A  STUDY OF  EXHAUST  EMISSIONS FROM
RECIPROCATING  AIRCRAFT  POWER PLANTS
                     Prtpartd for
         AIR POLLUTION CONTROL  OFFICE
      ENVIRONMENTAL  PROTECTION  AGENCY
            SCOTT RESEARCH LABORATORIES, INC.
                     P 0. BOX D-ll
               PLUMSTEAOVILLE, PENNSYLVANIA 18949

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        A Study Of Exhaust Emissions From
       Reciprocating Aircraft Power Plants
   APCO (Formerly NAPCA)  Project CPA 22-69-129
            Scott Project Number 1136
                  Prepared for
          Air Pollution Control Office
Division of Motor Vehicle Research & Development
         Environmental Protection Agency
                5 Research Drive
           Ann Arbor, Michigan  48103
                December 28, 1970
        SCOTT RESEARCH LABORATORIES, INC.
                 P. 0. Box D-ll
       Plumsteadvi'lle, Pennsylvania   18949

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                                  TABLE OF CONTENTS

                                                                         Page No.
     Summary

1.0  Introduction                                                          1-1

2.0  Background                                                            2-1

3.0  Description of Test Aircraft                                          3-1

4.0  Test Equipment and Procedures                                         4-1

     4.1  Aircraft Analytical Instrument System                            4-2

     4.2  Installation of Aircraft Analytical Instrument System            4-3

     4.3  Aircraft Testing Procedures                                      4-10

     4.4  Laboratory Analysis                                              4-12

     4.5  Data Reduction and Calculations                                  4-13

5.0  Results of Aircraft Emission Tests                                    5-1

     5.1  Takeoff-Cruise-Landing(TCL) Cycle                                5-1

     5.2  Emission Test Results                                            5-3

     5.3  Emission Rates                                                   5-3

6.0  Discussion of Data Collected                                          6-1

     6.1  Effect of Operational Mode on Exhaust Emissions                  6-1

     6.2  The Effect of Aircraft Parameters on Exhaust Emissions           6-3

     6.3  Comparison of Emissions from Light Aircraft & Automobiles        6-6

     6.4  Afterburning                                                     6-8

     6.5  Control Techniques for Aircraft Emissions                        6-11

     6.6  Conclusions                                                      6-12

     6.7  Recommendations for Future Studies                               6-13




                                    (Continued)
         SCOTT RESEARCH LABORATORIES, INC

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                           TABLE OF  CONTENTS (Continued)

                                                                          Page NO.
7.0  References                                                             7-1

     Appendix of Data                                                       A-l

        Concentration and Temperature  Data                                 A-2

        Emissions as Ib/lb Fuel                                             A-ll

        Emissions as Ib/min                                                 A-19

        Mode and Cycle Emissions                                            A-29

        Afterburning Analysis                                               A-38
        SCOTT RESEARCH LABORATORIES. INC

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                                 SUMMARY




          Under contract with the Air Pollution Control Office  (formerly




National Air Pollution Control Administration), Scott Research Laboratories




has documented the exhaust emissions of light, piston engine aircraft and




investigated the phenomena of natural afterburning of the exhaust gases on




contact with the ambient air.  The approach used in this study was to




measure the exhaust emissions of representative aircraft as they were flown




in a normal manner.  At the same time, the extent of afterburning was




measured by sampling the exhaust plume downstream of the exhaust stack and




comparing the plume composition, corrected for dilution, to the composition




of the stack gases.




          The exhaust emissions from nine light aircraft were determined




using a 9-mode takeoff-cruise-landing (TCL)  cycle developed for this




study.  Exhaust component concentrations and fuel consumption rates




were measured for each mode during ten test flights per aircraft.  The




pollutant concentrations were converted to emission rates per pound of




fuel, per minute, per mode, per TCL cycle, and per landing-takeoff (LTO)




cycle.  A summary of light aircraft emissions is given below.






              Summary of Emissions from Nine Light Aircraft
Rate Parameter
Pounds per Pound of Fuel
Pounds per Minute
Pounds per TCL cycle
Pounds per LTO cycle
CO
0.847
0.614
21.0
14.1
CO?
1.74
1.27
43.3
25.5
Total HC
(as hexane)
0.0210
0.0152
0.520
0.431
NOX
(as NO?)
0.0102
0.0074
0.254
0.128
      SCOTT RESEARCH LABORATORIES, INC

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          The rich mixtures employed during most operations resulted




in incomplete combustion as demonstrated by the high ratio of  carbon




monoxide to carbon dioxide recorded.  During  lean cruise operation




carbon monoxide and hydrocarbons were substantially lower and  nitrogen




oxides were much higher than at the normal rich mixture operation.




The difference in exhaust composition from one rich mode to another




was small.




          The fuel injected engines tested emitted much higher concen-




trations of hydrocarbons than the normally aspirated engines.   Exhaust




composition differences due to engine age, size and airframe design




were minor.




          No afterburning of exhaust carbon monoxide and hydrocarbons




was found for any of the test aircraft at any mode.  Apparently the




exhaust temperatures at the stack exit were too low for burning to




occur.  Means for enhancing afterburning are discussed.  The application




of automobile exhaust reactors to light aircraft is considered, and




design problems which must be solved are noted.
    SCOTT RESEARCH LABORATORIES. INC

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                                   1-1







                            1.0  INTRODUCTION




          This report describes the work performed by Scott Research




Laboratories, Inc. on the Air Pollution Control Office's project,




"A Study Of Exhaust Emissions From Reciprocating Aircraft Power




Plants" (Contract No. CPA-22-69-129).  This project was sponsored by the




Division of Motor Vehicle Research and Development of the Air  Pollution




Control Office.






1.1  PROJECT OBJECTIVES




          The general objective of the contract was to study the exhaust




emissions of light utility, piston engine aircraft.  The specific




objectives of the study were:




      1.  Document the emissions of carbon monoxide, hydrocarbons




          and nitrogen oxides from light aircraft under typical




          use conditions.




      2.  Determine the extent of natural afterburning in the




          emitted exhaust and consider means of increasing the




          extent of afterburning under typical use conditions.




      3.  Reach conclusions regarding the potential usefulness of




          exhaust system reactors in general, and the need for




          alternative methods for reducing carbon monoxide and




          organic gases emitted by light aircraft.




          The general approach used in reaching these objectives consisted




of monitoring the exhaust constituents of representative aircraft as they




were flown in a normal manner.  This approach was used because simulation




of normal flight in a test cell was considered extremely difficult.
     SCOTT RESEARCH LABORATORIES, INC

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                                    1-2






1.2  OUTLINE OF REPORT




          This report has been organized  into  six  sections following




the introduction.




          Section 2 supplies the background  to  this  study.




          Section 3 describes the aircraft tested  during  this  study and




the reasons for their selection.




          Section 4 describes the equipment  and ifethodology used in




conducting this study.




          Section 5 presents the results  of  the study.




          Section 6 discusses the results and presents  the conclusions




and recommendations.




          The report concludes with references  in  Section 7 and an




appendix of data collected during test operations.
   SCOTT RESEARCH LABORATORIES, INC

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                                   2-1


                             2.0  BACKGROUND

          Atmospheric contaminants emitted by aircraft constitute a small

but significant contribution to air pollution in the form of carbon monoxide,

nitrogen oxides, particulates and various organic compounds.  These are

basically the same pollutants as those emitted by highway vehicles.   In

1965 a study by the Los Angeles County Air Pollution Control District found

that non-military aircraft were responsible for between one. and  two per-

cent of all organic gases, carbon monoxide, and oxides of nitrogen., and

approximately ten percent of all aerosols emitted in Los Angeles County.   The

nationwide figures  indicate that civil aircraft were responsible for about

one percent of all organic gases and carbon monoxide emitted in  the

United States.  This percentage will increase, however, as  controls are

tightened on other pollution sources and the aircraft population increases.

The development of high speed aircraft with greater fuel consumption  rates

will also increase this percentage.

          A great deal of attention has been given to the emissions of

large turbojet engines.  This is due to their optically dense plume,

characteristic odor and their concentration around major air terminals.

The turbojet aircraft are generally large, multi-engined commercial

aircraft.  Several programs are underway to determine the amount and  type

of emissions from turbojets and the best way to reduce the  quantities

emitted.
1.  Page 1 of Ref. 1
2.  Table 43, page 283, Ref. 2
    SCOTT RESEARCH LABORATORIES, INC

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                                   2-2






          The general aviation category of aircraft, however, consists




primarily of light, piston engine aircraft.  They are large in number and




relatively dispersed across the country.  The emissions of this type of




aircraft have not been well documented, particularly the emissions under




true flight conditions.  These aircraft engines are very similar to




automobile engines in their manner of operation.  The basic element is




the combustion chamber in which fuel and air mixtures are burned and from




which energy is extracted through a piston and crank mechanism that drives




a propeller.  Nearly all aircraft piston engines have two or more cylinders




and are generally classified according to their cylinder arrangement.  The




arrangement in general use is the opposed configuration.  Some radial




engines are still in use in older large transport aircraft.




          All of the emission control techniques applicable to automobile




engines are applicable, in principle, to aircraft piston engines.  However,




the techniques vary widely in their practicability.  Some reduction in




emissions from piston engined aircraft was believed to occur as a result




of natural afterburning of hot exhaust gases as they enter the atmosphere.




Natural afterburning would reduce the amount of carbon monoxide, organic




gases and perhaps carbonaceous particulates emitted.  Little documentation




of the existence and effect of this afterburning can be found.  The




enhancement of afterburning is potentially a simple, effective means




of reducing emissions from aircraft piston engines.
   SCOn RESEARCH LABORATORIES. INC

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                                   3-1






                    3.0  DESCRIPTION OF TEST AIRCRAFT




          Aircraft tested under this contract were selected to represent




typical engines, exhaust system geometries and airframes  found in the




present light aircraft population.  From talks with consultants, aircraft




dealers, pilots and engine manufacturers, it was determined that the




engines in the present population were almost exclusively of horizontal,




opposed cylinder configuration, with four or six cylinders.  It was also




determined that most of the engines had a single exhaust stack, and the




most popular airframe was a single-engine monoplane with fixed tricycle




landing gear.




          The characteristics of the test aircraft are summarized in




Table 3-1.  All the engines in these aircraft had a horizontal, opposed




cylinder configuration.  These aircraft were selected so that they could




be grouped in various ways to show the effect of certain variables on




exhaust emissions and afterburning:




      1.  Engine Operating Time - The effect of total engine operating




          time was studied by testing a group of three Cessna 172's with




          four cyclinder engines and a group of two Cessna 182's with




          six cylinder engines.




      2.  Airframe Design - The effect of airframe design was




          investigated by comparison of a Piper PA-23, a low wing,




          twin-engined aircraft with retractable landing gear,




          with a Cessna 172, a high wing, monoplane with a fixed




          tricycle landing gear.   Both aircraft were powered by




          similar engines.
    SCOTT RESEARCH LABORATORIES, INC

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AIRCRAFT
Test
No. Manufacturer Model
1 Cessna Skyhawk
172K
2 Cessna Skyhawk
172D
3 Cessna Skyhawk
1721
4 Cessna Skyhawk
172K
5 Beechcraft Bonanza
36
6 Cessna Skylane
182H
7 Cessna Skylane
182H
8 Piper Apache
PA-23
9 Cessna Centurion
T210F
Reg.
No.
N78658
N236OU
N8410L
N7048G
N1697A
N1976X
N92687
N1314P
N6739R
ENGINE INFORMATION
Manufacturer
Lycoming
Continental
Ly coming
Lycoming
Continental
Continental
Continental
Lycoming
Continental
Engine
No. of Operation
Model Cylinders Time
0-320-E2D 4 140
Hrs.
0-300-D 6 295
Hrs.
0-320-E2D 4 672
Hrs.
0-320-E2D 4 105
Hrs.
IO-520-B 6 334
Hrs.
0-470-R 6 1053
Hrs.
0-470-R 6 53
Hrs.
0-320-A 4 423
Hrs.
TS-520-C 6 900
Hrs.
HP
150
145
150
150
285
230
230
150
285
P rope Her
Tvpe
Fixed
Pitch
Fixed
Pitch
Fixed
Pitch
Fixed
Pitch
Variable
Pitch
Variable
Pitch
Variable
Pitch
Variable
Pitch
Variable
Pitch
Fuel -Air
System
Normal
Aspiration
Normal
Aspiration
Normal
Aspiration
Normal
Aspiration
Fuel Injected
Normal
Aspiration
Normal
Aspiration
Normal
Aspiration
Turbo-chgd.
& Fuel Inj.
Exhaust
System
Single
Stack
Dual
Stack
Single
Stack
Single
Stack
Dual
Stack
Single
Stack
Single
Stack
Single
Stack
Single
Stack
                                                                                                  OJ
                                                                                                  ro
Table 3-1.  Characteristics of Test Aircraft

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                                    3-3


      3.  Engine Design Variables - Common engine design variations

          were represented by the Beechcraft Bonanza 36 with fuel

          injection, the turbocharged Cessna 210 with fuel injection,

          and the Cessna 182 with natural carburetion.  A super-

          charged aircraft was not tested because they are relatively

          rare.  Supercharging has been replaced almost entirely by

          turbocharging in the newer aircraft.

      4.  Exhaust System Geometry - Exhaust geometries represented

          included the six cylinder Cessna 172 with a dual exhaust,

          the Piper PA-23 with a venturi-ejector exhaust and the

          Cessna 172 and 182 with the more common single exhaust stack.

          The fuel used by all the aircraft except P5 and #9 was 80

octane.  The fuel injected aircraft used 100 octane fuel.  The specifications

for both these fuels are presented in Table 3-2.

          The aircraft tested were obtained from three local aircraft

dealers and air taxi operators.  The aircraft available from these

sources were well maintained and inspected every 100 operating hours.

          The aircraft selected for this program represented 68.5% of the

eligible* aircraft in the national population based upon FAA categories

presented in Reference 5.  The only major class not represented was the

small (one to three place)  aircraft because of limited room for our

instrumentation.   Table 3-3 presents the FAA categories, the number of

aircraft in each category,  and the aircraft tested in each category.
* Aircraft that are both registered and carry a valid airworthiness
  certificate.
    SCOTT RESEARCH LABORATORIES, INC

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                                      3-4
                  Table 3-2.   Specifications for Aviation Gasolines

                                   (ASTM D910-70)

Knock value, min, octane
number, lean rating
Knock value, min, octane
number, rich rating


Color
Dye content:
Permi ssible blue dye,
max, mg per gal
Permissible yellow dye,
max, mg per gal
Permi ssible red aye,
max, mg per gal
Tetraethy 1 lead, max, ml
per gal
Net heat of combustion,
min, Btu per Ib
Grade
80-87
80

87



Red


0-5

none

8.65

0.5

18 720















i



Grade
100-130
100

Isooctane plus
1 .28 ml of
tetraethyl lead
per gal Ion
Green


<».7

7-0

none

3-0

18 720
                                Requirements for All  Grades
 Distillation temperature,  deg F
   10 per cent evaporated,  max
   50 per cent evaporated,  max
   90 per cent evaporated,  min
   90 per cent evaporated,  max

 Final boiling point,  max,  deg F

 Sum of 10 and 50 per  cent  evaporated temperatures,
   min, deg F

 Distillation recovery,  min,  per cent

 Distillation residue, max,  per cent

 Distillation loss,  max, per cent

 Acidity of distillation residue

 Vapor pressure,  max,  Ib

 Potential gum (5 hr aging  gum), max, mg per  100  ml

 Visible lead precipitate,  max, mg  per 100  ml

 Sulfur, max, per cent

 Freezing point,  max,  deg F (deg C)

 Water tolerance
 Permissible antloxidants,  max,  Ib per  1000  bbl
   0*2 gal)
     158
     221
     212
     257

     338
     307

      97

     1.5

     1.5

Shall not be acid

     7.0

       6

       3

     0.05

- 72 (-58)

Volume change not to
exceed +_ 2 ml
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                                      3-5
                  Table 3-3.  United States  light  aircraft
                    population as categorized by the  FAA.

