
78
0.87
16
GASIFIER ASH
LEACHATE
4.13
2130
36
NA
<10
< 0.25
< 0.01
0.1
< 0.02
< 0.007
1710
2970
0.002
NA
NA
< 1
CYCLONE DUST
LEACHATE
4.04
2280
17
NA
<10
< 0.25
< 0.01
0.2
0.05
1.8
1410
3150
0.38
NA
NA
< 1
CYCLONE DUST
QUENCH WATER
10.0
390
NA
55
12
< 0.5*
< 0.01
0.1*
0.36
0.97
800
62-85f
9.8
34
2.0
185
*possible interference.
^possible toxic effects
NA - not analyzed.
All concentrations in pg/ml except pH.
92
-------
TABLE 4-25. TRACE AND MINOR ELEMENTS IN ASH SLUICE WATER, CYCLONE
QUENCH WATER, AND SERVICE WATER
SERVICE ASH SLUICE
ELEMENT WATER WATER
Aluminum 100 11
Antimony
Arsenic <1
Barium 30
Beryllium
Bismuth
Boron 10 4
Bromine 20
Cadmium
Calcium MC 220
Cerium 4
Cesium 2
Chlorine 200 78
Chromium 10
Cobalt <4
Copper 10
Dysprosium
Erbium
Europium
Fluorine 400
Gadolinium
Gallium
Germanium
Gold
Hafnium
Holmium
Iodine
Iridium
iron 300 1
Lanthanum
Lead
Lithium 10
Lutetium
Magnesium 5,000 11
Manganese 6
Mercury NR
Concentrations in yg/1.
Not listed is <1 yg/1.
,0002
23
n
3.33
f)
1302
_ _ 9
,6002
20
<2
,0002
2
,000'
72
<2
172
1
8701
8
,2002
<1
8
400
,0002
22
1.43
CYCLONE
QUENCH
WATER ELEMENT
11, OOO2 Molybdenum
Neodymium
1203 Nickel
n
570^ Niobium
Osmium
Palladium
990 Phosphorus
40 Platinum
<52 Potassium
54,0002 Praseodymium
2 Rhenium
4 Rubidium
34, 000 1 Ruthenium
<52 Samarium
9 Scandium
122 Selenium
Silicon
Silver
Sodium
2,0001 Strontium
Sulfur
20 Tantalum
7 Tellurium
Terbium
Thallium
Thorium
6 Thulium
Tin
t\
4,900^ Titanium
Tungsten
99 2 Uranium
40 Vanadium
Ytterbium
11, 000 2 Yttrium
<12 Zinc
0.43 Zirconium
MC = >10,000 yg/1.
NR = not reported.
SERVICE ASH SLUICE
WATER WATER
310
20 20
2
50 400
7,000 MC
1
2 40
<2
203
900 300
<1 1
7,000 1,700,0002
40 4.0002
3,000 970, 000 *
3,0002
<60 442
20
2 772
40 442
<4 2
CYCLONE
QUENCH
WATER
4
* O
<202
400
MC
20
6
2,000
2
220, OOO2
1,1002
23, OOO1
2,9002
1802
152
2
352
5
All analyses by SSMS except:
^nion/cation analysis
2ICP
3AAS
93
-------
The gasifier ash leachate and the cyclone dust leachate were not
subjected to any organic screening analysis. The total organic carbon
(TOG) content for either sample was less than 1 ppm. This low TOG implies
that the organics present in these solids do not leach under the Resource
Conservation and Recovery Act procedures (Ref. 1) even though an
appreciable amount of organic mass can be solvent extracted.
4.3.4 Solid Streams
The composition of the two solid wastes from the gasifier, gasifier ash
and cyclone dust are primarily dependent on the coal composition and effi-
ciency of gasifier operation (i.e., the extent of conversion of carbon-
aceous materials to gases). Table 4-26 presents the results of proximate
and ultimate analyses of the feed coal, gasifier ash, and cyclone dust.
Also included is a mineral analysis of the ash residue from each material
resulting from elemental analysis of the ash residue, and mathematical
conversion of the elemental concentrations to those for their equivalent
oxides. The carbon contents of the gasifier ash and cyclone dust give an
indication of the gasifier operating efficiency during the sampling period.
Appendix D includes the results of proximate/ultimate analyses of six indi-
vidual grab samples of the coal. These data give a measure of the vari-
ability of the coal composition over the sampling period. The data pre-
sented in Table 4-26 are for a composite coal sample consisting of portions
of five of these individual samples.
The trace and minor element concentrations in the gasifier ash and
cyclone duct follow a general trend that the more volatile metals and those
that form volatile compounds appear at higher levels in the cyclone dust.
Table 4-27 presents a side-by-side presentation of elemental concentrations
in the coal and the two solid waste streams. Enrichment factors were calcu-
lated from the ratio of the solid waste concentration to the concentration
in the coal. Table 4-28 presents these ration for the cyclone dust and the
gasifier ash. For comparison, the ratios are also presented for the ash
residue contents of the gasifier ash and cyclone dust. The observed ele-
ment enrichment may be the result of the volatilization of these elements
or their compounds in the gasifier. This volatilization provides the
mechanism for the selective partitioning of elements during the distri-
bution of the ashed material between the cyclone dust and the gasifier ash.
Figures 4-2, 4-3, 4-4, and 4-5 present the enrichment ratios ver-
sus the boiling points of the elements. Some degree of enrichment (concen-
tration increase relative to the coal) would be expected simply due to a
loss of carbonaceous material during gasification. The enrichment due to
this source is estimated by calculating enrichment ratios fiom the ash
(mineral matter) contents of the coal gasifier ash and cyclone dust. These
"ash residue" enrichment ratios are shown as horizontal lines in each
figure. Individual elements whose enrichment ratios follow those of the
ash residue may be assumed to be non-volatile and physically distributed
94
-------
TABLE 4-26. CHARACTERIZATION ANALYSIS RESULTS FOR SOLID STREAMS
GASIFIER ASH
Proximate (as received)
% Moisture
% Ash
% Volatiles
% Fixed Carbon
Btu
% Sulfur
Ultimate (dry basis)
% Carbon
% Hydrogen
% Nitrogen
% Chlorine
% Sulfur
'% Ash
% Oxygen (diff)
Mineral Composition of Ashed Residue
% Silica, Si02
Alumina, A1203
Titania, Ti02
Ferric oxide, Fe203
Lime, CaO
Magnesia, MgO
Potassium oxide, K20
Sodium Oxide, Na20
Sulfur Trioxide, S03
Phosphorus pentoxide, P205
Strontium oxide, SrO
Barium oxide, BaO
Manganese oxide, MnsOi*
1.01
73.66
6.49
18.84
3709
1.08
24.64
0.41
0.17
0.02
1.09
74.41
0.60
39.18
22.38
1.02
13.40
9.02
2.89
1.39
3.26
3.43
0.61
0.31
0.83
0.04
CYCLONE DUST
0.44
18.89
24.30
56.37
10670
1.50
67.18
2.32
0.93
0.03
1.51
18.97
9.06
20.71
12.21
0.35
6.95
21.55
6.82
0.81
7.83
17.02
0.70
0.85
2.01
0.01
COAL FEED
4.19
10.45
40.17
45.19
10036
0.58
60.06
4.41
0.87
0.03
0.58
10.45
19.41
30.21
14.93
0.46
6.36
16.39
6.46
1.49
9.00
10.93
0.63
0.72
1.32
0.01
95
-------
TABLE 4-27. TRACE AND MINOR ELEMENTAL RESULTS FOR COAL, GASIFIER ASH, AND CYCLONE DUST
ELEMENT
Ash
Aluminum
Antimony
Arsenic
Barium
Beryllium
Bismuth
Boron
Bromine
Cadmium
Calcium
Cerium
Cesium
Chlorine
Chromium
Cobalt
Copper
Dysprosium
Erbium
Europium
Fluorine
Gadolinium
Gallium
Germanium
Gold
Hafnium
Holmlum
Iodine
Iridium
Iron
Lanthanum
Lead
Lithium
Lutetium
Magnesium
Manganese
Mercury
GASIFIER
ASH
74.41%2
88, OOO2
<0.4!
30 1
5,5002
9
2103
2
0.8
48, OOO2
110
8
1502
100
23
81
7
3
3
190
4
9
1
1
4
0.2
90, OOO2
110
5
48
0.3
13, OOO2
2202
1.71
CYCLONE
DUST
18.97%2
12, OOO2
<0.41
63
1.3002
0.4
0.3
1103
9
2
29, OOO2
15
0.7
572
11
5
30
0.6
0.3
0.4
280
0.4
33
6
0.4
0.4
9.2002
8
8
6
7.8002
192 i
COAL
10.91%2
8.6002
0.06
6.51
1.3002
0.4
25
1
0.4
13, OOO2
8
0.9
332
10
2
8
0.2
210
0.4
19
0.7
0.2
4.9002
6
2
5
4.2002
II2
0.391
ELEMENT
Molybdenum
Neodymium
Nickel
Niobium
Osmium
Palladium
Phosphorus
Platinum
Potassium
Praseodymium
Rhenium
Rubidium
Ruthenium
Samarium
Scandium
Selenium
Silicon
Silver
Sodium
Strontium
Sulfur
Tantalum
Tellurium
Terbium
Thallium
Thorium
Thulium
Tin
Titanium
Tungsten
Uranium
Vanadium
Ytterbium
Yttrium
Zinc
Zirconium
GASIFIER
ASH
15
30
75
31
2, OOO2
8.6002
16
47
13
20
15 l
140, OOO2
0.6
18, OOO2
1,9002
8.8002
<0.8
1
23
0.4
0.5
4,5002
1
16
410
3
59
20
180
CYCLONE
DUST
2
3
4
5
5902
1.3002
2
3
2
5
141
18, OOO2
2
11, OOO2
1,4002
11, OOO2
0.2
0.1
0.9
2
2
4002
<0.7
0.9
19
0.6
13
160
29
COAL
1
1
5
2
2902
1.4002
0.7
9
1
5
I1
15, OOO2
1
7.3002
6702
4.1002
0.1
-------
TABLE 4-28.
ENRICHMENT RATIOS FOR THE GASIFIER ASH
AND CYCLONE DUST
ELEMENT GASIFIER ASH
• —
Ash
Antimony
Arsenic
Barium
Beryllium
Bismuth
Boron
Bromine
Cadmium
Calcium
Cerium
Cesium
Chlorine
Chromium
Cobalt
Copper
Dysprosium
Erbium
Europium
Fluorine
Gadolinium
Gallium
Germanium
Gold
Hafnium
Holmium
Iodine
Iridium
Iron
Lanthanum
Lead
Lithium
Lutetium
Magnesium
Manganese
Mercury
enrichment Ratio
6.8
10
<6.7
4.6
4.2
22
8.4
2.0
2.0
3.7
14
8.9
4.5
10
12
10
>70
>30
15
0.9
10
0.5
1.4
>40
1.0
18
18
2.5
9.6
>3
3.1 ,
20
4.3
= element
CYCLONE DUST ELEMENT GASIFIER ASH
1.7
1.4
<6.7
9.7
1.0
1.0
>3
4.4
9.0
5.0
2.2
1.9
0.8
1.7
1.1
2.5
3.8
>6
>3
2
1.3
1.0
1.7
8.6
>4
2.0
1.9
1.3
4.0
1.2
1.9
1.7
>5.9
concentration
Molybdenum
Neodymium
Nickel
Niobium
Osmium
Palladium
Phosphorus
Platinum
Potassium
Praseodymium
Rhenium
Rubidium
Ruthenium
Samarium
Scandium
Selenium
Silicon
Silver
Sodium
Strontium
Sulfur
Tantalum
Tellurium
Terbium
Thallium
Thorium
Thulium
Tin
Titanium
Tungsten
Uranium
Vanadium
Ytterbium
Yttrium
Zinc
Zirconium
(ug/g) in effluent
15
30
15
15
6.9
6.1
23
5.2
13
4
15
9.3
0.6
2.5
2.8
2.1
10
>23
>4
14
>i6
19
>30
15
6.7
10
stream
CYCLONE DUST
2.0
3.0
0.8
2.5
2.0
0.9
2.9
0.3
2
1
14
1.2
2.0
1.5
2.1
2.7
>2
1
>9
>2
1.3
>1
0.9
>6
3.3
53
1.7
element concentration (yg/g) in coal
97
-------
20 -
oo
10 -
S 6.8
Mn
n
Ba
N. sr
on n
Fe
Al
si n
Ti
0°C
1000°C 2000°C
ELEMENTAL BOILING POINT
3000°C
Ash Residue
4000°C
Figure 4-2. Gaslfler Ash Major Component Enrichment Ratio vs.
Elemental Boiling Point
-------
VO
VO
o
M
H
u
20 -
10 .
6.8
Se
As
Sr
On
-
Tt
Ni
Sm
Sb
Cd
n
Pb
(1
Cr Cu
A Sn
nil
B
1
Co
Ge
n
V
U
_-
o°c
2000°C 3000°C
ELEMENTAL BOILING POINT
Ash
Residue
4000°C
Figure 4-3. Gasifier Ash Trace Element Enrichment Ratio vs.
Elemental Boiling Point
-------
§ I
20 H
10 -I
1.7
0°C
K Na
Mg Sr Ca
Ba
Mn Si Al
II
1000°C 2000°C
ELEIffiNTAL BOILING POINT
Fe Ti
n
3000°C
Dust Residue
4000°C
Figure 4-4. Cyclone Dust Major Component Enrichment Ratio vs.
Elemental Boiling Point
-------
20 .
o
M
H
Se
w
10 .
1.7-
As
Br
r
i
n
0
Sb
Cd
•
Pb
•
Sm A
Ge
Sn B „
r
m
Cr
n
cu
Ni
n
n* cn u n
lin 0 n H
o°c
1000°C 2000°C
ELEMENTAL BOILING POINT
3000°C
Dust
Residue
AOOO°C
Figure 4-5. Cyclone Dust Trace Element Enrichment Ratio vs.
Elemental Boiling Point
-------
with the mineral matter In the coal. Elements deviating significantly
from the ash residue are exhibiting some additional mechanism of mobility
in the process. The most likely mechanism is volatiliztion resulting in
depletion in the gasifier ash and increased concentrations in the cyclone
dust. A general upward trend of enrichment with increasing boiling point
is seen in the gasifier ash. Anomalies in the trend are present for
silver, tin, and germanium which are depleted in the ash. These metals
form hydrides or volatile organometallic compounds that would be found
condensed in the cyclone dust. No unequivocable trend is seen in the
cyclone dust. However, germanium and tin, in addition to lead, antimony
arsenic, selenium, and cadmium show significant enrichment in the cyclone
dust. In general, elements with lower boiling points have higher enrich-
ment in the cyclone dust.
The volatilized elements from the lignite feed will remain
gaseous, condense partially, or condense completely. Condensation takes
place by nucleation or deposition on available surfaces. Nucleation re-
sults in small particles if the residence time in the system is relative-
ly low, and deposition is surface area dependent. Either phenomena may
result in enriched elemental concentrations for those volatilized elements
that condensed in the small partlculate trapped by the cyclone. For those
elements remaining In the gaseous phase, discharge will be through the
gaseous emission streams and product gas. Partial or complete condensation
will lead to increased concentration in the cyclone dust. The nonvolatil—
Ized elements will then be present in the gasifier ash at higher concentra-
tions than in the cyclone dust.
Components present in the gasifier ash and cyclone dust are
dissolved by the sluice or quench water and constitute a potential -water
pollution problem. In addition, materials may be leached from the dis-
carded solid wastes by runoff rain water. The potential for contamination
of surface and groundwater by the leachates aay impose restrictions on the
disposal of the solids. The extraction procedures specified in the RCRA
were used to estimate the leaching potential of the two solid wastes. The
results of characterization of these leachate solutions for general water
quality are presented In Table 4-24. Tables 4-29 and 4-30 provide the
concentrations of trace and minor elements in the leachate solutions from
the gasifier ash and cyclone dust, respectively, and the blank extraction
solution. The trace and minor element compositions of the sluice and
quench waters are also presented for comparison. For many elements the
lower pH of the RCRA extraction solution (°o5 versus 'vlO) resulted in higher
concentrations In the leachates than in the corresponding process waste-
water.
102
-------
TABLE 4-29 . GASIFIER ASH SLUICE WATER AND RCRA LEACHATE ELEMENTAL COMPOSITION
ELEMENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Bismuth
Boron
Bromine
Cadmium
Calcium
Cerium
Cesium
Chlorine
Chromium
Cobalt
Copper
Dysprosium
Erbium
Europium
Fluorine
Gadolinium
Gallium
Germanium
Gold
Hafnium
Holmium
Iodine
Iridium
Iron
Lanthanum
Lead
Lithium
Lutetium
Magnesium
Manganese
Mercury
ASH SLUICE
WATER
(pH=9.3)
11,OC02
23
Q
3.33
n
1302
A
4.6002
20
<2
220, OOO2
2
78, OOO1
72
<2
172
8701
8
1,2002
<1
8
400
t\
11, OOO2
22
1.43
ASH
LEACHATE
(pH-4.3)
100
Q
<603
n
193
1,000
80
4
<7
MC
4
1
50
1
7
100
3,000
1
2
2,000
4
7
6
MC
500
<0.63
LEACHATE
BLANK
(pH=2.01)
30
3
<603
3
<53
200
600
.60
1
8
40
60
10
MC
3
<0.23
ASH SLUICE
WATER
ELEMENT (pH=9.3)
Molybdenum
Neodymium
Nickel
Niobium
Osmium
Palladium
Phosphorus
Platinum
Potassium
Pras eo dymium
Rhenium
Rubidium
Ruthenium
Samarium
Scandium
Selenium
Silicon
Silver
Sodium 1
Strontium
Sulfur
Tantalum
Tellurium
Terbium
Thallium
Thorium
Thulium
Tin
Titanium
Tungsten
Uranium
Vanadium
Ytterbium
Yttrium
Zinc
Zirconium
3102
20
2
400
MC
1
40
Q
20 3
300
1
,700, OOO2
4, OOO2
970, OOO1
n
3, OOO2
442
20
772
442
2
ASH
LEACHATE
(pH=4,3)
10
40
70
MC
20
. q
14 3
MC
2,000
6,000
6,000
<8
100
<6
7
7
100
5
LEACHATE
BLANK
(pH=2.01)
7
20
700
O
123
80
300
20
80
<20
10
<20
40
Concentration in yg/1.
Not listed <1 yg/1.
MC = >10,000 yg/1.
All analyses by SSMS except:
1Anion/cation
2ICP
3AAS
103
-------
TABLE 4-30.
CYCLONE DUST QUENCH WATER AND RCRA
LEACHATE ELEMENTAL COMPOSITION
ELEMENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Bismuth
Boron
Bromine
Cadmium
Calcium
Cerium
Cesium
Chlorine
Chromium
Cobalt
Copper
Dysprosium
Erbium
Europium
Fluorine
Gadolinium
Gallium
Germanium
Gold
Hafnium
Holmium
Iodine
Irldium
Iron
Lanthanum
Lead
Lithium
Lutetium
Magnesium
Manganese
Mercury
QUENCH
WATER
(pH=10.0)
ll.OOO2
<603
1203
5702
9902
40
<5a
54, 000 a
2
4
34, 000 *
<5a
9
12a •
2,000*
20
7
6
4,900a
99a
40
ll,000a
1,000
8
333
1,000
100
<20
MC
i
4
100
1
2
6
4,000
2
600
8
40
MC
100
<0.33
LEACHATE QUENCH
BLANK WATER
(pH=2.01) ELEMENT (pH=10.0)
30
<603
<53
200
600
60
1
8
40
60
10
MC
3
<0.23
Molybdenum
Neodymium
Nickel
Niobium
Osmium
Palladium
Phosphorus
Platinum
Potassium
Praseodymium
Rhenium
Rubidium
Ruthenium
Samarium
Scandium
Selenium
Silicon 2
Silver
Sodium 220
Strontium 1
Sulfur 23
Tantalum
Tellurium
Terbium
Thallium
Thorium
Thulium
Tin 2
Titanium
Tungsten
Uranium
Vanadium
Ytterbium
Yttrium
Zinc
Zirconium
4
<202
400
MC
20
6
,000
2
,0002
,1002
,000l
,9002
ISO2
152
2
352
5
DUST
LEACHATE
(pH=4.04)
2
10
400
MC
20
6
MC
>3,000
7,000
>6,000
<10
2
50
<10
3
70
30
i IT 1 •
LEACHATE
BLANK
(pH»2.01)
7
20
700
,
12»
80
**v
300
•^>*Vr
20
^\*
80
<2Q
10
<2O
•^*vl ;
An
*+\f
Concentrations in yg/1.
Not listed <1 JJg/1.
MC = >10,000 yg/1.
All analyses by SSMS except:
^nion/cation
2ICP
3AAS
104
-------
Tables 4-31 and 4-32 present the total element concentration and
the total soluble element concentrations for gasifier ash and cyclone dust.
Total concentration was calculated from the solid waste composition (Table
4-27), the solid-to-liquid ratio for the process wastewaters (from flow
rates in Table 2-1), and the wastewater compositions (Table 4-25). Total
solubles per unit mass of solid for each element was calculated from the
wastewater and leachate compositions (Tables 4-29 and 4-30), and the solid-
to-liquid ratios for these process waters and the RCRA extraction
procedure. The calculations were performed as follows:
Total element = A + B
Total soluble = B + C
where: A = yg/g of each element in solid
B = yg/1 in wastewater X P 1/s wastewater flow "I
L yg/s solid flow J
C - ug/1 in leachate X P 21 leachate 1
[ 100 g solid J
In most cases, the soluble portion of each element is less than one percent
of the total originally available in the dry solid.
The gasifier ash contained 640 yg/g of extractable organics. From
the mass distribution in the liquid chromatography (LC) fractions, the
majority of these organics were non-polar, non-volatile aliphatics. Some
heterocyclic material and some carbonyl containing material were present.
There is very little evidence of aromatic character in the sample. The
halogen content of the unfractionated material appeared to be 300 Vg/g, but
this is probably due to an interference; the highest halogen content mea-
sured in an LC fraction was ^5 yg/g. From the halogen specific screening
results of the LC fractions, the ^300 yg/g halogenated value for the un-
fractionated samples could be in error by an order of magnitude.
The cyclone dust contained 13,000 yg/g of extractable organics.
Upon fractionation, the majority of this material was found in LC-6 and
LC-1, and was comprised of phenols, heterocyclic nitrogen compounds or
amines; and non-polar, non-volatile aliphatics. The chromatographable
halogen content was ^35 yg/g.
105
-------
TABLE 4-31. GASIFIER ASH TOTAL ELEMENT AND TOTAL SOLUBLE ELEMENT CONCENTRATIONS
ELEMENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Bismuth
Boron
Bromine
Cadmium
Calcium
Cerium
Cesium
Chlorine
Chromium
Cobalt
Copper
Dysprosium
Erbium
Europium
Fluorine
Gadolinium
Gallium
Germanium
Gold
Hafnium
Holmium
Iodine
Irldium
Iron
Lanthanum
Lead
Lithium
Lutetium
Magnesium
Manganese
Mercury
TOTAL
88,000
<0.4
30
5,500
9
<0.1
210
2
0.8
48,000
110
8
170
100
23
81
7
3
3
190
4
9
1
<0.1
1
4
0.2
<0.1
90,000
110
5
48
0.3
13,000
220
1.7
SOLUBLE
4.4
<0.24
0.24
17
<0.004
2.8
0.07
<0.12
<250
0.06
0.005
20
0.006
0.12
1.9
<0.004
<0.004
<0.004
60
<0.004
0.006
0.024
<0.004
<0.004
<0.004
39
0.064
0.002
0.21
<0.004
<43
10
<0.009
PERCENT
SOLUBLE
0.005
<1
0.08
0.3
<0.05
1.3
3.5
<1.5
<0.5
0.06
0.05
12
0.006
0.5
2.3
<0.006
<0.1
<0.1
31
<0.1
0.07
2.4
<0.4
<0.1
<2
0.04
0.06
0.04
0.4
<1.3
<0.3
4.5
<0.5
ELEMENT
Molybdenum
Neodymium
Nickel
Niobium
Osmium
Palladium
Phosphorus
Platinum
Potassium
Praseodymium
Rhenium
Rubidium
Ruthenium
Samarium
Scandium
Selenium
Silicon
Silver
Sodium
Strontium
Sulfur
Tantalum
Tellurium
Terbium
Thalliuu
Thorium
Thulium
Tin
Titanium
Tungsten
Uranium
Vanadium
Ytterbium
Yttrium
Zinc
Zirconium
TOTAL
15
30
75
31
<0.1
<0.1
2,000
0.1
>8,600
16
<0.1
47
<0.1
13
20
15
140,000
0.6
18,400
1,900
9,000
<0.8
<0.1
1
<0.1
23
0.4
1.3
4,500
1
16
410
3
59
20
180
— i L_|
SOLUBLE
— — — ,
0.26
<0.004
0.69
<0.005
1.2
<200
<0.004
0.39
<0.004
0.004
0.09
200
<0.004
480
120
370
<0.004
<0.004
<0.0003
<0.004
0.77
1.9
0.009
<0.0003
0.14
<0.004
0.12
1.4
0.084
••• .M
PERCENT
SOLUBLE
• — _
1 ft
x .0
-------
TABLE 4-32 . CYCLONE DUST TOTAL ELEMENT AND TOTAL SOLUBLE ELEMENT CONCENTRATIONS
=_..
ELEMENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Bismuth
Boron
Bromine
Cadmium
Calcium
Cerium
Cesium
Chlorine
Chromium
Cobalt
V^ Vh? *^^ ™
Copper
Dysprosium
Erbium
Europium
Fluorine
Gadolinium
Gallium
Germanium
Gold
Hafnium
Holmium
Iodine
Itidium
Iron
Lanthanum
Lead
Lithium
Lutetium
Magnesium
Manganese
Mercury
TOTAL
12,000
<0.5
63
1,300
0.4
0.3
112
9
2
29,000
15
0.7
120
11
5
30
0.6
0.3
0.4
280
0.4
33
6
<0.1
<0.1
0.4
0.4
<0.1
9,200
8
8
6
<0.1
7,800
19
<2.3
— — .. . _ L g. • =
SOLUBLE
40
<0.1
0.8
18
<0.006
<0.006
3.8
<0.46
<0.13
>290
0.008
0.07
64
<0.013
0.041
0.022
<0.006
<0.006
<0.006
83
<0.006
0.04
0.037
<0.006
0.015
20
<0.006
0.18
0.86
>60
1.9
<0.004
PERCENT
SOLUBLE
0.3
1.2
1.4
<1.5
<2
3.4
5
<0.7
>1
0.05
10
53
<0.12
0.8
0.07
<2
<1.5
30
<1.5
0.12
0.6
<1.5
3.8
0.2
<0.08
2.3
14
>0.8
10
ELEMENT
Molybdenum
Neodymium
Nickel
Niobium
Osmium
Palladium
Phosphorus
Platinum
Potassium
Praseodymium
Rhenium
Rubidium
Ruthenium
Samarium
Scandium
Selenium
Silicon
Silver
Sodium
Strontium
Sulfur
Tantalum
Tellurium
Terbium
Thallium
Thorium
Thulium
Tin
Titanium
Tungsten
Uranium
Vanadium
Ytterbium
Yttrium
Zinc
Zirconium
TOTAL
2
3
4
5
<0.1
<0.1
590
<0.1
>1,300
<0.1
<0. 1
3
<0.1
2
5
14
.18,000
2
11,400
1,400
11,000
<0.1
0.2
0.1
0.9
2
<0.1
52
400
<0.7
0.9
19
0.6
13
160
29
SOLUBLE
0.031
<0.006
<0.12
<0.006
8.4
>200
0.42
0.011
>200
<0.008
>460
140
>160
<0.006
<0.006
<0.006
<0.002
5.4
1.2
<0.002
0.032
<0.007
0.45
0.82
0.59
PERCENT
SOLUBLE
1.6
<0.2
<3
<0.1
1.4
0.14
0.08
<0.4
>4.0
10
>1.5
<3
<6
<0.7
<0.1
10
0.3
<2
0.17
<1.2
0.3
0.5
2.0
Concentrations in equivalent yg per g of solid
107
-------
Gross alpha and beta radioactivity was determined for the gasifier
ash, cyclone dust, and lignite. In addition, gamma and alpha spectrometry
was used to perform specific isotope analyses for each solid. Complete
results for these determinations are provided in Appendix D. To provide a
basis for comparison of the radioactivity results to the total element
concentrations in Table 4-27, the weight fraction of each isotope of
uranium and thorium was calculated from:
W » A M
NO X
where: W = mass of nuclide per unit of mass of sample
A = activity of nuclide per unit mass of sample
= Ci/g x 3.7 x 1010 atoms/sec/Ci
M • nuclide mass (grams/mole)
N0 - Avogadro constant
A « Decay constant
= In 2
^
ti^= nuclide half life in sec
The individual isotopes of each element were then summed to give
an estimate of the total element concentration. Table 4-33 presents the
results of this isotopic analysis and the SSMS results for uranium and
thorium. In general, the results from the two techniques agree within the
accepted confidence limits for the analysis techniques. In Table 4-34 the
measured isotopic concentrations for the three isotopes of uranium are pre-
sented as isotopic abundances along with the natural isotopic abundances.
The individual isotopes are present in the samples at approximately their
natural abundance. The apparent enrichment of U^-J in the cyclone dust
is due to the scatter in the counting measurement in the technique.
Specific isotopes identified in the specific isotope analysis,
which decay by alpha and beta emissions, were summed to give an estimate of
gross alpha and beta radioactivity. Except for the beta activity of the
gasifier ash, these estimates compared well with the measured values as
seen in Table 4-35.
108
-------
TABLE 4-33. COMPARISON OF ISOTOPE ANALYSIS AND SSMS
Feed Coal Cyclone Dust
(yg/g) (yg/g)
Gasifier Ash
(ug/g)
Uranium
Thorium
IA
SSMS
IA
SSMS
0.6
<.9
1.1
<1.0
2.4
0.9
3.8
2.0
16
16
24
23
TABLE 4-34 . ABUNDANCES FOR URANIUM ISOTOPES
Natural Abundances Feed Coal Cyclone Dust Gasifier Ash
u 23*
u 235
u 238
.0056
.72
99.27
.0055
1.06
98.94
.0046
7.56
92.43
.0052
.85
99.14
TABLE 4-35 . GROSS ALPHA AND BETA ANALYSIS
AND SPECIFIC ISOTOPE ANALYSIS
COMPARISON
ALPHA RADIATION* BETA
RADIATION*
Gross Specific Isotope Gross Specific Isotope
Feed Coal 1.7± 3.6 1.5 ± 1.1 0+13
Cyclone Dust 11 ±6 7.4 ± 1.9 0±15
Gasifier Ash 46 ± 11 32 ± 2 52 ± 15
1.6 ± 1.9
3.9 ± 1.0
1.0 ± 0.8
*pCi/g.
109
-------
REFERENCES
1. Environmental Protection Agency. Hazardous Waste, Proposed Guidelines
and Regulations and Proposal on Identification and Listing. Federal
Register, 43(243):58946-59028, 1978.
2. Thomas, W. C., K. N. Trede, and G. C. Page. Environmental Assessment:
Source Test and Evaluation Report—Wellman-Galusha (Glen Gery) Low-Btu
Gasification. EPA-600/7-79-185. Radian Corporation, Austin, Texas
August 1979. ' '
3. Lentzen, D. E. , D. E. Waggoner, E. D. Estes, and W. F. Gutknecht.
IERL-RTP Procedures Manual: Level 1 Environmental Asssessment.
EPA-600/7-78-201. Research Triangle Institute, Research Triangle Park
North Carolina, January 1979. *
4. Cleland, J. G., and G. L. Kingsbury. Multimedia Environmental Goals
for Environmental Assessment, Volumes I & II, Final Report. EPA-600/7-77,.
136a, Research Triangle Institute, Research Triangle Park, North Carolin
November 1977. »
5. Kingsbury, G. L. , and J. B. White. Multimedia Environmental Goals for
Environmental Assessment: Volume III. MEG Charts and Background
Information Summaries (Categories 1-12). EPA-600/7-79-176a, Research
Triangle Institute, Research Triangle Park, North Carolina, August 1979
6. Kingsbury, G. L., R. C. Sims, and J. B. White. Multimedia Environmental
Goals for Environmental Assessment: Volume IV. MEG Charts and Backgro *
Information Summaries (Categories 13-26). EPA-600/7-79- 176b. Research
Triangle Institute, Research Triangle Park, North Carolina, August 1979
7. Schalit, L. M., and K. J. Wolfe. SAM/1A: A Rapid Screening Method for
Environmental Assessment of Fossil Energy Process Effluents. EPA-600/7-
78-015. Acurex Corporation/Aerotherm Division, Mountain View CaliforrH
February 1978. ' a»
8. Harris, J. C., M. J. Hayes, P. L. Levins, and D. B. Lindsay. EPA/IERL-RTP
Procedures for Level 2 Sampling and Analysis of Organic Materials.
EPA-600/7-79-033. Arthur D. Little, Inc., Cambridge, Massachusetts
February, 1979.
110
-------
APPENDIX A
PROCESS MATERIAL AND ENERGY BALANCES
This appendix contains the process data characterizing the lignite
gasification test run conducted by the Bureau of Mines in December of 1978.
From this data, the process operation during the sampling periods was char-
acterized and the effluent flow rates were developed.
Material and energy balance data provided by the Bureau of Mines
for the lignite gasification test run conducted by the Bureau from December
11, 1978 through December 14, 1978 are presented in the following Tables
A-l through A-5. This information was developed from process data collec-
ted, stored, and calculated by the Bureau of Mines data acquisition system.
Each table represents information averaged over distinct operating periods.
The information contained in Tables A-l through A-5 was used to develop
most of the process data presented in Section 2.0 of this report.
Material balances presented in Tables A-6 and A-7 for carbon,
hydrogen, oxygen, nitrogen, sulfur, ash, and total mass for the process
streams during the two major sampling time periods were calculated from the
Bureau of Mines material balances (Tables A-2, A-3, and A-4). Figure A-l
shows the relationship between the two sampling time periods and the Bureau
material balance time periods. The first sampling time period 1430 to 2130
on December 12, 1978, occurred during the plant operating time period
covered by Table A-2 and this table was used directly to obtain Table A-6.
The second sampling time period, 1600 to 0300 on December 13 and 14, 1978
occurred during the plant operating time periods covered by Table A-3 and
A-4. The data from these tables were simply averaged to obtain Table A-7.
Table A-8 contains the flow rate data used in calculating Tables A-6 and
A-7 as well as the calculated flow rates excluding moisture which were used
in the body of this report to calculate mass flow. Gasifier ash sluice
water and cyclone dust quench water rates (not part of Tables A-6 and A-7)
were estimated at 0.007&/S CW gph) each. These estimates were made from
visual observations during the test run.
The test burner flue gas rate and composition presented in Table
A-9 were estimated from process and sampling data because no direct mea-
surement was made. The product gas rate to the burner was estimated by
subtracting the product gas flow rate measured to the kiln from the total
product gas produced as calculated by the Bureau material balances. The
natural gas rate to the burner pilot and the combustion air rates to the
burner were estimated using the design flow rates for the test burner.
From this data and the product gas composition measured by GC analysis
taken at 2010 on December 12, 1978, the test burner flue gas rate and com-
position was calculated. The estimated test burner dry flue gas composi-
tion compares favorably to the GC analysis of a sample taken at 2006 on
December 12, 1978. This close agreement between the estimated and measured
flue gas composition supports the assumptions.
A-l
-------
TABLE A-l. PROCESS DATA SEGMENT 1, 12-11-78
ro
OASIMFR MASS BALANCE- «KP-?9 TNOIAWMFAO L
TNOHTM.HS/MR)
COAL
STFAM
I)" V A 19
TOTAL
OUTPUT (I.US/HR)
0«Y GAS
ROT ASH
CYC OUST
rfATFP
TAB
TOTAJ.
C H
1*33. * ?>3.1
,O «»7.?
.H .0
1034.0 360.3
C M
1701.1 Iftft.*
?*.* 1.4
?9.0 1.9
.ft 1M4.H
)?**•? 1?.7
inn?. 7 3*1.4
0
1^33,?
77it.fl
1M7./T
3940. S
,-,
?*PH.H
7.0
*.?
14£3.*
1 ^.Q
39P1.3
TflMTTE IZ/1H3*'5)-?1»3« TO
N S ASH
?S.f. 34.? 31^>.9
.n .0 .0
4996.7 • .0 .0
SO??.* 34.2 31S.9
N S ASH
476H..1 J>7.3 1.4
.3 S.? 309. S
.4 .5 5.0
.0 .0 .0
?.» 1.1 .0
477?. 4 34. 2 31S.9
3**-nl'
TOTAL
4101.11
nr,*.u
6MU.O
115«S.7
136
TOTM
°?3*.v
347. H
4S.<|
1M7«<:
159.0
11434.0
•*»••••••••••••»*»••««•*•*«•»•••••*•«••»•••«»•••«•«••••*••»•••••••••»#••••••••••**•«•••«••••••••••••••
OPFWATIMQ DATA
COAL
ANALYSIS
C ' 64.40
H 4. 10
0 lH.i»0
N .91)
S 1.20
MOISTURE 30. *0
ASH 11 . 1 1)
HHV 10RQ6.
LMV 10373.
RAS
ANALYSIS
o? '
A
CO? ^
H?O 1 ^
C*LC M?O i«»
HV i4
.000
fiAS
PP.OOUCTION
WF.T ««CFH IIPY
SCFH
AIH: SCFH
AM^IKNT «77?0.
TO fiASIFJER 10S04S.
RH
Sn.QO
100.34
.ri71- M^ASMtlFO 179000. 1*4?74.
.S*7
.400
/^O.FT.G^ATE S39*.A? 434
/!.« OAW COAL 43. 6S 1
»M.?,»
is. in
.??° /!.•* ^^Y COAL fi?.fl9 SO. 6V
,7H9
/Lfl **AF COAL 74.H7 t
>0.34
H^S ,??4 CALCULATED 174865. J404SH.
C*LC H?s
CH4 1
C?Hft
H? 17
CO ?«»
C3H4
6MS TAR/ORY SCF
• *?4
.SOS
.own
• ?OA
.n*3
.093
.soo
(C BALANCE)
WATFMtftPM) :
AAITAT')*) 3.06
TO SHKLL fi.41
FkOM SHCLL 4.77
EVAPORATEO 1.64
s re AM/PAW COAL
TOTAL ViATEH/OPY COAL
AltJ/WAW COAI.
AIQ/OMY COAL
AIR/MAF COAL
MATER REACTF.O/MAF COAL
L"/LM
.?11
,74f>
1 .*?S
P.341
2.787
.199
-------
TABLE A-l. CONTINUED
HF*T HALANCF-
COAL
At1*
TOTAL
TOTAL
.134J67E-fO«>
. IOM4HF+05
,/»4071bF.+05
.OOOOOOF+OO
DATA
TEMPIOfR C)
AIR 19.1
AIR c-tt.4
AGITATOR H20 6.0
JACKET H?0 ft.O
OMT°IIT
10T ASH 78.4
rvc OIIST ISQ.O
AGITATOR H?0 19.9
,IAC*F.T H?O PS.I>
«?ASF» OIITLFT if-4.o
CYCLONF OUTLET is9.o
MAIM FLOW iso.o
KTLN FLOW 1BO.O
DATA
PCT
99.97
.03
100.00
?U30 TO
OHTPIIT(MTII/HH)
SOT
CYC OUST
H?0
HOT OA«:
(CYC OilTI.FT)
HF.AT LOSS
TOTAL
r)
RAH
AFTFP
AT CMAMM(14n.OFr) C)
AT KIL*MU7.nFR C)
TAR CO'ITPTR'ITION«60 F)
9TU/WFT SCF
SFMSIHI.F
TOTAL
,4*-7M HF + Oh
.3M33S7F+OS
onooonp^on
.310070E*nft
PCT
1 .30
l.M
1.10
90.S3
100.00
»*»**»***»»**»•»»*»•*'
13.7?
HT'l/HR
CYCLOWF
CYC-MATH e-|.0«
MAIN FI.OW-COMt> CMAM8 .SS739E+05
MAIN FLOU-KTLN FLOW ,3lOO?F-Ol
KILN FLOW-
-------
TABLE A-2. PROCESS DATA SEGMENT 2, 12-12-78
AASIFIFP MASS 8ALANCF- GKP-?<» 1NOIANHFAO LTGNITE 12/12<34M-13:30 TO ?i:ou
INPUT!
COAl
STFAM
OPY AfR
TOTAL
OUTPUT I
OQY GAS
HOT ASM
CYC OUST
WATFP l»f-
TAP ttilf
TOTAI,
C
11**. 3
.0
.S
i)**.*±
c
10*7. H
IS. I
X9..1
H
IftA.?
So.?
.0
??&>
H
101.3
,Q
1.3
N
1ft.0.
.0
ASH
TOTAL
. tJOO
0
301?.7
+1*3
N
• 3
.*)
70.S
IM .«
7.9
.0
.(I
3.°
S
17.0
3.2
.4-
.0
.7
21.3
.0
.0
.2
ASH
l.S
7057.0 '
TOTAL
.1)
.0
197.2
10^1.
»•»••••«••••««•••«<»«*»••»»•••••»•*»*•*«••»»««••«»*•»•»»»»»»«»••*»•»««*»•«*»»•*•»»»•»•»•»••»••••«»»»•»•••
n»TA
CO»L
ANALYSIS
c ft*.<»u
H 4.30
0 11.?0
N .40
S 1.20
MOTSTUPF 30.60
»SH 11.10
HMtf J0fl«6.
LHV 10373.
GAS
ANALYSIS
A
CO?
H?0
.000
GAS
PROO'ICTIOM
WFT SCFM
111000.
ORY SCFH
Al«: SCFH
A.-HIFMT s?ftOH.
TO OASlFIFR ft3!72«
PH
so.on
100.49
CALC
CALC
CH*
H?
CO
CZH*
GMS TAR/ORY SCF
1^.400
1«.«?Q
44.M79
.?'5
«if?fi
l.«S?l
. 1 03
17.4?1
?8.SOft
. 14S
.500
/l.B <»*M COAL 43.3ft
/LB 0»Y COAL ft?.4rt
/LB MAF COAL 74.37
CALCULATED 10933O.
(C BALANCE)
34. QS AGITATO** 3.4S
SO. 3ft TO SHFLL S.OO
SO. 94 FROM SHFLL 4.00
8H127. EVAP'IDATFO 1.00
STEVVQAw COAL
TOTAL WATF»/OPY COAI
AlK/i?AW COAL
A I a/OR Y COAL
A1R/MAF COAL
WATCH REACTED/MAP COAL
.?n«.
.73H
l.Sftl
?.249
?.ft77
.195
-------
TABLE A-2. CONTINUED
HF.AT HALANCE-
TM01ANHFAO 11RNITF.
TOTAL PCT
. l*»3'i03F. + OR 99.96
AIR . 7?71»>4E + 04 .OOOOOftF+00 .7279*14^ + 04 .04
TOTAL . lft8520E+Of> .193407F+0* . 193S7-SF+01 100.00
TO ?\ioo
CYC OUST
HOT
(CYC OIITLFT)
HP. AT LOSS
TOTAL
TOTAL
. 31imilK + i|ft .31
.ooooooF+on
J3
3H.56
6.as
100.00
Ul
ro'VL
• M'UFMT «TR
S4THPOTTO
A^ITATOB
.IACKFT H?0
DATA
TEMPiDFr. C)
19. ft
ASH
PYC OUST
AfiTTATno H?0
.IACKFT W'O
npTLFT
OUTLET
MAIN FLOW
KTLM FLOW
}?7.0
)4.1
90.1
1PO.O
115.0
OAW
AT CHA~tH(nn.OFG CJ
AT KTI.Md I^.NFR C)
TAR CONTf»tflMTION(60 F)
CYCLONF
CYC-MAIM PLOW
MAIM FLOW-CO^R CHAM3
.MAIM FLOW-KTLM FLOW
FLOW-lfTLN
1S0.4H
153.33
.27*7flF. + 05
.31249F+OS
,425S3F+04
,Pfi5lOF+n4
18^.711
21.4B
P4.07
3.?H
1.97
BTII/LB TAH)
-------
TABLE A-3. PROCESS DATA SEGMENT 3, 12-13-78
OASmfR MAM BALANCE- WCI»-f« TWDIANMTAO |.TA«m 11/13(3471-111130 TO MI3«
l»|PHT(LBS/HP.)
COM.
STFAM
OPY AIR
TOTAL
OUTPUT CLHS/HR)
DRY OAS
«OT ASH
CYC OUST
WATFP
TAR
TOTAL
C H 0 1.1
H4II. 4 1?0. * 74H.T \1.7
.0 ?*O.J 3''**.^ .0
.4 .0 A93.f ??S4.S
*4«.« 170.7 1R39.1"
£9»^.9
>*•**••***»*»*»••»**••»•
O\
OPFP4TIN& DATA
COAI. GAS RAS
ANALYSIS
C
H
0
N
S
»«OTSTU
ASH
HHV
LHV
64.40
4.30
1«.20
.vo
1 .70
PE 30. *0
11.10
10096.
10373.
ANALYSIS
0? .000
A .S77
CO? A.?03
H?O ??.300
CALC H?0 1«."??
N? 44.«7S
H?S ,?30"
CALC H?S .?30
CH'» 1.S71
C?H« . 1 03
•\f 17.41R
CO ?ft.A03
C2H4 .14S'
GMS TAR/ORY SCF .SOO
AM: SCFH
PRODUCTION AMHIFt-'T 394H«».
MCASMR^D
/SO.FT.fiRATE
/L9 RAM COAL
/I.R ORY COAL
/I M MAF COAL
PALCHLATEO
-------
TABLE A-3. CONTINUED
HEAT BALANCE- GKP-?«»
INPUT(RTM/Htt)
JNOIANHFAO I.TQNITE
COMHIISTIOM TOTAL PCT
COAL . F>nR 100.00
M1* . 185*»4«»E+03 .OOOOOOF+OO .1 ««>f.4W»f>07 .00
TOTAL .429256E+03 .142033E+OP .14203RE+OB 100.00
12/13(347)-lono TO ?,o:30
OllT0|IT(HT(l/HR)
CYC OUST
ARTT
AGITATOR H?0
.IACKFT M?0
OPF.«ATING OATA
TEMPJDFO C)
AJP lh!?
60.?
6.0
5.5
BO.?
115.0
Ih.R
9S.O
130.0
llf.O
110.0
11*.. 0
ROT A«>M
CYC niKT
H?0
H?0
OUTLET
CYCLONE OUTLET
MAIN FLOW
KILN FLOW
HOT
(CYC OUT! FT)
HEAT LOSS
TOTAL
PAW G/i«; DATA 9TII/WET SCF
AFTFP CYC(«.o.nFG F)
AT CHA'««(100.0FG C)
AT KHM(\1S.I>EC, C)
TAP CONTPIR|lTJON(ftO F) 13.?.
TRANSMISSION LOSSES HTII/HP
CYCLONE .44804E+OS fiO.OH
CYC-MAIM Ft OW .lAflOSE-fOS If-.ft*.
MAIN FLOW-COMfl CHAMR ,?.Q75HF.-f0*5 33.?II7
• 177S57E+07 .l?4Z8?E-f06 .l*203aE+08 100.00
»»»»»»*»•**«>«««<»•»*»»*•*««*•*»••*»«*«**••••*«*»
BTH/nPY SCF
inf..??
1«>O.S7
l'M.?7
17.D2(1S441 OTU/LR TAR)
-------
TABLE A-4, PROCESS DATA SEGMENT 4, 12-13-78
03
W4«f 9M.AHCC- ««OHP« INDIA**** Lt«M4!TF
COAI.
O»Y AiP
TOTAL
OHY WAS
BOT ASH
CV OUST
TAP
TOTAL
OPERATING DATA
COAL
ANALYSIS
C fi4.»0
M
0
N
S
ASH
LHW
4.30
18. *i)
.90
1.20
30.60
11.1(1
10373
. 7
.5
93».?
H
M4.7
16.1
.0
67.7
H
M*..?
.7
1.1
11*.?
ANALYSIS
0?
A
C'J?
CALC
M?
CALf H2S
CH4
. 7
n
l???.r
4.6
7.4
.0
,?J7
CO
CHH4
6MS TAP/OHY SCF
.103
17.4?4
,14f,
.500
N
13.1
.0
3067.4
30HO.B
12/13(34T»-HM3« TO 1»/|4-1)I3«
S ACM
.0
1.5
17.S
.0
.0
17.5
2.7
.3
.0
17^5
.0
.0
161.ft
1.1
.0
.0
161.8
HAS
PRODUCTION
SCFH
9MOOO.
/LI «»Aw COAL
/L" MAP COAL
(C BALANCE)
. 46.67
9<1."*i
91010.
TOTAL
?li»0.fl
,A
A3. 9
•»***••••••»•»•••*«•.••••*•*•<
Alftt
A1
TO
AfilTATOP
TO S"FLL
SHELL
SCFH
6S«37|
4. Mil
7.6S
1.15
COAI.
TOTAL MATFW/ORY COAL
AIM/RAN COAL
AIM/O^Y COAL
AI9/MAF COAL
HEACTfvO/MAF COAL
RM
SO.00
1.444
?.*I01
1.315
.1*6
-------
TABLE A-4. CONTINUED
fiA
-------
TABLE A-5. PROCESS DATA SEGMENT 5, 12-14-78
COAL
<;TFAM
o»y
TOTAL
c
1*37.7
.7
C
rvr OUST
.0
311.fi
H
137.3
1.?
TAP
IOJAI.
.0
107.7
15.70.4
10.7
11.7
M
Io.
4496.4
4447.9
M
4014.7
.0
4017^7
.0
.0
28.7
4.4
.4
.0
.9
n to
ASH TOTAL
.0
.0
lOMJi.2
ASH TOTAL
1.3 7771.0
.0
.0
»»*••••»••*•#'• •»»»»»»»»»4i»«»«»»»*»••*•4»»»»«»«»**••«••»•«»•••»»**»•»»**»»»***•»••»••»»•»••*«*»*««•••»•«•
ASH
HMV
LHV
DATA
COAL
ANALYSIS
C A4.40
H 4.3()
O 18.20
N .90
5 1.20
11.10
10HA6.
I03f3.
.0(10
GAS
ANALYSIS
03
A
CO? ft.2«^
MPO
CALC H?o
W« *4.H«1
C*LC
CH4
PRODUCTION
MrftsuuR)
/SO.FT.P°ATF
/I fl PAM COAL
/!.« ORY COAI.
/L"» MAF COAL
CALCIILATEO
(C BALANCE)
WF.T SCFM
lS6fl«n.
4701. «,1
4S.1S
6S.34
77.79
15275*.
OPY
TO HASIFIE9
SO. 77
t
AftlTATOP
TO SHELL
F-*OM SMELL
F.VADOWATEO
SCFH
77S1B,
939VH,
3.SO
4.MS
1.S6
PH
sn.on
10A.8S
H? n
CO ?H.f>07
C9
?."39
.108
-------
TABLE A-5. CONTINUED
6A«;iFiF.R HEAT HALANCF-
TNPTANHFAO I.TRNITF i?/i*o*8)-i*:.in TO
COAL
SFMSIHI.F
TOTAL Pf.T
.^Sy|.«J?F + 0« 100. Oi)
.OOOOOOF+OO .QMM4/,nt->o? .00
TOTAL ,:?26203E>03 .
100.00
MOT ASH
PYC mist
HIT <;AS
(CYC OOTI.F.T)
TOTAL
. 'IS1P.I.K
TOTAL
.ni (--7 )
..In^Os
. (KMiiior
.nooooOF+oo
PCT
1 ..M)
l.'«0
.Oft
1.45
9n.Sn
S.i?9
100.00
Cn*L
DATA
AIR
H?0
H5>0
C)
15.*
59.0
b^7
p«W RA«s MATA
AFTFO CYCCilt.f
AT fHAMM
AT KTI.MH7«r.nFp
TAW Ci
RTII/VFT SCF
F) 14S.OS
C) 149.Hh
0 ic;o.r7
FI n.?3
HT'l/llPY SCF
1'If-. 7 n
IV*.(14
1 7.0?
HTII/LR TAH)
H?0
17S.O
10.0
OHTLFT 1«-7.0
F OUTLET 17S.O
HAlN FLO« lfrb.0
KTLN FL<"'W 17?..0
CYCI.OWF
CYC-MATM FI.OM
MAIN Fl.n«.
MAIN FLO*
KILN FLOW-KTLN
CHAMH
,OOOOOE*00
?7.04
40.45
-.00
.00
-------
12-11-78
Is)
12-12-71
11-13-78
1J-1J-78
20 0 4 8 12 16 20 0 4 8 12 16 20 0 « 8 12 16 20 » 4 8 12
Teat Burner
HHj, HCN.
Product G»a
NHi, HCH
A A
A A
A.
Product
A A
A A
MTI
ton
PROCESS DATA SEGMENTS
TEST BURNER SAMPLING
PRODUCT GAS SAMPLING
COAT. BIN VENT SAMPLING
LTCNITE SAMPLING
GASIFIER ASH SAMPLING
CTCLOHE DUST SAMPLING
GASIFIER ASH SLUICE WATER
SAMPLING
CTCLONE DUST QUFNCH WATER
SAMPLING
A - Grab Samples
Figure A-l. Process Data and Sampling Periods
-------
TABLE A-6. MATERIAL BALANCES FOR FT. SNELLING PROCESS STREAMS
H-»
U)
Input (g/sec)
Coal
Steam
Dry Air
Total
Output (g/sec)
Product Gas -
Dry Gas
Moisture
Tar
Gasifier Ash
Cyclone Dust
Total
C
140
.06
140 ± 20
130
10
1.9
2.4
150 ± 19
SAMPLING PERIOD 1 - 1430 to 2130 on 12/12/78
H 0 N S Ash TOTAL
21
7.5
120
28 ±3.2
13
14
1.0
.11
.16
28±2.8
130
59
120
304 ± 25
200
110
1.1
.54
.69
310 + 32
2 2.7 25
380
380 ±25 2. 7 +.4 25 ±2. 8
370 2.1 .19
.23 .09
.03 0.4 24
.04 .05 .42
370±53 2.7 + 0.3 25±2.8
320128
67 ±8.4
500 ±55
890 ±92
720 ± 63
130 ±16
12 ±1.4
27 ±2.8
3.8 ±1.3
900 ± 84
-------
TABLE A-7. MATERIAL BALANCES FOR FT. SNELLING PROCESS STREAMS
Input (g/sec)
Coal
Steam
Dry Air
Total
Output (g/sec)
Product Gas -
Dry Gas
Moisture
Tar
Gasifier Ash
Total
C
110
.06
110 ±16
104
7,9
1.5
110 ±15
SAMPLING PERIOD 2 - 1600 to 0300 on 12/13-14/78
H 0 N S Ash
16
7,4
23±2.5
10
14
.78
.08
25 + 2.4
100
58
103
260 ± 21
150
107
.86
.42
260 ± 26
1.6 2.1 19
340
340 + 48 2.1+0.3 19 ±2.1
290 1.7 .18
,18 .04
.03 .32 19
290±42 2.1 + 0.3 19 + 2.1
TOTAL
250 + 21
66 +8.3
444 ± 49
760 + 79
570 ± 49
120115
9.8 + 1.1
21 ±2.1
721 ±67
-------
TABLE A-8. PROCESS STREAM FLOW RATE DATA
Ul
STREAM
Sampling Period I1
ACTUAL
WITHOUT MOISTURE
Sampling Period 2'
ACTUAL
WITHOUT MOISTURE
Product Gas
Test Burner Flue Gas
Gasifier Ash
Cyclone Dust
Gasifier Ash Sluice Water
Cyclone Dust Quench Water
Lignite
0.9 SCM/s
7.2 SCM/s
0.007 l/s
(7 g/s)
<0.007 l/s
(<7 g/s)
323 g/s
0.73 SCM/s (720 g/s)
6.77 SCM/s (8080 g/s)
27 g/s
3.8 g/s
0.69 SCM/s 0.57 SCM/s (590 g/s)
220 g/s
0.007 £/s
(7 g/s)
250 g/s
21 g/s
170 g/s
SCM at 25°C (77°F) and 101 kPa (1 atm).
112/12/78.
212/13-14/78.
-------
TABLE A-9. ESTIMATED TEST BURNER FLUE GAS FLOW RATE AND COMPOSITION
PRODUCT GAS NATURAL GAS1 COMBUSTION AIR1
COMPONENT VOL % SCM/SEC VOL % SCM/SEC VOL % SCM/SEC
H2 14.4 .099
Oh, 1.2 .008 100.0 .024
CO 22.9 .158
C02 5.7 .039
i. H20 23.7 .163
o\
02 0.0 21.0 1-37
N2 32.1 .221 79.0 5.14
TOTALS 100.0 0.688 100.0 .024 100.0 6.51
TEST BURNER FLUE GAS2
SCM/SEC ESTIMATED VOL %
NET DRY
0.23 3.2 3.4
0.32 4.6
1.18 16.6 17.4
5.36 75.6 79.2
7.09 100.0 100.0
SCM at 25°C (77°F) and 101 kPa (1 atm).
1 Assumed values based on maximum design rates.
2GC analysis taken 2006 on 12/12/78 gave CO - 0.0%; C02
(dry basis).
- 2.92; 02 - 17.2%; N2 - 79.9%
-------
Error Propagation Analyses
An error propagation analysis was used to establish error limits
for the calculated total inlet and outlet mass rates of major components.
The values indicate the degree of variance to be expected due to random
errors and should not be interpreted as variance over a set of data points.
A 95 percent confidence interval of 2S(Q) is calculated for a
given value of Q according to the following standard definition:
s2(Q) , i
where: S^(Q) = the variance in Q,
Q = the mass flow rate of a given element into or out
of the system
q^ = the itn independent measured value (stream flow
or elemental concentration), and
= the variance of q.
The error limits, 2S(q^), for the flow rates and analytical results are
listed in Table A-10.
A-17
-------
TABLE A-10. ESTIMATED ERROR LIMITS FOR FLOW RATES
AND ANALYTICAL RESULTS
STREAM FLOW RATE ERROR LIMIT 2S (%)
Air ± 10
Steam ± 10
Coal ± 10
Ash ± 10
Dust ± 10
Hot Product Gas ± 10
ELEMENT ANALYTICAL ERROR LIMIT 2S (%)
C ±10
H ±10
N ±10
0 ±10
S ±10
Ash ±5
A-18
-------
APPENDIX B
SAMPLE COLLECTION TECHNIQUES AND FIELD SAMPLING DATA
TABLE OF CONTENTS FOR APPENDIX B
Bl.O INTRODUCTION B-2
B2.0 TEST BURNER FLUE GAS - 9 B-4
B2.1 Organics and Trace Elements .......... B-4
B2.2 Ammonia B-7
B2.3 Cyanide B-7
B2.4 Samples for Gas Chromatographic Analyses .... B-9
B3.0 PRODUCT GAS - 7, 7a B-10
B3.1 Ammonia and Cyanide B-12
B3.2 Organics B-12
B3.3 Trace Elements B-16
B3.4 Total Sulfur Species B-16
B3.5 Gas Samples for Gas Chromatography B-17
B3.6 Volatile Organics B-17
B4.0 COAL BIN VENT - 8 B-18
B5.0 SOLID AND LIQUID SAMPLES B-20
B5.1 Lignite B-20
B5.2 Gasifier Ash B-20
B5.3 Gasifier Ash Sluice Water B-20
B5.4 Cyclone Dust B-20
B5.5 Cyclone Dust Quench Water B-21
B5.6 Service Water B-21
B6.0 SAMPLE LOG B-22
REFERENCE B-32
B-l
-------
Bl.O INTRODUCTION
This appendix describes the techniques used to collect samples fo
the environmental assessment of the two meter Wellman-Galusha gasifier at
the U.S. Bureau of Mines, Fort Snelling Iron Ore Pelletizing pilot plant.
Figure B-l provides a simplified schematic of the facility with sampling*
points numbered as follows:
Gas streams:
• Test Burner Flue Gas - 9
• Product Gas - 7
• Product Gas (at the start-up/emergency vent) - 7a
• Coal Bin Vent Gas - 8
Solid and liquid streams:
Lignite - 1
Gasifier Ash - 2
Gasifier Ash Sluice Water - 3
Cyclone Dust - 4
Cyclone Dust Quench Water - 5
Service Water - 6
The following sections describe the sample collection techniques
used at each location and the on-site sample log is given as Section 6.0»
B-2
-------
Coal
w
co
Jacket
Water
Jacket o
Water f
Ash Sluice
Water
Ash
and Sluice
Water
| Quench I
-0
Oust
Quench
Water
_^. ToPelletizer
Kiln
Natural
Gas
Scrubber
Test
Burner
o-
Sampling Points
70-1579-1
Figure B-l. Operating Schematic of the Wellman-Galusha Gasifier
-------
B2.0 TEST BURNER FLUE GAS - 9
Samples of the test burner flue gas were collected for:
particulates
organic characterization
trace element characterization
ammonia content
cyanide content
moisture content, and
vapor phase concentration of:
- Cj-Cg hydrocarbons
- sulfur species
- fixed gases
Original plans were to sample the test burner flue gas at a point
downstream of a 90° elbow at the exit of the burner and upstream of a 45°
elbow prior to the scrubber. However, some of the quench spray nozzles
located Just downstream of this point were misdirected and sprayed up-
stream. These spray nozzles showered the original test plane with quench
water which made sampling impractical.
A sight glass located in the 90° elbow and on the burner center
line was disassembled and used as a sampling port. This port provided
access to a single point in the center of the duct in the transition
between the burner chamber and the 90° elbow.
Data from the sampling performed at the test burner exit is
presented at the end of this section (Table B-l).
B2.1 Organics and Trace Elements
The EPA-developed Hi Volume Source Assessment Sampling System
(SASS train), Figure B-2; was used to collect samples for characterization
of the organic and trace element content of the test burner flue gas. The
particulate concentration of the gas stream was also determined from the
sample collected during this run. The train configuration and method of
operation met current specifications (Ref. B-l), except for the location of
the XAD-2 canister in the organic module. These procedures currently
require that the XAD-2 canister be positioned beneath the gas cooler, in
this position large quantities of aqueous and organic phase condensate flow
through the XAD-2 resin and are subsequently trapped in a knock-out below
the resin. This arrangement could coat the resin early in the sampling
effort and result in reduced collection efficiencies for vapor phase
organic material.
The modified configuration shown in Figure B-2 traps condensed
material before it passes through the resin, thus reducing the possibility
of reduced resin collection efficiency. It also simplifies sample recovery
and analysis.
B-4
-------
TABLE B-l.
TEST BURNER FLUE GAS
Summary:
Sampling Data:
Flow Rate
Velocity
Duct ID
Temperature
Pressure
% Moisture
Sampling Period
7.09 m3/sec (25°C, 101 kPa)1
NA
NA
4AO°C (835°F)
Atmospheric
13.5% by volume
1442-2115 12 Dec 1978
SAMPLE
TIME
DATE
VOLUME (SCM*)
HCN #1
NH3 #1
NH3 #2
NH3 #3
NH3 #4
SASS
1847
2030
2105
1430
1513
1617
1715
1903
2045
2115
1440
1530
1634
1740
1442 - 2009
12 December
12 December
12 December
12 December
12 December
12 December
12 December
12 December
.2735
.2721
.2232
.1751
.2678
.5672
.3899
29.686
GC Sample #1 TB
GC Sample #2 TB
GC Sample #3 TB
GC Sample #4 TB
1300
1535
1551
1715
12 December
12 December
12 December
12 December
1 Calculated value, wet basis.
* At 25°C (77°F) and 101 kPa (1 atm), dry basis,
B-5
-------
STACK T.C.
HEATER
CONTROLLER
CONVECTION OVEN
QASCOOLER
XAD-2 CARTRIDGE
OVEN T.C.
GAS TEMPERATURE T.C.
DRY GAS METER
ORIFICE METER
CENTRALIZED TEMPERATURE
AND PRESSURE READOUT
L
CONTROL MODULE
TRACE ELEMENT
IMPINGERS
(COOLED)
VACUUM PUMP
Figure f-2. Source 4M*fiM0t Stalling Syitm (SA8&) Schematic
7O-1MM-1
-------
The impinger solutions used for vapor phase trace element
collection were:
1. 6% H20 750 ml
2. 2M (NH4)2S208 + 0.2M AgN03 750 ml
3. 2M (NH4)2S208 + 0. 2M AgN03 750 ml
A. Preweighed silica gel
Sample recovered from the front half of the train (nozzle, probe,
cyclones, and filter) were weighed and used to calculate the particulate
concentration of the gas stream. A portion of this particulate and the
material recovered from the organic module were analyzed to characterize
the organic material collected. Portions from all three sections of the
train (front half, organic module, and trace element collection impingers)
were recovered for trace element analysis.
The mass of aqueous condensate collected by the train during this
run plus the total volume of flue gas sampled were used to calculate a
moisture fraction of 13.5% for the flue gas.
B2.2 Ammonia
Samples for analysis of ammonia in the flue gas were collected
during the SASS run. An auxiliary sampling train shown in Figure B-3 was
used. It consisted of a stainless steel probe and a heated 47 mm glass
fiber filter. The impinger contents were:
1. 10% H2S04 100 ml
2. 10% H2S04 100 ml
3. Dry
4. Preweighed silica gel
The gas temperature was held at 120°C (250°F) until the gas had
been filtered. Four sequential ammonia sampling runs were made simul-
taneously with ammonia sampling runs performed at the product gas duct. At
the completion of each run the impinger contents were transferred to sample
bottles and replaced with fresh solutions for the next runs. The impinger
solutions were analyzed on-site by the analytical method described in
Appendix C. Data pertinent to these ammonia sampling runs are presented at
the end of this section (Table B-l).
B2.3 Cyanide
Three samples for vapor phase cyanides were collected at the test
burner simultaneously with cyanide sampling of the product gas. The
auxiliary sampling assembly and sampling methodology used for ammonia
collection was also used for cyanides. The impinger solutions used for
cyanide collection were:
B-7
-------
S.S. PROBE
OVEN
IMPINGERS
xonn
FILTER HOLDER
TEFLON TUBING
GAS METERT.C.
ICEBATH-
RNE ADJUSTMENT
BY-PASS VALVE
VACUUM
DRY GAS METER
COARSE ADJUSTMENT
VALVE
VACUUM PUMP
Figure B-3.
Schematic Drawing of Impinger Sampling
Train Used at the Test Burner
B-8
-------
1. 10% NaOH 100 ml
2. 10% NaOH 100 ml
3. Dry
4. Preweighed silica gel
The resulting impinger solutions from each of the three runs were
treated to remove sulfides and then analyzed on-site, as described in
Appendix C. Pertinent data for each of these runs is presented at the end
of this section (Table B-l).
B2.4 Samples for Gas Chromatographic Analyses
The test burner flue gas was analyzed on-site by gas chromato-
graphy for major (fixed) gases, gaseous sulfur species, and C^-C^
hydrocarbons as described in Appendix C. The gas samples were collected
with a sampling and conditioning apparatus consisting of 1.2 meters of heat
traced Teflon sample line followed by a Teflon® membrane filter in a stain-
less steel filter holder. These were followed by a Perma-Pure Drier®, a
Teflon®-lined diaphragm pump and a flow meter. Silanized glass sample
bombs were used to collect the conditioned gas at the exit of the train.
Sample bombs were purged, pressurized to >135 kPa (5 psig) and immediately
transported to the mobile laboratory for analysis.
B-9
-------
B3.0 PRODUCT GAS - 7, 7a
The product gas from the gaslfier was sampled at two locations:
the exit of the cyclone just prior to the venturi flow meter and i^ the
duct to the start-up flare. The use of the second location was necessi-
tated by plant operational problems. As a result of these problems, the
product gas was directed to the start-up vent flare from a point upstream
of the cyclone. The original sampling port was by-passed (see Figure B-l).
Samples of the product gas were collected for characterization of.
• ammonia concentration
• cyanide concentration
• vapor phase concentrations of:
- Cj-Cg hydrocarabons
- volatile sulfur species
- fixed gases
• organic content
• trace element content
• volatile organ!cs
With the exception of ammonia and cyanide, all sampling was
performed at the port in the start-up vent duct. For both locations an
electrostatic precipitator (ESP) was used prior to the impingers in the
sampling trains and the organic module. The ESP shown in Figure B-4
removed particulates and oil and tar aerosols from the product gas. These
constituents would plug conventional filters.
The gas stream entered the lower portion of the ESP and was
directed toward a catch cup at the bottom of the ESP, thus permitting the
collection of any easily removed material (particulate and condensate)
without fouling the upper portion of the ESI. As the gas stream moved
upward through the ESP, electrostatic collection was induced by the 12 KVDC
potential between the 0.025 mm center electrode and the cylindrical shell.
Colloidal-sized aerosols were removed from the gas stream and forced to
coalerce by their ultimate contact with the outer shell and other aerosol
particles. Accumulated oils and tars flowed down the walls to the catch
cup at the bottom of the ESP. The cleaned gas exited near the ESP top.
Most collection occurred near the base of the ESP; the upper portions
remained relatively free of material.
ESP's of this configuration have been shown to be 99+% efficient
for dry material of colloidal size. However, the primary reason for the
use of the ESP was its ability to remove particulates and oil and tar
aerosols without frequent stops for servicing or changing filtering ele-
ments. A glass fiber filter was used at the exit of the ESP as a polish
and a back-up in the event of an ESP failure. The ESP temperature was held
B-10
-------
ELECTRODE
STANDOFF
OUTLET
0.010" DIA.S.S.
ELECTRODE
INLET
DC
POWER SUPPLY
ELECTRODE
STANDOFF
GROUND
Figure B-4. Schematic of ESP Used for Aerosol
and Particulate Removal
70-1596-1
B-ll
-------
at 140°C (285°F) and the filter at 150°C (300°F) to avoid further conden-
sation of any oils remaining in the gas streams. Figure B-5 shows the ESP
and filter in their respective ovens.
Material collected by the probe, ESP, and filter were common to
all trains used at the product gas start-up vent (7a). These fractions
remained separate through a portion of the analytical matrix to enable the
calculation of an ESP collection efficiency of 99.2%. Of the 78.60 grams
collected in the probe, ESP, and filter; 49.1% was collected in the probe
50.5% was collected in the ESP, and 0.4% was collected by the filter.
Methylene chloride soluble material was 68% of the total catch and the
balance 32% was insoluble.
B3.1 Ammonia and Cyanide
Samples for ammonia and cyanide analyses were collected at the
original product gas sampling port. These collections were made simul-
taneously with those made at the test burner. The sampling trains and
procedures were the same as those described for the test burner except that
the ESP was used prior to the filter. These samples were also analyzed
on-site using the procedures described in Appendix C. Pertinent data for
these samples are presented at the end of Section 3 (Table B-2).
B3.2 Organics
The SASS train shown in Figure B-6 was used to collect samples
from the start-up vent for organic characterization. An ESP and filter
were substituted for the three cyclones and filter normally used with the
SASS train. The position of the XAD-2 canister, downstream of the con-
densate collector as used for the test burner, was retained. The gas flow
rate through the SASS train was reduced to 0.017 cubic meters per minute
(0.6 cubic feet per minute) from 0.11 cubic meters per minute (4 cubic feet
per minute) for conventional SASS runs. The smaller gas flow rates per-
mitted the use of a smaller ESP and also permitted sampling for a longer
time. The total volume passed through the organic module was 5.08 nM^
instead of 30 nM^ for conventional SASS runs.
A lower oven temperture of 140°C, instead of 200°C for conven-
tional SASS runs was used to prevent heavy tars from reaching a plastic
state during filtration. Past experience has shown that even small quan-
tities of heavy tars at temperatures above 150°C (300°F) tend to flow after
isolation on the filter surface and cause a high pressure drop across the
filter. The SASS train impingers with the 6% peroxide and silver persul-
fate solutions were used as pump and meter protection and as reserve
analytical samples but were not analyzed.
B-12
-------
PROBE
O
OVEN POWER
SUPPLY
FILTER OVEN
-Q-
OVEN
OVEN CONTROL
TOIMPINGERS
Figure B-5. ESP and Filter Assembly
70-1597-1
B-13
-------
TABLE B-2
PRODUCT GAS (Main Duct)/(Vent)
Summary:
Flow Rate
Velocity
Duct ID
Temperature
Pressure
Z Moisture
Molecular Weight
Sampling Period
51.0m3/min (@ 25°C, 101 kPa)1 (1800 ncfm)
30.4 m/s (99.8 fps)
3.05 cm (10 in.)
160°C (321°F)
+3.8" H20
25% by volume
26.68 dry (24.51 actual)
1430 - 2124, 12 Dec 1978; 1722 - 0123, 13-14 Dec 1978
Sampling Data:
SAMPLE ID
TIME
DATE
VOLUME (SCM*)
(Main Duct)
HCN #1
HCN 12
HCN 13
NHa II
NHa 12
NHa 13
1845
2030
2105
1430
1513
1714
1907
2045
2124
1440
1523
1724
12 December
12 December
12 December
12 December
12 December
12 December
(Vent)
Total (ESP & Filter)
Organic Module
Vapor Trace Elements
Sulfur Species
GC Sample 15 PG
GC Sample 16 PG
GC Sample #7 PGV
GC Sample 18 PGV
GC Sample 19 PGV
GC Sample #10 PGV
GC Sample 111 PGV
GC Sample #12 PGV
1722 - 0123
1722 - 0123
1725 - 2321
0034 - 0117
2010
2013
1715
1735
1910
1930
2200
2320
13-14 December
13-14 December
13 December
14 December
12 December
12 December
13 December
13 December
13 December
13 December
13 December
13 December
.1434
.1169
.1338
.02736
.02981
.03221
8.523
5.555
2.613
0.355
* At 25°C (77°F) and 101 kPa (1 atm), dry basis.
1 Wet basis.
B-14
-------
W
i—«
Ui
STACK T.C.
HEATER
CONTROLLER
ESP AND FILTER
IN OVENS (FROM B-5)
TE SAMPLE TAP
GAS COOLER
XAD-2 CARTRIDGE
SS PROBE \
S-TYPE PITOT
GC SAMPLE
TAP
GAS TEMPERATURE T.C.
DRY GAS METER
ORIFICE METER
CENTRALIZED TEMPERATURE
AND PRESSURE READOUT
CONTROL MODULE
TRACE ELEMENT
IMPINGERS
(COOLED)
VACUUM PUMP
Figure B-6. Product Gas Sampling with ESP
70 1598 1
-------
B3.3 Trace Elements
Samples of the gas stream exiting the ESP shown in Figure B-6 were
collected for trace element analysis. The gas exiting the ESP was carried
directly to the impingers through a Teflon® tube. The organic module was
bypassed. This arrangement permitted a simpler sample recovery scheme and
also avoided the difficult process of obtaining an aliquot of the XAD-2
condensed organic mixture and condensate for trace element analysis. The
contents of the impingers used for this collection were:
1. Dry
2. 10Z HN03 250 ml
3. 102 HN03 250 ml
A. Dry
5. 10Z KOH 250 ml
6. 102 KOH 250 ml
7. Dry
8. Preweighed silica gel
The first empty impinger served as a knock-out for condensate
(aqueous and organic) which formed as the gas was cooled from 140PC. Other
dry Impingers were used to separate the acidic and basic portions of the
Impinger train. Due to the high organic content of the gas streams, acid/
base solutions were selected for trace element collection because of their
Increased oxidizing capacity over silver persulfate solutions were
selected.
B3.4 Total Sulfur Species
Samples for determination of the total sulfur concentration of the
product gas stream were collected at the exit of the ESP filter system.
The sulfur species were collected by a series of five impingers:
1. 6Z H202 200 ml
2. 2N ZnOAc 200 ml
3. 0. IN BOH in EtOH 200 ml
4. Dry
5. Preweighed silica gel
Sulfur oxides were collected in the peroxide solution, hydrogen
sulfide was collected in the acetate solution, and carbon disulfide and
carbonyl sulfide were collected in the alcoholic potassium hydroxide
solution. The total sulfur concentration determined from these samples
found to be In good agreement with the value calculated from the on-site
gas chromatographic analysis of the individual sulfur species.
B-16
-------
B3.5 Gas Samples for Gas Chromatography
Samples for GC analyses were collected with the gas sampling and
conditioning train described in Section 2.4. This train was used at both
the main product gas line and the start-up vent. Samples were obtained at
a tap downstream of the ESP. The ESP removed most of the particulates and
aerosols, thus permitting less frequent replacement of the filter in the
gas sampling and conditioning train. To verify that the ESP had no effect
on sample integrity, simultaneous samples were collected before and after
the ESP. The gas compositions determined at these two sites agreed within
experimental error. The locations of these two sample taps are shown in
Figure B-6.
B3.6 Volatile Organics
Gas samples for organic characterization were collected with Tenax
tubes. The 0.32 cm o.d. x 28 cm glass-lined stainless steel tubes were
packed with 10 cm of 60/80 mesh Tenax-GC followed by 5 cm of Davison Grade
15 silica gel. The sorbents were centered in the tube. A leakless dia-
phragm pump was used to draw samples through the Tenax tubes which were
followed by a flow meter to monitor gas flow rate. An initial leak check
was performed by plugging the tube entrance and setting the pump for
maximum flow. The leak rate was measured at the flow meter.
Samples were collected by removing the plug at the tube inlet and
inserting the tube into a tee downstream of the ESP. The sample flow rate
(typically 30-60 cm-^/min) was determined by the pressure drop through the
tube. The leak rate was rechecked after sampling. Due to the small sample
Volumes, the collection temperature was determined at ambient conditions
rather than the temperature of the gas in the sampling line.
B-17
-------
B4.0 COAL BIN VENT - 8
The coal bin is located directly above the upper lock hopper
valves. Gases from this bin are drawn through a hood and a 0.3 m duct by
an in-line fan. A 2.5 cm hole in this duct upstream of the fan served as
sampling port. Samples were collected from the coal bin vent to *
characterize the following parameters:
ammonia
cyanide
total volatile sulfur
volatile sulfur species
Cj-Cg hydrocarbons
fixed gases
metal carbonyls
A stainless steel probe 0.64 cm o.d. followed by a 47 mm glass
fiber filter in a stainless steel filter holder (Figure B-3) was used for
all impinger sampling done at this location. The filter holder was con-
nected to Smith-Greenburg impingers with Teflon® tubing. The gas stream
was relatively clean and did not require the use of an ESP. The impinger
solutions and sample handling procedures for the ammonia, cyanide, total
sulfur, and gas samples for GC analysis have been described in previous
sections. Sampling data for sampling at this site is given in Table B-3
Metal Carbonyls
Gas from the coal bin vent duct was filtered then passed through a
series of impingers designed to collect iron and nickel carbonyls. Vapor
phase iron and nickel collected by the impingers were analyzed and reported
as the respective metal carbonyl. The impinger solutions were:
1. 3Z Dltrex HC1 100 ml
2. 3Z Ultrex HC1 100 ml
3. Dry
4. Preweighed silica gel
The solutions were tranferred to polyethylene bottles for storage and
subsequent off-site analysis.
B-18
-------
TABLE B-3
COAL
RUN
HCN #1
HCN #2
HCN #3
NH3 #1
NH3 #2
NH3 #3
Species
Species
M(CO)n
BIN VENT
Summary :
Flow rate - 27.9 m3/min
Velocity - 6.62 mps (2.
Duct ID - 0.3 M (12")
Temperature - Ambient 4°C
Pressure - Ambient
% Moisture - 1% by volume
Sampling Period - 1604 - 0247
Sampling Data:
TIME
1907 - 1930
1940 - 2010
2015 - 2048
1604 - 1707
1715 - 1800
1805 - 1900
#2 2245 - 2323
#3 2330 - 2400
0051 - 0247
(@ 25 °C, 101 kPa)
17 fps)
(39°F)
13-14 December
DATE
13 December
13 December
13 December
13 December
13 December
13 December
13 December
13 December
14 December
1 (984 ncfm)
VOLUME (SCM*)
.4298
.5430
.5740
.5672
.4749
.4664
.6875
.5675
1.6736
* At 25°C (77°F) and 101 kPa (1 atm), dry basis.
1 Wet basis.
B-19
-------
B5.0 SOLID AND LIQUID SAMPLES
The solid and liquid streams sampled during the lignite run (9-13
December 1979) were:
Lignite - 1
Gasifier Ash - 2
Gasifier Ash Sluice Water - 3
Cyclone Dust - 4
Cyclone Dust Quench Water - 5
Service Water - 6
B5.1 Lignite
Lignite feed to the gasifier was brought from storage by front-end
loaders, screened to remove the fines «20 mm) and then conveyed to the
coal bin above the gasifier. Grab samples were collected as the sized
lignite fell from the conveyor belt to the receiving hopper of the bucket
elevator. During the test effort, a one liter grab sample was taken during
each batch loading operation (usually twice per eight hour shift).
B5.2 Gasifier Ash
Gasifier ash was periodically (usually once per eight hour shift)
transferred from the bottom of the gasifier into a bin. Service water was
added to the bottom of the gasifier to aid in the removal of the ash. Once
the ash was transferred to the bin, the water (gasifier ash sluice water)
was decanted from the ash. A 2-3 liter sample of the dewatered ash was
collected as it was dumped from the bin after the bin and ash had been
weighed.
B5.3 Gasifier Ash Sluice Water
As the gasifier ash sluice water (see Section 5.2) was decanted
from the ash, samples of the water were collected. The water was collected
in glass and plastic containers, transported to the on-site laboratory and
preserved for analysis.
B5.4 Cyclone Dust
A 1-2 liter cyclone dust sample was collected just after each
gasifier ash sample was collected (once per eight hour shift). These
samples were collected from a water quench trough at the bottom of the
cyclone leg. The sample was raked from the trough, and the quench water
was allowed to drain from the sample. The samples were then transferred t
containers.
B-20
-------
Water
During each cyclone dust sample collection, a 3-4 liter sample of
quench water was also collected from the quench water trough. The samples
were preserved, using the procedures described in Appendix C, immediately
after collection.
B5.6 Service Water
Two one-liter service water samples were collected at a tap in the
service water line. The analytical results from this sample were used to
make background corrections for the ash sluice water and cyclone dust
quench water results.
B-21
-------
B6.0 SAMPLE LOG
Sample No.
FS-1
FS-2
FS-3
FS-4
FS-5
FS-6
w FS-7
K FS-8
FS-9
FS-10
FS-11
FS-12
FS-1 3
FS-14
FS-15
FS-16
Description
ESP Ippinger and CHjda
ESP Filter
ESP Tar
Gasifier Cyclone Dust - Coke
Gasifier Ash Quench Water
Gasifier Ash Quench Water
Green Pellets
Finished Pellets
Lignite
Cyclone Quench Water
Lignite
Gasifier Ash Sluice water - glass
Gasifier Ash Sluice water - plas
Gasifier Ash Sluice water - plas
Gasifier Ash
Service Water
Date
12-9
12-9
12-9
12-11
12-11
12-11
12-11
12-11
12-12
12-12
12-12
12-12
12-12
12-12
12-12
12-12
Time
1500
2300
2300
2400
2400
0015
0030
1200
1430
1430
1430
1430
1445
Analysis
Hold
Hold
Hold
Hold
BOD
Hold
Hold
Hold
Ult, Prox, composite with FS-11, 21, 24, 50,
72 for SSMS*, a & 3, Size, mineral
Composited wi£h FS-19, 27 for pH, TDS, COD,
TOC, CN~, NHi, , anions
Ult, Prox, composite with FS-9, 21, 24, 50,
72 for SSMS*, a & B, Size, mineral
Composited with FS-43, 51, 66 for Phenols
Composite with FS-45, 52, 68 for
SSMS*
Composited with FS-46, 53, 67 for pH, TDS,
COD, CN-, NHi, , anions, TOC
Composite with FS-4 7, 61, 70 for BIO, SSMS*,
Ult, Prox, a & 3, Morph, ORG, Leaching, mineral
Trace elements by SSMS*
'Znclfttfaf Bfc, A«, fe, Sb by A, A.
-------
Sample No.
FS-17
FS-18
FS-19
FS-20
FS-21
FS-22
FS-23
w
tla FS-24
UJ
FS-25
FS-26
FS-27
Description
Cyclone Quench water
Cyclone Quench water
Cyclone Quench water
Cyclone Dust
Lignite
Green Pellets
Finished Pellets
Lignite
Cyclone Quench Water
Cyclone Quench water
Cyclone Quench water
- glass
- plas
- plas
- glass
- plas
- plas
Date
12-12
12-12
12-12
12-12
12-12
12-12
12-12
12-12
12-12
12-12
12-12
Time
1500
1500
1500
1500
1510
1800
1800
1945
2030
2030
2030
Analysis
Composited with FS-25 for Phenols
Trace elements by SSMS
Composited with FS-27, 10 for pH, TDS, TSS,
COD, TOC, CN , NH.» , anions
Composite with FS-28 for SSMS, ULT, PROX,
a & 8 size, Morph, Org, Leaching, BIO
Ult, Prox, composite with FS-9, 11, 24, 50,
72 for SSMS, a & 8 size, mineral
Hold
Hold
Ult, Prox, composite with FS-9, 11, 21, 50,
72 for SSMS, a & 8, size, mineral
Composited with FS-17 for phenols
Biological & BOD, TOC
Composited with FS-19, 10, for pH, TDS,
FS-28
FS-29
FS-30
FS-31
FS-32
Cyclone Dust
Green Pellets
Finished Pellets
Gasifier Ash
T.B. SASS Condensate
Aqueous phase 2107.04 grams
12-12 2030
12-12 2045
12-12 2045
12-12 1430
12-12
COD, TOC, CN , NH., , anions
Biological, composite with FS-20 for SSMS,
Ult, Prox, a & 8, size, Morph, Org and
Leaching, BIO
Hold
Hold
Hold
Organic
*Includes Hg, As, Se, Sb by A.A.
-------
w
Sample No.
FS-33
FS-34
FS-35
FS-36
FS-37
FS-38
FS-39
FS-40
FS-41
FS-42
FS-43
FS-44
FS-45
FS-46
FS-47
Description
T.B. SASS XAD-Resin
T.B. SASS Cyclone Particulates
> 3 y 0.03 grams
T.B. SASS Condensate
T.B. SASS Org. Module Wash
T.B. SASS Cyclone Rinse *
T.B. SASS 1st Impinger
T.B. SASS 2nd Impinger
T.B. SASS 3rd impinger
See FS-49
See FS-145
Gasifier Ash sluice water-glass
Gasifier ash sluice water
Gasifier ash sluice water
Gasifier ash sluice water
Gasifler ash
Date Time
12-12
12-12
12-12
12-12
12-12
12-12
12-12
12-12
12-13 0030
12-13 0030
12-13 0030
12-13 0030
12-13 0030
Analysis
SSMS*
SSMS
SSMS*
Organic
Filter & Weigh
Combine for SSMS*
Composited with FS-12
Composite with FS-54
and biological
Composite with FS-13,
, 51, 66 for phenols
& 69 for organics
52, 68 for SSMS*
Composited with FS-14, 53, 67 for pH,
TDS, TSS, COD, TOC, CN~, NHi, , anions
Composite with FS-15,
SSMS*, ULT, Prox, a &
61, 70 for BIO, mineral
3, Morph, ORD, leaching
*Tnc2udM flg, A*, 8ft, 8b by A.A.
-------
Sample No.
Description
Pate Time
Analysis
w
N3
FS-48
FS-49
FS-50
FS-51
FS-52
FS-53
FS-54
FS-55
Gasifier Ash
T.B. SASS Probe Wash
Lignite
12-13 0030
12-12
12-13 1730
Gasifier ash sluice water-glass 12-13 1900
Gasifier ash sluice water-plas 12-13 1900
Gasifier ash sluice water - plas 12-13 1900
Gasifier ash sluice water
Cyclone quench water - extra
12-13 1900
Hold
Evaporate MeCla and weigh
Ult, Prox, combine with FS-9, 11, 21,
24, 72 for SSMS*, a & $, size
Composited with FS-12, 43, 51, 66
for phenols
Composite with FS-13, 45, 68 for SSMS*
Composited with FS-14, 46, 67 for pH,
IDS, TSS, COD, TOC, CN~, NHi» , anions
Composite with FS-44 and 69 for Bioassay
and organic
FS-56
FS-57
FS-58
FS-59
FS-60
FS-61
FS-62
FS-63
FS-64
FS-65
_ j
glass
Cyclone
Cyclone
Cyclone
12-13 1900
quench water-extra 12-13 1900 BOD
quench water-extra 12-13 1900
quench water-extra 12-13 1900
TOC, organic
Cyclone Dust 12-13 1900 Hold
Service Water 12-13 1945 Hold
Gasifier
Gasifier
Gasifier
Ash 12-13 1900 Composite with FS-15, 47, 70 for SSMS*, mineral
Ult, Prox, a & 3, Morph, org, leaching, Bio
ash 12-13 1900 Hold
ash 12-13 1900 Hold
Tar deposits before test burner 12-13 Hold
Tar deposits in line to kiln 12-13 Hold
*Includes Hg, As, Se, Sb by A.A.
-------
Sample No. Description
Date Tine
Analysis
r
10
FS-66
FS-67
FS-68
FS-69
FS-70
FS-71
FS-72
FS-73
FS-74
FS-75
FS-76
FS-77
FS-78
FS-79
FS-80
FS-81
Gasifler ash sluice water-glass
Gasifier ash sluice vater-plas
Gasifler ash sluice water-plas
Gasi£ler ash sluice water
Gasifier ash
Gasifier ash
Lignite
PG SASS condensate aqueous
phase
PG SASS org. module rinse
PG SASS ESP Rinse
Gasifier condensate before
T.B. - 3 bottles
P.G. trace metals 1st
impinger - dry
P.G. trace metals 2nd
impinger- 10% HNOs
P.G. trace metals 3rd
impinger- 10Z HNOa
P.G. trace metals 4th
impinger- MaOH
P.G. trace metals 5th
iapingar- MaOH
12-13 2330
12-13 2330
12-13 2330
12-13 2330
12-13 2330
12-13 2330
12-14 0030
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13 .
12-13 /
Composited with FS-12, 43, 51 for phenols
Composited with FS-14, 46, 53 for pH,
IDS, TSS, COD, TOC, CN~, NHi» , anions
Composite with FS-13, 45, 52 for SSMS*
Composite with FS 44 and 54 for bio & org
Composite with FS-15, 47, 62, for SSMS*, mineral
Ult, Prox, a & @, Morph., org, leaching, Bio
Hold
Ult, prox, combine with FS-9, 11, 21, 24,
50 for SSMS*, a & 8, size, mineral
Organic, BIO
Organic, BIO
SSMS*, Organic, BIO
Hold
Combine for SSMS*
Combine for SSMS*
*Includ«« Hf, A«, to, ft> by A.A.
-------
I
NJ
Sample No.
FS-82
FS-83
FS-84
FS-85
FS-J86
FS-87
FS-88
FS-89
FS-90
FS-91
FS-92
FS-93
FS-94
FS-95
FS-96
Description
Coal Bin metal carbonyl-
1st impinger
Coal bin metal carbonyl -
2nd impinger
Coal bin metal carbonyl-
blanks
P.G. total Sulfur impingers 1-3
C.B. total sulfur impingers 2-2
C.B. total sulfur impingers 3-2
Blank - alcoholic KOH for
total sulfur
PG-6% HzOa for total sulfur
CB-6% H202 for total sulfur
impinger 2-3
PG-6% H202 for total sulfur
impinger 1-1
CB-6% H202 for total sulfur
impinger 3-3
Blank-6% H202 for total sulfur
CB zinc acetate for total
sulfur imp. 3-1
CB zinc acetate for total
sulfur imp. 1-1
CB zinc acetate for total
sulfur imp 2-1
Date Time
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
Fe, Ni
Fe, Ni
Fe, Ni
Sulfur as
Sulfur as
Sulfur as
Sulfur as
Sulfur as
Sulfur as
Sulfur as
Sulfur as
Sulfur as
Sulfur as
Sulfur as
Sulfur as
CS2
CS2
CS2
CS2
S0x
S0x
S0x
S0x
S0x
H2S
H2S
H2S
Analysis
sulfate
sulfate
sulfate
sulfate
sulfate
- Zn S
- Zn S
- Zn S
-------
Sample No.
FS-97
FS-98
FS-99
FS-100
FS-101
FS-102
FS-103
FS-104
FS-105
FS-106
FS-107
FS-108
FS-109
FS-110
FS-111
FS-112
FS-113
FS-114
FS-115
FS-116
FS-117
FS-118
FS-119
FS-120
Description
PG zinc acetate for total
sulfur imp 1-2
Train Rinse
Blank Rinse
TB -
TB -
TB -
TB -
TB -
TB -
PG -
PG -
PG -
PG -
PG -
PG -
TB -
TB -
TB -
CB -
CB -
CB -
CB -
CB -
CB -
5Z
5Z
5Z
5Z
51
5Z
51
5Z
5Z
5Z
5Z
5Z
5Z
5Z
5%
5Z
5Z
5%
5Z
5%
n
H2SO.,
H2SOi»
H2SOi»
H2SOif
H2SOi»
H2SOi»
H2SOi»
H2SO.»
H2SOi»
H2SOi»
HzSOu
H2SOi»
H2SOif
H2SOi»
H2SO(f
H2SOi»
H2SOi»
H2SO*
HlSQk
for
for
for
for
for
for
for
for
for
for
for
for
for
for
for
for
for
for
for
for
for
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
NHs-Imp
Wit-Imp
1-1
1-2
2-1
2-2
3-1
3-2
1-1
1-2
2-1
2-2
3-1
3-2
4-1
4-2
1-1
1-2
2-1
2-2
3-1
3-2
Date Time
12-13
12-13
12-13
12-12
12-12
12-12 t
12-12
12-12
12-12
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13 .
12-13
Sulfur
Sulfur
NH9
NHs
NHs
NH3
NHs
NHs
NHs
NHs
NHs
NHs
NH3
NHs
NHs
NH3
NH3
NH3
NH3
NH3
NH3
NHj
as
as
as
as
as
as
as
as
as
as
as
as
as
as
as
as
as
as
as
as
Analysis
as H2S - Zn S
as - H2S - Zn S
NH3
NHs
NHs
NH3
NH3
NH3
NHs
NH3
NH3
NH3
NH3
NHs
NHs
NHs
NH3
NH3
NHs
NHs
NHs
NHj
NHi,
NH/
Mutt
MHii
NH^+
Mil It
Hritf
M[!IA
NH./
NH.,*
NHi,+
NHu+
mk+
NHi,"*"
NH,,"1"
NHi»+
NHv+
NH*+
MH*+
-------
Sample No.
FS-121
FS-122
FS-123
FS-124
FS-125
FS-126
FS-127
FS-128
FS-129
00
i. FS-130
VO
FS-131
FS-132
FS-133
FS-134
FS-135
FS-136
FS-137
FS-138
FS-139
FS-140
FS-141
Description
CB
CB
CB
CB
CB
CB
PG
PG
PG
PG
PG
PG
PG
TB
TB
TB
TB
TB
TB
- 10%
- 10%
- 10%
- 10%
- 10%
- 10%
- 10%
- 10%
- 10%
- 10%
- 10%
- 10%
NaOH
NaOH
NaOH
NaOH
NaOH
NaOH
NaOH
NaOH
NaOH
NaOH
NaOH
NaOH
for
for
for
for
for
for
for
for
for
for
for
for
CN
CN
CN
CN
CN
CN
CN
CN
CN
CN
CN
CN
Imp
Imp
Imp
Imp
Imp
Imp
Imp
Imp
Imp
Imp
Imp
Imp
1-1
1-2
2-1
2-2
3-1
3-2
1-1
1-2
1-2
2-2
3-1
3-2
- CN Imp Rinse
- 10%
- 10%
- 10%
- 10%
- 10%
- 10%
NaOH
NaOH
NaOH
NaOH
NaOH
NaOH
for
for
for
for
for
for
CN
CN
CN
CN
CN
CN
Imp
Imp
Imp
Imp
Imp
Imp
1-1
1-2
2-1
2-2
3-1
3-2
Trailer DI water
PS
SASS 6% H202
Date Time
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-13
12-12
12-12
12-12
12-12
12-12
12-12
12-13
12-13
CN"
CN"
CN"
CN"
CN"
CN~
CN~
CN~
CN"
CN"
CN"
CN~
CN"
CN"
CN"
CN"
CN"
CN"
CN~
Hold
Hold
as
as
as
as
as
as
as
as
as
as
as
as
as
as
as
as
as
as
as
Analysis
HCN
HCN
HCN
HCN
HCN
HCN
HCN
HCN
HCN
HCN
HCN
HCN
HCN
HCN
HCN
HCN
HCN
HCN
HCN
-------
w
CO
o
Sample No.
FS-142
FS-143
FS-144
FS-145
FS-146
FS-147
FS-148
FS-149
FS-150
FS-151
FS-152
FS-153
FS-154
FS-155
FS-156
FS-157
FS-158
FS-159
FS-160
FS-161
FS-162
Description
PG
PG
PG
TB
TB
PG
CB
CB
CB
CB
CB
TB
TB
TB
TB
PG
PG
PG
PG
PG
PG
SASS AgS20| 11
SASS AgS2Oe #2
SASS ESP Tar
SASS Filter
SASS Wash Bottle
Tenax tube-100 ml € 25 ml/M
Tenax Tube-5 mln 9 60 ml/M
Tenax Tube-2 mln @ 50 ml/M
Tenax Tube- 7 mln @ 50 ml/M
Tenax tube-5 mln @ 50 ml/M
Tenax tube-10 mln @ 60 ml/M
Bomb fl
Bomb
Bomb
Bomb
Bomb
Bomb
Bomb
Bomb
Bomb
Bomb
12
13
#4
#5
16
#7 after ESP
#8 before ESP
19 before ESP
110 after ESP
Date
12-13
12-13
12-13
12-12
12-12
12-14
12-14
12-14
12-14
12-14
12-14
12-12
12-12
12-12
12-12
12-12
12-12
12-13
12-13
12-13
12-13
Time
0215
1525
1450
1515
1500
1530
0130
1535
1551
1751
2010
2013
1715
1730
1910
1913
Analysis
Hold
Hold
SSMS*. Org, BIO
Organic
Hold. Blank
Organic
Hold
Hold
Hold
Hold
Organic
Analysed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
by GC,
by GC,
by GC,
by GC,
by GC,
by GO,
by GC,
by GC,
by GC,
by GC,
majors
majors,
majors,
majors,
majors,
majors,
majors,
majors,
majors,
majors,
s, (
S, (
s,
s,
s,
s,
s,
s,
s,
s,
'l~Cs
]l-Cg
Ci-C6
Ci-C6
Ci-C6
Ci-C6
Ci-C6
Ci-C6
Cj-Cg
c,-c.
^Includes Hg, As, Se, Sb by A.A.
-------
Sample No.
Description
Date Time
Analysis
FS-163
FS-164
FS-165
FS-166
FS-167
FS-168
FS-169
FS-170
FS-171
PG Bomb #11 after ESP
PG Bomb #12 before ESP
CB Bomb #13
CB Bomb #14
AgS2Oe Blank
PG Probe Rinse (lumpy)
PG XAD resin
PG SASS Filter #122 (.3065g)
PG SASS Filter #123 (.2389g)
12-13 2200
12-13 2320
12-14 1415
12-14 1456
12-13
12-13
12-13
Analyzed by GC, majors, S,
Analyzed by GC, majors, S,
Analyzed by GC, majors, S,
Analyzed by GC, majors, S,
TM - SSMS
Organic, SSMS*, BIO
Organic, BIO
SSMS*, Organic, BIO
*Includes Hg, As, Se, Sb by A.A.
-------
REFERENCES
B-l Lentzen, D.E., D.E. Waggoner, E.D. Estes, and W.F. Gutknecht.
IERL-RTP Procedures Manual: Level 1 Environmental Assessment
(Second Edition). NTIS No. PB-293 795. Research Triangle
Institute, Research Triangle Park, North Carolina, 1978.
B-32
-------
APPENDIX C
ANALYSIS METHODS
TABLE OF CONTENTS FOR APPENDIX C
Cl.O ANION/CATION METHODS C-2
Cl.l Ammonia C-2
C1.2 Cyanide C-2
C1.3 Chloride C-2
C1.4 Fluoride C-2
C1.5 Phosphate C-3
C1.6 Nitrate C-3
C1.7 Nitrite C-3
C1.8 Sulfate C-3
C1.9 Sulfite - Sulfide C-3
C1.10 pH C-4
Cl.ll Total Dissolved Solids C-4
C2.0 ELEMENTAL ANALYSIS C-A
C2.1 Spark Source Mass Spectrometry .......... C-4
C2.2 Antimony, Arsenic, Selenium, and Mercury C-4
C2.3 Metal Carbonyls C-5
C2.4 Inductively Coupled Argon Plasma Emission
Spectrometry (ICP) C-5
C2.5 Proximate/Ultimate Analysis C-5
C2.6 Mineral Analysis C-5
C2.7 Gross Alpha and Beta Radiation C-5
C2.8 Specific Isotope Analyses C-6
C3.0 GAS CHROMATOGRAPHY C-7
C3.1 Volatile Sulfur Species C-7
C3.2 Fixed Gases C-7
C3.3 Light Hydrocarbons C-13
C4.0 ORGANIC ANALYSIS C-21
C4.1 Extractions C-21
C4.2 Total Chromatographable Organics (TCO) C-21
C4.3 Gravimetric Analyses (GRAY) C-22
C4.4 Liquid Chromatographic Separation C-22
C4.5 Infrared Analysis C-23
C4.6 Gas Chromatographic Analysis - Hall Dectector . . . C-23
C4.7 Mass Spectrometric Analysis C-23
C4.8 Chemical Oxygen Demand (COD) C-24
C4.9 Biochemical Oxygen Demand (BOD) C-24
C4.10 Phenols C-24
C4.11 Total Orgnaic Carbon (TOC) C-25
C5.0 LEACHING STUDIES C-26
REFERENCES C-27
C-l
-------
Cl.O ANION/CATION METHODS
Cl.l Ammonia
Ammonia in the sulfuric acid impinger solutions and water samples
was determined on-site by the distillation/titrimetric procedure (Ref.
C-l). The sample was initially distilled into an indicating boric acid
absorbing solution. The collected distillate was then titrated with
standard sulfuric acid. Detection limit for the procedure is 1.4 Mg/ml
ammonia. This is equivalent to 1.7 ppm ammonia by volume collected from
0.28 SCM of sample gas in 200 ml impinger solutions.
C1.2 Cyanide
Interfering sulfide was precipitated from the caustic impinger
solution and water samples with lead nitrate. An acid reflux distillation
procedure was then used to remove interferences, and the cyanide concentra-
tion determined using the standard colorimetric method (Ref. C-l). Dis-
tilled cyanide collected in a caustic solution, was converted to cyanogen
chloride by reaction with chloramine-T. Following complete conversion a
pyridine-barbituric acid reagent was added to produce a red-blue dye with
absorbance at 578 run. Cyanide in the range of 1-10 g was determined spec-
trophotometrieally by comparison with a standard calibration curve gener-
ated with potassium cyanide standard solutions. Detection limit for the
procedure is .02 yg/ml cyanide. This is equivalent to 0.15 ppm hydrogen
cyanide by volume collected from 0.28 SCM sampled gas in 200 ml impinger
solution.
C1.3 Chloride
A Dionex Model 14 ion chromatograph with a conductivity detector
was used to measure chloride concentration in aqueous samples. An
injection volume of 100 yl of sample was used and eluted with 0.003M
Na2C(>3/0.003M NaHC03. A detection limit of 0.1 ppm was reported.
Sample response was compared to a standard curve.
C1.4 Fluoride
Baker (Ref. C-2), Bauman (Ref. C-3), and Thomas (Ref. C-4),
describe standard addition techniques utilizing a specific ion electrode
for the measurement of fluoride in aqueous samples. A citrate buffer was
added to the sample to buffer both pH and ionic strength. Fluoride bound In
metal complexes is released by the buffer. Fluoride concentration was
related to potential changes which were measured using an Orion Model
94-09A solid state fluoride electrode and an Orion Model 701A Ion analyzer
meter. A detection limit of 0.05 ppm was reported.
C-2
-------
C1.5 Phosphate
Phosphate was determined by the standard method (Ref. C-l) as the
molybdenum blue complex. The aqueous sample was reacted with acidic
ammonium molybdate to form a yellow phosphomolybdate complex. The addition
of ascorbic acid develops the blue color which is measured with a
spectrophotometer. A detection limit of 0.5 ppm was reported.
C1.6 Nitrate
Nitrate was determined as in the standard method (Ref. C-l) by a
colorimetric method in which nitrate reacts with chromotropic acid to form
a yellow reaction product which was measured spectrophotometrically at 410
nm and compared to a set of standards. A detection limit of 0.1 ppm was
reported.
C1.7 Nitrite
Nitrite in solution was determined by a colorimetric procedure
(Ref. C-l) in which a reddish-purple dye was produced by the coupling of
diazotized sulfanilic acid with naphthylamine hydrochloride. The dye was
measured colorimetrically at 543 nm and compared to a standard calibration
curve. A detection limit of 0.01 ppm was reported.
C1.8 Sulfate
In aqueous samples, sulfate was determined by the addition of
barium chloride (Ref. C-l). The resulting turbid solution was analyzed
spectrophotometrically at 450 nm. Standard curves were prepared for sample
quantitation. A detection limit of 5 ppm was reported.
Sulfur dioxide and sulfur trioxide in gaseous streams were
analyzed as the sulfate. Both gas species were adsorbed and oxidized to
sulfate in hydrogen peroxide impinger solutions. The solutions were then
boiled to remove the excess H2
-------
C1.10 p_H
The pH of each sample was measured using an Orion 701 pH meter.
Cl.ll Total Dissolved Solids
Total dissolved solids were measured by the standard method (Ref.
C-l). A 100 ml aliquot of the aqueous sample was filtered through an 0.8u
filter. The filtrate was poured into a pre-weighed beaker and taken to
dryness. The salts and beaker were weighed and solids content calculated.
C2.0 ELEMENTAL ANALYSES
C2.1 Spark Source Mass Spectrometry
Trace metals in the gas streams were analyzed by spark source mass
spectrometry (SSMS). Samples were collected in two different sampling
trains; by the SASS silver persulfate method (Ref. C-5), and by the acid/
base collection method. The Impinger volumes were determined and aliquots
that represented a constant volume of gas were removed from each impinger
in the collection train. These aliquots of absorbing solution were com-
posited for SSMS analysis to form a sample representative of each collec-
tion train. Aliquots of the liquid samples were sent directly for SSMS
with no additional sample preparation. Solid samples were also sent di-
rectly for SSMS. XAD-2 resin samples were combusted in an oxygen combus-
tion bomb. The resulting gas was absorbed in dilute nitric acid and
analyzed like liquid samples by SSMS.
C2.2 Antimony, Arsenic, Selenium and Mercury
The volatile elements were analyzed directly from the composite
Impinger samples and aqueous samples by atomic absorption (AA) spectro-
photometry. Solids, however, were first weighed into a Vycor cup and placed
in a Parr combustion bomb. The bomb was sealed, pressurized with oxygen
and the sample ignited. The resultant combustion products were absorbed in
a 20Z Ultrex nitric acid solution for analysis by atomic absorption.
Arsenic, antimony, and selenium were analyzed by the use of the
hydride generation attachment of the atomic absorption spectrometer (Ref.
C-5). An aliquot of sample was Introduced into the system, acidified, and
sodium borohydride was added to reduce the species to the hydride. The
generated gas was purged into a hydrogen-argon flame for analysis.
The absorbances and detection limits are shown in the table below.
Element Wavelength Detection Limit*
As 193.7 ran 3 ppb
Sb 217.0 nm 5 ppb
Se 196.0 nm 4 ppb
* ng/ml of solution
C-4
-------
Mercury was determined by the procedure of Hatch and Ott (Ref.
C-6). Samples were acidified and the mercury oxidized with potassium perman-
ganate. Hydroxylamine hydrochloride and stannous chloride were used to
reduce the mercury to the metallic state. Then, air was bubbled through
the solution. The mercury-entrained air was passed through the absorption
cell of an AA and quantified at 263.7 nm. A detection limit of 0.2 ppb was
reported.
C2.3 Metal Carbonyls
Nickel and iron carbonyl trapped from gaseous streams in HC1
impinger solutions were analyzed by direct injection into the flameless
atomizer attachment of the AA. Instrumental parameters were:
Detection
ISlement Wavelength Dry Char Atomizer Limit*
Fe 248.3 nm 100°C 1100°C 2500°C 1 ppb
Ni 232.0 nm 100°C 1100°C 2700°C 5 ppb
*ng/ml of solution
C2.4 Inductively Coupled Argon Plasma Emission Spectrometry (ICP)
Samples of cyclone quench water, gasifier ash sluice water, and
perchloric acid digestions of gasifier ash, cyclone dust, and product gas
solids were analyzed for twenty-two elements by ICP. The liquid sample was
aspirated into an argon plasma. The high temperature of the plasma
(MO,000°C) induces electronic excitation of the atoms. The emitted light
is passed through a slit and diffracted by a grating. Photomultiplier
tubes are set at the characteristic wavelengths of the elements measured.
C2.5 Proximate/Ultimate Analysis
Proximate/Ultimate analyses were done on solids by ASTM methods
D-3172-73 and D-3176-74.
C2.6 Mineral Analysis
Mineral analyses were performed on solid samples by solid
dissolution and analysis by atomic absorption.
C2.7 Gross Alpha and Beta Radiation
The amount of alpha and beta radiation emitted from the solid
samples was measured by counting alpha and beta particles using a
Geiger-Mueller tube. Differential absorbing plates were used to separate
alpha particles from beta.
C-5
-------
C2.8
Specific Isotope Analyses
Samples of coal, gasifier ash, and cyclone dust were analyzed for
Radian by ORP/EERF. Each Isotope emits a characteristic radiation, there-
fore various counting techniques were employed. The following table lists
the isotopes and the measurement technique.
TABLE C-l. ISOTOPE MEASUREMENT TECHNIQUE
Isotope
U-234
U-235
U-238
Th-227
Th-230
Th-232
Po-210
Pb-210
Ra-226
K-40
Pb-214
Bi-214
Th-232 (ash)
Detector
alpha spectrometry (surface barrier detector)
alpha spectrometry (surface barrier detector)
alpha spectrometry (surface barrier detector)
alpha spectrometry (surface barrier detector)
alpha spectrometry (surface barrier detector)
alpha spectrometry (surface barrier detector)
alpha spectrometry (surface barrier detector)
alpha-beta detector (IPC)
Lucas chamber
Ge-Li gamma spectrometer
Ge-Li gamma spectrometer
Ge-Li gamma spectrometer
Ge-Li gamma spectrometer
C-6
-------
C3.0 GAS CHROMATOGRAPHY
Grab samples of the product gas, product gas vent, test burner
flue gas, and coal bin vent gas were taken for the gas chromatographic
analysis of:
• major components: H2, 02 + Ar, N2, C02, CO, and CH4,
• volatile sulfur species: H2S, COS, S02, CH3SH,
C2H5SH, (CH3)2S, and CS2,
• light hydrocarbons: Cj to C^, boiling range -160°C to 80°C
Samples were taken at the product gas vent before and after an
electrostatic precipitator (ESP) sampling device and evaluated for any
compositional changes due to the ESP. The samples were taken in silanized
glass sample bombs and analyzed immediately.
C3.1 Volatile Sulfur Species
The instrument operating parameters for the analysis of the
volatile sulfur species were:
Instrument: Tracor Model 560 FPD-GC
Column: 3.05 m x 3. 1 mm Teflon®, 1% TCEP
[l,2,3-tris(cyanoethoxy) propane] and
0.5% H3P04 on Carbopack B, 60/80 mesh
Carrier: Nitrogen at 20 ml/min
Detector Temperature: 150°C
Oven Program: 30°C for 7 min; 10°C/min to 120°C; 120°C
for 10 min
Standard samples were generated on site using Metronics permeation
tubes with certified permeation rates and zero grade nitrogen at known
flows. The calibration curves for H2S at both high, 190 to 1650 vppm,
and low, 5 to 25 vppm, concentration ranges are given in Figures C-l and
C-2. The calibration curves for COS, at 20 to 150 vppm, S02 at 50 to 450
vppm, and CS2 at 1 to 10 vppm are given in Figures C-3 to C-5. The 95
percent confidence interval (2a) and the number of determinations for each
calibration point are given on the figures.
C3.2 Fixed Gases
The fixed gas analyses were carried out under the following
conditions:
Instrument: Fisher Gas Partitioner Model 1200 TCD-GC
Column 1: 2 m x 3.1 mm, Porapak PQ
Column 2: 3.4 m x 4.8 mm, Molecular Sieve 13X
Carrier: 8.5% Hydrogen in Helium at 30 ml/min
Oven Temperature: 50°C
Bridge Current: 275 mA
C-7
-------
u
en
I
CO
to
15.7 _
15.5 -
15.3 -
15.1 -
14.9
14.7 _
14.5 -
14.3 -
14.1 -
(0.097, 6)
. (0.051, 3)
(0.030, 3)
T T I III III 1
30 40 50 75 100 125 150 200 250 300 350
SULFUR, ng (to detector)
Figure C-l. H2S Calibration Curve, High
Concentration Range
C-8
-------
w
en
O
p-
W
8.4 -
8.2 -
8.0 -
7.8 .
7.6 -
7.4 .
7.2 .
7.0 '
6.8 .
6.6 .
6.4 ,
6.2
6.0 .
5.8
5.6
5.4
5.2
(0.056, 2)
(0.064A, 4)
(a, b)
a - 2a
b » determinations
(0.120. 4)
SULFUR, ng (Co detector)
Figure C-2.
Calibration Curve, Low
Concentration Range
C-9
-------
12.4 -J
(0.199, 2)
12.2
(0.277, 2)
11.8
11.4
(0.099, 3)
w
a
11.0
10.6 J
. (0.154, 3)
(0.138, 6)
10.2 J
9.8 J
9.4 J
9.0 J
C0.270,3)»
8.6
I I I I
567
I I I I I I I
10 12 15 20 25 30 40
3 4
Sulfur, ng (to detector)
Figure C-3. COS Calibration Curve
C-10
-------
(0.150, 2)
CO
(0
C
o
p.
CO
14.4 _
14.0—
13.6 —
13.2.
12.!
12.4—
12.0—
11.6
11.2—
(0.279, 2).
(0.084, 3) •
(0.201. 6)
(0.244, 3)
(a. b)
a - 2o
b » determinations
10.8—
• (0.293. 3)
11 15 20 25 30 35 40 50
Sulfur, ng (to detector)
75 100
Figure C-4. S02 Calibration Curve
C-ll
-------
o
o
9.8-
9.4 _
9.0-
8.6-
8.2-
7.4 —
7.0.
6.2-
(O.m, 6)
0.270. 3),
(0.201, 2)
(0.5U. 2) •
'• (0.196. 3)
(0.184. 3)
(a,b) a - 2a
b » determinations
I I T IT III I I
0.5 0.75 1.0 1.25 1.5 2.0 2.5 3.0 4.0 5.0
Sulfur, ng (to detector)
Figure C-5. CSj Calibration Curve
C-12
-------
The instrument calibration for the fixed gases was performed
on-site using standard gas mixtures supplied by Scientific Gas Products
containing the species of interest. The certified mixtures used for
on-site calibration have the following compositions:
Species Standard 1 Standard 2
C02 19.6% 9.85%
H2 13.1% 48.6%
02 2.16% 0
N2 34.9% 12.9%
CO 25.6% 13.8%
CH4 4.6% 14.8%
Figures C-6 to C-9 show the calibrations that were used. The 95
percent confidence limit (2a) is given on each figure as is the number of
individual determinations included in each calibration point.
C3.3 Light Hydrocarbons
C^-Cg hydrocarbons were analyzed on site using the following
operating parameters:
Instrument: Hewlett-Packard Model 5737A FID-GC
Column: 3.05 m x 2 mm i.d. stainless steel,
Porapak Q
Carrier: Nitrogen at 30 ml/min
Detector Temperature: 200°C
Oven Program: 50°C for 8 min; 16°C/min to
200°C; 200°C for 16 min
The calibration curves for this analysis are given in Figures C-10 to C-12.
The number of determinations at each point and the 95 percent (2a) confi-
dence limits are given on each calibration curve.
C-13
-------
1000 -
CO,
CUMCEHTRATIOM
Figure C-6. COz and CO Calibration Curve
C-14
-------
30 -I
25 -4
(1.0, 3)
«2 20 -4
•3
0)
a,
CO
a
o
15 -J
10 H
(1.2, 3)
(a,b) a = 2a
b • determinations
I
10
i ^ r^
20 30 40
Concentration %
50
Figure C-7. H2 Calibration Curve
C-15
-------
200
T
10
CONCENTRATION Z
(45.6. 3)
(a. b)
a - 2o
b - dettrminations
15
Figure C-8. 02 and CH* Calibration Curve
C-16
-------
800
(22.6. 2)
700
•3
Q)
0)
-------
(106. 2)
1000 _J
800—J
«0
Q»
*« 600.
0
P«
m
o>
06
(«. b)
• - 2a
b • d«C«mlrution«
T I T
10 15 20 25
Concentration (VPPM)
30
Figure C-10. CI-GS Pariffins Calibration Curve
C-18
-------
1000 _
800 -
600 -
rt
cd
0)
-------
1200-1
1000—1
800—1
3
42
3 600-J
s
O
o.
CD
0>
400—1
200H
(119. 2)
C.
(241. 2)
(a. b)
a - 2o
b - determination*
0
f 1 1 r~
5 10 15
1
20
1
25
F"
30
Concentration (VPPM)
C-12. C5, Ce Oleflns Calibration Curve
C-20
-------
C4.0 ORGANIC ANALYSIS
Preliminary laboratory analysis of the samples was done using
previously established methods (Ref. C-5). Modifications to these
procedures are included with the following descriptions of the analytical
methods. The detailed analysis was done using specific ion monitoring
GC-MS, after a halogen-specific detector was used for gas chromatography.
The halogen-specific GC was added as a means of obtaining information which
could be used for specific compounds and classes of compounds at very low
additional cost to the detailed phase of the analysis.
C4.1 Extractions
Aliquots of the aqueous samples were extracted at both pH = 2 and
pH = 12. The extractions were done serially with methylene chloride and
ethyl ether in order to obtain the widest range of extractable organics.
Solid samples were extracted in Soxhlet continuous extractors for 24 hours
with methylene chloride followed by 24 hours with ethyl ether. The use of
ethyl ether in these extractions was an addition to the previously cited
procedures (Ref. C-5).
Following extractions, the solvent extracts were combined and
concentrated using Kuderna-Danish concentrators equipped with Snyder
columns.
C4.2 Total Chromatographable Organics (TCP)
The TOO analysis provides a means of quantifying organics in the
boiling range from 100°C to 300°C. The compounds eluted were quantified by
comparison to n-paraffin standards of the Cy to Cjj boiling range. TCO
analyses were performed according to the following conditions:
Instrument: Tracer Model 560 FID-GC
Column: 3.05 m x 2 mm o.d. glass, 10% OV-101 on
Supelcbport 100/120 mesh
Carrier: Nitrogen at 30 ml/min
Oven Program: 50°C for 5 min; 20°C/min to 250°C; 250°C
hold until baseline reestablished
Injector: 275°C
Detector: 300°C
Chromatograms were integrated and stored using a Spectra-Physics
Model 4000 with a Model 4050 printer-plotter. A Cj through Cjy plus
C2Q standard was run to establish retention times and boiling ranges
while quantification was done using a G£, Ci2> an<* ^16 standard at
concentrations approximating the sample values. Solvent blanks for all
samples were run and subtracted from the samples.
C-21
-------
C4.3 Gravimetric Analyses (GRAY)
The GRAV analysis provides a quantification for the non-volatile
components in a sample extract. Gravimetric analyses for unfractionated
samples were done using a Mettier Model H20 five place analytical balance.
A 5 ml aliquot of the sample extract was evaporated at room temperature in
a dessicator. If less than 10 mg of material was present, volumetric
aliquots were added until a reproducible +0.1 mg weight in the 10 mg ranee
was achieved. For concentrated extracts, a 1.0 ml aliquot was evaporated
in Cargllle microbeakers. For GRAV analysis of the 1C fractions a Perkin-
Elmer AD-2 electronic autobalance was used (Section 4.4). Sample aliquots
were taken according to the standard procedure (Ref. C-5). Solvent blanks
and 1C fraction blanks were run in the same manner as the samples. Prior to
use, all glassware was dichromate washed, rinsed with distilled water then
methanol and methylene chloride rinsed.
C4.4 Liquid Chroaatographic Separation (LC)
The LC separation gives a fractionation of the sample extract into
compound classes based on the polarity. This separation then facilitates
the subsequent detailed analysis. This is not a high resolution technique
and compound classes may overlap in individual fractions. However with
adequate care, reproducible, predictable separations can be achieved.
The samples were prepared for the liquid chromatography according
to recommended procedures (Ref. C-5). Extracts which had no TCO portion
such as the gasifier ash were evaporated to dryness on silica gel and the
silica gel which contained the sample transferred to the head of a prepared
LC column. Samples which had TCO content were exchanged from methylene
chloride/ethyl ether into cyclopentane using the recommended three 1 ml
exchange evaporations. After the exchange volume has been reduced to 1 ml
for the last time, the solvent mixture should be less than five percent
methylene chloride/ether. This should be sufficiently low not to alter the
polarity of the elution series so that no aromatic components will break
through into the aliphatic fraction. The LC column parameters were as
follows:
Column: 200 mm x 10.5 mm o.d., glass with Teflon*
stopcock, glass solvent reservoir, water
jacketed, outlet water temperature 20°C
Absorbent: Silica gel, 60-200 mesh, Davidson, Grade
950. Soxhlet extracted with methanol,
methylene chloride and pentane, activated
at 110°C for 2 hours
The LC column was slurry packed and a flow rate of less than 1
ml/min used. Seven LC fractions were collected according to the appropriate
elution sequence and volumes (Ref. C-5).
C-22
-------
C4.5 Infrared Analysis
Infrared analyses were done using a Perkin-Elmer Model 283 grating
spectrophotometer. The GRAV aliquots were taken up in methylene chloride
and run as thin films between two sodium chloride plates. Transmission
spectra were run from 4000 cm-1 to 400 cm-1. Daily quality checks were
made to verify that the instrument met the instrument operating require-
ments outlined (Ref. C-5).
C4.6 Gas Chromatographic Analysis - Hall Detector
Gas chromatography was done using the Hall 700 electrolytic con-
ductivity detector in halogen specific mode. This enabled a measurement to
be made analogous to the TCO value that indicated a chromatographic halogen
content. Aliquots of the samples prior to the LC separation were run as
well as specific fractions which could potentially contain the bulk of the
halogenated material. Dual injection mode was utilized as a means of
correlating the halogen containing peaks with the FID results. The
procedures used were:
Instrument: Tracer Model 560 Hall/FID/GC
Columns: 3.05 m x 2 mm o.d., glass, 10% OV-101 on
Supelcoport 100/120 mesh
Carrier: Nitrogen at 25 ml/min
Oven Program: 50°C for 5 min; 20°C/min to 300°C; 300°C
until baseline
Injector: 250°C
Detector: Hall = 300°C, FID = 300°C
Samples were solvent exchanged into acetonitrile prior to analysis
in order not to overload the Hall detector with halogenated solvent. A
chlorinated phenol standard was used as a reference for concentration
correlations.
C4.7 Mass Spectrometrlc Analysis
The LC fractions were submitted for mass spectral analysis
following a prioritization scheme based on the MEG's which generated lists
of some specific compounds of interest. Selected ion monitoring (SIM)
searches were performed to identify organics of interest. This technique
is based on the appearance of specific key fragmentation ions within a
known GC retention time window. Quantitation was done by response factor
comparison to a known amount of d}Q-anthracene which was used as an
internal standard. The selected ions monitored were varied as the gas
chromatographic retention times of the various compounds of interest
progressed. The mass spectral information obtained was stored on magnetic
disk for reference.
The concentrated sample extracts were analyzed using a computer-
controlled Hewlett-Packard Model 5985 mass spectrometer system in the
specific ion monitoring mode. The analyses were carried out under the
following gas chromatographic and mass spectrometer operating conditions:
C-23
-------
Column: 1.8 m x 2 mm o.d., glass, 3% SP-2250
Carrier: Helium at 30 ml/mln
Oven Program: 50°C for 4 min; 8°C/mln to 260°C; 260°C
for 8 min
lonization Voltage: 70eV
Tenax-GC with silica gel was used to trap components in the
boiling range of 30°C to 150°C and allow analysis for benzene-toluene-
xylene compounds at lower concentrations. The Tenax-GC tube was analyzed
by thermal desorption gas chromatography-mass spectrometry (GC-MS). With
this technique, the glass-lined steel tube which contains the volatile
sample sorbed onto Tenax-GC and silica gel is heated while nitrogen flows
through the tube. The nitrogen stream carries the thermally desorbed
organics onto the GC column where they are separated and then into the mass
spectrometer for quantification. Hexadeuterobenzene was used as the
internal standard for this analysis.
C4.8 Chemical Oxygen Demand (COD)
Chemical oxygen demand was determined by the standard method (Ref
C-l). Samples are refluxed for two hours with potassium dichromate and
sulfuric acid. After cooling, the remaining dichromate is titrated with
ferrous ammonium sulfate. The amount of potassium dichromate consumed is
proportional to the amount of oxidizable organic matter in the sample. A
detection limit of 5 ppm was reported.
C4.9 Biochemical Oxygen Demand (BOD)
BOD was determined according to specified procedures (Ref. C-l).
BOD is a measure of the change in dissolved oxygen after five days incu-*
bation at 20°C. An Initial dissolved oxygen determination is made using
the azide modification of the Winkler titration. In this procedure, iodine
is liberated and titrated with a standard sodium thiosulfate solution.
After five days a final concentration was determined. The change in dis-
solved oxygen is related to the amount of orgnaic mattter which is assimi-
lated and oxidized by microorganisms.
C4.10 Phenols
Phenols were analyzed in aqueous samples by standard methods (Ref
C-l). These methods include a distillation procedure in which phenols are
removed from interferences and a colorimetric measurement. In the colori-
metric procedure, phenols in the distillate react with 4-aminoantlpyrine
pH 10 in the presence of potassium ferricyanlde to form a colored anti-
pyrine dye. This dye is extracted with chloroform and the absorbance is
measured with a spectrophotometer at 460 nm. A detection limit of 10 DDK
was reported.
C-24
-------
C4.ll Total Organic Carbon (TOC)
TOG was determined using a Dohrmann Model 54 TOC Analyzer. The
sample was placed in a sparging reservoir and a potassium persulfate-
phosphoric acid reagent was added. The inorganic carbon was purged from
the sample, followed by UV oxidation of the organic carbon to C02« The
C02 is then subjected to reductive pyrolysis to produce methane and FID
detection of the methane determines the total organic carbon content of the
sample. A calibration curve was generated by analyzing known solutions of
potassium acid phthalate. A detection limit of 10 ppb was reported.
C-25
-------
C5.0 LEACHING STUDIES
Gasifier ash and cyclone dust were extracted using the Resource Conser-
vation and Recovery Act (RCRA) procedure as outlined in the Federal
Register of December 18, 1978, "Hazardous Waste, Proposed Guidelines and
Regulations'" (Ref. C-7). One hundred grams of the air dried solid was
weighed into a polyethylene bottle along with a weight of deionized water
equal to 16 times the weight of the solid. The pH was adjusted to 5.0 with
Ultrex glacial acetic acid. The pH was monitored for one hour and adjusted
as needed.
The sample was agitated for 24 hours with a rotary shaker. At the end of
the 24 hour leaching, the samples were filtered through a 0.45 micron
Millipore filter. The filtrate was diluted to 20 times the initial weight
of the solid. The dilute filtrates and blanks were preserved for analysis.
The total dissolved solids, total suspended solids, and the pH of the
samples were measured. They were also analyzed for:
Ammonia
Cyanide
Chloride
Fluoride
Phosphate
Nitrate
Nitrite
Sulfate, and
Sulfite
using the anion and cation analysis methods given in Section Cl.O. Analyses
for COD, BOD, TOC, and phenols were done by the methods described in Sec-
tion C4.0; and trace element analysis were done by the methods outlined in
Section C2.0.
