c/EPA
         " •T.'il S'/I'PS
         Environmental Protection
         Agency
          Laboratory
          Research T
EPA 600/7-79-166
July 1979
Development of
Droplet Sizing
for the Evaluation
of Scrubbing  Systems

Interagency
Energy/Environment
R&D Program Report

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                  RESEARCH REPORTING SERIES


Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology. Elimination of traditional  grouping  was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:

    1. Environmental Health Effects Research

    2. Environmental Protection Technology

    3. Ecological Research

    4. Environmental Monitoring

    5. Socioeconomic Environmental Studies

    6. Scientific and Technical Assessment Reports  (STAR)

    7. Interagency Energy-Environment Research and Development

    8. "Special" Reports

    9. Miscellaneous Reports

This report has been assigned to the INTERAGENCY ENERGY-ENVIRONMENT
RESEARCH AND DEVELOPMENT series. Reports in this series result from the
effort funded  under the  17-agency  Federal Energy/Environment Research and
Development Program. These studies relate to EPA's mission to protect the public
health and welfare from  adverse effects of pollutants associated with energy sys-
tems. The goal of the Program is to assure the rapid development of domestic
energy supplies in an environmentally-compatible manner by providing the nec-
essary environmental data and control technology. Investigations include analy-
ses of the  transport of energy-related pollutants and their health and ecological
effects; assessments  of,  and development of, control technologies for energy
systems; and integrated assessments of a wide-range of energy-related environ-
mental  issues.
                       EPA REVIEW NOTICE
This report has been reviewed by the participating Federal Agencies, and approved
for  publication. Approval does not signify that the contents  necessarily reflect
the  views and policies of the Government, nor does mention of trade names or
commercial products constitute endorsement or recommendation for use.

This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.

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                               EPA-600/7-79-166

                                         July 1979
Development of Droplet
Sizing for the Evaluation
  of Scrubbing Systems
                  by

      Hector Medecki, K.C. Wu, and D.E. Magnus

            KLD Associates, Inc.
              300 Broadway
        Huntington Station, New York 11746
           Contract No. 68-02-2111
          Program Element No. EHE624
        EPA Project Officer: D. Bruce Harris

     Industrial Environmental Research Laboratory
       Office of Energy, Minerals, and Industry
        Research Triangle Park, NC 27711
               Prepared for

     U.S. ENVIRONMENTAL PROTECTION AGENCY
        Office of Research and Development
            Washington, DC 20460

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                         DISCLAIMER
     This report has been reviewed by the Office of Research
and Development, U.S. Environmental Protection Agency, and
approved for publication.  Approval does not signify that the
contents necessarily reflect the views and policies of the
U.S. Environmental Protection Agency, nor does mention of
trade names or commercial products constitute endorsement or
recommendation for use.

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                         ABSTRACT
    The measurement of entrained droplets and their concen-
trations in gas streams is an important requirement in
pollution control technology.  The use of a hot-wire
sensor can successfully measure the desired parameters for
droplets in the size range from 1 pm to 600 ym.

    The development and characteristics of the DC-2
Droplet Counter is reported herein.  Extensive testing in
the laboratory are described and the comparison with results
from the Brink impactor is presented.  A correlation of
results for these two measurement techniques is achieved.
Field tests at four different sites are also described.
                            111

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                          CONTENTS


Abstract                                                   iii

Figures                                                      v

Tables                                                     vii

Acknowledgments                                            viii

    1.  GENERAL BACKGROUND                                  1
          Principle of Operation                            2
          Program Plan for Improved Performance             6
    2.  CONCLUSIONS AND RECOMMENDATIONS                     9
    3.  DEVELOPMENT OF THE PROBE                           10
          General Background                               12
    4.  THE DC-2                                           23
          General Description                              23
        •  Implementation of Temperature Measurement        26
          Implementation of Velocity Measurement           26
          Droplet Counting                                 31
          Physical Characteristics and Use of the DC-2     31
          Data Analysis                                    35
    5.  PRINTER/CONTROLLER                                 41
          General Description                              41
          Functions of Front Panel Switches                41
          Interfacing with Two DC-2's                      46
          Probe Multiplexer System                         46
    6.  LABORATORY INVESTIGATIONS                          49
          Calibration Tests                                49
          Laboratory Tests with the Impactor               54
    7.  FIELD TESTING                                      76
          Colbert Pilot Plant                              76
          Water Treatment Plant in New York                78
          Shippingport Power Plane                         78
          Cooling Tower of the High Flux Beam Reactor
     ,       at Brookhaven National Laboratory              84

References                                                 91
Appendix

    A.  Tabulation of Laboratory Tests                     92

                             iv

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                           FIGURES
No,
 1      Principle of Operation of the Sensor             3
 2      Electrical Signal from Sensor                    4
 3      Mechanical Model of Sensor                      13
 4      Aspirating Probe                                16
 5      Protected Probe                                 18
 6      Disposable Sensor Probe                         22
 7      Temperature Conversion Block Diagram            27
 8      Sensor Temperature Characteristics              28
 9      DC-2 Velocity Measurement Network               30
10      View of the DC-2 Front Panel                    33
11      Printout Illustration                           42
12      Printer Panel Layout                            43
13      Schematic of the DC-2 Interface with
          Printer/Controller                            47
14      Schematic of DC-2 Interface with Multiplexer
          System                                        48
15      Droplet Calibration Apparatus                   51
16      Capture Size vs. Dj_/d                           55
17      Laboratory Setup                                56
18      Average Number Concentration for Impactor
          and the DC-2 Data (Test No. 216)               62
19      Average Number Concentration for Impactor
          and the DC-2  (Test No.  212)                   63
20      Cumulative Entrainment Volume for Impactor
          and the DC-2 Data (Test No. 212)               64
21      Cumulative Entrainment Volume for Impactor
          and the DC-2 Data (Test No. 216)               65
22      Salt Collected on Stage 1                       66
23      Salt Collected on Stage 3                       67
24      Pressure Drop along the Impactor                71
25      Temperature Drop along the Impactor             72
26      Schematic of the Demister Scrubber at the
          Colbert Facility                              77
27      Distribution at the Prescrubber Demister
          Inlet at the Colbert Facility                 79
28      Distribution at the Prescrubber Demister
          Outlet at the Colbert Facility                80
                              v

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                     FIGURES (Continued)
No.
29      Distribution at the Exit Demister Inlet at
          the Colbert Facility                          81
30      Distribution at the Demister Outlet at the
          Colbert Facility                              82
31      Demister Cross Section at the Treatment
          Plant in Wantagh, New York                    83
32      Test Section of a Duct at Shippingport, Pa.      85
33      Average Number Concentration for the Demister
          Sections at Shippingport,  Pa.                  86
34      Average Cumulative Entrainment Volume as a
          Function of Diameter for the Demister
          Sections at Shippingport,  Pa.                  87
35      Average Cumulative Entrainment Volume as a
          Function of Droplet Size in the Exhaust
          of the Cooling Tower at Brookhaven National
          Laboratory                                    89
36      Droplet Number Concentration Measured in the
          Exhaust of the Cooling Tower at Brookhaven
          National Laboratory                           90
                             VI

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                           TABLES
No.

 1
 2
 3
 4
 5
 6
 7

 8

 9
Internal Sizing Distribution for Module 1       37
Internal Sizing Distribution for Module 2       38
Internal Sizing Distribution for Module 3       39
Internal Sizing Distribution for Module 4       40
050 for Brink Impactor                          59
Cascade Impactor Stage Parameters               70
Rate of Change in Radius for Water Droplets
at 293°K and P^-PQ = 0.1 mmHg                   73
Supersaturation Ratio, Pr/P^,, for Water
Droplet at 293°K                                74
Rate of Change in Radius for Water Droplet
at 293°K                                        74
                             VII

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                      ACKNOWLEDGMENTS
    The work reported herein was performed by KLD Associates,
Inc. under Contract No. 68-02-2111 from the Environmental
Protection Agency, Research Triangle Park, North Carolina.
Mr. Bruce Harris was the Project Officer for the EPA and
his support and suggestions are acknowledged.

    The field testing of the instrumentation was performed
at three sites—the Colbert Pilot Plant in Muscle Shoals,
Alabama; the Shippingport Power Plant in Shippingport,
Pennsylvania;  and Brookhaven National Laboratory in
Upton, New York.  Mr. Robert Statnick of EPA made the
necessary arrangements at the Colbert Facility,
Mr. Dennis Martin of York Research was responsible for the
arrangements at Shippingport, and Messrs. Seymour Protter,
Michael Brooks and Daniel Oldham assisted us at Brookhaven.
Their support is gratefully acknowledged.  The cooperation
of all individuals at the plants was outstanding and con-
tributed greatly to the success of the field testing.
                            Vlll

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                          SECTION 1

                     GENERAL BACKGROUND
     The measurement of size and concentration of liquid droplets
in the gas stream of scrubbers and mist eliminators is a require-
ment in pollution control technology.  The capability of making
such measurements will lead to improved performance of such
devices and to a better understanding of the processes involved.
Several methods of measuring droplets in such devices can be
suggested, but one measuring device, which uses the heat trans-
fer principle, appears most advantageous because of its
simplicity and capability for in-situ measurements without sample
extraction.

     The technique uses a hot wire exposed to the flow with en-
trained liquid droplets.  As a droplet attaches to the wire, an
electrical signal is generated.  The analysis of this signal
provides information on droplet size.  By electronically
processing the signal, the droplets can be sorted into diameter
ranges and the droplet distribution function determined.
Another parameter required for the computation of droplet concen-
tration is the gas stream velocity which is obtained from the
same sensor operating as a hot wire anenometer.

     In 1974, KLD Associates, Inc. developed and successfully
demonstrated an instrument using this hot wire principle.  The
device, which is designed as the DC-1 Droplet Counter, sorts the
droplets into six size ranges.  The laboratory and field studies
provided extensive insight into the droplet distribution in de-
misters.  Originally, the measurement range for such devices was
thought to be 20 um to 500 ym.  However, the field studies with
the DC-1 clearly showed the importance of measurements in the
range from 1 ym to 100 ym.  In addition, the field studies
indicated several areas for improving the operation of the in-
strument; these improvements are summarized below:

     •  Allocation of more than six droplet diameter ranges
        for a better description of droplet size distribution.

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     •  Reduction or elimination of adjustments to be per-
        formed by the operator.

     •  Elimination of calibration curves, providing the
        result of the measurements in digital form and
        engineering units (metric system).

     •  Improvement of the probe ruggedness, since this is
        the only element with limited life, subject to
        breakage and contamination.

     In the present report,  the work performed in the improve-
ment of the DC-1 is presented.  The result of this effort is
a second-generation instrument designated the DC-2 Droplet
Counter.

PRINCIPLE OF OPERATION

     The operation of the heat transfer droplet sensor is based
on the cooling caused by a droplet attaching to a hot wire.
The concept is schematically shown in Figure 1, where the hot
wire sensor and its longitudinal temperature distribution are
shown before (a) and after (b) a water droplet (cross-hatched
circle) attaches.  The electrical resistance of the wire is a
function of the wire temperature which in  (a) is high and sub-
stantially uniform along the wire.  In situation  (b)  the por-
tion of the wire covered by the droplet is cooled to approxi-
mately the droplet temperature.  A constant electrical current,
which flows along the wire to heat it, shows a measurable
voltage drop at the wire support when a droplet is attached to
the wire.  The voltage encountered before droplet attachment
(a) is reduced for condition  (b) in direct proportion to the
cooled length of wire; i.e.,  the droplet diameter.  The elec-
trical energy delivered to the wire evaporates the water,
leaving the sensor dry and ready for further interaction.

     The above description of the principle of operation of the
instrument is an idealization, and in actual practice, the
electrical signal is rather complex.  A typical electrical
signal obtained during a droplet-hot wire interaction is shown
in Figure 2.  Reduction of the voltage implies cooling of the
wire.  An initial fast decay of the signal is observed; it
corresponds to the initial lateral contact of the droplet and
wire with a basically radial cooling of the wire.  The duration
of this portion is of the order of a few microseconds.  The
less steep signal following the initial contact is caused  by
the droplet centering around the wire and by the longitudinal

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                  Support             Support'


                         	Hot Wire
    Hot-|-
Ambient
         Temp.
                                      Wire Longitudinal
                                          Dimension
               (a)  Temperature before Attachment
    Wire  Temp.


    Hot+
Ambient
     Figure  1
                       Wire Longitudinal
                           Dimension

(b)  Temperature after Attachment

 Principle  of  Operation of the Sensor

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Voltage
  Droplet
   Wire
  Contact
   Longitudinal
     Cooling
Droplet Heating
Droplet Evaporation
                                                                     Time
                Figure 2;   Electrical Signal from sensor.

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cooling of the wire beyond the area covered by the droplet.
During this time, a warming of the droplet-wire takes place,
raising the signal until the boiling temperature is reached;
the droplet shrinks due to evaporation and disappears.  The
voltage in the wire then returns to the initial level prior
to interaction of the droplet.

     For the purpose of determining the droplet diameter, only
the signal during the droplet contact is relevant and this
portion is processed in both the DC-1 and DC-2 instruments.
The processing is performed electronically, separating the front
of the signal and frequency filtering it.  After the analysis
of a droplet is started, the processor does not accept a
second droplet until the first droplet is fully evaporated
and the hot wire sensor is restored to the proper operating
temperature.

     The calibration of the instrument (i.e., sensor output
versus droplet diameter) is performed by simultaneously taking
a microscopic picture of the droplet and measuring the corres-
ponding electrical signal from the sensor  (voltage drop).  The
apparatus  for this purpose will be described later.  Many
calibrations may be obtained for different settings of
operating conditions and signal processing; however, an opti-
mum calibration was obtained as a compromise among many con-
flicting requirements, some of which are:

     •  One sensor and one operating .temperature should
        cover the total droplet size range from 1 ym to
        600 urn.

     •  The calibration curve should be monotonic.

     •  Air turbulence signals should not introduce false
        counting.

     •  The calibration curve should be independent of the
        droplet velocity relative to the sensor.

     These requirements were achieved in the implementation of
the DC-2 Droplet Counter, and its use in the field proved this
approach to be sound.

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PROGRAM PLAN FOR IMPROVED PERFORMANCE

     A program to upgrade the characteristics of the droplet
counter was undertaken.  The major areas of work to improve
its performance may be separated into five tasks as discussed
below:

     •  Improve Probe Life and Reliability

        The objective was to improve the design of the
        probe by making it more durable in a field
        environment.  Three probe configurations were
        investigated:  the aspirating probe, the supported
        probe and the replaceable probe.  The following
        improvements were implemented:

        a)  The construction of the probe was modified
           to reduce damage during handling and
           installation.  The configuration was modified
           to reduce the possibility of breakage due to
           large solid particles moving with the flow;

        b)  Techniques of cleaning the sensor while
           operating in slurries and deposit-prone
           contaminants were developed;

        c)  Effect of corrosive environment on the probe
           components was investigated in both laboratory
           and field tests;

        d)  A replaceable probe was designed, built and
           tested in the laboratory.

     •  Improve the Functional Characteristics of the
        Instrument

        The objective was to provide increased capability
        of the droplet counter/measuring device.  This
        objective was accomplished by:

        a)  Increasing the storage capacity of each storage
           bin from 999 to 10,000 counts;

        b)  Increasing the number of bins characterizing
           droplet size to fourteen (14);

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   c) Providing a buffered output for the measured
      data.  Such output may be then interfaced
      with an external recording and display
      device:

   d) Providing a display of flow velocity and
      temperature in engineering units;

   e) Controlling the selection of the droplet
      size range of each bin by changing
      modules on the front panel;

   f) Extending the capacity and control of the
      sample interval timer by providing several
      selectable time limits to a maximum of
      1,000 seconds.

•  Modification of the Physical Characteristics and
   Construction of the Instrument

   The objective was to better adapt the droplet/
   counter/measuring device to field work by making
   it more transportable and convenient to use.
   The device was redesigned as a small package
   with space for cables and probes.  Based upon
   the new design which incorporated all the
   electronic improvements discussed above, two
   (2) units were built for the EPA after receiving
   approval from the EPA Project Officer

•  Develop a Printer/Controller

   The objective of this phase of the effort was
   to provide the measured data in the form of
   printed hard copy.  In addition, the controller
   was to automate the operation of the instrumen-
   tation and be able to simultaneously monitor two
   DC-2's.  The device is also capable of controlling
   up to 12 hot-wire probes in a multiplex mode of
   operations.  The Printer/Controller was used
   extensively in the laboratory and field tests of
   this project.