    FAA Category
   (by total rated
engine takeoff power)           Eligible Aircraft*          Aircraft Tested
Single Engine
   100 hp and less                   28,262
   101-200 hp                        47,018                 Cessna 172
   201-350 hp                        31,231                 Cessna 182,  210 &
                                                            Beechcraft 36
   351-500 hp                         1,328
   501-700 hp                           559
   over 700 hp                          235
2 - Engine
   500 hp and less                    5,533                 Piper  Apache
   501-800 hp                         8,220
Total                               122,386
* Aircraft that are both registered and carry a valid airworthiness  certificate.
      SCOTT RESEARCH LABORATORIES, INC

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                                      4-1


                      4.0  TEST EQUIPMENT AND PROCEDURES

             In order to accomplish the objective of the study, it was

   necessary to monitor the concentration of carbon monoxide, hydro-

   carbons and nitrogen oxides in the exhaust stack and the concentrations

   of carbon monoxide and hydrocarbons in the exhaust plume after any

   afterburning had occurred.  Ideally, all monitoring should be done

   by an analytical instrument system installed in the aircraft.  Since

   this was not practical because of weight, volume and power constraints,

   an optimal combination of a limited analytical system in the aircraft

   for continuous analysis of the stack samples and laboratory analysis

   of the dilute exhaust plume sample was used.  Table 4-1 summarizes

   the analytical techniques used in this study.



                                   Table 4-1

                  Analytical Techniques For Aircraft Exhaust


                              Method Used for                Method Used for
   Compound (s)	             Stack Samples	             Plume Samples	

Carbon Monoxide            Continuous Infrared            Gas Chromatography of
                           Analyzer in aircraft           bag sample in labora-
                                                          tory

Carbon Dioxide             Continuous Infrared            Gas Chromatography of
                           Analyzer in aircraft           bag sample in labora-
                                                          tory

Total Hydrocarbons         Continuous Flame               Bag sample by Flame
                           lonization Detector            lonization Detector
                           in aircraft                    in laboratory

Nitrogen Oxides            Continuous Electro-
                           chemical Analyzer in
                           aircraft
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                                   4-2






4.1  AIRCRAFT ANALYTICAL INSTRUMENT SYSTEM




          The primary considerations  in  the design of  an  aircraft




analytical instrument system are accuracy, power  consumption, weight  and




volume.  Most of the aircraft tested  under this contract  were light,




four place aircraft with minimum baggage  space.   Since the  flight  crew




consisted of the pilot and an engineer to operate the  instrument system,




the space available for equipment was limited to  the remaining  seating




and baggage area and had to weigh no more than two people (340  Ibs) plus




the baggage allowance.  The equipment also had to remain  operable  in  an




airborne environment with its attendant  shock and vibration  field,  and




temperature and altitude variation.  The  aircraft tested  generally had




little electrical power available beyond  that needed for  aircraft




operation.  For this reason and to avoid  fluctuating voltage due to




engine speed and aircraft electrical  load variations,  the instrumentation




was powered by an independent auxiliary power supply.




          The instruments chosen were two Mine Safety  Appliance Corp.




LIRA Model 300 infrared analyzers for 0-10% carbon monoxide  and 0-15%




carbon dioxide, a Beckman Model 109A  flame ionization  detector  and a




Whittaker Model NX110 nitrogen oxides analyzer.   The responses  of  these




instruments as well as that of the thermocouples  mounted  on  the exhaust




probes, were recorded continuously on battery powered  Esterline Angus




Model T-171B strip chart recorders.  The  instruments were powered  by  a




heavy duty storage battery using a 250 VA inverter to  convert the




12 volts DC to 115 volts AC at 60 Hertz.  A diaphram pump mated to a




12 volt DC motor was used to drive the sample through  the analyzers.
    SCOTT RESEARCH LABORATORIES, INC

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                                    4-3







 The  pump was  powered  by  the  aircraft  electrical  system since  voltage variations




 would  not  seriously affect its  operation.   When  the  engine  was  not running,




 such as before  start  up  and  after  shut  down,  the pump was powered by the




 auxiliary  power supply.




           Figure 4-1  shows a schematic  of  the flow and electrical systems of




 the  airborne  analytical  instrument package.   Inputs  to the  system were




 selected by valves V-l and V-2.  The  possible inputs were:  1.  stack probe,




 2. plume probe,  3. zero  gas,  4. hi-span gas and  5. low-span gas.   The exhaust




 sample was taken at a rate of five liters  per minute and passed through a




 water  trap, a particulate filter and  a  cold trap in  an ice  bath.   The flow




 rate was monitored by flowmeters FM-1,  FM-2,  and FM-3 and controlled by




 valves FL-1 and FL-2.  The pressure at  the inlets of the infrared analyzers




 was  measured  and logged  throughout the  test.   After  passing through the




 infrared analyzers and flow  control equipment, the sample passed  through




 the  nitrogen  oxides monitor  and the hydrocarbon  analvzer.   Valve  V-3 then




 directed the  sample to a vent or to the connection where Tedlar bags were




 filled for subsequent laboratory analysis.







 4.2  INSTALLATION OF  AIRCRAFT ANALYTICAL INSTRUMENT  SYSTEM




           Prior  to installation of the  equipment,  all  seats but the pilot's




 were removed.   The equipment  was grouped into modules  in order  to facili-




 tate handling.   The five recorders, NOX analyzer,  thermocouple  reference




 cell and thermocouple selector switch were mounted in  a rack made of




 aluminum angle.  The  selector valves, water trap,  particulate filter and




 pump switch were mounted on a small flow control panel.  This panel  was




 usually attached to the forward end of  the recorder  rack within easy reach




of the operator.  The rack and flow control panel are  shown in Figure  4-2.
    SCOTT RESEARCH LABORATORIES, INC

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i
§
NOTES:
  I.	ELECTRICAL WIRING 4 INSTRUMENTS
    ) STRIP  CHART RECORDERS  ESTERLINE ANGUb
   MODEL T-17IB  (BATTERY  POWERED)
                                                                                       CD INVERTER

r
i 	 f
1
f
M
AIRCRAFT
CVLJAI |Cf
PIPE
SWCK r«^| STACK
Xi— - — THtRMO- . .
hi COUPLE ; ;
PROBE -i
THERMO- IL JJ _ 	 	 . 1 U L ' '

DILUIF_^^- — T2

rWJUt , i
7FBn r 1*1 i — t '

co r &j.~ r1 ... 	 ^ ! ' A
co,j £& 1 auNi1 ?!
Hr / e*s i _r

CALIBRATION
BAGS
r r-^_-^.— ... ^! [-"r'-t-----!^
~ r-> — = r; t:rr.: i i j 250 VA
J ' r.o— - ^ 	 JREFERENCE | ' ~^-
CELL -
. . — — 1 i —
- - U-FJ-^ !
	 i _.j ;«vj jr
STORAGE BATTERYl,
TO AIRCRAFT BUS^^j OFF J pR^JX..^
» fAUGEtT^
- ,
- PARTICULATE | 	 1 — i ',
iv-i 	 FILTER _c-; Fu , -. )F
r ^ 	 ^ n (ft — co^'—i
	 r 1 1 v"V — *•
WATER LM 5L,^S/M,« ^TT
TRAP J.L.^
1 roi n TRAP ' ''' '" '_A.
t^ (-ULL> 1RAK i co« 'tj
IL ' 	 '
V-P f 1 nU) t Pi CTTDITAI

SCHEMATIC FOR AIRCRAFT
EXHAUST SAMPLING SYSTEM
' ^ POWER JUNCTION
1 BOX
LJ!Qy_6OxJ I
-,-.--,-,'
. _ - _ _i . !
, i 	
' 	 ""*
A ' .^ 1 * Ljf ir/1^
-*» NO, | I -B*- W
^..ii.1 >"^'
', ! r-J ! '
LjfhFM-jLii6^^'"0^! 1 	 ^^Nf
^J ZM£S IO
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30
B
m
n
oo
O
pa
s
o
                                       Figure 4-2.   Recorder Rack,  NOx Monitor and

                                      Flow Control Panel  Installed  in a Cessna 210.

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                                    4-6






          The two MSA infrared analyzers and  the  Beckman  109A  FID  were  bolted




together and shock mounted ae a unit on an aluminum pallet  as  shown  in  Figure




4-3.  This assembly also held the nitrogen-hydrogen fuel  and compressed air




cylinders for the FID as well as the two flow control valves  (F  ,  F   in




Figure 4-1) and two flowmeters (FM., FM ) .  The pump and  motor were  likewise




shock mounted on an aluminum pallet.  The operator's seat,  a storage battery




holder and the inverter were mounted on a plywood floor panel.   The  floor




panel was then placed in the rear seat/baggage area and bolted to  the seat




rails and seat belt attachment points.  The recorder rack was  then attached




to the plywood floor panel.  The operator occupied the right rear  seat  area



and the recorder rack occupied the  left rear  seat area.   The inverter and




storage battery occupied the baggage area and are shown in  Figure  4-4.




          The shock mounted analyzer package  was  attached to the right  front




seat rails and seat belt anchor points.  The  pump module  was fastened down




in whatever space remained - either to a seat rail or to  the plywood floor




panel.  Interconnecting tubing and wiring completed the cabin  installation.




          Exhaust gases were collected by a probe that was  custom-made  for




each installation.  It contained two gas sampling points, one  well within




the exhaust stack to sample the stack gases and a second  usually about  four




inches below and four inches downstream of the exhaust stack exit  to sample




the plume gases.  The probe used on aircraft  #9 is shown  in Figure 4-5.




Thermocouples were located near each sampling point to monitor the gas




temperature at the two probe inlets.  The exhaust sample  was brought  into




the cabin through the existing inspection hatch located on  the aircraft belly




using Teflon and stainless steel tubing.  The length of tubing from  the




sampling points to the analyzers was approximately ten feet.
   SCOTT RESEARCH LABORATORIES, INC

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SCOTT RESEARCH LABORATORIES, INC
                                     4-7
            Figure 4-3.   Infrared Analyzers  and Flame lonization
              Unit Mounted on Aluminum Pallet  in a Cessna 210.

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                                                                                oo
Figure 4-4.  Inverter and Storage Battery
    in Baggage Area of a Cessna 210.

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                               4-9
              Figure 4-5.  Sampling Probe Installed
       on the Exhaust Stack of a Cessna 210 (two views)
SCOTT RESEARCH LABORATORIES, INC

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                                   4-10







          When the installation of the exhaust analysis equipment was




complete as shown in Figure 4-6, the FAA was notified and  a  request  for




aircraft recertification was made.  The aircraft was then  inspected  by




an FAA representative and recertified in the Experimental  category.  In




this category an airplane may be flown only by the project crew  and




only within a specified low population density area.




          After completing the testing on the aircraft, the  equipment




was removed and the aircraft returned to the standard configuration.  At




that time application was made to the FAA for certification  of the air-




craft into Standard category.   The aircraft was then inspected and certified




by the FAA, and returned to the owner.






4.3  AIRCRAFT TESTING PROCEDURES




          The test program was performed at Central Bucks  Airport,




Doylestown, Pennsylvania.  Approximately ten test flights  were




conducted for each aircraft.  A typical test flight lasted about a




half hour from engine start to engine shutdown.  During each mode of the




takeoff-cruise-landing  (TCL) cycle, the on-board instruments continuously




monitored the stack gases.  During part of each steady-state mode, Tedlar




bag samples and nitrogen oxide readings were taken of the  exhaust plume.




The bag samples were taken to Scott's Plumsteadville laboratory  for




analysis at the end of the flight.  The steady-state modes were  taxi,




ascent, cruise and descent.  Modes such as takeoff and landing were  non-




steady-state because the engine conditions changed rapidly due to loading




variations as well as adjustments by the pilot.  Calibrations were per-




formed using on-board calibration bags three times during  each flight, one a




at the end of the initial taxi, another during the cruise  mode and the last
   SCOTT RESEARCH LABORATORIES, INC

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X

rr
y

-r
c
X
--
                                          Figure 4-6.  Complete  Instrument  System



                                           Installed in a Beechcraft  Bonanza 3G.

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                                   4-12






 after shutdown.  Randomly  selected bag  samples  of  the  stack  gases  were




 taken for  laboratory  analysis as  a cross-check  on  the  aircraft analytical




 system.  Samples of the ambient air were  also taken  during the flight and




 brought to the laboratory  for analysis  with  the other  bag samples.




           Fuel flow data were obtained  by two methods.   For  aircraft with




 a gravity  fuel feed,  a calibrated rotometer  was inserted in  the fuel line.




 The readings were logged as the aircraft  was flown through the various




 operating  modes.  If  the aircraft had a fuel pump, a calibrated turbine




 meter was  installed in the fuel line and  its readings  logged.   The




 stainless  steel turbine meter had a flow  range  of  3.5  to 45  USGPH.   The




 turbine meter could only be used  on aircraft with  fuel pumps because




 the pressure drop across the meter restricted the gasoline flow of




 gravity fed aircraft.






 4.4  LABORATORY ANALYSIS




          The Tedlar  bag samples  of the exhaust plume  returned to  the




 Plumsteadville Laboratory were analyzed for  carbon monoxide, carbon




 dioxide and total hydrocarbons.   The concentrations  of the carbon




 oxides were determined by gas chromatography.   The hydrocarbon concen-




 tration was measured  using a Beckman Model 109A flame  ionization




detector operated under laboratory conditions.  The  stack samples were




 analyzed in a similar manner.   The ambient air  samples were  analyzed  only




 for carbon dioxide and hydrocarbons since normal carbon  monoxide levels




are extremely low.
   SCOTT RESEARCH LABORATORIES, INC

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                                  4-13






4.5  DATA REDUCTION AND CALCULATIONS




          The continuously recorded strip charts indicating temperature,




carbon monoxide, carbon dioxide, hydrocarbons and nitrogen oxides were




reduced by a manual procedure.  This procedure consisted of marking off




the various modes of the flight utilizing the hack marks recorded by the




operator, and taking an average reading for each mode.  These raw values




were corrected for altitude and converted to concentrations via cali-




bration curves made for the in-flight instrument calibrations.  The




resultant concentrations were averaged over the flight to arrive at an




average pollutant concentration per mode per plane.  Table 4-2 summarizes




the calculations performed on the data.