C-26
-------
REFERENCES
C-l American Public Health Association, American Water Works Association,
and Water Pollution Control Federation, Standard Methods for the
Examination of Water and Wastewater, 14th edition. Washington, D.C.,
American Public Health Association, 1975.
C-2 Baker, R.L., "Determination of Fluoride in Vegetation Using the
Specific Ion Electrobe," Anal. Chem. 44(7), 1326, (1972).
C-3 Baumann, Elizabeth W., "Trace Fluoride Determination with Specific Ion
Electrode," Anal. Chem. Acta 42, 127-132, (1968).
C-4 Thomas, Josephus, Jr. and Harold J. Gluskoter, "Determination of
Fluoride in Coal with the Fluoride Ion-Selective Electrode," Anal.
Chem. 46(9), 1321, (1974).
C-5 Lentzen, D.E., D.E. Waggoner, E.D. Estes, and W.F. Gutknecht, IERL-RTP
Procedures Manual: Level 1 Environmental Assessment (Second Edition),
NTIS No. Pb-293 795, Research Triangle Institute, Research Triangle
Park, North Carolina, October 1978.
C-6 Hatch, W. Ronald and Welland L. Ott, "Determination of Submicrogram
Quantities of Mercury by Atomic Absorption Spectrometry," Anal. Chem.
40(14), 2085-7, (1968).
C-7 Resource Conservation and Recovery Act, Public Law 95-580.
C-27
-------
APPENDIX D
ANALYTICAL DATA
TABLE OF CONTENTS FOR APPENDIX D
Dl.O ON-SITE GAS ANALYSIS RESULTS D-2
Product Gas, Tables Dl to D3 D-4
Test Burner Flue Gas, Tables D4 and D5 D-7
Coal Bin Vent Gas, Table D6 D-9
D2.0 INORGANIC ANALYSIS RESULTS D-10
Product Gas, Tables D7 to D14 D-14
Test Burner Flue Gas, Tables D15 to D26 D-23
Gasifier Ash, Tables D27 to D35 D-36
Cyclone Dust, Tables D36 to D44 D-46
Lignite, Tables D45 to D55 D-56
Service Water, Table D56 D-68
Leachate, Tables D57 to D64 D-70
D3.0 ORGANIC SCREENING ANALYSIS RESULTS D-78
Product Gas Particulates, Tables D65 and D66 D-80
Product Gas Organic Module Composite,
Tables D67 and D68 D-87
Test Burner Flue Gas Composite,
Tables D69 and D70 D-94
Gasifier Ash, Tables D71 and D72 D-101
Cyclone Dust, Tables D73 and D74 D-108
Gasifier Ash Sluice Water, Table D75 D-116
Cyclone Dust Quench Water, Table D76 D-119
D4.0 DETAILED ORGANIC ANALYSIS RESULTS D-120
Product Gas Particulates, Tables D77 to D83 D-122
Product Gas Organic Module Composite,
Tables D84 to D87 D-131
Test Burner Flue Gas Composite,
Tables D88 and D89 D-136
Gasifier Ash, Table D90 D-139
Cyclone Dust, Table D91 ...... D-141
D-l
-------
Dl.O ON-SITE GAS ANALYSIS RESULTS
The gas streams analyzed cm-site were the:
• Product Gas
- prior to the test burner, and
- at the start-up vent
• Test Burner Flue Gas
• Coal Bin Vent Gas
The anlaysis methods used on-site are given in Appendix C. The analytical
data is summarized by gas stream and the analysis parameters for each
stream are given in Figure Dl.
D-2
-------
Gas Chromatography Impinger Analysis
Fixed Sulfur
Gases Species Hydrocarbons Ammonia Cyanide
Product Gas e • • • •
Product Gas (Vent) • • •
Test Burner Flue Gas • • • • •
Coal Bin Vent Gas • •
Figure Dl. On-Site Gas Analysis Matrix
D-3
-------
TABLE Dl. GAS CHROMATOGRAPHY ANALYSIS RESULTS: PRODUCT GAS
DATE:
TIME:
Major Component s-%
CO 2
H2
02 + Ar
N2
CO
CHH
Sulfur Species - Vppm
H2S
COS
S02
CS2
Hydrocarbons - Vppm
CH,,
C2H6
C2KU
C3-isomers
C,,-isomers
Cg-isomers
Ce-isomers
12-12-78
2010
7.5
18.9
0.38
41.8
30.0
1.4
1033
130
ND
15.8
10222
725
315
456
178
88
148
12-12-78
2013
7.6
18.7
0.41
41.1
31.1
1.2
1015
137
1.4
15.7
10116
726
328
479
218
84
174
ND - not detected.
D-4
-------
TABLE D2. AMMONIA AND CYANIDE ANALYSIS RESULTS: PRODUCT GAS
Species
Ammonia
Ammonia
Ammonia
Cyanide
Cyanide
Cyanide
SCM*
Sampled
0.0274
0.0298
0.0322
0.143
0.117
0.134
Total
Mg
20400
659100
271600
37400
27800
22100
vppm
1299
869
357
236
215
150
*SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
D-5
-------
TABLE D3. GAS CHRCHaTOGRAPHY ANALYSIS RESULTS: PRODUCT GAS VENT
DATE:
TIME:
Major Component s-I
C02
H2
02+ Ar
N2
CO
CH*
Sulfur Species - Vppm
H2S
COS
SO 2
CS2
Hydrocarbons - Vppm
CH*
C2H6
C2Hi»
Cs + isomers
Ci» + isomers
C5 + Isomers
Ce + isomers
12-13-78
1715
After ESP
8.7
14.4
0.58
46.02
29.0
1.3
1055
139
1.0
12.9
9135*
618
288
455
191
96
169
12-13-78
1730
Before ESP
8.6
16.0
0.57
45.4
28.0
1.4
1140
145
1.4
15.5
10257*
701
307
459
184
98
186
12-13-78
1910
Before ESP
9.0
15.8
0.49
46.4
27.0
1.3
1098
145
2.2
10.6
10105*
697
347
462
199
98
199
12-13-78
1930
After ESP
9.4
16.8
0.54
45.0
27.0
1.3
1209
154
ND
12.9
10227*
694
361
482
231
172
253
12-13-78
2200
After ESP
10.8
13.4
1.0
50.6
23.0
1.2
1024
130
61.9
9.4
8356
540
274
388
177
149
123
12-13-78
2320
Before ESP
10.3
15.8
0.78
47.7
24.0
1.4
1121
145
30.2
9.8
9477
606
307
422
174
598
250
ND - Not detected.
*Single analysis only.
-------
TABLE DA. GAS CHROMATOGRAPHY ANALYSIS RESULTS: TEST BURNER FLUE GAS
DATE:
TIME:
Malor Components - %
CO 2
H2
02 + Ar
N2
CO
CKn
Sulfur Species - Vppm
H2S
COS
SO 2
CS2
12/12/78
0130
3.8
2.8
16.3
77.1
ND
ND
19.5
0.2
170.0
5.0
12/12/78
1535
6.0
ND
14.1
79.8
ND
ND
ND
ND
138.0
4.8
12/12/78
1551
5.8
ND
14.2
80.0
ND
ND
V
ND
ND
39.7
1.2
12/12/78
1715
*
6.2
ND
19.2
74.5
ND
ND
ND
ND
64.0
ND
Hydrocarbons - Vppmt
C2H6
Cs
C if
Cs
- isomers
- isomers
- isomers
- isomers
5.9
8.0
3.6
VSingle point analyses due to insufficient sample pressure,
sample probably diluted with additional air
*Slight condensate visible in sample bomb.
ND « Not detected.
tHydrocarbons not detected <1 Vppm
D-7
-------
TABLE D5. AMMONIA AND CYANIDE ANALYSIS RESULTS: TEST BURNER FLUE GAS
Species
Ammonia
Ammonia
Ammonia
Ammonia
Cyanide
Cyanide
Cyanide
SCM*
Sampled
0.175
0.268
0.567
0.390
0.274
0.272
0.223
Total
ug
ND
ND
ND
ND
ND
332
459
Vpptn
<0.005
<0.005
<0.005
<0.005
<0.02
1.1
1.9
ND = Not detected.
*SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
D-8
-------
TABLE D6. AMMONIA AND CYANIDE ANALYSIS RESULTS:
COAL BIN VENT GAS
Species
Ammonia
Ammonia
Ammonia
Cyanide
Cyanide
Cyanide
SCM*
Sampled
0.567
0.475
0.466
0.430
0.543
0.574
Total yg
193
ND
ND
27
17
20
Vppm
0.49
<.005
<.005
0.057
0.028
0.032
*SCH at 25°C (77°F) and 101 kPa (1 atm) , dry basis.
D-9
-------
D2.0 INORGANIC ANALYSIS RESULTS
The results of the laboratory analyses given in the following data
sections were obtained using the analytical methods described in Appendix
C. The individual samples and the analysis parameters are listed by stream
in Figure D2. The analysis results for each sample are presented following
the appropriate stream analysis diagrams. The streams analyzed were:
• Product Gas
- particulates
- impinger train
• Test Burner
- particulates
- resin catch
- condensate
- impinger composite
• Gasifier Ash
- gasifier ash
- gasifier ash sluice water
• Cyclone Dust
- cyclone dust
- cyclone dust quench water
The feed lignite, the service water, and the ash and dust leachate analysis
results are also givn in the data sections. Analytical results for the
quality assurance blanks are presented also.
D-10
-------
SAMPLE
NUMBER
SAMPLE TYPE
SSMS
AAS
RADIO- PROX/ ANION/
ICP ACTIVITY ULT CATION
2394
2395
2285
2296
2286
2285
2298
2299
2396
2398
2283
2284
PRODUCT GAS
Particulates
- Particulate extract
- Acid impinger composite
- Acid impinger blank
- Base impinger composite
- Base impinger blank
TEST BURNER
- SASS cyclone particulates <3 ym
- SASS probe rinse
- SASS condensate
- Extracted XAD resin
- XAD resin extract
- SASS AgaSzOs impinger composite
- XAD resin blank
- SASS Impinger blank
- CH2C12 blank
- Ether blank
2274
2280
2279
2281
GASIFIER ASH
- Gasifier ash composite
- Gasifier ash sluice water
CYCLONE DUST
- Cyclone dust
- Cyclone dust quench water
Figure D2. Inorganic Analysis Matrix
-------
Figure D2. Continued
SAMPLE
NUMBER
SAMPLE TYPE
ro
2272
2266
2267
2268
2269
2270
2271
2282
2352
2353
2354
LIGNITE
- Lignite composite
- Lignite
- Lignite
- Lignite
- Lignite
- Lignite
- Lignite
SERVICE WATER
- Service water
LEACHATES
- Gasifier ash leachate
- Cyclone dust leachate
- Leachate blank
RADIO- PROX/ ANION/
SSMS AAS ICP ACTIVITY ULT CATION
-------
SAMPLE
NUMBER
2394
2395
2285
2296
o 2286
co
2297
SAMPLE TYPE
Particulates
Particulate Extract
Acid Impinger Composite
Acid Impinger Blank
Base Impinger Composite
Base Impinger Blank
Prox/ Anion/
SSMS AAS ICP Radioactivity Ult Cation
.
•
•
•
•
* *
Figure D3. Analysis Results Matrix: Product Gas
-------
TABLE D7. SSMS ANALYSIS RESULTS: PRODUCT GAS PARTICULATES
Sample f2394
Concentration in ppm weight
QJftgNT
Uranium
Thorium
Bismuth
Lead
Thallium
Njrcury
told
Ptatlnum
IHdlum
OmmiuB
Rhenium
Tungsten
Tantalum
Hafnium
Luted urn
Ytterbium
Thulium
Erbium
HolBium
Dysprosium
1 Terbium
2 Gadolinium
0*8 Europium
39 Samarium
1 Neodjnlum
NR Praseodymium
Cerium
Lanthanum
Barium
Cesium
1000
INT - Interference
weight *Heterogeneous
^particulate
~c6S
-**f5
11
550
6
MC
MC
MC
MC
MC
MC
1C
1C
MC
«370
m
NR
NR
200
0.8
37
NR
Ppm
7.800 m:
D-14
-------
TABLE D8. SSMS ANALYSIS RESULTS: PRODUCT GAS PARTICULATE EXTRACT
Sample #2395
Concentration in yg/ml
ELEMENT
Uranium
Thorium
Bismuth
Lead
Thallium
Mercury
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbi um
Thulium
Erbium
Holmium
Dysprosium
CONC. ELEMENT CONC.
Terbium
Gadolinium
Europium
0.02 Samarium
Neodymi um
NR Praseodymium
Cerium
Lanthanum
Barium 0.2
Cesium
Iodine
Tellurium
Antimony 0.003
Tin <0.002
Indium STD
Cadmium <0.002
Silver' 0.04
Palladium
Rhodi um
STD - Internal Standard
NR - Not Reported
All elements not detected <0.001 ug/ml
iia/m*
/""element 3009 "l..*-......^ /^element
Vi x extractant i - 1 « —
^'extractant / \miCHiCl»
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Z1nc
Copper
Nickel
Cobal t
Iron
Manganese
Chromium
CONC. ELEMENT
Vanadium
0.003 Titanium
Scandium
0.01 Calcium
0.003 Potassium
0.008 Chlorine
<0.001 Sulfur
Phosphorus
0.003 Silicon
0.08 Aluminum
0.002 Magnesium
Sodium
0.1 Fluorine
0.06 Oxygen
0.02 Nitrogen
0.003 Carbon
<0.002 Boron
0.002 Beryllium
0.009 Lithium
Hydrogen
CONC.
0.002
0.04
<0.001
0.6
0.2
0.008
0.7
0.1
9
0.05
0.2
0.2
*0.3
NR
NR
NR
0.01
0.003
NR
MC - Major Component
INT - Interference
_ 300 ml,,, ,,
blank
* blank \
7.800
D-15
-------
TABLE D9. SSMS ANALYSIS RESULTS: PRODUCT GAS ACID IMPINGER COMPOSITE
Sample #2285
Concentration in yg/ml
ELEMENT
Uranium
Thorium
B1 smuth
Lead
Thallium
Mercury
Gold
Platinum
IMdium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thulium
Erbium
Holmlum
Dysprosium
CONC. ELEMENT CONC.
0.01 Terbium
Gadolinium
Europium
0.02 Samarium
Neodymlum
NR Praseodymi urn
Cerium 0.002
Lanthanum 0.003
Barium 0.03
Cesium
Iodine
Tellurium
Antimony
Tin 0.002
Indium STD
Cadmium
Silver 0.002
Palladium
Rhodium
ELEMENT
Ruthenium
Molybdenum
Ni obi urn
Zirconium
Yttri urn
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Z1nc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
CONC. ELEMENT
Vanadium
Titanium
Scandium
0.003 Calcium
Potassium
0.006 Chlorine
Sulfur
0.002 Phosphorus
0.01 Silicon
0.05 Aluminum
Magnesium
< 0.001 Sodium
0.07 Fluorine
0.03 Oxygen
0.03 Nitrogen
0.007 Carbon
0.6 Boron
0.01 Beryllium
0.03 Lithium
Hydrogen
CONC.
Q.Q04
0.06
1 0.001
2
0.3
0.06
2
0.2
0.9
0:02
0.1
0.1
a 0.05
NR
NR
NR
0.002
< o.ooi
NR
STD - Internal Standard
NR - Not Reported
All elements not detected <0.001 yg/ml
MC - Major Component MC >10 yg/ml
INT - Interference
,
\Blic1d soln
add blank
->
Ml*
D-16
-------
TABLE D10. SSMS ANALYSIS RESULTS: PRODUCT GAS ACID IMPINGER BLANK
Sample #2296
Concentration in yg/ml
ELEMENT
CONC.
ELEMENT
CONC.
ELEMENT
CONC. ELEMENT
CONC.
Uranium
Thorium
Bismuth
Lead
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thulium
Erbium
Hoimi urn
Dysprosium
Terbium
Gadolinium
Europium
Samarium
Neodymium
Praseodymium
Cerium
Lanthanum
Barium 0.01
Cesium
Iodine
Tellurium
Antimony
Tin
Indium STD
Cadmi urn
Silver 0.02
Palladium
Rhodi urn
Ruthenium
Molybdenum
Ni obi urn
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
STD - Internal Standard
NR - Not Reported
All elements not detected <0.002 yg/ml
MC - Major Component MC >10 yg/ml
INT - Interference
Vanadium
Titanium
Scandi urn
0.005 Calcium
Potassium
0.003 Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
0.05 Fluorine
0.009 Oxygen
0-08 Nitrogen
<0.001 carbon
O-4 Boron
0.005 Beryllium
0-009 Litnium
Hydrogen
0.004
0.02
<0.001
2
0.3
0.05
0.06
0.03
0.3
0.04
0.09
0.06
=0.06
NR
NR
NR
0.002
<0.001
NR
D-17
-------
TABLE Dll. SSMS ANALYSIS RESULTS: PRODUCT GAS BASE IMPINGER COMPOSITE
Sample #2286
Concentration in ug/ml
ELEMENT
Uranium
Thorium
Bismuth
Lead
Thallium
Mercury
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thulium
Erbium
Hoi ml urn
CONC. ELEMENT CONC.
Terbium
Gadolinium
Europium
0.08 Samarium
Neodymium
NR Praseodymium
Cerium
Lanthanum
Barium 0.04
Cesium
Iodine
Tel 1 uri urn
0.8 Antimony
Tin
Indium STD
Cadmium
Silver 0.2
Palladium
Rhodi urn
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttri urn
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
Dysprosium
STD - Internal Standard
NR - Not Reported
All elements not detected <0.009 yg/ml
MC - Major Component MC >10 yg/ml
INT - Interference
/"'elcmt 617 •
CONC. ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
0.009 Chlorine
0.008 Sulfur
Phosphorus
Silicon
0.02 Aluminum
Magnesium
0-1 Sodium
0.1 Fluorine
0.06 Oxygen
0-07 Nitrogen
0-002 carbon
1 Boron
°-02 Beryllium
°-03 Lithium
Hydrogen
CONC.
0.03
0.03
<0.01
4
0.3
1
MC
0.08
3
0.02
<_0.09
MC
= 2
NR
NR
NR
0.09
0.03
NR
u9/»'
'
bMt blink
2.394
D-18
-------
TABLE D12. SSMS ANALYSIS RESULTS: PRODUCT GAS BASE IMPINGER BLANK
Sample #2297
Concentration in yg/ml
ELEMENT CONC.
Uranium
Thorium
Bismuth
Lead
Thallium
Mercury NR
Gold
Platinum
iridium
Osmium
Rhenium
Tungsten
Tantalum 7
Hafnium
Lutecium
Ytterbi urn
Thulium
Erbium
Hoi mi urn
Dysprosium
ELEMENT CONC.
Terbium
Gadolinium
Europium
Samarium
Neodymi um
Praseodymium
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium STD
Cadmi um
Silver 0.1
Palladium
Rhodium
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttri um
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
CONC. ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
<0.06 Silicon
0.04 Aluminum
Magnesium
0.06 Sodium
0.07 Fluorine
0.08 Oxygen
0-04 Nitrogen
0.004 Carbon
0.3 Boron
0.006 Beryllium
0.02 Lithium
Hydrogen
CONC.
0.08
0.03
<0.03
5.
3
3
MC
0.04
MC
0.2
1
MC
MC
NR
NR
NR
0.05
0.008
NR
STD - Internal Standard
NR - Not Reported
All elements not detected <0.02 yg/ml
MC - Major Component MC >10 yg/ml
INT - Interference
D-19
-------
TABLE D13. VOLATILE METALS BY AAS: PRODUCT GAS
SAMPLE
NUMBER
2394
2395
2285
2296
2286
2297
SAMPLE TYPE
PartJtealates
Partieniate Extract
Acid Inptnger Composite
Acid Imp Ing er Blank
Base Xmpiager Cooposlte
Base Implnger Blank
As
77
.31
.043
<.005
.005
<.005
Hg
2.6
17
.007
<.0002
.0013
<.0002
Sb
<.4
<1
<.06
<.06
<.06
<.06
Se
15
.40
.011
.018
.015
<.01
As PPBU solids ug/g; liquids yg/ml.
-------
TABLE D14. ICP RESULTS: PRODUCT GAS PARTICULATES
Concentration in ppm weight (yg/g)
Ag
Ca
Fe
Ni
V
Al
Cd
Mg
Pb
Zn
As
Co
Mn
Sn
B
Cr
Mo
Sr
Ba
Cu
Na
Ti
Analysis #1
<6.20
45100
10100
<25.
<12.
8400
81.
12200
<87.
130
<99.
<190
33.
<50.
170.
30.
<50.
1200
2300
82.
<6200
290
Analysis #2
24.
44600
10500
41.22
15.
8300
87.
12100
<87.
140
<99.
<190
37.
<20.
170.
50.
<50.
1200
23000
70.
6500
280
Sample #2394
D-21
-------
SAMPLE Prox/ Anion/
NUMBER SAMPLE TYPE SSMS AAS ICP Radioactivity Ult Cation
2298 SASS Cyclone Particulates •
< 3 urn
2299 SASS Probe Rinse • •
SASS Condensete •
2396 Extracted XAD-2 Resin • •
Extracted XAD-2 Resin, •
T duplicate
K> r
M XAD-2 Resin Blank •
2398 XAD-2 Resin Extract • •
2283 SASS AgJTtT Impinger • •
228
2284 SASS Ag S 0 Impinger Blank • •
228
Methylene Chloride Blank •
Et>er Blank •
Figure D3. Analysis Results Matrix: Test Burner
-------
TABLE D15. SSMS ANALYSIS RESULTS: TEST BURNER SASS CYCLONE PARTICULATES
<3 urn
Sample #2298
F1 PMENT CONC.
Uranium
Thorium
Bi smuth
Lead 260
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmi um
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thulium
Erbium
Holmium
Dysprosium
ELEMENT CONC.
Terbium
Gadolinium
Europium
Samarium
Neodymi um 2
Praseodymi um 1
Cerium 27
Lanthanum 32
Barium MC
Cesium 0.5
Iodine
Tellurium
Antimony 2
Tin 6
Indium STD
Cadmium 2
Silver 73
Palladium
Rhodium
Concentration in ppm weight
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttri um
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobal t
Iron
Manganese
Chromium
STD - Internal Standard
NR . Not Reported
All elements not detected <0.9 ppm
MC - Major Component MC >1000 ppm
TNT - Interference ,_,
CONC. tLtMtNT
Vanadium
<16 Titanium
3 Scandium
20 Calcium
1 Potassium
280 Chlorine
12 Sulfur
6 Phosphorus
<17 Silicon
33 Aluminum
16 Magnesium
23 Sodium
79 Fluorine
95 Oxygen
110 Nitrogen
11 Carbon
MC Boron
36 Beryllium
36 Lithium
Hydrogen
y9element 0.03
a x
yparticulate
CUNC.
12
210
<0.8
MC
MC
79
MC
540
MC
140
MC
MC
=82
NR
NR
NR
13
99
NR
9particulate
27.196 m3
D-23
-------
TABLE D16. SSMS ANALYSIS RESULTS: TEST BURNER SASS PROBE RINSE
Sample #2299
COMCT
CLEM04T
Concentration in
B£MENT
yg/ml
CONC.
CONC.
ELEMBMT
CONC.
Uranlun <0.008
Thorium
Bismuth
Lead <0.005
Thallium
"jrcury NR
Gold
Platinum
Irldlum
Osmium
Rhenium
Tungsten
Tantalum 0.004
Hafnium
Lutecium
Ytterbium
Thulium
Erbium
Holmlum
Dysprosium
Terbium
Gadolinium
Europium
Samarium
Neodynrium
Praseodymium
Cerium
Lanthanum
Barium 0.003
Cesium
Iodine
Tellurium
Antimony
Tin
Indium STD
Cadmium
Silver 0.004
Palladium
Rhodium
Ruthenium
Molybdenum
N1obi urn
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
<0.001
0.002
<0.001
0.008
0.004
0.002
<0.001
0.001
0.02
0.007
0.01
<0.001
0.05
0.001
0.03
Vanadium
Titanium
Scandi urn
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
STD - Internal Standard
NR - Not Reported
All elements not detected <0.001 pg/ml
MC - Major Component
INT - Interference
"Heterogeneous
<0.001
0.02
<0.001
0.6
0.3
0.04
0.2
0.009
0.4
*0.04
0.05
1
=0.02
NR
NR
NR
<0.001
<0.001
NR
("•iiii
.f1?"* - «
_ . >>^trt*t
"*^
D-24
-------
TABLE D17. SSMS ANALYSIS RESULTS: TEST BURNER SASS TRAIN CONDENSATE
Sample #
ELEMENT
_— — • —
Uranium
Thorium
Bi smuth
Lead
Thallium
Mercury
Gold
Platinum
Ir1d1um
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thulium
Erbium
Hoi mi urn
Dysprosium
CONC. ELEMENT CONC.
Terbium
Gadolinium
Europi urn
Samarium
Neodyml urn
NR Praseodyml urn
Cerium 0.005
0.02 Lanthanum 0.008
Barium 0.02
Cesium
Iodine
Tellurium
Antimony
Tin
Indium STD
Cadmium
Silver
Palladium
Rhodi urn
STD - Internal Standard
NR - Not Reported
All elements not detected <0.003 yg/ml
Concentration in yg/ml
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobal t
Iron
Manganese
Chromium
nri/m' =
CONC. ELEMENT
Vanadium
0.03 Titanium
Scandium
0.006 Calcium
Potassium
0.003 Chlorine
Sulfur
Phosphorus
Silicon
£0.002 Aluminum
Magnesium
<0.003 Sodium
0.01 Fluorine
0.007 Oxygen
0.02 Nitrogen
<0.001 Carbon
0.05 Boron
0.002 Beryllium
0.004 Lithium
Hydrogen
ygelement „ 1507
ml
condensate
CONC.
0.001
0.03
<0.001
1
Q.I
0.1
3
0.03
0.3
0.04
<0.04
0.1
=0.3
NR
NR
NR
0.001
<0.001
NR
m condensate
MC - Major Component MC >10 ug/ml
INT - Interference
27.196 m3
D-25
-------
TABLE D18. SSMS ANALYSIS RESULTS: TEST BURNER EXTRACTED XAD-2 RESIN
le *2396
Concentration in ppu wight
Uranium *1
Thorium
Bismuth 0.03
Lead «U4
Thallium
Mercury .NR
told
Platinum
IridiuB
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thulium
Erbium
Holarium
Dysprosium
Terbium
Gadolinium
Europium
Samarium
Neodynium
Praseodymium
Cerium 0.04
Lanthanum 0.09
Barium 1
Cesium
Iodine
Tellurium
Antimony 0.02
Tin
Indium STD
Cadmium 0.03
Silver 0.2
Palladium
Rhodium
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
fiermanium
Gallium
line
Copper.
Nickel
Cobalt
Iron
Manganese
Chromium
0.4
0.02
0.5
0.01
0.3
0.009
0.03
<>.01
0.02
0.01
2
0.4
1
2
2
0.2
0.3
Vanadium
Titanium
Scandi urn
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Nitrogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
0.02
1
1000 ppm
INT - Interference
^Heterogeneous
NOTE: Sample was low
temperature plasma
ashed prior to analysis
D-26
-------
TABLE D19. SSMS ANALYSIS RESULTS: TEST BURNER EXTRACTED XAD-2 RESIN DUPLICATE
Concentration in ppm weight
ELEMENT CONC.
Uranium 0.8
Thorium
Bismuth
Lead 0.4
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbi um
Thulium
Erbium
Holmium
Dysprosium
ELEMENT
• Terbium
Gadolinium
Europium
Samarium
Neodymi um
Praseodymi um
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmi um
Silver
Palladium
Rhodi um
STD - Internal Standard
NR - Not Reported
All elements not detected <0.02
/vgvlMent 205 a— «\ /V9el«ent
\9XAD-2
v9/«' • •
/ \9XAD-2 bla
27.196 »'
CONC. ELEMENT
Ruthenium
CONC. ELEMENT
Vanadium
Molybdenum 2 Titanium
Niobium
Zirconium
Yttrium
0.03 Strontium
0.06 Rubidium
0.09 Bromine
0.5 Selenium
Arsenic
0.05 Germanium
Gallium
Zinc
0.08 Copper
STD Nickel
Cobalt
0.07 Iron
Manganese
Chromium
MC -
INT -
ppm weight NOTE;
x 205 9XAO-2 blank \
ink /
0.09 Scandium
1 Calcium
0.03 Potassium
0.3 Chlorine
0.02 Sulfur
0.2 Phosphorus
0.07 Silicon
0.06 Aluminum
Magnesium
0.03 Sodium
1 Fluorine
2 Oxygen
0.7 Nitrogen
2 Carbon
21 Boron
0.1 Beryllium
3 Lithium
Hydrogen
CONC.
0.07
0.6
<0.03
28
3
2
17
8
8
0.5
4
1
=8
NR
NR
NR
0.04
0.02
NR
Major Component
Interference
Sample was low temperature
plasma ashed prior to analysis
D-27
-------
TART.F. D20. SSMS ANALYSIS RESULTS: XAD-2 RESIN BLANK
Sample #
Concentration in ppm weight
ELEMfiNT OONC
Uranium 3
Thorium 2
Bismuth
Lead 1
Thallium
fercury NR
field
Platinum
Iridlum
(Mum
•mtnlum
Tungsten
Tantalum
Hefnlui
Lutecium
Ytterbium
Thulium
Erbium
Holmlum
Dysprosium
EUEM64T CONC.
Terbi urn
Gadolinium
Europium
Samarium
Neodymlu*
Praseodymium <0.1
Cerium 0.6
Lanthanum 0.9
Barium 2
Cesium <0.1
Iodine <0.1
Tellurium
Antimony
Tin <0.1
Indium STD
Outturn
Silver
Palladium
Rhodium
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bronlne
Selenium
Arsenic
Germanium
Gallium
Z1nc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
CONC.
0.6
270
0.9
>140
250
17
>22
HC
>H
^
NR
NR
NR
0.2
-------
TABLE D21. SSMS ANALYSIS RESULTS: TEST BURNER XAD-2 RESIN EXTRACT
Sample #2398
"ELEMENT CONC. "
Concentration in ug/ml
ELEMENT
CONC.
ELEMENT
CONC. ELEMENT
CONC.
Uranium
Thorium
Bismuth
Lead
Thallium
Mercury NR
Gold
platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbi urn
Thuli urn
Erbium
Holmium
Dysprosium
Terbium
Gadolinium
Europium
Samarium
Neodymi urn
Praseodymium
Cerium
Lanthanum
Barium 0.02
Cesium
Iodine
Tellurium
Antimony
Tin
Indium STD
Cadmium
Silver 0.004
Palladium
Rhodium
STD - Internal Standard
NR - Not Reported
All elements not detected <0.004 yg/ml
^extract
Xi6«-nextract
Ruthenium Vanadium <0.001
Molybdenum 0.1 Titanium 0.02
Niobium Scandium <0.001
Zirconium 0.007 Calcium 6
Yttrium 0.005 Potassium *6
Strontium 0.006 Chlorine 0.3
Rubidium 0.002 Sulfur 0.1
Bromi ne p'hosphorus 2
Selenium Silicon 0.2
Arsenic 0.008 Aluminum *0.2
Germanium Magnesium 0.09
Gallium Sodium 0.3
Zinc 0.01 Fluorine =0.7
Copper 0.003 Oxygen NR
Nickel 0.02 .Nitrogen NR
Cobalt 0.002 Carbon NR
Iron 0.07 Boron 0.009
Manganese 0.006 Beryllium
Chromium 0.02 Lithium <0.001
Hydrogen NR
1C - Major Component MC >10 yg/ml
INT - Interference
*Heterogeneous
V \( Assist— x 790 .1 CHtC1j Mank^ vge1a>ent ^ „,
/ L\ CHiClt blank
•1
Et20 blank
EtiO blank
27.196
D-29
-------
TABLE D22. SSMS ANALYSIS RESULTS: METhYLEHE CHLORIDE BLANK
Sample £
ELEMfNT CONC.
Uranium
Thorium
Bismuth
Lead
Thai Hut
Msrcury NR
told
natlnum
IHdlum
Onriu*
•lenlui
Tungsten
Tantalum
Hafnium
UtftClUB
Ytterbium
Thulium
Erbium
Holmlum
Dysprosium
ELEMENT CONC.
Terbium
Gadolinium
Europium
Samarium
Meodyplum *0.01
rras«odyw«um*0.006
Cerium *0,007
Lanthanum *0.01
laHum *0.01
Ctslum
Iodine
Tellurium
Antimony
Tin
Indium STD
Cadmium
Silver 0.004
Palladium
Rhodium
Concentration In yg/ml
ELEMENT ~ ~
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
CONC.
0.02
0.01
0.002
S.004
0.02
0.004
0.02
<0.001
0.03
0.003
0.007
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Nitrogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC. "
3>.004
0.01
<0.001
0.2
0.04
0.1
0.2
0.009
0.9
0.005
0.03
0.01
•0.09
NR
NR
NR
0.001
o.ooi
NR
STD - Internal Standard
NR - Not Reported
All elements not detected <0.02 ppm
MC - Major Component
INT - Interference
NOTE: Sample was plasma ashed
prior to analysis.
-------
TABLE D23. SSMS ANALYSIS RESULTS: ETHER BLANK
Sample #
Concentration in yg/ml
' ELEMENT CONC.
Uranium
Thori urn
Bismuth
Lead
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmi urn
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thul i urn
Erbium
Hoi mi urn
Dysprosium
ELEMENT CONC.
Terbium
Gadolinium
Europium
Samarium
Neodymi urn
Praseodymium
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium STD
Cadmium
Silver
Palladium
Rhodium
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttri urn
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
CONC.
0.03
0.01
0.003
10.003
0.02
0.002
0.02.
<0.001
0.02
0.002
0.002
ELEMENT
Vanadium
Ti tani urn
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC.
<0.001
0.02
O.001
0.6
0.05
0.09
0.01
0.02
0.3
0.005
0.05
0.02
=0.1
NR
NR
NR
0.001
<0.001
NR
STD - Internal Standard
NR - Not Reported
All elements not detected <0.002 yg/ml
MC - Major Component MC >10 ug/ml
INT - Interference
*Heterogeneous
D-31
-------
TABLE D24. SSMS ANALYSIS RESULTS: SASS Ag2S208 IMPINGER COMPOSITE
Sample #2283
Concentration in yg/ml
ELEMtNf
Uranium
Thorium
Bismuth
Lead
Thallium
Mercury
Gold
Platinum
Iridium
Osarium
Mtenlum
Tungsten
Tantalum
Hafniun
Lutecium
Ytterbium
Thulium
Erbium
Holmlum
63*. ELEMENT CONC.
Terbium
Gadolinium
Europium
0.07 Samarium
NeodymiuHi
NR Praseodymium
Cerium 0.001
0.003 Lanthanum 0.002
Barium 0.02
Cesium 0.01
Iodine 0.004
Tellurium
Antimony
Tin 0.008
Indium STD
Cadmium 0.003
Silver MC
Palladium
Rhodium
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
CONC.
0.01
0.01
0.01
<0.001
0.002
0.009
0.004
0.007
0.1
0.05
0.3
0.7
0.5
0.1
0.1
Dysprosium
STD -
NR -
All el
MC -
INT -
Internal Standard
Not Reported
orients not detected <0.001 yg/ml
Major Component MC >10 yg/ml
Interference .v
«*•
NOTE:
"jimur i40*"1*
'tapwlfc
Sample
ashed
at 300
*«*)-|
ELEMENT
Vanadium
Titanium
Scandi urn
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC.
0.02
0.1
10.001
2
1
0.05
>6
0.3
1
0.04
0.1
0.8
»0.1
NR
NR
NR
0.02
<0.001
NR
was thermally
prior to analysis
°C.
(35ft •"""'-«-)
0-32
-------
TABLE D25. SSMS ANALYSIS RESULTS: SASS Ag2S208 IMPINGER BLANK
Sample #2284
Concentration in ug/ml
ELEMENT
CONC.
ELEMENT
CONC.
ELEMENT
CONC. ELEMENT
CONC.
Uranium
Thorium
Bismuth
Lead 0.02
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmium
Rheni urn
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thulium
Erbium
Hoi mi urn
Dysprosium
Terbium
Gadolinium
Europium
Samarium
Neodymium
Praseodymi urn
Cerium 0.003
Lanthanum 0.005
Barium 0.01
Cesium 0.007
Iodine
Tellurium
Antimony
Tin
Indium STD
Cadmium £0.004
Silver MC
Palladium
Rhodi urn
STD - Internal Standard
NR - Not Reported
All elements not detected <0.002 jag/ml
MC - Major Component MC >10
INT - Interference
Ruthenium
Molybdenum
Niobium
Zirconium
Yttri urn
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
0.001
<0.001
0.003
0.07
0.1
0.09
0.001
0.2
0.003
0.05
Vanadium
Titanium
Scandi urn
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryl 1i urn
Lithium
Hydrogen
<0.001
0.01
<0.003
0.9
6
0.03
MC
0.2
0.2
0.2
0.05
6
=0.6
NR
NR
NR
0.002
0.003
NR
D-33
-------
TABLE D26. VOLATILE METALS BY AAS: TEST BURNER
SAMPLE
HDMBER
2299
2396
2398
2283
2284
SAMPLE TYPE
SASS Probe Rinse
Extracted XAD-2 Resin
XAD-2 Resin Extract
*
SASS Ag2S20g Impinger
Composite
SSAS AgzSzOs Impinger
Blank
As
0.005
2.7
1.0
0.033
0,014
Hg
0.0002
0.18
0.27
0.0007
0.0048
Sb
<0.06
<0.3
<0.06
<0.06
<0.06
Se
0.015
<1.1
<2.0
0.032
<0.01
As ppau solids ug/g; liquids yg/ml.
D-34
-------
SAMPLE Prox/ Anion/
NUMBER SAMPLE TYPE SSMS AAS ICP Radioactivity Ult Cation
2274 Gasifier Ash Composite
s
01 2280 Gasifier Ash Sluice Water
Figure D4. Analysis Results Matrix: Gasifier Ash
-------
TABLE D27. SSMS ANALYSIS RESULTS: GASIFIER ASH COMPOSITE
Sample #2274
Concentration in ppm weight
ELEMENT
Uranium
Thorl urn
B1 smuth
Lead
Thallium
Mercury
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thulium
Erbium
Hoi mi urn
Dysprosium
CONC.
16
23
5
NR
1
33.8
1
0.3
3
0.4
3
4
7
ELEMENT
Terbium
Gadolinium
Europium
Samarium
Neodymium
Praseodymi urn
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmi urn
Silver
Palladium
Rhodi urn
CONC.
.1
4
3
13
30
16
110
110
MC
8
0.2
2
0.5
STD
0.8
0.6
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromi urn
CONC.
15
31
180
59
MC
47
2
4
9
1
9
20
81
75
23
MC
170
100
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC.
410
MC
20
MC
MC
34
MC
MC
MC
MC
MC
MC
=190
NR
NR
NR
320
9
48
NR
STD - Internal Standard
NR - Not Reported
MC - Major Component MC >1000 ppm
INT - Interference
All elements not detected <0.1 ppm
D-36
-------
TABLE D28. SSMS ANALYSIS RESULTS: GASIFIER ASH SLUICE WATER
Sample #2280
Concentration in yg/ml
ELEMENT
Urani urn
Thori urn
Bismuth
Lead
Thallium
Mercury
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbi urn
Thulium
Erbium
Hoi mi urn
Dysprosium
CONC. ELEMENT CONC.
Terbium
Gadolinium
Europium
0.008 Samarium
Neodymi urn
MR Praseodymium 0.001
Cerium 0.002
Lanthanum <0.001
Barium o.l
Cesium <0.001
Iodine
0.02 Tellurium
Antimony 0.002
Tin
Indium STD
Cadmium < 0.002
Silver 0.001
Palladium
Rhodium
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromi urn
CONC. ELEMENT
Vanadium
0.1 Titanium
0.002 Scandium
0.002 Calcium
<0.001 Potassium
4 Chlorine
0.04 Sulfur
0.02 Phosphorus
0.005 Silicon
0.009 Aluminum
<0.001 Magnesium
0.008 Sodium
0.05 Fluorine
0.01 Oxygen
0.02 Nitrogen
10.002 Carbon
0.5 Boron
0.005 Beryllium
0.009 Lithium
Hydrogen
CONC.
0.02
0.05
10.001
MC
MC
0.5
>6
0.4
0.3
>1
5
>3
•^ 1
NR
NR
NR
0.2
<0.001
0.4
NR
STD - Internal Standard
NR - Not Reported
All elements not detected <0.001 yg/ml
MC - Major Component MC >10 yg/ml
INT - Interference
D-37
-------
TABLE D29. VOLATILE METALS BY AAS: GASIFIER ASH
SAMPLE
NUMBER
2274
2280
SAMPLE TYPE
Gaslfier Ash
Gasif ier Ash Sluice
As Hg
30 1.7
0.033 .0014
Sb
<0.4
<0.06
Se
15
.020
Water
As ppm: solids Vg/g; liquids ug/ml.
D-38
-------
TABLE D30. ICP RESULTS: GASIFIER ASH
Concentration in ppm weight (yg/g)
Ag
Ca
Fe
Ni
V
Al
Cd
Mg
Pb
Zn
As
Co
Mn
Sn
B
Cr
Mo
Sr
Ba
Cu
Na
Ti
Analysis #1
<6.2
48800
30400
71.
38.
19100
<6.2
12300
<87.
25.
<100
<190
64.
<50.
220
22.
<50.
1300
1900
33.
<6300
1200
Analysis #2
<6.2
48100
30100
62.
37.
18900
<6.2
12100
<87.
4.6
<100
<190
64.
<50.
200
20.
<50.
1300
1900
47.
<6200
1200
Sample #2274
D-39
-------
TABLE D31. ICP RESULTS: GASIFIER ASH SLUICE WATER
Concentration in ppm (yg/ml)
Ag
Ca
Fe
Ni
V
Al
Cd
Mg
Pb
Zn
As
Co
Mn
Sn
B
Cr
Mo
Sr
Ba
Cu
Na
Ti
<0.005
220.
1.2
<0.020
0.077
11.
<0.005
11.
<0.07
0.044
<0.08
<0.15
0.002
3.0
4.6
0.007
0.31
4.
0.13
0.017
1700
0.044
Sample #2280
D-40
-------
TABLE D32. ALPHA & BETA EMISSION ANALYSIS RESULTS: GASIFIER ASH
Determination , _p .8. .
± Precision*
Gross Alpha 46 ± 11
Gross Beta 52 ± 15
Sample #2278
Variability of the radioactive disintegration process (counting
error) at the 95 percent confidence level, 1.96a.
D-41
-------
TABLE D33. SPECIFIC ISOTOPE ANALYSIS RESULTS: GASIFIER ASH
NDCLIDE
Po-210
Ra-226
Pb-210
0-234
U-235
U-238
K-40
Pb-214
Bi-214
Th-232
Th-227
Th-228
Th-230
Th-232
ACTIVITY
pCi/g
0.496
5.500
0.539
4.8600
0.284
4.9600
8.8600
4.330
4.3500
2.1100
0.43100
2.6400
5.500
2.6100
PRECISION
2a
0.108
0.110
0.734
0.5832
0.05936
0.5952
1.1518
0.866
0.9135
0.3587
0.08189
0.1584
0.220
0.1566
COUNTING
SYSTEM
AS02
LC
ABET
AS
AS
AS
GEL2
GEL2
GEL2
GEL2
AS
AS
AS
AS
SAMPLE
SIZE
1.000 g
0.500 g
1.000 g
1.000 g
1.000 g
1.000 g
410.0 g
410.0 g
410.0 g
410.0 g
1.000 g
1.000 g
1.000 g
1.000 g
Sample ashed prior to analysis except for Po-210, Pb-210, K-40,
Pb-214, Bi-214, and Th-232.
Counting duration of 1000 minutes.
l>-42
-------
TABLE D34. PROXIMATE, ULTIMATE, AND MINERAL ANALYSIS RESULTS: GASIFIER ASH
to
PROXIMATE ANALYSIS
% Moisture
% Ash
% Volatile
% Fixed Carbon
Btu
% Sulfur
% Alk. as Na20
As received Dry Basis
1 oi
73.66 74.41
6.49 6.56
18.84 19.03
100.00 100.00
3709 3747
1.08 1.09
N/A N/A
MINERAL ANALYSIS
Silica, Si 02
Alumina, Al^
Titania, Ti02
Ferric oxide, Fe203
Lime, CaO
Magnesia, MgO
Potassium oxide, l<20
Sodium oxide, Na20
Sulfur Tri oxide, $03
Phos. pentoxide, P?05
Strontium oxide, 5rO
Barium oxide, BaO
Manganese oxide, 1^1304
Sum
ULTIMATE ANALYSIS
Moisture
Carbon
Hydrogen
Nitrogen
Chlorine
Sulfur
Ash
Oxygen (diff)
% Wt.
Ignited Basis
39.18
22.38
1.02
13.40
9.02
2.89
1.39
3.26
3.43
0.61
0.31
0.83
0.04
97.76
As received
1.01
24.39
0.41
0.17
0.02
1.08
73.66
0.60
100.00
Dry Basis
24.64
0.41
0.17
0.02
1.09
74.41
0.60
100.00
Sample #2274
-------
TABLE D35. ANION/CATION ANALYSIS RESULTS: GASIFIER ASH SLUICE WATER
Parameter
Concentration (ppm)
pH
IDS
TSS
Sulfate
Sulfite
Nitrate
Nitrite
Phosphate
Cyanide
Ammonia
COD
BOD
Phenol
Chloride
Fluoride
TOC
9.3
4300
2860
47
3
<.02
5.4
76
28 - 64t
.36
78
.87
16
Sanple #2280
* Possible interference
t Possible toxic effect
D-44
-------
SAMPLE Prox/ Anion/
NUMBER SAMPLE TYPE SSMS AAS ICP Radioactivity Ult Cation
2279 Cyclone Dust • • • • •
2281 Cyclone Dust Quench
Water
a
Ol
Figure D5. Analysis Results Matrix: Cyclone Dust
-------
Sample
TABLE D36. SSMS ANALYSIS RESULTS: CYCLONE DUST
#2279 Concentration in ppm weight
ak*NT
Uranium
Thorium
Bismuth
Lead
Thallium
Mrcury
told
Platinum
Irldlum
Osmium
Rhtnlum
Tungsten
Tantalum
HafnluK
Lutecium
Ytterbium
Thulium
Erbium
Holmium
Dysprosium
Cdwt
0.9
2
0.3
8
0.9
NR
<0.7
<0.1
0.6
<0.1
0.3
0.4
0.6
aEMBCT
Terbium
Gadolinium
Europium
Samarium
Neodymium
PraseodymluR
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmium
Silver
Palladium
Rhodium
COMC.
0.1
0.4
0.4
2
3
i 2
15
8
MC
0.7
0.4
0.2
3
2
STD
2
2
B£M£NT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Z1nc
Copper
Nickel
Cobalt
Iron
Manganese
Chromi urn
CONC.
2
5
29
13
MC
3
9
5
46
6
33
160
30
4
5
MC
20
11
&EMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC.
19
470
5
MC
MC
75
MC
MC
MC
MC
MC
MC
»280
NR
NR
NR
75
0.4
6
NR
STD - Internal Standard
NR - Not Reported
All elements not detected <0.1 ppm
MC - Major Component
INT - Interference
D-46
-------
TABLE D37. SSMS ANALYSIS RESULTS: CYCLONE DUST QUENCH WATER
Sample #2281
Concentration in yg/ml
ELEMENT CONG.
Uranium
Thorium
Bi smuth
Lead 0.02
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmi um
Rheni um
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thulium
Erbium
Holmium
Dysprosium
ELEMENT CONC.
Terbi um
Gadolinium
Europium
Samarium
Neodymi um
Praseodymium
Cerium 0-002
Lanthanum
Barium 0.002
Cesium 0.004
Iodine 0.006
Tellurium
Antimony
Tin
Indium STD
Cadmium
Silver 0.002
Palladium
Rhodi um
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttri um
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
CONC. ELEMENT
Vanadium
<0.004 Titanium
Scandi um
0.005 Calcium
0.002 Potassium
2 Chlorine
0.02 Sulfur
0.04 Phosphorus
0.006 Silicon
*0.05 Aluminum
0.007 Magnesium
*0.02 Sodium
0.06 Fluorine
0.02 Oxygen
0.08 Nitrogen
0.009 Carbon
2 Boron
0.005 Beryllium
0.01 Lithium
Hydrogen
CONC.
0.02
0.06
<0.001
MC
MC
0.3
>7
0.4
2
>1
1
>3
~?
NR
NR
NR
0.09
<0.001
0.04
NR
STD - Internal Standard
NR - Not Reported
All elements not detected <0.001 yg/ml
MC - Major Component MC >10 yg/ml
INT - Interference
*Heterogeneous
D-47
-------
TABLE D38. VOLATILE METALS BY AAS: CYCLONE DUST
SAMPLE
NUMBER SAMPLE TYPE As Hg Sb Se
2279 Cyclone Dust 63 <2.3 <.4 14
2281 Cyclone Dust Quench 0.12 .0004 <.06 <.025
Water
As ppm: solids Ug/g; liquids yg/ml.
D-48
-------
TABLE D39. ICP RESULTS: CYCLONE DUST
Concentration in ppm (yg/g)
Ag
Ca
Fe
Ni
V
Al
Cd
Mg
Pb
Zn
As
Co
Mn
Sn
B
Cr
Mo
Sr
Ba
Cu
Na
Ti
Analysis #1
<6.2
11300
7900
<25.
<12.
7200
<6.2
12300
<86.
15.
<100
<190
23.
<19.
118
<6.2
<49.
1180
2300
<6.2
6200
317
Analysis #2
<6.2
13600
7600
<25.
<13.
7000
<6.2
12100
<87.
34.
<100
<190
14.
<50.
110
<6.2
<50.
1170
2300
<6.2
6200
300
Sample #2279
D-49
-------
TABLE D40. ICP RESULTS: CYCLONE DUST QUENCH WATER
Concentration In yg/ml (ppm)
Ag
Ca
Fe
Ni
V
Al
Cd
Mg
Pb
Zn
As
Co
Mn
Sn
B
Cr
Mo
Sr
Ba
Cu
Na
Ti
<0.005
54.
4.9
<0.02
0.015
n.
<0.005
11.
0.099
0.035
<0.08
<0.15
<0.001
2.9
0.99
<0.005
<0.04
1.1
0.57
0.012
220
0.18
Sample #2281
-------
TABLE D41. ALPHA AND BETA EMISSION ANALYSIS RESULTS: CYCLONE DUST
Pd/g
Determination ± Preclsion*
Gross Alpha 11.1 ± 6.1
Gross Beta 0+15
Sample #2279
Variability of the radioactive disintegration process
(counting error) at the 95% confidence level, 1.96a.
D-51
-------
TABLE D42. SPECIFIC ISOTOPE ANALYSIS RESULTS: CYCLONE DUST
NUCLIDE
Po-210
Ra-226
Pb-210
U-234
U-235
U-238
Th-227
Th-228
Th-230
Th-232
ACTIVITY
pd/g
2.500
2.000
1.392
0.675
0.388
0.731
ND
0.528
0.639
0.417
PRECISION
2a
0.585
0.080
1.283
0.10125
0.20564
0,10965
ND
0.12672
0.14697
0.10842
COUNTING
SYSTEM
AS03
LC
ABET
AS
AS
AS
AS
AS
AS
AS
SAMPLE
SIZE
1.00 g
0.500 g
1.000 g
1.000 g
1.000 g
1.000 g
1.000 g
1.000 g
1.000 g
1.000 g
Sample ashed prior to analysis for U-234, U-235, and U-238.
Counting duration of 1000 minutes.
D-52
-------
TABLE D43. PROXIMATE, ULTIMATE, AND MINERAL ANALYSIS RESULTS: CYCLONE DUST
l_n
OJ
PROXIMATE ANALYSIS
% Moisture
% Ash
% Volatile
% Fixed Carbon
Btu
% Sulfur
% Alk. as Na20
As received Dry Basis
0 44
18.89 18.97
24.30 24.41
56.37 56.62
100.00 100.00
10670 10717
1.50 1.51
N/A H/A
MINERAL ANALYSIS
Silica, Si 02
Alumina, Al^
Titania, Ti02
Ferric oxide, Fe203
Lime, Cab
Magnesia, MgO
Potassium oxide, l<20
Sodium oxide, Na20
Sulfur Tri oxide, $03
Phos. pentoxide, P20i;
Strontium oxide, SrO
Barium oxide, BaO
Manganese oxide, ^304
Sum
ULTIMATE ANALYSIS
Moisture
Carbon
Hydrogen
Nitrogen
Chlorine
Sulfur
Ash
Oxygen (diff)
% Wt.
Ignited Basis
20.71
12.21
0.35
6.95
21.55
6.82
0.81
7.83
17.02
0.70
0.85
2.01
0.01
97.82
As received
0.44
66.88
2.31
0.93
0.03
1.50
18.89
9.02
100.00
Dry Basis
67.18
2.32
0.93
0.03
1.51
18.97
9.06
100.00
Sample #2279
-------
TABLE D4A. ANION/CATION ANALYSIS RESULTS: CYCLONE DUST QUENCH WATER
Parameter Concentration (ppm)
pB 10.0
IDS 390
TSS
Sulfate 55
Sulfite 12
Nitrate <-5*
Nitrite <-01
Phosphate <•!*
Cyanide • 36
- a .97
COD
BOD 62
Phenol 9-8
Chloride ^
Fluoride 2*°
TOC "5
Sample 12281
* Possible interference
t Possible toxic effects
D-54
-------
SAMPLE
NUMBER
SAMPLE TYPE
SSMS
AAS
Prox/ Anion/
ICP Radioactivity Ult Cation
o
i
Ln
Ui
2272
2266
2267
2268
2269
2270
2271
Lignite Composite
Lignite
Lignite
Lignite
Lignite
Lignite
Lignite
Figure D6. Analysis Results Matrix: Lignite Composite
-------
TABLE D45. SSMS ANALYSIS RESULTS: LIGNITE COMPOSITE
Sample #2272
Concentration in ppm weight
ELEMENT CONC.
Uranium <0.9
Thori urn fl
Bismuth
Lead 2
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thulium
Erbium
Hoi mi urn
Dysprosium
ELEMENT
Terbium
Gadolinium
Europium
Samarium
Neodymium
Praseodymi urn
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmi urn
Silver
Palladium
Rhodi urn
CONC.
0.1
0.4
0.2
1
1
0.7
8
6
630
0.9
0.2
0.2
0.5
STD
0.4
1
ELEMENT
Ruthenium
Molybdenum
Niobium
• Zirconium
Yttrium
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobal t
Iron
Manganese
Chromium
CONC.
1
2
17
4
280
9 '
1
0.7
12
0.7
*19
3
8
5
2
MC
13
10
ELEMENT
Vanadium
Titanium
Scandi urn
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC.
22
350
5
MC
MC
15
MC
910
MC
MC
MC
MC
= 210
NR
NR
NR
25
0.4
5
NR
STD - Internal Standard
NR - Not Reported
MC - Major Component MC >IOOO ppm
INT - Interference
All elements not detected <0.1 ppm
*Heterogeneous
D-56
-------
TABLE D46. VOLATILE METALS BY AAS: LIGNITE COMPOSITE
SAMPLE
NUMBER SAMPLE TYPE As Hg Sb Se
2272 Lignite 6.5 .39 <.06 1.0
As ppm: solids yg/g
D-57
-------
TABLE DA7. ALPHA AND BETA EMISSION ANALYSIS RESULTS: LIGNITE COMPOSITE
Pd/g
Determination ± Precision*
Gross Alpha 1.7 ± 3.6
Gross Beta 0 ± 13
Sample #2273
Variability of the radioactive disintegration process (counting
error) at the 95% confidence level, 1.96a.
-------
TABLE D48. SPECIFIC ISOTOPE ANALYSIS RESULTS: LIGNITE COMPOSITE
NUCLIDE
Po-210
Ra-226
Pb-210
U-234
U-235
U-238
Th-227
Th-228
Th-230
Th-232
ACTIVITY
pCi/g
0.627
0.280
0.984
0.211
0.014
0.205
0.041
0.134
0.186
0.126
PRECISION
2a
0.146
0.008
0.441
0.0295
0.0029
1.000
0.00779
0.01072
0.01488
0.01008
COUNTING
SYSTEM
AS07
LC
ABET
AS
AS
AS
AS
AS
AS
AS
SAMPLE
SIZE
1.000 g
0.500 g
1.000 g
1.000 g
1.000 g
1.000 g
1.000 g
1.000 g
1.000 g
1.000 g
Sample ashed prior to analysis except for Po-210 and Pb-210
determinations.
Counting duration of 1000 minutes.
D-59
-------
TABLE D49. PROXIMATE, ULTIMATE, AND MINERAL ANALYSIS RESULTS: LIGNITE COMPOSITE
o>
o
PROXIMATE ANALYSIS
% Moisture
% Ash
% Volatile
% Fixed Carbon
Btu
% Sulfur
% Alk. as Na20
As received Dry Basis
4 19
10.45 10.91
40.17 41.93
45.19 47.16
100.00 100.00
10036 10475
0.58 0.61
N/A N/A
MINERAL ANALYSIS
Silica, Si02
Alumina, AlpOo
Titania, T102
Ferric oxide, Fe203
Lime, CaO
Magnesia, MgO
Potassium oxide, 1^0
Sodium oxide, Na?0
Sulfur Tri oxide, 563
Phos. pentoxide, P?0§
Strontium oxide, 5rO
Barium oxide, BaO
Manganese oxide, Mn-^
Sum
ULTIMATE ANALYSIS
Moisture
Carbon
Hydrogen
Ni trogen
Chlorine
Sulfur
Ash
Oxygen (diff)
% Wt.
Ignited Basis
30.21
14.93
0.46
6.36
16.39
6.46
1.49
9.00
10.93
0.63
0.72
1.32
0.01
98.91
As received
4.19
60.06
4.41
0.87
0.03
0.58
10.45
19.41
100.00
Dry Basis
62.69
4.60
0.91
0.03
0.61
10.91
20.25
100.00
Sample #2272
-------
TABLE D50. PROXIMATE, ULTIMATE, AND MINERAL ANALYSIS RESULTS: LIGNITE FS-9
PROXIMATE ANALYSIS
% Moisture
% Ash
% Volatile
% Fixed Carbon
Btu
% Sulfur
As Received
6.82
6.29
41.18
45.71
100.00
10090
0.39
Dry Basis
6.75
44.19
49.06
100.00
10829
0.42
Weight
ULTIMATE ANALYSIS
Moisture
Carbon
Hydrogen
Nitrogen
Chlorine
Sulfur
Ash
Oxygen (diff)
As Received
6.82
60.59
4.20
0.85
0.03
0.39
6.29
20.83
100.00
Dry Basis
—
65.02
4.51
0.91
0.03
0.42
6.75
22.36
100.00
Sample #2266.
D-61
-------
TABLE D51. PROXIMATE, ULTIMATE, AND MINERAL ANALYSIS RESULTS: LIGNITE FS-11
PROXIMATE ANALYSIS
% Moisture
% Ash
% Volatile
% Fixed Carbon
Btu
% Sulfur
As Received Dry Basis
7.79
6.20
41.15
44.86
100.00
10071
0.44
6.72
44.63
48.65
100.00
10922
0.48
Weight
ULTIMATE ANALYSIS
Moisture
Carbon
Hydrogen
Nitrogen
Chlorine
Sulfur
Ash
Oxygen (diff)
As Received
7.79
60.07
4.44
0.81
0.02
0.44
6.20
20.23
100 .00
Dry Basis
nL
65.14
4.82
0.88
0.02
0.48
6.72
21.94
100 .00
Sample #2267.
D-62
-------
TABLE D52. PROXIMATE, ULTIMATE, AND MINERAL ANALYSIS RESULTS: LIGNITE FS-21
PROXIMATE ANALYSIS
% Moisture
% Ash
% Volatile
% Fixed Carbon
Btu
% Sulfur
As Received
3.79
6.54
42.56
47.11
100.00
10663
0.44
Dry Basis
6.80
44.24
48.96
100 .00
11083
0.46
% Weight
ULTIMATE ANALYSIS
As Received Dry Basis
Moisture
Carbon
Hydrogen
Nitrogen
Chlorine
Sulfur
Ash
Oxygen (diff)
3.79
63.10
4.73
0.90
0.03
0.44
6.54
20.47
100.00
_____
65.59
4.92
0.94
0.03
0.46
6.80
21.26
100.00
Sample #2268.
D-63
-------
TABLE D53. PROXIMATE AND ULTIMATE ANALYSIS RESULTS: LIGNITE FS-24
PROXIMATE ANALYSIS
Z Moisture
Z Ash
Z Volatile
Z Fixed Carbon
Btu
Z Sulfur
As Received
2.06
6.83
44.65
46.46
100.00
10828
0.57
Drv Basis
6.97
45.59
47.44
100.00
11056
0.58
ULTIMATE ANALYSIS
Weight
As Received Dry Basis
Moisture
Carbon
Hydrogen
Nitrogen
Chlorine
Sulfur
Ash
Oxygen (diff)
2.06
64.00
4.31
0.87
0.84
0.57
6.83
21.32
100.00
65.35
4.40
0.89
0.04
0.58
6.97
21.77
100.00
Sample #2269.
D-64
-------
TABLE D54. PROXIMATE, ULTIMATE, AND MINERAL ANALYSIS RESULTS:
LIGNITE FS-50
PROXIMATE ANALYSIS
% Moisture
% Ash
% Volatile
% Fixed Carbon
Btu
% Sulfur
As Received
1.83
17.50
39.89
40.78
100.00
9744
7.12
Drv Basis
17.83
40.63
41.54
100.00
9926
7.25
ULTIMATE ANALYSIS
Moisture
Carbon
Hydrogen
Nitrogen
Chlorine
Sulfur
Ash
Oxygen (diff)
7. Weight
As Received Dry Basis
1.83
55.79
3.62
0.81
0.02
7.12
17.50
13.31
100.00
56.83
3.69
0.83
0.02
7.25
17.83
13.55
100.00
Sample #2270
*Duplicate analysis results (2-8-1980)
% Moisture
% Ash
% Volatile
% Fixed Carbon
Btu
% Sulfur
As Received
6.81
14.52
38.00
40.67
100.00
9242
4.87
Dry Basis
15.58
40.78
43.64
100.00
9917
5.23
D-65
-------
TABLE D55. PROXIMATE, ULTIMATE, AND MINERAL ANALYSIS RESULTS: LIGNITE FS-72
PROXIMATE ANALYSIS As Received Dry Basis
Z Moisture 2.08
Z Ash 10.93 11.16
Z Volatile 45.06 46.02
Z Fixed Carbon 41.93 - 42.82
100.00 100.00
Btu 10143 10358
Z Sulfur 0.51 0.52
2 Weight
ULTIMATE ANALYSIS As Received Dry Basis
Moisture 2.08
Carbon 60.92
Hydrogen 4.50
Nitrogen 0.79
Chlorine 0.04
Sulfur 0.51
Ash 10.93
Oxygen (diff) 20.23 20.66
100.00 100.00
Sample #2271
D-66
-------
SAMPLE
NUMBER
SAMPLE TYPE
SSMS AAS
Prox/ Anion/
ICP Radioactivity Ult Cation
2282
Service Water
G
Figure D7. Analysis Results Matrix: Service Water
-------
TABLE D56. SSMS ANALYSIS RESULTS: SERVICE WATER
Sample #2282
Concentration in yg/ml
ELEMENT CONC
Uranium
Thorium
Bismuth
Lead
Thallium
Ntrcury NR
Gold
Platinum
Irldlum
Osalum
Itanium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thulium
Erbium
Hoi mi urn
Dysprosium
ELEMENT CONC.
Terbium
Gadolinium
Europium
Samarium
Neodymlum
Praseodymium
Cerium 0.004
Lanthanum
Barium 0.03
Cesium 0.002
Iodine
Tellurium
Antimony
Tin
Indium STD
Cadmium
Silver <0.003
Palladium
Rhodium
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Z1nc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
CONC. ELEMENT
Vanadium
Titanium
ScancH urn
<0.004 Calcium
Potassium
0.04 Chlorine
0.002 Sulfur
0.02 Phosphorus
Silicon
<0.001 Aluminum
Magnesium
Sodium
0.04 Fluorine
0.01 Oxygen
0.02 Nitrogen
<0.004 Carbon
0.3 Boron
0.006 Beryllium
0.01 Lithium
Hydrogen
CONC.
0.002
<0.06
<0.002
MC
7
0.2
3
0.05
0.9
0.1
5
7
=0.4
NR
NR
NR
0.01
0.01
NR
STD - Internal Standard
NR - Not Reported
All elements not detected <0.002 yg/ml
MC - Major Component MC >10 yg/ml
INT - Interference
D-68
-------
SAMPLE
NUMBER
SAMPLE TYPE
SSMS
AAS
Prox/ Anion/
ICP Radioactivity Ult Cation
I
VO
2352
2353
2354
Gasifier Ash Leachate
Cyclone Dust Leachate
Leachate Blank
Figure D8. Analysis Results Matrix: Leachates
-------
TABLE D57. SSMS ANALYSIS RESULTS: GASIFIER ASH LEACHATE
Sample #2352
Concentration in ug/ml
ELEMENT
cone.
ELEMENT
CONC.
ELEMENT
CONC. ELEMENT
COWC.
Uranium <0.006
Thorium 10 yg/ml
INT - Interference
*Heterogeneous
D-70
-------
TABLE D58. SSMS ANALYSIS RESULTS: CYCLONE DUST LEACHATE
Sample #2353
Concentration in yg/ml
ELEMENT CONC.
Uranium ±0.01
Thorium <0.01
Bismuth
Lead 0.008
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbium
Thul i urn
Erbium
Hoi mi urn
Dysprosium
ELEMENT CONC.
Terbium
Gadolinium
Europium
Samarium
Neodymi urn
Praseodymium
Cerium 0.001
Lanthanum
Barium 1
Cesium 0.004
Iodine
Tellurium
Antimony 0.008
Tin 0.002
Indium STD
Cadmi urn
Silver
Palladium
Rhodium
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttri urn
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromi urn
CONC.
0.002
0.03
0.003
7
0.02
<0.02
0.006
0.02
0.002
<0.001
0.07
0.006
0.01
0.002
0.6
0.1
0.001
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Nitrogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC.
<0.001
0.05
<0.001
MC
MC
0.1
>6
0.4
MC
>1
MC
>3
=4
NR
NR
NR
0.1
0.04
NR
STD - Internal Standard
NR - Not Reported
All elements not detected <0.001 yg/ml
MC - Major Component MC >10 yg/ml
INT - Interference
D-71
-------
TABLE D59. SSMS ANALYSIS RESULTS: LEACHATE BLANK
Sample #2354
Concentration in yg/ml
CONC. ELEMENT CONC. ELEMENT
ELEMENT
CONC.
ELEAAENT
CONC.
Uranium <0.02
Thorium <0.02
Bismuth
Lead 0.01
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutecium
Ytterbi urn
Thulium
Erbium
Hoi mi urn
Dysprosium
Terbium
Gadolinium
Europium
Samarium
Neodymium
Praseodymi urn
Cerium
Lanthanum
Barium 0.2
Cesium
Iodine
Tellurium
Antimony
Tin
Indium STD
Cadmium
Silver
Palladium
Rhodium
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gal 1i urn
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromi urn
Vanadium <0.001
Titanium 0.01
Scandium <0.001
Calcium 0.6
Potassium *0.7
0.02 Chlorine 0.06
Sulfur 0.08
Phosphorus 0.02
Silicon 0.08
Aluminum *0.03
Magnesium MC
Sodium *0.3
0-04 Fluorine =0.04
0.008 oxygen NR
0-007 Nitrogen NR
<0.001 carbon NR
O-06 Boron
0.003 Beryllium
°-°°l Lithium
Hydrogen
NR
STD - Internal Standard
NR - Not Reported
All elements not detected <0.002 yg/ml
MC - Major Component MC >10 yg/ml
INT - Interference
*Heterogeneous
D-72
-------
TABLE D60. VOLATILE METALS BY AAS: LEACHATES
SAMPLE
NUMBER
2352
2353
2354
SAMPLE TYPE
Gasifier Ash Leachate
Cyclone Dust Leachate
Leachate Blank
As
.019
.033
<.005
Hg
<.0006
<.0003
<.0002
Sb
<.06
<.06
<.06
Se
.014
<.01
.012
As ppm:
D-73
-------
TABLE D61. ANION/CATION ANALYSIS RESULTS: GASIFIER ASH LEACHATE
Parameter
Concentration (ppm)
PH
IDS
TSS
Sulfite
Nitrate
Nitrite
Phosphate
Cyanide
Ammonia
COD
BOD
Phenol
4.13
2131
36.1
<.25
<.01
.1
<.02
<.007
1710
2970
.002
Sample #2352
D-74
-------
TABLE D62. ANION/CATION ANALYSIS RESULTS: CYCLONE DUST LEACHATE
Parameter
pH
TDS
TSS
Sulfite
Nitrate
Nitrite
Phosphate
Cyanide
Ammonia
COD
BOD
Phenol
Concentration (ppm)
4.04
2281
16.7
<10
<.25
<.01
.2
.05
1.8
1410
3150
.038
Sample #2353
D-75
-------
TABLE D63. ANION/CATION ANALYSIS RESULTS: LEACHATE BLANK
Parameter
PH
IDS
TSS
Sulfite
Nitrate
Nitrite
Phosphate
Cyanide
AfmnnTiifl
COD
BOD
Phenol
TOC
Concentration (ppm)
2.01
15
3
<10
<.25
<.01
.1
<.02
<.007
1430
2661
<.002
1.3
Sample #2354
D-76
-------
TABLE D64. IRON AND NICKEL CARBONYL ANALYSIS RESULTS:
COAL BIN VENT GAS
CARBONYL SCM* SAMPLED TOTAL yg Vppm
Fe(CO)5 1.533 50 .033
Ni(COK 1.533 <.2 <.001
===== ~ ' -'-"- •••" • • -.'.' -"" -•-• -rr^^r r._— .:;..•—. . • ^ ^^^^,_ _ ,...—-.- - —— _ ._ ^.-.j— ,. ^^-^^
*SCM at 25°C (77°F) and 101 kPa (1 a tin) , dry basis.
D-77
-------
D3.0 ORGANIC SCREENING ANALYSIS RESULTS
The screening analyses were accomplished using the methods
described in Appendix C of this document. The analytical results are
presented in the following tables by stream:
• Product Gas
- product gas particulates
- product gas organic module composite
• Test Burner Flue Gas
• Gasifier Ash
- gasifier ash
- gasifier ash sluice water
• Cyclone Dust
- cyclone dust
- cyclone dust quench water
An analytical flow diagram of the sample compositing and the
screening analysis steps proceeds each sample results section. Each sample
results section contains the LC fractionatlon and Infrared analysis re-
sults. The gasifier ash sluice water and cyclone dust quench water flow
rates were not well known for the on-site sampling periods, and the cyclone
dust quench wtaer was allowed to remain the contact with the cyclone dust
for an extended period of time. Therefore, fractionation of these non-re-
presentative samples was not undertaken. The IR of each aqueous sample is
compared with the IR of the corresponding solid and the total extractable
organic content is given on the analytical flow diagram for each aqueous
sample.
D-78
-------
>-
h
r—
I
FILTER
SOLUBLES
FILTER
SOLUBLi
15
FILTER
SOLUBLE
:c
oni in^
SOLIDS
SOLIDS
SOLIDS
1
S S
f
K
?
SOXHLET EXTRACT
CH2Cl2-24 hours
EI2O • 24 hours
TCO » I.4mg/m3
GRAV = 240mg/m3
360mg/m3
GRAV = 6300 mgfm3
PARTICULATES
XCOMPOSITE/
TCO = 500 mg/m3
GRAV = 6900 mg/m3
CONCENTRATE FOR LC
TCO = 380 mg/m3
FRACTIONATE
1 1
1 I
I
o
TCO, GRAV, IR
ON EACH FRACTION
'-A
I
CNI
O
Figure D9. Product Gas Particulate Screening Analysis Schematic
D-79
-------
TABLE D65 . LC ANALYSIS RESULTS: PRODUCT GAS PARTICULATES
Total Sample
Taken for LC
Recovered
TCO
mg
3200
5.3
3.3
GRAV
mg
5900
97.6
90.0
TOTAL
mg
6200
102.9
93.3
CONCENTRATION
mg/SCM
7300
6500
LC 1
LC 2
LC 3
LC 4
LC 5
LC 6
LC 7
% Recovery
TCO
mg
0.26
ND
0.17
ND
0.16
2.74
ND
62%
GRAV
mg
12.2
1.3
9.6
5.9
6.9
49.6
4.5
92%
SAMPLE TOTAL
mg
7400
760
5800
3500
4200
31000
2600
89%
CONCENTRATION
mg/SCM
870
89
680
410
490
3600
300
ND - Less than 0.01 mg total TCO.
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
D-80
-------
cm
ooo ooo o o
.. ooo ooo mo
1 o o in Ouno r-» <•
•j- m CM CM I-H 1-1
Product Gas Particulates
TCO = 380 mg/SCM
GRAV = 6900 mg/SCM
LC-1
LC-2
LC-3
LC-4
LC-5
LC-6
LC-7
cm
cooo ooo o
oooo oom o
O O in O in O r~- -3"
- cs CM iH rH
TCO = 0.26 mg
GRAV = 12.2 mg
TCO = <0.0l mg
GRAV = 9.6 mg
TCO = 0.17 mg
GRAV = 9.6 mg
TCO = <0.0l mg
GRAV = 5.9 mg
TCO = 0.16 mg
GRAV = 6.9 mg
TCO = 2.74 mg
GRAV = 49.6 mg
TCO = <0.0l mg
GRAV = 4.5 mg
Figure D10. Infrared Spectra, Product Gas Particulates
D-81
-------
TABLE D66. INFRARED ANALYSIS: PRODUCT GAS PARTICULATE
IR REPORT
Sample: __
PRODUCT GAS PARTICULATE
WAVE NUMBER
ASSIGNMENT
3350
3050
2960, 2920
2850
1680
1600
1510
1460
1380
1270
1020
740
M
V
S
S
M Br
M
W
S
M
M Br
V
W
-OH, -NH
Aromatic CH
Aliphatic CH
Aliphatic CH
Carbonyls
Aromatic ring, COOH, amides,
Aromatic ring, C-N
Aliphatic CH, C-0
Aliphatic CH, C-0, C-N
C-0, C-N, Aromatic overtones
Aromatic overtones, C-0
Aromatic substitution, C-N,
amines
C-C1
Contents: Contains aromatic and oxygenated material as veil as nitrogenous
species.
IR REPORT
Sample: PRODUCT GAS PARTICULATE LC 1
WAVE NUMBER
(cm'1)
INTENSITY
ASSIGNMENT
3050
2920
2850
S
S
S
Aromatic CH
Aliphatic CH
Aliphatic CH
t»: Aliphatic hydrocarbons, some non-substituted aromaticf possible.
D-82
-------
TABLE D66. CONTINUED
IR REPORT
Sample: PRODUCT GAS PARTICULATE LCZ
WAVE NUMBER
(cm -1)
INTENSITY
ASSIGNMENT
3400
2950, 2920
2850
1450
S
S
S
M
-OH, -NH
Aliphatic CH
Aliphatic CH
Aliphatic CH, C-0, C-N
Comments: Appears to be primarily aliphatic. Very weak spectrum.
IR REPORT
Sample: PRODUCT GAS PARTICULATE LC3
WAVE NUMBER
(cm -1)
3400
3050
2960, 2930
2860
1730
1690
1600
1460
1380
1270
1190
1020
880
815
750
INTENSITY
W
W
S
S
W
W Br
W
M
M
W
W
W
W
W
W
ASSIGNMENT
-OH, -NH
Aromatic CH
Aliphatic CH
Aliphatic CH
Carbonyls
Esters, aldehydes, amides
Aromatic ring stretch, C-N
Aliphatic CH
Aliphatic CH, C-0, amides
C-0 amides, aromatic, amines
Aromatic overtones, esters, C-0, C-N
Aromatic overtones C-0
Aliphatic CH, aromatic substitution,
C-S, amines
Aliphatic CH, aromatic substitution,
C-S
Aliphatic CH, aromatic substitution,
C-C1
Comments: Aromatics and aliphatics present.
substitution, oxygenated.
Considerable indications of
D-83
-------
TABLE D66. CONTINUED
IR REPORT
Sample: PRODUCT GAS PARTICULATE LC 4
WAVE NUMBER
(cm -1)
3400
2960, 2920
2850
1700
1600
1460
1380
1240
1160
1020
740, 720
INTENSITY
V
S
S
W Br
W Br
M
W
W Br
W Br
W
W
ASSIGNMENT
-OH, -NH
Aliphatic CH
Aliphatic CH
Carbonyls
Aromatic ring stretch, C-N
Aliphatic CH
Aliphatic CH, C-0 amides, C-S
C-0, amines
Aromatic overtones, esters,
Aromatic overtones, C-O
Aromatic substitution, C-N,
C-N
C-C1
Comments:
Possibly weak aromatic, heterocyclic - 0 and -N probable.
to LC3 and LC5.
Similar
IR REPORT
Sample: PRODUCT GAS PARTICULATE LC 5
HAVE NUMBER
(cm-1)
INTENSITY
ASSIGNMENT
3400
3050
2960, 2920
2850
1700
1600
1460
1380
1270
890
820
750
M
W
S
S
M
M
S
M
M
W
W
W
-OH, -NH
Aromatic CH
Aliphatic CH
Aliphatic CH
Carbonyls
Aromatic ring stretch, C-N
Aliphatic CH, alcohols
Aliphatic CH, alcohols, aldehydes,
amides
Aromatic C-0 esters, C-N
Aromatic substitution, C-N, C-S
Aromatic substitution, C-N, C-S
Aromatic substitution, C-N, C-C1
Comments: Contains aromatic material, strong indication of heterocyclics and
oxygenated material.
D-84
-------
TABLE 66. CONTINUED
IR REPORT
Sample: PRODUCT GAS PARTICULATE LC 6
WAVE NUMBER
(cm "')
3400
3050
2950
2850
1680
1610
1520
1460
1380
1270
1040
810
740
700
Comments: Aromatics,
INTENSITY
S
W
S
S
M
S
W
S
M
S
W
W
M
W
amines and possibly
ASSIGNMENT
-OH, -NH
Aromatic CH
Aliphatic CH
Aliphatic CH
Carbonyls
Aromatic ring stretch, C-N
Aromatic ring stretch
Aliphatic CH, primary alcohols
Aliphatic CH, alcohols, amides,
aldehydes
Aromatic C-0, esters, C-N
Aromatic overtones C-0
Aromatic substitution, C-N
Aromatic substitution, C-N
Aromatic substitution, C-C1
carboxylic acids.
IR REPORT
Sample: PRODUCT GAS PARTICULATE LC 7
WAVE NUMBER
(cm -1)
3300
3060
2960, 2920
2850
1610
1520
1460
1380
1270
740
700
Comments: Similar
INTENSITY
M-
W
S
S
M
W
M
W
M
M
W
to LC 6,
ASSIGNMENT
-OH, -NH
Aromatic CH
Aliphatic CH
Aliphatic CH
Aromatic ring stretch,
Aromatic ring stretch,
Aliphatic CH
Aliphatic CH, C-0
C-0, amides
Aromatic substitution,
Aromatic substitution,
C-N
C-N, salts
C-C1, C-N
C-C1, C-N
D-85
-------
RESIN
EXTRACT
CH2C12.PH - 2
12
TCO - 3SOOmgtat3
QRAV - 1700martT»3
SOXHLET EXTRACT
CH2CI2, 24 hours
Et2O,24houn
TCO * 2000mg/m3
QRAV m 300moMi3
ORGANIC
COMPOSE
CONCENTRATE FOR LC
I
TCO s 6000mg/m3
GRAY s 2200 mg/m3
IR
FRACTIONATE
nil
&\
(SI
TCO.GRAVJR £
ON EACH FRACTION S
Figure Oil. Product Gas Organic Module Composite
Screening Analysis Schematic
D-86
-------
TABLE D67. LC ANALYSIS RESULTS: PRODUCT GAS ORGANIC MODULE COMPOSITE
TCO
mg
GRAV
mg
TOTAL
mg
CONCENTRATION
mg/SCM
Total Sample
Taken for LC
Recovered
33000
64.7
39.3
12000
24.0
30.4
45000
88.7
69.7
8100
6400
LC 1
LC 2
LC 3
LC 4
LC 5
LC 6
LC 7
% Recovery
TCO
mg
6.4
1.5
5.3
0.4
4.8
5.3
15.6
61%
GRAV
mg
11.5
1.0
2.0
1.0
1.4
2.5
11.0
127%
SAMPLE TOTAL
mg
9200
1300
3700
720
3200
4000
14000
80%
CONCENTRATION
mg/SCM
1600
230
660
130
570
710
2500
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
D-87
-------
cm
cm
Resin Blank
Product Gas Organic Module Composite
TCO = 6.0 g/SCM
GRAV =2.2 g/SCM
LC-1
LC-2
LC-3
LC-4
LC-5
LC-6
LC-7
TCO= 6.4 mg
GRAV = 11.5 mg
TCO = 1.5 mg
GRAV = 1.0 mg
TCO - 5.3 mg
GRAV = 2.0 mg
TCO = 0.4 mg
GRAV = 1.0 mg
TCO = 4.8 mg
GRAV = 1.4 mg
TCO = 5.3 mg
GRAV - 2.5 mg
TCO = 15.6 mg
GRAV = 11.0 mg
Figure D12 . Infrared Spectra, Product Gas Organic Module Composite
D-88
-------
TABLE D68. INFRARED ANALYSIS: PRODUCT GAS COMPOSITE
IR REPORT
Sample: PRODUCT GAS COMPOSITE
WAVE NUMBER
(cm ~!)
3350
3050
2960, 2920
2860
1710
1680
1600
1500
1455
1380
1280
1220
1115
1040
810
750
INTENSITY
M
W
S
M
W Br
M Br
M
M Br
S
M
M
W Br
W Br
W
W
W
ASSIGNMENT
-OH, -NH
Aromatic CH
Aliphatic CH
Aliphatic CH
Carbonyls
Carbonyls
Aromatic ring stretch, acids, amides,
amines
Aromatic ring stretch, C-N
Aliphatic CH, primary alcohols,
acids
Aliphatic CH, C-0, C-S
Aliphatic CH, esters, C-N
C-0
Aromatic overtones, C-N
Aromatic overtones, C-0, C-N
Aromatic substitution, C-N
Aromatic substitution, C-N, C-C1
Comments: Not heavily aromatic, contains significant oxygenated and
nitrogenous material.
IR REPORT
Sample: PRODUCT GAS COMPOSITE LC 1
WAVE NUMBER
(cm -1)
2960, 2920
2850
1460
1380
1200
1120
960
INTENSITY
S
S
M
W
W
W
W
ASSIGNMENT
Aliphatic CH
Aliphatic CH
Aliphatic CH
Aliphatic CH
Aromatic overtones
Aromatic overtones, aliphatic CH
Aliphatic CH
Commenta: Aliphatic hydrocarbons.
D-89
-------
TABLE D6S. CONTINUED
IR REPORT
Sample: PRODUCT GAS COMPOSITE LC 2
HAVE NUMBER
(on •>)
INTENSITY
ASSIGNMENT
Insufficient material for spectrum
IR REPORT
Sample: PRODUCT GAS COMPOSITE LC 3
WAVE NUMBER
(cm-1)
3450
3050
2960, 2920
2860
1600
1450
1380
1260
1180
810
745
INTENSITY
M
W
s
s
M Br
M
M
M
W
M
W
ASSIGNMENT
-OH, -NH
Aromatic CH
ATiphaftr CH
A1 -iplml-t r CH
Aromatic ring stretch, -SB
Aliphatic CH
Aliphatic CH, C-0, C-S
C-0, C-N
Aromatic overtones, C-0, C-N
Aroaatic substitution, C-N
Aromatic substitution, C-N, C-C1
Comments: Some aromatic character, primarily allphatics with strong indica-
tions of oxygenated material.
IR REPORT
Sample: PRODUCT GAS COMPOSITE Lc-4
WAVE NUMBER
(cm-1)
3400
2970, 2910
2850
INTENSITY
S
S
S
ASSIGNMENT
-OH, -NH
Aliphatic CH
Aliphatic CH
Comments: Very weak spectrum
D-90
-------
TABLE D68. CONTINUED
IR REPORT
Samp 1 e: PRODUCT GAS COMPOSITE LC 5
WAVE NUMBER
(cm a)
3400
3050
2970, 2930
2860
1700
1600
1500
1460
1380
1260
750
INTENSITY
S
W
S
S
M Br
M
W Br
M
W
W
W
ASSIGNMENT
-OH, -NH
Aromatic CH
Aliphatic CH
Aliphatic CH
Carbonyls
Aromatic ring stretch, C-N
Aromatic ring stretch
Aliphatic CH
Aliphatic CH, C-0
C-0, esters, C-N
Aromatic substitution, C-N, C-C1
Comments:
Weakly aromatic, strong indications of oxygenated compounds.
amines and heterocycllc-N probable.
IR REPORT
Sample: PRODUCT GAS COMPOSITE LC 6
WAVE NUMBER
(cm -1)
INTENSITY
ASSIGNMENT
3350
2970, 2930
2860
1600
1450
1380
S
S
M
M
M
W
-OH, -NH
Aliphatic CH
Aliphatic CH
Aromatic ring stretch, C-N
Aliphatic CH
Aliphatic CH, C-0, C-N
Comments: Weak spectrum
D-91
-------
TABLE D68. CONTINUED
IR REPORT
Sample: PRODUCT GAS COMPOSITE LC 7
WAVE NUMBER
(cm -1)
3300
3050
2970, 2930
2860
1710
1680
1600
1510
1450
1380
1280
1215
1030
810
740
680
INTENSITY
S
W Br
S
M
M Br
M Br
S
M
S Br
M
S
M
W
W
W
W
ASSIGNMENT
-OH, -NH
Aromatic CH
Aliphatic CH
Aliphatic CH
Carbonyls
Carbonyls
Aromatic ring stretch,
Aromatic ring stretch,
Aliphatic CH
Aliphatic CH
C-0
C-0
C-N
C-N
Aromatic overtones, C-0
Aromatic substitution,
Aromatic substitution,
Aromatic substitution,
C-N
C-C1
C-C1
Comments: Carboxylic acids and amines probable.
D-92
-------
o
FILTER 1
i
•MMHM
EVAP. SOLVENT
FILTER
|
-
EVAP. SOLVENT
4 WEIGH I
•j WEIGH
-I WEIGH
-j WEIGH
-j WEIGH I-
-((• ARTICULATES)
SOXHLET EXTRACT
CH2CI2- 24 hours
-24 hours
f CONOENSATE )
EXTRACT
CH2CI2PH = 2
CH2CI2PH = 12
CONCENTRATE FOR LC
| GRAV = 5.4 mg
IR
I FRACTIONATION
I I I I I I
V
TCO,GRAV,IR ON
EACH FRACTION
RESIN
SOXHLET EXTRACT
CH2CI2- 24 hours
E<2O- 24 hours
TEST
BURNER
COMPOSITE
Figure D13. Test Burner Composite Screening Analysis Schematic
-------
TABLE D69
LC ANALYSIS RESULTS: TEST BURNER COMPOSITE
TCO GRAV TOTAL CONCENTRATION
mg mg mg Ug/SCM
Total Sample
Taken for LC
Recovered
*
*
*
160
90.3
78.2
160
90.3
78.2
5400
4700
LC 1
LC 2
LC 3
LC 4
LC 5
LC 6
LC 7
% Recovery
TCO GRAV
mg mg
* 14.2
* 2.2
* 0.7
* 2.1
* 8.0
* 36.2
* 14.8
87%
SAMPLE TOTAL
rag
26
4.0
1.3
3.8
14
66
27
87%
CONCENTRATION
yg/SCM
880
130
44
130
470
2200
910
* Not required by protocol
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
D-94
-------
oo ooo oo o o
— looooomomoo o
cm oinOinor^inc^oin o
cm
Resin Blank
Test Burner Composite
GRAV =5.4 mg/SCM
LC-1
GRAV
LC-2
GRAV
14.2 mg
2.2 mg
LC-3
LC-4
LC-5
LC-6
LC-7
GRAV = 0.7 mg
GRAV = 2.1 mg
GRAV = 8.0 mg
GRAV = 36.2 mg
GRAV = 14.8 mg
Figure D14- Infrared Spectra, Test Burner Composite
D-95
-------
TABLE D70. INFRARED ANALYSIS: TEST BURNER COMPOSITE
IR REPORT
Sample: TEST BURNER COMPOSITE
WAVE NUMBER
(cm -1)
2960
2930
2880
1730
1600
1460
1380
1275
1120
1015
975
INTENSITY
S
S
S
S
W
M
M
S
S
M
M
ASSIGNMENT
Aliphatic CH
Aliphatic CH
Aliphatic CH
Carbonyl
Aromatic ring, amines, amides,
acids
In resin blank
In resin blank
C-0, ether, esters, alcohols
In resin blank
In resin blank
In resin blank
Comments: Negligible N-H and 0-H stretch and no aromatic C-H stretch make
assignments conflicting. Aliphatic ethers, esters, alcohols,
aldehydes, etc., are the only potential assignments
IR REPORT
Sample: TEST BURNER COMPOSITE LC i
WAVE NUMBER
(cm -1)
2950
2920
2850
1460
1375
1200, 1120
965
INTENSITY
S
S
S
M
W
M
M
ASSIGNMENT
Aliphatic CH
Aliphatic CH
Aliphatic CH
Aliphatic CH
Aliphatic CH
Aromatic overtones
Aromatic overtones, aliphatic,
bending
Comments: Weak spectrum, probably just aliphatics
D-96
-------
TABLE D70. CONTINUED
IR REPORT
Sample: TEST BURNER COMPOSITE LC 2
WAVE NUMBER
(cm !)
3050
2020, 2850
2300
1660, 1640
1465
1375
1265
895
735
700
INTENSITY
M
S
w
w
M, Br
W
S
W
S
M
ASSIGNMENT
Aromatic CH
Aliphatic CH
Nitriles, Si-H, C=C
Alkenes, aromatics
Aliphatics
Aliphatics
Inorganic sulfur, methyl silicones,
phosphorous, esters, C-0
Alkenes, aromatic substibution
Aromatic substitution
Aromatic substitution
Comments: Absence of aromatic ring patterns surprising with good aromatic
C-H. Heavy alkene possible but seems unlikely. Possible inor-
ganic compounds present from weak peaks. Most probable is fused
aromatic ring systems.
IR REPORT
Samp 1e : TEST BURNER COMPOSITE LC 3
WAVE NUMBER
(cm"1)
3400
2960, 2930, 2850
1740
1450
1375
1260
1100
1020
800
INTENSITY
W
S
W
M
W
S
W
w
S
ASSIGNMENT
-OH, -NH
Aliphatic CH
Carbonyls
Aliphatics
Aliphatics, strong in resin
C-0
blank
C-0, C-N, strong in resin blank
C-H, C-0
Aromatics, amines, silicone
in resin blank
, strong
Comments:
Very weak spectrum, possibly heterocyclic-N, carbonyl very poor,
-OH stretch could be moisture. Possible heterocyclic-0 or other
oxygen containing compounds.
D-97
-------
TABLE D70. CONTINUED
IR REPORT
Sample: TEST BURNER COMPOSITE LC 4
WAVE NUMBER
(cm *)
3350
2960, 2930, 2860
1740
1460
1260
1020
800
INTENSITY
W
S
S
M, Br
S
W
M
ASSIGNMENT
-OH, -NH
Aliphatic CH
Carbonyls
Aliphatic CH, in resin blank
C-0, strong in resin blank
C-H, C-0
Aromatics, amines, silicones, strong
in resin blank
Comments: Weak spectrum, only the presence of the carbonyl distinguishes
it from LC 3.
IR REPORT
Sample : TEST BURNER COMPOSITE LC 5
WAVE NUMBER
(cm -1)
3400
2970, 2920
2860, 2850
1725
1600, 1580
1460
1380
1260
1130
1070
1020, 1040
730
INTENSITY
W
S
S
S
W
M
W
S
M
M
W
W
ASSIGNMENT
-OH, -NH
Aliphatic CH
Aliphatic CH
Carbonyl
Aromatic ring stretch, amines,
amides
Amides, alkane CH, primary alcohols
Aliphatic C-H, alcohols, hetero-
cyclic-0, -N
Aromatic ethers, esters, hetero-
cyclic-0, amides, carboxylics
Alkenes, aromatic overtones, alde-
hydes, alcohols
Aromatic overtones C-0
Aromatic overtones C-0
Aromatic substitution, amines
Comments: No strong indication of aromatics.
-0 and -N probable.
Amines probable, heterocyclic
D-98
-------
TABLE D70. CONTINUED
IR REPORT
Sample: TEST BURNER COMPOSITE LC 6
WAVE NUMBER
(cm •')
INTENSITY
ASSIGNMENT
3400
3030
2970, 2930
2870
1730
1620, 1580
1460
1370
1280
1115
1015
970
710
680
M
W
S
S
S
M
M
M
S
S
M
S
W
W
-OH, -NH
Aromatic CH
Aliphatic CH
Aliphatic CH
Carbonyls
Aromatic ring stretch, amides, amines
Aliphatic CH, alcohols, aldehydes,
amines
Aliphatic CH, alcohols, aldehydes,
amines
Esters, ketones, heterocyclic-0, -N
Aromatic overtones, C-0, C-N
Aromatic overtones, C-0
Aliphatic CH
Aromatic substitution C-N, C-C1
Aromatic substitution C-S, C-C1
Comments: Similar to LC 5 but has more aromatic character.
IR REPORT
WAVE NUMBER
(cm -1)
3400
2960, 2930
2860
1730
1630
1450
1360
1275
1100
1010
970
INTENSITY
S
S
S
S
M Br
W Br
S
M Br
M Br
M
M
ASSIGNMENT
-OH, -NH
Aliphatic CH
Aliphatic CH
Carbonyls
Alkenes, aromatic ring, amides,
amines
Aliphatics, C-0
Aliphatics, C-0, C-N
C-0, esters, C-N
Aromatic overtones, C-0, C-N
C-0, C-N stretch
Aliphatic CH, C-0, C-N stretch
Comments: Heavily oxygenated, carboxylic acids, and amines, probable.
D-99
-------
SOXHLET EXTRACT
CH2CI2,24 hours
Et20,24 hours
TOO = 21 mg/kg
GRAV = 490 mg/kg
CONCENTRATE FOR LC
TCO = 48 mg/kg
GRAY = 590 mg/kg
IR
FRACTIONATE
I I I I I
TCO, GRAY, IR
ON EACH FRACTION
CM
O
Figure D15. Gasifier Ash Screening Analysis Schematic
0-100
-------
TABLE D71. LC ANALYSIS RESULTS: GASIFIER ASH
Total Sample
Taken for LC
Recovered
LC 1
LC 2
LC 3
LC 4
LC 5
LC 6
LC 7
7, Recovery
TCO*
mg
46
9.7
9.9
TCO*
mg
6.4
1.0
2.3
ND
0.04
0.12
ND
102%
GRAV
mg
550
117.4
99.9
GRAV
mg
59.6
2.0
5.6
4.0
5.2
20.1
3.4
85%
TOTAL CONCENTRATION
mg mg/kg
600
127.1
109.8
SAMPLE TOTAL
mg
310
14
37
19
24
95
16
86%
640
550
CONCENTRATION
mg/kg
330
15
39
20
26
100
17
* Not required by protocol.
ND - Less than 0.01 mg total TCO.
D-dOl
-------
cm
oo
CC
C O
sr o
oo oooo
OO OOiriO
in o m O r>» >*
CM CM r-t
oooo
oooo
ooino m
ST PI CM CM r-l
Gasifier Ash
TCO - 48 mg/kg
GRAV * 590 mg/kg
LC-1
LC-2
LC-3
LC-4
LC-5
LC-6
LC-7
TCO • 6.4 mg
GRAV - 59.6 mg
TCO - 1.0 mg
GRAV - 2.0 mg
TCO = 2.3 mg
GRAV - 5.6 mg
TCO * <0.01 mg
GRAV » 4.0 mg
TCO - 0.04 mg
GRAV - 5.2 mg
TCO - 0.12 mg
GRAV * 20.1 mg
TCO - <0.01 mg
GRAV - 3.4 mg
oo
Figure D16 . Infrared Spectra, Gasifier Ash
D-102
-------
TABLE D72. INFRARED ANALYSIS: GASIFIER ASH
IR REPORT
Sample:
GASIFIER ASH
WAVE NUMBER
(cm l)
INTENSITY
ASSIGNMENT
2970, 2930
2860
1700
1600
1460
1380
1265
1020
810
740
S
S
W
W
M
M
W
W
W
W
Aliphatic CH
Aliphatic CH
Carbonyls
Aromatic ring stretch
Aliphatic CH, C-0
Aliphatic CH, C-0
C-0
Aromatic overtones, C-0
Aromatic substitution
Aromatic substitution, C-C1
Comments: Aliphatic material predominates, oxygenation present.
IR REPORT
Sample:
GASIFIER ASH LC 1
WAVE NUMBER
(cm -1)
INTENSITY
ASSIGNMENT
2960, 2920
2850
1650
1460
1380
S
S
W
M
W
Aliphatic CH
Aliphatic CH
Aliphatic C=C
Aliphatic CH
Aliphatic CH
Comments: Aliphatic hydrocarbons, some alkenes
D-103
-------
TABLE D72. CONTINUED
IR REPORT
Sample: GASIFIER ASH LC 2
WAVE NUMBER
(cm "a)
3050
2960, 2920
2850
1600
1460
1370
1260
1070
1030
810
INTENSITY
W
S
S
W
M
M
S
W Br
W Br
W
ASSIGNMENT
Aromatic CH
Aliphatic CH
Aliphatic CH
Aromatic ring stretch
Aliphatic CH
Aliphatic CH
C-0, C-N
Aromatic overtones, C-0
Aromatic overtones, C-0
Aromatic substitution,
, C-N
, C-N
C-N
Comments: Weakly aromatic, no evidence of carbonyls. Heterocyclic-0
or heterocyclic-N a possibility. Branched chain aliphatics
predominate.
IR REPORT
Sample:
GASIFIER ASH LC 3
WAVE NUMBER
(on-1)
3050
2960, 2915
2850
1700
1600
1460
1375
1260
1030
870
850
750
700
INTENSITY
W
S
S
W
W
M
M
W
W
W
M
W
W
Br
Br
Br
Aromatic
Aliphatic
Aliphatic
ASSIGNMENT
CH
CH
CH
Carbonyls
Aromatic
ring stretch, C-N
Aliphatic CH
Br
Br
Aliphatic
C-0, C-S
Aromatic
Aromatic
Aromatic
Aromatic
Aromatic
CH
overtones,
overtones,
overtones ,
overtones ,
overtones ,
C-0,
C-S,
C-0,
C-0,
C-0,
C-N
C-0,
C-N
C-N,
C-N,
C-N
C-C1
C-C1
Comments: Very similar to LC 2 except more aromatics, some weak carbonyl
and some evidence for sulfur and halogens.
D-104
-------
TABLE D72. CONTINUED
IR REPORT
Sample: GASIFIER ASH LC 4
WAVE NUMBER
(cm -')
INTENSITY
ASSIGNMENT
3400
2960, 2920
2860
1710
1600
1460
1380
1265
1120
1030
810
750
730
700
W
S
S
M
W
S
M
W
W
W
W
W
W
W
-OH, -NH
Aliphatic CH
Aliphatic CH
Carbonyls
Aromatic ring stretch, C-N
Aliphatic CH
Aliphatic CH
C-0, C-N
Aromatic overtones, C-0, C-N
Aromatic overtones, C-0, C-N
Aromatic substitution, C-S
Aromatic substitution, C-C1
Aromatic substitution, C-C1
Aromatic substitution, C-C1
Comments: Heterocyclic-N, heterocyclic-0, heterocyclic-S all possible,
some carbonyl compounds, still a lot of brached aliphatics.
Some evidence of aromatic substitution but no significant
aromatic CH absorbances. Evidence of halogens.
IR REPORT
0 , Q GASIFIER
Sample:
WAVE NUMBER
(cm"1)
3400
2950, 2920
2850
1700
1600
1460
1360
970
ASH LC 5
INTENSITY
M
S
M
M Br
M Br
M
W
W
ASSIGNMENT
-OH, -NH
Aliphatic CH
Aliphatic CH
Carbonyls
Aromatic ring stretch, C-N
Aliphatic CH
Aliphatic CH, C-0
C-0, C-N, C-S, Aliphatic
CH
Comments: Rather weak spectrum. No strong indication of aromatics,
probably not much heterocyclic material.
D-105
-------
TABLE D72. CONTINUED
IR REPORT
Sample: _
GASIFTER ASH LC 6
HAVE NUMBER
(cm -1)
3350
2970, 2920
2850
1710
1510
1460
1380
1100
1020
975
INTENSITY
H
S
S
S Br
M
M
M
w Br
V
V
ASSIGNMENT
-OH, -NH
Aliphatic CH
Aliphatic CH
Carbonyls
Amines, aromatic ring
Aliphatic CH
AUpKaMen, C— 0, C— S
stretch
Aromatic overtones, C-0
C-0, C-N
C-0, C-N
Comments: Similar to LC 5 and LC 7.
IR REPORT
Sample:
GASIFIER ASH LC 7
HAVE SOMBER
(cm-1)
ASSIGNMENT
3350
2960, 2915
2850
1700
1600
1460
1380
1100
V
S
S
M Br
M Sh
M
M
V
-OH, -NH
Aliphatic CH
Aliphatic CH
Carbonyls
Amines, aromatic ring stretch
Aliphatics
Aliphatics, alcohols, amides
Phthalates, aromatic overtones, C-O
C-N
Comments: Quite similar to LC 5 and 6, probably contains carboxylic acids.
D-106
-------
SOXHET EXTRACT
CH2CI2,24 hours
Et2O , 24 hours
TCO = 210mg/kg
GRAY = 14000mg/kg
CONCENTRATE FOR LC
TCO = 660 mg/kg
GRAV = 12000 mg/kg
IR
FRACTIONATE
Fir i i
TCO, GRAV, IR
ON EACH FRACTION
r —
CM
I
-------
TABLE D73. LC ANALYSIS RESULTS: CYCLONE DUST
Total Sample
Taken for LC
Recovered
LC 1
LC 2
LC 3
LC 4
LC 5
LC 6
LC 7
% Recovery
TCO*
mg
94
3.2
1.7
TCO*
mg
1.4
ND
0.12
ND
0.09
0.05
ND
53%
GRAV TOTAL CONCENTRATION
mg mg mg/kg
2600 2700
88.2 91.4
75.3 77.0
GRAV SAMPLE TOTAL
mg mg
17.3 550
1.0 29
9.6 280
10.3 300
5.4 160
23.8 700
7.9 230
85% 83%
13000
11000
CONCENTRATION
mg/kg
2600
140
1300
1400
770
3400
1100
* Not required by protocol.
ND - Less than 0.01 mg total TCO.
D-108
-------
OO OO OOOO
1—— —-• •»_»• •—.- ^_^ s_^ <^_* v^j
OO OO O O in O
oo in o m o
I I. I I
Cyclone Dust
TCO = 660 mg/kg
GRAV = 12000 mg/kg
LC-1
LC-2
LC-3
LC-4
LC-5
LC-6
LC-7
OO OO OOOO
cm'1 §g £ g °, § £ S
-3" CO CM CM iH rH
TCO = 1.4 mg
GRAV = 17.3 mg
TCO = <0.01 mg
GRAV = 1.0 mg
TCO = 0.12 mg
GRAV = 9.6 mg
TCO = <0.01 mg
GRAV = 10.3 mg
TCO = 0.09 mg
GRAV = 5.4 mg
TCO = 0.05 mg
GRAV = 23.8 mg
TCO = <0.01 mg
GRAV = 7.9 mg
Figure D18 . Infrared Spectra, Cyclone Dust
D-109
-------
TABLE D74. INFRARED ANALYSIS: CYCLONE DUST
IR REPORT
Sample :
CYCLONE DUST
WAVE NUMBER
(cm -1)
2970, 2915
2850
1720
1600
1460
1380
1020
730, 720
INTENSITY
S
S
M
W
M
W
W
W
—
ASSIGNMENT
Aliphatic CH
Aliphatic CH
Carbonyls
Amines, aromatic ring stretch
Aliphatic CH
Aliphatic CH
C-0, C-C stretch
Aromatic substitution
Comments: Primarily aliphatic material, some carbonyls present.
IR REPORT
Sample:
CYCLONE DUST, LC 1
WAVE NUMBER
(cm -1
INTENSITY
ASSIGNMENT
2950
2920, 2850
1430
1360
1260
720, 740
M
S
M
W
W
W
Aliphatic CH
Aliphatic CH
Alkanes
Alkanes
Aliphatics
Alkenes
Comments: Aliphatic hydrocarbons. Peaks at 1430 & 1360 present in all
fractions. Not present in q.c. check of cells and instrument
D-110
-------
TABLE D74. CONTINUED
IR REPORT
Sample: CYCLONE DUST, LC 2
WAVE NUMBER
(cm -1) INTENSITY ASSIGNMENT
2980 M Aliphatic CH
2920, 2860 S Aliphatic CH
1020 W C-0
Comments: No indication of aromatics, appears to be slight band spreading
from LC-1. Possibly some ether residue.
IR REPORT
,, , CYCLONE DUST, LC 3
Sample: :
WAVE NUMBER
(cm -1)
2950
2920, 2850
1700
1600
1465
1380
750
INTENSITY
M
S
W Br
W Br
M
W
W
ASSIGNMENT
Aliphatic CH
Aliphatic CH
Carbonyls
C=C
Alkanes
Alkanes
Alkanes
Comments: Retains a great deal of aliphatic character, possibly some
aromatics present.
D-lll
-------
TABLE D74. CONTINUED
IR REPORT
Sample :
CYCLONE DUST, LC 4
WAVE NUMBER
(cm ~l)
3400
2920, 2850
1700
1600
1465
1380
1170
740
INTENSITY
W
S
M
M
S
M
W
M
ASSIGNMENT
-OH, -NH
Aliphatic CH
Carbonyls
C»C
Alkanes
Alkanes
C-0
Alkenes, aromatic
substitution
mts: Still strongly aliphatic, more oxygenated substitution.
Heterocyclic-0 probable, heterocyclic-N possible, phthalates
probably present.
IR REPORT
Sample:
WAVE NUMBER
(an'1)
3400
2920, 2850
1700
1600
1460
1380
740
CYCLONE DUST, LC 5
INTENSITY
W
S
M Br
M Br
M
M
W
ASSIGNMENT
-OH, -NH
Aliphatic CH
Carbonyls
OC
Alkanes
Alkenes , aromat ic
substitution
Comments: Very similar to LC-4
U-112
-------
TABLE D74. CONTINUED
IR REPORT
Sample: CYCLONE DUST, LC 6
WAVE NUMBER
(cm -1) INTENSITY ASSIGNMENT
3400 M -OH, -NH
3050 W Aromatic CH
2930, 2860 S Aliphatic CH
1710 S Br Carbonyls
1610 S Br C=C, C=N
1465 S Alkanes
1380 S Alkanes
1270 M C-0
890 W Aromatics, acids
820 W Aromatics, amines
740 M Aromatics, amines
710 W Aromatics, amines
Comments: Similar to LC-5 but showing more aromatic character. Phthalates,
carboxylic acids, heterocyclic-N compounds probable.
IR REPORT
Sample: CYCLONE
WAVE NUMBER
(cm -1)
3450
2960
2920, 7860
1710
1600
1465
1380
1270
DUST, LC 7
INTENSITY
W
M
S
M Br
W Br
M
W
W
ASSIGNMENT
-OH, -NH
Aliphatic CH
Aliphatic CH
Carbonyls
C=C, C=N
Alkanes
Alkanes
C-0
Comments: Similar to LC-6 except no strong aromatic character,
D-113
-------
GASIF1ERASH
SLUICE WATER
EXTRACT
CH2Cl2,pH*2
Et2O,pH =2
CH2Cl2,pH = 12
Et2O,pH = 12
TCO = 13.7mgfl
QRAV - 112mg/l
IR
JA
I
Figure D19. Gasifier Ash Sluice Water Screening Analysis Schematic
D-114
-------
cm
._ i
cm
: o oooo o oo oo
: o ooom o mo ino
; uo o i.r> o r* in CN c r^
-------
TABLE D75. INFRARED ANALYSIS: GASIFIER ASH SLUICE WATER
IR REPORT
Sample:
GASIFIER ASH SLUICE WATER
WAVE NUMBER
(cm -1)
INTENSITY
ASSIGNMENT
3050
2960, 2930, 2920
2850
1455
1375
1265
1030
740
700
W
s
s
M Br
W
M
W
M
W
Aromatic CH
Aliphatic CH
Aliphatic CH
Aliphatic CH
Aliphatic CH
C-0
C-0
Aromatic substitution, C-C1
Aromatic substitution, C-C1
Comments: Slightly enriched in aromatics from the gaslfier ash, carbonyl
absent.
D-116
-------
CYCLONE DUST
QUENCH WATER
EXTRACT
CH2Cl2,pH = 2
Et20, pH = 2
CH2CI2.PH = 12
Et20,pH = 12
TCO = 3.3 mg/l
GRAV = 56.2 mg/l
IR
u-\
-------
cm
-i
Cyclone Dust
TCO » 660 rag/kg
GRAV - 12000 mg/kg
Cyclone Dust Quench Water
TCO - 3.3 mg/1
GRAV - 56.2 mg/l
Figure D22 . Infrared Spectra, Cyclone Dust Quench Water
D-118
-------
TABLE D76. INFRARED ANALYSIS: CYCLONE DUST QUENCH WATER
IR REPORT
Sample: _
CYCLONE DUST QUENCH WATER
WAVE NUMBER
(cm -1)
INTENSITY
ASSIGNMENT
3350
3060
2960
2920
2860
1710
1610
1500
1460
1380
1270
810
740
710
M
W
M
S
M
M Br
M Br
W Sh
M
W
S
W
S
M
-OH, -NH
Aromatic CH
Aliphatic CH
Aliphatic CH
Aliphatic CH
Carbonyls
C=C, C-N
Aromatic ring overtones
Alkanes
Alkanes
C-0
Aromatic substitution, amines
Aromatic substitution, amines
Aromatic substitution, amines
Comments: Considerably enriched in aromatics from the cyclone dust, but
otherwise quite similar.
D-119
-------
D4.0 DETAILED ORGANIC ANALYSIS RESULTS
The results of the instrumental analyses given in the following
data section were obtained using the analytical methods described in
Section 4.0 of Appendix C. The results of the thermal desorption GC-MS
analysis of the Tenax GC/silica gel trap sample of the product gas are
given in Table D77. Also given in this data section are the results of the
halogen-specific GC analysis using the Hall electrolytic conductivity
detector. Samples for specific ion monitoring GC/MS were prioritized on
the basis of the weighted discharge severity (WDS) and the results of thse
anlayses are given along with the concentration of the compounds of
concern. The sample and analysis methods are listed by stream in the
detailed organic anlaysis results matrix which is Figure D23. The results
tables follow in the order shown in the Figure.
D-120
-------
SAMPLE HALL GC SIM GC-MS
Product Gas Particulates
Total Sample •
LC-1
LC-2
LC-3 •
LC-4 •
LC-5
LC-6 •
LC-7
Product Gas Organic Module Composite
Total Sample •
LC-1
LC-2
LC-3 •
LC-4
LC-5 •
LC-6
LC-7
Test Burner Composite
Total Sample •
LC-1
LC-2 •
LC-3 •
LC-4
LC-5
LC-6
LC-7
Gasifier Ash
Total Sample •
LC-1
LC-2
LC-3 •
LC-4
LC-5 •
LC-6 •
LC-7 •
Cyclone Dust
Total Sample •
LC-1
LC-2 •
LC-3 •
LC-4
LC-5
LC-6
LC-7
Figure D23. Detailed Organic Analysis Results Matrix
D-121
-------
TABLE D77. THERMAL DESORPTION GC-MS ANALYSIS RESULTS:
PRODUCT GAS TENAX GC/SILICA GEL TRAP
Compounds Identified
Benzene
Thiophene
Toluene
Ethyl Benzene
m- and p-Xylene
0-Xylene
Amount
ng
>1300
190
26
3.9
4.8
4.8
Concentration
yg/SCM*
>13,000
1,900
260
39
48
48
*SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
D-122
-------
SAMPLE HALL GC SIM GC-MS
Total Sample •
LC-1
LC-2 •
LC-3 • •
LC-4 • •
LC-5 •
LC-6 • •
LC-7
Figure D24. Product Gas Particulates
D-123
-------
TABLE D78. HALOGEN-SPECIFIC GC ANALYSIS RESULTS:
PRODUCT GAS PARTICULATES
SAMPLE HALOGENATED CONCENTRATION*
Total Sample <200 ug/SCM
LC-3 ND
LC-4 ND
LC-6 ND
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
ND - no detectable response.
*Weighed response factor approximating a monochlorinated
compound MW - 180.
D-124
-------
TABLE D79. SPECIFIC ION MONITORING GC-MS ANALYSIS RESULTS:
PRODUCT GAS PARTICULATES, LC-2
N3
1st
COMPOUND
Polychlorinated biphenylsf
Benzo (a) anthracene
7 , 12-Dlmethylbenzo (a) anthracene
Benzo (b) f luoranthene
Dibenzo (a , i) pyrene
Benzo (c)phenanthrene *
Benzo (a) pyrene
3-Methyl cholanthrene
Dibenzo (a, h) anthracene
RETENTION QUANTIFICATION
TIME IONS
23.3 222,
31.3 228,
256,
35.1 252,
302,
228,
252,
268,
178,
224, 256, 258
226
241
250
300
226
250
253
176
AMOUNT CONCENTRATION *
PPM Wg/SCM
£0.033 <7.6
0.12* 28
ND
0.044* 10
ND
ND
ND
ND
ND
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
ND = not detected.
naEB = a x 10b.
*Includes possible coeluting isotners.
^Standard unavilable, based on benzo (.a) anthracene and chrysene.
tBased on PCB-3 Cl.
-------
TABLE D60. SPECIFIC ION MONITORING GC-MS ANALYSIS RESULTS:
PRODUCT CAS PAHTICULATES, LC-3
COMPOUND
Polychlorlnated biphenylat
Blphenyl
Benzo (a) anthracene
7 , 12-Dlaethylbenzo(a)anthracene
Benzo (b) £ luoranthene
Dlbenzo (a, 1) pyrene
Benzo (c) phenanthrene*
c Benzo (a) pyrene
£ 3-Methyl cholanthrene
^
Dlbenzo (a ,h) anthracene
UTEHTXOH
TIME
16.5
31.1
34.6
35.0
30.4
35.4
36.8
43.1
QUAWTIFICATKW
IONS
222, 224, 256, 238
134, 153
228, 226
256, 241
252, 250
302, 300
228, 226
252, 250
268, 253
27ft, 276
AMOUNT
PPM
ND
0.9
12.6*
1.17*
2.7*
ND
7.04*
1.4
0.034
0.044
CONCENTRATION "
yg/SCM
1.2E2
1.7E3
1.6E2
3.7E2
9.7E2
1.9E2
4.7
6.1
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
ND • not detected.
"aEb -ax lflb,
*Includes possible coeluting Isomers.
Based on PCS-3 Cl.
^Standard unavailable, based on benzo(a)anthracene and chrysene.
-------
7
TABLE D81. SPECIFIC ION MONITORING GC-MS ANALYSIS RESULTS:
PRODUCT GAS PARTICULATES, LC-4
RETENTION
COMPOUND TIME
Chloronitrobenzene
Dinitro toluenes 19.8, 20.2,
21.2
Ethyl methyl dioxolane
Tetramethyl succinonitrllet
Benzothiophene
Benzonitrile
QUANTIFICATION AMOUNT CONCENTRATION
IONS PPM yg/SCM
157, 159 ND
165, 89 16* 2.2E3
101, 87 ND
136, 121 ND
134, 89 ND
103, 76 ND
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
ND = not detected.
o aEB - a x 10b.
*A11 possible isomers included.
tNo standard mass spectrum available.
-------
TABLE D82 SPECIFIC ION MONITORING GC-MS ANALYSIS RESULTS:
PRODUCT GAS PARTICULATES, LC-5
I
N:
c:
COMPOUND
N-Nitrosodlmethylamlne
Aminotoluene
0-propiolactone
Trinitrophenol
Dinltrocresol
Dihydroacr Id ine
Dibenzoacridine
RETENTION QUANTIFICATION
TIME IONS
74, 42
107, 106
42, 43
229, 91
12.5 198, 182
20.8 181, 180
279, 277
AMOUNT CONCENTRATION n
PPM Ug/SCM
ND
ND
ND
ND
6.1 8.4E2
0.17 23
ND
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
ND - not detected.
n v,
aEb - a x 10 .
^Standard unavailable, based on dihydrophenanthridine.
tNo standard available.
GC column: 1% SP-1240 DA for acidic compounds.
-------
TABLE D83. SPECIFIC ION MONITORING GC-MS ANALYSIS RESULTS:
PRODUCT GAS PARTICULATES, LC-6
1
K?
COMPOUND
N-Nitrosodimettiylamine
Amino toluene
(3-propiolactone
Trinitrophenol
Dinitrocresol
Dihydroacr idine*
Dibenzoacr idine
RETENTION QUANTIFICATION
TIME IONS
74, 42
107, 106
42, 43
229, 91
198, 182
20.3, 21.33 181, 180
279, 277
AMOUNT
PPM
ND
ND
ND
ND
ND
0.66
ND
CONCENTRATION
Ug/SCM
91
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
ND = not detected.
*Standard unavailable, based on dihydrophenanthridine.
tNo standard available.
u
GC column: 1% SP-1240 DA for acidic compounds.
-------
SAMPLE HALL GC SIM GC-MS
Total Sample •
LC-1
LC-2 •
LC-3 • •
LC-A
LC-5 • •
LC-7
Figure D25. Product Gas Organic Module Composite
D-130
-------
TABLE D84. HALOGEN-SPECIFIC GC ANALYSIS RESULTS:
PRODUCT GAS MODULE COMPOSITE
SAMPLE HALOGENATED CONCENTRATION-
Total Sample <2 mg/SCM
LC-3 ND
LC-5 ND
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
ND - no detectable response.
^Weighed response factor approximating a monochlorinated
compound MW = 180.
D-131
-------
TABLE D85. SPECIFIC ION MONITORING GC-MS ANALYSIS RESULTS:
PRODUCT GAS ORGANIC MODULE COMPOSITE, LC-2
COMPOUND
RETENTION
TIME
QUANTIFICATION AMOUNT
IONS PPM
CONCENTRATION
Ug/SCM
ho
Polychlorinated Biphenyls
Benzo (a) anthracene
7,12-Dimethylbenzo(a) anthracene
Benzo (b) f luoranthene
Dibenzo(a,i)pyrene
Benzo (c) phenanthrene*
Benzo(a)pyrene
3-Methyl cholanthrene
Dibenzo (a , h) anthracene
23.3 222, 224, 256, 258
31.3 228, 226
256, 241
252, 250
302, 300
228, 226
252, 250
268, 253
278, 276
<0.031
*
0.035
ND
ND
ND
ND
ND
ND
ND
£7.2
8.1
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
ND = not detected.
^Includes possible coeluting isomers.
Based on PCB-3 Cl.
^Standard unavailable, based on benzo(a)anthracene and chrysene.
-------
TABLE D86. SPECIFIC ION MONITORING GC-MS ANALYSIS RESULTS:
PRODUCT GAS ORGANIC MODULE COMPOSITE, LC-3
COMPOUND
RETENTION
TIME
QUANTIFICATION AMOUNT
IONS PPM
CONCENTRATION
yg/SCM
G
Poly chlorinated blphenylst
Biphenyl
Benzo (a) anthracene
7 , 12-Dimethylbenzo (a) anthracene
Benzo (b) f luoranthene
Dibenzo(a,i)pyrene
Benzo (Ophenanthrene^
Benzo(a)pyrene
3-Methyl cholanthrene
Dibenzo (a , h) anthracene
222,
16.5 154,
31.3 228,
256,
35.0 252,
302,
30.5 228,
252,
268,
278,
224, 256, 258 ND
153
226
241
250
300
226
250
253
276
16.1
*
0.46
ND
0.033*
ND
0.21
ND
ND
ND
5E3
140
10
65
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis.
ND = not detected.
«aEb = a x 10b
*Includes possible coeluting isomers.
tBased on PCB-3 Cl.
^Standard unavailable, based on benzo(a)anthracene and chrysene.
-------
TABLE D87. SPECIFIC ION MONITORING GC-MS ANALYSIS RESULTS:
PRODUCT GAS ORGANIC MODULE COMPOSITE, LC-5
G
COMPOUND
N-Nitrospdimethylamine
Aminotoluene
B-propiolactone
Trinitrophenola
Dinltrocresol
Dlhydroacrldine
Dibenzoacridine
RETENTION QUANTIFICATION
TIME IONS
74, 42
107, 106
42, 43
229, 91
12.5 198, 182
181, 180
279, 277
AMOUNT CONCENTRATION n
PPM yg/SCM
ND
ND
ND
ND
3.2 9.8E2
ND
ND
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis,
ND - not detected.
«aEb = a x 10b.
tNo standard available.
GC column: 1% SP-1240 DA for acidic compounds.
-------
SAMPLE HALL GC SIM GC-MS
Total Sample •
LC-1
LC-2 • .
LC-3 •
LC-4
LC-5
LC-6
LC-7
Figure D26. Test Burner Composite
-------
TABLE D88. HALOGEN-SPECIFIC GC ANALYSIS RESULTS:
TEST BURNER COMPOSITE
SAMPLE HALOGENATED CONCENTRATION*
Total Sample <30 yg/SCM
LC-2 <2 yg/SCM
LC-3 <5 yg/SCM
SCM at 256C <77°F) and 101 kPa (1 atm), dry basis.
^Weighed response factor approximating a monochlorinated
compound MW » 180.
D-136
-------
TABLE D89. SPECIFIC ION MONITORING GC-MS ANALYSIS RESULTS:
TEST BURNER COMPOSITE, LC-2
RETENTION QUANTIFICATION AMOUNT CONCENTRATION13
COMPOUND TIME IONS PPM Pg/SCM
Benzo(a)pyrene
Dibenzo (a, h) anthracene
7 , 12-Dimethylbenzo (a) anthracene
Benzo (a) anthracene
Polychlorinated biphenylst
252,
278,
256,
31.8 228,
188,
250
276
258
226
190, 222,
ND
ND
ND
0.17*
ND
4.5E2
224, 256, 258
SCM at 25°C (77°F) and 101 kPa (1 atm), dry basis,
ND = not detected.
n b
aEb = a x 10 .
*Includes possible coeluting isomers.
^Based on PCB-3 Cl.
-------
SAMPLE HALL GC SIM GC-MS
Total Sample •
LC-1
LC-2
LC-3 •
LC-4
LC-5 •
LC-6 •
LC-7 •
Figure D27. Gasifler Ash
D-138
-------
TABLE D90. HALOGEN-SPECIFIC GC ANALYSIS RESULTS:
GASIFIER ASH
SAMPLE HALOGENATED CONCENTRATION*
Total Sample <300 mg/kg1"
LC-3 <30 yg/kg
LC-5 <25 yg/kg
LC-6 <5 mg/kg
LC-7 <150 yg/kg
Possible interference.
^Weighed response factor approximating a
monochlorinated compound MW = 180.
D-139
-------
SAMPLE HALL GC SIM GC-MS
Total Sample •
LC-1
LC-2 •
LC-3 •
LC-4
LC-5
LC-6
•
LC-7
Figure D28. Cyclone Dust
D-140
-------
TABLE D91. HALOGEN-SPECIFIC GC ANALYSIS RESULTS:
CYCLONE DUST
SAMPLE HALOGENATED CONCENTRATION'
Total Sample <35 tng/kg
LC-2 ND
LC-3 ND
^Weighed response factor approximating a monochlorinated
compoung MW = 180.
ND = no detectable response.
D-141
-------
APPENDIX E
SOURCE ANALYSIS MODEL/1A RESULTS
TABLE OF CONTENTS FOR APPENDIX E
Notes for the Tables E-2
El.O GASEOUS STREAMS E-3
Product Gas Particulates, Health Impact E-3
Product Gas Particulates, Ecology Impact E-33
Product Gas Organic Module Composite, Health Impact .... E-41
Product Gas Organic Module Composite, Ecology Impact .... E-70
Test Burner Flue Gas Composite, Health Impact E-77
Test Burner Flue Gas Composite, Ecology Impact E-97
E2.0 LIQUID STREAMS E-104
Gasifier Ash Sluice Water, Health Impact E-104
Gasifier Ash Sluice Water, Ecology Impact E-123
Cyclone Dust Quench Water, Health Impact E-136
Cyclone Dust Quench Water, Ecology Impact E-154
E3.0 SOLID STREAMS E-167
Gasifier Ash, Health Impact E-167
Gasifier Ash, Ecology Impact E-179
Cyclone Dust, Health Impact E-195
Cyclone Dust, Ecology Impact . E-215
E-l
-------
NOTES FOR THE FOLLOWING TABLES:
P « compound is on Priority Pollutant List
W • compound is the worst case within the appropriate
matrix for that category/subcategory
T - concentration is total organic loading (TCO + GRAV)
for the LC fraction
S • concentration is from SSMS
D » concentration is determined experimentally; from
on-site analysis, SIM-GC/MS, Anion/Cation analysis
ICP or AAS
Cone - concentration in yg/SCM at 25°C (77°F) and 101 kPa
(1 atm) dry basis, for gases; yg/1 (ppb) for liquids;
and yg/g (ppm) for solids
WDS - units are g/s for all streams
LCCAT - established LC fraction if applicable
* * indicates that the compound appears more than once
in the listing, i.e. in more than one LC fraction
E-2
-------
PRODUCT GAS PARTICULATE
PLOW RATE 590 G/S (0.57 SCM/S, DRY BASIS)
8.523 SCM AT 25C AND 760 MM HG SAMPLED
TOTAL ORGANIC LOADING = 7.3 G/SCM
TOTAL TCO = 380 MG/SCM TUTAL GKAV = 6900 MG/SCM
0.17X ORIGINAL SAMPLE TO LC
LC TCO = 5.3 MG LC G*AV = 97.6 MG LC TOTAL s 102.9 MG
LCCAT ORGANIC LOADING
1 870000.0
2 89000.0
3 680000.0
a aioooo.o
5 490000.0
6 3600000.0
7 300000.0
FLOW RATE s 590.00
STATE: GAS, UNITS IN MICHOGRAMS/SCM
IMPACT: HEALTH
EXPERIMENTALY DETERMINED DATA
SPARK SOURCE DATA
w
OJ
-------
p]
PRODUCT GAS PARTICULATE, HEALTH IMPACT
DMEG
04
04
10
10
10
10
12
10
20
20
20
21
02
10
10
10
10
19
13
10
23
10
13
10
10
10
23
12
08
10
08
08
08
08
B
B
C
C
C
C
A
C
B
B
B
C
B
C
C
C
C
A
A
C
C
C
A
C
C
C
C
C
NO.