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0  Laboratory Test and Field Validation

   The objective was to calibrate and validate the
   two droplet counter/measurement devices result-
   ing from the modifications as discussed
   above in preparation for delivery to the EPA.
   The following work was performed in the
   laboratory in order to ascertain the performance
   of the improved instruments:

   a) A calibration of the instruments was performed;

   b) The instruments were made to operate with
      sprays simulating those encountered in
      typical facilities;

   c) Design modifications were incorporated to
      improve the performance under the simulated
      conditions

   d) An extensive test and measurement program
      was performed with a Brink impactor in the
      KLD laboratory.  The primary purpose of these
      tests was to generate data for comparison with
      the measurements simultaneously recorded with
      the DC-2.

   After the operation of the instruments was optimized
   in the laboratory, a program of field validation
   was undertaken.  Four facilities were selected and
   approved for field measurement bv the EPA
   Project Officer.

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                          SECTION 2

               CONCLUSIONS AND RECOMMENDATIONS
     A prototype instrument had been previously built and
successfully used in the field for measuring droplet size and
concentration in gas flows.  The device operated on the heat
transfer principle described in Section 1.  Under the program
reported herein, a second generation of the instrument was
implemented and demonstrated in the field.  From the work on
the improved version of the instrument, the following conclu-
sions and results were reached:

     »  Water droplets from 1 to 600 microns in diameter,
        flow velocities up to 10 meters per second and gas
        temperatures between 0°C and 100°C can be readily
        measured by the improved instrument (DC-2).   The
        distribution of droplet sizes is subdivided into
        14 size ranges by the device.

     •  The involvement of the operator is reduced to a
        minimum and no auxiliary equipment is required to
        perform the measurement.

     «  The instrument is particularly suitable for field
        use because of its portability and the small size
        of the sampling probe.

     •  The probe is the only component which requires
        care during handling and use.  Special effort was
        devoted to ruggedize this component.  Furthermore, a
        replaceable sensor was designed and successfully
        tested in the laboratory.

     «  The Printer/Controller enhanced the operation of
        the DC-2 in the laboratory and in the field.  The
        printed data facilitates the reduction and
        interpretation of results.

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     The results from the laboratory and field studies
provided some specific conclusions with respect to the
measurement of droplet distributions:

     «  The data obtained with the Brink impactor was
        higher than the data from the DC-2.
        This conclusion was reached after careful
        attention to minimize the data scatter in the
        impactor results.

     •  Measurements from the Brink impactor can be re-
        lated to the DC-2 measurements using an equiva-
        lence factor, K, which is applied over the size
        range of 1 ym to 10 vim.  The equivalence factor
        represents the aerodynamic influence on the
        capture area of the wire and other phenomena
        which characterize the difference in the two-
        measurement procedure.  The aerodynamic
        influence was investigated and defined for the
        size ranges between 1 ym to 10 urn.

     •  Laboratory measurements with the impactor
        exhibited substantial scatter even with care-
        fully controlled procedures.  If the droplets
        were water without trace elements as a diagnos-
        tic, the scatter in the data was unacceptable and
        meaningful results could not be obtained.  By
        using a 10% solution of NaCl, more reliable
        results were achieved.

     •  From a series of qualitative tests, it was con-
        cluded that the scatter in the impactor results
        is caused by evaporation/condensation within the
        impactor.  Small changes in environmental condi-
        tions can significantly alter the measurements
        with the impactor.

     «  The DC-2 was used at four different field sites,
        and the device performed well.  The Shippingsport
        Power Plant has a limestone scrubber, and the
        entrained liquid in the exhaust flow provided the
        most difficult test conditions.  However, with the
        correct procedure, meaningful results were achieved
        with the DC-2.
                              10

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     As a result of this research project, several recom-
mendations can be made with respect to future activities in
droplet measurements:

     •-  Further field testing should be performed with the
        DC-2 and Brink impactor.  These measurements should
        be compared and the reliability of the two proce-
        dures established.  The test sites should be
        selected to encompass many different test environ-
        ments to establish a range of applications for
        both devices.

     •  Guidelines and procedures should be developed for
        the operation of the DC-2 and the impactor for
        droplet measurements at various types of facili-
        ties.  These procedures should be documented in a
        handbook for use  by a field team.

     0  The replaceable probe for the DC-2 provides many
        advantages for operating the equipment in the
        field.  The development of this equipment should
        be completed and introduced as a field operating
        procedure.
                              11

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                         SECTION 3

                 DEVELOPMENT OF THE PROBE
GENERAL BACKGROUND

     The probe is the component which performs the droplet
measurement when inserted into the flow under investiga-
tion.  The probe has the shape of a thin cylinder and is
connected to the electronic processor with a single coaxial
cable.  Attached to the probe is a sensor composed of a
platinum wire, five microns in diameter and one millimeter
long.  The sensor detects droplets while the remaining part
of the probe provides a means of mounting and protecting the
sensor.

     The diameter of the platinum wire was selected as a
compromise  between its mechanical strength, requiring a
large wire diameter, and the minimum droplet diameter to be
measured, requiring a small wire diameter.  The sensor is the
only component of the droplet counter subject to damage, con-
tamination or destruction.  The improvement of the probe, in
particular the sensor, will result in a more useful and
reliable instrument.

Sensor as a Mechanical Structure

     The reliability of the sensor and its mount is directly
related to the accuracy of its measuring capability as well
as its structural soundness.  Studies were conducted to test
the sensor's reliability for measurement and handling.

     The mechanical model of a typical sensor is shown in
Figure 3.  The main supporting structure is a rigid metal ring
built around the sensor and at the end of the probe.  The
diameter of this ring is approximately one centimeter (.4
inches), which is large enough to prevent the accumulation of
water which may eventually clog the sensor.  The sensor is
mounted across the ring on two prongs (b).  The prongs,  each
3 mm long, provide both mechanical support and electrical con-
tact.  The sensor, originally a silver plated platinum wire,

                               12

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Figure 3:   Mechanical Model of Sensor
                 13

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is soldered at the two prongs.  The silver coating is then
removed from a section of the wire with nitric acid exposing
one millimeter of sensor  (S).   It is this exposed section that
is sensitive to and measures droplets.  The remaining unexposed
platinum wire  (a) serves as additional support for the sensor.
The dimensions of the sensor and its surrounding supports are
presented in Figure 3.

     This mechanical model was tested for its response to:

     • Vibrations (acceleration),
     • Aerodynamic flow,
     • Collision of solid particles

     In all practical situations, accelerations along the axis
of the sensor and support cannot produce breakage.  The sensor
is much more sensitive to accelerations along directions
perpendicular to the sensor axis.  The sensitivity depends
on the initial tension of the  wire which is basically taut
after the silver coating is dissolved, but acquires a certain
amount of slack when heated.  An additional limitation is
introduced by the flexure of sensor supports (b)  in Figure 3.
The flexure increases the separation of the prong tips.  The
widening gap between the prongs eventually becomes larger
than the length of the sensor, thus breaking it.   The study
indicates two separate solutions to the lateral acceleration:

    •  Very light supporting prongs so that the
       longitudinal strength of the sensor prevents
       its separation

    •  Strong prongs with large sections to minimize
       the deflection

    For relative ease of construction and to minimize the
electrical resistance of the connection, the second approach
was taken.  Also slack in the  wire greatly improves the
sensor integrity.  Furthermore, it became apparent that the
use of tapered prongs reduces  deflection for a given value of
lateral acceleration.

     Extensive testing showed  that a substantial gain in probe
ruggedness may be achieved by  mounting the supporting ring on
a resilient structure.  This substantially reduces the level
of acceleration transmitted to the sensor.  This feature was
incorporated in the disposable sensor probe.
                               14

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     The effect of air flow and the turbulence normally
associated with this flow may cause oscillation of the sensor.
The amplitude of this oscillation increases with the slack in
the wire.  Other factors inducing sensor vibrations with
associated flexure fatigue include the random attachment of
water droplets on the sensor and the collision of solid
particles with the sensor.  The requirement of a taut sensor
able to survive a strong gas flow contradicts the requirement
of a slack sensor, necessary to withstand large lateral
acceleration.  A compromise between  the conflicting require-
ments should allow a deflection of the sensor center point of
the order of 50 microns.  However, the technique used to build
the sensor does not allow for such close control.

    The collision of solid particles with the sensor requires
it to be slack to withstand the impact without breaking.  The
maximum force which may be applied to the sensor before it
breaks is approximately .5 gms.   With the above mentioned 50
microns of slack, breakage occurs when a 100-micron diameter
particle moving at 10 meters per second directly collides
with the sensor.   At a relative velocity of 1 meter per second,
solid particles within the diameter range of a quarter of a
millimeter may destroy the sensor.  There are no obvious
solutions to eliminate or reduce the risk of such collisions.
The use of a deflecting rod located upstream of the sensor and
mounted parallel to it was one of the approaches tested. This
solution, however, had  limited success.  The function of this
rod was to deviate the large solid particles or, at least, to
reduce their velocity to a safe value prior to collision with
the sensor.  In practice, however, the excessive collection of
water on the rod  prevented the proper interaction of drop-
lets with the sensor.

The Aspirating Probe

     The aspirating probe shown in Figure 4 uses the same
platinum wire sensor adopted for the open probe.  This sensor
is mounted across a small tube having a 1 mm to 6 mm inside
diameter (.040 to .25 inch).  A vacuum pump is used to create
a gas flow along this tube.

     Tests with the aspirating probe in the field and labora-
tory showed that the possibility of damaging the sensor during
handling and operation is almost entirely eliminated.  It was
also shown that, with a proper design of the conduit entrance,
the amount of noise due to air turbulence may be substantially
reduced.
                              15

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o\
                    Enlarged Section of the Entrance
                                                                                 Suction
                                     Figure 4:   Aspirating Probe

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     Several problems are associated with the aspirating probe,
a description of which follows.

     To remove a droplet having a diameter of 600 microns from
the sample flow and move it past, the hot wire sensor requires
an air flow velocity of approximately 30 meters/second  (100
feet/second) around the sensor.  However, this velocity is
too high to assure proper interactions of droplets and sensor.
Large droplets are shattered.  Interaction time of the small
droplets and sensor is too short,  greatly reducing the signal
output.  The reduction of aspiration flow velocity below
30 meters/second prevents the detection of large droplets.  As
an example, a flow of 3 meters/second (10 feet/second) does
not allow for detection of droplets 150 microns or larger.

     Another problem associated with the operation of the
aspirating probe at a high flow velocity is that the count
rate may exceed the maximum counting rate of the instrument,
which is 500 droplets per second.   An attempt to solve this
limitation was made by using a dilution stage.  Such a stage
mixes a measured droplet-carrying flow with a measured clean
air flow, thus reducing the droplet concentration to a level
which is compatible with the instrument count rate.  The sensor
is designed to operate on this diluted sample.

     The implementation and operation of a dilution stage is
a rather involved procedure.  Measurements performed in the
laboratory showed poor repeatability.  Differences in the
temperature of the mixing gases affected the measurements.
Furthermore, in order to create a good sample dilution, strong
mixing of the two flows is required.  The turbulence necessary
for this mixing affected the results of the measurement of
small droplets.  The results of this study were presented
to the contract monitor and it was decided that further work
with the aspirating probe should be discontinued.

Protected Probe

     In order to increase the sensor life, a new probe configu-
ration was implemented.  The basic idea was to have a sturdy
body with an enclosure to protect the sensor when not .in use.
Several configuratons were implemented and tested.  The one
finally selected is shown in Figure 5.   It consists of tubing
having a diameter of 10 mm  (.39 inch) and a length of 30 cm
(12 inches).  A hole is bored in one end of the tube where the
sensor is located.  A BNC connector provides the electrical
connection.  A thin 12 mm (.5 inch) diameter tubing slides

                               17

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                                OPEN POSITION
oo
                                                        CLOSED POSITION
                                  Figure 5:  Protected  Probe

-------
along the probe closing the opening and protecting the sensor
when not in use.  The support for the sensor is short and
strong to minimize the amplitude of vibration of the sensor when
the probe is subject to impact during handling.

     To use strong cleaning substances such as hydrochloric
and other inorganic acids, the probe is constructed from
corrosion-resistant materials.  The body of the probe and
support of the sensor is made with stainless steel and the
insulating material is ceramic.

Techniques to Clean the Sensor

     A study of techniques to clean the sensor after it has
been operating in slurries and deposit-prone mists and sprays
was undertaken.  These techniques may be grouped into three
approaches:

     •  Heating,
     «  Mechanical cleaning,
     •  Liquid cleaning.

     Some of the contaminants which accumulate on the sensor
may be removed by heating the probe above the contaminants'
boiling or decomposition temperatures.   Unfortunately, the
contamination may include substances which become baked onto
the sensor under the effect of heat.  This results in a crust
which is difficult to remove by other methods.  Hence, it was
concluded that heating the probe is not an acceptable cleaning
technique.

     The mechanical approaches included ultrasonic and sand
cleaning techniques.   The ultrasonic cleaning was performed by
submerging the contaminated sensor in a cleaning fluid and
subjecting it to an ultrasonic agitation.  The enhancement of
the fluid cleaning effect was negligible when low ultrasonic
power was used.  To be effective, the  ultrasonic agitation
technique required high power.  The extent of this power, how-
ever, is capable of destroying the sensor due to mechanical
vibration.   An attempt to solve this problem was made by
designing sensors with a smooth transition between the exposed
platinum wire and the silver supporting wire.  While sensors
of this design did last longer than short transition sensors,
they also tended to fail, probably due to flexural fatigue.
All the ultrasonic cleaning was performed at a frequency of
30 KHz.  If the assumption that sensors break due to flexural
fatigue is valid,  the use of higher frequencies, and thus
substantially lower vibration amplitudes may achieve the

                               19

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cleaning of the sensor without breaking it.  Such an extension
of the work was not pursued.

     Sand cleaning techniques were performed by dropping sand
on the contaminated sensor and also by sand blasting the
sensor with a small air jet containing fine particles.  The
dripping technique was successful, but required relatively large
particles and consumed excessive time.  The sand blast approach
consumed much less time, and was particularly effective for the
removal of dry deposits.  The sand blaster is mounted in a
small jar with a rubber stopper one inch in diameter.  The
probe, air jet tube and ventilation tube are mounted on the
stopper.  The sensor must be rotated to expose all areas to the
jet stream of sand.  Sticky  coatings on the sensor such as
grease tended to collect the sand, stopping the cleaning
action.  The best results were achieved with alundum grade 400
which is used to grind optical glass.  It was discovered that a
slight increase of the sensor's resistance  (~.04Q) during the
cleaning operation was a good indication that the bulk of the
contaminants were removed.  Care should be observed to keep
the grinding sand dry.

     Liquid cleaners are used either to dissolve the contami-
nants or to decompose them through chemical reactions. •

     A variety of organic grease and mineral oil type con-
taminants are easily removed with a sodium hydroxide solution,
which is a good general-purpose cleaner.  Greases and oils may
also be removed with carbon tetrachloride.  Carbon and soot
may be removed with commercial liquids used to clean carbure-
tors .

     The operation of the probe exposed  to tap water shows
accumulation of white crystals, mostly sulfates.   Solutions
of hydrochloric acid 10% prove to be very effective to remove
these crystals.  As mentioned previously, to submerge the
probe in such a corrosive medium, a corrosion proof probe was
built using stainless steel for the body and sensor support.
The sensor itself uses silver and platinum which are able to
withstand the acid.  As a dielectric insulator, a ceramic
material was used.

     Some of the contaminants encountered during the field test
of the instrument are soluble in plain water or boiling water.
Such is the case of the ammonia sulfate crystals typical of the
pilot scrubber at the Colbert Steam Plant in -Alabama.  Water
is also effective for the removal of sodium chloride crystals.