          The average stack concentrations were then reduced to a molar




carbon basis and emission rates in pounds per pound of fuel and pounds




per minute for each pollutant calculated.  This calculation is shown in




Table 4-2.  Also illustrated in Table 4-2 are calculation procedures to




determine the amount of afterburning.  The plume analyses for CO, C02




and THC were adjusted for background levels and then for dilution, and




compared with the appropriate stack concentrations.  Afterburning would




result in an increase in carbon dioxide levels with corresponding




decreases in carbon monoxide and hydrocarbon levels.
     SCOTT RESEARCH LABORATORIES, INC

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                                       Table 4-2.   Calculation Procedures


                                     Used in the Reduction of the Raw Data.
ALTITUDE CORRECTION OF AIRBORNE INSTRUMENT READINGS:



      Sea Level Bar. Pressure (atm.)
     Bar. Pressure at altitude (atm.)
                                      x Instrument reading at altitude = corrected reading
MASS EMISSION CALCULATIONS FOR POLLUTANT A:



     ni_  _   ...     .    Wt % C in Fuel    1    (Vol % A in exhaust) x Mn
     Ib Of A/lb Fuel = 	r—	 X — x -	rr^;	—:	A
                            100         12      Vol % C in exhaust



     where:


             Wt % C in fuel = Weight percent carbon in fuel



             Vol % C in exhaust = Volume percent of carbon containing compounds  in exhaust



                                    (Vol % CO2 + Vol % CO + Vol % THC as methane)



             Vol % A in exhaust = Volume percent of A in exhaust



             M  = Molecular weight of A
              A


     Also:



     Ib of A/min = (Ibs of A/lb Fuel) x (Ib Fuel/min)
CORRECTION OF PLUME SAMPLES FOR DILUTION:
     Dilution Factor =
                                          (Vol%CO2+Vol%CO+Vol%THC(as methane))  in stack
                       (Vol%CO2+Vol%CO+Vol%THC(as methane)) in plume  -  lVol%CO2+Vol%THC(as methane)) in air



     Corrected Plume Value for A = Dilution Factor X  (VOL%A in plume  -  Vol%A in air)

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                                   5-1







                5.0  RESULTS OF AIRCRAFT EMISSIONS TESTS




5.1  TAKEOFF-CRUISE-LANDING  (TCL) CYCLE




          In order to compile meaningful emissions data, it was first




necessary to establish an operating cycle for light aircraft.  The




takeoff-cruise-landing (TCL) cycle described in Table 5-1 was




developed based on discussion with pilots and several test flights.




The cycle was representative of light aircraft operation at Central




Bucks Airport.  However, since it may not be representative of




operations at other airports, additional cycle definition may be




needed.




          The time in each mode shown in Table 5-1 is approximate and




may vary from aircraft to aircraft.  Each mode has its own character-




istic power and mixture setting.  The power setting is a combination




of a throttle and propeller pitch setting, or in the case of an




aircraft with a fixed pitch propeller, a throttle setting alone.  The




mixture setting determines the engine air-fuel ratio.




          All modes are reasonably steady-state except for run-up,




cruise pattern and final approach.  These three modes are not steady




because of changing engine loads and pilot adjustments.  The rich




cruise mode is used during relatively short trips.  For longer trips




the air-fuel mixture is leaned to reduce fuel consumption once cruise




altitude had been reached.




          The cruise altitude during tests was usually 3,000 feet MSL.




Since higher performance aircraft, such as those with fuel injection and




turbocharging, generally cruise at higher altitudes, aircraft Mos. 5,




7, 8 and 9 were tested at a cruise altitude of 5,000 feet.
     SCOTT RESEARCH LABORATORIES, INC

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                                   5-2
               Table 5-1.  Takeoff-Cruise-Landing  Cycle

           Used in Study of Emissions  from  Ldght Aircraft.
     Mode
Taxi


Run-up



Ascent


Cruise, Rich


Cruise, Lean


Descent


Cruise Pattern

Final Approach

Final Taxi
       Description
Startup of engine and
taxi to end of runway

Checkout procedure at end
of runway, includes a run-
up of the engine

Takeoff and ascend to
cruise altitude

Rich cruise at cruise
altitude

Lean mixture cruise at
cruise altitude

Descend to landing pattern
altitude

Hold in landing pattern

Descend and land

Taxi back to hangar
Approximate
Time in Mode
 (minutes)

    4.5
    1.5
    6.5


    2.5


    7.5


    2

    2

    1.7
  SCOTT RESEARCH LABORATORIES, INC

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                                     5-3







  5.2  EMISSION TEST RESULTS




            The concentrations of carbon monoxide, carbon dioxide, hydro-




  carbons and nitrogen oxides found in the exhaust of the nine test aircraft




  are summarized in Table 5-3 along with stack gas temperatures.  Data are




  presented for the minimum, maximum and average for each of the nine modes




  in the TCL cycle.  Detailed data for each aircraft are given in the Appendix.




            The reported emission values are subject to random error due to




  differences in atmospheric conditions and pilot settings, and to random




  error inherent in the overall instrument system.  There is also a small




  systematic error introduced by the instrument system.  The systematic error




  was minimized by careful  calibration of the system.  The magnitude of the




  random error is indicated by the standard deviations of the data for




  individual flights.  The deviations were a function of the compound beinq




  measured, because of differences in the instruments used and the levels




  being measured, and the mode of operation, since certain modes were more




  reproducible than others.  The indicated precision of the emission data is




  shown in Table 5-2.




                   Table 5-2.  Precision of Emission Data








                           	    	    Precision*, %
   Parameter              Steady-State Modes           Non Steady-State Modes




Carbon Dioxide                    8                               8




Carbon Monoxide                  12                              12




Hydrocarbons                     11                              30




Nitrogen Oxides                  30                              50







*  One sigma limits  (1S% as defined in ASTM Recommended Practice F.177) .
       SCOTT RESEARCH LABORATORIES. INC

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RESEARCH LABORATOR
m
0







Table 5-3
Mode

Taxi - Initial
Idle (Run up)
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
Taxi - Final

Min.

5.20
6.41
6.86
5.43
0.47
5.72
5.38
4.30
3.62
C0(%)
Max.

11.69
10.35
9.91
10.19
4.80
10.98
10.89
8.39
10.00

Avg.

8.42
8.13
8.08
7.82
2.66
8.99
7.86
6.64
7.50

Min.

6.78
6.60
8.48
7.93
11.35
5.08
7.20
4.70
7.14
Summary of Exhaust
for
C02(%)
Max.

11.82
10.66
13.34
12.15
14.75
11.44
11.08
10.57
11.15
Composition Data
Nine Light Aircraft
Total HC(ppm-r)
Avg.

9.18
9.43
10.77
10.13
13.06
8.06
9.45
7.79
8.78
Min.

3270
2150
990
987
207
906
1140
2300
4080
Max.

15180
13080
3090
2730
1770
29000
5160
35000
27700
Avg.

7950
5820
2140
1850
966
6660
2950
16300
10500
NOx(ppm)
Min.

71
86
138
80
674
162
125
79
77
Max.

280
1220
600
612
4750
703
458
326
808
Stack Temp. (°F)
Avg.

128
355
334
213
2200
291
254
157
237
Min.

113
188
215
208
221
221
228
199
170
Max.

907
1150
1500
1450
1550
1380
1290
1010
889
Avrj .

6TS
849
1220
1190
1289
970
1090
759
642

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                                   5-5







5.3  EMISSION RATES




          The exhaust composition data were utilized to compute emission




rates on a basis of pounds of pollutant emitted per pound of fuel con-




sumed.  An average fuel composition of 85 weight % carbon and 15 weight %




hydrogen was assumed.  The computed emission rate data were converted to




pounds of pollutant emitted per minute using the measured fuel consumption




rates.




          Summaries of emission rates on a per pound of fuel basis and a




per minute basis are presented in Tables 5-4 and 5-5, respectively.  The




minimum, maximum and average emission rates for each operating mode are




given.  Detailed data for each aircraft are included in the Appendix.




          The air-fuel ratios shown in Table 5-4 and the Appendix were




estimated from the ratios of carbon monoxide to carbon dioxide measured




in the the exhaust.  The estimates were based on composition data for




an aircraft engine given in Figure 10-6, Page 317 of Reference 4.




          The total emissions per TCL cycle were calculated using the




time per mode shown in Table 5-1.  The emissions for a Landing-Takeoff




(LTO)  cycle were also calculated by omitting the cruise modes.  Total




emission data for each pollutant are presented in Table 5-6 for each




mode and test cycle.   Data for each test aircraft are given in the




Appendix.
     SCOTT RESEARCH LABORATORIES. INC

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8
en
30
O
00
o
§
30
m
_ Mode
t
Taxi - Initial
Idle (Run-up)
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
Taxi - Final
Table 5-4. Summary of Exhaust Emission Rates
for Nine Light Aircraft, Ib/lb fuel
Air-Fuel
Ratio*
(Ib/lb)
11.4
11.6
11.9
11.8
14.0
11.0
11.7
11.6
11.6
Emissions (Ib/lb Fuel)
Carbon Monoxide
Min.
.629
.746
.677
.740
.0792
.662
.778
.561
.475
Max.
1.170
1.167
.953
1.073
.560
1.186
1.175
.993
1.098
Avg.
.910
.896
.849
.859
.326
1.011
.917
.825
.853
Carbon Dioxide
Min.
1.07
1.21
1.59
1.40
2.22
0.90
1.22
1.18
1.23
Max.
2.08
1.90
2.04
1.95
3.01
2.08
1.89
1.96
2.30
Avg.
1.58
1.63
1.77
1.75
2.60
1.43
1.64
1.52
1.61
Hydrocarbons (as Hexane)
Min . Max . Avg .
.00175
.0123
.00521
.00518
.00179
.00536
.00645
.0148
.0247
.0819
.0680
.0053
.0163
.0110
.168
.0245
.189
.147
.0426
.0322
.0115
.0104
.00615
.0384
.0182
.1036
.0590
Nitroqen Oxides (as NO->)
Min.
.00122
.00233
.00226
.00136
.0135
.00288
.00214
.00137
.00140
Max.
.00565
.0235
.0127
.0137
.0977
.0130
.00855
.00699
.0195
Avg.
.00235
.00660
.00607 ^
.00422
.0463
.00535
.00477
.00343
.00502
            *  Estimated

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COTT RESEARCH LABORATORIES.
O







Table 5-5.
Summary of Exhaust Emission Rates
for Nine Light Aircraft, Ib/minute
Emissions (Ib/min)
Carbon Monoxide
Mode
Taxi - Initial
Idle (Run-up)
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
• Taxi - Final
Min.
.126
.351
.724
.621
.0568
.279
.306
.131
.0893
Max.
.407
.733
1.747
1.685
.665
1.109
1.256
.407
.396
Avg.
.223
.483
1.044
.943
.291
.536
.694
. 188
.196
Carbon Dioxide
Min.
.218
.571
1.73
1.31
1.81
.236
.742
.246
.231
Max.
.727
1.388
3.09
2.94
3.87
1.468
1.486
.550
.652
Avg.
.387
.885
2.13
1.85
2.22
.806
1.1C
.325
.363
Hydrocarbons (as
Min.
.00343
.00691
.00590
.00606
.00128
.00378
.00253
.00286
.00478
Max.
.0374
.0440
.0251
.0231
.0150
.0439
.0259
.0881
.0606
Hexane)
Avg.
.0116
.0184
.0144
.0115
.00555
.0147
.0146
.0240
.0161
Nitrogen Oxides
Min.
.000335
.000666
.00232
.00127
.0205
.000752
.00102
.000344
.000288
Max.
.00167
.00996
.0139
.0115
.0912
.00439
.00734
.00131
.00376
Avg.
.000597
.00329
.00718
.00417
.0376
.00234
.00413
.000647
.00103

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                                            5-8
                      Table 5-6.  Summary of Exhaust Emissions from Nine
Liqht Aircraft during Typical Operating Cycles
Mode
Taxi - Initial
Run-up
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
Taxi - Final
Total-TCL Cycle*
Total-LTO Cycle**
Mode Time
(Min.)
4.5
1.5
6
6.5
2.5
7.5
2
2
1.7
34.2
25.2

Carbon
Monoxide
1.00
.725
6.27
6.13
.764
4.02
1.39
.394 '
.334
21.0
14.1
Mode
Carbon
Dioxide
1.74
1.33
12.81
12.00
5.80
6.05
2.32
.678
.617
43.3
25.5
Emissions (Ib.)
Hydrocarbons
(as Hexane)
.0521
.0276
.0862
.0747
.0150
.110
.0820
.0452
.0274
.520
.431

Nitrogen Oxides
(as NO?)
.00269
.00493
.0442
.0271
.0988
.0651
.00827
.00144
.00174
.254
.128
*   Cycle as defined in Section 5.1.
**  Landing-Takeoff Cycle - as TCL cycle without cruise modes.
          SCOTT RESEARCH LABORATORIES. INC

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                                    6-1






                    6.0  DISCUSSION OF DATA COLLECTED




          The composition of the exhaust from a light, piston engine




aircraft is a complex function of the various fixed aircraft parameters,




such as engine type and airframe design, and the operating mode of  the




aircraft.  The aircraft selected for testing and the modes defined  in




the takeoff-cruise-landing (TCL) cycle allow evaluation of the effects




of many of these variables on the exhaust composition and the emission




rates.






6.1  EFFECT OF OPERATIONAL MODE ON EXHAUST EMISSIONS




          Light aircraft are generally operated with a rich mixture




setting during all operations except long cruise modes in which case




the mixture may be leaned to reduce fuel consumption.  Rich mixtures




are employed to protect the engine through cooler operation and to




provide for greater safety through more stable engine operation with




less chance of stalling than with stoichiometric mixtures.  In addition,




the pilot does not have to adjust the mixture control during the




critical operations of takeoff and landing.




          The exhaust composition resulting from the rich mixture




setting was relatively high in carbon monoxide as shown in Table 5-3.




The differences in carbon monoxide among the various rich modes were




small.  The hydrocarbons varied to a greater extent with the lowest




concentrations found at the high power settings used for ascent and




cruise, and the higher concentrations found at low power modes such




as descent, final approach and taxi.  The highest hydrocarbon con-




centrations occurred during final approach, a mode in which the engine
     SCOTT RESEARCH LABORATORIES, INC

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                                   6-2






absorbed energy through the propeller while idling as the aircraft  lost




altitude.  Nitrogen oxides concentrations showed little change from




one rich mixture mode to another.




          When the mixture was leaned during the cruise mode, a sub-




stantial reduction in carbon monoxide occurred along with a moderate




reduction in hydrocarbons, a moderate increase in carbon dioxide and




a very large increase in nitrogen oxides.  The emission rate of nitrogen




oxides at lean cruise exceeded the sum of the emission rates at the




other eight modes.




          As the aircraft's altitude increases, the decrease in ambient




air pressure might be expected to produce a richer air-fuel mixture




and thus less complete combustion.  However, the comparison data shown




in Table 6-1 indicate that cruise altitude had little effect on exhaust




emissions expressed as pounds per pound of fuel.  On the other hand,




it was noted that fuel consumption increased with altitude thereby




producing greater emissions per unit time.






       Table 6-1.  Effect of Cruise Altitude on Exhaust Emissions
Aircraft #3
Cruise @ 1,200'MSL
Cruise @ 3,000'MSL
Aircraft #1
Cruise @ 3,000'MSL
Cruise @ 4,500'MSL
Ib
CO
1.16
1.17
1.02
1.11
pollutant/lb fuel
CO?
1.24
1.23
1.44
1.36
THC
0.0258
0.0231
0.0280
0.0328
   SCOTT RESEARCH LABORATORIES. INC

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                                   6-3


          During warm, humid weather ice can form in the induction system

as an aircraft descends from cool air aloft into the humid air below or

as it passes through clouds.  To prevent ice from forming, the intake

air to the carburetor is heated in a heat exchanger using exhaust gas as

the source of heat.  Heating the intake air reduces the air-fuel ratio

and thus produces higher emissions.  This is illustrated in Table 6-2

where both carbon monoxide and hydrocarbons were about 30% higher when

the carburetor intake was heated than when it was not.  However, since

carburetor heat is generally used only for short periods of time, the

increase in total emissions is small.


