PB-203 465

GUIDES FOR SHORT-TERM  EXPOSURE  OF THE PUBLIC  TO
AIR POLLUTANTS.   III.   GUIDE  FOR  GASEOUS HYDROGEN
FLUORIDE

National Academy  of Sciences-
National Research Council
Washington,  D.  C.

August  1971
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Guides for Short-Term Exposures of the Public to Air Pollutants




           III. Guide for Gaseous Hydrogen Fluoride
                             by




                 The Committee on Toxicology





                            of the




   National Academy of Sciences - National Research Council





                       Washington, D. C.
                          August 1971

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BIBLIOGRAPHIC DATA
SHEET
1. Repon Nol

  APTD-0765
3.Jlecipient's Accession No.
4. Title and Subtitle
 Guides  for Short-Term Exposures of the  Public  to  Air
 Pollutants  III.   Guide for  Gaseous Hydrogen Fluoride
                                          5. Report Date
                                          August 1971
7. Author(s)
                                          8. Performing Organization Kept.
                                           No.
9.Petformina Organization Name and Address
 The Committee on  Toxicology
 National  Academy  of  Sciences
 National  Research Council
 2101 Constitution Avenue
 Washington,  D. C.   20418
                                          10. Project/Task/Work Unit No.
                                          11. Contract /Gram No.

                                          CPA  70-57
12. Sponsoring Organization Name and Address
 Environmental Protection Agency	
 Air Pollution Cpntrol Office
 Research  Triangle  Park, North  Carolina  27711
                                          13. Type of Report & Period
                                            Covered
                                          14.
15. Supplementary Notes DISCLAIMER -  This report  was furnished to  the Office  of
 Air Programs by National Academy of Sciences, National Research Council
 2101 Constitution Avenue, Washington, D.  C. 20A18  in fulfillment of	
16. Abstracts                                                       [Contract  70-57
A report is  presented which reviews experimental data  and histories of
exposure to  hydrogen fluoride of  humans and  experimental animals.
Specifically  reviewed are:  clinical and pathological effects of  UF;
toxicity studies; and instances of  apparent  HF injury.   A discussion is
presented of  susceptibility of species to  HF poisoning.   Short-term
Public Limits  (STPL's)  and Public Emergency  Limits  (PEL's) are  also
presented.
17. Key Words and Document Analysis. 17a. Descriptors
 Air pollution
 Exposure
                             Hydrogen  Fluoride
                             Sensitivity
17b. Identifiers/Open-Ended Terms
Air  pollution  effects  (Humans)
Air  pollution  effects  -(animals)
Short-term Public Limits  (STPL's)
Public Emergency  Limits  (PEL's)
17e. COSATI Field/Group  13B
18. Availability Statement Unlimited
                                19.. Security Class (This
                                  Report)
                                    UNCLASSIFlEf
                                                  20. Security Class (T
                                                    Page
                                                   -   UNCLASSIFIED
                                                               ft-
                                                               his
         21. No. of Pages
              16
                                                   22. Price
FORM NT1S-30 (10-70)
                                                                    USCOMM-DC 40329-P7I

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                      Committee on Toxicology

Herbert E. Stokinger,  Chairman                  Verald K.  Rowe
Arthur B. DuBois, Vice-Chairman                C.  Boyd Shaffer
Bertram D.  Dinman                              Frank G. Stahdaert
Seymour L.  Friess                              James H. Sterner
Harold M. Peck                                 Richard D.  Stewart
                 Subcommittee on Hydrogen Fluoride

                    Arthur B.  DuBois, Chairman
                    M. L. Keplinger
                    Charles  F.  Reinhardt
                    David L. Stoddard
                    Ralph C.  Wands,  Director
                  Advisory Center on Toxicology
       National Academy of Sciences-National Research Council

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Prepared under Contract No. CPA 70-57 between the
National Academy of Sciences,  Advisory Center on
Toxicology and the Air Pollution Control Office of the
Environmental Protection Agency.
Contract Monitor:
     Dr. Vaun A.. Newill, Director
     Division of Health Effects Research
     Air Pollution Control Office
     Environmental Protection Agency
     Durham,  North Carolina
         The information contained  in this
       letter is intended only as guidance
       for your professional and technical
       staff and contractors.  It  is  not  for
       publi.c  distribution  or attribution
       to the National  Academy of Scienc&s
       without prior written approval.