020* P H
020* P H
100*
043*
041*
042*
040* P
220*
041*
020* P M
042*
100* P M
140* P M
082*
061*
080*
081*
060* P M
100* M
200*
160* W
100*
140*
042*
043*
041*
160* *
040* P
122*
140* P
121*
123*
120* M
060* M
COMPOUND NAME
l»r-DICHLOROMETHYL ETHER
Irl'-DICHLOROMETHYL ETHER
1,4-UIAMINOBENZENE
4-AMINOTOLUENE
2-AMINOTOLUENE
3-AMINOTOLUENE
N-NITROSODIETHYLAMINE
2-AHlNONAPHTHAtENE
3,5-DlNlT«0-P-CRESOL
4,6-DINlTHO-U-CRtSOL
2,6-DlNlTKu-P-CRESOL
BENZO(A)PYRENE
HEXACHLOROCYCLOPENTADIENE
M-ANI3XDINE
P-ANISIOINE
ANISIDINES
0-ANISIDINE
PENTACMLOROPHENOL
BtNZENETHlOL
1-AM1NONAPHTHALENE
DIbtNZO(C,Q)CARBAZOLE
1,4-DIAMINOBENZENE
PERCHLORONETHANETHIUL
3-AMINOTOLUENE
4-AMlNOTULUtNE
2-AMINOTOLUENE
DlbENZO(C,G)CARBAZOLE
N-NITROSODItTHYLAMINE
PALMITIC ACID
BENZIDINE
MYRISTJC ACID
3TEAHIC ACID
SATURATED LONG CHAIN AC IDS ( MM s 228*285)
ft-HEXANELACTAH
TYPE CONC
E-6 t/SCM
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
4.90E
4.10E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
1.90E
8.70E
3.60E
3.60E
3.6UE
3.60E
3.6UE
3.6UE
i.60E
4.90fc
4.9UE
3.6UE
4.9&E
4.90E
4.90t
4.1UE
4.9UE
3.60E
3.60E
3.6UE
i.bOt
3.60E
J.6UE
Ob
05
06
06
06
06
06
06
06
06
06
02
05
06
06
06
06
06
U6
06
OS
OS
06
05
OS
US
OS
05
06
06
06
06
06
06
US
9.BOE
6.20E
S.bOt
3.JOE
3.30E
3. JOE
3.00E
2. HE
1.80E
l.dOE
1.80E
9.SOE
7.90E
7.20E
7.40E
7.20E
7.20E
7.20E
7.20E
6.42E
4.90£
4.90E
4. SOt
4.50E
4.SOE
4.SOE
4.10E
4.10E
3.60E
3.6UE
3.60t
J.60t
3.60E
3.60£
04
04
04
04
04
04
04
04
04
04
04
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
Y3
03
03
"US
G/S
5.80k
4.83t
2.12E
.93E
.93t
.V3E
.eot
.24E
.lot
.lot
.10E
5.60t
4.70t
4.24£
4.24E.
4.24t
4.24t
4.241:
4.24t
3.BOE
2.90t
2.90t
2.70t
2.62t
2.6^t
2.62t
2.41E
2.40E
2.Ut
2.12t
2.12E
2.12t
2.12E
2.12t
LCCAT
y/
07
07
07
07
07
07
07
07
07
07
06
06
06
06
06
06
06
06
Ob
06
06
06
06
06
06
06
06
06
06
06
06
06
06
S
4
6
6
6
6
6
6
6
6
S
S
6
5
S
5
4
5
-------
PRODUCT GAS PARTJCULATE, HEALTH IMPACT
DMEG NU.
COMPOUND NAME
TYPE CONC
E-b
US
WDS
LCCAT
21
21
21
21
21
21
21
21
21
21
21
10
10
12
20
20
20
20
20
20
20
20
IB
02
12
od
10
10
19
10
13
10
08
10
t
I
b
B
B
B
B
b
8
B
B
B
c
C
C
B
A
A
A
A
A
B
B
B
B
A
A
A
C
C
A
C
A
C
B
C
fl
i
_n
106*
103*
108*
105*
10B*
107*
104*
109*
102*
10A*
101*
220*
120*
020* rt
102*
101* P
100*
103*
OoO*
041*
04?*
020* P W
060* M
380* H
060* P
140*
062*
063*
060* P W
081*
100* W
OoO*
060* ri
200*
7-METHtL oENZOCUPHkNANTHittNE
2-METHYL btNZOCCJPHtNANTHKENt
2-tTHYL BENZO(C)PH£NANTHKENE
b-METHYL bENZO(OPrttNANTHHE^t
ISOPKUPYL btNZOCUPHEMNTHRENt
B-htTHYL BENZO(C)PHtNANTHK£NE
5-MtTHYL OtNZG(C )PHtNANTnrt£N£
b-tTHYL BENZO(C)PHENANTHR£Nt
1-METHYL btNZOCOPHtNANTHKENE
N-PKOPYL B£NZO(C)PHtMAf«THK£Nt
BENZOlUPHENANTHKtNt
2-AMINGNAPHTHAL£Nt
4-AMjNOBIPHtNYL
N-METHYL-N-NITHOSOANILINE
2,5-UlNITKOPHENGL
2»4-DINITKUPH£NGL
UlNITKOPHtNOLS
2rb-DIMTKOPHENOL
2-AMINO-4,b-OIMTKOPHENOL
3»5-L>IMTRO-P-CR£SOL
2fb-i)IMTKU-P-CRtSOL
4,6-DlNlTKO-O-CKtSuL
1,4-DlHYDROXYBENZENt
HEXACHLGSOCYCLOHEXANE
N-NlTROSOOIPrtOPYLAMlNt
OLEIC ACID
M-ANISIDINE
P-ANISIDINE
PENTACHLOKOPHENGL
O-ANISIDINE
BENZtNETHlUL
AN1SIOINES
B-PROPIOLACTUNE
1-AMINONAPHTHALENE
1
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
b.80t
b.BOE
b,60t
b.80E
b.COt
b.80t
b.SOt
b.80t
b.80E
b.BOE
b.oot
<4.9y£
3. but
3.60E
3.bOt
3.60E
3.60E
3.60E
3.60E
4.90t
4.90t
a.90t
3.60E
B.70E
3.60E
3.6UE
4.90E
4.90E
M.9Ut
4.90E
4.90E
M.90E
3. Out
4.VUt
05
05
05
05
05
05
05
05
05
Ob
Ob
Ob
06
06
06
06
Ob
Ub
Ob
05
05
05
00
05
06
06
05
05
05
05
05
05
05
05
3. lot
3. lot
3.10E
3. lot
3. 10t
3.1UE
3.iOt
3. lOt
3. lot
3.10c
3. iOt
2.VOt
2.80t
2.60t
2.60E
2.60E
2. but
2.bOE
2.bOt
2.50t
2. SOt
2.bOt
l.BOt
l./4t
1.50E
l.lot
9.80E
9.80E
9.8ot
9.00E
9.80E
9.60t
9.40£
8.60E
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
u3
03
03
i>3
03
03
03
03
02
02
02
02
02
02
02
02
l.«2t
I.b2t
1.82t
1.62t
1.62t
1 ,62t
1.62t
1.82t
1.62t
1.62t
l.»2t
1.70E
I.b3t
I.b3t
1.51t
l.blt
1.5lt
1.5it
1.51£
1.44E
1.44t
1 .44t
l.lot
1.02t
a.9ot
b.43t
5.00t
5.80t
5.60t
5.60t
5.80t
5.60t
5.53t
5.20t
Ob
06
Ob
06
06
Ob
06
Ob
06
Ob
Ob
06
06
06
06
06
Ob
06
Ob
06
Ub
Ob
Ob
Ob
05
05
05
05
05
05
05
U5
05
05
3
3
3
3
3
3
3
3
3
3
3
5
b
b
b
b
b
b
6
5
5
5
b
1
6
b
5
5
5
5
5
5
7
5
-------
PI
ON
PRODUCT GAS PARTICULAR, HEALTH IMPACT
DUE
23
02
23
06
08
Ob
oe
08
02
Ot)
06
06
06
08
21
21
13
23
23
23
23
10
19
06
17
17
08
08
08
10
08
22
22
21
.G
D
B
D
D
0
D
0
D
A
A
A
A
A
A
D
6
A
A
A
A
A
A
A
A
a
6
A
A
C
C
A
D
C
A
NO.
020* M
140* P M
040*
261*
263*
262*
260* P M
300* P
160*
101*
102*
104*
100*
103*
060*
060* W
140*
102*
100* M
103*
101*
060*
040* P
121*
060* «
040* w
123*
122*
060* W
140* P
120* W
020* P W
020* P
180* P W
COMPOUND NAME.
BENZOTHIAZOLE
HfcXACHLOROCYCLOPENTADlENE
METHYL BENZOTHIAZOLt
DIMETHYL PHTHALATE
DI-N-BUTYL PHTHALATE
DIETHYL PHTHALATE
PHTHALATE ESTERS (MK| 194-279)
DI-2-ETHYLHEXYL PHTHALATE
DIBKOMODICHLOHOME THANt
CAPROIC ACID
CAPRYLIC ACID
LAORIC ACID
SATURATED LONG CHAIN ACIDS (M« til 6-201)
CAPRIC ACID
DIBENZO(A,L)PYRENE
7,12-DIMfcTHYLBENZCA) ANTHRACENE
PERCHLOROMETHANETHIOL
3-CHLOROPYRIDINE
CHLOROPYRIDINES
4-CHLOROPYRIDINE
2-CHLOROPYRIDINE
ETHANOLAMINk
2»4-DICHLOROPHENUL
MYRISTIC ACID
1-CHLORO-4-N1TROBENZENE
l-CHLORO-2-MTRObENZENE
STtAHIC ACIU
PALMITIC ACID
6-HEXANELACTAM
BENZIDINt
SATURATED LONG CHAIN ACIDS (MM|228-285)
INDENO(l,2,3-CD)PYRtNE
BENZO(K)FLUORANTH£Nt
PHfcNANTHRfcNt
TYPE CONC
E-6 G/8CM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
3.60t
6.9UE
3.60E
3.60E
3.60E
3.60fc
3.60E
3.60E
6. TOE
3.60E
3.60E
3.60E
3.60E
3.60E
6. 80t
1.60E
4.90E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
4.90E
4.90E
4.90E
4.9WE
4.90E
4.90E
4.9UE
4.90E
6.60E
6. dOE
6.80E
06
04
06
06
06
06
06
06
05
06
06
06
06
06
05
02
05
06
06
06
06
06
06
05
05
05
05
05
05
05
05
05
05
05
US
6.40E
8.10E
7. TOE
7.20E
7.20E
7.20E
7.20E
7.20E
6.21E
6.20E
.20E
.20E
.20E
.20E
.20E
.20E
.12E
.10E
.10E
.lot
6.10E
6.00t
5.14t
4.90E
4.90E
4.VOE
4.VOE
4.90E
4.VOt
4.90£
4.90E
4.30E
4.30E
4.30E
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
WDS
U/S
4.93t
4.60E
4.51E
4.24L
4.24E
4.24E
4.24t
4.24k
3.70E
3.70fe
3.70E
3.70E
3.70E
3.70L
3.64L
3.63t
3.61t
3.60E
3.60b
3.6Ut
3.60t
3.54t
3.03t
2.9ot
2.90t
2.90t
2.90t
2.90E
2.Vot
2.90t
2.9Qt
2.bOfc
2.50C.
2. SOt
05
05
05
05
05
05
05
05
05
05
05
05
05
05
Ob
05
05
05
05
05
05
05
ub
Ob
OS
ub
05
05
Ob
05
05
05
05
05
LCCAT
6
2
b
6
6
6
6
6
1
6
t>
6
6
6
3
i
b
6
6
6
6
6
6
5
5
b
b
5
b
5
5
3
3
3
-------
PRODUCT GAS PARTICULAR, HtALTH IMPACT
DMEG NO.
COMPOUND NAME
TYPE CONC US
E-6 WSCM
LCCAT
U/b
21
21
21
21
21
21
21
21
21
21
21
21
21
21
10
17
12
14
18
18
Oe>
18
18
18
18
18
18
20
20
20
20
20
15
23
B
B
B
B
b
8
B
b
B
b
B
b
B
B
C
A
B
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
8
6
109*
102*
10A*
107*
104*
106*
103*
101*
10B*
105*
108*
142*
141*
140*
120*
060* W
020* W
020 W
063*
082*
020* W
041*
043*
0«0* W
04C* W
081*
042*
102*
080*
103*
100*
101* P
060* W
200*
6-ETHYL BENZO(C)PHENANTHRENE
1-METHYL d£NZO(C JPHENAN IHRE^E
N-PROPYL BENZO(C)PHtNAMTHKENE
8-METHYL bENZG (OPhENANTHKEwE
5-METhYL btNZO(C)PHENANTHKENE
7-METHYL BENZO(C)PHENANTHRENE
2-htTHYL BENZOCOPHtNANTHREist
BENZO(C)PHtNANTHRENt
ISOPKOPYL BENZOCOPHENANTHRENE
6-METHYL BENZU(CJPHENANTHRENE
2-ETriYL BENZO(C) PHENANTHRENE
5-rtETHYL CHRYSENE
4-METHYL CHKYSENE
METHYL CHRYSENES
4-AMIN03IPHENYL
4-NITROBIPHENYL
N-f.ETHYL-N-NlTROSU ANILINE
DIMETHYL SULFOXIDE
P-ETHYLPHENOL
rt-ETHYLPHENUL
ETHYLENE 6LYCOL
M-CRESOL
P-CRESOL
ETHYLPHENOLS
CRESOLS
0-ETHYLPHENOL
0-CRESOL
2r5-DINITROPHENOL
2-AMlNG-4,6-DlNlTROPHENUL
2,6-DINlTRUPHENOL
OINITROPHENOLS
2r4-DlNlTROPriENOL
4r4»-OIPHENYLBIPHENYL
BENZ(C)ACRIOINE
T
T
T
T
T
T
T
T
T
T
T
T
T
r
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
8.90E
8.90E
6.90E
6.90E
8.90E
8.90E
8.9o£
tt.90t
6.90E
8.90E
8.90E
6.80E
6.80E
6.80E
4.90E
4.90E
4.9ot
3.00E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.6oE
3.60E
4.90E
4.90E
4.90E
4.90E
4.90E
6. SOL
3.60E
04
04
04
04
04
04
04
0<4
oa
04
04
05
05
05
05
05
05
05
06
06
06
06
06
06
06
06
06
05
05
05
05
05
05
06
4.04E
4.04E
4.04E
U.04E
4.04E
4.04E
4.04t
4.04t
4.04E
4.04E
4.04E
3.ao£
3.60t
3.BOt
3.eot
3.80E
3.80E
3.70E
3.60t
3.60E
3.60t
3.60E
3.60t
3.60t
3.60E
3.60E
3.60E
3.50h
3.50E
3.50E
3.50E
3.50t
3.40E
3.30E
02
02
o2
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
o<;
02
02
02
02
02
02
02
02
02
2.40E
2.40E
2.40t
2.40E
2.40E
2.40E
2.40E
2.40E
2.aOt
2.40L
2.40E
2.22E
2.22t
2.22t
2.22E
2.22t
2.22E
2.20C
2.12E
2.12t
2. 12t
2.12E
2.12t
2.12E
d . I2t
2.12E
2. 12t
2. lot
2. lOt
2.10E
2. lOt
2. 10t
2.00fc
1.93E
05
05
05
05
05
05
05
05
05
05
05
05
o5
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
2
2
2
2
2
2
2
2
2
2
2
3
3
3
5
5
5
7
6
6
6
6
6
6
6
6
6
5
5
5
5
5
3
6
1
— 1
-------
PI
CD
DMEG NO,
PRODUCT GAS PARTICULATE, HEALTH IMPACT
COMPOUND NAME
TYPE CONC
E-6 G/3CM
OS
W03
G/S
LCCAT
17
17
17
17
17
17
17
17
21
Ott
08
08
08
07
18
18
18
18
18
18
18
17
17
17
17
17
17
21
08
04
04
04
18
23
A
A
A
A
A
A
A
A
b
A
A
A
A
8
A
A
A
A
C
D
A
A
A
B
A
084*
085*
083*
066*
081*
062*
060*
060*
120*
123*
120*
121*
122*
100*
143*
141*
144*
146*
142*
145*
140*
066*
085*
083*
084*
082*
081*
160*
080*
050*
060*
040*
060*
020*
P
P
w
P
w
w
P
P
P
H
N
W
*
2f«-DiNlTROTOl.UENE
2»S-DINITROTOLUENE
2»3-DlNlTROTOLUENE
3,S-DlNITROTOLUENfc
2»6-DINITROTOLUENE
S»4-OINITKUTOLUEN£
OINITROTOLUENE3
4-NITROBIPHENYL
CHRYSENE
3TEARU AC1U
SATURATED LONG CHAIN ACIDS (MKI22B-265)
MYKI8UC ACID
PALMITIC ACID
CAMPHOR
2r5-XYLENOL
2»3-XYLENOL
2rb-XYLENOL
3»«-XYLENOL
2rtt-XYLENOL
3,5-XYLENOL
XYLtNOLS
3»S-DINITROTOLUEN£
2rS-DJNITROTOLUENE
2»3-DINITROTOLUENE
2r«-OINITKOTOLUENE
3f«-D!NITROTOLUENE
2,6-DlNITROTOLUENE
PICENE
METHYL METHACRYLATE
EPICHLORHYDRIN
1-CHLORO-1,3-EPOXYPROPANE
2-CHLORO-1,2-EPOXYPKOPANE
1 / «»
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
r
4
4
4
4
4
•
•
•
•
•
90E
90E
90E
90E
90E
4.90E
4
4
6
3
3
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
•
•
•
•
•
•
•
•
•
•
•
•
90E
10E
60E
OOE
OOE
OOE
OOE
60E
60E
60E
60E
bOE
• 60E
.60E
•
•
•
•
•
•
•
6.
3
.
4.
60E
10E
1UE
10E
10E
10E
10E
BOE
60E
90E
4.90E
H.9UE
44
,(
JOt
J.ftOf
OS
05
OS
05
05
05
05
05
05
05
05
05
05
06
06
06
06
06
06
06
06
05
05
05
05
05
OS
05
06
OS
OS
OS
OS
06
3
3
3
3
3
3
3
3
3
3
3
3
3
3
.30E
.30E
.30E
.30E
.30E
.30E
.30E
.20E
.10E
.OOE
.OOE
.OOE
.OOE
.OOE
2.60E
2.60b
2
2
2
.60E
.60E
.60E
2.60E
2
2
2
2
2
2
2
2
2
.60E
.73E
.73E
.73E
.73E
.73E
.73k
.726
.60E
2.50E
2.50k
2.bO£
*.»0£
i»
*0ff
02 1.
02 1.
02 1*
02 1.
02 1.
02 1.
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
•
•
.
•
•
.
.
•
•
•
•
V2E
92E
926
92k
92E
92k
92E
90k
82k
606
60k
60k
60E
60k
63k
63k
63k
.63k
•
•
•
•
•
•
•
•
•
•
•
.
•
63E
63k
63k
61k
61E
61E
61k
61k
61E
60k
SU
44k
44t
.44£
t^
01 l.<
f»4£
tj*
OS
OS
05
OS
05
OS
OS
OS
OS
05
05
05
Ob
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
OS
OS
OS
5
5
5
5
5
5
b
4
3
7
7
7
7
4
4
4
4
4
4
3
6
5
i
S
s
6
-------
PRODUCT GAS PARTICULATE, HEALTH IMPACT
UMEG NO.
COMPOUND NAME
TYPE CUNC
t-t>
US
LCCAT
b/S
21
23
23
20
23
02
04
04
04
12
23
23
23
23
23
23
05
23
10
16
49
21
23
16
20
02
02
09
16
23
19
16
06
19
C
B
B
A
b
d
A
A
A
A
A
A
A
A
A
A
8
A
C
A
A
D
C
B
A
A
A
A
A
B
6
A
A
B
I2u*
020*
022*
060* P
021*
120* P
050* rf
040* M
060* W
060* P
141*
144*
143*
142*
140*
145*
1 oO* w
146*
020*
020* P
010 P
020*
020*
020*
040*
360* W
160* P
120* Ml
100*
2oO*
022* P
102*
060*
023*
BENZOCEJPYRENE
QUINOLINES
ISOQUINOLINE
4-NITROPHENOL
QUINOLINE
HEXACMLOfiObUTADlENE
EP1CHLORHY0RIN
2-CHLURO-l,2-£POXY PROPANE
l-ChLORO-l/3-EPOXYPROPANE
N-NITROSUUI PROP YL AMI N£
2, 3-DIMETHYLPYRID1NE
2/6-UIMETHYLPYRIDlNt
2r 5-DIMETHYLPYRIOINE
2,4-OIMETHYLPYRIDlNt
DISU8STITUTEU POLYSUBSTI TUT£l> ALKYL PYRIUlNES
3,4-DlMETHYLPYRIDlNE
1-PHENYLETHANOL
2r3,4,6-TETRAMETHYL PYRIDINE
ANILINE
PHENOL
ARSENIC
DIBENZO(A,H)PYRENE
PYRROLE
CATECHOL
3-NITROPHENOL
HEXACHLOROCYCLOHEXANE
BROMOFORM
TETRAMETHYLSUCCINONITRILE
PHENYLHrlENGLS
DIt)ENZ(C,H)ACRIDIN£
CHLURINATED-M-CRESOLS
P-PHENYLPHENOL
VALERiC ALIU
CHLORINATED-P-CRE50LS
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
0
T
T
T
T
T
T
T
T
T
T
T
T
T
o.60t
3.60E
3.60E
3.60E
3.60E
b.70t
4. lot
4.10E
4.10E
4.9Ut
3.60E
3.60E
3.60E
3.60E
3.60L
3.60E
3.60E
3.60t
3.60E
3.60E
3.70E
6.80E
4.9UE
3.60E
3.60E
6.90E
a.yot
4.90E
3.60fc
3.6o£
3.60E
3.60t
3.60E
3.60E
05
06
06
Oo
06
05
05
05
05
05
06
06
06
06
06
06
06
06
06
06
02
05
05
06
06
04
05
05
06
06
06
00
06
06
2.30-
2.30E
2.30E
2.3uE
2.3ut
2.12t
2.10E
2. lot
2.lOt
2.04t
2.00E
2. wOE
2. WOE
2.00E
2,uOt
2.00E
2.00E
2.00E
l.VOE
1.90E
1.90E
1.63E
l.tflt
i.eot
1 .SOt
l.OOE
1.74E
1.63E
1.60E
1.6Ut
1.60E
1.60E
1.60E
1.60E
02
02
02
02
02
W2
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
1.33t
1.32E
1.32t
1.32E
1.32t
1 .30t
1.20t
1.20E
1.20t
1.20t
1.20E
1.20t
1.20E
1.20E
1.20E
1.20E
1.20t
1.20E
l.llt
l.llt
l.lOt
1.10E
1.10E
l.lOt
l.lOt
l.iOt
1.02t
9.63t
9.23E
9.23t
V.23E
9.23E
9.23E
9.23E
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
04
04
04
04
04
04
04
3
6
6
6
6
1
4
4
4
5
6
O
6
6
6
6
6
6
6
6
3
5
b
6
2
1
5
6
6
6
b
6
6
-------
I
I—1
o
PRODUCT GAS PART1CULATE, HEALTH IMPACT
DMEG
19
IB
19
IB
23
16
Id
18
18
06
08
10
07
10
10
10
10
10
10
10
10
03
03
16
83
19
08
23
U3
03
08
18
22
23
B
A
B
A
C
A
A
A
A
A
A
C
B
C
C
C
A
C
C
D
C
b
B
B
A
A
C
D
6
B
A
A
C
0
NO.
021*
103*
020* W
101*
020*
162*
161*
163*
160*
140*
040*
Obi*
080* P
062*
Ob4*
063*
080*
065*
066*
020* W
060*
020* W
04G* rt
020* k
010 P
020* P
020*
020* W
020* W
040* W
060*
060*
040*
040*
COMPOUND NAME
CHLORINATED-0-CRESOLS
M-PHENYLPMENOL
CHLORINATED CRESOLS
0-PHENYLPHENOL
PYRROLE
4-ETHYL-O-CRESOL
6-ETHYL-M-CRESOL
2-ETHYL-P-CRESOL
ETHYL CRESOLS
OLEIC ACID
ACETIC ACID
2,3-XYLIDlNE
ISUHHORUNE
2»4-XYLIDlNE
2,6-XYLIDlNE
2f5-XYLIDINE
1,2-DIAMINOETHANE
3,4-XYLIDlNE
3»5-XYLlDlNE
N,N-OIMETHYL ANILINE
DIMtTHYLAMLlNES
1,4-DIOXANE
1»3-DIOXAN£
A-CHLUROTOLUENE
MERCUKY
2-CMLOROPHENOL
FOKMAM1DE
BEN20THIAZOLE
1,4-DIGXANE
1,3-OlGXANE
MALEIC ACID
2-MfcTHOXYPHENOL
BENZO(J)FLUORANTHENE
METHYL BtWZOTHJAZULfc
TYPE CONC OS
E-6 6/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
r
3.60E
3.60E
3.6VE
3.60E
4.10E
3.60E
3.60E
3.6Ut
3. 6Ut
4.90E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3. but
4.90E
4.90E
6.8ut
6.50E
3.bOE
3.60E
4.90E
4.10E
4.10E
3.60E
3.60E
b.80£
4.90C
06
06
06
06
05
06
06
06
06
05
06
06
06
06
06
.60E
.60E
.60E
.60E
.51E
.50E
.50E
.but
.50E
.50E
.44E
.44E
.44E
.44b
.44E
06 1.44E
06 1.44E
06 1.44E
06 1.44E
06 1.44E
06 1.44E
05 1.40b
05 1.40E
05 1.40t
03 1.30E
06 1.40E
06 1.20E
05 1.13E
05 1.13E
05 1.13E
06 1.12E
06 1.1UE
05 1.04E
05 l.U4t
02
02
02
02
02
02
U2
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
WD3
G/S
9.23E
9.23E
9.23fc
9.23t
9.00E
8.90E
6.90E
b.9ot
8.90E
e.eot
b.50t
6. SOt
o.bot
B.50E
8.50t
6.50t
b.bOt
e.sot
8. SOt
8.50E
8.50E
8.03t
8.03t
b.02E
7.70E
7. lot
7. 10E
6.72L
6.7lc
6.7lt
6.63E
6.5lt
b.20t
b.^Ot
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
U<4
04
04
04
04
04
U4
04
04
04
04
04
04
LCCAT
6
6
6
6
4
6
6
6
b
b
b
b
b
b
b
b
b
b
b
b
b
5
5
3
b
o
5
4
4
b
b
3
b
-------
PRODUCT GAS PARTICULATE, HEALTH IMPACT
DM
18
10
16
10
10
06
10
16
16
16
16
17
06
08
08
06
08
12
06
10
06
15
66
07
02
08
08
08
08
06
23
23
23
23
EG
A
A
b
A
A
B
A
6
B
B
B
A
D
D
D
0
0
A
A
A
B
A
A
B
A
A
A
A
A
A
A
A
A
A
NO.
120*
123*
080*
122*
121*
080*
120*
0<41*
040*
042*
043*
020* P
283*
260* P W
282*
281*
300* P
080*
140*
160*
041*
160* W
010 P
120*
320* P
100*
103*
101*
104*
102*
101*
102*
103*
100* W
COMPOUND NAME
2r 2'-DIHYDROXYDIPHENYL
l-AMINO-2-PROPANOL
1,2,3-TRIHYDROXYbENZENE
3-AMINO-1-PROPANUL
2-AMINU-1-PHOPANOL
Y-BUTYRULACTONE
PROPANOLAMINES
l,2-BIS(CHLOROMETHYBENZENt
BIS (CHLOROMETh YD BENZENES
If S-BISCCHLOROMETHYL) BENZENE
1,4-BIS(CHLOROMETHYL) BENZENE
NITROBENZENE
DI-N-BUTYL PHTHALATt
PHTHALATE ESTERS (M*:l94-279)
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
Ul-2-ETHYLHEXYL PHTHALATE
N-NITROSOOIISOPROPYLAMINE
OLtIC ACID
CYCLOHEXYLAMINE
2-HYDkOXYBENZOIC ACID
BIPHENYL
CHROMIUM
ACtTOPHENONE
HtXACHLOROETHANE
SATURATED LONG CHAIN ACIDS (MW:llb-201)
CAPRIC ACID
CAPROIC ACID
LAURIC ACID
CAPRYLIC ACID
2-CHLUROPYRIDINE
3-CHLOROPYRIDINE
4-CHLOROPYRIDINE
CHLOROPYRIDlNtS
TYPE CONC
E-6 G/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
3.60E
3.60t
3.60E
3.60E
3.60E
3.60E
3.60E
6.60E
6.80E
6.80t
6.80t
4.90E
4.90E
4.90E
4.90E
4.90h
4.90E
3.60E
3.00E
3.60E
3.60E
8.90E
6.80E
3.6UE
8.70E
4.90E
4.90E
4.90E
4.90E
4.90E
4.9ut
4.90E
4.90E
4.90E
06
06
Go
06
06
06
06
Ob
Ob
Ob
Ob
05
Ob
Ob
Ob
05
Ob
06
Ob
06
06
04
01
06
05
05
05
05
Ob
Ob
05
05
05
05
US
1.02E
1.UOE
1 .OOc
l.OOE
l.OOE
l.OOE
l.OOE
9.90E
9.90E
9.90E
9.90E
9.80E
9.80t
9.60E
9.60E
9.60£
9.60E
9.50t
9. lOt
9.00E
9.UOE
6.VOE
8.60t
8.ttOE
e.70t
8.44E
6.44£
6.44E
8.44E
6.44E
8.3UE
8.30t
6.30t
6.30E
02
U2
02
U2
02
02
02
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
NDS
b/S
6.10E
5.VOt
5.90E
5.90E
5.90E
5.90E
5.90E
5. Bit
5.61E
b.81t
5.61E
b.60t
5.80t
b.60£
5.80E
5.60t
5.60t
b.60t
b.4o£
5.3l£
5.3l£
5.30E
5.«!UE
5.20£
5.13t
b.OOt
b.OOt
b.OOt
5.00E
5.00£
4.VOH
4.VOE
A.90t
4.90t
04
04
04
04
04
04
U4
04
04
04
04
04
04
04
04
04
04
04
04
04
04
U4
04
OH
OH
04
04
04
04
04
04
04
04
04
LCCAT
b
6
6
6
6
6
6
3
3
3
3
5
5
5
b
5
5
6
7
6
6
2
6
1
b
5
5
5
5
5
5
5
5
re
i
-------
I
t-1
Ni
PRODUCT GAS PARTICIPATE, HEALTH IMPACT
UMEG
17
10
23
21
05
IB
02
02
02
15
15
15
15
54
19
23
23
23
23
21
23
21
23
23
23
23
23
23
23
05
23
23
02
20
A
A
C
D
C
B
B
d
ti
B
B
B
ti
A
A
A
A
A
A
C
C
C
6
B
B
B
6
B
B
A
B
B
A
A
NO.
020* P
060*
180*
060*
040* W
040*
104*
103*
100* P
IbO*
Io3*
162*
161*
010 P
040* P
101*
100* W
103*
102*
060*
180*
080* P
062*
061*
063*
067*
060*
066*
040*
140* W
065*
064*
180*
020* P
COMPOUND NAME
NITROBENZENE
ETHANOLAHINE
DIBENZO(A,GKARBAZOLE
DItiENZO(A,L)PYRENE
T-PENTANOL
1 ,3-DIHYDROXYBENZENt
TRANS-1,3-DICHLOKOPHOPENE
CIS-1,3-DICHLOROPROPEN£
OICHLOKUPROPENES
FErtPHENYLS
P-TERPHENYL
M-TERPHENYL
0-TERPHENYL
SELENIUM
2»4-DICHLOROPHENOL
2-CHLOROPYHIOINE
CHLOROPYKIDINES
4-CHLOROPYRIOINE
3-CMLOROPYRIDINE
DIBENZC A, C) ANTHRACENE
DI6ENZO(A,G)CARBAZOLE
DIBENZC A, HJANTHKACENE
2,6-DlMETHYLOUINULINE
2r3-DlrtETHYLQUlNULINE
2r6-DIMETHYLQUINOLINE
1,5-DI METHYL ISOQUlNULlNE
DIMETHYLUUINOLINES
1,3-DIMETHYLISOQUlNOLlNE
2-METHYLWUINOLINE
BENZYL ALCOHOL
6,8-DIMETMYLOUINOLINE
3»4-DIMETHYLOUlNOLIN£
DIbHOMOOICHLOROMETHANE
2-NITR0PHENOL
TYPE CONC OS
£•6 G/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
0
. T
T
T
T
T
T
T
0
T
T
T
T
T
T
T
T
T
T
T
T
4.10E
4.90E
4.90E
6.90E
3.60E
3.60E
6. TOE
a. TOE
8. TOE
6.60E
6.80E
6.80E
6.80E
l.SOE
4.90E
4.10E
4.10E
4.10E
4.10E
6.60E
4.10E
6.1UE
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
3.60E
6.90t
3,60£
OS 8.20E
05 8.20E
OS 8.20E
04 6.10E
06 8.00E
06 8.00E
05 7.90E
05 7.VOE
05 7.90E
05 7.60E
05 7.60E
05 7.60E
05 7.60E
04 7.50E
05 7.00E
05 6.94E
05
05
05
05
Ob
00
06
06
06
06
06
06
06
06
06
06
04
.94E
.V4t
.V4E
.90E
.b3t
.60t
.b4E
.54E
.5
S
2
6
6
1
1
1
3
3
3
3
5
4
4
4
4
3
4
3
6
6
6
6
6
6
6
6
6
6
2
6
-------
PRODUCT GAS PARTICULAR, HEALTH IMPACT
DM
18
18
16
18
06
16
16
16
22
22
21
23
as
23
25
23
23
23
23
23
23
23
23
08
08
08
08
08
10
06
21
21
21
18
EG
A
A
A
A
D
A
A
A
D
C
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
D
6
6
B
A
NO.
161*
itto*
163*
182*
160*
161*
160* P
162*
020* P W
020* P
180* P M
083*
120*
061*
121*
062*
082*
080*
061*
060*
063*
064*
122*
104*
100*
102*
101*
103*
100*
200*
140*
1«1*
142*
043*
COMPOUND NAME
2r4,6-TRJMETHYL METHYL PHtNOL
POLYALKYLPHENOLS (Mrt>135)
2.6-DIMETHYL-4-HEPTYL PHENOL
4,6-DI-TEKT-BUTYL-M-CRESOL
MtTHYL BENZOATE
1,2,4-TRICHLORUBENZtNE
PULYCHLORINATED BENZENES
HEXALHLORUBENZENt
INDENu(l,2,3-CO)PYRtNE
6£NZG(K)FLUORANTHENt
PHENANTHRENE
4-PHENYLPYRIDINE
COtLIOINtS
2-PHENYLPYRIDINE
5-ETHYL-2-METHYLPYHIDINE
3-ETHYLPYRiiJlNE
3-PHENYLPYRIDINE
PMtNYLPYRIDlNES
2-ETHYLPYRIOINE
MONOSUBSTITOTED ALKYL PYRIDINES
4-tTHYLPYRIOlNE
4-N-PROPYLPYRIDINE
2,4,6-COLLlOINE
LAURIC ACID
SAIURATEU LONG CHAIN ACIDS (Mrt:116-20U
CAPRYLIC ACID
CAPROIC ACIO
CAPHIC ACID
MOKHHOLINE
DIETHYL AUIPATE
METHYL CHHYSENES
4-METHYL CHRYSENE
S-METHYL CHHYSENE
P-CRESGL
TYPE CONC
E-o b/SC*
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
3.60E
3.60t
3.60E
3.60E
3.60f.
o.BOt
6.60E
6.80t
8.90E
6.Vu£
6.90E
3.60E
3.6ut
3.60E
3.6uE
3.60E
3.60E
3.6UE
3.6Ut
3.60t
3.60E
i.6o£
3.60E
3.00E
3.00E
3.00t
3.00E
3.00t
3.6UE
3.60E
8.90E
6.90E
6.90E
4.90L
Oo
06
Ob
Oo
06
05
Ob
Ob
04
04
04
Ob
06
06
06
Ob
06
06
06
06
Oo
06
06
05
Ob
05
05
05
06
Ofe
04
04
04
05
US
6. 10E
to. lOt
6.10£
6. lot
5.90E
b.70E
5.70E
b./Ot
5.60E
5.60E
5.00E
b.eJIE
b.2lt
b.dlt
5.21E
b.2lt
b.«!lE
5.«!lt
5.21E
5.21E
b.2lt
5.2lt
5.21E
5.20E
5.0t
.i.bOt
3.bOc
3.34t
3.34t
3.34t
3.30L
3.3ot
3.30E
3. lot
3. lOt
3. lOt
3. lOt
3. lOt
3. lOt
i.lot
3. lOt
3. lOt
3. lot
3. lot
3. lOt
3. lOc
3. lOt
3. lOt
3. lOt
3. lot
3.03E
3.00t
2.91t
2.VU
2.9U
2.90t
04
04
U4
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
U4
04
04
04
04
04
04
04
U4
04
04
04
04
LCCAT
o
b
o
6
6
3
3
3
2
2
2
6
6
6
6
6
6
6
6
6
b
6
b
7
7
7
7
7
6
6
2
2
2
5
I
I--
UJ
-------
PI
PRODUCT GAS PARTICIPATE, HEALTH IMPACT
OMEG NO.
COMPOUND NAME
TYPE CONC US
E-6 G/SCM
LCCAT
18
18
18
06
18
18
18
18
07
07
07
12
04
23
23
04
15
05
21
07
23
21
13
05
23
23
23
23
21
16
16
16
16
Id
A
A
A
A
A
A
A
A
B
B
B
A
A
C
B
8
6
A
C
B
C
8
B
d
b
B
6
6
b
A
A
A
A
A
083*
041*
040* W
020* ri
080* W
081*
042*
082*
180*
182*
161*
100*
140* P
040*
200*
100*
ObO* *
160*
040*
100* M
140*
120* P
080*
120*
IbO*
120*
080*
140*
040* P
143*
142* P
141*
145*
140*
P-ETHYLPHENOL
M-CRESOL
CRESOLS
ETHYLENE GLYCOL
ETHYLPHENOLS
U-ETHYLPHENOL
0-CRESOL
M-tTHYLPHENGL
CAPVONES
DIHYl>RO-(D OR DCArtVQNE
CARVONE(D OR L)
N-MTKOSGOIPENTYLAMINE
2-CHLOROETHYL VINYL ETHER
INUOLE
BE'MZ(C)ACRIUINE
2»2'-OICHLORODIISOPROPYL ETHER
4,4'-i)IPHENYLbIPHEnYL
PHtNETHYL ALCOHOL
BENZO(G)CHRYSENE
CAMPHOR
UIBENZO(A,I)CARBAZOLE
CHRYSEfxE
MtTHYL OISULFIDE
BORNEUL
BENZO(H)UUINOLINt
PHENANTHRIDINE
ACRIU1NE
B£NZO(F)UUINOLINE
BENZ(A)ANTH*ACENE
2,5-XYLENOL
2,4-XYLENOL
2,5-XYLENOL
3fb-XYLENGL
XYLENOLS
\
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
U
T
T
T
T
T
4.90E
4.90t
4.9UE
4.90E
4.90E
4.90E
4.90E
4.90E
3.60E
3.60E
3.60E
3.60E
4.90E
4.90E
4.90E
4,90t
6.90E
.S.bOt
6. HUE
4.9UE
4.90E
6.90E
3.60t
3.60E
3.60E
3.60E
3.60E
3.60t
1.70t
4.90E
4.90E
4.90E
4.90E
4.90t
05
05
05
05
05
05
Ot>
05
Ob
Ob
Ob
Ob
05
05
05
05
04
Ob
Ob
05
05
04
Ob
Ob
Ob
Ob
Oo
Ob
03
05
05
05
05
05
4 90E
4.90E
4.90E
4.VOE
4.90E
4.90E
4. VOt
4.90E
4.90E
4.VOE
4.90E
4.bOt
4.50E
4.50E
4.50E
4.50E
4.50E
4.44t
4.30E
4.10E
4.10t
4.04t
4.UOt
4.00E
4.00E
4.00E
4.00E
4.00E
3.80E
3.60E
3.80E
.S.tiOt
3.80t
3.00t
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
2.VOE
2. VOt
2.^oE
2.90t
2.9ut
2.90t
2.90t
2.VOE
2.90E
2.VOE
2.90E
2.7ot
2.o2t
2.o2t
2.fa2t
2.b2t
2.b2t
2.b2t
2. but
2.40E
2.40t
2.40t
2.4ot
2.40E
2.40E
2.40t
«!.40t
2.<40t
2.ci2t
2.22t
2.22t
2.22E
2.22t
2.2lt
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
OM
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
5
5
5
5
5
5
5
5
b
b
b
b
5
b
b
b
2
b
3
b
b
!>
b
b
b
b
b
b
3
b
b
b
5
5
-------
PRODUCT GAS PARTICULATE, HtALTH IMPACT
DMEG
16
18
13
04
23
04
21
06
23
72
18
23
48
23
23
20
23
16
21
01
23
23
23
23
23
23
23
23
05
62
18
23
10
06
A
A
B
B
C
A
C
0
C
A
C
A
A
b
B
A
B
C
C
B
A
A
A
A
A
A
A
A
d
A
A
C
C
0
NO.
146*
144*
060*
100*
040*
140* P
160*
080*
140*
010
040* W
020*
010
021*
020*
060* P
022*
020*
120*
220 W
020*
143*
140*
144*
145*
141*
142*
146*
100* W
010 P
020* P
120*
020*
320* P
COMPOUND NAME
3,4-XYLENUL
2f6-XYLENOL
DIPHENYL SULFIDE
2,2'-DICHLORODIISOPKOPYL ETHER
INOOLF.
2-CHLOROETHYL VINYL ETHER
P1CENE
METHYL METHACRYLATE
DIBENZO(A,I)CARBAZOLE
IRON (AS FE+2)
2-NAPHTHOL
PYKIOINE
PHOSPHORUS
QUINOLINE
OUINOLINES
4-NITROPHENOL
ISOUUINOLINE
1-NAPHTHOL
BENZO(E)PYWENE
DICYCLOPENTAOIENE
PYRIDINE
2,5-DIMETHYLPYRIOINt
DIS08STITUTED POLYSUflSTITUTED ALKYL PYKID1NES
2,6-UiM£THYLPYRIQi.Nt
3,4-DlMETMYLPYRIDlNE
2, 3-DIMETHYLPYHIDINE
2, a-OIMETHYLPYRIDINE
2/3,4,6-TETHAMETriYL PYRIDINE
1-HHENYLETHANOL
CADMIUM
PHENOL
BENZO(A)CAkBAZOLE
ANILINE
BUTYL BENZYL PHTHALATE
TYPE CONC
E-6 G/SCM
T
T
T
T
T
T
T
T
T
D
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
4.90E
4.90E
3.60E
4.10E
4. lot
4. IOE
6.90E
4.90E
4. IOE
< 3.30E
3.60E
4.90E
> 3.20E
4.9ot
4.90E
4.90E
4.90E
3.60t
b.90E
8./OE
4. IOE
4.90E
4.90E
4.9UE
4.9ot
4.90E
4.9Ut
4.9UE
4.90E
05
05
05
05
06
04
05
05
05
05
05
05
05
05
05
OS
02
Ob
05
05
Ob
DS
3. out
3.80E
3.80E
3.72E
3.72E
3.72c
3.60E
j. iOE
3.41E
3.30t
3.30t
3.30E
3.*OE
3.10E
3. IOE
3. IOE
3. lOt
3.00E
3.00E
2.90t
2.73E
2.72t
2./2E
2.72E
2.72t
2.72E
2.72E
tL, 72t
2.72t
2.70E
2.bOt
2.bOE
2.bOE
2.60E
01
01
01
01
(,\
01
01
01
01
ui<
01
01
01>
01
01
01
01
01
01
01
01
01
ol
01
01
01
01
01
01
01
01
01
01
01
WDS
G/b
2.22E
2.22E
2.21E
2.20E
2.20t
2.20t
2. IOE
2. 10c
2.01E
l.V4t
1.V3E
1 .92t
l.Voc
1.80t
l.ttOE
l.eot
l.ttoE
l.bOt
l.eot
l.Mt
1.61E
l.bOt
1.60E
l.bUc
l.bOt
l.bOt
1.60t
l.but
1.60E
1.60t
1.52E
1 . bdt
1.52E
l.blt
04
04
04
U4
04
04
04
04
04
04
04
U4
04
04
04
04
04
04
04
04
04
U4
04
U4
04
04
04
04
04
04
04
04
04
04
LCCAT
5
5
6
a
4
4
d
5
4
6
5
5
5
5
5
6
i.
1
4
b
5
b
5
b
5
5
b
5
5
b
b
w
I
-------
OMEG NO.
PRODUCT GAS PARTICULATE, HEALTH IMPACT
COMPOUND NAME
TYPE CONC US
t-b &/SCM
LCCAT
ws
06
18
20
21
16
18
16
05
16
05
23
23
23
23
23
23
23
05
06
09
02
23
25
25
18
23
19
18
19
19
25
23
09
16
A
B
A
D
C
C
c
A
C
A
A
A
A
A
A
A
A
B
A
A
b
C
A
A
A
C
6
A
6
6
A
C
A
A
IbO*
020*
040*
020*
082*
083*
080*
080*
061*
100*
140*
141*
144*
142*
14b*
143*
145*
080*
180*
100*
120* P
120*
040*
041*
103*
102*
020* rt
101*
023*
022* P
042*
100*
060*
102*
BtNZUlC ACID
CATfcCHOL
3-NITROPHENUL
DIBENZO(A,H)PYRENE
4-INOANOL
5-INDANOL
INOANULS
N-BUTANUL
1-1NDANOL
ISUbUTYL ALCOHOL
D1SUBSTITUTED POLYSUBSTITUTED ALKYL PYRIUINES
2,3-OIMETrtYLPYRIOlNt
2fb-i)Irt£TMYLPYRIOlNt
2,4-DIMETriYLPYRIDINt
2»3,4,b-TETRAMETHYL PYRIDINE
2f 5-UIMETHYLPYWIDINt
3,4-DIMETHYLPYRIDlNt
2fb-OlMETHYL-4-HEPTANOL
AD1P1C ACIO
1,3-DICYANO-1-HYDROXYBUUNE
HEXACHLOROBUTADIENE
BENZO(A)CARBAZOLt
METHYLTHIOPHENES
2-METHYLThIOPH£NE
M-PHENYLPHtNOL
9-METHYLCARBAZOLt
CHLORINATED CRESOLS
O-PHENYLPHENOL
CHLOR1NATED-P-CRESOLS
CHLOKINATED-M-CRESOLS
3-METHYLTHIUPHENE
METHYLCARBAZOLES
BUTyRONITKJLE
P-PH£NyLPH£N0L
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
r
3.bOE
4.90E
4.VOE
0.9uE
3.bOE
3.bOt
3. but
3. but
3. 6Ut
3.60E
4. lOt
4. lot
4. lOt
4. lot
4. lOt
4.10E
4.10E
3. bUt
3,bO£
4.90E
6.90E
4.10E
4.90E
4.90E
4.90E
4.90E
4.90E
4.90E
4.90t
4.90E
4.90E
4.90E
4.90E
4.90t
Ob
05
05
04
Ob
Ob
Ob
Ob
Ob
Ob
05
05
OS
05
05
05
05
Ob
Ob
05
04
05
05
05
05
OS
05
05
05
05
05
05
05
05
2.oOt
2.50E
2.50t
2.40E
2.40t
2.40E
2.40E
2.40E
2.40t
2.MOE
2.30t
2.3oE
2..SOE
2.30E
2.30E
2.30E
2.30E
2.30E
2.30E
2.22E
2.20t
2.20t
2.13E
2.13E
2.13E
2.13E
2.13E
2.13t
2.13E
2.13E
2.13E
2. lit
2.UE
2tiJE
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
1.51E
1.44C
1.44E
1.41t
1.41t
1.41t
i.41t
1.41t
1.41t
1.41t
1.34E
1.34t
1.34L
1 ,34t
1.34t
1.34t
1.34£
1 .32t
1.32t
1.3lt
1.30t
1.30t
i.30t
1.30t
1.30t
l.iofc
1.30t
1.30L
1.30t
1 .30t
1.30E
1.30E
1.30t
1«30£
04
04
04
04
04
04
04
04
04
04
04
04
U4
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
b
5
5
2
b
b
b
b
b
b
4
4
4
H
4
4
4
b
b
5
2
4
5
5
5
5
5
b
5
5
5
5
5
5
-------
PRODUCT l»AS PARTICIPATE, MtALTH IHPACT
OME& NO.
COMPOUND NAME
TYPE CONC US
E-b b/SCM
LCCAT
WS
23
23
18
19
i»6
23
25
lb
18
18
18
06
10
10
07
10
10
10
10
10
10
10
02
05
25
25
25
25
25
09
04
04
23
23
C
B
A
b
A
C
b
A
A
A
A
A
C
A
B
D
C
C
C
C
C
C
A
C
A
A
A
A
A
A
A
A
C
C
i
| _i
---J
101*
260*
100*
021*
080*
080*
040*
162*
Ib3*
161*
160*
040*
064*
060*
080* P
020*
005*
063*
060*
062*
061*
06t>*
140* P
060*
060*
064*
063*
Ob2*
061*
100*
180* P
200*
101*
102*
3-nETHYLCARbAZULE
D18ENZ(C,H)ACKIDINE
PHENYLPHENOLS
CHLORINATED-O-CRESOLS
VALERIC ACID
CAR8AZOLE
M BENZO(6)THIOPHENt
4-ETHYL-O-CRESOL
2-tTHYL-P-CRESOL
6-tTHYL-M-CRESOL
ETHYL CRESOLS
ACETIC ACID
2, 6-XYLIDINE
1,2-UIAMlNOtTHANE
ISOPHORONE
M Nf N-DIMETHYLANILINE
3* 4-XYLIDINE
2/5-XYLIOINE
UIMETHYLANILINES
2,4-XYLIDINt
2, 3-XYLIDINE
3,5-XYLIDlNE
DltiROMOCHLOROMETHANfc
A-TERPINEOL
DIMETHYLTH10PHENES
3f 4-DI METHYL TH I OPHENE
i, 5-DIMETHYLTHIOPHENE
2f4»DIMETHYLTHlOPrlENE
2/3-OlMETHYLTnIOPHENE
1,3-DICYANO-l-HYDROXYbUTANE
CHLOROPHENYL PHENYL ETHER
4-6ROMOPHENYL PHENYL ETHER
3-HETHYLCAKbAZOLt
9-METHYLCARbAZOLt
I
T
1
T
T
T
T
I
T
T
T
T
T
T
T
T
T
T
1
T
T
T
T
T
T
f
T
T
T
T
T
T
T
T
4.90E
4.90E
4.90E
4.9oE
4.91'E
4.9UE
4.9ut
4.90E
4.90E
4.90E
4.9ut
4.90t
4.9UE
4.90t
4.90E
4.90t
4.9Ut
4.90E
4.90t
4.90E
4.9ut
4.90E
b.70t
3.6UE
4.90E
4.9uE
4.90E
4.90t
4. VuE
4. lot
4.90E
4.90E
4. lot
4. lot
05
05
05
Ob
Ob
05
Ob
05
Ob
Ob
Ob
Ob
05
Ob
05
05
05
05
05
05
Ob
05
05
06
05
05
05
05
Ob
Ob
05
05
05
05
2.13E
2.13E
2.13E
2.13E
2.13t
2.13E
2.13t
2.04t
2.04E
2.04E
2.U4E
2.1/Ot
2. wo£
2.00E
2. WOE
2.00E
2. v/Ut
2.uOt
2.00E
2.uOt
2.00t
2.00t
1 .93t
l.vot
1 .90t
1.90E
l.VOt
1.90E
1 .S»0t
l.VOt
i.bit
i.bit
i.oot
1.60E
01
01
01
ui
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
Ul
01
01
01
01
01
01
01
01
01
01
01
01
1.30t
1.30E
1.30t
1.30t
1.30c
l.^Ot
1.30t
1.20E
1.20t
1.20E
i.iot
1.20t
1.20E
1.20t
1.20t
1.20E
1 ,20t
1.20t
1.2ot
1.20t
1.20t
1.20t
I.l4t
l.llt
l.llt
l.llt
l.llt
l.llt
l.llt
l.lOt
l.lot
l.lOt
1 .lot
l.lOt
04
04
04
U4
04
04
04
U4
04
04
04
04
04
04
04
04
04
04
04
04
U4
04
04
04
04
04
04
04
04
04
04
04
04
04
5
5
5
b
b
5
5
5
5
b
5
5
5
5
b
5
b
5
5
5
i
5
1
b
5
5
5
5
5
4
5
5
4
4
-------
M
I
PRODUCT CAS PARTICULATEr HEALTH IMPACT
OMEG NO.
COMPOUND NAME
TYPE CONC US
E-6 (i/SCM
LCCAT
u/s
23
25
23
09
25
25
02
16
25
25
04
17
17
17
04
19
17
06
25
25
25
25
25
02
02
09
09
06
09
09
36
04
04
^^
c
A
C
A
A
A
A
B
A
A
B
A
A
A
B
A
A
C
A
A
A
A
A
A
A
b
B
A
B
6
A
A
A
A
oeo*
041*
100*
oeo*
042*
040*
160* P
020* W
080*
081*
040* P
042*
040*
041*
ObO*
020* P
043*
020*
060*
063*
064*
062*
061*
361*
360*
042*
040* M
060*
041*
020* W
010
200*
160* P
010* W
CARBAZOLE
2-METHYLTHIOPHENE
METHYLCAKdAZOLES
BUTYRONITRILE
3-METHYLTHIOPHENE
METHYLTHIOPHENE5
BROMOFORM
A-CHLOROTOLUENE
TRIMETHYL AND TETRAMETHYL THIOPHENES
2»3,5-TRIMETHYLTHlOPHENE
Irl'-DICHLORODIETHYL ETHER
3-NITRUTOLUENE
NITROTOLUENES
2-NITROTOLUtNE
2, 2'-DICHLORODIETHYL ETHER
2-CHLOROPHENOL
4-NlT*OTOLUtNt
FORMAMIDE
OIMETHYLTHIOPHENES
2»5-DIMETHYLTHlOPH£NE
3r4-DlMETHYLTHIOPtl£NE
2r 4-D I METHYL ThIOPwENE
2»3-DIMETHYLTHlOPHEN£
1-BROMOBUTANE
BROMOBUTANES
B-NAPHTHON1TRILES
NAPHThUNITRILLS
MALEIC ACID
A-NAPHTHONITRILES
BENZQNITRILE
BAKlUM
4-8ROMOPHENYL PHENYL ETHER
CHLGROPHENYL PHENYL ETHER
INOENE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
It
T
T
T
4. lOt
4.10E
4. 10£
4.10E
4.10E
4.10E
8.90E
6.90E
4.90E
4.90E
4.90E
4.90E
4.90E
4.90E
4.90t
4.90E
4.90E
4.90E
4. lot
4.10E
4.10E
4. lOt
4. lOt
6.70E
b.70fe
4.90E
4.9UE
4.90t
4.90E
4.90E
7.60E
4.10E
4.10E
6.8UE
05
05
05
05
05
05
04
04
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
03
05
05
05
1.60E
1 .OOE
l.bot
l.bOE
1.60E
l.ttOt
l.OOh
i.eot
1.70E
1.70E
1.63E
1.0 it
1.63E
1.63E
1.63E
1.63E
1.63t
1.63E
l.bOt
1.60E
1.60t
1.60E
1.60E
l.oOt
1.60E
1.53E
1.53t
1.53E
1.53E
1.53E
1.52E
l.blt
1.51E
l.blt
01
01
Ul
01
Ul
Ul
01
01
Ul
Ul
Ul
01
01
01
01
01
Ul
01
01
01
01
Ul
Ul
Ul
Ul
01
01
Ul
01
01
01
01
01
01
I. lOt
l.lOt
l.lOt
1.1 lit
l.lOt
l.lOt
l.lOt
l.lOt
l.OOt
l.OOt
9.t>3t
9.63E
9.63t
9.63t
9.o3t
9.63t
9.63C
9.63E
9.30E
9.3UE
9.30t
9.30E
9.3ut
9.20t
9.20t
9.U3t
9.03t
9.03t
9.03t
9.03t
9.00L
9.00t
9.00E
d.9lfc
04
04
04
04
U4
U4
04
U4
04
U4
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
U3
03
03
03
03
03
03
03
03
4
4
4
4
4
4
-------
PRODUCT GAS PARTICULAR HEALTH IMPACT
DMEG NO.
COMPOUND NAME
TYPE CONC US
E-6 G/SCM
LCCAT
G/S
18 A 060*
08 D 240*
25 A 081*
25 A OCO*
18 A 120*
22 C 040*
04 B 040* P
17 A 042*
17 A 043*
17 A 040*
17 A 041*
04 B 080*
18 B 080*
10 A 122*
10 A 121*
08 b 080*
10 A 120*
10 A 123*
21 A 020* P
08 A 080*
16 B 041*
16 b 042*
16 B 040*
16 8 043*
12 A 080*
09 b 040* W
09 6 041*
09 6 042*
10 A 160*
08 8 041*
21 A 140* P
08 A 040*
07 8 120*
79 A 010 P
2-METHOXYPHENOL ,
DI-2-ETHYL6UTYL ADIPATE
2,3,5-TRIrttTHYLTHIOPHENE
TRIMETHYL AND TETRAM£THYL THIOPHENES
2» 2'-DIHYDROXYDIPHENYL
BENZO(J) FLUOR ANTHENE
If I'-DlCHLORODIEThYL ETHER
3-NITROTOLUENE
4-NITROTOLUENE
NITROTOLUENES
2-NITROTOLUENE
2, 2'-DICHLORODIETHYL ETHER
I, 2,3-TRIHYOROXYBENZENE
3-AMINO-1-PROPANOL
2-AMINO-l-PROPANOL
Y-BUTYROLACTONE
PROPANOLAMINES
1-AMINO-2-PROPANOL
NAPHTHALENE
VALERIC ACID
l,2-BIS(CHLOROMETHYb£NZENE
1,3-BIS(CHLOROMETHYL) BENZENE
BIS(CHLOROMETH YD BENZENES
1,4-BIS(CHLOROMETHYL) BENZENE
N-NITROSODIISOPROPYLAM1NE
NAPHTHONITRILES
A-NAPHTHONITRILES
B-NAPHTHONITR1LES
CYCLOHEXYLAMINE
2-HITDROXYBENZOIC ACID
ANTHRACENE
ACETIC ACID
ACETOPHENONE
SILVER
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
4.9UE 05
3.00E 06
4.10E 05
4.10E 05
4.9UE 05
8.90E 04
4. lot 05
4.10E 05
4.1UE 05
4. lot 05
4. lot 05
4.10E 05
4.9UE 05
4.9UE 05
4.9UE 05
4.9UE U5
4.9UE 05
4.9uE 05
b.ttot Ob
3.00E 05
8.90E 04
8.90E 04
6.9Ut 04
8.90E 04
4.9Ut U5
4. lot Ob
4. 1 uE 05
4.1UE 05
4.90E 05
4.9UE 05
6.80E 05
3.UUE 05
4.90E 05
1.1UE 02
l.bOt 01
1.44E 01
1.41E 01
1.41E Ul
i.40t 01
1.40t Ul
1.40E Ul
1.40E 01
1 . 40E U 1
1.40E 01
1.40E 01
1.40E Ul
1.40E 01
i.40t 01
1.40E 01
1.40E Ul
1.40E 01
1 .40E 01
1.40t Ul
1.30E 01
1.30E 01
1.30E 01
l.iOt Ul
1.30E Ul
1.30E 01
1 .iOt 01
1.30E 01
1.30t 01
1.22E Ul
1.22E Ul
1.21E 01
1.20E 01
1.20E 01
1.10E Ul
8.90E 03
6.50E 03
6.34E 03
8.34E 03
8.30E 03
8.10E 03
tt.lOt 03
8. 10E 03
e.lot 03
8.10E 03
8.10E 03
ti. lot 03
8.03t 03
6.03E 03
8.03t 03
8.U3E U3
6.03t 03
6.03E o3
6.o2t 03
7.70E 03
7.6U U3
7. bit 03
7.61t 03
7. bit 03
7.60t 03
7.60t o3
7.bOt o3
7.60t 03
7.22E U3
7.22C. U3
7.20E 03
7. lot 03
7. lot U3
6.50t 03
5
6
4
4
5
2
4
a
4
4
4
4
5
5
5
5
5
5
3
7
2
2
2
2
5
£4
4
4
5
5
3
7
5
M
I
-------
NJ
o
DMEG NO.
PRODUCT GAS PARTICULAR, HEALTH IMPACT
COMPOUND NAME
TYPE CONC DS
E-6 b/SCM
NDS
LCCAT
05
23
18
23
05
05
05
05
23
05
05
05
05
23
23
05
15
15
15
15
16
16
16
34
08
23
23
21
23
23
23
23
05
23
C
C
B
C
A
A
b
B
A
B
A
B
A
A
A
A
B
B
b
B
A
A
A
A
A
C
c
c
B
B
B
B
A
6
040* rt
061*
040*
060*
124*
123*
060*
061*
043*
062*
121*
063*
120*
041*
042*
122*
161*
160*
163*
162*
201*
202*
200* P
010
060*
060*
061*
OoO*
062*
066*
040*
061*
140* W
064*
T-PENUNOL
2-METHYLINOOLE
1,3-DlHYDHOXYBENZtNt
METHYLINDOLES
3-METHYL-l-BUTANUL
2»2-DIMETHYL-l-PKOPANOL
PtNTANOLS (SECONDARY)
2-PENTANOL
4-METHYLPYRIDINE
3-PENTANOL
N-PENTANOL
3-METHYL-2-BUTANUL
PENTANOLS (PRIMARY)
2-METHYLPYRIDINE
3-METHYLPYRIDINE
2-METHYL-l-BUTANOL
0-TERPHENYL
TERPHENYLS
P-TERPHENYL
M-TEKPHENYL
1-CHLORONAPHTHALENE
2-CHLORONAPHTHALENE
CHLORONAPrtTHALtNtS
CALCIUM (AS CA+2)
MALEIC ACID
METHYLINDOLES
2-METHYLINDOLE
DI8ENZ( A, o ANTHRACENE
2»6-DIMETHYLQUINOLINE
1,3-DIMETHYLISOQUlNOLlNt
2-METHYLOUINOLINE
2,3-DlMETHyLQUJNOLINE
6ENZY1 ALCOHOL
3^-OIMCTHVLeUJNOt 1*1
r
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
;* r,-
4.90E
4.90E
4.90E
4.90E
3.60E
3.60E
3.60E
3.60E
3. 6Ut
3.60E
3.60E
3.60E
3.60t
3.60E
3.60E
3.60E
8.90t
8.90E
8.90E
8.90E
6.60E
6.80E
6.80E
1.50E
3.00E
4.10E
4.10E
6.90E
4.90E
4.90E
4.90E
4.90£
4.90E
«»90£
05
05
05
05
06
06
06
Ob
06
06
06
06
06
06
06
06
04
04
04
04
05
05
05
05
05
05
05
04
05
05
05
05
OS
05
1.1 Oh
1.10E
1.10E
1.10E
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOt
l.oot
l.OOE
i.OOE
l.OOE
l.OOE
9.90E
9.90E
9.90E
9.90E
9.90t
9.90E
9.90E
9.40E
9.40t
9. HE
9.11E
9.00E
8.90E
8.90E
8.9UE
a.90E
6.9QL
0«90£
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
6.42E
6.42t
6.42t
6.42t
5.90t
5.90t
5.90t
5.90t
5.90t
5.90E
5.90t
5.90t
t>.90t
5.90t
5.90E
5.90t
5.b3t
5,b3t
5.63t
5.83t
5. bit
5. bit
s.eit
5.53t
5.53t
5.40E
5.40t
5.30t
5.30t
5.30fc
5.30t
b, 30t
5«30£
5.30t
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
5
5
5
5
6
6
6
0
6
6
6
6
6
6
6
6
£
2
^
2
3
3
3
7
4
4
2
5
5
5
5
5
S
-------
PRODUCT GAS PARTICULATh, HEALTH IMPACT
DMEG NU.
COMPOUND NAME
TYPE COUC US
E-6 G/SCM
WDS
LCCAT
23
23
23
23
02
08
20
26
06
18
18
07
18
18
02
02
02
08
16
22
08
14
16
16
16
7b
23
23
23
23
23
23
23
23
B
b
8
b
A
D
A
A
8
A
A
A
A
A
6
6
B
U
A
b
d
A
A
A
A
A
A
A
A
A
A
A
A
A
Oe>7*
060*
065*
063*
320* P
260*
020* P
020 W
080*
180*
183*
140*
182*
181*
100* P
104*
103*
160*
220* H
040* P W
041*
020 '4
loO* P
162*
161*
010 P
064*
063*
121*
082*
120*
080*
060*
061*
1,5-DI METHYL I SOUU1NULINE
DIMETHYLUUINOLINES
6,8-OIMETHYLGUINOLINE
2»8-DlMETHYH,iUINGLINE
HEXACHLOROETHANE
DI-a-ETHYLHEXYL ADIHATE
2-NITROPHENUL
TRIETHYL PHOSPHATE
Y-BUTYROLACTUNE
POLYALKYLPHENOLS (MW>135)
2/6-DIMETHYL-4-HEPTYL PHENOL
BENZALDEHYDE
4,6-DI-TERT-8UTYL-M-C«ESOL
2»4,6-TRIMEfHYL METHYL PHENOL
DICHLOROPROPENES
TRANS-1,3-OICHLOROPKOPENE
CIS-1,3-DICHLOROPHOP£N£
METHYL 8ENZOATE
POLYCHLORINATEO 6IPHENYLS
FLUORANTHENE
2-HYDROXY6ENZOIC ACID
BENZENESULFONIC ACID
POLYCHLORINATEO bENZENES
HEXACHLORUbENZENE
1,2,4-FRICHLOROBENZENE
NICKEL
4-N-PROPYLPYRIDINE
4-ETHYLPYRIUINE
5-ETHYL-2-METHYLPYRIDINE
3-PHENYLPYRIDINE
COLLIDINES
PHENYLPYRIOINES
MONGSUbSTITUTED ALKYL PYRIDINES
2-ETHYLPYKIDINE
1
T
T
T
T
T
T
T
T
T
T
T
T
r
T
T
T
T
D
T
T
T
T
T
r
S
T
T
T
T
T
T
T
T
4.90E
4.90t
4.90E
4.90E
8.90E
3.60E
4.90E
3.00E
3.0u£
4.9ufc
4.90E
4.90E
4.90E
4.90E
b.9ut
8.90E
8.90E
4.90E
< 7.60E
b.out
3.0uE
3«0
-------
fo
PRODUCT GAS PAHTICULATE* WEALTH IMPACT
DMEG NO.
COMPOUND NAK£
23 A 122*
23 A 083*
23 A 063*
23 A 081*
10 B 100*
07 A 140*
08 0 140*
08 0 141*
08 0 142*
08 0 143*
08 0 200*
15 A 141*
15 A 140*
15 A 143*
15 A 142*
07 B 16?*
07 B 180*
07 B 181*
33 A 010
08 D 220*
12 A 100*
05 A 160*
23 A 082*
23 A 061*
23 A 060*
23 A 121*
23 A 122*
23 A 063*
23 A 080*
23 A 120*
23 A 081*
23 A 083*
23 A 064*
23 A 062*
2r4,6-CULLIulNE
4-PHENYLPYKIDINE
3-ETHYLPYRIDINE
2-PHENYLPr«IDINE
MOHPHOLlNt
BENZALOEHYOE
AMYL ACETATES
N-AMYL ACETATE
SfcC-AMYL ACETATE
ISOAMYL ACETATE
OIETHYL AOIPATE
N-8UTYL BENZENE
6UTYL BENZENES
TERT-BUTYL BENZENE
SEC-BUTYL BENZENE
DIHYOKO-CU OR UCARVQNE
CARVONES
CARVONECD OR L)
MAGNESIUM
DIBUTYL AOIPA1E
N-NITROSUOIPENTYLAMINE
PHENETHYL ALCOHOL
3-PHENYLPYRIOINE
2-ETHYLPYKIDINE
MUNOSUBSTITUTEO ALKYL PYRIDINES
5-E T H YL-2-ME TH YLPYftlalNE
2,4,6-COLLIDlNE
4-tTHYLPYRIDlNE
PHENYLPYR1UINES
COLLIDINES
2-PMENYLPYRIDINE
4-HHENYLPYRIDlNE
4-N-PROHYLPYRIDINE
3-ETHYLPY«IDJNE
TYPE CONC DS
t-6 G/SCM
LCCAT
ti/S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
4.
4,
4.
4.
4.
4.
3,
3.
3.
3.
4,
6.
6,
6,
b.
4,
4,
/I
•* 1
3,
3,
4,
4,
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
,90t
,90E
,90£
,90E
,90E
,10E
,60E
,60E
60E
,60E
,90E
,80E
,80E
,80E
,80E
.90E
,90E
,90E
,90E
,60E
,90E
,90E
,10E
,10E
,10E
,10E
10E
10E
10E
lot
lot
10E
10E
10£
05
05
05
05
05
05
06
06
06
06
05
05
05
05
05
05
05
05
04
06
05
05
05
05
05
05
05
05
05
Ob
Ob
05
05
,05
7
7
7
7
7
6
6
6
6
6
6
6
6
6
6
6
6
b
6
6
6
6
5
5
5
5
5
5
5
5
5
5,
•
•
•
•
•
•
•
•
.
•
•
•
•
,
.
.
•
•
•
•
•
•
•
•
•
•
•
•
•
,
.
•
5.
5,
1
»
10E
10E
10E
10E
OOE
94E
92E
92E
92E
92E
tiOE
OOE
ttOE
60k
aoe
62k
62E
62E
50E
20k
dot
04E
94k
94E
94E
94E
94E
94t
94E
94k
94E
94E
94E
V4fc
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
.20k
.20k
.20k
.dot
.13E
.lot
.lot
.10k
.10k
.10k
.Olt
,01k
,01k
.01E
.Oik
.90k
,90k
,90t
,b3k
,70t
,70k
.60t
,50k
.50k
,50k
.50k
,50k
,50k
,50k
,50k
.but
,50k
.50k
3. 50fc
03
03
03
03
03
03
03
03
03
03
03
03
03
u3
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
5
5
5
5
5
4
6
b
b
b
5
3
3
3
^
b
b
b
o
b
b
4
4
M
14
4
H
14
4
4
4
4
4
-------
DMEG NU.
PRODUCT GAS PARTICULAR, HEALTH IMPACT
COMPOUND NAME
LCCAT
£-6 U/SCM
Ib
15
15
15
15
15
15
15
21
27
23
23
23
13
05
23
15
15
15
15
3d
08
06
08
08
13
Ib
21
08
Ob
20
18
Ob
03
b
b
B
B
B
B
B
B
C
A
B
b
B
b
B
B
b
B
b
6
A
D
D
D
D
6
C
B
D
D
B
C
A
B
Ibl*
Ib2*
202*
180*
201*
200*
183*
203*
040*
010
160*
080*
140*
ObO*
120*
120*
142*
141*
120*
140*
010
121*
122*
123*
120*
OoO*
040*
100*
101*
100*
040*
020*
040*
060*
1, 2,3-TRIMETHYLBENZtNE
1,2,4-TRIrtETHYLBENZfcNE
1,2,3,5-TtTRAMETHYLdENZENE
TRIMETHYLBENZENES
1,2,3,4-TETRAMETHYLBENZENE
TETRAMETHYLBENZENES
1,3,5-TRIMETHYLBENZENE
1,2,4,5-TEFRAMETHYLdENZENE
BENZG(G)CHRYSEN£
LITHIUM
BENZO(H)OUINULINE
ACRIDINE
BENZO(F)QUINOLINE
METHYL DISULFIDE
BORNEOL
PHENANTHRIDINE
1,4-DIHYDkONAPHTHALtNE
1,2-OlHYDRONAPHTHALENt
TETRAHYDKONAPHTHALENE
DIHYDRONAPHTHALENES
ALUMINUM
N-BUTYL ACETATE
SEC-BUTYL ACETATE
ISOBUTYL ACETATE
BUTYL ACETATES
DIPHENYL SULFIOE
W 2-NAPHTHOL
BENZO(C)PHENANTHRENE & ALKYL DERIVATIVES
N-PROPYL ACETATE
PROPYL ACETATES
M DINITRO-P-CRESOLS
1-NAPHTHOL
PROPYLENE GLrcoL
2-£THYL-4-METHYL-l,3-UIOxOLANE
T
T
T
T
T
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
D
T
T
D
T
T
T
b.eot
b.dOE
b.dot
b.80t
b.eot
6.80E
6.bOE
b.bOt
b.90t
1.20E
4.90E
4.90t
U.90E
4.90E
4.90E
4.90E
6.8ot
6. Sot
b.8o£
6. dot
2.70E
3.60t
3.bOt
3. but
3.60E
H t 90t
4 . 9wt
9.70E
3.60E
3.60E
b.40E
4.90E
3.60t
4.90E
05
05
Ob
05
05
05
05
05
04
02
05
05
05
05
05
05
05
05
Ob
05
04
Ob
06
06
Ob
05
05
02
06
06
(id
05
06
05
5.70E
b.70t
b./Ot
5.70E
5.70E
5.70E
5.70E
b.70t
b.6o£
5.50E
5.44E
5.44E
5.4<«E
b.44t
5.44E
5.44E
b.23t
b.23t
5.23H
5.23E
b.20t
5. 14E
5.14E
5.14E
5.14E
b.lOt
4.50E
4.40E
4.30E
4.30t
4.20t
4. lOt
3.00C.
3.bOt
ou
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
CO
00
00
00
00
00
00
00
00
00
uO
00
u/s
3.34L
3.34t
3.34t
3.34t
3.34t
3.34L
3.34E
3.34t
3.30t
3.21E
3.21E
3.2lt
3.2lt
3.2lt
3.2U
3.2lt
3. lOt
3. lot
3. lOt
3. lOt
3. lot
3.03t
3.03t
3.03t
3.03t
3.01t
2.62t
2.«>0t
2.b
-------
M
N3
DMEG NO,
PRODUCT 6A8 PARTICULATE, HEALTH IMPACT
COMPOUND NAME
08 A IbO*
08 0 320* P
Ob B 020* M
18 C 062*
18 C OBI*
10 C 060*
Ob A 100*
05 A 060*
18 C 063*
05 B 060*
06 A 160*
03 A 040* H
21 A 041*
21 B 160* P
21
21
15
21
21
21
21
21
21
06
15
16
061*
080*
020*
063*
062*
044*
043*
040*
042*
020* N
120*
160*
15 A 100*
05 C 060*
06 C 040*
03 A 040* W
02 A 343*
02 A
01 A
01 4
340* P
201
200 M
BENZOIC AC1U
BUTYL BENZYL PHTHALATE
2, J-EPOXY-1-PROPANOL
4-INDANOL
1-INDANOL
INDANOLS
ISOBUTYL
N-bUTANOL
5-INDANOL
ALCOHOL
2,6-DIM£THYL-4-HEPTANOL
AD1PIC ACID
3-METHOXYBIPHENYL
1-METHYLNAPHTHALENE
PYRENE
1,U-DIMETHYLNAPHTHALENE
DIMETHYLNAPHTHALENES
INDAN
2,6-DIHETHYLNAPHTHALENE
2,3-DIMETHYLNAPHTHALENE
2-ETHYLNAPHTHALENE
1-ETHYLNAPHTHALENE
MONOALKYL
NAPHTHALENES
2-METHYLNAPHTHALENE
2,3-EPOXY-l-PROPANOL
I80PROPYL
BENZENE
2-CHLOROTOLUEME
PROPYL BENZENE
A-TERPINEOL
ACETAMIDE
3-METHOXYBIPHENYL
1,3-DICHLUKOPHOPANE
DICHLUROPKOPANES
N-OCTANE
OCTANES
TYPE CONC
E-6 S/SCM
US
MDS
WS
LCCAT
T 4.90b
T 4.
T 4.
T 4.
T 4.
T 4.
T 4.
T 4.
T 4.
T 4.
T 4.
T 4.
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
.
.
.
.
.
«
•
.
•
.
.
.
.
.
,
T 4.
T 3.
T 4.
T 8.
T 8.
T fl.
90E
90E
90E
90E
90E
90E
90E
90E
90E
90t
90t
60E
80E
80t
80E
80E
60E
60E
60E
60E
60E
60E
10E
80E
80E
60E
90E
60E
10E
70E
70E
70E
T 0.70E
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
06
05
05
05
OS
05
3.50E
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
2
2
2
2
2
•
•
•
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
»
.
•
.
•
•
50E
30E
30E
30E
30E
30E
30E
30E
10E
lot
10E
OOE
OOE
OOE
OOE
OOE
OOE
OOE
oot
OOE
OOE
OOE
73t
71E
71E
71E
60E
60E
60E
50E
50E
2.50E
2,
(
•
50£
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
2.
2.
1.
1.
1.
i.
1.
1.
1.
1.
1.
1.
1.
1.
1.
.
,
.
,
.
.
.
.
1.
1.
.
9
9
9
9
9
9
1.
lot
lot
92E
92E
92t
92E
92t
92t
92E
60c
but
60E
74fc
74t
74t
74E
74t
74t
74t
74E
74t
74t
74E
61t
60E
60t
60t
52t
5lt
Sit
sot
50E
50fc
1.506
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
U3
03
03
03
03
03
03
5
5
5
5
5
5
5
5
5
5
5
<3
3
3
3
3
3
3
3
3
3
3
3
4
3
3
3
5
6
4
1
1
1
1
-------
DMEG NO.
PRODUCT GAS PARTICULATE, HEALTH IMPACT
COMPOUND NAME TYPE
US
LCCAT
E-6 WSCM
b/S
17
17
17
17
16
lo
14
14
26
08
14
02
22
08
17
17
17
17
16
08
15
21
16
16
16
16
15
02
21
02
15
15
15
15
C*
1
K
Li
B
B
B
B
A
A
A
A
b
A
A
A
A
(j
B
B
b
B
A
A
A
A
A
A
A
A
A
A
A
A
B
6
B
B
i
}
T
023*
020*
022*
021*
100* P
120* P
041
043
040 H
160*
04a
140* P
010* W
240*
021*
020*
022*
023*
020* P
180*
040* P
020* P
080*
083*
081*
082*
080*
361*
140* P
360*
083*
100*
081*
103*
l-METHUXY-4-NlTRObENZENE
METHOXYNITRUbENZENES
l-METHOXY-3-NlTRObENZENE
l-METHOXY-2-MTROdENZENE
1,2-DICHLOROBENZENE
l,3-DICHLOKOd£NZEN£
9,10-ANTHRAUUINONE-1,5-DI3ULFUNIC ACID
9r10-ANTHRAUUlNON£-l,7-DISULFONlC ACID
TR1TOTYL PHOSPHATES
BENZOIC ACID
9,10-ANTHKA(iUlNONE-l,8-DISULFONlC ACID
DIBROMOCHLUROME THANE
INDENE
DI-2-ETHYLBUTYL ADlPATt
l-^ETHOXY-2-NlTROBENZENE
METHOXYNlTROdtNZENES
l-METHUXY-3-NITROBENZENE
l-METHOXY-4-NITROBENZENE
CHLORGBENZENE
A01PIC ACID
TOLUENE
NAPHTHALENE
BROMOCHLOROBENZENES
l-bROMO-4-CHLOROBENZENE
l-BRUMO-2-CHLORObENZENE
l-bROMO-3-CHLOROBENZENE
STYRENE
1-BROMOBUTANE
ANTHRACENE
BROMObUTANES
P-XYLENE
DIALKYL BENZENES (Mw:134-191)
0-XYLENE
P-DIETHYL BENZENE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
r
T
T
T
T
T
T
T
T
T
T
T
T
T
T
4.90E
4.90E
4,9oE
4.90E
6.80E
6.80t
3. Out
3.00E
3.00E
3.00E
3.00t
«.90t
6.90E
4.9u£
4. lOt
4.10E
4. lu£
4. lot
6.8ot
3.00E
6.ttut
e.9ot
6.80t
e.eot
6.80E
6.80E
6.80E
tt.90t
8.90E
6.90E
6.80t
6.80E
6.80E
6.80E
Ob
Ob
Ob
05
05
05
05
05
05
05
05
04
04
05
05
05
05
05
05
05
05
04
05
05
05
05
05
04
04
04
05
05
05
05
2.33E
2.33E
2.33t
2.33t
2.30E
2.30E
2. 1 4c
2.14E
2. 1 4t
2.14E
2.14t
2.00E
2.00E
2.00E
2.00E
2.00E
2.0UE
2.00E
1.94E
1 .9ot
1.80E
1.60E
1.74E
1.74E
1.74E
1 . 74E
1.61E
1.60E
1.60E
1 .60t
1.54E
1.54E
1.54E
i.54t
00
00
00
00
00
Co
00
00
00
00
00
uO
00
oo
oo
00
00
00
00
00
00
00
00
00
00
00
00
00
oo
00
00
00
00
00
1.40E
1.40E
1.40t
1.40t
1.33E
1 .33E
1.30t
1.3ot
1.30E
1.30E
1.30t
1 ,20t
1.20E
1.20E
1.20E
1.20E
1.20t
1.20E
1.14E
l.lot
l.lOt
1.10E
1.02E
1.02t
1.02E
1.02t
V.60E
9.40E
9.40E
9.40E
9. lit
9. lit
9. lit
9. lit
03
03
o3
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
02
02
02
w2
02
02
02
02
5
5
5
5
3
3
7
7
7
7
7
2
2
5
a
4
4
a
3
/
3
2
3
3
3
3
3
2
2
2
3
3
3
3
-------
PRODUCT GAS PARTICIPATE, HEALTH IMPACT
DMEG NO,
COMPOUND NAME
TYPE CONC OS
E-6 G/SCM
LCCAT
s/s
15
15
15
IS
15
15
15
15
16
17
16
16
16
16
16
05
05
05
05
23
05
23
05
23
05
05
05
78
32
02
16
16
16
35
b
B
B
B
B
A
B
B
A
A
A
A
A
A
A
B
A
A
A
A
B
A
B
A
B
A
A
A
A
B
A
A
A
A
I0t>*
104*
082*
105*
102*
060* P
ObO*
101*
140* P
080*
063*
061*
062*
060*
040*
062*
122*
124*
123*
041*
060*
042*
061*
043*
063*
120*
121*
010 P
010 P
080* P
200* P
202*
201*
010
lr4-Dl-TEKT-BOTYL BENZENE
0-DIISOPROPYL BENZENE
M-XYLENE
M-OIISOPROPYL BENZENE
M-OIETHYL BENZENE
ETHYL BENZENE
XYLENES
0-DIETHYL bENZENE
1,4-DICHLORObENZtNE
OINITROTOLOENES
1 , 4-DIBROMObENZENE
lr2-DIBROMObENZENE
1,3-DIBROMOBENZENE
DIbROMOBENZENES
BRuMOBENZcNt
3-PENTANOL
2-METHYL-l-bOTANOL
3-METHYL-l-bUTANOL
2r2-DIMETHYL-l-PROPANOL
2-MtTHYLPYRIOINE
PENTANOLS (SECONDARY)
3-METHYLPYRlOlNt
2-PENTANOL
4-METHYLPYRIDINE
3-METHYL-2-BOTANOL
PENTANOLS (PRIMARY)
N-PENTANOL
COPPER
BERYLLIUM
TETRACHLOROETHENE
CHLORONAPHTHALENES
2-CHLORONAPHTHALENE
1-CHLORONAPHTHALEN£
STRONTIUM
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
U
S
T
T
T
T
D
6.80E
6.80E
6.806
6.60E
6. But
6.60E
6. 80t
6.80E
6.80E
2.20E
6. but
6.80E
6.80E
6.80E
o.8ot
4.90E
4.90t
4.90E
4.90E
4.90E
4.90E
4.90E
4.90t
4.90E
4.90E
4.90E
4.90t
2.70E
2.60t
d.70t
8.90E
6.VOE
5.906
3.9C£
05
05
05
05
05
05
05
05
05
03
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
02
00
05
04
04
04
03
1.54t
1.54t
1.54E
1.54E
1.54E
1.54E
1 .S4t
1.54E
l.blt
1.50E
1.41E
1.41E
1.41E
1.41E
1.40E
1 ,*«OE
1.40E
1.40t
1.40E
1 .40t
1 ,40t
1 ,40t
1.40E
1.4UE
1.40t
1.40E
1.40t
1.34E
1.30E
1.30E
1.30t
1.30E
1.30E
i.JOE
00
00
00
00
OU
00
00
00
00
00
00
00
uo
00
00
00
00
00
00
00
00
uo
00
00
oy
00
uO
00
00
00
00
00
00
00
9. HE
9. lit
9. lit
9. HE
9. lit
9. lit
9. lit
9. lit
8.91E
0.7UE
6.40t
6.40E
8.40t
b.40t
b.20t
6.03E
b.03t
8.03t
8.03t
8.03t
6.03t
tt.03t
b.03t
8.03t
«.03t
8.03E
8.o3fc
b.oot
7.7ot
1 .lot
7.61E
7.61t
7.61t
7.42t
02
02
02
02
02
02
02
02
02
02
02
02
02
02
U2
02
02
02
02
o2
02
02
02
02
02
0£
02
02
(id
02
02
02
02
02
3
3
3
3
3
3
_j
3
3
4
3
3
3
3
3
5
b
•a
5
5
b
5
5
5
5
b
5
1
2
2
2
-------
PRODUCT GAS PARTICULAR, HEALTH IMPACT
OMEQ NO.
COMPOUND NAME
TYPE CONC US
E-6 b/SCM
LCCAT
21
08
23
23
23
23
26
22
08
08
08
08
23
15
15
15
15
01
01
01
01
01
01
01
4b
08
50
15
15
15
15
15
15
15
R
1
K
B
D
A
A
A
C
B
B
D
0
D
0
C
A
A
A
A
A
A
A
A
A
A
A
A
D
A
B
D
B
B
B
B
B
]
5
080*
260*
042*
043*
041*
062*
020
040* P W
140*
141*
142*
143*
062*
142*
143*
141*
140*
242
240
241
220
260
222
221
010 P
220*
010 P
203*
181*
182*
180*
201*
183*
200*
3-METHYLCHOLANTHRENE
DI-2-ETHYLHEXYL ADIPATE
3-METrlYLPYRlDlNE
4-METHYLPYRIDINE
2-METHYLPYRIDINE
3-METHYLINOOLE
TRIPHENYL PHOSPHATE
FLUORANTHENE
AMYL ACETATES
N-AMYL ACETATE
SEC-AMYL ACETATE
ISOAMYL ACETATE
3-METHYLINDULE
SEC-BUTYL BENZENE
TERT-BUTYL BENZENE
N-BUTYL BENZENE
BUTYL BENZENES
N-UNDECANE
ALKANES(CslO,ll)
N-OECANE
NUNANES
N-OOOECANE
ISONONANE
N-NUNANE
LEAD
DIBUTYL ADIPATE
ANTIMONY
1,2,4,5-TETRAMETHYLBENZENE
1,2,3-TRIMETHYLBENZENE
1,2,4-TRlMETHYLBENZENt
TRIMETHYLbENZENEb
1,2,3,4-TtTKAMETHYLBENZENE
1,3,5-TRIMETHYLBENZENE
TETRAMETHYLBENZENES
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
D
T
T
T
r
T
T
T
4.70E
4.90E
4. lut
4.10E
4.1UE
4.90E
3.00E
8.90E
4.90E
4.9u£
4.90E
4.90E
4. 10E
8.90E
8.90E
8.90E
8.90E
d.70£
8.7UE
a. 7ot
8.70E
8.70E
O • j 0 1
o • f \) d
1.30t
4.90t
< 3. But
8.9UE
8.90E
8.90E
8.90E
a. 9o£
8.90E
8.9u£
00
05
05
05
05
Ob
05
04
05
05
05
05
05
04
04
04
04
Ob
05
05
05
05
05
05
02
05
02<
04
04
04
04
04
04
04
1
1
1
1
1
1
1
9
9
9
9
9
9
8
8
8
a
d
a
a
a
a
8
d
8
d
7
7
7
7
7
/
1
7
.23E 00
.20E 00
,13t 00
,13t 00
.13t 00
.10E 00
.03t 00
. 90t-01
.42E-01
. 42t-0l
.42E-01
.42t-01
.llt-01
. VOE-ol
,90t-0l
.9UE-01
.90E-01
. 7UE-U1
.70E-01
.70£-01
.70t-01
•70E-01
.70E-01
. /OE-fl
.70E-01
.44E-01
,bO£-01<
.41E-U1
,*4 1£-0 1
.41E-01
.41t-0l
.^lt-Ul
.41E-01
.41E-U1
7.30E
7. lOt
b . 7 1 1
6.71E
6.7lt
6.42E
6. lot
D.83t
5.60E
5.60t
S.bOE
5.bOt
5.40E
5.30t
5.30t
5.30t
5.30t
b.l^t
5.13t
5.13t
5.i3t
b.lit
5.13t
5.13E
b.llt
b.OOt
4.50t
4.40t
4.40t
4.40E
4.40E
4.40C
4.40E
4.40L
02
02
02
02
u2
02
o2
02
02
02
02
02
Od
02
02
02
02
02
Od
02
02
02
02
02
02
o2
02
02
02
02
02
02
02
02
3
5
14
4
4
5
7
2
5
5
5
b
4
2
d
a
2
i
i
i
i
i
i
i
5
2
2
2
2
2
2
2
-------
00
DMEG
NO.
PRODUCT tAS PARTICULATE, HEALTH IMPACT
COMPOUND NAME TYPE
CONC
US
E-6 U/SCM
15
08
08
08
06
15
15
15
15
43
21
08
06
23
56
06
22
28
01
21
21
21
21
21
21
21
21
21
15
21
15
16
15
95
B
(j
D
D
D
B
B
B
b
A
B
D
D
B
A
A
c
A
B
A
B
A
A
A
A
A
A
A
6
A
A
A
A
4
202*
122*
123*
121*
120*
120*
141*
140*
142*
010
040* P
101*
100*
100* *
010
040*
060* P M
010
080
040*
180* P
042*
081*
043*
082*
083*
044*
041*
020*
060*
100*
160*
120*
010
1,2,3,5-TETRAMETHYLBENZENE
SEC-BUTYL ACETATE
ISOBUTYL ACETATE
N-BUTYL ACETATE
BUTYL ACETATES
TETRAHYDRUNAPHTHALENE
lr2-DIHYDfcUNAPHTHALEN£
DIHYDRONAPHTHALENES
1,4-DIHYDRONAPHTHALENE
SILICON
bENZ(A)ANTHRACENE
N-PROPYL ACETATE
PROPYL ACETATES
DIHYDROACRIOINE
FLUORINE (AS F-)
PROPYLENE GLYCOL
BENZO(B)FLUORANTHENE
SODIUM
BUTADIENES
MONOALKYL NAPHTHALENES
PYRENE
2-METHYLNAPHTHALENE
If 4-DIMETHYLNAPHTHALENE
1-tTHYLNAPHTHALENE
2,3-DIMETHYLNAPHTHALENE
2f6-DIMETHYLNAPHfHALENE
2-tTHYLNAPHTHALENE
1-METHYLNAPHTHALENE
INDAN
DlMETHYLNAPHTHALENES
PROPYL BENZENE
2-CHLOROTOLUENE
ISOPROPYL BENZENE
URANIUM
T
T
T
T
T
T
T
T
T
S
D
T
T
D
S
T
D
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
9
6
4
4
4
4
6
8
8
8
> 6
2
4
4
9
1
4
3
2
8
6
6
8
8
6
8
8
8
6
6
6
8
,90E
.90E
,9o£
,90t
.90E
.90E
.90E
,90E
,90t
.7oE
.60E
.90E
.90E
.luE
.30E
.90E
.70E
.lot
,70t
,90E
,90E
• 90k
.90E
.90E
.90E
.90E
.90E
.90E
,90E
.90E
.90k
0.90E
8.90E
,J«
20£
04
05
05
05
05
04
04
04
04
03>
01
05
05
01
03
05
02
04
05
04
04
04
04
04
04
04
04
04
04
04
04
04
04
00
7.41E-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
6.64E-01
6.84k-01
6.84E-01
6.84k-01
6.70£-01>
6.22E-01
5.83E-01
5.83E-01
5.70E-01
5.20E-01
5.20E-01
4.11E-01
4.00k-01
4.00E-01
3.90k-01
3.90E-01
3.90E-01
3.90E-01
3.90k-01
3.90E-01
3.90E-01
3.90E-01
3.VOE-01
3.VOE-01
3.90E-01
3.60E-01
3.60E-01
J.OOE-01
j«60£»OJ
wDS
G/S
4.40k
4.12k
4.12k
4.12k
4.12t
4.03E
4.03k
4.03k
4.03k
4.00k
3.70k
3.44k
3.44k
3.40t
3.10k
3.04k
2.42k
2.33k
2.33k
2.30k
2.30k
2.30k
2.30k
2.30k
2.30k
2.30k
2.30k
2.30k
2.30E
2.30k
2.10k
2.10k
2. lOt
t.iot
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
LCCAT
2
5
5
5
^
2
2
2
2
2
5
5
b
5
3
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
-------
PRODUCT GAS PARTICULATEf HEALTH IMPACT
DM
08
16
lo
74
02
16
02
15
Ib
lo
16
lo
15
Ib
15
15
15
15
15
15
15
15
15
15
15
16
lo
16
lo
lo
16
37
62
23
EG
C
A
A
A
A
A
A
A
A
A
A
A
A
B
B
B
6
6
A
B
B
B
B
B
B
A
A
A
A
A
A
A
A
B
NO.
040*
100* P
120* P
010
340* P
020* P
343*
040* P
082*
083*
081*
000*
080*
101*
083*
104*
100*
082*
060* P
105*
106*
081*
103*
080*
102*
140* P
063*
ObO*
062*
061*
040*
010
010
100* W
COMPOUND NAME
ACtTAMlOE
If 2-DICHLOROBENZENE
If 3-DICHLOROBENZENE
CObALT
D1CHLOROPROPANES
CHLORObENZENE
If 3-DICHLOROPROPANE
TOLUENE
l-BROMO-3-CHLOROBENZENE
l-BROMO-4-CHLOROBENZENE
l-BKOMO-2-CHLOROBE\ZE'NE
BKUMOChLOROBENZE^tS
STYRENE
0-D1ETHYL BENZENE
P-XYLENE
0-OIISOPROPYL BENZENE
UIALKYL BtNZtNES Id* : 1 34-191 )
M-XYLEwE
ETHYL BENZENE
M-DIISOPROPYL BENZENE
If 4-UI-TEKT-BUTYL BENZENE
0-XYLENE
P-DIETHYL BENZENE
XYLENES
M-DIETHYL BENZENE
If 4-0 1 CHLOROBENZENE
1,4-OIBROMOBENZENE
DIBROMOBENZENES
If 3-DIBROMOBENZENE
If 2-DIBROMOBENZENE
BROMOBENZENE
BORON
TITANIUM
OIHYUROACR1UINE
TYPE CONC
E-6 U/3CM
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
]
T
T
T
T
T
T
T
T
T
V
T
U
0
U
4.90E
8.90E
8.90E
1 .4ut
8.90E
8.90E
0.90E
B.90E
8.90E
8.9UE
8.9UE
e.9v>t
8.9UE
8.90E
8.90E
6.9uE
b.9ut
8.90E
8.90E
6.90E
8.90E
B.9i>E
8.90E
8 . 9 y t
».9uc
8.9UE
8.9u£
8.90E
8.9ut
b.9uE
8.90E
5.50E
9.40E
2. 3i»t
05
04
04
01
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
02
02
01
3
us
boe-oi
3.WOE-01
3.
2,
,0t>£-01
,8l>t-0 1
2.54E-01
2 ,
d,
,b4t-0 1
.54E-0 1
2.34t-01
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
1.
1.
1.
1.
1.
1.
1.
1.
,iOE-01
,30E-01
(30c-ul
OOE-01
11E-01
02E-01
02E-01
02E-01
02t-yi
02E-01
02E-01
02E-01
02E-01
U2E-01
02E-01
02E-01
02E-01
uOt-01
90E-01
90t-0l
90E-01
VGE-01
6lt-01
80E-01
bOE-01
43E-01
WQS
b/S
2. lOt
1.80t
1.80E
1.70t
1 .bOt
l.bOt
l.bOt
1 . 40t
1.34E
1.34E
1 .34t
1 . 34t
1 . 30t
1.20E
1.20t
1.2UL
1.20c
1.20E
1.20E
1.20E
1 ,
-------
PRODUCT GAS PAKTICULATE, HEALTH IMPACT
DME
02
15
Bl
01
65
41
61
71
63
65
44
22
55
51
64
39
70
69
64
66
60
64
84
84
6<4
30
31
21
20
21
21
57
16
21
G
B
A
A
B
A
A
A
A
A
B
A
C
A
A
A
A
A
A
B
A
A
A
F
C
E
A
A
C
A
A
B
A
A
A
NO.
080* P
160* M
010 P
060
010
010 P
010
010 P
010
010
010
080* P M
010
010
010
010
010
010
010
010
010
010
010
010
010
010
010
100* P H
120* M
120* PH
080*
010
220* W
120* PH
COMPOUND NAME
TETRACHLOROETHENE
BIPHENYL
ZINC
BUTYLENES
VANADIUM
THALLIUM
YTTRIUM (AS Y + 3)
MANGANESE
ZIRCUNIUM (AS Z**4)
THORIUM
GERMANIUM
BENZO(B)FLUURANTH£NE
TELLURIUM
HI SMUT*
HAFNIUM, (AS *Ft 3
0
•
•
•
•
•
•
•
•
•
•
*
•
•
•
•
•
•
•
•
*
•
•
•
•
•
•
•
•
•
•
•
•
•
8.
90E 04
20E 02
80E 02
70E 05
60E 01
20E 00
OOE 01
20E 02
70E 01
40E 00
20E 00
OOE 01
70E-01
60E 00
90E 00
30E 01
20E 00
70E 00
10E ol
30E 01
90E 01
60E 01
70E 00
40E 00
4oE 00
OOE 00<
30b 00
OOE-Oi
OOE-01
60E 05
OOE-01
20E 03>
OOE-01
9UE 04
1.
1.
1.
9.
7.
3.
3.
2.
1.
1.
1.
1.
9.
6.
5.
4.
3.
1.
1.
5.
3.
3.
1.
1.
1.
5.
2.
0.
0.
0.
0.
0.
0.
0.
DS
32E-01
20E-01
20E-U1
60E-02
20E-02
20E-02
OOE-02
40E-02
74t-02
52t-02
30E-02
11E-02
70E-03
34E-03
60E-03
60t-03
20E-03
94E-03
40E-03
90E-04
60E-04
30E-04
82E-04
30E-04
20E-04
83t-05<
OOE-05
OOE-01
OOE-01
OOt-01
OOE-01
O0t-Ul>
OOE-01
UOE-ol
WDS
b/S
7.63E 01
7. lot 01
7.10E 01
5.64t 01
4.24t 01
1.90t 01
l.bOt 01
1.41t 01
1.02E 01
9.00t 00
7.toOt oO
fa.OGt 00
5.72E 00
3.74t 00
3.42t 00
2.7U 00
1.90t 00
1.14E 00
8.13t-01
3.50t-01
2.11t-01
1.93E-01
1.10t-01
7.40t-02
7.12t-02
3.44t-02
1.70t-02
0. OOt-01
0. OOE-01
0. OOt-01
0. OOt-01
0. OOt-01
0. OOE-01
0. OOt-01
LCCAT
2
3
1
2
2
0
3
2
3
2
-------
PKOUUCT GAS PARTICULAR, HtALTH IMPACT
DMEG NO.
21 c oeo* P
12 A 020* P W
10 C 040*
20 A 120* IN
21 8 100*
23 6 240*
21 A 100* PH
08 6 060* W
45 A 010
12 A 020* P M
10 C 040*
04 A 160* P
04 A 160* P
20 b 040* N
21 A IOC* PH
23 B 220*
23 8 240*
59 A 010
21 D 040* W
21 0 040* W
21 6 060* W
23 B 220*
84 0 010
17 B 040* W
17 b 060* W
03 6 060*
29 A 010
09 A 120* rt
25 B 040* W
09 6 020* W
21 0 OtiO* PH
21 0 080* PH
Oti 8 060* W
53 A 010
PI
i
LO
COMPOUND NAME
DIBENZU, H) ANTHRACENE
N-NITROSOOIMETHYLAMlNE
AMlNOTOLUfcNES
2,4,6-TRIMTROPHENOL
bENZOCOPHENANTHRENE & ALKYL OEHIVATIVES
DIBENZ(A,H)ACRIDINE
ACtNAPHTHENE
B-PROPIOLACTONE
TIN
N-NITROSQUIMETHYLAMINE
AMINOTOLUENES
A-CHLOR08UTYL ETHYL ETHER
A-CHLOROBUTYL ETHYL ETHER
DINITRO-P-CRESOLS
ACENAPHTHENE
DIBENZU, JJACRIDINE
DI6ENZ(A,H)ACKIDINE
IUUINE (AS i-J
DIBENZO(A,I)PYRENE
DI6ENZO(A,I)PYRENE
7, 12-DIMETHYLBENZC A) ANTHRACENE
DIBENZU, J)ACRIDINE
NEODYMIUM
l-CHLORO-2-NITROBENZENt
l-CHLORO-4-NITROBENZENE
2-tTriYL-4-METHYL-l,3-DIOXOLANE
POTASSIUM
TETRAMETHYLSUCCINONITRILE
BENZO(B)THIOPHENE
BtNZONITRILE
BtNZO(GHI)PERYLENE
BENZO(GHI)PERYLENE
B-PROPIOLACTONE
SULFUR
TYPE
u
L>
D
0
D
D
T
D
S
0
U
T
T
0
T
0
0
S <
0
0
D
U
S
D
0
0
a >
D
D
D
r
T
u
S >
CONC
E-6 (,/SCM
O.OOE-01
O.OOt-01
O.OOt-01
O.OOt-vl
O.OOE-01
O.OOE-01
8.90E 04
O.OOt-01
1.30E 01
O.OUE-01
O.OOE-01
4. lOt 05
4.90E 05
O.OOE-01
b.bOt 05
O.OOE-01
O.OOE-01
4.00E 00<
O.OUt-01
U.OUE-01
U.OOh-01
O.OOE-01
9.70E 00
O.OOE-01
O.i)0t-01
O.OOE-01
3.20E c»3>
O.OOE-01
O.OOE-01
O.OOt-01
B.90E 04
6.8UE 05
O.OOt-01
3.50E 03>
OS
U.OOE-Ul
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
U.UOE-01
O.OOt-ol
O.OOt-01
O.OOE-01
O.OOE-01
(J.OOfc-01
O.UOE-01
O.OOt-01
O.UOE-U1
O.OOt-01
O.OOt-01
O.OOE-01
0.00£-01<
O.OOE-01
O.UOE-U1
O.OOt-01
O.OOt-01
u.oot-oi
o.out-oi
O.OOE-01
o.oot-oi
O.Oi)E-01>
O.OOE-01
O.OOE-01
o.oot-oi
O.OOt-01
0. oO£-o 1
O.OOt-01
O.OOE-OI>
WDS
b/S
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
O.OOE-01
O.OOt-01
O.OOE-OI
o.oot-oi
O.OOE-01
o.oot-oi
o.oot-oi
O.OOt-01
O.oOt-ol
O.OOt-01
O.OOt-01
o.oot-oi
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOt-01
o.oot-oi
o.oot-oi
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
O.OOc-01
o. oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
LCCAT
2
5
5
5
2
5
tL
t>
b
6
4
5
6
3
6
b
3
ti
d
5
4
4
4
4
4
4
2
3
5
-------
1
OJ
to
PHOOUCT GAS PAHTICULATE, HEALTH IMPACT
)MEG
NO.
COMPOUND NAME
TYPE
CONC
E-6
22
22
56
A
A
A
020* PH
020* PH
010
FLUOHENE
FLUORENE
BROMINE
T
T
3
b
b
1
•
•
•
US
li/SCM
90E
flo£
30E
04
Ob
0
-------
1
2
3
(I
5
KATE =
STATE: GAS, UNITS IN
IMPACT: ECOLOGY
EXPEHIMENTALY D
SPAKK SOURCE DATA
PKODUCT GAS PAKTICULATE
FLOW KATE = 590 G/S -(0.b7 SCl*/S, OKY BASIS)
8. $23 SCM AT 25C AND 7bO Ml* HG SAMPLED
TOTAL ORGANIC LOADING = 7.3 G/SCh
TUTAL TCO = 380 MG/SCM 1UTAL GKAV = 6<*OU
0.17X UHIblNAL SAMPLt 7U LC
LC TCU = 5.3 MO LC GKAV = 97.6 MG, LC TOTAL = 10<£.9
OWGANIC LOADING
670000. U
89000.0
080000.0
410000.0
490000.0
3600000.0
300000.0
tn
i
U)
-------
PRODUCT UAS PARTICULAR ECOLOGY IMPACT
OMEG NU.
COMPOUND NAME
TYPE CUNC US
E-b (,/SCM
LCLAT
(a/S
63
15
15
15
65
ib
01
01
16
22
21
16
21
22
21
21
21
21
21
17
21
21
o3
09
25
09
12
10
06
20
20
23
23
23
A
A
A
A
A
A
B
B
A
C
C
A
b
C
B
B
C
U
C
B
B
C
B
A
b
b
A
C
B
A
B
B
B
B
010 P
120*
040* P
120*
010
040* P
060
060
220*
OBO* P
100* P
220*
060*
ObO* P
100*
060*
10(1* P
040*
ObO* P
040
060*
ObO* P
060
120
040
020
020* P
040*
060*
120*
040*
100*
220*
240*
MERCURY
1SOPROPYL BENZENE
TOLUENE
ISUPROPYL BENZENE
VANADIUM
TULUENE
BUTADIENES
BUTYLENES
HOLYtMLUHiNATED blPHENYLS
BENZO(b) FLOUR ANTHENE
BENZU(A)PYR£NE
PULYCHLOR1NATEO blPH£NYl.S
1 , 12-DlMElHYLbENZ(A)ANTrt*ACENE
bENZO(B)FLUOKANTHENE
tJENZUCUPHENANTMKENE & ALlSYL DERIVATIVES
7, l2-OIM£THYLbENZ(A)ANTH«ACENE
bENZOCAJPYRENE
UIBENZU(A,I)PYREH£
D IBENZ( A, MJ ANTHRACENE
l-CHLURO-2-NlTRObENZENE
3-METHYLCHOLANTrtRENE
0 1 BENZC A, H) ANTHRACENE
2-tTHYL-4-M£lHYL-lr3-DIOXULANE
1ETRAMETHYL5UCC1NONITKILE
HENZCUb)THlOPHENt
BENZONlTRlLt
U-MTKOSOUIMETHYLA-MINE
AMNOTOLUENES
H-PrtOPlOLAClONE
2»4,6-TKlNlTPUPHENOL
OINITRO-P-CRESOLS
UIHYOROACRIDINE
UIBENZ(A,J)ACKI01N£
DI«£NZ(A,h)ACRIDlN£
D
T
T
T
S
T
T
T
D
D
D
D
D
U
D
D
0
D
D
D
0
0
U
0
l>
U
0
D
D
0
D
D
U
D
6
6
6
b
3
6
B
b
< 7
1
0
0
1
3
0
0
1
0
6
0
0
0
0
U
0
0
0
0
0
U
b
2
U
U,
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
50E 03
BOE Ob
80E Ob
90E 04
but 01
9oE 04
7oE Ob
70E 05
60E 00<
OOE 01
OOE-01
OOE-01
60E 02
70E 02
OOE-01
OOE-01
9oE 02
OOE-01
10E 00
OOE-01
OuE-Ol
OOE-01
OOE-01
OOE-01
OOE-01
OuE-Ol
OOE-01
OOE-01
OOE-01
OuE-Ol
40t 02
30E 01
Oot-Ul
OOE-01
6.
b.
1.
/.
3.
1.
4.
i.
0.
0.
0.
0.
0.
0.
0.
0.
o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
bOE 02
70E 02
bOt 02
41E 01
60E 01
93E 01
OOE-01
bOE-02
OOE-ol<
OOE-01
OOt-01
oot-oi
oot-oi
OOE-01
OOE-01
OOE-01
wot-01
OOE-01
oot-oi
oot-oi
uot-oi
oot-oi
oot-oi
oot-oi
OOE-01
oot-oi
OOE-01
oot-oi
OOE-01
oot-oi
oot-oi
oOE-oi
OOE-01
ooE-oi
3.83t Ob
3.34E Ob
B.72E 04
<4.40t 04
2.12E 0<4
1.14E 04
-------
PHUUUCT GAS PAHTiCULATE, ECULUUY IMPACT
DMEG NU.
COMPOUND NAME
TYPE CONC US
E-o 1,/SCM
wub
LCCAT
12 A 020* P
10 C 040*
15 A loO
21 b 040* P
20 B 040*
23 B 100*
21 D 040*
dl B 100*
38 A 010
21 B 080*
49 A 010 P
36 A 010
17 B 060
17 A OtiO
34 A 010
7b A 010 P
72 A 010
33 A 010
71 A 010 P
21 B 0«0* P
54 A 010 P
28 A 010
35 A 010
62 A 010
61 A 010 P
32 A 010 P
51 A 010
50 A 010
84 b 010
31 A 010
57 A 010
e>6 A 010 P
74 A 010
84 F 010
i
LO
Ul
N-NITKOS001METHYLAM1NE
AMINOTOLUENES
BIPHENYL
BENZ(A)ANTHHACENE
OINITKO-P-CHESOLS
DIHYU^OACKIUNE
D1BENZO(A, DPYWENE
BENZO(C)PHENANTHKENE 4 AL*YL UEKIvATIVES
ALUMINUM
3-METHYLCHULANTHKENE
AKSEN1C
BAKIUM
l-CHLOkO-4-NITRUBENZENE
D1NITROTOLUENES
CALCIUM (AS CA+2)
COHPEK
IrtuN (AS F6 + 2)
MAGNESIUM
MANGANESE
BENZIA)ANIHKACENE
SELENIUM
SODIUM
STKUNTIUM
TITANIUM
ZINC
HEKYLLIUM
BISMUTH
otfUMINt
CEKIUM
CESIU^
CHLOWINE (AS CL-J
CHROMIUM
COBALT
OfSPKOSIUM
0
D
I)
L)
0
0
0
I)
u
0
0
0
0
D
0
D
D
U
D
D
U
D
L)
U
0
S
S
S
S
S
S
S
S
S
O.OOE-01
O.OOE-01
1.20E 02
1.70E 03
O.OOE-01
9. 10E 01
O.OOE-01
9.70E 0v£ 00
> 3.20E 03>
d. 80E 0 1
i.aoE 01
1 . 7i>E 00
O.OOE-U1
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
0 .OOt-wl
U.OOt-01
0. uuE-ul
o.yoE-oi
o.uOE-ol
o . uo«- -ul
o.ooE-oi
O.OOE-01
u.oot-ui
U .UOt-Ul <
U.UOE-OI
o.oot-ul
O.OOE-01
o.oot-oi
O.OOE-01
o.OOc-Ul
O.OOE-OI
O.OOE-01
o.oot-ul
O.OOt-01
0. OOt-01
O.OUE-Ul
o.uot-oi
o. UOE-U 1>
O.OOE-01
0. ui/t-0 1
O.OOE-U1
O.UUE-01
o.oot-oi
u.OOt-ul
u.oot-oi
O.yOt-01
o.uot-oi
o.oot-oi
O.OOE-01
O.OOt-01
o.oot-oi
O.UOt-ul
o.oot-oi
o.oot-oi
0.00t-v>l
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-ui
O.uOt-01
u. jot-oi
O.OOt-01
o. oot-ui
o.oot-oi
0. OoE-ul
O.OOt-01
o. uot-ui
O.OOt-01
O.uOt-01
0 . U 0 1 - 0 1
O.OOt-wl
0 . 0 0 1 - 0 1
o.oot-oi
O.UOt-Ul
o.uoE-tH
o
6
3
i
6
6
3
3
3
4
4
2
-------
PKOUUCT WAS PAHTICULMEr ECOLOGY IMPACT
NO.
GUWPUUNO
TYPE CUNC
E-b (i/SCM
US
LCLAF
b/S
010
010
010
010
010
56 A
39 A
44 A
o4 A
59 A
84 A dlu
46 A 010
•27 A 010
09 A 010
84 D ulO
76 A
66 A
46 A
29 A
84 C
30 A
04 E
60 A
43 A
79 A
53 A
55 A
41 A
85 B 010
45 A 010
70 A 010
85 A 010
50 A 010
61 A 010
010
010
010
ulo
010
010
010
010
010
010
010
010
010
010
010
A
63 A
37 A
82 A 010 P
02 A HO* P
02 A lay* p
FLUOKINE CAS F-)
GALLIUM
GEKMANIUM
HAFNIUM, IAS
lUUliviE (AS I-J
LANTHANUM
LEAD
LITHIUM
MOLYBDENUM
NEUDYMIUM
MCKEL
NlUblUM (AS Nb*3)
PHOSPHOHUS
POTASSIUM
PRASEODYMIUM
RUBIDIUM (AS HB+)
SAMAKIUM
SCANDIUM
SILICON
SILVER
SULFUH
TELLURIUM
THALLIUM
THUHIUM
TIN
TUNGSTEN
URANIUM
ANTIMONY
YTTRIUM (AS Y*3)
ZIKCUfclUM (AS ZR + <*)
bUKON
CADMIUM
DIdHUMUCHLOKUMtTHANt
3 1.30L 03 O.OOt-Ul O.OOt-01
S 2. JOE 01 U.UOE-01
S 7.20E 00 O.OOE-U1
8 2.90E 00 O.OOt-01
S < 4.00E 00< O.OOE-U1< O.OOt-01
S 3.6Ut 01 O.OOE-U1 U.OOt-Ul
S 1.30E 02 O.OOE-U1
S 1.20E 02 O.UOE-01
S 9.70E 00 U.UOE-U1
S 9.70E 00 O.OUE-01
S l.lOt 02 O.OOt-01
S 1.3UE 01 O.OOE-01
8 > 3.20E U3> O.UOt-01> U.OOt-01
9 > 3.20k 03> O.OOE-01> O.UOb»01
8 6.4UE 00 O.OOE-01 O.OOt-01
8 < 7.00E 00< O.OOE-OM O.OOt-01
8 6.40E 00 O.OOE-01 O.OOt-01
S 1.9UE 01 O.OOE-01 O.OOt-01
8 > 6.70E 03> U.00fc-Ul> O.OOt-01
S l.lOt 02 O.OOE-U1 O.UOt-01
S > 3.50E 03> O.OOE-Oi> O.OOt-01
8 9.70E-01 0.00t-0l
8 3.20E 00 U.OOt-01
S 6.40E 00 O.OOt-01
8 1.30E 01 O.OOt-01
S 3.20E 00 O.OOE-01
S 3.20E 00 O.OOt-01
D < 3.60k 02< O.OOE-01< O.OOt-01
S 3.00E 01 O.OOt-01 0.00t-0l
8 8.7UE 01 O.OOE-01
0 5.50t 02 O.OOt-01
0 2.70E 02 u.OOE-01
O.OOt-01
O.OOt-01
O.OOE-01
O.OOt-ol
O.OOh-01
O.OOb-ol
O.OUt-01
O.OOb-01
O.OOt-01
0.00t-0l
O.UOt-01
O.OOt-01
O.UOt-01
O.OOt-01
O.OOt-01
O.OOt-01
O.OOt-Ul
8.70E OS O.OOt-01 O.UOt-01 1
0.9UE 04 O.UOE-01 O.OOt-01 2
-------
PHOUUU bAS HAKUCULATt, tLULUbY 1MPAU
COMPOUND NAME
1YPE CO^C
t-o b/SCM
LCCAf
02 A loo* P
02 A Ibd* I-'
•yd A 320* P
02 A .5 2 C * P
02 A 340* P
02 A 3 4 o * P
u 2 H o » G * P
02 b 060* P
02 n 1 o o * P
02 b loo* P
02 b 12o* P
02 H i2o* P
0 c: h 1 4 0 * P
02 b lao* P
04 A mo* P
OU A 140* 1-
04 A loO* P
04 A loO* P
,)U A IrtO* P
04 A I d 0 * P
04 H 020* P
uU r) 02u* P
04 b 040* P
04 b 04u* P
07 b 000* P
07 b ObO* P
08 0 280* P
08 D 2bO* P
ob u 3oo* P
oa u 300* P
08 0 320* P
08 U 320* P
10 C 140* P
10 C lao* P
C K U tf U K LI H M
f-KUMUf- OHM
ncXAtHLGHUtlHAfJfc
ht xACHLUKUtTHANt
i,ILHLUM.lPKUHANtS
iJlCnLbnUPKUPANES
TtTMACi-iLUKUtTnlENt
TtTKALhLUKUtTHtNt
(UChLUHUPWUPtNtS
UlChLUKOPKJPt.NtS
HtXACHLUKUbUTAuitNt
Ht.XALhLUKUbUrAUltNt
htXALHLUNUCYLLOPtNTAUltNt
ntXAtHLuPuLrCLUPcNTAuit^t
2-CHLUHOtTnYL Vi*YL tTHtK
£?-lHLUrfUt IrtYL V 1 N Y L tTHtK
A-Ll-iLUHUbUl YL tI"YL tTrltrf
A-LHLUKUbUT YL. tTnYL tTntK
LhLUKUPhfcNYL PritNYL tThttt
CrtLUHUPHtfxYL PHfNYL t'l'MtK
1 , 1 '-UIChLUKUMtTrtYL tTHEK
1 , 1 '-DILHuUKL^tTnYu ElMtW
1 , 1 '-DlLhLUKOL'ItTriYL tTHt«
1 » 1 ' -DlCHLuKOuIc Int'L tT^EK
ISOPhOKONt
1 SuPHuHONt
PHTHALATt tbltkS (rtw;194-279J
PhFHALAFt ESTthS ( M" : 194-279)
DI-2-t TMYLhtXYL PMTMAUATfc
LJl-cf-tTnYLHtxYL PhTnALATt
HUIYL h£N^YL PHlnALATt
6UTYL DtNZYU PHflALAft
HtN^ IDlNt
MtfJZIulNt
T
I
T
T
T
r
i
r
T
l
T
i
i
r
T
i
i
i
i
T
T
1
I
T
f
I
I
T
T
T
T
T
T
T
b . 7 0 1 Ob
b , 9 0 1 04
o.7ot Ob
b . 9 0 1 04
b . 7 0 1 o b
o . 9 \/t 04
b.7ot ob
tt.90t 04
b.70t Ob
b.90t 04
b.7ut Ob
8 . o u t 04
b.7ot Ob
b.90t 04
<* . 1 ot ob
4.90t Ob
a.iot Ob
4.9ot Ob
<4. loc. Ob
4.9ot ob
4. lot Ob
4 . 9 0 1 Ob
4. lot ob
4.9<)t Ob
4 . 9 0 C 0 b
3.bOt Ob
4.9oE ob
3.oot Ob
4.9ot Ob
3. out Ob
4.90t Ob
3 . o u t Ob
4.Vot ob
3.bOt Ob
0 . 0 0 1 - 0 1
o . o o L - o 1
0 . OOt-Oi
o . oot-o l
0 . OOt-0 1
O.OOt-ul
0 . OOt-0 1
o . o o t - o 1
o . oot-o i
v . OOc-0 1
0 . 0 0 t - 0 1
0 . 0 0 1 - 0 1
o.oot-oi
o.oot-i'i
o.OOt-ol
o.oot-oi
0 . OOt-0 1
o.oot-oi
o.OOt-ol
o . oOE-o 1
o.oot-ol
0 . oOt-0 1
o.oot-oi
0 . UOt-0 1
w.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
0. OOt-0 1
U. OOt-0 1
o.oot-oi
o.out-oi
0 . OUfO 1
o.oot-oi
O.OOt-01
O.oot-oi
o . oot-o i
w.oot-oi
o.oot-ol
v> . OOt-0 1
U.0()t-0l
o.oot-oi
0 . 0 0 t - 1) 1
0 . OOt-0 1
0 . 0 o t - 0 1
0 . Ont-0 1
o.oot-oi
vJ.OOt-0 I
o.oot-oi
o .oot-o i
0 . OOt-0 1
o.oot-oi
0 .OOt-0 1
o.oot-oi
O.OOt-ol
0 .OOt-0 1
o.oot-oi
0 .OOt-0 1
o .oot-o 1
O.OOt-01
O.oOt-oi
O.OOt-01
0 .OOt-0 1
u . 0 0 1 - 0 1
o.oot-oi
o.oot-ol
o.oot-ol
o.oot-oi
1
2
1
2
1
2
1
2
1
d.
1
2
i
2
a
b
4
b
4
b
4
b
4
b
b
o
b
o
b
6
b
o
•3
b
-------
u>
00
PRODUCT GAS PARTKOLATE, ECOLOGY IMPACT
DMEG NO.
COMPOUND NAME
12 A 040* P
12 A 040* P
12 A 060* P
12 A ObO* P
06 B ObO*
20 A 1<>0*
15 A ObO* P
15 A ObO* P
23 B 2^0*
23 B 240*
16 A 020* P
16 A 020* P
16 A 100* P
16 A 100* P
16 A 120* P
16 A 120* P
16 A 140* P
16 A 140* P
16 A 160* P
16 A IbO* P
16 A 200* P
16 A 200* P
17 A 020* P
17 A 020* P
17 A Ottl* P
17 081* P
17 084* P
17 084* P
18 020* P
18 020* P
18 142* P
18 142* P
19 A 020* P
19 A 020* P
N-NITKUSOUIETHYLAMINE
N-NITKOSOUIETHYLAMIWE
N-NlTfcOSOOIPHUPYlAMlNt
N-NITHOSODIPKOPYI.AWINE
6-PHUPIULACTONE
2,4,6-THINITkOPHENOL
ETHYL BENZENE
ETHYL BENZENE
DlbtNZCA,J)ACKlDlNE
DIBEN2(A,H)ACKIDINE
CHLUkOBEMZtNt
CHLOROBENZENE
, 2-lHC*LUKOBENZtNE
,2-DICHLORlWtNZENE
r 3-DICHLOKObtNZE»E
, 3-UICHLUROBENZtME
,4-OICHLOR06ENZ£HE
lr4-DICHLGROb£NZENE
PULYCMLORINATED BENZENES
POLYCHLOfUNATtD BENZENES
CHLOkUNAPttTHALENES
CHLURUNAPHTMALENES
NITROBENZENE
NlTKOBENZtNt
2,6-DlNITROTOLUENE
2»b-DINIT«OTOLU£N£
2,4-DlNITKOTULUENE
2f4-L)iNlTK01ULUENE
PHENOL
PHENOL
2f4-XYLENOL
2/4-XYLENOL
2-CHLOHOPHtNOL
2-CHLOROPHENOL
TYPE CONC US
E-b U/SCM
LCCAT
b/S
T
T
T
T
u
L>
r
T
D
U
T
T
T
I
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
4.90E 05
3. toOt 06
4.90E 05
3.60E 06
O.OOE-01
O.OOE-01
8.90E 04
6.80E 05
O.OOE-01
O.OOt-01
8.90E 04
6.80E 05
8.90E 04
6.80E 05
8.90E 04
to.BOt 05
6.90E 04
b.dOE 05
8.90E 04
to.SOE Ob
8.90E 04
b.80E 05
4.10E 05
4.9oE 05
4. lot 05
4.90E 05
4. lot 05
4.90E 05
4.90E 05
3.bOE Ob
4.90E 05
3.toOt 00
4.90E 05
3,6Wt 06
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOt-01
o.ooE-01
O.OOt-ul
o.oot-oi
O.OOE-01
O.OUE-U1
u.wot-oi
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
O.OOt-01
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.uot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.out-ui
O.OOt-Ul
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-Ul
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.wot-oi
b
b
b
b
b
b
2
i
to
b
2
3
2
3
d
3
2
3
<:
3
2
3
4
5
4
3
4
5
b
o
b
6
b
6
-------
OMEG UU.
PKJOUCT GAS PArtTlCuLATt, tCUl_Ut»Y IMPACT
CUMPUUNU iMAME. TYPt CU^C
US
LCL.AT
19 A t'UO* P
19 A 040* P
19 A Ooo* P
19 A Ot>0* P
19 H 022* P
19 b 022* P
20 A 020* P
20 A 02i,* P
20 A uoo* ?
20 A ObO* P
20 A 101* P
20 A 101* P
20 B 020* P
20 b u20* P
21 A 020* P
21 A 02o* P
21 A 100* PH
21 A too* PH
21 A 120* PH
21 A 120* PH
21 A 14U* P
21 A 14U* P
21 A loo* P
21 A 1BO* P
21 o 120* P
21 rt 120* P
21 t< lao* P
21 H 1«0* P
21 (.) 0«0* PH
21 1) HbO* PH
22 A 020* PH
22 A 020* PH
22 b O4'j* P
22 b (>4o* P
m •
i
OJ
2»4-UICHI_UKUPHENUL
2»4-UiCHLUKuPHENUL
PENTACHLOKUPHt-NUL
PE'-UALHLOKUPhtNUL.
CHLOKlNATtD-M-CKESULS
CriLUNlNATtO-M-CHtSOLS
2-NlVKUPhtNUL
2-^ITKUPHE.NUL
4-NlTKOPHtNUL
4-NITK'jPHtNUL
2 » 4 - D I N I TKOPHtMJL
2»4-01NlTKUPHt^UL
4,0-L-lNlTKU-U-CKESuL
4»b-UlNlTWU-cJ-CKtbGu
NAPHTHALt.Nt
NAPHTHALENE
ACENAPHTHEMt
ACtNAPrtTHtNt
ALtMAPnTHYLtNE
ACtNAphTHYLtNE
ANT HHACtfvt
ANTHKACtNt
PHENAisTHrttNt
pHtNANThRtNt
CHKYbEuC
CHhYbtNt
PYKtl^E
i Y ^* t> r^ t
•JL.I-. J ( \ t f tJ T It^tk^Vl C i J P
t'C.f't ^ ' V v*'d x •l—'> I y. C- *i L.
HtNZU(&HlJPEPYLt"«t
FLUUKtNE
FLUUKtNE
PLUUWANTHENt
FLuOP-ANThtNt
T
T
T
T
T
I
T
r
T
T
T
1
T
T
1
T
T
T
T
T
1
1
T
T
T
T
1
T
T
T
T
T
T
f
4.9>>E Ob
3 . b w t 0 o
4.9ut Ob
3.bOt 00
4.9\;t Ob
3 . b u t 0 b
4 . 9 M E Ob
i . b U t Oo
4.*<>t ob
3 • bOt Oo
4 . S u t Ob
3.bUc. 06
4 . 9 0 1 Ob
3.faOt 00
«.90t 04
o.but Ob
tt . 9 0 E 04
b.ttfE ub
tt . 9 0 1 04
b.bot ob
6 . 9uE 04
o.but Ob
e.9ut 04
b.bOt Ob
b. 9uE 04
o.but Ob
0.90E 04
o . ft (/ 1 Ob
a . vot 04
b.bot Ob
b . 9 1. E 04
o . b u t o b
ti.vut 04
o.but 'J b
O.OOt-0 1
VJ . OOt-0 1
o . oot-oi
o.oot-oi
o.oot-oi
o .yot-o 1
u.OOt-ul
W . UOt-0 1
0 . U 0 t - U 1
U.OOt-ul
0 . U Ut-v; 1
0 . OOt-u 1
U . UOt-U 1
0 . UUt-Y 1
U . u 0 1 - 'J 1
o . oot-u l
0 . OOt-v 1
U . u 0 1 - 0 1
0 .uUt-u i
0 . 0 0 1 - 0 1
u.yot-oi
\>.out-ui
0 .UOt-0 1
o.uot-oi
'J.UUt.-wl
o . u 0 E - u i
0 . 0 0 1 - 0 1
u . out-o i
o. out -01
0 . 0 U t - U 1
o.out-ul
0 . U 0 1 - 0 1
U.OlJt~Ol
0 . OUt-U 1
o.oot-oi
O.OOt-01
O.uOt-01
o.oot-oi
U.OOt-01
O.vjOt-01
0 . 0 U t - U 1
u.uot-ul
u.OOt-01
0 . 0 0 1 - 0 1
U.OUt-Oi
0 . l/Ot-0 1
U.OOt-01
u.OOt-01
U . OUt-0 1
0 . OUC.-0 1
U.OOt-Ul
o.oot-ol
u.vOt-Ul
u . OOL-U1
0 . OUL-U 1
0 . 0 0 t - 0 1
U.OOL-Ol
o . uut-u i
U.Uwt-Yl
U . OUt-u 1
O.OOt-Ul
y.0v)t.-ol
o.uot-ui
U . U')t-0 1
U . U (j t - U 1
U . U JL-Ul
O.OOt-01
U . OUt-0 1
b
o
b
b
b
b
5
o
b
0
b
o
b
o
d.
t,
d
3
d
3
d
i
d
3
a
i
2
i
d
5
d
3
c.