      Table 6-2.  Effect of Carburetor Heat on Exhaust Composition

                         Air-fuel
                          Ratio        CO      CC>2        THC
       Aircraft #8       (Ib/lb)      (%)      (%)      (ppm-C)

     Descent with
     Carburetor Heat       10.6       10.6      8.0      3300

     Descent without
     Carburetor Heat       11.5        8.3     10.3      2500


6.2  THE EFFECT OF AIRCRAFT PARAMETERS ON EXHAUST EMISSIONS

          The aircraft tested in this program were selected to allow an

assessment of the effect of design differences on exhaust emissions.

Of particular interest was the effect of engine operating time, engine

size, engine induction system and airframe design on the composition of

the exhaust.  To quantify the comparisons made in this section, the

exhaust emissions as pounds of pollutant per pound of fuel were averaged

over the most reproducible rich modes of operation, specifically the

ascent,  rich cruise, descent and final taxi modes.  These comparisons
     SCOTT RESEARCH LABORATORIES, INC

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                                    6-4







are limited to exhaust  composition  and  do not take into account




differences in fuel  consumption  rates.







6.2.1  THE EFFECT OF ENGINE OPERATING TIME




          The effect of engine operating time,  that is the total number




of hours the engine  has been operated since its manufacture or last major




overhaul, is indicated  by  examining the emissions data for three similar




four cylinder and two similar six cylinder craft.  The data shown in




Table 6-4 indicates  that the effect of  engine age is small.  The




differences in pollutant levels  are probably due to engine settings rather




than engine use.







6.2.2  THE EFFECT OF ENGINE SIZE




          The Cessna 172 and 182 have similar airframes,  but the 182 is




heavier and has a larger engine.  The data presented in Table 6-4




indicates combustion in the larger  engines is more efficient.  The two




Cessna 182's emitted an average  of  15 percent less carbon monoxide and




49 percent less hydrocarbons per pound  of fuel than the three 172's.





                          Table 6-4. Effect of Engine Use
and Size on Exhaust
Emissions
Average Emissions Durinq Steady-State Modes
(Ib/lb Fuel)
Aircraft
#3
»1
*4
»6
*7
Cessna
Cessna
Cessna
Cessna
Cessna
172
172
172
182
182
Engine Power .
(HP)
150
150
150
235
235
Number of
Cylinders
4
4
4
6
6
Engine Use
(hrs)
672
140
105
1053
53
CO CO,
0
0,
1,
0.
0.
.820 1.79
,928 1.62
,011 1.46
766 1.88
789 1.87
THC
(as Hexajie)
0.0227
0.0184
0.0304
0.0128
0.0104
NOX
(as NO?)
0.00604
0.
0.
0.

,00822
00265
00207
.
   SCOTT RESEARCH LABORATORIES, INC

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                                    6-5







 6.2.3  THE EFFECT OF ENGINE INDUCTION SYSTEM




           A comparison of emission data for six cylinder engines with




 fuel injection and normal aspiration is made in Table 6-5.  The fuel




 injected engines in the Beechcraft 36 and Cessna 210 emitted  23 percent




 more carbon monoxide and 307 percent more hydrocarbons per pound of




 fuel than the Cessna 182's with normal aspiration.  There was  little




 difference between the emissions from the turbocharged Cessna  210  and




 the Beechcraft 36 without turbocharging.




                             Table 6-5. Effect of Engine
Induction System on exhaust Exi.aiona
Average Emissions During Steady-State Modes
(Ib/lb Fuel)
Aircraft
»6 Cessna 182
• 7 Cessna 182
• 5 Bonanza 36
»9 Cessna 210
Induction System
Normal Aspiration
Normal Aspiration
Fuel Injection
Fuel Injection,
Turbocharged
Engine Power
(HP)
230
230
285
28)
CO COj
0.776 1.88
0.789 1.87
0.994 1.43
0.955 1.49
(as
0
0
0
0
THC
Hexane)
.0128
.0104
.0462
.0482
NOX
(as NOi)
0.00207
-
0.00232
0.00380
 6.2.4   THE EFFECT OF AIRFRAME DRSIGN




           Two distinctly different airframes with similar engines were




 included  in the  test program.   Both the Cessna 172 and Piper ^A-23




 utilized  4 cylinder, 150 HP engines.  The Cessna 172 was a high wing




 monoplane  with fixed tricycle landing gear,  while the Piper PA-23




 was  a  low  wing twin-engine  aircraft with retractable landing gear.




           The  Piper  also had' an  ejector type exhaust.   The ejector




 exhaust is  a  venturi-shaped duct placed around the exhaust stack with




 the  stack  ending  at  the  venturi  throat.   The rear end  of the duct is




open to the atmosphere and  the front end is  open  to  the engine com-




partment.  The high  speed flow from the  engine exhaust stack draws
     SCOTT RESEARCH LABORATORIES, INC

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                                    6-6
 ambient  air over the engine thereby cooling  it with  little or no


 additional  drag.   The air also passes over the exhaust  stacks and


 cools  the exhaust gases.  This is evident by the  temperatures of


 approximately  200°F found at the stack sampling point.


          The  data presented in Table 6-6 show that  the emissions


 from the Piper were slightly lower in carbon monoxide and hydrocarbons


 than any of the three Cessna 172's.  However, it  is  not possible to


 draw firm conclusions based on one aircraft.


                            Table 6-6.  Effect of Airframe
Design on Exhaust
Emissions

Average Emissions During Steady-State Modes
(Ib/lb Fuel)
Aircraft
»3 Cessna 172
»1 Cessna 172
«4 Cessna 172
US Piper Apache
Airframe Design
High wing mono-
plane with fixed
landing gear.
U>w wing twin engine
Engine Use
(hrs)
672
140
105
423
CO CO?
0.820 1.78
0.928 1.62
1.011 1.46
0.736 1.93
THC
(as Hexane)
0.0227
0.0184
0.0304
0.0163
NOX
(as NO?)
0.00604
0.00822
0.00265
-
              landing gear and
              exhaust ejector.



6.3  COMPARISON OF EMISSIONS FROM LIGHT AIRCRAFT AND AUTOMOBILES


          The engines and fuels used in light aircraft  are  similar to


those employed in  automobiles so that a comparison of emissions  from


these two sources  may be  made.   The emission rates for  light  aircraft


obtained in this study are compared to present and projected  rates for


automobile exhaust in Table 6-7 on a basis of pounds of pollutant  per


pound of fuel.
   SCOTT RESEARCH LABORATORIES, INC

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                                   6-7
                     Table 6-7.  Comparison of Light
                    Aircraft and Automobile Emissions
                                    Ib pollutant/lh fuel consumed
Present Uncontrolled
Light Aircraft*

Uncontrolled
Automobiles**

Automobiles Meeting
1972 Federal Stds.**

Automobiles Meeting
Proposed HEW 1975
Federal Standards**
                           Carbon
                          Monoxide
0.847
0.525
0.176
0.050
             Hydrocarbons
              as Hexane
0.0210
0.066
0.015
0.002
              Nitrogen Oxides
                     as
              Nitrogen Dioxide
  0.0102
  0.018
No Standard
  0.0041
*   Average value for aircraft operated over TCL cycle described  in Table  5-1,
**  Reference 6 - Average values for automobiles operated over new Federal
    urban driving cycle assuming 12 miles per gallon of gasoline.
     SCOTT RESEARCH LABORATORIES. INC

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          Carbon monoxide emissions  from  light aircraft were  approximat tvly




60 percent higher than uncontrolled  automobiles and nearly five times  as




high as allowable emissions for 1972 automobiles.  Hydrocarbon emissions




 from current  aircraft were only slightly  higher  than  1972  automobile




 standards.  However, ground operations  of aircraft produced hydrocarbons




 at approximately twice the rate of  the  TCL cvcle.  Nitrogen oxides




 emissions from  aircraft, expeciallv  on  the ground, were not much  hiqher




 than proposed 1975  standards.  However, continued attention must  be paid




 to nitrogen oxides  since control  techniques for  carbon monoxide and




 hydrocarbons  could  increase aircraft nitrogen oxides  emissions.







6.4  AFTERBURNING




          Afterburning can take place when  very hot exhaust gases  con-




taining high  concentrations of carbon monoxide and hydrocarbons come




in contact with air.  This combustion could eliminate much of the  carbon




monoxide, hydrocarbons, hydrogen and carbonaceous particles present  in  the




exhaust.  Natural afterburning at the end of the aircraft exhaust  stack




would provide a convenient means of pollution control.  It would be




expected that afterburning would occur most readily at the high exhaust




temperatures  and rich mixtures present during the ascent and  rich  cruise




modes.




          Samples of the exhaust plume were taken downstream of the




exhaust stack during the initial taxi/  ascent, rich cruise and descent




modes.   The plume composition was corrected for dilution by carbon




balance after correcting for ambient air concentrations of carbon  dioxide




and hydrocarbons.  The corrected plume concentrations are compared to
   SCOTT RESEARCH LABORATORIES, INC

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                                   6-9
the corresponding stack values in Table A-37 in the Appendix.  A frequency




distribution of the net change in carbon dioxide concentration is shown




in Figure 6-1.  The figure shows a near normal distribution of data




points.  The difference between corrected plume and stack data was ten




percent or less for ninety percent of the test points.  This range covers




the expected level of random error.  A study of those points showing a




carbon dioxide increase of fifteen percent or more indicates that they




are widely distributed over aircraft and operating modes and thus the




result of random data error and not afterburning.




          The changes in hydrocarbons given in Table A-37 exhibit greater




dispersion than the changes in carbon dioxide and carbon monoxide.  This




is due to greater fluctuation of hydrocarbons during steady-state modes




and less precision in the plume measurements.  However, there is no




evidence of any consistent reduction in hydrocarbon emissions for any




aircraft or operating mode.




          The fact that no afterburning was found in this study is




plausible when the exhaust gas temperatures are examined.  The highest




temperatures occurred during ascent and cruise where values as high as




1500°F were recorded at the stack sampling point.  Cooling undoubtedly




occurred between the sampling point and the end of the stack.  Thus,




the temperature at the point where air needed for afterburning first




came in contact with the exhaust was too low for burning to take place.




          One means of enhancing afterburning would be to minimize the




distance from the engine manifold to the exhaust vent.  This exhaust




configuration was used on many radial piston engine aircraft for which




visible afterburning was reported at the exhaust vents.  Afterburning




might also be enhanced by insulation of the exhaust system.





     SCOTT RESEARCH LABORATORIES, INC

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s
o
X
o
38
                                                                    Figure  6-1.  Distribution of % change

                                                                     in CO? concentration  from stack to

                                                                      plume from afterburning analysis
           60-
                                                                                                           o
                                                                                                           I
                                                           « • • * *
                                                          IvXv!
>.
u
c
0)
a
o1
0)
           40-
•*««** ***«*«
>*«•>**• ******
****** *••*•*
* • * » • • »**«**
• * * * * « ******



Xv.v. •.•.•/.•.•.
       l    20-
                                         vv«
                                        •*•*** »*»**f|
                                        *» » * » «
                                             ,
                                        * * * * *•*•
                                        * • •!* ***.
                                                     * * * * *
                                                    ******
                                                     •*••«•
                                            .v.v.v-
                                            Xv*Xv vXvX
                                                ; ^gx
                                                '.' ».«•»«..
                15orless   -10       -5          0           *5         +10   +15ormorc
                              % Change   in CO«  concentration

-------
                                   6-11
6.5  CONTROL TECHNIQUES FOR AIRCRAFT EMISSIONS




          In addition to natural afterburning, techniques which have been




applied to automobile exhaust are potentially applicable to aircraft exhaust.




However, greater constraints are placed on the design of an aircraft




control system as compared to one suitable for automobiles.  Aircraft




safety must not be impaired in any manner.  This means that engine performance




cannot be reduced, any heat generated must be safely dissipated, and




additional weight and power requirements must be minimal.  On the other




hand, high temperatures must be maintained and substantial amounts of




air added to achieve combustion of exhaust products.




          While leaning of the engine mixture was shown to result in




substantial reductions in carbon monoxide and hydrocarbons at the cruise




mode, this cannot be done safely with the present engine design at the




high performance modes such as ascent.  The mixture could possibly be




leaned during ground operations, but a large increase in nitrogen oxides




emissions would be anticipated.




          Exhaust reactors can be applied in principle to aircraft




emissions.  The volume of air required for complete combustion of the




carbon monoxide, hydrocarbons and hydrogen in the exhaust would be as




great as 50 percent of the total exhaust volume at rich modes.  A pump




capable of supplying this large volume of air would be heavy and require




additional power thus limiting its practicability.  It would appear that




the air would best be supplied by the ram air pressure generated by the




aircraft motion.  The incoming air would have to be heated, preferably




in a heat exchanger with heat supplied by the reactor effluent, in




order to maintain combustion in a thermal reactor.  This may prove
     SCOTT RESEARCH LABORATORIES, INC

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                                   6-12







difficult  at ground level modes where exhaust temperatures are relatively




low.  A catalytic reactor could be used to obtain combustion at lower




temperatures, but with added catalyst bed weight and cost.  The lead




present in the exhaust would limit catalyst life but this could be over-




come by the use of unleaded fuel.




          In summary, the technology which has been developed for




controlling automobile exhaust emissions will be valuable in developing




control techniques for aircraft emissions.  However, a number of con-




straints unique to aircraft will make it necessary to carry out additional




design efforts to adapt the techniques and hardware utilized for auto-




mobiles for satisfactory performance in aircraft.  In the meantime,




proper engine maintenance and setting of the air-fuel mixture to the




minimum richness required for safe operation would be beneficial in




minimizing aircraft exhaust emissions.





6.6  CONCLUSIONS




          As a result of this study of nine light aircraft, the following




conclusions can be drawn:




      1.  The light piston engine aircraft tested emitted exhaust




          containing levels of carbon monoxide higher than




          uncontrolled automobiles and substantially higher than




          standards set for 1972 vehicles in terms of pounds of




          pollutant per pound of fuel.  Hydrocarbon emissions




          from the test aircraft were in the range emitted by




          current controlled automobiles.   Aircraft nitrogen




          oxide emissions were low except during lean mixture




          operation.
   SCOTT RESEARCH LABORATORIES. INC

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                                  6-13
      2.  Carbon monoxide and hydrocarbon emissions can be




          substantially reduced by leaning the aircraft air-




          fuel mixture, but this is not done because it




          increases the possibility of engine stalling.




      3.  Fuel injected engines of current design emitted much




          higher concentrations of hydrocarbons than normally




          aspirated engines.  The effect of other aircraft




          parameters such as use time, engine size, and




          airframe design, on exhaust composition was  small.




      4.  No natural afterburning of carbon monoxide




          or hydrocarbons occurred in the exhaust from




          the light aircraft tested during any operating




          mode.




      5.  Analytical instrumentation packages are avail-




          able to monitor exhaust emissions of  light




          aircraft during actual flight operation.