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                               NOTICE
       The study reported herein was undertaken under the aegis of the
National Research Council with the express approval of the Governing
Board of the National Research Council. Such approval indicated that
the Board considered that the problem is of national significance; that
elucidation and/or solution of the problem required scientific or
technical competence and that the resources of the National Research
Council were particularly suitable to the conduct of the project.  The
institutional responsibilities of the National Research Council were then
discharged in the following manner:
                         s
       The members of the committee were selected  for their individual
scholarly competence and judgment with due consideration for the
balance and breadth  of disciplines. Responsibility for all aspects of this
report rests with the committee,  to whom we express  our  sincere
appreciation.

       Although the  reports  of our study committees are not submitted
for approval to the Academy membership nor to the Council, each report
is reviewed by a second group of  scientists according to procedures
established and monitored by the Academy's Report Review Committee.
Such reviews are intended to  determine, inter alia, whether the major
questions and relevant points of view have been addressed and whether
the reported  findings,  conclusions and  recommendations arose from the
available data and information.  Distribution of the report is permitted
only after satisfactory completion of this review process.

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                           INTRODUCTION

      This is one of a series of documents prepared by the Committee on
Toxicology of the National Academy of Sciences-National Research Council,
with the support of the Advisory Center on Toxicology, at the request of
the Air Pollution Control Office of the Environmental Protection Agency.
A subcommittee was appointed to prepare the document which was then
endorsed by the Committee.

      In preparing this document the subcommittee was guided by the
principles set forth in the first document of this series: "Basis for
Establishing Short-Term Inhalation Exposure Limits of the Public to
Atmospheric Pollutants," (1) and the National Academy of Sciences-National
Research Council  report, "Fluorides, " (2) now in preparation by the
Committee on Biologic Effects of Atmospheric Pollutants  of the  Division
of Medical Sciences.  The latter document treats the effects  of HF on
vegetation and animals,  and methods for the analysis for airborne concen-
trations. Therefore,  this report gives only minimal attention to the effects
of HF on vegetation and  animals and no attention to analytical procedures.

      Most of the authoritative work on hydrogen fluoride  gas dates from
the mid-1940's,  although there are a few significant contributions from
earlier periods. In most of the documents  published  prior to the late
1960's, mathematical units expressing concentrations vary.  For ease of
comparison,  all units expressing atmospheric concentration have been
converted to mg/m^,  considering HF as a monomolecular compound
where 1 ppm = 0.8184 mg/m .  In those few instances where parts by
volume are more appropriate, either ppm or ppb has been used.

      Some atmospheric standards for HF already exist.  For instance,
occupational levels recommended by the American Conference of Govern-
mental Industrial Hygienists set the threshold limit value  (TLV) for an
eight-hour work day at 2 mg/m^ . By application of the ACGIH Permissible
Excursion (Time-weighted) rule, a maximum atmospheric concentration
for HF of 4. 0 mg/m^ is  permitted,  provided  it is compensated by an
equivalent excursion below the limit during the workday.  The state of
Pennsylvania has adopted an atmospheric limit for HF of 2 mg/m3  for
15 minutes (3) and the National Academy of Sciences-National Research
Council Committee on Toxicology recommended emergency exposure
limits for HF of 16 mg/m^ for ten minutes,  8 mg/m^ for  30 minutes,  and
approximately 7 mg/m^  for 60 minutes applicable only to  military and
space operations (4).

      Experimental data and histories of exposures are reviewed in this
report and recommendations for short-term exposure limits of the public
are made.

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                     Physical-Chemical Properties
      At atmospheric pressure, below 19° C, hydrogen fluoride is a
corrosive, fuming, nearly colorless liquid.  Above 19° C it is gaseous.