                               20

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     From the described work on sensor cleaning, it has been
concluded that sand blasting as well as liquid cleaning may be
used to deal with almost all contaminants.  The selection of
the most effective liquid cleaner requires some systematic
search.

Work on Disposable Sensors

     Work in the field showed that the cleaning of the con-
taminated sensor is a time consuming operation, especially
when dealing with limestone solutions.  In order to expedite
the measurement  procedure, direct replacement of the contami-
nated probe with a new one was adopted as a standard procedure.
The convenience of having an inexpensive sensor which can be
replaced in the field, saving most of the probe's supporting
structure,  is obvious and a study was undertaken.

     The disposable sensor was built on a two-prong plug.
The most important consideration was to have good mechanical
supporting characteristics and low electrical resistance of
the contacts.   The corrosion resistance of the materials was
not important, since it operates for a short time and it is
disposable.  Figure 6 shows the disposable sensor probe
successfully tested in the laboratory.

     Tests were performed with these probes in the laboratory
without any problem or deterioration of performance as compared
to other types of probes.  A probe having the socket mounted on
a resilient mount is presently being investigated by KLD. This
will effectively reduce the acceleration of the sensor below
the breaking point when the probe body or protective ring is
impacted during handling or use.  The cost of the disposable
sensor material is negligible and only the cost of labor for
its construction is relevant.

     The laboratory work demonstrated the feasibility of the
disposable probe, but only limited field experience was possi-
ble.  KLD recommends that future activities include extensive
field testing of the disposable probe.
                               21

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          Sensor
Figure 6:  Disposable
           Sensor Probe
          22

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                          SECTION 4

                          THE DC-2
GENERAL DESCRIPTION

     The DC-2 is a modified and advanced version of the DC-1
model.   The droplet counter/measuring device was extensively
investigated in the following areas:

     0  Temperature flow measurement,
     9  Velocity flow measurement,
     e  Droplet counting,
     e  Modifications of the physical characteristics
        and construction of the instrument.

     The use of the DC-1 droplet counter requires the operator
to determine the precise measurement of the probe's resistance
under various conditions of gas flow, velocity, temperature1
and instrument settings.  A built-in meter  (incorporating a
'wheatstone tri igo) is used to perform these measurements in
the DC-1 as follows (see Ref. 1):

     «  Setting the DC-1 dial on "TEMPERATURE," the sensor
        resistance is measured as  the temperature of the
        gas is obtained.  This is  accomplished by means of
        a calibration curve showing sensor resistance versus
        gas temperature.

     •  Setting the dial on "VELOCITY," the sensor
        resistance is first measured for a no-flow con-
        dition (zero velocity).   This is achieved by
        enclosing the sensor within a shielded container.
        The sensor resistance is again measured by exposing
        the sensor to the flow under study.  The gas flow
        velocity is obtained from a calibration curve,
        depicting gas flow velocity versus the ratio
        between shielded and exoosed sensor resistance.
                             23

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     e  After obtaining the sensor resistance for the
        gas temperature inside the stack, an overheat
        condition is set on the Wheatstone bridge at a
        resistance 1.75 times this resistance.  The DC-1
        is then set to count.  The electronics automati-
        cally maintain the sensor temperature at 192°C
        above the gas temperature.  At this time, the
        measurement of the droplet diameter occurs.  The
        counting is allocated to six droplet diameter
        ranges determined by the particular plug-in dis-
        tribution module selected.

     The convenience of reducing the operator's involvement,
as described above, to a minimum became evident after using
the DC-1 Droplet Counter in the field.  To achieve this,
each one of the steps required to perform the measurements
was investigated.  Possible schemes for their automatic
operation were devised and compared.  The most suitable were
     selected.
     The success of automatic operation of the droplet counter
depends on the following:

     e  To fabricate sensors so that a precise correla-
        tion between absolute temperature and sensor
        resistance is achieved.  The fabrication of a
        calibrated sensor requires that a specific resis-
        tance be achieved at the ambient temperature at
        which the etching takes place.

     •  To replace operator handled calibration curves by
        automatic electronic processing.  For this require-
        ment, the highly non-linear relationship between
        gas flow velocity and electrical output is
        linearized by an appropriate circuit.

     e  To automatically balance the Wheatstone bridge during
        the measurement of the flow temperature.  It should
        be emphasized that the measurement of the gas
        temperature itself has no relevance  for the
        measurement of droplet size and concentration.
        However, this temperature is required to set the
        operating condition of the sensor at a specific
        and constant temperature above the stack tempera-
        ture, thus achieving the proper cooling effect from
        the interacting droplets.

                               24

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     All the above aspects were successfully accomplished in
the course of the project, resulting in an instrument which
performs the entire measuring sequence automatically.

     The operator of the DC-2 is only required to locate the
probe on the facility and switch the power on.  By pressing
the START button, the following automatic sequence takes
place:

     •  The sensor is cold.   Its resistance, indicative
        of the gas temperature, is measured with an
        electronic circuit by balancing the i^hearsitoiie
        bridge.  The number of steps required to
        achieve this balance is a direct indication of
        the temperature. The temperature is displayed and
        stored in digital form.  The entire measurement
        takes less than a second.

     •  At the completion of the temperature measuring
        cycle, the Wheatstone bridge becomes imbalanced.
        The electronic feedback circuit heats the sensor,
        increasing its temperature a prescribed amount
        above the measured gas temperature.  The electric
        power required to keep the sensor temperature at
        this level is proportional to the cooling due to
        gas-to-sensor relative velocity.  The electrical
        power is digitized,  stored and displayed.  This
        measurement requires less than a second.

     o  The pulses generated by the cooling of the sensor
        under the impaction of the droplets are analyzed
        for amplitude.  Each is then categorized into one
        of 14 droplet size intervals, plus a total.  The
        time required for this process depends on the
        number of droplets being counted or the time limit
        setting.  During the counting period, a "C" appears
        on the display.   On reaching a time or droplet
        count limit, an "H"  (HOLD)  appears on the display.

     e  If the "START" button is pressed while the instru-
        ment is measuring velocity or counting,  a time
        delay assures that the sensor cools and reaches
        equilibrium with the surrounding gas prior to the
        measurement of the temperature.
                              25

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     «  When the time or droplet count limit is reached,
        the power to the sensor is disconnected, extending
        its life and preventing the accumulation of
        deposits.

IMPLEMENTATION OF TEMPERATURE MEASUREMENT

     The stack temperature is available directly at the DC-2
output display, via the front panel slide select switch.  The
operator simply sets the switch to "TEMPERATURE", presses
the "START" pushbutton, and reads out the temperature directly.
The readout is in units of degrees centigrade, with a range
of 0°-100°C and a resolution of 1°C.

     Figure 7 depicts a block diagram of the "Temperature
Conversion Logic."  In the DC-2 unit, a ladder network  (not
to be confused with the interval size module)  controlled bv a
counter and comparator, replaces the potentiometer/null meter
employed in the DC-1.  When the "START" button is pressed,
both the binary and decade counters are automatically incre-
mented to the point where the ladder resistance equals the
sensor resistance.  The counters contain the available stored
temperature information for display purposes.   The etching of
the platinum wire requires 4 ± .040 at 25°C to insure a match
in thermal characteristics to the matched ladder network.
Figure 8 depicts the sensor conductance versus temperature
characteristics.  The linear approximation curve resulting
from the ladder network is also displayed.  Sources of error
in the temperature readout and their associated percentage
of error are as follows:

     •  Linear approximation        ±4%
     •  Resistance of ladder        ±1%
     «  Resistance of probe         ±1%
     •  DC drift in the comparator  ±1%

These errors, of course, will not always cumulate in bhe
same direction.  An RMS average is more realistic, resulting
in a full scale-percent error of ±4.35%.

IMPLEMENTATION OF VELOCITY MEASUREMENT

     Several improvements for velocity measurement have been
incorporated in the DC-2.  First, the measurement was automated,
In addition, the measurement range and accuracy were improved
by three changes:
                             26

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                               + 5 VDC
8-Bit Ladder
  Network
Binary Counter
   (8 bits)
Decade Counter
  (3 decades)
                    (To Display Multiplexing)
       Figure  7:  Temperature  Conversion
                  Block  Diagram
                       27

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274-,
264-
254-
244-
234-
224-
214-
204-
194-
184"
174
                Sensor  and Cable Conductance  (—]
                                              0 (i
                               Linear Approximation
        10     20
         Figure 8:
30    40    50   .60      70     30     90
Sensor Temperature Characteristics
100
                                 28

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     •  The probe temperature was elevated (overheat
        mode).

     «  Constant probe temperature was employed instead
        of constant probe heating current.

     «  A precise linearizer circuit was used to compensate
        for the response of the sensor.

     e  A special circuit was incorporated to compensate
        for droplets which strike the probe and tend to
        cause velocity measurement errors.

     The DC-2 Droplet Counter provides a direct indication of
the flow velocity in digital form.  It is displayed by
setting the slide switch to "VELOCITY".  The readout is in
meters per second.  The range is between 0 to 10 with a
resolution of .1 meter per second.
     In measuring velocity with the DC-1, a constant heating
current is employed, whereas with the DC-2, the sensor is
maintained at a constant temperature.  A feedback power
amplifier maintains a sensor temperature of approximately
250°C above the ambient temperature.   ^.his automatic setting
is performed in two steps:

     •  The Wheatstone bridge is balanced, as described above,
        for the gas temperature measurement.

     •  The sensor is heated by short circuiting half of
        the bridge resistance, n, (see Figure 9) and
        connecting a power amplifier on the feedback loop.
        The sensor is heated until  its increase in resistance
        restores the bridge balance.

     From the principle associated with the operation of the
hot wire anemometer, it is known that the cooling effect of
a gas flow depends on the temperature difference of the sensor
and gas and on the velocity of the gas.  The voltage, VB, is
directly proportional to the energy released from the sensor
because of the gas flow.  This voltage ranges from .8 volts at
zero velocity to 1.3 volts at a velocity of 10 meters per
second.  An amplifier is used to subtract the voltage at
zero velocity.  The amplifier also scales the electrical
signal which is fed to a squaring network.  This results in a
relationship of linear voltage versus gas velocity.

                              29

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                 Power
                 Amplifier

800 mv
1300 mv
Scaling
Amplifier
and D.C.
Restoration


0 V
5 V
Squaring
Network


0
2.5V
Voltage
Controlled
Oscillator

0-]
— »•
l
.00 PPS
1-Second Gate
                         3-Decade
                         Counter
                            To
                          Display
                        Multiplexing
           Figure 9 :   DC-2 Velocity  Measurement
                      Network
                             30

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     To digitize the gas velocity information, the  linearized
signal acts on a voltage controlled oscillator whose
frequency is zero for no flow and increases to 100  pulses per
second for a flow of 10 meters per second.  The output from
the voltage controlled oscillator is accumulated during one
second.  The information is stored and displayed in meters
per second.  The presence of large numbers of droplets in the
gas flow has a cooling effect which may be interpreted by the
instrument as an apparent higher gas flow velocity.  To
compensate for this error, a special circuit was conceived
and incorporated into the DC-2.  The basic idea is  the
separation of droplet  signals, with characteristic spikes,
from the constant level electrical signal created by the gas
flow.  The droplet signals are integrated and the correction
is subtracted from the total bridge voltage.

DROPLET COUNTING

     The operation of the DC-2 in the count mode differs
from the operation of the DC-1.  The DC-2 is automated
with three droplet TOTAL LIMITS and three TIME LIMITS.
Furthermore, the number of droplet size intervals was
increased from six to 14.

     The operator of the DC-2 does not have to make any
potentiometer/null meter measurements as is necessary
with the DC-1.  When the operator presses the "START"
button, the temperature ladder network is automatically set
to the probe resistance as previously described.  At the end
of the temperature conversion cycle, lasting for less than
one second, the DC-2 automatically goes into the count mode.
This starts with the overheat mode, which is described in the
velocity flow section.  The overheat is held throughout the
entire count cycle and is released when the preset  limit is
reached.  Overheating of the probe only occurs during the
count mode, thus augmenting the life of the probe.  The
storage capacity of each of the size intervals for droplet
diameter was increased to 10,000.

PHYSICAL CHARACTERISTICS AND USE OF THE DC-2

     Particular attention was devoted to better adapt the
Droplet Counter to field work by making it more transportable
and convenient to use.  The DC-2 consists of the device itself,
five probes, four modules for different droplet size ranqes and a
coaxial cable approximately 15 feet long.  All components are
neatly contained in a portable case.  The dimensions of the
case are :
                             31

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     Length:  36.5 cm (14 1/2 inches)
     Width:   15.1 cm (6 inches)
     Height:  15.3 cm (5 27/32 inches)
     Weight:   4 kgm (10 Ibs.)

     The case and card bucket are made of drawn aluminum.
The circuit cards are wire-wrapped and made of glass epoxy.
The instrument is powered from 125 VAC (±15%), 60 Hz line,
requiring 2.5 watts of power.  The electronics were
designed with low power CMOS logic.  The digital display
is a liquid crystal type, chosen for its superior performance
in bright ambient light.

     A view of the instrument panel is presented in Figure 10,

Use of the Instrument

     In order to collect data on droplet size and concentra-
tion, the instrument must be powered from a 110-volt, 60-Hz
line.  The coaxial cable and probe are connected with the
instrument OFF.  A toggle switch is used to activate the
instrument; no warm-up period is required.  The probe is
inserted into the flow under study.  It is important to
realize that the DC-2 monitors the flow conditions and drop-
let population practically on a single stream line.  Whenever
average conditions over the facility cross section are
desired, an appropriate set of sampling points must be
adopted.

     It is important to position the sensor axis perpendicu-
lar to the gas flow to obtain valid gas flow velocity and
droplet population data.  In certain facilities, the flow
direction is not known; e.g., flow rotation generated by
spinners, blowers or flow barriers.  A proper sensor
positioning is achieved by observing the velocity reading
while reorienting the sensor direction.  The maximum
measured gas velocity corresponds to a sensor oernendicular
to the flow direction.

     The probe should be handled with care to avoid damage or
destruction of the sensor due to impacts.  Droplets and gas
flow do not damage the sensor.
                              32

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U)
                                                               Kl.l)   .'.I .. . -kl ! •. INC
                                                               ;•• f - r IMIJ I Ljrj ijTAriorj.  MY
                                      Figure 10:   View of  the DC-2 Front Panel

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Selection of the Droplet Distribution

     Four sizing modules are made available to the operator as
shown in Tables 1,2, 3 and 4.  Two of them cover the entire
droplet diameter range of the instrument, while the other two
emphasize detection of smaller droplets.  The operator selects
the module which best describes the facility conditions and
inserts it in the holder at the left side of the front panel.
The removal of the module is performed by pushing upwards
through a slot at the side of the module holder.  A series of
numbers are printed at the exposed side of each network.
These numbers represent the droplet diameter in microns.
The readout select switch points to the interval number on the
right and the corresponding droplet diameters on the left.
The interval size represents the smallest droplet diameter
for each interval.  The electronics also keeps a count of
the total number of droplets.
     The total number of droplets to be counted is selected
by a toggle switch which allows for the selection of 100,
1,000 or 10,000 total number of droplets.

     If so desired, the instrument can be operated on a time-
limit basis by selecting, with another toggle switch, 10,
100, or 1,000 seconds.

     The droplet counting process will stop whenever the total
selected number of droplets or time limit is reached, which-
ever happens first.  When this occurs, the letter "H" appears
in the display, signifying that the system is in hold, awaiting
another cycle initiation..  The following data is available
for readout:

     TEMPERATURE of the gas,
     VELOCITY of the gas flow,
     TIME interval,
     TOTAL number of droplets and the
     number of droplets in each one of the 14 size INTERVALS.

Handling and Maintenance

     A few precautions are necessary in handling the DC-2 to
achieve maximum performance and prevent damage to the sensor.
The probe should never be treated roughly, nor should the
operator attempt to touch the sensing wire.  The sensing wire
may be broken if the aerosol stream contains large solid
particles.
                             34

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     For best operation, the probe should be kept clean.  A
medium power magnifier may be used to determine the state of
cleanliness of the sensor, and liquid cleaners are the best
means of removing contaminants.