6.7  RECOMMENDATIONS FOR FUTURE STUDIES




          Future investigations related to light aircraft emissions




should be concentrated in two areas:   the contribution of light air-




craft emissions to pollution levels in the vicinity of airports and




the feasibility of various control techniques for reducing exhaust




emissions.




          Work on aircraft contributions to pollution  levels rhould




obtain information on typical operations at a number of airports and




thus improve upon the TCL cycle developed in the current study.  Special
     SCOTT RESEARCH LABORATORIES. INC

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 emphasis  should  be  placed  on  operations at or near ground level with




 attention also focused on  the dispersion of pollutants  in the  atmosphere




 surrounding the  airports.




          The evaluation of control techniques  should investigate the




potential schemes discussed in the previous section.  It  "hould include




enhancement of natural afterburning via increased  temperatures at the




stack vent.  Both thermal  and catalytic reactors  should be tested.




Because of the importance  of temperature in control device performance,




and because actual inflight heat transfer  is difficult  to simulate in




a test cell, the evaluations would best be accomplished in actual




flight tests.
   SCOTT RESEARCH LABORATORIES. INC

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                                   7-1
                             7.0  REFERENCES

1.  "Nature and Control of Aircraft Engine Exhaust Emissions"
    Report of the Secretary of Health, Education & Welfare to the
    United States Congress; December, 1968.

2.  "Nature and Control of Aircraft Engine Exhaust Emissions"
    Report prepared by Northern Research and Engineering Corporation
    for the National Air Pollution Control Administration under
    Contract No. PH22-68-27.

3.  "Standard Specifications for Aviation Gasolines" ASTM Standards
    (D910-70),  Part 17, November, 1970.

4.  "Internal Combustion Engines Analysis and Practice" Second
    Edition by  Edward F. Obert.

5.  "Aviation Statistics (Interum Report}", Office of Management
    Systems, Information and Statistics  Division, FAA/DOT,
    September,  1970.

6.  "Congressional  Record-Senate", September 21, 1970, pg. S16113.
     SCOTT RESEARCH LABORATORIES, INC

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                                  A-l
                           Appendix of  Data
SCOTT RESEARCH LABORATORIES, INC

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              Table A-l




Composition of  Light Aircraft Exhaust
if!
O
90
m
30
O
X
r-
i
30
i
2
m
O





MODE: Taxi - initial


1.
2.
2.
3.
4.
5.
6.
7.
a.
9.
Plane

Cessna 172K
(Right) - Cessna 172D
(Left) - Cessna 172D
Cessna 1721
Cessna 172K.
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
CO

8.68
10.85
10.45
5.20
11.69
8.46
6.97
7.92
7.39
8.88
002

7.79
7.03
7.02
10.92
6.78
9.60
11.82
10.82
8.51
9.50
THC
(ppm-C)

4650
9450
4050
3780
14670
15180
3630
3270
3525
16020
NOX
(ppm)
74
109
88
157
107
99
71
90
280
171
Stack
Temp. (°F)

630
643
653
631
774
747
907
753
113
512
                                                                                KJ

-------
              Table A-2




Composition of Light Aircraft Exhaust
i
30
m
in
r*i
33
n
r-
00
c
1
30

o




MODE
1.
2.
2.
3.
4.
5.
6.
7.
a.
9.
: Run-up
Plane
Cessna 172K
(Right) - Cessna 172D
(Left) - Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
CO
-
10.35
9.69
6.41
8.53
8.63
8.09
7.23
7.78
8.33
C02
-
6.81
6.40
10.39
8.71
9.72
10.66
10.45
8.89
10.01
THC
(ppm-C)
-
5670
4410
3540
8460
13080
3810
2150
3300
7080
NOX
(ppm)
360
120
292
320
140
86
260
1220
280
Stack
Temp. (OF)
-
849
892
855
1030
916
1150 >
i
GO
967
188
815

-------
              Table A-3




Composition of Light Aircraft Exhaust
m
C/l
8
30
m
m
•a
n
t-
00
o
30
H
0
30
-
0





MODE: Ascent
Plane

1.


2.
2.

3.
4.

5.
6.
7.
8.
9.

Cessna


(Right)

172K


- Cessna 172D
(Left) - Cessna 172D

Cessna
Cessna

Bonanza
Cessna
Cessna

1721
172K

36
182H
182N
Piper Apache
Cessna
210
CO

6.


8.
7.

9.
8.

8.
7.
6.
6.
9.

88


34
76

41
64

64
39
86
96
91
C02

8


8
8

10
9

10
12
12
13
11

.48


.15
.85

.83
.64

.10
.45
.43
.34
.14
THC
(ppm-C)

1550


3180
2350

2610
1640

2840
1740
990
2050
2770
NOX
(ppm)

600


4R5
678

483
217

201
138
202
-
247
St.-ick
Temp. (°F)

1 ~\'/D


I )1"
IV.n

Win
140',

ran
I'iOO
MOO
'/.I*.
M>

-------
                                                    Table  A-4




                                      Composition  of Light Aircraft Exhaust
SI MODE: P.ich
Cruise - 3,000'
CO
C02
2 Plane . (%) (%)
30
pn
t/i
m
30
n
LABOR,
*-
O
30
?
P




1.
2.
2.
3.
4.
5.
6.
7.
8.
9.
Cessna
(Right)
(Left)
Cessna
Cessna
Bonanza
Cessna
Cessna
172K
- Cessna 172D
- Cessna 172D
1721
172K
36*
182H
182N*
Piper Apache *
Cessna
210*
5.
7.
8.
7.
7.
10.
7.
8.
7.
8.
43
31
36
45
30
19
35
75
28
83
9.
3.
7.
10.
9.
8.
11.
10.
12.
10.
14
46
39
49
99
48
80
6
15
61
THC
(ppn-C)
1250
2580
2520
1970
1320
2730
1370
987
2060
2370
NO
(ppm)
612
330
387
164
85
85
80
112
-
208
Stack
Temp. (°F)
1260
1290
1290
1220
1350
1240
1450 >
i
1430
208
1260
*  Cruise at .5,000',  all others at 3,000'

-------
                                                    Tahle A-5




                                      Composition of Light Aircraft Exhaust
am
M MODE: Lean Cruise - 3,000'
-> Plane
73
m
m
33
n
X
CD
O
30
H
0
30
J"
Z
0







1.


2.
2.

3.

4.

5.
6.
7.
8.
9.


Cessna


(Right)
(Left)

Cessna

Cessna



172K


- Cessna 172D
- Cessna 172D

1721

172K

Bonanza 36 *
Cessna
Cessna
182H
182N *
Piper Apache *
Cessna
210*
CO


0.


—
2.

2.

3.

4.
3.
1.
3.
2.


47



64

24

09

80
02
61
20
91
CC-2


11.


—
.* 11.

13.

13.

12.
14.
14.
13.
13.


35



41

2G

40

12
75
29
64
36
THC
(ppm-C)


207


~
1520

879

795

1770
789
435
696
1580
NOX
(ppm)


2050


~
1880

2030

1910

1360
2900
4750
-
674
Stack
Temp. (OF)


1410



1440

1310

1470

1340
1550
1530
221
1310
*  Cruise at 5,000',  all others at 3,000'

-------
              Table A-6




Composition of Light Aircraft Exhaust
m
mm MODE: Descent
f.
n
50
m
m
50
n
X
r-
00
0
50
25
o
50
m
n







1.

2.
2.

3.

4.
5.
6.

7.
8.
9.

Plane
Cessna 172K

(Right) - Cessna 172D
(Left) - Cessna 172D

Cessna 1721

Cessna 172K
Bonanza 36
Cessna 182H

Cessna 182N
Piper Apache
Cessna 210
CO
(%)
9.32

9.50
9.92

9.28

10.98
10.41
8.08

5.72
6.83
10.57
C02

6.32

5.07
5.09

7.42

6-77
7.25
10.48

11.44
9-76
7.99
THC
(ppm-C)
4630

30400
27700

6180

7170
4410
1900

906
1970
3720
NOX
(ppm)
180

945
460

385

162
162
186

-
-
256
Stack
Temp. (°F)
743

1100
1130

803

894
1150
1330 >
-j
1380
221
1090

-------
              Table A-7




Composition of Light Aircraft Exhaust
mm
1
so
m
in
m
n
r-
DO
O
SO
H
O
50
5
o






MODE: Pattern
Plane
1.

2.

2.

3.
4.

5.
6.

7.
8.
9.
Cessna

(Right)

(Left)

Cessna
Cessna

Bonanza
Cessna

Cessna
172K

- Cessna 172D

- Cessna 172D

1721
172K

36
182II

182N
Piper Apache
Cessna
210
CO
-

8.

8.

7.
6.

9.
8.

7.
6.
10.


07

78

55
88

63
20

04
73
89
C02
-

9.

7.

9.
8.

8.
10.

10.
9.
7.


30

84

64
50

78
66

89
70
20
THC
(ppm-C)
1410

4650

5670

3030
3780

3390
2460

1140
2160
3990
NOX
(PPM)
-

500

415

255
324

150
125

—
-
212
Stack
Temp. (°F)
-

1290

1270

1070
1170

1190
1260 >
i
03
1290
228
1040

-------
              Table A-8




Composition of Light Aircraft Exhaust
m
1H MODE: Final Approach
8
30
[/>
30
n
LABORATOR]
f
2
p





1.
2.
2.
3.
4.
5.
6.
7.
8.
9.
Plane
Cessna 172K
(Right) - Cessna 172D
(Left) - Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
CO
6.54
-
5.09
4.30
6.26
8.26
5.38
7.87
7.70
8.39
C02
7.31
-
4.70
9.47
7.20
7.11
10.57
9.13
7.97
6.62
THC
(ppm-C)
14900
-
14500
15100
27600
35000
9570
9450
2300
18500
NOX
(ppm)
120
-
185
326
182
79
86
-
-
121
Stack
Temp. (°F)
558
-
729
740
809
1010
995 >
i
995
199
800

-------
              Table A-9




Composition of Light Aircraft Exhaust
1 SCOTT RESEARCH U
00
0
30
s
30
0





MODS
1.
2.
2.
3.
4.
5.
6.
7.
8.
9.
: Taxi - Final
Plane
Cessna 172K
(Right) - Cessna 172D
(Left) - Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
CO
7.66
9.88
9.78
3.62
10.00
8.07
6.74
8.18
4.88
8.50
C02
8.31
7.16
7.12
11.15
7.18
8.49
10.8
9.70
8.31
7.94
THC
(ppm-C)
4080
10500
7350
4500
11700
24100
4350
4620
4290
27700
NOX
(ppm)
140
280
145
288
126
83
77

808
158
Stack
Temp. (°F)
551
599
623
594
690
768
889 >
840 °
170
667

-------
           Table »-10




Light Aircraft Exhaust Emissions
r RESEARCH LABORATORIES. INC










MODE: Taxi - Initial
Aircraft
Number
1
2 (Right)

2 (Left)
3
4
5
6
7
8
9
Type
Cessna 172K
Cessna 172D

Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Air-Fuel
Ratio
Clb/lb)
11.0

10.3

12.8
10.0
11.5
12.3
11.9
11.6
11.4

Carbon
Monoxide
1.022
1.150

1.166
0.629
1.170
0.862
0.726
0.829
0.907
0-887
Emissions
Carbon
Dioxide
1.44
1.17

1.23
2.08
1.07
1.54
1.94
1.78
1.64
1.49
(Ib/lb Fuel)
Hydroc arbons
(as Hexane)
.0280
.0513

.0231
.0233
.0751
.0792
.0194
.0175
.0222
.0819

Nitrogen
Oxides (as NO2)
.00143
.00190

.00200 >
.00312 ^
.00176
.00166
.00122
.00155
.00565
.00281

-------
           Table A-ll




Light Aircraft Exhaust Emissions
30
t*l
tfl
m
= MODE: Run-up
CO
O
30
2 Number
8 *
2 (Right)

2 (Left)
3
4
5
6
7
8
9
Aircraft
Type
Cessna 172K
Cessna 172D

Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Air-Fuel
Ratio
Clb/lb)
-

10.3

12.3
11.3
11.5
11.9
12.0
11.5
11.7

Carbon
Monoxide
-
1.165

1.169
0.746
0.941
0.876
0.844
0.806
0.913
0.872
Emissions
Carbon
Dioxide
-
1.20

1.21
1.90
1.51
1.55
1.75
1.83
1.64
1.65
(Ib/lb Fuel)
Hydrocarbons
(as Hexane)
-
.0327

.0272
.0211
.0478
.0680
.0203
.0123
.0198
.0380

Nitrogen
Oxides (as NC-2)
-
.00666

.00238
.00558
.00580
.00233
.00147
.00476
.0235
.00482

-------
           Table A-12




Light Aircraft Exhaust Emissions
r RESEARCH LABORATORIES. 1!
P









MODE: Ascent
Aircraft
Number
1
2 (Right)

2 (Left)
3
4
5
6
7
8
9
Type
Cessna 172K
Cessna 172D

Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Air-Fuel
Ratio
Clb/lb)
11.7

11.4

11.6
11.5
11.6
12.3
12.5
12.6
11.5

Carbon
Monoxide
.885
.986

.919
.916
.935
.906
.737
.706
.677
.927
Emissions
Carbon
Dioxide
1.71
1.52

1.65
1.66
1.64
1.66
1.95
2.01
2.04
1.64
(Ib/lb Fuel)
Hydrocarbons
(as Hexane)
.0102
.0230

.0143
.0130
.00909
.0153
.00886
.00521
.0102
.0133

Nitrogen
Oxides (as NOj
.0127
.00942

.0132 *
.00772 ^
.00386
.00346
.00226
.00342
-
.00380

-------
SCOTT RESEARCH
LABORATORIES,
P










.1. «-*j_* _i- ^ n JL j
Light Aircraft Exhaust Emissions
MODE: Rich Cruise

Number

1
2 (Right)

2 (Left)
3
4
5
6
7
8
9
Aircraft
Type

Cessna 172K
Cessna 172D

Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36 *
Cessna 182H
Cessna 182N *
Piper Apache *
Cessna 210 *

Air-Fuel
Ratio
Clb/lb)

12.3

11.3

12.0
11.9
10.8
12.2
11.5
12.3
11.7


Carbon
Monoxide

.737
.910

1.042
.820
.836
1.073
.760
.898
.740
.895

Emissions
Carbon
Dioxide

1.95
1.66

1.45
1.81
1.80
1.40
1.92
1.71
1.94
1.69

(Ib/lb Fuel)
Hydrocarbons
(as Hexane)

.00862
.0164

.0161
.0111
.00772
.0147
.00726
.00518
.0107
.0123


Nitrogen
Oxides (as NO2)

.0137
.00675

.00793
.00296
.00160
.00147
.00136
.00189
-
.00346
*  Cruise at 5,000', all others at 3,000'.

-------
                                                Table A-14
SCOTT RESEARCH
LABORATORIES, INC









Light Aircraft Exhaust Emissions
MODE: Lean Cruise

Number
1
2 (Right)

2 (Left)
3
4
5
6
7
8
9
Aircraft
Type
Cessna 172K
Cessna 172D

Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36 *
Cessna 182H
Cessna 182N *
Piper Apache *
Cessna 210 *

Air-Fuel
Ratio
Clb/lb)
15.1
13.9

14.3
13.8
13.1
14.0
14.8
13.8
13.9


Carbon
Monoxide
.0792

-.371
.286
.372
.560
.338
.202
.378
..353

Emissions
Carbon
Dioxide
3.01

2.52
2.67
2.54
2..22
2.59
2.81
2.53
2.55

(Ib/lb Fuel)
Hydrocarbons
(as Hexane)
.00179

.0110
.00575
.00490
.0106
.00451
..00279
.00420
.00985


Nitrogen
Oxides (as NO^
.0566

.0434 :
1
.0426
.0377
.0261
.0533
.0977
-
.0135
Cruise at 5.000', all •: ;:h^r   at  3,000'.