      HF has a monomolecular weight of 20.01, but at 1 atmosphere
pressure and at a temperature below 100° C it exists as an associated
molecule up to H^F^, with an average molecular weight of 50 to 55.
Some authors  (5) have considered the possibility that toxicity may be
related to molecular species, but this concept has not been thoroughly
explored.

      Hydrogen fluoride gas has a density of 0. 921 g/1 at 0° C and
1 atmosphere  of pressure and is  very soluble in water.  When anhydrous
liquid HF is vaporized into the atmosphere it is an almost  colorless gas
cloud that forms a fog upon combination with moisture in air.  This fog
is an aerosol of hydrofluoric acid, which is corrosive to almost all
inorganic and  organic materials.
                            Sources of HF

      Active volcanoes are the only known natural source of gaseous HF.
Gaseous effluents from fumaroles and volcanoes contribute background
levels of HF throughout the world.  This gas  has been detected at locations
far removed from man-made  sources  (6).

      Many industrial processes contribute gaseous  HF to the atmosphere.
The gas is an  effluent of processes such as aluminum reduction,  phosphate
fertilizer manufacturing, petroleum refining, manufacture of fluorocarbon
compounds; the making of brick, pottery,  glass, and ceramics;  ferro-
enamel  production, metal fluxing agents used in foundries and metal-
fabricating plants, welding processes,  and the burning of coal. Coal may
contain  40 to 295 ppm of fluoride depending on its source,  some of which
is released as HF on burning.

      In recent years there has been a  change in aluminum-reduction
processes,  using a synthetic cryolite manufactured using HF, rather
than naturally occurring  cryolite.  This process, as  well as the  production
of HF itself, also contributes to atmospheric levels of the gas.

      Most of the modern industrial plants whose operations  can release
HF to the atmosphere have scrubbers that are reported to be about 95%

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efficient,  whereas less modern plants are estimated to have control
efficiencies as low as 80%.

      Within the past decade another potential source of atmospheric
HF has appeared: this  is liquid-fueled rockets employing propellant
oxidizers consisting of mixtures of liquid fluorine and liquid oxygen.  In
the event  of accidental release of these liquid oxidizers to the atmosphere,
which would almost certainly be attended by fire, the resultant products
would include  HF. HF also is a product of normal combustion of the fuel
in these rocket engines.

      Increased use  of HF for a variety of applications similarly increases
the need to transport the material from place of manufacture to place of
use. Temporary storage facilities at both locations and transfer from
storage containers to other containers are operational requirements.  In
each instance  there is  danger of accidental spills that could result  in
exposure  of occupational personnel and the public.
                 Clinical and Pathological effects of HF

      The primary effect of acute exposure to gaseous HF in concentra-
tions above a few mg/mr is irritation of the skin,  eyes,  and respiratory
passages.  In addition, localized tissue damage may occur as a result of
the corrosive nature of this compound at concentrations above the
recommended limits.

      There are  several published accounts of the  clinical effects in man
of acute poisoning with gaseous HF. Local irritation of the mucous
membranes of the eyes, nose, throat,and bronchi is reported by
Sollmann (7)  and  Williams (8). In addition, there may be difficulty in
breathing.  An individual exposed to more than 10 mg/m^ will almost
immediately  experience a biting or burning sensation in the nose, followed
by a nasal  discharge and, occasionally, a nosebleed; burning of the eyes
and lacrimation also occur.  Exposure to higher concentrations may lead
to pulmonary edema and respiratory distress with an onset  that may be
delayed 12  to 24 hours. This may  be accompanied by gastroenteritis,
with nausea, vomiting, abdominal burning,  diarrhea, and collapse.
Exposure to lethal concentrations produces muscular weakness and
tremors,  clonic  convulsions, a drop in blood pressure,  and moderate
cyanosis; and death may result from sudden respiratory or  cardiac
arrest.