     The electronics of the DC-2 is all solid state and
highly reliable.  If the unit does not perform, first check
the fuse that is located in the bottom of the box near the
power ON switch.  If the fuse is not open, place the Readout
Select Switch in the TEMPERATURE measuring position and press
the START button.  If the probe is operating properly, the
number in the display will count to some finite value and
remain there.  If the probe is faulty, the number in the
display will not reach a fixed value, but will continually
cycle from zero to a maximum.

DATA ANALYSIS

     The DC-2 Droplet Counter is capable of providing a
large amount of data which is usually presented in tables
or, more often, on graphs.  A volume or mass distribution
emphasizes large droplets and de-emphasizes or ignores the
small ones.  On the other hand, a description of the number
of droplets puts the emphasis on the smaller droplets, which
are more numerous.  A third presentation, seldom used, depicts
the surface of the liquid droplets versus its diameter.  In
this case, the emphasis is a compromise between the other two
methods.

     In principle, it is possible to convert from one dis-
tribution to another, but in practice, care should be
exercised to prevent the introduction of large errors due to
averages and approximations.  An obvious example is the
difference between direct average diameter and the diameter
of the average volume.

     The droplet distribution may be displayed by computing
and summarizing the number of droplets or by summarizing
the volume of these droplets.  The droplet concentration, n^,
corresponding to each droplet size interval is computed by
the expression:


                           Drop/cm3    (i = 1'14)
               v
                            35

-------
where

     Nj_ = Droplets counted in the itn channel
      v = Flow velocity  (cm/sec)
      t = Time interval  (sec)
      I = Sensor length  (.1 cm)
     Di = Average droplet diameter for the i*-n channel  (cm)
      d = Sensor wire diameter  (5x10""* cm) .

In plotting the distribution of the number of droplets  versus
droplet diameter, each of the values of nj_ is divided by  the
width of the droplet size interval, ADi, in microns.  This
ordinate is then plotted corresponding to  values of the
related average droplet diameter, Dj_.  To  simplify the  com-
putation, all the constants are grouped together by a
factor, Ki or Kj_v, presented in Tables 1,  2, 3 and 4.   This
allows for the following expression:
where nj_ is the number of droplets per unit volume of gas  per
unit diameter range for the itn size interval.

     For the volumetric distributions, Vj_, in the ifc" size
interval, the expression becomes
By writing in terms of the constant, Kj_v, of Tables  1  through  4,
                  V. =
With the above formulas, the data from the DC-2 can be  readily
reduced to produce number concentration or volume distribution.
Other quantities often encountered in particle sizing,  such  as
mass mean diameter, surface mean diameter, etc., can be
derived from the existing data without difficulty.  In
Section 6, Laboratory Testing, these formulas are applied  to
make comparisons with the mass measurements  from the Brink
impactor.  Also discussed in Section 6 are the effects  of
flow conditions on the capture size of the hot wire.
                              36

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Table 1:  Internal Sizing Distribution for Module 1
Size
Enterval
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Droplet
Diameter
(microns)
1.0-1.6
1.6-2.6
2.6-4.1
4.1-6.6
6.6-10
10 - 17
17 - 27
27 - 43
43 - 69
69 - 110
110 - 176
176 - 281
281 - 450
> 450
Di
(microns)
1.3
2.1
3.35
5.35
8.3
13.5
22.0
35.0
56.0
89.5
143.0
228.5
365.5
585.0
Ki
( l ]
ycm2microny
2.6 x 104 '
1.4 x 104
8.0 x 103
3.9 x 103
2.2 x 103
7.7 x 102
3.7 x 102
1.6 x 102
6.3 x 101
2.6 x 101
1.0 x 101
4.0 x 10°
1.6 x 10°
6.3 x 10'1
Kiv
f micron^
\ cm2 }
3.0 x 104
6.8 x 104
1.6 x 105
3.] x 105
6.6 x 105
9.9. x 10-
2.1 x 106
3.5: x 10
5.3 x 106
1.0 x 107
1.7 x 107
2.8 x 107
4.1 x 10 7
5.6 x 107
                         37

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Table 2:  Internal Sizing Distribution for Module 2
Size
Interval
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Droplet
Diameter
(microns)
1-36
36 - 70
70 - 105
105-139
139-174
174-209
209-243
243-278
278-313
313-347
347-382
382-416
416-450
> 450
Di
(microns)
18.5
53
87.5
122.0
156.5
191.5
226.0
260.5
295.5
330.0
364.5
399.0
433.0
468.0
K. \
(• l }
\ cm micron /
1.2 x 102
5.0 x 1C1
3.0 x 101
2.3 x 101
1.7 x 101
1.5 x 101
1.3 x 101
1.0 x 101
9. 5 x 10°
8.8 x 10°
7.7 x 10°
7.3 x 10°
6.7 x 10°
6.0 x 10°
Kiv
( micron2 \
I cm2 )
y-.o x ios
4. 0 x 106
1.2 x 107
2.3 x 107
3.6 x 107
5.5 x 107
7.6 x 107
9. 6 x 107
1.3 x 108
1.6 x 108
2.0 x 10 8
2.4 x 108
2.8 x 108
3.3 x 108
                         38

-------
Table 3:  Internal Sizing Distribution  for Module 3
Size
Interval
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Droplet
Diameter
(microns)
1 - 1.4
•1.4-1.8
1.8-2.5
2.5-3.3
3.3-4.5
4.5-6.1
6.1-8.2
8.2-11
11-15
15-20
20-27
27-37
37-50
> 50
Di
(microns)
1.2
. 1.6
2.15
2.90
3.90
5.3
7.15
9.6
13.
17.5
23.5
32.0
43.5
60
Ki
1
cm micron
4.0xl04
3.8xl04
2.0xl04
1.6xl04
9.4xl03
6.0xl03
4.0xl03
2.4xl03
1.4xl03
8.9xl02
S.OxlO2
2.7xl02
1.6xl02
7.7X101
Kiv
micron^
cm*
3.7xl04
8. IxlO4
l.lxlO5
2.1xl05
2.9xl05
S.OxlO5
7.9xl05
1.2xl06
1.7xl06
2.6xl06
3.6xl06
4.8xl06
6.£xl06
8. 7x1 O6
                          3T9

-------
Table 4:  Internal Sizing Distribution for Module
Size
Interval
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Droplet
Diameter
(microns)
1-3
3-5
5-7
7-9
9-11
11-13
13-15
15-17
17-19
19-21
21-23
23-25
25-27
> 27
Di
(microns)
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Ki
1
£
cm micron
7.1xl03
5.6xl03
4.5xl03
3.8xl03
3.3xl03
2.9xl03
2. 6xl03
2.4xl03
2.2X103
2.0xl03
1.9xl03
1.7xl03
1.6xl03
l.SxlO3
Kiv
micron^
cm^
3.0xl04
l.SxlO5
5.2xl05
l.OxlO6
l.SxlO6
2.7xl06
3.8xl06
S.lxlO6
6.7xl06
8.4xl06
l.OxlO7
1.3xl07
l.SxlO7
1.7xl07
                         40

-------
                           SECTION 5

                       PRINTER/CONTROLLER
GENERAL DESCRIPTION

     The Printer/Controller was designed to work in con-
junction with one or two DC-2 Droplet Counters and a Probe
Multiplexer.  It provides the user with a summary printout of
data measured by the Droplet Counters.  This eliminates
recording the data manually.

    The front panel controls make the printer/controller a very
versatile instrument.  The controls consist of Month and Day
thumbwheel switch, Number of Runs switch, Print Mode switch,
Time Interval switch, Limit Select switch,  Start switch, Paper
Feed switch and Clock Control switches.  The functions of these
switches will be discussed in greater detail later in this sec-
tion.

     At the beginning of each Print Cycle the Serial Number,
Date and Time information is printed out.  Other information
being printed out is Temperature, Total number of droplets
counted, Elapsed Time (time required to count droplets),
Velocity and Droplet Distribution.  When in the MUX Mode, the nrin-
ter will also print out the number of the probe being monitored.

     The Clock Module provides the time information while Month
and Day information is set manually with thumbwheel switches.
The droplet distribution information is received from the
Droplet Counter with respect to the Distribution Module being
used.  An example of a typical printout is illustrated in
Figure 11.

     Printing is done by a mosaic printer capable of printing
all characters that can be formed within a 7 by 5 dot matrix.
The printer is mounted in such a way that access to the paper
and ribbon only requires the removal of a cover plate.

FUNCTIONS OF FRONT PANEL SWITCHES

     Figure 12 is an illustration of the front panel of the
Printer/Controller.  The function of the panel switches are as
follows:

                                41

-------
          Serial  Number
                                    Date
          Droplet
          Distribution
          in MICRONS
       Total Number of
       Droplets Counted'

         Elapse Time in_
      Tenths of Seconds

           Velocity in
 .Decimeters per Second

         Temperature in
            Centigrade

      Multiplexer Probe
       being Monitored
                                                Time
SN1.-4/76  11 06 54
  1-1 4M 00710
1.4-1 8M 00881
1.8-2.5M 01416
2.5-3.3M 02827
3.3-4.5M 02099
4.5-6.1M 01010
6.1-8.2M 00507
8 2- 11M 00208
 11- 15M 00137
 15- 20M 00098
 20- 27M 00063
 27- 37M 00032
 37- 50M 00011
   > 50M 00001
'TOTAL    10000
S.T.0.1S 01226
VEL CM/S 00070
 EMP/C   00030
MUXPRB12 00000
Fiaure 11:   Printout Illustration
                         42

-------
            Hrs.  Min.   Sec.
             f^l
   DC-2
   111
   Coru-eclcr
/
2

3
1
           Month
         Day
 MUX
Conn.
   C   A
M    K    MUX
   DC-2
   tt2
Print Mode
       (flight
               o
                   No.  of Runs

                     15   30
                  10         1 Hr.
                  5            2 Hr.
                      Time Int.
                                                SN 1-0^22   11 15 33
                                                    1-1  6M 02 164
                                                  1. 6-2  6M O193't
                                                  2. 6-4  1 M 0 1 2 3 1
                                                  4. 1-6  6 M 01019
                                                  6. 6-10  M 00804
                                                   10-17  M 00791
                                                   17—27  M 00501
     Power     Fuse
     Switch
                                       Start
               Limit Select
                                                                    Paper
                                                                    Feed
               Figure  12 .   Printer Panel Layout

-------
1.   Limit Select switch determines when printer operation
    begins with respect to the Droplet Counter or Counters

    a)   In the £1 position,  the printer is activated
        whenever either one  of the two DC-2's goes into
        HOLD.

    b)   In the $2 position,  the printer is activated only
        when both DC-2's have reached HOLD.

2.   Print iMode Switch - This is a four-position switch
    selecting the following  print mode operations:

    a)   Manual Mode (M) - Each print cycle has to be
        initiated by depressing and releasing Start
        switch.

    b)   Continuous Mode (C)  - Once the print cycle is
        initiated, the printer will operate continuously
        until it is stopped  manually or by the Number of
        Runs switch.

    c)   Automatic Mode  (A) - This mode of operation is
        ideal for long-term  unmanned testing operations.
        After initiating the first print cycle, all other
        print cycles are under the full control of the
        Number of Runs switch and Time Interval switch.

    d)   MUX Mode - Initiation of first print cycle again
        is required and the  remainder is dependent on
        the setting of the Number of Runs switch.  The
        setting of the Number of Runs switch is dependent
        on the Number of Probes being monitored by the
        Multiplexer.  Printout of Probe data will be con-
        tinuous.  Each time  a set of Data is required, a
        new print cycle must be initiated.

3.   Month and Day Switch - The Month and Day information
    which is to appear on the printout must be manually
    set up with these thumbwheel switches.

4.   Number of Runs Switch -  The setting of this thumb-
    wheel switch determines  the number of cycles that
    will be printed out when the Print Mode Switch is
    in Continuous, Automatic  or MUX.
                             44

-------
5.   Time Interval Switch - This switch allows the print
    cycles to be spaced with respect to elapsed time.
    It is functional only when Print Mode Switch is in
    Automatic.

6.   Start Switch - To initiate printer operation, this
    switch must be depressed and released.   The depressing
    of the Start switch will put the DC-2's into the count
    mode and allow them to collect Data.

7.   Paper Feed - To advance paper, depress and hold until
    desired amount of paper has been advanced and then
    release.

8.   Clock Controls - The setting of the Clock Module and
    Display is accomplished by six Front Panel switches.
    Their functions are as follows:

    a)  Hours Set - The setting of the Hour is done by
        depressing and releasing the HRS pushbutton
        until desired hours reading is displayed.

    b)  Minutes Set - Minute setting is done by depressing
        and releasing MIN pushbutton switch until desired
        Minutes reading is displayed.

    c)  Seconds Set - To set the seconds, the SEC push-
        button must be depressed and released when
        desired seconds reading is displayed.

    d)  Reset - By depressing and releasing switch marked
        "R," the Clock Module and Display are set to
        0 hrs., 0 min. and 0 sec.

    e)  Run/Set Switch - This switch prevents the accidental
        changing of the Time while clock is running.  In
        the RUN Position, Clock Set switches are inhibited.

    f)  Run/Stop Switch - Controls operation of Clock
        Module when Run/Set switch is  in the Set position.
                             45

-------
INTERFACING WITH TWO DC-2's

    The Printer/Controller can be used with one or two
DC-2 Droplet Counters.  Figure 13 is a schematic of the
interface hookup o£ one and two Droplet Counters with the
Printer/Controller.  If two counters are connected to the
printer, the outputs of each are distinguished by the
serial number code on the printout.  Each DC-2 functions
separately and independently.

PROBE MULTIPLEXER SYSTEM

    The Probe Multiplexer, when used with the DC-2 and
Printer/Controller, expands the probe monitoring capability
from one to 12 probes.  Selection of probes to be monitored
is done with a 12-position pushbutton Selector Switch.
Only one probe will be able to transmit data to the DC-2
at a time.  The determination as to which probe will be
monitored is controlled by the Selector Switch and the
electronics within the Probe Multiplexer.  When more than
one selector button is depressed, probes are monitored in a
descending order, starting with the highest number probe
selected.

    The data collected by the probe is transmitted to the
DC-2 and then printed out by the Printer/Controller in a
similar manner as described at the beginning of this
section.

    The Probe Multiplexer electronics receives its DC power
from the Printer/Controller via the Probe Multiplexer Inter-
face cable which is supplied with the Printer Interface.
Therefore, any power failure in the Printer/Controller will
cause a loss of power in the Probe Multiplexer.  Once
power has been restored, probe monitoring will again start
from the highest number probe selected.

    Figure 14 is a schematic of the interface hookup of
the DC-2 with the Multiplexer system.
                             46

-------
To Probe -«*-
                       DC-2
                                                         DC-2
                                                         tfl
                                                          D
   MUX
                                                         DC-2
                                                         »2
 Printed
Controller


Interface
To Probe
To Probe   -«-
                      DC-2    jfl
                      DC-2
                                                         DC-2
 D
        Printer/
       Controller
                                                           MUX
DC-2
If 2
           Fiqure  13 .   Schematic of  DC-2 Interface with Printer/Controller

-------
oo
                                    DC-2
                                    To Probes
                                     1-12
                                    MULTIPLEXER
DC-2

ttl
                                                                              Printer/
                                                                             Controller
                                                                        MUX
DC-2
02
               Figure   14:   Schematic  of DC-2 Interface with  Multiplexer  System

-------
                          SECTION 6

                  LABORATORY INVESTIGATIONS
     Extensive laboratory investigations were performed
using the DC-2 and the hot wire probe.  The laboratory
studies concentrated on two main topics:

     »  Calibration Tests
        The objective of this effort was to calibrate the
        DC-2 for a range of operating conditions using
        laboratory equipment.  The procedures and apparatus
        used for these tests are described in this section.
        In addition, several analytical studies were per-
        formed in support of the calibration effort.  The
        most important result from the analytical studies
        was the analysis of the capture size of the wire.

     »  Laboratory Tests with the Impactor
        The objective of these tests was to accumulate
        laboratory data using a Brink impactor and to then
        make comparisons with the measurements from the
        DC-2.   Extensive tests were performed to achieve this
        objective and these tests are tabulated in
        Appendix A along with the test purpose and configura-
        tion of the experimental apparatus.  Again, certain
        analytical studies were performed in support of the
        experimental work.  Both the experimental and
        analytical results are discussed in the following
        section.