-------
§
30
m
t*i
30
n
3C
r~
i
30
VTORIES. INC















MODE: Descent


Number
1
2 (Right)
2 (Left)
3
4
5
6
7
8
9

Aircraft
Type
Cessna 172K
Cessna 172D
Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
             Table A-15

   Light  Aircraft Exhaust Emissions
Air-Fuel
 Ratio
db/lb)

  10.4
   9.8


  10.7

  10.2

  10.4

  11.8

  12.7

  12.0

  10.6
 Carbon
Monoxide

 1.155

 1,076

 1.113

 1.069

 1.186

 1.147

  .860

  .662

  .812

 1.114
                  Emissions  (Ib/lb Fuel)
Carbon
Dioxide

 1.23

  .90

  .90

 1.34

 1.15

 1.26

 1.75

 2.08

 1.82

 1.32
Hydroc arbo ns
 (as Hexanel

    .0294

    .176

    .159

    .0364

    .0397

    .0249

    .0104

    .00536

    .0120

    .0200
  Nitrogen
Oxides(as

    .00366

    .0176

    .00848

    .00729

    .00288

    .00293

    .00325
CTi
    .00443

-------
3
RESEARCH L
00
O
o
30
m
~
o











MODE: Pattern

Number

1

2 (Right)
2 (Left)
2
4
5
6
7
8
9
Aircraft
Type

Cessna 172K

Cessna 172D
Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
             Table A-16

  Light Aircraft Exhaust Emissions
Air-Fuel
 Ratio
llb/lb)
  11. 3


  11.8

  11.7

  11.0

  11.8

  12.2

  12.0

  10.3
 Carbon
Monoxide
  .903

 1.019

  .861

  .871

 1.025

  .856

  .778

  .807

 1.175
                  Emissions (Ib/lb Fuel)
Carbon
Dioxide
 1.64

 1.43

 1.73

 1.69

 1.47

 1.75

 1.89

 1.83

 1.22
Hydrocarbons
 (as Hexane)
    .0266

    .0337

    .0177

    .0245

    .0185

    .0132

    .00645

    .0133

    .0220
  Nitrogen
Oxides(as NO2
    .00919

    .00791

    .00478

    .00674

    .00262

    .00214
                                                                     .00376

-------
1
RESEARCH LAB
o
90
>
o
X
tn
J«
P











raoie A-I /
Light Aircraft Exhaust Emissions
HODS: Final Approach


Number

1
2 (Right)

2 (Left)

3
4
5
6
7
8
9

Aircraft
Type

Cessna 172K
Cessna 172D

Cessna 172D

Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Air-Fuel
Ratio
Ub/lb)

11.5

11.1


12.8
11.6
10.9
12.7
11.6
11.3
10.8

Carbon
Monoxide

.851
-

.904

.561
.770
.874
.635
.875
.966
.993
Emissions
Carbon
Dioxide

1.49
-

1.31

1.94
1.39
1.18
1.96
1.60
1.57
1.23
(Ib/lb Fuel)
Hydrocarbons
(as Hexanel

.0992
-

.131

:101
.174
.189
.0578
.0538
.0148
.112

Nitrogen
Oxides (as NO2)

.00256
-

.00540 >
i
00
.00699
.00368
.00137
.00167
-
-
.00235

-------
i
RESEARCH I
CD
)RATOH1ES, 1
O











MODE: Taxi - Final


Number
1

2 (Right)
2 (Left)
3
4
5
6
7
8
9

Aircraft
Type
Cessna 172K

Cessna 172D
Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
             Table A-18

  Light Aircraft Exhaust Emissions
Air-Fuel
 Ratio
Ub/lb)

  11.4
  10.5


  13.4

  10.5

  11.4

  12.2

  11.6

  12.4

  11.1
 Carbon
Monoxide

   .933

 .1.090

 1.106

   .475

 1.087

   .349

   .748

   .890

   .715

   .883
                  Emissions (Ib/lb Fuel)
Carbon
Dioxide

 1.59

 1.24

 1.27

 2.30

 1.23

 1.40

 1.88

 1.66

 1.91

 1.30
Hydrocarbons
 (as Hexane)

    .0254

    .0591

    .0426

    .0302

    .0651

    .130

    .0247

    .0257

    .0322

    .147
  Nitrogen
Oxides (as NO2)

    .00280

    .00507

    .00270

    .00620

    .00225

    .00143

    .00140



    .0195

    .00270

-------
                                                 Table A-19




                                      Light Aircraft Exhaust Emissions
• RESEARCH LABO
33
O
33
2
O











MODE: Taxi
- Initial
Aircraft
Number
1


2 (Right)

2 (Left)

3
4
5
6
7
8
9
Type
Cessna 172K


Cessna 172D
}
Cessna 172D

Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Fuel Flow
Rate
(Ib/min)
.204*



.204*


.204*
.204
.472
.177
.216
.296
.243
Emissions (Ib/min)
Carbon
Monoxide
.208



.236


.128
.239
.407
.126
.179
.268
.216
Carbon
Dioxide
.294



.245


.424
.218
.727
.343
.384
.485
.362
Hydrocarbons
(as Hexanel
.00571



.00759


.00475
.0153
.0374
.00343
.00378
.00657
.0199
Nitrogen
Oxides (as NO2)
.000292



.000398

i
.000636 o
.000359
.000784
.000216
.000335
.00167
.000683
* Fuel Flow estimated from measurements on Aircraft #4..

-------
                                                  Table  A-20
                                            Exhaust Emission Rates
                                              for Light Aircraft
-5
a
ITj
£ MODE: Run-up
n
§ Aircraft
> Number
1 1
p 2 (Right)
2 (Left)
3
4
5
6
7
8
9
Type
Cessna 172K
Cessna 172D
Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Fuel Flow
Rate
Clb/minl
-

.470*
.470*
.470
.647
.455**
.562**
.424**
.841**
Emissions (Ib/min)
Carbon
Monoxide
-

.548
.351
.442
.567
.382
.453
.387
.733
Carbon
Dioxide
-

.571
.893
.710
1.003
.793
1.028
.697
1.388
Hydrocarbons
Cas Hexanel
_

.0141
.00992
.0225
.0440
.00920
.00691
.00840
.0320
Nitrogen
Oxides (as NO?.)

.00212
.00262
.00273
.00151
.000666
.00268
.00996
.00405
 * Fuel Flow estimated from measurements on  Aircraft  #4.
** Fuel Flow estimated from measurements on  other  aircraft

-------
                                                 Table A-21
                                           Exhaust Emission Rates
                                             for Light Aircraft
RESEARCH LABORATORIES, II
P










MODE: Ascent
Aircraft
Number
1

2 (Right)

2 (Left)
3
4
5
6
7
8
9
Type
Cessna 172K

Cessna 172D
1
Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Fuel Flow
Rate
Clb/minl
1.093*


1.093*

1.093*
1.093
1.479
1.028
1.133
1.069
1.885
Emissions (Ib/min)
Carbon
Monoxide
.967


1.041

1.001
1.022
1.340
.758
.800
..724
1.747
Carbon
Dioxide
1.87


1.73

1.81
1.79
2.46
2.00
2.28
2.18
3.09
Hydrocarbons
(as Hexane);
.0111


.0204

.0142
..00994
.0226
.00911
.00590
.0109
.0251
Nitrogen
Oxides (as NO?)
.0139


.0124

.00844
i
.00422 K
.00512
.00232
.00387

.00716
* Fuel Flow estimated from measurements  on Aircraft  #4.

-------
                                                   Table  A-22
                                             Exhaust Emission Rates
                                               for Light Aircraft
T RESEARCH LABORATORIES,
P









MODE: Rich Cruise
Aircraft
Number
1
2 (Right)

2 (Left)
3
4
5
6
7
8
9
Type
Cessna 172K
Cessna 172D
}
Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Fuel Flow
Rate
Clb/minI
0.842*

0.842*

0.842*
0.842
1.57
.933
1.17
.648
1.74

Carbon
Monoxide
.621

.822

.690
.704
1.685
.709
1.051
.648
1.557
Emissions
Carbon
Dioxide
1.64

1.31

1.52
1.52
2.20
1.79
2.00
1.70
2.94
(Ib/min)
Hydrocarbons
(as Hexanel
.00726

.0137

.00935
.00650
.0231
.00677
.00606
.00936
.0214

Nitrogen
Oxides (as NO?)
.0115

.00618

.00249
.00135
.00231
.00127
.00221
-
.00602
                                                                                                                       I
                                                                                                                      K)
* Fuel Flow estimated from measurements on Aircraft  #4.

-------
                                                  Table  A-23
X
o
a
m
t/)
en
^ MODE: Lean Cruise
X
r-
o
o
5 Aircraft
o Number
rn
_ 1
p
2 (Right)

2 (Left)
3
4
5
6
7
8
9
Type

Cessna 172K

Cessna 172D
}
Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Exhaust Emission Rates
for Liqht Aircraft
Fuel Flow
Rate
Clb/minl

.717*


.717*

.717*
.717
1.187
.826
.933
.758
1.52
Emissions (Ib/min)
Carbon
Monoxide

.0568


.266

.205
.267
.665
.279
.188
.287
.537
Carbon
Dioxide

2.16


1.81

1.91
1.82
2.64
2.14
2.62
1.92
3.87
Hydrocarbons
(as Hexanel

.00128


.00789

.00412
.00351
.0126
.00373
.00260
.00318
.0150
Nitrogen
Oxides (as NO?)
.0406


.0311

.0305
.0270
.0310
.0440
.0912
-
.0205
                                                                                                                        NJ
                                                                                                                        .fc.
*Fuel Flow estimated from measurements on  Aircraft  #4.

-------
                                                 Table A-24
                                           Exhaust Emission Rates
                                             for Light Aircraft
r RESEARCH UBORATORIES,
O









MODE: Descent
Aircraft
Number
1
2 (Right)

2 (Left)
3
4
5
6
7
8
9
Type
Cessna 172K
Cessna 172D
}
Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Fuel Flow
Rate
Clb/m±nL
.261*

.261*

.261*
.261
.967
.648
.706
.505
.991
Emissions (Ib/min)
Carbon
Monoxide
.302

.286

.279
.310
1.109
.557
.467
.410
1.104
Carbon
Dioxide
.322

.236

.351
.300
1.218
1.134
1.468
.919
1.308
Hydrocarbons
(as Hexanel
.00769

.0439

.00953
.0104
.0241
.00674
.00378
.00606
.0198
Nitrogen
Oxides (as NO?.)
.000957

.00341

.00191
.000752
.00283
.00211
-
-
.00439
* Fuel Flow"estimated from measurements  on  Aircraft  #4.

-------
                                                  Table A-25
                                            Exhaust Emission Rates
RESEARCH LABORATORIES. INC










MODE: Pattern
Aircraft
Number
1
2 (Right)

2 (Left)
3
4
5
6
7
8
9
Type
Cessna 172K
Cessna 172D
}
Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Fuel Flow
Rate
( Ib/min 1.
-

.859 *

.859*
.859
.889
.476**
.393
.446**
1.069
Emissions (Ib/min)
Carbon
Monoxide
-

.825

..740
.748
.911
.407
.306
.360
1.256
Carbon
Dioxide
-

1.319

1.486
1.452
1.307
.833
.742
.816
1.304
Hydrocarbons
(as Hexanel
-

.0259

.0152
.0210
.0164
.00628
.00253
..00593
.0235
Nitrogen
Oxides (as NO?)
-

.00734

i
.00411 £
.00579
.00233
.00102
-
-
.00420
 * Fuel Flow estimated from measurements  on  Aircraft  #4.
** Fuel Flow estimated from measurements  on  other aircraft.

-------
                                                  Table A-26
                                            Exhaust Emission Rates
                                              for Light Aircraft
T RESEARCH U
03
o
ya
1
to
P
%









MODE: Final Approach

Number


1
2 (Right)

2 (Left)
3
4
5
6
7
8
9
Aircraft
Type


Cessna 172K
Cessna 172D
}
Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Fuel Flow
Rate
Clb/minl


.188*

.188*

.188*
.188
.466**
.206**
.216
.193**
.240**

Carbon
Monoxide


.160

.170

.150
.144
.407
.131
.189
.186
.238
Emissions
Carbon
Dioxide


.280

.246

.364
.261
.550
.404
.346
.303
.295
(Ib/min)
Hydrocarbons
(as Hexanel


.0186

.0246

.0190
.0326
.0881
.0119
.00333
.00286
.0269

Nitrogen
Oxides (as NO?)


.000481

.00102

.00131
.000690
.000638
.000344
-
-
.000564
 *  Fuel  Flow estimated from measurements on Aircraft #4.
**  Fuel  Flow  estimated from measurements  on other  aircraft.

-------
                                                Table A-27

                                          Exhaust Emission Rates
RESEARCH LABORATORIES, INC










MODE: Taxi - Final
Aircraft
Number
1
2 (Right)

2 (Left)
3
4
5
6
7
8
9
Type
Cessna 172K
Cessna 172D
}
Cessna 172D
Cessna 1721
Cessna 172K
Bonanza 36
Cessna 182H
Cessna 182N
Piper Apache
Cessna 210
Fuel Flow
Rate
(Ib/min)
.188*

.188*

.188*
.188**
.466
.206**
.216
.193**
.240**
Emissions (Ib/min)
Carbon
Monoxide
.175

.206

.0893
.204
.396
.154
.192
.138
.212
Carbon
Dioxide
.299

.236

.423
.231
.652
.387
..359
.369
.312
Hydrocarbons
(as Hexanel
.00478

.00956

.00568
.0122
.0606
.00509
.00555
..00621
.0353
Nitrogen
Oxides (as NO?)
.000526

.00073O
>
.00117 a
.000423
.000666
.000288
-
.00376
.000648
 * Fuel  Flow estimated  from  measurements on Aircraft #4.
** Fuel  Flow estimated  from  measurements on other  aircraft.