      There are  but a  few reports of pathological findings available from
fatal HF poisonings. According to one report (9) the heart was  dilated,
the bronchial tree was acutely inflamed with a partially ulcerated mucosa,
and the lungs were edematous,congested, and severely hemorrhagic.

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      Additional pathological studies have been done on experimental
animals exposed to either lethal or nonlethal concentrations of HF (10,11,
12). Pulmonary changes, mainly hemorrhage, edema, and congestion,
are consistently seen in acute HF poisoning. The severity of the change
is more or lees proportional to the duration and concentration of exposure
to HF. Lesions can be found in the kidney,  liver,  and nasal  passages.
Also, bone marrow obtained seven days after exposure shows an increased
cellularity,  but with a disproportionate increase in myeloid  cells.
                           Toxicity Studies


      Several groups  of workers have studied the  effects of HF gas on
experimental animals. Machle and co-workers  (10) conducted time-
concentration studies on rabbits and guinea pigs at concentrations  ranging
from 24 to 8000 mg/m^ for periods of five minutes to 41 hours. They
found that exposure for five minutes or longer to concentrations greater
than 1500 mg/m^ may be lethal to  rabbits and guinea pigs. Exposure to
1000 mg/m^ for 30 minutes caused changes in the lungs, but no deaths,
in either species of animals.  Concentrations below 100 mg/m^  for five
hours produced lung damage,  but no deaths,  in  rabbits or guinea pigs.
The primary tissue damage was manifested by hemorrhage, edema, or
congestion. At concentrations of HF above 2000 mg/m^ areas  of the
cornea were eroded,  there was necrosis of turbinates,  necrosis of
heart muscles,  alveolar and interstitial hemorrhage, edema,  emphysema,
and, in those that survived several days following exposure, broncho-
pneumonia. Also, in  the animals exposed at  the higher concentrations, the
liver showed necrosis of the parenchyma and destruction of cytoplasm;
the spleen was edematous  and congested and the kidneys showed some
degenerative changes in renal tubules and glomeruli.

      In another study (5), designed to bracket maximal and minimal
effects, five species  of animals inhaled  HF concentrations of 25 mg/m^
or 7 mg/m^  for 166 hours in repeated, daily  six-hour exposures for
approximately 30 days. Exposure  to the higher  concentration was lethal
to 100% of the rats and mice, but not lethal to guinea pigs, rabbits, and
dogs. Among the surviving animals,  the rabbits showed a slight loss  in
weight, the dogs were apparently unaffected,  and  the guinea pigs began
to lose weight after the third week of exposure.  Exposure to the low
concentration did not interfere with normal weight gains in any of  the
animals  except the rabbits. Three species,  the dog, rabbit, and rat,
were examined for pathological changes following exposure to  both con-
centrations of HF. At the 25 mg/m3 level there was moderate hemorrhage
and  edema of the lungs  in all three species,  ulceration of the scrotum in
dogs and renal cortical degeneration and necrosis in the rat. At the
7 mg/m^  level, localized hemorrhages were  found in the lungs of one dog

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out of five examined, and no changes were observed in the rat or rabbit.

      Rosenholtz and co-workers (11) studied rats, rabbits, guinea pigs,
and dogs to make possible a better estimate of the LC5Q (the concentra-
tion calculated to be lethal to 50% of a group of experimental animals)
from single exposures to high concentrations of HF for short periods of
time. The JLC's were as follows:
      Species               Exposure Time
                              (minutes)                  (mg/m3)
      Rat                          5                     4060
      Rat                         15                     2200
      Guinea Pig                  15                     3540
      Rat                         30                     1670
      Rat                         60                     1070

      Signs of toxicity in the animals included irritation of the conjunctiva,
 nasal tissues,  and respiratory system. The survivors ceased to show
 these signs about one week after the exposure.  Pathological lesions were
 observed in the kidney and liver, the  severity of which was directly
 related to the dosage received.  The external nares and nasal vestibules
 were black and,  at dosages causing considerable mortality, those areas
 showed zones of mucosal and submucosal necrosis. The skin of animals
 exposed to high (lethal) concentrations showed superficial subcutaneous
 and deep dermal zones of acute inflammation. The hair of these animals
 could be pulled out with ease and the  skin ruptured under minimal tension.
 The rat was found to be the most susceptible species of those tested,
 which confirmed the findings of Stokinger (5). Additional evaluations were
 made at nonlethal concentrations of HF that approximated 50%, 25%,  12. 5%,
 and 6%  of the rat LC$Q.