3
-------
PKOUUCT GAS HAKTICULAJE* ECOLOGY IMPACT
OMEli i
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE
FLOW RATE s 590 G/S (0.57 SCM/Sr UKY BASIS)
5.555 SCM AT 25C AND 760 Mh HG SAMPLED
TOTAL ORGANIC LOADING = 8.1 G/SCM
TOTAL TCO s 6.0 G/SCM TOTAL GRAV = 2.2 G/SCM
0.195X ORIGINAL SAMPLE TO LC
LC TCO = 6«.7 M6 LC GRAV = 2«.0 MG LC TOTAL = 88.7 MG
LCCAT ORGANIC LOADING
1 1600000.0
2 230000.0
3 660000.0
4 130000.0
5 570000.0
6 710000.0
7 2500000.0
FLOW RATE = 590.00
MINIMUM DISCHARGE SEVERITY = .010
STATE: GAS, UNJTS IN MICHOGRAMS/SCM
IMPACT: HEALTH
EXPERIMENTALY DETERMINED DATA
SPARK SOURCE DATA
-------
w
NJ
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
OMEG
OU B
04 6
02 B
12 A
08 B
42 A
20 A
10 C
10 C
10 C
10 C
10 C
12 A
10 C
23 C
10 C
10 C
10 C
12 A
23 B
10 C
20 B
20 B
20 B
20 B
10 C
23 B
02 A
14 B
21 B
21 B
21 B
21 B
21 B
NO.
020*
020*
140*
020*
060*
070
120*
100*
040*
043*
042*
041*
040*
100*
IbO*
041*
043*
042*
040*
100*
220*
042*
041*
020*
040*
220*
240*
3ttO*
020
106*
102*
103*
106*
107*
P M
P M
P W
P M
W
M
P
W
P
M
P M
W
W
W
COMPOUND NAME
l,t'-DICHLOROMfcTHYL ETHER
1,1'-DICHLOROMETHYL ETHER
HEXACHLOROCYCLOPENTAOIENE
N-NITKOSODIMETHYLAMINE
B-PROPIOLACTUNE
CARBON MONOXIDE
2r4,6-TRINITROPHENOL
1,4-DIAMINOBENZENE
AMINOTOLUENE3
4-AMINOTOLUENE
3-AMINOTOLUENE
2-AMINOTOLUENE
N-NITROSOUIETHYLAMINE
1,4-DIAMINOBENZENE
DIBENZO(C,G)CARBAZOLE
2-AMINOTOLUENE
4-AMINOTOLUENE
3-AMlNOTOLUtNt
N-NITHOSODIETHYLAMINE
D1HYDROACKIDINE
2-AMINONAPHTHALENE
2,6-DlNlTRO-P-CRE30L
3»S-DINITRU-P-CRESOL
4,6-DINITRO-O-CRESOL
UINITRO-P-CKESOLS
2-AMINONAPHTHALENE
DIBENZ(A,H)ACRIDINE
HEXACHLOROCYCLOHEXANE
DIMETHYL SULFOXIUE
7-METHYL BENZO(C)PHENANTHHENE
1-METHYL BENZO(C)PHENANTH*E«»E
2-METHYL bENZO(C)PHENANTH*ENE
2-ETHYL BENZO(C)PHfNANTHRENE
8-METHYL tJENZOtCJPHfcWANWIflK
TYPE CONC
E-6 (i/SCM
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
5. Tut
1.30E
1.60E
7.10E
2.SOE
3.00E
7.10E
7.10E
7.10E
7.10E
7.10E
7.10E
7. lOt
5.70E
5. TOE
5.70E
5.70E
5.70E
5.70E
7. lOt
7.10E
7.10E
7.1UE
7.1UE
7.10E
S.7VE
7.10E
1.60E
2.SOE
6.60E
6.60E
6. 6Ut
6.60E
6.*0t
Ob
OS
06
OS
06
Ob
OS
OS
OS
05
OS
05
05
05
05
05
05
OS
05
OS
OS
OS
OS
OS
05
OS
OS
06
06
OS
OS
OS
OS
05
OS
1.14E
2.60E
l.SOE
1.10E
7.81E
7.SOE
7.10E
7.10E
6.SOE
6.SOE
6. SUE
6.SOE
S.9U
5.70E
5.70E
S.20E
S.20E
5.40E
4.60E
4.43E
4.20E
3.60E
3.6UE
3.60E
3.60E
3.4UE
3.22E
3.20E
3.10E
3.00E
3.00E
3.00t
3.00E
3.00E
05
04
04
04
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
U3
03
03
03
NDS
U/S
6.72t
l.S3£
8.60E
6.44E
4.60E
4.42E
4.201:
4.20t
3.80b
3.8Ub
3.80E
3.80E
3.SOL
3.40k
3.40E
3. 10E
3. lot
3. lUt
2.60b
2.6lt
2. Sot
2.10E
2. lot
2.UE
2.10E
2.00E
1.VOE
i.vot
1.82t
l.bOt
1.60E
l.ttOt
l.BOE
l.eot
07
07
06
06
06
06
06
06
06
06
U6
06
06
06
06
06
06
06
06
06
Ob
06
06
Ob
06
06
U6
06
06
06
06
06
06
06
LCCAT
S
4
1
6
7
6
6
6
6
6
6
6
5
S
S
S
S
S
6
6
6
6
6
b
5
b
1
7
3
3
3
3
3
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
OMEG NO.
COMPOUND NAME
TYPE CONC OS
E-6 G/SCM
WDS
G/S
LCCAT
21 B 104*
21 B 10A*
21 B 105*
21 B 109*
21 B 101*
21 B 10B*
20 B 042*
20 B 020* P
20 B 041*
23 B 220*
06 A 121*
06 A 123*
08 A 120*
08 A 122*
08 B 060*
02 B 140* P
10 C 081*
10 C 080*
10 C 062*
19 A 060* P
10 C 083*
13 A 100*
23 C 160*
10 C 200*
02 A 180*
13 A 100*
10 C 081*
10 C 082*
10 C 063*
19 A 060* P
10 C 060*
21 B 10B*
21 B 102*
21 B 101*
W
W
W
H
W
W
W
W
W
5-METHYL BENZO(C)HHtNANTHKENfc
N-PROPYL BENZO(C)PH£NANTHKENE
6-METHYL BENZO(C)PHENANTHRENE
6-ETHYL BENZO(C)PHENANTHRENt
BENZO(C)PH£NANTH«£NE
ISOPROPYL BENZOCUPHENANTHRENE
2»6-DlNITRO-P-CRESOL
4,6-DINITRO-O-CRESOL
3f5-DINlTRO-P-CR£SOL
DIBENZ(A,J)ACRIOINE
MYRISTIC ACID
STEARIC ACID
SATURATED LONG CHAIN ACIDS (M*t226-2B5)
PALMITIC ACID
B-PROPIOLACTONE
HEXACHLOROCYCLOPENTADIENE
0-ANISIDINE
ANISIDINES
M-ANISIDINE
PENTACHLOROPHENOL
P-ANISIDINE
BENZENETHIOL
DlBENZO(CfG)CARBAZOLE
1-AMINONAPHTHALENE
DIBROMODICHLOROMETHANE
BENZENETHIOL
0-ANISIDINE
M-ANISIDINE
P-ANISIDINE
PENTACHLOROPHENOL
ANISIDINES
ISOPROPYL BENZOCUPHENANTHRENE
1-METHYL B£NZO(C)PHENANTHR£NE
BENZO(C)PHENANTHRENE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
6.60E
6.60E
6.60E
6.60E
6.60E
6.60E
5.70E
5.70E
5.70E
7. 10E
2.50E
2.50E
2.50E
2.50E
7,
,10E
2.30E
7.10E
7.
7.
7.
7.
7.
1.
7.
1.
5.
5.
5.
5.
5.
5.
2.
2.
2.
lot
10E
10E
10E
10E
30E
10E
60E
7ot
70E
70£
70E
70E
70E
3o£
30E
30E
05
05
05
05
05
05
05
05
05
05
06
06
06
06
05
05
05
05
05
05
05
05
05
OS
06
05
05
05
05
05
05
05
05
05
3.00E
3.00E
3.00E
3.00E
3.00E
3.00E
2.90E
2.90E
2.VOE
2.64E
2.50E
2.50E
2.50E
2.50E
2.
,21t
2.10E
1.
1 .
1.
1 .
1.
1 .
1.
1.
1.
1.
1.
1.
I.
1.
1 ,
1 .
1.
1 .
42E
42E
42E
42t
42E
*»2E
30E
-iOt
14E
14E
14E
14t
l<4t
14E
i4t
ua£
04E
0<«E
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
l.bOE
l.bOE
1.60E
l.bOt
l.bOE
l.bOE
1.70t
1.70t
1.70£
1.70t
1.50E
l.bOE
i!sot
1
1
b
0
b
6
b
b
7
7
6
6
6
6
6
6
6
6
6
6
4
,30t
.23t
•
4
«
•
•
.
•
•
•
•
•
9
•
•
•
•
•
•
,40t
,40t
<40t
,<40t
<40£
40t
70t
bOt
74t
72t
72t
72t
72E
72t
72t
20E
20t
20b
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
06
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
o5
3
3
3
3
3
3
5
5
5
6
7
7
7
7
6
2
6
6
0
6
6
6
4
6
1
5
5
5
5
5
5
d.
£
2
W
-------
P3
I
PRODUCT CAS OM6ANIC MODULE COMPOSITE, HEALTH IMPACT
DMEG
COMPOUND
21 B 103*
21 B 109*
21 B 10A*
21 B 108*
21 B 107*
21 B 105*
21 B lOb*
21 B 104*
10 C 200*
13 A 140*
06 A 140*
13 A 140*
08 A 120*
08 A 121*
08 C 060*
08 A 122*
10 C 140* P
08 A 123*
21 D ObO*
47 A ObO P
08 A 120*
08 A 122*
08 A 123*
08 A 121*
08 C ObO*
17 B 040*
10 C 140* P
17 B ObO*
12 B 020*
10 C 120*
20 A 100*
20 A 102*
20 A 101* P
19 4 090*
N
N
H
N
M
H
M
2-METHYL BENZO(C)PHENANTH«ENE
6-ETHYL 8ENZO(C)PHENANTHRENE
N-PROPYL BENZO(C)PHENANTHRENE
2*ETHYL BENZOCOPHENANTHRENE
8-METHYL BENZO(C)PHENANTh«ENE
6-METHYL BENZO(C)PHfcNANTHREN€
7-METHYL BENZO(CJPHENANTHRENE
5-METMYL BENZO(C)PHkNANTHHENE
1-AMINONAPHTHALENE
PEKCHLOROMETHANETHIOL
OLEIC ACID
PERCHLOROMETHANETHZOL
SATURATED LONG CHAIN ACIDS (MMt228*i85)
MYRISTIC ACID
6-HEXANELACTAM
PALMITIC ACID
BENZIDINE
STEARIC ACID
DIBENZO(A,L)PYRENE
AMMONIA
SATURATED LONG CHAIN ACIDS (MMl226-2d5)
PALMITIC ACID
STEARIC ACID
MYRISflC ACID
b-HEXANELACTAM
l«CHLORO-2-NITROBENZENE
BENZIDINE
1-CHLORO-4-NITROBENZENE
N-METMYL-N-NITROSOANILINE
4-AMINOBIPHENYL
DINITROPHENOL8
2,5-OINJTROPHENOL
TYPE CONC US
E-6 U/3CM
H03
LCCAT
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
0
T
T
T
T
T
T
T
T
T
T
T
T
T
r
2
2
2
2
2
2
2
2
5
7
•
•
•
.
•
.
•
.
*
.
30E
30E
30E
30E
30E
30k
30E
30k
70E
IOE
2.50E
5
7
7
7
7
7
7
6
1
S
5
S
5
5
5
S
5
7
7
7
7
.
.
.
.
.
.
.
•
.
.
•
•
.
.
.
•
.
.
.
•
i
7.
70E
IOE
IOE
IOE
IOE
IOE
IOE
60E
IOE
70E
70E
70E
70E
70E
70E
70E
70E
IOE
IOE
iOE
IOE
JOE
7.1 Of
05
05
05
05
05
05
05
05
05
05
Ob
05
05
05
05
05
05
05
05
07
05
05
OS
05
05
05
05
05
05
05
05
05
OS
OS
.
,
.
.
.
,
1.
1.
8.
7.
7.
7.
7.
7.
7.
7.
7.
b.
04E
04E
V4E
04k
U4£
04E
04E
oat
Oik
90E
bOE
12E
IOE
IOE
IOE
IOE
IOE
IOE
OOE
S.91E
5.
5.
5.
5.
5.
5.
5.
S.
5.
S.
5.
S.
70E
70E
70E
70E
70E
70E
70E
70E
bOE
50E
IOE
lot
5. IOE
03
03
03
03
03
03
03
03
03
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
S.10E 02
b.
b.
b.
b.
b.
<>.
b.
b.
6.
5.
4.
4,
4,
4,
4,
4,
4,
4,
3,
3.
3,
3,
3,
3,
3,
3,
3.
3.
3.
3.
3.
3.
3.
J.
20E
20k
20k
20k
20E
20k
20k
20k
00k
23k
50t
20k
,20k
,20k
,20k
,20E
,20k
,20E
,54E
,bOE
,40E
,40k
40k
40E
40k
40k
40E
40E
22k~
22k
OOE
OOE
OOE
OOfc
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
OS
2
2
2
2
2
2
2
2
b
b
7
5
b
b
b
b
b
b
3
5
S
5
5
5
5
b
b
b
b
b
b
6
6
-------
PRODUCT GAS ORGANIC MODULE COMPUSlTt, HEALTH IMPACT
DMEG NO.
20 A 103*
02 A 380* W
12 B 020* W
17 A ObO* W
10 C 120*
08 A 103*
08 A 104*
08 A 102*
08 A 100*
08 A 101*
22 C 020* P
22 D 020* P H
21 A 180* P W
20 A 100*
20 A 103*
20 A 101* P
20 A 080*
20 A 102*
02 b 120* P
17 A 082*
17 A 083*
17 A 080*
17 A 084* P
17 A 086*
17 A 081* P
17 A 085*
21 b 142*
21 B 141*
21 B 140*
18 B 060* *
15 6 060* W
02 A 160* P
21 b 120* P
12 A 060* P
i
.P-
Ln
COMPOUND NAME
2f 6-DINITHUPHENUL
HEXACHLOROCYCLOHtXANE
N-METHYL-N-NITROSOANILINE
4-NITRUBIPHENYL
4-AMINOBIPHENYL
CAPRIC ACID
LAURIC ACID
CAPRYLIC ACID
SATURATED LUNG CHAIN ACIDS (MW:llb-201)
CAPROIC ACID
BENZO(K) FLUOR ANT HENE
INDENO(1,2, 3-CD)PYRENE
PHENANTHRENE
DINITROPHENULS
2,6-DlNlTNOPHENOL
2f4-DIN!TROPHENOL
2-AMlNO-4,6-DIMTROPHENOL
2f5-DlNITROPHENOL
HEXACHLOROBUTADIENE
3f4-DlNlTROTOLUENE
2,A-DINITROTOLUENE
DINITROTOLUENES
2f4-DINITROTOLUENE
3,5-DINITROTGLUENE
2/6-DINITROTOLUENE
2,5-DlNITROTOLUENE
5-METHYL CHRYSENE
4-METHYL CHRYSENE
METHYL CHRYSENES
1,4-DlHYDROXYBENZENt
4,4'-DIPHENYLBIPHENYL
BROMOFORM
CHRYSENE
N-NI TRUSODIPROPYLAMINE
TYPE
1
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
CONC
E-6 b/SCM
7.10E 05
2.30E 05
5.70E 05
5.70E 05
5.70E 05
2.50E 06
2.5uE Oo
2.50E Ob
2.50E 06
2.50E Ob
6.60E 05
b.oOE 05
6.60t 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
1.60E Ob
5.70E 05
5.70E 05
5.70E OS
5.70E 05
5.70E 05
5.70E 05
5.70E 05
6.60E 05
6.60E 05
6.60E 05
7.10E 05
6.60E 05
1.60E 06
6.60E 05
7. ll)t 05
DS
S.iOE 02
4.bOE 02
4.40t 02
4.40t 02
4.40E 02
4.31E 02
*.31E 02
4.31E 02
4.31E 02
4.31E 02
4.12E 02
4.12E 02
4.12E 02
4.10E 02
4.10E 02
4.10E 02
4.10E 02
4.10c 02
3.VOE 02
3.80E 02
3.80E 02
3.80E 02
3.80E 02
3.80E 02
3.60E 02
3.80E 02
3.70E 02
3.70E 02
3.70E 02
3.60E 02
3.30E 02
3.20E 02
3.00E 02
3.00t 02
WDS
b/S
3.00E u5
2.7U 05
2.60t 05
2 .but w5
2.60t 05
2.54E 05
2.54t 05
2.54t 05
2.54L 05
2.54t 05
2.43E 05
2.43t 05
2.43t 05
2.40t 05
2.40E 05
2.40t 05
2.40E 05
2.40E 05
2.30t 05
2.24E 05
2.24E 05
2.24t 05
2.24E 05
2.24E 05
2.24E 05
2.24E 05
2.20E 05
2.20E 05
2.20t 05
2. lOt 05
l.S»4E 05
l.VOt 05
1.80E 05
1.74t 05
LCLAT
o
2
5
5
5
7
7
7
7
7
3
3
3
5
5
5
5
5
1
5
5
5
5
5
b
5
3
3
3
b
3
1
3
6
-------
PRODUCT GAS ORGANIC MODULE COMPOSlTEr HEALTH IMPACT
DMEG NO.
COMPOUND NAME
TYPE CONC
E-6 G/SCM
US
LCCAT
b/5
04 A
04 A
04 A
18 B
21 C
12 A
15 A
21 C
08 A
23 C
21 D
09 A
21 U
08 A
23 D
U2 A
02 A
03 B
03 B
23 D
02 B
02 B
02 B
22 D
22 C
21 A
08 D
08 D
08 D
08 D
08 D
23 D
16 S
17 6
050*
040*
060*
060*
160*
060*
160*
120*
140*
020*
060*
120*
020*
140*
020*
180*
320*
020*
040*
040*
100*
103*
104*
020*
020*
180*
281*
300*
283*
280*
282*
020*
020*
060*
rt
W
W
W
P
W
W
W
P
W
W
P
P M
P
P W
P
P N
W
W
W
EPICHLORHYDRIN
2-CHLORO- 1 , 2-EPOX YPROPANE
1-CHLORO- 1 , 3-EPOX YPROPANE
1,4-DlHYDROXYBENZENfc
PICENE
N-NITROSODIPROPYLAMINE
BIPHENYL
BENZO(E)PYRENE
OLEIC ACID
PYRROLE
DIBENZO(A,L)PYRENE
TETRAMETHYL3UCCINONITRILE
DIBENZO(A,H)PYRENE
OLEIC ACID
BENZOTHIAZOLE
DIBROMOOICHLOROMETHANE
HEXACHLORUE1HANE
1,4-DIOXANE
1,3-DIOXANE
METHYL BENZOTHIAZOLE
DICHLOROPROPENES
CIS-1,3-DICHLOROPROPEN£
TRANS- 1 , 3-DIChLOHOPHOPENE
INDENO(1,2,3-CD)PYRENE
BENZO(K)FLUURANTHENE
PHENANTHRENE
DIMETHYL PHTHALATE
DI-2-ETHYLHEXYL PHTHALATE
DI-N-BUTYL PHTHALATfc
PHTHALATE ESTERS (MW: 194-279)
DIETHYL PHTHALATE
bENZOTHIAZOLE
A-CHLGROTOLUENE
1-CHLORO-4-NJTROB6NZENE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
5.70E
5.70E
5.70E
5.70E
6.60E
5.70E
2.30E
6.60E
7.10E
5.70E
2.30E
5.70E
6.60E
5.70E
7. lOt
2.30E
1.60E
5.70t
5.70E
7.10E
1.60E
1.60E
1.60t
2.30E
2.30E
2.30E
7.10E
7.10E
7.10E
7.10E
7.10E
5.70E
6.60E
I.JOE
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
Ob
05
05
05
Ob
Ob
Ob
05
05
05
05
05
05
05
05
05
05
05
2.VOE
2.90t
2.VOE
2.90E
2.64E
2.40E
2.30E
2.20E
2*20t
2.11E
2. lOt
l.VOfc
1.80E
1.72E
1.70E
1.64E
l.bOt
l.bOE
l.OOt
1.51E
l.SOfc.
l.SOt
1.50E
1.43t
1.43E
1.43E
1.42t
1.42t
1 ^4 £E
1 M
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
OMEG
17
21
21
21
06
06
08
08
08
23
23
23
23
23
10
15
17
08
08
08
08
08
08
21
53
22
19
08
17
08
06
06
08
08
B
b
B
B
A
A
A
A
A
D
A
A
A
A
A
B
A
D
0
D
0
D
A
b
A
C
A
A
A
A
A
A
A
A
NO.
040* W
141*
142*
140*
102*
101*
104*
103*
100*
040*
102*
101*
100* W
103*
060*
060* W
020* P
282*
280* P W
281*
283*
300* P
080*
120* P
090
040*
040* P
040*
060* W
104*
102*
100*
101*
103*
COMPOUND NAME
1-CHLORU-2-NITROBENZENE
4-METHYL CHRYSENE
5-METHYL CHRYSENE
METHYL CHRYSENES
CAPRYLIC ACID
CAPROK ACID
LAURIC ACID
CAPRIC ACID
SATURATED LONG CHAIN ACIDS (MW:116-201)
METHYL BENZOTHIAZULE
3-CHLOROPYRIDINE
2-CHLOROPYRIDINE
CHLOROPYRIDINES
4-CHLOROPYRIDINE
ETHANOLAMINE
4,4'-DIPHENYLBIPHENYL
NITROBENZENE
DIETHYL PHTHALATE
PHTHALATE ESTERS (MW;194-279)
DIMETHYL PHTHALATE
DI-N-BUTYL PHTHALATE
DI-2-ETHYLHEXYL PHTHALATE
VALERIC ACID
CHRYSENE
HYDROGEN SULFIDE
BENZOCJJFLUORANTHENE
2>4-DICHLOROPHENOL
ACETIC ACID
4-NITKOBIPHENYL
LAURIC ACID
CAPRYLIC ACID
SATURATED LONG CHAIN ACIDS (MWU16-201)
CAPRUIC ACID
CAPKIC ACID
TYPE CONC
E-6 G/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
1.30E
2.30E
2.3uE
2.30E
7.10E
7.10E
7.10E
7.1UE
7.10E
5.70E
7.10E
7.10E
7.10E
7.10E
7.10E
2.30E
5.70E
5.70E
b.70t
5.70E
5.70E
5.70E
2.50E
2.30E
1.54E
b.60t
7.10E
2.50E
1.30E
5.70E
5.70E
5.70E
5.7UE
5.70E
05
05
Ob
05
05
05
05
05
05
Ob
05
05
05
05
05
05
05
05
05
05
05
05
06
05
06
05
05
Ob
05
05
05
05
05
05
US
1.30E
1.30E
1.30t
1.30E
1.22E
1.22E
1.22E
1.22E
1.22t
1.21E
1.20E
1.20E
l.cfOt
1.20fc
1.20E
1.20E
1.14E
1.14t
1.14c
1.14E
1.14E
1.14C
1.10E
1.04E
1.02E
1.01E
1.U1E
l.OOt
1.UOE
9.b2£
9.b2t
9.b2E
9.b2t
9.82E
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
U2
02
02
02
02
02
02
02
U2
02
02
02
02
02
01
01
01
01
01
WUS
G/S
7.70E
7.53t
7.53t
7.53E
7.22t
7.22t
7.22E
7.22t
7.22t
7.20t
7.10E
7. lot
7.10E
7. lot
7.00t
6.60E
6.72t
6.72E
6.72E
6.72E
6.72E
6.72L
6.4U
b.c^Ot
6.10E
b.yOt
6. OOt
5.90t
5.90t
5.bot
5. aot
b.ttOt
5.aot
b.bOt
04
04
04
04
04
04
04
04
04
04
04
U4
U4
04
04
U4
04
04
04
04
04
04
04
04
04
U4
04
04
04
U4
04
U4
04
U4
LCCAT
4
2
2
2
6
6
6
6
6
5
6
6
6
6
6
2
b
b
b
5
b
b
7
2
3
D
/
4
b
b
b
b
b
-------
ra
.£>
00
OMEG
23
23
23
23
16
16
16
16
10
23
21
17
17
17
17
17
17
17
19
08
21
15
15
15
15
18
18
18
18
18
18
18
18
06
A
A
A
A
b
B
B
B
A
C
C
A
A
A
A
A
A
A
A
A
C
6
B
B
B
A
A
A
A
A
A
A
A
A
NO.
101*
103*
102*
100* W
043*
042*
041*
040*
060*
180*
160*
081* P
085*
082*
086*
084* P
083*
080*
040* P
060*
120*
163*
161*
160*
162*
080* M
043*
082*
083*
041*
040* *
042*
061*
020* «
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
COMPOUND NAME TYPE CONC
E-6 b/SCM
2-CHLOROPYRIDINE
4-CHLOROPYRIDINE
3-CHLOftOPYKIDlNE
CHLOROPYRIUINES
l,4-bIS(CHLUROMETHYL) BENZENE
lf3-BIS(CHLOROMETHYL) BENZENE
1,2-BIS(CHLOROMETHYBENZENE
BIS (CHLOHOMETHYL) BENZENES
LTHANOLAMINE
DIBENZOUfGJCARBAZOLE
PICENE
2,6-DiNITROTOLUENE
2f5-0lNlTROTOLUENE
3r4-DlNITKOTOLU£NE
3»5-OlNITKOTOLUENE
2,4-DlNlTROTOLUENE
2f3-DINITROTOLUENE
DINITROTOLUENES
2r4-DICHLOROPHENOL
MALEIC ACID
BENZO(E)PYRENE
P-TEKPHENYL
0-TERPHENYL
TERPHtNYLS
M-TERPHENYL
ETHYLPHENOLS
P-CRESOL
M-ETHYLPHENOL
P-ETMYLPHENOL
M-CRESOL
CRESOLS
0-CRESOL
0-ETHYLPHENOL
ETHVLENE GLYCQL
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S.70E
5.70E
5.70E
S.70L
6.6UE
6.60E
6.60t
6.60E
5.70t
5.70E
2.3UE
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
5.70E
2.50E
2.30E
6.60E
6.6UE
6.60E
6.60E
7.10E
7. lOt
7.10E
7.10E
7.10E
7.10E
7.1UE
7.1UE
7. Hit
05
05
05
05
Ob
05
05
05
05
05
05
05
05
05
05
05
05
05
05
06
05
05
05
05
05
05
05
05
05
05
05
05
05
05
us
9.70E
9. 706
9.70E
9.70E
9.60£
9.60E
9.60E
9.60E
9.50E
9.50£
9.20E
6.70E
6.70E
8.70E
8.70£
8.70E
8.70E
8.70E
8.14E
7.81E
7.70E
7.33E
7.i3E
7.33t
7.33E
7.10E
7.10E
7.10E
7.10E
7.10E
7.10E
7.10E
7.10E
7. lOt
01
01
01
01
01
01
Ul
01
01
01
01
Ul
01
01
01
01
01
01
01
01
Ul
01
01
01
01
01
Ul
01
01
01
01
01
01
01
WDS
b/5
5.70t
5.70E
5.70E
5.70t
5.64t
5.64t
5.64t
5.6<4t
5.60t
S.60t
5.42t
5. lit
5.1U
5. lit
5.11E
5. lit
5. lit
5. lit
4.80t
4.60t
4.52t
4.32t
4.32t
4.32t
4.32E
4.20t
4.20t
4.20t
4.20E
4.20E
4.20E
4.20t
4.c!0t
4.^0£
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
LCCAT
5
5
5
5
i
i
3
3
5
5
2
4
4
4
4
4
4
4
5
7
2
3
3
i
3
6
6
6
6
6
6
6
6
6
-------
DMEG NO.
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
COMPOUND NAME TYPE CONC US
t-6 (i/SCM
LCCAT
G/S
26
08
21
04
04
04
23
14
08
21
07
18
18
10
18
18
06
18
18
18
02
1C
16
It}
18
18
18
18
18
18
18
01
04
23
A
b
C
A
A
A
b
A
b
D
B
A
A
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
A
A
A
b
B
b
020 W
080*
060*
050* W
040* rt
060* W
200*
020 *
041*
020*
100* W
040* w
080* rt
043*
041*
063*
020* W
042*
082*
081*
120* P
160* P
162*
161*
144*
143*
140*
146*
145*
141*
142* P
220 W
100*
200*
TRIETHYL PHOSPHATE
Y-bUTYROLACTONE
D I BENZC A, C) ANTHRACENE
EHICHLORHYDKIN
2-CHLORO-l,2-EPOXYPKoPANE
1"CHLOKO-1,3-EPOXYPROPAN£
bENZ(C)ACRIDIN£
btNZENESULFONlC ACID
2-HYDROXYBENZOIC ACID
DlbENZO(A,H)PYRENE
CAMPHOR
tRESOLS
ETHYLPHENOLS
P-CRESOL
M-CRESOL
P-ETHYLPHENOL
EfHYLENE GLYCOL
0-CRtSOL
M-ETHYLPHENOL
0-ETHYLPHENOL
HEXACHLORUbUTADlENt
POLYCHLORINATED tttNZENES
HEXACHLURObENZENE
1,2,4-TRICHLOR08ENZENE
2/6-XYLENOL
2,5-XYLENOL
XYLtNOLS
3,4-XYLENOL
3,5-XYLENUL
2,3-XYLENOL
2,4-XYLENOL
DICYCLOPENTADIENE
2,2'-i>ICHLOKuDIItiOPKOPYL ETHEH
BENZCOACKIDINE
r
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
2. Sot
d.50t
6.60L
1.3ot
1.30t
1.30t
7. lot
2.5ot
2.50t
2.3oE
7.1ut
5.70E
5.70t
5.70E
5.70E
5.7UE
5.70E
5.70E
5, 70t
5. 70E
2.30E
6.60E
6.60E
0.60E
7. lot
7.1ut
7. lot
7.10E
7. lOt
7.10E
7.10E
1.60E
5.70E
5.70E
06
06
05
u5
05
05
05
06
06
05
05
(/5
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
Ob
05
05
L O yi C
^\ O /I L
6. 70t
6.50£
6.50E
6.50t
6.50E
6. 30t
6..50t
0.21E
5. "VIE
5.70t
5.70t
5.70E
5.70E
5. 70£
5./OE
5.70t
5.70E
5.70E
5.60t
5.50E
5.50t
5.50E
5.50E
5.50t
5.50E
5.50t
5.50E
5.50E
5.50E
5.33E
5.20E
5.
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE* HEALTH IMPACT
DHEG
23
04
08
23
23
07
23
02
16
23
20
23
23
IB
18
18
18
18
18
18
09
21
08
23
05
23
23
23
25
23
23
23
18
10
C
A
D
C
C
B
A
A
B
B
A
B
B
A
A
A
A
A
A
A
A
C
D
A
B
A
A
A
A
A
A
A
A
C
NO.
QUO*
140* P
080*
020*
140*
100* M
020*
100* P
020* M
021*
060* P
020*
022*
141*
143*
140*
144*
142* P
145*
146*
120* *
040*
080*
145*
100* M
140*
144*
141*
146*
142*
143*
020*
020* P
020*
COMPOUND NAME
INDOLE
2-CHLOROETHYL VINYL ETHER
METHYL METHACRYLATE
PYRROLE
DIBENZO(A,I)CARBAZQLE
CAMPHOR
PYRIDINE
BRUMOFORM
A-CHLOROTOLUENE
QUINOLINE
4-NITROPHENOL
QUINOLINES
ISOttUlNOLINE
2,3-XYLENUL
2r5-XYLENOL
XYLENOLS
2,6-XYLENOL
2,4-XYLENOL
3,5-XYLENOL
3»4-XYLENOL
TETRAMETHYLSUCCINONITRILE
BENZO(G)CHRY9ENE
METHYL METHACRYLATE
3,4-DIMETHYLPYRIDlNfc
1-PHENYLETHANOL
OlSUbSTITUTED POLYSUBSTITUTED ALKYL PYRIDINES
2,6-DIMETHYLPYRIOINfc
2»3-DIMETHYLPYRIDlNfc
2* 3,4,6-TETRAMETHYL PYRIDINE
2, 4-DIMETHYLPYRIOINE
2»5-l)IMETHYLPYRIDINfc
PYRIDINE
PHENOL
ANILINE
TYPE CONC
E-6 (i/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
5. TOE
5. TOE
7. lot
1.30E
S.70t
5. TOE
7.10E
2.30E
2.30E
7.10E
7.10E
7.10E
7.10E
5.70E
5.70E
5.70E
5.70E
5.70E
5.70E
5.70E
1.30E
6.6UE
5.70E
7.10E
7.10E
7.10E
7.10E
7.10E
7. lot
7.10E
7.10E
5.70E
7.10E
7.JQ€
05
Ob
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
US
5. dot
5.20E
5.10E
4. tilt
4.BOE
4.00E
4.73E
4.60E
4.60t
4.43E
4.43E
4.43E
4.43E
4.40E
4.40E
4.40E
4.40E
4.4UE
4.<40E
4.40E
4.33E
4.12E
4. 10t
3.V4E
3.94E
3.94t
3.94E
3.94E
3.94E
3.94E
3.94E
3.80E
3.73E
3.73E
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
VI
NDS
Wb
3.10E
3. lot
3.00t
2.84E
2.bOb
2.60E
2.80b
2.7lt
2.7lh
2.6U
2.6U
2.6U
2.61E
2.60t
2.60t
2.60L
2.60E
2.60t
2.60E
2.60L
2.60t
2.43t
2.40E
2.32t
2.32L
2.32E
2.32k.
2.32E
2.32t
2.32t
2.32E
2.24t
2.20E
2.20t
04
04
04
04
04
04
04
04
04
04
04
04
04
U4
04
04
04
04
04
04
04
04
04
U4
04
04
04
04
04
04
04
04
04
04
LCCAT
5
5
6
4
S
5
6
2
2
0
6
6
6
5
5
5
5
5
5
b
a
3
b
6
b
6
0
6
6
6
6
5
6
6
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
OMEG
03
03
23
23
23
20
02
18
2
-------
Ul
NJ
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
DMEG
23
18
18
16
16
02
02
20
18
10
07
10
10
10
10
10
10
10
10
08
17
09
15
IS
15
15
23
19
19
25
la
16
25
16
c
A
A
A
A
A
A
A
B
D
B
C
C
C
C
C
A
C
C
A
A
A
B
B
B
B
C
B
B
A
A
A
B
4
NO.
120*
162*
163*
161*
160*
360*
361*
040*
020*
020* H
080* P
060*
065*
062*
063*
066*
080*
061*
064*
040*
020* P
100*
163*
160*
162*
161*
100*
021*
020* W
042*
1U3*
100*
040* M
102*
COMPOUND NAME
BENZO(A)CARBAZOLE
4-ETMYL-O-CRESOL
2-ETHYL-P-CNESOL
6-ETHYL-M-CRESOL
ETHYL CRESOLS
BROMUBUTANES
1-BRUMOBUTANE
3-NITROPHENOL
CATECHOL
N,N-DIMETHYLANILINE
ISOPHORONE
DIMETHYLANILINES
3,4-XYLIDINE
2,4-XYLIDlNE
2»5-XYLIDINE
3,5-XYLIDINE
1,2-DIAMlNOETHANE
2r3-XYLIDlNE
2,6-XYLIDlNE
ACETIC ACID
NITROBENZENE
1,3-DICYANO-l-HYDROXYBUTANE
P-TERPHENYL
TERPHENYL8
M-TERPHENYL
0-TERPHENYL
METHYLCARBAZOLES
CHLOR1NATED-0-CRE30L8
CHLORINATED CRESOLS
3-METHYLTHIOPHENE
M-PHENYLPHENOL
PHENYLPHENOLS
0ENZO(B)THZOPHEN£
P-PHEHYLPHtH(H*
TYPE CONC
£•6 U/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
5.70E
7.10E
7.10E
7.106
7.10E
1.60E
1.60E
5.70E
5.70E.
7.10E
7.10E
7. lot
7.10E
7.10E
7.10E
7.10E
7.10E
7.10E
7.10E
7.10E
1.30E
5.70E
2.30E
2.30E
2.3UE
2.30E
5.70fc
5.70E
5.70E
5.70E
S.70E
5.70E
S.70E
5.70E
05
05
05
05
05
06
06
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
US
3.00E
3.00E
3.00E
3.00E
3.00E
2.90E
2.90E
2.90E
2.90E
2.63E
2.63E
2.63E
2.83E
2.63E
2.83E
2.63E
2.03E
2.63E
2.83E
2.83E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.50t
2. SOE
2. SOE
2.50E
2. SOE
2. SOE
2. SOE
2. SOE
wob
U/S
01 1.80E
01 1.74E
01 1.74E
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
.74E
.74E
.70t
,/OE
,70E
,70t
,70t
.70E
.70t
,70t
.70E
.70E
.70E
,70E
,70E
,70£
.70E
.53t
.52E
.SOE
.sot
.sot
.sot
.SOE
.but
.SOE
.50E
.SOE
.SOE
.SOE
.50E
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
LCCAT
b
6
6
6
6
1
1
b
b
6
6
6
6
6
4
5
2
2
^
2
b
5
5
5
5
S
5
5
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
OMEG NO.
COMPOUND NAME
TYPE CONC US
E-6 b/SCM
LCCAT
b/b
23 C 101*
25 A 040*
25 A 041*
08 A 080*
18 A 101*
19 B 022* P
23 C 102*
09 A 080*
19 B 023*
23 C 080*
18 A 162*
18 A Ib3*
18 A 160*
18 A 161*
19 A 020* P
08 C 020*
21 C OoO*
02 A 320* P
10 C 063*
10 C 060*
10 D 020* W
10 C 062*
08 A 040*
10 A 080*
10 C 064*
07 B 080* P
10 C 061*
10 C 065*
10 C 066*
08 A 060*
23 A 102*
23 A 100* W
23 A 103*
23 A 101*
3-METHYLCARBAZOLE
METHYLTHIOPHENES
2-METHYLTHIOPhENE
VALERIC ACID
0-PHENYLPHENOL
CHLORINATED-M-CRESOLS
9-METHYLCARBAZOLE
BUTYRONITRILE
CHLORINATED-P-CRESOLS
CARBAZOLE
4-ETHYL-O-CRESOL
2-tTHYL-P-CRESOL
ETHYL CRESOLS
b-ETHYL-M-CRESOL
2-CHLOROPHENOL
FURMAMIDE
01 BENZC A, C) ANTHRACENE
HEXACHLOROETHANE
2r5-XYLlDINE
DIMETHYLANILINES
N,N-D1M£THYLANILIN£
2,4-XYLIDINE
ACETIC ACID
1,2-DIAMINOETHANE
2/6-XYLIDINE
ISOPHURONE
2,3-XYLlDINE
3,4-XYLlDINE
3,5-XYLIDlNE
MALEIC ACID
3-CHLOROPYRIDINE
CHLOROPYRIDINES
4-CHLOROPYRIDINE
2-CHLOROPYRIDINE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
5.70E 05
5.70E 05
5.70E. 05
5.70t u5
5.70E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
5.7UE 05
5.7ut 05
5.7uE 05
7.10E 05
7.10E 05
2.30E. 05
2.30E 05
5.7ot 05
5.7ut 05
5.70L 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
7.10E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
2.50E 01
2.50E 01
2.50t ul
2.50E 01
2.50E 01
2.50E 01
2.50E 01
2.50E 01
2.50E 01
2.50t 01
2.40E 01
2.40E 01
2.40E 01
2.40E 01
2.40E 01
2.40E 01
2.32E 01
2.30E 01
2.30E 01
2.30E 01
2.30E 01
2.30E 01
2.30E 01
2.30E 01
2.30E 01
2.30E 01
2.30E 01
2.30E 01
2.30E 01
2.21E 01
2.20E 01
2.20E 01
2.20E 01
2.20E 01
1.50E 04
1.50E 04
l.bOt 04
1.50t 04
1.50E 04
1.50E 04
1.50L 04
l.bOE 0<4
1.50E 04
1.50E 04
1.40E oa
1.40t 04
1.40t 04
1 . 40t 04
1.40t 04
1.4QE 04
1 . 40t 04
l.aot 04
1.3at 04
1.34t 04
1.34E 04
1.34E 04
1.34E 04
1.34E 04
1.34E 04
1.34E 04
1.34E 04
1.34E 04
1.34E 04
1.30t 04
1.30C. 04
1.30E 04
1.30E 04
i.-JOt 04
5
5
5
5
5
5
5
5
5
5
5
5
5
5
6
b
2
2
5
5
5
5
5
5
5
5
5
5
5
6
4
4
4
4
-------
Ui
PRODUCT GAS ORGANIC MODULE COMPOSITE* HEALTH IMPACT
DMEG NO.
25 A 062*
25 064*
25 060*
25 061*
25 063*
18 060*
23 C 180*
04 A 200*
04 A 180* P
02 B 103*
02 B 104*
02 B 100* P
Id A 120*
47 A 080 P
08 B 080*
10 A 121*
10 A 120*
10 A 122*
10 A 123*
18 B 080*
25 A 080*
25 A 081*
16 A 161*
16 A 160* P
16 A 162*
04 B 080*
19 A 020* P
08 C 020*
17 A 040*
17 A 041*
17 A 042*
04 B 040* P
17 A 043*
4^ A 060
COMPOUND NAME
2, 4-DIMETHYLTHIOPHENE
3r4-DIMETHYLTHIOPH£NE
DIMETHYLTHIOPHENES
2,3-DIMETHYLTHIOPHENE
2»5-DIMETHYLTHIOPHENE
2-METHOXYPHENOL
DIBENZOUrGKARBAZOLE
4-BROMOPHENYL PHENYL ETHER
CHLOROPHENYL PHENYL ETHER
CIS-1 , 3-DICHLOROPROPENE
TRANS-1 , 3-DICHLOROPROPENE
DICHLOROPRUPENES
2r2'-DlHYDROXYDIPHENYL
HYDROGEN CYANIDE
Y-BUTYROLACTONE
2-AMINO-l-PROPANOL
PROPANOLAMINES
3-AMINO-l-PROPANOL
l-AMINO-2-PROPANOL
1,2,3-TRIHYDROXYBENZENE
TRIMETHYL AND TETRAMETHYL THIOPHENES
2»3,5-TRIMETHYLTMIOPHENE
1 , 2, 4-TRICHLOROBkNZENE
POLYCHLORINATED BENZENES
HEXACHLOROBENZENE
2,2'-DICHLORODIETHYL ETHER
2-CHLOROPHENOL
FURMAMIDE
NITROTOLUENES
2-N1TROTOLUENE
3-NJTROTOLUkNE
1,1 '-UICHLUHODIETHYL ETHER
4-NITROTOLUENE
CARBON DIOXIDE
TYPE CONC US
E-6 G/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
5. TOE 05 2.20E 01
5.70E 05 2.20k 01
5. TOE 05 2.20E 01
5. TOE 05 2.20E 01
5.70E 05 2.20E 01
7.10E 05 2.20E 01
1.30E 05 2.20k 01
5.70E 05 2.11k 01
5.70E 05 2.11E 01
2.30k 05 2.10k 01
2.30E 05 2.10k 01
2.30E 05 2.10k 01
7.10E 05 2.02E 01
2.22E 05 2.U1E 01
7.10k 05 2.00E 01
7.10E 05 2.00E 01
7.10E 05 2.00E 01
7.10k 05 2.00E 01
7.10E 05 2.00k 01
7.10E 05 2.00E 01
5. TOE 05 2.00k 01
5.70E 05 2.00k 01
2.30E 05
2.30E 05
2. JOE 05
S.70E 05
5.70E 05
S.70E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
1.71E 06
.91E 01
.91E 01
.VIE 01
.90k 01
.90k 01
.90E 01
,90k 01
.90E 01
.90E 01
.90E 01
.90E 01
.90E 01
WD3
G/S
1.30k 04
1.30k 04
1.30k 04
1.30k 04
1.30k 04
1.30k 04
1.30k 04
1.24k 04
1.24E 04
1.23k 04
1.23k 04
1.23k 04
1.20k 04
1.20k 04
1.20k 04
1.20k 04
1.20k 04
1.20k 04
1.20k 04
1.20k 04
1.20k 04
1.20k 04
1.13k 04
1.13k 04
1.13k 04
1.12k 04
1.12k 04
1.12k 04
1.12k 04
1.12k 04
1.12k 04
1.12k 04
1.12k 04
1.12fc 04
LCCAT
5
5
5
5
b
6
4
5
5
i.
2
2
6
6
6
6
6
6
6
5
5
2
2
2
b
b
5
b
5
b
5
5
-------
DMEG NO.
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
COMPOUND NAME TYPE CONC DS
E-6 G/SCM
LCCAT
G/S
12 A 080*
14 A 041
08 A 160*
26 B 040 W
14 A 043
14 A 044
09 b 040* W
08 A 060*
09 B 042*
09 B 020* W
09 B 041*
10 A 160*
08 B 041*
18 A 060*
07 B 120*
18 A 120*
08 B 080*
10 A 123*
10 A 122*
18 b 080*
10 A 121*
10 A 120*
05 C 040* w
16 B 040*
08 A 160*
68 A 010 P
12 A 080*
22 A 010* W
21 C 040*
10 A 160*
08 B 041*
07 B 120*
21 A 020* P
23 B 061*
w
i
Ln
N-NITROSODIISOPROPYLAMINE
9,10-ANTHRAUUINONE-1,5-OISULFONIC ACID
BENZOIC ACID
TRITOTYL PHOSPHATES
9,10-ANTHRAQUINONE-1,7-DISULFONIC ACID
9, 10-ANTHRAOUINONE-l, 8-DISULFONlC ACIU
NAPHTHONITRILES
HALEIC ACID
B-NAPHTHONITRILES
BENZONITRILE
A-NAPHTHONITRILES
CYCLOHEXYLAMINE
2-HYDROXYbENZOIC ACID
2-METHOXYPHENOL
ACETOPHENONE
2»2'-OIHYDROXYDIPHENYL
Y-BUTYROLACTONE
l-AMINO-2-PROPANOL
3-AMINO-l-PROPANOL
1,2,3-TRIHYOROXYBENZENE
2-AMINO-l-PROPANOL
PROPANOLAMINES
T-PENTANOL
1,3-DIHYDROXYBENZENE
ADIPIC ACID
CHROMIUM
N-NITKOSODIISOPROPYLAMINE
INDENE
BENZOCGKHRYSENE
CYCLOHEXYLAMINE
2-HYDKOXY8ENZOIC ACID
ACETOPHENUNE
NAPHTHALENE
2,3-DIMETHYLQUINOLINE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
T
T
T
T
T
T
T
7.10E 05
2.50E 06
2.50E 06
2.50E 06
2.50E 06
2.50E 06
5.70E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
7.1 OE 05
7.10E 05
5.7UE 05
7.10E 05
5.70E 05
5.70b 05
5.70E 05
S.70E 05
5.70E 05
5.7UE 05
5.70E 05
7.10E 05
7.10E 05
2.50E 06
1.5ot 01
5.70b 05
6.6uE 05
2.30E 05
5.70E 05
5.7ot 05
5.70E 05
6.60E 05
7.10E 05
1.90E 01
1.60E 01
1.80E 01
1.80E 01
1.60E 01
1.60E 01
1.60E 01
l.tJOb 01
1.80E 01
l.OOE 01
1.80E 01
1.00E 01
1.60t 01
1.74E 01
U/3E 01
1.02E 01
1.60E 01
l.bOt 01
l.bOE 01
l.bOE 01
l.bOb 01
l.bOt ul
l.bOE 01
l.bOE 01
1.60t 01
1.5UE 01
1.50E 01
l.bOE 01
1.43E 01
1.42E 01
1.42b 01
1.40L 01
1.32E 01
1.30E Ul
1.1 OC. 04
1.10E 04
l.lOb 04
1.10E 04
1.10E 04
i.lOt 04
l.lOt 04
l.lOt U4
l.lUb 04
l.lOb 04
l.lOb 04
1.04b 04
1 . 04b 04
1.03b 04
1.02E 04
9.60b 03
9.34b 03
9.34E 03
9.34b 03
9.34E 03
9.34b 03
V.34b 03
9.30b 03
V.30E 03
9.21E 03
8.90t 03
8.90b 03
6.70b 03
8.50E 03
6.40b 03
6.40C 03
8.20b 03
7.80b 03
7.61E 03
6
7
7
7
7
7
5
5
5
5
5
6
b
5
b
5
5
5
5
5
5
5
6
6
7
5
3
2
5
5
5
3
6
-------
OHE6 NO.
PRODUCT CAS ORGANIC MODULE COMPOtlTEt HEALTH IMPACT
COMPOUND MAKE TYPE CONC
OS
23 B 060*
23 B 062*
23 B 065*
23 B 064*
23 B 067*
23 B 066*
23 B 040*
23 B 063*
05 A 140* M
23 C 060*
05 C 040* M
23 C 061*
16 B 040*
20 020* P
18 102*
16 183*
18 181*
18 160*
23 C 040*
04 A 140* P
04 B 100*
21 A 140* P
08 D 160*
23 C 140*
23 B 060*
05 A 140* W
23 B 062*
23 B 040*
23 B 064*
23 B 061*
23 B 065*
23 B 067*
23 0 063*
2) B OH*
DIMETHYLOUINOLINE8
2»6-DIMETMYLOUINOLINE
b,8-DIMETHYL8UINOLINE
3,4-DIMETHYLQUINOLlNE
1,5-DIMETHYLI80QUINOLINE
1,3-DIMETHYLISOOUlNULlNE
2-HETHYLOUINOLINE
2,8-DIMETHYLQUINGLINE
BENZYL ALCOHOL
METHYLINDOLES
T-PENTANOL
2-METHYL1NDOLE
1 , 3-DIHYDROXYBENZENE
2-NITROPHENOL
4r6-DI-TEKT-BUTYL-M-CRESOL
2»6-DIMETHYL-4-HEPTYL PHENOL
2,4,6-TRIMETHYL METHYL PHENOL
POLYALKYLPHENOLS (MN>135)
1NDOLE
2-CHLOROETHYL VINYL ETHER
2»2'-DICHLORODII30PKOPYL ETHER
ANTHRACENE
METHYL BENZOATE
DIBENZO(A,I)CARBAZOLE
OIMETHYLQUINOLINE8
BENZYL ALCOHOL
2,6-DIMETHYLQUINOLINE
2-METHYLQUINOLINE
3f4-DIMETHVLQUINQLINE
2»3-DZM£THYLQUINOLINE
6r8»DIMETHYLQUlNOLIN£
1, S-DIMETHYLISOQUINOLINE
2,8-DJMETHrLflUJNOLINE
hWIMtJHYLlSOMlNQilHt
HDS
C/S
LCCAT
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
7.10E 05
7.10E 05
7.10E 05
7.10E 05
7.10E 05
7.10E 05
7.10E 05
7.10E 05
7.10E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
7.10E 05
7.10E 05
7.10E 05
7.10E 05
7.10E 05
1.30E 05
I.30E 05
1.30E 05
6.60E 05
7.10E Ob
1.30E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
5.70E 05
S.70E 05
5.70E OS
S.70E OS
S.70E 05
I.70E 05
.30E 01 •
.30E 01 '
.30E 01 •
.30E 01 '
.30E 01 •
.30E 01 •
.30E 01 •
.30E 01 •
,30fc 01 '
.30E 01
.JOE 01
.30E 01
.30E 01
.22E 01
.20E 01
,20£ 01
.20E 01
.20E 01
.20E 01
.20E 01
.20E 01
.20E 01
,20fc 01
.10E 01
.03E 01
.U3E 01
.OJE 01
.03E 01
.03E 01
•03E 01
.U3E 01
•03E 01
•OJE 01
.OJE 01 6
r.6it 03
r.61E 03
r.6u 03
7. bit 03
7.61E 03
7. bit 03
F.61E 03
7. bit 03
r.blt U3
7.50t 03 5
7.50E 03 5
7.50E 03 5
7.50E 03 5
7.22E 03 6
7.10E 03 6
7. lOt 03 6
7.10E 03 6
7. lOt 03 6
7. Out 03 4
7.00t 03 4
7.00t 03 4
7.00E 03 3
.90t 03 6
.aot 03 4
.lit 03 5
.lit 03 5
.lit 03 5
.lit 03 5
.lit 03 5
.HE 03 5
.HE 03 5
.lit 03 5
.lit 03 5
•ill 03 S
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
DM
23
23
23
23
23
23
23
23
23
23
23
23
10
06
20
18
16
18
07
18
07
07
07
16
16
16
06
49
12
05
23
26
23
23
EG
A
A
A
A
A
A
A
A
A
A
A
A
B
D
A
A
A
A
A
A
B
B
B
A
A
A
D
A
A
A
A
B
A
A
NO.
Ob4*
061*
080*
063*
082*
122*
120*
121*
083*
062*
OoO*
081*
100*
200*
020* P
183*
181*
180*
140*
182*
182*
181*
180*
200* P
202*
201*
160*
010 P
100*
160*
020*
020
Ob4*
120*
COMPOUND NAME
4-N-PROPYLPYRIDINE
2-ETHYLPYRIDINE
PHENYLPYRIDINES
4-ETHYLPYHIDINE
3-PHENYLPYRIDINE
2,4,6-COLLIDINE
COLLIDINES
5-ETHYL-2-METHYLPYRIDINE
4-PHENYLPYRIDINE
3-ETHYLPYRIOINE
MONOSUBSTITUTED ALKYL PYRIDINES
2-PHENYLPYRIDINE
MORPHOLINE
DIETHYL ADIPATE
2-NITROPHENOL
2,6-DIMETHYL-4-HEPTYL PHENOL
2,4,6-TRIMETHYL METHYL PHENOL
POLYALKYLPHENOLS (MW>135)
BENZALDEHYDE
4,6-DI-TERT-BUTYL-M-CHESOL
DIHYDRO-(D OR DCARVONE
CARVON£(D OK L)
CARVONES
CHLORONAPHTHALENES
2-CHLOHONAPHTHALENE
1-CHLORONAPHTHALENE
METHYL BENZOATE
ARSENIC
N-NITROSODIPENTYLAMINE
PHENETHYL ALCOHOL
PYRIDINE
TR1PHENYL PHOSPHATE
4-N-PROPYLPYRIDINE
COLLIDINES
TYPE CONC
E — 6 (j/SC^
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
r
T
T
T
T
D
r
T
T
T
T
T
7.10E
7.1ut
7. lot
7.10E
7.10E
7.10E
7. lOt
7. 10E
7. lOt
7.10E
7.10E
7.10E
7. lot
7. lot
5.70t
5.70E
5.70E
5.70E
5.70E
5.70E
7.10E
7.10E
7. lot
6.60E
6.60E
6.60E
5.70E
> 1.80E
7.10E
7.10E
1.30E
2.5uE
5.70t
5.70E
05
Ob
05
Ob
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
01>
05
05
05
Ob
05
05
DS
i.02t
1.U2E
1.02E
1.02E
1.U2E
1.02E
1.02E
1.02t
1.02t
1.02E
1.02E
1.U2E
l.Olt
9.VOE
9,o2£
9.70E
9./OE
9.70E
9.70E
9./OE
9.60E
9.60t
9.60t
9.60E
9.60E
9.60E
9.34E
9.00t
9.00E
8.80E
8.70E
6.62E
8.30E
8.30t
01
01
01
01
Oi
01
01
01
y 1
01
01
01
01
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00>
00
00
00
00
00
00
WDS
b/b
b, lot
6. lOt
6.1Ut
6.iOt
to. lot
6. lot
6. lOt
6. lOt
6.10C
6. 10E
6. lOt
6. lOt
o.oot
5.01t
5.60t
5.70t
5.70t
5.70t
5.70t
5.70t
5.70t
5.70t
5.70t
5.64t
5.b4t
5.64t
5. bit
5.31t
5.30E
5.20E
5. lit
5. lot
4.90t
4.90t
03
03
03
03
03
03
03
03
03
03
u3
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
LCCAI
b
6
b
6
6
6
6
6
6
b
b
6
6
6
5
5
b
5
5
5
6
6
6
3
3
3
5
6
6
4
1
5
b
en
1
Oi
-------
oo
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
DMEG
23
23
23
23
23
23
23
23
23
23
10
06
23
05
23
23
23
13
07
07
07
13
22
23
23
23
23
23
23
23
12
16
05
23
A
A
A
A
A
A
A
A
A
A
6
D
B
B
B
B
B
B
B
B
B
B
B
A
A
A
A
A
A
A
A
A
A
c
NO.
061*
060*
060*
063*
122*
062*
121*
061*
062*
063*
100*
200*
160*
120*
060*
140*
120*
060*
161*
160*
182*
060*
040* P N
146*
145*
140*
144*
142*
143*
141*
100*
220* W
160*
120*
COMPOUND NAME
2-ETHYLPYRIDINE
MUNOSUB8TITUTED ALKYL PYRIDINE8
PHENYLPYRIDINE3
4-ETHYLPYRIDINE
2r4,6-COLLIDlNE
3-PHENYLPYRIDINE
5-ETHYL-2-METHYLPYRIDINE
2-PHENYLPYRIDINE
3-tTHYLPYRIDlNE
4-PHENYLPYRIDINE
MORPHOLINE
OIETHYL ADIPATE
BENZO(H)QUINOLINE
BURNEOL
ACRID1NE
BENZO(F)QUINOLINE
PHENANTHRID1NE
METHYL DISULFIOE
CARVONECD OR L)
CARVONES
DIHYDRO-(D OR DCARVQNE
DIPHENYL SULFIUE
FLUOHANTHENE
2,3,4,6-TETRAMETHYL PVRIDINE
3,4-DIMETHYLPYRIUINE
DISUflSTITUTtO POLYSUB9TITUTED A4.KYL PYRIDINES
2r6-DlMETHYLPYRIOlNt
2,4-DIMETHYLPYRIOlNfc
2,5-DIMETHYLPYRIDlNt
2,3-DlMETHYLPYRIDlNE
N-MTHOSOOIPENTYLAMlNt
POLYCHLORJNATtO dlPHtl^YLS
PHENETHYL ALCOHOL
dENZO(A)CAKbAZOLt
TYPE CONC
E-6 U/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
0
T
T
5.70E
5. TOE
S.70E
5.7UE
5.70E
5.70E
5.70E
5.70E
5.70E
5.70E
5.70E
5.70E
7.10E
7.1UE
7. lot
7.10E
7.1UE
7.10E
5.70E
5.70fc
5.70E
7.10E
6.60E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30t
1.30E
S.70E
< 7.20E
5.70E
1.30E
Ob
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
Ob
05
05
05
05
05
05
Ob
05
05
00<
05
05
US
6. JOE
6. JOE
6. JOE
6. JOE
6. JOE
6. JOE
6. JOE
6. JOE
6. JOE
6. JOE
6.14E
7.91E
7.90E
7.90E
7.90E
7.90E
7.90E
7.90E
7.70E
7.70E
7./UE
7.40E
7.J3E
7.22E
7.22E
7.*2t
7.22E
7.22E
7.22t
7. HE
7.21E
7.20E
7.0JE
6.64E
00
00
00
00
00
00
00
00
00
00
00
00
00
DO
00
00
UO
00
00
00
00
00
00
00
00
00
UO
00
00
uO
00
00<
00
00
WDS
b/3
4.90t
4.90E
4.90E
4.9oE
4.90E
4.90E
4.90E
4.90E
4.90t
4.90t
4.60t
4.70E
4.70fc
4.70h
4.70t
4.70E
4.70t
4.70t
4.54E
4.54b
4.b4b
4.40E
4.J2t
4.JOfc
4.30t
4. JOE
4.30t
4.30t
4.JOb
4. JOE
4. JOE
4.24t
4.20E
4.03b
03
03
03
03
03
03
03
03
03
03
OJ
03
03
03
03
OJ
03
03
03
03
03
03
03
03
03
03
03
03
OJ
03
03
03
03
03
LCCAT
b
b
5
5
5
5
5
5
b
b
b
5
b
6
6
b
b
b
5
b
b
b
J
a
<4
4
a
a
a
4
b
i.
5
4
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE* HEALTH IMPACT
OMEG NO.
COMPOUND NAME
TYPE CONC DS
E-b U/SCM
HDS
LCCAT
15 A 143*
15 A 141*
15 A 140*
15 A 142*
18 C 040* W
13 B 080*
23 B 140*
23 B 120*
23 B 080*
23 B 160*
05 B 120*
13 B 060*
18 C 020*
09 A 100*
23 C 080*
23 C 102*
23 C 101*
25 A 041*
23 C 100*
25 A 040*
09 A 080*
25 B 040* W
25 A 042*
15 B 182*
15 B 200*
15 B 181*
15 B 180*
15 B 183*
15 B 202*
15 B 201*
15 B 203*
18 C 040* W
02 A 140* P
22 A 010* W
TERT-BUTYL BENZENE
N-BUTYL BENZENE
BUTYL BENZENES
SEC-BUTYL BENZENE
2-NAPHTHOL
METHYL OISULFIDE
BENZO(F)QUINOLINE
PHENANTHRIDINE
ACRIDINE
BENZO(H)QUINOLINE
BORNEOL
DIPHENVL SULFIDE
1-NAPHTHOL
1, 3-DICYANO-l-HYDROXYBUTANE
CARBAZOLE
9-METHYLCARBAZOLE
3-METHYLCARBAZOLE
2-METHYLTHIOPHENE
METHYLCARBAZOLES
METHYLTHIOPHENES
BUTYRONITRILE
BENZO(B)TH10PHENE
3-METHYLTHIOPHENE
lf2,4-TRIMETMYLB£NZfcNE
TETRAMETHYLBENZENES
If 2, 3-TRIMETHYLBENZENE
TRIMETHYLBENZENES
1,3,5-TRIMETHYLBENZENE
lf2f3,5-TETRAM£THYLb£NZENE
1,2,3,4-TETRAMETHYLBENZENE
1,2,4,5-TETRAMETMYLBENZENE
2-NAPHTHOL
DIBROMOCHLOROMETHANE
INDENE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
b.fcoE 05
b.bOE 05
b.bOE 05
b.bOt 05
7.10E 05
5.70E 05
5.7ot 05
S.7uE 05
5.70E 05
5.70E 05
5.70E 05
5.7o£ 05
7.10E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.3o£ 05
1.30E 05
1.30E 05
1.30t 05
1.30E 05
6.606. 05
b.bOE 05
b.60b Ob
b.bOE 05
6.60E 05
b.bOE 05
6.60E 05
b.60E 05
5.70E 05
2.30E 05
2.30E 05
b.bOE 00
b.bOt 00
b.bOt 00
b.bOE 00
b.tiOE 00
6.33fc 00
b.33£ 00
b.33E 00
b.33t UO
6.33E 00
b.33b 00
5.V3E 00
5.91E 00
5.VOt 00
5./OE 00
5.70t 00
5.70t 00
5.7o£ 00
5.70b 00
5.70E 00
5.70t 00
5.70E 00
5.70E 00
S.bOc 00
5.50E 00
5.50E 00
5.50C. 00
b.bOb 00
5.50E 00
5.50E 00
5.50E 00
5.20t 00
b.UE 00
b.llb 00
3.90E 03
3.90E 03
3.90E 03
3.VOt 03
3.bOt 03
3.73b 03
3.73E 03
3.73E 03
3.73t 03
3.73E 03
3.73b 03
3.50L 03
3.50E 03
3. SOL 03
3.33t 03
3.33E 03
3.33t 03
3.33t 03
3.33t 03
3.33E 03
3.33E 03
3.33b 03
3.33t 03
3.24C 03
3.24b 03
3.24b 03
3.24b 03
3.24b 03
3.24C 03
3.24t 03
3.24b 03
3.10b 03
3.01t 03
3,oib 03
3
3
3
3
b
5
5
5
5
5
5
5
b
a
4
a
4
i*
a
4
4
4
4
3
3
3
3
3
3
3
3
5
2
2
-------
PRODUCT GAS ORGANIC MODULE COMPt)8IT£, HEALTH IMPACT
DMEG
is
is
IS
IS
06
06
25
25
15
25
25
25
20
04
04
16
16
18
05
18
OS
18
21
01
01
02
02
25
25
OS
08
03
04
15
B
B
B
B
A
D
A
A
A
A
A
A
B
A
A
C
C
C
A
C
A
C
A
A
A
A
A
A
A
B
A
B
B
A
NO.
142*
141*
140*
120*
160*
320* P
062*
064*
160* M
063*
001*
060*
040* N
180* P
200*
020*
083*
082*
100*
060*
060*
081*
020* P
200 W
201
343*
340* P
OiO*
081*
080*
160*
060*
060*
020 P
COMPOUND NAME
1 , 4-DIHYDRONAPHTHALENE
1 , 2-DlHYDRONAPHTHALfcNE
DIHYDRONAPHTHALENES
TETRAHYDRONAPHTHALENE
BENZOIC ACID
BUTYL BENZYL PHTHALATE
2f4-DIMETHYLTHIOPHENE
3,4-DIMETHYLTHIOPHENE
BIPHENYL
2»5-DIMETMYLTHIOPHENE
2»3-DIMETHYLTHIOPHENE
DIMETHYLTHIOPHENES
DINITRO-P-CRESOLS
CHLOROPHEHYL PHENYL ETHER
4-BROMOPHENYL PHENYL ETHER
1-NAPHTHOL
S-INOANOL
4-INOANUL
I80BUTYL ALCOHOL
INDANOLS
N-BUTANOL
1-INDANOL
NAPHTHALENE
OCTANES
N-OCTANE
1,3-DICHLOROPROPANE
DICHLOROPROPANES
TRJMETHYL AND TETRAMETHYL THIOPHENES
2»3,5-TRIMETHYLTHIOPHENE
2,b-DIMETHYL-4-H£PTANUL
ADIPIC ACID
2-t THYL-4-METHYL-1 , 3-DIOXOLANE
2r2'-DICHLORODI£THYL ETHEM
0ENZENE
TYPE CUNC
DS
E-fc G/3CM
T
T
T
T
T
T
T
T
D
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
6.60E
6.60E
6.60E
6.60E
7.10E
7.10E
1.30k
1.30E
5.00E
1.30E
1.30E
1.30E
9.80E
1.30E
1.30E
5.70E
7.10E
7.10E
7.10E
7.10k
7.10E
7.10E
2.30E
1.60E
1.60E
1.60E
1.60E
1.30E
1.30k
7.10E
7.10E
5.70k
1.30E
> 1.30E
05
05
05
05
05
05
05
05
03
05
05
05
02
05
05
05
OS
05
05
05
05
05
05
06
06
06
06
05
05
05
05
05
05
04>
5.10E
5.10k
5.10E
5.10E
5.10E
5.10E
5.00E
5.00E
5.00E
S.OOE
5.00E
5.00k
4.90E
4.61E
4.61E
4.60E
4.73k
4.73E
4.73E
4.73E
4. 736
4.73E
4.60E
4.60E
4.60k
4.60k
4.60E
4.50k
4.50E
4.43E
4.43E
4.40E
4.33k
4.J3E
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
uo
00
00
00
00
00
00
00
00
00>
NDS
G/8
3.00k
3.00k
3.oot
3.ook
3.00k
3.00k
3.00k
3.00k
3.00k
3.00E
3.00k
3.00k
2.90E
2.64k
2.64k
2.60k
2.00E
2.60k
2.80E
2.80k
2.80k
2.80k
2.71k
2.70k
2.70k
2.70k
2.70k
2.64k
2.64k
2.61k
2.61k
2.60k
2.60k
2.60k
LCCAT
03
03
03
03
03
u3
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
3
3
3
3
b
b
4
4
3
4
4
4
S
4
4
b
b
b
b
b
b
b
2
1
1
1
1
4
4
6
6
5
4
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE* HEALTH IMPACT
DMEG NO.
COMPOUND NAME
TYPE CUNC
E-6 G/SCM
DS
LCCAT
U/S
17 A 040*
17 A 041*
17 A 042*
17 A 043*
04 B 040* P
02 A 360*
21 A 140* P
02 A 361*
Ob A 160*
08 D 320* P
09 8 040* W
09 B 042*
09 B 020* W
09 B 041*
05 A 060*
IB C 061*
18 C 083*
06 B 020* W
05 A 100*
IB C 082*
18 C 080*
05 C 060*
05 B 080*
08 A 180*
03 A 040* M
16 A 201*
16 A 202*
16 A 200* P
53 A 060
21 8 040* P
79 A 010 P
05 C 060*
23 C 061*
23 C 060*
w
i
ON
NITROTOLUENES
2-NITROTOLUENE
3-NITROTOLUENE
4-NITROTOLUENE
lr I'-DICHLORODIETHYL ETHEH
BROMOBUTANES
ANTHRACENE
1-BRUMOBUTANE
BENZOIC ACID
BUTYL BENZYL PHTHALATE
NAPHTHONITRILES
B-NAPHTHONITRILES
BENZONITRILE
A-NAPHTHONITRILES
N-BUTANOL
1-INDANOL
5-INDANOL
2, 3-EPOXY-.1-PROPANOL
ISUBUTYL ALCOHOL
4-INDANOL
INDANOLS
A-TERPINEUL
2,6-DIMETHYL-4-HEPTANUL
ADIPIC ACID
3-METHOXYBIPHENYL
1-CriLORONAPHTHALENE
2-CHLORONAPhTHALtNE
CHLOPONAPHTHALENES
SULFUR DIOXIDE
BENZCA)ANTHRACENE
SILVER
A-TErtPINEOL
2-METHYLINDOLE
METHYLINDOLES
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
D
S
T
T
T
1.30E 05
1.30E 05
1.30E 05
1.30E Ob
1.30E Ob
2.30E 05
2.30E 05
2.30E Ob
5.70E Ob
5.70E 05
1.30t 05
1.30E Ob
1.30E 05
1.30E Ob
5.70E 05
5.70E 05
5.70t 05
5.70E 05
5.70E 05
5.70t 05
5.70E 05
7.10E 05
5.70E 05
5.70E 05
5.70E 05
2.30E 05
2.30E 05
2.30E 05
4.20E 04
1.40E 02
3.00E 01
5.70E 05
1.30E 05
1.30E 05
4.33E 00
4.33E 00
4.33c 00
4.33E OU
4.33E 00
4.10E 00
4. 10E 00
4. lOt 00
4.10E 00
4.10E 00
4. lot 00
4.10E OU
4.10E 00
4. 10E 00
3.80E UO
3. dOE 00
3.BOE 00
3.BOE 00
3.BOE 00
3.60E 00
3.BOE 00
3.73E 00
3.6UE 00
3.60E 00
3.60E 00
3.33E 00
3.33E 00
3.33E 00
3.21E 00
3. lit 00
3.UOE 00
3. OUt 00
2.9QE 00
2.90E 00
2.60E 03
2. tout. 03
2.60t 03
2.60t 03
2.60E 03
2.42t 03
2.42t U3
2.42t 03
2.40E 03
2.40t o3
2.40t 03
2.40E 03
2.<+Ot 03
2.40E 03
2.24t 03
2.24t 03
2.24E 03
2.24t 03
2.24E 03
2.24t 03
2.24E 03
d.dOt 03
2. lOh 03
2.10E 03
2.10E 03
2. OOt 03
2. Out 03
2. Out 03
1.90E 03
l.B3t 03
l.OOt 03
l.BOE 03
l.70t 03
1.70E 03
4
4
4
14
2
2
2
b
b
4
4
4
4
5
5
5
5
5
5
5
6
5
5
5
2
2
2
3
5
4
4
-------
NJ
OMEG NO.
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
COMPOUND NAME
TYPE CONC U3
E-6 G/SCM
NDS
B/S
LCCAT
21 A
21 A
21 A
21 B
21 A
21 A
21 A
21 A
15 B
21 A
21 A
08 D
17 B
17 B
17 B
17 B
IS A
15 A
16 A
22 B
02 B
15 A
15 A
15 A
15 A
06 D
07 A
16 A
Ib A
01 A
05 B
05 A
05 B
05 A
044*
040*
080*
180* P
081*
041*
082*
083*
020*
042*
043*
240*
020*
021*
022*
023*
100*
120*
180*
040* P
080* P
142*
143*
140*
141*
240*
140*
120* P
100* P
140
062*
122*
061*
121*
2-ETHYLNAPHTHALENE
MONOALKYL NAPHTHALENES
DIHETHYLNAPHTHALENES
PYRENE
1,4-DIMETHYLNAPHTHALENE
1-METHYLNAPHTHALENE
2»3-DIMETHYLNAPHTHALENE
2»6-DIMETHYLNAPHTMALENE
INDAN
2-METHYLNAPHTHALENE
1-ETHYLNAPHTHALENE
DI-2-ETHYLBUTYL AOIPATE
METHOXYNITROBENZENES
l-METHOXY-2-NJTRUbENZENt
l-METHOXY-3-NlTROBENZENt
l-METHOXY-4-NITRObENZtNE
PROPYL BENZENE
ISOPROPYL BENZENE
2-CHLOROTOLUENE
FLUO&ANTHENE
TETNACHLOROETHENE
SEC-bUTYL BtNZENE
TERT-BUTYL BENZENE
BUTYL BENZENES
N-BUTYL BENZENE
DI-2-ETHYLBUTYL AOIPATE
BENZALDEHYDE
1,3-DICHLOROBENZENE
1 ,2-DICHLOROBENZENE
HEXANES
3-PENTANOL
2-METHYL-l-BUTANOL
2-PENTANOL
N-PENTANOL
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
6.
6.
6.
6.
6,
6.
6,
6,
6.
6,
6.
7,
5,
5,
5,
b,
6,
6,
6,
2,
1,
2,
2.
2.
2.
b.
1.
6.
6.
6.
7.
7.
7.
7.
60E
60t
bUE
,60E
,60k
,60E
,60k
,60k
,60E
,60E
,60k
,10E
,70E
,70E
,70E
,70E
,60E
,60E
,60E
,30E
,60E
,30k
,30£
,30E
30t
70E
30E
60E
60E
92E
10E
10E
10E
lot
05
Ob
05
05
05
05
05
Ob
05
Ob
05
05
05
05
05
05
05
05
Ob
05
06
05
05
05
05
05
05
05
05
05
05
05
05
05
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
d.
90E
90E
90k
90E
90E
90k
90E
90E
90E
90E
90E
83k
71k
71k
71k
71E
63E
63E
63E
60E
40E
30E
30E
30k
30E
30E
20£
20E
20E
OOE
OOE
OOE
00k
OOE
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
•
•
•
•
•
•
•
•
•
•
•
•
•
•
*
•
•
•
*
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
70k
70k
70E
70k
70k
70E
70k
70k
70k
70k
70k
70k
60k
60k
60k
60k
60E
60k
60E
50k
40k
40E
40t
40k
40k
34k
30k
30E
30E
20k
20E
20k
20k
20k
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
3
3
3
3
3
3
3
3
3
3
3
b
b
b
b
b
3
3
3
2
1
I
£
2
d
b
4
3
3
b
6
6
6
-------
PRODUCT GAS OKGANlC MODULE COMPOSITE., HEALTH IMPACT
DMEG
23
05
05
05
05
23
23
05
15
15
15
15
15
15
15
15
01
16
23
23
23
23
23
23
23
23
23
23
23
23
15
15
15
15
A
A
A
b
A
A
A
B
B
B
B
B
B
B
B
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
B
B
B
NO.
043*
120*
123*
060*
124*
042*
041*
063*
180*
182*
203*
183*
202*
200*
201*
181*
020
020* P
062*
122*
0»2*
081*
121*
063*
064*
083*
061*
080*
120*
060*
120*
140*
141*
142*
COMPOUND NAME
4-MtTHYLPYKlDINE
PENTANOLS (PKIMARY)
2,2-DIMETHYL-l-PHOPANUL
PENTANOLS (SECONDARY)
3-METHYL-l-BUTANOL
3-METHYLPYKIDINE
2-METHYLPYRlDINt
3-METHYL-2-BUTANOL
TRIMETHYLbENZENES
1,2,4-TRIMETHYLSENZENE
1,2,4,5-TETRAMETHYLbENZENfc
1,3,5-TRIMETHYLBENZbNE
1,2,3,5-TETRAMETrlYLbENZENE
TETRAMETHYLBENZENES
1,2,3,4-TETHAMETHYLBENZENE
1,2,3-TRIMETHYLBENZENt
METHANE
CHLOKOBENZENE
3-ETHYLPYRIUINE
2,4,6-COLLlDlNE
3-PHENYLPYRIDINE
2-PHENYLPYRIDINE
5-ETHYL-2-METHYLPYRIDINE
4-ETHYLPYRIOINE
4-N-PKOPYLPYRIDINE
4-PHENYLPYRIDINE
2-ETHYLPYRIDINE
PHENYLPYRIDINES
CULLIDINES
MONOSUBSTITUTED ALKYL PYRIOINES
TETRAHYDRONAPHTHALENE
DIHYDRONAPHTHALENES
1,2-DlHYDRONAPHTHALtNE
1,4-DIHYDKONAPHTHALtNE
TYPE CONC
E-6 U/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
7.10E
7.10E
7.10E
7.10E
7.10E
7.10E
7.10E
7.10E
2.30E
2.30t
2.30E
2.30E
2.30E
2.3ot
2.30E
2.30E
6.30E
6.60E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30t
1.3oE
1.30t
1.30t
1.30E
1.30E
1.3ot
2.30E
2.30E
2.30E
2.30E
05
05
05
05
05
05
Ob
05
05
05
Ob
05
05
05
05
05
06
05
05
05
05
Ob
05
05
05
05
05
05
05
05
05
05
05
05
US
2.00t
2.00E
2.00E
2.00E
2.00E
2.vOE
2. Out
2.UOE
1.91E
1.91E
1.91E
l.Vlfc
1.Y1E
l.Ylfc
l.Vlt
l.Vlt
l.VOE
l.VOE
1.90L
1.90E
l.VOE
l.VOt
l.VOt
l.VOE
l.VOt
l.VOE
1.90c
1.90E
1.90E
1.90E
l.bOE
i.eot
l.dOE
l.bOt
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
uo
00
00
00
00
00
00
00
00
00
uo
00
00
00
00
00
00
00
NQS
b/S
1.20E
1.20E
1.20t
l.dut
1.20t
1.20C
1.20t
1.20t
1.13t
1.13t
1.13E
1.13b
1.13E
1.13L
1.13t
1.13L
1.12t
1.11E
l.llt
l.llt
l.llt
l.llt
l.llt
l.llt
1.11E
l.llt
l.llt
l.llt
l.llt
l.llt
1.04t
1.04t
1 .04t
1.04E
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
LCCAT
b
6
6
b
6
o
6
6
2
2
2
2
2
2
2
2
3
4
4
4
4
4
4
<4
4
4
4
4
a
2
2
2
2
I
o
uo
-------
M
O\
-p-
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
DME
06
01
16
lb
16
16
01
01
01
01
01
01
01
05
05
23
05
23
05
05
05
05
05
05
23
15
15
15
15
15
15
15
15
15
:G
D
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
A
A
B
A
B
B
A
A
A
B
B
B
B
B
B
B
e
NO.
260*
100
OB3*
082*
081*
080*
242
241
222
220
221
260
240
123*
120*
041*
062*
042*
122*
063*
124*
061*
060*
121*
043*
080*
082*
102*
104*
101*
100*
103*
106*
105*
COMPOUND NAME
DI-2-ETHYLHEXYL ADIPATE
PENTANES
l-BROMO-4-CHLOROBENZENE
l-BROMO-3-CMLOROBENZENE
1-6ROMO-2-CHLOR06ENZENE
BROMOCHLORUbENZENES
N-UNDECANE
N-DECANE
ISONONANE
NONANES
N-NONANE
N-DODECANE
ALKANES(C«10,11)
2»2-DIMETHYL-l-PROPANOL
PENTANOLS (PRIMARY)
2-METHYLPYRIDINE
3-PENTANOL
3-METHYLPYRIDINE
2-METHYL-l-BUTANOL
3-METHYL-2-BUTANOL
3-METHYL-l-BUTANOL
2-PENTANOL
PENTANOLS (SECONDARY)
N-PENTANOL
4-METHYLPYRIDINE
STYRENE
M-XYLENE
M-DIETHYL BENZENE
0-DIISOPROPYL BENZENE
0-DIETHYL BENZENE
DIALKYL BENZENES (MW|134-191)
P-DJETHYL BENZENE
1,I-TERT-BUTYL BENZENE
M-DJJSOPKOPrL BENZENE
TYPfc CONC
E-6 (i/SCM
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
7.10E
5.94E
6.60E
6.60E
6.60E
6.60E
.60E
• 60E
.60E
.60E
.60E
.60E
.60E
5.70E
5.70E
5.70E
5.70E
5.70E
5.70E
5.70E
5.70E
5.70E
5.70E
5.70E
5.70E
6.60E
6.606
6.60E
6.60E
6.60E
6.60E
6.60E
6.60E
6.6UE
05
05
05
05
05
05
06
06
06
06
06
06
06
05
05
05
05
05
05
05
05
05
05
05
05
05
05
Ob
05
05
05
05
05
05
US
1.73E
1.706
1.70E
1.70E
1.70E
1.70E
1.60E
1.60b
1.60E
l.bOt
1.60E
1.606
1.60E
1.60E
1.60E
1.606
1.60E
1.60E
1.60E
1.60E
1.60E
1.60E
.60E
.60E
.60E
.60E
.50E
l.bOE
1.50E
1.506
l.bOE
l.bOE
1.50E
1.50E
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
NDS
b/S
1.02t
1.006
1.006
1.006
1.006
1.006
9.436
9.436
9.436
9.436
9.436
9.43E
9.43t
9.346
9.346
9.346
9.346
9.346
9.346
9.346
9.346
9.346
9.346
9.346
9.346
9.306
tt.906
8.V06
8.906
8.906
8.90t
8.906
0.90E
tt.906
03
03
03
03
03
03
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
LCCAT
6
3
3
3
3
1
1
1
1
1
1
1
5
5
b
5
5
b
b
b
b
5
b
b
3
3
3
3
3
3
3
3
3
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE., HEALTH IMPACT
OMEG
15
16
08
16
16
16
16
06
06
08
08
16
23
08
06
08
08
08
06
08
08
06
03
21
21
21
21
21
21
21
15
21
21
21
B
A
D
A
A
A
A
D
D
D
D
A
C
D
D
D
D
D
D
D
D
D
B
A
A
A
A
A
A
A
B
8
A
A
NO.
083*
140* P
260*
063*
061*
062*
060*
142*
141*
143*
140*
040*
062*
220*
141*
142*
140*
143*
122*
120*
123*
121*
060*
042*
062*
041*
081*
044*
040*
080*
020*
180* P
083*
043*
COMPOUND NAME
P-XYLENE
1,4-DICHLOROBENZENE
DI-2-ETHYLHEXYL ADIPATE
1,4-DIBROMOBENZENE
1,2-DIBROMObENZENE
1,3-DIbROMObENZENE
DIBROMOBENZENES
SEC-AMYL ACETATE
N-AMYL ACETATE
ISOAMYL ACETATE
AMYL ACETATES
BROMOBENZENE
3-METHYLINDOLE
DIBUTYL ADIPATE
N-AMYL ACETATE
SEC-AMYL ACETATE
AMYL ACETATES
ISOAMYL ACETATE
SEC-BUTYL ACETATE
BUTYL ACETATES
ISOBUTYL ACETATE
N-bUTYL ACETATE
2-ETHYL-4-METHYL-l,3-DIOXOLANE
2-METHYLNAPHTHALENE
2,3-DIMtTHYLNApHTHALENE
1-METHYLNAPHTHALENE
1,4-DIMETHYLNAPHTHALENE
2-ETHYLNAPHTHALENE
MUNOALKYL NAPHTHALENES
DIMETHYLNAPHTHALENES
JNDAN
PYRENE
2,6-DIMETHYLNAPHTHALENE
1-ETHYLNAPHTHALENE
TYPE CONC
E-6 li/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
6.60E
6.60E
5.70E
6.60E
6.60E
6.60E
6.6UE
7.10E
7.1UE
7.1UE
7. lOt
6.6UE
5.70E
7.10E
5.70E
5.70E
5.7UE
5.70E
7.10E
7.10E
7.1UE
7.10E
1.30E
2.30E
2.30E
2.30E
2.30E
2.30E
2.30E
2.30E
2.30E
2.3UE
2.30E
2.30E
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
US
1.50E
1.50E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.34E
1.30E
1.22E
1.10E
1.10E
1.10E
l.lut
1.U1E
1.01E
1.01E
l.Uit
l.OOE
1.UUE
l.OOE
l.OOE
l.OOt
l.OOt
l.OOE
l.UOE
l.OOE
l.OOE
l.OOE
l.OOt
00
00
00
00
00
00
uo
uo
00
00
00
00
00
uo
00
UO
00
00
00
uu
00
uo
00
uo
00
uo
00
00
00
uu
00
00
00
00
WDS
U/b
6 90t
8.*7UE
6,20t
6. lit
fa. lit
8. lit
8. lit
8. lOt
8. lOt
8. lOt
6. lOt
7.94t
7.5ut
7.22t
6.50t
6.50E
6.50E
6.50E
6. OUt
6. OOt
6.UOE
6. OOt
5.90t
5.90t
5.9Ut
5.90E
5.90t
5.9Ut
5.90t
5.90E
S.VOt
5.9ot
5.90E
5.VOE
U2
02
02
U2
02
U2
02
02
02
U2
U2
02
u2
U2
02
U2
02
U2
02
02
U2
U2
U2
U2
u2
U2
02
02
02
02
U2
U2
02
02
LCCAT
3
3
5
1
3
3
3
0
6
6
6
3
5
6
5
5
5
5
6
6
6
6
4
2
2
2
2
2
2
2
2
2
2
2
w
-------
DMEG NO.
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
COMPOUND NAME
08 D 220*
48 A 010
16 A 180*
15 A 120*
15 A 100*
06 B 020* W
08 D 100*
08 D 101*
08 D 123*
08 D 122*
08 0 120*
08 0 121*
03 A 040* M
53 A 080
16 A 100* P
16 A 120* P
06 A 040*
01 B 080
08 D 101*
08 D 100*
02 A 340* P
16 A 020* P
02 A 343*
76 A 010 P
53 A 100
17 B 023*
17 B 020*
17 B 021*
17 B 022*
06 A 040*
16 A 083*
16 A 080*
16 A 081*
16 A 082*
DIBUTYL ADIPATE
PHOSPHORUS
2-CHLOROTOLUENE
ISOPROPYL BENZENE
PROPYL BENZENE
2,J-EPOMY-1-PROPANOL
PROPYL ACETATES
N-PROPYL ACETATE
ISOBUTYL ACETATE
SEC-BUTYL ACETATE
BUTYL ACETATES
N-BUTYL ACETATE
3-METHOXYBIPHENYL
CARBONYL SULFIDE
1 r 2-DICHLOR06ENZENE
1*3-DICHLOROBENZ£NE
PROPYLENE CLYCOL
BUTADIENES
N-PROPYL ACETATE
PROPYL ACETATES
DICHLOROPROPANES
CHLOROBENZENE
1 , 3-DICHLUROPROPANE
NICKEL
CARBON DISULFIDE
l-HETHOXY-4-NITROBENZENE
METHOXYNITROBENZENE8
l-METHOXY-2-NITROBENZENE
l-METHOXY-3-NITROBENZENE
PROPYLENE GLYCOL
l-BRUMO-4-CHLOROBENZENE
BROMOCHLOROBENZENES
l-bROMO-2-CHLOROBENZENE
1 -6RUMO-3-CHLOR08ENZENE
TYPE CONC
E-6 C/SCM
T
3
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
S
D
T
T
T
T
T
T
T
T
T
5. TOE
9.40E
2.30E
2.30E
2.30E
1.30E
7.10E
7.10E
5, TOE
5. TOE
5. TOE
5. TOE
1.30E
3. Sit
2.30E
2.30E
T.10E
1.60E
5. TOE
S.TOE
2.30E
2.30E
2.30E
9. 6Ut
3.T3E
1.30E
1.30E
1.30E
1.30E
S.TOE
2.30E
2.30E
2.3UE
2.3UE
05
01
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
06
05
05
05
05
05
00
04
05
05
05
05
05
05
05
05
05
us
9.82E-01
9.40E-01
9.20E-01
9.20E-01
9.20E-01
6.70E-U1
d.bOE-01
8.50&-01
8.14E-01
8.14E-01
8.14E-01
8.14E-01
8.12E-01
8.00E-01
T.70E-U1
7.70E-01
7.50E-01
7.30E-01
6.60E-01
6.tt0t-0i
6.60E-01
6.60E-01
6.60fc-01
6.40E-01
6.21E-01
6.20E-01
6.20E-01
6.20E-01
6.20E-01
6.UOE-01
5.VOE-01
5.90E-01
5.VOE-01
5.90E-01
WD3
li/S
S.bOE
5.54t
5.42t
5.42E
5.<42t
S.llfc
s.oot
b.OOt
a.BOt
4. but
a.eot
4. dot
4. bOt
4.70t
4.52E
4.52t
4.40t
a. JOE
4. OOt
a. out
3.90E
3.90t
3.90E
3.60t
3.70t
3.70t
3.70£
3.7Ut
3.70t
3.53t
3.50t
3.50E
3.50E
3.bOk
02
02
02
02
02
02
02
02
02
U2
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
LCCAT
5
2
2
2
4
b
b
5
5
5
5
4
2
2
b
1
5
5
2
2
2
4
4
4
4
5
2
2
2
2
-------
PRODUCT GAS ORGANIC MODULE. COMPOSITE, HEALTH IMPACT
DMEG NO.
COMPOUND NAME
TYPE CONC DS
E-6 G/SCM
LCCAT
G/S
15
15
15
15
15
15
15
15
15
15
85
16
08
16
16
16
16
16
72
25
08
23
23
23
02
01
21
23
27
46
21
01
01
01
A
B
B
B
B
B
B
B
B
B
A
A
C
A
A
A
A
A
A
A
C
A
A
A
B
A
B
C
A
A
B
B
A
A
080*
101*
102*
083*
100*
105*
104*
103*
082*
106*
010
140* P
040*
060*
061*
063*
062*
040*
010
020 W
040*
043*
042*
041*
080* P
080
100*
062*
010
010 P
040* P
060
040
060
STYRENE
0-DIETHYL BENZENE
M-DIETHYL BENZENE
P-XYLENE
DIALKYL BENZENES (MN;134-191)
M-DIISOPROPYL BENZENE
0-DIISOPROPYL BENZENE
P-OIETHYL BENZENE
M-XYLENE
1,4-DI-TERT-BUTYL BENZENE
URANIUM
1,4-DICHLUROBENZENE
ACETAMIDE
DIBROMOBENZENES
1,2-DIBROMOBENZENE
1,4-DIBROMObENZENE
1,3-DIbROMObENZENE
BROMOBENZENE
IRON (AS FEt2)
THIOPHENE
ACETAMIDE
4-METHYLPYRIDINE
3-METHYLPYRIDINE
2-METHYLPYRIDINE
TETKACHLOROETHENE
BUTANES
BENZOCOPHENANTHRENE & ALKYL DERIVATIVES
3-METHYLINDOLE
LITHIUM
LEAD
BENZ(A)ANTHRACENE
BUTYLENES
ETHANE
PROPANE
T
T
T
T
T
T
T
T
T
T
S
T
T
T
T
T
T
T
S
D
T
T
T
T
T
D
0
T
S
S
D
T
D
D
2.30E
2.30E
2.30E
2.30E
2.30E
2.30E
2.30E
2.30E
2.30E
2.30E
4.60E
2.30E
7.10E
2.30E
2.30E
2.30E
2.30E
2.30E
4.60E
1.90E
5.70E
1.30E
1.30E
1.30E
2.30E
4.60t
6.50E
1.30E
6.30E
2.90E
8.10E
1.60E
7.90E
8. OUt
05
05
05
05
05
05
05
05
05
05
00
05
05
05
05
05
05
05
02
03
Ob
05
05
Ob
05
Ob
01
05
00
01
00
06
05
05
5.50t-01
5.22E-01
5.22E-01
5.22E-01
5.22E-01
5.22E-01
5.22E-01
5.22E-01
5.22E-01
5.22E-01
b.llE-01
b.llt-01
b.lOE-01
4.80E-01
4.ttOt-01
4.80E-01
4.ttOt-01
4.70t-01
4.60E-01
4.22E-U1
4,l0t-0l
3.61E-01
3.61E-01
3.61E-01
3.43E-01
3.30t-01
3.00E-01
2.90E-01
2.YOE-01
1.V3E-01
1.80E-01
1.80E-01
1.30E-01
8.90E-02
3,
3,
3.
3.
3.
3.
3,
3.
3.
3.
3.
3.
3.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
1.
1.
1.
1.
1.
1.
1.
7.i
b.,
,23t
,10t
,10E
,iot
,10E
,10t
lot
lot
lot
lot
oit
oit
oot
82E
82t
82t
82E
80E
71E
50t
40t
13t
13E
13t
02t
93t
74t
70t
70E
I4t
lot
03t
t>2t
24t
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
01
01
2
2
2
2
2
2
2
2
2
2
6
2
d
2
2
2
5
4
4
4
2
3
4
2
1
-------
7
oo
PRODUCT CAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
DMEG
83
01
78
36
43
50
34
74
54
22
61
37
33
62
56
39
65
71
35
15
28
15
15
15
38
63
84
30
84
57
21
04
29
21
A
B
A
A
A
A
A
A
A
C
A
A
B
B
A
A
A
B
A
A
A
B
A
A
A
NO.
010
020
010
010
010
010
010
010
010
060*
010
010
010
010
010
010
010
010
010
040
010
080
061
060
010
010
010
010
010
010
060*
160*
010
120*
P
P
P
P
P W
P
P
P
P
P
PH
COMPOUND NAME
MERCURY
ETHYLENE
COPPER
BARIUM
SILICON
ANTIMONY
CALCIUM (AS CA+2)
COBALT
SELENIUM
BENZO(B)FLUORANTHENE
ZINC
BORON
MAGNESIUM
TITANIUM
FLUORINE (AS F-)
GALLIUM
VANADIUM
MANGANESE
STRONTIUM
TOLUENE
SODIUM
XYLENES
0-XYLENE
ETHYL BENZENE
ALUMINUM
ZIRCONIUM (A3 ZR+4)
CERIUM
RUBIDIUM (AS RB+)
LANTHANUM
CHLORINE (AS CL-)
3-METHYLCHOLANTHRENE
A-CHLOROBUTYL ETHYL ETHER
POTASSIUM
ACENAPHTHriENE
TYPE CONC
E-6 G/SCM
D
D
8
S
S
D
a
a
D
D
8
8
8
S
8
8
8
8
8
D
8
D
D
D
8
8
8
8
8
8
D
T
8
T
3.30E 00
3.60E 05
1.10E 01
2.10E 01
3.30E 02
< 1.60E OK
4.60E 02
> 6.00E-01>
> 3. OOE 00>
l.OOE 01
3.10E 01
> 1.30E 01>
2.SOE 01
2.40E 01
9.20E 00
1.30k 01
9.20E-01
7.10E 00
4.20E 00
2.60E 02
3.10E 01
4.80E 01
4.80E 01
3.90E 01
4.20E-01
2.50E-01
6.80E-01
2. OOE 00
1.30E 00
1.60E 01
0. OOE-01
I.JOE 05
6.90E 01
6.60E 05
6
6
5
4
3
3
2
1
1
1
7
4
4
4
3
2
1
1
1
6
5
1
1
6
6
5
2
1
1
0
0
0
.
•
.
•
•
.
•
.
.
t
.
.
.
.
•
•
•
•
.
.
•
.
.
.
•
•
.
.
*
.
.
.
0.
DS
60E-02
30E-02
50E-02
20E-02
30E-02
20E-02<
90E-02
60E-02>
50E-02>
11E-02
74E-03
20E-03>
20E-03
OOE-03
70E-03
60E-03
64E-03
42E-03
40E-03
64E-04
64E-04
10E-04
ltiE-04
90E-05
10E-05
OOE-05
40E-05
70E-05
20E-OS
OOE-01
OOE-01
OOE-01
OOE-01
0. OOE-01
WD3
G/3
3.90E 01
3.7lt Ul
3.246 01
2.50E 01
1.94k 01
1.90k 01
1.70E 01
9.43k 00
8.84k 00
6.60E 00
4.60k 00
2.bOE 00
2.50k 00
2.40E 00
2.20k 00
1.53k 00
1.10k 00
6.40k-01
8. OOE-01
4.U3E-01
3.50k-01
6.43E-02
6.43E-02
5.22E-02
4.bOk-02
2.94E-02
1.40E-02
9.83E-03
7.00k-03
O.OOk-01
0. OOE-01
0. OOE-01
0. OOE-01
O.OOk-Ul
LCCAT
3
2
4
3
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE, HEALTH IMPACT
DMEG NO.
COMPOUND NAME
TYPE CUNC US
E-6 b/SCM
NOS
LCCAT
45 A 010
21 C 100* P fc
21 6 100*
21 B OtoO* W
04 A ItoO* P
21 D 040* W
22 C 080* P M
21 C 100* P W
21 B 080*
21 C 080* P
12 A 020* P W
10 C 040*
08 B 060* W
20 A 120* W
16 A 220* W
23 B 100* *
23 fa 220*
23 6 240*
23 B 260*
53 A 010
21 D 080* PH
21 D OttO* PH
21 B 060* W
21 D 040* W
22 A 020* PH
22 A 020* PH
56 A 010
21 C 080* P
21 A 100* PH
21 A 100* PH
21 A 120* PH
TIN
BENZOCA)PYRENE
BENZO(C)PHENANTHKENt £ ALKYL DERIVATIVES
7, 12-DIMETHYLBENZ(A)ANTHRACENE
A-CHLOROBUTYL ETHYL ETHER
DIbtNZO(A,I)PYRENE
BENZO(B)FLUORANTHENE
BEN20(A)PYRENt
3-METHYLCHOLANTHRENE
DIBENZ(A,H)ANTHRACENE
N-NITROSOOIhETHYLAMlNE
AMINOTOLUENES
b-PRGPIOLACTONE
2, 4,6-TRINITROPHENOL
POLYCHLORINATED 81PHENYLS
DIHYDROACRIDINE
DIBENZ(A,J)ACRIDINE
DIBENZ(A,H)ACRIDINE
DI6ENZ(C,H)ACRIOIN£
SULFUR
BENZOCGHDPERYLENE
BENZO(GHI)PERYLENE
7, 12-DIMETHYLBENZC A) ANTHRACENE
OIBENZO(A,I)PYRENE
FLUORENE
FLUORENE
BROMINE
DIBENZC A, H) ANTHRACENE
ACENAPHTHENE
ACENAPHTHtNE
ACENAPHTHYLENE
S
D
D
D
T
D
P
D
D
0
D
D
0
D
D
D
D
D
0
S
1
T
U
D
T
T
S
D
T
T
T
8 80E-01
O.OOt-01
O.OUE-01
O.OOE-01
5.70E Ob
O.OOE-01
O.OOE-01
O.OuE-01
U.Out-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OoE-01
O.OOE-Oi
O.OuE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.bUt 02
2.30E Ob
o.60t Ob
O.OOE-01
O.OOE-01
2.30E 05
6.60E 05
8.80E-01
O.OOE-01
2.30E 05
6.60E 05
2.30E 05
O.OOE-01
o.oot-oi
O.uOE-01
O.OOE-01
O.OOE-ul
o.oot-oi
O.OOE-01
O.OUt-01
O.OOE-U1
0.00t-0l
O.OOE-01
O.UOE-01
U.UOt-01
o.uut-oi
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
o.uot-oi
o.oot-oi
O.OOE-01
O.OOE-01
O.OOt-01
o.uot-oi
O.OOE-U1
O.OOE-01
O.UOE-01
O.UOE-01
o.oot-oi
o.oot-oi
O.UOE-01
o.oot-ui
O.OOt-01
o.uot-oi
o.oot-oi
o.uoE-ui
u.oot-oi
O.OOt-01
O.OOE-01
o.oot-oi
O.OOE-01
o.oot-oi
o.oot-oi
O.OOE-01
u.oot-oi
O.OOE-01
O.OOt-01
O.OOt-Ul
O.UOE-01
o.oot-oi
O.OOE-01
O.OOE-U1
O.OOt-01
o.oot-oi
o.uot-oi
o.oot-oi
O.OOE-01
o.oot-oi
o.oot-oi
2
2
3
b
3
2
3
3
3
b
b
5
b
3
b
5
5
b
2
3
2
2
2
3
2
2
3
2
W
-------
PRODUCT GAS ORGANIC NODULE COMPOSITE
FLOW RATE • 590 G/3 (0.57 SCM/S» DRY BASIS)
5.555 SCM AT 25C AND 760 MM HG SAMPLED
TOTAL ORGANIC LOADING • a.i G/SCM
TOTAL TCO * 6.0 G/SCM TOTAL GRAV • 2.2 G/SCM
0.195X ORIGINAL SAMPLE TO 1C
LC TCO • 64.7 MG LC GRAV • 24.0 MG LC TOTAL • 88.7 MG
LCCAT ORGANIC LOADING
1 1600000.0
2 230000.0
3 660000.0
4 130000.0
5 570000.0
6 710000.0
7 2500000.0
FLOW RATE • 590.00
MINIMUM DISCHARGE SEVERITY • .010
STATE: GAS, UNITS IN MICROGRAMS/SCM
IMPACT! ECOLOGY
EXPtRIMENTALY DETERMINED DATA
SPARK SOURCE DATA
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE, ECOLOGY IMPACT
DMEG NO.
01 B 020 W
47 A 060 P
42 A 070
15 A 120*
15 A 120*
15 A 020 P
47 A 080 P
01 A 020 W
65 A 010
01 B 060
83 A 010 P
01 b 060
01 A 040
15 A 040 P
01 A 060
01 A 080
15 B 060
53 A 060
25 A 020
42 A 080
53 A 060
53 A 100
21 B 040* P
21 6 060*
21 D 040*
21 9 100*
15 A 060 P
21 B 080*
21 C 060* P
22 C 080* P
16 A 220*
15 A 160
21 B 040* P
16 A 220*
COMPOUND NAME
ETHYLENE
AMMONIA
CARBON MONOXIDE
ISOPROPYL BENZENE
ISOPROPYL BENZENE
BENZENE
HYDROGEN CYANIDE
METHANE
VANADIUM
BUTADIENES
MERCURY
BUTYLENES
ETHANE
TOLUENE
PROPANE
BUTANES
XYLENES
CARBONYL SULFIDE
THIOPHENE
CARBON DIOXIDE
SULFUR DIOXIDE
CARBON DISULFIDE
BENZ(A)ANTHRACENE
7»12-DIM£THYL6£NZ(AJ ANTHRACENE
DI6ENZOU, DPYRENE
BENZO(C)PHENANTHKENE & ALKYL DERIVATIVES
ETHYL BENZENE
3-METHYLCHULANTHHENE
D I BENZ( A, H) ANTHRACENE
BENZO(B)FLUORANTHENE
POLYCHLORINATED bIPHENYLS
BIPHENYL
BENZ(A)ANTHRACENE
POLYCHLORINATED BIPHENYLS
TYPE
D
U
D
T
T
U >
D
D
S
T
D
T
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D <
CUNC
E-b t/SCM
3.60E 05
1.10E 07
3.00E 08
6.60E 05
2.30E 05
1.30E 04>
2.22E 05
6.30E 06
9.20E-01
1.60E 06
3.30E 00
1.60E 06
7.90E 05
2.60E 02
8.00E 05
4.60E 05
4.80E 01
3.51E 05
1.90E 03
1.71E 08
4.20E 04
3.73E 04
8.10E 00
O.OOE-01
O.OOE-01
O.OOE-01
3.90E 01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
5. Out 03
1.40E 02
7.20E 00<
DS
3.60E 05
3.03E 04
2.50E 03
5.50E 02
1.91E 02
1.80E 01>
6.52E 00
9.64E-01
9.20E-01
7,iOE-Oi
3.30E-01
7.00E-02
6.60E-02
S.70E-02
4.44E-02
1.90E-02
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01<
WDS
t/S
2. HE 08
1.80E 07
1.50E 06
3.24E 05
1.13E 05
1.10E 04
3.90E 03
5.70L 02
5.42E 02
4. JOE 02
1.94E 02
4. 10E 01
3.90E 01
3.33t 01
2.62E 01
1.12E 01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OUE-01
o.oot-oi
O.OOE-01
O.OOt-Ul
O.OOt-01
LCCAT
3
2
1
1
2
2
2
2
2
2
2
3
3
3
2
w
-------
pa
OMFG NO.
PRODUCT 6AS ORGANIC MODULE COMPOSITE* ECOLOGY IMPACT
COMPOUND NAME TYPE CONC US
E-6 U/SCM
LCCAT
01
01
21
21
21
53
12
10
08
20
20
23
23
23
23
50
49
15
54
38
36
37
58
34
84
57
68
74
78
56
39
72
64
A
A
B
C
C
A
A
C
B
A
B
B
B
B
B
A
A
B
A
A
A
A
A
A
B
A
A
A
A
A
A
A
4
4
100
140
100*
100* P
100* P
090
020* P
040
060
120
040
100
220
240
260
010 P
010 P
081
010 P
010
010
010
010
010
010
010
010 P
010
010 P
010
010
010
010
019 P
PENTANES
HEXANES
BENZO(C)PHENANTHRENE ft ALKYL DERIVATIVES
BENZO(A)PYRENE
BENZO(A)PYRENE
HYDROGEN 8ULFIDE
N-NITROSODIMETHYLAMlNfc
AMINOTOLUENES
B-PROPIOLACTONE
2,4,6-TKINITROPHENOL
DINITRO-P-CRESOLS
DIHYDHOACRIDINE
DIBENZ(A,J)ACRIDINE
DIBENZ(A,H)ACRIDINE
OIBENZ(C,H)ACRIDlNb
ANTIMONY
ARSENIC
0-XYLENE
SELENIUM
ALUMINUM
BARIUM
BORON
BROMINE
CALCIUM (AS CA+2)
CERIUM
CHLORINE (AS CL-)
CHROMIUM
COBALT
COPPER
FLUORINE (AS F-)
GALLIUM
IRON (43 FE+2)
1 AJyVAJAAJJfM
|*4Q«T f ^HlVlr W
IE40
D
D
D
D
D
D
0
D
D
D
D
D
D
D
D
D
D
D
D
S
8
S
S
3
8
S
S
S
S
S
S
8
a
8
s
6
.94b 05
.92E 05
6.SOE 01
0
0
1
0
0
0
0
9
0
0
0
0
< 1
> 1
4
.OOE-01
.OOE-01
•54E 06
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.80E 02
.OOb-01
.OOE-01
.OOE-01
.OOE-01
.60E OK
,80E 01>
.806 01
> 3.00E 00>
4
2
> 1
8
4
8
1
1
> 8
1
.20E-01
.10E 01
.30E 01>
.80E-01
.60E 02
.80E-01
•60E 01
.50E 01
,OOE-01>
.10E 01
9.20E 00
l.SOE 01
4.60E 02
I.JOE 00
2.90E 01
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.OOE-01
.OOE-01
.OOE-01
.OOb-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
,00£-01<
.OOE-01>
.OOE-01
,OOE-01>
.OOE-01
.OOE-01
.00b-01>
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01>
.OOE-01
.OOE-01
.OOE-01
o.oos-oi
0. OOE-01
0. OOE-01
0.
0.
0,
0,
0,
0,
0,
o,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0.
0.
0.
0.
0.
0.
0.
0.
,00b-01
,00b-01
,oob-oi
.OOb-01
,00b-01
,00b-01
,00b-0l
.OOE-01
,00b-01
.OOE-01
.OOE-01
,00b-01
,00b-01
.OOE-01
.OOfc-01
.OOE-01
.OOE-01
,00b-01
,00b-01
,00b-01
,00b-01
,00b-01
,00b-01
,OOE-01
,00b-01
,OOE-01
,OOE-01
oot-ui
OOb-01
OOb-01
OOb-01
OOb-01
OOE-01
OOE-01
3
3
^
5
b
b
5
b
b
5
b
b
-------
PRODUCT GAS ORGANIC MODULE. COMPOSITE* tCOLOGY IMPACT
DMEG NO.
COMPOUND NAME
TYPE CO*C US
E-6 G/SCn
LCCAT
G/S
27
33
71
76
48
29
30
43
79
28
35
53
45
62
85
21
81
63
21
21
02
02
02
02
02
02
02
02
02
02
02
02
02
02
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
D
A
A
b
C
A
A
A
A
A
A
A
A
B
6
b
B
b
B
010
010
010
010
010
010
010
010
010
010
010
010
010
010
010
040*
010
010
080*
080*
140*
140*
160*
160*
320*
320*
340*
340*
080*
080*
100*
100*
120*
120*
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
LITHIUM
MAGNESIUM
MANGANESE
NICKEL
PHOSPHORUS
POTASSIUM
RUBIDIUM (AS RB+)
SILICON
SILVER
SODIUM
STRONTIUM
SULFUR
TIN
TITANIUM
URANIUM
DIbENZO(A,I)PYRENE
ZINC
ZIRCONIUM (AS ZR+4)
3-METHYLCHOLANTHRENE
DIBENZ( A, H) ANTHRACENE
DI8ROMOCHLOROMETHANE
DI6ROMOCHLUROMETHAME
BROMOFORM
BROMOFORM
HEXACHLOROETHANE
HEXACHLOROETHANE
DICHLOROPROPANES
DICHLOROPROPANES
TETRACHLOROETHENE
TETRACHLOROETHENE
D1CHLOROPROPENES
DICHLOROPROPENES
HExACHLOROBUTADlENE
HEXACHLOROBUTADIENE
S
S
S
S
S
S
S
S
S
5
S
S
S
S
S
D
S
S
D
0
T
T
T
T
T
T
T
T
T
T
T
T
T
T
b.3o£ oo
2.50E 01
7.1oE 00
9.60E 00
V.40E 01
6.90E 01
2.00E 00
3.30E 02
3.00E 01
3.10E 01
4.20E 00
8.60E 02
8.80E-01
2.40E 01
4.60E 00
O.OOE-01
3.10E 01
2.50E-01
0. OOE-01
O.OOE-01
l.bOE 06
2.30E 05
1.60E 06
2.30E OS
1.60E 06
2.30E 05
1.60E Ob
2.30E 05
1.60E 06
2.30E OS
1.60E Ob
2.3o£ 05
1.60E 06
2.30E OS
O.OOE-01
O.OOE-01
O.OOE-Ol
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.oOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
0.00t-0l
O.OOE-01
0. OOt-01
0 ,00t-0 1
0. OOt-01
0, OOE-01
0. OOt-01
O.OOE-01
0. OOt-01
O.OOE-01
0. OOt-01
0. OOE-01
0. OOt-01
0. OOt-01
O.OOE-01
0. OOt-01
0. OOt-01
0. OOt-01
0. OOt-01
0. OOt-01
0. OOt-ol
o. oot-oi
0. OOt-01
O.OOE-01
0. OOt-01
0. OOt-01
0. OOt-01
O.OOE-01
0. OOt-01
O.OOE-01
0. OOt-01
0. OOt-01
O.OOE-01
O.OOE-01
3
3
3
1
2
1
2
1
2
1
2
1
2
1
2
1
2
fn
I
-------
PRODUCT GAS ORGANIC MODULE COMPOSITE* ECOLOGY IMPACT
OME
02
02
04
04
04
04
04
04
04
04
04
04
07
07
08
06
08
08
08
08
to
10
12
12
12
12
12
21
22
16
16
16
16
16
:G
B
B
A
B
B
B
B
B
B
0
D
D
D
D
0
C
C
A
A
A
A
A
B
C
A
A
A
A
A
NO.
140*
140*
140*
140*
160*
160*
180*
180*
020*
020*
040*
040*
080*
080*
280*
280*
300*
300*
320*
320*
140*
140*
020*
040*
040*
060*
060*
060*
080*
020*
020*
100*
100*
120*
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
COMPOUND NAME
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROCYCLOPENTADIENE
2-CHLOROETHYL VINYL ETHER
2-CHLOROETHYL VINYL EThER
A-CHLOROBUTYL ETHYL ETHER
A-CHLOROBUTYL ETHYL ETHER
CHLOROPHENYL PHENYL ETHER
CHLOROPHENYL PHENYL ETHER
If I'-DICHLOROMETHYL ETHER
If I'-DICHLOROMETHYL ETHER
Ir I'-DICHLORODIETHYL ETHER
If I'-OICHLOROOIETHYL ETHER
ISUPHORONE
ISUPHORONE
PHTHALATE E3TER8 (MH|194-279)
PHTHALATE ESTERS (M*| 194-279)
DI-2-ETHYLHEXYL PHTHALATE
01-2-ETHYLHtXYL PHTHALATE
BUTYL BENZYL PHTHALATE
BUTYL BENZYL PHTHALATE
BENZIDINE
BENZIDINE
N-NITROSUOIMETHYLAMINE
N-NITROSOOIETHYLAMINE
N-NITROSODIETHYLAMINE
N-NITROSODIPROPYLAMINE
N-NITKOSOOIP«OPYLAMlN£
7f 12-DIMETHYLBENZ( A ) ANTHRACENE
BENZO(B)FLUORANTHENE
CHLOROBENZENE
CHLOHOBENZENE
lf2-DICHLOROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOHOBENZENE
TYPE CONC
E-6 G/8CM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
D
T
T
T
T
T
1
2
1
5
1
5
1
5
1
5
1
5
5
7
S
7
5
7
5
7
5
7
7
5
7
5
7
0
1
2
6
2
6
.60E
.30E
.30E
,70t
.30E
.70E
.30E
.70E
.30E
.70E
.30E
.70E
,70£
.10E
.70E
.10E
.70E
.10E
.70fc
.lot
.70E
.10E
.10E
.70E
.10E
.70E
.10E
06
OS
05
OS
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
.Out-01
.OOE
.30E
.60E
.30E
.60E
2. JOE
01
05
05
05
05
05
US
0. OOE.- 01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-OI
O.UOE-01
O.OOE-01
o.ooe-oi
O.OOE-01
O.OUE-OI
O.OOE-01
o.oot-oi
O.OUt-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OUE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
WD3
G/S
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-OI
O.OOE-01
O.OOE-01
O.OOE-01
U.OOE-OI
O.OOE-01
U.OOE-OI
O.OOt-01
O.OOE-01
O.OOt-01
O.UOt-01
0.00t-0l
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
0. out-oi
o.oot-oi
O.OOt-01
O.OOE-OI
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOt-ol
LCCAT
1
2
4
5
4
5
4
5
4
5
4
5
b
6
5
6
5
6
5
6
b
6
6
Is
6
5
6
3
3
2
3
2
3
t
-------
PRODUCT (iAS ORGANIC MODULE. COMPOSITEr ECOLOGY IMPACT
DMEG NO.
16 A 120* P
16 A 140* P
16 A 140* P
16 A 160* P
16 A 100* P
16 A 200* P
16 A 200* P
17 A 020* P
17 A 020* P
17 A 081* P
17 A 081* P
17 A 084* P
17 A 084* P
18 A 020* P
18 A 020* P
18 A 142* P
16 A 142* P
19 A 020* P
19 A 020* P
19 A 040* P
19 A 040* P
19 A 060* P
19 A 060* P
19 B 022* P
19 B 022* P
20 A 020* P
20 A 020* P
20 A 060* P
20 A 060* P
20 A 101* P
20 A 101* P
20 B 020* P
20 B 020* P
21 A 020* P
COMPOUND NAME
lr3-DICHLUROBENZENE
1,4-DICHLOROBENZENE
1,4-DICHLOROBENZENE
POLYCHLORINATED BENZENES
POLYCHuORINATED BENZENES
CHLORUNAPHTHALENES
CHLORONAPHTMALENES
NITROBENZENE
NITROBENZENE
2»6-DlNlTKOTOLUENE
2,6-DINITROTOLUENE
2,4-DINITROTOLUENE
2r4-DINITKOTOLUENE
PHENOL
PHENOL
2,4-XYLENOL
2r4-XYLENUL
2-CHLUROPMENOL
2-CHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DICHLQROPHENOL
PENTACHLOHOPHENOL
PENTACHLOrtOPHENOL
CHLORINATEO-M-CRESOLS
CHLOR1NATED-M-CRESOLS
2-NITROPHENOL
2-NITROPHENOL
4-NITROPHENOL
4-NITROPHENOL
2,4-DlNlTROPHENOL
2,4-DINlTROPHENOL
4,6-DIMTRO-O-CRESOL
4, 6-DINITRO-0-CRE80L
NAPHTHALENE
TYPE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
CONC
E-6 li/SCM
6.60E OS
2.30E 05
6.60E OS
2.30E OS
6.60E 05
2.30E 05
6.60E 05
1.30E 05
5.70E 05
1.30E 05
5.70E 05
1.3UE 05
5.70E 05
5.70E 05
7.10E 05
5.70E 05
7.1UE 05
5.70E 05
7.1uE 05
5.7UE 05
7.10E 05
5.7UE 05
7.10E 05
5.70E 05
7.1UE 05
5.70E 05
7.1UE 05
5.70E 05
7.10E 05
S.70E 05
7.10E 05
5.70E 05
7.10E 05
2.30E 05
OS
O.OOE-01
O.OOE-01
O.OOE-01
O.UUE-01
O.OOE-01
O.UOE-01
O.UOE-01
O.OUE-OI
O.OOE-01
O.UOt-01
O.UOE-01
O.OOE-01
O.UOE-01
O.UOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.UOE-01
O.OOE-U1
U.UOt-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
o.oot-oi
O.OOt-01
U.Out-01
o.oot-oi
O.OOE-01
o.oot-oi
U.UUt-01
O.OOE-01
O.Uut-01
MDb
ti/S
O.OOt-01
O.OOt-01
O.UOE-01
o.oot-oi
U.OOt-01
O.OOE-01
O.UOE-01
O.UOE-01
O.OOt-01
O.OOfc-01
O.OOE-01
O.OUE-01
o.oot-oi
O.UUE-01
O.OOt-Ul
o.oot-oi
O.UOE-01
O.OOt-01
O.OOE-Ul
O.UOt-01
o.uot-oi
o.oot-oi
o.uot-oi
O.OOt-01
O.OOt-01
u.oot-ui
o.uot-oi
O.OOt-Ul
U.OOt-01
O.OOt-01
O.OOE-01
o.oot-oi
o.uot-oi
O.OOt-01
LCCAT
3
2
3
-------
PRODUCT CAS ORGANIC MODULE COMPOSITE* ECOLOGY IMPACT
DMEG
21
21
21
21
21
21
21
21
21
21
21
21
21
21
21
22
22
22
22
22
22
22
22
A
A
A
A
A
A
A
A
A
B
B
B
B
D
D
A
A
B
B
C
C
D
D
NO.
020*
100*
100*
120*
120*
iao*
140*
180*
180*
120*
120*
180*
180*
080*
080*
020*
020*
040*
040*
020*
020*
020*
020*
P
PH
PH
PH
PH
P
P
P
PH
PH
PH
PH
P
P
P
P
P
P
COMPOUND NAME
NAPHTHALENE
ACENAPHTHENt
ACENAPHTHENE
ACENAPHTHYLENE
ACENAPHTHYLENE
ANTHRACENE
ANTHRACENE
PHENANTHRENE
PHENANTHRENE
CHRYSENE
CHRYSENE
PYRENE
PYRENE
BENZO(GHI)PERYLENE
BENZOCGHDPERYLENE
FLUORENE
FLUORENE
FLUORANTHENE
FLUOHANTHENE
BENZO(K) FLUORANTHENE
BENZOOOFLUORANTtlENE
INDENO(i,2,3-CD)PYRENE
INDENO(l,2r3-CD)PYRENE
TYPE CONC
E*6 G/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
b.bOE
2.30E
6.60E
2.30E
6.60E
2.30E
6.60E
2.30E
b.bOE
2.30E
b.bOE
2.30E
b.bOE
2.30E
6.60E
2.30E
6.60E
2.30E
6.60E
2.30E
6.60E
2.30E
6.60E
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
OS
.OOE-01
.oot-oi
.OOE-01
.VOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
WD3
G/S
0. OOE-01
0. OOE-01
O.OOt-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
O.OOb-01
O.OOE-U1
0. OOE-01
0. OOE-01
O.OOt-01
O.OOt-01
O.OOt-01
O.OOt-01
0. OOE-01
0. OOE-01
O.OOE-01
O.OOt-01
O.OOt-01
O.UOE-01
O.OOt-01
0. OOE-01
LCCAT
3
2
3
2
3
2
3
2
3
2
3
2
3
2
3
2
3
2
3
2
3
2
3
-------
LCCAT
1
2
3
a
•5
6
7
TEST BURNER FLUE. GAS COMPOSITE
FLOW RATE = 6080 6/S (6.77 SCM/Sr U«Y BASIS)
29.686 SCM AT 25C AND 760 MM MG SAMPLED
TOTAL ORGANIC LOADING = 5.a MG/SCM
TOTAL TOO = NR TOTAL GRAV = 5.4 MG/SCM
55.OX ORIGINAL SAMPLt TO LC
LC TCO = MR LC GRAV = 90.3 MG LC TOTAL - 90.3 MU
ORGANIC LOADING
860.0
130.0
44.0
130.0
470.0
2200.0
910.0
FLO* RATE = 6060.00
STATE: GAS, UNITS IN MICROGRAMS/SCM
IMPACT! HEALTH
EXPERIMENTALY DETERMINED DATA
SPARK SOURCE DATA
I
—I
—I
-------
I
^J
00
TEST BURNER FLUE GAS COMPOSITE, HEALTH IMPACT
DMEG
21 C
21 C
04 6
16 A
49 A
68 A
21 B
12 A
04 B
20 A
10 C
53 A
10 C
10 C
10 C
10 C
12 A
23 B
10 C
21 B
20 B
20 B
20 B
20 B
42 A
21 B
23 B
23 B
02 B
12 A
08 B
20 A
10 C
23 C
NO.
100*
060*
020*
220*
010
010
080*
020*
020*
120*
100*
060
040*
043*
041*
042*
040*
100*
220*
060*
042*
041*
020*
040*
060
040*
240*
220*
140*
020*
060*
120*
100*
160*
W
M
W
N
W
W
p
W
P W
W
P
P W
P M
W
M
M
COMPOUND NAME
BENZO(A)PYRENE
DIBENZ(A,H)ANTHRACEN£
Irl'-DICHLOROMETHYL ETHER
PQLYCHLORINATED BXPHENYLS
ARSENIC
CHROMIUM
3-METHYLCHOLANTHRENE
N-NITROSOOIMETHYLAMINE
lr I'-OICHLOROMETHYL ETHER
2»4,6-T«INlTROPHENOL
1,4-DIAMINOBENZENE
SULFUR DIOXIDE
AMINOTULUENES
4-AMINOTOLUENE
2-AMINOTOLUENE
3-AMINOTOLUENE
N-NITROSODIETHYLAMINE
DIHYDROACRIOINE
2-AMINONAPHTHALENE
3-METHYLCHOLANTHRENE
2rb-DlNITRO-P-CRE30L
3r5-DINITRO-P-CRESOL
4,6-DlNITRO-O-CRESOL
DINITRO-P-CRESOL3
CARBON DIOXIDE
BENZ(A)ANTHKACENE
DIBENZ(A,H)ACRIDINE
DIBENZ(A,J)ACRIDINE
HEXACHLOROCYCLOPENTADIENE
N-NITROSODIMETHYLAMINE
8-PROPIOLACTONE
2,4,6-TRINITROPHENOL
1,4-DIAMJNOBENZENE
DJ8ENZO(C,GK*«BAZOLE
TYPE CONC
£•6 U/SCM
T
T
T
T
D
8
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
D
D
T
T
T
T
T
T
T
T
4.40E
4.40t
4. TOE
4.40E
8.60E
3.70E
1.30E
2.20E
1.30E
2.20E
2.20E
2. TOE
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
4.40E
2.20E
2.20E
2.20E
2.20E
9.60E
4.50E
2.20E
2.20E
8.60E
4. TOE
2.20E
4.70E
4.7UE
4.70E
01
01
02
01
01
01
02
03
02
03
03
05
03
03
03
03
03
03
03
01
03
03
03
03
07
02
03
03
02
02
03
02
02
02
US
2.20E
4.73E
9.40E
4.40E
4. JOE
3.70E
3.42E
3.40E
2.60E
2.20E
2.20E
2.10E
2.00E
2.00E
2.00E
2.00E
1.&3E
1.40E
1.30E
l.dOE
1.1 OE
1.10E
1.10E
1.10E
1.10E
1.0 Oh
l.OOE
8.60E
6.00E
7.23E
6.90E
4.70E
4.70E
4.70E
03
02
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
00
00
00
00
00
00
00
HDS
b/3
l.bOt
3.82fc
7.60E
3.bOt
3. 50t
3.00t
2.80E
2.73E
2. 10E
1.80E
l.ttOt
1.70E
1.61E
1.61E
l.blt
1.6U
1.5ut
l.llt
i.o at.
9.40E
8. SOt
b.90t
8.90t
6.90t
ti.eot
6. lOt
8. 10E
7. lit
b.50t
5.b4t
5.60t
3.80t
3.«0t
3.60t
07
Ob
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
LCCAT
3
3
5
3
2
6
4
6
6
6
6
6
6
b
b
b
3
b
b
b
b
2
b
b
1
5
0
5
5
5
-------
TEST BURNER FLUE GAS COMPOSITE, HEALTH IMPACT
DMEG
10
19
10
10
10
13
10
10
10
10
10
12
21
76
23
08
10
13
74
20
20
20
20
08
08
10
08
08
08
23
23
02
48
12
C
A
C
C
C
A
C
C
C
C
C
A
D
A
B
B
C
A
A
B
B
B
8
A
A
C
C
A
A
B
B
A
A
B
NO.
080*
060* P W
081*
083*
082*
100* W
043*
042*
040*
041*
200*
040* P
040* W
010 P
100* W
060* W
220*
140*
010
042*
020* P W
040* W
041*
121*
122*
140* P
060* W
120* W
123*
240*
220*
380* W
010
020* W
COMPOUND NAME
ANISIDINES
PENTACHLOROPHENOL
0-ANIS1DINE
P-ANISIDINE
M-ANISIDINE
BENZENETHIOL
4-AMINOTOLUENE
3-AMINOTOLUENE
AMINOTOLUENES
2-AMINOTOLUENE
1-AMINONAPHTHALENE
N-NITROSODIETHYLAMINE
DIBENZO(A,I)PYRENE
NICKEL
DIHYDROACRIDINE
B-PROPIOLACTONE
2-AMINONAPHTHALENE
PERCHLOROMETHANETHIOL
COBALT
2,6-DINITRO-P-CRESOL
4,6-DINITRO-O-CRESOL
DINITRO-P-CRESOLS
3rb-UINITRO-P-CRE30L
MYRISTIC ACID
PALMITIC ACID
BENZIOINE
6-HEXANELACTAM
SATURATED LONG CHAIN ACIDS (M*:228-28b)
STEARIC ACIl>
DIBENZ(A,H)ACRIDINE
DIBENZ(A,J)ACRIDINE
HEXACHLOROCYCLOHEXANE
PHOSPHORUS
N-METHYL-N-NITROSO ANILINE
TYPE CONC
E-6 G/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
4.70E
4.70E
4.70E
4.70t
2.20E
4.70E
1.30E
4.50E
4.70E
9.10E
4.70E
2.20E
1.30E
4.70E
4.70fc
4.70E
4.70E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
4.70E
4.70E
8.80E
1.70E
2.20E
03
03
03
03
03
03
02
02
02
02
03
02
02
01
02
02
02
03
02
02
02
02
02
03
03
03
03
03
03
02
02
02
02
03
OS
4.40E
4.40E
4.40E
4.4DE
4.4QE
4.40t
4.30E
4.30E
4.30E
4.30h
3.92E
3.91E
3.02E
3.00E
2.93E
2.84E
2.60t
2.bOt
2.60E
2.34E
2.34t
2.34E
2.34E
2.20E
2.20E
2.20t
2.20E
2.20E
2.20E
2.13E
l.VOE
1.80E
1.70E
1.70E
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
WDS
li/S
3.60E
3.60L
3.60t
3.60E
3.60t
3.60t
3,bOt
3.bOt
3.bOt
3.byt
3.20k.