CALIBRATION TESTS

     A special apparatus was designed and built by KLD to
perform the calibration of the DC-2.  The approach adopted
for calibration is optical.  As an interacting dronlet makes
contact with the hot wire sensor, it is observed under a
microscope.  A photographic camera records the image of both
the sensor and the droplet.  By adopting this technique, a
permanent record is obtained to study the attachment mechanism
and to provide the calibration data.  Since the interaction
                              49

-------
time is short, an electronic flash is used to stop the motion
at the instant of droplet-sensor contact.  Thus, no appreci-
able shrinkage due to evaporation takes place and accurate
calibration data is obtained.  The duration of the flash is
approximately one microsecond,  which is compatible with the
time a droplet, with a diameter range of interest, moves and
shrinks.  The electronic flash provides a bright background
for the hot wire.  Both wire and droplet appear dark with
sharp boundaries, making a clear contrasting photograph.
Figure 15 shows the arrangement of the main components.  The
camera is a Polaroid with Type 107 film.  Optics capable of
magnifying the subject up to 100 times its actual size were
used.  Magnification limits were set by the length of the
wire (~1 mm)  and the diagonal dimension  (10 cm) in the
photographic plane.  A standard Leitz compound microscope was
used, and the microscope specimen holder was adapted for the
support of the probe.  The micrometric positioning setup was
used to position the sensor in the microscope field.

     Simultaneously, as the photograph of the interacting
droplet was taken, an oscilloscope picture of the electrical
signal was also recorded.  Measurements from each pair of
pictures were recorded, obtaining droplet diameter size in
microns and corresponding peak electrical signal in volts.

     An important aspect of this calibration is the generation
of water droplets.  A variety of devices were investigated to
create water droplets within the diameter range of interest.
The ideal droplet generator should provide a monodisperse
aerosol of adjustable droplet sizes.  Instruments with these
characteristics are available,  but their cost and complexity
do not always justify their use.  Therefore, KLD designed and
constructed a cost-effective device capable of generating
droplets using a compressed air-driven spray.  Droplet dia-
meter sizes were controlled by adjusting the pressure; low
air pressure emphasizes large droplets while high pressure
creates a fine mist or small droplets.  In order to measure
the electrical signal peak amplitude over the wide random
range of droplet sizes, a two-beam scope was used with a
different gain for each trace.

     The sensor was mounted ?way from the. apparatus creating
the spray (within 1 foot) so that one interaction  every few
seconds was obtained.  This period between  droolets  allowed
time for setting  the calibration anoaratus  and  avoided  multiple
droplet interactions.
                              50

-------
   Film
  Holder
     Photographic

         Camera
O
— Probe
           Electronic
              Flash
                                                               r
                                                                         =0
                 o
             Figure l.r>:   Droplet Calibration Apparatus

-------
Temperature Calibration

     The temperature calibration was performed by immersing
the sensor in water with temperatures ranging from melting ice
to boiling water.  A precision mercury column thermometer was
used as a control.  Temperature readings were displayed on
the front panel of the DC-2.

     An important condition to be satisfied when using the
sensor as a thermometer is that the electrical current should
only heat the sensor negligibly.  On the other hand, such
current is necessary to operate the Wheatstone bridge which
measures the temperature.    (A large current improves the sig-
nal-to-noise ratio of the electronic circuit.)  The effect of
sensor self-heating was investigated by repeated measurements
with several gas velocities.  The temperature reading should
remain independent of gas velocity.

Gas Velocity Calibration

     The calibration of the DC-2 operating as a hot wire
anemometer was performed with the use of a Thermo System Cali-
brator Model No. 1125.  This instrument generates a turbulence-
free flow whose velocity may be controlled to 1%.  Additional
equipment required for this measurement consisted of a micro-
manometer for the measurement of the decrease in pressure
across the calibrated orifice, a mercury thermometer to
correct the flow for temperature difference, and finally a
supply of compressed air.

Analysis of Capture Area

     As presented in the Data Analysis of Section 5, the drop-
let concentration, nj_, corresponding to the itn interval can
be computed with the expression:

               Ni
     ni = —.  o ," ,  -M          (i = 1,14).
      1   v t • H (Dj_+d )

     The denominator in the equation represents the volume
sampled and is based on the assumption that all sizes of
droplets have sufficient inertia to maintain a linear trajec-
tory.  This assumption, however, may not be accurate for
particles smaller than the diameter of the wire.  Flow prob-
lems of this type have been investigated in aerosol filtra-
tion  (Ref. 2 and 3)  using a two-dimensional analysis for the
                              52

-------
flow past an infinite cylinder.  Although  an  exact  descrip-
tion of the stream lines and droplet  trajectories is  not
possible, the interception mechanism  can be evaluated for
limiting cases.  As a convenience in  the analysis,  the non-
dimensionalized capture size function,  f,  is  defined  as

          Sampled Volume = vtfcd • f (Dj_d) .

Then, with the streamlin.es  characterized  by  the Reynold
Number based on the wire diameter  (i.e., vd/v) , the capture
size of the fiber can be determined.   Inertial  impaction occurs
because the droplet deviated from the  fluid motion  in
accordance with Stokes1
fluid; namely,
                        Law for a sphere  in  an  unbounded
          stk
                  = v _
where
                  v
                 w
          Stk -
            v = flow velocity

            t - dimensionless  time  =  time multiplied by —
           UD = particle velocity.

Some limiting solutions of the foregoing  equation are  tabu-
lated below and provide insight into the  capture size  func-
tion, f(Did), when normalized by  (l+Dj_/d).
     Flow Condition

1)  Stk -»- ~
   Particles follow a straight
   trajectory
2)  Stk =0;  no particle inertia

   a)  Potential flow
   b)  Oseen flow
                                   f (Dj_ , d ) / (l-f-Di/d
                                 1 -
                                      ll+Dj/d)2

                                         Di

                                         T2(lp/)'
                                    2.002 - In  (Re)
                             53

-------
     In Figure 16, the capture size function is plotted as a
function of the dimensionless droplet size.  For the case of
Oseen flow, the Reynold Number is assumed to be 0.3.  For
small droplets (Dj_/d10ym.   For small droplets between 1 to 10 ym, the more
complicated expressions for f(Dj_,d) should be used.

     For the experimental studies performed in the  laboratory,
the number of droplets below 10 ym was large and KLD applied
the modified values of the capture size function to the
measured data.  The effect of the capture size function on the
final experimental results is discussed in the next section.

LABORATORY TESTS WITH THE I.M.P ACTOR

     As reported in Appendix A, a large number of experiments
were performed in the laboratory during the period  from
June to December 1977.  The objective of this work  was to
accumulate data and to compare measurements made with the
Brink impactor and the DC-2.  Once the experiments  were
initiated, a secondary objective emerged; namely, to better
understand the flow behavior in the impactor and its effect
on the measured data.  Several qualitative experiments were
performed  to accomplish the secondary objective.

     To minimize measurement error, a closed system with a
steady flow was used in the laboratory  (Figure  17).  The
droplets were generated using a rotating disc, and  the speed
of the disc was carefully controlled with an optical tacho-
meter.  Several designs-of this droplet generator were
developed  and refined to achieve the required stable droplet
distribution.  The final design utilized a small volumetric
pump with  a controlled motor speed to continuous!/  pump the
liquid to  the center of the rotating disc.  As shown in
Figure  17, the rotating disc was enclosed in a plastic box.
This approach provides a reliable and rep^atable source of
entrained  droplets.

     The droplets were entrained in the flow and drawn through
the impactor using a peristaltic pump with a stable but
adjustable speed.  The  flow was monitored using a calibrated
orifice and manometer.  Most of the experiments were performed
with a flow rate of  .03 cfm  (.85 liter/min) for which a sub-
stantial amount of calibration data is available for the
                              54

-------
                Stk -»•
                Potential flow Stk = 0
                Viscous flow Stk =0, Re = .3
Figure  16:  Capture Size vs. Dj/d
                              55

-------
CTl
                                               I' r i.11 t:o r/Coi i L ro 1 br
                                                                    A
                                    IZZH3
                                    LX'-2
                               Caljbratcd
                                 Ori flee
                         pump  ^-=
             I	i.	!..
            DC- 2
l!ni|).'.ictor
                                           Probe
                                          ManoineUer
                                                                   Probe     Pl.ow
                                                                                      Spray
                                          Ficjurc  -1-7:  l.al^oratory Set-up

-------
impactor.  Other flow rates were used to investigate the
effect of flow velocity on the measurements.

     The impactor was operated with a cyclone and one to five
stages, depending upon the type of experiment.  Instead of
using the stainless steel targets of the standard impactor,
aluminum foil cups were used as targets.  This approach
simplified the procedure and increased the accuracy of the
measurement.  The aluminum foil cups were especially useful
for the fourth and fifth stages of the impactor when the
operating time was less than 20 minutes.

     Depending upon the type of test, measurements with the
DC-2 were performed upstream (A) and/or downstream  (B)  of
the impactor  (Figure 17 ).  The DC-2 data was automatically
recorded using the Printer/Controller described in Section 5.
For this application,  a special hot wire probe was designed
and built as an integral part of the 4.8 mm diameter glass
tube, which v.'?.= placed in the flow line.   The hot wire was
mounted perpendicular to the longitudinal axis of the tube to
achieve a well defined flow condition about the wire.  For
the prescribed flow conditions  (.85 liter/min), the air
velocity at the probe was .73 m/sec.

Experimental Procedure

     To obtain the desired accuracy in the data, careful
laboratory procedures had to be established early in the test
program.  The sources of data scatter had to be identified
and, where possible, techniques used to minimize the errors.
For example, the system was operated with pure water or a 10%
NaCl solution.  The tests with pure water identified some
sources of measurement errors in the impactor.  For example,
the DC-2 at location A indicated a stable droplet distribu-
tion, but the impactor results were erratic.  The length of
the sampling time has a pronounced influence on the measure-
ments with the impactor, and the scatter of data was found to
be unacceptable.  These problems were attributed to evapora-
tion and/or condensation taking place at various points in the
impactor.  Because of these problems with the impactor, the
quantitative studies with pure water were discontinued early
in the research.

     The impactor measurements with a salt solution were more
dependable, but still exhibited scatter  (see Discussion of
Results).  To control the scatter in the data, carefully

                             57

-------
controlled techniques for measuring the samples at each
stage were used.  As mentioned above, small aluminum foil cups
provided better accuracy and convenience when  weighing the
samples at each stage.  As a check upon the data, periodic
measurements of the accumulated liquid were made and the
evaporation history in the ambient environment was plotted.
This procedure supplied data with respect to the total amount
of liquid collected per stage when the test was completed but
before the samples were dried and weighted.  Such measure-
ments were used to verify the data obtained from the dried
sample of the NaCl residue.

     Depending upon the number of impactor stages, a "time
delay" was observed as the impactor achieved steady-state
conditions.  After the initial period of approximately
45 minutes, the measured droplet distribution became stable
within ±10%. Numerous tests were performed to understand this
phenomenon and develop acceptable experimental procedures.
The "time delay" effect is attributed to the condensation/
evaporation phenomenon occurring inside the impactor.

     Also, a procedure had to be established with respect to
the total sample period for a generic experiment.  Again, a
series of tests were performed to establish this methodology,
and a sample period of 20 to 40 minutes was used for the
majority of the experiments.

     The performance and data analysis with the Brink
impactor was based upon the best information available.
Efficiency curves, which accounted for wall losses at
different stages, are given in Table 8 of Reference 4, and
the cyclone efficiency curve appears as Figure 24 of
Reference 5.  These two reports are based upon a particle
density of 1.35 gm/cm3 and 1.0 gm/cm3, respectively.  For
the present study, the 10% NaCl solution has a density of
1.05 gm/cm3 approximately.  The values of 050 used in this
study have been properly adjusted for any differences in
density.  Moreover, the diameter of each impactor nozzle was
measured carefully to be sure that it was within the tolerance
of the published value.  The DSQ for the present study is
given below in  Table  5.
                             58

-------
             Table  5:  059  for  Brink  Iinpactor at
                      .85  liter/min  Flow  Rate, 22°C,
                      751.84 mm Kg and Particle
                      Density  1.05 gm/cm3
                 Stage        050

                Cyclone      17.00 urn
                   1         5.27 ym
                   2         3.61 urn
                   3         2.29 urr.
                   4         1.07 urn
                   5         0.74 urn
     The DC-2 was operated in  the standard manner.  As
expected, salt accumulated on  the hot wire, and after several
minutes of continuous operation, the response of  the instru-
ment would degrade.  To define a convenient sampling time,  the
instrument was operated for various periods.  Based on  these
tests, a sampling time of approximately  100 seconds was
adopted for the DC-2.  With this procedure, the effect  of  the
salt accumulation was negligible.  It was also observed  that
by leaving a contaminated sensor in the  flow, a self-cleaning
action occurred when the sensor was cold.  With a  time  delay
of five minutes between sample periods of 100 seconds,  the
response of the sensor was unaffected and the probe was
seldom replaced.

Discussion of Results

     The results from the laboratory tests permit  a direct
comparison of droplet number and volume distributions as
obtained with the Brink impactor and the DC-2.  In addition,
extensive data was accumulated with respect to the operating
characteristics of the impactor.   In this subsection both
these topics are discussed.

     The experimental data consistently shows that the
measurements with the DC-2 were lower than the impactor
measurements in the region from  1 to 10 ym.   Some of the
difference in the measurements can be attributed to the
aerodynamic influence on the capture size of the wire as
discussed under the Calibration Procedures.   In addition,
tests were indicative of condensation occuring in  the impactor.

                              59

-------
However, it is not possible to quantify completely  all  the
effects which contribute to the differences  in  the  measure-
ments, nor was such a quantification within  the  scope of  the
present research.

     To achieve a meaningful comparison of the  data from  the
many tests, KLD examined approximately four  similar experiments
with the impactor and averaged the results for  each impactor
stage.  The simultaneous measurements with the  DC-2 for
each experiment were average for each of the  14  size intervals.
All of this data in the form of a number concentration, ~,
was plotted as a function of droplet diameter.   Then an
equivalent factor, K, was defined as
      K =
          n-for Impactor
          r\i for DC-2
The computed values of K are tabulated below:
Inter-
 val
 No.
  1
  2
  3
  4
  5
  6
   Size
   Range
 1  - 1.6
1.6 - 2.6
2.6 - 4.1
      6
     10
4.1
 6
10  - 17
Ratio of
.Impactor
to DC-2
5.0
2.8
2.0
1.6
1.2
1.0
Kaero
Aerodynamic
factor
2.5
1.8
1.2
1.0
1.0
1.0


AK=K-Kaero
2.5
1.0
0.8
0.6
0.2
0
     As shown, the values of K approach one after  the  fifth
size interval.  The factor, K, includes the aerodynamic
effect on the capture area.  The aerodynamic  effect  can  he
computed and is represented by the column  labelled Kaero
in the above table.
been tabulated.
          The  difference  AK-K-Kaero has also
                              60

-------
     The tabulated values of K were applied to various sets
of experimental data to demonstrate the consistency of
results.  In Figures 18 and 19, the results from two
experiments are compared.  The dashed curve represents the
measured number concentration with the impactor whereas the
solid curve is for the DC-2 data after the factor K is ap-
plied.  A similar comparison is shown in Figures 20 and 21
for the results in terms of the accumulated volume concentra-
tion .

     The foregoing curves are in acceptable agreement and the
results from the two techniques of measurement can be related
using an equivalence coefficient, K.  It should be emphasized
that the agreement emerged only after very careful laboratory
work to minimize data scatter and by averaging results from
several tests.

     During the experimental work, theoperational characteris-
tics of the impactor became evident and it is worthwhile to
document some of the observations for the benefit of other
researchers.  Although the Brink impactor has been evaluated
on a theoretical basis by others and can be calibrated using
known solid particles, its use for entrained liquid droplets
is based upon assumptions which may not be justified.  The
complex flow at various stages can result in condensation or
evaporation depending upon the operating environment.   During
many tests, the collection of significant amounts of liquid
on the walls of the impactor was observed.  These problems
can cause scatter in the data and control of the scatter is a
difficult t a •"?]•: in the laboratory and certainly more difficult
in the field.   If the liquid is without trace elements, the
measurements with the impactor are significantly less
reliable and of little quantitative value.