      Exposure of animals to nonlethal concentrations  produced similar
 clinical signs that decreased in intensity and duration with decreasing
 dosage.  At 6% of the rat LC50 level (250 mg/m3 in rats for 15 minutes
 and 80 mg/m  in rats  for 60 minutes), clinical signs  decreased to mild
 irritation of the eyes and nose.  These signs disappeared  shortly after
 withdrawal from the chamber.  Few pathological changes were seen at
 sub-lethal concentrations, although the skin was not examined histo-
 pathologically. Two rabbits, one exposed at 1020 mg/m^  for 15 minutes,
 and one at 700 mg/m^ for 15 minutes, showed pulmonary changes  ranging
 from intense intra-alveolar septal congestion to frank hemorrhage with a
 discrete lobular distribution.

      In connection with the animal studies reported by Machle (10),  some
 observations were made on two humans.  After one minute at 100 mg/m ,
 there was smarting of the skin, conjunctival  and respiratory irritation,
 and recognition of the  flat sour taste of HF. Exposure at 50 mg/m3 was

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exceedingly uncomfortable, as shown by irritation of mucous membranes,
but there was no smarting of the skin. At 26 mg/m^ irritation decreased
and the ability to taste gas was delayed, but the atmosphere was uncomfort-
able throughout the three-minute period of exposure.
                   Instances of Apparent HF Injury

      Even though there are numerous industrial processes that can cause
HF injury to workers and closely associated nonworkers,  there are few
records of such injuries.  However,  there are several well-documented
reports of injuries resulting from accidental exposures to ruptured
containers of anhydrous HF (9).

      Although gaseous HF undoubtedly played some role in these accidents,
the major effect is associated with the liquid state. The information does,
however,  emphasize the extreme hazard of HF  and the clinical develop-
ments encountered.  In three separate events, a total of eight men were
splashed with liquid HF.  In one event,  involving four men, one died of
pulmonary edema approximately two hours  after the accident. The other
three survived, but suffered severe  chemical burns.  In the other  two
events, all four men died; two of them in two hours,  one in four hours,
and one ten hours after the accident. Consciousness remains until death,
which is usually sudden, from respiratory  distress and cardiac arrest.
Characteristically, the respiratory  tree is  inflamed and the lungs
moderately to severely congested.

      There are other reported cases of severe poisonings and  deaths
among workers in superphosphate factories, fertilizer factories,  among
welders, garage workers, waterworks  employees, and enamel-factory
workers (11).  In most of these cases the clinical picture in part resembles
HF poisoning,  but other fluoride-containing particulates and gases such
as SiF4» phosgene (from the high temperature decomposition of halogenated
hydrocarbons)  and a variety of fluoride dusts, also were present.
                Species Susceptibility to HF Poisoning

      Plants are more susceptible to damage from gaseous HF than are
animals, although among plant species there is a wide  variation in
tolerance.  Some plants,  gladiolus for example, may be severely damaged
by airborne concentrations as low as 3 ng/mr  (leading  to accumulations
of 20 ppm in plant tissues),  whereas camellia  can tolerate tissue accumula-
tion to as much as 1500 ppm. There is a complex and poorly understood
relationship between airborne concentrations and levels that accumulate in
plants.  Grasses and forage  crops vary throughout a wide range in
accumulation and tolerance.  HF is  absorbed systemically through the

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stems and leaves of plants.  The absorbed fluorides migrate  to the margins
of the leaves where early evidence of damage appears as yellowing or
browning of tissues.