3.20t
2.44t
2.42t
2.40t
2.30E
2.23t
2.22t
2. lot
l.^Ot
l.^Ot
1.90t
. vot
.80t
,80t
,80t
,80t
.bOt
.bOt
1.72t
l.blt
i ,42t
1.40L
1.4Ut
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
LCCAT
6
6
6
6
6
6
b
b
5
b
b
b
2
b
7
b
6
b
b
b
b
6
6
6
6
6
6
b
b
1
6
W
-------
co
o
TEST BURNER FLUE CAS COMPOSITE* HEALTH IMPACT
OMI
10
20
20
20
20
20
08
23
02
14
16
21
21
19
10
10
10
10
13
12
08
08
06
08
10
08
77
54
02
21
21
21
21
21
iG
C
A
A
A
A
A
B
C
B
B
B
D
B
A
C
C
C
C
A
A
A
A
A
A
C
A
A
A
A
B
B
B
B
0
NO.
120*
080*
101* P
102*
103*
100*
060* W
160* M
140* P W
020 H
060* M
040* H
040* P
060* P H
060*
081*
083*
082*
100* H
060* P
121*
122*
120* H
123*
200*
140*
010
010 P
180*
108*
102*
100*
10A*
106*
COMPOUND NAME
4-AMINOBIPHENYL
2-AMINO-4,6-DlNlTROPHENOL
2,4-DlNITHOPHENOL
2»5-DINITROPHENOL
2r6-DINITROPHENOL
DINITROPHENOLS
B-PROPIOLACTONE
DIBENZO(C,G)CARBAZOLE
HCXACHLOROCYCLOPENTADIENE
DIMETHYL SULFOXIDE
lr4-DIHYDROXYBENZENE
DIBENZO(A,I)PYRENE
BENZ(A)ANTHRACENE
PENTACHLOROPHENOL
ANISIDINES
0-ANISIDINE
P-ANISIDINE
M-ANISIDINE
BENZENETHIOL
N-NITROSODIPROPYLAMINE
MYRISTIC ACID
PALMITIC ACID
SATURATED LONG CHAIN ACIDS (M*|228»285)
STEARJC ACID
1-AMINONAPHTHALENE
OLEIC ACIU
PLATINUM
SELENIUM
DIBKOMODICHLOROMETHANE
2-ETHYL BENZO(C)PHENANTHRENE
1-METHYL BENZOtOPHENANTHRENE
BENZOCCJPHENANTHRENE I ALKYL DERIVATIVES
N-PROPYL BENZOCOPHENANTHRENE
ISOPROPYL 8ENZO(C;PH£NANTHRCN£
TYPE CONC
E-b tt/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
D
T
T
T
T
T
T
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
4.70E
1.30E
1.30E
9.10E
2.20E
4.40E
«.«OE
4.70E
M.70E
4.70E
4.70E
4.70E
4.70E
2.20E
9.10E
9.10E
9.10E
9.10E
4.70E
2.20E
.30E
< .30E
,80E
.30E
.30E
.JOE
.JOE
1.30E
03
03
03
03
03
03
02
02
02
02
03
01
01
02
02
02
02
02
02
03
02
02
02
02
02
03
00
02<
02
02
02
02
02
02
US
1.70E 00
1.60E 00
.60E 00
.60E 00
.60E 00
.60E 00
.50E 00
.30E 00
.20£ 00
.12E 00
.10E 00
.02E 00
9.bOt-01
9.40E-01
9.40E-01
9.40E-01
9.40E-01
9.40E-01
9.40E-01
9.20E-01
9.10E-01
9.10E-01
9.10E-01
9.10E-41
8.40E-01
6.70E-01
6.SOE-01
6.bOE-01<
6.30E-01
5.90E-01
S.90E-01
5.90E-01
S.90E-01
5.VOE-01
1
1
9
9
b
8
7
7
7
7
7
7
7
7
7
7
7
7
6
5
5
5
5
4
4
MDS
G/3
.40b
,30h
,30t
.30t
.30t
.30E
.2UE
.lot
• 54E
.lot
,90t
.30t
,90£
.bOt
.601:
.60E
.60E
.60E
.bOfc
.40t
.40E
.40t
.4Ut
.40t
.eot
.40E
.30E
.306
.lot
.ttOt
.eot
4.60E
4.SOE
4.00E
04
04
04
04
04
04
04
04
03
03
03
03
03
03
03
03
03
03
03
03
03
U3
03
03
03
03
03
03
03
03
03
03
03
03
LCCAT
6
6
6
6
6
6
5
4
2
7
6
3
3
5
5
5
5
5
5
6
7
7
7
7
5
6
1
2
2
2
2
2
-------
DHEG NO.
TEST BURNER FLUE GAS COMPOSITE* HEALTH IMPAC1
COMPOUND NAME TYPE CONC
E-b G/SCM
US
WDS
LCCAT
21
21
21
21
21
21
21
13
23
08
08
10
17
08
17
08
08
23
08
08
08
08
08
08
08
08
08
08
23
23
23
23
10
10
w
i
oo
b
B
6
13
B
B
B
A
D
A
A
C
B
A
B
C
A
D
0
D
D
D
0
A
A
A
A
A
A
A
A
A
A
C
106*
104*
107*
103*
101*
105*
109*
140*
020* W
123*
122*
140* P
040* W
120* W
ObO* W
ObO* W
121*
040*
281*
282*
283*
280* P W
300* P
100*
103*
101*
104*
102*
103*
102*
101*
100* W
ObO*
120*
7-METHYL BENZO(C)PHENANTHNENE
5-METHYL BENZO(C)PHENANTH«ENE
8-METHYL BENZO(UPHENANTH«ENE
2-METHYL BENZO(C)PHENANTHKENE
BfcNZO(C)PHENANTHRENE
b-METHYL BENZG
-------
CD
N5
TEST BURNER FLUE 0*8 COMPOSITE, HEALTH IMPACT
OMEG NO. COMPOUND NAME TYPE CONG
£•6 G/SCM
12 B 020* W
17
20
20
20
20
20
63
19
17
17
17
17
17
17
17
72
06
02
36
18
oa
04
oa
18
16
16
16
06
16
060* W
102*
100*
103*
080*
101* P
010 P
040* P
065*
083*
080*
082*
081* P
084* P
086*
010
140*
380* W
010
060* W
060* H
040* W
050* W
043*
083*
081*
040* W
020* W
042*
16 A 041*
16 A 062*
18 A 060* M
02 B 120* P
N-METHYL-N-NITROSOANILINE
4-NITROBIPHENYL
2r5-DINITROPHENOL
DINITROPHENOLS
2»6-DlNITROPHENOL
2-AMINO-4,6-DlNlTROPHENOL
2»4-DINITROPHENOL
MERCURY
2,4-DICHLOROPHENOL
2,5-DINITROTOlUENE
2,3-OINITHOTOLUENE
DINITROTOLUENES
3»4-DlNlTROTOLUENE
2»6-DINlTROTOLUENE
2,4-DINITROTOLUENE
3,5-DINITROTOLUENE
IRON (AS FE+2)
OLEIC ACID
HEXACHLOROCYCLOHEXANE
BARIUM
1,4-DIHYDROXYBENZENE
1-CHLORO-1,3-EPOXYPROPANE
2-CHLORO- 1 , 2-EPOXYPROPANE
EPICHLORHYOHIN
P-CRESOL
P-ETHYLPHENOL
0-ETHYLPHENOL
CRESOLS
ETHYLENE CLYCOL
0-CRESOL
M-CRESOL
M-ETHYLPHENOL
ETHYLPHENOLS
HEXACHLOP08UTADJCNE
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
8
T
T
8
T
T
T
T
T
T
T
T
T
T
T
T
T
T
4.70E
4. TOE
4.70E
4.70E
4.70E
4.70E
4. TOE
1.60E
2.20E
4.70E
4. TOE
4. TOE
4.70E
4.70E
4.70E
4.70E
> 3.10E
9.10E
1.30E
> 1.20E
4.70E
4. TOE
4.70E
4.70E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
6.80E
02
02
02
02
02
02
02
01
03
02
02
02
02
02
02
02
02>
02
02
02>
02
02
02
02
03
03
03
03
03
03
03
03
03
02
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
2
2
2
2
2
2
2
2
2
US
.61E-01
.61E-01
.40E-01
.4UE-01
.40E-01
.40E-01
.aoE-oi
.20E-01
.14E-01
.13E-01
.13E-01
.13E-01
.13E-01
.13E-01
.13E-01
.13E-01
,10E-01>
.80E-01
.bOt-01
,40E-01>
.40E-01
.40E-01
.40E-01
.40E-01
.2UE-01
.20E-01
.20E-U1
.20E-01
.20E-01
.20E-U1
2.20E-01
2.20E-01
2.20E-01
2.14E-V1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1
1
1
1
1
wos
ti/9
.92E
.92E
.71E
.71E
.71E
.71E
.71E
.60E
.53L
.53E
.S3E
.53t
,53t
.S3E
.53t
.53E
.50E
.22E
.lot
.93E
,90t
.VOE
.VOE
.9QE
.60t
.80t
.60E
.bOE
.bOE
.faOE
1.60E
i.eot
i.eot
1.73E
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
LCCAT
5
5
5
5
5
5
5
6
5
5
5
5
5
5
5
7
2
5
5
5
5
6
6
6
1
-------
TEST BURNER FLUE GAS COMPOSITE, HEALTH IMPACT
OMEG NO.
COMPOUND NAME
TYPE CONC US
E-6 U/SCM
LCCAT
G/S
21 B 107*
23 B 200*
21 B 101*
21 8 105*
21 B 102*
21 B 10B*
21 B 108*
21 B 109*
21 B 103*
21 B 100*
21 B 104*
21 B 106*
21 B 10A*
12 A 060* P
07 B 100* M
02 A 160* P
23 C 020*
18 A 144*
18 A 141*
18 A 140*
18 A 143*
18 A 145*
18 A 142* P
18 A 14b*
08 D 080*
08 A 103*
08 A 104*
08 A 102*
08 A 101*
08 A 100*
09 A 120* W
23 A 020*
22 C 080* P W
08 A 140*
tn
i
GO
UJ
8-METHYL 8ENZOCOPHENANTHRENE
BENZ(C)ACRIDINE
BENZO(C)PHENANTHRENE
6-METHYL BENZOCUPHENANTHRENE
1-METHYL BENZOCUPHENANTHRENE
ISOPROPYL BENZOCUPHENANTHRENE
2-ETHYL BENZOCUPHENANTHRENE
6-ETHYL BENZOCUPHENANTHRENE
2-ME7HYL BENZOCUPHENANTHKENE
BENZOCUPHENANTHRENt & ALKYL DERIVATIVES
5-METHYL BENZOCUPHENANTHRENE
7-METHYL BENZOCUPHENANTHRENE
N-PROPYL BENZOCUPHENANTHRENE
N-NITROSODIPROPYLAMINE
CAMPHOR
BROMOFOHM
PYRROLE
2, 6-XYLENOL
2,3-XYLENOL
XYLENOLS
2,5-XYLENOL
3,5-XYLENOL
2,4-XYLENOL
3f«-XYLENOL
METHYL METHACRYLATE
CAPRIC ACID
LAURIC ACID
CAPRYLIC ACID
CAPROIC ACID
SATURATED LONG CHAIN ACIDS (MN;ll6-20l)
TETRAMETHYLSUCCINONITKILE
PYKIDINE
BENZOCBJ FLUOR ANTHENE
OLEIC ACID
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
7
T
T
T
T
T
T
T
T
T
T
T
T
T
T
4.40E 01
2.20E 03
4.40E 01
4.40E 01
4.40E 01
4.40E 01
4.40E 01
4.40E 01
4.40E 01
4.40E 01
4.40E 01
4.40E 01
4.40E 01
4.70E 02
2.20E 03
8.80E 02
4.70E 02
2.20E 03
2.20E 03
2.20E 03
2.20E 03
2.20E 03
2.20E 03
2.20E 03
2.20E 03
9.10E 02
9. JOE 02
9.10E 02
9.10E 02
9.10E 02
4.70E 02
2.20E 03
1.30E 02
4.70E 02
2.00E-01
2.00E-01
2.00E-01
2.UOE-01
2.00E-01
2.00E-01
2.00E-01
2.00E-01
2.00E-01
2.00E-01
2.00E-01
2.00E-U1
2.00E-U1
2.00E-01
1.83E-01
1.80E-01
1.74E-01
1.70E-01
1.70E-01
1.70E-01
1.70E-01
1.70E-01
1.70E-01
1.70E-01
l.oOE-01
l.OOE-01
1.60E-01
1.60E-01
1.60E-01
1.60E-01
l.OOE-01
l.bOE-01
1.44E-U1
1.42E-01
1.61E 03
1.61E 03
l.bit 03
l.blt 03
l.blt 03
l.blfc 03
l.blfc 03
1.61E 03
l.blt 03
l.blfc 03
l.blfc 03
l.blt 03
l.blt 03
1.60E 03
1.50E 03
1.42t 03
1.40E 03
1.40E 03
1.40t 03
1.40t 03
l.aot 03
l.aot 03
l.aot 03
l.aot 03
1.30E 03
1.30t 03
1.30t 03
1.30E U3
1.30E 03
1.30E 03
1.30t 03
1.20t 03
1.20E 03
1.20E 03
3
6
3
3
3
3
3
3
3
3
3
3
3
5
6
1
5
6
6
6
6
6
6
6
6
7
7
7
7
7
5
6
2
5
-------
7
00
TEST BURNER FLUE 0*8 COMPOSITE, HEALTH IMPACT
DME.G NO.
COMPOUND NAME
TYPE CONC
E-6 6/8CM
US
MDS
LCCAT
23 B 021*
23 B 022*
23 B 020*
20 A 060* P
03 B 020* M
03 B 040* M
17 B 040* M
IS A 160* H
17 B 060* N
23 A 146*
23 A 143*
23 A 145*
23 A 144*
OS B 100* W
23 A 142*
23 A 140*
23 A 141*
21 D 060*
10 C 020*
IB A 020* P
18 B 020*
20 A 040*
23 D 020* M
17 A 060* M
23 D 040*
46 A 010 P
23 B 260*
19 B 020* N
IB A 103*
18 A 101*
19 B 023*
19 B 022* P
18 A 100*
06 4 060*
OU INCLINE
ISOQUINOLINE
QUINOLINES
4-NITROPHENOL
lr4-DIOXANE
1, J-DIOXANE
l-CHLORO-2-NITROBENZENE
BIPHENYL
1-CHLORO-4-NITROBENZENE
2,3,4,6-TETRAMETHYL PYRlDlNE
2,5-DIMETHYLPYRIDlNE
3,4-DIMETHYLPYRIDINE
2r6-DIMETHYLPYRlDINE
1-PHENYLETHANOL
2,4-DIMETHYLPYRIDINE
DISUBSTITUTED POLYSUB8TITUTED ALKYL PYRXOINE8
2r3-DlMETHYLPYRIDlNE
DIBENZO(A,L)PYRENE
ANILINE
PHENOL
CATECHOL
3-NITROPHENOL
BENZOTHIAZOLE
4-NITrfOBIPHENYL
METHYL BENZOTHIAZOLE
LEAD
DIBENZ(C,H)ACRIDINE
CHLORINATED CRE30LS
M-PHENYLPHENOL
0-PHENYLPHENOL
CHLORINATED-P-CRE80L8
CHLORINATED-M-CRE80L8
PHENYLPHEN0L8
MLE«IC ACID
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
8
T
T
T
T
T
T
T
f
2.20E 03 1.40E-01
2.20E 03 1.40E-01
2.20E 03 1.40E-01
2.20E 03 1.40E-01
4.706 02 1.30E-U1
4.70E 02 1.306-01
1.30E 02 1.30E-01
1.30E 02
1.30E 02
2.20E 03
2.20E 03
2.20E 03
2.20E 03
2.20E 03
2.20E 03
2.20E 03
2.20E 03
1.30E 02
2.20E 03
2.20E 03
2.20E 03
2.2UE 03
4.70E 02
1.30E 02
4.70E 02
l.SOE 01
.30E-01
.30E-01
.22E-01
.22E-01
.22E-01
.22E-01
.22E-01
.226-01
.226-01
.22E-01
•20E-01
.20E-01
.206-01
.10E-01
.10E-01
.10E-01
.OOE-01
.006-01
.OOE-01
2.20E 03 9.60E-02
2.20E 03 9.60E-02
2.20E 03 9.60E-02
2.2UE 03 9.60E-02
2.20E 03 9.60E-02
2.20E 03 9.60E-02
2.20E 03 9.60E-02
2.20E 01 9.60E-02
1.11E 03
1.116 03
l.llt 03
1.116 03
1,106 03
l.lOt 03
l.lOt 03
1,106 03
1.106 03
9.906 02
.906 02
.906 02
.906 02
.906 02
.906 02
.906 02
,906 02
.546 02
.406 02
.406 02
6.906 02
8.906 02
8.836 02
8.106 02
8.106 02
8.106 02
7.726 02
7.726 02
7.726 02
7.726 02
7.726 02
7.72E 02
7.726 02
7.726 02
6
6
6
6
5
5
4
2
-------
TEST BURNER FLUE GAS COMPOSITE, HEALTH IMPACT
DMEG NO.
COMPOUND NAME
TVPfc CONC
E-6
US
LCCAT
b/S
19
18
08
08
08
17
08
08
47
02
79
18
18
18
18
02
10
07
08
10
10
10
10
10
10
10
10
17
17
17
17
17
17
17
B
A
0
D
0
A
D
D
A
A
A
A
A
A
A
A
A
8
A
C
C
c
c
c
0
c
c
A
A
A
A
A
A
A
021*
102*
300* P
282*
280* P H
020* P
281*
283*
080 P
180*
010 P
161*
162*
163*
160*
320* P
080*
ObO* P
040*
065*
060*
064*
063*
062*
020* W
066*
061*
082*
084* P
061* P
083*
086*
085*
080*
CHLORINATEO-0-CRESOLS
P-PHENYLPHENOL
DI-2-ETHYLHEXYL PHTHALATE
DltTHYL PHTHALATE
PHTHALATE ESTERS (Mw:194-27?)
NITROBENZENE
DIMETHYL PHTHALATE
DI-N-8UTYL PHTHALATE
HYDROGEN CYANIDE
DIbROMOOICHLOkOMETHANE
SILVER
6-ETHYL-M-CRESOL
4-ETHYL-O-CRESOL
2-ETHYL-P-CRESOL
ETHYL CRESOLS
HEXACHLOKOETHANE
1,2-OIAMINOETHANE
ISOPHURONE
ACETIC ACID
3,4-XYLlDINE
DIMETHYLANILINES
2,6-XYLIDINE
2,5-XYLIDlNE
2,4-XYLIDINE
N,N-DIMETHYLANILINE
3,5-XYLIDlNE
2,3-XYLIDINt
3,4-OINITROTOLUENE
2,4-DINITROTOLUENE
2>6-OINITROTOLUENE
2,3-OINITROTOLUENE
3,5-DlNlTKOTOLU£NE
2, b-UINlTROTOLUENE
DINITROTOLUENES
T
T
T
T
T
T
T
T
D
T
S
f
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1
T
T
T
T
2.20E
2.20E
4.70E
4.70E
U.70E
4.70E
4.70E
4.70E
1.02E
1.30E
03
03
02
02
02
02
02
02
03
02
9.20E-01
2.20E
2.20E
2.20E
2.20E
8.80E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
2.20E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
03
03
03
03
02
03
03
03
03
03
03
03
03
03
03
03
02
02
02
02
02
02
02
9.60E-02
9.60E-02
9.40E-02
9.40E-U2
9.40E-02
9.40E-02
9. 40E-U2
9.40E-02
V.33E-02
9.30E-02
9.20E-U2
9.20E-02
9.20E-02
9.20E-02
9.20E-02
8.80E-02
8.80E-U2
8.80E-02
8.80E-02
8.80E-02
8.80E-02
8.80E-02
8.80E-02
8.80E-U2
8.80E-02
8.80E-02
8.bOE-02
8. 70L-02
8.70E-02
8.70E-02
8.70E-02
8./OE-02
8.70E-02
8.70E-02
7.72t
7.72E
7.60t
7.60t
7.60E
7.oOh
7.60L
7.60E
7,b4t
7.50E
7.43E
7.40E
7.4Qfc.
7.40E
7.40t
7. lit
7.11E
7. lit
7. lit
7.11E
7. HE
7.11E
7. HE
7. HE
7. HE
7.HE
7. lit
7.00t
7.00E
7.00E
7.00t
7.00E
7.00E
7.00E
02
02
02
02
02
02
02
02
02
02
02
02
02
02
U2
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
b
6
5
5
5
5
5
5
2
6
6
6
6
1
6
6
6
6
6
6
6
6
6
6
6
4
4
4
4
4
4
a
M
i
00
Ui
-------
oo
TEST BURNER FLUE CA8 COMPOSITE, HEALTH IMPACT
OMf
21
22
22
06
06
08
08
06
02
02
02
23
23
23
23
23
10
19
08
21
21
21
08
18
19
04
04
15
04
27
16
10
10
10
:G
A
0
C
B
B
B
A
A
A
A
C
A
A
C
B
B
B
A
A
A
A
A
6
NO.
180* P W
020* P W
020* P
101*
102*
100*
103*
104*
100* P
104*
103*
101*
102*
100* W
103*
160*
060*
020* P
020*
141*
140*
142*
060*
060*
040* P
050* W
060* W
060* W
040* W
010
120*
122*
120*
080*
COMPOUND NAME
PHENANTHRENE
INDENOU,2,3-CD)PYRENE
BENZO(K)FLUORANTHENE
CAPROIC ACID
CAPRYLIC ACID
SATURATED LONG CHAIN ACIDS (MM|U6-201)
CAPRIC ACID
LAURIC ACID
DICHLORUPROPENES
TRANS-U 3-DICHLOROPROPENE
CIS-1 , 3-DICHLOROPROPENE
2-CHLOROPYRIDINE
3-CHLOROPYRIDINE
CHLOROPYRIDINES
4-CHLOROPYRIDINE
DIBENZOU,G)CARBAZOLE
ETHANOLAMINE
2-CHLOROPHENOL
FORMAMIDE
4-METHYL CHRYSENE
METHYL CHRYSENES
5-METHYL CHRYSENE
MALEIC ACID
2-METHOXYPHENOL
2, 4-DICHLOROPHENOL
EPICHLORHYDRIN
1-CHLORO-1,3-EPOXYPROPANE
4,4'-DIPHENYLBIPHENYL
2-CHLORO-lr2-EPOXYPROPANE
LITHIUM
2»2'-DIHYU«OXYDIPHENYL
3-AMINO-1-PROPANOL
PROPANOLAMJNES
l,2,J-TRJHr0ROmfW*ENf
TYPE CONC
E-6 G/SCM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
T
T
T
1.30E
1.30E
1.30E
4. TOE
4. TOE
4. TOE
4. TOE
4. TOE
6.80E
8.80E
8.60E
4. TOE
4. TOE
4. TOE
4. TOE
4. TOE
4. TOE
2.20E
2.20E
1.30E
1.30E
1.30E
2.20E
2.20E
4. TOE
.30E
.30E
• 30E
.30E
< .40E
2.20E
2.20E
2.20E
2.2PE
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
03
03
02
02
02
03
03
02
02
02
02
02
00<
03
03
03
03
8
8
8
6
8
8
8
8
6
8
6
6
6
6
6
T
7
7
7
7
7
7
6
6
6
DS
12E-02
!l2E-02
.12E-02
.10E-02
.10E-02
.10E-02
.10E-02
.10E-02
.OOE-02
.OOE-02
.OOE-02
.OOE-02
.OOE-02
.OOE-02
.OOE-02
.63E-02
.83E-02
.33E-02
.33E-02
.22E-02
.22E-02
.22E-02
.90E-02
.74E-02
.71E-02
.50E-02
.50E-02
.50E-02
.50E-02
.40E-02<
.30E-02
.llt-02
.11E-02
•llk-02
N08
G/8
6.60E
6.60E
6.60E
6.54E
6.54E
6.54k
6.54E
6.54k
6.50E
6.50k
6.50E
6.43k
6.43k
6.43k
6.43k
6.32k
6.32k
5.92k
5.92k
5.63k
5.63k
5.63k
5.60k
5.50k
5.42E
5.30k
5.30k
5.30k
5.30k
5.14E
5.10k
4.93k
4.93k
4.93t~
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
LCCAT
2
2
2
5
5
5
5
5
1
1
1
5
5
b
5
5
5
b
b
^
2
2
b
b
5
4
4
I
4
6
6
6
6
-------
OMEG NO.
TEST BURNER FLUE GAS COMPOSITE, HEALTH IMPACT
COMPOUND NAME
TYPE CONC OS
E-6 &/SCM
LCCAT
U/S
06
10
10
21
12
06
10
07
21
22
18
05
34
23
16
18
18
18
18
18
lb
18
Oe>
78
15
09
21
23
23
04
04
23
23
05
p
i
a
B
A
A
B
A
B
A
B
C
C
B
C
A
C
A
A
A
A
A
A
A
A
A
A
A
A
C
B
C
6
A
B
B
A
•i
3
080*
121*
123*
120* P
080*
041*
160*
120*
160*
080* P W
040*
040* W
010
020*
083*
041*
042*
060* W
040* W
082*
081*
043*
020* W
010 P
160* W
120* *
120*
200*
040*
100*
140* P
061
063
140 W
Y-BUTYROLACTONE
2-AMINO-l-PROPANOL
l-AMINO-2-PROPANOL
CHRYSENE
N-NITROSODIISOPROPYLAMINE
2-HYDROXYBENZOIC ACID
CYCLOHEXYLAMINE
ACETOPHENONE
PICENE
BENZO(B)FLUORANTHENE
1,3-DIHYDROXYBENZENE
T-PENTANOL
CALCIUM (AS CA+2)
PYRROLE
P-ETHYLPHENOL
M-CRESOL
0-CRESOL
ETHYLPHENOLS
CRESOLS
M-ETHYLPHENOL
0-ETHYLPHENOL
P-CRESOL
ETHYLENE GLYCOL
COPPER
BIPHENYL
TETRAMETHYLSUCCINONITRILE
BENZO(E)PYRENE
BENZCCJACRIDINE
INDOLE
2,2'-DICHLORODIISOPROPYL ETHER
2-CHLOROETHYL VINYL ETHER
2,3-UIMETHYLOUINULINE
2,8-DIMETHYLOUINOLJNE
BENZYL ALCOHOL
T
T
T
T
T
T
T
T
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
2.20E
2.20E
2.20E
1.30E
2.20E
2.20E
2.20E
2.20E
1.30E
4.40E
2.20E
2.20E
> 7.60E
1.30E
4.70E
4.70E
4.70E
4.70E
4.70E
4.70E
4.70t
4.70E
4.70E
9.30E
4.40E
1.30E
1.30E
4.70E
4.70t
4.70E
4.70E
2.20L
2.20E
2.20E
03
03
03
02
03
03
03
03
02
01
03
03
02>
02
02
02
02
02
02
02
02
02
02
00
01
02
02
02
02
02
02
03
03
03
6.11E-02
6.11E-U2
6.11E-02
b.90t-02
S.bOE-02
b.bOE-v2
5,bOE-02
5.40E-02
b.20E-02
4.90E-02
4.90E-02
4.90E-02
4.90E-02>
4.blE-02
4. /OE-02
4.70E-02
4.70E-02
4.70E-02
4. 70E-02
4.70E-02
4.70E-02
4.70E-U2
4.70E-02
4.70E-02
4.40E-02
4.33E-02
4.33E-02
4.30E-02
4.30L-02
4.30E-02
4.30E-02
4.UOE-02
4.yOt-02
4.UOE-02
4
«
4
4
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3,
3,
3,
3,
3.
3,
.93t
.93E
.V3t
.bot
.70t
.44t
,44t
.33t
.20£
.OOt
.oot
.OOE
.93t
,9ot
,80t
,80E
.bot
.bot
.bot
.bot
.bot
.bot
,bot
.bot
.t>0t
.bot
.bot
.bOt
.bOt
.bOt
.bOt
,23t
,23t
,23t
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
6
6
6
2
6
6
6
6
2
3
6
6
4
b
5
b
b
5
5
5
b
b
3
4
2
5
5
5
5
6
6
6
-------
OO
00
TEST BURNER FLUE GAS COMPOSITE, HEALTH IMPACT
DMEG
23
23
23
23
56
23
21
23
23
08
23
07
20
18
16
16
18
06
18
18
16
18
18
18
16
03
03
08
21
08
23
23
23
2J
B
B
B
B
A
B
D
B
B
A
C
B
A
A
A
A
A
A
A
A
A
A
A
A
A
B
B
D
0
D
A
A
A
4
NO.
064
066
067
060
010
065
060*
062
040
080*
140*
100* H
020* P
182
163
161
160
040*
140*
141*
146*
144*
145*
143*
142* P
020* M
040* W
160
020*
060*
061
064
ill
062
COMPOUND NAME
3»4-DIMETMYLQUINOLINE
lf3-DIMETHVLI80QUINULJNE
1 rS-OIMETHYLISOQUINOLlNE
DIMETHYLQUINOLINE8
FLUORINE (AS F-)
6r 8-DIMETHYLQUINOLINE
DlbENZO(A,L)PYRENE
2»6-DIMETHYLQUINOLINE
2-METHYLQUINOLINE
VALERIC ACID
DIBENZO(A,I)CARBAZOLE
CAMPHOR
2-NITROPHENOL
4,6-DI-TERT-BUTYL-M-CRESOL
2»6-DIMETHYL-«-HEPTYL PHENOL
2r4,6-TRlM£THYL METHYL PHENOL
POLYALKYLPHENOLS (MW>13S)
ACETIC ACID
XYLENOL3
2r3-XYLENOL
3,4-XYLENOL
2,6-XYLENOL
3,5-XYLENOL
2,5-XYLENOL
2»4-XYLENOL
1,4-DIOXANE
1,3-DIOXANE
METHYL BENZOATE
DIBENZO(A,H)PYRENE
METHYL METHACRYLATE
2-PHENYLPYRIOINE
4-N-PROPYLPYR1DINE
2,0,6-COLLlDIHC
3-tTHYLPWlDlNt
TYPE CONC
E-6 (i/SCM
T
T
T
T
8
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
2.20E
2.20E
2.20E
2.20E
l.OOE
2.20E
4.40E
2.20E
2.20E
9.10E
4.70E
4.70E
2.20E
2.20E
2.20E
2.20E
2.20E
9.10E
4.70E
4. TOE
4.70E
4.70E
4.70E
4.70E
4.70E
1.30E
1.30E
2.20E
1.30E
4.70E
2.20E
2.20E
2.20E
2.20E
03
03
03
03
02
03
01
03
03
02
02
02
03
03
03
03
03
02
02
02
02
02
02
02
02
02
02
03
02
02
03
03
03
03
OS
4.00E-02
4.00E-02
4.00E-02
4.00E-02
4.00E-W2
4.00E-02
4.00E-02
4.00E-02
4.00E-02
4.00E-02
3.91E-02
3.91E-02
3.00E-02
3.72E-02
3.72E-02
3.72E-02
3.72E-02
3.64E-02
3.61E-02
3.6U-02
3.61E-02
3.61E-02
3.61E-02
3.61E-02
3.61E-02
3.61E-02
3.61E-02
3.60E-02
3.51E-02
3.40E-02
3.20E-02
3.20E-02
3.20E-02
3.20E-02
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
WD3
G/3
.23fc
• 23fc
• 23t
.23E
.23E
»23t
,23t
.23t
• 23t
.20E
.20E
.20t
,10fc
• Olfc
.oie
.oit
.OIE
,94£
.92E
.92E
,92t
,92E
.92t
,92E
.92E
,91t
.91E
.91E
.83E
.71E
.60t
2.60E
2.60E
2.60E
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
LCCAT
6
6
6
6
6
3
6
6
7
S
5
7
5
5
5
5
5
5
5
4
4
6
2
5
6
6
6
6
-------
DMEG NO.
TEST BURNER FLUE GAS COMPOSITE, HEALTH IMPACT
COMPOUND NAME
TYPE CUiMC uS
E-b G/SCM
LCCAT
t/S
23 A
23 A
23 A
23 A
23 A
23 A
23 A
23 A
02 B
10
23
06
07
07
07
23
23
20
23
01
43
08
12
22
21
22
OS
23
23
23
23
23
23
05
B
A
D
B
B
B
B
B
A
B
B
A
A
A
C
A
D
A
A
A
A
A
A
A
B
082
063
121
060
Obi
083
120
080
120* P
100
020*
200
181
182
180
020*
021*
060* P
022*
220 w
010
060*
100
020* P
180* P W
020* P W
160
143*
146*
142*
141*
140*
144*
100* W
3-PHENYLPYRIDINE
4-ETHYLPYRIDINE
5-ETHYL-2-METHYLPYRIDINE
MONOSUBSTITUTED ALKYL PYRIDINES
2-ETHYLPYRIUINE
4-PHENYLPYRIDINE
COLLIDINES
PHENYLPYRIDINES
HEXACHLOROBUTADIENE
MORPHOLINE
PYRIDINE
DIETHYL ADIPATE
CANVONECD OR L)
DIHYDRO-(D OR DCARVQNE
CARVONES
QUINOLINES
OUINOLINE
4-NITROPHENOL
ISUUUINOLINE
DICYCLOPENTAOIENE
SILICON
MALEIC ACID
N-NITROSOUIPENTYLAMINE
BENZO(K) FLUOR ANTHENt
PHENANTHRENE
INDENO(1,2,3-CD)PYRENE
PHENETHYL ALCOHOL
2,5-DIMETHYLPYRIDlNE
2,3,4,6-TETRAMETHYL PYRIDINE
2,4-DIMETHYLPVRlDlNE
?,3-DIMETHYLPYRIDINE
DISUBSTITUTED POLYSUBSTITUTED ALKYL PYKIUINES
2f6-DIMETMYLPYRIDlNE
1-PHENYLETHANOL
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
2.2UE
2.20E
2.20t
2.20E
2.20E
2.20E
2.20E
2.20E
1.30E
2.2ut
4.70E
2.20E
2.20E
2.20E
2.20E
4.70E
4.
4.
4.
8.
> 2.
9.
2.
4.
4.
4.
2.
4.
4.
4.
4.
4.
4.
4.
70E
70E
70E
80E
90E
10E
20t
40E
4UE
40E
20E
70E
70E
70E
70 E
70E
70E
70E
03
03
03
03
03
03
03
03
02
03
02
03
03
03
03
02
02
02
02
02
02>
02
03
01
01
01
03
02
02
02
02
02
02
02
3.20E-02
3.20E-02
3.20E-02
3.20t-02
3.20E-02
3.20t-02
3.20E-02
3.20E-02
3.2Ufc-02
3.14E-02
4.13E-02
3.10E-02
3.0UE-02
3.00E-02
3.00t-02
2.93E-02
2.V3E-02
2.93E-02
2.93E-02
2.93E-02
2.90E-02>
2.84E-02
2.00E-02
2.80E-02
2.80E-02
2.80E-02
2.71E-02
2.61E-02
2.61E-02
2.61E-02
2.61E-02
2.61E-02
2.61E-02
2.blE-02
2.60E
2.60E
2.60E
2.60E
2.60t
2.bOt
2.bOt
2.60L
2.60t
2.53t
2.53E
2.bOE
2.40E
2.40L
2.40C
2.40t
2.40E
2.40t
2.40fc
2.40E
2.34E
2.30E
2.30E
2.22E
2.22E
2.22E
2.20t
2. 10E
2.1UE
2.10E
2. 10E
2. lOb
2.10E
2.10k.
02
02
02
02
02
U2
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
6
6
6
6
6
b
b
6
2
b
5
6
6
6
b
5
5
5
5
1
7
b
3
3
3
6
5
5
5
5
5
5
5
00
VO
-------
w
TEST BURNER FLUE OAS COMPOSITE, HEALTH IMPACT
OMI
23
17
02
16
08
26
18
10
23
21
23
23
21
23
13
21
05
23
18
20
13
08
14
23
23
23
23
50
15
23
33
09
25
00
•G
A
A
A
B
B
A
A
C
C
B
B
B
B
B
B
B
B
B
B
A
B
B
A
A
A
A
A
A
B
C
A
A
A
A
NO.
145*
020* P
160* P
020 W
080*
020 M
020* P
020*
120
142*
140
160
140*
120
080
141*
120
080
020*
040*
060
041*
020 N
103*
102*
100* W
101*
010 P
060* M
180*
010
100
042
000*
COMPOUND NAME
3» 4-DIMETHYLPYRlUINE
NITROBENZENE
BROHOFORH
A-CHLOROTOLUENE
Y-BUTYROLACTONE
TRIETHYL PHOSPHATE
PHENOL
ANILINE
BENZO(A)CARBAZOLE
5-METHYL CHRY8ENE
BENZO(F)QUINOLINE
BENZO(H)QUINQLINE
METHYL CHHYSENES
PHENANTHRIDINE
METHYL DI8ULFIDE
4-METHYL CHRY8ENE
BOKNEOL
ACRIDINE
CATECHOL
3-NITROPHENOL
DIPHENYL SULFIDE
2-HYDROXYBENZOIC ACID
BENZENESULFONIC ACID
4-CHLOROPYRIDINE
3-CHLOROPYRIDINE
CHLOROPYRIDINES
2-CHLOROPYRIDINE
ANTIMONY
4,4'-DIPHENYLBIPHENVL
DIBENZO(A,GKARBAZOL£
MAGNESIUM
1 / 3-OICYANO-l-HYOKOX YflUTANE
3-METHYLTHJOPH£«E
VALERIC ACID
TYPE CONC
E-b U/3CM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
8
T
T
T
4.70E
1.30E
I.JOE
1.30E
.IOE
.iOE
.70E
.70E
.70E
4.40E
2.20E
2.20E
4.40E
2.20E
2.20E
4.40E
2.20E
2.20E
4.70E
4.70E
2.20E
9. IOE
9. IOE
.30E
.30E
.30E
.30E
< .IOE
.40E
.30E
> .30E
4.70E
4.70E
.
02
02
92
US
2.61E-02
2.60E-02
2.60E-02
2.60E-02
2.52E-02
2.52E-02
2.SOE-02
2.50E-02
2.50E-02
2.44E-02
2.44E-02
2.44E-02
2.44E-02
2.44t-02
2.44E-02
2.44E-02
2.44E-02
2.44E-02
2.40E-02
2.40E-02
2.30E-02
2.30E-02
2.30E-02
2.20E-02
2.20E-02
2.20E-02
2.20E-02
2.20E-02<
2.20E-02
2.40E-02
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
MD8
G/S
.lot
.IOE
• 10E
.IOE
.oat
.oat
.oot
.oot
.oot
.oot
.oot
.oot
.oot
.oot
.oot
.oot
.oot
.oot
,90t
.90E
,90t
.03t
.bit
.HOt
.ttOt
.bOt
.bot
.bot
.bOt
.bot
2.20E-U2> 1.80E
2.13E-02
2.04E-02
1.72E
1.70t
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
U2
*. 046-02 1.70t 02
LCCAT
5
4
2
2
7
7
5
5
5
3
b
6
3
b
b
3
b
b
5
5
b
7
7
4
4
a
a
3
4
5
5
5
-------
TEST BURNER FLUE GAS COMPOSITE, HEALTH IMPACT
DMEG NO.
COMPOUND NAME
CONC US
E-6 G/SCM
LCCAT
li/S
19
18
25
18
23
19
23
19
23
18
09
25
25
23
19
18
23
18
21
22
82
18
16
18
18
02
16
16
16
16
07
10
B
A
B
A
023*
100*
040 W
103*
B 260*
B
C
3
C
A
A
A
A
C
B
A
C
C
B
C
A
A
A
A
A
A
B
B
B
B
B
A
10 C
10 C
021*
101
022* P
080
102*
080
040
041
102
020* W
101*
100
040 M
120* P
040
010 P
162*
163*
160*
161*
140* P
040
043
041
042
080* P
080*
062*
064*
CHLORINATED-P-CRESOLS
PHENYLPHENOLS
BENZO(B)THIUPHENt
M-PHENYLPHENOL
DIbENZ(C,H)ACRIDINE
CHLORINATED-0-CRESOLS
3-METHYLCARBAZOLE
CHLORINATEO-M-CRESOLS
CAHBAZOLE
P-PHENYLPHENOL
BUTYRONITRILE
METHYLTHIOPHENES
2-METHYLTHIOPHENE
9-METHYLCARBAZOLE
CHLORINATED CRESOLS
0-PHENYLPHENOL
MFTHYLCARBAZOLES
2-NAPHTHOL
CHRYSENE
BENZO(J)FLUORANTHENE
CADMIUM
4-ETHYL-O-CRESOL
2-ETHYL-P-CRESOL
ETHYL CRESOLS
6-ETHYL-M-CHESOL
OIBROMOCHLOROMETHANE
BIS(CHLOROMETHYL)BENZENES
1,4-BISCCHLOROMETH YD BENZENE
1,2-BIS(CHLOROM£THYBENZENE
1,3-BIS(CHLOROMETH YL) BENZENE
ISUPHORONE
1,2-DIAMJNOETHANE
2,4-XYLIDlNE
2/6-XYLIDINE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
4.70E
4.70E
4.7UE
4.70E
4.70E
4.70E
4.70E
4.70E
4.70E
4.70E
4.70E
4.70E
4.70E
4.70E
4.70E
4.70E
4.70E
2.20E
4.40E
1.30E
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
03
01
02
> 2.00E-01>
4.70E
4.70E
4.70E
4.70E
8.60E
1.30E
1.30E
1.30E
1.30E
4.70E
4.70E
4.70E
4.70E
02
02
02
02
02
02
02
02
02
02
02
02
02
2.04E-02
2.04E-02
2.04E-02
2.04E.-02
2.04E-02
2.04E-02
2.04E-02
2.04E-02
2.04E-02
2.04E-02
2.0UE-02
2.U4E-02
2.04E-02
2.04E-02
2.04E-02
2.04E-02
2.04E-02
2.00E-02
2.00E-02
2.00E-02
2.00t-02>
2.00E-02
2.00E-02
2.00E-02
2.00E-02
2.00E-U2
1.90t-02
1.90t-02
1.90E-02
1.90E-02
l.VOE-02
1.90t-02
1.90E-U2
1.90E-02
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1,
1,
1,
,70E
.70E
.70E
,70t
.70E
.70t
.70E
.70t
.70t
.70E
.70t
.70t
.70E
,70t
.70E
.70E
,70t
.61fc
.61t
.bit
.61t
,60t
,60t
,60t
,60t
,60t
.b2t
,b2t
.b2t
,b2t
.bit
.bit
.bit
.bit
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
U2
Od
02
02
5
5
b
b
b
b
5
b
b
b
5
b
b
b
b
5
b
6
3
2
5
b
b
b
1
2
2
2
2
b
b
b
b
tn
i
-------
I
v£>
IsJ
DMEG NO.
TEtT BURNER FLUE 648 COMPOSITE, HEALTH IMPACT
COMPOUND NAME
10 C 065*
10 C 061*
OB A 040*
10 C 066*
10 C 060*
10 C 063*
10 0 020* W
18 C 020
25 A 061
25 A 060
25 A 064
25 A 062
25 A 063
21 C 160*
04 A 200
04 A 180* P
25 A 081
25 A 080
08 0 320* P
08 A 160
02 A 360
02 A 361
17 A 043
17 A 040
04 B 040* P
17 A 042
17 A 041
04 B 080
19 A 020* P
08 C 020*
09 B 042
09 B 020 H
09 A 060*
09 B 040 H
3»4»XYLIDINE
2,3-XYLIDINE
AC6TIC ACID
3,5-XYLIDINE
OIMETHYLANIIINE8
2,5-XYLIDlNE
N,N-DIMETHYLANILINE
1-NAPHTHOL
2, 3-OIMETHYLTHIOPMENE
DIHETHYLTHIOPHENES
3r4-OIMETHYLTHIOPH£NE
2,4-DlMETHYLTHIOPHENE
2,5-DlMETHYLTHIQPHENE
PICENE
4-BROMQPHENYL PHENVL ETHER
CHLOROPHENYL PHENYU ETHE*
2, 3»5-TRIMETHYLTHIOPHENE
THIMETHYL AND TETHAMETHYL TH10PHENE8
BUTYL BENZYL PHTHALATE
BENZOIC ACIU
BROMOBUTANES
1-BROMOBUTANE
4-NITROTOLUENE
NITR010LU6N68
1,1'-DICHLORODIETHYL ETHER
3-N1TROTOLUENE
2-NITROTOLUENE
2f2'-OICHLOHOOIETMYL ETHER
2-CHLOROPHENOL
FORMAMIOE
B-NAPHTHONITRILE8
BENZONITRZLE
MALEJC ACID
NAPHTHONJTRILES
TYPE
4^ WMB
T
T
T
T
T
T
T
T
T
T
T
T
T
T
t
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
CONC
E-6 6/3CH
•70E 02
.70E 02
.706 02
.70E 02
.706 02
• 70E 02
.70E 02
.206 03
.706 02
•70E 02
•70E 02
.70E 02
.70E 02
.40E 01
«70E 02
•70E 02
.70E 02
4.70E 02
2.20E 03
2.20E 03
6.60E 02
6.80E 02
4.70E 02
4.706 02
4.70E 02
4.706 02
4.706 02
4.706 02
4.70E 02
4.70E 02
a. TOE 02
«. TOE 02
4.70E 02
4.70E 02
U9
.90E-02
.906-02
.906-02
.906-02
.906-02
.906-02
.906-02
.836-02
.806-02
.806-02
.806-02
.806-02
.806-02
.806-02
. 746-02
.746-02
.626-02
.626-02
.606-02
.606-02
.606-02
.606-02
.606-02
.606-02
.606-02
.606-02
.606-02
.606-02
.606-02
.606-02
.506-02
.506-02
.&OE-02
.50E-02
MUS LCCA
tt/8
.516 02 5
• 5U 02 5
.516 02 5
.516 02 5
.516 02 5
.5lt 02 5
.SU 02 5
.506 02 6
.50t 02 5
.506 02 5
.50E 02 5
.506 02 5
.50E 02 5
.42E 02 3
.406 02 5
.406 02 5
.306 02 5
.306 02 5
.iOt 02 6
.306 02 6
.306 02 1
.306 02 1
.306 02 5
.306 02 5
.306 02 5
.306 02 5
.30k 02 5
.306 02 5
.306 02 5
,30t 02 5
.20E 02 5
.206 02 S
.20£ 02 5
.206 02 5
-------
TEST BURNER FLUE GAS COMPOSITE, HEALTH IMPACT
DMEG NO.
COMPOUND NAME
TYPE CONC DS
E-6 U/SCM
LCCAT
U/S
09 B 041
21 C 120*
18 C 083
05 A 080
05 A 100
18 C 081
18 C 082
18 C 080
15 b 163
15 B 161
15 B 162
15 8 160
18 A 060*
08 A 180
05 B 080
18 A 120*
21 C 060
10 A 122*
18 B 080*
08 b 080*
10 A 120*
10 A 121*
10 A 123*
02 A 320* P
12 A 080*
21 D 020*
23 C 040*
02 B 103*
02 B 104*
04 A 140* P
02 B 100* P
04 B 100*
10 A 160*
08 B 041*
«
^D
LJ
A-NAPHTHONITRILES
BENZO(E)PYRENE
5-INDAMOL
N-8UTANOL
ISOBUTYL ALCOHOL
1-INDANOL
4-INOANOL
INDANOLS
P-TERPHENYL
0-TERPHENYL
M-TERPHENYL
TERPHENYLS
2-METHOXYPHENOL
ADIPIC ACID
2r6-DlMtTHYL-4-HEPTANOL
2,2'-DIHYOROXYOIPHENYL
DIBENZ( A, C) ANTHRACENE
3-AMlNO-i-PROPANOL
If 2,3-TRIH YDROXY BENZENE
Y-bUTYROLACTONE
PROPANOLAMINES
2-AMINO-1-PKOPANOL
l-AMINO-2-PROPANOL
HEXACHLOROETHANE
N-NITROSODIISOPROPYLAMINE
DIBENZO(A,H)PYRENE
INUOLE
CIS-1 , 3-DICHLOROPKQPENE
TRANS- 1 , 3-DICHLOROPKOPENE
2-CHLOROETHYL VINYL ETHER
DICHLOROPROPENES
2, 2I-OICHLOROOIISOPKOPYL ETHER
CYCLOHEXYLAMINE
2-HYOROXYbENZOIC ACID
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
4.70fc 02
4.40E 01
2.20E 03
2.20E 03
2.20E 03
2.20E 03
2.20E 03
2.20E 03
1.30E 02
1.30E 02
1.30E 02
1.30E 02
4.71/E 02
2.20E 03
2.20E 03
4.70E 02
1.30E 02
4.70E 02
4.70E 02
4.70E 02
4.70E 02
4.70E 02
4.70t 02
1.30E 02
4.70E 02
4.40E 01
1.30E 02
1.30E 02
1.30E 02
1.30E 02
1.30E 02
1.30E 02
4.70E 02
4.70E 02
l.bOt-0^
l.50t-02
1.50E-02
1.50fc.-02
1.50t-02
1.50E-02
1.50E-02
1.50E-02
1.44t-02
l.y4E-Oc?
1.44t-0e!
1.44E-02
1.44E-02
l.MOE-02
1.40E-02
1.34E-02
l.jSlE-02
1.30E-02
1.30E-02
1.30E-02
1.30E-02
1.30E-02
1.30E-02
1.30t-02
1.23E-02
1.20E-02
1.20E-02
1.20E-02
1.20E-02
1.20E-02
1.20E-02
1.20t-02
1.20E-02
1.20E-02
1.20E 02
1.20E 02
1.20L 02
1.20t 02
1.20E 02
1.20L 02
1.20t 02
1.20L 02
1.20t 02
1.20t 02
1.20E 02
1.20L 02
1.20E 02
l.llb 02
l.llt 02
l.lOt 02
1.10L 02
l.lUt 02
l.lOt 02
l.lOt. 02
l.lOt 02
l.lOt 02
l.lOt 02
1.10E 02
l.OOE 02
9.60E 01
9.54E 01
9.54E 01
9.54E 01
9.54E 01
9,b4E 01
9.54E 01
9.50E 01
9.50t 01
5
3
6
6
6
6
6
6
2
2
2
2
5
6
6
5
2
5
5
5
5
5
5
2
5
3
4
2
2
4
2
4
5
5
-------
v£>
DMEG NO,
TEST BURNER FLUE OAS COMPOSITE, HEALTH IMPACT
COMPOUND NAME TYPE CONC
E-6 G/SCM
US
wOS
LCCAT
05
07
23
16
16
16
05
18
23
23
20
65
04
65
04
16
69
62
71
08
81
38
02
28
21
02
63
21
16
35
12
02
37
21
c
B
C
A
A
A
C
B
C
C
A
A
A
A
B
A
A
A
A
D
A
A
A
A
A
A
A
A
A
A
B
B
A
A
060
120*
140*
161
162
160*
040*
040*
060
061
020*
010
180*
010
040*
160*
010
010
010
320*
010
010
140*
010
020*
340*
010
140*
200*
010
040*
060*
010
020*
P
N
P
P
P
P
P
P
P
P
P
P
P
P
P N
P
P
A-TERPINEOL
ACETOPHENONE
DIBENZO(A,I)CARBAZOLE
1 , 2, 4-TRICHLORU8ENZENE
HEXACHLOROBENZENt
POLYCHLORINATED BENZENES
T-PENTANOL
1 , 3-DIHYDROXYBENZENE
METHYLINDOLES
2-METHYLINOOLE
2-NITROPHENOL
VANADIUM
CHLOROPHENYL PHENYL ETHER
URANIUM
Ifl'-DICHLORODIETHYL ETHER
POLYCHLORINATED BENZENES
MOLYBDENUM
TITANIUM
MANGANESE
BUTYL BENZYL PHTHALATE
ZINC
ALUMINUM
DIBROMOCHLOROMETHANE
SODIUM
NAPHTHALENE
DICHLOROPROPANES
ZIRCONIUM (A3 ZR*4)
ANTHRACENE
CHLORONAPHTHALENE8
STRONTIUM
FLUORANTHENE
TETRACHLOROETHENE
BORON
NAPHTHALENE
T
T
T
T
T
T
T
T
T
T
T
8
T
8
T
T
S
S
S
T
8
S
T
S
T
T
S
T
T
3
T
T
8
T
2.20E
4.70E
1.30E
1.30E
1.30E
1.3UE
4.70E
4.70E
4.70E
4.70E
4.70E
3.60E
1.30E
03
02
02
02
02
02
02
02
02
02
02
00
02
< 4.00E-02<
1.30E
4.40E
1.60E
2.10E
1.70E
4.70E
.30E
.60E
.30E
> .40E
.30E
6.60E
• 20E
.30E
1.30E
5.50E
ItlOE
6.60E
4.006
4.40E
02
01
01
01
01
02
01
01
02
02>
02
02
01
02
02
00
02
02
00
01
1.20E-02
1.14E-02
1.10E-02
1.10E-02
1.10E-02
1.10E-02
1.04E-02
1.04E-02
1.04E-02
1.04E-02
8.10E-03
7.20E-03
4.81E-03
4.44E-03<
4.33E-03
3.70E-03
3.60E-03
3.50E-03
3.40E-03
3.40E-03
3.30E-03
3.10E-03
2.90E-03
2.64E-03>
2.60E-03
2.51E-03
2.40E-03
2.32E-03
1.90E-03
1.80E-03
1.44E-03
1.31E-03
i. 306-03
6.00E-04
9.40E
9.30E
e.bot
6.80E
8.80E
e.bOE
8.43E
8.43E
8.43E
8.43E
b. bat
5.81E
3.90E
3.60E
3.50E
3.00E
2.90E
2.b2t
2.74E
2.71E
2.62E
2. 50t
2.33E
2.13E
2. IGt
2.03E
1.93E
1.90E
1.52E
1.43E
1.20E
1.10E
1.04E
7. lit
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
00
6
5
4
2
2
2
5
5
5
5
5
4
4
3
5
2
I
1
2
2
2
1
3
-------
TEST BURNER FLUE GAS COMPOSITE, HEALTH IMPACT
DMEG NO.
COMPOUND NAME
TYPE CONC US
E-6 G/SCM
LCCAT
G/S
21
16
21
47
22
16
16
16
02
44
15
15
16
39
02
21
16
16
16
15
15
16
61
84
31
66
30
60
84
57
01
21
16
22
A
A
B
A
B
A
A
A
A
A
A
A
A
A
B
B
A
A
A
A
A
A
A
B
A
A
A
A
C
A
A
B
A
A
i 140*
200*
. 180*
060
040*
120*
100*
020*
340*
010
040*
060*
140*
010
060*
160*
120*
100*
020*
040*
060*
140*
010
010
010
010
010
010
010
010
020
060
220*
020*
P
P
P
P
P H
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
W
W
PH
ANTHRACENE
CHLORONAPHTHALENES
PYRENE
AMMONIA
FLUORANTHENE
1,3-DICHLOROBENZENE
1,2-DICHLOROBENZENE
CHLOROBENZENE
DICHLOROPROPANES
GERMANIUM
TOLUENE
ETHYL BENZENE
1,4-DICHLOROBENZENE
GALLIUM
TETRACHLOKOETHENE
PYRENE
1,3-DICHLOROBENZENE
1,2-DICHLOROBENZENE
CHLOROBENZENE
TOLUENE
ETHYL BENZENE
1,4-DICHLOROBENZENE
YTTRIUM (AS Yt3)
CERIUM
CESIUM
NIOBIUM (AS NB+3)
RUBIDIUM (AS RBt)
SCANDIUM
PRASEODYMIUM
CHLORINE (AS CL-)
METHANE
7, 12-DIMETHYLBENZ( A) ANTHRACENE
POLYCHLORINATED d!PH£NYLS
FLUORENE
T
T
T
D
T
T
T
T
T
S
T
T
T
S
T
T
T
T
T
T
T
T
S
S
S
S
S
S
S
S
u
D
U
T
4.40E 01
4.40E 01
1.30E 02
< l.OOE OK
4.40E 01
1.30E 02
1.30E 02
1.30E 02
1.30E 02
2.00E-01
1.30E 02
1.30E 02
1.30E 02
< 1.30E 00<
1.30E 02
4.40E 01
4.40E 01
4.4UE 01
4.40E 01
4.40E 01
4.40E 01
4.40E 01
< 2.00E-02<
6.20E-01
1.10E 00
> 1.00E-01>
< 3.50E-OK
< 5.00E-02<
1.30E-02
3.30E 01
O.OOE-01
O.OOE-01
O.OuE-01
4.40E 01
7.90E-04
6.40E-04
b.70t-04
5.00E-04<
4.VOE-04
4.33E-04
4.33E-04
3.71E-04
3.71E-04
3.60E-04
3.42E-04
3.00E-04
2.VOE-04
2.60E-04<
1.94E-04
1.V1E-04
l.bOE-04
l.bOE-04
1.30E-04
1.20E-04
1 .UOE-04
9.bOE-05
2.00E-05<
1.70E-05
1.34E-05
4.b4E-06>
2.91E-06<
9.43E-07<
2.b4E-07
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
6.34E 00
5.20E 00
4.60E 00
4.bOt 00
4.0QE 00
3.bOE 00
3.bOE 00
3.00E 00
3.0QE 00
2.90E 00
2.80E 00
2.40E 00
2.33E 00
2. lot 00
1.60E 00
l.b4E 00
1.20L 00
1.20E 00
1.01E 00
9.40E-01
6.10E-01
7.9ot-0l
1.61t-01
1.40E-01
l.iOt-01
3.70E-02
2.40E-02
7.62L-03
2.10E-03
O.OOE-01
O.OOE-01
O.OOt-01
O.OOt-01
O.OOt-01
3
3
2
3
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
2
2
3
tn
I
-------
TEST BURNER FLUE CAS COHl»08ITt, HEALTH IMPACT
DMEG NO.
21 C 100* P W
53 A 010
22 A 020* PH
21 C 080* P
04 A 160* P
OU A 160* P
21 0 060* PH
21 D 080* PH
21 A 100* PH
01 A 040
01 A 060
29 A 010
84 D 010
01 A 100
01 A 140
01 B 020
59 A 010
45 010
21 100* PH
21 120* PH
21 120* PH
01 080
58 A 010
COMPOUND NAME
BENZO(A)PYRENE
SULFUR
FLUORENE
OIBENZ( A, H) ANTHRACENE
A-CHLOROBUTYL ETHYL ETHER
A-CHLOROBUTYL ETHYL ETHER
BENZO(GHI)PERYLENE
BENZO(GHI)PERYLENE
ACENAPHTHENE
ETHANE
PROPANE
POTASSIUM
NEODYMIUM
PENTANES
HEXANES
ETHYLENE
IODINE (AS I-)
TIN
ACENAPHTHENE
ACENAPHTHYLENE
ACENAPHTHYLENE
BUTANES
BROMINE
TYPE
D
S
T
D
T
T
T
T
T
D
D
8
8
D
D
D
8
S
T
T
T
D
3
CONC
E-6 G/SCM
O.OOE-01
> 1.20E 02>
1.30E 02
O.OOE-01
1.30E 02
4. TOE 02
1.30E 02
4.40E 01
1.30E 02
O.OOE-01
O.OOE-01
> 4.90E 02>
2.50E-02
O.OOE-01
O.OOE-01
O.OOE-01
6.60E-01
1.50E 00
4.40E 01
1.30E 02
4.40E 01
O.OOE-01
4.40E-01
OS
O.OOE-01
O.OOE-01>
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
0.00t-01>
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
NDS
b/s
o.oot-ui
o.oot-oi
O.OOE-01
o.oot-oi
o.oot-oi
O.OOt-01
O.OOE-01
O.OOt-01
y.uot-oi
O.OOE-01
o.oot-oi
O.OOh-01
o.oot-oi
o.oot-oi
o.oot-oi
O.OOE-01
O.OOL-01
O.OOE-01
o.oot-oi
o.oot-oi
o.oot-oi
0.00h-0l
O.OOE-01
LCCAT
2
2
2
4
5
2
3
2
3
2
3
-------
LCCAT
1
2
I
4
5
6
7
TEST BURNER FLUE GAS COMPOSITE
FLOW RATE a 8080 G/S (6.77 SCM/S, DRY BASIS)
29.666 SCM AT 25C AND 760 MM HG SAMPLED
TOTAL ORGANIC LOADING * 5.4 MG/SCM
TOTAL TCO = NR TOTAL GRAV • 5.4 MG/SCM
55.OX ORIGINAL SAMPLE TO LC
LC TCO c NR LC GRAV = 90.3 MG LC TOTAL 3 90.3 MG
ORGANIC LOADING
880.0
130.0
44.0
130.0
470.0
2200.0
910.0
FLOW RATE s 8080.00
STATE: GAS, UNITS IN MICROGRAMS/SCM
IMPACT! ECOLOGY
EXPERIMENTALY DETERMINED DATA
SPARK SOURCE DATA
-------
M
I
CO
TEST BURNER FLUE GAS COMPOSITE, ECOLOGY IMPACT
DMEG NO.
COMPOUND NAME
TYPE CONC DS
E-6 G/SCM
LCCAT
b/b
65
83
15
15
47
47
15
15
42
53
16
01
01
01
01
21
21
21
21
54
01
01
37
58
82
34
84
31
57
68
74
78
56
39
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
8
C
C
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
010
010
120*
120*
080
060
040*
040*
080
060
220
060
080
100
140
040*
060
080*
100*
010
020
040
010
010
010
010
010
010
010
010
010
010
010
010
p
p
p
p
p
p
p
p
p
w
p
p
p
VANADIUM
MERCURY
ISOPROPYL BENZENE
ISOPROPYL BENZENE
HYDROGEN CYANIDE
AMMONIA
TOLUENE
TOLUENE
CARBON DIOXIDE
SULFUR DIOXIDE
POLYCHLORINATED BIPH£NYLS
PROPANE
BUTANES
PENTANES
HEXANES
8ENZ(A)ANTHRACENE
7, 12-OIMETHYLBENZ(A)ANTHRACENE
DIBENZC A, H) ANTHRACENE
BENZO(A)PYRfcNE
SELENIUM
METHANE
ETHANE
BORON
BROMINE
CADMIUM
CALCIUM (AS CA+2)
CERIUM
CESIUM
CHLORINE (AS CL-)
CHROMIUM
COBALT
CUPPER
FLUORINE (AS F-)
GALLIUM
S
D
T
T
D
D
T
T
D
D
D
D
D
D
D
D
D
D
D
D
D
D
S
S
S
S
S
S
S
S
S
S
S
S
3
1
1
4
1
< 1
1
4
9
2
0
0
0
0
0
4
0
0
0
< 1
0
0
4
4
> 2
> 7
6
1
3
3
1
9
1
< 1
.606 00
.60E 01
.30E 02
.40E 01
.02E 03
.OOE OK
.30E 02
.40E 01
,80E 07
.70E 05
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.50E 02
.OOE-01
.OOE-01
.OOE-01
,30E 02<
.OOE-01
.OOE-01
.OOE 00
.40E-01
,OOE-01>
.80E 02>
.20E-01
.10E 00
.30E 01
.70E 01
.30E 02
.30E 00
.OOE 02
.30E 00<
3
1
1
3
3
2
2
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
,60t 00
.60E 00
.10E-01
.70E-02
.02E-02
,90E-02<
.82E-02
.60E-03
.OOE-01
.OOE-01
.oot-oi
.OOE-01
.OOE-01
.OOE-01
.oot-oi
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-OK
.OOE-01
.OOE-01
.OOE-01
.OOE-01
,OOE-01>
,00t-01>
.oot-oi
.OOE-01
.OOE-01
.OOE-01
.oot-oi
.OOE-01
.OOE-01
,OOE-01<
2.90E 04
1.30E 04
8.80E 02
3.00t 02
2.44t 02
2.30t 02
2.30t 02
7.72t 01
O.OOt-01
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
0. OOE-01
o.oot-oi
o.oot-oi
0. OOE-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
0. OOE-01
2
3
2
3
2
2
2
2
2
-------
TEST BURNER FLUE GAS COMPOSITE* ECOLOGY IMPACT
DMEG NO.
44 A 010
59 A 010
72 A 010
46 A 010 P
27 A 010
33 A 010
71 A 010 P
69 A 010
84 D 010
76 A 010 P
66 A 010
48 A 010
77 A 010
29 A 010
84 C 010
30 A 010
60 A 010
43 A 010
79 A 010 P
28 A 010
35 A 010
53 A 010
45 A 010
62 A 010
85 A 010
01 B 020 W
61 A 010
81 A 010 P
63 A 010
02 A 140* P
02 A 140* P
02 A 160* P
02 A 160* P
02 A 320* P
COMPOUND NAME
GERMANIUM
IODINE (AS I-)
IRON (AS FE+2)
LEAD
LITHIUM
MAGNESIUM
MANGANESE
MOLYBDENUM
NEODYMIUM
NICKEL
NIOBIUM (AS NB+3)
PHOSPHORUS
PLATINUM
POTASSIUM
PRASEODYMIUM
RUBIDIUM (AS RBt)
SCANDIUM
SILICON
SILVER
SODIUM
STRONTIUM
SULFUR
TIN
TITANIUM
URANIUM
ETHYLENE
YTTRIUM (AS Yt5)
ZINC
ZIRCONIUM (AS ZR*4)
DIBROMOCHLOROMETHANE
DIBROMOCHLOROMETHANE
BROMOFORM
BROMOFORM
HEXACHLOROETHANE
TYPE
S
S
S >
S
3 <
S >
S
S
S
S
S >
S
S
S >
S
S <
S <
S >
S
S >
3
8 >
S
S
S <
D
8 <
S
3
T
T
T
T
T
CONC US WD3
E-6 G/SCM G/S
2.00E-01 O.OOE-01 O.OOE-01
6.60E-01 O.UOE-01 O.OOt-01
3.10E 02> O.OOE-01> O.OOt-01
1.5UE 01 O.UOE-01 O.UOE-01
1.40E 00< O.OOE-01< O.OOE-01
1.30E 02> O.UOE-01> O.UOE-01
1.70E 01 O.OOE-01 O.OOE-01
1.80E 01 O.UOE-01 O.UOE-01
2.50E-02 O.UOE-01 O.OOt-01
4.50E 01 O.UOE-01 O.OOt-01
1.00E-01> O.OOE-01> O.OOt-01
1.70E 02 O.OOt-01 O.OOt-01
1.30E 00 O.OOE-01 O.OOt-01
4.90E 02> O.UOE-01> O.OOt-01
1.3UE-02 O.UUE-U1 O.OOt-01
3.50E-OK O.OOE-01< O.OOt-01
5.0UE-02< O.OOE-OK O.OOt-01
2.90E 02> O.OOE-01> O.OOE-01
9.20E-01 O.OOE-01 O.OOt-01
1.4UE 02> O.OOE-01> O.OOt-01
5.50E 00 O.OOt-01 O.OOt-01
1.20E 02> O.OOE-01> O.OOt-01
1.5UE 00 O.OOE-01 O.UOE-01
2.10E 01 O.OOE-01 O.Out-01
4.0UE-02< O.OOE-U1< O.OOt-01
O.OOE-01 O.UOE-01 O.OOt-01
2.0UE-02< O.UO£-01< O.OOt-01
1.30E 01 O.UOE-U1 O.OOt-01
1.20E 01 O.OOE-01 O.OOt-01
8.80E 02 O.OOE-01 O.OOt-01
1.30E 02 O.UOE-U1 O.OOt-01
8.80E 02 O.OOE-U1 O.OOt-01
1.30E 02 O.UOE-01 O.OOE-U1
8.80E 02 O.OOE-01 O.UOE-01
LCCAT
1
2
1
2
1
-------
o
o
TEST BURNER FLUE GAS COMPOSITE* ECOLOGY IMPACT
DMEG NO.
COMPOUND NAME
TYPE CONC US
E-b li/SCM
LCCAT
02
02
02
02
02
02
02
02
02
02
02
04
04
04
04
04
04
04
04
04
04
07
07
08
08
06
08
08
08
10
10
12
12
12
A
A
A
B
B
B
B
B
B
B
B
A
A
A
A
A
A
B
B
B
B
B
B
D
D
D
D
0
0
C
C
A
A
A
320*
340*
340*
060*
080*
100*
100*
120*
120*
140*
140*
140*
140*
160*
160*
180*
180*
020*
020*
040*
040*
080*
080*
260*
280*
300*
300*
320*
320*
140*
140*
020*
020*
040*
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
HEXACHLORUETHANE
OICHLOROPROPANES
OICHLOROPROPANES
TETRACHLOROETHENE
TETRACHLOROETHENE
DICHLOROPROPENES
OICHLOROPROPENE5
HEXACHLOROBUTAOIENE
HEXACHLOROBUTAOIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLORUCYCLOPENTADIENE
2-CHLOROETHYL VINYL ETHER
2-CHLOROETHYL VINYL ETHER
A-CHLOROBUTYL ETHYL ETHER
A-CHLOROBUTYL ETHYL ETHER
CHLOROPHENYL PHENYL ETHER
CHLOROPHENYL PHENYL ETHER
lr l'-DICHLOROMETHYL ETHER
lr I'-DICHLOROMETHYL ETHER
If I'-DICHLORODIETHYL ETHER
If I'-DICHLORODIETHYL ETHER
ISOPHORONE
ISOPKQRONE
PHTHALATE ESTERS (M*:l94-279)
PHTHALATE ESTERS (MWj 194-279)
OI-2-ETHYLHEXYL PHTHALATE
DI-2-ETHYLHEXYL PHTHALATE
BUTYL BENZYL PHTHALATE
BUTYL BENZYL PHTHALATE
BENZIDINE
BENZIDINE
N-NITROSODIMETHYLAMJNE
N-NJTROSOOIMETHYLAMINE
N-NITROSOOJErHYLAHINE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1.30E
8.60E
1.30E
d.eot
1.30E
6.80E
1.30E
8.80E
1.30E
e.eut
1.30E
1.30E
4.70E
1.30E
4.70E
1.30E
4.70E
1.30E
4.70E
1.30E
4.70E
4.70E
2.20E
4.70E
2.20E
4.70E
2.20E
4.70E
2.20E
4.70E
2.20E
4.70E
2.20E
4.70E
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
03
02
03
02
03
02
03
02
03
02
03
02
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.oot-oi
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
O.OOE-01
O.OOt-01
o.oot-oi
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
2
1
2
1
2
1
2
1
2
1
2
4
5
4
5
4
5
4
5
4
b
5
6
5
6
5
b
5
b
5
b
5
6
5
-------
TEST BUHNER FLUE GAS COMPOSITE, ECOLOGY IMPACT
OMEG NO.
12 040* P
12 060* P
12 060* P
50 010 P
49 010 P
15 060* P
15 060* P
38 A 010
36 A 010
16 A 020* P
16 A 020* P
16 A 100* P
16 A 100* P
16 A 120* P
16 A 120* P
16 A 140* P
16 A iao* P
16 A 160* P
16 A 160* P
16 A 200* P
16 A 200* P
17 A 020* P
17 A 020* P
17 A 081* P
17 A 081* P
17 A 084* P
17 A 084* P
18 A 020* P
18 A 020* P
18 A 142* P
18 A 142* P
19 A 020* P
19 A 020* P
19 A 040* P
COMPOUND NAME
N-NITROSOOIETHYLAMINE
N-NITROSOD1PROPYLAMINE
N-NITROSODIPROPYLAMINE
ANTIMONY
ARSENIC
ETHYL BENZENE
ETHYL BENZENE
ALUMINUM
BARIUM
CHLOROBENZENE
CHLOROBENZENE
1,2-DICHLOROBENZENg
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1, 4-OICHLOROBENZENE
1,4-DICHLOROBENZENE
POLYCHLORINATEO BENZENES
POLYCHLORINATEO BENZENES
CHLORONAPHTHALENES
CHLORONAPHTHALENES
NITROBENZENE
NITROBENZENE
2,6-DINlTROTOLUENE
2,6-DlNlTROTOLUENE
2,4-DINITROTOLUENE
2,4-DINITROTOLUENE
PHENOL
PHENOL
2,4-XYLENOL
2f4-XYLENOL
2-CHLOROPHENOL
2-CHLOROPHENOL
2,4-DICHLOROPHENOL
TYPE
T
T
T
D <
D
T
T
S
S >
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
CONC
E-6 G/SCM
2.20E 03
4.70E 02
2.20E 03
1.10E OK
8.60E 01
1.30E 02
4.40t 01
1.60E 01
1.20E 02>
1.30E 02
4.40E 01
1.30E 02
4.40E 01
1.30E 02
4.40E 01
1.30E 02
4.40E 01
1.30E 02
4.40E 01
1.30E 02
4.40E 01
1.3UE 02
4.70E 02
1.30E 02
4.70E 02
1.30E 02
4.70E 02
4.70E 02
2.20E 03
4.70E 02
2.20E 03
4.70E 02
2.20E 03
4.70E 02
US
O.OOE-OI
O.UOE-OI
O.UOE-01
0.00fc-01<
O.OOE-OI
O.OOE-OI
o.oot-oi
O.OOE-OI
O.OOE-01>
O.OOE-OI
o.uot-oi
O.OOE-OI
O.OOE-01
O.OOE-OI
O.UOE-OI
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
o.oot-oi
O.OOE-01
O.UOE-01
O.OOt-01
O.OOE-01
O.UOE-01
WDS
G/S
O.OOt-01
O.OOE-01
O.OOt-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOt-01
o.oot-oi
O.OOt-01
O.OOE-01
O.OOE-01
O.OOt-01
O.UOE-01
O.UOE-01
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.OOE-01
o.oot-oi
O.OOE-01
o.oot-oi
O.OOt-01
o.oot-oi
O.UOE-01
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
LCCAT
6
5
b
2
3
2
3
2
3
2
3
2
3
2
3
2
3
4
S
4
5
4
5
5
6
5
6
5
6
S
M
I-1
O
-------
o
NJ
TEST BUHNER FLUE GAS COMPOSITE* ECOLOGY IMPACT
OMEG NO.
COMPOUND NAME
TYPE CONC US
E-6 G/SCM
LCCAT
G/S
19
19
19
19
19
20
20
20
20
20
20
20
20
21
21
21
21
21
21
21
21
21
21
21
21
21
21
21
21
21
21
21
22
22
A
A
A
B
B
A
A
A
A
A
A
B
B
A
A
A
A
A
A
A
A
A
A
B
B
B
B
B
C
C
D
0
A
A
040*
060*
060*
022*
022*
020*
020*
060*
060*
101*
101*
020*
020*
020*
020*
100*
100*
120*
120*
140*
140*
180*
180*
040*
120*
120*
180*
180*
080*
100*
080*
oeo*
020*
020*
p
p
p
p
p
p
p
p
p
p
p
p
p
p
p
PH
PH
PH
PH
P
P
P
P
P
P
P
P
P
P
P
PH
PH
PH
PH
2 f 4-DICHLOROPHENOL
PENTACHLOROPHENOL
PENTACHLOROPHENOL
CHLORINATEU-M-CRESOLS
CHLORINATEO-M-CRESOLS
2-NITROPHENOL
2-NITROPHENOL
4-NITROPHENOL
4-MTROPHENOL
2r 4-DlNITROPHtNOL
2»4-DlNITROPHENOL
4,6-OlNlTRO-O-CRESOL
4,6-DlNITRO-O-CRESOL
NAPHTHALENE
NAPHTHALENE
ACENAPHTHENE
ACENAPHTHENE
ACENAPHTHYLENE
ACENAPHTHYLENE
ANTHRACENE
ANTHRACENE
PHENANTHRENE
PHENANTHRENE
BENZCAJANTHRACENE
CHRYSENE
CHRYSENE
PYRENE
PYRENE
01 BENZ( A, H) ANTHRACENE
BENZO(A)PYRENE
BENZO(GHI)P£RYLENE
BENZO(GHI)PERYLENE
FLUOPENE
FLUORENE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
2
4
2
4
2
4
2
4
2
4
2
4
2
1
4
1
4
1
4
1
4
1
4
4
1
4
1
4
4
4
1
4
.20E
.70E
.20E
,70E
.20E
.7Ut
.20E
,70t
.20E
,70E
.20E
,70E
.20E
.JOE
.40E
.JOE
.40E
.JOE
.40E
.JOE
.40E
.JOE
.40E
.UOE
.JOE
.40E
.JOE
.4UE
.40E
.40E
.JOE
.40E
I.JOE
4.40E
OJ
02
OJ
02
OJ
02
OJ
02
OJ
02
OJ
02
OJ
02
01
02
01
02
01
02
01
02
01
01
02
01
02
01
01
01
02
01
02
01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
o.oot-oi
o.oot-ui
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
o.oot-oi
o.oot-oi
O.OOE-01
o.oot-oi
O.OOE-O i
O.OOE-01
o.oot-oi
O.OOE-01
O.OOt-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
o.ooE-oi
O.OOt-01
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
O.OOt-01
6
5
6
b
6
5
b
5
6
5
to
b
b
i.
3
2
3
I
3
2
3
2
3
3
2
3
«?
3
3
3
2
3
2
3
-------
DMEG NU.
TEST BURNER FLUE GAS COMPOSITE, ECOLOGY IMPACT
COMPOUND NAME
TYPE CONC l>9
E-6 t/SCM
WD8
u/s
LCCAT
22 B 040* FLUORANTHENE
22 B 040* FLUORANTHENE
22 C 020* BENZO(K)FLUORANTHENE
22 C 020* BENZO(K)FLUORANTHENE
22 C 060* BENZO(B)FLUORANTHEN£
22 C 060* BENZO(B)FLUORANTHENE
22 0 020* INDENOU,2r3-CD)PYRENE
22 0 020* INDENO(1,2,3-CD)PYREN£
T
T
T
T
T
T
T
T
1.30E
4.40E
1.30E
4.40E
1.30E
4.40E
1.30E
4.40E
02
01
02
01
02
01
02
01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-Ol
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
2
3
2
3
2
3
2
3
M
I
O
U!
-------
GASIFIER ASH SLUICE HATER
APPROXIMATE FLO* RATfc = 7.0 G/S (0.007 L/S)
TOTAL ORGANIC LOADING 125.7 MG/L
ORGANIC LOADING
125700.0
FLOW HATE = 7.00
STATE: LIQUID, UNITS IN HICROGRAMS/L
IMPACT: HEALTH
EXPEHIMENTALY DETERMINED DATA
SPARK SOURCE DATA
-------
DMEG NO.
GASIFIER ASH SLUlCt MATER, HEALTH IMPACT
COMPOUND NAME
TYPE CONC US
E-6 G/L
ND8
li/S
LCCAT
16 A ?20 W
21 C 100* P N
21 C 080* P
16 C 020 M
18 A 142* P
18 A 145
18 C 040 M
18 A 160 M
18 A 144
18 A 162
18 A 163
18 A 180 W
18 A 181
18 A 182
18 A 18}
18 B 020 W
18 B 040 W
18 B 060 W
18 B 080 W
20 B 020* P W
18 A 083
18 C 080 W
18 C 081
18 C 082
18 C 083
19 A 020* P W
18 A 161
18 A 081
19 A 040* P M
20 A 080 W
18 A 100 W
19 A 060* P H
18 A 102
18 A 103
POLYCHLORINATED BIPHENYLS
BENZO(A)PYRENE
01BENZ(A,H)ANTHRACENE
1-NAPHTHOL
2r4-XYLENOL
3,5-XYLENOL
2-NAPHTHOL
ETHYL CRE30LS
2,6-XYLENOL
4-ETHYL-O-CRESOL
2-ETHYL-P-CRESOL
POLYALKYLPHENOLS (MM>135)
2,4,6-TRIMETHYL METHYL PHENOL
4,6-DI-TERT-BUTYL-M-CRESOL
2,6-DIMETHYL-4-HEPTYL PHENOL
CATECHOL
1,3-OIHYDROXYBENZENk
lr4-DIHYDROXYBENZENE
1,2,3-TRIHYDROXYBENZENE
4,6-DINITRO-O-CRESOL
P-ETHYLPHENOL
INUANOLS
1-INOANOL
4-INDANOL
5-INOANOL
2-CHLOROPHENOL
6-ETHYL-M-CRE80L
0-ETHYLPHENOL
2,4-DICHLOROPHENOL
2-AMINO-4,6«DINlTROPHENOL
PHENYLPHENOLS
PENTACHLOROPHENOL
P-PHENYLPHENOL
M-PHENYLPHENOL
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1.30E 05
1.30E OS
1.3UE 05
1.3UE OS
1.30E OS
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E OS
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E OS
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E OS
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
2.51E 07
4.20t 05
9.00E 04
2. ME 04
2.S1E 04
2.S1E 04
2.S1E 04
2.S1E 04
2.51E 04
2.51E 04
2. ME 04
2.S1E 04
2.blE 04
2.S1E 04
2.51E 04
2.S1E 04
2.51E 04
2.51E 04
2.S1E 04
2. ME 04
2. ME 04
2.51E 04
2.S1E 04
2.S1E 04
2.S1E 04
2.S1E 04
2.S1E 04
2.51E 04
2.S1E 04
2.S1E 04
2.51E 04
2. ME 04
2. ME 04
2. ME 04
1.80k 08
2.93E 06
6.30k 05
l.&OE OS
l.ttOt 05
1.60E 05
1.80E 05
1.80L 05
l.BOt OS
1.80E 05
l.ttOt 05
l.tiOE 05
1.80E 05
l.ttOt 05
1.80E 05
l.ttOt 05
1.60E 05
l.bot os
i.aoE 05
1.60k 05
1.80k 05
i.eofc 05
i.eok 05
1.80k 05
i.aok os
l.bot os
l.BOE 05
l.ttOE 05
l.ttOE 05
1.60k 05
l.tiOE 05
l.ttOE 05
1.60k 05
1.80k 05
o
t_n
-------
I
H1
O
GASIFIER ASH SLUICE WATER, HEALTH IMPACT
DrtEG
19
19
19
18
18
IB
20
18
20
20
20
20
18
18
20
20
18
18
20
20
18
18
20
18
18
20
19
18
02
21
014
21
21
12
6
b
B
A
A
A
A
A
8
A
A
A
A
A
A
A
A
A
A
A
A
A
B
A
A
B
9
A
A
B
B
0
B
A
NO.
020
021
022* P
082
146
143
020* P
042
040
040
060* P
120
141
043
100
101* P
041
101
102
103
080
140
041
040
120
042
023
060
360
080
020* P
040
040* P
020* P
w
w
w
w
w
w
w
w
w
w
w
rt
M
W
W
M
COMPOUND NAME
CHLORINATED CRESOLS
CHLOKINATED-0-CRESOLS
CHLORINATED-M-CRESOLS
M-ETHYLPHENOL
3, 4-XYLENOL
2»5-XYLENUL
2-NITROPHENOL
0-CRESOL
DINITRO-P-CKESOLS
3-NITROPHENOL
4-NITROPHENOL
2r4,6-TRINlTNOPHENOL
2r3-XYLENOL
P-CRESOL
OINITROPHENOLS
2r 4-DINITROPHENOL
M-CRESOL
0-PHENYLPHENOL
2,5-DINITHOPHENOL
2,6-DINITKOPHENOL
ETHYLPHENOLS
XYLtNOLS
3f5-DINITHO-P-CRESOL
CRESOLS
2r2'-DIMYUROXYDlPHENYL
2,6-DINITHU-P-CRESOL
CHLORINATED-P-CRESOLS
2-METHOXYPHENOL
HEXACHLOROCYCLOHEXANE
3-METHYLCHOLANTHKENt
1,1'-DICHLOROMETHYL ETHER
DJb£NZO(A,I)PYRENE
BENZOUANTHHACENE
N-NITROSOUIMETHN.AMINE
TYPE CONC
E-6 G/L
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
U30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30k
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30k
1.30k
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
OS
2. ME
2.51E
2.51E
2.51E
2.5tt
2.51E
2.51E
2.51k
2.51E
2.51E
2. ME
2.51E
2.51k
2.51k
2.51k
2.51k
2.51k
2.51k
2.51E
2.51k
2.51E
2.51k
2.51E
2.51k
2.51E
2.51E
2.51E
2.51k
6.30k
2.24k
1.70k
1.93k
1.90E
1.30k
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
U4
03
03
03
02
02
02
HDS
b/S
l.bOk
1.80k
l.bOk
1.80k
1.80k
i.eot
1.80k
1.80k
1.80k
l.bOk
i.eok
l.ttOk
l.ttOk
i.bot
i.bok
l.bOk
i.bot
l.bOt
l.ttOt
l.bOk
i.bot
i.bot
l.bOt
l.bOt
l.bOk
i.bot
i.bot
l.bOk
4.40t
1.60k
1.20k
1.40t
1.31k
8.tiOk
LCCAT
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
U5
05
U5
05
05
05
05
04
04
04
03
03
U2
-------
GA81FIER AftH SLUICE NAUR, HEALTH IMPACT
DMEG NO.
23 C 160 W
10 C 100
02 B 140* P M
10 C 041
10 C 040
10 C 042
10 C 043
18 A 020 P H
12 A 040* P
10 C 220
23 B 100 M
21 B 106
21 B 103
21 B 10B
21 B 107
21 B 104
21 B 10S
21 B 100
21 B 10A
21 B 102
21 8 101
23 B 240
21 B 109
21 B 108
23 B 220
08 B 060 M
10 C 083
10 C 080
10 C 061
10 C 082
13 A 100 M
10 C 200
14 B 020 M
13 A 140
i
o
COMPOUND NAME
DIBENZOCCtGKARBAZOLE
1,4-DIAMINOBENZENE
HEXACHLOROCYCLOPENTADIENE
2-AMINOTOLUENE
AMINOTOLUENES
3-AMINOTOLUENE
4-AMINOTOLUENE
PHENOL
N-NITROSODIETHYLAMINE
2-AMINONAPHTHALENE
DIHYDROACRIDINE
7-METHYL BENZOCOPHENANTHRENE
2-METHYL BENZOCOPHENANTHRENE
ISOPROPYL BENZOCOPHENANTHRENE
B-METHYL BENZOCOPHENANTHRENE
5-METHYL BENZOCOPHENANTHRENE
6-METHYL BENZOCOPHENANTHRENE
BENZOCOPHENANTHRENE t ALKYL DERIVATIVES
N-PROPYL BENZOCOPHENANTHRENE
1-METHYL BENZOCOPHENANTHRENE
BENZOCOPHENANTHRENE
DIBENZCA,H)ACRIDINE
6-ETHYL BENZOCOPHENANTHRENE
2-ETHYL BENZOCOPHENANTHRENE
DIBENZCA,J)ACRIDIN£
B-PROPIOLACTONE
P-ANISIDINE
ANISIDINES
0-ANISIDINE
M-ANISIDINE
BENZENETHIOL
1-AMINONAPHTHALENE
DIMETHYL SULFOXIDE
PERCHLOROMETHANETHIOL
TYPE
T
T
T
T
T
T
T
0
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
CONC
E-6 G/L
1.30E 05
I.JOE 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
3.6UE 02
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E OS
1.30E 05
1.30E 05
1.30E 05
1.30E OS
1.30E 05
1.3UE 05
1.30E 05
1.30E OS
1.30E 05
1.30E OS
1.30E OS
1.30E OS
1.30E 05
1.30E OS
1.30E OS
DS
8.40E 01
8.40E 01
7.90E 01
7.40E 01
7.40E 01
7.40E 01
7.40E 01
7.20E 01
7.00E 01
5.02E 01
5.02E 01
3.70E 01
3.70E 01
3.70E 01
3.70E 01
3.70E 01
3.70E 01
3.70E 01
3.70E 01
3.70E 01
3.70E 01
3.70E 01
3. TOE 01
3.70E 01
3.40E 01
2.61E 01
1.70E 01
1.70E 01
1.70E 01
1.70E 01
1.70E 01
1.50E 01
1.04L 01
1.04E 01
ND8 LCCAT
G/8
5.90E 02
S.90E 02
S.SOE 02
5.20E 02
5.20E 02
5.206. 02
S.20E 02
5.04E 02
4.90E 02
3.S1E 02
3.S1E 02
2.60E 02
2.60E 02
2.60fc 02
2.60E 02
2.60E 02
2.60E 02
2.60E 02
2.60fc 02
2.60E 02
2.60E 02
2.60E 02
2.606. 02
2.60E 02
2.40E 02
.83t 02
,20fc 02
.20E 02
,20fc 02
.iOt 02
.20E 02
.03E 02
7.33E 01
7.l3fc 01
-------
O
CO
DMEG NO.
GASIFIER ASH SLUICE MATER, HEALTH IMPACT
COMPOUND NAME
TYPE CONC US
E-6 G/L
LCCAT
G/3
22
08
15
10
17
17
21
08
08
08
08
12
17
10
02
17
17
17
17
17
17
17
21
22
22
21
21
21
04
04
15
04
21
12
C
C
A
C
B
B
U
A
A
A
A
B
A
C
A
A
A
A
A
A
A
A
A
D
C
B
B
B
A
A
6
A
B
A
080* P
060
160
140* P
040
060
060
122
121
120
123
020
060
120
180
086
085
080
081* P
083
084* P
082
180* P
020* P
020* P
142
140
141
050
040
060
060
120* P
060* P
H
M
W
W
M
M
M
W
H
W
M
W
W
W
BENZO(B)FLUORANTHENfc
6-HEXANELACTAM
BIPHENYL
BENZIDINE
l-CHLORO-2-NITROBENZENE
l-CHLORO-4-NITROBENZENE
DIBENZOCA,L)PYRENE
PALMITIC ACID
MYRISTIC ACID
SATURATED LONG CHAIN ACIDS (MM;228-285)
STEARIC ACID
N-METHYL-N-NITROSOANILINE
4-NITR08IPHENYL
4-AMINOBIPHENYL
DIBROMQDICHLOROMETHANE
3f5-DINITROTOLUENE
2,5-DINITROTOLUENE
DINITROTOLUENES
2f6-DINlTROTOLUENE
2f3-DINITROTOLUENE
2»4-DINITROTOLUENE
3»4-DINITROTOLUENt
PHENANTHRENE
INDENL(l,2,3-CD)PY«tNE
BENZO(K)FLUORANTH£NE
5-METHYL CHKYSENE
METHYL CHRYSENES
4-METHYL CHRYSENE
EPICHLORHYDRIN
2-CHLORO-l,2-EPOXYPROPANE
4/4'-OIPHENYLBIPHENYL
l-CHLORO-lf3-EPOXYPKQPANE
CHRySENE
N«AJ f T 0/1 fi/1 A YDDflOVI AaT ittf
™» 1 W vwU"* rnUr F w^PI* Hit
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1
1
1
1
]
j
1
1
1
1
1
;
1
1
1
l
l
l
1
1
1
1
1.30E 05
1.30E 05
1.30E 05
..JOE 05
1.30E 05
1.30E 05
..JOE 05
.JOE 05
1.30E 05
1.30E 05
1.30E 05
.JOE 05
.JOE 05
.JOE 05
.30E 05
.JOE 05
.JOE 05
.JOE 05
.JOE 05
.JOE 05
.JOE 05
.JOE 05
,30E 05
.JOE 05
.JOE 05
,30E 05
.JOE 05
•30E 05
.JOE 05
.JOE 05
.30E 05
.30E 05
.30E 05
•30E 05
9.70E
8.40E
8.40E
8.40E
8.40E
8.40E
7.90E
7.90E
7.90E
7.906.
7.90E
6.61E
6.30E
6.40E
b.OOt
5.50E
5.50E
5.50E
5.50E
5.50E
5.50E
S.bOE
5.23E
5.23E
5.23E
4.70E
4.70E
4.70E
4.20E
4.20E
4.20E
4.20E
3.80E
3.50E
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
6.bOfc
5.90t
b.90t
5.90t
5.90t
5.90E
S.bOt
5.50E
5.50t
5.50t
5.50t
4.63E
4.40E
4.40E
4.20t
3.82t
3.62E
3.82t
3.82E
3,tt2t
3.b2b
3.82£
3.70t
3.70E
3.70t
3.30E
3.30t
3.30t
2.93t
2.93E
2.93E
2.93E
2.70E
2.44E
01
01
01
01
ui
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
-------
GASIFIER ASH SLUICE WATER, HEALTH IMPACT
DMEG NO.
21 c i6o
23 C 020
09 A 120 W
21 C 120
08 A 140
03 B 020 H
03 6 040 W
21 0 020
47 A 060 P
28 A 010
02 B 120* P
23 D 020 W
23 D 040
02 A 160* P
08 D 263
17 A 020* P
08 D 262
16 B 020 W
08 0 281
08 D 300* P
08 D 260* P W
08 A 102
06 A 100
06 A 104
06 A 101
08 A 103
23 A 100 W
23 A 102
23 A 101
23 A 103
23 C 160
10 A 060
22 C 040
16 B 041
COMPOUND NAME
PICENE
PYKROLE
TETRAMETHYLSUCCINONITRILE
BENZO(E)PYRENE
OLtIC ACID
1,4-OIOXANE
1,3-DIOXANE
DIBENZO(A,H)PYRENE
AMMONIA
SODIUM
HEXACMLOROBUTADIENE
BENZOTHIAZOLE
METHYL BENZOTHIAZOLE
BROMOFORM
DI-N-BUTYL PHTHALATfc
NITROBENZENE
DIETHYL PHTHALATE
A-CHLOROTOLUENE
DIMETHYL PHTHALATE
DI-2-ETHYLHEXYL PHTHALATE
PHTHALATE ESTERS
-------
GASIFIER ASH SLUICE WATER, HEALTH IMPACT
DME
16
16
16
27
34
15
15
15
15
21
06
02
72
ou
23
23
02
02
02
04
07
23
16
16
16
08
23
21
23
23
23
23
23
23
:G
B
B
B
A
A
B
B
B
B
C
A
A
A
B
B
C
B
B
d
A
B
C
A
A
A
0
A
C
3
B
B
A
A
A
NO.
042
040
043
010
010
163
161
160
162
060
020 H
320* P
OiO
100
200
040
103
100* P
104
140* P
100 W
140
162
160* P
161
060
020
040
021
022
020
143
1*2
146
COMPOUND NAME
1,3-6IS(CHLOROMETHYL) BENZENE
BIS(CHLOROMETHYL)B£NZENES
1,4-BIS(CHLOROMETHYL)BENZENE
LITHIUM
CALCIUM (AS CA+2)
P-TERPHENYL
0-TtRPHENYL
TEKPHENYLS
M-TERPHENYL
DIBENZ(A,C)ANTHRACEN£
ETHYLENE ULYCOL
HEXACHLOROETHANE
IRON (AS FE+2)
2,2'-DICHLOROOII3UPROPYL ETHEH
BENZCUACRIOINE
INDOLE
CIS-1,3-DICHLOROPROPENE
DICHLOROPROPENES
TRANS-1 ,3-DICHLOKOPROPENE
2-CHLOROETHYL VINYL ETHER
CAMPHOR
DIBENZO(A,I)CARBAZOLE
HEXACHLOROBENZENE
POLYCHLORINATEO BENZENES
1 , 2, 4-TRICHLOROBtNZEN£
METHYL METHACRYLATE
PYRIOINE
BENZO(G)CH«YSENE
QUINOLINE
ISOQUINOLINE
QUINOLINE9
2,5-DIMETHYLPVRIDINfc
2,4-DIMETHYLPYRIOlME
2,3/4,6-T£TWAM£TMl-L PYRIOINE
TYPE CONC
E-6 G/L
T
T
T
S
D
T
T
T
T
T
T
T
0
T
r
T
T
T
T
T
T
T
T
T
T
T
T
T
T.
T
T
T
T
T
1
1
1
4
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.30E
.30E
.30E
• OOE
.20E
.30E
.30E
.30E
• 30E
.30E
.30E
.30E
.20E
.30E
.30E
.30E
.30E
.30E
.30E
.30E
.30E
.30E
,30t
.30E
.30E
.30E
.30E
.30E
.30E
.30E
.30E
.30E
1.30E
1.30E
05
05
05
02
05
05
05
05
05
05
05
05
03
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
1
1
1
1
9
9
9
9
9
8
8
8
8
7
7
7
7
7
7
7
7
7
7
7
7
6
b
5
5
5
5
4
4
US
.30E 00
.30E 00
.30E 00
.2.1E 00
.20E-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.aot-oi
.UOE-01
.40E-01
.OOE-01
.90E-01
.90E-01
.40E-01
.40E-01
.40E-01
.40E-01
,40fc-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
•OOt-01
.50E-01
,2iE-01
•23E-01
.23E-01
.23E-01
•70E-01
.70E-01
4.70E-01
NOS
G/S
b.bot
B.bOt
b.bOE
8.bOE
6.41t
6.30k
6.30E
6.30E
6.30t
5.90t
5.90E
5.90t
5.60t
5.50E
b.50fc
5.20t
5.20t
5.20E
5.20E
5.20t
4.90t
4.90L
4.90t
4.90E
4.90E
4.20E
3.62E
3.70fc
3.70E
3.70t
3.70t
3.30E
3.30t
3.30b
LCCAT
00
00
00
00
00
00
00
00
00
00
00
DO
00
00
00
00
00
00
00
00
00
00
00
00
00
uo
00
00
00
00
00
00
00
00
-------
GA8IFUR ASH SLUICE WATER, HEALTH IMPACT
OMEG NO.
23 A 145
05 B 100
23 A 141
23 A 140
23 A 144
23 C 120
10 C 020
54 A 010
09 A 100
09 A 080
25 A 040
25 A 041
23 C 101
23 C 100
23 C 102
06 A 080
25 A 042
23 B 260
23 C 080
25 B 040
10 C 064
10 C 065
10 C 063
10 A 000
10 C 061
08 A 040
10 D 020
10 C 060
07 B 060*
10 C 066
10 C 062
25 A 061
25 A 064
25 A 063
COMPOUND NAME
3»4«DIMETMYLPYRIOINE
N 1-PHENYLETHANOL
2»3-DIMETHYLPYRIDINfc
DISUBSTITUTED POLYSUB8TITUTED ALKYL PYRIDINES
2r6-DIMETHYLPYRIDlNE
BENZO(A)CARBAZOLE
ANILINE
P SELENIUM
1,3-DICYANO-l-HYDROXYBUTANE
BUTVRONITRILE
METHYLTHIOPHENES
2-METHYLTHIOPHENE
3-METHYLCARBAZOLE
METHYLCARBAZOLE3
9-METHYLCARBAZOLE
VALERIC ACID
3-METHYLTHIOPHENE
DIBENZ(C,H)ACRIDINE
CARBAZOLE
M BENZO(B)THIOPHENE
2,6-XYLIDINE
3,4-XYLIDINE
2»5-XYLIDINE
1,2-DIAMINOETHANE
2,3-XYLIDINE
ACETIC AGIO
W N,N-DIMETHYLANILINE
DIMETHYLANILINES
P ISOPHORONE
3,5-XYLIDlNE
2r4-XYLlDINE
2,3-DIMETHYLTHIOPHENE
3,4-DIMETHVLTHIOPHCNE
2,5-DIMETHYLTHIOPHENE
TYPE
T
T
T
T
T
T
T
0
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
CONC
E-6 G/L
.30E 05
.30E OS
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.OOE 01
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
•30E 05
•30E OS
US
4.70E-01
4.70E-01
4.70E-01
4.70E-01
4.70E-01
4.50E-01
4.33E-01
4.GOE-01
3.60E-01
3.80E-01
3.70E-01
3.70E-01
3.70E-01
3.70E-U1
J.70E-01
3.70E-01
3.70E-01
3.60E-01
3.60E-01
3.60E-01
3.30E-01
3.30E-01
3.30E-01
3.30E-01
3.30E-01
3.30E-01
3.30E-01
3.30E-01
3.30E-01
3.30E-01
3.30E-01
3.22E-01
3.22E-01
3.22E-01
MD8 LCCAT
G/8
3.30k 00
3.30E 00
3.30t 00
3.30E 00
3.30E 00
3.14E 00
3.03E 00
2.80E 00
2.70t 00
2.70E 00
2.60E 00
2.60E 00
2.60E 00
2.60E 00
2.60E 00
2.60t 00
2.60E 00
2.51E 00
2.5U 00
2.51E 00
2.31E 00
2.31E 00
2.3U 00
2.31E 00
2.3U 00
2.3U 00
2.3U 00
2.3U 00
2.31E 00
2.31E 00
2.31E 00
2.30t 00
2.30E 00
2.30& 00
-------
I
M
H-1
NJ
GASIFIEH ASH SLUICE HATER, HEALTH IMPACT
DMEG HO.
COMPOUND NAME
TYPE CONC OS
E-6 6/L
LCCAT
Wb
25
25
04
04
25
25
01
17
08
04
17
17
17
04
08
09
09
09
09
23
23
23
10
10
08
10
10
26
12
08
14
10
97
M
A
A
A
A
A
A
B
A
C
B
A
A
A
B
A
B
B
B
B
A
A
A
A
A
B
A
A
A
A
B
A
A
B
C
060
062
180* P
200
081
080
220 W
041
020
080
043
042
040
040* P
060
041
020 M
042
040 W
043
042
041
123
122
080
120
121
020 M
080
041
020 M
160
120
0*1
DIMETHYLTHIOPHENES
2»4-DIMETHYLTHIOPHENE
CHLOKOPHENYL PHENYL ETHER
tt-BROMOPHENYL PHENYL ETHEH
2r3,5-TKIMETHYLTHIOPHENE
TRIMETHYL AND TETRAM£THYL THIOPHENES
DlCYCLOPENTADIENb
2-NITROTOLUENE
FORMAMIDE
2>2'-DICHLORODIETHYL ETHEH
4-NITROTOLUENE
3-NITROTOLUENE
NITROTOLUENES
1, I'-DICHLOROOIETHYL ETHER
MALEIC ACID
A-NAPHTHONITRILES
BENZONITRILE
B-NAPHTHONITRILES
NAPHTHONITRILES
4-METHYLPYRIDINE
3-METHYLPYRIDINE
2-METHYLPYRIDINE
l-AMINO-2-PROPANUL
3-AMINO-1-PROPANOL
Y-BUTYROLACTONE
PROPANOLAMINES
2-AMINO-1-PROPANOL
TRIETHYL PHOSPHATE
N-MTROSOUIISOPROPYLAMINE
2-HYDROXYBEMZOIC ACID
BENZENESULFONIC ACIU
CYCLOHEXYLAMJNE
4CETOPHENONE
i'MtJHYLIHVQLE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
I.
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.30E
.30E
.30E
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
.JOE
,JOE
JOE
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
°5
3.22E-01
3.22E-01
3.10E-01
3.10E-01
2.40E-01
2.90E-01
2.bOE-01
2.60E-01
2.80E-01
2.60E-01
2.80E-01
2.bOE-01
2.60E-01
2.80E-01
2.61E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.40E-01
2.40E-01
2.40E-01
2.32E-01
2.32E-01
2.32b-01
2.32E-01
2.32E-01
2.32E-01
2.20E-01
2.10E-01
2.10E-01
2.10E-01
2.10E-01
1.04E-01
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1,
1,
.JOE
,30£
.14E
.I4b
.OOb
.OOb
.OOb
.OOb
.OOb
.OOb
.OOb
.OOb
.OOb
.OOb
.83b
.BOE
.SOL
.bOb
.bOb
,70b
,70b
,70b
.62b
.62b
,62b
.62b
.62b
.62b
.54E
,50b
.50E
,50t
,44t
30E
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
-------
GASIFIER ASH SLUICE MATER, HEALTH IMPACT
OMEG NO.
COMPOUND NAME
TYPE CONC DS
£•6 G/L
LCCAT
S/8
05 C 040 W
22 A 010 W
02 A 140* P
23 C 062
23 C 060
21 A 020* P
23 b 062
23 d 061
23 B 067
23 b 065
23 b 063
23 b 064
23 B 006
05 A 140 W
23 B 040
23 b 060
21 A 140* P
02 A 361
02 A 360
07 A 140
83 A 010 P
08 D 160
38 A 010
23 A 083
23 A 122
23 A 082
23 A 064
23 A 120
23 A 061
23 A 121
23 A 063
23 A 060
10 B 100
16 A 201
T-PENTANOL
INOENE
DIbHOMOCHLOROMETHANE
3-METHYLINDOLE
METHYLINDOLES
NAPHTHALENE
2,6-DIMETHYLGUINULINE
2f3-DlMETHYLQUINOLIN£
1,5-DIMETHYLISOQUINOLINE
6r8-UIMETHYLUUINOLINE
2»8-L>IMETHYLG)UINOLINE
3f4-DlMETHYLQUINULIN£
1,3-OIMETHYLISOQUINULINE
BENZYL ALCOHOL
2-METHYLQUINOLINE
DlMETHYLOUINOLINtS
ANTHRACENE
1-BROMUBUTANE
BROMOBUTANES
BENZALDEHYDE
MERCURY
METHYL bENZUATE
ALUMINUM
4-PHENYLPYRIDINE
2r4,6-COLLlDINE
3-PHENYLPYRIDINE
4-N-PROPYLPYRIDINE
COLLIDINES
2-ETHYLPYRIDINE
5-ETHYL-2-METHYLPYRIDINE
4-ETHYLPYHIDINE
MONOSUBSTITUTED ALKYL PYRIDINES
MORPHOLINE
1-CHLORONAPHTHALENE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
D
T
T
T
T
T
T
T
T
T
T
T
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30t 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.40E 00
1.30E 05
1.10E 04
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.B4E-01
I.tt4t-01
1.64E-01
1 .B4E-01
1 .B4fc-01
1.70E-01
1.51E-01
1.51E-01
1.51E-01
1.51E-01
1.51E-01
1.51E-01
1.51E-01
1.51E-01
1.51E-01
l.blE-01
1.50E-01
1.50E-01
1.50L-01
1.42E-01
1.40E-01
1.40E-01
1.40E-01
1.30E-01
1.30E-01
1.30E-01
1.30E-01
1.30E-01
1.30E-01
1.30E-01
1.30E-01
1.30E-01
1.30E-01
1.30E-01
1.30E 00
1.30E 00
1.30t 00
l.iOt 00
1.30t 00
1.20t 00
l.lOt 00
l.lOt 00
1.10E 00
l.lOt 00
l.lOt 00
l.lOb 00
l.lOt 00
1.10k 00
i.iut oo
l.lOt 00
1.04t 00
1.036. 00
1.03k 00
l.OOb 00
9.60E-01
V.70E-01
9.62E-01
8.60t-01
8.60t-01
8.bOt-01
6.60E-01
b.bot-oi
b.bOt»01
e.bot-oi
8.60E-01
B.80E-01
8.bOE-01
8.00E-01
-------
GASIFIER ASH SLUICE WATER* HEALTH IMPACT
OH
23
23
16
16
23
33
08
07
07
07
05
12
37
13
13
05
23
23
23
23
22
35
76
15
15
15
15
15
15
15
15
15
15
15
EG
A
A
A
A
A
A
D
B
6
B
A
A
A
B
B
B
B
B
B
B
B
A
A
A
A
A
A
B
B
B
B
B
6
S
NO.
081
062
202
200* P
080
010
200
182
161
180
160
100
010
060
080
120
080
160
140
120
040* P N
010
010 P
141
143
142
140
203
202
200
180
183
182
201
COMPOUND NAME
2-PHENYLPYRIOINE
3-ETHYLPYRIDINE
2-CHLORONAPHTHALENE
CHLORONAPHTHALENES
PHENYLPYRIDINES
MAGNESIUM
OIETHYL AOIPATE
OIHYDRO-(0 OK DCAHVONE
CARVONECD OR L)
CARVONES
PHENETHYL ALCOHOL
N-NITROSODIPENTYLAMlNE
BORON
OIPHENYL SULFIDE
METHYL DISULFIDE
BURNEOL
ACRIDINE
BENZO(H)QUINOLINE
BENZO(F)OUINOLINE
PHENANTHRIDINE
FLUORANTHENE
STRONTIUM
NICKEL
N-6UTYL BENZENE
TERT-BUTYL BENZENE
SEC-BUTYL BENZENE
BUTYL BENZENES
1,2, 4,5-TETHAMETHYLBENZENE
1,2,3,5-TETRAMETHYLBENZENE
TETRAMETHYLBENZENES
TRIMETHYLBENZENES
1 , 3, 5-TRIMETHYLBENZfcNE
1,2, 4-TRIMETHYL8£NZ£N£
l,2,3,4»rEr«AMETHrtbEN2fcNfr
TYPE CONC
E-6 G/L
T
T
T
T
T
D
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
D
S
T
T
T
T
T
T
T
T
T
T
T
1
1
1
1
1
1
1
1
1
1
1
1
4
1
1
1
1
1
1
1
1
a
2
1
1
1
1
1
1
1
1
1
.30E
.30E
.30E
.30E
.30E
.10E
.30E
.30E
.30E
.30E
.30E
.30E
.60E
.30E
.30E
.30E
.30E
.SUE
.30E
.30E
.30E
.OOE
.OOE
.30E
,30E
.30E
.30E
.30E
.30E
.30E
.30E
• 30E
1.30E
1.30E
05
05
05
05
05
04
05
05
05
05
05
05
03
05
05
05
05
05
05
05
05
03
01
05
05
05
05
05
05
05
05
05
05
05
1
1
\
I
1
I
1
9
9
9
9
9
9
9
9
9
8
8
8
8
b
8
7
7
7
7
7
US
.iOE-01
.30E-01
.JOE-01
.iOE-01
.iOE-01
.22E-01
.14E-01
. 14E.-01
.14E-01
.14E-01
.04E-01
.04E.-01
.80E.-02
.OOE-02
.OOE-02
.OOE-02
.OOt-02
.OOE-02
.OOE-02
. OOE-02
.OOE-02
•70E-02
.70E-02
.40E-02
,40t-02
,40t-02
.40E-02
.OOE-02
.OOE-V2
.OOt-02
.OOE-02
.OOE-02
7.00E-02
7.UOE-02
8
8
8
8
8
8
8
b
8
8
7
7
6
6
6
6
6
6
6
6
6
6
6
5
5
5
5
a
a
a
4
4
4
"OS LCCAT
G/b
.80E-01
,80t-01
.80E-01
.80E-01
.bOt-01
.60E-01
.OOt-01
.OOt-01
.OOt-01
.OOt-01
,33t-01
,33t-01
,90t-01
.30E-01
,30t-01
,30t-01
,30t-01
.30E-01
.iOt-01
.30E-01
,30t-0l
•10E-U1
.IOE-01
,90t-01
.90E-01
.90E-01
.90E-01
.9QE-01
.vot-oi
.90t-01
,90t-01
.VOt-01
.90E-01
4.VOE-01
-------
GASIFIER ASH SLUICE WATER, HEALTH IMPACT
DMEG NO.
15 B 181
15 B 141
15 B 142
15 B 140
03 B 060
15 B 120
26 B 040 W
57 A 010
08 D 320* P
08 A 160
14 A 043
14 A 044
14 A 041
05 A 100
06 B 020 W
05 A 080
08 A 180
03 A 040 M
05 B 080
OS C 060
47 A 080 P
82 A 010 P
17 8 023
17 B 022
17 B 020
17 B 021
21 A 080
21 A 044
21 A 042
15 B 020
21 A 043
21 A 041
21 A 083
21 A 082
COMPOUND NAME
1,2,3-TRIMETHYLBENZENE
1,2-DlHYDRONAPHTHALtNE
lr4-DIHYDRONAPHTHALENE
OIHYDRONAPHTHALENES
2-ETHYL-4-METHYL-lr 3-DIOXOLANE
TETRAHYDRONAPHTHALENE
THITOTYL PHOSPHATES
CHLORINE (AS CL-)
BUTYL BENZYL PHTHALATE
BENZOIC ACID
9r 10-ANTHRAQUINUNE-1,7-DISULFONIC ACID
9, 10-ANTHRAUU1NONE-1,8-DISULFONIC ACID
9, 10-ANTHRAGUINONE-1,5-DI8ULFONIC ACID
ISOBUTYL ALCOHOL
2»3-EPOXY-l-PROPANOL
N-BUTANOL
AOIPIC ACID
3-METHOXYBIPHENYL
2/6-OIMETHYL-4-HEPTANOL
A-TERPINEOL
HYDROGEN CYANIDE
CADMIUM
l-METHOXY-4-NITROBENZENE
1-METHOXY-3-NITROBENZENE
METHOXYNITROBENZENES
1-METHOXY-2-NITROBENZENE
DIMETHYLNAPHTHALENES
2-ETHYLNAPHTHALENE
2-METHYLNAPHTHALENE
INDAN
1-ETHYLNAPHTHALENE
1-METHYLNAPHTHALENE
2,6-DIMETHYLNAPHTHALENE
2»3-DIMETHYLNAPHTHALEN£
TYPE CONC
E-6 G/L
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
D
S
T
T
T
T
T
T
T
T
T
T
T
T
1.30E 05
1.3UE 05
1.30E 05
1.30E 05
1.30E 05
1.3UE 05
1.30E 05
7.80E 04
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E OS
1.30E 05
1.30E OS
1.30E 05
< 2.00E OK
< 2.00E 00<
1.30E 05
1.30E 05
1.3UE 05
1.3UE 05
1.30E 05
1.3UE 05
1.30E 05
1.30E 05
1.30E OS
1.30E 05
1.30E 05
1.30E 05
US
7.00E-02
6.61E-02
6.61E-02
6.61E-02
6.61E-02
6.30E-02
6.30t-02
6.00E-02
6.00E-02
6.00E-02
5.71E-02
5.71E-02
5.71E-02
5.50E-02
5.bOE-02
S.bOE-02
5.23E-02
5.23E-02
5.23E-02
4.33E-02
4.00E-02<
4.00E-02<
3.92E-02
3.92E-02
3.92E-02
3.92E-02
3.70E-02
3.70E-02
3.70E-02
3.70E-02
3.70E-02
3.70E-02
J.70E-02
3.70E-02
WD8 LCCAT
ti/S
4.90E-01
4.63E-01
4.63E-01
4.63E-01
4.63E-01
4.40E-01
4.40E-01
4.20E-01
4.20E-01
4.20E-01
a.oot-oi
4.00E-01
4.00E-01
3.82b-01
3.82E-01
3.82E-01
3.70E-01
3.70E-01
3.70E-01
3.03t-01
2.80E-01
2.80b-01
2.74E-01
2.74t-01
2.74E-01
2.74E-01
2.60E-U1
2.60E-01
2.60L-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60b-01
I
M
H
i_n
-------
tt
OMEG NO.
&ASIF1ER ASH SL^ICt WATER, HfcALTH IMPACT
COMPOUND NAME
21 A 040
21 A 061
21 B 180* P
15 A 120
15 A 100
06 0 240
16 A 160
46 A 010 P
65 A 010
26 B 020
66 A 010 P
16 A 120* P
16 A 100* P
46 A 010
36 A 010
01 A 201
02 A 343
02 A 340* P
01 A 200 M
16 A 020* P
05 A 123
05 A 120
05 A 124
05 A 122
05 6 063
05 6 060
05 A 121
05 B 062
05 B 061
56 A 010
15 A 040* P
16 A 060
16 A 062
16 A 00J
MONQALKYL NAPHTHALENES
U4-D1METHYLNAPHTHALENE
PYRENE
ISOPROPYL BENZENE
PROPYL BENZENE
DI-2-ETHYLBUTYL ADIPATE
2-CHLOROTOLUENE
LEAD
VANADIUM
TRIPHENYL PHOSPHATE
CHKOMIUM
1,3-DICHLORUBENZENE
lr2»OICHLOROBENZENE
PHOSPHORUS
BARIUM
N-OCTANE
1,3-UICH|_UROPROPANE
OICHLOROPROPANES
OCTANES
CHLOROBENZENE
2»2-DIMETHYL-l-PROPANOL
PENTANOLS (PRIMARY)
3-METHYL-l-BUTANOL
2-METHYC-l-bUTANOL
3-METHYL-2-BUTANUL
PENTANOLS (SECONDARY)
N-PENTANOL
3-PENTANOL
2-PENTANOL
FLUORINE (AS F-)
TOLUENE
BROMOCHLOROBENZErttS
J -B«OMO-3-CHLURObENZ£N£
l-B«OMO-4-CHLOR08£WZ£Wf
TYPE
T
T
T
T
T
T
T
S
0
T
0
T
T
S
0
T
T
T
T
T
T
T
T
T
T
T
T
T
T
0
T
T
T
T
CUNC
E-6 G/L
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.3UE 05
8.00E 00
7.70E 01
1.30E 05
7.00E 00
1.30E 05
1.30E 05
4.00E 02
1.30E 02
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
.30E 05
1.30E 05
6.70E 02
1.30E 05
1.30E 05
1.30E OS
l.JOE 05
US
3.70E-02
3.70E-02
3.60E-02
3.40E-02
3.40E-02
3.30E-02
3.30E-02
3.20E-02
3.10E-02
2.V2E-02
2.80E-02
2.60E-02
2.bOE-02
2.70E-02
2.60E-02
2.40E-02
2.40E-02
2.40E-02
2.40E-02
2.40E-02
2.32E-02
2.32E-02
2.32E-02
2.32E-02
2.32E-02
2.32E-02
2.32E-02
2.32E-02
2.32E-02
2.30E-02
2.24E-02
2.13E-02
2.13E-02
2.13E-V2
NDS LCCAT
b/S
2.60E-01
2.60t-01
2.51t-01
2.34b.-Ul
2.34t-01
2.31L-01
2.3U-01
2.24t-01
2.20t-01
2.oat-oi
2.00E-01
2.00L-01
2.00t-01
l.VOt-01
l.Blt-01
1.70E-01
l.70t-01
1.70E-01
,70t-01
,70t-01
,62t-01
.62E-01
.62E-01
.62E-01
,62t-01
.62E-01
1.62E-01
1.02L-01
1.62E-01
l.OOt-01
1.60t-0l
1.50t-01
1.50fc-01
l.SOfc-01
-------
GASIFIER ASH SLUICE NAUR, HEALTH IMPACT
DMEG NO.
COMPOUND NAME
TYPE CONC
E-6 U/L
US
LCCAT
U/S
16 A 081
08 D 260
15 A 080
15 6 102
15 B 082
15 B 104
15 B 101
15 B 100
15 A 060* P
15 B 103
15 B 083
15 B 106
15 B 081
15 B 105
15 B 080
16 140* P
16 061
16 063
16 062
16 060
16 A 040
08 D 142
06 0 143
08 0 141
06 0 140
08 0 220
49 A 010 P
02 B 080* P
08 0 122
08 0 123
08 D 120
08 0 121
71 A 010 P
69 A 010
l-BROMG-2-CHLOROBENZENfc
OI-2-ETHYLHEXYL ADIHATE
STYRENE
M-DIETHYL BENZENt
M-XYLENE
0-DIISOPROPYL BENZENE
0-OIETHYL BENZENE
DIALKYL BENZENES (MM|134-191)
ETHYL BENZENE
P-OIETHYL BENZENE
P-XYLENE
1»4-DI-TEHT-BUTYL BENZENE
0-XYLENE
M-OIISOPROPYL BENZENE
XYLENES
1»4-DICHLURQBENZEN£
1/2-DIBROMOBENZENE
1,4-DIBROMOBENZENE
1,3-DIBROMOBENZENE
DIBROMOBENZENES
BROMOBENZENE
SEC-AMYL ACETATE
ISOAMYL ACETATE
N-AMYL ACETATE
AMYL ACETATES
OIBUTYL ADIPATE
ARSENIC
TETRACHLOROETHENE
SEC-BUTYL ACETATE
ISOBUTYL ACETATE
BUTYL ACETATES
N-BUTYL ACETATE
MANGANESE
MOLYBDENUM
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
r
T
D
D
1.50E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
J.30E 05
1.30E 05
1.30E 05
1.30E 05
3.30E 00
1.30E 05
1.30E 05
1.3ut 05
1.30E 05
1.30E 05
2.00E 00
3.10E 02
2.13E-02
2.02E-02
2.00E-02
1.V3E-02
1.93E-02
1.93E-02
1.V3E-02
1.93E-02
1.93E-02
1.93fc-02
1.93E-02
1.93E-02
1.V3E-02
1.93E-02
1.93E-02
1.64E-02
1.74E-02
1.74E-02
1.74E-02
1.74E-02
1.72E-02
1.60E-02
1.60E-02
1.60E-02
1.60E-02
1.44E-02
1.32E-02
1.30E-02
1.14E-02
1.14E-02
1.14E-02
1.14E-02
8.00E-03
4.13E-03
1.50E-01
1 ,41b-01
1.40E-01
i.aot-oi
1.40E-01
1.40h-01
1.40L-01
1.40b-01
1.40t-01
1.40E-01
1.40E-01
1.40b-01
l.UOt-01
l.UOE-01
1.40E-01
l.JOE-01
1.22E-01
1.22E-01
1.22E-01
1 ,22b-01
l.iOt-Ul
l.UE-01
l.llb-01
l.llb-01
l.llb-01
l.Olb-01
9.23E-02
8.80E-02
8.00E-02
B.OOb-02
8.00b-02
e.OOb-02
5.60E-02
2.90b-02 •
-------
00
GASIFIER ASH SLUICE HATER, HEALTH IMPACT
DMEG NO.
79 A 010 P
78 A 010 P
74 A 010
43 A 010
61 A 010 P
70 A 010
62 A 010
50 A 010 P
39 A 010
63 A 010
30 A 010
66 A 010
84 a 010
64 C 010
64 A 010
16 A 120* P
07 B 080* P
02 A 160* P
53 A 010
21 A 120* PH
16 A 100* P
04 B 020* P W
45 A 010
08 D 280* P W
19 A 040* P W
53 A 04Q
47 A 030
16 A 200* P
17 A 020* P
08 0 300* P
02 B 140* P M
06 U 260* P W
02 b 100* P
21 A 100* PH
COMPOUND NAME
SILVER
COPPER
CObALT
SILICON
ZINC
TUNGSTEN
TITANIUM
ANTIMONY
GALLIUM
ZIRCONIUM (AS ZR+4)
RUblOIUM (AS HBt)
NIOBIUM (AS Nb+3)
CEKIUM
PRASEODYMIUM
LANTHANUM
1,3-DICHLORObENZENE
ISOPHOffONE
BHOMOFORM
SULFUR
ACENAPHTHYLENE
1 , 2-DICHL0ROBENZENE
1,1'-OICHLOROMETHYL ETHER
TIN
PHTHALATE ESTERS (Mhjl94-279)
2r4-DICHLUKOP*£NOL
SULFITEr S03 -2
NITRITE, N02-
CHLORONAPHTHAL€NES
NITROBENZENE
DI-2-ETHYLHEXYL PHTHALATE
HEXAChLOPOCYCLUPENTADlENt
PHTHALATE ESTERS *H«lt<94-.274)
DICHLOROPHOPENES
ACENAPHTHENE
TYI
S
D
S
S
D
S
D
D
S
S
S
S
S
S
S
T
T
T
D
T
T
T
D
T
T
D
D
T
T
T
T
T
T
T
>E CONC
£-6 G/L
l.OOE 00
1.70E 01
< 2.00E 00<
3.00E 02
4.40E 01
2.00E 01
4.40E 01
2.00E 00
6.00E 00
2.00E 00
4.00E 01
2.00E 00
2.00E 00
l.OOE 00
< l.OOE 00<
O.OOE-01
O.OOE-01
O.OOE-01
9.70E 05
O.OOE-01
O.OOE-01
O.OOE-01
3.00E 03
O.OOE-01
O.OOE-01
4.70E 04
< l.OOE OK
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
US
4.00E-03
3.40E-03
2.70E-03<
2.00E-03
1.80E-03
1.33E-03
4.90E-04
2.70E-04
1.10E-U4
2.70E-05
2.22E-05
6.10E-06
3.63E-06
1.30E-06
5.90E-07<
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-U1
O.OOE-01
O.OOE-01<
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
WDS
ws
2.60E-02
2.40t-02
l.VOfc-02
1.40E-02
1.23E-02
9.33E-U3
3.42E-03
1.90E-03
7.60E-04
1.90E-04
1.60E-04
4.24t-05
2.54t-0b
9.10t-U6
4.11t-06
o.oot-oi
O.OOt-01
O.OOt-01
O.OOt-01
O.OOE-01
O.UOE-01
O.OOt-01
O.OOt-Ul
O.OOt-01
U.OOt-01
O.OOt-01
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
O.OOb-01
O.OOt-01
LCCAF
3
5
1
3
3
b
6
5
2
a
6
1
5
2
2
-------
GA8IFUR ASH SLUICE WATER, HEALTH IMPACT
OMEG NO. COMPOUND NAME
21 A 100* PH ACENAPHTHENE
47 A 020 NITRATE, N03-
02 B 120*
21 C 080*
16 A 100*
19 A 020*
21 A 140*
16 A 120*
21 A 160*
21 A 160*
29 A 010
04 B 040*
16 A 140*
2! 0 080*
21 A 140*
08 D 320*
02 A 140*
HEXACHLOROBUTADIENE
DIBENZ( A, H) ANTHRACENE
lf2-DICHLOROB£NZEN£
M 2-CHLOROPHENOL
ANTHRACENE
1,3-OICHLOROBENZENE
W PHENANTHRENE
W PHENANTHRENE
POTASSIUM
1»1'»DICHLORODIETHYL ETHER
1,4-DICHLOROBENZCNE
H BENZO(GHI)PERYLENE
ANTHRACENE
BUTYL BENZYL PHTHALATE
DIBROMOCHLOROMETHANE
53 A 030 SULFATE, 804 -2
22 A 020* PH FLUORENE
02 A 160* P BROMOFORM
22 B 040* P W FLUORANTHENE
46 A 020 PHOSPHATE, P04 -3
17 A 061* P 2»6-DINITROTOLUEN£
04 A 160* P CHLOROPHENYL PHENYL ETHER
22 C 020* P BENZO(K)FLUORANTH£N£
02 A 340* P DICHLOROPROPANE8
04 B 020* P W lrl'-OJCHLOROMETHYL ETHER
21 B 120* P CHRYSENE
21 B 120* P CHRYSENE
58 A 010 BROMINE
08 D 300* P DI-2-ETHYLHEXYL PHTHALATE
22 D 020* P W INDENO(lr2»3-CD)PYRENE
17 A 061* P 2»6-DINlTROTOLUENE
02 B 060* P TETRACHLOROETHENE
TYPE
T
0
T
T
T
T
T
T
T
T
S >
T
T
T
T
T
T
D
T
T
T
0 <
T
T
T
T
T
T
T
8
T
T
T
T
CONC
E-6 G/L
O.OOE-01
3.00E 03
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
l.OOE 04>
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
2.90E 06
O.OOE-01
O.OOE-01
O.OOE-01
l.OOE 02<
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
2.00E 01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
US
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01>
O.OOE-01
o.ooE-oi
O.OOE-01
O.OOE-01
O.OOE-01
o.ooE-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01<
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-OI
O.OOE-01
MDS
G/S
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-U1
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
LCCAT
3
1
3
2
5
3
2
2
3
5
3
2
2
5
2
3
2
2
4
5
3
1
4
2
3
5
3
5
2
7
-------
to
o
&ASIFIER ASH SLUICE MATER* HfcALTH IMPACT
DMEG NO.
COMPOUND NAME
08 D 320* P
02 B 100* P
18 A 142* P
16 A 142* P
21 A 120* PH
12 A 020* P W
12 A 020* P w
02 A 320* P
12 A 040* P
12 A 040* P
02 B 140* P M
12 A ObO* P
12 A ObO* P
16 A 140* P
21 D 080* PH
21 8 040* P
02 B 120* P
16 A 160* P
16 A 160* P
04 A 140* P
04 A 140* P
04 A 160* P
04 A 160* P
04 A 160* P
16 A 200* P
04 A 160* P
15 0«0* P
15 040* P
19 020* P W
15 060* P
15 060* P
19 040* P W
22 D 020* P W
19 A 060* P W
HUTYL BENZYL PHTHALATE
DICHLOROPKUPENES
2,4-XYLENOL
2»<«-XYLENOL
ACENAPHTHYLENE
N-NITROSODIMETHYLAMINC
N-NITROSOUIMETHYLAMINE
HEXACHLOROETHANE
N-NITROSODIETHYLAMINE
N-NITkOSOOIETHYLAMINE
HEXACHLOROCYCLOPENTADIENE
N-NITROSODIPROPYLAMlNE
N-NITROSODIPROPYLAMINE
1,4-DICHLOROBENZENE
BENZO(CHI)PERYLENE
BENZ(A)ANTHRACENE
HEXACHLOROBUTAOIENE
POLYCHLORINATEO BENZENES
POLYCHLORINATEO BENZENES
2-CHLOROETHYL VINYL ETHER
2-CHLOROETHYL VINYL ETHER
A-CHLOROBUTYL ETHYL ETHER
A-CHLOROBUTYL ETHYL ETHER
A-CHLOROBUTYL ETHYL ETHER
CHLORONAPHTHALENES
CHLOROPHENYL PHENYL ETHER
TOLUENE
TOLUENE
2-CHLOROPHENOL
ETHYL BENZENE
ETHYL BENZENE
2r4-DICHLOKOPHENUL
INDENO (1 r 2> 3-CD) PrRtNE
PEN T ACHLOROPHENOi,
TYPE CONC
E-b G/L
US
WDS
LCCAT
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-OI
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-Ul
o.oot-oi
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
o.oot-oi
o.oot-oi
O.OOE-01
o.oot-oi
O.OOE-01
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
O.OOE-01
o.oot-oi
O.OOt-01
O.OOE-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
6
1
5
b
2
5
b
2
5
b
2
5
b
2
3
2
2
3
4
5
4
5
3
4
2
3
6
2
3
6
2
5
-------
GASIFIER ASH SLUICE WATER, HEALTH IMPACT
DMEG NO.