-------
                                           A-29
                            Table A-28-   Exhaust Emissions During
                                 Normal Operating Cycles for

                               Aircraft Number 1 - Cessna 172K
                                                     Mode Emissions (Ib.)
Mode
Taxi - Initial
Run-up
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
Taxi - Final
Total-TCL Cycle*
Total-LTO Cycle**
Mode Time
(Min.)
4.5
1.5
6
6.5
2.5
7.5
2
2
1.7
34.2
25.2
Carbon
Monoxide
0.936
-
5.80
4.04
0.142
2.27
-
0.320
0.298
-
-
Carbon
Dioxide
1.323
-
11.22
10.66
5.40
2.42
-
0.560
0.508
-
_
Hydrocarbons
(as Hexane)
0.0257
-
0.0666
0.0472
0.00320
0.0577
-
0.0372
0.00813
-
-
Nitrogen Oxides
(as NO?)
0.00131
-
0.0834
0.0748
0.102
0.00718
-
0.000962
0.000894
-
-
*   Cycle as defined in Section  5.1.
**  Landing-Takeoff Cycle - as TCL cycle  without  cruise  modes.
        SCOTT RESEARCH LABORATORIES, INC

-------
                                           A-30
                            Table A-29.   Exhaust Emissions During
                                 Normal Operating Cycles for
                               Aircraft  Number  2 -  Cessna  172D
                                                     Mode Emissions (Ib.)
Mode
Taxi - Initial
Run-up
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
Taxi - Final
Total-TCL Cycle*
Total-LTO Cycle**
Mode Time
(Min.)
4.
1.
6
6.
2.
7.
2
2
1.
34.
25.
5
5

5
5
5


7
2
2
Carbon
Monoxide
1.
0.
6.
5.
0.
2.
1.
0.
0.
18.
12.
062
822
25
34
665
15
65
340
350
63
62
Carbon
Dioxide
1.
0.
10.
8.
4.
1.
2.
0.
0.
30.
17.
103
857
38
52
53
77
64
492
401
69
64
Hydrocarbons
(as Hexane)
0
0
0
0
0
0
0
0
0


.0341
.0212
.122
.0891
.0197
.329
.0518
.0492
.0163
.732
.624
Nitrogen Oxides
(as NO?)
0
0
0
0
0
0
0
0
0


.00179
.00318
.0744
.0402
.0778
.0256
.0147
.00204
.00124
.2410
.1230
*   Cycle as defined in Section 5.1.
**  Landing-Takeoff Cycle - as TCL cycle without cruise modes.
     SCOTT RESEARCH LABORATORIES, INC

-------
                                           A-31
                            Table A-30•   Exhaust Emissions During
                                 Normal Operating Cycles for
                               Aircraft  Number  3 -  Cessna  1721
                                                     Mode Emissions (Ib.)
Mode
Taxi - Initial
Run-up
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
Taxi - Final
Total-TCL Cycle*
Total-LTO Cycle**
Mode Time
(Min.)
4.5
1.5
6
6.5
2.5
7.5
2
2
1.7
34.2
25.2
Carbon
Monoxide
0.576
0.527
6.01
4.49
0.513
2.09
1.48
0.300
0.152
16.14
11.14
Carbon
Dioxide
1.91
1.34
10.86
9.88
4.78
2.63
2.97
0.728
0.719
35.82
21.16
Hydrocarbons
(as Hexane)
0.0214
0.0149
0.0852
0.0608
0.0103
0.0715
0.0304
0.0380
0.00966
.2207
.1496
Nitrogen Oxides
(as NO?)
0.00286
0.00393
0.0506
0.0162
0.0763
0.0143
0.00822
0.00262
0.00199
.1770
.0845
*   Cycle as defined in Section 5.1.
**  Landing-Takeoff Cycle - as  TCL cycle  without  cruise  modes.
      SCOTT RESEARCH LABORATORIES, INC

-------
                                            A-32
                            Table A-31.   Exhaust Emissions During
                                 Normal Operating Cycles for
                               Aircraft  Number 4 - Cessna 172K
                                                     Mode Emissions  (Ib.)
Mode
Taxi - Initial
Run-up
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
Taxi - Final
Total-TCL Cycle*
Total-LTO Cycle**
Mode Time
(Min.)
4.5
1.5
6
6.5
2.5
7.5
2
2
1.7
34.2
25.2
Carbon
Monoxide
1.076
0.663
6.13
4.58
0.668
2.33
1.50
0.288
0.347
17.56
12.33
Carbon
Dioxide
0.981
1.065
10.74
9.88
4.55
2.25
2.90
0.522
0.393
33.28
18.85
Hydrocarbons
(as Hexane)
0.0689
0.0338
0.0596
0.0423
0.00878
0.0780
0.0420
0.0652
0.0207
.4193
.3682
Nitrogen Oxides
(as NO?)
0.00162
0.00410
0.0253
0.00878
0.0675
0.00564
0.0116
0.00138
0.000719
.1266
.0504
*   Cycle as defined in Section 5.1.
**  Landing-Takeoff Cycle - as TCL cycle without cruise modes.
      SCOTT RESEARCH LABORATORIES, INC.

-------
                                           A-33
                            Table A-32.   Exhaust Emissions During
                                 Normal Operating Cycles for
                               Aircraft Number 5 - Bonanza 36
                                                     Mode Emissions (Ib.)
Mode
Taxi - Initial
Run-up
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
Taxi - Final
Total-TCL Cycle*
Total-LTO Cycle**
Mode Time
(Min.)
4.5
1.5
6
6.5
2.5
7.5
2
2
1.7
34.2
25.2
Carbon
Monoxide
1.83
0.851
8.04
10.95
1.66
8.32
1.82
0.814
0.673
26.92
14.31
Carbon
Dioxide
3.27
1.51
14.8
14.3
6.60
9.14
2.61
1.10
1.11
54.4
33.5
Hydrocarbons
(aa Hexane)
0.168
0.0660
0.136
0.150
0.0315
0.181
0.0328
0.176
0.103
1.044
.863
Nitrogen Oxides
(as NO?)
0.00353
0.00227
0.0307
0.0150
0.0775
0.212
0.00466
0.00128
0.00113
.348
.256
*   Cycle as defined in Section 5.1.
**  Landing-Takeoff Cycle -  as  TCL cycle without  cruise modes.
       SCOTT RESEARCH LABORATORIES, INC

-------
                                           A-34
                            Table A-33.   Exhaust Emissions During
                                 Normal  Operating Cycles for
                               Aircraft  Number  6 -  Cessna  182H
                                                     Mode Emissions (Ib.)
Mode
Taxi - Initial
Run-up
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
Taxi - Final
Total-TCL Cycle*
Total-LTO Cycle**
Mode Time
CMin.)
4.5
1.5
6
6.5
2.5
7.5
2
2
1.7
34.2
25.2
Carbon
Monoxide
0.567
0.573
4.55
4.61
0.698
4.18
0.814
0.262
0.262
16.52
11.21
Carbon
Dioxide
1.54
1.19
12.0
11.6
5.35
8.51
1.67
0.808
0.658
43.3
26.4
Hydrocarbons
(as Hexane)
0.0154
0.0138
0.0547
0.0440
0.00933
0.0506
0.0126
0.0238.
0.00865
.2329
.1796
Nitrogen Oxides
(as NO?)
0.000972
0.000999
0.0139
0.00826
0.110
0.158
0.00204
0.000688
0.000490
.295
.177
*   Cycle as defined in Section 5.1.
'*  Landing-Takeoff Cycle - as  TCL cycle without  cruise  modes.
     SCOTT RESEARCH LABORATORIES, INC

-------
                                           A-35
                            Table A-34.   Exhaust Emissiona  During
                                 Normal  Operating Cycles for
                               Aircraft  Mumber  7 -  Cesina 182N
                                                     Mode Emissions  (Ib.)
Mode
Taxi - Initial
Run-up
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
Taxi - Final
Total-TCL Cycle*
Total-LTO Cycle**
Mode Time
(Min.)
4.5
1.5
6
6.5
2.5
7.5
2
2
1.7
34.2
25.2
Carbon
Monoxide
0.806
0.680
4.80
6.83
0.0470
3.50
0.612
0.378
0.326
18.40
11.10
Carbon
Dioxide
1.73
1.54
13.7
13.0
6.55
11.0
1.48
0.692
Q.61Q
50.3
30.8
Hydrocarbons
(as Hexane)
0.0170
0.0104
0.0354
0.0394
0.00650
0.0284
0.00506
0.00666
0.. 00.944
0.1583
0.1124
Nitrogen Oxides
(as NO?)
0.00151
0.00402
0.0232
0.0144
0.228
-
-
-
^
•
_
*   Cycle as defined in Section 5.1.
**  Landing-Takeoff Cycle - as TCL cycle without  cruise modes.
       SCOTT RESEARCH LABORATORIES, INC

-------
                                           A-36
                            Table A-35.  Exhaust Emissions During

                                 Normal Operating Cycles for

                              Aircraft Number 8 - Piper Apache
                                         (1  Engine)
                                                     Mode Emissions (Ib.)
Mode
Taxi - Initial
Run-up
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
Taxi - Final
Total-TCL Cycle*
Total-LTO Cycle**
Mode Time
(Win.)
4.5
1.5
6
6.5
2.5
7.5
2
2
1.7
34.2
25.2
Carbon
Monoxide
1.21
0.581
4.34
4.21
0.718
3.08
0.720
0.372
0.235
15.47
10.54
Carbon
Dioxide
2.18
1.046
13.1
11.1
4.80
6.89
1.63
0.606
0.627
42.0
26.1
Hydrocarbons
(as Hexane)
0.0296
0.0126
0.0654
0.0608
0.00795
0.0455
0.0117
0.00572
0.0106
.2499
.181
Nitrogen Oxides
(as NO?)
0.00752
0.0149
-
-
•
-
-
-
0.00639
-
-
*   Cycle as defined in Section 5.1.
**  Landing-Takeoff Cycle - as TCL cycle without cruise modes.
     SCOTT RESEARCH LABORATORIES. INC

-------
                                          A-37
                            Table A-36.   Exhaust Emisaione During
                                 Normal  Operating Cycles for
                                Aircraft Number  9 - Cessna  210
                                                     Mode Emissions (Ib.)
Mode
Taxi - Initial
Run-up
Ascent
Rich Cruise
Lean Cruise
Descent
Pattern
Final Approach
Taxi - Final
Total-TCL Cycle*
Total-LTO Cycle**
Mode Time
(Win.)
4.5
1.5
6
6.5
2.5
7.5
2
2
1.7
34.2
25.2
Carbon
Monoxide
0.972
1.10
10.48
10.12
1.34
6.28
2.51
0.476
0.360
35.64
24.18
Carbon
Dioxide
1.63
2.08
18.5
19.1
9.68
9.81
2.61
0.590
0.530
64.5
35.8
Hydrocarbons
(as Hexane)
0.0895
0.0480
0.151
0.139
0.0375
0.149
0.470
0.00538
0.0600
1.149
.973
Nitrogen Oxides
(as NO?)
0.00307
0.00608
0.0430
0.0391
0.0513
0.0329
0.00840
0.00113
0.00110
.1861
.0957
*   Cycle as defined in Section 5.1.
•*  Landing-Takeoff Cycle -  as  TCL cycle  without  cruise modes.
       SCOTT RESEARCH LABORATORIES. INC

-------
                                     Table A-37 .  Comparison of Stack and Corrected
o
30
m
I"

O
Aircraft
     1
     1
     1
     1
     1
     1
     1
     1
     1
     2
     2
     2
     2
     2
     2
     2
     2
     2
     2
     2
     2
     2
     2
     2
     2
Flight
   1
   2
   3
   3
   4
   4
   6
   6
   6
   4
   A
   4
   5
   5
   5
   7
   7
   8
   9
   9
  10
  10
  10
  11
  12-
 Mode
Ascent
Cruise
Cruise
Descent
Ascent
Descent
Ascent
Cruise
Descent
Taxi
Ascent
Cruise
Taxi
Ascent
Cruise
Ascent
Cruise
Ascent
Ascent
Cruise
Ascent
Cruise
Descent
Ascent
Cruise
Plume Analysis to Detect Afterburning

CO
(%)
6.85
A. 84
6.50
5.43
7.30
6.40
6.96
5.75
6.90
10.40
8.32
6.52
11.70
11.72
8.38
8.00
7.00
7.AO
8.00
8.AO
7.62
8.20
9.04
8.00
7.34
Stack
C02
(%)
9.60
8.70
8.65
3.20
9.68
2.60
8.41
8.12
2.88
6.80
7.86
8.16
7.15
11.70
10.90
8.00
8.50
9.70
9.10
7.47
8.70
7.25
5.25
7.90
8.72
Corrected Plume
HC
(PPMCI
450
380
480
555
A25
1070
6AO
SAO
2960
2640
1305
920
6200
1280
9A5
1210
780
820
730
825
775
800
12400
810
790
CO
(%)
6.5A
5.05
6.58
5.30
7.67
5.9A
5.63
2.55
5.75
8.01
8.68
6.53
12.16
10.92
7.98
7.61
7.23
7.37
7.5A
8.23
7.67
7.52
9.67
7.91
7.97
C02
(%1
9.89
8.AA
8.58
3.24
9.27
3.07
9.76
11.33
4.16
9.25
7.48
8.15
6.92
12.38
11.24
8.20
8.14
9.57
9.39
7.48
8.49
7.76
5.04
7.81
7.92
HC
(PPMC).
528
808
286
1294
671
876
366
347
1601
2000
1365
831
3784
2419
1378
3027
1989
2318
2333
2310
2211
2442
8179
2528
2372
Dilution
Factor
11.33
48.58
17.20
7.33
18.33
13.15
55.22
40.18
15.01
27.92
37.25
33.75
18.31
58.10
44.98
32.68
4.82
55.67
53.46
48.50
40. A6
43.11
86.42
39.12
29.05
                                                                                                    % Change  in  Cone.
   CO
 -4.48
  4.38
  1.37
 -2.22
  5.18
 -7.08
-19.07
-55.62
-16.63
-22.97
  A.A2
   .23
  A.00
 -6.80
 -4.66
 -4.81
  3.39
  -.38
 -5.63
 -1.95
   .74
 -8.24
  6.97.
 -1.11
  8.67
                                                                                                                            i
                                                                                                                           OJ

-------
                                                   Table A-37 Continued
o
m
•x
n
O
33
O
Aircraft
     3
     3
     3
     3
     3
     3
     3
     3
     3
     3
     3
     3
     3
     3
     3
     3
     4
     4
     4
     4
     4
     4
     4
     4
     4
     4
     4
     4
     4
     4
     4
     4
     5
     5
Flight
   1
   1
   1
   4
   4
   4
   5
   5
   6
   6
   7
   8
   8
  11
  11
  11
   2
   2
   4
   4
   4
   5
   5
   5
   6
   6
   6
   6
   7
   7
   7
   8
   1
   1
  Mode
Ascent
Cruise
Descent
Ascent
Cruise
Descent
Ascent
Cruise
Ascent
Cruise
Descent
Ascent
Cruise
Taxi
Cruise
Descent
Taxi
Cruise
Ascent
Cruise
Descent
Taxi
Ascent
Descent
Taxi
Ascent
Cruise
Descent
Ascent
Cruise
Descent
Cruise
Taxi
Ascent

CO
(%)
9.28
8.02
7.80
9.38
7.72
8.17
9.87
7.90
8.68
6.93
10.37
9.50
7.92
6.39
7.45
11.24
11.17
6.18
8.50
7.41
10.84
10.60
8.78
11.39
12.74
8.77
7.61
10.70
9.05
7.76
13.02
6.88
8.78
8.33
Stack
C02
(%)
9.73
9.65
8.42
9.40
9.60
7.80
11.97
11.38
11.17
10.59
6.82
11.10
10.59
10.44
11.80
7.00
6.51
10.39
10.08
10.32
6.91
7.91
10.00
6.83
7.25
11.00
10.52
7.68
9.98
10.65
6.52
9.51
8.74
11.04
Corrected Plume
HC
(PPMC1
980
740
1103
870
660
1590
905
640
840
630
2360
890
680
1055
650
2170
4650
595
640
415
2000
2040
580
3800
5700
560
500
1330
52"0
420
2800
420
27000
2391
CO
(%)
9.70
7.96
7.39
10.08
7.34
8.70
10.29
7.92
9.37
7.25
10.50
9.99
7.93
6.02
7.64
10.96
10.26
6.32
9.12
7.81
10.78
10.98
9.54
10.86
12.84
9.52
7.96
10.46
8.73
7.13
11.97
7.42
10.36
8.91
C02