      Cattle, sheep, and goats that feed on fluoride-contaminated forage
may sicken and die from chronic fluoride poisoning, fluorosis, a not
uncommon occurrence in areas where effluents containing fluorides affect
grazing lands. Animals with a total dietary intake of fluoride greater than
300 ppm per day are likely to  develop fluorosis. A generally accepted
guide (14) for fluoride concentration in animal forage  is based on an annual
average of no more than 40  ppm of fluoride by dry weight.

      Inhaled HF,  even in heavily contaminated areas, contributes so
small a fraction of the total intake by grazing animals that it cannot be
considered an important factor in either chronic or acute systemic
poisoning.

                  Atmospheric Concentrations of HF

      National surveillance  programs conducted since the mid-19601 a
reveal atmospheric levels of fluoride ranging from 0. 5 to 1. 89 ug/m^
in urban areas and 0. 05 to 0.16 (ig/m^ in nonurban areas (15).
Huffstutler (16),  reporting on fluoride concentrations  within a 7-1/2 mile
radius in an area of Florida where a number of fertilizer plants are
operated,  found a  four-hour sample peak of 100 jj.g fluoride/m^ one year,
and a maximum four-hour sample average of 2. 7 ug fluoride/m^ in
another year. Similarly, he reports a 24-hour sample peak of 68 |ig
fluoride/m^, and a maximum  24-hour sample average of 4. 3 (jig fluoride/m3.
These studies have been carried  out over a period of seven years and the
1969 data show a marked decrease both in peak levels and in sample
period averages as a result of improved scrubbing procedures.

      As with other gaseous contaminants, the greatest hazard is down-
wind from the effluent stacks.  Workers in the immediate environment
of operations involving  HF may not be as readily or as heavily exposed
as nonworkers some several hundred yards  downwind. Beyond two or
three miles  downwind,  mixing and  dilution  with air reduces HF below
detectable or background levels.

  Guides for Short-Term and Emergency Exposures of the Public to HF

      The basis for setting limits for short-term exposure of the public
and for  emergency exposure of the  public to air  pollutants is detailed  in
the first document of this series, "Basis for  Establishing Guides for
Short-Term Exposures of the  Public to Air Pollutants" (1)

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      Experimental data and occupational experience indicate that man
is susceptible to irritation and possible injury from gaseous  HF. At
10 mg/m3 the mucosa are irritated; at 26 mg/m3 for three minutes he
is uncomfortable and able to taste the gas; at 50 mg/m3 the severity of
the irritation increases; and at 100 mg/m3 a stinging sensation of the
skin is added and other irritations  are so severe as to make  exposure
for more than one minute intolerable. Since the primary irritant action
of HF is on the mucosa, particularly the  respiratory mucosa, it is
important to  recognize  the more sensitive segments of the population,
e.g. , the  asthmatics and bronchitics,  as the limiting factors.

      The following recommendations are time-weighted averages, which
are considered not to present any health hazard.  It should be recognized,
however,  that excursions above these averages are likely to  produce
objectionable odors  and, possibly, minimal irritation.


                  Short-Term Public  Limits (STPL's)

      The limits for short-term exposure of the public to air pollutants
are  established in view of the possibility of repeated  events  in the same
locality. These  events, such as intentional  release of HF to the atmosphere,
are assumed to  be controllable with respect to concentration and duration
of release so that the limit  is not exceeded.  No adverse health effects,
however transient, are anticipated at  the limits set forth below:
                               STPL's
      10-30 and 60 min                 3 mg/m3 (4 ppm) (frequency
                                                limit 1 hr daily)

      5 hr/day, 3-4 days/mo           1 mg/m3 (1 ppm)
                  Public Emergency Limits (PEL's)

      Public emergency limits represent values necessary to cope with
an accidental,  unpredictable, or uncontrollable event. The  PEL assumes
that some temporary discomfort may accrue to the public but that any
effect resulting from the exposure is reversible and without residual
damage.
                                PEL's
      10 min                   8 mg/m3              (10 ppm)
      30 min and               4 mg/m3              ( 5 ppm)
        60 min

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                           Research Needs

      The data from industrial experience and laboratory experimenta-
tion are insufficient to permit a relaxation in efforts to determine the
toxic hazards of atmospheric hydrogen fluoride.  It is hoped that this
guide will serve as a stimulus for occupational health authorities and
researchers to investigate further the effects of  HF on the health and
welfare of the public and on the environment so that greater confidence
can be placed in the recommended limits.