19 A 060* P M
17 A 020* P
21 B 160* P
21 B 180* P
19 B 022*
19 B 022*
21 A 120* H
21 C 080*
20 A 020* M
20 A 020* W
21 C 100* N
21 C 100* P W
20 A 060* P W
20 A 060* P W
17 A 084* P
17 A 064* P
21 B 040* P
20 A 101* P
20 A 101* P
21 D 060* PH
02 A 140* P
22 A 020* PH
22 A 020* PH
20 B 020* P M
20 3 020* W
07 B 060*
22 B 040* M
02 A 320*
22 C 020*
21 A 020*
21 A 020*
02 A 340*
22 C 060* P W
22 C 060* P W
COMPOUND NAME
PENTACHLOROPHENOL
NITROBENZENE.
PYRENE
PYRENE
CHLORINATED-M-CRESOLS
CHLORINATED-M-CRESOLS
ACENAPHTHYLENE
DI8ENZ( A, H) ANTHRACENE
2-NITROPHENOL
2-NITROPHENOL
BENZO(A)PYREN£
BENZO(A)PYRENE
4-NITROPHENOL
4-NITROPHENOL
2,4-DlNlTROTOLUENE
2f4-DINITROTOLUENE
BENZ(A)ANTHRACENE
2»4-DINlTROPHENOL
2f4-DINlTROPHENOL
BENZO(GHI)PERYLENE
OIBKOMOCHLOROMETHANE
FLUORENE
FLUORENE
4,6-DINITKO-O-CRESQL
4,6-DlNlTRO-O-CRESQL
ISOPHORONE
FLUORANTHbNE
HEXACHLOROETHANE
BENZO(K)FLUORANTHENE
NAPHTHALENE
NAPHTHALENE
DICHLOROPROPANES
BENZO(B)FLUORANTHENE
BENZO(B)FLUORANTHENE
TYP
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
E CONC
E-6 G/L
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOb-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
US
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.yoE-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
WD3
U/S
O.OOE-01
O.OOb-01
O.OOfc-01
O.OOE-Ol
U.OOb-01
O.OOE-01
o.oob-oi
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOb-01
O.OOE-01
O.OOb-01
O.OOE-01
O.OOb-01
O.OOb-01
O.OOb-01
O.OOb-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOb-01
O.OOb-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOb-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
LCCAT
6
5
2
3
5
6
2
5
6
2
3
5
6
4
5
2
5
6
3
1
2
5
6
6
3
1
2
2
3
2
2
3
-------
N>
GA8IF1ER ASH SLUICE HATER, HEALTH IMPACT
DME6
04
16
16
02
10
10
21
B
A
A
B
C
C
A
NO.
040*
020*
020*
080*
140*
140*
100*
P
P
P
P
P
P
PH
COMPOUND NAME
If I'-OICHLOROOXETHYi. ETHER
CHLOROBENZENE
CHLOROBENZENE
TETRACHLOROETHENE
BENZIOINE
BENZID1NE
ACENAPHTHENE
TYPE CONC
E-6 G/L
T
T
T
T
T
T
T
0.
0.
0.
0.
0.
0.
1.
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
30E 05
0,
0,
0,
0,
0,
0,
0,
us
•OOE-01
•OOE-01
•OOE-01
.OOE-01
.OOE-01
.OOE-01
•OOE-01
HDS
6/3
O.OOt-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOt-01
LCCAT
4
I
3
1
5
6
-------
GA8IFIER ASH SLUICE MATER
APPROXIMATE FLCM RATE • 7.0 G/8 (0.007 L/S)
TOTAL ORGANIC LOADING 125.7 HG/L
ORGANIC LOADING
125700.0
FLOW RATE « 7.00
STATES LIQUID* UNITS IN MICNOGRAMS/L
IMPACTS ECOLOGY
EXPERIMENTALY DETERMINED DATA
SPARK SOURCE DATA
NJ
U>
-------
IS)
•IS
GA3IPIER ASM SLUICE WATER, ECOLOGY IMPACT
DMEG NO.
16 A 220
02 A 360
06 0 263
06 0 262
06 D 261
06 D 260*
19 A 060*
16 A 0«0
26 B 0«0
16 A 020*
16 162
16 061
16 082
16 063
16 100*
10 200
16 060
16 120*
20 A 101*
10 C 140*
16 A 062
16 A 063
20 A 060
16 A 160*
16 B 043
21 A 020*
16 A 161
01 B 220
20 A 103
10 C 220
20 A 100
16 A 061
16 0 020
U 0 099
W
M
P M
P *
M
P
P
M
P
P
P N
N
P
P
W
W
M
W
COMPOUND NAME
POLYCHLORINATED BIPHEKYL3
HEXACHLOROCYCLOHEXANE
DI-N-BUTYL PHTHALATE
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
PHTHALATE E8TER8 (MX t 194-279]
PENTACHLOROPHENOL
BROHOBENZENE
TRITOTYL PHOSPHATES
CHLOROBENZENE
HEXACHLOROBENZENE
-BROMO-2-CHLOROBENZENE
•BRUMO-3-CHLOROBENZENE
-BROMO-4-CHLOROBENZENE
,2-DICHLOROBENZENE
-AHINONAPHTHALENE
BROMOCHLOROBENZENES
1»3-DICHLOROBENZENE
2»4-DlNITROPHENOL
BENZIDINE
1,3-DIBROMObENZENE
1,4-DIBROMOBENZENE
2-AMINO-4r6-DINITROPHENOL
POLYCriLORJNATED BENZENES
1,4-BISCCHLOROMETHYL)BENZENE
NAPHTHALENE
1,2,4-TRICHLOROBENZENE
DICVCLOPENTADIENE
2,6-OlNJTROPHENOL
2-AMJNONAPHTHALENE
DINITROPHENOLS
1,2-DI8ROM06ENZEN£
A-CHLOROTOLUENE
Bl»(C*LQ*Q»lTHYL)BtHllHn
TYPE CONC US
E-6 6/1
t .30E OS 2.S1E 07
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
.30E OS 6.30E 06
.JOE 05 6.40E 04
.30E OS 6.40E 04
.30E OS 6.40E 04
.JOt 05 6.40E 04
.JOE OS 5.02E 03
.JOE 05
.JOE OS
.JOE OS
.JOE OS
.JOE 05
.JOE OS
.JOE OS
.JOE OS
.JOE 05
.JOE 05
.JOE OS
.JOE 05
.JOE 05
.JOE 05
.JOE OS
.JOE 05
.JOE OS
.JOE 05
.JOE 05
.JOE OS
.JOE 05
.JOE 05
.JOE 05
.JOE OS
.JOE OS
«10E OS
•IOC OS
.JOE 03
.30E 03
.30E 03
.JOE 03
.JOE 03
.30E 03
.JOE 03
.JOE 03
.Jot 03
.JOE 03
.JOE 03
.JOE 03
.JOE. 03
.JOE 03
.JOE 03
.JOE 03
.JOE 03
.JOE 03
.JOE 03
.JOE 03
.JOE 03
.JOE 03
.JOE 03
•JOE 03
.JOE 03
.JOE 03
• JOE 03
NUS LCCAT
WS
1.60k 06
4.40E 07
5.90E 05
5.90E 05
5.90t 05
5.90t 05
3. ME 04
8. dot OJ
6.60E OJ
e.60k oj
6. 80t OJ
8.BOE OJ
6.60E OJ
8.bOt OJ
6.60k OJ
e.bok oj
6.60E OJ
8.60E OJ
6.60k OJ
6.60E 03
e.ttOE OJ
6.60k OJ
e.aot oj
6.60k OJ
8.60k OJ
8.60k OJ
6.60E OJ
6.60E OJ
6.60k OJ
8.60E OJ
8.60E 03
8.80E 03
S.SOE 03
e,«o£ 03
-------
DMEG NO.
GASIFIER ASH SLUICE WATER, ECOLOGY IMPACT
COMPOUND NAME
TYPE CUNC US
E-6 G/L
MOS
U/S
LCCAT
16 B 041
16 B 042
16 A 060
16 A 140* P
20 A 102
48 A 010
20 A 040
16 B 020 M
20 B 020* P W
19 A 020* P
16 A 163
16 A 120 H
16 C 061
16 C 062
18 B 060 W
16 A 142* P
16 A 060 W
19 A 040* P
20 A 020* P
20 A 120
16 A 145
20 A 060* P
16 A 160 W
16 A 040 W
16 A 041
16 A 042
16 A 043
23 B 060 M
16 A 060 W
16 A 061
19 b 023
18 A 144
16 A 100 W
18 A 101
lr2-BIS(CHLUROMETHYBENZENE
lr3-BISCCHLOROMETHYL)BENZENE
DIBROMOBENZENES
1,4-DICHLOROBENZENE
2,5-DINITROPHENOL
PHOSPHORUS
3-NITROPHENOL
CATECHOL
4,6-DINITKO-0-CRE30L
2-CHLOROPHENOL
2.6-DIMETHYL-4-HEPTYL PHENOL
2,2'-DIHYDRUXYDIPH£NYL
1-INDANOL
4-INDANOL
lt2,3-TRIHYDROXYBENZENE
2,4-XYLENOL
ETHYLPHENOLS
2,4-DICHLOROPHENUL
2-NITROPHENOL
2»4,6-TRINITROPHENOL
3»5-XYLENUL
4-NITROPHENOL
ETHYL CRESOLS
CRESOLS
M-CRESOL
0-CRC30L
P-CRESOL
ACRIDINE
2-METHOXYPHENOL
0-ETHYLPHENOL
CHLORINATEO-P-CRESOLS
2f6-XYLENOL
PHENYLPHENOLS
0-PHENYLPHENOL
T
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1.30E 05
1.3UE 05
.30E 05
.JOE 05
.30E 05
.OOE 02
.30E 05
.506. 05
.30E 05
.30E 05
,30E 05
.3UE 05
.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1. JOE 05
I.JOE 05
L.3UE 05
I.JOE 05
1.30E 05
.30E 05
.JOE 05
.JOE 05
.JOE 05
.JOE 05
.JOE 05
.JOE 05
.JOE 05
.JOE 05
.JOE 05
.JOE 05
.JOE 05
1.30F 03
l.-SOt OJ
1.3UL 03
I.JOE. 03
1.30E 03
8. OOE 02
2.51E 02
2.51E 02
2.51E 02
2.51E 02
l.blE 02
2.51E 02
2.bl£ 02
2.51E 02
2.51E 02
2.51E 02
2.51E 02
2.blE 02
2.S1E 02
2.51E 02
2.51E 02
2.5U 02
2.51E 02
2.51E 02
2.51E 02
2.51E 02
2.blE 02
2.blE 02
2.51E 02
2.5U 02
2.51E 02
2.51E 02
2.51E 02
2.blE 02
b.aot 03
e.boE 03
b.ttOt 03
b.aot 03
ti.OOt 03
5.60E 03
1.60E 03
l.bot 03
1.60k 03
1.60E 03
1.80E 03
i.eoE 03
1.60E 03
1.60E 03
l.bOE 03
i.eot 03
i.aoe 03
i.eot 03
l.bOE 03
1.60E 03
l.ttOt 03
1.BOE 03
l.bot 03
1.60E 03
l.bOE 03
l.bOE 03
l.bot 03
l.bot 03
l.bOt 03
l.bot 03
l.boE 03
1.60E 03
l.bOE 03
l.bOE 03
IS3
Ul
-------
to
GASIFIER ASH SLUICE WATER, ECOLOGY IMPACT
DMEG NO.
COMPOUND NAME
TYPE CONC US
E-6 G/L
LCCAT
b/S
18 A 102
18 A 103
16 C 080 W
16 A 140 w
16 C 063
18 A 141
18 A 181
18 A 161
16 A Ib2
16 A 143
18 B 060 W
16 A 146
16 C 020 W
16 C 04Q W
18 A 162
18 A 163
18 A 160 W
18 A 083
18 B 040 W
19 6 021
19 B 022* P
19 B 020 W
20 B 041
20 B 042
18 A 082
20 B 040 *
15 A 040* P W
17 A 065
06 D 142
06 0 143
17 A 063
02 A 340* P
02 B 100* P W
02 d 080* P H
P-PHENYLPHENOL
M-PHENYLPHENOL
INDANOLS
XYLENOLS
5-INDANOL
2»3-XYLENOL
2,4,6-TRIMETHYL METHYL PHENOL
6-ETHYL-M-CKESOL
4-ETHYL-O-CKESOL
2»5-XYLENOL
1,4-DlHYDROXYBENZENE
3,4-XYLENOL
1-NAPHTHOL
2-NAPHTHOL
4,6-UI-TEHT-bUTYL-M-CKE30L
2-ETHYL-P-CKESOL
PULYALKYLPHENOLS («W>1S5)
P-ETHYLPHENOL
1,3-DIHYDROXYBENZENE
CHLOR1NATED-0-CRESOLS
CHLORlNATED-*-CR£50LS
CHLORINATED CRESOLS
3f5-OlNlTHO-P-CR£SOL
2,6-DlNlT*0-P-CP-£SOL
M-ETHYLPHENOL
DINITRO-P-CKESOLS
TOLUENE
2,5-DlNITROTOLUENt
SEC-AMYL ACETATE
ISOAMYL ACETATE
2,3-DINITROTOLUENE
DICHLOROPROPANES
OICHLOROPROPENfS
Tfc'TRACHLOftO£TH£NE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1.30E 05
1.30E Ob
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
.JOE 05
.30E 05
.JOE 05
.JOE 05
.30E 05
l.JoE 05
1.30E 05
1.30E 05
1.30E 05
.30E 05
,30E 05
.JOE 05
.30E 05
.JOE 05
.30E 05
1.30E 05
1.30E 05
.30E 05
.JOE 05
.30E 05
,30E 05
.30E 05
.3UE 05
1.30E 05
2.51E 02
2.51E 02
2.5U 02
2.51E 02
2.51E 02
2.blE 02
2.51E 02
2.51E 02
2.51E 02
2.51E 02
2.51E 02
2.51E 02
2.51E 02
2.51E 02
2.51E 02
2.51E 02
2.blE 02
2.blE 02
2. bit 02
2.51E 02
2.5lt 02
2.51E 02
2.51E 02
2. bit 02
2. bit 02
2.51E 02
1.30E 02
1.30E 02
1.30E 02
1.30E 02
1.30E 02
1.30E 02
1.30E 02
1.30E 02
l.bOt U3
l.bOt 03
l.bOt 03
l.bOt 03
l.bOt 03
l.bot 03
l.bOt 03
l.ttOt 03
l.bOt 03
l.bOt 03
l.bOt 03
l.bot 03
l.bOt 03
1.80E 03
l.bot 03
l.eot 03
l.bot 03
l.bOE 03
l.bot 03
l.bOt 03
l.bot 03
l.bot 03
l.bot U3
l.bot 03
l.bOt 03
l.bot 03
b.bOt 02
b.bot 02
b.bOt 02
6.bOt 02
b.bOt 02
b.bot 02
b.bot 02
b.bOt 02
-------
GA8IFIER ASH SLUICE HAUR, ECOLOGY IHPACT
DMEG NO.
17 A 086
15 B 082
02 B 103
08 040 W
10 080 W
17 041
02 343
15 060* P W
17 082
08 0 141
15 B 081
15 B 083
17 A 040 W
17 A 042
17 A 020* P W
17 A 043
17 A 080 H
15 B 106
15 B 120 W
17 A 084* P
10 C 020
15 B 080 W
08 0 123
08 0 140
15 B 105
15 B 101
04 A 060 H
15 B 102
08 0 120
17 A 081* P
15 A 100 N
02 B 104
08 0 121
06 0 122
COMPOUND NAME
3,5-OlNlTKOTOLUENE
M-XYLENE
CIS-1, 3-DICHLOROPROPENE
ACETIC ACID
1,2-DJAMINOETHANE
2-NITROTOLUENE
1 , 3-DICHLOROPROPANE
ETHYL BENZENE
3,4-DINITROTOLUENE
N-AMYL ACETATE
0-XYLENE
P-XYLENE
NITROTOLUENES
3-NITROTOLUENE
NITROBENZENE
4-NITROTOLUENE
DINITROTOLUENE8
1,4-DI-TERT-BUTVL BENZENE
TETRAHYDRONAPHTHALENE
2,4-DINITROTOLUENE
ANILINE
XYLENES
I80BUTYL ACETATE
AMYL ACETATES
M-DIISOPROPYL BENZENE
0-OIETHYL BENZENE
l-CHLORO-1 , 3-EPOXYPROPANE
M-DIETHYL BENZENE
BUTYL ACETATES
2,6-DINITROTOLUEN£
PROPYL BENZENE
TRANS-1 r 3-DICHLOROPROPENE
N-BUTYL ACETATE
SEC-BUTYL ACETATE
TYP
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
E CONC
E-6 G/L
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E OS
1.30E 05
1.30E OS
1.30E 05
1.30E OS
1.30E 05
I.JOE 05
1.30E 05
1.30E 05
1.30E 05
I.JOE 05
1.30E 05
1.30E 05
1.30E 05
1.30E OS
OS
I.JOE 02
' I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
l.JOt 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
I.JOE 02
WDS LCCAT
G/8
tt.bOE 02
b.bOt 02
b.bOt 02
b.boE 02
s.aot 02
b.bOE 02
b.boE 02
6.80E 02
e.bot 02
b.bot 02
b.bOt 02
b.bot 02
b.bot 02
b.bOE 02
b.bot 02
b.bOt 02
b.bot 02
b.bOt 02
b.bot 02
b.bOt 02
b.bot 02
b.bot 02
b.bOt 02
b.bot 02
8.60E 02
8.60E 02
8. dot 02
e.bot 02
8.80E 02
e.bot 02
b.ttOt 02
s.aot 02
b.eot 02
b.bOt 02
-------
to
cc
UASIFIER ASH SLUICE HATER, ECOLOGY IMPACT
DMEG
15
15
04
15
15
15
04
a?
15
08
09
09
09
09
06
08
08
08
08
34
08
05
08
23
23
17
23
05
08
05
10
15
23
23
6
6
A
8
A
A
A
A
B
A
B
B
b
B
A
A
A
A
A
A
A
A
B
A
A
B
A
A
0
A
A
B
A
A
NO.
103
104
050
100
060
120
oao
060
020
080
042
040
020
041
104
103
102
101
100
010
180
120
060
062
120
060
060
100
080
123
060
201
082
121
w
w
w
w
w
p
M
W
w
w
W
W
W
W
COMPOUND NAME
P-DIETHYL BENZENE
O-OIISOPROPYL BENZENE
EP1CHLORHYDRIN
DIALKYL BENZENES (M« 1 134-191 )
STYRENE
ISOPROPYL BENZENE
2-CHLORO-l,2-EPOXYPHOPAN£
AMMONIA
INDAN
VALEKIC ACID
B-NAPHTHONITRILES
NAPHTHONJTRJLES
BENZONITR1LE
A-NAPHTHONITR1LES
LAUKIC ACID
CAPRIC ACID
CAPRYLIC ACID
CAPROIC ACID
SATURATED LONG CHAIN ACIDS (MWJ116-201)
CALCIUM (AS CA+2)
ADIPIC ACID
PtNTANOLS (PRIMARY)
B-PROPIOLACTONE
3-ETHYLPYKIDINE
COLLIDINES
l-CHLORO-4-NITROBENZENE
MONOSUBSTITUTED ALKYL PYRIDINES
ISOBUTYL ALCOHOL
METHYL METHACRYLATE
2,2-DIMETHYL-l-PROPANOL
ETHANOLAMINE
1,2,3,4-TETRAMETHYLBENZENE
3-PHENYLPYRJDINE
5-£THYL-2-M£THYLPrRJOlNfe
TYPE CONC
E-6 G/L
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
.30E
.306.
.30E
.30E
.30E
.30E
• 30E
5.40E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
2.20E
1.30E
1.30E
1.30E
1.30k
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
05
05
05
05
05
05
05
03
05
05
Ob
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
05
US
.30E
.30t
.30E
,30t
..sot
,30fc
.30t
1.10E
9.00E
1.63E
1.61E
1.61E
1.61E
l.olE
1.42t
1.42E
1.42E
1.42E
1.42E
.act
. 30E.
.30E
.iOk
.30E
.iOt
.4UE
• 30£
.30E
.30E
1.30E
1.30E
1.30E
1.30E
1.30E
02
02
02
02
02
02
02
02
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
NDtt
li/S
b.eot
8. bOb
b.tJOt.
tt.bOt
d.bot
e.bot
tt.bOt
7.60t
6.30t
1.1 at.
1.12&
1.12L
1.12E
1.1 2t
i.oot
i.oot
i.oot
i.oot
1.00k
9.62t
9. lOt
b.bOt
a.bot
e.bot
e.bot
s.eot
8.80E
b.bot
b.bot
8.80k
8.80E
8.80k
8.80t
e.bot
LCCAT
02
02
U2
02
02
02
02
02
02
02
02
02
U2
02
02
02
02
02
02
Ul
01
01
01
01
01
01
01
01
01
Ul
01
01
01
01
-------
GASIFIER ASH SLUICE. WATER, ECOLOGY IHPACT
OMEG NO.
COMPOUND NAME
TYPE CONC US
E-6 G/L
WDS
b/S
LCCAT
05 A 121
08 D 101
01 A 201
23 A 061
10 A 160
83 A 063
23 A 064
04 B 080 N
08 0 100
23 A 030 M
03 B 020
10 B 100
23 A 063
15 B 202
01 A 200
05 A 124
04 B 040* P W
23 A 080 W
15 B 203
06 A 020 W
IS B 200
05 A 122
17 B 040 W
US A 140 W
23 A 122
23 A 061
07 B 100 W
38 A 010
07 B 120
08 A 140
72 A 010
82 A 010 P
76 A 010 P
05 A 080
N-PENTANOL
N-PROPYL ACETATE
N-UCTANE
2-tTHYLPYRIDINE
CYCLCHEXYLAMINE
4-PHENYLPYRIDINE
4-N-PROPVLPYRIOINE
2»2'-DICHLORODIETHYL ETHER
PHOPYL ACETATES
PYKIUINE
1,4-DIOXANE
MORPHOLINE
4-ETHYLPYRIOINE
1,2,3,5-TETKAMETHYLBENZENE
OCTANES
3-METHYL-l-BUTANOL
1,1'-DICHLORODIETHYL ETHER
PHENYLPYRIDINES
1,2,4,5-TETRAMETHYLBENZENE
ETHYLENE GLYCOL
TETRAMETHYLBENZENES
2-METHYL-l-BUTANOL
l-CHLORO-2-NITROBENZENE
BENZYL ALCOHOL
2,4,6-COLLIDINE
2-PHENYLPYRIDINE
CAMPHOR
ALUMINUM
ACETOPHENONE
OLEIC ACID
IRON (AS FE*2)
CADMIUM
NICKEL
N-8UTANOL
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
D
S
S
T
1.30E 05
1.30E 05
1.30E 05
1.30E OS
1.30E 05
1.30E 05
1.30E 05
1.30t 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E OS
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E 05
1.30E OS
1.30E 05
1.30E 05
1.10E 04
1.30E 05
1.3UE 05
1.20E 03
2.00E 00<
2.00E 01
1.30E 05
1.30& 01
1.30E 01
1.30E 01
l.3ot 01
1.30E 01
1.30t 01
1.4 OE 01
1.30E 01
1.30t 01
1.30E 01
1.30E 01
1.30E. 01
1.30E 01
1.30E 01
1.30E 01
1.30E 01
1.30E 01
1.30E 01
1.30E 01
1.30E 01
1.30E 01
1.30E 01
1.30E 01
1.30E 01
1.30E 01
1.30E 01
1.14E 01
1.10E 01
7.90E 00
6.00E 00
4.bOE 00
2.00E 00<
2.00E 00
1.30E 00
B.ttOt 01
b.tiOb 01
tt.tJOt 01
e.tiot 01
b.tiot ui
b.bot 01
e.bot 01
b.eot 01
b.eoE 01
B.80E 01
tt.bot 01
fi.tiOE 01
tt.ttOt 01
e.bot 01
b.bot 01
B.bOt 01
b.bot 01
b.bot 01
B.bOt 01
B.bot ui
B.bOt 01
B.bOt 01
B.bOt 01
B.bOt 01
B.bOt 01
B.bOE 01
e.uot 01
7.70t 01
5. SOt 01
4.20E 01
3.40t 01
1.40t 01
1.40t 01
8.BOt 00
IT:
ho
vo
-------
H
O
DMEG
06
08
05
08
27
54
47
18
65
81
78
79
37
46
33
49
62
36
69
68
71
50
74
83
53
16
47
15
16
63
47
12
28
08
A
D
C
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
D
NO.
040
320*
040
080
010
010
080
020
010
010
010
010
010
010
010
010
010
010
010
010
010
010
010
010
010
100*
030
040*
020*
010
020
040*
010
260*
GASIFIER ASH SLUICE rtATER, ECOLOGY IMPACT
COMPOUND NAME TYPE COMC
E-6 G/L
P
W
P
P
P W
P
P
P
P
P
P
P
P
P
P
P W
P
P
P W
PRUPYLENE GLYCUL
BUTYL BENZYL PHTHALATE
T-PENTANOL
Y-6UTYROLACTONE
LITHIUM
SELENIUM
HYDROGEN CYANIDE
PHENOL
VANADIUM
ZINC
COPPER
SILVER
BORON
LEAD
MAGNESIUM
ARSENIC
TITANIUM
BARIUM
MOLYBDENUM
CHROMIUM
MANGANESE
ANTIMONY
COBALT
MERCURY
SULFUR
If 2-DICHLURUbENZENE
NITRITE, NU2-
TOLUENE
CHLOROBENZENE
ZIRCONIUM (AS ZR+4)
NITRATE, N03-
N-NITROSODIfcTHYLAMJNE
SODIUM
PHTHALATE ESTERS (M*| 194-279)
T
T
T
T
S
D
D
D
D
D
0
S
D
S
U
D
D
D
D
D
0
D
S
D
0
T
D
T
T
S
D
T
U
T
1.
1.
1.
1.
4.
2.
< 2.
3.
7.
4.
1.
1.
4.
8.
1.
3.
4.
1.
3.
7.
2.
2.
< 2.
1.
9.
0.
< 1.
0.
0.
2.
3.
0.
1.
0.
JOE 05
30E Ob
30E 05
30E 05
,OOE 02
,OOE 01
,OOE OK
60E 02
70E 01
,40E 01
70E 01
OOE 00
(60E 03
OOE 00
lOt 04
30E 00
40E 01
3UE 02
10E 02
OOE 00
OOt 00
OOE 00
OOE 00<
40E 00
70E 05
OOE-01
OOE OK
OOE-01
OOE-01
OOE 00
OOE 03
OOE-01
TOE 06
OOE-01
1
1
1
1
1
8
8
7
5
4
3
2
1
1
1
6
5
5
4
2
2
1
8
5
0
0
0
0
0
0
0
0
US
.30E 00
.JOE 00
.30E 00
.30E 00
.lot oo
.OOE-01
.OOE-OK
.20E-01
.13E-01
.40E-01
.40E-01
.oot-oi
.84E-01
.60E-01
.30E-01
.60E-02
,40fc-02
.20E-02
.42E-U2
,80t-02
.OOE-02
.OOE-02
,OOE-03<
.60E-U3
.oot-oi
.OOE-01
.OOE-OK
.oot-oi
.OOE-01
.OOE-01
.OOE-01
.OOE-01
0. OOE-01
0. OOE-01
NDS
G/S
8.*0t 00
8. dOt 00
8.bOt 00
b.bOE 00
7.40t 00
5.60t 00
5.60L 00
5.0it 00
3.60t 00
3. lOt 00
2.40t 00
1.40t 00
1.30t 00
l.llt 00
8.VOE-01
4.61E-01
3,BOt-01
3.64E-01
3.10L-01
2.00t-01
1.40E-01
7.UOE-02
5.60E-02
3.9U-02
O.OOt-01
o.oot-oi
O.OOt-01
O.OOt-01
o.oot-oi
0. OOE-01
o.oot-oi
O.OOt-01
0. OOE-01
O.OOt-01
LCCAT
3
3
3
6
b
-------
GASIFUR ASH SLUICE HATER* ECOLOGY 1HPACT
OHEG NO.
02 A 140* P
15 A 060* P W
12 A 040* P
53 A 040
16 A 140* P
12 A 060* P
12 A 020* P
53 A 030
16 A 160* P
15 A 040* P W
17 A 004* P
17 A 064* P
15 A 060* P M
02 A 140* P
02 A 160* P
02 A 160* P
70 A 010
08 D 300* P
35 A 010
02 B 120* P
10 C 140* P M
08 0 320* P
02 A 340* P
16 A 100* P
02 A 140* P
12 A 020* P
02 B 080* P M
02 B 060* P M
12 A 040* P
02 B 100* P N
12 A 020* P
02 B 120* P
12 A 060* P
16 A 142* P
COMPOUND NAME
DIBROMOCHLOROMETHANE
ETHYL BENZENE
N-NITROSOOIETHYLAMINE
SULFITE, 303 -2
1»4-DICHLOROBENZENE
N-NITROSOOIPROPYLAHINE
N-NITROSOOIMETHYLAMINE
SUIFATE, S04 -2
POLYCHLORINATED BENZENES
TOLUENE
2r4-DINITROTOLUENE
2»4-DINITROTOLUENE
ETHYL BENZENE
DIBROMOCHLOROMETHANE
BROMOFORM
BROMOFORM
TUNGSTEN
DI-2-ETHYLHEXYL PHTHALATE
STRONTIUM
HEXACHLOROBUTADIENE
BENZIOINE
BUTYL BENZYL PHTHALATE
DICHLOROPROPANES
1,2-DICHLOROBENZENE
DIbROMOCHLORQMETHANE
N-NITROSODIMETHYLAMINE
TETRACHLOROETHENE
TETRACHLOROETHENE
N-NITR030DIETHYLAMINE
DICHLOROPROPENES
N-NITROSOOIMETHYLAMINE
HEXACHLOROBUTADIENE
N-NITROSODIPROPYLAMINE
2f4-XVLENOL
TYPI
T
T
T
D
T
T
T
D
T
T
T
T
T
T
T
T
S
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
E CONC
E-6 G/L
1.30E 05
O.OOE-01
1.30E 05
4. TOE 04
O.OOE-01
1.30E 05
O.OOE-01
2.90E 06
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
2.00E 01
O.OOE-01
4.00E 03
O.OVE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
1.30E 05
1.30E 05
O.OOE-01
O.OOE-01
US
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
W08
tt/8
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-Ol
O.OOE-01
O.OOt-01
O.OOt-01
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-01
O.OOE-01
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
O.OOt-01
O.OOE-01
LCCAT
3
2
6
3
2
4
5
2
2
1
b
1
6
6
2
2
1
5
1
2
5
1
0
b
-------
U)
ho
6A8IFIER ASH SLUICE NAUR, ECOLOGY IMPACT
DMf
1«
02
02
02
02
58
02
02
02
12
10
02
17
17
66
08
84
30
43
08
17
08
29
08
19
19
16
19
19
57
19
19
56
07
:G
A
B
B
B
B
A
A
A
B
A
C
A
A
A
A
D
C
A
A
D
A
D
A
D
A
A
A
A
A
A
A
A
A
B
NO.
142*
120*
140*
140*
140*
010
160*
320*
100*
060*
140*
340*
020*
020*
010
280*
010
010
010
300*
081*
300*
010
320*
020*
020*
020*
040*
040*
010
060*
060*
010
080*
P
P
P
P
P
P
P
P H
P
P W
P
P W
P W
P W
P
P
P
P
P
P
P
P
P
P W
P W
P
COMPOUND NAME
2»4-XYLENOL
HEXACHLOROBUTADlbNE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROCYCLOPENTADiENE
HEXACHLOROCYCLOPENTADIENE
BROMINE
BROMOFORM
HEXACHLORUETHANE
DICHLOROPROPENES
N-NlTROSOUIPKOPYLAMlNb
BENZIDINE
DICHLOROPROPANES
NITROBENZENE
NITROBENZENE
NIOBIUM (AS NB+3)
PHTMALATE ESTERS (M*:194-279)
PRASEODYMIUM
RUBIDIUM (AS RB+)
SILICON
OI-2-ETHYLHEXVL PHTHALATE
2r 6-DINITROTOLUENE
OI-2-ETHYLHEXYL PHTHALATE
POTASSIUM
BUTYL BENZYL PHTHALATE
2-CHLOROPHENOL
2-CHLOROPHENOL
CHLOROBENZENE
2»4-DICHLOROPH£NOL
2,4-DICHLOROPHENOL
CHLORINE (AS CL-J
PENTACHLOROPHENOL
PENTACHLOROPHENOL
FLUORINE (AS f~)
ISOPHORONE
TYPE CONC
E-6 G/L
T
T
T
T
T
S
T
T
T
T
T
T
T
T
S
T
S
S
S
T
T
T
S
T
T
T
T
T
T
D
T
T
0
T
0
0
1
0
0
2
0
1
0
0
0
0
0
0
2
0
1
4
3
1
0
0
> 1
0
0
0
0
0
0
7
0
.OOE-01
.OOE-01
.30E 05
.OOE-01
.OOE-01
.OOE 01
.OOE-01
.30E 05
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE 00
.OOE-01
.OOE 00
.OOE 01
.OOE 02
.30E 05
.OOE-01
.OOE-01
.OOE 04>
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.80E 04
.OOE-01
O.OOE-01
6.70E 02
1.30E 05
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
us
.OOE-01
.OOE-01
.uob-oi
.OOE-U1
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOb-01
.OOE-01
,UOt-01>
.OOfc-01
.OOfc-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
O.OUE-01
O.OOE-01
MDS
b/S
o.uot-oi
0. OOb-01
o.oot-oi
O.OOE-01
O.OOt-01
O.UOt-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
O.OOE-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
0. OOb-01
O.OOE-01
o.uot-oi
LCCAT
6
2
1
2
2
2
b
b
1
4
5
b
4
6
5
5
b
2
5
6
b
6
-------
GASIFIER ASH SLUICE WATER, ECOLOGY IMPACT
OMEG
02
19
19
07
07
20
20
16
16
20
20
16
48
16
20
20
45
16
16
16
20
20
84
02
39
84
21
21
21
21
21
21
21
A
B
6
B
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
B
B
A
A
A
21 A
NU.
320*
022*
022*
080*
080*
020*
020*
120*
120*
060*
060*
140*
020
160*
101*
101*
010
200*
200*
200*
020*
020*
010
320*
010
010
020*
020*
100*
100*
100*
120*
120*
P
P
P
P
P
P
P
P
P
P
P
P
P
w
M
P
P
P
PH
PH
PH
PH
PH
120* PH
COMPOUND NAME
HEXACHLOROETHANE
CHLORINATED-M-CRESOLS
CHLORINATED-M-CRESOLS
ISOPHORONE
ISOPHORONE
2-NITROPHENOL
2-NITROPHENOL
1,3-DICHLOROBENZENE
1,3-DlCHLOROBENZENE
4-NITROPHENOL
4-NITROPHENOL
1,4-DICHLOROBENZENE
PHOSPHATE, P04 -3
POLYCHLORINATED BENZENES
2r4-DINITROPHENOL
2»4-DINlTROPHENOL
TIN
CHLORONAPHTHALENES
CHLORONAPHTHALENES
CHLORONAPHTHALENES
4»6-DINITRO-0-CRESOL
4,6-DINITRO-O-CRESOL
CERIUM
HEXACHLOROETHANE
GALLIUM
LANTHANUM
NAPHTHALENE
NAPHTHALENE
ACENAPHTHENE
ACENAPHTHENE
ACENAPHTHENE
ACENAPHTHYLENE
ACENAPHTHYLENE
ACENAPHTHYLENE
TYPE COMC
E-6 ti/L
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
D
T
T
T
T
T
S
T
S
S
T
T
T
T
T
T
T
T
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
< l.OOE 02<
O.OOE-01
O.OOE-01
O.OOE-01
3.00E 03
1.30E 05
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
2.0UE 00
O.OOE-01
8.00E 00
< l.OOE 00<
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
US
O.UOE-Ol
O.OOE-01
O.OOE-U1
O.OOE-01
O.OOE-01
U.OOfc-01
O.OOE-01
o.uob-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01<
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01<
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
WD3
U/S
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
o.oob-oi
O.OOE-01
O.OOb-01
O.OOE-01
O.OOb-01
O.OOE-01
O.OOb-01
O.OOt-01
O.OOb-01
O.OOb-01
O.UOE-01
O.OOb-01
o.oot-oi
O.OOb-01
O.OOb-01
O.OOb-01
Q.OOb-01
O.OOb-01
O.OOt-01
o.oot-oi
O.OOb-Ul
o.oot-oi
o.oot-oi
o.oot-oi
O.OOb-01
U.OOE-U1
O.OOE-01
O.OOb-01
o.oot-oi
O.OOt-01
LCCAT
2
b
6
5
6
5
6
2
3
5
6
3
2
5
6
2
3
5
6
1
2
3
2
3
2
3
u>
u>
-------
u>
GASIFIER ASH SLUICE MATER* ECOLOGY IMPACT
DMEG NO.
21 A 140* P
21 A 140* P
17 A 081* P
21 A ISO* P
21 A 160* P
21 A 180* P
21 B 040* P
21 B 040* P
21 6 040* P
21 B 120* P
21 b 120* P
21 6 120* P
21 B 180* P
21 b 180* P
21 B 180* P
21 C 080* P
21 C 080* P
21 C 080* P
21 C 100* P
21 C 100* P
21 C 100* P
21 0 080* PH
21 0 080* PH
21 0 080* PH
22 A 020* PH
22 A 020* PH
22 A 020* PH
22 8 040* P
22 B 040* P
22 B 040* P
22 C 020* P
22 C 020* P
22 C 020* P
22 C 080* P
COMPOUND NAME
ANTHRACENE
ANTHRACENE
2,6-DINITROTOLUENE
PHENANTHRENE
PHENANTHRENE
PHENANTHRENE
BENZ(A)ANTHRACENE
BENZ (A) ANTHRACENE
BENZC A) ANTHRACENE
CHRYSENE
CHRYSENE
CHRYSENE
PYRENE
PYRENE
PYRENE
DIBENZ( A, H) ANTHRACENE
DIbENZC A, H) ANTHRACENE
DIBENZ( A, H) ANTHRACENE
BtNZCKMPYHtNt
BENZO(A)PYRENE
B£NZO(A)PYrttNE
BENZOCtHDPtRYLENE
BENZO(GHI)P£RYLENE
BENZO(GHI)P£RYLENE
FLUORENE
FLUORENE
FLUORENE
FLUORANTHENE
FLUORANTHENE
FLUORANTHENE
BENZO(K)FLUURANTHEN£
6ENZO(K>FLUORANTri€Nfc
BENZU(K)PLUURANTrtENt
BENZO(6;FLUlW?AWTHfcN£
TYPE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
f
T
T
T
T
CONC
E-6 G/L
1.30E 05
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.OOE-01
1.30E 05
O.OOE-01
O.UOE-01
1.30E 05
OS
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-Ul
O.UOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
NDS
li/5
O.OOt-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
o.oot-oi
O.OOfc-01
o.oot-oi
O.OOE-01
o.oofc-oi
o.oot-oi
o.oot-oi
O.OOfc-01
o.oot-oi
o.oot-oi
O.OOE-01
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-01
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
LCCAT
2
5
2
3
2
3
2
3
2
3
2
3
2
3
2
3
2
3
2
3
2
3
-------
DMEG NO.
GA3IFIER ASH SLUICE MATER, ECOLOGY IMPACT
COMPOUND NAME
TYPE CONC
E-6 G/L
US
LCCAT
G/b
22
22
22
22
22
04
04
04
04
04
04
04
04
04
04
04
04
21
04
04
C
C
D
0
D
A
A
A
A
A
A
A
A
A
B
B
B
A
B
B
080* I
080*
020*
020*
020*
140*
140*
140*
160*
160*
160*
180*
180*
180*
020*
020*
020*
140*
040*
040* F
9 BENZU(B)FLUORANTHENE
BENZO(B)FLUORANTHENE
INDENO(1,2,3-CD)PYRENE
INDENO(1,2,3-CD)PYRENE
INDENO(1,2,3-CD)PYR£NE
2-CHLOROETHYL VINYL ETHER
2-CHLOROETHYL VINYL ETHER
2-CHLOROETHYL VINYL ETHER
A-CHLOROBUTYL ETHYL ETHER
A-CHLOROBUTYL ETHYL ETHER
A-CHLOROBUTYL ETHYL ETHER
CHLOROPHENYL PHENYL ETHER
CHLOROPHENYL PHENYL ETHER
CHLOROPHENYL PHENYL ETHER
I'-OICHLOROMETHYL ETHER
t'-OICHLOROMETHYL ETHER
I'-OICHLOROMETHYL ETHER
NTHRACENE
H i'-DICHLOROOIETHYL ETHEK
1 H I'-DICHLORODIETHYL ETHER
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
0
0
1
0
0
1
0
0
1
0
0
1
0
0
1
0
0
0
0
0
.OOE-01
.OOE-01
.30E OS
.OOE-01
.OOE-01
.30E 05
.OOE-01
.OOE-01
.30E OS
.OOE-01
.OOE-01
.30E 05
.OOE-01
.OOE-01
.30E 05
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.
.
.
•
•
•
.
•
•
•
.
.
•
•
.
•
.
•
•
•
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-Ol
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
o.oofc-oi
O.OOb-01
O.OOE-01
2
3
2
3
4
5
4
5
4
5
4
5
3
4
5
U)
Ul
-------
U)
OS
CYCLONE OUST QUENCH WATEH
APPROXIMATE FLO* «ATt « 7.0 (0.007 L/8)
TOTAL OR&ANIC LOADING « 59.9 MC/L
ORGANIC L04DIN6
59500.0
FLOW RATE « 7.00
MINIMUM DISCHARGE SEVERITY « .010
STATE: LIQUID* UNITS IN MICROGRAM8/L
IMPACT: HEALTH
EXPERIMENTALY DETERMINED DATA
SPAHK SUURCE DATA
-------
CYCLONE OUST QUENCH HATER, HEALTH IMPACT
DMEG NO.
16 A 220
21 C 100* P
21 C 080* P
18 8 QUO
18 8 060
18 A 183
18 B 020
18 C QUO
18 A 162
18 C 081
18 C 082
18 C C83
19 A 020* P
16 B 080
18 A 083
19 A 040* P
18 C 080
18 A 102
19 A 060* P
18 A 120
18 A 140
19 B 020
19 B 021
19 b 022* P
18 A 041
18 A 143
19 B 023
20 A 020* P
18 A 146
16 A 160
18 A 062
20 A 060* P
18 A 163
18 A 101
W
W
W
W
W
W
W
W
W
M
W
W
W
M
N
W
W
COMPOUND NAME
POLYCHLURINATED BIPHENYLS
BENZO(A)PYRENE
OIBENZ( A, H) ANTHRACENE
1, 3-OIHYDROXYBENZENE
lr4-DlHYDROXYBENZENE
2r6-OIMETHYL-4-HEPTYL PHENOL
CATECHOL
2-NAPHTHOL
4,6-DI-TERT-BUTYL-M-CRESOL
I-INDANOL
4-INDANOL
5-INOANOL
2-CHLOROPHENOL
1,2,3-TRIHYDROXYBENZENE
P-ETHYLPHENOL
2,4-DICHLOROPHENOL
INUANOLS
P-PHENYLPHENOL
PENTACHLOROPHENOL
2»2'-DIHYDROXYDIPHENYL
XYLENOLS
CHLORINATED CRESOLS
CHLORINATED-0-CRESOLS
CHLORINATED-M-CRESOL8
M-CRE30L
2r5-XYLENOL
CHLORINATED-P-CRESOLS
2-NITROPHENOL
3,4-XYLENOL
ETHYL CRESOLS
M-ETHYLPHENOL
4-NITROPHENOL
2-ETHYL-P-CRESOL
0-PHENYLPHENOL
TYPE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
CONC
E-6 G/L
6.00E 04
6.00E 04
6.00E 04
6. OOE. 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.0UE 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.0UE 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
US
1.20t 07
2.00E 05
4.30E 04
l.
-------
00
DMEG NO.
CYCLONE OUST UUENCH WATER, HEALTH IMPACT
COMPOUND NAME
TYPE CONC OS
E-b G/L
LCCAT
G/S
20 A
20 A
20 A
18 A
18 A
20 A
16 A
18 C
18 A
18 A
18 A
18 A
18 A
20 B
20 B
18 A
16 A
18 A
18 A
16 A
20 A
20 B
16 A
18 A
20 A
20 A
18 A
20 B
16 A
02 A
21 B
04 B
21 0
21 e
060
100
101* P
020* P
141
102
040
020
042
043
060
060
081
041
042
100
160
181
103
145
103
040
142* P
162
040
120
144
020* P
161
360
080
020* P
040
040* P
4
W
w
w
w
tt
w
M
W
W
W
W
¥t
M
W
W
2-AMINO-4,b-DlNITROPHENOL
DINITROPHENOLS
2r 4-DINITNOPHENOL
PHENOL
2f3-XYLENOL
2,5-DINITROPHENOL
CRESOLS
1-NAPHTHOL
0-CRESOL
P-CRESOL
2-METHOXYPHENOL
ETHYLPHENOLS
0-ETHYLPHENOL
3, 5-DINITRO-P-CRESOL
2, 6-DINITRO-P-CRESOL
PHENYLPHENOLS
POLYALKYLPHENULS (MMM35)
2f4,b-TRIM£THYL MtTNYL PHENOL
M-PHENYLPHENOL
3r5-XYLENOL
2»6-OINlTROPH£NOL
DINITRO-P-CHESOL3
2,4-XYLENOL
4-ETHYL-O-CRESOL
3-NITROPHENOL
2r4,b-TRINITROPH€tMOL
2,6-XYLENOL
4,6-DINITRO-O-CRESOL
6-ETHYL-M-CRESOL
HEXACHLOROCYCLOHEXANE
3-METHYLCHOLANTH«£NE
1,1'-DICHLOROM£THYL ETHER
DltJENZO(A,J)PYR£N£
BENZ (A) ANTHRACENE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
b.OOE
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
1
7
.20E
.20E
.20E
• 20E
.20E
.20E
.20E
.20E
• 20E
.20E
.20E
.dOE
.20E
.20E
,20E
.20E
.20E
.20E
.20E
.dot
.20E
.20E
.20t
.20E
.20E
• 20t
.dot
.20E
.OOE
.lot
.93E
9.20E
8.90E
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
03
03
02
01
01
8.33h
6.33E
8.33E
6.33b
6.33t
8.33t
8.33t
6.33E
6.33t
8.33E
8.33t
8.33E
6.33t
6.33t
8.33t
8.33t
8.33E
8*33t
e!33t
8.33t
6.33t
8.33t
6.33E
6.33t
tt.33t
6.33t
6.33E
2. lot
7.43t
5.60t
b.40t
6.2lt
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
U4
04
04
04
04
04
04
04
04
04
04
04
04
04
03
Oi
02
02
-------
CYCLONE DUST QUENCH HATER* HEALTH IMPACT
DMEG NO.
12 A 020* P W
10 C 100
23 C 160 W
02 B 140* P W
10 C 040
10 C 043
10 C 042
10 C 041
12 A 040* P
23 B 100 H
10 C 220
21 B 10B
21 B 103
21 B 100
23 B 240
21 B 109
21 B 10A
21 B 101
21 B 104
21 B 107
21 B 108
21 B 106
21 B 102
21 B 105
23 B 220
06 B 060 W
10 C 082
13 A 100 W
10 C 081
10 C 080
10 C 083
10 C 200
13 A 140
14 B 020 M
COMPOUND NAME
N-NITROSODIMETHYLAMINE
1,4-DIAMINOBENZENE
DIBENZOCC,G)CARBAZOLE
HEXACHLOROCYCLOPENTADIENE
AMINOTOLUENES
4-AMINOTOLUENE
3-AMINOTOLUENE
2-AMINOTOLUENE
N-NITROSODIETHYLAMINE
DIHYDROACRIDINE
2-AMINONAPHTHALENE
ISOPROPYL BENZOCOPHENANTHRENE
2-METHYL BENZOCOPHENANTHRENE
BENZOCOPHENANTHRENE t ALKYL DERIVATIVES
DIBENZ
-------
.p-
o
UMEG NO,
CYCLONE OUST QUENCH WATER* HEALTH IMPACT
COMPOUND NAME
TYPE CONC DS
E-6 G/L
WDS
G/8
LtCAT
22
17
15
OB
10
17
08
08
08
08
21
72
12
17
10
02
17
17
17
17
17
17
17
22
22
21
21
21
21
04
04
04
15
21
C
B
A
C
C
B
A
A
A
A
D
A
B
A
C
A
A
A
A
A
A
A
A
C
D
A
B
B
B
A
A
A
B
B
080* P
040
160
060
140* P
060
123
122
120
121
060
010
020
060
120
160
081* P
083
082
085
086
084* P
080
020* P
020* P
180* P
140
!41
142
060
040
050
060
120* P
W
rt
W
W
M
W
W
W
W
W
W
W
W
W
BENZO(B)FLUURANTHENE
1-CHLORO-2-NITR08ENZENE
BIPHENYL
6-HEXANELACTAM
BENZIDINE
1-CHLORU-4-NITR06ENZENE
STEARIC ACID
PALMITIC ACID
SATURATED LONG CHAIN ACIDS (MNs228-285)
MYRISTIC ACID
DIBENZO(A,L)PYRENE
IKON (AS FE+2)
N-METHYL-M-NITROSOANILINE
4-NITROBIPHENYL
4-AMINOBIPHENYL
DIBROMODICHLOROMETHANE
2,6-DlNjTROTOLUENE
2»3-DINIT«OTOLUENE
3r«-DlNlTKOTOLUENE
2,5-DINITROTOLUENE
3»5-DINITROTOLUENE
2,4-DINITROTOLUENE
DINITROTOLUENES
BENZO(K)FLUORANTHENE
INDENO(1,2,3-CD)PYRENE
PHENANTHRENE
METHYL CHRYSENE3
4-METHVL CHRYSENE
5-METHYL CHRYSENE
1-CHLORO-l,3-EPOXYPKOPANE
2-CHLORO-l,2-EPOXYPROPANE
EPICHLORHYDRIN
«,*»'-DJPHENYLBIPHENirL
CHKYSENE
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
6,
6,
6,
6,
6,
6,
6,
6,
6,
6,
6,
4,
6,
6,
6,
6,
6,
6,
6,
6,
6,
6.
6,
6,
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
,OOE
,OOE
,OOE
.OOE
.OOE
,OUE
,OOE
,OOE
.OOE
,OOE
,OOE
,90E
,OOE
,OOE
,OOE
.OOE
,OOE
,OOE
.OOE
.OOE
,00t
,OOE
,OOE
,OOE
,OOE
OOE
OOE
OOE
OOE
OOE
OOE
OOE
OOE
OOE
04
04
04
04
04
04
04
04
04
04
04
03
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
4,
4,
4,
4,
4,
4,
3,
3,
3.
3,
3,
3.
3,
3,
3,
2,
2,
2,
2,
2,
2,
2,
2.
2,
2.
2.
2.
2.
2.
2.
2.
2.
2.
1.
OOE
,OOE
,OOE
,OOE
.OOE
,OOE
,71E
,7U
,71E
,71E
,71E
,30E
,13E
.OOE
,OOE
,83E
.60E
,60E
,60E
,60E
,60E
,60E
,60E
,50E
bOt
SOE
20E
20E
20E
OOE
OOE
OOE
OOE
dOE
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
»
•
.
.
•
.
•
•
•
.
.
•
.
.
•
.
.
•
20E
80b
80b
80b
80E
tiOt
60b
60b
60b
60E
60b
30b
20b
lOb
lOb
OOb
ttlb
81t
.eiE
.
.
.
•
*
.
•
•
•
•
•
•
ttlb
81b
81b
81b
73b
73t
73E
bah
54E
Sat
40b
40E
1.40E
1.40E
1.30E
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
-------
CYCLONE DUST QUENCH WATER, HEALTH IMPACT
DMEG NO.
12 A 060* P
21 C 160
23 C 020
09 A 120 H
21 C 120
OB A 140
03 B 040 M
03 B 020 W
21 D 020
02 B 120* P
23 0 020 W
23 D 040
08 D 280* P W
08 D 261
08 D 300* P
08 D 263
17 A 020* P
02 A 160* P
16 B 020 *
08 D 282
08 A 103
08 A 101
06 A 104
06 A 100
08 A 102
23 A 103
23 A 101
23 A 102
23 A 100 W
10 A 060
23 C 180
22 C 040
16 B 043
16 B 042
i
H~*
•e>
COMPOUND NAME
N-NITKOSODIPROPYLAMINE
PICENE
PYRROLE
TETRAMETHYLSUCCINONITRILE
BENZO(E)PYRENE
OLfcIC ACID
1,3-DIOXANE
1,4-DIOXANE
DIBENZO(AfH)PYRENE
HEXACHLOROBUTADIENE
BENZOTHIAZOLE
METHYL BENZOTHIAZOLE
PHTHALATE ESTERS (MW|l94-279)
DIMETHYL PHTHALATE
DI-2-ETHYLHEXYL PHTHALATE
DI-N-BUTYL PHTHALATE
NITROBENZENE
BROMOFORM
A-CHLOROTOLUENE
DIETHYL PHTHALATE
CAPRIC ACID
CAPROIC ACID
LAURIC ACID
SATURATED LONG CHAIN ACIDS (MW|ll6-201)
CAPRYLIC ACID
4-CHLOROPYRIDINE
2-CHLOROPYRIDINE
3-CHLOROPYRIDINE
CHLOROPYRIDINES
ETHANOLAMINE
DIBENZO(A,G)CARBAZOLE
8ENZO(J)FLUORANTHENE
1 , 4-BISCCHLOROMETHYL) BENZENE
1,3-BIS(CMLOROMETNYL) BENZENE
TYPE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
CONC
E-6 G/L
6.00E 04
6.00E 04
6.0UE 04
6.00E 04
6.00E 04
6.00E 04
6.03E 04
6.00E 04
6.00E 04
6.0UE 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.0UE 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6. OOt 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.0UE 04
US
1.70E 00
l.bOE 00
l.bOE 00
1..62E UO
1.3UE 00
1.20E 00
1.10E 00
1.10E 00
1.10k 00
9.80E-01
9.30E-01
8.40k-01
7.93E-01
7.93E-01
7.93k-01
7.93E-01
7.93E-01
7.93E-01
7.93E-01
7.93E-01
6.63E-01
6.83E-01
6.63E-01
6.83E-01
6.63E-01
6.60k-01
6.ttOE-01
6.80E-01
6.60E-01
6.01E-01
6.61E-01
6.10E-01
6.00E-01
6.00E-01
Wl)b LCCAT
G/S
1.20k 01
1.10k 01
1.01k 01
9.30k 00
9.10k 00
8.32k 00
7.71k 00
7.71k 00
7.43E 00
6.82E 00
6.50k 00
5.90k 00
5.60k 00
5.60k 00
5.60k 00
5.60k 00
5.60k 00
5. 60k 00
5,60k 00
5,60k 00
4.60k 00
4,bOk 00
4.80E 00
4.60E 00
4.80E 00
4.73E 00
4.73E 00
4.73E 00
4.73E 00
4.62k 00
4.62k 00
4.24E 00
4.20k 00
4.20k 00
-------
CYCLONE OUST QUENCH MATER, HEALTH IMPACT
DME
16
16
49
15
15
15
15
02
21
06
4b
23
04
04
02
23
02
02
07
23
16
16
16
06
26
23
23
21
23
23
34
23
23
23
:G
B
B
A
B
B
B
B
A
C
A
A
B
B
A
B
C
B
B
B
C
A
A
A
D
A
A
B
C
B
b
A
A
A
A
NO.
041
040
010 P
163
162
160
161
320* P
060
020 W
010 P
200
100
140* P
104
040
103
100* P
100 W
140
160* P
162
161
060
010
020
021
040
022
020
010
145
143
HI
COMPOUND NAME
1,2-BISCCHLOROMETHYBENZENE
BIS (CHLOROMETHYL) BENZENES
ARSENIC
P-TERPHENYL
M-TERPHENYL
TERPHENYLS
0-TERPHENYL
HEXACHLOROETHANE
0 I BENZC A, C) ANTHRACENE
ETHYLENE GLYCOL
LEAD
BENZ(C)ACRIUINE
2,2'-DICHLORODIISUPKOHYL ETHER
2-CHLOROETHYL VINYL ETHER
TRANS-1 , 3-DICHLOHOPROPENE
INDOLE
CIS-1,3-DICHLOROPROPEN£
DICHLOROPROPENES
CAMPHOR
DIbEMZO(A,I)CARBAZOLE
POLYCHLORINATED BENZENES
HEXACHLOROBENZENE
1,2,4-TRICHLOROBENZENE
METHYL METHACRYLATE
SODIUM
PYRIDINE
OUINOLINE
BENZO(G)CHRYSENE
ISOQUINOLINE
QUINOLINES
CALCIUM (AS CA+2)
3,4-DlMETHYLPYRIDlNfc
2,5-DIMETHYLPYRlOJNE
2,3-DlMETHN.PyRJDINE
TYPE CONC
E-6 G/L
T
T
D
T
T
T
T
T
T
T
D
T
T
1
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
D
T
T
T
6
6
1
6
6
6
6
6
6
6
9
6
0
6
6
6
6
6
6
6
6
6
6
6
2
6
6
6
6
6
5
.out
.out
.20E
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.90E
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.20E
.OOE
.OOE
.OOE
.OOE
.OOE
.40E
6.00E
6.00E
6.00E
04
04
02
04
04
04
Oil
04
04
04
01
04
04
04
04
04
Qtt
04
04
04
04
04
04
04
OS
04
04
04
04
04
04
04
04
04
6
6
4
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
2
2
2
2
2
us
.OOE-01
.OOE-01
.oot-o i
.30E-01
.30E-01
.30E-01
.30E-01
.OOE-01
.OOE-01
.OOE-01
.OOE-01
.71E-01
.71E-01
.50E-01
.bOE-01
.50E-01
.bOE-01
.bOE-01
.30E-01
.30E.-01
.30fc-01
.30E-U1
.30t-Ul
.B3E-01
.BOE-01
.OOE-01
.50E-01
.bOE-01
.bOE-01
.bOE-01
.30E-01
.20E-01
2.20E-01
2.20E-01
WDS
G/5
4.20E
4.20b
3.40t
3.00t
i.OOt
3. OOE
3. OOE
2.60E
2. BOb
2.BOb
2.60b
2.60E
2.60E
2.44b
2.4ab
2.44b
2.44b
2.4Ub
2.31E
2.31b
2.31b
2.31b
2.31t
2.00b
1 . V2E
l.eit
1.73b
1.73E
1.73b
1.73b
1.60E
1.54E
1.54E
1.54E
LCCAT
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
-------
CYCLONE OUST QUENCH WATER, HEALTH IMPACT
OMEG NO.
COMPOUND NAME
TYPE CONC
E-6 G/L
ND3
G/8
LCCAT
23 A 142 2r4-OIMETHYLPYRIDlNE
05 B 100 N 1-PHENYLETHANOL
23 A 144 2,6-DIMETHYLPYRIDINE
23 A 140 DISUBSTITUTEO POLYSUBSTITUTEU ALKYL PYRIDINES
23 A 146 2,3,4,6-TETRAMETHYL PYRIDINE
23 C 120 BENZGCAKARBAZOLE
10 C 020 ANILINE
09 A 100 1,3-DICYANO-l-HYDROXYbUTANE
09 A 080 BUTYRONITRILE
102 9-METMYLCARBAZOLE
042 3-METHYLTHIOPHENE
040 METHYLTHIOPHENES
101 3-HETHYLCARBAZOLE
041 2-METHYLTHIOPHENE
080 VALERIC ACID
100 METHYLCARBAZOLES
040 W BENZO(B)THIOPHENE
260 DIBENZ(C,H)ACRIDINE
080 CARBAZOLE
080 1,2-DIAMINOETHANE
066 3'5-XYLIDINE
040 ACETIC ACID
065 3»4-XYLIDINE
020 W N,N-DIMETHYLANILINE
061 2,3-XYLlDINE
063 2»5*XYLIDINE
064 2»6-XYLIDINE
080* P I80PHORONE
062 2»4-XYLlDINE
060 DIMETHYLANILINES
064 3»4-DIMETHYLTHIOPHENE
063 2»5-DlMETHYLTHIOPH£NE
060 DIMETHYLTHIOPMENE8
062 2,4-DIMETHYLTHlOPHENE
A
A
23 C
25 A
25 A
23 C
25 A
OB A
23 C
25 B
23 B
23 C
10
10
08
10
10 D
10
10
10
07 B
10 C
10 C
25 A
25 A
25 A
25 A
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
6.00E 04 2.20E-01 1.54E 00
6.00E 04 2.20E-01
6.00E 04 2.20E-01
6.00E 04 2.20E-01
6.00E 04 2.20E-01
6.00E 04 2.12E-01
6.00E 04 2. 106.- 01
6.00E 04 1.80E-01
6.00E 04 1.80E-01
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.0UE 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.0UE 04
6.00E 04
6.00E 04
6.0UE 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.0UE 04
6.00E 04
6.00E 04
.tiOE-01
.ttOE-01
.ttOE-01
.80E-01
.80E-01
.00E-01
.BOE-01
.70E-01
.70E-01
.70E-01
•60E-01
.60E-01
.60E-01
.60E-01
.60E-01
.6UE-01
.60E-01
.60E-01
.60E-01
.54E 00
.54E 00
.54E 00
.54E 00
.SOE 00
.43E 00
.30E 00
.30E 00
.22E 00
.22E 00
.22E 00
.22E 00
.22E 00
.22E 00
.22E 00
.20E 00
.20E 00
.20t 00
.10E 00
.10E 00
.106. 00
.10E 00
.10E 00
.lot oo
.I0b 00
.10E 00
.lot oo
.60E-01 1.10E 00
.60E-01 1.10E 00
.b£E-01 1.10E 00
.52E-01 l.lOt 00
.52E*01 1.10E 00
.S2E-01 l.lOt 00
7
-------
CYCLONE DUST QUENCH WATER, HEALTH IMPACT
L)MtG
25
04
04
3B
25
25
04
17
01
04
17
OB
17
17
08
33
09
09
09
09
27
54
36
23
23
23
10
10
26
06
10
10
12
82
A
A
A
A
A
A
B
A
B
B
A
C
A
A
A
A
B
B
B
B
A
A
A
A
A
A
A
A
A
B
A
A
A
A
NO.
061
200
180* P
010
OBI
OBO
OBO
042
220 W
04Q* P
043
020
040
041
060
010
042
040 W
041
020 ri
010
010 P
010
043
042
041
120
122
020 W
OBO
121
123
060
010 P
COMPOUND NAME
2,3-DIMETHYLTHIOPHENE
4-BROMOPHENYL PHENYL ETHER
CHLOROPHENYL PHENYL ETHER
ALUMINUM
2,3,5-TRIMETHYLTHlOPHENE
TRIMETHYL AND TETHAMETHYL THIOPHENES
2»2'-DICHLORODIETHYL ETHER
3-NITROTOLUENE
DICYCLOPENTAOIENE
1,1'-OICHLORODIETHYL ETHER
4-NITROTOLUENE
FORMAM1DE
NITROTOLUENES
2-NITROTOLUENE
MALEIC ACID
MAGNESIUM
B-NAPHTHONITRILES
NAPHTHONITRILES
A-NAPHTHONITRILES
BENZONITRILE
LITHIUM
SELENIUM
BARIUM
4-METHYLPYRIDINE
3-METHYLPYRIDINE
2-METHYLPYRIDINE
PROPANOLAMINES
3-AMINO-l-PROPANOL
TRIETHYL PHOSPHATE
Y-BUTYROLACTONE
2-AMINO-1-PROPANOL
1-AMINO-2-PROPANOL
N-NITKOSODJISOPROPYLAMJNE
CADMIUM
TYPE tONC
E-6 G/L
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
S
S
D
T
T
T
T
T
T
T
T
T
T
0
6
6
6
1
6
6
6
6
6
6
6
6
6
6
6
1
6
6
6
6
4
6
5
6
6
6
6
6
6
6
6
6
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
*
•
•
•
•
•
•
•
•
•
6.
OOE
OOE
OOE
10E
OOE
OOb
OOE
OOE
OOE
OOE
OOE
OOE
OOE
OOE
OOE
10E
OOE
OOE
OOE
OOE
OOE
OOE
70E
OOE
OOE
OOE
OOE
OOE
OOE
OOE
OOE
OOE
OOE
< 5. OOE
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
01
00
02
04
04
04
04
04
04
04
04
04
04
00<
DS
1.52E-01
l.SOt-01
1.50E-01
1.40t-01
1.40E-01
1.40E-01
1.42E-01
1.32E-01
1.32E-01
1.32E-01
1.32E-01
1.32E-01
1.32E-01
1.32E-01
1.23E-01
1.22E-01
1.21t-01
1.21E-01
1.21E-01
1.21E-01
1.21E-01
1.20E-01
1.14E-01
1.12E-01
1.12E-01
1.12E-01
1.10E-01
1.10E-01
1.10E-01
1.10E-01
1.10E-01
1.10E-01
1.04E-01
1.00E-01<
1.
1.
1.
9.
9.
9.
9.
9.
9.
9.
9.
9.
9.
9.
8.
B.
8.
8.
8.
8.
B.
8.
6.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
HDS LCCAT
b/S
lOb 00
OIL oo
Olt 00
b2t-01
50t-01
,50t-01
.30E-01
30L-01
,30t-01
^Ot-Ol
,30t-01
,30E-01
,30E-01
,30E-01
JOE-01
.60E-U1
,bOt-01
,50E-01
,50t-01
.50E-U1
,50t-01
,40t-01
(OOE-01
90t-01
90E-01
90E-01
71E-01
71E-01
71E-01
71E-01
71E-01
71E-01
30E-01
OOE-01
-------
OMEG NO.
CYCLONE DUST QUENCH HATER, HEALTH IMPACT
COMPOUND NAME TYPE
CONC US
E-6 G/L
LCCAT
08 B 041
14 A 020 M
10 A 160
07 B 120
23 C 060
02 A 140* P
23 C 062
23 C 061
05 C 040 W
22 A 010 H
76 A 010 P
21 A 020* P
23 B 062
23 B 060
23 B 061
23 B 064
23 B 065
23 B 067
23 B 040
05 A 140 W
23 B 063
23 B 066
21 A 140* P
02 A 361
02 A 360
07 A 140
08 D 160
16 A 200* P
23 A 062
23 A 083
16 A 201
23 A 064
23 A 060
23 A 120
2-HYDROXYBENZOIC ACID
BENZENESULFONIC ACID
CYCLOHEXYLAMINE
ACETOPHENONE
METHYLINDOLES
DIBROMOCHLOROMETHANE
3-METHYLINOOLE
2-METHYLINDOLE
T-PENTANOL
INDENE
NICKEL
NAPHTHALENE
2,6-DIMETHYLQUINOLINE
DIMETHYLQUINOLINE3
2, 3-DIMETHYLQU INCLINE
3,4-DIMETHYLQUINOLINE
6,8-DIMETHYLQUINOLINE
1,5-DIMETHYLISOQUINOLINE
2-METHYLQUINOLINE
BENZYL ALCOHOL
2,8-DIMETHYLQUINOLINE
1,3-DIMETHYLISOQUlNOLlNt
ANTHRACENE
1-BROMOBUTANE
BROMOBUTANES
BENZALDEHYDE
METHYL BENZOATE
CHLORONAPHTHALENES
3-PHENYLPYRIDINE
4-PHENYLPYRIDINE
1-CHLORONAPHTHALENE
4-N-PROPYLPYRIDINE
PHENYLPYRIDINES
COLLIDINES
T
T
T
T
T
T
T
T
T
T
0
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
6.00E 04
6.00E 04
6.00E 04
b.OOE 04
b.OOE 04
6.0UE 04
6.00E 04
b.OOE 04
6. OUE 04
b.OOE 04
< 2.00E OK
6.00E 04
6.00E 04
6.00E 04
b.OOE 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
b.OOE 04
b.OOE 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
b.OOE 04
6.00E 04
6.00E 04
6.00E 04
6. OUE 04
b.OOE 04
6.00E 04
9.V1E-02
9.91E-02
9.91E-02
9.80E-02
8.74E-02
8.74t-02
8.74t-02
8.74O02
8.74E-02
8.74E-02
8.70E-02<
7.93E-02
7.20E-02
7.20E-02
7.20E-02
7.20E-02
7.20E-02
7.20E-02
7.20E-02
7.20E-02
7.20E-02
7.20E-02
7.10E-02
7.00E-02
7.00E-02
6.80E-02
6.b3E-02
6.00E-02
6.00E-02
6.00E-02
6.00E-02
6.00E-02
6.00E-02
6.00E-02
6.94E-01
6.94E-U1
6.94E-01
6.62E-01
6.12E-01
6.12E-01
6.12E-01
6.12E-01
6.12E-01
6.12L-U1
6.10E-01
S.bOt-Ul
5.01E-01
S.Olt-01
5.01E-01
5.01E-01
5.01E-01
5.0U-01
5.01E-01
5.0U-01
5.01E-01
b.Olt-01
5.00E-01
4.90E-01
4.90E-01
4.73fc-01
4.60E-01
4.20E-01
4.20E-01
4.20t-01
4.20t-01
4.20t-01
4.20E-01
4.20L-01
i
M
.e-
Ln
-------
I
h-1
.p-
CYCLONE OUST QUENCH WATER, HEALTH IMPACT
DMEG NO.
10 B 100
16 A 202
23 060
23 062
23 063
23 122
23 081
23 121
23 A 061
08 0 200
07 8 181
07 b 180
07 B 182
56 A 010
12 A 100
05 A 160
23 b 160
22 B 040* P M
23 B 140
23 B 120
13 8 080
13 B 060
05 B 120
23 B 080
83 A 010 P
15 A 142
15 A 141
15 A 143
15 A 140
15 B 203
15 B 200
15 B 180
15 B 182
15 8 202
COMPOUND NAME
MORPHOLINE
2-CHLORONAPHTHALENE
MONOSUBSTITUTED ALKYL PYRIOINES
3-ETHYLPYRIOINE
4-ETHYLPYRIDINE
2/4,6-COLLIDINE
2-PHENYLPYRIOINE
5-ETHYL-2-METHYLPYRIDINE
2-tTHYLPYRlDlNE
OltTHYL AOIPATE
CARVONE(f) 0« L)
CARVONES
DIHYDRO-(L) OR DCARVQNE
FLUORINE (AS F-)
N-NITROSOOIPENTYLAHINE
PHENETHYL ALCOHOL
BENZO(H)QUINOLINE
FLUORANTHENE
BENZO(F)QUINULINE
PHENANTHRIDINE
METHYL DISULFIDE
DIPHENYL SULFIDE
BURNEOL
ACRIDINE
MERCURY
SEC-BUTYL BENZENE
N-BUTYL BENZENE
TERT-8UTYL BENZENE
BUTYL BENZENES
1,2,4,5-TETRAMETHYLBENZENE
TETRAMETHYLBENZENES
TKIMETHYL8ENZENES
l,2,4-TRJMETHYLfl£NZENE
1 , 2, 3, 5-TETKAMET»trLBENZEN£
TYP
T
T
T
T
T
T
T
T
T
T
T
T
T
0
T
T
T
T
T
T
T
T
T
T
0
T
T
T
T
T
T
T
T
T
E CONC
E-6 G/L
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.0UE 04
2.00E 03
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
4.00E-01
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
us
6.00E-02
6.00E-02
6.00E-02
6.00E-02
6.00E-02
6.00E-02
6.00E-02
6.00E-02
6.00E-02
5.40E-02
5.40E-02
5.40E-02
5.40E-02
5.30E-02
5.00E-02
5.00E-02
4.30E-02
4.30E-02
4.30E-02
4.30E-U2
4.30E-02
4.30E-02
4.30E-02
4.30E-02
4.00E-02
4.00E-02
4.00E-02
4.00E-02
4.00E-02
3.30E-02
3.30E-02
3.30E-02
3.30E-02
3.30E-02
WOS LCCAT
ti/S
4.20E-01
4.20E-01
4.20t-01
4.20t-01
4.20E-01
4.20E-01
4.20t-01
4.20t-01
4.20E-01
3.ttOt-01
3.60t-01
3.60E-01
3.60E-01
3.70E-01
3.50E-01
3.50t-01
3.00t-Ul
3.00E-01
3.00E-01
3.00E-U1
3.00E-01
3.00t-0l
3.00E-01
3.00E-01
2,«0t-01
2.60E-01
2,aot-oi
2.80E-01
2.ttOt-01
2.3U-01
2.ilt-01
2.31E-01
2.3lfc-01
2.3U-01
-------
CYCLONE DUST QUENCH MAUR* HEALTH IMPACT
DHEG NO.
COMPOUND NAME
TYPE CONC DS
E-6 G/L
LCCAT
15 B 181
15 B 183
15 B 201
15 B 142
15 B 140
03 B 060
15 6 141
26 B 040 W
15 B 120
08 D 320* P
08 160
14 044
14 043
14 041
48 010
57 A 010
06 B 020 W
05 A 100
05 A 080
03 A 040 W
05 B 080
08 A 180
35 A 010
37 A 010
05 C 060
68 A 010 P
17 B 020
17 B 022
17 B 021
17 B 023
21 A 081
21 A 044
21 A 043
21 A 083
i
i_ j
P^
.0
i,2.3-TRIMETHYLBENZENE
1,3,5-TRIMETHYLBENZENE
1,2,3,4-TETRAMETHYLBENZENE
1,4-DJHYDRONAPHTHALENE
DIHYDRONAPHTHALENES
2-ETHYL-4-METHYL-l,3-OIOXOLANE
1,2-DIHYDRONAPHTHALENE
TRITOTYL PHOSPHATES
TETRAHYDRONAPHTHALENE
BUTYL BENZYL PHTHALATE
BENZOIC ACID
9, 10-ANTHRAQUINONE-1, 8-DISULFONIC ACID
9»10-ANTHRAQUINONE-1,7-DI8ULFONIC ACID
9, 10-ANTHRAQUINONE-1,5-DISULFONIC ACID
PHOSPHORUS
CHLORINE (AS CL-)
2»3-EPOXY-l-PROPANOL
ISOBUTYL ALCOHOL
N-BUTANOL
3-METHOXYBIPHENYL
2r6-DIM£THYL-4-MEPTANOL
ADIPIC ACID
STRONTIUM
BORON
A-TERPINEOL
CHROMIUM
METHOXYNITROBENZENES
l-METHOXY-3-NITROBENZENE
1-METHOXY-2-NITROBENZENE
l-METHOXY-4-NITROBENZENE
1,4-DIMETHYLNAPHTHALENE
2-ETHYLNAPHTHALENE
l-ETHYLNAPHTHALENE
2r6-DIMETHYLNAPHTHALEN£
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
D
T
T
T
T
T
T
D
0
T
D
T
T
T
T
T
T
T
T
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
4. OOE 02
3.40E 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
6. OOE 04
1.10E 03
9.90E 02
6. OOE 04
< 5. OOE 00<
6. OOE 04
6. OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
.OOE 04
3.JOE-02
3.30E-02
3.30E-U2
3.13E-02
3.13E-02
3.13E-02
3.13E-02
3.00E-02
3.00E-U2
2.63E-02
2.BJE-02
2.70E-02
2.70E-02
2.70E-02
2.70E-02
2.61E-02
2.60E-02
2.60E-02
2.60E-02
2.50E-02
2.50E-02
2.50E-02
2.40E-02
2.10E-02
2.10E-02
2.00E-02<
1.90E-02
1.90E-02
1.90E-02
1.90E-02
1.80E-02
1.80E-02
l.bOE-02
1.80E-02
2.3U-01
2.3U-01
2.31E-01
2.20E-01
2.20E-01
2.20L-01
2.20E-01
2.10E-01
2.10E-01
2.00E-01
2.00E-01
1.90L-U1
1.90E-01
.90E-U1
,90t-0 1
.83E-01
.ttlt-01
.81t»01
.ttlt-01
.73E-01
.73E-01
.73E-01
.70E-01
l.bOb-01
1.43t-Ul
.40E-01
.30E-01
.30E-01
.30t-01
.30E-01
1.22E-01
1.22E-U1
1.22t-01
1.22E-01
-------
I
I-"
CD
DMEG NO.
CYCLONE DUST UUENCH WATER, MtALTH IMPACT
COMPOUND NAME
TYPE CONC
E-6 G/L
US
LCCAT
G/S
15
21
21
21
21
21
21
15
15
08
16
26
43
16
16
74
02
01
02
01
16
05
05
05
05
05
05
05
05
OS
15
16
16
16
9
A
A
A
A
A
B
A
A
D
A
B
A
A
A
A
A
A
A
A
A
B
A
A
A
B
A
B
A
B
A
A
A
A
020
040
042
080
041
082
180* P
120
100
240
180
020
010
100* P
120* P
010
340* P
201
343
200 W
020* P
062
123
124
121
061
120
063
122
060
040* P
063
060
062
INDAN
MONOALKYL NAPHTHALENES
2-MtTHYLNAPHTHALENE
DIMETHYLNAPHTHALENES
1-METHYLNAPHTHALENE
2, 3-DIMETHYLNAPHTHALENE
PYRENE
ISOPROPYL BENZENE
PROPYL BENZENE
DI-P-ETHYLBUTYL ADIPATE
2-CHLOROTOLUENE
TKIPHENYL PHOSPHATE
SILICON
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZEN£
COBALT
DICHLOROPROPANES
N-OCTANE
lr 3-DICHLORUPROPANE
OCTANES
CHLOROBENZENE
3-PENTANOL
2, 2-DI METHYL- 1-PROPANUL
3-METHYL-l-BUTANOL
N-PENTANOL
2-PENTANOL
PENTANOLS (PRIMARY)
3-METHYL-2-BUTANOL
2-METHYL-l-BUTANOL
PENTANOLS (SECONDARY)
TOLUENE
1-BKOMO-4-CHLGR06ENZENE
BROMOCHLORObENZeNES
l-bROMO-3-CHLOROeENZENE
T
T
T
T
T
T
T
T
T
T
T
T
S
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E.
6. OOt
6.00E
6.00E
2.00E
6.00E
6. Out
9.0UE
6.00E
6.00E
6. OOt
6.00E
6. OOt
6. OOt
6.00E
6.00E
6.00E
6.00E
6. OOt
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.0UE
04
04
04
04
04
04
04
04
04
04
04
04
03
04
04
00
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
00
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.bOE-02
.80E-U2
.60E-02
.&OE-02
.80E-02
.bOfc-02
.70E-02
.60E-U2
.60E-02
.60E-02
.60E-02
.40E-02
.33E-02
.32E-02
.32E-02
.20E-02
.12E-02
.12E-02
.12E-02
.12E-02
.12E-02
.10E-02
.10E-02
.10E-02
.10E-02
.10E-02
.10E-U2
.10E-02
.10E-02
.10E-02
.10E-02
.OOE-02
.OOE-02
.OOE-02
1
1
1
1
1
1
9
9
9
9
8
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7,
*
%
•
*
•
9
•
t
•
•
*
•
•
•
•
•
*
9
•
,
•
•
•
•
*
•
•
•
*
*
*
•
•
»
22E-01
22t-o i
22H-01
22E-01
22t-01
22t-01
20t-01
1 1E-01
llh-01
lOE-01
10t-01
70E-02
33t-02
30t-02
30t-02
40E-02
90L-02
90t-U<>
90E-02
90t-02
90E-02
7U-02
7U-02
71E-02
71E-02
71&-02
7lt-02
71t-02
71E-02
71E-02
43E-02
10E-02
10E-02
IOE-02
-------
CYCLONE DUST QUENCH WATER, HEALTH IMPACT
DMEG NO.
COMPOUND NAME
TYPE
CONC
E-6 G/L
hDS
li/S
LCCAT
16 4 061
15 A 060* P
16 A 140* P
79 A 010 P
65 A 010
02 B 080* P
71 A 010 P
78 A 010 P
62 A 010
81 A 010 P
44 A 010
39 A 010
61 A 010
63 A 010
69 A 010
30 A 010
84 B 010
31 A 010
04 A 160* P
04 A 180* P
58 A 010
04 A 180* P
21 A 020* P
19 A 060* P
02 B 140* P
45 A 010
21 B 040* P
04 A 140* P
18 A 142* P
08 0 280* P I
02 B 120* P
17 A 084* P
53 A 010
21 A 100* PH
l-BROMO-2-CHLOROHENZENE
ETHYL BENZENE
1,4-DICHLOROBENZENE
SILVER
VANADIUM
TETRACHLOMOETHENE
MANGANESE
COPPER
TITANIUM
ZINC
GERMANIUM
GALLIUM
YTTRIUM (AS Y+3)
ZIRCONIUM (AS ZR + 4)
MOLYBDENUM
RUBIDIUM (AS RB+)
CERIUM
CESIUM
A-CHLOROBUTYL ETHYL ETHER
CHLOROPHENYL PHENYL ETHER
BROMINE
CHLOROPHENYL PHENYL ETHER
NAPHTHALENE
PENTACHLOROPHENOL
HEXACHLOROCYCLOPENTADIENE
TIN
BENZ(A)ANTHRACENE
2-CHLOROETHYL VINYL ETHER
2'4-XYLENOL
PHTHALATE ESTERS (MW|194-279)
HEXACHLOROBUTADIENE
2,4-DlNlTHOTOLUENE
SULFUR
ACENAPHTHENE
T 6.0UE 04 l.OOE-02 7.10E-02
T 6.00E 04 9.<>0t-03 6.4QE-02
T 6.00E 04 8.74E-U3 6.12E-02
8 2.00E 00 8.UOE-U3 5.60t-02
D 1.50E 01 6.00L-03 4.20t-02
T 6.00E 04 5.94E-03 4.20E-02
D < l.OOE 00< 4.00E-03< 2.60t-02
D 1.2UE 01 2.40E-03 1.70E-02
D 1.80E 02 2.UOE-U3 1.40E-U2
D 3.50E 01 1.4UE-03 9.80E-03
S 7.0UE 00 8.33E-04 5.tt3t-03
S 2.00E 01 2.70E-04 1.9QE-03
S 2.00E 00 1.33E-04 9.33E-04
S 5.00E 00 6.70E-05 4.70E-04
S 4.0UE 00 5.33E-05 3.73t»04
S 2.00E 01 1.11E-05 7.80E-05
8 2.0UE 00 3.63E-06 2.54E-05
S 4.00E 00 3.33E-06 2.33t»05
T O.OOE-01 O.OOE-U1 O.OOt-01
T O.OOE-01 O.OOE-01 O.OOE-01
S 4.0UE 01 O.UOE-U1 O.OOE-01
T O.OOE-01 O.OOE-01 O.OOE-01
T O.OOE-01 O.UOE-01 O.OOE-01
T O.OOE-01 O.OOE-01 O.OOE-01
T O.OOE-01 O.OOE-01 O.OOt-01
D 2.90E 03 O.OOE-01 O.OOt-01
T O.OOE-01 O.OOE-01 O.OOE-01
T O.OOE-01 O.OOE-01 O.OOt-01
T O.OOE-01 O.OOE-01 O.OOE-01
T O.OOE-01 O.OOE-01 O.OOt-01
T O.OOE-01 O.OOE-01 O.OOt-01
T O.OOE-01 O.OOE-01 O.OOE-01
D 2.30E 04 O.OOE-01 O.OOt-01
T O.OOE-01 O.OOt-01 O.OOE-01
4
5
4
3
S
1
2
5
5
5
2
4
-------
Ul
o
CYCLONE OUST UUENCH WATER, HEALTH IMPACT
OMEG NU.
08 0 300* P
17 A 081* P
21 A 120* PH
OU B 020* P W
21 C 080* P
02 A 320* P
02 B 080* P
21 A 180* P W
16 A 200* P
02 B 140* P W
16 A 020* P W
06 0 300* P
17 A 081* P
08 D 280* P W
02 8 120* P
21 8 180* P
21 B 180* P
17 A 084* P
59 A 010
17 A 020* P
21 A 020* P
22 B 040* P W
21 A 100* PH
04 A 160* P
22 C 020* P
22 C 020* P
21 B 120* P
21 B 120* P
22 C 080* P W
22 C 080* P W
22 B 04Q* P W
08 D 320* P
22 D 020* P W
10 C 140* P
COMPOUND NAME
D1-2-ETHYLHEXYL PHTHALATE
2r6-DINITROTOLUENE
ACENAPHTHYLENE
1,1'-OICHLOROMETHYL ETHtR
DIBENZ(A,H) ANTHRACENE
HEXACHLORUETHANE
TETRACHLOROETHENE
PHENANTHRENE
CHLORONAPHTHALENES
HEXACHLOROCYCLOPENTADIENE
PHENOL
DI-2-ETHYLHEXYL PHTHALATE
2,6-DINITROTOLUENE
PHTHALATE ESTERS (MW:194-279)
HEXACHLORObUTAOIENE
PYRENE
PYRENE
2,4-DINITROTOLUENE
IODINE (AS I-)
NITROBENZENE
NAPHTHALENE
FLUORANTHENE
ACENAPHTHENE
A-CHLOROBUTYL ETHYL ETHER
BENZO(K)FLUORANTHENE
BENZO(K)FLUORANTHENE
CHRYSENE
CHHYSENE
BENZO(B) FLUOR ANTHENE
BENZO(6)FLUORANTHENt
FLUORANTHENE
BUTYL BENZYL PHTHALATE
INOENO(1,2,3-CD)HYREN£
BE.NZIDINE
TYPI
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
: CONC
E-6 G/L
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OUE-01
O.OOE-01
O.OOE-01
O.OOE-01
6.00E 00
O.OOE-01
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
US
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
0.00t-0l
O.OOE-01
o.oot-oi
O.OOE-01
o.uot-oi
o.oot-oi
o.ooE-oi
o.oot-oi
O.UOE-01
o.ooE-oi
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-U1
O.OOfc-01
O.OOh-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
NUS
b/S
o.oot-oi
o.oot-oi
O.OOE-01
o.oot-oi
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOt-Ul
O.UOE-01
O.OOE-01
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
O.OOfc-Ul
O.OOt-01
O.OOb-01
o.oot-oi
o.oot-oi
O.OOE-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.OOE-01
O.OOE-01
o.oot-oi
o.oot-oi
O.OOfc-01
O.OOE-01
O.OOE-01
O.UOt-01
LCCAT
5
4
3
5
3
2
1
d
2
2
5
6
S
b
1
2
5
5>
4
2
2
b
2
3
2
3
2
3
3
6
3
6
-------
CYCLONE DUST QUENCH MATER, HEALTH IMPACT
DMEG NO.
02 B 060* P
21 A 120* PH
02 B 100* P
17 A 020* P
12 A 020* P M
12 A 020* P W
29 A 010
12 A oao* P
12 A 040* P
16 A 200* P
12 A 060* P
12 A 060* P
21 B 040* P
10 C 140* P
22 0 020* P N
21 0 060* PH
02 A 140* P
02 A 140* P
04 A 140* P
02 A 160* P
19 A 020* P H
19 A 020* P W
04 A 160* P
19 A 040* P W
19 A 040* P W
15 A 040* P
IS A 040* P
19 A 060* P W
15 A 060* P
15 A 060* P
08 D 320* P
19 B 022* P
19 B 022* P
04 B 040* P
CUHPOUNO NAME
TETRACHLOROETHENE
ACENAPHTHYLENE
DICHLOROPROPENES
NITROBENZENE
N-NITROSODIMETHYLAMINE
N-NITROSODIMETHYLAMINE
POTASSIUM
N-NITROSOOIETHYLAMINE
N-NITROSODIETHYLAMINE
CHLORONAPHTHALENES
N-NITROSOOIPROPYLAMINE
N-NITROSODIPROPYLAMINE
BENZ(A)ANTHRACENE
BENZIDINE
INDENO(1,2,3-CD)PYRENE
BENZO(GHI)PERYLENE
DIBROHOCHLOROMETHANE
DIBROMOCHLOROHETHANE
2-CHLOROETHYL VINYL ETHER
BROMOFORH
2-CHLOROPHENOL
2-CHLOROPHENOL
A-CHLOROBUTYL ETHYL ETHER
2r4-DICHLOROPHENUL
2,4-DICHLOROPHENOL
TOLUENE
TOLUENE
PENTACHLOROPHENOL
ETHYL BENZENE
ETHYL BENZENE
BUTYL BENZYL PHTHALATE
CHLORJNATED-H-CRE80LS
CHLORINATEO-M-CRE80L8
1,1'-DICHLORODIETHVL ETHER
TYPE
T
T
T
T
T
T
8 >
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
CONC
E-6 G/L
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
1.0UE 04>
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
6.00E 04
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
US
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01>
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-U1
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
MD8
G/S
O.OOE-01
O.OOt-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
o.oot-oi
O.OOE-01
O.OOt-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOt-01
o.oot-oi
O.OOE-01
o.oot-oi
LCCAT
2
1
5
5
6
5
6
3
5
6
3
5
2
3
1
2
4
1
5
6
5
6
2
3
6
2
3
5
5
6
4
ft]
H
l/i
-------
I
M
Ul
CYCLONE DUST QUENCH WATER, HEALTH IMPACT
DMfcG NO.
04 B 040* P
20 A 020* P W
20 A 020* P W
02 b 100* P
21 C 080* P
20 A 060* P W
20 A 060* P W
21 C 100* P w
21 C 100* P W
21 A 180* P M
20 A 101* P
20 A 101* P
18 A 020* P W
04 B 020* P W
21 0 060* PH
21 D 080* PH
20 B 020* P W
20 B 020* P W
22 A 020* PH
22 A 020* PH
22 A 020* PH
02 A 160* P
16 A 020* P
16 A 020* P
02 A 320* P
07 B 080* P
07 B 080* P
02 A 340* P
02 A 340* P
16 A 100* P
16 A 100* P
18 A 142* P
16 A 120* P
16 A 120* P
COMPOUND NAME
If 1 '-DICHLOKODIETHYL ETHER
2-NITROPHENOL
2-NITROPHENOL
D1CHLOROPKOPENES
DIBENZC A, H) ANTHRACENE
4-NITKOPHENOL
4-NITROPHENOL
6ENZO(A)PYRENE
BENZO(A)PYRENE
PHENANTHRfcNE
2f4-DINITROPHENOL
2f 4-DINITROPHENOL
PHENOL
If I'-OICHLOHOMETHYL ETHER
BENZO(GHI)PERYLENE
BENZO(GHI)PERYLENE
4,6-DlNlTRO-O-CRESOL
4,6-OINITRO-O-CRESOL
FLUORENE
FLUORENE
FLUORENE
BROMOFORM
CHLOROBENZENE
CHLOROBENZENE
HEXACHLOROETHANE
ISOPHORONE
ISOPHORONE
OICHLOROPROPANES
OICHLOROPROPANES
lf2-DICHLUROBENZtN£
1,2-DICHLOROBENZENE
2^-XYLENOL
1,3-DICHLORUBENZENE
1 r 3-DICH10R00ENZENE
TYPE CONC
E-6 G/L
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
0. OOfc-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
6. OOE 04
O.OOE-01
O.OOE-01
O.OOE-01
6.0UE 04
O.OOE-01
O.OOE-01
0. OOfc-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
US
O.OOE-01
O.UOfc-Ul
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
U.UUt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOt-01
O.UOE-01
O.UOE-U1
O.OOE-01
O.UOE-01
o.oot-oi
O.UOt-01
O.OOE-01
O.UOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-U1
O.OOE-01
O.UOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
WDS
G/S
O.OOt-01
o.oot-oi
o.oot-oi
O.OOE-01
0. OOfc-01
o.oot-oi
O.OOt-01
0. OOfc-01
0. OOfc-01
O.UOt-01
O.UOt-01
O.UOt-01
o.oot-oi
0. OOfc-01
O.OOk-01
0. OOfc-01
O.UOfc-01
o.oot-oi
O.OOfc-Ul
0. OOfc-01
O.OOt-01
0. OOfc-01
O.OOt-01
O.OOt-01
o.oot-oi
O.OOt-01
O.OOt-01
o.oot-oi
O.OOt-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
LCCAT
5
5
6
2
2
5
6
2
3
3
5
6
6
4
2
5
6
2
3
2
2
3
1
5
6
1
2
2
3
6
2
3
-------
CYCLONE DUST UUENCH WATER, HEALTH IMPACT
OMEG NO.
COMPOUND NAME
TYPE
CUNC
E-b G/L
US
LCCAT
U/5
21
lb
16
21
16
16
21
21
A
A
A
A
A
A
A
A
100*
140*
140*
120*
160*
160*
140*
140*
PH
P
P
PH
P
P
P
P
ACENAPHTHENE
1,4-DICHLOROBENZENE
1,4-uICHLOKOBENZENE
ACENAPHTHYLENE
POLYCHLORINATEO BENZENES
POLYCHLORJNATEO BENZENES
ANTHRACENE
ANTHRACENE
T
T
T
T
T
T
T
T
O.OOE-01
O.OOE-01
O.OUE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOt-01
o.oot-oi
O.OOt-Oi
O.OOt-01
O.OOE-01
o.oot-oi
I
2
3
2
2
3
2
3
-------
Ul
-C-
CYCLONE DUST QUENCH WATER
APPROXIMATE FLOW RATE s 7 G/S (0.007 L/S)
TOTAL ORGANIC LOADING * 59.9 MG/L
ORGANIC LOADING
59500.0
FLOW RATE = 7.00
MINIMUM DISCHARGE SEVERITY = .010
STATE: LIQUID* UNITS IN MICftOGRAMS/L
IMPACT: ECOLOGY
EXPERIMENTALY DETERMINED DATA
SPARK SOURCE DATA
-------
CYCLONE DUST QUENCH MATER, ECOLOGY IMPACT
DMEG
16
02
06
08
08
08
19
48
16
16
£1
16
16
16
16
16
16
16
01
16
16
16
do
16
16
26
16
20
20
16
16
16
10
A
A
D
D
D
D
A
A
A
A
A
A
A
A
A
B
8
A
B
A
A
A
A
A
A
B
B
A
A
B
B
A
C
10 C
NO.
220 W
380 W
282
283
281
280* P W
060* P w
010
082
063
020* P
081
060
083
062
040
041
160* P
220 W
061
140* P
162
101* P
120* P
040
040 W
020 to
103
100 W
042
043
161
220 W
140* P W
COMPOUND NAME
POLYCHLORINATED BIPHENYLS
HEXACHLOROCYCLOHEXANE
DIETHYL PHTHALATE
OJ-N-BUTYL PHTHALATE
DIMETHYL PHTHALATE
PHTHALATE ESTERS
-------
CYCLONE OUST QUENCH WATER, ECOLOGY IMPACT
DMEG
16 A
20 A
10 C
Ib A
20 A
Ib A
18 A
2U A
20 B
16 B
16 C
19 B
16 A
19 A
16 A
20 A
16 &
23 B
18 A
18 A
18 A
16 A
18 C
16 A
16 A
18 A
18 A
16 A
16 A
16 B
16 A
16 C
20 A
16 A
NU.
020* P
102
200
080
060
100* P
120
040
040
060
060
023
060
020* P
103
020* P
040
080
146
080
040
041
061
100
043
182
061
062
063
060
101
020
060* P
162
W
W
w
w
M
W
H
W
W
w
w
w
N
W
COMPOUND NAME
CHLORObENZENE
2, 5-OINITROPHENOL
1-AMINONAPHTHALENE
bROMOCHLOROBENZENES
2-AMINO-4,6-DlNITROPHENOL
1,2-DICHLURObENZENE
2,2'-DIHYUROXYDIPMENYL
3-NITKOPHENOL
DINITRO-P-CRESOLS
1,2,3-TRIHYUROXYBENZENE
INOANOLS
CHLORINATED-P-CRESOLS
2-METHOXYHHENOL
2-CHLOROPHENOL
M-PHENYLPHENOL
2-NITROPHENOL
1,3-DIHYDROXYBENZENE
ACRIOINE
3,4-XYLENOL
ETHYLPHENOLS
CRESOLS
M-CRESOL
1-INPANOL
PHENYtPHENOLS
P-CRESOL
4,6-DI-TERT-BUTYL-M-CRESOL
0-ETHYLPHENUL
M-ETHYLPHENOL
P-ETHYLPHENUL
1,4-DIHYDROXYBENZENt
0-PHENYLPHENOL
1-NAPHTHOL
4-NITROPHENOL
4-ETHrL-O-CRESOL
TYPE CONC
E-6 G/L
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1
T
T
T
T
T
T
T
T
T
T
T
T
6.00E
6.00E
6.00E
6.0UE
6.00E
6.00E
b.OOE
b.OOE
6.00E
6.00E
6.00E
6. Out
6.00E
6.00E
6.00E
b.OOE
b.OOE
b.OOE
6.00E
b.OOE
b.OOt
b.OOE
b.OOE
b.OOE
6.00E
6.00E
b.OOE
6.00E
b.OOE
6.00E
6.00E
6.00E
6.0UE
6.00E
04
04
04
0<4
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
0<4
04
04
04
04
04
04
04
04
04
04
04
04
04
04
b
b
b
b
b
6
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
OS
.OOE
.OOE
.OOE
.OOE
.out
.OOE
• 2uE
,
-------
CYCLONE DUST UUENCH HATER, ECOLOGY IMPACT
DM
16
18
18
16
18
16
19
16
20
16
18
16
18
20
16
20
18
16
18
16
18
19
19
16
18
20
19
15
17
17
EG
A
A
C
A
A
A
B
A
B
A
B
C
C
A
A
A
B
6
A
A
B
B
A
A
A
17 A
08 0
NO.
140 M
020* P W
083
102
163
143
040* P
145
120
160 M
161
020 W
163
042
161
020* P W
040 W
062
144
141
042
020 H
022* P
142* P
180 W
041
021
060* P W
085
063
060 W
120
17 A 062
02 B 060* P M
COMPOUNO NAME TYPE CONC
E-6 G/L
XYLENOLS
PHENOL
5-INDANOL
P-PHENYLPHENOL
2>6-DIMETHYL-4-HEPTYL PHENOL
2»5-XYLENOL
2»4-DICHLOROPHENOL
3,5-XYLENOL
2»4,6-TRINITROPH£NOL
ETHYL CRE80L3
6-ETHYL-M-CHESOL
CATECHOL
2-ETHYL-P-CRESOL
2,6-DINlTHO-P-CRESOL
2,4,6-TRIMETHYL METHYL PHENOL
4,6-OINITRO-0-CRE80L
2-NAPMTHOL
4-INDANOL
2,6-XYLENOL
2, 3-XYLENOL
0-CRESOL
CHLORINATED CRESOLS
CHLORINATED-M-CRESOLS
2r4-XYLENOL
PULYALKYLPHENOLS (MM>135)
3»5-OINITRO-P-CRESOL
CHLORINATEO-0-CRE80L8
ETHYL BENZENE
2,5-DINlTROTOLUENE
2,3-DINlTROTOLUENE
OINITROTOLUENES
BUTYL ACETATES
3/4-DINITROTOLUENE
TETRACHLOROETHENE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
6.00k
6. OOE
6.0UE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6.00k
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
6. OOE
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
1
1
1
1
1
1
1
1
OS
.20E
• 20t
.20t
.206.
.20E
• 20£
.20E
• 20E
1.20E
1.20E
1
»20E
1.20E
1.20E
1
• 20E
1.20E
1.20E
1.20E
1.20E
1.20E
1.20E
1.20E
1.20E
1.20E
1.20E
1.
1.
1.
6.
6.
6.
6.
6.
6.
6.
20E
20E
20E
OOE
OOE
OOE
OOE
OOE
OOE
OOE
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
01
01
01
01
01
01
01
WDS
b/S
6.33k
6.33k
6.33k
8.33t
6.33k
6.33k
6.33k
6.33E
6.33k
8.33k
6.33t
6.33E
6.33k
6.33k
6.33k
6.33k
8.33k
6.33k
6.33k
8.33k
6.33E
8.33E
8.33k
6.33E
8.33k
6.33k
6.33k
4.20E
4.20E
4.20E
4.20E
4.20E
4.20E
4.20E
LCCAT
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
Ln
-------
I
M
oo
CYCLONE OUST JUENCH WATER, ECOLOGY IMPACT
OMEG NO.
04 A OUO w
10 A 060 W
17 A 084* P
08 D 141
08 0 142
17 A U40 W
17 A 041
02 B 100* P W
17 A 043
17 A 081* P
15 B 106
15 B 120 w
15 B 080 W
15 B 081
15 A 040* P N
15 B 105
02 A 340* P
15 B 101
17 A 086
17 A 042
15 A 080 W
15 A 100 N
02 B 103
02 B 104
06 0 140
15 B 103
17 A 020* P W
06 0 121
15 A 120 w
10 C 020
15 B 102
08 D 122
15 B 104
04 A 050 W
COMPOUND NAME
2-CHLOPO-l,2-EPOXYPROPAN£
1,2-DIAHINOETHANE
2r4-OINITROTOLUENE
N-AMYL ACETATE
SEC-AMYL ACETATE
NITHOTOLUENES
2-NITROTOLUENE
DICHLOROPHOPENES
4-NITROTOLUENE
2fb-DlNlTROTOLUEN£
1,4-DI-TERT-BUTYL BENZENE
TtTRAHYDRUNAPHTHALENE
XYLENES
0-XYLENE
TOLUENE
M-OIISOPROPYL BENZENE
DICHLOROPROPANES
0-OIETHYL BENZENE
3,5-DlNITROTOLUENE
3-NITROTOLUENE
STYRENE
PROPYL BENZENE
CIS-1,3-DICHLOROPROPENE
TRAMS- 1,3-DICHLORUPROPENE
AMYL ACETATES
P-DIETHYL BENZENE
NITROBENZENE
N-BUTYL ACETATE
ISOPROPYL BENZENE
ANILINE
M-DIETHYL BENZENE
SEC-BUTYL ACETATE
0-DIISOPROPYL BENZENE
EPICHLORHYDRJN
TYPI
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T.
T
T
T
T
T
E CONC
E-6 G/L
6.00E 04
6.00E 04
b.OOE 04
6.00E 04
6.00E 04
6.00E 04
6.00E 04
6.00E 0"
6.00E 04
b.OOE 04
6.00E 04
6.00E 04
6.00E 04
b.OOE OU
b.OOE 04
b.OOE 04
b.OOE 04
b.OuE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
b.OOE 04
OS
b.OOE 01
b.OUE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOt 01
b.OOE 01
b.OOE 01
b.OOE Ul
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
6.UOE 01
b.OOE 01
b.OOE 01
b.UOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
b.OOE 01
WDS LCCAT
li/S
4.20t 02
4.20L 02
4.20E 02
4.20E 02
«.20t 02
4.20E 02
4.20E 02
4.20E 02
4.20E 02
4.20L 02
4.20E 02
4.20t 02
4.20E 02
4.20fc 02
4.20t 02
4.20t 02
«.20t 02
4.20h 02
4.20L 02
4.20b 02
4.20E 02
4.20t 02
4.20E 02
4.20E 02
4.20t 02
4.20t 02
4.20E 02
4.20E 02
4.20t 02
4.20E 02
4.20t 02
4.20E 02
4.20E 02
4.20E 02
-------
CYCLONE DUST QUENCH MATER, ECOLOGY IMPACT
DMEG
08 A
08
15
04
02
08
15
15
15
72
38
08
09
09
09
09
08
08
08
08
08
08
08
15
17
23
08
10
15
15
01
03
23
05
0
B
A
A
D
B
B
B
A
A
A
B
B
B
B
A
A
A
A
A
A
B
B
B
A
D
A
B
B
A
B
A
A
NO.
040
123
083
060
343
143
100
082
020
010
010
080
042
041
040
020
100
101
104
103
102
180
060
201
060
081
101
060
202
200
200
020
060
122
COMPOUND NAME
W ACETIC ACID
ISOBUTYL ACETATE
P-XYLENE
M 1-CHLORO-1,3-EPOXYPROPANE
1 f 3-DICMLOROPROPANE
ISOAMYL ACETATE
H DIALKYL BENZENES (MWi 134-191)
M-XYLENE
INDAN
IRON (AS FE+2)
ALUMINUM
VALERIC ACID
B-NAPHTMONITRILES
A-NAPHTHONITRILE3
W NAPHTHONITRILE3
M BENZONITRILE
SATURATED LONG CHAIN ACXD8 (MH|U6-20l)
CAPROIC ACID
LAURIC ACID
CAPRIC ACID
CAPRYLIC ACID
ADIPIC ACID
M B-PROPIOLACTONE
1,2,3,4-TETRAMETHYLBENZENE
W 1-CHLORO-4-NITROBENZENE
2-PHENYLPYRIDINE
N-PROPYL ACETATE
ETMANOLAMINE
1,2,3, 5-TETKAMETHYLBENZENE
TETRAMETHYLBENZENE3
OCTANES
1,4-DIOXANE
W PHENYLPYRIDINES
2-METHYL-l-BUTANOL
TYPE CONC
E-6 G/L
T
T
T
T
T
T
T
T
T
D
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
4.90E
1.10E
6.00E
b.OOt
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
b.OOt
6.00E
6.00E
6.00E
6.00E
b.OOt
6.00E
6. DUE
6.00E
6.00E
6.00E
6.00E
6.00E
04
04
04
04
04
04
04
04
04
03
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
US
6.UOE
6.00E
6.00E
6.UOE
6.00E
6.00E
b.OOt
6.00E
4.30E
2.00E
1.10E
7.72E
7.62E
7.62E
7.62E
7.62E
6.80E
6.80E
6.00E
6.80E
b.ttOt
6.13E
6.00E
6.00£
6.00E
6.00E
6.00E
6.00E
b.OOE
6.00E
b.OOt
b.OOt
b.OOt
6.00E
01
01
01
01
01
01
01
01
01
01
01
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
ND3
G/3
4.20E
4.20k
4.20E
4.20E
4.20E
4.20k
4.20E
4.20k
3.00E
1.40E
7.70E
5.40k
5.33t
5.J3E
5.33k
5.33k
4.73k
4.73k
4.73k
4.73E
4.73E
4.30E
4.20k
4.20k
4.20E
4.20k
4.20E
4.20k*
4.20k
4.20k
4.20k
4.20E
4.20k
4.20k
LCCAT
02
02
02
02
02
02
02
02
02
02
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
til
01
01
01
01
On
-------
ON
O
CYCLONE OUST QUENCH HATER, ECOLOGY IMPACT
DMEG
17
05
23
23
23
23
04
23
05
06
23
06
23
10
10
01
23
05
15
05
05
05
23
04
23
08
23
07
82
07
34
08
49
76
6
A
A
A
A
A
B
A
A
0
A
A
A
A
B
A
A
A
B
A
A
A
A
B
A
0
A
e
A
B
A
A
A
A
NO.
040
121
063
122
064
060
080
062
100
100
020
020
061
160
100
201
121
124
203
120
140
123
063
040* P
082
060
120
100
010 P
120
010
140
010 P
010 P
M
W
w
W
W
W
W
W
rt
M
W
COMPOUND NAME
1-CHLURO-2-NITROBENZENE
N-PENTANOL
4-ETHYLPYRIDINE
2,4,6-COLLIDINE
4-N-PROPYLPYRIOINE
MONOSUBSTITUTED ALKYL PYRIDINES
2»2'-DICHLORODIETHYL ETHER
3-ETHYLPYRIDINE
ISOBUTYL ALCOHOL
PROPYL ACETATES
PYRIDINE
ETHYLENE GLYCOL
2-ETHYLPYRIOINE
CYCLOHEXYLAMINE
MOKPHOLINE
N-OCTANE
5-ETHYL-2-METHYLPYRID1NE
3-METHYL-l-BUTANOL
1,2,4,5-TETRAMETHYLbENZENE
PENTANOLS (PRIMARY)
BENZYL ALCOHOL
2,2-DIMETHYL-l-PROPANOL
4-PHENYLPYRIOINE
It I'-DICHLORODIETHYL ETHER
3-PHENYLPYRIDINE
METHYL METHACRYLATE
COLLIOINES
CAMPHOR
CADMIUM
ACETOPHENONE
CALCIUM (AS CA+2)
OLEIC ACID
ARSENIC
NICKEL
TYPE CONC
E-6 U/L
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
U
T
0
0
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
< 5.00E
6.00E
5.40E
6. CUE.
1.20E
< 2.00t
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
00<
04
04
04
02
OK
us
6.00E
6.00E
6.00E
6.00k
6.00E
6.00E
6.00E
6.00E
6.00E
6.00t
6.00E
6.00E
6.00E
6.00E
6.00k
6.00E
6.00t
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
6.00E
5.40E
5.00E
3.71E
J.40E
2.83E
2.40E
2.00E
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00<
00
00
00
00
00<
NDS
&/S
4.20k
4.20k
4.20k
4.20k
4.20k
4.20k
4.20k
4.20k
4.20k
4.20k
4.20k
4.20k
4.20k
4.20k
4.20k
4.20E
4.20k
4.20k
4.20k
4.20k
4.20E
4.20k
4.20k
4.20k
4.20E
4.20k
4.20k
3.60E
3.50E
2.60E
2.40E
2.00k
1.70k
1.40E
LCCAT
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
-------
DMEG NO.
CYCLONE DUST QUENCH WATER, ECOLOGY IMPACT
COMPOUND NAME
TYPE CONC US
E-6 G/L
b/3
LCCAT
46 A 010 P
06 A 040
08 D 320* P
08 B 080
05 C 040 W
05 A 080
79 A 010 P
81 A 010 P
78 A 010 P
54 A 010 P
36 A 010
62 A 010
33 A 010
27 A 010
65 A 010
37 A 010
74 A 010
68 A 010 P
71 A 010 P
83 A 010 P
69 A 010
45 A 010
07 B 080* P
16 A 160* P
02 A 340* P
10 C 140* P W
57 A 010
12 A 020* P
53 A 010
12 A 040* P
12 A 060* P
59 A 010
08 D 320* P
15 A 040* P W
LEAD
PROPYLENE GLYCOL
BUTYL BENZYL PHTMALATE
Y-BUTYROLACTONE
T-PENTANOL
N-BUTANOL
SILVER
ZINC
COPPER
SELENIUM
BARIUM
TITANIUM
MAGNESIUM
LITHIUM
VANADIUM
BORON
COBALT
CHROMIUM
MANGANESE
MERCURY
MOLYBDENUM
TIN
ISOPHORONE
POLYCHLORINATED BENZENES
DICHLOROPROPANES
BENZIDJNE
CHLORINE (AS CL-)
N-NITROSODIMETHYLAMINE
SULFUR
N-NITROSODIETHYLAMINE
N-NITROSOUIPROPYLAMINE
IODINE (AS I-)
BUTYL BENZYL PHTHALATE
TOLUENE
0 9.90E 01
T 6.00E 04
T 6.00E 04
T 6.Out 04
T 6.00E 04
T b.OOE 04
S 2.00E 00
D 3.50E 01
D 1.20E 01
S 6.00E 00
D 5.70E 02
D 1.80E 02
D 1.10E 04
S 4.00E 01
D 1.50E 01
D 9.90E 02
S 9.00E 00
D < 5.00E 00<
D < l.OOE 00<
D 4.00E-01
S 4.00E 00
D 2.9UE 03
T O.OOE-01
T O.OOE-01
T O.OOE-01
T O.OOE-01
D 3.40E 04
T O.OOE-01
D 2.30E 04
T 6.00E 04
T O.OOE-01
S 6.00E 00
T O.OOE-01
T O.OOE-01
2. OOF 00
6.00E-01
6.00E-01
6.00E-01
6.00E-01
6.00E-01
4.00E-01
3.50E-01
2.40E-01
2.40E-01
2.30E-01
2.20E-01
1.30E-01
1.10E-01
l.OOE-01
4.00E-02
3.60E-02
2.00E-02<
1.00E-02<
1.60E-03
5.71E-04
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-U1
O.OOE-01
O.OOE-01
O.OOE-01
1.40E 01
4.20E 00
4.20E 00
4.20E 00
4.20L 00
4.20E 00
2. 80t 00
2.44E 00
1.70E 00
1.70E 00
1.60E 00
1.53t 00
8.90E-01
7.40E-01
7.001-01
2.80E-01
2.52E-01
1.40E-01
7.00E-02
1.12E-02
4.00E-03
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
U.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
5
2
1
5
5
5
6
2
-------
NJ
CYCLONE OUST QUENCH WATER, ECOLOGY IMPACT
DMEG NO.
84 B 010
16 A 140* P
16 A 100* P
12 A 060* P
16 A 200* P
12 A 040* P
IS A 060* P W
08 D 300* P
18 A 020* P W
07 B 060* P
02 A 340* P
10 C 140* P W
15 A 040* P W
17 A 020* P W
U2 B 080* P W
16 A 200* P
12 A 020* P
02 B 100* P W
08 D 300* P
12 A 040* P
28 A 010
02 B 120* P
02 B 120* P
16 A IbO* P
02 B 140* P
12 A 020* P
58 A 010
Iti A 142* P
18 A 142* P
02 A 320* P
02 B 100* P W
02 A 320* P
04 A 140* P
04 A 140* P
COMPOUND NAME
CERIUM
1,4-DICHLOROBENZENE
1,2-DICHLUROBENZENE
N-NITROSODIPROPYLAMINE
CHLORONAPHTHALENES
N-NITROSODIETHYLAMINE
ETHYL BENZENE
OI-2-ETHYLHEXYL PHTHALATE
PHENOL
ISOPHORONE
DICHLOROPROPANES
BENZIOINE
TOLUEME
NITROBENZENE
TETKACHLOROETHENE
CHLORONAPHTHALENES
N-NITROSODIMETHYLAMINE
DICHLOROPHOPENES
DI-2-ETHYLHEXYL PHTHALATE
N-NITROSOUIETHYLAMJNE
SODIUM
HEXACHLURUBUTADIENE
HEXACHLOROBUTAOIENE
POLYCHLORINATEO BENZENES
HEXACHLOROCYCLOPENTADIENE
N-NITKOSODIMETHYLAMINE
BROMINE
2»4-XYLENOL
2,4-XYLENOL
HEXACHLOROETHANE
OICHLOROPROPENES
HEXACHLOROETHANE
2-CHLOROETHYL VINYL ETHER
2-CHLOROETHa VJNVL ETHER
TYPE
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
S
T
T
T
T
T
T
T
CONG
E-6 G/L
2.00E 00
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
o.oot-oi
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
2.20E 05
6.00E 04
O.OOE-01
O.OOE-01
6.00E 04
6. ODE 04
4.00E 01
O.OUE-OI
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
US
O.OOE-01
O.OOE-01
o.ooe-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
o.ooe-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
o.uot-ui
O.OOE-01
O.UOE-01
O.OOE-01
O.UOE-01
O.UOE-01
U.UOE-U1
O.UOE-01
O.OOE-U1
O.OOE-01
U.UOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
WOS
G/S
O.OOE-01
o.oot-ui
O.OOE-01
O.OOt-01
O.OOt-01
O.OOt-01
o.oot-ui
O.OOt-01
O.OOt-01
O.OOE-U1
o.uot-oi
O.OOt-01
O.OOE-01
O.OOt-01
O.UOt-01
o.oot-oi
O.OOt-01
U.OOt-Ul
O.OOt-01
O.OOt-01
U.UOt-Ul
O.UOE-01
U.OOt-Ul
o.uot-ui
U.OUt-Ul
o.uot-ui
O.OOt-01
o.oot-oi
O.UOE-U1
o.oot-oi
O.OOE-01
o.oot-ui
O.OOE-01
O.OOE-01
LCCAT
2
3
6
3
5
3
6
5
2
o
3
5
1
2
6
1
5
6
1
3
5
6
2
2
4
5
-------
CYCLONE DUST QUENCH WATER, ECOLOGY IMPACT
DMEG NU. COMPOUND NAME
04 A 160* P A-CHLOROBUTYL ETHYL ETHER
04 A 160* P A-CHLOROBUTYL ETHYL ETHER
30 A 010 RUBIDIUM (AS KB*)
04 A 180* P CHLOROPHENYL PHENYL ETHER
29 A 010 POTASSIUM
02 B 080* P W TETRACHLOROETHENE
43 A 010 SILICON
08 D 300* P DI-2-ETHYLHEXYL PHTHALATE
61 A 010 YTTRIUM (AS Y + 3)
63 A 010 ZIRCONIUM (AS ZR+4)
12 A 060*
17 A 081*
08 D 320*
02 B 120*
02 A 140*
02 A 160*
15 A 060*
02 A 160*
02 A 160*
19 A 020*
02 A 320*
19 A 040*
19 A 040*
18 A 020*
19 A 060*
19 A 060*
07 b 030*
N-NITROSODIPROPYLAMINE
2/6-DINITROTOLUENE
BUTYL BENZYL PHTHALATE
HEXACHLOROBUTADIENE
DIBROMOCHLOROME THANE
BROMOFORM
M ETHYL BENZENE
BROMOFORM
BROMOFORM
2-CHLOROPHENOL
HEXACHLOROETHANE
2,4-DICHLOROPHENOL
2,4-DICHLOROPHENOL
W PHENOL
W PENTACHLOROPHENOL
M PENTACHLOROPHENOL
ISOPHORONE
56 A 010 FLUORINE (AS F-)
16 A 100* P 1,2-DICHLOROBENZENE
19 B 022* P CHLORINATED-M-CRESOLS
19 b 022* P CHLORINATED-M-CRESOLS
16 A 120* P 1,3-DICHLOROBENZENE
16 A 120* P 1,3-DICHLOROBENZENE
20 A 020* P 2-NITROPHENOL
TYPE
T
T
S
T
S >
T
S
T
S
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
CONC
E-6 G/L
6.00E 04
O.OOE-01
2.00E 01
6.00E 04
l.OOE 04>
O.OOE-01
2.00E 03
6.00E 04
2.00E 00
5.00E 00
6.00E 04
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
2.00E 03
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
us
o.oot-oi
O.UOE-U1
O.OOE-01
O.OOE-01
O.OOE-01>
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OUE-OI
O.OOE-01
O.OUE-U1
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.UOE-01
U.UOt-Ul
O.UOE-01
U.UOE-U1
U.UOE-OI
O.UOE-U1
O.OOE-01
NDS
li/S
O.OOE-01
o.oot-oi
U.UOt-01
O.OOE-01
O.OOt-01
o.ooE-oi
U.UOfc-01
O.OOE-UI
O.OOE-01
O.OOE-01
O.OOE-OI
O.OOE-U1
O.OOE-U1
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-U1
O.OOE-01
O.OOE-U1
O.UOE-01
O.OOE-U1
u.uot-ui
O.UOE-01
U.UUt-01
o.oot-oi
o.oot-oi
U.UUE-OI
O.OOE-01
O.OOE-UI
O.OOE-01
o.oot-oi
o.oot-oi
o.out-oi
u.oot-ui
LCCAT
4
2
5
b
2
tL
2
1
2
6
1
b
6
6
5
6
6
2
5
6
2
3
b
I
M
U)
-------
I
I-1
-p-
CYCLONE OUST UUENCH *ATER, ECOLOGY IMPACT
DrtEG NO.
20 A 020* P
Ib A 140* P
35 A 010
20 A 060* P
20 A 060* P
02 B iao* P
02 B 140* P
16 A 200* P
20 A 101* P
20 A 101* P
31 A 010
04 A 140* P
39 A 010
44 A 010
20 B 020* P W
20 B 020* P W
04 A 160* P
17 A 020* P W
06 D 280* P W
06 0 280* P W
21 A 020* P
21 A 020* P
21 A 100* PH
21 A 100* PH
17 A 061* P
21 A 120* PH
21 A 120* PH
02 A 140* P
02 A 140* P
17 A 064* P
17 A 084* P
21 A 180* P
21 A 180* P
21 A 100* P
COMPOUND NAME
2-NITKOPHENOL
1,4-DICHLOROBENZENE
STRONTIUM
4-NITROPHENOL
4-NITROPHENOL
HEXACHLOROCYCLOPENTADlfcNE
HEXACHLOROCYCLOPENTADIENE
CHLORONAPHTHALENE3
2,4-DINITROPHENOL
2,4-DlNITROPHENOL
CESIUM
2-CHLUROETHYL VINYL ETHER
GALLIUM
GERMANIUM
4,6-DINITKO-O-CRESOL
4,6-DINITRO-O-CRESOL
A-CHLOROBUTYL ETHYL ETHER
NITROBENZENE
PHTHALATE ESTERS (M*:194-279)
PHTHALATE ESTERS (M«: 194-279)
NAPHTHALENE
NAPHTHALENE
ACENAPHTHENE
ACENAPHTHENE
2f6-DINITROTOLUENE
ACENAPHTHYLENE
ACENAPHTHYLENE
DIBROMOCHLOROMETHANE
DIBROMOCHLOROMETHANE
2,4-DINITROTOLUENE
2,4-DINITHOTOLUENfc
PHENANTHRENE
PHENANTHRENE
PHENANfHRENE
TYPE CONC
E-b G/L
T
T
0
T
T
T
T
T
T
T
S
T
S
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
O.OOfc-01
O.OOE-01
1.10E 03
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
4.00E 00
6.00E 04
2.00E 01
7.00E 00
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
US
O.OOfc-01
O.UOE-01
O.OOE-oi
O.OOE-01
o.uofc-ui
o.oot-oi
O.OOE-OI
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
WUb
ws
O.OOE-01
O.OOt-01
O.OOE-01
o.oot-oi
o.oot-oi
O.UOt-01
o.oot-oi
O.OOE-01
o.oot-oi
O.OOfc-01
O.OOE-U1
o.oot-oi
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-U1
o.oot-oi
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOfc-01
O.OOfc-01
O.OOE-01
O.OOfc-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOfc-01
O.OOE-01
LCCAT
6
3
5
6
1
2
5
6
5
b
5
4
5
&
2
3
2
4
2
1
4
5
2
3
-------
CYCLONE OU3T UUENCH *ATtR, ECOLOGY IMPACT
OMEG NO.
COMPOUND NAME
TYPE CONC
£-6 G/L
US
LCCAT
G/S
21 H 040* P
21 B 040* P
21 8 040* P
21 8 120* P
21 B 120* P
21 B 120* P
21 B 160* P
21 B 180* P
21 B 180* P
21 C 080* P
21 C 060* P
21 C 080* P
21 C 100* P
21 C 100* P
21 C 100* P
21 D 080* PH
21 D 080* PH
21 D 080* PH
22 A 020* PH
22 A 020* PH
22 A 020* PH
22 B 040* P
22 B 040* P
22 B 040* P
22 C 020* P
22 C 020* P
22 C 020* P
22 C 080* P
22 C 080* P
22 C 080* P
22 0 020* P
22 0 020* P
22 0 020* P
04 A 180* P
BENZ(A)ANTHRACEN£
BENZ(A)ANTHRACENE
BENZ(A)ANTHRACENE
CHRYSENE
CHRYSENE
CHRYSENE
PYRENE
PYRENE
PYHENE
OIBENZ( A, H) ANTHRACENE
oiBENZ(A»H) ANTHRACENE
DIBENZC A, H) ANTHRACENE
BENZO(A)PYRENE
BENZO(A)PYRENE
BENZO(A)PYRENE
BENZO(GHI)PERYLENE
BENZO(GHI)PERYLENE
BENZOCGHDPERYLENE
FLUORENE
FLUORENE
FLUORENE
FLUORANTHENE
FLUORANTHENE
FLUORANTHENE
BENZO(K)FLUORANTHtNE
BENZO(K)FLUORANTH£NE
BENZO(K)FLUORANTHtNE
BENZO(B) FLUORANTHENE
BENZO(B)FLUORANTHENE
BENZO (8) FLUORANTHENE
INDENOU,2,3-CD)PYRENE
INDENO(i,2,3-CD)PYRENE
INDENOU, 2, 5-CD) PYRENE
CHLOROPHENYL PHENYL ETHER
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
6.00E 04
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
6.00E 04
O.OOE-01
O.OOE-01
b.OOE 04
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-OI
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
o.oot-oi
O.OOE-01
o.oot-oi
O.OOt-01
o.oot-oi
O.OOE-01
o.oot-oi
O.OOE-01
o.oot-oi
O.OOE-01
o.oot-oi
O.OOE-01
o.oot-oi
O.OOE-01
O.OOt-01
O.OOE-01
O.OOt-01
o.oot-oi
O.OOt-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOt-01
o.oot-oi
O.OOE-01
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
2
3
2
3
2
3
2
3
2
3
2
3
2
3
2
3
2
3
2
3
2
3
4
-------
CYCLONE DUST QUENCH WATEK, ECOLOGY IMPACT
OMEG
04
04
04
04
21
04
04
21
21
21
21
16
16
19
A
B
B
B
A
B
B
A
A
A
A
A
A
A
NO.
180*
020*
020*
020*
100*
040*
040*
120*
140*
140*
140*
020*
020*
020*
P
P
P
P
PH
P M
P W
PH
P
P
P
P
P
P
COMPOUND NAME
CHLOROPHENYL PHENYL ETHER
1,1'-DICHLOROMETHYL ETHER
1,1'-DICHLOROMETHYL ETHER
1, l'-DICHLOROMETHYL ETHER
ACENAPHTHENE
Irl'-OICHLORODIETHYL ETHER
If I'-OICHLORODIETHYL ETHE*
ACENAPHTHYLENE
ANTHRACENE
ANTHRACENE
ANTHRACENE
CHLORUBENZENE
CHLOROBENZENE
2-CHLOROPHENOL
TYPE CONC
E-6 G/L
T
T
T
T
T
T
T
T
T
T
T
T
T
T
0.
6.
0.
0.
0.
0.
0.
0.
b.
0.
0.
0.
0.
0.
OOE-01
OOE 04
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE 04
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OS
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0
0
0
0
0
0
0
0
0
0
0
0
0
0
toUS
t/s
.OOE-01
.OOE-U1
.OOE-01
.OOE-01
.OOE-01
.OOt-01
.OOE-01
.OOE-01
.OOt-01
.OOt-01
.OOt-Ul
.OOt-01
.OOt-01
.OOt-01
LCCAT
5
4
5
3
4
b
3
2
3
d
3
5
-------
GASIFUR A8H
AVERAGE: FLOW RATE • 24.2 c/s
939.7 G EXTRACTED TOTAL ORGANIC LOADING 8 640 MG/KG
TOTAL TCO * 48 MG/KG
21.23X ORGINIAL SAMPLE TO LC
LC TCO • 9.7 MG LG GRAV » 117.4 MG LC TOTAL • 127.1 MG
ORGANIC LOADING
i 310.0
2 15.0
3 39.0
4 20.0
5 26.0
6 100.0
7 I7t0
FLOW RATE « 24.20
STATEl SOLID, UNITS IN MICNOGRAMS/G
IMPACTI HEALTH
EXPERIMENTALY DETERMINED DATA
SPARK SOURCE DATA
-------
I
M
00
GASIF1ER ASH, HEALTH IMPACT
DMEG
16
72
16
21
36
36
as
71
21
66
76
32
54
21
34
16
16
16
16
16
16
16
16
16
16
18
19
16
19
18
19
16
19
18
A
A
A
C
A
A
A
A
C
A
A
A
A
C
A
B
A
A
A
C
A
C
A
A
A
A
A
A
B
A
B
A
B
A
NO.