     A typical example of the scatter in the laboratory data
is shown in Figures 22 and 23  for stages 1 and 3.  In each
diagram, the weight of the dried NaCl residue is plotted as
a function of sampling time.  In theory, the accumulated
salt should be a linear function of the sampling time.  For
stages 1 and 3, there is an obvious increase in the accumu-
lated salt with time, but the slope of this curve cannot be
accurately defined.  Several attempts were made to provide
better insight into the data.   For example, all the tests on
a particular day with known environmental conditions were
grouped and studied. - Unfortunately, this grouping tended to
reduce the scatter at some stages but not at all stages.
                              61

-------
                                             KEY:
10 r
 4 .
0
CP
c
a:
01
E
5

0
^
0
a
, — >
o
>
3


2

1Q3!
Q 1
8
7
6
5
4

3
101
                                                    Impactor
                                                    DC-2
Figure
                         456
                            Diameter (ijm)
                                                   10
                                                    11
18 •
Average  Number Concentration for  Irnpactor and
the DC-2  Data  (Test  Mo.  216)
                                62

-------
                                       KEY:
                                          —  impactor
                                             DC-2
I
4567
  Diameter (urn)
                                                         10
11
Figure 19:.  Average Number Concentration for  Impactor and
           the  DC-2 (Test No.  212)
                             63

-------
 e
 o
 c

 ,H
 0


 JJ
 c
 1)
 e
 E
 •r-l
c
cu

0)
>
•r-l
4J
(3
.— !
3
c
5
o
IS3
                                       KEY:
                                          •—  Impactor

                                             DC-2
                           4567

                             Diameter (in u)
                                                         10
11
     Figure 20 :   Cumulative Entrainment Volume for  Impactor

                  and the DC-2  Data  (Test  No.  212)
                                 64

-------
u
c
5
0)

3
r-l
0

4J
c
0)

c
4J
c
u

0)
3
E
3
U
10s
 9
 8
 7
 6
 5

 4

 3
  ICT
                                       KEY:


                                      _..«. _. Impactor

                                      	 DC-2
 i     i
4    5
 Diameter
                                                              I
                                                             10
                                                               11
     Figure  21:   Cumulative Entrainment Volume  for Impactor  and
                  the  DC-2 Data  (Test No. ?U',)
                                  65

-------
       6.0-1
       5.5-
       5.0-
       4.5-
Salt
Weight
(mg)
       4.CL
3.5_
       3.0-
       2.5-
       2.0-
       1.5-
       i.o-
       0.5-
       O.C-
          0
               20
~r
 40
                                     	T
                                      60
                                                         ~T~
                                                         80
                              Time (Mins.)
         Figure 22:  Salt Collected on  Stage  1
                               66

-------
      o.io-
      0.09 -
      0.08-
      0.07-
      0.06-

Salt

Weight o.o5-
(mg)


      0.04-
      0.03-
      0.02-
      0.01-
      0.00.
                      I
                     20
40         60
 Time  (Mins.)
 I
80
            Figure 23:  Salt Collected on  Stage  3
                            67

-------
     Several experiments were performed with the Brink impac-
tor inside the box where the droplets are generated.  This
approach was adopted with the assumption that scatter would be
minimized if the impactor is in equilibrium with the sample
flow.  It should be emphasized that the procedure was equiva-
lent to the field practice of placing the sample train in the
flow for long "soaking" periods.  The results from these ex-
periments were disappointing since no appreciable reduction
in the scatter was observed.

     KLD performed several experiments to gain better insight
into the phenomenon causing data scatter.  A glass tube was
constructed to resemble the impactor, and by visually
monitoring the flow inside the tube, varying conditions of
evaporation and/or condensation were observed.  When the two-
phase flow was introduced into the tube, wall condensation
was very evident.  The condensation on the wall could be
correlated with the droplet distribution at the outlet of
the tube.  The distribution at the outlet did not stabilize
until the condensation on the walls achieved a stable condi-
tion.  If a light source is placed near the tube (causing an
undetectably small temperature difference),  the condensation
phenomenon was greatly altered with evaporation on the side
exposed to the light and condensation on the diametrically
opposite side.  These qualitative experiments demonstrated the
sensitivity of the internal flow to extremely small changes in
wall conditions.  Further study to quantify this effect is of
interest and possible, but such an effort is beyond the scope
of this project.

     Analytical Considerations

     Several analytical studies were undertaken in support of
the experimental effort. . The objective of the studies was to
provide additional insight into the thermodynamic and aero-
dynamic conditions in the impactor.  The procedures used for
the studies are briefly reviewed in this subsection.

     An idealized pressure and temperature distribution in the
impactor can be determined using a one-dimensional flow
theory for a compressible, isentropic flow.  The temperature
and pressure ratios at a cross section with velocity, v, are
given by
                               68

-------
                                -i
where  A is ratio of specific heat  (A ~ 1.4)
       M is the Mach number
      To is the stagnation temperature
      Po is the stagnation pressure.

     These equations are used to obtain the idealized pressure
and temperature conditions in the impactor for a given set of
nozzle geometries.  The nozzle dimensions, the jet velocity
at each nozzle exit, as well as the pressure drop are pre-
sented in References 4 and 6.  For  r.he Brink impactor, these
parameters are given in Table 6 for stages n tnrouah 6.

     The resulting temperature and  pressure distributions are
given in Figures  24 and 25.   The first three stages, which
have a jet velocity less than 10 m/sec, show negligible
temperature and pressure drop.  Temperature difference of
0.5°C to .'. .5°C and pressure drop of 3 to 17 mm.Hg are found in
stages 4,  5 and 6.

     A second analysis was used to  qualitatively describe the
growth or reduction in droplet size.  It is well known that
aerosol particles, when in supersaturated atmosphere, may act
as nuclei, enhance condensation and growth.  A droplet passing
through an impactor undergoes a similar process.  In theory,
droplets may grow or shrink inside  an impactor.

     A complete analysis on the history of a droplet passing
through an impactor could be achieved numerically.  However,
such a complete study was not undertaken during this contract.
Rather, an idealized and simplified model was used for the
condensation/evaporation rate of droplets in the impactor
environment.

     For a spherical motionless droplet, assuming stationary
condensation/evaporation and ideal  behavior of the vapor, the
rate of change of the droplet radius can be described by
[Maxwell's equation:
                               69

-------
              TABLE  {•




  Cascade Impactor Stage Parameters




Modified Brink Model B Cascade Impactor
Stage No. of
No. Jets
0 1
1 1
2 1
3 1
4 1
5 1
6 1
D.-Jet
Diameter
(cm)
.3598
.2439
.1755
.1375
.0930
.0726
.0573
S-Jet
to Plate
Distance
(cm)
1.
0.
0.
0.
0.
0.
0.
016
749
544
424
277
213
191
S
D.
3
2
3
3
3
2
2
3
.02
.07
.10
.08
.98
.93
.33
Reynolds
Number
326
481
669
853
1263
1617
2049
Jet
Velocity
(m/sec)
1
3
6
9
21
35
58
.4
.0
.0
.7
.2
.3
.8
Cumulative Frac-
tion of Impac-
tor Pressure Drop
at each stage
0
0
0
0
0
0
1
.0
.0
.0
.0
.065
.255
.000

-------
   -5
tt,
  -10
        Stage 1
        •~T~~
Stage 2

   f~~
 Stage 3
—4—
Stage 4
          Y
 Stage 5
\



    f
Stage 6
                                                                                              Outlet
                                                                             'N
                                                                                \
                                                                                  \
                                       \
                Nozzle outlet of previous stage
                                                          H
                              10
15
                                   20
                                  25
                                                                                    30

                                                                                               \
-15
r ~~i 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 c -P .9 I
1 -H U 1
1 	 ' 1 0( l/> ',
L . c £ vt \
lit | | t 1 1 t 1 r-^->> M M < 1
r\ W a) fljr-itN n^a1 mvD'b-P
J\. II C tj> Q) (U
rH -*ty O m (U QJ i 4J4J4-)4-)-M4JT)O
2CJ-oWWWWWWs
(U . 	
f
i i i i i i |l
                                                                                            x(cm)
                                               35
     Figure 24:  Pressure drop along the impactor (760 mmHg  is used as  inlet pressure)

-------
    0	,
  - . 5-
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  -1.5-

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          5           10            15         ^"20

Figure  25.  Temperature drop along the  impactor. (20
                                                                      25    i       30

                                                              °C is used as inlet  temperature)
x (cm)

-------
                 dr
                 dt

 r =
 t =
 D =
 M =
PL =
 R =
P  =
where  r = radius of the droplet
           time
           vapor diffusivity
           molecular weight of the vapor
           density of the droplet
           ideal gas constant
           vapor pressure at the drop surface calculated
           from the drop temperature
      POO = vapor pressure in the air stream.

     By assuming Pco-P0 = 0.1 mmHg , the rate of change of the
droplet radius, dr/dt, for typical conditions is given in the
following table.  As shown, dr/dt is most significant for
small droplets.
           Table V:   Rate of Change in Radius for
                     Water Droplets at 293°K and
                     POO-PQ = 0.1 mmHg
                   0.25
                   0.50
                   1.0
                   2.5
                   5.0
                  10.0
                              dr  ,   i   -.
                              —  (urn/sec)
                           11.40
                            5.72
                            2.86
                            1.14
                            0.56
                            0.28
     The evaporation of small droplets in a saturated atmos-
phere was also investigated.  The vapor pressure on the surface
of a droplet of radius, r, is given by Kelvin's equation:
                r
               -— = exp
                         'RTpLr'
where a = surface tension.
                              73

-------
     The evaporation effect on dr/dt can be calculated
accordingly.  The supersaturation ratio, Pr/Poo/ for various
values of r is given in Table 7 and dr/dt at 293°K is pre-
sented in Table 8.  Again, the small droplets have the most
significant rates of change.
          Table R:  Supersaturation Ratio, Pr/Poa,
                    for Water Droplet at 293°K
                    r (ym)
Pr/pc
0
0
1
2
5
10
.25
.50
.0
. 5
.0
.0
1.
1.
1.
1.
1.
1.
0044
0022
0011
00044
00022
00011
          Table 9:   Rate of Change in Radius
                    Water Droplet at 293°K
               for
                    r (urn)

                     0.25
                     0.50
                     1.0
                     2.5
                     5.0
                    10.0
 dr  .   .   .
"7T  (ym/sec)
 dt
9.
2.
0.
0.
0.
40
36
59
094
0236
  0.0059
     The above calculations are based on the assumption that
the droplet is pure water and Maxwell's equation applies.
Theoretical consideration on the concentration change at  the
surface of the droplet as well as the evaporation/condensation
constant lead to
                              74

-------
                 dt
 MD
PLRT
D
                                  .rva
                                       + 1
where a = evaporation/condensation constant for a liquid

            RT
                =  1/4 of the mean absolute velocity of
                   the vapor molecules.

     For pure water,  a = 0.034, and the above equation gives
a smaller value of dr/dt than obtained from Maxwell's equation,

     Hence, the evaporation or growth of droplets in the
impactor appears possible for the small droplet sizes (D<10um)
and may account for the sensitivity of the impactor data to
environmental conditions.  These studies did not include the
influence of the walls as condensation surfaces nor the
effect of re-entrainment of droolets from wet surfaces.
                              75

-------
                          SECTION 7

                        FIELD TESTING

     An important objective of the research effort was to
demonstrate the use and suitability of the DC-2 under field
conditions.  In all, four different sites were used in the
demonstration.   At the Shippingport Power Plant, which has a
limestone scrubber, data was obtained with the DC-2 and was
to be compared with impactor data measured by an independent
source.  Unfortunately, the impactor data is not available
and the comparison cannot be reported.

     For each site, a test report was prepared and submitted
to the EPA Contract Monitor.  In this section, the results
from each site are summarized.

COLBERT PILOT PLANT
     A schematic of the demister scrubber at the Colbert
Pilot Plant in Muscle Shoals, Alabama is shown in Figure 26.
It consists basically of a duct where the flow carrying SO2
interacts with water within a prescrubber-demister .   The
scrubber injects saturated ammonia and the resulting droplets
are recovered in a demister.  This flow is created by means
of a centrifugal pump installed in the stack.

     A total of 1260 measurements were performed at the four
available ports shown in Figure 26.  The ports and the
corresponding number of measurements taken are:
         Port
A. Prescrubber-Demister Inlet
B. Prescrubber-Demister Outlet
C. Exit Demister-Inlet
D. Exit Demister-Outlet
                                        No. of Measurements

                                                  315
                                                  314
                                                  316
                                                  315
     Each measurement includes gas temperature, flow velocity
and droplet size distribution.
                               76

-------
                                   Exit
                                 Demister
Prescrubber
H

S0^~

2


0


Section
1
1
I A Prescrubber ^
Section
1C D l
10 0
1 1 It




Flow



M»—
| >•' Demister ^ Scrubber
I Inlet Outlet
i 1
1
1
|
r




Inlet i




Outlet
Sulfates
	 and
Bisulfate










Bx-|


                      Saturated
                       Ammonia
                        Water
Stack
Figure 26  :   Schematic of  the  Demister Scrubber  at
             the  Colbert Facility
                        77

-------
     Most of the measurements were performed with one probe
so as to monitor any degradation of its performance due to
the accumulation of contaminants.  The only detected
accumulation was crystals of ammonia sulphate.  A periodic
cleaning of the probe after 15 minutes of operation was
required for proper measurement.  Crystals of ammonia sulphate
are highly soluble in water, so that the sensor was cleaned
simply by immersing in tap water for a few seconds.

     For the performance of a single measurement  (a total of
1000 droplets)  the time limit was below 100 seconds, assuring
negligible deterioration of the sensor during a single
measurement.  The measured droplet distributions are presented
in Figures 27,  28, 29 and 30.

WATER TREATMENT PLANT IN NEW YORK

     Field testing at the New York site was made within a
demister located at the exhaust of diesel engines operating
with either fuel oil or methane.  At the site, a scrubber was
used to clear, the exhaust gas of odors and carbon particles.
The function of the demister was to capture water droplets
after the scrubbing action took place.

     A cross-section of the demister is shown in Figure -1.
Several thousand measurements were performed at this facility.
The main emphasis was to test the DC-2 viorformance under field
conditions rather than to evaluate the facility.  It was
observed that conditions at the facility changed with time.
Furthermore, the spinner caused localized conditions in the
flow.

     The measurements with the various instruments, i.e. one
prototype unit and two deliverable units were performed
simultaneously by locating their respective probes as close
together as possible.  Measurements were taken over the cross
sections at various vertical locations with the sensor placed
perpendicular to the flow.  The three instruments produced
results which are all rather similar.  Differences, when
present, may be traced to either spatial or time fluctuations.

SHIPPINGPORT POWER PLANT

     Field tests at Shippingport, Pennsylvania were made in
the demisters which are located at the exhaust of the coal-
fired power plant.  The droplets were generated by venturi
                             78

-------
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                           i

                           8
           10    12    14   16    18

           Droplet Diameter (ym)
20
22
24
        Figure  27:
Distribution at the Prescrubber Demister Inlet

Colbert  Plant
                                   79

-------
  1000-
  100
 e
 3.
<*i
 c
 O
 X.
 3 10
 o
 (—

 8
                                      I
                              4        56
                              Droplet Diameter  (ym)
               Figure 28  :  Distribution at  the  Prescrubber

                           Demister Outlet, Colbert Plant
                                   80

-------
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         Droplet Diameter (ym)
Distribution  at the Exit Demister  Inlet

Colbert Plant

-------
100
  10
e
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      Droplet Diameter  (\J.m)



Distribution  at the  Demister Outlet

Colbert Plant
                                   82

-------
                 De-entrainment
Spinner
Liquor
 Inlet
            Figure 31:  Demister Cross Section at the
                        Treatment Plant in tfantagh,
                        New York
                            83

-------
scrubbers and the liquor contained limestone in suspension
to remove the major pollutant, S02-  One double demister and
one single demister were investigated.  The survey was made
downstream of the demister and covered the entire cross
section of the duct.  Six access ports were available for the
measurement.  The cross section of the duct and location of
the survey points are shown in Figure 32 .