9.11
9.54
8.64
8.53
9.83
7.09
11.33
11.13
10.26
10.01
6.43
10.38
10.37
10.60
11.42
6.98
7.02
10.17
9.34
9.77
6.84
7.07
9.13
7.43
6.61
10.20
10.07
7.78
10.15
11.16
6.84
8.88
8.59
10.40
HC
CPPMC1
2866
2341
2891
2521
2120
3314
3021
2829
3002
3109
4797
3086
2690
3044
2435
5122
8590
1279
1791
1761
3108
6509
1609
3013
10960
907
1488
2629
1884
1541
10018
1244
12599
2911
Dilution
Factor
48.05
42.07
38.22
19.44
22.64
23.56
57.39
66.36
58.13
62.64
18.19
60.95
63.10
41.66
64.70
23.75
64.62
36.94
35.37
28.57
20.50
59 . 76
38.64
20.27
73.10
36.82
31.24
22.16
38.73
33.78
23.87
26.13
22.82
42.41
% Change in Cone.
CO
4.55
-.62
-5.21
7.48
-4.87
6.49
4.26
.29
7.96
4.67
1.34
5.16
.23
-5.85
2.66
-2.48
-8.12
2.35
7.34
5.49
-.46
3.62
8.66
-4.64
.81
8.62
4.60
-2.19
-3.43
-B.05
-8.02
7.87
18.06
7.03
CO?
-6.37
-1.13
2.61
-9.25
2.39
-9.10
-5.34
-2.19
-8.14
-5.A7
-5.71
-6.48
-2.07
1.53
-3.22
-.28
7.83
-2.11
-7.34
-5.32
-1.01
-10.61
-8.70
8.78
-8.82
-7.27
-4. 27
1.30
1.70
4.78
• 4.90
-6.62
-1.71
-5.79
HC
192.47
216.38
162.14
189.80
221.27
108.45
233.84
342.13
257.38
393.57
103.28
246.84
295.71
218.43
274.71
136.05
84.73
115.09
179.92
324.37
55.43
219.11
177.42
-20.68
92.28
62.02
197.68
97.70
262.34
267.10
257.80
196.41
-53.33
21.76
                                                                                                                             I
                                                                                                                             LO

-------
Table £-37 Ccniinued
Aircraft

••
m
m
0
o
^
rn
m
33
n
P.
33
O
33
1
33
."
2
O





















5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
6
6
6
6
6
6
6
6
6
6
6
6


Flight
2
2
2
3
3
3
4
4
5
5
5
6
6
6
7
7
7
a
8
8
3
9
9
10
10
10
10
1
1
1
2
2
2
2
3
3
3
4
4


Mode
Taxi
Cruise
Descent
Ascent
Cruise
Descent
Taxi
Descent
Ascent
Cruise
Descent
Taxi
Ascent
Descent
Taxi
Ascent
Cruise
Taxi
Ascent
Cruise
Descent
Ascent
Cruise
Taxi
Ascent
Cruise
Descent
Taxi
Ascent
Cruise
Taxi
Ascent
Cruise
Descent
Taxi
Ascent
Descent
Taxi
Ascent

CO
(%)
8.88
9.30
8.99
8.46
9.68
8.92
8.86
12.40
8.80
11.09 .
10.34
8.30
8.88
10.70
9.00
8.94
10.59
8.01
8.40
9.82
9.82
R.50
9.80
8.14
8.54
9.52
10.48
6.91
7.78
7.68
6.70
7.55
7.78
8.52
5.79
7.73
7.40
7.71
7.81
Stack
CO2
(%)
9.09
9.32
8.35
9.75
8.72
11.21
9.81
6.21
9.71
7.49
7.18
8.45
10.19
6.92
10.10
10.24
8.73
10.48
10.53
9.37
6.85
9.87
8.62
9.99
10.25
8.91
6.51
10.47
10.89
11.20
11.11
11.02
10.87
10.39
11.99
11.64
10.12
11.72
12.61
Corrected Plume
HC
(PPMCJ
12771
2220
2739
2400
2520
2709
12600
5709
3960
3330
3960
21300
2370
3435
18540
3534
3000
9900
2790
2775
5100
2340
2580
15600
2400
2490
6000
4074
2154
1404
4050
1695
1440
2520
2190
1752
2142
4200
1980
CO
(%)
9.53
9.50
8.49
7.71
9.02
9.74
9.14
11.64
8.83
11.26
10.32
7.68
8.12
10.91
9.97
9.29
11.00
8.89
8.48
10. 01
10.31
8.63
9.50
9.01
8.59
9.58
10.87
7.06
7.23
7.48
6.57
7.40
7.70
8.18
6.14
8.18
7.26
7.96
8.47
C02

8.58
8.98
8.78
10.43
9.27
10.22
9.62
6.10
9.79
7.10
7.17
9.36
10.76
6.41
9.51
9.91
8.13
9.58
10.41
9.03
6.52
9.68
8.71
9.51
10.18
8.66
6.35
10.42
11.48
11.37
11.38
11.17
10.92
10.77
11.61
11.17
10.29
11.52
11.98
HC
(PPMC).
11309
3505
3354
2477
3569
4270
11610
14314
2769
5407
4133
18319
4102
6404
14658
3200
4777
9977
3072
4177
3344
2876
4532
11522
2578
4234
3629
2995
1611
1619
2527
1571
1604
2035
2445
1858
1755
3580
1642
Dilution
Factor
21.75
60.82
71.92
17.48
65.33
78.16
41.03
48.58
16.32
51.18
58.51
43.41
37.41
73.92
25.23
17.23
54.51
28.11
45.42
68.38
50.94
15.33
56.12
25.05
15.28
60.64
50.66
17.22
17.02
20.32
14 . 37
15.93
17.90
24.93
16.75
15.40
23.52
19.15
17.92
% Change in Cone.
CO
7.36
2.21
-5.51
-8.78
-6.79
9.27
3.24
-6.12
.39
1.58
-.12
-7.46
-8.47
1.97
10.82
4.01
3.93
11.07
1.01
1.99
5.06
1.55
-2.98
10.79
.58
.71
3.74
2.26
-6.99
-2.58
-1.81
-1.93
-.96
-3.96.
6.06
5.91
-1.79
3.32
8.48
CO?
-5.f>]
-3.64
s . ] £
7.48
ft . 30
-8.83
-1.93
-1.77
.82
-5.20
-.13
10.7f,
5.59
-7.36
-5.84
-3.22
-6.87
-8.58
-1.13
-3.62
-4.81
-1.92
1.04
-4.80
-.68
-2.80
-2.45
-.47
3.41
1.51
2.43
1.36
.45
3.65
-3.16
-4.03
1.67
-1.70
-4.y9
HC
-11.44
57.91
22.47
3.21
41.65
57.65
-7.84
150.74
-30.06
62.38
4.37
-13.99
73.09
86.46
-20.93
-9.44
59.25
.78
10.12
50.53
-34.42
22.94
77.59
-26.13
7.42
72.05
-39.50
-26.47
-25.17
15.31
-37.59
-7.25
11.44
-19.20
11.65
6.06
-18.05
-14.75
-17.04

-------
                                     Table A-37 Continued
Aircraft


9
9
^^H
C/i
8
3
30
m
C/J
pi
x
0
a:
03
O
•sa
-i
O
2
P
2
0















6
6
6
6
6

6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
7
7
7
7
7
7
7
7
7
7
7
7
Flight

  4
  4
  5
  5
  5
  5
  6
  6
  6
  7
  7
  7
  8
  8
  8
  8
  9
  9
  9
 10
 10
  1
  3
  3
  3
  3
  4
  4
  4
  5
  6
  6
  6~
  Mode
Cruise
Descent
Taxi
Ascent
Cruise
Descent
Taxi
Ascent
Cruise
Ascent
Cruise
Descent
Taxi
Ascent
Cruise
Descent
Ascent
Cruise
Descent
Cruise
Descent
Cruise
Taxi
Ascent
Cruise
Descent
Taxi
Ascent
Cruise
Ascent
Taxi
Descent
Ascent

CO
(%)
8.07
8.52
7.10
7.80
7.55
7.87
7.08
6.51
7. 04
7.11
7.14
8.37
6.99
6.99
6.70
7.80
7.19
6.02
6.64
7.88
8.70
8.60
6.30
5.90
10.60
5.10
6.20
5.80
7.10
8.50
12.90
8.20
6.80
Stack
CO2
(%)
11.86
10.65
11.44
12.11
11.50
10.25
11.21
13.08
11.74
13.15
12.02
10.33
11.06
12.26
11.57
9.84
13.85
13.00
11.52
13.23
11.28
10.70
10.80
11.60
10.50
11.60
9.90
10.10
10.10
13.50
11.30
12.50
10.70
Corrected Plume
HC
CPPMC1
1428
1920
3660
1833
1404
2079
4110
1686
1251
1545
1260
1692
4260
1710
1284
1806
1695
1206
1866
1500
1971
1140
2370
570
720
570
2580
900
900
1110
2820
990
2160
CO
(%)
8.30
8.53
7.13
7.89
7.37
7.86
7.36
7.84
6.82
7.33
6.94
8.23
7.54
7.36
6.85
7.82
8.19
6.26
6.86
8.04
8.66
8.90
6.86
6.00
8.99
5.17
6.06
5.14
7.04
9.69
10.48
9.41
6.46
CO2
(%}
11.62
10.64
11.47
12.04
11.74
10.27
11.06
11.75
11.94
12.92
12.20
10.46
10.62
11.90
11.41
9.83
12.84
12.75
11.31
13.06
11. 33
10.37
10.27
11.47
12.06
11.50
10.12
10.77
10.15
12.27
13.69
11.29
11.23
HC
(PPMCL
1485
1863
2979
1539
1437
1892
2748
1613
1331
1540
1344
1701
3071
1518
1280
1619
1653
1256
1612
1488
1740
1296
2024
742
1132 .
744
1725
700
930
1314
2957
907
1808
Dilution
Factor
16.56
31.77
18.70
21.19
25.38
23.76
23.30
17.05
16.11
18.86
20.17
24.09
20.61
16.75
17.87
22.60
18.86
24.80
25.33
19.41
29.68
14.96
18.58
12.05
5.84
12.08
17.62
11.17
5.52
14.49
25.95
12.32
26.33
                                                                                       %  Change in Cone.
 1.
-2,
   CO

   .87
   .16
   .52
   .20
   .32
  -.09
  3.97
 20.45
 -3.06
  3.14
 -2.70
 -1.67
  7.92
  5.42
  2.26
   .26
 14.02
  4.04
  3.43
  2.12
  -.34
  3.54
  8.95
  1.84
-15.16
  1.53
 -2.18
-11.31
  -.82
 14.11
-18.69
 14.80
 -4.86
                      .46
                            >
            -9.68
             4.95

-------
Table A-37 Continued




Aircraft


Si
m
•H
o

30
m
>
50
n
X
r-
CD
O
33
d
33
m
J«
P


















7
7
7
7
7
/
7
7
7
7
7
7
8
8
8
8
8
8
8
8
8
8
8
8
9
9
9
9
9
9
9
9
9
9
9
9


Flight
7
7
7
8
8
8
9
9
9
10
10
10
1
2
2
2
2
3
3
4
4
4
5
5
3
3
4
4
4
9
9
9
10
10
10
10


Mode
Taxi
Cruise
Descent
Taxi
Cruise
Descent
Taxi
Ascent
Descent
Taxi
Cruise
Descent
Taxi
Taxi
Ascent
Cruise
Descent
Taxi
Ascent
Taxi
Ascent
Cruise
Cruise
Descent
Ascent
Cruise
Taxi
Ascent
Cruise
Taxi
Ascent
Cruise
Taxi
Ascent
Cruise
Descent

CO

7.30
6.50
6.20
9.30
9.40
5.00
8.10
9.50
5.80
8.10
9.80
5.70
8.25
6.60
6.25
6.20
6.60
9.60
6.50
6.65
6.95
8.10
6.30
7.35
10.70
8.95
8.25
9.15
8.00
7.70
10.75
9.60
7.80
9.35
8.10
8.65
Stack
C02

10.50
11.70
10.60
11.20
10.80
13.10
11.30
10.80
12.00
11.40
13.60
14.00
7.10
9.35
13.80
12.30
10.80
7.35
13.40
9.90
14.40
12.80
11.60
9.05
10.50
10.00
9.22
11.20
9.70
10.10
11.00
9.80
8.65
11.10
10.30
8.20
Corrected Plume
HC
(PPMC1
3000
780
840
6600
1320
720
4500
1350
900
3180
1320
1020
3900
3330
2460
1785
1710
3825
1545
3270
2160
2280
2025
2205
1680
900
16800
2790
2235
14100
2160
2580
16350
3240
2295
3930
CO
(%)
7.52
6.63
6.17
10.41
9.38
5.45
9.15
7.43
4.86
8.64
11.16
6.10
6.91
6.59
6.79
4.69
5.72
7.76
5.54
7.55
5.42
5.97
5.40
7.07
10.64
8.19
8.98
8.37
7.65
8.10
11.29
9.44
7.60
9.43
7.91
7.95
CO2
(%)
10.37
11.41
10.56
10.43
10.83
12.54
10.40
12.73
12.95
10.88
12.21
13.63
8.56
9.46
13.37
13.87
11.60
9.23
14.36
9.03
15.84
15.00
12.57
9.34
10.47
10.67
9.51
12.04
10.08
9.44
10.38
9.98
8.88
11.08
10.50
8.89
HC
(PPMCI
1982
2243
1473
3062
1112
1692
2878
2701
697
2865
1543
688
2594
2190
1265
1010
2334
3316
1380
2854
3002
1496
1180
1972
2435
1621
6434
2088
1864
16636
2863
2239
15976
2543
2054
3983
Dilution
Factor
18.37
10.07
13.82
26.41
5.71
13.91
24.83
15.46
15.97
18.49
7.77
19.88
20.76
21.70
18.70
18.49
19.03
19.28
18.74
17.00
15.42
13.05
11.97
11.76
4.38
16.77
14.33
4.67
15.98
61.40
4.09
16.51
25.12
3.95
13.91
72.91
% Change in Cone .
CO
3. '?
2.10
-.40
11.99
-.17
9.07
13.03
-21.74
-16.11
6.71
13.89
7.05
-16.17
-.04
8.65
-24.22
-13.19
-19.13
-14.64
13.65
-21.96
-26.27
-14.21
-3.67
-.53
-8.40
8.96
-8.42
-4.34
5.26
5.07
-1.61
-2.50
.90
-2.25
-8.03
CO?
-:.^3
-2.47
-.37
-6.87
.34
-4.27
-7.96
17.87
7.91
-4.56
-10.22
-2.64
20.56
1.17
-3.11
12.76
7.40
25.57
7.16
-8.7K
10.06
17.18
8.36
3.20
-.22
6.79
3.22
7.51
3.96
-6.52
-5.59
1.92
2.68
-.13
2.00
8.41
HC
-33.90
187.64
75.45
-53.60
-15.74
135.11
-36.02
100.11
-22.52
-9.89
16.93
-32.45
-33.47
-34.22
-48.56
-43.38
36.50
-13.30
-10.66
-12.69
38.98
-34.35
-41.69
-10.52
47.94
80.16
-61.70
-25.14
-16.59
17.98
32.55
-13.18
-2.28
-21.50
-10.48
1.37

-------