220* W
010
220* W
100* P w
010
010
010
010 P
100* P W
010 P
010 P
010 P
010 P
060* P
010
020* N
100* W
140* w
101*
040* W
102*
081*
082*
144*
063*
145*
060* P W
146*
020* W
160* W
021*
103*
022* P
162*
COMPOUND NAME
POLYCHLORINATED BIPH£NYLS
IRON (AS FE + 2)
POLYCHLORINATED BIPHENYLS
BENZO(A)PYRENE
ALUMINUM
BAHIUM
SILICON
MANGANESE
BENZO(A)PYRENE
CHKOMIUM
NICKEL
BERYLLIUM
SELENIUM
DIBENZ( A, H) ANTHRACENE
CALCIUM (AS CA+2)
CATECHOL
PHENYLPHENOLS
XYLENOLS
0-PHENYLPHENOL
2-NAPHTHOL
P-PHENYLPHENOL
1-INDANOL
M-ETHYLPHENOL
2»6-XYLENOL
P-ETHYLPHENOL
3, 5-XYLENOL
PENTACHLOROPHENOL
3f 4-XYLENUL
CHLORINATED CRESULS
ETHYL CRESOLS
CHLORINATED-0-CRESOLS
M-PHENYLPHENOL
CHLOKJNATED-M-CRE50LS
O-ErHN.-0-CHESOl
TYPE CONC
E-6 G/G
T
D
T
T
D
D
D
D
T
S
S
S
0
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
3.90E
9.00E
1.50E
3.9UE
8.80E
5.50E
1.4UE
2.20E
1.50E
l.OOE
7.50E
9.00E
1.50E
3.90E
4.80E
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
01
04
01
01
04
03
05
02
01
02
01
00
01
01
04
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
US
3.90E
i.OOE
1.50E
6.50E
5.50E
5.bOE
4.70E
4.40E
2. SUE
2.00E
1.70E
l.bUE
l.bOE
1.40E
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.UOE
l.UOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
04
04
04
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
WDS
G/S
9.43E
7.30E
3.62t
1.60E
1.43fc
1.33t
1.12E
l.lOt
6.04H
4.b3t
4.03E
3.63E
3.62E
3.40E
2.42E
2.42t
2.42E
2.42E
2.42E
2.42t
2.42E
2.42E
2.42E
2.42t
2.42E
2.42E
2.42E
2.42E
2.42E
2.42E
2.42E
2. 426
2.«2E
2.42E
05
05
05
04
04
04
04
04
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
LCCAT
3
2
3
2
3
6
6
6
6
6
6
O
6
6
6
6
6
6
6
6
6
6
6
6
-------
OMEG NO.
GASIFIER ASH, HEALTH IMPACT
CUMPOUNO NAME TYPE
CONC US
E-6 C/G
WDS
U/3
LCCAT
19 H 023*
18 A 163*
20 A 020* P
18 A 160*
18 A 141*
18 A 181*
20 A 060* P
18 A 161*
20 A 080*
19 A 020* P
20 A 100*
18 A 041*
20 A 101* P
18 B 040*
20 A 102*
18 B 060*
20 A 103*
18 B 080*
20 A 120*
18 C 020*
20 B 020* P
18 A 081*
20 B 040*
18 C 080*
20 6 041*
18 A 043*
20 B 042*
18 C 082*
18 A 182*
18 A 142* P
18 A 183*
18 C 083*
18 A 143*
19 A 040* P
N
W
W
M
W
W
W
W
H
W
W
W
M
W
W
CHLORINATED-P-CRESOLS
2-ETHYL-P-CRESOL
2-NITKOPHENOL
POLYALKYLPHENOLS (MM>135)
2,3-XYLENOL
2,4,6-TRJMETHYL METHYL PHENOL
4-NITROPHENOL
6-ETHYL-M-CRESOL
2-AMlNO-4,6-DlNlTHOPHENOL
2-CHLOROPHENOL
DINITROPHENOLS
M-CRESOL
2»4-DlNITROPHENOL
1,3-DIHYDRUXYBENZENt
2f5-DlNlTROPHENOL
1,4-DIHYDROXYBENZENt
2,6-DINITROPHENOL
1,2,3-TRIHYDROXYBENZENE
2f4,6-TRINITROPHENOL
1-NAPHTHOL
4,6-DINITRO-O-CRESOL
0-ETHYLPHENOL
OINITRO-P-CRESOLS
JNOANOL3
3r5-DINITRO-P-CRESOL
P-CRE80L
2»6-DINlTRO-P-CRE80L
4-INDANOL
4,6-DI-TERT-BUTYL-M-CRE30L
2,4-XYLENOL
2,6-DIMETHYL-4-HEPTYL PHENOL
5-INDANOL
2,5-XYLENOL
2,4-DICHLOROPHENOL
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.OOE
.OOE
.OOE
.OUE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.out
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
l.OOE
1
,OOE
l.OOE
l.OOE
1,
.OOE
l.OOE
l.OOE
1,
1,
,OOE
.OOE
l.OOE
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
1
1
]
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
l.OOE
L.OOE
.OOE
.UOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OUE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.UOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.UOE
.OOE
.OOE
.OOE
.OUE
.OOE
.OOE
.OOE
.UOE
l.UOE
l.OOE
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
U2
02
02
02
02
02
02
02
02
02
2.42E
2.42k
2.42k
2.42t
2.42b
2
2
2
2
2
2
a
2
2
2
2
2
2
2
2
2
2
.«2E
.42t
.42E
.42b
.42t
.42E
.42E
.42t
.42L
.42k
,42t
.42k
.42k
,42k
,42k
.42k
.42E
2.42E
2.42E
2.42k
2.42k
2.42k
2.42E
2.42E
2.42E
2.42E
2.42E
2.42E
2.42k
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
-------
-j
o
GASIFIER ASH, HEALTH IMPACT
DMEG
16 A
16 A
18 A
20 A
16 A
18 A
18 A
63 A
02 A
65 A
33 A
27 A
48 A
49 A
21 C
18 A
16 A
18 A
19 A
18 B
19 A
18 B
19 B
18 B
18 A
20 A
16 A
18 A
16 A
16 C
16 A
16 C
16 A
16 C
NO.
042*
120*
020*
040*
040*
060*
080*
010
380*
010
010
010
010
010
080*
163*
146*
160*
040*
020*
060*
040*
020*
060*
101*
101*
161*
141*
162*
040*
120*
060*
100*
061*
M
P W
W
W
W
H
P
W
P
P
W
P W
N
P W
N
M
W
P
W
W
W
*
COMPOUND NAME
0-CRESOL
2,2'-DIHYDROXYDIPHENYL
PHENOL
3»NITROPHENOL
CRESOLS
2-METHOXYPHENOL
ETHYLPHENOLS
MERCURY
HtXACHLOROCYCLOHEXANE
VANADIUM
MAGNESIUM
LITHIUM
PHOSPHORUS
ARSENIC
DI 6ENZ( A, H) ANTHRACENE
2-ETHYL-P-CRESOL
3»4-XYLENUL
ETHYL CRESOLS
2f 4-DICHLOPOPHENOL
CATECHOL
PENTACHLOHOPHENOL
lr 3-DIHYOROXY BENZENE
CHLORINATED CRESOLS
1,4-DIHYDROXY BENZENE
0-PHENYLPHENOL
2r4-DINlTROPHENOL
6-ETHYL-M-CRESOL
2,3-XYLENOL
4-ETHYL-O-CRESOL
2-NAPHTHOL
2,2'-DIHYDRUXYDIPHENYL
INDANOLS
PHENYLPHENOLS
I-INDANOL
TYPE CONC
E-6 G/G
T
T
T
T
T
T
T
D
T
S
D
S
0
D
T
T
T
T
T
T
T
T
T
T
T
T
T
r
T
T
T
T
T
T
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOt
1.70E
3.30E
4.10E
1.3UE
4.80E
2.00E
3.00E
1.50E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.6UE
2.60E
2.60E
2.60E
2.6UE
2.bOE
2.601:
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
02
02
02
02
02
02
02
00
02
02
04
01
03
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
us
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
B.bOE
8.3UE
8.20E
7.22E
6.90t
6.70E
6.00t
5.40E
2.60E
2.60E
2.60E
2. t>0t
2.60E
2.60E
2.&OE
2.&OE
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.&OE
02
02
02
02
02
02
02
01
01
01
01
Wl
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
WDS
G/S
2.42t
2.42E
2.42E
2.42t
2.42E
2.42t
2.42t
2.10t:
2. Out
2.00E
1.74L
1.70t
l.blt
l.bOt
1.30t
6.30t
6.30t
6.iOt
6.30E
6.30E
6.30t
6.30E
6.30E
6.30t
6.30L
6.30t
6.30t
6.30t
6.30E
6.30E
6.30b
6.30b
6.3UL
6.30E
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
02
02
02
02
02
02
0<>
02
02
Od
02
02
02
02
02
02
02
02
02
LCCAT
6
6
6
6
6
6
6
1
2
5
5
b
b
5
5
b
b
b
b
b
b
b
b
b
b
b
5
5
-------
DMEG NO.
6A81FIER ASH, HEALTH IMPACT
COMPOUND NAME TYPE
CONC US
E-b G/G
LCCAT
(*/3
20 B 042*
18 182*
18 142* P
18 020* H
18 183*
18 144*
20 100* W
18 A 082*
18 A 042*
18 A 145*
20 A 102*
20 A 040* W
18 A 020* P W
19 B 021*
18 A 040* M
19 B 022* P
18 A 041*
19 B 023*
18 A 103*
20 A 020* P W
18 A 180* W
20 B 041*
18 A 060* W
18 A 181*
18 A 080* W
20 A 080* W
18 A 081*
19 A 020* P W
18 C 083*
20 B 040* W
16 A 083*
18 A 102*
16 A 140* W
20 A 103*
2r6-DINITRO-P-CRESOL
4,6-DI-TERT-BUTYL-M-CRE80L
2,4-XYLENOL
1-NAPHTHOL
2»6-DIMETHYL-4-HEPTYL PHENOL
2f6-XYLENOL
DINITROPHENOLS
M-ETHYLPHENOL
0-CRESOL
3,5-XYLENOL
2,5-DlNITROPHENOL
3-NITROPHENOL
PHENOL
CHLORINATED-0-CRE80LS
CRESOLS
CHLORINATED-M-CRESOLS
M-CRESOL
CHLORINATED-P-CRE30L8
M-PHENYLPHENOL
2-MTROPHENUL
POLYALKYLPHENOLS (MW>135)
3,5-DINITRO-P-CRE80L
2-METHOXYPHENOL
2,4,6-TRlHETHYL METHYL PHENOL
ETHYLPHENOLS
2-AMINO-4,6-DlNITKOPHENOL
0-ETHYLPHENOL
2-CHLOROPHENOL
5-INDANOL
DINITRO-P-CRESOL8
P-ETHYLPHENOL
P-PHENYLPHENOL
XYLENOLS
2,6-DINlTROPHENOL
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
2.60k 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.6UE 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60k 01
2.60E 01
2.60k 01
2.60E 01
2.60k 01
2.60E 01
2.60E 01
2.60E 01
2.60k 01
2.6UE 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60k 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
6.30k 02
6.30E 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30E 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30E 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
6.30k 02
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
b
5
5
5
5
5
5
^
5
5
5
5
5
5
5
5
M
I
-------
GASIFIER ASH, HEALTH IMPACT
OMI
18
20
18
20
20
18
18
62
35
85
74
63
28
46
78
62
02
21
56
37
61
OU
21
04
79
02
02
64
81
10
10
10
10
JO
EG
8
A
A
b
A
C
A
A
A
B
A
A
A
A
A
A
A
B
A
A
A
B
B
B
A
A
B
A
A
C
C
C
C
C
NO.
080* w
120* W
043*
020* P W
060* P W
OH2*
143*
010
010
010
010
010
010
010 P
010 P
010 P
380* M
080*
010
010
010
020* P M
080*
020* P W
010 P
320* P
140* P W
010
010 P
100*
042*
040*
043*
041*
COMPOUND NAME
l»2,3-TRIHYDROXYBENZENE
2, 4,6-TRINITROPHENOL
P-CRESOL
4,6-OINITKO-O-CRESOL
4-NITROPHENOL
4-INDANOL
2»5-XYLENOL
TITANIUM
STRONTIUM
THORIUM
COBALT
ZIRCONIUM (AS ZR + 4)
SODIUM
LEAD
COPPER
CADMIUM
HEXACHLOROCYCLOHEXANE
3-METHYLCHOLANTHRENt
FLUORINE (AS F-)
BORON
YTTRIUM (AS Y + 3)
Irl'-OICHLOHOMETHYL ETHER
3-METHYLCHOLANTHRENt
l/l'-DICHLOROMETHYL ETHER
SILVER
HEXACHLOROETHANE
HEXACHLOROCYCLOPENTADIENE
HAFNIUM, (AS HF+4)
ZINC
1,4-DIAMINOBENZENE
3-AMINOTOLUENE
AHINOTOLUENES
4-AMINOTOLUENE
2-AMINOrOLU£N6
TYPE CONC
£-6 G/G
T
T
T
T
T
T
T
0
0
s
s
s
0
s
s
s
T
T
S
D
S
T
T
T
S
T
T
S
S
T
T
T
T
T
2.6UE
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
4.50E
1.90E
2.SOE
2.30E
i.eot
1.80E
5.00E
8.10E
01
01
01
01
01
01
01
03
03
01
01
02
04
00
01
6.00E-01
1.5UE
3.90E
1.90E
2.10E
5.90E
2.60E
l.SOfc
2.00E
01
01
02
02
01
01
01
01
6.00E-01
3.30E
3.30E
l.OOE
2.00E
l.OOE
l.OOE
i.OOE
l.OOE
l.OOE
02
02
00
01
02
02
02
02
02
US
2.60E 01
2.60E 01
2.60C 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2. 50t 01
2.10E 01
1.60E 01
l.b3E 01
1.20E 01
1.1 2E 01
l.OOE 01
8. lOt 00
8.00E 00
3.60E 00
3.b4E oo
2.53E 00
2.30E 00
2.00E 00
1.73E 00
1.40E 00
1.33fc 00
1.20E 00
1.10E 00
l.OOE 00
6.70E-01
4.00E-01
3.33E-01
3.0JE-01
3.03E-01
3.0JE-01
3.03E-01
6
6
6
6
6
6
6
6
S
4
3
2
2
2
2
1
9
6
6
5
4
4
3
3
2
2
2
1
9
8
HDb
b/5
,30fc
,30t
.30t
,30t
.30t
,30t
,30£
.oat
.oot
.30t
,71t
,90E
.72t
.42t
.oot
.93E
.lot
.601:
.13t
.bOt
.ttOt
,20fc
.30t
,22t
,90t
.70t
,42t
,61t
.70E
.lot
7.33E
7.33t
7.33t
7.J3fc
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
01
01
01
01
01
01
01
01
01
01
01
01
00
00
00
00
00
00
LCCAT
b
5
b
b
b
5
b
2
3
5
2
4
1
1
6
6
6
6
6
-------
DMEG NO.
GASIFIER ASH, HEALTH IMPACT
COMPOUND NAME TYPE
CONC US
E-b G/G
LCCAT
b/3
21
21
0
B
12 A
23
10
23
23
85
21
21
08
64
69
10
23
10
10
10
10
02
12
13
10
23
10
10
10
39
44
10
21
21
B
C
B
B
A
B
D
B
B
A
C
C
C
C
C
C
A
A
A
C
C
C
C
C
A
A
C
B
B
21 B
21 B
040* W
040* P
040* P
100* W
220*
240*
220*
010
040* P
040* W
060* W
010
010
100*
160* W
040*
041*
042*
043*
160
040* P
100* W
060*
160* W
061*
082*
063*
010
010
200*
105*
107*
101*
10B*
DIBENZO(A,I)PYRENE
BENZ(A)ANTHRACENE
N-NITROSODIETHYLAMINE
OIHYDROACRIOINE
2-AMINONAPHTHALENE
DIBENZ(A,H)ACRIDINE
DIBENZ(A,J)ACRIDINE
URANIUM
BENZCAJANTHRACENE
DIBENZO(A,I)PYRENE
B-PROPIOLACTONE
CERIUM
MOLYBDENUM
1,4-DIAMINOBENZENE
DIBENZO(C,G)CAR6AZOLE
AMINOTOLUENES
2-AMINOTOLUENE
3-AMINOTOLUENE
4-AMINOTOLUENE
DIBROMODICHLOROMETHANE
N-NITROSODIETHYLAMINE
BENZENETHIOL
ANISIDINES
DIBENZO(C,G)CARBAZOLE
0-ANISIDINE
M-ANISIDINE
P-ANISIDINE
GALLIUM
GERMANIUM
1-AM1NONAPHTHALENE
b-METHYL BENZOCOPHENANTHRENE
8-METHYL BENZOCOPHENANTHRENE
BENZOCOPHENANTHRENE
ISUPROPYL BENZOCOPHENANTHRENE
T
T
T
T
T
T
T
S
T
T
T
S
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
8
S
T
T
T
T
T
3.9UE
3.90E
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
1.60E
1.50E
1.50E
l.OOE
1.10E
1.50E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
3.30E
2.bOt
l.OOE
l.OOE
2.00E
l.OOE
l.OOE
l.OOE
9.00E
l.OOt
l.OOE
3.90E
3.90E
3.90E
3.90E
01
01
02
02
02
02
02
01
01
01
02
02
01
01
01
01
01
01
01
02
01
02
02
01
02
02
02
00
00
02
01
01
01
01
3.00E-01
3.00t-01
2.BOE-01
2.04£-0l
2.00E-01
l.bOE-01
1.40E-01
1.33E-01
1.20E-01
1.20E-01
1.10E-01
l.OOE-01
l.OOE-01
8.70E-02
8.70E-02
7.90E-02
7.90E-02
7.90E-02
7.90E-02
7.90E-02
7.22E-02
6./OE-02
6.70E-02
b.70E-02
6.70E-02
6.70E-02
6.70E-02
6.00E-02
5.90E-02
5.90k-02
5.82E-02
5.62E-02
5.62E-02
5.62E-02
7
7
b
4
4
3
3
3
2
I
2
2
2
2
2
1
1
.30t
.30t
.72t
.93t
.b3t
.bit
,3ok
.22t
.fcOt
.ttOt
.54E
.«lt
.ait
.lot
.lot
,9ofc
,90E
,90t
.90E
.90E
.74t
.blE
,bU
.61E
<
,blt
.blE
.bit
.50t
«
•
42t
42t
.40E
•
.
•
40E
40k
40k
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
3
3
b
b
b
b
b
2
2
b
b
5
5
5
S
5
1
5
b
b
4
b
b
b
b
3
3
3
3
en
i
-------
GASIFIER ASH, HEALTH IMPACT
DMEG
21
21
21
21
21
21
21
21
57
23
10
10
12
02
66
02
23
23
70
08
84
08
08
08
08
02
08
50
12
10
21
21
21
21
B
B
B
B
B
B
B
B
A
B
C
C
A
A
A
B
B
B
A
C
A
A
A
A
A
B
B
A
B
C
B
B
B
B
NO.
109*
108*
106*
100*
10A*
102*
104*
103*
010
100* H
220*
140* P
020* P W
320* P
010
140* P M
240*
220*
010
060 W
010
123
121
120 W
122
120* P
060* W
010 P
020 W
120
10B*
107*
105*
108*
COMPOUND NAME
6-ETHYL BENZOCOPHENANTHRENE
2-ETHYL bENZOCOPHENANTHRENE
7-METHYL BENZOCOPHENANTHRENE
BENZOCOPHENANTHKtNE & ALKYL DERIVATIVES
N-PROPYL BENZOCOPHENANTHRENE
1-KETHYL BENZOCOPHENANTHRENE
5-METHYL BENZOCOPHENANTHRENE
2-METHYL bENZOCOPHENANTHRENE
CHLORINE (AS CL-)
DIHYDROACRIDINE
2-AMINONAPHTHALENE
BENZIDINE
N-NITROSODIMETHYLAMlNE
HEXACHLOROETHANE
NIOBIUM (AS NB+3)
HEXACHLOROCYCLOPENTAD1ENE
DIBENZ(A,H)ACRIDINE
OIBENZCA, J)ACRIDIN£
TUNGSTEN
6-HfcXANELACTAM
LANTHANUM
STEARIC ACID
MYRISTIC ACID
SATURATED LONG CHAIN ACIDS (MM:228-285)
PALMITIC ACID
HEXACHLORUBUTADIENE
B-PROPIOLACTONE
ANTIMONY
N-METHYL-N-NITROSOANILINE
4-AMINOBIPHENYL
ISOPROPVL BENZOCOPHENANTHRENE
8-METHYL BENZOCOPHENANTHRENE
6-METHYL BENZOCOPHENANTHRENE
2-ETHVL BENZOCOPHENANTHRENE
TYPE CONC
E-6 G/G
T
T
T
T
T
T
T
T
D
T
T
T
T
T
S
T
T
T
S
T
S
T
T
T
T
T
T
D
T
T
T
T
T
T
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
l.bOE
2.60E
2.60E
l.OOE
l.OOE
1.50E
3.10E
1.50E
2.60E
2.60E
l.OOE
.OOE
.10E
.out
.OOE
.OOE
.OOE
3.30E
2.60E
01
01
01
01
01
01
01
01
02
01
01
02
02
01
01
01
01
01
00
02
02
02
02
02
02
02
01
< 4.00E-OK
l.OOE
l.OOE
1.50E
1.50E
1.50E
1.50E
02
02
01
01
01
01
b
b
5
5
b
5
5
5
b
b
5
5
b
5
4
4
3
3
3
3
3
3
3
3
3
2
2
2
2
2
2
2
2
US
.62E-02
.82E-02
.82E-02
.82E-02
.82E-02
.62E-02
.82E-02
.82E-02
.80E-02
.30E-02
.20E-02
.OOE-02
.OOt-02
.OOE-02
.dOt-02
,b4E-02
.90E-02
•blE-02
.33E-02
.33E-U2
.23E-02
.22E-02
.22E-02
.22E-02
.22E-02
.80E-02
.73E-02
,70E-02<
.toOE-02
.50E-02
.23E-02
.23E-02
.23E-02
2.23E-02
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1,
1,
1,
9.
8.
8.
8.
7.
7.
7.
7.
7.
6.
6.
6.
b.
6.
b.
5.
5.
5.
WDS
G/S
40t 00
aot oo
aot oo
40E 00
aot oo
aot oo
aot uo
aot oo
aot oo
30t 00
30t 00
20E 00
20t 00
2l>t 00
20t 00
lot oo
40E-01
50t-01
I0t-01
10t-01
b2t-01
dOt-01
80t-01
80E-01
80t-Ul
70t-01
b2t-01
50t-01
20E-01
04t-01
41t-01
41E-01
ait-oi
Mfc-01
LCCAT
3
3
3
3
3
3
3
3
b
b
b
b
2
2
b
b
b
b
b
b
b
1
b
b
b
2
2
2
2
-------
DMEG NO.
GA8IF16R A8H, HfcALTH IMPACT
COMPOUND NAME TYPE
CONC US
E-6 G/G
NUS
LCCAT
21 B 104*
21 B 10A*
21 B 100*
21 B 109*
21 B 101*
21 B 103*
21 B 102*
21 B 106*
02 A 160* P
08 B 060* H
10 C 082*
10 C 080*
10 C 081*
13 A 100* W
10 C 083*
10 C 200*
84 F 010
22 C 080* P W
30 A 010
15 A 160 M
12 A 020* P W
10 C 140* P
60 A 010
21 D 060
84 C 010
02 B 100* P
84 E 010
21 A 180* H
22 D 020* W
22 C 020*
08 D 300*
08 D 280* W
21 B 120*
17 A 084*
5-METHYL BENZOCOPHENANTHRENE
N-PROPYL BENZOCOPHENANTHRENE
BENZOCOPHENANTHRENE & ALKYL DERIVATIVES
6-ETHYL BENZOCOPHENANTHRENE
BENZOCOPHENANTHRENE
2-ME1HYL BENZOCOPHENANTHRENE
1-METHYL BENZOCOPHENANTHRENE
7-METHYL BENZOCOPHENANTHRENE
BROMOFORM
B-PROPIOLACTONE
M-ANISIDINE
ANISIOINES
0-ANISIDINE
BENZENETHIOL
P-ANISIDINE
1-AMINONAPHTHALENE
DYSPROSIUM
BENZOCB)FLUORANTHENE
RUBIDIUM CAS HB+)
BIPHENYL
N-NITROSODIMETHYLAMINE
BENZIDINE
SCANDIUM
DIBENZOCAtUPYRENE
PRASEODYMIUM
DICHLOROPROPENES
SAMARIUM
PHENANTHRENE
INDENOClr2r3-CD)PYRENE
BENZOCK)FLUORANTHbNE
DI-2-ETHYLHEXYL PHTHALATE
PHTHALATE ESTERS CMN|l94-279)
CHRYSENE
2,4-DINITROTOLUENE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
3
T
T
T
8
T
S
T
S
T
T
T
T
T
T
T
l.SOE 01
l.SOE 01
l.SOE 01
l.SOE 01
l.SOE 01
l.SOE 01
l.SOE 01
l.SOE 01
3.30E 02
1.70E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60t 01
2.60E 01
7.00E 00
3.90E 01
4.70E 01
3.90E 01
2.60E 01
2.60E 01
2.00E 01
3.90E 01
1.60E 01
3.30E 02
1.30E 01
3.90E 01
3.90E 01
3.90E 01
l.OOE 02
l.OOE 02
3.90E 01
2.60E 01
2.23E-02
2.23E-02
2.23E-02
2.23E-02
2.23E-02
2.23E-02
2.23E-02
2.23E-02
2.20E-02
1.80E-02
1.73E-02
1.73E-02
1.73E-02
1.73E-02
1.73E-02
l.b2E-02
1.&2E-02
1.44E-02
1.30E-02
1.30E-02
1.30E-02
1.30E-02
l.JOb-02
1.21E-02
1.10E-02
9.70E-03
8. 12b-03
8.12E-03
8.12E-03
8.00E-03
6.70E-03
6.70E-03
5.90E-03
S.80E-03
5.41E-01
5.41fc-01
5.41t-01
5.4U-01
5.4U-01
5.41t-01
5.41t-01
5.41E-01
5.32fc-01
4.33L-01
4.20E-01
4.20L-01
4.20fe-01
4.20L-01
4.20b-01
3.70t-01
3.70fc-01
3.SOb-01
3.20b-01
3.14t-01
3.14b-01
3.l4b-01
3.U2b-01
2.94E-01
2.60L-01
2.34t-01
2.00t-01
2.00E-01
2.00b-01
1.92t-01
l.fclt-01
1.61E-01
1.42L-01
l.«0t-01
2
2
2
2
2
2
2
2
1
7
5
5
5
S
S
S
3
3
5
S
3
1
3
3
3
6
6
3
5
m
i
-------
I
I-1
-J
GASIFIER ASH, HEALTH IMPACT
DMI
17
22
17
17
31
21
22
22
02
21
08
08
17
12
17
07
02
16
02
04
04
02
16
12
07
02
04
04
21
04
08
21
04
16
:G
A
C
A
A
A
A
D
C
A
B
D
D
A
A
A
B
B
A
A
A
A
B
A
A
B
A
A
B
A
A
D
A
B
A
NO.
081*
080*
084*
081*
010
160*
020*
020*
140*
120*
300*
280*
020*
060*
020*
080*
120*
160*
160*
140*
140*
100*
160*
060*
080*
340*
180*
040*
020*
180*
320*
140*
040*
200*
P
P W
P
p
P W
P rt
P
P
P
p
P W
P
p
p
P
P
p
P
P
p
p
P
P
P
P
P
P
P
P
P
P
p
P
COMPOUND NAME
2r6-DINITROTOLUENE
BENZO(B)FLUORANTHENE
2,4-DINITROTOLUENE
2r 6-DINITROTOLUENE
CESIUM
PHENANTHRENE
INDENO(1,2,3-CD)PYRENE
BENZO(K)FLUORANTHENE
DIbKOMOCHLOWOMETHANE
CHRYSENE
OI-2-ETHYLHEXYL PHTHALATE
PHTHALATE ESTERS (M*:l94-279)
NITROBENZENE
N-NITROSOOIPROPYLAMlNE
NITROBENZENE
ISOPHORONE
HEXACHLOROBUTADIENE
POLYCHLORINATED BENZENES
BROMOFORM
2-CHLOROETHYL VINYL ETHER
2-CHLOROETHYL VINYL ETHER
OICHLOROPHOPENES
POLYCHLORINATED BENZENES
N-NITROSOUIPROPYLAMINE
ISOPHORONE
OICHLOROPROPANES
CHLOROPHENYL PHENYL ETHER
1,1'-DICHLORODIETHYL ETHER
NAPHTHALENE
CHLOROPHENYL PHENYL ETHER
BUTYL BENZYL PHTHALATE
ANTHRACENE
l,l'-DICHLURODIETHYl EfHEH
CHLOPONAPHTHALENfc'S
TYPE CONC
E-6 G/G
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
2.60E
1.50E
2.00E
2. OOE
8.00E
1.50E
1.50E
1.50E
3.30E
1.50E
2.60E
2.60E
2.60E
l.OOE
2.00E
l.OOE
1.50E
3.90E
l.SOt
2.60E
2.00E
1.50E
1.50E
2.60E
2.60E
3.30E
2.60E
2.60E
3.90E
2.00E
l.OOE
3.90E
2.00E
3.90E
01
01
01
01
00
01
01
01
02
01
01
01
01
02
01
02
01
01
01
01
01
01
01
01
01
02
01
01
01
01
02
01
01
01
US
5.80E-03
5.60E-03
4.44E-03
4.44E-U3
3.20E-03
3.12E-U3
3.12E-03
3.10E-03
2.40k-u3
2.30E-03
1.73t-U3
1.73&-03
1.73E-03
1 ,40t-03
1.33E-03
1.33E-03
1.3UE-03
1.11E-03
l.OOE-03
7.64E-04
5.90E-04
4.41E-04
4.30E-04
3.61E-04
3,bO£-04
3.30E-04
3.20E-04
2.90E-04
2.60E-04
2.50E-04
2.32E-04
2.30E-04
1
1
1
1
7
7
7
7
S
5
4
4
4
3
3
3
3
2
2
1
1
1
1
8
6
8
7
7
6
6
li/S
.40t-01
.34E-01
.10t-01
.10E-01
,74t-02
.60E-02
.60L-02
.40E-02
,70t-02
,bOt-02
.20E-02
.iJOt-02
,20t-02
,40t-02
.22t-02
.22E-OZ
.02E-02
,70t-02
.41E-02
,90fc-02
.42E-02
.10t-02
.03t-02
.73E-03
,40t-03
.OOt-03
.bOt-03
.OOt-03
.30E-03
.OOb-03
5.62t-03
5.60E-03
2.22E-04 5.40L-03
1.90E-04
4,
,50t-U3
LCCAT
5
2
4
4
2
2
2
1
2
5
5
5
6
4
6
2
3
2
5
4
2
2
5
5
1
b
5
3
4
6
3
4
3
-------
GASIFIER ASH, HEALTH IMPACT
DMEG NO.
02 B 060* P
22 B oao* P w
02 A 140* P
21 A 020* P
21 A 140* P
16 A 200* P
08 0 320* P
21 B 180* P
22 B 040* P N
16 A 100* P
16 A 120* P
16 A 020* P
is A oao* P
15 A 060*
16 A 140*
21 B 180*
16 A 100*
16 A 120*
02 A 340*
15 A 040*
16 A 020*
15 A 060*
16 A 140*
02 8 060* P
45 A 010
22 A 020* PH
21 A 120* PH
04 A 160* P
59 A 010
29 A 010
04 A 160* P
21 D 080* PH
22 A 020* PH
84 D 010
COMPOUND NAME
TETRACHLOROfcTHENE
FLUORANTHENE
OIBROMOCHLOROMETHANE
NAPHTHALENE
ANTHRACENE
CHLORONAPHTHALENES
BUTYL BENZYL PHTHALATE
PYRENE
FLUORANTHENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
CHLOROBENZENE
TOLUENE
ETHYL BENZENE
1,4-DICHLOROBENZENE
PYRENE
1,2-DICHLUROBENZENE
1,3-DICHLOROBENZENE
DICHLOROPROPANE8
TOLUENE
CHLOROBENZENE
ETHYL BENZENE
1,4-DICHLOROBENZENE
TETRACHLOROETHENE
TIN
FLUORENE
ACENAPHTHYLENE
A-CHLOROBUTYL ETHYL ETHER
IODINE (AS I-)
POTASSIUM
A-CHLOROBUTYL ETHYL ETHER
BENZO(GHI)PERYLENE
FLUORENE
NEODYMIUM
TYPE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
T
T
8
D
T
T
T
S
CONC
E-6 t/G
3.30E 02
3.90E 01
1.506. 01
1.50E 01
1.5UE 01
1.50E 01
2.60E 01
3.9UE 01
1.5 06. 01
3.90E 01
3.90E 01
3.90E 01
3.90fc 01
3.90E 01
3.90E 01
1.50E 01
1.50E 01
1.50E 01
1.50E 01
1.50E 01
1.50E 01
1.50E 01
1.50E 01
1.50E 01
S.OOE-01
3.90E 01
3.90E 01
2.QOE 01
2.00E-01
8.60E 03
2.60E 01
3.90E 01
1.50E 01
3.00E 01
US
1.70E-04
1.40E-04
U10E-U4
UUOE-04
8.tt2t-05
7.14E-05
6.04E-U5
5.70E-05
5.40E-05
4.i3E-05
4.33E-05
3.54E-05
3.54E-05
3.00E-05
2.bOt-05
2.20E-U5
1.70E-05
.70E-05
.bOE-05
.40E-05
.40E-05
.20E-05
.10E-05
7.50E-06
o.oot-oi
O.UOE-01
O.OOE-Ul
O.OOt-01
O.UOE-01
O.OOE-01
O.UOE-01
O.UOE-01
O.OOE-01
O.OOE-01
HDS
b/s
4.00t»03
3.40E-03
2.60E-03
2.41L-03
2.13E-03
1.72E-03
l.bOE-03
i.40t-U3
1.30E-03
1.04E-03
1.04E-03
8.60E-04
8.60E-04
7.30E-04
6.74E-04
5.30(1-04
4.03E-04
4.03E-04
3.62E-04
3.30E-04
3.30t-04
2.60t-04
2.60E-04
1.8U-04
O.OOE-01
O.OOE-01
O.OOE-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
LCCAT
1
3
2
2
2
2
5
3
2
3
3
3
3
3
3
2
2
2
2
2
2
2
2
2
3
3
4
5
3
2
-•J
VJ
-------
I
M
00
GASIFIER ASH, HEALTH IMPACT
DMEG
53
21
58
21
21
21
A
0
A
A
A
A
NO.
010
080*
010
100*
100*
120*
PH
PH
PH
PH
COMPOUND NAME
SULFUR
BENZO(GHI)PERYLENE
BROMINE
ACENAPHTHENE
ACENAPHTHENE
ACENAPHTHYLENE
TYPE CONC
E-6 G/G
0
T
S
T
T
T
8.80E
1.50E
2.00E
l.SOt
3.90E
1.50E
03
01
00
01
01
01
0
0
0
0
0
0
OS
.OOE-Ol
.OOE-01
.OOE-Ol
.OOE-01
.UOE-01
.OOE-01
WDb
b/b
o.oot-oi
0. OOE-01
0. OOE-01
O.OOt-01
0. OOE-01
O.OOt-01
LCCAT
2
2
3
2
-------
GA8IFUH ASH
AVERAGE FLOW HATE * 24.2 G/S
939.7 G EXTRACTED TOTAL ORGANIC LOADING • 640 HG/KG
TOTAL TCO • 48 HG/KG
21.23X ORGINIAL SAMPLE TO LC
LC TCO * 9.7 HG LG GRAV » 117.4 MG LC TOTAL • 127.1 MG
LCCAT ORGANIC LOADING
1 330.0
2 15.0
3 39.0
4 20.0
5 26.0
6 100,0
7 17.0
FLOW RATE • 24.20
STATES SOLID, UNITS IN HICROGRAMS/G
IMPACT! ECOLOGY
EXPERIMENTALY DETERMINED DATA
SPARK SOURCE DATA
I
M
—I
-------
CO
o
OMEG NO.
GASIFIER ASH, ECOLOGY IMPACT
COMPOUND NAME TYPE
CONC US
E-6 G/G
WDS
LCCAT
02
16
48
16
02
72
38
08
06
08
06
76
06
08
08
08
62
19
01
34
65
36
71
78
19
20
20
10
20
20
10
10
20
82
A
A
A
A
A
A
A
D
D
D
D
A
D
D
D
D
A
A
B
A
A
A
A
A
A
A
A
C
A
A
C
C
A
A
380* W
220* w
010
220* M
360* M
010
010
281*
282*
280* P M
283*
010 P
280* P W
283*
282*
281*
010
060* P W
220 W
010
010
010
010 P
010 P
060* P W
102*
100* W
140* P W
101* P
080* *
220* *
200* W
103*
010 P
HEXACHLOROCYCLOHEXANE
POLYCHLORINATED BIPHENYLS
PHOSPHORUS
POLYCHLORINATED BIPHENYLS
HEXACHLOROCYCLOHEXANE
IRON (AS FE+2)
ALUMINUM
DIMETHYL HHTHALATE
DIETHYL PHTHALATE
PHTHALATE ESTERS (MM J 194-279)
DI-N-BUTYL PHTHALATE
MICKEL
PHTHALATE ESTERS lMWSl94-279)
DI-N-BUTYL PHTHALATfc
DIFTHYL PHTHALATE
DIMETHYL PHTHALATE
TITANIUM
PENTACHLOROPHENOL
DICYCLOPENTADIENE
CALCIUM (AS CA+2)
VANADIUM
BARIUM
MANGANESE
COPPER
PENTACHLOROPHENOL
2,5-DINITROPHENOL
DINITROPHENOLS
BENZIDINE
2,4-DINITROPHENOL
2-AMINO-4,6-DINITROPHENOL
2-AMINONAPHTHALENE
1-AMINONAPHTHALENE
2f6-OINlTROPHENOL
CADMIUM
T
T
D
T
T
D
U
T
T
T
T
S
T
T
T
T
D
T
T
D
S
D
D
S
T
T
T
T
T
T
T
T
T
S
3.30E
3.90E
2. Out
1.50E
1.50E
9.00E
8.8UE
l.OOt
l.OOE
l.OOE
l.OOE
7.50E
2.60E
2.60E
2.60E
2.60E
4.50E
l.OOE
3.30E
4.80E
4.10E
5.50E
2.20E
8.10E
2.60E
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
02
01
03
01
01
04
04
02
02
02
02
01
01
01
01
01
03
02
02
04
02
03
02
01
01
02
02
02
02
02
02
02
02
8.00E-01
8.24E
3.90fc
2.00E
l.bOt
3.74E
1.80t
4.40E
1.30E
1 .30E
l.iGt
1.30E
3. but
3.24E
3.24E
3.24E
3.24E
2.81E
2.00E
1.70E
1.50E
1.40E
1.1 OE
1.10E
8.10E
5.20E
b.OUE
5. Out
5.UOE
5.00E
5.00E
5.00E
S.OOE
5.00E
4.00E
04
04
04
04
03
03
02
02
02
02
02
01
01
01
01
01
01
01
01
01
01
01
01
00
00
00
00
00
00
00
00
00
00
00
2.00t
9.43t
4.63E
3.62t
9. lOt
4.40E
l.lOfc
3.02t
3.02t
3.02t
3.02t
9. lot
7.90E
7.90t
7.90t
7.90t
6.60t
4.83E
4.00t
3.62E
3.30t
2.70t
2.70E
2. Out
1.30t
1 ,21t
1.21E
1.21t
1.21E
1.21E
1.21E
1.21E
1.21E
9.70E
06
US
05
05
04
04
04
03
03
03
03
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
01
1
3
I
2
6
6
6
6
5
b
5
5
6
1
5
6
6
6
6
6
6
6
6
-------
DMEG NO.
GASIFIER ASH, ECOLOGY IMPACT
COMPOUND NAME TYPE
CONC
E-6 G/G
WD3
i*/a
LCCAT
49 A 010 P ARSENIC
54 A 010 P SELENIUM
66 A 010 P CHROMIUM
100* P 1,2-DICHLOROBENZENE
060* DIBROM08ENZENES
B.ROMOBENZENE
W A-CHLOROTOLUENE
POLYCHLORINATED BENZENES
MEXACHLOROBENZENE
1,2-BISCCHLOROMETHYBENZENE
1,4-UICHLOROBENZENE
l-BROMO-4-CHLOROBENZENE
l-BROMO-3-CHLOROBENZENE
1»3-BIS(CHLOROMETHYL)BENZENE
1,3-DICHLOROBENZENE
NAPHTHALENE
BISCCHLOROMETHYDBENZENES
1,2-DIBROMOBENZENE
1»3-DIBROMOBENZEN£
l-BROMO-2-CHLOROBENZENE
BROMOCHLOROBENZENES
1,4-DIBROMOBtNZENE
1,4-8IS(CHLOROMETHYL)BENZENE
1,2,4-TRICHLOROBENZENE
CHLOROBENZENE
TRANS-1,3-DICHLOROPROPENE
OICHLOROPROPANE8
TETRACHLOROETHENE
CIS-1,3-DICHLOROPROPENE
OICHLOROPROPENES
1,3-DICHLOROPROPANE
2,4»DINITROPHENOL
OINITROPHENOLS
2,6-DINlTROPHENOL
16 A
16 A
16 A 040*
16 B 020*
16 A 160* P
16 A 162*
16 6 041*
16 A 140* P
16 A 063*
16 A 082*
16 B 042*
16 A 120* P
21 A 020* P
16 B 040*
16 A 061*
16 A 062*
16 A 081*
16 A 080*
16 A 063*
16 B 043*
16 A 161*
16 A 020* P
02 B 104*
02 A 340* P
02 B 080* P W
02 B 103*
02 B 100*
02 A 343*
20 A 101* P
20 A 100* W
20 A 103*
P W
0
D
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
3.0UE 01
1.5UE 01
l.OOE 02
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.9UE 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.9UE 01
3.90E 01
3.90E 01
3.90E 01
3.30E 02
3.30E 02
3.30E 02
3.3VE 02
3.30E 02
3.30E 02
2.60E 01
2.60E 01
2.60E 01
3.00E 00
3.UOE 00
2.00E 00
2.00E. 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00t 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
2.00E 00
1.70E 00
l./OE 00
1.70t 00
1.70E 00
1.70E 00
l./OE 00
1.30E 00
1.30E 00
I.JOE 00
7.30E 01
7.30k 01
4.83t 01
4.71t 01
4.71E 01
4.71E 01
«.7lb 01
4.71E 01
4.71E 01
4.71E 01
4«7U 01
<*.71E 01
«.7lt 01
4.7U 01
4.71E 01
4.71k 01
4.7U 01
4.71E 01
4.7lt 01
4.71E 01
4.71E 01
4.71E 01
«.7lt 01
4.71k 01
4.71E 01
4.00k 01
4.00k 01
4.00k 01
4.00k 01
4.00k 01
4.00k 01
3.14k 01
3.14k 01
3.14k 01
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
5
b
5
I
M
00
-------
M
I
00
GASIFIER ASH, ECOLOGY IMPACT
DMEG
20 A
10 C
20 A
10 C
10 C
18 A
20 B
16 A
16 A
16 A
16 A
18 A
16 A
18 A
81 A
18 A
16 A
18 A
16 A
20 B
18 A
16 A
20 B
16 A
20 B
16 C
19 B
18 A
18 A
19 B
16 B
16 A
16 C
18 A
NO.
080*
220*
102*
140*
200*
182*
042*
145*
062*
043*
101*
160*
120*
080*
010
161*
140*
102*
060*
020*
100*
143*
040*
144*
041*
040*
020*
103*
183*
022*
020*
001*
063*
063*
w
w
P N
W
W
w
w
P
w
w
P W
«
w
w
M
P
w
COMPOUND NAME
2-AMINO-4,6-DlNlTKOPHENOL
2-AMINONAPH1HALENE
2,5-DINITROPHENOL
BENZIDINE
1-AMINONAPHTHALENE
4rb-DI-TERT-BUTYL-M-CRESOL
2,6-DINlTkO-P-CRESOL
3r5-XYLENUL
M-ETHYLPHENOL
P-CRESOL
0-PHENYLPHENOL
ETHYL CRE30LS
2i2'-DIHVDROXYDIPHENYL
ETHYLPHENULS
ZINC
6-ETHYL-M-CRESOL
XYLENOLS
P-PHENYLPHENOL
2-METHOXYPHENOL
4,b-DlNlTRO-0-CRESOL
PHENYLPHENOLS
2,5-XYLENOL
DINITRO-P-CRESOLS
2»6-XYLENOL
3f5-DINITRO-P-CRESOL
2-NAPHTHOL
CHLORINATED CRESOLS
M-PHENYLPHENOL
2»6-DIMETHYL-4-HEPTYL PHENOL
CHLORINATED-M-CRESOLS
CATECHOL
0-ETHVLPHENOL
5-INDANOL
P-ETHrLPHEMl
TYPE CONC US
E-b G/G
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
T
T
T
1
T
T
T
T
T
T
T
T
T
T
T
T
T
T
2.60E
2.60E
2.60E
2.60E
2.60E
.OOE
.out
.OOE
.OOE
.OOE
.OOE
l.OOE
l.OOE
l.OOE
2. OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
.OOE
.OOE
.OOE
.OOE
.OUE
.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
l.OOE
01 .JOE
01 .JOE
01 .JOE
01 .JOE
01 .JOE
02 l.OOE
02 l.OOE
02 l.OOE
02 l.OOE
02 l.OOE
02 l.OOE
02 l.OOE
02 l.OOE
02 l.OOE
01 l.OOE
02 l.OOE
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
.OOE
.OOE
.OOE
.OOE
.OOE
.out
.uot
.OUE
.OOE
.out
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
00
00
00
uo
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
wDS
b/5
3.14k
.i.iat
3.14E
J.14E
J.i4t
2.42E
2.42E
2.42E
2.42E
2.42E
2.42E
2.42t
2.42t
2.42t
2.42L
2.42E
2.42t
2.42t
2.42E
2.42t
2.4<>E
2.42k
2.42k
2.42k
2.42k
2.42E
2.42k
2.42k
2.42k
2.42k
2.42E
2.42k
2.42k
2.42k
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
LCCAT
5
5
5
5
5
6
6
6
6
6
6
6
6
6
6
6
6
6
b
b
b
b
b
b
b
b
b
b
6
b
b
6
6
-------
GA8IFIEK A8Hr ECOLOGY IMPACT
OMEG NO.
19 A 020* P
18 A 163*
19 040* P
20 060* P
16 160* W
18 042*
18 161*
23 B 080* W
16 C 080* M
16 A 146*
18 C 081*
18 A 041*
16 B 080* N
19 B 023*
18 A 162*
20 A 120*
16 A 040* W
18 A 142* P
16 B 060* W
20 A 040*
18 A 141*
18 C 020* N
16 B 040* N
16 A 020* P N
19 B 021*
16 C 082*
20 A 020* P
26 B 040 M
32 A 010 P
33 A 010
16 B 041*
16 B 020* W
16 A 063*
16 A 160* P
COMPOUND NAME
2-CHLOROPHENOL
2-ETHYl-P-CRESOL
2,4-DICHLOROPHENOL
4-NITROPHENOL
POLYALKYLPHENOLS (MW>135)
0-CRE30L
2,4,6-TRIMETHYL METHYL PHENOL
ACRIDINE
INDANOLS
3»4-XYLENOL
1-INDANOL
M-CRESOL
1,2,3-TRIHYDROXYBENZENE
CHLORINATED-P-CRE80LS
4-ETHYL-O-CRESOL
2»4,6"TRINITROPHENOL
CRESOLS
2»4-XYLENOL
1,4-DIHYDROXYBENZENE
3-NITROPMENOL
2»3-XVLENOL
1-NAPHTHOL
1,3-DIHVDROXYBENZENE
PHENOL
CHLORINATED-0-CRESOL8
4-INDANOL
2-NITROPHENOL
TRITOTYL PHOSPHATES
BERYLLIUM
MAGNESIUM
1,2-BIS(CHLOROMETHYBENZENE
A-CHLOROTOLUENE
l-BROMO-4-CHLOROBENZENE
POLVCHLORINATED BENZENES
TYPE CONC US
E-6 G/G
T l.OOE 02
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
8
D
T
T
T
T
.OOE 02
.OUE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 00
.OOE 02 l.OOE 00
.OOE 02 l.OOE 00
.OOE 02 l.OOE 00
.70E 01 8.SOE-01
.OOE 00 8.20E-01
.30E 04 7.64E-01
.50E 01 7.bOE-01
.50E 01 7.&OE-01
.50E 01 7.50E-01
.SOE 01 7.50E-01
HDb LCCAT
G/3
2.42t 01
2.42t 01
2.42k 01
2.42t 01
2.42E 01
2.42E 01
2.42E 01
2.42t 01
2.42E 01
2.42E 01
2.42k 01
2.42E 01
2.42E 01
2.42E 01
2.42E 01
2.42E 01
2.42k 01
2.42E 01
2.42E 01
2.42E 01
2.42k 01
2.42E 01
2.42E 01
2.42k 01
2.42E 01
2.42E 01
2.42k 01
2.10k 01 7
2. OOE 01
1.90k 01
1.61k 01 2
l.blk 01 2
1.61k 01 2
1.61k 01 2
00
-------
00
OMfcG NO.
GASIFIEK ASH, ECOLOGY IMPACT
COMPOUND NAME TYPE
CUNC
E-6 6/G
NDS
tt/S
LCCAT
16 A 040*
16 A 063*
16 A 100* P
16 A 140* P
16 A 062*
16 B 040*
16 A 061*
16 A 062*
21 A 020* P
16 A 060*
16 A 120* P
16 A 020* P
16 B 043*
16 A 060*
16 A 161*
16 A 061*
16 B 042*
16 A 162*
27 A 010
06 0 120*
10 A 060* M
06 0 12?*
06 D 142*
06 A 040* W
06 0 123*
06 0 143*
10 C 020*
06 0 141*
08 0 121*
06 D 140*
46 A 010 P
74 A 010
Id A 145*
J6 A 060* N
B
1
1
1
1
B
1
1
N
0
1
C
1
B
1
1
1
H
L
B
1
S
S!
Al
I
I
Al
N<
N<
Al
Lf
CC
I,
2»
BROMOBENZENE
1,4-DIBROMOBENZ£NE
1»2»DICHIOROBENZENE
4-DICHLOROBENZENE
1-BROMO-3»CHLOROBENZENE
BIS(CHLOROMETHYL)BENZENES
l»BROMO-2-CHLOROBENZENE
1»3-DIBROMOBENZENE
NAPHTHALENE
01BROMOBENZENES
li3-OICHLOROBENZENE
CHLOROBENZENE
1»4-BI3(CHLOROMETHYL)BENZENE
BROMOCHLOPOBENZENES
1,2,4-TRICHLOROBENZENE
lt2-DIBROMObENZENt
lr3-BIS(CHLOROMETHYL)BENZENE
HEXACHLORUBENZENE
LITHIUM
BUTYL ACETATES
1/2-DIAMINOETHANE
SEC-BUTYL ACETATE
SEC-AMYL ACETATE
ACETIC ACID
ISOBUTYL ACETATE
ISOAMYL ACETATE
ANILINE
N-AMYL ACETATE
N-BUTYL ACETATE
AMYL ACETATES
LEAD
COBALT
3,5-XrLENOl
T
Y
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
s
T
T
T
T
T
T
T
.50E 01
.50t 01
.SOE 01
.sot 01
.SOE 01
.sot 01
.SOb 01
.SOE 01
.SOE 01
.SOE 01
.SOE 01
.SOE 01
.SOE 01
.SOE 01
.SOE 01
.SUE 01
.SOE 01
.SOE 01
.60E 01
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
.OOE 02
T l.OOE 02
T l.OOE 02
T l.OOE 02
T l.OOE 02
S S.OOE 00
S 2.30E 01
T 2.60t 01
T 2.60E 01
7.SOE-01 l.blt 01
7.50E-01
7,bOE-01
7.50E-01
7.SOE-01
7.SOE-01
7.SOE-01
7.50E-01
7,bOE-01
7.50E-01
7.SOE-01
7.SOE-01
7.bOE-01
7.50E-01
7.bOE-01
.81E 01
.bit 01
.bit 01
.bit 01
.bit 01
.bit 01
.bit 01
.bit 01
.bit 01
.bit 01
.bit 01
.bit 01
.bit 01
.bit 01
7.SOE-01 l.blt 01
7.bOE-01 l.blt 01
7.50E-01
6.40E-01
S.OOE-01
S.OOE-01
S.OOE-01
S.OOE-01
5.00E-01
S.OOE-01
5.00E-01
S.OOE-01
5.00E-01
S.OOE-01
5.00t-01
5.00E-01
4.60E-01
.bit 01
,S4t 01
.21t 01
.21t 01
.21E 01
.21t 01
.21t 01
.21E 01
.21E 01
.21E 01
.21t 01
.2lt 01
.2lt 01
.21t 01
.lit 01
2.60E-01 6.30t 00
2.60E-01 6.30t 00
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
6
6
6
6
6
6
6
6
6
b
6
5
5
-------
GASIFIER ASH, ECOLOGY IMPACT
DMEG NO.
16 C 083*
18 A 103*
18 A 146*
18 A 043*
20 B 041*
18 C 040*
18 C 060*
18 A 101*
IB A 082*
18 A 161*
20 A 120*
19 B 021*
18 C 020*
18 A 042*
18 A 081*
23 B 080*
18 A 102*
18 A 181*
18 A 080*
18 A 160*
18 C 082*
18 A 140*
19 B 023*
18 A 162*
19 B 020*
16 A 100*
19 A 040* P
18 A 143*
20 B 040*
16 A 144*
18 A 180*
18 B 040*
18 A 063*
20 B 042*
COMPOUND NAME
5-INDANOL
M-PHENYLPHENOL
3,4-XYLENOL
P-CHESOL
3,5-DlNITRO-P-CRESOL
N 2-NAPHTHOL
N INDANOLS
0-PHENYLPHENOL
M-ETHYLPHENOL
6-ETHYL-M-CRESOL
2,4,6-TRINITROPHENOL
CHLORINATED-0-CRESOLS
W 1-NAPHTHOL
0-CRESOL
0-ETHYLPHENOL
N ACRIDINE
P-PHENVLPHENOL
2,4,6-TRIMETHYL METHYL PHENOL
M ETHYLPHENOLS
W ETHYL CRESOLS
4-INDANOL
N XYLENOL3
CHLORINATED-P-CRESOL3
4-ETHYL-O-CRESOL
M CHLORINATED CRE3UL3
M PHENYLPHENOLS
2, 4-DICHLOROPHENOL
2r5-XYLENOL
W OINITRO-P-CRE30L3
2,6-XYLENOL
M POLYALKYLPHENOL3 (MWM35)
H 1,3-DIHVDROXYBENZENE
P-ETHYLPHENOL
2,6-DINHRO-P-CRE80L
TYP
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
E CONC
t-b (i/G
2.60t 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60t 01
2.60E 01
2.60E 01
2.60E 01
2.6UE 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2. bUt 01
US
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-U1
2.60E-01
2.60E-01
2.60E-01
2.60E*01
2.60E-01
2.60E-01
2.60E-U1
2.60E-01
2.60E-01
2.60E-01
2.60k-01
2.60O01
2.60E-01
2.60E-01
2.C»OE-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
WDS
U/5
6. 30t 00
6.30L 00
6.30L 00
6.30E OQ
6.30E 00
6.30b 00
6.30t 00
6.30E 00
6.30k 00
6.30b 00
6.30E 00
6.30t 00
6.30k 00
6.30E 00
6.30b 00
6.30b 00
6.30k 00
6.30k 00
6.30k 00
6.30k 00
6,30k 00
6.30k 00
6.30E 00
6.30k 00
6.3Uk 00
6.30k 00
6.30k 00
6.30k 00
6.30k 00
6.30E 00
6.30E 00
6.30k 00
6.30k 00
6.30E 00
LCCAT
5
5
5
5
5
S
5
5
5
5
5
5
5
5
S
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
00
Ln
-------
w
I
GASIFJEH ASH, ECOLOGY IMPACT
OMEG
16 A
19 B
18 B
18 A
16 A
16 B
20 B
18 A
19 A
20 A
16 A
20 A
18 C
18 A
20 A
18 A
16 A
16 A
16 B
15 B
15 B
15 A
15 B
15 A
15 A
15 b
15 B
15 B
15 8
15 B
15 B
15 B
15 B
15 A
NO.
120* W
022* P
020* W
041*
163*
060* W
020* P W
040* W
020* P
060* P
020* P W
020* P
081*
163*
040*
162*
142* P
141*
060* W
101*
082*
060* P W
104*
120* W
080* W
080* W
081*
103*
102*
106*
100* W
120* W
063*
040* P W
COMPOUND NAME
2.2'-OIHYDROXYDIPHENYL
CHLORINATED-M-CRESOLS
CATECHOL
M-CRESOL
2-ETHYL-P-CRESOL
1,2, 3-TRIHYDROXYBENZENE
4,6-DINITKO-O-CRESOL
CHESOLS
2-CHLOHOPHENOL
4-NITROPHENOL
PHENOL
2-NITROPHtNOL
1-INDANOL
2,6-DIM£THYL-4-HtPTYL PHENOL
3-NITROPHENOL
4,6-DI-TERT-BUTYL-M-CRESOL
2,4-XYLENOL
2,3-XYLENOL
1, 4-DIHYDHOXYBENZENE
0-DIETHYL BENZENE
M-XYLENE
ETHYL BENZENE
0-DIISOPROPYL BENZENE
ISOPHUPYL BENZENE
STYRENE
XYLENES
0-XYLENE
P-DIETHYL BENZENE
M-DIETHYL BENZENE
1,4-DI-TERT-BUTYL BENZENE
DIALKYL BENZENES (MMtl34-19U
TETRAHYDRONAPHTHALENE
P-XYLENE
TOLUENE
TYPE CONC
E-6 G/G
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.6UE
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
3.90E
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
DS
2.00E-01
2.60E-01
2.60E-01
2.60E-W1
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60fc-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.60E-01
2.00E-01
2.60t-01
2.0Ut-01
2.00E-01
2.00E-U1
2.00E-01
2.00E-01
2.00E-01
2.00t-01
2.00t-01
2.00E-01
2.00E-01
2.00E-01
2.00E-01
2.00E-01
2.UOE-01
2.00E-CI1
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
4
a
a
4
4
4
4
4
4
4
4
4
4
•
•
•
•
•
•
•
•
•
•
•
0
•
•
•
•
•
•
•
•
•
0
•
•
•
•
•
•
•
•
•
•
4.
4,
•
u/s
30t
30t
30t
30t
30E
30t
30t
30t
30t
30t
30t
30t
3oE
30h
30fc
30t
30E
30E
30t
71E
7lt
7lt
7lfc
7lt
71t
7lt
71t
71t
7lt
71h
71t
7lt
71E
71E
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
LCCAT
b
5
5
b
5
5
5
5
b
5
5
5
5
5
b
b
b
b
5
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
-------
GA8IFUR A8H, ECOLOGY IMPACT
DME6 NO.
15 B 105*
15 A 100* N
01 A 201
01 A 200
85 A 010
15 B 020*
17 A 040* M
17 A 085*
08 0 140*
08 0 14f*
17 041*
17 043*
08 143*
04 040* W
17 083*
10 080* M
17 020* P W
17 086*
08 D 142*
04 A 050* M
10 C 020*
17 A 042*
08 D 122*
17 A 081* P
08 D 123*
17 A 084* P
08 D 121*
08 0 120*
08 A 040* W
04 A 060* M
17 A 082*
17 A 080* W
04 A 050* M
04 A 040* M
COMPOUND NAME
M-OIISOPROPYL BENZENE
PROPYL BENZENE
N-OCTANE
OCTANES
URANIUM
INDAN
NITROTOLUENE8
2»5-DINlTROTOLUENE
AMYL ACETATES
N-AMYL ACETATE
2-NITROTOLUENE
4-NITROTOLUENE
ISOAMYL ACETATE
2-CHLORO- 1 » 2-EPOX YPROPANE
2,3-DINlTHOTOLUEN£
1,2-DIAMINOETHANE
NITROBENZENE
3»5-DINITROTOLUENE
SEC-AMYL ACETATE
EPICHLORHYORIN
ANILINE
3-NITROTOLUENE
SEC-BUTYL ACETATE
2,6-DlNlTROTOLUENE
ISOBUTYL ACETATE
2*4-DINITROTOLUENE
N-BUTrL ACETATE
BUTYL ACETATES
ACETIC ACID
t-CHLORO-1 t 3-EPOXYPROPANE
3,4-DINlTROTOLUENE
DINITROTOLUENES
EPICHLORHYDRIN
2-CHLORO- 1* 2-EPOX YPROPANE
TYPE
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
CONC US
E-6 6/G
3.90E 01 2.00E-01
3.90k 01 2.00E-01
3.30E 02 1.70E-01
3.30E 02 1.70E-01
1.60E 01 1.60E-01
3.90E 01 1.40E-01
2.60E 01 1.30E-01
2.60E 01 1.30E-01
2.60E 01 1.30E-U1
2.60E 01 1.30E-01
2.6UE 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.6UE 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.6UE 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.60E 01
2.00E 01
2.00E 01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.3UE-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.UOE-01
.UOE-01
WDS
U/8
4.71t 00
4.71k 00
4.00k 00
a. out oo
3.90t 00
3.40C 00
3.14k 00
3.14k 00
3.14k 00
3.14t 00
3.14k 00
3.14E 00
3.14t 00
3.14k 00
3.14E 00
3.14E 00
3.14k 00
3.14k 00
3.14E 00
3.14k 00
3.14k 00
3.14k 00
3.14k 00
3.14k 00
3.14k 00
3.14k 00
.14k 00
.14k 00
.14k 00
.14k 00
.14k 00
.14k 00
2.41k 00
2.41k 00
LCCAT
3
3
1
1
3
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
S
5
5
5
5
5
5
5
4
4
00
-o
-------
00
00
GASIFIER ASH, ECOLOGY IMPACT
OMEG
NO.
COMPOUND
NAME
T
YPE
CONC
E-6 G/G
US
WDS
G/8
LCLAT
17 A
17 A
17 A
17 A
17 A
17 A
17 A
17 A
17 A
17 A
17 A
04 A
17 A
08 A
15 B
15 B
15 A
15 B
02 B
15 B
02 A
02 B
15 B
02 A
15 B
15 B
15 A
15 B
15 B
02 B
IS A
15 B
02 B
15 B
080*
042*
083*
020*
084*
041*
040*
086*
082*
081*
085*
060*
043*
040*
083*
105*
060*
103*
103*
106*
340*
104*
081*
343*
120*
102*
120*
080*
082*
100*
040*
104*
oao*
101*
M
P W
P
W
P
M
M
P M
P
N
H
W
P M
P W
P W
DINITROTOLUENES
3-MTROTOLUENE
2r3-OlNlTROTOLUENE
NITROBENZENE
2r4-DlNlTROTOLUENE
2-NITROTOLUENE
NITROTOLUENES
3f5-DIMTROTOLUENE
3f4-DINlTROTOLUENE
2r6-DINITROTOLUENE
2»5-DIMTROTOLUENE
1-CHLORO-1,3-EPOXYPKOPANE
4-NITROTOLUENE
ACETIC ACID
P-XYLENE
M-DIISOPROPYL BENZENE
ETHYL BENZENE
P-DIETHYL BENZENE
CIS-1,3-DICHLOROPROPENE
1»4-DI-TERT-BUTYL BENZENE
OICHLOROPROPANES
TRANS-1,3-DICHLOROPROPENE
O-XYIENE
1,3-DICHLOROPROPANE
TETRAHYDRONAPHTHALENE
M-OIETHYL BENZENE
ISOPROPYL BENZENE
XYLENES
M-XYLENE
OICHLOROPROPENES
TOLUENE
O-OIISOPROPYL BENZENE
TETRACHLOHOfcTHENE
0-OIETHYL BkNZENE
T 2.00E
T 2.00E
T 2.00E
T 2.00E
T 2. Out
T 2.00E
T 2.00E
T 2.00E
T 2.00E
T 2.00E
T 2.00E
T 2. Out
T 2. Out
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
»
T
T
T
T
T
.70E
.SOE
.SOE
,50t
.50E
.50E
.50E
• SUE
.SOE
.SOE
.SOE
.SOE
.SOE
.SOE
.SOE
.SOE
.SOE
.SOE
.SOE
.SOE
.SOE
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
1
1
1
1
1
1
1
1
1
1
1
1
1
8
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
OOE-01
oot-oi
OOE-01
OOE-01
bOE-02
50E-02
50E-02
bOt-02
50E.-02
50E-02
50E-02
50E-02
bOE-02
bO£-02
50E-02
!>OE-02
bOE-02
bOE-02
bOE-02
bOE-02
!>OE-02
.bOt-02
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1
1
1
1
1
1
1
1
1
.41t
.41E,
.41t
.41t
,41t
.41t
.ait
.«Ut
.41t
,41t
.41E
• 41t
.41t
.10t
.«lt
,»lt
.81E
.Bit
.81t
,81t
,61fc
.tilt
.eit
.ttlE
.ait
.bit
.ait
.ait
.bit
.«U
.bit
7.SOE-02 l.ttlt
7.SOE-02
7.50E-02
1,
,bU
1.816
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
4
4
4
4
4
4
4
4
4
4
4
4
4
7
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
-------
GASIFIEK ASH, ECOLOGY IMPACT
OMEG NO.
15 A 100*
15 B 100*
15 A 080*
08 A 080*
79 A 010
08 A 104*
08 A 101*
08 A 102*
08 A 100*
08 A 103*
15 B 020*
08 A 180*
05 A 124*
23 A 064*
08 D 080*
10 A 060*
23 A 080*
23 A 122*
08 D 101*
06 A 020*
08 B 060*
05 A 123*
05 A 122*
23 A 063*
23 A 020*
10 B 100*
23 A 082*
10 A 160*
23 A 083*
23 A 120*
23 A 121*
23 A 062*
23 A 081*
23 A 060*
i
t~^
00
COMPOUND NAME
N PROPYL BENZENE
W DIALKYL BENZENES (MM* 134*191)
M STYRENE
VALERIC ACID
P SILVER
LAURIC ACID
CAPROIC ACID
CAPRYLIC ACID
SATURATED LONG CHAIN ACIDS (MW»ll6-201)
CAPRIC ACID
INDAN
ADIPIC ACID
3-METHYL-l-BUTANOL
4-N-PROPYLPYRIDINE
METHYL METHACRYLATE
ETHANOLAMINE
W PHENYLPYRIDINES
2,4,6-COLLIDINE
N-PROPYL ACETATE
M ETHYLENE GLYCOL
W B-PROPIOLACTONE
2r2-DIMETHYL-l-PROPANOL
2-METHYL-l-BUTANOL
4-ETHYLPYRIDINE
N PYRIDINE
MORPHOLINE
3-PHENYLPYRIDINE
CYCLOHEXYLAMINE
4-PHENYLPYRIDINE
W COLLIDINES
5-ETHYL-2-METHYLPYRIDINE
3-ETHYLPYRIDINE
2-PHENYLPYRIDINE
W MONOSUBSTITUTED ALKYL PYRIDINE8
TYPE
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
CONC
E-6 G/G
1.50E 01
1.50E 01
1.50E Ul
l.OOE 02
6.00E-01
l.OOE 02
l.OUE 02
l.OOE 02
l.OOE 02
l.OOE 02
1.50E 01
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OOE 02
l.OUE 02
US
7.bUE-02
7.bOL-02
7.bOE-02
6.70&-02
b.UOE-02
5.60E-U2
b.bUE-02
b.bOi-02
5.60E-02
b.60E-U2
5.40E-U2
5.30E-02
5.00E-02
5.0UE-U2
5.00E-02
5.00E-02
b.OOE-02
5.00E-02
5.00E-02
5.00E-02
5.00E-02
5.00E-02
b.OOE-02
5.UOE-02
5.00E-02
5.00E-02
5.00E-02
5.00E-02
5.00E-02
5.00E-02
5.00E-02
5.00E-02
5.00E-02
b.OOE-02
WDb
U/5
l.ttlt UO
1.61L UO
l.Blt UO
l.blt 00
l.SOfc. UO
1.34E UO
1.34L UO
1.34t UO
1.34t UO
1.34fc UO
I.JOE uo
1.30E UO
1.20t 00
1.20t 00
1.20E 00
1.201: UO
1.20E UO
1.20E 00
1.20fc UO
1.20E UO
1.20E 00
1.20E 00
1.20E 00
1.20E 00
1.20fi 00
1.20k 00
1.20E 00
1.20E 00
1.20k UO
1.20E 00
1.20k 00
1.20E 00
I. dOt 00
1.201: 00
LCCAT
2
2
2
b
b
6
b
6
6
2
6
6
6
6
b
6
6
6
b
b
6
b
6
6
6
6
6
6
6
6
6
6
6
-------
M
I
GASIFIER ASH, ECOLOGY IMPACT
DM(
05
08
23
05
05
05
07
37
83
07
08
15
15
15
15
08
09
09
09
09
06
08
06
06
08
06
23
23
05
05
06
10
23
23
•G
A
D
A
A
A
A
B
A
A
B
A
B
B
B
b
A
B
B
b
B
A
A
A
A
A
A
A
A
A
A
0
A
A
A
NO.
100* H
100*
061*
140* M
120* M
121*
100* H
010
010 P
120
140
201
203
200
202
080*
020* W
042*
041*
040* M
103*
100*
102*
101*
104*
180*
081*
064*
123*
140* H
060*
160*
060* M
083*
COMPOUND NAME
ISQBUTYL ALCOHOL
PROPYL ACETATES
2-ETHYLPYRIDINE
BENZYL ALCOHOL
PkNTANOLS (PRIMARY)
N-PENTANOL
CAMPHOR
BORON
MtRCURY
ACETOPHENONE
OLEIC ACID
l,2,3»4-TETRAMETHYLBENZENk
1,2,4,5-TETKAMETHYLttENZENk
TETRAMETHYLBENZENES
l,2f3,5-TETRAMETHYLBENZENE
VALERIC ACID
BENZONITRILE
B-NAPHTHONITRILES
A-NAPHTHONITRILES
NAPHTHONITHILES
CAPRIC ACID
SATURATED LONG CHAIN ACIDS (MWtll6-201)
CAPRYLIC ACID
CAPROIC ACID
LAURIC ACID
ADIPIC ACID
2-PHENYLPYRIDINE
4-N-PROPYLPYRIDINE
2»2-DIMETHYL-l-PKOPANUL
BENZYL ALCOHOL
METHYL METHACHYLATE
CYCLOHEXYLAMINE
MONOSUBSTITUTED ALKYL PYRIDINES
«-PH£NYLPVKIDlNfc
TYPE CONC
E-6 G/G
T
T
T
T
T
T
T
D
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
I.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.OOE
.10E
,70E
.OOE
.OOE
3.90E
3.90E
3.90E
3.90E
2.60E
2.60k
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60k
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
02
02
02
02
02
02
02
02
00
02
02
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
b
5
5
5
5
5
4
4
3
3
2
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
US
.OOk-02
.OOk-02
.OOE-02
.OOk-02
.OOE-02
.OOE-02
,54k-02
.20E-02
,40k-02
,22t-02
.43E-U2
.OOE-02
.OOk-02
.OOE-02
.OOk-02
,73k-02
.62E-02
.62E-02
.62k-02
.62E-02
,44k-02
.4UE-02
,4
-------
GA81FIEH A8Hi ECOLOGY IMPACT
OMEG
23
06
23
05
17
17
23
10
06
03
05
23
06
06
05
23
10
23
23
05
04
04
23
05
23
09
09
09
09
07
06
69
50
04
A
B
A
A
B
B
A
B
A
B
A
A
D
D
A
A
A
A
A
A
B
B
A
A
A
B
B
B
B
B
A
A
A
B
NO.
060*
060*
063*
100*
060
040
120*
100*
020*
020
124*
062*
100*
101*
120*
121*
060*
062*
122*
122*
040* P
060
020*
121*
061*
042*
041*
040*
020*
100*
060*
010
010 P
040* P
tt
N
W
W
M
W
M
M
W
M
W
M
M
W
M
COMPOUND NAME
PHENYLPYRIDINES
B-PROPIOLACTONE
4-ETHYLPYRIDINE
ISOBUTYL ALCOHOL
l-CHLORO-4-NITROBENZENE
l-CHLORO-2-NITROBENZENE
COLLIOINES
MORPHOLINE
ETHYLENE GLYCOL
1,4-DIOXANE
3-METHYL-l-BUTANOL
3-PHENYLPYRIDINE
PROPYL ACETATES
N-PROPYL ACETATE
PENTANOLS (PRIMARY)
5-ETHYL-2-METHYLPYRIOINE
ETHANOLAMINE
3-ETHYLPYRIOINE
2»4,6-COLLIDINE
2-METHYL-l-BUTANOL
l,l'-DICHLORODIETHYL ETHER
2,2'-DICHLORODIETHYL ETHER
PYRIOINE
N-PENTANOL
2-ETHYLPYRIDINE
B-NAPHTHONITRILES
A-NAPHTHONITRILE8
NAPHTHONITRILES
BENZONITRILE
CAMPHOR
VALERIC ACID
MOLYBDENUM
ANTIMONY
1,1'-DICHLORODIETHYL ETHER
TYPE CONC
E-6 G/G
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
8
D
T
2.60E
2.60E
2.60E
2.60E
2.60E
2.6UE
2.6UE
2.60E
2.6UE
2.60E
2.6UE
2.6UE
2.6UE
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60E
2.60L
2.0UE
2.00E
2.0UE
2.00E
2.6UE
1.70E
1.50E
US
01 1.30E-02
01 1.30E-02
01 1.30E-02
01 l.JOfc-02
01 l.JOE-02
01 1,
30E-02
01 1.30E-02
01 1.30E-02
01 1.30E-02
01 1.30E-02
01 1.30E-02
01 1.30E-02
01 1.30E-02
01 1.30E-02
01 1.
01 1.
01 1.
01 1.
01 1.
01
01
01
01
01
01
01
01
01
01
01
01
•
•
•
•
•
•
•
•
•
•
•
•
01 1.
< 4.00E-OK 1.
2.00E
01 1.
30E-02
30E-02
30E-02
30E-02
30E-02
30E-02
30E-02
30E-02
30E-02
30E-02
30E-02
30E-02
30E-02
iOE-02
iOE-02
20E-02
13E-U2
10E-02
OOE-02<
OOE-02
*D8
(*/3
3.14E-01
3.14E-01
3.l4t-01
3.14E-01
3.14&-U1
3.14h-01
3.14E-01
3.14L-01
3.14E-01
3.14L-01
3.l4k-01
3.14E-01
3.14E-01
3.14L-U1
3.14E-01
3.14E-01
3.14E-01
3.14E-01
3.14E-01
3.14E-01
i.Ut-Oi
3.14E-01
3.14E-01
3.14E-01
3.l4t-01
3.02E-01
3.02OU1
3.02b-Ul
3.02L-01
2«9(Jt-01
2.74b-0l
2.60L-01
2.4U-01
2.41E-01
LCCAT
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
S
5
5
5
5
5
5
5
4
4
4
a
5
7
4
pi
h4
vO
-------
I
M
ro
GA3IFIEK ASH, ECOLOGY IMPACT
DMEG NO.
08 0 520* P
08 D 320* P
28 A 010
12 A 040* P
12 A 040* P
02 B 140* P
02 B 120* P
02 B 120* P
12 A 060* P
12 A 060* P
04 B 020* P
56 A 010
39 A 010
04 A 160* P
29 A 010
04 A 180* P
35 A 010
45 A 010
70 A 010
12 A 020* P
04 A 160* P
04 A 140* P
04 A 180* P
43 A 010
64 B 010
44 A 010
02 B 140* P
59 A 010
84 A 010
84 F 010
57 A 010
16 A 200* P
21 A 120* PH
04 fl 0*0* P
COMPOUND NAME
BUTYL BENZYL PHTHALATE
BUTYL BENZYL PHTHALATE
SODIUM
N-NITROSODIETHYLAMINE
N-MTROSOOIETHYLAMINE
HEXACHLOROCYCLOPENTAQIENE
HEXACHLOROBUTADIENE
HEXACHLOROBUTADIENE
N-NITROSODIPROPYLAMINE
N-NIThUSOOIPROPYLAMlNE
If I'-DICHLOROMETHYL ETHER
FLUORINE (AS F-)
GALLIUM
A-CHLOROBUTYL ETHYL ETHER
POTASSIUM
CHLOROPHENYL PHENYL ETHER
STRONTIUM
TIN
TUNGSTEN
N-NITROSODIMETHYLAMINE
A-CHLOROBUTYL ETHYL ETHtR
2-CHLOROETHYL VINYL ETHER
CHLOROPHENYL PHENYL ETHER
SILICtN
CERIUM
GERMANIUM
HEXACHLOROCYCLOPENTAQIENE
IODINE (AS I-)
LANTHANUM
DYSPROSIUM
CHLORINE (AS CL-)
CHLORONAPHTHALENES
ACENAPHTHN.ENE
Jr-l'-DJCHiOKOMETHn ETHER
TYP
T
T
D
T
T
T
T
T
T
T
T
S
S
T
D
T
D
S
S
T
T
T
T
D
S
S
T
S
S
S
D
T
T
T
E CUNC
E-6 G/G
l.OOE 02
2.60E 01
l.aOE 04
l.OOE 02
2.60E 01
3.30E 02
1.50E 01
3.30E 02
2.60E 01
l.OOE 02
2.60E 01
1.90E 02
9.00E 00
2.60E 01
6.60E 03
2.60E 01
1.90E 03
5.00E-01
l.OOE 00
2.60E 01
2.00E 01
2.60E 01
2.00E 01
1.40E 05
1.10E 02
l.OOE 00
1.50E 01
2.00E-01
1.10E 02
7.00E 00
l.SOE 02
3.90E 01
I.SUE 01
2.00E 01
OS
5.00E-03
1.30E-03
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-U1
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
WD8
li/8
1.20t-01
3.14t-02
O.OOE-01
O.OOb-01
O.OOt-01
O.OOt-01
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-01
O.OOt-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-01
o.oot-oi
O.OOE-01
O.OOt-01
o.oot-oi
LCCAT
6
b
6
5
1
2
1
5
6
5
5
5
5
4
5
4
2
3
2
4
-------
GA3IFIEK ASM, ECOLOGY IMPACT
DMEG NO.
21 A 140* P
ou A 140* P
21 A 180*
16 A 200*
63 A 010
12 A 020*
21 B 120*
21 B 120*
21 B 180*
53 A 010
21 A 160*
21 B 040*
58 A 010
21 C 100* P
21 0 080* PH
31 A 010
21 A 140* P
22 A 020* PH
22 B 040*
22 B 040*
22 C 020*
22 C 020*
22 C 080*
64 A 010
22 D 020* P
22 D 020* P
21 C 080* P
21 A 100* PH
21 A 100* PH
84 0 010
21 A 120* PH
66 A 010
84 C 010
30 A 010
COMPOUND NAME
ANTHRACENE
2-CHLOROETMYL VINYL ETHER
PHENANTHRENE
CHLORONAPHTHALENES
ZIRCONIUM (AS ZR+4)
N-NITROSOOIMETHYLAMINE
CHRYSENE
CHRYSENE
PYRENE
SULFUR
PHENANTHRENE
BENZ(A)ANTHRACENE
BROMINE
BENZO(A)PYRENE
BENZO(6HI)PERYLENE
CESIUM
ANTHRACENE
FLUORENE
FLUORANTHENE
FLUORANTHENE
BENZO(K)FLUORANTHENE
BENZO(K)FLUORANTHENb
BENZO(8)FLUOKANTHENb
HAFNIUM, (AS HF+4)
INDENO(l,2,3-CD)PYRENE
INDENO(1,2«3*CD)PYRENE
DIBENK A, H) ANTHRACENE
ACENAPHTHENE
ACENAPHTHENE
NEOOYMIUH
ACENAPHTHYLENE
NIOBIUM (AS NBt3)
PRASEODYMIUM
RUBIDIUM (AS RBt)
TYPE
T
T
T
T
S
T
T
T
T
D
T
T
S
T
T
S
T
T
T
T
T
T
T
S
T
T
T
T
T
S
T
S
8
S
CONC
E-6 G/G
l.Sub 01
2.00E 01
1.5UE 01
1.50E 01
1.80E 02
l.OOE 02
1.5UE 01
3.90E 01
1.50E 01
8.80E 03
3.90E 01
1.50E 01
2. CUE 00
3.90E 01
1.50E 01
8.00E 00
3.90E 01
3.90E 01
1.50E 01
3.90E 01
1.5UE 01
3.90E 01
1.50E 01
l.OOE 00
1.50E 01
3.90E 01
3.90E 01
1.50E 01
3.90E 01
3.00E 01
3.90E 01
3.10E 01
1.60E 01
4.70E 01
us
O.OOE-01
o.uoE-oi
O.OOE-01
O.UOE-01
O.OOE-01
u.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-OI
O.OOE-01
O.OOE-OI
O.UOb-01
o.oob-oi
O.OOE-01
O.OUE-01
o.oot-ui
O.OOE-OI
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oob-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
NDS
b/8
O.OOb-Ul
o.uot-ui
o.oot-oi
o.uob-ui
O.OOb-01
O.OOb-01
o.oot-oi
O.OOL-01
O.UOb-01
U.UOh-Ul
o.oot-oi
o.oot-oi
O.OQt-01
o.oot-oi
O.OOb-01
O.OOE-01
O.OOb-01
O.OOb-01
O.OOb-01
O.OOE-01
O.OOb-01
O.OOE-01
O.OOb-01
O.OOb-01
O.OOb-01
O.OOb-01
O.OOE-01
O.OOb-01
O.OOb-01
O.OOE-01
O.OOb-01
o.oofc-oi
O.OOE-OI
O.OOb-01
LCCAT
2
4
2
2
6
2
3
2
3
2
3
2
3
3
2
3
2
3
2
2
3
3
2
3
3
-------
I
M
VO
GASIFIER ASH, ECOLOGY IMPACT
UMEG
84
60
21
85
08
08
21
21
61
21
07
07
21
22
02
02
02
02
02
02
22
E
A
e
B
0
0
B
c
A
c
B
B
0
A
A
A
A
A
A
A
C
NO.
010
010
040*
010
500*
300*
180*
060*
010
100*
080*
080*
080*
020*
140*
140*
160*
160*
320*
320*
080*
P
P
P
P
P
P
P
P
PH
PH
P
P
P
P
P
P
P
COMPOUND NAME
SAMARIUM
SCANDIUM
BENZ(A)ANTHRACENE
THORIUM
OI-2-ETHYLHEXYL PHTMALATE
DI-2-ETHYLHEXYL PHTHALATE
PYRENE
DIBENZC A, H) ANTHRACENE
YTTRIUM (AS Y + 3)
BENZO(A)PYRENE
ISOPHORONE
ISOPHORONE
BENZO(GHI)PERYLEN£
FLUORENE
DIBROMOCHLOROMETHANE
DIBROMOCHLOROMETHANE
BKOMOFORM
BROMOFORM
HEXACHLORUETHANE
HEXACHLOROETHANE
BtNZO(B) FLUOR ANTHENt
TYPE CONC
£-6 G/G
S
S
T
S
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
1
2
3
2
2
1
3
1
5
1
2
1
3
1
3
1
3
1
3
1
3
.30E
.OOE
.90E
.30E
.60E
.OOE
.9UE
.50E
.90E
.50E
,6'JE
.OOE
.90E
.50E
.30E
.50E
.30E
.SUE
.30E
.50E
,90E
01
01
01
01
01
02
01
01
01
01
01
02
01
01
02
01
02
01
02
01
01
DS
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
O.UOE-01
O.OOE-01
O.UOE-U1
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.UOE-01
o.yoE-oi
O.OOE-01
WDS
b/S
o.oot-oi
o.uot-oi
O.OOE-01
O.OOt-01
U.OOt-01
o.oot-oi
O.OOE-01
o.oot-oi
O.OOL-01
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-U1
o.oot-oi
O.OOfc-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
U.OOE-01
LCCAT
3
5
6
3
2
2
b
6
3
2
1
2
1
2
1
2
3
-------
CYCLONE DUST
AVERAGE FLOW RATE • 3.8 G/8
207.15 6 EXTRACTED TOTAL ORGANIC LOADING 8 13 G/KG
TOTAL TCO * 0,66 G/KG TOTAL GRAV • 12.0 G/KG
3.4X ORIGINAL SAMPLE TO LC
LC TCO s 3.2 MG LC GRAV • 88.2 MG LC TOTAL • 91.4 MG
LCCAT ORGANIC LOADING
1 2600.0
2 140.0
3 1300*0
4 1400.0
5 770.0
6 3400,0
7 UOO.O
FLOW RATE • 3.80
STATES SOLID, UNITS IN MICR06RAM8/G
IMPACTS HEALTH
EXPERIMENTAL* DETERMINED DATA
SPARK SOURCE DATA
•p
M
SO
cn
-------
CYCLONE OUST, HfcALTM IMPACT
DHEG
16 A
16 A
21 C
21 C
19 A
19 A
20 B
19 A
16 A
19 B
16 C
18 A
16 A
18 A
18 A
18 A
16 A
20 A
18 A
20 A
18 A
20 A
16 A
20 A
18 A
20 A
18 A
20 A
16 A
20 A
18 A
20 A
16 A
20 A
NO.
220*
220*
100*
080*
020*
O4o*
041*
060*
042*
020*
083*
020*
060*
040*
080*
041*
081*
020*
062*
040*
063*
060*
100*
080*
101*
100*
102*
101*
103*
102*
120*
103*
140*
120*
w
w
P W
p
P W
P W
P W
w
P W
w
w
w
P H
w
P W
H
W
w
p
w
w
w
COMPOUND NAME
POLYCHLORINATED BIPMENYLS
POLYCHLORINATEO BIPHENYLS
BENZU(A)PYRENE
DIBENZC A, H) ANTHRACENE
2-CHLOROPHENOL
2»4-DICHLOROPHENOL
3f 5-DINITRO-P-CRESOL
PkNTACHLOROPHENOL
0-CRESOL
CHLORINATED CRESOLS
5-INDANOL
PHENOL
2-METHOXYPHENOL
CRESOLS
ETHYLPHENOLS
M-CRESOL
0-ETHYLPHENOL
2-NITROPHENOL
M-ETHYLPHENOL
3-NITROPHENOL
P-hTHYLPHENOL
4-NITROPHENOL
PHENYLPHENOLS
2-AMI\0-4,6-DlNlTKOPHENOL
O-PHENYLPHENOL
DINJTROPHENOLS
P-PHENYLPHENOL
2, 4-DINITKOPHENOL
M-PHENYLPHENOL
2/5-DINITROPHENOL
2,2'-DIHYDROXYDIPHENYL
2,6-DINITROPHENOL
XYLEN0LS
a^,6-TRJNJTROPH£NOL
TYPE CONC
E-6 G/G
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1.30E
1.40E
1.30t
U30E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.4UE
3.40E
3.40E
3.40E
3.40E
3.40C
03
02
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
US
1.30E
l.UOt
2.20E
4.64E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.4QE
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40L
3.40E
3.40E
3.40E
3.40E
3.40t
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
06
05
04
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
WDS
u/s
4.9at
b.32t
6.23£
1.60L
1.30L
1.30E
1.30t
1.30t
1.30E
1.30L
1.30E
1.30E
1.30t
1.30E
1.30t
1.30t
1.30t
1.30E
1.30E
1.30t
1.30t
1.30L
1.30t
1.30t
1.30t
1.30t
1.30L
1.30t
1.30t
1.30t
1.30E
1.30E
1.30L
1.30t
06
05
04
04
04
04
04
04
04
04
04
OU
04
04
OU
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
LCCAT
3
i.
3
3
6
6
6
6
6
6
6
b
6
6
6
6
b
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
-------
OMEG NO.
CYCLONE OUST, HtALTH IMPACT
COMPOUND NAME TYPE
CONC US
t-b U/G
LCCAT
G/S
18 A 141*
20 B 020* P W
18 A 142* P
20 B 040* W
18 A 143*
18 C
18 A
20 B
18 A
18 B
18 A
18 B
18 A
18 B
18 A
18 A
19 B
18 A
18 A
19 B
18 A
19 B
18 A
18 C
18 A
18 B
18 A
18 C
18 C
18 C
72 A
21 C
18 A
18 A
082*
144*
042*
145*
020* M
146*
040* M
160* W
060* W
161*
043*
021*
162*
163*
022* P
180* W
023*
181*
081*
182*
080* W
183*
020* W
040* W
080* W
010
100* P M
160* M
146*
2,3-XYLENOL
4,6-DINITRO-O-CRESOL
2,4-XYLENOL
DINITRO-P-CRESOLS
2,5-XYLENUl
4-INDANOL
2,6-XYLENOL
2f6-DINITRO-P-CRESOL
3,5-XYLENOL
CATECHOL
3,4-XYLENOL
1,3-DIHYDROXYBENZENE
ETHYL CRESOLS
1,4-DIHYDROXYBENZENE
6-ETHYL-M-CRESOL
P-CRESOL
CHLORINATED-0-CRESOLS
4-ETHYL-O-CRESOL
2-ETHYL-P-CRESOL
CHLORINATED-M-CRESOLS
POLYALKYLPHENOLS (M*>135)
CHLORINATED-P-CRE80LS
2,4,6-TRIMETHYL METHYL PHENOL
1-INDANOL
4,6-DI-TERT-BUTYL-M-CRESOL
1,2,3-TRIHYDROXYBENZ£NE
2r6-DIMETHYL-4-HEPTYL PHENOL
1-NAPHTHOL
2-NAPHTHOL
INOANOLS
IRON (AS FE+2)
BENZO(A)PYRENE
ETHYL CRESOLS
3,4-XYLENOL
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
0
T
T
T
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
9.20E
1.40E
7.70E
7.70E
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
02
02
02
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40k
3.40E
3.40k
3.40E
3.40E
3.40E
3.10E
2.33E
7.70E
7.70E
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
02
02
1.30E
1.30E
1.30k
1.30k
1.30t
1.30E
1.30k
1.30k
1.30k
1.30k
1.30k
1.30k
1.30E
1.30E
1.30E
1.30E
1.30k
1.30k
1.30k
1.30E
1.30k
1.30k
1.30k
1.30k
1.30k
1.30k
1.30k
1.30k
1.30E
1.30k
1 .20k
8.VOE
2.92k
2.92E
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
04
03
03
03
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
2
5
5
-------
I
M
00
CYCLONE DUST, HEALTH IMPACT
OMEG
16 A
18 C
16 B
16 C
16 B
18 C
16 B
18 C
18 B
18 C
16 C
18 A
18 A
19 A
18 A
19 A
18 A
19 A
18 A
19 B
16 A
19 B
18 A
19 B
18 A
19 B
18 A
18 A
18 A
20 A
16 A
20 A
18 A
20 A
NO.
183*
020*
020*
ouo*
QUO*
080*
060*
081*
080*
062*
083*
144*
020*
020*
040*
O4o*
041*
060*
161*
020*
0*43*
021*
163*
022*
180*
023*
181*
182*
062*
040*
063*
060*
100*
060*
W
w
w
w
w
w
w
P w
P W
w
P w
P N
w
P
w
w
P W
w
W
COMPOUND NAME
2,6-DIMETHYL-4-HEPTYL PHENOL
1-NAPHTHOL
CATECHOL
2-NAPHTHOL
1,3-DlHYDROXYBENZENE
INDANOLS
1,4-DIHYDROXYBENZENE
1-INDANOL
1,2,3-TRIHYDROXYBENZENE
4-INDANOL
5-INDANOL
2,6-XYLENOL
PHENOL
2-CHLOROPHENOL
CHESOLS
2r4-DICHLUROPHENOL
M-CRESOL
PEMTACHLOROPHENOL
6-ETHYL-M-CRESOL
CHLORINATED CRESOLS
P-CRESOL
CHLORINATED-O-CRESOLS
2-ETHYL-P-CRESOL
CHLORINATED-M-CRESOLS
POLYALKYLPHENOLS (MW>135)
CHLORINATED-P-CRESOLS
2,4,6-THIMETHYL METHYL PHENOL
4,6-DI-TEKT-BUTYL-M-CRESOL
M-ETHYLPHENOL
3-NITROPHENOL
P-ETHYLPHENOL
4-NITROPHENOL
PHENYLPHENOL3
2-AMINO-4, 6-DINI TROPHENUL
TYPE CONC
E-6 G/G
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
7.70E
7.70E
7.7UE
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7. TOE
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
T.TOE
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7. TOE
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
US
7.70E
7.70E
T.TOE
7.70E
7.70E
7. TOE
7.70E
7.70E
7.70E
7.70E
T.TOE
7.70E
7. TOE
7.70E
7.70E
T.TOt
7.70E
7.70E
T.TOE
7.70E
7.70E
7.70t
7.70t
7. TOt
7.70fc
7. TOE
7.70E
7.70E
7.70E
T.TOE
7.70E
7. TOE
7. TOt
T.70E
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
U2
02
U2
02
02
02
02
02
02
02
02
U2
02
U2
02
02
02
WOS
G/S
2.92t
2.92E
2.92E
2.92t
2.92t
2.92E
2.92t
2.92E
2.92t
2.92t
2.92t
2.92E
2.92t
2.92h
2.92t
2.92fc
2.92t
2.92L
2.92t
2.92t
2.92t
2.92t
2.V2t
2.92t
2.92t
2.92L
2.92t
2.92t
2.92t
2.92t
2.92t
2.92t
2.92t
2.92E
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
U3
03
03
03
03
03
03
03
03
03
03
03
03
LCCAT
S
5
5
5
5
5
S
5
5
5
5
5
S
5
b
5
5
b
S
b
5
b
b
b
b
b
b
b
b
b
5
5
5
5
-------
CYCLONE DUST, HEALTH IMPACT
DMEG
18
20
18
20
18
20
18
20
18
20
18
20
18
20
18
20
18
20
18
18
18
20
18
18
02
21
54
36
A
A
A
A
A
A
A
A
A
A
A
B
A
B
A
B
A
B
49 A
21 8
83 A
04 B
38 A
34 A
NO.
101*
100* M
102*
101* P
103*
102*
120* H
103*
140* W
120* W
141*
020* P M
142* P
040* W
143*
041*
081*
042*
145*
042*
080* M
020* P M
162*
060* W
380* W
080* P
010 P
010
010 P
080*
010 P
020* P M
010
010
COMPOUND NAME
0-PHENYLPHENOL
DINITROPHENOLS
P-PHENYLPHENOL
2f4-DINITROPHENOL
M-PHENYLPHENOL
2,5»DINITROPHENOL
2»2'-DIHVDROXYDIPHENYL
2,6-DlNlTROPHENOL
XYLENOLS
2»4,6-TRINITROPHENOL
2r3-XVLENOL
4r6-DlNlTRO-0-CRE80L
2,4-XYLENOL
DINITRO-P-CRE30L8
2,5-XYLENOL
3»5-DINITRO-P-CRE80L
0-ETHYLPHENOL
2,6-DINlTRO-P-CRESOL
3»5-XYLENOL
0-CRE80L
ETHYLPHENOL8
2-NITROPHENOL
4-ETHVL-O-CRESOL
2-METHOXYPHENOL
HEXACHLOROCYCLOHEXANE
OIBENZ( A, H) ANTHRACENE
SELENIUM
BARIUM
ARSENIC
3-METHYLCHOLANTHRENE
MERCURY
1,1'-DICHLOROMETHYL ETHER
ALUMINUM
CALCIUM (A3 CA+2)
TYPE CONC
E-6 G/G
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
0
0
0
T
D
T
D
D
7.70E
7. TOE
7.70E
7.70E
7.70E
7.70E
7.7UE
7.70E
7.70E
7.70E
7. TOE
7.70E
7.70E
T.TOE
7. TOE
7. TOE
7.70E
7.70E
7. TOE
7.70E
T.TOE
7.70E
7.70E
7.70E
2.60E
1.40E
1.40E
1.30E
6.30E
1.30E
< 2.30E
1.40E
1.2UE
2.90E
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
03
02
01
03
01
03
oo<
03
04
04
OS
7. TOE
7.70E
7.70E
7. TOE
T.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.706
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7. TOE
T.70E
7.70E
6.50E
5.UOE
.40E
.30E
.30E
.20E
.20E
9.33E
T.bOE
6.04E
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02<
01
01
01
MD8
t/S
2.92t
2.92t
2.92E
2.92k
2.<>2t
2.92k
2.V2*.
2.92k
2.92E
2.92t
2.92E
2.92E
2.92E
2.92E
2.92E
2.92b
2.92t
2.92E
2.92E
2.92E
2.92E
2.92E
2.92k
2.*2k
2. SOt
1.90t
5.31E
4.94k
4.80E
4.SOk
4.40k
3.S4k
2.90k
2.30E
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
02
02
02
02
02
02
02
02
LCCAT
5
5
5
5
5
5
5
5
5
S
5
5
5
5
5
5
5
5
5
&
b
b
5
5
1
2
3
4
-------
I
to
CYCLONE OUST, HEALTH IMPACT
DMEG
43 A
04 B
33 A
71 A
02 A
66 A
82 A
48 A
46 A
35 A
21 B
10 C
10 C
10 C
10 C
10 C
21 B
21 0
12 A
7b A
02 A
27 A
02 B
23 B
28 A
10 C
32 A
23 B
23 C
23 B
79 A
65 A
56 A
06 B
NO.
010
020*
010
010
360*
010
010
010
010
010
080*
ido*
041*
043*
042*
040*
040*
040*
040*
010
320*
010
140*
100*
010
220*
010
240*
160*
220*
010
010
010
060*
P W
p
w
p
p
p
p
w
p
p
p
P W
w
p
w
p
w
COMPOUND NAME
SILICON
1,1'-DICHLOROMETHYL ETHER
MAGNESIUM
MANGANESE
HEXACHLOROCYCLOHEXANE
CHROMIUM
CADMIUM
PHOSPHORUS
LEAD
STRONTIUM
3-METHYLCHOLANTHRENfc
1,4-DIAHINOBENZENE
2-AMINOTOLUENE
4-AMINOTULUENE
3-AMINOTOLUENE
AMINOTOLUENES
BENZ(A)ANTHRACENE
DI8ENZO(A,I)PYRENE
N-NITKOSOUIETHYLAMINE
NICKEL
HEXACHLOROETHANE
LITHIUM
HEXACHLOROCYCLOPENTADIENE
DIHYDKOACRIDINE
SODIUM
2-AMINONAPHTHALENE
BERYLLIUM
DIbENZ(A,H)ACRIDIN£
DIBENZOCC/GKARBAZOLE
DIBENZ(A,J)ACRIDIN£
SILVER
VANADIUM
FLUORINE (AS F-)
B-PROPIOLACTONE
TYPE CONC
E-6 G/G
D
T
D
D
T
S
S
D
S
D
T
T
T
T
T
T
T
T
T
S
T
S
T
T
D
T
S
T
T
T
S
S
S
T
1.60E
7.70E
7.BOE
1.90E
1.40E
1.10E
2.00E
5.90E
tt.OOE
1.40E
1.40E
3.40E
3.40E
3.40E
3.40E
3.40E
1.30E
1.30E
3.40E
4.00E
2.60E
6.00E
2.60E
3.40E
1.10E
3.40E
04
02
03
01
02
01
00
02
00
03
02
03
03
03
03
03
03
03
03
00
03
00
03
03
04
03
4.00E-01
3.40E
1.40E
3.40E
2.00E
1.90E
2.80E
3.40E
03
03
03
00
01
02
03
US
6.00E
5.13E
4.33E
3.bOE
3.50E
2.20E
2.00E
2.00E
1.60E
1.52E
1.30E
1.13E
1.03E
1.03L
1.03t
1.03E
l.OOE
l.OOE
9.44E
8.90E
8.70E
8.60E
7.90E
6.V3E
6.90E
6.80E
6.70E
5.10E
4.70E
4.60E
4.UOE
i.ttOE
3.73E
3.60E
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
NDS
G/b
2.30E
2.00k.
1.64L
1.4UL
1.33E
6.40t
7.60t
7. 50t
6. lot
S.bOt
4.83t
4.30t
3.91E
3.91E
3.9U
3.91E
3.80t
3. 80t
3.60t
3.40t
3.30t
3.30t
3.00E.
2.63t
2. bit
2.60t
2.53t
1.92t
l.BOt
1.74t
1.52E
1.44b
1.41E
1.40t
02
02
02
02
02
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
LCCAT
5
2
2
6
6
b
b
b
3
3
6
1
1
6
6
6
4
b
6
-------
DME.G NU.
CYCLONE DUST, HEALTH IMPACT
COMPOUND NAME TYPE
CUNC US
E-6 G/G
LCCAT
G/S
74 A 010
81 A 010 P
78 A 010 P
23 C 160* M
10 C 100*
10 C 043*
10 C 041*
10 C 042*
10 C 040*
10 C 082*
13 A 100* N
10 C 083*
10 C 081*
10 C 060*
62 A 010
12 A 040* P
10 C 200*
21 B 103*
21 B 102*
21 B 106*
21 B 10A*
21 B 104*
21 B 107*
21 B 10B*
21 B 105*
21 B 101*
21 8 100*
21 B 109*
21 8 108*
63 A 010
12 A 020* P W
10 C 140* P
23 B 100* W
10 C 220*
CD
N)
O
COBALT
ZINC
COPPER
DIbENZO(C,G)CARBAZOLE
1, 4-DIAMINOBENZENE
4-AMINOTOLUENE
2-AMINOTOLUENE
3-AMINOTOLUENE
AMINOTOLUENES
M-ANISIOINE
BENZENETHIOL
P-ANISIDINE
0-ANISIDXNE
ANISIOINES
TITANIUM
N-NITROSODIETHYLAMINE
1-AMINONAPHTHALENE
2-METHYL BENZO(C)PHENANTHR£NE
l-METHYL BENZO(C)PHENANTHRENE
7-METHYL BENZO(C)PHENANTHREN£
N-PROPYL BENZO(C)PHENANTHRENE
5-METHYL BENZO(C)PHENANTHREN£
8-METHYL BENZO(C)PHENANTHRENE
I80PROPYL BENZO(C)PH£NANTHRENE
6-METHYL BENZO(C)PHENANTHR£NE
BENZO(C)PHENANTHRENE
BENZO(C)PHENANTHRENE & ALKYL DERIVATIVES
6-ETHYL BENZOCOPHENANTHRENE
2-ETHYL BENZO(C)PH£NANTHRENE
ZIRCONIUM (A3 ZR+4)
N-NITROSODIMETHYLAMINE
.BENZIDINE
DIHYDROACRIDINE
2-AMINONAPHTHAL£Nb
3
8
3
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
3
T
T
T
T
5.0UE 00
1.60E 02
J.OOE 01
7.70E Qd
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
4.00E 02
7.70E 02
3.40E 03
1.30E 03
1.30E 03
1.30E 03
.JOE 03
.JOE 03
.30E 03
.30E 03
.JOE 03
.JOE 03
.30E 03
.30E 03
.JOE 03
2.90E 01
3.40E 03
3.40E 03
7.70E 02
7.70E 02
3.33E 00
3.20t 00
J.OOE 00
2.60E 00
2.60E 00
2.33t 00
2.33E 00
2.33E 00
2.33L 00
2.30k 00
2.30E 00
2.30E 00
2.30E 00
2. JOE 00
2.22E 00
2.13E 00
2.00E 00
1.94E 00
1.94E 00
1.94E 00
1.94E 00
1.94E 00
1.94E 00
1.94E 00
1.S4E 00
1.94E 00
1.94E 00
1.94E 00
1.94E 00
1.93E 00
1.70E 00
1.70E 00
1.60E 00
1.54E 00
1.30b 01
1.2lb 01
1.14E 01
9. hub 00
9.bOb 00
b.VOE 00
6.90E 00
C.VOb 00
8.90b 00
8.61E 00
8.61E 00
6.61b 00
8.61E 00
8.61E 00
8.44E 00
8.12E 00
7.60E 00
7.40b 00
7.40b 00
7.40£ 00
7.40b 00
7.40E 00
7.40b 00
7.«0b 00
7.40b 00
7.40E 00
7.40E 00
7.4QE 00
7.40b 00
7.34b 00
6. 50b 00
6. SOb 00
6.00E 00
5.90E 00
5
5
5
5
5
S
6
6
6
6
6
5
6
3
3
3
3
3
3
3
3
3
3
3
3
6
6
5
5
-------
pi
to
O
N>
DMEG
85
37
08
23
08
08
08
08
08
21
21
23
12
10
08
02
10
10
13
10
10
22
17
17
02
14
10
15
61
02
21
10
12
06
B
A
B
B
C
A
A
A
A
B
D
8
B
C
B
A
C
C
A
C
C
C
B
B
A
B
C
A
A
B
D
C
A
A
NO.
010
010
060* w
240*
060* M
123*
120* *
122*
121*
040* P
040* W
220*
020* W
120*
060* W
180*
OttO*
083*
100* W
082*
081*
080* P M
060* W
040* W
320* P
020 W
200*
160* W
010
140* P W
060*
140* P
020* P W
123*
CYCLONE OUST, HEALTH IMPACT
COMPOUND NAME TYPE CONC
E-6 G/G
THORIUM
BORON
B-PROPIOLACTONE
DIBENZ(A,H)ACRIDINE
6-HEXANELACTAM
STEARIC ACID
SATURATED LUNG CHAIN ACIDS (MW:228-285)
PALMITIC ACID
MYRISTIC ACID
BENZ(A)ANTHHACENE
DIBENZOCA, I)PYRENE
OIBENZ(A,J)ACRIDINE
N-METHYL-N-N I TROSO ANILINE
4-AMINOBIPHENYL
B-PROPIOLACTONE
DIBROMODICHLOROMETHANE
ANISIDINES
P-ANISIDINE
BENZENETHIUL
M-ANISIDINE
0-ANISIOINE
BENZO(B) FLUOR ANTHENt
l-CHLORO-4-NITROBENZENE
1-CHLORO-2-NITROBENZENE
HEXACHLOROETHANE
DIMETHYL SULFOXlDt
1-AMINONAPHTHALENE
BIPHENYL
YTTRIUM (AS Y+3)
HEXACHLORUCYCLOPENTADIENE
DIBENZU(A,L)PYRENE
BENZIDINE
N-NlTrtUSODIMETHYLAMlNE
STEARIC ACIU
S
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
T
T
T
T
T
2.00E
1.10E
1.10E
7.70E
3.40E
3.40E
3.40E
3.40E
3.40E
l.UUt
1.40E
7.70E
3.40E
3.40E
7.70E
2.60E
7.70E
7.70E
7.70E
7.70E
7.70E
1.30E
1.40E
1.40E
1.40E
1.10E
7.70E
1.30E
1.30E
1.40E
1.30E
7.70E
7.70E
1.10E
00
02
03
02
03
03
03
03
03
02
02
02
03
03
02
03
02
02
02
02
02
03
03
03
02
03
02
03
01
02
03
02
02
03
US
l.b3E 00
1.20E 00
1.20t 00
1.14E 00
1.13E 00
1.1 Oh 00
1.10E 00
1.10E 00
1.10E 00
1.10E 00
l.iot oo
1.U4E 00
8.71E-01
8.bOE-01
8.10E-01
6.20E-01
b,13t-01
5.13E-01
b. 13E-0 1
5.13E-01
5.13E-01
4.ttlE-Ul
4.70E-U1
4.70E-01
4.70t-01
4.60t-01
4.b2t-01
4.33E-01
4.33E-01
4.24E-01
4.10E-01
3.90t-0l
3.VOE-01
3.54E-01
5
4
4
4
4
4
4
4
4
4
4
4
3
3
3
2
2
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
G/S
,b4t
,bot
,40t
,40t
.30t
,20t
,20t
.20t
.20t
.lot
.lot
.OOt
,3lt
.23t
.lot
,40t
.OOt
.OOt
.OOt
.OOt
.OOt
.b2t
.ttOt
.eot
.toot
./4t
.72t
,64t
,64t
,61t
,b4t
,bOt
l.SOt
1.34E
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
LCCAT
7
5
6
6
6
6
6
2
I
5
6
6
5
1
5
b
b
b
5
3
4
4
2
7
b
3
2
3
b
b
7
-------
CYCLONE DUST, HEALTH IMPACT
DMEG NO.
08 A 121*
08 A 120* N
08 A 122*
44 A 010
17 A 060* N
08 A 140*
17 A 085*
17 A 083*
17 A 084* P
17 A 086*
17 A 082*
17 A 081* P
17 A 080*
41 A 010 P
22 D 020* P M
21 A 180* P W
22 C 020* P
23 D 020* M
17 B 040* W
08 C 060* W
17 B 060* W
08 A 123*
08 A 120* W
08 A 121*
08 A 122*
23 D 040*
21 B 142*
21 B 141*
21 B 140*
04 A 050* M
04 A 060* N
04 A 040* M
08 D 2S3*
08 D 281*
to
0
U)
COMPOUND NAME
MYRISTIC ACID
SATURATED LONG CHAIN ACIDS (M*|228-2B5)
PALMITIC ACID
GERMANIUM
4-NITR08IPHENYL
OLEIC ACID
2,5-DlNlTROTOLUENE
2r3-DIN!TROTOLUENE
2'4-DINITROTOLUENE
3r5-DINlTROTOLUENE
3r4-DINlTROTOLUENE
2r6-DINITROTOLUENE
DINITROTOLUENES
THALLIUM
INDENO(l,2,3-CD)PYRfcNE
PHENANTHRENE
BENZO(K)FLUORANTHENE
BENZOTHIAZOLE
l-CHLORO-2-NITROBENZENE
6-HEXANELACTAM
1-CHLORO-4-NITROBEN2ENE
STEARIC ACID
SATURATED LONG CHAIN ACIDS
-------
PI
1
IS3
o
-P-
CYCLONE DUST, HtALTM IMPACT
DMEG
06
08
08
39
02
15
21
21
21
21
21
21
21
21
21
21
21
21
08
08
08
08
08
12
21
17
10
10
23
23
23
23
02
21
D
D
D
A
8
B
B
B
B
B
B
B
B
B
B
B
B
B
A
A
A
A
A
B
B
A
C
A
A
A
A
A
A
C
NO.
300* P
282*
280* P W
010
120* P
060* W
108*
103*
107*
104*
106*
100*
109*
101*
108*
10A*
105*
102*
102*
103*
101*
100*
104*
020* M
120* P
060* W
120*
060*
100* W
102*
103*
101*
160* P
160*
COMPOUND NAME
DI-2-ETHYLHEXYL PMTMALATE
DIETHYL PHTHALATE
PHTMALATE ESTERS CMW:194-279)
GALLIUM
HEXACHLOROBUTADIENE
4,4'-DIPHENYLBIPHENYL
2-fcTHYL BENZOCOPHENANTHRENE
2-METHYL BENZOCOPHENANTHRENE
8-METHYL BENZOCOPHENANTHRENE
5-METHYL BENZOCOPHENANTHHENE
7-METHYL BENZOCOPHENANTHrtENE
BENZOCOPHENANTHKENt & ALKYL DERIVATIVES
6-ETHYL BENZO(C)PMENANTHRENE
BENZOCOPHENANTHRENE
ISOPROPYL BENZOCOPHENANTHRENE
N-PROPYL BENZOCOPHENANTHRFNE
6-METHYL BENZOCOPHENANTHHENE
1-METHYL BENZOCOPHtNANTHHENE
CAPRYLIC ACID
CAPRIC ACID
CAPROIC ACID
SATURATED LONG CHAIN ACIDS CM*:116-201)
LAURIC ACID
N-MET»,YL-N-NITROSOANILINE
CHRYSENE
4-NITROBIPHENYL
4-AMINOBIPHENYL
ETHANOLAMINE
CHLOROPYRIDINES
3-CHLOROPYRIDINE
4-CHLOROPYRIOINE
2-CHLOROPYRIDINE
BRGMOFORM
PICENE
TYPE CONC
E-6 G/G
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
3
3
3
3
2
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
7
1
7
7
3
3
3
.40E
.UOE
.40E
.30E
.60E
.30E
.40E
.40E
.40E
.40E
.40E
.40E
.auE
.40E
.40E
.40E
.40E
.40E
.40E
.40E
.40E
.40E
.40E
.70E
.3UE
.70E
.70E
.40E
.40E
,40fc
3.4UE
3.40E
2.60E
1.30E
03
03
03
01
03
03
02
02
02
02
02
02
02
02
02
02
02
02
03
03
03
03
03
02
03
02
02
03
03
03
03
03
03
03
US
2.30E-01
2.30E-01
2.30E-01
2.20E-01
2.20E-01
2.20E-01
2.10E-01
2.10E-01
2.10E.-01
2.10E-01
2.10E-01
2.10E-01
2.10E-01
2.10E-U1
2.10E-01
2.10E-U1
2.10E-01
2.10E-01
2.UOE-01
2.00E-01
2.00E-01
2.00E-01
2.00E-01
2.00E-01
2.00E-01
1.92E-01
1.V2E-01
.VOE-01
.90E-01
.VOE-01
.90E-01
.90E-01
8
8
8
8
8
8
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
KDS
G/S
.61t-01
.61E-01
.61E-01
,40t-01
.23E-01
.23E-01
.94E-01
,94t-01
.94E-01
.94E-01
,94fc-01
. V4t-Ul
.^at-oi
.94E-01
.94E-01
.94E-01
,94fc-01
.94E-01
. t>0t-01
.60E-01
.60E-01
,60t-01
.60E-01
,50t-01
,50t-01
.31E-01
.3U-01
.^Ot-01
,20t-01
.20E-01
,20t-01
7.20t-01
. 73E-01 6.60E-01
.73E-01
6.60t-01
LCCAT
b
6
6
1
3
2
2
2
2
2
2
2
2
2
2
2
2
6
6
6
6
6
5
3
5
5
6
6
6
6
6
1
3
-------
DMEG NU.
CYCLONE DUST, HEALTH IMPACT
COMPOUND NAME TYPE
w
0
Ln
CONC US
t-6 G/G
LCCAT
G/3
23 C 020*
17 A 080*
17
17
17
17
17
17
09
21
04
04
04
03
03
21
06
08
23
23
07
17
16
09
08
23
23
23
23
23
08
A 084* P
A
A
A
A
A
A
C
A
A
A
B
B
0
A
A
B
C
B
A
B
A
D
A
A
C
A
A
A
02 B
02 B
02 B
085*
083*
081* P
086*
082*
120*
120*
050*
040*
060*
020*
040*
020*
020*
140*
200*
020*
100*
020* P
020
120*
080*
101*
100*
ISO*
103*
102*
140*
103
104
100* P
W
W
H
W
W
W
W
W
W
W
W
PYRROLE
DINITROTOLUENES
2»4-DlNITHOTOLUENE
2r5-DlNJTROTOLUENE
2,3-DlNITROTOLUENE
2,6-DINITROTOLUENE
3,5-DlNITROTOLUENE
3,4-DlNITROTOLUENE
TETRAMETHYL3UCCINONITRILE
BENZO(E)PYRENE
EPICHLORHYORIN
2-CHLORO-l,2-EPOXYPROPANE
1-CHLORO-U3-EPOXYPROPANE
1,4-DIOXANE
1,3-DlOXANE
DIBENZO(A,H)PYREN£
ETHYLENE GLYCOL
OLEIC ACID
BENZCOACRIUINE
PYRROLE
CAMPHOR
NITROBENZENE
A-CHLOROTOLUENE
TETRAMETHYLSUCCINONITHILE
METHYL METHACRYLATE
2-CHLOROPYRIOINE
CHLOROPYRIDINES
DIBENZO(A,G)CARBAZOL£
4-CHLOROPYRIOINE
3-CHLOROPYRIDINE
OLEIC ACID
CIS-1/3-DICHLOROPROPENE
TRANS-1,3-DICHLOROP«OPENE
DICHLOROPROPENES
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1.4UE
7.70E
7.70E
7.70t
7.70E
7.70fc
7.7UE
7.70E
1.4UE
1.3UE
7.70E
7.70E
7.70E
1.40E
1.40E
1.30E
3.40E
1.10E
3.40E
7.70E
3.40E
1.40E
1.30E
7. TOE
3.40E
1.40E
1.40E
1.40E
1.40E
1.40E
7. TOE
2.60E
2.60E
2.60E
03
02
02
02
02
02
02
02
03
03
02
02
02
03
03 1
03 1
03 1
03 1
03 1
1.72E-01
1.7lc-Ul
1.71E-U1
.71E-01
.71E-U1
. 1 1E-01
.71E-01
.71E-01
.60E-01
.42E-01
.30E-01
.30E-01
.30E-01
.30E-01
.30E-01
.20E-01
.13E-01
.10E-01
.10E-01
6.bOt-01
6.50t-01
6.50L-01
6.bot-yi
6.50L-01
6.iOt-01
6.50E-01
6.bOE-01
5.9U-01
5.42t-01
4.90E-01
4.90E-01
«.90fc-01
4.83E-01
4.63E-01
4.50fe-01
4.30E-01
4.20E-01
4.03E-01
02 9.50E-02 3.6U-U1
03 9.44E-02
03 9.33E-02
03 8.TOE-02
02 8
03 8
03 7
03 7
03 7
03 7
03 7
02 7
03 7
03 7
03 7
.60E-02
.10E-02
.ttOE-02
.80E-02
.80E-02
.80E-02
.bOE-02
.70E-02
.64E-02
.64E-02
.64E-02
3.60E-01
3.54E-01
3.30t-01
3.30E-01
3.10L-01
3.00E-01
3.00E-01
3.0QE-01
3.00L-U1
3.00E-01
2.92t-01
2.90E-01
2.90t-01
2.90E-01
4
5
5
5
5
5
5
5
4
3
5
5
5
4
4
3
6
7
6
5
6
4
3
5
6
4
4
4
4
4
5
1
1
1
-------
w
OMEG NO.
CYCLONE DUST, HEALTH IMPACT
COMPOUND NAME TYPE
CONC US
E-6 G/G
LCCAT
G/S
23
23
23
23
03
03
55
22
08
08
08
08
08
23
23
23
23
05
23
23
23
16
16
16
16
10
23
23
22
08
08
08
08
17
A
B
B
B
B
B
A
C
A
A
A
A
A
A
A
A
A
B
A
A
A
B
B
B
B
C
D
D
C
D
D
D
0
A
020*
022*
020*
021*
040* M
020* M
010
040
100*
103*
102*
104*
101*
142*
146*
145*
140*
100* M
144*
HI*
143*
043
040
042
041
020*
020* M
040*
080* P M
283*
280* P W
300* P
232*
020* P
PYRIUINE
ISOQUINOLINE
QUINOLINES
QUINOLI'ME
U3-DIOXANE
1,4-DIOXANE
TELLURIUM
BENZO(J)FLUORANTHENE
SATURATED LONG CHAIN ACIDS (MW:116-201)
CAPRIC ACID
CAPRYLIC ACID
LAURIC ACID
CAPROIC ACIO
2,4-DIMETHYLPYRIDlNE
2,3,4,6-TETRAMETHYL PYRIDINE
3,4-DIMETHYLPYRlDlNE
DISUBSTITUTED POLYSUBSTITUTED ALKYL PYKIDINES
1-PhENYLETHANOL
2fb-DIMETHYLPYRlUlNE
2, 3-OIMETHYLPYRIDINE
2f b-DIM£THYLPYRIDINE
1,4-BISCCHLUROMETHYL) BENZENE
BIS CCHLOROMETHYL) BENZENES
If 3-BISCCHLUROMETHYL) BENZENE
1,2-BIS(CHLOROMETHYBENZENE
ANILINE
BENZOTHIAZOLE
METHYL BENZOTHIAZULfc
BENZO(b) FLUOR ANTHENE
DI-N-BUTYL PHTHALATE
PHTHALATE ESTERS (M*: 194-279)
01-2-ETHYLHtXYL PHTHALATE
DIETHYL PHTHALATE
NITROBENZENE
T
T
T
T
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
3
3
3
3
7
7
2
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
7
7
1
7
7
.40E
.UOE
.40E
.40E
.70E
.70E
03
03
03
03
02
02
.OOE-01
.30E
.lot
.10E
.10E
.10E
.10t
.40E
,40E
.40E
.40E
.40E
.40E
.40E
.40E
.30E
,30t
.30E
.30E
.40E
,70E
.70E
.40E
.70E
.70E
7.70E
7.70E
7.70fc
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
02
02
02
02
02
02
02
02
7.
7.
7.
7.
7.
7.
6.
6.
b.
6.
6.
6.
6.
6.
6.
b.
b.
b.
b.
b.
b.
b.
b.
6.
6.
b.
5.
5.
b.
5.
5.
5.
5.
bOE-02
^3E-U2
23E-02
23E-02
OOE-02
OOE-02
70E-02
bOE-02
bO£-02
bOE-02
bOE-02
bOt-02
50E-02
30t-02
30E-02
30E-02
30E-02
iOE-02
30E-02
30E-02
30E-02
«!0£-02
20E-02
20E-02
2UE-02
OOE-02
V2E-02
bOE-02
20E-02
13E-02
13E-02
13E-02
13E-02
5.13E-02
2.VOt-01
2.7«t-01
2.74E-01
2.74fc-01
2.70t-01
2.70E-01
2.b3t-Ul
2.bOt-01
-------
CYCLONE OUST, HEALTH IMPACT
DMEG
08
08
23
15
15
15
15
12
15
10
07
10
10
10
10
10
10
10
10
08
06
06
06
06
08
04
21
21
23
10
23
23
23
23
D
A
B
B
B
B
B
A
A
C
B
A
C
C
C
C
0
C
C
B
0
C
A
A
A
A
A
C
NO.
281*
080*
260*
162
160
161
163
060* P
160* W
062*
060* P
060*
066*
060*
064*
063*
020* W
065*
061*
100*
102*
103*
101*
104*
040*
100*
060*
060
102*
060*
101*
100* W
103*
180*
COMPOUND NAME
DIMETHYL PHTHALATE
VALERIC ACID
DIBENZ(C,H)ACRIDINE
M-TERPHENYL
TERPHENYL3
0-TEMPHENYL
P-TERPHENVL
N-NITROSOOIPROPYLAMINE
BIPHENYL
2,4-XYLIDlNE
ISOPHORONE
1,2-DIAMINOETHANE
3,5-XYLIDlNE
DIMETHYLANILINES
2,6-XYLIDlNE
2,5-XYLIDlNE
N,N-DIMETHYLANILINE
3,4-XYLlDlNE
2»3-XYLIOlNE
SATURATED LONG CHAIN ACIDS (MWllU-201)
CAPRYLIC ACID
CAPRIC ACID
CAPROIC ACID
LAURIC ACID
ACETIC ACID
2f2'-DICHLORODHSOPHOPYL ETHER
DIBENZO(A,L)PYRENE
DIBENZ
-------
M
NJ
o
00
OMEG NO
CYCLONE DUST, HEALTH IMPACT
COMPOUND NAME TYPE
CONC US
E-6 G/G
LCCAT
G/S
23 C 040*
04 A 140* P
23 C 140*
06 C 020
16 A 160* P
16 A 162
16 A 161
06 A 060*
02 A 180*
23 A 020*
10 A 120
12 A 060
06 B 060
10 A 121
23 A 041*
10 A 122
10 A 123
23 A 043*
23 A 042*
21 A 160* P W
22 D 020* P W
01 B 220 W
22 C 020* P
10 A 160
07 8 120
06 B 041
21 C 040
50 A 010 P
23 A 141*
23 A 146*
23 A 143*
23 A 142*
21 B 140*
21 B 142*
IM>OLE
2-CHLOROETHYL VINYL ETHER
DIBENZO(A,IKARBAZOLE
FORMAM1DE
POLYCHLORINATED BENZENES
HEXACHLOROBENZENE
1,2,4-TRlCHLGROBENZENE
MALEIC ACID
OIBROMODICHLOROMETHANE
PYRIDINE
PROPANOLAMINES
N-NITROSODIISOPROPYLAMINE
Y-bUTYROLACTONE
2-AMINO-1-PROPANUL
2-METHYLPYRIDINE
3-AMINO-l-PROPANOL
1-AMINO-2-PROPANOL
4-METHYLPYRIDINE
3-METHYLPYRIDINE
PHtNANTHRENE
INDENO(1,2,3-CD)PYRENE
DICYCLOPENTADIENE
BENZO(K)FLUORANTHENE
CYCLOhEXYLAMINE
ACETOPHENONE
2-HYDROXYBENZOIC ACID
BENZO(G)CHRYSENE
ANTIMONY
2/3-DIMETHYLPYRIDINE
2,3,4,6-TETRAMETHYL PYRJDlNE
2,5-DIMF.THYLPYRIDINE
2,4-DIMETHYLPYRIOJNt
METHYL CHftYSENES
5-HETHYL CHRYSENE
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
1.40E 03
1.40E 03
1.40E 03
3.40E 03
1.30E 03
1.30E 03
1.30E 03
3.40b 03
1.40E 02
1.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
1.40E 02
1.40E 02
2.60E 03
1.40E 02
3.40E 03
3.40E 03
3.40E 03
1.30E 03
< 4.00E-OK
1.40E 03
1.40E 03
1.40E 03
1.40E 03
1.40E 02
1.40C 02
4.24E-U2
4.1U-02
3.90E-02
3.bOE-02
3.71E-02
3.61E-02
3.61E-02
3.54E-02
3.33E-02
3.11E-02
3.10E-02
3.10E-U2
3.10E-02
3.10E-02
3.10E-02
3.10E-02
3.10E-02
3.10E-02
3.10E-02
2.V1E-U2
2.V1E-02
2.90E-02
2.YOE-U2
2.«3t-02
2.83E-02
2.63E-02
2.70E-02
2.70E-02<
2.60E-02
2.60E-02
2.60E-U2
2.60E-02
2.606-02
2.60E-02
1.61E-01
l.bOt-01
1 ,50t-01
1 ,43t-Wl
1.41E-U1
1.40t-01
1.40t-01
1.34t-01
1.30t-01
1.20E-01
1.20fc-01
1 ,20t-0 1
1.20t-01
1.20L-01
1.20t-01
1.20t-01
1.20E-U1
1.20t-01
1.20E-01
l.lOt-01
1.10t-01
1.10t-01
1.10t-01
1.10E-01
1.10t-01
1.10E-01
1.02t-01
l.Olt-01
9.VOE-02
9.90E-02
9.90t-02
9.90E-02
9.90E-02
9..90E-02
4
a
4
6
3
3
3
6
2
4
6
6
6
6
6
6
6
6
6
2
2
1
2
6
6
6
3
4
4
4
4
2
2
-------
CYCLONE DUST* HEALTH IMPACT
DMEG NO.