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                            REFERENCES

 1.    National Academy of Sciences-National Research Council Report to
        the Air Pollution Control Office, Environmental Protection
        Agency, Basis for Establishing Short-Term Inhalation Exposure
        Limits of the Public to Atmospheric Pollutants.  1 971.

 2.    National Academy of Sciences-National Research Council Report.
        Fluorides.  In press.

 3.    Pennsylvania Department of Health, Division of Occupational Health.
        Short-Term Limits for Exposure to Airborne Contaminants.   A
        Documentation.  1967-1969.

 4.    National Academy of Sciences-National Research Council, Basis for
        Establishing Emergency  Inhalation Exposure Limits Applicable
        to Military and Space Chemicals. 1964.

 5.    Stokinger, Herbert E. "Toxicity following inhalation of fluorine and
        hydrogen fluoride. " IN Pharmacology and Toxicology of Uranium
        Compounds, edited by Carl Voegtlin and Harold  C.  Hodge.
        New York, McGraw-Hill. 1949. p. 1021-1057.
 6.    MacDonald, H. E. Fluoride  as air pollutant.  Fluoride Qtly. Repts.
        (Internatl  Soc. for Fluoride Res. ) 2:4-12  Jan 1969.

 7.    Sollmann, To raid.  A Manual of Pharmacology and its Applications
        to Therapeutics and Toxicology. 8th ed. Philadelphia,  Saunders.
        1957.  p.  1104.

 8.    Williams, Charles R. "Atmospheric contamination from the casting
        of magnesium. "  J. Ind. Hyg. Toxicol. 24:277-280  Nov 1942.

 9.    Eagers, R. Y.  Toxic Properties of Inorganic Fluorire Compounds.
        New York,  Elsevier.  1969.  152 p.

10.    Machle, Willard, Frederick Thamann, Karl Kitzmiller,  and Jacob
        Cholak. "The effects of the inhalation of hydrogen  fluoride. I.
        The response following exposure to high concentrations. "
        J. Ind. Hyg. 16:129-145  March 1934.

11.    Rosenholtz,  Mitchell J. ,  Theophilus R.  Carson, Maurice H. Weeks,
        Frank Wilinski,  Duane F. Ford, and Fred W.  Oberst.
        "A Toxicopathologic study in animals  after brief single exposures
        to hydrogen fluoride. " Am. Ind. Hyg. Assoc. J.  24:253-261 May-
        June 1963.

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12.    Keplinger,  M. L.  Report of toxic effects of fluorine following
        short-term inhalation. NASA contract NCR 10-007-012. Rept.
        No. NASA-CR-100415.  Dec 31,  1968.  273 p.

13.    Krechniak, J.   Fluoride hazards among welders.  Fluoride Qtly.
        Rcpts.  (Internatl. Soc. for Fluoride Res.) 2:13-24 Jan. 1969.

14.    Suttie,  J. W. "Air quality standards for the protection of farm
        animals from fluorides." Air  Pollution Control Assoc., J.
        19:239-242 April 1969.

15.    U.S. Department of Health, Education, and Welfare. Public Health
        Service.  Robert A.  Taft Sanitary Engineering Center, Cincinnati,
        Ohio. Air pollution measurements of the National Air Sampling
        Network Analysis of suspended particulate  samples  collected
        1953-1957. Public Health Service Publication No. 637.  1958.

16.    Huffstutler, K. K.  "Fluoride concentrations in various receptors
        near phosphate industries."  Paper presented at the 63rd Annual
        Meeting of the Air Pollution Control Association, St. Louis,
        Mo. , June 14-18, 1970.

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