     The most serious problem encountered, during the field
work was the contamination of the sensor because of the
accumulation of limestone on the hot-wire probe.  This con-
tamination problem was overcome by inserting the probe into
the c.uct only when the DC-2 was actively taking data and by
choosing the measuring time to be as short as 10 seconds.
Temperature, flow velocity and droplet concentration were
within the expected range of operation at the facility.

     Large fluctuations were observed in the operating
conditions of the demisters.  The fluctuations are inherent
to the operation of this type of demister and extend for
periods of minutes.  Based on this observation,  average.
values of the various measurements were used for the
computation of the results.

     The average number and volume concentration for the
single demister and double demister are presented in
Figure 33 and 34.  The single demister has a larger droplet
concentration than the double demister, as expected.

COOLING TOWER OF THE HIGH FLUX BEAM REACTOR AT BROOKHAVEN
NATIONAL LABORATORY

     The objectives of this field test were to demonstrate:

    •  the DC-2 Droplet Counter connected with the
       Multiplexer and Pr i.nter/Controller .  Four
       multiplexer probes were used in these
       experiments:

    •  two DC-2 Droplet Counters interconnected with the
       Printer/Controller.

     For both types of experiments, all of the data was
recorded using the automatic mode of the Printer/Controller.
The equipment arrangements for the two configurations are
shown in Section 5 of this report.
                              84

-------
Port
         6     5
                               2      1
                      B.	S.
.1
                   2'
                            11  —»!••	 i > 	14»—^ J. '
                           12
         XX        X       X       XX
XX        X       X       XX
         XX        X       X       XX
                                                     12'
 Figure 32 :  Test Section of a Duct at Shippingport,
             Pennsylvania
                       85

-------
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P
5
.-i
o
!M
O
f±

m
4-1
0)
o
!M
Q

u-i
0
.5

cj
2
     10
     10 !
     10
     10
     10
     io~J-
                                                              1
   Fioure  33:
                              10                    100            500
                           Drop  Diameter,( urn)
                Average Number Concentration  for  the

                Demister  Sections at  Shippingport,  Pennsylvania
                                   36

-------
                                                        O
     "
                                                0
                                                    °
                                                                   0
                                           O
                                                            9
                                       o
o
• H
13
l-i
jj
•H
JJ
fu
r-H
3
C
3
CJ

01
en
       9
       8
       7
       6
       5
       a
                               o
                                       O
                                         OSingle Demister
                                         ©Double Demister
                       0
                  0
                          o
              o

    10
                            I
                           10
                                               100
                            Drop Diameter, urn
                                                                    1000
       Figure 34:
                   Average Cumulative Entrainment Volume  as  a
                   Function  of  Diameter for  the Demister Sections
                   at Shippingport,  Pennsylvania.
                                    37

-------
     The droplets were generated from domestic water with
a maximum of 1 PPM chloride chemical added for maintenance
purposes inside the cooling tower.   The survey covered several
radial cross sections in two of the five exhaust cell units.
The investigation included measurements with the exhaust fan
on and off during the test.

     The entire test program required approximately two hours,
but had to be scheduled over two days because of weather con-
ditions.  Measurements were taken automatically every five
minutes and were printed out by the Printer/Controller.
Throughout the testing, all equipment operated properly.
No probe breakage occurred and no contamination was detected
either by the operation of the instrument or by observing
the sensors under a microscope.  Typical results are given
in Figure  35 and 36.   It is found that both number and volume
concentration are dominated by drops smaller than 30 ym.
                              88

-------




^.
n
O
"e
o
""
0
D
O

C
0
E
C
••H
C
H
0)

.,-j
-U
(3
rH
D
£
5
CJ
0) )
0
^



10-7
9
8
7
6
5

4

3


2




10-8
9
8
7

6
5


4
3

2

ID'9

—
—
—
O O O
o

—
o

'

—
0



— 1





I o


•M
•^* i


o
1
1 I 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1
                    4  5  6  7 89 10      20

                          Droplet Diameter  (ym)
40
60  80 100
Figure 35:  Average Cumulative Entrainment Volume as a
           Function of  Droplet Size in  the Exhaust of the
           Cooling Tower  at  Brookhaven  National Laboratory
                            89

-------
 £
 U
    103
    10  -
 01

 I  101
 OJ
 c
 5
 •H
 i->
 5
 o
 u
 a
 I ID'2
 e
     -3
   10
Figure
                                10
                           Droplet  Diameter
                                                100
                               jm)
Droplet  Number Concentration Measured  in the
Exhaust  of  the Cooling tower at Brookhaven
National Laboratory
                               90

-------
                         REFERENCES
1.  Medecki, H., Kaufman, M.,  and Magnus, D., "Design,
Development, and Field Test of a Droplet Measuring Device,"
EPA-650/2-75-018, U.S. Environmental Protection Agency,
Research Triangle Park, N. C., 1976.

2.  Fuchs, N. A., "The Mechanics of Aerosol," MacMillan
Company,  1964.

3.  Davies, C.  N.,  "Aerosol Science," Academic Press, New
York,  N.  Y., 1966.

4.  Gushing, K. M.,  Lacey, G.  E., McCain, J. D. and
Smith, W. B., "Particulate Sizing Techniques for Control
Device Evaluation:  Cascade Impactor Calibrations,"
EPA-600/2-76-280, U.S. Environmental Protection Agency,
Research Triangle Park, N. C., 1976.

5.  Smith, W. B., Gushing, K.  M. and McCain, J. D.,
"Particulare Sizing Techniques for Control Device Evaluation,"
EPA-650/2-74-102, U.  S. Environmental Protection Agency,
Research Triangle Park, N. C., 1974.

6.  Harris, D.  B.,  "Procedures for Cascade Impactor Calibra-
tion and Operation in Process  Streams," EPA-600/2-77-004,
U. S.  Environmental Protection Agency, Research Triangle
Park,  N.  C., 1977.
                              91

-------
                         APPENDIX A
               TABULATION OF LABORATORY TESTS
     Over the period from June 30 to December 28, 1977,
approximately 160 experiments were performed in the KLD
laboratory using the Brink impactor and the DC-2 to measure
droplet concentration.  In Appendix A, these tests are
summarized in tabular form.

     For each test, a purpose number is assigned in the
table.  The definition of each purpose number (P.I...P.21)
is presented in tabular form at the end of this section.
Each test is further described by referring to a configura-
tion  (C.1...C.29) which is defined by the sketches appearing
in this Appendix.  For example, configuration C.5 consists of
a Brink impactor with a cyclone and three stages and a DC-2
probe located at the exit from the impactor.

     The only other tabulated parameter requiring explanation
is the flow rate, which is given in inches of water.  This
pressure drop is across a calibrated orifice and the flow
rate is obtained from the following equation:

                  AP = CO2

where  AP = pressure drop

        Q = flow rate

                 (cm of H20)  _      (inch of H20)
        C ~   UJ (liter/min)2   22^    (ft
                              92

-------
No.  of
                   Flow
                   Rate
Droplet  Liquid  (inch of  No. D.C.
 Total
 Test
Period  Purpose
Test
101

102

103

104

105

106

107

108

109

110

111

112

113

114

115

116

117

118

119

Date
6/30/77

6/30/77

6/30/77

6/30/77

6/30/77

6/30/77

6/30/77

6/30/77

6/30/77

6/30/77

6/30/77

6/30/77

6/30/77

7/1/77

7/1/77

7/1/77

7/1/77

7/1/77

7/1/77

Conf ig.
C.I

C.I

C.I

C.I

C.I

C.I

C.I

C.I

C.I

C.I

C.I

C.I

C.I

C.I

C.I

C.I

C.I

C.I

C.I

Counter
DC- 2
SN-1
DC- 2
SN-1
DC- 2
SN-1
DC- 2
SN-1
DC-2
SN-1
DC-2
SN-1
DC-2
SN-1
DC-2
SN-1
DC-2
SN-1
DC-2
SN-1
DC-2
SN-1
DC-2
SN-1
DC-2
SN-1
DC-2

DC-1

DC-2

DC-1

DC-2

DC-1

Type
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
H70)
7/8"

1"

1 1/2"

2"

2 1/2"

O "
-J

3 1/2"

4"

4 3/4"

1 5/8"

1 1/8"

7/8"

3/4"

2"

2"

3/4"

3/4"

2 5/8"

2 5/3"

Samples
6

9

7

6

5

4

3

4

5

4

4

5

3

3

5

2

2

3

2

(sec. )
520

180

100

60

40

280

185

235

235

400

690

1480

1270

5<1.0

500

300

440

300

160

No.
P.I

P.I

P.I

P.I

P.I

P.I

P.I

P.I

P.I

P.I

P.I

P.I

P.I

P. 2

P. 2

P. 2

P. 2

P. 2

P. 2

                                        93

-------
      Flow
      Rate
Total
Test
No. of
Test
120

121

122

123

124

125

126

127

128

129

130

131

132

133

134

135

136

137

133

139

140


Date
7/5/77

7/5/77

7/5/77

7/5/77

7/5/77

7/5/77

7/5/77

7/6/77

7/11/77

7/11/77

7/11/77

7/11/77

7/12/77

7/12/77

7/12/77

7/12/77

7/12/77

7/12/77

7/12/77

7/12/77

7/12/77



Conf ig.
C.

C.

C.

C.

C.

C.

C.

N.

C.

C.

C.

C.

C.

C.

C.

C.

C.

C.

C.

C.

C.

1

2

3

4

5

6

7

A.

1

2

3

4

8

8

8

8

8

3

8

8

3

Droplet
Counter
DC-2

DC- 2

DC-2

DC-2

DC-2

DC-2

DC-2

N.A.

DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
Liquid
Type
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
(inch of
H,0)
2"

2"

2"

2"

2"

2"

2"

2"

2"

2"

2"

2"

2"

2"

2"

2"

2"

2"

2"

2"

1"

No. D.C.
Samples
1

2

2

3

3

3

2

N.A.

6

6

6

1

5

5

4

3

4

4

4

4

4

Period
(sec. )
40

60

90

200

240

270

140

N.A.

180

1200

2000



340

920

1200

430

550

580

800

700

900

Purpose
No.
P. 3

P. 3

P. 3

P. 3

P. 3

P. 3

P. 3

P. 4

P. 3

P. 3

P. 3

P. 3

P. 5

P. 5

P. 5

P. 5

P. 5

P. 5

P. 5

P. 5

P. 5

94

-------


No. of
Test
141

142

143

144

145

146

147

148

149

150

151

152

153

154

155

156

157

158

159

160




Date
7/12/77

7/12/77

7/12/77

7/13/77

7/13/77

7/13/77

7/13/77

7/13/77

7/13/77

7/13/77

7/13/77

7/14/77

7/14/77

7/14/77

7/14/78

7/19/77

7/19/77

7/19/77

7/20/77

7/20/77




Conf ig.
C.8

C.8

C.8

C.9

C.8

C.8

C.8

C.10

C.10

C.10

C.10

C.ll

C.ll

C.12

C.12

N.A.

N.A.

N.A.

C.3

C.3



Droplet
Counter
DC- 2
SN-2
DC- 2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
DC-2
SN-2
N.A.

N.A.

N.A.

N.A.

N.A.



Liquid
Type
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Pure
Water
Flow
Rate
(inch of
H-,0)
1"

1"

1"

3/4"

3/4"

3/4"

3/4"

3/4"

3/4"

1 1/2"

1 1/2"

2"

2"

2"

2"

N.A.

N.A.

N.A.

2"

2"



No. D.C.
Samples
4

4

4

5

5

7

5

4

4

3

6

4

5

5

5

N.A.

N.A.

N.A.

N.A.

N.A.

Total
Test
Period
(sec. )
1050

950

1300

260

110

310

120

1300

1300

320

60

2800

65

60

1050

1200

1300

840

1800

900



Purpose
No.
P. 5

P. 5

P. 5

P. 6

P. 6

P. 6

P. 6

P. 6

P. 6

P. 6

P. 6

P. 6

P. 6

P. 6

P. 6

P. 7

P. 8

P. 8

P. 8

P. 9

95

-------
No.  of
 Test    Date
Conficr.
                   Flow
                   Rate
Droplet  Liquid   (inch of  No. D.C.
Counter   Type     H2O)    Samples
 Total
 Test
Period  Purpose
(sec.)    No.
161

162



163



164



165



166



167



163



169



170


171



7/20/77

7/20/77



7/20/77



7/21/77



7/21/77



7/22/77



7/22/77



7/22/77



7/25/77



7/25/77


7/25/77



C.3 N.A. Pure 2"
Water
C.3 N.A. 10% 2"
Saline
Solu-
tion
C.3 DC-1 10% 2"
Saline
Solu-
tion
C.3 DC-1 10% 2"
Saline
Solu-
tion
C.3 DC-1 10% 2"
Saline
Solu-
tion
C.4 DC-1 10% 2"
Saline
Solu-
tion
C.4 DC-1 10% 2"
Saline
Solu-
tion
N.A. N.A. 10% N.A.
Saline
Solu-
tion
C.14 DC-1 10% 2"
Saline
Solu-
tion
C.14 DC-1 10% 2"
Saline
Solution
C.13 DC-1 10% 2"
Saline
Solu-
tion
N.A. 900 P. 9

N.A. 1800 P. 10



6 3600 P. 11



9 7200 P. 11



21 3600 P. 11



17 7200 P. 11



19 3600 P. 11



N.A. 450 P. 12



13 2700 P. 13



12 1300 P. 13


17 2700 P. 13



                      96

-------
No. of
 Test    Date
Config.
                   Flow
                   Rate
Droplet  Liquid   (inch of  Mo. D.C.
Counter   Tvoe     H-?0)    Samples
Total
 Test
Period  Purpose
(sec.)     No.
172



173



174



175



176



177



178



179



180



181
182
7/25/77 C.14 DC-1



7/27/77 C.14 DC-1
DC-2


7/27/77 C.14 DC-1



7/27/77 C.14 DC-1



7/27/77 C.14 DC-1



7/28/77 C.14 N.A.