23 A 144*
23 A 145*
21 6 141*
23 A 140*
06 A 020* M
51 A 010
23 C 120*
05 C 040 W
04 B 100*
23 B 200*
15 B 060* W
23 C 040*
70 A 010
04 A 140* P
57 A 010
23 C 140*
07 B 100* H
21 B 120* P
09 A 100*
09 A 080*
23 C 102*
23 C 101*
23 C 100*
23 C 000*
23 B 061
23 B 065
23 B 040
23 B 067
23 B 060
23 B 064
23 B 063
23 B 062
23 B 066
25 A 040*
M
1
NJ
O
COMPOUND NAME
2r6-DIMETHYLPYRIOINE
3,4-DIMETHYLPYRIDlNE
4-METHYL CHRYSENE
DISUBSTITUTEO POLYSUflSTITUTEO ALKYL PYRIOINES
ETHYLENE GLYCOL
BISMUTH
BENZO(A)CARBAZOLE
T-PENTANOL
2f2'-DICHLORODIISOPNoPYL ETHER
BENZCOACRIDINE
4,4'-DIPHENYLBIPHENYL
INOOLE
TUNGSTEN
2-CHLOROETHYL VINYL ETHER
CHLORINE (AS CL-)
DIBENZO(A,I)CARBAZOLE
CAMPHOR
CHRYSENE
lr3-DICYANO-l-HYDKOXYBUTANE
BUTYRONITRILE
9-METHYLCARBAZOLE
3-METHYLCAR8AZOLE
METHYLCARBAZOLES
CARBAZOLE
2,3-DIMETHYLQUINULINE
6,6-DIMETHYLQUINOLINE
2-METHYLQUINOLINE
1,5-DIMETHYLISOQUINOLINE
OIMETHYLQUINOLINES
3,4-DIMETHYLQUINOLINE
2f6-DIM£THYLQUINOLINE
2,6-DIMETMYLQUINOLINE
1,3-DIMETHYLISOOUINOLINE
METHYLTHIOPHENES
TYPE CONC
E-6 G/G
T
T
T
T
T
S
T
T
T
T
T
T
S
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1.40E 03
1.40E 03
1.40E 02
l.MOt 03
7.70E 02
3.00E-01
1.40E 03
3.40E 03
7.70E 02
7.70E 02
1.40E 02
7.70E 02
< 7.00E-OK
7.70E 02
5.70E 01
7.70E 02
7.70E 02
,40E 02
.40E 03
.40E 03
.40E 03
.40E 03
.40E 03
1.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
1.40E 03
US
2.60E-U2
2.60E-02
2.60E-U2
2.6UE-02
2.6UE-U2
2.50E-02
2.50E-02
2.42E-02
2.40E-02
2.40E-02
2.33E-02
2.33E-02
2.33E-02<
2.30E-02
2.20E-02
2.13E-02
2.13E-02
2.12E-02
2.12E-02
2.12E-02
2.10E-02
2.10E-02
2.10E-02
2.10E-02
2.00E-02
2.00E-02
2.00E-02
2.00E-02
2.00E-02
2.00E-02
2.00E-02
2.00E-02
2.00E-02
2.00E-02
G/S
9.90t-02
9.90E-02
9.90t-02
9.90t-02
9,BOt-02
9.50E-02
9.33E-02
9.22E-02
9.14E-02
9.14E-02
fl.VOt-02
8.9QE-02
8.90E-02
8.60E-02
8.33E-02
8.12E-02
8.12E-02
8. 10t-02
e.iot-02
8.10E-02
7.82E-02
7.82t-02
7.82t-02
7.82E-02
7.60L-02
7.60E-02
7.60t-02
7.60E-02
7.60E-02
7.60E-02
7.60E-02
7.60E-02
7.60E-02
7.60t-02
LCCAT
4
4
2
4
5
4
6
5
5
2
b
5
5
5
2
4
4
4
4
4
4
6
6
6
6
6
6
6
6
6
4
-------
w
I
10
DMEG NO.
CYCLONE DUST, HEALTH IMPACT
COMPOUND NAME TYPE
CONC OS
E-6 G/G
LCCAT
b/S
05
25
25
25
08
21
02
06
25
25
25
25
25
04
04
23
23
23
23
23
23
10
23
23
23
23
23
23
23
23
23
23
06
25
A
B
A
A
D
C
A
0
A
A
A
A
A
A
A
A
B
B
B
A
A
B
A
A
A
A
A
A
A
A
A
A
A
A
140 W
040* M
042*
041*
160
160*
140* P
060*
061
064
060
062
063
200
160* P
020*
021*
022*
020*
061
060
100
120
122
121
063
06U
060
062
061
063
062
060*
081
BENZYL ALCOHOL
BENZO(B)THIOPHENE
3-METHYLTHIOPHENE
2-METHYLTHIOPHENE
METHYL BENZOATE
PICkNE
DIBROMOCHLOROMETHANE
METHYL METHACRYLATE
2»3-OIMETHYLTHIOPHEN£
3,4-DIMETHYLTHIOPHENE
OIMETHYLTHIOPHENES
2»4-DIMETHYLTHIOPHEN£
2f5-OIMETHYLTHIOPHEN£
4-BROMOPHENYL PHENYL ETHER
CHLOROPHENYL PHENYL ETHER
PYRIDINE
QUINOLINE
ISOQUINOLINE
UUINOLINES
2-PHENYLPYRIUINE
PHENYLPYRIDINES
MORPHOLINE
COLLIDINES
2,4,6-COLLIDINE
5-ETHYL-2-METHYLPYRIDINE
4-PHENYLPYRIDINE
4-N-PROPYLPYRIDINE
MONOSUBSTITUTED ALKYL PYRIDINES
3-ETHYLPYKIDINE
2-ETHYLPYRIUINE
4-ETHYLPYRIDINE
3-PHENYLPYRIOINE
VALERIC ACID
2,3,5-TRIMETHrLTHIOPHEN£
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
3.40E
1.40E
1.4UE
1.4UE
3.40E
l.UOE
2.60E
7.70E
1.4UE
1.40E
1.40E
1.40E
1.40E
1.4UE
1.40E
7.70t
7.70E
7.70E
7.70E
3.40E
3.4QE
3.4UE
3.40E
3.40E
3.40E
3.40b
3.4UE
3.40E
3.40E
3.40E
3.40E
3.4UE
I.IOE
l.ttOE
03
03
03
03
03
02
03
02
03
03
03
03
03
03
03
02
02
02
02
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.OOE-02
.OOE-02
.OOE-02
.OOE-02
.90E-02
.90E-02
.90E-02
.63t-02
.61E-02
.blE-02
.61E-02
.61E-02
.61E-U2
.72E-02
.72E-02
.71E-02
.63E-02
.b3E-02
.6it-02
.61E-02
.61E-02
.61E-02
.61E-02
.61E-02
.61E-02
.61E-02
,blt"l>2
.blt-02
,61fc-02
.blfc-02
.61E-02
.61E-U2
1.61t-02
1.60E-02
7.
7.
7.
7.
7.
7.
7.
7.
6.
6.
6.
6.
b.
6.
b.
6.
6.
6.
b.
6.
6.
b.
b.
b.
6.
b.
6.
6.
6.
6.
6.
6.
6.
6.
60L-U2
60E-02
60E-02
bOb-02
20t-02
10t-02
10t-02
OUt-UeJ
SKJt-02
VOt-02
VQt-02
VQt"02
Vot»02
bOt-02
60t-02
bOt-02
^^t -Oef
d^t-U^
-------
CYCLONE DUST* HEALTH IMPACT
DM EG NO.
25 A 060
04 B 080
17 A 04}
17 A 041
17 A 042
17 A 040
04 B 040* P
07 B 160
07 B 182
07 B 181
06 D 200
21 C 120*
02 A 361
02 A 360
08 A 040*
09 B 041
09 B 020 W
09 B 040 W
09 B 042
05 B 100* W
23 A 143*
23 A 140*
23 A 144*
23 A 142*
23 A 145*
23 A 141*
23 A 146*
05 A 160
12 A 100
84 B 010
10 C 020*
23 C 120*
69 A 010
21 0 020*
ra
KJ
COMPOUND NAME
THIMETHYL AND TETRAMETHYL THJOPHENE3
2,2'-DICHLORODIETHYL ETHER
4-NITROTOLUENE
2-NITROTOLUENE
3-NITROTOLUENE
NITROTOLUENES
1,1'-D1CHLORODIETHYL ETHEH
CARVONES
DIHYDRO-(D OR DCARVONE
CARVONE(D OR L)
DIETHYL ADIPATE
BENZO(E)PYRENE
1-BROMOBUTANE
BROMOBUTANES
ACETIC ACID
A-NAPHTHONITRILES
BENZONITRILE
NAPHTHONITRILES
B-NAPHTHONITRILES
1-PHENYLETHANOL
2,5-DIMETHYLPYRIDlNE
DISUBSTITUTED POLY3UB3TITUTED ALKYL PYRIDINE3
2,6-DlMETHYLPYRIDINE
2,4-DIMETHYLPYRIDlNE
3»4-OIMETHYLPYRIOINE
2f3-DIMETHYLPYRIDlNE
2»3,4,6-TETRAMETHYL PYRIDINE
PHENETHYL ALCOHOL
N-NITROSODIPENTYLAMINE
CERIUM
ANILINE
BENZO(A)CARBAZOLE
MOLYBDENUM
DI8£NZO(A,H)PYREN£
TYPE CONC D3
E-6 G/G
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
3
T
T
3
T
1.40E 03
1.40E 03
1.40E 03
1.40E 03
1.40E 03
1.40E 03
1.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
1.4UE 02
2.60E 03
2.60E 03
1.10E 03
1.40E 03
1.40E 03
1.40E 03
1.40E 03
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.7UE 02
7.70E 02
7.70E 02
7.70E 02
3.40E 03
3.40E 03
1.50E 01
.60E-02
.60E-02
.60E-02
.60E-02
.60E-02
.60E-02
.60E-02
.54E-02
.54E-02
.54E-U2
.54E-02
.53E-02
.52E-02
.52E-02
.44E-02
.42E-02
.42E-02
.42E-02
.42E-02
.42E-02
.42E-02
.42E-02
.42E-02
.42E-02
.42E-02
.42E-02
.42E-02
.41E-02
.41E-02
.40E-02
7.70E 02 1.40E-02
7.7VE 02 1.40E-02
2.00E 00 1.33E-W2
1.40E 02 1.30E-02
MD3
b/s
6.1U-02
5.9U-02
5.9U-02
5.91E-02
b.9lt-02
5.91t-02
5.91E-02
5.90E-02
5.VOE-02
5.90t-02
5.90E-02
5.84fc-02
5.61E-02
5.61t-02
5.bOt»02
5.42E-02
S.42E-U2
5.42E-02
5.42t-02
5.41E-02
5.4U-02
5.4U-02
5.4U-02
5.41t-02
5.41E-02
5.4U-02
5.4U-02
5.40t-02
5.40t-02
5.20t-ti2
5.13t-U2
5.136-02
5.lOb-02
4.b3b-02
LCCAT
4
4
4
4
4
4
4
6
6
6
6
2
1
1
7
4
4
4
4
5
5
5
5
5
5
5
5
6
6
5
5
2
-------
PI
I
CYCLONE DUST, HfcALTH IMPACT
DMEG NO.
23 A 042*
23 A 043*
23 A O4i*
23 B 160
23 6 1UO
23 B 120
05 B 120
13 b 080
23 B 080
13 B 060
09 A 100*
02 B 120* P
09 A 080*
08 A 060*
23 C 100*
23 C 080*
23 C 101*
23 C 102*
08 A 000*
23 B 260*
25 A 0*42*
25 B 040* W
25 A 0«0*
25 A 0
-------
OMEG NO.
CYCLONE DUST, HEALTH IMPACT
COMPOUND NAME
TYPE
07 B 080* P
08 A 040*
04 A 160* P
02 A 160* P
^l A 020* P
04 B 040* P
08 D 320* P
66 A 010
21 A 140* P
85 A 010
16 A 200* P
22 B 040* P M
02 B 100* P
16 A 160* P
60 A 010
02 A 340* P
84 A 010
21 B 180* P
08 0 320* P
16 A 120* P
16 A 100* P
84 C 010
84 F 010
02 B 080* P
84 E 010
IS A 040*
16 A 020*
02 A 140*
15 A 060*
21 A 020*
16 A 140*
30 A 010
21 A 140* P
16 A 200* P
w
i
to
ISOPHORONE
ACETIC ACID
CHLOROPHENYL PHENYL ETHER
BROMOFORM
NAPHTHALENE
Irl'-DICHLORODIETHYL ETHEK
BUTYL BENZYL PHTHALATE
NIOBIUM (AS NB+3)
ANTHRACENE
URANIUM
CHLORONAPHTHALENES
FLUORANTHENE
OICHLOROPHOPENES
POLYCHLORINATED BENZENES
SCANDIUM
DICHLOROPROPANE8
LANTHANUM
PYRENE
BUTYL BENZYL PHTHALATE
1,3-DICHLOROBENZENE
1,2-DICHLOROBENZENE
PRASEODYMIUM
DYSPROSIUM
TETRACHLOROETHENE
SAMARIUM
TOLUENE
CHLOROBENZENE
DIBROMOCHLOROMETHANE
ETHYL BENZENE
NAPHTHALENE
1,4-DICHLUROBENZENE
RUBIDIUM (AS RBt)
ANTHRACENE
CHLORONAPHTHALENES
CQNC US
E-6 U/6
LCCAT
G/ii
T
T
T
T
T
T
T
S
T
S
T
T
T
T
S
T
8
T
T
T
T
8
8
T
8
T
T
T
T
T
T
8
T
T
7. TOE 02
7.70E 02
7.70E 02
1.40E 02
1.30E 03
7. TOE 02
3.40E 03
5.00E 00
1.30E 03
9.00E-01
1.30E 03
1.30E 03
1.40E 02
1.40E 02
5.00E 00
2.60E 03
e.oot oo
1.30E 03
7. TOE 02
1.30E 03
1.30E 03
2.00E 00
6.00E-01
2.60E 03
2.00E 00
1.30E 03
.30E 03
.40E 02
.30E 03
.40E 02
.30E 03
.OOE 00
.40E 02
.40E 02
1.02E-02
l.OU-02
9.bOE-03
9.33fc-U3
8.70E-03
8.60E-03
7.90E-03
7.70E-03
7.64E-03
7.50E-03
6.20E-03
4.64E-03
4.11E-03
4. OOE-03
3.12E-03
2.60E-03
2.40E-03
1.90E-03
1.80E-03
.446-03
.44E-03
.33E-03
.30E-03
.306-03
.306-03
.206-03
.20E-03
.OOE-03
.OOE-03
9.33E-04
9.30E-04
8.33E-04
8.23E-04
6.70E-04
3.90E-02
3.90E-02
3.61E-02
3.b4E-02
3.30t-02
3.30L-02
3.00E-02
2.92L-02
2.90E-02
2.64fc-02
2.40fc-02
l.bOfc-02
1.60t-02
l.blfc-02
1.20L-02
9.90L-03
8.94E-03
7.20E-03
6.feOt-03
5.50fc-03
5.SOE-03
5.10E-03
5.00t-03
4.93t-03
4. 74fc-03
4.bOE-03
4.50E-03
3.80E-03
3.BOE-03
3.54E-03
3.b2b-03
3.20t-03
3. 12t-03
2.53L-03
5
5
5
2
3
b
6
3
3
3
2
2
1
3
5
3
3
1
3
3
2
3
2
3
2
2
u>
-------
ro
CYCLONE DUST, HEALTH IMPACT
DMEG
22
31
21
16
16
02
15
16
15
16
02
45
04
21
21
21
22
21
21
29
53
84
22
21
58
59
04
B
A
6
A
A
A
A
A
A
A
B
A
A
A
D
A
D
A
A
A
NO.
040*
010
180*
120*
100*
340*
040*
020*
060*
140*
080*
010
160*
120*
120*
060*
020*
100*
100*
010
010
010
020*
080*
010
010
160*
P w
P
P
P
P
P
P
P
P
P
P
PH
PH
PH
PH
PH
PH
PH
PH
P
COMPOUND NAME
FLUORANTHENE
CESIUM
PYRENE
1, 3-DICHLOROBENZENE
1,2-DICHLOROBENZENE
DICHLOROPROPANES
TOLUENE
CHLOROBENZENE
ETHYL BENZENE
1,4-DICHLOROBENZENE
TETRACHLOROETHENE
TIN
A-CHLOROBUTYL ETHYL ETHER
ACENAPHTHYLENE
ACENAPHTHYLENE
BENZOCGHDPERYLENE
FLUORENE
ACENAPHTHENE
ACENAPHTHENE
POTASSIUM
SULFUR
NEODYMIUM
FLUORENE
BENZU(GHI)PERYLENE
BROMINE
IODINE (AS I-)
A-CHLOROBUTYL ETHYL ETHER
TYPE CUNC
E-6 G/G
T
S
T
T
T
T
T
T
T
T
T
S
T
T
T
T
T
T
T
D
D
S
T
T
S
S
T
1.40E
02
7. OOt-01
1.40E
.40E
.40E
.40E
.40E
.40E
.40E
,40E
1.40E
2.00E
1.40E
1.40E
1.30E
1.30E
1.40E
1.40E
1.30E
1.30E
l.lot
3.00E
1.30E
1.40E
9.00E
02
02
02
02
02
02
02
02
02
00
03
02
03
03
02
02
03
03
04
00
03
02
00
4.00E-01
7.70E
02
DS
5.00E-04
2.80E-04
2.02E-04
1.60E-04
1.60E-04
1.40E-04
1.30E-04
1.30E-04
1.10E-04
1.00E-04
7.00E-Ob
O.OOE-01
O.OOE-01
O.OOE-01
O.UOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-OI
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-OI
O.OOE-01
O.OOE-01
O.OOE-01
1
1
7
b
5
b
4
4
4
3
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NDS
b/S
.90E-03
.10fc-03
.7lt-04
.9U-04
.91E-04
.31E-04
,«3t-04
,b3t-04
.10t-04
.ttOt-04
,70t-04
.oot-oi
.OOt-01
.oot-oi
.OOt-01
.OOt-01
.OOt-01
.OOt-01
.OOt-01
.OOt-01
.OOt-01
.oot-oi
.oot-oi
.oot-oi
.oot-oi
.OUt-01
.oot-oi
LCCAT
2
2
2
2
2
2
2
2
2
2
4
2
3
3
2
2
3
3
2
5
-------
CYCLONE DUST
AVERAGE FLOW RATE « 3.8 G/3
207.15 G EXTRACTED TOTAL ORGANIC LOADING • 13 G/KG
TOTAL TCO • 0.66 G/KG TOTAL GRAV • 12.0 G/KG
3.aX ORIGINAL SAMPLE TO LC
LC TCO • 3.2 MG LC GRAV • 66.2 MG LC TOTAL » 91.4 MG
LCCAT ORGANIC LOADING
1 2600.0
2 140.0
3 1300.0
4 1400.0
5 770.0
6 3400.0
7 1100.0
FLON RATE • 3.60
STATES SOLID, UNITS IN MICROGRAHS/U
IMPACT! ECOLOGY
EXPERIMENTALY DETERMINED DATA
SPARK SOURCE DATA
m
Cn
-------
w
DMEG NO,
CYCLONE DUST, ECOLOGY IMPACT
COMPOUND NAME TYPE
CONC
E-6 G/G
b/S
LCCAT
16 A 220*
02 A 380*
16 A 220*
02 A 360*
48 A 010
08 D 261*
08 D 283*
08 D 282*
08 D 280*
08 D 263*
08 D 282*
08 D 281*
08 D 280*
19 A 000*
72 A 010
20 A 102*
20 A 101*
20 A 100*
20 A 060*
20 A 103*
10 C 220*
10 C 200*
10 C 140*
19 A 060*
01 B 220
16 A 063*
16 A 162*
16 A 061*
16 A 060*
16 A 160*
16 B 020*
16 A 161*
16 B 043*
16 A 060*
w
w
M
W
P W
P W
P W
P
W
W
W
W
P N
P W
W
P
W
POLYCHLORINATEO BIPHENYLS
HEXACHLOROCYCLOHEXANE
POLYCHLORINATEO BIPHENYLS
HfcXACHLOROCYCLOHEXANE
PHOSPHORUS
DIMETHYL PHTHALATE
DI-N-BUTYL PHTHALATE
DIETHYL PHTHALATE
PHTHALATE ESTERS (M"ll94-279)
DI-N-BUTYL PHTHALATE
DUTHYL PHTHALATE
DIMETHYL PHTHALATE
PHTHALATE ESTERS (MW:194-279)
PENTACHLOROPHENOL
IKON (AS FE + 2)
2,5-DINITROPHENOL
2,4-DINlTROPHENOL
DINITROPHENULS
2-AMINO-«,6-DINITROPHENOL
2,6-DINITKOPHENOL
2-AMINONAPHTHALENE
1-AMINONAPHTHALENE
BENZIDINE
PENTACHLOROPHENOL
DICYCLOPENTAOIENE
1,4-DI6ROMOBENZENE
HEXACHLORUBENZENE
1,2-DIBROMOBENZENE
DI8ROMQBENZENES
POLYCHLORINATED BENZENES
A-CHLOROTULUENE
1,2,
-------
CYCLONE DUST, ECOLOGY IMPACT
UMEb NO. COMPOUND NAME TYPE CONC
£-6 G/G
21 A 020* P
16 A 081*
16 A 140* P
16 A 040*
16 A 083*
16 A 120* P
16 A 100* P
16 B 040*
16 B 042*
16 A 062*
16 B 041*
16 A 082*
16 A 020* P
38 A 010
26 B 040 W
10 C 140* P W
20 A 103*
20 A 101* P
10 C 220* W
20 A 100* W
10 C 200* M
20 A 102*
20 A 060* W
18 B 040* W
18 A 101*
18 A 020* P W
18 A 140* W
18 B 020* W
18 A 180* W
18 A 060* W
16 A 181*
18 A 081*
18 A 102*
23 B 080* W
NAPHTHALENE
l-BROMO-2-CHLOROBENZENE
lr4-DICHLOROBENZENE
BROMUBENZENE
l-BROMO-4-CHLOROBENZENE
1,3-DICHLOROBENZENE
1,2-DICHLOROBENZENE
BIS (CHLORUMETHYL) BENZENES
lr3-BIS(CHLOROMETHYL)BENZ£NE
1,3-DIBROMOBENZENE
1,2-BI8(CHLOROMETHYBENZENE
l-BROMO-3-CHLOROBENZENE
CHLOROBENZENE
ALUMINUM
TRITOTYL PHOSPHATES
BENZIOINE
2r6-DlNITROPHENOL
2,4-DINlTROPHENOL
2-AMINONAPHTHALENE
OINITROPHENOLS
1-AMINONAPHTHALENE
2»5-DINlTROPHENOL
2-AMINO-«,6-DlNITROPHENUL
1,3-DIHYDROXYBENZENE
0-PHENYLPHENOL
PHENOL
XYLENOLS
CATECHOL
POLYALKYLPHENOLS (MN>135)
ETHYLPHENOLS
2,4,6-TRIMETHYL METHYL PHtNOL
0-ETHYLPHENOL
P-PHENYLPHENOL
ACRIDINE
T
T
T
T
T
T
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1.30E 03
1.30E 03
.30E 03
.30E 03
.30E 03
.30E 03
.30E 03
.30E 03
.30E 03
.30E 03
I.JOE 03
1.30E 03
1.30E 03
1.20E 04
1.10E 03
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
3.40E 03
US
6.50E 01
6.50E 01
6,SOt 01
6.SOE 01
6.SOE 01
6.50E 01
6.50E 01
6. SOt 01
6.SOE 01
6.SOE 01
6.SOE 01
6. SOt 01
6.SOE 01
6.00E 01
S.SOE 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.90E 01
3.40E 01
3.40E 01
3.40E 01
3.40E 01
3.40E 01
3.40E 01
3.40E 01
3.40E 01
3.40E 01
3.40E 01
3.40E 01
WDS
G/S
2.50t 02
2. 50t 02
2. bOb 02
2.50t 02
2. 50b U2
2. SOt 02
2.bOE 02
2. SOt 02
2. SOt 02
2. SOt 02
2. SOt 02
2. SOt 02
2. SOt 02
2.30t 02
2. lot 02
l.SOt 02
l.SOt 02
.SOt 02
.SOt 02
.SOt 02
.SOt 02
.SOt 02
.SOt 02
1.30E 02
1.30E 02
1.30E. 02
1.30t 02
1.30t 02
l.SOt 02
1.30fc 02
1.30E 02
1.30t 02
1.30t 02
1.30E. 02
LCCAT
3
3
3
3
3
3
3
3
3
3
3
3
3
7
S
5
5
5
5
5
5
5
6
6
6
6
6
6
I
ho
-------
w
OMEG NO.
CYCLONE OUST, ECOLOGY IMPACT
COMPOUND NAME TYPE
CONC US
£-6 G/G
HD8 LCCAT
b/3
18
18
18
20
18
20
18
20
18
18
18
18
18
19
18
18
19
18
18
18
18
20
19
20
19
18
20
16
19
16
16
16
19
16
A
A
A
A
C
A
B
B
B
A
C
A
C
B
A
A
B
A
A
C
A
A
A
A
A
A
B
A
B
A
A
A
B
A
163*
183*
120* W
020* P
083*
040*
060* W
out*
080* M
083*
020* M
100* w
040* W
021*
182*
042*
023*
043*
103*
082*
146*
120*
020* P
060* P
040* P
082*
042*
142* P
020* N
143*
041*
144*
022* P
J45*
2-ETHYL-P-CRESOL
2,6-DIMETHYL-4-HEPTYL PHENOL
2,2'-DIHYOROXYOlPHENYL
2-NITROPHENOL
5-INDANOL
3-MTROPHENOL
1,4-DlHYDROXYBENiENt
3,S-DINITRO-P-CRESOL
1,2,3-TRIHYDROXYBENZENE
P-ETHYLPHENOL
1-NAPHTHOL
PHfcNYLPHENOLS
2-NAPHTHOL
CHLORJNATED-0-CRE30LS
4,6-DI-TERT-BUTYL-M-CRESOL
0-CRESOL
CHLORINATED-P-CRESOLS
P-CRESOL
M-PHENYLPHENOL
4-INDANOL
3,4-XYLtNOL
2,4,6-TRINITROPHENOL
2-CHLOROPHENOL
4-NITROPHENOL
2f 4-DICHLOROPHENOL
M-tTHYLPHENOL
2,6-DINlTHO-P-CRESOL
2,4-XYLENOL
CHLORINATED CRESOLS
2r5-XYLENOL
M-CKESOL
2/6-XYLENOL
CHLORINATED-M-CRESOLS
3/5-XYLENOL
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
3.40E
3.40E
3.40E
3.40E
3.4ut
3.40E
3.40E
3.40E
3.40E.
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.aot
3.40E
3.40E
3.4UE
3.40E
3.40E
3.40E
3.40t
3.40E
S.aot
3.40L
3.40E
3.40E
3.40t
3.406.
3.«0t
3.40£
3.40E
3.40E
3.40E
3.40E
3.40E
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
1.30t
1.30E
l.J>Ot
1.30L
1.30t
1.30t
1.30L
1.30E
1.30t
1.30t
1.30t
1.30t
1.30t
1.30t
1.30t
1.30L
1.3ut
1.30t
1.30t
1.30t
1.30t
1.30t
1.30t
1.30t
l.^Ot
1.30t
1.30t
1.30t
l.iot
1.30h
1.30t
1.30t
1.30C.
1.30L
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
6
6
6
6
6
6
6
6
b
6
6
6
b
6
6
6
6
6
b
b
b
b
b
b
b
b
b
b
b
b
b
6
6
6
-------
CYCLONE DUSTr ECOLOGY IMPACT
DM
18
18
18
18
20
18
20
18
18
18
08
08
08
10
08
08
08
08
10
08
08
02
02
02
02
02
02
82
34
81
19
20
18
EG
C
A
A
A
B
A
a
A
C
A
A
D
D
C
D
D
D
D
A
D
D
B
A
A
B
B
B
A
A
A
B
8
B
18 B
NO.
081*
060* W
040* W
160* W
040* W
161*
020* P W
141*
080* H
162*
040* W
143*
140*
020*
121*
142*
120*
122*
080* w
123*
141*
080* P N
340* P
343*
104*
100* P W
103*
010 P
010
010 P
020* W
042*
020* W
040* M
COMPOUND NAME
1-INDANOL
2-METHOXYPHENOL
CRESOLS
ETHYL CRESOLS
DINITRO-P-CRESOL8
6-ETHYL-M-CRESOL
4,6-DINITRO-O-CRESOL
2*3-XYLENOL
INDANOLS
4-ETHYL-O-CRESOL
ACETIC ACID
ISOAMYL ACETATE
AMYL ACETATES
ANILINE
N-BUTYL ACETATE
SEC-AMYL ACETATE
BUTYL ACETATES
SEC-BUTYL ACETATE
1,2-DIAMINOETMANE
ISOBUTYL ACETATE
N-AMYL ACETATE
TETRACHLOROETHENE
DICHLOROPROPANE3
1 , 3-DICHLOROPRQPANE
TRANS-1 , 3-PICHLOROPROPENE
DICHLOROPROPENES
CIS-lr3-DICHLOROPROPENE
CADMIUM
CALCIUM (AS CA+2)
ZINC
CHLORINATED CRESOLS
2,6-DINJTRO-P-CRESOL
CATECHOL
1,1-DIHYDROXYBENZENE
TYPE CONC
E-6 G/G
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
8
D
S
T
T
T
T
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
2.60E
2.6UE
2.60E
2.60E
2.60E
2.60E
2.00E
2.90E
1.60E
7.70k
7.70E
7.70E
7.70E
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
00
04
02
02
02
02
02
OS
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
1.70E
1.70E
.70E
.70E
.70E
.70E
.70E
.70E
1.70E
1.70E
.70E
.30E
.30E
.30E
.30k
• 30E
.30E
.OOE
9.10E
a. OOE
7.70E
7.70E
7.70E
7.70E
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
00
00
00
00
ou
00
N08
G/S
1.30k
1.30E
1.30k
1.30k
1.30k
1.30k
1.30k
1.30k
1.30k
1.30k
6.50k
6.50k
6.50k
6.50k
6.50k
6.50k
6.50k
6.50k
6.50k
6.50k
6.bOk
4.93E
4.93t
4.93k
4.93k
4.93k
4.93k
3.bOk
3.44k
3.03k
2.92k
2.92k
2.92k
2.92k
LCCAT
02
02
02
02
02
02
02
02
02
02
01
01
01
01
01
01
01
01
01
01
01
01 1
01 1
01 1
01 1
01 1
01 1
01
01
01
01 5
01 5
01 5
01 5
M
-------
S3
to
CYCLONE DUST, ECOLOGY IMPACT
DMEG
18 C
19 e
16 J
18 E
16 /
16 E
18 t
18 C
18 t
18 t
16 t
19 f
18 '
19 f
18 (
18
23 1
18
16
18
19
19
18
18
20
16
16
16
16
16
18
18
16 A
16 A
NO.
062*
\ 021*
i 120* M
> 060* W
l 140* W
» 080* M
k 183*
: 020* N
k 160* W
k 040* W
^ 161*
} 022* P
k 182*
J 023*
: 061*
\ 103*
i 060* N
A 063*
A 160* M
A 161*
020* P
040* P
162*
163*
041*
020* P W
142* P
100* W
143*
101*
144*
102*
042*
146*
COMPOUND NAME
4-INDANOL
CHLORINATEO-0-CRE30LS
2»2'-DIHYDROXYDIPHENYL
1,4-D1HYDROXYBENZENE
XYLENOLS
1,2,3-TRIHYDROXYBENZENE
2,6-DIMETMYL-4-HEPTYL PHENOL
1-NAPHTHOL
POLYALKYLPHENOLS lMW>135)
CRESOLS
2»4,6-THIMETHYL METHYL PHENOL
CHLORlNATtU-M-CRESOLS
4,6-DI-TERT-BUTYL-M-CRESOL
CHLORINATED-P-CRESOLS
1-INDANOL
M-PHENYLPHENOL
ACRIDINE
P-ETHYLPHENOL
ETHYL CRESOLS
6-ETHYL-M-CRESOL
2-CHLOROPHENOL
2»4-DICHLOROPHENOL
4-ETHYL-O-CRESOL
2-ETH.L-P-CRESOL
3,5-DINITRO-P-CRESOL
PHENOL
2r4-XYLENOL
PHENYLPHENOLS
2r5-XYLENOL
0-PHENYLPHENOL
2/6-XYLENOL
P-PHENYLPHENOL
0-CP-ESOL
3* 4-XYLENOL
TYPI
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
E. CONC
E-6 G
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7. TOE
T.TOE
T.TOE
/G
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
US
7.7UE
7.70E
7.70E
7./OE
7.70E
7.70E
7.70E
7.70E
7.70E
7.70fc
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
7.70E
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
oo
00
00
00
00
00
00
00
00
00
00
00
00
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
NDS
G/S
,92t
u o t
O ^ K
o ^ t
y -j t
O 3 P
U JJ t
.92E
,92t
.926.
.92t
.92t
.92t
• *2E
.92t
,92t
.92t
.92t
,92t
.92E
.92t
• '2E
,V2t
.92t
. V2t
,V2t
«^2t
.V2t
,92t
.92t
.92t
,92t
.92fc
,V2fc
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
LCCAT
b
b
b
b
b
b
b
b
5
b
b
b
b
b
b
b
b
5
b
b
b
b
b
b
b
b
5
5
5
b
5
b
5
5
-------
CYCLONE DUST, ECOLOGY IMPACT
DMEG NO.
18 C 083*
16 A OfaO*
20 A 020* P
20 8 020* P
20 A 040*
18 A 141*
20 A 060* P
20 B 040*
18 A 043*
18 C 040*
18 A 080*
18 C 080*
18 A 041*
18 A 145*
18 A 082*
20 A 120*
18 A 081*
16 A 040*
16 A 161*
16 A 081*
16 A 160* P
16 A 120* P
16 A 020* P
17 A 082*
17 A 081* P
16 B 042*
21 A 020* P
16 B 043*
16 A 162*
17 A 083*
17 A 084* P
16 A 140* P
17 A 086*
17 A 085*
COMPOUND NAME
5-INDANOL
W 2-METHOXYPHENOL
2-NITROPHENOL
N 4,6-DINITRO-O-CRESOL
3-NITROPHENOL
2/3-XYLENOL
4-NITROPHENOL
N DINITRO-P-CRESOLS
P-CRESOL
W 2-NAPHTHOL
H ETHYLPHENOLS
W INDANOLS
M-CPESOL
3,5-XYLENOL
M-ETHYLPHENOL
2,4,6-TRINITROPHENOL
0-ETHYLPHENOL
BROMOBENZENE
1,2,4-TRICHLOROBENZENE
l-BROMO-2-CHLOROBENZENE
POLYCHLORINATED BENZENES
1,3-DICHLOROBENZENE
CHLOROBENZENE
3,4-DINITROTOLUENE
2,6-DINITROTOLUENE
1,3-BIS(CHLOROMETHYL)BENZENE
NAPHTHALENE
l,4-BIS(CHLOROM£THYL)BENZENE
HEXACHLOROBEN2ENE
2,3-DINJTHOTOLUENE
2,4-DWTROTOLUENE
1,4-DICHLOROBENZENE
3,5-DINITROTOLUENE
2,5-DINJTHOTOLUENE
TYPE CONC
t-6 li/G
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1
T
T
7.70E 02
7.70fc 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.7UE 02
7.70E 02
1.40E 02
.40E 02
.40E 02
.40E 02
.40E 02
.40E 02
.40E 03
.40E 03
.40E 02
.40E 02
1.40E 02
1.40E 02
1.40E 03
1.40E 03
1.40E 02
1.40E 03
1.40E 03
US
7.70t 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.70E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
7.00E 00
WQb
b/b
2.92E 01
2.92k. 01
2.92t 01
2.V2t 01
2.92t 01
2.V2fc 01
2.92t 01
2.92E 01
2.92E 01
2.92E 01
2.92E 01
2.92E 01
2.92E 01
2.92t 01
2.92L 01
2.92b 01
2.92h 01
2.70t 01
2.70t 01
2.70t 01
2.70E 01
2.70E 01
2.70E 01
2.70E 01
2.70E 01
2.70E 01
2.70E 01
2.70E 01
2.70t 01
2.70E 01
2.70E Ul
2.70E 01
2.70E 01
2.70L 01
LCCAT
5
5
5
b
5
5
5
5
5
5
5
5
5
5
5
5
5
2
2
2
2
2
2
4
4
2
2
2
2
4
a
2
4
4
t-o
-------
CYCLONE DUST, ECOLOGY IMPACT
OMi
16
16
17
16
16
16
17
16
16
16
16
17
17
17
00
04
16
17
04
16
IS
15
15
15
15
15
15
15
15
15
15
15
15
15
LG
A
A
A
B
A
B
A
A
A
B
A
A
A
A
A
A
A
A
A
A
B
A
B
B
B
A
B
8
B
A
A
B
B
6
NO.
083*
060*
042*
040*
061*
041*
060* M
082*
062*
020* W
063*
020* P W
040* W
043*
050* W
060* W
100* P
041*
040* W
080*
120* W
120* w
101*
106*
102*
060* P W
081*
0«3*
082*
100* w
040* P M
105*
104*
100* W
COMPOUND NAME
l-SROMO-4-CHLOROBENZENE
DIBROMOBENZENES
3-NITHOTOLUENE
BIS (CHLOROMETHYL) BENZENES
1,2-OIBROMOBENZENE
1,2-BIS(CHLOROMETHYBENZENE
DINITROTOLUENES
l-BROMO-3-CHLOROBENZENE
lr3-DIBROMOBENZENE
A-CHLOROTOLUENE
1,4-DIBROMGBENZENE
NITROBENZENE
NURUTOLUENES
4-NITROTOLUENE
EPICHLORHYORIN
1-CHLORO-1,3-EPOXYPKUPANE
1,2-DICHLUROBENZENE
2-NITROTOLUENE
2-CHLORO-U2-EPOXYPROPANE
BROMOCHLOROBENZENES
TETRAHYDRUNAPHTHALENE
ISOPROPYL BENZENE
0-DIETHYL BENZENE
lr4-DI-TERT-BUTYL BENZENE
M-OIETHYL BENZENE
ETHYL BENZENE
0-XYLENE
P-XYLENE
M-XYLfcNE
PKUPYL BENZENE
TOLUENE
M-OIISOPROPYL BENZENE
0-DIISOPROPYL BENZENE
OIALKYL BENZENES (M*jl3<»-19U
TYPE CONC
E-6 G/G
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1.4UE
1.40E
1.40E
1.40E
1.4UE
1.40E
1.40E
l.UOt
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
l.aoE
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
1.30E
02
01
03
02
02
02
03
02
02
02
02
03
03
03
03
03
02
03
03
02
03
03
03
03
03
03
03
03
03
03
03
03
03
03
us
7.00E
7.00E
7.00E
7.00E
7.00E
7.00E
7.00E
7.00E
7.00E
7.00E
7.00E
7.00E
7.00fc
7. Out
7.00E
7.00E
7.UOE
7.UOE
7.00E
7.00E
6.bOE
to.bOt
6.SOE
o.SOfc
6. bOt
6.50E
6.bOE
6.50E
6.50E
6.bOE
6.50E
6.bOE
6.bOfc
6.50E
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
oo
00
00
uo
uo
00
00
00
00
00
00
00
00
wDb
G/b
2.70fc
2.70E
2.70t
2.70E
2.70E
2.70t
2.70E
2.70t
2.70t
2.70E
2.70t
2.70L
2.70E
2.70t
2.70E
2.70t
2.70t
2.70E
2.70t
2.70t
2.bOt
2.bOt
2. but
2.bOt
2.bOt
2.b'Jt
2.bOt
2.bOt
2.bOt
2.bOt
2.bOt
2.50t
2.50E
2.bOt
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
LCCAT
2
d
4
2
2
2
4
2
2
2
2
4
4
4
4
4
2
4
4
2
3
3
3
3
3
3
3
3
3
3
3
3
3
3
-------
CYCLONE DUSTr ECOLOGY IMPACT
OHEG NO.
15 A 080* N
15 B 103*
15 B 060* W
49 A 010 P
06 A 040* M
15 B 020*
08 P 143*
17 A 081* P
04 A 060* W
08 D 121*
08 A 040* N
06 D 140*
17 A 084* P
08 0 123*
17 A 020* P W
08 D 120*
17 A 082*
17 A 085*
10 A 080* W
17 A 083*
08 0 122*
04 A 040* M
17 A 043*
17 A 080* N
17 A 086*
17 A 040* M
08 D 141*
10 C 020*
08 0 142*
17 A 041*
04 A 050* W
17 A 042*
76 A 010 P
54 A 010 P
COMPOUND NAME
STYRENE
P-DIETHYL BENZENE
XYLENE8
ARSENIC
ACETIC ACID
INOAN
ISOAMYL ACETATE
2,6-DINlTKOTOLUENE
1-CHLORO-1,3-EPO*YPROPANE
N-BUTYL ACETATE
ACETIC ACID
AMYL ACETATES
2,4-DlNlTROTOLUENE
ISOBUTYL ACETATE
NITROBENZENE
BUTYL ACETATES
3,4-DlNlTROTOLUENE
2,5-DINlTROTOLUENE
1,2«DIAMINOETHANE
2»3-DINITROTOLUENE
SEC-BUTYL ACETATE
2-CHLORO-lr2-EPOXYPROPANE
4-NITROTOLUENE
OINITROTOLUENES
3r5»DINITROTOLUENE
NITROTOLUENES
N-AMYL ACETATE
ANILINE
SEC-AMYL ACETATE
2-NITROTOLUENE
EPICHLORHYDRIN
3-NITROTOLUENE
COPPER
SELENIUM
TYP
T
T
T
0
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
8
D
E CONC
E-6 G/G
,30E 03
.30E 03
.30E 03
6.30E 01
.10E 03
.30E 03
7.70E 02
7.70E 02
7.70E 02
7.7UE 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.7UE 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
7.70E 02
3.00E 01
1.40E 01
OS
6.bOfc 00
b.bOE 00
6.50E 00
6.30E 00
5.SOE 00
4.64E 00
3.64E 00
3.64E 00
3.&4E 00
3.84E 00
3.04E 00
3.84E 00
3.84E 00
3.64E 00
3.64E 00
3.84E 00
3.b4E 00
3.64E 00
3.84E 00
3. tut 00
3.84E 00
3.b4E 00
3.«4fc 00
3.b4E 00
3.84E 00
3.84E 00
3.84E 00
3.64E 00
3.64E OU
3.84E 00
3.84t 00
3.84E 00
3.00E 00
2.80E 00
NOS
G/3
2.50E 01
2. SOt 01
2.50E 01
2.40E 01
2. lOt 01
l.«0fc Ul
l.SOt Ul
l.SOE 01
l.bOt 01
l.SOb 01
l.bOt Ul
l.bOt 01
1.50L Ul
l.bOt 01
l.bOt Ul
l.bOt 01
l.bOt 01
l.bOfc 01
l.bOt 01
l.SOt 01
l.bOL 01
l.SOt 01
l.bOt 01
l.bOt 01
l.bOt 01
l.bOt 01
l.bOt 01
l.bOb Ul
l.but 01
l.bOt 01
l.bUt 01
l.bOt 01
l.iat ui
l.iot 01
LCCAT
3
3
3
7
3
5
5
b
5
b
5
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
W
I
KJ
NJ
UJ
-------
w
DMEG NO.
CYCLONE OUST* ECOLOGY IMPACT
COMPOUND MAME TYPE
CONC OS
E-6 (i/li
LCCAT
b/S
36
62
08
76
06
06
06
06
08
08
06
10
08
23
05
23
05
23
23
23
08
23
23
23
23
05
05
23
05
10
05
10
05
23
A
A
A
A
A
A
A
A
A
A
D
A
D
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
A
A
A
B
A
A
010
010
080*
010 P
101*
104*
102*
103*
100*
IbO*
101*
160*
100*
020* W
124*
121*
121*
063*
060* H
122*
060* W
081*
120* W
064*
061*
100* W
122*
080* W
123*
060*
120* W
100*
140* W
083*
BARIUM
TITANIUM
VALERIC ACID
NICKEL
CAPROIC ACID
LAURIC ACID
CAPRYLIC ACID
CAPRIC ACID
SATURATED LONG CHAIN ACIDS (MW:116-201)
ADIPIC ACID
N-PROPYL ACtTATE
CYCLOHEXYLAMINE
PROPYL ACETATES
PYHIDINE
3-METHYL-l-BUTANOL
5-ETHYL-2-METHYLPYRIDINE
N-PENTANOL
4-ETHYLPYRIDINE
MONOSUBSTITUTED ALKYL PYRIDINES
2,4,6-COLLIOINE
B-PROPIOLACTONE
2-PHENYLPYRIDINE
CULLIOIMES
4-N-PKOPYLPYRIDINE
2-ETHYLPYKIDINE
ISOBUTYL ALCOHOL
2-METHYL-l-BUTANOL
PHENYLPYRIDINES
2r2-DIMETHYL-l-PHOPANOL
ETHANOLAMINE
PENTANOLS (PRIMARY)
MORPHOLINE
BENZYL ALCOHOL
fl-PHENYLPYRJDlNE
D
D
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1.30E
4.00E
3.40E
4.00E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.4UE
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40k
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.40E
3.4UE
3.40E
3.40E
3.40E
3.40E
03
02
03
00
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
2.60E
2. SOt
2. JOE
2.00E
1.90E
1.90E
1.90E
1.90E
1.90E
l.tiOt
1.70E
1.70E
1.70E
1.70E
.70E
.70E
.70E
.70E
,70E
1.70t
1.70E
1.70E
1.70E
1.70E
,70E
,70£
.70E
.70E
,70E
.70E
,70E
.706
.70E
1.70E
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
9.90t
9. SOt
6. bit
7.60t
7.20t
7.20t
7.«20t
7. dot
7.20t
b.bOt
6. SOt
6. SOt
6. SOt
6. SOt
6. SOt
6.50fc
b.SOt
6. SOt
6. SOt
b.SOt
6. SOt
b.SOt
6. SOt
b.SOt
b.SOt
b.SOt
b.SOt
b.SOt
b.SOt
6.50E
6. SOt
b.SOt
6. SOt
6. SOt
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
6
6
6
6
6
6
-------
DMEG NO.
CYCLONE DUST, ECOLOGY IMPACT
COMPOUND NAME TYPE
CONC US
E-6 G/G
LCCAT
23 A
08 D
06 A
23 A
07 B
01 A
01 A
07 b
71 A
09 B
09 B
09 B
09 B
08 A
46 A
08 A
02 A
15 B
15 A
23 A
15 A
02 B
23 A
15 H
23 A
23 A
23 A
04 6
15 A
04 b
23 A 1
23 A (
23 A <
02 b C
M
1
ro
NJ
062*
080*
020* W
062*
100* W
201
200
120*
010 P
041*
042*
020* W
040* W
140*
010 P
080*
343*
120* M
060* W
061*
040* P M
100* P W
120* M
106*
121*
122*
080* M
040* P W
120* W
080* M
381*
320* W
)62*
)80* P W
3-ETHYLPYKIDINE
METHYL METHACRYLATE
ETHYLENE GLYCOL
3-HHEMYLPYRIDINE
CAMPHOR
N-OCTANE
OCTANES
ACETOPHENONE
MANGANESE
A-NAPHTHONITRILES
6-NAPHTHONITRILES
BENZONITRILE
NAPHTHONITRILES
OLEIC ACID
LEAD
VALERIC ACID
1,3-DICHLOROPROPANE
TETRAHYORONAPHTHALENE
STYRENE
2-ETHYLPYRIUINE
TOLUENE
DICHLOROPROPENES
COLLIDINES
lr4-DI-TERT-bUTYL BENZENE
5-ETHYL-2-METHYLPYRIDINE
2,4,6-COLLlUlNE
PHENYLPYRIDJNES
1, 1 '-DICHLORODIETHYL ETHER
ISOPROPYL BENZENE
2,2'-DICHLOROOIETHYL ETHER
2-PHENYLPYRIDINE
PYRIDINE
3-ETHYLPYRIUINE
TETRACHLOROETHENE
T
T
T
T
T
T
T
T
D
T
T
T
T
T
S
T
r
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
3.40E
3.40E
3.40E
3.40E
3.40E
2.60E
2.60E
3.40E
1.90E
1.40E
1.40E
1.40E
1.40E
3.40E
8.00E
1.10E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
L.40E
1.40E
.40E
.40E
.40E
.40E
.40E
.40E
.40fc
.4uE
.40E
.40E
03
03
03
03
03
03
03
03
01
03
03
03
03
03
00
03
02
02
02
03
02
02
03
02
03
03
03
03
02
03
03
03
03
02
1.70E 00
1.70E 00
1.70E 00
1.70t 00
l.54fc Ou
1.30E 00
1.30E 00
1.10E 00
9.bOE-01
8.60E-01
0.60E-01
«.60t-01
8.60h-01
6.30E-01
8.00E-01
7.33E-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00t-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
6
6
6
6
5
4
4
4
3
3
3
3
3
3
3
2
2
2
2
2
2,
2,
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
2.
.bOt
,50h
,50t
.bOt
,90h
.V3h
.93t
,20t
.61h
,32t
,32h
,32t
.32h
.20h
.04h
.tiOt
,70fc
,70h
, 70t
,70t
70t
70t
70h
70t
70t
70h
70h
70t
70t
7oh
7ot
70t
70t
70t
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
6
6
6
6
6
1
1
6
4
4
4
4
6
7
2
2
2
4
2
2
a
2
4
4
4
4
2
4
4
4
4
2
-------
N>
ro
CYCLONE OUST, ECOLOGY IMPACT
UME
02
IS
17
15
15
15
23
15
15
15
15
03
15
15
23
15
23
15
02
23
23
02
17
15
15
15
15
65
03
06
06
06
06
06
.G
B
8
B
B
6
A
A
B
A
B
B
B
B
8
A
B
A
B
B
A
A
A
B
B
8
6
B
A
A
A
A
A
A
A
NO.
103*
Obi*
060* W
080* w
082*
000* P W
064*
100* W
100* W
083*
101*
020*
105*
103*
082*
102*
083*
104*
104*
063*
060* H
340* P
040* H
201*
200*
203*
202*
010
103*
102*
100*
101*
104*
180*
COMPOUND NAME
CIS-l,3-DICHLOROPkoPENE
0-XYLENE
l-CHLORO-4-NITROBENZENE
XYLENES
M-XYLENE
ETHYL BENZENE
4-N-PROPYLPYRIDINE
DIALKYL BENZENES (MW»134-191)
PROPYL BENZENE
P-XYLENE
0-DIETHYL BENZENE
1,4-DIOXANE
M-DIISOPRUPYL BENZENE
P-DIETHYL BENZENE
3-PHENYLPYRIDINE
M-UIETHYL BENZENE
4-PHENYLPYRIDINE
0-OIISOPRUPYL BENZENE
TRANS- 1,3-DICHLOKOPKOPENE
4-tTHYLPYRIDINE
MONOSUBSTITUTED ALKYL PYRlDINES
DICHLOROPROPANES
l-CHLORO-2-NITROBENZENE
1,2,3,4-TETKAMETHYLbENZENE
TETRAMETHYLBENZENES
1,2,4,5-TETRAMETHYLBENZENE
1,2,3,5-TETRAMETHYLBENZENE
VANADIUM
CAPRIC ACID
CAPRYL1C ACID
SATURATED LONt CHAIN ACIDS (M*:llo-201)
CAPROIC ACID
LAURIC ACID
ADIPIC ACID
TYPE CONC
E-6 G/G
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
*•
T
T
S
T
T
T
T
T 1
T 1
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
1.40E
l.aot
1.40E
1.40E
1.40E
1.40E
1.40E
l.aot
1.4UE
1.40E
1.4UE
.40E
.40E
.4UE
.30E
,30t
.30E
.30E
.90E
.lot
.10E
.lot
.lot
.lot
.10E
02
02
03
02
02
02
03
02
02
02
02
03
02
02
03
02
03
02
02
03
03
02
03
03
03
03
03
01
03
03
03
03
03
03
DS
7.00E-01
7.0Ut-01
7.UOt-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00fc-01
7.UOE-01
7.00t"01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00E-01
7.00t-01
7.00E.-01
7.00E-01
7.uOt-01
7.UOt-01
7.00t-01
7.00E-01
7.00E-01
6.50t-01
6.bOt-01
6.bOE-Ul
6.50fc"01
6.33E-01
6.11E-01
6.11E-01
6.11E-01
6.11t-Ul
6.11E-01
5.80E-01
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
*ut>
Wb
,70t
,/ot
.70t
.70t
,70t
.70t
,70t
.70t
,70t
.7ot
,70t
,70t
,70t
,70t
.70t
,70t
.70t
,70t
,70t
,70t
,/ot
,70t
.70t
,bOt
,50t
.bOt
.bOt
,40t
.32h
.32t
,32t
.32L
,32t
.20t
00
OU
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
oo
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
LCCAT
2
2
a
2
2
2
a
2
2
2
2
a
2
2
4
2
a
2
2
a
a
2
4
3
3
3
3
7
7
7
7
7
7
-------
OMEG NO.
CYCLONE DUSTr tCULOGY IMPACT
COMPOUND NAME TYPE
CONC
E-6 G/G
WDb
G/S
LCCAT
OR B 060*
08 A 060*
15 B 020*
09 B 042*
09 B 040*
09 B 020*
09 B 041*
33 A 010
06 A 104*
06 A 100*
06 A 103*
06 A 102*
06 A 101*
06 A 160*
23 A 020*
06 D 060*
10 A 160*
23 A 063*
06 B 060*
05 A 100*
05 A 120*
17 B 060*
23 A 121*
23 A 064*
10 A 060*
23 A 060*
08 D 100*
03 B 020*
23 A 081*
23 A 061*
05 A 122*
23 A 082*
05 A 140*
23 A 062*
w
w
w
w
w
w
w
w
w
w
B-PROPIOLACTONE
VALERIC ACID
INDAN
B-NAPHTHONITRILES
NAPHTHONITRILE3
8ENZONITRILE
A-NAPHTHONITRILE3
MAGNESIUM
LAURIC ACID
SATURATED LONG CHAIN ACIDS (MWlllb-201)
CAPRIC ACID
CAPRYLIC ACID
CAPROIC ACID
ADIPIC ACID
PYRIDINE
METHYL METHACRYLATE
CYCLOHEXYLAMINE
4-PHENYLPYRIDINE
B-PROPIOLACTONE
I8UBUTYL ALCOHOL
PENTANOLS (PRIMARY)
1-CHLORO-4-NITROBEN2ENE
5-ETHYL-2-MfcTHYLPYRlDlNE
a-N-PROPYLPYRIDINE
ETHANOLAMINE
PHENYLPYRIDINES
PROPYL ACETATES
1,4-DIOXANE
2-PHENYLPYRIDINE
2-ETHYLPYRIOINE
2-METHYL-l-BUTANOL
3-PHENYLPYRIDINE
BENZYL ALCOHOL
3-ETHYLPYRIDINE
T
T
T
T
T
T
T
D
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
1
7
1
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7,
7,
7,
7,
7,
7,
7,
7,
7,
7,
7,
7.
7,
7.
7.
7.
.10E
.70E
.40E
.70E
.70E
.70E
.70E
.60E
.70E
,70£
.70E
.70E
.70E
.70E
.70E
,70t
.70E
.70E
.70E
.70E
,70E
.70E
,70E
,70E
,70E
,70E
,70E
,70E
,70E
,70E
,70E
70E
70E
70E
03
02
02
02
02
02
02
03
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
02
5.50E-01
5.13E-01
5.00E-01
4.81E-01
4.61E-01
4.61E-01
4.61E-01
4.60E-01
4.30E-01
4.30E-01
4.30E-01
4.30E-01
4.30E-01
4.10E-01
3.90E-01
3.90E-01
3.90E-01
3.90E-01
3.90E-01
3.90t-01
3.90E-01
3.90t-01
3.90E-01
3.90E-01
3.90E-01
3.90E-01
3.90E-01
3.90E-01
3.90E-01
3.90E-01
3.90E-01
3.90E-01
3.90E-01
3.90fc-01
2. 10E
2.00t
1.90t
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1,
1,
1.
1,
1,
.62b
,62b
.b2t
,b2b
.74t
.62t
.62t
,62b
.62E
.62E
.53E
.bOE
,50b
.bOt
.bOfc
.bOb
.bOt
.but
.bOt
.bob
.but
,bOb
.bob
.bOb
.bOfc
.bOb
.bOb
,bOb
,bOb
,bOb
,bOE
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
uu
00
00
00
7
5
2
5
5
b
5
5
5
5
5
b
5
5
5
5
5
b
b
b
b
b
b
b
5
b
5
5
5
b
5
b
b
IV)
ro
-------
I
KJ
K)
00
CYCLUNE DUST, ECOLOGY IMPACT
OMfcb
Ob
23
23
23
05
10
06
05
04
05
04
17
23
07
08
07
66
79
08
05
08
05
06
08
74
27
15
15
15
15
08
83
05
08
A
A
A
A
A
B
0
A
b
A
b
B
A
B
A
B
A
A
A
A
0
C
A
B
A
A
B
B
B
B
B
A
C
0
NO.
020* M
120* W
060* W
063*
121*
100*
1U1*
123*
040* P N
124*
080* W
040* M
122*
100* W
140*
120*
010 P
010 P
140*
080*
320* P
040* W
040*
080*
010
010
203*
200*
201*
202*
080*
010 P
040* W
320* P
COMPOUND NAME
ETHYLENE GLYCOL
COLLIOINES
MONOSUBSTITUTEO ALKYL PYRIDINES
4-hTHYLPYRIDINE
N-PENTANOL
MOKPHOLINE
N-PROPYL ACETATE
2,2-DIMETHYL-l-PROPANOL
1, I'-DICHLUKODIETHYL ETHEK
3-METHYL-l-BUTANOL
2r2'-DICHLORODIETHYL ETHEH
l-CHLORO-2-NITROBENZENE
2,4,6-COLLIOINE
CAMPHOR
OLEIC ACID
ACETOPHENONE
CHROMIUM
SILVER
OLEIC ACID
N-BUTANOL
BUTYL BENZYL PHTHALATE
T-PENTANOL
PROPYLENE GLYCOL
Y-BU1 ,'ROLACTONE
COBALT
LITHIUM
1,2,4,5-TETRAMETHYLBENZENE
TETRAMETHYLBENZENES
1,2,3,4-TETRAMETHYLBENZENE
1,2,3,5-TETRAMETHYLbENZENE
Y-BUTYROLACTONE
MERCURY
T-PENTANOL
BUTYL BENZYL PHTHALATE
TYPE CONC
E-6 G/G
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
S
S
T
T
T
T
T
T
S
S
T
T
T
T
T
D
T
T
7
7
7
7
7
7
7
7
7
7
7
7
7
7
1
7
1
2
7
3
3
3
3
3
5
6
1
1
1
1
1
< 2
7
.70E
.70E
• 70E
.70E
.70t
.70E
.70E
.701:
.70E
,70E
.70E
.70E
,70E
.70E
.lot.
,70E
.lot
.OOE
.70E
.40E
.40E
.40E
.40E
.40E
.OOE
.OOE
.40E
.40E
.40E
• «OE
.lot
.30E
,70E
7.70E
02
02
02
02
02
02
02
02
02
02
02
02
02
02
03
02
01
00
02
03
03
03
03
03
00
00
02
02
02
02
03
00<
02
02
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
1
1
1
1
1
1
1
8
7
7
7
7
5
4
3
US
.90E-01
.90E-01
.90E-01
.90E-01
.90E-U1
.90E-01
.90E-01
.90E-01
.90E-01
.90E-01
.90E-01
.90E-01
.VOE-01
.bOE-01
.70E-01
.bOE-01
.20E-01
.OOE-01
,90t-01
.70E-01
.70E-01
.70E-01
.70E-01
.70E-01
.OOE-01
.OOE-02
.OOE-02
•WOE-02
.OOE-02
.OOE-02
•bOE-02
,60E-02<
.90E-U2
3.90E-02
HDb
G/3
l.bOt 00
l.bOt 00
1.50L 00
l.bOt 00
,bOt 00
.bOt 00
.bOt 00
,50t 00
.bOt 00
l.bOt 00
l.bOt UO
l.bOt 00
l.bOE 00
1.33E 00
l.OU 00
9.43t-01
B.40E.-01
7.60E-01
7.13t-01
6.50t-01
6.50t-yi
6,bOfc-01
6.50t-01
6.bOt-yi
3.b0t-0l
3.03t-01
2.70t-01
2.70t-yi
2.70t-01
2.70fc-01
2.10t-01
1.74fc-Wl
l.bOt-01
l.SOt-01
LCCAT
5
b
>3
b
b
5
5
b
b
b
b
5
5
5
7
b
5
6
6
6
6
6
2
2
2
d
1
5
b
-------
CYCLONE DUST, ECOLOGY IMPACT
UMEG NO.
Ob A 040*
06 B 060*
05 A 080*
32 A 010 P
37 A 010
50 A 010 P
65 A 010
69 A 010
12 A 060* P
02 B 140* P
02 6 140* P
04 A 160* P
43 A 010
02 H 120* P
51 A 010
04 A 140* P
12 A 040* P
04 A 140* P
04 A 160* P
02 A 140* P
02 8 120* P
02 A 160* P
34 F 010
56 A 010
39 A 010
28 A 010
35 A 010
53 A 010
02 A 140* P
12 A 040* P
21 A 140* P
12 A 060* P
21 A 180* P
57 A 010
tn
l
r-o
NJ
COMPOUND NAME
PROPYLENE GLYCOL
Y-BUTYROLACTONE
N-BUTANOL
BERYLLIUM
BORON
ANTIMONY
URANIUM
MOLYBDENUM
N-NITROSOUIPROPYLAMINE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROCYCLOPENTAD1ENE
A-CHLOROtiUTYL ETHYL ETHER
SILICON
HEXACHLOROBUTADIENE
BISMUTH
2-CHLOROETHYL VINYL ETHER
N-NITROSODIETHYLAMINE
2-CHLOROETHYL VINYL ETHER
A-CHLOROBUTYL ETHYL ETHER
DIBROMOCHLOKOMETHANE
HEXACHLOROBUTADIENE
BROMOFOR*
DYSPROSIUM
FLUORINE (AS F-)
GALLIUM
SODIUM
STRONTIUM
SULFUR
DIBROMOCHLOROMETHANt
N-NITROSOUIETHYLAMINE
ANTHRACENE
N-NITROSODIPRUPYLAMINE
PHENANTHRENt
CHLORINE (AS CL-)
TYPE
T
T
T
S
D
0 <
S
S
T
T
T
T
U
T
S
T
T
T
T
T
T
T
S
S
S
D
D
U
T
T
T
r
T
D
COixC
E-6 U/G
7.70E 02
7.70E 02
7.70E 02
4.00E-01
l.luE 02
4.00E-Ol<
9.00E-01
2.00E 00
3.4UE 03
2.60E 03
1.40E 02
7.70E 02
l.bOE 04
2.60E 03
3.00E-01
1.40E 03
3.40E 03
7.70E 02
1.40E 03
2.60E 03
1.40E 02
2.60E 03
6.00E-01
2.80E 02
3.30E 01
l.lUt 04
1.40E 03
1.10E 04
1.40E 02
7.70E 02
1.30E 03
7.70E 02
1.30E 03
5.70E 01
OS
3.VOE-U2
3.90E-02
3.90t-02
3.63E-02
2.20E-U2
1.00t-02<
9.00t-03
1.42E-03
o.oot-oi
O.UOE-01
O.OOE-U1
O.OOE-OI
O.OOE-01
O.OOE-01
O.OOt-Ul
O.OOE-01
O.OOE-01
O.UOE-U1
O.OOE-01
O.OOE-01
O.OOE-01
o.ooE-oi
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
o.oot-oi
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
o.oot-oi
O.OOE-01
O.OOE-01
WS
l.bOt-01
l.bOt-01
1.50t-01
1.4ut-0l
6.40t-U2
3.bOt-02
3.42t-02
5.42t-03
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
O.OOt-01
O.OOt-01
O.OOt-01
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
O.OOE-01
O.OOt-01
o.oot-oi
O.OOt-01
O.OOt-01
O.OOt-01
o.oot-oi
LLCAT
5
1,
0
1
2
5
1
4
0
5
4
1
2
1
2
S
3
5
3
-------
w
NJ
OJ
o
DMEG
21
21
21
21
21
29
21
21
21
21
21
12
12
22
58
22
64
31
22
22
22
04
04
04
04
44
59
84
16
16
21
84
21
66
8
6
B
B
B
A
C
C
C
0
0
A
A
B
A
C
B
A
C
0
D
A
A
B
B
A
A
A
A
A
A
D
B
A
NO.
040*
120*
120*
160*
180*
010
060*
100*
100*
080*
080*
020*
020*
040*
010
020*
010
010
080*
020*
020*
180*
180*
020*
020*
010
010
010
200*
200*
180*
010
040*
010
P
P
P
P
P
P
P
P
PH
PH
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
CYCLONE DUST,
COMPOUND NAME
BENZ(A)ANTHKACENE
CHRY8ENE
CHRYSENE
PYHENE
PYHENE
POTASSIUM
DIBENZ( A, H) ANTHRACENE
BENZO(A)PYRENE
BENZO(A)PYRENE
BENZO(GHI)PERYLENE
BENZO(GHI)PERYL£NE
N-NITKOSODIMETHYLAMlNE
N-NITROSODIMETHYLAMlNE
FLUORANTHENt
BROMINE
BENZO(K)FLUORANTHENE
CEHIUM
CESIUM
BENZO(B)FLUORANTHENE
INDENO(l,2f 3-CDJPYRENE
INDENO(1,2,3-CD)PYRENE
CHLOROPHENYL PHENYL ETHER
CHLOROPHENYL PHENYL ETHER
1,1'-DICHLOROMETHYL ETHER
i,l'-DICHLOROMETHYL ETHER
GERMANIUM
IODINE (AS I-)
LANTHANUM
CHLORONAPHTHALENES
CHLUfeONAPHTHALENES
PHENANTHRENE
NEODYMIUM
BENZ(A)ANTHRACENE
NIOBIUM (AS NB+3)
ECOLOGY IMPACT
TYPE CONC
E-6 G/G
T
T
T
T
T
D
T
T
T
T
T
T
T
T
S
T
S
S
T
T
T
T
T
T
T
S
S
S
T
T
T
S
T
S
1
1
1
1
1
1
1
1
1
1
1
3
7
1
9
1
1
7
1
1
1
1
7
1
7
6
4
6
1
1
1
3
1
5
.30E
• 40E
.30E
.40t
.30E
.30E
.30E
.40E
.30E
.40E
.30E
.40E
.70E
.40E
.OOE
.40E
.50E
03
02
03
02
03
03
03
02
03
02
03
03
02
02
00
02
01
.OOE-01
.30E
.40E
.JOE
.40E
.70E
.40E
.70E
.OOE
03
02
03
03
02
03
02
00
.OOE-01
.OOE
.40E
.30E
.40E
.OOE
.40E
.OOE
00
02
03
02
00
02
00
OS
o.oot-oi
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
O.OOE-Oi
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0, OOE-01
0. OOE-01
O.OOE-U1
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
0. OOE-01
WDfc
l»/S
o.oot-ui
0. OOE-01
O.UOE-U1
o.oot-oi
O.OOE-Oi
O.OOE-U1
O.OOt-01
O.OOt-01
O.OOt-01
0. OOE-01
0. OOE-01
0. OOE-01
o.oot-ui
o.oot-ui
O.OOt-01
O.OOt-01
O.OOt-01
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-oi
o.oot-ui
O.OOt-01
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-01
o.oot-oi
o.oot-oi
o.oot-ui
0. OOE-01
o.oot-oi
O.OOt-01
O.OOt-01
LCCAT
3
2
3
2
3
3
2
3
2
3
b
b
2
i.
3
2
3
4
5
4
5
2
3
2
2
-------
OMEG NO.
CYCLONE OUST, ECOLOGY IMPACT
COMPOUND NAME TYPE
CONC OS
E-6 G/G
LCCAT
(i/S
84 C 010
30 A 010
84 E 010
60 A 010
21 C 080* P
55 A 010
41 A 010 P
85 B 010
45 A 010
70 A 010
22 A 020* PH
22 A 020* PH
61 A 010
22 B 040* P
63 A 010
22 C 020* P
22 C 080* P
07 B 080* P
07 B 080* P
08 D 300* P
08 D 300* P
02 A 160* P
02 A 320* P
02 A 320* P
21 A 100* PH
21 A 100* PH
21 A 120* PH
21 A 120* PH
21 A 140* P
PRASEODYMIUM
RUBIDIUM (AS HBO
SAMARIUM
SCANDIUM
DIBENZ( A, H) ANTHRACENE
TELLURIUM
THALLIUM
THORIUM
TIN
TUNGSTEN
FLUORENE
FLUORENE
YTTRIUM (AS Y+3)
FLUOHANTHENE
ZIRCONIUM (AS ZRt4)
BENZO(K) FLUOR ANTHENt
BENZO(B)FLUORANTHENE
ISOPHORONE
ISOPHORONE
DI-2-ETHYLHEXYL PHTHALATE
DI-2-ETHYLHEXYL PHTHALATE
BROMOFORM
HEXACHLOROETHANE
HEXACHLOROETHANE
ACENAPHTHENE
ACENAPHTHENE
ACENAPHTHYLENE
ACENAPHTHYLENE
ANTHRACENE
S
S
S
S
T
S
S
S
S
S
T
T
S
T
3
T
T
T
T
T
T
T
T
T
T
T
T
T
T
2.00E 00
3.00E 00
2.00E 00
5.00E 00
1.40E 02
2.00E-01
9.00E-01
2.00E 00
2.00E 00
< 7.00E-OK
1.40E 02
.JOE 03
.30E 01
.JOE 03
.90E 01
.30E 03
.40E 02
7.70E 02
3.40E 03
7.70E 02
3.40E 03
1.40E 02
2.60E 03
1.40E 02
1.40E 02
1.30E 03
1.40E 02
1.30E 03
1.40E 02
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-Oi
O.OOE-01
O.OOE-01
O.OOE-01<
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOfc-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-U1
O.OOE-01
O.OOE-01
O.OOE-01
O.OOE-01
O.OOfc-01
O.OOfc-01
O.OOE-01
O.OOfc-01
O.OOfc-01
o.oot-oi
O.OOfc-01
O.OOE-01
O.OOfc-01
o.oot-oi
O.OOE-01
O.OOt-01
O.OOt-01
O.OOE-01
O.OOE-01
O.OOfc-01
o.oot-oi
O.OOfc-01
O.OOE-01
O.OOfc-01
O.OOE-01
O.OOb-01
o.oofc-oi
o.oot-oi
o.oot-oi
o.oot-oi
O.OOt-01
o.oot-oi
O.OOt-01
2
2
3
3
3
2
5
0
5
6
2
1
2
2
3
2
3
2
w
I
-------
APPENDIX F
LEVEL 1 EPA HEALTH EFFECTS TESTS
ON COAL GASIFICATION SAMPLES
Final Report
to
RADIAN CORPORATION
P.O. Box 9948
Austin, TX 78766
AOL Reference C-82986
Subcontract under EPA Prime Contract 68-01-4136
(Task 15, Subtask 03)
May 31, T979
F-l
-------
TABLE OF CONTENTS
Page
I. INTRODUCTION 1
II. SUMMARY OF RESULTS 2
III. SPECIAL HANDLING OF SAMPLES 3
IV. SALMONELLA MUTAGENESIS ASSAY (AMES) OF SAMPLES
T.E. 2276, GASIFIER ASH; T.E. 2277, CYCLONE
DUST; FS-26, CYCLONE QUENCH HATER;
FS-1-714-2, ASH SLUICE WATER; 358-714, SASS
TEST BURNER COMPOSITE; AND 647-714, SASS
PRODUCT GAS COMPOSITE 6
Summary 6
Methods and Materials 6
Results 8
V. IN VITRO CYTOTOXICITY ASSAYS 12
A. WI-38 ASSAY OF SAMPLES FS-26, CYCLONE QUENCH
WATER; FS-1-714-2, ASH SLUICE WATER; 647-714,
SASS TEST BURNER COMPOSITE; AND 358-714, SASS
PRODUCT GAS COMPOSITE 12
Sumnary 12
Materials and Methods 12
Results 14
B. RABBIT ALVEOLAR MACROPHAGE (RAM) ASSAY OF
SAMPLES T.E. 2276, GASIFIER ASH; AND
T.E. 2277, CYCLONE DUST 19
Summary 19
Materials and Methods 19
Results 20
VI. ACUTE IN VIVO TOXICOLOGICAL TEST OF SAMPLES
T.E. 2276, T.E. 2277, FS-1-714-2, FS-26 AND
358-714 IN RODENTS - QUANTAL RESPONSE 23
Summary 23
Materials and Methods 23
Results 25
F-2
-------
I. INTRODUCTION
Arthur D. Little, Inc., Cambridge, MA 02140, conducted Level 1 EPA
Health Effects Tests on Coal Gasification Samples for the Radian Corpora-
tion. This study was begun on March 6, 1979, and completed on May 31,
1979. Samples are identified and described in Section III.
The test matrix conducted is given below:
Test Matrix
Bioassay
Sample No. DescriptionAmes HI-38 RAM Rodent
x x
x x '
x
x
T.E. 2276
T.E. 2277
FS-26
FS-1-714-2
647-714
358-714
Gasifier Ash
Cyclone Dust
Cyclone Quench Water
Composite of Ash Sluice
Water »'s 44, 54, 69
SASS Test Burner Composite
SASS Product Gas Composite
x
X
X
X
X
X
X
X
X
X
F-3
-------
II. SUMMARY OF RESULTS
In the Ames assay, no sample appeared to be mutagenic for any tester
strain with or without metabolic activation. Sample 358-714 (SASS Pro-
duct Gas Composite) was extremely toxic to the tester strains and could
only be tested at concentrations less than 10 yl/plate.
In the WI-38 assay, samples FS-1-714-2 (Composite of Ash Sluice
Water) and 358-714 (SASS Product Gas Composite) were moderately toxic.
Samples FS-26 (Cyclone Quench Water) and 647-714 (SASS Test Burner
Composite) were not cytotoxic at the highest concentrations tested
(600 and 80 -.I/ml).
In the RAM assay, samples T.E. 2276 (Gas1f1er Ash) and T.E. 2277
(Cyclone Dust) gave no detectable toxicity at 1,000 yg/ml.
In the Rodent Acute Toxicity (Quantal) Test, samples T.E. 2276
(Gasifier Ash), T.E. 2277 (Cyclone Dust), FS-26 (Cyclone Quench Water),
FS-1-714-2 (Composite of Ash Sluice Water), and 358-714 (SASS Product
Gas Composite) caused no deaths. The data indicate that the single-
dose oral LDg0 value for each of these materials 1s greater than
10.0 gm/kg or 10.0 ml/kg.
F-4
-------
III. SPECIAL HANDLING OF SAMPLES
The following six samples were received at Arthur D. Little, Inc.,
on March 6, 1979, from D. Scott Lewis, Analytical Chemistry Division,
Radian Corporation:
Sample No.
I.E. 2276
I.E. 2277
FS-26
FS-1-714-2
647-714*
358-714*
Description As Received
Gasifier Ash
Cyclone Dust
Cyclone Quench Water
Composite of Ash Sluice Water #'s 44, 54, 69
SASS Test Burner Composite
SASS Product Gas Composite
Solvent exchanged with dimethylsulfoxide (DMSO) before assay.
See text below.
Composition and stability of these materials was unknown.
Residual samples remaining from the conduct of these bioassays have
been returned to the Radian Corporation.
The solvents used in the bioassays are shown below:
Sample No.
T.E. 2276
T.E. 2277
FS-26
FS-1-714-2
647-714
358-714
Solvent Used
Ames
Dimethylsulfoxide
(suspension)
Dimethylsulfoxide
(suspension)
Sterile water
Sterile water
Dimethylsulfoxide
Dimethylsulfoxide
In Vitro Cytotoxicity Rodent
Tissue Culture Medium Saline
Tissue Culture Medium Saline
Tissue Culture Medium None
Tissue Culture Medium None
Tissue Culture Medium Not done
Tissue Culture Medium None
-------
Sterility
All samples were tested for sterility upon receipt. Liquid samples
FS-26 and FS-1-714-2 were tested by inoculation into Trypticase Soy
Broth (TSB), Thioglycollate Broth (THIO), and by streaking on nutrient
agar plates. Broth tubes were incubated at 37°C and at room temperature
for a period of one week. Nutrient agar plates were incubated at 37°C
for one week. Solid samples I.E. 2276 and I.E. 2277 were inoculated
onto nutrient agar plates and incubated at 37°C for one week. FS-26
proved to be grossly contaminated in TSB and THIO at room temperature;
all other sterility checks were negative. FS-1-714-2 was grossly con-
taminated in all tubes at both 37°C and room temperature and the nutrient
agar plates were free of contamination. Solid sample T.E. 2276 showed
mold contamination and T.E. 2277 showed no contamination. Even though
both liquid samples and sample T.E. 2276 showed contamination (in the
sterility tests described above), we chose not to filter-sterilize
these materials to avoid loss of sample on the filters. Instead, we
spot-tested the samples directly in the Ames assay medium, the liquids
at 250 J/piate, and the solid at 2,000 wg/plate, all in duplicate. In
this less rigorous test, no microbial contaminants grew; therefore, the
materials were tested as received. Samples 647-714 and 358-714 were
solvent-exchanged into DMSO upon receipt and were therefore not tested
for sterility.
Solvent Exchange Procedure
Samples 647-714 (SASS Test Burner Composite) and 358-714 (SASS
Product Gas Composite) were methylene chloride extracts in 1:1
methylene chloride and ethyl ether. These two samples required solvent
exchange, outlined below, before bioassay.
F-6
-------
Protocol for Solvent Exchange of Extracts
in Methylene Chloride and Ethyl Ether
Into Dimethylsulfoxide (DMSO)
Sample 647-714 - SASS Test Burner Composite (333 ml)
Sample 358-714 - SASS Product Gas Composite (412 ml)
+
Sample 647-714 Mas transferred to a flask containing
333 ml DMSO.
Sample 358-714 was transferred to a flask containing
412 ml DMSO.
+
Samples were mixed for one minute.
+
Methylene chloride and ethyl ether were removed under
a stream of nitrogen gas at 30°C for 6 hours.
4- 4-
SASS Test Burner Composite SASS Product Gas Composite
DMSO volume, 118.0 ml DMSO volume, 124.0 ml
4- 4-
48.5 ml DMSO added 13.3 ml DMSO added
4- 4-
Final volume, 166.5 ml Final volume, 137.3 ml
2X original concentration 3X original concentration
Resulting solvent-exchanged samples were concentrated 2X or 3X
with respect to original volumes received. Doses and EC5Q in bioassays
are expressed in terms of original sample volumes.
r-7
-------
IV. SALMONELLA MUTAGENESIS ASSAY (AMES) OF SAMPLES I.E. 2276. GASIFIER ASH:
I.E. 2277. CYCLONE DUST; FS-26, CYCLONE QUENCH WATER;
FS-1-714-2. ASH SLUICE WATER; 358-714, SASS TEST BURNER COMPOSITE;
AND 647-714. SASS PRODUCT GAS COMPOSITE
SUMMARY
All samples were assayed in duplicate in the plate incorporation
assay of Ames against Salmonella typhimurium strains TA-98, TA-100, TA-1535,
TA-1537 and TA-1538 with and without metabolic activation. Solid samples
were tested at four log doses, the highest dose being either 10 or 1 mg/
plate depending upon the compatibility of the sample with the test system.
Liquid samples were tested at 250, 200, 150 and 100 ul/plate except for
sample 358-714 which was extremely toxic and could only be tested at 10,
2, 0.4 and 0.08 vl/plate.
No sample appeared to be mutagenic in the presence or absence of
metabolic activation.
MATERIALS AND METHODS
The above samples were tested in the plate incorporation mutagenesis
assay of Ames. The Salmonella typhimurium strains TA-98, TA-100, TA-1535,
TA-1537 and TA-1538 used in this study were obtained from Dr. Bruce N. Ames.
The protocol for the assay is described in the IERL-RTP Procedures Manual,
Level 1, EPA 600/6-77-04, April, 1977. The assay was conducted with and
without metabolic activation (S-9) in a culture medium which contains in-
sufficient histidine to allow the tester strains to proliferate sufficiently
to give colonies. After incubation at 37°C for 48 hours, the mutant colonies
(formed by his* revertants) are counted. Results are reported as total
number of revertants per plate and the standard error of the mean is
calculated.
F-8
-------
Briefly, in this assay 0.5 ml of the test organism, 1.0 ml of the
histidine/biotin supplement and 0.1 ml of the appropriate solid sample
dilution (or 1.5 ml of the appropriate liquid dilution) were added to
10.0 ml of 0.6% molten top agar (or 9.0 ml of 0.6% molten top agar for
liquid samples). Two ml of this molten top agar mixture was then pipetted
onto each of duplicate Minimal Glucose Agar plates with and without
0.5 ml/piate of the S-9 mixture (Aroclor-induced rat S-9 prepared at
Arthur D. Little, Inc., on July 18, 1978).
Solid sample T.E. 2276, Gaslfier Ash, was tested at four log doses,
the highest dose being 10 mg/plate. Solid sample T.E. 2277, Cyclone
Dust, was tested at four log doses, the highest dose being 1.0 mg/plate.
A higher dose of T.E. 2276 could not be dispensed because of its vis-
cosity. Both solids were tested as suspensions. Liquid samples FS-26,
Cyclone Quench Water; FS-1-714-2, Composite of Ash Sluice Water; 647-714,
SASS Test Burner Composite, and 358-714, SASS Product Gas Composite, were
tested at 250 yl/plate, 200 yl/plate, 150 pi/plate and 100 yl/plate.
Liquid sample 358-714 was highly toxic at all of these doses and at
50 yl/plate; this sample was therefore assayed at 10 yl/plate, 2.0 yl/plate,
0.4 yl/plate and 0.08 yl/plate.
Controls which were included in every experiment consisted of nega-
tive (solvent) controls for the spontaneous reversion rate for each tester
strain, and the positive controls listed below, compounds which do and
do not require metabolic activation. Positive controls were made up
fresh the day of the assay.
F-9
-------
Positive Control Chemicals
Tester Strain
TA-98
TA-100
TA-1535
TA-1537
TA-1538
Non-Activation (-S-9)
Daunomycin, 10 yg/plate
Methylmethane sulfonate, 50 yg/plate
N-methyl-N'-nitro-N-nitrosoguanidine, 50 yg/plate
9-Aminoacridine, 50 yg/plate
2-Nitrofluorene, 10 yg/plate
Activation (+S-9)
All Strains 2-Anthramine, 10 yg/plate
RESULTS
Results are presented in the following tables.
No mutagenic activity was evident in any sample.
Sample I.E. 2276 was moderately toxic at the top dose of 10 mg/plate.
Sample 358-714 was highly toxic at all four doses in the initial
assay (250, 200, 150, and 100 yl/plate). It was also toxic at 50 yl/
plate. At 10 yl/plate it was toxic to TA-98 and TA-1538 without meta-
bolic activation and to TA-100 both with and without metabolic activation.
Senior Technician Evaluating Material
Case Leader, Senior Staff
Section Leader, Bio/Medical
Sciences Section
eth M. Mochen, B.S.
Andrew SiVak; Ph.D
F-10
-------
AMES ASSAY
CYCLONE QUENCH HATER IFS-26 AND
COMPOSITE OF ASH SLUICE MATER 11-714-2
Revertants Per Plate*
TA-98
Control
2-Anthramine**
(10 ug/plate)
Daunomycln***
(10 Mg/p1ate)
2-N1trofluorene**
(10
21 tl
>500
>500
>500
Nethylmethane sulfonate**
(50 pg/plate)
N-methyl-N'-nltro-N-
nltrosoguanldlne**
(50 ug/plate)
9-A«1noacr1d1ne+
(50 ug/plate)
Cyclone Quench Mater
IFS-26***
ilOO u I/plate
150 Ml/plate
200 Ml/plate
250 pi/plate
TA-1538
TA-100
TA-1535
-59
20±4
+59
24 1 5
-59
15 t 3
+59
16 tl
-59
104 t 2
+59
112t1
-59
10±2
+59
TA-1537
14 tl
>500
>500
262 t 17
118tl
>500
7tO
49±3
-59
6tl
9tl
1791 9
234 til
THTC
tt
THTC
t
+t
Mean of 2 replicate plates ± standard error of the mean.
Dissolved and/or suspended In dimethylsulfoxlde (DMSO).
Dissolved In sterile water.
Dissolved In 95t ethanol.
Too numerous to count.
9±1
+59
711
821 4
9t2
22 tl
32 ±0
22 1 2
21 tl
25 1 4
28i 1
27 t 3
23 tl
11t5
9t1
8tO
8tl
15 tl
16 1 2
12 1 3
14 tl
104 t 5
110t5
114±9
104 18
97 1 7
118 1 14
105t1
104 1 3
10t2
8tO
14 tl
9t1
9tl
8t1
7tl
11t3
8tl
9t1
8tl
Stl
7t2
Stl
8t3
10t1
Composite of Ash Sluice
Water 11-714-2***
100 Ml/plate)
150 ^I/plate)
200 pi/plate)
250 iil/plate)
18 t 2
17t1
25 1 2
26 1 2
20 1 5
26 tl
29 1 8
23 tl
10 tl
10 1 4
9t3
10 tl
IStl
14 1 2
16 1 4
17t1
100 ±2
91 tl
113tl
93 tO
110±8
116t3
11017
105 1 10
9t2
lltl
10t2
6tO
9t2
6tO
7tl
12t1
5±2
7i2
6±0
9t2
9t1
6±2
11±2
6*1
-------
AMES ASSAY
6ASIFIER ASH IT.E. 2276 AND CYCLONE DUST IT.E. 2277
Revertants Per Plate*
Control
2-Anthramine**
(10 gg/plate)
Daunomycin***
(10 pg/plate)
2-N1trofluorcne**
(10 ug/plate)
Methylmethane sulfonate**
(50 ug/plate)
N-roethyl-N'-nltro-N-
nltrosoguanldin***
(50 gg/plate)
9-Am1noacrid1nef
(50 pg/plate)
TA-98
TA-1538
TA-100
TA-1535
-S9
23 + 1
34+2
TNTC1t
+S9
26+1
>500
TNTC
-S9
17*1
13+3
>500
+S9
19+1
>500
>500
96 + 2
127 + 4
112 + 2
>500
-S9 +S9
14 + 4 12 + 4
10 + 2
68 + 2
187 + 9
213 + 0
>500
TNTC
TA-1537
-S9
6+1
262 + 22
* Mean of 2 replicate plates + standard error of the mean.
** Dissolved and/or suspended in dimethylsulfoxide (OMSO)
*** Dissolved In sterile water (H20).
r Dissolved in 95% ethanol.
tt Too numerous to count.
+59
8 + 1
6+1 102 + 1
141110
GaslHer Ash IT.E. 2276**
0.01 ing/plate)
0.1 nig/plate)
1.0 mg/plate)
10.0 mg/plate)
:yclone Oust IT.E. 2277**
0.001 mg/plate
0.01 mg/plate)
0.1 mg/plate)
1.0 mg/plate)
15±3
20 ±2
18 + 1
17 + 3
20+0
18+1
18 + 1
16+1
22+12
20 + 4
20+10
23 ±3
22 + 4
19 + 5
30+1
21 1 1
14 + 2
10 ±1
12 + 2
4 + 1
12*1
11 +3
8 + 0
10 + 2
10 + 0
14 ±2
12 ±1
12 tl
13 + 0
16 + 1
12 t 4
14 1 2
86 1 2
85 ±2
85 i 7
86 + 3
78±4
881 1
100 + 4
98 + 11
78 + 14
86 + 8
104 + 4
90 + 2
85 ±7
94 + 1
86+1
104 + 8
12 + 1
13+4
lOtl
7±3
10 + 2
12 + 6
16 + 1
14 ±2
7±2
12 tl
8 + 2
7tl
8 + 4
8+3
14±2
7 + 2
6 + 1
7 + 1
5 + 0
6 + 2
6 + 2
4±1
4 + 2
4 + 1
6 + 2
4tO
6t2
4 + 0
7±1
6 + 4
7 + 3
6 + 1
-------
AMES ASSAY
!—•
u>
Control
2-Anthramlne**
(10 pg/plate)
Daunomycln***
(10 pg/plate)
2-N1trof1uorene**
(10 pg/plate)
Methylmethane sulfonate**
(10 pg/plate)
N-Mthyl-N'-nltro-N-
nltrosoguanldlne**
(50 pg/plate)
9-Am1noacr1d1net
(50 u9/p1ate)
SASS Test Burner Coup.
1647-714**
100 ul/plate
150 pi/plate
200 pi/plate
250 pi/plate
SASS TEST BURNER COMPOSITE 1647-714 AND
SASS PRODUCT GAS COMPOSITE 1358-714
Revertants Per Plate*
TA-98 TA-1538 TA-100 TA-1535
-59 +S9 -S9 +S9 -S9 +S9 -§9 tS9
15 ±3 30 ±1 9±2 16 ±1 90 ±5 108 ±0 10 ±1 15 ±0
29 ±2 265 ±17 8±2 307 ± 92 99 ±7 361 ±39 12 ±1 39 ±2
TNTCtf TNTC
TA-1537
-S9 +S?
7±4 5±0
2±0 19±3
422 ±35 244 ±12
195 ±2
257 ±19
TNTC
TNTC
t
•ii
Mean of 2 replicate plates ± standard error of the mean.
Dissolved and/or suspended In dimethylsuIfoxide (OMSO).
Dissolved In sterile water.
Dissolved In 951 ethanol.
Too numerous to count.
10 ±5
8±1
12 ±3
15±2
18 ±0
14±3
18 ±1
33 ±1
25 ±4
33 ±3
10±1
5±1
8±1
10±2
16 ±0
18 1 3
17 ±1
21 ±1
96±2
100 ±9
104 ±3
78 ±13
92 ±4
115±5
115±5
121 ±7
9±2
8±1
6±1
8±2
14 ±4
17±8
19±1
13 ±1
3±0
4±1
5±1
6±2
7±1
8±1
6il
6il
SASS Product Gas Coup.
1358-714**
(0.08 Ml /pi ate)
(0.4 pi/plate)
(2.0 pi/plate)
(10 pi/plate)
11±2
11 ±2
23 ±5
toxic
33 ±4
30 ±2
33 ±2
23 ±7
6±2
5+1
9±3
toxic
13 ±1
16 ±2
19±3
8±1
62 ±2
74 ±4
68 til
toxic
98±6
98±3
103 ±13
toxic
14±1
8±1
9±1
6t1
15±2
15 ±2
13 ±1
11±1
1 ±1
6±0
5±1
5±1
9±3
4±1
4±1
9±1
-------
V. IN VITRO CYTOTOXICITY ASSAYS
A. UI-38 ASSAY OF SAMPLES FS-26. CYCLONE QUENCH WATER; FS-1-714-2. ASH
SLUICE WATER; 647-714. SASS TEST BURNER COMPOSITE; AND 358-714. SASS
PRODUCT GAS COMPOSITE
SUMMARY
Samples were assayed In triplicate in the WI-38 assay and determina-
tions of total cell counts, cell viability (trypan blue exclusion), pro-
tein and ATP levels were made at 20 hours. Samples FS-26 and 647-714
caused no detectable toxicity at the highest concentrations tested (600
and 80 yl/ml). Samples FS-1-714-2 and 358-714 caused moderate toxicity.
Sample
FS-26
FS-1-714-2
647-714
358-714
ECert Values in ul/ml
Cell Number
>600
145
>80
>120
Viability
>600
320
>80
>120
Viability
Index
>600
88
>80
>120
Protein
>600
54
>80
10
ATP
>600
35
>80
14
Toxicity
Classification
None
Moderate
None
Moderate
MATERIALS AND METHODS
WI-38 (human lung fibroblast) cells were originally received from
the American Type Culture Collection and subsequently stored frozen 1n
our liquid nitrogen bank. Cells were subcultured twice weekly in 75 cm2
Falcon flasks (Co-Star) with Basal Medium, Eagle's modification (BME,
G1bco #420-1100) plus 10* fetal calf serum (Kansas City Biologicals),
2 ymoles/ml L-glutamine, 2.5 vg/ml Fungizone, 100 units/ml Penicillin,
100 yg/ml Streptomycin, and 1.25 mg/rnl NaHC03 (complete BME). After
washing with Hank's Balanced Salt Solution, cells were removed by the
F-14
-------
action of 0.25% trypsin and split in a 1:2 ratio and incubated in com-
plete BME at 37°C in a humidified 5% C02 atmosphere with loose caps.
For assay, the cells (between passages 20 and 30) were plated at
2.0 x 10 cells/well in complete BME (4-well cluster dishes, Falcon
Plastics) and allowed to adhere for 24 hours. The medium was then
aspirated and the chemicals, diluted to appropriate concentrations in
culture medium, were added to triplicate wells and the dishes incubated
for 20 hours. Concentrated BME (2.5X) was used to dilute the 600 pi/
ml samples of FS-26 and FS-1-7H-2. Samples 647-714 and 358-714 had
been solvent-exchanged into DMSO and concentrated to 2X and 3X original
concentration. Due to solvent toxicity the highest concentrations of
these samples that it was possible to test were 80 and 120 yl/ml,
respectively (i.e., 40 yl/ml effective DMSO concentration). Changes
in medium pH were noted at the beginning and end of this 20-hour period.
Cells were removed by trypslnization, diluted with fresh medium, and
allquoted as follows for assay: 3.0 ml for protein assay, 1.0 ml for
ATP assay, and 0.5 ml for viability and total cell counts.
The protein assay aliquots were washed twice 1n cold phosphate-
buffered saline and the cell pellets stored at -85°C. The ATP assay
aliquot was also stored at -85°C. Viability (trypan blue exclusion) and
total cell count aliquots were kept on ice and determinations were made
immediately; protein (Lowry method) and ATP (DuPont Luminescence Bio-
meter) assays were performed within two weeks.
F-15
-------
RESULTS
Results are presented in the following tables.
Cells treated with sample 358-714 (SASS Product Gas Composite) at
the two highest concentrations tested (120 and 60 pi/ml) contained
numerous particles and it was difficult to distinguish viable from
non-viable cells.
Senior Technician Evaluating Material
Case Leader, Senior Staff
Section Leader, Bio/Nedical
Sciences Section
rolyn tf. CresWell, M.A
;", Ph.D.
F-16
-------
HI-38 CYTOTOXICITY ASSAY
Sample No.:
Description
of Sample:
Date Received:
Date Tested:
Vehicle:
358-714
Product
March 6,
April 10
Cell Viability:
Gas Composite Passage
1979
. 1979
Dimethyl sulf oxide
Seeding
No.:
Population:
94.6%
30
l.SxIOVwell
pH Alterations:
Lowest
change:
pH:
dose for pH
pH at highest dose:
1.8 ul/ml
8.1
7.3+8.2
ECcn Values
DU
Viability
Viability
Protein:
ATP:
•
•
Index :
>120 pi /ml
>120 ul/ml
10 ul/ml
14 pi /ml
Toxlclty Classi-
fication
Comments:
: Moderate toxiclty
Due to solvent
toxlclty,
to test at
unable
higher
concentrations.
Test Results*
Sample
Veh. Cont.**
1
Veh. Cont.
2
Veh. Cont.
3
Veh. Cont.
4
Veh. Cont.
5
Dose
i.l /ml
40
120
20
60
6
18
2
6
0.6
1.8
2
4
4
5
4
4
5
4
5
5
Total
Cells
.40x10?
.13x10*
.80x10?
.62x10*
.47x10?
.18x10*
.44x10?
.71x10*
.27x10?
.98x10*
%
Viable
82.2
94.0
92.3
95.6
89.7
65.2
95.4
87.7
87.3
90.8
Viability
% T/C
114.4
«.
103.6
72.7
—
91.9
_
104.0
Viability
Index
1.62
—
1.12
0.61
^
0.76
—
1.03
Protein
wg/ml
42.56
16.17
70.91
23.77
82.06
21.03
90.84
72.15
75.50
78.18
Protein
ATP
ATP
% T/C fg/10<> cells % T/C
38.0
_
33.5
25.6
_
79.4
_
103.6
3.42x10?
5.21x10*
2.45x10?
3.13x10°
2.27x10-}
2.47x10*
1.73x10?
2.83xlOy
2.18xlOQ
2.82x10*
15.3
.
12.8
•»
• 10.9
_
164.3
-
129.4
* Mean values for vehicle control and triplicate test samples.
** Same concentration of vehicle as In corresponding test.
This sample was concentrated 3X in solvent exchange procedure (See Section III)
of original sample volumes.
Data are presented in terms
-------
HI-38 CYTOTOXICITY ASSAY
00
Sample No.:
Description
of Sample:
647-714
SASS Test
Cell Viability: 94.
Burner
Composite
Date Received:
Date Tested:
Vehicle:
March 6, 1979
April 10,
1979
methyl sulf oxide
Passage No.:
30
6X
Seeding Population: 1.8xlOVwell
pH Alterations:
Lowest dose
change:
pH:
for pH
1.2
ul/ml
6.9+8.0
pH at highest dose: 7.2
ECC« Values
"OU
Viability:
Viability
Protein:
ATP:
: >80 ul/ml
Index: >80 ul/ml
>80 ul/ml
>80 ul/ml
Toxiclty Classl- No detectable
flcation:
Comments:
: toxlclty.
Due to solvent
toxldty. unable
to test at higher
concentrations.
Test Results*
Sample
Veh. Cont.*«
1
Veh. Cont.
2
Veh. Cont.
3
Veh. Cont.
4
Veh. Cont.
5
Dose
pi /ml
40
80
20
40
6
12
2
4
0.6
1.2
Total
Cells
2.70x10?
3.38x10*
3.47x10?
4.71x10*
4.67x10?
5.11x10*
3.94x10?
5.60x10*
5.97x10?
5.69x10*
X
Viable
74.2
88.4
93.3
93.4
92.7
88.5
88.2
94.5
89.2
89.4
Viability
% T/C
—
119.1
_
100.1
.
95.5
_
107.1
_
100.2
Viability
Index
«•
1.11
_
1.28
.
0.97
_
1.34
.»
0.853
Protein
ug/ml
42.56
48.75
70.91
70.10
82.06
97.91
90.84
102.67
75.50
70.82
Protein
% T/C
—
114.5
.
98.9
.
119.3
_
113.0
_
93.8
ATP
fg/106 cells
9.17x10?
8. 88x1 0*
1.95x1o]2
2.02xlOlu
1.05x1o}°
1.53xlOlu
1.03xlo]°
1.02xlOlu
7.74xlO?n
1.39xlOlu
ATP
% T/C
^
96.8
.
103.8
—
146.3
_
98.9
_
179.3
* Mean values for vehicle control and triplicate test samples.
** Same concentration of vehicle as in corresponding test.
This sample was concentrated 2X in solvent exchange procedure (see Section III)
terms of original sample volumes.
Data are presented In
-------
WI-38 CYTOTOXICITY ASSAY
Sample No. :
FS-26
. Cell Viability:
Description of Sample: Cyclone Quench Mater
Date Received:
Date Tested:
Vehicle:
March 6, 1979
March 27,
1979
Medium (BME)
Passage No.:
Seeding Population:
92%
20
ECc/i Values
2.0xlOVwell Viability: >600 yl/ml
pH Alterations:
Lowest dose for pH
change:
pH:
pH at highest dose:
Sample
Dose
ul/ml
Veh. Cont. 0
1
2
3
4
5
600
200
60
20
6
Total
Cells
4.91x105
4. 03x1 O5
5.13xl05
4.08xl05
5.04X105
4.77xl05
%
Viable
72.6
75.5
81.8
71.5
83.4
86.5
Test Results*
Viability Viability
X T/C Index
^
104.0
112.7
98.5
114.9
119.1
—
0.64
0.88
0.61
0.89
0.87
60 ul/ml
7.5
7.6
Viability Index: >600 ul/ml
Protein:
ATP:
: >600 pi /ml
>600 yl/ml
Toxlclty Classi-
fication: No
detectable
toxlclty
Protein
ua/ml
67.0
67.5
74.2
57.0
55.0
46.5
Protein
% T/C
••
100.6
110.7
85.1
82.0
69.5
ATP
fg/106 Cells
3. 94x1 O9
4.17xl09
3.12xl09
3. 53x1 O9
2. 54x1 O9
3. 23x1 O9
ATP
1T/C
.
105.8
79.3
89.5
64.4
81.9
* Mean values for vehicle control and triplicate test samples.
-------
HI-38 CYTOTOXICITY ASSAY
Sample No.:
Description
of Sampl<
Date Received:
Date Tested:
Vehicle:
FS 1-714-2
B: Ash Sluice Water
March 6, 1979
March 27, 1979
Medium
(BME)
Cell Viability:
Passage No.
Seeding
Population:
92%
20
ECcn Values
2.0xlO!>/well Viability: 320
pH Alterations:
Lowest
change:
pH:
dose for pH
pH at highest dose:
r
NJ
O
Sample
Veh. Cont.
1
2
3
4
5
Dose
ul/ml
0
600
200
60
20
6
Total
Cells
4.54xl05
1.37xl05
l.SlxlO5
3. 59x1 O5
3.61xl05
4. 23x1 O5
%
Viable
87.4
11.6
69.8
80.7
87.8
87.4
Test
Viability
% T/C
.
13.3
79.8
92.3
100.4
100.0
Results*
Viability
Index
_
0.03
0.27
0.60
0.66
0.78
Viability Index: 88
Protein: 66
60 ul/ml
7.5
7.6
Protein
ug/ml
67.0
15.9
25.5
32.6
34.2
39.4
ATP:
35
ul /ml
yl/ml
yl /ml
nl /ml
Toxldty Classi-
fication: Moderate
Protein
% T/C
_
23.7
38.1
48.6
51.1
58.8
ATP
fg/lOG Cells
10.04x109
5.92xl09
5. 40x1 O9
3. 74x1 O9
6. 90x1 O9
6. 42x1 O9
ATP
* T/C
_
59.0
53.8
33.2
68.7
63.9
* Mean values for vehicle control and triplicate test samples.
-------
B. RABBIT ALVEOLAR MACROPHAGE (RAM) ASSAY OF SAMPLES T.E. 2276.
GASIFIER ASH; AND T.E. 2277, CYCLONE DUST
SUMMARY
Samples T.E. 2276 and T.E. 2277 were assayed In triplicate in the
RAM assay at 1,000, 300, 100, 30 and 10 ug/ml. There was no detectable
toxicity manifested in total cell counts, cell viability (trypan blue
exclusion), protein and ATP levels determined at 20 hours. For sample
T.E. 2277, the ATP assay showed an apparent inverse dose-response
relationship which might be attributable to the particulate sample
material.
MATERIALS AND METHODS
Two Specific Pathogen Free (SPF) New Zealand albino rabbits weigh-
ing 1.5 to 2.0 kilograms were purchased from Charles River Breeding
Laboratories and housed in individual cages overnight at Arthur D.
Little, Inc. Alveolar macrophages were collected according to proce-
dures outlined in the IERL-RTP Procedures Manual: Level 1 Environmental
Assessment Biological Tests for Pilot Studies, EPA-600/7-77-043 (April,
1977). A total of 1.7 x 108 viable macrophages were recovered (98.4%
of total cells recovered). Twenty-five on2 Falcon flasks were seeded
with 2.0 x 10 macrophages in 2.0 ml of Medium 199 containing 10%
heat-inactivated fetal calf serum, 100 units/ml Penicillin, 100 ug/ml
Streptomycin, 100 ug/ml Kanamycin, and 1.2 mg/ml NaHCOj (Complete
Medium 199). The samples were ground to fine particles, suspended in
Complete Medium 199 in appropriate concentrations and 2.0 ml aliquots
were added to the flasks. The cultures were then incubated, with
rocking, for 20 hours at 37°C in a humidified 5% CO atmosphere.
F-21
-------
At the end of the incubation period the medium was aspirated and
retained; the cells were trypsinized and added to the aspirated medium.
The following aliquots of cell suspensions were made: 4.0 ml for pro-
tein assay, 1.0 ml for ATP assay, and 0.5 ml for viability and total
cell count.
The protein, ATP and viable and total cell counts were done in the
same manner as described for the MI-38 assays.
RESULTS
Results are presented in the following tables.
Senior Technician Evaluating Material £**<+&«** M' /bat
Mrolyn M. Cresifell, M.
Case Leader, Senior Staff
Section Leader, Bio/Medical
Sciences Section
Andrew Sivak, Ph.D
F-22
-------
RABBIT ALVEOLAR MACROPHAGE CYTOTOXICITY ASSAY
Sample No.:
Description
T.E. 2276
of Sample: Gasifier
Date Received:
Date Tested
Vehicle:
March 6,
Ash
1979
: April 19, 1979
Medium 199
pH Alterations:
Lowest dose for pH
change:
pH:
pH at highest dose:
No. Rabbits
Used: 2
ECm Values
Cell Viability: 98.4%
Differential Count:
Macrophaqes: 100%
Other:
0%
Viability: >1,000 pg/ml
Viability Index: >1,000 yg/ml
Protein: >1,000 uq/ml
Seeding Population: 1x1 0<> cells/flask ATP:
>1,000 yg/ml
Toxlclty Classi- No detectable
1 ,000 uq/ml
7.6
7.6
f1 cation: toxlclty
Test Results*
Sample
Veh. Cont.
1
2
3
4
5
Dose
ug/inl
0
1,000
300
100
30
10
Total
Cells
3.09x106
2.80xl06
2.16x106
2. 53x1 06
2. 79x1 06
2. 44x1 O6
Viability
%
99.5
90.8
97.5
97.1
98.5
98.3
Viability
% T/C
.
91.3
98.0
97.6
99.0
98.8
Viability
Index
.
0.82
0.68
0.80
0.89
0.78
Protein
tig/ml
264.84
243.04
248.54
232.35
249.93
259.24
Protein
% T/C
—
91.8
93.8
87.7
94.4
97.9
ATP
fg/106 cells
1.19x109
8. 56x1 O8
1.37X109
9. 93x1 08
8. 08x1 O8
l.lOxlO9
ATP
% T/C
_
71.6
114.9
83.2
67.7
92.2
Mean values for vehicle control and triplicate test samples.
-------
RABBIT ALVEOLAR MACROPHAGE CYTOTOXICITY ASSAY
Sample No. :
Description of Sample:
Date Received:
Date Tested:
Vehicle:
pH Alterations:
Lowest dose for pH
change:
PH:
pH at highest dose:
T.E. 2277
: Cyclone Particulate
March 6, 1979
April 19, 1979
Medium 199
1,000 pi /ml
7.2
7.2
No. Rabbits Used: 2
Cell Viabili
Differential
Macrophages
Other:
Seeding Popu
ty: 98.4%
Count:
: 100%
0%
lation: 1x1 0&
cells/flask
ECro Values
ou
Viability:
Viability Index:
Protein:
ATP:
Toxicity Classi-
fication:
>1,000 ugyml
>1 ,000 jis/ml
>1 ,000 ug/ml
>1,000 ug/ml
No detectable
toxicity
Test Results*
Sample
Veh. Cont.
1
2
3
4
5
Dose
up/ml
0
1,000
300
100
30
10
Total Viability
Cells %
2.84xl06 99.6
2. 73x1 O6 95.0
3. 23x1 O6 98.8
2.87xl06 97.9
3.38xl06 98.3
3.21xl06 99.0
Viability
% T/C
95.4
99.2
98.3
98.7
99.4
Viability
Index
0.92
1.13
0.99
1.17
1.12
Protein Protein ATP
ug/ml % T/C fg/106 cells
264.84
296.79
282.37
285.70
276.27
253.53
9.14xl08
112.1 8.36xl08
106.6 6.39xl08
107.9 5. 90x1 O8
104.3 4.60xl08
95.7 5.18xl08
ATP
% T/C
91.5
69.9
64.6
50.4
56.6
* Mean values for vehicle control and triplicate test samples.
-------
VI. ACUTE IN VIVO TOXICOLOGICAL TEST OF SAMPLES
I.E. 2276, I.E. 2277. FS-1-714-2. FS-26 AND 358-714
IN RODENTS - QUANTAL RESPONSE
SUMMARY
Samples No. I.E. 2276, I.E. 2277. FS-1-714-2, FS-26 and
358-714 were administered as a single dose by the oral route to evalu-
ate their acute toxicity in fasted rats. All animals which received
the dry test substances, I.E. 2276 and I.E. 2277 passed black, well-
formed feces on Day 2, apparently the unchanged test substance. None
of the numerous other signs of toxicity or pharmacological effects
monitored showed meaningful deviations from control values. No mor-
tality was recorded and resulting data suggest that the single-dose
oral LD5Q value for each of the test materials 1s greater than
10.0 gm/kg or 10.0 ml/kg. All animals autopsied after the two-week
observation period appeared normal and no gross lesions were detected.
MATERIALS AND METHODS
The materials received from Mildred G. Browne, Project
Director, Arthur D. Little, Inc., that were tested are listed below.
Sample No. Description As Received
T.E. 2276 Gas1f1er Ash
T.E. 2277 Cyclone Dust
FS-1-714-2 Sluice Water
FS-26 Cyclone Quench Water
358-714 SASS Product Gas Composite
F-25
-------
We understand that all of the solids (particulate) to be
tested in this quanta! response system are coal derived. The liquid
samples were administered as received resulting in 2.0-2.6 ml being
orally intubated/200 gm/rat. The dry materials were suspended in 0.9%
physiological saline (concentration: 2 gm solid/1 ml of saline). The
control animals were orally intubated with 0.9% physiological saline or
50% DMSO at the maximum volume employed with the test substances (^5.0 ml).
A group of young, adult albino Sprague-Dawley (CD) rats
weighing approximately 250 gms were purchased from the Charles River
Breeding Laboratories, Wilmington, Massachusetts, and conditioned in the
Arthur D. Little, Inc., laboratories for a minimum of 5 days. From this
group, five males and five females of comparable body weights per sex
were selected for testing each compound and fasted overnight.
Prior to administering a single dose of 10 ml/kg or 10 gm/kg
each animal was weighed and given a complete physical examination, as
described in the IERL-RTP Procedures Manual, Level 1, EPA 600/6-77-043,
April, 1977. This examination procedure also was followed Immediately
after administration of the test substance, and at 1, 4 and 24 hours
during the first day and daily during the 14-day observation period.
Observations, 1n addition to mortality, were recorded and all
toxic signs or pharmacological effects monitored Including changes in
behavior and movements, reactivity to various stimuli, cerebral and spinal
reflexes, muscle tone, pupil size, secretions, nostril discharge, charac-
ter and rate of breathing, palpation of cardiac region, GI events,
abdominal shape, feces consistency and color, vulva,mammary glands, penis
and perineal region, skin and fur changes, conjunctiva, mouth, eyeball,
rectal temperature and general condition, were measured. Their frequency
and severity were scored on a scale of 0 through 3 (0-normal, 1-slight,
2-moderate, 3-marked change from normal). All animals were killed on
Day 15, a complete necropsy was conducted, and the weights of the liver
F-26
-------
and kidneys were recorded. No tissues were taken for histopathological
examinations per the EPA protocol.
RESULTS
Only two of the signs of toxiclty or pharmacological effects
monitored showed deviations from control values:
1. All rats which received the dry test substances; I.E. 2276 and
I.E. 2277 passed black, well formed feces on Day 2, apparently
largely derived from the test substances.
2. It should be noted that although the mean respiratory rates,
mean cardiac rates and mean body temperatures showed varia-
tions, these values for the parameters monitored are within
ranges expected for untreated rats, and therefore it is
doubtful if these transitory changes are indicative of meaning-
ful toxic effects.
Mean body weight gains and the weights of the liver and
kidneys (Table IV), as well as the other parameters monitored, did not
appear to be significantly affected by dosage of the test materials.
No mortality was recorded following oral intubation with any
of the materials being evaluated under these test conditions which
suggests, as shown in Tables V-IX, that the single-dose LDgg value for
each of the test materials administered by the oral route is greater
than 10.0 gm/kg.
F-27
-------
All animals autopsied after the two-week observation period
appeared normal and no gross lesions were detected.
Subcase Leader,
Toxicology Unit
Case Leader
Peter C^Rachwall
/•fcfbome, Ph.D.
Section Manager
Bio/Medical Sciences Section
F-28
-------
TABLE 1
MEAN RESPIRATORY RATE/MINUTE
Material
Tested
Control
(saline)
.T.E. 2276
fi, T.E. 2277
UD
FS-1-714-2
FS-26
Control
(DMSO)
358-714
I
S.D.
I
S.D.
I
S.D.
I
S.D.
I
S.D.
X
S.D.
I
S.D.
0
165.6
47.5
139.0
33.4
138.4
34.5
136.4
21.0
143.6
37.6
153.2
39.9
163.2
44.6
Da>
1/2 hr
121.2
40.2
136.8
23.8
136.0
32.5
146.8
26.4
142.8
30.5
128.0
38.2
144.0
36.2
1
1 hr
164.8
57.1
114.0
31.0
133.6
32.2
154.4
31.6
147.2
28.7
114.8
29.5
118.8
28.1
DAY
4 hr
182.4
29.4
141.2
16.3
126.4
19.7
142.4
26.5
145.2
18.0
120.4
24.8
116.4
37.8
2
208.4
54.0
193.4
32.3
150.8
37.3
141.6
23.0
170.6
41.9
161.2
30.5
150.8
34.2
3
214.4
54.5
180.8
34.8
168.4
38.3
141.2
16.6
141.2
31.0
160.2
37.2
167.2
27.8
4
194.8
25.5
166.0
38.2
186.0
53.1
149.6
32.6
135.2
31.5
147.6
20.0
155.8
33.9
5
201.6
42.8
180.8
45.9
145.2
30.6
150.C
23.6
178.8
31.3
168.8
27.0
164.0
25.1
6
166.4
32.7
166.0
29.4
152.4
25.9
175.6
25.7
164.4
21.7
192.8
26.6
164.8
26.0
7
173.4
34.1
193.6
42.9
139.0
27.8
152.8
28.0
168.4
10.1
179.6
34.9
184.4
32.0
8
180.8
32.5
182.4
20.5
153.6
30.8
154.0
36.0
174.8
20.0
174.0
20.6
188.4
44.8
9
189.2
52.0
158.4
21.8
152.4
39.2
150.4
15.6
177.6
16.4
196.8
28.0
174.0
27.2
10
194.0
41.2
171.6
15.4
169.2
19.9
176.8
30.4
182.0
29.8
169.6
27.7
187.2
31.6
11
178.4
19.0
173.2
25.3
180.4
23.4
169.6
32.4
168.8
24.9
188.8
18.8
168.4
21.2
12
180.4
26.5
166.8
35.0
176.2
27.6
167.2
25.6
158. 0
21.1
177.6
33.0
174.4
31.6
13
171.6
39.2
171.2
31.8
182.0
27.6
168.0
35.4
178.4
29.6
184.0
35.4
169.6
33.4
14
176.8
21.5
174.8
42.3
188.4
25.5
151.6
35.4
169.2
14.7
173.6
25.9
163.6
24.2
IS
203.2
35.7
184.0
17.9
191.2
29.9
185.6
28.0
157.6
22.6
173.2
23.0
176.4
20.7
-------
TABLE II
MEAN CARDIAC RATE/HIMUTE
Material
Tested
Control
(saline)
T.E. 2276
7 T.E. 2277
o
FS-1-714-2
FS-26
Control
(DMSO)
353-714
I
S.O.
J
S.D.
I
S.D.
I
S.O.
I
S.D.
I
S.D.
I
S.D.
0
330.0
42.8
300.0
17.7
326.8
43.5
282.0
25.0
262.4
34.1
292.8
21.7
302.0
30.4
Cay 1
1/2 hr
281.6
52.7
312.4
39.4
313.6
36.9
319.6
28.9
308.4
21.2
281.2
51.7
303.2
27.3
1 hr
289.2
59.5
302.8
37.1
304.4
20.0
289.6
30.6
269.2
53.6
292.8
42.0
285.2
46.8
4 hr
346.8
26.7
306.8
36.4
309.2
20.8
305.2
27.7
288.0
20.7
302.8
42.6
291.6
39.8
2
315.6
48.2
315.2
33.6
311.6
20.7
294.4
29.6
298.8
27.0
288.0
48.3
304.0
28.0
3
298.0
41.3
318.4
41.8
282.0
26.4
293.8
36.7
287.6
45.5
308.0
29.7
292.4
13.0
4
305.6
21.7
295.2
20.7
310.8
47.4
292.8
28.6
288.8
47.4
296.4
15.5
296.8
25.0
5
319.2
18.9
291.6
49.2
311.6
23.9
316.8
23.8
291.2
44.6
302.4
17.5
282.2
22.1
6
298.0
19.2
289.6
42.9.
294.0
10.4
303.2
26.7
289.6
26.2
314.4
21.4
298.0
32.4
7
302.8
37.2
297.0
20.2
299.2
26.6
319.6
12.0
297.6
34.2
328.4
37.8
314.8
26.9
DA
8
310.0
33.8
286.8
26.5
311.6
23.0
294.8
30.9
303.6
17.1
297.2
19.9
286.4
17.7
Y
9
322.0
34.8
292.4
31.9
314.4
18.5
289.2
19.0
285.6
26.6
300.4
27.4
312.0
28.0
10
343.6
23.3
310.0
13.2
292.4
27.5
301.2
25.7
305.6
22.3
310.0
18.1
307.2
36.8
11
307.2
17.5
281.6
21.8
289.0
10.2
304.8
13.8
292.8
30.1
304.8
21.8
280.1
48.6
12
298.4
50.8
309.2
18.4
297.6
15.3
304.0
24.9
290.4
25.5
296.0
31.2
305.6
40.5
13
335.2
18.7
309.2
27.5
319.2
16.8
284.8
18.2
294.4
15.3
303.6
16.3
298.4
27.8
14
321.2
25.2
326.0
13.2
298.0
19.6
298.8
22.5
260.4
15.4
311.2
27.8
282.4
34.0
15
316.4
28.0
301.2
29.8
298.0
33.7
293.6
23.4
290.4
11.8
289.2
20.8
295.2
17.9
-------
TABLE III
to
Material
Tested
Control I
(saline) S.D.
T.E. 2276 T
S.D.
T.E. 2277 I
S.O.
FS-1-714-2 I
S.O.
FS-26 If
S.D.
Control If
(DMSO) S.D.
358-714 I
S.D.
Day
0
35.1
O.S8
35.0
0.92
35.1
0.97
36.3
1.28
35.9
1.33
35.8
1.02
35.9
1.35
1/2 hr
35.6
0.79
35. S
1.34
35.7
0.76
36.6
1.02
36.5
0.69
35.0
1.26
36.5
0.59
1 hr
36.0
0.57
35.5
0.91
35.7
0.74
36.5
0.92
36.8
0.93
35.0
1.08
36.2
0.65
4 hr
35.3
0.81
35.2
1.11
35.0
O.B4
37.0
0.42
36.5
0.87
34.4
1.66
36.4
0.71
34.9
0.74
35. S
1.16
35.9
0.83
36.1
0.54
36.2
0.73
36.3
0.64
35.7
0.90
3
36.0
0.94
36.5
0.8S
35.8
1.52
35.8
1.00
35.4
0.79
35.7
0.74
35.7
0.50
MEAN BODY TEMPERATURE
(Rectal C°)
35.5
1.40
35.6
1.64
35.9
0.84
35.6
0.53
35.5
0.59
36.0
0.69
35.8
0.66
36.7
0.56
36.4
0.57
36.4
0.74
35.7
0.79
35.4
0.77
36.1
0.63
35.6
0.73
6
35.4
0.96
35.1
1.35
35.3
1.07
36.0
1.04
36.2
0.59
36.1
0.74
36.2
0.46
7
35.8
1.04
36.2
0.73
35.9
0.85
35.8
1.17
36.0
0.74
36.3
0.63
35.9
1.27
DAY
8
35.4
0.78
35.9
1.28
36.2
1.09
36.2
0.58
35.8
0.62
36.1
0.80
36.2
0.73
9
36.2
0.27
34.8
1.61
35.4
1.62
36.3
0.61
36.1
0.63
35.8
0.97
36.0
0.73
10
36.2
0.64
36.7
1.20
36.5
0.89
36.3
0.94
36.2
1.14
36.5
0.76
36.1
0.73
11
36.0
0.98
35.8
1.01
36.0
1.19
36.6
0.62
36.1
1.01
35.8
0.57
36.4
0.94
12
36.0
0.96
36.6
1.21
35.7
1.42
35.9
1.05
36.2
0.97
36.4
0.31
36.3
0.84
13
36.0
0.35
36.7
0.97
36.6
1.15
36.6
0.80
36.3
0.37
36.6
0.53
36.6
0.67
14
36.5
0.85
36.4
1.30
35.8
1.52
36.7
0.36
36.6
0.31
36.6
0.34
36.5
0.38
15
36.2
1.27
35.8
1.21
35.7
1.31
36.2
0.98
36.4
0.54
36.5
0.68
36.5
0.39
-------
TABLE IV
Material
Tested
Control X
(saline) S.D.
Wt. Gain %
T.E. 2276 I
S.D.
Wt. Gain %
T.E. 2277 X
S.D.
Wt. Gain %
FS-1-714-2 x"
S.D.
Wt. Gain %
FS-26 X"
S.D.
Wt. Gain %
Control X
(DMSO) S.D.
Wt. Gain %
358-714 I
S.D.
Wt. Gain %
:AN BODY WEIGHT
AND LIVER
AND KIDNEY
WEIGHT DATA
Organ Weights
Body
Day 1
291.0
46.5
290.0
44.6
291.0
54.7
216.5
11.1
215.5
12.8
229.0
19.8
221.5
10.0
Weightl
Day 8
324.5
61.7
11.5
328.0
56.5
13.1
328.0
75.4
12.7
265.5
12.6
22.6
260.5
18.3
20.9
273.0
12.5
19.2
266.0
9.7
gms)
Day 15
342.0
74.5
17.5
350.0
71.1
20.7
350.0
85.3
20.3
287.5
21.1
32.8
281.0
27.3
30.4
304.5
22.5
33.0
290.5
21.7
Liver
(gms)
15.63
4.04
16.08
3.92
15.46
4.50
13.53
1.87
12.76
3.23
15.70
2.53
15.04
1.97
(% of
W
4.56
0.48
4.58
0.50
4.38
0.41
4.69
0.38
4.51
0.88
5.13
0.51
5.17
0.42
Body Weight)
Kidneys
(gms}
3.20
0.84
3.27
0.73
3.08
0.88
2.72
0.37
2.61
0.48
2.89
0.46
2.77
0.38
(%)
0.93
0.10
0.93
0.07
0.87
0.08
0.94
0.08
0.92
0.09
0.94
0.10
0.95
0.08
20.1 31.2
F-32
-------
TABLE V
SUMMARY OF SINGLE-DOSE ORAL TOXICITY OF I.E. 2276 IN RATS
Species:
Strain:
Body Weight Range (gm):
Day 1
Day 8
Day 15
Rat
Sprague-Dawley (CD)
240 - 355
255 - 405
255 - 440
Formulation: Suspended in normal saline with agitation at
room temperature.
Concentration (gm/ml): Suspension of 0.6 gm/ml.
Approximate Volume Administered (ml): 3 7 - 10.4/200-gram rat
Dosage (gm/kg), Mortality, and Percent Mean Body Height Gain
of Survivors Post-Treatment
Dosage
(gm/kg)
Control
10.0
Mortality
Day 8
0/10
0/10
Day IS
0/10
0/10
Mean Body Weight Gain
Day 8
11.5
13.1
Day 15
17.5
20.7
LD5Q (Day 15)
>10 gm/kg
F-33
Ar
-------
TABLE VI
SUMMARY OF SINGLE-DOSE ORAL TOXICITY OF I.E. 2277 IN RATS
Species: Rat
Strain: Sprague-Dawley (CD)
Body Weight Range (gm):
Day 1 235 - 360
Day 8 240- 410
Day 15 255 - 450
Formulation: Suspended In normal saline with agitation
at room temperature.
Concentration (gm/ml): Suspension of 0.6 gm/ml.
Approximate Volume Administered (ml): 3.7 - 10.4/200-gram rat
Dosage (gm/kg). Mortality, and Percent Mean Body Weight Gain
of Survivors Post-Treatment
Dosage Mortality % Mean Body Weight Gain
(gm/kg)
Control
10.0
Day 8
0/10
0/10
Day 15
0/10
0/10
Day 8
11.5
12.7
Day 16
17.5
20.3
LD50 (Day 15)
> 10 mg/kg
F-34
-------
TABLE VII
SUMMARY OF SINGLE-DOSE ORAL TOXICITY OF FS-1-714-2 IN RATS
Species: Rat
Strain: Sprague-Dawley (CD)
Body Weight Range (gm):
Day 1 205 - 355
Day 8 250 - 395
Day 15 255 - 425
Formulation: As received
Concentration (gm/ml): 100%
Approximate Volume Administered (ml): 2.1 - 3.6/200-gram rat
Dosage (ml/kg), Mortality, and Percent Mean Body Weight Gain
of Survivors Post-Treatment
Dosage Mortality % Mean Body Weight Gain
(ml /kg
Control
10.0
Day 8
0/10
0/10
Day 15
0/10
0/10
Day 8
11.5
22.6
Day 15
17.5
32.8
LD5Q (Day 15)
> 10 ml/kg
F-35
-------
TABLE VIII
SUMMARY OF SINGLE-DOSE ORAL TOXICITY OF FS-26 IN RATS
Species: Rat
Strain: Sprague-Dawley (CD)
Body Weight Range (gm):
Day 1 200 - 355
Day 8 225 - 395
Day 15 230 - 425
Formulation: As recieved
Concentration (gm/ml): 100%
Approximate Volume Administered (ml): 2.0 - 3.6/200-gram rat
Dosage (ml/kg), Mortality, and Percent Mean Body Weight Gain
of Survivors Post-Treatment
Dosage Mortality % Mean Body Weight Gain
(ml/kg)
Control
10.0
Day 8
0/10
0/10
Day 15
0/10
0/10
Day 8
11.5
20.9
Day 15
17.5
30.4
LD50 (Day 15)
> 10 ml/kg
F-36
-------
TABLE IX
SUMMARY OF SINGLE-DOSE ORAL TOXICITY OF 358-714 IN RATS
Species: Rat
Strain: Sprague-Dawley (CD)
Body Weight Range (gin):
Day 1 205 - 275
Day 8 245 - 295
Day 15 250 - 340
Formulation: Received in methylene chloride solvent
exchanged into DMSO
Concentration: Diluted with distilled H20, 2:1
Approximate Volume Administered (ml): 2.1 - 2.8/200-gram rat
Dosage (ml/kg), Mortality, and Percent Mean Body Weight Gain
of Survivors Post-Treatment
Dosage Mortality % Mean Body Weight Gain
(ml/kg)
Control DMSO
10.0
Day 8
0/10
0/10
Day 15
0/10
0/10
Day 8
19.2
20.1
Day 15
33.0
31.2
LD5Q (Day 15)
> 10 ml/kg
F-37
-------
TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing!
1. REPORT NO.
EPA-600/7-80-097
2.
3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
Environmental Assessment: Source Test and
Evaluation Report--We 11man-Galusha (Ft. Snelling)
Low-Btu Gasification
5. REPORT DATE
May 1980
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
M. P.Kilpatrick, R.A.Magee, T.E.Emmel, and
G.C.Page
8. PERFORMING ORGANIZATION REPORT NO.
80-218-143-116
». PERFORMING ORGANIZATION NAME AND ADDRESS
Radian Corporation
P.O. Box 9948
Austin, Texas 78766
10. PROGRAM ELEMENT NO.
INE825
11. CONTRACT/GRANT NO.
68-02-2147, Exhibit A
12. SPONSORING AGENCY NAME AND ADDRESS
EPA, Office of Research and Development
Industrial Environmental Research Laboratory
Research Triangle Park, NC 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final: 9/78-12/79
14. SPONSORING AGENCY CODE
EPA/600/13
is. SUPPLEMENTARY NOTES
919/541-2851.
project officer is William J. Rhodes, Mail Drop 61,
ie. ABSTRACT Tne repor|. gjves results of a. source test and evaluation of a Wellman-
Galusha gasifier at the U.S. Bureau of Mines' Twin Cities Metallurgy Research
Center at Ft. Snelling. The gasifier is operated as part of the Bureau's investiga-
tion of the use of low-Btu gas as a fuel for iron ore pelletizing. Program objectives
were to provide survey data from which a preliminary assessment of potential envi-
ronmental impact could be made, and to identify potential problems which would
require further characterization or pollution control technology implementation.
Difficulties with the test burner operation resulted in the product gas being vented
to the startup flare, bypassing the cyclone during a majority of the lignite test
(North Dakota, Indian Head), December 9-15, 1978. Therefore, data for the test
burner is somewhat limited and the product gas characterization does not reflect
the particulate removal capability of the process cyclone. Within these constraints,
the test objectives were met. The Source Analysis Model/IA was used to provide
rapid screening for identifying and prioritizing potentially harmful waste streams.
Identified as major contributors to the overall health discharge severity were benzo-
pyrene and CO in the product gas; and As and Cr in the test burner flue gas. Several
gasifier-related water components exceeded Federal drinking water standards.
7.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS
c. COSATI Field/Group
Pollution
Assessments
Coal Gasification
Iron Ores
Pelleting
Lignite
Dust
Toxicity
Pollution Control
Stationary Sources
Environmental Assess-
ment
Wellman-Galusha Pro-
cess
Particulate
13B
14B
13H
08G
07A
2 ID
11G
06T
3. DISTRIBUTION STATEMENT
Release to Public
19. SECURITY CLASS (ThisReport)
Unclassified
21. NO. OF PAGES
606
20. SECURITY CLASS (This page J
Unclassified
22. PRICE
EPA Form 2220-1 (9-73)
F-38
------- |