7/23/77 C.14 DC-1



7/28/77 C.14 DC-2
SN-2


7/29/77 C.14 DC-1



7/29/77 C.14 DC-1
7/29/77 C.14 DC-1
10% 2"
Saline
Solu-
tion
10% 2"
Saline
Solu-
tion
10% 2"
Saline
Solu-
tion
10% 2"
Saline
Solu-
tion
10% 2"
Saline
Solu-
tion
10% 2"
Saline
Solu-
tion
10% 2"
Saline
Solu-
tion
10% 2"
Saline
Solu-
tion
10% 2"
Saline
Solu-
tion
10% 2"
Saline
Solu-
tion
10% 2"
Saline
Solu-
tion
8 1300 P. 13



8 600 P. 13



2 300 P. 13



5 600 P. 13



4 600 P. 13



N.A. 300 P. 14



14 1200 P. 13



6 300 P. 13



4 600 P. 13



14 2400 P. 13
12 1200 P. 13
                                       97

-------


No. of
Test Date
201 8/1/77



202 8/1/77



203 8/1/77



204 8/1/77



205 8/2/77



206 8/2/77



207 8/2/77



208 8/3/77



209 8/3/77



210 8/5/77





Droplet
Config. Counter
C.15 DC-2
SN-1
DC-2
SN-2
C.15 DC-2
SN-1
DC-2
SN-2
C.15 DC-2
SN-1
DC-2
SN-2
C.15 DC-2
SN-1
DC-2
SN-2
C.15 DC-2
SN-1
DC-2
SN-2
C.12 DC-2
SN-2


C.15 DC-2
3N-1
DC-2
SN-2
C.15 DC-2
SN-1
DC-2
SN-2
C.16 DC-2
SN-1
DC-2
SN-2
C.17 DC-2
SN-1
DC-2
SN-2
Flow
Rate
Liquid (inch of No. D.C.
Type H20) Samples
10% 2" 4
Saline
Solu-
tion
10% 2" 12
Saline
Solu-
tion
10% 2" 3
Saline
Solu-
tion
10% 2" 6
Saline
Solu-
tion
10% 2" 10
Saline
Solu-
tion
10% 2" 7
Saline
Solu-
tion
10% 2" 10
Saline
Solu-
tion
10% 2" 6
Saline
Solu-
tion
10% 2" 8
Saline
Solu-
tion
10% 2" 12
Saline
Solu-
tion
Total
Test
Period Purpose
(sec . ) No.
300 P. 13



300 P. 13



600 P. 13



1200 P. 13



2400 P. 13



1300 P. 6



3600 P. 13



3600 P. 13



2400 P. 13



140 P. 15



98

-------


No. of
Test Date Config.
211 8/10/77 C.17



212 8/10/77 C.17



213 8/10/77 C.17



214 8/11/77 C.18



215 8/11/77 C.18



216 8/11/77 C.18



217 3/12/77 C.18



218 8/12/77 C.18



219 3/16/77 C.18



220 8/16/77 C.13





Droplet
Counter
DC- 2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2


Liquid
Type
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
Flow Total
Rate Test
(inch of No. D.C. Period Purpose
H->0) Samples (sec.) No.
2" 8 2400 P. 13



2" 8 2400 P. 13



2" 16 4800 P. 13



2" 16 4800 P. 13



2" 5 1200 P. 13


p
2" 2 1200 P. 13



~2" 16 2400 P. 13



2" 6 600 P. 13



2" 4 1200 P. 13



2" 5 1200 P. 13



99

-------


No. of
Test Date Config.
221 8/16/77 C.18



222 8/16/77 C.18



223 8/17/77 C.18



224 8/17/77 C.18



225 8/17/77 C.18



226 8/18/77 C.19



227 8/18/77 C.19



228 8/18/77 C.19



229 8/19/77 C . 20





Droplet
Counter
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
DC-2
SN-1
DC-2
SN-2
Flow
Rate
Liquid (inch of No. D.C.
Type H?O) Samples
10% 2" 4
Saline
Solu-
tion
10% 2" 3
Saline
Solu-
tion
10% 2" 4
Saline
Solu-
tion
10% 2" 4
Saline
Solu-
tion
10% 2" 8
Saline
Solu-
tion
10% 2" 2
Saline
Solu-
tion
10% 2" 2
Saline
Solu-
tion
10% 2" 8
Saline
Solu-
tion
10% 2" 8
Saline
Solu-
tion
Total
Test
Period Purpose
(sec.) No.
1200 P. 13



1200 P. 13



2400 P. 13



2400 P. 13



4800 P. 13



2400 P. 16



2400 P. 16



2400 P. 16



3600 P. 17



100

-------


No. of
Test Date
301 8/2/77



302 8/2/77



303 8/2/77



304 8/2/77



305 8/2/77



306 8/2/77



307 8/3/77



308 8/3/77



309 8/3/77



310 8/4/77





Droplet
Config. Counter
C.21 DC-2
SN-1
DC-2
SN-2
C.21 DC-2
SN-1
DC-2
SN-2
C.21 DC-2
SN-1
DC-2
SN-2
C.22 DC-2
SN-1
DC-2
SN-2
C.22 DC-2
SN-1
DC-2
SN-2
C.22 DC-2
SN-1
DC-2
SN-2
C.23 DC-2
SN-1
DC-2
SN-2
C.23 DC-2
3N-1
DC-2
SN-2
C.23 DC-2
SN-1
DC-2
SN-2
C.12 DC-2
SN-1
DC-2
SN-2
Flow
Rate
Liquid (inch of No. D.C.
Type H20) Samples
10% 2" 8
Saline
Solu-
tion
5% 2" 3
Saline
Solu-
tion
Pure 2" 8
Water


10% 2" 8
Saline
Solu-
tion
5% 2" 8
Saline
Solu-
tion
Pure 2" 8
Water


10% 2" 8
Saline
Solu-
tion
5% 2" 21
Saline
Solu-
tion
Pure 2" 8
Water


10% 2" 10
Saline
Solu-
tion
Total
Test
Period Purpose
(sec. ) No.
2100 P. 18



2100 P. 18



2100 P. 18



2100 P. 18



2100 P. 18



2100 P. 18



2100 P. 18



-2 hrs. P. 18



2100 P. 18



~1 hr. P. 18



101

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                                             Flow               Total
                                             Rate               Test
No.  of                    Droplet  Liquid  (inch of  No. D.C.  Period  Purpose
 Test    Date    Config.  Counter   Type     H20)    Samples   (sec.)    No.

 311    8/4/77    C.12     DC-2     5%        2"       10      ~1 hr.    P.18
                           SN-1    Saline
                           DC-2    Solu-
                           SN-2    tion
 312    8/4/77    C.12     DC-2    Pure       2"       26      ~2 hrs.   P.18
                           SN-1    Water
                           DC-2
                           SN-2
 313    8/2/77    N.A.     DC-1    10%      3 1/2"      2        2.1     P.19
                                   Saline
                                   Solu-
                                   tion
 314    8/2/77    N.A.     DC-1    10%      3 1/4"      2        2.8     P.19
                                   Saline
                                   Solu-
                                   tion
 315    8/2/77    N.A.     DC-1    10%        3"        3        4.6     P.19
                                   Saline
                                   Solu-
                                   tion
 316    8/2/77    N.A.     DC-1    10%      2 3/4"      2        3.3     P.19
                                   Saline
                                   Solu-
                                   tion
 317    8/2/77    M.A.     DC-1    10%      2 1/2"      2        2.5     P.19
                                   Saline
                                   Solu-
                                   tion
 318    8/2/77    N.A.     DC-1    10%      2 1/4"      2        3.6     P.19
                                   Saline
                                   Solu-
                                   tion
 319    8/2/77    M.A.     DC-1    10%        2"        3        7.4     P.19
                                   Saline
                                   Solu-
                                   tion
 320    8/2/77    N.A.     DC-1    10%      1 3/4"      2        9       P.19
                                   Saline
                                   Solu-
                                   tion

                                       102

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No. of
                   Flow
                   Rate
Droplet  Liquid  (inch of  No.  D.C.
 Total
 Test
Period  Purpose
Test
321



322



323



324



325



326



327



328



329



330



Date Config. Counter
8/2/77 N.A. DC-1



8/2/77 N.A. DC-1



8/2/77 N.A. DC-1



8/2/77 N.A. DC-1



8/2/77 N.A. DC-1



8/2/77 N.A. DC-2
SN-2


8/2/77 N.A. DC-2
SN-2


3/2/11 N.A. DC-2
SN-2


8/2/77 N.A. DC-2
SN-2


8/2/77 N.A. DC-2
SN-2


Type H20) Samples (sec.)
10% 1 1/2" 3 6.7
Saline
Solu-
tion
10% 1" 2 6.8
Saline
Solu-
tion
10% 3/4" 2 9
Saline
Solu-
tion
10% 1/2" 2 11.4
Saline
Solu-
tion
10% 1/4" 2 11.2
Saline
Solu-
tion
10% 3 1/2" 1 3.9
Saline
Solu-
tion
10% 3 1/4" 1 5.2
Saline
Solu-
tion
10% 3" 1 5.8
Saline
Solu-
tion
10% 2 3/4" 1 5.5
Saline
Solu-
tion
10% 2 1/2" 1 5.2
Saline
Solu-
tion
No.
P. 19



P. 19



P. 19



P. 19



P. 19



P. 19



P. 19



P. 19



P. 19



P. 19



                                      103

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No.  of
                   Flow
                   Rate
Droplet  Liquid  (inch of  No. D.C.
 Total
 Test
Period  Purpose
Test
331



332



333



334



335



336



337



338



339



Date Config. Counter
8/2/77 N.A. DC-2
SN-2


8/2/77 N.A. DC-2
SN-2


8/2/77 N.A. DC-2
SN-2


8/2/77 N.A. DC-2
SN-2


8/2/77 N.A. DC-2
SN-2


8/2/77 N.A. DC-2
SN-2


8/2/77 N.A. DC-2
SN-2


8/2/77 N.A. DC-2
SN-2


8/2/77 N.A. DC-2
SN-2


Type H20) Samples (sec.)
10% 2 1/4" 1 4.8
Saline
Solu-
tion
10% 2" 1 4.7
Saline
Solu-
tion
10% 1 3/4" 1 4.3
Saline
Solu-
tion
10% 1 1/2" 1 5.3
Saline
Solu-
tion
10% 1 1/4" 1 6.0
Saline
Solu-
tion
10% 1" 1 7.2
Saline
Solu-
tion
10% 3/4" 1 8.8
Saline
Solu-
tion
10% 1/2" 1 11.6
Saline
Solu-
tion
10% 1/4" 1 13.4
Saline
Solu-
tion
No.
P. 19



P. 19



P. 19



P. 19



P. 19



P. 19



P. 19



P. 19



P. 19



                                      104

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       Flow
       Rate
Total
Test
No. of
Test
401



402



403



404



405



406



407



408



409



410



Droplet
Date Config. Counter
8/24/77 C.21 DC-2
SN-1
DC-2
SN-2
8/24/77 C.22 DC-2
SN-1
DC-2
SN-2
8/25/77 C.23 DC-2
SN-1
DC-2
SN-2
8/26/77 C.15 DC-2
SN-1
DC-2
SN-2
9/16/77 C.17 DC-2 &
Multi-
plexer

9/19/77 C.17 DC-2 &
Multi-
plexer

9/19/77 C.24 DC-2 &
Multi-
plexer

9/20/77 C.25 DC-2 &
Multi-
plexer

9/20/77 C.25 DC-2 &
Multi-
plexer

11/23/77 C.26 DC-2
SN-1
2 probes

Liquid
Type
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
10%
Saline
Solu-
tion
(inch of No. D.C. Period Purpose
H20) Samples (sec.) No.
2" 5 2400 P. 18



2" 5 2400 P. 18



2" 14 3000 P. 18



2" 9 4800 P. 18


•
2" 16 P. 20



2" 7 P. 20



2" 15 3600 P. 18



2" 10 3600 P. 18



2" 15 4200 P. 18



2" 5 1800 P. 21



105

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No.  of
 Test

411
 Date    Config.
11/23/77  C.26


Droplet
Counter


Liquid
Type
Flow
Rate
(inch of
H20)


No . D . C -
Samples
Total
Test
Period
(sec.)


Purpose
No.
DC-2
SN-1
probes
10%
Saline
Solu-
tion
2"
2400
P.21
                                      106

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                Definition of Purpose Number

No.                           Purpose

P.I    Investigate the response of instrument for different
       flow rates

P.2    Compare results given by DC-1 and that of DC-2 under
       the same operating condition

P. 3    Investigate the output response of impactor by
       using DC-2

P.4    Measure the pressure and temperature drop after the
       cyclone--cyclone + 1 state, cyclone + 2 stages and
       cyclone + 3 stages individually

P.5    Obtain the droplet  distribution curves at the inlet
       and outlet of a vertical brass tube

P.6    Investigate the distribution curves at the inlet and
       outlet of a vertical glass tube for the study of
       condensation/evaporization and delay effect

P.7    Obtain the evaporation rate of pure water on foil
       target using the Cahn Balance

P.8    Investigate the evaporation rate of pure water on
       paper target using the Cahn Balance

P.9    Use paper as absorbing material to investigate the
       condensation effect behind the target

P.10   Investigate the evaporation rate and/or concentration
       change for drops collected on stage 1 of an impactor

P.11   Exercise the combined operation of impactor and DC-1

P.12   Obtain the evaporation rate for a drop of saline solu-
       tion using the Cahn Balance

P.13   Perform experiment for comparison of DC-2 against the
       Brink impactor
                             107

-------
No.                           Purpose

P.14   Perform experiment for comparison of the DC-2 against
       the Brink impactor with the impactor connected to the
       spray box overnight to establish an equilibrium
       initial condition

P.15   Compare the time required for measuring 100 drops by
       DC-2 SN-1 and DC-2 SN-2

P.16   Perform experiment for comparison of DC-2 against
       impactor by leaving the impactor inside the spray box

P.17   Investigate the distribution curve at the inlet and
       outlet of an impactor with no targets inside the
       impactor

P.18   Obtain distribution curves  at the inlet and outlet of
       the designed configuration for investigation of
       collection efficiency and delay phenomena

P.19   Investigate droplet size distribution and rate of
       counting for different flow velocities

P.20   Check the validity of measurement for two probes

P.21   Compare the mass of droplets collected by stage 1 of
       impactor with the mass difference indicated by the
       DC-2 measurements at the inlet and outlet
                             108

-------
         Test  Configurations  of Equipment
ci
 schematic of
 hot-wire probe
                      air  +
                      droplets
                      flow
C2
C3
            cyclone alone
— >•

c
1

cyclone +
1 stage
C5
                                      C6
                                                    cyclone +
                                                    3 stages
                                                    cyclone +
                                                    4 stages
 C4
            cyclone +
           V2 stages
                                      C7
              cyclone +
              5 stages
                           109

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C8
            Cll
   i
       Vertical  brass
       tube
         DC-2  is  connected
         to  probe either  at
         inlet or outlet
              Metal deflector  is  introduced
              in  the  glass  tube to  reduce
              turbulence  in  the flow
C9
             C12
                                                i
        Vertical  glass  tube
                               Vertical  glass
                               tube with metal
                               deflector
                                   C13
CIO
 -Z3Z
Z3E*
                                                     Cyclone  +  1  stage
   Horizontal  glass  tube
                                 110

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C14
C17
               Cyclone  +
               2  stages
 Two probes  are
   connected
 to 2DC-2's
CIS
CIS
C16
               Cyclone +
               3 stages
	 *" ^
C
1
2
3
4

Cyclone +
4 stages
0) 	 >.
                                        C19
•*• (D

C
1
2
3
4
5

Cyclone +
5 stages
                                   111

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C20
C24

c
1
2
3
4
5

impactor without
targets

-------
                                TECHNICAL REPORT DATA
                         (Please read Inumctions on the reverse before completing)
1. .REPORT NO.
 EPA-600/7-79-I66
                                                      3. RECIPIENT'S ACCESSION NO.
J. TITLE AND SUBTITLE
 Development of Droplet Sizing for the Evaluation of
   Scrubbing Systems
                                5. REPORT DATE
                                 July 1979
                                6. PERFORMING ORGANIZATION CODE
7. AUTHOH(S)

Hector Medecki, K.C. Wu, and D.E.Magnus
                                                      8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
 KLD Associates,  Inc.
 300 Broadway
 Huntington Station.  New York 11746
                                10. PROGRAM ELEMENT NO.
                                EHE624
                                1 1. CONTRACT/GRANT NO.
                                68-02-2111
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
                                13. TYPE OF REPORT AND PERIOD COVERED
                                Final:  6/75 -  3/77
                                14. SPONSORING AGENCY CODE
 Research Triangle  Park, NC
        27711
             EPA/600/13
15. SUPPLEMENTARY NOTES jERL-RTP project officer is D. Bruce Harris, Mail Drop 62,  919/
 541-2557.
16. ABSTRACT
          The report describes the development and characteristics of the DC-2
 Droplet Counter as used to evaluate scrubbing systems. The measurement of entrai-
 ned droplets and their concentrations in gas streams is important in pollution control
 technology. The use of a hot-wire sensor can successfully measured the desired
 parameters for droplets in the size range from 1 to 600 micrometers.  The report
 describes extensive testing in the laboratory and gives a comparison with results
 from the Brink impactor. A correlation of results  for these two measurement tech-
 niques  was  achieved.  The report also describes field tests at four different sites.
17.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                          b.IDENTIFIERS/OPEN ENDED TERMS
                                             c.  COSATI Field/Group
 Pollution
 Drops (Liquids)
 Measurement
 Testing
 Evaluation
 Gas Scrubbing
Counters
Pollution Control
Stationary Sources
DC-2 Droplet Counter
13B
07D
14 B
                                             07A,13H
13. DISTRIBUTION STATEMENT
 Release to Public
                                          19. SECURITY CLASS (This Report)
                                          Unclassified
                                             21. NO. OF PAGES
                                               120
                    20. SECURITY CLASS (This page)
                    Unclassified
                                             22. PRICE
EPA Form 2220-1 (9-73)
                  113

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